diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ebe7a302f545116b228b9daf9ee7bab5af9ac614
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc.srt
@@ -0,0 +1,1864 @@
+1
+00:00:06,600 --> 00:00:12,560
+اليوم بنختتم إن شاء الله الفصل الثالث هتلاحظوا أنه
+
+2
+00:00:12,560 --> 00:00:18,220
+هنتكلم على reactions of alkynes تفاعلات الـalkynes
+
+3
+00:00:18,220 --> 00:00:23,080
+و هتلاحظوا أنه إن شاء الله هتكون بسيطة بالذات بعد
+
+4
+00:00:23,080 --> 00:00:28,520
+ما أنتم فهمتوا كويس تفاعلات الـalkynes الآن
+
+5
+00:00:28,520 --> 00:00:33,020
+الـalkynes اللي فيها double bond كانت تفاعلها
+
+6
+00:00:33,020 --> 00:00:39,870
+الأساسي الـ addition الإضافة الـalkynes أيضًا
+
+7
+00:00:39,870 --> 00:00:45,630
+تفاعلها الأساسي الـ addition لأنه فيها triple bond
+
+8
+00:00:45,630 --> 00:00:51,670
+تقريبًا الـ reagents اللي شفناهم بيتفاعلوا مع
+
+9
+00:00:51,670 --> 00:00:56,740
+الـalkynes نفسهم بدنا نشوفهم كيف بيتفاعلوا مع الـ 
+
+10
+00:00:56,740 --> 00:01:02,500
+kinds فعلى سبيل المثال ممكن ناخد الـ addition of HX
+
+11
+00:01:02,500 --> 00:01:11,200
+HX يعني HCl أو HBr to all kinds اللي لاحظوا أنه
+
+12
+00:01:11,200 --> 00:01:19,260
+تفاعل الـ HX للـ  alkyne بيضيف مرتين لأن الـ alkyne في
+
+13
+00:01:19,260 --> 00:01:25,660
+كم triple bond اثنتين اثنتين غير الـ Sigma bond
+
+14
+00:01:25,660 --> 00:01:29,960
+الأصلية في الـ alkynes فبتتم عملية الإضافة
+
+15
+00:01:29,960 --> 00:01:35,780
+مرتين الإضافة الأولى بتضيف فيها HCl لأن لما بتضيف
+
+16
+00:01:35,780 --> 00:01:40,240
+HCl على مثل هذا الألكاين كيف بنتوقع تضيف
+
+17
+00:01:40,240 --> 00:01:44,940
+Markovnikov ولا Anti Markovnikov addition؟ بتضيف
+
+18
+00:01:44,940 --> 00:01:49,430
+Markovnikov addition واضح فهي زي ما بتلاحظوا في
+
+19
+00:01:49,430 --> 00:01:54,650
+عندي H إجت على هذه الذرة و Cl الآن هذا اللي بتكون
+
+20
+00:01:54,650 --> 00:02:00,610
+لما يكون عندي كمية زائدة من الـ HCl مباشرة بستمر
+
+21
+00:02:00,610 --> 00:02:04,570
+التفاعل مرة ثانية و بضيف كمان H ثانية و كمان Cl
+
+22
+00:02:04,570 --> 00:02:10,890
+ثانية إذا في المحصلة بيصير عندي إضافتين HCl و كل
+
+23
+00:02:10,890 --> 00:02:16,650
+إضافة منهم Markovnikov's addition واضح كل إضافة
+
+24
+00:02:16,650 --> 00:02:19,810
+منهم Markovnikov's addition كأنه بيجي هنا ذرتين
+
+25
+00:02:19,810 --> 00:02:25,910
+هيدروجين و بيجي هنا ذرتين كلورين ومثلها أيضًا الـ
+
+26
+00:02:25,910 --> 00:02:33,770
+HBr فالـ HBr و HCl بيضيفوا على حسب Markovnikov's
+
+27
+00:02:33,770 --> 00:02:38,550
+addition لكن two successive additions يعني إضافتين
+
+28
+00:02:38,550 --> 00:02:41,310
+متواليتين واضح
+
+29
+00:02:45,200 --> 00:02:49,960
+النوع الثاني اللي أخذنا إضافة الـ halogens إذا
+
+30
+00:02:49,960 --> 00:02:56,120
+متذكرين Br2 و Cl2 برضه بنفس المنطق تمامًا الـ
+
+31
+00:02:56,120 --> 00:03:01,660
+halogens بتضيف مرتين طبعًا أنتم متذكرين إن الإضافة
+
+32
+00:03:01,660 --> 00:03:07,070
+في الـ halogens كانت Anti addition لكن لما بضيف كمان
+
+33
+00:03:07,070 --> 00:03:12,590
+مرة خلاص بيصير عندي اثنتين Br و اثنتين Br فبرتفع الـ
+
+34
+00:03:12,590 --> 00:03:16,350
+halogens لما نضيف أفضل شيء بيضيف حقيقة لبرومين
+
+35
+00:03:16,350 --> 00:03:22,790
+بيصير عندي two successive additions مرتين بيضيف
+
+36
+00:03:22,790 --> 00:03:28,740
+لبروم بتكون عندي اللي هي الـ tetra bromocompounds
+
+37
+00:03:28,740 --> 00:03:31,860
+يعني لو أنا بدي آجي في الامتحان أقولك والله هي
+
+38
+00:03:31,860 --> 00:03:35,480
+tetra bromocompounds how can you prepare this
+
+39
+00:03:35,480 --> 00:03:39,560
+compound بدي يكون جزء من تفكيرك و لو كان عند
+
+40
+00:03:39,560 --> 00:03:46,060
+triple bond عملت عليها إضافة برومين مرتين عملت
+
+41
+00:03:46,060 --> 00:03:49,040
+عليها إضافة برومين على مرتين واضح
+
+42
+00:03:53,800 --> 00:04:01,040
+الآن بنجي للماء الماء عادة بيضيفوها في وجود حمض
+
+43
+00:04:01,040 --> 00:04:07,860
+و زئبق على الألكاين حمض و زئبق كثير الآن اللي بدو
+
+44
+00:04:07,860 --> 00:04:13,740
+يصير عندي أنه بيتم إضافة الماء لمرة واحدة حسب
+
+45
+00:04:13,740 --> 00:04:17,440
+قاعدة Markovnikov's addition بمعنى هنا بدو ييجي
+
+46
+00:04:17,440 --> 00:04:24,300
+عندي H وهنا بدو ييجي عندي OH هذه إضافة الماء H هذا
+
+47
+00:04:24,300 --> 00:04:26,980
+عبارة عن Markovnikov addition
+
+48
+00:04:29,750 --> 00:04:35,070
+المركب اللي تكون عندي فيه من ناحية المجموعات
+
+49
+00:04:35,070 --> 00:04:41,310
+الوظيفية مجموعتين وظيفيتين فيه الـ alkene اللي هو
+
+50
+00:04:41,310 --> 00:04:46,190
+الـ double bond وفيه الـ alcohol اللي هو الـ OH الـ
+
+51
+00:04:46,190 --> 00:04:51,550
+alcohol وعشان هيك بيسموه enol ايش يعني enol؟ en
+
+52
+00:04:51,550 --> 00:04:57,040
+المجموعة الوظيفية تبع الـ alkene و الـ ol المجموعة
+
+53
+00:04:57,040 --> 00:04:59,800
+الوظيفية بتاعت الـ alcohol مش بيقول ميثانول
+
+54
+00:04:59,800 --> 00:05:04,720
+ايثانول واضح فهذا عبارة عن enol في المجموعتين
+
+55
+00:05:04,720 --> 00:05:09,780
+الوظيفيتين هدول، الآن هذا الـ enol في الـ aliphatic
+
+56
+00:05:09,780 --> 00:05:15,100
+compounds بشكل عام مش ثابت، ما بيضلش زي ما هو،
+
+57
+00:05:15,100 --> 00:05:23,100
+بيغيّر واضح؟ يعني ما بنفعش أن أنا أحطه حتى نتيجة هذا
+
+58
+00:05:23,100 --> 00:05:30,240
+غير ثابت الـ enol طب ايش بيعمل؟ بيتحول إلى صيغة
+
+59
+00:05:30,240 --> 00:05:34,460
+ثانية فهذه الصيغة بتنتقل الـ bond هذه هنا و الـ H
+
+60
+00:05:34,460 --> 00:05:36,680
+بتيجي على الـ carbon لاحظوا ايش اللي أنا قاعد
+
+61
+00:05:36,680 --> 00:05:43,590
+بحكيه؟ شغلتين بدهم يتحركوا، بدها تتحرك هيدروجين و
+
+62
+00:05:43,590 --> 00:05:49,050
+بدأت تتحرك رابطة إذا حركة الإلكترونات و حركة
+
+63
+00:05:49,050 --> 00:05:54,950
+البروتونات الـ H فلما تلاحظوا أن هذا بدأت تتحرك هنا
+
+64
+00:05:54,950 --> 00:05:59,290
+الـ double bond والهيدروجين بدأ تيجي هنا كم حركة
+
+65
+00:05:59,290 --> 00:06:04,220
+عند الـ atoms و Charge أو Electrons لما تتم هذه
+
+66
+00:06:04,220 --> 00:06:08,520
+الحركة الـ C هذا بتصير C double bond O و الـ CH2
+
+67
+00:06:08,520 --> 00:06:13,960
+بتصير CH3 الآن إذا بتطلع على المجموعة الوظيفية
+
+68
+00:06:13,960 --> 00:06:20,180
+اللي موجودة هنا شو هي كيتون الـ C double bond O الـ
+
+69
+00:06:20,180 --> 00:06:24,900
+C double bond O هذه كيتون فبدل ما كان عندي مجمعتين
+
+70
+00:06:24,900 --> 00:06:29,810
+وظيفيتين جنب بعض اللي هم الـ enol والـ الانول
+
+71
+00:06:29,810 --> 00:06:35,490
+اتحول إلى كيتو form هذه العملية عملية التحول
+
+72
+00:06:35,490 --> 00:06:37,850
+بيسموها tautomerism
+
+73
+00:06:47,240 --> 00:06:54,700
+هي عبارة عن عملية بتتم فيها حركتين حركة الـ charge
+
+74
+00:06:54,700 --> 00:06:59,820
+و حركة الـ hydrogen واضح إذا أنا بتحرك عندي
+
+75
+00:06:59,820 --> 00:07:06,320
+electrons زائد الـ protons الـ hydrogen واضح بتفرق
+
+76
+00:07:06,320 --> 00:07:10,560
+عن الـ resonance يعني لو بدأت أقولكوا بلغة بسيطة ايش
+
+77
+00:07:10,560 --> 00:07:16,470
+الفرق ما بين الـ resonance و الـ tautomerism الـ
+
+78
+00:07:16,470 --> 00:07:25,390
+Resonance كانت بس الإلكترونات بتتحرك و
+
+79
+00:07:25,390 --> 00:07:29,850
+بيكون موجود عندها الشغل ثاني يعني بيكون مرة بهذا
+
+80
+00:07:29,850 --> 00:07:32,370
+الشكل مرة بهذا الشكل مرة بهذا الشكل مرة بهذا الشكل
+
+81
+00:07:32,370 --> 00:07:39,520
+التاوتوميرزم مختلفة التاوتوميرزم عبارة عن حركة شحنة
+
+82
+00:07:39,520 --> 00:07:47,720
+أو إلكترونات وحركة hydrogen atoms لو كنتم
+
+83
+00:07:47,720 --> 00:07:51,580
+بتتذكروا الـ resonance اللي هو حركة إلكترونات كيف
+
+84
+00:07:51,580 --> 00:07:55,360
+السهم اللي كنا نعبر فيه عن الـ resonance double
+
+85
+00:07:55,360 --> 00:08:01,600
+headed arrows بهذا الشكل التوتوميرزم عبارة عن
+
+86
+00:08:01,600 --> 00:08:06,720
+اتزان equilibrium يعني بيكون عندي موجود من هذا و
+
+87
+00:08:06,720 --> 00:08:10,220
+بيكون عندي موجود من هذا بنسب معينة في المحلول
+
+88
+00:08:10,220 --> 00:08:13,620
+فالـ tautomerism يعبر عن equilibrium والسهم تبع الـ
+
+89
+00:08:13,620 --> 00:08:18,440
+equilibrium كيف بيكون؟ عشان هيك كذا السهم بيديكم
+
+90
+00:08:18,440 --> 00:08:24,920
+بتصلحوا بهذا الشكل سهم اتزان واضح؟ فلو أنا بدي آجي
+
+91
+00:08:24,920 --> 00:08:29,740
+أقولكوا مثلًا أرسملكوا هذا السهم أقولكوا this arrow
+
+92
+00:08:29,740 --> 00:08:34,060
+is used to indicate tautomerism .. no it is used to
+
+93
+00:08:34,060 --> 00:08:38,540
+indicate resonance however the equilibrium arrow
+
+94
+00:08:38,540 --> 00:08:40,280
+or the double arrows
+
+95
+00:08:45,030 --> 00:08:51,710
+Tautomerism هي عبارة عن حركة شحنات وحركة بروتونات
+
+96
+00:08:51,710 --> 00:08:56,350
+بيستخدم لتوضيحها سهم الاتزان الكيميائي لأنه هي
+
+97
+00:08:56,350 --> 00:08:59,710
+عملية اتزان يعني لو قلنا tautomerism is an
+
+98
+00:08:59,710 --> 00:09:03,990
+equilibrium process الجواب صح غالبًا اللي بيصير
+
+99
+00:09:03,990 --> 00:09:09,130
+كالتالي أنه بيكون الـ keto هذا بنسبة أحيانًا تفوق الـ
+
+100
+00:09:09,130 --> 00:09:17,670
+99% و الـ enol بنسبة أقل من 1% واضح؟ هذا الـ
+
+101
+00:09:17,670 --> 00:09:22,390
+tautomerism شو احنا بنسميها حسب الأطراف تبعونها
+
+102
+00:09:22,390 --> 00:09:28,210
+keto enol tautomerism إذا احنا أمام شغلة جديدة
+
+103
+00:09:28,210 --> 00:09:37,140
+قاعدين بنتعلمها keto enol tautomerism فإذا كان عند
+
+104
+00:09:37,140 --> 00:09:41,880
+الـ enol فإنه يتحول إلى الـ ketone و هذا الكلام وين
+
+105
+00:09:41,880 --> 00:09:47,600
+بيكون في الـ aliphatic compounds يعني بالـ aliphatic
+
+106
+00:09:47,600 --> 00:09:53,520
+compounds كشكل كيميائي مش مقبول ولا مرغوب أن عمرك
+
+107
+00:09:53,520 --> 00:10:00,600
+تشوفه double bond جنبها OH يعني كأنه هذا بشكل عام
+
+108
+00:10:01,690 --> 00:10:05,470
+بغض النظر عن بعض الأمثلة الخاصة اللي مش موضوعنا بشكل
+
+109
+00:10:05,470 --> 00:10:09,890
+عام ممنوع وأنتم بتعملوا structures أنكوا تحاولوا
+
+110
+00:10:09,890 --> 00:10:15,050
+تعملوا double bond جنبها OH في الـ aliphatic compounds
+
+111
+00:10:15,050 --> 00:10:20,870
+الآن العكس بيصير في الـ aromatic compounds في الـ
+
+112
+00:10:20,870 --> 00:10:24,710
+aromatic compounds زي البنزين وغيرها مسموح مفضل
+
+113
+00:10:24,710 --> 00:10:31,410
+أنكوا تعملوا double bond جنبها OH إذا بتذكروا هذا
+
+114
+00:10:31,410 --> 00:10:38,890
+المركب إذا رسمناه اللي فيه OH ايش اسمه؟ فينول
+
+115
+00:10:38,890 --> 00:10:51,510
+لاحظوا من اسمه it is an enol هو فيه الـ phenol اللي هي
+
+116
+00:10:51,510 --> 00:10:58,690
+حلقة البنزين وهي en وهي ol موجودين جانب بعض واضح؟
+
+117
+00:10:58,690 --> 00:11:04,190
+فوجود الـ en و الـ ol جنب بعض في الـ aromatic
+
+118
+00:11:04,190 --> 00:11:09,530
+compounds مسموح، بالـ phenols مسموح، وجود الـ en و
+
+119
+00:11:09,530 --> 00:11:15,970
+الـ ol جنب بعض في الـ aliphatic compounds لا، واضح؟
+
+120
+00:11:15,970 --> 00:11:18,650
+وجود الـ en و الـ ol جنب بعض في الـ aliphatic
+
+121
+00:11:18,650 --> 00:11:24,850
+compounds مش مسموح نهائيًا، واضح؟ ولا فيها مشكلة
+
+122
+00:11:29,260 --> 00:11:32,860
+زي ما بتلاحظوا أن الخطوة الأولى في الأساس لما ضاف
+
+123
+00:11:32,860 --> 00:11:36,360
+الـ H و الـ OH قبل التوتوميرزم كانت حسب قاعدة
+
+124
+00:11:36,360 --> 00:11:39,000
+Markovnikov's addition ولا Anti Markovnikov's
+
+125
+00:11:39,000 --> 00:11:42,660
+addition Markovnikov's addition هذا في حالة أنه
+
+126
+00:11:42,660 --> 00:11:47,640
+ضفنا H3O plus في وجود الزئبق
+
+127
+00:11:49,610 --> 00:11:56,610
+ممكن تكون إضافة الماء في الخطوة الأولى ويتبعها
+
+128
+00:11:56,610 --> 00:11:58,070
+توتوميرزم
+
+129
+00:12:08,170 --> 00:12:11,970
+بهذا الشكل لو كان عندي بهذا الشكل الألكاين و اجى
+
+130
+00:12:11,970 --> 00:12:16,430
+إضافة الـ borane بالـ THF في الخطوة الأولى H2O2 و H-
+
+131
+00:12:16,430 --> 00:12:22,610
+متذكرين هذه كانت شروط ايش إضافة الماء عكس قاعدة
+
+132
+00:12:22,610 --> 00:12:27,250
+Markovnikov Anti Markovnikov's addition فزي ما
+
+133
+00:12:27,250 --> 00:12:33,190
+بتلاحظوا زي ما بتلاحظوا أن هنا بتيجي الـ H على هذا
+
+134
+00:12:33,190 --> 00:12:38,160
+الطرف و الـ OH على هذا الطرف هل هذا Markovnikov's و
+
+135
+00:12:38,160 --> 00:12:40,520
+لا Anti Markovnikov's Addition هذا Anti
+
+136
+00:12:40,520 --> 00:12:43,140
+Markovnikov's Addition الـ H ما ييجيش على الكربون
+
+137
+00:12:43,140 --> 00:12:48,040
+اللي حاملة هيدروجين اجت بالعكس و الـ OH اجت بهذا
+
+138
+00:12:48,040 --> 00:12:54,160
+الشكل طبعًا هنا برضه نفس الشيء بيصير عند توتوميرزم
+
+139
+00:12:54,160 --> 00:12:59,700
+بمعنى أن هذا الـ H هتيجي على هذا الموقع و الـ bond
+
+140
+00:12:59,700 --> 00:13:06,330
+تبعها بيجي تعمل C double bond O لكن زي ما بتلاحظوا
+
+141
+00:13:06,330 --> 00:13:09,890
+هنا أن المركب اللي تكون هو الديهيد ولا كيتون في
+
+142
+00:13:09,890 --> 00:13:15,030
+هذه الحالة في هذه الحالة تكون عندي الديهيد في
+
+143
+00:13:15,030 --> 00:13:19,190
+حالة مكان الألكاين اللي عندي الألكاين طرفي طبعًا
+
+144
+00:13:19,190 --> 00:13:22,330
+الألكاين طرفي أو terminal alkyne بمعنى أنه في على
+
+145
+00:13:22,330 --> 00:13:27,610
+طرف hydrogen واضح عارفين ايش معنى terminal alkyne
+
+146
+00:13:30,270 --> 00:13:35,070
+طرفي آه فلما نقول احنا في terminal alkyne بمعنى
+
+147
+00:13:35,070 --> 00:13:40,770
+أنه الـ triple bond موجودة على طرف الجزء في alkynes
+
+148
+00:13:40,770 --> 00:13:45,290
+ثانية الـ triple bond بتكون بنص الجزء و بالمناسبة
+
+149
+00:13:45,290 --> 00:13:49,010
+في الـ alkyne إذا الـ triple bond كانت بنص الجزء
+
+150
+00:13:49,010 --> 00:13:52,210
+خلاص ما فيش احتمال يكون عليها هيدروجين نهائيًا يعني
+
+151
+00:13:52,210 --> 00:13:57,290
+ما بيكونش على الـ triple bond هيدروجين إلا إذا كانت
+
+152
+00:13:57,600 --> 00:14:03,940
+على طرف الجزء إلا إذا كانت Terminal إذا
+
+153
+00:14:03,940 --> 00:14:07,440
+كانت Terminal بدي أضيف Anti Markovnikov's addition
+
+154
+00:14:07,440 --> 00:14:13,280
+طب لو كانت بوسط الجزئية الـ triple bond حيكون عندي
+
+155
+00:14:13,280 --> 00:14:16,320
+خليط من التفاعلات يعني ممكن أضيف Markovnikov's و
+
+156
+00:14:16,320 --> 00:14:19,220
+Anti Markovnikov's مبطل واضح Markovnikov's
+
+157
+00:14:19,220 --> 00:14:24,460
+addition فممكن تتم الإضافة باتجاهين واضح؟ خلينا
+
+158
+00:14:24,460 --> 00:14:28,400
+على الوضع البسيط أنه يكون عندي terminal alkyne بدي
+
+159
+00:14:28,400 --> 00:14:32,080
+أضيف عليه ماء يا بدي أحط الـ H و الـ OH  Markovnikov's addition 
+او بدي أحط الـ H و الـ OH
+
+160
+00:14:32,080 --> 00:14:35,900
+Anti Markovnikov's addition واضح؟ الآن بغض
+
+161
+00:14:42,080 --> 00:14:46,500
+النظر إذا تكون مركب للمركب اللي هيتكون ايش هيكون؟
+
+162
+00:14:46,500 --> 00:14:53,100
+enol  هيتحول أيضًا إلى الـ keto form اللي هو
+
+163
+00:14:53,100 --> 00:14:56,260
+الـ C=O المقصود، بغض النظر كونه الديهيد أو الكيتو
+
+164
+00:14:56,260 --> 00:15:01,200
+المهم أنه يتحول إلى C=O،
+
+165
+00:15:01,200 --> 00:15:06,180
+يتحول إلى C=O، إذًا ظاهرة التوتوميرزم في كل
+
+166
+00:15:06,180 --> 00:15:13,130
+الأحوال بتصير طبعًا هذا الكلام هو اللي ممكن تسأله
+
+167
+00:15:13,130 --> 00:15:17,410
+عنه أنتم يعني تخيلوا أن أنا لو جبتلكم مثلًا أي الـ
+
+168
+00:15:17,410 --> 00:15:21,930
+alkyne زي هذا و طلبت منكوا في النهاية أنكوا تحضرولي
+
+169
+00:15:21,930 --> 00:15:27,910
+مركب فيه C=O bond هنا بنفع
+
+170
+00:15:27,910 --> 00:15:33,150
+بدكوا تضيفوا الماء في وجود Hg2 plus و بتعمل
+
+171
+00:15:33,150 --> 00:15:37,430
+توتوميرزم و لو طلبت منكوا تحطولي الـ C=O bond هنا
+
+172
+00:15:38,450 --> 00:15:40,710
+بتكون تضيفوا الماء بهذه الطريقة تطلعوا أنتم ايش
+
+173
+00:15:40,710 --> 00:15:46,810
+المحصلة النهائية الـ C=O bond هنا طب لو بدي هنا
+
+174
+00:15:46,810 --> 00:15:57,450
+بدي أستعمل الطريقة السابقة H3O Plus مع الزئبق إذا
+
+175
+00:15:57,450 --> 00:16:04,870
+أنا بإمكاني على طرفي الرابطة أن أحط C=O bond بضل أني
+
+176
+00:16:04,870 --> 00:16:09,970
+انتقل للـ
+
+201
+00:18:00,970 --> 00:18:05,090
+triple bond، إنه هننزل يا لـ double bond، يا لـ 
+
+202
+00:18:05,090 --> 00:18:09,900
+single bond، في كل الأحوال العملية reductionبكل 
+
+203
+00:18:09,900 --> 00:18:13,680
+الأحوال العملية عملية reduction عشانك العنوان
+
+204
+00:18:13,680 --> 00:18:19,540
+تبعكم reduction of alkynes ال reduction of alkynes
+
+205
+00:18:19,540 --> 00:18:27,740
+مع الهيدروجين حقيقة له تلت احتمالات و تلت شروط
+
+206
+00:18:27,740 --> 00:18:34,520
+تفاعل و تلت نواتج مختلفة ال reduction of alkynes
+
+207
+00:18:35,450 --> 00:18:41,010
+باستعمال الهيدروجين بتتم بثلاث طرق و بتقدر تلت طرق
+
+208
+00:18:41,010 --> 00:18:48,010
+إلى تلت نواتج مختلفة الطريقة الأولى إذا أنا بضيف
+
+209
+00:18:48,010 --> 00:18:52,610
+الهيدروجين في وجود metal catalyst زي البلاديوم أو
+
+210
+00:18:52,610 --> 00:18:57,630
+البلاتين أو النيكل طبعا البلاديوم دائما بيكون
+
+211
+00:18:57,630 --> 00:19:02,930
+مخلوط بكاربون بيسموه بلاديوم كاربون كاربون فحم ناعم
+
+212
+00:19:02,930 --> 00:19:08,680
+جدا واضح بس الأساس في الـ catalyst اللي هو إيش الـ
+
+213
+00:19:08,680 --> 00:19:13,080
+بالاديوم فإضافة الـ hydrogen مع الـ بالاديوم و عشان
+
+214
+00:19:13,080 --> 00:19:16,080
+أنا مش كاتبينهم لو أجيكوا في الامتحان مع الـ nickel
+
+215
+00:19:16,080 --> 00:19:22,780
+أو مع الـ platinum مع أي metal من هدول بضيف مرتين
+
+216
+00:19:22,780 --> 00:19:27,100
+وبيعطيني الـ alkene بحصلش على الـ double bond بنتقل
+
+217
+00:19:27,100 --> 00:19:32,620
+مباشرة من الـ triple bond إلى الـ single bond إذا
+
+218
+00:19:32,620 --> 00:19:37,760
+هيدروجين مع بلاديوم أو نيكل أو بلاتين بيحوللي
+
+219
+00:19:37,760 --> 00:19:43,890
+الـ alkene إلى الكين .. واضح؟ يعني لو جيبنالكم سؤال
+
+220
+00:19:43,890 --> 00:19:47,150
+صح و غلط مرات طلاب بيخموا لما نجيب الأسئلة نقولوا
+
+221
+00:19:47,150 --> 00:19:52,190
+reduction of alkanes using hydrogen palladium
+
+222
+00:19:52,190 --> 00:20:00,110
+produces alkenes غلط it produces alkenes single
+
+223
+00:20:00,110 --> 00:20:06,110
+bonds .. واضح؟ هذا اللي هو التفاعل الأول الآن
+
+224
+00:20:06,110 --> 00:20:13,050
+التفاعل الثاني .. التفاعل الثاني ممكن إحنا نضيف بس
+
+225
+00:20:13,050 --> 00:20:17,670
+جزء واحد هيدروجين مش اتنين في الحالة الأولى كم
+
+226
+00:20:17,670 --> 00:20:22,550
+هيدروجين ضفنا؟ جزئين ممكن نضيف جزء واحد هيدروجين
+
+227
+00:20:22,550 --> 00:20:26,810
+الآن انتبهوا أنا بتيجينا نقطة فنية كتير مهمة لما
+
+228
+00:20:26,810 --> 00:20:32,170
+بدي أضيف جزء واحد هيدروجين هحول الـ triple bond إلى
+
+229
+00:20:32,170 --> 00:20:39,180
+double bond واضح؟ هحول الـ triple bond إلى double
+
+230
+00:20:39,180 --> 00:20:42,420
+bond .. الـ double bond فيها ظاهرة الـ cis و الـ
+
+231
+00:20:42,420 --> 00:20:51,460
+trans .. الـ alkanes مافيهم ظاهرة cis و trans .. فيش
+
+232
+00:20:51,460 --> 00:20:55,080
+فيهم ظاهرة الـ cis و الـ trans؟ واضح؟ ظاهرة الـ cis و
+
+233
+00:20:55,080 --> 00:20:59,060
+الـ trans مرتبطة بإيش؟ بالـ double bonds بالـ الـ
+
+234
+00:20:59,060 --> 00:21:02,440
+alkenes أو بالـ cyclic alkenes لما يكون عندي حلقات
+
+235
+00:21:02,440 --> 00:21:08,340
+الآن طالما أنا بتحول الألكاين هذا إلى الـ keen إذا
+
+236
+00:21:08,340 --> 00:21:12,480
+اللي بيصير عندي تساؤل هل يا ترى الأ الـ keen اللي
+
+237
+00:21:12,480 --> 00:21:17,840
+بيطلع عندي هيكون بالـ cis form ولا بالـ trans form
+
+238
+00:21:17,840 --> 00:21:25,400
+واضحة الفكرة؟ الآن حسب نوع الطريقة المستخدمة ممكن
+
+239
+00:21:25,400 --> 00:21:30,500
+أطلع نواتج بحيث إن الهيدروجين يضيف من جهة واحدة
+
+240
+00:21:30,500 --> 00:21:34,980
+وينتج عند الـ cis compound أو الهيدروجين يضيف من
+
+241
+00:21:34,980 --> 00:21:39,600
+جهتين متعاكستين وينتج عند الـ trans compound إذا
+
+242
+00:21:39,600 --> 00:21:45,260
+الاحتمالين ممكنين لكن بتحكم فيهم من خلال إيش؟ طريقة
+
+243
+00:21:45,260 --> 00:21:52,000
+التفاعل إذا ضيفت الهيدروجين في وجود كتاليست بنسميه
+
+244
+00:21:52,000 --> 00:21:58,460
+لندلارز كتاليست لندلارز كتاليست
+
+245
+00:21:58,460 --> 00:22:02,680
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+246
+00:22:02,680 --> 00:22:02,880
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+247
+00:22:02,880 --> 00:22:05,140
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+248
+00:22:05,140 --> 00:22:07,460
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+249
+00:22:07,460 --> 00:22:08,360
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+250
+00:22:08,360 --> 00:22:11,520
+لندلارز كتاليست لندلارز كتاليست لندلار
+
+251
+00:22:13,220 --> 00:22:18,140
+هذا المركب اللي هو الـ diphenylacetylene هذا لو
+
+252
+00:22:18,140 --> 00:22:21,040
+بدنا نسميه diphenylacetylene هاي أسيتيلين فيه
+
+253
+00:22:21,040 --> 00:22:26,300
+كربونتين عليه فنل و فنل، مظبوط ولا لأ؟ بهذا
+
+254
+00:22:26,300 --> 00:22:28,940
+المركب الـ diphenylacetylene، بزام الهيدروجينز
+
+255
+00:22:28,940 --> 00:22:34,500
+أجوا من جهة واحدة، إذا الـ two phenyl groups
+
+256
+00:22:34,500 --> 00:22:40,680
+هيروحواعلى الجهة الثانية المعاكسة واضح؟ هينتج عنده
+
+257
+00:22:40,680 --> 00:22:44,960
+الـ cis compound
+
+258
+00:22:44,960 --> 00:22:54,040
+شايفينه هذا؟ الآن إيش هو الـ Lindlar catalyst؟
+
+259
+00:23:03,700 --> 00:23:07,780
+ماذا يعني لندلار كتاليست؟ لندلار كتاليست هو عبارة
+
+260
+00:23:07,780 --> 00:23:14,200
+عن خليط موجود فيه 5% بالاديوم مع كالسيوم كربونيت
+
+261
+00:23:14,200 --> 00:23:19,600
+مع ليد أسيتيت مع كينولين، كل هذه الخلطة بتنبأ
+
+262
+00:23:19,600 --> 00:23:24,460
+بيشتريها الواحد، إيش اسمها؟ لندلار كتاليست، واضح؟
+
+263
+00:23:25,500 --> 00:23:30,200
+في بلاديوم لكن مع أشياء ثانية فالآن إحنا بنقدر
+
+264
+00:23:30,200 --> 00:23:36,580
+نقول إن الـ addition of hydrogen to alkynes using
+
+265
+00:23:36,580 --> 00:23:44,280
+Lindler's catalyst is a sin addition صح واضح؟
+
+266
+00:23:44,280 --> 00:23:49,700
+فالاضافة باستعمال Lindler's catalyst is a sin
+
+267
+00:23:49,700 --> 00:23:55,120
+addition بمعنى إضافة من جهة واحدة و في مرات كتيرة
+
+268
+00:23:55,120 --> 00:24:00,260
+بتطلعلي الـ cis compound الآن هل يا ترى بإمكاننا
+
+269
+00:24:00,260 --> 00:24:06,960
+أن نخلي الـ hydrogen يضيف من جهتين متعاكستين ممكن
+
+270
+00:24:06,960 --> 00:24:13,900
+إذا غيرنا الـ reagent إذا ضفنا الهيدروجين من خلال
+
+271
+00:24:13,900 --> 00:24:19,200
+إضافة معدل الليثيوم و الـ liquid ammonia لاحظوا
+
+272
+00:24:19,200 --> 00:24:22,740
+liquid ammonia مش solution يعني غاز الأمونيا بس
+
+273
+00:24:22,740 --> 00:24:28,160
+مبردينه بيصير إيش؟ سائل بضيف للهيدروجين من جهتين
+
+274
+00:24:28,160 --> 00:24:33,020
+متعاكستين بمعنى آخر بيعمل Anti-addition لاحظوا هنا
+
+275
+00:24:33,020 --> 00:24:38,690
+الهيدروجين كيف بيضيف؟ فلو كان عندي هذا المركب .. لو
+
+276
+00:24:38,690 --> 00:24:42,290
+كان عندي هذا المركب اللي هو two butane one two
+
+277
+00:24:42,290 --> 00:24:47,370
+three four هذا عبارة عن two butane أو أي واحدة كان
+
+278
+00:24:47,370 --> 00:24:51,190
+ممكن بطريقة السابقة تتخيل إن هو dimethylacetylene
+
+279
+00:24:51,190 --> 00:24:55,550
+مظبوط ولا لأ؟ اه فلما تضيف hydrogen من هنا و
+
+280
+00:24:55,550 --> 00:24:59,990
+hydrogen من هنا يضيفه بطريقتين متعاكستين شو هيطلع
+
+281
+00:24:59,990 --> 00:25:06,060
+له؟ لـ trans compound أو لـ trans two butane واضح؟ إذا
+
+282
+00:25:06,060 --> 00:25:11,940
+لما نقول إحنا إنه هذا بندوّب معدن الليثيوم في الـ
+
+283
+00:25:11,940 --> 00:25:15,740
+liquid ammonia و بنضيفه على الـ alkyne بده يعطينا
+
+284
+00:25:15,740 --> 00:25:21,560
+أي ناتج لـ Trans أو الـ Anti-addition product و بناء
+
+285
+00:25:21,560 --> 00:25:25,240
+على ذلك بإمكانكم أن تتخيلوا أن إحنا ممكن نيجي
+
+286
+00:25:25,240 --> 00:25:32,960
+نسألكم نجيبلكم الـ alkyne و نحطلكم تلت أسهم و على كل
+
+287
+00:25:32,960 --> 00:25:42,240
+سهم reagent و كل سهم بيطلع إيش؟ و كل سهم بيطلع نتيجة
+
+288
+00:25:42,240 --> 00:25:46,360
+زي هذه الحالة مثلا، هاي بعد صفحتين بتلاحظوا إنّه
+
+289
+00:25:46,360 --> 00:25:50,340
+اتخيلوا إن هذا جاي سؤال في الامتحان دايفين
+
+290
+00:25:50,340 --> 00:25:55,620
+الـ acetylene الآن لو قلت أنا مع hydrogen بالاديوم
+
+291
+00:25:55,620 --> 00:26:01,840
+كاربون شو هيعطيني؟ الـ alkyne will be converted to
+
+292
+00:26:01,840 --> 00:26:07,780
+alkane إذا إضافتين هيدروجين طيب هنا مافيش cis و
+
+293
+00:26:07,780 --> 00:26:12,360
+trans طبعا بس هيك الرسمة لإنه single bonds الـ cis
+
+294
+00:26:12,360 --> 00:26:15,520
+و الـ trans وين موجودة كظاهرة حوالينا؟ اه طبعا الـ
+
+295
+00:26:15,520 --> 00:26:19,040
+bonds الآن لو ضفنا هيدروجين في وجود الـ Lindlar
+
+296
+00:26:19,040 --> 00:26:19,640
+catalyst
+
+297
+00:26:32,660 --> 00:26:39,140
+دائما هذه المقارنات اهتموا فيها و هذه المقارنات
+
+298
+00:26:39,140 --> 00:26:43,580
+بالمناسبة يعني تعتبر جيدة جدا في الـ organic الـ
+
+299
+00:26:43,580 --> 00:26:46,840
+chemistry يعني أي واحدة بدأت تدرس تفاعل فيه مقارنة
+
+300
+00:26:46,840 --> 00:26:50,060
+ما تحفظش تفاعل واحد تحفظ أكثر من تفاعل شفته قبل
+
+301
+00:26:50,060 --> 00:26:58,150
+شوية إضافة الماء كانت على alkynes بطريقتين .. هيك
+
+302
+00:26:58,150 --> 00:27:01,930
+افهموا الكلام إذا ذكروا إضافة الماء مثلا على الـ
+
+303
+00:27:01,930 --> 00:27:05,950
+Alkynes لما أخدناها .. أخدناها بكم طريقة؟ بتلات
+
+304
+00:27:05,950 --> 00:27:10,270
+طرق و كل طريقة تؤدي إلى ناتج بمعنى أنا بإمكاني
+
+305
+00:27:10,270 --> 00:27:13,910
+أجيبلكوا Alkynes و أحطلكوا إضافة الماء في وجود
+
+306
+00:27:13,910 --> 00:27:18,490
+الحامض .. بتكونوا تقولوا؟ ماركوفنيكوفز Addition مع
+
+307
+00:27:18,490 --> 00:27:21,850
+احتمال الـ rearrangement إضافة الماء في وجود الـ
+
+308
+00:27:21,850 --> 00:27:26,230
+mercury كأسييتات ماركوفنيكوفز Addition بس مافيش
+
+309
+00:27:26,230 --> 00:27:30,730
+rearrangement إضافة الماء في وجود البورين
+
+310
+00:27:30,730 --> 00:27:33,910
+Hydroboration Oxidation Anti Markovnikov's
+
+311
+00:27:33,910 --> 00:27:37,810
+addition نفس الشيء لما أخدتوا في الـ alkenes مثلا HPR
+
+312
+00:27:37,810 --> 00:27:42,250
+في وجود الحامض HPR في وجود البروكسايل هنا مثلا
+
+313
+00:27:42,250 --> 00:27:47,750
+إضافة الهيدروجين مرة الـ alkane مرة cis الـ alkane مرة
+
+314
+00:27:47,750 --> 00:27:53,710
+trans الـ alkane واضح فدائما حاولوا تحفظوا هذه
+
+315
+00:27:53,710 --> 00:27:55,270
+المقارنات و تنتبهوها
+
+316
+00:28:00,970 --> 00:28:06,910
+آخر تفاعل .. آخر تفاعل بناخده في هذا chapter ..
+
+317
+00:28:06,910 --> 00:28:09,590
+chapter ثلاثة من أكبر الفصول اللي معنا إن شاء الله
+
+318
+00:28:09,590 --> 00:28:15,230
+بنخلصه الآن اللي هو use of alkyne anion in a
+
+319
+00:28:15,230 --> 00:28:20,170
+substitution reaction ممكن نصيغه بطريقة أو بجملة
+
+320
+00:28:20,170 --> 00:28:27,540
+مختلفة تماما، نسميه acidity of alkynes حمضية
+
+321
+00:28:27,540 --> 00:28:31,260
+الـ alkynes طبعا لو كنا بدنا نكون دقيقين بدنا نقول
+
+322
+00:28:31,260 --> 00:28:43,560
+acidity of terminal alkynes terminal alkynes طبعا
+
+323
+00:28:43,560 --> 00:28:46,960
+لما نيجي نقول إحنا الحامضية شو جابنا على الحامضية
+
+324
+00:28:46,960 --> 00:28:53,840
+في الـ alkynes اتذكروا أنتو الحامض حسب تعريف Lewis
+
+325
+00:28:57,090 --> 00:29:02,950
+هيدروجين دونار أو بروتون دونار مظبوط ولا لأ الحامض
+
+326
+00:29:02,950 --> 00:29:08,790
+حسب تعريف Lewis هو اللي بيعطينا إيش بروتون فأي شيء
+
+327
+00:29:08,790 --> 00:29:14,170
+بده يفقد H بلس بده أعمله إنه حامض الحامض الآن في
+
+328
+00:29:14,170 --> 00:29:19,950
+الـ alkynes مين اللي فيهم هيدروجين الـ Terminal
+
+329
+00:29:19,950 --> 00:29:25,410
+Alkynes لما تكون لـ Triple bond طرفية ملاحظين يعني
+
+330
+00:29:25,410 --> 00:29:28,870
+الـ Alkynes إذا ما كانش Terminal مافيش هذا الـ
+
+331
+00:29:28,870 --> 00:29:33,310
+section هذا الـ section متعلق بإيش الـ Terminal
+
+332
+00:29:33,310 --> 00:29:38,310
+Alkynes اللي فيهم هيدروجين الآن هذه الهيدروجين اللي
+
+333
+00:29:38,310 --> 00:29:41,930
+جنب الـ Alkynes زي الهيدروجين اللي على الـ OH في
+
+334
+00:29:41,930 --> 00:29:46,510
+الحامض إذا بنفعلها مع قاعدة قوية فإنها تفقد على
+
+335
+00:29:46,510 --> 00:29:51,260
+شكل البروتون و بالتالي الـ alkyne هنا can be
+
+336
+00:29:51,260 --> 00:29:57,480
+considered as an acid ممكن نعتبره حامض ممكن نعتبره
+
+337
+00:29:57,480 --> 00:30:04,740
+acid أو حامض فمعنى حامض إنه يفقد البروتون بدون
+
+338
+00:30:04,740 --> 00:30:11,100
+الالكترونات بس فاقد البروتون عشان هيك هذا الالكاين
+
+339
+00:30:11,100 --> 00:30:14,860
+لو أخدنا مثلا هذا الالكاين و فعلنا مع very strong
+
+340
+00:30:14,860 --> 00:30:19,320
+base هذه الـ strong base اسمها Sodamide زي ما في
+
+341
+00:30:19,320 --> 00:30:22,760
+عندكم Sodium Hydroxide Sodium Hydroxide إيش صيغته
+
+342
+00:30:22,760 --> 00:30:30,720
+العامة NaOH هذه الـ base أقوى منه NaNH2 عبارة عن Na
+
+343
+00:30:32,290 --> 00:30:38,790
+و N H2- طبعا الـ base اللي فيها هي عبارة عن إيش الـ
+
+344
+00:30:38,790 --> 00:30:44,450
+N H2- زي في الـ sodium hydroxide N A O H minus مين
+
+345
+00:30:44,450 --> 00:30:48,810
+اللي بياخد الـ proton أثناء التفاعل الـ O H minus الـ
+
+346
+00:30:48,810 --> 00:30:52,450
+O H minus من الـ N A O H لما تاخد الـ proton و
+
+347
+00:30:52,450 --> 00:31:00,650
+بتتحول إلى الـ H2O الآن هنا نفس الفكرة NA NH2-
+
+348
+00:31:00,650 --> 00:31:06,030
+بالنتيجة تاخد البروتون من هنا شو بده تصير الـ NH3
+
+349
+00:31:06,030 --> 00:31:14,610
+أمونيا واضح فهذا إيش اسمه Sodamide
+
+350
+00:31:14,610 --> 00:31:20,430
+زي Sodium Hydroxide بس هذا بيكون stronger base
+
+351
+00:31:20,430 --> 00:31:21,410
+than
+
+352
+00:31:32,450 --> 00:31:35,730
+هذا الكلام لو أنتو بتتطلعوا على الجدول الدوري و
+
+353
+00:31:35,730 --> 00:31:38,890
+كيف بتزيد القاعدية لما يكون عندي الـ O هان أو الـ N
+
+354
+00:31:38,890 --> 00:31:43,490
+هان بهذا الشكل بتزيد القاعدية فكل اللي بيصير إن هو
+
+355
+00:31:43,490 --> 00:31:45,570
+الـ N H 2 minus هتاخد H
+
+356
+00:31:48,910 --> 00:31:58,390
+أيون سالب بيسموه الـ acetylide anion بشكل
+
+357
+00:31:58,390 --> 00:32:04,070
+عام طبعا بيسموه أيون سالب شو الـ أيون المرافق اللي
+
+358
+00:32:04,070 --> 00:32:06,150
+معاه هيكون الـ anion
+
+359
+00:32:12,370 --> 00:32:19,910
+الآن هذا الـ أيون السالب لو أجيت فعلته مع مركب مثلا
+
+360
+00:32:19,910 --> 00:32:24,010
+مثل الـ methyl iodide بيروح بهاجم على الكربون اللي
+
+361
+00:32:24,010 --> 00:32:29,370
+هال لأنها موجبة و بيطر دليوت هذا بعد ما عملت أنا
+
+362
+00:32:29,370 --> 00:32:35,330
+إيش بعد ما شيلت منه الـ H و خليته أيون سالب قوي
+
+363
+00:32:35,330 --> 00:32:39,570
+بيصير strong nucleophile هذا الـ strong nucleophile
+
+364
+00:32:39,570 --> 00:32:43,510
+ممكن ييجي يهجم على مركب زي الـ methyl iodide يطرد
+
+365
+00:32:43,510 --> 00:32:47,650
+منه الـ iodine minus و يحل محله عشانك العنوان تبعكوا
+
+366
+00:32:47,650 --> 00:32:52,690
+إيش كان substitution الـ substitution هي أي خطوة
+
+367
+00:32:52,690 --> 00:33:00,350
+الثانية إحنا الأساس عندنا اليوم إيش الـ Terminal
+
+368
+00:33:00,350 --> 00:33:08,830
+Alkynes are Acids معناه Acids إنهم بيفقدوه H
+
+369
+00:33:08,830 --> 00:33:12,750
+Plus لما بيفقدوه H Plus كوانولي أيون سالب الايون
+
+370
+00:33:12,750 --> 00:33:17,330
+السالب من طبيعته من تفاعله إنه بيحلم حال أيون
+
+371
+00:33:17,330 --> 00:33:22,840
+سالب ثاني واضح؟ مثل هذا التفاعل بس الشيء الأساسي
+
+401
+00:35:53,200 --> 00:35:55,700
+وهيدروجين بيروكسايد اللي سمناه Hydroboration
+
+402
+00:35:55,700 --> 00:36:00,080
+Oxidation هذا بده يضيف إيش؟ بدكم تعرفوا أنه بده
+
+403
+00:36:00,080 --> 00:36:05,500
+يضيف مية Anti Markovnikovs وبعدين تتحول إلى الألكين
+
+404
+00:36:05,500 --> 00:36:12,330
+بال bond بمعنى حيضيف ال H هنا وال O H هنا طب مكان
+
+405
+00:36:12,330 --> 00:36:16,130
+ال O H شو حصل عندي في النهاية C double bond هو إذا
+
+406
+00:36:16,130 --> 00:36:20,670
+أنا لما بدي النتيجة صار عندي هنا C double bond هو
+
+407
+00:36:20,670 --> 00:36:27,650
+واضح؟ فهذا إضافة Anti Markovnikov addition على طول
+
+408
+00:36:27,650 --> 00:36:33,510
+هتتخيلوا إن هنا ال H هنا ال O H ودائما هذا ناتج 
+
+409
+00:36:34,340 --> 00:36:37,640
+الـ Transient Product يعني أثناء التفاعل، بس هلّي
+
+410
+00:36:37,640 --> 00:36:42,160
+بنفصله؟ لأ، آه إيش اللي بنفصل؟ إن هذا تصير C
+
+411
+00:36:42,160 --> 00:36:49,200
+double bond O وهنا تصير CH2 ماشي الحاجة، الآن هذا 
+
+412
+00:36:49,200 --> 00:36:58,040
+الكائن بدنا نضيف عليه Lithium و NH3 Terminal
+
+413
+00:36:58,040 --> 00:37:01,540
+الكائن هدول إيش بيعملوا ال Lithium مع ال NH3؟
+
+414
+00:37:02,620 --> 00:37:06,420
+بيضيفوا هيدروجينز .. بضيفوا هيدروجينز .. بيضيفوهم
+
+415
+00:37:06,420 --> 00:37:10,640
+anti addition انتبهوا معه .. يمكن أنتم بتضلكم
+
+416
+00:37:10,640 --> 00:37:16,200
+مصرين وتقولوها خمس مرات أو ستة أو سبعة إنكم 
+
+417
+00:37:16,200 --> 00:37:21,560
+تقولوا trans وفي كل مرة بتسمعوني أنا إيش بقول؟ anti
+
+418
+00:37:22,600 --> 00:37:28,320
+الآن إيش ال .. الدقة أو الفرق في الكلام؟ في فرق
+
+419
+00:37:28,320 --> 00:37:33,940
+بين شغلتين، شغلة بنسميها mode of addition بمعنى
+
+420
+00:37:33,940 --> 00:37:38,460
+طريقة التفاعل وشغلة بنسميها ال product of
+
+421
+00:37:38,460 --> 00:37:43,480
+addition، ناتج التفاعل الآن ال mode of addition إن
+
+422
+00:37:43,480 --> 00:37:48,380
+ال hydrogen من هنا ومن هنا بيجوا عكس بعض هذا كلام
+
+423
+00:37:48,380 --> 00:37:53,380
+مافيش فيه خلاف إذا كيف بتتم ال addition؟ Anti الآن
+
+424
+00:37:53,380 --> 00:37:58,460
+الناتج بيعتمد إيش أساسا عندي؟ أنا Substituent
+
+425
+00:37:58,460 --> 00:38:04,340
+بالتالي دائما وأبدا طريقة الإضافة جايين متعاكسات
+
+426
+00:38:04,340 --> 00:38:10,560
+Anti addition لكن هل يا ترى لازم يطلع cis و
+
+427
+00:38:10,560 --> 00:38:14,760
+trans؟ هذا بيعتمد إيش في عندي substitutes يعني هنا
+
+428
+00:38:14,760 --> 00:38:18,740
+لما اجوا إضافة واحدة من فوق واحدة من تحت هذه
+
+429
+00:38:18,740 --> 00:38:23,620
+الكربون اللي كان عليها H شو صار عليها؟ two
+
+430
+00:38:23,620 --> 00:38:29,600
+hydrogens بحيث إحدى الذرتين عليها إحدى ذرتين
+
+431
+00:38:29,600 --> 00:38:32,560
+الكربون اللي هو طرفين ال double bond عليها two
+
+432
+00:38:32,560 --> 00:38:39,150
+hydrogens موجودة كل ظاهرة ال cis وال trans؟ لأ شرط
+
+433
+00:38:39,150 --> 00:38:42,850
+.. شرط ظاهرة الـ cis trans .. شرط ظاهرة الـ
+
+434
+00:38:42,850 --> 00:38:46,970
+cis trans عشان تكون موجودة إنه على طرفين ال
+
+435
+00:38:46,970 --> 00:38:50,130
+double bond يكون هنا مجموعتين مختلفتين وهنا
+
+436
+00:38:50,130 --> 00:38:56,850
+مجموعتين مختلفتين فأنا هنا صح عملت anti addition
+
+437
+00:38:56,850 --> 00:39:00,010
+لكن بعد ما عملت ال anti addition صار هذه عليها
+
+438
+00:39:00,010 --> 00:39:03,230
+two hydrogens ما فيش كل ظاهرة ال cis trans
+
+439
+00:39:04,390 --> 00:39:09,490
+وعشانكم أنا بقول إن ال mode of addition دائما anti
+
+440
+00:39:09,490 --> 00:39:12,870
+addition مش مختلف معكم فيه لكن يا ترى هل هيطلع
+
+441
+00:39:12,870 --> 00:39:18,610
+عندي cis أو trans؟ هذا بيعتمد إيش موجود أصلا على
+
+442
+00:39:18,610 --> 00:39:23,750
+الجزء يعني مثلا انبسط عليكم الموضوع كثير انبسط
+
+443
+00:39:23,750 --> 00:39:28,330
+عليكم الموضوع كثير جدا لو احنا كنا جايبين لكم
+
+444
+00:39:28,330 --> 00:39:29,310
+أسيتيلين
+
+445
+00:39:34,340 --> 00:39:38,040
+وأنا بدي أفتح مخكم كويس جدا عشان تفهموا هذا
+
+446
+00:39:38,040 --> 00:39:42,260
+الكلام إيش معنى mode of addition وإيش معنى
+
+447
+00:39:42,260 --> 00:39:47,800
+product of addition لو أنا جايب لكم أسيتيلين وهذا
+
+448
+00:39:47,800 --> 00:39:54,680
+الأسيتيلين قلت إنه بدي أضيف عليه هيدروجين بطريقتين
+
+449
+00:39:54,680 --> 00:40:02,460
+مختلفتين بدي أضيف عليه بطريقة .. ممكن هذا ..
+
+450
+00:40:04,520 --> 00:40:10,060
+بطريقة الـ Lithium مع الـ NH3 وممكن نضيف بطريقة
+
+451
+00:40:10,060 --> 00:40:17,460
+الـ Hydrogen مع الـ Lindler's catalyst ماشي
+
+452
+00:40:17,460 --> 00:40:23,060
+الحالتين؟ الآن من ناحية المبدأ ك mode of addition
+
+453
+00:40:23,060 --> 00:40:27,740
+كطريقة إضافة الـ Hydrogen مع الـ Lindler's
+
+454
+00:40:27,740 --> 00:40:32,080
+catalyst كيف بيضيفوه؟
+
+455
+00:40:34,520 --> 00:40:40,060
+addition مظبوط ولا لأ؟ طيب إضافة الهيدروجين من
+
+456
+00:40:40,060 --> 00:40:46,100
+خلال الليثيام والليكود أمونيا Anti-addition في
+
+457
+00:40:46,100 --> 00:40:50,520
+خلاف في هالكلام؟ طيب خلينا نرسم النتيجة لو حطينا C
+
+458
+00:40:50,520 --> 00:40:57,260
+double bond C وحطينا هنا H وحطينا هنا H وحطينا
+
+459
+00:40:57,260 --> 00:41:02,600
+اللي ضفناهم باللون الأحمر بهذا الشكل إيش طلع عندي؟
+
+460
+00:41:05,070 --> 00:41:08,830
+إيثيلين ما فيش فيه cis و trans الإيثيلين هل ال mode
+
+461
+00:41:08,830 --> 00:41:14,750
+of addition هل هذول ضافوا من جهة واحدة؟ أكيد ضافوا
+
+462
+00:41:14,750 --> 00:41:19,010
+من جهة واحدة لكن هل يا ترى الناتج نفسه في
+
+463
+00:41:19,010 --> 00:41:22,770
+الإيثيلين في ال cis وال trans؟ لأ فالموضوع of
+
+464
+00:41:22,770 --> 00:41:26,410
+addition is in addition لكن الناتج ما فيش فيه من
+
+465
+00:41:26,410 --> 00:41:29,850
+الأساس ظاهرة ال cis وال trans طيب الآن لو جينا و
+
+466
+00:41:29,850 --> 00:41:33,910
+قلنا هانا بدنا نحط الناتج هيئتش صارت لتحت وهيئتش
+
+467
+00:41:33,910 --> 00:41:41,210
+لفوق اللي ضفناهم كيف ضافوا؟ Anti addition إيش
+
+468
+00:41:41,210 --> 00:41:43,430
+طلع لي؟ إيثيلين
+
+469
+00:41:47,930 --> 00:41:53,890
+ملاحظين؟ إذا لو أنا بدي أقول لكم the mode of
+
+470
+00:41:53,890 --> 00:41:59,550
+addition of hydrogen to acetylene using hydrogen
+
+471
+00:41:59,550 --> 00:42:05,770
+and Lindlar catalyst and lithium ammonia is the
+
+472
+00:42:05,770 --> 00:42:13,350
+same غلط ال mode of addition طريقة الإضافة مرة ضاف 
+
+473
+00:42:13,350 --> 00:42:15,990
+من جهة واحدة مرة ضاف من جهتين هذا ال mode of
+
+474
+00:42:15,990 --> 00:42:21,070
+addition ما بيختلفش لكن the product of addition نفس
+
+475
+00:42:21,070 --> 00:42:24,070
+الأشياء لأن في الأساس ما فيش انتظار cis ولا trans
+
+476
+00:42:24,070 --> 00:42:29,590
+عشانكم أنا دائما بفضل إن إيش أقول قدامكم إن طريقة
+
+477
+00:42:29,590 --> 00:42:35,250
+الإضافة من جهة واحدة أو من جهتين متعاكستين الآن
+
+478
+00:42:35,250 --> 00:42:39,990
+الناتج بيكون فيه cis بيكون فيه trans هذا بيعتمد على
+
+479
+00:42:39,990 --> 00:42:42,810
+إيش المركب اللي عنده إيش ال substituents اللي 
+
+480
+00:42:42,810 --> 00:42:49,010
+موجودة واضحة الفكرة بمعنى لو أنا كان عندي مثل ومثل
+
+481
+00:42:52,660 --> 00:42:55,740
+لأ طبعا .. ما هو .. بدك تكون مراجعة .. احنا قلنا
+
+482
+00:42:55,740 --> 00:43:00,880
+الـ cis وال trans شرطها إن كل carbon من طرفين ال
+
+483
+00:43:00,880 --> 00:43:03,700
+double bond يكون عليها مجموعتين مختلفتين .. الآن
+
+484
+00:43:03,700 --> 00:43:08,180
+هنا من الأساس ما فيش شيء .. كله نفس الشيء .. لكن لو
+
+485
+00:43:08,180 --> 00:43:14,520
+افترضتوا هنا مثل ومثل .. هيصير يخلي مثل ومثل و
+
+486
+00:43:14,520 --> 00:43:19,360
+H و H .. cis .. وهيصير يخلي مثل ومثل و H و
+
+487
+00:43:19,360 --> 00:43:24,320
+H .. الـ trans إذا في حالة ما كان عند ال
+
+488
+00:43:24,320 --> 00:43:28,920
+Acetylene ال mode of addition مختلف لكن الناتج
+
+489
+00:43:28,920 --> 00:43:33,520
+واحد في حالة ما كان عنده ال dye مثل ال Acetylene ولا
+
+490
+00:43:33,520 --> 00:43:36,480
+لا ال dye فين ال Acetylene ال mode of addition
+
+491
+00:43:36,480 --> 00:43:42,480
+برضه مختلف والناتج مختلف عشانكم احنا لما بدنا
+
+492
+00:43:42,480 --> 00:43:46,820
+نقول كمبدأ عام بنحكي عن الناتج ولا عن طريقة
+
+493
+00:43:46,820 --> 00:43:52,560
+الإضافة لما بدي أحكي قاعدة عامة أنا ما عنديش عارف
+
+494
+00:43:52,560 --> 00:43:58,400
+اللي بضيف عليه أساسا أسيتيلين ولا بروبين ولا
+
+495
+00:43:58,400 --> 00:44:05,960
+بيوتين في هذه الحالة أنا الأفضل إن أقول ال mode
+
+496
+00:44:05,960 --> 00:44:09,700
+of addition إن في كل الأحوال ال hydrogen في وجود
+
+497
+00:44:09,700 --> 00:44:17,640
+Lindlar catalyst proceeds through sin addition الآن
+
+498
+00:44:17,640 --> 00:44:21,840
+لو بدكم تأخذوها homework هتلاحظوا إن في حالة ال
+
+499
+00:44:21,840 --> 00:44:27,120
+acetylene الناتجين هيطلعوا نفس الشيء وفي حالة ال
+
+500
+00:44:27,120 --> 00:44:33,280
+bromine لما يكون عندكم ثلاث ذرات كربون الناتجين نفس
+
+501
+00:44:33,280 --> 00:44:40,100
+الشيء وفي حالة ال one butane الناتجين نفس الشيء
+
+502
+00:44:40,100 --> 00:44:46,270
+وفي حالة ال two butane الناتجين مختلفة .. الآن بصير
+
+503
+00:44:46,270 --> 00:44:50,610
+عندكم بيمشي اعملوا اتعبوا فيه فكروا بدكم تعملوا
+
+504
+00:44:50,610 --> 00:44:55,330
+إضافة الهيدروجين باستعمال الليثيام أمونيا وباستعمال
+
+505
+00:44:55,330 --> 00:45:01,270
+هيدروجين Lindlar's catalyst للأسيتيلين واضح
+
+506
+00:45:01,270 --> 00:45:05,850
+للبروبيلين للبروباين
+
+507
+00:45:05,850 --> 00:45:07,810
+للوان بيوتاين
+
+508
+00:45:09,230 --> 00:45:17,590
+للتو بيوتين كم مركب؟ أربعة أسيتيلين بروبين وان
+
+509
+00:45:17,590 --> 00:45:22,870
+بيوتين تو بيوتين اعملوها المرة اللي جاي بتسلموني
+
+510
+00:45:22,870 --> 00:45:27,430
+إياها هتلاحظوا بس بحالة واحدة الناتج بيختلف بس في
+
+511
+00:45:27,430 --> 00:45:30,970
+الأربع حالات لو بتستعملوا القلم الأحمر وأنتوا
+
+512
+00:45:30,970 --> 00:45:34,770
+بتحطوا الإضافة لازم هنا تعمله
+
+513
+00:45:37,140 --> 00:45:41,020
+Sin addition وهنا Anti addition فال mode of
+
+514
+00:45:41,020 --> 00:45:44,220
+addition في الأربع حالات لما تستعملون الجلم الأحمر
+
+515
+00:45:44,220 --> 00:45:48,880
+هيطلع نفس ال mode of addition بس الناتج بحالة
+
+516
+00:45:48,880 --> 00:45:52,560
+واحدة بيطلع في مرة ظاهرة تستثمر ل Trans ومرة لأ
+
+517
+00:45:52,560 --> 00:45:56,840
+عشان هيك احنا كنا نركز إننا دائما نقول لكم ال mode
+
+518
+00:45:56,840 --> 00:46:01,520
+of addition ال product بيعتمد على إيش؟ على ال
+
+519
+00:46:01,520 --> 00:46:02,940
+substituents اللي موجودة 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b8dc8d33eac0ca69c8b92abc66789fd59777c283
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_postprocess.srt
@@ -0,0 +1,2076 @@
+1
+00:00:06,600 --> 00:00:12,560
+اليوم بنختتم ان شاء الله الفصل التالت هتلاحظوا انه
+
+2
+00:00:12,560 --> 00:00:18,220
+هنتكلم على reactions of alkynes تفاعلات الalkynes
+
+3
+00:00:18,220 --> 00:00:23,080
+و هتلاحظوا انه ان شاء الله هتكون بسيطة بالذات بعد
+
+4
+00:00:23,080 --> 00:00:28,520
+ما انتوا اتفهمتوا كويس تفاعلات الalkynes الان
+
+5
+00:00:28,520 --> 00:00:33,020
+الalkynes اللي فيها double bond كانت تفاعلها
+
+6
+00:00:33,020 --> 00:00:39,870
+الأساسيالـ addition الإضافة الalkynes أيضًا
+
+7
+00:00:39,870 --> 00:00:45,630
+تفاعلها الأساسي ال addition لأنه فيها triple bond
+
+8
+00:00:45,630 --> 00:00:51,670
+تقريبًا ال reagents اللي شفناهم بيتفاعلوا مع
+
+9
+00:00:51,670 --> 00:00:56,740
+الalkynes نفسهم بدنا نشوفهم كيف بيتفاعلوامع ال ال
+
+10
+00:00:56,740 --> 00:01:02,500
+kinds فعلى سبيل المثال ممكن ناخد ال addition of hx
+
+11
+00:01:02,500 --> 00:01:11,200
+hx يعني hcl او hbr to all kinds اللي لاحظوا انه
+
+12
+00:01:11,200 --> 00:01:19,260
+تفاعل ال hx لل ال kind بيضيف مرتين لان ال kind في
+
+13
+00:01:19,260 --> 00:01:25,660
+كام bubble bond تنتين تنتينغير الـ Sigma bond
+
+14
+00:01:25,660 --> 00:01:29,960
+الأصلية في أندت انتن بايبولز فبتتم عملية الإضافة
+
+15
+00:01:29,960 --> 00:01:35,780
+مرتين الإضافة الأولى بتضيف فيها HCl لأن لما بتضيف
+
+16
+00:01:35,780 --> 00:01:40,240
+HCl على مثل هذا الألكاين كيف بنتوقع تضيف
+
+17
+00:01:40,240 --> 00:01:44,940
+Markovnikov ولا Anti Markovnikov addition؟ بتضيف
+
+18
+00:01:44,940 --> 00:01:49,430
+Markovnikov additionواضح فهي زي ما بتلاحظوا في
+
+19
+00:01:49,430 --> 00:01:54,650
+عندي H إجت على هذه الذرع و CL الان هذا اللي بتكون
+
+20
+00:01:54,650 --> 00:02:00,610
+لما يكون عندى كمية زائدة من ال HCL مباشرة بستمر
+
+21
+00:02:00,610 --> 00:02:04,570
+التفاعل مرة تانية و بضيف كمان H تانية و كمان CL
+
+22
+00:02:04,570 --> 00:02:10,890
+تانية إذا في المحصلة بيصير عندى إضافتين HCL و كل
+
+23
+00:02:10,890 --> 00:02:16,650
+إضافة منهمMarkovnikov's addition واضح كل إضافة
+
+24
+00:02:16,650 --> 00:02:19,810
+منهم Markovnikov's addition كأنه بيجي هنا ذرتين
+
+25
+00:02:19,810 --> 00:02:25,910
+هيدروجين و بيجي هنا ذرتين كلورين ومثلها أيضا ال
+
+26
+00:02:25,910 --> 00:02:33,770
+HPR فال HPR وHCL بيضيفوا على حسب Markovnikov's
+
+27
+00:02:33,770 --> 00:02:38,550
+addition لكن two successive additions يعني إضافتين
+
+28
+00:02:38,550 --> 00:02:41,310
+متواليتين واضح
+
+29
+00:02:45,200 --> 00:02:49,960
+النوع التاني اللي أخدنا إضافة ال halogens إذا
+
+30
+00:02:49,960 --> 00:02:56,120
+متذكرين PR2 و CL2 برضه بنفس المنطق تماما ال
+
+31
+00:02:56,120 --> 00:03:01,660
+halogens بتضيف مرتين طبعا إنتوا متذكرين إن الإضافة
+
+32
+00:03:01,660 --> 00:03:07,070
+في ال halogens كانت Anti additionلكن لما بضيف كمان
+
+33
+00:03:07,070 --> 00:03:12,590
+مرة خلاص بيصير عندى تلتين PR و تلتين PR فبرتفع ال
+
+34
+00:03:12,590 --> 00:03:16,350
+halogens لما نضيف أفضل اشي بيضيف حقيقة لبرومين
+
+35
+00:03:16,350 --> 00:03:22,790
+بيصير عندى two successive additions مرتين بيضيف
+
+36
+00:03:22,790 --> 00:03:28,740
+لبرومبتكون عند اللي هي ال tetra bromocompounds
+
+37
+00:03:28,740 --> 00:03:31,860
+يعني لو انا بدي اجي في الامتحان اقولك و الله هي
+
+38
+00:03:31,860 --> 00:03:35,480
+tetra bromocompounds how can you prepare this
+
+39
+00:03:35,480 --> 00:03:39,560
+compound بدي يكون جزء من تفكيرك و لو كان عند
+
+40
+00:03:39,560 --> 00:03:46,060
+triple bond اعملت عليها اضافة برومين مرتين اعملت
+
+41
+00:03:46,060 --> 00:03:49,040
+عليها اضافة برومين على مرتين واضح
+
+42
+00:03:53,800 --> 00:04:01,040
+الان بنيجي للميه الميه عادة بيضيفوها في وجود حامض
+
+43
+00:04:01,040 --> 00:04:07,860
+و ذئبق على الكائن حامض و ذئبق كتير الان اللي بدو
+
+44
+00:04:07,860 --> 00:04:13,740
+يصير عندى انه بيتم إضافة الميه لمرة واحدة حسب
+
+45
+00:04:13,740 --> 00:04:17,440
+قاعدة Markovnikov's addition بمعنى هنا بدو ييجي
+
+46
+00:04:17,440 --> 00:04:24,300
+عندى H وهنا بدو ييجي عنده OH هاي إضافة الميه Hهذا
+
+47
+00:04:24,300 --> 00:04:26,980
+عبارة عن markovnikov addition
+
+48
+00:04:29,750 --> 00:04:35,070
+المركب اللى اتكون عندى فيه من ناحية المجموعات
+
+49
+00:04:35,070 --> 00:04:41,310
+الوظيفية مجموعتين ووظيفيتين فيه ال الكين اللى هو
+
+50
+00:04:41,310 --> 00:04:46,190
+ال double bond وفيه ال alcohol اللى هو ال OH ال
+
+51
+00:04:46,190 --> 00:04:51,550
+alcohol وعشانك بيسموه in all ايش يعني in all؟ in
+
+52
+00:04:51,550 --> 00:04:57,040
+المجموعة الوظيفية تبع ال الكين و ال allالمجموعة
+
+53
+00:04:57,040 --> 00:04:59,800
+الوظيفية بتاعتين الالكوهول مش بيقول ميثانول
+
+54
+00:04:59,800 --> 00:05:04,720
+ايثانول واضح فهذا عبارة عن in all في المجمعتين
+
+55
+00:05:04,720 --> 00:05:09,780
+الوظيفيتين هدول، الآن هذا ال in all في الaliphatic
+
+56
+00:05:09,780 --> 00:05:15,100
+compounds بشكل عام مش ثابت، مابيضلوش زي ما هو،
+
+57
+00:05:15,100 --> 00:05:23,100
+بتغيرواضح؟ يعني مابنفعش ان انا احطه حتى كنتيجة هذا
+
+58
+00:05:23,100 --> 00:05:30,240
+غير ثابت ال enol طب ايش بيعمل؟ بيتحول الى صيغة
+
+59
+00:05:30,240 --> 00:05:34,460
+تانية فهذه الصيغة بتنتقل ال bond هذه هنا و ال H
+
+60
+00:05:34,460 --> 00:05:36,680
+بتيجي على ال carbon لاحظوا ايش اللي انا قاعد
+
+61
+00:05:36,680 --> 00:05:43,590
+بحكيه؟ شغلتين بدهم يتحركوا، بدها تتحركهيدروجين و
+
+62
+00:05:43,590 --> 00:05:49,050
+بدأت تتحرك رابطة إذا حركة الإلكترونات و حركة
+
+63
+00:05:49,050 --> 00:05:54,950
+البروتونات ال H فلما تلاحظوا أن هذا بدأت تتحرك هنا
+
+64
+00:05:54,950 --> 00:05:59,290
+ال double bond والهيدروجين بدأ تيجي هنا كم حركة
+
+65
+00:05:59,290 --> 00:06:04,220
+عند ال atomsو Charge او Electrons لما اتم هذه
+
+66
+00:06:04,220 --> 00:06:08,520
+الحركة ال C هذا بتصير C double bond O و ال CH2
+
+67
+00:06:08,520 --> 00:06:13,960
+بتصير CH3 الان اذا بتطلع على المجموعة الوظيفية
+
+68
+00:06:13,960 --> 00:06:20,180
+اللي موجودة هنا شو هي كيتون ال C double bond O ال
+
+69
+00:06:20,180 --> 00:06:24,900
+C double bond O هذه كيتون فبدل ما كان عندى مجمعتين
+
+70
+00:06:24,900 --> 00:06:29,810
+وظيفيتين جان بعض اللي هم ال in و ال allالانول
+
+71
+00:06:29,810 --> 00:06:35,490
+اتحول الى كيتو form هذه العملية عملية التحول
+
+72
+00:06:35,490 --> 00:06:37,850
+بيسموها tautomerism
+
+73
+00:06:47,240 --> 00:06:54,700
+هي عبارة عن عملية بتتم فيها حركتين حركة ال charge
+
+74
+00:06:54,700 --> 00:06:59,820
+و حركة ال hydrogen واضح اذا انا بتحرك اندي
+
+75
+00:06:59,820 --> 00:07:06,320
+electrons زائد ال protons ال hydrogen واضح بتفرق
+
+76
+00:07:06,320 --> 00:07:10,560
+عن ال resonance يعني لو بدأ أقولكوا بلغة بسيطة ايش
+
+77
+00:07:10,560 --> 00:07:16,470
+الفرق ما بين ال resonance و الtautomerismالـ
+
+78
+00:07:16,470 --> 00:07:25,390
+Resonance كانت بس الإلكترونات بتتحرك و
+
+79
+00:07:25,390 --> 00:07:29,850
+بيكون موجود عنده الشغل تاني يعني بيكون مرة بهذا
+
+80
+00:07:29,850 --> 00:07:32,370
+الشكل مرة بهذا الشكل مرة بهذا الشكل مرة بهذا الشكل
+
+81
+00:07:32,370 --> 00:07:39,520
+التاوتوميرزم مختلفة التاوتوميرزم عبارة عن حركةشحنة
+
+82
+00:07:39,520 --> 00:07:47,720
+أو إلكترونات وحركة hydrogen atoms لو كنتوا
+
+83
+00:07:47,720 --> 00:07:51,580
+بتتذكروا ال resonance اللي هو حركة إلكترونات كيف
+
+84
+00:07:51,580 --> 00:07:55,360
+السهم اللي كنا نعبر فيه عن ال resonance double
+
+85
+00:07:55,360 --> 00:08:01,600
+headed arrows بهذا الشكل التوتوميرزم عبارة عن
+
+86
+00:08:01,600 --> 00:08:06,720
+اتزان equilibriumيعني بيكون عندى موجود من هذا و
+
+87
+00:08:06,720 --> 00:08:10,220
+بيكون عندى موجود من هذا بنسب معينة في المحلول
+
+88
+00:08:10,220 --> 00:08:13,620
+فالtautomerism يعبر عن equilibrium والسهم تبع ال
+
+89
+00:08:13,620 --> 00:08:18,440
+equilibrium كيف بيكون؟ عشان ايه كذا السهم بيديكم
+
+90
+00:08:18,440 --> 00:08:24,920
+بتصلحوا بهذا الشكل سهم اتزان واضح؟فلو انا بدي اجي
+
+91
+00:08:24,920 --> 00:08:29,740
+اقولكوا مثلا ارسملكوا هذا السهم اقولكوا this arrow
+
+92
+00:08:29,740 --> 00:08:34,060
+is used to indicate automerism .. no it is used to
+
+93
+00:08:34,060 --> 00:08:38,540
+indicate resonance however the equilibrium arrow
+
+94
+00:08:38,540 --> 00:08:40,280
+or the double arrows
+
+95
+00:08:45,030 --> 00:08:51,710
+Tautomerism هي عبارة عن حركة شحنات وحركة بروتونات
+
+96
+00:08:51,710 --> 00:08:56,350
+بيستخدم لتوضيحها سهم الاتزان الكيميائي لأنه هي
+
+97
+00:08:56,350 --> 00:08:59,710
+عملية اتزان يعني لو قلنا توتو ميريزم is an
+
+98
+00:08:59,710 --> 00:09:03,990
+equilibrium processالجواب صح غالبا اللي بيصير
+
+99
+00:09:03,990 --> 00:09:09,130
+كالاتي انه بيكون ال keto هذا بنسبة أحيانا تفوق ال
+
+100
+00:09:09,130 --> 00:09:17,670
+99% و ال enol بنسبة أقل من 1% واضح؟ هذا ال
+
+101
+00:09:17,670 --> 00:09:22,390
+tautomerism شو احنا بنسميها حسب الأطراف تبعونها
+
+102
+00:09:22,390 --> 00:09:28,210
+keto enol tautomerism إذا احنا أمام شغلة جديدة
+
+103
+00:09:28,210 --> 00:09:37,140
+قاعدين بنتعلمها ketoEnol توتو ميريزم فإذا كان عند
+
+104
+00:09:37,140 --> 00:09:41,880
+ال Enol فإنه يتحول الى ال ketone و هذا الكلام وين
+
+105
+00:09:41,880 --> 00:09:47,600
+بيكون في ال aliphatic compounds يعني بال aliphatic
+
+106
+00:09:47,600 --> 00:09:53,520
+compounds كشكل كيميائي مش مقبول ولا مرغوب ان عمرك
+
+107
+00:09:53,520 --> 00:10:00,600
+تشوفه double bond جنبها OH يعني كأنه هذا بشكل عام
+
+108
+00:10:01,690 --> 00:10:05,470
+بغض نظر عن بعض الأمثلة الخاصة اللي مش موضوعنا بشكل
+
+109
+00:10:05,470 --> 00:10:09,890
+عام ممنوع وانتوا بتعملوا structures انكوا تحاولوا
+
+110
+00:10:09,890 --> 00:10:15,050
+تعملونا double bond جنبها OH في الالفاتيك كومباونز
+
+111
+00:10:15,050 --> 00:10:20,870
+الان العكس بيصير في ال aromatic compounds في ال
+
+112
+00:10:20,870 --> 00:10:24,710
+aromatic compounds زي البنزين وغيرها مسموحوا مفضل
+
+113
+00:10:24,710 --> 00:10:31,410
+انكوا تعملوا double bond جنبها OH إذا بتذكرواهذا
+
+114
+00:10:31,410 --> 00:10:38,890
+المُركّب إذا رسمناه اللي فيه OH إيش اسمه؟ فينول
+
+115
+00:10:38,890 --> 00:10:51,510
+لاحظوا من اسمه it is an enol هو فيه الفينل اللي هي
+
+116
+00:10:51,510 --> 00:10:58,690
+حلقة البنزين وهي en وهي all موجودين جانب بعضواضح؟
+
+117
+00:10:58,690 --> 00:11:04,190
+فوجود ال in و ال all جنب بعض في ال aromatic
+
+118
+00:11:04,190 --> 00:11:09,530
+compounds مسموح، بال phenols مسموح، وجود ال in و
+
+119
+00:11:09,530 --> 00:11:15,970
+ال all جنب بعض في ال aliphatic compounds لأ، واضح؟
+
+120
+00:11:15,970 --> 00:11:18,650
+وجود ال in و ال all جنب بعض في ال aliphatic
+
+121
+00:11:18,650 --> 00:11:24,850
+compounds مش مسموح نهائيا، واضح؟ ولا فيها مشكلة
+
+122
+00:11:29,260 --> 00:11:32,860
+زي ما بتلاحظوا ان الخطوة الأولى في الأساس لما ضاف
+
+123
+00:11:32,860 --> 00:11:36,360
+ال H و ال OH قبل التوتوماريزم كانت حسب قاعدة
+
+124
+00:11:36,360 --> 00:11:39,000
+Markovnikov's addition ولا Anti Markovnikov's
+
+125
+00:11:39,000 --> 00:11:42,660
+addition Markovnikov's addition هذا في حالة انه
+
+126
+00:11:42,660 --> 00:11:47,640
+ضفنا H3O plus في وجود الزبق
+
+127
+00:11:49,610 --> 00:11:56,610
+ممكن تكون إضافة الميه في الخطوة الأولى و يتبعها
+
+128
+00:11:56,610 --> 00:11:58,070
+توتوماريزم
+
+129
+00:12:08,170 --> 00:12:11,970
+بهذا الشكل لو كان عندى بهذا الشكل الكاين و اجى
+
+130
+00:12:11,970 --> 00:12:16,430
+اضفة ال borane بال THF في الخطوة الاولى H2O2 و H-
+
+131
+00:12:16,430 --> 00:12:22,610
+متذاكرين هذه كانت شروط ايش اضافة الماء عكس قاعدة
+
+132
+00:12:22,610 --> 00:12:27,250
+Markovnikov Anti Markovnikov's addition فزى ما
+
+133
+00:12:27,250 --> 00:12:33,190
+بتلاحظوا زى ما بتلاحظوا ان هنا بتيجى ال H على هذا
+
+134
+00:12:33,190 --> 00:12:38,160
+الطرفوال OH على هذا الطرف هل هذا Markovnikov's و
+
+135
+00:12:38,160 --> 00:12:40,520
+لا Anti Markovnikov's Addition هذا Anti
+
+136
+00:12:40,520 --> 00:12:43,140
+Markovnikov's Addition ال H مايجتش على الكربون
+
+137
+00:12:43,140 --> 00:12:48,040
+اللي حاملة هيدروجين اجت بالعكس و ال OH اجت بهذا
+
+138
+00:12:48,040 --> 00:12:54,160
+الشكل طبعا هنا برضه نفس الاشي بيصير عند توتوميرزم
+
+139
+00:12:54,160 --> 00:12:59,700
+بمعنى ان هذا ال H هتيجي على هذا الموقع و ال bond
+
+140
+00:12:59,700 --> 00:13:06,330
+تبعتها بيجيتعمل C double bond O لكن زي ما بتلاحظوا
+
+141
+00:13:06,330 --> 00:13:09,890
+هنا ان المركب اللي اتكون هو الديهيد ولا كيتون في
+
+142
+00:13:09,890 --> 00:13:15,030
+هذه الحالة في هذه الحالة اتكون عندى الديهيد في
+
+143
+00:13:15,030 --> 00:13:19,190
+حالة مكان ال الكاين اللى عندى الكاين طرفى طبعا
+
+144
+00:13:19,190 --> 00:13:22,330
+الكاين طرفى او terminal الكاين بمعنى انه في على
+
+145
+00:13:22,330 --> 00:13:27,610
+طرفه hydrogen واضح عارفين ايش معنى terminal الكاين
+
+146
+00:13:30,270 --> 00:13:35,070
+طرف اه فلما نقول احنا فينا terminal alkyne بمعنى
+
+147
+00:13:35,070 --> 00:13:40,770
+انه ال triple bond موجودة على طرف الجزء في alkynes
+
+148
+00:13:40,770 --> 00:13:45,290
+تانية ال triple bond بتكون بنص الجزء و بالمناسبة
+
+149
+00:13:45,290 --> 00:13:49,010
+في ال alkyne اذا ال triple bond كانت بنص الجزء
+
+150
+00:13:49,010 --> 00:13:52,210
+خلاص مافيش احتمال يكون عليها هيدروجين نهائيا يعني
+
+151
+00:13:52,210 --> 00:13:57,290
+مابيكونش على ال triple bond هيدروجين الا اذا كانت
+
+152
+00:13:57,600 --> 00:14:03,940
+على طرف الجزائع إلا إذا كانت Terminal إذا
+
+153
+00:14:03,940 --> 00:14:07,440
+كانت Terminal بدي أضيف Anti Markovnikov's addition
+
+154
+00:14:07,440 --> 00:14:13,280
+طب لو كانت بواسط الجزائع ال triple bond حيكون عندي
+
+155
+00:14:13,280 --> 00:14:16,320
+خليط من التفاعلات يعني ممكن أضيف Markovnikov's و
+
+156
+00:14:16,320 --> 00:14:19,220
+Anti Markovnikov's مبطل واضح Markovnikov's
+
+157
+00:14:19,220 --> 00:14:24,460
+addition فممكن تتم الإضافة باتجاهين واضح؟خلّينا
+
+158
+00:14:24,460 --> 00:14:28,400
+على الوضع البسيط انه يكون اندي تيرمن ال الكاين بدي
+
+159
+00:14:28,400 --> 00:14:32,080
+اضيف عليه مية يا بدي احط ال اتشان وال او اتشانة
+
+160
+00:14:32,080 --> 00:14:35,900
+markovnikov's addition او بدي احط ال اتشانة وال او
+
+161
+00:14:35,900 --> 00:14:42,080
+اتشانة انتي markovnikov's addition واضح؟ الآن بغض
+
+162
+00:14:42,080 --> 00:14:46,500
+النظر إذا اتكون مركب للمركب اللي هيتكون إيش هيكون؟
+
+163
+00:14:46,500 --> 00:14:53,100
+in allالانول هيتحول أيضًا إلى ال keto form اللي هو
+
+164
+00:14:53,100 --> 00:14:56,260
+الـCWO المقصود، بغض النظر كونه الديادة أو الكيتو
+
+165
+00:14:56,260 --> 00:15:01,200
+المهم أنه يتحول إلى CWO،
+
+166
+00:15:01,200 --> 00:15:06,180
+يتحول إلى CWO، إذًا ظاهرة التوتومينزم في كل
+
+167
+00:15:06,180 --> 00:15:13,130
+الأحوال بتصيرطبعا هذا الكلام هو اللي ممكن تسأله
+
+168
+00:15:13,130 --> 00:15:17,410
+عنه انتوا يعني اتخيلوا ان انا لو جبتلكم مثلا أي ال
+
+169
+00:15:17,410 --> 00:15:21,930
+kind زي هذا و طلبت منكوا في النهاية انكوا تحضرولي
+
+170
+00:15:21,930 --> 00:15:27,910
+مركب في cw bond o هنا بنفع
+
+171
+00:15:27,910 --> 00:15:33,150
+بدكوا تضيفوا الميه في وجود hg2 plus و بتعمل
+
+172
+00:15:33,150 --> 00:15:37,430
+توتماريزم و لو طلبت منكوا تحطولي ال cw bond o هنا
+
+173
+00:15:38,450 --> 00:15:40,710
+بتكون تضيف الميّه بهذه الطريقة تطلعوا أنتوا إيش
+
+174
+00:15:40,710 --> 00:15:46,810
+المحاسلة النهائية الـCWBond O هان طب لو بدى هان
+
+175
+00:15:46,810 --> 00:15:57,450
+بدى أستعمل الطريقة السابقة H3O Plus مع الذئبك إذا
+
+176
+00:15:57,450 --> 00:16:04,870
+أنا بإمكاني على طرفي الرابط أن أحط CWBond Oبضل اني
+
+177
+00:16:04,870 --> 00:16:09,970
+انتقل ال reagent المناسب اذا بديها تكون هنا يتكون
+
+178
+00:16:09,970 --> 00:16:16,940
+عندي كيتونهنا بدأ استعمل H3O Plus في وجود HG2 Plus
+
+179
+00:16:16,940 --> 00:16:20,600
+إذا بديها هنا بدأ استعمل شروط الـ Anti
+
+180
+00:16:20,600 --> 00:16:23,420
+Markovnikov's addition اللي هو الـ Hydroboration
+
+181
+00:16:23,420 --> 00:16:26,220
+يعني إضافة البرون والهيدروجين followed by
+
+182
+00:16:26,220 --> 00:16:30,660
+Oxidation بالهيدروجين البروكسايد اللي اتعلمناه،
+
+183
+00:16:30,660 --> 00:16:36,940
+واضح؟ فالاحتمالين ممكنينالاحتمالين ممكنين ان اعمل
+
+184
+00:16:36,940 --> 00:16:39,340
+markovnikov's addition او anti markovnikov's
+
+185
+00:16:39,340 --> 00:16:44,780
+addition وفي الحالتين ال a0 بده يصير keto form
+
+186
+00:16:44,780 --> 00:16:49,120
+بمعنى ال OH بده تصير C double bond O و ال double
+
+187
+00:16:49,120 --> 00:16:54,560
+bond بده تصير single bond ال double bond بده تصير
+
+188
+00:16:54,560 --> 00:17:03,630
+single bond الان بنجي لإضافة جديدة وهي إضافة الـ
+
+189
+00:17:03,630 --> 00:17:08,530
+Hydrogenإضافة الهيدروجين طبعا إضافة الهيدروجين
+
+190
+00:17:08,530 --> 00:17:14,270
+احنا بنسميها reduction عملية اختزال عملية اختزال
+
+191
+00:17:14,270 --> 00:17:19,230
+لاحظوا معنى ممكن احنا يكون عندنا single bond ممكن
+
+192
+00:17:19,230 --> 00:17:24,010
+يكون عندنا double bond ممكن يكون عندنا triple bond
+
+193
+00:17:24,010 --> 00:17:29,330
+إذا أنا بتحرك من ال single bond لل double bond أو
+
+194
+00:17:29,330 --> 00:17:32,550
+من ال double bond لل triple bond العملية بسميها
+
+195
+00:17:32,550 --> 00:17:37,290
+oxidationواضح؟ يعني لو عندى alkane بدي أخليه
+
+196
+00:17:37,290 --> 00:17:42,290
+alkene بقول oxidation of alkanes to alkenes لو
+
+197
+00:17:42,290 --> 00:17:46,310
+عندى alkene بدي أخليه alkyne بقول oxidation of
+
+198
+00:17:46,310 --> 00:17:52,030
+alkenes to alkynes إذا بتحرك بالعكسالعملية إيش
+
+199
+00:17:52,030 --> 00:17:56,910
+بنسميها reduction، عملية اختزار، الآن إحنا اللي
+
+200
+00:17:56,910 --> 00:18:00,970
+بدنا نعمله إنه عندنا triple bond، معنى عندنا
+
+201
+00:18:00,970 --> 00:18:05,090
+triple bond، إنه هننزل يا ل double bond، يا ل
+
+202
+00:18:05,090 --> 00:18:09,900
+single bond، في كل الأحوال العملية reductionبكل
+
+203
+00:18:09,900 --> 00:18:13,680
+الأحوال العملية عملية reduction عشانك العنوان
+
+204
+00:18:13,680 --> 00:18:19,540
+تبعكم reduction of alkynes ال reduction of alkynes
+
+205
+00:18:19,540 --> 00:18:27,740
+مع الهيدروجين حقيقة له تلت احتمالات و تلت شروط
+
+206
+00:18:27,740 --> 00:18:34,520
+تفاعل و تلت نواتج مختلفة ال reduction of alkynes
+
+207
+00:18:35,450 --> 00:18:41,010
+باستعمال الهيدروجين بتتم بثلاث طرق و بتقدر تلت طرق
+
+208
+00:18:41,010 --> 00:18:48,010
+الى تلت نواتج مختلفة الطريقة الأولى إذا أنا بضيف
+
+209
+00:18:48,010 --> 00:18:52,610
+الهيدروجين في وجود metal catalyst زى البلاديم او
+
+210
+00:18:52,610 --> 00:18:57,630
+البلاتين او ال nickel طبعا البلاديم دائما بيكون
+
+211
+00:18:57,630 --> 00:19:02,930
+مخلوط بكاربون بيسموه بلاديم كاربون كاربون فحم ناعم
+
+212
+00:19:02,930 --> 00:19:08,680
+جدا واضحبس الأساس في ال catalyst اللي هو إيش ال
+
+213
+00:19:08,680 --> 00:19:13,080
+بالاديام فإضافة ال hydrogen مع ال بالاديام و عشان
+
+214
+00:19:13,080 --> 00:19:16,080
+أنا مش كاتبينهم لو أجيكوا في الامتحان مع ال nickel
+
+215
+00:19:16,080 --> 00:19:22,780
+أو مع ال platinumمع أي metal من هدولة بضيف مرتين
+
+216
+00:19:22,780 --> 00:19:27,100
+وبيعطيني الalkene بحصلش على ال double bond بنتقل
+
+217
+00:19:27,100 --> 00:19:32,620
+مباشرة من ال triple bond إلى ال single bond إذا
+
+218
+00:19:32,620 --> 00:19:37,760
+هيدروجين مع بلاديم أو nickel أو platinum بيحوللي
+
+219
+00:19:37,760 --> 00:19:43,890
+الalkene إلىالكين .. واضح؟ يعني لو جيبنالكم سؤال
+
+220
+00:19:43,890 --> 00:19:47,150
+صح و غلط مرات طلاب التخموا لما نجيب الأسئلة نقولوا
+
+221
+00:19:47,150 --> 00:19:52,190
+reduction of alkanes using hydrogen palladium
+
+222
+00:19:52,190 --> 00:20:00,110
+produces alkenes غلط it produces alkenes single
+
+223
+00:20:00,110 --> 00:20:06,110
+bonds .. واضح؟ هذا اللي هو التفاعل الأولالان
+
+224
+00:20:06,110 --> 00:20:13,050
+التفاعل التاني .. التفاعل التاني ممكن احنا نضيف بس
+
+225
+00:20:13,050 --> 00:20:17,670
+جزء واحد هيدروجين مش اتنين في الحالة الأولى كم
+
+226
+00:20:17,670 --> 00:20:22,550
+هيدروجين ضفنا؟ جزين ممكن نضيف جزء واحد هيدروجين
+
+227
+00:20:22,550 --> 00:20:26,810
+الان انتبهوا انا بتيجينا نقطة فنية كتير مهمة لما
+
+228
+00:20:26,810 --> 00:20:32,170
+بدي اضيف جزء واحد هيدروجين هحول ال triple bond الى
+
+229
+00:20:32,170 --> 00:20:39,180
+double bondواضح؟ هحوّل ال triple bond إلى double
+
+230
+00:20:39,180 --> 00:20:42,420
+bond .. ال double bond فيها ظاهرة ال cis و ال
+
+231
+00:20:42,420 --> 00:20:51,460
+trans .. ال alkanes مافيهم ظاهرة cis و trans ..فيش
+
+232
+00:20:51,460 --> 00:20:55,080
+فيهم ظاهرة ال cis و ال trans؟ واضح؟ ظاهرة ال cis و
+
+233
+00:20:55,080 --> 00:20:59,060
+ال trans مرتبطة بإيش؟ بال double bonds بال ال
+
+234
+00:20:59,060 --> 00:21:02,440
+alkenes أو بال cyclic alkenes لما يكون عندي حلقات
+
+235
+00:21:02,440 --> 00:21:08,340
+الآن طالما أنا بتحول الألكاين هذا إلى ال keen إذا
+
+236
+00:21:08,340 --> 00:21:12,480
+اللي بيصير عندي تساؤل هل يا ترى الأ ال keen اللي
+
+237
+00:21:12,480 --> 00:21:17,840
+بيطلع عندي هيكون بال cis form ولا بال trans form
+
+238
+00:21:17,840 --> 00:21:25,400
+واضحة الفكرة؟الان حسب نوع الطريقة المستخدمة ممكن
+
+239
+00:21:25,400 --> 00:21:30,500
+اطلع نواتج بحيث ان الهيدروجين يضيف من جهة واحدة
+
+240
+00:21:30,500 --> 00:21:34,980
+وينتج عند الـ cis compound او الهيدروجين يضيف من
+
+241
+00:21:34,980 --> 00:21:39,600
+جهتين متعاكستين وينتج عند ال trans compound اذا
+
+242
+00:21:39,600 --> 00:21:45,260
+الاحتمالين ممكنين لكن بتحكم فيهم من خلال ايش؟طريقة
+
+243
+00:21:45,260 --> 00:21:52,000
+التفاعل إذا ضيفت الهيدروجين في وجود كتاليست بنسميه
+
+244
+00:21:52,000 --> 00:21:58,460
+لندلارز كتاليست لندلارز كتاليست
+
+245
+00:21:58,460 --> 00:22:02,680
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+246
+00:22:02,680 --> 00:22:02,880
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+247
+00:22:02,880 --> 00:22:05,140
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+248
+00:22:05,140 --> 00:22:07,460
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+249
+00:22:07,460 --> 00:22:08,360
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+250
+00:22:08,360 --> 00:22:11,520
+لندلارز كتاليست لندلارز كتاليست لندلار
+
+251
+00:22:13,220 --> 00:22:18,140
+هذا المُركّب اللي هو الـ diphenylacetylene هذا لو
+
+252
+00:22:18,140 --> 00:22:21,040
+بدنا نسميه diphenylacetylene هاي أسيتليلينه
+
+253
+00:22:21,040 --> 00:22:26,300
+كربونتين عليه فنل وفنل، مظبوط ولا لأ؟ بهذا
+
+254
+00:22:26,300 --> 00:22:28,940
+المُركّب الـ diphenylacetylene، بزام الهيدروجينز
+
+255
+00:22:28,940 --> 00:22:34,500
+إجوا من جهة واحدة، إذا الـ two phenyl groups
+
+256
+00:22:34,500 --> 00:22:40,680
+هيروحواعلى الجهة التانية المعاكسة واضح؟ هينتج عنده
+
+257
+00:22:40,680 --> 00:22:44,960
+ال cess compound
+
+258
+00:22:44,960 --> 00:22:54,040
+شايفينه هذا؟ الآن إيش هو ال landlord catalyst؟
+
+259
+00:23:03,700 --> 00:23:07,780
+ماذا يعني لندلار كتاليست؟ لندلار كتاليست هو عبارة
+
+260
+00:23:07,780 --> 00:23:14,200
+عن خليط موجود فيه 5% بالاديام مع كالسيام كربونيت
+
+261
+00:23:14,200 --> 00:23:19,600
+مع ليد أسيتيت مع إكوينولين، كل هذه الخلطة بتنبأ
+
+262
+00:23:19,600 --> 00:23:24,460
+بيشتريها الواحد، إيش اسمها؟ لندلار كتاليست، واضح؟
+
+263
+00:23:25,500 --> 00:23:30,200
+في بلاد يام لكن مع أشياء تانية فالان احنا بنقدر
+
+264
+00:23:30,200 --> 00:23:36,580
+نقول ان ال addition of hydrogen to alkynes using
+
+265
+00:23:36,580 --> 00:23:44,280
+Lindler's catalyst is a sin addition صح واضح؟
+
+266
+00:23:44,280 --> 00:23:49,700
+فالاضافة باستعمال Lindler's catalyst is a sin
+
+267
+00:23:49,700 --> 00:23:55,120
+additionبمعنى إضافة من جهة واحدة و في مرات كتيرة
+
+268
+00:23:55,120 --> 00:24:00,260
+بتطلعلي ال cess compound الان هل يا ترى بإمكاننا
+
+269
+00:24:00,260 --> 00:24:06,960
+ان نخلي ال hydrogen اضيف من جهتين متعاكستين ممكن
+
+270
+00:24:06,960 --> 00:24:13,900
+إذا غيرنا ال reagentإذا ضفنا الهيدروجين من خلال
+
+271
+00:24:13,900 --> 00:24:19,200
+إضافة معدل الليثيوم وال liquid ammonia لاحظوا
+
+272
+00:24:19,200 --> 00:24:22,740
+liquid ammonia مش solution يعني غاز الأمونيا بس
+
+273
+00:24:22,740 --> 00:24:28,160
+مبردينه بصير إيش؟ سائل بضف للهيدروجين من جهتين
+
+274
+00:24:28,160 --> 00:24:33,020
+متعاكستين بمعنى أخر بيعمل Anti-addition لاحظوا هنا
+
+275
+00:24:33,020 --> 00:24:38,690
+الهيدروجينكيف بيضيف؟ فلو كان عندى هذا المركب .. لو
+
+276
+00:24:38,690 --> 00:24:42,290
+كان عندى هذا المركب اللى هو two butane one two
+
+277
+00:24:42,290 --> 00:24:47,370
+three four هذا عبارة عن two butane او اى واحدة كان
+
+278
+00:24:47,370 --> 00:24:51,190
+ممكن بطريقة السابقة تتخيل ان هو dimethylacetylene
+
+279
+00:24:51,190 --> 00:24:55,550
+مظبوط ولا لأ؟ اه فلما تضيف hydrogen من هنا و
+
+280
+00:24:55,550 --> 00:24:59,990
+hydrogen من هنا يضيفه بطريقتين متعاكستين شو هيطلع
+
+281
+00:24:59,990 --> 00:25:06,060
+له؟ لtrans compound او لtrans two butaneواضح؟ إذا
+
+282
+00:25:06,060 --> 00:25:11,940
+لما نقول إحنا أنه هذا بندوّب معدن الليثيام في ال
+
+283
+00:25:11,940 --> 00:25:15,740
+liquid ammonia و بنضيفه على ال alkyne بده يعطينا
+
+284
+00:25:15,740 --> 00:25:21,560
+أي ناتج ل Trans أو ال Anti-addition product وبناء
+
+285
+00:25:21,560 --> 00:25:25,240
+على ذلك بإمكانكم أن تتخيلوا أن احنا ممكن نيجي
+
+286
+00:25:25,240 --> 00:25:32,960
+نسألكم نجيبلكم ال alkyne و نحطلكم تلت أسهموعلى كل
+
+287
+00:25:32,960 --> 00:25:42,240
+سهم reagent وكل سهم بيطلع ايش؟ وكل سهم بيطلع نتيجة
+
+288
+00:25:42,240 --> 00:25:46,360
+زي هذه الحالة مثلا، هاي بعد صفحتين بتلاحظوا انه
+
+289
+00:25:46,360 --> 00:25:50,340
+اتخيلوا ان هذا جاي سؤال في الامتحان دايفين
+
+290
+00:25:50,340 --> 00:25:55,620
+الacetylene الآن لو قلت انا مع hydrogen بالاديام
+
+291
+00:25:55,620 --> 00:26:01,840
+كاربون شو هيعطيني؟ الalkynwill be converted to
+
+292
+00:26:01,840 --> 00:26:07,780
+alkane إذا إضافتين هيدروجين طيب هنا مافيش cis و
+
+293
+00:26:07,780 --> 00:26:12,360
+trans طبعا بس هيك الرسمة لإنه single bonds ال cis
+
+294
+00:26:12,360 --> 00:26:15,520
+و ال trans وين موجودة كظاهرة حوالينا؟ أه طبعا ال
+
+295
+00:26:15,520 --> 00:26:19,040
+bonds الآن لو ضفنا هيدروجين في وجود ال lindlar
+
+296
+00:26:19,040 --> 00:26:19,640
+catalyst
+
+297
+00:26:32,660 --> 00:26:39,140
+دائما هذه المقارنات اهتموا فيهاوهذه المقارنات
+
+298
+00:26:39,140 --> 00:26:43,580
+بالمناسبة يعني تعتبر جيدة جدا في ال organ ال
+
+299
+00:26:43,580 --> 00:26:46,840
+chemistry يعني اي واحدة بدأت تدرس تفاعل فيه مقارنة
+
+300
+00:26:46,840 --> 00:26:50,060
+ما تحفظش تفاعل واحد تحفظ اكتر من تفاعل شوفته قبل
+
+301
+00:26:50,060 --> 00:26:58,150
+شوية اضافة الميه كانتعال Alkines بطريقتين .. هيك
+
+302
+00:26:58,150 --> 00:27:01,930
+افهموا الكلام اذا ذكروا إضافة الميه مثلا على ال
+
+303
+00:27:01,930 --> 00:27:05,950
+Alkines لما أخدناها .. أخدناها بكم طريقة؟ بتلات
+
+304
+00:27:05,950 --> 00:27:10,270
+طرق و كل طريقة تؤدي إلى ناتج بمعنى أنا بإمكان
+
+305
+00:27:10,270 --> 00:27:13,910
+أجيبلكوا Alkine و أحطلكوا إضافة الميه في وجود
+
+306
+00:27:13,910 --> 00:27:18,490
+الحامض .. بتكونوا تقولوا؟ماركوفنيكوفز اديشن مع
+
+307
+00:27:18,490 --> 00:27:21,850
+احتمال ال rearrangement إضافة الميه في وجود ال
+
+308
+00:27:21,850 --> 00:27:26,230
+mercury كأسيتات ماركوفنيكوفز اديشن بس مافيش
+
+309
+00:27:26,230 --> 00:27:30,730
+rearrangement إضافة الميه في وجود البورين
+
+310
+00:27:30,730 --> 00:27:33,910
+Hydroboration Oxidation Anti Markovnikov's
+
+311
+00:27:33,910 --> 00:27:37,810
+addition نفس الاشي لما خدتوا في ال الكينز مثلا HPR
+
+312
+00:27:37,810 --> 00:27:42,250
+في وجود الحامض HPR في وجود البروكسيل هنا مثلا
+
+313
+00:27:42,250 --> 00:27:47,750
+إضافة الهيدروجينمرة ال cane مرة cis ال cane مرة
+
+314
+00:27:47,750 --> 00:27:53,710
+trans ال cane واضح فدائما حاولوا تحفظوا هذه
+
+315
+00:27:53,710 --> 00:27:55,270
+المقارنات و تنتبهوها
+
+316
+00:28:00,970 --> 00:28:06,910
+أخر تفاعل .. أخر تفاعل بناخده في هذا chapter ..
+
+317
+00:28:06,910 --> 00:28:09,590
+chapter تلاتة من أكبر الفصول اللي معنا ان شاء الله
+
+318
+00:28:09,590 --> 00:28:15,230
+بنخلصه الآن اللي هو use of alkyne anion in a
+
+319
+00:28:15,230 --> 00:28:20,170
+substitution reaction ممكن نصيغه بطريقة أو بجملة
+
+320
+00:28:20,170 --> 00:28:27,540
+مختلفة تماما، نسميه acidity of alkynesحمضية
+
+321
+00:28:27,540 --> 00:28:31,260
+الalkynes طبعا لو كنا بدنا نكون دقيقين بدنا نقول
+
+322
+00:28:31,260 --> 00:28:43,560
+acidity of terminal alkynes terminal alkynes طبعا
+
+323
+00:28:43,560 --> 00:28:46,960
+لما نيجي نقول احنا الحامضية شو جابنا على الحامضية
+
+324
+00:28:46,960 --> 00:28:53,840
+في الalkynes اتذكروا انتوا الحامض حسب تعريف Lewis
+
+325
+00:28:57,090 --> 00:29:02,950
+هيدروجين دونار أو بروتون دونار مظبوط ولا لأ الحامض
+
+326
+00:29:02,950 --> 00:29:08,790
+حسب تعريف Lewis هو اللي بيعطينا إيش بروتون فأي إش
+
+327
+00:29:08,790 --> 00:29:14,170
+بده يفقد H بلس بده أعمله إنه حامض الحمض الآن في
+
+328
+00:29:14,170 --> 00:29:19,950
+الalkynes مين اللي فيهم هيدروجينالـ Terminal
+
+329
+00:29:19,950 --> 00:29:25,410
+Alkines لما تكون لـ Triple bond طرفية ملاحظين يعني
+
+330
+00:29:25,410 --> 00:29:28,870
+الـ Alkine إذا ماكانش Terminal مافيش هذا ال
+
+331
+00:29:28,870 --> 00:29:33,310
+section هذا ال section متعلق بإيش ال Terminal
+
+332
+00:29:33,310 --> 00:29:38,310
+Alkine اللي فيهم هيدروجين الآن هذه الهيدروجين اللي
+
+333
+00:29:38,310 --> 00:29:41,930
+جنب ال Alkine زي الهيدروجين اللي على ال OH في
+
+334
+00:29:41,930 --> 00:29:46,510
+الحامض إذا بنفعلها مع قاعدة قوية فإنها تفقد على
+
+335
+00:29:46,510 --> 00:29:51,260
+شكلالبروتون وبالتالي ال alkyne هنا can be
+
+336
+00:29:51,260 --> 00:29:57,480
+considered as an acid ممكن نعتبره حامض ممكن نعتبره
+
+337
+00:29:57,480 --> 00:30:04,740
+acid او حامض فمعنى حامض انه يفقد البروتون بدون
+
+338
+00:30:04,740 --> 00:30:11,100
+الالكتروناتبس فاقد البروتون عشان هيك هذا الالكاين
+
+339
+00:30:11,100 --> 00:30:14,860
+لو أخدنا مثلا هذا الالكاين وفعلنا مع very strong
+
+340
+00:30:14,860 --> 00:30:19,320
+base هذي ال strong base اسمها Sodamide زي ما في
+
+341
+00:30:19,320 --> 00:30:22,760
+عندكم Sodium Hydroxide Sodium Hydroxide إيش صيغته
+
+342
+00:30:22,760 --> 00:30:30,720
+العامة NaOH هذي ال base أقوى منه NaNH2 عبارة عن Na
+
+343
+00:30:32,290 --> 00:30:38,790
+و N H2- طبعا ال base اللي فيها هي عبارة عن إيش ال
+
+344
+00:30:38,790 --> 00:30:44,450
+N H2- زي في ال sodium hydroxide N A O H minus مين
+
+345
+00:30:44,450 --> 00:30:48,810
+اللي بياخد ال proton أثناء التفاعل ال O H minus ال
+
+346
+00:30:48,810 --> 00:30:52,450
+O H minus من ال N A O H لما تاخد ال proton و
+
+347
+00:30:52,450 --> 00:31:00,650
+بتتحول إلىالـ H2O الان هنا نفس الفكرة NA NH2-
+
+348
+00:31:00,650 --> 00:31:06,030
+بالنتيجة تاخد البروتون من هنا شو بده تصير الـ NH3
+
+349
+00:31:06,030 --> 00:31:14,610
+أمونيا واضح فهذا ايش اسمه Sodamide
+
+350
+00:31:14,610 --> 00:31:20,430
+زي Sodium Hydroxide بس هذا بيكون stronger base
+
+351
+00:31:20,430 --> 00:31:21,410
+than
+
+352
+00:31:32,450 --> 00:31:35,730
+هذا الكلام لو انتوا بتتطلعوا على الجدول الدوري و
+
+353
+00:31:35,730 --> 00:31:38,890
+كيف بتزيد القاعدية لما يكون عندي ال O هان او ال N
+
+354
+00:31:38,890 --> 00:31:43,490
+هان بهذا الشكل بتزيد القاعدية فكل اللي بيصير ان هو
+
+355
+00:31:43,490 --> 00:31:45,570
+ال N H 2 minus هتاخد H
+
+356
+00:31:48,910 --> 00:31:58,390
+أيون سالب بيسموه الacetylide anion بشكل
+
+357
+00:31:58,390 --> 00:32:04,070
+عام طبعا بيسموه ايون سالب شو ال ايون المرافق اللي
+
+358
+00:32:04,070 --> 00:32:06,150
+معاه هيكون ال anion
+
+359
+00:32:12,370 --> 00:32:19,910
+الان هذا ال ايون السالب لو اجيت فعلته مع مركب مثلا
+
+360
+00:32:19,910 --> 00:32:24,010
+مثل ال methyl iodide بيروح بهاجم على الكربون اللي
+
+361
+00:32:24,010 --> 00:32:29,370
+هال لأنها موجبة وبيطر دليوت هذا بعد ما اعملت انا
+
+362
+00:32:29,370 --> 00:32:35,330
+ايشبعد ما شيلت منه القدش و خلته ايون سالب قوي
+
+363
+00:32:35,330 --> 00:32:39,570
+بيصير strong nucleophile هال strong nucleophile
+
+364
+00:32:39,570 --> 00:32:43,510
+ممكن ييجي يهجم على مركب زي ال methyl iodide يطرد
+
+365
+00:32:43,510 --> 00:32:47,650
+منه اليود minus و يحل محله عشانك العنوان تبعكوا
+
+366
+00:32:47,650 --> 00:32:52,690
+ايش كان substitution ال substitution هي اي خطوة
+
+367
+00:32:52,690 --> 00:33:00,350
+التانية احنا الأساس عندنا اليوم ايشالـ Terminal
+
+368
+00:33:00,350 --> 00:33:08,830
+Alkines are Assets معناه Assets انهم بيفقدوه H
+
+369
+00:33:08,830 --> 00:33:12,750
+Plus لما بيفقدوه H Plus كوانولي ايون سالب الايون
+
+370
+00:33:12,750 --> 00:33:17,330
+السالب من طبيعته من تفاعلته انه بيحلم حال ايون
+
+371
+00:33:17,330 --> 00:33:22,840
+سالب تانيواضح؟ مثل هذا التفاعل بس الشيء الأساسي
+
+372
+00:33:22,840 --> 00:33:26,300
+عندنا احنا اليوم في موضوعنا الشيء الأساسي جدا في
+
+373
+00:33:26,300 --> 00:33:30,240
+موضوعنا ان ال terminal alkynes can be considered
+
+374
+00:33:30,240 --> 00:33:34,060
+as acids they lose their proton when reacted with
+
+375
+00:33:34,060 --> 00:33:38,660
+strong bases like Sodamate producing negative
+
+376
+00:33:38,660 --> 00:33:43,360
+anions or acetylide anions. Acetylide anions can
+
+377
+00:33:43,360 --> 00:33:56,600
+undergo substitutionlike this reaction واضح يعني
+
+378
+00:33:56,600 --> 00:34:00,000
+نجيب سؤال صح و غلط ان ال terminal alkines can be
+
+379
+00:34:00,000 --> 00:34:06,320
+considered as assets ولا بلاش ممكن نعتبرهم ممكن
+
+380
+00:34:06,320 --> 00:34:10,820
+فعلا نعتبرهم كأنهم كأنهم
+
+381
+00:34:12,830 --> 00:34:35,630
+بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+382
+00:34:35,630 --> 00:34:38,870
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+383
+00:34:38,870 --> 00:34:39,050
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+384
+00:34:39,050 --> 00:34:39,310
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+385
+00:34:39,310 --> 00:34:43,840
+بروتوز بيفقدواهذا المُركّب .. هذا المُركّب .. إذا
+
+386
+00:34:43,840 --> 00:34:48,600
+بتطلع عليه symmetric الـ kind .. الآن لما بدأ أضيف
+
+387
+00:34:48,600 --> 00:34:54,300
+عليه أنا HCL .. اتفقنا أن HCL بدي أضيف على مرتين
+
+388
+00:34:54,300 --> 00:34:58,280
+.. الآن لو إجيتوا تطلع على أول مرة بزامه مش
+
+389
+00:34:58,280 --> 00:35:03,760
+terminalمافيش تحديد وين بده تيجي ال H وين بده تيجي
+
+390
+00:35:03,760 --> 00:35:07,700
+ال CL لإن بالمناسبة الموقعين هنا نفس الأشياء لإنه
+
+391
+00:35:07,700 --> 00:35:12,580
+متماثل لكن مجرد ما بتم التفاعل الأول هنا بتيجي ال
+
+392
+00:35:12,580 --> 00:35:18,340
+H وهنا ال CL التفاعل التانيهييجي بنفس الاتجاه،
+
+393
+00:35:18,340 --> 00:35:21,760
+هيصير Markov-Nikols addition واضح، بمعنى أول خطوة
+
+394
+00:35:21,760 --> 00:35:26,480
+هنا، لو أي واحد اجت تضيف، مش هتشوف hydrogen، بيقول
+
+395
+00:35:26,480 --> 00:35:29,000
+لا مش مشكلة، اضيفي كيف ما كان، اضيفي ال-H and و ال
+
+396
+00:35:29,000 --> 00:35:32,140
+-Cl هنا، الآن بعد ما تضيف هنا H و هنا ال-Cl، ماتيش
+
+397
+00:35:32,140 --> 00:35:36,720
+تعمل الخطوة التانية، صارت ملزمة أن ال hydrogen وين
+
+398
+00:35:36,720 --> 00:35:40,260
+بدها تضيفها، على الكربون اللي حامله، ال hydrogen و
+
+399
+00:35:40,260 --> 00:35:46,960
+ال-Cl هنا، بدو يطلع عندنا هذا المراجع، واضح؟المثال
+
+400
+00:35:46,960 --> 00:35:53,200
+التاني عند triple bond مع BH3 وTHF
+
+401
+00:35:53,200 --> 00:35:55,700
+وهيدروجينبروقسايد اللي سمناه Hydroboration
+
+402
+00:35:55,700 --> 00:36:00,080
+Oxidation هذا بده يضيف ايش؟ بدكوا تعرفوا انه بده
+
+403
+00:36:00,080 --> 00:36:05,500
+يضيف مية Anti Markovnikovs وبعدين تتحول الى السيضة
+
+404
+00:36:05,500 --> 00:36:12,330
+بال bond بمعنى حيضيف ال H هناو ال O H هنا طب مكان
+
+405
+00:36:12,330 --> 00:36:16,130
+ال O H شو حصل عندى فى النهاية C double bond هو اذا
+
+406
+00:36:16,130 --> 00:36:20,670
+انا لما بدى النتيجة صار عندى هنا C double bond هو
+
+407
+00:36:20,670 --> 00:36:27,650
+واضح فهذا إضافة Anti Markov Necomedition على طول
+
+408
+00:36:27,650 --> 00:36:33,510
+هتتخيلوا ان هنا ال H هنا ال O H و دائما هذا ناتج
+
+409
+00:36:34,340 --> 00:36:37,640
+الـ Transient Product يعني أثناء التفاعل، بس هالي
+
+410
+00:36:37,640 --> 00:36:42,160
+بنفصله؟ لأ، أه إيش اللي بنفصل؟ إن هذا تصير C
+
+411
+00:36:42,160 --> 00:36:49,200
+double bond O وهنا تصير CH2 ماشي الحاجة، الآن هذا
+
+412
+00:36:49,200 --> 00:36:58,040
+الكائن بدنا نضيف عليه Lithium و NH3 Terminal
+
+413
+00:36:58,040 --> 00:37:01,540
+الكائن هدولة إيش بيعملوا ال Lithium مع ال NH3؟
+
+414
+00:37:02,620 --> 00:37:06,420
+بضيفوا هيدروجينز .. بضيفوا هيدروجينز .. بضيفوهم
+
+415
+00:37:06,420 --> 00:37:10,640
+anti addition انتبهوا معاه .. يمكن انتوا بتضلكوا
+
+416
+00:37:10,640 --> 00:37:16,200
+مصرين و قولتوها خمس مرات او ستة او سبعة انكوا
+
+417
+00:37:16,200 --> 00:37:21,560
+تقولوا trans و في كل مرة بتسمعوني انا اش بقول anti
+
+418
+00:37:22,600 --> 00:37:28,320
+الان ايش ال .. الدقة او الفرق في الكلام؟ في فرق
+
+419
+00:37:28,320 --> 00:37:33,940
+بين شغلتين، شغلة بنسميها mood of addition بمعنى
+
+420
+00:37:33,940 --> 00:37:38,460
+طريقة التفاعل وشغلة بنسميها ال product of
+
+421
+00:37:38,460 --> 00:37:43,480
+addition، ناتج التفاعل الان ال mood of addition ان
+
+422
+00:37:43,480 --> 00:37:48,380
+ال hydrogen من هنا و من هنا بيجوا عكس بعضهذا كلام
+
+423
+00:37:48,380 --> 00:37:53,380
+مافيش فيه خلاف إذا كيف بتتم ال addition؟ Anti الان
+
+424
+00:37:53,380 --> 00:37:58,460
+الناتج باعتمد ايش أساسا عند أنا Substituent
+
+425
+00:37:58,460 --> 00:38:04,340
+بالتالي دائما و أبدا طريقة الإضافة جايين متعاكسات
+
+426
+00:38:04,340 --> 00:38:10,560
+Anti addition لكن هل يا تورا لازم يطلعواسيس و
+
+427
+00:38:10,560 --> 00:38:14,760
+ترانس هذا بيعتمد ايش في عندى substitutes يعني هنا
+
+428
+00:38:14,760 --> 00:38:18,740
+لما اجوا اضافة واحدة من فوق واحدة من تحت هذه
+
+429
+00:38:18,740 --> 00:38:23,620
+الكربون اللى كان عليها اتش شو صار عليها two
+
+430
+00:38:23,620 --> 00:38:29,600
+hydrogens بزام احدى الذارتين عليها احدى ذارتين
+
+431
+00:38:29,600 --> 00:38:32,560
+الكربون اللى هو الطرفين ال double bond عليها two
+
+432
+00:38:32,560 --> 00:38:39,150
+hydrogens موجودة كل ظاهرة السيس و الترانس؟ لأشرط
+
+433
+00:38:39,150 --> 00:38:42,850
+.. شرط ظاهرة الـ sexual trance .. شرط ظاهرة الـ
+
+434
+00:38:42,850 --> 00:38:46,970
+sexual trance عشان تكون موجودة انه على طرفين ال
+
+435
+00:38:46,970 --> 00:38:50,130
+double bond يكون هنا مجموعتين مختلفتين و هنا
+
+436
+00:38:50,130 --> 00:38:56,850
+مجموعتين مختلفتين فانا هنا صح اعملت anti addition
+
+437
+00:38:56,850 --> 00:39:00,010
+لكن بعد ما اعملت ال anti addition صار هذه عليها
+
+438
+00:39:00,010 --> 00:39:03,230
+two hydrogens مافيش كل ظاهرة ال sexual trance
+
+439
+00:39:04,390 --> 00:39:09,490
+وعشانك انا بقول انه ال mood of addition دائما انت
+
+440
+00:39:09,490 --> 00:39:12,870
+addition مش مختلف معاكوا فيه لكن يا تورا هل هيطلع
+
+441
+00:39:12,870 --> 00:39:18,610
+عندى cis او trans هذا بيعتمد ايش موجود اصلا على
+
+442
+00:39:18,610 --> 00:39:23,750
+الجزاء يعني مثلا انبسط عليكم الموضوع كتير انبسط
+
+443
+00:39:23,750 --> 00:39:28,330
+عليكم الموضوع كتير جدا لو احنا كنا جايبينلكم
+
+444
+00:39:28,330 --> 00:39:29,310
+أسيتيلية
+
+445
+00:39:34,340 --> 00:39:38,040
+و أنا بدي اتفتح مخكم كويس جدا عشان تفهموا هذا
+
+446
+00:39:38,040 --> 00:39:42,260
+الكلام إيش معنى mood of addition و إيش معنى
+
+447
+00:39:42,260 --> 00:39:47,800
+product of addition لو أنا جايبلكم أسيتلين و هذا
+
+448
+00:39:47,800 --> 00:39:54,680
+الاسيتلين قولت إنه بدي أضيف عليه هيدروجين بطريقتين
+
+449
+00:39:54,680 --> 00:40:02,460
+مختلفتين بدي أضيف عليه بطريقة .. ممكن هذا ..
+
+450
+00:40:04,520 --> 00:40:10,060
+بطريقة الـ Lithium مع الـ NH3 و ممكن نضيف بطريقة
+
+451
+00:40:10,060 --> 00:40:17,460
+الـ Hydrogen مع الـ Lindler's catalyst ماشي
+
+452
+00:40:17,460 --> 00:40:23,060
+الحالت؟ الان من ناحية المبدأ ك mood of addition
+
+453
+00:40:23,060 --> 00:40:27,740
+كطريقة إضافة الـ Hydrogen مع الـ Lindler's
+
+454
+00:40:27,740 --> 00:40:32,080
+catalyst كيف بيضيفوه؟
+
+455
+00:40:34,520 --> 00:40:40,060
+addition مظبوط ولا لأ؟ طيب إضافة الهيدروجين من
+
+456
+00:40:40,060 --> 00:40:46,100
+خلال الليثيام والليكود أمونيا Anti-addition في
+
+457
+00:40:46,100 --> 00:40:50,520
+خلاف في هالكلام؟ طيب خلينا نرسم النتيجة لو حطينا C
+
+458
+00:40:50,520 --> 00:40:57,260
+double bond C وحطينا هنا H وحطينا هنا H وحطينا
+
+459
+00:40:57,260 --> 00:41:02,600
+اللي ضفناهم باللون الأحمر بهذا الشكل إيش طلع عندى؟
+
+460
+00:41:05,070 --> 00:41:08,830
+إيثالين مافيش فيه cis و trans الإيثالين هل ال mood
+
+461
+00:41:08,830 --> 00:41:14,750
+of addition هل ادول ضافوا من جهة واحدة؟ أكيدضافوا
+
+462
+00:41:14,750 --> 00:41:19,010
+من جهة واحدة لكن هل يا ترى الناتج نفسه في
+
+463
+00:41:19,010 --> 00:41:22,770
+الاثيليين في ال sis و ال trans؟ لأ فالموضوع of
+
+464
+00:41:22,770 --> 00:41:26,410
+addition is in addition لكن الناتج مافيش فيه من
+
+465
+00:41:26,410 --> 00:41:29,850
+الأساس ظاهرة ال sis و ال trans طيب الآن لو اجينا و
+
+466
+00:41:29,850 --> 00:41:33,910
+قولنا هانا بدنا نحط الناتج هيئتش صارت لتحت و هيئتش
+
+467
+00:41:33,910 --> 00:41:41,210
+لفوق اللي ضفناهم كيف ضافوا؟ Anti addition ايش
+
+468
+00:41:41,210 --> 00:41:43,430
+طلعولي؟ اثيليين
+
+469
+00:41:47,930 --> 00:41:53,890
+ملاحظين؟ إذا لو أنا بدي أقولكم the mode of
+
+470
+00:41:53,890 --> 00:41:59,550
+addition of hydrogen to acetylene using hydrogen
+
+471
+00:41:59,550 --> 00:42:05,770
+and lindar catalyst and lithium ammonia is the
+
+472
+00:42:05,770 --> 00:42:13,350
+same غلطال mood of addition طريقة الإضافة مرة ضافه
+
+473
+00:42:13,350 --> 00:42:15,990
+من جهة واحدة مرة ضافه من جهتين هذا ال mood of
+
+474
+00:42:15,990 --> 00:42:21,070
+addition مابختلفش لكن the product of additionنفس
+
+475
+00:42:21,070 --> 00:42:24,070
+الأشياء لأن في الأساس مافيش انتظارة تسس ولا ترازى
+
+476
+00:42:24,070 --> 00:42:29,590
+عشانك انا دائما بفضل ان ايش اقول قدامكم ان طريقة
+
+477
+00:42:29,590 --> 00:42:35,250
+الإضافة من جهة واحدة او من جهتين متعاكستين الان
+
+478
+00:42:35,250 --> 00:42:39,990
+الناتج يكون فيه سس يكون فيه trans هذا باعتمد على
+
+479
+00:42:39,990 --> 00:42:42,810
+ايش المركب اللي عنده ايش ال substituents اللي
+
+480
+00:42:42,810 --> 00:42:49,010
+موجودة واضح الفكرة بمعنى لو أنا كان عند مثل و مثل
+
+481
+00:42:52,660 --> 00:42:55,740
+لأ طبعا .. ما هو .. بدك تكون مراجعة .. احنا قولنا
+
+482
+00:42:55,740 --> 00:43:00,880
+الـ cis و الترانس شرطه ان كل carbon من طرفين ال
+
+483
+00:43:00,880 --> 00:43:03,700
+double bond يكون عليها مجموعتين مختلفتين .. الان
+
+484
+00:43:03,700 --> 00:43:08,180
+هنا من الأساس مافيش شيء .. كله نفس الاشي .. لكن لو
+
+485
+00:43:08,180 --> 00:43:14,520
+افترضتوا هنا مثل و مثل .. هيصير يخلي مثل و مثل و
+
+486
+00:43:14,520 --> 00:43:19,360
+أتش و أتش .. cis .. و هيصير يخلي مثل و مثل و أتش و
+
+487
+00:43:19,360 --> 00:43:24,320
+أتش ..الـ Trans إذا في حالة ما كان عند ال
+
+488
+00:43:24,320 --> 00:43:28,920
+Acetylene ال mode of addition مختلف لكن الناتج
+
+489
+00:43:28,920 --> 00:43:33,520
+واحد في حالة ما كان عنده ال dye مثل ال Acetylene و
+
+490
+00:43:33,520 --> 00:43:36,480
+لا ال dye فين ال Acetylene ال mode of addition
+
+491
+00:43:36,480 --> 00:43:42,480
+برضه مختلف و ال ناتج مختلف عشانك احنا لما بدنا
+
+492
+00:43:42,480 --> 00:43:46,820
+نقول كمبدأ عام بنحكي عن الناتج و لا عن طريقة
+
+493
+00:43:46,820 --> 00:43:52,560
+الإضافةلما بدي احكي قاعدة عامة انا ماعنديش مش عارف
+
+494
+00:43:52,560 --> 00:43:58,400
+اللي بضيف عليه أساسا أسيتلين ولا بروبين ولا
+
+495
+00:43:58,400 --> 00:44:05,960
+توبيوتين في هاد الحالة انا الأفضل ان اقول ال mood
+
+496
+00:44:05,960 --> 00:44:09,700
+of addition ان في كل الأحوال ال hydrogen في وجود
+
+497
+00:44:09,700 --> 00:44:17,640
+لندلار كتاليست proceeds through sin additionالان
+
+498
+00:44:17,640 --> 00:44:21,840
+لو بدكم تاخدوها homework هتلاحظوا انه في حالة ال
+
+499
+00:44:21,840 --> 00:44:27,120
+acetylene الناتجين هيطلعوا نفس الاشي وفي حالة ال
+
+500
+00:44:27,120 --> 00:44:33,280
+bromine لما يكون عندكم تلت ذرات كربون الناتجين نفس
+
+501
+00:44:33,280 --> 00:44:40,100
+الاشي وفي حالة ال one butane الناتجين نفس الاشي
+
+502
+00:44:40,100 --> 00:44:46,270
+وفي حالة ال two butaneالنتيجين مختلفة .. الان بصير
+
+503
+00:44:46,270 --> 00:44:50,610
+عندكم بيمشي اعملوا اتعبوا فيه فكروا بديكوا تعملوا
+
+504
+00:44:50,610 --> 00:44:55,330
+اضافة الهيدروجين باستعمال ليثيام أمونيا و باستعمال
+
+505
+00:44:55,330 --> 00:45:01,270
+هيدروجين لندلارس كاتاليست للأسيتيلين واضح
+
+506
+00:45:01,270 --> 00:45:05,850
+للبروبيلين للبروباين
+
+507
+00:45:05,850 --> 00:45:07,810
+للوانبيوتاين
+
+508
+00:45:09,230 --> 00:45:17,590
+للتو بيوتين أكم مركب أربعة أستيلين بروبين وان
+
+509
+00:45:17,590 --> 00:45:22,870
+بيوتين تو بيوتين اعملوها المرة اللي جاي بتسلموني
+
+510
+00:45:22,870 --> 00:45:27,430
+إياها هتلاحظوا بس بحالة واحدة الناتج بختلف بس في
+
+511
+00:45:27,430 --> 00:45:30,970
+الأربع حالات لو بتستعملوا القلم الأحمر و أنتوا
+
+512
+00:45:30,970 --> 00:45:34,770
+بتحطوا الإضافة لازم هنا تعمله
+
+513
+00:45:37,140 --> 00:45:41,020
+Sin addition وهنا Anti addition فال mood of
+
+514
+00:45:41,020 --> 00:45:44,220
+addition في الأربع حالات لما تستعملون الجلم الأحمر
+
+515
+00:45:44,220 --> 00:45:48,880
+هيطلع نفس ال mood of addition بس الناتج بحالة
+
+516
+00:45:48,880 --> 00:45:52,560
+واحدة بيطلع في مرة ظاهرة تستثمر ل Trans ومرة لأ
+
+517
+00:45:52,560 --> 00:45:56,840
+عشان هيك احنا كنا نركز اننا دايما نقولكوا ال mood
+
+518
+00:45:56,840 --> 00:46:01,520
+of addition ال product بيعتمد على ايش؟ على ال
+
+519
+00:46:01,520 --> 00:46:02,940
+substituents اللي موجودة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..18997977ad520c05344201002602daefb520d2ee
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_raw.json
@@ -0,0 +1 @@
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132.07, "word": " منهم", "probability": 0.985595703125}], "temperature": 1.0}, {"id": 6, "seek": 16131, "start": 133.11, "end": 161.31, "text": "Markovnikov's addition واضح كل إضافة منهم Markovnikov's addition كأنه بيجي هنا ذرتين هيدروجين و بيجي هنا ذرتين كلورين ومثلها أيضا ال HPR فال HPR وHCL بيضيفوا على حسب Markovnikov's addition لكن two successive additions يعني إضافتين متواليتين واضح", "tokens": [15168, 5179, 13123, 5179, 311, 4500, 4032, 46958, 5016, 28242, 11933, 11242, 31845, 3660, 9154, 16095, 3934, 5179, 13123, 5179, 311, 4500, 9122, 33456, 3224, 4724, 1829, 7435, 1829, 34105, 29910, 43500, 9957, 8032, 25708, 2288, 29245, 9957, 4032, 4724, 1829, 7435, 1829, 34105, 29910, 43500, 9957, 9122, 1211, 13063, 9957, 4032, 2304, 12984, 1211, 11296, 36632, 11242, 995, 2423, 12557, 49, 6156, 6027, 12557, 49, 4032, 39, 22458, 4724, 1829, 11242, 33911, 14407, 15844, 11331, 35457, 3934, 5179, 13123, 5179, 311, 4500, 44381, 732, 48043, 35113, 37495, 22653, 11933, 11242, 31845, 2655, 9957, 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"text": "بضل اني انتقل ال reagent المناسب اذا بديها تكون هنا يتكون عندي كيتون", "tokens": [3555, 11242, 1211, 16472, 1829, 16472, 2655, 4587, 1211, 2423, 26949, 317, 9673, 8315, 35457, 1975, 15730, 4724, 16254, 11296, 6055, 30544, 34105, 7251, 2655, 30544, 18871, 16254, 9122, 36081, 11536], "avg_logprob": -0.4272461049258709, "compression_ratio": 1.2580645161290323, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 963.65, "end": 964.35, "word": "بضل", "probability": 0.4401041666666667}, {"start": 964.35, "end": 964.87, "word": " اني", "probability": 0.490478515625}, {"start": 964.87, "end": 965.57, "word": " انتقل", "probability": 0.8287353515625}, {"start": 965.57, "end": 965.65, "word": " ال", "probability": 0.328369140625}, {"start": 965.65, "end": 966.29, "word": " reagent", "probability": 0.6552734375}, {"start": 966.29, "end": 967.15, "word": " المناسب", "probability": 0.98681640625}, {"start": 967.15, "end": 967.63, "word": " اذا", "probability": 0.64111328125}, 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1975, 5016, 8315, 16247, 3794, 32277, 43242, 8315, 45595, 20498, 1975, 1829, 8592], "avg_logprob": -0.23845109317613686, "compression_ratio": 1.6693227091633467, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1950.83, "end": 1951.25, "word": "بعد", "probability": 0.807861328125}, {"start": 1951.25, "end": 1951.63, "word": " ما", "probability": 0.55419921875}, {"start": 1951.63, "end": 1952.47, "word": " شيلت", "probability": 0.6917317708333334}, {"start": 1952.47, "end": 1952.79, "word": " منه", "probability": 0.94140625}, {"start": 1952.79, "end": 1953.25, "word": " القدش", "probability": 0.6280924479166666}, {"start": 1953.25, "end": 1953.35, "word": " و", "probability": 0.9658203125}, {"start": 1953.35, "end": 1953.83, "word": " خلته", "probability": 0.7120768229166666}, {"start": 1953.83, "end": 1954.27, "word": " ايون", "probability": 0.8668619791666666}, {"start": 1954.27, "end": 1954.87, "word": " سالب", "probability": 0.9270833333333334}, {"start": 1954.87, "end": 1955.33, "word": " قوي", "probability": 0.802001953125}, {"start": 1955.33, "end": 1956.01, "word": " بيصير", "probability": 0.8770751953125}, {"start": 1956.01, "end": 1956.55, "word": " strong", "probability": 0.619140625}, {"start": 1956.55, "end": 1957.79, "word": " nucleophile", "probability": 0.85107421875}, {"start": 1957.79, "end": 1958.29, "word": " هال", "probability": 0.6053466796875}, {"start": 1958.29, "end": 1958.69, "word": " strong", "probability": 0.6669921875}, {"start": 1958.69, "end": 1959.57, "word": " nucleophile", "probability": 0.926513671875}, {"start": 1959.57, "end": 1959.99, "word": " ممكن", "probability": 0.97412109375}, {"start": 1959.99, "end": 1960.27, "word": " ييجي", "probability": 0.815673828125}, {"start": 1960.27, "end": 1960.63, "word": " يهجم", "probability": 0.9737548828125}, {"start": 1960.63, "end": 1960.83, "word": " على", "probability": 0.80078125}, {"start": 1960.83, "end": 1961.41, "word": " مركب", "probability": 0.9013671875}, {"start": 1961.41, "end": 1961.93, "word": " زي", "probability": 0.7822265625}, {"start": 1961.93, "end": 1962.09, "word": " ال", "probability": 0.77490234375}, {"start": 1962.09, "end": 1962.41, "word": " methyl", "probability": 0.338623046875}, {"start": 1962.41, "end": 1963.07, "word": " iodide", "probability": 0.9111328125}, {"start": 1963.07, "end": 1963.51, "word": " يطرد", "probability": 0.8287353515625}, {"start": 1963.51, "end": 1963.77, "word": " منه", "probability": 0.986328125}, {"start": 1963.77, "end": 1964.27, "word": " اليود", "probability": 0.6552734375}, {"start": 1964.27, "end": 1965.47, "word": " minus", "probability": 0.68603515625}, {"start": 1965.47, "end": 1965.65, "word": " و", "probability": 0.7783203125}, {"start": 1965.65, "end": 1965.95, "word": " يحل", "probability": 0.73486328125}, {"start": 1965.95, "end": 1966.33, "word": " محله", "probability": 0.91162109375}, {"start": 1966.33, "end": 1966.77, "word": " عشانك", "probability": 0.719146728515625}, {"start": 1966.77, "end": 1967.15, "word": " العنوان", "probability": 0.9263916015625}, {"start": 1967.15, "end": 1967.65, "word": " تبعكوا", "probability": 0.79599609375}, {"start": 1967.65, "end": 1967.81, "word": " ايش", "probability": 0.6576334635416666}, {"start": 1967.81, "end": 1968.11, "word": " كان", "probability": 0.97998046875}, {"start": 1968.11, "end": 1969.55, "word": " substitution", "probability": 0.2318115234375}, {"start": 1969.55, "end": 1970.87, "word": " ال", "probability": 0.65673828125}, {"start": 1970.87, "end": 1971.45, "word": " substitution", "probability": 0.939453125}, {"start": 1971.45, "end": 1971.71, "word": " هي", "probability": 0.84716796875}, {"start": 1971.71, "end": 1971.89, "word": " اي", "probability": 0.85302734375}, {"start": 1971.89, "end": 1972.69, "word": " خطوة", "probability": 0.981201171875}, {"start": 1972.69, "end": 1973.87, "word": " التانية", "probability": 0.8357747395833334}, {"start": 1973.87, "end": 1974.41, "word": " احنا", "probability": 0.8966471354166666}, {"start": 1974.41, "end": 1975.11, "word": " الأساس", "probability": 0.8219401041666666}, {"start": 1975.11, "end": 1975.53, "word": " عندنا", "probability": 0.960205078125}, {"start": 1975.53, "end": 1975.93, "word": " اليوم", "probability": 0.969482421875}, {"start": 1975.93, "end": 1976.39, "word": " ايش", "probability": 0.9065755208333334}], "temperature": 1.0}, {"id": 84, "seek": 199831, "start": 1977.11, "end": 1998.31, "text": "الـ Terminal Alkines are Assets معناه Assets انهم بيفقدوه H Plus لما بيفقدوه H Plus كوانولي ايون سالب الايون السالب من طبيعته من تفاعلته انه بيحلم حال ايون سالب تاني", "tokens": [6027, 39184, 19835, 2071, 967, 74, 1652, 366, 6281, 1385, 20449, 8315, 3224, 6281, 1385, 16472, 16095, 4724, 33911, 28543, 2407, 3224, 389, 7721, 5296, 15042, 4724, 33911, 28543, 2407, 3224, 389, 7721, 9122, 2407, 7649, 12610, 1829, 1975, 1829, 11536, 8608, 6027, 3555, 42963, 1829, 11536, 21136, 6027, 3555, 9154, 23032, 21292, 34268, 3224, 9154, 6055, 5172, 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بيفقدوه", "probability": 0.71484375}, {"start": 1987.43, "end": 1988.83, "word": " H", "probability": 0.43701171875}, {"start": 1988.83, "end": 1989.39, "word": " Plus", "probability": 0.0643310546875}, {"start": 1989.39, "end": 1989.91, "word": " لما", "probability": 0.8251953125}, {"start": 1989.91, "end": 1990.31, "word": " بيفقدوه", "probability": 0.8818359375}, {"start": 1990.31, "end": 1990.51, "word": " H", "probability": 0.9296875}, {"start": 1990.51, "end": 1990.89, "word": " Plus", "probability": 0.87158203125}, {"start": 1990.89, "end": 1991.49, "word": " كوانولي", "probability": 0.67021484375}, {"start": 1991.49, "end": 1991.83, "word": " ايون", "probability": 0.6992594401041666}, {"start": 1991.83, "end": 1992.25, "word": " سالب", "probability": 0.8942057291666666}, {"start": 1992.25, "end": 1992.75, "word": " الايون", "probability": 0.7789713541666666}, {"start": 1992.75, "end": 1993.27, "word": " السالب", "probability": 0.97265625}, {"start": 1993.27, "end": 1993.53, "word": " من", "probability": 0.98046875}, {"start": 1993.53, "end": 1994.17, "word": " طبيعته", "probability": 0.9468994140625}, {"start": 1994.17, "end": 1994.45, "word": " من", "probability": 0.72021484375}, {"start": 1994.45, "end": 1995.97, "word": " تفاعلته", "probability": 0.87353515625}, {"start": 1995.97, "end": 1996.21, "word": " انه", "probability": 0.91455078125}, {"start": 1996.21, "end": 1996.61, "word": " بيحلم", "probability": 0.873779296875}, {"start": 1996.61, "end": 1996.93, "word": " حال", "probability": 0.697265625}, {"start": 1996.93, "end": 1997.33, "word": " ايون", "probability": 0.9420572916666666}, {"start": 1997.33, "end": 1997.83, "word": " سالب", "probability": 0.9816080729166666}, {"start": 1997.83, "end": 1998.31, "word": " تاني", "probability": 0.8756510416666666}], "temperature": 1.0}, {"id": 85, "seek": 202514, "start": 1999.3, "end": 2025.14, "text": "واضح؟ مثل هذا التفاعل بس الشيء الأساسي عندنا احنا اليوم في موضوعنا الشيء الأساسي جدا في موضوعنا ان ال terminal alkynes can be considered as acids they lose their proton when reacted with strong bases like Sodamate producing negative anions or acetylide anions. Acetylide anions can undergo substitution", "tokens": [2407, 46958, 5016, 22807, 50113, 1211, 23758, 16712, 5172, 995, 30241, 4724, 3794, 25124, 1829, 38207, 16247, 3794, 32277, 1829, 43242, 8315, 1975, 5016, 8315, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 8315, 25124, 1829, 38207, 16247, 3794, 32277, 1829, 10874, 28259, 8978, 3714, 2407, 11242, 45367, 8315, 16472, 2423, 14709, 37688, 2534, 279, 393, 312, 4888, 382, 21667, 436, 3624, 641, 31728, 562, 34037, 365, 2068, 17949, 411, 42059, 335, 473, 10501, 3671, 364, 626, 420, 696, 2210, 31264, 364, 626, 13, 5097, 2210, 31264, 364, 626, 393, 26426, 35827], "avg_logprob": -0.2160326031887013, "compression_ratio": 1.5587044534412955, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1999.3, "end": 1999.92, "word": "واضح؟", "probability": 0.7703857421875}, {"start": 1999.92, "end": 2000.18, "word": " مثل", "probability": 0.965576171875}, {"start": 2000.18, "end": 2000.4, "word": " هذا", "probability": 0.82080078125}, {"start": 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{"start": 2011.9, "end": 2012.38, "word": " lose", "probability": 0.7314453125}, {"start": 2012.38, "end": 2012.78, "word": " their", "probability": 0.60302734375}, {"start": 2012.78, "end": 2013.12, "word": " proton", "probability": 0.69921875}, {"start": 2013.12, "end": 2013.4, "word": " when", "probability": 0.88232421875}, {"start": 2013.4, "end": 2013.84, "word": " reacted", "probability": 0.86376953125}, {"start": 2013.84, "end": 2014.06, "word": " with", "probability": 0.9150390625}, {"start": 2014.06, "end": 2014.54, "word": " strong", "probability": 0.8046875}, {"start": 2014.54, "end": 2014.98, "word": " bases", "probability": 0.9189453125}, {"start": 2014.98, "end": 2015.5, "word": " like", "probability": 0.91259765625}, {"start": 2015.5, "end": 2016.66, "word": " Sodamate", "probability": 0.4986165364583333}, {"start": 2016.66, "end": 2017.56, "word": " producing", "probability": 0.60205078125}, {"start": 2017.56, "end": 2018.66, "word": " negative", "probability": 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نعتبرهم ممكن فعلا نعتبرهم كأنهم كأنهم", "tokens": [4092, 341, 5480, 4032, 46958, 5016, 37495, 22653, 8717, 7435, 1829, 3555, 8608, 33604, 6027, 20328, 5016, 4032, 32771, 1211, 9566, 16472, 2423, 14709, 419, 74, 1652, 393, 312, 4888, 382, 9769, 49429, 4724, 1211, 33599, 3714, 43020, 8717, 34268, 26890, 16095, 3714, 43020, 6156, 3615, 15040, 8717, 34268, 26890, 16095, 9122, 33456, 16095, 9122, 33456, 16095], "avg_logprob": -0.23114223829631148, "compression_ratio": 1.4038461538461537, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 2026.82, "end": 2027.26, "word": "like", "probability": 0.354736328125}, {"start": 2027.26, "end": 2027.62, "word": " this", "probability": 0.955078125}, {"start": 2027.62, "end": 2028.34, "word": " reaction", "probability": 0.91259765625}, {"start": 2028.34, "end": 2029.36, "word": " واضح", "probability": 0.8230794270833334}, {"start": 2029.36, "end": 2036.6, "word": " يعني", "probability": 0.671142578125}, {"start": 2036.6, "end": 2036.88, 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"text": "ملاحظين؟ إذا لو أنا بدي أقولكم the mode of addition of hydrogen to acetylene using hydrogen and lindar catalyst and lithium ammonia is the same غلط", "tokens": [2304, 15040, 5016, 19913, 9957, 22807, 11933, 15730, 45164, 41850, 4724, 16254, 5551, 39648, 24793, 264, 4391, 295, 4500, 295, 12697, 281, 696, 2210, 21323, 1228, 12697, 293, 287, 471, 289, 23868, 293, 32180, 46833, 307, 264, 912, 32771, 1211, 9566], "avg_logprob": -0.31212798399584635, "compression_ratio": 1.206896551724138, "no_speech_prob": 0.0, "words": [{"start": 2507.93, "end": 2509.29, "word": "ملاحظين؟", "probability": 0.6752522786458334}, {"start": 2509.29, "end": 2510.33, "word": " إذا", "probability": 0.62060546875}, {"start": 2510.33, "end": 2511.49, "word": " لو", "probability": 0.884765625}, {"start": 2511.49, "end": 2511.69, "word": " أنا", "probability": 0.72412109375}, {"start": 2511.69, "end": 2511.91, "word": " بدي", "probability": 0.70458984375}, {"start": 2511.91, "end": 2513.07, "word": " أقولكم", 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2715.19, "word": " أستيلين", "probability": 0.6690673828125}, {"start": 2715.19, "end": 2716.63, "word": " بروبين", "probability": 0.734619140625}, {"start": 2716.63, "end": 2717.59, "word": " وان", "probability": 0.4813232421875}, {"start": 2717.59, "end": 2718.39, "word": " بيوتين", "probability": 0.9388427734375}, {"start": 2718.39, "end": 2719.13, "word": " تو", "probability": 0.283935546875}, {"start": 2719.13, "end": 2719.91, "word": " بيوتين", "probability": 0.9638671875}, {"start": 2719.91, "end": 2721.41, "word": " اعملوها", "probability": 0.9408203125}, {"start": 2721.41, "end": 2721.87, "word": " المرة", "probability": 0.955810546875}, {"start": 2721.87, "end": 2721.99, "word": " اللي", "probability": 0.72119140625}, {"start": 2721.99, "end": 2722.15, "word": " جاي", "probability": 0.947021484375}, {"start": 2722.15, "end": 2722.87, "word": " بتسلموني", "probability": 0.78203125}, {"start": 2722.87, "end": 2723.19, "word": " إياها", "probability": 0.8505859375}, {"start": 2723.19, "end": 2724.07, "word": " هتلاحظوا", "probability": 0.9535319010416666}, {"start": 2724.07, "end": 2724.31, "word": " بس", "probability": 0.987548828125}, {"start": 2724.31, "end": 2724.81, "word": " بحالة", "probability": 0.908935546875}, {"start": 2724.81, "end": 2725.37, "word": " واحدة", "probability": 0.96142578125}, {"start": 2725.37, "end": 2726.17, "word": " الناتج", "probability": 0.8015950520833334}, {"start": 2726.17, "end": 2726.71, "word": " بختلف", "probability": 0.9376627604166666}, {"start": 2726.71, "end": 2727.27, "word": " بس", "probability": 0.81103515625}, {"start": 2727.27, "end": 2727.43, "word": " في", "probability": 0.88037109375}, {"start": 2727.43, "end": 2727.91, "word": " الأربع", "probability": 0.9796549479166666}, {"start": 2727.91, "end": 2728.35, "word": " حالات", "probability": 0.9484049479166666}, {"start": 2728.35, "end": 2728.49, "word": " لو", "probability": 0.93896484375}, {"start": 2728.49, "end": 2729.19, "word": " بتستعملوا", "probability": 0.964453125}, {"start": 2729.19, "end": 2729.53, "word": " القلم", "probability": 0.7474365234375}, {"start": 2729.53, "end": 2730.29, "word": " الأحمر", "probability": 0.9474283854166666}, {"start": 2730.29, "end": 2730.73, "word": " و", "probability": 0.9326171875}, {"start": 2730.73, "end": 2730.97, "word": " أنتوا", "probability": 0.7081705729166666}, {"start": 2730.97, "end": 2731.45, "word": " بتحطوا", "probability": 0.9549560546875}, {"start": 2731.45, "end": 2732.37, "word": " الإضافة", "probability": 0.978515625}, {"start": 2732.37, "end": 2733.87, "word": " لازم", "probability": 0.98681640625}, {"start": 2733.87, "end": 2734.09, "word": " هنا", "probability": 0.89013671875}, {"start": 2734.09, "end": 2734.77, "word": " تعمله", "probability": 0.81884765625}], "temperature": 1.0}, {"id": 114, "seek": 276294, "start": 2737.14, "end": 2762.94, "text": "Sin addition وهنا Anti addition فال mood of addition في الأربع حالات لما تستعملون الجلم الأحمر هيطلع نفس ال mood of addition بس الناتج بحالة واحدة بيطلع في مرة ظاهرة تستثمر ل Trans ومرة لأ عشان هيك احنا كنا نركز اننا دايما نقولكوا ال mood of addition ال product بيعتمد على ايش؟ على ال substituents اللي موجودة", "tokens": [50, 259, 4500, 37037, 8315, 27757, 4500, 6156, 6027, 9268, 295, 4500, 8978, 16247, 25513, 3615, 11331, 6027, 9307, 5296, 15042, 6055, 14851, 25957, 1211, 11536, 25724, 19528, 16247, 5016, 29973, 39896, 9566, 1211, 3615, 8717, 36178, 2423, 9268, 295, 4500, 4724, 3794, 28239, 9307, 7435, 4724, 5016, 6027, 3660, 36764, 24401, 3660, 4724, 1829, 9566, 1211, 3615, 8978, 3714, 25720, 1357, 116, 40294, 25720, 6055, 14851, 12984, 29973, 5296, 6531, 4032, 2304, 25720, 5296, 10721, 6225, 8592, 7649, 39896, 4117, 1975, 5016, 8315, 9122, 8315, 8717, 31747, 11622, 16472, 8315, 11778, 47302, 15042, 8717, 39648, 4117, 14407, 2423, 9268, 295, 4500, 2423, 1674, 4724, 1829, 34268, 2304, 3215, 15844, 1975, 1829, 8592, 22807, 15844, 2423, 4594, 6380, 791, 13672, 1829, 3714, 29245, 23328, 3660], 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"word": " الأربع", "probability": 0.9503580729166666}, {"start": 2742.22, "end": 2742.66, "word": " حالات", "probability": 0.83984375}, {"start": 2742.66, "end": 2742.84, "word": " لما", "probability": 0.719482421875}, {"start": 2742.84, "end": 2743.42, "word": " تستعملون", "probability": 0.90517578125}, {"start": 2743.42, "end": 2743.76, "word": " الجلم", "probability": 0.956787109375}, {"start": 2743.76, "end": 2744.22, "word": " الأحمر", "probability": 0.95166015625}, {"start": 2744.22, "end": 2745.12, "word": " هيطلع", "probability": 0.80169677734375}, {"start": 2745.12, "end": 2745.58, "word": " نفس", "probability": 0.990478515625}, {"start": 2745.58, "end": 2745.74, "word": " ال", "probability": 0.8818359375}, {"start": 2745.74, "end": 2745.92, "word": " mood", "probability": 0.97998046875}, {"start": 2745.92, "end": 2746.12, "word": " of", "probability": 0.97802734375}, {"start": 2746.12, "end": 2746.62, "word": " addition", "probability": 0.96630859375}, {"start": 2746.62, "end": 2747.22, "word": " بس", "probability": 0.918701171875}, {"start": 2747.22, "end": 2748.06, "word": " الناتج", "probability": 0.77685546875}, {"start": 2748.06, "end": 2748.88, "word": " بحالة", "probability": 0.9390869140625}, {"start": 2748.88, "end": 2749.2, "word": " واحدة", "probability": 0.9345703125}, {"start": 2749.2, "end": 2749.66, "word": " بيطلع", "probability": 0.8484375}, {"start": 2749.66, "end": 2750.32, "word": " في", "probability": 0.8505859375}, {"start": 2750.32, "end": 2750.64, "word": " مرة", "probability": 0.989501953125}, {"start": 2750.64, "end": 2751.06, "word": " ظاهرة", "probability": 0.872802734375}, {"start": 2751.06, "end": 2751.56, "word": " تستثمر", "probability": 0.4835205078125}, {"start": 2751.56, "end": 2751.74, "word": " ل", "probability": 0.297607421875}, {"start": 2751.74, "end": 2752.02, "word": " Trans", "probability": 0.30908203125}, {"start": 2752.02, "end": 2752.38, "word": " ومرة", "probability": 0.780029296875}, {"start": 2752.38, "end": 2752.56, "word": " لأ", "probability": 0.6767578125}, {"start": 2752.56, "end": 2752.92, "word": " عشان", "probability": 0.91943359375}, {"start": 2752.92, "end": 2753.06, "word": " هيك", "probability": 0.834716796875}, {"start": 2753.06, "end": 2753.24, "word": " احنا", "probability": 0.8916015625}, {"start": 2753.24, "end": 2753.5, "word": " كنا", "probability": 0.976318359375}, {"start": 2753.5, "end": 2754.14, "word": " نركز", "probability": 0.9583333333333334}, {"start": 2754.14, "end": 2754.5, "word": " اننا", "probability": 0.3902587890625}, {"start": 2754.5, "end": 2754.72, "word": " دايما", "probability": 0.8904622395833334}, {"start": 2754.72, "end": 2755.42, "word": " نقولكوا", "probability": 0.8511962890625}, {"start": 2755.42, "end": 2756.58, "word": " ال", "probability": 0.8017578125}, {"start": 2756.58, "end": 2756.84, "word": " mood", "probability": 0.99267578125}, {"start": 2756.84, "end": 2757.04, "word": " of", "probability": 0.98046875}, {"start": 2757.04, "end": 2757.6, "word": " addition", "probability": 0.9609375}, {"start": 2757.6, "end": 2758.42, "word": " ال", "probability": 0.8359375}, {"start": 2758.42, "end": 2758.78, "word": " product", "probability": 0.9619140625}, {"start": 2758.78, "end": 2759.34, "word": " بيعتمد", "probability": 0.87783203125}, {"start": 2759.34, "end": 2759.58, "word": " على", "probability": 0.7099609375}, {"start": 2759.58, "end": 2760.14, "word": " ايش؟", "probability": 0.6956787109375}, {"start": 2760.14, "end": 2761.14, "word": " على", "probability": 0.8369140625}, {"start": 2761.14, "end": 2761.52, "word": " ال", "probability": 0.93603515625}, {"start": 2761.52, "end": 2762.22, "word": " substituents", "probability": 0.8243815104166666}, {"start": 2762.22, "end": 2762.42, "word": " اللي", "probability": 0.918701171875}, {"start": 2762.42, "end": 2762.94, "word": " موجودة", "probability": 0.9552001953125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2767.67925, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o.srt
new file mode 100644
index 0000000000000000000000000000000000000000..88789a8fb246694b556c6d1ec364182e8e00e39c
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o.srt
@@ -0,0 +1,1754 @@
+1
+00:00:07,730 --> 00:00:12,390
+المحاضرة الماضية بعد ما اتكلمنا عن الـalcohols
+
+2
+00:00:12,390 --> 00:00:18,230
+والتسميتهم والـhydrogen bonding والخواص بدأنا في 
+
+3
+00:00:18,230 --> 00:00:21,270
+موضوع كثير مهم في موضوع الـalcohols اللي هو
+
+4
+00:00:21,270 --> 00:00:26,590
+الموضوع الحامضية الـacidity طبعا حكينا احنا شغلة 
+
+5
+00:00:26,590 --> 00:00:33,430
+أن الـacidity حسب تعريف لوري برونستيد الـacid
+
+6
+00:00:33,430 --> 00:00:39,450
+بروتون دونر بدو يفقد بروتون بيصف عندنا اللي هو
+
+7
+00:00:39,450 --> 00:00:44,990
+الأيون السالب والبروتون واضح؟ الآن المشكلة أن 
+
+8
+00:00:44,990 --> 00:00:51,870
+الحمض يكون قوي في قد إيش الأيون السالب يكون ثابت يعني 
+
+9
+00:00:51,870 --> 00:00:55,570
+المشكلة مش في البروتون، لأنه لو أخذنا عشر أحماض،
+
+10
+00:00:55,570 --> 00:00:58,630
+العشر أحماض هيفقدوا نفس البروتون، نفس البروتون، بس 
+
+11
+00:00:58,630 --> 00:01:04,810
+في كل حالة هيظل جزء سالب مختلف عن الجزء الثاني،
+
+12
+00:01:04,810 --> 00:01:08,950
+واضح؟ فبناء على ذلك، لما أنا بقارن قوة الأحماض،
+
+13
+00:01:08,950 --> 00:01:14,000
+ما بطلعش على البروتون أنا بطلع على الجزء السالب هل
+
+14
+00:01:14,000 --> 00:01:18,680
+يا ترى الجزء السالب اللي عندي قادر يتحمل الشحنة
+
+15
+00:01:18,680 --> 00:01:23,700
+يحملها ولا لأ؟ يعني مثلا لو بدنا بس كمراجعة بسيطة
+
+16
+00:01:23,700 --> 00:01:31,080
+هأذكركم في HBr و HCl الاثنين بيعملوا الـ H Plus
+
+17
+00:01:31,080 --> 00:01:35,720
+لكن هنا ما سيحدث لدي Br minus هنا ما سيحدث لدي Cl
+
+18
+00:01:35,720 --> 00:01:39,460
+minus إذا مشكلتي أنا الـ Br minus والـ Cl minus
+
+19
+00:01:39,460 --> 00:01:45,000
+مين أقدر فيهم على حمل الشحنة السالبة هو اللي بيحدد
+
+20
+00:01:45,000 --> 00:01:48,640
+قوة الحمض طبعا في هذه الحالة اللي لاحظوا أن الـ 
+
+21
+00:01:48,640 --> 00:01:54,380
+HBr أقوى وقالوا السبب أن حجم ذرة البروم أكبر من
+
+22
+00:01:54,380 --> 00:01:58,790
+حجم ذرة الكلور فالحجم الكبير بقدر يحمل أكثر من
+
+23
+00:01:58,790 --> 00:02:03,650
+الصغير، الولد الكبير بيحمل ثقل أكثر من إيش؟ من
+
+24
+00:02:03,650 --> 00:02:08,850
+الطفل الصغير، الآن هنا نفس الشيء، لو بدي أقارن 
+
+25
+00:02:08,850 --> 00:02:15,210
+مثلا، هاي عندي مجموعة ال goals مقارنة بالماء، HO,
+
+26
+00:02:15,330 --> 00:02:20,930
+H, HO مثل HO مثل HO attributed، زي ما بتلاحظوا كل
+
+27
+00:02:20,930 --> 00:02:25,500
+الجزء اللي موجود هنا هو اللي بده يمثل إيش؟ الجزء
+
+28
+00:02:25,500 --> 00:02:30,840
+السالب وهذه ستظهر على شكل الـ H بلس طبعا هو الكحول
+
+29
+00:02:30,840 --> 00:02:35,520
+ليس أيوني عشان الكلام يكون واضح الكحول ليس Ionic
+
+30
+00:02:35,520 --> 00:02:39,960
+compound يعني ما حدش يتخيل أن الكحول زي Na بلس Cl
+
+31
+00:02:39,960 --> 00:02:44,180
+ماينوس لأ الكحول عبارة عن Molecular compound لكن 
+
+32
+00:02:44,180 --> 00:02:50,200
+لما بده يتعامل كحمض بيفقد الـ H بلس واضح؟ و بيظهر
+
+33
+00:02:50,200 --> 00:02:55,820
+عند الجزء السالب ف قوة الحمض مرتبطة بإيش؟ بهذا
+
+34
+00:02:55,820 --> 00:03:00,500
+الجزء السالب حتى نفس الأشهر لو بدكم تقارنوا ال
+
+35
+00:03:00,500 --> 00:03:05,180
+filons كل هذا يمثل الـ H plus كل دول يمثلوا الجزء 
+
+36
+00:03:05,180 --> 00:03:08,820
+السالب وين فيه قدرة على حمل الجزء السالب بيكون
+
+37
+00:03:08,820 --> 00:03:16,140
+المركب أقوى إذا بدي أجي أطلع بوضوح بلاغظ إنه
+
+38
+00:03:16,140 --> 00:03:21,420
+المنطقة الأولى تقريباً كنا تمثل أحماض ضعيفة الماء
+
+39
+00:03:21,420 --> 00:03:25,600
+زي الـ Methanol نوعا ما زي الـ Ethanol شوية صغيرة
+
+40
+00:03:25,600 --> 00:03:29,300
+بتفرق في الـ tertiary-butanol ما فيش عندي مشكلة وين
+
+41
+00:03:29,300 --> 00:03:33,500
+بيبدأ يصير تغير و الحمض بيبدأ يصير أقوى كثير
+
+42
+00:03:33,500 --> 00:03:40,760
+هنطلع على هذا الحمض CH3CH2OH
+
+43
+00:03:40,760 --> 00:03:47,450
+Trifluoroethanol بنسميه إيثانول لكن موجود فيه ثلاث
+
+44
+00:03:47,450 --> 00:03:53,410
+ذرات هيدروجين بإيش بـ fluorine لو بدي أرسم هذا لحاله
+
+45
+00:03:53,410 --> 00:03:59,490
+أرسم الأيون السالب تبعه هاي CH2 O minus بعدين F
+
+46
+00:03:59,490 --> 00:04:07,090
+F F إيش اللي خلى هذا يصير حمض قوي؟
+
+47
+00:04:08,150 --> 00:04:12,170
+أنه الـ F electron withdrawing group واضح ال
+
+48
+00:04:12,170 --> 00:04:16,150
+electronegativity تبعته عالية بناء على ذلك صح أنا
+
+49
+00:04:16,150 --> 00:04:23,190
+عندي هنا في مشكلة لكن في عندي ساحب لهذه المشكلة في 
+
+50
+00:04:23,190 --> 00:04:26,470
+عندي شحنة سالبة في مجموعات بتسحب الشحنة السالبة
+
+51
+00:04:26,470 --> 00:04:31,270
+إذا ما ضلتش الشحنة السالبة مركزة هنا واضح هذا ال
+
+52
+00:04:31,270 --> 00:04:34,890
+effect هو مساعدة في حمل الشحنة السالبة هو اللي 
+
+53
+00:04:34,890 --> 00:04:40,750
+سميناه إيش؟ inductive effect إذا احنا بنقدر نقول 
+
+54
+00:04:40,750 --> 00:04:47,190
+الآن أن الـ trifluoroethanol is more acidic than 
+
+55
+00:04:47,190 --> 00:04:53,700
+ethanol due to inductive effect هيجي شيء يحمل فيها، 
+
+56
+00:04:53,700 --> 00:04:58,140
+يساعد في حملها، يسحب هذه الشحنة هذا عبارة عن 
+
+57
+00:04:58,140 --> 00:05:02,860
+inductive effect طبعا أكيد بيصير واضح عندكم تماما
+
+58
+00:05:02,860 --> 00:05:06,360
+لو كنتوا تعملوا مقارنات لو كنتوا بدأتوا تقارنوا
+
+59
+00:05:06,360 --> 00:05:09,700
+المركب في F واحدة و ثلاث F، أنه more 
+
+60
+00:05:09,700 --> 00:05:14,720
+acidic الثلاث F لو كنتوا بدأتوا تقارنوا المركب
+
+61
+00:05:14,720 --> 00:05:19,240
+في ثلاث F أو المركب اللي فيه ثلاث chlorine
+
+62
+00:05:20,740 --> 00:05:23,720
+الـ F أعلى الـ F الـ electronegativity له 
+
+63
+00:05:23,720 --> 00:05:30,120
+أعلى كل هذا هو عبارة عن ال inductive effect الآن
+
+64
+00:05:30,120 --> 00:05:36,580
+لاحظوا معي ال inductive effect زي ما ممكن يكون
+
+65
+00:05:36,580 --> 00:05:45,690
+مساعدة ممكن أنه يكون له أثر عكسي واضح؟ يعني مظبوط 
+
+66
+00:05:45,690 --> 00:05:49,810
+احنا بنجيب ناس يساعدونا وممكن يساعدونا بس في ناس
+
+67
+00:05:49,810 --> 00:05:55,610
+بنجيبهم يساعدوا ويحلوا المشكلة بيزيدوا .. إيش بيقول 
+
+68
+00:05:55,610 --> 00:06:03,170
+المثل؟ بيزيدوا الطينة بِاللَّعْنِ أو جبناك يا عبد المعين
+
+69
+00:06:03,170 --> 00:06:09,810
+اتعين لجناك؟ إذا ممكن هذا الأثر إذا مركب يكون أثر 
+
+70
+00:06:09,810 --> 00:06:15,930
+عكسي لو كانت المجموعة اللي هنا مش بتسحب بتعطيه
+
+71
+00:06:15,930 --> 00:06:22,110
+واضح؟ لو كانت المجموعة اللي هنا مش مجموعة ساحبة 
+
+72
+00:06:22,110 --> 00:06:27,570
+للإلكترونات بتخفف المشكلة مجموعة معطية للإلكترونات
+
+73
+00:06:27,570 --> 00:06:32,330
+بتزيد المشكلة لو بدنا نتخيل وين الكلام ممكن يصير 
+
+74
+00:06:32,330 --> 00:06:37,070
+لو شلنا هذا الـ F وحطينا بداله CH3
+
+75
+00:06:39,400 --> 00:06:43,600
+الـ methyl غالباً بتعمل كـ electron donating group
+
+76
+00:06:43,600 --> 00:06:51,040
+CH3 الآن هنا الـ CH3 إيش اللي بتعمله؟ بتعطي 
+
+77
+00:06:51,040 --> 00:06:54,500
+إلكترونات مش بتزيد إلكترونات إذا زادت الشحنة
+
+78
+00:06:54,500 --> 00:07:00,000
+السالبة عندها بناء على ذلك هذا المركب اللي زي هذا
+
+79
+00:07:00,000 --> 00:07:04,260
+أو لو كانت الـ OH مباشرة هنا يعني احنا موجود عندنا 
+
+80
+00:07:04,260 --> 00:07:08,810
+المركب اللي فيه الـ OH موجودة هيك مباشرة يعني ال O
+
+81
+00:07:08,810 --> 00:07:13,770
+minus اللي هو tertiary-butanol
+
+82
+00:07:13,770 --> 00:07:17,810
+اتطلعوا عليه هذا اللي حامل ثلاث CH3 إيش صار للـ
+
+83
+00:07:17,810 --> 00:07:26,850
+pKa تبعته صارت تمانتعش زادت الـ pKa قلت الـ acidity
+
+84
+00:07:26,850 --> 00:07:30,650
+الآن هنا ليش قلت الـ acidity؟ برضه بسبب الـ
+
+85
+00:07:30,650 --> 00:07:33,650
+inductive effect هو inductive effect سواء الـ
+
+86
+00:07:33,650 --> 00:07:40,730
+inductive effect أخذ أو إعطاء الإلكترونات و باعتماد 
+
+87
+00:07:40,730 --> 00:07:44,850
+على إيش بيصير في المحصلة للشحنة بيكون الجواب تبعنا
+
+88
+00:07:44,850 --> 00:07:50,970
+والله إذا الشحنة قلت بيكون الوضع ممتاز عندنا بتزيد 
+
+89
+00:07:50,970 --> 00:07:55,620
+الحمضية إذا الشحنة زادت بتقل الثبات .. قلّ الثبات
+
+90
+00:07:55,620 --> 00:08:00,220
+بتقل إيش؟ الحمضية .. واضح؟ فهذا هو inductive
+
+91
+00:08:00,220 --> 00:08:04,920
+effect الحقيقة المفروض هذا الكلام برضه يذكركم
+
+92
+00:08:04,920 --> 00:08:09,700
+بشغلة بس خلينا نلخصه شوية لما يكون عندكم شحنة 
+
+93
+00:08:09,700 --> 00:08:14,760
+سالبة .. شحنة سالبة و نيجي نقول إنه حطينا electron
+
+94
+00:08:14,760 --> 00:08:17,860
+withdrawing effect .. electron withdrawing 
+
+95
+00:08:17,860 --> 00:08:23,780
+group شو بتعمل في الشحنة السالبة؟ افهموا معايا هاي
+
+96
+00:08:23,780 --> 00:08:28,880
+بده ألخصلكم يعني لما يكون عندي negative charge
+
+97
+00:08:28,880 --> 00:08:34,520
+شحنة سالبة يا بيكون عندي electron withdrawing
+
+98
+00:08:34,520 --> 00:08:39,640
+group يعني مجموعة بتسحب الإلكترونات يا مجموعة 
+
+99
+00:08:39,640 --> 00:08:45,800
+بتعطي إلكترونات donating group الآن إذا في عندي 
+
+100
+00:08:45,800 --> 00:08:50,020
+electron withdrawing group شو بده يصير للشحنة؟
+
+101
+00:08:50,020 --> 00:08:51,060
+بدها
+
+102
+00:08:58,160 --> 00:09:04,360
+الشحنة السالبة بتبدأ تزيد طبعا أنتم عارفين أن ال
+
+103
+00:09:04,360 --> 00:09:10,680
+stability علاقة عكسية مع الشحنة
+
+104
+00:09:10,680 --> 00:09:15,340
+بناء على ذلك لو أنا هنا بحكي the charge decrease
+
+105
+00:09:15,340 --> 00:09:20,260
+إذا بدأت أقول هنا ال stability شو بدي أقول على ال
+
+106
+00:09:20,260 --> 00:09:21,360
+stability increase
+
+107
+00:09:24,600 --> 00:09:33,100
+loss of stability هنا تزيد هنا تتخلص إذا الشحنة
+
+108
+00:09:33,100 --> 00:09:36,240
+السالبة لما بنحط جنبها electron withdrawing group
+
+109
+00:09:36,240 --> 00:09:40,420
+بتزيد ثباتها لما نحط جنبها electron donating group
+
+110
+00:09:40,420 --> 00:09:46,720
+بتزيد تركيزها بتقل ثباتها هذا الكلام متعلق بإيش؟
+
+111
+00:09:46,720 --> 00:09:49,180
+بشحنة سالبة مثل هذا المثال
+
+112
+00:09:51,690 --> 00:09:56,850
+احنا عشان نأكد الكلام مر عليكم شغلة شبيهة لكن 
+
+113
+00:09:56,850 --> 00:10:02,970
+شحنة موجبة تكون أسلوب وقت وين ما مر عليّ الشحنة 
+
+114
+00:10:02,970 --> 00:10:07,990
+الموجبة إذا بتذكروا؟ في ال carbocation في ال
+
+115
+00:10:07,990 --> 00:10:11,830
+carbocation ال tertiary هتلاحظوا أن التأثير هنا
+
+116
+00:10:11,830 --> 00:10:17,730
+هيصير عكسي يعني لما تأخذوا هذا CH3
+
+117
+00:10:18,750 --> 00:10:24,550
+CH3 CH3 CH3
+
+118
+00:10:24,550 --> 00:10:28,030
+CH3
+
+119
+00:10:28,030 --> 00:10:28,370
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+120
+00:10:28,370 --> 00:10:31,050
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+121
+00:10:31,050 --> 00:10:31,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+122
+00:10:31,770 --> 00:10:31,870
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+123
+00:10:31,870 --> 00:10:33,050
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+124
+00:10:33,050 --> 00:10:34,070
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+125
+00:10:34,070 --> 00:10:40,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+126
+00:10:40,790 --> 00:10:44,870
+CH3
+
+127
+00:10:44,870 --> 00:10:52,700
+CH3 لاحظوا هنا عندي شحنة موجبة لما أسحب منها 
+
+128
+00:10:52,700 --> 00:10:58,900
+إلكترونات، شو بيصير للموجب؟ بيزيد، بيزيد لأن أنا 
+
+129
+00:10:58,900 --> 00:11:02,200
+قاعد بشيل إلكترونات، كل ما بشيل الإلكترونات، كل ما 
+
+130
+00:11:02,200 --> 00:11:05,900
+بشيل السالب، شو بعمل في الموجب؟ بيزيد، إذا الإلكترون
+
+131
+00:11:05,900 --> 00:11:13,260
+و الـdrawing groups they increase the charge بناء 
+
+132
+00:11:13,260 --> 00:11:18,040
+على ذلك، شو بيعملوا في ال stability؟ مباشرة لما 
+
+133
+00:11:18,040 --> 00:11:23,640
+بداجي أقول stability بتصير decrease فلو عندي
+
+134
+00:11:23,640 --> 00:11:30,060
+carbon cation و جنبه مثلا هنا ثلاث ذرات كلور أو مثل 
+
+135
+00:11:30,060 --> 00:11:35,650
+حملة كلور أو حملة فلور ثباته بيقلّ واضح؟ الآن لو عندي 
+
+136
+00:11:35,650 --> 00:11:39,310
+electron donating group positive بحط عليه 
+
+137
+00:11:39,310 --> 00:11:44,230
+إلكترونات شو بده يصير فيه؟ بتعدل .. بتعدل .. بتقلّش
+
+138
+00:11:44,230 --> 00:11:48,990
+.. و احنا إذا ال charge هنا decrease و ال
+
+139
+00:11:48,990 --> 00:11:54,810
+stability increase هذا الكلام اللي مر علينا لما
+
+140
+00:11:54,810 --> 00:11:58,070
+حكينا على ال carbocation قلنا ليش ال tertiary
+
+141
+00:11:58,070 --> 00:12:03,880
+carbocation is stable؟ لأنه فيه Electron donating
+
+142
+00:12:03,880 --> 00:12:08,040
+groups مجموعات بتعطي إلكترونات فهذه اللي بتعطي
+
+143
+00:12:08,040 --> 00:12:13,240
+إلكترونات شو بتعمل في positive charge؟ بتقلل؟ الـ
+
+144
+00:12:13,240 --> 00:12:18,540
+positive charge واضح؟ هذا هو اللي بنسميه inductive
+
+145
+00:12:18,540 --> 00:12:23,380
+effect و اللي بنفسر فيه ليش ال tertiary بيوت 
+
+146
+00:12:23,380 --> 00:12:28,080
+اللكحول حمضيته أقل من الإيثانول مثلا و ليش الـ
+
+147
+00:12:28,080 --> 00:12:31,920
+trifluoroethanol حمضيته أكثر من الإيثانول لأن مرة 
+
+148
+00:12:31,920 --> 00:12:37,440
+عندنا electron donation هنا في إعطاء إلكترونات
+
+149
+00:12:38,230 --> 00:12:41,430
+وبالتالي زيادة الشحنة هنا في سحب الإلكترونات
+
+150
+00:12:41,430 --> 00:12:44,070
+وبالتالي تقليل الشحنة اللي هي الشحنة أشهر بتكون
+
+151
+00:12:44,070 --> 00:12:50,390
+سالبة سالبة ال O minus هنا في ال carbocation الموجب
+
+152
+00:12:50,390 --> 00:12:54,950
+بس احنا راجعنالكم الموضوعين مع بعض حتى تكون عندكم
+
+153
+00:12:54,950 --> 00:13:00,230
+صورة كلية و أنا يمكن بقى أعتبر فهم هذا الجزء أو 
+
+154
+00:13:00,230 --> 00:13:04,770
+هذه الجزئية الصغيرة المتعلقة بالشحنات يعني تقريباً
+
+155
+00:13:04,770 --> 00:13:10,160
+أساس كبير جداً في فهم كل ال organic chemistry يعني
+
+156
+00:13:10,160 --> 00:13:12,880
+اللي بده يكون فاهم organic chemistry كويس و ليش 
+
+157
+00:13:12,880 --> 00:13:16,540
+بتصير الحركات و ما إلى ذلك بده يعرف إنه في نهاية 
+
+158
+00:13:16,540 --> 00:13:22,520
+التفاعلات قصة شحنات و الشحنات دائماً ساعه نحو زيادة 
+
+159
+00:13:22,520 --> 00:13:28,120
+الشحنات ولا تقليلها؟ تقليل، واضح؟ يعني أول ما تيجي
+
+160
+00:13:28,120 --> 00:13:31,200
+تقولوا التفاعل عمالكوا قاعدين بتقولوا positive
+
+161
+00:13:31,200 --> 00:13:33,700
+بيجي بها جمعة negative أو negative بيجي بها جمعة
+
+162
+00:13:33,700 --> 00:13:36,580
+positive لما negative و positive هاجموا مع بعض، شو
+
+163
+00:13:36,580 --> 00:13:44,790
+بيعملوا في الشحنات؟ بيقللوها، مظبوط ولا لا؟ 
+
+164
+00:13:44,790 --> 00:13:48,670
+إذن
+
+165
+00:13:48,670 --> 00:13:52,670
+هدول المثالين اللي هنا الـacidic بتاعتهم، بنفسرها
+
+166
+00:13:52,670 --> 00:13:56,670
+على الـinductive effect الآن لو إجينا على الفينول،
+
+167
+00:13:56,670 --> 00:14:00,710
+اتطلعوا معنا الفينول، بنلاحظ أنه more more acidic
+
+168
+00:14:00,710 --> 00:14:07,890
+than إيثانول، يعني الإيثانول 15 pKa الفينول 10
+
+169
+00:14:07,890 --> 00:14:14,550
+الـ Nitrophenol 7 صار حمض أكثر الـ 
+
+170
+00:14:14,550 --> 00:14:20,830
+Trinitrophenol هذا بيصير .. بيسموه حمض يعني 
+
+171
+00:14:20,830 --> 00:14:25,240
+بيسموه بكريك أسيد يعني بيبطلوا يسموه alcohol طلعوا
+
+172
+00:14:25,240 --> 00:14:31,000
+إيش بيسموه؟ acid طب إيش السبب هنا؟ السبب بالفينول
+
+173
+00:14:31,000 --> 00:14:35,620
+بشكل أساسي هو ال resonance effect إنه لما بيصير 
+
+174
+00:14:35,620 --> 00:14:39,280
+عندي هنا شحنة سالبة، بتنتقل هذه الشحنة السالبة
+
+175
+00:14:39,280 --> 00:14
+
+201
+00:16:46,040 --> 00:16:49,020
+localization of the negative charge أنه negative
+
+202
+00:16:49,020 --> 00:16:54,900
+charge تكون موزعة localization ثابتة بمكان مش
+
+203
+00:16:54,900 --> 00:17:05,520
+location موقع موضع موضع موضع
+
+204
+00:17:05,520 --> 00:17:08,720
+موضع موضع موضع موضع موضع موضع موضع موضع موضع موضع
+
+205
+00:17:08,720 --> 00:17:08,860
+موضع موضع موضع موضع موضع موضع موضع موضع موضع موضع
+
+206
+00:17:08,860 --> 00:17:10,400
+موضع موضع موضع موضع موضع
+
+207
+00:17:27,930 --> 00:17:33,430
+أو نقول مثلا الـ Trifluoroethanol is more acidic
+
+208
+00:17:33,430 --> 00:17:36,670
+than ethanol due to resonance effect لأ هناك 
+
+209
+00:17:36,670 --> 00:17:41,130
+inductive effect بتكون تميزه هدولة النوعين من
+
+210
+00:17:41,130 --> 00:17:46,010
+التأثير اللي هم ال resonance effect و ال inductive
+
+211
+00:17:46,010 --> 00:17:52,150
+effect الآن لاحظوا معنى لو صار عندي مجموعة نيترو
+
+212
+00:17:52,150 --> 00:18:00,140
+الحامضية بتزيد أكتر وأكثر واضح؟ يعني ال BKA كانت 
+
+213
+00:18:00,140 --> 00:18:07,080
+للفينول عشرة لنيتروفينول حسب الجدول سبعة تقريبا طب
+
+214
+00:18:07,080 --> 00:18:10,620
+إيش اللي موجود في النيتروفينول؟ النيتروفينول في
+
+215
+00:18:10,620 --> 00:18:14,700
+عندي resonance يعني هي ال negative موجودة مرة هنا
+
+216
+00:18:14,700 --> 00:18:19,770
+موجودة مرة هنا موجودة هنا موجودة بتتنقل كمان على ال
+
+217
+00:18:19,770 --> 00:18:24,330
+oxygen و بنفس الوقت رأس المجموعة ال nitro بيعمل
+
+218
+00:18:24,330 --> 00:18:28,190
+عندي positive هنا هذا ال positive شو بيعمل في ال
+
+219
+00:18:28,190 --> 00:18:34,130
+negative؟ سحب فهنا حقيقة في ال nitrophenol أنا في
+
+220
+00:18:34,130 --> 00:18:38,610
+عندي two effects في عندي resonance charge بصرا لها
+
+221
+00:18:38,610 --> 00:18:41,770
+resonance و بنفس الوقت في عندي طرف موجة بالطرف
+
+222
+00:18:41,770 --> 00:18:46,460
+الموجة بإيش دائما؟ بده يسحب السالب فصار عندي خليط
+
+223
+00:18:46,460 --> 00:18:51,820
+من resonance effect و inductive effect طبعا تخيلوا
+
+224
+00:18:51,820 --> 00:18:57,820
+لو صار عندي مش نيترو واحدة تري نيتروفينو المركبات
+
+225
+00:18:57,820 --> 00:19:01,560
+بيصير very acidic يعني ال بيكرك أسد لونه أصفر غامق
+
+226
+00:19:01,560 --> 00:19:05,080
+لو انكب على الأيدي أو شيء زي هيك أو على الملابس
+
+227
+00:19:05,080 --> 00:19:11,830
+بيحرجها واضح؟ بيصير حامضي، بينما ال Ethanol لأ يعني
+
+228
+00:19:11,830 --> 00:19:16,490
+لو أي طالبة نفترض فيكم وإيجي على جزء من ملابسها
+
+229
+00:19:16,490 --> 00:19:21,030
+شوية مادة عضوية فيها لون وعلى السريع راحت غسلتها
+
+230
+00:19:21,030 --> 00:19:25,350
+بشوية Ethanol، ما بتخربش الملابس، مش فيها شيء، بس
+
+231
+00:19:25,350 --> 00:19:28,570
+ال Bacric Acid لأ بيحرج الإيد
+
+232
+00:19:35,700 --> 00:19:39,500
+تقريبا هذه أمثلة تأكيدية على الـ electron
+
+233
+00:19:39,500 --> 00:19:44,100
+withdrawing groups لاحظوا هنا بنقول لما يكون عندي
+
+234
+00:19:44,100 --> 00:19:50,680
+ثلاثة كلور مثلا مع الاثانول بيكون more acidic than
+
+235
+00:19:50,680 --> 00:19:56,920
+the chloroethanol more acidic than الاثانول
+
+236
+00:19:56,920 --> 00:20:01,180
+itself كل هذا ال effect due to إيش؟ inductive
+
+237
+00:20:01,180 --> 00:20:05,840
+effect زي ما أنتم شايفينه هنا المقارنة inductive
+
+238
+00:20:05,840 --> 00:20:13,700
+effect الآن بشكل عام الثيول
+
+239
+00:20:13,700 --> 00:20:19,960
+الذين فيهم السلفر بدل الأكسجين هم أسود أكتر من
+
+240
+00:20:19,960 --> 00:20:25,780
+الألكوهول يعني لما بتكونوا تعملوا مقارنة RSH أو ROH
+
+241
+00:20:25,780 --> 00:20:30,920
+يعني بتقولوا Ethyl OH الاثانول أو Ethyl SH اللي هو
+
+242
+00:20:30,920 --> 00:20:37,750
+الثيو إيثانول أن هو بيكون more acidic السبب أنه لما
+
+243
+00:20:37,750 --> 00:20:41,370
+تفقد ال H بتظهر ال negative charge على الكبريت
+
+244
+00:20:41,370 --> 00:20:45,910
+والكبريت أكبر .. بتذكروا ال acidity في ال group
+
+245
+00:20:45,910 --> 00:20:50,390
+بتنزل لتحت كل ما المجموعة كبرت كل ما كانت أقدر على
+
+246
+00:20:50,390 --> 00:20:55,790
+حمل الشحنة لما أخذتو ال binary acids زي HCl وH2O
+
+247
+00:20:55,790 --> 00:20:59,410
+و HF وما إلى ذلك اتذكروا مع ال acidity في الجدول
+
+248
+00:20:59,410 --> 00:21:02,790
+الدوري كانت تزيد بهذا ..
+
+249
+00:21:04,390 --> 00:21:08,810
+بهذا الشكل وكنا نفسر السبب بال electronegativity
+
+250
+00:21:08,810 --> 00:21:12,910
+وبهذا الشكل وكنا نفسر السبب بال size كنا هنا نقول
+
+251
+00:21:12,910 --> 00:21:18,290
+السبب ال size وهنا السبب ال electronegativity
+
+252
+00:21:20,100 --> 00:21:24,760
+طبعا هنا ال oxygen تحت منه ال sulfur .. ال oxygen
+
+253
+00:21:24,760 --> 00:21:29,840
+تحت منه ال sulfur عشان هيك ال thyols they are more
+
+254
+00:21:29,840 --> 00:21:35,100
+acidic than alcohols و ال thyophenols they are
+
+255
+00:21:35,100 --> 00:21:40,040
+more acidic than phenols واضح؟ طبعا اللي بده
+
+256
+00:21:40,040 --> 00:21:45,110
+يقارنه المفروض يقارنه إيش؟ الأشياء المتشابهة هذا
+
+257
+00:21:45,110 --> 00:21:51,470
+مبدأ عام دائما في العلوم لما بتعملوا مقارنات ما حدش
+
+258
+00:21:51,470 --> 00:21:57,850
+عمره يعمل المقارنات بين الأشياء غير المتشابهة واضح
+
+259
+00:21:57,850 --> 00:22:03,150
+يعني اتطلعوا أنتم مثلا في الرياضة في الرياضة لما
+
+260
+00:22:03,150 --> 00:22:06,910
+بيجوا بيعملوا بطولات بيعملوا بطولة بيسموها بطولة
+
+261
+00:22:06,910 --> 00:22:12,350
+الأشبال بظبط ولا لأ؟ وبيعملوا بطولة بيسموها البطولة
+
+262
+00:22:12,350 --> 00:22:16,550
+الأولمبية الشباب الصغار شوية وبيعملوا بطولة اللي
+
+263
+00:22:16,550 --> 00:22:20,650
+هي بطولة الفريق الأول فكل مجموعة بيقارنوها مع
+
+264
+00:22:20,650 --> 00:22:26,190
+المجموعة المناظرة لها بس ما بيجوا يعملوا بطولة
+
+265
+00:22:26,190 --> 00:22:32,390
+أشبال يلعبوهم مع ناس كبار كلام مش منطقي طبعا معظم
+
+266
+00:22:32,390 --> 00:22:38,760
+البطولات في 99% منها بتلاقوا بطولات الرجال وبطولات
+
+267
+00:22:38,760 --> 00:22:44,720
+النساء .. ما شوفتش أنا بحياتي ممكن مباراة كورة قدم
+
+268
+00:22:44,720 --> 00:22:48,040
+إلا إذا Fantasy بس كانت بين فريق الرجال وفريق
+
+269
+00:22:48,040 --> 00:22:53,810
+النساء لكن بتلاقي دوري لإيش للنساء فالمقارنات دائما
+
+270
+00:22:53,810 --> 00:22:57,330
+أشياء زي بعض فلما أنا ببدأ أقارن بحط هنا R وهنا R
+
+271
+00:22:57,330 --> 00:23:02,610
+بقول ال RSH is more acidic than ROH بحط أنا AR و
+
+272
+00:23:02,610 --> 00:23:08,270
+أنا AR ال ARSH أكتر من ال AROH هنا بقدر أعطي جواب
+
+273
+00:23:08,270 --> 00:23:13,150
+بسهولة واضح؟ بقدر أعطي جواب بسهولة هذه القوة في ال
+
+274
+00:23:13,150 --> 00:23:17,190
+acidity بترتب عليها خواص كيميائية معنى خواص
+
+275
+00:23:17,190 --> 00:23:22,840
+كيميائية تفاعلات واضح؟ معنى خواص كيميائية تفاعلات
+
+276
+00:23:22,840 --> 00:23:28,880
+reactions ببساطة أنه لو أنا أخدت ROH الكحول بده
+
+277
+00:23:28,880 --> 00:23:33,480
+أفعله مع ال sodium hydroxide which is a strong
+
+278
+00:23:33,480 --> 00:23:39,220
+base رغم أنه هذه strong base لكن ال الكحول very
+
+279
+00:23:39,220 --> 00:23:46,210
+weak acid وبناء على ذلك ما بصيرش تفاعل يعني ما بتفعلش
+
+280
+00:23:46,210 --> 00:23:49,370
+ال alcohol مع ال sodium hydroxide كان ممكن أنتم
+
+281
+00:23:49,370 --> 00:23:52,690
+إيش اللي بتتوقعوا أنه يعطينا RO minus and A plus
+
+282
+00:23:52,690 --> 00:23:58,210
+بس مع ال sodium hydroxide ال alcohol ما بتفعلش واضح؟
+
+283
+00:23:58,210 --> 00:24:04,950
+بينما الـ thioalcohols بتعاملوا كأنهم acids RSH زي
+
+284
+00:24:04,950 --> 00:24:11,070
+NAOH حمض زي قاعدة ملح زي دماغ RS minus and A plus
+
+285
+00:24:11,070 --> 00:24:16,290
+هذا الملح زي H2O معادلة الحمض والقاعدة المعروفة
+
+286
+00:24:16,290 --> 00:24:22,580
+عندكم ليس اتفاعل ال RSH مع ال sodium hydroxide أكتر
+
+287
+00:24:22,580 --> 00:24:26,500
+من ال ROH، ال ROH ما تفعلش بالمرة السبب أن هو more
+
+288
+00:24:26,500 --> 00:24:32,640
+acidic than ال alcohol فالثيولز، الثيولز بنقول
+
+289
+00:24:32,640 --> 00:24:36,460
+عنهم they react with sodium hydroxide producing
+
+290
+00:24:36,460 --> 00:24:41,000
+salt and water however alcohols they don't react
+
+291
+00:24:41,000 --> 00:24:41,480
+with
+
+292
+00:24:44,170 --> 00:24:48,670
+واضح؟ رغم أن الـ Sodium Hydroxide عبارة عن قاعدة
+
+293
+00:24:48,670 --> 00:24:55,590
+قوية لكن ما زال مش قادر يسحب البروتون من الحامض لأن
+
+294
+00:24:55,590 --> 00:25:00,390
+هذا الحامض ضعيف الآن بيظل شغلة أنه زي ما بيقولوا
+
+295
+00:25:00,390 --> 00:25:06,610
+وفوق كل ذي علم عليم يعني هذا ال alcohol الحامض
+
+296
+00:25:06,610 --> 00:25:11,330
+الضعيف لو جبت له قاعدة أقوى من ال sodium hydroxide
+
+297
+00:25:11,330 --> 00:25:14,830
+يعني very strong base لاحظوا التعبير تبعي أنا بقول
+
+298
+00:25:14,830 --> 00:25:18,880
+ال sodium hydroxide is strong base أنا بدي أجيب له
+
+299
+00:25:18,880 --> 00:25:23,580
+very strong base يقدر يسحب منه البروتون ال very
+
+300
+00:25:23,580 --> 00:25:28,240
+strong base يا بيكون ال sodium يا بيكون الصوديوم
+
+301
+00:25:28,240 --> 00:25:32,600
+هيدرايد هدول they are stronger bases than sodium
+
+302
+00:25:32,600 --> 00:25:37,220
+hydroxide فال ROH مع الصوديوم أو مع الصوديوم
+
+303
+00:25:37,220 --> 00:25:44,380
+هيدرايد ROH بلس هنا مش يساوي بلس بلس NA بيعطيلي R
+
+304
+00:25:44,380 --> 00:25:49,560
+O minus NA plus أعطاني الملح واضح طبعا زاد
+
+305
+00:25:49,560 --> 00:25:56,100
+هيدروجين في الحالتين إذا أنا ممكن أكون اللي
+
+306
+00:25:56,100 --> 00:26:01,920
+بنسميها الكوكسايد سولتز هذه إيش اسمها؟ الكل اكسوجين
+
+307
+00:26:01,920 --> 00:26:08,980
+الكوكسايد الكوكسايد سولتز من خلال التفاعل مع very
+
+308
+00:26:08,980 --> 00:26:13,400
+strong base الكوكسايد يعني لو أجيت مثلا قلت بدي
+
+309
+00:26:13,400 --> 00:26:20,700
+CH3 O minus and A plus هذا المركب شو اسمه؟ Sodium
+
+310
+00:26:21,740 --> 00:26:26,260
+ميثوكسايد زي ما كنا لما يعني نشوف أي مركب لو كان
+
+311
+00:26:26,260 --> 00:26:30,580
+أسيتيت كنا نقول صوديوم أسيتيت هذا إيش بيكون اسمه
+
+312
+00:26:30,580 --> 00:26:38,400
+صوديوم ميثوكسايد فهذه المجموعة لما تكون مثل
+
+313
+00:26:38,400 --> 00:26:44,120
+ميثوكسايد لما تكون إيثل لما تكون فينل فينوكسايد
+
+314
+00:26:44,120 --> 00:26:48,200
+فينوكسايد يعني لو كان عندكم فينل O minus
+
+315
+00:26:56,450 --> 00:27:03,610
+Sodium phenoxide من الفينول طبعا
+
+316
+00:27:03,610 --> 00:27:07,450
+لو بدي أخد اسم عام لكل ال الكلي جروب فاسميهم
+
+317
+00:27:07,450 --> 00:27:14,550
+الكوكسايدز الكوكسايدز مثل ميثوكسايدز إيثوكسايدز
+
+318
+00:27:14,550 --> 00:27:15,710
+بروبوكسايدز
+
+319
+00:27:19,470 --> 00:27:26,470
+شو بتصير اسمها؟ الكوكسايد هو المجموعة العامة،
+
+320
+00:27:26,470 --> 00:27:32,710
+واضح؟ فالآن ال الكوكسايد ال RO minus مع الصوديوم
+
+321
+00:27:32,710 --> 00:27:37,830
+بيتكون من خلال التفاعل مع ال NaOH ولا مع ال NA
+
+322
+00:27:37,830 --> 00:27:44,970
+أو ال NaH إذا الكوكسايد لا يمكن أن يتم تصويره من
+
+323
+00:27:44,970 --> 00:27:50,290
+خلال تفاعل الكوكسايد مع الصوديوم هيدروكسايد واضح؟
+
+324
+00:27:50,290 --> 00:27:52,930
+مرات الطلاب بيلتقط ويقولوا من و أنه السؤال بنيجي
+
+325
+00:27:52,930 --> 00:27:56,830
+بنقول لهم الله Sodium ethoxide can be formed from
+
+326
+00:27:56,830 --> 00:28:01,010
+the reaction of ethanol with sodium hydroxide لأ
+
+327
+00:28:01,010 --> 00:28:04,970
+it can be formed from the reaction of ethanol with
+
+328
+00:28:04,970 --> 00:28:11,150
+sodium itself يا Sodium يا Sodium Hydride اللي هم
+
+329
+00:28:11,150 --> 00:28:17,370
+very strong bases بس ما بصيرش مع Sodium Hydroxide
+
+330
+00:28:19,820 --> 00:28:23,800
+طبعا، يجب أن يكون واضح عندكم .. يجب أن يكون واضح
+
+331
+00:28:23,800 --> 00:28:28,080
+عندكم إن هذه المجموعة اللي باينة على اللوح أضعف
+
+332
+00:28:28,080 --> 00:28:34,660
+تشي فيها الـ ROH واضح؟ الـ ROH هو اللي ما بتفعلش
+
+333
+00:28:34,660 --> 00:28:43,320
+مع الـ NaOH ما فيش تفاعل ROH مع الـ NaOH ما فيش
+
+334
+00:28:43,320 --> 00:28:46,440
+تفاعل بينما التلاتة هدول
+
+335
+00:28:51,760 --> 00:29:00,260
+AROH كلهم مع الـ NaOH بتفعل وبيعطوا الأملاح
+
+336
+00:29:00,260 --> 00:29:05,800
+المناظرة RS minus Na plus أو ARS minus Na plus أو
+
+337
+00:29:05,800 --> 00:29:11,700
+ARO minus Na plus يعني لما نحط فينول مع سوديوم
+
+338
+00:29:11,700 --> 00:29:16,980
+هيدروكسيد بيعطينا سوديوم فينوكسيد زي الميه فين الـ
+
+339
+00:29:16,980 --> 00:29:22,590
+OH مثلا فينول زاد NaOH بيعطينا فين ال O minus NA
+
+340
+00:29:22,590 --> 00:29:29,350
+plus زاد H2O حمض زاد قاعدة ملح زاد ماء إذن الوحيد
+
+341
+00:29:29,350 --> 00:29:32,830
+من هدول الأربعة اللي بتفعلش مع ال sodium hydroxide
+
+342
+00:29:32,830 --> 00:29:43,750
+وهو الأضعف فيهم اللي هو ال ROH تعبناكم؟
+
+343
+00:29:47,430 --> 00:29:52,490
+وهو الأضعف إذا بدنا نقرأها بقراءة .. برواية قالون
+
+344
+00:29:52,490 --> 00:29:57,790
+عن نافع كيف بنقولها؟ وهو بالسكون بس اللي بيقرأوه
+
+345
+00:29:57,790 --> 00:30:02,930
+بالسكون بالسكون برواية أبي عمرو البصري وبرواية
+
+346
+00:30:02,930 --> 00:30:06,030
+قالون عن نافع قراءة أبي عمرو البصري وبرواية قالون
+
+347
+00:30:06,030 --> 00:30:11,190
+عن نافع وهو العزيز والحكيم واضح؟ بس بحفظ عن عاصم
+
+348
+00:30:11,190 --> 00:30:18,330
+كيف بتقرأوها؟ وهو وهو معكم أينما كنتم وهو وفهو
+
+349
+00:30:18,330 --> 00:30:26,030
+ولا هو هدول بيجوا بالضمة عند حافظه بيجوا بالسكون
+
+350
+00:30:26,030 --> 00:30:32,670
+نرجع لل alcohol زمان تعون التربية قالوا لنا لازم
+
+351
+00:30:32,670 --> 00:30:40,810
+ترايحوا الطلاب شوية إذا حسيتوهم تعبوا preparation
+
+352
+00:30:40,810 --> 00:30:42,190
+of ethanol
+
+353
+00:30:45,280 --> 00:30:49,920
+على أي حال .. هذا الـ Ethanol الحقيقة بيمثل ..
+
+354
+00:30:49,920 --> 00:30:56,060
+بيمثل مشكلة الـ Ethanol بيمثل مشكلة ليش بيمثل
+
+355
+00:30:56,060 --> 00:31:01,940
+مشكلة الـ Ethanol؟ لأن الـ Ethanol زيه .. خليني
+
+356
+00:31:01,940 --> 00:31:06,020
+أشابه بالظبط زيه .. زي السكين السكين لابد من
+
+357
+00:31:06,020 --> 00:31:10,740
+وجودها في المطبخ مظبوط ولا لأ؟ والسكين في ذات
+
+358
+00:31:10,740 --> 00:31:16,370
+الوقت قاتلة يعني لو واحد بده يستعمل السكين لغير
+
+359
+00:31:16,370 --> 00:31:19,790
+الغرض الأساسي اللي هو غرض التقطيع والأشياء اللي
+
+360
+00:31:19,790 --> 00:31:23,890
+في المطبخ هذه بيروح بيستعملها بجريمة نكراء، الآن
+
+361
+00:31:23,890 --> 00:31:29,250
+هل بدنا نغضب على .. بدنا نغضب على السكين؟ ولا
+
+362
+00:31:29,250 --> 00:31:32,590
+بدنا نغضب على الفرد اللي بيستعمل السكين استعمال
+
+363
+00:31:32,590 --> 00:31:36,830
+خاطئ على الفرد؟ وهذا بالظبط الـ Ethanol الـ
+
+364
+00:31:36,830 --> 00:31:41,970
+Ethanol اللي هو الكحول الأساسي اللي يوجد في الخمر
+
+365
+00:31:43,120 --> 00:31:48,500
+واضح؟ الآن وبنفس الوقت ال ethanol هو المذيب
+
+366
+00:31:48,500 --> 00:31:52,800
+الأساسي الذي تقوم عليه الصناعة الكيميائية بمعنى
+
+367
+00:31:52,800 --> 00:31:57,860
+أنا لغرض الصناعة الكيميائية محتاج ال ethanol و
+
+368
+00:31:57,860 --> 00:32:03,940
+محتاجه يكون متوفر ومحتاجه يكون رخيص وبذات الوقت
+
+369
+00:32:03,940 --> 00:32:09,100
+إذا بدأت أقول ال ethanol للشرب مباشرة بيعمل اللي
+
+370
+00:32:09,100 --> 00:32:14,790
+هو الإسكار والخمر خمر الدنيا مش فيها إيثانول ولا
+
+371
+00:32:14,790 --> 00:32:19,990
+لأ؟ أنهي الخمر اللي مش فيها إيثانول؟ الخمر الآخر
+
+372
+00:32:19,990 --> 00:32:25,590
+اللي مش فيها الكحول؟ والآية إيش بتقول؟ لا فيها غول
+
+373
+00:32:25,590 --> 00:32:33,310
+ولا معناه .. الغول هو إيش؟ لأ الغول هو الكحول
+
+374
+00:32:33,310 --> 00:32:36,810
+لما إن شاء الله بتتخرج واحدة منكم وبتروح
+
+401
+00:34:42,770 --> 00:34:43,590
+يسمموه
+
+402
+00:34:46,070 --> 00:34:49,150
+صاروا يسمموا الـ Ethanol تبع الصناعة إذا بدك تشرب،
+
+403
+00:34:49,150 --> 00:34:52,510
+بدك تشرب من الغالي فالـ Ethanol تبع الصناعة
+
+404
+00:34:52,510 --> 00:34:56,330
+بيسمموه، بيسمموه بإيش؟ بالـ Methanol الـ Methanol
+
+405
+00:34:56,330 --> 00:35:01,250
+مادة سامة تؤدي للعمى بس بنضيف عليه شوية Methanol
+
+406
+00:35:01,250 --> 00:35:07,450
+بس الـ Ethanol، بيضيفوا عليه Methanol، بيصير مسمم
+
+407
+00:35:07,450 --> 00:35:12,750
+أو بالتالي، لو أي ناس من .. انقطع أو ييجي يشربوا 
+
+408
+00:35:12,750 --> 00:35:15,810
+Ethanol من المعمل، مابنفعش، بتسممه، بيأثر على ..
+
+409
+00:35:16,930 --> 00:35:21,030
+بشكل أساسي على عيون عندهم و بيقولوا أن أكثر ناس
+
+410
+00:35:21,030 --> 00:35:25,210
+اتأثروا بالكلام الجيش الألماني لما انقطع و شربوا
+
+411
+00:35:25,210 --> 00:35:29,150
+أشياء فيها ميثانول في النهاية و اتأذوا بعينيهم
+
+412
+00:35:29,150 --> 00:35:35,700
+واضح؟ فهذه النقطة الأولى في الموضوع أنكم تعرفوا أن
+
+413
+00:35:35,700 --> 00:35:40,220
+الاثانول سلاح ذو حدين، في الخمر حرام، بس في
+
+414
+00:35:40,220 --> 00:35:44,060
+الصناعة لابد منه، يعني هو الـ solvent اللي بنشتري
+
+415
+00:35:44,060 --> 00:35:47,700
+فيه التفاعلات، يعني احنا حتى في الجامعة الإسلامية 
+
+416
+00:35:47,700 --> 00:35:51,060
+لا نضيع سرا لما نقولكم بنشتري الاثانول بالبراميل
+
+417
+00:35:57,680 --> 00:36:02,460
+هو الوسط اللي بنعمل فيه التفاعلات، يعني لابد منه،
+
+418
+00:36:02,460 --> 00:36:09,310
+لابد منه، واضح؟ الآن الاثانول كيف بيحضروه؟ بيحضروه
+
+419
+00:36:09,310 --> 00:36:13,750
+بالتخمير، بنجيب السكريات و بواقي القصب أو النشويات
+
+420
+00:36:13,750 --> 00:36:17,730
+و ما إلى ذلك و بيعملوا إيش؟ تخمير التخمير بإيش؟
+
+421
+00:36:17,730 --> 00:36:22,830
+بكائنات حية دقيقة، خميرة هنا بيجينا التناقض جديد
+
+422
+00:36:24,160 --> 00:36:28,720
+أنه إحنا بنقولكوا لما بتعملوا مزرعة بكتيريا بعد ما
+
+423
+00:36:28,720 --> 00:36:32,220
+تخلصوا غسله بالإيثانول، الإيثانول بقتل البكتيريا،
+
+424
+00:36:32,220 --> 00:36:35,600
+مظبوط ولا لأ؟ والبكتيريا كائنات حية دقيقة، بعد
+
+425
+00:36:35,600 --> 00:36:41,420
+شوية بنيجي بنقولكوا الإيثانول بتحضر من البكتيريا
+
+426
+00:36:41,420 --> 00:36:45,920
+ومن الخميرة، طب ما هو بقتل البكتيريا والخميرة،
+
+427
+00:36:45,920 --> 00:36:52,780
+كيف بدو يصير؟ أنه أنا بقدر أعمل تخميرو أحضره وهو 
+
+428
+00:36:52,780 --> 00:37:00,000
+القاتل بيقولوا أن التخمير بس لحد نسبة حوالي 12% بحد
+
+429
+00:37:00,000 --> 00:37:05,160
+أقصى 15% بتطلع الكحول بعد هيك لو بدت تزيد نسبة
+
+430
+00:37:05,160 --> 00:37:10,200
+الكحول بتقتل الكائنات الحياة الدقيقة ملاحظين؟ طيب
+
+431
+00:37:10,200 --> 00:37:17,990
+لو شفتوا خمرة فيها نسبة الاثانول 70% كيف بدو يصير
+
+432
+00:37:17,990 --> 00:37:22,050
+هذا الكلام؟ هل تم هذا الـ Ethanol وصلت لنسبة 70%
+
+433
+00:37:22,050 --> 00:37:26,890
+منه بالتخمير؟ التخمير، لحد 4-5% الكائنات الحياة 
+
+434
+00:37:26,890 --> 00:37:32,910
+بتبقى عايشة وبتعمل التخمير، لحد 12% نقول بعد هيك،
+
+435
+00:37:32,910 --> 00:37:37,290
+إذا زاد الكحول، إذا عملت كحول أكثر، هتقتل نفسها
+
+436
+00:37:38,110 --> 00:37:42,810
+لحد 12% لـ 15% بعد ذلك يتوقف التخمير طب لو كان
+
+437
+00:37:42,810 --> 00:37:46,530
+فيه خمور من الأنواع اللي فيها الاثانول عالي 40% و
+
+438
+00:37:46,530 --> 00:37:51,630
+50% و 60% الويسكي والـ .. كيف هذا الكلام بيصير؟
+
+439
+00:37:51,630 --> 00:37:55,630
+بيضيفوا إيثانول إضافة عليها يعني لما بيعملوا ال
+
+440
+00:37:55,630 --> 00:38:01,210
+fermentation التخمير للفواكه بيصير لحد بواقي
+
+441
+00:38:01,210 --> 00:38:04,290
+الفواكه وما إلى ذلك مع الكحول ده بيمثل الخمرة
+
+442
+00:38:04,290 --> 00:38:11,270
+لكن هم بيزيدوا نسبة الـ Ethanol بيضيفوا إضافة بس
+
+443
+00:38:11,270 --> 00:38:16,990
+مافيش تخمير بيوصلنا لـ 70 و 80% Ethanol فالخمور ذات
+
+444
+00:38:16,990 --> 00:38:22,310
+المحتوى العالي من الكحول بيكون الكحول إيش ماله؟
+
+445
+00:38:22,310 --> 00:38:26,030
+أضيف إليها إضافة من الخارج
+
+446
+00:38:29,090 --> 00:38:33,510
+بقطره .. اه اه نفس الخمور لما بده ملكة الماء أنا
+
+447
+00:38:33,510 --> 00:38:37,610
+كيف بعمل .. يعني أنا بعمل التخمير وبعدين بعمل
+
+448
+00:38:37,610 --> 00:38:40,910
+تقطير .. التقطير بيطلق للإيثانول لحاله .. التقطير
+
+449
+00:38:40,910 --> 00:38:44,370
+بيطلق للإيثانول لحاله .. هنا بدكوا تنتبهوا لنقطة
+
+450
+00:38:44,370 --> 00:38:48,790
+برضه أرجو أنكم تكونوا فاهمينها كويس أنه إذا
+
+451
+00:38:48,790 --> 00:38:53,410
+التخمير بيطلّع لي إيثانول، يعني لو حطيت عنب أو
+
+452
+00:38:53,410 --> 00:38:58,730
+غيره أربع، خمس أيام، تلت أيام بيظبد زي ما بيقولوا
+
+453
+00:38:58,730 --> 00:39:03,050
+بيطلّع رغوة وبيحول لإيثانول وبالتالي بيتحول إلى
+
+454
+00:39:03,050 --> 00:39:09,070
+خمر طيب، الآن السؤال بزمّه بعد تلت أيام صار في نسبة
+
+455
+00:39:09,070 --> 00:39:13,390
+اتناشف في المية كحول يا ترى لو إجيت قولت بعد ساعة
+
+456
+00:39:14,620 --> 00:39:21,080
+ما بيصيرش .. بتكون فيه نسبة صغيرة جدا لكن لو سألنا 
+
+457
+00:39:21,080 --> 00:39:25,340
+نفسنا هل إحنا بنشرب عصير العنب بعد ساعة وبعد ساعة
+
+458
+00:39:25,340 --> 00:39:30,600
+ونص وبعد ساعتين أكيد آه الناس بتعصر عنب و
+
+459
+00:39:30,600 --> 00:39:34,560
+بتشربه وحلال ومعروف بالشرع أنه بنعصر العناب و
+
+460
+00:39:34,560 --> 00:39:39,060
+بنشرب العناب بنعصر اليوم بنشربه بس بعد تلت أيام لأ
+
+461
+00:39:40,370 --> 00:39:43,650
+وعشان هيك بيقولوا الخمر ما خمر العقل لأن لحظة ما
+
+462
+00:39:43,650 --> 00:39:47,450
+بيصل لدرجة عالية من التخمر، درجة عالية من الكحول،
+
+463
+00:39:47,450 --> 00:39:53,270
+بيصير حرام لكن أي فاكهة طبيعية، لو بدي أتركها، أي
+
+464
+00:39:53,270 --> 00:39:57,450
+عصير، كوكتيل طبيعي، بدي أتركه في الهواء شوية،
+
+465
+00:39:57,450 --> 00:40:00,770
+بيبدأ يطلع كحول، لو تركته أربع، خمس أيام وحطيت له
+
+466
+00:40:00,770 --> 00:40:04,030
+ظروف مناسبة من الحرارة، كل أنواع الكوكتيل بتصير 
+
+467
+00:40:04,030 --> 00:40:10,270
+خمرة ولذلك لابد من إيش؟ من الحذر الآن العلماء حددوا
+
+468
+00:40:10,270 --> 00:40:15,590
+نسبة قالوا إن هناك نسبة تخمر طبيعي أنا لا أستغني
+
+469
+00:40:15,590 --> 00:40:25,070
+عنها إذا كانت نسبة الـ alcohol أقل من less than أقل
+
+470
+00:40:25,070 --> 00:40:33,110
+من 0.5% مش 0.1%  نص الـ 0.1% 
+
+471
+00:40:33,110 --> 00:40:37,670
+إذا كانت أقل من 0.05% لجيتها في
+
+472
+00:40:37,670 --> 00:40:44,070
+عصير لا يعتبر مسكر ويمكن أن يشرب تعتبر نسبة طبيعية
+
+473
+00:40:44,070 --> 00:40:47,730
+هذا تخمر طبيعي لابد منه يعني لو بعد ما تقصروا
+
+474
+00:40:47,730 --> 00:40:51,600
+العنب أربع خمس دقايق هتشوفوا هيك نسبة النسبة 
+
+475
+00:40:51,600 --> 00:40:58,940
+المسموحة أن التخمر الطبيعي يكون 0
+
+476
+00:40:58,940 --> 00:41:02,560
+.001 إيثانول 
+
+477
+00:41:15,950 --> 00:41:20,950
+فالنسبة أو الحد اللي حطّه علماء المسلمين مع الفقهاء
+
+478
+00:41:20,950 --> 00:41:25,970
+مع تبعون الأغذية أن الكحول مش لازم يزيد في العصائر
+
+479
+00:41:25,970 --> 00:41:30,650
+الطبيعية عن 0.05% طب عن 0.05% نسبة
+
+480
+00:41:30,650 --> 00:41:33,910
+التخمر طبيعية، تنسوش أن الخمرة بنحكي عن عشرة
+
+481
+00:41:33,910 --> 00:41:39,210
+وخمستاشر وعشرين والأنواع التانية ستين واربعين واضح؟
+
+482
+00:41:39,210 --> 00:41:44,130
+لكن هذه نسبة تخمر طبيعي، لا تستغنى عنها الحياة
+
+483
+00:41:44,130 --> 00:41:48,310
+يعني، غصب عننا، مش بخاطرنا بتصير في العواصير، مش
+
+484
+00:41:48,310 --> 00:41:51,890
+إحنا .. اه بس برضه العلماء بيقولوا شغلة، إن هذا 
+
+485
+00:41:51,890 --> 00:41:55,750
+تكون نسبة طبيعية، يعني مش أنا أضيف كحول، لأن
+
+486
+00:41:55,750 --> 00:41:58,670
+الكحول بيعتبرونه نجس، يعني لو أنا بدي أضيفه، نو طلق
+
+487
+00:41:59,450 --> 00:42:04,710
+لكن أنه عصير وعمل نسبة صغيرة أقل من هذه النسبة
+
+488
+00:42:04,710 --> 00:42:11,830
+مقبول، لكن أنه يضاف متعمدًا، لأ، واضح؟ هذا بالنسبة
+
+489
+00:42:11,830 --> 00:42:17,830
+للإيثانول، بنحضره من التخمر، بهيك تقريبا بننهي
+
+490
+00:42:17,830 --> 00:42:19,490
+المحاضرة اليوم
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..15d0935f470f05da6ceff5814d97af7ba304b3c3
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o_postprocess.srt
@@ -0,0 +1,1960 @@
+1
+00:00:07,730 --> 00:00:12,390
+المحاضرة الماضية بعد ما اتكلمنا عن الـalcohols
+
+2
+00:00:12,390 --> 00:00:18,230
+والتسميتهم والـhydrogen bonding والخواص بدأنا في
+
+3
+00:00:18,230 --> 00:00:21,270
+موضوع كثير مهم في موضوع الـalcohols اللي هو
+
+4
+00:00:21,270 --> 00:00:26,590
+الموضوع الحامضية الـacidity طبعا حكينا احنا شغلة
+
+5
+00:00:26,590 --> 00:00:33,430
+ان الـacidity حسب تعريف لوري برونستيد الـacid
+
+6
+00:00:33,430 --> 00:00:39,450
+بروتون دونر بدو يفقد بروتونفبيصف عندنا اللي هو
+
+7
+00:00:39,450 --> 00:00:44,990
+الايون السالب والبروتون واضح؟ الان المشكلة ان
+
+8
+00:00:44,990 --> 00:00:51,870
+الحمض يكون قوي في قداش الايون السالب يكون ثابتيعني
+
+9
+00:00:51,870 --> 00:00:55,570
+المشكلة مش في البروتون، لأنه لو أخدنا عشر أحماض،
+
+10
+00:00:55,570 --> 00:00:58,630
+العشر أحماض هيفكروا نفس البروتون، نفس البروتون، بس
+
+11
+00:00:58,630 --> 00:01:04,810
+في كل حالة هيظل جزء سالب مختلف عن الجزء التاني،
+
+12
+00:01:04,810 --> 00:01:08,950
+واضح؟ فبناء على ذلك، لما أنا بقارن قوة الأحماض،
+
+13
+00:01:08,950 --> 00:01:14,000
+مابطلعش على البروتونأنا بتطلع على الجزء السالب هل
+
+14
+00:01:14,000 --> 00:01:18,680
+يا ترى الجزء السالب اللي عندى قادر يتحمل الشحنة
+
+15
+00:01:18,680 --> 00:01:23,700
+يحملها ولا لأ يعني مثلا لو بدنا بس كمراجعة بسيطة
+
+16
+00:01:23,700 --> 00:01:31,080
+هتذكركوا في hbr و hcl التانين بيعملواالـ H Plus
+
+17
+00:01:31,080 --> 00:01:35,720
+لكن هنا ما سيحدث لدي PR minus هنا ما سيحدث لدي CL
+
+18
+00:01:35,720 --> 00:01:39,460
+minus إذا مشكلتي أنا الـ PR minus والـ CL minus
+
+19
+00:01:39,460 --> 00:01:45,000
+مين أقدر فيهم على حمل الشحنة السالبة هو اللي بيحدد
+
+20
+00:01:45,000 --> 00:01:48,640
+قوة الحامض طبعا في هذه الحالة اللي لاحظوا أن الـ
+
+21
+00:01:48,640 --> 00:01:54,380
+HPR أقوى وقالوا السبب أن حجم ذرة البروم أكبر من
+
+22
+00:01:54,380 --> 00:01:58,790
+حجم ذرة الكلور فالحجم الكبيربقدر يحمل أكتر من
+
+23
+00:01:58,790 --> 00:02:03,650
+الصغير، الولد الكبير بحمل ثقل أكتر من إيش؟ من
+
+24
+00:02:03,650 --> 00:02:08,850
+الطفل الصغير، الآن هنا نفس الأشي، لو بدي أقارن
+
+25
+00:02:08,850 --> 00:02:15,210
+مثلا، هاي عندي مجموعة ال goals مقارنين بالمية، HO,
+
+26
+00:02:15,330 --> 00:02:20,930
+H, HO مثل HO مثل HO attributed، زي ما بتلاحظوا كل
+
+27
+00:02:20,930 --> 00:02:25,500
+الجزء اللي موجود هنا هو اللي بده يمثل إيشالجزء
+
+28
+00:02:25,500 --> 00:02:30,840
+السالب وهذه ستظهر على شكل الـ H بلس طبعا هو الكحول
+
+29
+00:02:30,840 --> 00:02:35,520
+ليس ايوني عشان الكلام يكون واضح الكحول ليس ايونيك
+
+30
+00:02:35,520 --> 00:02:39,960
+كومباوند يعني ماحدش يتخيل ان الكحول زي NA بلس CL
+
+31
+00:02:39,960 --> 00:02:44,180
+ماينوس لأ الكحول عبارة عن موليكيولار كومباوند لكن
+
+32
+00:02:44,180 --> 00:02:50,200
+لما بده يتعامل كاسد بيفقد الـ H بلس واضح؟ وبيظهر
+
+33
+00:02:50,200 --> 00:02:55,820
+عند الجزء السالبفقوة الأحمد مرتبطة بإيش؟ بهذا
+
+34
+00:02:55,820 --> 00:03:00,500
+الجزء السالب حتى نفس الأشهر لو بدكم اتقارنوا ال
+
+35
+00:03:00,500 --> 00:03:05,180
+filons كل هذا يمثل الـ H plus كل دول يمثلوا الجزء
+
+36
+00:03:05,180 --> 00:03:08,820
+السالب وين فيه قدرة على حمل الجزء السالب بيكون
+
+37
+00:03:08,820 --> 00:03:16,140
+المركب أقوى إذا بدي أجي أطلع بوضوحبلاحظ إنه
+
+38
+00:03:16,140 --> 00:03:21,420
+المنطقة الأولى تقريباً كنا تمثل أحمار ضعيفة الميّه
+
+39
+00:03:21,420 --> 00:03:25,600
+زي الـ Methanol نوعا ما زي الـ Ethanol شوية صغيرة
+
+40
+00:03:25,600 --> 00:03:29,300
+بتفرق في الـ tertiary-butanol مافيش عندي مشكلة وين
+
+41
+00:03:29,300 --> 00:03:33,500
+بيبدأ يصير تغير و الحامض بيبدأ يصير أقوى كتير
+
+42
+00:03:33,500 --> 00:03:40,760
+هنطلع على هذا الحامض CH3CH2OH
+
+43
+00:03:40,760 --> 00:03:47,450
+Trifluoroethanol بنسميهإيتالون لكن مقدل فيه تلت
+
+44
+00:03:47,450 --> 00:03:53,410
+ذرات هيدروجين بإيش ب floor لو بدي أرسم هذا لحاله
+
+45
+00:03:53,410 --> 00:03:59,490
+أرسم الايون السالب تبعه هاي CH2 O minus بعدين C
+
+46
+00:03:59,490 --> 00:04:07,090
+floor floor floor إيش اللي خلّى هذا يصير حامض قوي؟
+
+47
+00:04:08,150 --> 00:04:12,170
+إنه ال floor electron with drawing group واضح ال
+
+48
+00:04:12,170 --> 00:04:16,150
+electronegativity تبعتها عالية بناء على ذلك صح أنا
+
+49
+00:04:16,150 --> 00:04:23,190
+عندي هنا في مشكلة لكن في عندي ساحب لهذه المشكلة في
+
+50
+00:04:23,190 --> 00:04:26,470
+عندي شحنة سالبة في مجموعات بتسحب الشحنة السالبة
+
+51
+00:04:26,470 --> 00:04:31,270
+إذا ماضلتش الشحنة السالبة مركزة هناواضح هذا ال
+
+52
+00:04:31,270 --> 00:04:34,890
+effect هو مساعدة في حميل الشحنة السالبة هو اللي
+
+53
+00:04:34,890 --> 00:04:40,750
+سمناه إيش inductive effect إذا إحنا بنقدر نقول
+
+54
+00:04:40,750 --> 00:04:47,190
+الآن أن الـ trifluoroethanol is more acidic than
+
+55
+00:04:47,190 --> 00:04:53,700
+ethanol due to inductive effectهيجي شيء يحمل فيها،
+
+56
+00:04:53,700 --> 00:04:58,140
+يساعد في حملها، يسحب هذه الشحنة هذا عبارة عن
+
+57
+00:04:58,140 --> 00:05:02,860
+inductive effect طبعا أكيد بيصير واضح عندكم تماما
+
+58
+00:05:02,860 --> 00:05:06,360
+لو كنتوا تعملوا مقارنات لو كنتوا بدأوا تقارن
+
+59
+00:05:06,360 --> 00:05:09,700
+المركب في floor واحدة و تلاتة floor، انه more
+
+60
+00:05:09,700 --> 00:05:14,720
+acidic التلاتة floor لو كنتوا بدأوا تقارن المركب
+
+61
+00:05:14,720 --> 00:05:19,240
+في تلاتة floor أو المركب اللي فيه تلاتة chlorine
+
+62
+00:05:20,740 --> 00:05:23,720
+الـ floor أعلى الـ floor الـ electronegativity له
+
+63
+00:05:23,720 --> 00:05:30,120
+أعلى كل هذا هو عبارة عن ال inductive effect الأن
+
+64
+00:05:30,120 --> 00:05:36,580
+لاحظوا معي ال inductive effect زي ما ممكن يكون
+
+65
+00:05:36,580 --> 00:05:45,690
+مساعدة ممكن أنه يكونالو أثر عكسي واضح؟ يعني مظبوط
+
+66
+00:05:45,690 --> 00:05:49,810
+إحنا بنجيب ناس يساعدونا وممكن يساعدونا بس في ناس
+
+67
+00:05:49,810 --> 00:05:55,610
+بنجيبهم يساعدوا ويحلوا المشكلة بزيدوا .. إيش بيقول
+
+68
+00:05:55,610 --> 00:06:03,170
+المثل؟ بزيدوا الطينة باللأ أو جيبناك يا عبد المعين
+
+69
+00:06:03,170 --> 00:06:09,810
+اتعين لجناك؟ إذا ممكن هذا الأثر إذا مركب يكون أثر
+
+70
+00:06:09,810 --> 00:06:15,930
+عكسيلو كانت المجموعة اللي هنا مش بتسحب بتعطيه
+
+71
+00:06:15,930 --> 00:06:22,110
+واضح؟ لو كانت المجموعة اللي هنا مش مجموعة ساحبة
+
+72
+00:06:22,110 --> 00:06:27,570
+للإلكترونات بتخفف المشكلة مجموعة معطية للإلكترونات
+
+73
+00:06:27,570 --> 00:06:32,330
+بتزيد المشكلة لو بدنا نتخيل وين الكلام ممكن يصير
+
+74
+00:06:32,330 --> 00:06:37,070
+لو شيلنا هذا ال floor و حطينا بداله CH3
+
+75
+00:06:39,400 --> 00:06:43,600
+الـ method غالبا بتعمل كـ electron donating group
+
+76
+00:06:43,600 --> 00:06:51,040
+CH3 الآن هنا الـ CH3 إيش اللي بتعمله؟ بتعطي
+
+77
+00:06:51,040 --> 00:06:54,500
+إلكترونات مش بتزيد إلكترونات إذا زادت الشحنة
+
+78
+00:06:54,500 --> 00:07:00,000
+السالبة عنده بناء على ذلك هذا المركب اللي زي هذا
+
+79
+00:07:00,000 --> 00:07:04,260
+أو لو كانت الـ OH مباشرة هنا يعني إحنا موجود عندنا
+
+80
+00:07:04,260 --> 00:07:08,810
+المركب اللي فيه الـ OHموجودة هيك مباشرة يعني ال O
+
+81
+00:07:08,810 --> 00:07:13,770
+minus اللي هو التيرتشاريبيوتانول
+
+82
+00:07:13,770 --> 00:07:17,810
+اتطلعوا عليه هذا اللي حامل تلاتة CH3 ايش صار لل
+
+83
+00:07:17,810 --> 00:07:26,850
+BKA تبعته صارت تمانتعش زادت ال BKA قلت ال acidity
+
+84
+00:07:26,850 --> 00:07:30,650
+الآن هنا ليش قلت ال acidity؟ برضه بسبب ال
+
+85
+00:07:30,650 --> 00:07:33,650
+inductive effect هو inductive effect سواء ال
+
+86
+00:07:33,650 --> 00:07:40,730
+inductive effect أخد أو اعطاءالإلكترونات و باعتماد
+
+87
+00:07:40,730 --> 00:07:44,850
+على إيش بيصير في المحصلة للشحنة بيكون الجواب تبعنا
+
+88
+00:07:44,850 --> 00:07:50,970
+والله إذا الشحنة جلت بيكون الوضع ممتاز عندنا بتزيد
+
+89
+00:07:50,970 --> 00:07:55,620
+الحمضية إذا الشحنة زادتبقل الثبات .. قل الثبات
+
+90
+00:07:55,620 --> 00:08:00,220
+بتقل إيش؟ الحامضية .. واضح؟ فهذا هو inductive
+
+91
+00:08:00,220 --> 00:08:04,920
+effect الحقيقة المفروض هذا الكلام برضه يذكركوا
+
+92
+00:08:04,920 --> 00:08:09,700
+بشغلة بس خلينا نلخصه شوية لما يكون عندكم شحنة
+
+93
+00:08:09,700 --> 00:08:14,760
+سالبة .. شحنة سالبة ونيجي نقول إنه حطينا electron
+
+94
+00:08:14,760 --> 00:08:17,860
+with a drawing effect .. electron with a drawing
+
+95
+00:08:17,860 --> 00:08:23,780
+group شو بتعمل في الشحنة السالبة؟أفهموا معايا هاي
+
+96
+00:08:23,780 --> 00:08:28,880
+بده ألخصلكوا يعني لما يكون عندي negative charge
+
+97
+00:08:28,880 --> 00:08:34,520
+شحنة سالبة يا بيكون عندي electron with drawing
+
+98
+00:08:34,520 --> 00:08:39,640
+group يعني مجموعة بتسحب الإلكترونات يا مجموعة
+
+99
+00:08:39,640 --> 00:08:45,800
+بتعطي إلكترونات donating group الآن إذا في عندي
+
+100
+00:08:45,800 --> 00:08:50,020
+electron with drawing group شو بده يصير للشحنة؟
+
+101
+00:08:50,020 --> 00:08:51,060
+بدها
+
+102
+00:08:58,160 --> 00:09:04,360
+الشحنة السالبة بدأ تزيد طبعا انتوا عارفين ان ال
+
+103
+00:09:04,360 --> 00:09:10,680
+stability علاقة عكسية مع الشحنة
+
+104
+00:09:10,680 --> 00:09:15,340
+بناء على ذلك لو انا هنا بحكي the charge decrease
+
+105
+00:09:15,340 --> 00:09:20,260
+اذا بدأت اقول هنا ال stability شو بدأ اقول على ال
+
+106
+00:09:20,260 --> 00:09:21,360
+stability increase
+
+107
+00:09:24,600 --> 00:09:33,100
+loss of stability هنا تزيد هنا تتخلص إذا الشحنة
+
+108
+00:09:33,100 --> 00:09:36,240
+السالبة لما بنحط جنبها electron withdrawal group
+
+109
+00:09:36,240 --> 00:09:40,420
+بزيد ثابتها لما نحط جنبها electron donating group
+
+110
+00:09:40,420 --> 00:09:46,720
+بزيد تركيزها بقل ثابتها هذا الكلام متعلق بإيش؟
+
+111
+00:09:46,720 --> 00:09:49,180
+بشحنة سالبة مثل هذا المثال
+
+112
+00:09:51,690 --> 00:09:56,850
+إحنا عشان نأكد الكلام مار عليكم شغلة شبيهة لكن
+
+113
+00:09:56,850 --> 00:10:02,970
+شحنة موجبة تكون أسلوب وقت وين مارت عليّ الشحنة
+
+114
+00:10:02,970 --> 00:10:07,990
+الموجبة إذا بتذكروا؟ في ال carbocation في ال
+
+115
+00:10:07,990 --> 00:10:11,830
+carbocation ال tertiary هتلاحظوا أن التأثير هنا
+
+116
+00:10:11,830 --> 00:10:17,730
+هيصير عكسي يعني لما تاخدوا هذا CH3
+
+117
+00:10:18,750 --> 00:10:24,550
+CH3 CH3 CH3
+
+118
+00:10:24,550 --> 00:10:28,030
+CH3
+
+119
+00:10:28,030 --> 00:10:28,370
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+120
+00:10:28,370 --> 00:10:31,050
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+121
+00:10:31,050 --> 00:10:31,770
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+122
+00:10:31,770 --> 00:10:31,870
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+123
+00:10:31,870 --> 00:10:33,050
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+124
+00:10:33,050 --> 00:10:34,070
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+125
+00:10:34,070 --> 00:10:40,790
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+126
+00:10:40,790 --> 00:10:44,870
+CH3
+
+127
+00:10:44,870 --> 00:10:52,700
+CH3لاحظوا هنا عندي شحنة موجبة لما أسحب منها
+
+128
+00:10:52,700 --> 00:10:58,900
+إلكترونات، شو بيصير للموجب؟ بزيد، بزيد لأن أنا
+
+129
+00:10:58,900 --> 00:11:02,200
+قاعد بشيل إلكترونات، كل ما بشيل الإلكترونات، كل ما
+
+130
+00:11:02,200 --> 00:11:05,900
+بشيل السلم، شو بعمل في الموجب؟ بزيد، إذا الإلكترون
+
+131
+00:11:05,900 --> 00:11:13,260
+و الـdrawing groups they increase the charge بناء
+
+132
+00:11:13,260 --> 00:11:18,040
+على ذلك، شو بيعملوا في ال stability؟مباشرة لما
+
+133
+00:11:18,040 --> 00:11:23,640
+بداجي أقول stability بتصير decrease فلو عندي
+
+134
+00:11:23,640 --> 00:11:30,060
+carbon كتاين و جنبه مثلا هنا تلت ذرات كلور أو مثل
+
+135
+00:11:30,060 --> 00:11:35,650
+حملة كلور أو حملة فلور ثباته بقلواضح؟ الان لو عندي
+
+136
+00:11:35,650 --> 00:11:39,310
+electron donating group positive بحط عليه
+
+137
+00:11:39,310 --> 00:11:44,230
+إلكترونات شو بده يصير فيه؟ بتعدل .. بتعدل .. بتقلش
+
+138
+00:11:44,230 --> 00:11:48,990
+.. و احنا إذا ال charge هنا decrease و ال
+
+139
+00:11:48,990 --> 00:11:54,810
+stability increase هذا الكلام اللي مار علينا لما
+
+140
+00:11:54,810 --> 00:11:58,070
+حكينا على ال carbocation قولنا ليش ال tertiary
+
+141
+00:11:58,070 --> 00:12:03,880
+carbocation is stable؟ لأنه فيهElectron donating
+
+142
+00:12:03,880 --> 00:12:08,040
+groups مجموعات بتعطي إلكترونات فهذه اللي بتعطي
+
+143
+00:12:08,040 --> 00:12:13,240
+إلكترونات شو بتعمل في positive charge؟ بتقلل؟الـ
+
+144
+00:12:13,240 --> 00:12:18,540
+positive charge واضح؟ هذا هو اللي بنسميه inductive
+
+145
+00:12:18,540 --> 00:12:23,380
+effect و اللي بنفسر فيه ليش الـ tertiary بيوت
+
+146
+00:12:23,380 --> 00:12:28,080
+الألكوهول حمضيته أقل من الإيثانول مثلا و ليش الـ
+
+147
+00:12:28,080 --> 00:12:31,920
+trifluoroethanol حمضيته أكتر من الإيثانول لأن مرة
+
+148
+00:12:31,920 --> 00:12:37,440
+عندنا electron donation هنا في إعطاء إلكترونات
+
+149
+00:12:38,230 --> 00:12:41,430
+وبالتالي زيادة الشحنة هنا في سحب الإلكترونات
+
+150
+00:12:41,430 --> 00:12:44,070
+وبالتالي تقليل الشحنة اللي هي الشحنة أشهر بتكون
+
+151
+00:12:44,070 --> 00:12:50,390
+سالبةسالبة ال O minus هنا في ال carbocation الموجب
+
+152
+00:12:50,390 --> 00:12:54,950
+بس احنا راجعنالكم الموضوعين مع بعض حتى تكون عندكم
+
+153
+00:12:54,950 --> 00:13:00,230
+صورة كلية و انا يمكن بقى اعتبر فهم هذا الجزء او
+
+154
+00:13:00,230 --> 00:13:04,770
+هذه الجزئية الصغيرة المتعلقة بالشحنات يعني تقريبا
+
+155
+00:13:04,770 --> 00:13:10,160
+اساس كبير جدا في فهم كل ال organ ال chemistryيعني
+
+156
+00:13:10,160 --> 00:13:12,880
+اللي بده يكون فاهم organ ال chemistry كويس و ليش
+
+157
+00:13:12,880 --> 00:13:16,540
+بتصير الحركات و ما إلى ذلك بده يعرف إنه في نهاية
+
+158
+00:13:16,540 --> 00:13:22,520
+التفاعلات قصة شحنات و الشحنات دائما ساعه نحو زيادة
+
+159
+00:13:22,520 --> 00:13:28,120
+الشحنات ولا تقليلها؟ تقليل، واضح؟ يعني أول ما تيجي
+
+160
+00:13:28,120 --> 00:13:31,200
+تقولوا التفاعل عمالكوا قاعدين بتقولوا positive
+
+161
+00:13:31,200 --> 00:13:33,700
+بيجي بها جمعة negative أو negative بيجي بها جمعة
+
+162
+00:13:33,700 --> 00:13:36,580
+positive لما negative و positive هاجموا مع بعض، شو
+
+163
+00:13:36,580 --> 00:13:44,790
+بيعملوا في الشحنات؟بقللوها، مظبوط ولا لا؟
+
+164
+00:13:44,790 --> 00:13:48,670
+إذن
+
+165
+00:13:48,670 --> 00:13:52,670
+هدول المثالين اللي هنا الـacidic بتاعتهم، بنفسرها
+
+166
+00:13:52,670 --> 00:13:56,670
+على الـductal defect الآن لو إجينا على الفينول،
+
+167
+00:13:56,670 --> 00:14:00,710
+اتطلعوا معنا الفينول، بنلاحظ أنه more more acidic
+
+168
+00:14:00,710 --> 00:14:07,890
+than إيثانول، يعني الإيثانول 15 كسل الفينولعشرة
+
+169
+00:14:07,890 --> 00:14:14,550
+الـ Nitrophenol سبعة صار حامض أكتر الـ
+
+170
+00:14:14,550 --> 00:14:20,830
+Trinitrophenol هذا بيصير .. بيسموه حامض يعني
+
+171
+00:14:20,830 --> 00:14:25,240
+بيسموه بكريك أسد يعني بيبطلوا يسموه alcoholطلعوا
+
+172
+00:14:25,240 --> 00:14:31,000
+إيش بيسموه؟ acid طب إيش السبب هنا؟ السبب بالفينول
+
+173
+00:14:31,000 --> 00:14:35,620
+بشكل أساسي هو ال resonance effect إنه لما بيصير
+
+174
+00:14:35,620 --> 00:14:39,280
+عندي هنا شحنة سالبة، بتتنجل هذه الشحنة السالبة
+
+175
+00:14:39,280 --> 00:14:41,820
+وهذا اللي إحنا بنشوفه في ال slide
+
+176
+00:14:47,350 --> 00:14:52,090
+هنا إذا بتتطلعوا على ال slide لما تكون المجموعة R
+
+177
+00:14:52,090 --> 00:14:57,190
+يعني ألفتك مافيش إمكانية resonance بنقول ال charge
+
+178
+00:14:57,190 --> 00:15:02,190
+localized يعني هذه الشحنة اللي هنا ثابت مكانها
+
+179
+00:15:02,190 --> 00:15:07,650
+الشحنة بتحب تكون localized ثابت مكانها ولا
+
+180
+00:15:07,650 --> 00:15:15,130
+delocalized بدها تكون delocalized تطلع عشان تثبت
+
+181
+00:15:15,130 --> 00:15:20,810
+مظبوط ولا لأطب قد تستغربوا أساسا هذه الفكرة
+
+182
+00:15:20,810 --> 00:15:26,330
+الأساسية في العقوبة البشرية يوم ما بيجوا بعقبوا
+
+183
+00:15:26,330 --> 00:15:32,710
+البني آدم في السجن بش بيقولوا he's arrested خليته
+
+184
+00:15:32,710 --> 00:15:38,360
+ثابت مش معطيه مكان يتحركأكبر عقوبة اللي قاعدين
+
+185
+00:15:38,360 --> 00:15:41,860
+يعاقبوا فيها والأسرة وما إلى ذلك أنكوا تخلوا
+
+186
+00:15:41,860 --> 00:15:46,340
+الإنسان ثابت في مكانه الإنسان بحب إنه إيش يتحرك
+
+187
+00:15:46,340 --> 00:15:50,760
+فبيقولوا arrested يعني خلاص ثبتت أنا مكانه مافيش
+
+188
+00:15:50,760 --> 00:15:56,660
+إمكانية يعني بيبطل ثابت فبيقول هنا لما تكون ال R
+
+189
+00:15:56,660 --> 00:16:01,520
+ألفاتيك ال charge is localized وعشان هيك هنا بتكون
+
+190
+00:16:01,520 --> 00:16:07,420
+الحمضية قليلة بينمافي الـ Phenol بإمكانكوا تطلعوا
+
+191
+00:16:07,420 --> 00:16:10,040
+هنا الـ Charge، ماعرفش إذا واضحة أو مضحة أكتر
+
+192
+00:16:10,040 --> 00:16:15,140
+باللون الأحمر، هذه الـ Charge عامالها بتتنقل، يعني
+
+193
+00:16:15,140 --> 00:16:18,400
+لما بنعمل حركة زي هيك و حركة صارت مرة محمولة على
+
+194
+00:16:18,400 --> 00:16:21,060
+الـ Oxygen، مرة على الـ Carbon هادى، مرة على الـ
+
+195
+00:16:21,060 --> 00:16:23,740
+Carbon هادى، مرة على الـ Carbon هادى، تماما زي
+
+196
+00:16:23,740 --> 00:16:26,740
+إنسان عنده ثقل و بيحمله مرة بالإيد اليمين و مرة
+
+197
+00:16:26,740 --> 00:16:32,340
+بالإشمالمظبوط ولا لأ؟ وبالتالي الشحنهانة أصبحت
+
+198
+00:16:32,340 --> 00:16:38,040
+موزعة هذا اللي بنسميه احنا resonance effect واضح؟
+
+199
+00:16:38,040 --> 00:16:42,360
+اذا ال phenols they are more acidic than alcohols
+
+200
+00:16:42,360 --> 00:16:46,040
+due to resonance effect ايش يعني resonance؟ دي
+
+201
+00:16:46,040 --> 00:16:49,020
+localization of the negative charge انه negative
+
+202
+00:16:49,020 --> 00:16:54,900
+charge تكون موزعة localization ثابتة بمكان مش
+
+203
+00:16:54,900 --> 00:17:05,520
+locationموقع موضع موضع موضع
+
+204
+00:17:05,520 --> 00:17:08,720
+موضع موضع موضع موضع موضع موضع موضع موضع موضع موضع
+
+205
+00:17:08,720 --> 00:17:08,860
+موضع موضع موضع موضع موضع موضع موضع موضع موضع موضع
+
+206
+00:17:08,860 --> 00:17:10,400
+موضع موضع موضع موضع موضع
+
+207
+00:17:27,930 --> 00:17:33,430
+أو نقول مثلا الـ Trifluoroethanol is more acidic
+
+208
+00:17:33,430 --> 00:17:36,670
+than ethanol due to resonance effect لأ هناك
+
+209
+00:17:36,670 --> 00:17:41,130
+inductive effect بتكون تميزه هدولة النوعين من
+
+210
+00:17:41,130 --> 00:17:46,010
+التأثير اللي هم ال resonance effect و ال inductive
+
+211
+00:17:46,010 --> 00:17:52,150
+effect الأن لاحظوا معنى لو صار عندي مجموعة نيترو
+
+212
+00:17:52,150 --> 00:18:00,140
+الحامضيةبتزيد أكتر و أكتر واضح؟ يعني ال BKA كانت
+
+213
+00:18:00,140 --> 00:18:07,080
+للفينول عشرة لنيتروفينول حسب الجدول سبعة تقريبا طب
+
+214
+00:18:07,080 --> 00:18:10,620
+إيش اللي موجود في النيتروفينول؟ النيتروفينول في
+
+215
+00:18:10,620 --> 00:18:14,700
+عندي resonance يعني هي ال negative موجودة مرة هان
+
+216
+00:18:14,700 --> 00:18:19,770
+موجودة مرة هان موجودة هان موجودةبتتنقل كمان على ال
+
+217
+00:18:19,770 --> 00:18:24,330
+oxygen و بنفس الوقت راس المجموعة ال nitro بيعمل
+
+218
+00:18:24,330 --> 00:18:28,190
+عندى positive هنا هذا ال positive شو بيعمل في ال
+
+219
+00:18:28,190 --> 00:18:34,130
+negative؟ سحب فهنا حقيقة في ال nitrophenol انا في
+
+220
+00:18:34,130 --> 00:18:38,610
+عندى two effects في عندى resonance charge بصرا لها
+
+221
+00:18:38,610 --> 00:18:41,770
+resonance و بنفس الوقت في عندى طرف موجة بالطرف
+
+222
+00:18:41,770 --> 00:18:46,460
+الموجة بإيش دائما؟بدو يسحب السالب فصار عندى خليط
+
+223
+00:18:46,460 --> 00:18:51,820
+من resonance effect و inductive effect طبعا تخيلوا
+
+224
+00:18:51,820 --> 00:18:57,820
+لو صار عندى مش نيترو واحدة تري نيتروفينو المراكب
+
+225
+00:18:57,820 --> 00:19:01,560
+بيصير very acidic يعنى ال بيكرك أسد لونه أصفر غامق
+
+226
+00:19:01,560 --> 00:19:05,080
+لو انكب على الأيدين أو اشي زي هيك أو على الملابس
+
+227
+00:19:05,080 --> 00:19:11,830
+بيحرجهاواضح؟ بيصير حامضي، بينما ال Ethanol لأ يعني
+
+228
+00:19:11,830 --> 00:19:16,490
+لو أي طالبة نفترض فيك و إيجي على جزء من ملابسها
+
+229
+00:19:16,490 --> 00:19:21,030
+شوية مادة عضوية فيها لون و ع السريع راحت غسلتها
+
+230
+00:19:21,030 --> 00:19:25,350
+بشوية Ethanol، مابتخربش الملابس، مش فيها شيء، بس
+
+231
+00:19:25,350 --> 00:19:28,570
+ال Bacric Acid لأ بيحرج الإيدة
+
+232
+00:19:35,700 --> 00:19:39,500
+تقريبا هذه أمثلة تأكيدية على الـ electron
+
+233
+00:19:39,500 --> 00:19:44,100
+withdrawing groups لاحظوا هنا بنقول لما يكون عندي
+
+234
+00:19:44,100 --> 00:19:50,680
+تلاتة كلور مثلا مع الاثانول بيكون more acidic than
+
+235
+00:19:50,680 --> 00:19:56,920
+the chloroethanol more acidic than الاثانول
+
+236
+00:19:56,920 --> 00:20:01,180
+itself كل هذا ال effect due to إيش؟ inductive
+
+237
+00:20:01,180 --> 00:20:05,840
+effect زي ما أنتوا شايفينههنا المقارنة inductive
+
+238
+00:20:05,840 --> 00:20:13,700
+effect الآن بشكل عام الثيول
+
+239
+00:20:13,700 --> 00:20:19,960
+الذين فيهم السلفر بدل الأكسجين هم أسود أكتر من
+
+240
+00:20:19,960 --> 00:20:25,780
+الألكوهول يعني لما بتكون تعملوا مقارنة RSH أو ROH
+
+241
+00:20:25,780 --> 00:20:30,920
+يعني بتقول Ethyl OH الاثانول أو Ethyl SH اللي هو
+
+242
+00:20:30,920 --> 00:20:37,750
+الثيو اثانولأن هو بيكون more acidic السبب أنه لما
+
+243
+00:20:37,750 --> 00:20:41,370
+تفقد ال H بتظهر ال negative charge على الكابريت
+
+244
+00:20:41,370 --> 00:20:45,910
+والكابريت أكبر .. بتذكروا ال acidity في ال group
+
+245
+00:20:45,910 --> 00:20:50,390
+بتنزل لتحت كل ما المجموعة كبرت كل ما كانت أقدر على
+
+246
+00:20:50,390 --> 00:20:55,790
+حمل الشحنة لما أخدتوا ال binary acids زي HCl وH2O
+
+247
+00:20:55,790 --> 00:20:59,410
+وHF وما إلى ذلك اتذكروا مع ال acidity في الجدول
+
+248
+00:20:59,410 --> 00:21:02,790
+الدوري كانت تزيد بهذا ..
+
+249
+00:21:04,390 --> 00:21:08,810
+بهذا الشكل و كنا نفسر السبب بال electronegativity
+
+250
+00:21:08,810 --> 00:21:12,910
+وبهذا الشكل و كنا نفسر السبب بال size كنا هنا نقول
+
+251
+00:21:12,910 --> 00:21:18,290
+السبب ال size و هنا السبب ال electronegativity
+
+252
+00:21:20,100 --> 00:21:24,760
+طبعا هنا ال oxygen تحت منه ال sulfur .. ال oxygen
+
+253
+00:21:24,760 --> 00:21:29,840
+تحت منه ال sulfur عشان هيك ال thyols they are more
+
+254
+00:21:29,840 --> 00:21:35,100
+acidic than alcohols و ال thyophenols they are
+
+255
+00:21:35,100 --> 00:21:40,040
+more acidic than phenols واضح؟ طبعا اللي بده
+
+256
+00:21:40,040 --> 00:21:45,110
+يقارنه المفروض يقارنه إيش؟الاشياء المتشابهة هذا
+
+257
+00:21:45,110 --> 00:21:51,470
+مبدأ عام دائما في العلوم لما بتعملوا مقارنات ماحدش
+
+258
+00:21:51,470 --> 00:21:57,850
+عمره يعمل المقارنات بين الأشياء غير المتشابهة واضح
+
+259
+00:21:57,850 --> 00:22:03,150
+يعني اتطلعوا انتوا مثلا في الرياضة في الرياضة لما
+
+260
+00:22:03,150 --> 00:22:06,910
+بيجوا بيعملوا بطولات بيعملوا بطولة بيسموها بطولة
+
+261
+00:22:06,910 --> 00:22:12,350
+الأشبالبظبط ولا لا؟ وبيعملوا بطولة بيسموها البطولة
+
+262
+00:22:12,350 --> 00:22:16,550
+الأولمبية الشباب الصغار شوية وبيعملوا بطولة اللي
+
+263
+00:22:16,550 --> 00:22:20,650
+هي بطولة الفريق الأول فكل مجموعة بيقارنوها مع
+
+264
+00:22:20,650 --> 00:22:26,190
+المجموعة المناغرة إلها بس مابيجوش يعملوا بطولة
+
+265
+00:22:26,190 --> 00:22:32,390
+أشبال يلعبوهم مع ناس أكبار كلام مش منطقي طبعا معظم
+
+266
+00:22:32,390 --> 00:22:38,760
+البطولات في 99% منها بتلاقوا بطولات الرجالوبطولات
+
+267
+00:22:38,760 --> 00:22:44,720
+النساء .. ماشوفتش انا بحياتي ممكن مباراة كورة قدم
+
+268
+00:22:44,720 --> 00:22:48,040
+إلا إذا Fantasy بس كانت بين فريق الرجال وفريق
+
+269
+00:22:48,040 --> 00:22:53,810
+النساء لكن بتلاقي دوري لإيشللنساء فالمقارنات دائما
+
+270
+00:22:53,810 --> 00:22:57,330
+أشياء زي بعض فلما أنا بدأ اقارن بحط هان R و هان R
+
+271
+00:22:57,330 --> 00:23:02,610
+بقول ال RSH is more acidic than ROH بحط انا AR و
+
+272
+00:23:02,610 --> 00:23:08,270
+انا AR ال ARSH اكتر من ال AROH هنا بقدر اعطي جواب
+
+273
+00:23:08,270 --> 00:23:13,150
+بسهولة واضح؟ بقدر اعطي جواب بسهولة هذه القوة في ال
+
+274
+00:23:13,150 --> 00:23:17,190
+acidity بترتب عليها خواص كيميائية معنى خواص
+
+275
+00:23:17,190 --> 00:23:22,840
+كيميائية تفاعلاتواضح؟ معنى خواصة كيميائية تفاعلات
+
+276
+00:23:22,840 --> 00:23:28,880
+reactions ببساطة أنه لو أنا أخدت ROH الكهول بده
+
+277
+00:23:28,880 --> 00:23:33,480
+أفعله مع ال sodium hydroxide which is a strong
+
+278
+00:23:33,480 --> 00:23:39,220
+base رغم أنه هذي strong base لكن ال الكهول very
+
+279
+00:23:39,220 --> 00:23:46,210
+weak acid وبناء على ذلك مابصيرش تفاعليعني مابتفعلش
+
+280
+00:23:46,210 --> 00:23:49,370
+ال alcohol مع ال sodium hydroxide كان ممكن انتوا
+
+281
+00:23:49,370 --> 00:23:52,690
+ايش اللي بتتوقعوا انه يعطينا RO minus and A plus
+
+282
+00:23:52,690 --> 00:23:58,210
+بس مع ال sodium hydroxide ال alcohol مابتفعلشواضح؟
+
+283
+00:23:58,210 --> 00:24:04,950
+بينما الـ thioalcohols بتعاملوا كأنهم acids RSH زي
+
+284
+00:24:04,950 --> 00:24:11,070
+NAOH حمض زي قاعدة ملح زي دماغ RS minus and A plus
+
+285
+00:24:11,070 --> 00:24:16,290
+هذا الملح زي H2O معدلة الحمض والقاعدة المعروفة
+
+286
+00:24:16,290 --> 00:24:22,580
+عندكم ليس اتفاعل ال RSH مع ال sodium hydroxideأكتر
+
+287
+00:24:22,580 --> 00:24:26,500
+من ال ROH، ال ROH ما تفعلش بالمرة السبب أن هو more
+
+288
+00:24:26,500 --> 00:24:32,640
+acidic than ال alcohol فالثيولز، الثيولز بنقول
+
+289
+00:24:32,640 --> 00:24:36,460
+عنهم they react with sodium hydroxide producing
+
+290
+00:24:36,460 --> 00:24:41,000
+salt and water however alcohols they don't react
+
+291
+00:24:41,000 --> 00:24:41,480
+with
+
+292
+00:24:44,170 --> 00:24:48,670
+واضح؟ رغم أن الـ Sodium Hydroxide عبارة عن مؤسسة
+
+293
+00:24:48,670 --> 00:24:55,590
+قوية لكن ما زال مش قادر يسحب لبروتونمن الحامض لأن
+
+294
+00:24:55,590 --> 00:25:00,390
+هذا الحامض ضعيف الآن بيظل شغلة انه زي ما بيقولوا
+
+295
+00:25:00,390 --> 00:25:06,610
+وفوق كل ذي علم عليم يعني هذا ال alcohol الحامض
+
+296
+00:25:06,610 --> 00:25:11,330
+الضعيف لو جبتله قاعدة أقوى من ال sodium hydroxide
+
+297
+00:25:11,330 --> 00:25:14,830
+يعني very strong base لاحظوا التعبير تبعي أنا بقول
+
+298
+00:25:14,830 --> 00:25:18,880
+ال sodium hydroxide isstrong base انا بدي اجيبله
+
+299
+00:25:18,880 --> 00:25:23,580
+very strong base يقدر يسحب منه البروتون ال very
+
+300
+00:25:23,580 --> 00:25:28,240
+strong base يا بيكون ال sodiumيا بيكون السوديوم
+
+301
+00:25:28,240 --> 00:25:32,600
+هيدرايد هدولة they are stronger bases than sodium
+
+302
+00:25:32,600 --> 00:25:37,220
+hydroxide فال ROH مع السوديوم أو مع السوديوم
+
+303
+00:25:37,220 --> 00:25:44,380
+هيدرايد ROH بلس هنا مش يساوي بلس بلس NA بيعطيلي R
+
+304
+00:25:44,380 --> 00:25:49,560
+O minus NA plus أعطاني الملح واضح طبعا زاد
+
+305
+00:25:49,560 --> 00:25:56,100
+هيدروجين في الحالتينأذا انا ممكن اكوّن اللي
+
+306
+00:25:56,100 --> 00:26:01,920
+بنسميها الكوكسايد سولتز هذه ايش اسمها الكل اكسوجين
+
+307
+00:26:01,920 --> 00:26:08,980
+الكوكسايد الكوكسايد سولتز من خلال التفاعل مع very
+
+308
+00:26:08,980 --> 00:26:13,400
+strong base الكوكسايد يعني لو اجيت مثلا قولت بدي
+
+309
+00:26:13,400 --> 00:26:20,700
+CH3 O minus and A plus هذا المركب شو اسمه؟ Sodium
+
+310
+00:26:21,740 --> 00:26:26,260
+ميثوكسايد زي ما كنا لما يعني نشوف أي مركب لو كان
+
+311
+00:26:26,260 --> 00:26:30,580
+أسيتيت كنا نقول صوديوم أسيتيت هذا إيش بيكون اسمه
+
+312
+00:26:30,580 --> 00:26:38,400
+صوديوم ميثوكسايد فهذه المجموعة لما تكون مثل
+
+313
+00:26:38,400 --> 00:26:44,120
+ميثوكسايد لما تكون إثل لما تكون فينل فينوكسايد
+
+314
+00:26:44,120 --> 00:26:48,200
+فينوكسايد يعني لو كان عندكم فينل O minus
+
+315
+00:26:56,450 --> 00:27:03,610
+Sodium phenoxide من الفينول طبعا
+
+316
+00:27:03,610 --> 00:27:07,450
+لو بدى اخد اسم عام لكل ال الكلي جروب فاسميهم
+
+317
+00:27:07,450 --> 00:27:14,550
+الكوكسايدز الكوكسايدز مثل ميثوكسايدز اثوكسايدز
+
+318
+00:27:14,550 --> 00:27:15,710
+بروبوكسايدز
+
+319
+00:27:19,470 --> 00:27:26,470
+شو بتصير اسمها؟ الكوكسايد الهو المجموعة العامة،
+
+320
+00:27:26,470 --> 00:27:32,710
+واضح؟ فالان ال الكوكسايد ال R O minus مع الصوديوم
+
+321
+00:27:32,710 --> 00:27:37,830
+بيتكون من خلال التفاعل مع ال N A O H ولا مع ال N A
+
+322
+00:27:37,830 --> 00:27:44,970
+او ال N A H اذا الكوكسايد لا يمكن ان يتم تصويره من
+
+323
+00:27:44,970 --> 00:27:50,290
+خلال تفاعل الكوكسايد مع الصوديوم الهيدروكسايدواضح؟
+
+324
+00:27:50,290 --> 00:27:52,930
+مرات الطلاب بيلتقم ويقولوا من وانها السؤال بنيجي
+
+325
+00:27:52,930 --> 00:27:56,830
+بنقولهم الله Sodium ethoxide can be formed from
+
+326
+00:27:56,830 --> 00:28:01,010
+the reaction of ethanol with sodium hydroxide لأ
+
+327
+00:28:01,010 --> 00:28:04,970
+it can be formed from the reaction of ethanol with
+
+328
+00:28:04,970 --> 00:28:11,150
+sodium itself يا Sodium يا Sodium Hydride اللي هم
+
+329
+00:28:11,150 --> 00:28:17,370
+very strong bases بس مابصيرش مع Sodium Hydroxide
+
+330
+00:28:19,820 --> 00:28:23,800
+طبعاً، يجب أن يكون واضح عندكم .. يجب أن يكون واضح
+
+331
+00:28:23,800 --> 00:28:28,080
+عندكم إن هذه المجموعة اللي باينة على اللوح أضعف
+
+332
+00:28:28,080 --> 00:28:34,660
+تشي فيها الـ ROH واضح؟ الـ ROH هو اللي ما بتفعلش
+
+333
+00:28:34,660 --> 00:28:43,320
+مع الـ NaOH مافيش تفاعل ROH مع الـ NaOH مافيش
+
+334
+00:28:43,320 --> 00:28:46,440
+تفاعل بينما التلاتة هدولة
+
+335
+00:28:51,760 --> 00:29:00,260
+AROH كلهم مع الـ NaOH بتفعل وبيعطوا الأملاح
+
+336
+00:29:00,260 --> 00:29:05,800
+المناظرة RS minus Na plus أو ARS minus Na plus أو
+
+337
+00:29:05,800 --> 00:29:11,700
+ARO minus Na plus يعني لما نحط فينول مع سوديوم
+
+338
+00:29:11,700 --> 00:29:16,980
+هيدروكسيد بيعطينا سوديوم فينوكسيد زي الميه فين الـ
+
+339
+00:29:16,980 --> 00:29:22,590
+OH مثلا فينولزاد NAOH بيعطينا فين ال O minus NA
+
+340
+00:29:22,590 --> 00:29:29,350
+plus زاد H2O حمض زاد قاعدة ملح زاد ماء إذن الوحيد
+
+341
+00:29:29,350 --> 00:29:32,830
+من هدول الأربع اللي بتفعلش مع ال sodium hydroxide
+
+342
+00:29:32,830 --> 00:29:43,750
+وهو الأضعف فيهم اللي هو ال ROH تعبناكم؟
+
+343
+00:29:47,430 --> 00:29:52,490
+و هو الأضعف إذا بدنا نقرأها بقراءة .. برواية قالون
+
+344
+00:29:52,490 --> 00:29:57,790
+عن نافع كيف بنقولها؟ و هو بالسكون بس اللي بيقرأوه
+
+345
+00:29:57,790 --> 00:30:02,930
+بالسكون بالسكون برواية أبو عمرو البصر و برواية
+
+346
+00:30:02,930 --> 00:30:06,030
+قالون عن نافع قراية أبو عمرو البصر و برواية قالون
+
+347
+00:30:06,030 --> 00:30:11,190
+عن نافع و هو العزيزو الحكيم واضح؟ بس بحفظ عن عاصم
+
+348
+00:30:11,190 --> 00:30:18,330
+كيف بتقرأوها؟ و هووهو معاكم أينما كنتم وهو وفهو
+
+349
+00:30:18,330 --> 00:30:26,030
+ولا هو هدولة بيجوا بالضمة عند حافظه بيجوا بالسكون
+
+350
+00:30:26,030 --> 00:30:32,670
+نرجع لل alcohol زمان تعون التربية قالولنا لازم
+
+351
+00:30:32,670 --> 00:30:40,810
+ترايحوا الطلاب شوية إذا حسيتهم تعبوا preparation
+
+352
+00:30:40,810 --> 00:30:42,190
+of ethanol
+
+353
+00:30:45,280 --> 00:30:49,920
+على أي حال .. هذا الـ Ethanol الحقيقة بيمثل ..
+
+354
+00:30:49,920 --> 00:30:56,060
+بيمثل مشكلة الـ Ethanol بيمثل مشكلة ليش بيمثل
+
+355
+00:30:56,060 --> 00:31:01,940
+مشكلة الـ Ethanol؟ لأن الـ Ethanol زيه .. خلّيني
+
+356
+00:31:01,940 --> 00:31:06,020
+أشابه بالظبط زيه .. زي السكينة السكينة لابد من
+
+357
+00:31:06,020 --> 00:31:10,740
+وجودها في المطبخ مظبوط ولا لأ؟ والسكينة في ذات
+
+358
+00:31:10,740 --> 00:31:16,370
+الوقت قاتلةيعني لو واحد بده يستعمل السكينة لغير
+
+359
+00:31:16,370 --> 00:31:19,790
+الغرض الأساسي اللي هو غرض التقطيع و الأشياء اللي
+
+360
+00:31:19,790 --> 00:31:23,890
+في المطبخ هذه بيروح بيستعملها بجريمة نكراء، الآن
+
+361
+00:31:23,890 --> 00:31:29,250
+هل بدنا نغضب على .. بدنا نغضب على السكينة؟ ولا
+
+362
+00:31:29,250 --> 00:31:32,590
+بدنا نغضب على الفرد اللي بيستعمل السكينة استعمال
+
+363
+00:31:32,590 --> 00:31:36,830
+خاطئ على الفرد؟ وهذا بالظبط الـ Ethanol الـ
+
+364
+00:31:36,830 --> 00:31:41,970
+Ethanol اللي هو الكحول الأساسي اللي يوجد في الخمر
+
+365
+00:31:43,120 --> 00:31:48,500
+واضح؟ الان و بنفس الوقت ال ethanol هو المذيب
+
+366
+00:31:48,500 --> 00:31:52,800
+الأساسي الذي تقوم عليه الصناعة الكيميائية بمعنى
+
+367
+00:31:52,800 --> 00:31:57,860
+أنا لغرض الصناعة الكيميائية محتاج ال ethanol و
+
+368
+00:31:57,860 --> 00:32:03,940
+محتاجه يكون متوفر و محتاجه يكون رخيص و بذات الوقت
+
+369
+00:32:03,940 --> 00:32:09,100
+إذا بدأتش أقول ال ethanol للشرب مباشرة بيعمل اللي
+
+370
+00:32:09,100 --> 00:32:14,790
+هو الإسكار و الخمرخمر الدنيا مش فيها إيثانول ولا
+
+371
+00:32:14,790 --> 00:32:19,990
+لأ؟ أنهي الخمر اللي مش فيها إيثانول؟ الخمر الآخر
+
+372
+00:32:19,990 --> 00:32:25,590
+اللي مش فيها الكحول؟ والآية إيش بتقول؟ لا فيها غول
+
+373
+00:32:25,590 --> 00:32:33,310
+ولا معناه .. الغول هو إيش؟ لأ الغول هو الالكحول
+
+374
+00:32:33,310 --> 00:32:36,810
+لما ان شاء الله بتتخرج واحدة منك و بتروح تدرس في
+
+375
+00:32:36,810 --> 00:32:42,890
+سعودية بتلاقي عنوان هذا الفصل مش الكحولاتالأغوال
+
+376
+00:32:42,890 --> 00:32:50,190
+أه الغول هو الكحول بالترجمة العربية الغول هو
+
+377
+00:32:50,190 --> 00:32:54,270
+الكحول وبالتالي هناك في الكتب المدرسية بيكونوا
+
+378
+00:32:54,270 --> 00:32:58,150
+كاتبين يوجد غول بنسبة كذا والأغوال وما إلى ذلك
+
+379
+00:32:58,150 --> 00:33:03,350
+بمعنى الكحولات واضح فالأن هذا الاثانول صارت فيه
+
+380
+00:33:03,350 --> 00:33:12,240
+مشكلة انه كشرب حرام كاستعمال في الصناعةلابد منه
+
+381
+00:33:12,240 --> 00:33:15,520
+طيب الجماعة الكفار هدولة و اللي ضالين و اللي
+
+382
+00:33:15,520 --> 00:33:20,800
+بيشربوا alcohol عاملين صناعات ضخمة للخمور و يقوم
+
+383
+00:33:20,800 --> 00:33:25,600
+عليها اقتصاد دول يعني مثلا انا باذكر في ألمانيا
+
+384
+00:33:25,600 --> 00:33:30,040
+الواحد ممكن يمشي في القطار ساعتين تلاتة فقط وسط
+
+385
+00:33:30,040 --> 00:33:36,530
+حقول من العناب بيسموه vine trauben عناب للخمرشوف
+
+386
+00:33:36,530 --> 00:33:40,350
+جداش يعني جزء كبير من صناعتهم معتمد على الخمر و
+
+387
+00:33:40,350 --> 00:33:44,730
+اللي بده يعمل صناعة و بده يكسب بده يجيب فلوس كتيرة
+
+388
+00:33:44,730 --> 00:33:48,970
+و بنفس الوقت لما أنا بده أستعمله ك solvent و أغسل
+
+389
+00:33:48,970 --> 00:33:53,150
+إيديا فيه بعد ما أعمل مزرعة بكتيريا و إشي بدياه
+
+390
+00:33:54,280 --> 00:33:58,260
+أرخيص صار عندى مشكلة لأنه بتاع صناعة الخمر لما
+
+391
+00:33:58,260 --> 00:34:03,300
+بيكون ال Ethanol في الخمور بده يكون غالي يعني لتر
+
+392
+00:34:03,300 --> 00:34:06,660
+خمره بده يبيعه بقى اربعين خمسين شكل و بنفس الوقت
+
+393
+00:34:06,660 --> 00:34:11,440
+أنا لما بدياه في المعمل بدياه أرخيص لإن أنا بستعمل
+
+394
+00:34:11,440 --> 00:34:15,000
+و بغسل فيه و بكبه و بنظف فيه الأدوات و ما إلى ذلك
+
+395
+00:34:15,000 --> 00:34:19,870
+بدياه بقى أربعة شكل مثلا لتر بس مش أكترأربعة ..
+
+396
+00:34:19,870 --> 00:34:24,590
+تلاتة .. خمسة شكل .. حسب السعر طب كيف بدوا يحلوا
+
+397
+00:34:24,590 --> 00:34:30,030
+هذا المعضلة؟ قالوا احنا مستعدين نوفرلكم إيثانول
+
+398
+00:34:30,030 --> 00:34:34,710
+للصناعة بس بشرط ما تشربوهوش كل الناس بيقول okay
+
+399
+00:34:34,710 --> 00:34:38,210
+خلاص بنشربوش و من ورا لورا بيروحوا يشربوا .. رخيص
+
+400
+00:34:38,210 --> 00:34:42,770
+إيش عملوا؟ صاروا الإيثانول اللي بيوفروا للصناعة
+
+401
+00:34:42,770 --> 00:34:43,590
+يسمموه
+
+402
+00:34:46,070 --> 00:34:49,150
+صاروا يسمموا الـ Ethanol تبع الصناعة إذا بدك تشرب،
+
+403
+00:34:49,150 --> 00:34:52,510
+بدك تشرب من الغالي فالـ Ethanol تبع الصناعة
+
+404
+00:34:52,510 --> 00:34:56,330
+بيسمموه، بيسمموه بإيش؟ بالـ Methanol الـ Methanol
+
+405
+00:34:56,330 --> 00:35:01,250
+مادة سامة تؤدي للعمى بس بنضيف عليه شوية Methanol
+
+406
+00:35:01,250 --> 00:35:07,450
+بس الـ Ethanol، بيضيفوا عليه Methanol، بيصير مسمم
+
+407
+00:35:07,450 --> 00:35:12,750
+أو بالتالي، لو أي ناس من .. انقطع أو ييجي يشربوا
+
+408
+00:35:12,750 --> 00:35:15,810
+Ethanol من المعمل، مابنفعش، بتسممه، بيأثر على ..
+
+409
+00:35:16,930 --> 00:35:21,030
+بشكل أساسي على عيون عندهم و بيقولوا أن أكتر ناس
+
+410
+00:35:21,030 --> 00:35:25,210
+اتأثروا بالكلام الجيش الألماني لما انقطع و شربوا
+
+411
+00:35:25,210 --> 00:35:29,150
+أشياء فيها ميثانول في النهاية و اتأذوا بعينيهم
+
+412
+00:35:29,150 --> 00:35:35,700
+واضح؟فهذه النقطة الأولى في الموضوع أنكم تعرفوا أن
+
+413
+00:35:35,700 --> 00:35:40,220
+الاثانول سلاح دوحة الدنيا، في الخمر حرام، بس في
+
+414
+00:35:40,220 --> 00:35:44,060
+الصناعة لابد منه، يعني هو ال solvent اللي بنشتري
+
+415
+00:35:44,060 --> 00:35:47,700
+فيه التفاعلات، يعني احنا حتى في الجامعة الإسلامية
+
+416
+00:35:47,700 --> 00:35:51,060
+لا نضيع سرا لما نقولكم بنشتري الاثانول بالبراميل
+
+417
+00:35:57,680 --> 00:36:02,460
+هو الوسط اللي بنعمل فيه التفاعلات، يعني لابد منه،
+
+418
+00:36:02,460 --> 00:36:09,310
+لابد منه، واضح؟ الآن الاثانول كيف بيحضروه؟بحضروه
+
+419
+00:36:09,310 --> 00:36:13,750
+بالتخمير، بنجيب السكريات و بواقي القصب أو النشويات
+
+420
+00:36:13,750 --> 00:36:17,730
+و ما إلى ذلك و بيعملوا إيش؟ تخمير التخمير بإيش؟
+
+421
+00:36:17,730 --> 00:36:22,830
+بكائنات حية، دقيقة، خميرة هنا بيجينا التناقض جديد
+
+422
+00:36:24,160 --> 00:36:28,720
+إنه إحنا بنقولكوا لما بتعملوا مزرعة بكتيريا بعد ما
+
+423
+00:36:28,720 --> 00:36:32,220
+تخلصوا غسله بالإيثانول، الإيثانول بقتل البكتيريا،
+
+424
+00:36:32,220 --> 00:36:35,600
+مظبوط ولا لأ؟ والبكتيريا كائنات حية دقيقة، بعد
+
+425
+00:36:35,600 --> 00:36:41,420
+شوية بنيجي بنقولكوا الإيثانول بتحضر من البكتيريا
+
+426
+00:36:41,420 --> 00:36:45,920
+ومن الخميرة، طب ما هو بقتل البكتيريا و الخميرة،
+
+427
+00:36:45,920 --> 00:36:52,780
+كيف بدو يصير؟ إنه أنا بقدر أعمل تخميرو أحضروا و هو
+
+428
+00:36:52,780 --> 00:37:00,000
+القاتل بيقولوا أن التخمير بس لحد نسبة حوال 12% بحد
+
+429
+00:37:00,000 --> 00:37:05,160
+أقصى 15% بتطلع الكحول بعد هيك لو بدت زيد نسبة
+
+430
+00:37:05,160 --> 00:37:10,200
+الكحول بتقتل الكائنات الحياة الدقيقة ملاحظين؟ طيب
+
+431
+00:37:10,200 --> 00:37:17,990
+لو شفتوا خمرة فيها نسبة الاثانول 70%كيف بدو يصير
+
+432
+00:37:17,990 --> 00:37:22,050
+هذا الكلام؟ هل تم هذا الـ Ethanol وصلت لنسبة 70%
+
+433
+00:37:22,050 --> 00:37:26,890
+منه بالتخمير؟ التخمير، لحد 4-5% الكائنات الحياة
+
+434
+00:37:26,890 --> 00:37:32,910
+بتبقى عايشة وبتعمل التخمير، لحد 12% نقول بعد هيك،
+
+435
+00:37:32,910 --> 00:37:37,290
+إذا زاد الكحول، إذا عملت كحول أكتر، هتقتل نفسها
+
+436
+00:37:38,110 --> 00:37:42,810
+لعدد 12% لـ 15% بعد ذلك يتوقف التخمير طب لو كان
+
+437
+00:37:42,810 --> 00:37:46,530
+فيه خمور من الأنواع اللي فيها الاثانول عالي 40% و
+
+438
+00:37:46,530 --> 00:37:51,630
+50% و 60% الويسكي و ال .. كيف هذا الكلام بيصير؟
+
+439
+00:37:51,630 --> 00:37:55,630
+بيضيفوا اثانول إضافة عليها يعني لما بيعملوا ال
+
+440
+00:37:55,630 --> 00:38:01,210
+fermentation التخمير للفواكه بيصير لحد بواقي
+
+441
+00:38:01,210 --> 00:38:04,290
+الفواكه و ما إلى ذلك مع الكحولة ده بيمثل الخمرة
+
+442
+00:38:04,290 --> 00:38:11,270
+لكن هم بيزيدوا نسبةأه ال Ethanol بيضيفوا إضافة بس
+
+443
+00:38:11,270 --> 00:38:16,990
+مافيش تخمير بيوصلنا ل 70 و 80% Ethanol فالخمور ذات
+
+444
+00:38:16,990 --> 00:38:22,310
+المحتوى العالي من الكحول بيكون الكحول إيش ماله؟
+
+445
+00:38:22,310 --> 00:38:26,030
+أضيف إلها إضافة من الخارج
+
+446
+00:38:29,090 --> 00:38:33,510
+بقطره .. اه اه نفس الخمور لما بده ملكه الماء انا
+
+447
+00:38:33,510 --> 00:38:37,610
+كيف بعمل .. يعني انا بعمل التخمير و بعدين بعمل
+
+448
+00:38:37,610 --> 00:38:40,910
+تقدير .. التقدير بطلق للإيثانول لحاله .. التقدير
+
+449
+00:38:40,910 --> 00:38:44,370
+بطلق للإيثانول لحاله .. هنا بدكوا تنتبهوا لنقطة
+
+450
+00:38:44,370 --> 00:38:48,790
+برضه أرجو أنكوا تكونوا فاهمينها كويسأنه إذا
+
+451
+00:38:48,790 --> 00:38:53,410
+التخمير بيطلّع إلي إيثانول، يعني لو حطيت عنب أو
+
+452
+00:38:53,410 --> 00:38:58,730
+غيره أربع، خمس أيام، تلت أيام بيظبد زي ما بيقولوا
+
+453
+00:38:58,730 --> 00:39:03,050
+بيطلّع رغوة و بيحول لإيثانول وبالتالي بيتحول إلى
+
+454
+00:39:03,050 --> 00:39:09,070
+خمر طيب، الآن السؤال بزمه بعد تلت أيام صار في نسبة
+
+455
+00:39:09,070 --> 00:39:13,390
+اتناشف في المية كحول يا ترى لو إجيت قولت بعد ساعة
+
+456
+00:39:14,620 --> 00:39:21,080
+ما بيصيرش .. بتكون فيه نسبة صغيرة جدا لكن لو سألنا
+
+457
+00:39:21,080 --> 00:39:25,340
+نفسنا هل احنا بنشرب عصير العنب بعد ساعة و بعد ساعة
+
+458
+00:39:25,340 --> 00:39:30,600
+و نص و بعد ساعتين أكيد أه الناس بتعصر عناب و
+
+459
+00:39:30,600 --> 00:39:34,560
+بتشربه و حلال و معروف بالصيرة أنه بنعصر العناب و
+
+460
+00:39:34,560 --> 00:39:39,060
+بنشرب العناب بنعصر اليوم بنشربه بس بعد تلت أيام لأ
+
+461
+00:39:40,370 --> 00:39:43,650
+وعشان هيك بيقولوا الخمر ما خمر العقل لأن لحظة ما
+
+462
+00:39:43,650 --> 00:39:47,450
+بيصل لدرجة عالية من التخمر، درجة عالية من الكحول،
+
+463
+00:39:47,450 --> 00:39:53,270
+بيصير حرام لكن أي فاكهة طبيعية، لو بدي أتركها، أي
+
+464
+00:39:53,270 --> 00:39:57,450
+عصير، كوكتيل طبيعي، بدي أتركه في الهواء شوية،
+
+465
+00:39:57,450 --> 00:40:00,770
+بيبدأ يطلع كحول، لو تركته أربع، خمس أيام و حطتله
+
+466
+00:40:00,770 --> 00:40:04,030
+دروف مناسبة من الحرارة، كل أنواع الكوكتيل بتصير
+
+467
+00:40:04,030 --> 00:40:10,270
+خمرةولذلك لابد من إيش؟ من الحذر الآن العلماء حددوا
+
+468
+00:40:10,270 --> 00:40:15,590
+نسبة قالوا إن هناك نسبة تخمر طبيعي أنا لا أستغني
+
+469
+00:40:15,590 --> 00:40:25,070
+عنها إذا كانت نسبة ال alcohol أقل من less than أقل
+
+470
+00:40:25,070 --> 00:40:33,110
+من point five percent مش point oneنص ال point one
+
+471
+00:40:33,110 --> 00:40:37,670
+إذا كانت أقل من point oh five percent لجيتها في
+
+472
+00:40:37,670 --> 00:40:44,070
+عصير لا يعتبر مسكر ويمكن أن يشرب تعتبر نسبة طبيعية
+
+473
+00:40:44,070 --> 00:40:47,730
+هذا تخمر طبيعي لابد منه يعني لو بعد ما تقصروا
+
+474
+00:40:47,730 --> 00:40:51,600
+العناب أربع خمس دقايق هتشوفوا هيك نسبةالنسبة
+
+475
+00:40:51,600 --> 00:40:58,940
+المسموحة أن التخمر الطبيعي يكون 0
+
+476
+00:40:58,940 --> 00:41:02,560
+.001 إيثانول
+
+477
+00:41:15,950 --> 00:41:20,950
+فالنسبة أو الحد اللي حطول علماء المسلمين بالفقهاء
+
+478
+00:41:20,950 --> 00:41:25,970
+مع تبعون الأغذية أن الكحول مش لازم يزيد في العصائر
+
+479
+00:41:25,970 --> 00:41:30,650
+الطبيعية عن point 0.05% طب عن point 0.05% نسبة
+
+480
+00:41:30,650 --> 00:41:33,910
+التخمر طبيعية، تنسوش أن الخمرة بنحكي عن عشرة
+
+481
+00:41:33,910 --> 00:41:39,210
+وخمستاشر وعشرين والأنواع التانية ستين واربعينواضح؟
+
+482
+00:41:39,210 --> 00:41:44,130
+لكن هذه نسبة تخمر طبيعي، لا تستغنى عنها الحياة
+
+483
+00:41:44,130 --> 00:41:48,310
+يعني، غصب عننا، مش بخاطرنا بتصير في العواصير، مش
+
+484
+00:41:48,310 --> 00:41:51,890
+احنا .. اه بس برضه العلماء بيقولوا شغلة، ان هذا
+
+485
+00:41:51,890 --> 00:41:55,750
+تكون نسبة طبيعية، يعني مش انا اضيف كحول، لأن
+
+486
+00:41:55,750 --> 00:41:58,670
+الكحول بيعتبرونه نجس، يعني لو انا بدي اضيف نوك طلق
+
+487
+00:41:59,450 --> 00:42:04,710
+لكن إنه عصير وعمل نسبة صغيرة أقل من هذه النسبة
+
+488
+00:42:04,710 --> 00:42:11,830
+مقبول، لكن إنه يضاف متعمداً، لأ، واضح؟ هذا بالنسبة
+
+489
+00:42:11,830 --> 00:42:17,830
+للإيثانول، بنحضره من التخمر، بهيك تقريبا بننهي
+
+490
+00:42:17,830 --> 00:42:19,490
+المحاضرة اليوم
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..00cf7f0f814f0fa09d5c22bcd7aa793b5531a03e
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8_postprocess.srt
@@ -0,0 +1,1884 @@
+1
+00:00:09,410 --> 00:00:15,770
+بسم الله الرحمن الرحيم اليوم بنبدأ
+
+2
+00:00:15,770 --> 00:00:21,610
+بفصل جديد هو الفصل الثامن بتعرفوا الفصل السابق كان
+
+3
+00:00:21,610 --> 00:00:27,930
+عن ال alcohols يعني R وH الآن بنمشي خطوة للأمام لل
+
+4
+00:00:27,930 --> 00:00:35,390
+ethers بنصير R وR يعني الإختلاف أنه بدلنا H بR
+
+5
+00:00:37,440 --> 00:00:42,040
+بدل ما كان عندى في ال alcohols R.O.H في ال ethers
+
+6
+00:00:42,040 --> 00:00:49,980
+بيصير عندى R.O.R طبعا هذا التبديل الحقيقة بيجلب كل
+
+7
+00:00:49,980 --> 00:00:53,740
+إشي يعني مابنعش نقول أنه تبديل بسيط لأ الخواص و
+
+8
+00:00:53,740 --> 00:00:58,740
+التحضير كل إشي بيختلف تماما نتيجة هذا التبديل
+
+9
+00:00:58,740 --> 00:01:05,380
+فالخلاصة ال ethers الصيغة العامة إلهم إيش R.O.R
+
+10
+00:01:05,380 --> 00:01:12,130
+لاحظوا أولخاصية بتيجي على بالنا ال polarity لما
+
+11
+00:01:12,130 --> 00:01:19,830
+نيجي نقارنهم بال alcohol مثلا R O H ولا R O R؟ R O
+
+12
+00:01:19,830 --> 00:01:26,030
+H is more polar than ethers ليش؟ لأن هناك في عندى
+
+13
+00:01:26,030 --> 00:01:30,870
+hydrogen bonding فال ethers ال polarity تبعتهم أقل
+
+14
+00:01:30,870 --> 00:01:38,890
+من ال alcohol بشكل عام ال solubilityبرضه بيبطلوا
+
+15
+00:01:38,890 --> 00:01:42,910
+يدوبوا في الميه، ليش؟ لإن أساسا ذائبية ال alcohol
+
+16
+00:01:42,910 --> 00:01:46,290
+في الميه كانت معتمدة على إيش؟ على ال hydrogen
+
+17
+00:01:46,290 --> 00:01:54,060
+bonding، واضح؟وعلى كبر ال الكلجروب الان يعني
+
+18
+00:01:54,060 --> 00:01:59,120
+ابتداء من الداي إيثل إيثر الداي إيثل إيثر بدوبش في
+
+19
+00:01:59,120 --> 00:02:03,660
+الميه و بيعمله extraction .. بيعمله extraction لل
+
+20
+00:02:03,660 --> 00:02:07,300
+organ ال compounds بيستعمله واضح؟ يعني إذا قولنا
+
+21
+00:02:07,300 --> 00:02:12,590
+الداي ميثل إيثر اللي هو أصغر إيثر هذا غازلما نبدأ
+
+22
+00:02:12,590 --> 00:02:16,190
+في الـ liquids أول liquid في الـ aethers الـ
+
+23
+00:02:16,190 --> 00:02:19,410
+Diethyl ether الـ Diethyl ether لا تدوب في الماء
+
+24
+00:02:19,410 --> 00:02:24,150
+واضح؟ طبعا و باقي الـ aethers بالتأكيد لا تدوب في
+
+25
+00:02:24,150 --> 00:02:27,690
+الماء الـ melting points و الـ boiling points
+
+26
+00:02:27,690 --> 00:02:31,590
+تبعونهم أقل كتير من الالكوهولز لأنهم بالالكوهولز
+
+27
+00:02:31,590 --> 00:02:35,470
+كانوا مرفوعين بالـ hydrogen bonding يعني الـ
+
+28
+00:02:35,470 --> 00:02:39,510
+Diethyl ether مثلا الـ boiling point له ستة
+
+29
+00:02:39,510 --> 00:02:45,290
+وتلاتين أو سبعة وتلاتينبينما خدوا الاثانول كان
+
+30
+00:02:45,290 --> 00:02:51,670
+واحد و تمانين لاحظوا مع العلم ان الاثانول لسه في
+
+31
+00:02:51,670 --> 00:02:57,790
+الوزن جد نص الداي اثل ايثر يعني هناك عندي اثل او
+
+32
+00:02:57,790 --> 00:03:04,150
+اثل الاثانول اثل او اتش اذا مين اصغر كتير في الوزن
+
+33
+00:03:04,830 --> 00:03:08,950
+الإيثانول لكن في ال boiling point أعلى كثير شو
+
+34
+00:03:08,950 --> 00:03:13,110
+السبب ال hydrogen bonding إذا لاحظوا عما معظم
+
+35
+00:03:13,110 --> 00:03:17,530
+الخواص اللي قادة تختلف نتيجة اختلاف هذه ال R بدل
+
+36
+00:03:17,530 --> 00:03:24,860
+ما كانت R صارت H واضحأيضًا الـ Alcohols كانوا
+
+37
+00:03:24,860 --> 00:03:28,240
+بالتفاعلات، اللي لهم عدد كبير من التفاعلات، مظبوط
+
+38
+00:03:28,240 --> 00:03:31,880
+ولا لأ؟ أخدتوا تفاعلات substitution و تفاعلات
+
+39
+00:03:31,880 --> 00:03:37,240
+elimination و تفاعلات على حذف ال .. ال H مثلًا مع
+
+40
+00:03:37,240 --> 00:03:41,920
+الصوديوم as acids الethers they are generally
+
+41
+00:03:41,920 --> 00:03:47,070
+chemically inert، يعني خاملين كيميائيًاولذلك
+
+42
+00:03:47,070 --> 00:03:53,870
+الكثير من ال ethers تستعمل ك solvent من المميزات
+
+43
+00:03:53,870 --> 00:03:59,990
+اللي لازم يتمتع بفيها ال solvent انه يكون محايد
+
+44
+00:03:59,990 --> 00:04:05,610
+مايتفعلش يعني انا بدي اياه وسطوسط لإجراء التفاعل
+
+45
+00:04:05,610 --> 00:04:12,010
+بإنفعش هو يدخل و
+
+46
+00:04:12,010 --> 00:04:16,830
+يتفاعل ال solvent لازم يكون فقط وسط لإجراء التفاعل
+
+47
+00:04:16,830 --> 00:04:22,050
+يكون محايد لا اميل مع هذه المادة ولا مع هذه المادة
+
+48
+00:04:22,050 --> 00:04:25,190
+يعني انا بدي ادوب مادتين فيه اسيب المادتين
+
+49
+00:04:25,190 --> 00:04:30,490
+يتفاعلوا لحالهم مش هو يروح يتفاعل معهم واضح؟و هذا
+
+50
+00:04:30,490 --> 00:04:34,570
+الكلام يعني له انعكاس حقيقة في .. حتى في الواقع
+
+51
+00:04:34,570 --> 00:04:39,850
+الإنساني لما نيجي نقول أنه بدنا شخص يكون واسطة يحل
+
+52
+00:04:39,850 --> 00:04:44,910
+مشكلة بين اتنين المفروض مايكونش مرتبط لا مع هذا
+
+53
+00:04:44,910 --> 00:04:49,870
+ولا مع هذا أقل تقدير ارتباط male يعني ممكن يكون
+
+54
+00:04:49,870 --> 00:04:58,440
+مرتبطبصداقة بعائلة لكن لما ييجي حكم او وسط مش لازم
+
+55
+00:04:58,440 --> 00:05:03,720
+يميل هان ولا هان ايش مشكلة القضية الفلسطينية كلها؟
+
+56
+00:05:03,720 --> 00:05:10,710
+ان الحكامعوج من الحُكّام الأمم المتحدة والاتحاد
+
+57
+00:05:10,710 --> 00:05:14,590
+الأوروبي وبريطانيا وروسيا اللي أسسوا إسرائيل، في
+
+58
+00:05:14,590 --> 00:05:18,070
+آخر بيجو، بدهم يشرفوا على مفاوضات بين الفلسطينية
+
+59
+00:05:18,070 --> 00:05:22,990
+واليهود، هل هما محايدين؟ عشان هيك كل المسار تبعهم
+
+60
+00:05:24,540 --> 00:05:27,900
+اللي مش مصدق انه فاشل يقول انه مش فاشل ما انتوا
+
+61
+00:05:27,900 --> 00:05:31,900
+شايفين يعني ما .. مافيش براوح مكانه يعني مافيش
+
+62
+00:05:31,900 --> 00:05:35,880
+مفكر إلا بيقول قاعدين بتراوحوا مكانكوا و بالعكس
+
+63
+00:05:35,880 --> 00:05:41,820
+تلتهم الأرض و غيرها و غيرها لإنه ال solvent مش
+
+64
+00:05:41,820 --> 00:05:46,100
+inert لازم ال solvent يكون inert مايدخلش في
+
+65
+00:05:46,100 --> 00:05:52,450
+التفاعل أما نحط أمريكا solvent بنفعبشكل عام الـ
+
+66
+00:05:52,450 --> 00:05:56,950
+ethers فيهم مشكلة انهم قابلين للاشتعال بمعنى سريعي
+
+67
+00:05:56,950 --> 00:06:00,750
+الاشتعال و قابلين للاشتعال عشانك اللي بتعامل مع ال
+
+68
+00:06:00,750 --> 00:06:04,630
+ethers بالذات ال low boiling point ethers اللي هي
+
+69
+00:06:04,630 --> 00:06:09,130
+منخفضة درجة الغليان فبتطلع ابخرته وين ما في نار في
+
+70
+00:06:09,130 --> 00:06:13,710
+المختبر ممكن تمسك وتولعواضح؟ و لذلك يجب أن يكون
+
+71
+00:06:13,710 --> 00:06:18,290
+عندكم حذر يعني أنا ما زلت بأذكر أنه اتنين زملاء
+
+72
+00:06:18,290 --> 00:06:22,310
+لنا في المختبر واحد مولع نار و بشتغل شغلة و التاني
+
+73
+00:06:22,310 --> 00:06:26,290
+عبعد مترين منه بشتغل بال ether فجأة اللي مولع
+
+74
+00:06:26,290 --> 00:06:31,570
+النار لجه حاله نفسه مولع من الأبخرة تبع ال ether
+
+75
+00:06:31,570 --> 00:06:37,790
+اللي إجت من الشخص المقابلفإذا اتعاملتم في المختبر
+
+76
+00:06:37,790 --> 00:06:42,610
+مع الـ Ether بتكون تتعاملوا بحذر مش تكونوا حاطين
+
+77
+00:06:42,610 --> 00:06:47,230
+مرتبان Ether مفتوح وعلى بعد عشرين، تلاتين، اربعين
+
+78
+00:06:47,230 --> 00:06:52,190
+سانتمتر، نص متر حاطين لبنزين بيرنر أكيد هيعمل
+
+79
+00:06:52,190 --> 00:06:56,470
+حريقة وأكيد هيعمل مصيبة، واضح؟ فالتعامل مع
+
+80
+00:06:56,470 --> 00:07:01,570
+الـEthers بده حذر لأن الـAll are very flammable
+
+81
+00:07:01,570 --> 00:07:07,910
+قابلين للاشتئال وبلوكة النار بسرعةالان اذا بدنا
+
+82
+00:07:07,910 --> 00:07:16,000
+نحكي عن تسمية الـ ethersفي عندنا common name و
+
+83
+00:07:16,000 --> 00:07:21,540
+أيوبك names ال common name إن أجيب ال ether إله
+
+84
+00:07:21,540 --> 00:07:27,540
+جنحين بظبط ولا لأ إله مجمعتين إن أجيب الأسماء لل
+
+85
+00:07:27,540 --> 00:07:32,700
+الكل groups و أذكرها يعني لو مثلا عندي هنا مثل و
+
+86
+00:07:32,700 --> 00:07:40,100
+مثل ether مثل و مثل شو بده أسميه؟die مثل اثر لو
+
+87
+00:07:40,100 --> 00:07:45,000
+كانت اثر او اثر مرات
+
+88
+00:07:45,000 --> 00:07:48,360
+حتى بيستغنوا عن ال die يعني بتلاقيهم كاتبين مثل
+
+89
+00:07:48,360 --> 00:07:52,120
+اثر اذا جريتوا مثل اثر هو ال die مثل اثر او
+
+90
+00:07:52,120 --> 00:07:56,420
+بتلاقيهم كاتبين اثر اثر يعني لو قلتلكوا ارسموا ال
+
+91
+00:07:56,420 --> 00:08:02,300
+اثر اثر بتكونوا تحطولي اثر او اثر بس اختصارا و
+
+92
+00:08:02,300 --> 00:08:09,000
+خلاص يعني تقليديا صاروا يقولوا ايشبدون إيش؟ بدون
+
+93
+00:08:09,000 --> 00:08:15,420
+كلمة الضايق هل يجوز إن الإنسان مثلا يذكر نص الإسم؟
+
+94
+00:08:15,420 --> 00:08:22,320
+لا و الله إذا فهمت ضمنا يجوز ماشي يعني لو بدنا
+
+95
+00:08:22,320 --> 00:08:27,620
+نعطيكم مثال الناس اللي بيروحوا على الجنوب بيكونوا
+
+96
+00:08:27,620 --> 00:08:32,100
+يشوفوا السيارات بيقولوا ع الدير الكل بيقول ع الدير
+
+97
+00:08:32,100 --> 00:08:35,100
+وين طالع ع الدير ولا بيقول ع الدير البلح كل واحد
+
+98
+00:08:36,120 --> 00:08:41,800
+بنجيب نص الإسم و يفهم ضمنا؟ أكيد .. اه .. و هنا لو
+
+99
+00:08:41,800 --> 00:08:46,480
+قلت مثل إيثار أو إثل إيثار المقصود فيه die مثل
+
+100
+00:08:46,480 --> 00:08:50,400
+إيثار و مثلها بالمناسبة ال مثلسلفيت كتير بتجروا
+
+101
+00:08:50,400 --> 00:08:55,780
+اسم مثلسلفيت بيكون المقصود فيها die مثلسلفيت اللي
+
+102
+00:08:55,780 --> 00:09:00,700
+هي مخدة الشكل اللي زيه بس double point او مثل مثل
+
+103
+00:09:00,700 --> 00:09:04,980
+فبنقول احنا die مثلسلفيت و ممكن يتلاقوا ناس كتير
+
+104
+00:09:05,230 --> 00:09:11,250
+اختصارا نقولوها مثل سولفات، واضح؟ إذا لما يكون هذه
+
+105
+00:09:11,250 --> 00:09:15,770
+المجموعتين زي بعض، خلّيني أقول مثل إيثر، مثل إيثر،
+
+106
+00:09:15,770 --> 00:09:19,310
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+107
+00:09:19,310 --> 00:09:21,590
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+108
+00:09:21,590 --> 00:09:23,590
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+109
+00:09:23,590 --> 00:09:23,630
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+110
+00:09:23,630 --> 00:09:25,010
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+111
+00:09:25,010 --> 00:09:29,790
+مثل إيثر، مثل إيثر، مثل إيثر
+
+112
+00:09:48,720 --> 00:09:56,740
+مثلًا اذا كان المجموعات مختلفة مثلًا انا مثل وانا
+
+113
+00:09:56,740 --> 00:10:05,050
+CH2 CH2ثم اذا كنت تحب الذكر المجموعتين اذا كنت تحب
+
+114
+00:10:05,050 --> 00:10:07,210
+الذكر المجموعتين اذا كنت تحب الذكر المجموعتين اذا
+
+115
+00:10:07,210 --> 00:10:07,890
+كنت تحب الذكر المجموعتين اذا كنت تحب الذكر
+
+116
+00:10:07,890 --> 00:10:09,510
+المجموعتين اذا كنت تحب الذكر المجموعتين اذا كنت
+
+117
+00:10:09,510 --> 00:10:10,590
+تحب الذكر المجموعتين اذا كنت تحب الذكر المجموعتين
+
+118
+00:10:10,590 --> 00:10:12,950
+اذا كنت تحب الذكر المجموعتين اذا كنت تحب الذكر
+
+119
+00:10:12,950 --> 00:10:14,390
+المجموعتين اذا كنت تحب الذكر المجموعتين اذا كنت
+
+120
+00:10:14,390 --> 00:10:16,130
+تحب الذكر المجموعتين اذا كنت تحب الذكر المجموعتين
+
+121
+00:10:16,130 --> 00:10:21,750
+اذا كنت تحب الذكر المجموعتين اذا كنت تحب الذكر
+
+122
+00:10:21,750 --> 00:10:28,850
+المجمCH3 CH2 إثل فبصير كله chloromythin ethyl
+
+123
+00:10:28,850 --> 00:10:35,290
+ether واضح؟ الآن لاحظوا التسمية بهذه الطريقة ال
+
+124
+00:10:35,290 --> 00:10:40,030
+common name بتفترض شغلة أنه أنا أكون بسهولة بعرف
+
+125
+00:10:40,030 --> 00:10:42,070
+اسم المجموع اللي هنا و اللي هنا اللي هنا و اللي
+
+126
+00:10:42,070 --> 00:10:46,990
+هنا اللي هنا اللي هنا مرات كتيرة بتصعب الأمور يعني
+
+127
+00:10:46,990 --> 00:10:51,840
+بمعنى أنه أنتوا المجموعات اللي أخدتوهاعدد قليل من
+
+128
+00:10:51,840 --> 00:10:55,180
+المجموعات، يعني لو تتذكروا في ال الكل جروبز، أنتوا
+
+129
+00:10:55,180 --> 00:10:59,100
+أخدتوا الميثل، الاثل، البروبل، الايزوبروبل، ال
+
+130
+00:10:59,100 --> 00:11:04,840
+تيرتشار بيوتل، الفنل، الفنل، الألل، مصبوط ولا لا؟
+
+131
+00:11:04,840 --> 00:11:12,400
+بعد ذلك السكندر بيوتل، بعد ذلك ما أخدتوش؟مجموعات
+
+132
+00:11:12,400 --> 00:11:16,720
+وبناء على ذلك لو إحدى المجموعات كانت كبيرة مالهاش
+
+133
+00:11:16,720 --> 00:11:23,340
+اسم بسيط كيف بدي أسمي يعني لما يجيني مثلا CH3 CH و
+
+134
+00:11:23,340 --> 00:11:28,240
+أحط هنا CL و أحط هنا CH2 و أحط هنا CH3 تاني و
+
+135
+00:11:28,240 --> 00:11:33,040
+بعدين أحط هنا O CH3 و أقول بدي أسمي هذا ال ether
+
+136
+00:11:33,040 --> 00:11:39,900
+هنا لاحظوا حاطسين عندكم مشكلة انه هذه المجموعة CH3
+
+137
+00:11:40,830 --> 00:11:43,290
+معروفة اسمها مثلًا قابوهادي
+
+138
+00:11:46,370 --> 00:11:49,950
+مش من المجموعات اللي أخدناها و اللي إلها اسم و
+
+139
+00:11:49,950 --> 00:11:54,850
+بناءً على ذلك إذا كانت إحدى المجموعات مالهاش اسم
+
+140
+00:11:54,850 --> 00:11:59,350
+بسيط زي الأسماء اللي توي ذكرناها المطلوب نحوّل على
+
+141
+00:11:59,350 --> 00:12:03,910
+نظام تاني في تسمية الethers واضح؟ يعني بتصير
+
+142
+00:12:03,910 --> 00:12:07,550
+المسألة صعبة، مابقدرش أسميه و أعطي لهذه اسم
+
+143
+00:12:07,550 --> 00:12:12,280
+مجموعة، هذه مايلها نهائيا اسم مجموعةفي هذه الحالة
+
+144
+00:12:12,280 --> 00:12:17,380
+ماذا نفعل؟ نستعمل ايوباك نظام of nomenclature
+
+145
+00:12:17,380 --> 00:12:27,580
+نستعمل نظام ايوباك لنومنكلتشر ايوباك يعمل ايثر مثل
+
+146
+00:12:27,580 --> 00:12:34,520
+ما كنا نتعامل مع الالكينز طبعا أنا مابفضلشنقعد
+
+147
+00:12:34,520 --> 00:12:38,860
+نجرى كل هذا الكلام لكن بإمكاننا ناخد تطبيق بسيط
+
+148
+00:12:38,860 --> 00:12:42,060
+بإمكاننا ناخد تطبيق بسيط بالتطبيق بتصير الأمور
+
+149
+00:12:42,060 --> 00:12:48,100
+سهلة اتخيلوا مثلا هنا عندي ال O و انا عندي CH2 CH2
+
+150
+00:12:48,100 --> 00:12:54,840
+CH3 واضح ان هذا الصفر هي السلسلة الطويلة و هذا ال
+
+151
+00:12:54,840 --> 00:13:00,100
+O مع المثل السلسلة القصيرة الان لو انا افترض ان
+
+152
+00:13:00,100 --> 00:13:05,010
+انا اعطيكوا هذا الكلام و حاططلكوا هنا CLبذل الزرجة
+
+153
+00:13:05,010 --> 00:13:11,570
+شو هتسموا المُركّب؟ وان إكلورو إبروبين مظبوط ولا
+
+154
+00:13:11,570 --> 00:13:17,550
+لأ؟ لو حاطط PR وان إبرومو إبروبين الآن أنا مش
+
+155
+00:13:17,550 --> 00:13:25,250
+حاططه حاطط المجموعة OCH3 ال OCH3 نفسها إلها اسم ..
+
+156
+00:13:25,250 --> 00:13:32,750
+شو اسمها؟ مثوكسي مثوكسي مظبوط ولا لأ؟ O مثل مثوكسي
+
+157
+00:13:33,800 --> 00:13:44,140
+أو إثل إثوكسي أو فينل فينوكسي فينوكسي واضح ال أو
+
+158
+00:13:44,140 --> 00:13:45,560
+فينل فينوكسي
+
+159
+00:13:49,340 --> 00:13:54,240
+بناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+160
+00:13:54,240 --> 00:13:56,260
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+161
+00:13:56,260 --> 00:13:57,040
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+162
+00:13:57,040 --> 00:13:59,320
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+163
+00:13:59,320 --> 00:13:59,960
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+164
+00:13:59,960 --> 00:14:03,320
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+165
+00:14:03,320 --> 00:14:09,020
+وبناء العدالك اتل اثوكسي وبناءواضح؟ صرت أطول سلسلة
+
+166
+00:14:09,020 --> 00:14:13,980
+عندى سلسلة البروبين وهو البروبين عليه مجموعة
+
+167
+00:14:13,980 --> 00:14:18,140
+الميثوكسين الان لو بدى أجي أطلع على هذا المركب
+
+168
+00:14:18,140 --> 00:14:22,300
+الان هنا عندى كام كربونة؟ واحدة هنا عندى كام
+
+169
+00:14:22,300 --> 00:14:28,040
+كربونة؟ واحد، اتنين هدولة الكربونتين شو عليهم ال
+
+170
+00:14:28,040 --> 00:14:32,520
+substituents؟ كلور على الذرع الأولى وإيش كمان؟
+
+171
+00:14:34,570 --> 00:14:42,850
+وميثوكسي عليها اتن ميثوكسي اتن ميثوكسي
+
+172
+00:14:42,850 --> 00:14:48,090
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+173
+00:14:48,090 --> 00:14:50,590
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+174
+00:14:50,590 --> 00:14:52,390
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+175
+00:14:52,390 --> 00:14:53,070
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+176
+00:14:53,070 --> 00:14:58,830
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+177
+00:14:58,830 --> 00:15:06,770
+اتن مياللي فوق على موقع ات نيت شو شابك فيها برو
+
+178
+00:15:06,770 --> 00:15:14,630
+بوكسي اه
+
+179
+00:15:14,630 --> 00:15:19,050
+يعني خليني اكد عليه المثال هذا مرة تانية انه عندكم
+
+180
+00:15:19,970 --> 00:15:25,970
+سلسلة طويلة بيوتين من موقع 2xnt substitution فبناء
+
+181
+00:15:25,970 --> 00:15:31,190
+على ذلك هذا المُركّب يصبح 2-propoxy-butane الأن
+
+182
+00:15:31,190 --> 00:15:35,250
+لاحظوا في الأمثلة التلاتة اللي شرحناها المجموعة
+
+183
+00:15:35,250 --> 00:15:41,060
+لهذا السهل مثوكسيميثوكسي بروبوكسي واحدة ممكن تتسأل
+
+184
+00:15:41,060 --> 00:15:45,580
+طب تقول لو المجمعتين صاروا معقدين و صعبين وقتها
+
+185
+00:15:45,580 --> 00:15:50,000
+التسمية شوية بتصعب و بيصير المجموعة هذه بتحوطها
+
+186
+00:15:50,000 --> 00:15:54,480
+بين جثين و أفصل فيها مثلا لو كنت تتطلع على هذا
+
+187
+00:15:54,480 --> 00:15:59,450
+المركب اللي موجود عندناCH2 CH2 CH3 CH3 CH3 CH3 CH3
+
+188
+00:15:59,450 --> 00:16:05,770
+CH3 CH3 CH3 CH3 CH3
+
+189
+00:16:05,770 --> 00:16:07,370
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+190
+00:16:07,370 --> 00:16:07,930
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+191
+00:16:07,930 --> 00:16:08,970
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+192
+00:16:08,970 --> 00:16:09,330
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+193
+00:16:09,330 --> 00:16:10,530
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+194
+00:16:10,530 --> 00:16:13,850
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+195
+00:16:13,850 --> 00:16:17,810
+CH3
+
+196
+00:16:17,810 --> 00:16:24,590
+CH3 CH3 CH3مجموعة اذا بدي اقول three و اذكر اسم
+
+197
+00:16:24,590 --> 00:16:31,110
+المجموعة المجموعة اسمها مش مباشر لانها CH2 CH2 CL
+
+198
+00:16:31,110 --> 00:16:34,950
+و بناء على ذلك كأن غير الترقيم اللي بدي اعمله هو
+
+199
+00:16:34,950 --> 00:16:39,450
+one two three four بدي اعمل ترقيم تاني لهذه
+
+200
+00:16:39,450 --> 00:16:47,710
+المجموعة ممكن اقول one prime two primeوبناء على
+
+201
+00:16:47,710 --> 00:16:52,670
+ذلك هذه المجموعة لو أنها لحالة بدأ أسميها two
+
+202
+00:16:52,670 --> 00:16:58,420
+-prime-chloroethoxy ممكن نحطها برايم يكون أفضللما
+
+203
+00:16:58,420 --> 00:17:03,360
+يكون عندكم اكثر من نظام ترقيم في المُركّب، ميزوهم،
+
+204
+00:17:03,360 --> 00:17:07,120
+حطوا شرطة على واحد منهم فانا عندي نظام ترقيم
+
+205
+00:17:07,120 --> 00:17:12,880
+للسلسلة الطويلة وعندي نظام ترقيم للسلسلة القصيرة
+
+206
+00:17:12,880 --> 00:17:16,340
+هذه واضح انها إيثوكسي، بس على بوقع two prime
+
+207
+00:17:16,340 --> 00:17:21,800
+ابتداء من ال Oxygen، شو إجا عندى؟eclor فصارت two
+
+208
+00:17:21,800 --> 00:17:27,200
+prime ecloroethoxy فالمُركّب كله بيصير three two
+
+209
+00:17:27,200 --> 00:17:33,680
+prime ecloroethoxy one butanol لأنه alcohol
+
+210
+00:17:33,680 --> 00:17:39,540
+والالكولز بنتهوا باسم all واضح؟ والالكولز باسم all
+
+211
+00:17:39,540 --> 00:17:45,720
+الآن هل يا ترى في واحدة إلها مزاج تسمي هذا
+
+212
+00:17:45,720 --> 00:17:51,750
+المُركّب اللي هنا اللي رسمناه عشان نوضحلكم؟مين
+
+213
+00:17:51,750 --> 00:17:55,270
+بدأت تفضل؟
+
+214
+00:17:55,270 --> 00:18:00,490
+اتفضلي وين
+
+215
+00:18:00,490 --> 00:18:07,090
+اطول السلسلة عندك؟ هنا؟
+
+216
+00:18:07,090 --> 00:18:14,290
+كويس، اقرب اش على ال O وين؟ one two three four
+
+217
+00:18:14,290 --> 00:18:22,800
+ممكن نتخيلها زي هيك او one twothree four الخلاصة
+
+218
+00:18:22,800 --> 00:18:27,840
+ان ال substitutions اللي هنا على موقع اتنين و على
+
+219
+00:18:27,840 --> 00:18:32,560
+موقع تلاتة على موقع اتنين شوفي عندك كلورو و على
+
+220
+00:18:32,560 --> 00:18:41,340
+موقع تلاتة مثوكسي و المركب كله بيوتين اذا شو هتسمي
+
+221
+00:18:41,340 --> 00:18:48,560
+هذا المركب two chloro three methoxy
+
+222
+00:18:54,370 --> 00:19:02,530
+تو كلورو ثريمي ثوكسي بيوتين واضح طبعا المركبات لا
+
+223
+00:19:02,530 --> 00:19:06,730
+تنتهي لكن اهم شي ان انتوا اخدتوا المبادئ العامة في
+
+224
+00:19:06,730 --> 00:19:10,670
+التسمية ان في عندك common nomenclature لما تكون
+
+225
+00:19:10,670 --> 00:19:16,530
+المجموعات بسيطة و ذات اسماء معروفة و عندك اي
+
+226
+00:19:16,530 --> 00:19:21,210
+backnomenclature اذا صارت المجموعات اشمالها معقدة
+
+227
+00:19:21,210 --> 00:19:30,680
+و بطلة بسيطةهذا بالنسبة لتسمية الـ
+
+228
+00:19:30,680 --> 00:19:31,160
+Ethers
+
+229
+00:19:38,730 --> 00:19:43,890
+معلومة ثقافية عن الـ Ethers الـ Ethers ومشتقاتها
+
+230
+00:19:43,890 --> 00:19:49,470
+هي من أوائل المركبات اللي استعملت كمواد مخدرة
+
+231
+00:19:49,470 --> 00:19:54,410
+وعشانك برضه لا ينصح مثلا أن طالب تكون تشتغل بـ
+
+232
+00:19:54,410 --> 00:19:59,010
+Ether و تقعد يتحرك مركب و الـ Ether بتبخر جامها من
+
+233
+00:19:59,010 --> 00:20:03,770
+بيكر لمدة نص ساعة ساعة و هي تشم Ether Ether Ether
+
+234
+00:20:03,770 --> 00:20:09,410
+ممكن انها إيشبشكل أو باخر الدروخ أو تتخدر، فالـ
+
+235
+00:20:09,410 --> 00:20:14,870
+ETHER is the first general anesthetic يعني استعمل
+
+236
+00:20:14,870 --> 00:20:21,920
+كمادة مخدرةالان جزء من اللي بيستعملوه حتى في
+
+237
+00:20:21,920 --> 00:20:26,880
+التطبيق مش ال die-ethyl ether نفسه لكن المشتقات
+
+238
+00:20:26,880 --> 00:20:31,440
+فيها halogens يعني قبلت بعض الظرار ب halogens و
+
+239
+00:20:31,440 --> 00:20:35,300
+ماخد هذه أسماء شهرة يعني هنا مثلا عندكوا floriclor
+
+240
+00:20:35,300 --> 00:20:38,980
+floriclor floriclor floriclor واضح؟ هذا اسمه
+
+241
+00:20:38,980 --> 00:20:44,010
+penthrin وهذا enthrinما بهمناش نحفظهم، لكن في
+
+242
+00:20:44,010 --> 00:20:49,190
+النهاية هي عبارة عن مواد تستعمل في التخدير وفي
+
+243
+00:20:49,190 --> 00:20:55,610
+الطب اللي بديه يتعامل مع ال ethers حكينا عن خطرين
+
+244
+00:20:55,610 --> 00:21:02,050
+لحتى الآن لهم وضايل الخطر التالت الخطر الأول انهم
+
+245
+00:21:02,050 --> 00:21:09,000
+they are flammableبشتعلوا بسرعة، بدهم حذر، الخطر
+
+246
+00:21:09,000 --> 00:21:14,400
+التاني أن جزء منهم have anesthetic properties، لهم
+
+247
+00:21:14,400 --> 00:21:18,400
+خواص مخدرة وبالتالي الإنسان مايحطش راسه جانب ال
+
+248
+00:21:18,400 --> 00:21:23,220
+ether وقاعد ..يشتغلوا اشي ممكن يشيم كمية كبيرة منه
+
+249
+00:21:23,220 --> 00:21:30,080
+الخطر التالت للethers انه الكثير من ال ethers اللي
+
+250
+00:21:30,080 --> 00:21:35,680
+بتكون متروكة لفترات قديمة يعني مخزن مثلا محطوط في
+
+251
+00:21:35,680 --> 00:21:39,440
+ال ether سنتين تلاتة اربع راح الواحد طلب منه بوت
+
+252
+00:21:39,440 --> 00:21:44,860
+ال ether جابله بوت ال ether ممكن يكون عامل مواد
+
+253
+00:21:44,860 --> 00:21:50,460
+متفجرةيجي البني آدم يشتغل في ال ether ما يسخنوا
+
+254
+00:21:50,460 --> 00:21:55,930
+شوية ولا يكبوا مع الحركة؟يعمل فيه ايش؟ انفجار
+
+255
+00:21:55,930 --> 00:22:00,510
+ولذلك الـ ethers القديمة خطيرة ممكن تكون عاملة
+
+256
+00:22:00,510 --> 00:22:05,530
+ايش؟ مواد متفجرة بتكون عاملة مواد متفجرة لأنها
+
+257
+00:22:05,530 --> 00:22:10,670
+بتعمل أشياء من الأكسوجين البسيط اللي في الجو وعلى
+
+258
+00:22:10,670 --> 00:22:15,010
+المدى الزمن البعيد بنسميها ايش؟ peroxides هذه
+
+259
+00:22:15,010 --> 00:22:20,300
+البروكسايتز هي المواد اللي بتسببالانفجارات في الـ
+
+260
+00:22:20,300 --> 00:22:24,480
+ethers والطلاب لازم يكونوا حاذرين منها يعني لو
+
+261
+00:22:24,480 --> 00:22:27,720
+اشتغلتوا في المستقبل في مختبر طب في مختبر
+
+262
+00:22:27,720 --> 00:22:32,540
+biochemistry whatever لما يجيكوا ال ether بدوا
+
+263
+00:22:32,540 --> 00:22:38,140
+يكونوا في بالكوا انه ممكن يكون فيه مشكلة الان ممكن
+
+264
+00:22:38,140 --> 00:22:42,220
+يكون فيه مشكلة ثقافية هذا الكلام مابنفعش كيف بدنا
+
+265
+00:22:42,220 --> 00:22:46,140
+نكون احنا متأكدين ان المشكلة موجودة ولا لأ وإذا
+
+266
+00:22:46,140 --> 00:22:53,650
+موجودةبدنا نعالجها اول اشي كيف بتكون البروكسايد
+
+267
+00:22:53,650 --> 00:22:58,130
+اللي هي المادة المتفجرة هذه لو مثلا هذا الداي
+
+268
+00:22:58,130 --> 00:23:02,310
+إيثال إيثار هو أكتر المواد استعمالا ك solvent ترك
+
+269
+00:23:02,310 --> 00:23:06,870
+لفترة طويلة مع الأكسجين بيروح بيضيف لهنا OOH هذا
+
+270
+00:23:06,870 --> 00:23:10,790
+بيروكسايد معنى بيروكسايد يعني في أكسجين زيادة يعني
+
+271
+00:23:10,790 --> 00:23:21,500
+مش OH OOH واضح؟ والتكرار؟دائما بعلم الشطار ويفيد
+
+272
+00:23:21,500 --> 00:23:27,880
+التأكيد اللي بده يأكد أي جملة إيش بيعمل بيكرر وهنا
+
+273
+00:23:27,880 --> 00:23:32,320
+بنكرر لل oxygen كتير في الحديث النبوية بيجي تكرار
+
+274
+00:23:32,320 --> 00:23:37,200
+ولا لأ مثلا في الحديث اللي بيقول فذلكم الرباط
+
+275
+00:23:37,200 --> 00:23:44,800
+فذلكم الرباط فذلكم الرباط مظبوط ولا لأ؟ألا أدلكم
+
+276
+00:23:44,800 --> 00:23:47,900
+على ما يرفعوا الله به الدرجات ويمحوا به الخطايا
+
+277
+00:23:47,900 --> 00:23:53,280
+قالوا بلى يا رسول الله قال إسباغه الوضوءي على
+
+278
+00:23:53,280 --> 00:23:58,280
+المكاري هو كثرة الخطاة إلى المساجد وانتظار الصلاة
+
+279
+00:23:58,280 --> 00:24:03,240
+إلى الصلاة فذلكم الرباط فذلكم الرباط فذلكم الرباط
+
+280
+00:24:03,240 --> 00:24:07,800
+هذا في الحديث النبوي التكرار مشهور كتير لما بده
+
+281
+00:24:07,800 --> 00:24:13,160
+قال أمك ثم أمك ثم أبيك
+
+282
+00:24:14,010 --> 00:24:18,070
+واضح؟ الله يعطيكم العافية من التعب اللي بتشوفوه و
+
+283
+00:24:18,070 --> 00:24:22,110
+الله لو غير كل الحمل و الولادة بس مشاكل المناهج
+
+284
+00:24:22,110 --> 00:24:26,490
+الجديدة على الإممايات الله يعطيهم العافية العملات
+
+285
+00:24:26,490 --> 00:24:28,710
+اللي هي هو وزارة التربية و التعليم و اللي بعلموا
+
+286
+00:24:28,710 --> 00:24:33,890
+صغار بيعرفوا كده الناس صاروا تعبانين بحياتهم من
+
+287
+00:24:33,890 --> 00:24:37,750
+ورا مناهج التربية و التعليم اللي عندها الأطفال
+
+288
+00:24:37,750 --> 00:24:43,110
+الصغار واضح؟
+
+289
+00:24:44,190 --> 00:24:50,490
+بهمش خليهم يسمعونا يعني احنا اليوم بنجيبلكم معادلة
+
+290
+00:24:50,490 --> 00:24:56,590
+اوزنونا إياها معادلة أكسدة واختزال من السبعين
+
+291
+00:24:56,590 --> 00:25:01,270
+طالبة يمكن خمست عشر بيجاوبون إياها صح وانا لو
+
+292
+00:25:01,270 --> 00:25:04,330
+سألكوا هذا الموضوع وزن المعادلات الأكسدة واختزال
+
+293
+00:25:04,330 --> 00:25:08,890
+الموضوع سهل ولا صعب جزء كبير منكم هيقول صعب الان
+
+294
+00:25:08,890 --> 00:25:15,770
+لما بيجوا بيحطوا هذه المعادلة للصف التاسعوبطلبوا
+
+295
+00:25:15,770 --> 00:25:19,310
+منهم إنهم يوزنوها وحتى الأمثلة اللي بيحطولهم إياها
+
+296
+00:25:19,310 --> 00:25:25,030
+في الكتاب مش سهلة وأكتر من مدرس ومدرسة شفتهم
+
+297
+00:25:25,030 --> 00:25:30,050
+عاملينها غلط أو مش عارفين يعملوها وعاندين وزارة
+
+298
+00:25:30,050 --> 00:25:34,030
+التربية والتعليم لدرجة أنا مرة بعتلهم رسالة إذا
+
+299
+00:25:34,030 --> 00:25:37,550
+الطالب بوزن معادلة أكسدة واختزالة في تالتة أعدادي
+
+300
+00:25:37,550 --> 00:25:42,130
+هياخد جائزة نوبل في الكيميا بأولى ثانويو مازال
+
+301
+00:25:42,130 --> 00:25:46,370
+الموضوع موجود غصب من عنهم الطلاب في الآخر صفي
+
+302
+00:25:46,370 --> 00:25:52,710
+عندنا 15% علمي ولا 20% و باقي الطلاب كله أدبي و
+
+303
+00:25:52,710 --> 00:25:57,090
+ماحدش راضي يدخل الكليات العلمية مظبوط ولا لا؟
+
+304
+00:25:57,090 --> 00:26:01,310
+لأنهم كرهوا الناس في العلم اللي جابنا على هالكلام
+
+305
+00:26:01,310 --> 00:26:09,290
+كلهالتأكيد والمناهج إذا هذا أكسيد ولا بيروكسيد؟ أه
+
+306
+00:26:09,290 --> 00:26:14,090
+في أكم أكسوجينة، في أكسجيل زيادة الآن هذا
+
+307
+00:26:14,090 --> 00:26:18,270
+البروكسيد إذا اتكون بكمية كبيرة يعني ال ether
+
+308
+00:26:18,270 --> 00:26:22,470
+انترك لفترة طويلة و أخد فترة و مفتوح البُتل شوية و
+
+309
+00:26:22,470 --> 00:26:27,710
+دخلوا أكسجيل بيصير عبارة عن مادة صلبة موجودة بيشوف
+
+310
+00:26:27,710 --> 00:26:33,950
+الإنسان بعينيهفإذا شفتوا في ايبوت الاثر مادة صلبة
+
+311
+00:26:33,950 --> 00:26:37,870
+ارموه ما تستعملهوش راجعوا لا الفن ولا لا الشركة
+
+312
+00:26:37,870 --> 00:26:42,950
+يتخلصوا منه منه بطريقتهم يعني مالوش علاج معنى ذلك
+
+313
+00:26:42,950 --> 00:26:48,910
+كمية كبيرة منه اتحولت إلى بيروكسايد ويمثل خطورة
+
+314
+00:26:48,910 --> 00:26:53,370
+كبيرة الان ممكن تكون كمية صغيرة اتحولت لبروكسايد
+
+315
+00:26:53,370 --> 00:26:59,860
+وذائبة في الاثر يعني انا اشوفهصافي لكن هو حقيقة في
+
+316
+00:26:59,860 --> 00:27:04,600
+كمية صغيرة دائبة فيه واضح؟ في هذه الحالة بعمله فحص
+
+317
+00:27:04,600 --> 00:27:08,720
+يعني اللي بده أعمله فحص هو اللي بيكون clear
+
+318
+00:27:08,720 --> 00:27:13,200
+solution أما اللي فيه المادة الصلبة خلاص مابلزمش
+
+319
+00:27:13,200 --> 00:27:18,840
+نعمله فحص بلزم نعمله فحص؟ لأ واضح؟ خلاص بنرجعه
+
+320
+00:27:18,840 --> 00:27:24,340
+الآن اللي فيه المادة ذائبة إيش بيعمله؟ بيضيفوا
+
+321
+00:27:24,340 --> 00:27:30,580
+عليه FESO4فرّك الصرفات
+
+322
+00:27:30,580 --> 00:27:36,500
+لأن هذا oxidizing agent بيعمل أكسد لـ Fe2 plus هنا
+
+323
+00:27:36,500 --> 00:27:42,800
+بتصير Fe3 plusمو هذا فيه أكسجين زيادة عامل مؤكسد
+
+324
+00:27:42,800 --> 00:27:44,980
+البروكسايتز مؤكسد عامل مؤكسد البروكسايتز مؤكسد
+
+325
+00:27:44,980 --> 00:27:49,500
+عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل
+
+326
+00:27:49,500 --> 00:27:53,580
+مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد
+
+327
+00:27:53,580 --> 00:27:58,000
+عامل مؤكسد
+
+328
+00:27:58,000 --> 00:28:02,680
+عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل
+
+329
+00:28:02,680 --> 00:28:03,660
+مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد
+
+330
+00:28:03,660 --> 00:28:09,840
+عامل مؤكسد عامل مؤكسدالـ FE3 Plus أخدته test له
+
+331
+00:28:09,840 --> 00:28:15,800
+كيف نفحصه؟ بنضيف عليه الـ SCN- بيعطينا اللون
+
+332
+00:28:15,800 --> 00:28:20,760
+الأحمر الدمو الـ red color واضح؟ إذا أنا بضيف
+
+333
+00:28:20,760 --> 00:28:25,820
+FESO4 على الـ ether اللي بيكون clear بحركه شوية و
+
+334
+00:28:25,820 --> 00:28:32,540
+بحط بعدين فوقه SCN- إذا أعطاني لون أحمرإذا في عنده
+
+335
+00:28:32,540 --> 00:28:37,660
+Fe3+, طب من أين جاء الـ Fe3+, من الـ Fe2+, ماهو
+
+336
+00:28:37,660 --> 00:28:42,920
+أكسر الـ Fe2% لـ Fe3%؟ البروكسايد، إذا أنا شوفت
+
+337
+00:28:42,920 --> 00:28:47,890
+اللون الأحمر، معناه ذلك في عنده البروكسايدواضح؟
+
+338
+00:28:47,890 --> 00:28:52,130
+واعتمادا على غمج اللون انا بقدر اقول ان البروكسايد
+
+339
+00:28:52,130 --> 00:28:57,510
+اللى عندى كتير ولا قليل الان طالما ال ether clear
+
+340
+00:28:57,510 --> 00:29:01,850
+solution مش مرسّب المادة كمادة صلبة ممكن ان اعمله
+
+341
+00:29:01,850 --> 00:29:07,510
+معالجة ايش المعالجة اللى بعملها؟ بصير اضيف عليه
+
+342
+00:29:07,510 --> 00:29:14,790
+كميات اكبر من ال FESO4فهو لما بيشتغل كعمل مؤكسد
+
+343
+00:29:14,790 --> 00:29:20,090
+بيشيل إيش؟ بيشيل هذا الـ Oxygen و بيرجع لإيثار
+
+344
+00:29:20,090 --> 00:29:26,370
+عادي، واضح؟ فب .. ب .. بعمله shaking إضافي بكمية
+
+345
+00:29:26,370 --> 00:29:32,310
+أكبر من الـ FeSO4 و برود بعمل فحص لحد ما في
+
+346
+00:29:32,310 --> 00:29:40,340
+النهاية أبطل أشوف اللون الأحمربكون اتخلصت من كل
+
+347
+00:29:40,340 --> 00:29:44,500
+البروكسايد .. بكون اتخلصت من كل البروكسايد طبعا
+
+348
+00:29:44,500 --> 00:29:49,780
+لما احنا نعمل shaking بيكون هذا محلول مائي وهذا
+
+349
+00:29:49,780 --> 00:29:53,980
+محلول إيثار يعني ما بيخلطوش مع بعض .. shaking
+
+350
+00:29:53,980 --> 00:30:00,140
+بهدوءمش بقوة كبيرة والمياه بنفصلها بما حاولت مرتين
+
+351
+00:30:00,140 --> 00:30:05,540
+تلاتة بنعود نفحص ال ether بنلاقي رجع ether عادي
+
+352
+00:30:05,540 --> 00:30:15,400
+وبذلك بنتخلص احنا من قصة اللي هي خطر البروكسايد او
+
+353
+00:30:15,400 --> 00:30:19,300
+خطر الانفجار اذا دائما وانتوا بتتعاملوا مع ال
+
+354
+00:30:19,300 --> 00:30:21,940
+aethers حطوا في بالكوا تلت مخاطر
+
+355
+00:30:25,130 --> 00:30:30,130
+anesthetic properties له الشغلة التانية can form
+
+356
+00:30:30,130 --> 00:30:35,470
+explosive peroxides
+
+357
+00:30:35,470 --> 00:30:40,490
+ممكن يعمل peroxides و ال peroxides هذي لا سمح الله
+
+358
+00:30:40,490 --> 00:30:49,030
+انفجر واضح؟بعد ما صار عندى Ether جاهز تماما ان انا
+
+359
+00:30:49,030 --> 00:30:54,890
+استعمله ك solvent من أشهر استعمالات ال ether ك
+
+360
+00:30:54,890 --> 00:31:00,010
+solvent بيستعملوه بتفاعل شهير اسمه Greenyard
+
+361
+00:31:00,010 --> 00:31:04,750
+reaction بنحضر من خلاله Greenyard reaction وهذا
+
+362
+00:31:04,750 --> 00:31:09,510
+Greenyard التفاعل اللى عمله أخد عليه جائزة نوبل في
+
+363
+00:31:09,510 --> 00:31:14,930
+الكيميا يمكن بالـ1911 تماما قبل مائة سنةعشان
+
+364
+00:31:14,930 --> 00:31:19,210
+تشوفوا كده العالم كان بيشتغلوا متطور في الكيميا
+
+365
+00:31:19,210 --> 00:31:25,570
+الان ايش هو تفاعل جرينيارد reaction هذا تفاعل
+
+366
+00:31:25,570 --> 00:31:31,070
+جرينيارد reaction لو انا اخدت ARX او حتى ARX
+
+367
+00:31:31,070 --> 00:31:38,570
+وفعلتها مع بودرة مغنيسيامواضح؟ الـ RX Alkyl Halide
+
+368
+00:31:38,570 --> 00:31:45,930
+أو ARX يعني هنا يجوز أن تكون RX أو ARX وفعالة مع
+
+369
+00:31:45,930 --> 00:31:51,650
+بودرة مغنيسيوم الشرط في وجود Dry Ether يعني Ether
+
+370
+00:31:51,650 --> 00:31:56,790
+مافيش في جلبه ميه، بنمرره على عوامل مجففةبيعطيني
+
+371
+00:31:56,790 --> 00:32:04,710
+هذا المركب RMGX هذا المركب RMGX هو اللي بنسميه
+
+372
+00:32:04,710 --> 00:32:10,850
+احنا Greenyard Reagent متفاعل Greenyard واضح؟ طيب
+
+373
+00:32:10,850 --> 00:32:17,240
+ايش فيته هذا متفاعل Greenyard؟متفاعلي Greenyard
+
+374
+00:32:17,240 --> 00:32:24,080
+يمثل بالنسبة لنا مصدر لمجموعة R مع أزواج
+
+375
+00:32:24,080 --> 00:32:28,100
+الإلكترونات تبعها يعني بتصير الـR مع أزواج
+
+376
+00:32:28,100 --> 00:32:32,160
+الإلكترونات من وين بقدر أحصل عليها؟ من
+
+377
+00:32:32,160 --> 00:32:35,540
+الـGreenyard، لاحظوا، هذه فائدة الـGreenyard أنه
+
+378
+00:32:35,540 --> 00:32:41,260
+أنا لما بدي R مع أزواج الإلكترونات تبعتها، بحصل
+
+379
+00:32:41,260 --> 00:32:47,900
+عليها منلـ Grignard Reagent طبعاً لو انتوا بتكونوا
+
+380
+00:32:47,900 --> 00:32:56,520
+تيجوا تتطلعوا أنا بدأت بإيش؟ ب R X لو بدأتي أتطلع
+
+381
+00:32:56,520 --> 00:32:59,800
+على ال R X مين اللي كانت more electronegative
+
+382
+00:32:59,800 --> 00:33:04,040
+وتاخد أزواج الإلكترونات؟ ال X بمعنى لو أنا بدي
+
+383
+00:33:04,040 --> 00:33:08,580
+أفعل بس ال R X هتيجي ال X تاخد أزواج الإلكترونات
+
+384
+00:33:08,580 --> 00:33:11,540
+ويتكون عندي R Plus وهذا شفتوا بتفعل ال
+
+385
+00:33:11,540 --> 00:33:16,480
+substitutionاللي هو الـ Carbocation بينما أنا هنا
+
+386
+00:33:16,480 --> 00:33:22,140
+بحاجة إلى الـ R مع الإلكترونات أشبه ما تكون بـ
+
+387
+00:33:22,140 --> 00:33:26,840
+Carbanion هي ما بتكونش منفصلة لكن في لحظة التفعل
+
+388
+00:33:26,840 --> 00:33:32,360
+بتعطيني R مع أزواج الإلكترونات فكأنه هنا خلّيني
+
+389
+00:33:32,360 --> 00:33:41,620
+أقول يعني similar يعني شبيهة to إيش؟Carb and Ion
+
+390
+00:33:41,620 --> 00:33:46,200
+يعني كأنه كربون وعليه شحنة سالبة هو مابيكونش
+
+391
+00:33:46,200 --> 00:33:50,560
+المركب ايوني بيكون molecular وبيعطيه ال R و هذه
+
+392
+00:33:50,560 --> 00:33:54,920
+الى تطبيقات كتيرة هناخد كذا تطبيقه هناخد تفاعله مع
+
+393
+00:33:54,920 --> 00:33:59,920
+ال ال دي هايتز مع ال E Stars مع أشياء تانية لكن
+
+394
+00:33:59,920 --> 00:34:06,440
+لحظة خلينا بس نتعرفعليه هذه كمتفاعل طيب إيش دخل ال
+
+395
+00:34:06,440 --> 00:34:10,740
+ether في الموضوع ال ether هو ال solvent اللي بتنفي
+
+396
+00:34:10,740 --> 00:34:14,660
+التفاعل فبيكون عامة نوع من ال stabilization لهذه
+
+397
+00:34:14,660 --> 00:34:18,700
+بمعنى بيكون محوطة من فوق و من تحت بس يعني هو ال
+
+398
+00:34:18,700 --> 00:34:24,990
+solvent يساعد على تكوينهالكن أنا الـ reagent اللي
+
+399
+00:34:24,990 --> 00:34:31,850
+عنده هو الـ RMGX من الـ RMGX اللي مهتم أنا فيه
+
+400
+00:34:31,850 --> 00:34:36,930
+كيميائيا الـ R مع إلكتروناتها فكأنه في النهاية لو
+
+401
+00:34:36,930 --> 00:34:40,590
+بدأتش أسألكوا سؤال بسيط لو قلتلكوا Greenyard
+
+402
+00:34:40,590 --> 00:34:45,870
+reagent بالمجمل يمثللي Electrophile ولا
+
+403
+00:34:45,870 --> 00:34:49,350
+Nucleophile؟ Nucleophile
+
+404
+00:34:51,050 --> 00:34:56,190
+واضح؟ يعني كأنه صار عنده carbon nucleophile هذه
+
+405
+00:34:56,190 --> 00:35:00,190
+فائدة الـ Green Yardary Agent وهذه فائدة كبيرة
+
+406
+00:35:00,190 --> 00:35:05,250
+جداً طبعاً لأنه يمثل الـ nucleophile لأنه يمثل الـ
+
+407
+00:35:05,250 --> 00:35:11,030
+nucleophile وفي إلكترونات وين ما بيلاقي إشي موجب
+
+408
+00:35:11,030 --> 00:35:18,710
+بده يتفاعل معه مش هو سالب إذا السالب وين ما بيلاقي
+
+409
+00:35:18,710 --> 00:35:24,410
+موجببدي اتفاعل معاه يعني لو مثلا حطيت ميه او
+
+410
+00:35:24,410 --> 00:35:29,770
+اثانول او حامض او امين كل هدولة فيهم ايش القاسم
+
+411
+00:35:29,770 --> 00:35:36,070
+المشترك بينهم ال H plus بروح بياخد مباشرة منهم H
+
+412
+00:35:36,070 --> 00:35:43,730
+plus وبيعطيني RH لأن هو سالب وبيبحث عن الموجب طبعا
+
+413
+00:35:43,730 --> 00:35:49,450
+هل يا ترى هذا يعتبر تفاعل؟ هو تفاعل لكنه تفاعل غير
+
+414
+00:35:49,450 --> 00:35:57,380
+مرغوبلأن ال R هذه لازماني لأمور أخرى .. الآن تيجي
+
+415
+00:35:57,380 --> 00:36:00,840
+طالبة تشتغل ب flask يكون فيه شوية ميه و غيره و
+
+416
+00:36:00,840 --> 00:36:04,960
+غيراته و حضرت ال R MGX و لازماني لأمور أخرى .. و
+
+417
+00:36:04,960 --> 00:36:09,460
+ال flask تبعها في ميه .. بتروح ال R .. بتاخد H و
+
+418
+00:36:09,460 --> 00:36:14,710
+صارت RH .. هو أنا ناجسني RH .. أنا ناجسني ال Kأنا
+
+419
+00:36:14,710 --> 00:36:19,170
+بحضر ال green yard عشان في الآخر بده احضر منه ال
+
+420
+00:36:19,170 --> 00:36:23,210
+cane ولا لازمنا لتفاعلات تانية لازمنا لتفاعلات
+
+421
+00:36:23,210 --> 00:36:27,870
+تانية ولذلك الشرق هنا ايش يكون هذا ال dry ether
+
+422
+00:36:27,870 --> 00:36:33,670
+مافيش فيه اي مصدر لل H plus فكأننا بنقول انه الميه
+
+423
+00:36:33,670 --> 00:36:39,500
+بتخربمتفاعل الـ Green Yard الميّه والإيثانول و
+
+424
+00:36:39,500 --> 00:36:43,300
+الحامض كل شيء فيه H Plus حتى لو أخذنا الماء الثقيل
+
+425
+00:36:43,300 --> 00:36:52,460
+الـ D2O معه، سيعطينا RD إذا أنا مهتم أحضر RD على
+
+426
+00:36:52,460 --> 00:36:56,460
+العين والرأس، بيكون تفاعل إذا مش مهتم، معناه ذلك
+
+427
+00:36:56,460 --> 00:37:03,830
+يعمل بس بتخرّب إذا أنا مهتم أحضر RHع العين والرأس،
+
+428
+00:37:03,830 --> 00:37:07,290
+لكن إذا أنا مش مهتم إن أحضر RH، معنا ذلك الميه
+
+429
+00:37:07,290 --> 00:37:11,950
+هنا، بس بتخرّب علينا، واضح؟ بس بتخرّب علينا
+
+430
+00:37:16,320 --> 00:37:21,100
+ناخد مثال لو مثلًا قلنا لكم كيف تحضروا هذا
+
+431
+00:37:21,100 --> 00:37:25,080
+المُركّب اللي هو الـ isopropyl group اللي متصل
+
+432
+00:37:25,080 --> 00:37:30,240
+بالديوتيريام الديوتيريام نظيف الهيدروجين هتيجي
+
+433
+00:37:30,240 --> 00:37:37,120
+تفكروا أن هذا من وين بده يكون إجا الديوتيريام بده
+
+434
+00:37:37,120 --> 00:37:41,440
+يجي من a greenier reaction يعني كأنه الخطوة
+
+435
+00:37:41,440 --> 00:37:47,050
+السابقة بده يكون عندنا هذا المتفاعل مع Mgنفترض بي
+
+436
+00:37:47,050 --> 00:37:54,790
+اه الفعله مع D to O شو بيعطينا بدل ال MgBr؟ الـ
+
+437
+00:37:54,790 --> 00:38:00,950
+Deuterium لو فعله مع H to O شو بيعطينا بدالها؟ H
+
+438
+00:38:00,950 --> 00:38:06,270
+رأته اللي طلعت عنده ال MgX فعلته مع مية بيعطينا
+
+439
+00:38:06,270 --> 00:38:11,160
+بدالة H فعلته مع D to O بيعطينا بدالها؟دى بناء على
+
+440
+00:38:11,160 --> 00:38:15,280
+ذلك لو أنا كان عندى مركب لبروم وعملت منه green
+
+441
+00:38:15,280 --> 00:38:20,780
+yard نمرة واحد ونمرة اتنين صفر D to O بحول محكر
+
+442
+00:38:20,780 --> 00:38:27,400
+لبروم الى D بس كأنه انا ماشي بخطوطين هى نمرة واحد
+
+443
+00:38:27,400 --> 00:38:33,680
+و هى نمرة اتنين نمرة واحد تتحول لبروم و compound
+
+444
+00:38:33,680 --> 00:38:38,000
+لبروم و compound الى green yard نمرة اتنين ل green
+
+445
+00:38:38,000 --> 00:38:44,840
+yardإن فعلوا مع ال D2O بيجي مكانه ديوتيريام إذا لو
+
+446
+00:38:44,840 --> 00:38:49,360
+أنا قلتلكم من ال isopropyl bromide بدي مركب
+
+447
+00:38:49,360 --> 00:38:54,400
+لديوتيريام، بدنا نمشي كام خطوة؟ واحدة، تنتين طيب،
+
+448
+00:38:54,400 --> 00:38:57,340
+لو ماعطيتكوش ال isopropyl bromide، لو رجعت فيكوا
+
+449
+00:38:57,340 --> 00:39:00,740
+خطوة لوراه، أراجع ال synthesis اللي اتعلمتوا،
+
+450
+00:39:00,740 --> 00:39:07,660
+قلتلكوا بدي من ال .. البروبيل، بنضيف HPR في وجود
+
+451
+00:39:08,980 --> 00:39:13,800
+الـ H plus بيحط H و بيقعد صار عندي هذا و بنكمل إذا
+
+452
+00:39:13,800 --> 00:39:18,020
+نزلنا بس إيش خطوة لو كان عندي هنا ال alcohol هذه
+
+453
+00:39:18,020 --> 00:39:20,740
+مش alcohol
+
+454
+00:39:22,380 --> 00:39:26,960
+Isopropyl Alcohol وقلتلكم من الـ Isopropyl Alcohol
+
+455
+00:39:26,960 --> 00:39:31,620
+سؤال في الامتحان How can you prepare this compound
+
+456
+00:39:31,620 --> 00:39:34,860
+starting from isopropyl alcohol انتوا حتيجوا
+
+457
+00:39:34,860 --> 00:39:37,180
+ترجعوا برجعوا لورا بتعملوا إشي بنسميه
+
+458
+00:39:37,180 --> 00:39:42,840
+Retrosynthesis بتقولوا هذه ال D كانت MgBr ال MgBr
+
+459
+00:39:42,840 --> 00:39:47,520
+كانت PR أنا ماعنديش PR أنا عندي OH هل اتعلمنا
+
+460
+00:39:47,520 --> 00:39:56,330
+طريقة انحول فيها ال OH إلى PRأكيد كنا نفعل مع ال
+
+461
+00:39:56,330 --> 00:40:01,990
+PPR3 أو ال HPR في تفاعلات ال alcohols لما أخدنا
+
+462
+00:40:01,990 --> 00:40:10,350
+reaction of alcohols with HPR او PPR3 هنا ال HPR
+
+463
+00:40:10,350 --> 00:40:17,610
+بيمشي و ال PPR3 بيمشي واضح؟ لو كنا بنتحولها لCL
+
+464
+00:40:17,610 --> 00:40:27,410
+بنفعل HCLالالكول بيتحول بسهولة باستعمال ال HCl ولا
+
+465
+00:40:27,410 --> 00:40:34,290
+لازم أستعمل reagent تاني؟ يا بتستعمل BCl3 يا
+
+466
+00:40:34,290 --> 00:40:41,750
+ثيونيلاكلورايد تذكروا آخر محاضرة قلنا ال alcohols
+
+467
+00:40:41,750 --> 00:40:47,690
+لما بتحولوا لalkyl halides كنا بنستعمل BX3 أو
+
+468
+00:40:47,690 --> 00:40:49,710
+ثيونيلاكلورايد
+
+469
+00:40:56,340 --> 00:41:00,700
+تاكرتكم؟ على أي حال بنقف عند هذا الموضوع وان شاء
+
+470
+00:41:00,700 --> 00:41:04,720
+الله المحاضرة الجاية بنحكي فيه ال preparation of
+
+471
+00:41:04,720 --> 00:41:07,380
+ethers and their reactions
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3379df89c42d533cf39ad24e031282268193c696
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8_raw.srt
@@ -0,0 +1,1892 @@
+1
+00:00:09,410 --> 00:00:15,770
+بسم الله الرحمن الرحيم اليوم بنبدأ
+
+2
+00:00:15,770 --> 00:00:21,610
+بفصل جديد هو الفصل الثامن بتعرفوا الفصل السابق كان
+
+3
+00:00:21,610 --> 00:00:27,930
+عن ال alcohols يعني R وH الآن بنمشي خطوة للأمام لل
+
+4
+00:00:27,930 --> 00:00:35,390
+ethers بنصير R وR يعني الإختلاف أنه بدلنا H بR
+
+5
+00:00:37,440 --> 00:00:42,040
+بدل ما كان عندى في ال alcohols R.O.H في ال ethers
+
+6
+00:00:42,040 --> 00:00:49,980
+بيصير عندى R.O.R طبعا هذا التبديل الحقيقة بيجلب كل
+
+7
+00:00:49,980 --> 00:00:53,740
+إشي يعني مابنعش نقول أنه تبديل بسيط لأ الخواص و
+
+8
+00:00:53,740 --> 00:00:58,740
+التحضير كل إشي بيختلف تماما نتيجة هذا التبديل
+
+9
+00:00:58,740 --> 00:01:05,380
+فالخلاصة ال ethers الصيغة العامة إلهم إيش R.O.R
+
+10
+00:01:05,380 --> 00:01:12,130
+لاحظوا أولخاصية بتيجي على بالنا ال polarity لما
+
+11
+00:01:12,130 --> 00:01:19,830
+نيجي نقارنهم بال alcohol مثلا R O H ولا R O R؟ R O
+
+12
+00:01:19,830 --> 00:01:26,030
+H is more polar than ethers ليش؟ لأن هناك في عندى
+
+13
+00:01:26,030 --> 00:01:30,870
+hydrogen bonding فال ethers ال polarity تبعتهم أقل
+
+14
+00:01:30,870 --> 00:01:38,890
+من ال alcohol بشكل عام ال solubilityبرضه بيبطلوا
+
+15
+00:01:38,890 --> 00:01:42,910
+يدوبوا في الميه، ليش؟ لإن أساسا ذائبية ال alcohol
+
+16
+00:01:42,910 --> 00:01:46,290
+في الميه كانت معتمدة على إيش؟ على ال hydrogen
+
+17
+00:01:46,290 --> 00:01:54,060
+bonding، واضح؟وعلى كبر ال الكلجروب الان يعني
+
+18
+00:01:54,060 --> 00:01:59,120
+ابتداء من الداي إيثل إيثر الداي إيثل إيثر بدوبش في
+
+19
+00:01:59,120 --> 00:02:03,660
+الميه و بيعمله extraction .. بيعمله extraction لل
+
+20
+00:02:03,660 --> 00:02:07,300
+organ ال compounds بيستعمله واضح؟ يعني إذا قولنا
+
+21
+00:02:07,300 --> 00:02:12,590
+الداي ميثل إيثر اللي هو أصغر إيثر هذا غازلما نبدأ
+
+22
+00:02:12,590 --> 00:02:16,190
+في الـ liquids أول liquid في الـ aethers الـ
+
+23
+00:02:16,190 --> 00:02:19,410
+Diethyl ether الـ Diethyl ether لا تدوب في الماء
+
+24
+00:02:19,410 --> 00:02:24,150
+واضح؟ طبعا و باقي الـ aethers بالتأكيد لا تدوب في
+
+25
+00:02:24,150 --> 00:02:27,690
+الماء الـ melting points و الـ boiling points
+
+26
+00:02:27,690 --> 00:02:31,590
+تبعونهم أقل كتير من الالكوهولز لأنهم بالالكوهولز
+
+27
+00:02:31,590 --> 00:02:35,470
+كانوا مرفوعين بالـ hydrogen bonding يعني الـ
+
+28
+00:02:35,470 --> 00:02:39,510
+Diethyl ether مثلا الـ boiling point له ستة
+
+29
+00:02:39,510 --> 00:02:45,290
+وتلاتين أو سبعة وتلاتينبينما خدوا الاثانول كان
+
+30
+00:02:45,290 --> 00:02:51,670
+واحد و تمانين لاحظوا مع العلم ان الاثانول لسه في
+
+31
+00:02:51,670 --> 00:02:57,790
+الوزن جد نص الداي اثل ايثر يعني هناك عندي اثل او
+
+32
+00:02:57,790 --> 00:03:04,150
+اثل الاثانول اثل او اتش اذا مين اصغر كتير في الوزن
+
+33
+00:03:04,830 --> 00:03:08,950
+الإيثانول لكن في ال boiling point أعلى كثير شو
+
+34
+00:03:08,950 --> 00:03:13,110
+السبب ال hydrogen bonding إذا لاحظوا عما معظم
+
+35
+00:03:13,110 --> 00:03:17,530
+الخواص اللي قادة تختلف نتيجة اختلاف هذه ال R بدل
+
+36
+00:03:17,530 --> 00:03:24,860
+ما كانت R صارت H واضحأيضًا الـ Alcohols كانوا
+
+37
+00:03:24,860 --> 00:03:28,240
+بالتفاعلات، اللي لهم عدد كبير من التفاعلات، مظبوط
+
+38
+00:03:28,240 --> 00:03:31,880
+ولا لأ؟ أخدتوا تفاعلات substitution و تفاعلات
+
+39
+00:03:31,880 --> 00:03:37,240
+elimination و تفاعلات على حذف ال .. ال H مثلًا مع
+
+40
+00:03:37,240 --> 00:03:41,920
+الصوديوم as acids الethers they are generally
+
+41
+00:03:41,920 --> 00:03:47,070
+chemically inert، يعني خاملين كيميائيًاولذلك
+
+42
+00:03:47,070 --> 00:03:53,870
+الكثير من ال ethers تستعمل ك solvent من المميزات
+
+43
+00:03:53,870 --> 00:03:59,990
+اللي لازم يتمتع بفيها ال solvent انه يكون محايد
+
+44
+00:03:59,990 --> 00:04:05,610
+مايتفعلش يعني انا بدي اياه وسطوسط لإجراء التفاعل
+
+45
+00:04:05,610 --> 00:04:12,010
+بإنفعش هو يدخل و
+
+46
+00:04:12,010 --> 00:04:16,830
+يتفاعل ال solvent لازم يكون فقط وسط لإجراء التفاعل
+
+47
+00:04:16,830 --> 00:04:22,050
+يكون محايد لا اميل مع هذه المادة ولا مع هذه المادة
+
+48
+00:04:22,050 --> 00:04:25,190
+يعني انا بدي ادوب مادتين فيه اسيب المادتين
+
+49
+00:04:25,190 --> 00:04:30,490
+يتفاعلوا لحالهم مش هو يروح يتفاعل معهم واضح؟و هذا
+
+50
+00:04:30,490 --> 00:04:34,570
+الكلام يعني له انعكاس حقيقة في .. حتى في الواقع
+
+51
+00:04:34,570 --> 00:04:39,850
+الإنساني لما نيجي نقول أنه بدنا شخص يكون واسطة يحل
+
+52
+00:04:39,850 --> 00:04:44,910
+مشكلة بين اتنين المفروض مايكونش مرتبط لا مع هذا
+
+53
+00:04:44,910 --> 00:04:49,870
+ولا مع هذا أقل تقدير ارتباط male يعني ممكن يكون
+
+54
+00:04:49,870 --> 00:04:58,440
+مرتبطبصداقة بعائلة لكن لما ييجي حكم او وسط مش لازم
+
+55
+00:04:58,440 --> 00:05:03,720
+يميل هان ولا هان ايش مشكلة القضية الفلسطينية كلها؟
+
+56
+00:05:03,720 --> 00:05:10,710
+ان الحكامعوج من الحُكّام الأمم المتحدة والاتحاد
+
+57
+00:05:10,710 --> 00:05:14,590
+الأوروبي وبريطانيا وروسيا اللي أسسوا إسرائيل، في
+
+58
+00:05:14,590 --> 00:05:18,070
+آخر بيجو، بدهم يشرفوا على مفاوضات بين الفلسطينية
+
+59
+00:05:18,070 --> 00:05:22,990
+واليهود، هل هما محايدين؟ عشان هيك كل المسار تبعهم
+
+60
+00:05:24,540 --> 00:05:27,900
+اللي مش مصدق انه فاشل يقول انه مش فاشل ما انتوا
+
+61
+00:05:27,900 --> 00:05:31,900
+شايفين يعني ما .. مافيش براوح مكانه يعني مافيش
+
+62
+00:05:31,900 --> 00:05:35,880
+مفكر إلا بيقول قاعدين بتراوحوا مكانكوا و بالعكس
+
+63
+00:05:35,880 --> 00:05:41,820
+تلتهم الأرض و غيرها و غيرها لإنه ال solvent مش
+
+64
+00:05:41,820 --> 00:05:46,100
+inert لازم ال solvent يكون inert مايدخلش في
+
+65
+00:05:46,100 --> 00:05:52,450
+التفاعل أما نحط أمريكا solvent بنفعبشكل عام الـ
+
+66
+00:05:52,450 --> 00:05:56,950
+ethers فيهم مشكلة انهم قابلين للاشتعال بمعنى سريعي
+
+67
+00:05:56,950 --> 00:06:00,750
+الاشتعال و قابلين للاشتعال عشانك اللي بتعامل مع ال
+
+68
+00:06:00,750 --> 00:06:04,630
+ethers بالذات ال low boiling point ethers اللي هي
+
+69
+00:06:04,630 --> 00:06:09,130
+منخفضة درجة الغليان فبتطلع ابخرته وين ما في نار في
+
+70
+00:06:09,130 --> 00:06:13,710
+المختبر ممكن تمسك وتولعواضح؟ و لذلك يجب أن يكون
+
+71
+00:06:13,710 --> 00:06:18,290
+عندكم حذر يعني أنا ما زلت بأذكر أنه اتنين زملاء
+
+72
+00:06:18,290 --> 00:06:22,310
+لنا في المختبر واحد مولع نار و بشتغل شغلة و التاني
+
+73
+00:06:22,310 --> 00:06:26,290
+عبعد مترين منه بشتغل بال ether فجأة اللي مولع
+
+74
+00:06:26,290 --> 00:06:31,570
+النار لجه حاله نفسه مولع من الأبخرة تبع ال ether
+
+75
+00:06:31,570 --> 00:06:37,790
+اللي إجت من الشخص المقابلفإذا اتعاملتم في المختبر
+
+76
+00:06:37,790 --> 00:06:42,610
+مع الـ Ether بتكون تتعاملوا بحذر مش تكونوا حاطين
+
+77
+00:06:42,610 --> 00:06:47,230
+مرتبان Ether مفتوح وعلى بعد عشرين، تلاتين، اربعين
+
+78
+00:06:47,230 --> 00:06:52,190
+سانتمتر، نص متر حاطين لبنزين بيرنر أكيد هيعمل
+
+79
+00:06:52,190 --> 00:06:56,470
+حريقة وأكيد هيعمل مصيبة، واضح؟ فالتعامل مع
+
+80
+00:06:56,470 --> 00:07:01,570
+الـEthers بده حذر لأن الـAll are very flammable
+
+81
+00:07:01,570 --> 00:07:07,910
+قابلين للاشتئال وبلوكة النار بسرعةالان اذا بدنا
+
+82
+00:07:07,910 --> 00:07:16,000
+نحكي عن تسمية الـ ethersفي عندنا common name و
+
+83
+00:07:16,000 --> 00:07:21,540
+أيوبك names ال common name إن أجيب ال ether إله
+
+84
+00:07:21,540 --> 00:07:27,540
+جنحين بظبط ولا لأ إله مجمعتين إن أجيب الأسماء لل
+
+85
+00:07:27,540 --> 00:07:32,700
+الكل groups و أذكرها يعني لو مثلا عندي هنا مثل و
+
+86
+00:07:32,700 --> 00:07:40,100
+مثل ether مثل و مثل شو بده أسميه؟die مثل اثر لو
+
+87
+00:07:40,100 --> 00:07:45,000
+كانت اثر او اثر مرات
+
+88
+00:07:45,000 --> 00:07:48,360
+حتى بيستغنوا عن ال die يعني بتلاقيهم كاتبين مثل
+
+89
+00:07:48,360 --> 00:07:52,120
+اثر اذا جريتوا مثل اثر هو ال die مثل اثر او
+
+90
+00:07:52,120 --> 00:07:56,420
+بتلاقيهم كاتبين اثر اثر يعني لو قلتلكوا ارسموا ال
+
+91
+00:07:56,420 --> 00:08:02,300
+اثر اثر بتكونوا تحطولي اثر او اثر بس اختصارا و
+
+92
+00:08:02,300 --> 00:08:09,000
+خلاص يعني تقليديا صاروا يقولوا ايشبدون إيش؟ بدون
+
+93
+00:08:09,000 --> 00:08:15,420
+كلمة الضايق هل يجوز إن الإنسان مثلا يذكر نص الإسم؟
+
+94
+00:08:15,420 --> 00:08:22,320
+لا و الله إذا فهمت ضمنا يجوز ماشي يعني لو بدنا
+
+95
+00:08:22,320 --> 00:08:27,620
+نعطيكم مثال الناس اللي بيروحوا على الجنوب بيكونوا
+
+96
+00:08:27,620 --> 00:08:32,100
+يشوفوا السيارات بيقولوا ع الدير الكل بيقول ع الدير
+
+97
+00:08:32,100 --> 00:08:35,100
+وين طالع ع الدير ولا بيقول ع الدير البلح كل واحد
+
+98
+00:08:36,120 --> 00:08:41,800
+بنجيب نص الإسم و يفهم ضمنا؟ أكيد .. اه .. و هنا لو
+
+99
+00:08:41,800 --> 00:08:46,480
+قلت مثل إيثار أو إثل إيثار المقصود فيه die مثل
+
+100
+00:08:46,480 --> 00:08:50,400
+إيثار و مثلها بالمناسبة ال مثلسلفيت كتير بتجروا
+
+101
+00:08:50,400 --> 00:08:55,780
+اسم مثلسلفيت بيكون المقصود فيها die مثلسلفيت اللي
+
+102
+00:08:55,780 --> 00:09:00,700
+هي مخدة الشكل اللي زيه بس double point او مثل مثل
+
+103
+00:09:00,700 --> 00:09:04,980
+فبنقول احنا die مثلسلفيت و ممكن يتلاقوا ناس كتير
+
+104
+00:09:05,230 --> 00:09:11,250
+اختصارا نقولوها مثل سولفات، واضح؟ إذا لما يكون هذه
+
+105
+00:09:11,250 --> 00:09:15,770
+المجموعتين زي بعض، خلّيني أقول مثل إيثر، مثل إيثر،
+
+106
+00:09:15,770 --> 00:09:19,310
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+107
+00:09:19,310 --> 00:09:21,590
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+108
+00:09:21,590 --> 00:09:23,590
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+109
+00:09:23,590 --> 00:09:23,630
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+110
+00:09:23,630 --> 00:09:25,010
+مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر، مثل إيثر،
+
+111
+00:09:25,010 --> 00:09:29,790
+مثل إيثر، مثل إيثر، مثل إيثر
+
+112
+00:09:48,720 --> 00:09:56,740
+مثلًا اذا كان المجموعات مختلفة مثلًا انا مثل وانا
+
+113
+00:09:56,740 --> 00:10:05,050
+CH2 CH2ثم اذا كنت تحب الذكر المجموعتين اذا كنت تحب
+
+114
+00:10:05,050 --> 00:10:07,210
+الذكر المجموعتين اذا كنت تحب الذكر المجموعتين اذا
+
+115
+00:10:07,210 --> 00:10:07,890
+كنت تحب الذكر المجموعتين اذا كنت تحب الذكر
+
+116
+00:10:07,890 --> 00:10:09,510
+المجموعتين اذا كنت تحب الذكر المجموعتين اذا كنت
+
+117
+00:10:09,510 --> 00:10:10,590
+تحب الذكر المجموعتين اذا كنت تحب الذكر المجموعتين
+
+118
+00:10:10,590 --> 00:10:12,950
+اذا كنت تحب الذكر المجموعتين اذا كنت تحب الذكر
+
+119
+00:10:12,950 --> 00:10:14,390
+المجموعتين اذا كنت تحب الذكر المجموعتين اذا كنت
+
+120
+00:10:14,390 --> 00:10:16,130
+تحب الذكر المجموعتين اذا كنت تحب الذكر المجموعتين
+
+121
+00:10:16,130 --> 00:10:21,750
+اذا كنت تحب الذكر المجموعتين اذا كنت تحب الذكر
+
+122
+00:10:21,750 --> 00:10:28,850
+المجمCH3 CH2 إثل فبصير كله chloromythin ethyl
+
+123
+00:10:28,850 --> 00:10:35,290
+ether واضح؟ الآن لاحظوا التسمية بهذه الطريقة ال
+
+124
+00:10:35,290 --> 00:10:40,030
+common name بتفترض شغلة أنه أنا أكون بسهولة بعرف
+
+125
+00:10:40,030 --> 00:10:42,070
+اسم المجموع اللي هنا و اللي هنا اللي هنا و اللي
+
+126
+00:10:42,070 --> 00:10:46,990
+هنا اللي هنا اللي هنا مرات كتيرة بتصعب الأمور يعني
+
+127
+00:10:46,990 --> 00:10:51,840
+بمعنى أنه أنتوا المجموعات اللي أخدتوهاعدد قليل من
+
+128
+00:10:51,840 --> 00:10:55,180
+المجموعات، يعني لو تتذكروا في ال الكل جروبز، أنتوا
+
+129
+00:10:55,180 --> 00:10:59,100
+أخدتوا الميثل، الاثل، البروبل، الايزوبروبل، ال
+
+130
+00:10:59,100 --> 00:11:04,840
+تيرتشار بيوتل، الفنل، الفنل، الألل، مصبوط ولا لا؟
+
+131
+00:11:04,840 --> 00:11:12,400
+بعد ذلك السكندر بيوتل، بعد ذلك ما أخدتوش؟مجموعات
+
+132
+00:11:12,400 --> 00:11:16,720
+وبناء على ذلك لو إحدى المجموعات كانت كبيرة مالهاش
+
+133
+00:11:16,720 --> 00:11:23,340
+اسم بسيط كيف بدي أسمي يعني لما يجيني مثلا CH3 CH و
+
+134
+00:11:23,340 --> 00:11:28,240
+أحط هنا CL و أحط هنا CH2 و أحط هنا CH3 تاني و
+
+135
+00:11:28,240 --> 00:11:33,040
+بعدين أحط هنا O CH3 و أقول بدي أسمي هذا ال ether
+
+136
+00:11:33,040 --> 00:11:39,900
+هنا لاحظوا حاطسين عندكم مشكلة انه هذه المجموعة CH3
+
+137
+00:11:40,830 --> 00:11:43,290
+معروفة اسمها مثلًا قابوهادي
+
+138
+00:11:46,370 --> 00:11:49,950
+مش من المجموعات اللي أخدناها و اللي إلها اسم و
+
+139
+00:11:49,950 --> 00:11:54,850
+بناءً على ذلك إذا كانت إحدى المجموعات مالهاش اسم
+
+140
+00:11:54,850 --> 00:11:59,350
+بسيط زي الأسماء اللي توي ذكرناها المطلوب نحوّل على
+
+141
+00:11:59,350 --> 00:12:03,910
+نظام تاني في تسمية الethers واضح؟ يعني بتصير
+
+142
+00:12:03,910 --> 00:12:07,550
+المسألة صعبة، مابقدرش أسميه و أعطي لهذه اسم
+
+143
+00:12:07,550 --> 00:12:12,280
+مجموعة، هذه مايلها نهائيا اسم مجموعةفي هذه الحالة
+
+144
+00:12:12,280 --> 00:12:17,380
+ماذا نفعل؟ نستعمل ايوباك نظام of nomenclature
+
+145
+00:12:17,380 --> 00:12:27,580
+نستعمل نظام ايوباك لنومنكلتشر ايوباك يعمل ايثر مثل
+
+146
+00:12:27,580 --> 00:12:34,520
+ما كنا نتعامل مع الالكينز طبعا أنا مابفضلشنقعد
+
+147
+00:12:34,520 --> 00:12:38,860
+نجرى كل هذا الكلام لكن بإمكاننا ناخد تطبيق بسيط
+
+148
+00:12:38,860 --> 00:12:42,060
+بإمكاننا ناخد تطبيق بسيط بالتطبيق بتصير الأمور
+
+149
+00:12:42,060 --> 00:12:48,100
+سهلة اتخيلوا مثلا هنا عندي ال O و انا عندي CH2 CH2
+
+150
+00:12:48,100 --> 00:12:54,840
+CH3 واضح ان هذا الصفر هي السلسلة الطويلة و هذا ال
+
+151
+00:12:54,840 --> 00:13:00,100
+O مع المثل السلسلة القصيرة الان لو انا افترض ان
+
+152
+00:13:00,100 --> 00:13:05,010
+انا اعطيكوا هذا الكلام و حاططلكوا هنا CLبذل الزرجة
+
+153
+00:13:05,010 --> 00:13:11,570
+شو هتسموا المُركّب؟ وان إكلورو إبروبين مظبوط ولا
+
+154
+00:13:11,570 --> 00:13:17,550
+لأ؟ لو حاطط PR وان إبرومو إبروبين الآن أنا مش
+
+155
+00:13:17,550 --> 00:13:25,250
+حاططه حاطط المجموعة OCH3 ال OCH3 نفسها إلها اسم ..
+
+156
+00:13:25,250 --> 00:13:32,750
+شو اسمها؟ مثوكسي مثوكسي مظبوط ولا لأ؟ O مثل مثوكسي
+
+157
+00:13:33,800 --> 00:13:44,140
+أو إثل إثوكسي أو فينل فينوكسي فينوكسي واضح ال أو
+
+158
+00:13:44,140 --> 00:13:45,560
+فينل فينوكسي
+
+159
+00:13:49,340 --> 00:13:54,240
+بناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+160
+00:13:54,240 --> 00:13:56,260
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+161
+00:13:56,260 --> 00:13:57,040
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+162
+00:13:57,040 --> 00:13:59,320
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+163
+00:13:59,320 --> 00:13:59,960
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+164
+00:13:59,960 --> 00:14:03,320
+وبناء العدالك اتل اثوكسي وبناء العدالك اتل اثوكسي
+
+165
+00:14:03,320 --> 00:14:09,020
+وبناء العدالك اتل اثوكسي وبناءواضح؟ صرت أطول سلسلة
+
+166
+00:14:09,020 --> 00:14:13,980
+عندى سلسلة البروبين وهو البروبين عليه مجموعة
+
+167
+00:14:13,980 --> 00:14:18,140
+الميثوكسين الان لو بدى أجي أطلع على هذا المركب
+
+168
+00:14:18,140 --> 00:14:22,300
+الان هنا عندى كام كربونة؟ واحدة هنا عندى كام
+
+169
+00:14:22,300 --> 00:14:28,040
+كربونة؟ واحد، اتنين هدولة الكربونتين شو عليهم ال
+
+170
+00:14:28,040 --> 00:14:32,520
+substituents؟ كلور على الذرع الأولى وإيش كمان؟
+
+171
+00:14:34,570 --> 00:14:42,850
+وميثوكسي عليها اتن ميثوكسي اتن ميثوكسي
+
+172
+00:14:42,850 --> 00:14:48,090
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+173
+00:14:48,090 --> 00:14:50,590
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+174
+00:14:50,590 --> 00:14:52,390
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+175
+00:14:52,390 --> 00:14:53,070
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+176
+00:14:53,070 --> 00:14:58,830
+اتن ميثوكسي اتن ميثوكسي اتن ميثوكسي
+
+177
+00:14:58,830 --> 00:15:06,770
+اتن مياللي فوق على موقع ات نيت شو شابك فيها برو
+
+178
+00:15:06,770 --> 00:15:14,630
+بوكسي اه
+
+179
+00:15:14,630 --> 00:15:19,050
+يعني خليني اكد عليه المثال هذا مرة تانية انه عندكم
+
+180
+00:15:19,970 --> 00:15:25,970
+سلسلة طويلة بيوتين من موقع 2xnt substitution فبناء
+
+181
+00:15:25,970 --> 00:15:31,190
+على ذلك هذا المُركّب يصبح 2-propoxy-butane الأن
+
+182
+00:15:31,190 --> 00:15:35,250
+لاحظوا في الأمثلة التلاتة اللي شرحناها المجموعة
+
+183
+00:15:35,250 --> 00:15:41,060
+لهذا السهل مثوكسيميثوكسي بروبوكسي واحدة ممكن تتسأل
+
+184
+00:15:41,060 --> 00:15:45,580
+طب تقول لو المجمعتين صاروا معقدين و صعبين وقتها
+
+185
+00:15:45,580 --> 00:15:50,000
+التسمية شوية بتصعب و بيصير المجموعة هذه بتحوطها
+
+186
+00:15:50,000 --> 00:15:54,480
+بين جثين و أفصل فيها مثلا لو كنت تتطلع على هذا
+
+187
+00:15:54,480 --> 00:15:59,450
+المركب اللي موجود عندناCH2 CH2 CH3 CH3 CH3 CH3 CH3
+
+188
+00:15:59,450 --> 00:16:05,770
+CH3 CH3 CH3 CH3 CH3
+
+189
+00:16:05,770 --> 00:16:07,370
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+190
+00:16:07,370 --> 00:16:07,930
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+191
+00:16:07,930 --> 00:16:08,970
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+192
+00:16:08,970 --> 00:16:09,330
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+193
+00:16:09,330 --> 00:16:09,330
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+194
+00:16:09,330 --> 00:16:09,330
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+195
+00:16:09,330 --> 00:16:10,530
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+196
+00:16:10,530 --> 00:16:13,850
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+197
+00:16:13,850 --> 00:16:17,810
+CH3
+
+198
+00:16:17,810 --> 00:16:24,590
+CH3 CH3 CH3مجموعة اذا بدي اقول three و اذكر اسم
+
+199
+00:16:24,590 --> 00:16:31,110
+المجموعة المجموعة اسمها مش مباشر لانها CH2 CH2 CL
+
+200
+00:16:31,110 --> 00:16:34,950
+و بناء على ذلك كأن غير الترقيم اللي بدي اعمله هو
+
+201
+00:16:34,950 --> 00:16:39,450
+one two three four بدي اعمل ترقيم تاني لهذه
+
+202
+00:16:39,450 --> 00:16:47,710
+المجموعة ممكن اقول one prime two primeوبناء على
+
+203
+00:16:47,710 --> 00:16:52,670
+ذلك هذه المجموعة لو أنها لحالة بدأ أسميها two
+
+204
+00:16:52,670 --> 00:16:58,420
+-prime-chloroethoxy ممكن نحطها برايم يكون أفضللما
+
+205
+00:16:58,420 --> 00:17:03,360
+يكون عندكم اكثر من نظام ترقيم في المُركّب، ميزوهم،
+
+206
+00:17:03,360 --> 00:17:07,120
+حطوا شرطة على واحد منهم فانا عندي نظام ترقيم
+
+207
+00:17:07,120 --> 00:17:12,880
+للسلسلة الطويلة وعندي نظام ترقيم للسلسلة القصيرة
+
+208
+00:17:12,880 --> 00:17:16,340
+هذه واضح انها إيثوكسي، بس على بوقع two prime
+
+209
+00:17:16,340 --> 00:17:21,800
+ابتداء من ال Oxygen، شو إجا عندى؟eclor فصارت two
+
+210
+00:17:21,800 --> 00:17:27,200
+prime ecloroethoxy فالمُركّب كله بيصير three two
+
+211
+00:17:27,200 --> 00:17:33,680
+prime ecloroethoxy one butanol لأنه alcohol
+
+212
+00:17:33,680 --> 00:17:39,540
+والالكولز بنتهوا باسم all واضح؟ والالكولز باسم all
+
+213
+00:17:39,540 --> 00:17:45,720
+الآن هل يا ترى في واحدة إلها مزاج تسمي هذا
+
+214
+00:17:45,720 --> 00:17:51,750
+المُركّب اللي هنا اللي رسمناه عشان نوضحلكم؟مين
+
+215
+00:17:51,750 --> 00:17:55,270
+بدأت تفضل؟
+
+216
+00:17:55,270 --> 00:18:00,490
+اتفضلي وين
+
+217
+00:18:00,490 --> 00:18:07,090
+اطول السلسلة عندك؟ هنا؟
+
+218
+00:18:07,090 --> 00:18:14,290
+كويس، اقرب اش على ال O وين؟ one two three four
+
+219
+00:18:14,290 --> 00:18:22,800
+ممكن نتخيلها زي هيك او one twothree four الخلاصة
+
+220
+00:18:22,800 --> 00:18:27,840
+ان ال substitutions اللي هنا على موقع اتنين و على
+
+221
+00:18:27,840 --> 00:18:32,560
+موقع تلاتة على موقع اتنين شوفي عندك كلورو و على
+
+222
+00:18:32,560 --> 00:18:41,340
+موقع تلاتة مثوكسي و المركب كله بيوتين اذا شو هتسمي
+
+223
+00:18:41,340 --> 00:18:48,560
+هذا المركب two chloro three methoxy
+
+224
+00:18:54,370 --> 00:19:02,530
+تو كلورو ثريمي ثوكسي بيوتين واضح طبعا المركبات لا
+
+225
+00:19:02,530 --> 00:19:06,730
+تنتهي لكن اهم شي ان انتوا اخدتوا المبادئ العامة في
+
+226
+00:19:06,730 --> 00:19:10,670
+التسمية ان في عندك common nomenclature لما تكون
+
+227
+00:19:10,670 --> 00:19:16,530
+المجموعات بسيطة و ذات اسماء معروفة و عندك اي
+
+228
+00:19:16,530 --> 00:19:21,210
+backnomenclature اذا صارت المجموعات اشمالها معقدة
+
+229
+00:19:21,210 --> 00:19:30,680
+و بطلة بسيطةهذا بالنسبة لتسمية الـ
+
+230
+00:19:30,680 --> 00:19:31,160
+Ethers
+
+231
+00:19:38,730 --> 00:19:43,890
+معلومة ثقافية عن الـ Ethers الـ Ethers ومشتقاتها
+
+232
+00:19:43,890 --> 00:19:49,470
+هي من أوائل المركبات اللي استعملت كمواد مخدرة
+
+233
+00:19:49,470 --> 00:19:54,410
+وعشانك برضه لا ينصح مثلا أن طالب تكون تشتغل بـ
+
+234
+00:19:54,410 --> 00:19:59,010
+Ether و تقعد يتحرك مركب و الـ Ether بتبخر جامها من
+
+235
+00:19:59,010 --> 00:20:03,770
+بيكر لمدة نص ساعة ساعة و هي تشم Ether Ether Ether
+
+236
+00:20:03,770 --> 00:20:09,410
+ممكن انها إيشبشكل أو باخر الدروخ أو تتخدر، فالـ
+
+237
+00:20:09,410 --> 00:20:14,870
+ETHER is the first general anesthetic يعني استعمل
+
+238
+00:20:14,870 --> 00:20:21,920
+كمادة مخدرةالان جزء من اللي بيستعملوه حتى في
+
+239
+00:20:21,920 --> 00:20:26,880
+التطبيق مش ال die-ethyl ether نفسه لكن المشتقات
+
+240
+00:20:26,880 --> 00:20:31,440
+فيها halogens يعني قبلت بعض الظرار ب halogens و
+
+241
+00:20:31,440 --> 00:20:35,300
+ماخد هذه أسماء شهرة يعني هنا مثلا عندكوا floriclor
+
+242
+00:20:35,300 --> 00:20:38,980
+floriclor floriclor floriclor واضح؟ هذا اسمه
+
+243
+00:20:38,980 --> 00:20:44,010
+penthrin وهذا enthrinما بهمناش نحفظهم، لكن في
+
+244
+00:20:44,010 --> 00:20:49,190
+النهاية هي عبارة عن مواد تستعمل في التخدير وفي
+
+245
+00:20:49,190 --> 00:20:55,610
+الطب اللي بديه يتعامل مع ال ethers حكينا عن خطرين
+
+246
+00:20:55,610 --> 00:21:02,050
+لحتى الآن لهم وضايل الخطر التالت الخطر الأول انهم
+
+247
+00:21:02,050 --> 00:21:09,000
+they are flammableبشتعلوا بسرعة، بدهم حذر، الخطر
+
+248
+00:21:09,000 --> 00:21:14,400
+التاني أن جزء منهم have anesthetic properties، لهم
+
+249
+00:21:14,400 --> 00:21:18,400
+خواص مخدرة وبالتالي الإنسان مايحطش راسه جانب ال
+
+250
+00:21:18,400 --> 00:21:23,220
+ether وقاعد ..يشتغلوا اشي ممكن يشيم كمية كبيرة منه
+
+251
+00:21:23,220 --> 00:21:30,080
+الخطر التالت للethers انه الكثير من ال ethers اللي
+
+252
+00:21:30,080 --> 00:21:35,680
+بتكون متروكة لفترات قديمة يعني مخزن مثلا محطوط في
+
+253
+00:21:35,680 --> 00:21:39,440
+ال ether سنتين تلاتة اربع راح الواحد طلب منه بوت
+
+254
+00:21:39,440 --> 00:21:44,860
+ال ether جابله بوت ال ether ممكن يكون عامل مواد
+
+255
+00:21:44,860 --> 00:21:50,460
+متفجرةيجي البني آدم يشتغل في ال ether ما يسخنوا
+
+256
+00:21:50,460 --> 00:21:55,930
+شوية ولا يكبوا مع الحركة؟يعمل فيه ايش؟ انفجار
+
+257
+00:21:55,930 --> 00:22:00,510
+ولذلك الـ ethers القديمة خطيرة ممكن تكون عاملة
+
+258
+00:22:00,510 --> 00:22:05,530
+ايش؟ مواد متفجرة بتكون عاملة مواد متفجرة لأنها
+
+259
+00:22:05,530 --> 00:22:10,670
+بتعمل أشياء من الأكسوجين البسيط اللي في الجو وعلى
+
+260
+00:22:10,670 --> 00:22:15,010
+المدى الزمن البعيد بنسميها ايش؟ peroxides هذه
+
+261
+00:22:15,010 --> 00:22:20,300
+البروكسايتز هي المواد اللي بتسببالانفجارات في الـ
+
+262
+00:22:20,300 --> 00:22:24,480
+ethers والطلاب لازم يكونوا حاذرين منها يعني لو
+
+263
+00:22:24,480 --> 00:22:27,720
+اشتغلتوا في المستقبل في مختبر طب في مختبر
+
+264
+00:22:27,720 --> 00:22:32,540
+biochemistry whatever لما يجيكوا ال ether بدوا
+
+265
+00:22:32,540 --> 00:22:38,140
+يكونوا في بالكوا انه ممكن يكون فيه مشكلة الان ممكن
+
+266
+00:22:38,140 --> 00:22:42,220
+يكون فيه مشكلة ثقافية هذا الكلام مابنفعش كيف بدنا
+
+267
+00:22:42,220 --> 00:22:46,140
+نكون احنا متأكدين ان المشكلة موجودة ولا لأ وإذا
+
+268
+00:22:46,140 --> 00:22:53,650
+موجودةبدنا نعالجها اول اشي كيف بتكون البروكسايد
+
+269
+00:22:53,650 --> 00:22:58,130
+اللي هي المادة المتفجرة هذه لو مثلا هذا الداي
+
+270
+00:22:58,130 --> 00:23:02,310
+إيثال إيثار هو أكتر المواد استعمالا ك solvent ترك
+
+271
+00:23:02,310 --> 00:23:06,870
+لفترة طويلة مع الأكسجين بيروح بيضيف لهنا OOH هذا
+
+272
+00:23:06,870 --> 00:23:10,790
+بيروكسايد معنى بيروكسايد يعني في أكسجين زيادة يعني
+
+273
+00:23:10,790 --> 00:23:21,500
+مش OH OOH واضح؟ والتكرار؟دائما بعلم الشطار ويفيد
+
+274
+00:23:21,500 --> 00:23:27,880
+التأكيد اللي بده يأكد أي جملة إيش بيعمل بيكرر وهنا
+
+275
+00:23:27,880 --> 00:23:32,320
+بنكرر لل oxygen كتير في الحديث النبوية بيجي تكرار
+
+276
+00:23:32,320 --> 00:23:37,200
+ولا لأ مثلا في الحديث اللي بيقول فذلكم الرباط
+
+277
+00:23:37,200 --> 00:23:44,800
+فذلكم الرباط فذلكم الرباط مظبوط ولا لأ؟ألا أدلكم
+
+278
+00:23:44,800 --> 00:23:47,900
+على ما يرفعوا الله به الدرجات ويمحوا به الخطايا
+
+279
+00:23:47,900 --> 00:23:53,280
+قالوا بلى يا رسول الله قال إسباغه الوضوءي على
+
+280
+00:23:53,280 --> 00:23:58,280
+المكاري هو كثرة الخطاة إلى المساجد وانتظار الصلاة
+
+281
+00:23:58,280 --> 00:24:03,240
+إلى الصلاة فذلكم الرباط فذلكم الرباط فذلكم الرباط
+
+282
+00:24:03,240 --> 00:24:07,800
+هذا في الحديث النبوي التكرار مشهور كتير لما بده
+
+283
+00:24:07,800 --> 00:24:13,160
+قال أمك ثم أمك ثم أبيك
+
+284
+00:24:14,010 --> 00:24:18,070
+واضح؟ الله يعطيكم العافية من التعب اللي بتشوفوه و
+
+285
+00:24:18,070 --> 00:24:22,110
+الله لو غير كل الحمل و الولادة بس مشاكل المناهج
+
+286
+00:24:22,110 --> 00:24:26,490
+الجديدة على الإممايات الله يعطيهم العافية العملات
+
+287
+00:24:26,490 --> 00:24:28,710
+اللي هي هو وزارة التربية و التعليم و اللي بعلموا
+
+288
+00:24:28,710 --> 00:24:33,890
+صغار بيعرفوا كده الناس صاروا تعبانين بحياتهم من
+
+289
+00:24:33,890 --> 00:24:37,750
+ورا مناهج التربية و التعليم اللي عندها الأطفال
+
+290
+00:24:37,750 --> 00:24:43,110
+الصغار واضح؟
+
+291
+00:24:44,190 --> 00:24:50,490
+بهمش خليهم يسمعونا يعني احنا اليوم بنجيبلكم معادلة
+
+292
+00:24:50,490 --> 00:24:56,590
+اوزنونا إياها معادلة أكسدة واختزال من السبعين
+
+293
+00:24:56,590 --> 00:25:01,270
+طالبة يمكن خمست عشر بيجاوبون إياها صح وانا لو
+
+294
+00:25:01,270 --> 00:25:04,330
+سألكوا هذا الموضوع وزن المعادلات الأكسدة واختزال
+
+295
+00:25:04,330 --> 00:25:08,890
+الموضوع سهل ولا صعب جزء كبير منكم هيقول صعب الان
+
+296
+00:25:08,890 --> 00:25:15,770
+لما بيجوا بيحطوا هذه المعادلة للصف التاسعوبطلبوا
+
+297
+00:25:15,770 --> 00:25:19,310
+منهم إنهم يوزنوها وحتى الأمثلة اللي بيحطولهم إياها
+
+298
+00:25:19,310 --> 00:25:25,030
+في الكتاب مش سهلة وأكتر من مدرس ومدرسة شفتهم
+
+299
+00:25:25,030 --> 00:25:30,050
+عاملينها غلط أو مش عارفين يعملوها وعاندين وزارة
+
+300
+00:25:30,050 --> 00:25:34,030
+التربية والتعليم لدرجة أنا مرة بعتلهم رسالة إذا
+
+301
+00:25:34,030 --> 00:25:37,550
+الطالب بوزن معادلة أكسدة واختزالة في تالتة أعدادي
+
+302
+00:25:37,550 --> 00:25:42,130
+هياخد جائزة نوبل في الكيميا بأولى ثانويو مازال
+
+303
+00:25:42,130 --> 00:25:46,370
+الموضوع موجود غصب من عنهم الطلاب في الآخر صفي
+
+304
+00:25:46,370 --> 00:25:52,710
+عندنا 15% علمي ولا 20% و باقي الطلاب كله أدبي و
+
+305
+00:25:52,710 --> 00:25:57,090
+ماحدش راضي يدخل الكليات العلمية مظبوط ولا لا؟
+
+306
+00:25:57,090 --> 00:26:01,310
+لأنهم كرهوا الناس في العلم اللي جابنا على هالكلام
+
+307
+00:26:01,310 --> 00:26:09,290
+كلهالتأكيد والمناهج إذا هذا أكسيد ولا بيروكسيد؟ أه
+
+308
+00:26:09,290 --> 00:26:14,090
+في أكم أكسوجينة، في أكسجيل زيادة الآن هذا
+
+309
+00:26:14,090 --> 00:26:18,270
+البروكسيد إذا اتكون بكمية كبيرة يعني ال ether
+
+310
+00:26:18,270 --> 00:26:22,470
+انترك لفترة طويلة و أخد فترة و مفتوح البُتل شوية و
+
+311
+00:26:22,470 --> 00:26:27,710
+دخلوا أكسجيل بيصير عبارة عن مادة صلبة موجودة بيشوف
+
+312
+00:26:27,710 --> 00:26:33,950
+الإنسان بعينيهفإذا شفتوا في ايبوت الاثر مادة صلبة
+
+313
+00:26:33,950 --> 00:26:37,870
+ارموه ما تستعملهوش راجعوا لا الفن ولا لا الشركة
+
+314
+00:26:37,870 --> 00:26:42,950
+يتخلصوا منه منه بطريقتهم يعني مالوش علاج معنى ذلك
+
+315
+00:26:42,950 --> 00:26:48,910
+كمية كبيرة منه اتحولت إلى بيروكسايد ويمثل خطورة
+
+316
+00:26:48,910 --> 00:26:53,370
+كبيرة الان ممكن تكون كمية صغيرة اتحولت لبروكسايد
+
+317
+00:26:53,370 --> 00:26:59,860
+وذائبة في الاثر يعني انا اشوفهصافي لكن هو حقيقة في
+
+318
+00:26:59,860 --> 00:27:04,600
+كمية صغيرة دائبة فيه واضح؟ في هذه الحالة بعمله فحص
+
+319
+00:27:04,600 --> 00:27:08,720
+يعني اللي بده أعمله فحص هو اللي بيكون clear
+
+320
+00:27:08,720 --> 00:27:13,200
+solution أما اللي فيه المادة الصلبة خلاص مابلزمش
+
+321
+00:27:13,200 --> 00:27:18,840
+نعمله فحص بلزم نعمله فحص؟ لأ واضح؟ خلاص بنرجعه
+
+322
+00:27:18,840 --> 00:27:24,340
+الآن اللي فيه المادة ذائبة إيش بيعمله؟ بيضيفوا
+
+323
+00:27:24,340 --> 00:27:30,580
+عليه FESO4فرّك الصرفات
+
+324
+00:27:30,580 --> 00:27:36,500
+لأن هذا oxidizing agent بيعمل أكسد لـ Fe2 plus هنا
+
+325
+00:27:36,500 --> 00:27:42,800
+بتصير Fe3 plusمو هذا فيه أكسجين زيادة عامل مؤكسد
+
+326
+00:27:42,800 --> 00:27:44,980
+البروكسايتز مؤكسد عامل مؤكسد البروكسايتز مؤكسد
+
+327
+00:27:44,980 --> 00:27:49,500
+عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل
+
+328
+00:27:49,500 --> 00:27:53,580
+مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد
+
+329
+00:27:53,580 --> 00:27:58,000
+عامل مؤكسد
+
+330
+00:27:58,000 --> 00:28:02,680
+عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل
+
+331
+00:28:02,680 --> 00:28:03,660
+مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد
+
+332
+00:28:03,660 --> 00:28:09,840
+عامل مؤكسد عامل مؤكسدالـ FE3 Plus أخدته test له
+
+333
+00:28:09,840 --> 00:28:15,800
+كيف نفحصه؟ بنضيف عليه الـ SCN- بيعطينا اللون
+
+334
+00:28:15,800 --> 00:28:20,760
+الأحمر الدمو الـ red color واضح؟ إذا أنا بضيف
+
+335
+00:28:20,760 --> 00:28:25,820
+FESO4 على الـ ether اللي بيكون clear بحركه شوية و
+
+336
+00:28:25,820 --> 00:28:32,540
+بحط بعدين فوقه SCN- إذا أعطاني لون أحمرإذا في عنده
+
+337
+00:28:32,540 --> 00:28:37,660
+Fe3+, طب من أين جاء الـ Fe3+, من الـ Fe2+, ماهو
+
+338
+00:28:37,660 --> 00:28:42,920
+أكسر الـ Fe2% لـ Fe3%؟ البروكسايد، إذا أنا شوفت
+
+339
+00:28:42,920 --> 00:28:47,890
+اللون الأحمر، معناه ذلك في عنده البروكسايدواضح؟
+
+340
+00:28:47,890 --> 00:28:52,130
+واعتمادا على غمج اللون انا بقدر اقول ان البروكسايد
+
+341
+00:28:52,130 --> 00:28:57,510
+اللى عندى كتير ولا قليل الان طالما ال ether clear
+
+342
+00:28:57,510 --> 00:29:01,850
+solution مش مرسّب المادة كمادة صلبة ممكن ان اعمله
+
+343
+00:29:01,850 --> 00:29:07,510
+معالجة ايش المعالجة اللى بعملها؟ بصير اضيف عليه
+
+344
+00:29:07,510 --> 00:29:14,790
+كميات اكبر من ال FESO4فهو لما بيشتغل كعمل مؤكسد
+
+345
+00:29:14,790 --> 00:29:20,090
+بيشيل إيش؟ بيشيل هذا الـ Oxygen و بيرجع لإيثار
+
+346
+00:29:20,090 --> 00:29:26,370
+عادي، واضح؟ فب .. ب .. بعمله shaking إضافي بكمية
+
+347
+00:29:26,370 --> 00:29:32,310
+أكبر من الـ FeSO4 و برود بعمل فحص لحد ما في
+
+348
+00:29:32,310 --> 00:29:40,340
+النهاية أبطل أشوف اللون الأحمربكون اتخلصت من كل
+
+349
+00:29:40,340 --> 00:29:44,500
+البروكسايد .. بكون اتخلصت من كل البروكسايد طبعا
+
+350
+00:29:44,500 --> 00:29:49,780
+لما احنا نعمل shaking بيكون هذا محلول مائي وهذا
+
+351
+00:29:49,780 --> 00:29:53,980
+محلول إيثار يعني ما بيخلطوش مع بعض .. shaking
+
+352
+00:29:53,980 --> 00:30:00,140
+بهدوءمش بقوة كبيرة والمياه بنفصلها بما حاولت مرتين
+
+353
+00:30:00,140 --> 00:30:05,540
+تلاتة بنعود نفحص ال ether بنلاقي رجع ether عادي
+
+354
+00:30:05,540 --> 00:30:15,400
+وبذلك بنتخلص احنا من قصة اللي هي خطر البروكسايد او
+
+355
+00:30:15,400 --> 00:30:19,300
+خطر الانفجار اذا دائما وانتوا بتتعاملوا مع ال
+
+356
+00:30:19,300 --> 00:30:21,940
+aethers حطوا في بالكوا تلت مخاطر
+
+357
+00:30:25,130 --> 00:30:30,130
+anesthetic properties له الشغلة التانية can form
+
+358
+00:30:30,130 --> 00:30:35,470
+explosive peroxides
+
+359
+00:30:35,470 --> 00:30:40,490
+ممكن يعمل peroxides و ال peroxides هذي لا سمح الله
+
+360
+00:30:40,490 --> 00:30:49,030
+انفجر واضح؟بعد ما صار عندى Ether جاهز تماما ان انا
+
+361
+00:30:49,030 --> 00:30:54,890
+استعمله ك solvent من أشهر استعمالات ال ether ك
+
+362
+00:30:54,890 --> 00:31:00,010
+solvent بيستعملوه بتفاعل شهير اسمه Greenyard
+
+363
+00:31:00,010 --> 00:31:04,750
+reaction بنحضر من خلاله Greenyard reaction وهذا
+
+364
+00:31:04,750 --> 00:31:09,510
+Greenyard التفاعل اللى عمله أخد عليه جائزة نوبل في
+
+365
+00:31:09,510 --> 00:31:14,930
+الكيميا يمكن بالـ1911 تماما قبل مائة سنةعشان
+
+366
+00:31:14,930 --> 00:31:19,210
+تشوفوا كده العالم كان بيشتغلوا متطور في الكيميا
+
+367
+00:31:19,210 --> 00:31:25,570
+الان ايش هو تفاعل جرينيارد reaction هذا تفاعل
+
+368
+00:31:25,570 --> 00:31:31,070
+جرينيارد reaction لو انا اخدت ARX او حتى ARX
+
+369
+00:31:31,070 --> 00:31:38,570
+وفعلتها مع بودرة مغنيسيامواضح؟ الـ RX Alkyl Halide
+
+370
+00:31:38,570 --> 00:31:45,930
+أو ARX يعني هنا يجوز أن تكون RX أو ARX وفعالة مع
+
+371
+00:31:45,930 --> 00:31:51,650
+بودرة مغنيسيوم الشرط في وجود Dry Ether يعني Ether
+
+372
+00:31:51,650 --> 00:31:56,790
+مافيش في جلبه ميه، بنمرره على عوامل مجففةبيعطيني
+
+373
+00:31:56,790 --> 00:32:04,710
+هذا المركب RMGX هذا المركب RMGX هو اللي بنسميه
+
+374
+00:32:04,710 --> 00:32:10,850
+احنا Greenyard Reagent متفاعل Greenyard واضح؟ طيب
+
+375
+00:32:10,850 --> 00:32:17,240
+ايش فيته هذا متفاعل Greenyard؟متفاعلي Greenyard
+
+376
+00:32:17,240 --> 00:32:24,080
+يمثل بالنسبة لنا مصدر لمجموعة R مع أزواج
+
+377
+00:32:24,080 --> 00:32:28,100
+الإلكترونات تبعها يعني بتصير الـR مع أزواج
+
+378
+00:32:28,100 --> 00:32:32,160
+الإلكترونات من وين بقدر أحصل عليها؟ من
+
+379
+00:32:32,160 --> 00:32:35,540
+الـGreenyard، لاحظوا، هذه فائدة الـGreenyard أنه
+
+380
+00:32:35,540 --> 00:32:41,260
+أنا لما بدي R مع أزواج الإلكترونات تبعتها، بحصل
+
+381
+00:32:41,260 --> 00:32:47,900
+عليها منلـ Grignard Reagent طبعاً لو انتوا بتكونوا
+
+382
+00:32:47,900 --> 00:32:56,520
+تيجوا تتطلعوا أنا بدأت بإيش؟ ب R X لو بدأتي أتطلع
+
+383
+00:32:56,520 --> 00:32:59,800
+على ال R X مين اللي كانت more electronegative
+
+384
+00:32:59,800 --> 00:33:04,040
+وتاخد أزواج الإلكترونات؟ ال X بمعنى لو أنا بدي
+
+385
+00:33:04,040 --> 00:33:08,580
+أفعل بس ال R X هتيجي ال X تاخد أزواج الإلكترونات
+
+386
+00:33:08,580 --> 00:33:11,540
+ويتكون عندي R Plus وهذا شفتوا بتفعل ال
+
+387
+00:33:11,540 --> 00:33:16,480
+substitutionاللي هو الـ Carbocation بينما أنا هنا
+
+388
+00:33:16,480 --> 00:33:22,140
+بحاجة إلى الـ R مع الإلكترونات أشبه ما تكون بـ
+
+389
+00:33:22,140 --> 00:33:26,840
+Carbanion هي ما بتكونش منفصلة لكن في لحظة التفعل
+
+390
+00:33:26,840 --> 00:33:32,360
+بتعطيني R مع أزواج الإلكترونات فكأنه هنا خلّيني
+
+391
+00:33:32,360 --> 00:33:41,620
+أقول يعني similar يعني شبيهة to إيش؟Carb and Ion
+
+392
+00:33:41,620 --> 00:33:46,200
+يعني كأنه كربون وعليه شحنة سالبة هو مابيكونش
+
+393
+00:33:46,200 --> 00:33:50,560
+المركب ايوني بيكون molecular وبيعطيه ال R و هذه
+
+394
+00:33:50,560 --> 00:33:54,920
+الى تطبيقات كتيرة هناخد كذا تطبيقه هناخد تفاعله مع
+
+395
+00:33:54,920 --> 00:33:59,920
+ال ال دي هايتز مع ال E Stars مع أشياء تانية لكن
+
+396
+00:33:59,920 --> 00:34:06,440
+لحظة خلينا بس نتعرفعليه هذه كمتفاعل طيب إيش دخل ال
+
+397
+00:34:06,440 --> 00:34:10,740
+ether في الموضوع ال ether هو ال solvent اللي بتنفي
+
+398
+00:34:10,740 --> 00:34:14,660
+التفاعل فبيكون عامة نوع من ال stabilization لهذه
+
+399
+00:34:14,660 --> 00:34:18,700
+بمعنى بيكون محوطة من فوق و من تحت بس يعني هو ال
+
+400
+00:34:18,700 --> 00:34:24,990
+solvent يساعد على تكوينهالكن أنا الـ reagent اللي
+
+401
+00:34:24,990 --> 00:34:31,850
+عنده هو الـ RMGX من الـ RMGX اللي مهتم أنا فيه
+
+402
+00:34:31,850 --> 00:34:36,930
+كيميائيا الـ R مع إلكتروناتها فكأنه في النهاية لو
+
+403
+00:34:36,930 --> 00:34:40,590
+بدأتش أسألكوا سؤال بسيط لو قلتلكوا Greenyard
+
+404
+00:34:40,590 --> 00:34:45,870
+reagent بالمجمل يمثللي Electrophile ولا
+
+405
+00:34:45,870 --> 00:34:49,350
+Nucleophile؟ Nucleophile
+
+406
+00:34:51,050 --> 00:34:56,190
+واضح؟ يعني كأنه صار عنده carbon nucleophile هذه
+
+407
+00:34:56,190 --> 00:35:00,190
+فائدة الـ Green Yardary Agent وهذه فائدة كبيرة
+
+408
+00:35:00,190 --> 00:35:05,250
+جداً طبعاً لأنه يمثل الـ nucleophile لأنه يمثل الـ
+
+409
+00:35:05,250 --> 00:35:11,030
+nucleophile وفي إلكترونات وين ما بيلاقي إشي موجب
+
+410
+00:35:11,030 --> 00:35:18,710
+بده يتفاعل معه مش هو سالب إذا السالب وين ما بيلاقي
+
+411
+00:35:18,710 --> 00:35:24,410
+موجببدي اتفاعل معاه يعني لو مثلا حطيت ميه او
+
+412
+00:35:24,410 --> 00:35:29,770
+اثانول او حامض او امين كل هدولة فيهم ايش القاسم
+
+413
+00:35:29,770 --> 00:35:36,070
+المشترك بينهم ال H plus بروح بياخد مباشرة منهم H
+
+414
+00:35:36,070 --> 00:35:43,730
+plus وبيعطيني RH لأن هو سالب وبيبحث عن الموجب طبعا
+
+415
+00:35:43,730 --> 00:35:49,450
+هل يا ترى هذا يعتبر تفاعل؟ هو تفاعل لكنه تفاعل غير
+
+416
+00:35:49,450 --> 00:35:57,380
+مرغوبلأن ال R هذه لازماني لأمور أخرى .. الآن تيجي
+
+417
+00:35:57,380 --> 00:36:00,840
+طالبة تشتغل ب flask يكون فيه شوية ميه و غيره و
+
+418
+00:36:00,840 --> 00:36:04,960
+غيراته و حضرت ال R MGX و لازماني لأمور أخرى .. و
+
+419
+00:36:04,960 --> 00:36:09,460
+ال flask تبعها في ميه .. بتروح ال R .. بتاخد H و
+
+420
+00:36:09,460 --> 00:36:14,710
+صارت RH .. هو أنا ناجسني RH .. أنا ناجسني ال Kأنا
+
+421
+00:36:14,710 --> 00:36:19,170
+بحضر ال green yard عشان في الآخر بده احضر منه ال
+
+422
+00:36:19,170 --> 00:36:23,210
+cane ولا لازمنا لتفاعلات تانية لازمنا لتفاعلات
+
+423
+00:36:23,210 --> 00:36:27,870
+تانية ولذلك الشرق هنا ايش يكون هذا ال dry ether
+
+424
+00:36:27,870 --> 00:36:33,670
+مافيش فيه اي مصدر لل H plus فكأننا بنقول انه الميه
+
+425
+00:36:33,670 --> 00:36:39,500
+بتخربمتفاعل الـ Green Yard الميّه والإيثانول و
+
+426
+00:36:39,500 --> 00:36:43,300
+الحامض كل شيء فيه H Plus حتى لو أخذنا الماء الثقيل
+
+427
+00:36:43,300 --> 00:36:52,460
+الـ D2O معه، سيعطينا RD إذا أنا مهتم أحضر RD على
+
+428
+00:36:52,460 --> 00:36:56,460
+العين والرأس، بيكون تفاعل إذا مش مهتم، معناه ذلك
+
+429
+00:36:56,460 --> 00:37:03,830
+يعمل بس بتخرّب إذا أنا مهتم أحضر RHع العين والرأس،
+
+430
+00:37:03,830 --> 00:37:07,290
+لكن إذا أنا مش مهتم إن أحضر RH، معنا ذلك الميه
+
+431
+00:37:07,290 --> 00:37:11,950
+هنا، بس بتخرّب علينا، واضح؟ بس بتخرّب علينا
+
+432
+00:37:16,320 --> 00:37:21,100
+ناخد مثال لو مثلًا قلنا لكم كيف تحضروا هذا
+
+433
+00:37:21,100 --> 00:37:25,080
+المُركّب اللي هو الـ isopropyl group اللي متصل
+
+434
+00:37:25,080 --> 00:37:30,240
+بالديوتيريام الديوتيريام نظيف الهيدروجين هتيجي
+
+435
+00:37:30,240 --> 00:37:37,120
+تفكروا أن هذا من وين بده يكون إجا الديوتيريام بده
+
+436
+00:37:37,120 --> 00:37:41,440
+يجي من a greenier reaction يعني كأنه الخطوة
+
+437
+00:37:41,440 --> 00:37:47,050
+السابقة بده يكون عندنا هذا المتفاعل مع Mgنفترض بي
+
+438
+00:37:47,050 --> 00:37:54,790
+اه الفعله مع D to O شو بيعطينا بدل ال MgBr؟ الـ
+
+439
+00:37:54,790 --> 00:38:00,950
+Deuterium لو فعله مع H to O شو بيعطينا بدالها؟ H
+
+440
+00:38:00,950 --> 00:38:06,270
+رأته اللي طلعت عنده ال MgX فعلته مع مية بيعطينا
+
+441
+00:38:06,270 --> 00:38:11,160
+بدالة H فعلته مع D to O بيعطينا بدالها؟دى بناء على
+
+442
+00:38:11,160 --> 00:38:15,280
+ذلك لو أنا كان عندى مركب لبروم وعملت منه green
+
+443
+00:38:15,280 --> 00:38:20,780
+yard نمرة واحد ونمرة اتنين صفر D to O بحول محكر
+
+444
+00:38:20,780 --> 00:38:27,400
+لبروم الى D بس كأنه انا ماشي بخطوطين هى نمرة واحد
+
+445
+00:38:27,400 --> 00:38:33,680
+و هى نمرة اتنين نمرة واحد تتحول لبروم و compound
+
+446
+00:38:33,680 --> 00:38:38,000
+لبروم و compound الى green yard نمرة اتنين ل green
+
+447
+00:38:38,000 --> 00:38:44,840
+yardإن فعلوا مع ال D2O بيجي مكانه ديوتيريام إذا لو
+
+448
+00:38:44,840 --> 00:38:49,360
+أنا قلتلكم من ال isopropyl bromide بدي مركب
+
+449
+00:38:49,360 --> 00:38:54,400
+لديوتيريام، بدنا نمشي كام خطوة؟ واحدة، تنتين طيب،
+
+450
+00:38:54,400 --> 00:38:57,340
+لو ماعطيتكوش ال isopropyl bromide، لو رجعت فيكوا
+
+451
+00:38:57,340 --> 00:39:00,740
+خطوة لوراه، أراجع ال synthesis اللي اتعلمتوا،
+
+452
+00:39:00,740 --> 00:39:07,660
+قلتلكوا بدي من ال .. البروبيل، بنضيف HPR في وجود
+
+453
+00:39:08,980 --> 00:39:13,800
+الـ H plus بيحط H و بيقعد صار عندي هذا و بنكمل إذا
+
+454
+00:39:13,800 --> 00:39:18,020
+نزلنا بس إيش خطوة لو كان عندي هنا ال alcohol هذه
+
+455
+00:39:18,020 --> 00:39:20,740
+مش alcohol
+
+456
+00:39:22,380 --> 00:39:26,960
+Isopropyl Alcohol وقلتلكم من الـ Isopropyl Alcohol
+
+457
+00:39:26,960 --> 00:39:31,620
+سؤال في الامتحان How can you prepare this compound
+
+458
+00:39:31,620 --> 00:39:34,860
+starting from isopropyl alcohol انتوا حتيجوا
+
+459
+00:39:34,860 --> 00:39:37,180
+ترجعوا برجعوا لورا بتعملوا إشي بنسميه
+
+460
+00:39:37,180 --> 00:39:42,840
+Retrosynthesis بتقولوا هذه ال D كانت MgBr ال MgBr
+
+461
+00:39:42,840 --> 00:39:47,520
+كانت PR أنا ماعنديش PR أنا عندي OH هل اتعلمنا
+
+462
+00:39:47,520 --> 00:39:56,330
+طريقة انحول فيها ال OH إلى PRأكيد كنا نفعل مع ال
+
+463
+00:39:56,330 --> 00:40:01,990
+PPR3 أو ال HPR في تفاعلات ال alcohols لما أخدنا
+
+464
+00:40:01,990 --> 00:40:10,350
+reaction of alcohols with HPR او PPR3 هنا ال HPR
+
+465
+00:40:10,350 --> 00:40:17,610
+بيمشي و ال PPR3 بيمشي واضح؟ لو كنا بنتحولها لCL
+
+466
+00:40:17,610 --> 00:40:27,410
+بنفعل HCLالالكول بيتحول بسهولة باستعمال ال HCl ولا
+
+467
+00:40:27,410 --> 00:40:34,290
+لازم أستعمل reagent تاني؟ يا بتستعمل BCl3 يا
+
+468
+00:40:34,290 --> 00:40:41,750
+ثيونيلاكلورايد تذكروا آخر محاضرة قلنا ال alcohols
+
+469
+00:40:41,750 --> 00:40:47,690
+لما بتحولوا لalkyl halides كنا بنستعمل BX3 أو
+
+470
+00:40:47,690 --> 00:40:49,710
+ثيونيلاكلورايد
+
+471
+00:40:56,340 --> 00:41:00,700
+تاكرتكم؟ على أي حال بنقف عند هذا الموضوع وان شاء
+
+472
+00:41:00,700 --> 00:41:04,720
+الله المحاضرة الجاية بنحكي فيه ال preparation of
+
+473
+00:41:04,720 --> 00:41:07,380
+ethers and their reactions
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/0sNdGGE2F3c_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/0sNdGGE2F3c_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..6c17f75b7e100ceae44002790713f452e8c67260
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/0sNdGGE2F3c_raw.json
@@ -0,0 +1 @@
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144.05, "word": " carbon", "probability": 0.60107421875}, {"start": 144.05, "end": 144.79, "word": " عليها", "probability": 0.88671875}, {"start": 144.79, "end": 145.23, "word": " أربع", "probability": 0.9256184895833334}, {"start": 145.23, "end": 145.93, "word": " مجموعات", "probability": 0.9578125}, {"start": 145.93, "end": 146.77, "word": " مختلفة", "probability": 0.993408203125}], "temperature": 1.0}, {"id": 6, "seek": 17328, "start": 147.28, "end": 173.28, "text": "لما بدى اعمل تفاعل ال carbon هدى بدى يصير عليها اربع مجموعات مختلفة فبدى يصير في عندى chiral center واضح؟ ممكن ناخد مثال على هذا الكلام لو أخدته تفاعل أخدناه في ال alkanes لبيوتين العادى لما نعمله chlorination كنا نقول نعمل chlorination احنا على موقع واحد وعلى موقع اتنين", "tokens": [1211, 15042, 47525, 7578, 1975, 25957, 1211, 6055, 5172, 995, 30241, 2423, 5954, 8032, 3215, 7578, 47525, 7578, 7251, 9381, 13546, 25894, 11296, 1975, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660, 6156, 44510, 7578, 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2316, 41850, 30767, 1829, 19446, 31439, 3714, 2288, 3794, 20498, 43242, 24793, 15844, 13672, 2407, 5016, 39627, 15730, 25124, 28820, 46811, 10943, 995, 23032, 1211, 3615, 14407, 47356, 8032, 47302, 2423, 12697], "avg_logprob": -0.21523437152306238, "compression_ratio": 1.5060240963855422, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 270.81, "end": 271.47, "word": "هذا", "probability": 0.936767578125}, {"start": 271.47, "end": 271.83, "word": " ال", "probability": 0.9345703125}, {"start": 271.83, "end": 272.33, "word": " radical", "probability": 0.68017578125}, {"start": 272.33, "end": 273.27, "word": " ميزته", "probability": 0.894775390625}, {"start": 273.27, "end": 273.97, "word": " ان", "probability": 0.61572265625}, {"start": 273.97, "end": 274.33, "word": " هو", "probability": 0.70068359375}, {"start": 274.33, "end": 275.17, "word": " planar", "probability": 0.62744140625}, {"start": 275.17, "end": 276.61, "word": " كيف", "probability": 0.614990234375}, {"start": 276.61, "end": 276.81, "word": " يعني", "probability": 0.922119140625}, {"start": 276.81, "end": 277.61, "word": " planar؟", "probability": 0.7835286458333334}, {"start": 277.61, "end": 278.23, "word": " بهذا", "probability": 0.839599609375}, {"start": 278.23, "end": 278.63, "word": " الشكل", "probability": 0.9892578125}, {"start": 278.63, "end": 278.79, "word": " لو", "probability": 0.49951171875}, {"start": 278.79, "end": 279.41, "word": " بتعمله", "probability": 0.8385416666666666}, {"start": 279.41, "end": 279.77, "word": " model", "probability": 0.8134765625}, {"start": 279.77, "end": 280.13, "word": " أنا", "probability": 0.5498046875}, {"start": 280.13, "end": 280.51, "word": " زي", "probability": 0.957763671875}, {"start": 280.51, "end": 280.61, "word": " ما", "probability": 0.95361328125}, {"start": 280.61, "end": 280.81, "word": " هو", "probability": 0.88134765625}, {"start": 280.81, "end": 281.33, "word": " مرسوم", "probability": 0.9757080078125}, {"start": 281.33, "end": 281.73, "word": " عندكم", "probability": 0.947265625}, {"start": 281.73, "end": 281.95, "word": " على", "probability": 0.87451171875}, {"start": 281.95, "end": 282.45, "word": " اللوح", "probability": 0.97705078125}, {"start": 282.45, "end": 283.17, "word": " بهذا", "probability": 0.908203125}, {"start": 283.17, "end": 283.59, "word": " الشكل", "probability": 0.98486328125}, {"start": 283.59, "end": 284.33, "word": " تماما", "probability": 0.9817708333333334}, {"start": 284.33, "end": 285.01, "word": " طلعوا", "probability": 0.8057861328125}, {"start": 285.01, "end": 285.35, "word": " عليه", "probability": 0.97900390625}, {"start": 285.35, "end": 286.89, "word": " هاي", "probability": 0.6007080078125}, {"start": 286.89, "end": 287.35, "word": " ال", "probability": 0.97509765625}, {"start": 287.35, "end": 287.93, "word": " hydrogen", "probability": 0.6875}], "temperature": 1.0}, {"id": 12, "seek": 31385, "start": 289.91, "end": 313.85, "text": "مثل CH3 كربونا هاي إثل CH2 CH3 و هذا إيش ماله ال planner لسه في نص الطريق ال planner free radical الآن هذه الكلور واقفة هنا و بدأ تيجي تتفاعل في عدة احتمالين إما أن تأتي من الأمام و هدولة بيرتدوا للخلف أو تأتي من الجهة التانية", "tokens": [2304, 12984, 1211, 5995, 18, 9122, 25513, 2407, 8315, 8032, 47302, 11933, 12984, 1211, 5995, 17, 5995, 18, 4032, 23758, 11933, 1829, 8592, 3714, 6027, 3224, 2423, 31268, 5296, 3794, 3224, 8978, 8717, 9381, 41950, 16572, 4587, 2423, 31268, 1737, 12001, 6024, 48506, 29538, 33251, 1211, 13063, 36764, 4587, 5172, 3660, 34105, 4032, 47525, 10721, 6055, 1829, 7435, 1829, 6055, 2655, 5172, 995, 30241, 8978, 6225, 41891, 1975, 33753, 2304, 6027, 9957, 11933, 15042, 14739, 6055, 10721, 31371, 9154, 16247, 2304, 10943, 4032, 8032, 3215, 12610, 3660, 4724, 13546, 2655, 3215, 14407, 24976, 9778, 46538, 34051, 6055, 10721, 31371, 9154, 25724, 3224, 3660, 16712, 7649, 10632], "avg_logprob": -0.24737150201173586, "compression_ratio": 1.6244541484716157, "no_speech_prob": 5.960464477539063e-08, "words": 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"end": 297.03, "word": " planner", "probability": 0.2421875}, {"start": 297.03, "end": 297.79, "word": " لسه", "probability": 0.9153645833333334}, {"start": 297.79, "end": 297.91, "word": " في", "probability": 0.82958984375}, {"start": 297.91, "end": 298.11, "word": " نص", "probability": 0.880615234375}, {"start": 298.11, "end": 298.57, "word": " الطريق", "probability": 0.9923502604166666}, {"start": 298.57, "end": 298.73, "word": " ال", "probability": 0.8525390625}, {"start": 298.73, "end": 299.01, "word": " planner", "probability": 0.97607421875}, {"start": 299.01, "end": 299.41, "word": " free", "probability": 0.7275390625}, {"start": 299.41, "end": 300.05, "word": " radical", "probability": 0.96337890625}, {"start": 300.05, "end": 301.21, "word": " الآن", "probability": 0.57550048828125}, {"start": 301.21, "end": 301.69, "word": " هذه", "probability": 0.72314453125}, {"start": 301.69, "end": 302.13, "word": " الكلور", "probability": 0.7057291666666666}, {"start": 302.13, "end": 302.57, "word": " واقفة", "probability": 0.8902587890625}, {"start": 302.57, "end": 302.71, "word": " هنا", "probability": 0.8857421875}, {"start": 302.71, "end": 302.81, "word": " و", "probability": 0.91650390625}, {"start": 302.81, "end": 303.07, "word": " بدأ", "probability": 0.5001220703125}, {"start": 303.07, "end": 303.31, "word": " تيجي", "probability": 0.896484375}, {"start": 303.31, "end": 304.21, "word": " تتفاعل", "probability": 0.96689453125}, {"start": 304.21, "end": 305.57, "word": " في", "probability": 0.74658203125}, {"start": 305.57, "end": 305.81, "word": " عدة", "probability": 0.818115234375}, {"start": 305.81, "end": 306.53, "word": " احتمالين", "probability": 0.85751953125}, {"start": 306.53, "end": 307.61, "word": " إما", "probability": 0.6153564453125}, {"start": 307.61, "end": 308.31, "word": " أن", "probability": 0.59228515625}, {"start": 308.31, "end": 308.61, "word": " تأتي", "probability": 0.9391276041666666}, {"start": 308.61, "end": 308.81, "word": " من", "probability": 0.99609375}, {"start": 308.81, "end": 309.49, "word": " الأمام", "probability": 0.9586588541666666}, {"start": 309.49, "end": 310.45, "word": " و", "probability": 0.54931640625}, {"start": 310.45, "end": 310.79, "word": " هدولة", "probability": 0.8218994140625}, {"start": 310.79, "end": 311.23, "word": " بيرتدوا", "probability": 0.8708984375}, {"start": 311.23, "end": 311.71, "word": " للخلف", "probability": 0.8902994791666666}, {"start": 311.71, "end": 312.29, "word": " أو", "probability": 0.88623046875}, {"start": 312.29, "end": 312.69, "word": " تأتي", "probability": 0.9781901041666666}, {"start": 312.69, "end": 312.87, "word": " من", "probability": 0.9970703125}, {"start": 312.87, "end": 313.29, "word": " الجهة", "probability": 0.9889322916666666}, {"start": 313.29, "end": 313.85, "word": " التانية", "probability": 0.9869791666666666}], "temperature": 1.0}, {"id": 13, "seek": 33849, "start": 314.77, "end": 338.49, "text": "إذاً لأن هذا planner لأن هذا في مستوى واحد الكلور بيصير لإحتمالين عندها متساويات يا بتيجي من هنا يا من هنا أو لو مسكته زي هيك هاي الكلور إما بهذا الشكل أو بهذا الشكل واضح هذا الكلام طالما الكلور بيمكنها تيجي من الأمام و الخلف أو من الجنبين بيقدر إلى تكوين", "tokens": [28814, 15730, 14111, 5296, 33456, 23758, 31268, 5296, 33456, 23758, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 33251, 1211, 13063, 4724, 1829, 9381, 13546, 5296, 28814, 33753, 2304, 6027, 9957, 43242, 11296, 44650, 3794, 995, 45865, 9307, 35186, 39894, 1829, 7435, 1829, 9154, 34105, 35186, 9154, 34105, 34051, 45164, 47524, 4117, 47395, 30767, 1829, 39896, 4117, 8032, 47302, 33251, 1211, 13063, 11933, 15042, 39627, 15730, 25124, 28820, 34051, 39627, 15730, 25124, 28820, 4032, 46958, 5016, 23758, 2423, 28820, 10943, 23032, 6027, 15042, 33251, 1211, 13063, 4724, 32640, 19452, 11296, 6055, 1829, 7435, 1829, 9154, 16247, 2304, 10943, 4032, 33962, 46538, 34051, 9154, 25724, 1863, 3555, 9957, 4724, 1829, 28543, 2288, 30731, 6055, 4117, 2407, 9957], "avg_logprob": -0.2342403057063448, "compression_ratio": 1.9955947136563876, "no_speech_prob": 1.5497207641601562e-06, "words": [{"start": 314.77, "end": 315.43, "word": "إذاً", "probability": 0.4823404947916667}, {"start": 315.43, "end": 315.81, "word": " لأن", "probability": 0.81201171875}, {"start": 315.81, "end": 316.19, "word": " هذا", "probability": 0.89990234375}, {"start": 316.19, "end": 316.63, "word": " planner", "probability": 0.226806640625}, {"start": 316.63, "end": 317.05, "word": " لأن", "probability": 0.656494140625}, {"start": 317.05, "end": 317.29, "word": " هذا", "probability": 0.88037109375}, {"start": 317.29, "end": 317.43, "word": " في", "probability": 0.9345703125}, {"start": 317.43, "end": 318.07, "word": " مستوى", "probability": 0.97216796875}, {"start": 318.07, "end": 318.89, "word": " واحد", "probability": 0.991455078125}, {"start": 318.89, "end": 320.07, "word": " الكلور", "probability": 0.6684977213541666}, {"start": 320.07, "end": 320.69, "word": " بيصير", "probability": 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324.69, "word": " مسكته", "probability": 0.5741373697916666}, {"start": 324.69, "end": 324.95, "word": " زي", "probability": 0.94873046875}, {"start": 324.95, "end": 325.29, "word": " هيك", "probability": 0.94775390625}, {"start": 325.29, "end": 325.67, "word": " هاي", "probability": 0.46435546875}, {"start": 325.67, "end": 326.13, "word": " الكلور", "probability": 0.876953125}, {"start": 326.13, "end": 326.47, "word": " إما", "probability": 0.75146484375}, {"start": 326.47, "end": 328.15, "word": " بهذا", "probability": 0.908935546875}, {"start": 328.15, "end": 328.69, "word": " الشكل", "probability": 0.99072265625}, {"start": 328.69, "end": 329.71, "word": " أو", "probability": 0.91845703125}, {"start": 329.71, "end": 330.17, "word": " بهذا", "probability": 0.964599609375}, {"start": 330.17, "end": 330.63, "word": " الشكل", "probability": 0.981201171875}, {"start": 330.63, "end": 331.27, "word": " واضح", "probability": 0.8898111979166666}, {"start": 331.27, "end": 331.87, "word": " هذا", "probability": 0.435546875}, {"start": 331.87, "end": 332.57, "word": " الكلام", "probability": 0.9757486979166666}, {"start": 332.57, "end": 333.17, "word": " طالما", "probability": 0.96337890625}, {"start": 333.17, "end": 333.61, "word": " الكلور", "probability": 0.88134765625}, {"start": 333.61, "end": 334.07, "word": " بيمكنها", "probability": 0.77197265625}, {"start": 334.07, "end": 334.29, "word": " تيجي", "probability": 0.9910888671875}, {"start": 334.29, "end": 334.45, "word": " من", "probability": 0.9951171875}, {"start": 334.45, "end": 334.93, "word": " الأمام", "probability": 0.9230143229166666}, {"start": 334.93, "end": 335.07, "word": " و", "probability": 0.65673828125}, {"start": 335.07, "end": 335.47, "word": " الخلف", "probability": 0.878662109375}, {"start": 335.47, "end": 335.67, "word": " أو", "probability": 0.81640625}, {"start": 335.67, "end": 335.83, "word": " من", "probability": 0.91259765625}, {"start": 335.83, "end": 336.53, "word": " الجنبين", "probability": 0.8577880859375}, {"start": 336.53, "end": 337.47, "word": " بيقدر", "probability": 0.63037109375}, {"start": 337.47, "end": 337.69, "word": " إلى", "probability": 0.7880859375}, {"start": 337.69, "end": 338.49, "word": " تكوين", "probability": 0.78948974609375}], "temperature": 1.0}, {"id": 14, "seek": 36411, "start": 341.03, "end": 364.11, "text": "to enantiomers لما بتقول واحد الكلور في بهذا الشكل و التاني بهذا الشكل اتخيلهم كأنهم صورة مرآة لبعض و من البعض ايش بتلاحظوا انه عندى اتكون to enantiomers مش واحد الآن السؤال بأي نسبة لما تكون هذه الكلور بعيدة و هذا بلا نار", "tokens": [1353, 465, 11520, 298, 433, 5296, 15042, 39894, 39648, 36764, 24401, 33251, 1211, 13063, 8978, 39627, 15730, 25124, 28820, 4032, 16712, 7649, 1829, 39627, 15730, 25124, 28820, 1975, 2655, 9778, 26895, 16095, 9122, 33456, 16095, 20328, 13063, 3660, 3714, 2288, 148, 95, 3660, 5296, 3555, 3615, 11242, 4032, 9154, 29739, 3615, 11242, 1975, 1829, 8592, 39894, 15040, 5016, 19913, 14407, 16472, 3224, 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ال S و ال R بطلع منه ال S و ال R isomers لاحظوا معنى عمل الإلم بتوسع احنا زمان كنا نقولكم ببساطة ان ال addition of HBR to one butane produces two bromobutane مظبوط ولا لأ؟ الآن بنكتشف انه لأ هو بطلعش بركب واحد هو بطلع ال R", "tokens": [6027, 20292, 31439, 2423, 318, 4032, 2423, 497, 4724, 9566, 1211, 3615, 9154, 3224, 2423, 318, 4032, 2423, 497, 307, 298, 433, 20193, 5016, 19913, 14407, 20449, 1863, 7578, 6225, 42213, 33688, 19528, 39894, 41779, 3615, 1975, 5016, 8315, 30767, 2304, 7649, 9122, 8315, 8717, 39648, 24793, 4724, 3555, 3794, 41193, 3660, 16472, 2423, 4500, 295, 389, 11609, 281, 472, 457, 1929, 14725, 732, 50134, 996, 325, 1929, 3714, 19913, 3555, 2407, 9566, 49429, 5296, 10721, 22807, 6024, 48506, 44945, 4117, 2655, 8592, 5172, 16472, 3224, 5296, 10721, 31439, 4724, 9566, 1211, 3615, 8592, 4724, 31747, 3555, 36764, 24401, 31439, 4724, 9566, 1211, 3615, 2423, 497], "avg_logprob": -0.21743574571386676, "compression_ratio": 1.550660792951542, "no_speech_prob": 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681.5, "word": " المية", "probability": 0.97802734375}], "temperature": 1.0}, {"id": 28, "seek": 70993, "start": 682.71, "end": 709.93, "text": "بناء على ذلك لو جينا ندرس ال optical activity لو جيبت كل ال reactant اللي هنا قبل التفاعل و حطيته في ال polarimeter بيكون active ولا inactive؟ inactive لو جيبت خليق النواتج و حطيته في ال polarimeter؟ inactive لأنه بنسبة 50% ل 50% صفر ال rotation تبعه وهذا نفس الاشياء", "tokens": [3555, 1863, 16606, 15844, 29910, 23275, 45164, 10874, 1829, 8315, 8717, 3215, 2288, 3794, 2423, 20674, 5191, 45164, 10874, 1829, 3555, 2655, 28242, 2423, 4515, 394, 13672, 1829, 34105, 12174, 36150, 16712, 5172, 995, 30241, 4032, 11331, 9566, 36081, 3224, 8978, 2423, 12367, 9685, 4724, 1829, 30544, 4967, 49429, 294, 12596, 22807, 294, 12596, 45164, 10874, 1829, 3555, 2655, 16490, 20292, 4587, 28239, 2407, 9307, 7435, 4032, 11331, 9566, 36081, 3224, 8978, 2423, 12367, 9685, 22807, 294, 12596, 5296, 33456, 3224, 44945, 35457, 3660, 2625, 4, 5296, 2625, 4, 20328, 5172, 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{"start": 707.49, "end": 707.61, "word": " ال", "probability": 0.91162109375}, {"start": 707.61, "end": 707.95, "word": " rotation", "probability": 0.9296875}, {"start": 707.95, "end": 708.61, "word": " تبعه", "probability": 0.929931640625}, {"start": 708.61, "end": 709.23, "word": " وهذا", "probability": 0.68408203125}, {"start": 709.23, "end": 709.53, "word": " نفس", "probability": 0.98974609375}, {"start": 709.53, "end": 709.93, "word": " الاشياء", "probability": 0.79144287109375}], "temperature": 1.0}, {"id": 29, "seek": 73980, "start": 711.08, "end": 739.8, "text": "فيش chiral center inactive هنا رسمك mixture و الرسمك mixture inactive صار في عندنا قاعدة في ال stereo chemistry بتقول القاتي بتقول optically inactive reactants produces optically inactive products اللي بنقصده هنا ان كل الناتج على بعضه لو بعدك بطريقة ما فصلت هذا لحاله و بعد لحاله هذا بيكون active و هذا active", "tokens": [41185, 8592, 23782, 304, 3056, 294, 12596, 34105, 12602, 38251, 4117, 9925, 4032, 34892, 38251, 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"word": " ما", "probability": 0.89990234375}, {"start": 736.36, "end": 736.84, "word": " فصلت", "probability": 0.9402669270833334}, {"start": 736.84, "end": 737.06, "word": " هذا", "probability": 0.904296875}, {"start": 737.06, "end": 737.48, "word": " لحاله", "probability": 0.9818115234375}, {"start": 737.48, "end": 737.6, "word": " و", "probability": 0.69287109375}, {"start": 737.6, "end": 737.68, "word": " بعد", "probability": 0.68017578125}, {"start": 737.68, "end": 738.1, "word": " لحاله", "probability": 0.86785888671875}, {"start": 738.1, "end": 738.28, "word": " هذا", "probability": 0.88134765625}, {"start": 738.28, "end": 738.62, "word": " بيكون", "probability": 0.7284342447916666}, {"start": 738.62, "end": 739.02, "word": " active", "probability": 0.9609375}, {"start": 739.02, "end": 739.18, "word": " و", "probability": 0.880859375}, {"start": 739.18, "end": 739.36, "word": " هذا", "probability": 0.96484375}, {"start": 739.36, "end": 739.8, "word": " active", "probability": 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الأكيدة", "probability": 0.968505859375}, {"start": 781.29, "end": 781.91, "word": " إذا", "probability": 0.5782470703125}, {"start": 781.91, "end": 782.85, "word": " استوعبتوا", "probability": 0.78076171875}, {"start": 782.85, "end": 783.29, "word": " بالظبط", "probability": 0.91455078125}, {"start": 783.29, "end": 783.53, "word": " إيش", "probability": 0.82568359375}, {"start": 783.53, "end": 783.63, "word": " اللي", "probability": 0.970458984375}, {"start": 783.63, "end": 783.93, "word": " بيصير", "probability": 0.94384765625}, {"start": 783.93, "end": 784.37, "word": " عندى", "probability": 0.84326171875}, {"start": 784.37, "end": 784.87, "word": " لما", "probability": 0.875}, {"start": 784.87, "end": 785.23, "word": " نعمل", "probability": 0.9925130208333334}, {"start": 785.23, "end": 785.93, "word": " generation", "probability": 0.9345703125}, {"start": 785.93, "end": 786.29, "word": " of", "probability": 0.97998046875}, {"start": 786.29, "end": 786.51, "word": " a", 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0.6455078125}, {"start": 810.1, "end": 810.5, "word": " عملنا", "probability": 0.99169921875}, {"start": 810.5, "end": 811.22, "word": " تفاعل", "probability": 0.9666748046875}, {"start": 811.22, "end": 812.36, "word": " بعيدا", "probability": 0.9734700520833334}, {"start": 812.36, "end": 812.56, "word": " عن", "probability": 0.99560546875}, {"start": 812.56, "end": 812.76, "word": " ال", "probability": 0.85546875}, {"start": 812.76, "end": 813.26, "word": " chiral", "probability": 0.9423828125}, {"start": 813.26, "end": 813.7, "word": " center", "probability": 0.94287109375}, {"start": 813.7, "end": 813.92, "word": " شو", "probability": 0.860107421875}, {"start": 813.92, "end": 814.32, "word": " بيصير", "probability": 0.984375}, {"start": 814.32, "end": 815.06, "word": " عنده؟", "probability": 0.9264322916666666}], "temperature": 1.0}, {"id": 33, "seek": 84072, "start": 817.0, "end": 840.72, "text": "واضح السؤال؟ خلّيني أعطيكوا ياب بساطة، لو اتخيلت أنا هنا كإنسان عندي chiral center، هاي اتجاه، هاي الاتجاه التاني، هاي الاتجاه التالت، هاي الاتجاه الرابع، ومااخد هذه الاتجاهات بالظبط، وإجيت بعيد عن هذا ال chiral center، اعمل التفاعل، يعني مثلا نمسكت هذا هنا، هل يا تورا هذه الاتجاهات الأربعة تغير فيها إشي؟", "tokens": [2407, 46958, 5016, 21136, 33604, 6027, 22807, 16490, 1211, 11703, 9957, 1829, 5551, 3615, 9566, 1829, 4117, 14407, 7251, 16758, 4724, 3794, 41193, 3660, 12399, 45164, 1975, 2655, 9778, 26895, 2655, 41850, 34105, 9122, 28814, 1863, 3794, 7649, 18871, 16254, 23782, 304, 3056, 12399, 8032, 47302, 1975, 2655, 7435, 40294, 12399, 8032, 47302, 2423, 9307, 7435, 40294, 16712, 7649, 1829, 12399, 8032, 47302, 2423, 9307, 7435, 40294, 16712, 6027, 2655, 12399, 8032, 47302, 2423, 9307, 7435, 40294, 34892, 16758, 3615, 12399, 4032, 15042, 47283, 3215, 29538, 2423, 9307, 7435, 40294, 9307, 20666, 19913, 3555, 9566, 12399, 4032, 28814, 7435, 36081, 45030, 25708, 18871, 23758, 2423, 23782, 304, 3056, 12399, 1975, 25957, 1211, 16712, 5172, 995, 30241, 12399, 37495, 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1674, 12399, 13412, 2407, 4724, 25957, 1211, 22807, 4724, 25957, 1211, 8717, 3794, 9778, 22807], "avg_logprob": -0.2342155563588045, "compression_ratio": 1.2301587301587302, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 841.28, "end": 841.92, "word": "بمعنى", "probability": 0.89619140625}, {"start": 841.92, "end": 842.32, "word": " لو", "probability": 0.767578125}, {"start": 842.32, "end": 842.56, "word": " أنا", "probability": 0.475341796875}, {"start": 842.56, "end": 842.86, "word": " كنت", "probability": 0.984375}, {"start": 842.86, "end": 843.26, "word": " شغال", "probability": 0.9755859375}, {"start": 843.26, "end": 843.46, "word": " على", "probability": 0.76025390625}, {"start": 843.46, "end": 844.08, "word": " برنامج", "probability": 0.99296875}, {"start": 844.08, "end": 844.7, "word": " راسم", "probability": 0.7545572916666666}, {"start": 844.7, "end": 845.4, "word": " و", "probability": 0.403564453125}, {"start": 845.4, "end": 846.14, "word": " هذا", 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"end": 873.48, "text": "و لاصق و بغير بس شغلة بسيطة على الطرف لكن هل غيرت اتجاه المجموعات حول ال chiral center؟ اه إذا ال reaction لما بيكون away بعيد عن ال chiral center away from على ال orientation يعني نفس اتجاه المجموعات", "tokens": [2407, 5296, 33546, 4587, 4032, 4724, 17082, 13546, 4724, 3794, 13412, 17082, 37977, 4724, 3794, 1829, 9566, 3660, 15844, 41950, 28480, 44381, 8032, 1211, 32771, 13546, 2655, 1975, 2655, 7435, 40294, 9673, 7435, 2304, 45367, 9307, 11331, 12610, 2423, 23782, 304, 3056, 22807, 1975, 3224, 11933, 15730, 2423, 5480, 5296, 15042, 4724, 1829, 30544, 1314, 45030, 25708, 18871, 2423, 23782, 304, 3056, 1314, 490, 15844, 2423, 14764, 37495, 22653, 8717, 36178, 1975, 2655, 7435, 40294, 9673, 7435, 2304, 45367, 9307], "avg_logprob": -0.17525076866149902, "compression_ratio": 1.6684782608695652, "no_speech_prob": 1.1324882507324219e-06, "words": [{"start": 852.52, "end": 852.74, "word": "و", "probability": 0.211181640625}, {"start": 852.74, "end": 853.36, "word": " لاصق", "probability": 0.7147623697916666}, {"start": 853.36, "end": 854.12, "word": " و", "probability": 0.433837890625}, {"start": 854.12, "end": 854.64, "word": " بغير", "probability": 0.97509765625}, {"start": 854.64, "end": 854.96, "word": " بس", "probability": 0.841796875}, {"start": 854.96, "end": 855.28, "word": " شغلة", "probability": 0.8816731770833334}, {"start": 855.28, "end": 855.76, "word": " بسيطة", "probability": 0.983984375}, {"start": 855.76, "end": 855.94, "word": " على", "probability": 0.7421875}, {"start": 855.94, "end": 856.32, "word": " الطرف", "probability": 0.968994140625}, {"start": 856.32, "end": 856.6, "word": " لكن", "probability": 0.461669921875}, {"start": 856.6, "end": 856.94, "word": " هل", "probability": 0.984619140625}, {"start": 856.94, "end": 857.72, "word": " غيرت", "probability": 0.98583984375}, {"start": 857.72, "end": 858.5, "word": " اتجاه", "probability": 0.9815673828125}, {"start": 858.5, "end": 859.74, "word": " المجموعات", "probability": 0.98662109375}, {"start": 859.74, "end": 860.4, "word": " حول", "probability": 0.978515625}, {"start": 860.4, "end": 860.56, "word": " ال", "probability": 0.8525390625}, {"start": 860.56, "end": 861.0, "word": " chiral", "probability": 0.6602783203125}, {"start": 861.0, "end": 861.66, "word": " center؟", "probability": 0.5687255859375}, {"start": 861.66, "end": 862.5, "word": " اه", "probability": 0.796875}, {"start": 862.5, "end": 862.92, "word": " إذا", "probability": 0.604736328125}, {"start": 862.92, "end": 863.38, "word": " ال", "probability": 0.90576171875}, {"start": 863.38, "end": 863.9, "word": " reaction", "probability": 0.366943359375}, {"start": 863.9, "end": 864.26, "word": " لما", "probability": 0.909912109375}, {"start": 864.26, "end": 864.84, "word": " بيكون", "probability": 0.96435546875}, {"start": 864.84, "end": 865.76, "word": " away", "probability": 0.89404296875}, {"start": 865.76, "end": 866.42, "word": " بعيد", "probability": 0.7381591796875}, {"start": 866.42, 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{"start": 885.41, "end": 885.59, "word": " هذه", "probability": 0.9599609375}, {"start": 885.59, "end": 886.17, "word": " المجموعات", "probability": 0.9787109375}, {"start": 886.17, "end": 886.51, "word": " بتظل", "probability": 0.80322265625}, {"start": 886.51, "end": 886.73, "word": " زي", "probability": 0.8076171875}, {"start": 886.73, "end": 886.83, "word": " ما", "probability": 0.97998046875}, {"start": 886.83, "end": 887.07, "word": " هي", "probability": 0.9033203125}, {"start": 887.07, "end": 888.27, "word": " الآن", "probability": 0.55340576171875}, {"start": 888.27, "end": 889.25, "word": " ممكن", "probability": 0.964599609375}, {"start": 889.25, "end": 889.85, "word": " نعطي", "probability": 0.934814453125}, {"start": 889.85, "end": 890.95, "word": " أمثلة،", "probability": 0.832421875}, {"start": 890.95, "end": 891.25, "word": " ممكن", "probability": 0.92529296875}, {"start": 891.25, "end": 891.61, "word": " نعطي", "probability": 0.9892578125}, {"start": 891.61, "end": 892.13, "word": " أمثلة", "probability": 0.9901123046875}], "temperature": 1.0}, {"id": 37, "seek": 92245, "start": 893.41, "end": 922.45, "text": "مثلًا لو طلعنا على هذا المُركّب أنا مش كتير بهم أن تكونوا عارفين التفاعل لأنه لسه ما درستهوش في عندي CH3 و CH2 و CH3 و COH و COH أسد الأن لو هذا الحمض حولته ل E star هل يا تورة أنا غيرت في اتجاه هذه المجموعات؟ اتطلعوا مع ال مثل لفوق ال S لتحت ال H بهالاتجاه؟ و بهذه النطفة بعيدًا عن ال chiral center عملت تغيير واضح؟ إذا هنا في عندي عملية إيش؟", "tokens": [2304, 12984, 1211, 14111, 995, 45164, 23032, 1211, 3615, 8315, 15844, 23758, 9673, 10859, 31747, 11703, 3555, 41850, 37893, 9122, 2655, 13546, 4724, 16095, 14739, 6055, 30544, 14407, 6225, 9640, 5172, 9957, 16712, 5172, 995, 30241, 5296, 33456, 3224, 5296, 3794, 3224, 19446, 11778, 2288, 14851, 3224, 2407, 8592, 8978, 43242, 1829, 5995, 18, 4032, 5995, 17, 4032, 5995, 18, 4032, 3002, 39, 4032, 3002, 39, 5551, 3794, 3215, 16247, 1863, 45164, 23758, 21542, 2304, 11242, 11331, 12610, 47395, 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"seek": 96718, "start": 958.4, "end": 967.18, "text": "الخلاصة هل يا تورا هنا تم تغيير لاتجاهات المجموعات يعني لاحظوا ال H لchlorine ايه في الفيلم", "tokens": [6027, 9778, 1211, 33546, 3660, 8032, 1211, 35186, 6055, 13063, 995, 34105, 46811, 6055, 17082, 1829, 13546, 5296, 9307, 7435, 40294, 9307, 9673, 7435, 2304, 45367, 9307, 37495, 22653, 20193, 5016, 19913, 14407, 2423, 389, 5296, 11439, 284, 533, 1975, 1829, 3224, 8978, 27188, 1829, 19528], "avg_logprob": -0.34940159447649694, "compression_ratio": 1.319327731092437, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 958.3999999999999, "end": 959.4799999999999, "word": "الخلاصة", "probability": 0.87421875}, {"start": 959.4799999999999, "end": 960.56, "word": " هل", "probability": 0.725341796875}, {"start": 960.56, "end": 960.74, "word": " يا", "probability": 0.79150390625}, {"start": 960.74, "end": 961.28, "word": " تورا", "probability": 0.81787109375}, {"start": 961.28, "end": 961.96, "word": " هنا", "probability": 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"text": "الاختلاف، إذا مافيش اختلاف كيف بدأ أفصل أشياء عن بعض؟ العملية صعبة، الآن ال enantiomers اتذكروا مع ال physical appropriatism melting point لو كنت بده أعمل crystallization نفس الأشياء boiling point لو بده أعمل distillation نفس الأشياء polarity لو بده أعمل chromatography مش هاد الطرق الفصل اللي انتوا اتعلمتوها في ال organic lab", "tokens": [6027, 47283, 2655, 15040, 5172, 12399, 11933, 15730, 19446, 41185, 8592, 1975, 46456, 15040, 5172, 9122, 33911, 47525, 10721, 5551, 5172, 36520, 5551, 8592, 1829, 16606, 18871, 45030, 11242, 22807, 18863, 42213, 10632, 20328, 3615, 49401, 12399, 6024, 48506, 2423, 465, 11520, 298, 433, 1975, 2655, 8848, 37983, 14407, 20449, 2423, 4001, 5745, 267, 1434, 20493, 935, 45164, 9122, 29399, 47525, 3224, 5551, 25957, 1211, 31924, 2144, 8717, 36178, 16247, 8592, 1829, 16606, 16208, 935, 45164, 47525, 3224, 5551, 25957, 1211, 42923, 399, 8717, 36178, 16247, 8592, 1829, 16606, 12367, 507, 45164, 47525, 3224, 5551, 25957, 1211, 16209, 267, 5820, 37893, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w.srt
new file mode 100644
index 0000000000000000000000000000000000000000..bfb9fb7e9891b806258e02338dc3297eefa297df
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w.srt
@@ -0,0 +1,1802 @@
+1
+00:00:08,920 --> 00:00:14,050
+بسم الله الرحمن الرحيم،الجزء الأخير من مشتقات
+
+2
+00:00:14,050 --> 00:00:19,090
+الأحماض اللي بدأت تمر علينا اليوم هو الاميدات، واضح؟
+
+3
+00:00:19,090 --> 00:00:23,890
+الآن إذا بدنا نشوف شو هما الاميدات كمجموعة وظيفية 
+
+4
+00:00:23,890 --> 00:00:29,370
+لما نلتقي عند سيّدة بالرابط O وجنبها N سيّدة بالرابط 
+
+5
+00:00:29,370 --> 00:00:36,710
+O N هذه اللي بتمثل مجموعة الاميدات، واضح؟ لو بدنا 
+
+6
+00:00:36,710 --> 00:00:43,410
+نسمي الاميدات بنرجع للأصل اللي جاي منه ال amides
+
+7
+00:00:43,410 --> 00:00:46,990
+اللي بنفترض أنه الـ acid لأنّها مشتقة من مشتقات
+
+8
+00:00:46,990 --> 00:00:51,990
+الحامض، مثلاً هنا عندي كربونة، اثنتين، ثلاث، شو بيكون 
+
+9
+00:00:51,990 --> 00:00:57,870
+اسم الحامض؟ بروبانويك أسيد، بشيل اويك أسيد وبكتب
+
+10
+00:00:57,870 --> 00:01:05,590
+بروبان اميد، إذا كان الـ acid بروبانويك أسيد شيلت كل
+
+11
+00:01:05,590 --> 00:01:10,390
+اويك أسيد، بروبان اميد، مثلاً هذا الـ amide جاي من
+
+12
+00:01:11,430 --> 00:01:20,550
+البنزويك أسيد، فبيصير اسمه بنز اميد، وهكذا طبعاً 
+
+13
+00:01:20,550 --> 00:01:29,450
+بتلاحظوا أنتم أنّ الاميد فيها C=O وفيها N والـ 
+
+14
+00:01:29,450 --> 00:01:33,770
+Oxygen والـ Nitrogen طبعاً بالإضافة للـ Fluor هم 
+
+15
+00:01:33,770 --> 00:01:38,070
+الثلاث عناصر اللي معروف أنّهم بيعملوا الـ hydrogen
+
+16
+00:01:38,070 --> 00:01:43,670
+bonding، واضح؟ فبناءً على ذلك جزيئات الاميد بينها وبين
+
+17
+00:01:43,670 --> 00:01:47,410
+نفسها ممكن تكون عاملة hydrogen bonding سواء 
+
+18
+00:01:47,410 --> 00:01:51,610
+كان one hydrogen bond يعني الـ N مع الـ O تعمل 
+
+19
+00:01:51,610 --> 00:01:55,390
+hydrogen bonding أو بترتيب معين ممكن يكون بين
+
+20
+00:01:55,390 --> 00:01:59,110
+الجزيئين two hydrogen bonds يعني زي ما نتخيل زي 
+
+21
+00:01:59,110 --> 00:02:01,910
+هيك، هاي حالة، في عندي نيتروجين وأكسوجين ونيتروجين 
+
+22
+00:02:01,910 --> 00:02:05,510
+وأكسوجين، ممكن يصير اتحاد بس بهذا الشكل، وممكن
+
+23
+00:02:05,510 --> 00:02:11,350
+يصير اتحاد كل أكسوجين مع نيتروجين، لكنّ الإمكانية للـ
+
+24
+00:02:11,350 --> 00:02:16,010
+hydrogen bond قائمة وأساسية في ال amides هذا
+
+25
+00:02:16,010 --> 00:02:20,890
+الكلام بينعكس على شغلة، بينعكس على شغلة أنّ طالما
+
+26
+00:02:20,890 --> 00:02:25,350
+الاميد مع نفسها بتعمل hydrogen bonding إذا نتوقع 
+
+27
+00:02:25,350 --> 00:02:29,690
+شو بيصير في الـ boiling point؟ نقاط غليانها مرتفعة
+
+28
+00:02:29,690 --> 00:02:34,990
+طبعاً هنا لما بتيجوا بتتطلعوا على أيّ اميد محدد حقيقة
+
+29
+00:02:34,990 --> 00:02:40,440
+الاميد في N، أحنا قلنا بس أنّ بيصير اميد، لكن هذه الـ N
+
+30
+00:02:40,440 --> 00:02:44,520
+ممكن يكون عليها two hydrogens ممكن يكون عليها
+
+31
+00:02:44,520 --> 00:02:49,660
+hydrogen واحدة وR group وممكن يكون عليها two R 
+
+32
+00:02:49,660 --> 00:02:54,720
+groups، واضح؟ يعني مش لازم دائماً الـ nitrogen هذه 
+
+33
+00:02:54,720 --> 00:03:02,440
+تكون NH2، ممكن تكون هذه NH2، ممكن تكون NHR، وممكن 
+
+34
+00:03:02,440 --> 00:03:03,460
+تكون NR2
+
+35
+00:03:06,380 --> 00:03:10,120
+بناءً على ذلك، وبناءً على ذلك، كأنّه في عندي 
+
+36
+00:03:10,120 --> 00:03:14,880
+substituted amides وعندي unsubstituted amides يعني 
+
+37
+00:03:14,880 --> 00:03:20,200
+هذا الاميد اللي من كربونة واحدة جاي من أيّ حامض من 
+
+38
+00:03:20,200 --> 00:03:25,040
+الـ formic أو الـ methanoic acid فبنسميه form اميد
+
+39
+00:03:25,040 --> 00:03:29,900
+طيب، الآن لو عملت إبدال للـ two hydrogens اللي 
+
+40
+00:03:29,900 --> 00:03:36,410
+تبع الـ nitrogen هنا، الـ two مثل groups، بيصير إيش
+
+41
+00:03:36,410 --> 00:03:40,630
+اسمه؟ Dimethylformamide
+
+42
+00:03:40,630 --> 00:03:45,750
+طبعاً مرات بيروحوا بيحطوا N وN لإيضاح بأنّ الميثل
+
+43
+00:03:45,750 --> 00:03:50,370
+هذه والميثل هذه متصلات بالنيتروجين، فممكن تلاقوا
+
+44
+00:03:50,370 --> 00:03:56,670
+هذا المركب باسم N,N-Dimethylformamide، ممكن تلاقوا
+
+45
+00:03:56,670 --> 00:04:02,200
+باسم Dimethylformamide ويكونوا مختصرين، الآن أنّ 
+
+46
+00:04:02,200 --> 00:04:06,440
+وغالباً هذا الـ solvent وله تطبيقات كتير واستعمالات
+
+47
+00:04:06,440 --> 00:04:09,360
+كتير في الـ organic chemistry بيكتبوه مختصر على
+
+48
+00:04:09,360 --> 00:04:17,060
+الآخر بصيغة DMF، فسواء قلنا DMF، الاسم الاختصاري
+
+49
+00:04:17,060 --> 00:04:23,810
+تبعه dimethylformamide أو كتبناه بـ 
+
+50
+00:04:23,810 --> 00:04:27,230
+dimethylformamide أو كتبناه بـ N,N-
+
+51
+00:04:27,230 --> 00:04:32,170
+dimethylformamide، أحنا بنعبر عن نفس الشغلة، فلو 
+
+52
+00:04:32,170 --> 00:04:37,050
+قلنا لكم في الامتحان والله ارسموا لنا شكل الـ DMF بس 
+
+53
+00:04:37,050 --> 00:04:41,670
+كتبنا DMF وارسموا شكله، فالمفروض أنّكوا تعرفوا أنّ 
+
+54
+00:04:41,670 --> 00:04:48,510
+الـ DMF اللي هو هذا الشكل، الآن لاحظوا عاد بين الـ
+
+55
+00:04:48,510 --> 00:04:54,410
+formamide العادي والآن N,N-dimethyl formamide، في فرق
+
+56
+00:04:54,410 --> 00:04:59,270
+كبير، هذا الفرق أنّ الـ two هيدروجين اللي موجودات 
+
+57
+00:04:59,270 --> 00:05:04,270
+اختفوا وبناءً على ذلك هنا في إمكانية hydrogen 
+
+58
+00:05:04,270 --> 00:05:08,590
+bonding، هنا ما فيش إمكانية hydrogen bonding إذا أنّ
+
+59
+00:05:08,590 --> 00:05:13,550
+هو اللي بدو يكون أعلى في الـ boiling point، الأول 
+
+60
+00:05:13,550 --> 00:05:17,250
+اللي بيعمل hydrogen bonding، الـ unsubstituted أميد
+
+61
+00:05:17,250 --> 00:05:20,290
+بناءً على ذلك الـ form اميد مثلاً لو كنت تشوف نقطة
+
+62
+00:05:20,290 --> 00:05:25,990
+غليانه 210 بينما الـ N,N-dimethyl form اميد 153
+
+63
+00:05:25,990 --> 00:05:30,730
+رغم أنّ هذا بالوزن بالـ molecular weight أعلى من هذا
+
+64
+00:05:30,730 --> 00:05:34,830
+لكنّ هذا فقط خاصية مهمة جداً اللي هي خاصية الـ 
+
+65
+00:05:34,830 --> 00:05:39,360
+hydrogen bonding، طبعاً لو عندي مثل فورمامد واحدة 
+
+66
+00:05:39,360 --> 00:05:42,060
+يعني بدل ما يعمل من جهتين hydrogen bonds بيعمل من
+
+67
+00:05:42,060 --> 00:05:47,060
+واحدة بيكون in between بينهم، كذلك الحال لو أخدت
+
+68
+00:05:47,060 --> 00:05:50,900
+مثلاً هذا المركب الشهير اللي اسمه acetamide من
+
+69
+00:05:50,900 --> 00:05:57,240
+الـ acetic acid two carbons، acetic acid لما بيجي اميد 
+
+70
+00:05:57,240 --> 00:06:00,820
+بيصير acetamide، لو كان في مثلاً الـ methyl groups
+
+71
+00:06:00,820 --> 00:06:03,680
+بيصير N,N-dimethyl
+
+72
+00:06:11,460 --> 00:06:16,080
+بالنسبة لهذا البرنامج، موجود في الحالة الأولى ولم
+
+73
+00:06:16,080 --> 00:06:18,280
+يكن موجود في الحالة الثانية
+
+74
+00:06:22,670 --> 00:06:26,830
+دائماً قلنا ما بنعملش مقارنة بين شغلتين ما فيش بينهم
+
+75
+00:06:26,830 --> 00:06:32,190
+مشترك، بنطلع التجربة، نطلع التجربة، واضح؟ يعني
+
+76
+00:06:32,190 --> 00:06:38,070
+دائماً في المقارنة مبدأ أساسي، بس تخلوا إيش؟ متغير 
+
+77
+00:06:38,070 --> 00:06:43,650
+واحد، إذا صار أكثر من متغير، بدكوا تعمله تجارب،
+
+78
+00:06:43,650 --> 00:06:47,970
+وذكّرتكم سابقاً بقوانين الغازات لما بيعملوا مقارنة،
+
+79
+00:06:47,970 --> 00:06:53,300
+بنقارن الضغط بالحجم عن ثبات عدد المولات وعن ثبات
+
+80
+00:06:53,300 --> 00:06:59,760
+درجة الحرارة، وهكذا، الآن كيف تحضر الاميدات من
+
+81
+00:06:59,760 --> 00:07:03,660
+الحامض؟ بتفاعل الحامض مع الأمونيا والحرارة، بيصير
+
+82
+00:07:03,660 --> 00:07:08,200
+عندي اميد، وبتاع هيك شغلة مرت علينا من الـ acid 
+
+83
+00:07:08,200 --> 00:07:12,800
+chloride أو من الـ ester بتفاعله مع الأمونيا والـ
+
+84
+00:07:12,800 --> 00:07:17,840
+تفاعل اللي بيصير nucleophilic substitution الأمونيا 
+
+85
+00:07:17,840 --> 00:07:23,240
+بتهاجم والكلورة بيطلع، وبرضه مرّ علينا هذا التحضير 
+
+86
+00:07:23,240 --> 00:07:31,100
+الآن لو بدنا نتطلع على نقطة مهمة جداً حقيقة في الـ 
+
+87
+00:07:31,100 --> 00:07:37,060
+amides، الـ amide موجود في C=O وموجود في 
+
+88
+00:07:37,060 --> 00:07:42,730
+نيتروجين عليها زوج إلكترونات، واضح؟ الآن الـ C
+
+89
+00:07:42,730 --> 00:07:48,330
+double bond O، الـ C double bond O أخذنا عنها أنّها 
+
+90
+00:07:48,330 --> 00:07:54,450
+group very reactive والدليل على هيك إنّه أحنا قلنا
+
+91
+00:07:54,450 --> 00:07:58,030
+يمكن تلت أسابيع بناخد aldehydes و ketones و acids 
+
+92
+00:07:58,030 --> 00:08:02,950
+ومشتقاتها وكلهم عبارة عن تفاعلات على إيش؟ على الـ C
+
+93
+00:08:02,950 --> 00:08:06,910
+double bond O، ومحور الـ reactivity في الـ C double
+
+94
+00:08:06,910 --> 00:08:11,900
+bond O إنّه هذا الكربون partially positive والأكسجين
+
+95
+00:08:11,900 --> 00:08:17,280
+partially negative، فالتفاعل الأساسي للـ C=O هو
+
+96
+00:08:17,280 --> 00:08:21,200
+أنّ يجيب نيجاتيف يهاجم عليها أو الـ nucleophile الـ 
+
+97
+00:08:21,200 --> 00:08:24,080
+nucleophilic يا addition في حالة الألدهيدات
+
+98
+00:08:24,080 --> 00:08:28,700
+والكيتونات، يا substitution في حالة الأحماض المشتقة
+
+99
+00:08:28,700 --> 00:08:31,480
+إذا أنا هنا الكربون هذه مجموعة
+
+100
+00:08:36,660 --> 00:08:41,720
+السبب هو وجوده الـ positive، برضه نيتروجين أخذنا عنها 
+
+101
+00:08:41,720 --> 00:08:45,020
+هون أنّها ما كانت بتتفاعل يعني تطلع في المثال اللي قبل 
+
+102
+00:08:45,020 --> 00:08:49,980
+هيك، في التحضيرات هذه الـ nitrogen زوج الإلكترونات 
+
+103
+00:08:49,980 --> 00:08:53,040
+هذا بيخليها الـ nucleophile، يعني كأنّه أنشطتش في
+
+104
+00:08:53,040 --> 00:08:56,780
+التفاعل لما يكون شغلة positive ولا شغلة negative 
+
+105
+00:08:56,780 --> 00:09:02,280
+سواء بشكل كامل أو جزء، فالخلاصة أنّ هنا في الاميد 
+
+106
+00:09:02,280 --> 00:09:09,470
+بيلتقي بمجموعتين وظيفيتين ناشطات جداً، يعني الـ C
+
+107
+00:09:09,470 --> 00:09:13,870
+double bond O اللي فيها تلت أسابيع، chapter تسعة أو
+
+108
+00:09:13,870 --> 00:09:16,730
+عشر، الألدهيدات، الكيتونات، الأحماض، كلهم تفاعلاتها،
+
+109
+00:09:16,730 --> 00:09:20,250
+مظبوط ولا لأ؟ والنيتروجين لوحدها اللي هي الـ
+
+110
+00:09:20,250 --> 00:09:24,310
+amines عندنا الـ chapter إحدى عشر كله بيدرس 
+
+111
+00:09:24,310 --> 00:09:28,310
+تفاعلاتها، الـ amines، ولما أخذنا الـ substitution
+
+112
+00:09:28,310 --> 00:09:33,330
+هي nucleophile قوي، إذا أنا كأنّي هنا أمام أكثر
+
+113
+00:09:33,330 --> 00:09:37,420
+مجموعتين في الـ organic chemistry نشاطاً وتفاعلاً، ماذا 
+
+114
+00:09:37,420 --> 00:09:43,580
+هم؟ الـ C double bond O والنيتروجين، هذول الـ C 
+
+115
+00:09:43,580 --> 00:09:46,860
+double bond O والنيتروجين من أكثر المجموعات 
+
+116
+00:09:46,860 --> 00:09:50,960
+تفاعلاً، بس للأسف الشديد في شرط عشان يكون أكثر 
+
+117
+00:09:50,960 --> 00:09:55,600
+المجموعات تفاعلاً أنّ كل واحدة تكون لحالها، طيب لما
+
+118
+00:09:55,600 --> 00:09:58,580
+بيصيروا جانب بعض في الاميد 
+
+119
+00:10:01,120 --> 00:10:07,560
+لاحظوا أنا صارت اثنتين في جزء واحد جانب بعض، بيصير
+
+120
+00:10:07,560 --> 00:10:10,380
+أقل جزء في التفاعلات
+
+121
+00:10:12,630 --> 00:10:17,110
+ليش؟ لأنّه بيصير يتشغل بحاله، بدل ما يكون جاهز أنّ 
+
+122
+00:10:17,110 --> 00:10:20,870
+يتفاعل للخارج، هنا في عندي موجب وهنا سالب، السالب
+
+123
+00:10:20,870 --> 00:10:24,810
+بده موجب، والموجب بده سالب، فكأنّه هذا السالب بنقدر 
+
+124
+00:10:24,810 --> 00:10:28,270
+نتخيله بيجي على هذا الموجب بهذا الشكل، بيعمل
+
+125
+00:10:28,270 --> 00:10:33,330
+resonance structures، لا ضال هنا موجب ولا ضال هنا
+
+126
+00:10:33,330 --> 00:10:39,450
+سالب وبناءً على ذلك بيصير الاميد very very unreactive
+
+127
+00:10:39,450 --> 00:10:43,990
+ولا كأنّه فيه C=O ولا كأنّه فيه نيتروجين
+
+128
+00:10:43,990 --> 00:10:49,430
+ولذلك الآن ما بناخدش تفاعلات كتيرة للاميدات، ليش؟ 
+
+129
+00:10:49,430 --> 00:10:52,590
+لأنّ الـ C=O بحاجة لإلكترونات من وين
+
+130
+00:10:52,590 --> 00:10:58,150
+بتاخدهم؟ من داخل الجزء، ما بتروحش تستنى حاجة من برة 
+
+131
+00:10:58,150 --> 00:11:01,490
+تيجي تهجم عليها، وبصير هذا الـ resonance structures
+
+132
+00:11:01,490 --> 00:11:09,170
+فبسبب الـ Resonance يُعتبر الاميد unreactive، يعني 
+
+133
+00:11:09,170 --> 00:11:16,530
+الاميد الـ Resonance يُعتبر اميداً غير ردود فعل، واضح؟
+
+134
+00:11:16,530 --> 00:11:19,950
+إذن إيش سبب الـ unreactivity؟ اللي هو الاميد
+
+135
+00:11:19,950 --> 00:11:24,570
+resonance، رغم إنّ هالمجموعتين يُعتبروا زي ما اتفقنا
+
+136
+00:11:24,570 --> 00:11:28,550
+من إيش؟ من أنشط المجموعات لما يكونوا كل واحدة لحال
+
+137
+00:11:28,550 --> 00:11:34,290
+لكن إذا أتيوا مع بعض سبحان الله، بتشغلوا في بعض زي
+
+138
+00:11:34,290 --> 00:11:41,250
+هيك، ربما مما يثبت هذا الكلام أنّ الاميد is very 
+
+139
+00:11:41,250 --> 00:11:49,210
+unreactive، أنّ عندكم النايلون، النايلون، النايلون
+
+140
+00:11:49,210 --> 00:11:55,410
+الحقيقة هو عبارة عن اميد، النايلون اللي أحنا بنستعمله 
+
+141
+00:11:55,410 --> 00:12:00,630
+عبارة عن اميد، وهذا النايلون very unreactive في
+
+142
+00:12:00,630 --> 00:12:04,830
+الدليل على هيك إنّه أحنا مثلاً لو دفنّا عدة شغلات في
+
+143
+00:12:04,830 --> 00:12:08,750
+الأرض وجينا بعد شهرين فحرنا الأرض، بنلاقي فضلات
+
+144
+00:12:08,750 --> 00:12:12,790
+الطعام وأوراق الأشجار وما إلى ذلك كلها إش مالها 
+
+145
+00:12:12,790 --> 00:12:17,670
+متحللة، لكنّ كياس النايلون بتظلّ وبتعمل مشكلة بيئية 
+
+146
+00:12:18,380 --> 00:12:22,540
+واضح؟ طبعاً أيّ شيء ممكن يعمل... أيّ شيء ممكن
+
+147
+00:12:22,540 --> 00:12:28,880
+بالمناسبة يعمل مشكلة وممكن يكون مفيد حسب الحالة
+
+148
+00:12:28,880 --> 00:12:32,860
+اللي أنا بتعامل فيها، يعني تماماً زي السكينة على
+
+149
+00:12:32,860 --> 00:12:36,840
+سبيل المثال، لازمان عشان أقطع فيها أو عشان هيك 
+
+150
+00:12:36,840 --> 00:12:40,900
+بجيبها بالدار، لكن بنفس الوقت ممكن تجرح أو... تقتل 
+
+151
+00:12:40,900 --> 00:12:45,320
+بيعتمد على الاستعمال، الآن النايلون يوم ما أخلص من 
+
+152
+00:12:45,320 --> 00:12:48,700
+استعماله زي الكياس اللي بنشتري منها وبدنا نتخلص 
+
+153
+00:12:48,700 --> 00:12:52,020
+منها وهلوم، مجرد هو يمثل مشكلة بيئية أنا مش قادر
+
+154
+00:12:52,020 --> 00:12:56,420
+أتخلص منه، لكنّ النايلون في مرات ثانية لما بدي شيء
+
+155
+00:12:56,420 --> 00:13:03,340
+طول عنده، بكون بحاجة إلى نايلون، يعني مثلاً في الدول 
+
+156
+00:13:03,340 --> 00:13:07,240
+اللي بيمشوا فيها كوابل التليفونات أو كهربا في 
+
+157
+00:13:07,240 --> 00:13:11,900
+الأرض على عمق متر، بيحطوا الكابل في الأرض على عمق 
+
+158
+00:13:11,900 --> 00:13:15,640
+متر وبطمّوا شوية على عمق نصف متر، بتجيبوا شريط
+
+159
+00:13:15,640 --> 00:13:20,210
+النايلون الأصفر، إذا بتشوفوا إيش بيكون مكتوب، انتبه 
+
+160
+00:13:20,210 --> 00:13:25,210
+خطر الحفريات أو خطر الكهرباء، وفوق السلك المدفون
+
+161
+00:13:25,210 --> 00:13:29,130
+بنصف متر بيكونوا حاطين أشريط نايلون عليها الكتابة 
+
+162
+00:13:29,130 --> 00:13:32,590
+هذا الشريط مفترض أنّ ممكن يظلّ عشر أو خمسة عشر أو 
+
+163
+00:13:32,590 --> 00:13:37,310
+عشرين سنة، يعني لو واحد ييجي يفحر بجرافة أو إيش،
+
+164
+00:13:37,310 --> 00:13:42,510
+إنابيب، بعد نصف متر هتلاقي إيش؟ كابل كهربا، فبعد 
+
+165
+00:13:42,510 --> 00:13:47,870
+الحلقة أنا بصير مستفيد من فكرة أنّ النايلون ما بتحللش
+
+166
+00:13:47,870 --> 00:13:52,030
+فأيّ شيء ممكن أنّ أستفيد منها إذا بدّي إياها شغلة مهمة
+
+167
+00:13:52,030 --> 00:13:58,190
+ما يهمني ما تتحللش، لكن إذا خلصت منها بيصير مشكلة خصوصاً
+
+168
+00:13:58,190 --> 00:14:01,110
+بتشمه لما الناس في الليل بيحرجوا النايلون وكيف
+
+169
+00:14:01,110 --> 00:14:06,310
+الرائحة تبعته لأنّ النايلون ما بتحللش، طيب نرجع إلى الـ
+
+170
+00:14:06,310 --> 00:14:
+
+201
+00:16:51,170 --> 00:16:55,110
+الثانية تقريبا كل استفادة من النيلون للصناعات اللي
+
+202
+00:16:55,110 --> 00:16:59,530
+بتفيد الناس أغلقت لأنه صار لازم أعمل منه خيام
+
+203
+00:16:59,530 --> 00:17:04,670
+وبراشوت وما إلى ذلك فكل شغل النيلون صار يتحول
+
+204
+00:17:04,670 --> 00:17:08,930
+لإيش؟ للحرب في الحرب العالمية الثانية، خلصت الحرب 
+
+205
+00:17:08,930 --> 00:17:12,970
+رجعوا يستعملوا في الملابس النيلون fibers،
+
+206
+00:17:12,970 --> 00:17:18,890
+الـ fibers، اليوم أفضل الملابس، أقل تقدير بالنسبة
+
+207
+00:17:18,890 --> 00:17:23,690
+للنساء يعني، اللي بيكون فيها نسبة إيش؟ نيلون، مين
+
+208
+00:17:23,690 --> 00:17:30,530
+بيقدر يتعامل اليوم مع قميص كله قطن؟ من ناحية
+
+209
+00:17:30,530 --> 00:17:36,210
+الكوي، من ناحية إيش؟ بيكوي قميص القطن إلا يكون 60%
+
+210
+00:17:36,210 --> 00:17:42,550
+قطن و 40% نيلون، مظبوط ولا لأ؟ فالخلاصة هذا هو
+
+211
+00:17:42,550 --> 00:17:47,070
+النيلون اللي هو عبارة عن Amides، الآن احنا اللي
+
+212
+00:17:47,070 --> 00:17:53,700
+قلناه أن تفاعلات الـ Amides هي تفاعلات قليلة من
+
+213
+00:17:53,700 --> 00:17:57,460
+التفاعلات القليلة أنه في ظروف معينة ليست سهلة يعني
+
+214
+00:17:57,460 --> 00:18:03,120
+بلزم حرارة وبلزم زمان كتير، الأمن مع المي أو حامض
+
+215
+00:18:03,120 --> 00:18:07,620
+أو قاعدة أو حرارة أو زمان ممكن يتحول إلى أسف بمعنى
+
+216
+00:18:07,620 --> 00:18:11,300
+أن الـ O H تاعة المي أو المي كلها تهاجم وبعدين
+
+217
+00:18:11,300 --> 00:18:17,320
+تفقد H فالـ amine بيصير له عملية بيسميها hydrolysis،
+
+218
+00:18:17,320 --> 00:18:22,320
+hydrolysis ليش؟ لأنه هو تفاعل مع الميه، تفاعل
+
+219
+00:18:22,320 --> 00:18:26,480
+الشغل مع الميه، hydrolysis فالـ amide ممكن يصير له
+
+220
+00:18:26,480 --> 00:18:31,280
+hydrolysis بس زي ما قلتلكوا، بده وقت و بده حرارة و
+
+221
+00:18:31,280 --> 00:18:35,520
+ما إلى ذلك، الشروط التفصيلية بتكون مكتوبة في الكتب
+
+222
+00:18:35,520 --> 00:18:40,680
+العملية، الشغل الثاني أنه زي ما كان يحصل عندي للـ
+
+223
+00:18:40,680 --> 00:18:45,360
+Ester's reduction، الـ amide ممكن يحصل له reduction
+
+224
+00:18:45,360 --> 00:18:49,520
+اتذكروا معايا في حالة الـ Ester عشان اتقارنوا
+
+225
+00:18:49,520 --> 00:18:53,740
+المعادلتين بالظبط لما كان يكون عندي الـ Ester و
+
+226
+00:18:53,740 --> 00:18:57,460
+كنت أعمله reduction بدي أحطه تحته بالظبط كان عندي
+
+227
+00:18:57,460 --> 00:19:04,300
+RC double bond O وأعمل reduction
+
+228
+00:19:19,800 --> 00:19:24,760
+الـ amide بنفس المنطق تمامًا الـ C double bond O تبعته
+
+229
+00:19:24,760 --> 00:19:29,500
+في الـ reduction بتصير CH2، إذا لما بيكون عندي R C
+
+230
+00:19:29,500 --> 00:19:32,100
+double bond O NH2 معناه أن أنا الـ amide بهيدروجين 
+
+231
+00:19:32,100 --> 00:19:38,520
+بيصير R CH2 NH2 يعني كأنه في الحالتين أنا عمال
+
+232
+00:19:38,520 --> 00:19:43,800
+بخلي الـ C double bond O CH2 بس ما بتروحش هذا،
+
+233
+00:19:43,800 --> 00:19:49,820
+ما بنخصمش carbon واضح؟ فالـ amides are reduced to
+
+234
+00:19:49,820 --> 00:19:56,380
+amines، المركبات اللي فيهم بس N H2 هم عبارة عن إيش؟
+
+235
+00:19:56,380 --> 00:19:59,520
+الـ amides، بهيك احنا بنقول أخذنا طريقة لتحضير الـ
+
+236
+00:19:59,520 --> 00:20:04,240
+amines ولا لا؟ يعني لما نحكي في chapter 11
+
+237
+00:20:04,240 --> 00:20:10,080
+preparation of amines هنقول by reduction of amides
+
+238
+00:20:11,030 --> 00:20:15,510
+إذا هذا هو يمثل بالنسبة للـ amide تفاعل، بس بالنسبة
+
+239
+00:20:15,510 --> 00:20:20,890
+للـ amine طريقة تحضير، بالنسبة للـ amide هو تفاعل،
+
+240
+00:20:20,890 --> 00:20:24,190
+بالنسبة للـ amine هو طريقة تحضير
+
+241
+00:20:25,870 --> 00:20:33,390
+الآن هذا الـ slide بتفرجيكوا بعض الأدوية اللي فيها
+
+242
+00:20:33,390 --> 00:20:38,630
+من مشتقات الأحماض حتى تشوفوا أنه مش الكيميا بس
+
+243
+00:20:38,630 --> 00:20:43,750
+رموز لكنها أشياء على أرض الواقع، يمكن هذا المركب
+
+244
+00:20:43,750 --> 00:20:48,430
+اللي هنا اللي هو عبارة عن أسبرين وهنا Ester الـ
+
+245
+00:20:48,430 --> 00:20:52,850
+principle I see the word OOR هذا Ester وهذا أسبرين
+
+246
+00:20:52,850 --> 00:20:58,390
+هذا الـ Aspirin اللي سميناه أسبرين الـ salicylic acid
+
+247
+00:20:58,390 --> 00:21:02,870
+الأسبرين والأسبرين اللي هو الـ analgesics أو الـ
+
+248
+00:21:02,870 --> 00:21:11,220
+pain killer اللي هو قاتل الألم يعني بيشيل الألم، الثاني
+
+249
+00:21:11,220 --> 00:21:17,540
+اللي بيمر علينا كثير اللي هو الـ acetaminophen و
+
+250
+00:21:17,540 --> 00:21:22,620
+هذا إله أسماء كتيرة ودواء يمكن ماحدش شنطته ما بكونش 
+
+251
+00:21:22,620 --> 00:21:30,110
+فيها منه اللي هو الـ Acamol، Acamol بنادول Tylenol كل
+
+252
+00:21:30,110 --> 00:21:36,470
+دولة بطريقتها لكن الاسم العلمي تبعه Acetaminophen
+
+253
+00:21:36,470 --> 00:21:41,690
+ليش؟ لأن هذا Amino phenol بالأصل يعني لما ناخد
+
+254
+00:21:41,690 --> 00:21:47,490
+البنزين و OH هذا Phenol لما يكون هنا NH2 Amino
+
+255
+00:21:47,490 --> 00:21:52,890
+حطينا Acetyl هون فبتصير Acetaminophen
+
+256
+00:21:55,190 --> 00:22:01,090
+Aminophenol، فكله بيسموه أسيتامينوفين عرفتوا كيف
+
+257
+00:22:01,090 --> 00:22:05,990
+الاسم جاي؟ اللي هو الـ Acamol أسيتامينوفين هذا
+
+258
+00:22:05,990 --> 00:22:12,410
+فيناستين برضه pain killer وبنفس الوقت بنسميه
+
+259
+00:22:12,410 --> 00:22:21,090
+antibiotic، antibiotic، الاشياء المخفضة للحرارة واضح؟
+
+260
+00:22:21,090 --> 00:22:24,570
+يعني دائمًا أنتو لما الصغار اللي عندكم يسخنوا شو
+
+261
+00:22:24,570 --> 00:22:29,190
+بدكم تعطوهم؟ Antibiotic، هي Acetaminophen، هي Acetaminophen،
+
+262
+00:22:29,190 --> 00:22:33,310
+الـ Acetaminophen هي Acetaminophen، واضح؟ بس لأن الولد الصغير ما
+
+263
+00:22:33,310 --> 00:22:40,910
+بيبلعش وما إلى ذلك فبتعطوه الـ Acetaminophen، ودائمًا 
+
+264
+00:22:40,910 --> 00:22:49,120
+biotic كلمة مرتبطة بالإيش بالحرارة، بيروليسي مثلًا
+
+265
+00:22:49,120 --> 00:22:55,900
+إيش معناه بيروليسي؟ بيروليسي 
+
+266
+00:22:55,900 --> 00:22:58,220
+التكسر بالحرارة
+
+267
+00:23:02,080 --> 00:23:06,440
+واضح؟ يمكن يمكن لاحظت أن بعض الناس أن بعض
+
+268
+00:23:06,440 --> 00:23:12,720
+الناس بيخربطوا بين كلمتين باللغة العربية فبيلفظوا
+
+269
+00:23:12,720 --> 00:23:19,720
+كلمة بغير ما يجب أن تلفظ به، فالجهاز بتاع الغواصة
+
+270
+00:23:19,720 --> 00:23:24,520
+الجهاز الغواصة اللي فيه مرايتين وبيشوفوا فيه من
+
+271
+00:23:24,520 --> 00:23:30,540
+الأعماق لفوق أو تحت، شو بيسموه؟ بالظبط هي الغلط أنك
+
+272
+00:23:30,540 --> 00:23:37,220
+تقول بيروسكوب، بيروسكوب، الـ Periscope جهاز قياس حرارة
+
+273
+00:23:37,220 --> 00:23:42,260
+ثاني، فلاحظوا أنتو بالعربي بتكتبوا زي هي بيروسكوب
+
+274
+00:23:42,260 --> 00:23:46,220
+تبع المرايات واللي بنشوف فيه اللي بنستعمله
+
+275
+00:23:46,220 --> 00:23:48,680
+بالغواصة والحرارة عارفينه اللي فيه مرايتين
+
+276
+00:23:48,680 --> 00:23:54,560
+متعاكسات، هذا Periscope، الـ Periscope جهاز ثاني له
+
+277
+00:23:54,560 --> 00:24:00,260
+علاقة بالحرارة بهمش، أنا ليش بنبّخ؟ على أساس أنه
+
+278
+00:24:00,260 --> 00:24:04,460
+أنتوا لما تقولوها ما تقولوش بيروسكوب، بيرو حراري،
+
+279
+00:24:04,460 --> 00:24:10,960
+Antibiotic مضاد للحرارة، إيش يعني fever reducer؟
+
+280
+00:24:10,960 --> 00:24:17,320
+إيش الـ fever؟ الحمى وقد توفي يا رسول الله صلى
+
+281
+00:24:17,320 --> 00:24:24,650
+الله عليه وسلم بالحمى ولا ما بتعرفوش الحكي؟ في
+
+282
+00:24:24,650 --> 00:24:29,710
+أمثلة إضافية وهي آخر الـ slide جزء من الـ
+
+283
+00:24:29,710 --> 00:24:35,510
+Pheromones، مرت عليكم كلمة Pheromones، الـ 
+
+284
+00:24:35,510 --> 00:24:41,830
+Pheromones بالعربي اللي هي خلينا نقول المنبهات هي
+
+285
+00:24:41,830 --> 00:24:47,190
+مواد منبهة تفرزها الحشرات للتواصل، أيًا كان نوع
+
+286
+00:24:47,190 --> 00:24:50,890
+التواصل، غالبًا اللي هو التواصل الجنسي بين الذكور
+
+287
+00:24:50,890 --> 00:24:56,010
+والإناث، بيفرزوا فرمونات وهذا يعني لاحظوا العلماء
+
+288
+00:24:56,010 --> 00:25:00,410
+لما بيفهموا أي شغلة سبحان الله بيعملولها إيش
+
+289
+00:25:00,410 --> 00:25:05,230
+ع طول؟ تطبيق بيعملوله تطبيق النمل نفسه لما
+
+290
+00:25:05,230 --> 00:25:08,870
+بيلتقي مع بعضه وكيف بيدل بعض على الطرق وما إلى
+
+291
+00:25:08,870 --> 00:25:12,910
+برضه بيفرز فرمونات الآن البني آدمين
+
+292
+00:25:12,910 --> 00:25:16,230
+معروفين ساكنين في دور بيعرفوا بعض أبو محمد والـ
+
+293
+00:25:16,230 --> 00:25:20,330
+الأخرى لكن أنتو تخيلوا الحشرات لما نكون احنا
+
+294
+00:25:20,330 --> 00:25:25,150
+بفضاء كبير واسع وفي نهاية الحشرات بدأوا يتم فيها
+
+295
+00:25:25,150 --> 00:25:29,110
+تزاوج وتايهين في بعض في الفضاء فبتلاقوا أحد الأصناف
+
+296
+00:25:29,110 --> 00:25:32,410
+سواء كان الذكور أو الإناث بيفرز روائح معينة بيحس
+
+297
+00:25:32,410 --> 00:25:35,930
+فيها الصنف الثاني الآن كيف بيئيًا استفادوا من هذه
+
+298
+00:25:35,930 --> 00:25:36,570
+الفكرة؟
+
+299
+00:25:39,030 --> 00:25:43,410
+بدل ما يجوا يقتلوا الحشرة بالرش حضروا الـ pheromones
+
+300
+00:25:43,410 --> 00:25:47,830
+كيميائيًا، هااي مثال لفيرومون مثلًا Isoamyl acetate،
+
+301
+00:25:47,830 --> 00:25:53,230
+بيسموه honey bee alarm منبه للنحل مثلًا أو هذا
+
+302
+00:25:53,230 --> 00:26:00,510
+لدودة معينة الـ pheromone بيجيب الجنس الآخر الآن هذه
+
+303
+00:26:00,510 --> 00:26:03,930
+المركبات حضروها في المختبر بعد ما حضروها كل اللي
+
+304
+00:26:03,930 --> 00:26:09,950
+بيلزمهم القاتل بيجيبوا عود بهذا الشكل بيحطوا عليه
+
+305
+00:26:09,950 --> 00:26:18,270
+صمغ وشوية Pheromone وبيحطوه بالحقل زي هيك بيجذب كل
+
+306
+00:26:18,270 --> 00:26:21,970
+الحشرات بتيجي إيش بتلازق بالصمغ لا برش مبيدات
+
+307
+00:26:21,970 --> 00:26:27,260
+حشرية ولا ما يحزنون شفتوا كيف؟ هذا بيسموها مكافحة
+
+308
+00:26:27,260 --> 00:26:33,020
+نظيفة أو حيوية أو بيئية بدل ما يرشوا الـ pesticides
+
+309
+00:26:33,020 --> 00:26:39,560
+اللي هي DDT وغيره ويكون فيها كلورين وفوسفور زي
+
+310
+00:26:39,560 --> 00:26:44,360
+الغازات المثيلة للدموع وإشي ما يقل يمكن عملنا
+
+311
+00:26:44,360 --> 00:26:48,930
+احنا محاضرة عن ال الغازات السامة وغيرها معظم
+
+312
+00:26:48,930 --> 00:26:52,850
+المبيدات الحشرية هي كلورينية في الغالب يعني فيها
+
+313
+00:26:52,850 --> 00:26:56,350
+كلور، فوسفورية فيها فوسفور، الآن هذه الطريقة
+
+314
+00:26:56,350 --> 00:27:02,090
+نسبياً تعتبر إيش؟ يعني أكثر صداقة خلينا نقول مع
+
+315
+00:27:02,090 --> 00:27:12,530
+البيئة، بهيك بننتهي من هذا الفصل بننتقل على طول
+
+316
+00:27:12,530 --> 00:27:18,980
+طبعًا الآن أنا بحاجة لكل دقيقة إلى الفصل الأخير اللي
+
+317
+00:27:18,980 --> 00:27:24,180
+هو الـ amines أنا مش عارف بالمناسبة يعني أنا بدرس
+
+318
+00:27:24,180 --> 00:27:28,680
+الـ organic للطب عادة بخلص الـ amines في الأسبوع
+
+319
+00:27:28,680 --> 00:27:32,540
+السابع وبياخدوا أربع فصول biochemistry زيادة
+
+320
+00:27:32,540 --> 00:27:38,360
+حوالي 150 صفحة لأ لأ مش أشطر منكوا والله لأ لأ
+
+321
+00:27:38,360 --> 00:27:40,700
+أنتوا كثير منكم بتجيب علامة كاملة وممكن منهم
+
+322
+00:27:40,700 --> 00:27:43,080
+اثنين بيجيبوا علامات كاملة والباقي ممكن يجيبوا
+
+323
+00:27:43,080 --> 00:27:48,320
+ستين وخمسين ويورّس وبذاك وذاك و
+
+324
+00:27:48,320 --> 00:27:51,040
+بعدين هم بتغلبوا سبع سنين وبيلاقوا الشغل أنتو
+
+325
+00:27:51,040 --> 00:27:55,920
+بعد أربع سنين بتلاقوا وظيفة الشيء
+
+326
+00:27:55,920 --> 00:28:00,200
+المؤكد أن كل خريجين طبعًا بالذات التخصصات التدرسية
+
+327
+00:28:00,200 --> 00:28:06,440
+كيمياء فيزياء هدول بيلاقوا وظائف تربّي علوم بتلاقي
+
+328
+00:28:06,440 --> 00:28:14,260
+وظائف تحاليل طبية أقل، الآن نجي على الموضوع
+
+329
+00:28:14,260 --> 00:28:19,640
+الجديد تبعنا الـ Amines، الـ Amines هم مشتقات،
+
+330
+00:28:19,640 --> 00:28:24,240
+انتبهوا معي، الـ Amines هم مشتقات الأمونيا يعني
+
+331
+00:28:24,240 --> 00:28:29,420
+أبسط من ناحية المبدأ كأنه أبسط مركب عنده الأمونيا
+
+332
+00:28:29,420 --> 00:28:35,450
+اللي هي الـ NH3 طبعًا الأمونيا ما بنعتبرهاش organic
+
+333
+00:28:35,450 --> 00:28:41,790
+compound لأن ما فيش فيها Carbon لكن ممكن أبدل H
+
+334
+00:28:41,790 --> 00:28:48,350
+واحدة منها بـ R يصير R NH2 ممكن أبدل اثنتين بـ R يصير
+
+335
+00:28:48,350 --> 00:28:53,530
+R2 NH ممكن أبدل ثلاث بـ R يصير R3 N وممكن
+
+336
+00:28:53,530 --> 00:28:58,950
+على زوج الإلكترونات اللي مازال موجود هون الآن في كل
+
+337
+00:28:58,950 --> 00:29:03,050
+الأحوال الـ Nitrogen عليها إيش؟ زوج من الإلكترونات
+
+338
+00:29:03,050 --> 00:29:06,210
+أحط الـ R الرابعة في هذه الحالة بتصير الـ Nitrogen
+
+339
+00:29:06,210 --> 00:29:10,910
+موجبة وبتاخد جنب أيون سالب فبيصير عندي الـ ammonia
+
+340
+00:29:10,910 --> 00:29:17,450
+الـ primary amine اللي فيه NH2، secondary amine
+
+341
+00:29:17,450 --> 00:29:22,490
+اللي فيه NH، tertiary amine اللي فيه N لحظة
+
+342
+00:29:22,490 --> 00:29:28,570
+quaternary amine، رباعي يعني يعني متصل بأربعة R اللي
+
+343
+00:29:28,570 --> 00:29:33,830
+فيه الـ N positive والـ amines أنتو عارفين أنه أساسية
+
+344
+00:29:33,830 --> 00:29:37,330
+في جسم الإنسان في البروتينات في الـ RNA في الـ DNA
+
+345
+00:29:37,330 --> 00:29:42,130
+يعني كل إشي في الـ biology بتلاقوا فيه دائمًا إيش
+
+346
+00:29:42,130 --> 00:29:47,870
+نيتروجين بتلاقوا فيه نيتروجين سواء أمين أو أميد في
+
+347
+00:29:47,870 --> 00:29:53,270
+الآخر بالمناسبة هو الـ amide زي ما احنا قلنا النيلون
+
+348
+00:29:55,700 --> 00:29:59,660
+unreactive، شو الـ amide الثاني اللي كثير مشهور
+
+349
+00:29:59,660 --> 00:30:02,840
+و unreactive
+
+350
+00:30:02,840 --> 00:30:11,340
+يعني بيغلب لما يتكسر أبدًا ليش تبعدوه؟ البروتينات 
+
+351
+00:30:11,340 --> 00:30:11,960
+اللحمة
+
+352
+00:30:14,400 --> 00:30:18,680
+البروتينات ليش بتغلب في الهضم وبدواء كثير وحامض
+
+353
+00:30:18,680 --> 00:30:24,540
+ولما تتكسر لأن البروتين هو عبارة عن amide البروتين
+
+354
+00:30:24,540 --> 00:30:29,920
+اللحمة، مين بيقدر ياكل اللحمة
+
+355
+00:30:29,920 --> 00:30:35,840
+في الليل الساعة 11 و12 وينام؟ عملية صعبة جدًا على
+
+356
+00:30:35,840 --> 00:30:42,180
+البني آدم لأنه في الهضم بتغلب، الـ Properties of
+
+357
+00:30:42,180 --> 00:30:46,340
+Amines كما تعرفون أن النيتروجين هو Atom electro
+
+358
+00:30:46,340 --> 00:30:50,860
+negative من الثلاثة المشهورين اللي بيعملوا
+
+359
+00:30:50,860 --> 00:30:55,340
+الهيدروجين bonding بناء على ذلك الـ amine بتعمل
+
+360
+00:30:55,340 --> 00:30:59,760
+هيدروجين bonding إذا كان فيها H لو كانت amine بدون
+
+361
+00:30:59,760 --> 00:31:04,280
+H خلاص بتبطل تعمل هيدروجين bonding، اللي فيها H
+
+362
+00:31:04,280 --> 00:31:08,860
+وبتعمل هيدروجين bonding بيصير فيها high boiling
+
+363
+00:31:08,860 --> 00:31:15,600
+points، فالـ amines هم
+
+364
+00:31:15,600 --> 00:31:21,180
+عبارة عن organic bases لأن دائمًا Nitrogen عليها
+
+365
+00:31:21,180 --> 00:31:23,180
+زوج الإلكترونات
+
+366
+00:31:26,270 --> 00:31:31,450
+Electron donor بتعطي إلكترونات فمن أهم الـ organic
+
+367
+00:31:31,450 --> 00:31:35,790
+bases اللي هي مركبات الـ Nitrogen، واضح؟ مركبات الـ
+
+368
+00:31:35,790 --> 00:31:39,690
+Nitrogen من أهم الـ organic bases حتى المركبات اللي
+
+369
+00:31:39,690 --> 00:31:43,230
+زي الـ Nicotine والكافيين وإشي بيسموهم الـ Alkaloids
+
+370
+00:31:43,230 --> 00:31:47,430
+الـ Alkaloids يعني القاعدين ليش هدول يعتبروا الـ Alkaloids
+
+371
+00:31:47,430 --> 00:31:52,930
+أو قاعدين لأن فيهم Nitrogen لما
+
+401
+00:34:38,560 --> 00:34:42,320
+لو كانت R بنسمي الـ R  أثيل أمينو واحدة بقى الآن مثل
+
+402
+00:34:42,320 --> 00:34:45,780
+two dimethylamino
+
+403
+00:34:50,640 --> 00:34:54,920
+واضح؟ إيش كان السؤال؟
+
+404
+00:34:54,920 --> 00:35:01,330
+لا طبعا قد إيش واحدة، ما هو ده شابك بحاجة ثانية هيوغ
+
+405
+00:35:01,330 --> 00:35:05,150
+زي هانا هذا شابك بحاجة ثانية أنا بحكي عنها كمجموعة
+
+406
+00:35:05,150 --> 00:35:11,110
+بمعنى أنها شابكة بشيء ثاني يعني افترض مرتبطة بخمس
+
+407
+00:35:11,110 --> 00:35:14,810
+كربونات، شو بدي يكون؟ one على موقع واحد، one
+
+408
+00:35:14,810 --> 00:35:19,910
+aminobentain، one methylaminobentain، one 
+
+409
+00:35:19,910 --> 00:35:24,490
+dimethylaminobentain، بهذا الشكل لأن هي هانا
+
+410
+00:35:24,490 --> 00:35:30,170
+كمجموعة، والمجموعة دائما إيش بتكون؟ بتكون ناقص واحد
+
+411
+00:35:30,170 --> 00:35:37,110
+لما كنت أقول الميثين جزء CH4 الميثل مجموعة بتنقص
+
+412
+00:35:37,110 --> 00:35:42,530
+واحد دائما المجموعة هاي عندي أمثلة هنا لو في عندي
+
+413
+00:35:42,530 --> 00:35:48,830
+مثلا تلت كربونات على الذرع الأول NH2 إيش بنقول؟
+
+414
+00:35:48,830 --> 00:35:56,670
+one aminoborben هناك two aminoborben هنا ست ذراتها
+
+415
+00:35:56,670 --> 00:36:03,900
+على موقع اثنين to a minor hexane طيب هاي هنا مثال
+
+416
+00:36:03,900 --> 00:36:08,020
+جديد لاحظوا هاي السلسلة دي واحد اثنين ثلاثة هي
+
+417
+00:36:08,020 --> 00:36:14,420
+الأطول ماذا تحمل مجموعة الأن مثل
+
+418
+00:36:18,240 --> 00:36:23,280
+أه اللي هي الـ مثل أمينو طبعا بنقدر نقول.. هلأ
+
+419
+00:36:23,280 --> 00:36:26,520
+بيسموه بطرف ثاني يعني ممكن يقول أ مثل و أمينو
+
+420
+00:36:26,520 --> 00:36:31,140
+بروبين والأسهل أنه يقول one زي ما توي حكينالكوا
+
+421
+00:36:31,140 --> 00:36:38,860
+إيش اسم المجموعة مثل أمينو بروبين زي هيك بيكون إيش
+
+422
+00:36:38,860 --> 00:36:44,460
+أسهل one إيش اسم المجموعة مثل أمينو
+
+423
+00:36:47,250 --> 00:36:51,490
+Dimethyl Amino جاي على وين؟ على الـ Cyclohexane
+
+424
+00:36:51,490 --> 00:36:56,310
+فبنقول Dimethyl Amino Cyclohexane لو حط من عنده NN
+
+425
+00:36:56,310 --> 00:37:01,450
+عارفين شو معناه؟ يعني أن الميثلز متصلة بنيتروجين
+
+426
+00:37:01,450 --> 00:37:05,490
+وقبل شوية حكينا عنها بالـ form amides إذا أنتم
+
+427
+00:37:05,490 --> 00:37:12,210
+متذكرين، مظبوط؟ إذا زي ما قلنا الـNH2 اسمها Amino
+
+428
+00:37:12,210 --> 00:37:23,590
+الـNH Methyl مثل أمينو والآن مثلها دايمثل أمينو هاي
+
+429
+00:37:23,590 --> 00:37:29,550
+عندي هنا كمان أمثلة إضافية بإمكانكوا تقرؤوها بوضوح
+
+430
+00:37:29,550 --> 00:37:34,330
+أو زي ما بدكم هاي هنا مثلا واحد اثنين ثلاثة على
+
+431
+00:37:34,330 --> 00:37:40,340
+موقع واحد واثنين عندكوا أمينو أمينو إيش بيكون؟ 1,2
+
+432
+00:37:40,340 --> 00:37:43,800
+-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1
+
+433
+00:37:43,800 --> 00:37:44,040
+,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl
+
+434
+00:37:44,040 --> 00:37:46,720
+-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2
+
+435
+00:37:46,720 --> 00:37:49,400
+-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1
+
+436
+00:37:49,400 --> 00:37:50,360
+-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2
+
+437
+00:37:50,360 --> 00:37:57,840
+-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1
+
+438
+00:37:57,840 --> 00:38:06,650
+,2-dimethyl-1,2-dimethyl- تو بيوتانول تو بيوتانول
+
+439
+00:38:06,650 --> 00:38:11,910
+هاي السلسلة الأساسية بيوتان بيوتانول تو بيوتانول
+
+440
+00:38:11,910 --> 00:38:21,850
+ثلاث أمينو ثلاث بثلاث واضح المركب اللي فوق لاحظوا
+
+441
+00:38:21,850 --> 00:38:27,230
+هذا ترد شري أمين هذا ترد شري أمين يمكن لو انفصلوا
+
+442
+00:38:27,230 --> 00:38:28,610
+بسهولة
+
+443
+00:38:35,490 --> 00:38:39,870
+هنا CH3 وهنا CH2 وهنا CH3 وهنا CH3 وهنا CH3 وهنا
+
+444
+00:38:39,870 --> 00:38:43,830
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+445
+00:38:43,830 --> 00:38:43,970
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+446
+00:38:43,970 --> 00:38:45,530
+وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا
+
+447
+00:38:45,530 --> 00:38:46,390
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+448
+00:38:46,390 --> 00:38:47,270
+وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا
+
+449
+00:38:47,270 --> 00:38:48,450
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+450
+00:38:48,450 --> 00:38:51,790
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+451
+00:38:51,790 --> 00:38:57,730
+وهنا CH3 للإيثيل هذا الإيثيل هاي واحد هاي اثنين إيش
+
+452
+00:38:57,730 --> 00:39:06,870
+موجود عليه على موقع واحد انظروا أن إيثيل أن مثل
+
+453
+00:39:06,870 --> 00:39:11,790
+كل هذه المجموعة هاي اسمها هذه كلها تعتبر مجموعة
+
+454
+00:39:11,790 --> 00:39:14,570
+إيش اسمها أن إيثيل أن مثل
+
+455
+00:39:18,680 --> 00:39:23,980
+هذه ليست أن ضاي إثل ولا ضاي مثل عليها إثل ومثل
+
+456
+00:39:23,980 --> 00:39:34,220
+كإنها إثل مثل أمينو أو أن إثل أن مثل أمينو إثل فهو
+
+457
+00:39:34,220 --> 00:39:39,700
+قال أن إثل وأن مثل والأمين هو المتصلة على موقع
+
+458
+00:39:39,700 --> 00:39:45,220
+واحد one amino ethyl لو قال مثلا one ethyl مثل
+
+459
+00:39:45,220 --> 00:39:52,610
+أمينو إثل برضه بيمشي يعني مرات بتلاقوا يعني شغلة
+
+460
+00:39:52,610 --> 00:39:56,130
+بسيطة في اسم التغيير بس ما في مشكلة يعني كل هذه
+
+461
+00:39:56,130 --> 00:40:01,570
+المجموعة اللي في الأزرق جاية على أي موقع واحد لو
+
+462
+00:40:01,570 --> 00:40:06,170
+كانت هذه unatched وشو كنت حاسب المركب one Amino
+
+463
+00:40:06,170 --> 00:40:16,570
+اثنى الأن هذه Amino ولا اثنى مثل Amino
+
+464
+00:40:17,710 --> 00:40:22,330
+يعني هاي هذي كلها وان اثل مثل اماي دي مجموعة وكله
+
+465
+00:40:22,330 --> 00:40:29,270
+جاي على وين على اثنين على موقع الواحد فلما تحللوا
+
+466
+00:40:29,270 --> 00:40:33,550
+أي اسم بتلاحظوا أن العملية أو التسمية ليست أمرا
+
+467
+00:40:33,550 --> 00:40:35,450
+صعبة
+
+468
+00:40:47,010 --> 00:40:53,450
+الآن الـ amino ممكن تكون على الـ aromatic الـ NH2 هذه
+
+469
+00:40:53,450 --> 00:40:57,830
+ممكن تكون على الـ aromatic المركب البنزيني اللي
+
+470
+00:40:57,830 --> 00:41:04,310
+عليه NH2 أخد اسم شهرة شو تسمى؟ أنيلين الأن لو صار
+
+471
+00:41:04,310 --> 00:41:10,290
+أنيلين مع طولوين يعني لو بس NH2 أنيلين لو بس مثل
+
+472
+00:41:10,290 --> 00:41:15,860
+طولوين طب لما ينخلطوا مع بعض؟ زي ما بنخلط الكيميا
+
+473
+00:41:15,860 --> 00:41:21,080
+بالفيزياء إيش بنقول physical chemistry أو
+
+474
+00:41:21,080 --> 00:41:26,520
+المغناطيسية بالكهربائية إيش بنقول electromagnetic
+
+475
+00:41:26,520 --> 00:41:33,100
+أو كهرومغناطيسية هنا خلطنا التلوين بالأنيلين فبسموه
+
+476
+00:41:33,100 --> 00:41:41,810
+طبعا هذا بارا بارا توليدين هنا أورثو توليدين ميتا
+
+477
+00:41:41,810 --> 00:41:46,750
+توليدين هؤلاء التولدين هم اللي جايين من خلطة
+
+478
+00:41:46,750 --> 00:41:52,130
+التلوين مع الأنيلين فبيسموهم
+
+479
+00:41:52,130 --> 00:41:58,850
+بهذا الشكل بارا توليدين أورثو توليدين وميتا توليدين
+
+480
+00:41:58,850 --> 00:42:02,750
+لسه ضايل عندنا بس الـ common names إن الله يحب
+
+481
+00:42:02,750 --> 00:42:08,930
+الصابرين إذا صبروا الآن لو إجينا قلنا الـ common
+
+482
+00:42:08,930 --> 00:42:09,670
+names
+
+483
+00:42:12,800 --> 00:42:17,860
+زي ما كنا نسمي في حالة الـ halogens يعني أنا بدي
+
+484
+00:42:17,860 --> 00:42:22,060
+أعطيكوا مثال عشان بس أنتو تشوفوا الموازنة لما كان
+
+485
+00:42:22,060 --> 00:42:30,740
+كنت عندي CH3Cl شو كنت اسمي أنا؟ أيوبك أو common؟
+
+486
+00:42:30,740 --> 00:42:35,860
+في الـ أيوبك كنت أقول الـ chloro مثين مثين يعني
+
+487
+00:42:35,860 --> 00:42:39,420
+الأصل اللي عندك مثين هذا أيوبك
+
+488
+00:42:41,940 --> 00:42:49,440
+أخذ هذه المجموعة ما اسمها مثل مثل كلوريد مثل
+
+489
+00:42:49,440 --> 00:42:53,960
+كلوريد الأن لو الكلام نفسه اتكرر عندي هذا common
+
+490
+00:42:53,960 --> 00:43:01,780
+name لو اتكرر عندي في الـ amine هذا أمينو مثل بالـ
+
+491
+00:43:01,780 --> 00:43:13,990
+أيوبك طب الـ common مثل أمين هذا دائما مثل أميل هدا
+
+492
+00:43:13,990 --> 00:43:19,190
+هي أميل وحمل إثل إثل أميل لو كنت بدي أقابل أيوبك
+
+493
+00:43:19,190 --> 00:43:29,270
+one aminoethane أو أمينو إثل هدا مثل إثلمثل أمين
+
+494
+00:43:29,270 --> 00:43:39,350
+مثل أمين
+
+495
+00:43:39,350 --> 00:43:44,910
+مثل أمين
+
+496
+00:43:44,910 --> 00:43:48,850
+مثل أمين مثل أمين مثل أمين مثل أمين مثل أمين مثل
+
+497
+00:43:48,850 --> 00:43:51,370
+أمين مثل أمين مثل أمين نفس الـ isopropyl هاي الـ
+
+498
+00:43:51,370 --> 00:43:55,790
+isopropyl كمجموعة وهاد الـ amine هاد الـ isopropyl
+
+499
+00:43:55,790 --> 00:43:59,050
+amine طب لو قلنا لو إحنا سمينا يا بالـ ayobac
+
+500
+00:43:59,050 --> 00:44:02,390
+مظبوط
+
+501
+00:44:02,390 --> 00:44:08,270
+two aminopropane زي تماما لو كنت بتقوله بالـ
+
+502
+00:44:08,270 --> 00:44:12,290
+chlorine isopropyl chloride بيكون حاطين هنا
+
+503
+00:44:12,290 --> 00:44:16,210
+chlorine بالـ ayobac two chloro
+
+504
+00:44:34,690 --> 00:44:42,400
+Tropanol تقريبا تقريبا ما خلصناش التسمية بتضل slide
+
+505
+00:44:42,400 --> 00:44:46,440
+عشان تراجعوا كل موضوع التسمية فلما نشرحها بتجمع
+
+506
+00:44:46,440 --> 00:44:50,840
+إيش كل الموضوع بنذكر في التسمية في أول المحاضرة
+
+507
+00:44:50,840 --> 00:44:58,180
+القادمة إن شاء الله لا لا إن شاء الله يمكن الـ ..
+
+508
+00:44:58,180 --> 00:45:02,660
+الاثنين آخر محاضرة أنتو لسه امتحانكوا الثلاثة
+
+509
+00:45:02,660 --> 00:45:03,460
+اللي بعده يعني
+
+510
+00:45:16,180 --> 00:45:16,460
+أه 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0.srt
new file mode 100644
index 0000000000000000000000000000000000000000..61839fa60e85083eb774628fb00e02cc3047ec00
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0.srt
@@ -0,0 +1,1858 @@
+1
+00:00:06,190 --> 00:00:09,570
+بسم الله الرحمن الرحيم، اليوم إن شاء الله بدنا 
+
+2
+00:00:09,570 --> 00:00:17,870
+نكمل في موضوع تفاعلات البنزين، المرة الماضية كل 
+
+3
+00:00:17,870 --> 00:00:23,830
+كلامنا كان عن حلقة بنزين غير مبدلة، unsubstituted، 
+
+4
+00:00:23,830 --> 00:00:27,680
+يعني ما فيش عليها ولا إشي وبنحط 
+
+5
+00:00:27,680 --> 00:00:32,560
+Substituent واحدة طبعاً في هذه الحالة اللي بتطلع 
+
+6
+00:00:32,560 --> 00:00:36,920
+على شكل حلقة البنزين المتماثل هيلاحظ أنه على أي 
+
+7
+00:00:36,920 --> 00:00:41,140
+موقع من المواقع الستة بنقدر نحط ال Substituent 
+
+8
+00:00:41,140 --> 00:00:46,020
+وبيطلع عندنا نفس الناتج طبعاً أخدنا طرق كتيرة 
+
+9
+00:00:46,020 --> 00:00:49,860
+لإضافة Substituents أخدنا Alkylation, Acylation, 
+
+10
+00:00:50,000 --> 00:00:55,720
+Halogenation, Nitration, Sulfonation وكل طريقة في 
+
+11
+00:00:55,720 --> 00:00:59,920
+إلها reagents معينة، خلاصة الموضوع إن ال reagents 
+
+12
+00:00:59,920 --> 00:01:06,300
+لازم في النهاية يتوفر إلي electrophile لازم يتوفر 
+
+13
+00:01:06,300 --> 00:01:12,100
+إلي إشي موجب عشان هذا الموجب يهاجم على حلقة 
+
+14
+00:01:12,100 --> 00:01:15,280
+البنزين هذا الموضوع ما فيش فيه خلاف، الآن إيش 
+
+15
+00:01:15,280 --> 00:01:20,700
+الجديد اليوم في الموضوع تبعنا؟ الجديد كالتالي أنه 
+
+16
+00:01:20,700 --> 00:01:27,000
+لو أنا كنت حاطط على ذرة البنزين مجموعة وبدأ أحط 
+
+17
+00:01:27,000 --> 00:01:32,520
+المجموعة الثانية بيصير عندي شغلتين بيصير عندي 
+
+18
+00:01:32,520 --> 00:01:36,460
+شغلتين الآن 
+
+19
+00:01:36,460 --> 00:01:41,420
+لما بدنا نعمل إضافة على حلقة بنزين في بالأساس 
+
+20
+00:01:41,420 --> 00:01:47,670
+عليها مجموعة وبدنا نضيف المجموعة الثانية سنلاحظ 
+
+21
+00:01:47,670 --> 00:01:53,150
+القادة أن المجموعة الأولى تتدخل في سرعة التفاعل 
+
+22
+00:01:53,150 --> 00:01:57,210
+بمعنى يمكن بسبب وجود المجموعة الأولى أن حلقة 
+
+23
+00:01:57,210 --> 00:02:04,430
+البنزين تتفاعل بسرعة تتفاعل بسرعة أبطأ في التفاعل 
+
+24
+00:02:04,430 --> 00:02:09,130
+إذا إليها تأثير متعلق بشيء بنسميه ال reactivity أو 
+
+25
+00:02:09,130 --> 00:02:14,790
+النشاط إذا هذه ال substituent الأولى في إليها إيش 
+
+26
+00:02:14,790 --> 00:02:20,650
+reactivity effect يعني يا بتزيد السرعة لإبدال 
+
+27
+00:02:20,650 --> 00:02:25,830
+المجموعة الثانية يا بتقلل السرعة واضح الشغل الثاني 
+
+28
+00:02:25,830 --> 00:02:31,800
+أن المجموعة الأولى بتكون أخدت موقع فاللي دائما 
+
+29
+00:02:31,800 --> 00:02:34,960
+موجود في الأول بيصير يتحكم في اللي بيجي بعد هيك 
+
+30
+00:02:34,960 --> 00:02:38,840
+اليوم .. يوم ما بده تيجي المجموعة الثانية هل هتيجي 
+
+31
+00:02:38,840 --> 00:02:41,780
+على الموقع المجاور إلها اللي هو بيكون بالنسبة إلها 
+
+32
+00:02:41,780 --> 00:02:45,780
+ortho ولا هتيجي على بعض موقع meta ولا هتيجي على 
+
+33
+00:02:45,780 --> 00:02:49,480
+الموقع اللي بعده para برضه المجموعة اللي موجودة 
+
+34
+00:02:49,480 --> 00:02:54,730
+بتتحكم إذا ..هنا صار عندي إشي جديد أنا مهتم فيه 
+
+35
+00:02:54,730 --> 00:02:59,570
+أنه وجود مجموعة أثر على شغلتين أثر على ال 
+
+36
+00:02:59,570 --> 00:03:04,090
+reactivity سرعة التفاعل و ال orientation ال 
+
+37
+00:03:04,090 --> 00:03:08,570
+orientation يعني وين يروح أو وين تروح المجموعة 
+
+38
+00:03:08,570 --> 00:03:12,890
+الثانية بالنسبة للمجموعة الأولى وهذا الكلام اللي 
+
+39
+00:03:12,890 --> 00:03:17,970
+إحنا بدنا ندرسه في التفصيل في محاضرة اليوم إيش 
+
+40
+00:03:17,970 --> 00:03:21,370
+التأثير بتاع المجموعة الأولى من ناحية reactivity 
+
+41
+00:03:21,370 --> 00:03:26,850
+ومن ناحية orientation إذا لو بدنا نسألكوا المجموعة 
+
+42
+00:03:26,850 --> 00:03:31,450
+أكم effect إلها ال reactivity تسريع أو تباطؤ 
+
+43
+00:03:31,450 --> 00:03:37,790
+orientation توجيه وين تروح المجموعة لجديدة الآن 
+
+44
+00:03:37,790 --> 00:03:45,050
+بالنسبة لل band الأول المجموعات حقيقة تتراوح ما 
+
+45
+00:03:45,050 --> 00:03:50,950
+بين مجموعات بتزيد سرعة التفاعل بتزيد ال reactivity 
+
+46
+00:03:50,950 --> 00:03:56,830
+بشكل كبير وبين مجموعات بتثبط سرعة التفاعل بشكل 
+
+47
+00:03:56,830 --> 00:04:02,890
+كبير وفي عندنا هنا زي ما بتلاحظوا scheme واضح 
+
+48
+00:04:02,890 --> 00:04:08,010
+بيوضح هذا الكلام يعني لو اتطلعتوا على أفضل 
+
+49
+00:04:08,010 --> 00:04:11,430
+المجموعات اللي بنزيد السرعة على التفاعل هتلاحظوا 
+
+50
+00:04:11,430 --> 00:04:15,910
+مجموعة الـ NH2 يعني لو كان عندكم أنيلين و بدنا 
+
+51
+00:04:15,910 --> 00:04:21,530
+نعمل عليه تفاعل ثاني التفاعل سريع جداً مجموعة الـ 
+
+52
+00:04:21,530 --> 00:04:28,760
+OH اللي هو لو كان عندكم Phenol البنزين .. الـ 
+
+53
+00:04:28,760 --> 00:04:33,220
+Phenol نشيط جداً في التفاعل لو كان عندكم مجموعة 
+
+54
+00:04:33,220 --> 00:04:38,040
+الـ OCH3 البنزين اللي عليه OCH3 اسمه أنيزول 
+
+55
+00:04:38,040 --> 00:04:43,700
+الانيزول سريع جداً في التفاعل لو كان في عندكم 
+
+56
+00:04:43,700 --> 00:04:50,040
+مجموعة الميثل CH3 الطلوين سريع جدا في التفاعل لو 
+
+57
+00:04:50,040 --> 00:04:57,260
+كان عندكم N H عليها OCH3 برضه تعتبر من السريعة و 
+
+58
+00:04:57,260 --> 00:05:00,200
+بالمناسبة الترتيب اللي موجود هنا برضه بيعني أن 
+
+59
+00:05:00,200 --> 00:05:03,520
+واحدة أسرع من الثانية يعني إذا بتلاحظوا ال O H 
+
+60
+00:05:04,410 --> 00:05:10,210
+بتسرع أكثر من الميثل مثلاً واضح أو ال N H2 أكثر من 
+
+61
+00:05:10,210 --> 00:05:16,930
+ال OCH3 ال H اللي هو البنزين العادي تعتبر حالة وسط 
+
+62
+00:05:16,930 --> 00:05:21,550
+في السرعة الآن من أبطأ الشغلات اللي بتوجهنا ال 
+
+63
+00:05:21,550 --> 00:05:27,170
+Nitro النيترو بنزين بيكون يعني generally 
+
+64
+00:05:27,170 --> 00:05:33,150
+unreactive، التفاعل إيش ماله؟ بطيء كتير طبعاً زيه 
+
+65
+00:05:33,150 --> 00:05:37,730
+ال sulpholic acid و زيه ال COOH و ال CWBOR و ال 
+
+66
+00:05:37,730 --> 00:05:41,770
+cyano و ال CHO اللي هي CWBOH ال aldehyde و ال 
+
+67
+00:05:41,770 --> 00:05:46,210
+halogens كل هدولة من ناحية المبدأ في ال reactivity 
+
+68
+00:05:46,210 --> 00:05:51,390
+أقل من إيش؟ أقل من البنزين، إذا أنا حد المقارنة 
+
+69
+00:05:51,390 --> 00:05:54,710
+اللي عندي هو إيش؟ البنزين ال substitute اللي 
+
+70
+00:05:54,710 --> 00:06:00,250
+موجودة فيه هي ال H، في أشياء أسرع من البنزين في 
+
+71
+00:06:00,250 --> 00:06:03,810
+أشياء أبطأ من البنزين، اللي مشهور في الأسرع من 
+
+72
+00:06:03,810 --> 00:06:09,730
+البنزين الانيلين، الفينول، الطولوين، الانيزول، 
+
+73
+00:06:09,730 --> 00:06:14,110
+اللي أبطأ من البنزين بشوية صغيرة الهالوجينز، فلورو 
+
+74
+00:06:14,110 --> 00:06:18,870
+كلوري بروم، اللي أبطأ من البنزين كتير كتير الـ 
+
+75
+00:06:18,870 --> 00:06:23,250
+Nitro و ال Cyano يعني كأنه من أبطأ الأشياء في 
+
+76
+00:06:23,250 --> 00:06:29,230
+التفاعلات الـ Nitro و ال Cyano واضح؟ هذا بالنسبة 
+
+77
+00:06:29,230 --> 00:06:33,470
+للمجموعات إذا كأننا قسمنا المجموعات إلى strongly 
+
+78
+00:06:33,470 --> 00:06:38,550
+activating groups يعني منشطة بشكل كبير و strongly 
+
+79
+00:06:38,550 --> 00:06:46,130
+deactivating group مثبطة لسرعة التفاعل بشكل كبير 
+
+80
+00:06:49,150 --> 00:06:55,330
+الآن بنجي لعامل الثاني اللي حكينا عنه اللي هو الـ 
+
+81
+00:06:55,330 --> 00:07:00,890
+Orientation، واضح؟ إذا بنطلع على نفس المجموعات، 
+
+82
+00:07:00,890 --> 00:07:06,170
+لاحظوا كالتالي، إنه بشكل عام المجموعات اللي بتكون 
+
+83
+00:07:06,170 --> 00:07:09,490
+activating .. المجموعات اللي بتكون activating 
+
+84
+00:07:09,490 --> 00:07:14,270
+بتوجه المجموعات القادمة على موقع Ortho Para 
+
+85
+00:07:14,270 --> 00:07:21,050
+فبنسميها Ortho Para Directing Groups يعني مجموعات 
+
+86
+00:07:21,050 --> 00:07:25,050
+لما تيجي مجموعة جديدة بتخليها وين تروح على موقع 
+
+87
+00:07:25,050 --> 00:07:29,430
+Ortho وموقع Para بيصير خليط عندي يعني لو افترضت 
+
+88
+00:07:29,430 --> 00:07:34,650
+مثلاً عندي 100 جزء بتفاعلوا ممكن 60 منهم 100 جزء 
+
+89
+00:07:34,650 --> 00:07:39,230
+Phenol وقاعد بعمل عليهم مثلاً Nitrogen ممكن 60 جزء 
+
+90
+00:07:39,230 --> 00:07:43,110
+ييجي ال Nitro فيهم على موقع Ortho ممكن 40 جزء ييجي 
+
+91
+00:07:43,110 --> 00:07:47,710
+ال Nitro فيهم على موقع Para يعني بيطلع عندي خليط 
+
+92
+00:07:47,710 --> 00:07:51,810
+من النواتج مش على مش على نفس الجزء بيجي على 
+
+93
+00:07:51,810 --> 00:07:55,410
+ortho para لأ ما أنا مش جزء واحد اللي بفعله أنا 
+
+94
+00:07:55,410 --> 00:07:59,770
+بفعل ملايين الجزيات يعني لو كنت بفعل one mole مثلاً 
+
+95
+00:07:59,770 --> 00:08:03,170
+بكون بفعل six point oh two two في عشر أوس تلاتة 
+
+96
+00:08:03,170 --> 00:08:09,990
+وعشرين عدد avocado فجزء منهم بيتفعل على ال ortho و 
+
+97
+00:08:09,990 --> 00:08:16,130
+جزء منهم بتفعل وين؟ على ال para position فالقاعدة 
+
+98
+00:08:16,130 --> 00:08:20,330
+بشكلها العام أن ال activating groups they are 
+
+99
+00:08:20,330 --> 00:08:25,410
+generally ortho and para directing groups الآن ال 
+
+100
+00:08:25,410 --> 00:08:28,770
+deactivating groups they are generally meta 
+
+101
+00:08:28,770 --> 00:08:32,070
+directing groups يعني بيخلوا المجموعة الجديدة وين 
+
+102
+00:08:32,070 --> 00:08:38,350
+تروح؟ على موقع meta بيجينا شغلة أن في النص 
+
+103
+00:08:42,090 --> 00:08:45,250
+الهالوجينز الهالوجينز قبل شوية إيش قلنا عنهم إحنا 
+
+104
+00:08:45,250 --> 00:08:48,650
+طالما أنهم أقل من الهيدروجين activating ولا 
+
+105
+00:08:48,650 --> 00:08:52,450
+deactivating؟ deactivating لكن بيكونوا 
+
+106
+00:08:52,450 --> 00:08:58,110
+ortho para directing groups واضح؟ إذا بشكل عام ال 
+
+107
+00:08:58,110 --> 00:09:03,410
+activating groups أورثو بارا ال deactivating ميتا 
+
+108
+00:09:03,410 --> 00:09:08,390
+ما عدا ال halogens they are deactivating groups 
+
+109
+00:09:08,390 --> 00:09:13,390
+however أورثو بارا directing groups واضح؟ هذه 
+
+110
+00:09:13,390 --> 00:09:18,130
+أشياء طبعاً بنحصل عليها وعرفوها بالتجربة بعدين 
+
+111
+00:09:18,130 --> 00:09:21,310
+بيحاولوا يعملوا تفسير على إن و الرأس لكن الأساس 
+
+112
+00:09:21,310 --> 00:09:28,650
+فيها التجربة الأساس فيها التجربة، واضح؟ هذا اللي هو 
+
+113
+00:09:28,650 --> 00:09:34,050
+تأثير الـ Substituent من ناحية الـ activity و من 
+
+114
+00:09:34,050 --> 00:09:39,250
+ناحية الـ orientation من ناحية الـ activity و من 
+
+115
+00:09:39,250 --> 00:09:44,850
+ناحية الـ orientation الآن ممكن نحاول نعطي تفسيرات 
+
+116
+00:09:44,850 --> 00:09:51,460
+في الأساس إحنا قلنا الـ activity من وين عرفناها من 
+
+117
+00:09:51,460 --> 00:09:56,980
+التجربة لكن بعد هيك بنقدر نحاول نعمل تفسير يعني 
+
+118
+00:09:56,980 --> 00:10:03,340
+مثلاً الميثيلي جروب أو activating ليش يا ترى 
+
+119
+00:10:03,340 --> 00:10:10,880
+الميثيلي جروب بيودي على موقع أورثو بارا مش على موقع 
+
+120
+00:10:10,880 --> 00:10:16,260
+ميتا لما بدنا نيجي نعمل هذا الكلام بنيجي بنتخيل 
+
+121
+00:10:16,260 --> 00:10:21,140
+مثلاً بنقول خلينا ندرس الموقع بارا بنيجي بنحط 
+
+122
+00:10:21,140 --> 00:10:24,900
+الكتروفايل على الموقع بارا هاي الميثيل واحد اثنين 
+
+123
+00:10:24,900 --> 00:10:28,960
+ثلاثة واحد اثنين ثلاثة أربعة له موقع أربعة بالنسبة 
+
+124
+00:10:28,960 --> 00:10:34,240
+للميثيل أو هاي ال ortho ميتا هاي ال para بالنسبة له 
+
+125
+00:10:34,240 --> 00:10:39,400
+بنحط ال electro file هنا و بنشوف إيش اللي بينشق 
+
+126
+00:10:39,400 --> 00:10:43,080
+عندنا بنحط ال electro file مجرد ما حطينا ال 
+
+127
+00:10:43,080 --> 00:10:49,420
+electro file هنا حيصير في عندنا positive على هذا 
+
+128
+00:10:49,420 --> 00:10:54,760
+الموقع الآن هذا ال positive بيعمل resonance ولا لأ 
+
+129
+00:10:54,760 --> 00:10:58,220
+بيعمل resonance بمعنى أن هذه ممكن تتحرك تصير ال 
+
+130
+00:10:58,220 --> 00:11:03,620
+positive على هذا الموقع وهذا كمان بيعمل resonance 
+
+131
+00:11:03,620 --> 00:11:07,500
+ممكن تصير هنا إذا زي ما بتلاحظوا أن ال positive 
+
+132
+00:11:07,500 --> 00:11:16,380
+بيكون بينقل واضح delocalized يعني مش مثبت مش متمركز 
+
+133
+00:11:16,380 --> 00:11:19,560
+في موقع واحد، مين تقول هانه هانه هانه إذا أنا 
+
+134
+00:11:19,560 --> 00:11:23,340
+بتطلع .. إذا أنا بتطلع عليهم، بلاحظ إنه أحد 
+
+135
+00:11:23,340 --> 00:11:26,600
+الأشكال، يعني لو بدأ أشوف هذا ال carbocation هنا 
+
+136
+00:11:26,600 --> 00:11:30,100
+secondary carbocation لو بدأ أشوف هذا ال 
+
+137
+00:11:30,100 --> 00:11:35,930
+carbocation still secondary لو بدأ أشوف هذا الكاربو 
+
+138
+00:11:35,930 --> 00:11:40,850
+كاتيون tertiary لأن أحد ال resonance structures 
+
+139
+00:11:40,850 --> 00:11:46,290
+اللي عملها tertiary بفضل هذا الموقع طبعاً اللي بدو 
+
+140
+00:11:46,290 --> 00:11:51,510
+يصير أن أنتو بعد هيك لو اجيتوا عملتوا على الميتا 
+
+141
+00:11:51,510 --> 00:11:55,150
+هتلاحظوا أن مش هيكون في واحد tertiary 
+
+142
+00:11:58,080 --> 00:12:03,500
+عشان تكونوا متأكدين مثل هذه الرسمة تلت مرات تحطوا 
+
+143
+00:12:03,500 --> 00:12:08,780
+ال Electrophile على ال Ortho تحطوه على ال Meta 
+
+144
+00:12:08,780 --> 00:12:14,520
+تحطوه على ال Para هتلاحظوا أن في حالة ال Ortho و 
+
+145
+00:12:14,520 --> 00:12:18,320
+في حالة ال Para أحد ال structures ال resonance 
+
+146
+00:12:18,320 --> 00:12:21,540
+structures very stable هذا اللي بيشجع أن يروح على 
+
+147
+00:12:21,540 --> 00:12:24,820
+ال Ortho و ال Para في حالة ال Meta هتلاحظوا أن 
+
+148
+00:12:24,820 --> 00:12:31,030
+ما فيش شيء carbocation tertiary فالآن أي توجه بيكون 
+
+149
+00:12:31,030 --> 00:12:36,070
+أحد أطرافه اللي بيعمله contribution يعني بيدخلوا 
+
+150
+00:12:36,070 --> 00:12:39,630
+في ال resonance tertiary بيكون مفضل أن هو اللي 
+
+151
+00:12:39,630 --> 00:12:44,270
+بيقدي ال tertiary عندي البارا و ال اورثو لو عملته 
+
+152
+00:12:44,270 --> 00:12:47,650
+لو روحتوا عملتوا الميتا في البيت هيك زي واجب 
+
+153
+00:12:47,650 --> 00:12:51,150
+homework حطيتوا على الميتا H و electrophile و عملتوا 
+
+154
+00:12:51,150 --> 00:12:54,510
+بوستفانو نجلته و نجلته و نجلته هتلاحظوا أن مش هيجي 
+
+155
+00:12:54,510 --> 00:13:02,030
+على ال tertiary واضح فسبب التفضيل لل ortho و ال para 
+
+156
+00:13:02,030 --> 00:13:07,110
+positions هنا أن بيكون أحد ال resonance 
+
+157
+00:13:07,110 --> 00:13:12,010
+structures لل carbocation the stable tertiary 
+
+158
+00:13:12,010 --> 00:13:19,520
+carbocation واضح لاحظوا كم عملية الثبات عملية مهمة، 
+
+159
+00:13:19,520 --> 00:13:24,040
+واضح؟ كل الناس بتسأل إيش؟ للثبات التفاعل نتيجته 
+
+160
+00:13:24,040 --> 00:13:28,140
+الآن بإيش محكومة؟ بالثبات وجود أحد ال resonance 
+
+161
+00:13:28,140 --> 00:13:31,200
+structures، tertiary هو اللي بيخلي التفاعل يروح 
+
+162
+00:13:31,200 --> 00:13:38,540
+على ال ortho و ال para positions الآن لو اجينا 
+
+163
+00:13:38,540 --> 00:13:43,400
+عملنا تجربة نشوف النتائج لو اجينا عملنا تجربة نشوف 
+
+164
+00:13:43,400 --> 00:13:48,820
+النتائج بالظبط مثلاً لو أخدنا الطلوين الطلوين 
+
+165
+00:13:48,820 --> 00:13:55,820
+اتفقنا أن ortho para directing ال methyl group 
+
+166
+00:13:55,820 --> 00:13:59,400
+ortho para directing group بناء على ذلك لو اجينا 
+
+167
+00:13:59,400 --> 00:14:04,950
+عملنا nitration ال nitro وين هتروح؟ يا إما على الـ 
+
+168
+00:14:04,950 --> 00:14:10,230
+Ortho يا إما على الـ Para نشوف نتائج واقعية كيف 
+
+169
+00:14:10,230 --> 00:14:15,670
+طلعت بالتجربة بالظبط لما عملوا هذا التفاعل لاحظوا 
+
+170
+00:14:15,670 --> 00:14:22,610
+أنه 63% من الناتج أجت الـ Nitrofy على الـ 
+
+171
+00:14:22,610 --> 00:14:29,110
+Ortho position و 34% من الناتج أجت الـ Nitrofy على 
+
+172
+00:14:29,110 --> 00:14:35,210
+الـ Para position و فقط 3% من الناتج اللي بنعتبره 
+
+173
+00:14:35,210 --> 00:14:41,530
+إيش يعني negligible مهمل أجت فيه على الميتا واضح؟ 
+
+174
+00:14:42,410 --> 00:14:47,770
+أجت فيه علمية لاحظوا هنا بتكونوا برضه دقيقين بفهم 
+
+175
+00:1
+
+201
+00:16:56,170 --> 00:17:00,650
+بنجي بنحكي إنه هذا التفاعل بيعطينا الـ meta
+
+202
+00:17:00,650 --> 00:17:05,170
+product أو الـ ortho وزاد الـ para product بنقول as
+
+203
+00:17:05,170 --> 00:17:10,090
+major products كلمة major products بتختلف عن
+
+204
+00:17:10,090 --> 00:17:14,830
+exclusive products exclusive يعني حصري يعني ما فيش
+
+205
+00:17:14,830 --> 00:17:20,070
+ نهائيًا غيره أنا هنا ما بقولش exclusive بشكل مطلق
+
+206
+00:17:20,070 --> 00:17:26,820
+أنا بقول بشكل عام واضح؟ زي ما بنقول بشكل عام،
+
+207
+00:17:26,820 --> 00:17:32,440
+المسلم لا يغضب المسلم بشكل عام، بس حد بيقدر يقول
+
+208
+00:17:32,440 --> 00:17:38,140
+إنه هذا بشكل حصري؟ لأ، بشكل عام، بشكل عام التفاعل
+
+209
+00:17:38,140 --> 00:17:44,480
+مايله في حالة وجود الـ cyano group هذا ممنوعش إنه في
+
+210
+00:17:44,480 --> 00:17:50,900
+أشياء ثانية بتصير شديد عن القاعدة الآن
+
+211
+00:17:53,540 --> 00:17:57,920
+هكذا أصبح نوعًا ما واضح لدي أنه لو كان في عندي
+
+212
+00:17:57,920 --> 00:18:01,920
+مجموعة .. لو كان في عندي مجموعة، كيف تأثيرها؟ من
+
+213
+00:18:01,920 --> 00:18:06,980
+ناحية الـ reactivity ومن ناحية الـ orientation؟
+
+214
+00:18:06,980 --> 00:18:12,320
+الآن، يا تُرى، لو كان في مجموعتين، مش مجموعة
+
+215
+00:18:12,320 --> 00:18:19,680
+واحدة، وبدأ تيجي التالتة، بيصير في إيش؟ نوع من
+
+216
+00:18:19,680 --> 00:18:25,040
+التنافس لو في عندي مجموعتين وبدأ تيجي التالتة
+
+217
+00:18:25,040 --> 00:18:30,200
+بيصير في عندي نوعًا ما نوع من التنافس خلينا نأخذ 
+
+218
+00:18:30,200 --> 00:18:37,280
+بعض الأمثلة الآن اتطلع عندي هنا الـ CH3 والـ OCH3
+
+219
+00:18:37,280 --> 00:18:41,780
+نفترض هذا الجزء موجود ما لناش فيه كيف يتكون مش صعب
+
+220
+00:18:41,780 --> 00:18:48,460
+يتكون واضح؟ لو بدأت أقول لكم السؤال يا تُرى كيف هذا
+
+221
+00:18:48,460 --> 00:18:54,020
+الجزء ممكن يكون تكون؟ إيش أفضل طريقة عشان إحنا
+
+222
+00:18:54,020 --> 00:18:59,320
+نصنعه مبتدئين من البنزين؟
+
+223
+00:18:59,320 --> 00:19:05,260
+ارجعولي لنقطة، مين more activating؟
+
+224
+00:19:05,260 --> 00:19:12,660
+بنرجع وبنفرجيكوا إياها على الشاشة الـ OCH3 more
+
+225
+00:19:12,660 --> 00:19:19,700
+activating than CH3 واضح؟ بتعمل activation أكثر
+
+226
+00:19:19,700 --> 00:19:25,160
+بناءً على ذلك لو أنا بدي أبدأ ببنزين إذا حطيت الـ
+
+227
+00:19:25,160 --> 00:19:29,840
+OCH3 وبعدين بدي أكمل التفاعل أعمل methylation
+
+228
+00:19:29,840 --> 00:19:33,700
+هتيجي المثل على الـ ortho والـ para position باخد
+
+229
+00:19:33,700 --> 00:19:37,180
+مركب الـ para اللي أنا مهتم فيه ولو حطيت المثل
+
+230
+00:19:37,180 --> 00:19:42,330
+group وبدي أضيف الـ O مثل برضه هتيجي على الـ ortho والـ
+
+231
+00:19:42,330 --> 00:19:47,490
+para لكن أنا ولا أصح أن أعملُه أن أبدأ بطولين
+
+232
+00:19:47,490 --> 00:19:48,830
+ولا أبدأ
+
+233
+00:19:52,350 --> 00:19:59,250
+بالـ OCH3 لأن الـ OCH3 more activating واضح؟ تفاعلها
+
+234
+00:19:59,250 --> 00:20:04,290
+بيكون إيش أسرع الآن هذا مش شغلنا كيف حضروا هذا
+
+235
+00:20:04,290 --> 00:20:07,370
+الجزء إحنا شغلنا كيف هذا الجزء بدنا نعمل عليه
+
+236
+00:20:07,370 --> 00:20:13,040
+تفاعل إضافي مثلًا بدنا نفعلُه مع البروميين الـ مثل
+
+237
+00:20:13,040 --> 00:20:17,680
+group ortho para directing group الـ para تبعها مسكر
+
+238
+00:20:17,680 --> 00:20:24,760
+إيش بيضل لها الـ ortho والـ o مثل ortho para
+
+239
+00:20:24,760 --> 00:20:29,160
+directing group الـ para مسكر إيش بيضل لها الـ ortho
+
+240
+00:20:29,160 --> 00:20:32,540
+position اللي جنبها هنا طيب لو إجينا ضفنا
+
+241
+00:20:32,540 --> 00:20:36,860
+البرومية وين بده يروح التفاعل؟ بده ييجي على الـ
+
+242
+00:20:36,860 --> 00:20:41,920
+ortho تبع الـ مثل ولا على الـ ortho تبع الـ O مثل اه
+
+243
+00:20:41,920 --> 00:20:47,660
+هنا الأقوى بتغلب مين more activating الـ OCH3
+
+244
+00:20:47,660 --> 00:20:52,260
+عشانيك بلاحظ إن البروم بيجي هنا مش على هذا الموقع
+
+245
+00:20:54,000 --> 00:20:58,340
+واضح؟ بهمش، هو بيكون ortho بالنسبة للـ CH3 لكن ليش
+
+246
+00:20:58,340 --> 00:21:03,520
+ما بيجيش ortho للـ CH3؟ لأنه مثل أسرع وmore active
+
+247
+00:21:03,520 --> 00:21:09,160
+بالتفاعل، أنه أول ما ييجي لبروم، بيروح ياخذوا على الـ
+
+248
+00:21:09,160 --> 00:21:13,660
+ortho بالنسبة له إذا هنا اللي حكم نتيجة التفاعل الـ
+
+249
+00:21:13,660 --> 00:21:17,880
+activating جداش هذا activating جداش هذا activating
+
+250
+00:21:17,880 --> 00:21:23,180
+واضح اللي هو الـ reactivity النسبية relative
+
+251
+00:21:23,180 --> 00:21:27,920
+reactivity of both the O-methyl group and the CH3
+
+252
+00:21:27,920 --> 00:21:32,730
+group O-methyl group is more activating than الـ
+
+253
+00:21:32,730 --> 00:21:36,930
+CH3 group عشان هيك الناتج تبعها اتغلب على الناتج
+
+254
+00:21:36,930 --> 00:21:42,970
+تبع الـ CH3 واضح؟
+
+255
+00:21:42,970 --> 00:21:49,810
+هي هنا بيجي عندنا مثال ثاني عندنا مجموعتين وبدنا
+
+256
+00:21:49,810 --> 00:21:57,040
+نحط التالتة عندنا إيش؟ مجموعتين وبدنا نحط التالتة
+
+257
+00:21:57,040 --> 00:22:02,400
+الآن هالمجموعتين اللي عندياهم أنا المثل .. المثل
+
+258
+00:22:02,400 --> 00:22:08,040
+وين بتودي؟ على الـ ortho .. البرة بتبقى همسكتع
+
+259
+00:22:08,040 --> 00:22:12,200
+الـ ortho والنيترو وين بتودي؟ على الـ meta الآن
+
+260
+00:22:12,200 --> 00:22:16,440
+لاحظوا معنى الـ meta تبع النيترو هو نفس الـ ortho
+
+261
+00:22:16,440 --> 00:22:19,540
+تبع الـ methyl يعني كأنه صار عندي بس الـ tintel
+
+262
+00:22:19,540 --> 00:22:22,920
+بوجهه على هذا الموقع هذا الموقع نهائي اللي ما فيش
+
+263
+00:22:22,920 --> 00:22:30,550
+إشي بيودي عليه واضح؟ الآن O2 بتودع على الـ meta
+
+264
+00:22:30,550 --> 00:22:35,050
+بالنسبة لها هاي الـ meta one two three بتودع موقع
+
+265
+00:22:35,050 --> 00:22:39,550
+ثلاثة بالنسبة لها والمثل بتودع على موقع اثنين
+
+266
+00:22:39,550 --> 00:22:43,730
+بالنسبة لها ortho إذا كأنه المجموعتين بيودوا على
+
+267
+00:22:43,730 --> 00:22:49,910
+نفس الموقع عشانيك بيصير عندي مجموعة النيترو الجديدة
+
+268
+00:22:49,910 --> 00:22:54,050
+هذه بتيجي على هذا الموقع ولو كان عندنا النيترو
+
+269
+00:22:54,050 --> 00:22:58,930
+كثير بتيجي اللي بعدها كمان على هذا الموقع، على
+
+270
+00:22:58,930 --> 00:23:01,830
+الموقع الثاني، يعني بيصير مرتين نيتراشن، بيصير
+
+271
+00:23:01,830 --> 00:23:08,390
+عندي الـ Trinitro تلوين اللي هو الـ explosive TNT
+
+272
+00:23:08,390 --> 00:23:16,090
+المادة المتفجرة اللي بيسموها TNT، واضح؟
+
+273
+00:23:16,090 --> 00:23:24,210
+شفتوا كيف تجميع التأثيرات؟ يعني كأنه اتفقت مصالح
+
+274
+00:23:24,210 --> 00:23:30,940
+الـ Nitro والمثل على هذا الموقع زي ما بيصير تمامًا
+
+275
+00:23:30,940 --> 00:23:38,320
+في السياسة هاي في عندنا كمان مثال ممتعة هذه
+
+276
+00:23:38,320 --> 00:23:41,900
+الأمثلة لإيه؟ لإنه بتفرجيكوا واقع الدنيا كيف
+
+277
+00:23:41,900 --> 00:23:47,660
+المصالح بتتفق كيف التنافس بيصير في عندكم مثل
+
+278
+00:23:47,660 --> 00:23:49,040
+و chlor
+
+279
+00:23:51,960 --> 00:23:57,640
+الآن الميثل اكتفاط الكلور دي مش مشكلة مشكلتي أنا
+
+280
+00:23:57,640 --> 00:24:02,940
+في الـ orientation وين بيودي الميثل وين بيودي
+
+281
+00:24:02,940 --> 00:24:08,140
+الكلور الآن الميثل الأحمر بيودي على موقع ortho يعني
+
+282
+00:24:08,140 --> 00:24:13,470
+هذا الموقع أو هذا الموقع أو para ortho أو para يعني
+
+283
+00:24:13,470 --> 00:24:16,610
+المثل ممكن يحط حسب اللون تبعه زي ما أنتم شايفين
+
+284
+00:24:16,610 --> 00:24:21,270
+ortho ortho أو para يعني هذا الموقع متاح له هذا
+
+285
+00:24:21,270 --> 00:24:26,790
+الموقع متاح له هذا الموقع متاح له الكلور وين بيودي
+
+286
+00:24:26,790 --> 00:24:30,730
+بالنسبة له بيودع الـ ortho وين الـ ortho تبع الكلور
+
+287
+00:24:30,730 --> 00:24:37,710
+هذا وهذا هاي واحد اثنين واحد الاثنين والـ para اللي
+
+288
+00:24:37,710 --> 00:24:42,550
+هنا إذا مرة ثانية اتحدوا في الثلاثة موادع يعني
+
+289
+00:24:42,550 --> 00:24:48,050
+الميثل والكلور بيواجهوا على الثلاثة مواقع طيب خلينا
+
+290
+00:24:48,050 --> 00:24:54,770
+نشوف إيش نتيجة التجربة نشوف إيش نتيجة التجربة
+
+291
+00:24:54,770 --> 00:25:04,290
+الموقع هذا بيجي عليه كلور واضح؟ شايفينه؟ والموقع
+
+292
+00:25:05,470 --> 00:25:13,650
+هذا بيجي عليه chlorine والموقع هذا إيش مكتوب
+
+293
+00:25:13,650 --> 00:25:19,010
+عندكم الـ product not observed ما بينش عليه chlorine
+
+294
+00:25:19,010 --> 00:25:23,770
+رغم إنه نظريًا هنا وهنا وهنا متوقع ييجي الـ
+
+295
+00:25:23,770 --> 00:25:28,430
+chlorine بس عمليًا بيجي هنا وبيجي هنا ما بيجيش هنا
+
+296
+00:25:28,430 --> 00:25:34,030
+الآن لو قلنا لواحدة منكم ليش طيب تتوقع هذا الكلام
+
+297
+00:25:34,030 --> 00:25:34,450
+يصير؟
+
+298
+00:25:38,680 --> 00:25:43,340
+بيكون ازدحام ازدحام تنسواش إن كل الـ Geometry لما
+
+299
+00:25:43,340 --> 00:25:47,800
+درستوها في الكيمياء كانت مرتبطة بأي موضوع بالازدحام
+
+300
+00:25:47,800 --> 00:25:51,460
+لما كان يكون عندكم ثلاث ذرات ليش كنتوا تعملوا الجزء
+
+301
+00:25:51,460 --> 00:25:57,860
+linear؟ عشان تخلوا الزاوية 180 فالجزيئات بتشرط من
+
+302
+00:25:57,860 --> 00:26:02,920
+الازدحام الآن المجموعة اللي بدأت تيجي هنا تتخيلوا
+
+303
+00:26:02,920 --> 00:26:10,440
+إن الكلور مخد حيزه والمثل C ومخد H وH وH مخد حيز
+
+304
+00:26:10,440 --> 00:26:14,720
+لحد هنا بناءً على ذلك هل من السهل أن تدخل لو
+
+305
+00:26:14,720 --> 00:26:18,860
+تخيلتوا أن هذه إليها حيز إلكتروني مظبوط ولا لأ؟
+
+306
+00:26:18,860 --> 00:26:23,360
+وهذه إليها حيز إيه؟ هل من السهل إنها تيجي هنا؟ صعب
+
+307
+00:26:23,360 --> 00:26:27,740
+إذن هنا تدخل عامل الاسترهاب بس من ناحية نظرية
+
+308
+00:26:27,740 --> 00:26:30,100
+المفروض أنه ممكن تيجي هنا وممكن تيجي هنا وممكن
+
+309
+00:26:30,100 --> 00:26:33,400
+تيجي هنا لكن هذا الموقع product not observed
+
+310
+00:26:35,480 --> 00:26:40,840
+توهندرد يعني مزدحم كثيرًا هذا الموقع مزدحم كثيرًا
+
+311
+00:26:40,840 --> 00:26:50,200
+واضح؟ هذا الموقع مزدحم كثيرًا الآن
+
+312
+00:26:50,200 --> 00:26:55,100
+هنا في عندنا مجموعة من الأمثلة المحلولة بس نتأكد
+
+313
+00:26:55,100 --> 00:26:58,400
+إن ابتدقنوا أنتم الحال تبعها
+
+314
+00:27:02,010 --> 00:27:06,710
+بتطلع عندنا بدكم تبدأوا بطولين نعمله chlorination
+
+315
+00:27:06,710 --> 00:27:12,690
+وين هيجي الـ chlorine؟ على الـ ortho والـ para هنا
+
+316
+00:27:12,690 --> 00:27:17,890
+كتب الـ para وكتب الكزايد الـ ortho product يعني
+
+317
+00:27:17,890 --> 00:27:24,750
+بتطلع خليط من الناتجين عندكم sulfonic acid السيلفون
+
+318
+00:27:24,750 --> 00:27:28,670
+اللي قلنا عنها الـ Deactivating و Meta Directing
+
+319
+00:27:28,670 --> 00:27:33,130
+Group لما بتعمل البروميناتش مع FEPR3 وين هتيجي
+
+320
+00:27:33,130 --> 00:27:36,970
+بالنسبة لها على الـ meta يعني على موقع ثلاثة هاي الـ
+
+321
+00:27:36,970 --> 00:27:45,730
+S 123 إجت لبرومين على موقع meta واضح إجت لبرومين
+
+322
+00:27:45,730 --> 00:27:50,700
+على موقع meta بالنسبة للمجموعة اللي موجودة أصلًا
+
+323
+00:27:50,700 --> 00:27:55,460
+كل المجموعات اللي بتيجي بتيجي بالنسبة للمجموعة
+
+324
+00:27:55,460 --> 00:28:00,860
+اللي موجودة أصلًا الآن هنا عندكم نيترو بدنا نعمل
+
+325
+00:28:00,860 --> 00:28:06,080
+أيوا دي نيشت بدأت تيجي وين النيترو meta meta
+
+326
+00:28:06,080 --> 00:28:08,760
+directing group وين الـ meta تبعها واحد اثنين
+
+327
+00:28:08,760 --> 00:28:12,060
+ثلاثة أو واحد اثنين ثلاثة لاحظوا هي إجت واحد
+
+328
+00:28:12,060 --> 00:28:17,220
+اثنين ثلاثة إجت فعلًا على موقع ثلاثة اللي هو الـ
+
+329
+00:28:17,220 --> 00:28:24,370
+meta إجت على موقع ثلاثة اللي هو الـ meta position
+
+330
+00:28:24,370 --> 00:28:30,390
+نتطلع
+
+331
+00:28:30,390 --> 00:28:33,730
+كمان
+
+332
+00:28:33,730 --> 00:28:40,640
+على هذه الأمثلة عندكم الـ chlorine الكلورين وين
+
+333
+00:28:40,640 --> 00:28:47,180
+بيودي؟ ortho para لما تحط SO3 H2SO4 اللي هو سميناه
+
+334
+00:28:47,180 --> 00:28:52,200
+sulfonation أخذناه سميناه sulfonation بناء العدالة
+
+335
+00:28:52,200 --> 00:28:57,120
+كاي كتب لكم para product زائد الـ ortho isomers
+
+336
+00:28:57,120 --> 00:29:02,300
+لأن هدول isomers نفس الصيغة الجزئية لكن
+
+337
+00:29:02,300 --> 00:29:06,280
+الاختلاف في مواقع الروابط أو في الصيغة البنائية
+
+338
+00:29:06,510 --> 00:29:12,270
+الآن لو كان عندكم تولوين وحطينا excess HNO3 و
+
+339
+00:29:12,270 --> 00:29:17,770
+H2SO4 يجب أن يأتي على الـ para وبعدين زي ما قبل
+
+340
+00:29:17,770 --> 00:29:21,750
+شوية فرجيناكم بالمثال على الـ ortho وعلى الـ
+
+341
+00:29:21,750 --> 00:29:26,310
+ortho ثلاث مجموعات نيترو لأن التولوين اكتف وحطينا
+
+342
+00:29:26,310 --> 00:29:34,460
+excess فبيصير عندي tri-nitro تولوين لو كان عندكم هذا
+
+343
+00:29:34,460 --> 00:29:38,780
+المركب اللي هو اسمه إيش؟ مين اتذكره؟ الـ
+
+344
+00:29:38,780 --> 00:29:43,520
+isopropyl على البنزين الكيومين
+
+345
+00:29:43,520 --> 00:29:48,420
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+346
+00:29:48,420 --> 00:29:48,540
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+347
+00:29:48,540 --> 00:29:48,840
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+348
+00:29:48,840 --> 00:29:53,440
+الكيومين الكيومين الكيومين الكيومين الكيوم
+
+349
+00:29:54,730 --> 00:29:59,570
+Ortho para directing groups or activating بناءً على
+
+350
+00:29:59,570 --> 00:30:03,950
+ذلك لو بدأ تيجي هذا المركب اللي فيه C double bond
+
+351
+00:30:03,950 --> 00:30:07,150
+OCL مع aluminium chloride واضح الـ aluminium
+
+352
+00:30:07,150 --> 00:30:10,450
+chloride بده ياخد منه الـ chlorine بده يعمل
+
+353
+00:30:10,450 --> 00:30:14,630
+oscillation بده يحط C double bond O مع الحلقة
+
+354
+00:30:14,630 --> 00:30:19,750
+تمامًا هذا المثال زي لو كان عندكم CH3C double bond
+
+355
+00:30:19,750 --> 00:30:25,030
+OCL شو كنتوا تحطوا OCL؟ شو كنتوا تحطوه؟ الآن أنا لغيت
+
+356
+00:30:25,030 --> 00:30:29,550
+من هنا CH3 وحطيت Cyclopentane في مشكلة المهم
+
+357
+00:30:29,550 --> 00:30:34,650
+تفاعل وين بده يتم على هذه الكربون هذه الـ كلجروب
+
+358
+00:30:34,650 --> 00:30:40,750
+وين بتودي ortho وpara عشان إيه كانت بيانت على
+
+359
+00:30:40,750 --> 00:30:46,430
+الـ para لاحظوا هنا يمكن تلاحظوا شغلة ما كتبش زائد
+
+360
+00:30:46,430 --> 00:30:52,750
+ortho isomer بتقدروا تتخيلوا عاد ليش ما كتبش زي
+
+361
+00:30:52,750 --> 00:30:59,610
+إت ارثو اي زمر لأن هذه المجموعة لسه CH لما يطلع
+
+362
+00:30:59,610 --> 00:31:06,110
+منها ك CHHHH ومن هنا CHHHH وبده يجيب كل هذه هنا
+
+363
+00:31:06,110 --> 00:31:12,080
+جنبها بيصير ازدحام إذا وين الأريح اليها تروح؟ على
+
+364
+00:31:12,080 --> 00:31:15,760
+الـ para عشان هيك كما .. يعني كما يبدو إنه أنا بس
+
+365
+00:31:15,760 --> 00:31:19,960
+بيطلع عندكم الـ para product لأن هذي لما أفصلها
+
+366
+00:31:19,960 --> 00:31:24,280
+المجموعة لفوق ولتحت وهذي في الـ .. بالذات كمان الـ
+
+367
+00:31:24,280 --> 00:31:29,800
+cyclopentane مجموعة كبيرة بتصير هذه المنطقة مزدحمة
+
+368
+00:31:29,800 --> 00:31:32,620
+too hindered for a reaction to occur
+
+369
+00:31:35,750 --> 00:31:40,430
+بقول إنه من ناحية نظرية متوقع التفاعل يتم هنا أو
+
+370
+00:31:40,430 --> 00:31:46,690
+هنا أو هنا هذا
+
+371
+00:31:46,690 --> 00:31:53,070
+هاي الـ CH3 أول مجموعة وين بتيجي نفترض على الـ para
+
+372
+00:31:53,070 --> 00:31:56,810
+بعد ما إجت على الـ para where بتصير تودي هذه
+
+373
+00:31:56,810 --> 00:32:01,630
+المجموعة الـ Nitro اللي جاءت هنا على الـ meta
+
+374
+00:32:01,630 --> 00:32:04,030
+بالنسبة لي لو هذي
+
+401
+00:34:05,400 --> 00:34:08,320
+acetylation وبعدين in turn نعمل الخطوة الثانية
+
+402
+00:34:08,320 --> 00:34:11,700
+هان والخطوة الثانية هان على طول هتكتشفوا أن أحد
+
+403
+00:34:11,700 --> 00:34:18,420
+المسارين جيد والمسار الآخر غير جيد يعني لو مثلا
+
+404
+00:34:18,420 --> 00:34:24,730
+أنا بدأت بالبنزين عملت الطلوين إذا الخطوة الأولى
+
+405
+00:34:24,730 --> 00:34:30,430
+بنزين عملت بعدها إيش؟ طلوين ممكن نعملها على هذه
+
+406
+00:34:30,430 --> 00:34:41,290
+السطورة هذه بنزين حطيت CH3Cl  ألمنيوم كلوريد صار 
+
+407
+00:34:41,290 --> 00:34:46,790
+عنده طلوين okay الآن في الخطوة الثانية شو هأعمل؟
+
+408
+00:34:49,090 --> 00:34:55,190
+بدي أضيف الـ acetyl اللي هي CH3C double bond OCl
+
+409
+00:34:55,190 --> 00:35:01,630
+في وجود aluminium chloride مظبوط ولا لا؟ طيب لما
+
+410
+00:35:01,630 --> 00:35:05,770
+بعمل مين اللي بتحكم في نتيجة التفاعل؟ المجموعة
+
+411
+00:35:05,770 --> 00:35:09,290
+اللي already موجودة CH3 وين بتودي ال CH3؟ على ال
+
+412
+00:35:09,290 --> 00:35:14,270
+ortho وعلى ال para إذا في النهاية بتطلعلي المركب
+
+413
+00:35:14,270 --> 00:35:20,560
+اللي أنا بدياه ولا لأ؟ بتطلعوا هاي CH3 بتطلع للبارة
+
+414
+00:35:20,560 --> 00:35:27,140
+اللي أنا عاوزه زاد ال ortho زاد ال ortho product
+
+415
+00:35:27,140 --> 00:35:32,540
+إذا هذا المسار بتطلع للناتج واضح؟ هذا المسار بتطلع
+
+416
+00:35:32,540 --> 00:35:38,220
+للناتج الآن اتخيلوا لو بدأت بالمسار التالي حطيت في 
+
+417
+00:35:38,220 --> 00:35:44,560
+الأول الـ CW bond OCH3 الـ CW bond OCH3 لوين بتوده؟
+
+418
+00:35:44,560 --> 00:35:52,850
+للميتا يعني لو حطيت هنا بنزين وقولت بتحط CW.O CH3
+
+419
+00:35:52,850 --> 00:36:00,990
+ممكن نعملها هنا CH3 CW.O Cl Aluminium Chloride و
+
+420
+00:36:00,990 --> 00:36:05,310
+خلّيني أحطها على نفس الموقع اللي مبين عليه مش
+
+421
+00:36:05,310 --> 00:36:16,190
+مشكلة حطت هنا CW.O CH3 الآن اعملولي الـ second step
+
+422
+00:36:17,550 --> 00:36:22,930
+اللي هي CH3Cl زي الألومنيوم كلوريد وين هييجي
+
+423
+00:36:22,930 --> 00:36:30,810
+بالنسبة لهذه المجموعة؟ هل يعطي ناتج؟ لأ لأ واضح؟ 
+
+424
+00:36:30,810 --> 00:36:40,410
+إذا هذه الـC double bond O CH3 وهنا هل هذا قدّالي
+
+425
+00:36:40,410 --> 00:36:45,470
+لنفس الناتج؟ لكن يقصد بيعطي نفس الناتج لو CH3 وجهت
+
+426
+00:36:45,470 --> 00:36:50,710
+على الـR كيف؟ لأ طبعا ال ortho مش هو نفس النتيجة ده
+
+427
+00:36:50,710 --> 00:36:57,610
+ميتا لو بدأنا بال CH3 هاي بدأت بنزين CH3 بيعطينا 
+
+428
+00:36:57,610 --> 00:37:01,270
+البارا زاد ال ortho أنا باهتم بالبارا ال ortho
+
+429
+00:37:01,270 --> 00:37:05,450
+عليا والرأس طالع عندي بس أنا اللي بدياه البارا
+
+430
+00:37:05,450 --> 00:37:08,770
+product أنا اللي بدي اياه البارا product الآن
+
+431
+00:37:08,770 --> 00:37:12,810
+بإمكانكوا كل مرة تحللوه زي هيك بس بإمكانكوا صدقوني
+
+432
+00:37:12,810 --> 00:37:16,730
+بنظرة سريعة جدا تنتبهوا أنكوا متيجوا تقولوا المثل
+
+433
+00:37:16,730 --> 00:37:23,250
+لوين بتودي أورتو بارا إذا بتطلعلي هذا بتودي بارا
+
+434
+00:37:23,250 --> 00:37:28,050
+إذا ببدأ بالمثل وبثني بهذه المجموعة لو بدأت بهذه
+
+435
+00:37:28,050 --> 00:37:32,850
+لوين بتودي مثل بتطلع الناتج لأ إذا إيش أول خطوة في
+
+436
+00:37:32,850 --> 00:37:41,060
+هذا المثل المثل بعدين الاسيتل لازميك الترتيب هذا
+
+437
+00:37:41,060 --> 00:37:47,040
+المصاد بمشيش عندك مثلاشن ثم اسيتلاشن الآن واحدة
+
+438
+00:37:47,040 --> 00:37:52,540
+منكم منتبهة تيجي تطلعلي على هذا المثل تقولي إيش
+
+439
+00:37:52,540 --> 00:37:59,770
+اللي بدي أبدأ فيه إذا بدأتي ب CH3 وين بتودي؟ أورتو
+
+440
+00:37:59,770 --> 00:38:07,050
+أورتو بارا هتظبط معاه؟ لأ طب إذا بدأت بنيترو كان
+
+441
+00:38:07,050 --> 00:38:11,230
+بدأت بنيترو بتحط للميثل على الميتا إذا هذا المركب 
+
+442
+00:38:11,230 --> 00:38:18,810
+كيف لازم أبدأ فيه؟ أول إشي نيتريشن ثم مثليشن لو
+
+443
+00:38:18,810 --> 00:38:21,410
+عملت مثليشن ثم نيتريشن ما بظبطش
+
+444
+00:38:24,620 --> 00:38:29,120
+لأنه لو حطيت الميثل وين هيود النيترو؟ هان أو هان
+
+445
+00:38:29,120 --> 00:38:32,060
+أو هان، مش هيجيبها هان لو حطيت النيترو وين هتحط 
+
+446
+00:38:32,060 --> 00:38:37,700
+الميثل؟ على الميتا بالنسبة لها الآن
+
+447
+00:38:37,700 --> 00:38:42,840
+هذا المركب، اتطلع عليه، عليه مجموعتين، هذه
+
+448
+00:38:42,840 --> 00:38:50,320
+الـCOCH3 إلى وين بتوده؟ لأ، دي activating
+
+449
+00:38:50,320 --> 00:38:56,920
+meta directing group، تذكروها الـ COCH3 Deactivating
+
+450
+00:38:56,920 --> 00:39:03,100
+Ometa Directing Group بتودي على الميتا الـ PR
+
+451
+00:39:03,100 --> 00:39:07,700
+Orthopara إذا لو كنت أنا هذه موجودة عندي حطيتها في
+
+452
+00:39:07,700 --> 00:39:11,460
+الخطوة الأولى بتجيب للبرومين في الخطوة الثانية على
+
+453
+00:39:11,460 --> 00:39:17,440
+الميتا إذا في الأول الـ first step أضيف هذه وبعدها 
+
+454
+00:39:17,440 --> 00:39:21,340
+برومينيشن لو عملت العكس وضعت البروم البرومين بتودي 
+
+455
+00:39:21,340 --> 00:39:25,540
+أورتو أورتو بارا مش حتى عطيني الناتجة إذا هذا
+
+456
+00:39:25,540 --> 00:39:33,160
+المثال اسيلاشن أو اسيتليشن ثم برومينيشن واضح؟ آخر
+
+457
+00:39:33,160 --> 00:39:40,440
+مثال لو بدأت ب PR و اين بتودي الـ PR أورتو بارا
+
+458
+00:39:40,440 --> 00:39:43,140
+طلعت المركبة لو بدأت ب نيترو
+
+459
+00:39:47,510 --> 00:39:53,650
+promination then nitration
+
+460
+00:39:53,650 --> 00:40:01,070
+واضح كيف بصير التفكير بهذه المسائل؟ آخر.. آخر جزء
+
+461
+00:40:01,070 --> 00:40:05,650
+اللي بدنا نحكيه اليوم على بعض المركبات.. على بعض
+
+462
+00:40:05,650 --> 00:40:09,810
+المركبات اللي هم عبارة عن أكثر من حلقة بنزين مش
+
+463
+00:40:09,810 --> 00:40:13,870
+هنتعمق بس بنقولكوا لما بيكون في عندي أكثر من حلقة 
+
+464
+00:40:13,870 --> 00:40:18,530
+بنزين بنسمي المركبات polycyclic aromatic compounds
+
+465
+00:40:18,530 --> 00:40:23,810
+منهالو كانوا two benzene rings بصير المركب اسمه
+
+466
+00:40:23,810 --> 00:40:28,050
+نفثالين، لو كانوا ثلاثة benzene rings بهذا الشكل
+
+467
+00:40:28,050 --> 00:40:35,070
+أنثراسين، لو كانوا ثلاثة مش بخط مستقيم فنانثرين لو
+
+468
+00:40:35,070 --> 00:40:39,690
+كانوا أربعة بهذا الشكل اللي موجود عندك بيكونوا
+
+469
+00:40:39,690 --> 00:40:45,310
+بايرين ولو كانوا خمسة بهذا الشكل اللي موجود هنا
+
+470
+00:40:45,310 --> 00:40:54,210
+بيكونوا بنزو ا بايرين هذا الـ بنزو ا بايرين من
+
+471
+00:40:54,210 --> 00:41:00,960
+المركبات الخطيرة من المركبات الخطيرة جدا لما الناس 
+
+472
+00:41:00,960 --> 00:41:05,260
+بدخن السجائر نتيجة الحرق بتتكون aromatic compounds
+
+473
+00:41:05,260 --> 00:41:11,200
+polycyclic هذا من المركبات اللي بتتكون من السجائر
+
+474
+00:41:11,200 --> 00:41:15,590
+من حرق السجائر وهذا المركب بنقول عنه carcinogenic
+
+475
+00:41:15,590 --> 00:41:19,830
+معنى carcinogenic مسبب للسرطان بس بدكوا تنتبهوا
+
+476
+00:41:19,830 --> 00:41:23,950
+لشغلة.. بدكوا تنتبهوا لشغلة أنه في مركبات بنقول
+
+477
+00:41:23,950 --> 00:41:29,570
+ممكن تسبب سرطان وفي مركبات بنقول أسبوعين والثالث
+
+478
+00:41:29,570 --> 00:41:34,510
+بتعمل سرطان هذا مش من المركبات المزح مش من اللي
+
+479
+00:41:34,510 --> 00:41:40,030
+ممكن يسبب سرطان هذا من اللي أكيد بيعمل سرطان بس
+
+480
+00:41:40,030 --> 00:41:44,970
+طبعا، ليش بتأخر السرطان أحيانا عند المدخنين؟ لأنه 
+
+481
+00:41:44,970 --> 00:41:49,070
+بتكون الكميات قليلة، بس هذا لو أخذوه بتركيز كبير،
+
+482
+00:41:49,070 --> 00:41:52,810
+أعطوه لأي بني آدم، بعد أسبوعين عنده سرطان، ما فيش
+
+483
+00:41:52,810 --> 00:41:56,910
+إمكانية، بتأخر عند المدخنين لأنه في نائب بيطلعي
+
+484
+00:41:56,910 --> 00:42:01,610
+بتركيز قليل، cumulative، ما يصيروا يصلوا، يعني ال
+
+485
+00:42:01,610 --> 00:42:09,670
+80، 90% بيعود يصلوا، واضح؟ لكن لو أخذ بتركيز كبير
+
+486
+00:42:09,670 --> 00:42:13,650
+كتجربة يعني عندنا فار بدنا نعمل عليه تجربة نخليه 
+
+487
+00:42:13,650 --> 00:42:18,550
+يصير عنده سرطان لو أعطينا نيتروزو كمباونز أو بنزو
+
+488
+00:42:18,550 --> 00:42:22,530
+إيه بايرين وأنتم غامضين استنوا عليه أسبوعين و
+
+489
+00:42:22,530 --> 00:42:26,910
+بتشوفوا صار عنده إيش صار عنده سرطان هذا المركب
+
+490
+00:42:26,910 --> 00:42:33,470
+بالمناسبة عشان تنتبهوا بينتج كمان بشكل تحديد من
+
+491
+00:42:33,470 --> 00:42:39,260
+عملية حرق الكاكاوة الكاكاو إذا انحرج مش إذا داب 
+
+492
+00:42:39,260 --> 00:42:44,120
+وعملناه مشروب إذا انحرج يعني لو بتعمله كيك أو ما
+
+493
+00:42:44,120 --> 00:42:48,120
+إلى ذلك بكاكاو والكاكاو بنحرج بيطلع البنزو إيه 
+
+494
+00:42:48,120 --> 00:42:53,600
+بايرين وهذا حقيقة هو اللي موجود.. انتبهوا معاه
+
+495
+00:42:53,600 --> 00:42:57,760
+هو اللي موجود في السجائر لما بيقولولكوا نكهة كذا و
+
+496
+00:42:57,760 --> 00:43:03,560
+نكهة كذا وحقيقة بيضيفوا على التبغ كاكاو وحرق
+
+497
+00:43:03,560 --> 00:43:07,500
+الكاكاو عشان يطلع ريحة والناس ينبسط وبتعرف هذه
+
+498
+00:43:07,500 --> 00:43:10,140
+الأشياء اللي بيظلوا ميضيفوها والناس اللي بياخدوا
+
+499
+00:43:10,140 --> 00:43:13,980
+الشيشة المصايب هذه وبيسموهم عسلو أشياء حلوة كلها 
+
+500
+00:43:13,980 --> 00:43:19,420
+بتطلع روائح هذا الكاكاو هو اللي بيطلع لنا إيش؟ الـ
+
+501
+00:43:19,420 --> 00:43:23,380
+Benzo-A-Pyrene هذا الكاكاو اللي بيطلع الـ Benzo-A
+
+502
+00:43:23,380 --> 00:43:28,040
+-Pyrene اللي هو بيسموه نكهة كذا وبيجي في الدعاية 
+
+503
+00:43:28,040 --> 00:43:36,980
+الانتخابية معتز بهذا الكلام آخر شغلة بنحكيها اللي هي
+
+504
+00:43:36,980 --> 00:43:41,640
+الفوليرين يمكن مرة حكينالكوا عنه أنه غير الـ
+
+505
+00:43:41,640 --> 00:43:45,260
+diamond وغير الـ graphite من الالوتروبز تبعون
+
+506
+00:43:45,260 --> 00:43:50,040
+الكربون لقوا الالوتروبز عبارة عن ستين ذرة كربون
+
+507
+00:43:50,040 --> 00:43:55,280
+لما عملوا الـ structure تبعهم لقوا عبارة عن
+
+508
+00:43:55,280 --> 00:44:01,500
+aromatic structure تقريبا عبارة عن كرة هذه الكرة
+
+509
+00:44:01,500 --> 00:44:08,390
+موجود فيها طبعا حلقات سداسية وحلقات خمسية و double
+
+510
+00:44:08,390 --> 00:44:14,870
+bonds فكأنها تعتبر polycyclic aromatic ring هي أحد
+
+511
+00:44:14,870 --> 00:44:18,950
+الصور اللي ممكن تكون موجودة للكربون غير الـ mass
+
+512
+00:44:18,950 --> 00:44:24,130
+غير الـ graphite بيحكوا عن الـ C60 كرة الكربون ستين
+
+513
+00:44:24,130 --> 00:44:27,550
+هذه الكرة لو بتعدوا الطوبة بالزرقة اللي فيها ستين
+
+514
+00:44:27,550 --> 00:44:36,230
+واحدة واضح ستين طوبة زرقة موجود فيها بسموها
+
+515
+00:44:36,230 --> 00:44:40,570
+الفوليرين نسبة إلى الشخص اللي اكتشفها لاسمه Book
+
+516
+00:44:40,570 --> 00:44:44,810
+Monster Fowler Book Monster Fowler
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..94efe60f768dec9b92e6f8c51ba6b5aee0a0b67e
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_raw.json
@@ -0,0 +1 @@
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{"id": 35, "seek": 79401, "start": 775.83, "end": 794.01, "text": "واضح فسبب التفضيل لل ortho وال para positions هنا أنه بيكون أحد ال resonance structures لل carbocation the stable tertiary carbocation واضح", "tokens": [2407, 46958, 5016, 6156, 35457, 3555, 16712, 5172, 11242, 26895, 24976, 19052, 78, 16070, 1690, 8432, 34105, 14739, 3224, 4724, 1829, 30544, 5551, 24401, 2423, 30944, 9227, 24976, 12143, 27943, 264, 8351, 38726, 29104, 12143, 27943, 4032, 46958, 5016], "avg_logprob": -0.2642578035593033, "compression_ratio": 1.2836879432624113, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 775.83, "end": 776.31, "word": "واضح", "probability": 0.9832356770833334}, {"start": 776.31, "end": 778.07, "word": " فسبب", "probability": 0.8357747395833334}, {"start": 778.07, "end": 779.63, "word": " التفضيل", "probability": 0.9837646484375}, {"start": 779.63, "end": 779.95, "word": " لل", "probability": 0.9208984375}, {"start": 779.95, "end": 781.01, "word": " ortho", 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{"start": 826.44, "end": 827.36, "word": " التلوين", "probability": 0.81585693359375}, {"start": 827.36, "end": 828.82, "word": " التلوين", "probability": 0.975341796875}, {"start": 828.82, "end": 829.44, "word": " اتفقنا", "probability": 0.9525390625}, {"start": 829.44, "end": 831.28, "word": " انه", "probability": 0.832763671875}, {"start": 831.28, "end": 834.06, "word": " orthobaradirecting", "probability": 0.656494140625}, {"start": 834.06, "end": 835.0, "word": " ال", "probability": 0.5869140625}, {"start": 835.0, "end": 835.34, "word": " methyl", "probability": 0.75390625}, {"start": 835.34, "end": 835.82, "word": " group", "probability": 0.9677734375}, {"start": 835.82, "end": 837.08, "word": " orthobaradirecting", "probability": 0.891845703125}, {"start": 837.08, "end": 837.44, "word": " group", "probability": 0.90625}, {"start": 837.44, "end": 838.3, "word": " بناء", "probability": 0.960205078125}, {"start": 838.3, "end": 838.56, "word": " على", "probability": 0.85595703125}, 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السؤال يا تورا كيف هذا الجزء ممكن يكون اتكون؟ إيش أفضل طريقة عشان إحنا نصنعه مبتدئين من البنزين؟ ارجعولي لنقطة، مين more activating؟ بنرجع و بنفرجيكوا إياها على الشاشة", "tokens": [2407, 46958, 5016, 22807, 45164, 47525, 10721, 2655, 5551, 39648, 24793, 21136, 33604, 6027, 35186, 6055, 13063, 995, 9122, 33911, 23758, 25724, 11622, 38207, 3714, 43020, 7251, 30544, 1975, 2655, 30544, 22807, 11933, 1829, 8592, 5551, 5172, 11242, 1211, 23032, 16572, 28671, 6225, 8592, 7649, 11933, 5016, 8315, 8717, 9381, 1863, 3615, 3224, 3714, 3555, 2655, 3215, 19986, 9957, 9154, 29739, 1863, 11622, 9957, 22807, 1975, 47341, 3615, 12610, 1829, 5296, 1863, 47432, 3660, 12399, 3714, 9957, 544, 42481, 22807, 44945, 47341, 3615, 4032, 44945, 5172, 47341, 1829, 4117, 14407, 11933, 25528, 11296, 15844, 25124, 33599, 3660], "avg_logprob": -0.15553252049246613, "compression_ratio": 1.5420560747663552, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1123.1, "end": 1124.08, "word": "واضح؟", 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"word": " مين", "probability": 0.904296875}, {"start": 1140.78, "end": 1141.46, "word": " more", "probability": 0.91357421875}, {"start": 1141.46, "end": 1145.26, "word": " activating؟", "probability": 0.93798828125}, {"start": 1145.26, "end": 1145.98, "word": " بنرجع", "probability": 0.8123372395833334}, {"start": 1145.98, "end": 1146.08, "word": " و", "probability": 0.7705078125}, {"start": 1146.08, "end": 1146.86, "word": " بنفرجيكوا", "probability": 0.8882649739583334}, {"start": 1146.86, "end": 1147.12, "word": " إياها", "probability": 0.5945638020833334}, {"start": 1147.12, "end": 1147.3, "word": " على", "probability": 0.8779296875}, {"start": 1147.3, "end": 1148.0, "word": " الشاشة", "probability": 0.9951171875}], "temperature": 1.0}, {"id": 51, "seek": 117756, "start": 1150.28, "end": 1177.56, "text": "الـ OCH3 more activating than CH3 واضح؟ بتعمل activation أكتر بناء على ذلك لو أنا بدي أبدأ ببنزين إذا حطيت ال OCH3 و بعدين بدي أكمل التفاعل أعمل methylation هتيجي المثل على ال ortho و ال para position باخد مركب ال para اللي أنا مهتم فيه و لو حطيت المثل group", "tokens": [6027, 39184, 422, 5462, 18, 544, 42481, 813, 5995, 18, 4032, 46958, 5016, 22807, 39894, 25957, 1211, 24433, 5551, 4117, 2655, 2288, 44945, 16606, 15844, 29910, 23275, 45164, 41850, 4724, 16254, 5551, 44510, 10721, 4724, 3555, 1863, 11622, 9957, 11933, 15730, 11331, 9566, 36081, 2423, 422, 5462, 18, 4032, 39182, 9957, 4724, 16254, 5551, 24793, 1211, 16712, 5172, 995, 30241, 5551, 25957, 1211, 36599, 24278, 8032, 31371, 7435, 1829, 9673, 12984, 1211, 15844, 2423, 19052, 78, 4032, 2423, 1690, 2535, 4724, 47283, 3215, 3714, 31747, 3555, 2423, 1690, 13672, 1829, 41850, 3714, 3224, 39237, 8978, 3224, 4032, 45164, 11331, 9566, 36081, 9673, 12984, 1211, 1594], "avg_logprob": -0.19133255237116004, "compression_ratio": 1.5789473684210527, "no_speech_prob": 7.152557373046875e-07, "words": [{"start": 1150.2799999999997, "end": 1151.1599999999999, "word": "الـ", "probability": 0.668212890625}, {"start": 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الجزء بدنا نعمل عليه تفاعل إضافي", "tokens": [3555, 6027, 422, 5462, 18, 5296, 33456, 2423, 422, 5462, 18, 544, 42481, 4032, 46958, 5016, 22807, 6055, 5172, 995, 30241, 11296, 4724, 1829, 30544, 11933, 1829, 8592, 5551, 3794, 2288, 3615, 6024, 48506, 23758, 37893, 13412, 17082, 1211, 8315, 9122, 33911, 11331, 11242, 2288, 14407, 23758, 25724, 11622, 38207, 11933, 5016, 8315, 13412, 17082, 1211, 8315, 9122, 33911, 23758, 25724, 11622, 38207, 47525, 8315, 8717, 25957, 1211, 47356, 6055, 5172, 995, 30241, 11933, 11242, 31845, 1829], "avg_logprob": -0.18930288060353354, "compression_ratio": 1.532544378698225, "no_speech_prob": 1.2516975402832031e-06, "words": [{"start": 1192.35, "end": 1193.27, "word": "بال", "probability": 0.6123046875}, {"start": 1193.27, "end": 1194.19, "word": " OCH3", "probability": 0.8142903645833334}, {"start": 1194.19, "end": 1194.81, "word": " لأن", "probability": 0.58349609375}, {"start": 1194.81, "end": 1194.95, "word": " ال", "probability": 0.21533203125}, 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هاي CH3 بتطلع للبارة اللي أنا عاوزه زاد ال ortho زاد ال ortho product إذا هذا المسار بتطلع للناتج واضح؟ هذا المسار بتطلع للناتج الآن اتخيلوا لو بدأت بالمسار التالي حطيت في الأول ال CW bond OCH3 ال CW bond OCH3 لوين بتوده؟ للميجا", "tokens": [3555, 2655, 9566, 1211, 3615, 14407, 8032, 47302, 5995, 18, 39894, 9566, 1211, 3615, 24976, 3555, 9640, 3660, 13672, 1829, 41850, 6225, 995, 2407, 11622, 3224, 30767, 18513, 2423, 19052, 78, 30767, 18513, 2423, 19052, 78, 1674, 11933, 15730, 23758, 9673, 3794, 9640, 39894, 9566, 1211, 3615, 24976, 8315, 2655, 7435, 4032, 46958, 5016, 22807, 23758, 9673, 3794, 9640, 39894, 9566, 1211, 3615, 24976, 8315, 2655, 7435, 6024, 48506, 1975, 2655, 9778, 26895, 14407, 45164, 47525, 10721, 2655, 20666, 2304, 3794, 9640, 16712, 6027, 1829, 11331, 9566, 36081, 8978, 16247, 12610, 2423, 383, 54, 6086, 422, 5462, 18, 2423, 383, 54, 6086, 422, 5462, 18, 5296, 2407, 9957, 39894, 23328, 3224, 22807, 5296, 19528, 1829, 7435, 995], "avg_logprob": -0.23477224008006564, 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0.6063232421875}, {"start": 2124.1, "end": 2126.3, "word": " زاد", "probability": 0.795654296875}, {"start": 2126.3, "end": 2126.42, "word": " ال", "probability": 0.98388671875}, {"start": 2126.42, "end": 2126.74, "word": " ortho", "probability": 0.737060546875}, {"start": 2126.74, "end": 2127.14, "word": " product", "probability": 0.9765625}, {"start": 2127.14, "end": 2127.9, "word": " إذا", "probability": 0.6131591796875}, {"start": 2127.9, "end": 2128.46, "word": " هذا", "probability": 0.81005859375}, {"start": 2128.46, "end": 2128.9, "word": " المسار", "probability": 0.9215494791666666}, {"start": 2128.9, "end": 2129.38, "word": " بتطلع", "probability": 0.9390869140625}, {"start": 2129.38, "end": 2130.08, "word": " للناتج", "probability": 0.87060546875}, {"start": 2130.08, "end": 2131.0, "word": " واضح؟", "probability": 0.7843017578125}, {"start": 2131.0, "end": 2131.26, "word": " هذا", "probability": 0.8662109375}, {"start": 2131.26, "end": 2131.84, "word": " المسار", "probability": 0.9923502604166666}, {"start": 2131.84, "end": 2132.54, "word": " بتطلع", "probability": 0.97216796875}, {"start": 2132.54, "end": 2133.1, "word": " للناتج", "probability": 0.84521484375}, {"start": 2133.1, "end": 2133.84, "word": " الآن", "probability": 0.701904296875}, {"start": 2133.84, "end": 2134.54, "word": " اتخيلوا", "probability": 0.879296875}, {"start": 2134.54, "end": 2134.7, "word": " لو", "probability": 0.99169921875}, {"start": 2134.7, "end": 2135.1, "word": " بدأت", "probability": 0.85205078125}, {"start": 2135.1, "end": 2135.64, "word": " بالمسار", "probability": 0.978515625}, {"start": 2135.64, "end": 2136.78, "word": " التالي", "probability": 0.9612630208333334}, {"start": 2136.78, "end": 2138.06, "word": " حطيت", "probability": 0.9088541666666666}, {"start": 2138.06, "end": 2138.22, "word": " في", "probability": 0.9736328125}, {"start": 2138.22, "end": 2138.82, "word": " الأول", "probability": 0.98046875}, {"start": 2138.82, "end": 2139.78, "word": " ال", "probability": 0.89892578125}, {"start": 2139.78, "end": 2140.18, "word": " CW", "probability": 0.4615478515625}, {"start": 2140.18, "end": 2140.54, "word": " bond", "probability": 0.364990234375}, {"start": 2140.54, "end": 2141.68, "word": " OCH3", "probability": 0.75634765625}, {"start": 2141.68, "end": 2141.82, "word": " ال", "probability": 0.72900390625}, {"start": 2141.82, "end": 2142.12, "word": " CW", "probability": 0.829345703125}, {"start": 2142.12, "end": 2142.4, "word": " bond", "probability": 0.970703125}, {"start": 2142.4, "end": 2143.28, "word": " OCH3", "probability": 0.9820963541666666}, {"start": 2143.28, "end": 2143.64, "word": " لوين", "probability": 0.7501627604166666}, {"start": 2143.64, "end": 2144.56, "word": " بتوده؟", "probability": 0.695556640625}, {"start": 2144.56, "end": 2145.84, "word": " للميجا", "probability": 0.694287109375}], "temperature": 1.0}, {"id": 92, "seek": 217619, "start": 2147.31, "end": 2176.19, "text": "يعني لو حطيت هنا بنزين و قولت بتحط CW.O CH3 ممكن نعملها هنا CH3 CW.O Cl Aluminium Chloride و خلّيني أحطها على نفس الموقع اللي مبين عليه مش مشكلة حطت هنا CW.O CH3 الآن اعملولي ال second step", "tokens": [40228, 22653, 45164, 11331, 9566, 36081, 34105, 44945, 11622, 9957, 4032, 12174, 12610, 2655, 39894, 5016, 9566, 383, 54, 13, 46, 5995, 18, 3714, 43020, 8717, 25957, 1211, 11296, 34105, 5995, 18, 383, 54, 13, 46, 2033, 967, 7112, 2197, 761, 6746, 482, 4032, 16490, 1211, 11703, 9957, 1829, 5551, 5016, 9566, 11296, 15844, 8717, 36178, 9673, 30543, 3615, 13672, 1829, 3714, 3555, 9957, 47356, 37893, 37893, 28820, 3660, 11331, 9566, 2655, 34105, 383, 54, 13, 46, 5995, 18, 6024, 48506, 1975, 25957, 1211, 12610, 1829, 2423, 1150, 1823], "avg_logprob": -0.19774304893281724, "compression_ratio": 1.4405940594059405, "no_speech_prob": 7.748603820800781e-07, "words": [{"start": 2147.31, "end": 2147.61, "word": "يعني", "probability": 0.85302734375}, {"start": 2147.61, "end": 2147.77, "word": " لو", "probability": 0.98828125}, {"start": 2147.77, "end": 2148.23, "word": " حطيت", "probability": 0.97705078125}, {"start": 2148.23, "end": 2148.43, "word": " هنا", "probability": 0.96826171875}, {"start": 2148.43, "end": 2149.17, "word": " بنزين", "probability": 0.8453776041666666}, {"start": 2149.17, "end": 2149.71, "word": " و", "probability": 0.8994140625}, {"start": 2149.71, "end": 2150.03, "word": " قولت", "probability": 0.7600911458333334}, {"start": 2150.03, "end": 2150.67, "word": " بتحط", "probability": 0.7679036458333334}, {"start": 2150.67, "end": 2151.49, "word": " CW", "probability": 0.350830078125}, {"start": 2151.49, "end": 2152.03, "word": ".O", "probability": 0.59454345703125}, {"start": 2152.03, "end": 2152.85, "word": " CH3", "probability": 0.83154296875}, {"start": 2152.85, "end": 2153.21, "word": " ممكن", "probability": 0.948486328125}, {"start": 2153.21, "end": 2153.75, "word": " نعملها", "probability": 0.978759765625}, {"start": 2153.75, "end": 2154.11, "word": " هنا", "probability": 0.943359375}, {"start": 2154.11, "end": 2156.15, "word": " CH3", "probability": 0.9638671875}, {"start": 2156.15, "end": 2157.13, "word": " CW", "probability": 0.69287109375}, {"start": 2157.13, "end": 2158.01, "word": ".O", "probability": 0.967529296875}, {"start": 2158.01, "end": 2159.11, "word": " Cl", "probability": 0.51611328125}, {"start": 2159.11, "end": 2160.01, "word": " Aluminium", "probability": 0.5866495768229166}, {"start": 2160.01, "end": 2160.71, "word": " Chloride", "probability": 0.9026692708333334}, {"start": 2160.71, "end": 2160.99, "word": " و", "probability": 0.92236328125}, {"start": 2160.99, "end": 2161.31, "word": " خلّيني", "probability": 0.781640625}, {"start": 2161.31, "end": 2161.77, "word": " أحطها", "probability": 0.8607177734375}, {"start": 2161.77, "end": 2162.17, "word": " على", "probability": 0.91357421875}, {"start": 2162.17, "end": 2163.73, "word": " نفس", "probability": 0.973876953125}, {"start": 2163.73, "end": 2164.27, "word": " الموقع", "probability": 0.9934895833333334}, {"start": 2164.27, "end": 2164.41, "word": " اللي", "probability": 0.948974609375}, {"start": 2164.41, "end": 2164.75, "word": " مبين", "probability": 0.8277994791666666}, {"start": 2164.75, "end": 2165.03, "word": " عليه", "probability": 0.927734375}, {"start": 2165.03, "end": 2165.31, "word": " مش", "probability": 0.955078125}, {"start": 2165.31, "end": 2167.21, "word": " مشكلة", "probability": 0.9786783854166666}, {"start": 2167.21, "end": 2168.33, "word": " حطت", "probability": 0.955078125}, {"start": 2168.33, "end": 2168.69, "word": " هنا", "probability": 0.97412109375}, {"start": 2168.69, "end": 2169.87, "word": " CW", "probability": 0.87646484375}, {"start": 2169.87, "end": 2170.65, "word": ".O", "probability": 0.99072265625}, {"start": 2170.65, "end": 2172.07, "word": " CH3", "probability": 0.98193359375}, {"start": 2172.07, "end": 2172.81, "word": " الآن", "probability": 0.6190185546875}, {"start": 2172.81, "end": 2173.59, "word": " اعملولي", "probability": 0.90361328125}, {"start": 2173.59, "end": 2175.27, "word": " ال", "probability": 0.80029296875}, {"start": 2175.27, "end": 2175.53, "word": " second", "probability": 0.751953125}, {"start": 2175.53, "end": 2176.19, "word": " step", "probability": 0.9716796875}], "temperature": 1.0}, {"id": 93, "seek": 220611, "start": 2177.55, "end": 2206.11, "text": "اللي هي CH3Cl زي الألومنيوم الكلوري وين هييجي بالنسبة لهذه المجموعة؟ هل يعطي ناتج؟ لأ لأ واضح؟ إذا هذه الـC double bond O CH3 وهنا هل هذا قدّالي لنفس الناتج؟ لكن يقصد بيعطي نفس الناتج لو CH3 وجهت على الـR", "tokens": [6027, 20292, 39896, 5995, 18, 9966, 30767, 1829, 16247, 1211, 20498, 22653, 20498, 33251, 1211, 13063, 1829, 4032, 9957, 39896, 1829, 7435, 1829, 20666, 1863, 35457, 3660, 46740, 24192, 9673, 7435, 2304, 2407, 27884, 22807, 8032, 1211, 37495, 9566, 1829, 8717, 9307, 7435, 22807, 5296, 10721, 5296, 10721, 4032, 46958, 5016, 22807, 11933, 15730, 29538, 2423, 39184, 34, 3834, 6086, 422, 5995, 18, 4032, 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2182.53, "end": 2182.93, "word": " هييجي", "probability": 0.9722900390625}, {"start": 2182.93, "end": 2183.47, "word": " بالنسبة", "probability": 0.9923095703125}, {"start": 2183.47, "end": 2184.03, "word": " لهذه", "probability": 0.93115234375}, {"start": 2184.03, "end": 2185.73, "word": " المجموعة؟", "probability": 0.8345947265625}, {"start": 2185.73, "end": 2186.51, "word": " هل", "probability": 0.827880859375}, {"start": 2186.51, "end": 2186.87, "word": " يعطي", "probability": 0.9161783854166666}, {"start": 2186.87, "end": 2187.63, "word": " ناتج؟", "probability": 0.8809814453125}, {"start": 2187.63, "end": 2187.93, "word": " لأ", "probability": 0.58331298828125}, {"start": 2187.93, "end": 2189.09, "word": " لأ", "probability": 0.813720703125}, {"start": 2189.09, "end": 2190.81, "word": " واضح؟", "probability": 0.8642578125}, {"start": 2190.81, "end": 2191.85, "word": " إذا", "probability": 0.70166015625}, {"start": 2191.85, "end": 2192.15, "word": " هذه", "probability": 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"probability": 0.464111328125}, {"start": 2201.69, "end": 2202.11, "word": " يقصد", "probability": 0.62188720703125}, {"start": 2202.11, "end": 2202.57, "word": " بيعطي", "probability": 0.806787109375}, {"start": 2202.57, "end": 2202.89, "word": " نفس", "probability": 0.9697265625}, {"start": 2202.89, "end": 2203.29, "word": " الناتج", "probability": 0.8136393229166666}, {"start": 2203.29, "end": 2203.51, "word": " لو", "probability": 0.8349609375}, {"start": 2203.51, "end": 2205.01, "word": " CH3", "probability": 0.554779052734375}, {"start": 2205.01, "end": 2205.47, "word": " وجهت", "probability": 0.6797688802083334}, {"start": 2205.47, "end": 2205.67, "word": " على", "probability": 0.3857421875}, {"start": 2205.67, "end": 2206.11, "word": " الـR", "probability": 0.7268880208333334}], "temperature": 1.0}, {"id": 94, "seek": 222379, "start": 2207.03, "end": 2223.79, "text": "كيف؟ لأ طبعا ال ortho مش هو نفس النتيجة ده ميتا لو بدأنا بال CH3 هاي بدأت بنزين CH3 بيعطينا البارا زاد ال ortho انا باهتم بالبارا ال ortho عليا و الرأس طالع عندي بس انا اللي بدياه", "tokens": [4117, 33911, 22807, 5296, 10721, 23032, 3555, 3615, 995, 2423, 19052, 78, 37893, 31439, 8717, 36178, 28239, 31371, 7435, 3660, 11778, 3224, 3714, 36081, 995, 45164, 47525, 10721, 8315, 20666, 5995, 18, 8032, 47302, 47525, 10721, 2655, 44945, 11622, 9957, 5995, 18, 4724, 40228, 9566, 1829, 8315, 29739, 9640, 995, 30767, 18513, 2423, 19052, 78, 1975, 8315, 4724, 40294, 39237, 20666, 3555, 9640, 995, 2423, 19052, 78, 11203, 25528, 4032, 34892, 10721, 3794, 23032, 6027, 3615, 18871, 16254, 4724, 3794, 1975, 8315, 13672, 1829, 4724, 16254, 40294], "avg_logprob": -0.25550426000898535, "compression_ratio": 1.7241379310344827, "no_speech_prob": 1.1324882507324219e-06, "words": [{"start": 2207.03, "end": 2207.77, "word": "كيف؟", "probability": 0.6387532552083334}, {"start": 2207.77, "end": 2208.05, "word": " لأ", "probability": 0.842041015625}, {"start": 2208.05, "end": 2208.49, "word": " طبعا", "probability": 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4587, 9307, 8608, 3215, 32277, 10632, 4032, 11331, 1211, 4587, 9307, 16490, 2304, 3794, 10632, 4032, 3834, 14713, 6156, 4117, 33456, 11296, 6055, 34268, 26890, 6754, 1344, 66, 1050, 45831, 4875, 8032, 7578, 5551, 24401, 31767, 13063, 13672, 7578, 3714, 43020, 6055, 30544, 3714, 29245, 23328, 3660, 5296, 23275, 25513, 11536, 32771, 13546, 2423, 2758, 32771, 13546, 2423, 4295, 642, 4724, 1829, 5016, 4117, 14407, 18871, 2423, 383, 4550, 9122, 25720, 33251, 25513, 11536, 8608, 2655, 9957, 29538, 33251, 25720, 45164, 39894, 22488, 14407, 41950, 37746, 3660, 20666, 11622, 2288, 28671, 13672, 7578, 8978, 11296, 8608, 2655, 9957, 36764, 24401, 3660, 4032, 46958, 5016, 8608, 2655, 9957, 23032, 37746, 3660, 30767, 2288, 28671, 3714, 29245, 23328, 8978, 11296], "avg_logprob": -0.16386879869729035, "compression_ratio": 1.73828125, "no_speech_prob": 8.225440979003906e-06, "words": [{"start": 2645.53, "end": 2646.31, "word": "حلقات", "probability": 0.93115234375}, {"start": 2646.31, "end": 2646.97, "word": " سداسية", "probability": 0.756103515625}, {"start": 2646.97, "end": 2647.11, "word": " و", "probability": 0.96240234375}, {"start": 2647.11, "end": 2647.55, "word": " حلقات", "probability": 0.8753662109375}, {"start": 2647.55, "end": 2648.05, "word": " خمسية", "probability": 0.9249267578125}, {"start": 2648.05, "end": 2648.19, "word": " و", "probability": 0.96240234375}, {"start": 2648.19, "end": 2648.39, "word": " double", "probability": 0.6572265625}, {"start": 2648.39, "end": 2648.79, "word": " bonds", "probability": 0.7060546875}, {"start": 2648.79, "end": 2649.35, "word": " فكأنها", "probability": 0.8675537109375}, {"start": 2649.35, "end": 2649.97, "word": " تعتبر", "probability": 0.9571940104166666}, {"start": 2649.97, "end": 2651.47, "word": " polycyclic", "probability": 0.8214111328125}, {"start": 2651.47, "end": 2652.71, "word": " aromatic", "probability": 0.96484375}, {"start": 2652.71, "end": 2653.73, "word": " ring", "probability": 0.97509765625}, {"start": 2653.73, "end": 2654.41, "word": " هى", "probability": 0.617919921875}, {"start": 2654.41, "end": 2654.87, "word": " أحد", "probability": 0.878173828125}, {"start": 2654.87, "end": 2655.49, "word": " الصور", "probability": 0.98193359375}, {"start": 2655.49, "end": 2655.83, "word": " اللى", "probability": 0.9658203125}, {"start": 2655.83, "end": 2656.19, "word": " ممكن", "probability": 0.99072265625}, {"start": 2656.19, "end": 2656.69, "word": " تكون", "probability": 0.97998046875}, {"start": 2656.69, "end": 2657.51, "word": " موجودة", "probability": 0.9649658203125}, {"start": 2657.51, "end": 2658.13, "word": " للكربون", "probability": 0.83392333984375}, {"start": 2658.13, "end": 2658.41, "word": " غير", "probability": 0.97802734375}, {"start": 2658.41, "end": 2658.57, "word": " ال", "probability": 0.9443359375}, {"start": 2658.57, "end": 2658.95, "word": " mass", "probability": 0.38818359375}, {"start": 2658.95, "end": 2659.29, "word": " غير", "probability": 0.8642578125}, {"start": 2659.29, "end": 2659.41, "word": " ال", "probability": 0.69775390625}, {"start": 2659.41, "end": 2660.19, "word": " graphite", "probability": 0.964599609375}, {"start": 2660.19, "end": 2661.01, "word": " بيحكوا", "probability": 0.95009765625}, {"start": 2661.01, "end": 2661.29, "word": " عن", "probability": 0.98046875}, {"start": 2661.29, "end": 2661.89, "word": " ال", "probability": 0.85546875}, {"start": 2661.89, "end": 2662.59, "word": " C60", "probability": 0.59619140625}, {"start": 2662.59, "end": 2662.93, "word": " كرة", "probability": 0.83642578125}, {"start": 2662.93, "end": 2663.51, "word": " الكربون", "probability": 0.98388671875}, {"start": 2663.51, "end": 2664.13, "word": " ستين", "probability": 0.8515625}, {"start": 2664.13, "end": 2664.73, "word": " هذه", "probability": 0.654296875}, {"start": 2664.73, "end": 2665.07, "word": " الكرة", "probability": 0.98583984375}, {"start": 2665.07, "end": 2665.21, "word": " لو", "probability": 0.9501953125}, {"start": 2665.21, "end": 2665.69, "word": " بتعدوا", "probability": 0.8912760416666666}, {"start": 2665.69, "end": 2665.97, "word": " الطوبة", "probability": 0.5294596354166666}, {"start": 2665.97, "end": 2666.47, "word": " بالزرقة", "probability": 0.67437744140625}, {"start": 2666.47, "end": 2666.59, "word": " اللى", "probability": 0.96923828125}, {"start": 2666.59, "end": 2666.83, "word": " فيها", "probability": 0.9111328125}, {"start": 2666.83, "end": 2667.55, "word": " ستين", "probability": 0.9384765625}, {"start": 2667.55, "end": 2668.99, "word": " واحدة", "probability": 0.9283854166666666}, {"start": 2668.99, "end": 2669.77, "word": " واضح", "probability": 0.93359375}, {"start": 2669.77, "end": 2670.73, "word": " ستين", "probability": 0.82763671875}, {"start": 2670.73, "end": 2671.19, "word": " طوبة", "probability": 0.93017578125}, {"start": 2671.19, "end": 2671.69, "word": " زرقة", "probability": 0.9099934895833334}, {"start": 2671.69, "end": 2672.93, "word": " موجود", "probability": 0.9853515625}, {"start": 2672.93, "end": 2674.27, "word": " فيها", "probability": 0.933837890625}], "temperature": 1.0}, {"id": 114, "seek": 268481, "start": 2675.65, "end": 2684.81, "text": "بسموها الفوليري النسبة الى الشخص اللى اكتشفها لاسمه Book Monster Fowler Book Monster Fowler", "tokens": [3555, 38251, 2407, 11296, 27188, 12610, 13546, 1829, 28239, 35457, 3660, 2423, 7578, 25124, 9778, 9381, 13672, 7578, 1975, 4117, 2655, 8592, 5172, 11296, 5296, 32277, 2304, 3224, 9476, 21059, 479, 305, 1918, 9476, 21059, 479, 305, 1918], "avg_logprob": -0.2694310928002382, "compression_ratio": 1.35, "no_speech_prob": 0.0, "words": [{"start": 2675.65, "end": 2676.23, "word": "بسموها", "probability": 0.8582763671875}, {"start": 2676.23, "end": 2676.83, "word": " الفوليري", "probability": 0.65966796875}, {"start": 2676.83, "end": 2677.79, "word": " النسبة", "probability": 0.8955078125}, {"start": 2677.79, "end": 2678.27, "word": " الى", "probability": 0.5653076171875}, {"start": 2678.27, "end": 2678.67, "word": " الشخص", "probability": 0.9544270833333334}, {"start": 2678.67, "end": 2679.03, "word": " اللى", "probability": 0.889892578125}, {"start": 2679.03, "end": 2679.77, "word": " اكتشفها", "probability": 0.9608561197916666}, {"start": 2679.77, "end": 2680.33, "word": " لاسمه", "probability": 0.7855224609375}, {"start": 2680.33, "end": 2680.57, "word": " Book", "probability": 0.24365234375}, {"start": 2680.57, "end": 2681.09, "word": " Monster", "probability": 0.65869140625}, {"start": 2681.09, "end": 2682.61, "word": " Fowler", "probability": 0.6742350260416666}, {"start": 2682.61, "end": 2683.55, "word": " Book", "probability": 0.7041015625}, {"start": 2683.55, "end": 2683.97, "word": " Monster", "probability": 0.88525390625}, {"start": 2683.97, "end": 2684.81, "word": " Fowler", "probability": 0.9814453125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2692.6325, "duration_after_vad": 2597.0299999999897}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..cb54988afd2b2ff1fea4ff693c6de19531874b8b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8.srt
@@ -0,0 +1,1653 @@
+1
+00:00:08,200 --> 00:00:13,540
+بسم الله الرحمن الرحيم بنستكمل اليوم في موضوع الـ
+
+2
+00:00:13,540 --> 00:00:18,080
+aldehydes والـ ketones طبعا سبق إن أكدنا إنه they 
+
+3
+00:00:18,080 --> 00:00:23,240
+are reactive compounds with so many different
+
+4
+00:00:23,240 --> 00:00:29,230
+reactionsبشكل أساسي التفاعل الأساسي اللي حكينا عنه 
+
+5
+00:00:29,230 --> 00:00:33,190
+للـ aldehydes والـ ketones كان تفاعل الـ addition
+
+6
+00:00:33,710 --> 00:00:36,650
+حتى الـ reduction لما تعاملنا معاه في النهاية كان 
+
+7
+00:00:36,650 --> 00:00:40,470
+هو عبارة عن عملية addition حتى ال reduction لما 
+
+8
+00:00:40,470 --> 00:00:45,150
+تعاملنا معاه كان في نهاية عملية addition الآن
+
+9
+00:00:45,150 --> 00:00:50,350
+بناخد تفاعل ال oxidation of aldehydes and ketones
+
+10
+00:00:50,350 --> 00:00:55,310
+طبعا ال oxidation له معاني كثيرة خلينا ناخد أبسط
+
+11
+00:00:55,310 --> 00:00:58,550
+معنى بس اللي بدنا نتعامل معاه اليوم أنه بده يزيد
+
+12
+00:00:58,550 --> 00:01:02,610
+عندنا عدد الروابط مع الـ Oxygen
+
+13
+00:01:05,370 --> 00:01:09,810
+فبنلاحظ إحنا إنه في الـ aldehyde فيه هيدروجين
+
+14
+00:01:09,810 --> 00:01:14,490
+يمكن أن تستبدل ويجي مكانها أكسوجين بينما في الـ
+
+15
+00:01:14,490 --> 00:01:17,790
+Ketone هذا الكلام غير متوفر يعني المجموعات اللي
+
+16
+00:01:17,790 --> 00:01:21,910
+موجودة مجموعات R-groups وبناء على ذلك اللي حقيقة
+
+17
+00:01:21,910 --> 00:01:26,990
+بيصير له أكسدة الالدهيدس اللي حقيقة بيصير له أكسدة
+
+18
+00:01:26,990 --> 00:01:31,650
+الالدهيد فالالدهيد بيصير له أكسدة سواء في وسط حمضي
+
+19
+00:01:31,650 --> 00:01:37,860
+أو في وسط قاعدي بعوامل مثل الـ KMnO4 برمنجنات 
+
+20
+00:01:37,860 --> 00:01:42,100
+البوتاسيوم وغيرها اللي سبق أننا أخدناه وهذا
+
+21
+00:01:42,100 --> 00:01:46,460
+التفاعل كله سبق أخدناه حقيقة فبيعطينا الحامض أو
+
+22
+00:01:46,460 --> 00:01:51,380
+ملح الحامض اللي عنده الملح مجرد ما يضيف عليه H+
+
+23
+00:01:51,380 --> 00:01:55,360
+بيحصل على إيش؟ على الحامض يعني لو عملنا الأكسد في
+
+24
+00:01:55,360 --> 00:02:00,100
+الـ Basic Medium بيطلع عندنا R C double bond O O
+
+25
+00:02:00,100 --> 00:02:05,110
+minus غالبا بيكون معها مثلا الـ A+ إذا ضفنا
+
+26
+00:02:05,110 --> 00:02:10,990
+عليه H+ بنحصل على الحامض ففي النهاية أكسدت ال
+
+27
+00:02:10,990 --> 00:02:15,810
+الديهيدز أكسدت ال الديهيدز سواء ب basic medium أو
+
+28
+00:02:15,810 --> 00:02:20,470
+ب acidic medium في النهاية تؤدي إلى تكوين ال
+
+29
+00:02:20,470 --> 00:02:23,970
+carboxylic acid لاحظوا هنا في عندي رابطتين مع ال
+
+30
+00:02:23,970 --> 00:02:29,530
+oxygen هنا في عندي ثلاث روابط مع الأكسجين وهذا جزء
+
+31
+00:02:29,530 --> 00:02:33,770
+من مفهوم الأكسدة أننا نقول أن تمت عملية أكسدة لا
+
+32
+00:02:33,770 --> 00:02:37,750
+نريد القول في هذا التفاعل لأنه سبق أننا اتكلمنا
+
+33
+00:02:37,750 --> 00:02:42,630
+عنه عندما أخذنا الكمية تبع الكحولات سبق أننا
+
+34
+00:02:42,630 --> 00:02:49,720
+اتكلمنا عنه، واضح؟ الآن بيجينا تفاعل كثير جدا مشهور
+
+35
+00:02:49,720 --> 00:02:55,040
+وكثير جدا مهم للـ aldehydes و الـ ketones هذا
+
+36
+00:02:55,040 --> 00:03:01,860
+التفاعل هو التفاعل مع المركبات اللي فيها NH2 هذا
+
+37
+00:03:01,860 --> 00:03:07,240
+التفاعل هو التفاعل مع المركبات اللي فيها NH2 أو
+
+38
+00:03:07,240 --> 00:03:13,820
+طبعا NH3 بتعرفوا أبسط واحد فيهم الأمونيا الأمونيا
+
+39
+00:03:13,820 --> 00:03:18,520
+إيش ماخدة؟ NH3 وفيها زوج إلكترونات فيتمثل
+
+40
+00:03:18,520 --> 00:03:23,540
+الـ Nucleophile لأن لما بيصير عندي جزيئين أمونيا مع 
+
+41
+00:03:23,540 --> 00:03:28,380
+بعض المركب اللي هو NH2 NH2 هذا المركب بنسميها
+
+42
+00:03:28,380 --> 00:03:34,470
+هيدرازين واضح فالهيدرازين هو عبارة عن جزيئين
+
+43
+00:03:34,470 --> 00:03:37,650
+أمونيات اتحدوا مع بعض و فقدوا هيدروجين and H2O and
+
+44
+00:03:37,650 --> 00:03:43,230
+H2O هيدرازين الهيدرازين ممكن يكون substituted
+
+45
+00:03:43,230 --> 00:03:50,270
+هيدرازين يعني أشيل H منه و أحط فينيل بيصير فينيل
+
+46
+00:03:50,270 --> 00:03:57,070
+هيدرازين لو حطيت مثل مثل هيدرازيل، لو حطيت إيثيل إيثيل
+
+47
+00:03:57,070 --> 00:04:05,210
+هيدرازيل، واضح؟ الآن، لو حطيت مجموعة كبيرة شوية زي
+
+48
+00:04:05,210 --> 00:04:10,230
+هذه، هذه المجموعة، لو قلنا one, two, three, four,
+
+49
+00:04:10,470 --> 00:04:15,650
+five, six, two, four, dinitrophilin، كلها اسمها
+
+50
+00:04:15,650 --> 00:04:25,950
+هذه 2,4-dinitrophenyl 2,4-dinitrophenylhydrazine
+
+51
+00:04:37,000 --> 00:04:41,240
+إحنا بنيجي نتطلع كيف كل هذه المُركّبات بتتفاعل، 
+
+52
+00:04:41,240 --> 00:04:47,340
+يعني وين المحور الأساسي لتفاعلها، المحور الأساسي
+
+53
+00:04:47,340 --> 00:04:51,700
+لتفاعلها هو زوج الإلكترونات اللي موجود على
+
+54
+00:04:51,700 --> 00:04:53,800
+الـ Nitrogen
+
+55
+00:04:55,400 --> 00:04:59,380
+واضح؟ المحور الأساسي لتفاعلها هو زوج الإلكترونات
+
+56
+00:04:59,380 --> 00:05:03,160
+الموجودة عن نيتروجين وطبعا هذا بتدل على أن كل هذه
+
+57
+00:05:03,160 --> 00:05:09,180
+عبارة عن nucleophiles .. nucleophiles طالما أن 
+
+58
+00:05:09,180 --> 00:05:14,240
+هذه عبارة عن nucleophiles طالما أن هذه عبارة عن
+
+59
+00:05:14,240 --> 00:05:20,430
+nucleophiles إذا إيش التفاعل اللي بتعمله؟ in
+
+60
+00:05:20,430 --> 00:05:24,950
+nucleophilic addition يعني لو بده أجي أطلع هنا
+
+61
+00:05:24,950 --> 00:05:29,410
+بنفس المنطق أقول هاي زوج الإلكترونات اللي عندي هاي
+
+62
+00:05:29,410 --> 00:05:33,370
+زوج الإلكترونات اللي عندي بده يهاجم هنا و ال O إيش 
+
+63
+00:05:33,370 --> 00:05:40,670
+بده تصير؟ OH واضح؟ نفس التفاعل ولا لأ؟ لو إجينا
+
+64
+00:05:40,670 --> 00:05:49,130
+نعملوا هذا الناتج بدنا نقول هي عندنا carbon R R OH
+
+65
+00:05:50,750 --> 00:05:58,210
+إن هتفقد H بالتأكيد إن H كمان إن H وهذه ال
+
+66
+00:05:58,210 --> 00:06:03,630
+residue أو الجزء المتبقي الآن
+
+67
+00:06:03,630 --> 00:06:08,070
+لاحظوا هنا إحنا ما زلنا بنتكلم على نفس الفكرة ال
+
+68
+00:06:08,070 --> 00:06:14,690
+nucleophilic addition هي نضيف هذا إذا بتذكروا و
+
+69
+00:06:14,690 --> 00:06:23,050
+ال O صارت OH إذا أنا هنا بحكي عن الـ Nucleophilic
+
+70
+00:06:23,050 --> 00:06:27,570
+addition ولا لأ؟ آه طيب هذا التفاعل الآن إيش
+
+71
+00:06:27,570 --> 00:06:32,410
+بيختلف عن التفاعلات السابقة؟ في خطوة الأولى لا
+
+72
+00:06:32,410 --> 00:06:39,150
+يختلف شيء لكن عادة الخطوة الأولى تتبع مباشرة بخطوة
+
+73
+00:06:39,150 --> 00:06:44,410
+ثانية إضافية في الخطوة الثانية الإضافية بتم حدث 
+
+74
+00:06:44,410 --> 00:06:48,870
+الـ OH هذه مع ال H اللي موجودة على الآن H و بعمله
+
+75
+00:06:48,870 --> 00:06:56,630
+double bond واضح؟ فبيصير عندي عملية مركبة من عمليتين
+
+76
+00:06:56,630 --> 00:07:02,170
+العملية الأولى اللي إحنا متعودين عليها ال addition
+
+77
+00:07:02,170 --> 00:07:07,950
+والعملية الثانية عملية حدث جزئ ماء elimination
+
+78
+00:07:07,950 --> 00:07:15,470
+ولذلك التفاعل مع هدول المركبات حقيقة بتنفي خطوتين
+
+79
+00:07:15,470 --> 00:07:21,240
+الخطوتين شو هما addition و elimination هذا الكلام
+
+80
+00:07:21,240 --> 00:07:25,380
+addition و elimination لحد ما أصل للنتج النهائي
+
+81
+00:07:25,380 --> 00:07:29,840
+لحد ما أصل للنتج النهائي إذا أنا طلبت منكم تفصلوا
+
+82
+00:07:29,840 --> 00:07:33,760
+لي شو الكلام اللي بيصير لكن لو أنا باجي بسألكم في
+
+83
+00:07:33,760 --> 00:07:39,540
+امتحان أعطوني الجواب بسرعة و خلال ثانية أسهل طريقة
+
+84
+00:07:39,540 --> 00:07:43,420
+عشان تعطوا الجواب بسرعة و خلال ثانية إذا بنجيبلكم
+
+85
+00:07:43,420 --> 00:07:50,550
+تفاعلوا NH2 من هدولة مع C double bond O تجي تمسكوا الـ H2 مع
+
+86
+00:07:50,550 --> 00:07:57,610
+الـ O تشطبوهم و تمدوا الـ double bond واضح؟ حطوهم
+
+87
+00:07:57,610 --> 00:08:02,910
+جنب بعض الـ C double bond O جنب الـ N H2 و أخذوا
+
+88
+00:08:02,910 --> 00:08:09,550
+H2O مياه فيها واضح؟
+
+89
+00:08:09,550 --> 00:08:13,250
+مافيش أسهل منه يعني كيف أكتب ناتج تفاعل
+
+90
+00:08:13,250 --> 00:08:18,590
+الديهيد أو كيتون مع أي واحد من هدولة بدي أشيل الـ H2
+
+91
+00:08:18,590 --> 00:08:23,590
+مع الـ O و أعمل مكانهم double bond لكن بكون عارف
+
+92
+00:08:23,590 --> 00:08:28,830
+أن هذا الكلام نتاج خطوتين نتاج عملية addition
+
+93
+00:08:28,830 --> 00:08:34,870
+followed by elimination الآن في معظم الحالات إحنا 
+
+94
+00:08:34,870 --> 00:08:38,130
+بنقول لكم اكتبوا لنا الناتج الآن لما نقول اكتبوا
+
+95
+00:08:38,130 --> 00:08:41,650
+الناتج بديش أشوف الكلام هذا اللي في الوسط عطول
+
+96
+00:08:41,650 --> 00:08:48,200
+بتحطوا لي إيش؟ C double bond N ع طول بدنا نحط الـ C
+
+97
+00:08:48,200 --> 00:08:52,460
+double bond أن الناتج النهائي بحط الـ H2 جنب الـ O
+
+98
+00:08:52,460 --> 00:08:58,620
+و بشيلهم مع بعض هذه الطريقة العملية لكتابة الناتج
+
+99
+00:08:58,620 --> 00:09:04,800
+هذه العملية مركبة من عمليتين عملية addition وعملية
+
+100
+00:09:04,800 --> 00:09:11,660
+elimination إضافة وحدث واضح؟ وهذه حقيقة من
+
+101
+00:09:11,660 --> 00:09:17,390
+العمليات الهامة أو المهمة والتي تتكرر الآن لاحظوا
+
+102
+00:09:17,390 --> 00:09:22,690
+هنا بنعطي نوعا ما تعميم عام أنه لو عندي NH2 متصلة
+
+103
+00:09:22,690 --> 00:09:29,130
+مع إيش مكان يكون يعني صرت جاي ال X أنا هال X هذه
+
+104
+00:09:29,130 --> 00:09:33,630
+ممكن تكون NH2 الثانية زي الأمثلة اللي شوفناها ممكن 
+
+105
+00:09:33,630 --> 00:09:40,590
+تكون NH-phenyl ممكن تكون R أمين يعني يعني مثلا
+
+106
+00:09:40,590 --> 00:09:46,950
+تكون CH2 أو تكون phenyl NH2 أنا لين ممكن تكون OH في
+
+107
+00:09:46,950 --> 00:09:51,650
+كل الأحوال دائماً لما تيجي الـ NH2 مع الـ C double
+
+108
+00:09:51,650 --> 00:09:56,290
+bond O تبعت الألديهيد والكيتون دي ربالكوا لإنه بعد
+
+109
+00:09:56,290 --> 00:09:58,950
+هيك مع الـ C double bond O تبعت الأحماض
+
+110
+00:09:58,950 --> 00:10:03,510
+الكربوكسيلية بصير تفاعل ثاني أنا بحكي عن ألديهيد
+
+111
+00:10:03,510 --> 00:10:08,030
+و كيتون بدي أحدث الـ hydrogens بتنتهي مع الـ oxygen و
+
+112
+00:10:08,030 --> 00:10:13,170
+أعمل double bond هاي هنا الكلام واضح ولا أسهل منه
+
+113
+00:10:13,170 --> 00:10:19,110
+كمان هاي مع الـ hydrazine شيلنا الـ H2O و كل إيش
+
+114
+00:10:19,110 --> 00:10:22,990
+أخذناه زي ما هو و عملنا double bond مع الفين
+
+115
+00:10:22,990 --> 00:10:30,470
+الهيدرازين شيلنا الـ H2O و عملنا double bond،
+
+116
+00:10:30,470 --> 00:10:35,990
+واضح؟ الآن، هدول عن المُركّبات إيش بنسميهم اللي
+
+117
+00:10:35,990 --> 00:10:43,340
+بينتجوا عندنا نفترض هذا المُركّب كان CH3 CH3 شو
+
+118
+00:10:43,340 --> 00:10:50,760
+بيكون اسمه أسيتون أسيتون طب الناتج أسيتون زائد هذا
+
+119
+00:10:50,760 --> 00:10:59,680
+الـ NH2 NH2 هيدرازين إيش الناتج بيكون اسمه أسيتون
+
+120
+00:10:59,680 --> 00:11:08,480
+هيدرازون بيبطل هيدرازين CH3 CH3 بنكتب اسم ال
+
+121
+00:11:08,480 --> 00:11:11,180
+ketone في الأول و بعدين
+
+122
+00:11:14,180 --> 00:11:17,620
+هيدرازون، فبيصير كأنه عندي قاعدة عامة، القاعدة
+
+123
+00:11:17,620 --> 00:11:22,820
+العامة بتقول إن الـ hydrazines react with aldehydes
+
+124
+00:11:22,820 --> 00:11:26,900
+and ketones producing hydrazones، شو هما
+
+125
+00:11:26,900 --> 00:11:29,940
+الـ hydrazones المركبات اللي فيهم C double bond N
+
+126
+00:11:29,940 --> 00:11:34,440
+and H2 و، هذه عائلة الإيش؟ الـ hydrazones، C double
+
+127
+00:11:34,440 --> 00:11:36,300
+bond N، N ثانية
+
+128
+00:11:44,500 --> 00:11:47,680
+يعني ليش بننسب إليه؟ لما كان فيه مجموعة فينيل وكان
+
+129
+00:11:47,680 --> 00:11:51,120
+مجموعة نايترو، في النهاية نسبنا إليه، جبل يعني، جبل
+
+130
+00:11:51,120 --> 00:11:54,280
+متخدر. خليني أشوف الأمثلة الثانية، مش فاهم سؤالك،
+
+131
+00:11:54,280 --> 00:11:57,960
+أنا مش واضح. لو افترضنا هذا أسيتون اتفاعل مع فين
+
+132
+00:11:57,960 --> 00:12:01,520
+الهيدرازين، شو هسميه؟ الناتج.
+
+133
+00:12:04,140 --> 00:12:08,220
+لو هذا أسيتون مثل ومثل، شو هيكون اسم هذا الناتج؟
+
+134
+00:12:08,220 --> 00:12:16,480
+أسيتون فينيل هيدرازون لو حطينا الـ dinitro أسيتون
+
+135
+00:12:16,480 --> 00:12:29,220
+two four dinitro فينيل هيدرازون إيش المشكلة؟
+
+136
+00:12:29,220 --> 00:12:34,090
+هيك اسمه دائماً لما تتغلبوا في شغلة أسماء و يقعد
+
+137
+00:12:34,090 --> 00:12:37,430
+بالك و يروح شماله يمينه شره و غرب تتذكروا أن 
+
+138
+00:12:37,430 --> 00:12:41,210
+القرآن الكريم بيقول وعلم آدم الأسماء كلها ثم عرضهم
+
+139
+00:12:41,210 --> 00:12:44,430
+على الملائكة فقال أنبئوني بأسماء هؤلاء إن كنتم 
+
+140
+00:12:44,430 --> 00:12:51,030
+صادقين واضح؟ فقال أنبئوني بأسماء هؤلاء إن كنتم 
+
+141
+00:12:51,030 --> 00:12:54,600
+صادقين بالتسهيل بدناش ندخل في الهمزات كيف لما
+
+142
+00:12:54,600 --> 00:12:59,100
+بلتقيهم في كثير أشياء هيك اتسمت و اتسمية زي ما
+
+143
+00:12:59,100 --> 00:13:03,440
+حكيت لكم أنا سابقًا بدخل فيها مرات عوامل تاريخية و
+
+144
+00:13:03,440 --> 00:13:08,240
+مرات عوامل اشتقاقية، مظبوط ولا لا؟ common names
+
+145
+00:13:08,240 --> 00:13:14,480
+و غيره وغيراته، الآن لو افترضنا اللي كان عندنا NH2
+
+146
+00:13:14,480 --> 00:13:21,640
+مع OH هذا المركب بنسميه Hydroxyl Amine الـ NH2
+
+147
+00:13:21,640 --> 00:13:26,920
+OH2 شو بيسموه؟ Hydroxyl شايفين الـ Hydroxyl و الـ
+
+148
+00:13:26,920 --> 00:13:34,440
+NH2 Amine فبيصير Hydroxyl Amine الآن لو اتفعل مع 
+
+149
+00:13:34,440 --> 00:13:38,580
+كيتون نفترض أسيتون أسيتوفينون سايكلوهيكسانون 
+
+150
+00:13:38,580 --> 00:13:44,830
+بنتانون أي الناتج اللي بيطلع شو بنسميه؟ خلينا نحط
+
+151
+00:13:44,830 --> 00:13:48,310
+هدول مثيل و فينيل، إيش المركب اللي فيه مثيل
+
+152
+00:13:48,310 --> 00:13:56,790
+و فينيل؟ هنا فينيل و هنا CH3، فينيل سيضاو البندق و
+
+153
+00:13:56,790 --> 00:14:03,790
+CH3، أخذنا له لما قلبته أسيتوفينون،
+
+154
+00:14:03,790 --> 00:14:10,140
+أسيتوفينون الكيتون هذا إيش اسمه؟ أسيتوفينون
+
+155
+00:14:10,140 --> 00:14:15,540
+أسيتوفينون
+
+156
+00:14:15,540 --> 00:14:25,900
+أكسيم أسيتوفينون
+
+157
+00:14:25,900 --> 00:14:29,060
+أكسيم
+
+158
+00:14:29,060 --> 00:14:33,360
+أسيتوفينون
+
+159
+00:14:33,360 --> 00:14:37,060
+أكسيم أسيتوفينون أكسيم
+
+160
+00:14:40,040 --> 00:14:45,180
+أسيتوفينون أكسيم فال أكسيم لما نقول عائلة أكسيم 
+
+161
+00:14:45,180 --> 00:14:51,080
+مجرد ما تشوفه مركب C double bond N OH هذا أكسيم
+
+162
+00:14:51,080 --> 00:14:55,760
+مجرد ما تشوفه مركب C double bond N N ثانية
+
+163
+00:14:55,760 --> 00:15:00,820
+هيدرازون الآن لو كان NH2 بيكون simple hydrazone NH
+
+164
+00:15:00,820 --> 00:15:04,600
+phenyl فين الهيدرازون؟ مثل هيدرازون؟ two-four
+
+165
+00:15:04,600 --> 00:15:07,320
+-dinitro؟ فين الهيدرازون؟ ما أعرفش إذا في المختبر
+
+166
+00:15:07,320 --> 00:15:14,400
+صرتوا واصلين لتجربة الالديهيدس و الكيتونز ولا لسه؟
+
+167
+00:15:14,400 --> 00:15:17,660
+أنتوا فاصل ثاني ماخذين المادة؟ إذا 
+
+168
+00:15:22,550 --> 00:15:27,570
+انتبهوا معي في المشتقات .. في المشتقات تبعت اللي
+
+169
+00:15:27,570 --> 00:15:32,730
+هي الآن H2O مار عليكم الهيدرازين مار عليكم
+
+170
+00:15:32,730 --> 00:15:37,670
+الهيدروكس الأمين ونفس التفاعل اللي هو تفاعل فقد
+
+171
+00:15:37,670 --> 00:15:40,210
+الماء اللي هي عملية ال addition elimination
+
+172
+00:15:40,210 --> 00:15:49,440
+و بيجيكم كمان أشياء ثانية لكن كلها نفس الفكرة اللي
+
+173
+00:15:49,440 --> 00:15
+
+201
+00:18:52,780 --> 00:18:57,740
+المركبات اللي فيها C double bond N متصلة مع R
+
+202
+00:18:57,740 --> 00:19:02,620
+هنا مرات بتاخد كمان اسم تاني بيسموها Schiff bases
+
+203
+00:19:02,620 --> 00:19:07,300
+قواعد شيف بالنسبة للعالم شيف هم نفسهم الإيمينز
+
+204
+00:19:07,300 --> 00:19:10,720
+بس لو سمعتوا اسم شيف بيس اللي هي نفس هذه
+
+205
+00:19:10,720 --> 00:19:16,100
+المركبات الإيمينز اللي فيها C double bond N واضح؟
+
+206
+00:19:16,100 --> 00:19:22,980
+الآن نشوف من هذه الأمثلة اللي موجودة عندنا أي مثال
+
+207
+00:19:22,980 --> 00:19:30,700
+اللي أخذنا زيه هان هيندي كيتون مع RNH2 إذا كيتون
+
+208
+00:19:30,700 --> 00:19:38,900
+زائد أمين شو هيعطيلي؟ إيمين، إيمين ممتاز، هيندي كيتون
+
+209
+00:19:38,900 --> 00:19:46,160
+زائد هيدروكسيل أمين ماذا يعطيني؟ أوكسيم، هي أنا عندي
+
+210
+00:19:46,160 --> 00:19:50,740
+كيتون زائد سمبل هيدرازين، سمبل يعني أنا أنا أنا
+
+211
+00:19:50,740 --> 00:19:52,320
+أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا
+
+212
+00:19:52,320 --> 00:19:52,580
+أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا
+
+213
+00:19:52,580 --> 00:19:53,580
+أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا
+
+214
+00:19:53,580 --> 00:19:53,760
+أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا
+
+215
+00:19:53,760 --> 00:19:55,480
+أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا أنا
+
+216
+00:19:55,480 --> 00:20:08,640
+أنا أنا أنا أنا أنا أنا
+
+217
+00:20:08,640 --> 00:20:15,410
+أنا هذه الأخيرة ما مرتش عليكم لسه، إيش هو هذا آخر
+
+218
+00:20:15,410 --> 00:20:24,050
+جزء موجود عندي N-H2C-O-N-H-N-H2 طلع عليها مرة
+
+219
+00:20:24,050 --> 00:20:36,630
+ثانية نكبرها شوية C-O-N-H2-N-H2-N-H2 هذا المركب
+
+220
+00:20:36,630 --> 00:20:45,300
+بنسميه semi carbazide هذا المركب بيسميه
+
+221
+00:20:45,300 --> 00:20:49,760
+سيمي Carbazide اللي هي صيغته بالبنط O من جهة متصلة
+
+222
+00:20:49,760 --> 00:20:56,960
+بـ NH2 وحدة ومن جهة متصلة بـ NH NH2 الآن لو جئنا
+
+223
+00:20:56,960 --> 00:21:00,020
+قلنا هذه من وين بدها تتفاعل؟ بدها تتفاعل من الـ
+
+224
+00:21:00,020 --> 00:21:02,820
+NH2 هتيجي تتفاعل، كم NH2 
+
+225
+00:21:09,020 --> 00:21:13,820
+هل يا ترى في إمكانية من الجهتين ولا التفاعل بيتم
+
+226
+00:21:13,820 --> 00:21:21,020
+فقط من جهة واحدة؟ التفاعل فقط يتم من جهة واحدة اللي
+
+227
+00:21:21,020 --> 00:21:26,020
+هي جهة الهيدرازين اللي هي جهة ال NH NH2 من هنا
+
+228
+00:21:26,020 --> 00:21:31,500
+ما بيصيرش التفاعل إطلاقاً واضح؟
+
+229
+00:21:32,300 --> 00:21:38,960
+هذه نسميها أميد نيتروجين هناخذ عنها شوية بقى في
+
+230
+00:21:38,960 --> 00:21:42,900
+شبط 10 هذه غير متفاعلة Unreactive بالمرة
+
+231
+00:22:04,260 --> 00:22:08,320
+أن أتش أن أتش تو فعله مع هادي وحذف الأكسجين و
+
+232
+00:22:08,320 --> 00:22:13,620
+الناج عمل c double bond n ان أتش c double bond o
+
+233
+00:22:13,620 --> 00:22:18,440
+ان أتش تو دلتا يمكن كان رايحكم شوية لو إنه كان
+
+234
+00:22:18,440 --> 00:22:23,840
+عاكس واحدة من هدول، مش مشكلة، بأي طريقة يُكتب
+
+235
+00:22:23,840 --> 00:22:28,640
+التفاعل وين بيتم على الـ Amid Nitrogen ولا على الـ
+
+236
+00:22:28,640 --> 00:22:32,460
+Hydrazine Nitrogen؟ على الـ Hydrazine نحنا دائماً و
+
+237
+00:22:32,460 --> 00:22:36,200
+أبداً لما نجيبلكم سؤال في الامتحان بنحطه قريب
+
+238
+00:22:36,200 --> 00:22:40,820
+على الـ Amid Nitrogen عشان نشوف كوكبكم تفعلوه على
+
+239
+00:22:40,820 --> 00:22:44,940
+التانية مش على طول تقولوا أنا H2N-C double bond
+
+240
+00:22:44,940 --> 00:22:50,910
+O، نحذف ميه واضح؟ يعني هنا كان كثير أي واحدة بتيجي
+
+241
+00:22:50,910 --> 00:22:56,090
+تأخذ هدول مع بعض وتحذفهم وتعمل double bond احنا
+
+242
+00:22:56,090 --> 00:23:01,070
+بيقول ما بتفعلش على النيتروجين اللي مباشرة جنب ال
+
+243
+00:23:01,070 --> 00:23:03,990
+C double bond O بتفعل على التانية اللي هي ال
+
+244
+00:23:03,990 --> 00:23:07,710
+هيدروجين النيتروجين الآن هذا semi-carbazide شو
+
+245
+00:23:07,710 --> 00:23:13,280
+بيعطيني؟ سيمي كربازون، يعني لو هذا كان مثلاً أسيتون،
+
+246
+00:23:13,280 --> 00:23:19,940
+شو المركب الناتج؟ أسيتون سيمي كربازون، إذن هنا
+
+247
+00:23:19,940 --> 00:23:25,360
+كمان غير الإيمين إيمين، بتكون تضيفوا عندكم تحت،
+
+248
+00:23:25,360 --> 00:23:30,800
+سيمي كربازايد، سيمي كربازون، كل هذه عبارة عن
+
+249
+00:23:30,800 --> 00:23:37,830
+مشتقات الألدهيد والكيتون مع الـ NH2 إذا الـ NH2
+
+250
+00:23:37,830 --> 00:23:41,350
+موجودة على أنواع مختلفة، موجودة على شكل أمين على
+
+251
+00:23:41,350 --> 00:23:46,850
+شكل هيدرازين على شكل أوكسيم على شكل سيمي كربازايد
+
+252
+00:23:46,850 --> 00:23:53,570
+بتعطينا هيدرازون، أوكسيم، إيمين، سيمي كربازون، وأسهل
+
+253
+00:23:53,570 --> 00:23:57,130
+أشياء تطبقوه وتتمنوا أن يجيكم سؤال عليه في
+
+254
+00:23:57,130 --> 00:24:03,390
+الامتحانات، لأن كله عبارة عن أنكم تحذفوا ماء، كله
+
+255
+00:24:03,390 --> 00:24:07,210
+عبارة عن أنكم تحذفوا ماء، ما فيش غلبة غير بحالة
+
+256
+00:24:07,210 --> 00:24:10,910
+واحدة في الـ Semi-Carb ازايد تعرفوا من أي نيتروجين
+
+257
+00:24:10,910 --> 00:24:15,930
+التفاعل بده يتم وأنا بعتقد إنه وضحناها بما فيه
+
+258
+00:24:15,930 --> 00:24:16,470
+الكفاية 
+
+259
+00:24:34,870 --> 00:24:43,310
+بنجي لظاهرة جديدة حقيقة سبق إنها مرت علينا اللي
+
+260
+00:24:43,310 --> 00:24:48,810
+هي ظاهرة الـ keto-enol-tautomerism وين مرت
+
+261
+00:24:48,810 --> 00:24:53,560
+علينا إذا بتذكروا هذه الظاهرة؟ لما كنا نفعل الـ
+
+262
+00:24:53,560 --> 00:24:57,540
+triple bond ونضيف عليهم ماء من خلال الـ mercuric
+
+263
+00:24:57,540 --> 00:25:01,920
+acetate وما إلى ذلك كان يتكون عندي enol كنت أضيف
+
+264
+00:25:01,920 --> 00:25:06,980
+H و OH كنا دائماً نقولكم ال enol هي en يعني
+
+265
+00:25:06,980 --> 00:25:11,560
+double bond ol ألكيل ف enol يعني فيها double
+
+266
+00:25:11,560 --> 00:25:15,760
+bond وفيها ألكيل بتحول إلى ال keto form إيش هذه
+
+267
+00:25:15,760 --> 00:25:19,880
+العملية بيصير فيها حقيقة بيصير فيها نقل إلكترونات
+
+268
+00:25:19,880 --> 00:25:25,310
+ونقل بروتونات يعني الشحنة بتتحرك والبروتينات
+
+269
+00:25:25,310 --> 00:25:29,610
+بتتحرك، لأن هذا البروتون هذا البروتون وين بده ينقل؟
+
+270
+00:25:29,610 --> 00:25:34,650
+بده يجي على ال CH2 وهذا ال double bond بده تيجي
+
+271
+00:25:34,650 --> 00:25:39,330
+هنا فعندي عملية نقل بروتونات ونقل شحنات هذه
+
+272
+00:25:39,330 --> 00:25:44,170
+العملية سمنها احنا Tautomerism وقلنا السهم تبع ال
+
+273
+00:25:44,170 --> 00:25:48,610
+Tautomerism هو الـ double arrows it is an
+
+274
+00:25:48,610 --> 00:25:53,570
+equilibrium process إفرغناها عن ال resonance ال
+
+275
+00:25:53,570 --> 00:25:59,250
+resonance كان بس نقل شحنات أو إلكترونات وكنا
+
+276
+00:25:59,250 --> 00:26:07,130
+بنستعمله أي سهم ال ذكر ال
+
+277
+00:26:07,130 --> 00:26:10,590
+resonance زي البنزين مثلاً لما كنا نعمل فيه
+
+278
+00:26:10,590 --> 00:26:12,930
+resonance نقل الإلكترونات
+
+279
+00:26:15,920 --> 00:26:20,420
+double headed arrows هذا اسمه double headed arrows
+
+280
+00:26:20,420 --> 00:26:24,980
+يعني سهم أبو راسين هذا اسمهم double arrows يعني
+
+281
+00:26:24,980 --> 00:26:29,580
+سهمين double arrow و double headed arrow مرات
+
+282
+00:26:29,580 --> 00:26:33,140
+البعض منكم بيروح بحفظ نص الكلام ويوم ما يجي نسأل
+
+283
+00:26:33,140 --> 00:26:39,020
+في الموضوع مخابط هذا إيش اسمه double headed يعني
+
+284
+00:26:39,020 --> 00:26:44,760
+كم راس له يعني هذا صيني زي التنين في غير التنين
+
+285
+00:26:44,760 --> 00:26:49,430
+له راسين مش كان التنين يكونوا يلو راسين يطيروا سمو
+
+286
+00:26:49,430 --> 00:26:52,990
+وبتقطع راس وبتضرب راس الثاني، اه هذا أسهم أبو
+
+287
+00:26:52,990 --> 00:26:57,150
+راسين البلد فيها كثير أبو راسين وأبو عجلين وتلو
+
+288
+00:26:57,150 --> 00:27:05,590
+كل شيء اه وهذا إيش اسمه double أرز هذا سهمين اللي
+
+289
+00:27:05,590 --> 00:27:10,690
+هو equilibrium أرز اللي هي أسهم الاتزان
+
+290
+00:27:11,910 --> 00:27:16,070
+أسهم الاتزان واضح فالتوتمريزم is an equilibrium
+
+291
+00:27:16,070 --> 00:27:19,490
+process
+
+292
+00:27:19,490 --> 00:27:24,230
+which is indicated by double arrows، no by double
+
+293
+00:27:24,230 --> 00:27:28,410
+arrows، resonance is indicated by double headed
+
+294
+00:27:28,410 --> 00:27:32,550
+arrows، هاي سؤال انصحه غلط، التوتمريزم is
+
+295
+00:27:32,550 --> 00:27:37,680
+indicated by double arrows. Resonance is indicated
+
+296
+00:27:37,680 --> 00:27:41,700
+by double headed arrows. In resonance there is
+
+297
+00:27:41,700 --> 00:27:45,620
+only charge transfer or electron transfer.
+
+298
+00:27:46,260 --> 00:27:51,200
+However, in tautomerism we have transfer of charge
+
+299
+00:27:51,200 --> 00:27:54,720
+and atoms mainly protons.
+
+300
+00:27:57,020 --> 00:28:02,080
+هذه العملية مرت معنا لكن احنا هنا بنذكركم فيها
+
+301
+00:28:02,080 --> 00:28:04,680
+سبق إنه مرت
+
+302
+00:28:08,670 --> 00:28:15,830
+الآن بنجي لنقطة مهمة كثير في كيمياء الألدهيدس
+
+303
+00:28:15,830 --> 00:28:22,570
+والكيتونز وبتعمل نوعاً ما شغلة جديدة في تفاعلاتهم
+
+304
+00:28:22,570 --> 00:28:27,070
+اللي هي بنسميها ال acidity of alpha hydrogen
+
+305
+00:28:27,070 --> 00:28:32,850
+انتبهوا معي موضوع ال acidity ال acidity بشكل عام
+
+306
+00:28:32,850 --> 00:28:36,830
+لو جئنا نذكر فيه إيش كان ال acid؟
+
+307
+00:28:39,290 --> 00:28:46,530
+حسب خلّيني أقول ال Bronsted definition اللي
+
+308
+00:28:46,530 --> 00:28:52,730
+بيفقد بروتون H+ ال acid is the one that loses
+
+309
+00:28:52,730 --> 00:29:01,930
+H+ مش هذا بروتون دونر بيفقد H+ و ال base
+
+310
+00:29:04,240 --> 00:29:09,560
+Proton Acceptor الأن أنواع الـ Acids .. أنواع الـ
+
+311
+00:29:09,560 --> 00:29:13,620
+Acids كتيرة أسهل
+
+312
+00:29:13,620 --> 00:29:20,220
+شيء إنه يكون عندك حامض إنه الـ H Plus لما تفقد زي
+
+313
+00:29:20,220 --> 00:29:25,940
+ما سبق اتكلمت عنه بدا تترك مكانها شحنة سالبة
+
+314
+00:29:25,940 --> 00:29:31,710
+هالشحنة السالبة بدا يكون في قدرة على حملها و لذلك
+
+315
+00:29:31,710 --> 00:29:36,070
+أفضل شيء الأحماض الكربوكسيلية لما تفقد ال H بيصير
+
+316
+00:29:36,070 --> 00:29:42,810
+عندك R C double bond O O- هذه فقدت H مظبوط
+
+317
+00:29:42,810 --> 00:29:46,810
+ولا لأ؟ ليش هذه كانت ثابتة كثير؟ لأنها بتعمل
+
+318
+00:29:46,810 --> 00:29:50,930
+resonance هذه بتتحرك هنا وهذه بتتحرك هنا فشحنة
+
+319
+00:29:50,930 --> 00:29:55,230
+سالمة سهل التعامل معها هذا في الأحماض الكربوكسيلية
+
+320
+00:29:55,230 --> 00:30:00,970
+أخذنا إنه يمكن ال H أن تفقد من إيش كمان؟ من ال
+
+321
+00:30:00,970 --> 00:30:06,070
+alcohols بس من ال alcohols شو بيكونوا أقوى ولا
+
+322
+00:30:06,070 --> 00:30:11,030
+أضعف من الأحماض الكربوكسيلية؟ أضعف لإيش؟ لأنه هنا
+
+323
+00:30:11,030 --> 00:30:16,790
+ما فيش شيء .. resonance الحمض
+
+324
+00:30:16,790 --> 00:30:21,150
+الكربوكسيلي قوي لإيش؟ لأنه يصير minus ب resonance
+
+325
+00:30:21,150 --> 00:30:26,670
+ال alcohol is a weak acid قلنا زي وزي الماء لكن
+
+326
+00:30:26,670 --> 00:30:31,280
+ال alcohol فقد ال proton والحمض الكربوكسيلي فقد
+
+327
+00:30:31,280 --> 00:30:38,780
+بروتون مش هذا في الأساس كان RCH2OH في وجود ال base
+
+328
+00:30:38,780 --> 00:30:47,180
+فقط بروتون وهذا RCH2OH في وجود ال base برضه فقط
+
+329
+00:30:47,180 --> 00:30:52,680
+بروتون الآن هدول أخذناهم أخذنا كمان نوع من الـ ..
+
+330
+00:30:52,680 --> 00:30:55,860
+من الهيدروجينز اللي قلنا عنها بتكون acidic
+
+331
+00:30:55,860 --> 00:30:58,840
+hydrogen مين تتذكرها؟
+
+332
+00:31:02,090 --> 00:31:05,590
+كمان الهيدروجين يمكن أن تفقد في وجود الـ Base
+
+333
+00:31:05,590 --> 00:31:09,410
+وشرحنا عنها المحاضرة الماضية وجبناها سؤال في
+
+334
+00:31:09,410 --> 00:31:13,210
+الامتحان الهيدروجين
+
+335
+00:31:13,210 --> 00:31:20,490
+تبعت الـ terminal الكاين لما بيكون عنده R C triple
+
+336
+00:31:20,490 --> 00:31:24,690
+bond C وهذه الـ H هذه الهيدروجين يمكن أن تفقد في
+
+337
+00:31:24,690 --> 00:31:30,310
+وجود الـ Base وبتعطينا الـ acetylide anion R C
+
+338
+00:31:30,310 --> 00:31:31,450
+triple bond C
+
+339
+00:31:35,040 --> 00:31:39,920
+- إذا كم نوع مر علينا احنا الهيدروجين تبعت
+
+340
+00:31:39,920 --> 00:31:43,560
+الحمض يمكن أن تفقد، تبعت الكحول لكن بيكون weak
+
+341
+00:31:43,560 --> 00:31:46,720
+acid تبعت الـ acetylide تفقد برضه بصعوبة بيبقى
+
+342
+00:31:46,720 --> 00:31:53,020
+strong base الآن بيجي ناخذ النوع الرابع إيش هو
+
+343
+00:31:53,020 --> 00:31:56,580
+النوع الرابع؟ في الـ Ketone و الـ Aldehyde
+
+344
+00:31:56,580 --> 00:32:01,260
+الهيدروجين اللي جنب الـ C double bond O بنقول عنها
+
+345
+00:32:01,260 --> 00:32:06,120
+acidic hydrogen يعني لما نقول هي السيطة بالـ C double bond O
+
+346
+00:32:06,120 --> 00:32:10,360
+أول كربونة بالنسبة لها بيقولوا عنها الـ alpha
+
+347
+00:32:10,360 --> 00:32:15,790
+carbon مش نمر واحد بنستعمله احنا Alpha إذا لما ناخذ
+
+348
+00:32:15,790 --> 00:32:19,130
+احنا هاي الـ C double bond O أول كربونة بالنسبة
+
+349
+00:32:19,130 --> 00:32:23,150
+لها إيش بنقول عنها؟ Alpha Carbon الهيدروجين اللي
+
+350
+00:32:23,150 --> 00:32:26,710
+بتحملها أول كربونة جنب الـ C double bond O بنقول
+
+351
+00:32:26,710 --> 00:32:30,230
+عنها Alpha Hydrogen هذه Alpha Carbon وهذه Alpha
+
+352
+00:32:30,230 --> 00:32:37,190
+Hydrogen الآن الـ Alpha Hydrogen is acidic في وجود
+
+353
+00:32:37,190 --> 00:32:45,050
+strong base بتفقدها هنا نفترض أنه عندما يكون عندك C
+
+354
+00:32:45,050 --> 00:32:51,770
+double bond O نفترض هذا R وهنا عندكم CH وخلّيني
+
+355
+00:32:51,770 --> 00:32:56,610
+أقول كمان H2 هذه الهيدروجين اللي هي بعد الـ C
+
+356
+00:32:56,610 --> 00:33:01,410
+double bond O مباشرة شو بنسميها؟ Alpha-hydrogen
+
+357
+00:33:01,410 --> 00:33:03,790
+هذه بتفقد وبتعطي
+
+358
+00:33:21,940 --> 00:33:26,620
+الألف هيدروجين هو أسيدك هيدروجين
+
+359
+00:33:31,650 --> 00:33:36,450
+عادة بيستخدموا المركب اللي اسمه sodium ethoxide
+
+360
+00:33:48,440 --> 00:33:53,220
+إذا كل هذه عبارة عن أنواع من الـ hydrogens
+
+361
+00:33:53,220 --> 00:33:55,980
+الـ acidic hydrogens اللي في الحمض واللي في
+
+362
+00:33:55,980 --> 00:33:59,700
+الكحول واللي في الـ terminal alkyne والـ alpha
+
+363
+00:33:59,700 --> 00:34:03,940
+hydrogen of aldehydes and ketones، they are
+
+364
+00:34:03,940 --> 00:34:10,150
+acidic إيش بيفرجوا أن أقوى واحدة فيهم؟ تبعت الحمض
+
+365
+00:34:10,150 --> 00:34:13,430
+يعني هذا بـ Sodium Carbonate بتفقد which is a weak
+
+366
+00:34:13,430 --> 00:34:16,890
+base لكن هنا أنا بدي Sodium Metal هنا بدي Sodium
+
+367
+00:34:16,890 --> 00:34:22,350
+Ethoxide يعني هنا بدي strong bases واضح؟ هنا weak
+
+368
+00:34:22,350 --> 00:34:25,450
+base أي حمض اللي حط عليه كربونة بفقد النيتروجين
+
+369
+00:34:25,450 --> 00:34:29,670
+ولا لأ؟ أو بيصير .. حتى لو كان حمض ليمون حطه عليه
+
+370
+00:34:29,670 --> 00:34:33,970
+كربونة بتشوفوه بيصير يعمل bubbling وبفقد الـ .. آه
+
+371
+00:34:33,970 --> 00:34:34,470
+بسهولة
+
+372
+00:34:39,350 --> 00:34:44,290
+فاللي بنقوله إحنا إنه لو اجت أي base بتاخد الـ H
+
+373
+00:34:44,290 --> 00:34:50,450
+هذه لوحدها بدون زوج الإلكترونات وبيبقى زوج
+
+374
+00:34:50,450 --> 00:34:54,510
+الإلكترونات عامل minus على الكربون الآن في واحدة
+
+375
+00:34:54,510 --> 00:35:00,450
+ممكن تسأل طيب هل الكربون يستطيع أن يحمل الشحنة
+
+376
+0
+
+401
+00:37:19,310 --> 00:37:21,030
+الـ carbon على الـ oxygen على الـ carbon على الـ
+
+402
+00:37:21,030 --> 00:37:25,110
+oxygen على الـ carbon اتوزع الحمل هذه عملية إيش الـ
+
+403
+00:37:25,110 --> 00:37:29,030
+resonance إذا هذا زوج الإلكترونات لما يتحرك بهذا
+
+404
+00:37:29,030 --> 00:37:32,650
+الشكل وهذا تصير O minus هذه الـ minus كان هنا على
+
+405
+00:37:32,650 --> 00:37:37,910
+الـ carbon صار على الـ oxygen رايح جاي هذه العملية
+
+406
+00:37:37,910 --> 00:37:43,840
+عملية resonanceهذه العملية عملية Resonance وهي سهم
+
+407
+00:37:43,840 --> 00:37:48,520
+الـ Resonance ولذلك بيصير هنا عملية فقد البروتون
+
+408
+00:37:48,520 --> 00:37:55,040
+الآن هنا فيه جار أساعد معاه؟ مافيش ولذلك هذه
+
+409
+00:37:55,040 --> 00:38:03,660
+العملية لا تتم هنا واضح؟ بتتم بس هنا وهذا يمكن
+
+410
+00:38:03,660 --> 00:38:06,880
+يعني الواحد لما يفلسف الأمور شوية أو يحاول يوضحها
+
+411
+00:38:06,880 --> 00:38:16,550
+أكتر لما تسمع حديث المؤمنين يكمل؟ لأ
+
+412
+00:38:16,550 --> 00:38:20,490
+أنا بدي إيش يخدم موضوعي إعبّر عن إنكم فهمتم
+
+413
+00:38:20,490 --> 00:38:31,970
+الموضوع تماما المؤمن إيش ماله؟ قوي بإيش؟ بإخوانه
+
+414
+00:38:31,970 --> 00:38:38,970
+نبدأ؟ قارنوا دائما المناظر والصور المشتركة يعني
+
+415
+00:38:38,970 --> 00:38:45,610
+الأسد شو اللي خلّاه قوي؟ نفس إمكانية الـ Resonance 
+
+416
+00:38:45,610 --> 00:38:51,910
+مظبوط ولا لا؟ بتلاحظوا كيف المنظر هنا مشترك؟ إذا
+
+417
+00:38:51,910 --> 00:38:59,500
+الـ Acid صار حامض بسبب وجود C double bond O الالكول
+
+418
+00:38:59,500 --> 00:39:04,480
+كانت موازية لإيش؟ للمركبات الثانية، لأنه مافيش جنبها
+
+419
+00:39:04,480 --> 00:39:09,480
+C double bond O اتساعدها طبعا ممكن نجي نسأل سؤال
+
+420
+00:39:09,480 --> 00:39:17,410
+الآن، نقول أنه أقوى كحمض، الـ acid ولا هذا المركب
+
+421
+00:39:17,410 --> 00:39:23,190
+اللي هو CₒO جنبه CH2-  الأسد، عارفين ليش؟ لأنه في
+
+422
+00:39:23,190 --> 00:39:27,510
+النهاية في عندي مساعدة بحمل الـ minus لكن الـ O
+
+423
+00:39:27,510 --> 00:39:33,990
+نفسها كذراع أقدر على حمل الـ minus من الـ carbon ولذلك
+
+424
+00:39:33,990 --> 00:39:38,850
+هنا أنا ممكن بـ base صغيرة أتم عملية فقد لبروتون، بس
+
+425
+00:39:38,850 --> 00:39:44,070
+أنا بدي base قوية واضح؟ يعني هذا الجزء جزء الـ
+
+426
+00:39:44,070 --> 00:39:49,030
+resonance وجزء مشترك لكن بيضل أنه الـ minus هذا
+
+427
+00:39:49,030 --> 00:39:52,410
+يحمل على carbon في نص الـ resonance ولا يحمل على
+
+428
+00:39:52,410 --> 00:39:59,010
+Oxygen؟ وين أفضل؟ يحمل على Oxygen ولذلك الحامض هذا
+
+429
+00:39:59,010 --> 00:40:04,490
+بيكون أقوى من الحامض اللي هو ناشئ عن Alpha
+
+430
+00:40:04,490 --> 00:40:07,510
+Hydrogen أقوى من الحامض اللي ناشئ عن Alpha
+
+431
+00:40:07,510 --> 00:40:08,650
+Hydrogen
+
+432
+00:40:12,700 --> 00:40:16,580
+الآن أطلع بس مهتمش أن الله حب الصابرين والصابرات
+
+433
+00:40:16,580 --> 00:40:22,780
+كمان أن المؤمنين والمؤمنات والصادقين والصادقات
+
+434
+00:40:22,780 --> 00:40:25,740
+والقانتين والقانتات والمنفقين والمنفقات
+
+435
+00:40:25,740 --> 00:40:30,120
+والمستغفرين والمستغفرات والصابرين والصابرات
+
+436
+00:40:30,120 --> 00:40:35,780
+والصادقين والصادقات والصائمين والصائمات أو .. أنا
+
+437
+00:40:35,780 --> 00:40:39,660
+رايح بالصابرة انتبهوا معاه عاد .. الآن بعد إذنكم
+
+438
+00:40:39,660 --> 00:40:45,420
+في المقارنة لما تيجوا تعملوا مثلا مقارنة هنا لـ الـ
+
+439
+00:40:45,420 --> 00:40:51,260
+cane مع acetone يعني مركب فيه سيضا بالبندقو مركب
+
+440
+00:40:51,260 --> 00:40:55,540
+مافيش فيه سيضا بالبندقو اتخيلوا قداش الـ BKA هنا
+
+441
+00:40:55,540 --> 00:41:01,060
+حوالي التسعة عشر هنا تقريبا خمسين إذا هذا أقوى
+
+442
+00:41:02,260 --> 00:41:05,100
+ملايين المطلوب .. لأ لأ مش سالك تقريبا .. هذه
+
+443
+00:41:05,100 --> 00:41:11,300
+تقريبا خمسين مش سالك خمسين .. تقريبا خمسين .. يعني
+
+444
+00:41:11,300 --> 00:41:15,760
+أن هذا ..very very very very weak acid لا يُعتبر
+
+445
+00:41:15,760 --> 00:41:20,160
+acid الألكان اللي تاوه رسمناه تقريباً خمسين فلما
+
+446
+00:41:20,160 --> 00:41:24,180
+تقولوا خمسين للتسعة عشر بتقدروا تحسوا كده الفرق؟
+
+447
+00:41:24,180 --> 00:41:29,360
+بتقدروا تحسوه الآن إذا لو كان هذا carboxylic acid
+
+448
+00:41:29,360 --> 00:41:32,620
+الكربوكسيليك أسد لما تاخدوا الـ acetic acid كده
+
+449
+00:41:32,620 --> 00:41:37,720
+كانت الـ PKA له؟ متذكرينها؟
+
+450
+00:41:39,490 --> 00:41:43,450
+لأ الـKA اللي هي الـ 1.8 في عشرة أس ناقص خمسة الـ
+
+451
+00:41:43,450 --> 00:41:47,170
+BKA أربعة وسبعة بالعشرة أو هيك إشي كتير حاليتوا
+
+452
+00:41:47,170 --> 00:41:52,190
+عليها مثال اتزان لاحظوا الحامض أربعة وسبعة من عشرة
+
+453
+00:41:52,190 --> 00:42:00,930
+هذا تسعة عشر الألكين خمسين شوفتوا كيف اللي هو تدرج
+
+454
+00:42:00,930 --> 00:42:05,670
+الحامضية إذا الحامض أقوى كتير من هذا الحامض حوالي
+
+455
+00:42:05,670 --> 00:42:07,430
+خمسة هذا
+
+456
+00:42:10,730 --> 00:42:15,930
+الالكين بالمرة لا يعتبر حامض إذا بهيك قدرتوا
+
+457
+00:42:15,930 --> 00:42:20,730
+تشوفوا أنتو أن الالفا هيدروجين is an acid لكن
+
+458
+00:42:20,730 --> 00:42:24,610
+weak acid بزامها weak acid الـ base اللي بدها
+
+459
+00:42:24,610 --> 00:42:29,590
+تسحبها it should be a strong base من أنسب الـ bases
+
+460
+00:42:29,590 --> 00:42:34,810
+الـ sodium ethoxide يعني أنا لما بدنا نحط الـ base
+
+461
+00:42:34,810 --> 00:42:36,270
+المناسبة NA
+
+462
+00:42:38,920 --> 00:42:45,280
+السوديوم إثوكسايد بيسحب بروتون من جنب السيضة
+
+463
+00:42:45,280 --> 00:42:49,640
+بالبوند O فالألفا هيدروجين هو الهيدروجين الاسوديكي
+
+464
+00:42:49,640 --> 00:42:54,780
+الأسوديكي الأسوديكي ابنني لحد هان ولكلامي بقية إن
+
+465
+00:42:54,780 --> 00:42:55,240
+شاء الله
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..202658e5e0cae8b35f99a60e5a266e9454335425
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_postprocess.srt
@@ -0,0 +1,2036 @@
+1
+00:00:08,760 --> 00:00:15,860
+اليوم بنكمل في موضوع الأحماض وتحديدا
+
+2
+00:00:15,860 --> 00:00:20,600
+لسه ما زلنا في موضوع تسمية الأحماضالفكرة الأساسية
+
+3
+00:00:20,600 --> 00:00:24,620
+اللي حكيناها المرة الماضية أنه تسمية حامض تسمية
+
+4
+00:00:24,620 --> 00:00:30,240
+حامض بالتم بإضافة المقطع oic acid و بعد هيك شوفي
+
+5
+00:00:30,240 --> 00:00:35,620
+عندنا مجموعات substituents بنذكرها استعرضنا
+
+6
+00:00:35,620 --> 00:00:43,030
+استعرضنا الأحماض من واحد إلىعشرة باسمها ال IUPAC
+
+7
+00:00:43,030 --> 00:00:47,170
+وال common names يمكن هذه ال slide تكون شوية أهم
+
+8
+00:00:47,170 --> 00:00:54,450
+هنا كيف نسمي مركبات مختلفة لأحماض بتحتوي على
+
+9
+00:00:54,450 --> 00:00:57,590
+substituents
+
+10
+00:00:57,590 --> 00:01:03,310
+مثلا في هذا المثال الأول بتلاحظوا أن عندكم حامض
+
+11
+00:01:03,310 --> 00:01:10,730
+بكم كربونةأربعة بيوتانويك أسد لبيوتانويك أسد ع
+
+12
+00:01:10,730 --> 00:01:16,110
+موقع تلاتة في بروم لاحظوا الترقيم من وين بيبدأ من
+
+13
+00:01:16,110 --> 00:01:20,430
+الكاربون اللي حامل السيدة بالبندقه مش من بعيدها لو
+
+14
+00:01:20,430 --> 00:01:24,030
+كنا مرات بنستعمل نظام Alpha و Beta بيكون من اللي
+
+15
+00:01:24,030 --> 00:01:29,970
+بعيدها هذا الحامض واحد اتنين تلاتة اربعة خمسة اذا
+
+16
+00:01:29,970 --> 00:01:36,230
+احنا بنحكي عن بيتانويك أسدعلى تلاتة واربعة داي
+
+17
+00:01:36,230 --> 00:01:41,530
+كلورو وعلى خمسة ع تلاتة واربعة داي كلورو بس تلاتة
+
+18
+00:01:41,530 --> 00:01:47,070
+واربعة داي كلورو بنتانويك أسد طبعا الحامض اللي على
+
+19
+00:01:47,070 --> 00:01:52,150
+البنزين شو اسمه بنزويك أسد إذا هذا بقرا كلورو
+
+20
+00:01:52,150 --> 00:01:59,050
+بنزويك أسد مثل هذا الحامض واحد اتنين لاحظوا أنا
+
+21
+00:01:59,050 --> 00:01:59,570
+عندكم
+
+22
+00:02:05,530 --> 00:02:09,090
+الان المجموعة اللى بيكون حاملها هذا الحامض اي
+
+23
+00:02:09,090 --> 00:02:16,210
+مجموعة اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+24
+00:02:16,210 --> 00:02:16,530
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+25
+00:02:16,530 --> 00:02:17,930
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+26
+00:02:17,930 --> 00:02:19,290
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+27
+00:02:19,290 --> 00:02:19,850
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+28
+00:02:19,850 --> 00:02:25,410
+اثل اثل اثل اثل اثل اثل اثيمكن الأمثلة اللي بعد
+
+29
+00:02:25,410 --> 00:02:30,550
+هنا جزء منها بيحتوي على أكتر من مجموعة وظيفية،
+
+30
+00:02:30,550 --> 00:02:34,290
+يعني غير مجموعة الحامض، ممكن تلاقوا ال keen، ممكن
+
+31
+00:02:34,290 --> 00:02:39,210
+تلاقوا أو أتش، ممكن تلاقوا double bond، وأخدنا
+
+32
+00:02:39,210 --> 00:02:44,450
+احنا أولويات، والحمض تقريبا من أعلى الأولويات
+
+33
+00:02:45,440 --> 00:02:50,860
+المثال الأول بسيط اللي هو 2-bromopropanoic acid و
+
+34
+00:02:50,860 --> 00:02:54,300
+بالمنطق اللي مرات بيستعملوا فيه Alpha هذا منطق
+
+35
+00:02:54,300 --> 00:02:58,700
+common name Alpha-bromo بيستعملوا probionic acid
+
+36
+00:02:58,700 --> 00:03:03,960
+لأنه common name هذا المثال فيه مجموعتين وظيفيتين
+
+37
+00:03:03,960 --> 00:03:10,210
+اللي هو الحامض وال double bondالكين و acid مع بعض
+
+38
+00:03:10,210 --> 00:03:14,790
+الأولوية لمن؟ لل acid فبالترقيم هنبدأ من عند
+
+39
+00:03:14,790 --> 00:03:18,790
+الكاربون تحت ال acid و في التسمية بيبين عند أوك
+
+40
+00:03:18,790 --> 00:03:26,450
+أسد في الآخر طبعا هنا إفروبين أوك أسد ملاحظين
+
+41
+00:03:26,450 --> 00:03:27,030
+انتوا؟
+
+42
+00:03:29,550 --> 00:03:34,890
+الآن هذا السؤال أنه ال acid دائما على الطرف، ال
+
+43
+00:03:34,890 --> 00:03:38,550
+acid دائما على الطرف، بلزمش نحددله موقعه، ليش
+
+44
+00:03:38,550 --> 00:03:44,730
+ماقلناش هنا to a propionic acid؟ هذا هو السؤال
+
+45
+00:03:47,320 --> 00:03:51,200
+مافيش احتمالات لو كنت انا بحكي لو كنت بحكي عن ست
+
+46
+00:03:51,200 --> 00:03:55,900
+ذرات كربون مثلا C double bond OH وعندي ست ذرات
+
+47
+00:03:55,900 --> 00:04:00,000
+كربون واحد اتنين تلات اربعة خمسين افترن ستة الان
+
+48
+00:04:00,000 --> 00:04:06,730
+هنا ممكن تكون ال double bond هناهيكون 2-hexanoic
+
+49
+00:04:06,730 --> 00:04:11,630
+acid ممكن تكون هنا 3-hexanoic acid 4-hexanoic acid
+
+50
+00:04:11,630 --> 00:04:15,570
+5-hexanoic acid هنا فيه احتمالات بس هنا مافيش غير
+
+51
+00:04:15,570 --> 00:04:21,510
+هذا الاحتمال فمع علم ما بنزيدش كلام عليه واضح؟
+
+52
+00:04:21,510 --> 00:04:25,410
+بينما هنا انا مضطر مثل هذا المركب لما بدي اسميه 1
+
+53
+00:04:25,410 --> 00:04:33,310
+2 3 4 5 6 لازم اقول threeهكسين الان ال three بتكون
+
+54
+00:04:33,310 --> 00:04:43,330
+يتحدد موقع ايش ال double bond و بكمل oic acid ال
+
+55
+00:04:43,330 --> 00:04:51,510
+مركب
+
+56
+00:04:51,510 --> 00:04:59,730
+اللي بعده فيه كحول O H O Acid الاولوية لإيشللـ
+
+57
+00:04:59,730 --> 00:05:04,690
+acid في الترقيم هيكون واحد اتنين تلاتة اربعة هيكون
+
+58
+00:05:04,690 --> 00:05:14,630
+three hydroxy butanoic acid لأنه مابنسبوش للكحول
+
+59
+00:05:14,630 --> 00:05:19,850
+ال acid أعلى أولوية من الكحول هذا المركب
+
+60
+00:05:19,850 --> 00:05:24,510
+المجموعتين الوظيفيتين اللي فيه الديهيد و ال acid
+
+61
+00:05:24,510 --> 00:05:26,690
+الديهيد و ال acid
+
+62
+00:05:30,590 --> 00:05:34,790
+بروبانويك أسد على موقع تلاتة الالديهايد لما يكون
+
+63
+00:05:34,790 --> 00:05:40,890
+تعامل كمجموعة شو بنسميها اقزو اتري اقزو بروبانويك
+
+64
+00:05:40,890 --> 00:05:47,010
+أسد ها نفس الاشي واحد اتنين تلاتة اربعة خمسة على
+
+65
+00:05:47,010 --> 00:05:53,370
+موقع اتنين برومو على موقع اتنين برومو وعلى موقع
+
+66
+00:05:53,370 --> 00:05:59,380
+اربعة الكيتون مين له أولوية الكيتون ولا الاسدالاسد
+
+67
+00:05:59,380 --> 00:06:04,020
+فعشان هي كانت بترجع اكزو to promo for اكزو بين
+
+68
+00:06:04,020 --> 00:06:10,160
+تانويك اسد واضح هنا بتلاحظوا امثلة بنتقف فيها اكثر
+
+69
+00:06:10,160 --> 00:06:15,800
+من مجموعة وظيفية والاسد
+
+70
+00:06:15,800 --> 00:06:23,340
+طبعا اولويته عالية يمكن هنا كمان مزيد من الامثلة
+
+71
+00:06:24,680 --> 00:06:28,020
+هذا المثال بسيط لأنه فش ليه غير ال acid و بعدين ال
+
+72
+00:06:28,020 --> 00:06:33,020
+الكلجروكس المهم اتفتشوا على ال longest chain هذا
+
+73
+00:06:33,020 --> 00:06:39,260
+المثال فيه حامض و مجموعة ال amino و مجموعة ال
+
+74
+00:06:39,260 --> 00:06:46,220
+hydroxy 2 amino 3 hydroxybutanoic acid طبعا إله
+
+75
+00:06:46,220 --> 00:06:50,140
+اسم شهرة لأن هذا amino acid بيمر مع الناس في ال
+
+76
+00:06:50,140 --> 00:06:52,840
+biochemistry لثريونين
+
+77
+00:06:53,980 --> 00:06:57,860
+مش موضوع طبعا لو بديجي زي هي تقلكوا سؤال واحد
+
+78
+00:06:57,860 --> 00:07:02,600
+اتنين ثلاثة اربعة المفروض تحددوا هذي R ولا S و هذي
+
+79
+00:07:02,600 --> 00:07:08,060
+R ولا S فزي ما بتلاحظوا ان هنا هو بيقول ان عندنا
+
+80
+00:07:08,060 --> 00:07:15,060
+two S لو بدنا نذكركم هاي موقع اتنين وين اقل مجموعة
+
+81
+00:07:15,060 --> 00:07:21,480
+ال H هذيأنا بتحرك ال nitrogen بعدين الكربون اللي
+
+82
+00:07:21,480 --> 00:07:24,140
+حامله oxygen بعدين الكربون اللي حامله وانا oxygen
+
+83
+00:07:24,140 --> 00:07:30,980
+اذا it seems to R الـH I'm trying to resist to S
+
+84
+00:07:30,980 --> 00:07:35,360
+هذه نفس الاشي لو أننا ناخدها ال box أعلى مجموعة ال
+
+85
+00:07:35,360 --> 00:07:42,680
+O بعدين هذه بعدين هذه أنا بتحرك بهذا الشكل 3S it
+
+86
+00:07:42,680 --> 00:07:51,870
+is 3R not 3S واضح؟هذا مثال بسيط هذا لما تكون
+
+87
+00:07:51,870 --> 00:07:57,170
+مجموعة ال acid على حلقات بنستعمل لها carboxylic
+
+88
+00:07:57,170 --> 00:08:01,690
+acid زي ال aldehyde لما يكون على حلقة إذا بتذكرون
+
+89
+00:08:01,690 --> 00:08:07,150
+ايش كنا بنقول؟ Carb aldehyde هذا بنقول carboxylic
+
+90
+00:08:07,150 --> 00:08:12,350
+acid فيه تنتين شو بيصير عندك؟ Dicarboxylic acid
+
+91
+00:08:12,350 --> 00:08:19,600
+فهذا عبارة عن Cyclohexaneداي كربوكسليك أسد، الداي
+
+92
+00:08:19,600 --> 00:08:23,980
+كربوكسليك أسد وين موجودين؟ تتعتبر أنها دي واحد،
+
+93
+00:08:23,980 --> 00:08:30,020
+اتنين، تلاتة على واحد و تلاتة، وكيف اتجاههم؟
+
+94
+00:08:30,020 --> 00:08:36,100
+تطلعوا على جهة واحدة للأمام، إذا هم سيس سيس وان
+
+95
+00:08:36,100 --> 00:08:42,840
+ثري سايكلوهكسين داي كربوكسليك أسد سيس وان ثري
+
+96
+00:08:42,840 --> 00:08:45,380
+سايكلوهكسين داي كربوكسليك أسد
+
+97
+00:08:57,370 --> 00:09:04,170
+واضح؟ ها نفس الاشي أمثلة إضافية Cyclopentane بحمل
+
+98
+00:09:04,170 --> 00:09:11,270
+acid شو بنا نسميه؟ Cyclopentane carboxylic acid لو
+
+99
+00:09:11,270 --> 00:09:12,530
+كان حامل الديهايد
+
+100
+00:09:15,590 --> 00:09:19,790
+cyclobutane carbaldehyde وهذا Cyclobutane
+
+101
+00:09:19,790 --> 00:09:23,870
+Carboxylic Acid طبعا بتفيه على موقع تلاتة كلورو
+
+102
+00:09:23,870 --> 00:09:28,090
+مجموعة للأمام للخلف أو لفوق و تحت بتستعمله
+
+103
+00:09:28,090 --> 00:09:35,170
+Cystrans Benzoic Acid Parachlorobenzoic Acid Hana
+
+104
+00:09:35,170 --> 00:09:39,590
+Toluic Acid لأن هنا المجموعة من طلوين جاي هذا اسم
+
+105
+00:09:39,590 --> 00:09:45,040
+شهرة لكن ممكن نسميه one two two مثلبنزين
+
+106
+00:09:45,040 --> 00:09:50,540
+كاربوكسليك أسد أو two methyl benzoic acid هذا
+
+107
+00:09:50,540 --> 00:09:54,140
+المركب من النفثالين بتذكروا حلقتين بنزين شو
+
+108
+00:09:54,140 --> 00:09:58,980
+بنسميهم نفثالين لو كان الحامض على هذا الموقع واحد
+
+109
+00:09:58,980 --> 00:10:04,060
+بنسميه one naphthalic acid لما نكون على موقع اتنين
+
+110
+00:10:04,060 --> 00:10:12,570
+two naphthalic acid لو ايجي هنا لأ twoلو حطيت
+
+111
+00:10:12,570 --> 00:10:17,190
+الاصل هنا، شو بدأ أسميه؟ two ولا three؟ بنبدأ من
+
+112
+00:10:17,190 --> 00:10:23,090
+تحت، تصير واحد اتنين، برجع two لو حطيت هنا one،
+
+113
+00:10:23,090 --> 00:10:28,490
+اذا في نفسوق اصل حقيقة عندي بس حامضين منه، يا ال
+
+114
+00:10:28,490 --> 00:10:33,030
+one يا ال two لأن هذا الموقع و هذا و هذا و هذا نفس
+
+115
+00:10:33,030 --> 00:10:37,220
+الشيءو هذا الموقع و هذا و هذا و هذا نفس الشيء يعني
+
+116
+00:10:37,220 --> 00:10:40,720
+لو جبتلكوا نفثالين و قولتلكوا بقى كام حامض بقدر
+
+117
+00:10:40,720 --> 00:10:44,800
+أعمل منه بس حامضين ال one naphthalic acid و ال two
+
+118
+00:10:44,800 --> 00:10:48,740
+naphthalic acid ولو المواقع اتبعتوا كتيرة لكن
+
+119
+00:10:48,740 --> 00:10:55,080
+مواقعه أشمالها متماثلة هذا و هذا و هذا و هذا نفس
+
+120
+00:10:55,080 --> 00:11:02,000
+الموقع هذا و هذا و هذا و هذا نفس الموقع واضح؟
+
+121
+00:11:05,190 --> 00:11:09,950
+مي كان بدو يسأل هان؟ لا
+
+122
+00:11:09,950 --> 00:11:17,430
+لا دائما في الحلقات، دائما في الحلقات التارقية، في
+
+123
+00:11:17,430 --> 00:11:20,230
+الحلقة البطاسية اللي هيك بتسمى viewsdrags اللي
+
+124
+00:11:20,230 --> 00:11:21,830
+بيجي من الموقع اللي جامبل
+
+125
+00:11:28,730 --> 00:11:32,410
+مثلًا، اللي قبل هذا، هم .. هم .. هم .. هم .. هم ..
+
+126
+00:11:32,410 --> 00:11:32,810
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+127
+00:11:32,810 --> 00:11:34,890
+.. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم ..
+
+128
+00:11:34,890 --> 00:11:36,030
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+129
+00:11:36,030 --> 00:11:43,150
+.. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم ..
+
+130
+00:11:43,150 --> 00:11:46,250
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+131
+00:11:46,250 --> 00:11:46,310
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+132
+00:11:46,310 --> 00:11:56,250
+.. هم .. هم .. هم .. هم .. هم ..
+
+133
+00:11:56,250 --> 00:12:02,260
+همالـ D مش حرف علة فليش .. ها هي السؤالة تحديداً
+
+134
+00:12:02,260 --> 00:12:10,920
+هنا أن هذا حرف ال E موجود طبعا ليش احنا ماحذفنوش
+
+135
+00:12:10,920 --> 00:12:15,520
+لأنه بعده D بعده مش حرف علة بس مثلا لما بيكون عندى
+
+136
+00:12:15,520 --> 00:12:18,720
+دائما فعلا أنا دي قاعدة في الكيميا لما بيكون عندى
+
+137
+00:12:18,720 --> 00:12:23,740
+حرفين علة ورا بعض بحذف الأول منهم بنحذف الأول من
+
+138
+00:12:23,740 --> 00:12:27,180
+حرفين العلة واضح؟
+
+139
+00:12:31,240 --> 00:12:35,540
+هي كتيرة الأمثلة هيك لكن بلاش نطلع منكم أو نطلع عن
+
+140
+00:12:35,540 --> 00:12:41,060
+الموضوع تبعنا يعني مثلا لو بدكم تقولوا ISO oxazole
+
+141
+00:12:41,060 --> 00:12:46,380
+for example أو oxazole
+
+142
+00:12:46,380 --> 00:12:50,680
+اصلها oxazole
+
+143
+00:12:50,680 --> 00:12:52,160
+مثلا هذا مُركّب الآن
+
+144
+00:12:57,210 --> 00:13:01,170
+بشير الأولى دى قاعدة عامة بس هنا مافيش عندى التقاء
+
+145
+00:13:01,170 --> 00:13:10,010
+حرفى أو التقاء حرفى الا طبعا
+
+146
+00:13:10,010 --> 00:13:16,010
+طبعا طبعا طبعا alphabetical الان بننتقل ل ال die
+
+147
+00:13:16,010 --> 00:13:21,210
+acids احنا قولنا ان اى سلسلة عادية ممكن يكون لها
+
+148
+00:13:21,210 --> 00:13:25,390
+طرفين و احيانا ممكن يكونوا اكثر من طرفين طبعا الان
+
+149
+00:13:26,520 --> 00:13:32,000
+لو على الطرفين كان عندى حامض بيصير عنده داي أسد
+
+150
+00:13:32,000 --> 00:13:35,260
+يعني مثلا هنا هي carbon و carbon و هنا في عندى
+
+151
+00:13:35,260 --> 00:13:40,400
+حامض و حامض ايش صار عندى؟ داي أسد هي carbon تنتين
+
+152
+00:13:40,400 --> 00:13:46,360
+تلاتة حامض و carbon و حامض داي أسد هنا داي أسد
+
+153
+00:13:46,360 --> 00:13:50,160
+أربعة داي أسد خمسة الان هدولة لما بدنا نسميهم كم
+
+154
+00:13:50,160 --> 00:13:55,360
+بنسميهم بنعد كم carbon عندنا تنتين تنتين يعني ايش؟
+
+155
+00:13:55,990 --> 00:14:02,150
+ethane اذا بنقول ايثان او ايثان دايووك اسد اثان
+
+156
+00:14:02,150 --> 00:14:08,010
+داي اووك اسد لانه للاسد احنا بنحط ال اووك هنا عندي
+
+157
+00:14:08,010 --> 00:14:14,310
+تلاتة شو بيصير اسم المركب؟ بروبين داي اووك كل
+
+158
+00:14:14,310 --> 00:14:18,830
+هدولة داي اووك اسد فيهم حامضين على الجانب هنا عندي
+
+159
+00:14:18,830 --> 00:14:23,350
+اربعة بيوتين داي اووك اسد بنتين داي اووك اسد
+
+160
+00:14:23,350 --> 00:14:30,450
+هيكسين داي اووك اسدواضح؟ الآن هذا بمنعش أن هؤلاء
+
+161
+00:14:30,450 --> 00:14:35,310
+الأحماض لهم أصل أول ما اكتشفوهم وأخرجوهم من مصادر
+
+162
+00:14:35,310 --> 00:14:39,270
+أحيانا نباتية أحيانا حيوانية وبالتالي لهم أسماء
+
+163
+00:14:39,270 --> 00:14:45,550
+شهرة وأسماء الشهرة غالبا مرتبطة بالعائلات
+
+164
+00:14:45,550 --> 00:14:48,790
+الاستخراجوها منها مثلا الحمض الأول بيسموه oxalic
+
+165
+00:14:48,790 --> 00:14:56,130
+acid من نبات سوريلالأوكزاليك family التاني مالونك
+
+166
+00:14:56,130 --> 00:15:08,150
+أسد من المالون التالت التالت
+
+167
+00:15:08,150 --> 00:15:14,070
+ساكسينك أسد الغابع غلوتاريك أسد خمس ضرات كربون
+
+168
+00:15:14,070 --> 00:15:23,800
+غلوتاريك أسد ستة أديبك أسد7 بيملك acid على أي حال
+
+169
+00:15:23,800 --> 00:15:29,800
+الصعب طبعا انكوا تحفظوا ال common names لكن السهل
+
+170
+00:15:29,800 --> 00:15:33,660
+انكوا تعرفوا ال IUPAC names واضح فال IUPAC names
+
+171
+00:15:33,660 --> 00:15:38,780
+مرات كتيرة أسهل للطلاب هذا بمنعش انه لو الناس
+
+172
+00:15:38,780 --> 00:15:41,980
+اتخصصت كيميا و مع طول الفترة لما نقول مثلا ايش ال
+
+173
+00:15:41,980 --> 00:15:48,200
+adipic acid الحامض السوداسي اللي بيطولوا منهاللي
+
+174
+00:15:48,200 --> 00:15:53,340
+بيصنعوا منهم نيلون أساس صناعة النيلون الاديوك أسد
+
+175
+00:15:53,340 --> 00:15:59,640
+عليحال كل هذه أمثلة زي ما قلنا لما يكونوا أربعة شو
+
+176
+00:15:59,640 --> 00:16:06,480
+بنسميهم؟ الـ butyldioic acid الأن لاحظوا لو عندي
+
+177
+00:16:06,480 --> 00:16:11,240
+أربعة و فيهم ال triple bond شو بدي أسمي في هذه
+
+178
+00:16:11,240 --> 00:16:11,880
+الحالة؟
+
+179
+00:16:14,280 --> 00:16:19,320
+بدي أحطها لل triple bond آين فبدي أصبح ابيوتاين
+
+180
+00:16:19,320 --> 00:16:27,640
+dioic acid الان هل بلزم ان احدد موقع لل آين في هذه
+
+181
+00:16:27,640 --> 00:16:32,600
+الحالة لأ بس في حالات تانية لو المراكب كبير بلزم
+
+182
+00:16:32,600 --> 00:16:36,180
+احدد موقع يعني مثلا لو كان عندى ست ذرات كربون او
+
+183
+00:16:36,180 --> 00:16:41,680
+سبعة واحد اتنين تلات اربع خمس ست سبعة وحطيت هنا
+
+184
+00:16:41,680 --> 00:16:50,700
+حامضوحطيت هنا حامض هذا صار هبتين
+
+185
+00:16:50,700 --> 00:16:55,920
+ديويك أسد الان لو حطيتي triple point ممكن تكون هنا
+
+186
+00:16:55,920 --> 00:17:03,580
+ممكن تكون هنا واضح فبالتالي كام هبتين ديويك أسد
+
+187
+00:17:03,580 --> 00:17:09,720
+ممكن في هذه الحالة انا
+
+188
+00:17:09,720 --> 00:17:13,590
+لو جبتلكوا هذا يعني قولتلكوا بسؤالHow many
+
+189
+00:17:13,590 --> 00:17:18,950
+heptadioic acids are possible؟ طيب، إيه كويس،
+
+190
+00:17:18,950 --> 00:17:30,230
+خلّيني أقول هذا ال two heptadioic
+
+191
+00:17:30,230 --> 00:17:33,670
+acids، إيه كويس؟ لو إجت هنا
+
+192
+00:17:53,670 --> 00:18:04,430
+بعدين لو مشيناها كمان مرة طب لو عدينا من هنا بس
+
+193
+00:18:04,430 --> 00:18:10,380
+مركبين بس مركبينلأنه بقدر أعد من الجهتين يعني مش
+
+194
+00:18:10,380 --> 00:18:14,860
+أربعة أو خمس زي من بعض بتخيلها بس مركبين ال two
+
+195
+00:18:14,860 --> 00:18:18,820
+-heptane-dioic acid و ال three-heptane-dioic acid
+
+196
+00:18:18,820 --> 00:18:22,320
+واضح؟ هذا ماجيش بعده four من هنا يعني أنا صح بقدر
+
+197
+00:18:22,320 --> 00:18:26,520
+أقول one, two, three, four بس في عندي عد تاني one,
+
+198
+00:18:26,680 --> 00:18:31,750
+two, three، أن هو الأولى؟دائما ال lower numbering
+
+199
+00:18:31,750 --> 00:18:36,690
+اللي هي فيها أرقام قليلة فهذه الأشياء يعني دائما
+
+200
+00:18:36,690 --> 00:18:42,890
+ينتبهوا إليها الآن ممكن مع البيوتين يكون .. مع
+
+201
+00:18:42,890 --> 00:18:48,810
+البيوتين يكون بيوتين بمعنى double bond مش triple
+
+202
+00:18:48,810 --> 00:18:53,720
+bondلاحظوا في حالة الـ double bond بتجيني ظاهرة
+
+203
+00:18:53,720 --> 00:18:56,320
+غير موجودة في الـ triple bond اللي هي ظاهرة الـ
+
+204
+00:18:56,320 --> 00:18:59,880
+cis و الـ trans ال triple bond linear اتفقنا احنا
+
+205
+00:18:59,880 --> 00:19:04,420
+ان ال triple bond linear دائما حوالين ال triple
+
+206
+00:19:04,420 --> 00:19:10,440
+bond ازاوي كدهش؟ 180 يعني اي جزء ولو هنا تنور اسمه
+
+207
+00:19:10,440 --> 00:19:16,530
+اكمال لكن حقيقة اي جزءدبل بوند هو عبارة عن linear
+
+208
+00:19:16,530 --> 00:19:20,530
+molecule بس لما بيصير عندي double bond و بيكونها
+
+209
+00:19:20,530 --> 00:19:24,130
+مجموعات مختلفة و مع المجموعات مختلفة بيصير عندي
+
+210
+00:19:24,130 --> 00:19:29,090
+إمكانية لظاهراتالـ cis والـ trans فلو إجينا على
+
+211
+00:19:29,090 --> 00:19:34,790
+هذا الحامض اللي هو الـ 2-butyldioic acid أو الـ
+
+212
+00:19:34,790 --> 00:19:40,010
+butyldioic acid واطلعنا على مجموعات الحامض هنا كيف
+
+213
+00:19:40,010 --> 00:19:46,330
+اتجاهها؟ في عنده cis وفي عنده trans في عنده cis
+
+214
+00:19:46,330 --> 00:19:55,210
+وفي عنده trans الآن الـ cis بيسموه malic acidالسس
+
+215
+00:19:55,210 --> 00:20:03,750
+شو بيسموه ماليك أسد والترانس اثيومارك أسد لاحظوا
+
+216
+00:20:03,750 --> 00:20:09,610
+بدياكم اتميزوه عن التلات كربونات اسمها مالونك في
+
+217
+00:20:09,610 --> 00:20:13,150
+التلات كربونات الاسم ال common malonic الآن هنا
+
+218
+00:20:13,150 --> 00:20:23,200
+الاسم ماليك ماليك أسد الآن الترانس منهfumeric acid
+
+219
+00:20:23,200 --> 00:20:29,340
+هدولة حقيقة الإسمين جايين من أسماء التفاح وبعض
+
+220
+00:20:29,340 --> 00:20:34,520
+الأعشاب اللاتينة من الأحماض الشهيرة ولمفصولة
+
+221
+00:20:34,520 --> 00:20:38,780
+الزمان وإذا حتى يعني مش مصدقين إذا ناس اشتروا كتاب
+
+222
+00:20:38,780 --> 00:20:43,320
+ال organ الchemistryبلاحظوا أن صفحة الغلاف تبعته
+
+223
+00:20:43,320 --> 00:20:47,620
+مرسوم عليها تفاحة خضرة لأن التفاحة الخضرة أو
+
+224
+00:20:47,620 --> 00:20:52,000
+التفاح أساس هذا الحامض شايفين التفاحة اللي هيك
+
+225
+00:20:52,000 --> 00:20:57,700
+خضرة عصفار اللي اشتروا الكتاب Malic and fumaric
+
+226
+00:20:57,700 --> 00:21:02,080
+acid طبعا الماليك و ال fumaric acid أسماء common
+
+227
+00:21:02,080 --> 00:21:08,500
+names مطلوب نحفظهم بالذات هدولةوبتايالي مرات في
+
+228
+00:21:08,500 --> 00:21:11,560
+تجربة في المختبر بيمروا عليك وماعرفش إذا أخدت
+
+229
+00:21:11,560 --> 00:21:15,520
+ماليكوفيوماريك
+
+230
+00:21:15,520 --> 00:21:19,460
+أسد المفروض في طالبة organic تحفظهم الآن لما بيكون
+
+231
+00:21:19,460 --> 00:21:25,240
+عنده حامضين على البنزين بيستعملوا إذا كانوا على
+
+232
+00:21:25,240 --> 00:21:29,300
+الـ orthoposition of phthalic acid على الميتا
+
+233
+00:21:29,300 --> 00:21:39,540
+ايزوفتاليك أسد وعلى ال باراتيريفتاليك أسدواضح؟ إذا
+
+234
+00:21:39,540 --> 00:21:43,860
+فى عندى الـPhthalic Acid و الـIso-Phthalic Acid و
+
+235
+00:21:43,860 --> 00:21:48,760
+الـTere-Phthalic Acid أقل تقدير لازم تكونوا عارفين
+
+236
+00:21:48,760 --> 00:21:51,780
+و حافظين الـPhthalic Acid لأنه بعد شوية هتتعلموا
+
+237
+00:21:51,780 --> 00:21:56,160
+أنه الـMalic Acid و الـPhthalic Acid بنعمل منهم
+
+238
+00:21:56,160 --> 00:22:00,680
+Unhydrates بينما بنعملهم مش من مركبات تانية يعني
+
+239
+00:22:00,680 --> 00:22:07,260
+هدول المركبات تحديدة الـMalic Acidو ال ethylic
+
+240
+00:22:07,260 --> 00:22:11,120
+acid لما ناخد ال unhydrates هنتعلم انه they can
+
+241
+00:22:11,120 --> 00:22:15,020
+form unhydrates ممكن يعملوا unhydrates التاليين
+
+242
+00:22:15,020 --> 00:22:20,520
+مابيعملوش بس هدول المركبين في عامل مشترك بينهم انه
+
+243
+00:22:20,520 --> 00:22:25,360
+they can form unhydrates يعني بيفقدوا الميه و
+
+244
+00:22:25,360 --> 00:22:30,000
+بيعملوا شكل معين لما ناخد ال unhydrates بنركز عليه
+
+245
+00:22:30,000 --> 00:22:30,380
+اكثر
+
+246
+00:22:52,220 --> 00:22:57,060
+الآن نجي لـPhysical Properties of Acids زي ما
+
+247
+00:22:57,060 --> 00:23:02,020
+اتفقنا أننا عادة بناخد العائلات العضوية تسمية،
+
+248
+00:23:02,020 --> 00:23:08,660
+خواص، تحضير، تفاعلات، واضح؟ دائما تسمية، خواص،
+
+249
+00:23:08,660 --> 00:23:14,360
+تحضير، تفاعلات، هذا اللي بنمشي عليه أهم شغلة بتميز
+
+250
+00:23:14,360 --> 00:23:19,820
+الأحمد قصة حقيقة الـhydrogen bondingيعني الـ
+
+251
+00:23:19,820 --> 00:23:23,020
+hydrogen bonding اللي هي الـ H اللي موجودة على
+
+252
+00:23:23,020 --> 00:23:26,360
+القهة دي مهمة كتير ممكن يعملوا hydrogen bonding
+
+253
+00:23:26,360 --> 00:23:30,700
+بطرق كثيرة وفعلا ممكن نطلع على حامضين كيف بيعملوا
+
+254
+00:23:30,700 --> 00:23:37,420
+hydrogen bonding يعني هذا يعتبر حامض وهذا يعتبرحمض
+
+255
+00:23:37,420 --> 00:23:43,020
+تاني لاحظوا بين هذه ال H و ال O في الرابط ال .. ال
+
+256
+00:23:43,020 --> 00:23:47,220
+dash المقطعة هذه عبارة عن hydrogen bond وهنا في
+
+257
+00:23:47,220 --> 00:23:52,060
+كمان hydrogen bond هذا الكلام بيقدي إلى إيش؟ بيقدي
+
+258
+00:23:52,060 --> 00:23:57,820
+إلى إن ال boiling point لهذه الأحماض تصير مرتفعة
+
+259
+00:23:57,820 --> 00:24:01,420
+جدا لأنها عاملة intramolecular forces فإذا بتطلع
+
+260
+00:24:01,420 --> 00:24:09,010
+مثلا على ال formic acid أبسط حامضمية واحد قارنوا
+
+261
+00:24:09,010 --> 00:24:12,270
+انتوا بالميثان اللي هو كربونا واحدة بس فيش فيه
+
+262
+00:24:12,270 --> 00:24:15,230
+hydrogen bonding ناجس مية وستين يعني الفرق بينهم
+
+263
+00:24:15,230 --> 00:24:20,030
+حوالي مائتين وستين درجة ايش اللي خلي هذا يكون
+
+264
+00:24:20,030 --> 00:24:25,470
+مرتفع جدا زي وزي الميه تقريبا الacetic acid مية و
+
+265
+00:24:25,470 --> 00:24:32,930
+تمانتعاشالاسيتك أسد 118 عالي جداً لما أجيب روبانوك
+
+266
+00:24:32,930 --> 00:24:43,770
+أسد 141، 164، 205 زي ما بتلاحظوا أنه ال
+
+267
+00:24:43,770 --> 00:24:48,650
+boiling point عالية ال solubility تقريبا نفس
+
+268
+00:24:48,650 --> 00:24:52,290
+الفكرة اللي حكيناها في ال alcohols أن ال lower
+
+269
+00:24:52,290 --> 00:24:57,180
+acids are solubleليش؟ لأنه بيكون متغلب فيهم جانب
+
+270
+00:24:57,180 --> 00:25:03,260
+الـOH لكن لما الحمض بيكبر زي الـ hexanoic acid
+
+271
+00:25:03,260 --> 00:25:08,440
+بيصير جزء الـOH هذا اللي هو جزء الذوبان في الميه
+
+272
+00:25:08,440 --> 00:25:12,840
+أو الـhydrophilic اللي بيدوب في الميه مقارنة
+
+273
+00:25:12,840 --> 00:25:20,250
+بالجزء اللي بيدوبش في الميه هذاو لذلك الأحماط
+
+274
+00:25:20,250 --> 00:25:24,010
+الصغيرة زي ال formic acid و ال acetic acid و ال
+
+275
+00:25:24,010 --> 00:25:27,910
+propanoic acid و ال butanoic acid هم سوليوبيلين
+
+276
+00:25:27,910 --> 00:25:31,290
+لما أجعل الhexanoic acid بلاحظة السوليوبيلية واحد
+
+277
+00:25:31,290 --> 00:25:35,430
+جرام في كل مائة من الميه خلاص بيبطل يدوب تقريبا
+
+278
+00:25:36,450 --> 00:25:42,550
+ليش؟ لأنه بيصير ال non-polar part أكبر كتير من ال
+
+279
+00:25:42,550 --> 00:25:48,690
+polar part فهذه الأحماض مكونة من شغلتين، non-polar
+
+280
+00:25:48,690 --> 00:25:54,850
+part و polar part واضح؟ فبالأحماض الصغيرة ال polar
+
+281
+00:25:54,850 --> 00:25:59,030
+part غالب، بالأحماض الكبيرة ال non-polar part
+
+282
+00:25:59,030 --> 00:26:04,230
+affects the solubility and makes them insoluble in
+
+283
+00:26:04,230 --> 00:26:11,740
+waterهذا بالنسبة للـ boiling point بالنسبة للـ
+
+284
+00:26:11,740 --> 00:26:20,340
+solubility تبتيجي شغلة بالنسبة للـ acidity
+
+285
+00:26:20,340 --> 00:26:25,220
+الحامضية بتهيألي احنا لما حكينا على ال alcohols
+
+286
+00:26:25,220 --> 00:26:30,060
+اكثر من مرة ركزنا على ال acidity قولنا ان هدول
+
+287
+00:26:30,060 --> 00:26:34,100
+الأحماض بالنسبة لل alcohols تعتبر ال acidity
+
+288
+00:26:34,100 --> 00:26:39,230
+تبعتهمأعلى بكتير يعني ال alcohol ال BKA كداش كان
+
+289
+00:26:39,230 --> 00:26:45,530
+تقريبا 17 و 18 و 16 الأحماض زي ال acetic acid
+
+290
+00:26:45,530 --> 00:26:51,690
+أربعة و خمسة فهدولة أعلى كتير كتير من ال alcohol
+
+291
+00:26:51,690 --> 00:26:55,410
+في ال acidity شو هو السبب أنهم أعلى كتير كتير من
+
+292
+00:26:55,410 --> 00:26:59,370
+ال alcohol في ال acidity أنه لما بيفقد هذا ال
+
+293
+00:26:59,370 --> 00:27:03,170
+proton لما بيفقد هذا ال proton في عنده هنا ال
+
+294
+00:27:03,170 --> 00:27:08,410
+minus chargeممكن تكون على هذه الأكسجينة و ممكن تلف
+
+295
+00:27:08,410 --> 00:27:12,590
+بهذا الشكل وتصير على الأكسجينة التانية إذا السبب
+
+296
+00:27:12,590 --> 00:27:18,100
+هو ال resonanceواضح؟ الـ stability لـ negative ion
+
+297
+00:27:18,100 --> 00:27:22,360
+is due to resonance stability of the negative ion
+
+298
+00:27:22,360 --> 00:27:27,720
+is due to resonance فال acids they are .. يعني
+
+299
+00:27:27,720 --> 00:27:32,260
+their acidity is high due to resonance هذه الفكرة
+
+300
+00:27:32,260 --> 00:27:37,040
+الأساسية لما بدأ اقارن أنا حامض بكحول يعني لما بدأ
+
+301
+00:27:37,040 --> 00:27:42,320
+اقارن مثلا الاثانون بيعمل الايون الـ minus CH2 O
+
+302
+00:27:42,320 --> 00:27:51,820
+minus CH3مع الـ acid C double bond O O minus CH3
+
+303
+00:27:51,820 --> 00:27:58,960
+هنا ال BKA تقريبا كانت لإيثانول 17 هنا ال BKA
+
+304
+00:27:58,960 --> 00:28:04,940
+أربعة و نص واضح؟ ليه شد أعلى بكتير من هذا؟لأن هنا
+
+305
+00:28:04,940 --> 00:28:09,500
+الـ charge بيقول عنها localized يعني متموضعة في
+
+306
+00:28:09,500 --> 00:28:14,140
+مكانها، ما بتتغيرش زي واحد حامل شغلة طول الطريق
+
+307
+00:28:14,140 --> 00:28:17,780
+بإيد واحدة، شو بيصير له إيده؟ بتتعب، لكن واحد عنده
+
+308
+00:28:17,780 --> 00:28:22,880
+إتين، بيكون بيعمل resonance فهنا عندي localized
+
+309
+00:28:22,880 --> 00:28:28,280
+charge وهنا في عند الـcharged إيش بتكون؟
+
+310
+00:28:28,280 --> 00:28:32,650
+Delocalized مرة هناو مرة هنا يعني هذا ال resonance
+
+311
+00:28:32,650 --> 00:28:38,970
+structure التاني تبعه كيف بده يكون CH3C
+
+312
+00:28:38,970 --> 00:28:44,550
+لو حركنا هذا ال minus هيك وهذه هنا بهذا الشكل O
+
+313
+00:28:44,550 --> 00:28:48,750
+minus double bond O فزي ما بتلاحظوا ال minus هذه
+
+314
+00:28:48,750 --> 00:28:52,590
+مرة موجودة على هذه ال oxygen مرة موجودة على هذه ال
+
+315
+00:28:52,590 --> 00:28:55,370
+oxygen فال minus charge is
+
+316
+00:29:00,220 --> 00:29:03,860
+والـ Delocalization هو أحد أسباب الـ stability of
+
+317
+00:29:03,860 --> 00:29:08,720
+its charge دايما، زي ما قلنا، الحمل إذا توزع،
+
+318
+00:29:08,720 --> 00:29:12,940
+ينشد، هملاحظين؟ هذه محمولة على جهتين الـ negative
+
+319
+00:29:12,940 --> 00:29:16,640
+charge مش على جهة واحدة، Delocalized وبالتالي، الـ
+
+320
+00:29:16,640 --> 00:29:20,940
+Ion السالب تبات وبيزيد، الحامض بيصير أقوى هذا
+
+321
+00:29:20,940 --> 00:29:26,950
+الكلام، لو أنا كنت بقارن حامضمع كحول، لو كنت بقارن
+
+322
+00:29:26,950 --> 00:29:36,170
+حامض مع كحول، لكن في .. وعشانك لاحظوا في الأحمار
+
+323
+00:29:36,170 --> 00:29:45,370
+بشكل عام لما تتطلعوا على ال BKA معظمها
+
+324
+00:29:45,370 --> 00:29:51,720
+في منطقة التلاتة والاربعة، واضح؟أتنين، أربع، أربع،
+
+325
+00:29:51,720 --> 00:29:55,840
+أربع، تلاتة، اتنين، واطفر، فمعظمها بينما لو بدأ
+
+326
+00:29:55,840 --> 00:30:02,820
+أقارن بالإيثانول والميّه هذا كحول تقريبا، وهذا
+
+327
+00:30:02,820 --> 00:30:09,260
+ميّه 16 و15، واضح؟ الفينول بدأ يصير فيه resonance
+
+328
+00:30:09,260 --> 00:30:13,900
+بس ال resonance على أكسوجين و Carbon بينزل لعشرة،
+
+329
+00:30:13,900 --> 00:30:19,050
+لكن وين مافيش resonance نهائيهدولة التلين اللي تحت
+
+330
+00:30:19,050 --> 00:30:23,730
+الاثانون والمي مافيش إمكانية وبالتالي هدولة
+
+331
+00:30:23,730 --> 00:30:27,790
+بنلاقيهم إحنا إيش في دايل الخيبة بينما بشكل عام
+
+332
+00:30:27,790 --> 00:30:36,670
+الأحماض كلهم لهم PKA عالية due to resonance PKA
+
+333
+00:30:36,670 --> 00:30:41,610
+منخفضة acidity عالية ماكل ما ال PKA نزلت الحمضية
+
+334
+00:30:41,610 --> 00:30:46,520
+أقوى بيكون ال K a أعلىوهذا الـ Resonance بتايل
+
+335
+00:30:46,520 --> 00:30:50,700
+المرض حانة بشكل جيد الان اذا يتبع هذا الـ
+
+336
+00:30:50,700 --> 00:30:56,890
+Resonance نقطةإنه في نفس الحامض في نفس الحامض لو
+
+337
+00:30:56,890 --> 00:31:01,470
+حطيت electron with a drawing group أو electron
+
+338
+00:31:01,470 --> 00:31:05,530
+donating group شو بتأثر على ال acidity؟ يعني مثلا
+
+339
+00:31:05,530 --> 00:31:10,570
+هي ال acidic acid وفي resonance طب لو حطيت
+
+340
+00:31:10,570 --> 00:31:15,470
+chloroacetic acid و بعدك حطيت dichloroacetic acid
+
+341
+00:31:15,470 --> 00:31:19,690
+و بعدك حطيت trichloroacetic acid و سؤالتك which is
+
+342
+00:31:19,690 --> 00:31:26,830
+more acidic؟الـ trichloroacetic acid في عملية
+
+343
+00:31:26,830 --> 00:31:31,930
+electron withdrawing يعني في inductive effect
+
+344
+00:31:31,930 --> 00:31:36,910
+فلاحظوا هنا لما أنا بحكي عن الـ acetic acid هذا
+
+345
+00:31:36,910 --> 00:31:43,210
+التنقل اللي هنا شو احنا سميناه؟ resonance effect
+
+346
+00:31:43,210 --> 00:31:47,390
+الآن هذا ال resonance موجود فيهم كلهم إن زاد على
+
+347
+00:31:47,390 --> 00:31:54,130
+ال resonance ال resonance ما زال موجودزاد عليه الـ
+
+348
+00:31:54,130 --> 00:31:58,210
+inductive effect إنه فيه مجموعة بتسحب الإلكترونات
+
+349
+00:31:58,210 --> 00:32:02,570
+بتساعد في حمل الإلكترونات فصار عندي تأثيرين صار
+
+350
+00:32:02,570 --> 00:32:07,030
+عندي بدل التأثير اتنين inductive effect plus
+
+351
+00:32:07,030 --> 00:32:11,370
+resonance effect وبالتالي هذا الحامض اللي هو الـ
+
+352
+00:32:11,370 --> 00:32:16,130
+trichloroacetic acid بتكون ال acidity تبعته أقوى
+
+353
+00:32:16,130 --> 00:32:22,560
+كتير منمن الاسيتك أسد او من ال .. طبعا لو اجيتوا و
+
+354
+00:32:22,560 --> 00:32:26,660
+قارنتوا ال trifluoroacetic acid مع ال trichloro ال
+
+355
+00:32:26,660 --> 00:32:31,400
+trifluoro أقوى كتير ماعرفش اذا انا حاطينلكم هاي
+
+356
+00:32:31,400 --> 00:32:35,780
+القيم هنا لما بدكم تحديدا للاسيتك أسد مع ال
+
+357
+00:32:35,780 --> 00:32:39,920
+trichloroacetic acid ان هو اللي قولنا عنه أعلى
+
+358
+00:32:39,920 --> 00:32:44,340
+واحد هاي ال trichloroacetic acid شايفينه؟ و هاي ال
+
+359
+00:32:44,340 --> 00:32:50,230
+acidic acid ال acidic acid four point7.4 لـ
+
+360
+00:32:50,230 --> 00:32:56,470
+Trichloroacetic acid 0.7 ملاحظين قداش صار أقوى
+
+361
+00:32:56,470 --> 00:33:01,150
+كحمض بالتالي لو بدو ييجي على الإدل ولا إش بدو
+
+362
+00:33:01,150 --> 00:33:04,770
+يحرقهم ال Acetic acid بحرق الإدل بس لما يكون مخفف
+
+363
+00:33:04,770 --> 00:33:09,590
+بمية ممكن الناس يعني ييجي على الإدل إذا في جرح
+
+364
+00:33:09,590 --> 00:33:13,710
+بيحرق بس إذا خفف بمية كتير بيمسكون الناس اللي خلوه
+
+365
+00:33:13,710 --> 00:33:19,380
+بيشربوه كمان بالمناسبةبس لازم يكون مخفف و أفضل ما
+
+366
+00:33:19,380 --> 00:33:25,340
+تداويتم بيه الخل واضح؟ ليش؟ لأنه لما تدرسوا
+
+367
+00:33:25,340 --> 00:33:28,440
+biochemistry هتلاحظوا أن هذا الخل المكون من
+
+368
+00:33:28,440 --> 00:33:32,640
+كربونتين هو مصدر للمراكبات الأكبر، يعني التنين
+
+369
+00:33:32,640 --> 00:33:35,080
+بيصيروا أربعة، الأربعة بيصيروا ستة، الستة بيصيروا
+
+370
+00:33:35,080 --> 00:33:38,160
+تمانية، التمانية بيصيروا عشرة، بيصير عندى تفاعل
+
+371
+00:33:38,160 --> 00:33:42,240
+متتالي بزيد لعدد الكربونات، وبهيك بتتكون المراكبات
+
+372
+00:33:42,240 --> 00:33:46,700
+في جسم الإنسان، فنقطة الإطلاق تبعها إيش؟الـ two
+
+373
+00:33:46,700 --> 00:33:50,120
+carbons ولذلك كثير من المراكبات الطبيعية بتلاقوها
+
+374
+00:33:50,120 --> 00:33:55,020
+زوجية مش فردية يعني اتنين اربعة ستة تمانية بتلاقوش
+
+375
+00:33:55,020 --> 00:34:00,100
+سبعة أو تسعة بسهولة واضح فالـ trichloroacetic acid
+
+376
+00:34:00,100 --> 00:34:05,960
+is more acidic than acetic acid itself هذا الكلام
+
+377
+00:34:05,960 --> 00:34:11,920
+لو بدنا نقول ليش due to inductive effect ال
+
+378
+00:34:11,920 --> 00:34:16,500
+resonance effect هنا مشتركالـ resonance effect
+
+379
+00:34:16,500 --> 00:34:21,020
+مشترك ليس هو السبب يعني دائما .. دائما لما بتكون
+
+380
+00:34:21,020 --> 00:34:25,700
+.. تعملوا مقارنة .. لما بتكون تعملوا مقارنة بتكون
+
+381
+00:34:25,700 --> 00:34:30,000
+تقارنوا بالشيء اللي بيختلف .. بتكون تقارنوا بالشيء
+
+382
+00:34:30,000 --> 00:34:35,380
+المختلف واضح؟ يعني أنا لما بدي أجي أقارن مثلا
+
+383
+00:34:35,380 --> 00:34:42,680
+اتنين أبطال سن عشرين سنةوزن 80 كيلو والتانين ذكور
+
+384
+00:34:42,680 --> 00:34:48,780
+الآن الفرق اللي بينهم أكيد مش ناجح عن أنهم التانين
+
+385
+00:34:48,780 --> 00:34:53,600
+ذكور أو أنهم عشرين سنة أو أن طولهم كذا ووزنهم كذا
+
+386
+00:34:53,600 --> 00:34:57,040
+لأن هدول أنا لما نزلتهم في حلبة الملاكمة كل هذه
+
+387
+00:34:57,040 --> 00:35:00,960
+الأشياء بينهم مشتركة طب هليش واحد منهم كان بيفوز
+
+388
+00:35:00,960 --> 00:35:06,790
+على التاني والله عمل تدريب أكترواضح؟ بينما لو كنت
+
+389
+00:35:06,790 --> 00:35:11,110
+بدأ أقارن واحد عمره عشرين سنة بواحد عمره أربع سنين
+
+390
+00:35:11,110 --> 00:35:16,990
+هنا بقول إنه فرق السن هنا بقول فرق السن هو السبب
+
+391
+00:35:16,990 --> 00:35:20,670
+في فرق القوة لكن لما اتنين بيلعبوا ملا كما و اتنين
+
+392
+00:35:20,670 --> 00:35:24,710
+عشرين سنة واحد ليش بيصير أقوى من التاني؟ بتكون
+
+393
+00:35:24,710 --> 00:35:28,570
+تقولوا لأ عشان هو رجل و عمره عشرين سنة؟ طب ما
+
+394
+00:35:28,570 --> 00:35:31,730
+التاني رجل و عمره عشرين سنة؟ إذا بتكون دايما
+
+395
+00:35:31,730 --> 00:35:38,040
+تفتشوا سبب الفرقالمحدد فهنا بين هدولة سبب الفرق مش
+
+396
+00:35:38,040 --> 00:35:43,160
+ال resonance ال inductive effect هما فيهم الشغلتين
+
+397
+00:35:43,160 --> 00:35:48,160
+لكن سبب فرق الحامضية ال inductive effect لأن ال
+
+398
+00:35:48,160 --> 00:35:52,440
+resonance موجود في الحد
+
+399
+00:35:58,550 --> 00:36:01,310
+الأساس ده أموراتها بشكل عام مش في الـ .. مش في
+
+400
+00:36:01,310 --> 00:36:04,770
+الأسماع وفي الأساس بشكل عام واحد فيه رزوناس واحد
+
+401
+00:36:04,770 --> 00:36:11,870
+فيه مجتمع دائما إذا .. إذا اختلفت .. إذا اختلفت
+
+402
+00:36:11,870 --> 00:36:16,690
+الأشياء بيصير المقارنة من خلال إنه نبحث عن القيم
+
+403
+00:36:16,690 --> 00:36:21,630
+الحقيقية بالتجربة بقدرش أعطي جواب بقدرش أعطي جواب
+
+404
+00:36:21,630 --> 00:36:24,930
+وجدها واضح؟ يعني ممكن
+
+405
+00:36:26,980 --> 00:36:31,940
+كيف .. كيف يصير السؤال؟ يعني لو انت .. إجينا و
+
+406
+00:36:31,940 --> 00:36:38,220
+سألناكي أيهما أقوى الـ trifluoroacetic acid و لا
+
+407
+00:36:38,220 --> 00:36:42,940
+ال trifluoroacetic acid؟ الان أنا .. أنا بسهولة
+
+408
+00:36:42,940 --> 00:36:47,400
+بقدر أقول أنه ال trifluoro لأنه ال acid مشترك
+
+409
+00:36:48,140 --> 00:36:53,380
+وتلاتة مشتركين سالبية الفلورو صح كل الإلكترونات
+
+410
+00:36:53,380 --> 00:36:58,620
+أعلى من سالبية الكلور طيب لو أتيت أسألك بهذا الشكل
+
+411
+00:36:58,620 --> 00:37:07,140
+كنتلك سيضة بالبنط OOH CH2 وفلورو واحدة الفلورو
+
+412
+00:37:07,140 --> 00:37:14,830
+أسيتك أسد ولا تريكلورو أسيتك أسد؟صار عندى انا
+
+413
+00:37:14,830 --> 00:37:19,530
+متغيرين مش متغير واحد صار المتغير الاول اللى عندى
+
+414
+00:37:19,530 --> 00:37:22,890
+عدد الذرات اللى هنا والمتغير بتاع ال
+
+415
+00:37:22,890 --> 00:37:27,770
+electronegativity في هذه الحالة انا بقول مابعرفش
+
+416
+00:37:27,770 --> 00:37:33,370
+الجواب لازم اشوف التجربة وانتش انا بسهولة كان بعرف
+
+417
+00:37:33,370 --> 00:37:37,430
+الجواب لو كان السؤال زى هى صيدم ال point O O H
+
+418
+00:37:41,640 --> 00:37:48,400
+هنا المتغير الواحد عندى asset عندى one one atom بس
+
+419
+00:37:48,400 --> 00:37:50,600
+اتغير ال floor و ال chlorine مين more electro
+
+420
+00:37:50,600 --> 00:37:58,280
+negative ال floor لكن لو صاروا هدولة تنين يمكن
+
+421
+00:37:58,280 --> 00:38:02,800
+يكون مجموعة دول الاتنين مغطية الزيادة اللى بسببها
+
+422
+00:38:02,800 --> 00:38:07,340
+ال floor فانها لازم اعمل تجربة يعني مابقدرش اعطى
+
+423
+00:38:07,340 --> 00:38:13,220
+الجواب مباشر إذا كان عندىأكتر من الشيء وهذا الكلام
+
+424
+00:38:13,220 --> 00:38:18,040
+بالمناسبة يعني من مبادئ العلم الأساسية .. من مبادئ
+
+425
+00:38:18,040 --> 00:38:21,260
+العلم الأساسية جدا أنه إنتوا إذا بدكوا تقارنوا
+
+426
+00:38:21,260 --> 00:38:27,420
+شغلات .. إذا بدكوا تقارنوا شغلات بدكوا توحدوا جميع
+
+427
+00:38:27,420 --> 00:38:34,940
+الظروف .. بدكوا توحدوا جميع الظروف ما عدا متغير
+
+428
+00:38:34,940 --> 00:38:42,420
+واحدبتكون تواحده جميع الظروف مع دقاش، متغير واحد،
+
+429
+00:38:42,420 --> 00:38:45,460
+هذا الكلام ممكن أعطيكم عليه مثال من العلم، من
+
+430
+00:38:45,460 --> 00:38:49,120
+الكيميا وممكن مثال من السياسة، من الدنيا، الآن لما
+
+431
+00:38:49,120 --> 00:38:54,860
+أخدتوا قوانين الغازاتالغاز محكوم بإيش؟ بالضغط
+
+432
+00:38:54,860 --> 00:39:00,160
+والحجم ودرجة الحرارة والمولات كان عندى أربع
+
+433
+00:39:00,160 --> 00:39:06,160
+متغيرات لما كنت بعمل مقارنة كيف كنت أنا أقارن كنت
+
+434
+00:39:06,160 --> 00:39:11,120
+أثبت متغيرات وأقارن متغيرات تانية بس مابقدرش أسيب
+
+435
+00:39:11,120 --> 00:39:16,780
+الأربعة يتغيرواهذا الغاز بضغط معين، بحجم معين،
+
+436
+00:39:16,780 --> 00:39:19,900
+number of moles معين، temperature معينة و هداك
+
+437
+00:39:19,900 --> 00:39:24,800
+بالاربع أشياء مختلفة، بتصير العملية إياش صعبة،
+
+438
+00:39:24,800 --> 00:39:29,680
+فالإنسان العلمي لما بده يقارن، بده يوحدالظروف ..
+
+439
+00:39:29,680 --> 00:39:35,200
+بده يوحد الظروف و بعدين بده ييجي يقارن أما نيجي
+
+440
+00:39:35,200 --> 00:39:39,420
+نعمل حالنا شاطرين .. نعمل حالنا شاطرين و بدنا
+
+441
+00:39:39,420 --> 00:39:46,180
+نقارن بظروف مختلفة فالكلام ما بصيرش ربما مثلا يعني
+
+442
+00:39:46,180 --> 00:39:51,460
+أعطيكوا مثال إيش منطق التفكير الغربي .. إيش منطق
+
+443
+00:39:51,460 --> 00:39:58,680
+التفكير الغربي التفكير الغربي فكر بشكل آتيإنه بدوا
+
+444
+00:39:58,680 --> 00:40:04,180
+يوقع مثلا الفلسطينيين بإشكالية
+
+445
+00:40:04,180 --> 00:40:07,960
+مع الإسلاميين ومع الحكومات الإسلامية وما إلى ذلك
+
+446
+00:40:07,960 --> 00:40:14,580
+فإنها بدوا يثبت فشل كل الإسلام مش حركة معينة
+
+447
+00:40:14,580 --> 00:40:21,440
+العداوة عامة صار في حكومة بشكل أو بآخر اسمها حكومة
+
+448
+00:40:21,440 --> 00:40:24,380
+حركة إسلامية إيش الحل اللي بدوا يعملوا؟ بدوا يثبت
+
+449
+00:40:24,380 --> 00:40:28,790
+للناس إن هدولةسواد وجه ما جاش منهم غير الفلس
+
+450
+00:40:28,790 --> 00:40:31,930
+والاسبالة في الشوارع و هلوم هلوم هلوم هلوم هلوم
+
+451
+00:40:31,930 --> 00:40:38,310
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+452
+00:40:38,310 --> 00:40:38,390
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+453
+00:40:38,390 --> 00:40:38,750
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+454
+00:40:38,750 --> 00:40:40,590
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+455
+00:40:40,590 --> 00:40:46,350
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+456
+00:40:46,350 --> 00:40:53,710
+هلوم
+
+457
+00:40:54,720 --> 00:40:59,480
+مافيش إمكانية للمقارنة كيف .. كيف أنا بدي أقارن
+
+458
+00:40:59,480 --> 00:41:04,480
+تماما ممكن واحدة منكوا تكون ذكية كتير لكن هذه أمها
+
+459
+00:41:04,480 --> 00:41:08,740
+الله يرحمها توفتوا عندها ست إخوة في الدار و واحدة
+
+460
+00:41:08,740 --> 00:41:11,520
+فاضية و عامليني لا فاصليني لا أقضى لحالة و أقعد
+
+461
+00:41:11,520 --> 00:41:14,900
+أدرسي و ما إلى ذلك هل بقدر أنا أعمل مقارنة بينهم
+
+462
+00:41:14,900 --> 00:41:19,870
+في الذكاء ولا .. ما الظروف إيش؟الظروف مختلفة،
+
+463
+00:41:19,870 --> 00:41:23,670
+فاللي بده يقارن، يعني لو بده أقول مين فيهم أذكى من
+
+464
+00:41:23,670 --> 00:41:28,990
+التانية، بده أجي لأختينالتنتين توم خلّينا نقول
+
+465
+00:41:28,990 --> 00:41:32,590
+ساكنين بنفس البيت، كل واحدة معطينها غرفة، معطينها
+
+466
+00:41:32,590 --> 00:41:36,390
+كمبيوتر، معطينها كتاب، معطينها مصروف، معطينها أكل،
+
+467
+00:41:36,390 --> 00:41:40,550
+وفي الآخر هذه بتيجي اللي هي جايبالي 90% و هذه
+
+468
+00:41:40,550 --> 00:41:44,910
+بالعافية بتجيبي ال 60% و أجتا بقول أكيد هذه مخها
+
+469
+00:41:44,910 --> 00:41:51,030
+أنضف شوية من هذه، لأن أنا وحدت كل إيشكل الظروف
+
+470
+00:41:51,030 --> 00:41:56,850
+فهنا نفس الفكرة واضح؟ لما بدي أقارن بدي أوحد
+
+471
+00:41:56,850 --> 00:42:02,710
+الظروف ما عدا المتغير اللي بندرسه بالمناسبة هذا
+
+472
+00:42:02,710 --> 00:42:07,730
+الكلام هو سبب إشكالية في العلم إنه كتير شغلات لحد
+
+473
+00:42:07,730 --> 00:42:13,610
+الآن الناس مش قادرين بالظبط يحكموا عليها يعني مثلا
+
+474
+00:42:13,610 --> 00:42:17,150
+كتير من الأشياء بيجوا بيقولوا لكوا والله هالشغلة
+
+475
+00:42:17,150 --> 00:42:24,180
+بتسبب سرطان ولا لأ؟أو بتسبب مشاكل صحية ولا لأ؟ طب
+
+476
+00:42:24,180 --> 00:42:27,700
+ليش احنا مش قادرين نحكم؟ لسبب بسيط أن البني آدم
+
+477
+00:42:27,700 --> 00:42:33,180
+اللي بندرسه حقيقة هو مش بس معرض مش بس معرض مثلا
+
+478
+00:42:33,180 --> 00:42:37,790
+للكيمويات اللي ارتشت على الفراولةما هو المشكلة لو
+
+479
+00:42:37,790 --> 00:42:43,030
+أن البني آدم محطوط في جو معزول تماما و بس بياكل
+
+480
+00:42:43,030 --> 00:42:47,010
+فراولة مرشوشة و التاني بياكل فراولة مش مرشوشة و
+
+481
+00:42:47,010 --> 00:42:50,670
+هذا مرض و هذا لأ بقول أنه السبب من الفراولة لكن
+
+482
+00:42:50,670 --> 00:42:55,630
+البني آدم معرضممكن واحد يكون ساكن عند ساحة
+
+483
+00:42:55,630 --> 00:43:00,450
+التكسيات، بشم إرصاص في البنزين، و هالومة جرّان
+
+484
+00:43:00,450 --> 00:43:03,910
+كتير، و التاني ساكن في منطقة رفي. هاي متغير تاني
+
+485
+00:43:03,910 --> 00:43:09,230
+صار عنده. ممكن هذا بياكل بندورة مرشوشة و هذا لأ، و
+
+486
+00:43:09,230 --> 00:43:11,670
+هذا بياكل سبانخ مرشوشة و هذا لأ، و بياكل فراولة
+
+487
+00:43:11,670 --> 00:43:15,270
+مرشوشة و هذا لأ. الآن السؤال عاد، بقدر أنا أحلف
+
+488
+00:43:15,270 --> 00:43:20,530
+يمين أن هذا سبب مشكلته الفراولة؟ طب ما هو ..
+
+489
+00:43:20,790 --> 00:43:25,530
+الاختلاف بينهم بالهوى و بالميه اللى بيشربوها، هذا
+
+490
+00:43:25,530 --> 00:43:28,510
+بيشرب من البيرو، هذا بيشرب الهوى و الميه و
+
+491
+00:43:28,510 --> 00:43:31,550
+البندورة و الخيار و الفراولة بكل ما تحويه من
+
+492
+00:43:31,550 --> 00:43:37,130
+مبيدات، شو عرفنا ان الفراولة هي السببنفس الاشي
+
+493
+00:43:37,130 --> 00:43:41,550
+مشكلة مثلا أمواج الجوال لليوم لما ييجيوا يركبوا
+
+494
+00:43:41,550 --> 00:43:45,290
+برج جوال على دار ناس بيصيروا الجيران يتقاتلوا و
+
+495
+00:43:45,290 --> 00:43:50,550
+الله هذا برج الجوال بيسبب مشاكل ولا لأ و كل القصص
+
+496
+00:43:50,550 --> 00:43:54,910
+ليش احنا مش عارفين و مش قادرين لأنه كتير متغيرات
+
+497
+00:43:54,910 --> 00:44:00,810
+هي بس أنا عندي أمواج الجوال عندي جوال على كيمويات
+
+498
+00:44:00,810 --> 00:44:05,910
+على هوا ملوث يمكن نيصل إشعاع ذرع كمان من فكوشيما
+
+499
+00:44:07,890 --> 00:44:13,270
+تستغربوش، هذه دنيا واسعة يعني التاني يوم أو تالت
+
+500
+00:44:13,270 --> 00:44:16,530
+يوم من مفاعل Fukushima كل الأسماك اللي
+
+501
+00:44:16,530 --> 00:44:22,110
+بـCalifornia ماتت شوفتوا الصور بتاعتها؟ اكتبوا على
+
+502
+00:44:22,110 --> 00:44:28,030
+Google بس موت الأسماك في California بعد تسنامي
+
+503
+00:44:28,030 --> 00:44:32,200
+اليابانجداش المسافة بين اليابان وكاليفورنيا
+
+504
+00:44:32,200 --> 00:44:38,800
+هتشوفوا جرفات عدد كبير من الجرفات بس بزيه سمك ميت
+
+505
+00:44:38,800 --> 00:44:43,060
+البحر ممكن البناء الأدمين يمشوا عليه لإن كل السمك
+
+506
+00:44:43,060 --> 00:44:48,160
+مات وكان طاف فوق سطح البحر الدنيا يعني التأثيرات
+
+507
+00:44:48,160 --> 00:44:53,220
+هذه بتنتقل لما صارت شيرنوبال مثلا هو شيرنوبال
+
+508
+00:44:53,220 --> 00:44:59,330
+localized ولاde-localized عليها البنجف على ال
+
+509
+00:44:59,330 --> 00:45:03,310
+preparation of carboxylic acids
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..717c3f589a30a812049d1423d60bd3fc96f4d02c
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_raw.srt
@@ -0,0 +1,2044 @@
+1
+00:00:08,760 --> 00:00:15,860
+اليوم بنكمل في موضوع الأحماض وتحديدا
+
+2
+00:00:15,860 --> 00:00:20,600
+لسه ما زلنا في موضوع تسمية الأحماضالفكرة الأساسية
+
+3
+00:00:20,600 --> 00:00:24,620
+اللي حكيناها المرة الماضية أنه تسمية حامض تسمية
+
+4
+00:00:24,620 --> 00:00:30,240
+حامض بالتم بإضافة المقطع oic acid و بعد هيك شوفي
+
+5
+00:00:30,240 --> 00:00:35,620
+عندنا مجموعات substituents بنذكرها استعرضنا
+
+6
+00:00:35,620 --> 00:00:43,030
+استعرضنا الأحماض من واحد إلىعشرة باسمها ال IUPAC
+
+7
+00:00:43,030 --> 00:00:47,170
+وال common names يمكن هذه ال slide تكون شوية أهم
+
+8
+00:00:47,170 --> 00:00:54,450
+هنا كيف نسمي مركبات مختلفة لأحماض بتحتوي على
+
+9
+00:00:54,450 --> 00:00:57,590
+substituents
+
+10
+00:00:57,590 --> 00:01:03,310
+مثلا في هذا المثال الأول بتلاحظوا أن عندكم حامض
+
+11
+00:01:03,310 --> 00:01:10,730
+بكم كربونةأربعة بيوتانويك أسد لبيوتانويك أسد ع
+
+12
+00:01:10,730 --> 00:01:16,110
+موقع تلاتة في بروم لاحظوا الترقيم من وين بيبدأ من
+
+13
+00:01:16,110 --> 00:01:20,430
+الكاربون اللي حامل السيدة بالبندقه مش من بعيدها لو
+
+14
+00:01:20,430 --> 00:01:24,030
+كنا مرات بنستعمل نظام Alpha و Beta بيكون من اللي
+
+15
+00:01:24,030 --> 00:01:29,970
+بعيدها هذا الحامض واحد اتنين تلاتة اربعة خمسة اذا
+
+16
+00:01:29,970 --> 00:01:36,230
+احنا بنحكي عن بيتانويك أسدعلى تلاتة واربعة داي
+
+17
+00:01:36,230 --> 00:01:41,530
+كلورو وعلى خمسة ع تلاتة واربعة داي كلورو بس تلاتة
+
+18
+00:01:41,530 --> 00:01:47,070
+واربعة داي كلورو بنتانويك أسد طبعا الحامض اللي على
+
+19
+00:01:47,070 --> 00:01:52,150
+البنزين شو اسمه بنزويك أسد إذا هذا بقرا كلورو
+
+20
+00:01:52,150 --> 00:01:59,050
+بنزويك أسد مثل هذا الحامض واحد اتنين لاحظوا أنا
+
+21
+00:01:59,050 --> 00:01:59,570
+عندكم
+
+22
+00:02:05,530 --> 00:02:09,090
+الان المجموعة اللى بيكون حاملها هذا الحامض اي
+
+23
+00:02:09,090 --> 00:02:16,210
+مجموعة اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+24
+00:02:16,210 --> 00:02:16,530
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+25
+00:02:16,530 --> 00:02:17,930
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+26
+00:02:17,930 --> 00:02:19,290
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+27
+00:02:19,290 --> 00:02:19,850
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+28
+00:02:19,850 --> 00:02:25,410
+اثل اثل اثل اثل اثل اثل اثيمكن الأمثلة اللي بعد
+
+29
+00:02:25,410 --> 00:02:30,550
+هنا جزء منها بيحتوي على أكتر من مجموعة وظيفية،
+
+30
+00:02:30,550 --> 00:02:34,290
+يعني غير مجموعة الحامض، ممكن تلاقوا ال keen، ممكن
+
+31
+00:02:34,290 --> 00:02:39,210
+تلاقوا أو أتش، ممكن تلاقوا double bond، وأخدنا
+
+32
+00:02:39,210 --> 00:02:44,450
+احنا أولويات، والحمض تقريبا من أعلى الأولويات
+
+33
+00:02:45,440 --> 00:02:50,860
+المثال الأول بسيط اللي هو 2-bromopropanoic acid و
+
+34
+00:02:50,860 --> 00:02:54,300
+بالمنطق اللي مرات بيستعملوا فيه Alpha هذا منطق
+
+35
+00:02:54,300 --> 00:02:58,700
+common name Alpha-bromo بيستعملوا probionic acid
+
+36
+00:02:58,700 --> 00:03:03,960
+لأنه common name هذا المثال فيه مجموعتين وظيفيتين
+
+37
+00:03:03,960 --> 00:03:10,210
+اللي هو الحامض وال double bondالكين و acid مع بعض
+
+38
+00:03:10,210 --> 00:03:14,790
+الأولوية لمن؟ لل acid فبالترقيم هنبدأ من عند
+
+39
+00:03:14,790 --> 00:03:18,790
+الكاربون تحت ال acid و في التسمية بيبين عند أوك
+
+40
+00:03:18,790 --> 00:03:26,450
+أسد في الآخر طبعا هنا إفروبين أوك أسد ملاحظين
+
+41
+00:03:26,450 --> 00:03:27,030
+انتوا؟
+
+42
+00:03:29,550 --> 00:03:34,890
+الآن هذا السؤال أنه ال acid دائما على الطرف، ال
+
+43
+00:03:34,890 --> 00:03:38,550
+acid دائما على الطرف، بلزمش نحددله موقعه، ليش
+
+44
+00:03:38,550 --> 00:03:44,730
+ماقلناش هنا to a propionic acid؟ هذا هو السؤال
+
+45
+00:03:47,320 --> 00:03:51,200
+مافيش احتمالات لو كنت انا بحكي لو كنت بحكي عن ست
+
+46
+00:03:51,200 --> 00:03:55,900
+ذرات كربون مثلا C double bond OH وعندي ست ذرات
+
+47
+00:03:55,900 --> 00:04:00,000
+كربون واحد اتنين تلات اربعة خمسين افترن ستة الان
+
+48
+00:04:00,000 --> 00:04:06,730
+هنا ممكن تكون ال double bond هناهيكون 2-hexanoic
+
+49
+00:04:06,730 --> 00:04:11,630
+acid ممكن تكون هنا 3-hexanoic acid 4-hexanoic acid
+
+50
+00:04:11,630 --> 00:04:15,570
+5-hexanoic acid هنا فيه احتمالات بس هنا مافيش غير
+
+51
+00:04:15,570 --> 00:04:21,510
+هذا الاحتمال فمع علم ما بنزيدش كلام عليه واضح؟
+
+52
+00:04:21,510 --> 00:04:25,410
+بينما هنا انا مضطر مثل هذا المركب لما بدي اسميه 1
+
+53
+00:04:25,410 --> 00:04:33,310
+2 3 4 5 6 لازم اقول threeهكسين الان ال three بتكون
+
+54
+00:04:33,310 --> 00:04:43,330
+يتحدد موقع ايش ال double bond و بكمل oic acid ال
+
+55
+00:04:43,330 --> 00:04:51,510
+مركب
+
+56
+00:04:51,510 --> 00:04:59,730
+اللي بعده فيه كحول O H O Acid الاولوية لإيشللـ
+
+57
+00:04:59,730 --> 00:05:04,690
+acid في الترقيم هيكون واحد اتنين تلاتة اربعة هيكون
+
+58
+00:05:04,690 --> 00:05:14,630
+three hydroxy butanoic acid لأنه مابنسبوش للكحول
+
+59
+00:05:14,630 --> 00:05:19,850
+ال acid أعلى أولوية من الكحول هذا المركب
+
+60
+00:05:19,850 --> 00:05:24,510
+المجموعتين الوظيفيتين اللي فيه الديهيد و ال acid
+
+61
+00:05:24,510 --> 00:05:26,690
+الديهيد و ال acid
+
+62
+00:05:30,590 --> 00:05:34,790
+بروبانويك أسد على موقع تلاتة الالديهايد لما يكون
+
+63
+00:05:34,790 --> 00:05:40,890
+تعامل كمجموعة شو بنسميها اقزو اتري اقزو بروبانويك
+
+64
+00:05:40,890 --> 00:05:47,010
+أسد ها نفس الاشي واحد اتنين تلاتة اربعة خمسة على
+
+65
+00:05:47,010 --> 00:05:53,370
+موقع اتنين برومو على موقع اتنين برومو وعلى موقع
+
+66
+00:05:53,370 --> 00:05:59,380
+اربعة الكيتون مين له أولوية الكيتون ولا الاسدالاسد
+
+67
+00:05:59,380 --> 00:06:04,020
+فعشان هي كانت بترجع اكزو to promo for اكزو بين
+
+68
+00:06:04,020 --> 00:06:10,160
+تانويك اسد واضح هنا بتلاحظوا امثلة بنتقف فيها اكثر
+
+69
+00:06:10,160 --> 00:06:15,800
+من مجموعة وظيفية والاسد
+
+70
+00:06:15,800 --> 00:06:23,340
+طبعا اولويته عالية يمكن هنا كمان مزيد من الامثلة
+
+71
+00:06:24,680 --> 00:06:28,020
+هذا المثال بسيط لأنه فش ليه غير ال acid و بعدين ال
+
+72
+00:06:28,020 --> 00:06:33,020
+الكلجروكس المهم اتفتشوا على ال longest chain هذا
+
+73
+00:06:33,020 --> 00:06:39,260
+المثال فيه حامض و مجموعة ال amino و مجموعة ال
+
+74
+00:06:39,260 --> 00:06:46,220
+hydroxy 2 amino 3 hydroxybutanoic acid طبعا إله
+
+75
+00:06:46,220 --> 00:06:50,140
+اسم شهرة لأن هذا amino acid بيمر مع الناس في ال
+
+76
+00:06:50,140 --> 00:06:52,840
+biochemistry لثريونين
+
+77
+00:06:53,980 --> 00:06:57,860
+مش موضوع طبعا لو بديجي زي هي تقلكوا سؤال واحد
+
+78
+00:06:57,860 --> 00:07:02,600
+اتنين ثلاثة اربعة المفروض تحددوا هذي R ولا S و هذي
+
+79
+00:07:02,600 --> 00:07:08,060
+R ولا S فزي ما بتلاحظوا ان هنا هو بيقول ان عندنا
+
+80
+00:07:08,060 --> 00:07:15,060
+two S لو بدنا نذكركم هاي موقع اتنين وين اقل مجموعة
+
+81
+00:07:15,060 --> 00:07:21,480
+ال H هذيأنا بتحرك ال nitrogen بعدين الكربون اللي
+
+82
+00:07:21,480 --> 00:07:24,140
+حامله oxygen بعدين الكربون اللي حامله وانا oxygen
+
+83
+00:07:24,140 --> 00:07:30,980
+اذا it seems to R الـH I'm trying to resist to S
+
+84
+00:07:30,980 --> 00:07:35,360
+هذه نفس الاشي لو أننا ناخدها ال box أعلى مجموعة ال
+
+85
+00:07:35,360 --> 00:07:42,680
+O بعدين هذه بعدين هذه أنا بتحرك بهذا الشكل 3S it
+
+86
+00:07:42,680 --> 00:07:51,870
+is 3R not 3S واضح؟هذا مثال بسيط هذا لما تكون
+
+87
+00:07:51,870 --> 00:07:57,170
+مجموعة ال acid على حلقات بنستعمل لها carboxylic
+
+88
+00:07:57,170 --> 00:08:01,690
+acid زي ال aldehyde لما يكون على حلقة إذا بتذكرون
+
+89
+00:08:01,690 --> 00:08:07,150
+ايش كنا بنقول؟ Carb aldehyde هذا بنقول carboxylic
+
+90
+00:08:07,150 --> 00:08:12,350
+acid فيه تنتين شو بيصير عندك؟ Dicarboxylic acid
+
+91
+00:08:12,350 --> 00:08:19,600
+فهذا عبارة عن Cyclohexaneداي كربوكسليك أسد، الداي
+
+92
+00:08:19,600 --> 00:08:23,980
+كربوكسليك أسد وين موجودين؟ تتعتبر أنها دي واحد،
+
+93
+00:08:23,980 --> 00:08:30,020
+اتنين، تلاتة على واحد و تلاتة، وكيف اتجاههم؟
+
+94
+00:08:30,020 --> 00:08:36,100
+تطلعوا على جهة واحدة للأمام، إذا هم سيس سيس وان
+
+95
+00:08:36,100 --> 00:08:42,840
+ثري سايكلوهكسين داي كربوكسليك أسد سيس وان ثري
+
+96
+00:08:42,840 --> 00:08:45,380
+سايكلوهكسين داي كربوكسليك أسد
+
+97
+00:08:57,370 --> 00:09:04,170
+واضح؟ ها نفس الاشي أمثلة إضافية Cyclopentane بحمل
+
+98
+00:09:04,170 --> 00:09:11,270
+acid شو بنا نسميه؟ Cyclopentane carboxylic acid لو
+
+99
+00:09:11,270 --> 00:09:12,530
+كان حامل الديهايد
+
+100
+00:09:15,590 --> 00:09:19,790
+cyclobutane carbaldehyde وهذا Cyclobutane
+
+101
+00:09:19,790 --> 00:09:23,870
+Carboxylic Acid طبعا بتفيه على موقع تلاتة كلورو
+
+102
+00:09:23,870 --> 00:09:28,090
+مجموعة للأمام للخلف أو لفوق و تحت بتستعمله
+
+103
+00:09:28,090 --> 00:09:35,170
+Cystrans Benzoic Acid Parachlorobenzoic Acid Hana
+
+104
+00:09:35,170 --> 00:09:39,590
+Toluic Acid لأن هنا المجموعة من طلوين جاي هذا اسم
+
+105
+00:09:39,590 --> 00:09:45,040
+شهرة لكن ممكن نسميه one two two مثلبنزين
+
+106
+00:09:45,040 --> 00:09:50,540
+كاربوكسليك أسد أو two methyl benzoic acid هذا
+
+107
+00:09:50,540 --> 00:09:54,140
+المركب من النفثالين بتذكروا حلقتين بنزين شو
+
+108
+00:09:54,140 --> 00:09:58,980
+بنسميهم نفثالين لو كان الحامض على هذا الموقع واحد
+
+109
+00:09:58,980 --> 00:10:04,060
+بنسميه one naphthalic acid لما نكون على موقع اتنين
+
+110
+00:10:04,060 --> 00:10:12,570
+two naphthalic acid لو ايجي هنا لأ twoلو حطيت
+
+111
+00:10:12,570 --> 00:10:17,190
+الاصل هنا، شو بدأ أسميه؟ two ولا three؟ بنبدأ من
+
+112
+00:10:17,190 --> 00:10:23,090
+تحت، تصير واحد اتنين، برجع two لو حطيت هنا one،
+
+113
+00:10:23,090 --> 00:10:28,490
+اذا في نفسوق اصل حقيقة عندي بس حامضين منه، يا ال
+
+114
+00:10:28,490 --> 00:10:33,030
+one يا ال two لأن هذا الموقع و هذا و هذا و هذا نفس
+
+115
+00:10:33,030 --> 00:10:37,220
+الشيءو هذا الموقع و هذا و هذا و هذا نفس الشيء يعني
+
+116
+00:10:37,220 --> 00:10:40,720
+لو جبتلكوا نفثالين و قولتلكوا بقى كام حامض بقدر
+
+117
+00:10:40,720 --> 00:10:44,800
+أعمل منه بس حامضين ال one naphthalic acid و ال two
+
+118
+00:10:44,800 --> 00:10:48,740
+naphthalic acid ولو المواقع اتبعتوا كتيرة لكن
+
+119
+00:10:48,740 --> 00:10:55,080
+مواقعه أشمالها متماثلة هذا و هذا و هذا و هذا نفس
+
+120
+00:10:55,080 --> 00:11:02,000
+الموقع هذا و هذا و هذا و هذا نفس الموقع واضح؟
+
+121
+00:11:05,190 --> 00:11:09,950
+مي كان بدو يسأل هان؟ لا
+
+122
+00:11:09,950 --> 00:11:17,430
+لا دائما في الحلقات، دائما في الحلقات التارقية، في
+
+123
+00:11:17,430 --> 00:11:20,230
+الحلقة البطاسية اللي هيك بتسمى viewsdrags اللي
+
+124
+00:11:20,230 --> 00:11:21,830
+بيجي من الموقع اللي جامبل
+
+125
+00:11:28,730 --> 00:11:32,410
+مثلًا، اللي قبل هذا، هم .. هم .. هم .. هم .. هم ..
+
+126
+00:11:32,410 --> 00:11:32,810
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+127
+00:11:32,810 --> 00:11:34,890
+.. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم ..
+
+128
+00:11:34,890 --> 00:11:36,030
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+129
+00:11:36,030 --> 00:11:43,150
+.. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم ..
+
+130
+00:11:43,150 --> 00:11:46,250
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+131
+00:11:46,250 --> 00:11:46,250
+.. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم ..
+
+132
+00:11:46,250 --> 00:11:46,310
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+133
+00:11:46,310 --> 00:11:56,250
+.. هم .. هم .. هم .. هم .. هم ..
+
+134
+00:11:56,250 --> 00:12:02,260
+همالـ D مش حرف علة فليش .. ها هي السؤالة تحديداً
+
+135
+00:12:02,260 --> 00:12:10,920
+هنا أن هذا حرف ال E موجود طبعا ليش احنا ماحذفنوش
+
+136
+00:12:10,920 --> 00:12:15,520
+لأنه بعده D بعده مش حرف علة بس مثلا لما بيكون عندى
+
+137
+00:12:15,520 --> 00:12:18,720
+دائما فعلا أنا دي قاعدة في الكيميا لما بيكون عندى
+
+138
+00:12:18,720 --> 00:12:23,740
+حرفين علة ورا بعض بحذف الأول منهم بنحذف الأول من
+
+139
+00:12:23,740 --> 00:12:27,180
+حرفين العلة واضح؟
+
+140
+00:12:31,240 --> 00:12:35,540
+هي كتيرة الأمثلة هيك لكن بلاش نطلع منكم أو نطلع عن
+
+141
+00:12:35,540 --> 00:12:41,060
+الموضوع تبعنا يعني مثلا لو بدكم تقولوا ISO oxazole
+
+142
+00:12:41,060 --> 00:12:46,380
+for example أو oxazole
+
+143
+00:12:46,380 --> 00:12:50,680
+اصلها oxazole
+
+144
+00:12:50,680 --> 00:12:52,160
+مثلا هذا مُركّب الآن
+
+145
+00:12:57,210 --> 00:13:01,170
+بشير الأولى دى قاعدة عامة بس هنا مافيش عندى التقاء
+
+146
+00:13:01,170 --> 00:13:10,010
+حرفى أو التقاء حرفى الا طبعا
+
+147
+00:13:10,010 --> 00:13:16,010
+طبعا طبعا طبعا alphabetical الان بننتقل ل ال die
+
+148
+00:13:16,010 --> 00:13:21,210
+acids احنا قولنا ان اى سلسلة عادية ممكن يكون لها
+
+149
+00:13:21,210 --> 00:13:25,390
+طرفين و احيانا ممكن يكونوا اكثر من طرفين طبعا الان
+
+150
+00:13:26,520 --> 00:13:32,000
+لو على الطرفين كان عندى حامض بيصير عنده داي أسد
+
+151
+00:13:32,000 --> 00:13:35,260
+يعني مثلا هنا هي carbon و carbon و هنا في عندى
+
+152
+00:13:35,260 --> 00:13:40,400
+حامض و حامض ايش صار عندى؟ داي أسد هي carbon تنتين
+
+153
+00:13:40,400 --> 00:13:46,360
+تلاتة حامض و carbon و حامض داي أسد هنا داي أسد
+
+154
+00:13:46,360 --> 00:13:50,160
+أربعة داي أسد خمسة الان هدولة لما بدنا نسميهم كم
+
+155
+00:13:50,160 --> 00:13:55,360
+بنسميهم بنعد كم carbon عندنا تنتين تنتين يعني ايش؟
+
+156
+00:13:55,990 --> 00:14:02,150
+ethane اذا بنقول ايثان او ايثان دايووك اسد اثان
+
+157
+00:14:02,150 --> 00:14:08,010
+داي اووك اسد لانه للاسد احنا بنحط ال اووك هنا عندي
+
+158
+00:14:08,010 --> 00:14:14,310
+تلاتة شو بيصير اسم المركب؟ بروبين داي اووك كل
+
+159
+00:14:14,310 --> 00:14:18,830
+هدولة داي اووك اسد فيهم حامضين على الجانب هنا عندي
+
+160
+00:14:18,830 --> 00:14:23,350
+اربعة بيوتين داي اووك اسد بنتين داي اووك اسد
+
+161
+00:14:23,350 --> 00:14:30,450
+هيكسين داي اووك اسدواضح؟ الآن هذا بمنعش أن هؤلاء
+
+162
+00:14:30,450 --> 00:14:35,310
+الأحماض لهم أصل أول ما اكتشفوهم وأخرجوهم من مصادر
+
+163
+00:14:35,310 --> 00:14:39,270
+أحيانا نباتية أحيانا حيوانية وبالتالي لهم أسماء
+
+164
+00:14:39,270 --> 00:14:45,550
+شهرة وأسماء الشهرة غالبا مرتبطة بالعائلات
+
+165
+00:14:45,550 --> 00:14:48,790
+الاستخراجوها منها مثلا الحمض الأول بيسموه oxalic
+
+166
+00:14:48,790 --> 00:14:56,130
+acid من نبات سوريلالأوكزاليك family التاني مالونك
+
+167
+00:14:56,130 --> 00:15:08,150
+أسد من المالون التالت التالت
+
+168
+00:15:08,150 --> 00:15:14,070
+ساكسينك أسد الغابع غلوتاريك أسد خمس ضرات كربون
+
+169
+00:15:14,070 --> 00:15:23,800
+غلوتاريك أسد ستة أديبك أسد7 بيملك acid على أي حال
+
+170
+00:15:23,800 --> 00:15:29,800
+الصعب طبعا انكوا تحفظوا ال common names لكن السهل
+
+171
+00:15:29,800 --> 00:15:33,660
+انكوا تعرفوا ال IUPAC names واضح فال IUPAC names
+
+172
+00:15:33,660 --> 00:15:38,780
+مرات كتيرة أسهل للطلاب هذا بمنعش انه لو الناس
+
+173
+00:15:38,780 --> 00:15:41,980
+اتخصصت كيميا و مع طول الفترة لما نقول مثلا ايش ال
+
+174
+00:15:41,980 --> 00:15:48,200
+adipic acid الحامض السوداسي اللي بيطولوا منهاللي
+
+175
+00:15:48,200 --> 00:15:53,340
+بيصنعوا منهم نيلون أساس صناعة النيلون الاديوك أسد
+
+176
+00:15:53,340 --> 00:15:59,640
+عليحال كل هذه أمثلة زي ما قلنا لما يكونوا أربعة شو
+
+177
+00:15:59,640 --> 00:16:06,480
+بنسميهم؟ الـ butyldioic acid الأن لاحظوا لو عندي
+
+178
+00:16:06,480 --> 00:16:11,240
+أربعة و فيهم ال triple bond شو بدي أسمي في هذه
+
+179
+00:16:11,240 --> 00:16:11,880
+الحالة؟
+
+180
+00:16:14,280 --> 00:16:19,320
+بدي أحطها لل triple bond آين فبدي أصبح ابيوتاين
+
+181
+00:16:19,320 --> 00:16:27,640
+dioic acid الان هل بلزم ان احدد موقع لل آين في هذه
+
+182
+00:16:27,640 --> 00:16:32,600
+الحالة لأ بس في حالات تانية لو المراكب كبير بلزم
+
+183
+00:16:32,600 --> 00:16:36,180
+احدد موقع يعني مثلا لو كان عندى ست ذرات كربون او
+
+184
+00:16:36,180 --> 00:16:41,680
+سبعة واحد اتنين تلات اربع خمس ست سبعة وحطيت هنا
+
+185
+00:16:41,680 --> 00:16:50,700
+حامضوحطيت هنا حامض هذا صار هبتين
+
+186
+00:16:50,700 --> 00:16:55,920
+ديويك أسد الان لو حطيتي triple point ممكن تكون هنا
+
+187
+00:16:55,920 --> 00:17:03,580
+ممكن تكون هنا واضح فبالتالي كام هبتين ديويك أسد
+
+188
+00:17:03,580 --> 00:17:09,720
+ممكن في هذه الحالة انا
+
+189
+00:17:09,720 --> 00:17:13,590
+لو جبتلكوا هذا يعني قولتلكوا بسؤالHow many
+
+190
+00:17:13,590 --> 00:17:18,950
+heptadioic acids are possible؟ طيب، إيه كويس،
+
+191
+00:17:18,950 --> 00:17:30,230
+خلّيني أقول هذا ال two heptadioic
+
+192
+00:17:30,230 --> 00:17:33,670
+acids، إيه كويس؟ لو إجت هنا
+
+193
+00:17:53,670 --> 00:18:04,430
+بعدين لو مشيناها كمان مرة طب لو عدينا من هنا بس
+
+194
+00:18:04,430 --> 00:18:10,380
+مركبين بس مركبينلأنه بقدر أعد من الجهتين يعني مش
+
+195
+00:18:10,380 --> 00:18:14,860
+أربعة أو خمس زي من بعض بتخيلها بس مركبين ال two
+
+196
+00:18:14,860 --> 00:18:18,820
+-heptane-dioic acid و ال three-heptane-dioic acid
+
+197
+00:18:18,820 --> 00:18:22,320
+واضح؟ هذا ماجيش بعده four من هنا يعني أنا صح بقدر
+
+198
+00:18:22,320 --> 00:18:26,520
+أقول one, two, three, four بس في عندي عد تاني one,
+
+199
+00:18:26,680 --> 00:18:31,750
+two, three، أن هو الأولى؟دائما ال lower numbering
+
+200
+00:18:31,750 --> 00:18:36,690
+اللي هي فيها أرقام قليلة فهذه الأشياء يعني دائما
+
+201
+00:18:36,690 --> 00:18:42,890
+ينتبهوا إليها الآن ممكن مع البيوتين يكون .. مع
+
+202
+00:18:42,890 --> 00:18:48,810
+البيوتين يكون بيوتين بمعنى double bond مش triple
+
+203
+00:18:48,810 --> 00:18:53,720
+bondلاحظوا في حالة الـ double bond بتجيني ظاهرة
+
+204
+00:18:53,720 --> 00:18:56,320
+غير موجودة في الـ triple bond اللي هي ظاهرة الـ
+
+205
+00:18:56,320 --> 00:18:59,880
+cis و الـ trans ال triple bond linear اتفقنا احنا
+
+206
+00:18:59,880 --> 00:19:04,420
+ان ال triple bond linear دائما حوالين ال triple
+
+207
+00:19:04,420 --> 00:19:10,440
+bond ازاوي كدهش؟ 180 يعني اي جزء ولو هنا تنور اسمه
+
+208
+00:19:10,440 --> 00:19:16,530
+اكمال لكن حقيقة اي جزءدبل بوند هو عبارة عن linear
+
+209
+00:19:16,530 --> 00:19:20,530
+molecule بس لما بيصير عندي double bond و بيكونها
+
+210
+00:19:20,530 --> 00:19:24,130
+مجموعات مختلفة و مع المجموعات مختلفة بيصير عندي
+
+211
+00:19:24,130 --> 00:19:29,090
+إمكانية لظاهراتالـ cis والـ trans فلو إجينا على
+
+212
+00:19:29,090 --> 00:19:34,790
+هذا الحامض اللي هو الـ 2-butyldioic acid أو الـ
+
+213
+00:19:34,790 --> 00:19:40,010
+butyldioic acid واطلعنا على مجموعات الحامض هنا كيف
+
+214
+00:19:40,010 --> 00:19:46,330
+اتجاهها؟ في عنده cis وفي عنده trans في عنده cis
+
+215
+00:19:46,330 --> 00:19:55,210
+وفي عنده trans الآن الـ cis بيسموه malic acidالسس
+
+216
+00:19:55,210 --> 00:20:03,750
+شو بيسموه ماليك أسد والترانس اثيومارك أسد لاحظوا
+
+217
+00:20:03,750 --> 00:20:09,610
+بدياكم اتميزوه عن التلات كربونات اسمها مالونك في
+
+218
+00:20:09,610 --> 00:20:13,150
+التلات كربونات الاسم ال common malonic الآن هنا
+
+219
+00:20:13,150 --> 00:20:23,200
+الاسم ماليك ماليك أسد الآن الترانس منهfumeric acid
+
+220
+00:20:23,200 --> 00:20:29,340
+هدولة حقيقة الإسمين جايين من أسماء التفاح وبعض
+
+221
+00:20:29,340 --> 00:20:34,520
+الأعشاب اللاتينة من الأحماض الشهيرة ولمفصولة
+
+222
+00:20:34,520 --> 00:20:38,780
+الزمان وإذا حتى يعني مش مصدقين إذا ناس اشتروا كتاب
+
+223
+00:20:38,780 --> 00:20:43,320
+ال organ الchemistryبلاحظوا أن صفحة الغلاف تبعته
+
+224
+00:20:43,320 --> 00:20:47,620
+مرسوم عليها تفاحة خضرة لأن التفاحة الخضرة أو
+
+225
+00:20:47,620 --> 00:20:52,000
+التفاح أساس هذا الحامض شايفين التفاحة اللي هيك
+
+226
+00:20:52,000 --> 00:20:57,700
+خضرة عصفار اللي اشتروا الكتاب Malic and fumaric
+
+227
+00:20:57,700 --> 00:21:02,080
+acid طبعا الماليك و ال fumaric acid أسماء common
+
+228
+00:21:02,080 --> 00:21:08,500
+names مطلوب نحفظهم بالذات هدولةوبتايالي مرات في
+
+229
+00:21:08,500 --> 00:21:11,560
+تجربة في المختبر بيمروا عليك وماعرفش إذا أخدت
+
+230
+00:21:11,560 --> 00:21:15,520
+ماليكوفيوماريك
+
+231
+00:21:15,520 --> 00:21:19,460
+أسد المفروض في طالبة organic تحفظهم الآن لما بيكون
+
+232
+00:21:19,460 --> 00:21:25,240
+عنده حامضين على البنزين بيستعملوا إذا كانوا على
+
+233
+00:21:25,240 --> 00:21:29,300
+الـ orthoposition of phthalic acid على الميتا
+
+234
+00:21:29,300 --> 00:21:39,540
+ايزوفتاليك أسد وعلى ال باراتيريفتاليك أسدواضح؟ إذا
+
+235
+00:21:39,540 --> 00:21:43,860
+فى عندى الـPhthalic Acid و الـIso-Phthalic Acid و
+
+236
+00:21:43,860 --> 00:21:48,760
+الـTere-Phthalic Acid أقل تقدير لازم تكونوا عارفين
+
+237
+00:21:48,760 --> 00:21:51,780
+و حافظين الـPhthalic Acid لأنه بعد شوية هتتعلموا
+
+238
+00:21:51,780 --> 00:21:56,160
+أنه الـMalic Acid و الـPhthalic Acid بنعمل منهم
+
+239
+00:21:56,160 --> 00:22:00,680
+Unhydrates بينما بنعملهم مش من مركبات تانية يعني
+
+240
+00:22:00,680 --> 00:22:07,260
+هدول المركبات تحديدة الـMalic Acidو ال ethylic
+
+241
+00:22:07,260 --> 00:22:11,120
+acid لما ناخد ال unhydrates هنتعلم انه they can
+
+242
+00:22:11,120 --> 00:22:15,020
+form unhydrates ممكن يعملوا unhydrates التاليين
+
+243
+00:22:15,020 --> 00:22:20,520
+مابيعملوش بس هدول المركبين في عامل مشترك بينهم انه
+
+244
+00:22:20,520 --> 00:22:25,360
+they can form unhydrates يعني بيفقدوا الميه و
+
+245
+00:22:25,360 --> 00:22:30,000
+بيعملوا شكل معين لما ناخد ال unhydrates بنركز عليه
+
+246
+00:22:30,000 --> 00:22:30,380
+اكثر
+
+247
+00:22:52,220 --> 00:22:57,060
+الآن نجي لـPhysical Properties of Acids زي ما
+
+248
+00:22:57,060 --> 00:23:02,020
+اتفقنا أننا عادة بناخد العائلات العضوية تسمية،
+
+249
+00:23:02,020 --> 00:23:08,660
+خواص، تحضير، تفاعلات، واضح؟ دائما تسمية، خواص،
+
+250
+00:23:08,660 --> 00:23:14,360
+تحضير، تفاعلات، هذا اللي بنمشي عليه أهم شغلة بتميز
+
+251
+00:23:14,360 --> 00:23:19,820
+الأحمد قصة حقيقة الـhydrogen bondingيعني الـ
+
+252
+00:23:19,820 --> 00:23:23,020
+hydrogen bonding اللي هي الـ H اللي موجودة على
+
+253
+00:23:23,020 --> 00:23:26,360
+القهة دي مهمة كتير ممكن يعملوا hydrogen bonding
+
+254
+00:23:26,360 --> 00:23:30,700
+بطرق كثيرة وفعلا ممكن نطلع على حامضين كيف بيعملوا
+
+255
+00:23:30,700 --> 00:23:37,420
+hydrogen bonding يعني هذا يعتبر حامض وهذا يعتبرحمض
+
+256
+00:23:37,420 --> 00:23:43,020
+تاني لاحظوا بين هذه ال H و ال O في الرابط ال .. ال
+
+257
+00:23:43,020 --> 00:23:47,220
+dash المقطعة هذه عبارة عن hydrogen bond وهنا في
+
+258
+00:23:47,220 --> 00:23:52,060
+كمان hydrogen bond هذا الكلام بيقدي إلى إيش؟ بيقدي
+
+259
+00:23:52,060 --> 00:23:57,820
+إلى إن ال boiling point لهذه الأحماض تصير مرتفعة
+
+260
+00:23:57,820 --> 00:24:01,420
+جدا لأنها عاملة intramolecular forces فإذا بتطلع
+
+261
+00:24:01,420 --> 00:24:09,010
+مثلا على ال formic acid أبسط حامضمية واحد قارنوا
+
+262
+00:24:09,010 --> 00:24:12,270
+انتوا بالميثان اللي هو كربونا واحدة بس فيش فيه
+
+263
+00:24:12,270 --> 00:24:15,230
+hydrogen bonding ناجس مية وستين يعني الفرق بينهم
+
+264
+00:24:15,230 --> 00:24:20,030
+حوالي مائتين وستين درجة ايش اللي خلي هذا يكون
+
+265
+00:24:20,030 --> 00:24:25,470
+مرتفع جدا زي وزي الميه تقريبا الacetic acid مية و
+
+266
+00:24:25,470 --> 00:24:32,930
+تمانتعاشالاسيتك أسد 118 عالي جداً لما أجيب روبانوك
+
+267
+00:24:32,930 --> 00:24:43,770
+أسد 141، 164، 205 زي ما بتلاحظوا أنه ال
+
+268
+00:24:43,770 --> 00:24:48,650
+boiling point عالية ال solubility تقريبا نفس
+
+269
+00:24:48,650 --> 00:24:52,290
+الفكرة اللي حكيناها في ال alcohols أن ال lower
+
+270
+00:24:52,290 --> 00:24:57,180
+acids are solubleليش؟ لأنه بيكون متغلب فيهم جانب
+
+271
+00:24:57,180 --> 00:25:03,260
+الـOH لكن لما الحمض بيكبر زي الـ hexanoic acid
+
+272
+00:25:03,260 --> 00:25:08,440
+بيصير جزء الـOH هذا اللي هو جزء الذوبان في الميه
+
+273
+00:25:08,440 --> 00:25:12,840
+أو الـhydrophilic اللي بيدوب في الميه مقارنة
+
+274
+00:25:12,840 --> 00:25:20,250
+بالجزء اللي بيدوبش في الميه هذاو لذلك الأحماط
+
+275
+00:25:20,250 --> 00:25:24,010
+الصغيرة زي ال formic acid و ال acetic acid و ال
+
+276
+00:25:24,010 --> 00:25:27,910
+propanoic acid و ال butanoic acid هم سوليوبيلين
+
+277
+00:25:27,910 --> 00:25:31,290
+لما أجعل الhexanoic acid بلاحظة السوليوبيلية واحد
+
+278
+00:25:31,290 --> 00:25:35,430
+جرام في كل مائة من الميه خلاص بيبطل يدوب تقريبا
+
+279
+00:25:36,450 --> 00:25:42,550
+ليش؟ لأنه بيصير ال non-polar part أكبر كتير من ال
+
+280
+00:25:42,550 --> 00:25:48,690
+polar part فهذه الأحماض مكونة من شغلتين، non-polar
+
+281
+00:25:48,690 --> 00:25:54,850
+part و polar part واضح؟ فبالأحماض الصغيرة ال polar
+
+282
+00:25:54,850 --> 00:25:59,030
+part غالب، بالأحماض الكبيرة ال non-polar part
+
+283
+00:25:59,030 --> 00:26:04,230
+affects the solubility and makes them insoluble in
+
+284
+00:26:04,230 --> 00:26:11,740
+waterهذا بالنسبة للـ boiling point بالنسبة للـ
+
+285
+00:26:11,740 --> 00:26:20,340
+solubility تبتيجي شغلة بالنسبة للـ acidity
+
+286
+00:26:20,340 --> 00:26:25,220
+الحامضية بتهيألي احنا لما حكينا على ال alcohols
+
+287
+00:26:25,220 --> 00:26:30,060
+اكثر من مرة ركزنا على ال acidity قولنا ان هدول
+
+288
+00:26:30,060 --> 00:26:34,100
+الأحماض بالنسبة لل alcohols تعتبر ال acidity
+
+289
+00:26:34,100 --> 00:26:39,230
+تبعتهمأعلى بكتير يعني ال alcohol ال BKA كداش كان
+
+290
+00:26:39,230 --> 00:26:45,530
+تقريبا 17 و 18 و 16 الأحماض زي ال acetic acid
+
+291
+00:26:45,530 --> 00:26:51,690
+أربعة و خمسة فهدولة أعلى كتير كتير من ال alcohol
+
+292
+00:26:51,690 --> 00:26:55,410
+في ال acidity شو هو السبب أنهم أعلى كتير كتير من
+
+293
+00:26:55,410 --> 00:26:59,370
+ال alcohol في ال acidity أنه لما بيفقد هذا ال
+
+294
+00:26:59,370 --> 00:27:03,170
+proton لما بيفقد هذا ال proton في عنده هنا ال
+
+295
+00:27:03,170 --> 00:27:08,410
+minus chargeممكن تكون على هذه الأكسجينة و ممكن تلف
+
+296
+00:27:08,410 --> 00:27:12,590
+بهذا الشكل وتصير على الأكسجينة التانية إذا السبب
+
+297
+00:27:12,590 --> 00:27:18,100
+هو ال resonanceواضح؟ الـ stability لـ negative ion
+
+298
+00:27:18,100 --> 00:27:22,360
+is due to resonance stability of the negative ion
+
+299
+00:27:22,360 --> 00:27:27,720
+is due to resonance فال acids they are .. يعني
+
+300
+00:27:27,720 --> 00:27:32,260
+their acidity is high due to resonance هذه الفكرة
+
+301
+00:27:32,260 --> 00:27:37,040
+الأساسية لما بدأ اقارن أنا حامض بكحول يعني لما بدأ
+
+302
+00:27:37,040 --> 00:27:42,320
+اقارن مثلا الاثانون بيعمل الايون الـ minus CH2 O
+
+303
+00:27:42,320 --> 00:27:51,820
+minus CH3مع الـ acid C double bond O O minus CH3
+
+304
+00:27:51,820 --> 00:27:58,960
+هنا ال BKA تقريبا كانت لإيثانول 17 هنا ال BKA
+
+305
+00:27:58,960 --> 00:28:04,940
+أربعة و نص واضح؟ ليه شد أعلى بكتير من هذا؟لأن هنا
+
+306
+00:28:04,940 --> 00:28:09,500
+الـ charge بيقول عنها localized يعني متموضعة في
+
+307
+00:28:09,500 --> 00:28:14,140
+مكانها، ما بتتغيرش زي واحد حامل شغلة طول الطريق
+
+308
+00:28:14,140 --> 00:28:17,780
+بإيد واحدة، شو بيصير له إيده؟ بتتعب، لكن واحد عنده
+
+309
+00:28:17,780 --> 00:28:22,880
+إتين، بيكون بيعمل resonance فهنا عندي localized
+
+310
+00:28:22,880 --> 00:28:28,280
+charge وهنا في عند الـcharged إيش بتكون؟
+
+311
+00:28:28,280 --> 00:28:32,650
+Delocalized مرة هناو مرة هنا يعني هذا ال resonance
+
+312
+00:28:32,650 --> 00:28:38,970
+structure التاني تبعه كيف بده يكون CH3C
+
+313
+00:28:38,970 --> 00:28:44,550
+لو حركنا هذا ال minus هيك وهذه هنا بهذا الشكل O
+
+314
+00:28:44,550 --> 00:28:48,750
+minus double bond O فزي ما بتلاحظوا ال minus هذه
+
+315
+00:28:48,750 --> 00:28:52,590
+مرة موجودة على هذه ال oxygen مرة موجودة على هذه ال
+
+316
+00:28:52,590 --> 00:28:55,370
+oxygen فال minus charge is
+
+317
+00:29:00,220 --> 00:29:03,860
+والـ Delocalization هو أحد أسباب الـ stability of
+
+318
+00:29:03,860 --> 00:29:08,720
+its charge دايما، زي ما قلنا، الحمل إذا توزع،
+
+319
+00:29:08,720 --> 00:29:12,940
+ينشد، هملاحظين؟ هذه محمولة على جهتين الـ negative
+
+320
+00:29:12,940 --> 00:29:16,640
+charge مش على جهة واحدة، Delocalized وبالتالي، الـ
+
+321
+00:29:16,640 --> 00:29:20,940
+Ion السالب تبات وبيزيد، الحامض بيصير أقوى هذا
+
+322
+00:29:20,940 --> 00:29:26,950
+الكلام، لو أنا كنت بقارن حامضمع كحول، لو كنت بقارن
+
+323
+00:29:26,950 --> 00:29:36,170
+حامض مع كحول، لكن في .. وعشانك لاحظوا في الأحمار
+
+324
+00:29:36,170 --> 00:29:45,370
+بشكل عام لما تتطلعوا على ال BKA معظمها
+
+325
+00:29:45,370 --> 00:29:51,720
+في منطقة التلاتة والاربعة، واضح؟أتنين، أربع، أربع،
+
+326
+00:29:51,720 --> 00:29:55,840
+أربع، تلاتة، اتنين، واطفر، فمعظمها بينما لو بدأ
+
+327
+00:29:55,840 --> 00:30:02,820
+أقارن بالإيثانول والميّه هذا كحول تقريبا، وهذا
+
+328
+00:30:02,820 --> 00:30:09,260
+ميّه 16 و15، واضح؟ الفينول بدأ يصير فيه resonance
+
+329
+00:30:09,260 --> 00:30:13,900
+بس ال resonance على أكسوجين و Carbon بينزل لعشرة،
+
+330
+00:30:13,900 --> 00:30:19,050
+لكن وين مافيش resonance نهائيهدولة التلين اللي تحت
+
+331
+00:30:19,050 --> 00:30:23,730
+الاثانون والمي مافيش إمكانية وبالتالي هدولة
+
+332
+00:30:23,730 --> 00:30:27,790
+بنلاقيهم إحنا إيش في دايل الخيبة بينما بشكل عام
+
+333
+00:30:27,790 --> 00:30:36,670
+الأحماض كلهم لهم PKA عالية due to resonance PKA
+
+334
+00:30:36,670 --> 00:30:41,610
+منخفضة acidity عالية ماكل ما ال PKA نزلت الحمضية
+
+335
+00:30:41,610 --> 00:30:46,520
+أقوى بيكون ال K a أعلىوهذا الـ Resonance بتايل
+
+336
+00:30:46,520 --> 00:30:50,700
+المرض حانة بشكل جيد الان اذا يتبع هذا الـ
+
+337
+00:30:50,700 --> 00:30:56,890
+Resonance نقطةإنه في نفس الحامض في نفس الحامض لو
+
+338
+00:30:56,890 --> 00:31:01,470
+حطيت electron with a drawing group أو electron
+
+339
+00:31:01,470 --> 00:31:05,530
+donating group شو بتأثر على ال acidity؟ يعني مثلا
+
+340
+00:31:05,530 --> 00:31:10,570
+هي ال acidic acid وفي resonance طب لو حطيت
+
+341
+00:31:10,570 --> 00:31:15,470
+chloroacetic acid و بعدك حطيت dichloroacetic acid
+
+342
+00:31:15,470 --> 00:31:19,690
+و بعدك حطيت trichloroacetic acid و سؤالتك which is
+
+343
+00:31:19,690 --> 00:31:26,830
+more acidic؟الـ trichloroacetic acid في عملية
+
+344
+00:31:26,830 --> 00:31:31,930
+electron withdrawing يعني في inductive effect
+
+345
+00:31:31,930 --> 00:31:36,910
+فلاحظوا هنا لما أنا بحكي عن الـ acetic acid هذا
+
+346
+00:31:36,910 --> 00:31:43,210
+التنقل اللي هنا شو احنا سميناه؟ resonance effect
+
+347
+00:31:43,210 --> 00:31:47,390
+الآن هذا ال resonance موجود فيهم كلهم إن زاد على
+
+348
+00:31:47,390 --> 00:31:54,130
+ال resonance ال resonance ما زال موجودزاد عليه الـ
+
+349
+00:31:54,130 --> 00:31:58,210
+inductive effect إنه فيه مجموعة بتسحب الإلكترونات
+
+350
+00:31:58,210 --> 00:32:02,570
+بتساعد في حمل الإلكترونات فصار عندي تأثيرين صار
+
+351
+00:32:02,570 --> 00:32:07,030
+عندي بدل التأثير اتنين inductive effect plus
+
+352
+00:32:07,030 --> 00:32:11,370
+resonance effect وبالتالي هذا الحامض اللي هو الـ
+
+353
+00:32:11,370 --> 00:32:16,130
+trichloroacetic acid بتكون ال acidity تبعته أقوى
+
+354
+00:32:16,130 --> 00:32:22,560
+كتير منمن الاسيتك أسد او من ال .. طبعا لو اجيتوا و
+
+355
+00:32:22,560 --> 00:32:26,660
+قارنتوا ال trifluoroacetic acid مع ال trichloro ال
+
+356
+00:32:26,660 --> 00:32:31,400
+trifluoro أقوى كتير ماعرفش اذا انا حاطينلكم هاي
+
+357
+00:32:31,400 --> 00:32:35,780
+القيم هنا لما بدكم تحديدا للاسيتك أسد مع ال
+
+358
+00:32:35,780 --> 00:32:39,920
+trichloroacetic acid ان هو اللي قولنا عنه أعلى
+
+359
+00:32:39,920 --> 00:32:44,340
+واحد هاي ال trichloroacetic acid شايفينه؟ و هاي ال
+
+360
+00:32:44,340 --> 00:32:50,230
+acidic acid ال acidic acid four point7.4 لـ
+
+361
+00:32:50,230 --> 00:32:56,470
+Trichloroacetic acid 0.7 ملاحظين قداش صار أقوى
+
+362
+00:32:56,470 --> 00:33:01,150
+كحمض بالتالي لو بدو ييجي على الإدل ولا إش بدو
+
+363
+00:33:01,150 --> 00:33:04,770
+يحرقهم ال Acetic acid بحرق الإدل بس لما يكون مخفف
+
+364
+00:33:04,770 --> 00:33:09,590
+بمية ممكن الناس يعني ييجي على الإدل إذا في جرح
+
+365
+00:33:09,590 --> 00:33:13,710
+بيحرق بس إذا خفف بمية كتير بيمسكون الناس اللي خلوه
+
+366
+00:33:13,710 --> 00:33:19,380
+بيشربوه كمان بالمناسبةبس لازم يكون مخفف و أفضل ما
+
+367
+00:33:19,380 --> 00:33:25,340
+تداويتم بيه الخل واضح؟ ليش؟ لأنه لما تدرسوا
+
+368
+00:33:25,340 --> 00:33:28,440
+biochemistry هتلاحظوا أن هذا الخل المكون من
+
+369
+00:33:28,440 --> 00:33:32,640
+كربونتين هو مصدر للمراكبات الأكبر، يعني التنين
+
+370
+00:33:32,640 --> 00:33:35,080
+بيصيروا أربعة، الأربعة بيصيروا ستة، الستة بيصيروا
+
+371
+00:33:35,080 --> 00:33:38,160
+تمانية، التمانية بيصيروا عشرة، بيصير عندى تفاعل
+
+372
+00:33:38,160 --> 00:33:42,240
+متتالي بزيد لعدد الكربونات، وبهيك بتتكون المراكبات
+
+373
+00:33:42,240 --> 00:33:46,700
+في جسم الإنسان، فنقطة الإطلاق تبعها إيش؟الـ two
+
+374
+00:33:46,700 --> 00:33:50,120
+carbons ولذلك كثير من المراكبات الطبيعية بتلاقوها
+
+375
+00:33:50,120 --> 00:33:55,020
+زوجية مش فردية يعني اتنين اربعة ستة تمانية بتلاقوش
+
+376
+00:33:55,020 --> 00:34:00,100
+سبعة أو تسعة بسهولة واضح فالـ trichloroacetic acid
+
+377
+00:34:00,100 --> 00:34:05,960
+is more acidic than acetic acid itself هذا الكلام
+
+378
+00:34:05,960 --> 00:34:11,920
+لو بدنا نقول ليش due to inductive effect ال
+
+379
+00:34:11,920 --> 00:34:16,500
+resonance effect هنا مشتركالـ resonance effect
+
+380
+00:34:16,500 --> 00:34:21,020
+مشترك ليس هو السبب يعني دائما .. دائما لما بتكون
+
+381
+00:34:21,020 --> 00:34:25,700
+.. تعملوا مقارنة .. لما بتكون تعملوا مقارنة بتكون
+
+382
+00:34:25,700 --> 00:34:30,000
+تقارنوا بالشيء اللي بيختلف .. بتكون تقارنوا بالشيء
+
+383
+00:34:30,000 --> 00:34:35,380
+المختلف واضح؟ يعني أنا لما بدي أجي أقارن مثلا
+
+384
+00:34:35,380 --> 00:34:42,680
+اتنين أبطال سن عشرين سنةوزن 80 كيلو والتانين ذكور
+
+385
+00:34:42,680 --> 00:34:48,780
+الآن الفرق اللي بينهم أكيد مش ناجح عن أنهم التانين
+
+386
+00:34:48,780 --> 00:34:53,600
+ذكور أو أنهم عشرين سنة أو أن طولهم كذا ووزنهم كذا
+
+387
+00:34:53,600 --> 00:34:57,040
+لأن هدول أنا لما نزلتهم في حلبة الملاكمة كل هذه
+
+388
+00:34:57,040 --> 00:35:00,960
+الأشياء بينهم مشتركة طب هليش واحد منهم كان بيفوز
+
+389
+00:35:00,960 --> 00:35:06,790
+على التاني والله عمل تدريب أكترواضح؟ بينما لو كنت
+
+390
+00:35:06,790 --> 00:35:11,110
+بدأ أقارن واحد عمره عشرين سنة بواحد عمره أربع سنين
+
+391
+00:35:11,110 --> 00:35:16,990
+هنا بقول إنه فرق السن هنا بقول فرق السن هو السبب
+
+392
+00:35:16,990 --> 00:35:20,670
+في فرق القوة لكن لما اتنين بيلعبوا ملا كما و اتنين
+
+393
+00:35:20,670 --> 00:35:24,710
+عشرين سنة واحد ليش بيصير أقوى من التاني؟ بتكون
+
+394
+00:35:24,710 --> 00:35:28,570
+تقولوا لأ عشان هو رجل و عمره عشرين سنة؟ طب ما
+
+395
+00:35:28,570 --> 00:35:31,730
+التاني رجل و عمره عشرين سنة؟ إذا بتكون دايما
+
+396
+00:35:31,730 --> 00:35:38,040
+تفتشوا سبب الفرقالمحدد فهنا بين هدولة سبب الفرق مش
+
+397
+00:35:38,040 --> 00:35:43,160
+ال resonance ال inductive effect هما فيهم الشغلتين
+
+398
+00:35:43,160 --> 00:35:48,160
+لكن سبب فرق الحامضية ال inductive effect لأن ال
+
+399
+00:35:48,160 --> 00:35:52,440
+resonance موجود في الحد
+
+400
+00:35:58,550 --> 00:36:01,310
+الأساس ده أموراتها بشكل عام مش في الـ .. مش في
+
+401
+00:36:01,310 --> 00:36:04,770
+الأسماع وفي الأساس بشكل عام واحد فيه رزوناس واحد
+
+402
+00:36:04,770 --> 00:36:11,870
+فيه مجتمع دائما إذا .. إذا اختلفت .. إذا اختلفت
+
+403
+00:36:11,870 --> 00:36:16,690
+الأشياء بيصير المقارنة من خلال إنه نبحث عن القيم
+
+404
+00:36:16,690 --> 00:36:21,630
+الحقيقية بالتجربة بقدرش أعطي جواب بقدرش أعطي جواب
+
+405
+00:36:21,630 --> 00:36:24,930
+وجدها واضح؟ يعني ممكن
+
+406
+00:36:26,980 --> 00:36:31,940
+كيف .. كيف يصير السؤال؟ يعني لو انت .. إجينا و
+
+407
+00:36:31,940 --> 00:36:38,220
+سألناكي أيهما أقوى الـ trifluoroacetic acid و لا
+
+408
+00:36:38,220 --> 00:36:42,940
+ال trifluoroacetic acid؟ الان أنا .. أنا بسهولة
+
+409
+00:36:42,940 --> 00:36:47,400
+بقدر أقول أنه ال trifluoro لأنه ال acid مشترك
+
+410
+00:36:48,140 --> 00:36:53,380
+وتلاتة مشتركين سالبية الفلورو صح كل الإلكترونات
+
+411
+00:36:53,380 --> 00:36:58,620
+أعلى من سالبية الكلور طيب لو أتيت أسألك بهذا الشكل
+
+412
+00:36:58,620 --> 00:37:07,140
+كنتلك سيضة بالبنط OOH CH2 وفلورو واحدة الفلورو
+
+413
+00:37:07,140 --> 00:37:14,830
+أسيتك أسد ولا تريكلورو أسيتك أسد؟صار عندى انا
+
+414
+00:37:14,830 --> 00:37:19,530
+متغيرين مش متغير واحد صار المتغير الاول اللى عندى
+
+415
+00:37:19,530 --> 00:37:22,890
+عدد الذرات اللى هنا والمتغير بتاع ال
+
+416
+00:37:22,890 --> 00:37:27,770
+electronegativity في هذه الحالة انا بقول مابعرفش
+
+417
+00:37:27,770 --> 00:37:33,370
+الجواب لازم اشوف التجربة وانتش انا بسهولة كان بعرف
+
+418
+00:37:33,370 --> 00:37:37,430
+الجواب لو كان السؤال زى هى صيدم ال point O O H
+
+419
+00:37:41,640 --> 00:37:48,400
+هنا المتغير الواحد عندى asset عندى one one atom بس
+
+420
+00:37:48,400 --> 00:37:50,600
+اتغير ال floor و ال chlorine مين more electro
+
+421
+00:37:50,600 --> 00:37:58,280
+negative ال floor لكن لو صاروا هدولة تنين يمكن
+
+422
+00:37:58,280 --> 00:38:02,800
+يكون مجموعة دول الاتنين مغطية الزيادة اللى بسببها
+
+423
+00:38:02,800 --> 00:38:07,340
+ال floor فانها لازم اعمل تجربة يعني مابقدرش اعطى
+
+424
+00:38:07,340 --> 00:38:13,220
+الجواب مباشر إذا كان عندىأكتر من الشيء وهذا الكلام
+
+425
+00:38:13,220 --> 00:38:18,040
+بالمناسبة يعني من مبادئ العلم الأساسية .. من مبادئ
+
+426
+00:38:18,040 --> 00:38:21,260
+العلم الأساسية جدا أنه إنتوا إذا بدكوا تقارنوا
+
+427
+00:38:21,260 --> 00:38:27,420
+شغلات .. إذا بدكوا تقارنوا شغلات بدكوا توحدوا جميع
+
+428
+00:38:27,420 --> 00:38:34,940
+الظروف .. بدكوا توحدوا جميع الظروف ما عدا متغير
+
+429
+00:38:34,940 --> 00:38:42,420
+واحدبتكون تواحده جميع الظروف مع دقاش، متغير واحد،
+
+430
+00:38:42,420 --> 00:38:45,460
+هذا الكلام ممكن أعطيكم عليه مثال من العلم، من
+
+431
+00:38:45,460 --> 00:38:49,120
+الكيميا وممكن مثال من السياسة، من الدنيا، الآن لما
+
+432
+00:38:49,120 --> 00:38:54,860
+أخدتوا قوانين الغازاتالغاز محكوم بإيش؟ بالضغط
+
+433
+00:38:54,860 --> 00:39:00,160
+والحجم ودرجة الحرارة والمولات كان عندى أربع
+
+434
+00:39:00,160 --> 00:39:06,160
+متغيرات لما كنت بعمل مقارنة كيف كنت أنا أقارن كنت
+
+435
+00:39:06,160 --> 00:39:11,120
+أثبت متغيرات وأقارن متغيرات تانية بس مابقدرش أسيب
+
+436
+00:39:11,120 --> 00:39:16,780
+الأربعة يتغيرواهذا الغاز بضغط معين، بحجم معين،
+
+437
+00:39:16,780 --> 00:39:19,900
+number of moles معين، temperature معينة و هداك
+
+438
+00:39:19,900 --> 00:39:24,800
+بالاربع أشياء مختلفة، بتصير العملية إياش صعبة،
+
+439
+00:39:24,800 --> 00:39:29,680
+فالإنسان العلمي لما بده يقارن، بده يوحدالظروف ..
+
+440
+00:39:29,680 --> 00:39:35,200
+بده يوحد الظروف و بعدين بده ييجي يقارن أما نيجي
+
+441
+00:39:35,200 --> 00:39:39,420
+نعمل حالنا شاطرين .. نعمل حالنا شاطرين و بدنا
+
+442
+00:39:39,420 --> 00:39:46,180
+نقارن بظروف مختلفة فالكلام ما بصيرش ربما مثلا يعني
+
+443
+00:39:46,180 --> 00:39:51,460
+أعطيكوا مثال إيش منطق التفكير الغربي .. إيش منطق
+
+444
+00:39:51,460 --> 00:39:58,680
+التفكير الغربي التفكير الغربي فكر بشكل آتيإنه بدوا
+
+445
+00:39:58,680 --> 00:40:04,180
+يوقع مثلا الفلسطينيين بإشكالية
+
+446
+00:40:04,180 --> 00:40:07,960
+مع الإسلاميين ومع الحكومات الإسلامية وما إلى ذلك
+
+447
+00:40:07,960 --> 00:40:14,580
+فإنها بدوا يثبت فشل كل الإسلام مش حركة معينة
+
+448
+00:40:14,580 --> 00:40:21,440
+العداوة عامة صار في حكومة بشكل أو بآخر اسمها حكومة
+
+449
+00:40:21,440 --> 00:40:24,380
+حركة إسلامية إيش الحل اللي بدوا يعملوا؟ بدوا يثبت
+
+450
+00:40:24,380 --> 00:40:28,790
+للناس إن هدولةسواد وجه ما جاش منهم غير الفلس
+
+451
+00:40:28,790 --> 00:40:31,930
+والاسبالة في الشوارع و هلوم هلوم هلوم هلوم هلوم
+
+452
+00:40:31,930 --> 00:40:38,310
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+453
+00:40:38,310 --> 00:40:38,390
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+454
+00:40:38,390 --> 00:40:38,750
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+455
+00:40:38,750 --> 00:40:40,590
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+456
+00:40:40,590 --> 00:40:40,590
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+457
+00:40:40,590 --> 00:40:46,350
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+458
+00:40:46,350 --> 00:40:53,710
+هلوم
+
+459
+00:40:54,720 --> 00:40:59,480
+مافيش إمكانية للمقارنة كيف .. كيف أنا بدي أقارن
+
+460
+00:40:59,480 --> 00:41:04,480
+تماما ممكن واحدة منكوا تكون ذكية كتير لكن هذه أمها
+
+461
+00:41:04,480 --> 00:41:08,740
+الله يرحمها توفتوا عندها ست إخوة في الدار و واحدة
+
+462
+00:41:08,740 --> 00:41:11,520
+فاضية و عامليني لا فاصليني لا أقضى لحالة و أقعد
+
+463
+00:41:11,520 --> 00:41:14,900
+أدرسي و ما إلى ذلك هل بقدر أنا أعمل مقارنة بينهم
+
+464
+00:41:14,900 --> 00:41:19,870
+في الذكاء ولا .. ما الظروف إيش؟الظروف مختلفة،
+
+465
+00:41:19,870 --> 00:41:23,670
+فاللي بده يقارن، يعني لو بده أقول مين فيهم أذكى من
+
+466
+00:41:23,670 --> 00:41:28,990
+التانية، بده أجي لأختينالتنتين توم خلّينا نقول
+
+467
+00:41:28,990 --> 00:41:32,590
+ساكنين بنفس البيت، كل واحدة معطينها غرفة، معطينها
+
+468
+00:41:32,590 --> 00:41:36,390
+كمبيوتر، معطينها كتاب، معطينها مصروف، معطينها أكل،
+
+469
+00:41:36,390 --> 00:41:40,550
+وفي الآخر هذه بتيجي اللي هي جايبالي 90% و هذه
+
+470
+00:41:40,550 --> 00:41:44,910
+بالعافية بتجيبي ال 60% و أجتا بقول أكيد هذه مخها
+
+471
+00:41:44,910 --> 00:41:51,030
+أنضف شوية من هذه، لأن أنا وحدت كل إيشكل الظروف
+
+472
+00:41:51,030 --> 00:41:56,850
+فهنا نفس الفكرة واضح؟ لما بدي أقارن بدي أوحد
+
+473
+00:41:56,850 --> 00:42:02,710
+الظروف ما عدا المتغير اللي بندرسه بالمناسبة هذا
+
+474
+00:42:02,710 --> 00:42:07,730
+الكلام هو سبب إشكالية في العلم إنه كتير شغلات لحد
+
+475
+00:42:07,730 --> 00:42:13,610
+الآن الناس مش قادرين بالظبط يحكموا عليها يعني مثلا
+
+476
+00:42:13,610 --> 00:42:17,150
+كتير من الأشياء بيجوا بيقولوا لكوا والله هالشغلة
+
+477
+00:42:17,150 --> 00:42:24,180
+بتسبب سرطان ولا لأ؟أو بتسبب مشاكل صحية ولا لأ؟ طب
+
+478
+00:42:24,180 --> 00:42:27,700
+ليش احنا مش قادرين نحكم؟ لسبب بسيط أن البني آدم
+
+479
+00:42:27,700 --> 00:42:33,180
+اللي بندرسه حقيقة هو مش بس معرض مش بس معرض مثلا
+
+480
+00:42:33,180 --> 00:42:37,790
+للكيمويات اللي ارتشت على الفراولةما هو المشكلة لو
+
+481
+00:42:37,790 --> 00:42:43,030
+أن البني آدم محطوط في جو معزول تماما و بس بياكل
+
+482
+00:42:43,030 --> 00:42:47,010
+فراولة مرشوشة و التاني بياكل فراولة مش مرشوشة و
+
+483
+00:42:47,010 --> 00:42:50,670
+هذا مرض و هذا لأ بقول أنه السبب من الفراولة لكن
+
+484
+00:42:50,670 --> 00:42:55,630
+البني آدم معرضممكن واحد يكون ساكن عند ساحة
+
+485
+00:42:55,630 --> 00:43:00,450
+التكسيات، بشم إرصاص في البنزين، و هالومة جرّان
+
+486
+00:43:00,450 --> 00:43:03,910
+كتير، و التاني ساكن في منطقة رفي. هاي متغير تاني
+
+487
+00:43:03,910 --> 00:43:09,230
+صار عنده. ممكن هذا بياكل بندورة مرشوشة و هذا لأ، و
+
+488
+00:43:09,230 --> 00:43:11,670
+هذا بياكل سبانخ مرشوشة و هذا لأ، و بياكل فراولة
+
+489
+00:43:11,670 --> 00:43:15,270
+مرشوشة و هذا لأ. الآن السؤال عاد، بقدر أنا أحلف
+
+490
+00:43:15,270 --> 00:43:20,530
+يمين أن هذا سبب مشكلته الفراولة؟ طب ما هو ..
+
+491
+00:43:20,790 --> 00:43:25,530
+الاختلاف بينهم بالهوى و بالميه اللى بيشربوها، هذا
+
+492
+00:43:25,530 --> 00:43:28,510
+بيشرب من البيرو، هذا بيشرب الهوى و الميه و
+
+493
+00:43:28,510 --> 00:43:31,550
+البندورة و الخيار و الفراولة بكل ما تحويه من
+
+494
+00:43:31,550 --> 00:43:37,130
+مبيدات، شو عرفنا ان الفراولة هي السببنفس الاشي
+
+495
+00:43:37,130 --> 00:43:41,550
+مشكلة مثلا أمواج الجوال لليوم لما ييجيوا يركبوا
+
+496
+00:43:41,550 --> 00:43:45,290
+برج جوال على دار ناس بيصيروا الجيران يتقاتلوا و
+
+497
+00:43:45,290 --> 00:43:50,550
+الله هذا برج الجوال بيسبب مشاكل ولا لأ و كل القصص
+
+498
+00:43:50,550 --> 00:43:54,910
+ليش احنا مش عارفين و مش قادرين لأنه كتير متغيرات
+
+499
+00:43:54,910 --> 00:44:00,810
+هي بس أنا عندي أمواج الجوال عندي جوال على كيمويات
+
+500
+00:44:00,810 --> 00:44:05,910
+على هوا ملوث يمكن نيصل إشعاع ذرع كمان من فكوشيما
+
+501
+00:44:07,890 --> 00:44:13,270
+تستغربوش، هذه دنيا واسعة يعني التاني يوم أو تالت
+
+502
+00:44:13,270 --> 00:44:16,530
+يوم من مفاعل Fukushima كل الأسماك اللي
+
+503
+00:44:16,530 --> 00:44:22,110
+بـCalifornia ماتت شوفتوا الصور بتاعتها؟ اكتبوا على
+
+504
+00:44:22,110 --> 00:44:28,030
+Google بس موت الأسماك في California بعد تسنامي
+
+505
+00:44:28,030 --> 00:44:32,200
+اليابانجداش المسافة بين اليابان وكاليفورنيا
+
+506
+00:44:32,200 --> 00:44:38,800
+هتشوفوا جرفات عدد كبير من الجرفات بس بزيه سمك ميت
+
+507
+00:44:38,800 --> 00:44:43,060
+البحر ممكن البناء الأدمين يمشوا عليه لإن كل السمك
+
+508
+00:44:43,060 --> 00:44:48,160
+مات وكان طاف فوق سطح البحر الدنيا يعني التأثيرات
+
+509
+00:44:48,160 --> 00:44:53,220
+هذه بتنتقل لما صارت شيرنوبال مثلا هو شيرنوبال
+
+510
+00:44:53,220 --> 00:44:59,330
+localized ولاde-localized عليها البنجف على ال
+
+511
+00:44:59,330 --> 00:45:03,310
+preparation of carboxylic acids
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U.srt
new file mode 100644
index 0000000000000000000000000000000000000000..cfe96dc7aab919308b0e221d9d28baacf869b3f2
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U.srt
@@ -0,0 +1,1784 @@
+1
+00:00:08,740 --> 00:00:13,200
+اليوم بنكمل الجزء الأخير إن شاء الله في الموضوع ال
+
+2
+00:00:13,200 --> 00:00:18,900
+الديهايدز والكيتونز وممكن ننتقل للفصل اللي بعده 
+
+3
+00:00:18,900 --> 00:00:24,660
+اللي هو الأحماض الكربوكسيلية آخر شغلة اتكلمنا عنها 
+
+4
+00:00:24,660 --> 00:00:29,590
+المرة الماضية كانت ال acidity of alpha hydrogen
+
+5
+00:00:29,590 --> 00:00:32,650
+يمكن 
+
+6
+00:00:32,650 --> 00:00:38,890
+أن تفقد في وجود قاعدة قوية السبب أنه يمكن أن تفقد
+
+7
+00:00:38,890 --> 00:00:44,140
+أن الأيون السالب اللي بتكون بإمكانه يعمل resonance
+
+8
+00:00:44,140 --> 00:00:48,260
+بنقول عنه الإنوليت أيون يعني ممكن يكون محمول على
+
+9
+00:00:48,260 --> 00:00:52,460
+الكربون ممكن يكون محمول على الأكسجين هذا ال
+
+10
+00:00:52,460 --> 00:00:55,520
+resonance هو اللي بيقدر ال stability لل أيون 
+
+11
+00:00:55,520 --> 00:01:01,260
+السالب وبيقدر أن ال alpha هيدروجين يمكن أن تفقد
+
+12
+00:01:01,260 --> 00:01:06,070
+الآن هناخد تطبيقات على الاستفادة من هذه الفكرة يعني
+
+13
+00:01:06,070 --> 00:01:10,010
+احنا أخدناها كفكرة أن ال alpha Hydrogen يمكن أن
+
+14
+00:01:10,010 --> 00:01:13,810
+تفقد، الآن في تطبيقات في استفادة من هذا الكلام
+
+15
+00:01:13,810 --> 00:01:19,630
+واضح؟ من التطبيقات على سبيل المثال لو أنا أخدت
+
+16
+00:01:19,630 --> 00:01:24,230
+مركب زي ال cyclohexanone واطلعت هل ال 
+
+17
+00:01:24,230 --> 00:01:29,010
+cyclohexanone في Alpha Hydrogen الحقيقة بلاقي أنه
+
+18
+00:01:29,010 --> 00:01:33,110
+في عدد كبير من ال alpha هيدروجينز يعني هذه الكاربون
+
+19
+00:01:33,110 --> 00:01:37,510
+هذه الكاربون ألفا والهيدروجينز اللي عليها ألفا إذا
+
+20
+00:01:37,510 --> 00:01:42,210
+أنا في عندي two هيدروجينز وبنفس الوقت على الجهة
+
+21
+00:01:42,210 --> 00:01:45,290
+التالية في عندي كمان two هيدروجينز إذا هذه
+
+22
+00:01:45,290 --> 00:01:52,210
+الكربون محاطة بأربع ألفا هيدروجينز الآن لو حطيتها
+
+23
+00:01:52,210 --> 00:01:58,170
+في base ال base ممكن تسحب منها ال H وتتكون أيونات
+
+24
+00:01:58,170 --> 00:02:02,190
+سالبة اللي بيصير أنه احنا لو حطناها في ال base مع
+
+25
+00:02:02,190 --> 00:02:05,970
+solvent هذا ال solvent بنقول عنه ديوتريتد
+
+26
+00:02:05,970 --> 00:02:14,390
+ميثانول الميثانول العادي ما مر علينا CH3OH هذا بدل 
+
+27
+00:02:14,390 --> 00:02:19,390
+ال H حطينا نظير ال H اللي هو الديوتيريوم فبنقول عنه
+
+28
+00:02:19,390 --> 00:02:24,890
+ديوتريتد ميثانول يعني ميثانول قبل في الهيدروجين 
+
+29
+00:02:24,890 --> 00:02:29,850
+بنظيره اللي هو الديوتيريوم الآن لاحظوا معنى هذا
+
+30
+00:02:29,850 --> 00:02:33,650
+حاطينه احنا بشكل كبير اللي بيصير في هذه الحالة أن 
+
+31
+00:02:33,650 --> 00:02:38,010
+ال base بتسحب ال H التفاعل بشكل عكسي بيروح بده يحط
+
+32
+00:02:38,010 --> 00:02:42,410
+بدالها ايش بيحط بدالها D لأن هنا ما فيش H بال
+
+33
+00:02:42,410 --> 00:02:46,950
+solvent بترد تاخد من ال solvent D الكلام على مدى
+
+34
+00:02:46,950 --> 00:02:50,590
+طويل ممكن يتكرر مع القادش الثاني مع القادش الثالثة
+
+35
+00:02:50,590 --> 00:02:54,690
+مع القادش الرابعة لو اجينا للتفاعل هذا بعد ساعتين
+
+36
+00:02:54,690 --> 00:03:00,130
+ثلاثة بنلاحظ أنه كل الهيدروجين ابدلت بديوتيريوم
+
+37
+00:03:00,130 --> 00:03:04,870
+هذا بيسموه ايش الديوتيريوم exchange يعني ابدال
+
+38
+00:03:04,870 --> 00:03:08,250
+الهيدروجين بديوتيريوم الفكرة فيه ايش اللي خلى
+
+39
+00:03:08,250 --> 00:03:12,790
+الهيدروجين تنسحب أن ألفا هيدروجين في وجود ال base
+
+40
+00:03:12,790 --> 00:03:17,150
+انسحبت عملت ماينص اجت لديوتيريوم مكانها، انسحبت عملت
+
+41
+00:03:17,150 --> 00:03:21,390
+ماينص اجت لديوتيريوم مكانها، كمان مرة، كمان مرة، ففي 
+
+42
+00:03:21,390 --> 00:03:27,610
+النهاية بلاغظ أن كل الألفا هيدروجين عملوا متحولوا
+
+43
+00:03:27,610 --> 00:03:34,050
+إلى ديوتريريوم كذلك الحال لو أنا مثلا أخدت هذا 
+
+44
+00:03:34,050 --> 00:03:39,970
+المركب بيوتنال هي فيه كربونيل جروب وهي الألفا 
+
+45
+00:03:39,970 --> 00:03:45,390
+هيدروجينز هدول اللي ماخذين لون أزرق لو حطيتهم في
+
+46
+00:03:45,390 --> 00:03:52,300
+ال water لفترة طويلة في وجود ديوتريريوم كمان إضافة
+
+47
+00:03:52,300 --> 00:03:56,400
+بلاحظ أن كل الهيدروجين بتحولوا إلى ايش إلى
+
+48
+00:03:56,400 --> 00:04:00,120
+ديوتريريوم ليش هذا الكلام بتم لأن الهيدروجين هدول
+
+49
+00:04:00,120 --> 00:04:06,200
+قابلات للفقد بيفقدوا وبيجي مكانهم الديوتريريوم
+
+50
+00:04:06,200 --> 00:04:10,400
+بيفقدوا وبيجي مكانهم الديوتريريوم هذا بيسمي احنا 
+
+51
+00:04:10,400 --> 00:04:15,020
+alpha hydrogen exchange يعني تبديل ال alpha
+
+52
+00:04:15,020 --> 00:04:20,110
+hydrogen بال deuterium هذا أحد الأمثلة على
+
+53
+00:04:20,110 --> 00:04:25,810
+الاستفادة من ال acidity of alpha hydrogen المثال
+
+54
+00:04:25,810 --> 00:04:32,010
+الثاني .. المثال الثاني تفاعل شهير عادة التفاعلات 
+
+55
+00:04:32,010 --> 00:04:34,870
+الشهيرة بيسموها name reactions يعني من كثر ما هي 
+
+56
+00:04:34,870 --> 00:04:41,470
+مشهورة منسوبة لاسم محدد ممكن الاسم يكون اسم شخص وممكن
+
+57
+00:04:41,470 --> 00:04:45,470
+يكون شيء ثاني، واضح؟ هذا ال name reaction أو
+
+58
+00:04:45,470 --> 00:04:51,070
+التفاعل الشهير اسمه ال aldol condensation بتعرف ال
+
+59
+00:04:51,070 --> 00:04:55,070
+condensation تكثيف .. التكثيف أن اجمع جزيئين مع
+
+60
+00:04:55,070 --> 00:04:59,850
+بعض .. التكثيف أن اجمع جزيئين مع بعض طبعا بأجمعهم 
+
+61
+00:04:59,850 --> 00:05:05,030
+ممكن يفقد جزيء صغير في هذه الحالة ايش الفكرة في
+
+62
+00:05:05,030 --> 00:05:11,990
+aldol condensation الفكرة لو أنا أخدت الألدهيد أو 
+
+63
+00:05:11,990 --> 00:05:17,670
+كيتون وهذا الألدهيد أو الكيتون فعلته مع base مع 
+
+64
+00:05:17,670 --> 00:05:23,570
+قاعدة بنسبة 2 إلى 1 ممكن الألدهيد اللي ناخده يكون 
+
+65
+00:05:23,570 --> 00:05:28,730
+ال acetaldehyde أطلع عليه هذا acetaldehyde باخده 
+
+66
+00:05:28,730 --> 00:05:35,010
+بأي نسبة ال acetaldehyde بنسبة اثنين بفعله مع قاعدة
+
+67
+00:05:35,010 --> 00:05:39,830
+القاعدة بتكون بنسبة واحد فأنتوا انتبهوا معايا لما 
+
+68
+00:05:39,830 --> 00:05:46,910
+يكون عندي اثنين acetaldehyde اثنين من هذا المركب
+
+69
+00:05:46,910 --> 00:05:50,510
+ال HCWOCH3
+
+70
+00:05:50,510 --> 00:05:56,580
+ونفعلهم مع واحد من ال base ال base ايش بتاخد عندنا
+
+71
+00:05:56,580 --> 00:06:01,940
+دائما؟ ال alpha هيدروجين طيب لو افترضت مثلا عندي 
+
+72
+00:06:01,940 --> 00:06:05,460
+مئة جزء من الألدهيد بكون أنفعله مع كم جزء من ال
+
+73
+00:06:05,460 --> 00:06:10,220
+base؟ مع خمسين هذا الكلام بيقدر إلى نص كمية
+
+74
+00:06:10,220 --> 00:06:14,420
+الألدهيد بتصير عبارة عن أيون بتسحب منها
+
+75
+00:06:14,420 --> 00:06:20,770
+الهيدروجين والنص الثاني بيضل زي ما هو الآن لاحظوا
+
+76
+00:06:20,770 --> 00:06:25,230
+معي بزام صار نص أيونه هذا ما زال زي ما هو الأيون
+
+77
+00:06:25,230 --> 00:06:30,810
+عبارة عن ال nucleophile والتفاعل الأساسي لل
+
+78
+00:06:30,810 --> 00:06:34,490
+الألدهيدز والكيتونز ال nucleophilic addition فهذا 
+
+79
+00:06:34,490 --> 00:06:37,930
+الأيون اللي اتكون بيجي مضاف هنا و ال O بتصير
+
+80
+00:06:43,190 --> 00:06:48,450
+وال O- بتاخد مية في النهاية بيصير عندك OH
+
+81
+00:06:53,620 --> 00:06:56,820
+ال nucleophilic addition اللي احنا حكيناها أنه
+
+82
+00:06:56,820 --> 00:07:02,800
+هذا ال nucleophile اتفاعل هنا و ال O صارت OH هذا 
+
+83
+00:07:02,800 --> 00:07:07,960
+المركب نفسه لو رسمته كطريقة ثانية بتلاحظوا أنه
+
+84
+00:07:07,960 --> 00:07:12,800
+بيحتوي على مجموعتين وظيفيتين مجموعة ال aldehyde ومجموعة
+
+85
+00:07:12,800 --> 00:07:19,030
+ال alcohol واضح؟ بيحتوي على مجموعة ال
+
+86
+00:07:19,030 --> 00:07:23,250
+الديهايد ومجموعة الكحول وعشان هيك احنا بنسمي 
+
+87
+00:07:23,250 --> 00:07:29,170
+المركب aldol condensation الام هذه كلمة aldol جاية 
+
+88
+00:07:29,170 --> 00:07:38,130
+من أن الناتج فيه الديهايد وفي الكحول aldol واضح
+
+89
+00:07:38,130 --> 00:07:43,930
+هلأ aldol مش اسم بني ادم aldol نسبة لمكونات
+
+90
+00:07:43,930 --> 00:07:49,150
+المركب الناتج اللي هو بيحتوي على الألدهيد 
+
+91
+00:07:49,150 --> 00:07:53,010
+وبيحتوي على ال alcohol ال alcohol all وال
+
+92
+00:07:53,010 --> 00:07:57,710
+الديهايد بنعطي ال فبيصير aldol condensation طبعا
+
+93
+00:07:57,710 --> 00:08:01,670
+إذا احنا بدنا نتطلع على هذا المركب اللي هو ناتج
+
+94
+00:08:01,670 --> 00:08:09,490
+ال aldol بنلاحظ أن الناتج هو عبارة عن beta-hydroxy
+
+95
+00:08:09,490 --> 00:08:13,130
+aldehyde يعني لما أجي أقول هاي الألدهيد واحد
+
+96
+00:08:13,130 --> 00:08:16,490
+اثنين ثلاثة أربعة هاي موقع Alpha بالنسبة له وهاي
+
+97
+00:08:16,490 --> 00:08:22,410
+موقع Beta ايش بيكون الناتج لتفاعل aldol بيتا لا مش 
+
+98
+00:08:22,410 --> 00:08:31,770
+اثنين مش اثنين beta-hydroxy-aldehyde فلما بدنا نقول 
+
+99
+00:08:31,770 --> 00:08:35,930
+تفاعل aldol شو ناتج اللي بيعطينا بيتا هيدروكس 
+
+100
+00:08:35,930 --> 00:08:43,550
+الألدهيد؟ ليش مش اثنين؟ لأن اعطاء ألفا وبيتا 
+
+101
+00:08:43,550 --> 00:08:47,430
+بيبدأ بعد مجموعة الكربون يعني بنقول هي الكربون
+
+102
+00:08:47,430 --> 00:08:51,190
+بنقول اللي بعدها الأولى ألفا هاد بيتا واضح؟ 
+
+103
+00:08:51,190 --> 00:08:56,150
+بينما الترقيم بيبدأ من نفس مجموعة الكربون هذه واحدة
+
+104
+00:08:56,150 --> 00:08:59,890
+وهذه اثنين وهذه ثلاثة عشان ايه هذا المركب لو بدأ 
+
+105
+00:08:59,890 --> 00:09:07,370
+أسميه بال IUPAC هو عبارة عن 3-hydroxy طبعا
+
+106
+00:09:07,370 --> 00:09:14,410
+أربع كربونات بيوتنال لا برضه مش 1 من اللي حكت
+
+107
+00:09:14,410 --> 00:09:20,510
+1؟ من اللي حكت 1؟ ما بتعترفش ليش لأن احنا قلنا 
+
+108
+00:09:20,510 --> 00:09:23,250
+ال aldehyde دائما على الطرف بس ما تعملوش 1
+
+109
+00:09:39,160 --> 00:09:43,500
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+110
+00:09:43,500 --> 00:09:51,900
+الهيدروكسي الهيدروكسي الهيدروكسي 
+
+111
+00:09:51,900 --> 00:09:53,300
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي 
+
+112
+00:09:53,300 --> 00:09:59,130
+الهيدروكسي شرط تفاعل aldol اللي ما بيمشيش بدونه أن 
+
+113
+00:09:59,130 --> 00:10:04,790
+يكون عنده aldehyde أو كيتون فيه alpha هيدروجين كل 
+
+114
+00:10:04,790 --> 00:10:08,550
+الفكرة معتمدة على وجود alpha هيدروجين نسحب منها
+
+115
+00:10:09,250 --> 00:10:13,610
+البروتون بمعنى مش كل ال aldehydes اللي في الدنيا
+
+116
+00:10:13,610 --> 00:10:18,530
+ولا كل ال ketones اللي في الدنيا ممكن تعمل aldol
+
+117
+00:10:18,530 --> 00:10:23,290
+reaction ممكن أعطيكوا أمثلة مثلا لو أخذنا ال
+
+118
+00:10:23,290 --> 00:10:28,090
+formaldehyde C double bond O H H هذا فيه alpha 
+
+119
+00:10:28,090 --> 00:10:28,730
+hydrogen
+
+120
+00:10:31,330 --> 00:10:34,790
+لاحظوا ال alpha هيدروجين هي الهيدروجين على الكربون
+
+121
+00:10:34,790 --> 00:10:38,030
+المجاورة لل C double bond O هاي ال C double bond
+
+122
+00:10:38,030 --> 00:10:41,830
+O كربون مجاورة عليها alpha هيدروجين بس هاد 
+
+123
+00:10:41,830 --> 00:10:45,530
+الهيدروجين على نفس الكربون لا مش alpha هيدروجين
+
+124
+00:10:45,530 --> 00:10:51,710
+عشان كده لو بتفعلوا مع base ما بيمشيش يعني لو بدي أجي 
+
+125
+00:10:51,710 --> 00:10:56,070
+أسألكوا في الامتحان أنه formaldehydes undergo
+
+126
+00:10:56,070 --> 00:10:59,890
+aldol condensation in the presence of a base
+
+127
+00:10:59,890 --> 00:11:05,050
+الجواب لا لأنه ما فيش بال formaldehyde alpha 
+
+128
+00:11:05,050 --> 00:11:09,010
+hydrogen طيب لو أخذنا ال benzaldehyde متذكرين ولا 
+
+129
+00:11:09,010 --> 00:11:13,670
+لا هل
+
+130
+00:11:13,670 --> 00:11:21,920
+هذا في alpha hydrogen طلع عليه هذا الكربون لا يحمل
+
+131
+00:11:21,920 --> 00:11:25,340
+أي نوع من الهيدروجين هنا في عندكم ما تنسوش عندما نفصل
+
+132
+00:11:25,340 --> 00:11:30,600
+البنزين نضع الروابط ليس هنا أي نوع من الهيدروجين
+
+133
+00:11:30,600 --> 00:11:32,860
+هنا رابطتين أو ثلاثة أو أربعة ليس هنا أي نوع من 
+
+134
+00:11:32,860 --> 00:11:35,560
+ال alpha هيدروجين ولا هناك أي نوع من ال alpha هيدروجين
+
+135
+00:11:40,680 --> 00:11:44,320
+و ال benzaldehyde ما بيصيرش عليهم aldol reaction
+
+136
+00:11:44,320 --> 00:11:48,860
+لأنه ما فيش alpha hydrogen نحذفها في وجود ال base
+
+137
+00:11:48,860 --> 00:11:54,760
+شرط aldol reaction أنه يكون عنده aldehyde أو 
+
+138
+00:11:54,760 --> 00:11:58,260
+كيتون ويكون ال aldehyde أو الكيتون بيحتوي على
+
+139
+00:11:58,260 --> 00:12:05,660
+alpha hydrogen واضح؟
+
+140
+00:12:05,660 --> 00:12:08,160
+تالتاني على ال aldol reaction
+
+141
+00:12:11,450 --> 00:12:17,390
+لو أخذنا هذا ال aldehyde الكبير هذا ال aldehyde
+
+142
+00:12:17,390 --> 00:12:22,390
+شايفينه؟ واحد اثنين ثلاثة بيوتنال two مثل 
+
+143
+00:12:22,390 --> 00:12:26,310
+بيوتنال أنا اللي بيهمني منه كله أنه يكون بيحتوي
+
+144
+00:12:26,310 --> 00:12:30,310
+على ايش؟ alpha Hydrogen هاي الكربون الأساسي هاي
+
+145
+00:12:30,310 --> 00:12:34,090
+الكربون اللي جنبها الكربون اللي جنبها حاملة
+
+146
+00:12:34,090 --> 00:12:39,150
+Hydrogen في عليها alpha Hydrogen إذا في وجود base
+
+147
+00:12:39,150 --> 00:12:44,730
+.. إذا في وجود base زي مثلا ال sodium hydroxide
+
+148
+00:12:44,730 --> 00:12:50,750
+ممكن إنه يعمل condensation مع نفسه يعطينا الناتج
+
+149
+00:12:50,750 --> 00:12:56,110
+اللي موجود هناك طبعا هنا بصراحة إنه كيف نكتب
+
+150
+00:12:56,110 --> 00:13:02,050
+الناتج إذا أنتو ما تدربتوش في البيت بالقلم الرصاص
+
+151
+00:13:02,050 --> 00:13:06,730
+كيف تعملوا هذا التفاعل مش هيكون سهل عليكم تكتبوا
+
+152
+00:13:06,730 --> 00:13:10,900
+الناتج طيب، الآن ايش أسهل؟ أسهل طريقة إنه أي 
+
+153
+00:13:10,900 --> 00:13:15,740
+aldehyde أو ketone موجود عندي أرسمه مرتين جانب بعض 
+
+154
+00:13:15,740 --> 00:13:22,540
+مش هيووم أرسمها هو عادة موجود بنسبة ايش؟ 2 إلى 1
+
+155
+00:13:22,540 --> 00:13:26,300
+إذا أنا بدي أعيد الرسمة تبعته بدي أعيد الرسمة
+
+156
+00:13:26,300 --> 00:13:30,060
+تبعته زي ما هي بالظبط بدي أحط C double bond OH
+
+157
+00:13:30,060 --> 00:13:32,980
+وهنا CH
+
+158
+00:13:34,940 --> 00:13:42,080
+CH3 CH3 هاي صار عندي جزيئين الآن هدول الجزيئين
+
+159
+00:13:42,080 --> 00:13:49,020
+واحد منهم بيفقد البروتون وبيعمل أيون سالب هاي هدا
+
+160
+00:13:49,020 --> 00:13:57,700
+فقد البروتون وعمل أيون سالب والثاني بيضل زي ما هو
+
+161
+00:13:57,700 --> 00:14:02,240
+الآن بعد هيك شو اللي بده يصير الأيون السالب بده
+
+162
+00:14:02,240 --> 00:14:08,850
+يخجمعلي ال C double bond O تبع المركب الثاني
+
+163
+00:14:08,850 --> 00:14:15,290
+هيهاجمها واحد بدأ تصير O minus وتصير في نهاية OH
+
+164
+00:14:15,290 --> 00:14:20,730
+عشان ذلك لما تيجوا تتطلعوا هنا بتلاحظوا أنه عملية
+
+165
+00:14:20,730 --> 00:14:25,290
+الاتصال تمت من أي كربون اللي كانت حاملة alpha
+
+166
+00:14:25,290 --> 00:14:28,910
+Hydrogen يعني لو حطينا هدول اللي لونهم أحمر في
+
+167
+00:14:28,910 --> 00:14:31,930
+صندوق هما عبارة عن
+
+168
+00:14:35,410 --> 00:14:42,630
+هذا الجزء واضح هيأنا اتكون الأيون السالب شايفينه
+
+169
+00:14:42,630 --> 00:14:51,590
+هاجم وأعطاني ال OH هيأنا
+
+170
+00:14:51,590 --> 00:14:58,870
+اتكون الأيون السالب وهاجم وأعطاني ال OH طبعا
+
+171
+00:15:00,970 --> 00:15:05,250
+نفس الشيء .. نفس الشيء لو كنا بدنا نعمل تفاعل
+
+172
+00:15:05,250 --> 00:15:12,170
+للأسيتون مع نفسه في وجود base هاي أسيتون سيبنا من 
+
+173
+00:15:12,170 --> 00:15:15,550
+هذه الأشياء اللي بتتكون بشكل بسيط خلينا بالأسيتون 
+
+174
+00:15:15,550 --> 00:15:20,030
+الآن لو قلنا لأي واحدة فيكوا اعملوا لنا الأسيتون شو
+
+175
+00:15:20,030 --> 00:15:25,270
+الخطوة اللي لازم تعملها أول شيء بدك ترسمه
+
+201
+00:18:02,960 --> 00:18:12,340
+معين يعمل الـ ion ويهاجم على aldehyde تاني واضح؟ لأ
+
+202
+00:18:12,340 --> 00:18:16,640
+احنا ما كناش نعمل زيك، احنا كنا .. انتبهوا معايا،
+
+203
+00:18:16,640 --> 00:18:21,280
+بده .. بده هدوء في فهم النقطة، احنا كنا بنحط الـ
+
+204
+00:18:21,280 --> 00:18:27,300
+الديهايد بنسبة 2 والـ base بنسبة 1، الآن نص كمية
+
+205
+00:18:27,300 --> 00:18:32,860
+الـ الديهايد بتصير ايون وبتهاجم على النص الثاني
+
+206
+00:18:32,860 --> 00:18:37,520
+اللي ما صار ايون الآن أنا ممكن أعمل بطريقة ثانية
+
+207
+00:18:37,520 --> 00:18:42,000
+أن أخلط two aldehydes يعني كل الأمثلة السابقة اللي
+
+208
+00:18:42,000 --> 00:18:46,200
+شفتوها كان aldehyde مع نفسه يعني لو كان عندكوا ثلاث
+
+209
+00:18:46,200 --> 00:18:50,300
+كربونات في الـ aldehyde فالنتيجة النهائية كده يكون
+
+210
+00:18:50,300 --> 00:18:58,190
+عندكم؟ ستة، اثنين يتحدوا مع بعض، خلينا نرجع نعلمكم
+
+211
+00:18:58,190 --> 00:19:02,450
+العدل من أول وجديد، هنا كم carbon عندكم؟ اثنتين ..
+
+212
+00:19:02,450 --> 00:19:06,290
+ولما يتفاعل مع نفسه .. ف .. okay الناتج النهائي
+
+213
+00:19:06,290 --> 00:19:10,750
+.. كم carbon يطلع فيه؟ أربعة .. واضح؟ هنا كم
+
+214
+00:19:10,750 --> 00:19:14,290
+carbon عندكم؟ واحد .. اثنين .. ثلاثة .. أربعة .. و
+
+215
+00:19:14,290 --> 00:19:17,110
+لما يتفاعل مع نفسه .. الناتج النهائي .. كم يطلع
+
+216
+00:19:17,110 --> 00:19:19,570
+فيه؟ واحد .. اثنين .. ثلاثة .. أربعة .. خمسة ..
+
+217
+00:19:19,570 --> 00:19:22,790
+ستة .. سبعة .. تمام .. إذًا هو كرر نفسه بشكل أو
+
+218
+00:19:22,790 --> 00:19:28,800
+بآخر واضح؟ بينما الـ mixed aldol أنا بأخذ الديهايد
+
+219
+00:19:28,800 --> 00:19:34,780
+ما يتفاعلش مع نفسه، يتفاعل مع ديهايد ثاني، واضح؟ فمثلًا
+
+220
+00:19:34,780 --> 00:19:41,280
+لو أخدت الـ benz aldehyde والـ acetaldehyde وعملتم
+
+221
+00:19:41,280 --> 00:19:46,790
+مع base الـ benz aldehyde بنسبة 1، الـ Acetal
+
+222
+00:19:46,790 --> 00:19:51,030
+Dehydrate بنسبة 1، الـ Base بنسبة 1، الآن
+
+223
+00:19:51,030 --> 00:19:54,670
+لاحظوا معايا، الـ Base، الديهايد ما فيه Alpha Hydrogen
+
+224
+00:19:54,670 --> 00:20:00,790
+مش هيعمل ايون، الـ Acetal Dehydrate فيه Alpha
+
+225
+00:20:00,790 --> 00:20:05,050
+Hydrogen، فلما يكون بنسبة 1 لـ 1 هيعمل ايون، وين
+
+226
+00:20:05,050 --> 00:20:11,290
+الايون السالب هيصير؟ على الـ Alpha Carbon، الآن هذا
+
+227
+00:20:11,290 --> 00:20:12,350
+الايون السالب
+
+228
+00:20:21,550 --> 00:20:31,690
+واضح؟ فهي ناتج الألدول، هي ناتج الألدول، هي
+
+229
+00:20:31,690 --> 00:20:36,930
+الجزء، الجزء الأحمر الديهايد والجزء الأسود
+
+230
+00:20:37,950 --> 00:20:42,530
+الديهايد الثاني، أنا خلطت two different aldehydes
+
+231
+00:20:42,530 --> 00:20:48,090
+أنا خلطت two different aldehydes، بالمناسبة هذا في 
+
+232
+00:20:48,090 --> 00:20:52,750
+شوية تسخين بسيط، بفقد OH من هنا وOH من هنا، بيعطينا
+
+233
+00:20:52,750 --> 00:20:57,690
+double bond، بيعطينا الـ aldehyde اللي شو اسمه؟
+
+234
+00:20:57,690 --> 00:21:01,150
+cinnamaldehyde، هذا الـ aldehyde مشهور
+
+235
+00:21:01,150 --> 00:21:04,390
+cinnamaldehyde، cinnamaldehyde من ايه جاي؟
+
+236
+00:21:07,010 --> 00:21:11,310
+اتذكروا معايا cinema
+
+237
+00:21:11,310 --> 00:21:17,710
+aldehyde، هو aldehyde .. الـ cinnamon .. cinnamon ..
+
+238
+00:21:17,710 --> 00:21:24,950
+مرت عليكم كلمة cinnamon؟ ايش هي؟ الجرفة .. الجرفة
+
+239
+00:21:24,950 --> 00:21:30,420
+.. هذا aldehyde الجرفة، يعني ممكن أن حضره في المختبر
+
+240
+00:21:30,420 --> 00:21:37,120
+ويطلق نفس الريحة اللي
+
+241
+00:21:37,120 --> 00:21:43,300
+بيمنع أن
+
+242
+00:21:43,300 --> 00:21:47,820
+أنا حاطط هذا بنسبة 1 إلى 1، فحولت كل هذا ..
+
+243
+00:21:47,820 --> 00:21:53,390
+حولت كل هذا إلى ايون سالب، يعني التفاعل مع الـ base
+
+244
+00:21:53,390 --> 00:21:57,550
+أقوى الآن، السؤال اللي بتسألوا زميلتكم .. السؤال
+
+245
+00:21:57,550 --> 00:22:02,670
+اللي بتسألوا زميلتكم ايه وجهها لو أنا حطيت .. لو
+
+246
+00:22:02,670 --> 00:22:07,350
+أنا حطيت two aldehydes .. لو حطيت two aldehydes
+
+247
+00:22:07,350 --> 00:22:12,730
+والاثنين فيهم alpha hydrogen، ورحت أنفعلهم مع base
+
+248
+00:22:12,730 --> 00:22:18,590
+يعني مثلًا حطيت هذا الـ acetaldehyde اللي عندك CH3
+
+249
+00:22:23,710 --> 00:22:33,290
+CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH3
+
+250
+00:22:33,290 --> 00:22:41,790
+CH3 CH2 CH3 CH3
+
+251
+00:22:41,790 --> 00:22:43,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+252
+00:22:43,170 --> 00:22:44,550
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+253
+00:22:44,550 --> 00:22:44,730
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+254
+00:22:44,730 --> 00:22:45,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+255
+00:22:45,130 --> 00:22:45,350
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+256
+00:22:45,350 --> 00:22:46,310
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+257
+00:22:46,310 --> 00:22:46,510
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+258
+00:22:46,510 --> 00:22:46,590
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+259
+00:22:48,660 --> 00:22:55,080
+الأمور هنا كتير بتتعقد، تمامًا إذا بتذكروا لما
+
+260
+00:22:55,080 --> 00:22:59,400
+كنا نخلط .. لما كنا نخلط two alcohols مع بعض عشان
+
+261
+00:22:59,400 --> 00:23:03,900
+نحضر unsymmetrical ether كم ناتج كان يطلع عنده؟
+
+262
+00:23:03,900 --> 00:23:09,940
+ثلاثة، هنا لو عملنا زي هيك في عندنا إمكانية أنه هنا
+
+263
+00:23:09,940 --> 00:23:17,690
+يتكون عندك ايون سالب، يعني هذا تصير CH2-، و تهاجم على
+
+264
+00:23:17,690 --> 00:23:21,490
+الجزء اللي منه ما اتفعلش، وفي إمكانية أنه كمان
+
+265
+00:23:21,490 --> 00:23:27,470
+يتكون عند ايون سالب، يعني هذا تصير CH-، و تهاجم على
+
+266
+00:23:27,470 --> 00:23:31,310
+نفسها، وفي إمكانية هذه تهاجم على هذه وهذه تهاجم على
+
+267
+00:23:31,310 --> 00:23:35,570
+هذه، إذًا كم ناتج هان بدو يطلع عندكم؟ أربعة .. طبعًا
+
+268
+00:23:35,570 --> 00:23:40,390
+جزء أساسي .. انتبهوا معي .. جزء أساسي من فهم مثل هذا
+
+269
+00:23:40,390 --> 00:23:44,610
+المثال أنه انتوا تكونوا منتبهين أنه احنا ما بنفعلش
+
+270
+00:23:44,610 --> 00:23:49,950
+الجزيئات بنسبة 1 إلى 1، بمعنى ما بنفعلش جزء من
+
+271
+00:23:49,950 --> 00:23:54,830
+هذا وجزء من هذا وجزء من هذا، لو أحد فيكو جاع بتخيل
+
+272
+00:23:54,830 --> 00:23:58,930
+أنه أنا بس أفعل جزء واحد من هذا وجزء من هذا وجزء
+
+273
+00:23:58,930 --> 00:24:02,390
+من هذا، كان هيقول الـ base أكيد يا بده تاخد بروتون
+
+274
+00:24:02,390 --> 00:24:06,630
+من هان يا من هان، وبتفعل على التاني، بس أنا حقيقة
+
+275
+00:24:06,630 --> 00:24:11,710
+لما بأفعل بالوضع الطبيعي بأفعل واحد mole، لو بتقول
+
+276
+00:24:11,710 --> 00:24:15,590
+مثلًا واحد mole أو نص mole بلاش خليني أقول مليون
+
+277
+00:24:15,590 --> 00:24:21,110
+جزء، اتخيلوا أنا بدي أفعل مليون جزء من هذا مع مليون
+
+278
+00:24:21,110 --> 00:24:28,290
+من اللي هان مع مليون من الـ base، خلّي الـ base مثلًا
+
+279
+00:24:28,290 --> 00:24:33,350
+تاخد نص مليون من هدول، تخليهم ايش؟ ايون سالب،
+
+280
+00:24:33,350 --> 00:24:37,210
+بمعنى ذلك، ضل عندكم نص مليون مش محولين لأيون
+
+281
+00:24:37,210 --> 00:24:42,470
+وخلّي الـ base كمان تتحول من هدول نصهم، نص مليون
+
+282
+00:24:42,470 --> 00:24:46,990
+صاروا ايون ونص؟ لأ، إذًا مخلوط التفاعل في هذه
+
+283
+00:24:46,990 --> 00:24:51,140
+الحالة، شو هيصفى فيه بالنهاية؟ نص مليون من الـ
+
+284
+00:24:51,140 --> 00:24:56,860
+ديهايد هذا ونص مليون من الايون ونص مليون من
+
+285
+00:24:56,860 --> 00:24:59,660
+الـ ديهايد هذا ونص مليون من الايون، وخلّيهم
+
+286
+00:24:59,660 --> 00:25:04,180
+يتفاعلوا مع بعض كم ناتج بيطلع عندكم؟ أربعة نواتج
+
+287
+00:25:04,180 --> 00:25:10,140
+هذا مع نفسه، هذا مع نفسه، هذا مع الـ ديهايد اللي
+
+288
+00:25:10,140 --> 00:25:15,000
+هان، هذا مع الـ ديهايد اللي هان، أربعة نواتج، على أي
+
+289
+00:25:15,000 --> 00:25:19,860
+حال عشان ما نضيعش وقت ونشجعكم إنه تفكروا فيهم
+
+290
+00:25:19,860 --> 00:25:27,080
+بشكل ممتاز، اعملوهم homework، الأربعة نواتج المتوقعة
+
+291
+00:25:27,080 --> 00:25:31,140
+من هنا، homework مرتب وسلموني إياه المحاضرة الجاية، هذا
+
+292
+00:25:31,140 --> 00:25:38,420
+آخر homework عليه ايش درجات؟ أربعة نواتج بدو يطلع
+
+293
+00:25:38,420 --> 00:25:43,500
+عندكم، وارسموهم صح، لازم عشان تعملوا هذا الكلام
+
+294
+00:25:43,500 --> 00:25:46,780
+تراجعوا الموضوع كله من الأول، اتعودوا إيدكم ترسموا
+
+295
+00:25:46,780 --> 00:25:50,700
+الأمثلة كلها اللي أخذناها لحد ما تصلوا هنا في
+
+296
+00:25:50,700 --> 00:25:56,300
+النهاية، بيطلع عندكم مثل هذا المثال، أربعة نواتج، طبعًا
+
+297
+00:25:56,300 --> 00:25:59,640
+هنا احنا ارتحنا، ما طلع إلا ناتج واحد لإن واحد
+
+298
+00:25:59,640 --> 00:26:04,080
+منهم فيه Alpha Hydrogen، الثاني ما فيش فيه Alpha Hydrogen
+
+299
+00:26:04,080 --> 00:26:05,860
+واضح؟
+
+300
+00:26:07,550 --> 00:26:13,030
+طيب، الآن اتفقتوا معي كلكم أن المفروض يطلع أربعة
+
+301
+00:26:13,030 --> 00:26:21,190
+نواتج هان؟ ولا لأ؟ هتعملوهم في البيت؟ طيب، آخر سؤال
+
+302
+00:26:21,190 --> 00:26:26,490
+.. آخر سؤال ممكن نسأله؟ آخر سؤال ممكن نسأله؟
+
+303
+00:26:26,490 --> 00:26:32,610
+مستعدين أن نسأله؟ آه، لأ، بدكم تنتبهوا لإن اللي
+
+304
+00:26:32,610 --> 00:26:36,030
+بده يجاوبه هأعطيه علامات، على طول هينزلوا على ..
+
+305
+00:26:37,180 --> 00:26:42,400
+هينزلوا على الرصيد تبعه، لو بدي واحد محدد من
+
+306
+00:26:42,400 --> 00:26:47,280
+الأربعة يطلع، أنا قاعد بقولكم، إذا خلطتمهم مع الـ
+
+307
+00:26:47,280 --> 00:26:51,860
+base بنسبة 1 إلى 1 إلى 1، هيطلع عندي كم
+
+308
+00:26:51,860 --> 00:26:55,660
+ناتج؟ أربعة نواتج، وهتكتبوهم في الـ homework وتسلمون
+
+309
+00:26:55,660 --> 00:27:03,960
+اياهم، الآن لو بدي ناتج محدد ممكن .. ممكن أرسملكوا
+
+310
+00:27:03,960 --> 00:27:09,340
+هذا الناتج المحدد اللي أنا بدي إياه، بمشي مثلًا لو
+
+311
+00:27:09,340 --> 00:27:18,480
+قلنا بدنا هذا الناتج، هذه
+
+312
+00:27:18,480 --> 00:27:25,700
+CH2 وهنا
+
+313
+00:27:25,700 --> 00:27:27,780
+حطينا C
+
+314
+00:27:37,380 --> 00:27:42,620
+CH3، بدي بس هذا الناتج حصريًا يطلع عندي، exclusive
+
+315
+00:27:42,620 --> 00:27:48,180
+بتعرف ايش أنا؟ حصري بس هذا الناتج، ما يطلعوش أربعة،
+
+316
+00:27:48,180 --> 00:27:52,280
+هذا أحد الأربعة بالمناسبة اللي كان هيطلعوا، الآن
+
+317
+00:27:52,280 --> 00:27:58,140
+أنا بدي التفاعل بس يطلع لي هذا ولا شيء أغيره، تفضلي
+
+318
+00:27:58,140 --> 00:28:03,860
+هاي لا لا، أبعد ولا خاصة green yard فيها المنطقة
+
+319
+00:28:08,810 --> 00:28:14,530
+مش هتظبط معك، هيطلع خليط من الأربعة، هيطلع خليط
+
+320
+00:28:14,530 --> 00:28:19,710
+من الأربعة برضه، طالما
+
+321
+00:28:19,710 --> 00:28:25,790
+مع بعض هيطلع خليط من الأربعة، أنا بدي واحد مية في
+
+322
+00:28:25,790 --> 00:28:30,990
+المية، بس يطلع عندي واحد فقط، لغير، only one
+
+323
+00:28:30,990 --> 00:28:32,550
+product مش four products
+
+324
+00:28:37,450 --> 00:28:41,970
+ما خصش الـ resonance هنا، خليني أشوف غيرك، تفضلي
+
+325
+00:28:41,970 --> 00:28:46,250
+الربع
+
+326
+00:28:46,250 --> 00:28:51,890
+بس، هتأخذ .. الربع بينك سيمتوم لين؟ طمون هيجي يعمل
+
+327
+00:28:51,890 --> 00:28:57,230
+هنا وطمون هنا وبرضه هيطلع عندك خليط وهتطلع لي
+
+328
+00:28:57,230 --> 00:29:02,790
+كمان ثمان مركبات لإن هتفضل أشياء مش متفاعلة، لأ لأ
+
+329
+00:29:02,790 --> 00:29:11,830
+البس بس حرام عليكم، مين كانت هناك بدأت تجاوب؟ لأ لأ
+
+330
+00:29:11,830 --> 00:29:14,870
+احنا .. أنا في الـ rearrangement، بعدي بعدي كتير عن
+
+331
+00:29:14,870 --> 00:29:18,610
+الـ rearrangement، لأ لأ، بنضيف الشغلة، والله فكرة
+
+332
+00:29:18,610 --> 00:29:22,950
+بسيطة، لأ، انتوا لاحظوا بس أنا ليش بسألكوا هذا
+
+333
+00:29:22,950 --> 00:29:29,010
+الكلام حتى تشوفوا أنه مرات ما بين .. ما بين الشغلة
+
+334
+00:29:29,010 --> 00:29:35,770
+الصعبة كتير والشغلة السهلة أو ما بين المشكلة و
+
+335
+00:29:35,770 --> 00:29:44,910
+حلها، فكرة بسيطة جدًا جدًا، ما بين المشكلة وحلها، فكرة
+
+336
+00:29:44,910 --> 00:29:50,370
+بسيطة جدًا جدًا، يعني مش الاشي المعقد ولا الاشي اللي
+
+337
+00:29:50,370 --> 00:29:54,470
+بيغلب، المشكلة بتنحل بسهولة كتير، إن بدل ما يطلع
+
+338
+00:29:54,470 --> 00:30:01,610
+عندي أربعة نواتج يطلع ايش؟ ناتج واحد، في حد بده يجاوب
+
+339
+00:30:01,610 --> 00:30:10,650
+ولا خلاص انطحنا في السؤال، آخر جاوب، تفضل ممتاز
+
+340
+00:30:10,650 --> 00:30:16,390
+هذا الكلام الصح اللي حكته زميلتكم، هتأخذ .. شو اسمك؟
+
+341
+00:30:16,390 --> 00:30:20,950
+سمية .. سمية خفاجة .. آه .. سمية حكت كلام بسيط
+
+342
+00:30:20,950 --> 00:30:24,090
+احنا كانت المشكلة عندنا .. نكون .. نكون ماخذين
+
+343
+00:30:24,090 --> 00:30:27,770
+هدول الألدهيدات .. تتخيلوا أنه في عندنا flask .. هي
+
+344
+00:30:27,770 --> 00:30:32,330
+flask .. حاطينهم كلهم .. حاطينهم كلهم مع بعض، و
+
+345
+00:30:32,330 --> 00:30:37,970
+حاطين الـ base معهم .. فالـ base بتتطلعب، تلاقي من هذا
+
+346
+00:30:37,970 --> 00:30:42,990
+بتعمل منه ion، تلاقي من هذا بتعمل منه ion، الكلام
+
+347
+00:30:42,990 --> 00:30:47,770
+اللي هي حكته أنه احنا بعيدًا الله لجزازات كتير في
+
+348
+00:30:47,770 --> 00:30:54,110
+المختبر، ما بدناش نستعمل flask واحد، بنستعمل two flasks
+
+349
+00:30:54,110 --> 00:30:59,110
+خلينا نقول هي الـ flask الأسود، وبنحط فيه هذا
+
+350
+00:30:59,110 --> 00:31:01,870
+المركب CH3
+
+351
+00:31:03,390 --> 00:31:09,970
+CH2C double bond O H، كويس، وبنستعمل الـ flask الثاني
+
+352
+00:31:09,970 --> 00:31:15,610
+خلينا نقول عنه الـ flask الأحمر، وبنحط فيه المركب
+
+353
+00:31:15,610 --> 00:31:22,410
+هذا CH3C double bond O H، لو افترضت مثلًا عندي مليون
+
+354
+00:31:22,410 --> 00:31:29,670
+جزء من هذا ومليون من هذا، باجي بحط الـ base بس على
+
+355
+00:31:29,670 --> 00:31:34,200
+هذا، هنا بحط الـ base، هذا بسيبه زي ما هو، ما بحطش عليه
+
+356
+00:31:34,200 --> 00:31:38,920
+base، الآن لما حطينا الـ base بنسبة 1 إلى 1 كل
+
+357
+00:31:38,920 --> 00:31:45,000
+هذا صار عبارة عن ايش؟ ايون سالب، المليون جزء اللي
+
+358
+00:31:45,000 --> 00:31:49,800
+هنا كلهم صاروا ايونات سالبة، وهذا كله ما جاش عليه
+
+359
+00:31:49,800 --> 00:31:55,780
+base، خليه زي ما هو، بعدين بننزّل هذا الـ flask، بنكبه
+
+360
+00:31:55,780 --> 00:32:01,700
+فوق هذا، بنكب الايون، كل هذا ايون وكل هذا الديهايد
+
+361
+00:32:01,700 --> 00:32:04,720
+لما نمسك هذا الـ flask ونكبه فوق هذا، شو التفاعل
+
+362
+00:32:04,720 --> 00:32:12,360
+بدي يصير؟ هيعطينا الناتج المحدد اللي أنا رسمته، و
+
+363
+00:32:12,360 --> 00:32:18,280
+لو كنت بدي، الناتج التاني، بضيف الـ base هان، شوفتوا
+
+364
+00:32:18,280 --> 00:32:23,930
+قد ايه الفكرة؟ يعني كل الفرق تبعها، flask إن أنا ضفت
+
+365
+00:32:23,930 --> 00:32:30,130
+على واحد حولته بشكل كامل للـ ايون بدون ما أعطي هذا
+
+366
+00:32:30
+
+401
+00:35:30,790 --> 00:35:36,810
+الربع ساعة بتنجزوا فيها فكرة و بتنجزوا فيها عمل لا
+
+402
+00:35:36,810 --> 00:35:43,310
+تستهيلوا بالوقت الـ chapter عشر لإكمال لفصل التاسع لكن
+
+403
+00:35:43,310 --> 00:35:47,830
+بيحكي عن ايش اللي هي الـ carboxylic acids and their
+
+404
+00:35:47,830 --> 00:35:52,210
+derivatives بتذكروا احنا حكينا أن السيطرة بالـ bond
+
+405
+00:35:52,210 --> 00:35:58,380
+O عبارة عن النوعين، اللي هي الـ Carbonyl group الـ
+
+406
+00:35:58,380 --> 00:36:06,400
+Aldehydes و الـ Ketones أخذناهم كمجموعة واحدة و
+
+407
+00:36:06,400 --> 00:36:11,160
+اللي بيميزهم كلمة واحدة شو الكلمة اللي بتميز الـ
+
+408
+00:36:11,160 --> 00:36:15,020
+Aldehydes و الـ Ketones؟ أكثر كلمة حكيناها إذا 
+
+409
+00:36:15,020 --> 00:36:21,840
+بترجعوا للمحاضرات المصورة إن تفاعلهم الأساسي تفاعل
+
+410
+00:36:21,840 --> 00:36:23,480
+addition
+
+411
+00:36:25,770 --> 00:36:31,150
+كله بيضيف و الـ O بتصير OH الآن في الـ chapter عشرة
+
+412
+00:36:31,150 --> 00:36:34,270
+بنا نأخذ اللي هم الـ C double bond O الثانية
+
+413
+00:36:34,270 --> 00:36:37,670
+الكربوني الـ compounds الثانية اللي هي الأحماض و
+
+414
+00:36:37,670 --> 00:36:44,310
+مشتقاتها وهتلاحظوا أن هدول كلهم هنستعمل برضه 
+
+415
+00:36:44,310 --> 00:36:47,150
+فيهم كلمة واحدة لكن في هذه الحالة الكلمة
+
+416
+00:36:47,150 --> 00:36:48,070
+substitution
+
+417
+00:36:52,290 --> 00:36:56,830
+هذه مبادئ أساسية في الـ Organic Chemistry يعني
+
+418
+00:36:56,830 --> 00:37:00,910
+إنتوا لو بدكم تدخلوا عندي مقابل التوظيف بدكم
+
+419
+00:37:00,910 --> 00:37:05,170
+تشتغلوا أنا ما بجيش أجيب لكم ورقة أو أقول عبّولي
+
+420
+00:37:05,170 --> 00:37:10,970
+أربع خمس صفحات لأ، المفروض إنه عندي خمسين طالبة كل
+
+421
+00:37:10,970 --> 00:37:14,170
+طالبة تبدأ تيجي لمدة دقيقتين وأعرف مين فيهم اللي
+
+422
+00:37:14,170 --> 00:37:18,270
+بتفهم كيميا ومين اللي ما بتعرفش كيميا باجي بسألكم
+
+423
+00:37:18,270 --> 00:37:21,850
+أسئلة عامة ايش التفاعل الأساسي للالكينز؟
+
+424
+00:37:25,330 --> 00:37:29,250
+free radical substitution وإن كانوا بشكل عام inert
+
+425
+00:37:29,250 --> 00:37:35,210
+ايش التفاعل الأساسي للالكينز مثلاً؟ أي addition؟
+
+426
+00:37:35,210 --> 00:37:38,210
+Electrophilic لازم اللي بتضيف يكون موجبة، ايش
+
+427
+00:37:38,210 --> 00:37:43,220
+التفاعل الأساسي للالكالهالايدز؟ substitution when
+
+428
+00:37:43,220 --> 00:37:46,840
+nucleophilic؟ ايش التفاعل الأساسي للألديهيدس
+
+429
+00:37:46,840 --> 00:37:50,580
+والكيتونز؟ addition when nucleophile؟ لأنه هذه
+
+430
+00:37:50,580 --> 00:37:56,480
+موجبة، الآن ايش التفاعل الأساسي للأحماض ومشتقاتها؟
+
+431
+00:37:56,480 --> 00:38:00,160
+الـ nucleophilic substitution، هتلاحظوا أنه في كل
+
+432
+00:38:00,160 --> 00:38:03,600
+المحاضرتين، التلاتة الجايات، بس هنتكلم substitution,
+
+433
+00:38:03,740 --> 00:38:05,680
+substitution, substitution، واضح؟
+
+434
+00:38:19,180 --> 00:38:26,400
+الآن كيف بنسمي الأحماض؟ الحامض من ناحية المبدأ هو
+
+435
+00:38:26,400 --> 00:38:32,100
+مثل الـ alkane هو مثل الـ alkane وهذا الـ alkane في طرفه
+
+436
+00:38:32,940 --> 00:38:38,220
+COOH طالما أنه المجموعة الحامضية بتيجي على الطرف إذا
+
+437
+00:38:38,220 --> 00:38:43,760
+بلزمش نعطيها رقم طب لما بنسمي بنشوف ايش الالكان 
+
+438
+00:38:43,760 --> 00:38:49,380
+مثلاً هكسين صار في طرفه acid بنضيف في النهاية oic
+
+439
+00:38:49,380 --> 00:38:52,740
+acid فمن الهكسين شو الحامض اللي بيطلع عندي؟
+
+440
+00:38:52,740 --> 00:39:00,040
+hexanoic acid من البروبين بروبانويك acid من
+
+441
+00:39:00,040 --> 00:39:00,740
+البيوتين
+
+442
+00:39:06,270 --> 00:39:14,110
+مثانوك أسيد من الإيثان ethanoic acid إذا تسمى الأحماض
+
+443
+00:39:14,110 --> 00:39:19,650
+بإضافة النهاية oic acid بنشيل الـ E اللي في آخر 
+
+444
+00:39:19,650 --> 00:39:24,290
+الالكان oic acid فلو مثلاً بدي أشوف هذا المركب طبعاً 
+
+445
+00:39:24,290 --> 00:39:27,690
+ببدأ أعد من الـ carbon تبعت الحامض يعني هاي عندي
+
+446
+00:39:27,690 --> 00:39:33,170
+واحد اثنين ثلاثة أربعة خمسة ستة وهذا حامل على ذرة
+
+447
+00:39:33,170 --> 00:39:37,230
+ثلاثة مجموعة مثل هذه الـ methyl معناها متصلة من هنا
+
+448
+00:39:38,630 --> 00:39:41,930
+دائماً اللي بتكون بين قوسين معنى ذلك هي متصلة 
+
+449
+00:39:41,930 --> 00:39:45,990
+برابطة ليست جزء من السلسلة اللي مكتوبة بين قوسين
+
+450
+00:39:45,990 --> 00:39:50,490
+شو معناها أن متصلة برابطة يعني هذه CH3 لما تكون 
+
+451
+00:39:50,490 --> 00:39:54,490
+بين قوسين يعني معناها موجودة هنا الآن هذا لما كله
+
+452
+00:39:54,490 --> 00:40:01,110
+بدأ أسمي شو بدأ أسمي one two three على موقع three
+
+453
+00:40:01,110 --> 00:40:09,580
+حامل methyl three methyl hexanoic acid three methyl hexanoic
+
+454
+00:40:09,580 --> 00:40:14,760
+acid واضح؟
+
+455
+00:40:14,760 --> 00:40:20,660
+وطبعاً جد ما تتعقد الأمور بإمكاننا أننا نستمر في 
+
+456
+00:40:20,660 --> 00:40:26,060
+التسمية وهنأخذ أمثلة كثير لكن خلينا نتعرض للأحماض
+
+457
+00:40:26,060 --> 00:40:31,040
+من أبسط حامض ونطلع قولنا أبسط حامض اللي فيه كم
+
+458
+00:40:31,040 --> 00:40:39,000
+كربونا؟ واحدة شو بدنا نسميه احنا؟ مثانوك أسيد الآن
+
+459
+00:40:39,000 --> 00:40:45,420
+الـ IUPAC name تبعه مثانوك أسيد الـ formic acid اللي
+
+460
+00:40:45,420 --> 00:40:50,160
+هو عبارة عن common name كويس أنتم ممتازين حافظينه و
+
+461
+00:40:50,160 --> 00:40:53,740
+عارفين أن formic acid لكن الـ formic acid اسم
+
+462
+00:40:53,740 --> 00:41:02,000
+الشهرة واضح بس اسمه بالـ IUPAC مثانوك أسيد بالـ
+
+463
+00:41:02,000 --> 00:41:10,720
+common بالإنجليزية formic acid بالعربية حمض
+
+464
+00:41:10,720 --> 00:41:16,540
+الفورميك اسم ثاني مين تتذكر ايش اسمه الثاني
+
+465
+00:41:16,540 --> 00:41:26,040
+بالعربية حمض الفورميك حمض النمليك لأن هذا من النمل
+
+466
+00:41:26,040 --> 00:41:30,600
+حمض النمليك من النمل بالألماني
+
+467
+00:41:32,720 --> 00:41:36,720
+Ameisensäure Ameisensäure يعني نمل و Säure يعني حمض
+
+468
+00:41:36,720 --> 00:41:41,380
+حمض النمل الألمان زي ما احنا بنسميه حمض النمليك هم 
+
+469
+00:41:41,380 --> 00:41:49,360
+برضه بيسموه حمض النمل واضح؟ آه لأنه
+
+470
+00:41:49,360 --> 00:41:53,480
+أصله من وين الـ source تبعه من الـ ants الـ ants اللي
+
+471
+00:41:53,480 --> 00:41:59,060
+هي النمل طب ليش سموه formic لأنه باللاتينية النمل
+
+472
+00:41:59,060 --> 00:42:05,480
+formica لاحظوا الأصل اللاتيني و الـ formica اللي هي
+
+473
+00:42:05,480 --> 00:42:10,700
+اسم النمل باللاتينية الآن الحامض اللي من Carbon اثنين
+
+474
+00:42:10,700 --> 00:42:19,100
+اللي هو Acetic Acid بالـ common حمض الخل بالعربية،
+
+475
+00:42:19,100 --> 00:42:23,340
+مظبوط ولا لأ؟ Essigsäure بالألمانية بالـ Ayurvedic
+
+476
+00:42:23,340 --> 00:42:27,900
+Ethanoic Acid وأصله من الـ vinegar الـ vinegar اللي 
+
+477
+00:42:27,900 --> 00:42:34,870
+هو الخل الآن الحامض اللي من ثلاث كربونات أصله من 
+
+478
+00:42:34,870 --> 00:42:41,130
+الحليب أصله من الحليب بيسموه بروبيونيك أسيد
+
+479
+00:42:41,130 --> 00:42:48,250
+بروبيونيك يعني اللي هو الـ common name تبعه الـ 
+
+480
+00:42:48,250 --> 00:42:56,090
+IUPAC بروبانويك انتبهوا للفرق بين الكلمتين في الـ IUPAC
+
+481
+00:42:56,090 --> 00:43:02,810
+بروبانويك، بالـ common بروبيونيك، بس أصله من وين؟ من
+
+482
+00:43:02,810 --> 00:43:08,470
+الحليب، من الـ Milch، عشان ذلك الألمان شو بيسموه؟ Milch
+
+483
+00:43:08,470 --> 00:43:14,910
+Säure، حمض الحليب، حمض الحليب على أصله، آه الأربع
+
+484
+00:43:14,910 --> 00:43:20,930
+كربونات أصله من ايش؟ من الزبدة، شكله احنا هنوهوله
+
+485
+00:43:20,930 --> 00:43:28,650
+للمطبخ بيقولوا عنه الـ Buttersäure حمض الزبدة أو بيوتيرك
+
+486
+00:43:28,650 --> 00:43:32,790
+لاحظوا كيف بيوتيرك بالواو هذا الاسم common name بس
+
+487
+00:43:32,790 --> 00:43:44,190
+الـ IUPAC بيوتانويك الخامسة
+
+488
+00:43:44,190 --> 00:43:50,210
+بنتانويك الاسم تبعه بالـ common Valeric إذا ما عليكم الستة
+
+489
+00:43:50,210 --> 00:43:57,170
+هكسانويك بيسموه كابرويك من الـ goats اللي هي الغنم أو المعز السابعة
+
+490
+00:43:57,170 --> 00:44:04,910
+هبتانويك بيسموه إينانتيك بالـ common name الثمانية أكتانويك
+
+491
+00:44:04,910 --> 00:44:08,850
+بيسموه كابريليك التاسعة نونانويك بيسموه بيلارغونيك العشرة
+
+492
+00:44:08,850 --> 00:44:13,150
+ديكانويك بيسموه كابريك طبعاً انتوا هتقولوا مطلوب مننا نحفظ كل
+
+493
+00:44:13,150 --> 00:44:17,340
+هالأسماء؟ لأ لكن انتبهوا معاه وانتوا بتقرأوا
+
+494
+00:44:17,340 --> 00:44:22,140
+وانتوا بتدرسوا في المستقبل بيكون في بالكم أن كل 
+
+495
+00:44:22,140 --> 00:44:26,080
+الأحماض هدول اللي اللهم نظام سهل في التسمية هانة
+
+496
+00:44:26,080 --> 00:44:31,080
+سهولة نظام الـ IUPAC يعني لو قلت لكم سامول الـ IUPAC 
+
+497
+00:44:31,080 --> 00:44:35,620
+من واحد لعشرة بتسموه بسهولة مثانوك إيثانوك بروبانوك
+
+498
+00:44:35,620 --> 00:44:40,350
+بيوتانوك متانوك لحد كانوك ما عندكم مشكلة لكن الكومون 
+
+499
+00:44:40,350 --> 00:44:45,050
+يلهّم أصل تاريخي اللي من الغنم واللي من الحليب
+
+500
+00:44:45,050 --> 00:44:49,790
+واللي من الخل واللي من النمل واللي .. واضح؟ لكن في
+
+501
+00:44:49,790 --> 00:44:54,890
+أي لحظة من اللحظات بتحتاجوا أنتم تتذكروا هذه
+
+502
+00:44:54,890 --> 00:44:58,410
+الشغلات تتذكروا أن في عندكم جدول للأحماض وأن كل
+
+503
+00:44:58,410 --> 00:45:02,530
+حامض زي ما إله اسم IUPAC إله اسم كومون لو في يوم من
+
+504
+00:45:02,530 --> 00:45:09,410
+الأيام لزمكم بتكونوا عارفينه .. وبهيك بننهي اليوم
+
+505
+00:45:09,410 --> 00:45:14,790
+وإن شاء الله للكلام بقية .. للكلام بقية ..
+
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..28acfbb4836254330112be3d669069c7b8b227ea
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_postprocess.srt
@@ -0,0 +1,2024 @@
+1
+00:00:08,740 --> 00:00:13,200
+اليوم بنكمل الجزء الأخير ان شاء الله في الموضوع ال
+
+2
+00:00:13,200 --> 00:00:18,900
+الدي هايتس والكيتونز وممكن ننتقل للفصل اللي بعده
+
+3
+00:00:18,900 --> 00:00:24,660
+اللي هو الأحماض الكربوكسيلية أخر شغلة اتكلمنا عنها
+
+4
+00:00:24,660 --> 00:00:29,590
+المرة الماضيةكانت ال acidity of alpha hydrogen
+
+5
+00:00:29,590 --> 00:00:32,650
+يمكن
+
+6
+00:00:32,650 --> 00:00:38,890
+ان تفقد في وجود قاعدة قوية السبب انه يمكن ان تفقد
+
+7
+00:00:38,890 --> 00:00:44,140
+ان الايون السالب اللى بتكون بامكانه يعملresonance
+
+8
+00:00:44,140 --> 00:00:48,260
+بنقول عنه الانوليت انايون يعني ممكن يكون محمول على
+
+9
+00:00:48,260 --> 00:00:52,460
+الكابون ممكن يكون محمول على ال oxygen هذا ال
+
+10
+00:00:52,460 --> 00:00:55,520
+resonance هو اللي بيقدر ال stability لل ايون
+
+11
+00:00:55,520 --> 00:01:01,260
+السالب وبيقدر ان ال alpha هيدروجين يمكن ان تفقد
+
+12
+00:01:01,260 --> 00:01:06,070
+الان هناخد تطبيقات على الاستفادة من هذه الفكرةيعني
+
+13
+00:01:06,070 --> 00:01:10,010
+احنا أخدناها كفكرة أن الـ Alpha Hydrogen يمكن أن
+
+14
+00:01:10,010 --> 00:01:13,810
+تفقد، الآن في تطبيقات في استفادة من هذا الكلام
+
+15
+00:01:13,810 --> 00:01:19,630
+واضح؟ من التطبيقات على سبيل المثال لو أنا أخدت
+
+16
+00:01:19,630 --> 00:01:24,230
+مراكب زي الـ Cyclohexanone واطلعت هل الـ
+
+17
+00:01:24,230 --> 00:01:29,010
+Cyclohexanone في Alpha Hydrogenالحقيقة بلاقي انه
+
+18
+00:01:29,010 --> 00:01:33,110
+في عدد كبير من الـ α هيدروجينز يعني هذه الكاربون
+
+19
+00:01:33,110 --> 00:01:37,510
+هذه الكاربون ألفة والهيدروجينز اللي عليها ألفة اذا
+
+20
+00:01:37,510 --> 00:01:42,210
+انا في اندي two هيدروجينز وبنفس الوقت على الجهة
+
+21
+00:01:42,210 --> 00:01:45,290
+التالية في اندي كمان two هيدروجينز اذا هذه
+
+22
+00:01:45,290 --> 00:01:52,210
+الكاربون محاطة باربع ألف هيدروجينز الان لو حطيتها
+
+23
+00:01:52,210 --> 00:01:58,170
+في base ال base ممكن تسحب منها ال Hو اتكون ايونات
+
+24
+00:01:58,170 --> 00:02:02,190
+سالبة اللى بيصير انه احنا لو حطناها في ال base مع
+
+25
+00:02:02,190 --> 00:02:05,970
+solvent هذا ال solvent بنقول عنه اديوتيريتد
+
+26
+00:02:05,970 --> 00:02:14,390
+ميثانول الميثانول العادى مار علينا CH3OH هذا بدل
+
+27
+00:02:14,390 --> 00:02:19,390
+ال H حطينا نظير ال H اللى هو الديوتيريا فبنقول عنه
+
+28
+00:02:19,390 --> 00:02:24,890
+اديوتيريتدميثانول يعني ميثانول قبدل في الهيدروجين
+
+29
+00:02:24,890 --> 00:02:29,850
+بنظيره اللي هو الديوتريان الان لاحظوا معنى هذا
+
+30
+00:02:29,850 --> 00:02:33,650
+حاطينه احنا بشكل كبير اللي بيصير في هذه الحالة ان
+
+31
+00:02:33,650 --> 00:02:38,010
+ال base بتسحب ال H التفاعل بشكل عكسي بيروح بده يحط
+
+32
+00:02:38,010 --> 00:02:42,410
+بدالها ايش بيحط بدالها D لان هنا مافيش H بال
+
+33
+00:02:42,410 --> 00:02:46,950
+solventبترد تاخد من الـ solvent D الكلام على مدى
+
+34
+00:02:46,950 --> 00:02:50,590
+طويل ممكن يتكرر مع القدش التاني مع القدش التالتة
+
+35
+00:02:50,590 --> 00:02:54,690
+مع القدش الرابعة لو أجينا للتفاعل هذا بعد ساعتين
+
+36
+00:02:54,690 --> 00:03:00,130
+تلاتة بنلاحظ أنه كل الهيدروجين ابدلت بديوتيريام
+
+37
+00:03:00,130 --> 00:03:04,870
+هذا بيسموه ايش الديوتيريام exchange يعني ابدال
+
+38
+00:03:04,870 --> 00:03:08,250
+الهيدروجين بديوتيريام الفكرة فيه ايش اللي خلى
+
+39
+00:03:08,250 --> 00:03:12,790
+الهيدروجين تنسحبأن ألف هيدروجين في وجود الbase
+
+40
+00:03:12,790 --> 00:03:17,150
+انسحبت عملة minus إجت لديوتريان مكانا، انسحبت عملة
+
+41
+00:03:17,150 --> 00:03:21,390
+minus إجت لديوتريان مكانا، كمان مرة، كمان مرة، ففي
+
+42
+00:03:21,390 --> 00:03:27,610
+النهاية بلاحظ أن كل الألف هيدروجين عملوا متحولوا
+
+43
+00:03:27,610 --> 00:03:34,050
+إلى ديوتريانكذلك الحال لو انا مثلا اخدت هذا
+
+44
+00:03:34,050 --> 00:03:39,970
+المُركّب لبيوتنال هى فيه كربونيل جروب وهى الالف
+
+45
+00:03:39,970 --> 00:03:45,390
+هيدروجينز هدولة اللي ماخدين لون أزرق لو حطيتهم في
+
+46
+00:03:45,390 --> 00:03:52,300
+ال water لفترة طويلةفي وجود ديوتريام كمان إضافة
+
+47
+00:03:52,300 --> 00:03:56,400
+بلاحظ ان كل الهيدروجين بتحولوا الى ايش الى
+
+48
+00:03:56,400 --> 00:04:00,120
+ديوتريام ليش هذا الكلب بتم لأن الهيدروجين هدولة
+
+49
+00:04:00,120 --> 00:04:06,200
+قابلات للفقد بيفقدوا و بيجي مكانهم الديوتريام
+
+50
+00:04:06,200 --> 00:04:10,400
+بيفقدوا و بيجي مكانهم الديوتريام هذا بيسمي احنا
+
+51
+00:04:10,400 --> 00:04:15,020
+alpha hydrogen exchange يعني تبديل ال alpha
+
+52
+00:04:15,020 --> 00:04:20,110
+hydrogenبالـ deuterium هذا أحد الأمثلة على
+
+53
+00:04:20,110 --> 00:04:25,810
+الاستفادة من ال acidity of alpha hydrogen المثال
+
+54
+00:04:25,810 --> 00:04:32,010
+التاني .. المثال التاني تفاعل شهير عادة التفاعلات
+
+55
+00:04:32,010 --> 00:04:34,870
+الشهيرة بيسموها name reactions يعني من كتر ما هي
+
+56
+00:04:34,870 --> 00:04:41,470
+مشهورة منسوبة لاسم محددممكن الاسم يكون اسم شخص و
+
+57
+00:04:41,470 --> 00:04:45,470
+ممكن يكون اشي تاني، واضح؟ هذا ال name reaction او
+
+58
+00:04:45,470 --> 00:04:51,070
+التفاعل الشهير اسمه ال doll condensation بتعرف ال
+
+59
+00:04:51,070 --> 00:04:55,070
+condensation تكثيف .. التكثيف ان اجمع جزيئين مع
+
+60
+00:04:55,070 --> 00:04:59,850
+بعض .. التكثيف ان اجمع جزيئين مع بعض طبعا باجمعهم
+
+61
+00:04:59,850 --> 00:05:05,030
+ممكن يفقد جزيئ صغير في هذه الحالةأيش الفكرة في
+
+62
+00:05:05,030 --> 00:05:11,990
+aldol condensation الفكرة لو أنا أخدت الديهايد او
+
+63
+00:05:11,990 --> 00:05:17,670
+كيتون وهذا الديهايد او الكيتون فعلته مع base مع
+
+64
+00:05:17,670 --> 00:05:23,570
+قاعدة بنسبة 2 إلى 1 ممكن الديهايد اللي ناخده يكون
+
+65
+00:05:23,570 --> 00:05:28,730
+ال acetaldehyde اتطلع عليه هذا acetaldehyde باخده
+
+66
+00:05:28,730 --> 00:05:35,010
+بأي نسبة ال acetaldehydeبنسبة اتنين بفعله مع قاعدة
+
+67
+00:05:35,010 --> 00:05:39,830
+القاعدة بتكون بنسبة واحد فانتوا انتبهوا معايا لما
+
+68
+00:05:39,830 --> 00:05:46,910
+يكون عندى اتنين acetaldehyde اتنين من هذا المركب
+
+69
+00:05:46,910 --> 00:05:50,510
+ال HCWOCH3
+
+70
+00:05:50,510 --> 00:05:56,580
+ونفعلهم مع واحد من ال baseالـ base ايش بتاخد عندنا
+
+71
+00:05:56,580 --> 00:06:01,940
+دائما؟ الـ alpha هيدروجين طيب لو افترضت مثلا عندى
+
+72
+00:06:01,940 --> 00:06:05,460
+مية جزء من الالديهيد بكون انفعله مع كام جزء من ال
+
+73
+00:06:05,460 --> 00:06:10,220
+base؟ مع خمسين هذا الكلام بيقدر الى نص كمية
+
+74
+00:06:10,220 --> 00:06:14,420
+الالديهيد بتصير عبارة عن ايون بتسحب منها
+
+75
+00:06:14,420 --> 00:06:20,770
+الهيدروجين والنص التانى بيضل زى ما هوالان لاحظوا
+
+76
+00:06:20,770 --> 00:06:25,230
+معي بزام صار نص ايونه هذا ما زال زي ما هو الايون
+
+77
+00:06:25,230 --> 00:06:30,810
+عبارة عن الـ eucleophile والتفاعل الأساسي لل
+
+78
+00:06:30,810 --> 00:06:34,490
+الديهيدز والكيتونز الـ eucleophilic addition فهذا
+
+79
+00:06:34,490 --> 00:06:37,930
+الايون اللي اتكوّن بيجي مضيف هنا و ال O بتصير
+
+80
+00:06:43,190 --> 00:06:48,450
+والـ O- بتاخد ميّه في النهاية بيصير عندك OH
+
+81
+00:06:53,620 --> 00:06:56,820
+الـ nucleophilic addition اللي احنا حكيناها انه
+
+82
+00:06:56,820 --> 00:07:02,800
+هذا ال nucleophile اتفاعل هنا و ال O صارت OH هذا
+
+83
+00:07:02,800 --> 00:07:07,960
+المركب نفسه لو رسمته كطريقة تانية بتلاحظوا انه
+
+84
+00:07:07,960 --> 00:07:12,800
+بيحتوي على مجموعتين وظيفيتين مجموعة ال aldehyde و
+
+85
+00:07:12,800 --> 00:07:19,030
+مجموعة ال alcohol واضح؟بيحتوي على مجموعة ال
+
+86
+00:07:19,030 --> 00:07:23,250
+الديهايد ومجموعة الالكهول وعشان هيك احنا بنسمي
+
+87
+00:07:23,250 --> 00:07:29,170
+المركب aldol condensation الام هذه كلمة aldol جاية
+
+88
+00:07:29,170 --> 00:07:38,130
+من ان الناتج في الديهايد وفي الالكهول aldol واضح
+
+89
+00:07:38,130 --> 00:07:43,930
+هلأ aldol مش اسم بني ادمالدول نسبة لمكونات
+
+90
+00:07:43,930 --> 00:07:49,150
+المُركّب الناتج اللي هو بيحتوي على الديهايد
+
+91
+00:07:49,150 --> 00:07:53,010
+وبيحتوي على ال alcohol ال alcohol all و ال
+
+92
+00:07:53,010 --> 00:07:57,710
+الديهايد بنعطي ال فبصير ال دول condensation طبعا
+
+93
+00:07:57,710 --> 00:08:01,670
+إذا احنا بدنا نتطلع على هذا المُركّب اللي هو ناتج
+
+94
+00:08:01,670 --> 00:08:09,490
+ال دول بنلاحظ أن الناتجهو عبارة عن beta-hydroxy
+
+95
+00:08:09,490 --> 00:08:13,130
+-aldehyde يعني لما أجي أقول هاي الديهايد واحد
+
+96
+00:08:13,130 --> 00:08:16,490
+اتنين تلاتة أربعة هاي موقع Alpha بالنسبة له و هاي
+
+97
+00:08:16,490 --> 00:08:22,410
+موقع Beta إيش بيكون الناتج لتفاعل الدول بيتا لا مش
+
+98
+00:08:22,410 --> 00:08:31,770
+اتنين مش اتنين beta-hydroxy-aldehydeفلما بدنا نقول
+
+99
+00:08:31,770 --> 00:08:35,930
+تفاعل ألدول، شو ناتج اللي بيعطينا بيتا هيدروكس
+
+100
+00:08:35,930 --> 00:08:43,550
+الألدهايد؟ ليش مش اتنين؟ لأن إعطاء ألفة وبيتا
+
+101
+00:08:43,550 --> 00:08:47,430
+بيبدأ بعد مجموعة الكربون، يعني بنقول هي الكربون،
+
+102
+00:08:47,430 --> 00:08:51,190
+بنقول اللي بعدها الأولى ألفة، هاد بيتا، واضح؟
+
+103
+00:08:51,190 --> 00:08:56,150
+بينما الترقيم بيبدأ من نفس مجموعة الكربونهذه واحدة
+
+104
+00:08:56,150 --> 00:08:59,890
+وهذه اتنين وهذه تلاتة عشان ايه هذا المركب لو بدأ
+
+105
+00:08:59,890 --> 00:09:07,370
+أسميه بال Iopaque هو عبارة عن three hydroxy طبعا
+
+106
+00:09:07,370 --> 00:09:14,410
+اربع كربونات بيوتنال لأ برضه مش one من اللي حكت
+
+107
+00:09:14,410 --> 00:09:20,510
+one؟ من اللي حكت one؟ ماتاعترفش ليش لأن احنا قولنا
+
+108
+00:09:20,510 --> 00:09:23,250
+ال aldehyde دائما على الطرف بس تعملوش one
+
+109
+00:09:39,160 --> 00:09:43,500
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+110
+00:09:43,500 --> 00:09:51,900
+الهيدروكسي الهيدروكسي الهيدروكسي
+
+111
+00:09:51,900 --> 00:09:53,300
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+112
+00:09:53,300 --> 00:09:59,130
+الهيدروكسيشرط تفاعل الألدول اللي مابمشيش بدونه أن
+
+113
+00:09:59,130 --> 00:10:04,790
+يكون عنده ألديهيد أو كيتون فيه ألف هيدروجين كل
+
+114
+00:10:04,790 --> 00:10:08,550
+الفكرة معتمدة على وجود ألف هيدروجين نسحب منها
+
+115
+00:10:09,250 --> 00:10:13,610
+البروتون بمعنى مش كل ال الديهيدز اللى فى الدنيا
+
+116
+00:10:13,610 --> 00:10:18,530
+ولا كل ال ketones اللى فى الدنيا ممكن تعمل aldol
+
+117
+00:10:18,530 --> 00:10:23,290
+reaction ممكن أعطيكوا أمثلة مثلا لو أخدنا ال
+
+118
+00:10:23,290 --> 00:10:28,090
+formaldehyde C double bond O H H هذا فيه alpha
+
+119
+00:10:28,090 --> 00:10:28,730
+hydrogen
+
+120
+00:10:31,330 --> 00:10:34,790
+لاحظوا الـ α هيدروجين هي الهيدروجين على الكاربون
+
+121
+00:10:34,790 --> 00:10:38,030
+المجاورة للـ C double bond O هاي الـ C double bond
+
+122
+00:10:38,030 --> 00:10:41,830
+O كاربون مجاورة عليها الف هيدروجين بس هاد
+
+123
+00:10:41,830 --> 00:10:45,530
+الهيدروجين على نفس الكاربون لأ مش الف هيدروجين
+
+124
+00:10:45,530 --> 00:10:51,710
+عشان كده لو بتفعلوا مع باسبمشيش يعني لو بدي أجي
+
+125
+00:10:51,710 --> 00:10:56,070
+أسألكوا في الامتحان أنه formaldehydes undergo
+
+126
+00:10:56,070 --> 00:10:59,890
+aldol condensation in the presence of a base
+
+127
+00:10:59,890 --> 00:11:05,050
+الجواب لأ لأنه مافيش بالformaldehyde alpha
+
+128
+00:11:05,050 --> 00:11:09,010
+hydrogen طيب لو أخدنا ال bins aldehyde متذكرين ولا
+
+129
+00:11:09,010 --> 00:11:13,670
+لأ هل
+
+130
+00:11:13,670 --> 00:11:21,920
+هذا في alpha hydrogen طلع عليههذا الكربون لا يحمل
+
+131
+00:11:21,920 --> 00:11:25,340
+أي نوع من الهيدروجين هنا في عندكم تنسوش عندما نفصل
+
+132
+00:11:25,340 --> 00:11:30,600
+البنزين نضع الروابط ليس هنا أي نوع من الهيدروجين
+
+133
+00:11:30,600 --> 00:11:32,860
+هنا رابطتين او تلاتة او اربعة ليس هنا أي نوع من
+
+134
+00:11:32,860 --> 00:11:35,560
+الالفهيدرجين ولا هناك أي نوع من الالفهيدرجين
+
+135
+00:11:40,680 --> 00:11:44,320
+و الـ benz aldehyde ما بيصيرش عليهم aldol reaction
+
+136
+00:11:44,320 --> 00:11:48,860
+لأنه مافيش alpha hydrogen نحذفها في وجود ال base
+
+137
+00:11:48,860 --> 00:11:54,760
+شرط ال aldol reaction أنه يكون عنده aldehyde أو
+
+138
+00:11:54,760 --> 00:11:58,260
+كيتون و يكون ال aldehyde أو الكيتون بيحتوي على
+
+139
+00:11:58,260 --> 00:12:05,660
+alpha hydrogen واضح؟
+
+140
+00:12:05,660 --> 00:12:08,160
+تالتاني على ال aldol reaction
+
+141
+00:12:11,450 --> 00:12:17,390
+لو أخدنا هذا ال الديهيد الكبير هذا ال الديهيد
+
+142
+00:12:17,390 --> 00:12:22,390
+شايفينه؟ واحد، اتنين، تلاتة، بيوتنال، two مثل
+
+143
+00:12:22,390 --> 00:12:26,310
+بيوتنال أنا اللي بيهمني منه كله أنه يكون بيحتوي
+
+144
+00:12:26,310 --> 00:12:30,310
+على إيش؟ Alpha Hydrogen هاي الكربون الأساسي، هاي
+
+145
+00:12:30,310 --> 00:12:34,090
+الكربون اللي جنبها الكربون اللي جنبها حملة
+
+146
+00:12:34,090 --> 00:12:39,150
+Hydrogen في عليها Alpha Hydrogenإذا في وجود base
+
+147
+00:12:39,150 --> 00:12:44,730
+.. إذا في وجود base زي مثلا ال sodium hydroxide
+
+148
+00:12:44,730 --> 00:12:50,750
+ممكن إنه يعمل condensation مع نفسه يعطينا الناتج
+
+149
+00:12:50,750 --> 00:12:56,110
+اللي موجود هناك طبعا هنا بصراحة إنه كيف نكتب
+
+150
+00:12:56,110 --> 00:13:02,050
+الناتج إذا أنتوا ماتدربتوش في البيت بالجلم لرصاص
+
+151
+00:13:02,050 --> 00:13:06,730
+كيف تعملوا هذا التفاعل مش هيكون سهل عليكم تكتبوا
+
+152
+00:13:06,730 --> 00:13:10,900
+الناتجطيب، الأن إيش أسهل؟ أسهل طريقة إنه أي
+
+153
+00:13:10,900 --> 00:13:15,740
+الديهايد أو كيتون موجود عندى أرسمه مرتين جانب بعض
+
+154
+00:13:15,740 --> 00:13:22,540
+مش هيوم أرسمها هو عادة موجود بنسبة إيش؟ 2 إلى 1
+
+155
+00:13:22,540 --> 00:13:26,300
+إذا أنا بدي أعيد الرسمة تبعته بدي أعيد الرسمة
+
+156
+00:13:26,300 --> 00:13:30,060
+تبعته زي ما هي بالظبط بدي أحط C double bond OH
+
+157
+00:13:30,060 --> 00:13:32,980
+وهنا CH
+
+158
+00:13:34,940 --> 00:13:42,080
+CH3 CH3 هاي صار عندى جزيئين الان هدول الجزيئين
+
+159
+00:13:42,080 --> 00:13:49,020
+واحد منهم بيفقد البروتون وبيعمل ايون سالب هاي هدا
+
+160
+00:13:49,020 --> 00:13:57,700
+فقد البروتون وعمل ايون سالب والتانى بيضل زى ما هو
+
+161
+00:13:57,700 --> 00:14:02,240
+الان بعد هيك شو اللى بده يصير الايون السالب بده
+
+162
+00:14:02,240 --> 00:14:08,850
+يخجمعلى الـ C double bond O تبع المُركّب التاني
+
+163
+00:14:08,850 --> 00:14:15,290
+هيهاجمها واحد بدأ تصير O minus وتصير في نهاية OH
+
+164
+00:14:15,290 --> 00:14:20,730
+عشان ذلك لما تيجوا تتطلعوا هنا بتلاحظوا أنه عملية
+
+165
+00:14:20,730 --> 00:14:25,290
+الاتصال تمت من أي كاربون اللي كانت حاملة Alpha
+
+166
+00:14:25,290 --> 00:14:28,910
+Hydrogen يعني لو حطينا هدول اللي لونهم أحمر في
+
+167
+00:14:28,910 --> 00:14:31,930
+صندوق هما عبارة عن
+
+168
+00:14:35,410 --> 00:14:42,630
+هذا الجزء واضح هيانا اتكون الايون السالب شايفينه
+
+169
+00:14:42,630 --> 00:14:51,590
+هاجم و أعطاني ال OH هيانا
+
+170
+00:14:51,590 --> 00:14:58,870
+اتكون الايون السالب و هاجم و أعطاني ال OH طبعا
+
+171
+00:15:00,970 --> 00:15:05,250
+نفس الشيء .. نفس الشيء لو كنا بدنا نعمل تفاعل
+
+172
+00:15:05,250 --> 00:15:12,170
+للأسيتون مع نفسه في وجود base هاي أسيتون سيبنا من
+
+173
+00:15:12,170 --> 00:15:15,550
+هذه الأشياء اللي بتتكون بشكل بسيط خلينا بالأسيتون
+
+174
+00:15:15,550 --> 00:15:20,030
+الان لو قولنا لأي واحدة فيكوا اعمليلنا الاسيتون شو
+
+175
+00:15:20,030 --> 00:15:25,270
+الخطوة اللي لازم تعملها أول إشي بدا ترسمه زي ما هو
+
+176
+00:15:25,270 --> 00:15:28,290
+مرة تانية CH3
+
+177
+00:15:29,510 --> 00:15:35,650
+C double bond O CH3 بعد هيك على أحد الجهات ممكن
+
+178
+00:15:35,650 --> 00:15:42,450
+تتكون تصير هذه CH2- في وجود ال base عملة الآيون
+
+179
+00:15:42,450 --> 00:15:50,690
+السالب الآيون السالب وين بيهاجم؟ و
+
+180
+00:15:50,690 --> 00:15:56,650
+هذه بتصير واجهة إذا بتطلعوا هنا هتلاحظوا إن هاي
+
+181
+00:15:56,650 --> 00:16:05,170
+الجزء الأحمر هو هذاCH3C CH3 وحملة OH و هذا
+
+182
+00:16:05,170 --> 00:16:11,230
+الاسيتون هاجم من هذه واضح زي ما بحكيلكوا انه هذا
+
+183
+00:16:11,230 --> 00:16:15,790
+الكلام مش سهل مش سهل انكوا تجاوبوا عليه في
+
+184
+00:16:15,790 --> 00:16:20,930
+الامتحان اذا ماقعدتوش عمله و كتابتوا بقلم لرصاص و
+
+185
+00:16:20,930 --> 00:16:24,630
+اتدربتوا عليه كيف تكتبوا لقده ل product هي عندكوا
+
+186
+00:16:24,630 --> 00:16:29,910
+مثال علىالـ Acetaldehyde هاي مثال تاني كان على
+
+187
+00:16:29,910 --> 00:16:35,870
+مثلا تومثيلبروبانال هاي مثال تالت على الاسيتون
+
+188
+00:16:35,870 --> 00:16:41,530
+ممكن أي واحدة تعمللنا مثال على مثلا ال .. البيوت
+
+189
+00:16:41,530 --> 00:16:46,430
+.. البروبانال CH3
+
+190
+00:16:46,430 --> 00:16:53,710
+CH2 C double bond OH ممكن نجيبلكوا هذا السؤالبدنا
+
+191
+00:16:53,710 --> 00:16:59,090
+نعمل لبرو بانال ادو ال product الفعله بنسبة اتنين
+
+192
+00:16:59,090 --> 00:17:03,570
+الى واحد مع ال base بتعملوه فى البيت بتجربوه
+
+193
+00:17:03,570 --> 00:17:09,650
+براحتكوا لحد ما يظبط معاكم بس دائما ال hydrogen
+
+194
+00:17:09,650 --> 00:17:16,910
+اللى بده يصير لها abstract اللى بده تفقد اي
+
+195
+00:17:16,910 --> 00:17:22,220
+hydrogen ال alpha hydrogenوالهجوم بيكون على ال c
+
+196
+00:17:22,220 --> 00:17:29,600
+double bond o تبعت الجزاء التانى جربوا هذا المركب
+
+197
+00:17:29,600 --> 00:17:35,880
+اعمله هدوء فى البيت كمزيد من التدريب
+
+198
+00:17:44,860 --> 00:17:52,000
+أخر شغلة ممكن ناخد مثال على إيش بنسميه mixed aldol
+
+199
+00:17:52,000 --> 00:17:57,360
+condensation إيش يعني mixed aldol؟ يعني ما أستعملش
+
+200
+00:17:57,360 --> 00:18:02,960
+ال aldehyde يتفاعل مع نفسه ممكن أستعمل aldehyde
+
+201
+00:18:02,960 --> 00:18:12,340
+معين يعمل ال ion ويهاجم على aldehyde تانيواضح؟ لأ
+
+202
+00:18:12,340 --> 00:18:16,640
+احنا ماكناش نعمل زيك، احنا كنا .. انتبهوا معايا،
+
+203
+00:18:16,640 --> 00:18:21,280
+بده .. بده هدوء في فهم النقطة، احنا كنا بنحط ال
+
+204
+00:18:21,280 --> 00:18:27,300
+الديهايد بنسبة 2 و ال base بنسبة 1، الان نص كمية
+
+205
+00:18:27,300 --> 00:18:32,860
+ال الديهايد بتصير ايون و بتهاجمعلى النص التاني
+
+206
+00:18:32,860 --> 00:18:37,520
+اللي ما صارش ايون الان انا ممكن اعمل بطريقة تانية
+
+207
+00:18:37,520 --> 00:18:42,000
+ان اخلط two aldehydes يعني كل الأمثلة السابقة اللي
+
+208
+00:18:42,000 --> 00:18:46,200
+شفتوها كان aldehyde مع نفسه يعني لو كان عندكوا تلت
+
+209
+00:18:46,200 --> 00:18:50,300
+كربونات في ال aldehyde فالنتج النهائي كده يكون
+
+210
+00:18:50,300 --> 00:18:58,190
+عندكم؟ ستة اتنين يتحدوا مع بعضخلّينا نرجع نعلمكم
+
+211
+00:18:58,190 --> 00:19:02,450
+العدل من أول و جديد هنا كام carbon عندكم؟ تنتين ..
+
+212
+00:19:02,450 --> 00:19:06,290
+و لما يتفاعل مع نفسه .. ف .. okay الناتج النهائي
+
+213
+00:19:06,290 --> 00:19:10,750
+.. كام carbon أطلع فيه؟ أربعة .. واضح؟ هنا كام
+
+214
+00:19:10,750 --> 00:19:14,290
+carbon عندكم؟ واحد .. اتنين .. تلاتة .. أربعة .. و
+
+215
+00:19:14,290 --> 00:19:17,110
+لما يتفاعل مع نفسه .. الناتج النهائي .. كم يطلع
+
+216
+00:19:17,110 --> 00:19:19,570
+فيه؟ واحد .. اتنين .. تلاتة .. أربعة .. خمسة ..
+
+217
+00:19:19,570 --> 00:19:22,790
+ستة .. سبعة .. تمام .. إذا هو كرر نفسه بشكل أو
+
+218
+00:19:22,790 --> 00:19:28,800
+باخرواضح؟ بينما الـ mixed aldol أنا باخد الديهيد
+
+219
+00:19:28,800 --> 00:19:34,780
+مايتفعلش مع نفسه يتفعل مع الديهيد تاني واضح؟ فمثلا
+
+220
+00:19:34,780 --> 00:19:41,280
+لو أخدت ال benz aldehyde و الacetaldehyde و فعلتم
+
+221
+00:19:41,280 --> 00:19:46,790
+مع base ال benz aldehyde بنسبة واحدالـ Acetal
+
+222
+00:19:46,790 --> 00:19:51,030
+Dehydrate بنسبة واحد الـ Base بنسبة واحد الان
+
+223
+00:19:51,030 --> 00:19:54,670
+لاحظوا معاه الـ Base الداهيد مافيه Alpha Hydrogen
+
+224
+00:19:54,670 --> 00:20:00,790
+مش هيعمل ايون الـ Acetal Dehydrate فيه Alpha
+
+225
+00:20:00,790 --> 00:20:05,050
+Hydrogen فلما يكون بنسبة واحد لواحد هيعمل ايون وين
+
+226
+00:20:05,050 --> 00:20:11,290
+الايون السالب هيصير؟ على الـ Alpha Carbon الان هذا
+
+227
+00:20:11,290 --> 00:20:12,350
+الايون السالب
+
+228
+00:20:21,550 --> 00:20:31,690
+واضح؟ فهي ناتج الألدل، هي ناتج الألدل، هي
+
+229
+00:20:31,690 --> 00:20:36,930
+الجزء، الجزء الأحمر الديهايد والجزء الأسود
+
+230
+00:20:37,950 --> 00:20:42,530
+الالديهيد التاني انا خلطت two different aldehydes
+
+231
+00:20:42,530 --> 00:20:48,090
+انا خلطت two different aldehydes بالمناسبة هذا في
+
+232
+00:20:48,090 --> 00:20:52,750
+شوية تسخين بسيط بفقد OH من هنا و OH من هنا بيعطينا
+
+233
+00:20:52,750 --> 00:20:57,690
+double bond بيعطينا ال aldehyde اللي شو اسمه؟
+
+234
+00:20:57,690 --> 00:21:01,150
+cinnamaldehyde هذا ال aldehyde مشهور
+
+235
+00:21:01,150 --> 00:21:04,390
+cinnamaldehyde cinnamaldehyde من أيه جاي؟
+
+236
+00:21:07,010 --> 00:21:11,310
+اتذكروا معاه cinema
+
+237
+00:21:11,310 --> 00:21:17,710
+aldehyde هو aldehyde .. ال cinnamon .. cinnamon ..
+
+238
+00:21:17,710 --> 00:21:24,950
+مرت عليكم كلمة cinnamon؟ إيش هي؟ الجرفة .. الجرفة
+
+239
+00:21:24,950 --> 00:21:30,420
+.. هذا aldehyde الجرفةيعني ممكن ان حضره في المختبر
+
+240
+00:21:30,420 --> 00:21:37,120
+و يطلق نفس الريحة اللي
+
+241
+00:21:37,120 --> 00:21:43,300
+بيمنع ان
+
+242
+00:21:43,300 --> 00:21:47,820
+انا حاطط هذا بنسبة واحد إلى واحد فحولت كل هذا ..
+
+243
+00:21:47,820 --> 00:21:53,390
+حولت كل هذا إلى ايون سالبيعني التفاعل مع ال base
+
+244
+00:21:53,390 --> 00:21:57,550
+أقوى الآن السؤال اللي بتسألوا زملتكم .. السؤال
+
+245
+00:21:57,550 --> 00:22:02,670
+اللي بتسألوا زملتكم إيه وجهها لو أنا حطيت .. لو
+
+246
+00:22:02,670 --> 00:22:07,350
+أنا حطيت two aldehydes .. لو حطيت two aldehydes
+
+247
+00:22:07,350 --> 00:22:12,730
+والتانين فيهم alpha hydrogen وروحت انفعلهم مع base
+
+248
+00:22:12,730 --> 00:22:18,590
+يعني مثلا حطيت هذا ال acetaldehyde اللي عندك CH3
+
+249
+00:22:23,710 --> 00:22:33,290
+CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH3
+
+250
+00:22:33,290 --> 00:22:41,790
+CH3 CH2 CH3 CH3
+
+251
+00:22:41,790 --> 00:22:43,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+252
+00:22:43,170 --> 00:22:44,550
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+253
+00:22:44,550 --> 00:22:44,730
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+254
+00:22:44,730 --> 00:22:45,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+255
+00:22:45,130 --> 00:22:45,350
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+256
+00:22:45,350 --> 00:22:46,310
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+257
+00:22:46,310 --> 00:22:46,510
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+258
+00:22:46,510 --> 00:22:46,590
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+259
+00:22:48,660 --> 00:22:55,080
+الامور هنا كتير بتتعقد زي تماما إذا بتذكروا لما
+
+260
+00:22:55,080 --> 00:22:59,400
+كنا نخلط .. لما كنا نخلط two alcohols مع بعض عشان
+
+261
+00:22:59,400 --> 00:23:03,900
+نحضر unsymmetrical ether كام ناتج كان يطلع عنده؟
+
+262
+00:23:03,900 --> 00:23:09,940
+تلاتة هنا لو عملنا زي هيك في عندنا إمكانية أنه هنا
+
+263
+00:23:09,940 --> 00:23:17,690
+يتكون عندكأيون سالب يعني هذا تصير CH2- واتهاجم على
+
+264
+00:23:17,690 --> 00:23:21,490
+الجزء اللي منها ما اتفعلش وفي إمكانية نهانة كمان
+
+265
+00:23:21,490 --> 00:23:27,470
+يتكون عند أيون سالب يعني هذا تصير CH- واتهاجم على
+
+266
+00:23:27,470 --> 00:23:31,310
+نفسها وفي إمكانية هذه تهاجم على هذه وهذه تهاجم على
+
+267
+00:23:31,310 --> 00:23:35,570
+هذه إذا كام ناتج هان بدو يطلع عندكم؟اربع .. طبعا
+
+268
+00:23:35,570 --> 00:23:40,390
+جزء أساس .. انتبهوا معي .. جزء أساس من فهم مثل هذا
+
+269
+00:23:40,390 --> 00:23:44,610
+المثال أنه أنتوا تكونوا منتبهين أنه احنا بنفعلش
+
+270
+00:23:44,610 --> 00:23:49,950
+الجزيئات بنسبة واحد إلى واحد بمعنى بنفعلش جزء من
+
+271
+00:23:49,950 --> 00:23:54,830
+هذا وجزء من هذا وجزء من هذالو حد فيكو جاعت بتخيل
+
+272
+00:23:54,830 --> 00:23:58,930
+أنه أنا بس افعل جزء واحد من هذا وجزء من هذا وجزء
+
+273
+00:23:58,930 --> 00:24:02,390
+من هذا كان هيقول ال base أكيد يا بده تاخد بروتون
+
+274
+00:24:02,390 --> 00:24:06,630
+من هان يا من هان و بتفعل على التاني بس أنا حقيقة
+
+275
+00:24:06,630 --> 00:24:11,710
+لما بفعل بالوضع الطبيعي بفعل واحد mole لو بتقول
+
+276
+00:24:11,710 --> 00:24:15,590
+مثلا واحد mole او نص mole بلاش خليني اقول مليون
+
+277
+00:24:15,590 --> 00:24:21,110
+جزء اتخيلوا انا بده افعل مليون جزء من هذا مع مليون
+
+278
+00:24:21,110 --> 00:24:28,290
+من اللي هانمع مليون من الـ base خلّي ال base مثلا
+
+279
+00:24:28,290 --> 00:24:33,350
+تاخد نص مليون من هدولة تخلّيهم ايش؟ ايون سالب،
+
+280
+00:24:33,350 --> 00:24:37,210
+بمعنى ذلك، ضال عندكم نص مليون مش محولين لأيون
+
+281
+00:24:37,210 --> 00:24:42,470
+وخلّي ال base كمان تتحول من هدولة نصهم، نص مليون
+
+282
+00:24:42,470 --> 00:24:46,990
+صاروا ايون ونص؟ لأ، إذا مخلوط التفاعل في هذه
+
+283
+00:24:46,990 --> 00:24:51,140
+الحالة، شو هيصف فيه بالنهاية؟نص مليون من ال
+
+284
+00:24:51,140 --> 00:24:56,860
+الديهايد هذا و نص مليون من ال ايون و نص مليون من
+
+285
+00:24:56,860 --> 00:24:59,660
+ال الديهايد هذا و نص مليون من ال ايون و خلهم
+
+286
+00:24:59,660 --> 00:25:04,180
+يتفعلوا مع بعض كام ناتج بيطلع عندكم؟ أربع نواتج
+
+287
+00:25:04,180 --> 00:25:10,140
+هذا مع نفسه هذا مع نفسه هذا مع ال الديهايد اللي
+
+288
+00:25:10,140 --> 00:25:15,000
+هان هذا مع ال الديهايد اللي هان أربع نواتجعلى أي
+
+289
+00:25:15,000 --> 00:25:19,860
+حال عشان ما نضيعش وقت ونشجعكوا انه تفكروا فيهم
+
+290
+00:25:19,860 --> 00:25:27,080
+بشكل ممتاز اعملوهم homework الاربع نواتج المتوقعة
+
+291
+00:25:27,080 --> 00:25:31,140
+من هنا homework مرتب و سلموني المحاضرة الجاي هذا
+
+292
+00:25:31,140 --> 00:25:38,420
+اخر homework عليه ايش درجات اربع نواتج بدو يطلع
+
+293
+00:25:38,420 --> 00:25:43,500
+عندكم ورسموهم صحلازم عشان تعملوا هذا الكلام
+
+294
+00:25:43,500 --> 00:25:46,780
+تراجعوا الموضوع كله من الأول اتعودوا إيدكم ترسموا
+
+295
+00:25:46,780 --> 00:25:50,700
+الأمثلة كلها اللي أخدناها لحد ما تصلوا هنا في
+
+296
+00:25:50,700 --> 00:25:56,300
+النهاية بيطلع عندكم مثل هذا المثال أربع نواتج طبعا
+
+297
+00:25:56,300 --> 00:25:59,640
+هنا احنا اتريحنا ماطلعش إلا ناتج واحد لإن واحد
+
+298
+00:25:59,640 --> 00:26:04,080
+منهم في Alpha Hydrogen إتانفش في Alpha Hydrogen
+
+299
+00:26:04,080 --> 00:26:05,860
+واضح؟
+
+300
+00:26:07,550 --> 00:26:13,030
+طيب، الأن اتفقتوا معي كلكم أن المفروض يطلع أربع
+
+301
+00:26:13,030 --> 00:26:21,190
+نوات جهان؟ ولا لأ؟ هتعملهم في البيت؟ طيب، أخر سؤال
+
+302
+00:26:21,190 --> 00:26:26,490
+.. أخر سؤال ممكن نسأله؟ أخر سؤال ممكن نسأله؟
+
+303
+00:26:26,490 --> 00:26:32,610
+مستعدين أن نسأله؟ أه لأ، بديكوا تنتبهوا لإن اللي
+
+304
+00:26:32,610 --> 00:26:36,030
+بده يجاوبه هعطيه علامات، على طول هينزلوا على ..
+
+305
+00:26:37,180 --> 00:26:42,400
+هينزلوا على الرصيد تبعه لو بدي واحد محدد من
+
+306
+00:26:42,400 --> 00:26:47,280
+الأربعة يطلع انا قاعد بقولكوا اذا خلطتهم مع ال
+
+307
+00:26:47,280 --> 00:26:51,860
+base بنسبة واحد الى واحد الى واحد هيطلع عندى كام
+
+308
+00:26:51,860 --> 00:26:55,660
+ناتج اربع نواتج و هتكتبوهم بال homework و تسلمون
+
+309
+00:26:55,660 --> 00:27:03,960
+اياهم الان لو بدي ناتج محدد ممكن ..ممكن أرسملكوا
+
+310
+00:27:03,960 --> 00:27:09,340
+هذا الناتج المحدد اللي أنا بديها بمشي مثلا لو
+
+311
+00:27:09,340 --> 00:27:18,480
+قولنا بدنا هذا الناتج هذه
+
+312
+00:27:18,480 --> 00:27:25,700
+CH2 وهنا
+
+313
+00:27:25,700 --> 00:27:27,780
+حطينا C
+
+314
+00:27:37,380 --> 00:27:42,620
+CH3 بدي بس هذا الناتج حصريا يطلع عندى exclusive
+
+315
+00:27:42,620 --> 00:27:48,180
+بتعرف إيش أنا حصري بس هذا الناتج مايطلعوش أربعة
+
+316
+00:27:48,180 --> 00:27:52,280
+هذا أحد الأربعة بالمناسبة اللي كان هيطلعوا الآن
+
+317
+00:27:52,280 --> 00:27:58,140
+أنا بدي التفاعل بس يطلعلي هذا ولا شيء أغيره اتفضلى
+
+318
+00:27:58,140 --> 00:28:03,860
+هاي لا لا أبعد ولا خاصة green yard فيها المنطقة
+
+319
+00:28:08,810 --> 00:28:14,530
+مش هتظبط معاك، هيطلع خليط من الأربعة، هيطلع خليط
+
+320
+00:28:14,530 --> 00:28:19,710
+من الأربعة برضه طالما
+
+321
+00:28:19,710 --> 00:28:25,790
+مع بعض هيطلع خليط من الأربعة، أنا بدي واحد مية في
+
+322
+00:28:25,790 --> 00:28:30,990
+المية، بس يطلع عندى واحد فقط لغير، only one
+
+323
+00:28:30,990 --> 00:28:32,550
+product مش four products
+
+324
+00:28:37,450 --> 00:28:41,970
+ماخصش ال resonance هنا خليني أشوف غيرك، اتفضلي
+
+325
+00:28:41,970 --> 00:28:46,250
+الربع
+
+326
+00:28:46,250 --> 00:28:51,890
+بس، هتاخد .. الربع بينك سيمتوم لين؟ طمون هيجي يعمل
+
+327
+00:28:51,890 --> 00:28:57,230
+هنا و طمون هنا و برضه هيطلع عندك خليط و هتطلعيلي
+
+328
+00:28:57,230 --> 00:29:02,790
+كمان تمان مراكبات لأنه هيضل أشياء مش متفاعلة لأ لأ
+
+329
+00:29:02,790 --> 00:29:11,830
+البس بس حرام عليكممين كانت هناك بدأت تجاوب؟ لأ لأ
+
+330
+00:29:11,830 --> 00:29:14,870
+احنا .. انا في ال rearrangement، بعدي بعدي كتير عن
+
+331
+00:29:14,870 --> 00:29:18,610
+ال rearrangementلأ لأ بنضيف الشغلة و الله فكرة
+
+332
+00:29:18,610 --> 00:29:22,950
+بسيطة لأ انتوا لاحظوا بس أنا ليش بسألكوا هذا
+
+333
+00:29:22,950 --> 00:29:29,010
+الكلام حتى تشوفوا انه مرات ما بين .. ما بين الشغلة
+
+334
+00:29:29,010 --> 00:29:35,770
+الصعبة كتير و الشغلة السهلة أو ما بين المشكلة و
+
+335
+00:29:35,770 --> 00:29:44,910
+حلها فكرة بسيطة جدا جدا ما بين المشكلة و حلهافكرة
+
+336
+00:29:44,910 --> 00:29:50,370
+بسيطة جدا جدا يعني مش الاشي المعقد ولا الاشي اللي
+
+337
+00:29:50,370 --> 00:29:54,470
+بيغلب المشكلة بتنحل بسهولة كتير ان بدل ما يطلع
+
+338
+00:29:54,470 --> 00:30:01,610
+عندى أربع نواتج اطلع ايش ناتج واحد في حد بده يجاوب
+
+339
+00:30:01,610 --> 00:30:10,650
+ولا خلاص انطحين في السؤال اخر جاوب اتفضل ممتاز
+
+340
+00:30:10,650 --> 00:30:16,390
+هذا الكلام الصح اللي حكته زملتكنهتاخد .. شو اسمك؟
+
+341
+00:30:16,390 --> 00:30:20,950
+سمية .. سمية خفاجة .. اه .. سمية حكت كلام بسيط
+
+342
+00:30:20,950 --> 00:30:24,090
+احنا كانت المشكلة عندنا .. نكون .. نكون ماخدين
+
+343
+00:30:24,090 --> 00:30:27,770
+هدول الأزدهار .. تتخيلوا أنه في عندنا flask .. هي
+
+344
+00:30:27,770 --> 00:30:32,330
+flask .. حاطينهم كلهم .. حاطينهم كلهم مع بعض و
+
+345
+00:30:32,330 --> 00:30:37,970
+حاطين ال base معهم .. فال base بتتطلعبتلاقي من هذا
+
+346
+00:30:37,970 --> 00:30:42,990
+بتعمل منه ion بتلاقي من هذا بتعمل منه ion الكلام
+
+347
+00:30:42,990 --> 00:30:47,770
+اللي هي حكته انه احنا بعيدنا الله لجزاز كتير في
+
+348
+00:30:47,770 --> 00:30:54,110
+المختبر بدناش نستعمل flask واحد بنستعمل two flasks
+
+349
+00:30:54,110 --> 00:30:59,110
+خلينا نقول هي ال flask الأسود و بنحط فيه هذا
+
+350
+00:30:59,110 --> 00:31:01,870
+المركب CH3
+
+351
+00:31:03,390 --> 00:31:09,970
+CH2C double bond O H كويس و بنستعمل ال flask تاني
+
+352
+00:31:09,970 --> 00:31:15,610
+خلينا نقول عنه ال flask الأحمر و بنحط فيه المركب
+
+353
+00:31:15,610 --> 00:31:22,410
+هذا CH3C double bond O H لو افترضت مثلا عندي مليون
+
+354
+00:31:22,410 --> 00:31:29,670
+جزء من هذا و مليون من هذا باجي بحط ال base بس على
+
+355
+00:31:29,670 --> 00:31:34,200
+هذاهنا بحط ال base هذا بسيبه زي ما هو بحطش عليه
+
+356
+00:31:34,200 --> 00:31:38,920
+base الأن لما حطينا ال base بنسبة واحد إلى واحد كل
+
+357
+00:31:38,920 --> 00:31:45,000
+هذا صار عبارة عن ايش ايون سالب المليون جزء اللي
+
+358
+00:31:45,000 --> 00:31:49,800
+هنا كلهم صاروا ايونات سالبة وهذا كله ماجتش عليه
+
+359
+00:31:49,800 --> 00:31:55,780
+base دله زي ما هو بعدين بننزك هذا ال flask بنكبه
+
+360
+00:31:55,780 --> 00:32:01,700
+فوق هذابنكب الايون كل هذا ايون و كل هذا الديهايد
+
+361
+00:32:01,700 --> 00:32:04,720
+لما نمسك هذا ال flask و نكبه فوق هذا، شو التفاعل
+
+362
+00:32:04,720 --> 00:32:12,360
+بدي يصير؟ هيعطينا الناتج المحدد اللي أنا رسمته و
+
+363
+00:32:12,360 --> 00:32:18,280
+لو كنت بدي، الناتج التالع، بضيف ال base هان شوفتوا
+
+364
+00:32:18,280 --> 00:32:23,930
+قداش الفكرة؟ يعني كل الفرق تبعهافلسك ان انا ضفت
+
+365
+00:32:23,930 --> 00:32:30,130
+على واحد حولته بشكل كامل لل ايون بدون ما اعطي هذا
+
+366
+00:32:30,130 --> 00:32:33,050
+امكانيا ان يصبح ايون حاطه انا بفلسك تاني جاعت
+
+367
+00:32:33,050 --> 00:32:39,550
+باستنى وبعدين ضفت التانية فوق بعض بهيك بالطول
+
+368
+00:32:39,550 --> 00:32:44,610
+مراكب واحد لاحظوا جداش المشكلة خدوا مبدأ للحياة
+
+369
+00:32:44,610 --> 00:32:54,200
+جداش المشكلة ممكنتكون كبيرة جداش المشكلة ممكن تكون
+
+370
+00:32:54,200 --> 00:33:05,350
+كبيرة و جداش الحل تبعها ممكن يكونسهل او صغير جداش
+
+371
+00:33:05,350 --> 00:33:08,930
+المشكلة ممكن تكون كبيرة و جداش الحال تبعها ممكن
+
+372
+00:33:08,930 --> 00:33:15,030
+تكون سهل او صغير ممكن بعد ما نخلص المحاضرة نحكيلكم
+
+373
+00:33:15,030 --> 00:33:19,470
+على قصة دائما بيروها تبعون إدارة الأعمال في هذا
+
+374
+00:33:19,470 --> 00:33:27,470
+المجال كيف انه في مشكلة كبيرة و حالها ايش و حالها
+
+375
+00:33:28,310 --> 00:33:32,390
+بسيط، بعد ما نخلص المحاضرة، في آخر دقيقتين
+
+376
+00:33:32,390 --> 00:33:35,970
+بنحكيلكوا المشكلة كيف بتكون كبيرة و في الآخر
+
+377
+00:33:35,970 --> 00:33:43,130
+الحالة تبعها سهل أو بسيط خلصنا الشبطر بس ما خلصناش
+
+378
+00:33:43,130 --> 00:33:47,630
+المحاضرة لازم
+
+379
+00:33:47,630 --> 00:33:52,920
+دائما نبدأ في إيش؟في chapter جديد عشان نقول احنا
+
+380
+00:33:52,920 --> 00:33:58,320
+بديني بعشرة ومن السنة كمان إذا أنتم ما بتعرفوش أن
+
+381
+00:33:58,320 --> 00:34:03,580
+الإنسان يكون له word في قراءة القرآن يعني دائما
+
+382
+00:34:03,580 --> 00:34:09,600
+لما نيجي نسأله أنت وين واصل يقول أنا واصلللنقطة
+
+383
+00:34:09,600 --> 00:34:13,180
+الفلانية يعني يكون إله مكان واصل إله .. الأصل
+
+384
+00:34:13,180 --> 00:34:16,440
+الإنسان المسلم كل يوم بده يقرأ إيش؟ قرآن .. وكل
+
+385
+00:34:16,440 --> 00:34:20,260
+يوم .. لامد جزء .. ماحدش قال من العلماء جزء .. كل
+
+386
+00:34:20,260 --> 00:34:23,960
+يوم بده يقرأ قرآن .. و دائما قلبه معلق .. إن أنا
+
+387
+00:34:23,960 --> 00:34:26,760
+وصلت لهان .. أنا وصلت لهان .. أنا وصلت لهان .. طب
+
+388
+00:34:26,760 --> 00:34:29,820
+السؤال عاد .. لما بيخلص قراية القرآن .. شو بده
+
+389
+00:34:29,820 --> 00:34:37,170
+يعمله؟من السنة أنه بنفس الجلسة يبدأ من الأول وجديد
+
+390
+00:34:37,170 --> 00:34:41,630
+يقرأ الفاتحة وجزء صغير من البجرة عشان يقول أنا
+
+391
+00:34:41,630 --> 00:34:47,910
+واصل لنقطة الفلانية وبدأ أستمر .. بنفع .. بس مش
+
+392
+00:34:47,910 --> 00:34:52,330
+محبّذ .. احنا بنقول من السنة أنه مايختمش عند نهاية
+
+393
+00:34:52,330 --> 00:34:56,290
+المصحف ويسكر المصحف وخلاص .. لما تختموا القرآن ..
+
+394
+00:34:56,290 --> 00:35:02,050
+شو بدكوا تعمله؟بتكونوا تبدأوا تجيبوا الفاتحة و
+
+395
+00:35:02,050 --> 00:35:05,490
+أكام من آية من صورة البقرة عشان تكونوا انتوا دائما
+
+396
+00:35:05,490 --> 00:35:10,490
+القراءة عندكم إيش تكون متصلة و احنا نفس الاشي
+
+397
+00:35:10,490 --> 00:35:14,970
+بنفعل الآن ننهي chapter 9 لأ لازم ناخدلنا خمس
+
+398
+00:35:14,970 --> 00:35:20,250
+دقايق بعشرة الآن
+
+399
+00:35:20,250 --> 00:35:27,490
+خلينا في chapter 10 خمس دقائق مقدمةمقدمة كل دقيقة
+
+400
+00:35:27,490 --> 00:35:30,790
+وقت الناس لازم يستغلوا لما يكون عندكم ربع ساعة
+
+401
+00:35:30,790 --> 00:35:36,810
+الربع ساعة بتنجزوا فيها فكرة و بتنجزوا فيها عمل لا
+
+402
+00:35:36,810 --> 00:35:43,310
+تستهيلوا بالوقت chapter عشر اكمال لفصل التاسع لكن
+
+403
+00:35:43,310 --> 00:35:47,830
+بيحكي عن ايش اللي هي ال carboxylic acids and their
+
+404
+00:35:47,830 --> 00:35:52,210
+derivatives بتذكروا احنا حكينا ان السيطة بال bond
+
+405
+00:35:52,210 --> 00:35:58,380
+O عبارة عنالنوعين، اللي هي الـ Carbonyl group الـ
+
+406
+00:35:58,380 --> 00:36:06,400
+Aldehydes و الـ Ketones أخدناهم كمجموعة واحدة و
+
+407
+00:36:06,400 --> 00:36:11,160
+اللي بيميزهم كلمة واحدة شو الكلمة اللي بتميز الـ
+
+408
+00:36:11,160 --> 00:36:15,020
+Aldehydes و الـ Ketones؟ أكتر كلمة حكيناها إذا
+
+409
+00:36:15,020 --> 00:36:21,840
+بترجعوا للمحاضرات المصورة إن تفاعلهم الأساسي تفاعل
+
+410
+00:36:21,840 --> 00:36:23,480
+addition
+
+411
+00:36:25,770 --> 00:36:31,150
+كله بيضيف و ال O بتصير OH الان في chapter عشرة
+
+412
+00:36:31,150 --> 00:36:34,270
+بينا ناخد اللي هم ال C double bond O التانية
+
+413
+00:36:34,270 --> 00:36:37,670
+الكربوني ال compounds التانية اللي هي الأحماض و
+
+414
+00:36:37,670 --> 00:36:44,310
+مشتقاتها و هتلاحظوا ان هدولة كلهم هنستعمل برضه
+
+415
+00:36:44,310 --> 00:36:47,150
+فيهم كلمة واحدة لكن في هذه الحالة الكلمة
+
+416
+00:36:47,150 --> 00:36:48,070
+substitution
+
+417
+00:36:52,290 --> 00:36:56,830
+هذه مبادئ أساسية في الـ Organic Chemistry يعني
+
+418
+00:36:56,830 --> 00:37:00,910
+إنتوا لو بدكوا تدخلوا عندى مقابل التوظيف بدكوا
+
+419
+00:37:00,910 --> 00:37:05,170
+تشتغلوا أنا مابجيش أجيبلكوا ورقة أو أقول عبّولي
+
+420
+00:37:05,170 --> 00:37:10,970
+أربع خمس صفحات لأ، المفروض إنه عندي خمسين طالبة كل
+
+421
+00:37:10,970 --> 00:37:14,170
+طالبة بدأ تيجي لمدة دقيقتين وأعرف مين فيهم اللي
+
+422
+00:37:14,170 --> 00:37:18,270
+بتفهم كيميا ومين اللي مابتعرفش كيميا باجي بسألكوا
+
+423
+00:37:18,270 --> 00:37:21,850
+أسئلة عامة إيش التفاعل الأساسي للالكينز؟
+
+424
+00:37:25,330 --> 00:37:29,250
+free radical substitution وإن كانوا بشكل عام inert
+
+425
+00:37:29,250 --> 00:37:35,210
+ايش التفاعل الأساسي للالكينز مثلا؟ أي addition؟
+
+426
+00:37:35,210 --> 00:37:38,210
+Electrophilic لازم اللي بتضيف يكون موجة، ايش
+
+427
+00:37:38,210 --> 00:37:43,220
+التفاعل الأساسي للالكالهالايدز؟substitution when
+
+428
+00:37:43,220 --> 00:37:46,840
+eucleophilic؟ إيش التفاعل الأساسي للألديهيدس
+
+429
+00:37:46,840 --> 00:37:50,580
+والكيتونز؟ addition when eucleophile؟ لأنه هذه
+
+430
+00:37:50,580 --> 00:37:56,480
+موجبة، الآن إيش التفاعل الأساسي للأحماض ومشتقاتها؟
+
+431
+00:37:56,480 --> 00:38:00,160
+الـ eucleophilic substitution، هتلاحظوا أنه في كل
+
+432
+00:38:00,160 --> 00:38:03,600
+المحاضرتين، تلاتة الجايات، بس هنتكلم substitution,
+
+433
+00:38:03,740 --> 00:38:05,680
+substitution, substitution، واضح؟
+
+434
+00:38:19,180 --> 00:38:26,400
+الان كيف بنسمي الأحباب الحامض من ناحية المبدأ هو
+
+435
+00:38:26,400 --> 00:38:32,100
+مثل ال cane هو مثل ال cane و هذا ال cane في طرفه
+
+436
+00:38:32,940 --> 00:38:38,220
+COOH طالما أنه المجموعة الحامض بتيجي على الطرف إذا
+
+437
+00:38:38,220 --> 00:38:43,760
+بلزمش نعطيها رقم طب لما بنسمي بنشوف إيش الألكان
+
+438
+00:38:43,760 --> 00:38:49,380
+مثلا هكسين صار في طرفه acid بنضيف في النهاية oic
+
+439
+00:38:49,380 --> 00:38:52,740
+acid فمن الهكسين شو الحامض اللي بيطلع عندى؟
+
+440
+00:38:52,740 --> 00:39:00,040
+hexanoic acid من البروبين بروبانوك acid من
+
+441
+00:39:00,040 --> 00:39:00,740
+البيوتين
+
+442
+00:39:06,270 --> 00:39:14,110
+مثانوك أسد من الاثانethanoic acid إذا تسمى الأحماض
+
+443
+00:39:14,110 --> 00:39:19,650
+بإضافة النهاية oic acid بنشيل ال E اللي في أخر
+
+444
+00:39:19,650 --> 00:39:24,290
+الألكان oic acid فلو مثلا بدي أشوف هذا المركب طبعا
+
+445
+00:39:24,290 --> 00:39:27,690
+ببدأ أعد من ال carbon تبعت الحامض يعني هاي عندي
+
+446
+00:39:27,690 --> 00:39:33,170
+واحد اتنين تلاتة أربعة خمسة ستة وهذا حامل على ذرة
+
+447
+00:39:33,170 --> 00:39:37,230
+تلاتة مجموعة مثل هذه المثل معناها متصلة من هنا
+
+448
+00:39:38,630 --> 00:39:41,930
+دائما اللي بتكون بين قوسين معنى ذلك هي متصلة
+
+449
+00:39:41,930 --> 00:39:45,990
+برابطة ليست جزء من السلسلة اللي مكتوبة بين قوسين
+
+450
+00:39:45,990 --> 00:39:50,490
+شو معناها انه متصلة برابطة يعني هذه CH3 لما تكون
+
+451
+00:39:50,490 --> 00:39:54,490
+بين قوسين يعني معناها موجودة هنا الآن هذا لما كله
+
+452
+00:39:54,490 --> 00:40:01,110
+بدأ أسمي شو بدأ أسمي one two three على موقع three
+
+453
+00:40:01,110 --> 00:40:09,580
+حامل مثل three مثل hexanoic acid three مثلHexanoic
+
+454
+00:40:09,580 --> 00:40:14,760
+acid واضح؟
+
+455
+00:40:14,760 --> 00:40:20,660
+وطبعا جد ما تتعقد الأمور بإمكاننا أننا نستمر في
+
+456
+00:40:20,660 --> 00:40:26,060
+التسمية و هناخد أمثلة كتير لكن خلينا نتعرض للأحماض
+
+457
+00:40:26,060 --> 00:40:31,040
+من أبسط حامض و نطلع قولنا أبسط حامض اللي فيه كام
+
+458
+00:40:31,040 --> 00:40:39,000
+كربونا؟ واحدة شو بدنا نسميه احنا؟ميثانوك أسد الآن
+
+459
+00:40:39,000 --> 00:40:45,420
+ال IUPAC name تبعه مثانوك أسد ال formic acid اللي
+
+460
+00:40:45,420 --> 00:40:50,160
+هو عبارة عن common name كويس انتم ممتاز حافظينه و
+
+461
+00:40:50,160 --> 00:40:53,740
+عارفين انه formic acid لكن ال formic acid اسم
+
+462
+00:40:53,740 --> 00:41:02,000
+الشهرة واضح بس اسمه بال IUPAC مثانوك أسد بال
+
+463
+00:41:02,000 --> 00:41:10,720
+common الإنجليزيformic acid بالعربي حمض
+
+464
+00:41:10,720 --> 00:41:16,540
+الفورميك إسم تاني مين تتذكر إيش اسمه التاني
+
+465
+00:41:16,540 --> 00:41:26,040
+بالعربي حمض الفورميك حمض النمليك لأن هذا من النمل
+
+466
+00:41:26,040 --> 00:41:30,600
+حمض النمليك من النمل بالالماني
+
+467
+00:41:32,720 --> 00:41:36,720
+amaisin zörey amaisin يعني نمل و zörey يعني حمض
+
+468
+00:41:36,720 --> 00:41:41,380
+حمض النمل الألمان زي ما احنا بنسميه حمض النمليك هم
+
+469
+00:41:41,380 --> 00:41:49,360
+برضه بيسموه حمض النمل واضح؟ أه لأنه
+
+470
+00:41:49,360 --> 00:41:53,480
+أصله من وين ال source تبعه من ال ants ال ants اللي
+
+471
+00:41:53,480 --> 00:41:59,060
+هي النمل طب ليش سموه formic لأنه باللاتيني النمل
+
+472
+00:41:59,060 --> 00:42:05,480
+formicaلاحظوا الاصل اللاتيني و ال formica اللي هي
+
+473
+00:42:05,480 --> 00:42:10,700
+اسم النمل باللاتيني الآن الحامض اللي من Carbontane
+
+474
+00:42:10,700 --> 00:42:19,100
+اللي هو Acetic Acid بال Common حمض الخل بالعربي،
+
+475
+00:42:19,100 --> 00:42:23,340
+مظبوط ولا لأ؟ Essigzeure بالالماني بال Ayurvedic
+
+476
+00:42:23,340 --> 00:42:27,900
+Ethanoic Acid و أصله من ال vinegar ال vinegar اللي
+
+477
+00:42:27,900 --> 00:42:34,870
+هوالخلق الآن الحمض اللي من تلت كربونات أصله من
+
+478
+00:42:34,870 --> 00:42:41,130
+الحليب أصله من الحليب بيسموه إبروبيونك أسد
+
+479
+00:42:41,130 --> 00:42:48,250
+إبروبيونك يعني اللي هو ال common name تبعه ال
+
+480
+00:42:48,250 --> 00:42:56,090
+أيوبك إبروبانوك انتبه الفرق بين الكلمتينفي الايوبك
+
+481
+00:42:56,090 --> 00:43:02,810
+بروبانويك، بالكمون بروبيونيك، بس أصله من وين؟ من
+
+482
+00:43:02,810 --> 00:43:08,470
+الحليب، من الملش، عشان ذلك الألمان شو بيسموه؟ ملش
+
+483
+00:43:08,470 --> 00:43:14,910
+زيري، حمض الحليب، حمض الحليب على أصله، أه الأربع
+
+484
+00:43:14,910 --> 00:43:20,930
+كربونات أصله من إيش؟ من الزبدة، شكله إحنا هنهوله
+
+485
+00:43:20,930 --> 00:43:28,650
+لمطبخبيقولوا عنه البوترزايري حمض الزبدة او بيوتيرك
+
+486
+00:43:28,650 --> 00:43:32,790
+لاحظوا كيف بيوتيرك بالواو هذا الاسم common name بس
+
+487
+00:43:32,790 --> 00:43:44,190
+ال أيوبك بيوتانويك الخامسة
+
+488
+00:43:44,190 --> 00:43:50,210
+بنتانويك الاسم تبعه بال common valeric إذا مال
+
+489
+00:43:50,210 --> 00:43:57,170
+عليكم الستةهكسانوك بيسموه كبروك من ال goods اللي
+
+490
+00:43:57,170 --> 00:44:04,910
+هي الغنم او المعز السابعة هبتانوك بيسموه انانفك
+
+491
+00:44:04,910 --> 00:44:08,850
+بال common name التمانية أكتانوك بيسموه كابريليك
+
+492
+00:44:08,850 --> 00:44:13,150
+التسعة نونانوك بيسموه بيلارغونك العشرة ديكانوك
+
+493
+00:44:13,150 --> 00:44:17,340
+بيسموه كابريكطبعا انتوا هتقولوا مطلوب مننا نحفظ كل
+
+494
+00:44:17,340 --> 00:44:22,140
+هالاسماء؟ لأ لكن انتبهوا معاه وانتوا بتقرأوا
+
+495
+00:44:22,140 --> 00:44:26,080
+وانتوا بتدرسوا في المستقبل بيكون في بالكوا ان كل
+
+496
+00:44:26,080 --> 00:44:31,080
+الأحماض هدولة اللي اللهم نظام سهل في التسميهانة
+
+497
+00:44:31,080 --> 00:44:35,620
+سهولة نظام ال أيوبك يعني لو قلتلكوا سامول ال أيوبك
+
+498
+00:44:35,620 --> 00:44:40,350
+من واحد لعشرةبتسموه بسهولة مثانوك اثانوك بروبانوك
+
+499
+00:44:40,350 --> 00:44:45,050
+بيوتانوك متانوك لحد كانوك ماعندكم مشكلة لكن الكمون
+
+500
+00:44:45,050 --> 00:44:49,790
+يلهم أصل تاريخي اللي من الغنم واللي من الحليب
+
+501
+00:44:49,790 --> 00:44:54,890
+واللي من الخل واللي من النمل واللي .. واضح؟ لكن في
+
+502
+00:44:54,890 --> 00:44:58,410
+أي لحظة من اللحظات بتحتاجوا أنتم تتذكروا هذه
+
+503
+00:44:58,410 --> 00:45:02,530
+الشغلات تتذكروا أن في عندكم جدول للأحماض وأن كل
+
+504
+00:45:02,530 --> 00:45:09,410
+حامض زي ما إله اسم أيوبك إله اسمكومن لو في يوم من
+
+505
+00:45:09,410 --> 00:45:14,790
+الأيام لزمكم بتكونوا عارفينه ..وبهيك بننهي اليوم
+
+506
+00:45:14,790 --> 00:45:21,810
+وإن شاء الله للكلام بقية .. للكلام بقية ..
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..50f5118d4268fc55b8e1f09859176c5228485e76
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2572, "start": 8.74, "end": 25.72, "text": "اليوم بنكمل الجزء الأخير ان شاء الله في الموضوع ال الدي هايتس والكيتونز وممكن ننتقل للفصل اللي بعده اللي هو الأحماض الكربوكسيلية أخر شغلة اتكلمنا عنها المرة الماضية", "tokens": [6027, 1829, 20498, 44945, 24793, 1211, 25724, 11622, 38207, 16247, 9778, 13546, 16472, 13412, 16606, 21984, 8978, 9673, 2407, 11242, 45367, 2423, 2423, 16254, 8032, 995, 36081, 3794, 16070, 4117, 36081, 11536, 11622, 4032, 2304, 43020, 8717, 29399, 4587, 1211, 24976, 5172, 36520, 13672, 1829, 39182, 3224, 13672, 1829, 31439, 16247, 35571, 46958, 33251, 25513, 2407, 4117, 3794, 26895, 10632, 5551, 34740, 13412, 17082, 37977, 1975, 2655, 4117, 19528, 8315, 18871, 11296, 9673, 25720, 9673, 46958, 10632], "avg_logprob": -0.15334535867739946, "compression_ratio": 1.75, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 8.74, "end": 9.64, "word": "اليوم", "probability": 0.9274088541666666}, {"start": 9.64, "end": 10.54, "word": " 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هذا ال resonance هو اللي بيقدر ال stability لل ايون السالب وبيقدر ان ال alpha هيدروجين يمكن ان تفقد الان هناخد تطبيقات على الاستفادة من هذه الفكرة", "tokens": [495, 266, 719, 44945, 39648, 18871, 3224, 2423, 7649, 12610, 36081, 1975, 8315, 1829, 11536, 37495, 22653, 3714, 43020, 7251, 30544, 3714, 35571, 12610, 15844, 33251, 16758, 11536, 3714, 43020, 7251, 30544, 3714, 35571, 12610, 15844, 2423, 9169, 23758, 2423, 30944, 31439, 13672, 1829, 4724, 1829, 28543, 2288, 2423, 11826, 24976, 1975, 1829, 11536, 21136, 6027, 3555, 4032, 21292, 28543, 2288, 16472, 2423, 8961, 8032, 25708, 2288, 29245, 9957, 7251, 43020, 16472, 6055, 5172, 28543, 2423, 7649, 8032, 1863, 47283, 3215, 6055, 9566, 21292, 4587, 9307, 15844, 42963, 14851, 5172, 18513, 3660, 9154, 29538, 27188, 4117, 25720], "avg_logprob": -0.26004462978061366, "compression_ratio": 1.92018779342723, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 43.32, "end": 44.14, "word": "resonance", "probability": 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"probability": 0.9314778645833334}, {"start": 1153.95, "end": 1154.05, "word": " ..", "probability": 0.72509765625}, {"start": 1154.05, "end": 1154.29, "word": " و", "probability": 0.912109375}, {"start": 1154.29, "end": 1154.47, "word": " لما", "probability": 0.934326171875}, {"start": 1154.47, "end": 1154.95, "word": " يتفاعل", "probability": 0.9580078125}, {"start": 1154.95, "end": 1155.15, "word": " مع", "probability": 0.99462890625}, {"start": 1155.15, "end": 1155.63, "word": " نفسه", "probability": 0.9978841145833334}, {"start": 1155.63, "end": 1155.67, "word": " ..", "probability": 0.55810546875}, {"start": 1155.67, "end": 1156.09, "word": " الناتج", "probability": 0.845703125}, {"start": 1156.09, "end": 1156.49, "word": " النهائي", "probability": 0.9891357421875}, {"start": 1156.49, "end": 1156.53, "word": " ..", "probability": 0.87890625}, {"start": 1156.53, "end": 1156.69, "word": " كم", "probability": 0.849853515625}, {"start": 1156.69, "end": 1157.11, "word": " يطلع", "probability": 0.79119873046875}, {"start": 1157.11, "end": 1157.73, "word": " فيه؟", "probability": 0.9501953125}, {"start": 1157.73, "end": 1158.13, "word": " واحد", "probability": 0.89208984375}, {"start": 1158.13, "end": 1158.15, "word": " ..", "probability": 0.9638671875}, {"start": 1158.15, "end": 1158.35, "word": " اتنين", "probability": 0.92431640625}, {"start": 1158.35, "end": 1158.41, "word": " ..", "probability": 0.9921875}, {"start": 1158.41, "end": 1158.73, "word": " تلاتة", "probability": 0.966552734375}, {"start": 1158.73, "end": 1158.79, "word": " ..", "probability": 0.99365234375}, {"start": 1158.79, "end": 1159.11, "word": " أربعة", "probability": 0.88232421875}, {"start": 1159.11, "end": 1159.17, "word": " ..", "probability": 0.99072265625}, {"start": 1159.17, "end": 1159.57, "word": " خمسة", "probability": 0.895263671875}, {"start": 1159.57, "end": 1159.57, "word": " ..", "probability": 0.9931640625}, {"start": 1159.57, "end": 1159.87, "word": " ستة", "probability": 0.9462890625}, {"start": 1159.87, "end": 1159.93, "word": " ..", "probability": 0.98828125}, {"start": 1159.93, "end": 1160.21, "word": " سبعة", "probability": 0.9391276041666666}, {"start": 1160.21, "end": 1160.29, "word": " ..", "probability": 0.97412109375}, {"start": 1160.29, "end": 1160.49, "word": " تمام", "probability": 0.3817138671875}, {"start": 1160.49, "end": 1160.73, "word": " ..", "probability": 0.70458984375}, {"start": 1160.73, "end": 1160.95, "word": " إذا", "probability": 0.6640625}, {"start": 1160.95, "end": 1161.13, "word": " هو", "probability": 0.9677734375}, {"start": 1161.13, "end": 1161.63, "word": " كرر", "probability": 0.9332682291666666}, {"start": 1161.63, "end": 1162.19, "word": " نفسه", "probability": 0.9983723958333334}, {"start": 1162.19, "end": 1162.63, "word": " بشكل", "probability": 0.9501953125}, {"start": 1162.63, "end": 1162.79, "word": " أو", "probability": 0.92041015625}, {"start": 1162.79, "end": 1163.41, "word": " باخر", "probability": 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"word": "واضح؟", "probability": 0.805908203125}, {"start": 1164.54, "end": 1165.28, "word": " بينما", "probability": 0.942138671875}, {"start": 1165.28, "end": 1166.04, "word": " الـ", "probability": 0.5926513671875}, {"start": 1166.04, "end": 1166.36, "word": " mixed", "probability": 0.3095703125}, {"start": 1166.36, "end": 1167.08, "word": " aldol", "probability": 0.73583984375}, {"start": 1167.08, "end": 1167.58, "word": " أنا", "probability": 0.47509765625}, {"start": 1167.58, "end": 1168.02, "word": " باخد", "probability": 0.9392903645833334}, {"start": 1168.02, "end": 1168.8, "word": " الديهيد", "probability": 0.6973876953125}, {"start": 1168.8, "end": 1169.76, "word": " مايتفعلش", "probability": 0.8529296875}, {"start": 1169.76, "end": 1170.0, "word": " مع", "probability": 0.9794921875}, {"start": 1170.0, "end": 1170.38, "word": " نفسه", "probability": 0.9933268229166666}, {"start": 1170.38, "end": 1170.8, "word": " يتفعل", "probability": 0.90869140625}, {"start": 1170.8, "end": 1170.98, "word": " مع", "probability": 0.9755859375}, {"start": 1170.98, "end": 1171.62, "word": " الديهيد", "probability": 0.962646484375}, {"start": 1171.62, "end": 1172.38, "word": " تاني", "probability": 0.9811197916666666}, {"start": 1172.38, "end": 1174.14, "word": " واضح؟", "probability": 0.7598876953125}, {"start": 1174.14, "end": 1174.78, "word": " فمثلا", "probability": 0.9456787109375}, {"start": 1174.78, "end": 1175.34, "word": " لو", "probability": 0.58154296875}, {"start": 1175.34, "end": 1175.9, "word": " أخدت", "probability": 0.9776611328125}, {"start": 1175.9, "end": 1176.08, "word": " ال", "probability": 0.91796875}, {"start": 1176.08, "end": 1176.4, "word": " benz", "probability": 0.59228515625}, {"start": 1176.4, "end": 1177.38, "word": " aldehyde", "probability": 0.8363037109375}, {"start": 1177.38, "end": 1177.74, "word": " و", "probability": 0.55810546875}, {"start": 1177.74, "end": 1180.08, "word": " الacetaldehyde", "probability": 0.83251953125}, {"start": 1180.08, "end": 1180.7, "word": " و", "probability": 0.865234375}, {"start": 1180.7, "end": 1181.28, "word": " فعلتم", "probability": 0.6790364583333334}, {"start": 1181.28, "end": 1181.52, "word": " مع", "probability": 0.8837890625}, {"start": 1181.52, "end": 1181.96, "word": " base", "probability": 0.33935546875}, {"start": 1181.96, "end": 1182.2, "word": " ال", "probability": 0.79248046875}, {"start": 1182.2, "end": 1182.5, "word": " benz", "probability": 0.93896484375}, {"start": 1182.5, "end": 1183.32, "word": " aldehyde", "probability": 0.9776611328125}, {"start": 1183.32, "end": 1184.08, "word": " بنسبة", "probability": 0.8430989583333334}, {"start": 1184.08, "end": 1184.72, "word": " واحد", "probability": 0.781982421875}], "temperature": 1.0}, {"id": 49, "seek": 121234, "start": 1185.87, "end": 1212.35, "text": "الـ Acetal Dehydrate بنسبة واحد الـ Base بنسبة واحد الان لاحظوا معاه الـ Base الداهيد مافيه Alpha Hydrogen مش هيعمل ايون الـ Acetal Dehydrate فيه Alpha Hydrogen فلما يكون بنسبة واحد لواحد هيعمل ايون وين الايون السالب هيصير؟ على الـ Alpha Carbon الان هذا الايون السالب", "tokens": [6027, 39184, 5097, 302, 304, 1346, 21591, 4404, 44945, 35457, 3660, 36764, 24401, 2423, 39184, 21054, 44945, 35457, 3660, 36764, 24401, 2423, 7649, 20193, 5016, 19913, 14407, 20449, 40294, 2423, 39184, 21054, 2423, 28259, 3224, 25708, 19446, 41185, 3224, 20588, 24231, 7747, 37893, 39896, 25957, 1211, 1975, 1829, 11536, 2423, 39184, 5097, 302, 304, 1346, 21591, 4404, 8978, 3224, 20588, 24231, 7747, 6156, 1211, 15042, 7251, 30544, 44945, 35457, 3660, 36764, 24401, 5296, 14407, 24401, 39896, 25957, 1211, 1975, 1829, 11536, 4032, 9957, 42963, 1829, 11536, 21136, 6027, 3555, 39896, 9381, 13546, 22807, 15844, 2423, 39184, 20588, 31453, 2423, 7649, 23758, 42963, 1829, 11536, 21136, 6027, 3555], "avg_logprob": -0.24334491140864514, "compression_ratio": 2.123076923076923, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1185.87, "end": 1186.29, "word": "الـ", 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"end": 1192.57, "word": " الـ", "probability": 0.84912109375}, {"start": 1192.57, "end": 1192.79, "word": " Base", "probability": 0.515625}, {"start": 1192.79, "end": 1193.25, "word": " الداهيد", "probability": 0.4482421875}, {"start": 1193.25, "end": 1193.63, "word": " مافيه", "probability": 0.7550455729166666}, {"start": 1193.63, "end": 1193.89, "word": " Alpha", "probability": 0.65576171875}, {"start": 1193.89, "end": 1194.67, "word": " Hydrogen", "probability": 0.760498046875}, {"start": 1194.67, "end": 1196.41, "word": " مش", "probability": 0.58740234375}, {"start": 1196.41, "end": 1196.79, "word": " هيعمل", "probability": 0.9002278645833334}, {"start": 1196.79, "end": 1197.13, "word": " ايون", "probability": 0.7724609375}, {"start": 1197.13, "end": 1197.91, "word": " الـ", "probability": 0.760986328125}, {"start": 1197.91, "end": 1198.53, "word": " Acetal", "probability": 0.93701171875}, {"start": 1198.53, "end": 1199.13, "word": " Dehydrate", "probability": 0.9482421875}, {"start": 1199.13, "end": 1200.55, "word": " فيه", "probability": 0.7900390625}, {"start": 1200.55, "end": 1200.79, "word": " Alpha", "probability": 0.97314453125}, {"start": 1200.79, "end": 1201.43, "word": " Hydrogen", "probability": 0.919189453125}, {"start": 1201.43, "end": 1202.01, "word": " فلما", "probability": 0.84326171875}, {"start": 1202.01, "end": 1202.27, "word": " يكون", "probability": 0.98779296875}, {"start": 1202.27, "end": 1202.77, "word": " بنسبة", "probability": 0.94482421875}, {"start": 1202.77, "end": 1203.07, "word": " واحد", "probability": 0.96923828125}, {"start": 1203.07, "end": 1203.69, "word": " لواحد", "probability": 0.8331705729166666}, {"start": 1203.69, "end": 1204.47, "word": " هيعمل", "probability": 0.9226888020833334}, {"start": 1204.47, "end": 1204.79, "word": " ايون", "probability": 0.9664713541666666}, {"start": 1204.79, "end": 1205.05, "word": " وين", "probability": 0.6024169921875}, {"start": 1205.05, "end": 1205.47, "word": " الايون", "probability": 0.8523763020833334}, {"start": 1205.47, "end": 1205.87, "word": " السالب", "probability": 0.8684895833333334}, {"start": 1205.87, "end": 1207.61, "word": " هيصير؟", "probability": 0.7298583984375}, {"start": 1207.61, "end": 1209.09, "word": " على", "probability": 0.779296875}, {"start": 1209.09, "end": 1209.31, "word": " الـ", "probability": 0.9013671875}, {"start": 1209.31, "end": 1209.57, "word": " Alpha", "probability": 0.88134765625}, {"start": 1209.57, "end": 1210.21, "word": " Carbon", "probability": 0.8974609375}, {"start": 1210.21, "end": 1210.97, "word": " الان", "probability": 0.706787109375}, {"start": 1210.97, "end": 1211.29, "word": " هذا", "probability": 0.955078125}, {"start": 1211.29, "end": 1211.69, "word": " الايون", "probability": 0.9803059895833334}, {"start": 1211.69, "end": 1212.35, "word": " السالب", "probability": 0.9851888020833334}], "temperature": 1.0}, {"id": 50, "seek": 123693, "start": 1221.55, "end": 1236.93, "text": "واضح؟ فهي ناتج الألدل، هي ناتج الألدل، هي الجزء، الجزء الأحمر الديهايد والجزء الأسود", "tokens": [2407, 46958, 5016, 22807, 6156, 3224, 1829, 8717, 9307, 7435, 16247, 1211, 3215, 1211, 12399, 39896, 8717, 9307, 7435, 16247, 1211, 3215, 1211, 12399, 39896, 25724, 11622, 38207, 12399, 25724, 11622, 38207, 16247, 5016, 29973, 2423, 16254, 11296, 25708, 16070, 7435, 11622, 38207, 16247, 3794, 23328], "avg_logprob": -0.24035903811454773, "compression_ratio": 1.7816091954022988, "no_speech_prob": 0.0, "words": [{"start": 1221.5499999999997, "end": 1222.9499999999998, "word": "واضح؟", "probability": 0.81329345703125}, {"start": 1222.9499999999998, "end": 1224.35, "word": " فهي", "probability": 0.7373046875}, {"start": 1224.35, "end": 1225.15, "word": " ناتج", "probability": 0.9816080729166666}, {"start": 1225.15, "end": 1226.05, "word": " الألدل،", "probability": 0.6098388671875}, {"start": 1226.05, "end": 1226.53, "word": " هي", "probability": 0.42333984375}, {"start": 1226.53, "end": 1226.97, "word": " ناتج", 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اللي شو اسمه؟ cinnamaldehyde هذا ال aldehyde مشهور cinnamaldehyde cinnamaldehyde من أيه جاي؟", "tokens": [6027, 6027, 16254, 3224, 25708, 16712, 7649, 1829, 1975, 8315, 16490, 1211, 9566, 2655, 732, 819, 16798, 68, 3495, 14792, 1975, 8315, 16490, 1211, 9566, 2655, 732, 819, 16798, 68, 3495, 14792, 20666, 2304, 8315, 35457, 3660, 23758, 8978, 13412, 2407, 10632, 6055, 3794, 9778, 9957, 4724, 3794, 1829, 9566, 4724, 5172, 28543, 13931, 9154, 34105, 4032, 13931, 9154, 34105, 4724, 40228, 9566, 1829, 8315, 3834, 6086, 4724, 40228, 9566, 1829, 8315, 2423, 16798, 68, 3495, 1479, 13672, 1829, 13412, 2407, 24525, 2304, 3224, 22807, 6539, 5378, 304, 1479, 3495, 1479, 23758, 2423, 16798, 68, 3495, 1479, 37893, 3224, 13063, 6539, 5378, 304, 1479, 3495, 1479, 6539, 5378, 304, 1479, 3495, 1479, 9154, 36632, 3224, 10874, 47302, 22807], "avg_logprob": -0.18684349240375167, "compression_ratio": 1.9121951219512194, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1237.95, "end": 1238.65, 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الجرفة .. الجرفة .. هذا aldehyde الجرفة", "tokens": [9307, 8848, 37983, 14407, 20449, 40294, 17178, 16798, 68, 3495, 1479, 31439, 16798, 68, 3495, 1479, 4386, 2423, 22969, 4386, 22969, 4386, 3714, 43500, 25894, 24793, 9122, 19528, 3660, 22969, 22807, 11933, 1829, 8592, 39896, 22807, 25724, 28480, 3660, 4386, 25724, 28480, 3660, 4386, 23758, 16798, 68, 3495, 1479, 25724, 28480, 3660], "avg_logprob": -0.2945165071847304, "compression_ratio": 1.5114503816793894, "no_speech_prob": 0.0, "words": [{"start": 1267.01, "end": 1267.69, "word": "اتذكروا", "probability": 0.88427734375}, {"start": 1267.69, "end": 1268.11, "word": " معاه", "probability": 0.868408203125}, {"start": 1268.11, "end": 1271.31, "word": " cinema", "probability": 0.1761474609375}, {"start": 1271.31, "end": 1271.93, "word": " aldehyde", "probability": 0.7144775390625}, {"start": 1271.93, "end": 1272.09, "word": " هو", "probability": 0.8232421875}, {"start": 1272.09, "end": 1273.21, "word": " aldehyde", "probability": 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"ماخصش ال resonance هنا خليني أشوف غيرك، اتفضلي الربع بس، هتاخد .. الربع بينك سيمتوم لين؟ طمون هيجي يعمل هنا و طمون هنا و برضه هيطلع عندك خليط و هتطلعيلي كمان تمان مراكبات لأنه هيضل أشياء مش متفاعلة لأ لأ البس بس حرام عليكم", "tokens": [15042, 9778, 9381, 8592, 2423, 30944, 34105, 16490, 1211, 9957, 1829, 5551, 8592, 38688, 32771, 13546, 4117, 12399, 1975, 2655, 5172, 11242, 20292, 34892, 3555, 3615, 4724, 3794, 12399, 8032, 2655, 47283, 3215, 4386, 34892, 3555, 3615, 49374, 4117, 8608, 32640, 2655, 20498, 5296, 9957, 22807, 23032, 2304, 11536, 39896, 7435, 1829, 7251, 25957, 1211, 34105, 4032, 23032, 2304, 11536, 34105, 4032, 4724, 43042, 3224, 8032, 1829, 9566, 1211, 3615, 43242, 4117, 16490, 20292, 9566, 4032, 8032, 2655, 9566, 1211, 3615, 1829, 20292, 9122, 2304, 7649, 46811, 7649, 3714, 23557, 4117, 3555, 9307, 5296, 33456, 3224, 39896, 11242, 1211, 5551, 8592, 1829, 16606, 37893, 44650, 5172, 995, 30241, 3660, 5296, 10721, 5296, 10721, 29739, 3794, 4724, 3794, 11331, 2288, 10943, 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"text": "مثانوك أسد من الاثان", "tokens": [2304, 12984, 7649, 2407, 4117, 5551, 3794, 3215, 9154, 2423, 5718, 104, 7649], "avg_logprob": -0.43750000851494925, "compression_ratio": 0.8809523809523809, "no_speech_prob": 0.0, "words": [{"start": 2346.27, "end": 2347.67, "word": "مثانوك", "probability": 0.6972900390625}, {"start": 2347.67, "end": 2348.37, "word": " أسد", "probability": 0.7818196614583334}, {"start": 2348.37, "end": 2348.81, "word": " من", "probability": 0.9033203125}, {"start": 2348.81, "end": 2349.61, "word": " الاثان", "probability": 0.6878662109375}], "temperature": 1.0}, {"id": 95, "seek": 237723, "start": 2350.57, "end": 2377.23, "text": "ethanoic acid إذا تسمى الأحماض بإضافة النهاية oic acid بنشيل ال E اللي في أخر الألكان oic acid فلو مثلا بدي أشوف هذا المركب طبعا ببدأ أعد من ال carbon تبعت الحامض يعني هاي عندي واحد اتنين تلاتة أربعة خمسة ستة وهذا حامل على ذرة تلاتة مجموعة مثل هذه المثل معناها متصلة من هنا", "tokens": [3293, 3730, 299, 8258, 11933, 15730, 6055, 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c7aae5f5878d7fd89e5923f14419652d40861972
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/DhyTIfWzD5U_raw.srt
@@ -0,0 +1,2040 @@
+1
+00:00:08,740 --> 00:00:13,200
+اليوم بنكمل الجزء الأخير ان شاء الله في الموضوع ال
+
+2
+00:00:13,200 --> 00:00:18,900
+الدي هايتس والكيتونز وممكن ننتقل للفصل اللي بعده
+
+3
+00:00:18,900 --> 00:00:24,660
+اللي هو الأحماض الكربوكسيلية أخر شغلة اتكلمنا عنها
+
+4
+00:00:24,660 --> 00:00:29,590
+المرة الماضيةكانت ال acidity of alpha hydrogen
+
+5
+00:00:29,590 --> 00:00:32,650
+يمكن
+
+6
+00:00:32,650 --> 00:00:38,890
+ان تفقد في وجود قاعدة قوية السبب انه يمكن ان تفقد
+
+7
+00:00:38,890 --> 00:00:44,140
+ان الايون السالب اللى بتكون بامكانه يعملresonance
+
+8
+00:00:44,140 --> 00:00:48,260
+بنقول عنه الانوليت انايون يعني ممكن يكون محمول على
+
+9
+00:00:48,260 --> 00:00:52,460
+الكابون ممكن يكون محمول على ال oxygen هذا ال
+
+10
+00:00:52,460 --> 00:00:55,520
+resonance هو اللي بيقدر ال stability لل ايون
+
+11
+00:00:55,520 --> 00:01:01,260
+السالب وبيقدر ان ال alpha هيدروجين يمكن ان تفقد
+
+12
+00:01:01,260 --> 00:01:06,070
+الان هناخد تطبيقات على الاستفادة من هذه الفكرةيعني
+
+13
+00:01:06,070 --> 00:01:10,010
+احنا أخدناها كفكرة أن الـ Alpha Hydrogen يمكن أن
+
+14
+00:01:10,010 --> 00:01:13,810
+تفقد، الآن في تطبيقات في استفادة من هذا الكلام
+
+15
+00:01:13,810 --> 00:01:19,630
+واضح؟ من التطبيقات على سبيل المثال لو أنا أخدت
+
+16
+00:01:19,630 --> 00:01:24,230
+مراكب زي الـ Cyclohexanone واطلعت هل الـ
+
+17
+00:01:24,230 --> 00:01:29,010
+Cyclohexanone في Alpha Hydrogenالحقيقة بلاقي انه
+
+18
+00:01:29,010 --> 00:01:33,110
+في عدد كبير من الـ α هيدروجينز يعني هذه الكاربون
+
+19
+00:01:33,110 --> 00:01:37,510
+هذه الكاربون ألفة والهيدروجينز اللي عليها ألفة اذا
+
+20
+00:01:37,510 --> 00:01:42,210
+انا في اندي two هيدروجينز وبنفس الوقت على الجهة
+
+21
+00:01:42,210 --> 00:01:45,290
+التالية في اندي كمان two هيدروجينز اذا هذه
+
+22
+00:01:45,290 --> 00:01:52,210
+الكاربون محاطة باربع ألف هيدروجينز الان لو حطيتها
+
+23
+00:01:52,210 --> 00:01:58,170
+في base ال base ممكن تسحب منها ال Hو اتكون ايونات
+
+24
+00:01:58,170 --> 00:02:02,190
+سالبة اللى بيصير انه احنا لو حطناها في ال base مع
+
+25
+00:02:02,190 --> 00:02:05,970
+solvent هذا ال solvent بنقول عنه اديوتيريتد
+
+26
+00:02:05,970 --> 00:02:14,390
+ميثانول الميثانول العادى مار علينا CH3OH هذا بدل
+
+27
+00:02:14,390 --> 00:02:19,390
+ال H حطينا نظير ال H اللى هو الديوتيريا فبنقول عنه
+
+28
+00:02:19,390 --> 00:02:24,890
+اديوتيريتدميثانول يعني ميثانول قبدل في الهيدروجين
+
+29
+00:02:24,890 --> 00:02:29,850
+بنظيره اللي هو الديوتريان الان لاحظوا معنى هذا
+
+30
+00:02:29,850 --> 00:02:33,650
+حاطينه احنا بشكل كبير اللي بيصير في هذه الحالة ان
+
+31
+00:02:33,650 --> 00:02:38,010
+ال base بتسحب ال H التفاعل بشكل عكسي بيروح بده يحط
+
+32
+00:02:38,010 --> 00:02:42,410
+بدالها ايش بيحط بدالها D لان هنا مافيش H بال
+
+33
+00:02:42,410 --> 00:02:46,950
+solventبترد تاخد من الـ solvent D الكلام على مدى
+
+34
+00:02:46,950 --> 00:02:50,590
+طويل ممكن يتكرر مع القدش التاني مع القدش التالتة
+
+35
+00:02:50,590 --> 00:02:54,690
+مع القدش الرابعة لو أجينا للتفاعل هذا بعد ساعتين
+
+36
+00:02:54,690 --> 00:03:00,130
+تلاتة بنلاحظ أنه كل الهيدروجين ابدلت بديوتيريام
+
+37
+00:03:00,130 --> 00:03:04,870
+هذا بيسموه ايش الديوتيريام exchange يعني ابدال
+
+38
+00:03:04,870 --> 00:03:08,250
+الهيدروجين بديوتيريام الفكرة فيه ايش اللي خلى
+
+39
+00:03:08,250 --> 00:03:12,790
+الهيدروجين تنسحبأن ألف هيدروجين في وجود الbase
+
+40
+00:03:12,790 --> 00:03:17,150
+انسحبت عملة minus إجت لديوتريان مكانا، انسحبت عملة
+
+41
+00:03:17,150 --> 00:03:21,390
+minus إجت لديوتريان مكانا، كمان مرة، كمان مرة، ففي
+
+42
+00:03:21,390 --> 00:03:27,610
+النهاية بلاحظ أن كل الألف هيدروجين عملوا متحولوا
+
+43
+00:03:27,610 --> 00:03:34,050
+إلى ديوتريانكذلك الحال لو انا مثلا اخدت هذا
+
+44
+00:03:34,050 --> 00:03:39,970
+المُركّب لبيوتنال هى فيه كربونيل جروب وهى الالف
+
+45
+00:03:39,970 --> 00:03:45,390
+هيدروجينز هدولة اللي ماخدين لون أزرق لو حطيتهم في
+
+46
+00:03:45,390 --> 00:03:52,300
+ال water لفترة طويلةفي وجود ديوتريام كمان إضافة
+
+47
+00:03:52,300 --> 00:03:56,400
+بلاحظ ان كل الهيدروجين بتحولوا الى ايش الى
+
+48
+00:03:56,400 --> 00:04:00,120
+ديوتريام ليش هذا الكلب بتم لأن الهيدروجين هدولة
+
+49
+00:04:00,120 --> 00:04:06,200
+قابلات للفقد بيفقدوا و بيجي مكانهم الديوتريام
+
+50
+00:04:06,200 --> 00:04:10,400
+بيفقدوا و بيجي مكانهم الديوتريام هذا بيسمي احنا
+
+51
+00:04:10,400 --> 00:04:15,020
+alpha hydrogen exchange يعني تبديل ال alpha
+
+52
+00:04:15,020 --> 00:04:20,110
+hydrogenبالـ deuterium هذا أحد الأمثلة على
+
+53
+00:04:20,110 --> 00:04:25,810
+الاستفادة من ال acidity of alpha hydrogen المثال
+
+54
+00:04:25,810 --> 00:04:32,010
+التاني .. المثال التاني تفاعل شهير عادة التفاعلات
+
+55
+00:04:32,010 --> 00:04:34,870
+الشهيرة بيسموها name reactions يعني من كتر ما هي
+
+56
+00:04:34,870 --> 00:04:41,470
+مشهورة منسوبة لاسم محددممكن الاسم يكون اسم شخص و
+
+57
+00:04:41,470 --> 00:04:45,470
+ممكن يكون اشي تاني، واضح؟ هذا ال name reaction او
+
+58
+00:04:45,470 --> 00:04:51,070
+التفاعل الشهير اسمه ال doll condensation بتعرف ال
+
+59
+00:04:51,070 --> 00:04:55,070
+condensation تكثيف .. التكثيف ان اجمع جزيئين مع
+
+60
+00:04:55,070 --> 00:04:59,850
+بعض .. التكثيف ان اجمع جزيئين مع بعض طبعا باجمعهم
+
+61
+00:04:59,850 --> 00:05:05,030
+ممكن يفقد جزيئ صغير في هذه الحالةأيش الفكرة في
+
+62
+00:05:05,030 --> 00:05:11,990
+aldol condensation الفكرة لو أنا أخدت الديهايد او
+
+63
+00:05:11,990 --> 00:05:17,670
+كيتون وهذا الديهايد او الكيتون فعلته مع base مع
+
+64
+00:05:17,670 --> 00:05:23,570
+قاعدة بنسبة 2 إلى 1 ممكن الديهايد اللي ناخده يكون
+
+65
+00:05:23,570 --> 00:05:28,730
+ال acetaldehyde اتطلع عليه هذا acetaldehyde باخده
+
+66
+00:05:28,730 --> 00:05:35,010
+بأي نسبة ال acetaldehydeبنسبة اتنين بفعله مع قاعدة
+
+67
+00:05:35,010 --> 00:05:39,830
+القاعدة بتكون بنسبة واحد فانتوا انتبهوا معايا لما
+
+68
+00:05:39,830 --> 00:05:46,910
+يكون عندى اتنين acetaldehyde اتنين من هذا المركب
+
+69
+00:05:46,910 --> 00:05:50,510
+ال HCWOCH3
+
+70
+00:05:50,510 --> 00:05:56,580
+ونفعلهم مع واحد من ال baseالـ base ايش بتاخد عندنا
+
+71
+00:05:56,580 --> 00:06:01,940
+دائما؟ الـ alpha هيدروجين طيب لو افترضت مثلا عندى
+
+72
+00:06:01,940 --> 00:06:05,460
+مية جزء من الالديهيد بكون انفعله مع كام جزء من ال
+
+73
+00:06:05,460 --> 00:06:10,220
+base؟ مع خمسين هذا الكلام بيقدر الى نص كمية
+
+74
+00:06:10,220 --> 00:06:14,420
+الالديهيد بتصير عبارة عن ايون بتسحب منها
+
+75
+00:06:14,420 --> 00:06:20,770
+الهيدروجين والنص التانى بيضل زى ما هوالان لاحظوا
+
+76
+00:06:20,770 --> 00:06:25,230
+معي بزام صار نص ايونه هذا ما زال زي ما هو الايون
+
+77
+00:06:25,230 --> 00:06:30,810
+عبارة عن الـ eucleophile والتفاعل الأساسي لل
+
+78
+00:06:30,810 --> 00:06:34,490
+الديهيدز والكيتونز الـ eucleophilic addition فهذا
+
+79
+00:06:34,490 --> 00:06:37,930
+الايون اللي اتكوّن بيجي مضيف هنا و ال O بتصير
+
+80
+00:06:43,190 --> 00:06:48,450
+والـ O- بتاخد ميّه في النهاية بيصير عندك OH
+
+81
+00:06:53,620 --> 00:06:56,820
+الـ nucleophilic addition اللي احنا حكيناها انه
+
+82
+00:06:56,820 --> 00:07:02,800
+هذا ال nucleophile اتفاعل هنا و ال O صارت OH هذا
+
+83
+00:07:02,800 --> 00:07:07,960
+المركب نفسه لو رسمته كطريقة تانية بتلاحظوا انه
+
+84
+00:07:07,960 --> 00:07:12,800
+بيحتوي على مجموعتين وظيفيتين مجموعة ال aldehyde و
+
+85
+00:07:12,800 --> 00:07:19,030
+مجموعة ال alcohol واضح؟بيحتوي على مجموعة ال
+
+86
+00:07:19,030 --> 00:07:23,250
+الديهايد ومجموعة الالكهول وعشان هيك احنا بنسمي
+
+87
+00:07:23,250 --> 00:07:29,170
+المركب aldol condensation الام هذه كلمة aldol جاية
+
+88
+00:07:29,170 --> 00:07:38,130
+من ان الناتج في الديهايد وفي الالكهول aldol واضح
+
+89
+00:07:38,130 --> 00:07:43,930
+هلأ aldol مش اسم بني ادمالدول نسبة لمكونات
+
+90
+00:07:43,930 --> 00:07:49,150
+المُركّب الناتج اللي هو بيحتوي على الديهايد
+
+91
+00:07:49,150 --> 00:07:53,010
+وبيحتوي على ال alcohol ال alcohol all و ال
+
+92
+00:07:53,010 --> 00:07:57,710
+الديهايد بنعطي ال فبصير ال دول condensation طبعا
+
+93
+00:07:57,710 --> 00:08:01,670
+إذا احنا بدنا نتطلع على هذا المُركّب اللي هو ناتج
+
+94
+00:08:01,670 --> 00:08:09,490
+ال دول بنلاحظ أن الناتجهو عبارة عن beta-hydroxy
+
+95
+00:08:09,490 --> 00:08:13,130
+-aldehyde يعني لما أجي أقول هاي الديهايد واحد
+
+96
+00:08:13,130 --> 00:08:16,490
+اتنين تلاتة أربعة هاي موقع Alpha بالنسبة له و هاي
+
+97
+00:08:16,490 --> 00:08:22,410
+موقع Beta إيش بيكون الناتج لتفاعل الدول بيتا لا مش
+
+98
+00:08:22,410 --> 00:08:31,770
+اتنين مش اتنين beta-hydroxy-aldehydeفلما بدنا نقول
+
+99
+00:08:31,770 --> 00:08:35,930
+تفاعل ألدول، شو ناتج اللي بيعطينا بيتا هيدروكس
+
+100
+00:08:35,930 --> 00:08:43,550
+الألدهايد؟ ليش مش اتنين؟ لأن إعطاء ألفة وبيتا
+
+101
+00:08:43,550 --> 00:08:47,430
+بيبدأ بعد مجموعة الكربون، يعني بنقول هي الكربون،
+
+102
+00:08:47,430 --> 00:08:51,190
+بنقول اللي بعدها الأولى ألفة، هاد بيتا، واضح؟
+
+103
+00:08:51,190 --> 00:08:56,150
+بينما الترقيم بيبدأ من نفس مجموعة الكربونهذه واحدة
+
+104
+00:08:56,150 --> 00:08:59,890
+وهذه اتنين وهذه تلاتة عشان ايه هذا المركب لو بدأ
+
+105
+00:08:59,890 --> 00:09:07,370
+أسميه بال Iopaque هو عبارة عن three hydroxy طبعا
+
+106
+00:09:07,370 --> 00:09:14,410
+اربع كربونات بيوتنال لأ برضه مش one من اللي حكت
+
+107
+00:09:14,410 --> 00:09:20,510
+one؟ من اللي حكت one؟ ماتاعترفش ليش لأن احنا قولنا
+
+108
+00:09:20,510 --> 00:09:23,250
+ال aldehyde دائما على الطرف بس تعملوش one
+
+109
+00:09:39,160 --> 00:09:43,500
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+110
+00:09:43,500 --> 00:09:51,900
+الهيدروكسي الهيدروكسي الهيدروكسي
+
+111
+00:09:51,900 --> 00:09:53,300
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+112
+00:09:53,300 --> 00:09:53,300
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+113
+00:09:53,300 --> 00:09:53,300
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+114
+00:09:53,300 --> 00:09:53,300
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+115
+00:09:53,300 --> 00:09:53,300
+الهيدروكسي الهيدروكسي الهيدروكسي الهيدروكسي
+
+116
+00:09:53,300 --> 00:09:59,130
+الهيدروكسيشرط تفاعل الألدول اللي مابمشيش بدونه أن
+
+117
+00:09:59,130 --> 00:10:04,790
+يكون عنده ألديهيد أو كيتون فيه ألف هيدروجين كل
+
+118
+00:10:04,790 --> 00:10:08,550
+الفكرة معتمدة على وجود ألف هيدروجين نسحب منها
+
+119
+00:10:09,250 --> 00:10:13,610
+البروتون بمعنى مش كل ال الديهيدز اللى فى الدنيا
+
+120
+00:10:13,610 --> 00:10:18,530
+ولا كل ال ketones اللى فى الدنيا ممكن تعمل aldol
+
+121
+00:10:18,530 --> 00:10:23,290
+reaction ممكن أعطيكوا أمثلة مثلا لو أخدنا ال
+
+122
+00:10:23,290 --> 00:10:28,090
+formaldehyde C double bond O H H هذا فيه alpha
+
+123
+00:10:28,090 --> 00:10:28,730
+hydrogen
+
+124
+00:10:31,330 --> 00:10:34,790
+لاحظوا الـ α هيدروجين هي الهيدروجين على الكاربون
+
+125
+00:10:34,790 --> 00:10:38,030
+المجاورة للـ C double bond O هاي الـ C double bond
+
+126
+00:10:38,030 --> 00:10:41,830
+O كاربون مجاورة عليها الف هيدروجين بس هاد
+
+127
+00:10:41,830 --> 00:10:45,530
+الهيدروجين على نفس الكاربون لأ مش الف هيدروجين
+
+128
+00:10:45,530 --> 00:10:51,710
+عشان كده لو بتفعلوا مع باسبمشيش يعني لو بدي أجي
+
+129
+00:10:51,710 --> 00:10:56,070
+أسألكوا في الامتحان أنه formaldehydes undergo
+
+130
+00:10:56,070 --> 00:10:59,890
+aldol condensation in the presence of a base
+
+131
+00:10:59,890 --> 00:11:05,050
+الجواب لأ لأنه مافيش بالformaldehyde alpha
+
+132
+00:11:05,050 --> 00:11:09,010
+hydrogen طيب لو أخدنا ال bins aldehyde متذكرين ولا
+
+133
+00:11:09,010 --> 00:11:13,670
+لأ هل
+
+134
+00:11:13,670 --> 00:11:21,920
+هذا في alpha hydrogen طلع عليههذا الكربون لا يحمل
+
+135
+00:11:21,920 --> 00:11:25,340
+أي نوع من الهيدروجين هنا في عندكم تنسوش عندما نفصل
+
+136
+00:11:25,340 --> 00:11:30,600
+البنزين نضع الروابط ليس هنا أي نوع من الهيدروجين
+
+137
+00:11:30,600 --> 00:11:32,860
+هنا رابطتين او تلاتة او اربعة ليس هنا أي نوع من
+
+138
+00:11:32,860 --> 00:11:35,560
+الالفهيدرجين ولا هناك أي نوع من الالفهيدرجين
+
+139
+00:11:40,680 --> 00:11:44,320
+و الـ benz aldehyde ما بيصيرش عليهم aldol reaction
+
+140
+00:11:44,320 --> 00:11:48,860
+لأنه مافيش alpha hydrogen نحذفها في وجود ال base
+
+141
+00:11:48,860 --> 00:11:54,760
+شرط ال aldol reaction أنه يكون عنده aldehyde أو
+
+142
+00:11:54,760 --> 00:11:58,260
+كيتون و يكون ال aldehyde أو الكيتون بيحتوي على
+
+143
+00:11:58,260 --> 00:12:05,660
+alpha hydrogen واضح؟
+
+144
+00:12:05,660 --> 00:12:08,160
+تالتاني على ال aldol reaction
+
+145
+00:12:11,450 --> 00:12:17,390
+لو أخدنا هذا ال الديهيد الكبير هذا ال الديهيد
+
+146
+00:12:17,390 --> 00:12:22,390
+شايفينه؟ واحد، اتنين، تلاتة، بيوتنال، two مثل
+
+147
+00:12:22,390 --> 00:12:26,310
+بيوتنال أنا اللي بيهمني منه كله أنه يكون بيحتوي
+
+148
+00:12:26,310 --> 00:12:30,310
+على إيش؟ Alpha Hydrogen هاي الكربون الأساسي، هاي
+
+149
+00:12:30,310 --> 00:12:34,090
+الكربون اللي جنبها الكربون اللي جنبها حملة
+
+150
+00:12:34,090 --> 00:12:39,150
+Hydrogen في عليها Alpha Hydrogenإذا في وجود base
+
+151
+00:12:39,150 --> 00:12:44,730
+.. إذا في وجود base زي مثلا ال sodium hydroxide
+
+152
+00:12:44,730 --> 00:12:50,750
+ممكن إنه يعمل condensation مع نفسه يعطينا الناتج
+
+153
+00:12:50,750 --> 00:12:56,110
+اللي موجود هناك طبعا هنا بصراحة إنه كيف نكتب
+
+154
+00:12:56,110 --> 00:13:02,050
+الناتج إذا أنتوا ماتدربتوش في البيت بالجلم لرصاص
+
+155
+00:13:02,050 --> 00:13:06,730
+كيف تعملوا هذا التفاعل مش هيكون سهل عليكم تكتبوا
+
+156
+00:13:06,730 --> 00:13:10,900
+الناتجطيب، الأن إيش أسهل؟ أسهل طريقة إنه أي
+
+157
+00:13:10,900 --> 00:13:15,740
+الديهايد أو كيتون موجود عندى أرسمه مرتين جانب بعض
+
+158
+00:13:15,740 --> 00:13:22,540
+مش هيوم أرسمها هو عادة موجود بنسبة إيش؟ 2 إلى 1
+
+159
+00:13:22,540 --> 00:13:26,300
+إذا أنا بدي أعيد الرسمة تبعته بدي أعيد الرسمة
+
+160
+00:13:26,300 --> 00:13:30,060
+تبعته زي ما هي بالظبط بدي أحط C double bond OH
+
+161
+00:13:30,060 --> 00:13:32,980
+وهنا CH
+
+162
+00:13:34,940 --> 00:13:42,080
+CH3 CH3 هاي صار عندى جزيئين الان هدول الجزيئين
+
+163
+00:13:42,080 --> 00:13:49,020
+واحد منهم بيفقد البروتون وبيعمل ايون سالب هاي هدا
+
+164
+00:13:49,020 --> 00:13:57,700
+فقد البروتون وعمل ايون سالب والتانى بيضل زى ما هو
+
+165
+00:13:57,700 --> 00:14:02,240
+الان بعد هيك شو اللى بده يصير الايون السالب بده
+
+166
+00:14:02,240 --> 00:14:08,850
+يخجمعلى الـ C double bond O تبع المُركّب التاني
+
+167
+00:14:08,850 --> 00:14:15,290
+هيهاجمها واحد بدأ تصير O minus وتصير في نهاية OH
+
+168
+00:14:15,290 --> 00:14:20,730
+عشان ذلك لما تيجوا تتطلعوا هنا بتلاحظوا أنه عملية
+
+169
+00:14:20,730 --> 00:14:25,290
+الاتصال تمت من أي كاربون اللي كانت حاملة Alpha
+
+170
+00:14:25,290 --> 00:14:28,910
+Hydrogen يعني لو حطينا هدول اللي لونهم أحمر في
+
+171
+00:14:28,910 --> 00:14:31,930
+صندوق هما عبارة عن
+
+172
+00:14:35,410 --> 00:14:42,630
+هذا الجزء واضح هيانا اتكون الايون السالب شايفينه
+
+173
+00:14:42,630 --> 00:14:51,590
+هاجم و أعطاني ال OH هيانا
+
+174
+00:14:51,590 --> 00:14:58,870
+اتكون الايون السالب و هاجم و أعطاني ال OH طبعا
+
+175
+00:15:00,970 --> 00:15:05,250
+نفس الشيء .. نفس الشيء لو كنا بدنا نعمل تفاعل
+
+176
+00:15:05,250 --> 00:15:12,170
+للأسيتون مع نفسه في وجود base هاي أسيتون سيبنا من
+
+177
+00:15:12,170 --> 00:15:15,550
+هذه الأشياء اللي بتتكون بشكل بسيط خلينا بالأسيتون
+
+178
+00:15:15,550 --> 00:15:20,030
+الان لو قولنا لأي واحدة فيكوا اعمليلنا الاسيتون شو
+
+179
+00:15:20,030 --> 00:15:25,270
+الخطوة اللي لازم تعملها أول إشي بدا ترسمه زي ما هو
+
+180
+00:15:25,270 --> 00:15:28,290
+مرة تانية CH3
+
+181
+00:15:29,510 --> 00:15:35,650
+C double bond O CH3 بعد هيك على أحد الجهات ممكن
+
+182
+00:15:35,650 --> 00:15:42,450
+تتكون تصير هذه CH2- في وجود ال base عملة الآيون
+
+183
+00:15:42,450 --> 00:15:50,690
+السالب الآيون السالب وين بيهاجم؟ و
+
+184
+00:15:50,690 --> 00:15:56,650
+هذه بتصير واجهة إذا بتطلعوا هنا هتلاحظوا إن هاي
+
+185
+00:15:56,650 --> 00:16:05,170
+الجزء الأحمر هو هذاCH3C CH3 وحملة OH و هذا
+
+186
+00:16:05,170 --> 00:16:11,230
+الاسيتون هاجم من هذه واضح زي ما بحكيلكوا انه هذا
+
+187
+00:16:11,230 --> 00:16:15,790
+الكلام مش سهل مش سهل انكوا تجاوبوا عليه في
+
+188
+00:16:15,790 --> 00:16:20,930
+الامتحان اذا ماقعدتوش عمله و كتابتوا بقلم لرصاص و
+
+189
+00:16:20,930 --> 00:16:24,630
+اتدربتوا عليه كيف تكتبوا لقده ل product هي عندكوا
+
+190
+00:16:24,630 --> 00:16:29,910
+مثال علىالـ Acetaldehyde هاي مثال تاني كان على
+
+191
+00:16:29,910 --> 00:16:35,870
+مثلا تومثيلبروبانال هاي مثال تالت على الاسيتون
+
+192
+00:16:35,870 --> 00:16:41,530
+ممكن أي واحدة تعمللنا مثال على مثلا ال .. البيوت
+
+193
+00:16:41,530 --> 00:16:46,430
+.. البروبانال CH3
+
+194
+00:16:46,430 --> 00:16:53,710
+CH2 C double bond OH ممكن نجيبلكوا هذا السؤالبدنا
+
+195
+00:16:53,710 --> 00:16:59,090
+نعمل لبرو بانال ادو ال product الفعله بنسبة اتنين
+
+196
+00:16:59,090 --> 00:17:03,570
+الى واحد مع ال base بتعملوه فى البيت بتجربوه
+
+197
+00:17:03,570 --> 00:17:09,650
+براحتكوا لحد ما يظبط معاكم بس دائما ال hydrogen
+
+198
+00:17:09,650 --> 00:17:16,910
+اللى بده يصير لها abstract اللى بده تفقد اي
+
+199
+00:17:16,910 --> 00:17:22,220
+hydrogen ال alpha hydrogenوالهجوم بيكون على ال c
+
+200
+00:17:22,220 --> 00:17:29,600
+double bond o تبعت الجزاء التانى جربوا هذا المركب
+
+201
+00:17:29,600 --> 00:17:35,880
+اعمله هدوء فى البيت كمزيد من التدريب
+
+202
+00:17:44,860 --> 00:17:52,000
+أخر شغلة ممكن ناخد مثال على إيش بنسميه mixed aldol
+
+203
+00:17:52,000 --> 00:17:57,360
+condensation إيش يعني mixed aldol؟ يعني ما أستعملش
+
+204
+00:17:57,360 --> 00:18:02,960
+ال aldehyde يتفاعل مع نفسه ممكن أستعمل aldehyde
+
+205
+00:18:02,960 --> 00:18:12,340
+معين يعمل ال ion ويهاجم على aldehyde تانيواضح؟ لأ
+
+206
+00:18:12,340 --> 00:18:16,640
+احنا ماكناش نعمل زيك، احنا كنا .. انتبهوا معايا،
+
+207
+00:18:16,640 --> 00:18:21,280
+بده .. بده هدوء في فهم النقطة، احنا كنا بنحط ال
+
+208
+00:18:21,280 --> 00:18:27,300
+الديهايد بنسبة 2 و ال base بنسبة 1، الان نص كمية
+
+209
+00:18:27,300 --> 00:18:32,860
+ال الديهايد بتصير ايون و بتهاجمعلى النص التاني
+
+210
+00:18:32,860 --> 00:18:37,520
+اللي ما صارش ايون الان انا ممكن اعمل بطريقة تانية
+
+211
+00:18:37,520 --> 00:18:42,000
+ان اخلط two aldehydes يعني كل الأمثلة السابقة اللي
+
+212
+00:18:42,000 --> 00:18:46,200
+شفتوها كان aldehyde مع نفسه يعني لو كان عندكوا تلت
+
+213
+00:18:46,200 --> 00:18:50,300
+كربونات في ال aldehyde فالنتج النهائي كده يكون
+
+214
+00:18:50,300 --> 00:18:58,190
+عندكم؟ ستة اتنين يتحدوا مع بعضخلّينا نرجع نعلمكم
+
+215
+00:18:58,190 --> 00:19:02,450
+العدل من أول و جديد هنا كام carbon عندكم؟ تنتين ..
+
+216
+00:19:02,450 --> 00:19:06,290
+و لما يتفاعل مع نفسه .. ف .. okay الناتج النهائي
+
+217
+00:19:06,290 --> 00:19:10,750
+.. كام carbon أطلع فيه؟ أربعة .. واضح؟ هنا كام
+
+218
+00:19:10,750 --> 00:19:14,290
+carbon عندكم؟ واحد .. اتنين .. تلاتة .. أربعة .. و
+
+219
+00:19:14,290 --> 00:19:17,110
+لما يتفاعل مع نفسه .. الناتج النهائي .. كم يطلع
+
+220
+00:19:17,110 --> 00:19:19,570
+فيه؟ واحد .. اتنين .. تلاتة .. أربعة .. خمسة ..
+
+221
+00:19:19,570 --> 00:19:22,790
+ستة .. سبعة .. تمام .. إذا هو كرر نفسه بشكل أو
+
+222
+00:19:22,790 --> 00:19:28,800
+باخرواضح؟ بينما الـ mixed aldol أنا باخد الديهيد
+
+223
+00:19:28,800 --> 00:19:34,780
+مايتفعلش مع نفسه يتفعل مع الديهيد تاني واضح؟ فمثلا
+
+224
+00:19:34,780 --> 00:19:41,280
+لو أخدت ال benz aldehyde و الacetaldehyde و فعلتم
+
+225
+00:19:41,280 --> 00:19:46,790
+مع base ال benz aldehyde بنسبة واحدالـ Acetal
+
+226
+00:19:46,790 --> 00:19:51,030
+Dehydrate بنسبة واحد الـ Base بنسبة واحد الان
+
+227
+00:19:51,030 --> 00:19:54,670
+لاحظوا معاه الـ Base الداهيد مافيه Alpha Hydrogen
+
+228
+00:19:54,670 --> 00:20:00,790
+مش هيعمل ايون الـ Acetal Dehydrate فيه Alpha
+
+229
+00:20:00,790 --> 00:20:05,050
+Hydrogen فلما يكون بنسبة واحد لواحد هيعمل ايون وين
+
+230
+00:20:05,050 --> 00:20:11,290
+الايون السالب هيصير؟ على الـ Alpha Carbon الان هذا
+
+231
+00:20:11,290 --> 00:20:12,350
+الايون السالب
+
+232
+00:20:21,550 --> 00:20:31,690
+واضح؟ فهي ناتج الألدل، هي ناتج الألدل، هي
+
+233
+00:20:31,690 --> 00:20:36,930
+الجزء، الجزء الأحمر الديهايد والجزء الأسود
+
+234
+00:20:37,950 --> 00:20:42,530
+الالديهيد التاني انا خلطت two different aldehydes
+
+235
+00:20:42,530 --> 00:20:48,090
+انا خلطت two different aldehydes بالمناسبة هذا في
+
+236
+00:20:48,090 --> 00:20:52,750
+شوية تسخين بسيط بفقد OH من هنا و OH من هنا بيعطينا
+
+237
+00:20:52,750 --> 00:20:57,690
+double bond بيعطينا ال aldehyde اللي شو اسمه؟
+
+238
+00:20:57,690 --> 00:21:01,150
+cinnamaldehyde هذا ال aldehyde مشهور
+
+239
+00:21:01,150 --> 00:21:04,390
+cinnamaldehyde cinnamaldehyde من أيه جاي؟
+
+240
+00:21:07,010 --> 00:21:11,310
+اتذكروا معاه cinema
+
+241
+00:21:11,310 --> 00:21:17,710
+aldehyde هو aldehyde .. ال cinnamon .. cinnamon ..
+
+242
+00:21:17,710 --> 00:21:24,950
+مرت عليكم كلمة cinnamon؟ إيش هي؟ الجرفة .. الجرفة
+
+243
+00:21:24,950 --> 00:21:30,420
+.. هذا aldehyde الجرفةيعني ممكن ان حضره في المختبر
+
+244
+00:21:30,420 --> 00:21:37,120
+و يطلق نفس الريحة اللي
+
+245
+00:21:37,120 --> 00:21:43,300
+بيمنع ان
+
+246
+00:21:43,300 --> 00:21:47,820
+انا حاطط هذا بنسبة واحد إلى واحد فحولت كل هذا ..
+
+247
+00:21:47,820 --> 00:21:53,390
+حولت كل هذا إلى ايون سالبيعني التفاعل مع ال base
+
+248
+00:21:53,390 --> 00:21:57,550
+أقوى الآن السؤال اللي بتسألوا زملتكم .. السؤال
+
+249
+00:21:57,550 --> 00:22:02,670
+اللي بتسألوا زملتكم إيه وجهها لو أنا حطيت .. لو
+
+250
+00:22:02,670 --> 00:22:07,350
+أنا حطيت two aldehydes .. لو حطيت two aldehydes
+
+251
+00:22:07,350 --> 00:22:12,730
+والتانين فيهم alpha hydrogen وروحت انفعلهم مع base
+
+252
+00:22:12,730 --> 00:22:18,590
+يعني مثلا حطيت هذا ال acetaldehyde اللي عندك CH3
+
+253
+00:22:23,710 --> 00:22:33,290
+CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH3
+
+254
+00:22:33,290 --> 00:22:41,790
+CH3 CH2 CH3 CH3
+
+255
+00:22:41,790 --> 00:22:43,170
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+256
+00:22:43,170 --> 00:22:44,550
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+257
+00:22:44,550 --> 00:22:44,730
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+258
+00:22:44,730 --> 00:22:45,130
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+259
+00:22:45,130 --> 00:22:45,350
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+260
+00:22:45,350 --> 00:22:46,310
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+261
+00:22:46,310 --> 00:22:46,510
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+262
+00:22:46,510 --> 00:22:46,590
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+263
+00:22:48,660 --> 00:22:55,080
+الامور هنا كتير بتتعقد زي تماما إذا بتذكروا لما
+
+264
+00:22:55,080 --> 00:22:59,400
+كنا نخلط .. لما كنا نخلط two alcohols مع بعض عشان
+
+265
+00:22:59,400 --> 00:23:03,900
+نحضر unsymmetrical ether كام ناتج كان يطلع عنده؟
+
+266
+00:23:03,900 --> 00:23:09,940
+تلاتة هنا لو عملنا زي هيك في عندنا إمكانية أنه هنا
+
+267
+00:23:09,940 --> 00:23:17,690
+يتكون عندكأيون سالب يعني هذا تصير CH2- واتهاجم على
+
+268
+00:23:17,690 --> 00:23:21,490
+الجزء اللي منها ما اتفعلش وفي إمكانية نهانة كمان
+
+269
+00:23:21,490 --> 00:23:27,470
+يتكون عند أيون سالب يعني هذا تصير CH- واتهاجم على
+
+270
+00:23:27,470 --> 00:23:31,310
+نفسها وفي إمكانية هذه تهاجم على هذه وهذه تهاجم على
+
+271
+00:23:31,310 --> 00:23:35,570
+هذه إذا كام ناتج هان بدو يطلع عندكم؟اربع .. طبعا
+
+272
+00:23:35,570 --> 00:23:40,390
+جزء أساس .. انتبهوا معي .. جزء أساس من فهم مثل هذا
+
+273
+00:23:40,390 --> 00:23:44,610
+المثال أنه أنتوا تكونوا منتبهين أنه احنا بنفعلش
+
+274
+00:23:44,610 --> 00:23:49,950
+الجزيئات بنسبة واحد إلى واحد بمعنى بنفعلش جزء من
+
+275
+00:23:49,950 --> 00:23:54,830
+هذا وجزء من هذا وجزء من هذالو حد فيكو جاعت بتخيل
+
+276
+00:23:54,830 --> 00:23:58,930
+أنه أنا بس افعل جزء واحد من هذا وجزء من هذا وجزء
+
+277
+00:23:58,930 --> 00:24:02,390
+من هذا كان هيقول ال base أكيد يا بده تاخد بروتون
+
+278
+00:24:02,390 --> 00:24:06,630
+من هان يا من هان و بتفعل على التاني بس أنا حقيقة
+
+279
+00:24:06,630 --> 00:24:11,710
+لما بفعل بالوضع الطبيعي بفعل واحد mole لو بتقول
+
+280
+00:24:11,710 --> 00:24:15,590
+مثلا واحد mole او نص mole بلاش خليني اقول مليون
+
+281
+00:24:15,590 --> 00:24:21,110
+جزء اتخيلوا انا بده افعل مليون جزء من هذا مع مليون
+
+282
+00:24:21,110 --> 00:24:28,290
+من اللي هانمع مليون من الـ base خلّي ال base مثلا
+
+283
+00:24:28,290 --> 00:24:33,350
+تاخد نص مليون من هدولة تخلّيهم ايش؟ ايون سالب،
+
+284
+00:24:33,350 --> 00:24:37,210
+بمعنى ذلك، ضال عندكم نص مليون مش محولين لأيون
+
+285
+00:24:37,210 --> 00:24:42,470
+وخلّي ال base كمان تتحول من هدولة نصهم، نص مليون
+
+286
+00:24:42,470 --> 00:24:46,990
+صاروا ايون ونص؟ لأ، إذا مخلوط التفاعل في هذه
+
+287
+00:24:46,990 --> 00:24:51,140
+الحالة، شو هيصف فيه بالنهاية؟نص مليون من ال
+
+288
+00:24:51,140 --> 00:24:56,860
+الديهايد هذا و نص مليون من ال ايون و نص مليون من
+
+289
+00:24:56,860 --> 00:24:59,660
+ال الديهايد هذا و نص مليون من ال ايون و خلهم
+
+290
+00:24:59,660 --> 00:25:04,180
+يتفعلوا مع بعض كام ناتج بيطلع عندكم؟ أربع نواتج
+
+291
+00:25:04,180 --> 00:25:10,140
+هذا مع نفسه هذا مع نفسه هذا مع ال الديهايد اللي
+
+292
+00:25:10,140 --> 00:25:15,000
+هان هذا مع ال الديهايد اللي هان أربع نواتجعلى أي
+
+293
+00:25:15,000 --> 00:25:19,860
+حال عشان ما نضيعش وقت ونشجعكوا انه تفكروا فيهم
+
+294
+00:25:19,860 --> 00:25:27,080
+بشكل ممتاز اعملوهم homework الاربع نواتج المتوقعة
+
+295
+00:25:27,080 --> 00:25:31,140
+من هنا homework مرتب و سلموني المحاضرة الجاي هذا
+
+296
+00:25:31,140 --> 00:25:38,420
+اخر homework عليه ايش درجات اربع نواتج بدو يطلع
+
+297
+00:25:38,420 --> 00:25:43,500
+عندكم ورسموهم صحلازم عشان تعملوا هذا الكلام
+
+298
+00:25:43,500 --> 00:25:46,780
+تراجعوا الموضوع كله من الأول اتعودوا إيدكم ترسموا
+
+299
+00:25:46,780 --> 00:25:50,700
+الأمثلة كلها اللي أخدناها لحد ما تصلوا هنا في
+
+300
+00:25:50,700 --> 00:25:56,300
+النهاية بيطلع عندكم مثل هذا المثال أربع نواتج طبعا
+
+301
+00:25:56,300 --> 00:25:59,640
+هنا احنا اتريحنا ماطلعش إلا ناتج واحد لإن واحد
+
+302
+00:25:59,640 --> 00:26:04,080
+منهم في Alpha Hydrogen إتانفش في Alpha Hydrogen
+
+303
+00:26:04,080 --> 00:26:05,860
+واضح؟
+
+304
+00:26:07,550 --> 00:26:13,030
+طيب، الأن اتفقتوا معي كلكم أن المفروض يطلع أربع
+
+305
+00:26:13,030 --> 00:26:21,190
+نوات جهان؟ ولا لأ؟ هتعملهم في البيت؟ طيب، أخر سؤال
+
+306
+00:26:21,190 --> 00:26:26,490
+.. أخر سؤال ممكن نسأله؟ أخر سؤال ممكن نسأله؟
+
+307
+00:26:26,490 --> 00:26:32,610
+مستعدين أن نسأله؟ أه لأ، بديكوا تنتبهوا لإن اللي
+
+308
+00:26:32,610 --> 00:26:36,030
+بده يجاوبه هعطيه علامات، على طول هينزلوا على ..
+
+309
+00:26:37,180 --> 00:26:42,400
+هينزلوا على الرصيد تبعه لو بدي واحد محدد من
+
+310
+00:26:42,400 --> 00:26:47,280
+الأربعة يطلع انا قاعد بقولكوا اذا خلطتهم مع ال
+
+311
+00:26:47,280 --> 00:26:51,860
+base بنسبة واحد الى واحد الى واحد هيطلع عندى كام
+
+312
+00:26:51,860 --> 00:26:55,660
+ناتج اربع نواتج و هتكتبوهم بال homework و تسلمون
+
+313
+00:26:55,660 --> 00:27:03,960
+اياهم الان لو بدي ناتج محدد ممكن ..ممكن أرسملكوا
+
+314
+00:27:03,960 --> 00:27:09,340
+هذا الناتج المحدد اللي أنا بديها بمشي مثلا لو
+
+315
+00:27:09,340 --> 00:27:18,480
+قولنا بدنا هذا الناتج هذه
+
+316
+00:27:18,480 --> 00:27:25,700
+CH2 وهنا
+
+317
+00:27:25,700 --> 00:27:27,780
+حطينا C
+
+318
+00:27:37,380 --> 00:27:42,620
+CH3 بدي بس هذا الناتج حصريا يطلع عندى exclusive
+
+319
+00:27:42,620 --> 00:27:48,180
+بتعرف إيش أنا حصري بس هذا الناتج مايطلعوش أربعة
+
+320
+00:27:48,180 --> 00:27:52,280
+هذا أحد الأربعة بالمناسبة اللي كان هيطلعوا الآن
+
+321
+00:27:52,280 --> 00:27:58,140
+أنا بدي التفاعل بس يطلعلي هذا ولا شيء أغيره اتفضلى
+
+322
+00:27:58,140 --> 00:28:03,860
+هاي لا لا أبعد ولا خاصة green yard فيها المنطقة
+
+323
+00:28:08,810 --> 00:28:14,530
+مش هتظبط معاك، هيطلع خليط من الأربعة، هيطلع خليط
+
+324
+00:28:14,530 --> 00:28:19,710
+من الأربعة برضه طالما
+
+325
+00:28:19,710 --> 00:28:25,790
+مع بعض هيطلع خليط من الأربعة، أنا بدي واحد مية في
+
+326
+00:28:25,790 --> 00:28:30,990
+المية، بس يطلع عندى واحد فقط لغير، only one
+
+327
+00:28:30,990 --> 00:28:32,550
+product مش four products
+
+328
+00:28:37,450 --> 00:28:41,970
+ماخصش ال resonance هنا خليني أشوف غيرك، اتفضلي
+
+329
+00:28:41,970 --> 00:28:46,250
+الربع
+
+330
+00:28:46,250 --> 00:28:51,890
+بس، هتاخد .. الربع بينك سيمتوم لين؟ طمون هيجي يعمل
+
+331
+00:28:51,890 --> 00:28:57,230
+هنا و طمون هنا و برضه هيطلع عندك خليط و هتطلعيلي
+
+332
+00:28:57,230 --> 00:29:02,790
+كمان تمان مراكبات لأنه هيضل أشياء مش متفاعلة لأ لأ
+
+333
+00:29:02,790 --> 00:29:11,830
+البس بس حرام عليكممين كانت هناك بدأت تجاوب؟ لأ لأ
+
+334
+00:29:11,830 --> 00:29:14,870
+احنا .. انا في ال rearrangement، بعدي بعدي كتير عن
+
+335
+00:29:14,870 --> 00:29:18,610
+ال rearrangementلأ لأ بنضيف الشغلة و الله فكرة
+
+336
+00:29:18,610 --> 00:29:22,950
+بسيطة لأ انتوا لاحظوا بس أنا ليش بسألكوا هذا
+
+337
+00:29:22,950 --> 00:29:29,010
+الكلام حتى تشوفوا انه مرات ما بين .. ما بين الشغلة
+
+338
+00:29:29,010 --> 00:29:35,770
+الصعبة كتير و الشغلة السهلة أو ما بين المشكلة و
+
+339
+00:29:35,770 --> 00:29:44,910
+حلها فكرة بسيطة جدا جدا ما بين المشكلة و حلهافكرة
+
+340
+00:29:44,910 --> 00:29:50,370
+بسيطة جدا جدا يعني مش الاشي المعقد ولا الاشي اللي
+
+341
+00:29:50,370 --> 00:29:54,470
+بيغلب المشكلة بتنحل بسهولة كتير ان بدل ما يطلع
+
+342
+00:29:54,470 --> 00:30:01,610
+عندى أربع نواتج اطلع ايش ناتج واحد في حد بده يجاوب
+
+343
+00:30:01,610 --> 00:30:10,650
+ولا خلاص انطحين في السؤال اخر جاوب اتفضل ممتاز
+
+344
+00:30:10,650 --> 00:30:16,390
+هذا الكلام الصح اللي حكته زملتكنهتاخد .. شو اسمك؟
+
+345
+00:30:16,390 --> 00:30:20,950
+سمية .. سمية خفاجة .. اه .. سمية حكت كلام بسيط
+
+346
+00:30:20,950 --> 00:30:24,090
+احنا كانت المشكلة عندنا .. نكون .. نكون ماخدين
+
+347
+00:30:24,090 --> 00:30:27,770
+هدول الأزدهار .. تتخيلوا أنه في عندنا flask .. هي
+
+348
+00:30:27,770 --> 00:30:32,330
+flask .. حاطينهم كلهم .. حاطينهم كلهم مع بعض و
+
+349
+00:30:32,330 --> 00:30:37,970
+حاطين ال base معهم .. فال base بتتطلعبتلاقي من هذا
+
+350
+00:30:37,970 --> 00:30:42,990
+بتعمل منه ion بتلاقي من هذا بتعمل منه ion الكلام
+
+351
+00:30:42,990 --> 00:30:47,770
+اللي هي حكته انه احنا بعيدنا الله لجزاز كتير في
+
+352
+00:30:47,770 --> 00:30:54,110
+المختبر بدناش نستعمل flask واحد بنستعمل two flasks
+
+353
+00:30:54,110 --> 00:30:59,110
+خلينا نقول هي ال flask الأسود و بنحط فيه هذا
+
+354
+00:30:59,110 --> 00:31:01,870
+المركب CH3
+
+355
+00:31:03,390 --> 00:31:09,970
+CH2C double bond O H كويس و بنستعمل ال flask تاني
+
+356
+00:31:09,970 --> 00:31:15,610
+خلينا نقول عنه ال flask الأحمر و بنحط فيه المركب
+
+357
+00:31:15,610 --> 00:31:22,410
+هذا CH3C double bond O H لو افترضت مثلا عندي مليون
+
+358
+00:31:22,410 --> 00:31:29,670
+جزء من هذا و مليون من هذا باجي بحط ال base بس على
+
+359
+00:31:29,670 --> 00:31:34,200
+هذاهنا بحط ال base هذا بسيبه زي ما هو بحطش عليه
+
+360
+00:31:34,200 --> 00:31:38,920
+base الأن لما حطينا ال base بنسبة واحد إلى واحد كل
+
+361
+00:31:38,920 --> 00:31:45,000
+هذا صار عبارة عن ايش ايون سالب المليون جزء اللي
+
+362
+00:31:45,000 --> 00:31:49,800
+هنا كلهم صاروا ايونات سالبة وهذا كله ماجتش عليه
+
+363
+00:31:49,800 --> 00:31:55,780
+base دله زي ما هو بعدين بننزك هذا ال flask بنكبه
+
+364
+00:31:55,780 --> 00:32:01,700
+فوق هذابنكب الايون كل هذا ايون و كل هذا الديهايد
+
+365
+00:32:01,700 --> 00:32:04,720
+لما نمسك هذا ال flask و نكبه فوق هذا، شو التفاعل
+
+366
+00:32:04,720 --> 00:32:12,360
+بدي يصير؟ هيعطينا الناتج المحدد اللي أنا رسمته و
+
+367
+00:32:12,360 --> 00:32:18,280
+لو كنت بدي، الناتج التالع، بضيف ال base هان شوفتوا
+
+368
+00:32:18,280 --> 00:32:23,930
+قداش الفكرة؟ يعني كل الفرق تبعهافلسك ان انا ضفت
+
+369
+00:32:23,930 --> 00:32:30,130
+على واحد حولته بشكل كامل لل ايون بدون ما اعطي هذا
+
+370
+00:32:30,130 --> 00:32:33,050
+امكانيا ان يصبح ايون حاطه انا بفلسك تاني جاعت
+
+371
+00:32:33,050 --> 00:32:39,550
+باستنى وبعدين ضفت التانية فوق بعض بهيك بالطول
+
+372
+00:32:39,550 --> 00:32:44,610
+مراكب واحد لاحظوا جداش المشكلة خدوا مبدأ للحياة
+
+373
+00:32:44,610 --> 00:32:54,200
+جداش المشكلة ممكنتكون كبيرة جداش المشكلة ممكن تكون
+
+374
+00:32:54,200 --> 00:33:05,350
+كبيرة و جداش الحل تبعها ممكن يكونسهل او صغير جداش
+
+375
+00:33:05,350 --> 00:33:08,930
+المشكلة ممكن تكون كبيرة و جداش الحال تبعها ممكن
+
+376
+00:33:08,930 --> 00:33:15,030
+تكون سهل او صغير ممكن بعد ما نخلص المحاضرة نحكيلكم
+
+377
+00:33:15,030 --> 00:33:19,470
+على قصة دائما بيروها تبعون إدارة الأعمال في هذا
+
+378
+00:33:19,470 --> 00:33:27,470
+المجال كيف انه في مشكلة كبيرة و حالها ايش و حالها
+
+379
+00:33:28,310 --> 00:33:32,390
+بسيط، بعد ما نخلص المحاضرة، في آخر دقيقتين
+
+380
+00:33:32,390 --> 00:33:35,970
+بنحكيلكوا المشكلة كيف بتكون كبيرة و في الآخر
+
+381
+00:33:35,970 --> 00:33:43,130
+الحالة تبعها سهل أو بسيط خلصنا الشبطر بس ما خلصناش
+
+382
+00:33:43,130 --> 00:33:47,630
+المحاضرة لازم
+
+383
+00:33:47,630 --> 00:33:52,920
+دائما نبدأ في إيش؟في chapter جديد عشان نقول احنا
+
+384
+00:33:52,920 --> 00:33:58,320
+بديني بعشرة ومن السنة كمان إذا أنتم ما بتعرفوش أن
+
+385
+00:33:58,320 --> 00:34:03,580
+الإنسان يكون له word في قراءة القرآن يعني دائما
+
+386
+00:34:03,580 --> 00:34:09,600
+لما نيجي نسأله أنت وين واصل يقول أنا واصلللنقطة
+
+387
+00:34:09,600 --> 00:34:13,180
+الفلانية يعني يكون إله مكان واصل إله .. الأصل
+
+388
+00:34:13,180 --> 00:34:16,440
+الإنسان المسلم كل يوم بده يقرأ إيش؟ قرآن .. وكل
+
+389
+00:34:16,440 --> 00:34:20,260
+يوم .. لامد جزء .. ماحدش قال من العلماء جزء .. كل
+
+390
+00:34:20,260 --> 00:34:23,960
+يوم بده يقرأ قرآن .. و دائما قلبه معلق .. إن أنا
+
+391
+00:34:23,960 --> 00:34:26,760
+وصلت لهان .. أنا وصلت لهان .. أنا وصلت لهان .. طب
+
+392
+00:34:26,760 --> 00:34:29,820
+السؤال عاد .. لما بيخلص قراية القرآن .. شو بده
+
+393
+00:34:29,820 --> 00:34:37,170
+يعمله؟من السنة أنه بنفس الجلسة يبدأ من الأول وجديد
+
+394
+00:34:37,170 --> 00:34:41,630
+يقرأ الفاتحة وجزء صغير من البجرة عشان يقول أنا
+
+395
+00:34:41,630 --> 00:34:47,910
+واصل لنقطة الفلانية وبدأ أستمر .. بنفع .. بس مش
+
+396
+00:34:47,910 --> 00:34:52,330
+محبّذ .. احنا بنقول من السنة أنه مايختمش عند نهاية
+
+397
+00:34:52,330 --> 00:34:56,290
+المصحف ويسكر المصحف وخلاص .. لما تختموا القرآن ..
+
+398
+00:34:56,290 --> 00:35:02,050
+شو بدكوا تعمله؟بتكونوا تبدأوا تجيبوا الفاتحة و
+
+399
+00:35:02,050 --> 00:35:05,490
+أكام من آية من صورة البقرة عشان تكونوا انتوا دائما
+
+400
+00:35:05,490 --> 00:35:10,490
+القراءة عندكم إيش تكون متصلة و احنا نفس الاشي
+
+401
+00:35:10,490 --> 00:35:14,970
+بنفعل الآن ننهي chapter 9 لأ لازم ناخدلنا خمس
+
+402
+00:35:14,970 --> 00:35:20,250
+دقايق بعشرة الآن
+
+403
+00:35:20,250 --> 00:35:27,490
+خلينا في chapter 10 خمس دقائق مقدمةمقدمة كل دقيقة
+
+404
+00:35:27,490 --> 00:35:30,790
+وقت الناس لازم يستغلوا لما يكون عندكم ربع ساعة
+
+405
+00:35:30,790 --> 00:35:36,810
+الربع ساعة بتنجزوا فيها فكرة و بتنجزوا فيها عمل لا
+
+406
+00:35:36,810 --> 00:35:43,310
+تستهيلوا بالوقت chapter عشر اكمال لفصل التاسع لكن
+
+407
+00:35:43,310 --> 00:35:47,830
+بيحكي عن ايش اللي هي ال carboxylic acids and their
+
+408
+00:35:47,830 --> 00:35:52,210
+derivatives بتذكروا احنا حكينا ان السيطة بال bond
+
+409
+00:35:52,210 --> 00:35:58,380
+O عبارة عنالنوعين، اللي هي الـ Carbonyl group الـ
+
+410
+00:35:58,380 --> 00:36:06,400
+Aldehydes و الـ Ketones أخدناهم كمجموعة واحدة و
+
+411
+00:36:06,400 --> 00:36:11,160
+اللي بيميزهم كلمة واحدة شو الكلمة اللي بتميز الـ
+
+412
+00:36:11,160 --> 00:36:15,020
+Aldehydes و الـ Ketones؟ أكتر كلمة حكيناها إذا
+
+413
+00:36:15,020 --> 00:36:21,840
+بترجعوا للمحاضرات المصورة إن تفاعلهم الأساسي تفاعل
+
+414
+00:36:21,840 --> 00:36:23,480
+addition
+
+415
+00:36:25,770 --> 00:36:31,150
+كله بيضيف و ال O بتصير OH الان في chapter عشرة
+
+416
+00:36:31,150 --> 00:36:34,270
+بينا ناخد اللي هم ال C double bond O التانية
+
+417
+00:36:34,270 --> 00:36:37,670
+الكربوني ال compounds التانية اللي هي الأحماض و
+
+418
+00:36:37,670 --> 00:36:44,310
+مشتقاتها و هتلاحظوا ان هدولة كلهم هنستعمل برضه
+
+419
+00:36:44,310 --> 00:36:47,150
+فيهم كلمة واحدة لكن في هذه الحالة الكلمة
+
+420
+00:36:47,150 --> 00:36:48,070
+substitution
+
+421
+00:36:52,290 --> 00:36:56,830
+هذه مبادئ أساسية في الـ Organic Chemistry يعني
+
+422
+00:36:56,830 --> 00:37:00,910
+إنتوا لو بدكوا تدخلوا عندى مقابل التوظيف بدكوا
+
+423
+00:37:00,910 --> 00:37:05,170
+تشتغلوا أنا مابجيش أجيبلكوا ورقة أو أقول عبّولي
+
+424
+00:37:05,170 --> 00:37:10,970
+أربع خمس صفحات لأ، المفروض إنه عندي خمسين طالبة كل
+
+425
+00:37:10,970 --> 00:37:14,170
+طالبة بدأ تيجي لمدة دقيقتين وأعرف مين فيهم اللي
+
+426
+00:37:14,170 --> 00:37:18,270
+بتفهم كيميا ومين اللي مابتعرفش كيميا باجي بسألكوا
+
+427
+00:37:18,270 --> 00:37:21,850
+أسئلة عامة إيش التفاعل الأساسي للالكينز؟
+
+428
+00:37:25,330 --> 00:37:29,250
+free radical substitution وإن كانوا بشكل عام inert
+
+429
+00:37:29,250 --> 00:37:35,210
+ايش التفاعل الأساسي للالكينز مثلا؟ أي addition؟
+
+430
+00:37:35,210 --> 00:37:38,210
+Electrophilic لازم اللي بتضيف يكون موجة، ايش
+
+431
+00:37:38,210 --> 00:37:43,220
+التفاعل الأساسي للالكالهالايدز؟substitution when
+
+432
+00:37:43,220 --> 00:37:46,840
+eucleophilic؟ إيش التفاعل الأساسي للألديهيدس
+
+433
+00:37:46,840 --> 00:37:50,580
+والكيتونز؟ addition when eucleophile؟ لأنه هذه
+
+434
+00:37:50,580 --> 00:37:56,480
+موجبة، الآن إيش التفاعل الأساسي للأحماض ومشتقاتها؟
+
+435
+00:37:56,480 --> 00:38:00,160
+الـ eucleophilic substitution، هتلاحظوا أنه في كل
+
+436
+00:38:00,160 --> 00:38:03,600
+المحاضرتين، تلاتة الجايات، بس هنتكلم substitution,
+
+437
+00:38:03,740 --> 00:38:05,680
+substitution, substitution، واضح؟
+
+438
+00:38:19,180 --> 00:38:26,400
+الان كيف بنسمي الأحباب الحامض من ناحية المبدأ هو
+
+439
+00:38:26,400 --> 00:38:32,100
+مثل ال cane هو مثل ال cane و هذا ال cane في طرفه
+
+440
+00:38:32,940 --> 00:38:38,220
+COOH طالما أنه المجموعة الحامض بتيجي على الطرف إذا
+
+441
+00:38:38,220 --> 00:38:43,760
+بلزمش نعطيها رقم طب لما بنسمي بنشوف إيش الألكان
+
+442
+00:38:43,760 --> 00:38:49,380
+مثلا هكسين صار في طرفه acid بنضيف في النهاية oic
+
+443
+00:38:49,380 --> 00:38:52,740
+acid فمن الهكسين شو الحامض اللي بيطلع عندى؟
+
+444
+00:38:52,740 --> 00:39:00,040
+hexanoic acid من البروبين بروبانوك acid من
+
+445
+00:39:00,040 --> 00:39:00,740
+البيوتين
+
+446
+00:39:06,270 --> 00:39:14,110
+مثانوك أسد من الاثانethanoic acid إذا تسمى الأحماض
+
+447
+00:39:14,110 --> 00:39:19,650
+بإضافة النهاية oic acid بنشيل ال E اللي في أخر
+
+448
+00:39:19,650 --> 00:39:24,290
+الألكان oic acid فلو مثلا بدي أشوف هذا المركب طبعا
+
+449
+00:39:24,290 --> 00:39:27,690
+ببدأ أعد من ال carbon تبعت الحامض يعني هاي عندي
+
+450
+00:39:27,690 --> 00:39:33,170
+واحد اتنين تلاتة أربعة خمسة ستة وهذا حامل على ذرة
+
+451
+00:39:33,170 --> 00:39:37,230
+تلاتة مجموعة مثل هذه المثل معناها متصلة من هنا
+
+452
+00:39:38,630 --> 00:39:41,930
+دائما اللي بتكون بين قوسين معنى ذلك هي متصلة
+
+453
+00:39:41,930 --> 00:39:45,990
+برابطة ليست جزء من السلسلة اللي مكتوبة بين قوسين
+
+454
+00:39:45,990 --> 00:39:50,490
+شو معناها انه متصلة برابطة يعني هذه CH3 لما تكون
+
+455
+00:39:50,490 --> 00:39:54,490
+بين قوسين يعني معناها موجودة هنا الآن هذا لما كله
+
+456
+00:39:54,490 --> 00:40:01,110
+بدأ أسمي شو بدأ أسمي one two three على موقع three
+
+457
+00:40:01,110 --> 00:40:09,580
+حامل مثل three مثل hexanoic acid three مثلHexanoic
+
+458
+00:40:09,580 --> 00:40:14,760
+acid واضح؟
+
+459
+00:40:14,760 --> 00:40:20,660
+وطبعا جد ما تتعقد الأمور بإمكاننا أننا نستمر في
+
+460
+00:40:20,660 --> 00:40:26,060
+التسمية و هناخد أمثلة كتير لكن خلينا نتعرض للأحماض
+
+461
+00:40:26,060 --> 00:40:31,040
+من أبسط حامض و نطلع قولنا أبسط حامض اللي فيه كام
+
+462
+00:40:31,040 --> 00:40:39,000
+كربونا؟ واحدة شو بدنا نسميه احنا؟ميثانوك أسد الآن
+
+463
+00:40:39,000 --> 00:40:45,420
+ال IUPAC name تبعه مثانوك أسد ال formic acid اللي
+
+464
+00:40:45,420 --> 00:40:50,160
+هو عبارة عن common name كويس انتم ممتاز حافظينه و
+
+465
+00:40:50,160 --> 00:40:53,740
+عارفين انه formic acid لكن ال formic acid اسم
+
+466
+00:40:53,740 --> 00:41:02,000
+الشهرة واضح بس اسمه بال IUPAC مثانوك أسد بال
+
+467
+00:41:02,000 --> 00:41:10,720
+common الإنجليزيformic acid بالعربي حمض
+
+468
+00:41:10,720 --> 00:41:16,540
+الفورميك إسم تاني مين تتذكر إيش اسمه التاني
+
+469
+00:41:16,540 --> 00:41:26,040
+بالعربي حمض الفورميك حمض النمليك لأن هذا من النمل
+
+470
+00:41:26,040 --> 00:41:30,600
+حمض النمليك من النمل بالالماني
+
+471
+00:41:32,720 --> 00:41:36,720
+amaisin zörey amaisin يعني نمل و zörey يعني حمض
+
+472
+00:41:36,720 --> 00:41:41,380
+حمض النمل الألمان زي ما احنا بنسميه حمض النمليك هم
+
+473
+00:41:41,380 --> 00:41:49,360
+برضه بيسموه حمض النمل واضح؟ أه لأنه
+
+474
+00:41:49,360 --> 00:41:53,480
+أصله من وين ال source تبعه من ال ants ال ants اللي
+
+475
+00:41:53,480 --> 00:41:59,060
+هي النمل طب ليش سموه formic لأنه باللاتيني النمل
+
+476
+00:41:59,060 --> 00:42:05,480
+formicaلاحظوا الاصل اللاتيني و ال formica اللي هي
+
+477
+00:42:05,480 --> 00:42:10,700
+اسم النمل باللاتيني الآن الحامض اللي من Carbontane
+
+478
+00:42:10,700 --> 00:42:19,100
+اللي هو Acetic Acid بال Common حمض الخل بالعربي،
+
+479
+00:42:19,100 --> 00:42:23,340
+مظبوط ولا لأ؟ Essigzeure بالالماني بال Ayurvedic
+
+480
+00:42:23,340 --> 00:42:27,900
+Ethanoic Acid و أصله من ال vinegar ال vinegar اللي
+
+481
+00:42:27,900 --> 00:42:34,870
+هوالخلق الآن الحمض اللي من تلت كربونات أصله من
+
+482
+00:42:34,870 --> 00:42:41,130
+الحليب أصله من الحليب بيسموه إبروبيونك أسد
+
+483
+00:42:41,130 --> 00:42:48,250
+إبروبيونك يعني اللي هو ال common name تبعه ال
+
+484
+00:42:48,250 --> 00:42:56,090
+أيوبك إبروبانوك انتبه الفرق بين الكلمتينفي الايوبك
+
+485
+00:42:56,090 --> 00:43:02,810
+بروبانويك، بالكمون بروبيونيك، بس أصله من وين؟ من
+
+486
+00:43:02,810 --> 00:43:08,470
+الحليب، من الملش، عشان ذلك الألمان شو بيسموه؟ ملش
+
+487
+00:43:08,470 --> 00:43:14,910
+زيري، حمض الحليب، حمض الحليب على أصله، أه الأربع
+
+488
+00:43:14,910 --> 00:43:20,930
+كربونات أصله من إيش؟ من الزبدة، شكله إحنا هنهوله
+
+489
+00:43:20,930 --> 00:43:28,650
+لمطبخبيقولوا عنه البوترزايري حمض الزبدة او بيوتيرك
+
+490
+00:43:28,650 --> 00:43:32,790
+لاحظوا كيف بيوتيرك بالواو هذا الاسم common name بس
+
+491
+00:43:32,790 --> 00:43:44,190
+ال أيوبك بيوتانويك الخامسة
+
+492
+00:43:44,190 --> 00:43:50,210
+بنتانويك الاسم تبعه بال common valeric إذا مال
+
+493
+00:43:50,210 --> 00:43:57,170
+عليكم الستةهكسانوك بيسموه كبروك من ال goods اللي
+
+494
+00:43:57,170 --> 00:44:04,910
+هي الغنم او المعز السابعة هبتانوك بيسموه انانفك
+
+495
+00:44:04,910 --> 00:44:08,850
+بال common name التمانية أكتانوك بيسموه كابريليك
+
+496
+00:44:08,850 --> 00:44:13,150
+التسعة نونانوك بيسموه بيلارغونك العشرة ديكانوك
+
+497
+00:44:13,150 --> 00:44:17,340
+بيسموه كابريكطبعا انتوا هتقولوا مطلوب مننا نحفظ كل
+
+498
+00:44:17,340 --> 00:44:22,140
+هالاسماء؟ لأ لكن انتبهوا معاه وانتوا بتقرأوا
+
+499
+00:44:22,140 --> 00:44:26,080
+وانتوا بتدرسوا في المستقبل بيكون في بالكوا ان كل
+
+500
+00:44:26,080 --> 00:44:31,080
+الأحماض هدولة اللي اللهم نظام سهل في التسميهانة
+
+501
+00:44:31,080 --> 00:44:35,620
+سهولة نظام ال أيوبك يعني لو قلتلكوا سامول ال أيوبك
+
+502
+00:44:35,620 --> 00:44:40,350
+من واحد لعشرةبتسموه بسهولة مثانوك اثانوك بروبانوك
+
+503
+00:44:40,350 --> 00:44:45,050
+بيوتانوك متانوك لحد كانوك ماعندكم مشكلة لكن الكمون
+
+504
+00:44:45,050 --> 00:44:49,790
+يلهم أصل تاريخي اللي من الغنم واللي من الحليب
+
+505
+00:44:49,790 --> 00:44:54,890
+واللي من الخل واللي من النمل واللي .. واضح؟ لكن في
+
+506
+00:44:54,890 --> 00:44:58,410
+أي لحظة من اللحظات بتحتاجوا أنتم تتذكروا هذه
+
+507
+00:44:58,410 --> 00:45:02,530
+الشغلات تتذكروا أن في عندكم جدول للأحماض وأن كل
+
+508
+00:45:02,530 --> 00:45:09,410
+حامض زي ما إله اسم أيوبك إله اسمكومن لو في يوم من
+
+509
+00:45:09,410 --> 00:45:14,790
+الأيام لزمكم بتكونوا عارفينه ..وبهيك بننهي اليوم
+
+510
+00:45:14,790 --> 00:45:21,810
+وإن شاء الله للكلام بقية .. للكلام بقية ..
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..f1473f4f9ad55cac7305143021a356bc1926a9d0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 4453, "start": 15.47, "end": 44.53, "text": "اليوم إن شاء الله هنبدأ بفصل جديد الفصل السابع زي ما بتلاحظوا على السطورة العنوان اللي عندنا alcohols, phenols and thiols يعني كأنه في هذا الفصل بدأ نستعرض تلت أنواع من المركبات بس أكيد أكيد دول الأنواع التلاتة في بينهم شبه وفي بينهم", "tokens": [6027, 1829, 20498, 36145, 13412, 16606, 21984, 8032, 1863, 44510, 10721, 4724, 5172, 36520, 10874, 16254, 3215, 27188, 36520, 21136, 16758, 3615, 30767, 1829, 19446, 39894, 15040, 5016, 19913, 14407, 15844, 21136, 9566, 13063, 3660, 18863, 1863, 2407, 7649, 13672, 1829, 43242, 8315, 7658, 82, 11, 7279, 19385, 293, 30994, 19385, 37495, 22653, 9122, 33456, 3224, 8978, 23758, 27188, 36520, 47525, 10721, 8717, 14851, 3615, 43042, 6055, 1211, 2655, 14739, 14407, 3615, 9154, 9673, 31747, 3555, 9307, 4724, 3794, 5551, 4117, 25708, 5551, 4117, 25708, 11778, 12610, 16247, 1863, 14407, 3615, 16712, 1211, 9307, 3660, 8978, 49374, 16095, 13412, 3555, 3224, 4032, 41185, 49374, 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مثل ال alkanes المناظرة بس بزيادة النهاية all", "tokens": [6027, 7649, 45164, 1975, 7435, 1829, 8315, 32767, 2407, 11242, 45367, 16712, 38251, 10632, 2423, 7658, 82, 6055, 38251, 7578, 50113, 1211, 2423, 419, 5225, 279, 9673, 1863, 5718, 116, 25720, 4724, 3794, 4724, 11622, 1829, 18513, 3660, 28239, 11296, 10632, 439], "avg_logprob": -0.22819767719091372, "compression_ratio": 1.3070175438596492, "no_speech_prob": 0.0, "words": [{"start": 150.39, "end": 150.93, "word": "الان", "probability": 0.6715087890625}, {"start": 150.93, "end": 151.35, "word": " لو", "probability": 0.96240234375}, {"start": 151.35, "end": 151.81, "word": " اجينا", "probability": 0.8194580078125}, {"start": 151.81, "end": 152.81, "word": " لموضوع", "probability": 0.9161376953125}, {"start": 152.81, "end": 153.79, "word": " التسمية", "probability": 0.9674479166666666}, {"start": 153.79, "end": 154.71, "word": " ال", "probability": 0.8359375}, {"start": 154.71, "end": 155.61, "word": " alcohols", "probability": 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مثلا بدي أقول cholesterol هي نهايته all هذا OL هذا OL", "tokens": [36, 8978, 6024, 95, 34740, 37495, 22653, 4724, 3794, 39191, 19446, 44945, 39648, 8592, 422, 2634, 23758, 2423, 28820, 10943, 7251, 43020, 7251, 30544, 9154, 3224, 6156, 16373, 41891, 5296, 33456, 3224, 5296, 15042, 39894, 4587, 2288, 10721, 5551, 5016, 1829, 7649, 995, 5551, 38251, 16606, 3714, 31747, 3555, 9307, 4032, 8717, 11296, 36081, 11296, 422, 2634, 20449, 8315, 3224, 29910, 23275, 37893, 7658, 82, 29538, 37495, 22653, 45164, 41850, 50113, 15040, 4724, 16254, 5551, 39648, 24716, 39896, 8717, 11296, 36081, 3224, 439, 23758, 39191, 23758, 39191], "avg_logprob": -0.217151988805695, "compression_ratio": 1.61244019138756, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 167.13, "end": 167.45, "word": "E", "probability": 0.73828125}, {"start": 167.45, "end": 167.67, "word": " في", "probability": 0.8984375}, {"start": 167.67, "end": 168.33, "word": " الآخر", "probability": 0.97021484375}, {"start": 168.33, 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مجموعة ال OH الآن لو هذه المركبات بدي أسميها", "tokens": [2304, 1829, 12984, 7649, 12610, 11933, 15730, 18871, 16254, 11933, 1829, 12984, 9957, 11933, 1829, 12984, 7649, 12610, 11933, 15730, 18871, 16254, 4724, 32887, 3555, 9957, 4724, 32887, 3555, 7649, 12610, 44381, 41850, 44650, 30543, 3615, 6055, 1829, 7435, 1829, 15844, 3714, 30543, 3615, 9957, 4724, 3794, 18871, 16254, 472, 4724, 32887, 3555, 7649, 12610, 4032, 732, 4724, 32887, 3555, 7649, 12610, 37495, 22653, 5296, 31377, 2304, 5551, 24401, 3215, 4032, 9957, 10874, 995, 10632, 3714, 7435, 2304, 2407, 27884, 2423, 13931, 6024, 48506, 45164, 29538, 9673, 31747, 3555, 9307, 4724, 16254, 5551, 38251, 1829, 11296], "avg_logprob": -0.17316366470966144, "compression_ratio": 1.8932584269662922, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 294.1, "end": 294.72, "word": "ميثانول", "probability": 0.7763671875}, {"start": 294.72, "end": 295.22, "word": " إذا", "probability": 0.759521484375}, {"start": 295.22, "end": 295.5, 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"probability": 0.9580078125}, {"start": 818.69, "end": 819.29, "word": " بيكونوا", "probability": 0.918701171875}, {"start": 819.29, "end": 819.81, "word": " تنتين", "probability": 0.9765625}, {"start": 819.81, "end": 820.27, "word": " لازم", "probability": 0.9931640625}, {"start": 820.27, "end": 821.13, "word": " احدد", "probability": 0.9601236979166666}], "temperature": 1.0}, {"id": 32, "seek": 85037, "start": 822.15, "end": 850.37, "text": "و المواقعهم في الأول بالنسبة لبعض ممكن يكونوا جايين ورا بعض واحد و اتنين و ممكن واحد و تلاتة، مظبوط ولا لا؟ اذا كأنه انا عندي one, two, three, four, five فهذا لازم احط عنه one, two, cyclopentane, diol لان لو الـ OH إجت هنا، إيش بدي يصير؟ one, three, cyclopentane, diol لو إجت هنا", "tokens": [2407, 9673, 14407, 4587, 3615, 16095, 8978, 16247, 12610, 20666, 1863, 35457, 3660, 5296, 3555, 3615, 11242, 3714, 43020, 7251, 30544, 14407, 10874, 47302, 9957, 4032, 23557, 45030, 11242, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 4032, 3714, 43020, 36764, 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"probability": 0.89599609375}, {"start": 844.55, "end": 844.71, "word": " الـ", "probability": 0.5264892578125}, {"start": 844.71, "end": 844.95, "word": " OH", "probability": 0.368896484375}, {"start": 844.95, "end": 845.31, "word": " إجت", "probability": 0.6725667317708334}, {"start": 845.31, "end": 845.63, "word": " هنا،", "probability": 0.781005859375}, {"start": 845.63, "end": 845.71, "word": " إيش", "probability": 0.8219401041666666}, {"start": 845.71, "end": 845.87, "word": " بدي", "probability": 0.453369140625}, {"start": 845.87, "end": 846.99, "word": " يصير؟", "probability": 0.923828125}, {"start": 846.99, "end": 847.27, "word": " one,", "probability": 0.6806640625}, {"start": 847.37, "end": 847.69, "word": " three,", "probability": 0.93310546875}, {"start": 847.89, "end": 849.33, "word": " cyclopentane,", "probability": 0.9610595703125}, {"start": 849.41, "end": 849.63, "word": " diol", "probability": 0.938720703125}, {"start": 849.63, "end": 849.77, "word": " لو", 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{"start": 852.09, "end": 852.23, "word": " and", "probability": 0.5244140625}, {"start": 852.23, "end": 852.49, "word": " three", "probability": 0.94921875}, {"start": 852.49, "end": 853.39, "word": " من", "probability": 0.89453125}, {"start": 853.39, "end": 853.79, "word": " الجهات", "probability": 0.9368489583333334}, {"start": 853.79, "end": 854.27, "word": " التانية", "probability": 0.9788411458333334}, {"start": 854.27, "end": 856.93, "word": " دائما", "probability": 0.8136393229166666}, {"start": 856.93, "end": 857.23, "word": " بتكون", "probability": 0.6351318359375}, {"start": 857.23, "end": 857.47, "word": " تسع", "probability": 0.8885091145833334}, {"start": 857.47, "end": 857.71, "word": " ورا", "probability": 0.65576171875}, {"start": 857.71, "end": 858.29, "word": " اقل", "probability": 0.782958984375}, {"start": 858.29, "end": 859.27, "word": " ترقيم", "probability": 0.9375}, {"start": 859.27, "end": 859.75, "word": " اه", "probability": 0.75048828125}, {"start": 859.75, 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المجموعات مع بعض ولا عكس بعض، في هذه الحالة هم مرسومين ال wedges مع بعض ولا لأ؟ جايين هيك للأمام باتجاهنا، إذا هذا cis one two cyclopentane diol", "tokens": [6027, 39184, 3834, 14713, 4032, 21542, 1211, 4587, 9307, 29538, 3834, 14713, 13412, 995, 33911, 9957, 11296, 22807, 8978, 16095, 1357, 116, 40294, 25720, 11933, 1829, 8592, 22807, 2423, 37847, 4032, 2423, 24999, 36145, 3224, 9673, 7435, 2304, 45367, 9307, 20449, 45030, 11242, 49429, 6225, 4117, 3794, 45030, 11242, 12399, 8978, 29538, 21542, 6027, 3660, 8032, 2304, 3714, 2288, 3794, 20498, 9957, 2423, 6393, 2880, 20449, 45030, 11242, 49429, 5296, 10721, 22807, 10874, 47302, 9957, 39896, 4117, 24976, 10721, 2304, 10943, 4724, 9307, 7435, 40294, 8315, 12399, 11933, 15730, 23758, 37847, 472, 732, 19474, 404, 317, 1929, 1026, 401], "avg_logprob": -0.27140624195337293, "compression_ratio": 1.6222222222222222, "no_speech_prob": 0.0, "words": [{"start": 865.69, "end": 866.05, "word": "الـ", "probability": 0.790771484375}, {"start": 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الميثانول عند حوالي ستين أو واحد وستين الإثانول عند حوالي تمانين أو تمانية وسبعين ملاحظين؟ طبعا الميّه أعلى منهم لأنه بتعمل تنتين hydrogen bonding ومر علينا كيف الميّه بتعمل hydrogen bonding", "tokens": [3615, 6027, 10632, 8717, 35457, 25528, 14111, 4032, 46958, 5016, 22807, 50113, 1211, 8032, 3215, 12610, 3660, 50113, 15040, 9673, 10859, 31747, 11703, 3555, 9307, 9673, 1829, 11703, 3224, 20666, 2407, 11242, 3615, 41950, 21292, 3615, 1829, 39894, 17082, 22653, 43242, 11296, 9122, 2304, 22807, 43242, 3714, 10632, 9673, 1829, 12984, 7649, 12610, 43242, 11331, 2407, 6027, 1829, 8608, 2655, 9957, 34051, 36764, 24401, 4032, 14851, 9957, 33688, 12984, 7649, 12610, 43242, 11331, 2407, 6027, 1829, 46811, 7649, 9957, 34051, 46811, 7649, 10632, 4032, 35457, 3615, 9957, 3714, 15040, 5016, 19913, 9957, 22807, 23032, 3555, 3615, 995, 9673, 1829, 11703, 3224, 5551, 3615, 23942, 9154, 16095, 5296, 33456, 3224, 39894, 25957, 1211, 6055, 29399, 9957, 12697, 28824, 4032, 29973, 25894, 8315, 9122, 33911, 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1656.19, "end": 1656.39, "word": " له", "probability": 0.5771484375}, {"start": 1656.39, "end": 1656.69, "word": " نفس", "probability": 0.994873046875}, {"start": 1656.69, "end": 1657.31, "word": " الوزن", "probability": 0.9935302734375}, {"start": 1657.31, "end": 1657.79, "word": " زي", "probability": 0.822021484375}, {"start": 1657.79, "end": 1657.97, "word": " الـ", "probability": 0.572509765625}, {"start": 1657.97, "end": 1658.43, "word": " إيثان", "probability": 0.73095703125}], "temperature": 1.0}, {"id": 67, "seek": 168836, "start": 1661.22, "end": 1688.36, "text": "غير قصة اللي هي ال boiling point ذائبية ال alcohol في الميه ذائبية ال alcohol في الميه الآن هنا بدكوا تنتبهوا ال boiling point لما بتعمل ال alcohol هيدروجيلبون مع ايش؟ مع نفسها", "tokens": [17082, 13546, 12174, 9381, 3660, 13672, 1829, 39896, 2423, 16208, 935, 29910, 16373, 3555, 10632, 2423, 7658, 8978, 9673, 1829, 3224, 29910, 16373, 3555, 10632, 2423, 7658, 8978, 9673, 1829, 3224, 6024, 48506, 34105, 47525, 4117, 14407, 6055, 29399, 3555, 3224, 14407, 2423, 16208, 935, 5296, 15042, 39894, 25957, 1211, 2423, 7658, 8032, 25708, 2288, 29245, 26895, 3555, 11536, 20449, 1975, 1829, 8592, 22807, 20449, 8717, 36178, 11296], "avg_logprob": -0.22610960231311078, "compression_ratio": 1.7515923566878981, "no_speech_prob": 0.0, "words": [{"start": 1661.22, "end": 1661.78, "word": "غير", "probability": 0.947265625}, {"start": 1661.78, "end": 1663.12, "word": " قصة", "probability": 0.9853515625}, {"start": 1663.12, "end": 1663.34, "word": " اللي", "probability": 0.518798828125}, {"start": 1663.34, "end": 1663.6, "word": " هي", "probability": 0.93701171875}, {"start": 1663.6, "end": 1664.32, "word": " ال", "probability": 0.732421875}, {"start": 1664.32, "end": 1664.72, "word": " boiling", "probability": 0.49462890625}, {"start": 1664.72, "end": 1665.06, "word": " point", "probability": 0.9853515625}, {"start": 1665.06, "end": 1666.24, "word": " ذائبية", "probability": 0.87109375}, {"start": 1666.24, "end": 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"word": " تنتبهوا", "probability": 0.97900390625}, {"start": 1675.58, "end": 1676.0, "word": " ال", "probability": 0.9140625}, {"start": 1676.0, "end": 1676.4, "word": " boiling", "probability": 0.970703125}, {"start": 1676.4, "end": 1677.22, "word": " point", "probability": 0.9853515625}, {"start": 1677.22, "end": 1677.86, "word": " لما", "probability": 0.946533203125}, {"start": 1677.86, "end": 1678.4, "word": " بتعمل", "probability": 0.9755859375}, {"start": 1678.4, "end": 1678.52, "word": " ال", "probability": 0.95654296875}, {"start": 1678.52, "end": 1679.0, "word": " alcohol", "probability": 0.92724609375}, {"start": 1679.0, "end": 1680.08, "word": " هيدروجيلبون", "probability": 0.7471749441964286}, {"start": 1680.08, "end": 1683.6, "word": " مع", "probability": 0.183349609375}, {"start": 1683.6, "end": 1685.68, "word": " ايش؟", "probability": 0.74200439453125}, {"start": 1685.68, "end": 1687.5, "word": " مع", "probability": 0.9697265625}, {"start": 1687.5, "end": 1688.36, "word": " نفسها", "probability": 0.9938151041666666}], "temperature": 1.0}, {"id": 68, "seek": 171318, "start": 1689.44, "end": 1713.18, "text": "مع نفسها يعني انا لما اقول methanol و عامل hydrogen bonding كأن هنا بقول بالظبط CH3OH و من هنا عامل hydrogen bonding مع واحد تاني هاي hydrogen bonding هيك مقطعة H OCH3 فهي عندي جزء", "tokens": [2304, 3615, 8717, 36178, 11296, 37495, 22653, 1975, 8315, 5296, 15042, 1975, 39648, 1131, 35735, 4032, 6225, 10943, 1211, 12697, 28824, 9122, 33456, 34105, 4724, 39648, 20666, 19913, 3555, 9566, 5995, 18, 31187, 4032, 9154, 34105, 6225, 10943, 1211, 12697, 28824, 20449, 36764, 24401, 6055, 7649, 1829, 8032, 47302, 12697, 28824, 39896, 4117, 3714, 47432, 27884, 389, 422, 5462, 18, 6156, 3224, 1829, 18871, 16254, 10874, 11622, 38207], "avg_logprob": -0.3181612232457037, "compression_ratio": 1.5114942528735633, "no_speech_prob": 0.0, "words": [{"start": 1689.44, "end": 1689.8, "word": "مع", "probability": 0.582763671875}, {"start": 1689.8, "end": 1690.48, "word": " نفسها", "probability": 0.9734700520833334}, {"start": 1690.48, "end": 1691.12, "word": " يعني", "probability": 0.7685546875}, {"start": 1691.12, "end": 1691.42, "word": " انا", "probability": 0.6527099609375}, {"start": 1691.42, "end": 1691.58, "word": " لما", "probability": 0.81494140625}, {"start": 1691.58, "end": 1691.96, "word": " اقول", "probability": 0.834228515625}, {"start": 1691.96, "end": 1692.82, "word": " methanol", "probability": 0.6016845703125}, {"start": 1692.82, "end": 1693.02, "word": " و", "probability": 0.7802734375}, {"start": 1693.02, "end": 1693.4, "word": " عامل", "probability": 0.780517578125}, {"start": 1693.4, "end": 1694.02, "word": " hydrogen", "probability": 0.8564453125}, {"start": 1694.02, "end": 1694.7, "word": " bonding", "probability": 0.931640625}, {"start": 1694.7, "end": 1695.58, "word": " كأن", "probability": 0.79443359375}, {"start": 1695.58, "end": 1695.82, "word": " هنا", "probability": 0.23779296875}, {"start": 1695.82, "end": 1696.26, "word": " بقول", "probability": 0.861083984375}, {"start": 1696.26, "end": 1696.84, "word": " بالظبط", "probability": 0.79376220703125}, {"start": 1696.84, "end": 1699.54, "word": " CH3OH", "probability": 0.8815104166666666}, {"start": 1699.54, "end": 1700.14, "word": " و", "probability": 0.7880859375}, {"start": 1700.14, "end": 1700.32, "word": " من", "probability": 0.76513671875}, {"start": 1700.32, "end": 1700.72, "word": " هنا", "probability": 0.98291015625}, {"start": 1700.72, "end": 1701.98, "word": " عامل", "probability": 0.9912109375}, {"start": 1701.98, "end": 1702.6, "word": " hydrogen", "probability": 0.96240234375}, {"start": 1702.6, "end": 1703.3, "word": " bonding", "probability": 0.96044921875}, {"start": 1703.3, "end": 1703.84, "word": " مع", "probability": 0.9697265625}, {"start": 1703.84, "end": 1704.82, "word": " واحد", "probability": 0.950927734375}, {"start": 1704.82, "end": 1706.0, "word": " تاني", "probability": 0.88671875}, {"start": 1706.0, "end": 1706.36, "word": " هاي", "probability": 0.4443359375}, {"start": 1706.36, "end": 1706.8, "word": " hydrogen", "probability": 0.89599609375}, {"start": 1706.8, "end": 1707.24, "word": " bonding", "probability": 0.95166015625}, {"start": 1707.24, "end": 1707.54, "word": " هيك", "probability": 0.6783447265625}, {"start": 1707.54, "end": 1708.12, "word": " مقطعة", "probability": 0.60595703125}, {"start": 1708.12, "end": 1708.62, "word": " H", "probability": 0.68798828125}, {"start": 1708.62, "end": 1711.36, "word": " OCH3", "probability": 0.64892578125}, {"start": 1711.36, "end": 1712.16, "word": " فهي", "probability": 0.8211263020833334}, {"start": 1712.16, "end": 1712.52, "word": " عندي", "probability": 0.7156982421875}, {"start": 1712.52, "end": 1713.18, "word": " جزء", "probability": 0.7788899739583334}], "temperature": 1.0}, {"id": 69, "seek": 174021, "start": 1714.25, "end": 1740.21, "text": "وجزء هذا الـ hydrogen bonding ما بين جزيئات نفس المادة بيعمل الارتفاع في نقطة الغليان الآن بيجيني الذائبية الذائبية ال alcohol في الميه الذائبية ال alcohol في الميه الذائبية برضه عبارة عن hydrogen bonding بس المرة هذه ال hydrogen bonding بتكون معاشر", "tokens": [2407, 7435, 11622, 38207, 23758, 2423, 39184, 12697, 28824, 19446, 49374, 10874, 11622, 1829, 19986, 9307, 8717, 36178, 9673, 18513, 3660, 4724, 1829, 25957, 1211, 2423, 9640, 2655, 5172, 45761, 8978, 8717, 47432, 3660, 6024, 118, 20292, 7649, 6024, 48506, 4724, 1829, 7435, 9957, 1829, 32545, 16373, 3555, 10632, 32545, 16373, 3555, 10632, 2423, 7658, 8978, 9673, 1829, 3224, 32545, 16373, 3555, 10632, 2423, 7658, 8978, 9673, 1829, 3224, 32545, 16373, 3555, 10632, 4724, 43042, 3224, 6225, 3555, 9640, 3660, 18871, 12697, 28824, 4724, 3794, 9673, 25720, 29538, 2423, 12697, 28824, 39894, 30544, 20449, 33599, 2288], "avg_logprob": -0.1675257682800293, "compression_ratio": 2.062176165803109, "no_speech_prob": 0.0, "words": [{"start": 1714.25, "end": 1715.03, "word": "وجزء", "probability": 0.605316162109375}, {"start": 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{"start": 1722.91, "end": 1723.57, "word": " نقطة", "probability": 0.9912109375}, {"start": 1723.57, "end": 1724.77, "word": " الغليان", "probability": 0.9610595703125}, {"start": 1724.77, "end": 1725.73, "word": " الآن", "probability": 0.6944580078125}, {"start": 1725.73, "end": 1726.25, "word": " بيجيني", "probability": 0.86708984375}, {"start": 1726.25, "end": 1727.07, "word": " الذائبية", "probability": 0.9635009765625}, {"start": 1727.07, "end": 1727.69, "word": " الذائبية", "probability": 0.806884765625}, {"start": 1727.69, "end": 1727.91, "word": " ال", "probability": 0.8134765625}, {"start": 1727.91, "end": 1728.35, "word": " alcohol", "probability": 0.467529296875}, {"start": 1728.35, "end": 1729.13, "word": " في", "probability": 0.8134765625}, {"start": 1729.13, "end": 1729.81, "word": " الميه", "probability": 0.7073567708333334}, {"start": 1729.81, "end": 1731.01, "word": " الذائبية", "probability": 0.932861328125}, {"start": 1731.01, "end": 1731.19, "word": " ال", "probability": 0.93310546875}, {"start": 1731.19, "end": 1731.61, "word": " alcohol", "probability": 0.89990234375}, {"start": 1731.61, "end": 1731.95, "word": " في", "probability": 0.469970703125}, {"start": 1731.95, "end": 1733.27, "word": " الميه", "probability": 0.951171875}, {"start": 1733.27, "end": 1734.37, "word": " الذائبية", "probability": 0.941650390625}, {"start": 1734.37, "end": 1734.73, "word": " برضه", "probability": 0.8199055989583334}, {"start": 1734.73, "end": 1735.11, "word": " عبارة", "probability": 0.9833984375}, {"start": 1735.11, "end": 1735.29, "word": " عن", "probability": 0.9921875}, {"start": 1735.29, "end": 1735.83, "word": " hydrogen", "probability": 0.82763671875}, {"start": 1735.83, "end": 1736.57, "word": " bonding", "probability": 0.95751953125}, {"start": 1736.57, "end": 1737.23, "word": " بس", "probability": 0.90966796875}, {"start": 1737.23, "end": 1737.67, "word": " المرة", "probability": 0.942626953125}, {"start": 1737.67, "end": 1737.93, "word": " هذه", "probability": 0.64892578125}, {"start": 1737.93, "end": 1738.07, "word": " ال", "probability": 0.94677734375}, {"start": 1738.07, "end": 1738.51, "word": " hydrogen", "probability": 0.86767578125}, {"start": 1738.51, "end": 1738.99, "word": " bonding", "probability": 0.943359375}, {"start": 1738.99, "end": 1739.45, "word": " بتكون", "probability": 0.918701171875}, {"start": 1739.45, "end": 1740.21, "word": " معاشر", "probability": 0.764892578125}], "temperature": 1.0}, {"id": 70, "seek": 175790, "start": 1740.84, "end": 1757.9, "text": "مع الميّه بمعنى خلّيني أتخيل أنه عندى نفس جزء الالكوهون هذا CH3OH وهي أزواج إلكترونات عليه و بعدين بده يجي يعمل hydrogen bonding مع الميّه واضح؟", "tokens": [2304, 3615, 9673, 1829, 11703, 3224, 4724, 2304, 3615, 1863, 7578, 16490, 1211, 11703, 9957, 1829, 5551, 2655, 9778, 26895, 14739, 3224, 43242, 7578, 8717, 36178, 10874, 11622, 38207, 2423, 6027, 4117, 2407, 3224, 11536, 23758, 5995, 18, 31187, 37037, 1829, 5551, 11622, 2407, 26108, 11933, 23275, 2655, 2288, 11536, 9307, 47356, 4032, 39182, 9957, 47525, 3224, 7251, 7435, 1829, 7251, 25957, 1211, 12697, 28824, 20449, 9673, 1829, 11703, 3224, 4032, 46958, 5016, 22807], "avg_logprob": -0.3079166650772095, "compression_ratio": 1.396551724137931, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 1740.84, "end": 1741.18, "word": "مع", "probability": 0.58612060546875}, {"start": 1741.18, "end": 1741.66, "word": " الميّه", "probability": 0.77899169921875}, {"start": 1741.66, "end": 1742.32, "word": " بمعنى", "probability": 0.86865234375}, {"start": 1742.32, "end": 1742.66, "word": " خلّيني", "probability": 0.86337890625}, {"start": 1742.66, "end": 1743.06, "word": " أتخيل", "probability": 0.848388671875}, {"start": 1743.06, "end": 1743.32, "word": " أنه", "probability": 0.5067138671875}, {"start": 1743.32, "end": 1743.58, "word": " عندى", "probability": 0.63916015625}, {"start": 1743.58, "end": 1743.84, "word": " نفس", "probability": 0.989990234375}, {"start": 1743.84, 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{"start": 1750.64, "end": 1751.3, "word": " يعمل", "probability": 0.95947265625}, {"start": 1751.3, "end": 1752.62, "word": " hydrogen", "probability": 0.759765625}, {"start": 1752.62, "end": 1753.36, "word": " bonding", "probability": 0.919921875}, {"start": 1753.36, "end": 1755.16, "word": " مع", "probability": 0.958984375}, {"start": 1755.16, "end": 1755.8, "word": " الميّه", "probability": 0.88330078125}, {"start": 1755.8, "end": 1757.9, "word": " واضح؟", "probability": 0.73046875}], "temperature": 1.0}, {"id": 71, "seek": 178088, "start": 1759.84, "end": 1780.88, "text": "هنا بتلاحظوا ان الالكول مع الالكول عملوا hydrogen bonding هذه ال hydrogen bonding اللي ما بين الالكول مع نفسه بين أثرها وين؟ في ال boiling point المرتفعة ان الجزيات مرتبطة عشان أفصلها عن بعض الغليان عبارة عن عملية ash", "tokens": [3224, 8315, 39894, 15040, 5016, 19913, 14407, 16472, 2423, 6027, 4117, 12610, 20449, 2423, 6027, 4117, 12610, 6225, 42213, 14407, 12697, 28824, 29538, 2423, 12697, 28824, 13672, 1829, 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أحماض ضعيفة عليهم شحنة الـ Oxygen اللي بدأ تحمل الشحنة صغيرة لا تستطيع أن تحمل شحنة مش ال Oxygen ذرة صغيرة مابتقدرش تحمل شحنة إذا كل هدولة يعتبروا أحماض", "tokens": [6027, 39184, 430, 16135, 6225, 6027, 10632, 9122, 12984, 13546, 11933, 15730, 8032, 3215, 12610, 3660, 28242, 16095, 6225, 3555, 9640, 3660, 18871, 5336, 21667, 5551, 35571, 46958, 48812, 3615, 33911, 3660, 25894, 16095, 13412, 5016, 1863, 3660, 2423, 39184, 16489, 8647, 13672, 1829, 47525, 10721, 6055, 35571, 1211, 25124, 5016, 1863, 3660, 20328, 17082, 48923, 20193, 6055, 14851, 9566, 40228, 14739, 6055, 35571, 1211, 13412, 5016, 1863, 3660, 37893, 2423, 16489, 8647, 29910, 25720, 20328, 17082, 48923, 3714, 16758, 2655, 28543, 2288, 8592, 6055, 35571, 1211, 13412, 5016, 1863, 3660, 11933, 15730, 28242, 8032, 3215, 12610, 3660, 7251, 34268, 26890, 14407, 5551, 35571, 46958], "avg_logprob": -0.15905071190505657, "compression_ratio": 1.745, "no_speech_prob": 0.0, "words": [{"start": 2923.05, "end": 2923.33, "word": "الـ", 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"word": " حامضية", "probability": 0.8890380859375}, {"start": 3023.4, "end": 3024.24, "word": " الإيثانول", "probability": 0.95087890625}, {"start": 3024.24, "end": 3024.92, "word": " زي", "probability": 0.976806640625}, {"start": 3024.92, "end": 3025.66, "word": " حامضية", "probability": 0.9967041015625}, {"start": 3025.66, "end": 3026.64, "word": " إيش؟", "probability": 0.8590087890625}, {"start": 3026.64, "end": 3027.24, "word": " الميه", "probability": 0.8899739583333334}], "temperature": 1.0}, {"id": 123, "seek": 305127, "start": 3027.81, "end": 3051.27, "text": "أحنا لسه خلّينا نقول في أول الموضوع، اليوم المحاضرة خلصت، لكن الموضوع الحمضية كبير، اللي صرنا ماخدينه أنه اتذكرنا شوية معلومات عن الحمضية وقلنا أنه الميه والميثانول والإيثانول كلهم عبارة عن weak acids، very weak acids كمان، وبنغسل وجوهنا فيهم وإيدينا ولا بنحرج ولا إشي", "tokens": [10721, 5016, 8315, 5296, 3794, 3224, 16490, 1211, 11703, 1829, 8315, 8717, 39648, 8978, 5551, 12610, 9673, 2407, 11242, 45367, 12399, 45595, 20498, 9673, 5016, 46958, 25720, 16490, 1211, 9381, 2655, 12399, 44381, 9673, 2407, 11242, 45367, 21542, 2304, 11242, 10632, 9122, 3555, 13546, 12399, 13672, 1829, 20328, 2288, 8315, 3714, 47283, 3215, 9957, 3224, 14739, 3224, 1975, 2655, 8848, 37983, 8315, 13412, 2407, 10632, 20449, 1211, 20498, 9307, 18871, 21542, 2304, 11242, 10632, 4032, 4587, 1211, 8315, 14739, 3224, 9673, 1829, 3224, 16070, 2304, 1829, 12984, 7649, 12610, 16070, 28814, 1829, 12984, 7649, 12610, 28242, 16095, 6225, 3555, 9640, 3660, 18871, 5336, 21667, 12399, 588, 5336, 21667, 9122, 2304, 7649, 12399, 4032, 3555, 1863, 17082, 3794, 1211, 49610, 2407, 3224, 8315, 8978, 16095, 4032, 28814, 1829, 16254, 8315, 49429, 44945, 5016, 47341, 49429, 11933, 8592, 1829], "avg_logprob": -0.18840580023285272, "compression_ratio": 1.8577075098814229, "no_speech_prob": 0.0, "words": [{"start": 3027.81, "end": 3028.15, "word": "أحنا", "probability": 0.7876790364583334}, {"start": 3028.15, "end": 3028.75, "word": " لسه", "probability": 0.8743489583333334}, {"start": 3028.75, "end": 3029.37, "word": " خلّينا", "probability": 0.703857421875}, {"start": 3029.37, "end": 3029.81, "word": " نقول", "probability": 0.989990234375}, {"start": 3029.81, "end": 3030.11, "word": " في", "probability": 0.8828125}, {"start": 3030.11, "end": 3030.41, "word": " أول", "probability": 0.963623046875}, {"start": 3030.41, "end": 3031.01, "word": " الموضوع،", "probability": 0.90830078125}, {"start": 3031.01, "end": 3031.19, "word": " اليوم", "probability": 0.974365234375}, {"start": 3031.19, "end": 3031.75, "word": " المحاضرة", "probability": 0.968994140625}, {"start": 3031.75, "end": 3032.73, "word": " خلصت،", "probability": 0.876904296875}, {"start": 3032.73, "end": 3033.01, "word": " لكن", "probability": 0.9814453125}, {"start": 3033.01, "end": 3033.45, "word": " الموضوع", "probability": 0.9180908203125}, {"start": 3033.45, "end": 3034.01, "word": " الحمضية", "probability": 0.8851318359375}, {"start": 3034.01, "end": 3034.79, "word": " كبير،", "probability": 0.80047607421875}, {"start": 3034.79, "end": 3034.97, "word": " اللي", "probability": 0.937255859375}, {"start": 3034.97, "end": 3035.25, "word": " صرنا", "probability": 0.7052408854166666}, {"start": 3035.25, "end": 3035.81, "word": " ماخدينه", "probability": 0.95478515625}, {"start": 3035.81, "end": 3036.03, "word": " أنه", "probability": 0.53558349609375}, {"start": 3036.03, "end": 3036.87, "word": " اتذكرنا", "probability": 0.92822265625}, {"start": 3036.87, "end": 3037.19, "word": " شوية", "probability": 0.92333984375}, {"start": 3037.19, "end": 3037.67, "word": " معلومات", "probability": 0.9739990234375}, {"start": 3037.67, "end": 3037.83, "word": " عن", "probability": 0.99462890625}, {"start": 3037.83, "end": 3038.59, "word": " الحمضية", "probability": 0.9920654296875}, {"start": 3038.59, "end": 3039.39, "word": " وقلنا", "probability": 0.6612548828125}, {"start": 3039.39, "end": 3039.77, "word": " أنه", "probability": 0.5823974609375}, {"start": 3039.77, "end": 3040.41, "word": " الميه", "probability": 0.71630859375}, {"start": 3040.41, "end": 3041.19, "word": " والميثانول", "probability": 0.8355305989583334}, {"start": 3041.19, "end": 3042.01, "word": " والإيثانول", "probability": 0.8859049479166666}, {"start": 3042.01, "end": 3042.59, "word": " كلهم", "probability": 0.869873046875}, {"start": 3042.59, "end": 3043.05, "word": " عبارة", "probability": 0.996826171875}, {"start": 3043.05, "end": 3043.49, "word": " عن", "probability": 0.99658203125}, {"start": 3043.49, "end": 3044.91, "word": " weak", "probability": 0.87109375}, {"start": 3044.91, "end": 3045.83, "word": " acids،", "probability": 0.66357421875}, {"start": 3045.83, "end": 3046.11, "word": " very", "probability": 0.84521484375}, {"start": 3046.11, "end": 3046.51, "word": " weak", "probability": 0.97900390625}, {"start": 3046.51, "end": 3046.99, "word": " acids", "probability": 0.87890625}, {"start": 3046.99, "end": 3047.63, "word": " كمان،", "probability": 0.8616943359375}, {"start": 3047.63, "end": 3048.17, "word": " وبنغسل", "probability": 0.8495279947916666}, {"start": 3048.17, "end": 3048.65, "word": " وجوهنا", "probability": 0.8778076171875}, {"start": 3048.65, "end": 3048.99, "word": " فيهم", "probability": 0.989013671875}, {"start": 3048.99, "end": 3049.63, "word": " وإيدينا", "probability": 0.782666015625}, {"start": 3049.63, "end": 3050.05, "word": " ولا", "probability": 0.701171875}, {"start": 3050.05, "end": 3050.67, "word": " بنحرج", "probability": 0.7542317708333334}, {"start": 3050.67, "end": 3050.85, "word": " ولا", "probability": 0.95458984375}, {"start": 3050.85, "end": 3051.27, "word": " إشي", "probability": 0.8938802083333334}], "temperature": 1.0}, {"id": 124, "seek": 306059, "start": 3051.93, "end": 3060.59, "text": "مصبوط ولا لا؟ بعد هيك هنتوسع في الموضوع يعني يمكن بدنا في ال acidity كمان نص ساعة ان شاء الله في المحاضرة القادمة", "tokens": [2304, 9381, 3555, 2407, 9566, 49429, 20193, 22807, 39182, 39896, 4117, 8032, 29399, 41779, 3615, 8978, 9673, 2407, 11242, 45367, 37495, 22653, 7251, 43020, 47525, 8315, 8978, 2423, 8258, 507, 9122, 2304, 7649, 8717, 9381, 8608, 995, 27884, 16472, 13412, 16606, 21984, 8978, 9673, 5016, 46958, 25720, 25062, 18513, 46007], "avg_logprob": -0.13756126749749278, "compression_ratio": 1.4275362318840579, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 3051.93, "end": 3052.41, "word": "مصبوط", "probability": 0.74599609375}, {"start": 3052.41, "end": 3052.53, "word": " ولا", "probability": 0.86669921875}, {"start": 3052.53, "end": 3053.15, "word": " لا؟", "probability": 0.674560546875}, {"start": 3053.15, "end": 3053.43, "word": " بعد", "probability": 0.90087890625}, {"start": 3053.43, "end": 3053.87, "word": " هيك", "probability": 0.9150390625}, {"start": 3053.87, "end": 3054.97, "word": " هنتوسع", "probability": 0.9034423828125}, {"start": 3054.97, "end": 3055.11, "word": " في", "probability": 0.9599609375}, {"start": 3055.11, "end": 3055.47, "word": " الموضوع", "probability": 0.9984130859375}, {"start": 3055.47, "end": 3055.63, "word": " يعني", "probability": 0.7353515625}, {"start": 3055.63, "end": 3055.89, "word": " يمكن", "probability": 0.843017578125}, {"start": 3055.89, "end": 3056.17, "word": " بدنا", "probability": 0.6966552734375}, {"start": 3056.17, "end": 3056.31, "word": " في", "probability": 0.921875}, {"start": 3056.31, "end": 3056.39, "word": " ال", "probability": 0.96875}, {"start": 3056.39, "end": 3056.87, "word": " acidity", "probability": 0.7900390625}, {"start": 3056.87, "end": 3057.23, "word": " كمان", "probability": 0.9446614583333334}, {"start": 3057.23, "end": 3057.51, "word": " نص", "probability": 0.96142578125}, {"start": 3057.51, "end": 3057.99, "word": " ساعة", "probability": 0.9703776041666666}, {"start": 3057.99, "end": 3058.43, "word": " ان", "probability": 0.6279296875}, {"start": 3058.43, "end": 3058.63, "word": " شاء", "probability": 0.984619140625}, {"start": 3058.63, "end": 3058.71, "word": " الله", "probability": 0.95556640625}, {"start": 3058.71, "end": 3058.87, "word": " في", "probability": 0.95849609375}, {"start": 3058.87, "end": 3059.57, "word": " المحاضرة", "probability": 0.982177734375}, {"start": 3059.57, "end": 3060.59, "word": " القادمة", "probability": 0.9871419270833334}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 3062.73525, "duration_after_vad": 2914.815624999988}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8928c196b1a33cb82cdb1088d358d58eccc18bbd
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk.srt
@@ -0,0 +1,2035 @@
+1
+00:00:08,820 --> 00:00:14,060
+إذا بتسمحوا آخر
+
+2
+00:00:14,060 --> 00:00:19,200
+نقطة المرة الماضية تكلمنا عنها كانت إضافة الماء 
+
+3
+00:00:19,200 --> 00:00:24,140
+للالكينز وقولنا إنه في عدة طرق من خلالها تتم
+
+4
+00:00:24,140 --> 00:00:28,510
+عملية إضافة الماء، الطريقة الأولى إضافة الماء في
+
+5
+00:00:28,510 --> 00:00:34,170
+وجود حامض اللي سمّناه احنا acid-catalyzed hydration
+
+6
+00:00:34,170 --> 00:00:38,910
+of alkenes إذا بنذكر في الكلام اللي حكيناه قولنا
+
+7
+00:00:38,910 --> 00:00:44,030
+وظيفة الحامض أنه يبدأ التفاعل، الحامض اللي بيعطينا 
+
+8
+00:00:44,030 --> 00:00:48,290
+الـ H plus وظيفته أنه يبدأ التفاعل، بتتحرك ال
+
+9
+00:00:48,290 --> 00:00:54,390
+double bond بهذا الشكل بتضيف هنا بتترك عندنا 
+
+10
+00:00:54,390 --> 00:00:58,970
+Carbocation موجب، بتترك إنه Carbocation موجب،
+
+11
+00:00:58,970 --> 00:01:03,310
+الـ Carbocation الموجب هذا بعد هيك بتضيف عليه الميه 
+
+12
+00:01:03,310 --> 00:01:08,010
+وبتفقد بروتون، فبيصير في المحصلة إضافة هيدروجين 
+
+13
+00:01:08,010 --> 00:01:15,430
+OH واضح؟ إذا المحصلة هي إضافة إيش؟ ماء، المحصلة لإضافة
+
+14
+00:01:15,430 --> 00:01:19,830
+ماء، كان التساؤل .. كان التساؤل أنه أنا في عندي
+
+15
+00:01:19,830 --> 00:01:23,510
+احتمالين لحركة الـ double bond يعني كان ممكن الـ
+
+16
+00:01:23,510 --> 00:01:27,050
+double bond تتحرك بهذا الشكل وتعمل Carbocation
+
+17
+00:01:27,050 --> 00:01:30,530
+على هذه الكربونة أو تتحرك بهذا الشكل وتعمل
+
+18
+00:01:30,530 --> 00:01:35,110
+Carbocation على هذه الكربونة، واضح السؤال ليش
+
+19
+00:01:35,110 --> 00:01:40,670
+بتتحرك باتجاه معين مش بالاتجاه الثاني، الآن إذا هذا 
+
+20
+00:01:40,670 --> 00:01:45,910
+الكلام بدنا نأكده، خلينا نقول ال .. نوضح الاحتمالين
+
+21
+00:01:45,910 --> 00:01:50,410
+هدول بالظبط، لما نيجي نتخيل أنه عندنا هذا الألكين و
+
+22
+00:01:50,410 --> 00:01:53,870
+بدنا نضيف عليه H plus، هذا الـ H plus اللي لونه
+
+23
+00:01:53,870 --> 00:01:59,250
+أحمر، من وين جاية؟ جاية من الحامض، الـ H plus هذه
+
+24
+00:01:59,250 --> 00:02:04,690
+ممكن تضيف على هذا الطرف وبالتالي تعمل أيون كربون
+
+25
+00:02:04,690 --> 00:02:10,220
+موجب على أي كربون؟ على الكربون الأولى، وممكن تضيف 
+
+26
+00:02:10,220 --> 00:02:14,800
+على هذا الطرف وبالتالي تعمل أيون كربون موجب على
+
+27
+00:02:14,800 --> 00:02:19,520
+هذا الكربون، واضح؟ هي الاحتمالين إنه كأنه هذه
+
+28
+00:02:19,520 --> 00:02:25,500
+اتحركت بهذا الشكل أو هذه اتحركت بهذا الشكل، الآن
+
+29
+00:02:25,500 --> 00:02:30,380
+إذا بنيجي بنطلع احنا على أيون الكربون اللي اتكون
+
+30
+00:02:30,380 --> 00:02:36,380
+لاحظوا هنا، هذه الكربون متصلة بكم كربون؟ متصلة بـ H
+
+31
+00:02:36,380 --> 00:02:41,000
+و H وبكربون واحدة، بناء على ذلك بنسمّي أيون 
+
+32
+00:02:41,000 --> 00:02:46,420
+الكربون تبعها الـ primary Carbocation، يعني أيون 
+
+33
+00:02:46,420 --> 00:02:53,360
+كربون موجب أول، يعني متصل بكم كربون؟ بواحدة، الآن لو 
+
+34
+00:02:53,360 --> 00:02:57,500
+صار عندنا الشغل التاني، هذه الكربون اللي هنا اللي 
+
+35
+00:02:57,500 --> 00:03:00,620
+بتحمل الـ positive charge متصلة بكم كربون؟
+
+36
+00:03:03,650 --> 00:03:07,990
+بناء على ذلك هذا الـ Carbocation بيكون اسمه
+
+37
+00:03:07,990 --> 00:03:12,310
+secondary Carbocation، واضح؟ إذا الأيون الموجب 
+
+38
+00:03:12,310 --> 00:03:16,850
+ممكن يكون primary يعني الكربون متصلة بكربون 
+
+39
+00:03:16,850 --> 00:03:21,030
+واحدة، ممكن يكون secondary يعني الكربون متصلة
+
+40
+00:03:21,030 --> 00:03:27,010
+بكاربونين، الآن بعد هيك بتيجي الميه تضيف، إذا كان
+
+41
+00:03:27,010 --> 00:03:31,590
+الـ positive موجود عندنا هنا، بدي أضيف الميه وتفقد
+
+42
+00:03:31,590 --> 00:03:36,870
+H plus بيصير عندي OH، ملاحظين أنتو؟ لاحظوا في إضافة 
+
+43
+00:03:36,870 --> 00:03:41,370
+الميه، طلعوا على الألوان كويس، الـ H من وين إجت؟ من
+
+44
+00:03:41,370 --> 00:03:46,770
+الحامض، الـ OH من وين إجت؟ من الميه، فالـ H OH ما إجتش
+
+45
+00:03:46,770 --> 00:03:51,690
+من الميه، الـ H إجت من الحمض والـ OH إجت من الميه، لو
+
+46
+00:03:51,690 --> 00:03:56,230
+هذا التفاعل بده يكمل هنا، بده يجي محل الـ positive
+
+47
+00:03:56,230 --> 00:04:00,770
+في نهاية OH وتطلع H plus اللي بتخلي سلسلة التفاعل
+
+48
+00:04:00,770 --> 00:04:06,070
+تستمر، الواقع اللي بيصير إن هذا الناتج لا يتكون
+
+49
+00:04:07,280 --> 00:04:10,820
+واضح؟ الناتج اللي بيمر من خلال الـ primary
+
+50
+00:04:10,820 --> 00:04:14,540
+Carbocation ما بتكونش، بتكون الناتج اللي بيمر من خلال
+
+51
+00:04:14,540 --> 00:04:19,340
+الـ secondary Carbocation هنا بتكونوا، تلاحظوا نقطة 
+
+52
+00:04:19,340 --> 00:04:26,610
+كتير مهمة، إن هذا التفاعل كام خطوة؟ خطوتين أساسيتين
+
+53
+00:04:26,610 --> 00:04:29,690
+الخطوة الأولى إضافة لبروتون، الخطوة الثانية
+
+54
+00:04:29,690 --> 00:04:36,150
+أكمل التفاعل، أي خطوة هي اللي بتتحمل أو يعني مسئولة 
+
+55
+00:04:36,150 --> 00:04:42,340
+عن تحديد وين تيجي الـ H ووين تيجي الـ OH؟ هل هي الخطوة 
+
+56
+00:04:42,340 --> 00:04:45,900
+الأولى ولا الخطوة الثانية؟ الخطوة الأولى، لأن الخطوة
+
+57
+00:04:45,900 --> 00:04:50,260
+الأولى فيها اختيار، يعني هنا الـ H plus واقفة في 
+
+58
+00:04:50,260 --> 00:04:53,420
+عنده احتمالين، إما هذا الاحتمال أو هذا الاحتمال
+
+59
+00:04:53,420 --> 00:04:57,520
+مظبوط ولا لا؟ لكن لو صار هذا الاحتمال، الـ H two أولى
+
+60
+00:04:57,520 --> 00:05:01,350
+ما عندها تيجي فيش هنا غير احتمال واحد، غير مكان واحد
+
+61
+00:05:01,350 --> 00:05:05,570
+هنا تيجي عليه، واضح؟ فاللي بيتحكم في التفاعل من 
+
+62
+00:05:05,570 --> 00:05:13,170
+ناحية وين موضع الإضافة هو حقيقة الخطوة الأولى مش
+
+63
+00:05:13,170 --> 00:05:18,190
+الخطوة الثانية، الخطوة الثانية ملزمة، تحصيل حاصل،
+
+64
+00:05:18,190 --> 00:05:21,830
+واضح؟ تماما هذا الكلام لو بدّي .. يعني أعمل لكم
+
+65
+00:05:21,830 --> 00:05:26,050
+تشبيه عشان تفهموه، لو افترضنا مثلا إنه في طالبات
+
+66
+00:05:26,050 --> 00:05:30,910
+مغتربات إجوا بدهم يسكنوا في سكن طالبة، تسكن غرفتين 
+
+67
+00:05:30,910 --> 00:05:37,790
+واضح؟ إجت أول طالبة وصلت السكن الساعة سبعة الصبح و
+
+68
+00:05:37,790 --> 00:05:41,690
+بدها تحط أغراضها في غرفة، الآن هي عندها غرفتين، هي
+
+69
+00:05:41,690 --> 00:05:45,890
+بتختار ولا لأ؟ هي بتختار، عندها احتمال تحط هنا أو
+
+70
+00:05:45,890 --> 00:05:50,650
+تحط هنا، حطّت أغراضها في هذه الغرفة الساعة عشرة، إجت
+
+71
+00:05:50,650 --> 00:05:56,640
+زميلتها، في عندها اختيار؟ إجت المكان الأول مشغول فأصبحت
+
+72
+00:05:56,640 --> 00:05:59,340
+ملزمة بالمكان الثاني، فعملية الاختيار، شو اللي 
+
+73
+00:05:59,340 --> 00:06:03,230
+بيحكمها؟ الخطوة الأولى مش الخطوة الثانية، الآن 
+
+74
+00:06:03,230 --> 00:06:08,410
+بيضل السؤال قائم، ليش في الخطوة الأولى الهيدروجين
+
+75
+00:06:08,410 --> 00:06:13,670
+الفضل ييجي هنا وبالتالي يعمل secondary Carbocation
+
+76
+00:06:13,670 --> 00:06:18,330
+من إنه ييجي هنا ويعمل primary Carbocation، هذا
+
+77
+00:06:18,330 --> 00:06:21,850
+الكلام متعلق في إيش؟ بنسمّيه الـ stability of
+
+78
+00:06:21,850 --> 00:06:26,010
+Carbocation، ثبات الـ Carbocation، واضح؟
+
+79
+00:06:28,220 --> 00:06:31,860
+ثبات الكربوكاتيون، بالشكل اللي موجود عندنا فوق 
+
+80
+00:06:31,860 --> 00:06:37,160
+الـ tertiary Carbocation اللي متصل بتلت كربونات، بيكون 
+
+81
+00:06:37,160 --> 00:06:42,660
+أثبت من الـ secondary، أثبت من الـ primary، أثبت من الـ
+
+82
+00:06:42,660 --> 00:06:46,100
+CH3 اللي مش متصل ولا بكربونات، الـ methyl Carbocation
+
+83
+00:06:46,100 --> 00:06:50,300
+واضح؟ إذا the stability of Carbocation's tertiary
+
+84
+00:06:50,300 --> 00:06:52,620
+is more stable than the secondary is more stable
+
+85
+00:06:52,620 --> 00:06:58,520
+than the primary، ممكن واحد تسأل ليش؟ واضح؟ هذه
+
+86
+00:06:58,520 --> 00:07:02,300
+النتيجة إنه احنا علميا بنقول الـ tertiary
+
+87
+00:07:02,300 --> 00:07:06,740
+Carbocation أثبت من الـ secondary والـ secondary
+
+88
+00:07:06,740 --> 00:07:12,240
+أثبت من الـ primary، والشيء الثابت هو اللي إيش؟ هو
+
+89
+00:07:12,240 --> 00:07:16,880
+اللي بيتكون، صارت الشغلة سهلة، لكن ليش الـ tertiary
+
+90
+00:07:16,880 --> 00:07:20,700
+أثبت من الـ secondary والـ secondary أثبت من الـ
+
+91
+00:07:20,700 --> 00:07:25,680
+primary؟ واضح السؤال؟ ثبات الشحنة دائما يكون
+
+92
+00:07:25,680 --> 00:07:26,680
+بتقليلها
+
+93
+00:07:31,890 --> 00:07:39,930
+أي شحنة بدنا نثبتها لازم تكون قليلة، إذا زادت
+
+94
+00:07:39,930 --> 00:07:47,710
+الشحنة قلّ الثبات، وإذا قلت الشحنة زاد الثبات، واضح؟
+
+95
+00:07:47,710 --> 00:07:52,470
+هذا الكلام قاعدة عامة، حتى لو كنتوا يعني بدكم تحكوا
+
+96
+00:07:52,470 --> 00:07:56,170
+في موضوع الغضب، اعتبروا الغضب شحنة، اعتبروا الغضب
+
+97
+00:07:56,170 --> 00:07:59,890
+شحنة، الآن اللي عنده شحنة عالية من الغضب، بيكون 
+
+98
+00:07:59,890 --> 00:08:04,200
+ثابت ولا بيقاتل في حاله؟ بيكون مش ثابت .. unstable
+
+99
+00:08:04,200 --> 00:08:08,480
+.. واضح .. حتى لما بيروح بيتعالج .. إيش بيسووا؟
+
+100
+00:08:08,480 --> 00:08:11,860
+بيقللوا الشحنة اللي عنده .. البني آدم اللي بيقولوا
+
+101
+00:08:11,860 --> 00:08:15,300
+بتزيد عنده الكهربا .. بتشوفوا كيف بعض الناس عندهم
+
+102
+00:08:15,300 --> 00:08:18,720
+مشكلة .. زيادة الكهربا .. هذه زيادة الشحنة بتعمل
+
+103
+00:08:18,720 --> 00:08:22,980
+ثابت ولا عدم ثابت؟ بتعمل عدم ثابت .. وقت إيش بيصير
+
+104
+00:08:22,980 --> 00:08:29,520
+الثابت؟ إذا قلت الشحنة .. إذا قلت الشحنة .. واضح
+
+105
+00:08:29,520 --> 00:08:33,700
+كيف؟ عشان يك .. حتى البني آدم .. حتى البني آدم لو
+
+106
+00:08:33,700 --> 00:08:39,420
+عنده شحنة حزن مثلا .. أي شخص كان عنده مناسبة توفى
+
+107
+00:08:39,420 --> 00:08:43,260
+قريب أو عزيزه .. صار عنده شحنة كبيرة من الحزن .. 
+
+108
+00:08:43,260 --> 00:08:48,240
+إيش الناس بيعملوا؟ بيجوا بعزوه، لما بيجوا بعزوه إيش
+
+109
+00:08:48,240 --> 00:08:52,740
+بيسووا؟ كأنه هذا أخذ منه شوية حزن وهذا أخذ شوية وهذا
+
+110
+00:08:52,740 --> 00:08:56,320
+أخذ شوية وهذا أخذ شوية، واضح؟ أو اللي عنده
+
+111
+00:08:56,320 --> 00:09:01,240
+مصيبة كبيرة مثلا نفترض داره انهدت بالحرب، بيجي هذا 
+
+112
+00:09:01,240 --> 00:09:05,700
+بيجيب له مساعدة، هذا بيعمله هذا بيعمله، فإيش بيصير
+
+113
+00:09:05,700 --> 00:09:10,680
+لشحنة اللي عنده؟ بتقل، الكلام نفسه بتكرر في الـ
+
+114
+00:09:10,680 --> 00:09:17,100
+positive charge، الـ R group بتعطي إلكترونات لما أكون
+
+115
+00:09:17,100 --> 00:09:20,380
+عندي positive charge، افترضوا هذا الـ positive بس
+
+116
+00:09:20,380 --> 00:09:26,500
+كعدد عشوائي إنه عشر وحدات، عشر وحدات هذه تمثل إيش
+
+117
+00:09:26,500 --> 00:09:31,680
+ثقل أو شحنة، الآن لما تيجي الـ R group، الـ R group
+
+118
+00:09:31,680 --> 00:09:38,500
+بتعطي إلكترونات يعني بتعطي إيش؟ بتعطي سالب، السالب شو
+
+119
+00:09:38,500 --> 00:09:42,680
+بيعمل في الموجب؟ بيقلله، يعني لو افترضت إنه شحنة
+
+120
+00:09:42,680 --> 00:09:46,500
+الموجب بعشر وحدات، إجت أي شيء ساعده، لما يكون عنده
+
+121
+00:09:46,500 --> 00:09:50,780
+تلت هيدروجينات لأ، طيب لو افترضنا إن الـ R group
+
+122
+00:09:50,780 --> 00:09:55,720
+بتعطي اثنين سالب وهذه عشرة موجة، شو بتعمل الـ R 
+
+123
+00:09:55,720 --> 00:09:59,440
+group في الموجب في هذه الحالة؟ بتعدّل اثنين منه، كم 
+
+124
+00:09:59,440 --> 00:10:03,160
+بيصفي الموجب؟ ثمانية، إذا هنا الموجب قلت، هنا الشحنة
+
+125
+00:10:03,160 --> 00:10:09,680
+قلت، طيب، لو كان عندي اثنين R-groups، إيش بيصير
+
+126
+00:10:09,680 --> 00:10:12,880
+لشحنة الموجب بقى؟ بتقل أكثر وأكثر، يعني لو افترضت
+
+127
+00:10:12,880 --> 00:10:17,340
+هذه عشرة، وهذه نقصت اثنين، عدلت اثنين، وهذه عدّلت 
+
+128
+00:10:17,340 --> 00:10:21,760
+اثنين، كم بيصفي الموجب؟ ستة، إذا، قاعد التباك بيزيد،
+
+129
+00:10:21,760 --> 00:10:27,360
+لو افترضت هنا ثلاث مجموعات R، ترضوا هذه عشرة هذه بتعطي
+
+130
+00:10:27,360 --> 00:10:30,240
+اثنين سالب واثنين سالب واثنين سالب، كده إيش ضلّ 
+
+131
+00:10:30,240 --> 00:10:35,320
+الموجب عنده؟ أربعة، إذا الموجب عمله بيقلّ، كأن أنا بقدر
+
+132
+00:10:35,320 --> 00:10:39,660
+أقول إن الـ electron donating groups المجموعات
+
+133
+00:10:39,660 --> 00:10:44,020
+المعطية للإلكترونات، المعطية للشحنة السالبة ماذا
+
+134
+00:10:44,020 --> 00:10:46,960
+تفعل في شحنة الموجبة؟ decreases
+
+135
+00:11:02,800 --> 00:11:06,380
+معنى شحنة قلت شحنة صارت more stable
+
+136
+00:11:09,360 --> 00:11:14,660
+معنى إن هالشحنة قلت إنه شحنة صارت more stable، إذا
+
+137
+00:11:14,660 --> 00:11:19,620
+قدرنا نفهم إيش سبب هذا الـ trend of stability إنه
+
+138
+00:11:19,620 --> 00:11:22,160
+الـ tertiary is more stable than the secondary is
+
+139
+00:11:22,160 --> 00:11:25,800
+more stable than the primary because of the 
+
+140
+00:11:25,800 --> 00:11:32,100
+presence of more electron donating groups، بسبب 
+
+141
+00:11:32,100 --> 00:11:37,600
+وجود مجموعات معطية للإلكترونات، بتقلل الـ positive
+
+142
+00:11:37,600 --> 00:11:43,640
+charge، واضح؟ الآن في عندي شغلة مهمة جدا، الـ
+
+143
+00:11:43,640 --> 00:11:46,500
+rate of formation of Carbocation زي ما هي الـ 
+
+144
+00:11:46,500 --> 00:11:50,000
+stability of Carbocation، الـ tertiary أفضل من
+
+145
+00:11:50,000 --> 00:11:53,120
+الـ secondary أفضل من الـ primary، سرعة التكوين بتكون
+
+146
+00:11:53,120 --> 00:11:57,900
+حسب الثبات، برضه الـ tertiary أفضل من الـ secondary
+
+147
+00:11:57,900 --> 00:12:03,200
+أفضل من الـ primary، واضح هذا الكلام، بناء على ذلك
+
+148
+00:12:03,200 --> 00:12:07,200
+بنقدر نفهم الكلام اللي في الـ slide السابق ببساطة، 
+
+149
+00:12:07,200 --> 00:12:13,340
+ليش بتكون هذا مش هذا؟ لأن هنا الـ Carbocation primary
+
+150
+00:12:13,340 --> 00:12:17,880
+هنا الـ Carbocation secondary، the more stable 
+
+151
+00:12:17,880 --> 00:12:22,890
+secondary Carbocation will form، الـ Carbocation اللي
+
+152
+00:12:22,890 --> 00:12:26,890
+هو more stable، الـ secondary بتكون، الآن الخطوة اللي
+
+153
+00:12:26,890 --> 00:12:33,030
+بعديها تحصل حاصل، أكمل التفاعل، لكن التفاعل وين
+
+154
+00:12:33,030 --> 00:12:38,290
+انحكم؟ the reaction is controlled by the first or by
+
+155
+00:12:38,290 --> 00:12:43,870
+the second step؟ by the first step، واضح؟ التفاعل
+
+156
+00:12:43,870 --> 00:12:48,390
+بينحكم بالخطوة الأولى، إنه إيش اللي أثبت بتكون
+
+157
+00:12:50,880 --> 00:12:56,440
+Stability أو ثبات، واضح؟ الآن لو في تفاعل ثاني كنت 
+
+158
+00:12:56,440 --> 00:13:01,020
+بعمل إضافة وعندي تنافس ما بين إمكانية tertiary
+
+159
+00:13:01,020 --> 00:13:06,140
+-Carbocation و secondary، الهيدروجين بيضيف بحيث يكون
+
+160
+00:13:06,140 --> 00:13:10,500
+الـ tertiary-Carbocation مش الـ secondary، الهيدروجين
+
+161
+00:13:10,500 --> 00:13:16,450
+بيضيف بحيث يكون الـ tertiary-Carbocation، هنا ابتدينا
+
+162
+00:13:16,450 --> 00:13:24,630
+شغلة إضافية والحقيقة جميلة جدا، لو بدنا نطلع على
+
+163
+00:13:24,630 --> 00:13:28,710
+المثال هذا، لو بدنا نطلع على المثال هذا عندكم CH2
+
+164
+00:13:28,710 --> 00:13:38,320
+CH وهنا CH3 CH3، لو قلنا بدنا نضيف H Plus زي ما 
+
+165
+00:13:38,320 --> 00:13:42,000
+اتفقنا، الـ H plus ممكن تيجي على هذا الموقع تكون
+
+166
+00:13:42,000 --> 00:13:46,040
+لإيش؟ secondary Carbocation، أو تيجي على هذا الموقع
+
+167
+00:13:46,040 --> 00:13:49,600
+تكون primary Carbocation، وبعد هيك الـ reaction
+
+168
+00:13:49,600 --> 00:13:54,840
+يكتمل، الآن من أول لحظة secondary ولا primary؟
+
+169
+00:13:54,840 --> 00:13:59,630
+secondary، إذا هذا الاحتمال ألغى اللي بتكون عندي الـ
+
+170
+00:13:59,630 --> 00:14:04,590
+secondary، لاحظوا هنا الـ secondary، هتلاحظوا فيه
+
+171
+00:14:04,590 --> 00:14:11,230
+jumbo carbon حاملة CH
+
+201
+00:16:48,000 --> 00:16:53,260
+مكانها هل يتحول secondary ولا tertiary؟ لاحظوا
+
+202
+00:16:53,260 --> 00:17:00,200
+carbon تنتين تلاتة صار tertiary هذه العملية بنسميها
+
+203
+00:17:00,200 --> 00:17:05,540
+rearrangement أو إعادة ترتيب Rearrangement إن الـ
+
+204
+00:17:05,540 --> 00:17:10,760
+H بتنتقل أو الهيدرايد أيون بنتقل بحيث يحول لي إذا 
+
+205
+00:17:10,760 --> 00:17:14,260
+في إمكانية في التفاعل زي هذا المثال ال secondary
+
+206
+00:17:14,260 --> 00:17:20,200
+carbocation إلى tertiary carbocation بعد هيك لما
+
+207
+00:17:20,200 --> 00:17:24,710
+بتيجي المياه تضيف، بتضيف مكان الموجة في مكان ال
+
+208
+00:17:24,710 --> 00:17:30,150
+tertiary تحط OH لاحظوا هنا ال H اللي ضفناها وين
+
+209
+00:17:30,150 --> 00:17:36,360
+أجت؟ على موقع واحد، ال OH اللي من المية موقع تلاتة
+
+210
+00:17:36,360 --> 00:17:40,820
+ملاحظين يعني بدل ما تيجي ال H هنا و ال O H هنا
+
+211
+00:17:40,820 --> 00:17:45,400
+بتلاحظوا أن ال O H نقلت موقعها هذه عملية ال
+
+212
+00:17:45,400 --> 00:17:49,140
+rearrangement أو إعادة الترتيب اللي موجودة في
+
+213
+00:17:49,140 --> 00:17:53,820
+الجزء ليش تم تقول هذه العملية عملية إعادة الترتيب؟
+
+214
+00:17:53,820 --> 00:18:00,540
+عشان ننتقل من ال secondary carbocation إلى الـ
+
+215
+00:18:00,540 --> 00:18:03,700
+tertiary carbocation عشان ننتقل من 
+
+216
+00:18:03,700 --> 00:18:08,160
+ال secondary carbocation إلى tertiary carbocation بتم 
+
+217
+00:18:08,160 --> 00:18:12,340
+هنا rearrangement من خلال عملية إيش بنسميها؟
+
+218
+00:18:12,340 --> 00:18:18,260
+Hydride shift يعني تحرك هيدروجين مع إلكتروناته
+
+219
+00:18:18,260 --> 00:18:23,920
+كلام منطقي ليش؟ لأن هذا موجب، الموجب إيش بيكون بده؟
+
+220
+00:18:23,920 --> 00:18:29,400
+بده سالب إيش السالب؟ الهيدروجين و إلكتروناته هما
+
+221
+00:18:29,400 --> 00:18:34,240
+السالب هما ال أيون الهيدروجين مع الإلكترونات تبعته
+
+222
+00:18:38,050 --> 00:18:42,330
+من مميزات ال Acid Catalyzed Addition of Water أنه
+
+223
+00:18:42,330 --> 00:18:45,910
+في إمكانية طالما بتكون عندي Carbocation في إمكانية 
+
+224
+00:18:45,910 --> 00:18:49,530
+لل rearrangement معنى إمكانية ال rearrangement أنه
+
+225
+00:18:49,530 --> 00:18:54,390
+ممكن ال secondary يصير أحيانا في أمثلة معينة فيها
+
+226
+00:18:54,390 --> 00:18:58,910
+primary برضه ممكن يتحول إلى tertiary واضح؟ هنا
+
+227
+00:18:58,910 --> 00:19:04,450
+عملية ال rearrangement تمت من خلال إيش؟ الحقيقة
+
+228
+00:19:04,450 --> 00:19:08,810
+اللي لاحظوا إنه مش بس من خلال ال hydride shift
+
+229
+00:19:08,810 --> 00:19:12,330
+يعني لو إنه بدل ما عندي هنا hydrogen خلتها دول
+
+230
+00:19:12,330 --> 00:19:16,690
+تلاتة methyls لاحظوا المثال السابق هدى إيش كانت؟
+
+231
+00:19:17,340 --> 00:19:22,460
+أتش خلّيتهم تلاتة مثلًا لو الآن بدأ أضيف H بلاص زي
+
+232
+00:19:22,460 --> 00:19:25,720
+ما اتفقنا يا بنضيفها هنا بنكون primary يا بنضيفها
+
+233
+00:19:25,720 --> 00:19:30,420
+هنا بنكون secondary أن هو الاحتمال الملغي ال
+
+234
+00:19:30,420 --> 00:19:35,700
+primary بيظل عنده ال secondary الآن بالإمكان تتحرك
+
+235
+00:19:35,700 --> 00:19:42,940
+مجموعة CH3 كاملة مع إلكتروناتها كل CH3 تنتقل هذه
+
+236
+00:19:42,940 --> 00:19:48,000
+بنسميها إيش إحنا ال methyl shift لما كانت H مع
+
+237
+00:19:48,000 --> 00:19:53,160
+إلكتروناتها hydride shift لما تكون CH3 مع إلكتروناتها
+
+238
+00:19:53,160 --> 00:19:58,800
+ال methyl shift واضح؟ ممكن يصير عنده ال methyl shift تنتقل كل ال
+
+239
+00:19:58,800 --> 00:20:01,700
+CH3 هان لحظة الجزء كله بتغير و ال positive وين
+
+240
+00:20:01,700 --> 00:20:06,080
+بيصير؟ هان عشان هذا tertiary carbocation بعدين لما
+
+241
+00:20:06,080 --> 00:20:10,690
+الميه بتضيف تحط OH وين بتحطها؟ عادة الموقع، لاحظوا 
+
+242
+00:20:10,690 --> 00:20:14,010
+كده إعادة الترتيب اللي صارت في الجزيرة، إن الـ H
+
+243
+00:20:14,010 --> 00:20:19,210
+أجت هنا كويس، الـ OH ماجتش جنبها، انتقلت الـ CH3
+
+244
+00:20:19,210 --> 00:20:22,070
+و الـ OH أجت على الموقع اللي بعدها، هذه عملية 
+
+245
+00:20:22,070 --> 00:20:24,830
+rearrangement، هنا ال rearrangement from the
+
+246
+00:20:24,830 --> 00:20:28,550
+secondary carbocation to the tertiary carbocation is
+
+247
+00:20:28,550 --> 00:20:35,220
+through ال methyl shift، واضح؟ ففي ميزة دائما في ال
+
+248
+00:20:35,220 --> 00:20:38,680
+carbocations بزام ال carbocations بتسعى لل stability
+
+249
+00:20:38,680 --> 00:20:44,300
+إذا في إمكانية لإيش؟ لل rearrangement واضح؟ هذا عمر
+
+250
+00:20:44,300 --> 00:20:49,500
+بسيط يعني تماما تماما اتخيلوه بشكل الآتي ممكن يكون
+
+251
+00:20:49,500 --> 00:20:52,720
+عندكوا إحساس أن أفضل ناس عندهم ثبات و بيشوفوا كويس
+
+252
+00:20:52,720 --> 00:20:56,620
+اللي قاعدين هنا واضح؟ لو افترضنا أن الأخت اللي هنا
+
+253
+00:20:56,620 --> 00:21:03,660
+طلعت، شو بيصير؟ بتنجح عملية ال rearrangement إذا
+
+254
+00:21:03,660 --> 00:21:08,020
+الناس دائما بتسعى نحوها مزيد من الثبات ولا لأ؟ تسعى
+
+255
+00:21:08,020 --> 00:21:14,460
+نحوها مزيد من الثبات الآن
+
+256
+00:21:14,460 --> 00:21:20,900
+بنجي لطريقة ثانية غير إضافة الماء في وجود الحامض
+
+257
+00:21:20,900 --> 00:21:28,360
+في طريقة إضافة الماء في وجود الحامض الزئبق وتحديدا
+
+258
+00:21:28,360 --> 00:21:32,700
+المركب اللي احنا بنستعمله اللي اسمه ال mercuric
+
+259
+00:21:32,700 --> 00:21:37,020
+acetate mercuric acetate يعني mercuric acetate
+
+260
+00:21:37,020 --> 00:21:42,480
+اللي بنسميه احنا إيش؟ خلات الزئبق ال acetic acid
+
+261
+00:21:42,480 --> 00:21:48,540
+حمض الخل .. حمض الخل و ال mercuric acetate خلات 
+
+262
+00:21:48,540 --> 00:21:53,700
+الزئبق .. الآن إذا كان في عندي double bond .. إذا
+
+263
+00:21:53,700 --> 00:21:58,270
+كان في عندي double bond ضيفت عليها على خطوتين
+
+264
+00:21:58,270 --> 00:22:03,110
+متتاليتين الخطوة الأولى mercuric acetate في وجود
+
+265
+00:22:03,110 --> 00:22:07,190
+الميه دايب في الميه الخطوة التانية مركب بنسميه
+
+266
+00:22:07,190 --> 00:22:11,510
+sodium borohydride هدولة مع بعض بقالية معينة مش
+
+267
+00:22:11,510 --> 00:22:15,930
+هنتطرق لها حتى ما نتوسعش كتير بضيفوا ميه يعني
+
+268
+00:22:15,930 --> 00:22:21,730
+محصلة هذا ال reagent كله هي عملية إضافة إيش؟ إضافة
+
+269
+00:22:21,730 --> 00:22:27,790
+ميه الآن الميه هنا كيف بتضيف؟ بتضيف حسب قاعدة
+
+270
+00:22:27,790 --> 00:22:34,430
+Markovnikov زي ما الحامض كان يعمل بمعنى على هذا
+
+271
+00:22:34,430 --> 00:22:40,410
+الموقع شو بده يجيني H ولا OH؟ وع هذا الموقع OH ليش
+
+272
+00:22:40,410 --> 00:22:43,350
+هنا بيجيني ال H؟ إذا بتلاحظوا هنا كام هيدروجين
+
+273
+00:22:43,350 --> 00:22:50,070
+عندي؟ في الأساس 10-10 هنا كم هيدروجين عندي؟ واحدة
+
+274
+00:22:50,070 --> 00:22:53,570
+احنا المرة الماضية قلنا إنه في الإضافة في وجود
+
+275
+00:22:53,570 --> 00:22:58,010
+الحامض و أيضا في وجود ال mercuric acetate بتمشي على
+
+276
+00:22:58,010 --> 00:23:02,230
+حسب قاعدة Markovnikov إنه الهيدروجين بتيجي على أي
+
+277
+00:23:02,230 --> 00:23:07,590
+كربون على حاملة هيدروجين أكثر بلاحظين أنتو بناء
+
+278
+00:23:07,590 --> 00:23:12,150
+على ذلك الهيدروجين بتضيف هنا و ال OH بتضيف على هذا
+
+279
+00:23:12,150 --> 00:23:17,900
+الموقع ممكن الآن واحدة تسأل طب إيش هدى بتختلف عن
+
+280
+00:23:17,900 --> 00:23:24,220
+الإضافة في وجود الحامض؟
+
+281
+00:23:24,220 --> 00:23:28,560
+واضح الكلام؟ الإضافة في وجود الحامض Markovnikov
+
+282
+00:23:28,560 --> 00:23:34,620
+addition و الإضافة في وجود الذئبق برضه Markovnikov
+
+283
+00:23:34,620 --> 00:23:40,590
+addition طب إيش ده بتفرق؟ بتفرق أن الإضافة في وجود
+
+284
+00:23:40,590 --> 00:23:46,050
+الذئبق لا يحصل فيها rearrangement،
+
+285
+00:23:46,050 --> 00:23:49,890
+الإضافة في وجود الذئبق ما بيصيرش فيها 
+
+286
+00:23:49,890 --> 00:23:53,130
+rearrangement، بتضيف على طرفي الرابطة الزوجية، 
+
+287
+00:23:53,130 --> 00:23:57,170
+الإضافة في وجود الحامض قبل شوية، لاحظنا أن فيها
+
+288
+00:23:57,170 --> 00:24:03,090
+إيش؟ rearrangement بس في وجود الذئبق ما بيصيرش
+
+289
+00:24:03,090 --> 00:24:07,870
+rearrangement يعني لو رجعنا للمثال السابق اللي 
+
+290
+00:24:07,870 --> 00:24:12,530
+عندنا هنا و بقولنا لكوا هاي هذا المثال بدنا نضيف H
+
+291
+00:24:12,530 --> 00:24:18,650
+plus H to O أعطونا الناتج شو هتعطونا؟ هتعطونا أن ال
+
+292
+00:24:18,650 --> 00:24:22,590
+H بيضيف هنا secondary carbocation بيصير tertiary
+
+293
+00:24:22,590 --> 00:24:27,130
+ال O H بيضيف هنا هاي الناتج طيب لو كنت حاططركم ال 
+
+294
+00:24:27,130 --> 00:24:32,560
+reagent هنا مش H plus زئبق mercuric acetate و ميه و
+
+295
+00:24:32,560 --> 00:24:36,560
+بعدين sodium borohydride شو النتج اللي هتعطونيه؟
+
+296
+00:24:36,560 --> 00:24:41,860
+بده يضيف ال H و ال OH على طرفي الرابطة بحيث أن
+
+297
+00:24:41,860 --> 00:24:45,020
+ال H تيجي على أكتر و ال OH هنا، بده يطلع هذا الناتج
+
+298
+00:24:47,610 --> 00:24:51,410
+واضح؟ يعني لو ال reagent اللي عندي mercuric acetate
+
+299
+00:24:51,410 --> 00:24:55,210
+بدي يطلع هذا الناتج لو ال reagent اللي عندي H plus
+
+300
+00:24:55,210 --> 00:25:00,190
+H2O بدي يطلع هذا الناتج شوفت وين الفرق ما بين 
+
+301
+00:25:00,190 --> 00:25:06,490
+الشغلتين؟ واضح هذا هو الفرق بين إضافة الميه في وجود
+
+302
+00:25:06,490 --> 00:25:09,990
+حامض إنه فيه إمكانية ل rearrangement إضافة الميه
+
+303
+00:25:09,990 --> 00:25:15,370
+في وجود الذئبق لأ بتضيف حسب Markovnikov rule بدون
+
+304
+00:25:15,370 --> 00:25:19,810
+عملية ال rearrangement عشانك حتى لو بترجع يمكن لل
+
+305
+00:25:19,810 --> 00:25:24,650
+slides لل slides بتلاحظوا في عندنا هنا كلمة إنه ال
+
+306
+00:25:24,650 --> 00:25:29,470
+addition Markovnikov regiochemistry is observed إن
+
+307
+00:25:29,470 --> 00:25:33,850
+الإضافة حسب قاعدة Markovnikov وهذا ال reaction
+
+308
+00:25:33,850 --> 00:25:40,870
+إيش ماله؟ Rearrangements do not occur إذا لو احنا
+
+309
+00:25:40,870 --> 00:25:47,770
+كنا بنسألكوا سؤال صح و غلط مثلًا، بنقولكم in the
+
+310
+00:25:47,770 --> 00:25:52,070
+acid-catalyzed hydration of alkenes, rearrangement
+
+311
+00:25:52,070 --> 00:25:53,030
+is possible
+
+312
+00:25:55,370 --> 00:25:58,810
+صح في ال acid catalyzed addition rearrangement is
+
+313
+00:25:58,810 --> 00:26:02,970
+possible in oxymercuration طبعًا هذا بنسمي
+
+314
+00:26:02,970 --> 00:26:06,190
+oxymercuration لأنه بضيف الزئبق و ال oxygen اللي هي
+
+315
+00:26:06,190 --> 00:26:09,430
+إضافة من خلال الزئبق in oxymercuration
+
+316
+00:26:09,430 --> 00:26:13,790
+rearrangement is possible rearrangement does not
+
+317
+00:26:13,790 --> 00:26:18,770
+occur in oxymercuration شفتوا الفرق بين الإضافتين
+
+318
+00:26:18,770 --> 00:26:25,230
+للميه؟ الآن هي هذا مثال لو قلنا لكوا بدنا نضيف عليه
+
+319
+00:26:25,230 --> 00:26:29,410
+mercuric acetate في وجود الميه وبعدين sodium boro
+
+320
+00:26:29,410 --> 00:26:33,930
+hydride الإضافة على طرفي الرابطة لو أنتو بدكوا
+
+321
+00:26:33,930 --> 00:26:36,970
+تحللوا المثال هتلاحظوا أن هنا في شغل مفقود شوي
+
+322
+00:26:36,970 --> 00:26:43,170
+هدي الهيدروجين إذا اللي بده أرسمها هنا بالأحمر هي
+
+323
+00:26:43,170 --> 00:26:46,750
+اللي كانت موجودة أصلا إذا لما بده اضيف الميه اضيف
+
+324
+00:26:46,750 --> 00:26:52,610
+H و OH وين هتيجي ال H؟ على هذه اللي حاملة هيدروجين
+
+325
+00:26:52,610 --> 00:26:56,610
+وين هتيجي ال OH؟ على هذه اللي حاملة هيدروجين وين
+
+326
+00:26:56,610 --> 00:26:56,730
+هتيجي ال OH؟ على هذه اللي حاملة هيدروجين وين هتيجي
+
+327
+00:26:56,730 --> 00:26:57,310
+ال OH؟ على هذه اللي حاملة هيدروجين وين هتيجي ال
+
+328
+00:26:57,310 --> 00:27:00,450
+OH؟ على هذه اللي حاملة هيدروجين وين هتيجي ال OH؟
+
+329
+00:27:00,450 --> 00:27:01,030
+على هذه اللي حاملة هيدروجين وين هتيجي ال OH؟ على
+
+330
+00:27:01,030 --> 00:27:04,130
+هذه اللي حاملة هيدروجين وين هتيجي ال OH؟ على هذه
+
+331
+00:27:04,130 --> 00:27:05,490
+اللي حاملة هيدروجين وين هتيجي ال OH؟ على هذه اللي
+
+332
+00:27:05,490 --> 00:27:09,790
+حاملة هيدروجين وين هتيجي ال OH؟ على هذه اللي حاملة
+
+333
+00:27:09,790 --> 00:27:14,130
+هيدروجين وين هتيجي ال OH؟ على هذه اللي حاملة
+
+334
+00:27:14,130 --> 00:27:19,510
+هيدروجين
+
+335
+00:27:19,510 --> 00:27:26,840
+و هن بحط ال H و هن بحط ال OH طبعًا
+
+336
+00:27:26,840 --> 00:27:30,760
+في هذا المثال الحقيقة ما فيش إمكانية برضه ل
+
+337
+00:27:30,760 --> 00:27:34,120
+rearrangement يعني لو كنت هذا المثال تحديدا بدي
+
+338
+00:27:34,120 --> 00:27:39,460
+أكمل ه في وجود H plus و H to O برضه هيعطي نفس النتجة
+
+339
+00:27:40,250 --> 00:27:43,350
+يعني احنا دائما بنقول إن ال rearrangement possible
+
+340
+00:27:43,350 --> 00:27:46,830
+بس مش دائما ممكن ال rearrangement يعني لما يكون
+
+341
+00:27:46,830 --> 00:27:51,450
+فيه إمكانية إنه أي carbocation يتحسن لشيء أفضل
+
+342
+00:27:51,450 --> 00:27:56,010
+بيصير طب لو ما فيش إمكانية ما بيصيرش يعني لو على هذا
+
+343
+00:27:56,010 --> 00:28:01,870
+المثال أنا كنت بدي أضيف H plus H2O الخطوة الأولى
+
+344
+00:28:01,870 --> 00:28:08,100
+شو هتكون؟ إضافة ال H plus تخيلوا إضافته هنا صار
+
+345
+00:28:08,100 --> 00:28:14,080
+Carbocation هنا شو نوع هذا Carbocation؟
+
+346
+00:28:14,080 --> 00:28:19,280
+طيب tertiary هيعمل rearrangement؟ في أحسن من ال
+
+347
+00:28:19,280 --> 00:28:23,080
+tertiary؟ بناء على ذلك هيكمل بدون rearrangement
+
+348
+00:28:23,080 --> 00:28:26,300
+وبالتالي في هذا المثال تحديدا في هذا المثال
+
+349
+00:28:26,300 --> 00:28:29,760
+تحديدا بأي شكل من الأشكال ضفت أنا
+
+350
+00:28:33,200 --> 00:28:37,800
+بالمركب mercuric acetate بيختلف الناتج لأ بينما لاحظوا
+
+351
+00:28:37,800 --> 00:28:43,240
+لو بدنا نحكي بهذا المثال خليني أكملكم الهيدروجين
+
+352
+00:28:43,240 --> 00:28:49,320
+كلها للجزيء باللون الأحمر وهنا
+
+353
+00:28:49,320 --> 00:28:54,240
+في عندي كمان هيدروجين الآن أول ما بده ييجي أضيف
+
+354
+00:28:54,240 --> 00:28:57,600
+ميه في وجود الحامض مش في وجود الزئبق بتكونوا 
+
+355
+00:28:57,600 --> 00:29:02,950
+تتخيلوا okay لما نقول إن هذا بده يضيف في وجود H
+
+356
+00:29:02,950 --> 00:29:10,370
+plus H2O وين هتيجي الهيدروجين؟ على هذا الموقع واضح
+
+357
+00:29:10,370 --> 00:29:13,650
+هاي الهيدروجين أجت على هذا الموقع ال double bond
+
+358
+00:29:13,650 --> 00:29:19,550
+راحت و شو صار عندي هنا انتبهوا معي لسه carbocation
+
+359
+00:29:19,550 --> 00:29:26,930
+هذا ال carbocation إذا بتطلع عليه في
+
+360
+00:29:26,930 --> 00:29:32,090
+إمكانية إنه ينقل H إنه يعمل rearrangement هذا نفس
+
+361
+00:29:32,090 --> 00:29:36,610
+المثال السابق اللي احنا شرحناه لكوا واضح؟ بتلاقي
+
+362
+00:29:36,610 --> 00:29:41,790
+ال methyl هنا و أين بتيجي ال OH بيصير ال positive
+
+363
+00:29:41,790 --> 00:29:45,670
+هنا و ال OH بتيجي هنا مثل هذه المعادلة، لو كنا
+
+364
+00:29:45,670 --> 00:29:52,410
+جايلين أكمل المعادلة في وجود H plus H2O، شو
+
+365
+00:29:52,410 --> 00:29:56,230
+الناتج اللي بتتوقعوه؟ مش اللي أنتو شايفينه على
+
+366
+00:29:56,230 --> 00:29:56,530
+اللوحة
+
+367
+00:30:00,950 --> 00:30:05,470
+هنا هتيجي ال H في البداية تكون carbocation على هذا
+
+368
+00:30:05,470 --> 00:30:11,790
+الموقع secondary بينقل هاي
+
+369
+00:30:11,790 --> 00:30:17,340
+الناتج شوفتوا الفرق بين الطريقتين؟ إذا في هذا
+
+370
+00:30:17,340 --> 00:30:23,100
+المثال يختلف عندي إذا أضيف الميه باستعمال الحامض
+
+371
+00:30:23,100 --> 00:30:26,760
+أو باستعمال الذئبق باستعمال الذئبق لا يوجد نقاش
+
+372
+00:30:26,760 --> 00:30:32,000
+أتيت ال H هنا و ال O هنا التفاعل هذا لا يوجد فيه
+
+373
+00:30:32,000 --> 00:30:35,980
+rearrangement على طرفي الرامض لا يوجد 
+
+374
+00:30:35,980 --> 00:30:40,200
+rearrangement في وجود الحامض أول ما تأتي ال H هنا
+
+375
+00:30:40,200 --> 00:30:45,490
+و تعمل positive شو بي
+
+401
+00:32:25,170 --> 00:32:25,190
+plus و H plus و H plus و H plus و H plus و H plus
+
+402
+00:32:25,190 --> 00:32:25,210
+plus و H plus و H plus و H plus و H plus و H plus
+
+403
+00:32:25,210 --> 00:32:34,790
+و H plus و H plus و الآن في طريقة ثالثة لإضافة 
+
+404
+00:32:34,790 --> 00:32:41,090
+الماء طريقة
+
+405
+00:32:41,090 --> 00:32:47,710
+إضافة الماء الثالثة بنسميها hydroboration of an
+
+406
+00:32:47,710 --> 00:32:52,510
+alkene with oxidative workup أو مرات بيسموها
+
+407
+00:32:52,510 --> 00:32:57,110
+hydroboration oxidation واضح؟  إيش معناه 
+
+408
+00:32:57,110 --> 00:33:02,030
+hydroboration؟ في عندي عنصر في الجدول الدوري اللي
+
+409
+00:33:02,030 --> 00:33:08,610
+اسمه ال boron عارفينه؟ العنصر اللي بيجي بعد ال
+
+410
+00:33:08,610 --> 00:33:12,990
+helium ثالث عنصر مش عندي أول عنصر ال hydrogen
+
+411
+00:33:12,990 --> 00:33:21,640
+الثاني ال helium الثالث ال boron البورون موجود منه
+
+412
+00:33:21,640 --> 00:33:30,060
+مركب مع ثلاثة هيدروجين بورين BH3 مركب بورين
+
+413
+00:33:30,060 --> 00:33:34,000
+BH3 مركب
+
+414
+00:33:34,000 --> 00:33:41,500
+بورين BH3 مركب بورين BH3 مركب بورين BH3 مركب
+
+415
+00:33:41,500 --> 00:33:45,440
+بورين BH3 مركب بورين BH3 مركب بورين BH3 مركب
+
+416
+00:33:45,440 --> 00:33:47,960
+بورين BH3 مركب بورين BH3 مركب بورين BH3 مركب
+
+417
+00:33:47,960 --> 00:33:48,280
+بورين BH3 مركب بورين BH3 مركب بورين BH3 مركب
+
+418
+00:33:48,280 --> 00:33:53,280
+بخطوة أولى وبعدين بالخطوة الثانية ضفنا له H2O2
+
+419
+00:33:53,280 --> 00:33:57,020
+ماء الأكسجين اللي بنسميها احنا إيش hydrogen
+
+420
+00:33:57,020 --> 00:34:04,800
+peroxide في basic medium في OH minus بضيف برضه 
+
+421
+00:34:04,800 --> 00:34:09,080
+بالمحصلة ماء لاحظوا هذه الأشياء عشان تحفظوا
+
+422
+00:34:09,080 --> 00:34:16,170
+أسماءها ال BH3 عبارة عن إيش؟ البورين ال THF هذا عبارة
+
+423
+00:34:16,170 --> 00:34:25,230
+عن solvent مذيب solvent ال H2O2 هيدروجين بيروكسايد
+
+424
+00:34:25,230 --> 00:34:28,870
+فوق أكسيد الهيدروجين هيدروجين بيروكسايد و ال OH
+
+425
+00:34:28,870 --> 00:34:33,570
+minus معنى ذلك أن التفاعل يتم في basic medium كل
+
+426
+00:34:33,570 --> 00:34:40,940
+هذا الكلام إيش بضيف عنده؟ بيضيف H و OH، بيصير السؤال 
+
+427
+00:34:40,940 --> 00:34:48,960
+طيب إيش يختلف عن الإضافة في وجود الحامض وعن 
+
+428
+00:34:48,960 --> 00:34:54,530
+الإضافة في وجود الزئبق؟ الإضافة في وجود الحامض كانت 
+
+429
+00:34:54,530 --> 00:34:59,370
+Markovnikov لكن ممكن ال rearrangement الإضافة في 
+
+430
+00:34:59,370 --> 00:35:04,390
+وجود الزئبق Markovnikov بدون rearrangement الآن
+
+431
+00:35:04,390 --> 00:35:09,510
+الإضافة بهذه الطريقة Anti Markovnikov نتيجتها عكس 
+
+432
+00:35:09,510 --> 00:35:16,230
+Markovnikov واضح؟ هذه الفرق Anti Markovnikov's
+
+433
+00:35:16,230 --> 00:35:22,290
+addition بضيف عكس قاعدة Markovnikov هم لاحظين هنا
+
+434
+00:35:22,290 --> 00:35:28,590
+إيش احنا بنقول Anti Markovnikov's addition يعني
+
+435
+00:35:28,590 --> 00:35:33,090
+لما يكون في عندي رابطة مش متماثلة على جهة Hydrogen
+
+436
+00:35:33,090 --> 00:35:37,030
+أكثر ال H بتروح على ال H الـ Hydrogen أكثر ولا 
+
+437
+00:35:37,030 --> 00:35:42,890
+أقل في هذه الحالة؟ أقل لأن عكس قاعدة Markovnikov
+
+438
+00:35:46,700 --> 00:35:52,820
+طبعا كميكانيزم أو آلية كيف يتم هذا التفاعل احنا زي
+
+439
+00:35:52,820 --> 00:35:56,880
+ما اتفقنا أن التفاعل هذا هو ممكن نأخذه مع هذا
+
+440
+00:35:56,880 --> 00:36:01,280
+المركب ممكن نأخذه مع هذا المركب بدنا نضيف هنا واضح
+
+441
+00:36:01,280 --> 00:36:07,400
+بدنا نضيف هنا اللي بده يضيف ال bhc3 اتخيلوا ال
+
+442
+00:36:07,400 --> 00:36:13,490
+bhc3 أتى بهذا الشكل بدأت هذه الـ double bond تتحرك
+
+443
+00:36:13,490 --> 00:36:17,550
+وتعمل رابطة مع البورون؟ ليش الـ double bond بتعمل
+
+444
+00:36:17,550 --> 00:36:21,930
+رابطة مع البورون؟
+
+445
+00:36:21,930 --> 00:36:26,910
+اتذكروا البورون هنا في الـ BH3 أصلا، كم إلكترون
+
+446
+00:36:26,910 --> 00:36:30,910
+حوله؟ كم رابطة؟
+
+447
+00:36:35,600 --> 00:36:40,760
+البورون هل هو في الوضع الطبيعي اللي بيكون حوله ثمانية
+
+448
+00:36:40,760 --> 00:36:46,740
+إلكترونات ولا إلكترون deficient إلكترون poor نقصه 
+
+449
+00:36:46,740 --> 00:36:52,020
+إلكترونات؟ نقص إلكترونات الوضع الطبيعي كم حول الذرة 
+
+450
+00:36:52,020 --> 00:36:56,980
+يكون عندها إلكترونات 8 أربع روابط الآن هنا البورون
+
+451
+00:36:56,980 --> 00:37:02,900
+في هذا الجزء ال بي اتش تري كم أصلا حواليه ستة إذا
+
+452
+00:37:02,900 --> 00:37:07,420
+هو electron acceptor بده إلكترونات والإلكترون
+
+453
+00:37:07,420 --> 00:37:11,560
+acceptor حسب تعريف الحمض والقاعدة حسب Lewis
+
+454
+00:37:11,560 --> 00:37:16,440
+Definition اتذكروا تعريف Lewis للحمض والقاعدة ال
+
+455
+00:37:16,440 --> 00:37:22,190
+acid is electron acceptor و ال base is electron
+
+456
+00:37:22,190 --> 00:37:28,910
+donor إذا ال borane هنا عبارة عن إيش Lewis acid
+
+457
+00:37:28,910 --> 00:37:35,730
+حامض بمنطقة Lewis هو حامض هو بحاجة إلى إلكترونات
+
+458
+00:37:35,730 --> 00:37:40,210
+واضح وبناء على ذلك لما بيجي jump double bond ال
+
+459
+00:37:40,210 --> 00:37:44,220
+double bond بتبدأ تتحرك هنا إيش .. إيش بتعمل لما 
+
+460
+00:37:44,220 --> 00:37:47,360
+تجيله ال double bond هنا؟ إيش بتعمل؟ بتعطيه
+
+461
+00:37:47,360 --> 00:37:51,980
+إلكترونات هو بده إلكترونات و ال double bond تمثل
+
+462
+00:37:51,980 --> 00:37:56,980
+إلكترونات أو كثافة إلكترونية بتبدأ تتحرك زي هيك، 
+
+463
+00:37:56,980 --> 00:37:59,980
+الآن مجرد ما تبدأ تتحرك زي هيك، الأكشن مع
+
+464
+00:37:59,980 --> 00:38:04,940
+إلكتروناتها بتصير تتحرك .. لاحظوا هذا لما تتحرك 
+
+465
+00:38:04,940 --> 00:38:10,160
+بهذا الاتجاه، هتترك مكانها إيش؟ فراغ positive
+
+466
+00:38:10,160 --> 00:38:13,440
+charge أقل من الكاربوكاتيون أقل شوية من 
+
+467
+00:38:13,440 --> 00:38:16,600
+الكربوكاتيون partial charge الكاربوكاتيون شحنة 
+
+468
+00:38:16,600 --> 00:38:21,160
+كاملة موجب كامل هذا يعني سبعين أو ستين في المئة 
+
+469
+00:38:21,160 --> 00:38:25,900
+موجب بتترك هنا positive charge مباشرة بتيجي ال H 
+
+470
+00:38:25,900 --> 00:38:30,180
+مع إلكتروناتها بالضيف إذا هنا في الخطوة الأولى
+
+471
+00:38:30,180 --> 00:38:37,700
+بيصير عندك H و BH2 هدول اللي ضافوا واضح؟ فعدك مجرد
+
+472
+00:38:37,700 --> 00:38:42,860
+ما تحط ال H2O2 و ال hydrogen peroxide مكان ال BH2
+
+473
+00:38:42,860 --> 00:38:47,780
+ال hydrogen peroxide بتطرد ال BH2 بتحط محلها OH
+
+474
+00:38:47,780 --> 00:38:53,840
+الآن لاحظوا معي وين إجت ال H على اللي حمل ال 
+
+475
+00:38:53,840 --> 00:38:59,710
+hydrogen أكثر ولا أقل حسب Markovnikov كان ال H لازم 
+
+476
+00:38:59,710 --> 00:39:04,670
+تيجي هنا و ال O H هنا لكن هذا التفاعل Anti Markov
+
+477
+00:39:04,670 --> 00:39:10,850
+nikov ال H إجت هنا و ال O H إجت بهذا الموقع واضح؟
+
+478
+00:39:10,850 --> 00:39:14,930
+إذا هنا النتيجة Anti Markovnikov بمعنى لو أنا هذا 
+
+479
+00:39:14,930 --> 00:39:19,830
+كنت المثال نفسه جايب وقايلكم H plus في وجود H2O
+
+480
+00:39:19,830 --> 00:39:28,420
+كيف كان هتحطوا النتيجة؟ هتحطوها بهذا الشكل هنا ال H
+
+481
+00:39:28,420 --> 00:39:37,660
+وهنا ال OH وهي ال H الأصلية وهي CH3 إذا لو احنا
+
+482
+00:39:37,660 --> 00:39:41,900
+بدنا نيجي نسألكوا نحط هذا المركب ونعمل سهمين سهم
+
+483
+00:39:41,900 --> 00:39:47,000
+نكتب عليه BH3, THF كذا كل هدول الأشياء هتحطوا H و
+
+484
+00:39:47,000 --> 00:39:51,500
+OH لو سهمتان بدنا نعمل عليه H plus H2O هذه
+
+485
+00:39:51,500 --> 00:39:57,060
+الإضافة ماركوفنيكوف هذه الإضافة أنتيماركوفنيكوف
+
+486
+00:39:57,060 --> 00:40:00,780
+شوفت وين الفرق بين الإضافة باستعمال البورين
+
+487
+00:40:00,780 --> 00:40:07,020
+والإضافة باستعمال الحامض والماء؟ الآن بيجي السؤال
+
+488
+00:40:07,020 --> 00:40:15,810
+مرة ثانية خلينا نحلل الأمور ولو بشكل مبسط الآن هذا
+
+489
+00:40:15,810 --> 00:40:20,890
+التفاعل لما يمشي أنتيماركوفنيكوف addition إيش اللي
+
+490
+00:40:20,890 --> 00:40:23,770
+حكم التفاعل؟ هل هو الخطوة الثانية أو الخطوة
+
+491
+00:40:23,770 --> 00:40:28,690
+الأولى؟ الخطوة الأولى .. واضح؟ ليش؟ لأن الخطوة 
+
+492
+00:40:28,690 --> 00:40:31,810
+الثانية تحصيل حاصل .. المحل ما عنده بورون، بده
+
+493
+00:40:31,810 --> 00:40:37,250
+يصير OH لكن السؤال أن هذا الجزء كله لما يتفاعل
+
+494
+00:40:37,250 --> 00:40:40,550
+هنا، إيش كان فيه مانع أنه يكون بهذا الشكل؟ تكون
+
+495
+00:40:40,550 --> 00:40:44,810
+البورون زي هيك؟ والـ H هنا بمعنى تضيف الـ H هنا و
+
+496
+00:40:44,810 --> 00:40:49,090
+تضيف ال boron هنا واضح؟
+
+497
+00:40:49,090 --> 00:40:52,790
+يعني كأنه .. اتخيلوا أن هذه الحمرة .. هذه الغطاية
+
+498
+00:40:52,790 --> 00:40:56,570
+الحمرة هي ال H ماشي؟ وهنا ال boron الآن هذا جاي
+
+499
+00:40:56,570 --> 00:40:59,730
+يضيف على ال double bond احنا قلنا بضيف زي هيك طب
+
+500
+00:40:59,730 --> 00:41:06,210
+السؤال إيش المانع أنه يضيف زي هيك؟ واضحة الفكرة؟ اه
+
+501
+00:41:06,210 --> 00:41:10,530
+الآن بنقدر نقول إيش المانع لو خلينا يضيف بهذا الشكل
+
+502
+00:41:10,530 --> 00:41:15,630
+أول ما هذه تتحرك هتكون لي شحنة موجبة، الآن شحنة
+
+503
+00:41:15,630 --> 00:41:21,790
+الموجبة هنا إيش نوعها؟ primary طب الآن لو عملنا
+
+504
+00:41:21,790 --> 00:41:27,390
+بالعكس خلينا هذه تتحرك زي هيك، وين هتتكون الشحنة
+
+505
+00:41:27,390 --> 00:41:33,820
+الموجبة؟ هنا إيش بيكون نوعها؟ secondary متصلة
+
+506
+00:41:33,820 --> 00:41:38,640
+بـ carbon 2 واضح؟ بيكون نوع الشحنة secondary إذا أن 
+
+507
+00:41:38,640 --> 00:41:43,200
+هو أنسب لهذه double bond تبدأ تتحرك زي هيك وتترك
+
+508
+00:41:43,200 --> 00:41:48,100
+tertiary charge ولا تبدأ تتحرك زي هيك وتترك
+
+509
+00:41:48,100 --> 00:41:53,320
+secondary charge؟ إذا الموضوع هنا يتعلق بإيش؟ بال
+
+510
+00:41:53,320 --> 00:41:57,420
+stability ثبات الشحنة الجزئية الموجبة ب stability
+
+511
+00:41:57,420 --> 00:42:02,480
+of the partial positive charge حركة معينة بتعملي
+
+512
+00:42:02,480 --> 00:42:07,540
+tertiary partial positive charge الحركة الثانية لو
+
+513
+00:42:07,540 --> 00:42:12,460
+تمت لو تمت بهذا الشكل شو هتعملي؟ هتعملي برضه
+
+514
+00:42:12,460 --> 00:42:15,700
+positive charge partial لكن شو هيكون نوعها؟
+
+515
+00:42:15,700 --> 00:42:23,730
+secondary أن هو أفضل tertiary ولا secondary؟ إذا زي
+
+516
+00:42:23,730 --> 00:42:29,690
+ما بتلاحظوا .. زي ما بتلاحظوا أن النتيجة ..
+
+517
+00:42:29,690 --> 00:42:37,680
+النتيجة مختلفة بس روح الكلام واحد يعني النتيجة 
+
+518
+00:42:37,680 --> 00:42:42,940
+الإضافة في وجود ال H plus و ال H2O كنا نقول عنها
+
+519
+00:42:42,940 --> 00:42:48,940
+كنتيجة إيش Markovnikov addition في حالة ال borane
+
+520
+00:42:49,840 --> 00:42:54,360
+Anti Markovnikov addition الآن هذه النتيجة بالتأكيد 
+
+521
+00:42:54,360 --> 00:43:00,920
+مختلفة تماما ولا لأ؟ طيب لو إجينا سألنا ليش في حالة 
+
+522
+00:43:00,920 --> 00:43:06,920
+ال H plus مع الماء النتيجة Markovnikov addition
+
+523
+00:43:06,920 --> 00:43:14,870
+السبب تكوين ال more stable Intermediate تكوين الـ
+
+524
+00:43:14,870 --> 00:43:18,670
+intermediate اللي هي أشد ثباتا ما يمكن، مظبوط ولا لأ؟ 
+
+525
+00:43:18,670 --> 00:43:22,930
+طب ولو إجينا سألنا هنا ليش برضه صارت عند ال Anti
+
+526
+00:43:22,930 --> 00:43:27,810
+Markovnikov addition؟ إيش السبب؟ تكوين ال more
+
+527
+00:43:27,810 --> 00:43:33,730
+stable intermediate فحقيقة السبب يمكن أن يكون واحد 
+
+528
+00:43:33,730 --> 00:43:37,710
+رغم أن النتيجة مختلفة 
+
+529
+00:43:39,490 --> 00:43:44,450
+معقول أن السبب يكون واحد والنتيجة مختلفة؟ أعطيكم
+
+530
+00:43:44,450 --> 00:43:48,710
+مثال، أي واحدة فيكم عندها ولد صغير، عندها ولد
+
+531
+00:43:48,710 --> 00:43:57,650
+صغير، الآن ممكن مرة أكافئه، أعززه، تعطيه شغلة، و
+
+532
+00:43:57,650 --> 00:44:03,430
+مرة ثانية أعاقبه، الآن هل المكافأة زي المعاقبة
+
+533
+00:44:03,430 --> 00:44:09,770
+كنتيجة عكس بعض تماما؟ طب إيه السبب أنه هي قاعدة مرة
+
+534
+00:44:09,770 --> 00:44:16,930
+بتكافئه ومرة بتعاقبه؟ السعي وراء ثباته ومصلحته
+
+535
+00:44:16,930 --> 00:44:24,890
+لاحظين الأم ولا الأب؟ إذا عزز فهو يسعى لمصلحة الطفل 
+
+536
+00:44:24,890 --> 00:44:29,590
+وإذا عاقب فهو يسعى لمصلحة الطفل رغم أن هالنتيجة
+
+537
+00:44:29,590 --> 00:44:35,760
+تبدو إيش؟ مختلفة، لكن الروح هي إيش؟ السعي نحو 
+
+538
+00:44:35,760 --> 00:44:39,680
+المصلحة، الآن نفس الفكرة تماما، أنه هنا طلعت نتيجة
+
+539
+00:44:39,680 --> 00:44:44,560
+مختلفة، لكن في الحالتين أنا مريت عبر ال more
+
+540
+00:44:44,560 --> 00:44:47,900
+stable intermediate، في الحالة الأولى كانت ال more
+
+541
+00:44:47,900 --> 00:44:52,480
+stable carbocation وفي حالة ال hydroboration ال
+
+542
+00:44:52,480 --> 00:45:00,270
+more stable partial charge يعني شحنة جزئية، واضح؟
+
+543
+00:45:00,270 --> 00:45:05,750
+بناء على ذلك قبل ما ننتهي من هذا الموضوع وننهي
+
+544
+00:45:05,750 --> 00:45:11,870
+المحاضرة فيه لو أعطناكم الآن homework، أعطناكم هذا
+
+545
+00:45:11,870 --> 00:45:18,530
+المثال وحطينا لكم عليه ثلاثة أسهم أكمل المعادلة في
+
+546
+00:45:18,530 --> 00:45:23,830
+وجود الـ perchloric acid أكمل المعادلة في وجود H plus
+
+547
+00:45:23,830 --> 00:45:30,930
+H2O  و أكمل المعادلة في وجود ال BH3 و كل الأشياء
+
+548
+00:45:30,930 --> 00:45:37,380
+اللي موجودة معه في كل حالة حيخرج عندي ناتج في 
+
+549
+00:45:37,380 --> 00:45:41,560
+الحالة الأولى هنا اتفقنا بضيف H و OH بدون 
+
+550
+00:45:41,560 --> 00:45:45,260
+rearrangement في الحالة الثانية عملناها قبل شوية
+
+551
+00:45:45,260 --> 00:45:48,800
+بضيف ال H هنا ويصير rearrangement وفي الآخر ال
+
+552
+00:45:48,800 --> 00:45:55,480
+OH بتيجي هنا في هذه الحالة الأخيرة Anti
+
+553
+00:45:55,480 --> 00:46:00,780
+Markovnikov addition وين هتيجي ال H وال OH
+
+554
+00:46:03,670 --> 00:46:09,090
+عكس قاعدة ماركوفنيكوف .. إذا هذا المثال الثلاث طرق 
+
+555
+00:46:09,090 --> 00:46:16,430
+إضافة فيه بتعطيه كم ناتج؟ ثلاثة نواتج مختلفة ولذلك 
+
+556
+00:46:16,430 --> 00:46:21,890
+بدكم مش بس تقولوا أن الماء بضيف ثلاث طرق لأ بدكم 
+
+557
+00:46:21,890 --> 00:46:28,460
+تفهموا الفرق بين هذه الطرق الثلاث الحالة الأولى 
+
+558
+00:46:28,460 --> 00:46:32,240
+Markovnikov addition with rearrangement مع الزئبق 
+
+559
+00:46:32,240 --> 00:46:35,780
+Markovnikov addition without rearrangement مع
+
+560
+00:46:35,780 --> 00:46:41,220
+البورين Anti Markovnikov addition واضح هذا الكلام؟
+
+561
+00:46:41,220 --> 00:46:47,340
+هنا ضيعنا فيه محاضرة لما نسأل فيه سؤال واحد لازم 
+
+562
+00:46:47,340 --> 00:46:51,660
+كلكم تجاوبوه واضح؟ واللي مش فاهمه بتروح على
+
+563
+00:46:51,660 --> 00:46:53,460
+التسجيل بتسمعوا كمان مرة
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2a9bdd1a7238dce5e93f887ecd8f6c9ffc86b78a
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_raw.srt
@@ -0,0 +1,2276 @@
+1
+00:00:08,820 --> 00:00:14,060
+إذا بتسمحوا أخر
+
+2
+00:00:14,060 --> 00:00:19,200
+نقطة المرة الماضية اتكلمنا عنها كانت إضافة الماء
+
+3
+00:00:19,200 --> 00:00:24,140
+للالكينز وقولنا إنه في عدة طرق من خلالها بتتم
+
+4
+00:00:24,140 --> 00:00:28,510
+عملية إضافة الماء، الطريقة الأولىإضافة الماء في
+
+5
+00:00:28,510 --> 00:00:34,170
+وجود حامض اللي سمناه احنا acid-catalyzed hydration
+
+6
+00:00:34,170 --> 00:00:38,910
+of alkenes إذا بنذكر في الكلام اللي حكيناه قولنا
+
+7
+00:00:38,910 --> 00:00:44,030
+وظيفة الحامض أنه يبدأ التفاعل الحامض اللي بيعطينا
+
+8
+00:00:44,030 --> 00:00:48,290
+الـ H plus وظيفته أنه يبدأ التفاعل بتتحرك ال
+
+9
+00:00:48,290 --> 00:00:54,390
+double bond بهذا الشكل بتضيف هنا بتترك عندنا
+
+10
+00:00:54,390 --> 00:00:58,970
+Carbocation موجببتترك انه كاربو كاتاين موجب،
+
+11
+00:00:58,970 --> 00:01:03,310
+الكاربو كاتاين الموجب هذا بعد هيك بتضيف عليه الميه
+
+12
+00:01:03,310 --> 00:01:08,010
+و بتفقد بروتون فبصير في المحصل عالي إضافة هيدروجين
+
+13
+00:01:08,010 --> 00:01:15,430
+OH واضح؟ إذا المحصل هي إضافة إيش؟ماء المحص لإضافة
+
+14
+00:01:15,430 --> 00:01:19,830
+ماء كان التساؤل .. كان التساؤل أنه أنا في عندى
+
+15
+00:01:19,830 --> 00:01:23,510
+احتمالين لحركة ال double bond يعني كان ممكن ال
+
+16
+00:01:23,510 --> 00:01:27,050
+double bond تتحرك بهذا الشكل و تعمل carbocation
+
+17
+00:01:27,050 --> 00:01:30,530
+على هذه الكربونة أو تتحرك بهذا الشكل و تعمل
+
+18
+00:01:30,530 --> 00:01:35,110
+carbocation على هذه الكربونة واضح السؤال ليش
+
+19
+00:01:35,110 --> 00:01:40,670
+بتتحرك باتجاه معين مش بالاتجاه الثانيالان إذا هذا
+
+20
+00:01:40,670 --> 00:01:45,910
+الكلام بدنا نأكده خلينا نقول ال .. نوضح الاحتمالين
+
+21
+00:01:45,910 --> 00:01:50,410
+هدول بالظبط لما نيجي نتخيل أنه عندنا هذا الألكيد و
+
+22
+00:01:50,410 --> 00:01:53,870
+بدنا نضيف عليه H plus هذا ال H plus اللي اللون
+
+23
+00:01:53,870 --> 00:01:59,250
+أحمر من وين جاية؟ جاية من الحامض ال H plus هذه
+
+24
+00:01:59,250 --> 00:02:04,690
+ممكن تضيف على هذا الطرف و بالتالي تعمل أيون كربون
+
+25
+00:02:04,690 --> 00:02:10,220
+موجب على أي كربون؟ على الكربون الأولىو ممكن تضيف
+
+26
+00:02:10,220 --> 00:02:14,800
+على هذا الطرف وبالتالي تعمل ايون كربون موجب على
+
+27
+00:02:14,800 --> 00:02:19,520
+هذا الكربون واضح هاي الاحتمالين انه كأنه هذه
+
+28
+00:02:19,520 --> 00:02:25,500
+اتحركت بهذا الشكل او هذه اتحركت بهذا الشكل الآن
+
+29
+00:02:25,500 --> 00:02:30,380
+اذا بنيجي بنطلع احنا على ايون الكربون اللي اتكون
+
+30
+00:02:30,380 --> 00:02:36,380
+لاحظوا هنا هذه الكربون متصلة بكم كربونمتصلة ب اتش
+
+31
+00:02:36,380 --> 00:02:41,000
+و اتش و بكربون واحدة بناء على ذلك بنسمي ايون
+
+32
+00:02:41,000 --> 00:02:46,420
+الكربون تبعها ال primary carbocation يعني ايون
+
+33
+00:02:46,420 --> 00:02:53,360
+كربون موجب اول يعني متصل بكم كربون بواحدة الآن لو
+
+34
+00:02:53,360 --> 00:02:57,500
+صار عند الشغل التاني هذه الكربون اللي هنا اللي
+
+35
+00:02:57,500 --> 00:03:00,620
+بتحمل ال positive charge متصلة بكم كربون
+
+36
+00:03:03,650 --> 00:03:07,990
+بناء على ذلك هذا الكاربو كتايون بيكون اسمه
+
+37
+00:03:07,990 --> 00:03:12,310
+secondary carbocation، واضح؟ إذا الايون الموجب
+
+38
+00:03:12,310 --> 00:03:16,850
+ممكن يكون primary يعني الكاربون متصلة بكاربون
+
+39
+00:03:16,850 --> 00:03:21,030
+واحدة، ممكن يكون secondary يعني الكاربون متصلة
+
+40
+00:03:21,030 --> 00:03:27,010
+بكاربون واحدةالان بعد هيك بتيجي الميه تضيف إذا كان
+
+41
+00:03:27,010 --> 00:03:31,590
+ال positive موجود عندنا هنا بدي أضيف الميه و تفقد
+
+42
+00:03:31,590 --> 00:03:36,870
+H plus بصير عندي OH ملاحظين انتوا؟ لاحظوا في إضافة
+
+43
+00:03:36,870 --> 00:03:41,370
+الميه، طلعوا على الألوان كويس ال H من وين إجت؟ من
+
+44
+00:03:41,370 --> 00:03:46,770
+الحامض ال OH من وين إجت؟ من الميه فال H OH ما إجتش
+
+45
+00:03:46,770 --> 00:03:51,690
+من الميهالـ H إجت من الحمض والـ OH إجت من الميض لو
+
+46
+00:03:51,690 --> 00:03:56,230
+هذا التفاعل بده يكمل هنا بده يجي محل ال positive
+
+47
+00:03:56,230 --> 00:04:00,770
+في نهاية OH و تطلع H plus اللي بتخلي سلسلة التفاعل
+
+48
+00:04:00,770 --> 00:04:06,070
+تستمر الواقع اللي بيصير أن هذا الناتج لا يتكون
+
+49
+00:04:07,280 --> 00:04:10,820
+واضح؟ الناتج اللى بيمر من خلال ال primary
+
+50
+00:04:10,820 --> 00:04:14,540
+carbocation بتكونش بتكون الناتج اللى بيمر من خلال
+
+51
+00:04:14,540 --> 00:04:19,340
+ال secondary carbocation هنا بتكونوا تلاحظوا نقطة
+
+52
+00:04:19,340 --> 00:04:26,610
+كتير مهمة ان هذا التفاعل كام خطوةخطوتين أساسيتين
+
+53
+00:04:26,610 --> 00:04:29,690
+الخطوة الأولى إضافة لبروتون الخطوة الأولى التانية
+
+54
+00:04:29,690 --> 00:04:36,150
+أكمل التفاعل أي خطوة هي اللي بتتحمل أو يعني مسئولة
+
+55
+00:04:36,150 --> 00:04:42,340
+عن تحديدوين تيجي ال H وين تيجي ال OH هل هي الخطوة
+
+56
+00:04:42,340 --> 00:04:45,900
+الأولى ولا الخطوة التانية الخطوة الأولى لأن الخطوة
+
+57
+00:04:45,900 --> 00:04:50,260
+الأولى فيها اختيار يعني هنا ال H plus واقفة في
+
+58
+00:04:50,260 --> 00:04:53,420
+عنده احتمالين اما هذا الاحتمال او هذا الاحتمال
+
+59
+00:04:53,420 --> 00:04:57,520
+مظبوط ولا لا لكن لو صار هذا الاحتمال ال H two أولى
+
+60
+00:04:57,520 --> 00:05:01,350
+مامده تيجيفيش هنا غير احتمال واحد، غير مكان واحد
+
+61
+00:05:01,350 --> 00:05:05,570
+هنا تيجي عليه، واضح؟ فاللي بيتحكم في التفاعل من
+
+62
+00:05:05,570 --> 00:05:13,170
+ناحية وين موضع الإضافة هو حقيقة الخطوة الأولى مش
+
+63
+00:05:13,170 --> 00:05:18,190
+الخطوة الثانية، الخطوة التانية ملزمة، تحصيل حاصل،
+
+64
+00:05:18,190 --> 00:05:21,830
+واضح؟ تماما هذا الكلام لو بدى .. يعني أعمللكوا
+
+65
+00:05:21,830 --> 00:05:26,050
+تشبيه عشان تفهموه لو افترضنا مثلا انه في طالبات
+
+66
+00:05:26,050 --> 00:05:30,910
+مغتربات إيجوا بدهم يسكنوافي سكن طالبة تسكن غرفتين
+
+67
+00:05:30,910 --> 00:05:37,790
+واضح؟ إجت أول طالبة وصلت السكن الساعة سبعة الصبح و
+
+68
+00:05:37,790 --> 00:05:41,690
+بدها تحط أغراضها في غرفة الآن هي عندها غرفتين هي
+
+69
+00:05:41,690 --> 00:05:45,890
+بتختار ولا لأ؟ هي بتختار عندها احتمال تحط هنا أو
+
+70
+00:05:45,890 --> 00:05:50,650
+تحط هنا حطت أغراضها في هذه الغرفة الساعة عشرة إجت
+
+71
+00:05:50,650 --> 00:05:56,640
+زملتهافي عند اختيار لجت المكان الأول مشغول فأصبحت
+
+72
+00:05:56,640 --> 00:05:59,340
+ملزمة بالمكان الثاني فعملية الاختيار شو اللي
+
+73
+00:05:59,340 --> 00:06:03,230
+بيحكمها؟الخطوة الأولى مش الخطوة الثانية الآن
+
+74
+00:06:03,230 --> 00:06:08,410
+بيضلوا السؤال قائم ليش في الخطوة الأولى الهيدروج
+
+75
+00:06:08,410 --> 00:06:13,670
+الفضل ييجي هنا وبالتالي يعمل secondary carbocation
+
+76
+00:06:13,670 --> 00:06:18,330
+من إنه ييجي هنا ويعمل primary carbocation هذا
+
+77
+00:06:18,330 --> 00:06:21,850
+الكلام متعلق في إيش بنسميه ال stability of
+
+78
+00:06:21,850 --> 00:06:26,010
+carbocation ثبات ال carbocation واضح؟
+
+79
+00:06:28,220 --> 00:06:31,860
+ثبات الكربوكاتيون بالشكل اللى موجود عندنا فوق
+
+80
+00:06:31,860 --> 00:06:37,160
+التيرتشاري كربوكاتيون اللى متصل بتلت كربونات بيكون
+
+81
+00:06:37,160 --> 00:06:42,660
+أثبت من ال secondary أثبت من ال primary أثبت من ال
+
+82
+00:06:42,660 --> 00:06:46,100
+CH3 اللى مش متصل ولا بكربونات المثل كربوكاتيون
+
+83
+00:06:46,100 --> 00:06:50,300
+واضح؟ اذا the stability of kerbocation's tertiary
+
+84
+00:06:50,300 --> 00:06:52,620
+is more stable than the secondary is more stable
+
+85
+00:06:52,620 --> 00:06:58,520
+than the primary ممكن واحد تسأل ليش؟واضح؟ هذه
+
+86
+00:06:58,520 --> 00:07:02,300
+النتيجة انه احنا علميا بنقول ال tertiary
+
+87
+00:07:02,300 --> 00:07:06,740
+carbocation أثبت من ال secondary و ال secondary
+
+88
+00:07:06,740 --> 00:07:12,240
+أثبت من ال primary و الاشي الثابت هو اللي ايش؟ هو
+
+89
+00:07:12,240 --> 00:07:16,880
+اللي بيتكون صارت الشغل سهل لكن ليش ال tertiary
+
+90
+00:07:16,880 --> 00:07:20,700
+أثبت من ال secondary و ال secondary أثبت من ال
+
+91
+00:07:20,700 --> 00:07:25,680
+primary؟ واضح السؤال؟ ثبات الشحنة دائما يكون
+
+92
+00:07:25,680 --> 00:07:26,680
+بتقليلها
+
+93
+00:07:31,890 --> 00:07:39,930
+أي شحنة بدنا نثبتها لازم تكون قليلة إذا زادت
+
+94
+00:07:39,930 --> 00:07:47,710
+الشحنةقل الثبات، وإذا قلت الشحنة زاد الثبات، واضح؟
+
+95
+00:07:47,710 --> 00:07:52,470
+هذا الكلام قاعدة عامة حتى لو كنتوا يعني بدكم تحكوا
+
+96
+00:07:52,470 --> 00:07:56,170
+في موضوع الغضب، اعتبروا الغضب شحنة، اعتبروا الغضب
+
+97
+00:07:56,170 --> 00:07:59,890
+شحنة، الآن اللي عنده شحنة عالية من الغضب، بيكون
+
+98
+00:07:59,890 --> 00:08:04,200
+ثابت ولا بيقاتل في حاله؟بكون مش ثابت .. unstable
+
+99
+00:08:04,200 --> 00:08:08,480
+.. واضح .. حتى لما بيروح بيتعالج .. إيش بيسووا؟
+
+100
+00:08:08,480 --> 00:08:11,860
+بيقللوا الشحنة اللي عنده .. البني آدم اللي بيقولوا
+
+101
+00:08:11,860 --> 00:08:15,300
+بتزيد عنده الكهربا .. بتشوفوا كيف بعض الناس عندهم
+
+102
+00:08:15,300 --> 00:08:18,720
+مشكلة .. زيادة الكهربا .. هذه زيادة الشحنة بتعمل
+
+103
+00:08:18,720 --> 00:08:22,980
+ثابت ولا عدم ثابت؟ بتعمل عدم ثابت .. وقت إيش بيصير
+
+104
+00:08:22,980 --> 00:08:29,520
+الثابت؟إذا قلت الشحنة .. إذا قلت الشحنة .. واضح
+
+105
+00:08:29,520 --> 00:08:33,700
+كيف؟ عشان يك .. حتى البني آدم .. حتى البني آدم لو
+
+106
+00:08:33,700 --> 00:08:39,420
+عنده شحنة حزن مثلا .. أي شخص كان عنده مناسبة توفى
+
+107
+00:08:39,420 --> 00:08:43,260
+قريب أو عزيزه .. صار عنده شحنة كبيرة من الحزن ..
+
+108
+00:08:43,260 --> 00:08:48,240
+إيش الناس بيعملوا؟بيجوا بعزوه لما بيجوا بعزوه إيش
+
+109
+00:08:48,240 --> 00:08:52,740
+بيسووا؟ كأنه هذا أخد منه شوية حزن و هذا أخد شوية و
+
+110
+00:08:52,740 --> 00:08:56,320
+هذا أخد شوية و هذا أخد شوية واضح أو اللي عنده
+
+111
+00:08:56,320 --> 00:09:01,240
+مصيبة كبيرة مثلا نفترض داره انهدت بالحرب بيجي هذا
+
+112
+00:09:01,240 --> 00:09:05,700
+بيجيبله مساعدة هذا بيعمله هذا بيعمله فإيش بيصير
+
+113
+00:09:05,700 --> 00:09:10,680
+للشحنة اللي عنده؟ بتخلق الكلام نفسه بتكرر في ال
+
+114
+00:09:10,680 --> 00:09:17,100
+positive chargeال R group بتعطي إلكترونات لما أكون
+
+115
+00:09:17,100 --> 00:09:20,380
+عندي positive charge افترضوا هذا ال positive بس
+
+116
+00:09:20,380 --> 00:09:26,500
+كعدد عشوائي إنها عشر وحدات عشر وحدات هذه تمثل إيش
+
+117
+00:09:26,500 --> 00:09:31,680
+ثقل أو شحنة الآن لما تيجي ال R group ال R group
+
+118
+00:09:31,680 --> 00:09:38,500
+بتعطي إلكترونات يعني بتعطي إيشبتعطي سالب السالب شو
+
+119
+00:09:38,500 --> 00:09:42,680
+بيعمل في الموجة بيقلله يعني لو افترضت انه شحن
+
+120
+00:09:42,680 --> 00:09:46,500
+الموجة بعشر وحدات لجت اي اشي ساعده لما يكون عنده
+
+121
+00:09:46,500 --> 00:09:50,780
+تلت هيدروجينات لأ طيب لو افترضنا ان ال R group
+
+122
+00:09:50,780 --> 00:09:55,720
+بتعطي اتنين سالب وهذه عشرة موجة شو بتعمل ال R
+
+123
+00:09:55,720 --> 00:09:59,440
+group في الموجة في هذه الحالة؟بتعدل تنتين منه، كم
+
+124
+00:09:59,440 --> 00:10:03,160
+يصف الموجب؟ تمانية، إذا هنا الموجب قلت، هنا الشحنة
+
+125
+00:10:03,160 --> 00:10:09,680
+قلت طيب، لو كان عندي تنتين R-groups، إيش بيصي
+
+126
+00:10:09,680 --> 00:10:12,880
+لشحنة الموجب بقى؟ بتقل أكثر وأكثر، يعني لو افترضت
+
+127
+00:10:12,880 --> 00:10:17,340
+هذه عشرة، وهذه نقصت اتنين، عدلت اتنين، وهذه عدلت
+
+128
+00:10:17,340 --> 00:10:21,760
+اتنين، كم هيصف الموجب؟ ستة إذا، قاعد التباك بزيد،
+
+129
+00:10:21,760 --> 00:10:27,360
+لو افترضت هنا تلت مجموعات Rترضو هذه عشرة هذه بتعطي
+
+130
+00:10:27,360 --> 00:10:30,240
+اتنين سالب و اتنين سالب و اتنين سالب كده اش ضال
+
+131
+00:10:30,240 --> 00:10:35,320
+الموجب عنده اربع اذا الموجب عمله بقل كأن انا بقدر
+
+132
+00:10:35,320 --> 00:10:39,660
+اقول ان ال electron donating groups المجموعات
+
+133
+00:10:39,660 --> 00:10:44,020
+المعطية للالكترونات المعطية للشحنة السالبة ماذا
+
+134
+00:10:44,020 --> 00:10:46,960
+تفعل في شحنة الموجبة؟ decreases
+
+135
+00:11:02,800 --> 00:11:06,380
+معنى شحنة جلة شحنة صارت more stable
+
+136
+00:11:09,360 --> 00:11:14,660
+معنى إن هالشحنة جلت إنه شحنة صارت more stable إذا
+
+137
+00:11:14,660 --> 00:11:19,620
+اقدرنا نفهم إيش سبب هذا ل trend of stability إنه
+
+138
+00:11:19,620 --> 00:11:22,160
+ال tertiary is more stable than the secondary is
+
+139
+00:11:22,160 --> 00:11:25,800
+more stable than the primary because of the
+
+140
+00:11:25,800 --> 00:11:32,100
+presence of more electron donating groups بسبب
+
+141
+00:11:32,100 --> 00:11:37,600
+وجود مجموعات معطية للإلكترونات بتقللالـ positive
+
+142
+00:11:37,600 --> 00:11:43,640
+is charged واضح؟ الآن في عندي شغلة مهمة جدا ال
+
+143
+00:11:43,640 --> 00:11:46,500
+rate of formation of carbocation زي ما هي ال
+
+144
+00:11:46,500 --> 00:11:50,000
+stability of carbocation ال tertiary أفضل من
+
+145
+00:11:50,000 --> 00:11:53,120
+الsecondary أفضل من ال primary سرعة التكوين بتكون
+
+146
+00:11:53,120 --> 00:11:57,900
+حسب الثباتبرضه ال tertiary أفضل من ال secondary
+
+147
+00:11:57,900 --> 00:12:03,200
+أفضل من ال primary واضح هذا الكلام بناء على ذلك
+
+148
+00:12:03,200 --> 00:12:07,200
+بنقدر نفهم الكلام اللي في ال slide السابق ببساطة
+
+149
+00:12:07,200 --> 00:12:13,340
+ليش بتكون هذا مش هذا لأن هنا الكربوكاتيون primary
+
+150
+00:12:13,340 --> 00:12:17,880
+هنا الكربوكاتيون secondary the more stable
+
+151
+00:12:17,880 --> 00:12:22,890
+secondary كربوكاتيون will formالكاربوكاتيون اللى
+
+152
+00:12:22,890 --> 00:12:26,890
+هو more stable ال secondary بتكون الآن الخطوة اللى
+
+153
+00:12:26,890 --> 00:12:33,030
+بعيدها تحصل حاصل اكمل التفاعل لكن التفاعل وين
+
+154
+00:12:33,030 --> 00:12:38,290
+انحكم ال reaction is controlled by the first or by
+
+155
+00:12:38,290 --> 00:12:43,870
+the second step by the first step واضح التفاعل
+
+156
+00:12:43,870 --> 00:12:48,390
+بينحكم بالخطوة الأولى انه ايش اللى أثبت بتكون
+
+157
+00:12:50,880 --> 00:12:56,440
+Stability أو ثبات واضح؟ الآن لو في تفاعل تاني كنت
+
+158
+00:12:56,440 --> 00:13:01,020
+بعمل إضافة وعندي تنافس ما بين إمكانية tertiary
+
+159
+00:13:01,020 --> 00:13:06,140
+-carbocation وsecondary الهيدروجين بيضيف بحيث يكون
+
+160
+00:13:06,140 --> 00:13:10,500
+ال tertiary-carbocation مش ال secondary الهيدروجين
+
+161
+00:13:10,500 --> 00:13:16,450
+بيضيف بحيث يكون ال tertiary-carbocationهنا ابتدينا
+
+162
+00:13:16,450 --> 00:13:24,630
+شغلة إضافية والحقيقة جميلة جدا لو بدنا نطلع على
+
+163
+00:13:24,630 --> 00:13:28,710
+المثال هذا لو بدنا نطلع على المثال هذا عندكم CH2
+
+164
+00:13:28,710 --> 00:13:38,320
+CH وهنا CH3 CH3 لو قلنا بدنا نضيف H Plusزي ما
+
+165
+00:13:38,320 --> 00:13:42,000
+اتفقنا ال H plus ممكن تيجي على هذا الموقع تكون
+
+166
+00:13:42,000 --> 00:13:46,040
+لإيش؟ secondary carbocation أو تيجي على هذا الموقع
+
+167
+00:13:46,040 --> 00:13:49,600
+تكون primary carbocation وبعد هيك ال reaction
+
+168
+00:13:49,600 --> 00:13:54,840
+يكتمل، الآن من أول لحظة secondary ولا primary؟
+
+169
+00:13:54,840 --> 00:13:59,630
+secondary، إذا هذا الاحتمال ألغىاللي بتكون عندى ال
+
+170
+00:13:59,630 --> 00:14:04,590
+secondary لاحظوا هنا ال secondary هتلاحظوا فيه
+
+171
+00:14:04,590 --> 00:14:11,230
+jumbo carbon حاملة CH3 و CH3OH بيصير عندى شغل جديد
+
+172
+00:14:11,230 --> 00:14:16,230
+ان ال secondary نفسه قبل ما يكمل التفاعل ممكن
+
+173
+00:14:16,230 --> 00:14:23,350
+يتحول إلى tertiaryإذا هو يتجه إلى مزيد من الثبات
+
+174
+00:14:23,350 --> 00:14:26,750
+يعني لما مايصارش ال primary صار ال secondary هذا
+
+175
+00:14:26,750 --> 00:14:31,270
+توجه نحو إيش الثبات الآن ال secondary ممكن يتجه
+
+176
+00:14:31,270 --> 00:14:35,230
+إلى مزيد من الثبات كيف كيف ال secondary بتحول ل
+
+177
+00:14:35,230 --> 00:14:41,490
+tertiary بتيجي ال H مع زوج الإلكترونات تبعها ال H
+
+178
+00:14:41,490 --> 00:14:47,660
+مع زوج الإلكترونات تبعها بنسميها hydride ionلاحظوا
+
+179
+00:14:47,660 --> 00:14:54,300
+ال H بلس بدون إلكترونات شو اسمها بروتون انتبهوا
+
+180
+00:14:54,300 --> 00:15:00,400
+معايا ال H يبدأ تكون ذرة متعادلة يبدأ تكون موجبة
+
+181
+00:15:00,400 --> 00:15:06,220
+ال H كذرة متعادلة شو موجود فيها؟Electron واحد إذا
+
+182
+00:15:06,220 --> 00:15:11,620
+بدت تصير ال H تفقدها ال Electron شو بتصير؟ H plus
+
+183
+00:15:11,620 --> 00:15:16,620
+وإذا ال H بدت تكتسب Electron تصير عليها Electronين
+
+184
+00:15:16,620 --> 00:15:22,200
+شو بتصير؟ H minus واضح؟ إذا ال H بوضعها الطبيعي
+
+185
+00:15:22,200 --> 00:15:28,740
+كذرة عليهايابتفقد هذا ال electron بتصير H بلس،
+
+186
+00:15:28,740 --> 00:15:34,980
+يابتكون مكتسبة فوقه كمان electron بتصير H مينوس ال
+
+187
+00:15:34,980 --> 00:15:40,640
+H بلس اسمها بروتون لأنه
+
+188
+00:15:40,640 --> 00:15:46,140
+خلاص دل عندي موجب و electron، راح ال electron، شو
+
+189
+00:15:46,140 --> 00:15:51,200
+دل؟الموجة بظل لبروتون فال H بلس اسمها بروتون ال H
+
+190
+00:15:51,200 --> 00:15:56,260
+ماينوس شو اسمها هيدرايد ايون شفتوا الفرق بين
+
+191
+00:15:56,260 --> 00:15:57,960
+الهيدرايد ايون و البروتون
+
+192
+00:16:05,370 --> 00:16:08,730
+الخطوة الأولى عندما يضيف من الحامض ماذا يضيف عنده
+
+193
+00:16:08,730 --> 00:16:15,330
+؟ H بلس بروتون بروتون اللي بضيف عنده هنا بصير
+
+194
+00:16:15,330 --> 00:16:26,560
+انتقال أو shiftلـ H- الهيدرايد انايون الهيدرايد
+
+195
+00:16:26,560 --> 00:16:33,320
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+196
+00:16:33,320 --> 00:16:35,120
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+197
+00:16:35,120 --> 00:16:35,780
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+198
+00:16:35,780 --> 00:16:35,780
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+199
+00:16:35,780 --> 00:16:35,780
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+200
+00:16:35,780 --> 00:16:35,780
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+201
+00:16:35,780 --> 00:16:36,000
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+202
+00:16:36,000 --> 00:16:43,960
+انايون الهيدرايد انايون الهيدIon موجة positive
+
+203
+00:16:43,960 --> 00:16:48,000
+اتطلعوا الآن على هذا ال ion الموجة اللي تركته
+
+204
+00:16:48,000 --> 00:16:53,260
+مكانها هل يتورا secondary ولا tertiary؟ لاحظوا
+
+205
+00:16:53,260 --> 00:17:00,200
+carbon تنتين تلاتةصار تيرتشاري هذه العملية بنسميها
+
+206
+00:17:00,200 --> 00:17:05,540
+rearrangement أو إعادة ترتيب Rearrangement إن الـ
+
+207
+00:17:05,540 --> 00:17:10,760
+H بتنتقل أو الهيدرايد أنايون بنتقل بحيث يحولني إذا
+
+208
+00:17:10,760 --> 00:17:14,260
+في إمكانية في التفاعل زي هذا المثال ال secondary
+
+209
+00:17:14,260 --> 00:17:20,200
+carbocation إلى tertiary carbocation بعد هيك لما
+
+210
+00:17:20,200 --> 00:17:24,710
+بتيجي المياه تضيف، بتضيف مكانالموجة في مكان ال
+
+211
+00:17:24,710 --> 00:17:30,150
+tertiary تحط OH لاحظوا هنا ال H اللي ضفناها وين
+
+212
+00:17:30,150 --> 00:17:36,360
+إجت؟ على موقع واحد ال OH اللي من الميهع موقع تلاتة
+
+213
+00:17:36,360 --> 00:17:40,820
+ملاحظين يعني بدل ما تيجي ال H هنا و ال O H هنا
+
+214
+00:17:40,820 --> 00:17:45,400
+بتلاحظوا أن ال O H نجلة موقعها هذه عملية ال
+
+215
+00:17:45,400 --> 00:17:49,140
+rearrangement أو إعادة الترتيب اللي موجودة في
+
+216
+00:17:49,140 --> 00:17:53,820
+الجزء ليش تم تقول هذه العملية عملية إعادة الترتيب؟
+
+217
+00:17:53,820 --> 00:18:00,540
+عشان أنتقل من السكندري كاربو كاتايون إلىالـ
+
+218
+00:18:00,540 --> 00:18:03,700
+tertiary carbocation عشان ننتقل من
+
+219
+00:18:03,700 --> 00:18:08,160
+السكندريكاربوكاتيون الى التيرتشاريكاربوكاتيون بتم
+
+220
+00:18:08,160 --> 00:18:12,340
+هنا rearrangement من خلال عملية إيش بنسميها؟
+
+221
+00:18:12,340 --> 00:18:18,260
+Hydride shift يعني تحرك هيدروجين مع إلكتروناته
+
+222
+00:18:18,260 --> 00:18:23,920
+كلام منطقي ليش؟ لأن هذا موجب الموجب إيش بيكون بده؟
+
+223
+00:18:23,920 --> 00:18:29,400
+بده سالب إيش السالب؟الهيدروجين و إلكتروناته هما
+
+224
+00:18:29,400 --> 00:18:34,240
+السالب هما الانيون الهيدروجين مع الإلكترونات تبعته
+
+225
+00:18:38,050 --> 00:18:42,330
+من مميزات الـ Acid Catalyzed Addition of Water أنه
+
+226
+00:18:42,330 --> 00:18:45,910
+في إمكانية طالما بتكون عندي Carbocation في إمكانية
+
+227
+00:18:45,910 --> 00:18:49,530
+لل rearrangement معنى إمكانية ال rearrangement أنه
+
+228
+00:18:49,530 --> 00:18:54,390
+ممكن ال secondary يصير أحيانا في أمثلة معينة فيها
+
+229
+00:18:54,390 --> 00:18:58,910
+primary برضه ممكن يتحول إلى tertiary واضح؟ هنا
+
+230
+00:18:58,910 --> 00:19:04,450
+عملية ال rearrangement تمت من خلال إيش؟الحقيقة
+
+231
+00:19:04,450 --> 00:19:08,810
+اللى لاحظوا انه مش بس من خلال ال hydride shift
+
+232
+00:19:08,810 --> 00:19:12,330
+يعني لو انه بدل ما عندى هنا hydrogen خلتها دول
+
+233
+00:19:12,330 --> 00:19:16,690
+تلاتة methyls لاحظوا المثال السابق هدى إيش كانت؟
+
+234
+00:19:17,340 --> 00:19:22,460
+أتش خلّيتهم تلاتة مثلًا لو الآن بدأ أضيف H بلاص زي
+
+235
+00:19:22,460 --> 00:19:25,720
+ما اتفقنا يا بنضيفها هنا بنكون primary يا بنضيفها
+
+236
+00:19:25,720 --> 00:19:30,420
+هنا بنكون secondary أن هو الاحتمال الملغي ال
+
+237
+00:19:30,420 --> 00:19:35,700
+primary بيظل عنده ال secondary الآن بالإمكان تتحرك
+
+238
+00:19:35,700 --> 00:19:42,940
+مجموعة CH3 كاملة مع إلكتروناتها كل CH3 تنتقل هذه
+
+239
+00:19:42,940 --> 00:19:48,000
+بنسميها إيش إحنا ال kill shiftلما كانت H مع
+
+240
+00:19:48,000 --> 00:19:53,160
+إلكتروناتها هيدرايتشفت لما تكون CH3 مع إلكتروناتها
+
+241
+00:19:53,160 --> 00:19:58,800
+الكلشفت واضح؟ ممكن يصير عنده الكلشفت تنتقل كل ال
+
+242
+00:19:58,800 --> 00:20:01,700
+CH3 هان لحظة الجزء كله بتغير و ال positive وين
+
+243
+00:20:01,700 --> 00:20:06,080
+بيصير؟ هان عشان هذا تيرتشاريكاربوكاتيون بعدين لما
+
+244
+00:20:06,080 --> 00:20:10,690
+الميه بتضيف تحط OH وين بتحطها؟عادة الموقع، لاحظوا
+
+245
+00:20:10,690 --> 00:20:14,010
+كده إعادة الترتيب اللي صارت في الجزيرة، إن الـH
+
+246
+00:20:14,010 --> 00:20:19,210
+إجت هنا كويس، الـOH ماجتش جنبها، انتقلت الـCH3
+
+247
+00:20:19,210 --> 00:20:22,070
+والـOH إجت على الموقع اللي بعدها، هذه عملية
+
+248
+00:20:22,070 --> 00:20:24,830
+rearrangement، هنا ال rearrangement from the
+
+249
+00:20:24,830 --> 00:20:28,550
+secondary كربوكاتيون to the tertiary كربوكاتيون is
+
+250
+00:20:28,550 --> 00:20:35,220
+through ال kill shift، واضح؟ففي ميزة دائما في ال
+
+251
+00:20:35,220 --> 00:20:38,680
+carbocations بزام الكربوكاتيونز بتسعى لل stability
+
+252
+00:20:38,680 --> 00:20:44,300
+إذا في إمكانية لإيش لل rearrangement واضح؟ هذا عمر
+
+253
+00:20:44,300 --> 00:20:49,500
+بسيط يعني تماما تماما اتخيلوه بشكل الآتي ممكن يكون
+
+254
+00:20:49,500 --> 00:20:52,720
+عندكوا إحساس أن أفضل ناس عندهم ثبات و بيشوفوا كويس
+
+255
+00:20:52,720 --> 00:20:56,620
+اللي قاعدين هنا واضح؟ لو افترضنا أن الأخت اللي هنا
+
+256
+00:20:56,620 --> 00:21:03,660
+طلعت، شو بيصير؟بتناجح عملية ال rearrangement إذا
+
+257
+00:21:03,660 --> 00:21:08,020
+الناس دايما بتسعى نحوها مزيد من الثبات ولا لأ تسعى
+
+258
+00:21:08,020 --> 00:21:14,460
+نحوها مزيد من الثبات الآن
+
+259
+00:21:14,460 --> 00:21:20,900
+بنجي لطريقة تانية غير إضافة الماء في وجود الحامض
+
+260
+00:21:20,900 --> 00:21:28,360
+في طريقة إضافة الماء في وجود الحامضالزقبق وتحديدا
+
+261
+00:21:28,360 --> 00:21:32,700
+المركب اللي احنا بنستعمله اللي اسمه ال mercuryic
+
+262
+00:21:32,700 --> 00:21:37,020
+acetate mercuryic acetate يعني mercuryic acetate
+
+263
+00:21:37,020 --> 00:21:42,480
+اللي بنسميه احنا ايش خلات الزقبق ال acetic acid
+
+264
+00:21:42,480 --> 00:21:48,540
+حمضالخل .. حمض الخل و ال mercury acetate خلات
+
+265
+00:21:48,540 --> 00:21:53,700
+الزبا .. الآن إذا كان في عندي double bond .. إذا
+
+266
+00:21:53,700 --> 00:21:58,270
+كان في عندي double bondضيفت عليها على خطوتين
+
+267
+00:21:58,270 --> 00:22:03,110
+متتاليتين الخطوة الأولى ميركوريك أسيتيت في وجود
+
+268
+00:22:03,110 --> 00:22:07,190
+الميه دايب في الميه الخطوة التانية مركّب بنسميه
+
+269
+00:22:07,190 --> 00:22:11,510
+sodium borohydride هدولة مع بعض بقالية معينة مش
+
+270
+00:22:11,510 --> 00:22:15,930
+هنتطرق لها حتى ما نتوسعش كتير بضيفوا ميه يعني
+
+271
+00:22:15,930 --> 00:22:21,730
+محصلة هذا ال reagent كله هي عملية إضافة إيش إضافة
+
+272
+00:22:21,730 --> 00:22:27,790
+ميه الآن الميه هنا كيف بتضيفبتضيف حسب قاعدة
+
+273
+00:22:27,790 --> 00:22:34,430
+Markovnikov زي ما الحامض كان يعمل بمعنى على هذا
+
+274
+00:22:34,430 --> 00:22:40,410
+الموقع شو بده يجيني H ولا OH؟ وع هذا الموقع OH ليش
+
+275
+00:22:40,410 --> 00:22:43,350
+هنا بيجيني ال H؟ إذا بتلاحظوا هنا كام هيدروجين
+
+276
+00:22:43,350 --> 00:22:50,070
+عندى؟ في الأساس10-10 هنا كم هيدروجين عندى؟ واحدة
+
+277
+00:22:50,070 --> 00:22:53,570
+احنا المرة الماضية قولنا انه في الإضافة في وجود
+
+278
+00:22:53,570 --> 00:22:58,010
+الحامض و ايضا في وجود ال mercury acetate بتمشي على
+
+279
+00:22:58,010 --> 00:23:02,230
+حسب قاعدة ماركوفنيكوف انه الهيدروجين بتيجي على اي
+
+280
+00:23:02,230 --> 00:23:07,590
+كاربون على حاملة هيدروجين اكتر بلاحظين انتوا بناء
+
+281
+00:23:07,590 --> 00:23:12,150
+على ذلك الهيدروجين بتضيف هنا و ال OH بتضيف على هذا
+
+282
+00:23:12,150 --> 00:23:17,900
+الموقعممكن الآن واحدة تسأل طب إيش هدى بتختلف عن
+
+283
+00:23:17,900 --> 00:23:24,220
+الإضافة في وجود الحامض؟
+
+284
+00:23:24,220 --> 00:23:28,560
+واضح الكلام؟ الإضافة في وجود الحامض Markovnikov
+
+285
+00:23:28,560 --> 00:23:34,620
+addition والإضافة في وجود الذئبق برضه Markovnikov
+
+286
+00:23:34,620 --> 00:23:40,590
+addition طب إيش ده بتفرق؟بتفرق أن الإضافة في وجود
+
+287
+00:23:40,590 --> 00:23:46,050
+الذئبق لا يحصل فيها rearrangement،
+
+288
+00:23:46,050 --> 00:23:49,890
+الإضافة في وجود الذئبق ما بيصيرش فيها
+
+289
+00:23:49,890 --> 00:23:53,130
+rearrangement، بتضيف على الطرفي الرابط الزوجية،
+
+290
+00:23:53,130 --> 00:23:57,170
+الإضافة في وجود الحامض قبل شوية، لاحظنا أن فيها
+
+291
+00:23:57,170 --> 00:24:03,090
+إيش؟ rearrangementبس في وجود الذئبق ما بيصيرش
+
+292
+00:24:03,090 --> 00:24:07,870
+rearrangement يعني لو رجعنا للمثال السابق اللي
+
+293
+00:24:07,870 --> 00:24:12,530
+عندنا هنا و بقولنا لكوا هاي هذا المثال بدنا نضيف H
+
+294
+00:24:12,530 --> 00:24:18,650
+plus H to O اعطونا الناتج شو هتعطونا هتعطونا ان ال
+
+295
+00:24:18,650 --> 00:24:22,590
+H بيضيف هنا secondary carbocation بيصير tertiary
+
+296
+00:24:22,590 --> 00:24:27,130
+ال O H بيضيف هنا هاي الناتج طيب لو كنت حاططركم ال
+
+297
+00:24:27,130 --> 00:24:32,560
+reagent هنا مش H plusزئبق ميركوريك أسيتيت وميه و
+
+298
+00:24:32,560 --> 00:24:36,560
+بعدين صوديوم بورو هايدرايد شو النتج اللي هتعطونيه؟
+
+299
+00:24:36,560 --> 00:24:41,860
+بده يضيف ال H و ال OH على الطرفين الرابط بحيث ان
+
+300
+00:24:41,860 --> 00:24:45,020
+ال H تيجي على أكتر و ال OH هنا، بده يطلع هذا النتج
+
+301
+00:24:47,610 --> 00:24:51,410
+واضح؟ يعني لو ال reagent اللى عندى mercury acetate
+
+302
+00:24:51,410 --> 00:24:55,210
+بدي يطلع هذا النتج لو ال reagent اللى عندى H plus
+
+303
+00:24:55,210 --> 00:25:00,190
+H2O بدي يطلع هذا النتج شوفت وين الفرق ما بين
+
+304
+00:25:00,190 --> 00:25:06,490
+الشغلتين؟واضح هذا هو الفرق بين إضافة الميه في وجود
+
+305
+00:25:06,490 --> 00:25:09,990
+حامض إنه فيه إمكانية ل rearrangement إضافة الميه
+
+306
+00:25:09,990 --> 00:25:15,370
+في وجود الذئبق لأ بتضيف حسب Markovnikov rule بدون
+
+307
+00:25:15,370 --> 00:25:19,810
+عملية ال rearrangement عشانك حتى لو بترجع يمكن لل
+
+308
+00:25:19,810 --> 00:25:24,650
+slides لل slides بتلاحظوا في عندنا هنا كلمة إنه ال
+
+309
+00:25:24,650 --> 00:25:29,470
+addition Markovnikov regiochemistry is observedإن
+
+310
+00:25:29,470 --> 00:25:33,850
+الإضافة حسب قاعدة ماركوف نيكوف وهذا ال reaction
+
+311
+00:25:33,850 --> 00:25:40,870
+إيش ماله؟ Rearrangements do not occur إذا لو احنا
+
+312
+00:25:40,870 --> 00:25:47,770
+كنا بنسألكوا سؤال صح و غلط مثلا، بنقولكم in the
+
+313
+00:25:47,770 --> 00:25:52,070
+acid-catalyzed hydration of alkenes, rearrangement
+
+314
+00:25:52,070 --> 00:25:53,030
+is possible
+
+315
+00:25:55,370 --> 00:25:58,810
+صح في ال acid catalyzed addition rearrangement is
+
+316
+00:25:58,810 --> 00:26:02,970
+possible in oxymercuration طبعا هذا بنسمي
+
+317
+00:26:02,970 --> 00:26:06,190
+oxymercuration لأنه بضيف الزبق و ال oxygen اللي هي
+
+318
+00:26:06,190 --> 00:26:09,430
+إضافة من خلال الزبق in oxymercuration
+
+319
+00:26:09,430 --> 00:26:13,790
+rearrangement is possible rearrangement does not
+
+320
+00:26:13,790 --> 00:26:18,770
+occur in oxymercuration شفتوا الفرق بين الإضافتين
+
+321
+00:26:18,770 --> 00:26:25,230
+للميه؟الان هي هذا مثال لو قلنا لكوا بدنا نضيف عليه
+
+322
+00:26:25,230 --> 00:26:29,410
+ميركوريك أسيتات في وجود الميه وبعدين صوديوم بورو
+
+323
+00:26:29,410 --> 00:26:33,930
+هيدرايد الإضافة على الطرفين الرابطة لو أنتوا بدكوا
+
+324
+00:26:33,930 --> 00:26:36,970
+تحللوا المثال هتلاحظوا أن هنا في شغل مفقود هشوية
+
+325
+00:26:36,970 --> 00:26:43,170
+هادى الهيدروجين إذا اللي بده أرسمها هنا بالأحمر هي
+
+326
+00:26:43,170 --> 00:26:46,750
+اللي كانت موجودة أصلا إذا لما بده اضيف الميه اضيف
+
+327
+00:26:46,750 --> 00:26:52,610
+H و OH وين هتيجي ال H؟على هذه اللي حاملة هيدروجين
+
+328
+00:26:52,610 --> 00:26:56,610
+وين هتيجي ال OH؟ على هذه اللي حاملة هيدروجين وين
+
+329
+00:26:56,610 --> 00:26:56,730
+هتيجي ال OH؟ على هذه اللي حاملة هيدروجين وين هتيجي
+
+330
+00:26:56,730 --> 00:26:57,310
+ال OH؟ على هذه اللي حاملة هيدروجين وين هتيجي ال
+
+331
+00:26:57,310 --> 00:27:00,450
+OH؟ على هذه اللي حاملة هيدروجين وين هتيجي ال OH؟
+
+332
+00:27:00,450 --> 00:27:01,030
+على هذه اللي حاملة هيدروجين وين هتيجي ال OH؟ على
+
+333
+00:27:01,030 --> 00:27:04,130
+هذه اللي حاملة هيدروجين وين هتيجي ال OH؟ على هذه
+
+334
+00:27:04,130 --> 00:27:05,490
+اللي حاملة هيدروجين وين هتيجي ال OH؟ على هذه اللي
+
+335
+00:27:05,490 --> 00:27:09,790
+حاملة هيدروجين وين هتيجي ال OH؟ على هذه اللي حاملة
+
+336
+00:27:09,790 --> 00:27:14,130
+هيدروجين وين هتيجي ال OH؟ على هذه اللي حاملة
+
+337
+00:27:14,130 --> 00:27:19,510
+هيدروجين
+
+338
+00:27:19,510 --> 00:27:26,840
+وهن بحط ال H و هن بحط ال OH طبعا
+
+339
+00:27:26,840 --> 00:27:30,760
+في هذا المثال الحقيقة مافيش إمكانية برضه ل
+
+340
+00:27:30,760 --> 00:27:34,120
+rearrangement يعني لو كنت هذا المثال تحديدا بدي
+
+341
+00:27:34,120 --> 00:27:39,460
+أكمله في وجود H plus وH to O برضه هيعطي نفس النتجة
+
+342
+00:27:40,250 --> 00:27:43,350
+يعني احنا دايما بنقول ان ال rearrangement possible
+
+343
+00:27:43,350 --> 00:27:46,830
+بس مش دايما ممكن ال rearrangement يعني لما يكون
+
+344
+00:27:46,830 --> 00:27:51,450
+فيه امكانية انه اي carbocation يتحسن لاشي افضل
+
+345
+00:27:51,450 --> 00:27:56,010
+بيصير طب لو مافيش امكانية مابصيرش يعني لو على هذا
+
+346
+00:27:56,010 --> 00:28:01,870
+المثال انا كنت بده اضيف H plus H2O الخطوة الأولى
+
+347
+00:28:01,870 --> 00:28:08,100
+شو هتكون؟إضافة الـ H plus تخيلوا إضافت هنا صار
+
+348
+00:28:08,100 --> 00:28:14,080
+Carbocation هنا شو نوع هذا Carbocation؟
+
+349
+00:28:14,080 --> 00:28:19,280
+طيب tertiary هيعمل rearrangement؟ في أحسن من ال
+
+350
+00:28:19,280 --> 00:28:23,080
+tertiary؟ بناء على ذلك هيكمل بدون rearrangement
+
+351
+00:28:23,080 --> 00:28:26,300
+وبالتالي في هذا المثال تحديدًا في هذا المثال
+
+352
+00:28:26,300 --> 00:28:29,760
+تحديدًا بأي شكل من الأشكال ضفت أنا
+
+353
+00:28:33,200 --> 00:28:37,800
+بال ميركوريك أسيتيت بيختلف الناتج لأ بينما لاحظوا
+
+354
+00:28:37,800 --> 00:28:43,240
+لو بدنا نحكي بهذا المثال خليني أكملكم الهيدروجين
+
+355
+00:28:43,240 --> 00:28:49,320
+كلها للجزيء باللون الأحمر وهنا
+
+356
+00:28:49,320 --> 00:28:54,240
+في عندي كمان هيدروجين الان أول ما بده ييجي اضيف
+
+357
+00:28:54,240 --> 00:28:57,600
+ميه في وجود الحامض مش في وجود الزئبق بتكونوا
+
+358
+00:28:57,600 --> 00:29:02,950
+تتخيلوا okay لما نقول ان هذا بده يضيف في وجودH
+
+359
+00:29:02,950 --> 00:29:10,370
+plus H2O وين هتيجي الهيدروجين على هذا الموقع واضح
+
+360
+00:29:10,370 --> 00:29:13,650
+هاي الهيدروجين اجت على هذا الموقع ال double bond
+
+361
+00:29:13,650 --> 00:29:19,550
+راحت وشو صار عندى هنا انتبهوا معاه لسه كاربو
+
+362
+00:29:19,550 --> 00:29:26,930
+كاتايون هذا الكاربو كاتاين إذا بتطلع عليه في
+
+363
+00:29:26,930 --> 00:29:32,090
+إمكانية انه ينقل Hإنه يعمل rearrangement هذا نفس
+
+364
+00:29:32,090 --> 00:29:36,610
+المثال السابق اللي احنا شرحناه لكوا واضح؟ بتلقى
+
+365
+00:29:36,610 --> 00:29:41,790
+الكل هادي هنا و أين بتيجي ال OH بيصير ال positive
+
+366
+00:29:41,790 --> 00:29:45,670
+هنا و ال OH بتيجي هنا مثل هذه المعادلة، لو كنا
+
+367
+00:29:45,670 --> 00:29:52,410
+جايليني أكمل المعادلة في وجود H plus H2O، شو
+
+368
+00:29:52,410 --> 00:29:56,230
+الناتج اللي بتتوقعوه؟ مش اللي انتوا شايفينه على
+
+369
+00:29:56,230 --> 00:29:56,530
+اللوحة
+
+370
+00:30:00,950 --> 00:30:05,470
+هنا هتيجي ال H في البداية تكون كاربو كتاين على هذا
+
+371
+00:30:05,470 --> 00:30:11,790
+الموقع السكندري بينقل هاي
+
+372
+00:30:11,790 --> 00:30:17,340
+الناتج شوفتوا الفرق بين الطريقتين؟إذا في هذا
+
+373
+00:30:17,340 --> 00:30:23,100
+المثال يختلف عندي إذا أضيف الميه باستعمال الحامض
+
+374
+00:30:23,100 --> 00:30:26,760
+أو باستعمال الذئبق باستعمال الذئبق لا يوجد نقاش
+
+375
+00:30:26,760 --> 00:30:32,000
+أتيت ال H هنا و ال O هنا التفاعل هذا لا يوجد فيه
+
+376
+00:30:32,000 --> 00:30:35,980
+rearrangement على الطرفين الرامض لا يوجد
+
+377
+00:30:35,980 --> 00:30:40,200
+rearrangement في وجود الحامض أول ما تأتي ال H هنا
+
+378
+00:30:40,200 --> 00:30:45,490
+و تعمل positiveشو بيصير عندى؟ بيصير عندى الـ
+
+379
+00:30:45,490 --> 00:30:47,810
+hydrate shift rearrangement الـ positive بيصير على
+
+380
+00:30:47,810 --> 00:30:51,810
+هذا الموقع و الـ OH بتيجي على هذا الموقع إذا هنا
+
+381
+00:30:51,810 --> 00:30:57,250
+الناتج مختلف تماما ولا لأ؟ أه فوجود طريقتين،
+
+382
+00:30:57,250 --> 00:31:01,870
+الطريقتين لا يعطوا نفس الناتج مرات بيعطوا إذا
+
+383
+00:31:01,870 --> 00:31:04,490
+مافيش إمكانية لل rearrangement لكن لو في إمكانية
+
+384
+00:31:04,490 --> 00:31:08,070
+لل rearrangement ال rearrangement بتصير في وجود
+
+385
+00:31:08,070 --> 00:31:11,950
+الحامض مابتصيرش في وجود الذئبق
+
+386
+00:31:15,420 --> 00:31:18,400
+يعني ال arrangement بتصير في وجود الحامض و
+
+387
+00:31:18,400 --> 00:31:22,940
+مابتصيرش في وجود الذئب اكتر يعني دكتور انا احنا
+
+388
+00:31:22,940 --> 00:31:28,800
+لما نيجي نعملها بيصير مثلا كاربوكاتيا على سكنها
+
+389
+00:31:28,800 --> 00:31:32,240
+بتعملوله ال arrangement هو نفسه كأنه بدور من اقرب
+
+390
+00:31:32,240 --> 00:31:38,370
+واحدة يعني ممكن تيرشفإذا فيه بيصير tertiary واضح؟
+
+391
+00:31:38,370 --> 00:31:41,370
+لو .. لو كان tertiary مش هيعمل rearrangement لو
+
+392
+00:31:41,370 --> 00:31:46,730
+كان secondary ونقل مجموعة H minus أو مجموعة مثل
+
+393
+00:31:46,730 --> 00:31:52,530
+بتخليه tertiary هيعمل واضح؟ بيعتمد على نوع المثال
+
+394
+00:31:52,530 --> 00:31:57,550
+إذا هنا في وجود الحامض هل تستطيعون تكتبوا الجواب
+
+395
+00:31:57,550 --> 00:32:02,050
+مباشرة ولا لازم تعملوا ميكانيزم للتفاعل؟المفروض
+
+396
+00:32:02,050 --> 00:32:05,430
+تعملوا mechanism يعني لو واحدة بس بدا ت .. بدا ت
+
+397
+00:32:05,430 --> 00:32:10,070
+.. تحط نتاج و تقول H O H و خلاص مابظبطش لازم تشتغل
+
+398
+00:32:10,070 --> 00:32:15,590
+تحليل للمسألة H اي الموجب بالامكان يتحسنها ده
+
+399
+00:32:15,590 --> 00:32:19,550
+secondary يصير tertiary بعدين ال O H بتضيف في حالة
+
+400
+00:32:19,550 --> 00:32:23,090
+الإضافة في وجود H plus و H plus و H plus و H plus
+
+401
+00:32:23,090 --> 00:32:23,150
+و H plus و H plus و H plus و H plus و H plus و H
+
+402
+00:32:23,150 --> 00:32:24,710
+plus و H plus و H plus و H plus و H plus و H plus
+
+403
+00:32:24,710 --> 00:32:25,170
+و H plus و H plus و H plus و H plus و H plus و H
+
+404
+00:32:25,170 --> 00:32:25,190
+plus و H plus و H plus و H plus و H plus و H plus
+
+405
+00:32:25,190 --> 00:32:25,190
+و H plus و H plus و H plus و H plus و H plus و H
+
+406
+00:32:25,190 --> 00:32:25,210
+plus و H plus و H plus و H plus و H plus و H plus
+
+407
+00:32:25,210 --> 00:32:34,790
+و H plus و H plus و Hالان في طريقة تالتة لإضافة
+
+408
+00:32:34,790 --> 00:32:41,090
+الميّه طريقة
+
+409
+00:32:41,090 --> 00:32:47,710
+إضافة الميّه التالتة بنسميها hydroboration of an
+
+410
+00:32:47,710 --> 00:32:52,510
+alkene with oxidative workup أو مرات بيسموها
+
+411
+00:32:52,510 --> 00:32:57,110
+hydroboration oxidationواضح؟ اش معناه
+
+412
+00:32:57,110 --> 00:33:02,030
+hydroboration؟ في عندى عنصر فى الجدول الدورى اللى
+
+413
+00:33:02,030 --> 00:33:08,610
+اسمه ال boron عارفينه؟ العنصر اللى بيجينى بعد ال
+
+414
+00:33:08,610 --> 00:33:12,990
+helium تالت عنصر مش عندى اول عنصر ال hydrogen
+
+415
+00:33:12,990 --> 00:33:21,640
+التانى ال helium التالت ال boronالبرون موجود منه
+
+416
+00:33:21,640 --> 00:33:30,060
+مُركّب مع تلاتة هيدروجين بورين BH3 مُركّب بورين
+
+417
+00:33:30,060 --> 00:33:34,000
+BH3 مُركّب
+
+418
+00:33:34,000 --> 00:33:41,500
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+419
+00:33:41,500 --> 00:33:45,440
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+420
+00:33:45,440 --> 00:33:47,960
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+421
+00:33:47,960 --> 00:33:47,960
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+422
+00:33:47,960 --> 00:33:47,960
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+423
+00:33:47,960 --> 00:33:48,280
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+424
+00:33:48,280 --> 00:33:53,280
+بكخطوة أولى و بعدين بالخطوة التانية ضيفنا له H2O2
+
+425
+00:33:53,280 --> 00:33:57,020
+مية الأكسجين اللى بنسميها إحنا إيش hydrogen
+
+426
+00:33:57,020 --> 00:34:04,800
+peroxide في basic medium في OH minus بضيف برضه
+
+427
+00:34:04,800 --> 00:34:09,080
+بالمحصلة مية لاحظوا هذه الأشياء عشان تحفظوا
+
+428
+00:34:09,080 --> 00:34:16,170
+أسماءها ال BH3 عبارة عن إيشالبرين ال THF هذا عبارة
+
+429
+00:34:16,170 --> 00:34:25,230
+عن solvent مذيب solvent ال H2O2 هيدروجين بيروكسايد
+
+430
+00:34:25,230 --> 00:34:28,870
+فوق أكسيد الهيدروجين هيدروجين بيروكسايد و ال OH
+
+431
+00:34:28,870 --> 00:34:33,570
+minus معنى ذلك أن التفاعل بتم في basic medium كل
+
+432
+00:34:33,570 --> 00:34:40,940
+هذا الكلام ايش بضيف عندهبيضيف H و OH، بيصير السؤال
+
+433
+00:34:40,940 --> 00:34:48,960
+طيب إيش بيختلف عن الإضافة في وجود الحامض و عن
+
+434
+00:34:48,960 --> 00:34:54,530
+الإضافة في وجود الذئبق؟الإضافة في وجود الحامد كانت
+
+435
+00:34:54,530 --> 00:34:59,370
+Markovnikov لكن ممكن ال rearrangement الإضافة في
+
+436
+00:34:59,370 --> 00:35:04,390
+وجود الذئبق Markovnikov بدون rearrangement الآن
+
+437
+00:35:04,390 --> 00:35:09,510
+الإضافة بهذه الطريقة Anti Markovnikov نتيجتها عكس
+
+438
+00:35:09,510 --> 00:35:16,230
+Markovnikov واضح؟ هذه الفرقAnti Markovnikov's
+
+439
+00:35:16,230 --> 00:35:22,290
+addition بضيف عكس قاعدة Markovnikov هم لاحظين هنا
+
+440
+00:35:22,290 --> 00:35:28,590
+إيش إحنا بنقول Anti Markovnikov's addition يعني
+
+441
+00:35:28,590 --> 00:35:33,090
+لما يكون في عندي رابطة مش متماثلة على جهة Hydrogen
+
+442
+00:35:33,090 --> 00:35:37,030
+أكتر ال H1 بتروح على اللحام ل Hydrogen أكتر ولا
+
+443
+00:35:37,030 --> 00:35:42,890
+أقل في هذه الحالة؟ أقل لأن عكس قاعدة Markovnikov
+
+444
+00:35:46,700 --> 00:35:52,820
+طبعا كميكانيزم أو آلية كيف يتم هذا التفاعل احنا زي
+
+445
+00:35:52,820 --> 00:35:56,880
+ما اتفقنا ان التفاعل هذا هو ممكن ناخده مع هذا
+
+446
+00:35:56,880 --> 00:36:01,280
+المركب ممكن ناخده مع هذا المركب بدنا نضيف هنا واضح
+
+447
+00:36:01,280 --> 00:36:07,400
+بدنا نضيف هنا اللي بده يضيف ال bhc3 اتخيلوا ال
+
+448
+00:36:07,400 --> 00:36:13,490
+bhc3 اتي بهذا الشكل بدأهذه الـ double bond تتحرك
+
+449
+00:36:13,490 --> 00:36:17,550
+وتعمل رابطة مع البورون؟ ليش الـ double bond بتعمل
+
+450
+00:36:17,550 --> 00:36:21,930
+رابطة مع البورون؟
+
+451
+00:36:21,930 --> 00:36:26,910
+اتذكروا البورون هنا في الـ BH3 أصلا، كام إلكترون
+
+452
+00:36:26,910 --> 00:36:30,910
+حوله؟ كام رابطة؟
+
+453
+00:36:35,600 --> 00:36:40,760
+البرون هل هو في الوضع الطبيعي اللي بيكون حوله تمان
+
+454
+00:36:40,760 --> 00:36:46,740
+إلكترونات ولا إلكترون deficient إلكترون poor نقصه
+
+455
+00:36:46,740 --> 00:36:52,020
+إلكترونات؟نقص إلكترونات الوضع الطبيعي كم حول الذر
+
+456
+00:36:52,020 --> 00:36:56,980
+يكون عنده إلكترونات 8 أربع روابط الآن هنا البرون
+
+457
+00:36:56,980 --> 00:37:02,900
+في هذا الجزء ال بي اتش تري كم أصلا حواليه ستة إذا
+
+458
+00:37:02,900 --> 00:37:07,420
+هو electron acceptor بده إلكترونات والإلكترون
+
+459
+00:37:07,420 --> 00:37:11,560
+acceptor حسب تعريف الحمض والقاعدة حسب Lewis
+
+460
+00:37:11,560 --> 00:37:16,440
+Definition اتذكروا تعريف Lewis للحمض والقاعدة ال
+
+461
+00:37:16,440 --> 00:37:22,190
+acid is electronacceptor و ال base is electron
+
+462
+00:37:22,190 --> 00:37:28,910
+donor إذا ال borane هنا عبارة عن إيش Lewis acid
+
+463
+00:37:28,910 --> 00:37:35,730
+حامض بمنطقه Lewis هو حامض هو بحاجة إلى إلكترونات
+
+464
+00:37:35,730 --> 00:37:40,210
+واضح و بناء على ذلك لما بيجي jump double bond ال
+
+465
+00:37:40,210 --> 00:37:44,220
+double bond بتبدأ تتحرك هناإيش .. إيش بتعمل لما
+
+466
+00:37:44,220 --> 00:37:47,360
+تجيله ال double bond هنا؟ إيش بتعمل؟ بتعطيه
+
+467
+00:37:47,360 --> 00:37:51,980
+إلكترونات هو بده إلكترونات و ال double bond تمثل
+
+468
+00:37:51,980 --> 00:37:56,980
+إلكترونات أو كثافة إلكترونية بتبدأ تتحرك زي هيك،
+
+469
+00:37:56,980 --> 00:37:59,980
+الآن مجرد ما تبدأ تتحرك زي هيك، الأكش مع
+
+470
+00:37:59,980 --> 00:38:04,940
+إلكتروناتها بتصير تتحرك .. لاحظوا هذا لما تتحرك
+
+471
+00:38:04,940 --> 00:38:10,160
+بهذا الاتجاه، هتترك مكانها إيش؟فراغ positive
+
+472
+00:38:10,160 --> 00:38:13,440
+charge أقل من الكربوكاتيون اقل شوية من
+
+473
+00:38:13,440 --> 00:38:16,600
+الكربوكاتيون partial charge الكربوكاتيون شحنة
+
+474
+00:38:16,600 --> 00:38:21,160
+كاملة موجب كامل هذا يعني سبعين أو ستين في المية
+
+475
+00:38:21,160 --> 00:38:25,900
+موجب بتترك هنا positive charge مباشرة بتيجي ال H
+
+476
+00:38:25,900 --> 00:38:30,180
+مع إلكتروناتها بالضيف إذا هنا في الخطوة الأولى
+
+477
+00:38:30,180 --> 00:38:37,700
+بيصير عندك H و BH2 هدولة اللي ضافواواضح؟ فعدك مجرد
+
+478
+00:38:37,700 --> 00:38:42,860
+ما تحط ال H2O2 و ال hydrogen peroxide مكان ال BH2
+
+479
+00:38:42,860 --> 00:38:47,780
+ال hydrogen peroxide بتطرد ال BH2 بتحط محلها OH
+
+480
+00:38:47,780 --> 00:38:53,840
+الان لاحظوا معي وين إجت ال H على اللي حمل ال
+
+481
+00:38:53,840 --> 00:38:59,710
+hydrogen أكتر ولا أقل حسب Markovnikovكان ال H لازم
+
+482
+00:38:59,710 --> 00:39:04,670
+تيجي هنا و ال O H هنا لكن هذا التفاعل Anti Markov
+
+483
+00:39:04,670 --> 00:39:10,850
+Nikov ال H إجت هنا و ال O H إجت بهذا الموقع واضح؟
+
+484
+00:39:10,850 --> 00:39:14,930
+إذا هنا النتيجة Anti Markov Nikov بمعنى لو أنا هذا
+
+485
+00:39:14,930 --> 00:39:19,830
+كنت المثال نفسه جايب و قايلكم H plus في وجود H2O
+
+486
+00:39:19,830 --> 00:39:28,420
+كيف كان هتحطوا النتيجة؟ هتحطوها بهذا الشكلهنا ال H
+
+487
+00:39:28,420 --> 00:39:37,660
+وهنا ال OH وهي ال H الأصلية وهي CH3 إذا لو احنا
+
+488
+00:39:37,660 --> 00:39:41,900
+بدنا نيجي نسألكوا نحط هذا المركب و نعمل سهمين سهم
+
+489
+00:39:41,900 --> 00:39:47,000
+نكتب عليه BH3, THF كذا كل هدول الأشياء هتحطوا H و
+
+490
+00:39:47,000 --> 00:39:51,500
+OH لو ساهمتان بدنا نعمل عليه H plus H2O هذه
+
+491
+00:39:51,500 --> 00:39:57,060
+الإضافةماركوفنيكوف هذه الإضافة أمتي ماركوفنيكوف
+
+492
+00:39:57,060 --> 00:40:00,780
+شوفت وين الفرق بين الإضافة باستعمال البورين
+
+493
+00:40:00,780 --> 00:40:07,020
+والإضافة باستعمال الحامض والميه؟ الآن بيجي السؤال
+
+494
+00:40:07,020 --> 00:40:15,810
+مرة تانية خلينا نحلل الأمور ولو بشكل مبسطالان هذا
+
+495
+00:40:15,810 --> 00:40:20,890
+التفاعل لما يمشي امتي ماركوف نيكوف اديشن ايش اللي
+
+496
+00:40:20,890 --> 00:40:23,770
+حكم التفاعل؟ هل هو الخطوة التانية او الخطوة
+
+497
+00:40:23,770 --> 00:40:28,690
+الاولى؟ الخطوة الاولى .. واضح؟ ليش؟ لان الخطوة
+
+498
+00:40:28,690 --> 00:40:31,810
+التانية تحصيل حاصل .. المحل ماعنديه بورون، بده
+
+499
+00:40:31,810 --> 00:40:37,250
+يصير OH لكن السؤال ان هذا الجزء كله لما اتفاعل
+
+500
+00:40:37,250 --> 00:40:40,550
+هنا، ايش كان فيه مانع انه يكون بهذا الشكل؟ تكون
+
+501
+00:40:40,550 --> 00:40:44,810
+البورون زي هيك؟والـ H هنا بمعنى تضيف الـ H هنا و
+
+502
+00:40:44,810 --> 00:40:49,090
+تضيف ال boron هنا واضح؟
+
+503
+00:40:49,090 --> 00:40:52,790
+يعني كأنه .. اتخيلوا ان هذه الحمرة .. هذه الغطاية
+
+504
+00:40:52,790 --> 00:40:56,570
+الحمرة هي ال H ماشي؟ و هنا ال boron الآن هذا جاي
+
+505
+00:40:56,570 --> 00:40:59,730
+يضيف ع ال double bond احنا قولنا بضيف زي هيك طب
+
+506
+00:40:59,730 --> 00:41:06,210
+السؤال ايش المانع انه يضيف زي هيك؟واضحة الفكرة؟ اه
+
+507
+00:41:06,210 --> 00:41:10,530
+الآن بنقدر نقول إيش المانع لو خلنا يضيف بهذا الشكل
+
+508
+00:41:10,530 --> 00:41:15,630
+أول ما هذه تتحرك هتكونلي شحنة موجبة، الآن شحنة
+
+509
+00:41:15,630 --> 00:41:21,790
+الموجبة هنا إيش نوعها؟ تيرشة طب الآن لو أعملنا
+
+510
+00:41:21,790 --> 00:41:27,390
+بالعكس خلينا هذه تتحرك زي هيك، وين هتتكون الشحنة
+
+511
+00:41:27,390 --> 00:41:33,820
+الموجبة؟ هنا إيش بيكون نوعها؟secondary متصلة
+
+512
+00:41:33,820 --> 00:41:38,640
+بcarbon 2 واضح؟ بيكون نوع الشحنة secondary إذا أن
+
+513
+00:41:38,640 --> 00:41:43,200
+هو أنسب لهذه double bond تبدأ تتحرك زي هيك و تترك
+
+514
+00:41:43,200 --> 00:41:48,100
+tertiary charge ولا تبدأ تتحرك زي هيك و تترك
+
+515
+00:41:48,100 --> 00:41:53,320
+secondary charge؟إذا الموضوع هنا يتعلق بإيش بال
+
+516
+00:41:53,320 --> 00:41:57,420
+stability ثبات الشحنة الجزئية الموجة ب stability
+
+517
+00:41:57,420 --> 00:42:02,480
+of the partial positive charge حركة معينة بتعملي
+
+518
+00:42:02,480 --> 00:42:07,540
+tertiary partial positive charge الحركة التانية لو
+
+519
+00:42:07,540 --> 00:42:12,460
+تمت لو تمت بهذا الشكل شو هتعملي؟ هتعملي برضه
+
+520
+00:42:12,460 --> 00:42:15,700
+positive charge partial لكن شو هيكون نوعها؟
+
+521
+00:42:15,700 --> 00:42:23,730
+secondary أن هو أفضلtertiary ولا secondary؟ اذا زي
+
+522
+00:42:23,730 --> 00:42:29,690
+ما بتلاحظوا .. زي ما بتلاحظوا انه النتيجة ..
+
+523
+00:42:29,690 --> 00:42:37,680
+النتيجة مختلفة بس روح الكلام واحديعني النتيجة
+
+524
+00:42:37,680 --> 00:42:42,940
+الإضافة في وجود ال H plus و ال H2O كنا نقول عنها
+
+525
+00:42:42,940 --> 00:42:48,940
+كنتيجة إيش Markovnikov addition في حالة ال borane
+
+526
+00:42:49,840 --> 00:42:54,360
+انت ماركوف نيكوف اديشن الان هذه نتيجة بالتأكيد
+
+527
+00:42:54,360 --> 00:43:00,920
+مختلفة تماما ولا لأ طيب لو اجينا سألنا ليش في حالة
+
+528
+00:43:00,920 --> 00:43:06,920
+ال H بلس مع المياء النتيجة ماركوف نيكوف اديشن
+
+529
+00:43:06,920 --> 00:43:14,870
+السبب تكوين ال more stableIntermediate تكوين الـ
+
+530
+00:43:14,870 --> 00:43:18,670
+intermediate اللي هي أثبت ما يمكن، مظبوط ولا لأ؟
+
+531
+00:43:18,670 --> 00:43:22,930
+طب و لو إجينا سألنا هنا ليش برضه صارت عند ال Anti
+
+532
+00:43:22,930 --> 00:43:27,810
+Markovnikov addition؟ إيش السبب؟ تكوين ال more
+
+533
+00:43:27,810 --> 00:43:33,730
+stable intermediate فحقيقة السبب يمكن أن يكون واحد
+
+534
+00:43:33,730 --> 00:43:37,710
+رغم إن النتيجة مختلفة
+
+535
+00:43:39,490 --> 00:43:44,450
+معقول أن السبب يكون واحد والنتيجة مختلفة؟ أعطيكم
+
+536
+00:43:44,450 --> 00:43:48,710
+مثال، أي واحدة فيكم عندها ولد صغير، عندها ولد
+
+537
+00:43:48,710 --> 00:43:57,650
+صغير، الان ممكن مرة اتكافئه، اتعززه، تعطيه شغله، و
+
+538
+00:43:57,650 --> 00:44:03,430
+مرة تانية اتعاقبه، الان هل المكافئةزي المعاقبة
+
+539
+00:44:03,430 --> 00:44:09,770
+كنتيجة عكس بعض تماما طب إيه السبب إنه هي قاعدة مرة
+
+540
+00:44:09,770 --> 00:44:16,930
+بتكافؤه ومرة بتعاقبه السعي ورا ثباته ومصلحته
+
+541
+00:44:16,930 --> 00:44:24,890
+لاحظين الأم ولا الأب إذا عزز فهو يسعى لمصلحت الطفل
+
+542
+00:44:24,890 --> 00:44:29,590
+وإذا عاقب فهو يسعى لمصلحت الطفل رغم إن هالنتيجة
+
+543
+00:44:29,590 --> 00:44:35,760
+تبدو إيشمختلفة، لكن الروح هي إيش؟ الساعة نحو
+
+544
+00:44:35,760 --> 00:44:39,680
+المصلحة، الآن نفس الفكرة تماما، إنه هنا طلعت نتيجة
+
+545
+00:44:39,680 --> 00:44:44,560
+مختلفة، لكن في الحالتين أنا مريت عبر ال more
+
+546
+00:44:44,560 --> 00:44:47,900
+stable intermediate، في الحالة الأولى كانت ال more
+
+547
+00:44:47,900 --> 00:44:52,480
+stable carbocation وفي حالة ال hydroboration ال
+
+548
+00:44:52,480 --> 00:45:00,270
+more stablepartial charge يعني شحنة جزئية، واضح؟
+
+549
+00:45:00,270 --> 00:45:05,750
+بناء على ذلك قبل ما ننتهي من هذا الموضوع و ننهي
+
+550
+00:45:05,750 --> 00:45:11,870
+المحاضرة فيه لو أعطناكم الآن homework، أعطناكم هذا
+
+551
+00:45:11,870 --> 00:45:18,530
+المثال و حطنالكم عليه تلت أسهمأكمل المعادلة في
+
+552
+00:45:18,530 --> 00:45:23,830
+وجود البركوريك أستيت أكمل المعادلة في وجود H بلس
+
+553
+00:45:23,830 --> 00:45:30,930
+H2O و أكمل المعادلة في وجود ال BH3 و كل الأشياء
+
+554
+00:45:30,930 --> 00:45:37,380
+اللي موجودة معهفى كل حالة حيطلع عندى ناتج فى
+
+555
+00:45:37,380 --> 00:45:41,560
+الحالة الأولى هنا اتفقنا بتضيف H و OH بدون
+
+556
+00:45:41,560 --> 00:45:45,260
+rearrangement فى الحالة التانية عملناها قبل شوية
+
+557
+00:45:45,260 --> 00:45:48,800
+بتضيف ال H هنا و بيصير rearrangement و فى الأخر ال
+
+558
+00:45:48,800 --> 00:45:55,480
+OH ون بتيجي هنا فى هذه الحالة الأخيرة Anti
+
+559
+00:45:55,480 --> 00:46:00,780
+Markovnikov addition وين هتيجي ال H و ال OH
+
+560
+00:46:03,670 --> 00:46:09,090
+عكس قاعدة ماركوفيكو .. إذا هذا المثال التلت طرق
+
+561
+00:46:09,090 --> 00:46:16,430
+إضافة فيه بتعطيه كام ناتج؟ تلت نواتج مختلفة و لذلك
+
+562
+00:46:16,430 --> 00:46:21,890
+بدكم مش بس تقولوا أن المية بتضيف تلت طرق لأ بدكم
+
+563
+00:46:21,890 --> 00:46:28,460
+تفهموا الفرق بين هذه الطرق التلاتةالحالة الأولى
+
+564
+00:46:28,460 --> 00:46:32,240
+Markovnikov addition with rearrangement مع الذئبق
+
+565
+00:46:32,240 --> 00:46:35,780
+Markovnikov addition without rearrangement مع
+
+566
+00:46:35,780 --> 00:46:41,220
+البورين Anti Markovnikov addition واضح هذا الكلام؟
+
+567
+00:46:41,220 --> 00:46:47,340
+هنا ضيعنا فيه محاضرة لما نسأل فيه سؤال واحد لازم
+
+568
+00:46:47,340 --> 00:46:51,660
+كلكوا تجاوبوه واضح؟ واللي مش فاهمه بتروح على
+
+569
+00:46:51,660 --> 00:46:53,460
+التسجيل بتسمعوا كمان مرة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ.srt
new file mode 100644
index 0000000000000000000000000000000000000000..45a061fc6bdbe6411a7bce68b4923764c8d84c9b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ.srt
@@ -0,0 +1,1137 @@
+1
+00:00:08,920 --> 00:00:15,980
+بسم الله الرحمن الرحيم بنكمل اليوم في الفصل الأول
+
+2
+00:00:15,980 --> 00:00:21,980
+اللي هو مقدمة للكيمياء العضوية كنا اتكلمنا طبعًا عن
+
+3
+00:00:21,980 --> 00:00:26,620
+التوزيع الإلكتروني وأنواع الروابط اليوم إن شاء 
+
+4
+00:00:26,620 --> 00:00:32,250
+الله نقطة البداية تبعتنا هي كيف تتكون الروابط من
+
+5
+00:00:32,250 --> 00:00:36,310
+خلال الـ Orbitals أو الموضوع اللي بنسميه احنا The
+
+6
+00:00:36,310 --> 00:00:41,350
+Orbital View of Bonding يعني كيف أنا الـ Orbitals
+
+7
+00:00:41,350 --> 00:00:46,470
+نفسي اللي هي مواقع وجود الإلكترونات بتتحد مع بعضها
+
+8
+00:00:46,470 --> 00:00:51,470
+و بتعطينا الروابط طبعًا احنا سبق اتعرفنا على الـ
+
+9
+00:00:51,470 --> 00:00:56,000
+Orbitals كان في عندنا الـ S-Orbital وإذا بتذكروا
+
+10
+00:00:56,000 --> 00:01:00,860
+جميعًا أن الـ S-Orbital كان الشكل تبعه Spherical
+
+11
+00:01:00,860 --> 00:01:07,320
+والـ P-Orbitals كانت عادة تكون عبارة عن Two Loops
+
+12
+00:01:07,320 --> 00:01:12,760
+بناءً على ذلك لو مثلًا فكرنا نعمل رابطة لجزء
+
+13
+00:01:12,760 --> 00:01:16,100
+الهيدروجيني يعني اتحد عندي هيدروجين مع هيدروجين
+
+14
+00:01:16,100 --> 00:01:20,280
+الهيدروجين فيه One Electron هذا الـ Electron اللي
+
+15
+00:01:20,280 --> 00:01:24,490
+في الهيدروجين موجود بـ S-Orbital والـ electron اللي
+
+16
+00:01:24,490 --> 00:01:27,630
+في الهيدروجين الثاني بـ S orbital بناءً على ذلك أنا
+
+17
+00:01:27,630 --> 00:01:32,390
+لما أبدأ أكون رابطة بده يجى يصير تداخل أو بنسميه
+
+18
+00:01:32,390 --> 00:01:38,710
+overlap ما بين spherical S orbital و another
+
+19
+00:01:38,710 --> 00:01:44,050
+spherical S orbital فبدهم يتحدوا two spherical S
+
+20
+00:01:44,050 --> 00:01:49,430
+orbitals ويعطونا جزيء الهيدروجين ويعطونا جزيء
+
+21
+00:01:49,430 --> 00:01:57,140
+الهيدروجين طيب لو فكرنا بدنا نعمل جزء الـ HF لاحظوا
+
+22
+00:01:57,140 --> 00:02:01,620
+الـ H فيه one electron وهذا الـ electron برضه
+
+23
+00:02:01,620 --> 00:02:06,160
+موجود في S orbital و الفلورين الـ odd electron
+
+24
+00:02:06,160 --> 00:02:09,540
+اللي فيه لما نشوف توزيعه الإلكتروني موجود في P
+
+25
+00:02:09,540 --> 00:02:14,570
+orbital فلو اتكونت الرابطة ما بين الـ H و الـ F
+
+26
+00:02:14,570 --> 00:02:19,130
+هتكون ما بين S orbital .. spherical S orbital مع
+
+27
+00:02:19,130 --> 00:02:24,590
+الـ P orbital بهذا الشكل بيكون جزء الـ HF إذا الـ
+
+28
+00:02:24,590 --> 00:02:29,990
+bond هي حقيقة بين الـ S orbital و الـ P orbital لو
+
+29
+00:02:29,990 --> 00:02:35,390
+أجيتنا جزء مثل الـ F2 كل ذرة فلور فيها odd electron
+
+30
+00:02:35,390 --> 00:02:39,030
+في P orbital هي P orbital لذرة هي P orbital لذرة
+
+31
+00:02:39,030 --> 00:02:44,270
+لما بدهم يتفاعلوا هيعملوا sigma bond في كل الأحوال
+
+32
+00:02:44,270 --> 00:02:47,350
+الثلاث روابط اللي موجودة عندي هنا sigma bonds head
+
+33
+00:02:47,350 --> 00:02:52,710
+to head bonds وهيتكون عندي جزء لفلورين اللي هو
+
+34
+00:02:52,710 --> 00:02:57,290
+مكون من P orbital متحدة مع P orbital
+
+35
+00:02:59,970 --> 00:03:05,730
+الآن لو جئنا لأبسط جزء في الـ organic chemistry
+
+36
+00:03:05,730 --> 00:03:10,290
+اللي هو الميثين ومن بعده الـ إيثين وبدنا نشوف كيف
+
+37
+00:03:10,290 --> 00:03:16,370
+يتكون جزء الميثين كلنا بنعرف أن جزء الميثين CH4
+
+38
+00:03:16,370 --> 00:03:21,770
+طيب لما نقول الميثين CH4 معنى ذلك عندي أربع روابط
+
+39
+00:03:21,770 --> 00:03:28,150
+متصلة بالكاربون عندي أربع روابط متصلة بالـ Carbon
+
+40
+00:03:28,150 --> 00:03:34,010
+هذه الأربع روابط اللي متصلة بالـ Carbon بلزمها أنه
+
+41
+00:03:34,010 --> 00:03:37,950
+يكون عندي أربع أقود Electrons لو أنا بتطلع التوزيع
+
+42
+00:03:37,950 --> 00:03:42,850
+الإلكتروني للـ Carbon 1S2 2S2 2P2، 2P2 اللي أنا شايفه عبارة عن Two أقود Electrons
+
+43
+00:03:42,850 --> 00:03:46,490
+بناءً على ذلك اقترحت فكرة أنه يصير Promotion يصير
+
+44
+00:03:46,490 --> 00:03:53,260
+الـ ProMotion يطلع إلكترون من الـ S-Orbital يجي
+
+45
+00:03:53,260 --> 00:03:56,780
+على الـ P-Orbital الثالث الفاضي صار عنده أربع أقود
+
+46
+00:03:56,780 --> 00:04:01,540
+إلكترون لما تتم عملية hybridization يداخلوا دول
+
+47
+00:04:01,540 --> 00:04:05,700
+يتم عملية تهجين اللي مع بعض بيصيروا الأربع
+
+48
+00:04:05,700 --> 00:04:09,720
+Orbitals equivalent في الطاقة هدول الأربع Orbitals
+
+49
+00:04:09,720 --> 00:04:16,880
+equivalent في الطاقة هدول الأربع Orbitals
+
+50
+00:04:18,070 --> 00:04:22,850
+كل واحد مكون فيهم من جزء من S ومن الـ P الثلاثة
+
+51
+00:04:22,850 --> 00:04:30,130
+ولذلك كل واحد فيهم يسمى SP3 SP3 SP3 SP3 Orbitals
+
+52
+00:04:30,130 --> 00:04:35,470
+كيف شكلوا الـ SP3 Orbitals؟ هو حقيقة عبارة عن لوب
+
+53
+00:04:35,470 --> 00:04:42,390
+كبير لوب كبير ومعه لوب صغير ثاني موجود خليط من الـ
+
+54
+00:04:42,390 --> 00:04:46,890
+S و الـ P Orbitals هدولة بيكونوا الأربعة loops
+
+55
+00:04:46,890 --> 00:04:51,230
+اللي هم SP3 و SP3 و SP3 و SP3 hybrid orbitals
+
+56
+00:04:51,230 --> 00:04:56,150
+موجودين على رأس الـ tetrahedral structure وكل واحد
+
+57
+00:04:56,150 --> 00:04:59,190
+فيه odd electron يعني هنا في عندي odd electron هنا
+
+58
+00:04:59,190 --> 00:05:02,430
+odd electron هنا odd electron هنا odd electron لما
+
+59
+00:05:02,430 --> 00:05:06,350
+يجي يتفاعل مع الهيدروجين ال spherical orbital هذا
+
+60
+00:05:06,350 --> 00:05:08,990
+في odd electron هذا odd electron هذا odd electron
+
+61
+00:05:08,990 --> 00:05:13,970
+هذا odd electron بيعملوا عندي رابطة اثنتين ثلاث
+
+62
+00:05:13,970 --> 00:05:18,750
+أربع فصار عندي جزء الميثين carbon hydrogen
+
+63
+00:05:18,750 --> 00:05:23,230
+hydrogen hydrogen hydrogen لو قلنا ايش نوع الرابطة
+
+64
+00:05:23,230 --> 00:05:28,450
+في جزء الميثين الجواب الرابطة في جزء الميثين
+
+65
+00:05:28,450 --> 00:05:35,730
+مكونة من S orbital من الهيدروجين مع SP3 orbital
+
+66
+00:05:35,730 --> 00:05:41,730
+من الكربون SP3 hybrid orbital من الكربون مع S
+
+67
+00:05:41,730 --> 00:05:47,830
+orbital من الهيدروجين طبعًا هذا الشكل اللي هو شكل
+
+68
+00:05:47,830 --> 00:05:52,830
+الزوايا الـ Tetrahedral Structure أو الميثين هو
+
+69
+00:05:52,830 --> 00:05:58,710
+الشكل اللي احنا بنشوفه هنا بالموديل عبارة عن ذرة
+
+70
+00:05:58,710 --> 00:06:05,970
+كربون بـ three dimensions طالع منها أربع روابط في
+
+71
+00:06:05,970 --> 00:06:10,130
+الأساس كانوا أربع orbitals وصاروا أربع روابط رابطة
+
+72
+00:06:10,130 --> 00:06:14,920
+مع الهيدروجين اثنتين ثلاث أربع الآن كل زاوية من
+
+73
+00:06:14,920 --> 00:06:19,080
+هذه الزوايا .. كل زاوية من هذه الزوايا مئة وتسعة
+
+74
+00:06:19,080 --> 00:06:21,780
+ونصف يعني هذه زاوية مئة وتسعة ونصف، هذه مئة و
+
+75
+00:06:21,780 --> 00:06:24,120
+تسعة ونصف، هذه مئة وتسعة ونصف، هذه مئة وتسعة و
+
+76
+00:06:24,120 --> 00:06:26,280
+نصف، هذه مئة وتسعة ونصف، هذه مئة وتسعة ونصف، هذه
+
+77
+00:06:26,280 --> 00:06:27,160
+مئة وتسعة ونصف، هذه مئة وتسعة ونصف فالشكل هذا
+
+78
+00:06:27,160 --> 00:06:32,870
+متماثل بشكل عام هذا الـ tetrahedral structure أسهل
+
+79
+00:06:32,870 --> 00:06:38,150
+طريقة لتخيله إنه نبسطه بهذا الشكل نتخيل أنه احنا
+
+80
+00:06:38,150 --> 00:06:42,470
+أمام مستويين متعامدين هذه هيدروجين و هذه
+
+81
+00:06:42,470 --> 00:06:47,350
+هيدروجين نخليهم بمستوى أفقي هذول هيدروجين
+
+82
+00:06:47,350 --> 00:06:52,870
+نخليهم بمستوى أفقي والزاوية بينهم 109.5 عمودي على
+
+83
+00:06:52,870 --> 00:06:57,780
+هذا المستوى الأفقي عمودي عليه تمامًا مستوى ثاني في
+
+84
+00:06:57,780 --> 00:07:01,760
+الـ Two Hydrogens وأيضًا الزاوية بينهم 109.5 ونصف
+
+85
+00:07:01,760 --> 00:07:07,000
+إذًا احنا بنقول أفضل طريقة للتعامل مع الـ
+
+86
+00:07:07,000 --> 00:07:11,500
+tetrahedral structure أن أتخيل الروابط موجودة في
+
+87
+00:07:11,500 --> 00:07:15,800
+مستويين متعامدين مستوى horizontal و مستوى
+
+88
+00:07:15,800 --> 00:07:20,650
+perpendicular عليه يعني عمودي عليه الزاوية هي 109.5
+
+89
+00:07:20,650 --> 00:07:25,470
+و 109.5 طبعًا باقي الزاوية بتكون كلها 109.5 ولذلك
+
+90
+00:07:25,470 --> 00:07:30,270
+هذا الميثين يعتبر جزء عالي التماثل هذا الميثين
+
+91
+00:07:30,270 --> 00:07:37,750
+يعتبر جزء عالي التماثل الآن لو اطلعنا من جزء
+
+92
+00:07:37,750 --> 00:07:42,370
+الميثين إلى جزء أكبر شوية منه اللي هو فيه two
+
+93
+00:07:42,370 --> 00:07:47,990
+carbons اللي هو جزء ال إيثين عشان أعمل جزء الـ
+
+94
+00:07:47,990 --> 00:07:52,610
+Ethane باستفيد من كل الكلام السابق بفترض أنه الـ
+
+95
+00:07:52,610 --> 00:07:58,160
+Carbon عاملة SP3 Hybrid Orbitals أربع الآن بين
+
+96
+00:07:58,160 --> 00:08:00,800
+الـ Carbon و الـ Carbon هذه الرابطة اللي احنا
+
+97
+00:08:00,800 --> 00:08:05,300
+بنركز عليها بين الـ Carbon و الـ Carbon بتحد SP3
+
+98
+00:08:05,300 --> 00:08:10,040
+Hybrid Orbital من الـ Carbon الأولى مع SP3 Hybrid
+
+99
+00:08:10,040 --> 00:08:13,440
+Orbital من الـ Carbon الثانية إذا كل واحدة من هدول
+
+100
+00:08:13,440 --> 00:08:18,220
+هذه SP3 وهذه SP3 بيعملوا الرابطة الأحادية اللي هي
+
+101
+00:08:18,220 --> 00:08:22,120
+بين الـ Carbon و الـ Carbon طيب باقي ال orbitals
+
+102
+00:08:22,120 --> 00:08:27,540
+كلهم بيعملوا روابط مع الهيدروجين فبصير جزاء الـ Ethane
+
+103
+00:08:27,540 --> 00:08:33,660
+عبارة عن CH3 CH3
+
+104
+00:08:34,790 --> 00:08:39,190
+زي ما بنلاحظ كل روابط سبعة كل روابط بين الكاربون
+
+105
+00:08:39,190 --> 00:08:43,510
+والهيدروجين واحدة اثنتين ثلاث أربع خمسة ستة اثنتين
+
+106
+00:08:43,510 --> 00:08:50,350
+ثلاث أربع خمسة ستة اثنتين ثلاث خمسة ستة 
+
+107
+00:08:50,350 --> 00:08:54,950
+اثنتين ثلاث ثلاث ثلاث
+
+108
+00:08:54,950 --> 00:08:58,010
+اثنتين
+
+109
+00:08:58,010 --> 00:09:02,270
+ثلاث ثلاث ثلاث
+
+110
+00:09:02,680 --> 00:09:07,700
+SP3 hybrid orbital من الكربون الثانية وزي ما أنتم 
+
+111
+00:09:07,700 --> 00:09:11,300
+شايفين احنا بنقول the bond formed by end to end
+
+112
+00:09:11,300 --> 00:09:15,960
+overlap رأس لرأس أو طرف لطرف is called a sigma
+
+113
+00:09:15,960 --> 00:09:24,400
+bond وهذا هو شكل جزء الـ Ethane زي ما أنتم شايفينه 
+
+114
+00:09:24,400 --> 00:09:30,600
+عندي Carbon حاملة ثلاث Hydrogens Carbon ثانية
+
+115
+00:09:30,600 --> 00:09:34,220
+حاملة ثلاث Hydrogens وبين الـ Carbon و الـ
+
+116
+00:09:34,220 --> 00:09:37,740
+Carbon عندي Single Bond الآن لما بدي أكد على ال
+
+117
+00:09:37,740 --> 00:09:41,220
+Orbitals اللي مكونة منها روابط هذه الرابطة اللي
+
+118
+00:09:41,220 --> 00:09:45,110
+بين ال Carbon و ال Carbon مكونة من ايش؟ من SP3
+
+119
+00:09:45,110 --> 00:09:49,050
+hybrid orbital مع SP3 كل هدول الروابط مكونين من
+
+120
+00:09:49,050 --> 00:09:51,630
+SP3 مع S SP3 مع S وهكذا
+
+121
+00:09:56,240 --> 00:10:01,460
+طبعًا هذا الشكل بأكد لنا اللي هو جزء الـ Methane
+
+122
+00:10:01,460 --> 00:10:05,160
+اللي تاوم سيكناه وفرجناكوا إياه واللي زاوية فيه
+
+123
+00:10:05,160 --> 00:10:10,540
+109.5 ونرسمه بطرق مختلفة هذه أفضل طريقة نرسمه اللي
+
+124
+00:10:10,540 --> 00:10:14,860
+بنتخيل أنه في عندنا أفقيًا ذرتين هيدروجين للأمام
+
+125
+00:10:14,860 --> 00:10:19,980
+في مستوى أفقي وعمودي عليهم ذرتين هيدروجين للخلف
+
+126
+00:10:20,070 --> 00:10:24,510
+في المستوى المتعامد عليهم وجميع الزوايا اللي موجودة
+
+127
+00:10:24,510 --> 00:10:28,350
+في هذا الـ tetrahedral structure هي حقيقة زوايا
+
+128
+00:10:28,350 --> 00:10:30,890
+109.5 درجة
+
+129
+00:10:33,100 --> 00:10:38,620
+الآن بنقول طيب كيف ال bonding في جزاء ال إيثين ال
+
+130
+00:10:38,620 --> 00:10:43,240
+إيثيلين أو ال إيثين اسمه بال أيوبك إيثين هناخده
+
+131
+00:10:43,240 --> 00:10:48,880
+بالتفصيل وبال common name إيثيلين هذا الجزء عبارة
+
+132
+00:10:48,880 --> 00:10:53,840
+عن ذرتين كربون وأربع هيدروجينات بمعنى CH2 CH2
+
+133
+00:10:54,960 --> 00:10:59,280
+ولما شافوا الزوايا تبعته بالقياسات لاحظوا أن
+
+134
+00:10:59,280 --> 00:11:03,940
+الزاوية هذه 120 هذه 120 هذه 120 هذه 120 هذه 120 هذه
+
+135
+00:11:03,940 --> 00:11:04,900
+120 هذه 120 هذه 120 هذه 120 هذه 120 هذه 120 هذه
+
+136
+00:11:04,900 --> 00:11:04,920
+120 هذه 120 هذه 120 هذه 120 هذه 120 هذه 120 هذه
+
+137
+00:11:04,920 --> 00:11:05,020
+120 هذه 120 هذه 120 هذه 120 هذه 120 هذه 120 هذه
+
+138
+00:11:05,020 --> 00:11:05,040
+120 هذه 120 هذه 120 هذه 120 هذه 120 هذه 120 هذه
+
+139
+00:11:05,040 --> 00:11:05,060
+120 هذه 120 هذه 120 هذه 120 هذه 120 هذه 120 هذه
+
+140
+00:11:05,060 --> 00:11:05,100
+120 هذه 120 هذه 120 هذه 120 هذه 120 هذه 120 هذه
+
+141
+00:11:05,100 --> 00:11:05,440
+120 هذه 120 هذه 120 هذه 120 هذه 120 هذه 120 هذه
+
+142
+00:11:05,440 --> 00:11:08,480
+120 هذه
+
+143
+00:11:16,160 --> 00:11:19,860
+الآن زي ما بنلاحظ أن الكربون بشكل أساسي طالع من
+
+144
+00:11:19,860 --> 00:11:25,200
+الثلاث اتجاهات 1 2 3 بناءً على ذلك الروابط الأساسية
+
+145
+00:11:25,200 --> 00:11:28,980
+اللي بتعملها الكربون ثلاثة لما نيجي نشوف كيف هذا
+
+146
+00:11:28,980 --> 00:11:32,520
+الكلام بيصير نرجع للتوزيع الإلكتروني للكربون
+
+147
+00:11:32,520 --> 00:11:34,320
+1S2 2S2 2P2
+
+148
+00:11:35,920 --> 00:11:40,980
+لو عملنا promotion طلعنا هذول الاثنين وحطينا
+
+149
+00:11:40,980 --> 00:11:46,700
+واحد هنا صار عنده SP2 SP2 SP2 وكمان واحد اسمه P
+
+150
+00:11:46,700 --> 00:11:50,040
+orbital لاحظوا أن احنا عملنا ال promotion في
+
+151
+00:11:50,040 --> 00:11:53,320
+الأول طلعنا ال electron صار أربع electronات لما
+
+152
+00:11:53,320 --> 00:11:56,800
+بدي أخلط أنا كم رابطة أساسية بدي واحدة اثنتين
+
+153
+00:11:56,800 --> 00:12:01,340
+ثلاث عشان هيك بنخلط ال S مع اثنين من ال P هاي ال
+
+154
+00:12:01,340 --> 00:12:06,380
+S مع اثنين من ال P بيعطيني SP2 SP2 SP2 وبيظل عندي
+
+155
+00:12:06,380 --> 00:12:11,780
+بي أوربيتال لما بدي آتي أطلع عليهم هدولة كيف شكلهم
+
+156
+00:12:11,780 --> 00:12:18,320
+الروابط بيكون عند SP2 SP2 SP2 اللي مبينين باللون
+
+157
+00:12:18,320 --> 00:12:22,960
+الأخضر والزاوية بينهم بين كل أخضر والتاني 120
+
+158
+00:12:22,960 --> 00:12:28,540
+درجة مئوية عمودي عليهم بيكون الـ P orbital عمودي
+
+159
+00:12:28,540 --> 00:12:31,960
+عليهم الـ P orbital الآن زي ما بتلاحظوا كل SP2
+
+160
+00:12:31,960 --> 00:12:37,250
+orbital في one electron و ال P orbital فيها one
+
+161
+00:12:37,250 --> 00:12:41,410
+electron طيب لو بدي أكون جزيه الإيثيلين بكونه من كم
+
+162
+00:12:41,410 --> 00:12:46,350
+carbon؟ اثنتين يعني بدي هذه وكمان واحدة زيها نحطهم
+
+163
+00:12:46,350 --> 00:12:52,240
+جنب بعض لاحظوا لما نحطهم جنب بعض الرابطة الأساسية
+
+164
+00:12:52,240 --> 00:12:56,300
+اللي بين الـ Carbon والـ Carbon الـ End to End أو
+
+165
+00:12:56,300 --> 00:13:02,240
+Head to Head الـ Sigma Bond مكونة من ايش؟ من SP2
+
+166
+00:13:02,240 --> 00:13:06,700
+Hybrid Orbital مع SP2 Hybrid Orbital ظل عند اثنين
+
+167
+00:13:06,700 --> 00:13:12,180
+SP2 هدول هيتفاعلوا من خلال ايش؟ مع الـ Hydrogen
+
+168
+00:13:12,180 --> 00:13:16,520
+هتكون الرابطة بين الكربون والهيدروجين في الإيثيلين
+
+169
+00:13:16,520 --> 00:13:24,200
+مكونة من أي Orbitals SP2 مع S SP2 مع S SP2 مع S
+
+170
+00:13:24,200 --> 00:13:25,540
+SP2 مع S SP2 مع S SP2 مع S 
+
+171
+00:13:25,540 --> 00:13:26,200
+SP2 مع S SP2 مع S SP2 مع S 
+
+172
+00:13:26,200 --> 00:13:28,120
+SP2 مع S SP2 مع S SP2 مع S 
+
+173
+00:13:28,120 --> 00:13:29,780
+SP2 مع S SP2 مع S SP2 مع S 
+
+174
+
+201
+00:15:31,910 --> 00:15:36,250
+وما أدراك إذا بتلاحظوا الجزء من ناحية الذرات
+
+202
+00:15:36,250 --> 00:15:40,330
+hydrogen .. hydrogen .. carbon .. carbon ..
+
+203
+00:15:40,330 --> 00:15:44,550
+hydrogen .. hydrogen الجزء كله planar الجزء كله 
+
+204
+00:15:44,550 --> 00:15:48,830
+في مستوى واحد طب هايش اللي متعمد عليه هنا بي
+
+205
+00:15:48,830 --> 00:15:54,080
+orbital هنا و B orbital هنا هذا فيه إلكترون وهذا 
+
+206
+00:15:54,080 --> 00:15:58,700
+فيه إلكترون الآن هنا بيصير overlapping أو تداخل
+
+207
+00:15:58,700 --> 00:16:02,020
+للإلكترونات من فوق ومن تحت بيعملولي الـ pi bond
+
+208
+00:16:02,020 --> 00:16:07,000
+فالإيثيلين بيوصف بأكمله بـ two bonds double bond
+
+209
+00:16:07,000 --> 00:16:11,200
+واحدة منهم sigma جاية من overlaping وما overlaping والتانية 
+
+210
+00:16:11,200 --> 00:16:15,800
+بي من تداخل الـ P orbital من فوق مستوى الجزء ومن
+
+211
+00:16:15,800 --> 00:16:18,640
+تحت مستوى الجزء، هذه الجزء، هذه المستوى تبع الجزء
+
+212
+00:16:19,300 --> 00:16:22,140
+الجزء زي ما احنا شايفينه الـ planar والـ P
+
+213
+00:16:22,140 --> 00:16:26,860
+-orbitals متعامدات عليه هذا هو الـ orbital view
+
+214
+00:16:26,860 --> 00:16:33,500
+لجزء الإيثيلين هذا هو ال orbital view لجزء الإيثيلين
+
+215
+00:16:33,500 --> 00:16:38,700
+الآن
+
+216
+00:16:39,770 --> 00:16:44,970
+لو بدنا ناخد جزء ثالث اللي هو جزء الـ Acetylene
+
+217
+00:16:44,970 --> 00:16:51,090
+الـ Acetylene معروف هو الجزء اللي هو عبارة عن C2H2
+
+218
+00:16:51,090 --> 00:16:57,390
+دراسة هذا الجزء أثبتت أن هذا الجزء Linear يعني
+
+219
+00:16:57,390 --> 00:17:02,230
+ماخد الشكل الخطي والرابط بين الكربون والكربون 
+
+220
+00:17:02,230 --> 00:17:07,410
+triple bond قصيرة الآن كيف بيصير ال orbitals
+
+221
+00:17:09,110 --> 00:17:13,590
+بتتكون وبتتحد في هذا الجزء نفس الشيء شكل الـ
+
+222
+00:17:13,590 --> 00:17:18,710
+Carbon 1 S2 to S2 to P2 بيصير عنده promotion الآن
+
+223
+00:17:18,710 --> 00:17:22,090
+هنا الـ Carbon كام رابطة أساسية عاملة؟ رابطة
+
+224
+00:17:22,090 --> 00:17:27,510
+والثانية الأساسية بناءً على ذلك، بيصير اتحاد أسمع 
+
+225
+00:17:27,510 --> 00:17:33,420
+P بيكون ليه؟ SP Orbital و SP Orbital، بيظل عندي 2P
+
+226
+00:17:33,420 --> 00:17:36,980
+Orbitals، خلينا مثلا نتجاوز نقول إن هما الـ 2PY و
+
+227
+00:17:36,980 --> 00:17:41,600
+2PZ و هدول زي ما احنا عارفين متعامدات على بعض
+
+228
+00:17:42,570 --> 00:17:48,070
+لاحظوا هذا هو شكل الـOrbitals، هذا الأخضر هو الـSP
+
+229
+00:17:48,070 --> 00:17:52,370
+Orbital، وهذا SP Orbital، وفي عندي P Orbital
+
+230
+00:17:52,370 --> 00:17:56,650
+عمودي، وفي P Orbital ثاني عمودي عليه، يعني واحد
+
+231
+00:17:56,650 --> 00:18:02,370
+فوق وتحت والثاني للأمام وللخلف الآن عندما أعمل
+
+232
+00:18:02,370 --> 00:18:06,170
+اتحاد كربون ثاني من هذا الشكل هلاحظ أن الكربون
+
+233
+00:18:06,170 --> 00:18:11,310
+الأولى هيجي SP Orbital منها يتحد مع الـ SP Orbital
+
+234
+00:18:11,310 --> 00:18:15,970
+تبع الكربون الثاني ويعمل sigma bond هذه الـ
+
+235
+00:18:15,970 --> 00:18:18,510
+sigma bond زي ما بنلاحظ بين الكربون والكربون في 
+
+236
+00:18:18,510 --> 00:18:23,530
+الـ acetylene من أي Orbitals من SP مع SP الـ SP 
+
+237
+00:18:23,530 --> 00:18:28,090
+Orbital الثاني هيتحد مع الهيدروجين بناء على ذلك هيصير
+
+238
+00:18:28,090 --> 00:18:33,630
+شكل الجزء هيدروجين كربون كربون هيدروجين Linear
+
+239
+00:18:33,630 --> 00:18:37,530
+لاحظوا هذه الأربع نقاط السمر هيدروجين كربون
+
+240
+00:18:37,530 --> 00:18:41,890
+كربون هيدروجين Linear ايش ضال عنده؟ ضال عند ال P
+
+241
+00:18:41,890 --> 00:18:49,560
+Orbitals فوقو تحت وأمام و خلف اللي فوق مع بعض
+
+242
+00:18:49,560 --> 00:18:53,440
+بيعملوا overlapping بيصير كثافة أو سحابة إلكترونية
+
+243
+00:18:53,440 --> 00:18:57,500
+فوق سحابة إلكترونية تحت سحابة إلكترونية في الخلف 
+
+244
+00:18:57,500 --> 00:19:01,920
+سحابة إلكترونية في الأمام كأنه بيصير عنده
+
+245
+00:19:01,920 --> 00:19:06,220
+cylindrical electronic cloud يعني سحابة إلكترونية
+
+246
+00:19:06,220 --> 00:19:10,380
+أسطوانية فوق وتحت وقدام وورا يعني كأنه الجزيء 
+
+247
+00:19:10,750 --> 00:19:18,650
+بالمجمل محاط بـ سحابات إلكترونية لاحظوا هنا أن هذا
+
+248
+00:19:18,650 --> 00:19:23,650
+الجزء فيه ثلاث روابط لو أجينا نصنفهم لـ triple bond
+
+249
+00:19:23,650 --> 00:19:27,940
+عبارة عن ايش؟ لو إجينا نشوف الـ triple bonds عبارة
+
+250
+00:19:27,940 --> 00:19:33,000
+عن ايش؟ عبارة عن واحدة منهم sigma bond جاية من SP
+
+251
+00:19:33,000 --> 00:19:39,200
+مع SP والثانية منهم عبارة عن pi bond جاية مثلا من
+
+252
+00:19:39,200 --> 00:19:44,160
+PY مع PY والثالثة برضه pi bond جاية مع PY مع PY لو
+
+253
+00:19:44,160 --> 00:19:50,070
+بدنا نشوف هذا الجزء بتفصيل كـ Orbitals بنقول في
+
+254
+00:19:50,070 --> 00:19:55,090
+عندنا الـ Carbon عاملة رابطة مع الـ Carbon رابطة
+
+255
+00:19:55,090 --> 00:19:58,390
+أحادية الأولى هذه الـ Sigma Bond اللي إحنا شايفينها 
+
+256
+00:19:58,390 --> 00:20:03,550
+هذه عبارة عن SP مع SP الـ SP الثاني عامل مع الـ 
+
+257
+00:20:03,550 --> 00:20:06,250
+Hydrogen والـ SP الثاني عامل مع الـ Hydrogen لما
+
+258
+00:20:06,250 --> 00:20:11,110
+نشوف شكل الجزء الجزء Linear Hydrogen Carbon Carbon
+
+259
+00:20:11,110 --> 00:20:16,790
+Hydrogen Linear زاوية 180 درجة الآن في عند الـ PY
+
+260
+00:20:18,170 --> 00:20:22,890
+عمودي فوق وتحت وهي الـ PY هدول لما ييجوا يتحدوا 
+
+261
+00:20:22,890 --> 00:20:25,650
+مع بعض بيعملوا سحابة إلكترونية فوق وسحابة
+
+262
+00:20:25,650 --> 00:20:31,850
+إلكترونية تحت عنده الـ PZ عمودي عليه لكن للأمام
+
+263
+00:20:31,850 --> 00:20:35,650
+هاي PZ وهاي PZ هدول بيعملوا سحابة إلكترونية من
+
+264
+00:20:35,650 --> 00:20:39,030
+قدام هدول بيعملوا سحابة إلكترونية من ورا بناء على
+
+265
+00:20:39,030 --> 00:20:44,610
+ذلك كأنه صار عنده سحابة إلكترونية من فوق ومن تحت و
+
+266
+00:20:44,610 --> 00:20:50,150
+من قدام ومن ورا يعني محوطة الـ Sigma bond هدولة
+
+267
+00:20:50,150 --> 00:20:52,950
+اللي من فوق ومن تحت عبارة عن Pi bond واللي من 
+
+268
+00:20:52,950 --> 00:20:55,870
+الأمام والخلف عبارة عن Pi bond إذا الـ Triple
+
+269
+00:20:55,870 --> 00:21:02,330
+bond حقيقة مكونة من Sigma bond زائد Two Pi bonds
+
+270
+00:21:02,330 --> 00:21:05,410
+واحدة اللي هي من فوق ومن تحت والتالية اللي هي من 
+
+271
+00:21:05,410 --> 00:21:12,860
+الأمام ومن الخلف هذا هو شكل جزء الـ Acetylene من 
+
+272
+00:21:12,860 --> 00:21:17,780
+ناحية الـ Orbitals وبهيك تقريباً بيكون غطينا الـ
+
+273
+00:21:17,780 --> 00:21:21,240
+Orbital View للجزيئات الأساسية في الـ Organ
+
+274
+00:21:21,240 --> 00:21:25,780
+الكميسترية اللي هم الـ Methane والإيثان والإيثين
+
+275
+00:21:25,780 --> 00:21:33,530
+أو الإيثيلين والإيثاين أو ال Acetylene آخر حاجة في
+
+276
+00:21:33,530 --> 00:21:37,670
+هذا الفصل واحنا زي ما اتفقنا أن هذا فصل مقدمة
+
+277
+00:21:37,670 --> 00:21:42,810
+بجهزنا لدراسة الـ Organ Chemistry كيف احنا بدنا
+
+278
+00:21:42,810 --> 00:21:46,150
+ندرس الـ Organ Chemistry الـ Organ Chemistry
+
+279
+00:21:46,150 --> 00:21:51,150
+مركبات كثيرة بتزيد عن خمسة مليون مركب لاحظوا لما
+
+280
+00:21:51,150 --> 00:21:55,210
+بنحكي عن خمسة مليون مركب قصة كبيرة كيف أنا بدي
+
+281
+00:21:55,210 --> 00:21:59,870
+أدرس خمسة مليون مركب بصنفهم لعائلات بسميها
+
+282
+00:21:59,870 --> 00:22:04,350
+الـfunctional groups أو المجموعات الوظيفية هذه
+
+283
+00:22:04,350 --> 00:22:07,590
+الـfunctional groups مثلا المركبات اللي فيها
+
+284
+00:22:07,590 --> 00:22:10,710
+رابطة أحادية شايفينها باللون الأحمر بسميها الـAlkanes
+
+285
+00:22:10,710 --> 00:22:16,420
+اللي فيها رابطة ثنائية الـAlkenes اللي فيها رابطة
+
+286
+00:22:16,420 --> 00:22:22,380
+ثلاثية الـAlkynes اللي فيها حلقة مع روابط ثنائية
+
+287
+00:22:22,380 --> 00:22:27,380
+بقول عنها الـ Aromatic Compounds اللي فيها OH الـ
+
+288
+00:22:27,380 --> 00:22:32,080
+Alcohol اللي فيها SH الـ Thiols اللي فيها Oxygen
+
+289
+00:22:32,080 --> 00:22:38,040
+بين مجموعتين R بين كربنتين الـ Ethers اللي فيها
+
+290
+00:22:38,040 --> 00:22:43,220
+Sulphur بين كربنتين الـ Thioethers اللي فيها C
+
+291
+00:22:43,220 --> 00:22:46,780
+double bond O جنبها H  الـAldehyde، C double bond O
+
+292
+00:22:46,780 --> 00:22:50,700
+جنبها Carbons من الجهتين R groups الـKetone، C 
+
+293
+00:22:50,700 --> 00:22:55,280
+double bond O جنبها OH الـCarboxylic acid، C double bond O
+
+294
+00:22:55,280 --> 00:22:59,700
+جنبها OR الـEster، C double bond O جنبها Cl أو Br
+
+295
+00:22:59,700 --> 00:23:04,380
+الـAcid halide، جنبها NH2 الـAmide، المركبات الكربون 
+
+296
+00:23:04,380 --> 00:23:08,200
+اللي حاملة الـNH2 الـAmine، اللي حاملة الـCN الـNitrile
+
+297
+00:23:09,110 --> 00:23:12,530
+لاحظوا هذه هي العائلات الأساسية خلينا نقول في الـ 
+
+298
+00:23:12,530 --> 00:23:16,470
+Organ Chemistry احنا في هذا المساق هندرس كل هذه
+
+299
+00:23:16,470 --> 00:23:21,670
+العائلات، يعني في الفصل الأول أخدنا مقدمة، بالفصل
+
+300
+00:23:21,670 --> 00:23:26,560
+الثاني بناخد الـ Alkanes بالفصل الثالث بناخد
+
+301
+00:23:26,560 --> 00:23:30,700
+الـAlkenes والـAlkynes، بالفصل الرابع بناخد
+
+302
+00:23:30,700 --> 00:23:34,200
+الـAromatic Compounds، بالفصل الخامس بناخد شوية 
+
+303
+00:23:34,200 --> 00:23:38,340
+Stereochemistry، وبالسادس بندرس تفاعلات الإبدال،
+
+304
+00:23:38,340 --> 00:23:43,270
+في السابع بناخد الـAlcohols والـThiols في الثامن 
+
+305
+00:23:43,270 --> 00:23:46,930
+بناخد الـEthers والـ Thioethers في التاسع الـAldehyde
+
+306
+00:23:46,930 --> 00:23:51,530
+والـKetone في العاشر الـCarboxylic acid ومشتقاته وفي شبطر 11 ال
+
+307
+00:23:51,530 --> 00:23:57,070
+Amines هذا هو المفردات اللي بدنا ندرسها في هذا
+
+308
+00:23:57,070 --> 00:24:02,120
+المساق بـ 11 فصل تمثل العائلات الأساسية في الـ
+
+309
+00:24:02,120 --> 00:24:05,460
+organic compounds كل عائلة أثناء دراستها بناخدها 
+
+310
+00:24:05,460 --> 00:24:11,600
+بالتفصيل وبناخد خواصها وتحضيرها وتفاعلاتها وإن شاء 
+
+311
+00:24:11,600 --> 00:24:13,560
+الله إلى محاضرة قادمة
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e04652c40021ef51f2b462cea2cacaac8f3837c8
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_postprocess.srt
@@ -0,0 +1,1244 @@
+1
+00:00:08,920 --> 00:00:15,980
+بسم الله الرحمن الرحيم بنكمل اليوم في الفصل الأول
+
+2
+00:00:15,980 --> 00:00:21,980
+اللي هو مقدمة للكيمياء العضوية كنا اتكلمنا طبعا عن
+
+3
+00:00:21,980 --> 00:00:26,620
+التوزيع الإلكتروني وأنواع الروابط اليوم إن شاء
+
+4
+00:00:26,620 --> 00:00:32,250
+الله نقطة البداية تبعتناهي كيف تتكون الروابط من
+
+5
+00:00:32,250 --> 00:00:36,310
+خلال الـ Orbitals أو الموضوع اللي بنسميه احنا The
+
+6
+00:00:36,310 --> 00:00:41,350
+Orbital View of Bonding يعني كيف انا الـ Orbitals
+
+7
+00:00:41,350 --> 00:00:46,470
+نفسي اللي هي مواقع وجود الإلكترونات بتتحد مع بعضها
+
+8
+00:00:46,470 --> 00:00:51,470
+و بتعطينا الروابط طبعا احنا سبق اتعرفنا على الـ
+
+9
+00:00:51,470 --> 00:00:56,000
+Orbitals كان في عندنا الـ S-Orbitalوإذا بتذكروا
+
+10
+00:00:56,000 --> 00:01:00,860
+جميعًا إن الـ S-Orbital كان الشكل تبعه Spherical
+
+11
+00:01:00,860 --> 00:01:07,320
+والـ B-Orbitals كانت عادة تكون عبارة عن Two Loops
+
+12
+00:01:07,320 --> 00:01:12,760
+بناءً على ذلك لو مثلًا فكرنا نعمل رابطة لجزء
+
+13
+00:01:12,760 --> 00:01:16,100
+الهيدروجيني يعني اتحد عنده هيدروجين مع هيدروجين
+
+14
+00:01:16,100 --> 00:01:20,280
+الهيدروجين فيه One Electron هذا الـ Electron اللي
+
+15
+00:01:20,280 --> 00:01:24,490
+في الهيدروجين موجود بـ S-Orbitalوالـ electron اللى
+
+16
+00:01:24,490 --> 00:01:27,630
+فى الهيدروجين التانى بـ S orbital بناء على ذلك أنا
+
+17
+00:01:27,630 --> 00:01:32,390
+لما بدأ أكون رابطة بده يجى يصير تداخل أو بنسميه
+
+18
+00:01:32,390 --> 00:01:38,710
+overlap ما بين spherical S orbital و another
+
+19
+00:01:38,710 --> 00:01:44,050
+spherical S orbital فبدهم يتحدوا two spherical S
+
+20
+00:01:44,050 --> 00:01:49,430
+orbitals ويعطونا جزيء الهيدروجين ويعطونا جزيء
+
+21
+00:01:49,430 --> 00:01:57,140
+الهيدروجينطيب لو فكرنا بدنا نعمل جزء الـ HF لاحظوا
+
+22
+00:01:57,140 --> 00:02:01,620
+الـ H فيه one electron و هذا الـ electron برضه
+
+23
+00:02:01,620 --> 00:02:06,160
+موجود في S orbital و الفلورين الـ odd electron
+
+24
+00:02:06,160 --> 00:02:09,540
+اللي فيه لما نشوف توزيعه الإلكتروني موجود في B
+
+25
+00:02:09,540 --> 00:02:14,570
+orbitalفلو اتكونت الرابطة ما بين الـ H و الـ F
+
+26
+00:02:14,570 --> 00:02:19,130
+هتكون ما بين S orbital .. spherical S orbital مع
+
+27
+00:02:19,130 --> 00:02:24,590
+الـ B orbital بهذا الشكل بيكون جزء الـ HF إذا الـ
+
+28
+00:02:24,590 --> 00:02:29,990
+bond هي حقيقة بين الـ S orbital و الـ B orbital لو
+
+29
+00:02:29,990 --> 00:02:35,390
+إجيتنا جزء مثل الـ F2كل ذرة فلور فيها odd electron
+
+30
+00:02:35,390 --> 00:02:39,030
+في B orbital هي B orbital لذرة هي B orbital لذرة
+
+31
+00:02:39,030 --> 00:02:44,270
+لما بدهم يتفاعلوا هيعملوا sigma bond في كل الأحوال
+
+32
+00:02:44,270 --> 00:02:47,350
+التلت روابط اللي موجودة عندى هنا sigma bonds head
+
+33
+00:02:47,350 --> 00:02:52,710
+to head bonds وهيتكون عندى جزء لفلورين اللى هو
+
+34
+00:02:52,710 --> 00:02:57,290
+مكوّن من B orbital متحدة مع B orbital
+
+35
+00:02:59,970 --> 00:03:05,730
+الآن لو اجينا لأبسط جزء في الـ organic chemistry
+
+36
+00:03:05,730 --> 00:03:10,290
+اللي هو الميثين ومن بعده الـ إيثين وبدنا نشوف كيف
+
+37
+00:03:10,290 --> 00:03:16,370
+بيتكون جزء الميثين كلنا بنعرف إن جزء الميثين CH4
+
+38
+00:03:16,370 --> 00:03:21,770
+طيب لما نقول الميثين CH4 معنى ذلك عندي أربع روابط
+
+39
+00:03:21,770 --> 00:03:28,150
+متصلة بالكاربون عندي أربع روابط متصلةبالـ Carbon
+
+40
+00:03:28,150 --> 00:03:34,010
+هذي الأربع روابط اللي متصلة بالـ Carbon بلزمها أنه
+
+41
+00:03:34,010 --> 00:03:37,950
+يكون عندى أربع أقود Electrons لو أنا بتطلع التوزيع
+
+42
+00:03:37,950 --> 00:03:42,850
+الإلكتروني للـ Carbon One S Two، Two S Two، Two B
+
+43
+00:03:42,850 --> 00:03:46,490
+Two اللي أنا شايفه عبارة عن Two أقود Electrons
+
+44
+00:03:46,490 --> 00:03:53,260
+بناء على ذلك اقترحت فكرة أنه يصير promotionيصير
+
+45
+00:03:53,260 --> 00:03:56,780
+الـ ProMotion يطلع إلكترون من الـ S-Orbital يجي
+
+46
+00:03:56,780 --> 00:04:01,540
+على الـ B-Orbital التالت الفاضي صار عنده أربع أقود
+
+47
+00:04:01,540 --> 00:04:05,700
+إلكترون لما يتم عملية hybridization يداخلوا دول
+
+48
+00:04:05,700 --> 00:04:09,720
+يتم عملية تهجين اللي مع بعض بيصيروا الأربع
+
+49
+00:04:09,720 --> 00:04:16,880
+Orbitals equivalent في الطاقة هدول الأربع Orbitals
+
+50
+00:04:18,070 --> 00:04:22,850
+كل واحد مكوّن فيهم من جزء من S ومن الـ B التلاتة
+
+51
+00:04:22,850 --> 00:04:30,130
+ولذلك كل واحد فيهم يسمى SB3 SB3 SB3 SB3 Orbitals
+
+52
+00:04:30,130 --> 00:04:35,470
+كيف شكلوا الـ SB3 Orbitals؟ هو حقيقة عبارة عن لوب
+
+53
+00:04:35,470 --> 00:04:42,390
+كبير لوب كبير ومعه لوب صغير تانيموجود خليط من الـ
+
+54
+00:04:42,390 --> 00:04:46,890
+S و الـ B Orbitals هدولة بيكونوا الأربعة loops
+
+55
+00:04:46,890 --> 00:04:51,230
+اللي هم S B3 و S B3 و S B3 و S B3 hybrid orbitals
+
+56
+00:04:51,230 --> 00:04:56,150
+موجودين على رأس الـ tetrahedral structureوكل واحد
+
+57
+00:04:56,150 --> 00:04:59,190
+فيه odd electron يعني هنا في عندي odd electron هنا
+
+58
+00:04:59,190 --> 00:05:02,430
+odd electron هنا odd electron هنا odd electron لما
+
+59
+00:05:02,430 --> 00:05:06,350
+يجي يتفاعل مع الهيدروجين ال spherical orbital هذا
+
+60
+00:05:06,350 --> 00:05:08,990
+في odd electron هذا odd electron هذا odd electron
+
+61
+00:05:08,990 --> 00:05:13,970
+هذا odd electron بيعملوا عنده رابطة تنتين تلاتة
+
+62
+00:05:13,970 --> 00:05:18,750
+أربعة فصار عندي جزء الميثين carbon hydrogen
+
+63
+00:05:18,750 --> 00:05:23,230
+hydrogen hydrogen hydrogenلو قولنا ايش نوع الرابطة
+
+64
+00:05:23,230 --> 00:05:28,450
+في جزء الميثين الجواب الرابطة في جزء الميثين
+
+65
+00:05:28,450 --> 00:05:35,730
+امكونة من S orbital من الهيدروجين مع Sb3 orbital
+
+66
+00:05:35,730 --> 00:05:41,730
+من الكربون Sb3 hybrid orbital من الكربون مع S
+
+67
+00:05:41,730 --> 00:05:47,830
+orbital من الهيدروجين طبعاً هذا الشكل اللي هو شكل
+
+68
+00:05:47,830 --> 00:05:52,830
+الزواياالـ Tetrahedral Structure أو الميثين هو
+
+69
+00:05:52,830 --> 00:05:58,710
+الشكل اللي احنا بنشوفه هنا بالموديل عبارة عن ذرة
+
+70
+00:05:58,710 --> 00:06:05,970
+كربون بـ three dimensions طالع منها أربع روابط في
+
+71
+00:06:05,970 --> 00:06:10,130
+الأساس كانوا أربع orbitals وصاروا أربع روابط رابطة
+
+72
+00:06:10,130 --> 00:06:14,920
+مع الهيدروجين تنتين تلاتة أربعةالان كل زاوية من
+
+73
+00:06:14,920 --> 00:06:19,080
+هذه الزوايا .. كل زاوية من هذه الزوايا مية و تسعة
+
+74
+00:06:19,080 --> 00:06:21,780
+و نص يعني هذه زاوية مية و تسعة و نص، هذه مية و
+
+75
+00:06:21,780 --> 00:06:24,120
+تسعة و نص، هذه مية و تسعة و نص، هذه مية و تسعة و
+
+76
+00:06:24,120 --> 00:06:26,280
+نص، هذه مية و تسعة و نص، هذه مية و تسعة و نص، هذه
+
+77
+00:06:26,280 --> 00:06:27,160
+مية و تسعة و نص، هذه مية و تسعة و نص فالشكل هذا
+
+78
+00:06:27,160 --> 00:06:32,870
+متماثلبشكل عام هذا الـ tetrahedral structure أسهل
+
+79
+00:06:32,870 --> 00:06:38,150
+طريقة لتخيله إنه نبسكه بهذا الشكل نتخيل إنه احنا
+
+80
+00:06:38,150 --> 00:06:42,470
+أمام مستويين متعامدين هذه الهيدروجين و هذه
+
+81
+00:06:42,470 --> 00:06:47,350
+الهيدروجين نخليهم بمستوى أفقي هذول الهيدروجين
+
+82
+00:06:47,350 --> 00:06:52,870
+نخليهم بمستوى أفقي و الزاوية بينهم 109.5 عمودي على
+
+83
+00:06:52,870 --> 00:06:57,780
+هذا المستوى الأفقي عمودي عليه تماماًمستوى ثاني في
+
+84
+00:06:57,780 --> 00:07:01,760
+الـ Two Hydrogens و أيضًا الزاوية بينهم 1.9 و نص
+
+85
+00:07:01,760 --> 00:07:07,000
+إذًا إحنا بنقول أفضل طريقة للتعامل مع الـ
+
+86
+00:07:07,000 --> 00:07:11,500
+tetrahedral structure إن أتخيل الروابط موجودة في
+
+87
+00:07:11,500 --> 00:07:15,800
+مستويين متعمدين مستوى horizontal و مستوى
+
+88
+00:07:15,800 --> 00:07:20,650
+perpendicular عليه يعني عمودي عليهالزاوية هي 109.5
+
+89
+00:07:20,650 --> 00:07:25,470
+و 109.5 طبعا باقي الزاوية بتكون كلها 109.5 ولذلك
+
+90
+00:07:25,470 --> 00:07:30,270
+هذا الميثين يعتبر جزء عالي التماثل هذا الميثين
+
+91
+00:07:30,270 --> 00:07:37,750
+يعتبر جزء عالي التماثل الأن لو اطلعنا من جزء
+
+92
+00:07:37,750 --> 00:07:42,370
+الميثين إلى جزء أكبر شوية منه اللي هو فيه two
+
+93
+00:07:42,370 --> 00:07:47,990
+carbons اللي هو جزء ال إيثينعشان أعمل جزء الـ
+
+94
+00:07:47,990 --> 00:07:52,610
+Ethane باستفيد من كل الكلام السابق بفترض أنه الـ
+
+95
+00:07:52,610 --> 00:07:58,160
+Carbon عاملة SB3 Hybrid Orbitals، أربعةالان بين
+
+96
+00:07:58,160 --> 00:08:00,800
+الـ Carbon و الـ Carbon هذه الرابطة اللي احنا
+
+97
+00:08:00,800 --> 00:08:05,300
+بنقشر عليها بين الـ Carbon و الـ Carbon بتحد SB3
+
+98
+00:08:05,300 --> 00:08:10,040
+Hybrid Orbital من الـ Carbon الأولى مع SB3 Hybrid
+
+99
+00:08:10,040 --> 00:08:13,440
+Orbital من الـ Carbon التانية إذا كل واحدة من هدول
+
+100
+00:08:13,440 --> 00:08:18,220
+هذه SB3 وهذه SB3 بيعملوا الرابطة الأحدية اللي هي
+
+101
+00:08:18,220 --> 00:08:22,120
+بين الـ Carbon و الـ Carbonطيب باقي ال orbitals
+
+102
+00:08:22,120 --> 00:08:27,540
+كلهم بيعملوا روابط مع الهيدروجين فبصير جزاء الـ A2
+
+103
+00:08:27,540 --> 00:08:33,660
+عبارة عن CH3 CH3
+
+104
+00:08:34,790 --> 00:08:39,190
+زي ما بنلاحظ كل روابط وسبعة كل روابط بين الكاربون
+
+105
+00:08:39,190 --> 00:08:43,510
+والهيدروجين واحدة، اتنتين، تلاتة، اربعة، خمسة،
+
+106
+00:08:43,510 --> 00:08:50,350
+ستة، اتنتين،
+
+107
+00:08:50,350 --> 00:08:54,950
+تلاتة، اربعة، خمسة، ستة، اتنتين، تلاتة، خمسة، ستة،
+
+108
+00:08:54,950 --> 00:08:58,010
+اتنتين،
+
+109
+00:08:58,010 --> 00:09:02,270
+تلاتة، تلاتة، تلاتة
+
+110
+00:09:02,680 --> 00:09:07,700
+Sb3 hybrid orbital من الكربون التاني وزي ما انتوا
+
+111
+00:09:07,700 --> 00:09:11,300
+شايفين احنا بنقول the bond formed by end to end
+
+112
+00:09:11,300 --> 00:09:15,960
+overlap راس لراس او طرف لطرف is called a sigma
+
+113
+00:09:15,960 --> 00:09:24,400
+bondوهذا هو شكل جزء الـ E2 زي ما انتوا شايفينه،
+
+114
+00:09:24,400 --> 00:09:30,600
+عندي Carbon حاملة تلاتة Hydrogens، Carbon تانية
+
+115
+00:09:30,600 --> 00:09:34,220
+حاملة تلاتة Hydrogens، و بين الـ Carbon و الـ
+
+116
+00:09:34,220 --> 00:09:37,740
+Carbon عندي Single Bond، الآن لما بدي أكد على ال
+
+117
+00:09:37,740 --> 00:09:41,220
+Orbitals اللي مكونة منها روابط، هذه الرابطة اللي
+
+118
+00:09:41,220 --> 00:09:45,110
+بين ال Carbon و ال Carbon مكونة من إيش؟من Sb3
+
+119
+00:09:45,110 --> 00:09:49,050
+hybrid orbital مع Sb3 كل هدول الروابط امكونين من
+
+120
+00:09:49,050 --> 00:09:51,630
+Sb3 مع S Sb3 مع S و هكذا
+
+121
+00:09:56,240 --> 00:10:01,460
+طبعاً هذا الشكل بأكدلنا اللي هو جزء الـ Methane
+
+122
+00:10:01,460 --> 00:10:05,160
+اللي تاوم سيكناه وفرجناكوا إياه و اللي زاوية فيه
+
+123
+00:10:05,160 --> 00:10:10,540
+109.5 ويرسم بطرق مختلفة هذه أفضل طريقة نرسمه اللي
+
+124
+00:10:10,540 --> 00:10:14,860
+بنتخيل أنه في عندنا أفقياً ذارتين هيدروجين للأمام
+
+125
+00:10:14,860 --> 00:10:19,980
+في مستوى أفقي و عمودي عليهم ذارتين هيدروجين للخلف
+
+126
+00:10:20,070 --> 00:10:24,510
+في المستوى المتعمد عليهم وجميع الزوايا اللي موجودة
+
+127
+00:10:24,510 --> 00:10:28,350
+في هذا الـ tetrahedral structure هي حقيقة زوايا
+
+128
+00:10:28,350 --> 00:10:30,890
+109.5 درجة
+
+129
+00:10:33,100 --> 00:10:38,620
+الان بنقول طيب كيف ال bonding في جزاء ال إيثين ال
+
+130
+00:10:38,620 --> 00:10:43,240
+إيثيلين أو ال إيثين اسمه بال أيوبك إيثين هناخده
+
+131
+00:10:43,240 --> 00:10:48,880
+بالتفصيل و بال common name إيثيلين هذا الجزء عبارة
+
+132
+00:10:48,880 --> 00:10:53,840
+عن ذرتين كربون و أربع هيدروجينات بمعنى CH2 CH2
+
+133
+00:10:54,960 --> 00:10:59,280
+ولمّا شافوا الزوايا تبعته بالقياسات لاحظوا إن
+
+134
+00:10:59,280 --> 00:11:03,940
+الزاوية هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+135
+00:11:03,940 --> 00:11:04,900
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+136
+00:11:04,900 --> 00:11:04,920
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+137
+00:11:04,920 --> 00:11:05,020
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+138
+00:11:05,020 --> 00:11:05,040
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+139
+00:11:05,040 --> 00:11:05,060
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+140
+00:11:05,060 --> 00:11:05,100
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+141
+00:11:05,100 --> 00:11:05,440
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+142
+00:11:05,440 --> 00:11:08,480
+120، هد
+
+143
+00:11:16,160 --> 00:11:19,860
+الان زي ما بنلاحظ ان الكربون بشكل أساسي طالع من
+
+144
+00:11:19,860 --> 00:11:25,200
+التلت اتجاهات 1 2 3 بناء على ذلك الروابط الأساسية
+
+145
+00:11:25,200 --> 00:11:28,980
+اللي بتعملها الكربون تلاتة لما نيجي نشوف كيف هذا
+
+146
+00:11:28,980 --> 00:11:32,520
+الكلام بيصير نرجع للتوزيع الإلكتروني للكربون
+
+147
+00:11:32,520 --> 00:11:34,320
+1S22S22B
+
+148
+00:11:35,920 --> 00:11:40,980
+2 لو عملنا promotion طلعنا هدول التنين و حطينا
+
+149
+00:11:40,980 --> 00:11:46,700
+واحد هنا صار عنده SB2 SB2 SB2 و كمان واحد اسمه B
+
+150
+00:11:46,700 --> 00:11:50,040
+orbital لاحظوا انه احنا عملنا ال promotion في
+
+151
+00:11:50,040 --> 00:11:53,320
+الأول طلعنا ال electron صار أربع electronات لما
+
+152
+00:11:53,320 --> 00:11:56,800
+بدي أخلط أنا كام رابطة أساسية بدي واحدة تنتين
+
+153
+00:11:56,800 --> 00:12:01,340
+تلاتة عشان هيك بنخلط ال S مع اتنين من ال B هاي ال
+
+154
+00:12:01,340 --> 00:12:06,380
+S مع اتنين من ال B بيعطيني SB2 SB2 SB2و بيظل عند
+
+155
+00:12:06,380 --> 00:12:11,780
+بي أوربيتال لما بدي أتي أطلع عليهم هدولة كيف شكلهم
+
+156
+00:12:11,780 --> 00:12:18,320
+الروابط بيكون عند SB2 SB2 SB2 اللي مبينين باللون
+
+157
+00:12:18,320 --> 00:12:22,960
+الأخضر و الزاوية بينهم بين كل أخضر و التاني 120
+
+158
+00:12:22,960 --> 00:12:28,540
+درجة مئوية عمودي عليهم بيكون الـ B orbital عمودي
+
+159
+00:12:28,540 --> 00:12:31,960
+عليهم الـ B orbital الآن زي ما بتلاحظوا كل SB2
+
+160
+00:12:31,960 --> 00:12:37,250
+orbitalفي one electron و ال B orbital فيها one
+
+161
+00:12:37,250 --> 00:12:41,410
+electron طيب لو بدي أكون جزيه الاثلين بكونه من كام
+
+162
+00:12:41,410 --> 00:12:46,350
+carbon؟ تنتين يعني بدي هذه و كمان واحدة زي نحطهم
+
+163
+00:12:46,350 --> 00:12:52,240
+جنب بعضلاحظوا لما نحطهم جان بعض الرابطة الأساسية
+
+164
+00:12:52,240 --> 00:12:56,300
+اللي بين الـ Carbon والـ Carbon الـ End to End أو
+
+165
+00:12:56,300 --> 00:13:02,240
+Head to Head الـ Sigma Bond امكونة من إيش؟ من SB2
+
+166
+00:13:02,240 --> 00:13:06,700
+Hybrid Orbital مع SB2 Hybrid Orbital ضال عند اتنين
+
+167
+00:13:06,700 --> 00:13:12,180
+SB2 هدول هيتفاعلوا من خلال إيش؟مع الـ Hydrogen
+
+168
+00:13:12,180 --> 00:13:16,520
+هتكون الرابطة بين الكربون والهيدروجين في الإثالين
+
+169
+00:13:16,520 --> 00:13:24,200
+مكوّنة من أي Orbitals SB2 مع S SB2 مع S SB2 مع S
+
+170
+00:13:24,200 --> 00:13:25,540
+SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2
+
+171
+00:13:25,540 --> 00:13:26,200
+مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S
+
+172
+00:13:26,200 --> 00:13:28,120
+SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2
+
+173
+00:13:28,120 --> 00:13:29,780
+مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S
+
+174
+00:13:29,780 --> 00:13:31,240
+SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2
+
+175
+00:13:31,240 --> 00:13:31,340
+مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S
+
+176
+00:13:31,340 --> 00:13:31,420
+SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2
+
+177
+00:13:31,420 --> 00:13:40,280
+مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SBو B
+
+178
+00:13:40,280 --> 00:13:44,780
+orbital في one electron هدول الـ B orbital بيصير
+
+179
+00:13:44,780 --> 00:13:48,880
+overlapping بينهم تداخل من فوق و من تحت مستوى
+
+180
+00:13:48,880 --> 00:13:54,260
+الجزء بيعملوا الرابطة التانية اللي بنسميها by bond
+
+181
+00:13:54,260 --> 00:13:57,920
+هيوم انا اتداخل و من فوق و من تحت عملوا كثافة
+
+182
+00:13:57,920 --> 00:14:01,820
+إلكترونية فوق و كثافة إلكترونية تحت زي ما احنا
+
+183
+00:14:01,820 --> 00:14:06,750
+شايفين هنا بتكون اللي هي بنسميها الـ by bondالـ bi
+
+184
+00:14:06,750 --> 00:14:10,650
+-bond زي ما بتشوفه is one in which the electrons
+
+185
+00:14:10,650 --> 00:14:15,530
+in the B orbitals are held above هيهم موجودين،
+
+186
+00:14:15,530 --> 00:14:20,170
+فوق، above and below the plane of the molecule
+
+187
+00:14:20,170 --> 00:14:24,610
+يعني كأنه كل الجزء في مستوى واحد والإلكترونات
+
+188
+00:14:24,610 --> 00:14:29,930
+موجودة فوقهو تحته الجزء في مستوى واحد والإلكترونات
+
+189
+00:14:29,930 --> 00:14:33,350
+فوق و تحته طبعاً بدكوا تلاحظوا انه كام رابطة صار
+
+190
+00:14:33,350 --> 00:14:36,950
+عند تنتين الرابطة الأساسية بين ال carbon و ال
+
+191
+00:14:36,950 --> 00:14:43,790
+carbon ال single bond الأساسية هي اسمها sigma bond
+
+192
+00:14:43,790 --> 00:14:50,310
+وهذه الرابطة مكونة من SB2 مع SB2 الرابطة الثانية
+
+193
+00:14:50,310 --> 00:14:58,360
+هي اسمها ال bi bond ومكونة من الالـ Overlapping لـ
+
+194
+00:14:58,360 --> 00:15:03,160
+B مع B-Orbitals الـ B-Orbital مع الـ B-Orbital لو
+
+195
+00:15:03,160 --> 00:15:08,900
+بدنا نطلع على شكل هذا الشكل الحقيقة بوضّح عندنا
+
+196
+00:15:08,900 --> 00:15:13,500
+جزء الـ إثيلين زي ما بتلاحظوا، هذه عندي أنا الذرات
+
+197
+00:15:13,500 --> 00:15:17,400
+السمرة هذه الـ Carbons هذه هي الـ Carbons الـ
+
+198
+00:15:17,400 --> 00:15:21,800
+Carbon مع الـ Carbon عامل رابطة هذه الرابطة من أي
+
+199
+00:15:21,800 --> 00:15:28,310
+Orbitals Sb2 مع Sb2الان مع الـ hydrogen عامل رابطة
+
+200
+00:15:28,310 --> 00:15:31,910
+أثبت و ما أث و أثبت و ما أث و أثبت و ما أث و أثبت
+
+201
+00:15:31,910 --> 00:15:36,250
+و ما أث إذا بتلاحظوا الجزء من ناحية الذرات
+
+202
+00:15:36,250 --> 00:15:40,330
+hydrogen .. hydrogen .. carbon .. carbon ..
+
+203
+00:15:40,330 --> 00:15:44,550
+hydrogen .. hydrogen الجزء كله planner الجزء كله
+
+204
+00:15:44,550 --> 00:15:48,830
+في مستوى واحد طب هايش اللي متعمد عليه هنا بي
+
+205
+00:15:48,830 --> 00:15:54,080
+orbitalهنا و B orbital هنا هذا فيه إلكترون وهذا
+
+206
+00:15:54,080 --> 00:15:58,700
+فيه إلكترون الآن هنا بيصير overlapping أو تداخل
+
+207
+00:15:58,700 --> 00:16:02,020
+للإلكترونات من فوق ومن تحت بيعملولي الـ bi bond
+
+208
+00:16:02,020 --> 00:16:07,000
+فالإيثيلين بيصف بأكم bond ب two bonds double bond
+
+209
+00:16:07,000 --> 00:16:11,200
+واحدة منهم sigma جاية من أثبت وما أثبته والتانية
+
+210
+00:16:11,200 --> 00:16:15,800
+بي من تداخل الـ B orbital من فوق مستوى الجزء ومن
+
+211
+00:16:15,800 --> 00:16:18,640
+تحت مستوى الجزء، هذه الجزء، هذه المستوى تبع الجزء
+
+212
+00:16:19,300 --> 00:16:22,140
+الجزء زي ما احنا شايفينه الـ planar والـ B
+
+213
+00:16:22,140 --> 00:16:26,860
+-orbitals متعامدات عليه هذا هو الـ orbital view
+
+214
+00:16:26,860 --> 00:16:33,500
+لجزء الاثلين هذا هو ال orbital view لجزء الاثلين
+
+215
+00:16:33,500 --> 00:16:38,700
+الآن
+
+216
+00:16:39,770 --> 00:16:44,970
+لو بدنا ناخد جزء تالت اللي هو جزء الـ Acetylene
+
+217
+00:16:44,970 --> 00:16:51,090
+الـ Acetylene معروف هو الجزء اللي هو عبارة عن C2H2
+
+218
+00:16:51,090 --> 00:16:57,390
+دراسة هذا الجزء أثبتت أن هذا الجزء Linear يعني
+
+219
+00:16:57,390 --> 00:17:02,230
+ماخد الشكل الخطي والرابط بين الكربون والكربون
+
+220
+00:17:02,230 --> 00:17:07,410
+triple bond قصيرة الآن كيف بيصير ال orbitals
+
+221
+00:17:09,110 --> 00:17:13,590
+بتتكوّن و بتتحد في هذا الجزء نفس الشيء شكل الـ
+
+222
+00:17:13,590 --> 00:17:18,710
+Carbon 1 S2 to S2 to B2 بيصير عنده promotion الآن
+
+223
+00:17:18,710 --> 00:17:22,090
+هنا الـ Carbon كام رابطة أساسية عاملة؟ رابطة
+
+224
+00:17:22,090 --> 00:17:27,510
+والتانية الأساسية بناءً على ذلك، بيصير اتحاد أسمع
+
+225
+00:17:27,510 --> 00:17:33,420
+Bبيكوّن ليه؟ SB Orbital و SB Orbital، بيظل عندي 2B
+
+226
+00:17:33,420 --> 00:17:36,980
+Orbitals، خلّينا مثلا تجاوز نقول إن هما الـ 2BY و
+
+227
+00:17:36,980 --> 00:17:41,600
+2BZ و هدولة زي ما احنا عارفين متعامدات على بعض
+
+228
+00:17:42,570 --> 00:17:48,070
+لاحظوا هذا هو شكل الـOrbitals، هذا الأخضر هو الـSb
+
+229
+00:17:48,070 --> 00:17:52,370
+Orbital، وهذا Sb Orbital، وفي عندي B Orbital
+
+230
+00:17:52,370 --> 00:17:56,650
+عمودي، وفي B Orbital تاني عمودي عليه، يعني واحد
+
+231
+00:17:56,650 --> 00:18:02,370
+فوق وتحت والتانيللأمام و للخلف الان عندما أعمل
+
+232
+00:18:02,370 --> 00:18:06,170
+اتحاد كاربون تان من هذا الشكل هلاحظ ان الكاربون
+
+233
+00:18:06,170 --> 00:18:11,310
+الأولى هيجي SB Orbital منها يتحد مع الـ SB Orbital
+
+234
+00:18:11,310 --> 00:18:15,970
+تبع الكاربون التاني و يعمل sigma bond هذه الـ
+
+235
+00:18:15,970 --> 00:18:18,510
+sigma bond زي ما بنلاحظ بين الكاربون و الكاربون في
+
+236
+00:18:18,510 --> 00:18:23,530
+الـ acetylene من أي orbitals من SB مع SB الـ SB
+
+237
+00:18:23,530 --> 00:18:28,090
+Orbital التاني هيتحد مع الهيدروجينبنان ع ذلك هيصير
+
+238
+00:18:28,090 --> 00:18:33,630
+شكل الجزء هيدروجين كاربون كاربون هيدروجين لينيار
+
+239
+00:18:33,630 --> 00:18:37,530
+لاحظوا هذه الأربع نقاط السمر هيدروجين كاربون
+
+240
+00:18:37,530 --> 00:18:41,890
+كاربون هيدروجين لينيار ايش ضال عنده؟ ضال عند ال B
+
+241
+00:18:41,890 --> 00:18:49,560
+Orbitals فوقو تحت و أمام و خلف اللي فوق مع بعض
+
+242
+00:18:49,560 --> 00:18:53,440
+بيعملوا overlapping بيصير كثافة أو سحابة إلكترونية
+
+243
+00:18:53,440 --> 00:18:57,500
+فوق سحابة إلكترونية تحت سحابة إلكترونية في الخلف
+
+244
+00:18:57,500 --> 00:19:01,920
+سحابة إلكترونية في الأمام كأنه بيصير عنده
+
+245
+00:19:01,920 --> 00:19:06,220
+cylindrical electronic cloud يعني سحابة إلكترونية
+
+246
+00:19:06,220 --> 00:19:10,380
+استوانية فوق و تحت و قدام و ورا يعني كأنه الجزيء
+
+247
+00:19:10,750 --> 00:19:18,650
+بالمجمل محاط بـ سحابات إلكترونية لاحظوا هنا أن هذا
+
+248
+00:19:18,650 --> 00:19:23,650
+الجزء فيه تلت روابط لو أجينا نصنفهم لـ triple bond
+
+249
+00:19:23,650 --> 00:19:27,940
+عبارة عن إيش؟لو إجينا نشوف الـ triple bonds عبارة
+
+250
+00:19:27,940 --> 00:19:33,000
+عن إيش؟ عبارة عن واحدة منهم sigma bond جاية من Sb
+
+251
+00:19:33,000 --> 00:19:39,200
+مع Sb والتانية منهم عبارة عن bi bond جاية مثلا من
+
+252
+00:19:39,200 --> 00:19:44,160
+By مع By والتالتة برضه bi bond جاية مع By مع By لو
+
+253
+00:19:44,160 --> 00:19:50,070
+بدنا نشوف هذا الجزءبتفصيل ك Orbitals بنقول في
+
+254
+00:19:50,070 --> 00:19:55,090
+عندنا الـ Carbon عاملة رابطة مع الـ Carbon رابطة
+
+255
+00:19:55,090 --> 00:19:58,390
+أحدية الأولى هذه الـ Sigma Bond اللي إحنا شايفينها
+
+256
+00:19:58,390 --> 00:20:03,550
+هذه عبارة عن Sb مع Sb الـ Sb التاني عامل مع الـ
+
+257
+00:20:03,550 --> 00:20:06,250
+Hydrogen والـ Sb التاني عامل مع الـ Hydrogen لما
+
+258
+00:20:06,250 --> 00:20:11,110
+نشوف شكل الجزء الجزء Linear Hydrogen Carbon Carbon
+
+259
+00:20:11,110 --> 00:20:16,790
+Hydrogen Linear زاوية 180 درجة الآن في عند الـ By
+
+260
+00:20:18,170 --> 00:20:22,890
+عمودي فوق و تحت وهي الـ BY هدول لما ييجيوا يتحدوا
+
+261
+00:20:22,890 --> 00:20:25,650
+مع بعض بيعملوا صحابة إلكترونية فوق وصحابة
+
+262
+00:20:25,650 --> 00:20:31,850
+إلكترونية تحت عنده الـ BZ عمودي عليه لكن للأمام
+
+263
+00:20:31,850 --> 00:20:35,650
+هاي BZ وهاي BZ هدول بيعملوا صحابة إلكترونية من
+
+264
+00:20:35,650 --> 00:20:39,030
+قدام هدول بيعملوا صحابة إلكترونية من ورا بناء على
+
+265
+00:20:39,030 --> 00:20:44,610
+ذلك كأنه صار عندهسحابة إلكترونية من فوق و من تحت و
+
+266
+00:20:44,610 --> 00:20:50,150
+من قدام و من ورا يعني محوطة الـ Sigma bond هدولة
+
+267
+00:20:50,150 --> 00:20:52,950
+اللي من فوق و من تحت عبارة عن Bi bond و اللي من
+
+268
+00:20:52,950 --> 00:20:55,870
+الأمام و الخلف عبارة عن Bi bond إذا الـ Triple
+
+269
+00:20:55,870 --> 00:21:02,330
+bond حقيقة مكونة من Sigma bond زائد Two Bi bonds
+
+270
+00:21:02,330 --> 00:21:05,410
+واحدة اللي هي من فوق و من تحت و التالية اللي هي من
+
+271
+00:21:05,410 --> 00:21:12,860
+الأمام و من الخلف هذا هو شكل جزءالـ Acetylene من
+
+272
+00:21:12,860 --> 00:21:17,780
+ناحية الـ Orbitals وبهك تقريبًا بيكون غطينا الـ
+
+273
+00:21:17,780 --> 00:21:21,240
+Orbital View للجزيئات الأساسية في الـ Organ
+
+274
+00:21:21,240 --> 00:21:25,780
+الكميسترية اللي هم الـ Methane والإيثين والإيثين
+
+275
+00:21:25,780 --> 00:21:33,530
+أو الإيثيلين والإيثاين أو ال Acetyleneأخر حاجة في
+
+276
+00:21:33,530 --> 00:21:37,670
+هذا الفصل و احنا زي ما اتفقنا ان هذا فصل مقدمة
+
+277
+00:21:37,670 --> 00:21:42,810
+بجهزنا لدراسة الـ Organ Chemistry كيف احنا بدنا
+
+278
+00:21:42,810 --> 00:21:46,150
+ندرس الـ Organ Chemistry الـ Organ Chemistry
+
+279
+00:21:46,150 --> 00:21:51,150
+مركبات كتيرة بتزيد عن خمس مليون مركبلحظوا لما
+
+280
+00:21:51,150 --> 00:21:55,210
+بنحكي عن خمسة مليون مُركّب قصة كبيرة كيف أنا بدي
+
+281
+00:21:55,210 --> 00:21:59,870
+أدرس خمسة مليون مُركّب بصنفهم لعائلات بسميها
+
+282
+00:21:59,870 --> 00:22:04,350
+الـfunctional groups أو المجموعات الوظيفية هذه
+
+283
+00:22:04,350 --> 00:22:07,590
+الـfunctional groups مثلا المُركّبات اللي فيها
+
+284
+00:22:07,590 --> 00:22:10,710
+رابطة أحدية شايفينها باللون الأحمر بسميها الـCains
+
+285
+00:22:10,710 --> 00:22:16,420
+اللي فيها رابطة ثنائيةالـ Keynes اللي فيها رابطة
+
+286
+00:22:16,420 --> 00:22:22,380
+ثلاثية الـ Kynes اللي فيها حلقة مع روابط ثنائية
+
+287
+00:22:22,380 --> 00:22:27,380
+بقول عنها الـ Aromatic Compounds اللي فيها OH الـ
+
+288
+00:22:27,380 --> 00:22:32,080
+Alcohol اللي فيها SH الـ Thiols اللي فيها Oxygen
+
+289
+00:22:32,080 --> 00:22:38,040
+بين مجمعتين R بين كربنتين الـ Ethers اللي فيها
+
+290
+00:22:38,040 --> 00:22:43,220
+Sulphur بين كربنتين الـ Thioetherاللي فيها C
+
+291
+00:22:43,220 --> 00:22:46,780
+double bond O جنبها H الألديهيد، C double bond O
+
+292
+00:22:46,780 --> 00:22:50,700
+جنبها Carbons من الجهتين R groups الكيتون، C
+
+293
+00:22:50,700 --> 00:22:55,280
+double bond O جنبها OH الأسد، C double bond O
+
+294
+00:22:55,280 --> 00:22:59,700
+جنبها OR الأيستر، C double bond O جنبها Cl أو Br
+
+295
+00:22:59,700 --> 00:23:04,380
+الأسد هيلايد، جنبها NH2 الأمد، المركبات الكاربون
+
+296
+00:23:04,380 --> 00:23:08,200
+اللي حملة الـNH2 الأمين، اللي حملة الـCN نيترال
+
+297
+00:23:09,110 --> 00:23:12,530
+لاحظوا هذه هي العائلات الأساسية خلّينا نقول في الـ
+
+298
+00:23:12,530 --> 00:23:16,470
+Organ Chemistry إحنا في هذا المساق هندرس كل هذه
+
+299
+00:23:16,470 --> 00:23:21,670
+العائلات، يعني في الفصل الأول أخدنا مقدمة، بالفصل
+
+300
+00:23:21,670 --> 00:23:26,560
+التاني بناخد الـ Alkanesبالفصل التالت بناخد
+
+301
+00:23:26,560 --> 00:23:30,700
+الـAlkenes والـAlkynes، بالفصل الرابع بناخد
+
+302
+00:23:30,700 --> 00:23:34,200
+الـAromatic Compounds، بالفصل الخامس بناخد شوية
+
+303
+00:23:34,200 --> 00:23:38,340
+Stereochemistry، وبالسادس بندرس تفاعلات الإبدال،
+
+304
+00:23:38,340 --> 00:23:43,270
+في السابع بناخد الـAlcohols والـThiolsفي التامن
+
+305
+00:23:43,270 --> 00:23:46,930
+بناخد الـ ether والـ thioether في التاسع الالدهايد
+
+306
+00:23:46,930 --> 00:23:51,530
+والكيتون في العاشر الاسد ومشتقاته وفي شبطر 11 ال
+
+307
+00:23:51,530 --> 00:23:57,070
+amines هذا هو المفردات اللي بدنا ندرسها في هذا
+
+308
+00:23:57,070 --> 00:24:02,120
+المساق ب 11 فصل تمثل العائلات الأساسيةفي الـ
+
+309
+00:24:02,120 --> 00:24:05,460
+organic compounds كل عائلة أثناء دراستها بناخدها
+
+310
+00:24:05,460 --> 00:24:11,600
+بالتفصيل وبناخد خواصها وتحضيرها وتفاعلاتها وإن شاء
+
+311
+00:24:11,600 --> 00:24:13,560
+الله إلى محاضرة قادمة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..d4deb14c03213254ac1f3af90e6fb707ba47b257
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2854, "start": 8.92, "end": 28.54, "text": "بسم الله الرحمن الرحيم بنكمل اليوم في الفصل الأول اللي هو مقدمة للكيمياء العضوية كنا اتكلمنا طبعا عن التوزيع الإلكتروني وأنواع الروابط اليوم إن شاء الله نقطة البداية تبعتنا", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 44945, 24793, 1211, 45595, 20498, 8978, 27188, 36520, 16247, 12610, 13672, 1829, 31439, 3714, 28543, 46007, 5296, 23275, 32640, 1829, 16606, 18863, 11242, 2407, 10632, 9122, 8315, 1975, 2655, 4117, 19528, 8315, 23032, 3555, 3615, 995, 18871, 16712, 2407, 11622, 40228, 33688, 23275, 2655, 2288, 11536, 1829, 4032, 33456, 14407, 3615, 34892, 14407, 3555, 9566, 45595, 20498, 36145, 13412, 16606, 21984, 8717, 47432, 3660, 29739, 28259, 10632, 6055, 3555, 34268, 8315], "avg_logprob": -0.09529321281998246, "compression_ratio": 1.8372093023255813, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 8.92, "end": 10.12, "word": "بسم", "probability": 0.69287109375}, 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Electron", "probability": 0.860595703125}, {"start": 78.84, "end": 79.46, "word": " هذا", "probability": 0.86669921875}, {"start": 79.46, "end": 79.64, "word": " الـ", "probability": 0.802001953125}, {"start": 79.64, "end": 80.12, "word": " Electron", "probability": 0.855712890625}, {"start": 80.12, "end": 80.28, "word": " اللي", "probability": 0.87890625}, {"start": 80.28, "end": 80.42, "word": " في", "probability": 0.9833984375}, {"start": 80.42, "end": 81.04, "word": " الهيدروجين", "probability": 0.9881184895833334}, {"start": 81.04, "end": 81.46, "word": " موجود", "probability": 0.9778645833333334}, {"start": 81.46, "end": 81.64, "word": " بـ", "probability": 0.78271484375}, {"start": 81.64, "end": 81.84, "word": " S", "probability": 0.83154296875}, {"start": 81.84, "end": 82.58, "word": "-Orbital", "probability": 0.9073486328125}], "temperature": 1.0}, {"id": 4, "seek": 11083, "start": 83.21, "end": 110.83, "text": "والـ electron اللى فى الهيدروجين التانى بـ S orbital بناء على ذلك أنا لما بدأ أكون رابطة بده يجى يصير تداخل أو بنسميه overlap ما بين spherical S orbital و another spherical S orbital فبدهم يتحدوا two spherical S orbitals ويعطونا جزيء الهيدروجين ويعطونا جزيء الهيدروجين", "tokens": [2407, 6027, 39184, 6084, 13672, 7578, 6156, 7578, 2423, 3224, 25708, 2288, 29245, 9957, 16712, 7649, 7578, 4724, 39184, 318, 27677, 44945, 16606, 15844, 29910, 23275, 41850, 5296, 15042, 47525, 10721, 5551, 30544, 12602, 16758, 9566, 3660, 47525, 3224, 7251, 7435, 7578, 7251, 9381, 13546, 6055, 28259, 9778, 1211, 34051, 44945, 38251, 1829, 3224, 19959, 19446, 49374, 37300, 318, 27677, 4032, 1071, 37300, 318, 27677, 6156, 44510, 16095, 7251, 2655, 24401, 14407, 732, 37300, 318, 50015, 4032, 40228, 9566, 2407, 8315, 10874, 11622, 1829, 38207, 2423, 3224, 25708, 2288, 29245, 9957, 4032, 40228, 9566, 2407, 8315, 10874, 11622, 1829, 38207, 2423, 3224, 25708, 2288, 29245, 9957], "avg_logprob": -0.1712908939780476, "compression_ratio": 1.8883720930232557, "no_speech_prob": 0.0, 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0.8798828125}, {"start": 94.01, "end": 94.47, "word": " بين", "probability": 0.98046875}, {"start": 94.47, "end": 96.03, "word": " spherical", "probability": 0.79736328125}, {"start": 96.03, "end": 96.89, "word": " S", "probability": 0.95263671875}, {"start": 96.89, "end": 97.63, "word": " orbital", "probability": 0.8037109375}, {"start": 97.63, "end": 98.29, "word": " و", "probability": 0.97802734375}, {"start": 98.29, "end": 98.71, "word": " another", "probability": 0.86572265625}, {"start": 98.71, "end": 99.57, "word": " spherical", "probability": 0.95654296875}, {"start": 99.57, "end": 100.37, "word": " S", "probability": 0.98779296875}, {"start": 100.37, "end": 100.99, "word": " orbital", "probability": 0.904296875}, {"start": 100.99, "end": 101.89, "word": " فبدهم", "probability": 0.7477213541666666}, {"start": 101.89, "end": 102.69, "word": " يتحدوا", "probability": 0.970703125}, {"start": 102.69, "end": 103.01, "word": " two", "probability": 0.86474609375}, {"start": 103.01, "end": 103.59, "word": " spherical", "probability": 0.9453125}, {"start": 103.59, "end": 104.05, "word": " S", "probability": 0.96826171875}, {"start": 104.05, "end": 104.73, "word": " orbitals", "probability": 0.8486328125}, {"start": 104.73, "end": 105.97, "word": " ويعطونا", "probability": 0.877734375}, {"start": 105.97, "end": 106.97, "word": " جزيء", "probability": 0.8330078125}, {"start": 106.97, "end": 108.09, "word": " الهيدروجين", "probability": 0.97412109375}, {"start": 108.09, "end": 108.77, "word": " ويعطونا", "probability": 0.90576171875}, {"start": 108.77, "end": 109.43, "word": " جزيء", "probability": 0.9564208984375}, {"start": 109.43, "end": 110.83, "word": " الهيدروجين", "probability": 0.9729817708333334}], "temperature": 1.0}, {"id": 5, "seek": 13030, "start": 111.74, "end": 130.3, "text": "طيب لو فكرنا بدنا نعمل جزء الـ HF لاحظوا الـ H فيه one electron و هذا الـ electron برضه موجود في S orbital و الفلورين الـ odd electron اللي فيه لما نشوف توزيعه الإلكتروني موجود في 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S orbital و الـ B orbital لو إجيتنا جزء مثل الـ F2", "tokens": [5172, 1211, 2407, 1975, 2655, 30544, 2655, 34892, 16758, 9566, 3660, 19446, 49374, 2423, 39184, 389, 4032, 2423, 39184, 479, 8032, 2655, 30544, 19446, 49374, 318, 27677, 4386, 37300, 318, 27677, 20449, 2423, 39184, 363, 27677, 39627, 15730, 25124, 28820, 4724, 1829, 30544, 10874, 11622, 38207, 2423, 39184, 389, 37, 11933, 15730, 2423, 39184, 6086, 39896, 11331, 38436, 28671, 49374, 2423, 39184, 318, 27677, 4032, 2423, 39184, 363, 27677, 45164, 11933, 7435, 36081, 8315, 10874, 11622, 38207, 50113, 1211, 2423, 39184, 479, 17], "avg_logprob": -0.20926340013032868, "compression_ratio": 1.7065217391304348, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 131.07, "end": 131.83, "word": "فلو", "probability": 0.8497721354166666}, {"start": 131.83, "end": 132.69, "word": " اتكونت", "probability": 0.8468017578125}, {"start": 132.69, "end": 133.35, "word": " الرابطة", "probability": 0.8043212890625}, {"start": 133.35, 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"probability": 0.8740234375}, {"start": 148.21, "end": 148.91, "word": " orbital", "probability": 0.9169921875}, {"start": 148.91, "end": 149.99, "word": " لو", "probability": 0.90966796875}, {"start": 149.99, "end": 150.45, "word": " إجيتنا", "probability": 0.52728271484375}, {"start": 150.45, "end": 150.81, "word": " جزء", "probability": 0.9816080729166666}, {"start": 150.81, "end": 151.15, "word": " مثل", "probability": 0.988037109375}, {"start": 151.15, "end": 151.25, "word": " الـ", "probability": 0.783447265625}, {"start": 151.25, "end": 151.71, "word": " F2", "probability": 0.92431640625}], "temperature": 1.0}, {"id": 7, "seek": 17729, "start": 152.97, "end": 177.29, "text": "كل ذرة فلور فيها odd electron في B orbital هي B orbital لذرة هي B orbital لذرة لما بدهم يتفاعلوا هيعملوا sigma bond في كل الأحوال التلت روابط اللي موجودة عندى هنا sigma bonds head to head bonds وهيتكون عندى جزء لفلورين اللى هو مكوّن من B orbital متحدة مع B orbital", "tokens": [28820, 29910, 25720, 6156, 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0.98828125}, {"start": 813.1, "end": 813.18, "word": " مع", "probability": 0.84326171875}, {"start": 813.18, "end": 813.46, "word": " S", "probability": 0.91259765625}, {"start": 813.46, "end": 814.6, "word": " SB2", "probability": 0.98828125}, {"start": 814.6, "end": 814.6, "word": " مع", "probability": 0.8408203125}, {"start": 814.6, "end": 815.04, "word": " S", "probability": 0.9013671875}, {"start": 815.04, "end": 816.96, "word": " SB2", "probability": 0.988037109375}, {"start": 816.96, "end": 816.98, "word": " مع", "probability": 0.81982421875}, {"start": 816.98, "end": 817.72, "word": " S", "probability": 0.87890625}, {"start": 817.72, "end": 819.8, "word": " SB", "probability": 0.9765625}], "temperature": 1.0}, {"id": 37, "seek": 84550, "start": 819.84, "end": 845.5, "text": "و B orbital في one electron هدول الـ B orbital بيصير overlapping بينهم تداخل من فوق و من تحت مستوى الجزء بيعملوا الرابطة التانية اللي بنسميها by bond هيوم انا اتداخل و من فوق و من تحت عملوا كثافة إلكترونية فوق و كثافة إلكترونية تحت زي ما احنا شايفين هنا بتكون اللي هي بنسميها الـ by bond", "tokens": [2407, 363, 27677, 8978, 472, 6084, 8032, 3215, 12610, 2423, 39184, 363, 27677, 4724, 1829, 9381, 13546, 33535, 49374, 16095, 6055, 3215, 47283, 1211, 9154, 6156, 30543, 4032, 9154, 6055, 33753, 3714, 14851, 2407, 7578, 25724, 11622, 38207, 4724, 1829, 25957, 1211, 14407, 34892, 16758, 9566, 3660, 16712, 7649, 10632, 13672, 1829, 44945, 38251, 1829, 11296, 538, 6086, 39896, 20498, 1975, 8315, 1975, 2655, 3215, 47283, 1211, 4032, 9154, 6156, 30543, 4032, 9154, 6055, 33753, 6225, 42213, 14407, 9122, 12984, 31845, 3660, 11933, 23275, 2655, 2288, 11536, 10632, 6156, 30543, 4032, 9122, 12984, 31845, 3660, 11933, 23275, 2655, 2288, 11536, 10632, 6055, 33753, 30767, 1829, 19446, 1975, 5016, 8315, 13412, 995, 33911, 9957, 34105, 39894, 30544, 13672, 1829, 39896, 44945, 38251, 1829, 11296, 2423, 39184, 538, 6086], "avg_logprob": -0.140625006868504, "compression_ratio": 1.9024390243902438, 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"probability": 0.82861328125}, {"start": 825.68, "end": 826.3, "word": " بينهم", "probability": 0.9775390625}, {"start": 826.3, "end": 826.94, "word": " تداخل", "probability": 0.802734375}, {"start": 826.94, "end": 827.12, "word": " من", "probability": 0.994140625}, {"start": 827.12, "end": 827.54, "word": " فوق", "probability": 0.975341796875}, {"start": 827.54, "end": 827.7, "word": " و", "probability": 0.99072265625}, {"start": 827.7, "end": 827.82, "word": " من", "probability": 0.92333984375}, {"start": 827.82, "end": 828.22, "word": " تحت", "probability": 0.986083984375}, {"start": 828.22, "end": 828.88, "word": " مستوى", "probability": 0.9813232421875}, {"start": 828.88, "end": 829.52, "word": " الجزء", "probability": 0.711181640625}, {"start": 829.52, "end": 830.56, "word": " بيعملوا", "probability": 0.97900390625}, {"start": 830.56, "end": 831.26, "word": " الرابطة", "probability": 0.8511962890625}, {"start": 831.26, "end": 831.9, "word": " التانية", "probability": 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836.66, "word": " تحت", "probability": 0.994140625}, {"start": 836.66, "end": 837.4, "word": " عملوا", "probability": 0.9488932291666666}, {"start": 837.4, "end": 837.92, "word": " كثافة", "probability": 0.9949951171875}, {"start": 837.92, "end": 838.74, "word": " إلكترونية", "probability": 0.9009195963541666}, {"start": 838.74, "end": 839.24, "word": " فوق", "probability": 0.977783203125}, {"start": 839.24, "end": 839.48, "word": " و", "probability": 0.9873046875}, {"start": 839.48, "end": 839.96, "word": " كثافة", "probability": 0.97607421875}, {"start": 839.96, "end": 840.62, "word": " إلكترونية", "probability": 0.9917805989583334}, {"start": 840.62, "end": 840.98, "word": " تحت", "probability": 0.995849609375}, {"start": 840.98, "end": 841.56, "word": " زي", "probability": 0.95458984375}, {"start": 841.56, "end": 841.64, "word": " ما", "probability": 0.9462890625}, {"start": 841.64, "end": 841.82, "word": " احنا", "probability": 0.8557942708333334}, {"start": 841.82, "end": 842.28, "word": " شايفين", "probability": 0.9810791015625}, {"start": 842.28, "end": 842.52, "word": " هنا", "probability": 0.9130859375}, {"start": 842.52, "end": 843.0, "word": " بتكون", "probability": 0.9404296875}, {"start": 843.0, "end": 843.64, "word": " اللي", "probability": 0.978759765625}, {"start": 843.64, "end": 843.88, "word": " هي", "probability": 0.82177734375}, {"start": 843.88, "end": 844.54, "word": " بنسميها", "probability": 0.920654296875}, {"start": 844.54, "end": 844.72, "word": " الـ", "probability": 0.80712890625}, {"start": 844.72, "end": 845.08, "word": " by", "probability": 0.81103515625}, {"start": 845.08, "end": 845.5, "word": " bond", "probability": 0.91796875}], "temperature": 1.0}, {"id": 38, "seek": 86623, "start": 846.23, "end": 866.23, "text": "الـ bi-bond زي ما بتشوفه is one in which the electrons in the B orbitals are held above هيهم موجودين، فوق، above and below the plane of the molecule يعني كأنه كل الجزء في مستوى واحد والإلكترونات موجودة فوقه", "tokens": [6027, 39184, 3228, 12, 65, 684, 30767, 1829, 19446, 39894, 8592, 38688, 3224, 307, 472, 294, 597, 264, 14265, 294, 264, 363, 50015, 366, 5167, 3673, 8032, 1829, 16095, 3714, 29245, 23328, 9957, 12399, 6156, 30543, 12399, 3673, 293, 2507, 264, 5720, 295, 264, 15582, 37495, 22653, 9122, 33456, 3224, 28242, 25724, 11622, 38207, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 16070, 28814, 23275, 2655, 2288, 11536, 9307, 3714, 29245, 23328, 3660, 6156, 30543, 3224], "avg_logprob": -0.1798930970069609, "compression_ratio": 1.3476190476190477, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 846.23, "end": 846.59, "word": "الـ", "probability": 0.944091796875}, {"start": 846.59, "end": 846.75, "word": " bi", "probability": 0.2005615234375}, {"start": 846.75, "end": 846.95, "word": "-bond", "probability": 0.8362630208333334}, {"start": 846.95, "end": 847.19, "word": " زي", "probability": 0.89404296875}, {"start": 847.19, "end": 847.27, "word": " ما", "probability": 0.93701171875}, {"start": 847.27, "end": 847.95, "word": " بتشوفه", "probability": 0.896728515625}, {"start": 847.95, "end": 848.77, "word": " is", "probability": 0.304931640625}, {"start": 848.77, "end": 849.09, "word": " one", "probability": 0.9306640625}, {"start": 849.09, "end": 849.31, "word": " in", "probability": 0.94921875}, {"start": 849.31, "end": 849.59, "word": " which", "probability": 0.96630859375}, {"start": 849.59, "end": 849.87, "word": " the", "probability": 0.837890625}, {"start": 849.87, "end": 850.65, "word": " electrons", "probability": 0.810546875}, {"start": 850.65, "end": 851.03, "word": " in", "probability": 0.9541015625}, {"start": 851.03, "end": 851.23, "word": " the", "probability": 0.91845703125}, {"start": 851.23, "end": 851.39, "word": " B", "probability": 0.64990234375}, {"start": 851.39, "end": 852.13, "word": " orbitals", "probability": 0.53271484375}, {"start": 852.13, "end": 852.67, "word": " are", "probability": 0.92236328125}, {"start": 852.67, "end": 853.05, "word": " held", "probability": 0.921875}, {"start": 853.05, "end": 853.79, "word": " above", "probability": 0.9306640625}, {"start": 853.79, "end": 854.73, "word": " هيهم", "probability": 0.4888916015625}, {"start": 854.73, "end": 855.53, "word": " موجودين،", "probability": 0.85634765625}, {"start": 855.53, "end": 856.27, "word": " فوق،", "probability": 0.9288736979166666}, {"start": 856.27, "end": 856.69, "word": " above", "probability": 0.81005859375}, {"start": 856.69, "end": 857.37, "word": " and", "probability": 0.66259765625}, {"start": 857.37, "end": 857.93, "word": " below", "probability": 0.8994140625}, {"start": 857.93, "end": 858.75, "word": " the", "probability": 0.9140625}, {"start": 858.75, "end": 859.29, "word": " plane", "probability": 0.87890625}, {"start": 859.29, "end": 859.53, "word": " of", "probability": 0.9833984375}, {"start": 859.53, "end": 859.71, "word": " the", "probability": 0.90869140625}, {"start": 859.71, "end": 860.17, "word": " molecule", "probability": 0.86376953125}, {"start": 860.17, "end": 860.73, "word": " يعني", "probability": 0.934326171875}, {"start": 860.73, "end": 861.15, "word": " كأنه", "probability": 0.93603515625}, {"start": 861.15, "end": 861.37, "word": " كل", "probability": 0.97705078125}, {"start": 861.37, "end": 861.97, "word": " الجزء", "probability": 0.9474283854166666}, {"start": 861.97, "end": 862.17, "word": " في", "probability": 0.96533203125}, {"start": 862.17, "end": 862.69, "word": " مستوى", "probability": 0.9884033203125}, {"start": 862.69, "end": 863.23, "word": " واحد", "probability": 0.987548828125}, {"start": 863.23, "end": 864.61, "word": " والإلكترونات", "probability": 0.8077566964285714}, {"start": 864.61, "end": 865.37, "word": " موجودة", "probability": 0.98876953125}, {"start": 865.37, "end": 866.23, "word": " فوقه", "probability": 0.9720052083333334}], "temperature": 1.0}, {"id": 39, "seek": 89419, "start": 866.93, "end": 894.19, "text": "و تحته الجزء في مستوى واحد والإلكترونات فوق و تحته طبعاً بدكوا تلاحظوا انه كام رابطة صار عند تنتين الرابطة الأساسية بين ال carbon و ال carbon ال single bond الأساسية هي اسمها sigma bond وهذه الرابطة مكونة من SB2 مع SB2 الرابطة الثانية هي اسمها ال bi bond ومكونة من ال", "tokens": [2407, 6055, 33753, 3224, 25724, 11622, 38207, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 16070, 28814, 23275, 2655, 32887, 8315, 2655, 6156, 30543, 4032, 6055, 33753, 3224, 23032, 3555, 3615, 995, 14111, 47525, 4117, 14407, 6055, 15040, 5016, 19913, 14407, 16472, 3224, 9122, 10943, 12602, 16758, 9566, 3660, 20328, 9640, 43242, 6055, 29399, 9957, 34892, 16758, 9566, 3660, 16247, 3794, 32277, 10632, 49374, 2423, 5954, 4032, 2423, 5954, 2423, 2167, 6086, 16247, 3794, 32277, 10632, 39896, 24525, 2304, 11296, 12771, 6086, 37037, 24192, 34892, 16758, 9566, 3660, 3714, 30544, 3660, 9154, 26944, 17, 20449, 26944, 17, 34892, 16758, 9566, 3660, 6024, 104, 7649, 10632, 39896, 24525, 2304, 11296, 2423, 3228, 6086, 4032, 2304, 30544, 3660, 9154, 2423], 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"text": "لو بدنا ناخد جزء تالت اللي هو جزء الـ Acetylene الـ Acetylene معروف هو الجزء اللي هو عبارة عن C2H2 دراسة هذا الجزء أثبتت أن هذا الجزء Linear يعني ماخد الشكل الخطي والرابط بين الكربون والكربون triple bond قصيرة الآن كيف بيصير ال orbitals", "tokens": [1211, 2407, 47525, 8315, 8717, 47283, 3215, 10874, 11622, 38207, 6055, 6027, 2655, 13672, 1829, 31439, 10874, 11622, 38207, 2423, 39184, 5097, 2210, 21323, 2423, 39184, 5097, 2210, 21323, 20449, 32887, 5172, 31439, 25724, 11622, 38207, 13672, 1829, 31439, 6225, 3555, 9640, 3660, 18871, 383, 17, 39, 17, 11778, 23557, 3794, 3660, 23758, 25724, 11622, 38207, 5551, 12984, 3555, 2655, 2655, 14739, 23758, 25724, 11622, 38207, 14670, 289, 37495, 22653, 3714, 47283, 3215, 25124, 28820, 33962, 9566, 1829, 16070, 2288, 16758, 9566, 49374, 33251, 25513, 11536, 16070, 4117, 25513, 11536, 15508, 6086, 12174, 9381, 48923, 6024, 48506, 9122, 33911, 4724, 1829, 9381, 13546, 2423, 50015], "avg_logprob": -0.13384434271533535, "compression_ratio": 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" احنا", "probability": 0.8160807291666666}, {"start": 1059.78, "end": 1060.18, "word": " عارفين", "probability": 0.9853515625}, {"start": 1060.18, "end": 1060.98, "word": " متعامدات", "probability": 0.9630859375}, {"start": 1060.98, "end": 1061.18, "word": " على", "probability": 0.8583984375}, {"start": 1061.18, "end": 1061.6, "word": " بعض", "probability": 0.99560546875}], "temperature": 1.0}, {"id": 47, "seek": 107865, "start": 1062.57, "end": 1078.65, "text": "لاحظوا هذا هو شكل الـOrbitals، هذا الأخضر هو الـSb Orbital، وهذا Sb Orbital، وفي عندي B Orbital عمودي، وفي B Orbital تاني عمودي عليه، يعني واحد فوق وتحت والتاني", "tokens": [15040, 5016, 19913, 14407, 23758, 31439, 13412, 28820, 2423, 39184, 21520, 5260, 1124, 12399, 23758, 16247, 9778, 11242, 2288, 31439, 2423, 39184, 50, 65, 44329, 1686, 12399, 37037, 15730, 318, 65, 44329, 1686, 12399, 4032, 41185, 43242, 1829, 363, 44329, 1686, 6225, 2304, 2407, 16254, 12399, 4032, 41185, 363, 44329, 1686, 6055, 7649, 1829, 6225, 2304, 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0.9443359375}, {"start": 1144.34, "end": 1144.72, "word": " يعني", "probability": 0.8212890625}, {"start": 1144.72, "end": 1145.52, "word": " سحابة", "probability": 0.9947509765625}, {"start": 1145.52, "end": 1146.22, "word": " إلكترونية", "probability": 0.9925944010416666}, {"start": 1146.22, "end": 1146.94, "word": " استوانية", "probability": 0.82891845703125}, {"start": 1146.94, "end": 1147.4, "word": " فوق", "probability": 0.94287109375}, {"start": 1147.4, "end": 1147.56, "word": " و", "probability": 0.66064453125}, {"start": 1147.56, "end": 1147.86, "word": " تحت", "probability": 0.949462890625}, {"start": 1147.86, "end": 1148.0, "word": " و", "probability": 0.923828125}, {"start": 1148.0, "end": 1148.4, "word": " قدام", "probability": 0.8544921875}, {"start": 1148.4, "end": 1148.52, "word": " و", "probability": 0.998046875}, {"start": 1148.52, "end": 1148.78, "word": " ورا", "probability": 0.916259765625}, {"start": 1148.78, "end": 1149.34, "word": " يعني", "probability": 0.973388671875}, {"start": 1149.34, "end": 1149.74, "word": " كأنه", "probability": 0.9661458333333334}, {"start": 1149.74, "end": 1150.38, "word": " الجزيء", "probability": 0.7645263671875}], "temperature": 1.0}, {"id": 51, "seek": 116551, "start": 1150.75, "end": 1165.51, "text": "بالمجمل محاط بـ سحابات إلكترونية لاحظوا هنا أن هذا الجزء فيه تلت روابط لو أجينا نصنفهم لـ triple bond عبارة عن إيش؟", "tokens": [3555, 45340, 7435, 42213, 3714, 5016, 41193, 4724, 39184, 8608, 5016, 16758, 9307, 11933, 23275, 2655, 2288, 11536, 10632, 20193, 5016, 19913, 14407, 34105, 14739, 23758, 25724, 11622, 38207, 8978, 3224, 6055, 1211, 2655, 12602, 14407, 3555, 9566, 45164, 5551, 7435, 1829, 8315, 8717, 9381, 1863, 5172, 16095, 5296, 39184, 15508, 6086, 6225, 3555, 9640, 3660, 18871, 11933, 1829, 8592, 22807], "avg_logprob": -0.16343245727400627, "compression_ratio": 1.3092105263157894, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 1150.75, "end": 1151.71, "word": "بالمجمل", "probability": 0.93310546875}, {"start": 1151.71, "end": 1152.79, "word": " محاط", "probability": 0.9166666666666666}, {"start": 1152.79, "end": 1153.73, "word": " بـ", "probability": 0.756103515625}, {"start": 1153.73, "end": 1154.53, "word": " سحابات", "probability": 0.79681396484375}, {"start": 1154.53, "end": 1155.77, "word": " إلكترونية", "probability": 0.9091796875}, {"start": 1155.77, "end": 1156.71, "word": " لاحظوا", "probability": 0.84771728515625}, {"start": 1156.71, "end": 1157.03, "word": " هنا", "probability": 0.9912109375}, {"start": 1157.03, "end": 1157.95, "word": " أن", "probability": 0.422119140625}, {"start": 1157.95, "end": 1158.65, "word": " هذا", "probability": 0.890625}, {"start": 1158.65, "end": 1159.43, "word": " الجزء", "probability": 0.9163411458333334}, {"start": 1159.43, "end": 1160.41, "word": " فيه", "probability": 0.8876953125}, {"start": 1160.41, "end": 1160.67, "word": " تلت", "probability": 0.82861328125}, {"start": 1160.67, "end": 1161.33, "word": " روابط", "probability": 0.98193359375}, {"start": 1161.33, "end": 1161.67, "word": " لو", "probability": 0.72265625}, {"start": 1161.67, "end": 1162.05, "word": " أجينا", "probability": 0.8028564453125}, {"start": 1162.05, "end": 1162.73, "word": " نصنفهم", "probability": 0.9796875}, {"start": 1162.73, "end": 1163.01, "word": " لـ", "probability": 0.860595703125}, {"start": 1163.01, "end": 1163.19, "word": " triple", "probability": 0.2376708984375}, {"start": 1163.19, "end": 1163.65, "word": " bond", "probability": 0.86962890625}, {"start": 1163.65, "end": 1164.29, "word": " عبارة", "probability": 0.9833984375}, {"start": 1164.29, "end": 1164.65, "word": " عن", "probability": 0.994140625}, {"start": 1164.65, "end": 1165.51, "word": " إيش؟", "probability": 0.856201171875}], "temperature": 1.0}, {"id": 52, "seek": 118559, "start": 1165.76, "end": 1185.6, "text": "لو إجينا نشوف الـ triple bonds عبارة عن إيش؟ عبارة عن واحدة منهم sigma bond جاية من Sb مع Sb والتانية منهم عبارة عن bi bond جاية مثلا من By مع By والتالتة برضه bi bond جاية مع By مع By لو بدنا نشوف هذا الجزء", "tokens": [1211, 2407, 11933, 7435, 1829, 8315, 8717, 8592, 38688, 2423, 39184, 15508, 14713, 6225, 3555, 9640, 3660, 18871, 11933, 1829, 8592, 22807, 6225, 3555, 9640, 3660, 18871, 36764, 24401, 3660, 9154, 16095, 12771, 6086, 10874, 995, 10632, 9154, 318, 65, 20449, 318, 65, 16070, 2655, 7649, 10632, 9154, 16095, 6225, 3555, 9640, 3660, 18871, 3228, 6086, 10874, 995, 10632, 50113, 15040, 9154, 3146, 20449, 3146, 16070, 2655, 6027, 2655, 3660, 4724, 43042, 3224, 3228, 6086, 10874, 995, 10632, 20449, 3146, 20449, 3146, 45164, 47525, 8315, 8717, 8592, 38688, 23758, 25724, 11622, 38207], "avg_logprob": -0.1301243241115283, "compression_ratio": 1.8361581920903955, "no_speech_prob": 0.0, "words": [{"start": 1165.76, "end": 1165.98, "word": "لو", "probability": 0.877685546875}, {"start": 1165.98, "end": 1166.32, "word": " إجينا", "probability": 0.7120361328125}, {"start": 1166.32, "end": 1166.72, "word": " 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"probability": 0.85986328125}, {"start": 1171.6, "end": 1172.42, "word": " جاية", "probability": 0.9108072916666666}, {"start": 1172.42, "end": 1172.58, "word": " من", "probability": 0.9853515625}, {"start": 1172.58, "end": 1173.0, "word": " Sb", "probability": 0.4979248046875}, {"start": 1173.0, "end": 1173.18, "word": " مع", "probability": 0.990234375}, {"start": 1173.18, "end": 1173.8, "word": " Sb", "probability": 0.967041015625}, {"start": 1173.8, "end": 1174.86, "word": " والتانية", "probability": 0.938720703125}, {"start": 1174.86, "end": 1175.44, "word": " منهم", "probability": 0.9951171875}, {"start": 1175.44, "end": 1176.46, "word": " عبارة", "probability": 0.99853515625}, {"start": 1176.46, "end": 1176.94, "word": " عن", "probability": 0.98046875}, {"start": 1176.94, "end": 1177.74, "word": " bi", "probability": 0.3466796875}, {"start": 1177.74, "end": 1178.2, "word": " bond", "probability": 0.80712890625}, {"start": 1178.2, "end": 1178.7, "word": " جاية", "probability": 0.9762369791666666}, {"start": 1178.7, "end": 1179.06, "word": " مثلا", "probability": 0.98779296875}, {"start": 1179.06, "end": 1179.2, "word": " من", "probability": 0.72802734375}, {"start": 1179.2, "end": 1179.48, "word": " By", "probability": 0.75927734375}, {"start": 1179.48, "end": 1179.76, "word": " مع", "probability": 0.99462890625}, {"start": 1179.76, "end": 1180.18, "word": " By", "probability": 0.97509765625}, {"start": 1180.18, "end": 1181.18, "word": " والتالتة", "probability": 0.96064453125}, {"start": 1181.18, "end": 1181.54, "word": " برضه", "probability": 0.98828125}, {"start": 1181.54, "end": 1181.82, "word": " bi", "probability": 0.818359375}, {"start": 1181.82, "end": 1182.1, "word": " bond", "probability": 0.95654296875}, {"start": 1182.1, "end": 1182.4, "word": " جاية", "probability": 0.9881184895833334}, {"start": 1182.4, "end": 1182.54, "word": " مع", "probability": 0.505859375}, {"start": 1182.54, "end": 1182.84, "word": " By", "probability": 0.9658203125}, {"start": 1182.84, "end": 1183.08, "word": " مع", "probability": 0.99560546875}, {"start": 1183.08, "end": 1183.72, "word": " By", "probability": 0.94140625}, {"start": 1183.72, "end": 1184.16, "word": " لو", "probability": 0.900390625}, {"start": 1184.16, "end": 1184.4, "word": " بدنا", "probability": 0.81005859375}, {"start": 1184.4, "end": 1184.66, "word": " نشوف", "probability": 0.9967447916666666}, {"start": 1184.66, "end": 1184.88, "word": " هذا", "probability": 0.92724609375}, {"start": 1184.88, "end": 1185.6, "word": " الجزء", "probability": 0.8518880208333334}], "temperature": 1.0}, {"id": 53, "seek": 121679, "start": 1187.31, "end": 1216.79, "text": "بتفصيل ك Orbitals بنقول في عندنا الـ Carbon عاملة رابطة مع الـ Carbon رابطة أحدية الأولى هذه الـ Sigma Bond اللي إحنا شايفينها هذه عبارة عن Sb مع Sb الـ Sb التاني عامل مع الـ Hydrogen والـ Sb التاني عامل مع الـ Hydrogen لما نشوف شكل الجزء الجزء Linear Hydrogen Carbon Carbon Hydrogen Linear زاوية 180 درجة الآن في عند الـ By", 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thioether", "probability": 0.7535807291666666}, {"start": 1425.07, "end": 1425.61, "word": " في", "probability": 0.5966796875}, {"start": 1425.61, "end": 1426.19, "word": " التاسع", "probability": 0.99462890625}, {"start": 1426.19, "end": 1426.93, "word": " الالدهايد", "probability": 0.658642578125}, {"start": 1426.93, "end": 1427.71, "word": " والكيتون", "probability": 0.90283203125}, {"start": 1427.71, "end": 1427.87, "word": " في", "probability": 0.701171875}, {"start": 1427.87, "end": 1428.41, "word": " العاشر", "probability": 0.97705078125}, {"start": 1428.41, "end": 1429.01, "word": " الاسد", "probability": 0.8391927083333334}, {"start": 1429.01, "end": 1430.17, "word": " ومشتقاته", "probability": 0.9557059151785714}, {"start": 1430.17, "end": 1430.63, "word": " وفي", "probability": 0.878173828125}, {"start": 1430.63, "end": 1430.97, "word": " شبطر", "probability": 0.7755126953125}, {"start": 1430.97, "end": 1431.31, "word": " 11", "probability": 0.77587890625}, {"start": 1431.31, "end": 1431.53, "word": " ال", "probability": 0.88525390625}, {"start": 1431.53, "end": 1431.97, "word": " amines", "probability": 0.53582763671875}, {"start": 1431.97, "end": 1432.59, "word": " هذا", "probability": 0.81689453125}, {"start": 1432.59, "end": 1432.97, "word": " هو", "probability": 0.98193359375}, {"start": 1432.97, "end": 1435.47, "word": " المفردات", "probability": 0.9244140625}, {"start": 1435.47, "end": 1435.71, "word": " اللي", "probability": 0.907470703125}, {"start": 1435.71, "end": 1435.99, "word": " بدنا", "probability": 0.969482421875}, {"start": 1435.99, "end": 1436.61, "word": " ندرسها", "probability": 0.99453125}, {"start": 1436.61, "end": 1436.79, "word": " في", "probability": 0.97509765625}, {"start": 1436.79, "end": 1437.07, "word": " هذا", "probability": 0.97705078125}, {"start": 1437.07, "end": 1437.67, "word": " المساق", "probability": 0.9422607421875}, {"start": 1437.67, "end": 1437.79, "word": " ب", "probability": 0.87744140625}, {"start": 1437.79, "end": 1438.15, "word": " 11", "probability": 0.53125}, {"start": 1438.15, "end": 1438.69, "word": " فصل", "probability": 0.814697265625}, {"start": 1438.69, "end": 1439.81, "word": " تمثل", "probability": 0.9606119791666666}, {"start": 1439.81, "end": 1440.59, "word": " العائلات", "probability": 0.9898681640625}, {"start": 1440.59, "end": 1441.51, "word": " الأساسية", "probability": 0.9815673828125}], "temperature": 1.0}, {"id": 64, "seek": 145356, "start": 1441.66, "end": 1453.56, "text": "في الـ organic compounds كل عائلة أثناء دراستها بناخدها بالتفصيل وبناخد خواصها وتحضيرها وتفاعلاتها وإن شاء الله إلى محاضرة قادمة", "tokens": [41185, 2423, 39184, 10220, 21810, 28242, 6225, 16373, 37977, 5551, 12984, 1863, 16606, 11778, 23557, 14851, 11296, 44945, 47283, 3215, 11296, 20666, 2655, 5172, 9381, 26895, 46599, 1863, 47283, 3215, 16490, 2407, 33546, 11296, 34683, 5016, 11242, 13546, 11296, 34683, 5172, 995, 30241, 9307, 11296, 4032, 28814, 1863, 13412, 16606, 21984, 30731, 3714, 5016, 46958, 25720, 12174, 18513, 46007], "avg_logprob": -0.1245442713300387, "compression_ratio": 1.4166666666666667, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 1441.66, "end": 1441.96, "word": "في", "probability": 0.70947265625}, {"start": 1441.96, "end": 1442.12, "word": " الـ", "probability": 0.759521484375}, {"start": 1442.12, "end": 1442.48, "word": " organic", "probability": 0.36376953125}, {"start": 1442.48, "end": 1443.18, "word": " compounds", "probability": 0.91943359375}, {"start": 1443.18, "end": 1443.72, "word": " كل", "probability": 0.59375}, {"start": 1443.72, "end": 1444.1, "word": " عائلة", "probability": 0.9855143229166666}, {"start": 1444.1, "end": 1444.46, "word": " أثناء", "probability": 0.981689453125}, {"start": 1444.46, "end": 1444.98, "word": " دراستها", "probability": 0.9305419921875}, {"start": 1444.98, "end": 1445.46, "word": " بناخدها", "probability": 0.874267578125}, {"start": 1445.46, "end": 1446.2, "word": " بالتفصيل", "probability": 0.9703125}, {"start": 1446.2, "end": 1446.68, "word": " وبناخد", "probability": 0.79913330078125}, {"start": 1446.68, "end": 1447.54, "word": " خواصها", "probability": 0.9281005859375}, {"start": 1447.54, "end": 1448.92, "word": " وتحضيرها", "probability": 0.89951171875}, {"start": 1448.92, "end": 1450.44, "word": " وتفاعلاتها", "probability": 0.9151204427083334}, {"start": 1450.44, "end": 1451.36, "word": " وإن", "probability": 0.8689778645833334}, {"start": 1451.36, "end": 1451.6, "word": " شاء", "probability": 0.981689453125}, {"start": 1451.6, "end": 1451.76, "word": " الله", "probability": 0.96044921875}, {"start": 1451.76, "end": 1452.06, "word": " إلى", "probability": 0.90283203125}, {"start": 1452.06, "end": 1453.0, "word": " محاضرة", "probability": 0.9573974609375}, {"start": 1453.0, "end": 1453.56, "word": " قادمة", "probability": 0.99267578125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 1456.262625, "duration_after_vad": 1422.6453437499986}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..9ee5856ca1d692124855fba4c0c6f9e929375b61
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/MPjycepi0PQ_raw.srt
@@ -0,0 +1,1256 @@
+1
+00:00:08,920 --> 00:00:15,980
+بسم الله الرحمن الرحيم بنكمل اليوم في الفصل الأول
+
+2
+00:00:15,980 --> 00:00:21,980
+اللي هو مقدمة للكيمياء العضوية كنا اتكلمنا طبعا عن
+
+3
+00:00:21,980 --> 00:00:26,620
+التوزيع الإلكتروني وأنواع الروابط اليوم إن شاء
+
+4
+00:00:26,620 --> 00:00:32,250
+الله نقطة البداية تبعتناهي كيف تتكون الروابط من
+
+5
+00:00:32,250 --> 00:00:36,310
+خلال الـ Orbitals أو الموضوع اللي بنسميه احنا The
+
+6
+00:00:36,310 --> 00:00:41,350
+Orbital View of Bonding يعني كيف انا الـ Orbitals
+
+7
+00:00:41,350 --> 00:00:46,470
+نفسي اللي هي مواقع وجود الإلكترونات بتتحد مع بعضها
+
+8
+00:00:46,470 --> 00:00:51,470
+و بتعطينا الروابط طبعا احنا سبق اتعرفنا على الـ
+
+9
+00:00:51,470 --> 00:00:56,000
+Orbitals كان في عندنا الـ S-Orbitalوإذا بتذكروا
+
+10
+00:00:56,000 --> 00:01:00,860
+جميعًا إن الـ S-Orbital كان الشكل تبعه Spherical
+
+11
+00:01:00,860 --> 00:01:07,320
+والـ B-Orbitals كانت عادة تكون عبارة عن Two Loops
+
+12
+00:01:07,320 --> 00:01:12,760
+بناءً على ذلك لو مثلًا فكرنا نعمل رابطة لجزء
+
+13
+00:01:12,760 --> 00:01:16,100
+الهيدروجيني يعني اتحد عنده هيدروجين مع هيدروجين
+
+14
+00:01:16,100 --> 00:01:20,280
+الهيدروجين فيه One Electron هذا الـ Electron اللي
+
+15
+00:01:20,280 --> 00:01:24,490
+في الهيدروجين موجود بـ S-Orbitalوالـ electron اللى
+
+16
+00:01:24,490 --> 00:01:27,630
+فى الهيدروجين التانى بـ S orbital بناء على ذلك أنا
+
+17
+00:01:27,630 --> 00:01:32,390
+لما بدأ أكون رابطة بده يجى يصير تداخل أو بنسميه
+
+18
+00:01:32,390 --> 00:01:38,710
+overlap ما بين spherical S orbital و another
+
+19
+00:01:38,710 --> 00:01:44,050
+spherical S orbital فبدهم يتحدوا two spherical S
+
+20
+00:01:44,050 --> 00:01:49,430
+orbitals ويعطونا جزيء الهيدروجين ويعطونا جزيء
+
+21
+00:01:49,430 --> 00:01:57,140
+الهيدروجينطيب لو فكرنا بدنا نعمل جزء الـ HF لاحظوا
+
+22
+00:01:57,140 --> 00:02:01,620
+الـ H فيه one electron و هذا الـ electron برضه
+
+23
+00:02:01,620 --> 00:02:06,160
+موجود في S orbital و الفلورين الـ odd electron
+
+24
+00:02:06,160 --> 00:02:09,540
+اللي فيه لما نشوف توزيعه الإلكتروني موجود في B
+
+25
+00:02:09,540 --> 00:02:14,570
+orbitalفلو اتكونت الرابطة ما بين الـ H و الـ F
+
+26
+00:02:14,570 --> 00:02:19,130
+هتكون ما بين S orbital .. spherical S orbital مع
+
+27
+00:02:19,130 --> 00:02:24,590
+الـ B orbital بهذا الشكل بيكون جزء الـ HF إذا الـ
+
+28
+00:02:24,590 --> 00:02:29,990
+bond هي حقيقة بين الـ S orbital و الـ B orbital لو
+
+29
+00:02:29,990 --> 00:02:35,390
+إجيتنا جزء مثل الـ F2كل ذرة فلور فيها odd electron
+
+30
+00:02:35,390 --> 00:02:39,030
+في B orbital هي B orbital لذرة هي B orbital لذرة
+
+31
+00:02:39,030 --> 00:02:44,270
+لما بدهم يتفاعلوا هيعملوا sigma bond في كل الأحوال
+
+32
+00:02:44,270 --> 00:02:47,350
+التلت روابط اللي موجودة عندى هنا sigma bonds head
+
+33
+00:02:47,350 --> 00:02:52,710
+to head bonds وهيتكون عندى جزء لفلورين اللى هو
+
+34
+00:02:52,710 --> 00:02:57,290
+مكوّن من B orbital متحدة مع B orbital
+
+35
+00:02:59,970 --> 00:03:05,730
+الآن لو اجينا لأبسط جزء في الـ organic chemistry
+
+36
+00:03:05,730 --> 00:03:10,290
+اللي هو الميثين ومن بعده الـ إيثين وبدنا نشوف كيف
+
+37
+00:03:10,290 --> 00:03:16,370
+بيتكون جزء الميثين كلنا بنعرف إن جزء الميثين CH4
+
+38
+00:03:16,370 --> 00:03:21,770
+طيب لما نقول الميثين CH4 معنى ذلك عندي أربع روابط
+
+39
+00:03:21,770 --> 00:03:28,150
+متصلة بالكاربون عندي أربع روابط متصلةبالـ Carbon
+
+40
+00:03:28,150 --> 00:03:34,010
+هذي الأربع روابط اللي متصلة بالـ Carbon بلزمها أنه
+
+41
+00:03:34,010 --> 00:03:37,950
+يكون عندى أربع أقود Electrons لو أنا بتطلع التوزيع
+
+42
+00:03:37,950 --> 00:03:42,850
+الإلكتروني للـ Carbon One S Two، Two S Two، Two B
+
+43
+00:03:42,850 --> 00:03:46,490
+Two اللي أنا شايفه عبارة عن Two أقود Electrons
+
+44
+00:03:46,490 --> 00:03:53,260
+بناء على ذلك اقترحت فكرة أنه يصير promotionيصير
+
+45
+00:03:53,260 --> 00:03:56,780
+الـ ProMotion يطلع إلكترون من الـ S-Orbital يجي
+
+46
+00:03:56,780 --> 00:04:01,540
+على الـ B-Orbital التالت الفاضي صار عنده أربع أقود
+
+47
+00:04:01,540 --> 00:04:05,700
+إلكترون لما يتم عملية hybridization يداخلوا دول
+
+48
+00:04:05,700 --> 00:04:09,720
+يتم عملية تهجين اللي مع بعض بيصيروا الأربع
+
+49
+00:04:09,720 --> 00:04:16,880
+Orbitals equivalent في الطاقة هدول الأربع Orbitals
+
+50
+00:04:18,070 --> 00:04:22,850
+كل واحد مكوّن فيهم من جزء من S ومن الـ B التلاتة
+
+51
+00:04:22,850 --> 00:04:30,130
+ولذلك كل واحد فيهم يسمى SB3 SB3 SB3 SB3 Orbitals
+
+52
+00:04:30,130 --> 00:04:35,470
+كيف شكلوا الـ SB3 Orbitals؟ هو حقيقة عبارة عن لوب
+
+53
+00:04:35,470 --> 00:04:42,390
+كبير لوب كبير ومعه لوب صغير تانيموجود خليط من الـ
+
+54
+00:04:42,390 --> 00:04:46,890
+S و الـ B Orbitals هدولة بيكونوا الأربعة loops
+
+55
+00:04:46,890 --> 00:04:51,230
+اللي هم S B3 و S B3 و S B3 و S B3 hybrid orbitals
+
+56
+00:04:51,230 --> 00:04:56,150
+موجودين على رأس الـ tetrahedral structureوكل واحد
+
+57
+00:04:56,150 --> 00:04:59,190
+فيه odd electron يعني هنا في عندي odd electron هنا
+
+58
+00:04:59,190 --> 00:05:02,430
+odd electron هنا odd electron هنا odd electron لما
+
+59
+00:05:02,430 --> 00:05:06,350
+يجي يتفاعل مع الهيدروجين ال spherical orbital هذا
+
+60
+00:05:06,350 --> 00:05:08,990
+في odd electron هذا odd electron هذا odd electron
+
+61
+00:05:08,990 --> 00:05:13,970
+هذا odd electron بيعملوا عنده رابطة تنتين تلاتة
+
+62
+00:05:13,970 --> 00:05:18,750
+أربعة فصار عندي جزء الميثين carbon hydrogen
+
+63
+00:05:18,750 --> 00:05:23,230
+hydrogen hydrogen hydrogenلو قولنا ايش نوع الرابطة
+
+64
+00:05:23,230 --> 00:05:28,450
+في جزء الميثين الجواب الرابطة في جزء الميثين
+
+65
+00:05:28,450 --> 00:05:35,730
+امكونة من S orbital من الهيدروجين مع Sb3 orbital
+
+66
+00:05:35,730 --> 00:05:41,730
+من الكربون Sb3 hybrid orbital من الكربون مع S
+
+67
+00:05:41,730 --> 00:05:47,830
+orbital من الهيدروجين طبعاً هذا الشكل اللي هو شكل
+
+68
+00:05:47,830 --> 00:05:52,830
+الزواياالـ Tetrahedral Structure أو الميثين هو
+
+69
+00:05:52,830 --> 00:05:58,710
+الشكل اللي احنا بنشوفه هنا بالموديل عبارة عن ذرة
+
+70
+00:05:58,710 --> 00:06:05,970
+كربون بـ three dimensions طالع منها أربع روابط في
+
+71
+00:06:05,970 --> 00:06:10,130
+الأساس كانوا أربع orbitals وصاروا أربع روابط رابطة
+
+72
+00:06:10,130 --> 00:06:14,920
+مع الهيدروجين تنتين تلاتة أربعةالان كل زاوية من
+
+73
+00:06:14,920 --> 00:06:19,080
+هذه الزوايا .. كل زاوية من هذه الزوايا مية و تسعة
+
+74
+00:06:19,080 --> 00:06:21,780
+و نص يعني هذه زاوية مية و تسعة و نص، هذه مية و
+
+75
+00:06:21,780 --> 00:06:24,120
+تسعة و نص، هذه مية و تسعة و نص، هذه مية و تسعة و
+
+76
+00:06:24,120 --> 00:06:26,280
+نص، هذه مية و تسعة و نص، هذه مية و تسعة و نص، هذه
+
+77
+00:06:26,280 --> 00:06:27,160
+مية و تسعة و نص، هذه مية و تسعة و نص فالشكل هذا
+
+78
+00:06:27,160 --> 00:06:32,870
+متماثلبشكل عام هذا الـ tetrahedral structure أسهل
+
+79
+00:06:32,870 --> 00:06:38,150
+طريقة لتخيله إنه نبسكه بهذا الشكل نتخيل إنه احنا
+
+80
+00:06:38,150 --> 00:06:42,470
+أمام مستويين متعامدين هذه الهيدروجين و هذه
+
+81
+00:06:42,470 --> 00:06:47,350
+الهيدروجين نخليهم بمستوى أفقي هذول الهيدروجين
+
+82
+00:06:47,350 --> 00:06:52,870
+نخليهم بمستوى أفقي و الزاوية بينهم 109.5 عمودي على
+
+83
+00:06:52,870 --> 00:06:57,780
+هذا المستوى الأفقي عمودي عليه تماماًمستوى ثاني في
+
+84
+00:06:57,780 --> 00:07:01,760
+الـ Two Hydrogens و أيضًا الزاوية بينهم 1.9 و نص
+
+85
+00:07:01,760 --> 00:07:07,000
+إذًا إحنا بنقول أفضل طريقة للتعامل مع الـ
+
+86
+00:07:07,000 --> 00:07:11,500
+tetrahedral structure إن أتخيل الروابط موجودة في
+
+87
+00:07:11,500 --> 00:07:15,800
+مستويين متعمدين مستوى horizontal و مستوى
+
+88
+00:07:15,800 --> 00:07:20,650
+perpendicular عليه يعني عمودي عليهالزاوية هي 109.5
+
+89
+00:07:20,650 --> 00:07:25,470
+و 109.5 طبعا باقي الزاوية بتكون كلها 109.5 ولذلك
+
+90
+00:07:25,470 --> 00:07:30,270
+هذا الميثين يعتبر جزء عالي التماثل هذا الميثين
+
+91
+00:07:30,270 --> 00:07:37,750
+يعتبر جزء عالي التماثل الأن لو اطلعنا من جزء
+
+92
+00:07:37,750 --> 00:07:42,370
+الميثين إلى جزء أكبر شوية منه اللي هو فيه two
+
+93
+00:07:42,370 --> 00:07:47,990
+carbons اللي هو جزء ال إيثينعشان أعمل جزء الـ
+
+94
+00:07:47,990 --> 00:07:52,610
+Ethane باستفيد من كل الكلام السابق بفترض أنه الـ
+
+95
+00:07:52,610 --> 00:07:58,160
+Carbon عاملة SB3 Hybrid Orbitals، أربعةالان بين
+
+96
+00:07:58,160 --> 00:08:00,800
+الـ Carbon و الـ Carbon هذه الرابطة اللي احنا
+
+97
+00:08:00,800 --> 00:08:05,300
+بنقشر عليها بين الـ Carbon و الـ Carbon بتحد SB3
+
+98
+00:08:05,300 --> 00:08:10,040
+Hybrid Orbital من الـ Carbon الأولى مع SB3 Hybrid
+
+99
+00:08:10,040 --> 00:08:13,440
+Orbital من الـ Carbon التانية إذا كل واحدة من هدول
+
+100
+00:08:13,440 --> 00:08:18,220
+هذه SB3 وهذه SB3 بيعملوا الرابطة الأحدية اللي هي
+
+101
+00:08:18,220 --> 00:08:22,120
+بين الـ Carbon و الـ Carbonطيب باقي ال orbitals
+
+102
+00:08:22,120 --> 00:08:27,540
+كلهم بيعملوا روابط مع الهيدروجين فبصير جزاء الـ A2
+
+103
+00:08:27,540 --> 00:08:33,660
+عبارة عن CH3 CH3
+
+104
+00:08:34,790 --> 00:08:39,190
+زي ما بنلاحظ كل روابط وسبعة كل روابط بين الكاربون
+
+105
+00:08:39,190 --> 00:08:43,510
+والهيدروجين واحدة، اتنتين، تلاتة، اربعة، خمسة،
+
+106
+00:08:43,510 --> 00:08:50,350
+ستة، اتنتين،
+
+107
+00:08:50,350 --> 00:08:54,950
+تلاتة، اربعة، خمسة، ستة، اتنتين، تلاتة، خمسة، ستة،
+
+108
+00:08:54,950 --> 00:08:58,010
+اتنتين،
+
+109
+00:08:58,010 --> 00:08:58,010
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+110
+00:08:58,010 --> 00:08:58,010
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+111
+00:08:58,010 --> 00:08:58,010
+تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة، تلاتة،
+
+112
+00:08:58,010 --> 00:09:02,270
+تلاتة، تلاتة، تلاتة
+
+113
+00:09:02,680 --> 00:09:07,700
+Sb3 hybrid orbital من الكربون التاني وزي ما انتوا
+
+114
+00:09:07,700 --> 00:09:11,300
+شايفين احنا بنقول the bond formed by end to end
+
+115
+00:09:11,300 --> 00:09:15,960
+overlap راس لراس او طرف لطرف is called a sigma
+
+116
+00:09:15,960 --> 00:09:24,400
+bondوهذا هو شكل جزء الـ E2 زي ما انتوا شايفينه،
+
+117
+00:09:24,400 --> 00:09:30,600
+عندي Carbon حاملة تلاتة Hydrogens، Carbon تانية
+
+118
+00:09:30,600 --> 00:09:34,220
+حاملة تلاتة Hydrogens، و بين الـ Carbon و الـ
+
+119
+00:09:34,220 --> 00:09:37,740
+Carbon عندي Single Bond، الآن لما بدي أكد على ال
+
+120
+00:09:37,740 --> 00:09:41,220
+Orbitals اللي مكونة منها روابط، هذه الرابطة اللي
+
+121
+00:09:41,220 --> 00:09:45,110
+بين ال Carbon و ال Carbon مكونة من إيش؟من Sb3
+
+122
+00:09:45,110 --> 00:09:49,050
+hybrid orbital مع Sb3 كل هدول الروابط امكونين من
+
+123
+00:09:49,050 --> 00:09:51,630
+Sb3 مع S Sb3 مع S و هكذا
+
+124
+00:09:56,240 --> 00:10:01,460
+طبعاً هذا الشكل بأكدلنا اللي هو جزء الـ Methane
+
+125
+00:10:01,460 --> 00:10:05,160
+اللي تاوم سيكناه وفرجناكوا إياه و اللي زاوية فيه
+
+126
+00:10:05,160 --> 00:10:10,540
+109.5 ويرسم بطرق مختلفة هذه أفضل طريقة نرسمه اللي
+
+127
+00:10:10,540 --> 00:10:14,860
+بنتخيل أنه في عندنا أفقياً ذارتين هيدروجين للأمام
+
+128
+00:10:14,860 --> 00:10:19,980
+في مستوى أفقي و عمودي عليهم ذارتين هيدروجين للخلف
+
+129
+00:10:20,070 --> 00:10:24,510
+في المستوى المتعمد عليهم وجميع الزوايا اللي موجودة
+
+130
+00:10:24,510 --> 00:10:28,350
+في هذا الـ tetrahedral structure هي حقيقة زوايا
+
+131
+00:10:28,350 --> 00:10:30,890
+109.5 درجة
+
+132
+00:10:33,100 --> 00:10:38,620
+الان بنقول طيب كيف ال bonding في جزاء ال إيثين ال
+
+133
+00:10:38,620 --> 00:10:43,240
+إيثيلين أو ال إيثين اسمه بال أيوبك إيثين هناخده
+
+134
+00:10:43,240 --> 00:10:48,880
+بالتفصيل و بال common name إيثيلين هذا الجزء عبارة
+
+135
+00:10:48,880 --> 00:10:53,840
+عن ذرتين كربون و أربع هيدروجينات بمعنى CH2 CH2
+
+136
+00:10:54,960 --> 00:10:59,280
+ولمّا شافوا الزوايا تبعته بالقياسات لاحظوا إن
+
+137
+00:10:59,280 --> 00:11:03,940
+الزاوية هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+138
+00:11:03,940 --> 00:11:04,900
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+139
+00:11:04,900 --> 00:11:04,920
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+140
+00:11:04,920 --> 00:11:05,020
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+141
+00:11:05,020 --> 00:11:05,040
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+142
+00:11:05,040 --> 00:11:05,060
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+143
+00:11:05,060 --> 00:11:05,100
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+144
+00:11:05,100 --> 00:11:05,440
+120، هد 120، هد 120، هد 120، هد 120، هد 120، هد
+
+145
+00:11:05,440 --> 00:11:08,480
+120، هد
+
+146
+00:11:16,160 --> 00:11:19,860
+الان زي ما بنلاحظ ان الكربون بشكل أساسي طالع من
+
+147
+00:11:19,860 --> 00:11:25,200
+التلت اتجاهات 1 2 3 بناء على ذلك الروابط الأساسية
+
+148
+00:11:25,200 --> 00:11:28,980
+اللي بتعملها الكربون تلاتة لما نيجي نشوف كيف هذا
+
+149
+00:11:28,980 --> 00:11:32,520
+الكلام بيصير نرجع للتوزيع الإلكتروني للكربون
+
+150
+00:11:32,520 --> 00:11:34,320
+1S22S22B
+
+151
+00:11:35,920 --> 00:11:40,980
+2 لو عملنا promotion طلعنا هدول التنين و حطينا
+
+152
+00:11:40,980 --> 00:11:46,700
+واحد هنا صار عنده SB2 SB2 SB2 و كمان واحد اسمه B
+
+153
+00:11:46,700 --> 00:11:50,040
+orbital لاحظوا انه احنا عملنا ال promotion في
+
+154
+00:11:50,040 --> 00:11:53,320
+الأول طلعنا ال electron صار أربع electronات لما
+
+155
+00:11:53,320 --> 00:11:56,800
+بدي أخلط أنا كام رابطة أساسية بدي واحدة تنتين
+
+156
+00:11:56,800 --> 00:12:01,340
+تلاتة عشان هيك بنخلط ال S مع اتنين من ال B هاي ال
+
+157
+00:12:01,340 --> 00:12:06,380
+S مع اتنين من ال B بيعطيني SB2 SB2 SB2و بيظل عند
+
+158
+00:12:06,380 --> 00:12:11,780
+بي أوربيتال لما بدي أتي أطلع عليهم هدولة كيف شكلهم
+
+159
+00:12:11,780 --> 00:12:18,320
+الروابط بيكون عند SB2 SB2 SB2 اللي مبينين باللون
+
+160
+00:12:18,320 --> 00:12:22,960
+الأخضر و الزاوية بينهم بين كل أخضر و التاني 120
+
+161
+00:12:22,960 --> 00:12:28,540
+درجة مئوية عمودي عليهم بيكون الـ B orbital عمودي
+
+162
+00:12:28,540 --> 00:12:31,960
+عليهم الـ B orbital الآن زي ما بتلاحظوا كل SB2
+
+163
+00:12:31,960 --> 00:12:37,250
+orbitalفي one electron و ال B orbital فيها one
+
+164
+00:12:37,250 --> 00:12:41,410
+electron طيب لو بدي أكون جزيه الاثلين بكونه من كام
+
+165
+00:12:41,410 --> 00:12:46,350
+carbon؟ تنتين يعني بدي هذه و كمان واحدة زي نحطهم
+
+166
+00:12:46,350 --> 00:12:52,240
+جنب بعضلاحظوا لما نحطهم جان بعض الرابطة الأساسية
+
+167
+00:12:52,240 --> 00:12:56,300
+اللي بين الـ Carbon والـ Carbon الـ End to End أو
+
+168
+00:12:56,300 --> 00:13:02,240
+Head to Head الـ Sigma Bond امكونة من إيش؟ من SB2
+
+169
+00:13:02,240 --> 00:13:06,700
+Hybrid Orbital مع SB2 Hybrid Orbital ضال عند اتنين
+
+170
+00:13:06,700 --> 00:13:12,180
+SB2 هدول هيتفاعلوا من خلال إيش؟مع الـ Hydrogen
+
+171
+00:13:12,180 --> 00:13:16,520
+هتكون الرابطة بين الكربون والهيدروجين في الإثالين
+
+172
+00:13:16,520 --> 00:13:24,200
+مكوّنة من أي Orbitals SB2 مع S SB2 مع S SB2 مع S
+
+173
+00:13:24,200 --> 00:13:25,540
+SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2
+
+174
+00:13:25,540 --> 00:13:26,200
+مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S
+
+175
+00:13:26,200 --> 00:13:28,120
+SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2
+
+176
+00:13:28,120 --> 00:13:29,780
+مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S
+
+177
+00:13:29,780 --> 00:13:31,240
+SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2
+
+178
+00:13:31,240 --> 00:13:31,340
+مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S
+
+179
+00:13:31,340 --> 00:13:31,420
+SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SB2
+
+180
+00:13:31,420 --> 00:13:40,280
+مع S SB2 مع S SB2 مع S SB2 مع S SB2 مع S SBو B
+
+181
+00:13:40,280 --> 00:13:44,780
+orbital في one electron هدول الـ B orbital بيصير
+
+182
+00:13:44,780 --> 00:13:48,880
+overlapping بينهم تداخل من فوق و من تحت مستوى
+
+183
+00:13:48,880 --> 00:13:54,260
+الجزء بيعملوا الرابطة التانية اللي بنسميها by bond
+
+184
+00:13:54,260 --> 00:13:57,920
+هيوم انا اتداخل و من فوق و من تحت عملوا كثافة
+
+185
+00:13:57,920 --> 00:14:01,820
+إلكترونية فوق و كثافة إلكترونية تحت زي ما احنا
+
+186
+00:14:01,820 --> 00:14:06,750
+شايفين هنا بتكون اللي هي بنسميها الـ by bondالـ bi
+
+187
+00:14:06,750 --> 00:14:10,650
+-bond زي ما بتشوفه is one in which the electrons
+
+188
+00:14:10,650 --> 00:14:15,530
+in the B orbitals are held above هيهم موجودين،
+
+189
+00:14:15,530 --> 00:14:20,170
+فوق، above and below the plane of the molecule
+
+190
+00:14:20,170 --> 00:14:24,610
+يعني كأنه كل الجزء في مستوى واحد والإلكترونات
+
+191
+00:14:24,610 --> 00:14:29,930
+موجودة فوقهو تحته الجزء في مستوى واحد والإلكترونات
+
+192
+00:14:29,930 --> 00:14:33,350
+فوق و تحته طبعاً بدكوا تلاحظوا انه كام رابطة صار
+
+193
+00:14:33,350 --> 00:14:36,950
+عند تنتين الرابطة الأساسية بين ال carbon و ال
+
+194
+00:14:36,950 --> 00:14:43,790
+carbon ال single bond الأساسية هي اسمها sigma bond
+
+195
+00:14:43,790 --> 00:14:50,310
+وهذه الرابطة مكونة من SB2 مع SB2 الرابطة الثانية
+
+196
+00:14:50,310 --> 00:14:58,360
+هي اسمها ال bi bond ومكونة من الالـ Overlapping لـ
+
+197
+00:14:58,360 --> 00:15:03,160
+B مع B-Orbitals الـ B-Orbital مع الـ B-Orbital لو
+
+198
+00:15:03,160 --> 00:15:08,900
+بدنا نطلع على شكل هذا الشكل الحقيقة بوضّح عندنا
+
+199
+00:15:08,900 --> 00:15:13,500
+جزء الـ إثيلين زي ما بتلاحظوا، هذه عندي أنا الذرات
+
+200
+00:15:13,500 --> 00:15:17,400
+السمرة هذه الـ Carbons هذه هي الـ Carbons الـ
+
+201
+00:15:17,400 --> 00:15:21,800
+Carbon مع الـ Carbon عامل رابطة هذه الرابطة من أي
+
+202
+00:15:21,800 --> 00:15:28,310
+Orbitals Sb2 مع Sb2الان مع الـ hydrogen عامل رابطة
+
+203
+00:15:28,310 --> 00:15:31,910
+أثبت و ما أث و أثبت و ما أث و أثبت و ما أث و أثبت
+
+204
+00:15:31,910 --> 00:15:36,250
+و ما أث إذا بتلاحظوا الجزء من ناحية الذرات
+
+205
+00:15:36,250 --> 00:15:40,330
+hydrogen .. hydrogen .. carbon .. carbon ..
+
+206
+00:15:40,330 --> 00:15:44,550
+hydrogen .. hydrogen الجزء كله planner الجزء كله
+
+207
+00:15:44,550 --> 00:15:48,830
+في مستوى واحد طب هايش اللي متعمد عليه هنا بي
+
+208
+00:15:48,830 --> 00:15:54,080
+orbitalهنا و B orbital هنا هذا فيه إلكترون وهذا
+
+209
+00:15:54,080 --> 00:15:58,700
+فيه إلكترون الآن هنا بيصير overlapping أو تداخل
+
+210
+00:15:58,700 --> 00:16:02,020
+للإلكترونات من فوق ومن تحت بيعملولي الـ bi bond
+
+211
+00:16:02,020 --> 00:16:07,000
+فالإيثيلين بيصف بأكم bond ب two bonds double bond
+
+212
+00:16:07,000 --> 00:16:11,200
+واحدة منهم sigma جاية من أثبت وما أثبته والتانية
+
+213
+00:16:11,200 --> 00:16:15,800
+بي من تداخل الـ B orbital من فوق مستوى الجزء ومن
+
+214
+00:16:15,800 --> 00:16:18,640
+تحت مستوى الجزء، هذه الجزء، هذه المستوى تبع الجزء
+
+215
+00:16:19,300 --> 00:16:22,140
+الجزء زي ما احنا شايفينه الـ planar والـ B
+
+216
+00:16:22,140 --> 00:16:26,860
+-orbitals متعامدات عليه هذا هو الـ orbital view
+
+217
+00:16:26,860 --> 00:16:33,500
+لجزء الاثلين هذا هو ال orbital view لجزء الاثلين
+
+218
+00:16:33,500 --> 00:16:38,700
+الآن
+
+219
+00:16:39,770 --> 00:16:44,970
+لو بدنا ناخد جزء تالت اللي هو جزء الـ Acetylene
+
+220
+00:16:44,970 --> 00:16:51,090
+الـ Acetylene معروف هو الجزء اللي هو عبارة عن C2H2
+
+221
+00:16:51,090 --> 00:16:57,390
+دراسة هذا الجزء أثبتت أن هذا الجزء Linear يعني
+
+222
+00:16:57,390 --> 00:17:02,230
+ماخد الشكل الخطي والرابط بين الكربون والكربون
+
+223
+00:17:02,230 --> 00:17:07,410
+triple bond قصيرة الآن كيف بيصير ال orbitals
+
+224
+00:17:09,110 --> 00:17:13,590
+بتتكوّن و بتتحد في هذا الجزء نفس الشيء شكل الـ
+
+225
+00:17:13,590 --> 00:17:18,710
+Carbon 1 S2 to S2 to B2 بيصير عنده promotion الآن
+
+226
+00:17:18,710 --> 00:17:22,090
+هنا الـ Carbon كام رابطة أساسية عاملة؟ رابطة
+
+227
+00:17:22,090 --> 00:17:27,510
+والتانية الأساسية بناءً على ذلك، بيصير اتحاد أسمع
+
+228
+00:17:27,510 --> 00:17:33,420
+Bبيكوّن ليه؟ SB Orbital و SB Orbital، بيظل عندي 2B
+
+229
+00:17:33,420 --> 00:17:36,980
+Orbitals، خلّينا مثلا تجاوز نقول إن هما الـ 2BY و
+
+230
+00:17:36,980 --> 00:17:41,600
+2BZ و هدولة زي ما احنا عارفين متعامدات على بعض
+
+231
+00:17:42,570 --> 00:17:48,070
+لاحظوا هذا هو شكل الـOrbitals، هذا الأخضر هو الـSb
+
+232
+00:17:48,070 --> 00:17:52,370
+Orbital، وهذا Sb Orbital، وفي عندي B Orbital
+
+233
+00:17:52,370 --> 00:17:56,650
+عمودي، وفي B Orbital تاني عمودي عليه، يعني واحد
+
+234
+00:17:56,650 --> 00:18:02,370
+فوق وتحت والتانيللأمام و للخلف الان عندما أعمل
+
+235
+00:18:02,370 --> 00:18:06,170
+اتحاد كاربون تان من هذا الشكل هلاحظ ان الكاربون
+
+236
+00:18:06,170 --> 00:18:11,310
+الأولى هيجي SB Orbital منها يتحد مع الـ SB Orbital
+
+237
+00:18:11,310 --> 00:18:15,970
+تبع الكاربون التاني و يعمل sigma bond هذه الـ
+
+238
+00:18:15,970 --> 00:18:18,510
+sigma bond زي ما بنلاحظ بين الكاربون و الكاربون في
+
+239
+00:18:18,510 --> 00:18:23,530
+الـ acetylene من أي orbitals من SB مع SB الـ SB
+
+240
+00:18:23,530 --> 00:18:28,090
+Orbital التاني هيتحد مع الهيدروجينبنان ع ذلك هيصير
+
+241
+00:18:28,090 --> 00:18:33,630
+شكل الجزء هيدروجين كاربون كاربون هيدروجين لينيار
+
+242
+00:18:33,630 --> 00:18:37,530
+لاحظوا هذه الأربع نقاط السمر هيدروجين كاربون
+
+243
+00:18:37,530 --> 00:18:41,890
+كاربون هيدروجين لينيار ايش ضال عنده؟ ضال عند ال B
+
+244
+00:18:41,890 --> 00:18:49,560
+Orbitals فوقو تحت و أمام و خلف اللي فوق مع بعض
+
+245
+00:18:49,560 --> 00:18:53,440
+بيعملوا overlapping بيصير كثافة أو سحابة إلكترونية
+
+246
+00:18:53,440 --> 00:18:57,500
+فوق سحابة إلكترونية تحت سحابة إلكترونية في الخلف
+
+247
+00:18:57,500 --> 00:19:01,920
+سحابة إلكترونية في الأمام كأنه بيصير عنده
+
+248
+00:19:01,920 --> 00:19:06,220
+cylindrical electronic cloud يعني سحابة إلكترونية
+
+249
+00:19:06,220 --> 00:19:10,380
+استوانية فوق و تحت و قدام و ورا يعني كأنه الجزيء
+
+250
+00:19:10,750 --> 00:19:18,650
+بالمجمل محاط بـ سحابات إلكترونية لاحظوا هنا أن هذا
+
+251
+00:19:18,650 --> 00:19:23,650
+الجزء فيه تلت روابط لو أجينا نصنفهم لـ triple bond
+
+252
+00:19:23,650 --> 00:19:27,940
+عبارة عن إيش؟لو إجينا نشوف الـ triple bonds عبارة
+
+253
+00:19:27,940 --> 00:19:33,000
+عن إيش؟ عبارة عن واحدة منهم sigma bond جاية من Sb
+
+254
+00:19:33,000 --> 00:19:39,200
+مع Sb والتانية منهم عبارة عن bi bond جاية مثلا من
+
+255
+00:19:39,200 --> 00:19:44,160
+By مع By والتالتة برضه bi bond جاية مع By مع By لو
+
+256
+00:19:44,160 --> 00:19:50,070
+بدنا نشوف هذا الجزءبتفصيل ك Orbitals بنقول في
+
+257
+00:19:50,070 --> 00:19:55,090
+عندنا الـ Carbon عاملة رابطة مع الـ Carbon رابطة
+
+258
+00:19:55,090 --> 00:19:58,390
+أحدية الأولى هذه الـ Sigma Bond اللي إحنا شايفينها
+
+259
+00:19:58,390 --> 00:20:03,550
+هذه عبارة عن Sb مع Sb الـ Sb التاني عامل مع الـ
+
+260
+00:20:03,550 --> 00:20:06,250
+Hydrogen والـ Sb التاني عامل مع الـ Hydrogen لما
+
+261
+00:20:06,250 --> 00:20:11,110
+نشوف شكل الجزء الجزء Linear Hydrogen Carbon Carbon
+
+262
+00:20:11,110 --> 00:20:16,790
+Hydrogen Linear زاوية 180 درجة الآن في عند الـ By
+
+263
+00:20:18,170 --> 00:20:22,890
+عمودي فوق و تحت وهي الـ BY هدول لما ييجيوا يتحدوا
+
+264
+00:20:22,890 --> 00:20:25,650
+مع بعض بيعملوا صحابة إلكترونية فوق وصحابة
+
+265
+00:20:25,650 --> 00:20:31,850
+إلكترونية تحت عنده الـ BZ عمودي عليه لكن للأمام
+
+266
+00:20:31,850 --> 00:20:35,650
+هاي BZ وهاي BZ هدول بيعملوا صحابة إلكترونية من
+
+267
+00:20:35,650 --> 00:20:39,030
+قدام هدول بيعملوا صحابة إلكترونية من ورا بناء على
+
+268
+00:20:39,030 --> 00:20:44,610
+ذلك كأنه صار عندهسحابة إلكترونية من فوق و من تحت و
+
+269
+00:20:44,610 --> 00:20:50,150
+من قدام و من ورا يعني محوطة الـ Sigma bond هدولة
+
+270
+00:20:50,150 --> 00:20:52,950
+اللي من فوق و من تحت عبارة عن Bi bond و اللي من
+
+271
+00:20:52,950 --> 00:20:55,870
+الأمام و الخلف عبارة عن Bi bond إذا الـ Triple
+
+272
+00:20:55,870 --> 00:21:02,330
+bond حقيقة مكونة من Sigma bond زائد Two Bi bonds
+
+273
+00:21:02,330 --> 00:21:05,410
+واحدة اللي هي من فوق و من تحت و التالية اللي هي من
+
+274
+00:21:05,410 --> 00:21:12,860
+الأمام و من الخلف هذا هو شكل جزءالـ Acetylene من
+
+275
+00:21:12,860 --> 00:21:17,780
+ناحية الـ Orbitals وبهك تقريبًا بيكون غطينا الـ
+
+276
+00:21:17,780 --> 00:21:21,240
+Orbital View للجزيئات الأساسية في الـ Organ
+
+277
+00:21:21,240 --> 00:21:25,780
+الكميسترية اللي هم الـ Methane والإيثين والإيثين
+
+278
+00:21:25,780 --> 00:21:33,530
+أو الإيثيلين والإيثاين أو ال Acetyleneأخر حاجة في
+
+279
+00:21:33,530 --> 00:21:37,670
+هذا الفصل و احنا زي ما اتفقنا ان هذا فصل مقدمة
+
+280
+00:21:37,670 --> 00:21:42,810
+بجهزنا لدراسة الـ Organ Chemistry كيف احنا بدنا
+
+281
+00:21:42,810 --> 00:21:46,150
+ندرس الـ Organ Chemistry الـ Organ Chemistry
+
+282
+00:21:46,150 --> 00:21:51,150
+مركبات كتيرة بتزيد عن خمس مليون مركبلحظوا لما
+
+283
+00:21:51,150 --> 00:21:55,210
+بنحكي عن خمسة مليون مُركّب قصة كبيرة كيف أنا بدي
+
+284
+00:21:55,210 --> 00:21:59,870
+أدرس خمسة مليون مُركّب بصنفهم لعائلات بسميها
+
+285
+00:21:59,870 --> 00:22:04,350
+الـfunctional groups أو المجموعات الوظيفية هذه
+
+286
+00:22:04,350 --> 00:22:07,590
+الـfunctional groups مثلا المُركّبات اللي فيها
+
+287
+00:22:07,590 --> 00:22:10,710
+رابطة أحدية شايفينها باللون الأحمر بسميها الـCains
+
+288
+00:22:10,710 --> 00:22:16,420
+اللي فيها رابطة ثنائيةالـ Keynes اللي فيها رابطة
+
+289
+00:22:16,420 --> 00:22:22,380
+ثلاثية الـ Kynes اللي فيها حلقة مع روابط ثنائية
+
+290
+00:22:22,380 --> 00:22:27,380
+بقول عنها الـ Aromatic Compounds اللي فيها OH الـ
+
+291
+00:22:27,380 --> 00:22:32,080
+Alcohol اللي فيها SH الـ Thiols اللي فيها Oxygen
+
+292
+00:22:32,080 --> 00:22:38,040
+بين مجمعتين R بين كربنتين الـ Ethers اللي فيها
+
+293
+00:22:38,040 --> 00:22:43,220
+Sulphur بين كربنتين الـ Thioetherاللي فيها C
+
+294
+00:22:43,220 --> 00:22:46,780
+double bond O جنبها H الألديهيد، C double bond O
+
+295
+00:22:46,780 --> 00:22:50,700
+جنبها Carbons من الجهتين R groups الكيتون، C
+
+296
+00:22:50,700 --> 00:22:55,280
+double bond O جنبها OH الأسد، C double bond O
+
+297
+00:22:55,280 --> 00:22:59,700
+جنبها OR الأيستر، C double bond O جنبها Cl أو Br
+
+298
+00:22:59,700 --> 00:23:04,380
+الأسد هيلايد، جنبها NH2 الأمد، المركبات الكاربون
+
+299
+00:23:04,380 --> 00:23:08,200
+اللي حملة الـNH2 الأمين، اللي حملة الـCN نيترال
+
+300
+00:23:09,110 --> 00:23:12,530
+لاحظوا هذه هي العائلات الأساسية خلّينا نقول في الـ
+
+301
+00:23:12,530 --> 00:23:16,470
+Organ Chemistry إحنا في هذا المساق هندرس كل هذه
+
+302
+00:23:16,470 --> 00:23:21,670
+العائلات، يعني في الفصل الأول أخدنا مقدمة، بالفصل
+
+303
+00:23:21,670 --> 00:23:26,560
+التاني بناخد الـ Alkanesبالفصل التالت بناخد
+
+304
+00:23:26,560 --> 00:23:30,700
+الـAlkenes والـAlkynes، بالفصل الرابع بناخد
+
+305
+00:23:30,700 --> 00:23:34,200
+الـAromatic Compounds، بالفصل الخامس بناخد شوية
+
+306
+00:23:34,200 --> 00:23:38,340
+Stereochemistry، وبالسادس بندرس تفاعلات الإبدال،
+
+307
+00:23:38,340 --> 00:23:43,270
+في السابع بناخد الـAlcohols والـThiolsفي التامن
+
+308
+00:23:43,270 --> 00:23:46,930
+بناخد الـ ether والـ thioether في التاسع الالدهايد
+
+309
+00:23:46,930 --> 00:23:51,530
+والكيتون في العاشر الاسد ومشتقاته وفي شبطر 11 ال
+
+310
+00:23:51,530 --> 00:23:57,070
+amines هذا هو المفردات اللي بدنا ندرسها في هذا
+
+311
+00:23:57,070 --> 00:24:02,120
+المساق ب 11 فصل تمثل العائلات الأساسيةفي الـ
+
+312
+00:24:02,120 --> 00:24:05,460
+organic compounds كل عائلة أثناء دراستها بناخدها
+
+313
+00:24:05,460 --> 00:24:11,600
+بالتفصيل وبناخد خواصها وتحضيرها وتفاعلاتها وإن شاء
+
+314
+00:24:11,600 --> 00:24:13,560
+الله إلى محاضرة قادمة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5207ee38c45164b509a3ec5f74b05164c8065474
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI.srt
@@ -0,0 +1,1641 @@
+1
+00:00:05,670 --> 00:00:13,010
+ما زلنا في موضوع تفاعلات الإضافة للـ aldehydes والـ 
+
+2
+00:00:13,010 --> 00:00:17,250
+ketones هذا الحقيقة التفاعل اللي احنا بده يمر 
+
+3
+00:00:17,250 --> 00:00:22,990
+علينا هو تفاعل sodium 
+
+4
+00:00:24,030 --> 00:00:28,550
+السوديوم الهيدروجين السلفيت للألديهيد والكيتون 
+
+5
+00:00:28,550 --> 00:00:33,670
+طبعا  السوديوم الهيدروجين السلفيت في النهاية 
+
+6
+00:00:33,670 --> 00:00:40,330
+بيتفاعل مع سواء الألديهيد أو الكيتون هذا aldehyde
+
+7
+00:00:40,330 --> 00:00:45,250
+وهذا ketone زي ما أنتم شايفين من خلال sulfur اللي
+
+8
+00:00:45,250 --> 00:00:50,310
+موجود هنا بيصير عندنا رابطة S double bond O double
+
+9
+00:00:50,310 --> 00:00:57,590
+bond O O-Na+, بناءً على ذلك هو بيعطينا  soluble يعني
+
+10
+00:00:57,590 --> 00:01:03,050
+هذه الـ S O 3 minus Na plus هي عبارة عن هذا الشكل 
+
+11
+00:01:03,050 --> 00:01:08,770
+S double bond O double bond O O minus Na plus 
+
+12
+00:01:08,770 --> 00:01:15,950
+واضح؟ هي تفصيلها زي ما بتلاحظوا أن هذا المركب أن
+
+13
+00:01:15,950 --> 00:01:23,970
+هذا المركب الناتج هو عبارة عن ionic compound يعني
+
+14
+00:01:23,970 --> 00:01:30,050
+plus و minus عبارة عن ions وبناء على ذلك هذا 
+
+15
+00:01:30,050 --> 00:01:35,430
+المركب الأيوني بيكون عادة بيذوب في الماء
+
+16
+00:01:38,750 --> 00:01:44,830
+نتطلع على ال .. طبعا الـ .. ال lower aldehydes والـ
+
+17
+00:01:44,830 --> 00:01:48,670
+ketones زي ال acetaldehyde و زي ال acetone هدول
+
+18
+00:01:48,670 --> 00:01:52,630
+بيذوبوا في الماء، لكن السؤال لو ال aldehyde كبر صار 
+
+19
+00:01:52,630 --> 00:01:58,390
+خمس ذرات كربون، ببطل يذوب في الماء، الآن فائدة هذا 
+
+20
+00:01:58,390 --> 00:02:03,330
+التفاعل حقيقة أنه بيستخدم في عملية تنقية الـ 
+
+21
+00:02:03,330 --> 00:02:07,630
+الديهيد والكيتون يعني هذا ال الديهيد أو ال كيتون
+
+22
+00:02:07,630 --> 00:02:14,330
+خلينا نقول organic مركب أطول موجود مع أشياء ثانية 
+
+23
+00:02:14,330 --> 00:02:19,850
+كلها مخلوطة مع بعض مع organic compounds مخلوطين مع
+
+24
+00:02:19,850 --> 00:02:23,690
+بعض واضح أنا لما بفاعله مع ال sodium hydrogen 
+
+25
+00:02:23,690 --> 00:02:29,290
+sulfide هذا بحوله إلى salt، ال salt بيكون بيذوب في 
+
+26
+00:02:29,290 --> 00:02:34,190
+الماء باقي المركبات بتظهر في ال solvent ال organic
+
+27
+00:02:34,190 --> 00:02:41,130
+باخد الماء وبعاود أضيف عليها base .. برجع للالدهايد
+
+28
+00:02:41,130 --> 00:02:46,610
+أو الكيتون النقي واضحة الفكرة؟ مرة ثانية بيكون عند
+
+29
+00:02:46,610 --> 00:02:51,290
+أنا الالدهايد والكيتون مع other organic compounds
+
+30
+00:02:51,290 --> 00:02:57,310
+كيف بدي أنقيه، أفرزه لوحده؟ الآن الالدهايد أو 
+
+31
+00:02:57,310 --> 00:03:00,530
+الكيتون بيتفاعل مع ال sodium hydrogen sulfide 
+
+32
+00:03:00,530 --> 00:03:04,750
+وبيعطيني ionic compound هذا ال ionic compound إيش 
+
+33
+00:03:04,750 --> 00:03:10,600
+إحنا بنقول عنه؟ water soluble؟ بناء على ذلك أنا
+
+34
+00:03:10,600 --> 00:03:16,920
+باخد طبقة الماء بيكون بس اللي دايب فيها هذا المركب 
+
+35
+00:03:16,920 --> 00:03:19,520
+اللي هو ال الديهايد والكيتون، باقي ال organic
+
+36
+00:03:19,520 --> 00:03:23,100
+compounds ال impurities كلها بتكون في ال organic 
+
+37
+00:03:23,100 --> 00:03:27,440
+layer ما بديش إياها، باخد الماء بضيف عليها شوية base
+
+38
+00:03:28,120 --> 00:03:33,660
+أو أسيد فبيصير التفاعل العكسي برجع هذا المركب وبرجع 
+
+39
+00:03:33,660 --> 00:03:37,960
+ال الديهيد والكيتون بتكون كـ organic compound نقي
+
+40
+00:03:37,960 --> 00:03:42,740
+فهذه الطريقة اللي هي طريقة إضافة ال sodium 
+
+41
+00:03:42,740 --> 00:03:48,040
+hydrogen sulfide is a method to purify الديهيد والـ
+
+42
+00:03:48,040 --> 00:03:53,830
+كيتون by changing them to ionic compounds water
+
+43
+00:03:53,830 --> 00:03:58,850
+soluble ionic compounds بناخد الماء بس بيكون فيها 
+
+44
+00:03:58,850 --> 00:04:04,110
+مركب ال الديهايد أو ال كيتون على شكل أيون بعدين
+
+45
+00:04:04,110 --> 00:04:09,390
+بيتفاعل عكسي برجع للديهايد وكيتون نقي واضحة هذه
+
+46
+00:04:09,390 --> 00:04:16,330
+القصة يعني تطبيقية، الأساس فيها اللي هو addition يعني
+
+47
+00:04:16,330 --> 00:04:19,810
+هنا في النهاية برضه اللي صار عملية addition هيكوا
+
+48
+00:04:19,810 --> 00:04:23,190
+شايفين ال nucleophile والسيدة والبندقش وسارة 
+
+49
+00:04:23,190 --> 00:04:27,410
+الأساس فيها عملية addition
+
+50
+00:04:35,920 --> 00:04:42,080
+بعد هيك .. بعد هيك بنيجي لنوع ثاني .. لنوع ثاني من 
+
+51
+00:04:42,080 --> 00:04:47,700
+تفاعلات ال الديهيدس والكيتونز، طبعا ال الديهيدس 
+
+52
+00:04:47,700 --> 00:04:52,720
+والكيتونز احنا بنقدر نعتبرهم مثل بني آدم اللي
+
+53
+00:04:52,720 --> 00:04:58,080
+واقف على نص الدرج واضح؟ يعني لو في عندنا درج معين
+
+54
+00:04:58,080 --> 00:05:02,060
+وفي بني آدم واقف على نص الدرج شو الاحتمالات اللي 
+
+55
+00:05:02,060 --> 00:05:08,300
+عنده؟ اللي يطلع لفوق؟ أو ينزل لتحت، الآن ايش قصته 
+
+56
+00:05:08,300 --> 00:05:13,720
+هذا الدرج وأن ال aldehyde و ال ketone واقف على نص 
+
+57
+00:05:13,720 --> 00:05:18,880
+الدرج، هذا قصته بتجيني في موضوع الأكسدة والاختزال
+
+58
+00:05:18,880 --> 00:05:25,520
+لما أنا بحكي بقول في عندي alcohol R O H وفي عندي
+
+59
+00:05:25,520 --> 00:05:28,960
+بعد هيك ال aldehydes و ال ketones اللي هم ال R C
+
+60
+00:05:28,960 --> 00:05:36,190
+double bond O H وال R C double bond O R واضح هذا 
+
+61
+00:05:36,190 --> 00:05:41,970
+الـ alcohol وهذا الـ aldehyde وكيتون، بعد ذلك يأتي ال R-C-O
+
+62
+00:05:41,970 --> 00:05:50,770
+-H  الـ acid، الآن هذولا الثلاث احنا بنقدر نتحرك بينهم 
+
+63
+00:05:50,770 --> 00:05:55,030
+وسبق مر علينا هذا الكلام من خلال عمليات الأكسدة
+
+64
+00:05:55,030 --> 00:05:59,610
+والاختزال، بمعنى الـ alcohol أنا ممكن أعمل له oxidation
+
+65
+00:05:59,610 --> 00:06:03,950
+بيصير aldehyde، الـ aldehyde ممكن أعمل له oxidation
+
+66
+00:06:06,470 --> 00:06:11,510
+الـ acid، ممكن أعمل له reduction بيرجع aldehyde، ممكن أعمل له 
+
+67
+00:06:11,510 --> 00:06:16,850
+reduction بيرجع alcohol، لما بقاجي أنا هنا للـ aldehyde
+
+68
+00:06:16,850 --> 00:06:21,830
+والـ ketone موجودين في نص الطريق، بمعنى ممكن أنا أعمل
+
+69
+00:06:21,830 --> 00:06:28,140
+عملية reduction اختزال بيرجع الـ aldehyde والـ ketone
+
+70
+00:06:28,140 --> 00:06:32,700
+لالكحولز وممكن أعمل لهم oxidation، للـ aldehyde من 
+
+71
+00:06:32,700 --> 00:06:37,020
+الـ aldehyde للكيتون ما بتتأكسدش للـ aldehyde بيصير ايش؟ acid
+
+72
+00:06:37,020 --> 00:06:40,800
+هذه العملية oxidation واضحة؟
+
+73
+00:06:43,500 --> 00:06:48,760
+إذا كأنه الـ aldehyde اللي بنص الطريق أو بنعني بنص
+
+74
+00:06:48,760 --> 00:06:54,640
+الدرج ممكن أنزل فيه أرجعه لالكهول وممكن أعمل له
+
+75
+00:06:54,640 --> 00:06:59,940
+أكسدة ويصير حامض، ولذلك هدول التفاعلين بدنا
+
+76
+00:06:59,940 --> 00:07:04,880
+ندرسهم ونركز عليهم اللي هم reduction of aldehydes
+
+77
+00:07:04,880 --> 00:07:10,800
+و oxidation of aldehydes لإن هم جايين وين؟ في نص 
+
+78
+00:07:10,800 --> 00:07:14,920
+الطريق، طبعا في عندي كمان reduction of ketones بس
+
+79
+00:07:14,920 --> 00:07:18,400
+ما فيش عنده oxidation of ketones الكيتونز
+
+80
+00:07:18,400 --> 00:07:23,880
+ما بتتأكسدش لحمض، لكن اللي بتتأكسد الـ aldehyde واضحة؟
+
+81
+00:07:23,880 --> 00:07:29,860
+عشان ما فيش فيها H الـ ketone، الآن شو العوامل المؤكسدة
+
+82
+00:07:29,860 --> 00:07:33,960
+والمختزلة اللي بدها تدرس؟ أول شيء بندرس عملية
+
+83
+00:07:35,390 --> 00:07:43,690
+الاختزال، أول أشهر العوامل المختزلة العاملين هدول
+
+84
+00:07:43,690 --> 00:07:48,250
+اللي موجودين هنا اللي هم الليثيوم مع الالومنيوم و
+
+85
+00:07:48,250 --> 00:07:53,250
+4 ذرات هيدروجين على شكل هيدريد فبنسموه lithium 
+
+86
+00:07:53,250 --> 00:07:56,450
+tetrahydroaluminate
+
+87
+00:07:56,940 --> 00:08:02,560
+الحقيقة بصراحة هذا الاسم يمكن مش كثير مستعمل، في
+
+88
+00:08:02,560 --> 00:08:06,040
+اسم ثاني أكثر شهرة وأكثر استعمالًا، يعني خلّيني
+
+89
+00:08:06,040 --> 00:08:08,580
+أقول يمكن عشرة في المية من الناس بيحكوا بهذا
+
+90
+00:08:08,580 --> 00:08:13,600
+الطريقة والباقي بيقولوا عنه Lithium Aluminum 
+
+91
+00:08:13,600 --> 00:08:18,460
+Hydride واضحة؟ يعني هذا سواء شفتوه بهذا الاسم أو
+
+92
+00:08:18,460 --> 00:08:26,140
+بالاسم الأشهر Lithium Aluminum Hydride
+
+93
+00:08:26,570 --> 00:08:33,370
+هذا عبارة عن عامل مختزل، والعامل الثاني اللي كثير
+
+94
+00:08:33,370 --> 00:08:37,470
+الاستعمال برضه اللي هو ال sodium tetrahydride والـ
+
+95
+00:08:37,470 --> 00:08:44,130
+borate برضه هذا بنسميه sodium borohydride
+
+96
+00:08:44,130 --> 00:08:50,090
+sodium borohydride لما أنا كنت أسمع ثانية ما يعرفش 
+
+97
+00:08:50,090 --> 00:08:52,990
+حوالين اللي ألقاني ومصر ما يعرفش أكملت هيدروجين 
+
+98
+00:08:52,990 --> 00:08:58,890
+بالتحديد بظبط لكن في النهاية اسم شهرة، يعني لما ينقل
+
+99
+00:08:58,890 --> 00:09:05,130
+lithium aluminium hydride صح مش مبين بس خبرة الناس 
+
+100
+00:09:05,130 --> 00:09:11,110
+أنه lithium AlH4 واضحة؟ ولما بنقول sodium
+
+101
+00:09:11,110 --> 00:09:20,200
+borohydride NaBH4 واضحة؟ فسواء شفته بهذا الاسم أو 
+
+102
+00:09:20,200 --> 00:09:25,560
+شفته بهذا الاسم هدول هما أشهر العوامل المختزلة
+
+103
+00:09:25,560 --> 00:09:31,280
+اللي بتستخدم لاختزال ال الديهيد والكيتون واضحة؟ الآن
+
+104
+00:09:31,280 --> 00:09:35,740
+اللي بيصير عندي ببساطة لو أنا أخدت مثلا الـ 
+
+105
+00:09:35,740 --> 00:09:40,800
+acetaldehyde فعلته مع hydride لحظة أنا حاطط اثنين 
+
+106
+00:09:40,800 --> 00:09:43,900
+وبين قوسين ال H اللي هي ال hydride أكيد أنتم
+
+107
+00:09:43,900 --> 00:09:48,060
+بتميزوا كلمة hydride عن ال proton، ال hydride ايش 
+
+108
+00:09:48,060 --> 00:09:53,660
+معناها H minus، ال proton H plus، مرة ثانية بنذكر
+
+109
+00:09:53,660 --> 00:10:00,140
+فيها ال H plus ايش اسمها ال proton وال H minus
+
+110
+00:10:05,660 --> 00:10:14,120
+هنا التفاعل ببساطة هو عبارة عن تفاعل addition ولو
+
+111
+00:10:14,120 --> 00:10:18,340
+احنا ماخذينه تحت عنوان reduction of aldehydes and
+
+112
+00:10:18,340 --> 00:10:23,220
+ketones، أنا في عندي ببساطة H مع أزواج إلكترونات
+
+113
+00:10:23,220 --> 00:10:27,900
+يعني H minus، الآن هذه عبارة عن الـ nucleophile وهي
+
+114
+00:10:27,900 --> 00:10:31,920
+الـ C double bond O شو التفاعل المتوقع؟ أن هذا
+
+115
+00:10:31,920 --> 00:10:37,890
+النيوكليوفايل بده يهاجم وهذه بتصير OH واضحة نفس
+
+116
+00:10:37,890 --> 00:10:41,770
+الكلام اللي كنا نحكيه المرة الماضية أن هاي الـ
+
+117
+00:10:41,770 --> 00:10:46,870
+nucleophile وهاي ال C double bond O صارت OH
+
+118
+00:10:46,870 --> 00:10:54,590
+فحقيقة ضمن هذا المبدأ بتكون عملية ال reduction of
+
+119
+00:10:54,590 --> 00:10:58,770
+aldehydes and ketones using sodium or sodium
+
+120
+00:10:58,770 --> 00:11:01,950
+borohydride or lithium aluminum hydride is an 
+
+121
+00:11:01,950 --> 00:11:07,340
+addition reaction في محصلة هو addition reaction والـ
+
+122
+00:11:07,340 --> 00:11:13,000
+nucleophile is the hydride anion، ال nucleophile
+
+123
+00:11:13,000 --> 00:11:19,260
+is the hydride anion واضحة؟ طبعا ال hydride anion
+
+124
+00:11:19,260 --> 00:11:24,160
+لأنه ببساطة الالومنيوم بشكل عام بيكون حامل hydride 
+
+125
+00:11:24,160 --> 00:11:28,500
+زايدة، الالومنيوم عادة بيكون حامل ثلاث روابط، بستة
+
+126
+00:11:28,500 --> 00:11:32,900
+عشان يوصل لثمانية بيحمل hydride زايدة، لما بفقدها هذه
+
+127
+00:11:32,900 --> 00:11:38,930
+ال hydride الزائدة بيجي بيعمل addition reaction
+
+128
+00:11:38,930 --> 00:11:49,470
+فبيتحول الـ aldehyde إلى ال primary alcohol، بلاحظين
+
+129
+00:11:49,470 --> 00:11:53,070
+أنتم الـ aldehyde صار أي نوع من ال alcohol primary 
+
+130
+00:11:53,070 --> 00:11:59,370
+الـ aldehyde لما تطلع CH2 ال primary alcohol بعد 
+
+131
+00:11:59,370 --> 00:12:06,030
+شوية لما بنيجي نعمل reduction لل ketone بيصير 
+
+132
+00:12:06,030 --> 00:12:11,310
+بإمكانكم تطلعوا هنا هي الـ ketone وإجت ال H هاجمت و
+
+133
+00:12:11,310 --> 00:12:16,830
+صار عنده هي ال nucleophile وهي ال OH صار عنده 
+
+134
+00:12:16,830 --> 00:12:21,330
+secondary alcohol، إذا هذه من الجمل اللي أنتم
+
+135
+00:12:21,330 --> 00:12:27,370
+بدكم تكونوا عارفينها أنه بال reduction بالـ
+
+136
+00:12:27,370 --> 00:12:33,710
+reduction ال aldehyde شو بده يصير؟ ال primary
+
+137
+00:12:33,710 --> 00:12:34,250
+alcohol
+
+138
+00:12:38,420 --> 00:12:44,820
+بتصير secondary، واضحة هذه النقطة؟ هي اللي هي عملية
+
+139
+00:12:44,820 --> 00:12:51,440
+ال reduction، أنا بقي لي مش عملية صعبة الكلام فيها
+
+140
+00:12:51,440 --> 00:12:56,340
+واضحة؟ بالذات إذا احنا بنفهمها أن هي عملية addition
+
+141
+00:12:56,340 --> 00:13:01,120
+of a hydride، أنا يعني بطلت مختلفة عن كل عمليات الـ
+
+142
+00:13:01,120 --> 00:13:05,220
+additions السابقة، مش مختلفة عن عمليات ال additions
+
+143
+00:13:05,220 --> 00:13:12,960
+السابقة، طبعا هنا ممكن أحاول أعمل لكم ايش الـ
+
+144
+00:13:12,960 --> 00:13:17,400
+mechanism، ايش ال mechanism of addition مش كثير
+
+145
+00:13:17,400 --> 00:13:23,500
+بصراحة بهم عندي أن نتطلع عليها، لكن لو بتطلعوا
+
+146
+00:13:23,500 --> 00:13:28,700
+الأساس فيها أن أنتم بتجيبوا أيون هيدرايد وتخلوه 
+
+147
+00:13:28,700 --> 00:13:34,670
+يهاجم، واضحة؟ مش كثير مهتمين في هذه، نفس الشيء إذا 
+
+148
+00:13:34,670 --> 00:13:40,410
+استعملنا ال Sodium Borohydride المحصلة تماما نفس
+
+149
+00:13:40,410 --> 00:13:44,810
+الشيء تماما، واضحة؟ يعني سواء قلنا Lithium Aluminum
+
+150
+00:13:44,810 --> 00:13:51,590
+Hydride أو Sodium Borohydride النتيجة واحدة، إضافة
+
+151
+00:13:51,590 --> 00:13:57,530
+H minus وتحويل ال C double bond O إلى OH أو أكثر 
+
+152
+00:13:57,530 --> 00:14:02,890
+من هيك، ما نلزمنيش، واضحة؟ عشان أنا لما بتيجوا
+
+153
+00:14:02,890 --> 00:14:07,070
+بتتطلعوا على أمثلة هاي Lithium Aluminum Hydride، 
+
+154
+00:14:07,070 --> 00:14:09,850
+هاي Sodium Borohydride، هاي Sodium Borohydride، 
+
+155
+00:14:09,850 --> 00:14:17,430
+هاي Lithium Aluminum Hydride، هاي 
+
+156
+00:14:17,430 --> 00:14:17,750
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+157
+00:14:17,750 --> 00:14:19,050
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+158
+00:14:19,050 --> 00:14:21,050
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+159
+00:14:21,050 --> 00:14:21,570
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+160
+00:14:21,570 --> 00:14:21,610
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+161
+00:14:21,610 --> 00:14:22,010
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+162
+00:14:22,010 --> 00:14:25,650
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+163
+00:14:25,650 --> 00:14:30,450
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+164
+00:14:33,570 --> 00:14:38,070
+الـ ketone صار secondary alcohol والـ aldehyde صار
+
+165
+00:14:38,070 --> 00:14:41,650
+primary alcohol، والـ aldehyde اللي هان صار primary
+
+166
+00:14:41,650 --> 00:14:50,120
+alcohol، طبعا .. ربما سهولة الـ .. سهولة الكيمياء وين 
+
+167
+00:14:50,120 --> 00:14:55,720
+أن أنتم .. ايش ما بدها تكبر الجزئيات عندكم تكونوا 
+
+168
+00:14:55,720 --> 00:14:59,520
+عارفين أن أنتم بتتعاملوا مع رأس للتفاعل يعني ايش 
+
+169
+00:14:59,520 --> 00:15:03,380
+يكون المركب هنا .. هذا المركب هذا .. فيه شيء كثير
+
+170
+00:15:03,380 --> 00:15:08,020
+هنا .. كل هذا الكلام .. كل هذا الكلام بالنسبة لي 
+
+171
+00:15:08,020 --> 00:15:13,120
+.. كل هذا الكلام بالنسبة لي هو يمثل عملية نسخ و
+
+172
+00:15:13,120 --> 00:15:13,520
+لصق
+
+173
+00:15:16,400 --> 00:15:20,580
+تلاحظون؟ كل هذا الكلام يمثل بالنسبة لي عملية نسخ
+
+174
+00:15:20,580 --> 00:15:27,160
+ولصق لكن محور التفاعل الأساسي أنه .. أن هذه 
+
+175
+00:15:27,160 --> 00:15:34,200
+المجموعة ستصبح CH2OH، فقط، خلصنا الآن إن شاء
+
+176
+00:15:34,200 --> 00:15:38,920
+الله، بعد ذلك هذه المجموعة نربطها بقطار هنا، ليس
+
+177
+00:15:38,920 --> 00:1
+
+201
+00:18:10,930 --> 00:18:15,170
+كتير مهم اللي هو reaction with the Greenyard reagent
+
+202
+00:18:15,170 --> 00:18:20,770
+تفاعل الألديهيدز والكيتونز مع the Greenyard reagent
+
+203
+00:18:20,770 --> 00:18:26,750
+ربما البعض منكم ربما البعض منكم يكون ناسي يكون ناسي
+
+204
+00:18:26,750 --> 00:18:31,330
+the Greenyard reagent مر علينا .. وين ال Greenyard يا
+
+205
+00:18:31,330 --> 00:18:37,430
+أدرى إيه جد .. في chapter ال ethers .. في chapter
+
+206
+00:18:37,430 --> 00:18:43,710
+ال ethers احنا قلنا لما يكون عندنا RX نفاعلها مع
+
+207
+00:18:43,710 --> 00:18:50,550
+ال MG في وجود ال dry ether بيعطينا R
+
+208
+00:19:00,220 --> 00:19:04,420
+مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس
+
+209
+00:19:04,420 --> 00:19:08,360
+مجيكس
+
+210
+00:19:08,360 --> 00:19:11,900
+مجيكس
+
+211
+00:19:11,900 --> 00:19:18,380
+مجيكس مجيكس مجيكس من خلاله، فللـ Greenyard Reagent
+
+212
+00:19:18,380 --> 00:19:23,580
+عبارة عن R نيوكليوفايل في الآخر بس زم أنا قلت لـ
+
+213
+00:19:23,580 --> 00:19:27,100
+Greenyard Reagent هو R نيوكليوفايل إذا خلصنا شغل
+
+214
+00:19:27,100 --> 00:19:31,300
+بدي أخد أي ألديهيد أو كيتون و أتخيل إن أنا بفعله مع R
+
+215
+00:19:31,300 --> 00:19:36,960
+مع أزواج الإلكترونات تبعتها طبعا هي بتكون مرتبطة
+
+216
+00:19:36,960 --> 00:19:46,150
+بالـ MgBr بس كتفاعل R مع أزواج الإلكترونات مرة
+
+217
+00:19:46,150 --> 00:19:49,930
+تانية هذا عبارة عن ال addition reaction بهذا الشكل
+
+218
+00:19:49,930 --> 00:19:55,690
+و هذا بتصير OH في النهاية طبعا احنا بنضيف لجرينيار
+
+219
+00:19:55,690 --> 00:20:01,770
+و بعد هيك بنضيف له حامض مع ميه فالنهاية لما
+
+220
+00:20:01,770 --> 00:20:05,690
+بتكتيجوا تتطلعوا هنا هاي لجرينيار بفادل مثال عبارة
+
+221
+00:20:05,690 --> 00:20:13,940
+عن مجموعة إيش ال R اللي هنا CH3 CH2 في النتج انها
+
+222
+00:20:13,940 --> 00:20:20,300
+هتشوفوا CH3 CH2 إجت كمجموعة و الـ CW bond O صارت
+
+223
+00:20:20,300 --> 00:20:26,140
+OH هم لاحظين هذا المستطيل و ال .. هاي ال addition
+
+224
+00:20:26,140 --> 00:20:31,260
+هذا ال nuclear file و هاي ال CW bond O صارت OH
+
+225
+00:20:31,260 --> 00:20:33,660
+واضح؟
+
+226
+00:20:37,040 --> 00:20:44,380
+التفاعل مع الادهايط و الكيتون هو تفاعل اضافي طبعا
+
+227
+00:20:44,380 --> 00:20:48,880
+كتطبيق ليس أسهل منه نحضر الـR و نفعلها و نضع الـc
+
+228
+00:20:48,880 --> 00:20:54,600
+double bond O من خلّيها O H لكن متعودين احنا الآن
+
+229
+00:20:54,600 --> 00:21:00,700
+نميز النواتج اللي بتطلع متعودين نميز النواتج اللي
+
+230
+00:21:00,700 --> 00:21:03,000
+بتطلع وهذا الكلام هتشوفوه هنا
+
+231
+00:21:08,360 --> 00:21:14,260
+أنه هذا الـ Greenyard Reagent ممكن نفعله مع أبسط 
+
+232
+00:21:14,260 --> 00:21:18,320
+الديهيد في الدنيا اللي هو الـ Formaldehyde ممكن
+
+233
+00:21:18,320 --> 00:21:22,780
+نفعله مع أي الديهيد تاني غير الـ Formaldehyde و
+
+234
+00:21:22,780 --> 00:21:27,620
+ممكن نفعله مع الـ Ketone واضح؟
+
+235
+00:21:29,380 --> 00:21:33,220
+طريقة التفاعل أنه بدأ تأتي من مجموعة جرنير و
+
+236
+00:21:33,220 --> 00:21:39,000
+الـ CWbO تصير OH هذا كلام متفق عليه ما فيش فيه أي
+
+237
+00:21:39,000 --> 00:21:42,520
+مشكلة يعني هنا لما استعملنا مجموعة الإيثل هاي
+
+238
+00:21:42,520 --> 00:21:47,720
+مجموعة الإيثل حطناها بصندوق و الـ CWbO صارت OH و
+
+239
+00:21:47,720 --> 00:21:51,200
+نفس الشيء مع الأسيتالديهيد الو الديهيد أكبر هاي
+
+240
+00:21:51,200 --> 00:21:56,450
+مجموعة الإيثل و الـ CWbO صارت أو أتش وهنا مع
+
+241
+00:21:56,450 --> 00:22:00,350
+الأسيتون هاي مجموعة الإيثل و ال C double bond O
+
+242
+00:22:00,350 --> 00:22:06,070
+صارت أو أتش إذا أنا بحكي عن addition و نفسي
+
+243
+00:22:06,070 --> 00:22:12,510
+التفاعل لكن لما أجي أطلع على نوع الناتج لما أجي
+
+244
+00:22:12,510 --> 00:22:16,870
+أطلع على نوع الناتج بلاحظ أنه أنا لو فعلت ال Greenyard
+
+245
+00:22:16,870 --> 00:22:21,790
+Reagent مع ال Formaldehyde بيطلع عندي primary
+
+246
+00:22:21,790 --> 00:22:29,930
+alcohol تطلع هذا CH2OH إذا الناتج هنا primary
+
+247
+00:22:29,930 --> 00:22:35,970
+alcohol ولو فعلت ال Greenyard Reagent مع أي aldehyde تاني
+
+248
+00:22:35,970 --> 00:22:39,530
+أكبر من ال formaldehyde كمثال هنا الacetaldehyde
+
+249
+00:22:39,530 --> 00:22:46,010
+بيطلع عندي secondary alcohol ولو فعلت ال Greenyard
+
+250
+00:22:46,010 --> 00:22:51,210
+Reagent مع ال ketone بيطلع عندي tertiary alcohol
+
+251
+00:22:54,330 --> 00:23:00,270
+رغم أن أنا بحكي على نفس التفاعل بنفس النمط لكن
+
+252
+00:23:00,270 --> 00:23:06,110
+النواتج عندي مختلفة أن التفاعل مع ال Formaldehyde
+
+253
+00:23:06,110 --> 00:23:11,530
+بيعطيني Primary Alcohol التفاعل مع Any Other
+
+254
+00:23:11,530 --> 00:23:16,690
+Aldehyde بيعطيني Secondary Alcohol والتفاعل مع ال
+
+255
+00:23:16,690 --> 00:23:21,810
+Ketones بيعطيني Tertiary Alcohol هذا كلام طبعا
+
+256
+00:23:21,810 --> 00:23:27,350
+بالنسبة للكيميائيين أكثر من ممتاز لأنه بيصير عند
+
+257
+00:23:27,350 --> 00:23:31,650
+ال طرق من خلالها أقدر أحضر primary alcohol و
+
+258
+00:23:31,650 --> 00:23:36,090
+secondary alcohol و tertiary alcohol بمعنى لو أنا
+
+259
+00:23:36,090 --> 00:23:39,290
+في الامتحان بدي أجي أسأل الطلاب مثلا أو الطالبات
+
+260
+00:23:39,290 --> 00:23:43,770
+كيف بنحضر هذا المركب و المركب اللي أنا جايب له ماء
+
+261
+00:23:43,770 --> 00:23:48,690
+كحول مباشرة بيصير تفكيرهم أنه إيش نوع الكحول اللي
+
+262
+00:23:48,690 --> 00:23:54,290
+أنا بسأل عنه والله إذا tertiary بقدر أفعل كيتون
+
+263
+00:23:54,290 --> 00:24:01,310
+مع Greenyard Reagent إذا secondary الديهيد مع Greenyard Reagent
+
+264
+00:24:01,310 --> 00:24:09,370
+إذا primary Formaldehyde مع Greenyard Reagent واضح؟ فإنه
+
+265
+00:24:09,370 --> 00:24:15,780
+يكون عندي تفاعل بيطلع لي كل الاحتمالات هذا إيش أكتر
+
+266
+00:24:15,780 --> 00:24:18,720
+من ممتاز أحسن يبقى هذا التفاعل صحي من ال reduction
+
+267
+00:24:18,720 --> 00:24:22,760
+لأن ال reduction ما كانش طالع لنا tertiary، صح؟ لأ
+
+268
+00:24:22,760 --> 00:24:27,060
+ال reduction ما تطلعش منه tertiary alcohol من
+
+269
+00:24:27,060 --> 00:24:32,480
+الكيتون ال tertiary alcohol من الكيتون مع .. مع ال
+
+270
+00:24:32,480 --> 00:24:36,500
+Greenyard Reagent يعني .. مع ال Greenyard Reagent يعني لما أجيب لكم مثل how
+
+271
+00:24:36,500 --> 00:24:39,140
+can you prepare a tertiary alcohol ما أعرفش إذا أنا
+
+272
+00:24:39,140 --> 00:24:44,840
+على ال slides حاطط لكم أمثلة هنا يمكن نحط أمثلة
+
+273
+00:24:44,840 --> 00:24:50,120
+إكمال المعادلة لكن احنا بالتأكيد بإمكاننا يعني لو
+
+274
+00:24:50,120 --> 00:24:54,680
+رجعنا على هذا ال slide الآن انتبهوا معي لو مثلا
+
+275
+00:24:54,680 --> 00:25:00,460
+أنا اجيت في الامتحان سألتكم هذا السؤال جبت لكم هذا
+
+276
+00:25:00,460 --> 00:25:04,500
+المركب بنزين 
+
+277
+00:25:04,500 --> 00:25:07,320
+COH
+
+278
+00:25:12,150 --> 00:25:19,250
+How can you prepare this compound؟
+
+279
+00:25:19,250 --> 00:25:24,810
+ممكن أسيب السؤال زي ما هو هيك How can you prepare
+
+280
+00:25:24,810 --> 00:25:30,730
+this compound؟ و ممكن أزيد عليه كلام طالما هذا
+
+281
+00:25:30,730 --> 00:25:35,010
+tertiary alcohol إذا أنتم بتكونوا تتخيلوا أن ال
+
+282
+00:25:35,010 --> 00:25:44,020
+OH هذه كانت C double bond O وتفاعلت مع كيتون الآن
+
+283
+00:25:44,020 --> 00:25:50,200
+أي واحدة لكيتون أي واحدة لكيتون و أي واحدة ل Greenyard
+
+284
+00:25:50,200 --> 00:25:54,260
+Reagent في عندكم الحقيقة احتمالين يعني أنا لو عملت
+
+285
+00:25:54,260 --> 00:26:03,320
+هذا التفاعل C double bond O CH3 هاي كيتون و هذا
+
+286
+00:26:03,320 --> 00:26:06,060
+كيتون مشهور و موجود في المختبر شو اسمه
+
+287
+00:26:10,670 --> 00:26:15,150
+أسيتوفينون رخيص و موجود في المختبر المحلي
+
+288
+00:26:15,150 --> 00:26:20,090
+أسيتوفينون طب لو بدي أعمل ال كيتون زيّك بمجموعتين
+
+289
+00:26:20,090 --> 00:26:24,890
+مثل بمشي 
+
+290
+00:26:24,890 --> 00:26:32,250
+ولا لأ؟ هذا أي كيتون؟ أسيتون، أسيتون، أسيتون،
+
+291
+00:26:32,250 --> 00:26:34,730
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+292
+00:26:34,730 --> 00:26:36,910
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+293
+00:26:36,910 --> 00:26:43,610
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+294
+00:26:43,610 --> 00:26:49,770
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+295
+00:26:49,770 --> 00:26:52,370
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+296
+00:26:52,370 --> 00:26:52,530
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+297
+00:26:52,530 --> 00:27:04,090
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون مثل مثل
+
+298
+00:27:04,090 --> 00:27:08,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+299
+00:27:08,950 --> 00:27:09,010
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+300
+00:27:09,010 --> 00:27:10,010
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+301
+00:27:10,010 --> 00:27:14,150
+مثل مثل
+
+302
+00:27:14,150 --> 00:27:23,860
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل أكتر من
+
+303
+00:27:23,860 --> 00:27:27,720
+احتمال طبعا وارد هنا نفس الأشياء لو كنا نجيب الـ
+
+304
+00:27:27,720 --> 00:27:32,580
+co-secondary الكيتون راجعوا ال OH إلى CWO اعملوا 
+
+305
+00:27:32,580 --> 00:27:37,320
+ال ALDEHYDE وفاعلوه مع Greenyard Reagent لو كنا نطلب تحضير ال
+
+306
+00:27:37,320 --> 00:27:44,260
+primary الكيتون في هذه الحالة من إيه نحضره من تفاعل
+
+307
+00:27:44,260 --> 00:27:49,040
+Greenyard Reagent مع ال Formaldehyde من تفاعل Greenyard Reagent
+
+308
+00:27:49,040 --> 00:27:53,240
+مع ال Formaldehyde فهذه المنطقة بتكونوا عارفينها
+
+309
+00:27:53,240 --> 00:27:57,880
+هي منطقة بالتأكيد .. بالتأكيد هي منطقة سؤال في
+
+310
+00:27:57,880 --> 00:28:01,460
+الامتحان من أي ناحية هذه منطقة سؤال في الامتحان
+
+311
+00:28:01,460 --> 00:28:04,980
+عشان تعرفوا أن الأساتذة بتغلبوش لما يحطوا الامتحان
+
+312
+00:28:04,980 --> 00:28:08,000
+بكم
+
+313
+00:28:08,000 --> 00:28:13,120
+طريقة هنا بنسأل على هذا الموضوع؟
+
+314
+00:28:13,120 --> 00:28:20,260
+ممكن نقول لكم أكمل معادلة ممكن نقولكم كيف تحضر مركب،
+
+315
+00:28:20,260 --> 00:28:27,800
+وممكن نجيب لكم سؤال صح و غلط Formaldehyde acts
+
+316
+00:28:27,800 --> 00:28:31,920
+with the Greenyard Reagent producing tertiary
+
+317
+00:28:31,920 --> 00:28:36,060
+alcohol واضح؟
+
+318
+00:28:36,060 --> 00:28:40,080
+أو مثلا، secondary alcohols can be prepared from
+
+319
+00:28:40,080 --> 00:28:43,000
+the reaction of ketones with the Greenyard
+
+320
+00:28:43,000 --> 00:28:48,460
+Reagent واضح؟ مثل هذه الجملة اللي أحيانا بتغلب
+
+321
+00:28:48,460 --> 00:28:52,840
+فيكم، لكن زي ما أنتم ملاحظين الموضوع سهل جدا ال
+
+322
+00:28:52,840 --> 00:28:55,620
+Formaldehyde primary ال ال aldehydes الثانية
+
+323
+00:28:55,620 --> 00:29:00,600
+secondary ال ketone tertiary alcohol مع
+
+324
+00:29:17,340 --> 00:29:23,660
+هذه المعادلة العامة طبعا احنا عادة التفاعل مع
+
+325
+00:29:23,660 --> 00:29:26,980
+جرينيار نقول بالفعل نمرة واحد مع جرينيار نمرة اثنين
+
+326
+00:29:26,980 --> 00:29:31,620
+مع حامض يعني ما بديش منكم تعملوها خطوتين هو
+
+327
+00:29:31,620 --> 00:29:35,440
+التفاعل في داخل نفسه يتم على خطوتين لكن احنا
+
+328
+00:29:35,440 --> 00:29:41,380
+متعودين أن نقول لكم نفعل مع RMGX نمرة واحد و نمرة
+
+329
+00:29:41,380 --> 00:29:48,190
+اثنين H3O plus بناء على ذلك ماذا تكتبون ال Final
+
+330
+00:29:48,190 --> 00:29:53,790
+Product لكن أكيد التفاعل بيمشي على مراحل أنا مش
+
+331
+00:29:53,790 --> 00:29:58,650
+كتير مهتم بالمرحلة الوسطى أنه بيصير عندي O- MgBr
+
+332
+00:29:58,650 --> 00:30:03,950
+Plus و بعدين بالحمد بيعطينا نتيجة نهائية الآن إذا
+
+333
+00:30:03,950 --> 00:30:09,120
+بدنا نتطلع على الأمثلة الموجودة عندنا هي عندنا مثلا
+
+334
+00:30:09,120 --> 00:30:14,800
+هذا المركب ال Acetophenone شايفينه؟ بدفعله مع
+
+335
+00:30:14,800 --> 00:30:19,380
+إيثل ماغنسيوم بروميد إيش المجموعة اللي بده تيجي
+
+336
+00:30:19,380 --> 00:30:25,800
+عندك؟ الـ Ethyl إذا هاي الـ Acetophenone و الـ
+
+337
+00:30:25,800 --> 00:30:31,080
+Carbonyl O تبعته صارت OH و هاي المجموعة اللي هي
+
+338
+00:30:31,080 --> 00:30:34,180
+الـ Ethyl إجت من الـ Greenyard Reagent واضح؟
+
+339
+00:30:39,400 --> 00:30:44,420
+هنا تفاعل ثاني مش مع Greenyard Reagent مع metal ثاني شبيه
+
+340
+00:30:44,420 --> 00:30:47,660
+ب Greenyard Reagent مع ال lithium لكن نفس فكرة Greenyard Reagent
+
+341
+00:30:47,660 --> 00:30:51,140
+بالضبط يعني هذا يمثل اللي هو المركبات اللي مع ال
+
+342
+00:30:51,140 --> 00:30:54,200
+lithium برضه زي و زي المركبات اللي مع ال Greenyard Reagent
+
+343
+00:30:54,200 --> 00:31:00,580
+مجموعة ال R مع إلكترونات بناء على ذلك كل هذه
+
+344
+00:31:00,580 --> 00:31:06,180
+المجموعة بنتيجة تهاجم هنا و ال O تصير أقصر هذي
+
+345
+00:31:06,180 --> 00:31:07,560
+المجموعة اللي هي
+
+346
+00:31:14,510 --> 00:31:24,190
+هنا بس أكيد إنه ناسي يحط ال CH3 هذا خطأ طيب يعني
+
+347
+00:31:24,190 --> 00:31:28,550
+هاي المجموعة هادي اللي هي إجت دخلت عندنا و هادي
+
+348
+00:31:28,550 --> 00:31:35,380
+صارت OH هنا مثلا هي الديهيد لاحظوا احنا ليش
+
+349
+00:31:35,380 --> 00:31:40,260
+بنجيب لكم أحيانا تفاعلات بجزيئات كبيرة؟ عشان في
+
+350
+00:31:40,260 --> 00:31:43,940
+النهاية تأخذوا الجزء الكبير زي ما هو و المحور
+
+351
+00:31:43,940 --> 00:31:46,920
+الأساسي تبع التفاعل اللي عندكم هو محور إيش؟
+
+352
+00:31:46,920 --> 00:31:52,780
+المجموعة الوظيفية يعني هي هنا جزء كبير أنا كل هذا
+
+353
+00:31:52,780 --> 00:31:57,790
+الجزء الكبير هيني ب أُحُطه في دائرة اللي هو عبارة عن
+
+354
+00:31:57,790 --> 00:32:05,890
+CH CH3 CH3 إذا بتلاحظوا هذا كله نفسه مازال موجود
+
+355
+00:32:05,890 --> 00:32:11,590
+زي ما هو لكن إجت مجموعة الـ CH اللي مع مغنيسيوم أو
+
+356
+00:32:11,590 --> 00:32:18,950
+مع ليثيوم شبكت واسطة بالبندقوش و صارت OH فقط هاي
+
+357
+00:32:18,950 --> 00:32:23,850
+هادي شبيه جرينيار درجة هنا هاي مجموعة مثلا كبيرة
+
+358
+00:32:23,850 --> 00:32:28,920
+هادي كلها المجموعة اللي هيتمثل الـ Grignard Reagent
+
+359
+00:32:28,920 --> 00:32:37,700
+Agent هذا الجزء كله ماذا يعني؟ محور
+
+360
+00:32:37,700 --> 00:32:39,060
+التفاعل اللي عندك
+
+361
+00:32:42,440 --> 00:32:46,240
+دخلت المجموعة اللي عندنا و الـ C double bond O
+
+362
+00:32:46,240 --> 00:32:50,880
+صارت OH و كذلك الحال في الأمثلة اللي موجودة تحت
+
+363
+00:32:50,880 --> 00:32:56,640
+هذا الكلام طبعا لازم ننبهكم لشغلة أنه مثل هذه
+
+364
+00:32:56,640 --> 00:33:01,500
+الأمثلة و كل دراسة ال organic chemistry إذا ما كنتم
+
+365
+00:33:01,500 --> 00:33:05,220
+بتمسكوا ورقة و قلم و بتعيدوا كتابة التفاعل و
+
+366
+00:33:05,220 --> 00:33:08,480
+بتعيدوا كيف أن هذه المجموعة إجت كيف أن الـ C
+
+367
+00:33:08,480 --> 00:33:13,940
+double bond O في كل الأحوال عاملة بتصير OH OH OH OH
+
+368
+00:33:13,940 --> 00:33:20,740
+OH OH OH تطلع عليها هي كرموز تبدو العملية متعبة
+
+369
+00:33:20,740 --> 00:33:27,400
+تتعاملوا معها بنوع من التحليل العملية بسيطة جدا
+
+370
+00:33:27,400 --> 00:33:31,000
+أنه أنا عندي جزء إن شاء الله يكون رسم له أنا خريطة
+
+371
+00:33:31,000 --> 00:33:35,360
+فلسطين مش مواد كيميائية بدي أخده زي ما هو في
+
+372
+00:33:35,360 --> 00:33:39,380
+النهاية الـC double bond O شو هتصير؟ الـCOH و
+
+373
+00:33:39,380 --> 00:33:44,430
+المجموعة بتدخل كله بيصير عليه واضح؟ هذا الكلام
+
+374
+00:33:44,430 --> 00:33:48,810
+بالتأكيد إذا ما طبقتوه و عدتوا كتابته بالقلم الرصاص
+
+375
+00:33:4
+
+401
+00:36:28,900 --> 00:36:32,100
+بدي أكبر و أعمل زيك و زيك و زيك و زيك هذه كلها
+
+402
+00:36:32,100 --> 00:36:39,270
+ذرات carbon و في الآخر أجه أحط هنا فنلواضح؟ الآن
+
+403
+00:36:39,270 --> 00:36:44,410
+الـ Terminal Alkynes أخدنا عنهم إن هما عبارة عن
+
+404
+00:36:44,410 --> 00:36:52,370
+Acids لمن فعلهم مع ال NA مع ال Sodium بيفقد بروتون
+
+405
+00:36:52,370 --> 00:36:56,550
+و بيعطينا ال Acetylide إذا لما أنا .. هذا التفاعل
+
+406
+00:36:56,550 --> 00:36:59,410
+لسه اللي أخدته اللي بدأ أستفيد منه لما أجي بدأ
+
+407
+00:36:59,410 --> 00:37:03,090
+أتذكر هالكلام جزء كبير شوية الامتحان الصعب ولا
+
+408
+00:37:03,090 --> 00:37:07,310
+كبير ولا إشي هذه ال C ال triple bond C اللي جمّع H
+
+409
+00:37:07,310 --> 00:37:10,110
+لما أفعلها مع ال Sodium بدأ تشيلي ال H و تحطلي
+
+410
+00:37:10,110 --> 00:37:13,490
+Sodium معنا ذلك أنا إيش اللي بدأ أعمله لو أنا قاعد
+
+411
+00:37:13,490 --> 00:37:18,940
+على برنامج رسم و بعمل نسخ و لاصق؟بدي أخد هذه
+
+412
+00:37:18,940 --> 00:37:23,060
+المجموعة كلها و أحطها هنا فقط بدي أشيل الـH و أحط
+
+413
+00:37:23,060 --> 00:37:27,840
+الـNA ألاحظين كيف التعامل مع ال .. مع ال organic
+
+414
+00:37:27,840 --> 00:37:32,820
+problems C
+
+415
+00:37:32,820 --> 00:37:37,620
+triple bond C NA
+
+416
+00:37:37,620 --> 00:37:43,590
+بتصير هذه minus وهذه plus أيا كان الجزء اللي هنا
+
+417
+00:37:43,590 --> 00:37:49,110
+الآن هنا محور المسألة أنه هذا ال Acetylide
+
+418
+00:37:49,110 --> 00:37:52,610
+compound اللي سمناه Acetylide بيحتوي على ايه عشان
+
+419
+00:37:52,610 --> 00:37:59,850
+علمه بالأزرق كمان مرة بيحتوي على سالب إذا هو يمثل
+
+420
+00:37:59,850 --> 00:38:05,790
+ال nucleophile هذا الجزء كله يمثل ال nucleophile
+
+421
+00:38:05,790 --> 00:38:12,140
+كيف بتفاعل ال nucleophile مع الالديهال او الكيتون
+
+422
+00:38:12,140 --> 00:38:18,620
+أكيد بتفاعل الاديشن كل هذا بده ييجي يهجم على
+
+423
+00:38:18,620 --> 00:38:24,580
+الكربونة ويحول السيما بالبند أو إلى OH واضح؟ هاي
+
+424
+00:38:24,580 --> 00:38:29,840
+مثلا هنا أستيلايد صغير مش كبير زي هذا اللي بخوف
+
+425
+00:38:29,840 --> 00:38:35,030
+هاي أستيلايد صغير شايفينه؟ بدو يتفاعل مع هذا الـ
+
+426
+00:38:35,030 --> 00:38:40,130
+Ketone وين المحور؟ إن هذا زوج الإلكترونات يجي
+
+427
+00:38:40,130 --> 00:38:45,450
+يتفاعل، هاد الكربون أو هاد تصير فزي ما بتلاحظوا
+
+428
+00:38:45,450 --> 00:38:50,590
+أنتوا، باقي الـ Ketone أو الـ aldehyde، ضالوا زي
+
+429
+00:38:50,590 --> 00:39:00,010
+ما هو، باقي الـ acetylide، ضالوا زي ما هو، طبعا،
+
+430
+00:39:00,010 --> 00:39:05,430
+إذا إيش التفاعل بيصف في النهاية؟ حقيقة التفاعل
+
+431
+00:39:05,430 --> 00:39:09,470
+بالنهاية هو عبارة .. يعني لو كنتوا بتكونوا بسطوا
+
+432
+00:39:09,470 --> 00:39:13,410
+الموضوع جدا جدا هو عبارة عن زوج إلكترونات بيهاجم
+
+433
+00:39:13,410 --> 00:39:19,130
+هنا و بيحولها إلى OH هذه زوج الإلكترونات وهذه صارت
+
+434
+00:39:19,130 --> 00:39:24,610
+OH طب و باقي الكلام كله اللي هنا زي ما هو و باقي
+
+435
+00:39:24,610 --> 00:39:28,350
+الكلام كله اللي هنا مع هذا زوج الإلكترونات زي ما
+
+436
+00:39:28,350 --> 00:39:31,150
+هو واضح؟
+
+437
+00:39:36,120 --> 00:39:42,360
+الآن انتبهوا مثلا على هذا المركب هاي مركب كبير
+
+438
+00:39:42,360 --> 00:39:49,900
+جد البحر شايفينه؟ في النهاية إيش موجود فيه؟ أسيطة
+
+439
+00:39:49,900 --> 00:39:53,780
+بالـ bond O كل هذا المركب هيظل زي ما هو بدا
+
+440
+00:39:53,780 --> 00:39:57,580
+أفعله أنا في هذه الحالة معي green يعني رجعت ل
+
+441
+00:39:57,580 --> 00:40:02,640
+green يعني هذه الـCH3 بنتيجة أنا وهذه الأسيطة بالـ
+
+442
+00:40:02,640 --> 00:40:03,580
+bond O تصير
+
+443
+00:40:07,570 --> 00:40:11,170
+الآن هذا الناتج بعدين بيعمل عملية cyclization تخرج
+
+444
+00:40:11,170 --> 00:40:15,250
+الموضوع احنا هاي الناتج اللي ملاحظينه ان واحدة من
+
+445
+00:40:15,250 --> 00:40:22,190
+ال CH3 اتجت من برا وهي هذا الجزء كله اللي كان
+
+446
+00:40:22,190 --> 00:40:27,270
+موجود عندى عشانك مثلا هذا الجزء الأخير اللي مبين
+
+447
+00:40:27,270 --> 00:40:33,310
+كبير لو قلتلكوا بدي افعله مع benzaldehyde بقدر بدي
+
+448
+00:40:33,310 --> 00:40:41,640
+أقول زائد phenylC double bond OH كيف
+
+449
+00:40:41,640 --> 00:40:50,380
+هتعملوه هذي بده تاجم هنا و ال O بده تصير OH فقط
+
+450
+00:40:50,380 --> 00:40:57,980
+مجرد انكوا تجيبوا هذي هنا و هذي بتخلوها OH هنا و
+
+451
+00:40:57,980 --> 00:41:03,420
+رسموه طبعا أنا بصير جديش عندكم القدرة أنه بجلم
+
+452
+00:41:03,420 --> 00:41:07,240
+لرصاص تلسخه الأشياء زي ما هي ترسموها مش أكتر،
+
+453
+00:41:07,240 --> 00:41:13,280
+واضح؟ فزي ما بتلاحظوا لما انا من محاضرتين قلتلكوا
+
+454
+00:41:13,280 --> 00:41:17,160
+انه في ال الديهيدس والكيتونز كل الشغل اللي عندكوا
+
+455
+00:41:17,160 --> 00:41:22,300
+تطبيق وقاعد انا بدور محاضرتين كاملين حوالي الفكرة
+
+456
+00:41:22,300 --> 00:41:26,220
+واحدة انه زوج إلكترونات بيهاجم على ال C double
+
+457
+00:41:26,220 --> 00:41:32,160
+bond O و بيحولها إلى OH مازدناش عن هذه الفكرة لكن
+
+458
+00:41:32,160 --> 00:41:38,950
+إيش عملنا؟ عملنا أمثلة تطبيقية كتيرة بنجح عند موضوع
+
+459
+00:41:38,950 --> 00:41:43,390
+الـ oxidation of aldehydes and keto
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..92c61feaf239fd5de8b752a526fda3fa220122c7
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2299, "start": 5.67, "end": 22.99, "text": "ما زلنا في موضوع تفاعلات الإضافة للـ aldehydes و الـ ketones هذا الحقيقة التفاعل اللي لان بده يمر علينا هو تفاعل ham", "tokens": [15042, 30767, 1211, 8315, 8978, 3714, 2407, 11242, 45367, 6055, 5172, 995, 30241, 9307, 33688, 11242, 31845, 3660, 24976, 39184, 16798, 68, 3495, 14792, 4032, 2423, 39184, 14979, 2213, 23758, 21542, 38436, 28671, 16712, 5172, 995, 30241, 13672, 1829, 5296, 7649, 47525, 3224, 7251, 29973, 25894, 8315, 31439, 6055, 5172, 995, 30241, 7852], "avg_logprob": -0.23755787368173953, "compression_ratio": 1.3617021276595744, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 5.67, "end": 6.77, "word": "ما", "probability": 0.342529296875}, {"start": 6.77, "end": 7.19, "word": " زلنا", "probability": 0.9475911458333334}, {"start": 7.19, "end": 7.47, "word": " في", "probability": 0.93310546875}, {"start": 7.47, "end": 8.87, "word": " موضوع", "probability": 0.989990234375}, {"start": 8.87, "end": 10.83, "word": " تفاعلات", "probability": 0.8884765625}, {"start": 10.83, "end": 11.65, "word": " الإضافة", "probability": 0.9635009765625}, {"start": 11.65, "end": 12.21, "word": " للـ", "probability": 0.6282958984375}, {"start": 12.21, "end": 12.83, "word": " aldehydes", "probability": 0.7298583984375}, {"start": 12.83, "end": 13.01, "word": " و", "probability": 0.5}, {"start": 13.01, "end": 13.21, "word": " الـ", "probability": 0.656005859375}, {"start": 13.21, "end": 13.79, "word": " ketones", "probability": 0.763671875}, {"start": 13.79, "end": 14.87, "word": " هذا", "probability": 0.423095703125}, {"start": 14.87, "end": 15.41, "word": " الحقيقة", "probability": 0.9803059895833334}, {"start": 15.41, "end": 16.23, "word": " التفاعل", "probability": 0.894775390625}, {"start": 16.23, "end": 16.41, "word": " اللي", "probability": 0.845703125}, {"start": 16.41, "end": 16.75, "word": " لان", "probability": 0.39471435546875}, {"start": 16.75, "end": 17.03, "word": " بده", "probability": 0.5640869140625}, {"start": 17.03, "end": 17.25, "word": " يمر", "probability": 0.9189453125}, {"start": 17.25, "end": 17.61, "word": " علينا", "probability": 0.943115234375}, {"start": 17.61, "end": 17.73, "word": " هو", "probability": 0.943359375}, {"start": 17.73, "end": 18.47, "word": " تفاعل", "probability": 0.89990234375}, {"start": 18.47, "end": 22.99, "word": " ham", "probability": 0.529296875}], "temperature": 1.0}, {"id": 2, "seek": 5099, "start": 24.03, "end": 50.99, "text": "السوديوم الهيدروجين السلفيت للألديهيد والكيتون طبعا السوديوم الهيدروجين السلفيت في النهاية بيتفاعل مع سواء الألديهيد أو الكيتون هذا ألديهيد وهذا كيتون زي ما انتوا شايفين من خلال السلفر اللي موجود هنا بيصير عندنا رابطة S double bond O double bond O", "tokens": [6027, 3794, 23328, 1829, 20498, 2423, 3224, 25708, 2288, 29245, 9957, 21136, 46538, 36081, 24976, 10721, 1211, 16254, 3224, 25708, 4032, 6027, 4117, 36081, 11536, 23032, 3555, 3615, 995, 21136, 23328, 1829, 20498, 2423, 3224, 25708, 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28.55, "word": " والكيتون", "probability": 0.725390625}, {"start": 28.55, "end": 30.01, "word": " طبعا", "probability": 0.7547454833984375}, {"start": 30.01, "end": 30.99, "word": " السوديوم", "probability": 0.75286865234375}, {"start": 30.99, "end": 31.65, "word": " الهيدروجين", "probability": 0.939453125}, {"start": 31.65, "end": 32.79, "word": " السلفيت", "probability": 0.9593098958333334}, {"start": 32.79, "end": 32.95, "word": " في", "probability": 0.78515625}, {"start": 32.95, "end": 33.67, "word": " النهاية", "probability": 0.9153645833333334}, {"start": 33.67, "end": 35.27, "word": " بيتفاعل", "probability": 0.8974609375}, {"start": 35.27, "end": 35.69, "word": " مع", "probability": 0.89404296875}, {"start": 35.69, "end": 36.39, "word": " سواء", "probability": 0.8541666666666666}, {"start": 36.39, "end": 37.43, "word": " الألديهيد", "probability": 0.8814453125}, {"start": 37.43, "end": 38.15, "word": " أو", "probability": 0.78759765625}, {"start": 38.15, "end": 39.11, "word": " الكيتون", "probability": 0.865234375}, {"start": 39.11, "end": 39.63, "word": " هذا", "probability": 0.473876953125}, {"start": 39.63, "end": 40.33, "word": " ألديهيد", "probability": 0.854541015625}, {"start": 40.33, "end": 40.61, "word": " وهذا", "probability": 0.6727294921875}, {"start": 40.61, "end": 41.01, "word": " كيتون", "probability": 0.9617513020833334}, {"start": 41.01, "end": 41.21, "word": " زي", "probability": 0.6226806640625}, {"start": 41.21, "end": 41.29, "word": " ما", "probability": 0.943359375}, {"start": 41.29, "end": 41.97, "word": " انتوا", "probability": 0.69384765625}, {"start": 41.97, "end": 43.07, "word": " شايفين", "probability": 0.9737548828125}, {"start": 43.07, "end": 43.65, "word": " من", "probability": 0.96044921875}, {"start": 43.65, "end": 44.17, "word": " خلال", "probability": 0.99365234375}, {"start": 44.17, "end": 45.09, "word": " السلفر", "probability": 0.7168782552083334}, {"start": 45.09, "end": 45.25, "word": " اللي", "probability": 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"seek": 7937, "start": 51.35, "end": 79.37, "text": "O-NA+, بناءً على ذلك هو بيعطينا solved يعني هذه الـ S O 3 minus NA plus هي عبارة عن هذا الشكل S double bond O double bond O O minus NA plus واضح؟ هي تفصيلها زي ما بتلاحظوا ان هذا المركب ان هذا المركب الناتج هو عبارة عن", "tokens": [46, 12, 5321, 46797, 44945, 16606, 14111, 15844, 29910, 23275, 31439, 4724, 1829, 3615, 9566, 1829, 8315, 13041, 37495, 22653, 29538, 2423, 39184, 318, 422, 805, 3175, 16585, 1804, 39896, 6225, 3555, 9640, 3660, 18871, 23758, 25124, 28820, 318, 3834, 6086, 422, 3834, 6086, 422, 422, 3175, 16585, 1804, 4032, 46958, 5016, 22807, 39896, 6055, 5172, 9381, 26895, 11296, 30767, 1829, 19446, 39894, 15040, 5016, 19913, 14407, 16472, 23758, 9673, 31747, 3555, 16472, 23758, 9673, 31747, 3555, 2423, 8315, 2655, 7435, 31439, 6225, 3555, 9640, 3660, 18871], "avg_logprob": -0.35564631867137825, "compression_ratio": 1.64, "no_speech_prob": 3.7550926208496094e-06, "words": [{"start": 51.35, "end": 51.67, "word": "O", 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ينقل lithium aluminium hydride صح مش مبين بس خبرة الناس انه lithium AlH4 واضح؟ و لما بنقول sodium borohydride NaBH4 واضح؟", "tokens": [3555, 19913, 3555, 9566, 44381, 8978, 28239, 11296, 10632, 24525, 2304, 13412, 3224, 25720, 37495, 22653, 5296, 15042, 7251, 1863, 4587, 1211, 32180, 35239, 5796, 25502, 20328, 5016, 37893, 3714, 3555, 9957, 4724, 3794, 16490, 3555, 25720, 2423, 8315, 3794, 16472, 3224, 32180, 967, 39, 19, 4032, 46958, 5016, 22807, 4032, 5296, 15042, 44945, 39648, 20265, 14828, 1445, 6655, 25502, 6056, 33, 39, 19, 4032, 46958, 5016, 22807], "avg_logprob": -0.19723731970441513, "compression_ratio": 1.4096385542168675, "no_speech_prob": 0.0, "words": [{"start": 534.83, "end": 535.45, "word": "بظبط", "probability": 0.7379150390625}, {"start": 535.45, "end": 535.71, "word": " لكن", "probability": 0.7412109375}, {"start": 535.71, "end": 536.15, "word": " في", "probability": 0.857421875}, {"start": 536.15, "end": 536.51, "word": " النهاية", "probability": 0.94921875}, {"start": 536.51, "end": 536.93, "word": " اسم", "probability": 0.947021484375}, {"start": 536.93, "end": 537.49, "word": " شهرة", "probability": 0.9609375}, {"start": 537.49, "end": 537.99, "word": " يعني", "probability": 0.68505859375}, {"start": 537.99, "end": 538.35, "word": " لما", "probability": 0.95556640625}, {"start": 538.35, "end": 538.89, "word": " ينقل", "probability": 0.926513671875}, {"start": 538.89, "end": 539.87, "word": " lithium", "probability": 0.48291015625}, {"start": 539.87, "end": 540.41, "word": " aluminium", "probability": 0.439697265625}, {"start": 540.41, "end": 541.61, "word": " hydride", "probability": 0.669921875}, {"start": 541.61, "end": 542.31, "word": " صح", "probability": 0.983642578125}, {"start": 542.31, "end": 542.51, "word": " مش", "probability": 0.98828125}, {"start": 542.51, "end": 543.15, "word": " مبين", "probability": 0.71923828125}, {"start": 543.15, "end": 543.89, "word": " بس", "probability": 0.906005859375}, {"start": 543.89, "end": 544.49, "word": " خبرة", "probability": 0.8821614583333334}, {"start": 544.49, "end": 545.13, "word": " الناس", "probability": 0.9925130208333334}, {"start": 545.13, "end": 545.61, "word": " انه", "probability": 0.73291015625}, {"start": 545.61, "end": 546.99, "word": " lithium", "probability": 0.8193359375}, {"start": 546.99, "end": 548.63, "word": " AlH4", "probability": 0.7833658854166666}, {"start": 548.63, "end": 549.77, "word": " واضح؟", "probability": 0.9052734375}, {"start": 549.77, "end": 549.87, "word": " و", "probability": 0.93359375}, {"start": 549.87, "end": 550.07, "word": " لما", "probability": 0.734130859375}, {"start": 550.07, "end": 550.49, "word": " بنقول", "probability": 0.91259765625}, {"start": 550.49, "end": 551.11, "word": " sodium", "probability": 0.4423828125}, {"start": 551.11, "end": 553.07, "word": " borohydride", "probability": 0.9044189453125}, {"start": 553.07, "end": 555.49, "word": " NaBH4", "probability": 0.82977294921875}, {"start": 555.49, "end": 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"end": 564.38, "word": " العوامل", "probability": 0.988525390625}, {"start": 564.38, "end": 565.56, "word": " المختزلة", "probability": 0.982177734375}, {"start": 565.56, "end": 565.82, "word": " اللي", "probability": 0.76611328125}, {"start": 565.82, "end": 566.54, "word": " تستعمل", "probability": 0.9774169921875}, {"start": 566.54, "end": 567.32, "word": " لاختزال", "probability": 0.93662109375}, {"start": 567.32, "end": 567.62, "word": " ال", "probability": 0.9599609375}, {"start": 567.62, "end": 568.12, "word": " الديهيد", "probability": 0.669677734375}, {"start": 568.12, "end": 568.98, "word": " والكيتون", "probability": 0.693603515625}, {"start": 568.98, "end": 570.66, "word": " واضح؟", "probability": 0.70086669921875}, {"start": 570.66, "end": 571.28, "word": " الآن", "probability": 0.645263671875}, {"start": 571.28, "end": 572.48, "word": " اللي", "probability": 0.949462890625}, {"start": 572.48, "end": 572.9, "word": " بيصير", "probability": 0.8175048828125}, {"start": 572.9, 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نحكيه المرة الماضية ان هاي ال nucleophile و هاي ال C double bond O صارت OH فحقيقة ضمن هذا المبدأ بتكون عملية ال reduction of aldehydes and ketones using sodium or sodium borohydride or lithium aluminum hydride is an addition reaction", "tokens": [2655, 9381, 13546, 13931, 4032, 46958, 5016, 8717, 36178, 2423, 28820, 10943, 13672, 1829, 9122, 8315, 8717, 5016, 4117, 1829, 3224, 9673, 25720, 9673, 46958, 10632, 16472, 8032, 47302, 2423, 14962, 49242, 4032, 8032, 47302, 2423, 383, 3834, 6086, 422, 20328, 9640, 2655, 13931, 6156, 5016, 38436, 28671, 48812, 27842, 23758, 9673, 44510, 10721, 39894, 30544, 6225, 42213, 10632, 2423, 11004, 295, 16798, 68, 3495, 14792, 293, 14979, 2213, 1228, 20265, 420, 20265, 14828, 1445, 6655, 25502, 420, 32180, 15656, 5796, 25502, 307, 364, 4500, 5480], "avg_logprob": -0.22737068759983983, "compression_ratio": 1.5128205128205128, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 635.17, "end": 635.75, "word": "تصير", "probability": 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"word": " or", "probability": 0.57568359375}, {"start": 658.15, "end": 658.77, "word": " sodium", "probability": 0.4501953125}, {"start": 658.77, "end": 659.59, "word": " borohydride", "probability": 0.9027099609375}, {"start": 659.59, "end": 659.79, "word": " or", "probability": 0.487548828125}, {"start": 659.79, "end": 660.07, "word": " lithium", "probability": 0.806640625}, {"start": 660.07, "end": 660.39, "word": " aluminum", "probability": 0.427734375}, {"start": 660.39, "end": 661.13, "word": " hydride", "probability": 0.767822265625}, {"start": 661.13, "end": 661.51, "word": " is", "probability": 0.90283203125}, {"start": 661.51, "end": 661.95, "word": " an", "probability": 0.87451171875}, {"start": 661.95, "end": 662.51, "word": " addition", "probability": 0.91943359375}, {"start": 662.51, "end": 663.31, "word": " reaction", "probability": 0.91552734375}], "temperature": 1.0}, {"id": 28, "seek": 69422, "start": 664.84, "end": 694.22, "text": "في محصلة هو addition reaction و ال nucleophile is the hydride anion ال nucleophile is the hydride anion واضح؟ طبعا ال hydride anion لأنه ببساطة الألمنيوم بشكل عام بيكون حامل hydride زايدة الألمنيوم عادة بيكون حامل تلت روابط بستة عشان يصل تمانية بيحمل hydride زايدة لما بفقدها هذه ال hydride زيادة", "tokens": [41185, 3714, 5016, 9381, 37977, 31439, 4500, 5480, 4032, 2423, 14962, 49242, 307, 264, 5796, 25502, 364, 313, 2423, 14962, 49242, 307, 264, 5796, 25502, 364, 313, 4032, 46958, 5016, 22807, 23032, 3555, 3615, 995, 2423, 5796, 25502, 364, 313, 5296, 33456, 3224, 4724, 3555, 3794, 41193, 3660, 16247, 19528, 22653, 20498, 4724, 8592, 28820, 6225, 10943, 4724, 1829, 30544, 11331, 10943, 1211, 5796, 25502, 30767, 995, 25708, 3660, 16247, 19528, 22653, 20498, 6225, 18513, 3660, 4724, 1829, 30544, 11331, 10943, 1211, 6055, 1211, 2655, 12602, 14407, 3555, 9566, 4724, 14851, 3660, 6225, 8592, 7649, 7251, 36520, 46811, 7649, 10632, 4724, 1829, 35571, 1211, 5796, 25502, 30767, 995, 25708, 3660, 5296, 15042, 4724, 5172, 28543, 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0.97998046875}, {"start": 686.3, "end": 686.64, "word": " بيكون", "probability": 0.9130859375}, {"start": 686.64, "end": 686.9, "word": " حامل", "probability": 0.904296875}, {"start": 686.9, "end": 687.28, "word": " تلت", "probability": 0.8036295572916666}, {"start": 687.28, "end": 687.82, "word": " روابط", "probability": 0.9427490234375}, {"start": 687.82, "end": 688.5, "word": " بستة", "probability": 0.8811848958333334}, {"start": 688.5, "end": 689.28, "word": " عشان", "probability": 0.97900390625}, {"start": 689.28, "end": 689.54, "word": " يصل", "probability": 0.944580078125}, {"start": 689.54, "end": 689.96, "word": " تمانية", "probability": 0.86279296875}, {"start": 689.96, "end": 690.3, "word": " بيحمل", "probability": 0.8658447265625}, {"start": 690.3, "end": 690.82, "word": " hydride", "probability": 0.8984375}, {"start": 690.82, "end": 691.36, "word": " زايدة", "probability": 0.983154296875}, {"start": 691.36, "end": 691.86, "word": " لما", "probability": 0.91064453125}, {"start": 691.86, "end": 692.6, "word": " بفقدها", "probability": 0.88037109375}, {"start": 692.6, "end": 692.9, "word": " هذه", "probability": 0.416259765625}, {"start": 692.9, "end": 693.0, "word": " ال", "probability": 0.90673828125}, {"start": 693.0, "end": 693.5, "word": " hydride", "probability": 0.933837890625}, {"start": 693.5, "end": 694.22, "word": " زيادة", "probability": 0.88623046875}], "temperature": 1.0}, {"id": 29, "seek": 72365, "start": 695.33, "end": 723.65, "text": "بيجي بيعمل addition reaction فبيتحول ال الديهيد إلى ال primary alcohol بلاحظين انتوا ال الديهيد صار اي نوع من ال alcohol primary ال الديهيد لما تطلع ICH2 ال primary alcohol بعد شوية لما بنيجي نعمل reduction لل ketone", "tokens": [3555, 1829, 7435, 1829, 4724, 1829, 25957, 1211, 4500, 5480, 6156, 21292, 2655, 5016, 12610, 2423, 2423, 16254, 3224, 25708, 30731, 2423, 6194, 7658, 4724, 15040, 5016, 19913, 9957, 16472, 2655, 14407, 2423, 2423, 16254, 3224, 25708, 20328, 9640, 1975, 1829, 8717, 45367, 9154, 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"probability": 0.5283203125}, {"start": 704.55, "end": 705.95, "word": " ال", "probability": 0.6015625}, {"start": 705.95, "end": 706.47, "word": " primary", "probability": 0.488525390625}, {"start": 706.47, "end": 707.61, "word": " alcohol", "probability": 0.84375}, {"start": 707.61, "end": 709.47, "word": " بلاحظين", "probability": 0.7572265625}, {"start": 709.47, "end": 709.77, "word": " انتوا", "probability": 0.6373697916666666}, {"start": 709.77, "end": 709.87, "word": " ال", "probability": 0.99365234375}, {"start": 709.87, "end": 710.33, "word": " الديهيد", "probability": 0.9542236328125}, {"start": 710.33, "end": 710.61, "word": " صار", "probability": 0.943603515625}, {"start": 710.61, "end": 710.83, "word": " اي", "probability": 0.693115234375}, {"start": 710.83, "end": 711.01, "word": " نوع", "probability": 0.99658203125}, {"start": 711.01, "end": 711.23, "word": " من", "probability": 0.98974609375}, {"start": 711.23, "end": 711.39, "word": " ال", "probability": 0.9716796875}, 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"probability": 0.187255859375}, {"start": 2437.44, "end": 2437.88, "word": " bond", "probability": 0.8828125}, {"start": 2437.88, "end": 2438.58, "word": " OH", "probability": 0.479248046875}, {"start": 2438.58, "end": 2441.64, "word": " كيف", "probability": 0.881103515625}, {"start": 2441.64, "end": 2442.52, "word": " هتعملوه", "probability": 0.7896321614583334}, {"start": 2442.52, "end": 2444.64, "word": " هذي", "probability": 0.3736165364583333}, {"start": 2444.64, "end": 2445.06, "word": " بده", "probability": 0.51513671875}, {"start": 2445.06, "end": 2445.5, "word": " تاجم", "probability": 0.8811848958333334}, {"start": 2445.5, "end": 2445.84, "word": " هنا", "probability": 0.50048828125}, {"start": 2445.84, "end": 2447.62, "word": " و", "probability": 0.6220703125}, {"start": 2447.62, "end": 2448.06, "word": " ال", "probability": 0.5517578125}, {"start": 2448.06, "end": 2448.22, "word": " O", "probability": 0.69091796875}, {"start": 2448.22, "end": 2448.5, "word": " بده", "probability": 0.814453125}, {"start": 2448.5, "end": 2448.92, "word": " تصير", "probability": 0.9591471354166666}, {"start": 2448.92, "end": 2449.8, "word": " OH", "probability": 0.8134765625}, {"start": 2449.8, "end": 2450.38, "word": " فقط", "probability": 0.984130859375}, {"start": 2450.38, "end": 2450.96, "word": " مجرد", "probability": 0.9317626953125}, {"start": 2450.96, "end": 2451.78, "word": " انكوا", "probability": 0.6253255208333334}, {"start": 2451.78, "end": 2452.1, "word": " تجيبوا", "probability": 0.87919921875}, {"start": 2452.1, "end": 2452.44, "word": " هذي", "probability": 0.7605794270833334}, {"start": 2452.44, "end": 2452.76, "word": " هنا", "probability": 0.63916015625}, {"start": 2452.76, "end": 2453.18, "word": " و", "probability": 0.78759765625}, {"start": 2453.18, "end": 2453.42, "word": " هذي", "probability": 0.9298502604166666}, {"start": 2453.42, "end": 2454.18, "word": " بتخلوها", "probability": 0.92392578125}, {"start": 2454.18, "end": 2455.68, "word": " OH", "probability": 0.4677734375}, {"start": 2455.68, "end": 2456.06, "word": " هنا", "probability": 0.309326171875}, {"start": 2456.06, "end": 2457.98, "word": " و", "probability": 0.404052734375}, {"start": 2457.98, "end": 2458.66, "word": " رسموه", "probability": 0.8544921875}], "temperature": 1.0}, {"id": 96, "seek": 246780, "start": 2459.58, "end": 2467.8, "text": "طبعا أنا بصير جديش عندكم القدرة أنه بجلم لرصاص تلسخه الأشياء زي ما هي ترسموها مش أكتر، واضح؟", "tokens": [9566, 3555, 3615, 995, 41850, 4724, 9381, 13546, 10874, 16254, 8592, 43242, 24793, 25062, 3215, 25720, 14739, 3224, 4724, 7435, 19528, 5296, 2288, 9381, 33546, 6055, 1211, 3794, 9778, 3224, 16247, 8592, 1829, 16606, 30767, 1829, 19446, 39896, 6055, 2288, 38251, 2407, 11296, 37893, 5551, 4117, 2655, 2288, 12399, 4032, 46958, 5016, 22807], "avg_logprob": -0.1668113417647503, "compression_ratio": 1.3688524590163935, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2459.58, "end": 2459.98, "word": "طبعا", "probability": 0.952392578125}, {"start": 2459.98, "end": 2460.14, "word": " أنا", "probability": 0.54638671875}, {"start": 2460.14, "end": 2460.62, "word": " بصير", "probability": 0.9576822916666666}, {"start": 2460.62, "end": 2461.92, "word": " جديش", "probability": 0.7322591145833334}, {"start": 2461.92, "end": 2462.3, "word": " عندكم", "probability": 0.9833984375}, {"start": 2462.3, "end": 2462.86, "word": " القدرة", "probability": 0.9733072916666666}, {"start": 2462.86, "end": 2463.12, "word": " أنه", "probability": 0.7021484375}, {"start": 2463.12, "end": 2463.42, "word": " بجلم", "probability": 0.8570963541666666}, {"start": 2463.42, "end": 2463.96, "word": " لرصاص", "probability": 0.79296875}, {"start": 2463.96, "end": 2464.46, "word": " تلسخه", "probability": 0.7857421875}, {"start": 2464.46, "end": 2464.84, "word": " الأشياء", "probability": 0.970947265625}, {"start": 2464.84, "end": 2465.08, "word": " زي", "probability": 0.948974609375}, {"start": 2465.08, "end": 2465.14, "word": " ما", "probability": 0.96142578125}, {"start": 2465.14, "end": 2465.3, "word": " هي", "probability": 0.875}, {"start": 2465.3, "end": 2465.92, "word": " ترسموها", "probability": 0.93037109375}, {"start": 2465.92, "end": 2466.12, "word": " مش", "probability": 0.66552734375}, {"start": 2466.12, "end": 2467.24, "word": " أكتر،", "probability": 0.820166015625}, {"start": 2467.24, "end": 2467.8, "word": " واضح؟", "probability": 0.9559326171875}], "temperature": 1.0}, {"id": 97, "seek": 249316, "start": 2469.6, "end": 2493.16, "text": "فزي ما بتلاحظوا لما انا من محاضرتين قلتلكوا انه في ال الديهيدس والكيتونز كل الشغل اللي عندكوا تطبيق وقاعد انا بدور محاضرتين كاملين حوالي الفكرة واحدة انه زوج إلكترونات بيهاجم على ال C double bond O و بيحولها إلى OH مازدناش عن هذه الفكرة لكن ايش عملنا؟", "tokens": [5172, 11622, 1829, 19446, 39894, 15040, 5016, 19913, 14407, 5296, 15042, 1975, 8315, 9154, 3714, 5016, 46958, 43500, 9957, 12174, 1211, 2655, 23275, 14407, 16472, 3224, 8978, 2423, 2423, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 11622, 28242, 25124, 17082, 1211, 13672, 1829, 43242, 4117, 14407, 6055, 9566, 21292, 4587, 4032, 4587, 995, 22488, 1975, 8315, 47525, 13063, 3714, 5016, 46958, 43500, 9957, 9122, 10943, 1211, 9957, 11331, 2407, 6027, 1829, 27188, 4117, 25720, 36764, 24401, 3660, 16472, 3224, 30767, 29245, 11933, 23275, 2655, 2288, 11536, 9307, 4724, 1829, 3224, 26108, 2304, 15844, 2423, 383, 3834, 6086, 422, 4032, 4724, 1829, 5016, 12610, 11296, 30731, 13931, 19446, 11622, 3215, 1863, 33599, 18871, 29538, 27188, 4117, 25720, 44381, 1975, 1829, 8592, 6225, 42213, 8315, 22807], "avg_logprob": -0.19072420481178495, "compression_ratio": 1.7894736842105263, "no_speech_prob": 0.0, "words": [{"start": 2469.6, "end": 2470.52, "word": "فزي", "probability": 0.6888834635416666}, {"start": 2470.52, "end": 2470.62, "word": " ما", "probability": 0.970703125}, {"start": 2470.62, "end": 2471.36, "word": " بتلاحظوا", "probability": 0.94970703125}, {"start": 2471.36, "end": 2471.52, "word": " لما", "probability": 0.7568359375}, {"start": 2471.52, "end": 2471.74, "word": " انا", "probability": 0.6590576171875}, {"start": 2471.74, "end": 2471.92, "word": " من", "probability": 0.95166015625}, {"start": 2471.92, "end": 2472.72, "word": " محاضرتين", "probability": 0.95830078125}, {"start": 2472.72, "end": 2473.28, "word": " قلتلكوا", "probability": 0.9224609375}, {"start": 2473.28, "end": 2473.52, "word": " انه", "probability": 0.8330078125}, {"start": 2473.52, "end": 2473.64, "word": " في", "probability": 0.8642578125}, {"start": 2473.64, "end": 2473.74, "word": " ال", "probability": 0.974609375}, {"start": 2473.74, "end": 2474.36, "word": " الديهيدس", "probability": 0.681201171875}, {"start": 2474.36, "end": 2475.3, "word": " والكيتونز", "probability": 0.81396484375}, {"start": 2475.3, "end": 2476.12, "word": " كل", "probability": 0.89111328125}, {"start": 2476.12, "end": 2476.64, "word": " الشغل", "probability": 0.9899088541666666}, {"start": 2476.64, "end": 2476.78, "word": " اللي", "probability": 0.908935546875}, {"start": 2476.78, "end": 2477.16, "word": " عندكوا", "probability": 0.78955078125}, {"start": 2477.16, "end": 2477.88, "word": " تطبيق", "probability": 0.9725341796875}, {"start": 2477.88, "end": 2478.72, "word": " وقاعد", "probability": 0.8138427734375}, {"start": 2478.72, "end": 2479.0, "word": " انا", "probability": 0.850341796875}, {"start": 2479.0, "end": 2479.64, "word": " بدور", "probability": 0.933349609375}, {"start": 2479.64, "end": 2480.82, "word": " محاضرتين", "probability": 0.9916015625}, {"start": 2480.82, "end": 2481.38, "word": " كاملين", "probability": 0.9222412109375}, {"start": 2481.38, "end": 2481.82, "word": " حوالي", "probability": 0.9224853515625}, {"start": 2481.82, "end": 2482.3, "word": " الفكرة", "probability": 0.9913736979166666}, {"start": 2482.3, "end": 2483.04, "word": " واحدة", "probability": 0.9856770833333334}, {"start": 2483.04, "end": 2483.7, "word": " انه", "probability": 0.6209716796875}, {"start": 2483.7, "end": 2483.98, "word": " زوج", "probability": 0.974365234375}, {"start": 2483.98, "end": 2484.98, "word": " إلكترونات", "probability": 0.8255411783854166}, {"start": 2484.98, "end": 2485.64, "word": " بيهاجم", "probability": 0.9138671875}, {"start": 2485.64, "end": 2485.88, "word": " على", "probability": 0.685546875}, {"start": 2485.88, "end": 2485.92, "word": " ال", "probability": 0.85986328125}, {"start": 2485.92, "end": 2486.04, "word": " C", "probability": 0.285888671875}, {"start": 2486.04, "end": 2486.22, "word": " double", "probability": 0.33154296875}, {"start": 2486.22, "end": 2486.6, "word": " bond", "probability": 0.95458984375}, {"start": 2486.6, "end": 2486.78, "word": " O", "probability": 0.90283203125}, {"start": 2486.78, "end": 2486.92, "word": " و", "probability": 0.57861328125}, {"start": 2486.92, "end": 2487.6, "word": " بيحولها", "probability": 0.865234375}, {"start": 2487.6, "end": 2488.3, "word": " إلى", "probability": 0.55859375}, {"start": 2488.3, "end": 2488.78, "word": " OH", "probability": 0.49755859375}, {"start": 2488.78, "end": 2490.28, "word": " مازدناش", "probability": 0.75439453125}, {"start": 2490.28, "end": 2490.52, "word": " عن", "probability": 0.98583984375}, {"start": 2490.52, "end": 2490.86, "word": " هذه", "probability": 0.916015625}, {"start": 2490.86, "end": 2491.52, "word": " الفكرة", "probability": 0.9962565104166666}, {"start": 2491.52, "end": 2492.16, "word": " لكن", "probability": 0.7666015625}, {"start": 2492.16, "end": 2492.46, "word": " ايش", "probability": 0.7913411458333334}, {"start": 2492.46, "end": 2493.16, "word": " عملنا؟", "probability": 0.9136962890625}], "temperature": 1.0}, {"id": 98, "seek": 250339, "start": 2494.19, "end": 2503.39, "text": "عملنا أمثلة تطبيقية كتيرة بنجح عند موضوع الـ oxidation of aldehydes and keto", "tokens": [25957, 1211, 8315, 5551, 2304, 12984, 37977, 6055, 9566, 21292, 4587, 10632, 9122, 2655, 48923, 44945, 7435, 5016, 43242, 3714, 2407, 11242, 45367, 2423, 39184, 36767, 295, 16798, 68, 3495, 14792, 293, 44299], "avg_logprob": -0.24977020656361298, "compression_ratio": 1.018018018018018, "no_speech_prob": 0.0, "words": [{"start": 2494.19, "end": 2494.75, "word": "عملنا", "probability": 0.791748046875}, {"start": 2494.75, "end": 2495.25, "word": " أمثلة", "probability": 0.9248046875}, {"start": 2495.25, "end": 2496.11, "word": " تطبيقية", "probability": 0.9650390625}, {"start": 2496.11, "end": 2497.07, "word": " كتيرة", "probability": 0.6611328125}, {"start": 2497.07, "end": 2497.93, "word": " بنجح", "probability": 0.490234375}, {"start": 2497.93, "end": 2498.27, "word": " عند", "probability": 0.88916015625}, {"start": 2498.27, "end": 2498.95, "word": " موضوع", "probability": 0.9837646484375}, {"start": 2498.95, "end": 2499.43, "word": " الـ", "probability": 0.5181884765625}, {"start": 2499.43, "end": 2499.87, "word": " oxidation", "probability": 0.6455078125}, {"start": 2499.87, "end": 2500.75, "word": " of", "probability": 0.9482421875}, {"start": 2500.75, "end": 2501.75, "word": " aldehydes", "probability": 0.8404541015625}, {"start": 2501.75, "end": 2502.27, "word": " and", "probability": 0.908203125}, {"start": 2502.27, "end": 2503.39, "word": " keto", "probability": 0.80224609375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2503.48275, "duration_after_vad": 2358.491249999992}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..45d9c0b1b7fb930de5c0aeeee6de1c2bdb605ca0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_raw.srt
@@ -0,0 +1,1848 @@
+1
+00:00:05,670 --> 00:00:13,010
+ما زلنا في موضوع تفاعلات الإضافة للـ aldehydes و
+
+2
+00:00:13,010 --> 00:00:17,250
+الـ ketones هذا الحقيقة التفاعل اللي لان بده يمر
+
+3
+00:00:17,250 --> 00:00:22,990
+علينا هو تفاعل ham
+
+4
+00:00:24,030 --> 00:00:28,550
+السوديوم الهيدروجين السلفيت للألديهيد والكيتون
+
+5
+00:00:28,550 --> 00:00:33,670
+طبعا السوديوم الهيدروجين السلفيت في النهاية
+
+6
+00:00:33,670 --> 00:00:40,330
+بيتفاعل مع سواء الألديهيد أو الكيتون هذا ألديهيد
+
+7
+00:00:40,330 --> 00:00:45,250
+وهذا كيتون زي ما انتوا شايفين من خلال السلفر اللي
+
+8
+00:00:45,250 --> 00:00:50,310
+موجود هنا بيصير عندنا رابطة S double bond O double
+
+9
+00:00:50,310 --> 00:00:57,590
+bond OO-NA+, بناءً على ذلك هو بيعطينا solved يعني
+
+10
+00:00:57,590 --> 00:01:03,050
+هذه الـ S O 3 minus NA plus هي عبارة عن هذا الشكل
+
+11
+00:01:03,050 --> 00:01:08,770
+S double bond O double bond O O minus NA plus
+
+12
+00:01:08,770 --> 00:01:15,950
+واضح؟ هي تفصيلها زي ما بتلاحظوا ان هذا المركب ان
+
+13
+00:01:15,950 --> 00:01:23,970
+هذا المركب الناتج هو عبارة عنIonic compound يعني
+
+14
+00:01:23,970 --> 00:01:30,050
+plus و minus عبارة عن ions وبناء على ذلك هذا
+
+15
+00:01:30,050 --> 00:01:35,430
+المركب الايوني بيكون عادة بدوب في الميه
+
+16
+00:01:38,750 --> 00:01:44,830
+نتطلع على ال .. طبعا ال .. ال lower aldehydes و
+
+17
+00:01:44,830 --> 00:01:48,670
+ketones زي ال acetaldehyde و زي ال acetone هدول
+
+18
+00:01:48,670 --> 00:01:52,630
+بدوبوا في الميه، لكن السؤال لو ال aldehyde كبر صار
+
+19
+00:01:52,630 --> 00:01:58,390
+خمس درات كربون، بيبطل يدوب في الميهالان فائدة هذا
+
+20
+00:01:58,390 --> 00:02:03,330
+التفاعل حقيقة انه بيستعمل في عملية تنقية ال
+
+21
+00:02:03,330 --> 00:02:07,630
+الديهيد والكيتون يعني هذا ال الديهيد او ال كيتون
+
+22
+00:02:07,630 --> 00:02:14,330
+خلينا نقول organic مركب أطوىو موجود مع أشياء تانية
+
+23
+00:02:14,330 --> 00:02:19,850
+كلها مخلوطة مع بعض مع organic compounds مخلوطين مع
+
+24
+00:02:19,850 --> 00:02:23,690
+بعض واضح أنا لما بفعله مع ال sodium hydrogen
+
+25
+00:02:23,690 --> 00:02:29,290
+sulfide هذا بحوله إلى salt ال salt بيكون بدوب في
+
+26
+00:02:29,290 --> 00:02:34,190
+الميه باقى المركبات بتظهر في ال solvent ال organic
+
+27
+00:02:34,190 --> 00:02:41,130
+باخد الميهوبعاود أضيف عليها base .. برجع للالدهايد
+
+28
+00:02:41,130 --> 00:02:46,610
+أو الكيتون النقي واضحة الفكرة؟ مرة تانية بيكون عند
+
+29
+00:02:46,610 --> 00:02:51,290
+أنا الالدهايد والكيتون مع other organic compounds
+
+30
+00:02:51,290 --> 00:02:57,310
+كيف بدي أنقيه، أفصله لوحده؟ الآن الالدهايد أو
+
+31
+00:02:57,310 --> 00:03:00,530
+الكيتون بتفاعل مع ال sodium hydrogen sulfide
+
+32
+00:03:00,530 --> 00:03:04,750
+وبيعطيني ionic compound هذا ال ionic compound إيش
+
+33
+00:03:04,750 --> 00:03:10,600
+إحنا بيقول عنه؟ water؟سوليومن بناء على ذلك أنا
+
+34
+00:03:10,600 --> 00:03:16,920
+باخد طبقة الميه بيكون بس اللي دايب فيها هذا المركب
+
+35
+00:03:16,920 --> 00:03:19,520
+اللي نشعل الدايد والكيتون باقي ال organic
+
+36
+00:03:19,520 --> 00:03:23,100
+compounds ال impurities كلها بتكون في ال organic
+
+37
+00:03:23,100 --> 00:03:27,440
+layer مابديش إياها باخد الميه بضيف عليها شوية base
+
+38
+00:03:28,120 --> 00:03:33,660
+أو أسد فبصير التفاعل العكسي برجع هذا بتكون و برجع
+
+39
+00:03:33,660 --> 00:03:37,960
+ال الديهيد والكيتون بتكون ك organic compound نقي
+
+40
+00:03:37,960 --> 00:03:42,740
+فهذه الطريقة اللي هي طريقة إضافة ال sodium
+
+41
+00:03:42,740 --> 00:03:48,040
+hydrogen sulfide is a method to purify الديهيد و
+
+42
+00:03:48,040 --> 00:03:53,830
+الكيتون by changing them toIonic compounds water
+
+43
+00:03:53,830 --> 00:03:58,850
+soluble Ionic compounds بناخد الميه بس بيكون فيها
+
+44
+00:03:58,850 --> 00:04:04,110
+مركب ال الديهايد او ال كيتون على شكل ايون بعدين
+
+45
+00:04:04,110 --> 00:04:09,390
+بتفاعل عكسي برجع ل الديهايد و كيتون نقي واضح هذه
+
+46
+00:04:09,390 --> 00:04:16,330
+قصة يعني تطبيقيةالأساس فيها اللي هو addition يعني
+
+47
+00:04:16,330 --> 00:04:19,810
+هنا في النهاية برضه اللي صار عملية addition هيكوا
+
+48
+00:04:19,810 --> 00:04:23,190
+شايفين ال nucleophile و السيدة و البندقش و سارة
+
+49
+00:04:23,190 --> 00:04:27,410
+الاساس فيها عملية addition
+
+50
+00:04:35,920 --> 00:04:42,080
+بعد هيك .. بعد هيك بنيجي لنوع تاني .. لنوع تاني من
+
+51
+00:04:42,080 --> 00:04:47,700
+تفاعلات ال الديهيدس والكيتونز طبعا ال الديهيدس
+
+52
+00:04:47,700 --> 00:04:52,720
+والكيتونز احنا بنقدر نعتبرهم مثل البني آدم اللي
+
+53
+00:04:52,720 --> 00:04:58,080
+واقف على نص الدرج واضح؟ يعني لو في عندنا درج معين
+
+54
+00:04:58,080 --> 00:05:02,060
+وفي بني آدم واقف على نص الدرج شو الاحتمالات اللي
+
+55
+00:05:02,060 --> 00:05:08,300
+عنده؟ اللي يطلع لفوق؟أو ينزل لتحت الان ايش قصته
+
+56
+00:05:08,300 --> 00:05:13,720
+هذا الدرج و ان ال aldehyde و ال ketone واقف على نص
+
+57
+00:05:13,720 --> 00:05:18,880
+الدرج هذا قصته بتجيني في موضوع الأكسدة و الاختزال
+
+58
+00:05:18,880 --> 00:05:25,520
+لما انا بحكي بقول في عندى alcohol R O H و في عندى
+
+59
+00:05:25,520 --> 00:05:28,960
+بعد هيك ال aldehydes و ال ketones اللي هم ال R C
+
+60
+00:05:28,960 --> 00:05:36,190
+double bond O H و ال R C double bond O Rواضح هذا
+
+61
+00:05:36,190 --> 00:05:41,970
+الكهول وهذا الديهايد وكيتون بعد ذلك يأتي ال R-C-O
+
+62
+00:05:41,970 --> 00:05:50,770
+-H الاسد الآن هذولا التلاتة احنا بنقدر نتحرك بينهم
+
+63
+00:05:50,770 --> 00:05:55,030
+وسبق مر علينا هذا الكلام من خلال عمليات الأكسدة
+
+64
+00:05:55,030 --> 00:05:59,610
+والاختزال بمعنى الالكهول انا ممكن اعمله oxidation
+
+65
+00:05:59,610 --> 00:06:03,950
+يصير الديهايد الديهايد ممكن اعمله oxidation
+
+66
+00:06:06,470 --> 00:06:11,510
+الاسد ممكن اعمله reduction يرجع الديهيد ممكن اعمله
+
+67
+00:06:11,510 --> 00:06:16,850
+reduction يرجع الكول لما بقاجي انا هنا للديهيد
+
+68
+00:06:16,850 --> 00:06:21,830
+والكيتون موجودين في نص الطريق بمعنى ممكن انا اعمل
+
+69
+00:06:21,830 --> 00:06:28,140
+عملية reduction اختزانبيرجع ال الديهايد في الكيتون
+
+70
+00:06:28,140 --> 00:06:32,700
+لالكهولز و ممكن اعمل لهم oxidation لل الديهايد من
+
+71
+00:06:32,700 --> 00:06:37,020
+اللي الكيتون مابتأكسدش لل الديهايد بيصير ايش؟ acid
+
+72
+00:06:37,020 --> 00:06:40,800
+هذه العملية oxidation واضح؟
+
+73
+00:06:43,500 --> 00:06:48,760
+إذا كأنه ال الديهيد اللي بنص الطريق أو بنعنو بنص
+
+74
+00:06:48,760 --> 00:06:54,640
+الدرج ممكن أنزل فيه أرجعه لالكهول و ممكن أعمله
+
+75
+00:06:54,640 --> 00:06:59,940
+أكسدة و يصير حامض و لذلك هدول التفاعلين بدنا
+
+76
+00:06:59,940 --> 00:07:04,880
+ندرسهم و نركز عليهم اللي هم reduction of aldehydes
+
+77
+00:07:04,880 --> 00:07:10,800
+و oxidation of aldehydes لإن هم جايين وين؟في نص
+
+78
+00:07:10,800 --> 00:07:14,920
+الطريق طبعا في عندى كمان reduction of ketones بس
+
+79
+00:07:14,920 --> 00:07:18,400
+مافيش عنده oxidation of ketones الكيتونز
+
+80
+00:07:18,400 --> 00:07:23,880
+مابتتأكسدش لحمض لكن اللي بتأكسد ال الديهايد واضح؟
+
+81
+00:07:23,880 --> 00:07:29,860
+عشان مافيش فيها H الكيتون الآن شو العوامل المؤكسدة
+
+82
+00:07:29,860 --> 00:07:33,960
+والمختزلة اللي بدها تدرس؟ أول اشي بندرس عملية
+
+83
+00:07:35,390 --> 00:07:43,690
+الاختزال اول اشهر العوامل المختزلة العاملين هدولة
+
+84
+00:07:43,690 --> 00:07:48,250
+اللي موجودين هنا اللي هم الليثيوم مع الالومنيوم و
+
+85
+00:07:48,250 --> 00:07:53,250
+4 ذرات هيدروجين على شكل هيدرايد فبسموه lithium
+
+86
+00:07:53,250 --> 00:07:56,450
+tetrahydroaluminate
+
+87
+00:07:56,940 --> 00:08:02,560
+الحقيقة بصراحة هذا الاسم يمكن مش كتير مستعمل في
+
+88
+00:08:02,560 --> 00:08:06,040
+اسم تاني أكثر شهرة و أكثر استعمالي يعني خلّيني
+
+89
+00:08:06,040 --> 00:08:08,580
+أقول يمكن عشرة في المية من الناس بيحكوا بهذا
+
+90
+00:08:08,580 --> 00:08:13,600
+الطريقة و الباقي بيقولوا عنه Lithium Aluminum
+
+91
+00:08:13,600 --> 00:08:18,460
+Hydride واضح؟ يعني هذا سواء شفتوا بهذا الاسم أو
+
+92
+00:08:18,460 --> 00:08:26,140
+بالاسم الأشهر Lithium Aluminum Hydride
+
+93
+00:08:26,570 --> 00:08:33,370
+هذا عبارة عن عامل مختصر و العامل التاني اللي كثير
+
+94
+00:08:33,370 --> 00:08:37,470
+الاستعمال برضه اللي هو ال sodium tetrahydride و
+
+95
+00:08:37,470 --> 00:08:44,130
+borate برضه هذا بيسموه sodium borohydride
+
+96
+00:08:44,130 --> 00:08:50,090
+sodium borohydride لما أنا كنت اسمع تانية مايعرفش
+
+97
+00:08:50,090 --> 00:08:52,990
+حوالين اللي ألقاني و مصر مايعرفش أكملت هدروجين
+
+98
+00:08:52,990 --> 00:08:58,890
+بالتحديدبظبط لكن في النهاية اسم شهرة يعني لما ينقل
+
+99
+00:08:58,890 --> 00:09:05,130
+lithium aluminium hydride صح مش مبين بس خبرة الناس
+
+100
+00:09:05,130 --> 00:09:11,110
+انه lithium AlH4 واضح؟ و لما بنقول sodium
+
+101
+00:09:11,110 --> 00:09:20,200
+borohydride NaBH4 واضح؟فسواء شفته بهذا الإسم أو
+
+102
+00:09:20,200 --> 00:09:25,560
+شفته بهذا الإسم هدولة هما أشهر العوامل المختزلة
+
+103
+00:09:25,560 --> 00:09:31,280
+اللي تستعمل لاختزال ال الديهيد والكيتون واضح؟ الآن
+
+104
+00:09:31,280 --> 00:09:35,740
+اللي بيصير عندي ببساطة لو أنا أخدت مثلا ال
+
+105
+00:09:35,740 --> 00:09:40,800
+acetaldehydeفعلته مع hydride لحظة انا حاطط اتنين
+
+106
+00:09:40,800 --> 00:09:43,900
+وبين جثين ال H اللي هي ال hydride اكيد انتوا
+
+107
+00:09:43,900 --> 00:09:48,060
+بتميزوا كلمة hydride عن ال proton ال hydride ايش
+
+108
+00:09:48,060 --> 00:09:53,660
+معناها H minus ال proton H plus مرة تانية بنذكر
+
+109
+00:09:53,660 --> 00:10:00,140
+فيها ال H plus ايش اسمها ال proton و ال H minus
+
+110
+00:10:05,660 --> 00:10:14,120
+هنا التفاعل ببساطة هو عبارة عن تفاعل addition و لو
+
+111
+00:10:14,120 --> 00:10:18,340
+احنا ماخدينه تحت عنوان reduction of aldehydes and
+
+112
+00:10:18,340 --> 00:10:23,220
+ketones انا في عندي ببساطة H مع أزواج إلكتروناد
+
+113
+00:10:23,220 --> 00:10:27,900
+يعني H minus الآن هذه عبارة عن النيوكليوفايل وهي
+
+114
+00:10:27,900 --> 00:10:31,920
+الـC double bond O شو التفاعل المتوقع؟ ان هذا
+
+115
+00:10:31,920 --> 00:10:37,890
+النيوكليوفايل بده نهاجم وهذهتصير OH واضح نفس
+
+116
+00:10:37,890 --> 00:10:41,770
+الكلام اللي كنا نحكيه المرة الماضية ان هاي ال
+
+117
+00:10:41,770 --> 00:10:46,870
+nucleophile و هاي ال C double bond O صارت OH
+
+118
+00:10:46,870 --> 00:10:54,590
+فحقيقة ضمن هذا المبدأ بتكون عملية ال reduction of
+
+119
+00:10:54,590 --> 00:10:58,770
+aldehydes and ketones using sodium or sodium
+
+120
+00:10:58,770 --> 00:11:01,950
+borohydride or lithium aluminum hydride is an
+
+121
+00:11:01,950 --> 00:11:07,340
+addition reactionفي محصلة هو addition reaction و
+
+122
+00:11:07,340 --> 00:11:13,000
+ال nucleophile is the hydride anion ال nucleophile
+
+123
+00:11:13,000 --> 00:11:19,260
+is the hydride anion واضح؟ طبعا ال hydride anion
+
+124
+00:11:19,260 --> 00:11:24,160
+لأنه ببساطة الألمنيوم بشكل عام بيكون حامل hydride
+
+125
+00:11:24,160 --> 00:11:28,500
+زايدة الألمنيوم عادة بيكون حامل تلت روابط بستة
+
+126
+00:11:28,500 --> 00:11:32,900
+عشان يصل تمانية بيحمل hydride زايدة لما بفقدها هذه
+
+127
+00:11:32,900 --> 00:11:38,930
+ال hydride زيادةبيجي بيعمل addition reaction
+
+128
+00:11:38,930 --> 00:11:49,470
+فبيتحول ال الديهيد إلى ال primary alcohol بلاحظين
+
+129
+00:11:49,470 --> 00:11:53,070
+انتوا ال الديهيد صار اي نوع من ال alcohol primary
+
+130
+00:11:53,070 --> 00:11:59,370
+ال الديهيد لما تطلع ICH2 ال primary alcohol بعد
+
+131
+00:11:59,370 --> 00:12:06,030
+شوية لما بنيجي نعمل reduction لل ketoneبيصير
+
+132
+00:12:06,030 --> 00:12:11,310
+بإمكانكم تتطلعوا هنا هي الكيتون و إجت ال H هاجمت و
+
+133
+00:12:11,310 --> 00:12:16,830
+صار عنده هي ال nucleophile و هي ال OH صار عنده
+
+134
+00:12:16,830 --> 00:12:21,330
+secondary alcohol إذا هذه من الجملة اللي أنتوا
+
+135
+00:12:21,330 --> 00:12:27,370
+بدكم تكونوا عارفينها أنه بال reduction بال
+
+136
+00:12:27,370 --> 00:12:33,710
+reduction ال aldehyde شو بده يصير ال primary
+
+137
+00:12:33,710 --> 00:12:34,250
+alcohol
+
+138
+00:12:38,420 --> 00:12:44,820
+بتصير secondary واضحة هذه النقطة هاي اللي هي عملية
+
+139
+00:12:44,820 --> 00:12:51,440
+ال reduction انا بقيالي مش عملية صعبة الكلام فيها
+
+140
+00:12:51,440 --> 00:12:56,340
+واضح بالذات اذا احنا بنفهمها ان هي عملية addition
+
+141
+00:12:56,340 --> 00:13:01,120
+of a hydride انا يعني بطلت مختلفة عن كل عمليات ال
+
+142
+00:13:01,120 --> 00:13:05,220
+additions السابقة مش مختلفة عن عمليات ال additions
+
+143
+00:13:05,220 --> 00:13:12,960
+السابقةطبعا هنا ممكن احاول اعمللكم ايش ال
+
+144
+00:13:12,960 --> 00:13:17,400
+mechanism ايش ال mechanism of addition مش كتير
+
+145
+00:13:17,400 --> 00:13:23,500
+بصراحة بهم عندى انه نتطلع عليها لكن لو بتطلعوا
+
+146
+00:13:23,500 --> 00:13:28,700
+الاساس فيها ان انتوا بتجيبوا ايون هيدرايد و تخلوه
+
+147
+00:13:28,700 --> 00:13:34,670
+اهاجم واضح؟ مش كتير مهتمين في هذهنفس الشيء إذا
+
+148
+00:13:34,670 --> 00:13:40,410
+استعملنا الـ Sodium Borohydride المحصلة تماما نفس
+
+149
+00:13:40,410 --> 00:13:44,810
+الشيء تماما، واضح؟ يعني سواء قلنا Lithium Aluminum
+
+150
+00:13:44,810 --> 00:13:51,590
+Hydride أو Sodium Borohydride النتيجة واحدة إضافة
+
+151
+00:13:51,590 --> 00:13:57,530
+H minus وتحويل الـ C double bond O إلى OH أو أكثر
+
+152
+00:13:57,530 --> 00:14:02,890
+من هيك، مابلزمناشواضح؟ عشان انا لما بتيجوا
+
+153
+00:14:02,890 --> 00:14:07,070
+بتتطلعوا على أمثلة هاي Lithium Aluminum Hydride،
+
+154
+00:14:07,070 --> 00:14:09,850
+هاي Sodium Borohydride، هاي Sodium Borohydride،
+
+155
+00:14:09,850 --> 00:14:17,430
+هاي Lithium Aluminum Hydride، هاي
+
+156
+00:14:17,430 --> 00:14:17,750
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+157
+00:14:17,750 --> 00:14:19,050
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+158
+00:14:19,050 --> 00:14:21,050
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+159
+00:14:21,050 --> 00:14:21,570
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+160
+00:14:21,570 --> 00:14:21,610
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+161
+00:14:21,610 --> 00:14:22,010
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+162
+00:14:22,010 --> 00:14:25,650
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+163
+00:14:25,650 --> 00:14:30,450
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+164
+00:14:30,450 --> 00:14:30,450
+Sod
+
+165
+00:14:33,570 --> 00:14:38,070
+الكيتول صار secondary alcohol والالديهيد صار
+
+166
+00:14:38,070 --> 00:14:41,650
+primary alcohol والالديهيد اللي هان صار primary
+
+167
+00:14:41,650 --> 00:14:50,120
+alcoholطبعا .. ربما سهولة ال .. سهولة الكيميا وين
+
+168
+00:14:50,120 --> 00:14:55,720
+ان انتوا .. ايش ما بدوا يكبر الجزائع عندكم تكونوا
+
+169
+00:14:55,720 --> 00:14:59,520
+عارفين ان انتوا بتتعاملوا مع رأس للتفاعل يعني ايش
+
+170
+00:14:59,520 --> 00:15:03,380
+يكون المركب هنا .. هذا المركب هذا .. فيه اشي كتير
+
+171
+00:15:03,380 --> 00:15:08,020
+هنا .. كل هذا الكلام .. كل هذا الكلام بالنسبة لي
+
+172
+00:15:08,020 --> 00:15:13,120
+.. كل هذا الكلام بالنسبة لي هو يمثل عملية نسخ و
+
+173
+00:15:13,120 --> 00:15:13,520
+لاسخ
+
+174
+00:15:16,400 --> 00:15:20,580
+تلاحظون؟ كل هذا الكلام يمثل بالنسبة إلى عملية نسخ
+
+175
+00:15:20,580 --> 00:15:27,160
+و لصق لكن محور التفاعن الأساسي أنه .. أن هذه
+
+176
+00:15:27,160 --> 00:15:34,200
+المجموعة ستصبح CH2OH، فقط، خلّصنا الأن، إن شاء
+
+177
+00:15:34,200 --> 00:15:38,920
+الله بعد ذلك، هذه المجموعة نربطها بقطار هنا، ليس
+
+178
+00:15:38,920 --> 00:15:42,100
+لازم تخافوا من المسألة و تقولوا بيجينا سؤال في
+
+179
+00:15:42,100 --> 00:15:49,230
+جزيات معقدةواضح؟ هاي محور التفاعل هذا نفس الاشياء
+
+180
+00:15:49,230 --> 00:15:56,490
+لاحظوا مثلا حطلكم Cyclopropyl وحطلكم Methyl إيش ما
+
+181
+00:15:56,490 --> 00:15:59,730
+أحط و أحط ان شاء الله أحطون أشياء أنا عندي C
+
+182
+00:15:59,730 --> 00:16:04,690
+double bond O تبعت كيتون، هذا محور التفاعل، شو
+
+183
+00:16:04,690 --> 00:16:11,190
+بتصير؟ بتصير O H و بتجيل الـH من بره، باقي الأشياء
+
+184
+00:16:13,100 --> 00:16:20,020
+زي ما هي مش محور التفاعل يمكن بهذا التفاعل هانا
+
+185
+00:16:20,020 --> 00:16:25,620
+كان عامل Acetal هانا كان عامل Acetal وبإضافة الحمض
+
+186
+00:16:25,620 --> 00:16:33,580
+كسر ال Acetal كخطوة نهائية مش كثير مهم عندى هذه
+
+187
+00:16:33,580 --> 00:16:37,060
+الشغله لكن المهم برضه عندى هانا انها السيطه بال
+
+188
+00:16:37,060 --> 00:16:47,050
+bond OH هي محور التفاعل اللى صارتCH2OH واضح CH2OH
+
+189
+00:16:47,050 --> 00:16:53,130
+واضح هذا الاسيتال عادة بتنكسر في وجود الحمض في آخر
+
+190
+00:16:53,130 --> 00:17:01,170
+التفاعل مش الموضوع ها نفس الشيء ال CH2OH ال ketone
+
+191
+00:17:01,170 --> 00:17:08,240
+صارت CHالان لو كانت على حلقة خماسية او سوداسية او
+
+192
+00:17:08,240 --> 00:17:12,240
+سباعية او تمانية او حلقة كبيرة معجدة ايش ما كانت
+
+193
+00:17:12,240 --> 00:17:18,220
+تكون انا بيفرج عندى اه و هنا بيبدأ يصير انه ليش
+
+194
+00:17:18,220 --> 00:17:21,300
+بعض الناس بتعاملوا مع المعادلات الكيميائية بسهولة
+
+195
+00:17:21,300 --> 00:17:26,320
+و البعض مابتعاملش بسهولة اللي بيفهم المحور الأساسي
+
+196
+00:17:26,320 --> 00:17:30,590
+في السؤال هو اللي بتعامل بسهولةالمحور الأساسي أن
+
+197
+00:17:30,590 --> 00:17:35,570
+الكيميا عبارة عن قصة مجموعات وظيفية، يعني رؤوس
+
+198
+00:17:35,570 --> 00:17:41,050
+تتفاعل مع بعض، بس هذه الرؤوس، الآن باقي الأشياء
+
+199
+00:17:41,050 --> 00:17:46,410
+بتظهر زي ما هي، مابتصيرش فيها تغيير بشكل عام
+
+200
+00:17:59,610 --> 00:18:04,770
+بيجينا تفاعل إضافة جديد إحنا اتفقنا إن الـ
+
+201
+00:18:04,770 --> 00:18:10,930
+reduction في النهاية is an addition reaction تفاعل
+
+202
+00:18:10,930 --> 00:18:15,170
+كتير مهم اللي هو reaction with green yard reagent
+
+203
+00:18:15,170 --> 00:18:20,770
+تفاعل الألديهيدز والكيتونز مع green yard reagent
+
+204
+00:18:20,770 --> 00:18:26,750
+ربما البعض منكم ربما البعض منكم يكون نسي يكون نسي
+
+205
+00:18:26,750 --> 00:18:31,330
+ال green yard reagentمر علينا .. وين ال green يا
+
+206
+00:18:31,330 --> 00:18:37,430
+اردري ايه جد .. في chapter ال ethers .. في chapter
+
+207
+00:18:37,430 --> 00:18:43,710
+ال ethers احنا قلنا لما يكون عندنا RX انفعلها مع
+
+208
+00:18:43,710 --> 00:18:50,550
+ال MG في وجود ال dry ether بيعطينا R
+
+209
+00:19:00,220 --> 00:19:04,420
+مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس
+
+210
+00:19:04,420 --> 00:19:08,360
+مجيكس
+
+211
+00:19:08,360 --> 00:19:11,900
+مجيكس
+
+212
+00:19:11,900 --> 00:19:18,380
+مجيكس مجيكس مجيكسمن خلاله، فللـ Green Yard Reagent
+
+213
+00:19:18,380 --> 00:19:23,580
+عبارة عن R نيوكليوفايل في الآخر بس زم أنا قلت لـ
+
+214
+00:19:23,580 --> 00:19:27,100
+Green Yard Reagent هو R نيوكليوفايل إذا خلصنا شغل
+
+215
+00:19:27,100 --> 00:19:31,300
+بدي أخد أي ألديهيدوكيتون و أتخيل إن أنا بفعله مع R
+
+216
+00:19:31,300 --> 00:19:36,960
+مع أزواج الإلكترونات تبعتها طبعا هي بتكون مرتبطة
+
+217
+00:19:36,960 --> 00:19:46,150
+بالـ MgBr بس كتفاعل R مع أزواج الإلكتروناتمرة
+
+218
+00:19:46,150 --> 00:19:49,930
+تانية هذا عبارة عن ال addition reaction بهذا الشكل
+
+219
+00:19:49,930 --> 00:19:55,690
+و هذا بتصير OH في النهاية طبعا احنا بنضيف لغرينيا
+
+220
+00:19:55,690 --> 00:20:01,770
+و بعد هيك بنضيف له حامض مع ميه فالنهاية لما
+
+221
+00:20:01,770 --> 00:20:05,690
+بتكتيجوا تتطلعوا هنا هاي لغرينيا بفادل مثال عبارة
+
+222
+00:20:05,690 --> 00:20:13,940
+عن مجموعة إيش ال R اللي هنا CH3 CH2في النتج انها
+
+223
+00:20:13,940 --> 00:20:20,300
+هتشوفوا CH3 CH2 إجت كمجموعة و الـ CW bond O صارت
+
+224
+00:20:20,300 --> 00:20:26,140
+OH هم لاحظين هذا المستطيل و ال .. هاي ال addition
+
+225
+00:20:26,140 --> 00:20:31,260
+هذا ال nuclear file و هاي ال CW bond O صارت OH
+
+226
+00:20:31,260 --> 00:20:33,660
+واضح؟
+
+227
+00:20:37,040 --> 00:20:44,380
+التفاعل مع الادهايط و الكيتون هو اتفاعل اضافي طبعا
+
+228
+00:20:44,380 --> 00:20:48,880
+كتطبيق ليس أسهل منه نحضر الـR و نفعلها و نضع الـc
+
+229
+00:20:48,880 --> 00:20:54,600
+double bond O من خلّيها O H لكن متعودين احنا الآن
+
+230
+00:20:54,600 --> 00:21:00,700
+نميز النواتج اللي بتطلع متعودين نميز النواتج اللي
+
+231
+00:21:00,700 --> 00:21:03,000
+بتطلع وهذا الكلام هتشوفوه هنا
+
+232
+00:21:08,360 --> 00:21:14,260
+إنه هذا الـ Greenyard Reagent ممكن نفعله مع أبسط
+
+233
+00:21:14,260 --> 00:21:18,320
+الديهيد في الدنيا اللي هو الـ Formal Dehyde ممكن
+
+234
+00:21:18,320 --> 00:21:22,780
+نفعله مع أي الديهيد تاني غير الـ Formal Dehyde و
+
+235
+00:21:22,780 --> 00:21:27,620
+ممكن نفعله مع الـ Ketone واضح؟
+
+236
+00:21:29,380 --> 00:21:33,220
+طريقة التفاعل أنه بدأ تأتي من مجموعة أتجرنيار و
+
+237
+00:21:33,220 --> 00:21:39,000
+الـ CWbO تصير OH هذا كلام متفق عليه مافيش فيه أي
+
+238
+00:21:39,000 --> 00:21:42,520
+مشكلة يعني هنا لما استعملنا مجموعة الاثل هاي
+
+239
+00:21:42,520 --> 00:21:47,720
+مجموعة الاثل حطناها بصندوق و الـ CWbO صارت OH و
+
+240
+00:21:47,720 --> 00:21:51,200
+نفس الاشي مع الاسيتالديهيد الو الديهيد أكبر هاي
+
+241
+00:21:51,200 --> 00:21:56,450
+مجموعة الاثل و الـ CWbO صارتأو أتش وهنا مع
+
+242
+00:21:56,450 --> 00:22:00,350
+الاسيتون هاي مجموعة ال إفل و ال C double bond O
+
+243
+00:22:00,350 --> 00:22:06,070
+صارت أو أتش إذا أنا بحكي عن addition و نفسي
+
+244
+00:22:06,070 --> 00:22:12,510
+التفاعل لكن لما أجي أطلع على نوع الناتج لما أجي
+
+245
+00:22:12,510 --> 00:22:16,870
+أطلع على نوع الناتج بلاحظ أنه انا لو فعلت ال green
+
+246
+00:22:16,870 --> 00:22:21,790
+yard مع ال formal دي هادي بيطلع عندى primary
+
+247
+00:22:21,790 --> 00:22:29,930
+alcoholتطلع هذا CH2OH إذا الناتج هنا primary
+
+248
+00:22:29,930 --> 00:22:35,970
+alcohol ولو فعلت ال green yard مع أي aldehyde تاني
+
+249
+00:22:35,970 --> 00:22:39,530
+أكبر من ال formaldehyde كمثال هنا الacetaldehyde
+
+250
+00:22:39,530 --> 00:22:46,010
+بيطلع عندى secondary alcohol ولو فعلت ال green
+
+251
+00:22:46,010 --> 00:22:51,210
+yard مع ال ketone بيطلع عندى tertiary alcohol
+
+252
+00:22:54,330 --> 00:23:00,270
+رغم ان انا بحكي على نفس التفاعل بنفس النمط لكن
+
+253
+00:23:00,270 --> 00:23:06,110
+النواتج عندى مختلفة ان التفاعل مع ال Formal Dehyde
+
+254
+00:23:06,110 --> 00:23:11,530
+بيعطينى Primary Alcohol التفاعل مع Any Other
+
+255
+00:23:11,530 --> 00:23:16,690
+Aldehyde بيعطينى Secondary Alcohol والتفاعل مع ال
+
+256
+00:23:16,690 --> 00:23:21,810
+Ketones بيعطينى Tertiary Alcoholهذا كلام طبعا
+
+257
+00:23:21,810 --> 00:23:27,350
+بالنسبة للكيميائيين أكثر من ممتاز لأنه بصير عند
+
+258
+00:23:27,350 --> 00:23:31,650
+الطرق من خلالها أقدر أحضر primary alcohol و
+
+259
+00:23:31,650 --> 00:23:36,090
+secondary alcohol و tertiary alcohol بمعنى لو أنا
+
+260
+00:23:36,090 --> 00:23:39,290
+في الامتحان بدي أجي أسأل الطلاب مثلا أو الطالبات
+
+261
+00:23:39,290 --> 00:23:43,770
+كيف بنحضر هذا المركب و المركب اللي أنا جايبله مياه
+
+262
+00:23:43,770 --> 00:23:48,690
+كحولمباشرة بيصير تفكيرهم أنه إيش نوع الكحول اللي
+
+263
+00:23:48,690 --> 00:23:54,290
+أنا باسأل عنه والله إذا tertiary بقدر أفعل كيتون
+
+264
+00:23:54,290 --> 00:24:01,310
+مع green yard إذا secondary الديهيد معي green yard
+
+265
+00:24:01,310 --> 00:24:09,370
+إذا primary form الديهيد معي green yard واضح؟ فإنه
+
+266
+00:24:09,370 --> 00:24:15,780
+يكون عندى تفاعل بيطلعلي كل الاحتمالات هذا إشأكتر
+
+267
+00:24:15,780 --> 00:24:18,720
+من ممتاز أحسن يبقى هذا التفاعل صحي من ال reduction
+
+268
+00:24:18,720 --> 00:24:22,760
+لأن ال reduction ماكانش طالع لنا tertiary، صح؟ لأ
+
+269
+00:24:22,760 --> 00:24:27,060
+ال reduction ماتطلعش منه tertiary alcohol من
+
+270
+00:24:27,060 --> 00:24:32,480
+الكيتون ال tertiary alcohol من الكيتون مع .. مع ال
+
+271
+00:24:32,480 --> 00:24:36,500
+green يعني .. مع ال green يعني لما أجيبلكم مثل how
+
+272
+00:24:36,500 --> 00:24:39,140
+can you prepare a tertiary alcohol ماعرفش إذا أنا
+
+273
+00:24:39,140 --> 00:24:44,840
+على ال slides حاطتلكم أمثلةهنا يمكن نحط أمثلة
+
+274
+00:24:44,840 --> 00:24:50,120
+اكمال المعادلة لكن احنا بالتأكيد بإمكاننا يعني لو
+
+275
+00:24:50,120 --> 00:24:54,680
+رجعنا على هذا ال slide الان انتبهوا معي لو مثلا
+
+276
+00:24:54,680 --> 00:25:00,460
+انا اجيت في الامتحان سألتكم هذا السؤال جبتلكوا هذا
+
+277
+00:25:00,460 --> 00:25:04,500
+المركب بنزين
+
+278
+00:25:04,500 --> 00:25:07,320
+COH
+
+279
+00:25:12,150 --> 00:25:19,250
+How can you prepare this compound؟
+
+280
+00:25:19,250 --> 00:25:24,810
+ممكن أسيب السؤال زي ما هو هيك How can you prepare
+
+281
+00:25:24,810 --> 00:25:30,730
+this compound؟ و ممكن أزيد عليه كلام طالما هذا
+
+282
+00:25:30,730 --> 00:25:35,010
+tertiary alcohol إذا انتوا بتكونوا تتخيلوا أن ال
+
+283
+00:25:35,010 --> 00:25:44,020
+OH هذه كانتC double bond O واتفاعلت مع كيتون الأن
+
+284
+00:25:44,020 --> 00:25:50,200
+أي واحدة لكيتون أي واحدة لكيتون و أي واحدة ل green
+
+285
+00:25:50,200 --> 00:25:54,260
+yard في عندكم الحقيقة احتمالين يعني انا لو اعملت
+
+286
+00:25:54,260 --> 00:26:03,320
+هذا التفاعل C double bond O CH3 هاي كيتون و هذا
+
+287
+00:26:03,320 --> 00:26:06,060
+كيتون مشهور وموجود في المختبر شو اسمه
+
+288
+00:26:10,670 --> 00:26:15,150
+أسيتوفينون رخيص وموجود في المختبر المحلى
+
+289
+00:26:15,150 --> 00:26:20,090
+أسيتوفينون طب لو بدى اعمل ال كيتون زيك بمجموعتين
+
+290
+00:26:20,090 --> 00:26:24,890
+مثل بمشي
+
+291
+00:26:24,890 --> 00:26:32,250
+ولا لأ؟هذا أي كيتون؟ أسيتون، أسيتون، أسيتون،
+
+292
+00:26:32,250 --> 00:26:34,730
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+293
+00:26:34,730 --> 00:26:36,910
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+294
+00:26:36,910 --> 00:26:43,610
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+295
+00:26:43,610 --> 00:26:49,770
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+296
+00:26:49,770 --> 00:26:52,370
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+297
+00:26:52,370 --> 00:26:52,530
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+298
+00:26:52,530 --> 00:27:04,090
+أسيتون، أسيتون، أسيتون، أسيتون، أسمثل مثل
+
+299
+00:27:04,090 --> 00:27:08,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+300
+00:27:08,950 --> 00:27:08,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+301
+00:27:08,950 --> 00:27:08,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+302
+00:27:08,950 --> 00:27:09,010
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+303
+00:27:09,010 --> 00:27:10,010
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+304
+00:27:10,010 --> 00:27:14,150
+مثل مثل
+
+305
+00:27:14,150 --> 00:27:23,860
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثأكتر من
+
+306
+00:27:23,860 --> 00:27:27,720
+احتمال طبعا وارد هنا نفس الأشياء لو كنا نجيب الـ
+
+307
+00:27:27,720 --> 00:27:32,580
+co-secondary الكهون راجعوا ال OH إلى CWO اعملوا
+
+308
+00:27:32,580 --> 00:27:37,320
+ALDEHYDE وفعلوه مع Greenyard لو كنا نطلب تحضير ال
+
+309
+00:27:37,320 --> 00:27:44,260
+primary الكهون في هذه الحالة من أيه نحضره من تفاعل
+
+310
+00:27:44,260 --> 00:27:49,040
+Greenyard معالـ Formaldehyde من تفاعلي Greenyard
+
+311
+00:27:49,040 --> 00:27:53,240
+مع الـ Formaldehyde فهذه المنطقة بتكونوا عارفينها
+
+312
+00:27:53,240 --> 00:27:57,880
+هي منطقة بالتأكيد .. بالتأكيد هي منطقة سؤال في
+
+313
+00:27:57,880 --> 00:28:01,460
+الامتحان من أي ناحية هذه منطقة سؤال في الامتحان
+
+314
+00:28:01,460 --> 00:28:04,980
+عشان تعرفوا ان الأساتذة بتغلبوش لما يحطوا الامتحان
+
+315
+00:28:04,980 --> 00:28:08,000
+بكم
+
+316
+00:28:08,000 --> 00:28:13,120
+طريقة هنا بنسأل على هذا الموضوع؟
+
+317
+00:28:13,120 --> 00:28:20,260
+ممكن نقولكوا أكمل معادلةممكن نقولكم كيف تحضر مركب،
+
+318
+00:28:20,260 --> 00:28:27,800
+وممكن نجيبلكم سؤال صح و غلط Formal Dehydrate acts
+
+319
+00:28:27,800 --> 00:28:31,920
+with the green yard reagent producing tertiary
+
+320
+00:28:31,920 --> 00:28:36,060
+alcohol واضح؟
+
+321
+00:28:36,060 --> 00:28:40,080
+أو مثلا، secondary alcohols can be prepared from
+
+322
+00:28:40,080 --> 00:28:43,000
+the reaction of ketones with the green yard
+
+323
+00:28:43,000 --> 00:28:48,460
+reagentواضح؟ مثل هذه الجملة اللي أحيانا بتغلب
+
+324
+00:28:48,460 --> 00:28:52,840
+فيكوا، لكن زي ما انتوا ملاحظين الموضوع سهل جدا ال
+
+325
+00:28:52,840 --> 00:28:55,620
+formal dehyde primary ال ال dehydes التانية
+
+326
+00:28:55,620 --> 00:29:00,600
+secondary ال ketone tertiary alcohol مع
+
+327
+00:29:17,340 --> 00:29:23,660
+هذه المعادلة العامة طبعا احنا عادة التفاعل مع
+
+328
+00:29:23,660 --> 00:29:26,980
+جرينيا نقول بالفعل نمرة واحد مع جرينيا نمرة اتنين
+
+329
+00:29:26,980 --> 00:29:31,620
+مع حامض يعني مابديش ياكوا تعملوها خطواتين هو
+
+330
+00:29:31,620 --> 00:29:35,440
+التفاعل في داخل نفسه يتم على خطواتين لكن احنا
+
+331
+00:29:35,440 --> 00:29:41,380
+متعودين ان نقولكوا نفعل مع RMGX نمرة واحد ونمرة
+
+332
+00:29:41,380 --> 00:29:48,190
+اتنين H3O plus بناء على ذلك ماذا تكتبونالـ Final
+
+333
+00:29:48,190 --> 00:29:53,790
+Product لكن أكيد التفاعل بيمشي على مراحل أنا مش
+
+334
+00:29:53,790 --> 00:29:58,650
+كتير مهتم بالمرحلة الوسطى أنه بيصير عندي O- MgBr
+
+335
+00:29:58,650 --> 00:30:03,950
+Plus و بعدين بالحمد بيعطينا نتيجة نهائية الآن إذا
+
+336
+00:30:03,950 --> 00:30:09,120
+بدنا نتطلع على الأمثلة الموجودة عندناهي عندنا مثلا
+
+337
+00:30:09,120 --> 00:30:14,800
+هذا المُركّب الـ Acetophenon شايفينه؟ بدفعله مع
+
+338
+00:30:14,800 --> 00:30:19,380
+إثل ميجنيسيا ميبروميدل إيش المجموعة اللي بده تيجي
+
+339
+00:30:19,380 --> 00:30:25,800
+عندك؟ الـ Ethyl إذا هاي الـ Acetophenon و الـ
+
+340
+00:30:25,800 --> 00:30:31,080
+Cedarwood O تبعته صارت OH و هاي المجموعة اللي هي
+
+341
+00:30:31,080 --> 00:30:34,180
+الـ Ethyl إجت من الـ Grenade واضح؟
+
+342
+00:30:39,400 --> 00:30:44,420
+هنا تفاعل تاني مش مع green yard مع metal تاني شبيه
+
+343
+00:30:44,420 --> 00:30:47,660
+ب green yard مع ال lithium لكن نفس فكرة green yard
+
+344
+00:30:47,660 --> 00:30:51,140
+بالظبط يعني هذا يمثل اللي هو المراكب اللي مع ال
+
+345
+00:30:51,140 --> 00:30:54,200
+lithium برضه زي و زي المراكب اللي مع ال green yard
+
+346
+00:30:54,200 --> 00:31:00,580
+مجموعة ال R مع إلكترونات بناء على ذلك كل هذه
+
+347
+00:31:00,580 --> 00:31:06,180
+المجموعة بنتيجة تهاجم هنا و ال O تصير أقصر هذي
+
+348
+00:31:06,180 --> 00:31:07,560
+المجموعة اللي هي
+
+349
+00:31:14,510 --> 00:31:24,190
+هنا بس أكيد إنه ناسي يحط ال CH3 هذا خطأ طيب يعني
+
+350
+00:31:24,190 --> 00:31:28,550
+هاي المجموعة هادي اللي هي إجت دخلت عندنا و هادي
+
+351
+00:31:28,550 --> 00:31:35,380
+صارت OHهنا مثلا هي الديهيد لاحظوا احنا ليش
+
+352
+00:31:35,380 --> 00:31:40,260
+بنجيبلكوا أحيانا أنفلة بجزيئات كبيرة؟ عشان في
+
+353
+00:31:40,260 --> 00:31:43,940
+النهاية تاخدوا الجزء الكبير زي ما هو و المحور
+
+354
+00:31:43,940 --> 00:31:46,920
+الأساسي تبع التفاعل اللي عندكم هو محور إيش؟
+
+355
+00:31:46,920 --> 00:31:52,780
+المجموعة الوظيفية يعني هي هنا جزء كبير أنا كل هذا
+
+356
+00:31:52,780 --> 00:31:57,790
+الجزء الكبير هيني بتحطه في دائرةاللي هو عبارة عن
+
+357
+00:31:57,790 --> 00:32:05,890
+CH CH3 CH3 إذا بتلاحظوا هذا كله نفسه مازال موجود
+
+358
+00:32:05,890 --> 00:32:11,590
+زي ما هو لكن إجت مجموعة الـCH اللي مع مغنيسيوم أو
+
+359
+00:32:11,590 --> 00:32:18,950
+مع ليثيا شبكت واسيطة بالبندغوش وصارت OH فقط هاي
+
+360
+00:32:18,950 --> 00:32:23,850
+هادي شبيه جرينيا درجة هنا هاي مجموعة مثلا كبيرة
+
+361
+00:32:23,850 --> 00:32:28,920
+هادي كلها المجموعة اللي هيتمثل الـ Grignard Ray
+
+362
+00:32:28,920 --> 00:32:37,700
+Agent هذا الجزء كله ماذا يعني؟ محور
+
+363
+00:32:37,700 --> 00:32:39,060
+التفاعل اللي عندك
+
+364
+00:32:42,440 --> 00:32:46,240
+دخلت المجموعة اللي عندنا و الـ C double bond O
+
+365
+00:32:46,240 --> 00:32:50,880
+صارت OH و كذلك الحال في الأمثلة اللي موجودة تحت
+
+366
+00:32:50,880 --> 00:32:56,640
+هذا الكلام طبعا لازم نبحكوا لشغله أنه مثل هذه
+
+367
+00:32:56,640 --> 00:33:01,500
+الأمثلة و كل دراسة ال organ chemistry إذا ماكنتوش
+
+368
+00:33:01,500 --> 00:33:05,220
+بتمسكوا ورقة و جلم و بتقيدوا كتابة التفاعل و
+
+369
+00:33:05,220 --> 00:33:08,480
+بتقيدوا كيف أن هذه المجموعة إجت كيف أن الـ C
+
+370
+00:33:08,480 --> 00:33:13,940
+double bond O في كل الأحوال عاملة بتصيرOH OH OH OH
+
+371
+00:33:13,940 --> 00:33:20,740
+OH OH OHتطلع عليها هي كرموز تبدو العملية متعبة
+
+372
+00:33:20,740 --> 00:33:27,400
+تتعاملوا معها بنوع من التحليل العملية بسيطة جدا
+
+373
+00:33:27,400 --> 00:33:31,000
+انه انا عندي جزء ان شاء الله يكون رسم ليهانا خريطة
+
+374
+00:33:31,000 --> 00:33:35,360
+فلسطين مش مواد كيميائية بدي اخده زي ما هو في
+
+375
+00:33:35,360 --> 00:33:39,380
+النهاية الـC double bond او شو هتصير؟ الـCOH و
+
+376
+00:33:39,380 --> 00:33:44,430
+المجموعة بتدخل كالله بيصير عليهمواضح؟ هذا الكلام
+
+377
+00:33:44,430 --> 00:33:48,810
+بالتأكيد إذا ما طبقتوش و عدتوا كتابته بالجلم لرصاص
+
+378
+00:33:48,810 --> 00:33:52,150
+و اتعودتوا عليه ابتديوا يوم الامتحان فاهمين
+
+379
+00:33:52,150 --> 00:34:00,350
+الموضوع بس مابتقدروش تطبقوه فلابد إلا إيش؟
+
+380
+00:34:00,350 --> 00:34:06,910
+لابد إلا إنكم تعملوا تطبيق كتير لأنه مش كل العلم
+
+381
+00:34:06,910 --> 00:34:16,110
+بالمناسبة مش كل العلم يُأخذنظريا في أشياء لابد ..
+
+382
+00:34:16,110 --> 00:34:22,530
+لابد فيها من الجزء العمل أو التطبيق أحكي ولا أظلني
+
+383
+00:34:22,530 --> 00:34:27,630
+ساكت؟ لأ خليني ساكت أحسن يعني الـ Geta لو بدنا
+
+384
+00:34:27,630 --> 00:34:32,230
+نيجي نقولكم كيف الناس بيعملوا الملخية بتكونوا
+
+385
+00:34:32,230 --> 00:34:36,590
+تقولوا بعد ما نجيها بنفرمها هيك؟ طب روحوا أظبطوها
+
+386
+00:34:39,960 --> 00:34:44,620
+إذا ما صارش عندكم تطبيق بدل المرة عشرة مش هتظبط
+
+387
+00:34:44,620 --> 00:34:49,580
+معاكم، هتقعدوا تتطلعوا بحالكوا و تلاقوا أنها إيش؟
+
+388
+00:34:49,580 --> 00:34:53,500
+أنها مش سابقة معاكم، لابد من عملية التطبيق الكثير
+
+389
+00:34:53,500 --> 00:35:01,640
+حتى تصيروا .. تتقنوا أي عملية، واضح؟ لابد من عملية
+
+390
+00:35:01,640 --> 00:35:05,540
+التطبيق الكثير حتى تتقنوا العمليات
+
+391
+00:35:08,610 --> 00:35:17,970
+هذا التفاعل 100% مش 99% موازي لتفاعل الـ Green
+
+392
+00:35:17,970 --> 00:35:24,110
+Yard Reagent نفس الفكرة تماما .. نفس فكرة Green
+
+393
+00:35:24,110 --> 00:35:29,430
+Yard Reagent تماما لكن الآن هنا النيوكليوفايل اللي
+
+394
+00:35:29,430 --> 00:35:35,810
+بنفاعل معه هو الـ Acetylide الآن يا تورا متذكرين
+
+395
+00:35:35,810 --> 00:35:44,660
+الـ Acetylide ولا لأ؟أنا بذكركوا فيه لما
+
+396
+00:35:44,660 --> 00:35:47,960
+درسنا ال ال kinds المركبات اللي فيهم ال travel
+
+397
+00:35:47,960 --> 00:35:55,130
+bondلأ مش ضروري أبسط واحد أي ألكاين بنقول عنه
+
+398
+00:35:55,130 --> 00:36:02,850
+terminal طرفي بمعنى في هنا C triple bond C وهنا H
+
+399
+00:36:02,850 --> 00:36:08,730
+هذا بزن في أحد أطرافه H إذا هو terminal الكاين
+
+400
+00:36:08,730 --> 00:36:14,010
+الآن هذا ال terminal الكاين قاعدي أحط هنا فيه إيش
+
+401
+00:36:14,010 --> 00:36:14,690
+بدكم؟
+
+402
+00:36:17,600 --> 00:36:24,840
+فنل بمشي مثل بمشي مجموعة من أربع ذرات بمشي إيش ما
+
+403
+00:36:24,840 --> 00:36:28,900
+كان بمشي بيبطل محور السؤال يعني خليني مثلا قد ما
+
+404
+00:36:28,900 --> 00:36:32,100
+بدي أكبر و أعمل زيك و زيك و زيك و زيك هذه كلها
+
+405
+00:36:32,100 --> 00:36:39,270
+ذرات carbon و في الآخر أجه أحط هنا فنلواضح؟ الآن
+
+406
+00:36:39,270 --> 00:36:44,410
+الـ Terminal Alkines أخدنا عنهم إن هما عبارة عن
+
+407
+00:36:44,410 --> 00:36:52,370
+Assets لمن فعلهممع ال NA مع ال Sodium بيفقد بروتون
+
+408
+00:36:52,370 --> 00:36:56,550
+و بيعطينا ال Acetylide إذا لما أنا .. هذا التفاعل
+
+409
+00:36:56,550 --> 00:36:59,410
+لسه اللي أخدته اللي بدأ أستفيد منه لما أجي بدأ
+
+410
+00:36:59,410 --> 00:37:03,090
+أتذكر هالكلام جزء كبير شوية الامتحان الصعب ولا
+
+411
+00:37:03,090 --> 00:37:07,310
+كبير ولا إشي هذه ال C ال triple bond C اللي جمّع H
+
+412
+00:37:07,310 --> 00:37:10,110
+لما أفعلها مع ال Sodium بدأ تشيلي ال H و تحطلي
+
+413
+00:37:10,110 --> 00:37:13,490
+Sodium معنا ذلك أنا إيش اللي بدأ أعمله لو أنا قاعد
+
+414
+00:37:13,490 --> 00:37:18,940
+على برنامج رسم و بعمل نسخ و لاصق؟بدي أخد هذه
+
+415
+00:37:18,940 --> 00:37:23,060
+المجموعة كلها و أحطها هنا فقط بدي أشيل الـH و أحط
+
+416
+00:37:23,060 --> 00:37:27,840
+الـNA ألاحظين كيف التعامل مع ال .. مع ال organic
+
+417
+00:37:27,840 --> 00:37:32,820
+problems C
+
+418
+00:37:32,820 --> 00:37:37,620
+triple bond C NA
+
+419
+00:37:37,620 --> 00:37:43,590
+بتصير هذه minus وهذه plusأيا كان الجزء اللي هنا
+
+420
+00:37:43,590 --> 00:37:49,110
+الان هنا محور المسألة انه هذا ال Acetylide
+
+421
+00:37:49,110 --> 00:37:52,610
+compound اللي سمناه Acetylide بيحتوي على ايه عشان
+
+422
+00:37:52,610 --> 00:37:59,850
+علمه بالأزرق كمان مرة بيحتوي على سالب اذا هو يمثل
+
+423
+00:37:59,850 --> 00:38:05,790
+ال nucleophile هذا الجزء كله يمثل ال nucleophile
+
+424
+00:38:05,790 --> 00:38:12,140
+كيف بتفاعل ال nucleophileمع الالديهال او الكيتون
+
+425
+00:38:12,140 --> 00:38:18,620
+اكيد بتفاعل الاديشن كل هذا بده ييجي يهجم على
+
+426
+00:38:18,620 --> 00:38:24,580
+الكربونة ويحول السيما بالبند أو إلى OH واضح؟ هاي
+
+427
+00:38:24,580 --> 00:38:29,840
+مثلا هنا أستيلايد صغير مش كبير زي هذا اللي بخوف
+
+428
+00:38:29,840 --> 00:38:35,030
+هاي أستيلايد صغير شايفينه؟بدو يتفاعل مع هذا الـ
+
+429
+00:38:35,030 --> 00:38:40,130
+Ketone وين المحور؟ إن هذا زوج الإلكترونات يجي
+
+430
+00:38:40,130 --> 00:38:45,450
+يتفاعل، هاد الكربون أو هاد تصير فزي ما بتلاحظوا
+
+431
+00:38:45,450 --> 00:38:50,590
+أنتوا، باقي الـ Ketone أو الـ aldehyde، ضالوا زي
+
+432
+00:38:50,590 --> 00:39:00,010
+ما هو، باقي الـ acetylide، ضالوا زي ما هو، طبعا،
+
+433
+00:39:00,010 --> 00:39:05,430
+إذا إيش التفاعل بيصف في النهاية؟حقيقة التفاعل
+
+434
+00:39:05,430 --> 00:39:09,470
+بالنهاية هو عبارة .. يعني لو كنتوا بتكونوا بسطوا
+
+435
+00:39:09,470 --> 00:39:13,410
+الموضوع جدا جدا هو عبارة عن زوج إلكترونات بيهاجم
+
+436
+00:39:13,410 --> 00:39:19,130
+هنا و بيحولها إلى OH هذه زوج الإلكترونات وهذه صارت
+
+437
+00:39:19,130 --> 00:39:24,610
+OH طب و باقي الكلام كله اللي هنا زي ما هو و باقي
+
+438
+00:39:24,610 --> 00:39:28,350
+الكلام كله اللي هنا مع هذا زوج الإلكترونات زي ما
+
+439
+00:39:28,350 --> 00:39:31,150
+هو واضح؟
+
+440
+00:39:36,120 --> 00:39:42,360
+الان انتبهوا مثلا على هذا المُركّب هاي مُركّب كبير
+
+441
+00:39:42,360 --> 00:39:49,900
+جد البحر شايفينه؟ في النهاية إيش موجود فيه؟ أسيطة
+
+442
+00:39:49,900 --> 00:39:53,780
+بالـ bond O كل هذا المُركّب هيظل زي ما هو بدا
+
+443
+00:39:53,780 --> 00:39:57,580
+أفعله أنا في هذه الحالة معي green يعني رجعت ل
+
+444
+00:39:57,580 --> 00:40:02,640
+green يعني هذه الـCH3 بنتيجة أنا وهذه الأسيطة بالـ
+
+445
+00:40:02,640 --> 00:40:03,580
+bond O تصير
+
+446
+00:40:07,570 --> 00:40:11,170
+الان هذا الناتج بعدين بيعمل عملية cyclization تخرج
+
+447
+00:40:11,170 --> 00:40:15,250
+الموضوع احنا هاي الناتج اللي ملاحظينه ان واحدة من
+
+448
+00:40:15,250 --> 00:40:22,190
+ال CH3 اتجت من برا وهي هذا الجزء كله اللي كان
+
+449
+00:40:22,190 --> 00:40:27,270
+موجود عندى عشانك مثلا هذا الجزء الأخير اللي مبين
+
+450
+00:40:27,270 --> 00:40:33,310
+كبير لو قلتلكوا بدي افعله مع benzaldehyde بقدر بدي
+
+451
+00:40:33,310 --> 00:40:41,640
+اقول زائد phenylC double bond OH كيف
+
+452
+00:40:41,640 --> 00:40:50,380
+هتعملوه هذي بده تاجم هنا و ال O بده تصير OH فقط
+
+453
+00:40:50,380 --> 00:40:57,980
+مجرد انكوا تجيبوا هذي هنا و هذي بتخلوها OH هنا و
+
+454
+00:40:57,980 --> 00:41:03,420
+رسموهطبعا أنا بصير جديش عندكم القدرة أنه بجلم
+
+455
+00:41:03,420 --> 00:41:07,240
+لرصاص تلسخه الأشياء زي ما هي ترسموها مش أكتر،
+
+456
+00:41:07,240 --> 00:41:13,280
+واضح؟فزي ما بتلاحظوا لما انا من محاضرتين قلتلكوا
+
+457
+00:41:13,280 --> 00:41:17,160
+انه في ال الديهيدس والكيتونز كل الشغل اللي عندكوا
+
+458
+00:41:17,160 --> 00:41:22,300
+تطبيق وقاعد انا بدور محاضرتين كاملين حوالي الفكرة
+
+459
+00:41:22,300 --> 00:41:26,220
+واحدة انه زوج إلكترونات بيهاجم على ال C double
+
+460
+00:41:26,220 --> 00:41:32,160
+bond O و بيحولها إلى OH مازدناش عن هذه الفكرة لكن
+
+461
+00:41:32,160 --> 00:41:38,950
+ايش عملنا؟عملنا أمثلة تطبيقية كتيرة بنجح عند موضوع
+
+462
+00:41:38,950 --> 00:41:43,390
+الـ oxidation of aldehydes and keto
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..dba938d0ed10f113530e1d3729aaacd3fc68259b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_postprocess.srt
@@ -0,0 +1,2000 @@
+1
+00:00:07,360 --> 00:00:13,000
+بسم الله الرحمن الرحيم اتكلمنا المرة الماضية في
+
+2
+00:00:13,000 --> 00:00:18,800
+موضوع ال ethers بشكل أساسي تسمية ال ethers وخواصها
+
+3
+00:00:18,800 --> 00:00:27,600
+اليوم بنستمر في تناول هذا الموضوع هنتكلم على تحضير
+
+4
+00:00:27,600 --> 00:00:33,340
+ال ethers و بعض تفاعلاتها زي التوسع في هذا المجال
+
+5
+00:00:33,950 --> 00:00:40,830
+الان يوم ما بيجيكم اي ether بتكونوا عارفين ان ال
+
+6
+00:00:40,830 --> 00:00:47,070
+ether تقسم الى نوعين ممكن ال ether تكون symmetric
+
+7
+00:00:47,070 --> 00:00:52,730
+بمعنى مجموعتين ال R اللي موجودات زي بعض يعني لما
+
+8
+00:00:52,730 --> 00:00:58,890
+نقول اثل اثل هذا symmetric etherمثل مثل فنل فنل كل
+
+9
+00:00:58,890 --> 00:01:03,890
+هذه عبارة عن symmetrical ethers وممكن ال ethers
+
+10
+00:01:03,890 --> 00:01:10,770
+تكون unsymmetrical بمعنى يكون في عند مثلا اثل مع
+
+11
+00:01:10,770 --> 00:01:17,700
+مثل اوإيثل مع فيلل أو ايزو بروبل مع إيثل احتمالات
+
+12
+00:01:17,700 --> 00:01:21,620
+كتير الآن هنا بيصير عندنا طريقتين للتحضير يعني لما
+
+13
+00:01:21,620 --> 00:01:26,860
+بيحضر symmetrical ethers في عنده طريقة و لما بيحضر
+
+14
+00:01:26,860 --> 00:01:31,950
+unsymmetrical ethers في عنده طريقة تانيةالـ
+
+15
+00:01:31,950 --> 00:01:35,270
+symmetrical ethers طريقة تحضيرهم سهلة وممكن مرت
+
+16
+00:01:35,270 --> 00:01:41,310
+علينا عرضا أثناء تكلمنا عن الألكينات إذا أخدنا
+
+17
+00:01:41,310 --> 00:01:46,530
+الكحول وسخناه لحرارة محددة في وجود حامض بيعطينا ال
+
+18
+00:01:46,530 --> 00:01:51,950
+ether يعني مثلا ال diethyl ether إذا احنا أخدنا ال
+
+19
+00:01:51,950 --> 00:01:56,830
+ethanol مع sulfuric acid على 140 درجة مئوية
+
+20
+00:01:56,830 --> 00:02:02,470
+بيعطينا ال diethyl ether واضح؟كذلك الحالة لو بدى
+
+21
+00:02:02,470 --> 00:02:08,530
+dipropyl ether مثلا أو ما إلى ذلك طريقة سهلة كتير
+
+22
+00:02:08,530 --> 00:02:15,050
+الآن بتصير عندنا .. بتصير عندنا مشكلة لما بنحضر ال
+
+23
+00:02:15,050 --> 00:02:20,770
+unsymmetrical ethers اتخيلوا انتوا لو اجينا بنحضر
+
+24
+00:02:20,770 --> 00:02:25,170
+ال unsymmetrical ethers بنفس الطريقة في هذه الحالة
+
+25
+00:02:25,170 --> 00:02:30,610
+بدنا نكون مضطرين ناخد كام كحول اتنينواضح؟ يعني لو
+
+26
+00:02:30,610 --> 00:02:35,310
+مثلا بدي ether جاي من ال .. من ال methanol و ال
+
+27
+00:02:35,310 --> 00:02:40,230
+ethanol بكون بدي two alcohols يعني بدي ال methyl
+
+28
+00:02:40,230 --> 00:02:48,390
+OH و ال ethyl OH الآن لو هدول الاتنين خلطتهم أنا
+
+29
+00:02:48,390 --> 00:02:53,790
+مع sulfuric acid و سخنت ايش اللي بدي اقول ان دي؟
+
+30
+00:02:53,790 --> 00:02:58,290
+تخيلوا ان انا خلطت H plus مع sulfuric acid و تسخين
+
+31
+00:02:58,600 --> 00:03:03,760
+ماذا تتوقع ان يحدث في هذه الحالة؟
+
+32
+00:03:03,760 --> 00:03:10,660
+طبعا تضعوا في اعتباركم ان انا لما اعمل التفاعل لم
+
+33
+00:03:10,660 --> 00:03:15,640
+اضع جزء واحد من الميثانول و جزء واحد من الاثانول
+
+34
+00:03:15,640 --> 00:03:19,520
+انا اضعت مثلا one mole of methanol و one mole of
+
+35
+00:03:19,520 --> 00:03:23,900
+ethanol لحظة مبدأ اقول one mole يعني بحكي عن 6 في
+
+36
+00:03:23,900 --> 00:03:24,680
+10 او 23
+
+37
+00:03:36,250 --> 00:03:42,450
+ممكن يلتقي الميثانول مع جزء ميثانول تاني وبالتالي
+
+38
+00:03:42,450 --> 00:03:49,450
+يعمل dimethyl ether يعني يعطي الميثل وميثل وممكن
+
+39
+00:03:49,450 --> 00:03:57,340
+الاثانول يلتقي مع جزء اثانول تاني ويعطيمثل او اثل
+
+40
+00:03:57,340 --> 00:04:02,640
+او اثل
+
+41
+00:04:02,640 --> 00:04:05,000
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+42
+00:04:05,000 --> 00:04:05,700
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+43
+00:04:05,700 --> 00:04:07,220
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+44
+00:04:07,220 --> 00:04:07,500
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+45
+00:04:07,500 --> 00:04:13,580
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل ا
+
+46
+00:04:13,880 --> 00:04:17,980
+خليط من ثلاث نواتج وهذا دائما الكلام الكيميائيين
+
+47
+00:04:17,980 --> 00:04:22,520
+بتجنبوه لأن عملية فصل المراكبات عن بعض بالتقطير و
+
+48
+00:04:22,520 --> 00:04:28,640
+غيرها عملية متعبة و مكلفة و ما إلى ذلك فعملية ان
+
+49
+00:04:28,640 --> 00:04:33,180
+انا بضح أحضر un-symmetrical ether من خلط two
+
+50
+00:04:33,180 --> 00:04:36,820
+different alcohols ليست طريقة عملية is not a
+
+51
+00:04:36,820 --> 00:04:41,440
+practical methodمش مقبولة يعني لو بداجي أقولكوا
+
+52
+00:04:41,440 --> 00:04:44,940
+حضرولي ال مثل و إثل و طالبي بداجي أجابني إنه بخلق
+
+53
+00:04:44,940 --> 00:04:49,400
+ميثانول و إيثانول و حامض و حرارة الجواب غلط هذا
+
+54
+00:04:49,400 --> 00:04:52,700
+الكلام مش مقبول لأن هذا الكلام بيطلق تلت نواتج
+
+55
+00:04:52,700 --> 00:04:58,260
+عملية فصل التلت نواتج هدول عن بعضهم عملية صعبة و
+
+56
+00:04:58,260 --> 00:05:04,430
+مزعجةأذن كان لابد من طريقة تانية لتحضير الـ
+
+57
+00:05:04,430 --> 00:05:08,430
+Unsymmetrical ethers يطلع فيها المركّب لوحده، ليس
+
+58
+00:05:08,430 --> 00:05:13,990
+لدي خليط من تلت نواتجواضح الفكرة؟ اه ..الان هذه
+
+59
+00:05:13,990 --> 00:05:18,910
+كيف بيعملوها؟ بيجيبوا alcohol، واحد من ال alcohol
+
+60
+00:05:18,910 --> 00:05:24,250
+بيخلوه ROH، ال alcohol نفسه ROH، لو فعلنا مع ال
+
+61
+00:05:24,250 --> 00:05:28,350
+sodium، كلكوا عارفين ان ال sodium بياخد ال H و
+
+62
+00:05:28,350 --> 00:05:34,590
+بيعملنا RO minusفصار عندى RO-NA+, يعني لو كان عندى
+
+63
+00:05:34,590 --> 00:05:41,030
+مثلا إيثانول بيصير عندى Sodium Ethoxide لو كان
+
+64
+00:05:41,030 --> 00:05:45,470
+عندى هنا إيثانول مع ال Sodium بيعطينا Sodium
+
+65
+00:05:45,470 --> 00:05:49,770
+Ethoxide هذا المركب بتطلع هذه معادلة هيك لوحدها
+
+66
+00:05:49,770 --> 00:05:56,130
+الناتج اللى صار عندى هنا باجب فعله مع RX تانية
+
+67
+00:05:56,920 --> 00:06:00,300
+واضح؟ يعني أرجو أنه ما تفهموش هذه المعادلة لأن هذا
+
+68
+00:06:00,300 --> 00:06:04,960
+بيطلع الناتجين لأ هذه معادلة لوحدها أنه انا لو
+
+69
+00:06:04,960 --> 00:06:09,040
+أخدت الethanol مع ال sodium بيطلع له sodium
+
+70
+00:06:09,040 --> 00:06:13,080
+ethoxide صار كل المحلول عبارة عن sodium ethoxide
+
+71
+00:06:13,080 --> 00:06:18,230
+الآن هذا ال sodium ethoxide بنيجي بنضيفهأو من فعله
+
+72
+00:06:18,230 --> 00:06:28,170
+مرة تانية مع R' X أي R تانية نفترض مثلا CH3CL الـ
+
+73
+00:06:28,170 --> 00:06:32,990
+RO- هذه بتيجي بتعمل عملية إبدال على الـ RX بتهاجم
+
+74
+00:06:32,990 --> 00:06:37,210
+هيك و بتطرد الـ Xواخدنا أن التفاعل الأساسي
+
+75
+00:06:37,210 --> 00:06:42,090
+لمُركّبات الـRX هو الـ Substitution واخدنا أنها
+
+76
+00:06:42,090 --> 00:06:48,750
+ممكن تتم بـ Sn1 وممكن تتم بـ Sn2 ميكانيزم، واضحة؟
+
+77
+00:06:48,750 --> 00:06:54,030
+فكأنه أنا صار عندي هلأ بالتأكيد ر أو ماينوس هاجمت
+
+78
+00:06:54,030 --> 00:06:59,350
+على R' X طلعت الـ X فبصير عندي ر أو ر ناتج واحد
+
+79
+00:06:59,350 --> 00:07:07,470
+فقط ناتج واحد فقطهنا يفضل حتى يكون التفاعل أفضل ما
+
+80
+00:07:07,470 --> 00:07:13,070
+يمكن انه لما بعمل عملية اختيار ان ال R' X هذه تكون
+
+81
+00:07:13,070 --> 00:07:19,450
+ال primary يفضل ان ال R' X تكون ال primary خلينا
+
+82
+00:07:19,450 --> 00:07:26,930
+ناخد مثال حقيقي بدون R و A مثلا لو أخدنا الفيلول
+
+83
+00:07:26,930 --> 00:07:32,530
+مع السوديومبدي يعطينا Sodium Phenoxide ممتازة كل
+
+84
+00:07:32,530 --> 00:07:36,810
+المحلول اللي عندى صار Sodium Phenoxide الان هذا
+
+85
+00:07:36,810 --> 00:07:43,970
+المحلول باجب اضيفه على مثلا Ethyl Chloride او
+
+86
+00:07:43,970 --> 00:07:48,090
+Ethyl Bromide لاحظوا اذا انا هنا بتعامل مع two
+
+87
+00:07:48,090 --> 00:07:52,910
+flasks هاي حضرت هنا ال ethoxide بعد ما اتحضر
+
+88
+00:07:52,910 --> 00:07:59,750
+بنضيفه هنا ايش بتعمل ال filler O minusبتهاجم هنا
+
+89
+00:07:59,750 --> 00:08:08,110
+وبتطرد ال X بيصير عندى Phenyl O CH2 CH3 واضحة
+
+90
+00:08:08,110 --> 00:08:16,890
+الفكرة لاحظوا هنا لحظة ما انا بأعمل الاختيار بفضل
+
+91
+00:08:16,890 --> 00:08:24,450
+و لازم انه يكونالـ RX Primary يعني مثلا لو إجينا
+
+92
+00:08:24,450 --> 00:08:29,750
+بنسألكوا السؤال الآن كيف ممكن تحضرولنا هذا الـ
+
+93
+00:08:29,750 --> 00:08:34,610
+Etherكيف ممكن تحضروا هذا الـ Ether؟ انتوا لما
+
+94
+00:08:34,610 --> 00:08:39,170
+بتكونوا تجيبوا على السؤال هذا الـ Ether هذا عبارة
+
+95
+00:08:39,170 --> 00:08:42,350
+عن symmetrical ولا unsymmetrical؟ unsymmetrical ..
+
+96
+00:08:42,350 --> 00:08:44,070
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+97
+00:08:44,070 --> 00:08:45,530
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+98
+00:08:45,530 --> 00:08:47,870
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+99
+00:08:47,870 --> 00:08:49,790
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+100
+00:08:49,790 --> 00:08:50,590
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+101
+00:08:50,590 --> 00:08:51,990
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+102
+00:08:51,990 --> 00:08:54,910
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+103
+00:08:54,910 --> 00:08:57,670
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+104
+00:08:57,670 --> 00:09:01,500
+unsymmetrical .. unsلـ Probability group واحدة
+
+105
+00:09:01,500 --> 00:09:11,800
+منهم بيكون O- والتانية RX الصعوبة هنا أن أعرف أنية
+
+106
+00:09:11,800 --> 00:09:17,140
+اللي بيبقى معها الـ O- وأنية اللي بيكون الـ RX
+
+107
+00:09:17,140 --> 00:09:22,340
+احنا أخدنا شرط الـ RX لازم تكون الـ Primary إذا
+
+108
+00:09:22,340 --> 00:09:26,620
+هذا لما بدي أحلله للمكونات تبعونه، إيش بيكون؟
+
+109
+00:09:31,030 --> 00:09:38,210
+بدي اخد هذا الكحول اللي هو الـ tertiary-butanol و
+
+110
+00:09:38,210 --> 00:09:42,930
+التيرتشاري بيوتانول هذا لما نفعله مع السوديوم بدي
+
+111
+00:09:42,930 --> 00:09:46,850
+يعطينا التيرتشاري بيوت أكسيد هذه المعادلة الأولى
+
+112
+00:09:46,850 --> 00:09:51,030
+اللي عندنا، واضح؟ إذا إحنا حضرنا التيرتشاري بيوت
+
+113
+00:09:51,030 --> 00:09:56,190
+أكسيد انايون الايون السالف بعد هيك بدنا نفعله مع
+
+114
+00:09:56,190 --> 00:10:06,380
+إيش؟مع الـ R هذه اللي هي CH3 CH2 CH2 و هنا بيكون
+
+115
+00:10:06,380 --> 00:10:13,360
+اندت CL أو PR واضح؟ في هذه الحالة بيتم عملية هجوم
+
+116
+00:10:13,360 --> 00:10:19,880
+من الـ O minus هنا وعملية طرد لل PR بنحصل على
+
+117
+00:10:19,880 --> 00:10:20,680
+الناتج الباكر
+
+118
+00:10:23,830 --> 00:10:28,570
+الان لو واحدة عملت الجواب هنا بالعكس خلت هذا تصير
+
+119
+00:10:28,570 --> 00:10:34,070
+O minus وال X تكون هنا tertiary مش هيصير التفاعل
+
+120
+00:10:34,070 --> 00:10:41,430
+واضح؟ اذا شرط هذا التفاعل ان ال R X نخليها primary
+
+121
+00:10:41,430 --> 00:10:45,190
+بصعوبة لو كان secondary ممكن يمشي بصعوبة كتير يعني
+
+122
+00:10:45,190 --> 00:10:51,030
+بيكون بطيء tertiary مستحيل فطالما ان احد مكونات ال
+
+123
+00:10:51,030 --> 00:10:55,590
+etherالبرايماري والتاني secondary او tertiary اذا
+
+124
+00:10:55,590 --> 00:10:59,710
+انا نية اللى بده اخليها RX لبرايماري لو كان مثلا
+
+125
+00:10:59,710 --> 00:11:06,530
+برايماري مع فنل لأن
+
+126
+00:11:06,530 --> 00:11:11,570
+الفنل لو حد عمل عليها X مش لأنها tertiary لأ انتوا
+
+127
+00:11:11,570 --> 00:11:16,370
+اخدتوا كمان قبل هيك شغلة انه لا يمكن ابدال X على
+
+128
+00:11:16,370 --> 00:11:23,180
+حلقة بنزينمتذكرين لما قلنا لكم ARX لا يحدث ابدال
+
+129
+00:11:23,180 --> 00:11:28,440
+بناء ع ذلك لو برضه بدي يجيكم سؤال في الامتحانات
+
+130
+00:11:28,440 --> 00:11:33,760
+واضح نخلصناه زي
+
+131
+00:11:33,760 --> 00:11:42,270
+هذا المثال تتطلع عليه من الآخرحضرولنا فين ال O إثل
+
+132
+00:11:42,270 --> 00:11:46,490
+و لا مثل و لا global واحدة تيجي تقسم هذا تقسيم
+
+133
+00:11:46,490 --> 00:11:54,890
+خاطئ يعني تخليلي هذه فين ال X زائد مثلا إثل O
+
+134
+00:11:54,890 --> 00:11:58,290
+minus و تقول والله هذه إثل O minus بتهاجم على فين
+
+135
+00:11:58,290 --> 00:12:04,050
+ال X بتتردها إذا السؤال عليه خمس درجات كده بتاخد؟0
+
+136
+00:12:04,050 --> 00:12:07,490
+ليش؟
+
+137
+00:12:07,490 --> 00:12:12,750
+لأنه لا يتم الإبدال على الاروماتيك كومباونز السابق
+
+138
+00:12:12,750 --> 00:12:16,670
+أخدناها واضح؟ لا يتم الإبدال في هذه الحالة جواب
+
+139
+00:12:16,670 --> 00:12:21,290
+الصح أن تكون هذه فين الـO-؟ وهذه تكون FX
+
+140
+00:12:23,140 --> 00:12:27,240
+هذا اللي هو William Sons Synthesis و بالمناسبة
+
+141
+00:12:27,240 --> 00:12:30,420
+طبيعة .. هيك يا ربنا خلق الدنيا سبحانه وتعالى
+
+142
+00:12:30,420 --> 00:12:35,140
+طبيعة الامتحانات لا يمكن اصحكوا تفكروا ييجي امتحان
+
+143
+00:12:35,140 --> 00:12:39,660
+و ما نجيبش عليه سؤال نختبركوا بهذه المنطقة بتاعة
+
+144
+00:12:39,660 --> 00:12:43,640
+تحضير Unsymmetrical Ether و تعرفولي بالظبط ايش
+
+145
+00:12:43,640 --> 00:12:47,860
+معنى ال primary و secondary و tertiary و كيف
+
+146
+00:12:47,860 --> 00:12:54,540
+تعملوا مكونات هذا ال ether ماشي؟هنا قدام الكاميرا
+
+147
+00:12:54,540 --> 00:13:00,880
+كشفنا سؤال من الامتحان الآن
+
+148
+00:13:00,880 --> 00:13:07,910
+الـ cleavage of ethersلاحظوا معنى لما بنحكي احنا
+
+149
+00:13:07,910 --> 00:13:13,070
+عن بعض المُركّبات أو العائلات بنقول reactions of
+
+150
+00:13:13,070 --> 00:13:16,570
+مثلا alcohols بناخد أربع خمس ست أنواع من ال
+
+151
+00:13:16,570 --> 00:13:20,350
+reactions بعد شوية لما نحكي مثلا عن ال aldehydes و
+
+152
+00:13:20,350 --> 00:13:24,090
+ال ketones بناخد reactions of aldehydes و ketones
+
+153
+00:13:24,090 --> 00:13:27,910
+ممكن ناخد محاضرتين أو تلاتة لما حكينا على ال
+
+154
+00:13:27,910 --> 00:13:32,930
+alkenesتفاعلات الإضافة والـ Palmer وما إلى ذلك
+
+155
+00:13:32,930 --> 00:13:37,210
+كانت قصة، بظبط ولا لا؟ لكن لما بنحكي على
+
+156
+00:13:37,210 --> 00:13:41,730
+الـEthers، إحنا في الأساس قلنا الـEthers they are
+
+157
+00:13:41,730 --> 00:13:46,770
+considered to be inert، يعني تقريبا ما بتفعلوش، هم
+
+158
+00:13:46,770 --> 00:13:51,530
+تقريبا، الملومش غيرها التفاعل اليتيممع حامض قوى
+
+159
+00:13:51,530 --> 00:13:57,210
+مثل الـ HI بس حامض قوى مثل الـ HI بكسرهم إذا
+
+160
+00:13:57,210 --> 00:14:03,150
+تفاعلهم تفاعل إكليفج إيش يعني إكليفج؟ تكسير إكليفج
+
+161
+00:14:03,150 --> 00:14:10,190
+reaction يعني إن أكسر المركب إلى نصين طيب كيف مثلا
+
+162
+00:14:10,190 --> 00:14:15,210
+لو أخدنا هذا ال ether الفيرل O CH2 CH3 نرجع لنفس
+
+163
+00:14:15,210 --> 00:14:19,450
+ال ether الآن هذا لما نيجي الفعل مع HI ال I تعتبر
+
+164
+00:14:21,030 --> 00:14:25,650
+أو الـ Strong nucleophile بنتيجة التهاجم هل يترى
+
+165
+00:14:25,650 --> 00:14:28,690
+هذا الـ I لما بيتهاجم تهاجم على ال primary carbon
+
+166
+00:14:28,690 --> 00:14:32,850
+ولا على الفينيل؟ بتهاجم على ال primary carbon أسهل
+
+167
+00:14:32,850 --> 00:14:36,110
+إيش أن تتصل إلى ال primary carbon؟ فبتم هجوم بهذا
+
+168
+00:14:36,110 --> 00:14:43,020
+الشكل؟وبتكسر هذه كأنه عملت عكس التفاعل السابق كأنه
+
+169
+00:14:43,020 --> 00:14:46,280
+عملت عكس التفاعل السابق بتصير أدفين الـ O minus
+
+170
+00:14:46,280 --> 00:14:50,600
+وبعدين بتاخد الـ H plus من اللي كانت مع الـ I زائد
+
+171
+00:14:50,600 --> 00:14:57,960
+CH3CH2I إذا هنا تكسير هذا ال ether بالـ HI أعطاني
+
+172
+00:14:57,960 --> 00:15:05,830
+الكهول زائد الكلهلين لاحظوا هو عكسالتفاعل السابق
+
+173
+00:15:05,830 --> 00:15:08,910
+بس في التفاعل السابق انا ماكنتش افعل ال alcohol
+
+174
+00:15:08,910 --> 00:15:13,130
+كنت اقويه انا اول اش افعله مع ال sodium عشان تصير
+
+175
+00:15:13,130 --> 00:15:17,050
+فين ال O minus كان ال nucleophile اقوى لانه احنا
+
+176
+00:15:17,050 --> 00:15:20,170
+اخدنا ان اللي charged ال nucleophiles are stronger
+
+177
+00:15:20,170 --> 00:15:26,750
+than ال neutral ال nucleophiles مظبوط ولا لا الان
+
+178
+00:15:26,750 --> 00:15:32,170
+نفس الفكرة لو بدكم تطلعوا على هذا ال ether اللي هو
+
+179
+00:15:32,170 --> 00:15:39,220
+ايش اسمهفي تيرتشاريبيوتيل جروب وفي إبروبيل إذا هذا
+
+180
+00:15:39,220 --> 00:15:45,020
+تيرتشاريبيوتيل إبروبيل إيثر مظبوط ولا لا
+
+181
+00:15:45,020 --> 00:15:51,120
+تيرتشاريبيوتيل إبروبيل إيثر الآن لما بتفعل ولا مع
+
+182
+00:15:51,120 --> 00:15:57,620
+I minus وين المكان السهل انها تصل ال I minus ال
+
+183
+00:15:57,620 --> 00:16:01,080
+primary تخيلوا السهل اتصل هنا
+
+184
+00:16:05,110 --> 00:16:08,670
+طبعا ده زوج الإلكترونات بيجي على الأكسجين بيصير
+
+185
+00:16:08,670 --> 00:16:13,410
+عندنا ترتشالفيوتانول
+
+186
+00:16:13,410 --> 00:16:20,910
+زائد بروبل أيوديت اذا احنا اللي بيصير عندنا بالظبط
+
+187
+00:16:20,910 --> 00:16:28,040
+لما بنفعل ال ethersمع الـ HI بينكسروا ل Alcohol
+
+188
+00:16:28,040 --> 00:16:32,680
+زائد Alkyl Halide بينكسروا ل Alcohol زائد Alkyl
+
+189
+00:16:32,680 --> 00:16:37,400
+Halide أحيانا لو كان هذا ال primary وع الجهة
+
+190
+00:16:37,400 --> 00:16:43,520
+التالية primary شو بيصير عنده واضح التساؤل اللي
+
+191
+00:16:43,520 --> 00:16:50,280
+أنا بطرحه يعني مثلا لو كنا حاطين هنا CH3O
+
+192
+00:16:51,840 --> 00:16:56,960
+CH2 CH3 هذي primary و هذي أحسن كمان من ال primary
+
+193
+00:16:56,960 --> 00:17:02,660
+حقيقة اللي بدو يطلع عندى الاحتمالين طبعا هنا لو
+
+194
+00:17:02,660 --> 00:17:06,720
+كنت أنا مستعمل HI كتير يعنى خلينا نفترض انه مع ال
+
+195
+00:17:06,720 --> 00:17:20,000
+HI هذا أعطانا هذا أعطانا CH3 I زائد CH3 CH2
+
+196
+00:17:21,060 --> 00:17:26,040
+الان اذا اله اي كتير بيجي يتفاعل مع هذا الكحول لان
+
+197
+00:17:26,040 --> 00:17:34,460
+هذا الكحول ال primary و بيحاولوا كمان CH3 CH2I في
+
+198
+00:17:34,460 --> 00:17:38,660
+النهاية بيطلع
+
+199
+00:17:38,660 --> 00:17:44,020
+ال two iodides واضح؟ لكن في مثل هذه الحالة مثلا هل
+
+200
+00:17:44,020 --> 00:17:49,330
+اليوت بيقدر يحل محل OH على البنزين؟أو هاليود بحب
+
+201
+00:17:49,330 --> 00:17:53,050
+كتير حلم حلو أشتري Cherry لأ لكن لو كانت ال
+
+202
+00:17:53,050 --> 00:17:57,030
+primary ممكن كمية إضافية تكون موجودة من اليود
+
+203
+00:17:57,030 --> 00:18:00,730
+excess اتحال وبالتالي يطلع عندى بس ال iodide بمعنى
+
+204
+00:18:00,730 --> 00:18:04,310
+انه صح اتكون ال alcohol في البداية لكن ال alcohol
+
+205
+00:18:05,890 --> 00:18:10,990
+بخطوة إضافية اتحول ل iodide فكأنه يعني ال two
+
+206
+00:18:10,990 --> 00:18:14,670
+parts of the ether are converted to alkyl halides
+
+207
+00:18:14,670 --> 00:18:20,950
+الجزئين من ال ether اتحولوا ل ال alkyl halide
+
+208
+00:18:44,950 --> 00:18:51,910
+في عندنا موضوع تاني ال ethers مرات بتكون cyclic
+
+209
+00:18:51,910 --> 00:18:56,850
+ethers واضح يعني بشكل عام ال ethers العادية
+
+210
+00:18:56,850 --> 00:19:03,370
+الفاتحة ROR الان لو ال O صارت موجودة جوا حلقة
+
+211
+00:19:03,370 --> 00:19:09,690
+بنصير نحكي عنcyclic ether ممكن تكون ال O بحلقة
+
+212
+00:19:09,690 --> 00:19:14,130
+ثلاثية ممكن تكون بحلقة رباعية ممكن تكون بحلقة
+
+213
+00:19:14,130 --> 00:19:18,350
+خماسية سوداسية خلينا بس نعود التذكير بالحلقة
+
+214
+00:19:18,350 --> 00:19:22,650
+الثلاثية وانا بتهيأ له مرت علينا الحلقة الثلاثية
+
+215
+00:19:22,650 --> 00:19:28,410
+بتفاعل ال alkyls واضح؟ هذه وين مرت علينا ال
+
+216
+00:19:28,410 --> 00:19:35,270
+ethylene oxide لما كان يكون عندي ethyleneCH2 CH2
+
+217
+00:19:35,270 --> 00:19:43,230
+مع البروكساكبراسيت كان يعطينا الابوكسايد لاحظوا مع
+
+218
+00:19:43,230 --> 00:19:50,130
+الابوكسايد هو اسم عائلة لكن المركب نفسه بنسميه إما
+
+219
+00:19:50,130 --> 00:19:55,230
+إفليل أوكسايد أو أوكس إيرين في الكيميا الحلقية غير
+
+220
+00:19:55,230 --> 00:20:01,030
+المتجانسة هذا المركب شو بيسموه أوكس إيرين بنسميه
+
+221
+00:20:01,030 --> 00:20:07,130
+أوكس إيرينأو لأنه إجاب للإيثالين بنقول عنه إيثالين
+
+222
+00:20:07,130 --> 00:20:13,190
+أكسايد الأن لو حطيت هنا مثل معنى ذلك الألكين الأصل
+
+223
+00:20:13,190 --> 00:20:18,830
+اللي كان عندي CH3 CH double bond CH2 بروبيل أو
+
+224
+00:20:18,830 --> 00:20:23,590
+بروبيلين بناء على ذلك المراكب شو حيصير بروبيلين
+
+225
+00:20:23,590 --> 00:20:31,780
+أكسايدطيب، لو كان عنده واحد، اتنين، تلاتة، أربعة
+
+226
+00:20:31,780 --> 00:20:37,200
+وكانت الـ double bond هنا الـ butane هيكون one
+
+227
+00:20:37,200 --> 00:20:40,160
+butane oxide، تنسوش الـ butane كان فيه منه one
+
+228
+00:20:40,160 --> 00:20:44,540
+butane وكان فيه منه two butane، الآن هذا على أي
+
+229
+00:20:44,540 --> 00:20:48,180
+double bond إجا؟ على الـ one، إذا هذا one butane
+
+230
+00:20:48,180 --> 00:20:52,780
+oxide طبعا، ممكن نفس المراكبات ينسميها نسبة إلى
+
+231
+00:20:52,780 --> 00:20:57,000
+الـ oxiraneهذه الحلقة بدون أي substituent ايش
+
+232
+00:20:57,000 --> 00:21:01,740
+اسمها Oxirane وترقيمها دائما يبدأ من ال Oxygen
+
+233
+00:21:01,740 --> 00:21:07,020
+واحد اتنين هنا على موقع اتنين شو بتحمل مثل اذا هذا
+
+234
+00:21:07,020 --> 00:21:16,600
+مثل او two مثل Oxirane لو طلعنا على المركب اللي
+
+235
+00:21:16,600 --> 00:21:23,870
+بعده هاي واحدتو مثل أوكز إيران لاحظوا معاك يمكن
+
+236
+00:21:23,870 --> 00:21:29,530
+هنا في الكتابة مش كاتبين احنا ال two ليش مش
+
+237
+00:21:29,530 --> 00:21:34,870
+كاتبينها؟ لأنه مافيش احتمال تاني يعني لو اجت المثل
+
+238
+00:21:34,870 --> 00:21:39,370
+هنا بده تكون two مثل طب لو حطيناها هنا بنعدنا هنا
+
+239
+00:21:39,370 --> 00:21:43,070
+two مثل يعني لمثل واحدة لا يمكن الا تكون على موقع
+
+240
+00:21:43,070 --> 00:21:46,130
+اتنين فيه ولمثل واحدة لا يمكن الا تكون على موقع
+
+241
+00:21:46,130 --> 00:21:54,010
+اتنينلكن لو صار عندي مثلا زي هذا المركب هاي carbon
+
+242
+00:21:54,010 --> 00:21:58,430
+تنتين تلاتة أربعة كان هنا double bond وكان المركب
+
+243
+00:21:58,430 --> 00:22:03,390
+cis-2-butyl فعلنا مع ال bare acid بيعطينا cis-2
+
+244
+00:22:03,390 --> 00:22:07,230
+-butyl oxide في ال common name لو أجينا بنسميه على
+
+245
+00:22:07,230 --> 00:22:09,730
+تسمية الكيمياء الحلقية
+
+246
+00:22:15,980 --> 00:22:21,160
+على موقع اتنين و تلاتة منها، شوفي عندي، Dimethyl،
+
+247
+00:22:21,160 --> 00:22:26,140
+في هذه الحالة أنا صرت مضطر ان احط الأرقام، ليش؟
+
+248
+00:22:26,140 --> 00:22:30,400
+لأنه لو عندي مجموعتين مثل اللي هم اكتر من احتمال،
+
+249
+00:22:30,400 --> 00:22:34,400
+انا كان .. لأ، واحد مستحيل، لأن ال Oxygen ما
+
+250
+00:22:34,400 --> 00:22:37,460
+بيحملش اشي تاني، ال Oxygen بس رابطتين، ايش
+
+251
+00:22:37,460 --> 00:22:43,040
+الاحتمال التاني؟ ايش الاحتمال التاني لما يكون عندي
+
+252
+00:22:43,040 --> 00:22:45,120
+مجموعتين مثل على ال Oxygen؟
+
+253
+00:22:50,280 --> 00:22:53,800
+بعيدا .. هذا عشانه معاجيها واحدة بنقول cis مش
+
+254
+00:22:53,800 --> 00:23:02,120
+مختلفين أنا بدي على المواقع ايوة من اتنين ممكن
+
+255
+00:23:02,120 --> 00:23:08,840
+مجموعتين المثل يكونوا هنا لو أتيكم هذا المركب صموه
+
+256
+00:23:08,840 --> 00:23:13,640
+في الامتحان شو هتصموه في هذه الحلقة؟ one two three
+
+257
+00:23:13,640 --> 00:23:18,580
+two two die مثل Ox and Rail طب لو سألناك هو هذا
+
+258
+00:23:18,580 --> 00:23:23,740
+cis ولا trans؟مافيش دائرة الـ cis والترانس هنا
+
+259
+00:23:23,740 --> 00:23:27,540
+لأنه احنا سبق قلنا دائرة ال cis والترانس سواء
+
+260
+00:23:27,540 --> 00:23:31,560
+حوالين ال double bond او حوالين الحلقة بتطلب انه
+
+261
+00:23:31,560 --> 00:23:36,200
+كل كربونا يكون عليها مجموعتين مختلفتين مجموعتين
+
+262
+00:23:36,200 --> 00:23:39,920
+مختلفتين اذا هنا في عند دائرة ال cis والترانس فعلا
+
+263
+00:23:39,920 --> 00:23:44,000
+هي ال cis two three dimethyl oxirane وهذا لما يكون
+
+264
+00:23:44,000 --> 00:23:50,440
+عكس بعض لترانس two three dimethyl oxirane واضح؟
+
+265
+00:23:53,560 --> 00:23:58,600
+الان هذه ال Oxirans لما قولنالكوا كيف بتتحطر ذكرنا
+
+266
+00:23:58,600 --> 00:24:02,320
+انها بشكل أساسي من ال bare acids يعني هاي مثلا
+
+267
+00:24:02,320 --> 00:24:11,240
+Cyclohexane مع bare acid بيعطيني Cyclohexane Oxide
+
+268
+00:24:12,210 --> 00:24:17,490
+أو إثنين سواء مع Fair Acid أو صناعيا لأنه يلزمنا
+
+269
+00:24:17,490 --> 00:24:20,910
+كتير ال Oxirane بيحضروا مع ال Oxygen في وجود
+
+270
+00:24:20,910 --> 00:24:26,330
+silver catalyst ودرجة حرارة 250 وضغط برضه بيعطينا
+
+271
+00:24:26,330 --> 00:24:31,290
+ال Oxirane واضح؟إذن هي العملية في الآخر Oxidation
+
+272
+00:24:31,290 --> 00:24:34,710
+لا ال الكنز الكبيرة بيستعملوا ال bare acids ال
+
+273
+00:24:34,710 --> 00:24:38,410
+إيثيلين لأنه صناعة و الصناعة هي اللي فيها استعمال
+
+274
+00:24:38,410 --> 00:24:41,730
+درجات حرارة عالية و استعمال ضغط و ما إلى ذلك
+
+275
+00:24:41,730 --> 00:24:46,510
+فبياخدوا إيثيلين مع أكسجين silver catalyst حرارة
+
+276
+00:24:46,510 --> 00:24:54,150
+ضغط بيعطينا الأمس إليههذا الـ Oxirane اللي هو أبسط
+
+277
+00:24:54,150 --> 00:24:59,610
+Cyclic Ether لكن هذا Cyclic Ether مهم كتير لأنه له
+
+278
+00:24:59,610 --> 00:25:05,710
+تطبيقات في التحضيرات العضوية وانا بتهيأها ليه؟ انه
+
+279
+00:25:05,710 --> 00:25:06,670
+احنا أخدنا
+
+280
+00:25:09,100 --> 00:25:14,940
+طبعته احنا أخدنا بعض التطبيقات تبعته لما نيجي
+
+281
+00:25:14,940 --> 00:25:20,400
+نفعله اول اشي لازم نعمل التفاعل ب acidic medium
+
+282
+00:25:20,400 --> 00:25:23,800
+لازم نعمل التفاعل ب acidic medium بيعمل
+
+283
+00:25:23,800 --> 00:25:27,340
+protonation هنا الان بعديك لو فعلنا مع الميه الميه
+
+284
+00:25:27,340 --> 00:25:28,960
+بتحط any uq file
+
+285
+00:25:32,960 --> 00:25:38,440
+واضح اذا كأنه الميه او اي ال يوكليوفايل انتم
+
+286
+00:25:38,440 --> 00:25:42,080
+تتخيلوا ان هذا ال oxirid معاي ال يوكليوفايل بده
+
+287
+00:25:42,080 --> 00:25:46,180
+يهاجم لليوكليوفايل بهذا الشكل وهذا الرابط تكسل
+
+288
+00:25:46,180 --> 00:25:55,620
+فبصير عند ال يوكليوفايل هاي ال يوكليوفايل CH2 كمان
+
+289
+00:25:55,620 --> 00:25:59,540
+CH2 OH
+
+290
+00:26:00,800 --> 00:26:05,280
+هذا الجزء اللى حاطينه احنا هنا فى الدائرة من وين
+
+291
+00:26:05,280 --> 00:26:11,460
+اتى من الـ Ox-Urane وهذا النيوكليوفايل اللى بيهجم
+
+292
+00:26:11,460 --> 00:26:17,440
+هذه الكربونة فبصير عندنا هنا CH2 CH2 OH وهذا
+
+293
+00:26:17,440 --> 00:26:21,860
+النيوكليوفايل اللى من برا واضح مثلا لو كان عندكم
+
+294
+00:26:21,860 --> 00:26:23,500
+النيوكليوفايل Methanol
+
+295
+00:26:30,420 --> 00:26:35,440
+ال O مثل كأنه لنيكوليوفايل هنا O مثل لو كان عندكم
+
+296
+00:26:35,440 --> 00:26:40,420
+مثلا إثالين غلايكول واحدة من هدولة ال O H بتهاجم
+
+297
+00:26:40,420 --> 00:26:48,460
+بتفتح حلقة CH2 CH2 OH لو كان عندكم فين ال MgBr مار
+
+298
+00:26:48,460 --> 00:26:53,340
+عليكم فين ال MgBr يمكن المحاضرة الماضية هذا اللي
+
+299
+00:26:53,340 --> 00:26:58,350
+سمناه احنا ايش؟الـ Greenyard Reagent والـ
+
+300
+00:26:58,350 --> 00:27:02,370
+Greenyard Reagent اتفقنا ان هو يمثل الـ
+
+301
+00:27:02,370 --> 00:27:09,130
+nucleophile بمعنى فنل مع زوج الالكترونات، تطلعوا
+
+302
+00:27:09,130 --> 00:27:14,490
+هنا زوج الالكترونات كأنه تابع لمن؟ للفنل، بناء على
+
+303
+00:27:14,490 --> 00:27:17,970
+ذلك هذا زوج الالكترونات اللي على الفنل هو اللي
+
+304
+00:27:17,970 --> 00:27:21,630
+بيجي يهاجمها لو بتكون طابقوا على هذه المعادلة كأن
+
+305
+00:27:21,630 --> 00:27:26,310
+اللي عندكم هي فنلهيزوج الإلكترونات بيهاجم هنا
+
+306
+00:27:26,310 --> 00:27:35,310
+بيعمل ال bond بيصير عندي CH2 CH2 finally OH واضح؟
+
+307
+00:27:36,680 --> 00:27:41,280
+إذا لو احنا بنجي .. بنجيبلكوا سؤال synthesis كيف
+
+308
+00:27:41,280 --> 00:27:46,940
+ممكن نتحضروا مركب إذا لمحتوا في هذا المركب مجموعة
+
+309
+00:27:46,940 --> 00:27:52,920
+CH2 CH2 OH إذا بإمكانكوا تتخيلوا أن هذه المجموعة
+
+310
+00:27:52,920 --> 00:28:01,290
+أصلها كان Oxirane واضح؟ إذا لمحتوا مجموعةالـ CH2
+
+311
+00:28:01,290 --> 00:28:06,830
+CH2 OH بتكون تصيروا تفكروا أن هذه المجموعة الأصل
+
+312
+00:28:06,830 --> 00:28:12,910
+تبعها كان Oxirane لأن حلقة Oxirane بتفتح لما تتفعل
+
+313
+00:28:12,910 --> 00:28:19,590
+مع ال eucleophiles و بتعطينا مركبات تحتوي على هذه
+
+314
+00:28:19,590 --> 00:28:21,450
+المجموعة CH2 CH2 OH
+
+315
+00:28:27,970 --> 00:28:33,090
+تنسوش تحطوا ال O هذي اللي مانسية في الراسي أول
+
+316
+00:28:33,090 --> 00:28:42,890
+مركّب O H طبعا
+
+317
+00:28:42,890 --> 00:28:49,910
+ال cyclic ethers مش بس حلقات ثلاثية ممكن يكونوا
+
+318
+00:28:49,910 --> 00:28:55,640
+موجودين على شكلحلقة رباعية ممكن يكون يعني رباعية
+
+319
+00:28:55,640 --> 00:28:59,840
+يعني زي هيك oxygen و أربع ذضار ممكن يكونوا على شكل
+
+320
+00:28:59,840 --> 00:29:05,440
+حلقات خماسية ممكن سداسية ممكن في حلقات سداسية يكون
+
+321
+00:29:05,440 --> 00:29:08,160
+فيها two oxygens يعني
+
+322
+00:29:13,210 --> 00:29:18,250
+واضح؟ الان المركب اللى فى حلقة ربعية مش كتير
+
+323
+00:29:18,250 --> 00:29:24,250
+مشهوره يمكن عشان هيك احنا مش راسمينه بيسموه OXYZ
+
+324
+00:29:24,250 --> 00:29:31,250
+مش كتير مشهور المركب اللى فى حلقة خماسية هذا مشهور
+
+325
+00:29:31,250 --> 00:29:36,590
+كتير هذا يستعمل فى الكيميا القضوية ك solvent اسمه
+
+326
+00:29:39,570 --> 00:29:44,370
+واختصاره THF كتير بتلاحظوا موجود عندكم solvent
+
+327
+00:29:44,370 --> 00:29:49,450
+اسمه THF أو Tetrahydrofuran هذا عبارة عن Cyclic
+
+328
+00:29:49,450 --> 00:29:53,450
+Ether الأن المركب اللي في الحلقة السادسية
+
+329
+00:29:53,450 --> 00:29:56,590
+Tetrahydropyrene
+
+330
+00:29:56,590 --> 00:30:04,100
+Tetrahydropyrene إذا كان في عندكأكسجنتين في الحلقة
+
+331
+00:30:04,100 --> 00:30:08,440
+السادسية بيصير المركب اللي اسمه دايوكسين هذا
+
+332
+00:30:08,440 --> 00:30:14,740
+الديوكسين هو عبارة عن مركب سام كارسينوجينيك مركب
+
+333
+00:30:14,740 --> 00:30:19,380
+كارسينوجينيك سام الديوكسينيمكن بتذكروا من عدة
+
+334
+00:30:19,380 --> 00:30:26,240
+سنوات يمكن قبل حوالي خمس سنين، ستة الأسبان اكتشفوا
+
+335
+00:30:26,240 --> 00:30:29,600
+الناس أنه في الزيوت اللي بيبيعوها زيت الزتون فيه
+
+336
+00:30:29,600 --> 00:30:33,920
+دايوكسين سام وبناء على ذلك سحبوا كل شحنات زيت
+
+337
+00:30:33,920 --> 00:30:38,400
+الزتون تبعتهم من مصر ومن السعودية ومن اليمن ليش كل
+
+338
+00:30:38,400 --> 00:30:43,860
+هذا الكلام صار؟ لأنه لقوا أن هذه مخلوطة بدايوكسين
+
+339
+00:30:45,110 --> 00:30:49,010
+لجوا انه فيها نسبة ديوكسين هم الحقيقة لما ياخدوا
+
+340
+00:30:49,010 --> 00:30:54,070
+بقايا الزيوت يعملولها استخلاص و extraction ب
+
+341
+00:30:54,070 --> 00:30:58,690
+solvents زي ال .. زي ال hexanes و ال heptanes و ال
+
+342
+00:30:58,690 --> 00:31:04,250
+.. هي ال .. ال fuels هذه بيكون جزء منها ديوكسين و
+
+343
+00:31:04,250 --> 00:31:07,690
+ضال مخلوط مع الزيت فلما بيحللوا الزيت لجوا فيه
+
+344
+00:31:07,690 --> 00:31:14,670
+نسبة ديوكسين فسحبوا الزيوت تبعتهم من الأسواق واضح؟
+
+345
+00:31:15,720 --> 00:31:22,760
+غير هدول المُركّبات، في عيلة جديدة تدخل الجمال،
+
+346
+00:31:22,760 --> 00:31:25,120
+يعني الواحدة ليها خطر، وغيرها كلها بالفعلات
+
+347
+00:31:25,120 --> 00:31:32,380
+التطريزيةاللي هم مجموعة مُركّبات اكتشفت حديثًا،
+
+348
+00:31:32,380 --> 00:31:35,720
+يعني مش زمان تم اكتشافها، يعني الناس اللي اشتغلوا
+
+349
+00:31:35,720 --> 00:31:40,140
+عليها اشتغلوا تقريبًا في أوائل التمانينات،
+
+350
+00:31:40,140 --> 00:31:43,520
+وبالنسبة لنا أوائل التمانينات ما تُعتبرش بعيدة
+
+351
+00:31:43,520 --> 00:31:47,640
+نسبيًا، لأنه احنا بنحكي أحيانًا عن بعض الشغلات قبل
+
+352
+00:31:47,640 --> 00:31:51,920
+مية ومية وخمسين سنةيعني بتذكروا لما حكينا مثلا عن
+
+353
+00:31:51,920 --> 00:32:00,440
+البنزين .. البنزين اكتشافه كسائل كان 1825 يعني قبل
+
+354
+00:32:00,440 --> 00:32:06,180
+حوالي 200 سنة لما نحكي مثلا عن green yard reagent،
+
+355
+00:32:06,180 --> 00:32:12,540
+green yard أخد جائزة نوبل في الكيميا سنة 1911هذا
+
+356
+00:32:12,540 --> 00:32:16,400
+بالظبط قبل مائة سنة، مظبوط ولا لا؟ لكن هدولة
+
+357
+00:32:16,400 --> 00:32:19,900
+المركبات الحلوين اللي موجودين هنا بيسموهم ال crown
+
+358
+00:32:19,900 --> 00:32:24,740
+ethers ال crown ethers هدولة في ال .. في
+
+359
+00:32:24,740 --> 00:32:28,580
+التمانينات اكتشفوا و الناس اللي اشتغلوا عليهم و
+
+360
+00:32:28,580 --> 00:32:31,780
+طلعوهم أخدوا عليهم جائزة نوبل في الكيميا بالألف
+
+361
+00:32:31,780 --> 00:32:37,360
+تسعمائة و سبعة و ثمانين ألف
+
+362
+00:32:37,360 --> 00:32:41,440
+تسعمائة و سبعة و ثمانين سنة ميلادكوا ولا برضه قبل؟
+
+363
+00:32:42,950 --> 00:32:48,470
+خلاص خلاص انتوا مولد 2010 فيعتبروا
+
+364
+00:32:48,470 --> 00:32:52,630
+نسبية نجدال ايش هم هدولة ال crown ethers اللي لهم
+
+365
+00:32:52,630 --> 00:32:58,250
+الأهمية زي ما انتوا بتلاحظوا Cyclic ethers فيهم
+
+366
+00:32:58,250 --> 00:33:03,410
+تكرار لمجموعة CH2 CH2 و بعدين Oxygen CH2 CH2 و
+
+367
+00:33:03,410 --> 00:33:06,690
+بعدين Oxygen CH2 CH2 و بعدين Oxygen CH2 CH2 و
+
+368
+00:33:06,690 --> 00:33:11,920
+بعدين Oxygen و ممكن يكونوا على عدةأحجام ممكن يكون
+
+369
+00:33:11,920 --> 00:33:16,540
+على عدة أحجام الان كيف بيجوا بيسموهم لما يجوا
+
+370
+00:33:16,540 --> 00:33:20,180
+يسموهم خلينا نبدأ نعد من أي نقطة يعني لو بدأنا من
+
+371
+00:33:20,180 --> 00:33:24,640
+هنا و اتحركنا نعد كل الظرات واحد اتنين تلاتة اربعة
+
+372
+00:33:24,640 --> 00:33:28,660
+خمسة ستة سبعة تمانية تسعة عشرة احد عشر اتمعش
+
+373
+00:33:28,660 --> 00:33:34,890
+فبنقول هذا المركب اتمعش اتمعش هي العدد الكليللضرر
+
+374
+00:33:34,890 --> 00:33:38,590
+بعد ذلك بيقول crown معناه crown انه بيدرسله استعمل
+
+375
+00:33:38,590 --> 00:33:45,570
+CH2 CH2 O CH2 CH2 O و بعدين بيحط عدد الأكسجين كام
+
+376
+00:33:45,570 --> 00:33:51,450
+أكسجين اربعة اذا هنا بيقول twelve crown four معناه
+
+377
+00:33:51,450 --> 00:33:57,110
+total atoms twelve و عدد الأكسجين four
+
+378
+00:34:01,100 --> 00:34:05,280
+واضح؟ الان لو اجينا على هذا و عدينا مثلا من هنا و
+
+379
+00:34:05,280 --> 00:34:12,160
+اتحركنا 15 atoms فبصير 15 crown 5 لو اجينا على
+
+380
+00:34:12,160 --> 00:34:17,860
+اللي بعده و عدينا 18 ثغرة بكم أكسجينة؟ 6 أكسجينات
+
+381
+00:34:17,860 --> 00:34:26,940
+فبصير 80 crown 8 80 crown 6 طبعا بيلزمكم اتدربوا
+
+382
+00:34:26,940 --> 00:34:30,820
+ايدكم على رسمهأنا المرة اللى فاتت فى الامتحان
+
+383
+00:34:30,820 --> 00:34:36,920
+جبتلهم ارسمولى 18 crown 6 لو
+
+384
+00:34:36,920 --> 00:34:41,100
+جبنالكوا فى الامتحان ارسموا 18 crown 6 انتوا
+
+385
+00:34:41,100 --> 00:34:47,220
+بتفكروه سهل هل كانت تروحوا بهدوء و جربوا ارسموا
+
+386
+00:34:47,220 --> 00:34:50,880
+هتلاقوا هتخربشوا مية مرة قبل ما تظبطوا فعوضوا
+
+387
+00:34:50,880 --> 00:34:54,760
+حالكم دائما ال organic بدها تطبيق باليد عشان
+
+388
+00:34:54,760 --> 00:35:01,660
+ترسموا الشكلهذه المراكبات الحقيقة ليش الناس اللي
+
+389
+00:35:01,660 --> 00:35:06,920
+اشتغلوها أخدوا عليها جوائز وتعتبر مراكبات مهمة ..
+
+390
+00:35:06,920 --> 00:35:14,170
+تعتبر مراكبات مهمة لأن في إلها كثير تطبيقاتجزء ..
+
+391
+00:35:14,170 --> 00:35:18,810
+جزء من التطبيقات تبعتها أنه أنا طالما عندي ..
+
+392
+00:35:18,810 --> 00:35:22,610
+طالما عندي oxygens هنا و ال oxygens بتحمل إيش؟
+
+393
+00:35:22,610 --> 00:35:28,170
+أزواج .. إلكترونات، مصبوط ولا لأ؟ إذن، و الجزء هنا
+
+394
+00:35:28,170 --> 00:35:34,250
+إحنا بنقول إله cavity عارفين إيش يعني cavity؟
+
+395
+00:35:34,250 --> 00:35:38,870
+cavity الوسعة أو الفراغة الدهانة، هذه cavity،
+
+396
+00:35:38,870 --> 00:35:46,480
+الحفرةواضح الفجوة الجزء له cavity الان هذه ال
+
+397
+00:35:46,480 --> 00:35:51,260
+cavity ممكن يدخل فيها ايون موجب الايون الموجب ليش
+
+398
+00:35:51,260 --> 00:35:55,280
+بيجي بدخلها لو بتريح لأنه في أزواج إلكترونات يعمل
+
+399
+00:35:55,280 --> 00:36:01,950
+bonding معاها يعني نحط هنا metal plusملاحظين انتوا
+
+400
+00:36:01,950 --> 00:36:06,450
+metal plus ممكن يدخل بالفجوة الان اذا انتوا
+
+401
+00:36:06,450 --> 00:36:12,150
+بتيجيوا تتطلعوا هنا الفجوة
+
+402
+00:36:12,150 --> 00:36:17,550
+بتعتمد على نوع ال ether يعني هذا ال ether ال 12
+
+403
+00:36:17,550 --> 00:36:23,250
+crown 4 قارن الفجوة تبعته مع ال 15 crown 5 قارن
+
+404
+00:36:23,250 --> 00:36:29,830
+الفجوة تبعته معالـ 18 crown 6 بتلاحظوا ان حجم
+
+405
+00:36:29,830 --> 00:36:37,770
+الفجوات مختلف هذا الكلام اشبدل على ان الايونات
+
+406
+00:36:37,770 --> 00:36:43,690
+المعدنية حجمها مختلف فكأنه كل فجوة بتتناسب مع حجم
+
+407
+00:36:43,690 --> 00:36:50,990
+ايون معين كل فجوة بتتناسب مع حجم ايون معين بمعنى
+
+408
+00:36:50,990 --> 00:36:56,700
+لو انا هنا حطيت ايون كبير بصبطبتسعش الفجوة، لو أنا
+
+409
+00:36:56,700 --> 00:37:01,480
+حطيت هنا أيون صغير كتير، بيطلع من الفجوة، بيعملش
+
+410
+00:37:01,480 --> 00:37:06,560
+ارتباط، لازم ال أيون يكون جد و جدالفجوة تقريبا
+
+411
+00:37:06,560 --> 00:37:12,900
+فبناء على ذلك بيستفيدوا من هذه الشغلة في الصناعة
+
+412
+00:37:12,900 --> 00:37:18,540
+وفي ال biology مثلا لو انا اجيت اخدت تلت ايونات ال
+
+413
+00:37:18,540 --> 00:37:23,640
+sodium و ال potassium و ال cesium وشوفت قداش ال
+
+414
+00:37:23,640 --> 00:37:30,080
+diameter تبعهم قداش القطر تبعهم ال sodium قطره 1.9
+
+415
+00:37:30,080 --> 00:37:33,080
+angstrom ال potassium 2.6
+
+416
+00:37:36,290 --> 00:37:43,250
+3.34 الان لو جيت جبت هذا المُركّب وقصد قداش الفجوة
+
+417
+00:37:43,250 --> 00:37:48,050
+تبعته كل العلماء بيشتغلوا بقصه ال cavity تبعته 2.6
+
+418
+00:37:48,050 --> 00:37:55,230
+إلى 3.2 cavity تقريبا الان لو جيت قولت أحط هذا ال
+
+419
+00:37:55,230 --> 00:38:00,150
+crown إيثر في محلول يحتوي على التلت أيونات هدولة
+
+420
+00:38:00,150 --> 00:38:02,590
+ان هو اللي بيصبط معه ال potassium
+
+421
+00:38:05,360 --> 00:38:11,400
+هذا متناسب مع هذه الفجوة بناء على ذلك لو كان عندي
+
+422
+00:38:11,400 --> 00:38:16,100
+محلول فيه تلت أيونات و حطيت هذا ال crown بياخد ال
+
+423
+00:38:16,100 --> 00:38:19,860
+potassium و يسيب التنين التانين اتلاحظين انتوا؟
+
+424
+00:38:19,860 --> 00:38:25,920
+يعني ال cavity تبعته بس على جد ال potassium ال
+
+425
+00:38:25,920 --> 00:38:33,040
+cavity تبعته بس على جد ال potassiumمش على جد
+
+426
+00:38:33,040 --> 00:38:39,660
+السيزيام كبير ولا السوديوم يعتبر صغير واضح؟ يمكن
+
+427
+00:38:39,660 --> 00:38:45,120
+هذا الكلام يلو تطبيق فتفتر أكثر فتفتر احنا ناخد
+
+428
+00:38:45,120 --> 00:38:51,360
+نظرينا ان السوديوم بما انه تكره عيب كبير دائمية
+
+429
+00:38:51,360 --> 00:38:54,620
+ارتباط كفر كفر يعني من الحكي الكبير بوصل لصغير
+
+430
+00:38:54,620 --> 00:38:58,760
+بعكس اللي .. اه بس لصغير اللي هو بده يعمل ارتباط
+
+431
+00:38:59,460 --> 00:39:05,020
+بدو يعمل ارتباط، واضح؟ بدو يعمل ارتباط، هل بيقدر و
+
+432
+00:39:05,020 --> 00:39:09,580
+هو صغير، هاي كل حجم الـmetal في درجة، هالجد و هاي
+
+433
+00:39:09,580 --> 00:39:13,580
+حجم الخضر، هل بيقدر يصل لهدول أزواج الإلكترونية
+
+434
+00:39:13,580 --> 00:39:17,260
+يعمل ارتباط معهم؟ مابقدرش يعمل ارتباط، زي ما هذا
+
+435
+00:39:17,260 --> 00:39:21,700
+رابط من كل الجهةهذا لما يكون بهذا الشكل القطر تبعه
+
+436
+00:39:21,700 --> 00:39:28,000
+فيمكن يعمل ال bonding بس لصغير لا مابظبطش هذا
+
+437
+00:39:28,000 --> 00:39:32,380
+الكلام له حقيقة تطبيقات كتير سواء في الكيميا
+
+438
+00:39:32,380 --> 00:39:38,680
+ككيميا او في الفروع الطبية المتعلقة بالكيميا مثلا
+
+439
+00:39:38,680 --> 00:39:43,460
+جزء من تطبيقاته ان لو انا اخدت مركب ايوني زي ال
+
+440
+00:39:43,460 --> 00:39:50,400
+potassium permanganate ال KMnO4هذا الكيامان او فور
+
+441
+00:39:50,400 --> 00:39:56,500
+تخيل لو انا قلت ادوب في البنزين البنزين مش البنزين
+
+442
+00:39:56,500 --> 00:40:03,090
+solvent الكيامان او فور في البنزين لا يدوبمابيدوبش
+
+443
+00:40:03,090 --> 00:40:08,970
+ليش مابيدوبش لأن هذا الـ KMnO4 K Plus MnO4 minus
+
+444
+00:40:08,970 --> 00:40:13,090
+Ionic وهذا Non Ionic وانتوا القاعدة العامة اللي
+
+445
+00:40:13,090 --> 00:40:16,570
+عندكم في الذابية Like Dissolve Like هذا و هذا مش
+
+446
+00:40:16,570 --> 00:40:21,350
+من نفس الأشياء هذا Ionic وهذا مش Ionic بناء على
+
+447
+00:40:21,350 --> 00:40:26,730
+ذلك لو أنا لغرض التفاعل بدي أفعل مركب الـ KMnO4 في
+
+448
+00:40:26,730 --> 00:40:33,170
+البنزينما بيدوبش طب كيف بيدوبوه بيجوا جوا البنزين
+
+449
+00:40:33,170 --> 00:40:38,210
+جوا البنزين يعني ال servant اللي عنده بنزين بيحطوا
+
+450
+00:40:38,210 --> 00:40:45,970
+ال crown هذا اللي هو ال 18 crown 6 بيحطوا ال 18
+
+451
+00:40:45,970 --> 00:40:51,830
+crown 6 هذا ال 18 crown 6 لما انا بدي احط kmn04
+
+452
+00:40:51,830 --> 00:41:00,980
+ايش بيعمل؟ بياخد ال Kفي الـ cavity تبعته صارت دوّب
+
+453
+00:41:00,980 --> 00:41:05,400
+المُركّب لأن الـ crown بيدوب في البنزين و الـ
+
+454
+00:41:05,400 --> 00:41:10,780
+crown بيدوّب البوتاسيوم في قلبه بيحط البوتاسيوم في
+
+455
+00:41:10,780 --> 00:41:14,660
+قلب الـ cavity تبعته وبناء على ذلك برمجانات
+
+456
+00:41:14,660 --> 00:41:20,300
+البوتاسيوم مع البنزين لا تدوب مع بنزين مخلوط فيه
+
+457
+00:41:20,300 --> 00:41:25,420
+شوية crown بيدوب أنا مش مهم عندي لغرض التفاعل
+
+458
+00:41:25,420 --> 00:41:30,390
+بالمناسبة لأن crownولا البوتاسيوم ولا البنزين
+
+459
+00:41:30,390 --> 00:41:34,070
+عارفين إنتوا إيش اللي أنا مهم عندى بالتفاعل؟ الأمن
+
+460
+00:41:34,070 --> 00:41:38,190
+O4 minus اللى ضالت حرة بتمشي فى البنزين لأنها عامل
+
+461
+00:41:38,190 --> 00:41:42,850
+مؤكسد لما درستوا الأكسدة و العوامل المؤكسدة أنه
+
+462
+00:41:42,850 --> 00:41:46,450
+اللى كان اسمه عامل مؤكسد ومهم كتير بالنسبة إليه
+
+463
+00:41:46,450 --> 00:41:51,190
+بيرمانجانات البوتاسيوم يعني إنه .. إن واحدة تيجي
+
+464
+00:41:51,190 --> 00:41:54,990
+تقول يا الله البوتاسيوم خسرناه راح جوا ال crownمع
+
+465
+00:41:54,990 --> 00:41:58,570
+السلامة، ما هو المطلوب؟ أنا المطلوب عندى لغرض
+
+466
+00:41:58,570 --> 00:42:04,190
+إجراء تفاعل X ده جزء البوتاسيوم على جزء الـMnO4-
+
+467
+00:42:04,190 --> 00:42:09,890
+فالبوتاسيوم خلّى يدوب في الـ crown و الـ MnO4-
+
+468
+00:42:09,890 --> 00:42:13,970
+بتصير تمشي في المحلول طبعا لاحظوا معى لما تمت
+
+469
+00:42:13,970 --> 00:42:19,400
+عملية ذابيها ديبرمجانات البوتاسيوم شو لونها؟بنفسجي
+
+470
+00:42:19,400 --> 00:42:26,220
+بناء على ذلك البنزين هنا بيصير لونه بنفسجي البنزين
+
+471
+00:42:26,220 --> 00:42:30,480
+اللي مدوق فيه برمجانات البوتاسيوم بمساعدة الـ
+
+472
+00:42:30,480 --> 00:42:35,240
+ethyl crown 6 بيسموه pear ball بنزينماذا يعني
+
+473
+00:42:35,240 --> 00:42:40,540
+بيربو البنزين؟ البنزين البنفسجي وهذا يعتبر
+
+474
+00:42:40,540 --> 00:42:45,900
+oxidizing agent عامل مؤكسد ليش عامل مؤكسد؟ بسبب
+
+475
+00:42:45,900 --> 00:42:49,280
+وجود مجموعة البرمانجانات الحرة ومجموعة
+
+476
+00:42:49,280 --> 00:42:54,820
+البرمانجانات من أفضل العوامل المؤكسدة، مظبوط ولا
+
+477
+00:42:54,820 --> 00:43:01,060
+لا؟ هذه تطبيق كيميائي استفدنا فيه من قصة الـ
+
+478
+00:43:01,060 --> 00:43:09,570
+cavityطبعا كتير مرات بيستعملوا .. بيستعملوا كلمات
+
+479
+00:43:09,570 --> 00:43:16,730
+موازية في اللغة العربية لفكرة الضيف والمضيف، يعني
+
+480
+00:43:16,730 --> 00:43:22,390
+لما هذا يكون هذا في وسع، إيش بنعتبره؟ مضيف، و
+
+481
+00:43:22,390 --> 00:43:25,830
+الآيون اللي بدأ يدخل فيه؟ ضيف، باللغة الإنجليزية
+
+482
+00:43:25,830 --> 00:43:33,120
+إيش بيقولوها؟host guest host guest هذا ال host و
+
+483
+00:43:33,120 --> 00:43:36,800
+ال potassium اللي إجا فيه ال guest إذا صار عندى
+
+484
+00:43:36,800 --> 00:43:40,340
+ضيف و مضيف host guest لكن في البنزين العكس صار
+
+485
+00:43:40,340 --> 00:43:44,960
+البنزين هو ال host لا أبدا أبدا في البنزين البنزين
+
+486
+00:43:44,960 --> 00:43:50,240
+solvent و ال crown دايب فيه دايب في البنزين الآن
+
+487
+00:43:50,240 --> 00:43:55,140
+إيش اللي إجا جوا ال crown ال K اللي إجا في قلبه
+
+488
+00:43:55,140 --> 00:44:03,670
+واضح؟هي هنا عندكم صورة شبيهة لمضاد حيوي يستعمل
+
+489
+00:44:03,670 --> 00:44:08,710
+شبيه فكرته زي ما بتلاحظوا بإيش بال crown ethers
+
+490
+00:44:08,710 --> 00:44:12,770
+وإن كان على أكبر لكن في عندكم هنا oxygens اشملها
+
+491
+00:44:12,770 --> 00:44:18,490
+متكررة بناء على ذلك هذه ال oxygens ممكن تحتوي ايون
+
+492
+00:44:18,490 --> 00:44:23,060
+في قلبها ولا لأ؟زي آيون البوتاسيوم وهذا المضاد
+
+493
+00:44:23,060 --> 00:44:28,620
+الحيوي بياخد تحديدا حسب حجم الـ cavity الفراغة
+
+494
+00:44:28,620 --> 00:44:32,180
+اللي فيها للبوتاسيوم و بيمشي في البوتاسيوم من داخل
+
+495
+00:44:32,180 --> 00:44:36,620
+جدار الخلية يعني شوفوا كيف عملية أنه بنتقل كل هذا
+
+496
+00:44:36,620 --> 00:44:39,680
+بدخل في جدار الخلية و بيدخل حامل معاه إيش؟
+
+497
+00:44:39,680 --> 00:44:44,600
+البوتاسيوم بيدخل جدار الخلية و بيدخل حامل معاه
+
+498
+00:44:44,600 --> 00:44:50,660
+البوتاسيومبهيك تقريبا بنكون انتهينا من هذا الفصل
+
+499
+00:44:50,660 --> 00:44:53,500
+اللي هو ال ether ومتعلقاته الحصة اللي جاي ان شاء
+
+500
+00:44:53,500 --> 00:44:55,340
+الله بنبدأ في ال aldi heights
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..dde856efe4f7ef37c11fd244528e9a395a1943b0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3334, "start": 7.36, "end": 33.34, "text": "بسم الله الرحمن الرحيم اتكلمنا المرة الماضية في موضوع ال ethers بشكل أساسي تسمية ال ethers وخواصها اليوم بنستمر في تناول هذا الموضوع هنتكلم على تحضير ال ethers و بعض تفاعلاتها زي التوسع في هذا المجال", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 1975, 2655, 4117, 19528, 8315, 9673, 25720, 9673, 46958, 10632, 8978, 3714, 2407, 11242, 45367, 2423, 6468, 433, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 6055, 38251, 10632, 2423, 6468, 433, 4032, 9778, 2407, 33546, 11296, 45595, 20498, 44945, 14851, 29973, 8978, 6055, 8315, 12610, 23758, 9673, 2407, 11242, 45367, 8032, 29399, 4117, 19528, 15844, 6055, 5016, 11242, 13546, 2423, 6468, 433, 4032, 45030, 11242, 6055, 5172, 995, 30241, 9307, 11296, 30767, 1829, 16712, 41779, 3615, 8978, 23758, 9673, 7435, 6027], "avg_logprob": -0.10533997154497839, "compression_ratio": 1.875, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 7.36, "end": 7.68, "word": "بسم", "probability": 0.87890625}, {"start": 7.68, "end": 7.84, "word": " الله", "probability": 0.9658203125}, {"start": 7.84, "end": 8.14, "word": " الرحمن", "probability": 0.9708658854166666}, {"start": 8.14, "end": 8.52, "word": " الرحيم", "probability": 0.994140625}, {"start": 8.52, "end": 10.52, "word": " اتكلمنا", "probability": 0.94765625}, {"start": 10.52, "end": 10.84, "word": " المرة", "probability": 0.9560546875}, {"start": 10.84, "end": 11.5, "word": " الماضية", "probability": 0.9949544270833334}, {"start": 11.5, "end": 13.0, "word": " في", "probability": 0.90478515625}, {"start": 13.0, "end": 13.52, "word": " موضوع", "probability": 0.9967041015625}, {"start": 13.52, "end": 13.74, "word": " ال", "probability": 0.9677734375}, {"start": 13.74, "end": 14.36, "word": " ethers", "probability": 0.462310791015625}, {"start": 14.36, "end": 14.82, "word": " بشكل", "probability": 0.97412109375}, {"start": 14.82, "end": 15.6, "word": " أساسي", "probability": 0.95703125}, {"start": 15.6, "end": 16.9, "word": " تسمية", "probability": 0.9684244791666666}, {"start": 16.9, "end": 17.12, "word": " ال", "probability": 0.9873046875}, {"start": 17.12, "end": 17.66, "word": " ethers", "probability": 0.706298828125}, {"start": 17.66, "end": 18.8, "word": " وخواصها", "probability": 0.83291015625}, {"start": 18.8, "end": 20.3, "word": " اليوم", "probability": 0.861083984375}, {"start": 20.3, "end": 21.64, "word": " بنستمر", "probability": 0.9261067708333334}, {"start": 21.64, "end": 22.06, "word": " في", "probability": 0.96044921875}, {"start": 22.06, "end": 23.28, "word": " تناول", "probability": 0.8938802083333334}, {"start": 23.28, "end": 23.56, "word": " هذا", "probability": 0.986328125}, {"start": 23.56, "end": 24.26, "word": " الموضوع", "probability": 0.9991455078125}, {"start": 24.26, "end": 26.02, "word": " هنتكلم", "probability": 0.921630859375}, {"start": 26.02, "end": 26.48, "word": " على", "probability": 0.79736328125}, {"start": 26.48, "end": 27.6, "word": " تحضير", "probability": 0.983642578125}, {"start": 27.6, "end": 28.1, "word": " ال", "probability": 0.99365234375}, {"start": 28.1, "end": 28.88, "word": " ethers", "probability": 0.883056640625}, {"start": 28.88, "end": 29.92, "word": " و", "probability": 0.7421875}, {"start": 29.92, "end": 30.18, "word": " بعض", "probability": 0.92138671875}, {"start": 30.18, "end": 31.26, "word": " تفاعلاتها", "probability": 0.93603515625}, {"start": 31.26, "end": 31.84, "word": " زي", "probability": 0.5264892578125}, {"start": 31.84, "end": 32.42, "word": " التوسع", "probability": 0.9874674479166666}, {"start": 32.42, "end": 32.6, "word": " في", "probability": 0.9873046875}, {"start": 32.6, "end": 32.76, "word": " هذا", "probability": 0.98828125}, {"start": 32.76, "end": 33.34, "word": " المجال", "probability": 0.99658203125}], "temperature": 1.0}, {"id": 2, "seek": 5543, "start": 33.95, "end": 55.43, "text": "الان يوم ما بيجيكم اي ether بتكونوا عارفين ان ال ether تقسم الى نوعين ممكن ال ether تكون symmetric بمعنى مجموعتين ال R اللي موجودات زي بعض يعني لما نقول اثل اثل هذا symmetric ether", "tokens": [6027, 7649, 7251, 20498, 19446, 4724, 1829, 7435, 1829, 24793, 1975, 1829, 37096, 39894, 30544, 14407, 6225, 9640, 5172, 9957, 16472, 2423, 37096, 6055, 4587, 38251, 2423, 7578, 8717, 45367, 9957, 3714, 43020, 2423, 37096, 6055, 30544, 32330, 4724, 2304, 3615, 1863, 7578, 3714, 7435, 2304, 2407, 34268, 9957, 2423, 497, 13672, 1829, 3714, 29245, 23328, 9307, 30767, 1829, 45030, 11242, 37495, 22653, 5296, 15042, 8717, 39648, 1975, 12984, 1211, 1975, 12984, 1211, 23758, 32330, 37096], "avg_logprob": -0.2883522758236179, "compression_ratio": 1.6589595375722543, "no_speech_prob": 0.0, "words": [{"start": 33.95, "end": 34.45, "word": "الان", "probability": 0.703857421875}, {"start": 34.45, "end": 34.87, "word": " يوم", "probability": 0.769775390625}, {"start": 34.87, "end": 35.01, "word": " ما", "probability": 0.767578125}, {"start": 35.01, "end": 35.53, "word": " بيجيكم", "probability": 0.83212890625}, {"start": 35.53, "end": 35.97, "word": " اي", "probability": 0.823974609375}, {"start": 35.97, "end": 36.59, "word": " ether", "probability": 0.383056640625}, {"start": 36.59, "end": 39.51, "word": " بتكونوا", "probability": 0.8426106770833334}, {"start": 39.51, "end": 40.09, "word": " عارفين", "probability": 0.81585693359375}, {"start": 40.09, "end": 40.39, "word": " ان", "probability": 0.8828125}, {"start": 40.39, "end": 40.83, "word": " ال", "probability": 0.5048828125}, {"start": 40.83, "end": 41.29, "word": " ether", "probability": 0.30224609375}, {"start": 41.29, "end": 42.21, "word": " تقسم", "probability": 0.8111979166666666}, {"start": 42.21, "end": 42.53, "word": " الى", "probability": 0.6953125}, {"start": 42.53, "end": 43.07, "word": " نوعين", "probability": 0.98974609375}, {"start": 43.07, "end": 44.27, "word": " ممكن", "probability": 0.82177734375}, {"start": 44.27, "end": 44.49, "word": " ال", "probability": 0.9365234375}, {"start": 44.49, "end": 45.01, "word": " ether", "probability": 0.64599609375}, {"start": 45.01, "end": 46.05, "word": " تكون", "probability": 0.884521484375}, {"start": 46.05, "end": 47.07, "word": " symmetric", "probability": 0.2474365234375}, {"start": 47.07, "end": 48.81, "word": " بمعنى", "probability": 0.9373046875}, {"start": 48.81, "end": 49.61, "word": " مجموعتين", "probability": 0.9095052083333334}, {"start": 49.61, "end": 49.85, "word": " ال", "probability": 0.8818359375}, {"start": 49.85, "end": 50.39, "word": " R", "probability": 0.362548828125}, {"start": 50.39, "end": 50.83, "word": " اللي", "probability": 0.6494140625}, {"start": 50.83, "end": 51.55, "word": " موجودات", "probability": 0.863525390625}, {"start": 51.55, "end": 51.83, "word": " زي", "probability": 0.833984375}, {"start": 51.83, "end": 52.27, "word": " بعض", "probability": 0.990234375}, {"start": 52.27, "end": 52.51, "word": " يعني", "probability": 0.6295166015625}, {"start": 52.51, "end": 52.73, "word": " لما", "probability": 0.75927734375}, {"start": 52.73, "end": 53.07, "word": " نقول", "probability": 0.963134765625}, {"start": 53.07, "end": 53.59, "word": " اثل", "probability": 0.6256917317708334}, {"start": 53.59, "end": 54.13, "word": " اثل", "probability": 0.97412109375}, {"start": 54.13, "end": 54.47, "word": " هذا", "probability": 0.5}, {"start": 54.47, "end": 54.97, "word": " symmetric", "probability": 0.488037109375}, {"start": 54.97, "end": 55.43, "word": " ether", "probability": 0.72216796875}], "temperature": 1.0}, {"id": 3, "seek": 7189, "start": 56.19, "end": 71.89, "text": "مثل مثل فنل فنل كل هذه عبارة عن symmetrical ethers وممكن ال ethers تكون unsymmetrical بمعنى يكون في عند مثلا اثل مع مثل او", "tokens": [2304, 12984, 1211, 50113, 1211, 6156, 1863, 1211, 6156, 1863, 1211, 28242, 29538, 6225, 3555, 9640, 3660, 18871, 40360, 6468, 433, 4032, 2304, 43020, 2423, 6468, 433, 6055, 30544, 2693, 32497, 32283, 4724, 2304, 3615, 1863, 7578, 7251, 30544, 8978, 43242, 50113, 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"probability": 0.9715169270833334}, {"start": 322.27, "end": 323.09, "word": " ROH،", "probability": 0.6630045572916666}, {"start": 323.09, "end": 323.37, "word": " لو", "probability": 0.982421875}, {"start": 323.37, "end": 323.81, "word": " فعلنا", "probability": 0.98828125}, {"start": 323.81, "end": 324.03, "word": " مع", "probability": 0.82763671875}, {"start": 324.03, "end": 324.25, "word": " ال", "probability": 0.69580078125}, {"start": 324.25, "end": 325.09, "word": " sodium،", "probability": 0.764404296875}, {"start": 325.09, "end": 325.45, "word": " كلكوا", "probability": 0.7135416666666666}, {"start": 325.45, "end": 325.97, "word": " عارفين", "probability": 0.99169921875}, {"start": 325.97, "end": 326.23, "word": " ان", "probability": 0.491455078125}, {"start": 326.23, "end": 326.57, "word": " ال", "probability": 0.74609375}, {"start": 326.57, "end": 326.91, "word": " sodium", "probability": 0.93212890625}, {"start": 326.91, "end": 327.55, "word": " بياخد", "probability": 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X", "probability": 0.62255859375}, {"start": 381.71, "end": 382.03, "word": " أي", "probability": 0.66748046875}, {"start": 382.03, "end": 382.33, "word": " R", "probability": 0.87744140625}, {"start": 382.33, "end": 382.79, "word": " تانية", "probability": 0.9654947916666666}, {"start": 382.79, "end": 384.21, "word": " نفترض", "probability": 0.83740234375}, {"start": 384.21, "end": 384.75, "word": " مثلا", "probability": 0.816650390625}, {"start": 384.75, "end": 386.77, "word": " CH3CL", "probability": 0.8082682291666666}, {"start": 386.77, "end": 388.17, "word": " الـ", "probability": 0.55419921875}, {"start": 388.17, "end": 388.57, "word": " RO", "probability": 0.32421875}, {"start": 388.57, "end": 389.03, "word": "-", "probability": 0.467529296875}, {"start": 389.03, "end": 389.63, "word": " هذه", "probability": 0.39794921875}, {"start": 389.63, "end": 390.23, "word": " بتيجي", "probability": 0.67742919921875}, {"start": 390.23, "end": 390.79, "word": " بتعمل", "probability": 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الأساسي لمُركّبات الـRX هو الـ Substitution واخدنا أنها ممكن تتم بـ Sn1 وممكن تتم بـ Sn2 ميكانيزم، واضحة؟ فكأنه أنا صار عندي هلأ بالتأكيد ر أو ماينوس هاجمت على R' X طلعت الـ X فبصير عندي ر أو ر ناتج واحد فقط ناتج واحد فقط", "tokens": [2407, 47283, 3215, 8315, 14739, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 32767, 10859, 31747, 11703, 3555, 9307, 2423, 39184, 49, 55, 31439, 2423, 39184, 42090, 6518, 4032, 47283, 3215, 8315, 14739, 11296, 3714, 43020, 6055, 39237, 4724, 39184, 9264, 16, 4032, 2304, 43020, 6055, 39237, 4724, 39184, 9264, 17, 3714, 1829, 41361, 1829, 11622, 2304, 12399, 4032, 46958, 5016, 3660, 22807, 6156, 4117, 33456, 3224, 41850, 20328, 9640, 43242, 1829, 8032, 1211, 10721, 20666, 2655, 10721, 4117, 25708, 12602, 34051, 19446, 9957, 41779, 8032, 26108, 2304, 2655, 15844, 497, 6, 1783, 23032, 1211, 34268, 2423, 39184, 1783, 6156, 3555, 9381, 13546, 43242, 1829, 12602, 34051, 12602, 8717, 9307, 7435, 36764, 24401, 6156, 47432, 8717, 9307, 7435, 36764, 24401, 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"word": " أنا", "probability": 0.255126953125}, {"start": 409.97, "end": 410.43, "word": " صار", "probability": 0.7427978515625}, {"start": 410.43, "end": 410.75, "word": " عندي", "probability": 0.572998046875}, {"start": 410.75, "end": 411.01, "word": " هلأ", "probability": 0.7802734375}, {"start": 411.01, "end": 411.77, "word": " بالتأكيد", "probability": 0.99443359375}, {"start": 411.77, "end": 412.11, "word": " ر", "probability": 0.1634521484375}, {"start": 412.11, "end": 412.33, "word": " أو", "probability": 0.365478515625}, {"start": 412.33, "end": 413.05, "word": " ماينوس", "probability": 0.7215169270833334}, {"start": 413.05, "end": 414.03, "word": " هاجمت", "probability": 0.8603515625}, {"start": 414.03, "end": 414.25, "word": " على", "probability": 0.91796875}, {"start": 414.25, "end": 414.51, "word": " R'", "probability": 0.8955078125}, {"start": 414.73, "end": 415.17, "word": " X", "probability": 0.6845703125}, {"start": 415.17, "end": 415.59, "word": " طلعت", "probability": 0.6158854166666666}, {"start": 415.59, "end": 415.81, "word": " الـ", "probability": 0.76513671875}, {"start": 415.81, "end": 416.01, "word": " X", "probability": 0.74609375}, {"start": 416.01, "end": 416.45, "word": " فبصير", "probability": 0.7861328125}, {"start": 416.45, "end": 416.77, "word": " عندي", "probability": 0.78662109375}, {"start": 416.77, "end": 417.03, "word": " ر", "probability": 0.36474609375}, {"start": 417.03, "end": 417.25, "word": " أو", "probability": 0.94287109375}, {"start": 417.25, "end": 417.59, "word": " ر", "probability": 0.548828125}, {"start": 417.59, "end": 418.69, "word": " ناتج", "probability": 0.94580078125}, {"start": 418.69, "end": 419.35, "word": " واحد", "probability": 0.99072265625}, {"start": 419.35, "end": 419.91, "word": " فقط", "probability": 0.994140625}, {"start": 419.91, "end": 420.67, "word": " ناتج", "probability": 0.8465169270833334}, {"start": 420.67, "end": 421.19, "word": " واحد", "probability": 0.995849609375}, 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"probability": 0.9890950520833334}, {"start": 429.87, "end": 430.39, "word": " اختيار", "probability": 0.932373046875}, {"start": 430.39, "end": 430.53, "word": " ان", "probability": 0.79541015625}, {"start": 430.53, "end": 430.73, "word": " ال", "probability": 0.70458984375}, {"start": 430.73, "end": 430.99, "word": " R'", "probability": 0.389404296875}, {"start": 431.23, "end": 431.89, "word": " X", "probability": 0.734375}, {"start": 431.89, "end": 432.39, "word": " هذه", "probability": 0.322021484375}, {"start": 432.39, "end": 433.07, "word": " تكون", "probability": 0.975341796875}, {"start": 433.07, "end": 433.17, "word": " ال", "probability": 0.357421875}, {"start": 433.17, "end": 433.73, "word": " primary", "probability": 0.888671875}, {"start": 433.73, "end": 435.51, "word": " يفضل", "probability": 0.9510498046875}, {"start": 435.51, "end": 436.59, "word": " ان", "probability": 0.833984375}, {"start": 436.59, "end": 436.79, "word": " ال", "probability": 0.8544921875}, {"start": 436.79, "end": 437.03, "word": " R'", "probability": 0.9287109375}, {"start": 437.35, "end": 437.69, "word": " X", "probability": 0.962890625}, {"start": 437.69, "end": 438.05, "word": " تكون", "probability": 0.972900390625}, {"start": 438.05, "end": 438.15, "word": " ال", "probability": 0.931640625}, {"start": 438.15, "end": 438.59, "word": " primary", "probability": 0.966796875}, {"start": 438.59, "end": 439.45, "word": " خلينا", "probability": 0.7818603515625}, {"start": 439.45, "end": 439.99, "word": " ناخد", "probability": 0.97998046875}, {"start": 439.99, "end": 440.87, "word": " مثال", "probability": 0.990478515625}, {"start": 440.87, "end": 441.77, "word": " حقيقي", "probability": 0.9835611979166666}, {"start": 441.77, "end": 442.11, "word": " بدون", "probability": 0.958984375}, {"start": 442.11, "end": 442.39, "word": " R", "probability": 0.84130859375}, {"start": 442.39, "end": 442.53, "word": " و", "probability": 0.72119140625}, {"start": 442.53, "end": 442.79, "word": " A", "probability": 0.297119140625}, {"start": 442.79, "end": 445.33, "word": " مثلا", "probability": 0.77294921875}, {"start": 445.33, "end": 445.79, "word": " لو", "probability": 0.63818359375}, {"start": 445.79, "end": 446.31, "word": " أخدنا", "probability": 0.937255859375}, {"start": 446.31, "end": 446.93, "word": " الفيلول", "probability": 0.6986490885416666}, {"start": 446.93, "end": 447.17, "word": " مع", "probability": 0.98193359375}, {"start": 447.17, "end": 447.99, "word": " السوديوم", "probability": 0.7493896484375}], "temperature": 1.0}, {"id": 20, "seek": 47765, "start": 449.45, "end": 477.65, "text": "بدي يعطينا Sodium Phenoxide ممتازة كل المحلول اللي عندى صار Sodium Phenoxide الان هذا المحلول باجب اضيفه على مثلا Ethyl Chloride او Ethyl Bromide لاحظوا اذا انا هنا بتعامل مع two flasks هاي حضرت هنا ال ethoxide بعد ما اتحضر بنضيفه هنا ايش بتعمل ال filler O minus", "tokens": [3555, 16254, 37495, 9566, 1829, 8315, 42059, 2197, 2623, 268, 46053, 3714, 2304, 2655, 31377, 3660, 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"word": " Phenoxide", "probability": 0.7138671875}, {"start": 451.15, "end": 451.85, "word": " ممتازة", "probability": 0.8462890625}, {"start": 451.85, "end": 452.53, "word": " كل", "probability": 0.802734375}, {"start": 452.53, "end": 453.07, "word": " المحلول", "probability": 0.9908447265625}, {"start": 453.07, "end": 453.21, "word": " اللي", "probability": 0.892578125}, {"start": 453.21, "end": 453.55, "word": " عندى", "probability": 0.66552734375}, {"start": 453.55, "end": 453.95, "word": " صار", "probability": 0.985107421875}, {"start": 453.95, "end": 455.21, "word": " Sodium", "probability": 0.9384765625}, {"start": 455.21, "end": 455.91, "word": " Phenoxide", "probability": 0.9143880208333334}, {"start": 455.91, "end": 456.47, "word": " الان", "probability": 0.624755859375}, {"start": 456.47, "end": 456.81, "word": " هذا", "probability": 0.91650390625}, {"start": 456.81, "end": 457.59, "word": " المحلول", "probability": 0.996337890625}, {"start": 457.59, "end": 458.81, "word": " 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CH3 CH2 CH2 و هنا بيكون اندت CL أو PR واضح؟ في هذه الحالة بيتم عملية هجوم من الـ O minus هنا وعملية طرد لل PR بنحصل على الناتج الباكر", "tokens": [2304, 3615, 2423, 39184, 497, 29538, 13672, 1829, 39896, 5995, 18, 5995, 17, 5995, 17, 4032, 34105, 4724, 1829, 30544, 16472, 3215, 2655, 12855, 34051, 11568, 4032, 46958, 5016, 22807, 8978, 29538, 21542, 6027, 3660, 4724, 36081, 2304, 6225, 42213, 10632, 8032, 7435, 20498, 9154, 2423, 39184, 422, 3175, 34105, 4032, 25957, 1211, 10632, 23032, 2288, 3215, 24976, 11568, 44945, 5016, 36520, 15844, 2423, 8315, 2655, 7435, 29739, 995, 37983], "avg_logprob": -0.3107394382987224, "compression_ratio": 1.494047619047619, "no_speech_prob": 0.0, "words": [{"start": 598.18, "end": 598.5, "word": "مع", "probability": 0.647705078125}, {"start": 598.5, "end": 598.7, "word": " الـ", "probability": 0.6312255859375}, {"start": 598.7, "end": 598.88, "word": " R", "probability": 0.5341796875}, {"start": 598.88, "end": 599.2, "word": " هذه", "probability": 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"word": " اليتيم", "probability": 0.76025390625}], "temperature": 1.0}, {"id": 36, "seek": 85945, "start": 830.05, "end": 859.45, "text": "مع حامض قوى مثل الـ HI بس حامض قوى مثل الـ HI بكسرهم إذا تفاعلهم تفاعل إكليفج إيش يعني إكليفج؟ تكسير إكليفج reaction يعني إن أكسر المركب إلى نصين طيب كيف مثلا لو أخدنا هذا ال ether الفيرل O CH2 CH3 نرجع لنفس ال ether الآن هذا لما نيجي الفعل مع HI ال I تعتبر", "tokens": [2304, 3615, 11331, 10943, 11242, 12174, 2407, 7578, 50113, 1211, 2423, 39184, 44376, 4724, 3794, 11331, 10943, 11242, 12174, 2407, 7578, 50113, 1211, 2423, 39184, 44376, 4724, 4117, 3794, 2288, 16095, 11933, 15730, 6055, 5172, 995, 30241, 16095, 6055, 5172, 995, 30241, 11933, 4117, 20292, 5172, 7435, 11933, 1829, 8592, 37495, 22653, 11933, 4117, 20292, 5172, 7435, 22807, 6055, 4117, 3794, 13546, 11933, 4117, 20292, 5172, 7435, 5480, 37495, 22653, 36145, 5551, 4117, 3794, 2288, 9673, 31747, 3555, 30731, 8717, 9381, 9957, 23032, 1829, 3555, 9122, 33911, 50113, 15040, 45164, 5551, 9778, 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{"start": 850.19, "end": 850.39, "word": " لو", "probability": 0.978515625}, {"start": 850.39, "end": 850.85, "word": " أخدنا", "probability": 0.96923828125}, {"start": 850.85, "end": 851.17, "word": " هذا", "probability": 0.97412109375}, {"start": 851.17, "end": 851.37, "word": " ال", "probability": 0.978515625}, {"start": 851.37, "end": 851.65, "word": " ether", "probability": 0.51708984375}, {"start": 851.65, "end": 852.33, "word": " الفيرل", "probability": 0.5494791666666666}, {"start": 852.33, "end": 852.77, "word": " O", "probability": 0.7705078125}, {"start": 852.77, "end": 853.63, "word": " CH2", "probability": 0.879638671875}, {"start": 853.63, "end": 854.33, "word": " CH3", "probability": 0.837646484375}, {"start": 854.33, "end": 854.79, "word": " نرجع", "probability": 0.92578125}, {"start": 854.79, "end": 855.21, "word": " لنفس", "probability": 0.9156901041666666}, {"start": 855.21, "end": 855.39, "word": " ال", "probability": 0.98583984375}, {"start": 855.39, "end": 855.69, 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بيتهاجم تهاجم على ال primary carbon ولا على الفينيل؟ بتهاجم على ال primary carbon أسهل إيش أن تتصل إلى ال primary carbon؟ فبتم هجوم بهذا الشكل؟", "tokens": [10721, 2407, 2423, 39184, 22792, 14962, 49242, 4724, 29399, 1829, 7435, 3660, 16712, 3224, 26108, 2304, 8032, 1211, 7251, 2655, 2288, 7578, 23758, 2423, 39184, 286, 5296, 15042, 4724, 36081, 3224, 26108, 2304, 6055, 3224, 26108, 2304, 15844, 2423, 6194, 5954, 49429, 15844, 27188, 9957, 26895, 22807, 39894, 3224, 26108, 2304, 15844, 2423, 6194, 5954, 5551, 3794, 3224, 1211, 11933, 1829, 8592, 14739, 6055, 2655, 36520, 30731, 2423, 6194, 5954, 22807, 6156, 3555, 39237, 8032, 7435, 20498, 39627, 15730, 25124, 28820, 22807], "avg_logprob": -0.5094126506024096, "compression_ratio": 1.7666666666666666, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 861.03, "end": 861.27, "word": "أو", "probability": 0.26544189453125}, {"start": 861.27, "end": 861.27, "word": " الـ", "probability": 0.441162109375}, {"start": 861.27, "end": 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catalyst", "probability": 0.556640625}, {"start": 1461.89, "end": 1463.35, "word": " ودرجة", "probability": 0.8936767578125}, {"start": 1463.35, "end": 1463.73, "word": " حرارة", "probability": 0.9931640625}, {"start": 1463.73, "end": 1464.35, "word": " 250", "probability": 0.84130859375}, {"start": 1464.35, "end": 1465.23, "word": " وضغط", "probability": 0.91015625}, {"start": 1465.23, "end": 1465.75, "word": " برضه", "probability": 0.9313151041666666}, {"start": 1465.75, "end": 1466.33, "word": " بيعطينا", "probability": 0.89345703125}, {"start": 1466.33, "end": 1466.63, "word": " ال", "probability": 0.60888671875}, {"start": 1466.63, "end": 1467.49, "word": " Oxirane", "probability": 0.9542643229166666}, {"start": 1467.49, "end": 1468.35, "word": " واضح؟", "probability": 0.77386474609375}], "temperature": 1.0}, {"id": 60, "seek": 149017, "start": 1468.83, "end": 1490.17, "text": "إذن هي العملية في الآخر Oxidation لا ال الكنز الكبيرة بيستعملوا ال bare acids ال إيثيلين لأنه صناعة و الصناعة هي اللي فيها استعمال درجات حرارة عالية و استعمال ضغط و ما إلى ذلك فبياخدوا إيثيلين مع أكسجين silver catalyst حرارة ضغط بيعطينا الأمس إليه", "tokens": [28814, 8848, 1863, 39896, 18863, 42213, 10632, 8978, 6024, 95, 34740, 16489, 327, 399, 20193, 2423, 2423, 19452, 11622, 33251, 3555, 48923, 4724, 1829, 14851, 25957, 1211, 14407, 2423, 6949, 21667, 2423, 11933, 1829, 12984, 26895, 9957, 5296, 33456, 3224, 20328, 8315, 27884, 4032, 31767, 8315, 27884, 39896, 13672, 1829, 8978, 11296, 44713, 25957, 6027, 11778, 47341, 9307, 11331, 2288, 9640, 3660, 6225, 6027, 10632, 4032, 44713, 25957, 6027, 48812, 17082, 9566, 4032, 19446, 30731, 29910, 23275, 6156, 21292, 47283, 3215, 14407, 11933, 1829, 12984, 26895, 9957, 20449, 5551, 4117, 3794, 7435, 9957, 8753, 23868, 11331, 2288, 9640, 3660, 48812, 17082, 9566, 4724, 40228, 9566, 1829, 8315, 16247, 2304, 3794, 11933, 20292, 3224], "avg_logprob": -0.2568530610256028, "compression_ratio": 1.7863247863247864, "no_speech_prob": 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كتير لأنه له تطبيقات في التحضيرات العضوية وانا بتهيأها ليه؟ انه احنا أخدنا", "tokens": [3224, 15730, 2423, 39184, 16489, 347, 1929, 13672, 1829, 31439, 5551, 3555, 3794, 9566, 10295, 66, 1050, 38636, 44381, 23758, 10295, 66, 1050, 38636, 3714, 16095, 9122, 2655, 13546, 5296, 33456, 3224, 46740, 6055, 9566, 21292, 4587, 9307, 8978, 16712, 5016, 11242, 13546, 9307, 18863, 11242, 2407, 10632, 4032, 7649, 995, 39894, 3224, 1829, 10721, 11296, 32239, 3224, 22807, 16472, 3224, 1975, 5016, 8315, 5551, 9778, 3215, 8315], "avg_logprob": -0.23075181504954462, "compression_ratio": 1.3902439024390243, "no_speech_prob": 1.0728836059570312e-06, "words": [{"start": 1491.07, "end": 1491.59, "word": "هذا", "probability": 0.834228515625}, {"start": 1491.59, "end": 1491.87, "word": " الـ", "probability": 0.3358154296875}, {"start": 1491.87, "end": 1492.53, "word": " Oxirane", "probability": 0.635498046875}, {"start": 1492.53, "end": 1492.77, "word": " اللي", "probability": 0.5186767578125}, {"start": 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{"id": 84, "seek": 206850, "start": 2041.1, "end": 2068.5, "text": "واضح؟ الان لو اجينا على هذا و عدينا مثلا من هنا و اتحركنا 15 atoms فبصير 15 crown 5 لو اجينا على اللي بعده و عدينا 18 ثغرة بكم أكسجينة؟ 6 أكسجينات فبصير 80 crown 8 80 crown 6 طبعا بيلزمكم اتدربوا ايدكم على رسمه", "tokens": [2407, 46958, 5016, 22807, 2423, 7649, 45164, 1975, 7435, 1829, 8315, 15844, 23758, 4032, 6225, 16254, 8315, 50113, 15040, 9154, 34105, 4032, 1975, 2655, 5016, 31747, 8315, 2119, 16871, 6156, 3555, 9381, 13546, 2119, 11841, 1025, 45164, 1975, 7435, 1829, 8315, 15844, 13672, 1829, 39182, 3224, 4032, 6225, 16254, 8315, 2443, 38637, 17082, 25720, 4724, 24793, 5551, 4117, 3794, 7435, 9957, 3660, 22807, 1386, 5551, 4117, 3794, 7435, 9957, 9307, 6156, 3555, 9381, 13546, 4688, 11841, 1649, 4688, 11841, 1386, 23032, 3555, 3615, 995, 4724, 26895, 11622, 2304, 24793, 1975, 2655, 3215, 25513, 14407, 1975, 25708, 24793, 15844, 12602, 38251, 3224], "avg_logprob": -0.164062494448587, "compression_ratio": 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"probability": 0.839111328125}, {"start": 2670.98, "end": 2671.06, "word": " في", "probability": 0.84130859375}, {"start": 2671.06, "end": 2671.7, "word": " البوتاسيوم", "probability": 0.9765625}, {"start": 2671.7, "end": 2671.88, "word": " من", "probability": 0.97900390625}, {"start": 2671.88, "end": 2672.18, "word": " داخل", "probability": 0.93505859375}, {"start": 2672.18, "end": 2672.54, "word": " جدار", "probability": 0.98291015625}, {"start": 2672.54, "end": 2673.04, "word": " الخلية", "probability": 0.97314453125}, {"start": 2673.04, "end": 2673.44, "word": " يعني", "probability": 0.9111328125}, {"start": 2673.44, "end": 2673.74, "word": " شوفوا", "probability": 0.95849609375}, {"start": 2673.74, "end": 2673.86, "word": " كيف", "probability": 0.963134765625}, {"start": 2673.86, "end": 2674.42, "word": " عملية", "probability": 0.9786783854166666}, {"start": 2674.42, "end": 2675.0, "word": " أنه", "probability": 0.7005615234375}, {"start": 2675.0, "end": 2675.86, "word": " بنتقل", "probability": 0.8880615234375}, {"start": 2675.86, "end": 2676.36, "word": " كل", "probability": 0.59716796875}, {"start": 2676.36, "end": 2676.62, "word": " هذا", "probability": 0.93896484375}, {"start": 2676.62, "end": 2676.98, "word": " بدخل", "probability": 0.792236328125}, {"start": 2676.98, "end": 2677.12, "word": " في", "probability": 0.92431640625}, {"start": 2677.12, "end": 2677.42, "word": " جدار", "probability": 0.99267578125}, {"start": 2677.42, "end": 2677.84, "word": " الخلية", "probability": 0.9876302083333334}, {"start": 2677.84, "end": 2677.96, "word": " و", "probability": 0.89990234375}, {"start": 2677.96, "end": 2678.34, "word": " بيدخل", "probability": 0.9100341796875}, {"start": 2678.34, "end": 2678.7, "word": " حامل", "probability": 0.9899088541666666}, {"start": 2678.7, "end": 2679.02, "word": " معاه", "probability": 0.79248046875}, {"start": 2679.02, "end": 2679.68, "word": " إيش؟", "probability": 0.61212158203125}, {"start": 2679.68, "end": 2681.52, "word": " البوتاسيوم", "probability": 0.9529296875}, {"start": 2681.52, "end": 2682.12, "word": " بيدخل", "probability": 0.89306640625}, {"start": 2682.12, "end": 2682.46, "word": " جدار", "probability": 0.9676106770833334}, {"start": 2682.46, "end": 2682.96, "word": " الخلية", "probability": 0.9899088541666666}, {"start": 2682.96, "end": 2683.34, "word": " و", "probability": 0.9677734375}, {"start": 2683.34, "end": 2683.66, "word": " بيدخل", "probability": 0.9466552734375}, {"start": 2683.66, "end": 2684.2, "word": " حامل", "probability": 0.9910481770833334}, {"start": 2684.2, "end": 2684.6, "word": " معاه", "probability": 0.971435546875}, {"start": 2684.6, "end": 2685.64, "word": " البوتاسيوم", "probability": 0.9740234375}], "temperature": 1.0}, {"id": 110, "seek": 269534, "start": 2686.4, "end": 2695.34, "text": "بهيك تقريبا بنكون انتهينا من هذا الفصل اللي هو ال ether ومتعلقاته الحصة اللي جاي ان شاء الله بنبدأ في ال aldi heights", "tokens": [3555, 3224, 1829, 4117, 6055, 4587, 16572, 3555, 995, 44945, 30544, 16472, 47395, 1829, 8315, 9154, 23758, 27188, 36520, 13672, 1829, 31439, 2423, 37096, 4032, 2304, 2655, 30241, 4587, 9307, 3224, 21542, 9381, 3660, 13672, 1829, 10874, 47302, 16472, 13412, 16606, 21984, 44945, 44510, 10721, 8978, 2423, 16798, 72, 25930], "avg_logprob": -0.2408088276199266, "compression_ratio": 1.3900709219858156, "no_speech_prob": 0.0, "words": [{"start": 2686.4, "end": 2686.88, "word": "بهيك", "probability": 0.59454345703125}, {"start": 2686.88, "end": 2687.56, "word": " تقريبا", "probability": 0.96201171875}, {"start": 2687.56, "end": 2688.38, "word": " بنكون", "probability": 0.59002685546875}, {"start": 2688.38, "end": 2689.0, "word": " انتهينا", "probability": 0.9339599609375}, {"start": 2689.0, "end": 2689.32, "word": " من", "probability": 0.962890625}, {"start": 2689.32, "end": 2690.18, "word": " هذا", "probability": 0.75244140625}, {"start": 2690.18, "end": 2690.66, "word": " الفصل", "probability": 0.9541015625}, {"start": 2690.66, "end": 2690.82, "word": " اللي", "probability": 0.674072265625}, {"start": 2690.82, "end": 2691.0, "word": " هو", "probability": 0.978515625}, {"start": 2691.0, "end": 2691.14, "word": " ال", "probability": 0.9169921875}, {"start": 2691.14, "end": 2691.5, "word": " ether", "probability": 0.537109375}, {"start": 2691.5, "end": 2692.58, "word": " ومتعلقاته", "probability": 0.87841796875}, {"start": 2692.58, "end": 2692.94, "word": " الحصة", "probability": 0.9578450520833334}, {"start": 2692.94, "end": 2693.02, "word": " اللي", "probability": 0.656982421875}, {"start": 2693.02, "end": 2693.18, "word": " جاي", "probability": 0.74462890625}, {"start": 2693.18, "end": 2693.28, "word": " ان", "probability": 0.73681640625}, {"start": 2693.28, "end": 2693.5, "word": " شاء", "probability": 0.97265625}, {"start": 2693.5, "end": 2693.54, "word": " الله", "probability": 0.95263671875}, {"start": 2693.54, "end": 2694.08, "word": " بنبدأ", "probability": 0.9560546875}, {"start": 2694.08, "end": 2694.34, "word": " في", "probability": 0.83447265625}, {"start": 2694.34, "end": 2694.58, "word": " ال", "probability": 0.97021484375}, {"start": 2694.58, "end": 2694.96, "word": " aldi", "probability": 0.37890625}, {"start": 2694.96, "end": 2695.34, "word": " heights", "probability": 0.802734375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2699.06425, "duration_after_vad": 2558.171249999992}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..86d6147d4bbdcaa9a6d490ec28fd2fb73db811a6
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g_raw.srt
@@ -0,0 +1,2028 @@
+1
+00:00:07,360 --> 00:00:13,000
+بسم الله الرحمن الرحيم اتكلمنا المرة الماضية في
+
+2
+00:00:13,000 --> 00:00:18,800
+موضوع ال ethers بشكل أساسي تسمية ال ethers وخواصها
+
+3
+00:00:18,800 --> 00:00:27,600
+اليوم بنستمر في تناول هذا الموضوع هنتكلم على تحضير
+
+4
+00:00:27,600 --> 00:00:33,340
+ال ethers و بعض تفاعلاتها زي التوسع في هذا المجال
+
+5
+00:00:33,950 --> 00:00:40,830
+الان يوم ما بيجيكم اي ether بتكونوا عارفين ان ال
+
+6
+00:00:40,830 --> 00:00:47,070
+ether تقسم الى نوعين ممكن ال ether تكون symmetric
+
+7
+00:00:47,070 --> 00:00:52,730
+بمعنى مجموعتين ال R اللي موجودات زي بعض يعني لما
+
+8
+00:00:52,730 --> 00:00:58,890
+نقول اثل اثل هذا symmetric etherمثل مثل فنل فنل كل
+
+9
+00:00:58,890 --> 00:01:03,890
+هذه عبارة عن symmetrical ethers وممكن ال ethers
+
+10
+00:01:03,890 --> 00:01:10,770
+تكون unsymmetrical بمعنى يكون في عند مثلا اثل مع
+
+11
+00:01:10,770 --> 00:01:17,700
+مثل اوإيثل مع فيلل أو ايزو بروبل مع إيثل احتمالات
+
+12
+00:01:17,700 --> 00:01:21,620
+كتير الآن هنا بيصير عندنا طريقتين للتحضير يعني لما
+
+13
+00:01:21,620 --> 00:01:26,860
+بيحضر symmetrical ethers في عنده طريقة و لما بيحضر
+
+14
+00:01:26,860 --> 00:01:31,950
+unsymmetrical ethers في عنده طريقة تانيةالـ
+
+15
+00:01:31,950 --> 00:01:35,270
+symmetrical ethers طريقة تحضيرهم سهلة وممكن مرت
+
+16
+00:01:35,270 --> 00:01:41,310
+علينا عرضا أثناء تكلمنا عن الألكينات إذا أخدنا
+
+17
+00:01:41,310 --> 00:01:46,530
+الكحول وسخناه لحرارة محددة في وجود حامض بيعطينا ال
+
+18
+00:01:46,530 --> 00:01:51,950
+ether يعني مثلا ال diethyl ether إذا احنا أخدنا ال
+
+19
+00:01:51,950 --> 00:01:56,830
+ethanol مع sulfuric acid على 140 درجة مئوية
+
+20
+00:01:56,830 --> 00:02:02,470
+بيعطينا ال diethyl ether واضح؟كذلك الحالة لو بدى
+
+21
+00:02:02,470 --> 00:02:08,530
+dipropyl ether مثلا أو ما إلى ذلك طريقة سهلة كتير
+
+22
+00:02:08,530 --> 00:02:15,050
+الآن بتصير عندنا .. بتصير عندنا مشكلة لما بنحضر ال
+
+23
+00:02:15,050 --> 00:02:20,770
+unsymmetrical ethers اتخيلوا انتوا لو اجينا بنحضر
+
+24
+00:02:20,770 --> 00:02:25,170
+ال unsymmetrical ethers بنفس الطريقة في هذه الحالة
+
+25
+00:02:25,170 --> 00:02:30,610
+بدنا نكون مضطرين ناخد كام كحول اتنينواضح؟ يعني لو
+
+26
+00:02:30,610 --> 00:02:35,310
+مثلا بدي ether جاي من ال .. من ال methanol و ال
+
+27
+00:02:35,310 --> 00:02:40,230
+ethanol بكون بدي two alcohols يعني بدي ال methyl
+
+28
+00:02:40,230 --> 00:02:48,390
+OH و ال ethyl OH الآن لو هدول الاتنين خلطتهم أنا
+
+29
+00:02:48,390 --> 00:02:53,790
+مع sulfuric acid و سخنت ايش اللي بدي اقول ان دي؟
+
+30
+00:02:53,790 --> 00:02:58,290
+تخيلوا ان انا خلطت H plus مع sulfuric acid و تسخين
+
+31
+00:02:58,600 --> 00:03:03,760
+ماذا تتوقع ان يحدث في هذه الحالة؟
+
+32
+00:03:03,760 --> 00:03:10,660
+طبعا تضعوا في اعتباركم ان انا لما اعمل التفاعل لم
+
+33
+00:03:10,660 --> 00:03:15,640
+اضع جزء واحد من الميثانول و جزء واحد من الاثانول
+
+34
+00:03:15,640 --> 00:03:19,520
+انا اضعت مثلا one mole of methanol و one mole of
+
+35
+00:03:19,520 --> 00:03:23,900
+ethanol لحظة مبدأ اقول one mole يعني بحكي عن 6 في
+
+36
+00:03:23,900 --> 00:03:24,680
+10 او 23
+
+37
+00:03:36,250 --> 00:03:42,450
+ممكن يلتقي الميثانول مع جزء ميثانول تاني وبالتالي
+
+38
+00:03:42,450 --> 00:03:49,450
+يعمل dimethyl ether يعني يعطي الميثل وميثل وممكن
+
+39
+00:03:49,450 --> 00:03:57,340
+الاثانول يلتقي مع جزء اثانول تاني ويعطيمثل او اثل
+
+40
+00:03:57,340 --> 00:04:02,640
+او اثل
+
+41
+00:04:02,640 --> 00:04:05,000
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+42
+00:04:05,000 --> 00:04:05,700
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+43
+00:04:05,700 --> 00:04:07,220
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+44
+00:04:07,220 --> 00:04:07,500
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+45
+00:04:07,500 --> 00:04:07,500
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل
+
+46
+00:04:07,500 --> 00:04:13,580
+او اثل او اثل او اثل او اثل او اثل او اثل او اثل ا
+
+47
+00:04:13,880 --> 00:04:17,980
+خليط من ثلاث نواتج وهذا دائما الكلام الكيميائيين
+
+48
+00:04:17,980 --> 00:04:22,520
+بتجنبوه لأن عملية فصل المراكبات عن بعض بالتقطير و
+
+49
+00:04:22,520 --> 00:04:28,640
+غيرها عملية متعبة و مكلفة و ما إلى ذلك فعملية ان
+
+50
+00:04:28,640 --> 00:04:33,180
+انا بضح أحضر un-symmetrical ether من خلط two
+
+51
+00:04:33,180 --> 00:04:36,820
+different alcohols ليست طريقة عملية is not a
+
+52
+00:04:36,820 --> 00:04:41,440
+practical methodمش مقبولة يعني لو بداجي أقولكوا
+
+53
+00:04:41,440 --> 00:04:44,940
+حضرولي ال مثل و إثل و طالبي بداجي أجابني إنه بخلق
+
+54
+00:04:44,940 --> 00:04:49,400
+ميثانول و إيثانول و حامض و حرارة الجواب غلط هذا
+
+55
+00:04:49,400 --> 00:04:52,700
+الكلام مش مقبول لأن هذا الكلام بيطلق تلت نواتج
+
+56
+00:04:52,700 --> 00:04:58,260
+عملية فصل التلت نواتج هدول عن بعضهم عملية صعبة و
+
+57
+00:04:58,260 --> 00:05:04,430
+مزعجةأذن كان لابد من طريقة تانية لتحضير الـ
+
+58
+00:05:04,430 --> 00:05:08,430
+Unsymmetrical ethers يطلع فيها المركّب لوحده، ليس
+
+59
+00:05:08,430 --> 00:05:13,990
+لدي خليط من تلت نواتجواضح الفكرة؟ اه ..الان هذه
+
+60
+00:05:13,990 --> 00:05:18,910
+كيف بيعملوها؟ بيجيبوا alcohol، واحد من ال alcohol
+
+61
+00:05:18,910 --> 00:05:24,250
+بيخلوه ROH، ال alcohol نفسه ROH، لو فعلنا مع ال
+
+62
+00:05:24,250 --> 00:05:28,350
+sodium، كلكوا عارفين ان ال sodium بياخد ال H و
+
+63
+00:05:28,350 --> 00:05:34,590
+بيعملنا RO minusفصار عندى RO-NA+, يعني لو كان عندى
+
+64
+00:05:34,590 --> 00:05:41,030
+مثلا إيثانول بيصير عندى Sodium Ethoxide لو كان
+
+65
+00:05:41,030 --> 00:05:45,470
+عندى هنا إيثانول مع ال Sodium بيعطينا Sodium
+
+66
+00:05:45,470 --> 00:05:49,770
+Ethoxide هذا المركب بتطلع هذه معادلة هيك لوحدها
+
+67
+00:05:49,770 --> 00:05:56,130
+الناتج اللى صار عندى هنا باجب فعله مع RX تانية
+
+68
+00:05:56,920 --> 00:06:00,300
+واضح؟ يعني أرجو أنه ما تفهموش هذه المعادلة لأن هذا
+
+69
+00:06:00,300 --> 00:06:04,960
+بيطلع الناتجين لأ هذه معادلة لوحدها أنه انا لو
+
+70
+00:06:04,960 --> 00:06:09,040
+أخدت الethanol مع ال sodium بيطلع له sodium
+
+71
+00:06:09,040 --> 00:06:13,080
+ethoxide صار كل المحلول عبارة عن sodium ethoxide
+
+72
+00:06:13,080 --> 00:06:18,230
+الآن هذا ال sodium ethoxide بنيجي بنضيفهأو من فعله
+
+73
+00:06:18,230 --> 00:06:28,170
+مرة تانية مع R' X أي R تانية نفترض مثلا CH3CL الـ
+
+74
+00:06:28,170 --> 00:06:32,990
+RO- هذه بتيجي بتعمل عملية إبدال على الـ RX بتهاجم
+
+75
+00:06:32,990 --> 00:06:37,210
+هيك و بتطرد الـ Xواخدنا أن التفاعل الأساسي
+
+76
+00:06:37,210 --> 00:06:42,090
+لمُركّبات الـRX هو الـ Substitution واخدنا أنها
+
+77
+00:06:42,090 --> 00:06:48,750
+ممكن تتم بـ Sn1 وممكن تتم بـ Sn2 ميكانيزم، واضحة؟
+
+78
+00:06:48,750 --> 00:06:54,030
+فكأنه أنا صار عندي هلأ بالتأكيد ر أو ماينوس هاجمت
+
+79
+00:06:54,030 --> 00:06:59,350
+على R' X طلعت الـ X فبصير عندي ر أو ر ناتج واحد
+
+80
+00:06:59,350 --> 00:07:07,470
+فقط ناتج واحد فقطهنا يفضل حتى يكون التفاعل أفضل ما
+
+81
+00:07:07,470 --> 00:07:13,070
+يمكن انه لما بعمل عملية اختيار ان ال R' X هذه تكون
+
+82
+00:07:13,070 --> 00:07:19,450
+ال primary يفضل ان ال R' X تكون ال primary خلينا
+
+83
+00:07:19,450 --> 00:07:26,930
+ناخد مثال حقيقي بدون R و A مثلا لو أخدنا الفيلول
+
+84
+00:07:26,930 --> 00:07:32,530
+مع السوديومبدي يعطينا Sodium Phenoxide ممتازة كل
+
+85
+00:07:32,530 --> 00:07:36,810
+المحلول اللي عندى صار Sodium Phenoxide الان هذا
+
+86
+00:07:36,810 --> 00:07:43,970
+المحلول باجب اضيفه على مثلا Ethyl Chloride او
+
+87
+00:07:43,970 --> 00:07:48,090
+Ethyl Bromide لاحظوا اذا انا هنا بتعامل مع two
+
+88
+00:07:48,090 --> 00:07:52,910
+flasks هاي حضرت هنا ال ethoxide بعد ما اتحضر
+
+89
+00:07:52,910 --> 00:07:59,750
+بنضيفه هنا ايش بتعمل ال filler O minusبتهاجم هنا
+
+90
+00:07:59,750 --> 00:08:08,110
+وبتطرد ال X بيصير عندى Phenyl O CH2 CH3 واضحة
+
+91
+00:08:08,110 --> 00:08:16,890
+الفكرة لاحظوا هنا لحظة ما انا بأعمل الاختيار بفضل
+
+92
+00:08:16,890 --> 00:08:24,450
+و لازم انه يكونالـ RX Primary يعني مثلا لو إجينا
+
+93
+00:08:24,450 --> 00:08:29,750
+بنسألكوا السؤال الآن كيف ممكن تحضرولنا هذا الـ
+
+94
+00:08:29,750 --> 00:08:34,610
+Etherكيف ممكن تحضروا هذا الـ Ether؟ انتوا لما
+
+95
+00:08:34,610 --> 00:08:39,170
+بتكونوا تجيبوا على السؤال هذا الـ Ether هذا عبارة
+
+96
+00:08:39,170 --> 00:08:42,350
+عن symmetrical ولا unsymmetrical؟ unsymmetrical ..
+
+97
+00:08:42,350 --> 00:08:44,070
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+98
+00:08:44,070 --> 00:08:45,530
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+99
+00:08:45,530 --> 00:08:47,870
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+100
+00:08:47,870 --> 00:08:47,870
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+101
+00:08:47,870 --> 00:08:47,870
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+102
+00:08:47,870 --> 00:08:49,790
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+103
+00:08:49,790 --> 00:08:50,590
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+104
+00:08:50,590 --> 00:08:51,990
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+105
+00:08:51,990 --> 00:08:54,910
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+106
+00:08:54,910 --> 00:08:57,670
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+107
+00:08:57,670 --> 00:08:57,670
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+108
+00:08:57,670 --> 00:08:57,670
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+109
+00:08:57,670 --> 00:08:57,670
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+110
+00:08:57,670 --> 00:08:57,670
+unsymmetrical .. unsymmetrical .. unsymmetrical ..
+
+111
+00:08:57,670 --> 00:09:01,500
+unsymmetrical .. unsلـ Probability group واحدة
+
+112
+00:09:01,500 --> 00:09:11,800
+منهم بيكون O- والتانية RX الصعوبة هنا أن أعرف أنية
+
+113
+00:09:11,800 --> 00:09:17,140
+اللي بيبقى معها الـ O- وأنية اللي بيكون الـ RX
+
+114
+00:09:17,140 --> 00:09:22,340
+احنا أخدنا شرط الـ RX لازم تكون الـ Primary إذا
+
+115
+00:09:22,340 --> 00:09:26,620
+هذا لما بدي أحلله للمكونات تبعونه، إيش بيكون؟
+
+116
+00:09:31,030 --> 00:09:38,210
+بدي اخد هذا الكحول اللي هو الـ tertiary-butanol و
+
+117
+00:09:38,210 --> 00:09:42,930
+التيرتشاري بيوتانول هذا لما نفعله مع السوديوم بدي
+
+118
+00:09:42,930 --> 00:09:46,850
+يعطينا التيرتشاري بيوت أكسيد هذه المعادلة الأولى
+
+119
+00:09:46,850 --> 00:09:51,030
+اللي عندنا، واضح؟ إذا إحنا حضرنا التيرتشاري بيوت
+
+120
+00:09:51,030 --> 00:09:56,190
+أكسيد انايون الايون السالف بعد هيك بدنا نفعله مع
+
+121
+00:09:56,190 --> 00:10:06,380
+إيش؟مع الـ R هذه اللي هي CH3 CH2 CH2 و هنا بيكون
+
+122
+00:10:06,380 --> 00:10:13,360
+اندت CL أو PR واضح؟ في هذه الحالة بيتم عملية هجوم
+
+123
+00:10:13,360 --> 00:10:19,880
+من الـ O minus هنا وعملية طرد لل PR بنحصل على
+
+124
+00:10:19,880 --> 00:10:20,680
+الناتج الباكر
+
+125
+00:10:23,830 --> 00:10:28,570
+الان لو واحدة عملت الجواب هنا بالعكس خلت هذا تصير
+
+126
+00:10:28,570 --> 00:10:34,070
+O minus وال X تكون هنا tertiary مش هيصير التفاعل
+
+127
+00:10:34,070 --> 00:10:41,430
+واضح؟ اذا شرط هذا التفاعل ان ال R X نخليها primary
+
+128
+00:10:41,430 --> 00:10:45,190
+بصعوبة لو كان secondary ممكن يمشي بصعوبة كتير يعني
+
+129
+00:10:45,190 --> 00:10:51,030
+بيكون بطيء tertiary مستحيل فطالما ان احد مكونات ال
+
+130
+00:10:51,030 --> 00:10:55,590
+etherالبرايماري والتاني secondary او tertiary اذا
+
+131
+00:10:55,590 --> 00:10:59,710
+انا نية اللى بده اخليها RX لبرايماري لو كان مثلا
+
+132
+00:10:59,710 --> 00:11:06,530
+برايماري مع فنل لأن
+
+133
+00:11:06,530 --> 00:11:11,570
+الفنل لو حد عمل عليها X مش لأنها tertiary لأ انتوا
+
+134
+00:11:11,570 --> 00:11:16,370
+اخدتوا كمان قبل هيك شغلة انه لا يمكن ابدال X على
+
+135
+00:11:16,370 --> 00:11:23,180
+حلقة بنزينمتذكرين لما قلنا لكم ARX لا يحدث ابدال
+
+136
+00:11:23,180 --> 00:11:28,440
+بناء ع ذلك لو برضه بدي يجيكم سؤال في الامتحانات
+
+137
+00:11:28,440 --> 00:11:33,760
+واضح نخلصناه زي
+
+138
+00:11:33,760 --> 00:11:42,270
+هذا المثال تتطلع عليه من الآخرحضرولنا فين ال O إثل
+
+139
+00:11:42,270 --> 00:11:46,490
+و لا مثل و لا global واحدة تيجي تقسم هذا تقسيم
+
+140
+00:11:46,490 --> 00:11:54,890
+خاطئ يعني تخليلي هذه فين ال X زائد مثلا إثل O
+
+141
+00:11:54,890 --> 00:11:58,290
+minus و تقول والله هذه إثل O minus بتهاجم على فين
+
+142
+00:11:58,290 --> 00:12:04,050
+ال X بتتردها إذا السؤال عليه خمس درجات كده بتاخد؟0
+
+143
+00:12:04,050 --> 00:12:07,490
+ليش؟
+
+144
+00:12:07,490 --> 00:12:12,750
+لأنه لا يتم الإبدال على الاروماتيك كومباونز السابق
+
+145
+00:12:12,750 --> 00:12:16,670
+أخدناها واضح؟ لا يتم الإبدال في هذه الحالة جواب
+
+146
+00:12:16,670 --> 00:12:21,290
+الصح أن تكون هذه فين الـO-؟ وهذه تكون FX
+
+147
+00:12:23,140 --> 00:12:27,240
+هذا اللي هو William Sons Synthesis و بالمناسبة
+
+148
+00:12:27,240 --> 00:12:30,420
+طبيعة .. هيك يا ربنا خلق الدنيا سبحانه وتعالى
+
+149
+00:12:30,420 --> 00:12:35,140
+طبيعة الامتحانات لا يمكن اصحكوا تفكروا ييجي امتحان
+
+150
+00:12:35,140 --> 00:12:39,660
+و ما نجيبش عليه سؤال نختبركوا بهذه المنطقة بتاعة
+
+151
+00:12:39,660 --> 00:12:43,640
+تحضير Unsymmetrical Ether و تعرفولي بالظبط ايش
+
+152
+00:12:43,640 --> 00:12:47,860
+معنى ال primary و secondary و tertiary و كيف
+
+153
+00:12:47,860 --> 00:12:54,540
+تعملوا مكونات هذا ال ether ماشي؟هنا قدام الكاميرا
+
+154
+00:12:54,540 --> 00:13:00,880
+كشفنا سؤال من الامتحان الآن
+
+155
+00:13:00,880 --> 00:13:07,910
+الـ cleavage of ethersلاحظوا معنى لما بنحكي احنا
+
+156
+00:13:07,910 --> 00:13:13,070
+عن بعض المُركّبات أو العائلات بنقول reactions of
+
+157
+00:13:13,070 --> 00:13:16,570
+مثلا alcohols بناخد أربع خمس ست أنواع من ال
+
+158
+00:13:16,570 --> 00:13:20,350
+reactions بعد شوية لما نحكي مثلا عن ال aldehydes و
+
+159
+00:13:20,350 --> 00:13:24,090
+ال ketones بناخد reactions of aldehydes و ketones
+
+160
+00:13:24,090 --> 00:13:27,910
+ممكن ناخد محاضرتين أو تلاتة لما حكينا على ال
+
+161
+00:13:27,910 --> 00:13:32,930
+alkenesتفاعلات الإضافة والـ Palmer وما إلى ذلك
+
+162
+00:13:32,930 --> 00:13:37,210
+كانت قصة، بظبط ولا لا؟ لكن لما بنحكي على
+
+163
+00:13:37,210 --> 00:13:41,730
+الـEthers، إحنا في الأساس قلنا الـEthers they are
+
+164
+00:13:41,730 --> 00:13:46,770
+considered to be inert، يعني تقريبا ما بتفعلوش، هم
+
+165
+00:13:46,770 --> 00:13:51,530
+تقريبا، الملومش غيرها التفاعل اليتيممع حامض قوى
+
+166
+00:13:51,530 --> 00:13:57,210
+مثل الـ HI بس حامض قوى مثل الـ HI بكسرهم إذا
+
+167
+00:13:57,210 --> 00:14:03,150
+تفاعلهم تفاعل إكليفج إيش يعني إكليفج؟ تكسير إكليفج
+
+168
+00:14:03,150 --> 00:14:10,190
+reaction يعني إن أكسر المركب إلى نصين طيب كيف مثلا
+
+169
+00:14:10,190 --> 00:14:15,210
+لو أخدنا هذا ال ether الفيرل O CH2 CH3 نرجع لنفس
+
+170
+00:14:15,210 --> 00:14:19,450
+ال ether الآن هذا لما نيجي الفعل مع HI ال I تعتبر
+
+171
+00:14:21,030 --> 00:14:25,650
+أو الـ Strong nucleophile بنتيجة التهاجم هل يترى
+
+172
+00:14:25,650 --> 00:14:28,690
+هذا الـ I لما بيتهاجم تهاجم على ال primary carbon
+
+173
+00:14:28,690 --> 00:14:32,850
+ولا على الفينيل؟ بتهاجم على ال primary carbon أسهل
+
+174
+00:14:32,850 --> 00:14:36,110
+إيش أن تتصل إلى ال primary carbon؟ فبتم هجوم بهذا
+
+175
+00:14:36,110 --> 00:14:43,020
+الشكل؟وبتكسر هذه كأنه عملت عكس التفاعل السابق كأنه
+
+176
+00:14:43,020 --> 00:14:46,280
+عملت عكس التفاعل السابق بتصير أدفين الـ O minus
+
+177
+00:14:46,280 --> 00:14:50,600
+وبعدين بتاخد الـ H plus من اللي كانت مع الـ I زائد
+
+178
+00:14:50,600 --> 00:14:57,960
+CH3CH2I إذا هنا تكسير هذا ال ether بالـ HI أعطاني
+
+179
+00:14:57,960 --> 00:15:05,830
+الكهول زائد الكلهلين لاحظوا هو عكسالتفاعل السابق
+
+180
+00:15:05,830 --> 00:15:08,910
+بس في التفاعل السابق انا ماكنتش افعل ال alcohol
+
+181
+00:15:08,910 --> 00:15:13,130
+كنت اقويه انا اول اش افعله مع ال sodium عشان تصير
+
+182
+00:15:13,130 --> 00:15:17,050
+فين ال O minus كان ال nucleophile اقوى لانه احنا
+
+183
+00:15:17,050 --> 00:15:20,170
+اخدنا ان اللي charged ال nucleophiles are stronger
+
+184
+00:15:20,170 --> 00:15:26,750
+than ال neutral ال nucleophiles مظبوط ولا لا الان
+
+185
+00:15:26,750 --> 00:15:32,170
+نفس الفكرة لو بدكم تطلعوا على هذا ال ether اللي هو
+
+186
+00:15:32,170 --> 00:15:39,220
+ايش اسمهفي تيرتشاريبيوتيل جروب وفي إبروبيل إذا هذا
+
+187
+00:15:39,220 --> 00:15:45,020
+تيرتشاريبيوتيل إبروبيل إيثر مظبوط ولا لا
+
+188
+00:15:45,020 --> 00:15:51,120
+تيرتشاريبيوتيل إبروبيل إيثر الآن لما بتفعل ولا مع
+
+189
+00:15:51,120 --> 00:15:57,620
+I minus وين المكان السهل انها تصل ال I minus ال
+
+190
+00:15:57,620 --> 00:16:01,080
+primary تخيلوا السهل اتصل هنا
+
+191
+00:16:05,110 --> 00:16:08,670
+طبعا ده زوج الإلكترونات بيجي على الأكسجين بيصير
+
+192
+00:16:08,670 --> 00:16:13,410
+عندنا ترتشالفيوتانول
+
+193
+00:16:13,410 --> 00:16:20,910
+زائد بروبل أيوديت اذا احنا اللي بيصير عندنا بالظبط
+
+194
+00:16:20,910 --> 00:16:28,040
+لما بنفعل ال ethersمع الـ HI بينكسروا ل Alcohol
+
+195
+00:16:28,040 --> 00:16:32,680
+زائد Alkyl Halide بينكسروا ل Alcohol زائد Alkyl
+
+196
+00:16:32,680 --> 00:16:37,400
+Halide أحيانا لو كان هذا ال primary وع الجهة
+
+197
+00:16:37,400 --> 00:16:43,520
+التالية primary شو بيصير عنده واضح التساؤل اللي
+
+198
+00:16:43,520 --> 00:16:50,280
+أنا بطرحه يعني مثلا لو كنا حاطين هنا CH3O
+
+199
+00:16:51,840 --> 00:16:56,960
+CH2 CH3 هذي primary و هذي أحسن كمان من ال primary
+
+200
+00:16:56,960 --> 00:17:02,660
+حقيقة اللي بدو يطلع عندى الاحتمالين طبعا هنا لو
+
+201
+00:17:02,660 --> 00:17:06,720
+كنت أنا مستعمل HI كتير يعنى خلينا نفترض انه مع ال
+
+202
+00:17:06,720 --> 00:17:20,000
+HI هذا أعطانا هذا أعطانا CH3 I زائد CH3 CH2
+
+203
+00:17:21,060 --> 00:17:26,040
+الان اذا اله اي كتير بيجي يتفاعل مع هذا الكحول لان
+
+204
+00:17:26,040 --> 00:17:34,460
+هذا الكحول ال primary و بيحاولوا كمان CH3 CH2I في
+
+205
+00:17:34,460 --> 00:17:38,660
+النهاية بيطلع
+
+206
+00:17:38,660 --> 00:17:44,020
+ال two iodides واضح؟ لكن في مثل هذه الحالة مثلا هل
+
+207
+00:17:44,020 --> 00:17:49,330
+اليوت بيقدر يحل محل OH على البنزين؟أو هاليود بحب
+
+208
+00:17:49,330 --> 00:17:53,050
+كتير حلم حلو أشتري Cherry لأ لكن لو كانت ال
+
+209
+00:17:53,050 --> 00:17:57,030
+primary ممكن كمية إضافية تكون موجودة من اليود
+
+210
+00:17:57,030 --> 00:18:00,730
+excess اتحال وبالتالي يطلع عندى بس ال iodide بمعنى
+
+211
+00:18:00,730 --> 00:18:04,310
+انه صح اتكون ال alcohol في البداية لكن ال alcohol
+
+212
+00:18:05,890 --> 00:18:10,990
+بخطوة إضافية اتحول ل iodide فكأنه يعني ال two
+
+213
+00:18:10,990 --> 00:18:14,670
+parts of the ether are converted to alkyl halides
+
+214
+00:18:14,670 --> 00:18:20,950
+الجزئين من ال ether اتحولوا ل ال alkyl halide
+
+215
+00:18:44,950 --> 00:18:51,910
+في عندنا موضوع تاني ال ethers مرات بتكون cyclic
+
+216
+00:18:51,910 --> 00:18:56,850
+ethers واضح يعني بشكل عام ال ethers العادية
+
+217
+00:18:56,850 --> 00:19:03,370
+الفاتحة ROR الان لو ال O صارت موجودة جوا حلقة
+
+218
+00:19:03,370 --> 00:19:09,690
+بنصير نحكي عنcyclic ether ممكن تكون ال O بحلقة
+
+219
+00:19:09,690 --> 00:19:14,130
+ثلاثية ممكن تكون بحلقة رباعية ممكن تكون بحلقة
+
+220
+00:19:14,130 --> 00:19:18,350
+خماسية سوداسية خلينا بس نعود التذكير بالحلقة
+
+221
+00:19:18,350 --> 00:19:22,650
+الثلاثية وانا بتهيأ له مرت علينا الحلقة الثلاثية
+
+222
+00:19:22,650 --> 00:19:28,410
+بتفاعل ال alkyls واضح؟ هذه وين مرت علينا ال
+
+223
+00:19:28,410 --> 00:19:35,270
+ethylene oxide لما كان يكون عندي ethyleneCH2 CH2
+
+224
+00:19:35,270 --> 00:19:43,230
+مع البروكساكبراسيت كان يعطينا الابوكسايد لاحظوا مع
+
+225
+00:19:43,230 --> 00:19:50,130
+الابوكسايد هو اسم عائلة لكن المركب نفسه بنسميه إما
+
+226
+00:19:50,130 --> 00:19:55,230
+إفليل أوكسايد أو أوكس إيرين في الكيميا الحلقية غير
+
+227
+00:19:55,230 --> 00:20:01,030
+المتجانسة هذا المركب شو بيسموه أوكس إيرين بنسميه
+
+228
+00:20:01,030 --> 00:20:07,130
+أوكس إيرينأو لأنه إجاب للإيثالين بنقول عنه إيثالين
+
+229
+00:20:07,130 --> 00:20:13,190
+أكسايد الأن لو حطيت هنا مثل معنى ذلك الألكين الأصل
+
+230
+00:20:13,190 --> 00:20:18,830
+اللي كان عندي CH3 CH double bond CH2 بروبيل أو
+
+231
+00:20:18,830 --> 00:20:23,590
+بروبيلين بناء على ذلك المراكب شو حيصير بروبيلين
+
+232
+00:20:23,590 --> 00:20:31,780
+أكسايدطيب، لو كان عنده واحد، اتنين، تلاتة، أربعة
+
+233
+00:20:31,780 --> 00:20:37,200
+وكانت الـ double bond هنا الـ butane هيكون one
+
+234
+00:20:37,200 --> 00:20:40,160
+butane oxide، تنسوش الـ butane كان فيه منه one
+
+235
+00:20:40,160 --> 00:20:44,540
+butane وكان فيه منه two butane، الآن هذا على أي
+
+236
+00:20:44,540 --> 00:20:48,180
+double bond إجا؟ على الـ one، إذا هذا one butane
+
+237
+00:20:48,180 --> 00:20:52,780
+oxide طبعا، ممكن نفس المراكبات ينسميها نسبة إلى
+
+238
+00:20:52,780 --> 00:20:57,000
+الـ oxiraneهذه الحلقة بدون أي substituent ايش
+
+239
+00:20:57,000 --> 00:21:01,740
+اسمها Oxirane وترقيمها دائما يبدأ من ال Oxygen
+
+240
+00:21:01,740 --> 00:21:07,020
+واحد اتنين هنا على موقع اتنين شو بتحمل مثل اذا هذا
+
+241
+00:21:07,020 --> 00:21:16,600
+مثل او two مثل Oxirane لو طلعنا على المركب اللي
+
+242
+00:21:16,600 --> 00:21:23,870
+بعده هاي واحدتو مثل أوكز إيران لاحظوا معاك يمكن
+
+243
+00:21:23,870 --> 00:21:29,530
+هنا في الكتابة مش كاتبين احنا ال two ليش مش
+
+244
+00:21:29,530 --> 00:21:34,870
+كاتبينها؟ لأنه مافيش احتمال تاني يعني لو اجت المثل
+
+245
+00:21:34,870 --> 00:21:39,370
+هنا بده تكون two مثل طب لو حطيناها هنا بنعدنا هنا
+
+246
+00:21:39,370 --> 00:21:43,070
+two مثل يعني لمثل واحدة لا يمكن الا تكون على موقع
+
+247
+00:21:43,070 --> 00:21:46,130
+اتنين فيه ولمثل واحدة لا يمكن الا تكون على موقع
+
+248
+00:21:46,130 --> 00:21:54,010
+اتنينلكن لو صار عندي مثلا زي هذا المركب هاي carbon
+
+249
+00:21:54,010 --> 00:21:58,430
+تنتين تلاتة أربعة كان هنا double bond وكان المركب
+
+250
+00:21:58,430 --> 00:22:03,390
+cis-2-butyl فعلنا مع ال bare acid بيعطينا cis-2
+
+251
+00:22:03,390 --> 00:22:07,230
+-butyl oxide في ال common name لو أجينا بنسميه على
+
+252
+00:22:07,230 --> 00:22:09,730
+تسمية الكيمياء الحلقية
+
+253
+00:22:15,980 --> 00:22:21,160
+على موقع اتنين و تلاتة منها، شوفي عندي، Dimethyl،
+
+254
+00:22:21,160 --> 00:22:26,140
+في هذه الحالة أنا صرت مضطر ان احط الأرقام، ليش؟
+
+255
+00:22:26,140 --> 00:22:30,400
+لأنه لو عندي مجموعتين مثل اللي هم اكتر من احتمال،
+
+256
+00:22:30,400 --> 00:22:34,400
+انا كان .. لأ، واحد مستحيل، لأن ال Oxygen ما
+
+257
+00:22:34,400 --> 00:22:37,460
+بيحملش اشي تاني، ال Oxygen بس رابطتين، ايش
+
+258
+00:22:37,460 --> 00:22:43,040
+الاحتمال التاني؟ ايش الاحتمال التاني لما يكون عندي
+
+259
+00:22:43,040 --> 00:22:45,120
+مجموعتين مثل على ال Oxygen؟
+
+260
+00:22:50,280 --> 00:22:53,800
+بعيدا .. هذا عشانه معاجيها واحدة بنقول cis مش
+
+261
+00:22:53,800 --> 00:23:02,120
+مختلفين أنا بدي على المواقع ايوة من اتنين ممكن
+
+262
+00:23:02,120 --> 00:23:08,840
+مجموعتين المثل يكونوا هنا لو أتيكم هذا المركب صموه
+
+263
+00:23:08,840 --> 00:23:13,640
+في الامتحان شو هتصموه في هذه الحلقة؟ one two three
+
+264
+00:23:13,640 --> 00:23:18,580
+two two die مثل Ox and Rail طب لو سألناك هو هذا
+
+265
+00:23:18,580 --> 00:23:23,740
+cis ولا trans؟مافيش دائرة الـ cis والترانس هنا
+
+266
+00:23:23,740 --> 00:23:27,540
+لأنه احنا سبق قلنا دائرة ال cis والترانس سواء
+
+267
+00:23:27,540 --> 00:23:31,560
+حوالين ال double bond او حوالين الحلقة بتطلب انه
+
+268
+00:23:31,560 --> 00:23:36,200
+كل كربونا يكون عليها مجموعتين مختلفتين مجموعتين
+
+269
+00:23:36,200 --> 00:23:39,920
+مختلفتين اذا هنا في عند دائرة ال cis والترانس فعلا
+
+270
+00:23:39,920 --> 00:23:44,000
+هي ال cis two three dimethyl oxirane وهذا لما يكون
+
+271
+00:23:44,000 --> 00:23:50,440
+عكس بعض لترانس two three dimethyl oxirane واضح؟
+
+272
+00:23:53,560 --> 00:23:58,600
+الان هذه ال Oxirans لما قولنالكوا كيف بتتحطر ذكرنا
+
+273
+00:23:58,600 --> 00:24:02,320
+انها بشكل أساسي من ال bare acids يعني هاي مثلا
+
+274
+00:24:02,320 --> 00:24:11,240
+Cyclohexane مع bare acid بيعطيني Cyclohexane Oxide
+
+275
+00:24:12,210 --> 00:24:17,490
+أو إثنين سواء مع Fair Acid أو صناعيا لأنه يلزمنا
+
+276
+00:24:17,490 --> 00:24:20,910
+كتير ال Oxirane بيحضروا مع ال Oxygen في وجود
+
+277
+00:24:20,910 --> 00:24:26,330
+silver catalyst ودرجة حرارة 250 وضغط برضه بيعطينا
+
+278
+00:24:26,330 --> 00:24:31,290
+ال Oxirane واضح؟إذن هي العملية في الآخر Oxidation
+
+279
+00:24:31,290 --> 00:24:34,710
+لا ال الكنز الكبيرة بيستعملوا ال bare acids ال
+
+280
+00:24:34,710 --> 00:24:38,410
+إيثيلين لأنه صناعة و الصناعة هي اللي فيها استعمال
+
+281
+00:24:38,410 --> 00:24:41,730
+درجات حرارة عالية و استعمال ضغط و ما إلى ذلك
+
+282
+00:24:41,730 --> 00:24:46,510
+فبياخدوا إيثيلين مع أكسجين silver catalyst حرارة
+
+283
+00:24:46,510 --> 00:24:54,150
+ضغط بيعطينا الأمس إليههذا الـ Oxirane اللي هو أبسط
+
+284
+00:24:54,150 --> 00:24:59,610
+Cyclic Ether لكن هذا Cyclic Ether مهم كتير لأنه له
+
+285
+00:24:59,610 --> 00:25:05,710
+تطبيقات في التحضيرات العضوية وانا بتهيأها ليه؟ انه
+
+286
+00:25:05,710 --> 00:25:06,670
+احنا أخدنا
+
+287
+00:25:09,100 --> 00:25:14,940
+طبعته احنا أخدنا بعض التطبيقات تبعته لما نيجي
+
+288
+00:25:14,940 --> 00:25:20,400
+نفعله اول اشي لازم نعمل التفاعل ب acidic medium
+
+289
+00:25:20,400 --> 00:25:23,800
+لازم نعمل التفاعل ب acidic medium بيعمل
+
+290
+00:25:23,800 --> 00:25:27,340
+protonation هنا الان بعديك لو فعلنا مع الميه الميه
+
+291
+00:25:27,340 --> 00:25:28,960
+بتحط any uq file
+
+292
+00:25:32,960 --> 00:25:38,440
+واضح اذا كأنه الميه او اي ال يوكليوفايل انتم
+
+293
+00:25:38,440 --> 00:25:42,080
+تتخيلوا ان هذا ال oxirid معاي ال يوكليوفايل بده
+
+294
+00:25:42,080 --> 00:25:46,180
+يهاجم لليوكليوفايل بهذا الشكل وهذا الرابط تكسل
+
+295
+00:25:46,180 --> 00:25:55,620
+فبصير عند ال يوكليوفايل هاي ال يوكليوفايل CH2 كمان
+
+296
+00:25:55,620 --> 00:25:59,540
+CH2 OH
+
+297
+00:26:00,800 --> 00:26:05,280
+هذا الجزء اللى حاطينه احنا هنا فى الدائرة من وين
+
+298
+00:26:05,280 --> 00:26:11,460
+اتى من الـ Ox-Urane وهذا النيوكليوفايل اللى بيهجم
+
+299
+00:26:11,460 --> 00:26:17,440
+هذه الكربونة فبصير عندنا هنا CH2 CH2 OH وهذا
+
+300
+00:26:17,440 --> 00:26:21,860
+النيوكليوفايل اللى من برا واضح مثلا لو كان عندكم
+
+301
+00:26:21,860 --> 00:26:23,500
+النيوكليوفايل Methanol
+
+302
+00:26:30,420 --> 00:26:35,440
+ال O مثل كأنه لنيكوليوفايل هنا O مثل لو كان عندكم
+
+303
+00:26:35,440 --> 00:26:40,420
+مثلا إثالين غلايكول واحدة من هدولة ال O H بتهاجم
+
+304
+00:26:40,420 --> 00:26:48,460
+بتفتح حلقة CH2 CH2 OH لو كان عندكم فين ال MgBr مار
+
+305
+00:26:48,460 --> 00:26:53,340
+عليكم فين ال MgBr يمكن المحاضرة الماضية هذا اللي
+
+306
+00:26:53,340 --> 00:26:58,350
+سمناه احنا ايش؟الـ Greenyard Reagent والـ
+
+307
+00:26:58,350 --> 00:27:02,370
+Greenyard Reagent اتفقنا ان هو يمثل الـ
+
+308
+00:27:02,370 --> 00:27:09,130
+nucleophile بمعنى فنل مع زوج الالكترونات، تطلعوا
+
+309
+00:27:09,130 --> 00:27:14,490
+هنا زوج الالكترونات كأنه تابع لمن؟ للفنل، بناء على
+
+310
+00:27:14,490 --> 00:27:17,970
+ذلك هذا زوج الالكترونات اللي على الفنل هو اللي
+
+311
+00:27:17,970 --> 00:27:21,630
+بيجي يهاجمها لو بتكون طابقوا على هذه المعادلة كأن
+
+312
+00:27:21,630 --> 00:27:26,310
+اللي عندكم هي فنلهيزوج الإلكترونات بيهاجم هنا
+
+313
+00:27:26,310 --> 00:27:35,310
+بيعمل ال bond بيصير عندي CH2 CH2 finally OH واضح؟
+
+314
+00:27:36,680 --> 00:27:41,280
+إذا لو احنا بنجي .. بنجيبلكوا سؤال synthesis كيف
+
+315
+00:27:41,280 --> 00:27:46,940
+ممكن نتحضروا مركب إذا لمحتوا في هذا المركب مجموعة
+
+316
+00:27:46,940 --> 00:27:52,920
+CH2 CH2 OH إذا بإمكانكوا تتخيلوا أن هذه المجموعة
+
+317
+00:27:52,920 --> 00:28:01,290
+أصلها كان Oxirane واضح؟ إذا لمحتوا مجموعةالـ CH2
+
+318
+00:28:01,290 --> 00:28:06,830
+CH2 OH بتكون تصيروا تفكروا أن هذه المجموعة الأصل
+
+319
+00:28:06,830 --> 00:28:12,910
+تبعها كان Oxirane لأن حلقة Oxirane بتفتح لما تتفعل
+
+320
+00:28:12,910 --> 00:28:19,590
+مع ال eucleophiles و بتعطينا مركبات تحتوي على هذه
+
+321
+00:28:19,590 --> 00:28:21,450
+المجموعة CH2 CH2 OH
+
+322
+00:28:27,970 --> 00:28:33,090
+تنسوش تحطوا ال O هذي اللي مانسية في الراسي أول
+
+323
+00:28:33,090 --> 00:28:42,890
+مركّب O H طبعا
+
+324
+00:28:42,890 --> 00:28:49,910
+ال cyclic ethers مش بس حلقات ثلاثية ممكن يكونوا
+
+325
+00:28:49,910 --> 00:28:55,640
+موجودين على شكلحلقة رباعية ممكن يكون يعني رباعية
+
+326
+00:28:55,640 --> 00:28:59,840
+يعني زي هيك oxygen و أربع ذضار ممكن يكونوا على شكل
+
+327
+00:28:59,840 --> 00:29:05,440
+حلقات خماسية ممكن سداسية ممكن في حلقات سداسية يكون
+
+328
+00:29:05,440 --> 00:29:08,160
+فيها two oxygens يعني
+
+329
+00:29:13,210 --> 00:29:18,250
+واضح؟ الان المركب اللى فى حلقة ربعية مش كتير
+
+330
+00:29:18,250 --> 00:29:24,250
+مشهوره يمكن عشان هيك احنا مش راسمينه بيسموه OXYZ
+
+331
+00:29:24,250 --> 00:29:31,250
+مش كتير مشهور المركب اللى فى حلقة خماسية هذا مشهور
+
+332
+00:29:31,250 --> 00:29:36,590
+كتير هذا يستعمل فى الكيميا القضوية ك solvent اسمه
+
+333
+00:29:39,570 --> 00:29:44,370
+واختصاره THF كتير بتلاحظوا موجود عندكم solvent
+
+334
+00:29:44,370 --> 00:29:49,450
+اسمه THF أو Tetrahydrofuran هذا عبارة عن Cyclic
+
+335
+00:29:49,450 --> 00:29:53,450
+Ether الأن المركب اللي في الحلقة السادسية
+
+336
+00:29:53,450 --> 00:29:56,590
+Tetrahydropyrene
+
+337
+00:29:56,590 --> 00:30:04,100
+Tetrahydropyrene إذا كان في عندكأكسجنتين في الحلقة
+
+338
+00:30:04,100 --> 00:30:08,440
+السادسية بيصير المركب اللي اسمه دايوكسين هذا
+
+339
+00:30:08,440 --> 00:30:14,740
+الديوكسين هو عبارة عن مركب سام كارسينوجينيك مركب
+
+340
+00:30:14,740 --> 00:30:19,380
+كارسينوجينيك سام الديوكسينيمكن بتذكروا من عدة
+
+341
+00:30:19,380 --> 00:30:26,240
+سنوات يمكن قبل حوالي خمس سنين، ستة الأسبان اكتشفوا
+
+342
+00:30:26,240 --> 00:30:29,600
+الناس أنه في الزيوت اللي بيبيعوها زيت الزتون فيه
+
+343
+00:30:29,600 --> 00:30:33,920
+دايوكسين سام وبناء على ذلك سحبوا كل شحنات زيت
+
+344
+00:30:33,920 --> 00:30:38,400
+الزتون تبعتهم من مصر ومن السعودية ومن اليمن ليش كل
+
+345
+00:30:38,400 --> 00:30:43,860
+هذا الكلام صار؟ لأنه لقوا أن هذه مخلوطة بدايوكسين
+
+346
+00:30:45,110 --> 00:30:49,010
+لجوا انه فيها نسبة ديوكسين هم الحقيقة لما ياخدوا
+
+347
+00:30:49,010 --> 00:30:54,070
+بقايا الزيوت يعملولها استخلاص و extraction ب
+
+348
+00:30:54,070 --> 00:30:58,690
+solvents زي ال .. زي ال hexanes و ال heptanes و ال
+
+349
+00:30:58,690 --> 00:31:04,250
+.. هي ال .. ال fuels هذه بيكون جزء منها ديوكسين و
+
+350
+00:31:04,250 --> 00:31:07,690
+ضال مخلوط مع الزيت فلما بيحللوا الزيت لجوا فيه
+
+351
+00:31:07,690 --> 00:31:14,670
+نسبة ديوكسين فسحبوا الزيوت تبعتهم من الأسواق واضح؟
+
+352
+00:31:15,720 --> 00:31:22,760
+غير هدول المُركّبات، في عيلة جديدة تدخل الجمال،
+
+353
+00:31:22,760 --> 00:31:25,120
+يعني الواحدة ليها خطر، وغيرها كلها بالفعلات
+
+354
+00:31:25,120 --> 00:31:32,380
+التطريزيةاللي هم مجموعة مُركّبات اكتشفت حديثًا،
+
+355
+00:31:32,380 --> 00:31:35,720
+يعني مش زمان تم اكتشافها، يعني الناس اللي اشتغلوا
+
+356
+00:31:35,720 --> 00:31:40,140
+عليها اشتغلوا تقريبًا في أوائل التمانينات،
+
+357
+00:31:40,140 --> 00:31:43,520
+وبالنسبة لنا أوائل التمانينات ما تُعتبرش بعيدة
+
+358
+00:31:43,520 --> 00:31:47,640
+نسبيًا، لأنه احنا بنحكي أحيانًا عن بعض الشغلات قبل
+
+359
+00:31:47,640 --> 00:31:51,920
+مية ومية وخمسين سنةيعني بتذكروا لما حكينا مثلا عن
+
+360
+00:31:51,920 --> 00:32:00,440
+البنزين .. البنزين اكتشافه كسائل كان 1825 يعني قبل
+
+361
+00:32:00,440 --> 00:32:06,180
+حوالي 200 سنة لما نحكي مثلا عن green yard reagent،
+
+362
+00:32:06,180 --> 00:32:12,540
+green yard أخد جائزة نوبل في الكيميا سنة 1911هذا
+
+363
+00:32:12,540 --> 00:32:16,400
+بالظبط قبل مائة سنة، مظبوط ولا لا؟ لكن هدولة
+
+364
+00:32:16,400 --> 00:32:19,900
+المركبات الحلوين اللي موجودين هنا بيسموهم ال crown
+
+365
+00:32:19,900 --> 00:32:24,740
+ethers ال crown ethers هدولة في ال .. في
+
+366
+00:32:24,740 --> 00:32:28,580
+التمانينات اكتشفوا و الناس اللي اشتغلوا عليهم و
+
+367
+00:32:28,580 --> 00:32:31,780
+طلعوهم أخدوا عليهم جائزة نوبل في الكيميا بالألف
+
+368
+00:32:31,780 --> 00:32:37,360
+تسعمائة و سبعة و ثمانين ألف
+
+369
+00:32:37,360 --> 00:32:41,440
+تسعمائة و سبعة و ثمانين سنة ميلادكوا ولا برضه قبل؟
+
+370
+00:32:42,950 --> 00:32:48,470
+خلاص خلاص انتوا مولد 2010 فيعتبروا
+
+371
+00:32:48,470 --> 00:32:52,630
+نسبية نجدال ايش هم هدولة ال crown ethers اللي لهم
+
+372
+00:32:52,630 --> 00:32:58,250
+الأهمية زي ما انتوا بتلاحظوا Cyclic ethers فيهم
+
+373
+00:32:58,250 --> 00:33:03,410
+تكرار لمجموعة CH2 CH2 و بعدين Oxygen CH2 CH2 و
+
+374
+00:33:03,410 --> 00:33:06,690
+بعدين Oxygen CH2 CH2 و بعدين Oxygen CH2 CH2 و
+
+375
+00:33:06,690 --> 00:33:11,920
+بعدين Oxygen و ممكن يكونوا على عدةأحجام ممكن يكون
+
+376
+00:33:11,920 --> 00:33:16,540
+على عدة أحجام الان كيف بيجوا بيسموهم لما يجوا
+
+377
+00:33:16,540 --> 00:33:20,180
+يسموهم خلينا نبدأ نعد من أي نقطة يعني لو بدأنا من
+
+378
+00:33:20,180 --> 00:33:24,640
+هنا و اتحركنا نعد كل الظرات واحد اتنين تلاتة اربعة
+
+379
+00:33:24,640 --> 00:33:28,660
+خمسة ستة سبعة تمانية تسعة عشرة احد عشر اتمعش
+
+380
+00:33:28,660 --> 00:33:34,890
+فبنقول هذا المركب اتمعش اتمعش هي العدد الكليللضرر
+
+381
+00:33:34,890 --> 00:33:38,590
+بعد ذلك بيقول crown معناه crown انه بيدرسله استعمل
+
+382
+00:33:38,590 --> 00:33:45,570
+CH2 CH2 O CH2 CH2 O و بعدين بيحط عدد الأكسجين كام
+
+383
+00:33:45,570 --> 00:33:51,450
+أكسجين اربعة اذا هنا بيقول twelve crown four معناه
+
+384
+00:33:51,450 --> 00:33:57,110
+total atoms twelve و عدد الأكسجين four
+
+385
+00:34:01,100 --> 00:34:05,280
+واضح؟ الان لو اجينا على هذا و عدينا مثلا من هنا و
+
+386
+00:34:05,280 --> 00:34:12,160
+اتحركنا 15 atoms فبصير 15 crown 5 لو اجينا على
+
+387
+00:34:12,160 --> 00:34:17,860
+اللي بعده و عدينا 18 ثغرة بكم أكسجينة؟ 6 أكسجينات
+
+388
+00:34:17,860 --> 00:34:26,940
+فبصير 80 crown 8 80 crown 6 طبعا بيلزمكم اتدربوا
+
+389
+00:34:26,940 --> 00:34:30,820
+ايدكم على رسمهأنا المرة اللى فاتت فى الامتحان
+
+390
+00:34:30,820 --> 00:34:36,920
+جبتلهم ارسمولى 18 crown 6 لو
+
+391
+00:34:36,920 --> 00:34:41,100
+جبنالكوا فى الامتحان ارسموا 18 crown 6 انتوا
+
+392
+00:34:41,100 --> 00:34:47,220
+بتفكروه سهل هل كانت تروحوا بهدوء و جربوا ارسموا
+
+393
+00:34:47,220 --> 00:34:50,880
+هتلاقوا هتخربشوا مية مرة قبل ما تظبطوا فعوضوا
+
+394
+00:34:50,880 --> 00:34:54,760
+حالكم دائما ال organic بدها تطبيق باليد عشان
+
+395
+00:34:54,760 --> 00:35:01,660
+ترسموا الشكلهذه المراكبات الحقيقة ليش الناس اللي
+
+396
+00:35:01,660 --> 00:35:06,920
+اشتغلوها أخدوا عليها جوائز وتعتبر مراكبات مهمة ..
+
+397
+00:35:06,920 --> 00:35:14,170
+تعتبر مراكبات مهمة لأن في إلها كثير تطبيقاتجزء ..
+
+398
+00:35:14,170 --> 00:35:18,810
+جزء من التطبيقات تبعتها أنه أنا طالما عندي ..
+
+399
+00:35:18,810 --> 00:35:22,610
+طالما عندي oxygens هنا و ال oxygens بتحمل إيش؟
+
+400
+00:35:22,610 --> 00:35:28,170
+أزواج .. إلكترونات، مصبوط ولا لأ؟ إذن، و الجزء هنا
+
+401
+00:35:28,170 --> 00:35:34,250
+إحنا بنقول إله cavity عارفين إيش يعني cavity؟
+
+402
+00:35:34,250 --> 00:35:38,870
+cavity الوسعة أو الفراغة الدهانة، هذه cavity،
+
+403
+00:35:38,870 --> 00:35:46,480
+الحفرةواضح الفجوة الجزء له cavity الان هذه ال
+
+404
+00:35:46,480 --> 00:35:51,260
+cavity ممكن يدخل فيها ايون موجب الايون الموجب ليش
+
+405
+00:35:51,260 --> 00:35:55,280
+بيجي بدخلها لو بتريح لأنه في أزواج إلكترونات يعمل
+
+406
+00:35:55,280 --> 00:36:01,950
+bonding معاها يعني نحط هنا metal plusملاحظين انتوا
+
+407
+00:36:01,950 --> 00:36:06,450
+metal plus ممكن يدخل بالفجوة الان اذا انتوا
+
+408
+00:36:06,450 --> 00:36:12,150
+بتيجيوا تتطلعوا هنا الفجوة
+
+409
+00:36:12,150 --> 00:36:17,550
+بتعتمد على نوع ال ether يعني هذا ال ether ال 12
+
+410
+00:36:17,550 --> 00:36:23,250
+crown 4 قارن الفجوة تبعته مع ال 15 crown 5 قارن
+
+411
+00:36:23,250 --> 00:36:29,830
+الفجوة تبعته معالـ 18 crown 6 بتلاحظوا ان حجم
+
+412
+00:36:29,830 --> 00:36:37,770
+الفجوات مختلف هذا الكلام اشبدل على ان الايونات
+
+413
+00:36:37,770 --> 00:36:43,690
+المعدنية حجمها مختلف فكأنه كل فجوة بتتناسب مع حجم
+
+414
+00:36:43,690 --> 00:36:50,990
+ايون معين كل فجوة بتتناسب مع حجم ايون معين بمعنى
+
+415
+00:36:50,990 --> 00:36:56,700
+لو انا هنا حطيت ايون كبير بصبطبتسعش الفجوة، لو أنا
+
+416
+00:36:56,700 --> 00:37:01,480
+حطيت هنا أيون صغير كتير، بيطلع من الفجوة، بيعملش
+
+417
+00:37:01,480 --> 00:37:06,560
+ارتباط، لازم ال أيون يكون جد و جدالفجوة تقريبا
+
+418
+00:37:06,560 --> 00:37:12,900
+فبناء على ذلك بيستفيدوا من هذه الشغلة في الصناعة
+
+419
+00:37:12,900 --> 00:37:18,540
+وفي ال biology مثلا لو انا اجيت اخدت تلت ايونات ال
+
+420
+00:37:18,540 --> 00:37:23,640
+sodium و ال potassium و ال cesium وشوفت قداش ال
+
+421
+00:37:23,640 --> 00:37:30,080
+diameter تبعهم قداش القطر تبعهم ال sodium قطره 1.9
+
+422
+00:37:30,080 --> 00:37:33,080
+angstrom ال potassium 2.6
+
+423
+00:37:36,290 --> 00:37:43,250
+3.34 الان لو جيت جبت هذا المُركّب وقصد قداش الفجوة
+
+424
+00:37:43,250 --> 00:37:48,050
+تبعته كل العلماء بيشتغلوا بقصه ال cavity تبعته 2.6
+
+425
+00:37:48,050 --> 00:37:55,230
+إلى 3.2 cavity تقريبا الان لو جيت قولت أحط هذا ال
+
+426
+00:37:55,230 --> 00:38:00,150
+crown إيثر في محلول يحتوي على التلت أيونات هدولة
+
+427
+00:38:00,150 --> 00:38:02,590
+ان هو اللي بيصبط معه ال potassium
+
+428
+00:38:05,360 --> 00:38:11,400
+هذا متناسب مع هذه الفجوة بناء على ذلك لو كان عندي
+
+429
+00:38:11,400 --> 00:38:16,100
+محلول فيه تلت أيونات و حطيت هذا ال crown بياخد ال
+
+430
+00:38:16,100 --> 00:38:19,860
+potassium و يسيب التنين التانين اتلاحظين انتوا؟
+
+431
+00:38:19,860 --> 00:38:25,920
+يعني ال cavity تبعته بس على جد ال potassium ال
+
+432
+00:38:25,920 --> 00:38:33,040
+cavity تبعته بس على جد ال potassiumمش على جد
+
+433
+00:38:33,040 --> 00:38:39,660
+السيزيام كبير ولا السوديوم يعتبر صغير واضح؟ يمكن
+
+434
+00:38:39,660 --> 00:38:45,120
+هذا الكلام يلو تطبيق فتفتر أكثر فتفتر احنا ناخد
+
+435
+00:38:45,120 --> 00:38:51,360
+نظرينا ان السوديوم بما انه تكره عيب كبير دائمية
+
+436
+00:38:51,360 --> 00:38:54,620
+ارتباط كفر كفر يعني من الحكي الكبير بوصل لصغير
+
+437
+00:38:54,620 --> 00:38:58,760
+بعكس اللي .. اه بس لصغير اللي هو بده يعمل ارتباط
+
+438
+00:38:59,460 --> 00:39:05,020
+بدو يعمل ارتباط، واضح؟ بدو يعمل ارتباط، هل بيقدر و
+
+439
+00:39:05,020 --> 00:39:09,580
+هو صغير، هاي كل حجم الـmetal في درجة، هالجد و هاي
+
+440
+00:39:09,580 --> 00:39:13,580
+حجم الخضر، هل بيقدر يصل لهدول أزواج الإلكترونية
+
+441
+00:39:13,580 --> 00:39:17,260
+يعمل ارتباط معهم؟ مابقدرش يعمل ارتباط، زي ما هذا
+
+442
+00:39:17,260 --> 00:39:21,700
+رابط من كل الجهةهذا لما يكون بهذا الشكل القطر تبعه
+
+443
+00:39:21,700 --> 00:39:28,000
+فيمكن يعمل ال bonding بس لصغير لا مابظبطش هذا
+
+444
+00:39:28,000 --> 00:39:32,380
+الكلام له حقيقة تطبيقات كتير سواء في الكيميا
+
+445
+00:39:32,380 --> 00:39:38,680
+ككيميا او في الفروع الطبية المتعلقة بالكيميا مثلا
+
+446
+00:39:38,680 --> 00:39:43,460
+جزء من تطبيقاته ان لو انا اخدت مركب ايوني زي ال
+
+447
+00:39:43,460 --> 00:39:50,400
+potassium permanganate ال KMnO4هذا الكيامان او فور
+
+448
+00:39:50,400 --> 00:39:56,500
+تخيل لو انا قلت ادوب في البنزين البنزين مش البنزين
+
+449
+00:39:56,500 --> 00:40:03,090
+solvent الكيامان او فور في البنزين لا يدوبمابيدوبش
+
+450
+00:40:03,090 --> 00:40:08,970
+ليش مابيدوبش لأن هذا الـ KMnO4 K Plus MnO4 minus
+
+451
+00:40:08,970 --> 00:40:13,090
+Ionic وهذا Non Ionic وانتوا القاعدة العامة اللي
+
+452
+00:40:13,090 --> 00:40:16,570
+عندكم في الذابية Like Dissolve Like هذا و هذا مش
+
+453
+00:40:16,570 --> 00:40:21,350
+من نفس الأشياء هذا Ionic وهذا مش Ionic بناء على
+
+454
+00:40:21,350 --> 00:40:26,730
+ذلك لو أنا لغرض التفاعل بدي أفعل مركب الـ KMnO4 في
+
+455
+00:40:26,730 --> 00:40:33,170
+البنزينما بيدوبش طب كيف بيدوبوه بيجوا جوا البنزين
+
+456
+00:40:33,170 --> 00:40:38,210
+جوا البنزين يعني ال servant اللي عنده بنزين بيحطوا
+
+457
+00:40:38,210 --> 00:40:45,970
+ال crown هذا اللي هو ال 18 crown 6 بيحطوا ال 18
+
+458
+00:40:45,970 --> 00:40:51,830
+crown 6 هذا ال 18 crown 6 لما انا بدي احط kmn04
+
+459
+00:40:51,830 --> 00:41:00,980
+ايش بيعمل؟ بياخد ال Kفي الـ cavity تبعته صارت دوّب
+
+460
+00:41:00,980 --> 00:41:05,400
+المُركّب لأن الـ crown بيدوب في البنزين و الـ
+
+461
+00:41:05,400 --> 00:41:10,780
+crown بيدوّب البوتاسيوم في قلبه بيحط البوتاسيوم في
+
+462
+00:41:10,780 --> 00:41:14,660
+قلب الـ cavity تبعته وبناء على ذلك برمجانات
+
+463
+00:41:14,660 --> 00:41:20,300
+البوتاسيوم مع البنزين لا تدوب مع بنزين مخلوط فيه
+
+464
+00:41:20,300 --> 00:41:25,420
+شوية crown بيدوب أنا مش مهم عندي لغرض التفاعل
+
+465
+00:41:25,420 --> 00:41:30,390
+بالمناسبة لأن crownولا البوتاسيوم ولا البنزين
+
+466
+00:41:30,390 --> 00:41:34,070
+عارفين إنتوا إيش اللي أنا مهم عندى بالتفاعل؟ الأمن
+
+467
+00:41:34,070 --> 00:41:38,190
+O4 minus اللى ضالت حرة بتمشي فى البنزين لأنها عامل
+
+468
+00:41:38,190 --> 00:41:42,850
+مؤكسد لما درستوا الأكسدة و العوامل المؤكسدة أنه
+
+469
+00:41:42,850 --> 00:41:46,450
+اللى كان اسمه عامل مؤكسد ومهم كتير بالنسبة إليه
+
+470
+00:41:46,450 --> 00:41:51,190
+بيرمانجانات البوتاسيوم يعني إنه .. إن واحدة تيجي
+
+471
+00:41:51,190 --> 00:41:54,990
+تقول يا الله البوتاسيوم خسرناه راح جوا ال crownمع
+
+472
+00:41:54,990 --> 00:41:58,570
+السلامة، ما هو المطلوب؟ أنا المطلوب عندى لغرض
+
+473
+00:41:58,570 --> 00:42:04,190
+إجراء تفاعل X ده جزء البوتاسيوم على جزء الـMnO4-
+
+474
+00:42:04,190 --> 00:42:09,890
+فالبوتاسيوم خلّى يدوب في الـ crown و الـ MnO4-
+
+475
+00:42:09,890 --> 00:42:13,970
+بتصير تمشي في المحلول طبعا لاحظوا معى لما تمت
+
+476
+00:42:13,970 --> 00:42:19,400
+عملية ذابيها ديبرمجانات البوتاسيوم شو لونها؟بنفسجي
+
+477
+00:42:19,400 --> 00:42:26,220
+بناء على ذلك البنزين هنا بيصير لونه بنفسجي البنزين
+
+478
+00:42:26,220 --> 00:42:30,480
+اللي مدوق فيه برمجانات البوتاسيوم بمساعدة الـ
+
+479
+00:42:30,480 --> 00:42:35,240
+ethyl crown 6 بيسموه pear ball بنزينماذا يعني
+
+480
+00:42:35,240 --> 00:42:40,540
+بيربو البنزين؟ البنزين البنفسجي وهذا يعتبر
+
+481
+00:42:40,540 --> 00:42:45,900
+oxidizing agent عامل مؤكسد ليش عامل مؤكسد؟ بسبب
+
+482
+00:42:45,900 --> 00:42:49,280
+وجود مجموعة البرمانجانات الحرة ومجموعة
+
+483
+00:42:49,280 --> 00:42:54,820
+البرمانجانات من أفضل العوامل المؤكسدة، مظبوط ولا
+
+484
+00:42:54,820 --> 00:43:01,060
+لا؟ هذه تطبيق كيميائي استفدنا فيه من قصة الـ
+
+485
+00:43:01,060 --> 00:43:09,570
+cavityطبعا كتير مرات بيستعملوا .. بيستعملوا كلمات
+
+486
+00:43:09,570 --> 00:43:16,730
+موازية في اللغة العربية لفكرة الضيف والمضيف، يعني
+
+487
+00:43:16,730 --> 00:43:22,390
+لما هذا يكون هذا في وسع، إيش بنعتبره؟ مضيف، و
+
+488
+00:43:22,390 --> 00:43:25,830
+الآيون اللي بدأ يدخل فيه؟ ضيف، باللغة الإنجليزية
+
+489
+00:43:25,830 --> 00:43:33,120
+إيش بيقولوها؟host guest host guest هذا ال host و
+
+490
+00:43:33,120 --> 00:43:36,800
+ال potassium اللي إجا فيه ال guest إذا صار عندى
+
+491
+00:43:36,800 --> 00:43:40,340
+ضيف و مضيف host guest لكن في البنزين العكس صار
+
+492
+00:43:40,340 --> 00:43:44,960
+البنزين هو ال host لا أبدا أبدا في البنزين البنزين
+
+493
+00:43:44,960 --> 00:43:50,240
+solvent و ال crown دايب فيه دايب في البنزين الآن
+
+494
+00:43:50,240 --> 00:43:55,140
+إيش اللي إجا جوا ال crown ال K اللي إجا في قلبه
+
+495
+00:43:55,140 --> 00:44:03,670
+واضح؟هي هنا عندكم صورة شبيهة لمضاد حيوي يستعمل
+
+496
+00:44:03,670 --> 00:44:08,710
+شبيه فكرته زي ما بتلاحظوا بإيش بال crown ethers
+
+497
+00:44:08,710 --> 00:44:12,770
+وإن كان على أكبر لكن في عندكم هنا oxygens اشملها
+
+498
+00:44:12,770 --> 00:44:18,490
+متكررة بناء على ذلك هذه ال oxygens ممكن تحتوي ايون
+
+499
+00:44:18,490 --> 00:44:23,060
+في قلبها ولا لأ؟زي آيون البوتاسيوم وهذا المضاد
+
+500
+00:44:23,060 --> 00:44:28,620
+الحيوي بياخد تحديدا حسب حجم الـ cavity الفراغة
+
+501
+00:44:28,620 --> 00:44:32,180
+اللي فيها للبوتاسيوم و بيمشي في البوتاسيوم من داخل
+
+502
+00:44:32,180 --> 00:44:36,620
+جدار الخلية يعني شوفوا كيف عملية أنه بنتقل كل هذا
+
+503
+00:44:36,620 --> 00:44:39,680
+بدخل في جدار الخلية و بيدخل حامل معاه إيش؟
+
+504
+00:44:39,680 --> 00:44:44,600
+البوتاسيوم بيدخل جدار الخلية و بيدخل حامل معاه
+
+505
+00:44:44,600 --> 00:44:50,660
+البوتاسيومبهيك تقريبا بنكون انتهينا من هذا الفصل
+
+506
+00:44:50,660 --> 00:44:53,500
+اللي هو ال ether ومتعلقاته الحصة اللي جاي ان شاء
+
+507
+00:44:53,500 --> 00:44:55,340
+الله بنبدأ في ال aldi heights
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d198ebc5db8a453fa0d949b0c1bcb6154e2c8a7b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo.srt
@@ -0,0 +1,1797 @@
+1
+00:00:06,440 --> 00:00:12,000
+اليوم إن شاء الله هنبدأ Chapter جديد اللي هو ال
+
+2
+00:00:12,000 --> 00:00:16,080
+Aromatic Compounds الفصل الرابع الـ Aromatic 
+
+3
+00:00:16,080 --> 00:00:23,980
+Compounds Chapter بسيط وسهل وممتع طبعا حتى نعرف
+
+4
+00:00:23,980 --> 00:00:28,340
+إيش موقعهم من الإعراب الـ Aromatic Compounds حتى
+
+5
+00:00:28,340 --> 00:00:34,640
+نعرف إيش موقعهم من الإعراب بنذكر التقسيم العام لل
+
+6
+00:00:34,640 --> 00:00:38,360
+Hydrocarbons لحظة ما قلنا إن في عندنا Saturated
+
+7
+00:00:38,360 --> 00:00:43,420
+Hydrocarbons وفي عندنا Unsaturated Hydrocarbons الـ
+
+8
+00:00:43,420 --> 00:00:47,520
+Unsaturated اللي كان فيهم Double Bonds فمن ال
+
+9
+00:00:47,520 --> 00:00:51,260
+Unsaturated الـ Alkenes كانت عندي بـ One Double Bond
+
+10
+00:00:51,260 --> 00:00:54,920
+والـ Alkynes بـ Two Double Bonds يعني بالـ Triple
+
+11
+00:00:54,920 --> 00:00:58,780
+Bond وكان عندنا الجزء الآخر اللي هو موضوع درسنا
+
+12
+00:00:58,780 --> 00:01:02,660
+اليوم الـ Aromatic Compounds اللي هي المركبات
+
+13
+00:01:02,660 --> 00:01:09,940
+الحلقية اللي فيها أكثر من رابطة زوجية وبدل الروابط
+
+14
+00:01:09,940 --> 00:01:13,240
+الزوجية بنقول عنهم بيكونوا Conjugated يعني بيكونوا
+
+15
+00:01:13,240 --> 00:01:17,840
+على شكل Double Single Double Single ولازم كل الـ
+
+16
+00:01:17,840 --> 00:01:22,600
+Aromatic Compounds يكونوا في إيش؟ في حلقة لازم 
+
+17
+00:01:22,600 --> 00:01:26,080
+عشان نحكي عن Aromatic Compounds نحكي عن حلقة يعني
+
+18
+00:01:26,080 --> 00:01:30,180
+لو بدنا نجيب لكم مركب مش حلقة ما حدش عمره يفكر أنه 
+
+19
+00:01:30,180 --> 00:01:33,880
+يصنفوا تحت Aromatic Compounds واضح؟
+
+20
+00:01:36,110 --> 00:01:41,090
+الآن إذا برضه بدنا نرجع لـ Slide نتذكر بعض
+
+21
+00:01:41,090 --> 00:01:44,830
+المعلومات بخصوص الـ Double Bond والـ Single Bond و
+
+22
+00:01:44,830 --> 00:01:48,730
+الـ Triple Bond أخذنا احنا الـ Bond Length وأخذنا
+
+23
+00:01:48,730 --> 00:01:53,980
+الـ Bond Angles والـ Rotation والـ Geometry والـ
+
+24
+00:01:53,980 --> 00:01:58,000
+Hybridization يمكن أكثر شيء بيهمنا نركز عليه الـ
+
+25
+00:01:58,000 --> 00:02:03,640
+Double Bond ليش Double Bond؟ لأنه البنزين موجود
+
+26
+00:02:03,640 --> 00:02:08,600
+فيه Double Bonds البنزين كحلقة سداسية موجود فيه 
+
+27
+00:02:08,600 --> 00:02:13,240
+Double Bonds واضح؟ يعني لو بدي أشوف أنا Model
+
+28
+00:02:13,240 --> 00:02:19,360
+للبنزين هي حلقة البنزين بهذا الشكل هذا الشكل في
+
+29
+00:02:19,360 --> 00:02:22,840
+حلقة البنزين زي ما أنتم شايفين فبتلاحظوا إيش اللي 
+
+30
+00:02:22,840 --> 00:02:27,420
+موجود عندي Double Single Double Single Double 
+
+31
+00:02:27,420 --> 00:02:29,640
+Single هذا اللي هي عملية اللي بنسميها ال
+
+32
+00:02:29,640 --> 00:02:34,260
+Conjugation إن الـ Double Bonds are Conjugated واضح
+
+33
+00:02:34,260 --> 00:02:40,060
+الآن كل Carbon كل Carbon من الـ Carbons الستة لو
+
+34
+00:02:40,060 --> 00:02:44,880
+أجيت أطلع عليها حقيقة بلاقيها على طرف Double Bond
+
+35
+00:02:44,880 --> 00:02:48,620
+يعني هي هذه طرف Double Bond هذه .. هذه .. هذه ..
+
+36
+00:02:48,620 --> 00:02:52,900
+هذه وبناء على ذلك لو أجينا بدنا نتساءل إيش الـ
+
+37
+00:02:52,900 --> 00:02:59,800
+Hybridization لكل Carbon هلاحظ أنه طالع منها اتجاه
+
+38
+00:02:59,800 --> 00:03:02,760
+اتجاهين ثلاثة
+
+39
+00:03:06,160 --> 00:03:15,260
+الزاوية 120 المجموع 360 إذا الـ Carbons اللي
+
+40
+00:03:15,260 --> 00:03:22,720
+موجودين في البنزين جميعهم sp2 Hybrid Carbons All
+
+41
+00:03:22,720 --> 00:03:28,300
+the Carbons in Benzene are sp2 Hybrid Carbons واضح
+
+42
+00:03:28,300 --> 00:03:37,290
+الـ Bond Angle 120 الـ Bond Angle 120 الآن بيجينا
+
+43
+00:03:37,290 --> 00:03:42,910
+شغلة كثير مهمة اللي هي الـ Bond Order والـ Bond
+
+44
+00:03:42,910 --> 00:03:50,690
+Length الـ Bond Order بنقصد فيه كم عدد الروابط بين
+
+45
+00:03:50,690 --> 00:03:56,900
+ذرتين الكربون كم عدد الروابط من ذرات الكربون الآن 
+
+46
+00:03:56,900 --> 00:04:01,940
+إذا كنت تتطلع على شكل واحد من هدول هتقول والله
+
+47
+00:04:01,940 --> 00:04:06,720
+الروابط في عنده Double وSingle وDouble وSingle
+
+48
+00:04:06,720 --> 00:04:10,580
+ودouble وSingle هذا الكلام لو أنه زي هيك والشكل 
+
+49
+00:04:10,580 --> 00:04:14,720
+ثابت الـ Single Bond أطول من الـ Double Bond أطلع 
+
+50
+00:04:14,720 --> 00:04:21,240
+طول الـ Single Bond بشكل عادل 154 Double Bond 134
+
+51
+00:04:21,540 --> 00:04:24,820
+فلو هذا الكلام .. لو شكل البنزين زي هيك .. إنه فيه
+
+52
+00:04:24,820 --> 00:04:29,040
+Double Bond وSingle Bond .. كان هذه بدها تكون 134
+
+53
+00:04:29,040 --> 00:04:34,140
+و الثانية بدها تكون 154 .. إذا هل بيكون الطول تبع
+
+54
+00:04:34,140 --> 00:04:40,280
+هدول متساوي؟ .. حيصير شكل البنزين كيف؟ غير منتظم
+
+55
+00:04:40,280 --> 00:04:47,840
+.. بمعنى مش الست روابط جت بعض الآن بالتجربة لاحظوا
+
+56
+00:04:47,840 --> 00:04:52,100
+إن البنزين الست روابط اللي موجودة فيه نفس الطول
+
+57
+00:04:52,100 --> 00:04:59,560
+واضح؟ الست روابط نفس الطول طيب ماشي نفس الطول هل 
+
+58
+00:04:59,560 --> 00:05:05,380
+هما يا ترى طولهم من طول الـ Double Bond اللي قصيرة
+
+59
+00:05:05,380 --> 00:05:09,680
+ولا من طول الـ Single Bond اللي طويلة اللي لاحظوا
+
+60
+00:05:09,680 --> 00:05:15,560
+إن طولهم شيء ما Between the Double Bond Lengths and
+
+61
+00:05:15,560 --> 00:05:18,960
+the Single Bond Lengths يعني طولهم جاي بين بين 
+
+62
+00:05:18,960 --> 00:05:25,140
+واضح طول الرابطة لا هو Double Bond قصير ولا هو
+
+63
+00:05:25,140 --> 00:05:30,380
+Single Bond طويل الآن السؤال كأنه إذا مش Double 
+
+64
+00:05:30,380 --> 00:05:33,560
+Bond إذا مش اثنين أو مش واحد إيش بدي يطلع أنا بدي
+
+65
+00:05:33,560 --> 00:05:38,480
+أطلع واحد ونصف اللي هو عدد الروابط بالظبط بيطلع
+
+66
+00:05:38,480 --> 00:05:43,890
+واحد ونصف الـ Bond Order .. الـ Bond Order في
+
+67
+00:05:43,890 --> 00:05:49,610
+البنزين لو هو واحد ولا هو اثنين واحد ونصف أنتم لو
+
+68
+00:05:49,610 --> 00:05:52,870
+كنتم بتشوفوا كيف هذا الكلام بيصير بيصير بسبب ال
+
+69
+00:05:52,870 --> 00:05:57,030
+Resonance إن هذه في لحظة من اللحظات Double Bond
+
+70
+00:05:57,030 --> 00:06:00,210
+وهذه Single Bond نتيجة الـ Resonance هذه بتصير
+
+71
+00:06:00,210 --> 00:06:04,150
+Double Bond وهذه Single Bond يعني كأنه هالمكانين
+
+72
+00:06:04,150 --> 00:06:07,090
+هدول لو أجيتوا طلعتوا كم Bond اللي موجود فيهم؟
+
+73
+00:06:07,090 --> 00:06:15,470
+واحد اثنين ثلاثة لما يصير في Resonance 1.5 إذا كل
+
+74
+00:06:15,470 --> 00:06:22,730
+رابطة في البنزين 1.5 Bond Order يعني عندي رابطة و
+
+75
+00:06:22,730 --> 00:06:26,270
+نص Bond
+
+76
+00:06:26,270 --> 00:06:33,180
+Order in بنزين is 1.5 بسبب الـ Resonance إنه في عندي
+
+77
+00:06:33,180 --> 00:06:38,020
+حركة في الـ Bonds Double Single Double Single مرة
+
+78
+00:06:38,020 --> 00:06:40,860
+هذه Double هذه Single مرة هذه Double هذه Single
+
+79
+00:06:40,860 --> 00:06:45,200
+المتوسط تبعهم إيش بده يطلع بده يطلع عندنا المتوسط
+
+80
+00:06:45,200 --> 00:06:49,260
+تبعهم واحد ونصف وعشان هيك الـ Bond Length للرابطة
+
+81
+00:06:49,260 --> 00:06:52,580
+في البنزين بيكون بين الرابطة القصيرة اللي هي الـ
+
+82
+00:06:52,580 --> 00:06:58,490
+Double Bond الـ 134 وبين الكبيرة 154 بالتجربة نثبت 
+
+83
+00:06:58,490 --> 00:07:06,730
+139 جاي قيمة بين القيمتين واضح فالـ Bond Length هيك
+
+84
+00:07:06,730 --> 00:07:14,100
+بيصير عندي واضح إن هو بين بين والـ Bond Order واحد
+
+85
+00:07:14,100 --> 00:07:17,280
+ونص بالظبط واحد ونصف يعني لما نسألكم The Bond
+
+86
+00:07:17,280 --> 00:07:22,480
+Order in بنزين is Two and One لأ لو Two and One
+
+87
+00:07:22,480 --> 00:07:26,260
+كان بيكون رابطة قصيرة ورابطة طويلة وشكل البنزين
+
+88
+00:07:26,260 --> 00:07:30,720
+غير منتظم لكن الحقيقة البنزين شكله منتظم الآن 
+
+89
+00:07:30,720 --> 00:07:34,860
+معلومة إضافية عن البنزين لأن كل هدول الزوايا مية و
+
+90
+00:07:34,860 --> 00:07:37,820
+عشرين كجزء كل البنزين شو بيكون
+
+91
+00:07:43,700 --> 00:07:51,280
+البنزين Planar لأن كل الروابط اللي فيه sp2 Hybrid
+
+92
+00:07:51,280 --> 00:07:52,280
+Orbitals
+
+93
+00:08:00,190 --> 00:08:03,970
+الآن لو بتكونوا تتطلعوا على الـ Hydrogens اللي هم
+
+94
+00:08:03,970 --> 00:08:08,450
+بيكملوا البنزين .. صيغته العامة إيش البنزين؟ C6 ..
+
+95
+00:08:08,450 --> 00:08:13,610
+H6 .. الـ Hydrogens اللي بيكملوا هذا البنزين .. هل 
+
+96
+00:08:13,610 --> 00:08:17,390
+يا ترى بتفرق هذه عن هذه عن هذه عن هذه ولا متكافئات 
+
+97
+00:08:17,390 --> 00:08:21,510
+كلهم .. كلهم متكافئات .. بمعنى لو قلنا بدنا نعمل
+
+98
+00:08:21,510 --> 00:08:27,240
+تفاعل .. نشيل واحدة منهم ونحط مكانها Chlorine هل 
+
+99
+00:08:27,240 --> 00:08:31,240
+بتفرق هذه عن هذه عن هذه عن هذه عن هذه ولا كلهم زي 
+
+100
+00:08:31,240 --> 00:08:34,860
+بعض؟ كلهم زي بعض زي تماما لما كنتم تاخدوا جزء
+
+101
+00:08:34,860 --> 00:08:41,700
+الميثين مثلا CH4 هل كان بيفرق عندي إن أشيل أي
+
+102
+00:08:41,700 --> 00:08:47,580
+هيدروجينة عن الثانية؟ ما بيفرقش، واضح؟ فبناء على ذلك
+
+103
+00:08:47,580 --> 00:08:50,920
+لو أنا بدأت أشيل أي هيدروجينة أحط بدلها Substitute
+
+104
+00:08:50,920 --> 00:08:56,700
+All the Six Hydrogens are Equivalent are
+
+105
+00:08:56,700 --> 00:09:01,900
+Equivalent، متكافئات، أي واحدة الإنسان بيقدر إيش؟ 
+
+106
+00:09:01,900 --> 00:09:07,580
+أشيلها، كل الأماكن زي بعض، كل الأماكن زي بعض، زي
+
+107
+00:09:07,580 --> 00:09:11,680
+اللي بده يروح يحج، بده يقف على جبل عرفات، الرسول عليه
+
+108
+00:09:11,680 --> 00:09:22,010
+الصلاة والسلام إيش قال؟ وعرفته كلها موقف وانتبهوا 
+
+109
+00:09:22,010 --> 00:09:27,930
+معي لشغل كثير مهمة لو شيلت واحدة من هدول وحطيت 
+
+110
+00:09:27,930 --> 00:09:35,690
+مكانها نفترض ذرة كلور زي هيك صار الجزء اختلف أول
+
+111
+00:09:35,690 --> 00:09:40,170
+واحدة أشيل أي واحدة ما بيفرقش بعد هيك بدي أشيل واحدة
+
+112
+00:09:40,170 --> 00:09:46,900
+ثانية بيصير إذا شيلت من هان أو من هان أحط مركب معين
+
+113
+00:09:46,900 --> 00:09:51,540
+لو شيلت من هان حيصير مركب ثاني لو شيلت من هان
+
+114
+00:09:51,540 --> 00:09:55,140
+حيصير مركب ثاني بيصير عنده إيش جديد لما يكون عنده 
+
+115
+00:09:55,140 --> 00:10:01,560
+Two Substituents بس The First Substituent الست
+
+116
+00:10:01,560 --> 00:10:06,020
+أماكن متكافئة لكن بعد ما غيرت واحدة الآن بنقول
+
+117
+00:10:06,020 --> 00:10:09,980
+بدنا نشيل الثانية ونحط ذرة ثانية أكيد هدول اثنتين
+
+118
+00:10:10,890 --> 00:10:16,510
+زي بعض بالنسبة لهذه اللي لونها أسود وهدول الاثنتين 
+
+119
+00:10:16,510 --> 00:10:20,230
+زي بعض بالنسبة للي لونها أسود وهذه اللي جاية 
+
+120
+00:10:20,230 --> 00:10:26,090
+مقابل لها تمثل واحدة طبعا إذا كنت أنا شايل أي 
+
+121
+00:10:26,090 --> 00:10:29,330
+Carbon أو أجيت أحط على الموقع هذا يمين أو شمال
+
+122
+00:10:29,330 --> 00:10:34,810
+بقول هذا الموقع Ortho اللي هو الموقع المجاور ل
+
+123
+00:10:34,810 --> 00:10:38,310
+الموقع الأول اللي أنا حطيته اللي هو موقع Two Two 
+
+124
+00:10:38,310 --> 00:10:43,830
+عن اليمين أو Two عن الشمال لو أجيت على هذا الموقع
+
+125
+00:10:43,830 --> 00:10:47,570
+اللي هو موقع ثلاثة واحد اثنين ثلاثة أو واحد اثنين
+
+126
+00:10:47,570 --> 00:10:52,090
+ثلاثة بسمي Meta Position ولو أجيت على الموقع هذا
+
+127
+00:10:52,090 --> 00:10:55,350
+اللي جاي على أربعة واحد اثنين ثلاثة أربعة بسمي
+
+128
+00:10:55,350 --> 00:10:59,030
+الـ Para Position بيصير عندي لما بده أحط الـ Substituent 
+
+129
+00:10:59,030 --> 00:11:02,190
+و أنت الثاني يا بده أحط على هذا
+
+130
+00:11:06,350 --> 00:11:11,530
+هذا الكلام هناخذه أكثر بالتفصيل لما بدنا نشرح
+
+131
+00:11:11,530 --> 00:11:14,990
+تفاعلات
+
+132
+00:11:14,990 --> 00:11:20,410
+البنزين لحتى الآن واضح إنكم الـ Hybridization الـ 
+
+133
+00:11:20,410 --> 00:11:23,210
+Bond Angles الـ Bond Lengths البنزين
+
+134
+00:11:25,950 --> 00:11:31,250
+بداياتكم تتذكروا شغلة إنه العلم ما بيجيش ببلاش ..
+
+135
+00:11:31,250 --> 00:11:37,510
+العلم ما بيجيش ببلاش .. البنزين أول ما اكتشف ..
+
+136
+00:11:37,510 --> 00:11:42,430
+اكتشف سائل كان بيعمل فردق .. العالم فردق إذا
+
+137
+00:11:42,430 --> 00:11:47,250
+بتعرفوا تقطير لقطران الفحم الكول تار وما إلى ذلك 
+
+138
+00:11:47,250 --> 00:11:52,990
+فصل سائل هذا السائل لجأ أن الـ Boiling Point له 80
+
+139
+00:11:52,990 --> 00:12:01,170
+.81% الآن عمل الصيغة الـ Molecular Formula له لجأ
+
+140
+00:12:01,170 --> 00:12:04,910
+أو قبل ذلك عمل الـ Empirical Formula الـ Empirical 
+
+141
+00:12:04,910 --> 00:12:12,430
+Formula متذكرينها أصغر صيغة أصغر نسبة لجها CH الـ
+
+142
+00:12:12,430 --> 00:12:16,550
+CH هلومة C2H2 C3H3 C4H4
+
+143
+00:12:16,550 --> 00:12:21,330
+في تحاليل معينة عملوا الـ Molecular Formula اللي هي 
+
+144
+00:12:21,330 --> 00:12:26,530
+تمثل العدد الحقيقي مش النسبة مش أبسط نسبة الـ
+
+145
+00:12:26,530 --> 00:12:33,160
+Empirical Formula أبسط نسبة ممكن تكون مضروبة باثنين 
+
+146
+00:12:33,160 --> 00:12:34,900
+أو ثلاثة أو أربعة أو خمسة وأطفال 
+
+147
+00:12:46,610 --> 00:12:54,650
+C6H6 فثبت عنده الآن إن البنزين عبارة عن 6 ذرات
+
+148
+00:12:54,650 --> 00:12:59,470
+كربون و6 ذرات هيدروجين هذه اللي بنسميها احنا إيش
+
+149
+00:12:59,470 --> 00:13:04,410
+Molecular Formula دائما وأبدا السؤال الأصعب في 
+
+150
+00:13:04,410 --> 00:13:08,290
+الكيمياء إن 6 ذرات كربون و6 ذرات هيدروجين كيف 
+
+151
+00:13:08,290 --> 00:13:14,070
+بإمكاننا نحطهم يعملوا شكل فيه قلوم كثير Structural
+
+152
+00:13:14,070 --> 00:13:17,030
+Formulas .. الـ Structural Formula اللي هي بنسميها
+
+153
+00:13:17,030 --> 00:13:21,310
+الصيغة الإش .. الصيغة التفصيلية أو الصيغة البنائية
+
+154
+00:13:22,220 --> 00:13:27,600
+الصيغة البنائية صعبة جدا إيجادها وبحاجة إلى كثير 
+
+155
+00:13:27,600 --> 00:13:32,780
+من التجارب وإلى كثير من العلم الآن إذا تخيلتوا بس
+
+156
+00:13:32,780 --> 00:13:38,120
+أنه اكتشف البنزين كـ Molecular Formula في الـ 1824
+
+157
+00:13:38,120 --> 00:13:46,700
+عشان يقولوا بعد هيك إن الـ C6H6 موجودين بهذا الشكل 
+
+158
+00:13:46,700 --> 00:14:00,170
+كم لازمهم شغلوا بحثكم شهر؟ كم سنة؟ أربعين سنة من 
+
+159
+00:14:00,170 --> 00:14:03,570
+الألف وثمانمية تقريبا وخمسة وعشرين كان الاكتشاف
+
+160
+00:14:03,570 --> 00:14:08,690
+للألف وثمانمية وخمسة وستين بس عشان أقول ست ذرات
+
+161
+00:14:08,690 --> 00:14:14,720
+كربون وست هيدروجين كيف موجودين يصل لهذا الشكل تشوف
+
+162
+00:14:14,720 --> 00:14:20,120
+قد إيش العلم بياخد وجهته .. الآن طالما إن لزمني أربعين
+
+163
+00:14:20,120 --> 00:14:24,620
+سنة وأنا أعمل تجارب لحد ما أصل للشكل اللي ما زال
+
+164
+00:14:24,620 --> 00:14:29,120
+مقبول وبنقدر نعتبره صحيح في زماننا .. إذا بين بين 
+
+165
+00:14:29,120 --> 00:14:35,980
+المفروض نعمله كثير شغل غلط واضح؟ بيوم من الأيام
+
+166
+00:14:35,980 --> 00:14:39,300
+الشغل الغلط اللي عملوه كان موجود في الكتب وكان 
+
+167
+00:14:39,300 --> 00:14:44,760
+يتدرس وكانوا يحلفوا عليه يمين عشانك الناس ما تغترش
+
+168
+00:14:44,760 --> 00:14:49,740
+أول ما تجيها فكرة إنها الفكرة اللي هي جاياها أنهي 
+
+169
+00:14:49,740 --> 00:14:58,050
+الصح بعد عشر سنين ممكن تكتشف إن الفكرة خطأ، مظبوط
+
+170
+00:14:58,050 --> 00:15:01,890
+ولا لا؟ يعني مناسق مفاوضات Camp David اللي بدهم 
+
+171
+00:15:01,890 --> 00:15:05,670
+يحطوه الآن وزير خارجية في مصر، مبارح شو بيقول؟
+
+172
+00:15:05,670 --> 00:15:08,110
+والله أنا اكتشفت إن Camp David بالنسبة لنا
+
+173
+00:15:08,110 --> 00:15:11,910
+المصريين كويسة، لكن بالنسبة للفلسطينيين دمرت 
+
+174
+00:15:11,910 --> 00:15:17,630
+القضية الفلسطينية، الآن وقت إيش اكتشف الكلام؟ بعد
+
+175
+00:15:17,630 --> 00:15:21,530
+سنين بعد ما صارت إسرائيل تلعب فينا وما فيش أي حد 
+
+176
+00:
+
+201
+00:17:21,070 --> 00:17:25,930
+الآن أنتم إيش بتخلطوا؟ الكيمياء بالهندسة وقد
+
+202
+00:17:25,930 --> 00:17:30,310
+تستغربوا إنه كيكولي.. كيكولي هذا اللي حاطين صورته 
+
+203
+00:17:30,310 --> 00:17:36,490
+كان مهندس معماري بعد ما خلص الهندسة المعمارية
+
+204
+00:17:36,490 --> 00:17:40,430
+حول ودرس كيمياء زي ما اليوم كتير بيعملوا من
+
+205
+00:17:40,430 --> 00:17:44,150
+المهندسات المعماريات لما بيلاقوا الشغل كلهم بيجوا
+
+206
+00:17:44,150 --> 00:17:47,710
+بيندرسوا من أول وجديد كيمياء وفيزياء وتعليم أساسي
+
+207
+00:17:48,240 --> 00:17:53,740
+عدد كبير جدا واضح كيكولي لأنه أحب الكيمياء و
+
+208
+00:17:53,740 --> 00:17:58,200
+الكيمياء كلها structures وكلها هندسة بناء رباني كل
+
+209
+00:17:58,200 --> 00:18:01,280
+الأشكال اللي بتشوفوها أنتم لاحظوا هي عبارة عن
+
+210
+00:18:01,280 --> 00:18:05,720
+فعلا إيش؟ Geometry مش احنا بندرس Geometry أو هندسة
+
+211
+00:18:05,720 --> 00:18:10,800
+فكيكولي كان مهندس معماري حول إلى كيميائي وهو اللي
+
+212
+00:18:10,800 --> 00:18:18,290
+اقترح الشكل هذا تبع البنزين واضح؟ هو ليش اقترح شكل
+
+213
+00:18:18,290 --> 00:18:22,290
+البنزين؟
+
+214
+00:18:22,290 --> 00:18:27,570
+لأ لأ، وإيش بيعرفوا من التركيبة؟ احنا بنستنتج، احنا
+
+215
+00:18:27,570 --> 00:18:30,910
+لا شايفين ذرات ولا.. ولا ما يحزنون، هذه أشكال
+
+216
+00:18:30,910 --> 00:18:34,070
+استنتاجية على الأقل في المراحل الأولى، الآن بعد ال
+
+217
+00:18:34,070 --> 00:18:38,410
+X-ray صارت أشكال بإمكاننا نشوفها أو نقدرها..
+
+218
+00:18:38,410 --> 00:18:43,130
+نقدرها باستعمال أشعة X، فذاك الوقت كنا بنستنتج
+
+219
+00:18:43,130 --> 00:18:47,470
+الأشكال يعني الكيمياء مثلا ضلت مش قادرة تفهم شكل
+
+220
+00:18:47,470 --> 00:18:52,730
+الميثين اللي هو أبسط شكل للـ 1873 لبعد شكل البنزين
+
+221
+00:18:52,730 --> 00:18:56,950
+لما اكتشفوا شكل الميثين بعد ما اكتشفوا شكل الميثين
+
+222
+00:18:56,950 --> 00:18:59,550
+اللي حكينالكوا هي التتراهيدرال الكيمياء تطورت قبل
+
+223
+00:18:59,550 --> 00:19:04,030
+أيه ماكانوش قادرين يفهموها واضح؟ فالخلاصة بدأ شوية
+
+224
+00:19:04,030 --> 00:19:08,890
+عقول هندسية ربما مرة حكينالكوا في الالوتروبز على
+
+225
+00:19:08,890 --> 00:19:14,200
+الكربون وقلنالكوا في كرة الكربون 60 كيف لما يكون
+
+226
+00:19:14,200 --> 00:19:17,780
+عندي ستين ذرة كربون يكونوا في كرة بعد ما اكتشفوا
+
+227
+00:19:17,780 --> 00:19:21,920
+إن عندي جزء مكون من ستين ذرة كربون تغلبوا جدا في
+
+228
+00:19:21,920 --> 00:19:28,540
+موضوعه في النهاية اللي اتدخله حسب الشكل برضه مهندس
+
+229
+00:19:28,540 --> 00:19:31,700
+معماري book monster fuller فصاروا يسموا المركبات
+
+230
+00:19:31,700 --> 00:19:35,580
+fullerines fullerines واخدوا عليها جائزة نوبل مش
+
+231
+00:19:35,580 --> 00:19:41,600
+زمان في 1987 يعني سنة من ولادته جابل؟
+
+232
+00:19:41,600 --> 00:19:42,900
+ماشي
+
+233
+00:19:45,110 --> 00:19:50,970
+الآن قادرين تشوفوا إنه البنزين resonance structure
+
+234
+00:19:50,970 --> 00:19:54,250
+ولأنه resonance structures بشكل عام مرات بيحطوا
+
+235
+00:19:54,250 --> 00:19:59,450
+الحلقة واضحة the orbitals تبعت البنزين the orbitals
+
+236
+00:19:59,450 --> 00:20:04,250
+تبعت البنزين طبعا هاي بعض the orbitals أنا حاططلكوا
+
+237
+00:20:04,250 --> 00:20:10,050
+ياها هي عبارة عن pi orbitals عمودية على المستوى
+
+238
+00:20:10,050 --> 00:20:16,550
+الآن هذا بيعمل pi bond من الجهتين هذا بتعمل pi bond
+
+239
+00:20:16,550 --> 00:20:19,350
+من الجهتين والاخرانيات اللي هن بيعملوا pi bond من
+
+240
+00:20:19,350 --> 00:20:22,970
+الجهتين بناء على ذلك إيش بيصير فوق البنزين وتحت
+
+241
+00:20:22,970 --> 00:20:28,290
+البنزين electronic cloud حركة إلكترونية واضح و
+
+242
+00:20:28,290 --> 00:20:31,630
+لأنه كلها حركة إلكترونية يعني هل ال pi bond هل هي
+
+243
+00:20:31,630 --> 00:20:36,210
+هان ولا هان؟ مش عارف، في حركة إلكترونية ولذلك احنا
+
+244
+00:20:36,210 --> 00:20:40,630
+إيجي الاقتراح اللي عندنا إنه ال bond order واحد ونص
+
+245
+00:20:40,630 --> 00:20:46,330
+وإنه كل الروابط متساوين ومافيش عنده single و
+
+246
+00:20:46,330 --> 00:20:51,330
+double bonds لكن في عنده resonance structure زي ما
+
+247
+00:20:51,330 --> 00:20:55,830
+أنتم شايفين هنا إذا ال pi orbitals بشكل عام كيف
+
+248
+00:20:55,830 --> 00:21:02,170
+بيكونوا عموديات على مستوى الجزء وهم اللي بيعملوا
+
+249
+00:21:04,320 --> 00:21:08,380
+الـ double bonds هم اللي بيعملوا ال pi bonds على
+
+250
+00:21:08,380 --> 00:21:18,820
+أي الأشكال الآن نيجي لتسمية مركبات البنزين عبر
+
+251
+00:21:18,820 --> 00:21:22,800
+التاريخ البنزين كتير فيه مركبات منه من مشتقاته
+
+252
+00:21:22,800 --> 00:21:26,620
+إلى استعمالات وتطبيقات مهمة ولذلك في بعض
+
+253
+00:21:26,620 --> 00:21:32,320
+المركبات أخدت أسماء شهرة قبل ما نعمل نظام
+
+254
+00:21:32,320 --> 00:21:37,040
+systematic يعني نظام تحليلي من خلاله نقدر نسمي
+
+255
+00:21:37,040 --> 00:21:41,960
+المركبات هذه المركبات اللي أخدت أسماء شهرة
+
+256
+00:21:41,960 --> 00:21:46,680
+موجودة على اللوح أبسط مركبات زي ما أنتم شايفين أي
+
+257
+00:21:46,680 --> 00:21:51,740
+واحد فيهم البنزين البنزين بعد البنزين اللي عليه
+
+258
+00:21:51,740 --> 00:21:59,250
+مثل تولوين اللي عليه isopropyl الكيومين الكيومين
+
+259
+00:21:59,250 --> 00:22:04,410
+بيذكركوا بإيش؟ بالكمون هذا المكون الأساسي للكمون
+
+260
+00:22:04,410 --> 00:22:10,250
+الكيومين واضح؟ مكون الكمون اللي متصل فيه double 
+
+261
+00:22:10,250 --> 00:22:14,610
+bond أخذناه الاستايرين اللي بيعمل ال polymer اللي
+
+262
+00:22:14,610 --> 00:22:18,590
+اسمه ال polystyrene اللي بيعمل ال plastic ال
+
+263
+00:22:18,590 --> 00:22:23,850
+polystyrene اللي عليه OH الفينول أخذناه قولنا
+
+264
+00:22:23,850 --> 00:22:31,370
+بيفضل الشكل phenol في double bond جنبها OH واضح؟
+
+265
+00:22:31,370 --> 00:22:38,470
+اللي فيه O مثل بيسموه Anisole.. Anisole اللي فيه
+
+266
+00:22:38,470 --> 00:22:47,090
+مجموعة Aldehyde البنزالدهيد اللي في هذه المجموعة ال C
+
+267
+00:22:47,090 --> 00:22:51,950
+double bond OCH3 هذه المجموعة بالكيمياء بنسميها
+
+268
+00:22:51,950 --> 00:22:57,370
+acetyl احنا هذول مجمعين كمجموعات لوحدهم ال C
+
+269
+00:22:57,370 --> 00:23:04,710
+double bond OH كمجموعة لوحدها اسمها formyl المجموعة
+
+270
+00:23:04,710 --> 00:23:09,430
+إيش اسمها؟ Formyl group وهذه المجموعة C double
+
+271
+00:23:09,430 --> 00:23:18,390
+bond O CH3 اسمها؟ acetyl ومرات إيش بيختصروها؟ AC
+
+272
+00:23:18,390 --> 00:23:23,510
+فهذا المركب اللي في مجموعة ال formyl كله اسمه
+
+273
+00:23:25,040 --> 00:23:31,080
+بنزالدهيد اللي فيه مجموعة الأسيتيل أسيتوفينون..
+
+274
+00:23:31,080 --> 00:23:39,560
+أسيتوفينون اللي فيه حامض COOH.. COOH بنزوات 
+
+275
+00:23:39,910 --> 00:23:46,270
+اللي فيه nh2 أنيلين okay طيب السؤال يا ترى هدول
+
+276
+00:23:46,270 --> 00:23:51,870
+مطلوب مننا نحفظهم؟ أكيد هدول مركبات أساسية ما
+
+277
+00:23:51,870 --> 00:23:58,290
+بيستغنى عنهم اللي بدرسوا الكيمياء الآن بعد ذلك
+
+278
+00:23:58,290 --> 00:24:03,380
+بنستعمل طريقة الاشتقاق IUPAC method of nomenclature
+
+279
+00:24:03,380 --> 00:24:10,240
+اشتقاق مثلا لو عندي بروم بنسمي المركب برومو بنزين
+
+280
+00:24:10,240 --> 00:24:15,240
+لو عندنا نيترو بنزين نيترو بنزين لو عندها دي مثلا
+
+281
+00:24:15,240 --> 00:24:23,380
+CH2 CH3 إيثيل إيثيل بنزين لو عندنا بروبيل CH2 CH2 CH3
+
+282
+00:24:23,380 --> 00:24:27,120
+بروبيل بنزين لو عندنا tertiary butyl اللي عامله زي
+
+283
+00:24:27,120 --> 00:24:27,860
+الصليب
+
+284
+00:24:34,990 --> 00:24:40,530
+Tertiarybutylbenzene، واضح؟ فهمتوا عليّ، هذا الاسم
+
+285
+00:24:40,530 --> 00:24:44,790
+سبق، هذا اسم.. اسم شهرة، فكان المركب مفصول وما
+
+286
+00:24:44,790 --> 00:24:48,250
+أخذ اسم شهرة قبل ما نحطها الكلام، فما بيسموهش مثل
+
+287
+00:24:48,250 --> 00:24:51,590
+بنزين، يعني لو بدك تتطلع على كل كتب ال organic ال
+
+288
+00:24:51,590 --> 00:24:55,630
+chemistry بيقوله شلة تولوين، كمنطق أنت بدك تقول في
+
+289
+00:24:55,630 --> 00:25:00,060
+الآخر مثل بنزين، مظبوط ولا لا؟ صحيح وأنا كان
+
+290
+00:25:00,060 --> 00:25:04,640
+بإمكاني أقول amino benzene لكن أخذ اسم ال aniline
+
+291
+00:25:04,640 --> 00:25:10,020
+خلاص هذه أسماء common names وال common names سبقت
+
+292
+00:25:10,020 --> 00:25:17,200
+النظام اللي هو الاشتقاقي فبتضل.. بتضل عند الناس
+
+293
+00:25:17,200 --> 00:25:22,260
+أسماء إيش؟ ال common names يعني مثلا احنا في غزة
+
+294
+00:25:22,260 --> 00:25:27,490
+ممكن نقول بدنا نروح على السدرة كل الناس بتعرف
+
+295
+00:25:27,490 --> 00:25:33,030
+السدرة لأن عمرها صار كم مت ولا ألف سنة، الآن يا
+
+296
+00:25:33,030 --> 00:25:38,210
+تورا الشوارع اللي هناك مالهم مش اسم، إلهم اسم لو
+
+297
+00:25:38,210 --> 00:25:41,290
+بدكم تروحوا تشوفوا، طب مين بيعرفهم باسم الشوارع
+
+298
+00:25:41,290 --> 00:25:44,890
+بتاعتهم؟
+
+299
+00:25:44,890 --> 00:25:50,050
+إلهم أسماء لكن ماحد بيعرفهم باسمهم ال common name
+
+300
+00:25:50,050 --> 00:25:56,390
+سبق اللي هو الاسم الاشتقاقي واضح؟ الكم والنعم سبق
+
+301
+00:25:56,390 --> 00:25:59,630
+الاسم الاشتقاقي مثلا احنا عند كل البلد تقولوله
+
+302
+00:25:59,630 --> 00:26:04,050
+بدنا نركب ع شرع المشتل في النصر بركبكوا اجرؤش
+
+303
+00:26:04,050 --> 00:26:09,310
+مكتوب ع الشرع بيتلاقوهش مكتوب شرع المشتل واضح؟
+
+304
+00:26:09,310 --> 00:26:13,230
+فالكم والنعم لما يسبق خلاص بياخد أولوية بتصير
+
+305
+00:26:13,230 --> 00:26:19,290
+تتسمى فيه وإلا كان ممكن سؤالك انسهله أكتر هذا شو
+
+306
+00:26:19,290 --> 00:26:24,400
+أخذ اسم؟ بنزين.. طب سميه اشتقاقيا..
+
+307
+00:26:24,400 --> 00:26:29,580
+Cyclohexatriene
+
+308
+00:26:29,580 --> 00:26:34,920
+.. مش Cyclohexane
+
+309
+00:26:34,920 --> 00:26:40,000
+كيومين.. اتراين.. Cyclohexatriene.. عمركم
+
+310
+00:26:40,000 --> 00:26:45,040
+سمعتوا حد بيقول عنه.. Cyclohexatriene.. بنزين..
+
+311
+00:26:45,040 --> 00:26:49,240
+واضح؟ فالاسم الاشتقاقي سبق.. عفوا.. ال common
+
+312
+00:26:49,240 --> 00:26:55,470
+name سبق خلاص الآن لما بيصير في عندي.. لما بيصير في
+
+313
+00:26:55,470 --> 00:27:01,790
+عندي أكثر من substituent على الجزاء المفروض إن أنا
+
+314
+00:27:01,790 --> 00:27:09,110
+بصير بدي استعمل نظام ترقيم، نظام ترقيم عشان أسميهم
+
+315
+00:27:09,110 --> 00:27:13,750
+أو نظام حروف أحيانا اللي حكينالكوا ياه قبل شوية
+
+316
+00:27:13,750 --> 00:27:18,910
+قولنالكوا إن إذا اعتبرنا إنه أول موضع أساس أيا كان
+
+317
+00:27:18,910 --> 00:27:23,590
+اللي بيكون بالنسبة له على موضع اثنين وعلى موضع
+
+318
+00:27:23,590 --> 00:27:30,570
+ثلاثة وعلى موضع أربعة قارة بس رجاء في ناس يعني من
+
+319
+00:27:30,570 --> 00:27:34,470
+تجربتنا رغم إن الواحد بيحبش يقول هالكلام قدام
+
+320
+00:27:34,470 --> 00:27:40,730
+الكاميرا بس مش مشكلة من تجربتنا في ناس بتخيل إنه
+
+321
+00:27:40,730 --> 00:27:45,970
+أنا لازم أكون ماسك الجزء زي هيك وهذا ال ortho
+
+322
+00:27:45,970 --> 00:27:50,710
+position لفوق الأصل وال ortho موجود بهالشكل لأ
+
+323
+00:27:50,710 --> 00:27:54,470
+احنا ما بنقولش هذا الكلام احنا بنقول إنه إذا في
+
+324
+00:27:54,470 --> 00:28:01,940
+عندي substituent أولى اللي جنبها بتكون ortho واضح؟
+
+325
+00:28:01,940 --> 00:28:06,640
+الآن لو أنا مش ماسك الجزء بهذه الهيئة، ماسكه بهذه
+
+326
+00:28:06,640 --> 00:28:12,460
+الهيئة، هذا الموقع إيش يعتبر؟ برضه ortho بالنسبة
+
+327
+00:28:12,460 --> 00:28:16,500
+لهذه، إذا ال ortho هو موقع اثنين، طب لو ماسكه بهذه
+
+328
+00:28:16,500 --> 00:28:21,360
+الهيئة، يعني هذه.. هذه الصفراء برضه ortho.. لو
+
+329
+00:28:21,360 --> 00:28:24,260
+ماسكوا هيك.. برضه ortho.. لو ماسكوا هيك.. برضه
+
+330
+00:28:24,260 --> 00:28:28,540
+ortho.. فال ortho هو الموقع المجاور.. في ناس
+
+331
+00:28:28,540 --> 00:28:34,360
+خلاص مصرين إنه بدهم يتخيلوا إن هذا المكان هو ortho
+
+332
+00:28:34,360 --> 00:28:38,760
+.. بالتالي لو أنا مسكت الجزء زي هيك.. لو أنا مسكت
+
+333
+00:28:38,760 --> 00:28:41,620
+الجزء زي هيك وعندي substituent تحت.. محل ما أنا
+
+334
+00:28:41,620 --> 00:28:46,620
+ماسكه.. وقلتلكوا هذا الموقع.. إيش بيكون..
+
+335
+00:28:46,620 --> 00:28:52,620
+بيكون meta بالنسبة لي.. لأن واحد.. اثنين.. ثلاثة
+
+336
+00:28:52,620 --> 00:28:59,660
+واضح؟ فكلمة ortho وmeta وpara هي شغلة نسبية اللي
+
+337
+00:28:59,660 --> 00:29:03,640
+بيجي على موقع اثنين بسميه ortho واللي على موقع
+
+338
+00:29:03,640 --> 00:29:09,100
+ثلاثة meta اللي على موقع أربعة para واضح؟ الآن لو
+
+339
+00:29:09,100 --> 00:29:12,060
+الناس بدهم مش يكتبوا لا ortho ولا meta ولا para
+
+340
+00:29:12,060 --> 00:29:19,480
+بدهم يكتبوا اثنين بيروحوا حالهم واضح؟ بمعنى لو أنا
+
+341
+00:29:19,480 --> 00:29:25,080
+إجيت واطلعت على هذا المركب لاحظوا هذا المركب
+
+342
+00:29:25,080 --> 00:29:29,920
+إيش موجود فيه؟ ذرتين الكلور هدول ذرتين الكلور لما
+
+343
+00:29:29,920 --> 00:29:34,960
+بدي أقول المركب dichlorobenzene كيف جايين
+
+344
+00:29:34,960 --> 00:29:39,720
+بالنسبة لبعض؟ ortho إذا بقدر أنا أقول ortho
+
+345
+00:29:39,720 --> 00:29:45,060
+dichlorobenzene طب لو بدي أستعمل الأرقام بقدر أقول
+
+346
+00:29:45,060 --> 00:29:52,530
+1,2-Dichlorobenzene فال ortho على موقع 1 و2
+
+347
+00:29:52,530 --> 00:29:57,930
+وانتو dichlorobenzene واضح؟ الآن خلّيني أعطيكم
+
+348
+00:29:57,930 --> 00:30:06,130
+مثل تسميه بطريقتين لو كان عندكم هنا CH3 وهنا عندكم
+
+349
+00:30:06,130 --> 00:30:13,670
+Cl خلّيني نعتبر إنه الأساس في المركب التولوين الآن
+
+350
+00:30:13,670 --> 00:30:19,710
+التولوين على الموقعاتنين اتجاني إيش؟ كلورو شو بقدر
+
+351
+00:30:19,710 --> 00:30:26,590
+اسمي هذا؟ ortho كلورو
+
+352
+00:30:26,590 --> 00:30:27,710
+كلورو كلورو كلورو كلورو كلورو كلورو كلورو
+
+353
+00:30:27,710 --> 00:30:31,530
+كلورو كلورو كلورو كلورو كلورو كلورو كلورو
+
+354
+00:30:31,530 --> 00:30:32,650
+كلورو كلورو كلورو كلورو كلورو كلورو كلورو
+
+355
+00:30:32,650 --> 00:30:34,050
+كلورو كلورو كلورو كلورو كلورو كلورو كلورو
+
+356
+00:30:34,050 --> 00:30:34,810
+كلورو كلورو كلورو كلورو كلورو كلورو كلورو
+
+357
+00:30:34,810 --> 00:30:36,050
+كلورو كلورو كلورو كلورو كلورو كلورو كلورو
+
+358
+00:30:36,050 --> 00:30:43,970
+كلورو كلورو كلورو كلورو كلورو كلورو 
+
+359
+00:30:45,660 --> 00:30:50,620
+الآن لو حطيت أكثر من substituent بصير بستعمل بس
+
+360
+00:30:50,620 --> 00:30:55,340
+نظام الأرقام، يعني لو حطيت هنا Cl وحطيت هنا
+
+361
+00:30:55,340 --> 00:30:59,320
+Br و
+
+362
+00:30:59,320 --> 00:31:00,620
+بجانب بعض بالتلوين
+
+363
+00:31:03,520 --> 00:31:09,300
+2-كلور-4-بروموتولوين إذا
+
+364
+00:31:09,300 --> 00:31:15,320
+نقطة ابتداء في الترقيم عند الكربون اللي حاملة
+
+365
+00:31:15,320 --> 00:31:16,720
+الميثيل
+
+366
+00:31:26,710 --> 00:31:32,150
+كان ممكن نسمي المركب orthodimethylbenzene
+
+367
+00:31:32,150 --> 00:31:38,990
+لكن ال dimethylbenzene أخذ اسم شهرة xylene ال
+
+368
+00:31:38,990 --> 00:31:42,130
+dimethylbenzene أخذ اسم شهرة.. شو اسم الشهرة لل
+
+369
+00:31:42,130 --> 00:31:46,350
+dimethylbenzene؟ xylene الآن لو التنتين مثل جنب
+
+370
+00:31:46,350 --> 00:31:51,640
+بعض، شو بنسميه؟ ortho xylene لو إنهم على موقع
+
+371
+00:31:51,640 --> 00:31:57,000
+واحد لثلاثة لبعض meta xylene لو على موقع واحد
+
+372
+00:31:57,000 --> 00:32:02,580
+لاربع على بعض para xylene إذا ال xylene في عند
+
+373
+00:32:02,580 --> 00:32:09,640
+منه ortho يعني مجمعتين مثل جنب بعض meta على موقع
+
+374
+00:32:09,640 --> 00
+
+401
+00:34:18,920 --> 00:34:25,840
+bond CH أخذت لها اسم في
+
+402
+00:34:25,840 --> 00:34:34,600
+واحدة حكت شوية غلط إيش اسمها دي اللي حكت؟ Vinyl
+
+403
+00:34:34,600 --> 00:34:39,860
+سمعيني .. سمعيني .. بس نسألك شوية .. إيش اسمها؟
+
+404
+00:34:39,860 --> 00:34:49,380
+Vinyl فنيل مش فنل الآن الفنل هي حلقة البنزين الفنل
+
+405
+00:34:49,380 --> 00:34:52,880
+فنيل
+
+406
+00:34:52,880 --> 00:35:10,240
+فنيل فنيل فنيل فنيل فنيل فنيل فنيل فنيل فنيل فنيل
+
+407
+00:35:11,580 --> 00:35:16,520
+هي حلقة البنزين لأ حلقة البنزين نفسها اسمها phenyl
+
+408
+00:35:16,520 --> 00:35:20,960
+واضح؟
+
+409
+00:35:20,960 --> 00:35:24,580
+حلقة البنزين نفسها اسمها H-Phenyl يعني لو اجت على
+
+410
+00:35:24,580 --> 00:35:28,720
+مركب مثلا معين و كانت هي تعتبر substituent أو
+
+411
+00:35:28,720 --> 00:35:33,060
+group بنسميها H-Phenyl فالخلاصة أنه مثل هذه الحالة
+
+412
+00:35:33,060 --> 00:35:36,740
+من الحالات اللي بتحير هل يا ترى المركب اللي عندي
+
+413
+00:35:36,740 --> 00:35:37,940
+بدي أنسبه
+
+414
+00:35:44,770 --> 00:35:49,770
+الحقيقة في عندنا قواعد بتقدروا تعملوها أو تعتبروها
+
+415
+00:35:49,770 --> 00:35:55,190
+كقواعد عامة بتعطي أولويات .. بتعطي أولويات الآن
+
+416
+00:35:55,190 --> 00:36:00,230
+الأولويات بتقول أعلى أولوية بأبدأ الترقيم من عنده
+
+417
+00:36:00,230 --> 00:36:06,050
+و باعتبرها الأساسي ال-Ester أقل منها ال-acid أقل
+
+418
+00:36:06,050 --> 00:36:10,110
+منها ال-aldehyde بمعنى لو عندي acid و عندي
+
+419
+00:36:10,110 --> 00:36:14,810
+aldehyde بيه نمر واحد ال-acid الأقل منه ال-ketone
+
+420
+00:36:14,810 --> 00:36:21,890
+لو عندي aldehyde و ketone مين اللي له أولوية ال
+
+421
+00:36:21,890 --> 00:36:27,650
+aldehyde واضح؟ الآن أطلع هذا الشكل هذا الشكل كثير
+
+422
+00:36:27,650 --> 00:36:34,530
+حلو في ال-aldehyde والـketone و المركب كله مع الديهيد
+
+423
+00:36:34,530 --> 00:36:40,550
+شو اسمه؟ أخذنا Benzaldehyde و المركب تحت مع
+
+424
+00:36:40,550 --> 00:36:44,590
+الـketone أسيتوفينون
+
+425
+00:36:45,460 --> 00:36:49,300
+قبل شوية أخذناه بالاسم أشور هل يا ترى بدي أنسب
+
+426
+00:36:49,300 --> 00:36:53,620
+المركب للـ الديهايد ولا للـ ketone؟ للـ الديهايد، إذا
+
+427
+00:36:53,620 --> 00:36:57,660
+بدي أقول هذه الأساس اللي عندي، هذا بنزالديهيد، من
+
+428
+00:36:57,660 --> 00:37:01,500
+وين نمر واحد افترق قيمة؟ من عند الـ الديهايد، one,
+
+429
+00:37:01,700 --> 00:37:08,280
+two, three, four، الآن هذه كمجموعة إيش اسمها؟ C
+
+430
+00:37:08,280 --> 00:37:16,420
+double bond O C H3 بتصير مجموعة أسيتيل واضح؟ فبصير 4
+
+431
+00:37:16,420 --> 00:37:22,720
+-acetyl أو paraacetyl benzaldehyde شوفتوا كيف؟
+
+432
+00:37:22,720 --> 00:37:26,240
+يعني لما التقى ال-aldehyde و ال-ketone الأولوية
+
+433
+00:37:26,240 --> 00:37:31,240
+لمين؟ للـ aldehyde لو التقى ال-ketone و ال-alcohol
+
+434
+00:37:31,240 --> 00:37:35,420
+الأولوية لمين؟ ال-ketone طبعا أكيد لو التقى ال
+
+435
+00:37:35,420 --> 00:37:40,900
+aldehyde و ال-alcohol الأولوية لمين؟ لل-aldehyde
+
+436
+00:37:40,900 --> 00:37:43,040
+لاحظوا مثلا هذا المثال
+
+437
+00:37:46,390 --> 00:37:53,630
+مع الالديهايد اسمه
+
+438
+00:37:53,630 --> 00:37:55,330
+benzaldehyde
+
+439
+00:37:58,060 --> 00:38:03,220
+فينول أنا لإيش بدي أسميه؟ للـ aldehyde إذا أنا كأنه
+
+440
+00:38:03,220 --> 00:38:07,160
+هي الأساس اللي عندي هذا بنزالديهايد وهي موقع واحد
+
+441
+00:38:07,160 --> 00:38:11,520
+اثنين ثلاثة أربعة هذا بنزالديهايد على موقع أربعة
+
+442
+00:38:11,520 --> 00:38:16,200
+إيش حامل؟ مجموعة الـ OH مجموعة الـ OH إذا ماكانش
+
+443
+00:38:16,200 --> 00:38:19,560
+منسوب إلى المركب شو تسمى؟ هيدروكسي
+
+444
+00:38:21,480 --> 00:38:28,640
+بارا هيدروكسي واضح بارا هيدروكسي واضح إذا كيف اللي
+
+445
+00:38:28,640 --> 00:38:35,750
+هو نظام التسمية الـ alcohol أكثر منالأمين اللي هو
+
+446
+00:38:35,750 --> 00:38:40,590
+الـ NH2، الأمين أكثر من الألكين اللي فيه double
+
+447
+00:38:40,590 --> 00:38:46,310
+bond، الألكين أكثر من الألكيل، والألكين أكثر من ال
+
+448
+00:38:46,310 --> 00:38:51,230
+halogen، في هيك الأمور، و الـ halogens زيها كمان
+
+449
+00:38:51,230 --> 00:38:56,030
+بتيجي الـ nitrate يعني منخفضة في الأولوية بناء على
+
+450
+00:38:56,030 --> 00:38:59,810
+ذلك لو بدنا نيجي نشوف كل هدولة طبعا هدولة لما
+
+451
+00:38:59,810 --> 00:39:03,350
+كانوا اثنتين halogens بيخلوهم alphabetical اللي
+
+452
+00:39:03,350 --> 00:39:06,430
+بتكون alphabetical في الأول بيحطوه بالنسبة للثانية
+
+453
+00:39:06,430 --> 00:39:12,190
+okay الآن هنا لما عندكم الـ kno نيترو وين نمر واحد
+
+454
+00:39:12,190 --> 00:39:15,290
+الـ kno الـ kno الـ kno الـ kno الـ kno الـ kno الـ kno الـ kno
+
+455
+00:39:15,290 --> 00:39:16,890
+الـ kno الـ kno الـ kno الـ kno الـ kno الـ kno الـ kno الـ kno
+
+456
+00:39:16,890 --> 00:39:25,090
+الـ kno الـ kno طلوين إذاً هذه صارت ميتا نيترو
+
+457
+00:39:25,090 --> 00:39:35,010
+طلوين واضح هنا عندكم ألكين و ألكين لمن
+
+458
+00:39:35,010 --> 00:39:40,510
+الأولوية الألكين مركب الألكين شو اسمه استيرين هاي
+
+459
+00:39:40,510 --> 00:39:44,390
+واحد اثنين ثلاثة بناخد أقل ترقيم ممكنش واحدة تيجي
+
+460
+00:39:44,390 --> 00:39:49,110
+ترقم واحد اثنين ثلاثة أربعة خمسة تروح تكتب five
+
+461
+00:39:49,110 --> 00:39:55,500
+مثل لحظة وقت رجعت إن اسمها مجموعة three مثل أو ميتا
+
+462
+00:39:55,500 --> 00:40:01,320
+مثل واضح هنا التقى عندكم الـ halogen مع الـ OH هي الـ
+
+463
+00:40:01,320 --> 00:40:07,110
+OH هي الـ halogen من الأولوية مركب الـ watch إيش
+
+464
+00:40:07,110 --> 00:40:13,670
+اسمه؟ فينول إذا بارا كلورو فينول بارا كلورو فينول
+
+465
+00:40:13,670 --> 00:40:18,590
+هذا المركب التقى فيه المثل مع ثلاث مجموعات نايترو
+
+466
+00:40:18,590 --> 00:40:23,210
+مين أعلى؟ الألكين ولا النايترو؟ الألكين مركب
+
+467
+00:40:23,210 --> 00:40:26,150
+الألكين لحاله طلوين
+
+468
+00:40:28,350 --> 00:40:35,850
+4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3
+
+469
+00:40:35,850 --> 00:40:41,610
+-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4
+
+470
+00:40:41,610 --> 00:40:45,290
+-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3
+
+471
+00:40:45,290 --> 00:40:52,790
+-6-3-4-6-3-4-6-3-4-6
+
+472
+00:40:52,790 --> 00:40:55,270
+-3-4-
+
+473
+00:40:57,880 --> 00:41:03,680
+هي الـ ketone و الحامض و الـ acid ممتاز مين اللي
+
+474
+00:41:03,680 --> 00:41:07,900
+أولوية الـ acid و لا الـ ketone الـ acid إذا ترقيم
+
+475
+00:41:07,900 --> 00:41:12,900
+أنا عند الـ acid واحد اثنين ثلاثة أربعة مركب ال
+
+476
+00:41:12,900 --> 00:41:19,420
+acid إيش اسمه بنزويك acid إيش بيحمل بنزويك acid
+
+477
+00:41:19,420 --> 00:41:24,460
+على موقع أربعة C double bond OCH3 هذه المجموعة
+
+478
+00:41:24,460 --> 00:41:33,860
+ما اسمها Acetyl Okay طيب هذا المثال مين تحكيلنا عنه
+
+479
+00:41:33,860 --> 00:41:43,460
+فضلوا إيش انتقام فيه OH OH نيترو مين الأولوية هذا
+
+480
+00:41:43,460 --> 00:41:52,690
+ايه فنول فنول إيش بيحمل؟ على اثنين وأربعة وستة تراي
+
+481
+00:41:52,690 --> 00:41:57,650
+نايترو فنول هذا المركب مشهور في الـ biology الـ 246
+
+482
+00:41:57,650 --> 00:42:03,650
+تراي نايترو فنول اللي اسم شهرة بيسموه بكريك أسيد
+
+483
+00:42:03,650 --> 00:42:06,830
+حامض لونه أصفر غامق اللي بيشتغل فيكوا القواعد و
+
+484
+00:42:06,830 --> 00:42:13,210
+إيديه بيصيروا أصفر غامق جدا واضح؟ أصفر غامق جدا
+
+485
+00:42:13,210 --> 00:42:14,810
+طيب آخر شيء
+
+486
+00:42:25,730 --> 00:42:29,570
+آخر شيء بنعطيكوا يا بس بنأكدلكوا إن الـ aromatic
+
+487
+00:42:29,570 --> 00:42:33,950
+compounds اللي هم تطبيقات كثيرة في الدنيا .. اللي
+
+488
+00:42:33,950 --> 00:42:39,870
+هم تطبيقات كثيرة في الدنيا مثلا هذا المركب
+
+489
+00:42:39,870 --> 00:42:43,910
+aromatic بنزين acetosilic acid هذا هو الدواء
+
+490
+00:42:43,910 --> 00:42:50,200
+المشهورة اسمه اسبيرين هذا الاسبيرين هو عبارة عن
+
+491
+00:42:50,200 --> 00:42:57,260
+حلقة بنزين هذا المركب الديهايد معه مثل مع OH هذا
+
+492
+00:42:57,260 --> 00:43:04,520
+المركب اللي هو الفانيلا الفانيلا تبعت الكيك هذا
+
+493
+00:43:04,520 --> 00:43:09,260
+المركب برضه في حلقة بنزين مع CH2 و بعدين ايزو
+
+494
+00:43:09,260 --> 00:43:15,060
+بروفين ايزو بيوتيل جروب و CH3 و COH هذا
+
+495
+00:43:15,060 --> 00:43:21,580
+الايبوبروفين مار عليكم ال ibuprofen اللي ضد الصداع
+
+496
+00:43:21,580 --> 00:43:26,540
+اللي بيجيب أجل الصداع الـ 600 الـ algonol 600 اللي
+
+497
+00:43:26,540 --> 00:43:32,300
+بيكون هيك راسهم بده ينفجر واضح فاللي ماعندوش بس
+
+498
+00:43:32,300 --> 00:43:35,540
+بدخل على الكتاب بياخد ibuprofen أسبيرين إيش ما
+
+499
+00:43:35,540 --> 00:43:40,820
+بلزمكم خدوا منهم فهذه مركبات لها أهمية في التطبيق
+
+500
+00:43:40,820 --> 00:43:42,900
+المرة اللي جاي إن شاء الله بنحكي عن التفاعلات
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..55cf9ff63077f2ba6fdce291a58cb0a37942e3e1
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo_raw.srt
@@ -0,0 +1,2008 @@
+1
+00:00:06,440 --> 00:00:12,000
+اليوم ان شاء الله هنبدأ chapter جديد اللي هو ال
+
+2
+00:00:12,000 --> 00:00:16,080
+aromatic compounds الفصل الرابع ال aromatic
+
+3
+00:00:16,080 --> 00:00:23,980
+compounds chapter بسيط و مسهل و ممتعطبعا حتى نعرف
+
+4
+00:00:23,980 --> 00:00:28,340
+إيش موقعهم من الإعراب ال aromatic compounds حتى
+
+5
+00:00:28,340 --> 00:00:34,640
+نعرف إيش موقعهم من الإعراب بنذكر التقسيم العام لل
+
+6
+00:00:34,640 --> 00:00:38,360
+hydrocarbons لحظة ما قلنا إن في عندنا saturated
+
+7
+00:00:38,360 --> 00:00:43,420
+hydrocarbons وفي عندناunsaturated hydrocarbons الـ
+
+8
+00:00:43,420 --> 00:00:47,520
+unsaturated اللي كان فيهم double bonds فمن ال
+
+9
+00:00:47,520 --> 00:00:51,260
+unsaturated ال alkenes كانت عندى ب one double bond
+
+10
+00:00:51,260 --> 00:00:54,920
+و ال alkynes ب two double bonds يعني بال triple
+
+11
+00:00:54,920 --> 00:00:58,780
+bond و كان عندنا الجزء الأخر اللى هو موضوع درسنا
+
+12
+00:00:58,780 --> 00:01:02,660
+اليوم ال aromatic compounds اللى هي المركبات
+
+13
+00:01:02,660 --> 00:01:09,940
+الحلقية اللى فيهاأكثر من رابطة زوجية وبدول الروابط
+
+14
+00:01:09,940 --> 00:01:13,240
+الزوجية بنقول عنهم بيكونوا conjugated يعني بيكونوا
+
+15
+00:01:13,240 --> 00:01:17,840
+على شكل double single double single و لازم كل ال
+
+16
+00:01:17,840 --> 00:01:22,600
+aromatic compounds يكونوا في إيش؟ في حلقة لازم
+
+17
+00:01:22,600 --> 00:01:26,080
+عشان نحكي عن aromatic compounds نحكي عن حلقة يعني
+
+18
+00:01:26,080 --> 00:01:30,180
+لو بدنا نجيبلكم مركب مش حلقة ماحدش عمره يفكر أنه
+
+19
+00:01:30,180 --> 00:01:33,880
+يصنفوا تحت aromatic compounds واضح؟
+
+20
+00:01:36,110 --> 00:01:41,090
+الان اذا برضه بدنا نرجع ل slide نتذكر بعض
+
+21
+00:01:41,090 --> 00:01:44,830
+المعلومات بخصوص ال double bond و ال single bond و
+
+22
+00:01:44,830 --> 00:01:48,730
+ال triple bond اخدنا احنا ال bond length و اخدنا
+
+23
+00:01:48,730 --> 00:01:53,980
+ال bond anglesو ال rotation و ال geometry و ال
+
+24
+00:01:53,980 --> 00:01:58,000
+hybridization يمكن اكتر اشي بيهمنا نركز عليه ال
+
+25
+00:01:58,000 --> 00:02:03,640
+double bond ليش double bond؟ لأنه البنزين موجود
+
+26
+00:02:03,640 --> 00:02:08,600
+فيه double bonds البنزين كحلقة سداسية موجود فيه
+
+27
+00:02:08,600 --> 00:02:13,240
+double bonds واضح؟ يعني لو بدى اشوف انا model
+
+28
+00:02:13,240 --> 00:02:19,360
+للبنزين هي حلقة البنزين بهذا الشكلهذا الشكل في
+
+29
+00:02:19,360 --> 00:02:22,840
+حلقة البنزين زي ما انتوا شايفين فبتلاحظوا ايش اللي
+
+30
+00:02:22,840 --> 00:02:27,420
+موجود عندى double single double single double
+
+31
+00:02:27,420 --> 00:02:29,640
+single هذا اللي هي عملية اللي بنسميها ال
+
+32
+00:02:29,640 --> 00:02:34,260
+conjugation ان ال double bonds are conjugated واضح
+
+33
+00:02:34,260 --> 00:02:40,060
+الان كل carbonكل carbon من ال carbons الستة لو
+
+34
+00:02:40,060 --> 00:02:44,880
+اجيت اطلع عليها حقيقة بلاقينها على طرف double bond
+
+35
+00:02:44,880 --> 00:02:48,620
+يعني هي هذه طرف double bond هذه .. هذه .. هذه ..
+
+36
+00:02:48,620 --> 00:02:52,900
+هذه و بناء على ذلك لو اجينا بدنا نتساءل ايش ال
+
+37
+00:02:52,900 --> 00:02:59,800
+hybridization لكل carbon هلاحظ انه طالع منها اتجاه
+
+38
+00:02:59,800 --> 00:03:02,760
+اتجاهين تلاتة
+
+39
+00:03:06,160 --> 00:03:15,260
+الزاوية 120 المجموع 360 اذا ال carbons اللي
+
+40
+00:03:15,260 --> 00:03:22,720
+موجودين في البنزين جميعهم sb2 hybrid carbons all
+
+41
+00:03:22,720 --> 00:03:28,300
+the carbons in benzene are sb2 hybrid carbons واضح
+
+42
+00:03:28,300 --> 00:03:37,290
+ال bond angle 120الـ bond angle 120 الآن بيجينا
+
+43
+00:03:37,290 --> 00:03:42,910
+شغلة كتير مهمة اللي هي ال bond order و ال bond
+
+44
+00:03:42,910 --> 00:03:50,690
+length ال bond order بنقصد فيه كام عدد الروابط بين
+
+45
+00:03:50,690 --> 00:03:56,900
+ذرتين الكربونكم عدد الروابط من ذرات الكربون الان
+
+46
+00:03:56,900 --> 00:04:01,940
+اذا كنت تتطلع على شكل وحيد من هدولة هتقول والله
+
+47
+00:04:01,940 --> 00:04:06,720
+الروابط في عنده double و single و double و single
+
+48
+00:04:06,720 --> 00:04:10,580
+و double و single هذا الكلام لو انه زي هيك و الشكل
+
+49
+00:04:10,580 --> 00:04:14,720
+ثابت ال single bond أطول من ال double bond اتطلع
+
+50
+00:04:14,720 --> 00:04:21,240
+طول ال single bond بشكل عادل 154 double bond 134
+
+51
+00:04:21,540 --> 00:04:24,820
+فلو هذا الكلام .. لو شكل البنزين زي هيك .. انه فيه
+
+52
+00:04:24,820 --> 00:04:29,040
+double bond و single bond .. كان هذه بده تكون 134
+
+53
+00:04:29,040 --> 00:04:34,140
+و التانية بده تكون 154 .. اذا هل هيكون الطول تبع
+
+54
+00:04:34,140 --> 00:04:40,280
+هدوله متساوي؟ .. هيصير شكل البنزين كيف؟ غير منتظم
+
+55
+00:04:40,280 --> 00:04:47,840
+.. بمعنى مش الست روابط جات بعضالان بالتجربة لاحظوا
+
+56
+00:04:47,840 --> 00:04:52,100
+ان البنزين الست روابط اللى موجودة فيه نفس الطول
+
+57
+00:04:52,100 --> 00:04:59,560
+واضح؟ الست روابط نفس الطول طيب ماشي نفس الطول هل
+
+58
+00:04:59,560 --> 00:05:05,380
+هما يا ترى طولهم من طول ال double bond اللى قصيرة
+
+59
+00:05:05,380 --> 00:05:09,680
+ولا من طول ال single bond اللى طويلة اللى لاحظوا
+
+60
+00:05:09,680 --> 00:05:15,560
+ان طولهم شئ ما betweenthe double bond lengths and
+
+61
+00:05:15,560 --> 00:05:18,960
+the single bond lengths يعني طولهم جاي بين بين
+
+62
+00:05:18,960 --> 00:05:25,140
+واضح طول الرابطة لا هو double bond اكسير ولا هو
+
+63
+00:05:25,140 --> 00:05:30,380
+single bond طويل الآن السؤال كأنه إذا مش double
+
+64
+00:05:30,380 --> 00:05:33,560
+bond إذا مش اتنين أو مش واحد إيش بدي يطلع أنا بدي
+
+65
+00:05:33,560 --> 00:05:38,480
+أطلع واحد و نص اللي هو عدد الروابط بالظبط بطلع
+
+66
+00:05:38,480 --> 00:05:43,890
+واحد و نصفال bond order .. ال bond order في
+
+67
+00:05:43,890 --> 00:05:49,610
+البنزين لو هو واحدولا هو اتنين واحد و نص انتوا لو
+
+68
+00:05:49,610 --> 00:05:52,870
+كنتوا بتشوفوا كيف هذا الكلام بيصير بيصير بسبب ال
+
+69
+00:05:52,870 --> 00:05:57,030
+resonance انه هذه في لحظة من اللحظات double bond
+
+70
+00:05:57,030 --> 00:06:00,210
+وهذه single bond نتيجة ال resonance هذه بتصير
+
+71
+00:06:00,210 --> 00:06:04,150
+double bond وهذه single bond يعني كأنه هالمكانين
+
+72
+00:06:04,150 --> 00:06:07,090
+هدول لو اجيتوا اطلعتوا كام bond اللي موجود فيهم؟
+
+73
+00:06:07,090 --> 00:06:15,470
+واحد اتنين تلاتة لما يصير في resonance1.5 إذا كل
+
+74
+00:06:15,470 --> 00:06:22,730
+رابطة في البنزين 1.5 bond order يعني عندي رابطة و
+
+75
+00:06:22,730 --> 00:06:26,270
+نص bond
+
+76
+00:06:26,270 --> 00:06:33,180
+order in بنزين is 1.5بسبب ال resonance انه في عندى
+
+77
+00:06:33,180 --> 00:06:38,020
+حركة في ال bonds double single double single مرة
+
+78
+00:06:38,020 --> 00:06:40,860
+هدى double هدى single مرة هدى double هدى single
+
+79
+00:06:40,860 --> 00:06:45,200
+المتوسط تبعهم اش بده يطلع بده يطلع عندنا المتوسط
+
+80
+00:06:45,200 --> 00:06:49,260
+تبعهم واحد و نصف و عشان هيك ال bond length للرابطة
+
+81
+00:06:49,260 --> 00:06:52,580
+في البنزين بيكون بين الرابطة القصيرة اللى هى ال
+
+82
+00:06:52,580 --> 00:06:58,490
+double bondالـ 134 و بين الكبيرة 154 بالتجربة نسو
+
+83
+00:06:58,490 --> 00:07:06,730
+139 جاي قيمة بين القيمتين واضح فال bond length هيك
+
+84
+00:07:06,730 --> 00:07:14,100
+بيصير عندى واضح ان هوبين بين و ال bond order واحد
+
+85
+00:07:14,100 --> 00:07:17,280
+و نص بالظبط واحد و نص يعني لما نسألكوا the bond
+
+86
+00:07:17,280 --> 00:07:22,480
+order in بنزين is two and one لأ لو two and one
+
+87
+00:07:22,480 --> 00:07:26,260
+كان بيكون رابطة صيرة و رابطة طويلة و شكل البنزين
+
+88
+00:07:26,260 --> 00:07:30,720
+غير منتظم لكن الحقيقة البنزين شكله منتظم الآن
+
+89
+00:07:30,720 --> 00:07:34,860
+معلومة إضافية عن البنزين لأن كل هدول الزوايا مية و
+
+90
+00:07:34,860 --> 00:07:37,820
+عشرين كجزء كل البنزين شو بيكون
+
+91
+00:07:43,700 --> 00:07:51,280
+البنزين بلانر لأن كل الروابط اللي فيه SB2 hybrid
+
+92
+00:07:51,280 --> 00:07:52,280
+orbitals
+
+93
+00:08:00,190 --> 00:08:03,970
+الآن لو بتكن تتطلعوا على ال hydrogens اللي هم
+
+94
+00:08:03,970 --> 00:08:08,450
+بيكملوا البنزين .. صيغته العامة إيش البنزين؟ C6 ..
+
+95
+00:08:08,450 --> 00:08:13,610
+H6 .. ال hydrogens اللي بيكملوا هذا البنزين .. هل
+
+96
+00:08:13,610 --> 00:08:17,390
+يا ترى بتفرج هدي عن هدي عن هدي عن هدي ولا متكافئات
+
+97
+00:08:17,390 --> 00:08:21,510
+كلهم .. كلهم متكافئات .. بمعنى لو قولنا بدنا نعمل
+
+98
+00:08:21,510 --> 00:08:27,240
+تفاعل .. انشيل واحدة منهم و نحط مكانها chlorineهل
+
+99
+00:08:27,240 --> 00:08:31,240
+بتفرق هذه عن هذه عن هذه عن هذه عن هذه ولا كلهم زي
+
+100
+00:08:31,240 --> 00:08:34,860
+بعض؟ كلهم زي بعض زي تماما لما كنتوا تاخدوا جزء
+
+101
+00:08:34,860 --> 00:08:41,700
+الميثين مثلا CH4 هل كان بيفرق عندى ان اشيل اي
+
+102
+00:08:41,700 --> 00:08:47,580
+هيدروجينة عن التانية؟ مابفرقش، واضح؟ فبناء على ذلك
+
+103
+00:08:47,580 --> 00:08:50,920
+لو انا بدأ اشيل اي هيدروجينة احط بدلها substitute
+
+104
+00:08:50,920 --> 00:08:56,700
+all the six hydrogens are equivalentare
+
+105
+00:08:56,700 --> 00:09:01,900
+equivalent، متكافئات، أي واحدة الإنسان بيقدر إيش؟
+
+106
+00:09:01,900 --> 00:09:07,580
+اشيلها، كل الأماكن زي بعض، كل الأماكن زي بعض، زي
+
+107
+00:09:07,580 --> 00:09:11,680
+اللي بدو يروح يحج، بدو يقف ع جبل عرفة، الرسول عليه
+
+108
+00:09:11,680 --> 00:09:22,010
+الصلاة والسلام إيش قال؟وعرفته كلها موقف وانتبهوا
+
+109
+00:09:22,010 --> 00:09:27,930
+معي لشغل كتير مهمة لو شيلت واحدة من هدولة وحطيت
+
+110
+00:09:27,930 --> 00:09:35,690
+مكانها نفترض ذرة كلور زي هيك صار الجزء اختلف اول
+
+111
+00:09:35,690 --> 00:09:40,170
+واحدة اشيل اي واحدة مفرجش بعد هيك بدي اشيل واحدة
+
+112
+00:09:40,170 --> 00:09:46,900
+تانيةبصير إذا شيلت من هان أو من هان بحط مركب معين
+
+113
+00:09:46,900 --> 00:09:51,540
+لو شيلت من هان حيصير مركب تاني لو شيلت من هان
+
+114
+00:09:51,540 --> 00:09:55,140
+حيصير مركب تاني بصير عنده إش جديد لما يكون عنده
+
+115
+00:09:55,140 --> 00:10:01,560
+two substituents بس the first substituent الست
+
+116
+00:10:01,560 --> 00:10:06,020
+أماكن متكافئة لكن بعد ما غيرت واحدة الآن بنقول
+
+117
+00:10:06,020 --> 00:10:09,980
+بدنا نشيل التانية و نحط ذرة تانية أكيد هدولة تنتين
+
+118
+00:10:10,890 --> 00:10:16,510
+زي بعض بالنسبة لهذه اللي لونها أسود و هدول التنتين
+
+119
+00:10:16,510 --> 00:10:20,230
+زي بعض بالنسبة اللي لونها أسود و هذه اللي جاية
+
+120
+00:10:20,230 --> 00:10:26,090
+مقابل إلها تمثل واحدة طبعا إذا كنت أنا شايل أي
+
+121
+00:10:26,090 --> 00:10:29,330
+carbon أو إجيت أحط على الموقع هذا يمين أو شمال
+
+122
+00:10:29,330 --> 00:10:34,810
+بقول هذا الموقع ortho اللي هو الموقع المجاورلأ
+
+123
+00:10:34,810 --> 00:10:38,310
+الموقع الأول اللي انا حطيته اللي هو موقع two two
+
+124
+00:10:38,310 --> 00:10:43,830
+عن اليمين او two عن الجمال لو اجيت على هذا الموقع
+
+125
+00:10:43,830 --> 00:10:47,570
+اللي هو موقع تلاتة واحد اتنين تلاتة او واحد اتنين
+
+126
+00:10:47,570 --> 00:10:52,090
+تلاتة بسمي ميتا position و لو اجيت على الموقع هذا
+
+127
+00:10:52,090 --> 00:10:55,350
+اللي جاي على اربعة واحد اتنين تلاتة اربعة بسمي
+
+128
+00:10:55,350 --> 00:10:59,030
+البارا position بيصير عندى لما بده احط ال sub city
+
+129
+00:10:59,030 --> 00:11:02,190
+و انت التاني يا بده احط على هذا
+
+130
+00:11:06,350 --> 00:11:11,530
+هذا الكلام هناخده اكثر بالتفصيل لما بدنا نشرح
+
+131
+00:11:11,530 --> 00:11:14,990
+تفاعلات
+
+132
+00:11:14,990 --> 00:11:20,410
+البنزين لحتى الان واضح انكم ال hybridization ال
+
+133
+00:11:20,410 --> 00:11:23,210
+bond angles ال bond lengths البنزين
+
+134
+00:11:25,950 --> 00:11:31,250
+بداياكوا تتذكروا شغلة أنه العلم مابيجيش ببلاش ..
+
+135
+00:11:31,250 --> 00:11:37,510
+العلم مابيجيش ببلاش .. البنزين أول ما اكتشف ..
+
+136
+00:11:37,510 --> 00:11:42,430
+اكتشف سائل كان بيعمل فردق .. العالم فردق إذا
+
+137
+00:11:42,430 --> 00:11:47,250
+بتعرفواتقطير لقطران الفحم الكول تار وما إلى ذلك
+
+138
+00:11:47,250 --> 00:11:52,990
+فصل سائل هذا السائل لجأ أن ال boiling point له 80
+
+139
+00:11:52,990 --> 00:12:01,170
+.81% الآن عمل الصيغة ال molecular formula له لجأ
+
+140
+00:12:01,170 --> 00:12:04,910
+أو قبل ذلك عمل ال empirical formula ال empirical
+
+141
+00:12:04,910 --> 00:12:12,430
+formula متذكرينها أصغر صيغة أصغر نسبة لجها CHالـ
+
+142
+00:12:12,430 --> 00:12:16,550
+CH هلومة C2H2C3H3C4H4
+
+143
+00:12:16,550 --> 00:12:21,330
+في تحاليل معينة عملوا ال molecular formula اللي هي
+
+144
+00:12:21,330 --> 00:12:26,530
+تمثل العدد الحقيقي مش النسبة مش أبسط نسبة ال
+
+145
+00:12:26,530 --> 00:12:33,160
+empirical formulaأبسط نسبة ممكن تكون مضروبة بتنين
+
+146
+00:12:33,160 --> 00:12:34,900
+او تلاتة او اربع او خمس واطفال
+
+147
+00:12:46,610 --> 00:12:54,650
+C6H6 فثبت عنده الآن ان البنزين عبارة عن 6 ذرات
+
+148
+00:12:54,650 --> 00:12:59,470
+كربون و 6 ذرات هيدروجين هذه اللي بنسميها احنا ايش
+
+149
+00:12:59,470 --> 00:13:04,410
+molecular formula دائما و ابدا السؤال الاصعب في
+
+150
+00:13:04,410 --> 00:13:08,290
+الكيميا ان 6 ذرات كربون و 6 ذرات هيدروجين كيف
+
+151
+00:13:08,290 --> 00:13:14,070
+بإمكاننا نحطهم يعملوا شكلفيه قلوم كتير structural
+
+152
+00:13:14,070 --> 00:13:17,030
+formulas .. ال structural formula اللي هي بنسميها
+
+153
+00:13:17,030 --> 00:13:21,310
+الصيغة الاش .. الصيغة التفصيلية أو الصيغة البنائية
+
+154
+00:13:22,220 --> 00:13:27,600
+الصيغة البنائية صعبة جدا إيجادها و بحاجة إلى كثير
+
+155
+00:13:27,600 --> 00:13:32,780
+من التجارب و إلى كثير من العلم الآن إذا تخيلتوا بس
+
+156
+00:13:32,780 --> 00:13:38,120
+أنه اكتشف البنزين ك molecular formula في ال 1824
+
+157
+00:13:38,120 --> 00:13:46,700
+عشان يقولوا بعد هيك أن ال C6H6 موجودين بهذا الشكل
+
+158
+00:13:46,700 --> 00:14:00,170
+كم لازمهم شغلوا بحثكم شهر؟ كم سنة؟ أربعين سنة من
+
+159
+00:14:00,170 --> 00:14:03,570
+الف و تمانمية تقريبا و خمسة و عشرين كان الاكتشاف
+
+160
+00:14:03,570 --> 00:14:08,690
+للألف و تمانمية و خمسة و ستين بس عشان اقول ست ذرات
+
+161
+00:14:08,690 --> 00:14:14,720
+كربون و ست هيدروجين كيف موجودين يصل لهذا الشكلتشوف
+
+162
+00:14:14,720 --> 00:14:20,120
+قدش العلم بياخد وجهته ..الان طالما ان لزمني اربعين
+
+163
+00:14:20,120 --> 00:14:24,620
+سنة و انا اعمل تجارب لحد ما اصل للشكل اللي مازال
+
+164
+00:14:24,620 --> 00:14:29,120
+مقبول و بنقدر نعتبره صحيح في زماننا .. اذا بين بين
+
+165
+00:14:29,120 --> 00:14:35,980
+المفروض نعمله كتير شغل غلطواضح؟ بيوم من الأيام
+
+166
+00:14:35,980 --> 00:14:39,300
+الشغل الغلط اللي عملوه كان موجود في الكتب وكان
+
+167
+00:14:39,300 --> 00:14:44,760
+يتدرس وكانوا يحلفوا عليه يمين عشانك الناس ما تغترش
+
+168
+00:14:44,760 --> 00:14:49,740
+أول ما تجيها فكرة أنها الفكرة اللي هي جاياها أنهي
+
+169
+00:14:49,740 --> 00:14:58,050
+الصح بعد عشر سنين ممكن تكتشف أن الفكرةخطأ، مظبوط
+
+170
+00:14:58,050 --> 00:15:01,890
+ولا لا؟ يعني مناسق مفاوضات Camp David اللي بدهم
+
+171
+00:15:01,890 --> 00:15:05,670
+يحطوه الآن وزير خارجية في مصر، امبارح شو بيقول؟
+
+172
+00:15:05,670 --> 00:15:08,110
+والله انا اكتشفت ان Camp David بالنسبة لنا
+
+173
+00:15:08,110 --> 00:15:11,910
+المصريين كويسة، لكن بالنسبة للفلسطينيين دمرت
+
+174
+00:15:11,910 --> 00:15:17,630
+القضية الفلسطينية، الان وقت ايش اكتشف الكلام؟بعد
+
+175
+00:15:17,630 --> 00:15:21,530
+سنين بعد ما صارت اسرائيل تلعب فينا ومافيش اي حد
+
+176
+00:15:21,530 --> 00:15:25,690
+يدافع عنها بعد ما عزلت القضية عن كل العرب فشيء
+
+177
+00:15:25,690 --> 00:15:30,410
+اليوم انت بتعتقده صح بكرا بيصير غلط من الأشكال
+
+178
+00:15:30,410 --> 00:15:34,790
+اللي كانت موجودة قبل شكل البنزين انا جبتلكوا بعض
+
+179
+00:15:34,790 --> 00:15:38,810
+الأشكال وإذا انتوا بتتطلعوا على هذه الأشكال ويلها
+
+180
+00:15:38,810 --> 00:15:41,390
+أسماء ودُرستة في يوم من الأيام مابتناش ندخل فيها
+
+181
+00:15:41,390 --> 00:15:44,010
+بالتفصيل احنا في النهاية اصفين هذه البنزين set
+
+182
+00:15:44,010 --> 00:15:49,290
+carbonate و set hydrogenateانتهينا منه لكن بس عشان
+
+183
+00:15:49,290 --> 00:15:54,270
+تشوفوا كيف منطق العلم هذا الشكل مثلا الشكل 45
+
+184
+00:15:54,270 --> 00:15:58,990
+بيسموه ديوار بنزين نسبة للعالم ديوار لو بتطلعوا
+
+185
+00:15:58,990 --> 00:16:01,890
+carbon اتنين تلاتة اربعة خمسة ستة ده زي صفحة
+
+186
+00:16:01,890 --> 00:16:06,290
+الكتاب المفتوح او زي ال laptop المفتوح هاي موقع
+
+187
+00:16:06,290 --> 00:16:09,490
+اتنين تلاتة اربعة خمسة ستة حطوها هيدروجين هيدروجين
+
+188
+00:16:09,490 --> 00:16:12,190
+هيدروجين هيدروجين هيدروجين هيدروجين و رابطة في
+
+189
+00:16:12,190 --> 00:16:17,980
+النصزي الكتاب المفتوح هذا كان مقترح للبنزين عمله
+
+190
+00:16:17,980 --> 00:16:23,840
+العالم ديوار العالم مشهورين هدول الأسماء في العلوم
+
+191
+00:16:23,840 --> 00:16:32,700
+هوكل عمل شكل زي هيك واضح؟ عالم تانيلادنبورغ عمل
+
+192
+00:16:32,700 --> 00:16:37,820
+البرزمان زي المنشورة بتعرفوا البرزمان سموه إيش
+
+193
+00:16:37,820 --> 00:16:45,040
+برزمان هذا لادنبورغ ألماني ناس قالوا لأ هو عبارة
+
+194
+00:16:45,040 --> 00:16:50,160
+عن سايكلوبروبين ومربوط برابط أحد يعدوا carbon 2 3
+
+195
+00:16:50,160 --> 00:16:54,760
+4 5 6 و هنا بيجي هيدروجين هيدروجين هيدروجين
+
+196
+00:16:54,760 --> 00:16:59,500
+هيدروجين هيدروجين هيدروجين هاي C6H6واضح؟ شكل تاني
+
+197
+00:16:59,500 --> 00:17:04,820
+كان بالطريقة اللى موجودة هناك 49 Klaus و هدولة
+
+198
+00:17:04,820 --> 00:17:09,700
+كانوا علماء اكبر فى النهاية بس اللى ثبت ان الشكل
+
+199
+00:17:09,700 --> 00:17:15,400
+الصحيح هو الشكل اللى عمله العالم Kekuli الآن
+
+200
+00:17:15,400 --> 00:17:19,800
+لاحظوا هنا انتوا جاعدين بتخلطوا الكيميا بالهندسة
+
+201
+00:17:21,070 --> 00:17:25,930
+الان إنتوا إيش بتخلطوا؟ الكيميا بالهندسة و قد
+
+202
+00:17:25,930 --> 00:17:30,310
+تستغربوا إنه كيكولي .. كيكولي هذا اللي حاطين صورته
+
+203
+00:17:30,310 --> 00:17:36,490
+كان مهندس معماري بعد ما خلص الهندسة المعمارية
+
+204
+00:17:36,490 --> 00:17:40,430
+حولوا درس كيميا زي ما اليوم كتير بيعملوا من
+
+205
+00:17:40,430 --> 00:17:44,150
+المهندسات المعماريات لما بيلاقوا الشغل كلهم بيجوا
+
+206
+00:17:44,150 --> 00:17:47,710
+بيندرسوا من أول و جديد كيميا و فيزيا و تعليم أساسي
+
+207
+00:17:48,240 --> 00:17:53,740
+عدد كبير جدا واضح كيكولي لأنه أحب الكيميا و
+
+208
+00:17:53,740 --> 00:17:58,200
+الكيميا كلها structures و كلها هندسة بناء رباني كل
+
+209
+00:17:58,200 --> 00:18:01,280
+الأشكال اللي بتشوفوها انتوا لاحظوا هي عبارة عن
+
+210
+00:18:01,280 --> 00:18:05,720
+فعلا إيش؟ Geometry مش احنا بندرس Geometry او هندسة
+
+211
+00:18:05,720 --> 00:18:10,800
+فكيكولي كان مهندس معماري حول إلى كيميائي و هو اللي
+
+212
+00:18:10,800 --> 00:18:18,290
+اقترح الشكل هذا تبع البنزينواضح؟ هو ليش اخترح شكل
+
+213
+00:18:18,290 --> 00:18:22,290
+البنزين؟
+
+214
+00:18:22,290 --> 00:18:27,570
+لأ لأ، وش بيعرفوا من التركيبة؟ احنا بنستنتج، احنا
+
+215
+00:18:27,570 --> 00:18:30,910
+لا شايفين ذرات ولا .. ولا ما يحزنون، هذه أشكال
+
+216
+00:18:30,910 --> 00:18:34,070
+استنتاجية على الأقل في المراحل الأولى، الآن بعد ال
+
+217
+00:18:34,070 --> 00:18:38,410
+X-ray صارت أشكال بإمكاننا نشوفها أو نقدرها ..
+
+218
+00:18:38,410 --> 00:18:43,130
+نقدرها باستعمال أشعة X، فذاك الوقت كنا بنستنتج
+
+219
+00:18:43,130 --> 00:18:47,470
+الأشكاليعني الكيميا مثلا ضالت مش قادرة تفهم شكل
+
+220
+00:18:47,470 --> 00:18:52,730
+الميثين اللي هو أبسط شكل للـ 1873 لبعد شكل البنزين
+
+221
+00:18:52,730 --> 00:18:56,950
+لما اكتشفوا شكل الميثين بعد ما اكتشفوا شكل الميثين
+
+222
+00:18:56,950 --> 00:18:59,550
+اللي حكينالكوا هي التتراهيدرال الكيميا اتطورت قبل
+
+223
+00:18:59,550 --> 00:19:04,030
+ايه ماكانوش قادرين يفهموها واضح؟ فالخلاصة بدأ شوية
+
+224
+00:19:04,030 --> 00:19:08,890
+عقول هندسية ربما مرة حكينالكوا في الالوتروبز على
+
+225
+00:19:08,890 --> 00:19:14,200
+الكربون وقلنالكوا في كرة الكربون 60كيف لما يكون
+
+226
+00:19:14,200 --> 00:19:17,780
+عندى ستين ذرة كربون يكونوا فى كرة بعد ما اكتشفوا
+
+227
+00:19:17,780 --> 00:19:21,920
+ان عندي جزء مكون من ستين ذرة كربون اتغلبوا جدا فى
+
+228
+00:19:21,920 --> 00:19:28,540
+موضوعه فى النهاية اللى اتدخله حسب الشكل برضه مهندس
+
+229
+00:19:28,540 --> 00:19:31,700
+معمارى book monster fuller فصاروا يسموا المركبات
+
+230
+00:19:31,700 --> 00:19:35,580
+fullerines fullerines واخدوا عليها جائزة نوبل مش
+
+231
+00:19:35,580 --> 00:19:41,600
+زمان فى 1987 يعني سنة من ولدته جابل؟
+
+232
+00:19:41,600 --> 00:19:42,900
+ماشي
+
+233
+00:19:45,110 --> 00:19:50,970
+الان قدرين تشوفوا انه البنزين resonance structure
+
+234
+00:19:50,970 --> 00:19:54,250
+و لانه resonance structures بشكل عام مرات بيحطوا
+
+235
+00:19:54,250 --> 00:19:59,450
+الحلقة واضحة ال orbitals تبعت البنزين ال orbitals
+
+236
+00:19:59,450 --> 00:20:04,250
+تبعت البنزين طبعا هاي بعض ال orbitals انا حاططلكوا
+
+237
+00:20:04,250 --> 00:20:10,050
+ياها هي عبارة عن بي orbitals عمودية على المستوى
+
+238
+00:20:10,050 --> 00:20:16,550
+الان هذا بيعملبايبوند من الجهتين هذا بتعمل بايبوند
+
+239
+00:20:16,550 --> 00:20:19,350
+من الجهتين والاخرانيات الهان بيعملوا بايبوند من
+
+240
+00:20:19,350 --> 00:20:22,970
+الجهتين بناء على ذلك إيش بيصير فوق البنزين و تحت
+
+241
+00:20:22,970 --> 00:20:28,290
+البنزين electronic cloud حركة إلكترونية واضح و
+
+242
+00:20:28,290 --> 00:20:31,630
+لأنه كلها حركة إلكترونية يعني هل ال بايبوند هل هي
+
+243
+00:20:31,630 --> 00:20:36,210
+هان ولا هانمش بعرف، في حركة إلكترونية و لذلك إحنا
+
+244
+00:20:36,210 --> 00:20:40,630
+إيجي الاقتراح اللي عندنا أنه ال bond order واحد و
+
+245
+00:20:40,630 --> 00:20:46,330
+نص و أنه كل الروابط متساوين و مافيش عنده single و
+
+246
+00:20:46,330 --> 00:20:51,330
+double bonds لكن في عنده resonance structure زي ما
+
+247
+00:20:51,330 --> 00:20:55,830
+أنتوا شايفين هنا إذا ال B orbitals بشكل عام كيف
+
+248
+00:20:55,830 --> 00:21:02,170
+بيكونوا عموديات على مستوى الجزء و هم اللي بيعملوا
+
+249
+00:21:04,320 --> 00:21:08,380
+الـ double bonds هم اللي بيعملوا ال buy bonds على
+
+250
+00:21:08,380 --> 00:21:18,820
+أي الأشكال الآن نيجي لتسمية مراكبات البنزين عبر
+
+251
+00:21:18,820 --> 00:21:22,800
+التاريخ البنزين كتير فيه مراكبات منه من مشتقاته
+
+252
+00:21:22,800 --> 00:21:26,620
+إلى استعمالات و تطبيقات مهمة ولذلك في بعض
+
+253
+00:21:26,620 --> 00:21:32,320
+المراكبات أخدت أسماءشهرة قبل ما نعمل نظام
+
+254
+00:21:32,320 --> 00:21:37,040
+systematic يعني نظام تحليلي من خلاله نقدر نسم
+
+255
+00:21:37,040 --> 00:21:41,960
+المراكبات هذه المراكبات اللي أخدت أسماء شهرة
+
+256
+00:21:41,960 --> 00:21:46,680
+موجودة على اللوح أبسط مراكب زي ما أنتوا شايفين أي
+
+257
+00:21:46,680 --> 00:21:51,740
+واحد فيهم البنزين البنزين بعد البنزين اللي عليه
+
+258
+00:21:51,740 --> 00:21:59,250
+مثل طلوين اللي عليه isopropylاكيومين اكيومين
+
+259
+00:21:59,250 --> 00:22:04,410
+بيذكركوا بإيش؟ بالكمون هذا المكون الأساسي للكمون
+
+260
+00:22:04,410 --> 00:22:10,250
+اكيومين واضح؟ مكون الكمون اللي متصل فيه double
+
+261
+00:22:10,250 --> 00:22:14,610
+bond أخدناه الاستايرين اللي بيعمل ال polymer اللي
+
+262
+00:22:14,610 --> 00:22:18,590
+اسمه ال polystyrene اللي بيعمل ال plastic ال
+
+263
+00:22:18,590 --> 00:22:23,850
+polystyrene اللي عليه OH الفينول أخدناه قولنا
+
+264
+00:22:23,850 --> 00:22:31,370
+بيفضل الشكلEinol في double bond جنبها OH واضح؟
+
+265
+00:22:31,370 --> 00:22:38,470
+اللي فيه O مثل بيسموه Anisole .. Anisole اللي فيه
+
+266
+00:22:38,470 --> 00:22:47,090
+مجموعة Aldehydeبنزالدهيد اللي في هذه المجموعة ال C
+
+267
+00:22:47,090 --> 00:22:51,950
+double bond OCH3 هذه المجموعة بالكيميا بنسميها
+
+268
+00:22:51,950 --> 00:22:57,370
+acetyl احنا هذول مجمعتين كمجموعات لوحدهم ال C
+
+269
+00:22:57,370 --> 00:23:04,710
+double bond OH كمجموعة لوحدها اسمها formalالمجموعة
+
+270
+00:23:04,710 --> 00:23:09,430
+ايش اسمها؟ Formula group وهذه المجموعة C double
+
+271
+00:23:09,430 --> 00:23:18,390
+bond O CH3 اسمها? Acetel و مرات ايش بيختصروها؟ AC
+
+272
+00:23:18,390 --> 00:23:23,510
+فهذا المركب اللي في مجموعة ال formula كله اسمه
+
+273
+00:23:25,040 --> 00:23:31,080
+بنزالديهيد اللي فيه مجموعة الاسيتل أسيتوفينون ..
+
+274
+00:23:31,080 --> 00:23:39,560
+أسيتوفينون اللي فيه حامض COOH .. COOH بنزوك أسيت
+
+275
+00:23:39,910 --> 00:23:46,270
+اللي فيه nh2 أنيلين okay طيب السؤال يا ترى هدولة
+
+276
+00:23:46,270 --> 00:23:51,870
+مطلوب مننا نحفظهم أكيد هدول مركبات أساسية ما
+
+277
+00:23:51,870 --> 00:23:58,290
+بيستغنى عنهم اللي بدرسوا الكيميا الآن بعد ذلك
+
+278
+00:23:58,290 --> 00:24:03,380
+بنستعمل طريقة الاشتقاءIobac method of nomenclature
+
+279
+00:24:03,380 --> 00:24:10,240
+اشتغال مثلا لو عند بروم بنسمي المركب بروم وبنزين
+
+280
+00:24:10,240 --> 00:24:15,240
+لو عندنا نيترو بنزين نيترو بنزين لو عندها دي مثلا
+
+281
+00:24:15,240 --> 00:24:23,380
+CH2 CH3 إتل إتل بنزين لو عندنا بروبل CH2 CH2 CH3
+
+282
+00:24:23,380 --> 00:24:27,120
+بروبل بنزين لو عندنا tertiary butyl اللي عامله زي
+
+283
+00:24:27,120 --> 00:24:27,860
+الصليب
+
+284
+00:24:34,990 --> 00:24:40,530
+Tertiarybutylbenzene، واضح؟ فهم عليك، هذا الإسم
+
+285
+00:24:40,530 --> 00:24:44,790
+سبق، هذا إسم .. إسم شهرة، فكان المركب مفصول وما
+
+286
+00:24:44,790 --> 00:24:48,250
+أخد إسم شهرة قبل ما نحطها الكلام، فما بيسموهش مثل
+
+287
+00:24:48,250 --> 00:24:51,590
+بنزين، يعني لو بدك تتطلع على كل كتب ال organ ال
+
+288
+00:24:51,590 --> 00:24:55,630
+chemistry بيقوله شلة طلوين، كمنطق أنت بدك تقول في
+
+289
+00:24:55,630 --> 00:25:00,060
+الآخر مثل بنزين، مظبوط ولا لا؟صحيح و أنا كان
+
+290
+00:25:00,060 --> 00:25:04,640
+بإمكاني أقول amino benzene لكن أخد اسم ال aniline
+
+291
+00:25:04,640 --> 00:25:10,020
+خلاص هذه أسماء common names و ال common names سبقت
+
+292
+00:25:10,020 --> 00:25:17,200
+النظام اللي هو الاشتقاقي فبتضل .. بتضل عند الناس
+
+293
+00:25:17,200 --> 00:25:22,260
+أسماء إيش ال common names يعني مثلا إحنا في غزة
+
+294
+00:25:22,260 --> 00:25:27,490
+ممكن نقول بدنا نروح على السدرةكل الناس بتعرف
+
+295
+00:25:27,490 --> 00:25:33,030
+السدرة لأن عمرها صار أكم مت ولا ألف سنة، الآن يا
+
+296
+00:25:33,030 --> 00:25:38,210
+تورا الشارعين اللي هناك مالهم مش اسم، إلهم اسم لو
+
+297
+00:25:38,210 --> 00:25:41,290
+بدكوا تروحوا تشوفوا، طب مين بيعرفهم باسم الشوارع
+
+298
+00:25:41,290 --> 00:25:44,890
+بتاعتهم؟
+
+299
+00:25:44,890 --> 00:25:50,050
+إلهم أسماء لكن ماحد بيعرفهم باسمهم ال common name
+
+300
+00:25:50,050 --> 00:25:56,390
+سبقاللي هو الاسم الاشتقاقي واضح؟ الكم و النعم سبق
+
+301
+00:25:56,390 --> 00:25:59,630
+الاسم الاشتقاقي مثلا إحنا عند كل البلد تقولوله
+
+302
+00:25:59,630 --> 00:26:04,050
+بدنا نركب ع شرع المشتل في النصر بركبكوا اجرؤش
+
+303
+00:26:04,050 --> 00:26:09,310
+مكتوب ع الشرع بيتلاقوهش مكتوب شرع المشتل واضح؟
+
+304
+00:26:09,310 --> 00:26:13,230
+فالكم و النعم لما يسبق خلاص بياخد أولوية بتصير
+
+305
+00:26:13,230 --> 00:26:19,290
+تتسمى فيه وإلا كان ممكن سؤالك انسهله أكتر هذا شو
+
+306
+00:26:19,290 --> 00:26:24,400
+أخد اسم؟بنزين .. طب سموليه اشتقاقيا ..
+
+307
+00:26:24,400 --> 00:26:29,580
+Cyclohexatriene
+
+308
+00:26:29,580 --> 00:26:34,920
+.. مش Cyclohexane
+
+309
+00:26:34,920 --> 00:26:40,000
+اكمين .. اتراين .. Cyclohexatriene .. عمركوا
+
+310
+00:26:40,000 --> 00:26:45,040
+سمعتوا حد بيقول عنه .. Cyclohexatriene .. بنزين ..
+
+311
+00:26:45,040 --> 00:26:49,240
+واضح؟ فالاسم الاشتقاقي سبق .. عفوا .. ال common
+
+312
+00:26:49,240 --> 00:26:55,470
+noun سبق خلاصالان لما بصير في عندى .. لما بصير في
+
+313
+00:26:55,470 --> 00:27:01,790
+عندى اكثر من substituent على الجزاء المفروض ان انا
+
+314
+00:27:01,790 --> 00:27:09,110
+بصير بدي استعمل نظامترقيم، نظام ترقيم عشان أسميهم
+
+315
+00:27:09,110 --> 00:27:13,750
+أو نظام حروف أحيانا اللي حكينالكوا ياه قبل شوية
+
+316
+00:27:13,750 --> 00:27:18,910
+قولنالكوا إن إذا اعتبرنا أنه أول موضع أساس أيا كان
+
+317
+00:27:18,910 --> 00:27:23,590
+اللي بيكون بالنسبة له على موضع اتنين وعلى موضع
+
+318
+00:27:23,590 --> 00:27:30,570
+تلاتة وعلى موضع أربعة قارة بس رجاء في ناس يعني من
+
+319
+00:27:30,570 --> 00:27:34,470
+تجربتنا رغم إن الواحد بيحبش يقول هالكلامقدام
+
+320
+00:27:34,470 --> 00:27:40,730
+الكاميرا بس مش مشكلة من تجربتنا في ناس بتخيل انه
+
+321
+00:27:40,730 --> 00:27:45,970
+انا لازم اكون ماسك الجزء زي هيك و هذا ال ortho
+
+322
+00:27:45,970 --> 00:27:50,710
+position لفوق الاصل و ال ortho موجود بهالشكل لأ
+
+323
+00:27:50,710 --> 00:27:54,470
+احنا مابنقولش هذا الكلام احنا بنقول انه اذا في
+
+324
+00:27:54,470 --> 00:28:01,940
+عندى substituent أولى اللي جنبها بتكون orthoواضح؟
+
+325
+00:28:01,940 --> 00:28:06,640
+الآن لو أنا مش ماسك الجزء بهذه الهيئة، ماسكه بهذه
+
+326
+00:28:06,640 --> 00:28:12,460
+الهيئة، هذا الموقع إيش يعتبر؟ برضه Ortho بالنسبة
+
+327
+00:28:12,460 --> 00:28:16,500
+لهذه، إذا ال Ortho هو موقع اتنين، طب لو ماسكه بهذه
+
+328
+00:28:16,500 --> 00:28:21,360
+الهيئة، يعني هذه .. هذه الصفرةبرضه Ortho .. لو
+
+329
+00:28:21,360 --> 00:28:24,260
+ماسكوا هيك .. برضه Ortho .. لو ماسكوا هيك .. برضه
+
+330
+00:28:24,260 --> 00:28:28,540
+Ortho .. فال Ortho هو الموقع المجاور .. في ناس
+
+331
+00:28:28,540 --> 00:28:34,360
+خلاص مصرين انه بدهم يتخيلوا ان هذا المكان هو Ortho
+
+332
+00:28:34,360 --> 00:28:38,760
+.. بالتالي لو انا مسكت الجزء زي هيك .. لو انا مسكت
+
+333
+00:28:38,760 --> 00:28:41,620
+الجزء زي هيك و عندي substituent تحت .. محل ما انا
+
+334
+00:28:41,620 --> 00:28:46,620
+ماسكه .. و قلتلكوا هذا الموقع .. ايش بيكون ..
+
+335
+00:28:46,620 --> 00:28:52,620
+بيكون نيتا بالنسبة لي ..لأن واحد .. تين .. تلاتة
+
+336
+00:28:52,620 --> 00:28:59,660
+واضح؟ فكلمة Ortho و Meta و Para هي شغلة نسبية اللي
+
+337
+00:28:59,660 --> 00:29:03,640
+بيجي على موقع اتنين بسميه Ortho و اللي على موقع
+
+338
+00:29:03,640 --> 00:29:09,100
+تلاتة Meta اللي على موقع أربعة Para واضح؟ الان لو
+
+339
+00:29:09,100 --> 00:29:12,060
+الناس بدهم مش يكتبوا لا Ortho ولا Meta ولا Para
+
+340
+00:29:12,060 --> 00:29:19,480
+بدهم يكتبوا اتنين بيرايحوا حالهم واضح؟ بمعنىلو أنا
+
+341
+00:29:19,480 --> 00:29:25,080
+إجيت واطلعت على هذا المُركّب لاحظوا هذا المُركّب
+
+342
+00:29:25,080 --> 00:29:29,920
+إيش موجود فيه؟ ذرتين الكلور هدولة ذرتين الكلور لما
+
+343
+00:29:29,920 --> 00:29:34,960
+بدي أقول المُركّب dichlorobenzene كيف جايين
+
+344
+00:29:34,960 --> 00:29:39,720
+بالنسبة لبعض؟ Ortho إذا بقدر أنا أقول Ortho
+
+345
+00:29:39,720 --> 00:29:45,060
+dichlorobenzene طب لو بدي أستعمل الأرقام بقدر أقول
+
+346
+00:29:45,060 --> 00:29:52,530
+one twoDichlorobenzene فالأورتوا على موقع 1 و2
+
+347
+00:29:52,530 --> 00:29:57,930
+وانتوا Dichlorobenzene واضح؟ الآن خلّيني أعطيكم
+
+348
+00:29:57,930 --> 00:30:06,130
+مثل تسموه بطريقتين لو كان عندكم هنا CH3 وهنا عندكم
+
+349
+00:30:06,130 --> 00:30:13,670
+CL خلّيني نعتبر أنه الأساس في المركب الطلوين الآن
+
+350
+00:30:13,670 --> 00:30:19,710
+الطلوين على الموقعاتنين اتجاني ايش اكلورو شو بقدر
+
+351
+00:30:19,710 --> 00:30:26,590
+اسمي هذا اورثو اكلورو
+
+352
+00:30:26,590 --> 00:30:27,710
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+353
+00:30:27,710 --> 00:30:31,530
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+354
+00:30:31,530 --> 00:30:32,650
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+355
+00:30:32,650 --> 00:30:34,050
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+356
+00:30:34,050 --> 00:30:34,810
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+357
+00:30:34,810 --> 00:30:36,050
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+358
+00:30:36,050 --> 00:30:43,970
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+359
+00:30:45,660 --> 00:30:50,620
+الان لو حطيت اكتر من Substituent بصير بستعمل بس
+
+360
+00:30:50,620 --> 00:30:55,340
+نظام الأرقام، يعني لو حطيت هنا Chlor و حطيت هنا
+
+361
+00:30:55,340 --> 00:30:59,320
+Brom و
+
+362
+00:30:59,320 --> 00:31:00,620
+بجانس بلد تلوين
+
+363
+00:31:03,520 --> 00:31:09,300
+تو كلوروم تلوين اذا
+
+364
+00:31:09,300 --> 00:31:15,320
+نقطة ابتداء في الترقيم عنده الكاربون اللي حاملة
+
+365
+00:31:15,320 --> 00:31:16,720
+الميثل
+
+366
+00:31:26,710 --> 00:31:32,150
+كان ممكن تسمه المركب orthodimethylbenzene
+
+367
+00:31:32,150 --> 00:31:38,990
+لكن ال dimethylbenzene أخد اسم شهرة Exilin ال
+
+368
+00:31:38,990 --> 00:31:42,130
+dimethylbenzene أخد اسم شهرة .. شو اسم الشهرة لل
+
+369
+00:31:42,130 --> 00:31:46,350
+dimethylbenzene؟ Exilin الآن لو التنتين مثل جنب
+
+370
+00:31:46,350 --> 00:31:51,640
+بعض، شو بنسميه؟Ortho إكزايلين لو إنهم على موقع
+
+371
+00:31:51,640 --> 00:31:57,000
+واحد لتلاتة لبعض ميتا إكزايلين لو على موقع واحد
+
+372
+00:31:57,000 --> 00:32:02,580
+لاربع على بعض بارا إكزايلين إذا الإكزايلين في عند
+
+373
+00:32:02,580 --> 00:32:09,640
+منه Ortho يعني مجمعتين مثل جنب بعض ميتا على موقع
+
+374
+00:32:09,640 --> 00:32:18,450
+واحد تلاتة بارا على موقع واحد وأربع واضح؟ طيبلو
+
+375
+00:32:18,450 --> 00:32:24,720
+كان في عندى الديهايد مثلا مع ال chlorineبدنا نعتبر
+
+376
+00:32:24,720 --> 00:32:29,860
+الأولوية للالدهايد لإن الجزاء ماخد اسم common مع
+
+377
+00:32:29,860 --> 00:32:36,020
+الالدهايد، شو اسمه؟ بنزالدهايد، بنزالدهايد، الان
+
+378
+00:32:36,020 --> 00:32:39,840
+لما تكون هذه number one، one, two, three, four،
+
+379
+00:32:39,840 --> 00:32:44,460
+إيش هتكون؟ Barachlorobenzaldehyde
+
+380
+00:32:44,460 --> 00:32:51,050
+أو 4-chlorobenzaldehydeواضح بارا كلورو بنزلديهيد
+
+381
+00:32:51,050 --> 00:32:58,290
+او four chlorobenzaldehyde الان
+
+382
+00:32:58,290 --> 00:33:07,530
+مرات بيصير الحقيقة عندكم مشكلة لما بيكون عندكم في
+
+383
+00:33:07,530 --> 00:33:14,800
+الجزاءلما بيكون عندكم في الجزاء مجموعتين واحدة
+
+384
+00:33:14,800 --> 00:33:20,580
+منهم بتكون تعتبرها الأصل و تبدأوا الترقيم من عندها
+
+385
+00:33:20,580 --> 00:33:24,640
+و التانية بتكون تقول عنها number two يعني أنيا بدي
+
+386
+00:33:24,640 --> 00:33:28,220
+أقول عنها number one أنيا بدي أقول عنها number two
+
+387
+00:33:28,220 --> 00:33:32,640
+يعني ببساطة لو بتكون تطلعوا مثلا على هذا الجزاء أو
+
+388
+00:33:32,640 --> 00:33:37,460
+على هذا الجزاء هل يا ترى بدي أقول onetwo three
+
+389
+00:33:37,460 --> 00:33:42,660
+four five six ولا بتقول one two three four five
+
+390
+00:33:42,660 --> 00:33:49,050
+six او لو عندي مثلا هنا مثل هذا الجزءهذا من
+
+391
+00:33:49,050 --> 00:33:53,810
+الجزيات اللي بتحير، لو أخدت البنزين مع الميثل، إله
+
+392
+00:33:53,810 --> 00:33:57,830
+اسم شهرة، شو اسم الشهرة تبعه؟ طولوين، طولوين، و لو
+
+393
+00:33:57,830 --> 00:34:01,810
+أخدت البنزين مع ال double bond، إله اسم شهرة؟
+
+394
+00:34:01,810 --> 00:34:04,770
+استيرين، استيرين، شو اسم الشهرة؟ استيرين، استيرين،
+
+395
+00:34:04,770 --> 00:34:05,090
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+396
+00:34:05,090 --> 00:34:05,130
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+397
+00:34:05,130 --> 00:34:06,830
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+398
+00:34:06,830 --> 00:34:09,950
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+399
+00:34:09,950 --> 00:34:09,950
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+400
+00:34:09,950 --> 00:34:13,260
+استيرين، استيرين، استيرين، استيرين، استيرينوالله
+
+401
+00:34:13,260 --> 00:34:18,920
+Toluene يحمل مجموعة .. إيش اسمها دي؟ CH2 double
+
+402
+00:34:18,920 --> 00:34:25,840
+bond CH أخدتولها اسم في
+
+403
+00:34:25,840 --> 00:34:34,600
+واحدة حكت شوية غلط إيش اسمها دي اللي حكت؟ Vinyl
+
+404
+00:34:34,600 --> 00:34:39,860
+سمعيني .. سمعيني .. بس نسألك شوية .. إيش اسمها؟
+
+405
+00:34:39,860 --> 00:34:49,380
+Vinylفنل مش فنل الان الفنل هي حلقة البنزين الفنل
+
+406
+00:34:49,380 --> 00:34:52,880
+فنل
+
+407
+00:34:52,880 --> 00:35:10,240
+فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل
+
+408
+00:35:11,580 --> 00:35:16,520
+هي حلقة البنزين لأ حلقة البنزين نفسها اسمها phenyl
+
+409
+00:35:16,520 --> 00:35:20,960
+واضح؟
+
+410
+00:35:20,960 --> 00:35:24,580
+حلقة البنزين نفسها اسمها H-Phenyl يعني لو اجت على
+
+411
+00:35:24,580 --> 00:35:28,720
+مركب مثلا معين و كانت هي تعتبر substituent أو
+
+412
+00:35:28,720 --> 00:35:33,060
+group بنسميها H-Phenyl فالخلاصة انه مثل هذه الحالة
+
+413
+00:35:33,060 --> 00:35:36,740
+من الحالات اللي بتحير هل يا تورا المركب اللي عندى
+
+414
+00:35:36,740 --> 00:35:37,940
+بدي أنسبه
+
+415
+00:35:44,770 --> 00:35:49,770
+الحقيقة في عندنا قواعد بتقدروا تعملوها أو تعتبروها
+
+416
+00:35:49,770 --> 00:35:55,190
+كقواعد عامة بتعطي أولويات .. بتعطي أولويات الآن
+
+417
+00:35:55,190 --> 00:36:00,230
+الأولويات بتقول أعلى أولوية بأبدأ الترقيم من عنده
+
+418
+00:36:00,230 --> 00:36:06,050
+و باعتبرها الأساسي ال Easterأقل منها ال acid أقل
+
+419
+00:36:06,050 --> 00:36:10,110
+منها ال aldehyde بمعنى لو عندى acid و عندى
+
+420
+00:36:10,110 --> 00:36:14,810
+aldehyde بيه نمر واحد ال acid الأقل منه ال ketone
+
+421
+00:36:14,810 --> 00:36:21,890
+لو عندى aldehyde و ketone مين اللى له أولوية ال
+
+422
+00:36:21,890 --> 00:36:27,650
+aldehyde واضح؟ الأن اتطلع هذا الشكل هذا الشكل كتير
+
+423
+00:36:27,650 --> 00:36:34,530
+حلو في ال aldehydeوالكيتون و المركب كله مع الديهيد
+
+424
+00:36:34,530 --> 00:36:40,550
+شو اسمه؟ أخدنا Benzaldehyde و المركب تحت مع
+
+425
+00:36:40,550 --> 00:36:44,590
+الكيتون أسيتوفينون
+
+426
+00:36:45,460 --> 00:36:49,300
+قبل شوية أخدناه بالاسم أشور هل يا ترى بدي أنسب
+
+427
+00:36:49,300 --> 00:36:53,620
+المركب لل الديهايد ولا لل كيتون؟ لل الديهايد، إذا
+
+428
+00:36:53,620 --> 00:36:57,660
+بدي أقول هذه الأساس اللي عندى، هذا بنزالديهيد، من
+
+429
+00:36:57,660 --> 00:37:01,500
+وين نمر واحد افترق قيمة؟ من عند ال الديهايد، one,
+
+430
+00:37:01,700 --> 00:37:08,280
+two, three, four، الآن هذه كمجموعة إيش اسمها؟ C
+
+431
+00:37:08,280 --> 00:37:16,420
+double bond O C H3 بتصير مجموعة أسيتلواضح؟ فبصير 4
+
+432
+00:37:16,420 --> 00:37:22,720
+-acetyl أو paraacetyl benzaldehyde شوفتوا كيف؟
+
+433
+00:37:22,720 --> 00:37:26,240
+يعني لما التقى ال aldehyde و ال ketone الأولوية
+
+434
+00:37:26,240 --> 00:37:31,240
+لمين؟ لل aldehyde لو التقى ال ketone و ال alcohol
+
+435
+00:37:31,240 --> 00:37:35,420
+الأولوية لمين؟ ال ketone طبعا أكيد لو التقى ال
+
+436
+00:37:35,420 --> 00:37:40,900
+aldehyde و ال alcohol الأولوية لمين؟ لل aldehyde
+
+437
+00:37:40,900 --> 00:37:43,040
+لاحظوا مثلا هذا المثال
+
+438
+00:37:46,390 --> 00:37:53,630
+مع الالديهايد اسمه
+
+439
+00:37:53,630 --> 00:37:55,330
+benzaldehyde
+
+440
+00:37:58,060 --> 00:38:03,220
+فيلول أنا لإيش بدي أسميه؟ للالديهايد إذا أنا كأنه
+
+441
+00:38:03,220 --> 00:38:07,160
+هي الأساس اللي عندى هذا بنزالديهايد وهي موقع واحد
+
+442
+00:38:07,160 --> 00:38:11,520
+اتنين تلاتة أربعة هذا بنزالديهايد على موقع أربعة
+
+443
+00:38:11,520 --> 00:38:16,200
+إيش حامل؟ مجموعة ال OH مجموعة ال OH إذا ماكانش
+
+444
+00:38:16,200 --> 00:38:19,560
+منسوب إلى المركب شو تسمى؟ هيدروكسي
+
+445
+00:38:21,480 --> 00:38:28,640
+بارا هيدروكسي واضح بارا هيدروكسي واضح إذا كيف اللي
+
+446
+00:38:28,640 --> 00:38:35,750
+هو نظام التسمية ال alcohol أكتر منالأمين اللي هو
+
+447
+00:38:35,750 --> 00:38:40,590
+ال NH2، الأمين أكتر من الألكين اللي فيه double
+
+448
+00:38:40,590 --> 00:38:46,310
+bond، الألكين أكتر من الألكيل، والألكين أكتر من ال
+
+449
+00:38:46,310 --> 00:38:51,230
+halogen، في هيك الأمور، و ال halogens زيها كمان
+
+450
+00:38:51,230 --> 00:38:56,030
+بتيجي ال nitrateيعني منخفضة في الأولوية بناء على
+
+451
+00:38:56,030 --> 00:38:59,810
+ذلك لو بدنا نيجي نشوف كل هدولة طبعا هدولة لما
+
+452
+00:38:59,810 --> 00:39:03,350
+كانوا تنتين halogens بيخلوهم alphabetical اللي
+
+453
+00:39:03,350 --> 00:39:06,430
+بتكون alphabetical في الأول بيحطوه بالنسبة للثانية
+
+454
+00:39:06,430 --> 00:39:12,190
+okay الان هنا لما عندكم الكنو نيترو وين نمر واحد
+
+455
+00:39:12,190 --> 00:39:15,290
+الكنو الكنو الكنو الكنو الكنو الكنو الكنو الكنو
+
+456
+00:39:15,290 --> 00:39:16,890
+الكنو الكنو الكنو الكنو الكنو الكنو الكنو الكنو
+
+457
+00:39:16,890 --> 00:39:25,090
+الكنو الكنو الكنوطلوين إذاً هذه صارت ميتا نيترو
+
+458
+00:39:25,090 --> 00:39:35,010
+طلوين واضح هنا عندكم ألكين و ألكين لمن
+
+459
+00:39:35,010 --> 00:39:40,510
+الأولوية الألكين مركب الألكين شو اسمه استيرين هاي
+
+460
+00:39:40,510 --> 00:39:44,390
+واحد اتنين تلاتة بناخد أقل ترقيم ممكنش واحدة تيجي
+
+461
+00:39:44,390 --> 00:39:49,110
+ترقم واحد اتنين تلاتة اربعة خمسة تروح تكتب five
+
+462
+00:39:49,110 --> 00:39:55,500
+مثللحظة وقت رجعت ان اسمها مجموعة three مثل او ميتا
+
+463
+00:39:55,500 --> 00:40:01,320
+مثل واضح هنا التقى عندكم ال halogen مع ال OH هي ال
+
+464
+00:40:01,320 --> 00:40:07,110
+OH هي ال halogen من الاولويةمُركّب الواتش إيش
+
+465
+00:40:07,110 --> 00:40:13,670
+اسمه؟ فينول إذا بارا كلورو فينول بارا كلورو فينول
+
+466
+00:40:13,670 --> 00:40:18,590
+هذا المُركّب التقى فيه المثل مع تلت مجموعات نايترو
+
+467
+00:40:18,590 --> 00:40:23,210
+مين أعلى؟ الألكين ولا النايترو؟ الألكين مُركّب
+
+468
+00:40:23,210 --> 00:40:26,150
+الألكين لحاله طلوين
+
+469
+00:40:28,350 --> 00:40:35,850
+4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4
+
+470
+00:40:35,850 --> 00:40:41,610
+-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6
+
+471
+00:40:41,610 --> 00:40:45,290
+-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3
+
+472
+00:40:45,290 --> 00:40:45,290
+-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4
+
+473
+00:40:45,290 --> 00:40:52,790
+-6-3-4-6-3-4-6-3-4-6
+
+474
+00:40:52,790 --> 00:40:55,270
+-3-4-
+
+475
+00:40:57,880 --> 00:41:03,680
+هي الـ ketone و الحامض و ال acid ممتاز مين اللي
+
+476
+00:41:03,680 --> 00:41:07,900
+أولوية ال acid و لا ال ketone ال acid إذا ترقيم
+
+477
+00:41:07,900 --> 00:41:12,900
+أنا عند ال acid واحد اتنين تلاتة أربعة مركب ال
+
+478
+00:41:12,900 --> 00:41:19,420
+acid إيش اسمه بنزويك acid إيش بيحمل بنزويك acid
+
+479
+00:41:19,420 --> 00:41:24,460
+على موقع أربعة C double bond OCH3 هذه المجموعة
+
+480
+00:41:24,460 --> 00:41:33,860
+مااسمها AcetylOkay طيب هذا المثال مين تحكيلنا عنه
+
+481
+00:41:33,860 --> 00:41:43,460
+فضلوا ايش انتقام فيه OH OH نيترو مين الهولوية هذا
+
+482
+00:41:43,460 --> 00:41:52,690
+ايه فنولفينول ايش بيحمل؟ عتنين واربعة وستة تراي
+
+483
+00:41:52,690 --> 00:41:57,650
+نايترو فينول هذا المركب مشهور في ال biology ال 246
+
+484
+00:41:57,650 --> 00:42:03,650
+تراي نايترو فينول اللي اسم شهرة بيسموه بكريك أسد
+
+485
+00:42:03,650 --> 00:42:06,830
+حامض لونه أصفر غامق اللي بيشتغل فيكوا القواعي و
+
+486
+00:42:06,830 --> 00:42:13,210
+إيديه بيصيروا أصفر غامق جدا واضح؟ أصفر غامق جدا
+
+487
+00:42:13,210 --> 00:42:14,810
+طيب أخر شيء
+
+488
+00:42:25,730 --> 00:42:29,570
+اخر شي بنعطيكوايا بس بنأكدلكوا ان ال aromatic
+
+489
+00:42:29,570 --> 00:42:33,950
+compounds اللي هم تطبيقات كتيرة في الدنيا .. اللي
+
+490
+00:42:33,950 --> 00:42:39,870
+هم تطبيقات كتيرة في الدنيا مثلا هذا المركب
+
+491
+00:42:39,870 --> 00:42:43,910
+aromatic بنزين acetosilic acid هذا هو الدوة
+
+492
+00:42:43,910 --> 00:42:50,200
+المشهورة اسمه اسبيرينهذا الاسبيرين هو عبارة عن
+
+493
+00:42:50,200 --> 00:42:57,260
+حلقة بنزين هذا المركب الديهايد معه مثل مع OH هذا
+
+494
+00:42:57,260 --> 00:43:04,520
+المركب اللي هو الفانيلا الفانيلا تبعت الكيك هذا
+
+495
+00:43:04,520 --> 00:43:09,260
+المركب برضه في حلقة بنزين مع CH2 و بعدين ايزو
+
+496
+00:43:09,260 --> 00:43:15,060
+بروفين ايزو بيوتلي جروب و CH3 و COH هذا
+
+497
+00:43:15,060 --> 00:43:21,580
+الابوبروفينمار عليكم ال ibuprofen اللي ضد الصداع
+
+498
+00:43:21,580 --> 00:43:26,540
+اللي بيجيب أجل الصداع ال 600 ال algonol 600 اللي
+
+499
+00:43:26,540 --> 00:43:32,300
+بيكون هيك راسهم بده ينفجر واضح فاللي ماعندوش بس
+
+500
+00:43:32,300 --> 00:43:35,540
+بدخل على الكتاب بياخد ibuprofen أسبيرين إيش ما
+
+501
+00:43:35,540 --> 00:43:40,820
+بلزمكم خدوا منهم فهذه مركبات لها أهمية في التطبيق
+
+502
+00:43:40,820 --> 00:43:42,900
+المرة اللي جاي ان شاء الله بنحكي عن التفاعلات
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..bec7c5e9595da4fb02e33cfdbe5237d80883b518
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3275, "start": 5.99, "end": 32.75, "text": "بنكمل في موضوع تفاعلات الـ alkenes تحديدًا تفاعلات الإضافة تحديدًا تفاعلات الإضافة المرة الماضية كملخص، كملخص على الكلام اللي حكيناه قلنا إنه إحنا لما بندرس تفاعل إضافة الـ alkene بدنا نتطلع على شغلتين بدنا نتطلع على الـ alkene symmetric ولا unsymmetric بدنا نتطلع على ال reagent", "tokens": [3555, 1863, 24793, 1211, 8978, 3714, 2407, 11242, 45367, 6055, 5172, 995, 30241, 9307, 2423, 39184, 419, 2653, 279, 6055, 5016, 16254, 3215, 14111, 995, 6055, 5172, 995, 30241, 9307, 33688, 11242, 31845, 3660, 6055, 5016, 16254, 3215, 14111, 995, 6055, 5172, 995, 30241, 9307, 33688, 11242, 31845, 3660, 9673, 25720, 9673, 46958, 10632, 9122, 42213, 9778, 9381, 12399, 9122, 42213, 9778, 9381, 15844, 2423, 28820, 10943, 13672, 1829, 11331, 4117, 1829, 8315, 3224, 12174, 1211, 8315, 36145, 3224, 11933, 5016, 8315, 5296, 15042, 44945, 3215, 2288, 3794, 6055, 5172, 995, 30241, 11933, 11242, 31845, 3660, 2423, 39184, 37688, 1450, 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"probability": 0.86328125}], "temperature": 1.0}, {"id": 6, "seek": 14947, "start": 121.89, "end": 149.47, "text": "مع الـ Br minus بكمل إضافة HBr واضح؟ فعملية الإضافة أو الـ mechanism of addition زيها زي إضافة إيش؟ المية على خطوتين الخطوة الأولى إضافة الـ H plus على ال double bond تكوين Carbocation الخطوة التانية اللي هو تفاعل الـ negative ion مع ال Carbocation واستكمال الإضافة", "tokens": [2304, 3615, 2423, 39184, 1603, 3175, 4724, 24793, 1211, 11933, 11242, 31845, 3660, 389, 22170, 4032, 46958, 5016, 22807, 6156, 25957, 1211, 10632, 33688, 11242, 31845, 3660, 34051, 2423, 39184, 7513, 295, 4500, 30767, 1829, 11296, 30767, 1829, 11933, 11242, 31845, 3660, 11933, 1829, 8592, 22807, 9673, 10632, 15844, 16490, 9566, 2407, 2655, 9957, 33962, 9566, 2407, 3660, 16247, 12610, 7578, 11933, 11242, 31845, 3660, 2423, 39184, 389, 1804, 15844, 2423, 3834, 6086, 6055, 4117, 2407, 9957, 2741, 65, 27943, 33962, 9566, 2407, 3660, 16712, 7649, 10632, 13672, 1829, 31439, 6055, 5172, 995, 30241, 2423, 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0.58154296875}, {"start": 1364.51, "end": 1364.77, "word": " ال", "probability": 0.8603515625}, {"start": 1364.77, "end": 1365.43, "word": " الكينز", "probability": 0.7969970703125}], "temperature": 1.0}, {"id": 60, "seek": 138381, "start": 1366.27, "end": 1383.81, "text": "واضح؟ تكوين مركبات بيسميها ال oxirans أو ال Epoxides من الalkenes إذا إحنا أخدنا alkene فعلناه مع pear acid، pear إيش معناه pear؟ لأ pear لأ لأ", "tokens": [2407, 46958, 5016, 22807, 6055, 4117, 2407, 9957, 3714, 31747, 3555, 9307, 4724, 1829, 38251, 1829, 11296, 2423, 5976, 347, 599, 34051, 2423, 462, 42871, 1875, 9154, 2423, 667, 25973, 11933, 15730, 11933, 5016, 8315, 5551, 9778, 3215, 8315, 37688, 1450, 6156, 30241, 8315, 3224, 20449, 37320, 8258, 12399, 37320, 11933, 1829, 8592, 20449, 8315, 3224, 37320, 22807, 5296, 10721, 37320, 5296, 10721, 5296, 10721], "avg_logprob": -0.28953597401127673, "compression_ratio": 1.367741935483871, "no_speech_prob": 1.1324882507324219e-06, "words": [{"start": 1366.27, "end": 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berichlorate", "probability": 0.55633544921875}], "temperature": 1.0}, {"id": 62, "seek": 142299, "start": 1399.51, "end": 1422.99, "text": "يكون في كام أكسجينة؟ أربع أكسجينات فال bear هنا تعني الزيادة bear acid معناه حامض فيه أكسجين زيادة، هاي معناه bear acid، bear acid الحامض اللي فيه أكسجين زيادة، بشكل عام صيغة الحامض العضوي إيش هي؟ R C double bond O OH", "tokens": [1829, 30544, 8978, 9122, 10943, 5551, 4117, 3794, 7435, 9957, 3660, 22807, 5551, 25513, 3615, 5551, 4117, 3794, 7435, 9957, 9307, 6156, 6027, 6155, 34105, 37279, 22653, 6024, 110, 1829, 18513, 3660, 6155, 8258, 20449, 8315, 3224, 11331, 10943, 11242, 8978, 3224, 5551, 4117, 3794, 7435, 9957, 30767, 1829, 18513, 3660, 12399, 8032, 47302, 20449, 8315, 3224, 6155, 8258, 12399, 6155, 8258, 21542, 10943, 11242, 13672, 1829, 8978, 3224, 5551, 4117, 3794, 7435, 9957, 30767, 1829, 18513, 3660, 12399, 4724, 8592, 28820, 6225, 10943, 20328, 1829, 17082, 3660, 21542, 10943, 11242, 18863, 11242, 45865, 11933, 1829, 8592, 39896, 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"temperature": 1.0}, {"id": 64, "seek": 145122, "start": 1443.7, "end": 1451.22, "text": "حمض العضوى الوظيفة للحمض", "tokens": [5016, 2304, 11242, 18863, 11242, 2407, 7578, 2423, 2407, 19913, 33911, 3660, 24976, 35571, 11242], "avg_logprob": -0.6240234151482582, "compression_ratio": 0.9375, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1443.6999999999998, "end": 1445.1, "word": "حمض", "probability": 0.5593668619791666}, {"start": 1445.1, "end": 1445.86, "word": " العضوى", "probability": 0.8218994140625}, {"start": 1445.86, "end": 1450.64, "word": " الوظيفة", "probability": 0.61866455078125}, {"start": 1450.64, "end": 1451.22, "word": " للحمض", "probability": 0.6505533854166666}], "temperature": 1.0}, {"id": 65, "seek": 147540, "start": 1454.32, "end": 1475.4, "text": "بصير زيادة أكسوجينة زي الميه، الميه كانت H2O واحدة، لما صارت hydrogen peroxide، إيه صارت؟ تنتين أكسوجين، pear، مشقولنا hydrogen peroxide، فكلمة pear إيش بتعني؟ زيادة أكسوجينة", "tokens": [3555, 9381, 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{"start": 1457.06, "end": 1457.56, "word": " الميه،", "probability": 0.67779541015625}, {"start": 1457.56, "end": 1457.86, "word": " الميه", "probability": 0.94873046875}, {"start": 1457.86, "end": 1458.32, "word": " كانت", "probability": 0.93017578125}, {"start": 1458.32, "end": 1460.44, "word": " H2O", "probability": 0.8478190104166666}, {"start": 1460.44, "end": 1462.06, "word": " واحدة،", "probability": 0.630828857421875}, {"start": 1462.06, "end": 1462.58, "word": " لما", "probability": 0.895263671875}, {"start": 1462.58, "end": 1463.34, "word": " صارت", "probability": 0.9915364583333334}, {"start": 1463.34, "end": 1464.14, "word": " hydrogen", "probability": 0.79736328125}, {"start": 1464.14, "end": 1465.44, "word": " peroxide،", "probability": 0.7373046875}, {"start": 1465.44, "end": 1465.64, "word": " إيه", "probability": 0.8099772135416666}, {"start": 1465.64, "end": 1467.44, "word": " صارت؟", "probability": 0.9847412109375}, {"start": 1467.44, "end": 1468.12, "word": " تنتين", "probability": 0.8924153645833334}, {"start": 1468.12, "end": 1468.96, "word": " أكسوجين،", "probability": 0.8938802083333334}, {"start": 1468.96, "end": 1469.62, "word": " pear،", "probability": 0.359619140625}, {"start": 1469.62, "end": 1470.66, "word": " مشقولنا", "probability": 0.6145833333333334}, {"start": 1470.66, "end": 1471.16, "word": " hydrogen", "probability": 0.9697265625}, {"start": 1471.16, "end": 1472.2, "word": " peroxide،", "probability": 0.8606770833333334}, {"start": 1472.2, "end": 1472.72, "word": " فكلمة", "probability": 0.9515380859375}, {"start": 1472.72, "end": 1472.94, "word": " pear", "probability": 0.91943359375}, {"start": 1472.94, "end": 1473.18, "word": " إيش", "probability": 0.9226888020833334}, {"start": 1473.18, "end": 1474.32, "word": " بتعني؟", "probability": 0.9288330078125}, {"start": 1474.32, "end": 1474.78, "word": " زيادة", "probability": 0.9874267578125}, {"start": 1474.78, "end": 1475.4, "word": " أكسوجينة", "probability": 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2144.37, "end": 2144.67, "word": " هنا", "probability": 0.9921875}, {"start": 2144.67, "end": 2145.83, "word": " بتلاحظوا", "probability": 0.9177734375}, {"start": 2145.83, "end": 2145.99, "word": " ان", "probability": 0.41259765625}, {"start": 2145.99, "end": 2146.61, "word": " الميه", "probability": 0.6854654947916666}], "temperature": 1.0}, {"id": 92, "seek": 217067, "start": 2148.39, "end": 2170.67, "text": "الميّه وين بتهاجم؟ على الكربون لأن الميّه فيها إلكترونات والكربون موجبة هادة لما بتتحرك زيك بتصير OH plus هي بتكون أخدت ال H من الأول بفتح في النهاية بعدين ال OH إذا الهجوم بيكون من السالب على الموجبة", "tokens": [45340, 1829, 11703, 3224, 4032, 9957, 39894, 3224, 26108, 2304, 22807, 15844, 33251, 25513, 11536, 5296, 33456, 9673, 1829, 11703, 3224, 8978, 11296, 11933, 23275, 2655, 2288, 11536, 9307, 16070, 4117, 25513, 11536, 3714, 29245, 49401, 8032, 18513, 3660, 5296, 15042, 39894, 2655, 5016, 31747, 30767, 1829, 4117, 39894, 9381, 13546, 13931, 1804, 39896, 39894, 30544, 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2153.47, "word": " فيها", "probability": 0.8642578125}, {"start": 2153.47, "end": 2154.27, "word": " إلكترونات", "probability": 0.8347981770833334}, {"start": 2154.27, "end": 2155.09, "word": " والكربون", "probability": 0.78851318359375}, {"start": 2155.09, "end": 2156.49, "word": " موجبة", "probability": 0.8898111979166666}, {"start": 2156.49, "end": 2157.21, "word": " هادة", "probability": 0.66552734375}, {"start": 2157.21, "end": 2157.55, "word": " لما", "probability": 0.89404296875}, {"start": 2157.55, "end": 2158.11, "word": " بتتحرك", "probability": 0.902587890625}, {"start": 2158.11, "end": 2158.41, "word": " زيك", "probability": 0.888671875}, {"start": 2158.41, "end": 2158.95, "word": " بتصير", "probability": 0.8006184895833334}, {"start": 2158.95, "end": 2160.57, "word": " OH", "probability": 0.462158203125}, {"start": 2160.57, "end": 2161.25, "word": " plus", "probability": 0.19384765625}, {"start": 2161.25, "end": 2161.51, "word": " هي", "probability": 0.380859375}, {"start": 2161.51, "end": 2161.83, "word": " بتكون", "probability": 0.93359375}, {"start": 2161.83, "end": 2162.31, "word": " أخدت", "probability": 0.9320068359375}, {"start": 2162.31, "end": 2162.43, "word": " ال", "probability": 0.93505859375}, {"start": 2162.43, "end": 2162.65, "word": " H", "probability": 0.220458984375}, {"start": 2162.65, "end": 2162.85, "word": " من", "probability": 0.98974609375}, {"start": 2162.85, "end": 2163.35, "word": " الأول", "probability": 0.988037109375}, {"start": 2163.35, "end": 2163.91, "word": " بفتح", "probability": 0.84521484375}, {"start": 2163.91, "end": 2164.05, "word": " في", "probability": 0.89599609375}, {"start": 2164.05, "end": 2164.41, "word": " النهاية", "probability": 0.9073893229166666}, {"start": 2164.41, "end": 2164.77, "word": " بعدين", "probability": 0.6168212890625}, {"start": 2164.77, "end": 2164.85, "word": " ال", "probability": 0.65087890625}, {"start": 2164.85, "end": 2165.25, "word": " OH", "probability": 0.810546875}, {"start": 2165.25, "end": 2167.07, "word": " إذا", "probability": 0.48260498046875}, {"start": 2167.07, "end": 2167.79, "word": " الهجوم", "probability": 0.951904296875}, {"start": 2167.79, "end": 2168.25, "word": " بيكون", "probability": 0.9091796875}, {"start": 2168.25, "end": 2168.49, "word": " من", "probability": 0.99267578125}, {"start": 2168.49, "end": 2169.19, "word": " السالب", "probability": 0.8767903645833334}, {"start": 2169.19, "end": 2170.21, "word": " على", "probability": 0.64453125}, {"start": 2170.21, "end": 2170.67, "word": " الموجبة", "probability": 0.8479817708333334}], "temperature": 1.0}, {"id": 93, "seek": 218377, "start": 2171.27, "end": 2183.77, "text": "هذا اللي أنا بابنك، الهجوم من السالب على الموجب، بيصير عنده ring opening، كل هذه عبارة عن أمثلة على الموضوع بنقف عند formation of diodes", "tokens": [3224, 15730, 13672, 1829, 41850, 4724, 16758, 1863, 4117, 12399, 2423, 3224, 7435, 20498, 9154, 21136, 6027, 3555, 15844, 9673, 29245, 3555, 12399, 4724, 1829, 9381, 13546, 43242, 3224, 4875, 5193, 12399, 28242, 29538, 6225, 3555, 9640, 3660, 18871, 5551, 2304, 12984, 37977, 15844, 9673, 2407, 11242, 45367, 44945, 4587, 5172, 43242, 11723, 295, 1026, 4789], "avg_logprob": -0.2069627130240725, "compression_ratio": 1.4285714285714286, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2171.27, "end": 2171.63, "word": "هذا", "probability": 0.943115234375}, {"start": 2171.63, "end": 2171.77, "word": " اللي", "probability": 0.906982421875}, {"start": 2171.77, "end": 2172.03, "word": " أنا", "probability": 0.50244140625}, {"start": 2172.03, "end": 2172.85, "word": " بابنك،", "probability": 0.53466796875}, {"start": 2172.85, "end": 2173.29, "word": " الهجوم", "probability": 0.978759765625}, {"start": 2173.29, "end": 2173.47, "word": " من", "probability": 0.990234375}, {"start": 2173.47, "end": 2174.15, "word": " السالب", "probability": 0.711669921875}, {"start": 2174.15, "end": 2174.99, "word": " على", "probability": 0.79833984375}, {"start": 2174.99, "end": 2175.93, "word": " الموجب،", "probability": 0.87890625}, {"start": 2175.93, "end": 2176.41, "word": " بيصير", "probability": 0.9093017578125}, {"start": 2176.41, "end": 2177.03, "word": " عنده", "probability": 0.82421875}, {"start": 2177.03, "end": 2177.47, "word": " ring", "probability": 0.8056640625}, {"start": 2177.47, "end": 2178.43, "word": " opening،", "probability": 0.75732421875}, {"start": 2178.43, "end": 2178.69, "word": " كل", "probability": 0.9248046875}, {"start": 2178.69, "end": 2178.97, "word": " هذه", "probability": 0.7138671875}, {"start": 2178.97, "end": 2179.41, "word": " عبارة", "probability": 0.9918212890625}, {"start": 2179.41, "end": 2179.57, "word": " عن", "probability": 0.99365234375}, {"start": 2179.57, "end": 2180.05, "word": " أمثلة", "probability": 0.9632568359375}, {"start": 2180.05, "end": 2180.25, "word": " على", "probability": 0.81787109375}, {"start": 2180.25, "end": 2180.75, "word": " الموضوع", "probability": 0.989990234375}, {"start": 2180.75, "end": 2181.25, "word": " بنقف", "probability": 0.7232259114583334}, {"start": 2181.25, "end": 2181.55, "word": " عند", "probability": 0.64111328125}, {"start": 2181.55, "end": 2182.43, "word": " formation", "probability": 0.79638671875}, {"start": 2182.43, "end": 2183.01, "word": " of", "probability": 0.984375}, {"start": 2183.01, "end": 2183.77, "word": " diodes", "probability": 0.62841796875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2185.137, "duration_after_vad": 2119.8856249999935}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e4bc9a76feda9e6f8de77b19b7f38004d4fd2f18
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM.srt
@@ -0,0 +1,1798 @@
+1
+00:00:07,730 --> 00:00:11,930
+اليوم بنكمل إن شاء الله في موضوع الكحولات 
+
+2
+00:00:11,930 --> 00:00:19,490
+alcohols طبعًا كلكم عارفين أنه احنا بدأنا
+
+3
+00:00:19,490 --> 00:00:24,250
+كما يبدأ عادة بدراسة أي عائلة من المركبات العضوية
+
+4
+00:00:24,250 --> 00:00:30,350
+بالتعريف فيها، بتسميتها، بخواصها الفيزيائية، بطرق 
+
+5
+00:00:30,350 --> 00:00:35,810
+تحضيرها، يمكن من طرق التحضير حكينا طريقة واحدة اللي 
+
+6
+00:00:35,810 --> 00:00:41,910
+هي تعتبر طريقة تجارية وخاصة بالإيثانول اللي هي 
+
+7
+00:00:41,910 --> 00:00:46,310
+طريقة الـ fermentation أو التخمير، اتكلمنا عنها لكن
+
+8
+00:00:46,310 --> 00:00:53,450
+كطرق مختبر، الطريقة المشهورة أكثر في المختبر هي 
+
+9
+00:00:53,450 --> 00:01:02,170
+طريقة الإضافة على الـ alkenes، أنه احنا نضيف على 
+
+10
+00:01:02,170 --> 00:01:03,730
+الـ alkene ماء
+
+11
+00:01:06,030 --> 00:01:10,090
+بتكونوا تتذكروا شغلة.. بتكونوا تتذكروا شغلة أنه احنا
+
+12
+00:01:10,090 --> 00:01:16,070
+هذه الطريقة، طريقة الإضافة على الالكين أخذناها و 
+
+13
+00:01:16,070 --> 00:01:23,710
+بتمشي بثلاث طرق مختلفة اعتمادًا على نوع المتفاعل
+
+14
+00:01:23,710 --> 00:01:26,730
+اللي عندنا، طبعًا لما بنضيف على الكين بالذات لما 
+
+15
+00:01:26,730 --> 00:01:31,410
+يكون un symmetric بيصير عندنا possibility لـ Markov
+
+16
+00:01:31,410 --> 00:01:36,450
+-Nikov addition و Anti Markov-Nikov addition طبعًا 
+
+17
+00:01:36,450 --> 00:01:39,950
+حكينا احنا سابقًا أنه وقتاش بيصير الـ markovnikov's 
+
+18
+00:01:39,950 --> 00:01:45,550
+addition قولنا ممكن طريقة الإضافة في وجود الماء في 
+
+19
+00:01:45,550 --> 00:01:50,610
+وجود الحامض، والطريقة الثانية بيقول ما.. اللي هي 
+
+20
+00:01:50,610 --> 00:01:56,530
+الإضافة في وجود الـ BH3 وبعدين H2O2 والطريقة 
+
+21
+00:01:56,530 --> 00:02:02,650
+الثالثة الإضافة في وجود الـ mercury plus ميركوريك
+
+22
+00:02:02,650 --> 00:02:07,790
+أسيتيت وكل هذا الكلام واضح، وكل طريقة بتعطيني نواة
+
+23
+00:02:07,790 --> 00:02:11,650
+شكل ومواصفات، شكل هنا Markov-Nikov addition هنا 
+
+24
+00:02:11,650 --> 00:02:14,970
+Anti-Markov-Nikov addition هنا Markov-Nikov
+
+25
+00:02:14,970 --> 00:02:19,110
+addition بتفرق الأولى عن الثالثة إن هنا في
+
+26
+00:02:19,110 --> 00:02:23,930
+possibility of rearrangement كل هذا الكلام بتكونوا
+
+27
+00:02:23,930 --> 00:02:31,650
+متذكرينه لأنه شرح بالتفصيل، تفاعلات الكحولات الآن 
+
+28
+00:02:31,650 --> 00:02:38,810
+reactions of alcohols التفاعل الأول خلينا نقول نوعًا 
+
+29
+00:02:38,810 --> 00:02:44,930
+ما معاكس للتفاعل السابق.. معاكس للتفاعل السابق 
+
+30
+00:02:44,930 --> 00:02:49,990
+بمعنى أنا في الطريقة السابقة كان يكون عندي الـ keen
+
+31
+00:02:49,990 --> 00:02:57,010
+أضيف عليه ماء يصير alcohol، الآن بإمكاني الـ alcohol 
+
+32
+00:02:57,010 --> 00:03:03,730
+أنزع منه ماء يصير الـ keen واضح؟ يعني العملية يمكن أن 
+
+33
+00:03:03,730 --> 00:03:08,210
+تتم بشكل عكسي، كيف بتتم هذه العملية اللي هي بيسموها 
+
+34
+00:03:08,210 --> 00:03:13,010
+acidic dehydration، إيش يعني dehydration؟
+
+35
+00:03:13,010 --> 00:03:18,290
+dehydration يعني نزع الماء، دائمًا كلمة dehydration
+
+36
+00:03:18,290 --> 00:03:22,810
+معناها نزع الماء، وأنتم طبعًا كلكم إن شاء الله 
+
+37
+00:03:22,810 --> 00:03:28,460
+أمهات المستقبل لما يصير عندكم ولاد صغار وتبقوا 
+
+38
+00:03:28,460 --> 00:03:31,960
+تروحوا فيهم على المستشفى دائمًا بتلاقوا الأطباء 
+
+39
+00:03:31,960 --> 00:03:35,760
+بيقولوا هذا الولد عنده dehydration إيش يعني الـ
+
+40
+00:03:35,760 --> 00:03:39,940
+dehydration؟ أنه عنده جفاف.. أنه عنده جفاف لإن
+
+41
+00:03:39,940 --> 00:03:44,720
+الماء كلها طلعت منه، فبتكون تعطوه إيش؟ محلول تعويضي 
+
+42
+00:03:44,720 --> 00:03:51,040
+واضح؟ الآن الـ dehydration هذه العملية دائمًا بتتم في
+
+43
+00:03:51,040 --> 00:03:56,080
+وجود حامض و بالتسخين، العملية بتتم في وجود حامض
+
+44
+00:03:56,080 --> 00:04:00,920
+وبالتسخين، طيب لو أجينا قولنا إيش بالظبط وظيفة
+
+45
+00:04:00,920 --> 00:04:05,940
+الحامض، إيش بالظبط وظيفة الحامض، ليش أنا بدي أضيف 
+
+46
+00:04:05,940 --> 00:04:12,140
+حامض عشان أتم هذه العملية، إذا أنتم بتطلعوا لما
+
+47
+00:04:12,140 --> 00:04:17,810
+بدها تتم الـ dehydration بتطلع OH- أو اتش بلس في
+
+48
+00:04:17,810 --> 00:04:23,370
+النهاية بيطلع شكل جزء ماء، لكن الإشكالية أن الـ OH-
+
+49
+00:04:23,370 --> 00:04:28,950
+لحالها الـ OH- لحالها هذه المجموعة شايفينها هذه
+
+50
+00:04:28,950 --> 00:04:33,210
+المجموعة لو طلعت بدها تحمل إلكترونات على الأكسوجين 
+
+51
+00:04:33,210 --> 00:04:39,410
+الصغير، والأكسوجين مش قادرة أنه تحمل إلكترونات، ذرة 
+
+52
+00:04:39,410 --> 00:04:43,450
+صغيرة مش كثير بتقدر تحمل إلكترونات، إلا يجيها 
+
+53
+00:04:43,450 --> 00:04:47,090
+مساعدة خارجية، ممكن البعض منكم يقول طب ما هو في NA
+
+54
+00:04:47,090 --> 00:04:53,610
+OH مثلًا عندي NA plus OH minus، أه بس الـ OH minus
+
+55
+00:04:53,610 --> 00:04:58,560
+هنا جزء منها رايح بالتجاذب مع الـ إيش الآن A plus 
+
+56
+00:04:58,560 --> 00:05:03,600
+لكن إنه يطلع عندي OH minus لحالها مشكلة، الـ O H
+
+57
+00:05:03,600 --> 00:05:07,060
+مابتقدرش تحمل الإلكترونات، عشان إحنا متعودين في
+
+58
+00:05:07,060 --> 00:05:12,040
+الكيمياء نقول عن مجموعة الـ O H أنه is a bad leaving
+
+59
+00:05:12,040 --> 00:05:16,640
+group إيش 
+
+60
+00:05:16,640 --> 00:05:21,300
+يعني bad leaving group يعني مجموعة مغادرة سيئة مش 
+
+61
+00:05:21,300 --> 00:05:27,430
+هي بدها تطلع مابتطلعش بسهولة لازم أعمل طرق معينة
+
+62
+00:05:27,430 --> 00:05:34,250
+عشان أخلي هذه المجموعة الـ OH- تطلع، لأنها مابتقدرش
+
+63
+00:05:34,250 --> 00:05:38,450
+تحمل إلكترونات، شو هي العملية اللي بنعملها إحنا 
+
+64
+00:05:38,450 --> 00:05:42,990
+عشان نخلي الـ OH- تطلع؟ بنجي للتفاعل في الخطوة 
+
+65
+00:05:42,990 --> 00:05:48,800
+الأولى بنضيف حامض H plus، الآن الـ H plus هذا خلوه 
+
+66
+00:05:48,800 --> 00:05:52,440
+يجي يتفاعل مع زوج الإلكترونات اللي موجود عندنا هنا
+
+67
+00:05:52,440 --> 00:05:59,720
+ويعمل ماء بعد هيك، إذا صار مجموعة بدها تطلع إيش
+
+68
+00:05:59,720 --> 00:06:03,620
+هتكون المجموعة اللي بدها تطلع OH minus 
+
+69
+00:06:07,180 --> 00:06:13,120
+الـ H2O في هذه الحالة تظهر على شكل جزء متعادل، بزام
+
+70
+00:06:13,120 --> 00:06:16,280
+جزء متعادل مش حامل شحنة، مش عنده مشكلة، المشكلة وين
+
+71
+00:06:16,280 --> 00:06:23,320
+أنه تظهر مجموعة صغيرة حاملة شحنة ومش قادرة تحمل مش 
+
+72
+00:06:23,320 --> 00:06:28,120
+قادرة تحمل هذه الشحنة، ولذلك دائمًا التفاعلات تبعت 
+
+73
+00:06:28,120 --> 00:06:34,050
+الـ alcohols أول ما بدي أبدأ فيها بدي أحول الـ bad 
+
+74
+00:06:34,050 --> 00:06:39,150
+leaving group اللي هي الـ OH إلى الـ good leaving
+
+75
+00:06:39,150 --> 00:06:42,270
+group، الـ good leaving group هي الماء، كيف بتتم هذا
+
+76
+00:06:42,270 --> 00:06:47,470
+الكلام؟ من خلال إضافة الحامض، إذا عرفنا إيش وظيفة 
+
+77
+00:06:47,470 --> 00:06:51,950
+الحامض، the function of the acid is to convert the
+
+78
+00:06:51,950 --> 00:06:57,330
+bad leaving group to a good leaving group ليش هذه
+
+79
+00:06:57,330 --> 00:07:01,840
+كانت bad؟ لأنها charged، negative charge، it cannot
+
+80
+00:07:01,840 --> 00:07:04,480
+carry the negative charge، ليش هذه good living
+
+81
+00:07:04,480 --> 00:07:09,100
+group؟ لأنها neutral، لأنها متعادلة، مش حاملة، 
+
+82
+00:07:09,100 --> 00:07:11,800
+شحنة، واحد مافيش عنده مصايب، ولا واحد فيه عنده
+
+83
+00:07:11,800 --> 00:07:15,560
+مصايب، مين بيكون مرتاح أكثر؟ المتعادل، اللي مافيش
+
+84
+00:07:15,560 --> 00:07:19,140
+عنده مصايب، الآن هذه خطوة تحضيرية، إحنا 
+
+85
+00:07:19,140 --> 00:07:23,680
+مابنعتبرهاش خطوة من الـ mechanism، ليش؟ لأن الـ 
+
+86
+00:07:23,680 --> 00:07:30,690
+mechanism هي عملية حذف الماء في النهاية وتكوين الـ 
+
+87
+00:07:30,690 --> 00:07:35,850
+double bond، هل تم فيها حد في شيء لحد الآن؟ لأ بس 
+
+88
+00:07:35,850 --> 00:07:38,330
+أنا عملت الـ bad living group و الـ good living
+
+89
+00:07:38,330 --> 00:07:41,250
+group، عشانك، هذه الخطوة ليست جزء من الميكانيزم، طب
+
+90
+00:07:41,250 --> 00:07:45,130
+ها إيش الميكانيزم؟ الميكانيزم الآن لما تيجي تطلع
+
+91
+00:07:45,130 --> 00:07:50,560
+الاتش هذه لحالها بدون زوج الإلكترونات، اتش plus واضح؟
+
+92
+00:07:50,560 --> 00:07:54,340
+الـ double bond بتتحرك بهذا الشكل، بيفقد جزء الماء 
+
+93
+00:07:54,340 --> 00:07:59,520
+لاحظوا معه إيش بتكون بهذه الحالة؟ هدول حركة بتطلع
+
+94
+00:07:59,520 --> 00:08:04,820
+الـ H، الـ double bond بتتحرك، الماء كلها بتفقد بيصير
+
+95
+00:08:04,820 --> 00:08:10,080
+عند الـ alkene، زاد الـ H plus زاد الماء في النهاية
+
+96
+00:08:10,080 --> 00:08:15,050
+إيش اللي بتلاحظوا؟ أنه تم فقد الماء مظبوط ولا لأ؟ و
+
+97
+00:08:15,050 --> 00:08:19,710
+الـ H plus اللي استعملت هنا عوضت طلعت ولا لأ؟ إذا
+
+98
+00:08:19,710 --> 00:08:24,090
+إيش بنقول عن الـ H plus هنا اللي دخلت في التفاعل و
+
+99
+00:08:24,090 --> 00:08:28,950
+عوضت طلعت catalyst، H plus is a catalyst هم لاحظين
+
+100
+00:08:28,950 --> 00:08:37,400
+هنا catalyst عامل مساعد فقط، إيه جت عملت وظيفة معينة 
+
+101
+00:08:37,400 --> 00:08:41,180
+ساعدت الـ Bad Living Group أنها تطلع وبعدين عودت
+
+102
+00:08:41,180 --> 00:08:44,600
+رجعت H Plus؟ الآن هذه اللي رجعت ممكن تبدأ تعمل
+
+103
+00:08:44,600 --> 00:08:49,860
+تفاعل جديد ولا لأ؟ أكيد، ولذلك لما أنا بدي أضيف على
+
+104
+00:08:49,860 --> 00:08:55,840
+التفاعل H Plus بضيفه بكمية مكافئة ولا بكمية قليلة؟
+
+105
+00:08:55,840 --> 00:09:00,280
+بكمية قليلة لأن أنا بتشتغل الشغلة، بتعود ترجع، 
+
+106
+00:09:00,280 --> 00:09:04,550
+بتشتغل الشغلة، بتعود ترجع، واضح؟ زي على سبيل 
+
+107
+00:09:04,550 --> 00:09:08,770
+المثال، لو تتخيلوا مدينتين، فكرة الـ Catalyst، لما
+
+108
+00:09:08,770 --> 00:09:13,510
+يكون عندي خمس سيارات بينقلوا ناس طول النهار، رايح
+
+109
+00:09:13,510 --> 00:09:18,690
+جاي، هم يمثلوا Catalyst، وسيلة بتعمل عملية إيش 
+
+110
+00:09:18,690 --> 00:09:22,230
+نقل، بس مش لازم لو بدي أنقل ألف بني آدم يكون عنده 
+
+111
+00:09:22,970 --> 00:09:27,310
+ألف سيارة، خمسة بيقوموا المهم رايح جاي رايح جاي، وهذا 
+
+112
+00:09:27,310 --> 00:09:30,610
+نفس الشيء، الـ H plus بتطوف بتصير، هذا good living
+
+113
+00:09:30,610 --> 00:09:35,190
+group بتطلع وبترجع الـ H plus بتطلع من جديد وهكذا 
+
+114
+00:09:35,190 --> 00:09:40,970
+واضح، هذا اللي هو التفاعل الأول اللي بنسميه acidic
+
+115
+00:09:40,970 --> 00:09:45,970
+dehydration، ليش قلنا acidic لأنه بنستعمل الـ 
+
+116
+00:09:45,970 --> 00:09:52,200
+catalyst الـ H plus اللي هو الحامض واضح؟ حتى تتم
+
+117
+00:09:52,200 --> 00:09:58,300
+عملية الـ dehydration والتحول إلى الالكين لازم 
+
+118
+00:09:58,300 --> 00:10:07,160
+نستعمل أسلوب، هنا بدنا بس تنويه صغير أنه نفس هذا 
+
+119
+00:10:07,160 --> 00:10:12,600
+التفاعل مثلًا هنا الإيثانول بيصير إيثيلين، هذا التفاعل 
+
+120
+00:10:12,600 --> 00:10:18,200
+شوية حساس لدرجة الحرارة بمعنى إذا كانت تسخين لـ 180
+
+121
+00:10:18,200 --> 00:10:22,240
+درجة مئوية بتصير عملية الـ dehydration، بس إذا بنسخن
+
+122
+00:10:22,240 --> 00:10:28,940
+عند 140 درجة مئوية بيصير ناتج ثاني اللي هو تكوين الـ
+
+123
+00:10:28,940 --> 00:10:34,160
+ether، الـ ether هذه مجموعة الـ ether، فعند الـ 140
+
+124
+00:10:34,160 --> 00:10:37,140
+درجة مئوية هيصير عند الـ ether اللي هو الـ ether o
+
+125
+00:10:38,720 --> 00:10:42,400
+بناخده بالفصل الثامن، تكوين الـ Ether لما ناخد 
+
+126
+00:10:42,400 --> 00:10:45,940
+تكوين الـ Ether من الـ Ethanol هنقول نفس التفاعل 
+
+127
+00:10:45,940 --> 00:10:51,680
+بنسخن وجود H Plus لكن عند 140 درجة مئوية، الآن هنا
+
+128
+00:10:51,680 --> 00:10:58,560
+عشان التفاعل حساس لدرجة الحرارة لازم تحفظوها،
+
+129
+00:10:58,560 --> 00:11:02,520
+واضح؟ يعني عند 180 درجة مئوية بيصير عند الـ Alkyl 
+
+130
+00:11:02,520 --> 00:11:06,680
+عند 140 درجة مئوية بيصير عند الـ Ether 
+
+131
+00:11:10,370 --> 00:11:16,550
+طبعًا هذا الـ alcohol اللي احنا كتبناها أنه عبارة عن 
+
+132
+00:11:16,550 --> 00:11:22,970
+الـ primary alcohol، ملاحظين CH2OH CH2OH، الميكانيزم
+
+133
+00:11:22,970 --> 00:11:27,150
+هذا بخطوة واحدة تطلع الـ H هذا تلف هذا تطلع، شو 
+
+134
+00:11:27,150 --> 00:11:33,230
+سميناها سابقًا إحنا E2 ميكانيزم، عملنا زيها بالظبط 
+
+135
+00:11:33,230 --> 00:11:40,590
+للـ elimination للـ HX برضه لما أخذنا الـ mechanisms of 
+
+136
+00:11:40,590 --> 00:11:46,110
+elimination في chapter 6 قلنا هما نوعين E2 و E1 
+
+137
+00:11:46,110 --> 00:11:50,210
+mechanism، الآن هنا الـ mechanism اللي هي الـ E2 الـ
+
+138
+00:11:50,210 --> 00:11:55,690
+one step mechanism واللي بتصير عادة مع الـ primary 
+
+139
+00:11:55,690 --> 00:12:01,170
+واضح، طيب لو انتقلنا للـ tertiary على طول هتلاحظوا 
+
+140
+00:12:01,170 --> 00:12:05,170
+إن أنتم متذاكرين إن مع الـ tertiary الـ mechanism
+
+141
+00:12:05,170 --> 00:12:10,040
+المشهورة اللي هي الـ E1 ميكانيزم، والـ E1 ميكانيزم 
+
+142
+00:12:10,040 --> 00:12:15,120
+عبارة عن كم step؟ two steps، الخطوة الأولى تكوين
+
+143
+00:12:15,120 --> 00:12:21,640
+الكربوكاتيون، والخطوة الثانية فقد البروتون وتكوين 
+
+144
+00:12:21,640 --> 00:12:27,360
+الـ double bond، خلينا نشوف كيف تتم هذه العملية أول
+
+145
+00:12:27,360 --> 00:12:32,340
+شيء لابد من الخطوة التحضيرية في كل الأحوال أن هذا 
+
+146
+00:12:32,340 --> 00:12:37,560
+الـ OH إيش ما لها؟ bad leaving group، لازم أعمل
+
+147
+00:12:37,560 --> 00:12:42,940
+تفاعل في وجود حامض عشان يحول الـ OH إلى H2O، الآن
+
+148
+00:12:42,940 --> 00:12:46,320
+صارت الـ bad leaving group و الـ good leaving 
+
+149
+00:12:46,320 --> 00:12:49,980
+group، هذا لسه مش خطوة في الميكانيزم، هذا مش خطوة في
+
+150
+00:12:49,980 --> 00:12:54,220
+الميكانيزم، من وين بتبدأ الميكانيزم؟ بتبدأ بفقد
+
+151
+00:12:54,220 --> 00:12:59,560
+الماء لما تفقد الماء بتكون عندك كاربوكتايون، هذا 
+
+152
+00:12:59,560 --> 00:13:05,860
+الكاربوكتايون، الأيون الموجب، أثبت شيء بيكون مع الـ 
+
+153
+00:13:05,860 --> 00:13:09,700
+tertiary وهنا احنا بنشتغل على الـ tertiary ولذلك
+
+154
+00:13:09,700 --> 00:13:13,500
+هذا بيكون stable الكاربوكتايون، أثبت شيء مع الـ 
+
+155
+00:13:13,500 --> 00:13:18,220
+tertiary هذا الكاربوكتايون الآن بعد ذلك بيفقد H 
+
+156
+00:13:18,220 --> 00:13:20,840
+plus في الخطوة الثانية وبتيجي الـ double bond ده
+
+157
+00:13:20,840 --> 00:13:24,820
+بتتحرك هنا، بتكون الـ alkene، زي الـ H plus مرة ثانية 
+
+158
+00:13:24,820 --> 00:13:30,180
+بتلاحظوا إن الـ H plus بدأنا فيها وطلعت ثاني، إذا 
+
+159
+00:13:30,180 --> 00:13:37,330
+الـ H plus is a catalyst لاحظوا التفاعل خطوتين
+
+160
+00:13:37,330 --> 00:13:43,270
+بسيطات، الخطوة الأولى فقد الماء وتكوين Carbocation 
+
+161
+00:13:43,270 --> 00:13:49,030
+الخطوة الثانية فقد البروتون اللي هو في الأساس تم 
+
+162
+00:13:49,030 --> 00:13:54,930
+إضافته لعملية catalys للتفاعل وتكوين الألكين، هذه 
+
+163
+00:13:54,930 --> 00:13:58,850
+الميكانيزم اللي بـ two steps، الـ first step و الـ 
+
+164
+00:13:58,850 --> 00:14:04,210
+second step هي اللي سميناها إحنا E1 ميكانيزم، إذا لو 
+
+165
+00:14:04,210 --> 00:14:08,530
+بدنا نقول كيف بتتم عملية الـ elimination من الـ
+
+166
+00:14:08,530 --> 00:14:15,030
+primary alcohols بـ E2 ميكانيزم، من tertiary
+
+167
+00:14:15,030 --> 00:14:15,950
+alcohols
+
+168
+00:14:25,790 --> 00:14:30,950
+في الـ alkenes بتيجينا نفس المشكلة اللي تواجهنا
+
+169
+00:14:30,950 --> 00:14:35,490
+فيها بالـ alkyl halides، إذا بتذكروا لما كنا نقول
+
+170
+00:14:35,490 --> 00:14:41,97
+
+201
+00:17:13,610 --> 00:17:19,790
+مثال لو أخذنا هذا الـ cyclopentanol اللي حامل OH
+
+202
+00:17:19,790 --> 00:17:25,690
+وهنا CH3 وهنا فيه H's الآن بالتأكيد الـ OH بدأت تطلع
+
+203
+00:17:26,300 --> 00:17:32,140
+هذا مش موضوع نقاش لكن السؤال مع أي هيدروجين مع أي 
+
+204
+00:17:32,140 --> 00:17:36,200
+بروتون بدها تطلع في إمكانية تطلع مع الهيدروجين
+
+205
+00:17:36,200 --> 00:17:40,340
+اللي هنا وفي إمكانية تطلع مع واحدة من هدولة اللي
+
+206
+00:17:40,340 --> 00:17:45,700
+هنا واضح؟ الآن إذا طلعت مع هيدروجين من هدولة هتكون
+
+207
+00:17:45,700 --> 00:17:50,200
+لأي مركب؟ المركب الثاني اللي هناك وإذا طلعت الـ OH
+
+208
+00:17:50,200 --> 00:17:53,580
+مع هيدروجين من هنا هتكون الـ double bond في هذا
+
+209
+00:17:53,580 --> 00:17:58,140
+الموقع لما نيجي نحلل which is the major product أنه
+
+210
+00:17:58,140 --> 00:18:02,720
+هو الناتج الأساسي الـ more substituted اتطلعولي هنا
+
+211
+00:18:02,720 --> 00:18:06,460
+كم Substitution عندي وهنا كم Substitution عندي
+
+212
+00:18:06,460 --> 00:18:12,680
+هنا في عندي هي الـ double bond هي دي متصلة بـ carbon
+
+213
+00:18:12,680 --> 00:18:16,240
+وهي دي بـ carbon وهي دي بـ carbon واحدة منهم بس
+
+214
+00:18:16,240 --> 00:18:22,950
+hydrogen إذا كم Substitution عندي هنا؟ ثلاثة
+
+215
+00:18:22,950 --> 00:18:26,130
+من الهيدروجين راحوا، ضلت واحدة، إذا عندي ثلاث 
+
+216
+00:18:26,130 --> 00:18:31,030
+إبدالات، لأن المركب غير المبدل اللي يحتوي عليه،
+
+217
+00:18:31,030 --> 00:18:35,690
+أربعة هيدروجين، واضح؟ هنا الآن كم Substitution؟
+
+218
+00:18:35,690 --> 00:18:39,730
+عندي هذه كم وهذه؟ هنا هيدروجين وهيدروجين ما فيش
+
+219
+00:18:39,730 --> 00:18:43,190
+إبدال هنا، اثنين، اثنين، إذا which is the major
+
+220
+00:18:43,190 --> 00:18:47,770
+product؟ the first one is the major product واضح؟
+
+221
+00:18:47,770 --> 00:18:51,370
+عشانك لو أنا بدي أجيب لكم أكمل المعادلة هذه أو هذه
+
+222
+00:18:51,370 --> 00:18:56,570
+وأكتب لكم اعطوني الـ major product تعملوا الـ
+
+223
+00:18:56,570 --> 00:19:01,910
+Substitution يعني تعملوا المركب الـ major product
+
+224
+00:19:01,910 --> 00:19:07,050
+يكون الـ more substituted واضح؟ الناتج الأكثر إبدال
+
+225
+00:19:07,050 --> 00:19:10,730
+هو الناتج الأساسي
+
+226
+00:19:17,840 --> 00:19:22,120
+النوع الثاني من التفاعلات، لاحظوا كل التفاعل الأول
+
+227
+00:19:22,120 --> 00:19:26,960
+اللي أخذناه حذف الـ OH مع H لتكوين الـ alkene اللي
+
+228
+00:19:26,960 --> 00:19:33,120
+سميناه عملية dehydration، نزع الماء، الآن التفاعل
+
+229
+00:19:33,120 --> 00:19:41,180
+الثاني هو تفاعل إبدال، أن أبدل الـ OH بـ X، الـ X 
+
+230
+00:19:41,180 --> 00:19:49,670
+يعني Cl أو Br أو I واضح؟ substitution reaction كيف
+
+231
+00:19:49,670 --> 00:19:53,670
+بتتم عملية الـ substitution reaction؟ كيف هذا الـ OH
+
+232
+00:19:53,670 --> 00:20:00,170
+بدي أخليها تصير X؟ واضح؟ ببساطة، لو كان عندي
+
+233
+00:20:00,170 --> 00:20:04,790
+tertiary alcohol لو كان عندي tertiary alcohol بأجي
+
+234
+00:20:04,790 --> 00:20:10,380
+بفاعله مع الـ HCl  الـ tertiary alcohol بفاعله مع الـ 
+
+235
+00:20:10,380 --> 00:20:15,580
+HCl بتطلع الـ OH ومع الـ H هذا بتعمل ماء وبيجي
+
+236
+00:20:15,580 --> 00:20:21,400
+عندي هنا Cl الآن لو جينا قلنا إيش الميكانيزم اللي
+
+237
+00:20:21,400 --> 00:20:27,240
+بدو يتم في هذا التفاعل؟ واحدة
+
+238
+00:20:27,240 --> 00:20:33,920
+تعطينا وصفيا هذا التفاعل كيف بدو يتم؟ على كم خطوة
+
+239
+00:20:41,140 --> 00:20:47,160
+بدي يكون فيه خطوتين أساسيات في الميكانيزم وقولوا
+
+240
+00:20:47,160 --> 00:20:55,360
+واحدة خطوة تحضيرية إيش الخطوة التحضيرية؟ تحويل الـ O
+
+241
+00:20:55,360 --> 00:21:00,160
+H إلى good leaving group الـ bad leaving group إلى 
+
+242
+00:21:00,160 --> 00:21:04,760
+group إذا في الأول هذا لما تكتبوا الميكانيزم له
+
+243
+00:21:05,590 --> 00:21:12,030
+بتقولوا زائد H+ بتصير هذا H2O بعدين الخطوة
+
+244
+00:21:12,030 --> 00:21:18,550
+الأولى الـ H2O تفقد بتصير carbocation
+
+245
+00:21:18,550 --> 00:21:24,970
+بعدين الـ Cl بتيجي بتتفاعل بيصير عنده اللي هو الـ
+
+246
+00:21:24,970 --> 00:21:30,410
+alkyl chloride واضح؟
+
+247
+00:21:30,410 --> 00:21:37,420
+إذا كم خطوة عندي؟ مرة ثانية مني تعيد لي أهم اثنتين
+
+248
+00:21:37,420 --> 00:21:41,680
+أساسيات الميكانيزم؟ زائد خطوة تحضيرية في الأول دائما
+
+249
+00:21:41,680 --> 00:21:46,380
+كل تفاعلات الكحول وأنتم غامضين الـ OH الـ
+
+250
+00:21:46,380 --> 00:21:51,140
+OH هذا بدها تصير H2O بعد أن الـ H2O تفقد بتعطيني
+
+251
+00:21:51,140 --> 00:21:54,720
+carbocation هاي الـ first step الـ carbocation مع الـ
+
+252
+00:21:54,720 --> 00:22:00,360
+Cl بيعطيني المركب تبعي هذه الميكانيزم اللي احنا
+
+253
+00:22:00,360 --> 00:22:06,240
+سميناها SN1 mechanism الآن أنا بتكون تتذكروا شغلة
+
+254
+00:22:06,240 --> 00:22:11,260
+كمان طالما أنه أنا بقول أنه بتكون عندي carbocation
+
+255
+00:22:11,260 --> 00:22:15,140
+طالما أنا بقول بتكون عندي carbocation في الخطوة
+
+256
+00:22:15,140 --> 00:22:20,100
+الأولى، إذا متوقع في النتائج أن يصير عندي إيش؟
+
+257
+00:22:21,340 --> 00:22:24,420
+rearrangement الكربوكاتيون من مواصفاته الـ
+
+258
+00:22:24,420 --> 00:22:27,780
+rearrangement يعني لو كان عندي مثلا secondary
+
+259
+00:22:27,780 --> 00:22:31,680
+كربوكاتيون ممكن يعمل rearrangement ويصير tertiary
+
+260
+00:22:31,680 --> 00:22:37,340
+كربوكاتيون more stable وأحيانا primary كربوكاتيون
+
+261
+00:22:37,340 --> 00:22:41,100
+وبيصير tertiary كربوكاتيون أو secondary
+
+262
+00:22:41,100 --> 00:22:45,690
+كربوكاتيون واضح؟ كل الكلام اللي أخذته على الـ SN1
+
+263
+00:22:45,690 --> 00:22:49,590
+mechanism برضه بنطبق هنا لكن أنتم لما درستوا
+
+264
+00:22:49,590 --> 00:22:52,150
+chapter 6 كان عندكم الـ halide كانت بالخطوة
+
+265
+00:22:52,150 --> 00:22:56,670
+الأولى تفقد الـ X وتكون carbocation الآن هنا بتفقد
+
+266
+00:22:56,670 --> 00:23:02,890
+الماء وتكون carbocation والتفاعل بيمشي الآن
+
+267
+00:23:02,890 --> 00:23:04,930
+بالنسبة لـ primary
+
+268
+00:23:07,730 --> 00:23:13,770
+الحقيقة لـ Primary Alcohols لو جينا نفعلها مع الـ
+
+269
+00:23:13,770 --> 00:23:21,050
+HCl لوحدها، ما بيصيرش تفاعل، واضح؟ الـ Primary
+
+270
+00:23:21,050 --> 00:23:28,510
+Alcohols مع HCl لوحدها، ما بيصيرش تفاعل من أساسه،
+
+271
+00:23:28,510 --> 00:23:34,410
+تفاعل بطيء جدا الآن إيش بيعملوا عشان يصير التفاعل
+
+272
+00:23:34,410 --> 00:23:41,750
+الـ primary alcohol بياخدوها مع الـ HCL وبيحطوا عليه
+
+273
+00:23:41,750 --> 00:23:48,990
+كمان catalyst زنك كلوريد وكمان حرارة وكل هذا
+
+274
+00:23:48,990 --> 00:23:52,430
+لسه بيعطيني التفاعل مش كثير مقنع يعني بياخد عدة
+
+275
+00:23:52,430 --> 00:23:59,650
+ساعات تسخين لما تتم عملية الإبدال لـ الـ OH بها لوجد
+
+276
+00:23:59,650 --> 00:24:03,610
+وطبعا هنا طالما هذا primary إذا الميكانيزم اللي
+
+277
+00:24:03,610 --> 00:24:08,110
+بتتوقعوها SN2 mechanism الميكانيزم اللي بتتوقعها
+
+278
+00:24:08,110 --> 00:24:12,290
+SN2 mechanism واليود هنا بتتفاعل أسرع من الـ bromine
+
+279
+00:24:12,290 --> 00:24:17,670
+أسرع من الـ chlorine واضح؟ لأن اليود بده يهاجم واليود
+
+280
+00:24:17,670 --> 00:24:21,300
+stronger and nucleophile than bromine which is
+
+281
+00:24:21,300 --> 00:24:27,220
+stronger than chlorine وبناء على ذلك هذه يعني أو
+
+282
+00:24:27,220 --> 00:24:32,720
+التفاعل بهذا الشكل رغم أنه ممكن عبر تسخين لعدة
+
+283
+00:24:32,720 --> 00:24:38,360
+ساعات لكنه ليس الطريقة المثلى لتحويل الـ primary
+
+284
+00:24:38,360 --> 00:24:44,470
+alcohols إلى الـ alkyl halides في طرق أفضل منه واضح؟
+
+285
+00:24:44,470 --> 00:24:47,910
+إذا لو أنا بدي آجي أسألكم في الامتحان أنه الـ
+
+286
+00:24:47,910 --> 00:24:52,710
+primary alcohols react with HCl forming alkyl
+
+287
+00:24:52,710 --> 00:24:58,550
+halides، الجواب لأ، مع الـ HCl لحالها لأ، طب مع الـ
+
+288
+00:24:58,550 --> 00:25:04,620
+HCl وzinc chloride وحرارة بصير لكن يعتبر تفاعل
+
+289
+00:25:04,620 --> 00:25:09,320
+بطيء إذا إيش الـ best method؟ إيش أفضل طريقة لتحويل
+
+290
+00:25:09,320 --> 00:25:11,880
+الـ primary alcohol هي مثلا أنا عندنا واحد اثنين
+
+291
+00:25:11,880 --> 00:25:17,220
+ثلاث بروبانول هذا المركب بروبانول هذا primary
+
+292
+00:25:17,220 --> 00:25:22,720
+alcohol بنجي بنفعلها مع الـ PCl3 فوسفورس تراي كلوريد
+
+293
+00:25:22,720 --> 00:25:27,920
+مثلا أو فوسفورس تراي برومايد هذا التفاعل خصوصا للـ
+
+294
+00:25:27,920 --> 00:25:34,230
+primary alcohol عقولها بتحب محل الـ OACA إذن أنهي أفضل
+
+295
+00:25:34,230 --> 00:25:38,290
+طريقة؟ أنه الـ Primary Alcohol لما بدي أعمل منه
+
+296
+00:25:38,290 --> 00:25:43,630
+alkyl halide أفعله مع الـ PCl3 الـ Phosphorus
+
+297
+00:25:43,630 --> 00:25:48,330
+trichloride لكن بنجي نقول Primary Alcohol مع PCl3
+
+298
+00:25:48,330 --> 00:25:54,250
+لحالها ما بتحولها لـ alkyl
+
+299
+00:25:54,250 --> 00:25:57,530
+halide هذه الطريقة اللي هي الـ reaction with
+
+300
+00:25:57,530 --> 00:26:02,420
+phosphorus chloride في طريقة ثانية كمان بنفعلها مع
+
+301
+00:26:02,420 --> 00:26:07,840
+مادة بنسميها thionyl chloride thionyl chloride الـ
+
+302
+00:26:07,840 --> 00:26:13,580
+thionyl chloride مادة مشهورة SOCl2 صيغتها واضحة
+
+303
+00:26:13,580 --> 00:26:18,560
+S رابطة O Cl Cl S O Cl2 thionyl chloride
+
+304
+00:26:18,560 --> 00:26:23,360
+برضه هذا التفاعل ممتاز بيحول الـ primary alcohols
+
+305
+00:26:23,360 --> 00:26:26,760
+إلى الـ alkyl halide
+
+306
+00:26:27,940 --> 00:26:32,200
+Alkyl Halides can be prepared from primary
+
+307
+00:26:32,200 --> 00:26:36,820
+alcohols or can be best prepared يعني أفضل شيء by
+
+308
+00:26:36,820 --> 00:26:43,800
+reaction with PCl3 or thionyl chloride واضح؟ إذا 
+
+309
+00:26:43,800 --> 00:26:49,300
+أفضل طريقتين يا PCl3 يا thionyl chloride في حالة
+
+310
+00:26:49,300 --> 00:26:53,360
+إن أنا بدي أحول الـ primary alcohol إلى
+
+311
+00:26:57,020 --> 00:27:02,360
+الـ alkyl halide هنا بتجينا شغلة أنه احنا أخذنا في عندنا
+
+312
+00:27:02,360 --> 00:27:09,300
+tertiary alcohol OH بـ HCl بنحولها إلى halide الـ
+
+313
+00:27:09,300 --> 00:27:16,100
+primary مع الـ PCl3 والـ SOCl2 الآن بنجي لـ لو
+
+314
+00:27:16,100 --> 00:27:22,200
+كان عندي phenolic compound يعني ArOH فينول أو مشتقة
+
+315
+00:27:22,200 --> 00:27:28,410
+فينول واضح؟ الأوقات شوية موجودة على بنزين أو طواقي 
+
+316
+00:27:28,410 --> 00:27:33,790
+الـ Ar capital small R بالغلط مكتوبة مش مشكلة Ar
+
+317
+00:27:33,790 --> 00:27:43,930
+هيك الـ Ar كمجموعة مش capital الـ ArOH لو فعلناها
+
+318
+00:27:43,930 --> 00:27:50,150
+مع HCl مع HCl وزنك مع PCl3 مع SOCl2 كله
+
+319
+00:27:50,150 --> 00:27:55,290
+ما بتتفعلش ولا بتتحول إلى الـ halide الـ aryl halide
+
+320
+00:27:57,090 --> 00:28:01,110
+إذن لاحظوا معي لو بدأت أسألكم أنا أقولها الـ 
+
+321
+00:28:01,110 --> 00:28:04,890
+phenols can be converted to aryl halides by
+
+322
+00:28:04,890 --> 00:28:08,830
+heating it with HCl or HCl with zinc chloride or
+
+323
+00:28:08,830 --> 00:28:11,930
+by reacting it with phosphorus trichloride or with
+
+324
+00:28:11,930 --> 00:28:16,150
+thionyl chloride كله لأ الـ phenols أبدا من
+
+325
+00:28:16,150 --> 00:28:25,180
+هالناحية مسكرة واضح؟ ما بتتحول الـ phenols إلى aryl
+
+326
+00:28:25,180 --> 00:28:30,140
+halides ما بتتحول الفينول إلى أريل هيلايدز طبعا
+
+327
+00:28:30,140 --> 00:28:33,300
+احنا الحمد لله لو احتجنا أريل هيلايدز في اننا طرق
+
+328
+00:28:33,300 --> 00:28:37,600
+ثانية لتحضيره يعني لما أكون أنا بدي كلور بنزين
+
+329
+00:28:37,600 --> 00:28:42,000
+بلازم ان اجي أحوله من فينول ما تحضير الفينول اساسا
+
+330
+00:28:42,000 --> 00:28:46,080
+صعب أنا بأخذ البنزين كلور وألمونيوم كلوريدز
+
+331
+00:28:46,080 --> 00:28:47,620
+متذكرين المعادلة؟
+
+332
+00:28:50,330 --> 00:28:53,410
+بقدر أحضره لـ chlorobenzene لكن بطريقة ثانية بس
+
+333
+00:28:53,410 --> 00:28:57,950
+بالتأكيد مش من خلال الفينول مش من خلال تحويل الـ 
+
+334
+00:28:57,950 --> 00:29:06,330
+OH تاعة الفينول إلى كلوريد أبنيجى لا
+
+335
+00:29:06,330 --> 00:29:13,230
+تفاعل ثالث للـ alcohol لحد الآن الوضع تحت السيطرة
+
+336
+00:29:13,230 --> 00:29:19,150
+أخذنا تفاعلات الـ dehydration نزع الماء النوع 
+
+337
+00:29:19,150 --> 00:29:24,860
+الثاني الإبدال لأن الـ OH نحط مكانها X التفاعل
+
+338
+00:29:24,860 --> 00:29:30,620
+الثالث الأكسدة oxidation التفاعل الثالث الأكسدة
+
+339
+00:29:30,620 --> 00:29:37,460
+واضح؟ طبعا الأكسدة دائما مرتبطة في ذهنها بإيش؟
+
+340
+00:29:37,460 --> 00:29:42,900
+بالأكسجين بالأكسجين يعني جزء من معنى الأكسدة بغض 
+
+341
+00:29:42,900 --> 00:29:47,460
+النظر عن المعنى المتعلق بالتأكسد فقد إلكترونات
+
+342
+00:29:47,460 --> 00:29:51,900
+والاختزال اكتساب إلكترونات في أساس المفهوم كانت
+
+343
+00:29:51,900 --> 00:29:53,980
+الأكسدة تعني
+
+344
+00:29:56,110 --> 00:30:02,750
+زيادة في الروابط مع إيش؟ مع الأكسجين الأكسدة كانت
+
+345
+00:30:02,750 --> 00:30:07,450
+تعني زيادة في الروابط مع الأكسجين بمعنى كل ما أنا
+
+346
+00:30:07,450 --> 00:30:11,970
+بزيد الروابط مع الأكسجين كأن أنا بعمل إيش؟ أكسدة 
+
+347
+00:30:11,970 --> 00:30:17,070
+عشان هيك لو بعيدا عن هذه تخيلنا المركبات الآتية
+
+348
+00:30:17,070 --> 00:30:23,130
+لو جيت تخيلت أنا الإيثانول CH3 CH2 OH مع كم
+
+349
+00:30:23,130 --> 00:30:29,380
+أكسجين متحد مع واحدة، مظبوط ولا لا؟ الآن لو شيلت H
+
+350
+00:30:29,380 --> 00:30:36,340
+و H من هنا، سيصبح CH3CHO OH صار مع كم أكسجين من
+
+351
+00:30:36,340 --> 00:30:40,500
+التحت؟ مع اثنتين، إذا أنا صارت عندي عملية
+
+352
+00:30:40,500 --> 00:30:46,770
+oxidation، لو شيلت الـ H بدي يصير عندي C double bond
+
+353
+00:30:46,770 --> 00:30:52,630
+O أو H هنا الكربون مع كم أكسجين متحدة؟ ثلاث لو
+
+354
+00:30:52,630 --> 00:30:56,250
+أتيت تعمل التكسير إضافي فيك، أصبحت منها وطلع C
+
+355
+00:30:56,250 --> 00:30:59,270
+double bond O أو C double bond O ثاني أكسيد 
+
+356
+00:30:59,270 --> 00:31:06,250
+الكربون، كم؟ رابط، أربع، إذا أنا عملية تحويل
+
+357
+00:31:06,250 --> 00:31:12,810
+الإيثانول لهذا المركب اللي هو الـ acetaldehyde لهذا
+
+358
+00:31:12,810 --> 00:31:16,590
+المركب اللي هو acetic acid لهذا المركب اللي هو
+
+359
+00:31:16,590 --> 00:31:21,650
+ثاني أكسيد الكربون حافظين هم دول المركبات إيثانول
+
+360
+00:31:21,650 --> 00:31:27,710
+وهنا acetaldehyde 
+
+361
+00:31:27,710 --> 00:31:37,370
+وبعدين هذا acetic acid وبعدين هذا carbon dioxide
+
+362
+00:31:37,370 --> 00:31:43,190
+ثاني أكسيد الكربون قصة كبيرة هذه ولا لأ؟ عارفين أن
+
+363
+00:31:43,190 --> 00:31:53,090
+بتصير هذه القصة الكبيرة؟ مين بتعرف فيكم؟ في جسم
+
+364
+00:31:53,090 --> 00:32:03,690
+البني آدم أي بني آدم؟ لأ مش احنا لأ بجسم
+
+365
+00:32:03,690 --> 00:32:09,590
+الكفار مش المسلمين احنا هنا معظمنا مسلمين هذي
+
+366
+00:32:09,590 --> 00:32:14,030
+بتصير عند الناس اللي بيشربوا الخمرة اللي بيشربوا
+
+367
+00:32:14,030 --> 00:32:18,570
+الخمرة بياخذوا على جسمهم إيثانول مظبوط ولا لأ؟
+
+368
+00:32:19,630 --> 00:32:23,590
+الآن هذا الإيثانول بيعمل تأثير الإسكار تبعه كم
+
+369
+00:32:23,590 --> 00:32:27,250
+يأخذ تأثير الإسكار لحد ما يروح حسب الكمية اللي
+
+370
+00:32:27,250 --> 00:32:31,430
+الناس شاربينها يوم نص يوم ست سبع ثمان تسع
+
+371
+00:32:31,430 --> 00:32:34,470
+عشر ساعات إيش بيصير في هالست سبع ثمان تسع
+
+372
+00:32:34,470 --> 00:32:39,030
+عشر ساعات اللي بنقول البني آدم فيها drunk سكران
+
+373
+00:32:39,030 --> 00:32:43,930
+ومش قادر يسيطر على
+
+401
+00:34:56,280 --> 00:35:03,200
+جريمة قتل التهم فيها شخص بيشرب .. بيشرب كحول و
+
+402
+00:35:03,200 --> 00:35:07,900
+إجوا يحققوا المحققين طبعا برضه في بلد إسلامي بس
+
+403
+00:35:07,900 --> 00:35:13,500
+الشخص بيشرب كحول للأسف إيش عملوا؟ ضالهم يستنوا يوم
+
+404
+00:35:13,500 --> 00:35:17,040
+كامل مع العلم إن كل دقيقة التحقيق بتفيدهم لحد ما
+
+405
+00:35:17,040 --> 00:35:20,810
+البني آدم يصحى اللي بدهم يحققوا معه من الكحول اللي
+
+406
+00:35:20,810 --> 00:35:25,090
+شربينه ما فيش عندهم إبرة ولا حبوب دواء يعطوها له 
+
+407
+00:35:25,090 --> 00:35:30,410
+خلال ربع ساعة تضيع تأثير الكحول من جسمه العلم في
+
+408
+00:35:30,410 --> 00:35:35,230
+هذه المنطقة ما زال بيشتغل على رتم جسم الإنسان رتم
+
+409
+00:35:35,230 --> 00:35:42,410
+جسم الإنسان على البطيء رتم جسم الإنسان على البطيء
+
+410
+00:35:42,410 --> 00:35:49,750
+واضح؟ هنا خلّينا فلسفيا نحكي كمان عن شغلة ثانية لو
+
+411
+00:35:49,750 --> 00:35:56,870
+إجينا للإيثانول، الإيثانول من وين جاي؟ إحنا أخذنا
+
+412
+00:35:56,870 --> 00:36:02,510
+في تحضير الإيثانول، sugar، لو الإيثانول مكوّن
+
+413
+00:36:02,510 --> 00:36:08,690
+المزعج في الخمر، من الـ sugar، تمام؟ الإيثانول مش 
+
+414
+00:36:08,690 --> 00:36:12,990
+بيجي من السكريات وتخميرها، بيخمروا العنب وبيخمروا
+
+415
+00:36:12,990 --> 00:36:16,850
+القصب وبيخمروا العسل وبيخمروا المولاس، مظبوط ولا
+
+416
+00:36:16,850 --> 00:36:22,530
+لأ؟ والخمور كلها من الانجاص والفواكه والطمر اللي
+
+417
+00:36:22,530 --> 00:36:26,350
+بيعرف كلها الأشياء، الآن هذه بتحطنا بالحقيقة عند
+
+418
+00:36:26,350 --> 00:36:32,090
+شغلة مهمة في الدنيا، أن الأشياء وليست بتاريخها،
+
+419
+00:36:32,090 --> 00:36:36,390
+المهم في الواقع إيش موجود للإنسان اليوم، يعني
+
+420
+00:36:36,390 --> 00:36:40,670
+كإننا بنحكي عن اللي اتعلمتوها إذا اتعلمتوا أنتم،
+
+421
+00:36:40,670 --> 00:36:44,050
+ما أعرفش ممكن ما اتعلمتوش، إيش معنى state function؟
+
+422
+00:36:45,880 --> 00:36:48,200
+دالة الحالة، إيش اللي بنقصده إحنا بالـ state
+
+423
+00:36:48,200 --> 00:36:52,480
+function أو دالة الحالة؟ دالة الحالة اللي هي الشيء
+
+424
+00:36:52,480 --> 00:36:55,640
+اللي باعتمد على الوضع الآن، ما باعتمدش على
+
+425
+00:36:55,640 --> 00:36:59,340
+التاريخ، ما باعتمدش على الـ history، المهم إيش هو
+
+426
+00:36:59,340 --> 00:37:04,320
+الآن؟ تماما زي ما أجي مثلا أنا ألاقي ولد صغير
+
+427
+00:37:04,320 --> 00:37:08,620
+بيلعب في مية، okay؟ ممكن الولد الصغير اللي بيلعب
+
+428
+00:37:08,620 --> 00:37:11,840
+في المية، هيك ساطل صغير في مية وجاعة بيلعب وبحط
+
+429
+00:37:11,840 --> 00:37:17,940
+على وشه أمه من حد ما تشوفه تغلي بالدنيا صراخ؟ شوفي
+
+430
+00:37:17,940 --> 00:37:23,950
+شو مالك؟ بتقول والله المي كانت بتغلي والولد عنده
+
+431
+00:37:23,950 --> 00:37:27,550
+انحراج المية كانت بتغلي قبل تلات ساعات بس هالجيتها
+
+432
+00:37:27,550 --> 00:37:31,390
+المية ما بتغليش والمية هالجيت باردة والولد ببساطة
+
+433
+00:37:31,390 --> 00:37:35,490
+الآن هل أثر التاريخ إن هذي المية قبل تلات ساعات
+
+434
+00:37:35,490 --> 00:37:39,490
+كانت تغلي على حالة المية الآن؟ عرفت إيش معنى
+
+435
+00:37:39,490 --> 00:37:43,410
+state function؟ إن أنا المهم عندي الحالة الآن يعني
+
+436
+00:37:43,410 --> 00:37:46,810
+تجيني طالبة تقولي والله أنا في توجيه الأولى على
+
+437
+00:37:46,810 --> 00:37:50,470
+القطاع ما له مالك وما له مال القطاع المهم في الـ
+
+438
+00:37:50,470 --> 00:37:54,800
+organic جايبة خمسة من تلاتين state function هل
+
+439
+00:37:54,800 --> 00:37:58,680
+الأولى على القطاع أبتشفعلها إنه كانت الأولى على
+
+440
+00:37:58,680 --> 00:38:02,520
+القطاع اتجوزت وانشغلت وعندها ميد شغلة وبتجيب
+
+441
+00:38:02,520 --> 00:38:05,480
+تطبخ وبعدين بدأت تاخد تلاتين من تلاتين لأنها كانت
+
+442
+00:38:05,480 --> 00:38:08,980
+الأولى على القطاع دي state إيش؟ function المهم
+
+443
+00:38:08,980 --> 00:38:12,720
+عندي الحالة الآن الآن انتبهوا معايا كيف بتصير
+
+444
+00:38:12,720 --> 00:38:17,160
+الأمور من ناحية شرعية السكر حلال
+
+445
+00:38:19,360 --> 00:38:24,580
+العنب حلال، الانجاص حلال، التفاح حلال، صار خمرة
+
+446
+00:38:24,580 --> 00:38:29,020
+صار إيثانول حرام، الآن ما حدا ييجي يقول يا أخي
+
+447
+00:38:29,020 --> 00:38:32,580
+انجليز شجرة مباركة، يا أخي طمر، الرسول عليه الصلاة
+
+448
+00:38:32,580 --> 00:38:36,240
+والسلام كان يفطر على الطمر، كان يفطر على الطمر، بس
+
+449
+00:38:36,240 --> 00:38:42,030
+مش لما يصير مش لما يصير خمرة، واضح؟ كان يفطر على
+
+450
+00:38:42,030 --> 00:38:47,210
+التمر، مش على التمر اللي اتخمر، مظبوط ولا لأ؟ إذا
+
+451
+00:38:47,210 --> 00:38:54,890
+هنا الـ sugar حلال، والفواكه حلال، الكحولات، حرام،
+
+452
+00:38:54,890 --> 00:38:58,310
+الالدهايدات، مرحلة بين هدول الاثنين، بعدين تعالولي
+
+453
+00:38:58,310 --> 00:39:03,050
+على الخل الخل
+
+454
+00:39:03,050 --> 00:39:09,460
+حلال، طب هو من وين جاي؟ من الخمر مظبوط ولا لأ؟
+
+455
+00:39:09,460 --> 00:39:14,020
+الخمر تتحول إلى خل يعني الناس اللي بيعملوا خل
+
+456
+00:39:14,020 --> 00:39:16,400
+التفاح في البيت اللي بيجيبوا التفاح وبيسكروا عليه
+
+457
+00:39:16,400 --> 00:39:19,740
+في الجزازة وشوية بالشمس هو اللي بيصير إن التفاح
+
+458
+00:39:19,740 --> 00:39:23,320
+الحلال بيصير خمرة حرام والخمرة الحرام بتصير خل
+
+459
+00:39:23,320 --> 00:39:27,960
+حلال وأفضل ما أكلتم الخل لأنه غذاء كامل وفي
+
+460
+00:39:27,960 --> 00:39:32,530
+أحاديث نبوية في الخل واضح؟ إذا إحنا قاعدين بنتحول
+
+461
+00:39:32,530 --> 00:39:36,650
+من حلال لحرام لحلال بهمني إيش الـ .. إيش اللي أنا
+
+462
+00:39:36,650 --> 00:39:42,130
+الآن قاعد بتعامل معه، هل بهمني تاريخه؟ آه، إذا
+
+463
+00:39:42,130 --> 00:39:50,930
+الخل هنا كيف أصبح حلالا؟ بالشريعة بيستعمله مصطلح،
+
+464
+00:39:50,930 --> 00:39:56,790
+إيش بيقولوا عنه؟ طهورة بالتحول
+
+465
+00:39:58,210 --> 00:40:04,070
+طهورة بإيش؟ بالتحول، هذه عملية التحول من الإيثانول
+
+466
+00:40:04,070 --> 00:40:08,850
+للخل، هذه عملية تطهير لما تاخدوا التطهير في كتاب
+
+467
+00:40:08,850 --> 00:40:12,570
+دراسات في الفقه، بتاخدوا التطهير بالماء، وفي
+
+468
+00:40:12,570 --> 00:40:18,650
+التطهير بإيش؟ بالتحول، إن المادة إذا تحولت من مادة
+
+469
+00:40:18,650 --> 00:40:24,530
+ناجسة إلى مادة طاهرة، خلاص، اتغير تركيبها
+
+470
+00:40:24,530 --> 00:40:30,110
+الكيميائي، بدنا نضل نقول أنا حرام؟ ولذلك الخمر
+
+471
+00:40:30,110 --> 00:40:37,170
+الناجس يصبح خلاً طاهراً وعصير الفواكه الطاهر يصبح
+
+472
+00:40:37,170 --> 00:40:42,930
+خمراً ناجساً أنا بتعامل مع اللي موجود عندي
+
+473
+00:40:42,930 --> 00:40:47,670
+وبالمناسبة هنا بتدخل كمان قضية شرعية ثانية لأنه
+
+474
+00:40:47,670 --> 00:40:51,470
+لها علاقة .. لها علاقة بالكيمياء وكتير الناس اللي
+
+475
+00:40:51,470 --> 00:40:56,200
+بنقشوا هالأمور هذه الناس اللي بعيشوا في أوروبا و
+
+476
+00:40:56,200 --> 00:41:00,830
+كويس أن تفهموها لأنها في الأساس قضية علمية إنه
+
+477
+00:41:00,830 --> 00:41:05,170
+بيجيبوا على الجيلاتين الجيلاتين بدخل في تحضير كتير
+
+478
+00:41:05,170 --> 00:41:10,730
+من الأطعمة ومنها الكيك وأشياء كثيرة الآن من وين
+
+479
+00:41:10,730 --> 00:41:14,750
+بيجيبوا الجيلاتين هنا المشكلة الجيلاتين في أنواع
+
+480
+00:41:14,750 --> 00:41:18,590
+منه بيجيبوا من النباتات من التفاح من غيرها زي
+
+481
+00:41:18,590 --> 00:41:23,950
+البكتين بمعنى هناك جيلاتين بأصل نباتي وهناك
+
+482
+00:41:23,950 --> 00:41:27,850
+جيلاتين بأصل حيواني الجيلاتين اللي بأصل حيواني
+
+483
+00:41:27,850 --> 00:41:31,840
+ممكن يجينا من غل العظام يعني لو أخذت عظام بقر أو
+
+484
+00:41:31,840 --> 00:41:35,660
+غيره أو غيرها غلق مع بعض التحولات الكيميائية في
+
+485
+00:41:35,660 --> 00:41:39,560
+نهاية بالتهب جيلاتين الآن الإشكالية إنه في أوروبا
+
+486
+00:41:39,560 --> 00:41:45,080
+العظام اللي مشهورة أكثر هي عظام إيش؟ الخنزير وبناء
+
+487
+00:41:45,080 --> 00:41:49,440
+على ذلك جزء كبير من الجيلاتين اللي موجود عندهم
+
+488
+00:41:49,440 --> 00:41:56,880
+طالع من وين؟ طالع من الخنزير لكن على رأي كثير من
+
+489
+00:41:56,880 --> 00:42:01,790
+العلماء ومنهم الدكتور القرضاوي وشيخ حسام الدين
+
+490
+00:42:01,790 --> 00:42:06,790
+عفانا والمقالات كثيرة وموجودة بأنه قد حصل على هذه
+
+491
+00:42:06,790 --> 00:42:10,410
+المواد حتى أخذناها جيلاتين ما أخذناهاش زي ما هي ما
+
+492
+00:42:10,410 --> 00:42:13,610
+أخذناهاش عظم عملنا تفاعلات كيميائية لحد ما حصلنا
+
+493
+00:42:13,610 --> 00:42:17,910
+على الجيلاتين فالجيلاتين بيعتبروا قد طهر بالتحول
+
+494
+00:42:17,910 --> 00:42:23,330
+حتى لو كان من إيش؟ حتى لو كان من عظام الخنزير وهذا
+
+495
+00:42:23,330 --> 00:42:28,880
+الدارج في الفتوى واضح؟ الجيلاتين حتى لو كان من عظام
+
+496
+00:42:28,880 --> 00:42:34,740
+الخنزير فهو قد طهر بالتحول على رأي كثير جداً،
+
+497
+00:42:34,740 --> 00:42:38,720
+والغالب من العلماء اللي ناقشوا هذا الموضوع والنقاش
+
+498
+00:42:39,360 --> 00:42:44,000
+فقه موجود كثير ومنشور في كتب ومجلات وفي فتوى على
+
+499
+00:42:44,000 --> 00:42:47,600
+الانترنت أفهمتوا إيش يعني التطهر بالتحول؟ لأنه
+
+500
+00:42:47,600 --> 00:42:51,940
+المادة تغيرت أنا عملت عليه تفاعلات، غيرته واضح أنا
+
+501
+00:42:51,940 --> 00:42:55,420
+عملت عليه تفاعلات، ما أخذتهوش زي ما هو زي ما عملت على
+
+502
+00:42:55,420 --> 00:43:00,450
+الكحول تفاعلات خلاه في الآخر إيش؟ خلاً الآن هذه
+
+503
+00:43:00,450 --> 00:43:06,010
+العملية عملية إيش؟ أكسدة المحاضرة الجاية بنعود
+
+504
+00:43:06,010 --> 00:43:09,490
+نحكي عن الأكسدة من ناحية كيميائية يعني هنا إحنا
+
+505
+00:43:09,490 --> 00:43:14,530
+اتكلمنا عن الأكسدة من ناحية ثقافية خليني أقول
+
+506
+00:43:14,530 --> 00:43:19,750
+كثقافة تفهموا إيش يعني الأكسدة؟ الآن كعوامل مؤكسدة
+
+507
+00:43:19,750 --> 00:43:21,970
+وكيميائية في المحاضرة الجاية إن شاء الله
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..77889bbbd1be0cf619369afc5403b5a6373dade6
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_raw.json
@@ -0,0 +1 @@
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"seek": 17951, "start": 155.63, "end": 179.51, "text": "التفاعل الأول خلينا نقول نوعا ما معاكس للتفاعل السابق .. معاكس للتفاعل السابق بمعنى أنا في الطريقة السابقة كان يكون عندى ال keen أضيف عليه ما يصير alcohol، الآن بإمكاني ال alcohol أنزع منه ما يصير ال keen", "tokens": [6027, 2655, 5172, 995, 30241, 16247, 12610, 16490, 1211, 9957, 995, 8717, 39648, 8717, 45367, 995, 19446, 20449, 995, 4117, 3794, 24976, 2655, 5172, 995, 30241, 21136, 16758, 4587, 4386, 20449, 995, 4117, 3794, 24976, 2655, 5172, 995, 30241, 21136, 16758, 4587, 4724, 2304, 3615, 1863, 7578, 41850, 8978, 41950, 16572, 28671, 21136, 16758, 28671, 25961, 7251, 30544, 43242, 7578, 2423, 20297, 5551, 11242, 33911, 47356, 19446, 7251, 9381, 13546, 7658, 12399, 6024, 48506, 4724, 28814, 2304, 41361, 1829, 2423, 7658, 14739, 11622, 3615, 9154, 3224, 19446, 7251, 9381, 13546, 2423, 20297], "avg_logprob": -0.13113239760039955, "compression_ratio": 1.9277777777777778, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 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" كلكوا", "probability": 0.7810872395833334}, {"start": 202.49, "end": 202.57, "word": " ان", "probability": 0.849609375}, {"start": 202.57, "end": 202.75, "word": " شاء", "probability": 0.94775390625}, {"start": 202.75, "end": 202.81, "word": " الله", "probability": 0.96630859375}, {"start": 202.81, "end": 203.25, "word": " أمهات", "probability": 0.92333984375}, {"start": 203.25, "end": 204.01, "word": " المستقبل", "probability": 0.990966796875}, {"start": 204.01, "end": 204.79, "word": " لما", "probability": 0.934326171875}, {"start": 204.79, "end": 205.07, "word": " يصير", "probability": 0.9765625}, {"start": 205.07, "end": 205.41, "word": " عندكم", "probability": 0.8681640625}, {"start": 205.41, "end": 205.89, "word": " ولاد", "probability": 0.885498046875}, {"start": 205.89, "end": 206.51, "word": " صغار", "probability": 0.95068359375}], "temperature": 1.0}, {"id": 8, "seek": 22550, "start": 207.92, "end": 225.5, "text": "وتبقوا تروحوا فيهم على المستشفى دائما بتلاقوا الأطباء بيقولوا هذا الولد عنده dehydration إيش يعني ال dehydration؟ انه عنده جفاف .. انه عنده جفاف لإن الميه كلها طلعت منه فبتكون تعطوه إيش؟ محليل تعوضية واضح؟", "tokens": [35473, 3555, 4587, 14407, 6055, 32887, 5016, 14407, 8978, 16095, 15844, 9673, 14851, 8592, 5172, 7578, 11778, 16373, 15042, 39894, 15040, 4587, 14407, 16247, 9566, 3555, 16606, 4724, 1829, 39648, 14407, 23758, 2423, 12610, 3215, 43242, 3224, 32102, 2405, 11933, 1829, 8592, 37495, 22653, 2423, 32102, 2405, 22807, 16472, 3224, 43242, 3224, 10874, 5172, 31845, 4386, 16472, 3224, 43242, 3224, 10874, 5172, 31845, 5296, 28814, 1863, 9673, 1829, 3224, 28242, 11296, 23032, 1211, 34268, 9154, 3224, 6156, 3555, 2655, 30544, 37279, 9566, 2407, 3224, 11933, 1829, 8592, 22807, 3714, 5016, 20292, 1211, 37279, 2407, 11242, 10632, 4032, 46958, 5016, 22807], "avg_logprob": -0.15663675742574257, "compression_ratio": 1.6923076923076923, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 207.92, "end": 208.46, "word": "وتبقوا", 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"probability": 0.95654296875}, {"start": 286.33, "end": 286.51, "word": " في", "probability": 0.84619140625}, {"start": 286.51, "end": 287.09, "word": " NA", "probability": 0.38427734375}, {"start": 287.09, "end": 287.45, "word": " OH", "probability": 0.69287109375}, {"start": 287.45, "end": 288.43, "word": " مثلا", "probability": 0.983642578125}, {"start": 288.43, "end": 289.49, "word": " عندي", "probability": 0.7066650390625}, {"start": 289.49, "end": 289.75, "word": " NA", "probability": 0.77587890625}, {"start": 289.75, "end": 290.31, "word": " plus", "probability": 0.283447265625}, {"start": 290.31, "end": 291.45, "word": " OH", "probability": 0.41455078125}, {"start": 291.45, "end": 292.11, "word": " minus", "probability": 0.89990234375}, {"start": 292.11, "end": 292.37, "word": " أه", "probability": 0.59735107421875}, {"start": 292.37, "end": 292.57, "word": " بس", "probability": 0.957763671875}, {"start": 292.57, "end": 292.71, "word": " ال", "probability": 0.92822265625}, {"start": 292.71, "end": 293.05, "word": " OH", "probability": 0.49462890625}, {"start": 293.05, "end": 293.61, "word": " minus", "probability": 0.9599609375}, {"start": 293.61, "end": 293.85, "word": " هنا", "probability": 0.68310546875}, {"start": 293.85, "end": 294.29, "word": " جزء", "probability": 0.99658203125}, {"start": 294.29, "end": 294.81, "word": " منها", "probability": 0.99072265625}, {"start": 294.81, "end": 295.47, "word": " رايح", "probability": 0.9903971354166666}, {"start": 295.47, "end": 296.25, "word": " بالتجاذب", "probability": 0.987890625}, {"start": 296.25, "end": 296.43, "word": " مع", "probability": 0.990234375}, {"start": 296.43, "end": 296.61, "word": " ال", "probability": 0.79541015625}, {"start": 296.61, "end": 296.99, "word": " إيش", "probability": 0.7665201822916666}], "temperature": 1.0}, {"id": 12, "seek": 32216, "start": 297.64, "end": 322.16, "text": "الان A plus لكن انه يطلع عندي OH minus لحالها مشكلة ال O H مابتقدرش تحمل الإلكترونات عشانك احنا متعودين في الكيميا نقول عن مجموعة ال O H انه is a bad leaving group ايش يعني bad leaving group يعني مجموعة مغادرة سيئة مش هي بده تطلع", "tokens": [6027, 7649, 316, 1804, 44381, 16472, 3224, 7251, 9566, 1211, 3615, 43242, 1829, 13931, 3175, 5296, 5016, 6027, 11296, 37893, 28820, 3660, 2423, 422, 389, 3714, 16758, 2655, 28543, 2288, 8592, 6055, 35571, 1211, 33688, 23275, 2655, 2288, 11536, 9307, 6225, 8592, 7649, 4117, 1975, 5016, 8315, 44650, 3615, 23328, 9957, 8978, 33251, 32640, 25528, 8717, 39648, 18871, 3714, 7435, 2304, 2407, 27884, 2423, 422, 389, 16472, 3224, 307, 257, 1578, 5012, 1594, 1975, 1829, 8592, 37495, 22653, 1578, 5012, 1594, 37495, 22653, 3714, 7435, 2304, 2407, 27884, 3714, 17082, 18513, 25720, 8608, 1829, 19986, 3660, 37893, 39896, 47525, 3224, 6055, 9566, 1211, 3615], "avg_logprob": -0.19017857369922456, "compression_ratio": 1.6425339366515836, "no_speech_prob": 0.0, "words": [{"start": 297.64, "end": 298.06, "word": "الان", "probability": 0.84228515625}, {"start": 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"probability": 0.953125}, {"start": 308.82, "end": 309.0, "word": " O", "probability": 0.60791015625}, {"start": 309.0, "end": 309.36, "word": " H", "probability": 0.9580078125}, {"start": 309.36, "end": 310.06, "word": " انه", "probability": 0.714599609375}, {"start": 310.06, "end": 310.34, "word": " is", "probability": 0.67431640625}, {"start": 310.34, "end": 310.72, "word": " a", "probability": 0.974609375}, {"start": 310.72, "end": 311.3, "word": " bad", "probability": 0.94677734375}, {"start": 311.3, "end": 312.04, "word": " leaving", "probability": 0.78076171875}, {"start": 312.04, "end": 312.74, "word": " group", "probability": 0.96142578125}, {"start": 312.74, "end": 316.64, "word": " ايش", "probability": 0.5863037109375}, {"start": 316.64, "end": 316.86, "word": " يعني", "probability": 0.958984375}, {"start": 316.86, "end": 317.14, "word": " bad", "probability": 0.88720703125}, {"start": 317.14, "end": 317.46, "word": " leaving", "probability": 0.8828125}, {"start": 317.46, "end": 318.24, "word": " group", "probability": 0.98095703125}, {"start": 318.24, "end": 318.84, "word": " يعني", "probability": 0.8291015625}, {"start": 318.84, "end": 319.64, "word": " مجموعة", "probability": 0.97822265625}, {"start": 319.64, "end": 320.62, "word": " مغادرة", "probability": 0.991943359375}, {"start": 320.62, "end": 321.16, "word": " سيئة", "probability": 0.9798583984375}, {"start": 321.16, "end": 321.3, "word": " مش", "probability": 0.92431640625}, {"start": 321.3, "end": 321.42, "word": " هي", "probability": 0.87353515625}, {"start": 321.42, "end": 321.62, "word": " بده", "probability": 0.5606689453125}, {"start": 321.62, "end": 322.16, "word": " تطلع", "probability": 0.9686279296875}], "temperature": 1.0}, {"id": 13, "seek": 34391, "start": 322.95, "end": 343.91, "text": "مابتطلعش بسهولة لازم اعمل طرق معينة عشان اخلي هذه المجموعة ال OH- تطلع لانها مابتقدرش تحمل إلكترونات شو هي العملية اللي بنعملها احنا عشان نخلي ال OH- تطلع بنجي للتفاعل في الخطوة الأولى بنضيف", 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ميه بعد هيك اذا صار مجموعة بدها تطلع ايش هتكون المجموعة اللى بدها تطلع OH minus", "tokens": [5016, 10943, 11242, 389, 1804, 2423, 7649, 2423, 389, 1804, 23758, 16490, 1211, 2407, 3224, 7251, 7435, 7578, 7251, 2655, 5172, 995, 30241, 20449, 30767, 29245, 2423, 6027, 4117, 2655, 2288, 11536, 9307, 13672, 7578, 3714, 29245, 23328, 43242, 8315, 34105, 4032, 7251, 25957, 1211, 3714, 1829, 3224, 39182, 39896, 4117, 1975, 15730, 20328, 9640, 3714, 7435, 2304, 2407, 27884, 47525, 11296, 6055, 9566, 1211, 3615, 1975, 1829, 8592, 8032, 2655, 30544, 9673, 7435, 2304, 2407, 27884, 13672, 7578, 47525, 11296, 6055, 9566, 1211, 3615, 13931, 3175], "avg_logprob": -0.24360795386812903, "compression_ratio": 1.6896551724137931, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 344.1, "end": 344.92, "word": "حامض", "probability": 0.76171875}, {"start": 344.92, "end": 345.7, "word": " H", "probability": 0.443115234375}, {"start": 345.7, "end": 346.16, "word": " plus", "probability": 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اللي بدو يتم في هذا التفاعل واحدة تعطينا وصفيا هذا التفاعل كيف بدو يتم على كام خطوة", "tokens": [6027, 39184, 38726, 29104, 7658, 4724, 5172, 30241, 3224, 20449, 2423, 39184, 389, 9966, 39894, 9566, 1211, 3615, 2423, 39184, 13931, 4032, 20449, 2423, 39184, 389, 23758, 39894, 25957, 1211, 3714, 1829, 3224, 4032, 4724, 1829, 7435, 1829, 43242, 34105, 12855, 6024, 48506, 45164, 10874, 1829, 8315, 12174, 12610, 8315, 11933, 1829, 8592, 9673, 1829, 41361, 1829, 11622, 2304, 13672, 1829, 47525, 2407, 7251, 39237, 8978, 23758, 16712, 5172, 995, 30241, 36764, 24401, 3660, 37279, 9566, 1829, 8315, 4032, 9381, 5172, 25528, 23758, 16712, 5172, 995, 30241, 9122, 33911, 47525, 2407, 7251, 39237, 15844, 9122, 10943, 16490, 9566, 2407, 3660], "avg_logprob": -0.2883663271913434, "compression_ratio": 1.714975845410628, "no_speech_prob": 0.0, "words": [{"start": 1207.62, "end": 1207.92, "word": "الـ", "probability": 0.494140625}, {"start": 1207.92, "end": 1208.44, "word": " tertiary", "probability": 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{"start": 1255.36, "end": 1255.9, "word": " H", "probability": 0.642578125}, {"start": 1255.9, "end": 1256.5, "word": " minus", "probability": 0.57958984375}, {"start": 1256.5, "end": 1256.84, "word": " ال", "probability": 0.8662109375}, {"start": 1256.84, "end": 1257.12, "word": " bad", "probability": 0.64990234375}, {"start": 1257.12, "end": 1257.6, "word": " leaving", "probability": 0.65478515625}, {"start": 1257.6, "end": 1258.2, "word": " group", "probability": 0.97021484375}, {"start": 1258.2, "end": 1258.54, "word": " إلى", "probability": 0.5830078125}, {"start": 1258.54, "end": 1259.68, "word": " good", "probability": 0.62255859375}, {"start": 1259.68, "end": 1260.16, "word": " leaving", "probability": 0.890625}, {"start": 1260.16, "end": 1260.54, "word": " group", "probability": 0.9794921875}, {"start": 1260.54, "end": 1260.84, "word": " إذا", "probability": 0.5888671875}, {"start": 1260.84, "end": 1261.06, "word": " في", "probability": 0.828125}, {"start": 1261.06, "end": 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{"start": 1271.49, "end": 1272.03, "word": " الخطوة", "probability": 0.873779296875}, {"start": 1272.03, "end": 1272.39, "word": " الأولى", "probability": 0.9640299479166666}, {"start": 1272.39, "end": 1273.43, "word": " الـH2O", "probability": 0.69697265625}, {"start": 1273.43, "end": 1274.11, "word": " تفقد", "probability": 0.9041341145833334}, {"start": 1274.11, "end": 1274.87, "word": " بتصير", "probability": 0.8811848958333334}, {"start": 1274.87, "end": 1278.55, "word": " Carbocation", "probability": 0.5598958333333334}, {"start": 1278.55, "end": 1279.17, "word": " بعدين", "probability": 0.7275390625}, {"start": 1279.17, "end": 1279.65, "word": " الـCl", "probability": 0.7639973958333334}, {"start": 1279.65, "end": 1280.13, "word": " بتيجي", "probability": 0.76812744140625}, {"start": 1280.13, "end": 1281.07, "word": " بتتفاعل", "probability": 0.89365234375}, {"start": 1281.07, "end": 1282.03, "word": " بيصير", "probability": 0.8673095703125}, {"start": 1282.03, "end": 1282.63, 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0.737548828125}], "temperature": 1.0}, {"id": 104, "seek": 260196, "start": 2579.73, "end": 2601.97, "text": "الآن هذه العملية عملية إيش؟ أكسدة المحاضرة الجاية بنعود نحكي عن الأكسدة من ناحية كيميائية يعني هنا إحنا اتكلمنا عن الأكسدة من ناحية ثقافية خليني أقول كثقافة تفهموا إيش يعني الأكسدة؟ الآن كعوامل مؤكسدة وكيمية في المحاضرة الجاية إن شاء الله", "tokens": [6027, 148, 48506, 29538, 18863, 42213, 10632, 6225, 42213, 10632, 11933, 1829, 8592, 22807, 5551, 4117, 3794, 41891, 9673, 5016, 46958, 25720, 25724, 995, 10632, 44945, 3615, 23328, 8717, 5016, 4117, 1829, 18871, 16247, 4117, 3794, 41891, 9154, 8717, 39319, 10632, 9122, 32640, 1829, 16373, 10632, 37495, 22653, 34105, 11933, 5016, 8315, 1975, 2655, 4117, 19528, 8315, 18871, 16247, 4117, 3794, 41891, 9154, 8717, 39319, 10632, 38637, 4587, 31845, 10632, 16490, 1211, 9957, 1829, 5551, 39648, 9122, 12984, 4587, 31845, 3660, 6055, 5172, 16095, 14407, 11933, 1829, 8592, 37495, 22653, 16247, 4117, 3794, 41891, 22807, 6024, 48506, 9122, 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{"start": 2590.71, "end": 2591.25, "word": " الأكسدة", "probability": 0.9906005859375}, {"start": 2591.25, "end": 2591.43, "word": " من", "probability": 0.9951171875}, {"start": 2591.43, "end": 2592.19, "word": " ناحية", "probability": 0.990234375}, {"start": 2592.19, "end": 2593.65, "word": " ثقافية", "probability": 0.9957275390625}, {"start": 2593.65, "end": 2594.09, "word": " خليني", "probability": 0.8126220703125}, {"start": 2594.09, "end": 2594.53, "word": " أقول", "probability": 0.96142578125}, {"start": 2594.53, "end": 2595.75, "word": " كثقافة", "probability": 0.92783203125}, {"start": 2595.75, "end": 2596.27, "word": " تفهموا", "probability": 0.927490234375}, {"start": 2596.27, "end": 2596.49, "word": " إيش", "probability": 0.96875}, {"start": 2596.49, "end": 2596.83, "word": " يعني", "probability": 0.958984375}, {"start": 2596.83, "end": 2598.29, "word": " الأكسدة؟", "probability": 0.85830078125}, {"start": 2598.29, "end": 2598.67, "word": " الآن", "probability": 0.781982421875}, {"start": 2598.67, "end": 2599.27, "word": " كعوامل", "probability": 0.97900390625}, {"start": 2599.27, "end": 2599.75, "word": " مؤكسدة", "probability": 0.94912109375}, {"start": 2599.75, "end": 2600.31, "word": " وكيمية", "probability": 0.860107421875}, {"start": 2600.31, "end": 2600.61, "word": " في", "probability": 0.9560546875}, {"start": 2600.61, "end": 2601.15, "word": " المحاضرة", "probability": 0.996826171875}, {"start": 2601.15, "end": 2601.49, "word": " الجاية", "probability": 0.8453776041666666}, {"start": 2601.49, "end": 2601.67, "word": " إن", "probability": 0.5947265625}, {"start": 2601.67, "end": 2601.85, "word": " شاء", "probability": 0.970703125}, {"start": 2601.85, "end": 2601.97, "word": " الله", "probability": 0.96923828125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2603.7465, "duration_after_vad": 2505.8231249999935}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c976362be721fa6eeeef28168571b72b334f50d0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_raw.srt
@@ -0,0 +1,2028 @@
+1
+00:00:07,730 --> 00:00:11,930
+اليوم بنكمل ان شاء الله في موضوع الكحولات ال
+
+2
+00:00:11,930 --> 00:00:19,490
+alcohols طبعا كلكوا عارفين انه احنا بدأنا
+
+3
+00:00:19,490 --> 00:00:24,250
+كما يبدأ عادة بدراسة اي عائلة من المراكبات الأضوية
+
+4
+00:00:24,250 --> 00:00:30,350
+بالتعريف فيها بتسميتها بخواصها الفيزيائية بطرق
+
+5
+00:00:30,350 --> 00:00:35,810
+تحضيرها يمكن من طرق التحضير حكينا طريقة واحدة اللي
+
+6
+00:00:35,810 --> 00:00:41,910
+هي تعتبرطريقة تجارية و خاصة بالإيثانول اللي هي
+
+7
+00:00:41,910 --> 00:00:46,310
+طريقة ال fermentation أو التخمير اتكلمنا عنها لكن
+
+8
+00:00:46,310 --> 00:00:53,450
+كطرق مختبر الطريقة المشهورة اكثر في المختبر هي
+
+9
+00:00:53,450 --> 00:01:02,170
+طريقة الإضافة على الalkenes انه احنا نضيف على
+
+10
+00:01:02,170 --> 00:01:03,730
+الalkene ميه
+
+11
+00:01:06,030 --> 00:01:10,090
+بتكون تتذكروا شغلة .. بتكون تتذكروا شغلة أنه احنا
+
+12
+00:01:10,090 --> 00:01:16,070
+هذه الطريقة طريقة الإضافة على الالكين أخدناها و
+
+13
+00:01:16,070 --> 00:01:23,710
+بتمشي بتلت طرق مختلفة اعتمادا على نوع المتفاعل
+
+14
+00:01:23,710 --> 00:01:26,730
+اللي عندنا طبعا لما بنضيف على الكين بالذات لما
+
+15
+00:01:26,730 --> 00:01:31,410
+يكون un symmetric بيصير عندنا possibility ل Markov
+
+16
+00:01:31,410 --> 00:01:36,450
+-Nikov addition و Anti Markov-Nikov additionطبعا
+
+17
+00:01:36,450 --> 00:01:39,950
+حكينا احنا سابقا انه وقتاش بيصير ال markovnikov's
+
+18
+00:01:39,950 --> 00:01:45,550
+addition قولنا ممكن طريقة الإضافة في وجود الميه في
+
+19
+00:01:45,550 --> 00:01:50,610
+وجود الحامض و الطريقة التانية بيقول ما .. اللي هي
+
+20
+00:01:50,610 --> 00:01:56,530
+الإضافة في وجود ال BH3 و بعدين H2O2 و الطريقة
+
+21
+00:01:56,530 --> 00:02:02,650
+التالتة الإضافة في وجود ال mercury plus ميركوريك
+
+22
+00:02:02,650 --> 00:02:07,790
+أسيتيت و كل هذا الكلام واضحوكل طريقة بتعطيني نواة
+
+23
+00:02:07,790 --> 00:02:11,650
+شكل ومواصفات شكل هنا Markov-Nikov addition هنا
+
+24
+00:02:11,650 --> 00:02:14,970
+Anti-Markov-Nikov addition هنا Markov-Nikov
+
+25
+00:02:14,970 --> 00:02:19,110
+addition بتفرق الأولى عن التالتى ان هنا في
+
+26
+00:02:19,110 --> 00:02:23,930
+possibility of rearrangement كل هذا الكلام بتكونوا
+
+27
+00:02:23,930 --> 00:02:31,650
+متذكرينه لأنه شرح بالتفصيل تفاعلات الكحولات الان
+
+28
+00:02:31,650 --> 00:02:38,810
+reactions of alcoholsالتفاعل الأول خلينا نقول نوعا
+
+29
+00:02:38,810 --> 00:02:44,930
+ما معاكس للتفاعل السابق .. معاكس للتفاعل السابق
+
+30
+00:02:44,930 --> 00:02:49,990
+بمعنى أنا في الطريقة السابقة كان يكون عندى ال keen
+
+31
+00:02:49,990 --> 00:02:57,010
+أضيف عليه ما يصير alcohol، الآن بإمكاني ال alcohol
+
+32
+00:02:57,010 --> 00:03:03,730
+أنزع منه ما يصير ال keenواضح؟ يعني العملية يمكن أن
+
+33
+00:03:03,730 --> 00:03:08,210
+تتم بشكل عكسي كيف بتتم هذه العملية اللي هي بيسموها
+
+34
+00:03:08,210 --> 00:03:13,010
+acidic dehydration اش يعني dehydration؟
+
+35
+00:03:13,010 --> 00:03:18,290
+dehydration يعني نزع الماء دائما كلمة dehydration
+
+36
+00:03:18,290 --> 00:03:22,810
+معناها نزع الماء وانتوا طبعا كلكوا ان شاء الله
+
+37
+00:03:22,810 --> 00:03:28,460
+أمهات المستقبل لما يصير عندكم ولاد صغاروتبقوا
+
+38
+00:03:28,460 --> 00:03:31,960
+تروحوا فيهم على المستشفى دائما بتلاقوا الأطباء
+
+39
+00:03:31,960 --> 00:03:35,760
+بيقولوا هذا الولد عنده dehydration إيش يعني ال
+
+40
+00:03:35,760 --> 00:03:39,940
+dehydration؟ انه عنده جفاف .. انه عنده جفاف لإن
+
+41
+00:03:39,940 --> 00:03:44,720
+الميه كلها طلعت منه فبتكون تعطوه إيش؟ محليل تعوضية
+
+42
+00:03:44,720 --> 00:03:51,040
+واضح؟الان ال dehydration هذه العملية دائما بتتم في
+
+43
+00:03:51,040 --> 00:03:56,080
+وجود حامض وبالتسخين العملية بتتم في وجود حامض
+
+44
+00:03:56,080 --> 00:04:00,920
+وبالتسخين طيب لو اجينا قولنا ايش بالظبط وظيفة
+
+45
+00:04:00,920 --> 00:04:05,940
+الحامض ايش بالظبط وظيفة الحامض ليش انا بدي اضيف
+
+46
+00:04:05,940 --> 00:04:12,140
+حامض عشان اتم هذه العملية اذا انتوا بتطلعوا لما
+
+47
+00:04:12,140 --> 00:04:17,810
+بدوا يتم ال dehydration بتطلع OH-أو اتش بلاس في
+
+48
+00:04:17,810 --> 00:04:23,370
+النهاية بيطلع شكل جزء ماء لكن الإشكالية أن الـ OH-
+
+49
+00:04:23,370 --> 00:04:28,950
+لحالها الـ OH- لحالها هذه المجموعة شايفينها هذه
+
+50
+00:04:28,950 --> 00:04:33,210
+المجموعة لو طلعت بده تحمل إلكترونات على الأكسوجين
+
+51
+00:04:33,210 --> 00:04:39,410
+الصغير والأكسوجين مش قدرة أنه يحمل إلكتروناتذرة
+
+52
+00:04:39,410 --> 00:04:43,450
+صغيرة مش كتير بتقدر تحمل إلكترونات إلا يجيها
+
+53
+00:04:43,450 --> 00:04:47,090
+مساعدة خارجية ممكن البعض منكوا يقول طب ما هو في NA
+
+54
+00:04:47,090 --> 00:04:53,610
+OH مثلا عندي NA plus OH minus أه بس ال OH minus
+
+55
+00:04:53,610 --> 00:04:58,560
+هنا جزء منها رايح بالتجاذب مع ال إيشالان A plus
+
+56
+00:04:58,560 --> 00:05:03,600
+لكن انه يطلع عندي OH minus لحالها مشكلة ال O H
+
+57
+00:05:03,600 --> 00:05:07,060
+مابتقدرش تحمل الإلكترونات عشانك احنا متعودين في
+
+58
+00:05:07,060 --> 00:05:12,040
+الكيميا نقول عن مجموعة ال O H انه is a bad leaving
+
+59
+00:05:12,040 --> 00:05:16,640
+group ايش
+
+60
+00:05:16,640 --> 00:05:21,300
+يعني bad leaving group يعني مجموعة مغادرة سيئة مش
+
+61
+00:05:21,300 --> 00:05:27,430
+هي بده تطلعمابتطلعش بسهولة لازم اعمل طرق معينة
+
+62
+00:05:27,430 --> 00:05:34,250
+عشان اخلي هذه المجموعة ال OH- تطلع لانها مابتقدرش
+
+63
+00:05:34,250 --> 00:05:38,450
+تحمل إلكترونات شو هي العملية اللي بنعملها احنا
+
+64
+00:05:38,450 --> 00:05:42,990
+عشان نخلي ال OH- تطلع بنجي للتفاعل في الخطوة
+
+65
+00:05:42,990 --> 00:05:48,800
+الأولى بنضيفحامض H plus الان ال H plus هذا خلوه
+
+66
+00:05:48,800 --> 00:05:52,440
+يجى يتفاعل مع زوج الالكترونات اللى موجود عندنا هنا
+
+67
+00:05:52,440 --> 00:05:59,720
+و يعمل ميه بعد هيك اذا صار مجموعة بدها تطلع ايش
+
+68
+00:05:59,720 --> 00:06:03,620
+هتكون المجموعة اللى بدها تطلع OH minus
+
+69
+00:06:07,180 --> 00:06:13,120
+الـ H2O في هذه الحالة تظهر على شكل جزء متعادل بزام
+
+70
+00:06:13,120 --> 00:06:16,280
+جزء متعادل مش حامل شحنة مش عنده مشكلة المشكلة وين
+
+71
+00:06:16,280 --> 00:06:23,320
+انه تظهر مجموعة صغيرة حاملة شحنة ومش قادرة تحمل مش
+
+72
+00:06:23,320 --> 00:06:28,120
+قادرة تحمل هذه الشحنة ولذلك دائما التفاعلات تبعت
+
+73
+00:06:28,120 --> 00:06:34,050
+ال alcohols أول ما بدي أبدأ فيهابدي أحول ال bad
+
+74
+00:06:34,050 --> 00:06:39,150
+leaving group اللي هي ال OH إلى ال good leaving
+
+75
+00:06:39,150 --> 00:06:42,270
+group ال good leaving group هي الميه كيف بتتم هذا
+
+76
+00:06:42,270 --> 00:06:47,470
+الكلام؟ من خلال إضافة الحامض إذا نعرفنا إيش وظيفة
+
+77
+00:06:47,470 --> 00:06:51,950
+الحامض the function of the acid is to convert the
+
+78
+00:06:51,950 --> 00:06:57,330
+bad leaving group to a good leaving group ليش هذه
+
+79
+00:06:57,330 --> 00:07:01,840
+كانت bad؟ لأنها chargednegative charge، it cannot
+
+80
+00:07:01,840 --> 00:07:04,480
+carry the negative charge، ليش هذه good living
+
+81
+00:07:04,480 --> 00:07:09,100
+group؟ لأنها neutral، لأنها متعادلة، مش حاملة،
+
+82
+00:07:09,100 --> 00:07:11,800
+شحنة، واحد مافيش عنده مصايب ولا واحد فيه عنده
+
+83
+00:07:11,800 --> 00:07:15,560
+مصايب، مين بيكون متريح أكتر؟ المتعادل، اللي مافيش
+
+84
+00:07:15,560 --> 00:07:19,140
+عنده مصايب، الآن هذه خطوة تحضيرية، احنا
+
+85
+00:07:19,140 --> 00:07:23,680
+مابنعتبرهاش خطوة من ال mechanism، ليش؟ لأن ال
+
+86
+00:07:23,680 --> 00:07:30,690
+mechanism هي عملية حذفالميّة في النهاية وتكوين الـ
+
+87
+00:07:30,690 --> 00:07:35,850
+double bond هل تم فيها حد في إشي لحد الآن؟ لأ بس
+
+88
+00:07:35,850 --> 00:07:38,330
+أنا عملت ال bad living group و ال good living
+
+89
+00:07:38,330 --> 00:07:41,250
+group عشانك هذا الخطوة ليست جزء من الميكانيزم طب
+
+90
+00:07:41,250 --> 00:07:45,130
+ها إيش الميكانيزم؟ الميكانيزم الآن لما تيجي تطلع
+
+91
+00:07:45,130 --> 00:07:50,560
+الاتش هذه لحالة بدون زوج الإلكترونات اتش plusواضح؟
+
+92
+00:07:50,560 --> 00:07:54,340
+الـ double bond بتتحرك بهذا الشكل بيفقد جزء الميّه
+
+93
+00:07:54,340 --> 00:07:59,520
+لاحظوا معاه إيش بتكون بهذه الحالة هدولة حركة بتطلع
+
+94
+00:07:59,520 --> 00:08:04,820
+ال H ال double bond بتتحرك الميّه كلها بتفقد بيصير
+
+95
+00:08:04,820 --> 00:08:10,080
+عند ال alkene زاد ال H plus زاد الميّه في النهاية
+
+96
+00:08:10,080 --> 00:08:15,050
+إيش اللي بتلاحظوا؟ أنه تم فقد الماءمظبوط ولا لأ؟ و
+
+97
+00:08:15,050 --> 00:08:19,710
+ال H plus اللي استعملت هنا عوضت طلعت ولا لأ؟ إذا
+
+98
+00:08:19,710 --> 00:08:24,090
+إيش بنقول عن ال H plus هنا اللي دخلت في التفاعل و
+
+99
+00:08:24,090 --> 00:08:28,950
+عوضت طلعت catalyst H plus is a catalyst هم لاحظين
+
+100
+00:08:28,950 --> 00:08:37,400
+هنا catalyst عامل مساعد فقطأيه جت عملت وظيفة معينة
+
+101
+00:08:37,400 --> 00:08:41,180
+ساعدت الـ Bad Living Group أنها تطلع وبعدين عودت
+
+102
+00:08:41,180 --> 00:08:44,600
+رجعت H Plus؟ الآن هذه اللي رجعت ممكن تبدأ تعمل
+
+103
+00:08:44,600 --> 00:08:49,860
+تفاعل جديد ولا لأ؟ أكيد ولذلك لما أنا بدي أضيف على
+
+104
+00:08:49,860 --> 00:08:55,840
+التفاعل H Plus بضيفه بكمية مكافئة ولا بكمية قليلة؟
+
+105
+00:08:55,840 --> 00:09:00,280
+بكمية قليلة لأن انا بتشتغل الشغلة، بتعود ترجع،
+
+106
+00:09:00,280 --> 00:09:04,550
+بتشتغل الشغلة، بتعود ترجع، واضح؟زي على سبيل
+
+107
+00:09:04,550 --> 00:09:08,770
+المثال، لو تتخيلوا مدينتين، فكرة الـ Catalyst، لما
+
+108
+00:09:08,770 --> 00:09:13,510
+يكون عندى خمس سيارات بينقلوا ناس طول النهار، رايح
+
+109
+00:09:13,510 --> 00:09:18,690
+جاي، هم يمثلوا Catalyst، وسيلة بتعمل عملية إيش
+
+110
+00:09:18,690 --> 00:09:22,230
+نقل، بس مش لازم لو بدى أنقل ألف بني آدم يكون عنده
+
+111
+00:09:22,970 --> 00:09:27,310
+الف سيارة خمسة بيقوم المهم رايح جاى رايح جاى وهذا
+
+112
+00:09:27,310 --> 00:09:30,610
+نفس الاشي ال H plus بتطيف بتصير هذا good living
+
+113
+00:09:30,610 --> 00:09:35,190
+group بتطلع و بترجع ال H plus بتطلع من جديد و هكذا
+
+114
+00:09:35,190 --> 00:09:40,970
+واضح هذا اللي هو التفاعل الأول اللي بنسميه acidic
+
+115
+00:09:40,970 --> 00:09:45,970
+dehydration ليش قلنا acidic لأنه بنستعمل ال
+
+116
+00:09:45,970 --> 00:09:52,200
+catalystالـ H plus اللي هو الحامض واضح؟ حتى تتم
+
+117
+00:09:52,200 --> 00:09:58,300
+عملية الـ dehydration والتحول إلى الالكين لازم
+
+118
+00:09:58,300 --> 00:10:07,160
+نستعمل أسلوب هنا بدنا بس تنويه صغير أنه نفس هذا
+
+119
+00:10:07,160 --> 00:10:12,600
+التفاعل مثلا هنا الاثانول بيصير إيثالينهذا التفاعل
+
+120
+00:10:12,600 --> 00:10:18,200
+شويه حساس لدرجة الحرارة بمعنى إذا كانت تسخين ل 180
+
+121
+00:10:18,200 --> 00:10:22,240
+درجة مئوية بتصير عملية ال dehydration بس إذا بنسخن
+
+122
+00:10:22,240 --> 00:10:28,940
+عند 140 درجة مئوية بصير ناتج تاني اللي هو تكوين ال
+
+123
+00:10:28,940 --> 00:10:34,160
+ether ال ether هذه مجموعة ال ether فعند ال 140
+
+124
+00:10:34,160 --> 00:10:37,140
+درجة مئوية هيصير عند ال ether اللي هو ال ether o
+
+125
+00:10:38,720 --> 00:10:42,400
+بناخده بالفصل التامن تكوين الـ Ether لما ناخد
+
+126
+00:10:42,400 --> 00:10:45,940
+تكوين الـ Ether من الـ Ethanol هنقول نفس التفاعل
+
+127
+00:10:45,940 --> 00:10:51,680
+بنسخن وجود H Plus لكن عند 140 درجة موية، الآن هنا
+
+128
+00:10:51,680 --> 00:10:58,560
+عشان التفاعل حساس لدرجة الحرارة لازم تحفظوها،
+
+129
+00:10:58,560 --> 00:11:02,520
+واضح؟ يعني عند 180 درجة موية بيصير عند الـ Alkyl
+
+130
+00:11:02,520 --> 00:11:06,680
+عند 140 درجة موية بيصير عند الـ Ether
+
+131
+00:11:10,370 --> 00:11:16,550
+طبعا هذا ال alcohol اللي احنا كتبناها انه عبارة عن
+
+132
+00:11:16,550 --> 00:11:22,970
+ال primary alcohol ملاحظين CH2OH CH2OH الميكانيزم
+
+133
+00:11:22,970 --> 00:11:27,150
+هذا بخطوة واحدة تطلع ال H هذا تلف هذا تطلع شو
+
+134
+00:11:27,150 --> 00:11:33,230
+سمناها سابقا احنا E2 ميكانيزم اعملنا زيها بالظبط
+
+135
+00:11:33,230 --> 00:11:40,590
+لل elimination لل HXبر لما أخدنا ال mechanisms of
+
+136
+00:11:40,590 --> 00:11:46,110
+elimination في chapter 6 قلنا هما نوعين E2 و E1
+
+137
+00:11:46,110 --> 00:11:50,210
+mechanism الآن هنا ال mechanism اللي هي ال E2 ال
+
+138
+00:11:50,210 --> 00:11:55,690
+one step mechanism و اللي بتصير عادة مع ال primary
+
+139
+00:11:55,690 --> 00:12:01,170
+واضح طيب لو انتقلنا لل tertiary على طول هتلاحظوا
+
+140
+00:12:01,170 --> 00:12:05,170
+ان انتوا متذاكرين ان مع ال tertiary ال mechanism
+
+141
+00:12:05,170 --> 00:12:10,040
+المشهورة اللي هيالـ E1 ميكانيزم والـ E1 ميكانيزم
+
+142
+00:12:10,040 --> 00:12:15,120
+عبارة عن كام step؟ two steps الخطوة الأولى تكوين
+
+143
+00:12:15,120 --> 00:12:21,640
+الكربوكاتيون والخطوة الثانية فقد البروتون وتكوين
+
+144
+00:12:21,640 --> 00:12:27,360
+ال double bond خلينا نشوف كيف تتم هذه العملية أول
+
+145
+00:12:27,360 --> 00:12:32,340
+شيء لابد من الخطوة التحضيرية في كل الأحوال أن هذا
+
+146
+00:12:32,340 --> 00:12:37,560
+الـ OH إيش ما لها؟bad leaving group لازم أعمل
+
+147
+00:12:37,560 --> 00:12:42,940
+اتفاعل في وجود حامض عشان يحول الـ OH إلى H2O الأن
+
+148
+00:12:42,940 --> 00:12:46,320
+صارت الـ bad leaving group و الـ good leaving
+
+149
+00:12:46,320 --> 00:12:49,980
+group هذا لسه مش خطوة في الميكانيزم هذا مش خطوة في
+
+150
+00:12:49,980 --> 00:12:54,220
+الميكانيزم من وين بتبدأ الميكانيزم؟ بتبدأ بفقد
+
+151
+00:12:54,220 --> 00:12:59,560
+الميّه لما تفقد الميّه بتكون عندك كاربو كتايون هذا
+
+152
+00:12:59,560 --> 00:13:05,860
+الكاربو كتايون الأيون الموجب أثبت شيء بيكونمع الـ
+
+153
+00:13:05,860 --> 00:13:09,700
+tertiary وهنا احنا بنشتغل على الـ tertiary ولذلك
+
+154
+00:13:09,700 --> 00:13:13,500
+هذا بيكون stable الكاربو كتايون أثبت شيء مع الـ
+
+155
+00:13:13,500 --> 00:13:18,220
+tertiary هذا الكاربو كتايون الآن بعد ذلك بيفقد H
+
+156
+00:13:18,220 --> 00:13:20,840
+plus في الخطوة التانية وبتيجي ال double bond ده
+
+157
+00:13:20,840 --> 00:13:24,820
+بتتحرك هنا بتكون الalkene زي الـH plus مرة تانية
+
+158
+00:13:24,820 --> 00:13:30,180
+بتلاحظوا ان الـH plus بدأنا فيها وطلعت تاني إذا
+
+159
+00:13:30,180 --> 00:13:37,330
+الـH plus is a catalystلاحظوا التفاعل خطوتين
+
+160
+00:13:37,330 --> 00:13:43,270
+بسيطات الخطوة الأولى فقد الماء وتكوين Carbocation
+
+161
+00:13:43,270 --> 00:13:49,030
+الخطوة التانية فقد البروتون اللي هو في الأساس تم
+
+162
+00:13:49,030 --> 00:13:54,930
+إضافته لعملكتاليسيز للتفاعل وتكوين الألكيد هذه
+
+163
+00:13:54,930 --> 00:13:58,850
+الميكانيزم اللي بـ two steps ال first step و ال
+
+164
+00:13:58,850 --> 00:14:04,210
+second step هي اللي سمناها احنا E1 ميكانيزم اذا لو
+
+165
+00:14:04,210 --> 00:14:08,530
+بدنا نقول كيف بتتم عملية ال elimination من ال
+
+166
+00:14:08,530 --> 00:14:15,030
+primary alcohols ب E2 ميكانيزم من tertiary
+
+167
+00:14:15,030 --> 00:14:15,950
+alcohols
+
+168
+00:14:25,790 --> 00:14:30,950
+في الـ alkenes بتيجينا نفس المشكلة اللي تواجهنا
+
+169
+00:14:30,950 --> 00:14:35,490
+فيها بالـ alkyl halides إذا بتذكروا لما كنا نقول
+
+170
+00:14:35,490 --> 00:14:41,970
+بدنا نعمل عملية حذف من الـ alkyl halides كان في
+
+171
+00:14:41,970 --> 00:14:47,230
+إمكانية أحيانا يتكون عند أكثر من ال keen لما أنا
+
+172
+00:14:47,230 --> 00:14:50,990
+كنت بدأ أحذف ال X ممكن ال H من اليمين و لا ال H من
+
+173
+00:14:50,990 --> 00:14:55,740
+الشمال عشان أكمل H Xالان نفس الفكرة لما بدي أحذف
+
+174
+00:14:55,740 --> 00:15:00,080
+ال OH ال OH اللي بدي أحذفها بدي أحذفها مع إيش؟ هاي
+
+175
+00:15:00,080 --> 00:15:06,100
+ال OH اللي بدي نحذفها مع H مع H هال H هذه ممكن
+
+176
+00:15:06,100 --> 00:15:11,320
+تكون من هنا وبالتالي زيك أحذف الميه وممكن تكون من
+
+177
+00:15:11,320 --> 00:15:14,760
+هنا وبالتالي زيك أحذف الميه الآن إذا حذفت من هنا
+
+178
+00:15:14,760 --> 00:15:20,400
+شو هيتكون؟ هذا ال LK وإذا حذفت من هنا شو هيتكون؟
+
+179
+00:15:21,460 --> 00:15:26,580
+أذا كم ألكين متوقع عنده؟ اتنين و هذه الفكرة بتاعي
+
+180
+00:15:26,580 --> 00:15:31,780
+اللي حكيناها بوضوح لما أخدنا ال elimination of HX
+
+181
+00:15:31,780 --> 00:15:35,780
+قولنا الـ HX X مع H من هنا و لا H من هنا في عندي
+
+182
+00:15:35,780 --> 00:15:40,280
+two possibilities الأهم ايش اللي بيحكم لأي ناتج
+
+183
+00:15:40,280 --> 00:15:47,210
+اللي بيطلع؟ ايش سمينا احنا؟الـ more substituted
+
+184
+00:15:47,210 --> 00:15:51,190
+القين والـ formed القلقين اللي بيكون عليه إبدال
+
+185
+00:15:51,190 --> 00:15:56,350
+أكثر القلقين اللي بيكون عليه إبدال أكثر اللي قال
+
+186
+00:15:56,350 --> 00:16:01,470
+لو جيت سؤالت هذا ال two-butene و ال one-butene قدش
+
+187
+00:16:01,470 --> 00:16:06,650
+الإبدالات اللي على ال two-butene كام substitution؟
+
+188
+00:16:06,650 --> 00:16:08,550
+من تحسب النيارة؟
+
+189
+00:16:11,210 --> 00:16:15,990
+هي في عندى H و H و واحدة قبلت مثل و واحدة قبلت مثل
+
+190
+00:16:15,990 --> 00:16:22,130
+اذا كام substitution انا عندى اتنين هذا المركب هى
+
+191
+00:16:22,130 --> 00:16:28,070
+H و H و H و واحدة اثل اذا كام substitution واحد
+
+192
+00:16:28,070 --> 00:16:33,310
+which is more substituted ال two butene is more
+
+193
+00:16:33,310 --> 00:16:37,490
+substituted than one butene عشان هيك ال major
+
+194
+00:16:37,490 --> 00:16:42,320
+product في هذه الحالة isتو بيوتين و لاحظوا معي لو
+
+195
+00:16:42,320 --> 00:16:48,020
+كانت هذه ال CL و حطينا مع KOH كان برضه هنكتب نفس
+
+196
+00:16:48,020 --> 00:16:54,380
+النتيجة لما أخدنا المثال مع CL و بر هنا و كنا نعمل
+
+197
+00:16:54,380 --> 00:16:58,520
+التفاعل في وجود ال KOH كان يطلع عندنا one butane و
+
+198
+00:16:58,520 --> 00:17:02,810
+two butane و اللي كنا نقول عنهالناتج اللي بتكون
+
+199
+00:17:02,810 --> 00:17:06,510
+بنسبة أعلى ال major product مش ال minor ال major
+
+200
+00:17:06,510 --> 00:17:13,610
+اللي هو ال more substituted ال keen okay هاي كمان
+
+201
+00:17:13,610 --> 00:17:19,790
+مثال لو أخدنا هذا ال cyclopentanol اللي حامل OH
+
+202
+00:17:19,790 --> 00:17:25,690
+وهنا CH3 وهنا فيه H's الآن بالتأكيد ال OH بدأ تطلع
+
+203
+00:17:26,300 --> 00:17:32,140
+هذا مش موضوع نقاش لكن السؤال مع أي هيدروجين مع أي
+
+204
+00:17:32,140 --> 00:17:36,200
+بروتون بدها تطلع في إمكانية تطلع مع الهيدروجين
+
+205
+00:17:36,200 --> 00:17:40,340
+اللي هان وفي إمكانية تطلع مع واحدة من هدولة اللي
+
+206
+00:17:40,340 --> 00:17:45,700
+هان واضح؟ الآن إذا طلعت مع هيدروجين من هدولة هتكون
+
+207
+00:17:45,700 --> 00:17:50,200
+لأي مركب المركب التاني اللي هناك وإذا طلعت ال OH
+
+208
+00:17:50,200 --> 00:17:53,580
+مع هيدروجين من هنا هتكون ال double bond في هذا
+
+209
+00:17:53,580 --> 00:17:58,140
+الموقع لما نيجي نحللwhich is the major product أنه
+
+210
+00:17:58,140 --> 00:18:02,720
+هو الناتج الأساسي ال more substituted اتطلعولي هنا
+
+211
+00:18:02,720 --> 00:18:06,460
+كام substitution عندى و هنا كام substitution عندى
+
+212
+00:18:06,460 --> 00:18:12,680
+هنا في عندى هى ال double bond هى ده متصلة ب carbon
+
+213
+00:18:12,680 --> 00:18:16,240
+و هى ده ب carbon و هى ده ب carbon واحدة منهم بس
+
+214
+00:18:16,240 --> 00:18:22,950
+hydrogen إذا كام substitution عندى هنا تلاتةثلاثة
+
+215
+00:18:22,950 --> 00:18:26,130
+من الهيدروجين راحوا، ضالت واحدة، إذا عندي تلت
+
+216
+00:18:26,130 --> 00:18:31,030
+إبدالات، لإن المركب غير المبدل اللي يحتوي عليه،
+
+217
+00:18:31,030 --> 00:18:35,690
+أربعة هيدروجين، واضح؟ هنا الآن كام substitution؟
+
+218
+00:18:35,690 --> 00:18:39,730
+عندي هذه كام و هذه؟ هنا هيدروجين و هيدروجين مافيش
+
+219
+00:18:39,730 --> 00:18:43,190
+إبدال هنا، اتنين، اتنين، إذا which is the major
+
+220
+00:18:43,190 --> 00:18:47,770
+product؟the first one is the major product واضح؟
+
+221
+00:18:47,770 --> 00:18:51,370
+عشانك لو انا بدي اجيبلكوا اكمل المعادلة هذه او هذه
+
+222
+00:18:51,370 --> 00:18:56,570
+و اكتبلكوا اعطوني ال major product تعملوا ال
+
+223
+00:18:56,570 --> 00:19:01,910
+substitution يعني تعملوا المركب ال major product
+
+224
+00:19:01,910 --> 00:19:07,050
+يكون ال more substituted واضح؟ الناتج الأكثر إبدال
+
+225
+00:19:07,050 --> 00:19:10,730
+هو الناتج الأساسي
+
+226
+00:19:17,840 --> 00:19:22,120
+النوع التاني من التفاعلات، لاحظوا كل التفاعل الأول
+
+227
+00:19:22,120 --> 00:19:26,960
+اللي أخدناه حذف الـ OH مع H لتكوين الكني اللي
+
+228
+00:19:26,960 --> 00:19:33,120
+سمناه عملية dehydration، نزع الماء، الآن التفاعل
+
+229
+00:19:33,120 --> 00:19:41,180
+الثاني هو تفاعل إبدال، إن أبدل الـ OH ب X، ال X
+
+230
+00:19:41,180 --> 00:19:49,670
+يعني CL أو PR أو Uواضح؟ substitution reaction كيف
+
+231
+00:19:49,670 --> 00:19:53,670
+بتتم عملية ال substitution reaction؟ كيف هذا ال OH
+
+232
+00:19:53,670 --> 00:20:00,170
+بدي أخليها تصير X؟ واضح؟ ببساطة، لو كان عندي
+
+233
+00:20:00,170 --> 00:20:04,790
+tertiary alcohol لو كان عندي tertiary alcohol بأجي
+
+234
+00:20:04,790 --> 00:20:10,380
+بفعله ماعدش Clالـ tertiary alcohol بفعله مع الـ
+
+235
+00:20:10,380 --> 00:20:15,580
+HCl بتطلع الـ OH و مع الـ H هذا بتعمل ميه و بيجي
+
+236
+00:20:15,580 --> 00:20:21,400
+عند هنا CL الآن لو جينا قولنا إيش الميكانيزم اللي
+
+237
+00:20:21,400 --> 00:20:27,240
+بدو يتم في هذا التفاعل واحدة
+
+238
+00:20:27,240 --> 00:20:33,920
+تعطينا وصفيا هذا التفاعل كيف بدو يتم على كام خطوة
+
+239
+00:20:41,140 --> 00:20:47,160
+بدي يكون فيه خطوتين أساسيات في الميكانيزم وقولا
+
+240
+00:20:47,160 --> 00:20:55,360
+واحدا خطوة تحضيرية ايش الخطوة التحضيرية تحويل ال O
+
+241
+00:20:55,360 --> 00:21:00,160
+H minus ال bad leaving group إلى good leaving
+
+242
+00:21:00,160 --> 00:21:04,760
+group إذا في الأول هذا لما تكتبوا الميكانيزم له
+
+243
+00:21:05,590 --> 00:21:12,030
+بتقولوا زائد H plus بتصير هذا H2O بعدين الخطوة
+
+244
+00:21:12,030 --> 00:21:18,550
+الأولى الـH2O تفقد بتصير Carbocation
+
+245
+00:21:18,550 --> 00:21:24,970
+بعدين الـCl بتيجي بتتفاعل بيصير عنده اللي هو ال
+
+246
+00:21:24,970 --> 00:21:30,410
+Alkyl chloride واضح؟
+
+247
+00:21:30,410 --> 00:21:37,420
+اذاكام خطوة عندى مرة تانية منى تعيدلى اهم تنتين
+
+248
+00:21:37,420 --> 00:21:41,680
+اساسيات الميكانيزم زاد خطوة تحذيرية في الاول دائما
+
+249
+00:21:41,680 --> 00:21:46,380
+كل التفاعلات الالكحول وانتم غامضين ال OH minus ال
+
+250
+00:21:46,380 --> 00:21:51,140
+OH هذا بدأ تصير H2O بعد ان ال H2O تفقد بتعطيني
+
+251
+00:21:51,140 --> 00:21:54,720
+carbocation هاي ال first step ال carbocation مع ال
+
+252
+00:21:54,720 --> 00:22:00,360
+CL بيعطيني المركب تبعى هذه الميكانيزم اللى احنا
+
+253
+00:22:00,360 --> 00:22:06,240
+سمناها SNone mechanism الآن أنا بتكون تتذكروا شغلة
+
+254
+00:22:06,240 --> 00:22:11,260
+كمان طالما أنه أنا بقول أنه بتكون عندي carbocation
+
+255
+00:22:11,260 --> 00:22:15,140
+طالما أنا بقول بتكون عندي carbocation في الخطوة
+
+256
+00:22:15,140 --> 00:22:20,100
+الأولى، إذا متوقع في النتائج أنه يصير عندي إيش؟
+
+257
+00:22:21,340 --> 00:22:24,420
+rearrangement الكربوكاتيون من مواصفته ال
+
+258
+00:22:24,420 --> 00:22:27,780
+rearrangement يعني لو كان عندي مثلا secondary
+
+259
+00:22:27,780 --> 00:22:31,680
+كربوكاتيون ممكن يعمل rearrangement و يصير tertiary
+
+260
+00:22:31,680 --> 00:22:37,340
+كربوكاتيون more stable و أحيانا primary كربوكاتيون
+
+261
+00:22:37,340 --> 00:22:41,100
+و بيصير tertiary كربوكاتيون أو secondary
+
+262
+00:22:41,100 --> 00:22:45,690
+كربوكاتيون واضح؟كل الكلام اللي أخدته على الـ SN1
+
+263
+00:22:45,690 --> 00:22:49,590
+ميكانيزم برضه بنطبق هنا لكن إنتوا لما درستوا
+
+264
+00:22:49,590 --> 00:22:52,150
+chapter 6 كان عندكوا ال الهيلايت كانت بالخطوة
+
+265
+00:22:52,150 --> 00:22:56,670
+الأولى تفقد ال X و تكون Carbocation الآن هنا بتفقد
+
+266
+00:22:56,670 --> 00:23:02,890
+الميه وبتكون Carbocation والتفاعل بمشي الان
+
+267
+00:23:02,890 --> 00:23:04,930
+بالنسبة ل primary
+
+268
+00:23:07,730 --> 00:23:13,770
+الحقيقة لـ Primary Alcohols لو جينا نفعلهم مع الـ
+
+269
+00:23:13,770 --> 00:23:21,050
+HCl لوحده، ما بيصيرش تفاعل، واضح؟ الـ Primary
+
+270
+00:23:21,050 --> 00:23:28,510
+Alcohols مع HCl لوحده، ما بيصيرش تفاعل من أساسه،
+
+271
+00:23:28,510 --> 00:23:34,410
+تفاعل بطيء جداًالان ايش بيعملوا عشان يصير التفاعل
+
+272
+00:23:34,410 --> 00:23:41,750
+ال primary alcohol بياخدوه مع ال HCL و بيحطوا عليه
+
+273
+00:23:41,750 --> 00:23:48,990
+كمان catalyst زنك كلورايد و كمان حرارة و كل هذا
+
+274
+00:23:48,990 --> 00:23:52,430
+لسه بيعطيني التفاعل مش كتير مقنع يعني بياخد عدة
+
+275
+00:23:52,430 --> 00:23:59,650
+ساعات تسخين لما تم عملية الإبداللأ ال OH بها لوجد
+
+276
+00:23:59,650 --> 00:24:03,610
+و طبعا هنا طالما هذا primary إذا الميكانيزم اللي
+
+277
+00:24:03,610 --> 00:24:08,110
+بتتوقعوها SN2 ميكانيزم الميكانيزم اللي بتتوقعها
+
+278
+00:24:08,110 --> 00:24:12,290
+SN2 ميكانيزم و اليود هنا بتتفاعل أسرع من ال brom
+
+279
+00:24:12,290 --> 00:24:17,670
+أسرع من الchlor واضح لأن اليود بده يهاجم و اليود
+
+280
+00:24:17,670 --> 00:24:21,300
+stronger and nucleophile thanIbromine which is
+
+281
+00:24:21,300 --> 00:24:27,220
+stronger than chlorine وبناء على ذلك هذه يعني أو
+
+282
+00:24:27,220 --> 00:24:32,720
+التفاعل بهذا الشكل رغم أنه ممكن عبر تسخين لعدة
+
+283
+00:24:32,720 --> 00:24:38,360
+ساعات لكنه ليس الطريقة الأمثل لتحويل ال primary
+
+284
+00:24:38,360 --> 00:24:44,470
+alcohols ل ال alkyl halides في طرق أفضل منهواضح؟
+
+285
+00:24:44,470 --> 00:24:47,910
+إذا لو أنا بدي أجي أسألكوا في الامتحان أنه ال
+
+286
+00:24:47,910 --> 00:24:52,710
+primary alcohols react with HCl forming alkyl
+
+287
+00:24:52,710 --> 00:24:58,550
+halides، الجواب لأ، مع ال HCl لحاله لأ، طب مع ال
+
+288
+00:24:58,550 --> 00:25:04,620
+HCl و Zinc chloride و حرارةبصير لكن يعتبر تفاعل
+
+289
+00:25:04,620 --> 00:25:09,320
+بطيء إذا إيش ال best method؟ إيش أفضل طريقة لتحويل
+
+290
+00:25:09,320 --> 00:25:11,880
+ال primary alcohol هي مثلا أنا عندنا واحد اتنين
+
+291
+00:25:11,880 --> 00:25:17,220
+تلاتة بروبانول هذا المركب بروبانول هذا primary
+
+292
+00:25:17,220 --> 00:25:22,720
+alcohol بنيجي بنفعله مع ال BCL3 فوسفوراس تريكلوريد
+
+293
+00:25:22,720 --> 00:25:27,920
+مثلا أو فوسفوراس تريبروميد هذا التفاعل خصوص لل
+
+294
+00:25:27,920 --> 00:25:34,230
+primary alcohol عقول بحب محل ال OACAإذن أنهي أفضل
+
+295
+00:25:34,230 --> 00:25:38,290
+طريقة أنه الـ Primary Alcohol لما بدي أعمل منه
+
+296
+00:25:38,290 --> 00:25:43,630
+Alkyl Halide أفعله مع الـ PCL3 الـ Phosphorus
+
+297
+00:25:43,630 --> 00:25:48,330
+Trichloride لكن نيجي نقول Primary Alcohol مع TCL
+
+298
+00:25:48,330 --> 00:25:54,250
+لحاله ما بتحولها لAlkyl
+
+299
+00:25:54,250 --> 00:25:57,530
+Halide هذه الطريقة اللي هي ال reaction with
+
+300
+00:25:57,530 --> 00:26:02,420
+Phosphorus Chloride في طريقة تانية كمانبنفعله مع
+
+301
+00:26:02,420 --> 00:26:07,840
+مادة بنسميها Theonyl Chloride Theonyl Chloride الـ
+
+302
+00:26:07,840 --> 00:26:13,580
+Theonyl Chloride مادة مشهورة S O C L 2 صيغتها واضح
+
+303
+00:26:13,580 --> 00:26:18,560
+S ضب ال bond O C L C L S O C L 2 Theonyl Chloride
+
+304
+00:26:18,560 --> 00:26:23,360
+برضه هذا التفاعل ممتاز بيحول ال primary alcohols
+
+305
+00:26:23,360 --> 00:26:26,760
+إلى ال الكالهيلايد
+
+306
+00:26:27,940 --> 00:26:32,200
+Alkyl Halides can be prepared from primary
+
+307
+00:26:32,200 --> 00:26:36,820
+alcohols or can be best prepared يعني أفضل إشي by
+
+308
+00:26:36,820 --> 00:26:43,800
+reaction with BCL3 or thionyl chloride واضح؟ إذا
+
+309
+00:26:43,800 --> 00:26:49,300
+أفضل طريقتين يا BCL3 يا thionyl chloride في حالة
+
+310
+00:26:49,300 --> 00:26:53,360
+إن أنا بدي أحول ال primary alcohol إلى
+
+311
+00:26:57,020 --> 00:27:02,360
+الكالهلايد هنا بتجينا شغلة انه احنا اخدنا في عندنا
+
+312
+00:27:02,360 --> 00:27:09,300
+tertiary alcohol OH بHCl بنحولها الى الهلايد ال
+
+313
+00:27:09,300 --> 00:27:16,100
+primary مع ال BCL3 و ال SOCl2 الان بنيجي ل .. لو
+
+314
+00:27:16,100 --> 00:27:22,200
+كان عندى phenolic compound يعني AROH فينل او مشتقة
+
+315
+00:27:22,200 --> 00:27:28,410
+فينلواضح الأوقات شنوية موجودة على بنزينة أو طوابع
+
+316
+00:27:28,410 --> 00:27:33,790
+الـ ARA capital small R بالغلط مكتوبة مش مشكلة AR
+
+317
+00:27:33,790 --> 00:27:43,930
+هيكا الـ AR كمجموعة مش capitalالـ AROH لو فعلناها
+
+318
+00:27:43,930 --> 00:27:50,150
+مع HCl مع HCl و Zinc مع BCl3 مع SOCl2 كله
+
+319
+00:27:50,150 --> 00:27:55,290
+مابتتفعلش ولا بتتحول إلى ال الهيلايد الارلهيلايد
+
+320
+00:27:57,090 --> 00:28:01,110
+إذن لاحظوا معي لو بداجة أسألكوا أنا أقولها الـ
+
+321
+00:28:01,110 --> 00:28:04,890
+Phenols can be converted to aryl halides by
+
+322
+00:28:04,890 --> 00:28:08,830
+heating it with HCl or HCl with zinc chloride or
+
+323
+00:28:08,830 --> 00:28:11,930
+by reacting it with phosphorus trichloride or with
+
+324
+00:28:11,930 --> 00:28:16,150
+thionyl chloride كله لأ ال Phenols أبدا من
+
+325
+00:28:16,150 --> 00:28:25,180
+هالناحية مسكرة واضح؟ ما بتتحول ال Phenols إلىأريل
+
+326
+00:28:25,180 --> 00:28:30,140
+هيلايدز ما بتتحول الفينول إلى اريل هيلايدز طبعا
+
+327
+00:28:30,140 --> 00:28:33,300
+احنا الحمد لله لو احتجنا اريل هيلايدز في اننا طرق
+
+328
+00:28:33,300 --> 00:28:37,600
+تانية لتحضيره يعني لما اكون انا بدي كلور و بنزين
+
+329
+00:28:37,600 --> 00:28:42,000
+بلزم ان اجي احوله من فينول ما تحضير الفينول أساسا
+
+330
+00:28:42,000 --> 00:28:46,080
+صعب انا باخد البنزين كلور و ألمنيوم كلورايدز
+
+331
+00:28:46,080 --> 00:28:47,620
+متذكرين المعادلة؟
+
+332
+00:28:50,330 --> 00:28:53,410
+بقدر أحضره لـ Chlorobenzene لكن بطريقة تانية، بس
+
+333
+00:28:53,410 --> 00:28:57,950
+بالتأكيد مش من خلال الفينول، مش من خلال تحويل الـ
+
+334
+00:28:57,950 --> 00:29:06,330
+OH تاعة الفينول إلى إكلورايد إبنيجيلا
+
+335
+00:29:06,330 --> 00:29:13,230
+تفاعل تالت للـ Alcohol لحد الآن الوضع تحت السيطرة
+
+336
+00:29:13,230 --> 00:29:19,150
+أخدنا تفاعلات الـ dehydration نزع الماء النوع
+
+337
+00:29:19,150 --> 00:29:24,860
+التانيالإبداء لأن الـ OH نحط مكانها X التفاعل
+
+338
+00:29:24,860 --> 00:29:30,620
+التالت الأكسدة Oxidation التفاعل التالت الأكسدة
+
+339
+00:29:30,620 --> 00:29:37,460
+واضح؟ طبعا الأكسدة دائما مرتبطة في ذهنها بإيش؟
+
+340
+00:29:37,460 --> 00:29:42,900
+بالأكسوجين بالأكسوجين يعني جزء من معنى الأكسدة بغض
+
+341
+00:29:42,900 --> 00:29:47,460
+النظر عن المعنى المتعلق بالتأكسد فقد إلكترونات
+
+342
+00:29:47,460 --> 00:29:51,900
+والاختصال اكتساب إلكتروناتفي أساس المفهوم كانت
+
+343
+00:29:51,900 --> 00:29:53,980
+الأكسدة تعني
+
+344
+00:29:56,110 --> 00:30:02,750
+زيادة في الروابط مع إيش؟ مع الأكسجين الأكسدة كانت
+
+345
+00:30:02,750 --> 00:30:07,450
+تعني زيادة في الروابط مع الأكسجين بمعنى كل ما أنا
+
+346
+00:30:07,450 --> 00:30:11,970
+بزيد الروابط مع الأكسجين كأن أنا بعمل إيش؟ أكسدة
+
+347
+00:30:11,970 --> 00:30:17,070
+عشان هيك لو بعيدا عن هذه اتخيلنا المراكبات الآتية
+
+348
+00:30:17,070 --> 00:30:23,130
+لو جيت اتخيلت أنا الاثانول CH3 CH2 OH مع كام
+
+349
+00:30:23,130 --> 00:30:29,380
+أكسجين متحدمع واحدة، مظبوط ولا لا؟ الآن لو شيلت H
+
+350
+00:30:29,380 --> 00:30:36,340
+وH من هنا، سيصبح CH3CWbO OH صار مع كام أكسجين من
+
+351
+00:30:36,340 --> 00:30:40,500
+التحت؟ مع تنتين، إذا أنا صارت عندي عملية
+
+352
+00:30:40,500 --> 00:30:46,770
+oxidation، لو شيلت ال Hبدي يصير عند C double bond
+
+353
+00:30:46,770 --> 00:30:52,630
+O أو H هنا الكربون مع كام أكسجين متحدة؟ تلاتة لو
+
+354
+00:30:52,630 --> 00:30:56,250
+أتيت تعمل التكسير إضافي فيك، أصارت منها وامطلعت C
+
+355
+00:30:56,250 --> 00:30:59,270
+double bond O أو C double bond O ثانو أكسيد
+
+356
+00:30:59,270 --> 00:31:06,250
+الكربون، كم؟ رابط، أربع، إذا أنا عملية تحويل
+
+357
+00:31:06,250 --> 00:31:12,810
+الإيثانوللهذا المركب اللي هو ال Acetaldehyde لهذا
+
+358
+00:31:12,810 --> 00:31:16,590
+المركب اللي هو Acetic Acid لهذا المركب اللي هو
+
+359
+00:31:16,590 --> 00:31:21,650
+ثانو أكسيد الكربون حافظين هم دول المركبات إيثالون
+
+360
+00:31:21,650 --> 00:31:27,710
+و هنا Acetaldehyde
+
+361
+00:31:27,710 --> 00:31:37,370
+و بعدين هذا Acetic Acid و بعدين هذا Carbon Dioxide
+
+362
+00:31:37,370 --> 00:31:43,190
+ثانو أكسيد الكربونقصة كبيرة هذه ولا لأ؟ عارفين وان
+
+363
+00:31:43,190 --> 00:31:53,090
+بتصير هذه القصة الكبيرة؟ مين بتعرف فيكم؟ في جسم
+
+364
+00:31:53,090 --> 00:32:03,690
+البني أدمين أي بني أدمين؟ لأ مش احنا لأ بجسم
+
+365
+00:32:03,690 --> 00:32:09,590
+الكفار مش المسلمينأحنا هنا معظمنا مسلمين، هذي
+
+366
+00:32:09,590 --> 00:32:14,030
+بتصير عند الناس اللي بيشربوا الخمرة، اللي بيشربوا
+
+367
+00:32:14,030 --> 00:32:18,570
+الخمرة بياخدوا على جسمهم إيثانول، مظبوط ولا لأ؟
+
+368
+00:32:19,630 --> 00:32:23,590
+الان هذا الاثانول بيعمل تأثير الإسكار تبعه، كم
+
+369
+00:32:23,590 --> 00:32:27,250
+يأخذ تأثير الإسكار لحد ما يروح، حسب الكمية اللي
+
+370
+00:32:27,250 --> 00:32:31,430
+الناس شربينها، يوم، نص، يوم، ست، سبع، تمان، تسعة،
+
+371
+00:32:31,430 --> 00:32:34,470
+عشر ساعات، إيش بيصير في هال ست، سبع، تمان، تسعة،
+
+372
+00:32:34,470 --> 00:32:39,030
+عشر ساعات اللي بنقول البني آدم فيها drunk، سكران
+
+373
+00:32:39,030 --> 00:32:43,930
+ومش قادر يسيطر على حاله؟ بيصير مختبر كيميا في جسمه
+
+374
+00:32:45,010 --> 00:32:49,570
+بصير في جسمه إيش؟ مختبر كيميا، الإيثانول اللي
+
+375
+00:32:49,570 --> 00:32:53,550
+بياخده من خلال الإنزيمات ومن خلال أشياء معينة في
+
+376
+00:32:53,550 --> 00:32:57,470
+الجسم بيصير acetaldehyde بتأكسد، ال acetaldehyde
+
+377
+00:32:57,470 --> 00:33:05,440
+سام، لحصل الحظ بتأكسد بسرعة إلىأسيتك أسد بتأكسد
+
+378
+00:33:05,440 --> 00:33:09,260
+بسرعة إلى أسيتك أسد والأسيتك أسد بتأكسد لثانو
+
+379
+00:33:09,260 --> 00:33:12,120
+أكسيد الكربون الآن ثانو أكسيد الكربون بنطلع ولا
+
+380
+00:33:12,120 --> 00:33:16,500
+لأ؟ مش احنا كجسم شو بنطلع؟ بنطلع ثانو أكسيد
+
+381
+00:33:16,500 --> 00:33:21,820
+الكربون لاحظوا هذه العملية اللي هو إن الكحول يصير
+
+382
+00:33:21,820 --> 00:33:25,820
+الديهيد يصير أسد يصير ثانو أكسيد الكربون هي عملية
+
+383
+00:33:25,820 --> 00:33:29,810
+كيمية وإحنا في الكيميا بناخد كتاليسيزأحنا في
+
+384
+00:33:29,810 --> 00:33:33,590
+الكيميا بناخد Catalysis، مظبوط ولا لا؟ إيش يعني
+
+385
+00:33:33,590 --> 00:33:38,670
+Catalysis؟ إنه نسرع التفاعلات، الآن السؤال عادي،
+
+386
+00:33:38,670 --> 00:33:45,290
+هل يا تورا في Catalist بيسرع هذا التفاعل؟ إيش معنى
+
+387
+00:33:45,290 --> 00:33:50,370
+الكلام؟ لو هذا ال Catalist موجود، إنه لو شخص معين
+
+388
+00:33:50,370 --> 00:33:56,450
+راح على حفلة وصار شارب إيثانول كتير وبدو يروح
+
+389
+00:33:56,450 --> 00:34:03,100
+بسيارتهممنوع حسب القانون أنه يسوق السيارة لأنه
+
+390
+00:34:03,100 --> 00:34:06,440
+سكران، مش هيسيطر عليها، إيش الحال والله؟ في
+
+391
+00:34:06,440 --> 00:34:10,220
+إمكانية أنه نيجي نعطيه catalyst، حبة حبوب، هال
+
+392
+00:34:10,220 --> 00:34:14,040
+catalyst خلال عشر دقايق، يحول الاثانول لالديهيد،
+
+393
+00:34:14,040 --> 00:34:18,420
+لأسد، لثانوكسيد كربون، خلصنا من الاثانول؟ أبدًا،
+
+394
+00:34:18,420 --> 00:34:23,580
+العلماء مش ناجحين بهالشغلة، لازم ياخد ال .. ال ..
+
+395
+00:34:24,700 --> 00:34:30,200
+الكحول حجه حسب نظام الجسم مافيش عند العلماء لحد
+
+396
+00:34:30,200 --> 00:34:33,840
+اليوم على أقل تقدير إيش بيصير في الدنيا الله بيعلم
+
+397
+00:34:33,840 --> 00:34:41,560
+مافيش طريقة يسرعوا فيها إخراج الكحول من الجسم كتير
+
+398
+00:34:41,560 --> 00:34:45,800
+شغلات أحيانا الملحدين بياخدوا سموم معينة في عندهم
+
+399
+00:34:45,800 --> 00:34:49,540
+toxins مضادات للسموم بيعطوها و بيجدوا على السم
+
+400
+00:34:49,540 --> 00:34:56,280
+بلحظته مظبوط ولا لأ بس الكحول لسه لأيعني بأذكر مرة
+
+401
+00:34:56,280 --> 00:35:03,200
+جريمة قتل التهم فيها شخص بيشرب .. بيشرب كحول و
+
+402
+00:35:03,200 --> 00:35:07,900
+إجوا يحققوا المحققين طبعا برضه في بلد إسلامي بس
+
+403
+00:35:07,900 --> 00:35:13,500
+الشخص بيشرب كحول للأسف إيش عملوا؟ ضالهم يستنوا يوم
+
+404
+00:35:13,500 --> 00:35:17,040
+كامل مع العلم إن كل دقيقة التحقيق بتفيدهم لحد ما
+
+405
+00:35:17,040 --> 00:35:20,810
+البني أدم يصحىاللي بدهم يحققوا معه من الالكو اللي
+
+406
+00:35:20,810 --> 00:35:25,090
+شربينه مافيش عندهم إبرة ولا حب الدواء يعطوياها
+
+407
+00:35:25,090 --> 00:35:30,410
+خلال ربع ساعة تضيع تأثير الكحول من جسمه العلم في
+
+408
+00:35:30,410 --> 00:35:35,230
+هذه المنطقة ما زال بيشتغل على رتم جسم الإنسان رتم
+
+409
+00:35:35,230 --> 00:35:42,410
+جسم الإنسان على البطيء رتم جسم الإنسان على البطيء
+
+410
+00:35:42,410 --> 00:35:49,750
+واضح؟هنا خلّينا فلسفيا نحكي كمان عن شغلة تانية لو
+
+411
+00:35:49,750 --> 00:35:56,870
+إجينا للإيثانول، الإيثانول من وين جاي؟ احنا أخدنا
+
+412
+00:35:56,870 --> 00:36:02,510
+في تحضير الإيثانول، sugar، لو الإيثانول مكوّن
+
+413
+00:36:02,510 --> 00:36:08,690
+المزعج في الخمر، من ال sugar، تمام؟الإيثانول مش
+
+414
+00:36:08,690 --> 00:36:12,990
+بيجي من السكريات وتخميرها، بيخمروا العنب و بيخمروا
+
+415
+00:36:12,990 --> 00:36:16,850
+القصب و بيخمروا العسل و بيخمروا المولاس، مظبوط ولا
+
+416
+00:36:16,850 --> 00:36:22,530
+لأ؟ و الخمور كلها من الانجاص و الفواكه و الطمراللي
+
+417
+00:36:22,530 --> 00:36:26,350
+بيعرف كلها الأشياء، الآن هذه بتحطنا الحقيقة عند
+
+418
+00:36:26,350 --> 00:36:32,090
+شغلة مهمة في الدنيا، أن الأشياء وليست بتاريخها،
+
+419
+00:36:32,090 --> 00:36:36,390
+المهم في الواقع إيش موجود الإنسان اليوم، يعني
+
+420
+00:36:36,390 --> 00:36:40,670
+كإننا بنحكي عن اللي اتعلمتوها إذا اتعلمتوا أنتوا،
+
+421
+00:36:40,670 --> 00:36:44,050
+ماعرفش ممكن ما اتعلمتوش، إيش معنى state function؟
+
+422
+00:36:45,880 --> 00:36:48,200
+دالة الحالة، إيش اللي بنقصده إحنا بال state
+
+423
+00:36:48,200 --> 00:36:52,480
+function أو دالة الحالة؟ دالة الحالة اللي هي الشيء
+
+424
+00:36:52,480 --> 00:36:55,640
+اللي باعتمد على الوضع الآن، ما باعتمدش على
+
+425
+00:36:55,640 --> 00:36:59,340
+التاريخ، ما باعتمدش على ال history، المهم إيش هو
+
+426
+00:36:59,340 --> 00:37:04,320
+الآن؟ تماما زي ما أجي مثلا أنا ألاقي ولد صغير
+
+427
+00:37:04,320 --> 00:37:08,620
+بيلعب في ميا، okay؟ ممكن الولد الصغير اللي بيلعب
+
+428
+00:37:08,620 --> 00:37:11,840
+في المية، هيك ساطل صغير في مية و جاعة بيلعب و بحط
+
+429
+00:37:11,840 --> 00:37:17,940
+على وشه أمه من حد ما تشوفهتغلي بالدنيا أسراخ؟ شوفي
+
+430
+00:37:17,940 --> 00:37:23,950
+شو مالك؟ بتقول والله المي كانت بتغليوالولد عنده
+
+431
+00:37:23,950 --> 00:37:27,550
+انحراج الميّه كانت بتغلي قبل تلت ساعات بس هالجيتها
+
+432
+00:37:27,550 --> 00:37:31,390
+الميّه مابتغليش والميّه هالجيت باردة و الولد ببسوط
+
+433
+00:37:31,390 --> 00:37:35,490
+الان هل أثر التاريخ ان هذي الميّه قبل تلت ساعات
+
+434
+00:37:35,490 --> 00:37:39,490
+كانت تغلي على حالة الميّه الآن؟ عرفت ايش معنى
+
+435
+00:37:39,490 --> 00:37:43,410
+state function؟ ان انا المهم عندي الحالة الآن يعني
+
+436
+00:37:43,410 --> 00:37:46,810
+تجيني طالبة تقولي والله أنا في توجيه الأولى على
+
+437
+00:37:46,810 --> 00:37:50,470
+القطاع ما له مالك و ما له مال القطاع المهم في ال
+
+438
+00:37:50,470 --> 00:37:54,800
+organic جايبة خمسة من تلاتينstate function هل
+
+439
+00:37:54,800 --> 00:37:58,680
+الأولى على القطاع ابتشفعلها أنه كانت الأولى على
+
+440
+00:37:58,680 --> 00:38:02,520
+القطاع اتجوزت و انشغلت و عندها ميد شغلة و بتجلب
+
+441
+00:38:02,520 --> 00:38:05,480
+تطبخ و بعدين بدأت تاخد تلاتين من تلاتين لأنها كانت
+
+442
+00:38:05,480 --> 00:38:08,980
+الأولى على القطاع دي state ايش؟ function المهم
+
+443
+00:38:08,980 --> 00:38:12,720
+عندى الحالة الآن الان انتبهوا معايا كيف بتصير
+
+444
+00:38:12,720 --> 00:38:17,160
+الأمور من ناحية شرعية السكر حلال
+
+445
+00:38:19,360 --> 00:38:24,580
+العناب حلال، الانجاص حلال، التفاح حلال، صار خمرة
+
+446
+00:38:24,580 --> 00:38:29,020
+صار إيثانول حرام، الآن ماحدش ييجي يقول يا أخي
+
+447
+00:38:29,020 --> 00:38:32,580
+انجاص شجرة مباركة، يا أخي طمر، الرسول عليه الصلاة
+
+448
+00:38:32,580 --> 00:38:36,240
+والسلام كان يفطر على الطمر، كان يفطر على الطمر، بس
+
+449
+00:38:36,240 --> 00:38:42,030
+مش لما يصيرمش لما يصير خمرة، واضح؟ كان يفطر على
+
+450
+00:38:42,030 --> 00:38:47,210
+التمر، مش على التمر اللي اتخمر، مظبوط ولا لأ؟ إذا
+
+451
+00:38:47,210 --> 00:38:54,890
+هنا ال sugar حلال، والفواكه حلال، الكحولات، حرام،
+
+452
+00:38:54,890 --> 00:38:58,310
+الالدهايتسام، مرحلة بين هدولة تنتين، بعدين تعالولي
+
+453
+00:38:58,310 --> 00:39:03,050
+على الخل الخل
+
+454
+00:39:03,050 --> 00:39:09,460
+حلال، طب هو من وين جاي؟ من الخمرمظبوط ولا لأ؟
+
+455
+00:39:09,460 --> 00:39:14,020
+الخمر تتحول إلى خل يعني الناس اللي بيعملوا خل
+
+456
+00:39:14,020 --> 00:39:16,400
+التفاح في البيت اللي بيجيبوا التفاح و بيسكروا عليه
+
+457
+00:39:16,400 --> 00:39:19,740
+في الجزازة و شوية بالشمس هو اللي بيصير أن التفاح
+
+458
+00:39:19,740 --> 00:39:23,320
+الحلال بيصير خمرة حرام و الخمرة الحرام بتصير خل
+
+459
+00:39:23,320 --> 00:39:27,960
+حلال و أفضل ما أكلتم الخل لأنه غذاء كامل و في
+
+460
+00:39:27,960 --> 00:39:32,530
+أحاديث نبوية في الخلواضح؟ إذا إحنا جاعدين بنتحول
+
+461
+00:39:32,530 --> 00:39:36,650
+من حلال لحرام لحلال بهمني إيش ال .. إيش اللي أنا
+
+462
+00:39:36,650 --> 00:39:42,130
+الآن قاعد بتعامل معه، هل بهمني تاريخه؟ أه، إذا
+
+463
+00:39:42,130 --> 00:39:50,930
+الخل هنا كيف أصبح حلالا؟ بالشريعة بيستعمله مصطلح،
+
+464
+00:39:50,930 --> 00:39:56,790
+إيش بيقولوا عنه؟ طهرة بالتحول
+
+465
+00:39:58,210 --> 00:40:04,070
+طهورة بإيش؟ بالتحول، هذه عملية التحول من الإثانون
+
+466
+00:40:04,070 --> 00:40:08,850
+للخلق، هذه عملية تطهير لما تاخدوا التطهير في كتاب
+
+467
+00:40:08,850 --> 00:40:12,570
+دراسات في الفقه، بتاخدوا التطهير بالماء، وفي
+
+468
+00:40:12,570 --> 00:40:18,650
+التطهير بإيش؟ بالتحول، إن المادة إذا تحولت من مادة
+
+469
+00:40:18,650 --> 00:40:24,530
+ناجسة إلى مادة طاهرة، خلاص، اتغير تركيبها
+
+470
+00:40:24,530 --> 00:40:30,110
+الكيميائي، بدنا نضل نقول أنا حرام؟ولذلك الخمر
+
+471
+00:40:30,110 --> 00:40:37,170
+الناجس يصبح خلّا طاهرا وعصير الفواكه الطاهر يصبح
+
+472
+00:40:37,170 --> 00:40:42,930
+خمرا ناجسا أنا بتعامل مع اللي موجود عندى
+
+473
+00:40:42,930 --> 00:40:47,670
+وبالمناسبة هنا بتدخل كمان قضية شرعية تانية لأنه
+
+474
+00:40:47,670 --> 00:40:51,470
+لها علاقة .. لها علاقة بالكيميا وكتير الناس اللي
+
+475
+00:40:51,470 --> 00:40:56,200
+بنقشوا هالأمور هذه الناس اللي بعيشوا في أوروباو
+
+476
+00:40:56,200 --> 00:41:00,830
+كويس أن تفهموها لأنها في الأساس قضية علميةإنه
+
+477
+00:41:00,830 --> 00:41:05,170
+بيجيوا على الجيلاتين الجيلاتين بدخل في تحضير كتير
+
+478
+00:41:05,170 --> 00:41:10,730
+من الأطعمة و منها الكيك و أشياء كتيرة الآن من وين
+
+479
+00:41:10,730 --> 00:41:14,750
+بيجيبوا الجيلاتين هنا المشكلة الجيلاتين في أنواع
+
+480
+00:41:14,750 --> 00:41:18,590
+منه بيجيبوها من النباتات من التفاح من غيرها زي
+
+481
+00:41:18,590 --> 00:41:23,950
+البكتين بمعنى هناك جيلاتين بأصل نباتي و هناك
+
+482
+00:41:23,950 --> 00:41:27,850
+جيلاتين بأصل حيواني الجيلاتين اللي بأصل حيواني
+
+483
+00:41:27,850 --> 00:41:31,840
+ممكن يجين من غل العظاميعني لو أخدت عظام بقر أو
+
+484
+00:41:31,840 --> 00:41:35,660
+غيره أو غيراته غالق مع بعض التحولات الكيميائية في
+
+485
+00:41:35,660 --> 00:41:39,560
+نهاية بالتهب جيلاتين الآن الإشكالية أنه في أوروبا
+
+486
+00:41:39,560 --> 00:41:45,080
+العظام اللي مشهورة أكتر هي عظام إيش؟ الخنزير وبناء
+
+487
+00:41:45,080 --> 00:41:49,440
+على ذلك جزء كبير من الجيلاتين اللي موجود عندهم
+
+488
+00:41:49,440 --> 00:41:56,880
+طالع من وين؟ طالع من الخنزير لكن على رأي كثير من
+
+489
+00:41:56,880 --> 00:42:01,790
+العلماءومنهم الدكتور القرضاوي وشيخ حسام الدين
+
+490
+00:42:01,790 --> 00:42:06,790
+عفانى والمقالات كثيرة وموجودة بأنه قد حصل على هذه
+
+491
+00:42:06,790 --> 00:42:10,410
+المواد حتى أخدناها جيلاتين ما خدناهاش زيمية ما
+
+492
+00:42:10,410 --> 00:42:13,610
+خدناهاش عضم اعملنا تفاعلات كيميائية لحد ما حصلنا
+
+493
+00:42:13,610 --> 00:42:17,910
+على الجيلاتين فالجيلاتين بيعتبروا قد طهرة بالتحول
+
+494
+00:42:17,910 --> 00:42:23,330
+حتى لو كان من إيش؟ حتى لو كان من عظام الخنزير وهذا
+
+495
+00:42:23,330 --> 00:42:28,880
+الدارج في الفتوىواضح؟ الجيلاتين حتى لو كان من عظام
+
+496
+00:42:28,880 --> 00:42:34,740
+الخنزير فهو قد طهر بالتحول على رأي كثير جدا،
+
+497
+00:42:34,740 --> 00:42:38,720
+والغالب من العلماء اللي ناقشوا هذا الموضوع والنقاش
+
+498
+00:42:39,360 --> 00:42:44,000
+فقه موجود كثير ومنشور في كتب و بجلات و بفتوى على
+
+499
+00:42:44,000 --> 00:42:47,600
+الانترنت أفهمتوا إيش يعني التطهر بالتحول؟ لأنه
+
+500
+00:42:47,600 --> 00:42:51,940
+المادة تغيرت أنا عملت عليه تفاعلات، غيرته واضح أنا
+
+501
+00:42:51,940 --> 00:42:55,420
+عملت عليه تفاعلات، ماخدتوش زي ما هو زي ما عملت على
+
+502
+00:42:55,420 --> 00:43:00,450
+الكحول تفاعلات خلته في الآخر إيش؟ خلالآن هذه
+
+503
+00:43:00,450 --> 00:43:06,010
+العملية عملية إيش؟ أكسدة المحاضرة الجاية بنعود
+
+504
+00:43:06,010 --> 00:43:09,490
+نحكي عن الأكسدة من ناحية كيميائية يعني هنا إحنا
+
+505
+00:43:09,490 --> 00:43:14,530
+اتكلمنا عن الأكسدة من ناحية ثقافية خليني أقول
+
+506
+00:43:14,530 --> 00:43:19,750
+كثقافة تفهموا إيش يعني الأكسدة؟ الآن كعوامل مؤكسدة
+
+507
+00:43:19,750 --> 00:43:21,970
+وكيمية في المحاضرة الجاية إن شاء الله
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..9e270f68f83bf9bddad16a1290f3f5bcebeb401e
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8.srt
@@ -0,0 +1,1955 @@
+1
+00:00:05,080 --> 00:00:09,300
+اليوم إن شاء الله بنكمل تقريباً الجزء الأخير في هذا
+
+2
+00:00:09,300 --> 00:00:18,060
+الفصل لما قلنا موضوعنا ال alkyl halides ال R X و
+
+3
+00:00:18,060 --> 00:00:23,460
+بشكل أساسي تفاعلاتهم حكينا أنه فيه تفاعلين أساسيين
+
+4
+00:00:23,460 --> 00:00:27,960
+إما أن تتم عملية إبدال لل X substitution وهذه
+
+5
+00:00:27,960 --> 00:00:32,760
+درسناها بالتفصيل وأخذنا different mechanisms SN1
+
+6
+00:00:32,760 --> 00:00:38,680
+و SN2 mechanismsالآن الاحتمال الثاني أن ال X يتم
+
+7
+00:00:38,680 --> 00:00:43,500
+حذفها مع بروتون  elimination of HX في هذه
+
+8
+00:00:43,500 --> 00:00:48,840
+الحالة لما أحذف ال X مع بروتون يتكون عندي double
+
+9
+00:00:48,840 --> 00:00:54,340
+bond بمعنى أن ال alkyl halides يعطوننا ال alkenes
+
+10
+00:00:54,340 --> 00:01:01,640
+ال alkyl halides يعطوننا ال alkenes هل لازم تلاحظوا نقطة أن 
+
+11
+00:01:01,640 --> 00:01:08,300
+هدول التفاعلين تفاعلين خلّينا نقول تنافسيين يعني
+
+12
+00:01:08,300 --> 00:01:14,100
+ممكن الاثنين يحصلوا ولو بنسب متفاوتة في نفس الوقت
+
+13
+00:01:14,100 --> 00:01:19,880
+يعني بيطلع عندي ناتج هو عبارة عن خليط من تفاعل
+
+14
+00:01:19,880 --> 00:01:26,500
+إبدال وتفاعل حذف يعني لو مثلاً أخذت هذا المركب
+
+15
+00:01:26,500 --> 00:01:30,620
+اللي هو two bromopropane أو isopropyl bromide اللي
+
+16
+00:01:30,620 --> 00:01:36,620
+مر علينا وقلت بدي أفعله مع ال NaOH واضح؟
+
+17
+00:01:36,620 --> 00:01:42,350
+ممكن يصير عندي إبدال لل brom بال OH يعطينا ال
+
+18
+00:01:42,350 --> 00:01:46,510
+alcohol ال isopropyl alcohol وممكن يصير عندي
+
+19
+00:01:46,510 --> 00:01:51,050
+عملية حذف لبروم مع إلكتروناتها لاحظوا الحذف ليش
+
+20
+00:01:51,050 --> 00:01:56,490
+بيكون لبروم مع إلكتروناتها زائد واحدة من ال
+
+21
+00:01:56,490 --> 00:02:00,350
+hydrogens بهذا الشكل بدون إلكترونات طبعاً لما بدي
+
+22
+00:02:00,350 --> 00:02:04,010
+أحذف هذه ال hydrogen بدون إلكترونات طب زوج
+
+23
+00:02:04,010 --> 00:02:08,230
+الإلكترونات اللي عامل bond معاها شو هيعمل؟ هو اللي
+
+24
+00:02:08,230 --> 00:02:14,230
+حيلف يعمل ال double bond واضح فبيصير عملية حدث HBr
+
+25
+00:02:14,230 --> 00:02:20,310
+كأن بظبط بقول H plus Br minus لكنه بيطلعش أيوني
+
+26
+00:02:20,310 --> 00:02:23,910
+موليكيول موليكيول بيطلع موليكيولار موليكيول يعني
+
+27
+00:02:23,910 --> 00:02:28,230
+ال HBr مش جزء أيوني ما بنقدرش نقول أن صيغته
+
+28
+00:02:28,230 --> 00:02:32,150
+الكيميائية H plus Br minus اللي هو جزء equivalent
+
+29
+00:02:33,090 --> 00:02:38,170
+bond موليكيولار موليكيول واضح الآن لما بيحذف ال HBr
+
+30
+00:02:38,170 --> 00:02:42,910
+بيصير عنده elimination طبعاً هذا الكلام هيعمل عندكم
+
+31
+00:02:42,910 --> 00:02:48,510
+مشكلة نوعاً ما أنه لو أنا بدي آجي أسألكم إيش الناتج
+
+32
+00:02:48,510 --> 00:02:54,360
+اللي بدكم تحطوه واضح؟ غالباً الناتج خليط من هذه
+
+33
+00:02:54,360 --> 00:02:59,880
+المركبين واضح وإن كان ممكن يزيد في حالات معينة
+
+34
+00:02:59,880 --> 00:03:02,760
+تفاعل ال substitution ويكون تفاعل ال elimination
+
+35
+00:03:02,760 --> 00:03:07,020
+قليل وممكن في حالات ثانية تكون نسبة ال elimination
+
+36
+00:03:07,020 --> 00:03:11,780
+عالية ويكون نسبة ال substitution قليل وفي حالات
+
+37
+00:03:11,780 --> 00:03:15,700
+ثالثة ممكن تلاقوهم مثلاً بنسبة أربعين لستين في
+
+38
+00:03:15,700 --> 00:03:19,380
+المية أو خمسين لخمسين في المية يكون الناتجين وبنسب
+
+39
+00:03:19,380 --> 00:03:26,140
+تكاد تكون متساوية هذا بالحقيقة بيعتمد على عوامل كثيرة
+
+40
+00:03:26,140 --> 00:03:29,980
+أن يصير الناتج اللي عنده elimination أو
+
+41
+00:03:29,980 --> 00:03:34,660
+substitution بيعتمد على عدة عوامل لاحظوا أنا مثلاً
+
+42
+00:03:34,660 --> 00:03:40,280
+ذاكرلكم أربعة أنواع من العوامل العامل الأول ال
+
+43
+00:03:40,280 --> 00:03:46,240
+type of alkyl halide نوع ال alkyl halide بشكل عام
+
+44
+00:03:46,240 --> 00:03:50,800
+بشكل عام لما يكون عنده primary alkyl halide
+
+45
+00:03:50,800 --> 00:03:55,720
+primary primary alkyl halide وبالذات ممكن هنا
+
+46
+00:03:55,720 --> 00:04:01,160
+نضيف زائد strong nucleophile strong nucleophile
+
+47
+00:04:01,160 --> 00:04:07,400
+التفاعل الأساسي إيش بيكون substitution غالباً
+
+48
+00:04:07,400 --> 00:04:12,840
+التفاعل بنسبته الكبيرة جداً جداً substitution وهذا
+
+49
+00:04:12,840 --> 00:04:17,660
+ال substitution كمان بيكون in SN2 mechanism واضح
+
+50
+00:04:17,660 --> 00:04:23,040
+طيب واحدة ممكن تقول لو كان عنده ال primary alkyl
+
+51
+00:04:23,040 --> 00:04:27,840
+halide مع weakened nucleophile ال primary alkyl
+
+52
+00:04:27,840 --> 00:04:32,450
+halide مع weakened nucleophile غالباً ما يتفاعل واضح؟
+
+53
+00:04:32,450 --> 00:04:35,370
+الـ Primary Alkyl Halide لو بدأ أضعه على الجهة
+
+54
+00:04:35,370 --> 00:04:40,570
+الثانية زي الـ weak nucleophile غالباً ما بيصيرش
+
+55
+00:04:40,570 --> 00:04:46,490
+نتيجة لا حتى تفاعل إبدال بشكل كامل ولا تفاعل
+
+56
+00:04:46,490 --> 00:04:51,490
+elimination واضح؟ الآن لما يكون عنده secondary ال
+
+57
+00:04:51,490 --> 00:04:55,330
+secondary هو دائماً اللي فيه الاحتمالين عاليين
+
+58
+00:04:55,330 --> 00:04:59,750
+بيكون عنده Substitution و Elimination
+
+59
+00:05:27,300 --> 00:05:33,300
+أنا بقدر أفعله مع الاثنين بقدر أفعله مع ال strong
+
+60
+00:05:33,300 --> 00:05:39,380
+وبقدر أفعله مع weak nucleophile الآن أنتم أخذتم
+
+61
+00:05:39,380 --> 00:05:43,080
+أن ال tertiary alkyl halide مع ال weak nucleophile
+
+62
+00:05:43,080 --> 00:05:48,590
+من اللي بيعمل substitution بأسهم واحدة هذا الكلام
+
+63
+00:05:48,590 --> 00:05:52,870
+صحيح ال tertiary alkyl halide مع ال weak nucleophile
+
+64
+00:05:52,870 --> 00:05:57,410
+بشكل أساسي بيعمل substitution أعلى بـ SN1 ولما يكون
+
+65
+00:05:57,410 --> 00:06:03,510
+tertiary مع strong nucleophile بيعمل elimination
+
+66
+00:06:03,510 --> 00:06:07,410
+طبعاً
+
+67
+00:06:07,410 --> 00:06:11,480
+ال elimination ما أخذناش الميكانزم قليل حتى الآن
+
+68
+00:06:11,480 --> 00:06:14,520
+هناخذه بعد شوية لما نأخذه بس عشان أنا الجدول
+
+69
+00:06:14,520 --> 00:06:17,640
+يكتمل معكم هتلاحظوا أنه بنقوله بيعمل elimination
+
+70
+00:06:17,640 --> 00:06:24,020
+ال E2 mechanism بنتعلم بعد شوية إيش معناه؟ E2 
+
+71
+00:06:24,020 --> 00:06:30,500
+Mechanism تقريباً هيك الأمور بتصير سهلة الجزء اللي
+
+72
+00:06:30,500 --> 00:06:35,700
+احنا كنا ماخدينه حتى ما تحسوش أن العلم فيه تناقض
+
+73
+00:06:35,700 --> 00:06:39,840
+احنا كنا ماخدينه أن ال primary alkyl halide مع ال
+
+74
+00:06:39,840 --> 00:06:43,620
+strong nucleophile مين اللي بيعمل substitution وب
+
+75
+00:06:43,620 --> 00:06:47,920
+SN2 هذا الكلام كنا ماخدينه وكنا ماخدينه أن ال
+
+76
+00:06:47,920 --> 00:06:51,500
+tertiary alkyl halide مع ال weak nucleophile مين
+
+77
+00:06:51,500 --> 00:06:56,940
+اللي بيعمل substitution ب SN1 الآن يمكن نضيفها لأن
+
+78
+00:06:56,940 --> 00:07:01,200
+ال primary مع ال weak nucleophile غالباً ما فيش
+
+79
+00:07:01,200 --> 00:07:07,000
+تفاعل والـ tertiary مع الـ strong الـ nucleophile
+
+80
+00:07:07,000 --> 00:07:14,460
+بيعمل إيقاف بميكانيزم E2 تقريباً يمكن هذا أكثر أو
+
+81
+00:07:14,460 --> 00:07:18,880
+من أكثر العوامل اللي بتأثر على التفاعل أن نشوف الـ
+
+82
+00:07:18,880 --> 00:07:21,580
+Alkyl Halide اللي عندنا primary أو secondary أو
+
+83
+00:07:21,580 --> 00:07:27,640
+tertiary وال nucleophile weak أو strong والنتائج
+
+84
+00:07:27,640 --> 00:07:32,200
+موجودة عندكم ابتيجي عوامل أخرى تأثيرها أقل من هدول
+
+85
+00:07:32,200 --> 00:07:36,340
+يعني العوامل الأساسية زي لما أخذنا الميكانيزم كنا
+
+86
+00:07:36,340 --> 00:07:42,800
+بشكل أساسي نركز نوع ال alkyl halide نوع ال nucleophile
+
+87
+00:07:42,800 --> 00:07:48,480
+واضح نوع ال alkyl halide ونوع ال nucleophile
+
+88
+00:07:49,530 --> 00:07:53,750
+واضح؟ زي نفترض اثنين أصدقاء بدوا يكون بينهم علاقة
+
+89
+00:07:53,750 --> 00:07:58,890
+أحمد ومحمد أكتر شيء بيحدد هذه العلاقة أحمد ومحمد
+
+90
+00:07:58,890 --> 00:08:04,050
+هذا ما بيمنعش أنه في ظروف خارجية موجودة ممكن أنها
+
+91
+00:08:04,050 --> 00:08:07,370
+تأثر على هذا الكلام لكن إيش الشيء الأساسي اللي
+
+92
+00:08:07,370 --> 00:08:14,520
+بيأثر؟ اللي هم نفس الأساسية نفس المتفاعلين الآن من
+
+93
+00:08:14,520 --> 00:08:18,620
+الأشياء الأساسية الإضافية اللي ممكن تأثر هي ال
+
+94
+00:08:18,620 --> 00:08:22,620
+solvent أنا أي تفاعل بعمله ب solvent لاحظوا معي لو
+
+95
+00:08:22,620 --> 00:08:26,760
+كنت مثلاً تفاعل عمله ب water بمية المية بتشجع ال
+
+96
+00:08:26,760 --> 00:08:30,500
+substitution لو كنت عامله ب more polar solvent زي
+
+97
+00:08:30,500 --> 00:08:35,310
+ethanol ال ethanol بتشجع ال elimination هاي معلومات
+
+98
+00:08:35,310 --> 00:08:39,190
+بالتجربة إيش نسبها ما إلى ذلك ما بنقدرش كل شغلة
+
+99
+00:08:39,190 --> 00:08:44,710
+ندخل فيها درجة الحرارة مثلاً الحرارة كل ما كانت
+
+100
+00:08:44,710 --> 00:08:49,690
+مرتفعة في أثناء التفاعل بتشجع ال elimination ال
+
+101
+00:08:49,690 --> 00:08:53,350
+concentration بالذات إذا كان عنده strong
+
+102
+00:08:53,350 --> 00:08:57,630
+nucleophile أو strong base يعني لما أنا بدي آجي
+
+103
+00:08:57,630 --> 00:09:00,790
+أحط هنا strong زي ما أخذ ال KOH مثلاً
+
+104
+00:09:03,410 --> 00:09:08,770
+هذا قوي وأكون بفعله مع الـ tertiary هيشجع بشكل
+
+105
+00:09:08,770 --> 00:09:14,350
+كبير ال elimination ال concentration of sodium or
+
+106
+00:09:14,350 --> 00:09:19,090
+potassium hydroxide تركيز عالية منه بتشجع ال
+
+107
+00:09:19,090 --> 00:09:24,370
+elimination بشكل أساسي في حالة ما يكون التفاعل مع
+
+108
+00:09:24,370 --> 00:09:28,570
+ال tertiary مع ال primary بيظل تفاعلنا الأساسي إيش
+
+109
+00:09:28,570 --> 00:09:35,270
+ال substitution على أي حال، هنا يعني بتحسوا أنه
+
+110
+00:09:35,270 --> 00:09:41,790
+الكلام كثير وشوية بلخم، قد يظن البعض أنه بده يقول
+
+111
+00:09:41,790 --> 00:09:47,030
+فصل، بصراحة لازم تكونوا عارفين أن الدنيا ما بتمشيش
+
+112
+00:09:47,030 --> 00:09:57,090
+دائماً بقول فصل أنه في أشياء هي هيك مش واضحة يعني في
+
+113
+00:09:57,090 --> 00:10:01,070
+النهاية لازم أعمل تجربة لحد ما أعرف النتيجة بالظبط
+
+114
+00:10:01,070 --> 00:10:06,910
+يعني مش كل شيء بيكون مثالي وبنقدر نحكم عليه بشكل
+
+115
+00:10:06,910 --> 00:10:12,090
+مثالي غير في الآخر إيش الواقع والتجربة هي اللي
+
+116
+00:10:12,090 --> 00:10:15,770
+بتطلع النتيجة النهائية يعني كلكم أنا متأكد مليون
+
+117
+00:10:15,770 --> 00:10:19,410
+في المية داخلين على مساق ال organic chemistry بنية
+
+118
+00:10:19,410 --> 00:10:23,610
+صادقة في الدراسة وبنية صادقة بتحصيل علامة 100 من
+
+119
+00:10:23,610 --> 00:10:29,470
+100 الآن هذا الوضع المثالي أن أنتم بتحضروا عندكم
+
+120
+00:10:29,470 --> 00:10:33,730
+الكتب بتدرسوا بتسمعوا المحاضرة بدكم تأخذوا 100 من
+
+121
+00:10:33,730 --> 00:10:37,710
+100 الآن إيش أرض الواقع؟ الله يعيدكم وأقولكم بس
+
+122
+00:10:37,710 --> 00:10:43,850
+واضح مش دائماً الواقع بيطلع مثالي وبالتالي هلما
+
+123
+00:10:43,850 --> 00:10:47,650
+أقولكم ممكن هيك ممكن هيك ممكن هيك أنتم في الحياة
+
+124
+00:10:47,650 --> 00:10:51,810
+الاجتماعية لو ناقشنا أي موضوع مش بتقول والله ممكن
+
+125
+00:10:51,810 --> 00:10:55,810
+هيك ممكن هيك ممكن هيك في شيء دائماً هيك واضح و
+
+126
+00:10:55,810 --> 00:11:02,010
+clear cut هيك طبيعة إيش طبيعة الحياة الآن لو أتينا
+
+127
+00:11:02,010 --> 00:11:08,170
+بدنا ندرس ال mechanisms of elimination واضح؟ لو
+
+128
+00:11:08,170 --> 00:11:14,890
+أخذنا ال E2 mechanism ال E2 mechanism ال E2 mechanism
+
+129
+00:11:14,890 --> 00:11:19,590
+دائماً بتتم في حالة ما يكون عنده strong base وأكثر
+
+130
+00:11:19,590 --> 00:11:22,930
+إيش يقولنا لما يكون عنده strong base مع tertiary
+
+131
+00:11:22,930 --> 00:11:27,210
+يعني بدكم تعملوها زي فتوى شرقية أنه ال mechanism
+
+132
+00:11:27,210 --> 00:11:32,890
+إيش ال E2 mechanism ال E2 تقريباً شبيه بال SN2
+
+133
+00:11:32,890 --> 00:11:42,170
+إذا بتذكروا ال SN2 كانت one step mechanism مظبوط
+
+134
+00:11:42,170 --> 00:11:48,310
+ولا لأ وبنفس الوقت كانت ال kinetics تبعتها معتمدة
+
+135
+00:11:48,310 --> 00:11:52,970
+على متفاعلين يعني ال rate تبعها بيساوي تركيز ال
+
+136
+00:11:52,970 --> 00:11:57,590
+alkyl halide في تركيز ال nucleophile ال OH minus
+
+137
+00:11:57,590 --> 00:12:02,850
+وفيها نوع من المصارعة بين متفاعلين مش واحد واقف
+
+138
+00:12:02,850 --> 00:12:07,070
+بتفرج والثاني بيتفعل هذا الكلام وين شفته في ال SN1
+
+139
+00:12:07,070 --> 00:12:13,720
+الآن ال E2 في هذه الشغلة موازية لل SN2 ال E2
+
+140
+00:12:13,720 --> 00:12:21,040
+موازية لل SN2 لما بيجي ال OH- لما بيجي ال OH- وبده
+
+141
+00:12:21,040 --> 00:12:26,360
+يتفاعل لاحظوا هنا ال OH- عبارة عن negative
+
+142
+00:12:26,360 --> 00:12:32,240
+charge و negative charge أسرع ما يمكن أسرع ما يمكن
+
+143
+00:12:32,240 --> 00:12:38,560
+بدها إيش؟ بدها positive دائماً ال negative أسرع ما
+
+144
+00:12:38,560 --> 00:12:44,000
+يمكن بدها positive الآن لو إجينا سألنا أنفسنا و
+
+145
+00:12:44,000 --> 00:12:48,360
+خلينا نأخذ التفصيل اللي تحت يترى وين ال positive
+
+146
+00:12:48,360 --> 00:12:54,220
+ممكن تلاقيها ال OH minus ممكن تلاقي ال carbon هادي
+
+147
+00:12:55,760 --> 00:12:59,600
+واضح؟ ممكن تلاقي ال carbon هذه اللي هنا مشكلة
+
+148
+00:12:59,600 --> 00:13:03,780
+أنها partially positive وهذه البرومين partially
+
+149
+00:13:03,780 --> 00:13:08,540
+negative إذا هي positive الآن في كمان positive
+
+150
+00:13:08,540 --> 00:13:11,100
+ثاني ال proton ال H
+
+151
+00:13:14,170 --> 00:13:18,530
+هذا ال H لحاله برضه يمثل إيش؟ positive ولو بده
+
+152
+00:13:18,530 --> 00:13:22,550
+يطلع لحاله يظل زوج الإلكترونات positive كامل إذا
+
+153
+00:13:22,550 --> 00:13:27,510
+ال OH هذه اللي جاية وبتبحث عن positive صار عندها
+
+154
+00:13:27,510 --> 00:13:32,710
+ال H عبارة عن positive وال carbon اللي هنا عبارة
+
+155
+00:13:32,710 --> 00:13:38,810
+عن positive واضح؟ إذا هاجمت على ال carbon اللي هنا
+
+156
+00:13:38,810 --> 00:13:45,860
+هيبدأ يصير عندي خمس روابط حتوت رد ال Br هيصير عند
+
+157
+00:13:45,860 --> 00:13:51,760
+ال SN2 mechanism هيصير عند ال substitution الإبدال
+
+158
+00:13:51,760 --> 00:13:57,300
+بمعنى لو أنا بدي آجي أقول هي ال OH- هاجمت هنا وطردت
+
+159
+00:13:57,300 --> 00:14:03,580
+ال Cl أي تفاعل بدي يصير الإبدال أنه مكان مكان
+
+160
+00:14:03,580 --> 00:14:10,720
+عندي ال Cl صار عنده OH طيب لو هذه هاجمت على ال
+
+161
+00:14:10,720 --> 00:14:15,820
+hydrogen هنا أخذت بس ال H لحالها بدون أزواج
+
+162
+00:14:15,820 --> 00:14:20,440
+الإلكترونات شو بده يصير لزوج الإلكترونات هذا؟ بده
+
+163
+00:14:20,440 --> 00:14:23,300
+يكوّن double bond مجرد ما يبدأ يكوّن double bond
+
+164
+00:14:23,300 --> 00:14:28,920
+كم bond بيصير عندي هنا؟ خمسة عشان نتخلص منهم ال
+
+165
+00:14:28,920 --> 00:14:34,000
+Br بتطلع إذا في خطوة واحدة الميكانيزم ببساطة أنه
+
+166
+00:14:34,000 --> 00:14:40,400
+في خطوة واحدة ال OH- بتيجي مع ال H صار هذا زوج
+
+167
+00:14:40,400 --> 00:14:49,190
+إلكترونات بيلوف بهذا الشكل عشان ما يصيبش خمسة بتطلع
+
+168
+00:14:49,190 --> 00:14:56,350
+ال Br طبعاً هنا لاحظوا أنه هيطلع عندي Br minus وال
+
+169
+00:14:56,350 --> 00:15:01,090
+Br minus معاكش بده يصفق ال Br minus عفواً مع ال
+
+170
+00:15:01,090 --> 00:15:05,550
+sodium ماهي ال OH minus إيش بيكون معها Sodium أو
+
+171
+00:15:05,550 --> 00:15:11,060
+Potassium يعني تخيلوا كانت يا K plus يعني إيه a a
+
+172
+00:15:11,060 --> 00:15:15,040
+plus و a H minus فال Br minus هذه مع ال K plus
+
+173
+00:15:15,040 --> 00:15:19,660
+إيه بتعمل KBr وال H minus مع ال H plus
+
+174
+00:15:19,660 --> 00:15:24,900
+ماية إذا نتيجة هذا التفاعل أن ال H minus أخذت ال
+
+175
+00:15:24,900 --> 00:15:31,830
+H plus عملت المية الآن ال K plus مع ال Br تعمل
+
+176
+00:15:31,830 --> 00:15:38,850
+KBr وال Alkyl Halide شو صار؟ صار alkene صار alkene
+
+177
+00:15:38,850 --> 00:15:42,390
+لأن هنا التفاعل في خطوة واحدة بمعنى هذه بتاخد
+
+178
+00:15:42,390 --> 00:15:46,45
+
+201
+00:17:59,610 --> 00:18:05,420
+انتوا؟ مع الـ tertiary الـ OH- ما عندهاش وسع تصل
+
+202
+00:18:05,420 --> 00:18:10,900
+للكربون هذه الموجبة، بل الكربون مدفونة لما 
+
+203
+00:18:10,900 --> 00:18:17,540
+تتخيل أن هذا الكربون مثلا CH3 CHHH و هنا CH3 CHHH
+
+204
+00:18:17,540 --> 00:18:25,930
+كله محوط، قادرة تصل الـ positive المخفي اللي هناك لكن
+
+205
+00:18:25,930 --> 00:18:32,130
+بسهولة، بتصطدم بـ H بأي H plus لأن الـ H plus طرفية
+
+206
+00:18:32,130 --> 00:18:39,830
+الكربون مخفية، الواحد دايما بياخد من الاشي اللي على 
+
+207
+00:18:39,830 --> 00:18:46,650
+الطرف ولا من الاشي المخفي الآن زي ما حكينا عندنا
+
+208
+00:18:46,650 --> 00:18:52,740
+الـ OH minus بتبحث عن positive في positive مخبية
+
+209
+00:18:52,740 --> 00:18:57,180
+صعبة الوصول إليها وفي positive طرفية إن هي اللي
+
+210
+00:18:57,180 --> 00:19:00,700
+هتاخدها في حالة الـ tertiary الطرفية، فطالما أنه
+
+211
+00:19:00,700 --> 00:19:04,280
+خبطت في هذا الـ positive اللي على الطرف هنا، معنى
+
+212
+00:19:04,280 --> 00:19:09,440
+ذلك هتمشي أو تستكمل الميكانزم بـ E2 elimination
+
+213
+00:19:09,440 --> 00:19:13,500
+هيكون التفاعل بشكل أساسي elimination لكن لو هذه
+
+214
+00:19:13,500 --> 00:19:18,980
+كانت primary H OH في وسع كتير، في وسع كتير للـ OH
+
+215
+00:19:18,980 --> 00:19:23,600
+minus تجي وتتفاعل فبتتم عملية الـ substitution
+
+216
+00:19:23,600 --> 00:19:30,500
+الآن لو سألناكم على .. لو سألناكم على هذا الكلام
+
+217
+00:19:30,500 --> 00:19:37,860
+رغم أنه يبدو كلام كيميائي فيه، له كمان دليل شرعي؟
+
+218
+00:19:37,860 --> 00:19:46,360
+آه، في الشريعة، ما هي الكيمياء زي الشريعة آه لأن طبعا
+
+219
+00:19:48,300 --> 00:19:52,720
+أيوه، وين بيربطوا المفاهيم العلمية بالإنسانية؟
+
+220
+00:19:52,720 --> 00:20:03,320
+الاشي بياخد اللي على الطرف ولا اللي في النص؟ إنما
+
+221
+00:20:03,320 --> 00:20:08,280
+يأكلوا الذئبة من الغنم القاصية، الذئب لما بيجي يعمل
+
+222
+00:20:08,280 --> 00:20:12,120
+abstraction احنا هنا بناخد حاجة، بنتفاعل مع حاجة
+
+223
+00:20:12,120 --> 00:20:15,860
+بيجي الذئب على غنمة في وسط القطيع ولا على اللي شرد
+
+224
+00:20:15,860 --> 00:20:20,900
+على برة؟ على اللي شارد لبرا، مظبوط ولا لأ؟ دايما 
+
+225
+00:20:20,900 --> 00:20:25,660
+اللي متطرف وشارد لبرا هو اللي بيجي الذئب بيأكله،
+
+226
+00:20:25,660 --> 00:20:28,660
+مظبوط ولا لأ؟ الآن هذه الـH، ما شاء الله عليها،
+
+227
+00:20:28,660 --> 00:20:33,260
+طرفية، وهذا الـcarbon في حالة الـ tertiary مخفية،
+
+228
+00:20:33,260 --> 00:20:39,950
+مدفونة، ما هو الأسهل للـ OH-؟ أن تأخذ الاشي الخارجي
+
+229
+00:20:39,950 --> 00:20:45,870
+الطرفي ولذلك هذا التعليل أنه ليش الـ tertiary مع 
+
+230
+00:20:45,870 --> 00:20:51,090
+الـ strong nucleophiles undergo mainly elimination
+
+231
+00:20:51,090 --> 00:20:57,030
+reaction with E2 mechanism because it can reach ..
+
+232
+00:20:57,030 --> 00:21:02,840
+طبعا هذا secondary هذا اللي هنا secondary، تخيلوا لو
+
+233
+00:21:02,840 --> 00:21:07,800
+كان tertiary، بتكون العملية أصعب، it can reach the
+
+234
+00:21:07,800 --> 00:21:16,220
+H plus easier than the carbon plus واضح؟ بتقدر تصل
+
+235
+00:21:16,220 --> 00:21:21,900
+للـ H Plus أسهل ما تصل لـ Carbon واضح؟ ولهذا احنا
+
+236
+00:21:21,900 --> 00:21:25,000
+كتبنا الجملة إنه لما يكون عندنا tertiary alkyl
+
+237
+00:21:25,000 --> 00:21:29,940
+halide مع strong base زي الـ KOH التفاعل بشكل أساس
+
+238
+00:21:29,940 --> 00:21:37,180
+الـ main reaction is elimination الآن هنا بتجينا
+
+239
+00:21:37,180 --> 00:21:46,810
+شغلة مرة تانية، موجودة عندنا بمثل بيقول خيره خيره، واضح
+
+240
+00:21:46,810 --> 00:21:50,690
+الكلام نفسه بيجي مرات و بيواجهنا بالكيمياء لو
+
+241
+00:21:50,690 --> 00:21:54,930
+افترضنا عند هذا المركب .. لو افترضنا عند هذا المركب
+
+242
+00:21:54,930 --> 00:22:02,630
+one two three four two promo بيوتين وأنا بدي أعمل
+
+243
+00:22:02,630 --> 00:22:06,550
+تفاعل مع الـ OH- مركز إنه أشوف ناتج الـ elimination
+
+244
+00:22:06,550 --> 00:22:11,250
+احنا قلنا أكيد بزام بنحكي عن elimination بده تطلع
+
+245
+00:22:11,250 --> 00:22:16,950
+الـ PR مع إلكتروناتها الـ OH على كربونة مجاورة، دائما الـ
+
+246
+00:22:16,950 --> 00:22:21,470
+H من وين بتطلع؟ مش من نفس الكربون، من الكربونة
+
+247
+00:22:21,470 --> 00:22:24,870
+المجاورة عشان تعمل double bond الآن هنا بنلاحظ
+
+248
+00:22:24,870 --> 00:22:28,590
+عندي احتمال ايه؟ إنه هذه الكربون، هذه الكربون اللي 
+
+249
+00:22:28,590 --> 00:22:32,960
+هنا في عندها احتمال هنا وفي عندها احتمال هذا لو 
+
+250
+00:22:32,960 --> 00:22:38,360
+أتت الـ OH اخدت هذا الـ H شو بيصير عندي؟ هاي البودة
+
+251
+00:22:38,360 --> 00:22:42,060
+هاتيجي وتعمل double bond هاتيجي وتعمل double
+
+252
+00:22:42,060 --> 00:22:43,040
+bond هاتيجي وتعمل double bond هاتيجي وتعمل
+
+253
+00:22:43,040 --> 00:22:44,660
+double bond هاتيجي وتعمل double bond هاتيجي و
+
+254
+00:22:44,660 --> 00:22:46,540
+تعمل double bond هاتيجي وتعمل double bond هاتيجي
+
+255
+00:22:46,540 --> 00:22:47,780
+تعمل double bond هاتيجي وتعمل double bond هاتيجي
+
+256
+00:22:47,780 --> 00:22:52,400
+وتعمل double bond
+
+257
+00:22:55,920 --> 00:23:01,360
+بيطلع عنده ألوان بيوتين إذا أنا في عندي جنب الـ PR
+
+258
+00:23:01,360 --> 00:23:07,300
+من الجهتين اتشز وين بده يكون الاختيار إنه بيطلع
+
+259
+00:23:07,300 --> 00:23:11,740
+بشكل أعلى، هنا في عندنا قاعدة بتقول لما يكون عند
+
+260
+00:23:11,740 --> 00:23:17,320
+هذا النمط من الاختيار، مش دايما موجود، هذا النمط
+
+261
+00:23:17,320 --> 00:23:22,440
+يعني مرات ما بيكونش غير نوع واحد فقط من الهيدروجين
+
+262
+00:23:22,440 --> 00:23:27,580
+وما بيكون إلا احتمال واحد للناتج، مرات بيكون عنده 
+
+263
+00:23:27,580 --> 00:23:32,420
+احتمالين ومرات بيكون عنده تلاتة، يعني لو اتخيلتوا
+
+264
+00:23:32,420 --> 00:23:35,760
+مثلا أن هذا الكربون اللي حاملة الـ PR حاملة هنا كمان 
+
+265
+00:23:35,760 --> 00:23:40,400
+كربون وعليها اتشز يا بده يطلع من هنا، يا من هنا،
+
+266
+00:23:40,400 --> 00:23:44,060
+يا من الكربون الثالثة، بيصير عندي تلت احتمالات طب
+
+267
+00:23:44,060 --> 00:23:46,780
+لما يكون عندي احتمالين أو تلت احتمالات، أي 
+
+268
+00:23:46,780 --> 00:23:50,840
+الاحتمالات هو المفضل الحدث؟ عندنا قاعدة بسيطة
+
+269
+00:23:50,840 --> 00:23:57,220
+بيسموها the more substituted ال keen will form، الـ
+
+270
+00:23:57,220 --> 00:24:02,780
+keen اللي فيه substitution اكتر بيتكون، الآن بيصير
+
+271
+00:24:02,780 --> 00:24:09,320
+ايش معنى؟ more substituted ال keen واضح؟ عشان نعرف 
+
+272
+00:24:09,320 --> 00:24:12,900
+معنى more substituted ال keen يمكن لازم نكون
+
+273
+00:24:12,900 --> 00:24:18,120
+متذاكرين الـ unsubstituted ال keen، ال keen الغير مبدل
+
+274
+00:24:18,120 --> 00:24:23,080
+ايش هو ال keen الغير مبدل اللي بنسميه الـ parent
+
+275
+00:24:23,080 --> 00:24:28,320
+ال keen في الكينز ايش بنسميه الـ parent ال keen، الـ
+
+276
+00:24:28,320 --> 00:24:33,360
+parent يعني ال keen الأساسي اللي هو الـ unsubstituted
+
+277
+00:24:33,360 --> 00:24:34,160
+معنى parent
+
+278
+00:24:36,900 --> 00:24:41,000
+unsubstituted ما فيش عليه ولا ابدال، ابو ال keenز 
+
+279
+00:24:41,000 --> 00:24:45,760
+كلها هو الايثيلين اللي ما فيش عليه ولا ابدال واضح
+
+280
+00:24:45,760 --> 00:24:53,100
+فالـ parent ال keen لما يكون عندي C double bond C H H
+
+281
+00:24:53,100 --> 00:25:00,580
+H H كم هيدروجينة عندي اربع، في أي واحدة منهم ابدلت
+
+282
+00:25:01,580 --> 00:25:06,860
+بزام كله هيدروجينز، إذا هذا هو الـ parent، الابو، 
+
+283
+00:25:06,860 --> 00:25:11,620
+ما فيش فيه ولا ابدال، عرفتوا ايش معنى parent؟ طيب
+
+284
+00:25:11,620 --> 00:25:15,080
+لو بدي اجي اقولكم مثلا في الـ aromatic compounds، 
+
+285
+00:25:15,080 --> 00:25:20,200
+ايش الـ parent aromatic compound؟ البنزين عليه ستة
+
+286
+00:25:20,200 --> 00:25:25,360
+هيدروجينات، ممكن ابدل منهم واحدة بيصير mono
+
+287
+00:25:25,360 --> 00:25:30,320
+substitute، ممكن نتين تراي substitute، ممكن تلاتة 
+
+288
+00:25:30,320 --> 00:25:36,700
+ممكن اربعة تترا substitute وهاكذا الآن الايثيلين
+
+289
+00:25:36,700 --> 00:25:40,780
+is the parent compound the unsubstituted compound
+
+290
+00:25:40,780 --> 00:25:48,220
+الآن ممكن أبدأ أعمل عمليات ابدال للهيدروجين، لو اجيت
+
+291
+00:25:48,220 --> 00:25:53,840
+شيلت هيدروجين وحطيت بدالها R بيصير هذا كم
+
+292
+00:25:53,840 --> 00:25:58,400
+substitution فيه؟ واحد .. one substitution لو من
+
+293
+00:25:58,400 --> 00:26:02,780
+أي مكان شيلت كمان هيدروجين وحطيت كمان R؟ die
+
+294
+00:26:02,780 --> 00:26:07,640
+substituted، لو شيلت كمان هيدروجين وحطيت كمان R
+
+295
+00:26:07,640 --> 00:26:12,580
+تالتة try substituted، لو شيلت كمان هيدروجين وحطيت
+
+296
+00:26:12,580 --> 00:26:19,280
+كمان R رابعة أنا ممكن أعمل على الايثيلين ابدال
+
+297
+00:26:19,280 --> 00:26:23,720
+لهيدروجين نتين تلاتة اربعة إذا صار عندي غير
+
+298
+00:26:23,720 --> 00:26:28,480
+المبدل اطلاقا وصار عندي اقصى ابدال على الايثيلين 
+
+299
+00:26:28,480 --> 00:26:35,090
+جداش اربعة اني ابدل الاربع هيدروجينات، الآن لما بدنا
+
+300
+00:26:35,090 --> 00:26:39,350
+نشوف أي ناتج بيطلع بنشوف كم ابدال عندنا لو لاحظنا
+
+301
+00:26:39,350 --> 00:26:44,650
+ناتج تم فيه اربع ابدالات والناتج التاني فيه
+
+302
+00:26:44,650 --> 00:26:49,370
+ابدالين، من المفضل اللي فيه اربعة لو ناتج فيه تلت 
+
+303
+00:26:49,370 --> 00:26:55,040
+ابدالات والتاني فيه ابدالين من المفضل التلاتة، نجي
+
+304
+00:26:55,040 --> 00:26:59,440
+نطلع على النواتج المكونة هنا واتخيلوا الـ etches
+
+305
+00:26:59,440 --> 00:27:03,040
+كأنها طالعة من الـ carbons تبعون الـ double bond و
+
+306
+00:27:03,040 --> 00:27:08,960
+نجي نسأل نفسنا في هذا المركب الـ one بيوتين كم
+
+307
+00:27:08,960 --> 00:27:15,020
+ابدال عنده؟ لاحظوا معي لو شطبت هذول الـ etches
+
+308
+00:27:15,020 --> 00:27:21,120
+موجودين، هاي etch، هاي etch، فيهم ابدال؟ وهاد الـ
+
+309
+00:27:21,120 --> 00:27:27,780
+etch موجودة، إذا كم ابدال عندي في هذا؟ واحد فقط
+
+310
+00:27:27,780 --> 00:27:32,820
+هنا في عندي one substitution من الاربع 
+
+311
+00:27:32,820 --> 00:27:38,840
+هيدروجينات، كم ضايل؟ ضايل تلاتة، ابدلت واحدة، إذا
+
+312
+00:27:38,840 --> 00:27:43,400
+هنا الـ substitution كم؟ واحد، لو اجيت هنا حوالي الـ
+
+313
+00:27:43,400 --> 00:27:49,880
+double bond، ايش في عندي؟ H وH كم ابدال عندي؟
+
+314
+00:27:49,880 --> 00:27:54,250
+اتنين إذا هذا المركب الـ two butane كم
+
+315
+00:27:54,250 --> 00:27:57,810
+substitution فيه؟ اتنين، والـ one butane كم
+
+316
+00:27:57,810 --> 00:28:02,750
+substitution فيه؟ واحد أي مركب اللي بتكون بنسبة
+
+317
+00:28:02,750 --> 00:28:07,970
+اعلى اللي هو الـ more substituted، إذا الـ two butane
+
+318
+00:28:07,970 --> 00:28:13,410
+will form more than the one butane because two
+
+319
+00:28:13,410 --> 00:28:16,510
+butane is more substituted فاهمتوا ايش معناه more
+
+320
+00:28:16,510 --> 00:28:22,270
+substituted؟ فدائما إذا في عندكم احتمالات إنه ممكن
+
+321
+00:28:22,270 --> 00:28:26,950
+هذا الالكين وهذا الالكين، بارسم اتنين بشوف إن هو 
+
+322
+00:28:26,950 --> 00:28:31,850
+الـ more substituted، بالتجربة لاحظوا كثيرا حتى
+
+323
+00:28:31,850 --> 00:28:35,170
+أصبحت قاعدة في النهاية إنه دائما الـ more
+
+324
+00:28:35,170 --> 00:28:39,840
+substituted ال keen هو اللي ايش هو اللي بيتكون، واضح
+
+325
+00:28:39,840 --> 00:28:44,020
+إذا كيف لما يكون عندي PR من أكثر من جهة Hydrogen
+
+326
+00:28:44,020 --> 00:28:50,140
+بارسم كل النواتج الممكنة وبشوف الـ more
+
+327
+00:28:50,140 --> 00:28:53,580
+substituted، الآن واحدة ممكن تقول ممكن التانية يطلع
+
+328
+00:28:53,580 --> 00:28:56,120
+هذا فيه two substitution وهذا two substitution
+
+329
+00:28:56,120 --> 00:29:01,640
+وقتها بطلع خليط شبه متساوي من مركبين، وقتها بطلع
+
+330
+00:29:01,640 --> 00:29:06,200
+خليط شبه متساوي من مركبين
+
+331
+00:29:18,410 --> 00:29:23,430
+بنجي للنوع التاني للنوع التاني من الـ elimination و
+
+332
+00:29:23,430 --> 00:29:27,370
+احنا قلنا هذا النوع التاني من الـ elimination اكتر 
+
+333
+00:29:27,370 --> 00:29:33,810
+اشي ممكن يواجهنا لما يكون في عندنا weak الـ
+
+334
+00:29:33,810 --> 00:29:38,730
+nucleophile او weak base، طالما weak nucleophile
+
+335
+00:29:38,730 --> 00:29:43,890
+اتفقنا احنا إنه الـ weak nucleophile بقدرش يعمل ولا 
+
+336
+00:29:43,890 --> 00:29:52,710
+شغلة بقعد يتفرج، ايش بستنى؟ باستثناء إن الـ Cl تفقد مع
+
+337
+00:29:52,710 --> 00:29:59,910
+إلكتروناته ويتكون عنده carbocation واضح؟ الآن هذا
+
+338
+00:29:59,910 --> 00:30:03,790
+ال carbocation هذا ال carbocation اللي اتكون عنده
+
+339
+00:30:03,790 --> 00:30:09,510
+ممكن يكمل التفاعل لـ substitution وممكن يكمل
+
+340
+00:30:09,510 --> 00:30:13,370
+التفاعل لـ elimination إذا اجا النيوكليوفايل هنا
+
+341
+00:30:13,370 --> 00:30:20,220
+وهاجم على الكاربون إذا جاء النيوكليوفايل وهاجم على 
+
+342
+00:30:20,220 --> 00:30:24,940
+الكاربون، ماذا سيحصل عنده؟ يبدأ النيوكليوفايل
+
+343
+00:30:24,940 --> 00:30:29,880
+باستخدام الـ SN1 طيب، هذا النيوكليوفايل بتطلع على
+
+344
+00:30:29,880 --> 00:30:34,970
+ايش؟ على الموجب وشاف الـ carbon موجبة، طيب وهذا الـ
+
+345
+00:30:34,970 --> 00:30:38,830
+nucleophile ممكن كما نشوف هنا الـ hydrogen كأنها
+
+346
+00:30:38,830 --> 00:30:44,090
+موجبة؟ ممكن آه، وبالتالي الـ nucleophile هذا لو اجا
+
+347
+00:30:44,090 --> 00:30:47,750
+واصطدم بالـ hydrogen واخد هيشال .. هيشال الـ
+
+348
+00:30:47,750 --> 00:30:53,390
+hydrogen، ايش بيترك لهنا؟ هيترك لل bond هذه وبتقول
+
+349
+00:30:53,390 --> 00:30:56,870
+له، فانا بتعمل double bond بيصير عندي الـ elimination
+
+350
+00:30:56,870 --> 00:31:05,230
+واضح؟ إذا بنقدر نستنتج إن الـ SN1 والـ E1 حقيقة
+
+351
+00:31:05,230 --> 00:31:12,930
+عبارة عن تفاعل بخطوتين، الخطوة الاولى منهم مشتركة
+
+352
+00:31:13,780 --> 00:31:21,500
+يعني both SN1 و E1 لديهم نفس الـ first step، لو كنا 
+
+353
+00:31:21,500 --> 00:31:27,380
+رسمين هدول هيك برسمة واحدة كأننا بيقول الـ first
+
+354
+00:31:27,380 --> 00:31:33,780
+step minus CL minus، فقدت الـ CL هذه، الـ first step 
+
+355
+00:31:33,780 --> 00:31:38,300
+مشتركة للتانتين، بعد ما تفقد الـ CL بيجي nucleophile 
+
+356
+00:31:38,300 --> 00:31:39,880
+على الـ positive بيعطيني
+
+357
+00:31:49,990 --> 00:31:57,450
+الخطوة الصعبة في هذا التفاعل هو
+
+358
+00:31:57,450 --> 00:32:05,460
+أن السالب يلتقي بالموجب، افصل هذا السالب عن الموجب 
+
+359
+00:32:05,460 --> 00:32:06,160
+أفصل هذا السالب عن الموجة افصل هذا السالب عن
+
+360
+00:32:06,160 --> 00:32:06,840
+الموجة افصل هذا السالب عن الموجة افصل هذا السالب
+
+361
+00:32:06,840 --> 00:32:08,960
+عن الموجة افصل هذا السالب عن الموجة افصل هذا
+
+362
+00:32:08,960 --> 00:32:10,700
+السالب عن الموجة افصل هذا السالب عن الموجة افصل
+
+363
+00:32:10,700 --> 00:32:13,040
+هذا السالب عن الموجة افصل هذا السالب عن الموجة
+
+364
+00:32:13,040 --> 00:32:14,160
+أفصل هذا السالب عن الموجة افصل هذا السالب عن
+
+365
+00:32:14,160 --> 00:32:14,960
+الموجة افصل هذا السالب عن الموجة افصل هذا السالب
+
+366
+00:32:14,960 --> 00:32:16,560
+عن الموجة افصل هذا السالب عن الموجة افصل هذا
+
+367
+00:32:16,560 --> 00:32:17,600
+السالب عن الموجة افصل هذا السالب عن الموجة افصل
+
+368
+00:32:17,600 --> 00:32:22,100
+هذا السالب عن الموجة افصل هذا السالب عن الموجة
+
+369
+00:32:22,100 --> 00:32:28,720
+أفصل هذا السالب عن الموجة
+
+370
+00:32:32,740 --> 00:32:41,100
+في بينهم Carbocation والـ rate تبعتهم بتعتمد على
+
+371
+00:32:41,100 --> 00:32:48,86
+
+401
+00:35:20,770 --> 00:35:24,710
+التفاعل يطرد حرارة وأن الـ Delta S تكون positive
+
+402
+00:35:24,710 --> 00:35:31,150
+أن التفاعل يزيد الفوضى، أفضل تفاعل على الإطلاق هو
+
+403
+00:35:31,150 --> 00:35:37,950
+الذي يطرد طاقة ويزيد الفوضى، بيعطي جزيئات كتير،
+
+404
+00:35:37,950 --> 00:35:43,150
+واضح؟ عرفتو ليش اليهود بدمروا على الناس دورهم و
+
+405
+00:35:43,150 --> 00:35:48,960
+سياراتهم وما إلى ذلك؟ لأن تفاعل الانفجار هو أفضل
+
+406
+00:35:48,960 --> 00:35:53,920
+تفاعل على الإطلاق، مجنون، تفاعل مجنون، بيفقد طاقة
+
+407
+00:35:53,920 --> 00:35:59,560
+كتير، وبطلع جزيئات كتير صغيرة وبعمل فوضى، وعشان
+
+408
+00:35:59,560 --> 00:36:02,640
+هيك ممشي بشكل ممتاز، بتشوفوا كيف الدنيا كلها
+
+409
+00:36:02,640 --> 00:36:06,780
+بتطير، والمادة المتفجرة بتصير غازات، هي المادة
+
+410
+00:36:06,780 --> 00:36:10,820
+المتفجرة بتكون عبارة عن جزيئات، خلّيني أتخيلك
+
+411
+00:36:10,820 --> 00:36:13,940
+صغيرة وكلها مربوطة مع بعض، ما بتصدق إنها بدها
+
+412
+00:36:13,940 --> 00:36:19,310
+إيش؟ بدأت تتحرر وتفلت، وبعد تحرورها وفلتانها كمان
+
+413
+00:36:19,310 --> 00:36:24,530
+بتطلع طاقة كتير، وعشان هي هذا التفاعل بتلاقيه أسهل
+
+414
+00:36:24,530 --> 00:36:28,770
+منه، هل الواحد بيولع بابور تحت المادة المتفجرة ولا
+
+415
+00:36:28,770 --> 00:36:34,340
+لحالها؟ لحالها بتشيل، ليش؟ لأن فيها الشرطين أنه
+
+416
+00:36:34,340 --> 00:36:41,000
+تفقد طاقة وتزيد الفوضى، وهذه أهم معادلة بتحكم سير
+
+417
+00:36:41,000 --> 00:36:44,740
+التفاعلات، المفروض أنه أخدتوها ولو بثقافة عامة
+
+418
+00:36:44,740 --> 00:36:48,780
+بكيمياء B، الـ Delta G لازم تكون negative، Delta G
+
+419
+00:36:48,780 --> 00:36:54,400
+= Delta H - T Delta S، فاللي بيحكم أنه ليش يكتمل
+
+420
+00:36:54,400 --> 00:36:59,040
+التفاعل ويصيروا حسابات متعلقة بأمرين دائما، إيش
+
+421
+00:36:59,040 --> 00:37:05,580
+هما الأمرين؟ الطاقة والانتروبي، اللي معبر عنهم في
+
+422
+00:37:05,580 --> 00:37:12,040
+المعادلة Delta H و Delta S، فما تنسوهوش، Delta H و
+
+423
+00:37:12,040 --> 00:37:17,500
+Delta S، طبعا أكيد أن أنتم لاحظتوا هنا أنه نوعا ما
+
+424
+00:37:17,500 --> 00:37:22,920
+في موازاة، حتى لما تدرسوا لازم تكونوا بالكوشة ما بين
+
+425
+00:37:22,920 --> 00:37:28,440
+الـ SN1 والـ E1 والـ SN2 والـ E2 في بعض الـ aspects
+
+426
+00:37:31,190 --> 00:37:37,130
+حتى نختتم هذا الفصل، بس بيظل عندنا slide أو اثنتين
+
+427
+00:37:37,130 --> 00:37:41,550
+معلومات ثقافية عامة، أن الـ Alkyl halides هدول اللي 
+
+428
+00:37:41,550 --> 00:37:46,390
+احنا درسنا تفاعلاتهم، فيهم في واقع الحياة العملية
+
+429
+00:37:46,390 --> 00:37:52,790
+كتير من التطبيقات، بنعرض بعض هنا حتى تظهروا أن
+
+430
+00:37:52,790 --> 00:37:56,430
+الكيمياء هي جزء من الحياة، في مركبات بيسموها
+
+431
+00:37:56,430 --> 00:37:59,710
+polyhalogenated aliphatic compounds يعني
+
+432
+00:37:59,710 --> 00:38:04,810
+الهالوجينات المتصلة بهالوجين، وأحيانا بأكثر من
+
+433
+00:38:04,810 --> 00:38:11,130
+هالوجين، من المركبات اللي استعملها كتير في التطبيق
+
+434
+00:38:11,390 --> 00:38:17,910
+الـ CH3Br، الميثيل برومايد، هذا الميثيل برومايد الناس
+
+435
+00:38:17,910 --> 00:38:22,530
+الذين .. الزراعيين منكم يعني الأخوات اللي في
+
+436
+00:38:22,530 --> 00:38:26,970
+الزراعة وفي بيت لاهيا وما إلى ذلك بيعرفوا شغلة
+
+437
+00:38:26,970 --> 00:38:34,750
+أن الفلاحين لما بيجهزوا الأرض للزراعة إيش بيرشوها؟
+
+438
+00:38:34,750 --> 00:38:39,700
+بيرشوها غاز بيجيبوا الأرض و بيرشوها غاز .. هذا
+
+439
+00:38:39,700 --> 00:38:43,620
+الغاز مثل البروميد .. بيقتل كل الحشرات اللي موجودة
+
+440
+00:38:43,620 --> 00:38:47,200
+في التربة .. قبل ما يزرعها .. قبل ما يزرعها ..
+
+441
+00:38:47,200 --> 00:38:52,100
+بيرشها غاز .. وهذا الغاز بالمناسبة مكلف، يعني من
+
+442
+00:38:52,100 --> 00:38:56,540
+فترة صغيرة يعني أحد الفلاحين بيقول أن هو عشان رشّه
+
+443
+00:38:56,540 --> 00:39:02,400
+المين دفع حاجة غاز سبعتلاف شكل عشان قبل ما يزرع
+
+444
+00:39:02,400 --> 00:39:08,600
+الفراولة، أنظف من كل إيش من كل الحشرات الآن حتى
+
+445
+00:39:08,600 --> 00:39:13,120
+نزيدكوا تخافوا، هذا الغاز له أضرار سلبية كتير وبدأ
+
+446
+00:39:13,120 --> 00:39:19,960
+العالم يسعى نحو منعه، بدوا يعملوا مؤتمرات لمنعه، ومن
+
+447
+00:39:19,960 --> 00:39:24,940
+أكثر المعارضين لمنعه الولايات المتحدة الأمريكية
+
+448
+00:39:24,940 --> 00:39:28,900
+اللي أنا بدها محصولها، هي من أكثر المعارضين، تطالب
+
+449
+00:39:28,900 --> 00:39:33,900
+العالم أن يمنعه، وتطالب بمنحها فترة إضافية أكثر حتى
+
+450
+00:39:33,900 --> 00:39:39,040
+هي تمنعه، واضح؟ فيه إله كتير أضرار، مثل الـ Bromide
+
+451
+00:39:39,040 --> 00:39:44,180
+اللي هو الـ fumigant أو اللي بيقتل الحشرات والأشياء
+
+452
+00:39:44,180 --> 00:39:47,740
+اللي بتكون في إيش .. في التربة، والفلاحين عندنا
+
+453
+00:39:47,740 --> 00:39:52,300
+بشكل standard بيستعملوه يعني قبل كل زرعة فراولة
+
+454
+00:39:52,300 --> 00:39:59,270
+لازم يرشوا التربة كلها غاز، وهذا مكلف، الـ CH2Cl2
+
+455
+00:39:59,270 --> 00:40:02,730
+اللي هو دايكلوروميثان، والـ CHCl3 اللي هو
+
+456
+00:40:02,730 --> 00:40:06,950
+الكلوروفورم، هدول عبارة عن organic solvents بنجر
+
+457
+00:40:06,950 --> 00:40:13,950
+فيهم، التفاعل الـ CF2CF2 to the N هو عبارة عن الـ
+
+458
+00:40:13,950 --> 00:40:18,050
+polymer اللي اسمه التفلون، مار عليكم التفلون؟
+
+459
+00:40:19,150 --> 00:40:23,730
+Polymer بلاستيكي، يمكن اليوم أكثر شيء بيستعملوه
+
+460
+00:40:23,730 --> 00:40:27,310
+دايما بتقولوا بدنا نشتري تفلون، لما بيركبوا
+
+461
+00:40:27,310 --> 00:40:32,330
+المواصير ببعض، بتشوفوا هذا الأبيض اللفة الصغيرة
+
+462
+00:40:32,330 --> 00:40:35,010
+البيضة اللي بلفوها حوالين المواصير بدل ما كانوا
+
+463
+00:40:35,010 --> 00:40:41,430
+زمان بيستعملوا الشعر أو الخطان، هذا اسمه إيش؟ تفلون
+
+464
+00:40:41,430 --> 00:40:45,530
+وموجود منه أنواع كتيرة من الـ plastic بمواصفات
+
+465
+00:40:45,530 --> 00:40:49,890
+معينة، برضه عبارة عن .. من مركبات ال .. الـ
+
+466
+00:40:49,890 --> 00:40:53,650
+Alkyl halides، الـ Chlorofluorocarbons اللي هم
+
+467
+00:40:53,650 --> 00:40:57,690
+المركبات ال .. الـ carbons اللي فيهم chlor و fluor
+
+468
+00:40:57,690 --> 00:41:02,430
+هدول بختصرهم بـ CFC، وهذه كلمة كتير بسمعوها في
+
+469
+00:41:02,430 --> 00:41:07,620
+البيئة، ودايما بحكوا عنها، الـ Chlorofluorocarbons
+
+470
+00:41:07,620 --> 00:41:13,320
+هذه من أمثلتها، غاز الـ Freon-12، هذا Freon-12 اللي
+
+471
+00:41:13,320 --> 00:41:16,820
+هو الغاز اللي بيستعملوه في التبريد في داخل
+
+472
+00:41:16,820 --> 00:41:20,840
+التلاجات نفسه، كانوا يحطوه في علب الـ spray عشان
+
+473
+00:41:20,840 --> 00:41:24,340
+تعمل الـ spraying جيد، علب العطر وما إلى ذلك، و
+
+474
+00:41:24,340 --> 00:41:28,800
+البوية عشان تعمل الـ spraying، بيحطوها، هي بالنسبة
+
+475
+00:41:28,800 --> 00:41:34,540
+لوضع الأرض، inert gases، لكن وين مشكلتها؟ في السماء
+
+476
+00:41:34,540 --> 00:41:38,940
+مش في الأرض، مشكلتها لما بتطلع على السماء في
+
+477
+00:41:38,940 --> 00:41:44,020
+الطبقات العليا مع الـ UV light، بتكسر من خلال
+
+478
+00:41:44,020 --> 00:41:49,300
+تفاعلات معينة طبقة الأوزون، ولذلك الآن بيتكلموا عن
+
+479
+00:41:49,300 --> 00:41:54,140
+الثقوب في طبقة الأوزون، مار عليكم الثقوب في طبقة
+
+480
+00:41:54,140 --> 00:41:58,600
+الأوزون، الآن الثقوب في طبقة الأوزون العلماء
+
+481
+00:41:58,600 --> 00:42:00,640
+بيرجحوا أن هو بشكل أساسي جاي من الـ
+
+482
+00:42:00,640 --> 00:42:06,000
+Chlorofluorocarbons، ولذلك اليوم صناعيا التلاجات
+
+483
+00:42:06,000 --> 00:42:11,500
+بيحاولوا يعملوها بنظم غير غاز الـ Freon، الـ spraying
+
+484
+00:42:11,500 --> 00:42:18,280
+بيحاولوا يقللوا يعني بأذكر مرة يمكن قبل ما تموت
+
+485
+00:42:18,280 --> 00:42:24,910
+الأميرة ديانا الـ Lady Diana، جابوها بتجيب إجزازة
+
+486
+00:42:24,910 --> 00:42:28,410
+ريحة وبتكوب على إيدها كاب بدل ما تعمل الـ spraying
+
+487
+00:42:28,410 --> 00:42:34,270
+حتى يقولوا للعالم أن الـ spraying هذا بيطلع أشياء
+
+488
+00:42:34,270 --> 00:42:38,870
+بتضر بالبيئة أو بتضر بطبقة الأوزون، يعني ممكن الناس
+
+489
+00:42:38,870 --> 00:42:42,930
+يستعملوا ريحة عادي هيك يحطوه على إيدهم أفضل من أن
+
+490
+00:42:42,930 --> 00:42:46,890
+كل البشر قاعدين يعملوا spraying، والـ spraying هذا
+
+491
+00:42:46,890 --> 00:42:54,120
+إيش بيعمل؟ بيعمل تدمير لطبقة الأوزون، طبعا إنكمل
+
+492
+00:42:54,120 --> 00:42:59,240
+تدمير طبقة الأوزون إيش بيزيد عندنا؟ بيزيد الاحتباس
+
+493
+00:42:59,240 --> 00:43:02,140
+الحراري، طب إيش مشكلة الاحتباس الحراري الأساسية
+
+494
+00:43:02,140 --> 00:43:09,140
+علينا؟ إيش بتتبع زيادة درجات الحرارة؟ وإيش بتتبع
+
+495
+00:43:09,140 --> 00:43:12,640
+ذوبان الجليد؟
+
+496
+00:43:13,820 --> 00:43:20,060
+غرق كتير من المدن، مدن أساسية في العالم، اللي راح
+
+497
+00:43:20,060 --> 00:43:24,000
+على أوروبا وما إلى ذلك سيعرف أن دول كاملة ممكن
+
+498
+00:43:24,000 --> 00:43:33,080
+تغرق، واضح؟ طبعا ليش بدها تغرق؟ الموضوع بسيط جدا لو
+
+499
+00:43:33,080 --> 00:43:37,000
+أنتم تخيلتوا أن هنا عندكم جبل من الجليد وهذا في
+
+500
+00:43:37,000 --> 00:43:41,540
+المناطق القطبية وثابت ثابت، جبل الجليد ما فيش عليه
+
+501
+00:43:41,540 --> 00:43:47,040
+أي مشكلة، وأنا عندكم بهذا الشكل نوعا ما سهل، وأنا
+
+502
+00:43:47,040 --> 00:43:52,880
+في مدينة زي أمستردام والناس عايشين والجليد هذا
+
+503
+00:43:52,880 --> 00:43:56,820
+معلق على الجبل، عمره ما بينزل، متجمد، الآن لو أنا رفعت
+
+504
+00:43:56,820 --> 00:44:04,040
+الحرارة، مجرد ما صار مية، مش انهيار، مش انهيار، إيش
+
+505
+00:44:04,040 --> 00:44:04,740
+الكلمة؟
+
+506
+00:44:07,250 --> 00:44:12,010
+انصهار، كتير ناس متعودين يقولوا ذوبان الجليد،
+
+507
+00:44:12,010 --> 00:44:16,490
+الذوبان مادة في مادة، الجليد دايما استعملوله انصهار
+
+508
+00:44:16,490 --> 00:44:23,190
+واضح، انصهار مش ذوبان، لما يصير مياه شو هيعمل في مثل
+
+509
+00:44:23,190 --> 00:44:27,310
+هذه المدن؟ هيغرقها، هذه المشكلة، أن الجليد هو صلب
+
+510
+00:44:27,310 --> 00:44:32,270
+بيضل على رأس الجبل، بيضلوا على رأس الجبل، ما فيش عندكم
+
+511
+00:44:32,270 --> 00:44:35,310
+أي مشكلة، هذه تجربة روحوا اعملوها في البيت عندكم
+
+512
+00:44:35,310 --> 00:44:39,850
+هاتوا جوالب ثلج كبيرة، اعملوها وحطوها جانب حوض
+
+513
+00:44:39,850 --> 00:44:44,070
+المغسلة، والحوض ناشف ما فيش فيه ولا شغلة طولها من
+
+514
+00:44:44,070 --> 00:44:48,890
+الجامدة بتضلها عاملة زي الجبل وثابتة مكانها
+
+515
+00:44:48,890 --> 00:44:56,510
+ارتفعت الحرارة شوية، صارت مية، إيه بتنزل؟ بتغرق
+
+516
+00:44:56,510 --> 00:45:01,110
+الحوض، مظبوط ولا لأ؟ وهذه اللي هي الإشكالية أنه في
+
+517
+00:45:01,110 --> 00:45:04,870
+دول كاملة منخفضة، هولندا شو بيسموها؟ Netherlands،
+
+518
+00:45:04,870 --> 00:45:11,430
+الأرض المنخفضة، فدول كاملة ممكن تغرق لو هذه الشغلة
+
+519
+00:45:11,430 --> 00:45:17,900
+بتزيد، دول كاملة ممكن تغرق لو هذه الشغلة بتزيد، أخر
+
+520
+00:45:17,900 --> 00:45:24,040
+شغلة في عندكم من المركبات اللي فيها halogens يعني
+
+521
+00:45:24,040 --> 00:45:28,100
+كربون ومع بروم وchlorofluor أشياء كتيرة، بيسموها
+
+522
+00:45:28,100 --> 00:45:33,280
+الـ halons، الـ halons هذه عبارة عن bromine
+
+523
+00:45:33,280 --> 00:45:36,980
+containing chlorofluorocarbons، they are called
+
+524
+00:45:36,980 --> 00:45:41,520
+halons and are used to extinguish fire، بيستعملهم
+
+525
+00:45:41,520 --> 00:45:45,460
+في الطفايات، بتعرفوا طفاية الـ halon، الطفايات اللي
+
+526
+00:45:45,460 --> 00:45:50,510
+بتكون عليها الإشارة الخضراء، وغالبا هذه طفايات
+
+527
+00:45:50,510 --> 00:45:55,170
+الـ halons، لأن هؤلاء غازات خاملة، لما يكون عنده مورشة
+
+528
+00:45:55,170 --> 00:45:59,530
+بصلح أجهزة كهربائية ما إلى ذلك، لو صار عنده حريقة
+
+529
+00:45:59,530 --> 00:46:04,390
+لا يفضل أنه يجيب مية ويطف يعني لو افترضنا واحد
+
+530
+00:46:04,390 --> 00:46:07,570
+بيصلح تلفزيون كبير وما إلى ذلك متوقع يصير عنده
+
+531
+00:46:07,570 --> 00:46:12,650
+حريقة، بيحط جنبه طفاية مية، لو حط طفاية مية وكبها
+
+532
+00:46:12,650 --> 00:46:18,110
+المية على الجهاز مع الكهربا اللي موجودة، وحتى لو
+
+533
+00:46:18,110 --> 00:46:21,190
+ما فيش كهربا بتخرب كل مكونات الجهاز، لكن هو بتجيب
+
+534
+00:46:21,190 --> 00:46:26,790
+طفاية الغاز الـ halon، بعص بتعمل منع لـ أكسجين عن
+
+535
+00:46:26,790 --> 00:46:32,050
+النار بتطفيها، بعد هيك كله بيروح ما خربش الجهاز عنده
+
+536
+00:46:32,050 --> 00:46:35,990
+فهذه الطفايات، طفايات الـ halons، ويلها أرقام بيعرفوها
+
+537
+00:46:35,990 --> 00:46:40,130
+تعون الإطفاء لإطفاء الحرائق بالذات المتعلقة
+
+538
+00:46:40,130 --> 00:46:46,790
+ بالأجهزة الكهربائية، بهيك تقريبا بنأمل أن أعطيناكوا
+
+539
+00:46:46,790 --> 00:46:50,190
+فكرة عن الـ alkyl halides وإن شاء الله الحصة
+
+540
+00:46:50,190 --> 00:46:53,650
+القادمة بنبدأ في موضوع جديد
+
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..aad08de7ef8fe4eb1785d00b5b0aecf5cd5bfb51
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2164, "start": 5.62, "end": 21.64, "text": "موضوع ال alkanes موضوع واسع، واسع كتير ويمكن بتلاحظوا مقارنة في ال .. في ال alkanes لما حكينا عن التفاعل .. التفاعلات بتاعي تقولنا ال alkanes inner", "tokens": [2304, 2407, 11242, 45367, 2423, 419, 5225, 279, 3714, 2407, 11242, 45367, 4032, 32277, 3615, 12399, 4032, 32277, 3615, 9122, 2655, 13546, 4032, 32640, 19452, 39894, 15040, 5016, 19913, 14407, 3714, 4587, 9640, 1863, 3660, 8978, 2423, 4386, 8978, 2423, 419, 5225, 279, 5296, 15042, 11331, 4117, 1829, 8315, 18871, 16712, 5172, 995, 30241, 4386, 16712, 5172, 995, 30241, 9307, 39894, 45761, 1829, 6055, 39648, 8315, 2423, 419, 5225, 279, 7284], "avg_logprob": -0.14377170304457346, "compression_ratio": 1.6413793103448275, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 5.620000000000005, "end": 6.740000000000003, "word": "موضوع", "probability": 0.8836669921875}, {"start": 6.740000000000003, "end": 7.86, "word": " ال", "probability": 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"probability": 0.5087890625}, {"start": 45.53, "end": 46.45, "word": " تفاعلات", "probability": 0.92822265625}, {"start": 46.45, "end": 47.59, "word": " الإضافة", "probability": 0.9263916015625}, {"start": 47.59, "end": 48.35, "word": " سواء", "probability": 0.8001302083333334}, {"start": 48.35, "end": 48.87, "word": " إضافة", "probability": 0.9818115234375}, {"start": 48.87, "end": 49.29, "word": " أشياء", "probability": 0.9722900390625}, {"start": 49.29, "end": 50.15, "word": " متماثلة", "probability": 0.89658203125}, {"start": 50.15, "end": 50.37, "word": " أو", "probability": 0.9287109375}, {"start": 50.37, "end": 50.79, "word": " إضافة", "probability": 0.929931640625}, {"start": 50.79, "end": 51.13, "word": " أشياء", "probability": 0.984130859375}, {"start": 51.13, "end": 51.33, "word": " غير", "probability": 0.996826171875}, {"start": 51.33, "end": 52.15, "word": " متماثلة", "probability": 0.905078125}, {"start": 52.15, "end": 52.95, "word": " إضافة", "probability": 0.9219970703125}, {"start": 52.95, "end": 53.85, "word": " الهيدروجين", "probability": 0.913330078125}, {"start": 53.85, "end": 54.35, "word": " إضافة", "probability": 0.8709716796875}, {"start": 54.35, "end": 54.95, "word": " البروم", "probability": 0.9274088541666666}, {"start": 54.95, "end": 55.43, "word": " إضافة", "probability": 0.97119140625}, {"start": 55.43, "end": 56.03, "word": " الماء", "probability": 0.9736328125}, {"start": 56.03, "end": 57.29, "word": " إضافة", "probability": 0.9864501953125}, {"start": 57.29, "end": 57.59, "word": " ال", "probability": 0.442626953125}, {"start": 57.59, "end": 58.67, "word": " HPR", "probability": 0.588134765625}, {"start": 58.67, "end": 60.03, "word": " تكوين", "probability": 0.9600830078125}, {"start": 60.03, "end": 60.21, "word": " ال", "probability": 0.83447265625}, {"start": 60.21, "end": 61.37, "word": " epoxides", "probability": 0.5972086588541666}, {"start": 61.37, "end": 62.61, "word": " تكسير", "probability": 0.937744140625}, {"start": 62.61, "end": 62.79, "word": " ال", "probability": 0.94384765625}, {"start": 62.79, "end": 63.73, "word": " epoxides", "probability": 0.92041015625}, {"start": 63.73, "end": 64.61, "word": " واضح؟", "probability": 0.82666015625}], "temperature": 1.0}, {"id": 4, "seek": 9232, "start": 65.34, "end": 92.32, "text": "هي هذا تقريبا الكلام اللي أخدناه الان اليوم موضوعنا formation of diols تحديدا one two diols معنى all المركب اللي فيه OH ال alcohol زي ميثانول إيثانول بروبانول فيه OH فالمجموع الواضح في ال alcohol هي مجموعة إيش ال all لما يكون عندى diols معنى ذلك مركبات فيها", "tokens": [3224, 1829, 23758, 6055, 4587, 16572, 3555, 995, 2423, 28820, 10943, 13672, 1829, 5551, 9778, 3215, 8315, 3224, 2423, 7649, 45595, 20498, 3714, 2407, 11242, 45367, 8315, 11723, 295, 1026, 19385, 6055, 5016, 16254, 28259, 472, 732, 1026, 19385, 20449, 1863, 7578, 439, 9673, 31747, 3555, 13672, 1829, 8978, 3224, 13931, 2423, 7658, 30767, 1829, 3714, 1829, 12984, 7649, 12610, 11933, 1829, 12984, 7649, 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"word": " اللي", "probability": 0.890625}, {"start": 75.74, "end": 76.0, "word": " فيه", "probability": 0.81982421875}, {"start": 76.0, "end": 76.54, "word": " OH", "probability": 0.64990234375}, {"start": 76.54, "end": 77.4, "word": " ال", "probability": 0.65087890625}, {"start": 77.4, "end": 77.94, "word": " alcohol", "probability": 0.6376953125}, {"start": 77.94, "end": 78.72, "word": " زي", "probability": 0.843994140625}, {"start": 78.72, "end": 79.48, "word": " ميثانول", "probability": 0.7776123046875}, {"start": 79.48, "end": 80.22, "word": " إيثانول", "probability": 0.8451171875}, {"start": 80.22, "end": 81.1, "word": " بروبانول", "probability": 0.94501953125}, {"start": 81.1, "end": 81.74, "word": " فيه", "probability": 0.7021484375}, {"start": 81.74, "end": 82.28, "word": " OH", "probability": 0.94287109375}, {"start": 82.28, "end": 83.5, "word": " فالمجموع", "probability": 0.8541015625}, {"start": 83.5, "end": 83.9, "word": " الواضح", "probability": 0.7906494140625}, {"start": 83.9, "end": 84.08, "word": " في", "probability": 0.8740234375}, {"start": 84.08, "end": 84.34, "word": " ال", "probability": 0.525390625}, {"start": 84.34, "end": 85.18, "word": " alcohol", "probability": 0.9287109375}, {"start": 85.18, "end": 86.1, "word": " هي", "probability": 0.8427734375}, {"start": 86.1, "end": 86.68, "word": " مجموعة", "probability": 0.9478515625}, {"start": 86.68, "end": 87.12, "word": " إيش", "probability": 0.8287760416666666}, {"start": 87.12, "end": 87.8, "word": " ال", "probability": 0.82080078125}, {"start": 87.8, "end": 88.12, "word": " all", "probability": 0.84619140625}, {"start": 88.12, "end": 88.94, "word": " لما", "probability": 0.9287109375}, {"start": 88.94, "end": 89.2, "word": " يكون", "probability": 0.974853515625}, {"start": 89.2, "end": 89.6, "word": " عندى", "probability": 0.546142578125}, {"start": 89.6, "end": 90.44, "word": " diols", "probability": 0.9033203125}, {"start": 90.44, "end": 90.88, "word": " معنى", "probability": 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كمان تلت ذرات كدهش المجموعة تمانية تلاتة انكوا حاطين تلت كربونات و بعدين اربعة خمسة ستة سبعة تمانية و جيت و قولتلكم four five dihydroxy مثلا octane is an example of a one two diol", "tokens": [2407, 1975, 24401, 4032, 1975, 2655, 1863, 9957, 37495, 22653, 50113, 15040, 45164, 11331, 9566, 36081, 34105, 6055, 1211, 2655, 29910, 2288, 9307, 37037, 1829, 9122, 2304, 7649, 29910, 2288, 2655, 9957, 4032, 9122, 2304, 7649, 6055, 1211, 2655, 29910, 2288, 9307, 9122, 3215, 3224, 8592, 9673, 7435, 2304, 2407, 27884, 6055, 2304, 7649, 10632, 6055, 1211, 9307, 3660, 16472, 4117, 14407, 11331, 41193, 9957, 6055, 1211, 2655, 9122, 25513, 2407, 8315, 2655, 4032, 39182, 9957, 1975, 25513, 27884, 16490, 2304, 3794, 3660, 8608, 2655, 3660, 8608, 3555, 27884, 46811, 7649, 10632, 4032, 10874, 36081, 4032, 12174, 12610, 2655, 23275, 2304, 1451, 1732, 1026, 21591, 340, 12876, 50113, 15040, 13350, 1929, 307, 364, 1365, 295, 257, 472, 732, 1026, 401], "avg_logprob": -0.2512913301956555, "compression_ratio": 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فيه؟ أه الأبيض", "tokens": [38, 2662, 642, 4032, 26593, 4032, 383, 4550, 9154, 5551, 2304, 12984, 1211, 2655, 11296, 20666, 5172, 41779, 5172, 13063, 6055, 3555, 3615, 21542, 25513, 1975, 1829, 8592, 31767, 13063, 13672, 1829, 44945, 29245, 3215, 25894, 11296, 27188, 41779, 5172, 13063, 20666, 9566, 21292, 27884, 22807, 16247, 21292, 11242, 4032, 16247, 5016, 29973, 1975, 1829, 8592, 13672, 1829, 16472, 9778, 3555, 9566, 14407, 8978, 3224, 22807, 5551, 3224, 16247, 21292, 11242], "avg_logprob": -0.2339409753266308, "compression_ratio": 1.5178571428571428, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 1014.0100000000001, "end": 1015.07, "word": "Graphite", "probability": 0.6930338541666666}, {"start": 1015.07, "end": 1015.27, "word": " و", "probability": 0.95068359375}, {"start": 1015.27, "end": 1015.71, "word": " Diamond", "probability": 0.268310546875}, {"start": 1015.71, "end": 1015.95, "word": " و", "probability": 0.99072265625}, {"start": 1015.95, "end": 1016.51, 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{"start": 1546.24, "end": 1546.66, "word": " صارت", "probability": 0.9612630208333334}, {"start": 1546.66, "end": 1546.92, "word": " عندى", "probability": 0.7509765625}, {"start": 1546.92, "end": 1547.34, "word": " مشكلة", "probability": 0.98291015625}, {"start": 1547.34, "end": 1547.8, "word": " جديدة", "probability": 0.9910481770833334}], "temperature": 1.0}, {"id": 63, "seek": 157760, "start": 1548.82, "end": 1577.6, "text": "هذا ال ايون الموجة بالجديد إما بيلاقي PR- وبالتالي بتضيف بسرعة هذا إذا ما لاجعش ممكن ال double bond ترجع و ترجع تكون هذا الايون إذا كأنه هذا الايون اللي احنا بنسميه قلل كتايون مر علينا في double bonds مجموعة القلل القلل double bond CH2 زي هي كانت double bond", "tokens": [3224, 15730, 2423, 1975, 1829, 11536, 9673, 29245, 3660, 20666, 7435, 16254, 3215, 11933, 15042, 4724, 1829, 15040, 38436, 11568, 12, 46599, 6027, 2655, 6027, 1829, 39894, 11242, 33911, 4724, 3794, 2288, 27884, 23758, 11933, 15730, 19446, 5296, 26108, 3615, 8592, 3714, 43020, 2423, 3834, 6086, 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بيعمل resonance اش يعني resonance حركة إلكترونات فقط عمرنا لما نسأل نقولكوا اش يعني انكتوا اعطونى ترجمة العرب اعطونى المعنى", "tokens": [5462, 17, 8032, 3215, 7578, 25961, 2655, 3714, 7435, 2304, 2407, 27884, 25062, 1211, 1211, 3714, 19913, 3555, 2407, 9566, 2423, 7649, 45164, 23032, 1211, 34268, 3224, 1975, 8315, 3834, 6086, 5995, 17, 8032, 3215, 7578, 12174, 1211, 1211, 49429, 5296, 10721, 1975, 3224, 8032, 3215, 7578, 25062, 1211, 1211, 9122, 2655, 995, 26895, 44945, 39648, 18871, 3224, 4724, 1829, 25957, 1211, 30944, 1975, 8592, 37495, 22653, 30944, 11331, 31747, 3660, 11933, 23275, 2655, 2288, 11536, 9307, 6156, 47432, 6225, 29973, 8315, 5296, 15042, 8717, 3794, 10721, 1211, 8717, 39648, 4117, 14407, 1975, 8592, 37495, 22653, 16472, 4117, 2655, 14407, 1975, 3615, 9566, 11536, 7578, 6055, 47341, 46007, 18863, 25513, 1975, 3615, 9566, 11536, 7578, 9673, 3615, 1863, 7578], "avg_logprob": -0.22161457935969034, "compression_ratio": 1.7727272727272727, "no_speech_prob": 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"word": " bond", "probability": 0.9326171875}, {"start": 1584.94, "end": 1586.54, "word": " CH2", "probability": 0.972900390625}, {"start": 1586.54, "end": 1586.96, "word": " هدى", "probability": 0.7654622395833334}, {"start": 1586.96, "end": 1587.32, "word": " قلل", "probability": 0.9562174479166666}, {"start": 1587.32, "end": 1587.54, "word": " ولا", "probability": 0.8544921875}, {"start": 1587.54, "end": 1588.02, "word": " لأ", "probability": 0.88916015625}, {"start": 1588.02, "end": 1588.82, "word": " اه", "probability": 0.5574951171875}, {"start": 1588.82, "end": 1589.26, "word": " هدى", "probability": 0.8015950520833334}, {"start": 1589.26, "end": 1589.68, "word": " القلل", "probability": 0.9733072916666666}, {"start": 1589.68, "end": 1590.38, "word": " كتايل", "probability": 0.59527587890625}, {"start": 1590.38, "end": 1591.16, "word": " بنقول", "probability": 0.89697265625}, {"start": 1591.16, "end": 1591.48, "word": " عنه", "probability": 0.948486328125}, {"start": 1591.48, 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"probability": 0.9755859375}, {"start": 1947.61, "end": 1948.05, "word": " الامتحان", "probability": 0.9427734375}, {"start": 1948.05, "end": 1948.31, "word": " ال", "probability": 0.9169921875}, {"start": 1948.31, "end": 1948.59, "word": " kids", "probability": 0.94580078125}, {"start": 1948.59, "end": 1948.89, "word": " are", "probability": 0.96923828125}, {"start": 1948.89, "end": 1949.41, "word": " inert", "probability": 0.91357421875}, {"start": 1949.41, "end": 1950.09, "word": " و", "probability": 0.71240234375}, {"start": 1950.09, "end": 1950.35, "word": " واحدة", "probability": 0.9161783854166666}, {"start": 1950.35, "end": 1950.65, "word": " بتقول", "probability": 0.906494140625}, {"start": 1950.65, "end": 1951.37, "word": " مظبوط", "probability": 0.9517578125}], "temperature": 1.0}, {"id": 80, "seek": 197281, "start": 1954.37, "end": 1972.81, "text": "الالكينز تفاعلاته مكتيرة جدا هذا التفاعل بنسميه deals elder reaction deals elder reaction هو عبارة عن تفاعل بنسميه cycle addition reaction ايش يعني cycle addition reaction؟", "tokens": [6027, 6027, 4117, 9957, 11622, 6055, 5172, 995, 30241, 9307, 3224, 3714, 4117, 2655, 48923, 10874, 28259, 23758, 16712, 5172, 995, 30241, 44945, 38251, 1829, 3224, 11215, 12995, 5480, 2028, 82, 12995, 5480, 31439, 6225, 3555, 9640, 3660, 18871, 6055, 5172, 995, 30241, 44945, 38251, 1829, 3224, 6586, 4500, 5480, 1975, 1829, 8592, 37495, 22653, 6586, 4500, 5480, 22807], "avg_logprob": -0.3221354305744171, "compression_ratio": 1.6971830985915493, "no_speech_prob": 6.556510925292969e-07, "words": [{"start": 1954.3700000000001, "end": 1955.63, "word": "الالكينز", "probability": 0.56839599609375}, {"start": 1955.63, "end": 1956.27, "word": " تفاعلاته", "probability": 0.8047688802083334}, {"start": 1956.27, "end": 1956.71, "word": " مكتيرة", "probability": 0.71527099609375}, {"start": 1956.71, "end": 1957.15, "word": " جدا", "probability": 0.980712890625}, {"start": 1957.15, "end": 1957.93, "word": " هذا", "probability": 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متصلة ب CL CH2 to the N بصير polyvinyl chloride ال polyvinyl chloride له اسم شهره مختصر ايش بنختصره PVC مين فيكم ماسمعش في plastic ال PVC", "tokens": [53, 22946, 35434, 2423, 7649, 45164, 2423, 25226, 35434, 6225, 42213, 12610, 3224, 20073, 2144, 4724, 8592, 17082, 1211, 44945, 36178, 41950, 16572, 28671, 4724, 25957, 20292, 5995, 44650, 36520, 3660, 4724, 12855, 5995, 17, 281, 264, 426, 4724, 9381, 13546, 6754, 85, 22946, 35434, 2423, 6754, 85, 22946, 35434, 46740, 24525, 2304, 13412, 3224, 2288, 3224, 3714, 46456, 9381, 2288, 1975, 1829, 8592, 44945, 46456, 9381, 2288, 3224, 46700, 3714, 9957, 8978, 24793, 19446, 38251, 3615, 8592, 8978, 5900, 2423, 46700], "avg_logprob": -0.25244729131101123, "compression_ratio": 1.5544554455445545, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2675.75, "end": 2676.19, "word": "Vinyl", "probability": 0.7266845703125}, {"start": 2676.19, "end": 2676.71, "word": " chloride", "probability": 0.8017578125}, {"start": 2676.71, "end": 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{"start": 2708.36, "end": 2709.18, "word": " الأرضيات", "probability": 0.9803466796875}, {"start": 2709.18, "end": 2709.34, "word": " اللي", "probability": 0.881103515625}, {"start": 2709.34, "end": 2709.66, "word": " مرات", "probability": 0.9228515625}, {"start": 2709.66, "end": 2710.08, "word": " بيعملوا", "probability": 0.93330078125}, {"start": 2710.08, "end": 2710.34, "word": " منها", "probability": 0.99658203125}, {"start": 2710.34, "end": 2711.44, "word": " المستشفيات", "probability": 0.9744140625}, {"start": 2711.44, "end": 2711.88, "word": " وغيرها", "probability": 0.91357421875}, {"start": 2711.88, "end": 2711.98, "word": " و", "probability": 0.93359375}, {"start": 2711.98, "end": 2712.1, "word": " ال", "probability": 0.71044921875}, {"start": 2712.1, "end": 2712.44, "word": " studio", "probability": 0.791015625}, {"start": 2712.44, "end": 2713.04, "word": " هذه", "probability": 0.201171875}, {"start": 2713.04, "end": 2713.94, "word": " كلها", "probability": 0.976318359375}, 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2880.32, "word": " بلاستيك", "probability": 0.78916015625}, {"start": 2880.32, "end": 2881.34, "word": " لبراميل", "probability": 0.9100341796875}, {"start": 2881.34, "end": 2881.74, "word": " وغيرها", "probability": 0.9095458984375}, {"start": 2881.74, "end": 2882.14, "word": " وغيرها", "probability": 0.966796875}, {"start": 2882.14, "end": 2882.48, "word": " بس", "probability": 0.937255859375}, {"start": 2882.48, "end": 2882.64, "word": " اللي", "probability": 0.839599609375}, {"start": 2882.64, "end": 2883.06, "word": " بنعمل", "probability": 0.7880859375}, {"start": 2883.06, "end": 2883.32, "word": " منه", "probability": 0.989013671875}, {"start": 2883.32, "end": 2884.12, "word": " fibers", "probability": 0.5146484375}, {"start": 2884.12, "end": 2885.1, "word": " هو", "probability": 0.97900390625}, {"start": 2885.1, "end": 2886.6, "word": " البولي", "probability": 0.9710286458333334}, {"start": 2886.6, "end": 2887.18, "word": " إستر", "probability": 0.96728515625}, {"start": 2887.18, "end": 2889.38, "word": " ابهيك", "probability": 0.519073486328125}, {"start": 2889.38, "end": 2889.58, "word": " احنا", "probability": 0.8671875}, {"start": 2889.58, "end": 2890.12, "word": " بنكون", "probability": 0.952880859375}, {"start": 2890.12, "end": 2891.26, "word": " خلصنا", "probability": 0.9918212890625}, {"start": 2891.26, "end": 2892.9, "word": " تفاعلات", "probability": 0.947265625}, {"start": 2892.9, "end": 2893.66, "word": " الalkynes", "probability": 0.580902099609375}, {"start": 2893.66, "end": 2893.82, "word": " ان", "probability": 0.78955078125}, {"start": 2893.82, "end": 2894.04, "word": " شاء", "probability": 0.93896484375}, {"start": 2894.04, "end": 2894.04, "word": " الله", "probability": 0.9443359375}, {"start": 2894.04, "end": 2894.68, "word": " المحاضرة", "probability": 0.9727783203125}, {"start": 2894.68, "end": 2895.0, "word": " الجاية", "probability": 0.7482096354166666}, {"start": 2895.0, "end": 2895.38, "word": " بنبدأ", "probability": 0.892578125}, {"start": 2895.38, "end": 2896.38, "word": " بتفاعلات", "probability": 0.90703125}, {"start": 2896.38, "end": 2898.02, "word": " الalkynes", "probability": 0.93212890625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2900.6135, "duration_after_vad": 2796.373749999988}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..60d89e15ac5730f334d8258a2920d6f659e2dc7a
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_raw.srt
@@ -0,0 +1,2208 @@
+1
+00:00:05,620 --> 00:00:12,680
+موضوع ال alkanes موضوع واسع، واسع كتير ويمكن
+
+2
+00:00:12,680 --> 00:00:18,420
+بتلاحظوا مقارنة في ال .. في ال alkanes لما حكينا
+
+3
+00:00:18,420 --> 00:00:21,380
+عن التفاعل .. التفاعلات بتاعي تقولنا ال alkanes
+
+4
+00:00:21,380 --> 00:00:27,130
+innerوحكينا تفاعلات بعشر دقائق وربع ساعة و سكرنا
+
+5
+00:00:27,130 --> 00:00:31,610
+بينما ال alkanes they are very reactive يعني هي
+
+6
+00:00:31,610 --> 00:00:37,670
+تالت محاضرة و احنا بنشرح التفاعلات ال alkanes
+
+7
+00:00:37,670 --> 00:00:41,450
+واضح؟ فتفاعلاتها كثيرة الحقيقة they are reactive
+
+8
+00:00:42,470 --> 00:00:48,350
+أخذنا طبعا على ال الكينز تفاعلات الإضافة سواء
+
+9
+00:00:48,350 --> 00:00:52,150
+إضافة أشياء متماثلة أو إضافة أشياء غير متماثلة
+
+10
+00:00:52,150 --> 00:00:57,590
+إضافة الهيدروجين إضافة البروم إضافة الماء إضافة ال
+
+11
+00:00:57,590 --> 00:01:05,680
+HPR تكوين ال epoxides تكسير ال epoxides واضح؟هي
+
+12
+00:01:05,680 --> 00:01:09,320
+هذا تقريبا الكلام اللي أخدناه الان اليوم موضوعنا
+
+13
+00:01:09,320 --> 00:01:14,540
+formation of diols تحديدا one two diols معنى all
+
+14
+00:01:14,540 --> 00:01:20,220
+المركب اللي فيه OH ال alcohol زي ميثانول إيثانول
+
+15
+00:01:20,220 --> 00:01:26,100
+بروبانول فيه OH فالمجموع الواضح في ال alcohol هي
+
+16
+00:01:26,100 --> 00:01:31,140
+مجموعة إيش ال all لما يكون عندى diols معنى ذلك
+
+17
+00:01:31,140 --> 00:01:37,750
+مركبات فيهاتنتيل OH مش واحدة OH واضح؟ لما بنقول
+
+18
+00:01:37,750 --> 00:01:43,570
+one two dials معناه ذلك التنتيل OH جانب بعض التنتو
+
+19
+00:01:43,570 --> 00:01:49,250
+.. التنتيل OH جانب بعض الآن خليكم منتبهين معي مش
+
+20
+00:01:49,250 --> 00:01:54,370
+ضروري انه يكون معنى one two dials انه التنتيل OH
+
+21
+00:01:54,830 --> 00:01:58,750
+واحدة منهم على موقع واحد وواحدة منهم على موقع
+
+22
+00:01:58,750 --> 00:02:02,750
+اتنين لأ لأ مافيش علاقة دايما لما بنقول one two
+
+23
+00:02:02,750 --> 00:02:06,850
+dioles او مثلا نقول one two addition معنى ذلك
+
+24
+00:02:06,850 --> 00:02:10,730
+التنتين جايات جنب بعض بمعنى ممكن يكونوا اتنين و
+
+25
+00:02:10,730 --> 00:02:14,790
+تلاتة و لا بعض ممكن يكونوا تلاتة و اربعة ممكن
+
+26
+00:02:14,790 --> 00:02:18,510
+يكونوا اربعة و خمسة مش الزام انه كلمة one two
+
+27
+00:02:18,510 --> 00:02:23,400
+dioles ان التنتين يكونوا ايشو احد و اتنين يعني
+
+28
+00:02:23,400 --> 00:02:26,680
+مثلا لو حطيت هنا تلت ذرات وهي كمان ذرتين و كمان
+
+29
+00:02:26,680 --> 00:02:31,720
+تلت ذرات كدهش المجموعة تمانية تلاتة انكوا حاطين
+
+30
+00:02:31,720 --> 00:02:35,840
+تلت كربونات و بعدين اربعة خمسة ستة سبعة تمانية و
+
+31
+00:02:35,840 --> 00:02:43,420
+جيت و قولتلكم four five dihydroxy مثلا octane is
+
+32
+00:02:43,420 --> 00:02:49,980
+an example of a one two diolواضح؟ هو مثال على one
+
+33
+00:02:49,980 --> 00:02:54,380
+two diol بمعنى أن المجمعتين موجودات على موقعين
+
+34
+00:02:54,380 --> 00:02:59,460
+متتاليين، هاي معنى كلمة one two diol مش معناها أنه
+
+35
+00:02:59,460 --> 00:03:05,670
+تحديدا في الجزء على موقع واحد وعلى موقع اتنينبنحصل
+
+36
+00:03:05,670 --> 00:03:10,730
+عليهم بطريقتين من خلال two different reagents ال
+
+37
+00:03:10,730 --> 00:03:16,010
+reagent الأول ال Osmium Oxide Osmium O4 و ال
+
+38
+00:03:16,010 --> 00:03:21,350
+Osmium هو معدن من المعادن الثقيلة بالعكس هو تقريبا
+
+39
+00:03:21,350 --> 00:03:27,590
+أثقل معدن يعني بكثافة ابتصل لواحد وعشرين وكسر
+
+40
+00:03:27,590 --> 00:03:35,570
+تقريبا اجرام لكل سنتمتر مكعب واضح؟يعني لو كنتوا
+
+41
+00:03:35,570 --> 00:03:40,210
+بتكون .. تحمله liter منه .. لو كنتوا بتكون تحمله
+
+42
+00:03:40,210 --> 00:03:43,750
+liter منه، معناه ذلك هذا ال liter بدي يكون وزنه
+
+43
+00:03:43,750 --> 00:03:49,350
+واحد و عشرين كيلو جرام، لاحظوا liter الميه كام
+
+44
+00:03:49,350 --> 00:03:55,050
+وزنه؟ كيلو جرام واحد، مظبوط ولا لا؟ liter الزئبق،
+
+45
+00:03:55,050 --> 00:03:58,730
+كداش وزنه؟ كتير مار عليكم
+
+46
+00:04:01,880 --> 00:04:07,200
+تلتاش وستة من عشرة الكثافة، كثافة الزباق، يعني لتر
+
+47
+00:04:07,200 --> 00:04:13,260
+الزباق تلتاش وستة من عشرة كيلو جرام، لتر الدهب،
+
+48
+00:04:13,260 --> 00:04:20,360
+المفروض تعرفوه، حوالي عشرين كيلو جرامواضح؟ عشان
+
+49
+00:04:20,360 --> 00:04:24,520
+هيك لما .. زمان كنتوا تقرأوا في القصص أنه الصياد
+
+50
+00:04:24,520 --> 00:04:31,820
+مثلا لجى جرة و الجرة فيها ملانة دهب فحملها فرحا و
+
+51
+00:04:31,820 --> 00:04:35,320
+حاطيله هيك حامل الجرة و مروح هو لو عنده جر الدهب
+
+52
+00:04:35,320 --> 00:04:41,040
+فيها عشرين كيلو جرام، كدهش بده يكون وزن الجرة؟
+
+53
+00:04:41,040 --> 00:04:45,520
+عشرين في عشرين؟ اربعمية كيلو جرام، مين بيقدر يحمل
+
+54
+00:04:45,520 --> 00:04:50,290
+اربعمية كيلو جرام هيك بين اديه و يروح؟اللي جابنا
+
+55
+00:04:50,290 --> 00:04:54,470
+لها الكلام انه لما تمر عليكم الشغلات مرات تتبهولا
+
+56
+00:04:54,470 --> 00:04:58,430
+الأزوميوم O4 تقريبا أثقل المعادل لو أخدنا هذا
+
+57
+00:04:58,430 --> 00:05:01,730
+الأزوميوم O4 مع السوديوم هيدروجين سولفايد في وجود
+
+58
+00:05:01,730 --> 00:05:07,590
+الميه بيعملوا إضافة مجموعتين OH والإضافة بتكون من
+
+59
+00:05:07,590 --> 00:05:11,450
+جهة واحدة sin addition سبق إن حكينا لكم زي من جهة
+
+60
+00:05:11,450 --> 00:05:16,090
+واحدة هذه إيش sin addition من جهتين متعاكستين anti
+
+61
+00:05:16,090 --> 00:05:20,670
+additionفي عندي sin addition وفي عندي anti
+
+62
+00:05:20,670 --> 00:05:24,950
+addition اتذكروا لما أخدنا إضافة الهيدروجين قولنا
+
+63
+00:05:24,950 --> 00:05:28,310
+الهيدروجين addition is sin addition لما أخدنا
+
+64
+00:05:28,310 --> 00:05:33,070
+إضافة البرومين البرومين addition is anti addition
+
+65
+00:05:33,070 --> 00:05:38,990
+الآن إضافة مجموعتي ال OH من خلال الوزوميوم O4 في
+
+66
+00:05:38,990 --> 00:05:43,250
+وجود ال Sodium Hydrogen Sulphide أو من خلال
+
+67
+00:05:43,250 --> 00:05:49,080
+التفاعل مع الكئمن O4 البوتاسيومبرمجانات في basic
+
+68
+00:05:49,080 --> 00:05:54,360
+medium في OH minus بيعملي sin addition بضيف
+
+69
+00:05:54,360 --> 00:05:59,840
+المجمعتين ومن جهة واحدة مرات كتير .. مرات كتير
+
+70
+00:05:59,840 --> 00:06:03,340
+انتوا لما بتكونوا تحفظوا و بتكونوا تكملوا معادلات
+
+71
+00:06:03,340 --> 00:06:06,960
+بتاخدوا double bond و بتحفظوا هنا كلمة K من O4 و
+
+72
+00:06:06,960 --> 00:06:12,460
+بتقولوا بتحط مجمعتينالحقيقة هنا لأ بدياكوا تنتبهوا
+
+73
+00:06:12,460 --> 00:06:18,760
+الكيمان O4 بتتفاعل بطريقتين مختلفتين تماما في وجود
+
+74
+00:06:18,760 --> 00:06:24,560
+ال basic medium OH minus بتعطي مجموعتين OH على جهة
+
+75
+00:06:24,560 --> 00:06:28,320
+واحدة بعد شوية ان شاء الله في المحاضرة هذه هناخد
+
+76
+00:06:28,320 --> 00:06:35,130
+ان في وجود H plusالحامض بتكسر الالكين بطريقة معينة
+
+77
+00:06:35,130 --> 00:06:39,250
+فمابديش احفظ التفاعل انه تفاعل الالكين مع الكئمن
+
+78
+00:06:39,250 --> 00:06:47,110
+O4 لأ بدي احفظ انه تفاعل الالكين مع الكئمن O4 in
+
+79
+00:06:47,110 --> 00:06:51,570
+basic medium في وجود ال OH- لأن بعد شوية في وجود
+
+80
+00:06:51,570 --> 00:06:57,970
+ال H plusهتعطيكوا تفاعل مختلف تماما واضح هدول ال
+
+81
+00:06:57,970 --> 00:07:02,110
+two reagents اللي بيكونولي one two diol وزي ما
+
+82
+00:07:02,110 --> 00:07:08,770
+اتفقنا ان ال addition is sin addition بمعنى إضافة
+
+83
+00:07:08,770 --> 00:07:14,090
+من جهة واحدة طبعا اللي بيخلي ال addition تكون sin
+
+84
+00:07:14,090 --> 00:07:18,990
+addition لو أخدنا كمثال ال camon O4 في ال camon O4
+
+85
+00:07:18,990 --> 00:07:26,050
+المنغنيز متصل باربع ذراتأكسوجين واضح و هيجوا تنتين
+
+86
+00:07:26,050 --> 00:07:29,730
+منهم يتفاعلوا الآن هل من الممكن يعني لو اتخيلتوا
+
+87
+00:07:29,730 --> 00:07:32,150
+ان هاي مثلا هنا المنجانيز في ال center هاي واحد
+
+88
+00:07:32,150 --> 00:07:35,930
+اتنين تلاتة اربعة نفترض هل من الممكن ان انا اقدر
+
+89
+00:07:35,930 --> 00:07:40,350
+اضيف زي هيك من جهتين مختلفتين طالما كلهم مربطين
+
+90
+00:07:40,350 --> 00:07:44,790
+بذرة مركزية يعني لما نكون عند امن او فور هاي
+
+91
+00:07:44,790 --> 00:07:48,650
+المنجانيز في النص و هاي الامن او فور و بدى اضيف
+
+92
+00:07:48,650 --> 00:07:53,780
+تنتين منهمبدهم ييجيوا يضيفوا بهذا الشكل هل ممكن ان
+
+93
+00:07:53,780 --> 00:07:57,140
+واحد اضيف من هنا و التانية من وراه فلأن كلهم
+
+94
+00:07:57,140 --> 00:08:02,360
+مرتبطين الأربع ذرات أكسجيل بالمانجاليز بيضيفوا
+
+95
+00:08:02,360 --> 00:08:07,700
+تنتين منهم من جهة واحدة فبيعطينا ال sin addition
+
+96
+00:08:07,700 --> 00:08:11,500
+عشانك لو كان عندي Cyclohexane ولا Cyclobutane ولا
+
+97
+00:08:11,500 --> 00:08:15,640
+Cyclooctane وبدو كترسم الاتجاه دبعهم لاحظوا ال
+
+98
+00:08:15,640 --> 00:08:19,140
+stereo chemistry الشكل بالفراغ التنتين يا بيكونوا
+
+99
+00:08:19,140 --> 00:08:22,960
+لقداميا بيكونوا لورا في الحالتين هذا يعتبر نفس
+
+100
+00:08:22,960 --> 00:08:26,200
+المركب في هذه الحالة اللي هو sin addition بس
+
+101
+00:08:26,200 --> 00:08:31,820
+مابيكونش واحدة لقدام واحدة لورا اللي هو anti
+
+102
+00:08:31,820 --> 00:08:37,980
+addition .. اللي هو anti additionلو هنا قلنا لكم
+
+103
+00:08:37,980 --> 00:08:42,760
+اكمل المعادلات موضوع سهل هيضاف ال bond مع ال
+
+104
+00:08:42,760 --> 00:08:47,640
+osmium O4 لاحظوا مجموعتين ال OH كيف رسمناهم على
+
+105
+00:08:47,640 --> 00:08:51,920
+جهة واحدة عملنا sin addition Cyclopentane مثلا
+
+106
+00:08:51,920 --> 00:08:56,220
+بالكامن O4 in basic medium انتوا لاحظين كلمة ال
+
+107
+00:08:56,220 --> 00:09:00,080
+basic medium برضه إضافة مجموعتين ال OH من جهة
+
+108
+00:09:00,080 --> 00:09:08,280
+واحدةهنا بدكم تتذكروا ان هذا ليس أول مرة ناخد فيها
+
+109
+00:09:08,280 --> 00:09:13,040
+احنا تكوين ال 1,2-Diol المحاضرة الماضية أخذنا
+
+110
+00:09:13,040 --> 00:09:17,800
+تكوين 1,2-Diol من خلال ان احنا من الالكين بداية
+
+111
+00:09:17,800 --> 00:09:23,080
+اعملنا الابوكسايد بعد هيك الابوكسايد باضافة الماء
+
+112
+00:09:23,080 --> 00:09:29,440
+في وجود الحامض كان بيفتحبهذا الشكل متذكرين؟ ال a
+
+113
+00:09:29,440 --> 00:09:34,800
+لما هذا المكان العلوي كله مسكر .. مسكر بوجود ال
+
+114
+00:09:34,800 --> 00:09:40,960
+oxygen الميه مضطرة تيجي من وين؟ من اتجاه المعاكس،
+
+115
+00:09:40,960 --> 00:09:45,800
+مظبوط ولا لا؟ من عند وين؟ اتجاه المعاكس، من عند
+
+116
+00:09:45,800 --> 00:09:51,450
+فصل القاسم، وبناء على ذلك ماشي بتعمل؟تنتن أو أتش
+
+117
+00:09:51,450 --> 00:09:57,150
+بأي mood of addition أنتي addition واضح؟ إذا لو
+
+118
+00:09:57,150 --> 00:10:00,890
+أنا إجيت لان جيبتلكوا السؤال و قولتولكوا حضرولي ال
+
+119
+00:10:00,890 --> 00:10:07,410
+1,2 ديول بسن addition في عندكم الطريقة كيامان أو
+
+120
+00:10:07,410 --> 00:10:10,510
+فور باسيك ميديام أو أزوميام أوفور لو قولتلكوا
+
+121
+00:10:10,510 --> 00:10:18,350
+بدياها في ال anti addition من نفس الألكين أول إش
+
+122
+00:10:18,350 --> 00:10:24,400
+من الألكينبدا اكوّن الابوكسايد كيف كنا نكونه الكين
+
+123
+00:10:24,400 --> 00:10:29,120
+بير أسد بيعطينا الابوكسايد بعدين الابوكسايد بنعمله
+
+124
+00:10:29,120 --> 00:10:35,180
+ring opening اللي هو فتح الحلقة في وجود H بلس H2O
+
+125
+00:10:35,180 --> 00:10:41,680
+بتفتح وبيعطينا ال Anti-addition الان هذا التفاعل
+
+126
+00:10:41,680 --> 00:10:47,820
+التاني لل الكين مع ال KMnO4 اللي انا قلتلكم بيعمل
+
+127
+00:10:49,240 --> 00:10:54,880
+تكسير للـ Double Bond هذا التفاعل اللي بالـ Acidic
+
+128
+00:10:54,880 --> 00:11:01,920
+Medium Oxidation of Alkenes by Acidic MnO4- لو
+
+129
+00:11:01,920 --> 00:11:05,520
+إحنا إجينا عملنا .. خلّيني أنظر في الأول المعادلة
+
+130
+00:11:05,520 --> 00:11:10,460
+اللي تحت إحنا إجينا عملنا Oxidation لألكين بالـ
+
+131
+00:11:10,460 --> 00:11:15,080
+MnO4 في وجود الحامض بيكسر الـ Double Bond اللي
+
+132
+00:11:15,080 --> 00:11:21,140
+موجود هنا من النصبتكسرها من النصف هذي تخلوها C
+
+133
+00:11:21,140 --> 00:11:25,460
+double bond O وهذه تخلوها C double bond O يعني
+
+134
+00:11:25,460 --> 00:11:29,060
+عندما أعمل الناتج ببساطة بدي أكسر هذه من النصف
+
+135
+00:11:29,060 --> 00:11:34,460
+يصير عند RCR وهذا C double bond O وRCR وC double
+
+136
+00:11:34,460 --> 00:11:39,160
+bond O بهذا الشكل الكمان أفور بكسر ال double bond
+
+137
+00:11:39,160 --> 00:11:46,260
+واضح؟ الآن هذا الكسر هذا الكسر لل double bondهو
+
+138
+00:11:46,260 --> 00:11:51,860
+أول خطوة في التفاعل إذا كانت المجموعات هذه R كلها
+
+139
+00:11:51,860 --> 00:11:58,440
+بمعنى مثل اثل بروبل بيوتل أي ان كانت يقف التفاعل
+
+140
+00:11:58,440 --> 00:12:03,660
+بهذا الشكل يعني بس بتعملوا الكسر ثم يقف التفاعل
+
+141
+00:12:03,660 --> 00:12:08,160
+واضح طب إيش في احتمال على أي كربونا أنه يكون غير
+
+142
+00:12:08,160 --> 00:12:15,860
+ال R و ال R ممكن يكون عندي H و H أو R و Rأو
+
+143
+00:12:15,860 --> 00:12:22,500
+الاحتمال التالت مين بدى تحكيلنا يا او R أو H 100%
+
+144
+00:12:22,500 --> 00:12:31,200
+واضح يا بدى يكون عندى H و H او R و R او R و H اذا
+
+145
+00:12:31,200 --> 00:12:36,120
+كان عندى المجموعات R و R بتم كسر لتن تن C double
+
+146
+00:12:36,120 --> 00:12:43,930
+bond O ولا يحصل اي تفاعل اضافى اذا كان عندىH وH
+
+147
+00:12:43,930 --> 00:12:48,790
+بيصير عندى C double bond O وحملة H وH فى الخطوة
+
+148
+00:12:48,790 --> 00:12:52,990
+الأولى الكمن و for هذا المركب بيأكسد و إضافة
+
+149
+00:12:52,990 --> 00:12:59,150
+بيطلعوا إيش فى الآخر ثالث أكسيد كربون واضح إيش
+
+150
+00:12:59,150 --> 00:13:05,630
+بيطلعوا ثالث أكسيد كربون إذا لو عندى أنا CHH شو
+
+151
+00:13:05,630 --> 00:13:09,490
+الناتج تبعها اللى بدى يتكون عندى ثالث أكسيد كربون
+
+152
+00:13:09,490 --> 00:13:20,270
+واضحطيب لو عندى RCH بدا تصير R C double bond O H
+
+153
+00:13:20,270 --> 00:13:25,150
+فى الخطوة الأولى هذا الديهيد بيأكسد الكيامان O4
+
+154
+00:13:25,150 --> 00:13:33,550
+بخطوة إضافية بيخليه حامض واضح فال CH2 بتصير CO2
+
+155
+00:13:45,300 --> 00:13:52,260
+والـ RCRبيبقى زي ما هي R C double bond O R واضح
+
+156
+00:13:52,260 --> 00:13:57,860
+اذا انتوا لو اتياكم اي مركب و بدنا نعمله تكسير في
+
+157
+00:13:57,860 --> 00:14:01,440
+ال KMnO4 صح احنا عارفين انه بالخطوة الاولى بدنا
+
+158
+00:14:01,440 --> 00:14:04,700
+نعمل C double bond O و C double bond O هذا كلام
+
+159
+00:14:04,700 --> 00:14:09,360
+مافيش عليه خلاف لكن بيصير عندى further oxidation
+
+160
+00:14:09,360 --> 00:14:14,920
+يعني تاكسد اضافي لان ال KMnO4 عامل مؤكسد قوي ايش
+
+161
+00:14:14,920 --> 00:14:19,980
+تاكسد الاضافة اي CH2النتيجة النهائية بتاعتها ايش
+
+162
+00:14:19,980 --> 00:14:29,800
+بتكون؟ CO2 IRCH النتيجة النهائية بتاعتها RCOOH
+
+163
+00:14:29,800 --> 00:14:36,980
+و IRCR بظلة زي ما هي RCOOR فلو جيبنا لكوا أي خلية
+
+164
+00:14:36,980 --> 00:14:40,540
+من هذه المراكبات يعني مثلا لو هذا المراكب اللي
+
+165
+00:14:40,540 --> 00:14:44,980
+رسمناه كنا حاطين هنا R و R و حاطنا لكوا من كيعمن
+
+166
+00:14:44,980 --> 00:14:45,640
+O4
+
+167
+00:14:50,300 --> 00:14:55,520
+هتكسروا الى جزءين هذا الجزء الاول شو هيعمل هيظله
+
+168
+00:14:55,520 --> 00:15:09,040
+زى ما هو R C double bond O R و الجزء التانى R C
+
+169
+00:15:09,040 --> 00:15:15,800
+double bond O O H واضح بهذا الشكل
+
+170
+00:15:28,220 --> 00:15:37,280
+الان شغلة إضافية ال الكينز نفسها ممكن تتكسر تكسر
+
+171
+00:15:37,280 --> 00:15:43,900
+شبيه باستعمال الأوزون بتعرفوا الأوزون اللي بنسميه
+
+172
+00:15:43,900 --> 00:15:48,380
+الاتروبوف أكسجين يعني الأكسجين في وضعه الطبيعي في
+
+173
+00:15:48,380 --> 00:15:57,810
+الدنيا O2 في صورة تانية له O3هذه الصور للعنصر
+
+174
+00:15:57,810 --> 00:16:01,510
+الواحد بس اللي بتختلف بشكل وجوده في الطبيعة
+
+175
+00:16:01,510 --> 00:16:09,650
+بنسميها الوتروبز أو بالعرب شو بتسموها؟ نظائر لا
+
+176
+00:16:09,650 --> 00:16:15,910
+نظائر ايزوتوبز وموضوعها مختلف اتفاق في عدد
+
+177
+00:16:15,910 --> 00:16:19,430
+البروتونات واختلاف في عدد النيوترونات هذه ايزوتوبز
+
+178
+00:16:19,430 --> 00:16:29,740
+الوتروبز مش ايزوتوبز الوتروبزمر عليكم؟ Allotropes
+
+179
+00:16:29,740 --> 00:16:34,700
+من أمثلتها ال O2 و ال O3 من أمثلتها في الكربون،
+
+180
+00:16:34,700 --> 00:16:40,000
+مين اتذكرنا؟ اه كيف الكربون في الطبيعة؟ ال
+
+181
+00:16:40,000 --> 00:16:46,400
+graphite و ال diamond ال diamond هو ال mass و C60
+
+182
+00:16:46,400 --> 00:16:51,920
+كرة الكربون ستين إذا سمعتوا أنا ماسمعتوش من أوض
+
+183
+00:16:51,920 --> 00:16:57,510
+نحكيلكوا عنهاGraphite و Diamond و C60 من أمثلتها
+
+184
+00:16:57,510 --> 00:17:03,090
+بالفوسفور تبع الحرب ايش الصور اللي بنوجد عليها
+
+185
+00:17:03,090 --> 00:17:10,930
+الفوسفور بالطبيعة؟ الأبيض و الأحمر ايش اللي
+
+186
+00:17:10,930 --> 00:17:18,310
+انخبطوا فيه؟ أه الأبيضوالأحمر طبعا الاختلاف بينهم
+
+187
+00:17:18,310 --> 00:17:22,570
+كيف الذرات بتكون متركبة مع بعض واضح هذه الأشياء
+
+188
+00:17:22,570 --> 00:17:27,630
+بنسميها Allotropes أو صور تهاصل يحصل الان إذا
+
+189
+00:17:27,630 --> 00:17:31,910
+فعلنا ال double bond مع ال allotrope تبع ال oxygen
+
+190
+00:17:31,910 --> 00:17:34,350
+ال O2 اللي هو ال O3 الأوزون
+
+191
+00:17:36,980 --> 00:17:43,720
+وأكمل التفاعل مع الزنك في وجود حامض النتيجة
+
+192
+00:17:43,720 --> 00:17:47,820
+النهائية أسهل من المثال السابق تبع الكمان او فورت
+
+193
+00:17:47,820 --> 00:17:52,780
+ايا كان عندى بدأ تنكسر هذه الرابط و تعمل cw.o وcw
+
+194
+00:17:52,780 --> 00:17:58,540
+.o بدون ما تعمل further oxidation يعني في حالة
+
+195
+00:17:58,540 --> 00:18:02,770
+الكمان او فورت لما كان عندى CH2 كنت اردتأكسد
+
+196
+00:18:02,770 --> 00:18:08,230
+المُركّب درجة إضافية واصلة لـ CO2 أو RCH أكسده لـ
+
+197
+00:18:08,230 --> 00:18:13,110
+R C double bond O H الأن هنا لأ الناتج اللى بيطلع
+
+198
+00:18:13,110 --> 00:18:17,250
+عندى في التكسر بغض النظر عن ال intermediate يعني
+
+199
+00:18:17,250 --> 00:18:22,510
+هذه القطعة لاحظوا فيها H في الأساس ايش الناتج
+
+200
+00:18:22,510 --> 00:18:28,440
+بيطلع فين ال CHC double bond O غيرت فيها اشيزي ميا
+
+201
+00:18:28,440 --> 00:18:33,680
+بس كسرتها من النصف هاد ال CH2 شو بتصير CH2C double
+
+202
+00:18:33,680 --> 00:18:40,660
+bond O فكأنه .. كأنه هنا الأوزون عامل مؤكسب أضعف
+
+203
+00:18:40,660 --> 00:18:45,500
+من إيش ال camon O4 بمعنى بس بيكسر ال double bond
+
+204
+00:18:45,500 --> 00:18:53,180
+لتنتين C double bond O و بعد هيك و بعد هيك مابعملش
+
+205
+00:18:53,180 --> 00:18:59,440
+إيش إضافي ال camon O4بعمل شغل إضافي، واضح الكلام؟
+
+206
+00:18:59,440 --> 00:19:04,660
+هذا نتيجة التكثُر اللي بنسميه احنا ash و zonolysis
+
+207
+00:19:04,660 --> 00:19:08,180
+of alkanes طبعا بيمور عبر intermediate مش كتير
+
+208
+00:19:08,180 --> 00:19:10,460
+احنا مهتمين بتفاصيلها
+
+209
+00:19:14,620 --> 00:19:19,520
+هنا في عندى أمثلة مختلفة .. أمثلة مختلفة ممكن
+
+210
+00:19:19,520 --> 00:19:25,060
+نتطلع عليها بسرعة، المثال الأول هو ozonolysis،
+
+211
+00:19:25,060 --> 00:19:28,520
+ozone و رمرة واحد و رمرة اتنين zinc في وجود
+
+212
+00:19:28,520 --> 00:19:33,020
+الحامض، إيش اللي بدنا نعمله؟بناخد المُركّب زي ما
+
+213
+00:19:33,020 --> 00:19:40,100
+هو C double bond O و C double bond O المثال التالي
+
+214
+00:19:40,100 --> 00:19:44,300
+نفس الاشي و التالت و الرابع بس طبعا المثال التالت
+
+215
+00:19:44,300 --> 00:19:47,000
+عشان ال double bond في داخل حلقة و كذلك الرابع
+
+216
+00:19:47,000 --> 00:19:50,460
+بتفتح الحلقة يعني بيصير عندي C double bond O و C
+
+217
+00:19:50,460 --> 00:19:56,060
+double bond O بيصير عندي ring opening ملاحظين كيف
+
+218
+00:19:56,060 --> 00:20:00,340
+الحلقة الفتحت من هنا في نهاي كل double bond بتصير
+
+219
+00:20:02,190 --> 00:20:07,770
+وهل ال ozone بيعمل further oxidation لأ لما يكون
+
+220
+00:20:07,770 --> 00:20:12,130
+عنده H بيبقى H لو كانت CH2 بيبقى CH2 وما بيعمل ال
+
+221
+00:20:12,130 --> 00:20:14,210
+ozone further oxidation
+
+222
+00:20:19,320 --> 00:20:25,280
+بنجي لأ مثال إضافي على ال alkanes لكن هنا إحنا
+
+223
+00:20:25,280 --> 00:20:30,760
+بناخد نوع من ال alkanes مش double bond واحدة فيه،
+
+224
+00:20:30,760 --> 00:20:35,440
+فيه تنتين، واضح؟
+
+225
+00:20:35,440 --> 00:20:40,380
+الآن لو قولنا إن إحنا عندنا تنتين double bonds،
+
+226
+00:20:40,380 --> 00:20:48,850
+بدو يصير المركب بدل ما هو alkanes بدو يصيرواضح؟
+
+227
+00:20:48,850 --> 00:20:54,070
+اذا ان انا في عندى in double bond واحدة, die in
+
+228
+00:20:54,070 --> 00:20:57,630
+two double bonds, try in ..
+
+229
+00:21:07,440 --> 00:21:28,020
+تلاتة double bonds
+
+230
+00:21:28,020 --> 00:21:32,910
+و هكذاتنفصل بـ double bond يعني يكون عندي double
+
+231
+00:21:32,910 --> 00:21:39,060
+single double إذا ممكن يكون عندي double doubleاو
+
+232
+00:21:39,060 --> 00:21:43,900
+double single double او اكون بين ال two double
+
+233
+00:21:43,900 --> 00:21:49,160
+bonds اكتر من واحدة تنتين تلاتة اربعة كله بيصير
+
+234
+00:21:49,160 --> 00:21:53,420
+نفس الاشي يعني يكون عندى double bond single كمان
+
+235
+00:21:53,420 --> 00:21:57,260
+single واحدة او تنتين او تلاتة اي ان كانوا وبعدين
+
+236
+00:21:57,260 --> 00:22:01,600
+double bond تانية هذه الانواع التلاتة من ال
+
+237
+00:22:01,600 --> 00:22:08,360
+alkanes لها اسماء النوع الاول بيسموه cumulatedيعني
+
+238
+00:22:08,360 --> 00:22:15,700
+ورا بعض بالظبط .. cumulated .. cumulated ضايين
+
+239
+00:22:15,700 --> 00:22:22,080
+واضح؟ النوع التاني هو اللي عندنا هو محور النقطة
+
+240
+00:22:22,080 --> 00:22:25,340
+اللي بنحكيها الآن conjugated معناه conjugation
+
+241
+00:22:25,340 --> 00:22:30,390
+double singledouble إذا هذا النوع التالت اللي هو
+
+242
+00:22:30,390 --> 00:22:36,350
+دارسنا اليوم إيش اسمه conjugated diet وإله تفاعلات
+
+243
+00:22:36,350 --> 00:22:41,670
+خاصة فيه النوع التالت ابعيد عن بعضه منعزل عن بعضه
+
+244
+00:22:41,670 --> 00:22:47,330
+إيش بنسميه isolated بتعرف isolation عزل لما نقول
+
+245
+00:22:47,330 --> 00:22:53,390
+إنه في بني آدم isolated منعزل بنفعل بني آدم يكون
+
+246
+00:22:53,390 --> 00:23:00,690
+منعزل إجتماعيااه أبو .. وين بيكون منعزل؟ إذا كان
+
+247
+00:23:00,690 --> 00:23:04,890
+في مجتمع كافر لازم ينعزل، الآية بتقول و أعتزلكم
+
+248
+00:23:04,890 --> 00:23:09,170
+وما تدعونا من دون الله و أدعو ربي عسى الله أكون
+
+249
+00:23:09,170 --> 00:23:16,110
+بدعاه، ربي .. ايه مش هاطل؟ اجتماعي بالمناسبة في
+
+250
+00:23:16,110 --> 00:23:19,850
+المجتمع المسلم حتى لو فيه مشاكل
+
+251
+00:23:21,420 --> 00:23:26,200
+المسلم الذي يخالط الناس ويصبر على أذاههم خيره من
+
+252
+00:23:26,200 --> 00:23:29,660
+الذي لا يخالطهم ولا يصبر على أذاههم، عشانك مش لازم
+
+253
+00:23:29,660 --> 00:23:32,060
+نعزز الاجتماع، عشان فين قدش بتغلبوا في ال homework
+
+254
+00:23:32,060 --> 00:23:37,540
+لكن مش عاملين نعزز الاجتماع، الآن احنا اللي بدنا
+
+255
+00:23:37,540 --> 00:23:47,820
+ناخده تحديدا على ال conjugated ضايين إضافة HBRلأنه
+
+256
+00:23:47,820 --> 00:23:54,740
+إلها مواصفة معينة إضافة الـ HPR في وجود حامض بتعرف
+
+257
+00:23:54,740 --> 00:23:58,360
+إحنا إنه في وجود الحامض أول ما بيبدأ التفاعل H
+
+258
+00:23:58,360 --> 00:24:02,280
+Plus بتضيف على أحد الطرفين الآن اتخيلوا معاك،
+
+259
+00:24:02,280 --> 00:24:05,560
+تذكروا الكلام اللي أخدنا إذا ضافت الـ H Plus هنا،
+
+260
+00:24:05,560 --> 00:24:09,800
+شو بيصير؟ secondary carbocation إذا ضافت هنا
+
+261
+00:24:09,800 --> 00:24:16,420
+primary، الأول مفضل، secondary إذن هذا مش خلافأذا
+
+262
+00:24:16,420 --> 00:24:20,800
+الـ H plus بتضيف هنا بتكون له الـ secondary
+
+263
+00:24:20,800 --> 00:24:26,120
+carbocation هل ال secondary carbocation إذا لقى PR
+
+264
+00:24:26,120 --> 00:24:32,990
+minus بتفاعل وبناء على ذلك بيصير عند H و PRالاضافة
+
+265
+00:24:32,990 --> 00:24:37,750
+العادية اللى احنا اتعلمناها اضافة HPR على رابطة
+
+266
+00:24:37,750 --> 00:24:44,270
+زوجية الارياتورا لو ال PR minus اتأخر لما يصل
+
+267
+00:24:44,270 --> 00:24:49,450
+للايون الموجب ملاحظين انتوا ممكن يتأخر في التفاعل
+
+268
+00:24:49,450 --> 00:24:53,670
+لما يصل للايون الموجب بيصير عندى احتمال تانى انه
+
+269
+00:24:53,670 --> 00:24:57,990
+هنا انا في عندى هنا انا في عندى جنب هذا الموجب
+
+270
+00:24:57,990 --> 00:24:59,950
+الموجب قاعد بيستنى بده ايش
+
+271
+00:25:02,810 --> 00:25:08,190
+الموجب دائما يمثل شحنة مصيبة بده يتعادل بده سالب
+
+272
+00:25:08,190 --> 00:25:14,450
+فإذا لقى ال PR minus زي ما بيقولوا بها ونعمة بضيف
+
+273
+00:25:14,450 --> 00:25:19,550
+ال PR على طول طب إذا مالقاش ال PR minus بتيجي ال
+
+274
+00:25:19,550 --> 00:25:24,250
+double boot بتقول أنا كثافة إلكترونية بتلوف بهذا
+
+275
+00:25:24,250 --> 00:25:29,960
+الشكل بتعطي إلكتروناتواضح؟ الان لاحظوا .. لاحظوا
+
+276
+00:25:29,960 --> 00:25:34,040
+معنى لما ال double bond تلف بهذا الشكل تعطيه
+
+277
+00:25:34,040 --> 00:25:38,300
+إلكترونات محال هانا شو بده يصير عندى؟ Ion Moja
+
+278
+00:25:38,300 --> 00:25:45,580
+بجديد، إذا هي حلت مشكلة حقيقة ماحلتش مشكلة، بناء
+
+279
+00:25:45,580 --> 00:25:51,100
+على ذلك صارت عندى مشكلة جديدةهذا ال ايون الموجة
+
+280
+00:25:51,100 --> 00:25:56,720
+بالجديد إما بيلاقي PR- وبالتالي بتضيف بسرعة هذا
+
+281
+00:25:56,720 --> 00:26:00,880
+إذا ما لاجعش ممكن ال double bond ترجع و ترجع تكون
+
+282
+00:26:00,880 --> 00:26:07,400
+هذا الايون إذا كأنه هذا الايون اللي احنا بنسميه
+
+283
+00:26:07,400 --> 00:26:12,420
+قلل كتايون مر علينا في double bonds مجموعة القلل
+
+284
+00:26:12,420 --> 00:26:20,100
+القلل double bond CH2 زي هي كانت double bondCH2
+
+285
+00:26:20,100 --> 00:26:24,060
+هدى كانت مجموعة القلل مظبوط الان لو طلعته انا
+
+286
+00:26:24,060 --> 00:26:30,380
+double bond CH2 هدى قلل ولا لأ اه هدى القلل كتايل
+
+287
+00:26:30,380 --> 00:26:36,480
+بنقول عنه بيعمل resonance اش يعني resonance حركة
+
+288
+00:26:36,480 --> 00:26:40,000
+إلكترونات فقط عمرنا لما نسأل نقولكوا اش يعني
+
+289
+00:26:40,000 --> 00:26:44,300
+انكتوا اعطونى ترجمة العرب اعطونى المعنىلما أخدنا
+
+290
+00:26:44,300 --> 00:26:50,060
+ال resonance في أول فصل قلنا لكم ال resonance حركة
+
+291
+00:26:50,060 --> 00:26:54,840
+إلكترونات ال resonance حركة إلكترونات وكيف يعبر
+
+292
+00:26:54,840 --> 00:26:59,580
+عنه؟بالسهم اللي زي هيك اللي اسمه double headed
+
+293
+00:26:59,580 --> 00:27:03,340
+arrows فقط الإلكترونات اللي قاعدة بتتحرك هيك مرة و
+
+294
+00:27:03,340 --> 00:27:07,060
+بترجع هيك مرة فقط حركة إيش؟ إلكترونات الرانين
+
+295
+00:27:07,060 --> 00:27:11,720
+رانين إلكترونات بتكون تتحرك باتجاههم movement of
+
+296
+00:27:11,720 --> 00:27:16,320
+electrons واضح؟ فاللي بنقوله إحنا أن القليل
+
+297
+00:27:16,320 --> 00:27:20,500
+الكاتيون بيكون في عملية resonance هذا الكلام
+
+298
+00:27:20,500 --> 00:27:24,480
+بيخلّي بعد ما ضافة ال H على أول موقع ال PR يا
+
+299
+00:27:24,480 --> 00:27:30,340
+بضيفها موقع اتنينيعني على موقع اربعة اذا انا في
+
+300
+00:27:30,340 --> 00:27:37,340
+اضافة ال HBR ع ال conjugated دايين بلاحظ ان عنده
+
+301
+00:27:37,340 --> 00:27:44,760
+ناتجين اما انه يكون عنده one two additionأو one
+
+302
+00:27:44,760 --> 00:27:49,240
+four addition يا الإضافة بالتم على موقع و على اللي
+
+303
+00:27:49,240 --> 00:27:53,840
+بعده مباشرة يا بتضيف على موقع و على نمرة أربعة
+
+304
+00:27:53,840 --> 00:27:57,040
+بالنسبة له شوفتوا إيش تفسير ال one two و ال one
+
+305
+00:27:57,040 --> 00:28:00,940
+four addition اللي بنقولكوا فسروا انه على هذا
+
+306
+00:28:00,940 --> 00:28:06,980
+الضين ال conjugated ضين الناتجخليط من مركبين خليط
+
+307
+00:28:06,980 --> 00:28:10,680
+من ال one two addition و ال one four addition ماهو
+
+308
+00:28:10,680 --> 00:28:14,720
+السبب انه بتكون عندى قليل كتاين ال قليل كتاين
+
+309
+00:28:14,720 --> 00:28:18,920
+بيعمل resonance مرة لمو جبهال مرة لمو جبهال مرة
+
+310
+00:28:18,920 --> 00:28:23,120
+لمو جبهال مرة لمو جبهال يا ترى ال resonance بيقلل
+
+311
+00:28:23,120 --> 00:28:24,620
+الثبات ولا بيزيده؟
+
+312
+00:28:28,020 --> 00:28:32,160
+يعني بيكون more stable ولا less stable لما بيكون
+
+313
+00:28:32,160 --> 00:28:39,020
+في عندى resonance طيب خلينا نتخيل القاتل انه احنا
+
+314
+00:28:39,020 --> 00:28:46,610
+مروحين من السوق وحملين عشرة كيلوو بدنا نمشي تقريبا
+
+315
+00:28:46,610 --> 00:28:51,330
+500 متر للدار هل يا تورا احنا بنضل حاملين العشرة
+
+316
+00:28:51,330 --> 00:28:54,810
+كيلو بإيد واحدة ولا بنكون قاعدين نعمل resonance؟
+
+317
+00:28:54,810 --> 00:28:59,470
+لو صورنا أي بني أدم مروح بعشرة كيلو، إيش بيعمل؟
+
+318
+00:28:59,470 --> 00:29:02,190
+بيعمل resonance، مرة بالإيد هذه، مرة بالإيد هذه،
+
+319
+00:29:02,190 --> 00:29:06,010
+مرة بالإيد هذه، مرة بالإيد هذه فال resonance حقيقة
+
+320
+00:29:06,010 --> 00:29:13,650
+is a stabilizing effectهو تأثير تثبيتي بثبت الشحنة
+
+321
+00:29:13,650 --> 00:29:22,670
+بدل ما الشحنة على جهة واحدة بتكون الشحنة على جهتين
+
+322
+00:29:22,670 --> 00:29:28,610
+واضح؟ الان كل بني آدم .. كل بني آدم بيقدر يفهم
+
+323
+00:29:28,610 --> 00:29:33,990
+الموضوع بطريقته في موضوع ال resonanceواضح؟ كل بني
+
+324
+00:29:33,990 --> 00:29:37,870
+أدم بيقدر في موضوع ال resonance يفهم الموضوع
+
+325
+00:29:37,870 --> 00:29:44,950
+بطريقته اعطيكم مثال .. مثال من الحياة مثلا لو
+
+326
+00:29:44,950 --> 00:29:53,650
+افترضنا اتنين اخوة و عندهم ام او اب كبير بدوا خدمة
+
+327
+00:29:53,650 --> 00:30:00,810
+معينة ايش بتلاحظوا بواقع الناس؟بحاولوا يعملوا
+
+328
+00:30:00,810 --> 00:30:06,150
+resonance، انه والله خلّي أسبوع هنا و أسبوع هنا،
+
+329
+00:30:06,150 --> 00:30:11,430
+أسبوع هنا و أسبوع هنا، واضح؟ الآن هذا ال resonance
+
+330
+00:30:11,430 --> 00:30:16,650
+في وجهة نظرهم في الدنيا، ان هم ايش؟ بتريحوا هم أو
+
+331
+00:30:16,650 --> 00:30:22,110
+نسوانهم، بتريحوا من غلبة الأب أو الأم، مظبوط ولا
+
+332
+00:30:22,110 --> 00:30:26,620
+لا؟لكن الناس اللي بيفهم و شو بيعملوا؟ بيكونوا
+
+333
+00:30:26,620 --> 00:30:31,020
+يتقاتلوا مين يخلي الأب أو الام عنده، في قضية
+
+334
+00:30:31,020 --> 00:30:34,980
+مرفوعة بالمحاكم السعودية بين اتنين أخوة و حاطين
+
+335
+00:30:34,980 --> 00:30:38,740
+أكبر المحامين بتقاتلوا على أمهم، كل واحد بده أمه
+
+336
+00:30:38,740 --> 00:30:42,720
+تكون عنده يقدمها في العشر الأواخر زي ما بيقولوا من
+
+337
+00:30:42,720 --> 00:30:46,480
+العمر، و انتوا احسبوها عد ايش اللي بتعملوا بحياتكم
+
+338
+00:30:49,210 --> 00:30:52,990
+ما .. ما هو الان اللي بيكونوا ينقلوا الام و الأبو
+
+339
+00:30:52,990 --> 00:30:57,590
+بيقولوا بدهم ثبات إيش؟ بدهم ال resonance أو الثبات
+
+340
+00:30:57,590 --> 00:31:03,350
+اللي هو تبع الدنيا و اللي بده يحافظ عليهم طيب و
+
+341
+00:31:03,350 --> 00:31:11,550
+الآية إيش بتقول؟ و للآخرة خير و أبقى فمن الناس ما
+
+342
+00:31:11,550 --> 00:31:16,510
+يقولوا ربنا آتنا في الدنيا و ما له في الآخرةومنهم
+
+343
+00:31:16,510 --> 00:31:21,570
+من يقول ربنا أتنا في الدنيا حسنة وفي الآخرة حسنة
+
+344
+00:31:21,570 --> 00:31:28,810
+وقنا عذاب النهار والله سريع الحساب هذا الكلام نزل
+
+345
+00:31:28,810 --> 00:31:30,250
+في الآيات اللي هي إيش؟
+
+346
+00:31:33,690 --> 00:31:38,270
+في الآيات لبعد الحج مباشرة لأن العرب كانوا بعد
+
+347
+00:31:38,270 --> 00:31:42,630
+الحج مجرد ما يخلصوا الرجم وكل إشي يتجهوا باتجاه
+
+348
+00:31:42,630 --> 00:31:46,590
+جبل عرفات هم في مينة ويصيروا يدعوا ويتفاخروا
+
+349
+00:31:46,590 --> 00:31:50,950
+بالآباء والأجداد ولذلك الآية قالتلهم فإذا قضيتم
+
+350
+00:31:50,950 --> 00:31:56,330
+مناسككم فاذكروا الله كذكركم آباءكم أو أشد ذكرة
+
+351
+00:31:56,330 --> 00:32:01,110
+يعني يكون هدفكوا الآخرة مش الدنيا هم كانوا يحجوا
+
+352
+00:32:01,110 --> 00:32:06,870
+اخلصواإيش يقفوا يقولوا في نهاية الحجة؟ أبويا و
+
+353
+00:32:06,870 --> 00:32:11,910
+أبوك يتفخروا بالدنيا، الآية جالتلهم فاذكروا الله
+
+354
+00:32:11,910 --> 00:32:16,790
+كذكركم آباءكم أو أشد ذكره فمن الناس من يقولوا ربنا
+
+355
+00:32:16,790 --> 00:32:23,370
+آتنا فاتنا على أي حال، تفاعل إضافي، اتعبتم من
+
+356
+00:32:23,370 --> 00:32:27,210
+تفاعلات ال ال kids إذا جيبنالكم على السؤال صح و
+
+357
+00:32:27,210 --> 00:32:30,650
+غلط في الامتحان ال kids are inert و واحدة بتقول
+
+358
+00:32:30,650 --> 00:32:31,370
+مظبوط
+
+359
+00:32:34,370 --> 00:32:39,170
+الالكينز تفاعلاته مكتيرة جدا هذا التفاعل بنسميه
+
+360
+00:32:39,170 --> 00:32:43,630
+deals elder reaction deals elder reaction هو عبارة
+
+361
+00:32:43,630 --> 00:32:50,330
+عن تفاعل بنسميه cycle addition reaction ايش يعني
+
+362
+00:32:50,330 --> 00:32:55,110
+cycle addition reaction؟معنى cycle addition
+
+363
+00:32:55,110 --> 00:33:01,130
+reaction هو تفاعل بأكون أنا فيه رابطتين في نفس
+
+364
+00:33:01,130 --> 00:33:05,990
+الوقت، في نفس اللحظة، يعني لو افترضت أنا عند
+
+365
+00:33:05,990 --> 00:33:11,180
+قطعتين بهذا الشكلو إي جيت جربتهم جربتهم جربتهم على
+
+366
+00:33:11,180 --> 00:33:15,620
+بعض بهذا الشكل لحد ما صار رابطة لان أنا كام رابطة
+
+367
+00:33:15,620 --> 00:33:20,380
+قاعد بعمل بنفس اللحظة رابطتين هذا التفاعل اللي
+
+368
+00:33:20,380 --> 00:33:24,660
+بضيف قطعتين بنفس اللحظة و بكون two new sigma bonds
+
+369
+00:33:24,660 --> 00:33:30,520
+بسميه cycle addition reaction
+
+370
+00:33:30,520 --> 00:33:33,280
+و من هذه التفاعلات تفاعلات إيش
+
+371
+00:33:48,260 --> 00:33:52,440
+بينما لو انا كنت بدي اعمل حلقة معينة زي هيك بس
+
+372
+00:33:52,440 --> 00:33:59,170
+اسكر طرفينهابعمل رابطة واحدة
+
+373
+00:33:59,170 --> 00:34:02,190
+تفاعل
+
+374
+00:34:02,190 --> 00:34:03,030
+عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل
+
+375
+00:34:03,030 --> 00:34:03,510
+حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة
+
+376
+00:34:03,510 --> 00:34:05,210
+تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل
+
+377
+00:34:05,210 --> 00:34:12,710
+عمل حلقة تفاعل عمل حلقة تفاعل
+
+378
+00:34:12,710 --> 00:34:15,610
+عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل
+
+379
+00:34:15,610 --> 00:34:15,610
+حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة
+
+380
+00:34:15,610 --> 00:34:17,350
+تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل
+
+381
+00:34:17,350 --> 00:34:24,570
+عمل حلقة تفاعل عمل حcycloaddition واضح؟ إذا في
+
+382
+00:34:24,570 --> 00:34:28,410
+عندي نوعين لتكوين الحلقات يا إما cyclization من
+
+383
+00:34:28,410 --> 00:34:32,650
+خلال رابط واحدة يا إما cycloaddition من خلال
+
+384
+00:34:32,650 --> 00:34:38,190
+رابطتين ال deals under reaction هو أحد التفاعلات
+
+385
+00:34:38,190 --> 00:34:43,770
+ال cycloaddition المتعلقة بال double bonds ولذلك
+
+386
+00:34:43,770 --> 00:34:47,670
+احنا بندرسه هنا ليش بندرس ال deals under reaction
+
+387
+00:34:47,670 --> 00:34:53,630
+لأن هو تمين تفاعلاتالـ Double bonds من تفاعلات الـ
+
+388
+00:34:53,630 --> 00:34:56,210
+Double bonds طيب نشوف ايش هو ال deals under
+
+389
+00:34:56,210 --> 00:35:03,270
+reaction ال deals under reaction بتتم في تفاعل ال
+
+390
+00:35:03,270 --> 00:35:06,750
+one three دايين او ال conjugated دايين لاحظوا هذا
+
+391
+00:35:06,750 --> 00:35:11,390
+one two three four conjugated دايين مع double bond
+
+392
+00:35:11,390 --> 00:35:15,990
+يعني تنتين double bonds conjugated مع double bond
+
+393
+00:35:15,990 --> 00:35:19,730
+واحدة ايش النتيجة النهائية تكوين رابط اهان و رابط
+
+394
+00:35:19,730 --> 00:35:26,100
+اهانإذا كام رابطة؟ تن تن عشان ما تغلطوش في التعبير
+
+395
+00:35:26,100 --> 00:35:29,480
+عن الناتج بيقولولكوا تخيلوا انكوا حركتوا الرابطة
+
+396
+00:35:29,480 --> 00:35:33,040
+هذي زي هيك هذي زي هيك هذي زي هيك بتطلع عندى حلقة
+
+397
+00:35:33,040 --> 00:35:39,680
+سداسية فيها رابطة زوجية واحدة يعني كإنا بنقول ان
+
+398
+00:35:39,680 --> 00:35:43,420
+ال reaction of the one three ضايين هذا one two
+
+399
+00:35:43,420 --> 00:35:48,400
+threeone three-diene with an alkene with double
+
+400
+00:35:48,400 --> 00:35:53,880
+bond produces cyclohexane
+
+401
+00:35:53,880 --> 00:35:59,460
+..hexane in يعني فيه double bond واحدة لما بتكون
+
+402
+00:35:59,460 --> 00:36:02,980
+تحطوا الجواب صح أسهل إش تحركوا رابط هيك و رابط هيك
+
+403
+00:36:02,980 --> 00:36:07,970
+و رابط هيك حتى تكتبوا الجواب بسهولةهي عندى مثال
+
+404
+00:36:07,970 --> 00:36:11,430
+تانى هى تضيين هذا ال conjugated وهى double bond
+
+405
+00:36:11,430 --> 00:36:15,070
+حتى لو double bond كانت بحلقة مش مشكلة هى واحد
+
+406
+00:36:15,070 --> 00:36:20,010
+اتنين تلاتة هذه اللى بده تصير ال new sigma bond
+
+407
+00:36:20,010 --> 00:36:23,390
+هنا هذه اللى بده تصير ال new sigma bond هنا و هذه
+
+408
+00:36:23,390 --> 00:36:28,490
+اللى بده تتحرك هنا طلع عندى برضه cyclohexane ولو
+
+409
+00:36:28,490 --> 00:36:33,640
+متحد مع حلقة تانية هذا التفاعل شو بنسميه احناdeals
+
+410
+00:36:33,640 --> 00:36:38,600
+elder reaction او deals elder cycloaddition
+
+411
+00:36:38,600 --> 00:36:44,540
+reaction فاذا قلنالكم deals elder reaction is a
+
+412
+00:36:44,540 --> 00:36:50,220
+cyclizing reaction او cyclization reaction خطأ هو
+
+413
+00:36:50,220 --> 00:36:55,900
+cycloaddition a reaction in which two new sigma
+
+414
+00:36:55,900 --> 00:37:03,510
+bondsare formed at the same time اني بكون رابطتين
+
+415
+00:37:03,510 --> 00:37:08,950
+مش رابطة واحدة هم لاحظين هى و هنا اجت رابطة و هنا
+
+416
+00:37:08,950 --> 00:37:14,170
+اجت رابطة we are forming two new sigma bonds
+
+417
+00:37:28,040 --> 00:37:37,740
+من التفاعلات الإضافية المهمة جدا لـAlkenes
+
+418
+00:37:37,740 --> 00:37:42,080
+وتحديدا ممكن ناخد لأبسط Alkenes اللي هو الاثيليين
+
+419
+00:37:42,080 --> 00:37:47,760
+تفاعل عمل Polymerإيش يعني polymer؟ بيكون عندى جزيق
+
+420
+00:37:47,760 --> 00:37:53,060
+واحد بسميه أنا monomer بتحد مع عدد كبير من
+
+421
+00:37:53,060 --> 00:37:57,480
+الجزيقات بيعمله سلسلة polymer يعني لو افترضت هدول
+
+422
+00:37:57,480 --> 00:38:02,400
+الأقلام الأربعة زي بعض وكل واحد فيهم عبارة عن إيش؟
+
+423
+00:38:02,400 --> 00:38:06,940
+إثالين، هاي monomer، monomer، monomer، monomerهذا
+
+424
+00:38:06,940 --> 00:38:10,720
+الإثالين لأنه جزء واحد بالوضع الطبيعي بيكون إيش؟
+
+425
+00:38:10,720 --> 00:38:15,840
+غاز، مظبوط ولا لا؟ مش الإثالين غاز وبيحطوه بالغرف
+
+426
+00:38:15,840 --> 00:38:20,820
+المغلقة على الموز الأخضر عشان يستوي، بتشوفوا الموز
+
+427
+00:38:20,820 --> 00:38:24,550
+لما بيجيبوه استيراد كيف بيكون لونه؟أخضر على الآخر،
+
+428
+00:38:24,550 --> 00:38:28,250
+هيك .. هيك لازم الموز ي .. ينقل لأنه بيخرب بسرعة،
+
+429
+00:38:28,250 --> 00:38:31,830
+الآن قبل ما ينزلوا على السوق بيحطوا ليلة بغرفة
+
+430
+00:38:31,830 --> 00:38:36,130
+مغلقة بيمرروا عليه غاز الاثيلين، بينضج، بيصير
+
+431
+00:38:36,130 --> 00:38:41,010
+أصفر، الآن هذا الاثيلين لو أجينا وحدنا عدة جزيئات
+
+432
+00:38:41,010 --> 00:38:46,990
+منه، هاي جزيئة اتنين، تلاتة، أربعة، بدأ يكبر،
+
+433
+00:38:46,990 --> 00:38:50,070
+يكبر، يكبر، صيرنا ألفين، تلاتة آلاف، بيصير
+
+434
+00:38:50,070 --> 00:38:54,710
+polymer، ال polymer هذا plasticاملاحظين؟ يعني أنا
+
+435
+00:38:54,710 --> 00:39:00,490
+ببدأ بغاز، بضغطه، بنتهي ب plastic اللي هو ال
+
+436
+00:39:00,490 --> 00:39:04,390
+plastic الأبيض اللي بيعمله منه كثير من القوانين
+
+437
+00:39:04,390 --> 00:39:08,710
+وغيره وغيراتها هذا اللي اسمه polyethylene يعني فيه
+
+438
+00:39:08,710 --> 00:39:11,750
+أكتر من جزء إيثيلين هذه العملية عملية
+
+439
+00:39:11,750 --> 00:39:16,370
+polymerization فال polymerization أنه يكون عنده
+
+440
+00:39:16,370 --> 00:39:22,640
+monomerبظروف معينة من الضغط من درجة الحرارة من
+
+441
+00:39:22,640 --> 00:39:26,100
+إضافة البروكسايد البروكسايد عشان التفاعل free
+
+442
+00:39:26,100 --> 00:39:30,080
+radical reaction المرة الماضية أخدنا البروكسايد
+
+443
+00:39:30,080 --> 00:39:35,200
+بيصير CH2 CH2 to the N و N هذه بتطلع إلى تلتة اربع
+
+444
+00:39:35,200 --> 00:39:39,460
+تلاف جزء مع بعض لما يصير تلتة اربع تلاف جزء مع بعض
+
+445
+00:39:39,460 --> 00:39:46,600
+الغاز بيصيرplastic solid مظبوط ولا لأ؟ هذا زي حال
+
+446
+00:39:46,600 --> 00:39:50,920
+.. زي حال الناس حتى يعني لما يكون بني آدم لوحده
+
+447
+00:39:50,920 --> 00:39:57,720
+المعارض مثلا أيمن نور إيش عمل فيه النظام المصري؟
+
+448
+00:39:57,720 --> 00:40:02,280
+زلوا لأنه لحاله غاز و حبس و هو كان مرشح رئيس
+
+449
+00:40:02,280 --> 00:40:09,770
+جمهورية لكن لما صار عندى بوليمار من كل الشعبصرت
+
+450
+00:40:09,770 --> 00:40:14,790
+أمام حالة صلبة، هذه الحالة الصلبة انهرت قدامها كل
+
+451
+00:40:14,790 --> 00:40:20,830
+الدنيا، وعشان هي كبيت الشعر، ايش بيقول؟ تقبل
+
+452
+00:40:20,830 --> 00:40:28,550
+رماحه، إذا اجتمعنا تكسره، وإذا افترقنا تكسرت غاز
+
+453
+00:40:28,550 --> 00:40:35,230
+ذاتي، غاز بيكونانتوا افهموا يعني ال polymers ال
+
+454
+00:40:35,230 --> 00:40:39,050
+polymers مش موضوع بسيط يعني بيقولوا أهم اكتشافات
+
+455
+00:40:39,050 --> 00:40:43,850
+يمكن القرن الماضي مرات بيحكوا تكوين ال polymers
+
+456
+00:40:43,850 --> 00:40:48,110
+يعني تكوين ال nylon و تكوين ال plastic و تكوين ال
+
+457
+00:40:48,110 --> 00:40:52,570
+polystyrene و تكوينها الأقمشة الصناعية كل هذه
+
+458
+00:40:52,570 --> 00:40:56,130
+الأشياء هي اللي اليوم هي اللي رابطة حياتنا يعني
+
+459
+00:40:56,130 --> 00:41:00,370
+هذا الجلم اللي تطلع عليه الآن هذا ال plasticقبل
+
+460
+00:41:00,370 --> 00:41:03,470
+سبعين سنة ماكنش فيه ماكنش فيه غير جلم الارصاص اللي
+
+461
+00:41:03,470 --> 00:41:07,350
+بعمله من الخشب وفي قلبه كربون كان عندى هذه الشغلات
+
+462
+00:41:07,350 --> 00:41:11,210
+ماكنش هذا السبورة ماكنتش هذا الإجماش ماكنش هذا ال
+
+463
+00:41:11,210 --> 00:41:14,690
+plastic ماكنش هذا ال plastic ماكنش هذا ال plastic
+
+464
+00:41:14,690 --> 00:41:17,990
+ماكنش اليوم كل حياتكو صارت مبنية على هذه الفكرة
+
+465
+00:41:17,990 --> 00:41:22,450
+البسيطة يعني مش فكرة صغيرة تتخيلوها أنه أنا قاعد
+
+466
+00:41:22,450 --> 00:41:31,800
+بعص غاز بخليه solid واضح؟يعني هي من أكبر الأفكار
+
+467
+00:41:31,800 --> 00:41:35,700
+اللي صارت في القرن العشرين فكرة تكوين ال polymers
+
+468
+00:41:35,700 --> 00:41:40,440
+صناعات لبلاستيك و الأنابيب زمان كانت الأنابيب كلها
+
+469
+00:41:40,440 --> 00:41:44,800
+يا إما يعملوها أحيانا من ال اسمنت ماعرفش إذا أنتوا
+
+470
+00:41:44,800 --> 00:41:48,660
+وعيين لهذا النوع من الأنابيب أو من الحديد يعني
+
+471
+00:41:48,660 --> 00:41:52,260
+اللي كانوا ينظروا للبيوت القديمة الأنابيب المجارة
+
+472
+00:41:52,260 --> 00:41:56,890
+من إيش كانت تكون؟من الحديد الظاهر اللي بيكسر،
+
+473
+00:41:56,890 --> 00:42:00,430
+الأنابيب تبعت المي اللي في الشوارع، من إيش كانت
+
+474
+00:42:00,430 --> 00:42:05,850
+تكون؟ إسمنت، إسمنت و أشياء زي هيك اليوم كل الدنيا
+
+475
+00:42:05,850 --> 00:42:10,650
+صارت plastic من ورا مثل هذا التفاعل البسيط فما
+
+476
+00:42:10,650 --> 00:42:14,190
+تفهموش الموضوع أنه بس يعني أنه احنا بنحكي رموز و
+
+477
+00:42:14,190 --> 00:42:20,110
+بس، لا احنا بنحكي واقع، واقع حياةالان هذا التفاعل
+
+478
+00:42:20,110 --> 00:42:24,210
+كيف بيتم، بزام احنا عندنا البروكسايد، البروكسايد
+
+479
+00:42:24,210 --> 00:42:28,570
+اول ما شوية حرارة بيعطينا ايش، بنكسر homolytic
+
+480
+00:42:28,570 --> 00:42:32,550
+cleavage، الحصة الماضية أخدناها بيعطينا2 free
+
+481
+00:42:32,550 --> 00:42:36,650
+radicals هذا ال free radical بيجي على ال double
+
+482
+00:42:36,650 --> 00:42:39,110
+bond اللي لها ال double bond اللي لها كام electron
+
+483
+00:42:39,110 --> 00:42:45,390
+اتنين هياخد التفاعل مع electron واحد صار عند ال RO
+
+484
+00:42:45,390 --> 00:42:51,130
+CH2 CH2 و هذه ال CH2 بترفنية شو طال عليها electron
+
+485
+00:42:51,130 --> 00:42:57,090
+مظبوط الآن خدوا هذا الجزء ال RO CH2 CH2 و عليها
+
+486
+00:42:58,500 --> 00:43:04,220
+free radical فعلوها مع جزء إيثالين جديد و خليها
+
+487
+00:43:04,220 --> 00:43:10,280
+تعمل رابطة هنا كبرة اتنين و على الطرف free radical
+
+488
+00:43:10,280 --> 00:43:14,580
+كمان مرة كمان مرة كمان مرة لانه واصل لتالتة اربع
+
+489
+00:43:14,580 --> 00:43:19,640
+تلاف جزء صار عند بوليمار طبعا عشانه غاز انا بحاجة
+
+490
+00:43:19,640 --> 00:43:23,760
+إلى حرارة بحاجة إلى البروكسايد اللي بده يبدأ
+
+491
+00:43:23,760 --> 00:43:28,450
+للتفاعلهذا الشرارة تاعت التفاعل تاعت free radical
+
+492
+00:43:28,450 --> 00:43:31,890
+reaction و هذا ال polymerization بالمناسبة شو
+
+493
+00:43:31,890 --> 00:43:37,130
+بيسموها free radical polymerization of ethylene
+
+494
+00:43:37,130 --> 00:43:40,350
+free radical polymerization of ethylene عشان
+
+495
+00:43:40,350 --> 00:43:45,520
+يعطينا ال polyethylene شوفتوا كيف بالتم؟الان
+
+496
+00:43:45,520 --> 00:43:51,020
+العلماء طموحهم مابيقفش يعني انا بدأت بال إيثيلين
+
+497
+00:43:51,020 --> 00:43:57,700
+وصارت الوحدة المتكررة عندى إيش هي CH2 CH2 CH2 CH2
+
+498
+00:43:57,700 --> 00:44:05,720
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+499
+00:44:05,720 --> 00:44:09,160
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+500
+00:44:09,160 --> 00:44:09,160
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+501
+00:44:09,160 --> 00:44:09,920
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+502
+00:44:09,920 --> 00:44:09,940
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+503
+00:44:09,940 --> 00:44:11,300
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+504
+00:44:11,300 --> 00:44:11,300
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+505
+00:44:11,300 --> 00:44:18,570
+CH2 CH2 CHحطيت مكانها chlorine يعني بمعنى ان الجزء
+
+506
+00:44:18,570 --> 00:44:24,630
+الاول يكون زي هيك بس انا حطيت chlorine هذا المركب
+
+507
+00:44:24,630 --> 00:44:30,590
+اسمه vinyl chloride اخدتوا انتوا مجموعة CH2 double
+
+508
+00:44:30,590 --> 00:44:34,410
+bond CH اسم المجموعة ال vinyl لما يكون معاها
+
+509
+00:44:34,410 --> 00:44:38,250
+chlorineVinyl chloride الان لو ال vinyl chloride
+
+510
+00:44:38,250 --> 00:44:43,270
+عملوله polymerization بشغل بنفس الطريقة بعملي CH
+
+511
+00:44:43,270 --> 00:44:50,210
+متصلة ب CL CH2 to the N بصير polyvinyl chloride ال
+
+512
+00:44:50,210 --> 00:44:56,030
+polyvinyl chloride له اسم شهره مختصر ايش بنختصره
+
+513
+00:44:56,030 --> 00:45:05,900
+PVC مين فيكم ماسمعش في plastic ال PVCلأ لأ أبدا
+
+514
+00:45:05,900 --> 00:45:09,660
+ولا ألياف بصرية ولا إشي شوفتوا الأرضيات اللي مرات
+
+515
+00:45:09,660 --> 00:45:13,040
+بيعملوا منها المستشفيات وغيرها و ال studio هذه
+
+516
+00:45:13,040 --> 00:45:18,260
+كلها PVC شوفتوا هذا ال plastic و هذا التبع الشاشة
+
+517
+00:45:18,260 --> 00:45:23,390
+و الشونات تبعتكوا ال plastic كل هذا ال PVCنوع ابن
+
+518
+00:45:23,390 --> 00:45:27,590
+عمه للبولي إيثنين واضح؟ ابن عمه للبولي إيثنين ال
+
+519
+00:45:27,590 --> 00:45:32,050
+BVC أشهر إشي بتلاقوا المحلات تابعون ال decor اللي
+
+520
+00:45:32,050 --> 00:45:37,850
+بيبيعوا ستاير بيكونوا كاتبين لبايع ال BVC اللي هو
+
+521
+00:45:37,850 --> 00:45:41,630
+ال plastic اللي بيفردوه على الأرض على ال studio
+
+522
+00:45:41,630 --> 00:45:46,230
+على المطبخ عمركوا شفته؟ يمكن الآن الناس مع روح
+
+523
+00:45:46,230 --> 00:45:51,500
+السعر لكراميكابطلوا يهتموا فيه بس قبل حوالي 15 سنة
+
+524
+00:45:51,500 --> 00:45:56,100
+كنتوا معظم المحلات التجارية لما تدخلوها اتلاقوها
+
+525
+00:45:56,100 --> 00:46:02,480
+حاطة على الأرض بدل هذا السجاد PVC هو هذا البوليمار
+
+526
+00:46:02,480 --> 00:46:10,460
+ممكن كمان يبدو باستايرين الاستايرين المرة الماضية
+
+527
+00:46:10,460 --> 00:46:15,160
+حكينالكوا عنه اللي هو CH2 ضم ال bond CH وعليه
+
+528
+00:46:15,160 --> 00:46:22,700
+مجموعة بنزينبلاحظين هذا اسمه إيش؟ استايرين ..
+
+529
+00:46:22,700 --> 00:46:27,320
+استايرين ال polymer تبعه زي ال إفلين بس بدل H بال
+
+530
+00:46:27,320 --> 00:46:33,280
+hot funnel بصير polystyrene، plastic برضه، ما
+
+531
+00:46:33,280 --> 00:46:38,310
+تخلطوهوش في ال polyesterبتعرفوا البوليستر أول ما
+
+532
+00:46:38,310 --> 00:46:43,970
+بتشتريه جماش، إيش بتقوله؟ قداش قطن و قداش بوليستر
+
+533
+00:46:43,970 --> 00:46:48,890
+و كل ما نسبة القطن صارت أعلى، بتعتبروه أجود، بس
+
+534
+00:46:48,890 --> 00:46:54,890
+اليوم ماحدش برضه بيقبل نسبة قطن مية في الميةالا
+
+535
+00:46:54,890 --> 00:46:58,950
+polyester يكون معه يعني يكون اربعين او خمسين او
+
+536
+00:46:58,950 --> 00:47:02,670
+ستين في المية قطن كويس اربعين في المية polyester
+
+537
+00:47:02,670 --> 00:47:06,490
+بس مايكونش مية في المية polyester مية في المية
+
+538
+00:47:06,490 --> 00:47:10,250
+polyester بيكون petrol يعني لو اجت نار بيولع على
+
+539
+00:47:10,250 --> 00:47:16,450
+طول بالحرارة شديد على الجسم مظبوط ولا لأ؟ بيكون
+
+540
+00:47:16,450 --> 00:47:20,850
+خليط من القطن و من ال polyester الآن ال polyester
+
+541
+00:47:20,850 --> 00:47:26,660
+غير ال polystyreneعشان انتوا ماتخربتوش polystyrene
+
+542
+00:47:26,660 --> 00:47:31,860
+بلاستيك معين البولي إستر بيناعمل منه ال fibers
+
+543
+00:47:31,860 --> 00:47:38,060
+الخطان و منه كل الأقمشة مافيش فينا حد في لبسه إلا
+
+544
+00:47:38,060 --> 00:47:41,980
+موجود بولي إستر لا يمكن مافيش حد لابس قطن كتمة ولا
+
+545
+00:47:41,980 --> 00:47:45,200
+بمصنع اليوم كل هذا الجماش اللي انتوا شايفينه
+
+546
+00:47:45,200 --> 00:47:49,140
+الجاكيتات اللي بصاريش غالبا مخلوطة الخطان بتاعتها
+
+547
+00:47:49,140 --> 00:47:52,700
+اربعين خمسين في المية قطن اربعين خمسين في المية
+
+548
+00:47:53,460 --> 00:47:58,380
+بولي إستر البولي إستر بمر علينا بعدين غير البولي
+
+549
+00:47:58,380 --> 00:48:01,740
+ستايرين البولي ستايرين بلاستيك لبراميل وغيرها
+
+550
+00:48:01,740 --> 00:48:07,180
+وغيرها بس اللي بنعمل منه fibers هو البولي إستر
+
+551
+00:48:07,180 --> 00:48:14,040
+ابهيك احنا بنكون خلصنا تفاعلات الalkynes ان شاء
+
+552
+00:48:14,040 --> 00:48:18,020
+الله المحاضرة الجاية بنبدأ بتفاعلات الalkynes
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ.srt
new file mode 100644
index 0000000000000000000000000000000000000000..46a9fecdb1f977d2b95aafe5d0e62a77cb026125
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ.srt
@@ -0,0 +1,1842 @@
+1
+00:00:08,680 --> 00:00:13,980
+بسم الله الرحمن الرحيم اليوم بنكمل إن شاء الله في
+
+2
+00:00:13,980 --> 00:00:17,700
+موضوع مشتقات الأحماض المرة الماضية أخذنا فكرة عن
+
+3
+00:00:17,700 --> 00:00:23,100
+الأحماض ويمكن فكرة عامة عن المشتقات بشكل عام 
+
+4
+00:00:23,100 --> 00:00:28,730
+تحضيرها اليوم بنتوسع أكثر في هذا الموضوع، المشتقة
+
+5
+00:00:28,730 --> 00:00:35,290
+الأولى للأحماض اللي هي الإسترز، واضح لما نتطلع 
+
+6
+00:00:35,290 --> 00:00:39,230
+على شكل أي إستر، لما نتطلع على شكل أي إستر 
+
+7
+00:00:39,230 --> 00:00:46,230
+بنلاحظ أنه الإستر بتكون من شقين، بتكون من شق من 
+
+8
+00:00:46,230 --> 00:00:50,550
+الحامض و شق من الكحول، وهو عادة بتحضر بتفاعل
+
+9
+00:00:50,550 --> 00:00:54,550
+الحامض والكحول، فمثلا لو بدي أطلع على الإستر 
+
+10
+00:00:54,550 --> 00:00:58,510
+اللي موجود عندي، بلاحظ أنه عندي الشق اللي فيه C 
+
+11
+00:00:58,510 --> 00:00:59,630
+double bond O
+
+12
+00:01:09,010 --> 00:01:14,010
+الشق الثاني اللي مكون من ثلاث كربونات كانوا متصلين
+
+13
+00:01:14,010 --> 00:01:20,020
+بأكسجين، هو الكحول، البروبانول، الآن لما هدول بدوا
+
+14
+00:01:20,020 --> 00:01:26,260
+يعملوا إستر، الإستر اسمه بده يبين فيه الشقين،
+
+15
+00:01:26,260 --> 00:01:31,660
+شق الكحول و شق الحامض، عادة بتتم التسمية بهذا
+
+16
+00:01:31,660 --> 00:01:37,500
+الشكل، بنشوف ايش اسم المجموعة تبعت الكحول، لما يكون
+
+17
+00:01:37,500 --> 00:01:42,300
+عندي ثلاث ذرات كربون، المجموعة اسمها بروبيل، بروبيل 
+
+18
+00:01:42,300 --> 00:01:48,220
+والحامض بيوتانويك أسيد، بنستبدل كلمة بيوتانويك
+
+19
+00:01:48,220 --> 00:01:53,340
+أسيد ببيوتانويت، فبيصير كل هذا اسمه بروبيل
+
+20
+00:01:53,340 --> 00:02:00,620
+بيوتانويت، بروبيل اللي هو شقّ الكحول، وبيوتانويت
+
+21
+00:02:00,620 --> 00:02:05,860
+اللي هو شقّ الإستر، طبعًا هنا بيكون شبيه بتسمية
+
+22
+00:02:05,860 --> 00:02:10,310
+الأيونات السالبة، لأن الأيونات السالبة احنا اتفقنا 
+
+23
+00:02:10,310 --> 00:02:19,150
+إننا بنسميها بالنهاية  "ate" ، الآن لو بدنا نطلع على بعض 
+
+24
+00:02:19,150 --> 00:02:25,520
+الأمثلة حتى نأكد طريقة التسمية، أهم شيء .. أهم شيء
+
+25
+00:02:25,520 --> 00:02:32,420
+كنت أحدد جزء الكحول وجزء الكحول هو الجزء المتصل
+
+26
+00:02:32,420 --> 00:02:36,340
+بالـ O، هذه الميثيل، ده بدون الـ سيطة من bond O يعني
+
+27
+00:02:36,340 --> 00:02:39,280
+لو في كل هدول قبل ما أشتغل بتقول ايش هو جزء
+
+28
+00:02:39,280 --> 00:02:44,560
+الكحول؟ هنا الميثيل، هذه جاية من الميثانول، هنا 
+
+29
+00:02:44,560 --> 00:02:46,960
+الإيثيل 
+
+30
+00:02:48,900 --> 00:02:52,780
+مرة ثانية مثل الجزء الثاني اللي فيه صيغة و point O
+
+31
+00:02:52,780 --> 00:02:59,040
+هو جزء الحامض، هنا الفينيل 
+
+32
+00:02:59,040 --> 00:03:09,060
+هنا مثل الآن، هذا شقّ الكحول، عادة احنا بنكتب اسم
+
+33
+00:03:09,060 --> 00:03:12,860
+المجموعة تبعته وبنسيب فراغ بعدها فبهذه الحالة
+
+34
+00:03:12,860 --> 00:03:19,640
+بنقول مثل الآن الحامض اللي من carbon 10، أسيتيك أسيد
+
+35
+00:03:19,640 --> 00:03:26,100
+فبيصير المركب مثل أسيتات، لو كنت بدي بالأيوباك المطلق
+
+36
+00:03:26,100 --> 00:03:32,420
+إيثانوك أسيد، بدي يصير مثل إيثانويت، واضح نفس الفكرة
+
+37
+00:03:32,420 --> 00:03:40,500
+هنا إيثيل وكربونتين، إذا أسيتيك أسيد إيثيل أسيتات، لو كنت
+
+38
+00:03:40,500 --> 00:03:44,820
+بتطلع المركب اللي بعده مثل كربونتين، تلاتة أربعة
+
+39
+00:03:44,820 --> 00:03:52,740
+هيصير مثل بيوتانويت، مثل بيوتانويت، لما بدي أجي أطلع
+
+40
+00:03:52,740 --> 00:03:57,300
+هنا، هذه المجموعة البنزين لما تكون جاية كمجموعة 
+
+41
+00:03:57,300 --> 00:04:04,200
+اسمها فينيل، فينيل، وهذا كربونتين من الأسيتيك أسيد حيصير 
+
+42
+00:04:04,200 --> 00:04:11,380
+فينيل أسيتات، فينيل أسيتات، واضح؟ لو بدي أطلع هنا هذه 
+
+43
+00:04:11,380 --> 00:04:18,100
+مثل والبنزين مع مجموعة الحامض اسمه بنزويك أسيد
+
+44
+00:04:18,100 --> 00:04:23,540
+فبتصير كلها مثل بنزويت، واضح؟ لاحظوا مثل هدول
+
+45
+00:04:23,540 --> 00:04:28,840
+المركبين، ربما تلاحظوا نوعًا ما شبه بينهم وأحيانًا
+
+46
+00:04:28,840 --> 00:04:33,540
+كتيرة لما بنسأل سؤال الطلاب بيخربوا التنين في بعض
+
+47
+00:04:33,540 --> 00:04:37,680
+يعني ممكن يسموا هذا مثلاً فينيل أسيتين أو يسموا هذا
+
+48
+00:04:37,680 --> 00:04:43,040
+مثل بنزويت، فبيلزم الانتباه أن الجزء اللي بيذكر في
+
+49
+00:04:43,040 --> 00:04:49,000
+الأول هو جزء الكحول، الجزء المتصل بالأكسجين من 
+
+50
+00:04:49,000 --> 00:04:54,720
+خلال single bond، والجزء الثاني هو جزء ال acid، فهنا
+
+51
+00:04:54,720 --> 00:05:00,420
+هذه فينيل وال acid هو ايش؟ أسيتيك أسيد، يعني حتى
+
+52
+00:05:00,420 --> 00:05:04,220
+لو قلنا لكم كيف بدنا نحضر هذا المركب على سبيل
+
+53
+00:05:04,220 --> 00:05:08,060
+المثال بتكون ال acid اللي تحضروا منه يكون ال
+
+54
+00:05:08,060 --> 00:05:13,630
+أسيتيك أسيد، والكحول يكون الفينول، بينما لو بنقول
+
+55
+00:05:13,630 --> 00:05:18,010
+هذا كيف بدنا نحضر المركب؟ بدنا بنزويك أسيد وهذا
+
+56
+00:05:18,010 --> 00:05:24,770
+بيكون الميثانول، واضح؟ هذا الكلام بحاجة إلى انتباه
+
+57
+00:05:24,770 --> 00:05:30,850
+واعتقد بهذا الشكل تسمية تسمية الإسترز تسمية
+
+58
+00:05:30,850 --> 00:05:36,270
+سهلة، طبعًا ربما بتلاحظوا هنا أنه احنا أخذنا تسمية
+
+59
+00:05:36,270 --> 00:05:40,390
+الإسترز بدون Substituents
+
+60
+00:06:12,740 --> 00:06:18,960
+إيثان، واضح؟ الآن لاحظوا هنا الحقيقة في عندي 
+
+61
+00:06:18,960 --> 00:06:26,160
+إستر سيطة بال bond O OR، وفي عندي كيتون سيطة بال 
+
+62
+00:06:26,160 --> 00:06:32,480
+bond O، الأولوية لمين؟ بتكون للإستر، علشان هيك هذا
+
+63
+00:06:32,480 --> 00:06:38,720
+كاسم هيكون فيه إيثان في البداية دائمًا اللي هو جزء
+
+64
+00:06:38,720 --> 00:06:42,640
+ال alcohol، واللي بدي يكون في البداية بعدين بعد
+
+65
+00:06:42,640 --> 00:06:48,100
+الحامض ابتداء من سيطة الـ point O، واحد اثنين 
+
+66
+00:06:48,100 --> 00:06:57,320
+ثلاثة أربعة، واضح؟ الآن هذا الحامض عبارة عن ايش؟
+
+67
+00:06:57,320 --> 00:07:03,400
+بيوتانويك أسيد، لما بدي يصير إستر بيوتانويت، هذا ال
+
+68
+00:07:03,400 --> 00:07:10,540
+بيوتانويت شو بيحمل مجموعات؟ كلورين وأكسجين، إذا
+
+69
+00:07:10,540 --> 00:07:16,300
+لما أنا بدي اسميه هقول إيثيل، نسيب فراغ، Two 
+
+70
+00:07:16,300 --> 00:07:29,800
+Chlorine، Three Oxygen، بيوتانويت، يعني
+
+71
+00:07:29,800 --> 00:07:34,380
+كأنه الإستر إيثيل بيوتانويت، وهدول ال
+
+72
+00:07:34,380 --> 00:07:39,980
+substituents ذكرناهم، واضح، الإستر مثل بيوتانويت
+
+73
+00:07:39,980 --> 00:07:46,980
+وبنذكر ال substituents، الآن بدنا واحدة بشكل كامل 
+
+74
+00:07:46,980 --> 00:07:54,540
+تسمينا المركب اللي بعده، ولو
+
+75
+00:07:54,540 --> 00:07:59,000
+يبدو كبير بس مافيش شيء صعب، Systematic بشكل متدرج
+
+76
+00:07:59,000 --> 00:08:05,630
+تفضلي شكلك حابة تسميه جارتك أشطر منك، تفضلي ايش
+
+77
+00:08:05,630 --> 00:08:12,170
+المجموعة تبع ال alcohol؟ هذه المجموعة ال isopropyl
+
+78
+00:08:12,170 --> 00:08:18,450
+كويس؟ الآن باجي على جزء الحامض بشوف كم كربونة قبل
+
+79
+00:08:18,450 --> 00:08:23,720
+انتبهوا معايا دائمًا وأبدًا .. دائمًا وأبدًا لا تبدأ
+
+80
+00:08:23,720 --> 00:08:27,620
+بـ 2-hydroxy، أنا لم أضع أرقام ولا حددت الحامض ..
+
+81
+00:08:27,620 --> 00:08:30,960
+ماذا يعرفني أنها 2-hydroxy أو 3-hydroxy؟ التسمية 
+
+82
+00:08:30,960 --> 00:08:35,340
+دائمًا وأبدًا تبدأ من الخلف للأمام .. لكي تحددوا 
+
+83
+00:08:35,340 --> 00:08:39,420
+الـhydroxy هذه وين .. ماذا يلزمك في الأول؟ تريد أن 
+
+84
+00:08:39,420 --> 00:08:43,660
+تعرف كم كربونة عندك؟ اتحددني هنا .. ماهو الحامض 
+
+85
+00:08:43,660 --> 00:08:44,620
+أساسًا .. 1
+
+86
+00:08:47,550 --> 00:08:55,630
+ثلاثة أربعة خمسة ستة، إذا أنا أمام هكسانويك أسيد، في
+
+87
+00:08:55,630 --> 00:09:00,590
+الإستر هيصير هكسانويل، شو اللي متفرع من هذا
+
+88
+00:09:00,590 --> 00:09:07,570
+الهكسانويك أسيد مثل
+
+89
+00:09:07,570 --> 00:09:16,480
+ومثل وهيدروكسي، واضح؟ إذا كأنه لو أنا بدي أسمي هذا 
+
+90
+00:09:16,480 --> 00:09:25,200
+كـ إستر بدون المجموعات بدي أقول isopropyl وفي
+
+91
+00:09:25,200 --> 00:09:28,900
+الآخر هيكون عنده hexanoate
+
+92
+00:09:30,740 --> 00:09:33,340
+أيزو بروبيل هكسانويت، يعني لو شيلت كل هدول
+
+93
+00:09:33,340 --> 00:09:37,220
+المجموعات أيزو بروبيل هكسانويت، من الأخطاء الدارجة
+
+94
+00:09:37,220 --> 00:09:40,760
+للأسف الشديد أنه كتير بعد ما يسموا بيروحوا بيسموا
+
+95
+00:09:40,760 --> 00:09:46,060
+هذه أوكزو، هذه جزء من الإستر، الـ C double bond O
+
+96
+00:09:46,060 --> 00:09:52,040
+O، بلاقيهم كاتبين لكلمة أوكزو هي جزء من الإستر، ما
+
+97
+00:09:52,040 --> 00:09:56,080
+بتاخدش شيء لحالها، بينما لو كانت واحدة ثانية بعيد
+
+98
+00:09:56,080 --> 00:09:59,200
+عنها هنا السيدة من البندقية هذه جزء من الإستر 
+
+99
+00:09:59,200 --> 00:10:03,500
+هذه زيادة سميناها أوكزو، بس هنا ما بنيجي نقول one 
+
+100
+00:10:03,500 --> 00:10:07,860
+أوكزو، كتير بنلاحظ أنه كاتبين هذه one أوكزو هذه جزء
+
+101
+00:10:07,860 --> 00:10:15,220
+من الإستر، ايش اللي موجود عندك؟ تفضلي من اللي
+
+102
+00:10:15,220 --> 00:10:23,910
+بتكملي؟ سامعيني طيب؟ اه، الـ 3,5-Dimethyl-4
+
+103
+00:10:23,910 --> 00:10:27,990
+-hydroxy، لاحظوا الإستر ايه له أولوية على ايش؟
+
+104
+00:10:27,990 --> 00:10:35,090
+على الكحول، إذا أنا عندي 3,5-dimethyl 
+
+105
+00:10:35,090 --> 00:10:43,050
+4-hydroxyhexanoate
+
+106
+00:10:43,050 --> 00:10:47,750
+كلمة واحدة، لاحظوا الفراغ الوحيد اللي موجود بين كلمة
+
+107
+00:10:47,750 --> 00:10:51,470
+isopropyl وهذه المجموعة، بيقول isopropyl فراغ
+
+108
+00:10:51,470 --> 00:10:54,410
+هدول كلهم كلمة واحدة، يعني لو على الكمبيوتر 
+
+109
+00:10:54,410 --> 00:10:58,890
+بتكتبوا المفروض ولا فراغ، تسيبوا كلهم متصل ببعض و
+
+110
+00:10:58,890 --> 00:11:08,690
+بدون ولا فراغ 3,5-dimethyl-4-hydroxyhexanoate، ماشي؟
+
+111
+00:11:08,690 --> 00:11:11,830
+طيب
+
+112
+00:11:11,830 --> 00:11:19,870
+وأنا اسميه يلا، إذا 
+
+113
+00:11:19,870 --> 00:11:28,490
+هذا مثل ايش؟ الحامض أربع
+
+114
+00:11:28,490 --> 00:11:32,730
+ذرات كربون، بيوتان
+
+115
+00:11:32,730 --> 00:11:40,770
+و "ويت" ايه جاله double bond، ايش حيصير؟ بيوتين "ويت"
+
+116
+00:11:40,770 --> 00:11:43,610
+الـ double bond بحاجة إلى ايش؟
+
+117
+00:11:49,710 --> 00:11:55,170
+لو اتشت هنا أو هنا، إذا بتاخد مواقع الـ double 
+
+118
+00:11:55,170 --> 00:12:00,910
+bond، لازم أحدد نقطة البداية تبعتها، أعطينا عدّي
+
+119
+00:12:00,910 --> 00:12:05,070
+الاسم كامل، مثل
+
+120
+00:12:05,070 --> 00:12:08,330
+Two
+
+121
+00:12:08,330 --> 00:12:11,730
+بيوتين 
+
+122
+00:12:11,730 --> 00:12:20,050
+"ويت"، لاحظوا الـ two هذه عشان تحدد لي وين موقع تلقين
+
+123
+00:12:20,050 --> 00:12:28,150
+مثل Two بيوتين "ويت" حددت لي وين موقع الـ double
+
+124
+00:12:28,150 --> 00:12:35,510
+bond، حددت لي وين موقع الـ double bond، ماشي؟ اه، الآن
+
+125
+00:12:35,510 --> 00:12:40,090
+بدك تسميه، تفضلي، شو اسمك أنت؟ مروة 
+
+126
+00:12:41,060 --> 00:12:46,320
+ماروة أبو دالو، تفضلي، ماروة أبو دالو، تفضلي، هنا ايش
+
+127
+00:12:46,320 --> 00:12:51,980
+المجموعات اللي عندك؟ اللي تحت؟ ماشي، ابن عم اللي
+
+128
+00:12:51,980 --> 00:13:02,580
+فوق ايش اللي عندك؟ تفضلي، الإيثيل هو جزء الكحول خمسة
+
+129
+00:13:02,580 --> 00:13:07,140
+تفضلي
+
+130
+00:13:07,140 --> 00:13:15,680
+ايش هنسميه؟ إيثيل؟ أيوة، إيثيل 
+
+131
+00:13:15,680 --> 00:13:23,980
+Two بنتين، حطينا البنتين هدي عشان تقوليله triple
+
+132
+00:13:23,980 --> 00:13:35,260
+point، "ويت" مش "ات"، إيثيل Two بنتين "ويت"، إيثيل Two
+
+133
+00:13:35,260 --> 00:13:44,760
+بنتين "ويت"، واضح؟ ممتاز، يلا يا شايماء، 
+
+134
+00:13:44,760 --> 00:13:49,120
+ايش المجموعتين الوظيفيتين اللي هنا، حتى يترسخ مبدأ
+
+135
+00:13:49,120 --> 00:13:53,640
+التفاضل؟ 
+
+136
+00:13:53,640 --> 00:13:58,680
+هذا إستر، إستر و Aldehyde، الأولوية لمين؟ 
+
+137
+00:13:58,680 --> 00:14:01,240
+للإستر، والجزء اللي للكل؟
+
+138
+00:14:09,080 --> 00:14:19,760
+فينيل ثري أوكزو بيوتانويت، واضح
+
+139
+00:14:19,760 --> 00:14:26,120
+فينيل ثري أوكزو بيوتانويت، زي ما بتلاحظوا طبعًا أنه
+
+140
+00:14:26,120 --> 00:14:32,030
+لما بنحلل تسمية المركبات العضوية ليست صعبة، ليش؟
+
+141
+00:14:32,030 --> 00:14:38,030
+لأن هذه IUPAC، ايش معنى IUPAC؟ إنه بتمشي على قواعد 
+
+142
+00:14:38,030 --> 00:14:42,530
+مُضطردة، المشكلة أحيانًا اللي بتواجه الناس في الـ
+
+143
+00:14:42,530 --> 00:14:47,360
+common names، الـ Common Names هي اللي ممكن تواجه 
+
+144
+00:14:47,360 --> 00:14:51,820
+الناس إنهم مش عارفين والله هذا الـ common name شو
+
+145
+00:14:51,820 --> 00:14:56,240
+هو، لما نقول glutaric acid فاتشة في المخ شولك ..
+
+146
+00:14:56,240 --> 00:15:00,640
+واضح؟ لكن التسمية اللي بتمشي على قواعد مُضطردة ليست
+
+147
+00:15:00,640 --> 00:15:01,800
+صعبة
+
+148
+00:15:22,990 --> 00:15:27,670
+طبعًا أكدنا وبنود نذكر أن من الإسترز كيف
+
+149
+00:15:27,670 --> 00:15:32,410
+بتحضروا من تفاعل الـ substitution للأحماض
+
+150
+00:15:32,410 --> 00:15:37,870
+الكربوكسيلية، الـ alcohol بيهاجم على الحامض وبيطرد 
+
+151
+00:15:39,110 --> 00:15:43,410
+الـ OH وبيصير عندي إستر، نفس الشيء هنا alcohol
+
+152
+00:15:43,410 --> 00:15:48,390
+بيهاجم على الحامض وبيطرد الـ OH، هذا تأكيد بس أن الـ
+
+153
+00:15:48,390 --> 00:15:53,410
+إستر من alcohol ومن حامض، وأن التفاعل هذا هجوم
+
+154
+00:15:53,410 --> 00:15:58,110
+وخروج، هو تفاعل substitution، لما نيجي نقول لكم أن
+
+155
+00:15:58,110 --> 00:16:03,870
+الـ main reaction of esters is substitution أو الـ
+
+156
+00:16:03,870 --> 00:16:09,070
+acids أو كل المشتقات هذه substitution، تستخدم يكل 
+
+157
+00:16:09,070 --> 00:16:15,010
+البلاد؟ أكيد، أكيد، أكيد، مش minus بس عليها زوج
+
+158
+00:16:15,010 --> 00:16:18,330
+electronic، الـ neutral الـ neutral
+
+159
+00:16:22,140 --> 00:16:27,100
+يعني اللي بدها إستر ايش بدها تعمل؟ كحول وحامض بس
+
+160
+00:16:27,100 --> 00:16:30,440
+طبعًا لاحظوا هنا في لقطة دائمًا بتجينا في الموضوع
+
+161
+00:16:30,440 --> 00:16:36,060
+أنه حقيقة هذا تفاعل الإستر هو تفاعل اتزان يعني
+
+162
+00:16:36,060 --> 00:16:41,200
+بيضال عند الحامض مع الكحول مع الإستر مع المية
+
+163
+00:16:41,200 --> 00:16:45,700
+الآن لما بدنا يمشي أكثر باتجاه تكوين الإستر
+
+164
+00:16:45,700 --> 00:16:52,170
+بنستعمل أي مبدأ في الكيمياء؟ بنستعمل مبدأ لوشاتلييه 
+
+165
+00:16:52,170 --> 00:16:56,170
+لحرف الاتزان، طب كيف بتدخل الإستر يطلع بشكل
+
+166
+00:16:56,170 --> 00:17:05,990
+كبير؟ بنزيد تركيز متفاعل هنا أو بشيل
+
+167
+00:17:05,990 --> 00:17:11,120
+واحد من هناك، شو اللي بدنا نشيله عادة؟ المية يعني
+
+168
+00:17:11,120 --> 00:17:15,840
+بيكونوا عاملين التفاعل بطريقة يسحبوا المية، فكل ما 
+
+169
+00:17:15,840 --> 00:17:19,860
+بيسحبوا المية التفاعل بيظل يمشي بهذا الاتجاه، فممكن
+
+170
+00:17:19,860 --> 00:17:23,400
+نمشي حتى النهاية حسب قاعدة Le Chatelet، أنه أنا لما
+
+171
+00:17:23,400 --> 00:17:29,160
+بشيل متفاعل من هنا بوجه الاتزان لتعديل التفاعل مرة
+
+172
+00:17:29,160 --> 00:
+
+201
+00:20:17,070 --> 00:20:20,210
+من هنا و Acid من هنا و يتفاعلوا و يعملوا ال Ester
+
+202
+00:20:20,210 --> 00:20:24,790
+هذا التفاعل بنقول عنه Intermolecular reaction هو
+
+203
+00:20:24,790 --> 00:20:29,850
+تفاعل بين جزء من هنا و جزء ثاني من هنا ممكن في
+
+204
+00:20:29,850 --> 00:20:37,590
+جزيئات معينة أكون ال alcohol و الحامض بنفس الجزيئة
+
+205
+00:20:38,830 --> 00:20:42,770
+وبالتالي التفاعل يتم في داخل الجزء اللي بنسميه
+
+206
+00:20:42,770 --> 00:20:47,350
+Intramolecular reaction مثلا لو اتطلعنا على هذا
+
+207
+00:20:47,350 --> 00:20:55,340
+المركب 1,2,3,4 إذا هذا بيوتانويك أسيد هذا
+
+208
+00:20:55,340 --> 00:21:00,120
+البيوتانويك أسيد على موقع أربعة شو موجود عليه
+
+209
+00:21:00,120 --> 00:21:07,440
+هيدروكسي four hydroxy butanoic acid لما أجي أسخنه
+
+210
+00:21:07,440 --> 00:21:13,720
+في وجود حامض بيعطيني cyclic ester لاحظوا هذا ال
+
+211
+00:21:13,720 --> 00:21:17,540
+Easter Cyclic طبعا مرات لما يكون مرسوم بهذا الشكل
+
+212
+00:21:17,540 --> 00:21:23,340
+بيغلبكم لكن ممكن نفس المركب يكون مرسوم و احنا سيئة
+
+213
+00:21:23,340 --> 00:21:31,140
+بال bond O OH هي carbon تنتين تلاتة اربعة واحد
+
+214
+00:21:31,140 --> 00:21:39,860
+اتنين تلاتة اربعة و أنا عندك ال OH هذا نفس المركب 1
+
+215
+00:21:39,860 --> 00:21:44,740
+,2,3,4,4 هيدروكسي بيوتانوك أسيد الآن عندما أسخنه يعمل
+
+216
+00:21:44,740 --> 00:21:53,940
+ال E star الكحول سيهاجم هنا و سيطرد ال O H وبعدها
+
+217
+00:21:53,940 --> 00:21:58,380
+ستفقد ال H لأن ال O H مع ال H من هنا سيصبح ماء إذا
+
+218
+00:21:58,380 --> 00:22:03,550
+أعطاني في هذه الحالة Cyclic E star أعطاني في هذه
+
+219
+00:22:03,550 --> 00:22:07,550
+الحالة Cyclic Easter أكيد ال reaction هو عبارة عن
+
+220
+00:22:07,550 --> 00:22:13,370
+Intramolecular إيش يعني Intramolecular أن الجزئين
+
+221
+00:22:13,370 --> 00:22:16,990
+اللي متفاعلوا موجودين في داخل جزيء واحد يعني ما
+
+222
+00:22:16,990 --> 00:22:22,720
+استعملتش جزيئين واضح؟ ما استعملتش جزيئين مجموعة
+
+223
+00:22:22,720 --> 00:22:27,160
+الكحول ومجموعة الحامض موجودة في جزيء واحد، ما جبتش
+
+224
+00:22:27,160 --> 00:22:32,700
+الكحول من جزيء والحامض من جزيء ثاني فبيعطونا اللي
+
+225
+00:22:32,700 --> 00:22:37,540
+هو ال cyclic esters، C double bond O موجودة جوا
+
+226
+00:22:37,540 --> 00:22:44,040
+cycle أو جوا حلقة هذه ال cyclic esters كعائلة
+
+227
+00:22:44,040 --> 00:22:51,310
+بيسموها lactones واضح؟ الـ Cyclic E Stars كعائلة
+
+228
+00:22:51,310 --> 00:22:55,230
+بيسموها Lactones كيف بعرف إنه هذه عائلة اللاكتون؟
+
+229
+00:22:55,230 --> 00:22:58,650
+كيف بعرف إنه هذه عائلة اللاكتون؟ بدي أشوف C double
+
+230
+00:22:58,650 --> 00:23:03,810
+bond O و جنبها O في داخل حلقة، إذا هذه العائلة
+
+231
+00:23:03,810 --> 00:23:09,670
+كعائلة بيكون اسمها إيش؟ Lactone واضح؟ بيكون اسمها
+
+232
+00:23:09,670 --> 00:23:15,250
+lactone طبعا عشان الأمور اللي ضالها متذكرينها
+
+233
+00:23:15,250 --> 00:23:20,570
+انتوا بالمقارنة الحقيقية ممكن يكون عندي غير ال
+
+234
+00:23:20,570 --> 00:23:24,910
+cyclic ester اللي هي اسم عائلة lactone ممكن يكون
+
+235
+00:23:24,910 --> 00:23:29,150
+عندي cyclic amide إيش ال cyclic amide
+
+236
+00:23:36,810 --> 00:23:40,970
+لأن C double bond O N في مركب مفتوح أميد لما تصير
+
+237
+00:23:40,970 --> 00:23:44,430
+في حلقة طبعا غالبا بتكون N H أو أي شيء يكون
+
+238
+00:23:44,430 --> 00:23:47,990
+بتصير Cyclic Amide إذا أنا في عندي في الدنيا
+
+239
+00:23:47,990 --> 00:23:54,410
+Cyclic E star C double bond O O و Cyclic Amide C
+
+240
+00:23:54,410 --> 00:23:59,930
+double bond O N عائلة ال Cyclic E stars إيش اسمها
+
+241
+00:23:59,930 --> 00:24:06,090
+Lactones طب عائلة ال Cyclic Amides شو اسمها
+
+242
+00:24:08,600 --> 00:24:14,000
+Lactam عشان الإسمين زي بعض ما تخربوش بينهم مرات
+
+243
+00:24:14,000 --> 00:24:18,880
+بتجروا lactone و مرات بتجروا lactam فلو إجينا بدنا
+
+244
+00:24:18,880 --> 00:24:23,580
+نسألكم سؤال صح و غلط نقولكم lactams are cyclic
+
+245
+00:24:23,580 --> 00:24:30,640
+esters lactams are cyclic amides lactons are
+
+246
+00:24:30,640 --> 00:24:38,860
+cyclic esters ال lactons هم اللي عبارة عن Esters
+
+247
+00:24:38,860 --> 00:24:45,800
+طبعا ال lactams هذه الحقيقة مهمة كثير ال lactams
+
+248
+00:24:45,800 --> 00:24:53,220
+مهمة كثير ليش؟ لأنه من أهم عائلات الأدوية بالذات
+
+249
+00:24:53,220 --> 00:24:58,220
+للي بيدرسوا تحاليل طبية زي جزء كبير منكم عائلة
+
+250
+00:24:58,220 --> 00:25:04,680
+بيقولولها ال beta lactams إذا عمركم سمعتوا beta
+
+251
+00:25:04,680 --> 00:25:11,070
+lactams هذه ال beta lactams مهمة جدا جدا جدا
+
+252
+00:25:11,070 --> 00:25:16,130
+فبتلاقوا مكتوب عنوان كامل وكتب كاملة وأبحاث
+
+253
+00:25:16,130 --> 00:25:20,330
+كاملة شيء اسمه beta lactam antibiotics
+
+254
+00:25:23,580 --> 00:25:29,040
+Antibiotics هي عائلة مضادات حيوية وهي تحديدا عائلة
+
+255
+00:25:29,040 --> 00:25:34,280
+البنسالين ومشتقاته البنسالين والسيفالوسبورين وكل هذه
+
+256
+00:25:34,280 --> 00:25:40,400
+العائلة بيكون فيها مع c double bond o في حلقة
+
+257
+00:25:40,400 --> 00:25:44,940
+رباعية طبعا ليش بيقولوا beta إذا أنا قلت هاي
+
+258
+00:25:44,940 --> 00:25:48,280
+الموضوع alpha بعد c double bond o هاي الموضوع beta
+
+259
+00:25:48,280 --> 00:25:52,520
+هاي alpha هاي beta فال nitrogen اللي هنا متصل في
+
+260
+00:25:52,520 --> 00:25:57,960
+أي موقع في beta بالنسبة للحمض الأصلي طبعا هنا في
+
+261
+00:25:57,960 --> 00:26:03,480
+عائلة البنسالين في عائلة البنسالين بيكون مع الحلقة
+
+262
+00:26:03,480 --> 00:26:09,400
+الرباعية هذه حلقة خماسية يعني هذا الإطار العام لشكل
+
+263
+00:26:09,400 --> 00:26:14,580
+أدوية البنسالين واضح؟ الآن طوروا البنسالين ..
+
+264
+00:26:14,580 --> 00:26:18,980
+طوروا البنسالين للعائلات الثانية الـ cephalosporin
+
+265
+00:26:18,980 --> 00:26:24,420
+والمضادات الحيوية الجديدة مع الحلقة الرباعية صار
+
+266
+00:26:24,420 --> 00:26:30,120
+يحطوا حلقة إيش؟ سداسية الأصل البنسلي الحلقة
+
+267
+00:26:30,120 --> 00:26:36,520
+الرباعية وخماسية طوروا ضالت هذه رباعية وهذه سداسية
+
+268
+00:26:36,520 --> 00:26:41,760
+ودائما عندهم قناعة أن الحلقة الرباعية لا مفر من
+
+269
+00:26:41,760 --> 00:26:45,840
+وجودها عشان هذه المضادات الحيوية تكون بتشتغل
+
+270
+00:26:45,840 --> 00:26:49,820
+الحلقة الخماسية مش مشكلة ممكن تصير سداسية وممكن
+
+271
+00:26:49,820 --> 00:26:54,260
+تكون مش حلقة بس الأساس في هذول المضادات الحيوية
+
+272
+00:26:54,260 --> 00:26:58,860
+كلهم إيش؟ الحلقة الرباعية وعشان هيك بنقول إنه عندنا
+
+273
+00:26:58,860 --> 00:27:03,440
+عائلة كاملة من المضادات الحيوية اللي هي بيسموها ال
+
+274
+00:27:03,440 --> 00:27:09,240
+beta-lactam antibiotics اللي هي عائلة البنسالين
+
+275
+00:27:09,240 --> 00:27:13,960
+وأجياله ومشتقاته طبعا هنا انتبهوا لو كنتوا بتكون
+
+276
+00:27:13,960 --> 00:27:20,060
+تتطلعوا على اللاكتون هنا مثلا Alpha Beta Delta
+
+277
+00:27:20,060 --> 00:27:27,960
+Gamma نسميه Gamma Lactone ألفا بيتا جاما هاي
+
+278
+00:27:27,960 --> 00:27:34,200
+الألفا هاي البيتا هاي الجامعة ال O جاية وين؟ جاما
+
+279
+00:27:34,200 --> 00:27:42,460
+واضح؟ هيك احنا بنعد من ال C ضب ال point O تبعت
+
+280
+00:27:42,460 --> 00:27:46,640
+الحامض من بعدها لو كنا بنرقم في الأحماض من وين
+
+281
+00:27:46,640 --> 00:27:53,330
+بنرقم؟ بنرقم من عند الـ C double bond O لكن لما
+
+282
+00:27:53,330 --> 00:28:00,130
+بنستعمل نظام Alpha و Beta من وين بنستعملها؟ من بعد
+
+283
+00:28:00,130 --> 00:28:01,870
+الـ C double bond O
+
+284
+00:28:05,460 --> 00:28:10,280
+على سبيل المثال ال amino acids الأحماض الأمينية ال
+
+285
+00:28:10,280 --> 00:28:14,480
+amino acids لما تاخدوا حامض زي هيك C double bond O
+
+286
+00:28:14,480 --> 00:28:19,440
+أو H وهنا تحطوا C بغض النظر إيش حاملة نفترض H و
+
+287
+00:28:19,440 --> 00:28:27,680
+حاملة R وهنا NH2 هذه العائلة شو بيسموها amino O
+
+288
+00:28:27,680 --> 00:28:35,210
+acid الآن هي ال alpha عشان هيك هذه بيسموها الألفا
+
+289
+00:28:35,210 --> 00:28:40,330
+أمينو أسيد اللي هي الألفا أمينو أسيد اللي بتكون
+
+290
+00:28:40,330 --> 00:28:45,410
+لبروتينات الآن وقت إيش بتكون بيتا لو حطيت كمان
+
+291
+00:28:45,410 --> 00:28:50,310
+كربونا بعد الألفا والأمينو إجت عليها بيصير بيتا
+
+292
+00:28:50,310 --> 00:28:54,950
+أمينو أسيد طبعا الأحماض الأمينية المكونة لبروتينات
+
+293
+00:28:54,950 --> 00:28:58,750
+في جسم الإنسان المشهورة
+
+294
+00:28:59,300 --> 00:29:02,240
+كلها عبارة عن أي نوع من الـ Amino Acids Alpha
+
+295
+00:29:02,240 --> 00:29:07,220
+بمعنى أن الـ Amino على أول كربونا بعد الكربونيل
+
+296
+00:29:07,220 --> 00:29:15,580
+group لكن لو كنت برقم وين واحد؟ اتنين هنا واضح؟ و
+
+297
+00:29:15,580 --> 00:29:20,600
+هذا الكلام السابق إن حكينا فيه فما في داعي نرد إن
+
+298
+00:29:20,600 --> 00:29:27,790
+هي الآن هي أنا أمثلة ومكتوب اسمها بيهمنيش تحفظوا
+
+299
+00:29:27,790 --> 00:29:30,810
+اسمها بس حتى تكونوا بالصورة في مركبات ذات
+
+300
+00:29:30,810 --> 00:29:37,290
+استعمالات وكلها عبارة عن إيش؟ كلها عبارة عن
+
+301
+00:29:37,290 --> 00:29:42,030
+lactones كل هذه المركبات عبارة عن lactones و لها
+
+302
+00:29:42,030 --> 00:29:48,530
+تطبيقات في الحياة بنجي
+
+303
+00:29:48,530 --> 00:29:59,610
+لموضوع الحقيقة مهم كثير موضوع مهم كثير أن الزيوت
+
+304
+00:29:59,610 --> 00:30:05,670
+اللي هو الزيت وكمان بيجي زيه السمنة والفات وال
+
+305
+00:30:05,670 --> 00:30:11,930
+lipids وما إلى ذلك هم عبارة عن .. بنسميهم ال tri
+
+306
+00:30:11,930 --> 00:30:17,370
+-glycerides Esters of جلسرين
+
+307
+00:30:18,400 --> 00:30:23,800
+يعني ال glycerin اللي بتعرفوه ال glycerin اللي
+
+308
+00:30:23,800 --> 00:30:27,400
+بيحطوه بيرطب الأيدين وما إلى ذلك هو المركب ده
+
+309
+00:30:27,400 --> 00:30:35,560
+اللي في تلت مجموعات OHs CH2OH CHOH CH2OH هذا عبارة
+
+310
+00:30:35,560 --> 00:30:43,000
+عن إيش؟ ال glycerin أو ال glycerol الآن هذا ال
+
+311
+00:30:43,000 --> 00:30:46,560
+glycerin لو تخيلته إنه بدنا نفعله مع حامض، لو
+
+312
+00:30:46,560 --> 00:30:50,720
+تخيلته إنه بدنا نفعله مع حامض، بنحضر ال Ester بس
+
+313
+00:30:50,720 --> 00:30:54,940
+بيكون عندي كم Ester؟ التلاتة يعني هي أنا حامض
+
+314
+00:30:54,940 --> 00:30:59,900
+متصل ب OH تاعة alcohol وأنا حامض متصل ب OH تاعة
+
+315
+00:30:59,900 --> 00:31:04,340
+alcohol وأنا حامض متصل ب OH تاعة alcohol التلاتة
+
+316
+00:31:04,340 --> 00:31:07,840
+موجودين في جزء واحد ال OHS اللي هو جزء ال glycerin
+
+317
+00:31:07,840 --> 00:31:12,720
+عشانك هذه المركبات احنا بنسميها ال tri glycerides
+
+318
+00:31:12,720 --> 00:31:18,180
+هذا هو الزيت أو السيرج أو زيت الزيتون طب إيش بيفرق
+
+319
+00:31:18,180 --> 00:31:24,570
+زيت عن زيت؟ يعني لما نقول سيرج، عباد الشمس، عن زيت
+
+320
+00:31:24,570 --> 00:31:29,270
+الصويا، عن زيت الزيتون، إيش بيفرقوا عن بعض؟ عن زيت
+
+321
+00:31:29,270 --> 00:31:37,450
+النخيل؟ بيفرقوا في الـR group اللي هنا هذه الـR
+
+322
+00:31:37,450 --> 00:31:42,290
+ممكن تكون في التلاتة نفس الأشياء وممكن تكون مختلفة
+
+323
+00:31:42,290 --> 00:31:47,030
+وغالبا هي سلسلة طويلة
+
+324
+00:31:48,700 --> 00:31:54,060
+ممكن تكون مشبعة ما فيش فيها double bonds وممكن
+
+325
+00:31:54,060 --> 00:32:00,680
+تكون فيها double bonds واضح؟ طبعا الزيوت اللي عادة
+
+326
+00:32:00,680 --> 00:32:07,050
+فيها double bonds بتكون سائلة ولا صلبة؟ سائلة لما
+
+327
+00:32:07,050 --> 00:32:11,290
+يكون عندي double bonds بتكون الزيوت سائلة بنعمل
+
+328
+00:32:11,290 --> 00:32:15,610
+لها هدرجة سمعتوا عن هدرجة الزيوت؟ يعني بنحطها
+
+329
+00:32:15,610 --> 00:32:19,870
+هيدروجين بنلغي double bonds في هذه الحالة الزيوت
+
+330
+00:32:19,870 --> 00:32:24,190
+بتتحول إلى إيش؟ إلى زيوت صلبة اللي هي السمنة و
+
+331
+00:32:24,190 --> 00:32:29,110
+المارجرين وما إلى ذلك يعني السمنة من وين في الآخر
+
+332
+00:32:29,110 --> 00:32:33,830
+بيجيبوها؟ من الزيوت من السيرج وزيت عباد الشمس
+
+333
+00:32:33,830 --> 00:32:37,790
+وغيره وغيرته بالهدرجة بيكون في عند double bonds
+
+334
+00:32:37,790 --> 00:32:44,150
+بنلغي ال double bonds فبتحول الزيت السائل إلى زيت
+
+335
+00:32:44,150 --> 00:32:50,930
+صلب الآن هذه الزيوت كمان بيحضروا منها شغلة ثانية
+
+336
+00:32:50,930 --> 00:32:57,540
+بيحضروا منها الصابون الصابون بيحضروا من الزيوت
+
+337
+00:32:57,540 --> 00:33:01,620
+الصابون مش دايما بنقول احنا الصابون النابلسي
+
+338
+00:33:01,620 --> 00:33:07,920
+بيحضروا من زيت الزيتون كيف بيحضروا الصابون من
+
+339
+00:33:07,920 --> 00:33:12,120
+الزيوت؟ بيجوا بيفعلوها مع ال sodium hydroxide
+
+340
+00:33:12,120 --> 00:33:16,900
+بشوية تسخين بيعملوا تحلل مائي لهذا الزيت بيكسروا
+
+341
+00:33:16,900 --> 00:33:22,190
+من هنا فبيطلع عندنا ال glycerin ال glycerin مش هو
+
+342
+00:33:22,190 --> 00:33:28,650
+فيت القصيد زائد ملح للأحماض ما بديش أنا أنسى إنه هذه
+
+343
+00:33:28,650 --> 00:33:33,030
+الأحماض أحماض أطوالها كبيرة fatty acids يعني مش
+
+344
+00:33:33,030 --> 00:33:36,970
+كربونتين تلاتة أربع طعش ست عشر تمن طعش فأنتوا
+
+345
+00:33:36,970 --> 00:33:43,050
+تخيلوا هذا الحامض إنه بهذا الشكل ست عشر كربونا مع
+
+346
+00:33:43,050 --> 00:33:48,840
+سيئة بالبندق O O minus الآن هذه هي الصابونة
+
+347
+00:33:48,840 --> 00:33:54,620
+الصابونة زي ما بتلاحظوا مكونة من إيش؟ من شكلتين
+
+348
+00:33:54,620 --> 00:34:00,400
+الجزء اللي فيه ال minus هذا Polar ولا non polar؟
+
+349
+00:34:00,400 --> 00:34:06,240
+polar bar والجزء اللي فيه السلسلة الألفتية
+
+350
+00:34:06,240 --> 00:34:12,860
+الطويلة non polar إذا الصابون مكون من جزءين من
+
+351
+00:34:12,860 --> 00:34:18,380
+polar part و non polar part الفتك تشين طويلة 16
+
+352
+00:34:18,380 --> 00:34:23,360
+كربونا 18 كربونا هذه non polar والطرف أو الرأس
+
+353
+00:34:23,360 --> 00:34:30,360
+تبعه C double bond O O minus هذا الجزء polar الآن
+
+354
+00:34:30,360 --> 00:34:32,320
+كيف بيعمل الصابون
+
+355
+00:34:35,560 --> 00:34:45,320
+بيقوم بعمله في التنظيف الصابون بنظف إيش؟ آه لازم
+
+356
+00:34:45,320 --> 00:34:50,840
+تكونوا عارفين يعني لو حد يجي على إيديه سكر سكر
+
+357
+00:34:50,840 --> 00:34:54,560
+ماء وعليه سكر وماء إلى ذلك ما يلزمه يروح يغسل
+
+358
+00:34:54,560 --> 00:34:59,000
+بالصابون الصابون غالي اليوم الهواي ب 2.5 شكل بكفي
+
+359
+00:34:59,000 --> 00:35:05,480
+ماء الماء بتنظف السكر السكر Polar والماء Polar Polar
+
+360
+00:35:05,480 --> 00:35:08,660
+بيدوب في Polar خلصنا الماء بتنظف السكر ما يلزمه اروح
+
+361
+00:35:08,660 --> 00:35:12,660
+اغسل من السكر يجي على إيديه بالصابون ما فيش لزوم
+
+362
+00:35:12,660 --> 00:35:18,520
+الصابون لتنظيف إيش؟ الدهون كيف بتتم عملية التنظيف
+
+363
+00:35:18,520 --> 00:35:23,920
+هذا الجزء اللي هو ال non-polar والدهون non-polar
+
+364
+00:35:23,920 --> 00:35:29,730
+والقاعدة العامة like dissolve like فالدهون غير
+
+365
+00:35:29,730 --> 00:35:35,210
+القطبية ال non polar بتدوب في هذا الجزء الطويل تبع
+
+366
+00:35:35,210 --> 00:35:40,450
+الزيت بدوبها بيحوط هذا الجزء الطويل اللي هو ال
+
+367
+00:35:40,450 --> 00:35:44,350
+chain أو ال non polar part بيحوط نقطة الدهن أو
+
+368
+00:35:44,350 --> 00:35:49,630
+الزيت وبعدين بتعمل شيء بنسميه كورا mycel وبتنزل
+
+369
+00:35:49,630 --> 00:35:55,620
+مع الماء وهي تحمل في داخلها نقطة إيش؟ الدهون زي ما
+
+370
+00:35:55,620 --> 00:36:01,340
+أنتوا شايفين هنا في هذا المثال كيف بيشتغل الصابون
+
+371
+00:36:01,340 --> 00:36:06,000
+كيف بيشتغل الصابون هاي الجزء ال polar هذا الجزء
+
+372
+00:36:06,000 --> 00:36:11,020
+ال polar كله بيحمل شحن
+
+401
+00:38:48,300 --> 00:38:54,580
+الجزء اللي هو الأليفاتيك بس ما بدناش ننسى هانّا نقطة
+
+402
+00:38:54,580 --> 00:39:01,420
+أنه الزيت مكوّن من جزئين جزء للجليسرين و الجزء
+
+403
+00:39:01,420 --> 00:39:09,120
+الأليفاتيك الآن اللي بيصلح كوقود fuel هو هذا الجزء
+
+404
+00:39:10,110 --> 00:39:16,810
+الأليفاتيك والجليساريل هو المصيبة اللي كانت تطلع
+
+405
+00:39:16,810 --> 00:39:23,010
+الرائحة فالرائحة أصلها من وين؟ من الجليساريل أنه
+
+406
+00:39:23,010 --> 00:39:27,550
+الجليساريل بالحرارة بيفقد جزيئين ماء بيعطينا مركب
+
+407
+00:39:27,550 --> 00:39:33,070
+زي هيك السيطة بالبوند أو اللي هو هذا الألدهيد اللي
+
+408
+00:39:33,070 --> 00:39:41,210
+بنسميه أكريلديهيد هذا بالإنجليزية بيلعب بالتسخين Acryl
+
+409
+00:39:41,210 --> 00:39:49,070
+Aldehyde واضح؟ هذا الجزء من أين جاية الرائحة؟ من
+
+410
+00:39:49,070 --> 00:39:52,810
+الجلسريل الجزء الثاني هو اللي بيولع اللي فيه R
+
+411
+00:39:52,810 --> 00:39:56,550
+كبيرة ما أنتم ما تنسوش برضه أنه البنزين السيارة
+
+412
+00:39:56,550 --> 00:40:02,690
+أساسا هو عبارة عن إيش؟ مش والكيّل؟ لأ لأ شوف C6H6
+
+413
+00:40:02,690 --> 00:40:08,640
+الفيول اللي هو الجازولين بنسميه الجازولين تبع
+
+414
+00:40:08,640 --> 00:40:14,840
+السيارة أو البنزين هو عبارة عن إيش؟ مش هو عبارة عن
+
+415
+00:40:14,840 --> 00:40:21,080
+سلسلة ألكين خليط من الهبتين 1، 2، 3،
+
+416
+00:40:21,080 --> 00:40:27,400
+4، 5، 6، 7 هبتين و Iso-Octane، هاي
+
+417
+00:40:27,400 --> 00:40:35,720
+مجموعة الـ I's وهنا، وعدّه 1,2,3,4,5,6,7,8 ايزو
+
+418
+00:40:35,720 --> 00:40:41,880
+أكتين مع هبتين بيعطينا إيش؟ بيعطينا الجازولين أو
+
+419
+00:40:41,880 --> 00:40:45,300
+الوقود اللي احنا بنستعمله بنزين السيارات خليط من
+
+420
+00:40:45,300 --> 00:40:49,440
+الهبتين والايزو أكتين والايزو أكتين بنحط بنسبة
+
+421
+00:40:49,440 --> 00:40:55,150
+معينة وعشان هيك بيصير عندي رقم الاكتين واضح؟ مش فيه
+
+422
+00:40:55,150 --> 00:40:58,970
+عندي بنزين تسعين وبنزين خمسة وتسعين وإذا اختل
+
+423
+00:40:58,970 --> 00:41:02,730
+البنزين بيصير خبط في الموتور وما إلى ذلك الـ
+
+424
+00:41:02,730 --> 00:41:06,430
+knocking فالجازولين هو عبارة عن aliphatic compound
+
+425
+00:41:06,430 --> 00:41:10,890
+الآن هذا الجزء الأليفاتيك اللي بيولع نفسه موجود
+
+426
+00:41:10,890 --> 00:41:17,580
+وين؟ في الـ Ester الأليفاتيك بيولع و الـ Ester
+
+427
+00:41:17,580 --> 00:41:24,500
+بيولع وبيعطي طاقة ولذلك يمكن أن يستعمل الـ Ester
+
+428
+00:41:24,500 --> 00:41:29,280
+كوقود المشكلة وين بتصير؟
+
+429
+00:41:31,640 --> 00:41:36,100
+المشكلة بتصير من الـ acrylaldehyde من الريحة يعني
+
+430
+00:41:36,100 --> 00:41:40,540
+لما استعمل كوقود السيارات كانت تمشي طبيعي بس كانت
+
+431
+00:41:40,540 --> 00:41:45,900
+مشكلة الناس من الروائح اللي بتطلع اللي هي رائحة
+
+432
+00:41:45,900 --> 00:41:50,240
+الـ acrylaldehyde الآن هذه المشكلة ما لهاش حل علمي
+
+433
+00:41:50,240 --> 00:41:57,200
+مش بإمكاني الآن أنا أجيب زيوت وأحولها إلى وقود
+
+434
+00:41:58,590 --> 00:42:03,390
+العالم شغال على هذا الكلام وبيحضروا شيء بيسموه
+
+435
+00:42:03,390 --> 00:42:10,150
+biodiesel الديزل الحيوي هنا في الـ .. في الوقود،
+
+436
+00:42:10,150 --> 00:42:15,510
+بتتميزوا بين شغلتين، بين شيء بنسميه bio fuel
+
+437
+00:42:15,510 --> 00:42:21,570
+الوقود الحيوي وبين biodiesel
+
+438
+00:42:27,240 --> 00:42:31,080
+البيوفيول أول ما بدوا كانوا ياخدوا الإيثانول
+
+439
+00:42:31,080 --> 00:42:36,760
+الإيثانول بيولع ولا لأ؟ اللي هو الـ ethyl-OH من وين
+
+440
+00:42:36,760 --> 00:42:42,330
+بيجيبوه الإيثانول؟ من الدورة وتخمورها وما إلى ذلك
+
+441
+00:42:42,330 --> 00:42:46,450
+صاروا يزرعوا نصف أمريكا وغيرها وغيرّاتها دورة و
+
+442
+00:42:46,450 --> 00:42:49,630
+يحولوه لإيثانول والإيثانول بتمشي عليه السيارات
+
+443
+00:42:49,630 --> 00:42:54,750
+بدون أي مشكلة زمان كان كل بيت صغير عشان يعمل الصبح
+
+444
+00:42:54,750 --> 00:43:02,330
+فنجان قهوة يكون عنده إيش؟ بابور سبيرتو كنا نشتري
+
+445
+00:43:02,330 --> 00:43:05,810
+السبيرتو بجزازة ويكون بابور صغير هالجد إله في
+
+446
+00:43:05,810 --> 00:43:08,410
+طيلة يمكن الآن صار من الذكريات
+
+447
+00:43:10,700 --> 00:43:14,780
+أيوا بابور هيك صغير وهنا إله فتيلة، هذا كان يتعبى
+
+448
+00:43:14,780 --> 00:43:19,920
+Spirto إيثانول، كل دار كان عنده بابور Spirto،
+
+449
+00:43:19,920 --> 00:43:22,400
+بيعملوا عليه في أنجان القهوة الصبح لأنه بيولع
+
+450
+00:43:22,400 --> 00:43:28,320
+بإيش؟ بسهولة، فالإيثانول وقود، هذا bio fuel، لكن
+
+451
+00:43:28,320 --> 00:43:33,700
+إيش قصة الـ biodiesel؟ إيش قصة الـ Biodiesel اللي
+
+452
+00:43:33,700 --> 00:43:37,220
+اليوم العالم شغالين عليه بشكل كبير؟ ولو
+
+453
+00:43:37,220 --> 00:43:42,640
+معلوماتكم، بالـ2008 وبالـ2009 طيّرت Airbus
+
+454
+00:43:44,990 --> 00:43:49,710
+طائرات على الـ biodiesel مخلوط طبعا بوقود عادي
+
+455
+00:43:49,710 --> 00:43:55,270
+يعني شوفوا كذا رحلة عملوها رحلات تجريبية طيّرت طائرة
+
+456
+00:43:55,270 --> 00:43:59,750
+باستعمال الـ biodiesel طب إيش بيعملوا في الـ
+
+457
+00:43:59,750 --> 00:44:05,010
+biodiesel اللي بيعملوا في الـ biodiesel بييجوا لهذا
+
+458
+00:44:05,010 --> 00:44:10,090
+الزيت طبعا ما بياخدوش زيت يؤكل فيه أشجار معينة زي
+
+459
+00:44:10,090 --> 00:44:15,580
+القطروفة والنخيل زيوت بيسموها non edible يعني زيوت
+
+460
+00:44:15,580 --> 00:44:19,120
+غير مأكولة بدل ما ياخدوا الزيت اللي بتاكل فيه
+
+461
+00:44:19,120 --> 00:44:23,600
+نباتات صحراوية وبتطلع زيت كثير بياخدوا هذا الزيت و
+
+462
+00:44:23,600 --> 00:44:30,100
+بيفعلون افترض مع الإيثانول إيثل أو OH إيش بدّه يعمل
+
+463
+00:44:30,100 --> 00:44:36,380
+الإيثانول هذا Ester بيهاجم هنا وبيطرد هذا الجزء
+
+464
+00:44:36,380 --> 00:44:40,760
+لاحظوا بيبدل Ester بـ Ester وعشان هيك هذه العملية
+
+465
+00:44:40,760 --> 00:44:43,920
+بيسموها الشيء اللي بيبدل .. شو بنقول عنه
+
+466
+00:44:43,920 --> 00:44:50,140
+بالإنكليزي؟ اللي بيبدل الكهرباء Trans .. Trans
+
+467
+00:44:50,140 --> 00:44:55,500
+فالعملية بيسموها Trans Esterification
+
+468
+00:45:07,630 --> 00:45:18,020
+ترانس إستر فICATION ترانس إستر فICATION أو إيثل إيثل
+
+469
+00:45:18,020 --> 00:45:22,500
+إيثل
+
+470
+00:45:22,500 --> 00:45:24,100
+إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل 
+
+471
+00:45:24,100 --> 00:45:24,140
+إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل
+
+472
+00:45:24,140 --> 00:45:24,960
+إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل
+
+473
+00:45:24,960 --> 00:45:25,160
+إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل
+
+474
+00:45:25,160 --> 00:45:33,380
+إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل إيثل
+
+475
+00:45:35,420 --> 00:45:39,620
+لكن ما بياخدش الزيت مباشرة يعني الفرق بين العالم
+
+476
+00:45:39,620 --> 00:45:43,520
+اللي بيشتغل صح واللي عندنا حرجوا الـ sewage إن
+
+477
+00:45:43,520 --> 00:45:49,440
+اللي عندنا أخذوا هذا الزيت زي ما هو وسخّنوه زي ما
+
+478
+00:45:49,440 --> 00:45:52,860
+هو فطلع المادة السامة اللي هي الـ acrylaldehyde
+
+479
+00:45:52,860 --> 00:45:57,000
+نتيجة حرق الـ Glycerin العالم لأ العالم بيقول ليش
+
+480
+00:45:57,000 --> 00:46:02,840
+أنا أخسر الـ Glycerin نمرا واحد ونمرة اثنين أحرقه
+
+481
+00:46:02,840 --> 00:46:09,470
+وأطلع منه رائحة سيئة أو irritant يعني بتشعط كلّكم
+
+482
+00:46:09,470 --> 00:46:13,710
+جرّبته يمكن كيف التجربة كانت سيئة قالوا لأ بنفعله
+
+483
+00:46:13,710 --> 00:46:18,450
+مع الإيثانول بيعطينا Ester زاد Glycerin الآن احنا
+
+484
+00:46:18,450 --> 00:46:24,410
+في الراحه بنفصل الـ Glycerin لحاله بناخده وبنستعمل
+
+485
+00:46:24,410 --> 00:46:29,290
+استعمالاته المعهودة وبناخد هذه الـ Esters اللي
+
+486
+00:46:29,290 --> 00:46:33,750
+فيها سلاسل طويلة وبنحطها في السيارات والطيارات
+
+487
+00:46:34,330 --> 00:46:38,970
+وبتشتغل كويس هذا هو الـ biodiesel فالـ biodiesel
+
+488
+00:46:38,970 --> 00:46:44,290
+فكرته مش بعيدة كثير عن اللي عملوه الناس عندنا لكن
+
+489
+00:46:44,290 --> 00:46:49,770
+الناس عندنا أخذوا الزيت بكامله بـ .. زي ما قال مين
+
+490
+00:46:49,770 --> 00:46:56,590
+طه حسين ولا مين علينا أن نأخذ الثقافة الغربية
+
+491
+00:46:56,590 --> 00:47:04,760
+بحلوها ومرّها إنظرنا لأنه نتاج حرق الجليسرين كان
+
+492
+00:47:04,760 --> 00:47:11,460
+بضرّنا بينما لما أخذوا حلوها صار biodiesel ومرّها
+
+493
+00:47:11,460 --> 00:47:17,380
+برضه الـ Glycerin استفدنا منه في الصناعات الدوائية و
+
+494
+00:47:17,380 --> 00:47:20,300
+بنضيف على الشامبو وشيء مش الشامبوهات وغير و
+
+495
+00:47:20,300 --> 00:47:24,140
+غيّراتها بتلاقوا مكتوب عليها بالجليسرين بالجليسرين
+
+496
+00:47:24,140 --> 00:47:30,300
+واضح فاستفادوا بهذا الشكل وعملوا اللي هي بيسموها
+
+497
+00:47:30,300 --> 00:47:37,070
+الـ biodiesel الآن يمكن يظل عندنا موضوع بس مش الآن
+
+498
+00:47:37,070 --> 00:47:40,190
+هأحكي عنه بس بكون مبسوط إذا أنتم رحتوا جيبتوا
+
+499
+00:47:40,190 --> 00:47:47,590
+معلومات عنه أنه الصابونة من الزيت، مظبوط؟ طب اليوم
+
+500
+00:47:47,590 --> 00:47:52,510
+الصوابين اللي موجودة هل هي من الزيت؟ اللي بنسميها
+
+501
+00:47:52,510 --> 00:47:58,010
+synthetic detergents المنظفات الصناعية الجديدة هذه
+
+502
+00:47:58,010 --> 00:48:01,730
+والصوابين وإشي ولا إفرجة شوية صغيرة؟
+
+503
+00:48:04,480 --> 00:48:08,380
+إفرجة شوية صغيرة عن أنها تكون من الزيت بالمناسبة
+
+504
+00:48:08,380 --> 00:48:12,120
+صابونة الزيت زي صابونة الشكعة النابلسية وما إلى
+
+505
+00:48:12,120 --> 00:48:17,580
+ذلك على مية غزة المية المالحة اللي بنسميها الـ hard
+
+506
+00:48:17,580 --> 00:48:22,500
+water ما بترغيش بالمرة الماء العسر بينما اليوم
+
+507
+00:48:22,500 --> 00:48:26,420
+الصوابين بنجيبلها أملح ماء في الدنيا زي ماء البحر
+
+508
+00:48:26,420 --> 00:48:29,980
+بتجيبولنا إياها بترغي الصابونة ولا لأ؟ هذه مش
+
+509
+00:48:29,980 --> 00:48:34,740
+صابونة من الزيوت هذه صابونة صناعية بصير السؤال
+
+510
+00:48:34,740 --> 00:48:40,440
+بتقدروا تروحوا وتبحثوا في الإنترنت وتشوفوا قداش أو
+
+511
+00:48:40,440 --> 00:48:45,340
+في الكتب العلمية طبعا الفرق ما بين الـ Synthetic
+
+512
+00:48:45,340 --> 00:48:50,420
+detergents المنظفات الصناعية وما بين الصابون
+
+513
+00:48:50,420 --> 00:48:54,340
+العادي لمن الزيت وين الفرق؟ و المرة الجاية إذا صار
+
+514
+00:48:54,340 --> 00:48:58,420
+فرصة ممكن نحكي في الموضوع أو نخلي حد منكم يحكينا
+
+515
+00:48:58,420 --> 00:49:03,920
+في الموضوع الفرق ما بين الصابون العادي والمنظفات
+
+516
+00:49:03,920 --> 00:49:06,500
+الصناعية ماشي؟
+
+517
+00:49:29,310 --> 00:49:32,490
+trichloroethanol لما نقارنه مع ال trichloroethanol 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..029b0bc6b210e7b5eb43ae145c018d18522bfdd2
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_postprocess.srt
@@ -0,0 +1,2068 @@
+1
+00:00:08,680 --> 00:00:13,980
+بسم الله الرحمن الرحيم اليوم بنكمل ان شاء الله في
+
+2
+00:00:13,980 --> 00:00:17,700
+موضوع مشتقات الأحماض المرة الماضية أخدنا فكرة عن
+
+3
+00:00:17,700 --> 00:00:23,100
+الأحماض ويمكن فكرة عامة عن المشتقات بشكل عام
+
+4
+00:00:23,100 --> 00:00:28,730
+تحضيرها اليوم بنتوسع أكثر في هذا الموضوعالمشتقة
+
+5
+00:00:28,730 --> 00:00:35,290
+الأولى للأحماض اللى هى ال E Stars واضح لما نتطلع
+
+6
+00:00:35,290 --> 00:00:39,230
+على شكل أي E Star لما نتطلع على شكل أي E Star
+
+7
+00:00:39,230 --> 00:00:46,230
+بنلاحظ أنه ال E Star بتكون من شقينبتكون من شق من
+
+8
+00:00:46,230 --> 00:00:50,550
+الحامض و شق من الكحول و هو عادة بتحضر التفاعل
+
+9
+00:00:50,550 --> 00:00:54,550
+الحامض و الكحول فمثلا لو بدى أطلع على ال Easter
+
+10
+00:00:54,550 --> 00:00:58,510
+اللى موجود عندى بلاحظ أنه عندى الشق اللى فيه C
+
+11
+00:00:58,510 --> 00:00:59,630
+double bond O
+
+12
+00:01:09,010 --> 00:01:14,010
+الشق التاني اللي مكون من تلت كربونات كانوا متصلين
+
+13
+00:01:14,010 --> 00:01:20,020
+بأكسجين هو الكحول البروبانولالان لما هدولة بدوا
+
+14
+00:01:20,020 --> 00:01:26,260
+يعملوا E star، ال E star اسمه بده يبين فيه الشقين،
+
+15
+00:01:26,260 --> 00:01:31,660
+شق الكحول و شق الحامض، عادة بتتم التسمية بهذا
+
+16
+00:01:31,660 --> 00:01:37,500
+الشكل، بنشوف ايش اسم المجموعة تبعت الكحوللما يكون
+
+17
+00:01:37,500 --> 00:01:42,300
+عندى تلت ذرات كربون المجموعة اسمها Eprobil Eprobil
+
+18
+00:01:42,300 --> 00:01:48,220
+و الحامض ابيوتانووك أسد بنستبدل كلمة ابيوتانووك
+
+19
+00:01:48,220 --> 00:01:53,340
+أسد ببيوتانويت فبصير كل هذا اسمه Eprobil
+
+20
+00:01:53,340 --> 00:02:00,620
+ابيوتانويت Eprobil اللى هو شغق الالكول وبيوتانويت
+
+21
+00:02:00,620 --> 00:02:05,860
+اللى هو شغق الديستر طبعا هنا بيكون شبيه بتسمية
+
+22
+00:02:05,860 --> 00:02:10,310
+الأيوناتالسالبة لأن ال أيونات السالبة إحنا اتفقنا
+
+23
+00:02:10,310 --> 00:02:19,150
+إننا بنسميها بالنهاية it الان لو بدنا نطلع على بعض
+
+24
+00:02:19,150 --> 00:02:25,520
+الأمثلة حتى نأكد طريقة التسميةأهم شيء .. أهم شيء
+
+25
+00:02:25,520 --> 00:02:32,420
+كنت أحدده جزء الكحول و جزء الكحول هو الجزء المتصل
+
+26
+00:02:32,420 --> 00:02:36,340
+بالـ O هذه الميثير ده بدون السيطة من bond O يعني
+
+27
+00:02:36,340 --> 00:02:39,280
+لو في كل هدولة قبل ما أشتغل بتقول إيش هو جزء
+
+28
+00:02:39,280 --> 00:02:44,560
+الكحول؟ هنا الميثل، هذه جاية من الميثانول، هنا
+
+29
+00:02:44,560 --> 00:02:46,960
+الاثل
+
+30
+00:02:48,900 --> 00:02:52,780
+مرة تانية مثل الجزء التاني اللي فيه صيغة و point O
+
+31
+00:02:52,780 --> 00:02:59,040
+هو جزء الحامض هنا الفنل
+
+32
+00:02:59,040 --> 00:03:09,060
+هنا مثل الآن هذا شق الألكول عادة احنا بنكتب اسم
+
+33
+00:03:09,060 --> 00:03:12,860
+المجموعة تبعته و بنسيب فراغ بعدها فبهذه الحالة
+
+34
+00:03:12,860 --> 00:03:19,640
+بنقول مثل الآن الحامض اللي من carbon 10أسيتك أسد
+
+35
+00:03:19,640 --> 00:03:26,100
+فبصير المركب مثل أسيتيت لو كنت بدي بالأيوبك المطلق
+
+36
+00:03:26,100 --> 00:03:32,420
+أثانوك أسد بدي يصير مثل أثانويت واضح نفس الفكرة
+
+37
+00:03:32,420 --> 00:03:40,500
+هنا اثل و كربونتين اذا أسيتك أسد اثل أسيتيت لو كنت
+
+38
+00:03:40,500 --> 00:03:44,820
+بتطلع المركب اللي بعده مثل كربونتين تلاتة أربعة
+
+39
+00:03:44,820 --> 00:03:52,740
+هيصير مثلبيوتانويت مثل بيوتانويت لما بدي أجي أطلع
+
+40
+00:03:52,740 --> 00:03:57,300
+هنا هذه المجموعة البنزين لما تكون جاية كمجموعة
+
+41
+00:03:57,300 --> 00:04:04,200
+اسمها فنل فنل وهذا كربونتين من الاسيتك أسيت حيزير
+
+42
+00:04:04,200 --> 00:04:11,380
+فنل أسيتيت فنل أسيتيت واضح؟ لو بدي أطلع هنا هذه
+
+43
+00:04:11,380 --> 00:04:18,100
+مثل و البنزين مع مجموعة الحامض اسمهبنزويك أسد
+
+44
+00:04:18,100 --> 00:04:23,540
+فبتصير كلها مثل بنزويت واضح؟ لاحظوا مثل هدول
+
+45
+00:04:23,540 --> 00:04:28,840
+المركبين ربما تلاحظوا نوعا ما شبه بينهم و أحيانا
+
+46
+00:04:28,840 --> 00:04:33,540
+كتيرة لما بنسأل سؤال الطلاب بيخربوا التنين في بعض
+
+47
+00:04:33,540 --> 00:04:37,680
+يعني ممكن يسموا هذا مثلا فين الأسيتين أو يسموا هذا
+
+48
+00:04:37,680 --> 00:04:43,040
+مثل بنزويت فبيلزم الانتباه أن الجزء اللي بيذكر في
+
+49
+00:04:43,040 --> 00:04:49,000
+الأول هو جزءالألكوهول الجزء المتصل بالأكسجين من
+
+50
+00:04:49,000 --> 00:04:54,720
+خلال single bond والجزء التاني هو جزء ال acid فهنا
+
+51
+00:04:54,720 --> 00:05:00,420
+هذه فينيل و ال acid هو ايش؟ acidic acid يعني حتى
+
+52
+00:05:00,420 --> 00:05:04,220
+لو قلنا لكم كيف بدنا نحضر هذا المركب على سبيل
+
+53
+00:05:04,220 --> 00:05:08,060
+المثال بتكون ال acid اللي تحضروا منه يكون ال
+
+54
+00:05:08,060 --> 00:05:13,630
+acidic acid والألكوهول يكونالفينول بينما لو بنقول
+
+55
+00:05:13,630 --> 00:05:18,010
+هذا كيف بدنا نحضر المركب بدنا بنزويك أسيت وهذا
+
+56
+00:05:18,010 --> 00:05:24,770
+بيكون الميثانول واضح فهذا الكلام بحاجة إلى انتباه
+
+57
+00:05:24,770 --> 00:05:30,850
+وباعتقد بهذا الشكل تسمية تسمية ال E-stars تسمية
+
+58
+00:05:30,850 --> 00:05:36,270
+سهلة طبعا ربما بتلاحظوا هنا انه احنا أخدنا تسمية
+
+59
+00:05:36,270 --> 00:05:40,390
+ال E-stars بدونSubstituents
+
+60
+00:06:12,740 --> 00:06:18,960
+Ethane واضح؟ الآن لاحظوا هنا الحقيقة في عندي
+
+61
+00:06:18,960 --> 00:06:26,160
+Easter سيضة بال bond O OR وفي عندي كيتون سيضة بال
+
+62
+00:06:26,160 --> 00:06:32,480
+bond O الأولوية لمين بتكون ال Easter علشان هيك هذا
+
+63
+00:06:32,480 --> 00:06:38,720
+كاسم هيكون فيه Ethane في البداية دائمااللي هو جزء
+
+64
+00:06:38,720 --> 00:06:42,640
+ال alcohol و اللي بدي يكون في البداية بعدين بعد
+
+65
+00:06:42,640 --> 00:06:48,100
+الحامض ابتداء من السيطب ال point O واحد اتنين
+
+66
+00:06:48,100 --> 00:06:57,320
+تلاتة اربعة واضح؟ الآن هذا الحامض عبارة عن ايش؟
+
+67
+00:06:57,320 --> 00:07:03,400
+بيوتانويك اسد لما بدي يصير Easter بيوتانويت هذا ال
+
+68
+00:07:03,400 --> 00:07:10,540
+بيوتانويت شو بيحمل مجموعات؟Chlorine و Oxygen اذا
+
+69
+00:07:10,540 --> 00:07:16,300
+لما انا بدي اسميه هقول Ethyl انسيب فراغ Two
+
+70
+00:07:16,300 --> 00:07:29,800
+Chlorine Three Oxygen بيوتنويت يعني
+
+71
+00:07:29,800 --> 00:07:34,380
+كأنه ال Easter Ethyl بيوتنويت و هدول ال
+
+72
+00:07:34,380 --> 00:07:39,980
+substituents ذكرناهمواضح ال E star مثل بيوتانويت
+
+73
+00:07:39,980 --> 00:07:46,980
+وبنذكر ال substituents الآن بدنا واحدة بشكل كامل
+
+74
+00:07:46,980 --> 00:07:54,540
+تسمينا المركب اللي بعده ولو
+
+75
+00:07:54,540 --> 00:07:59,000
+يبدو كبير بس مافيش اشي صعب Systematic بشكل متدرج
+
+76
+00:07:59,000 --> 00:08:05,630
+تفضلي شكلك حابة تسميهجارتك أشطر منك تفضلي ايس
+
+77
+00:08:05,630 --> 00:08:12,170
+المجموعة تبع ال alcohol؟ هذه المجموعة ال isopropyl
+
+78
+00:08:12,170 --> 00:08:18,450
+كويس؟ الآن باجي على جزء الحامض بشوف كم كربونا قبل
+
+79
+00:08:18,450 --> 00:08:23,720
+انتبهوا معايادائما و أبدا .. دائما و أبدا لا تبدأ
+
+80
+00:08:23,720 --> 00:08:27,620
+بـ 2-hydroxy أنا لم أضع أرقام ولا حددت الحامض ..
+
+81
+00:08:27,620 --> 00:08:30,960
+ماذا يعرفني انها 2-hydroxy او 3-hydroxy التسمية
+
+82
+00:08:30,960 --> 00:08:35,340
+دائما و أبدا تبدأ من الخلف للأمام .. لكي تحددوا
+
+83
+00:08:35,340 --> 00:08:39,420
+الـhydroxy هذي وين .. ماذا يلزمك في الأول؟ تريد ان
+
+84
+00:08:39,420 --> 00:08:43,660
+تعرف كم كربونا عندك؟ اتحددني هنا .. ماهو الحامض
+
+85
+00:08:43,660 --> 00:08:44,620
+أساسا .. 1
+
+86
+00:08:47,550 --> 00:08:55,630
+تلاتة أربعة خمسة ستة إذا أنا أمام هكسانويك أسد في
+
+87
+00:08:55,630 --> 00:09:00,590
+ال Easter هيصير هكسانويل شو اللي متفرع من هذا
+
+88
+00:09:00,590 --> 00:09:07,570
+الهكسانويك أسد مثل
+
+89
+00:09:07,570 --> 00:09:16,480
+و مثل و هيدروكسيواضح؟ إذا كأنه لو أنا بدي أسمي هذا
+
+90
+00:09:16,480 --> 00:09:25,200
+ك E star بدون المجموعات بدي أقول isopropyl وفي
+
+91
+00:09:25,200 --> 00:09:28,900
+الآخر هيكون عنده hexanoate
+
+92
+00:09:30,740 --> 00:09:33,340
+أيزو برو بالهجسانويت يعني لو شيلت كل هدول
+
+93
+00:09:33,340 --> 00:09:37,220
+المجموعات ايزو برو بالهجسانويت من الأخطاء الدارجة
+
+94
+00:09:37,220 --> 00:09:40,760
+للأسف الشديد انه كتير بعد ما يسموا بروحوا بيسموا
+
+95
+00:09:40,760 --> 00:09:46,060
+هذه أوكزو هذه جزء من ال Easter ال C double bond O
+
+96
+00:09:46,060 --> 00:09:52,040
+O بلقيهم كاتبين لكلمة أوكزو هي جزء من ال Easterما
+
+97
+00:09:52,040 --> 00:09:56,080
+بتاخدش اشي لحالها بينما لو كانت واحدة تانية بعيد
+
+98
+00:09:56,080 --> 00:09:59,200
+عنها هانا السيدة من البندقه هذي جزء من ال Easter
+
+99
+00:09:59,200 --> 00:10:03,500
+هذي زيادة سميناها اقزو بس هانا مابنشيش نقول one
+
+100
+00:10:03,500 --> 00:10:07,860
+اقزو كتير بنلاحظ انه كاتبين هذي one اقزو هذي جزء
+
+101
+00:10:07,860 --> 00:10:15,220
+من ال Easter ايش اللي موجود عندك؟ اتفضلي من اللي
+
+102
+00:10:15,220 --> 00:10:23,910
+بتكمل؟ سامعيني طيب اه ال three fiveDimethyl-4
+
+103
+00:10:23,910 --> 00:10:27,990
+-hydroxy لحظوا ال Easter إيه له أولوية على إيش؟
+
+104
+00:10:27,990 --> 00:10:35,090
+على ال alcohol إذا أنا عندي three five dimethyl
+
+105
+00:10:35,090 --> 00:10:43,050
+four hydroxyhexanoate
+
+106
+00:10:43,050 --> 00:10:47,750
+كلمة واحدةلاحظوا الفراغ الوحيد اللي موجود بين كلمة
+
+107
+00:10:47,750 --> 00:10:51,470
+isopropyl و هذه المجموعة بيقول isopropyl فراغ
+
+108
+00:10:51,470 --> 00:10:54,410
+هدولة كلهم كلمة واحدة يعني لو على الكمبيوتر
+
+109
+00:10:54,410 --> 00:10:58,890
+بتكتبوا المفروض ولا فراغ تسيبوا كلهم متصل ببعض و
+
+110
+00:10:58,890 --> 00:11:08,690
+بدون ولا فراغ 3,5-dimethyl 4-hydroxyhexanoate ماشي
+
+111
+00:11:08,690 --> 00:11:11,830
+طيب
+
+112
+00:11:11,830 --> 00:11:19,870
+وانا سميةيلا اذا
+
+113
+00:11:19,870 --> 00:11:28,490
+هذا مثل ايش الحامض اربع
+
+114
+00:11:28,490 --> 00:11:32,730
+ذرات كربون بيوتان
+
+115
+00:11:32,730 --> 00:11:40,770
+و ويت ايه جاله double bond ايش حيصير بيوتين و ويت
+
+116
+00:11:40,770 --> 00:11:43,610
+ال double bond بحاجة الى ايش
+
+117
+00:11:49,710 --> 00:11:55,170
+لو اتشت هانا او هانا اذا بتاخد مواقع ال double
+
+118
+00:11:55,170 --> 00:12:00,910
+bond لازم احدد نقطة البداية تبعتها اعطينا عدي
+
+119
+00:12:00,910 --> 00:12:05,070
+الاسم كامل مثل
+
+120
+00:12:05,070 --> 00:12:08,330
+تو
+
+121
+00:12:08,330 --> 00:12:11,730
+بيوتين
+
+122
+00:12:11,730 --> 00:12:20,050
+اويتلاحظوا الـ two هذه عشان تحدد لي وين موقع تلقين
+
+123
+00:12:20,050 --> 00:12:28,150
+مثل two بيوتين قوات حددت لي وين موقع ال double
+
+124
+00:12:28,150 --> 00:12:35,510
+bond حددت لي وين موقع ال double bond ماشي اه الآن
+
+125
+00:12:35,510 --> 00:12:40,090
+بدك تسميه تفضلي شو اسمك انت مروة
+
+126
+00:12:41,060 --> 00:12:46,320
+ماروة أبو دالو تفضلي ماروة أبو دالو تفضلي هنا إيش
+
+127
+00:12:46,320 --> 00:12:51,980
+المجموعات اللي عندك؟ اللي تحت؟ ماشي ابن عم اللي
+
+128
+00:12:51,980 --> 00:13:02,580
+فوق إيش اللي عندك؟ تفضلي الإثل هو جزء الكحول خمسة
+
+129
+00:13:02,580 --> 00:13:07,140
+تفضلي
+
+130
+00:13:07,140 --> 00:13:15,680
+إيش هنسميه؟ إثل؟ايوة اتل
+
+131
+00:13:15,680 --> 00:13:23,980
+تو بنتين حطينا البنتين هدى عشان تقوليله triple
+
+132
+00:13:23,980 --> 00:13:35,260
+point اويت مش ات اويت اتل تو بنتين اويت اتل تو
+
+133
+00:13:35,260 --> 00:13:44,760
+بنتين اويت واضح؟ ممتازيلا يا شايماء،
+
+134
+00:13:44,760 --> 00:13:49,120
+إيش المجموعتين الوظيفيات اللي هنا، حتى يترسخ مبدأ
+
+135
+00:13:49,120 --> 00:13:53,640
+التفاضل؟
+
+136
+00:13:53,640 --> 00:13:58,680
+هذا Easter، Easter وAldehyde، الأولوية لمين؟
+
+137
+00:13:58,680 --> 00:14:01,240
+للإيستر، و الجزء اللي للكل؟
+
+138
+00:14:09,080 --> 00:14:19,760
+فنل ثري اقزو ابروفانويت واضح
+
+139
+00:14:19,760 --> 00:14:26,120
+فنل ثري اقزو ابروفانويت زي ما بتلاحظوا طبعا انه
+
+140
+00:14:26,120 --> 00:14:32,030
+لما بنحلل تسمية المراكبات العضوية ليست صعبةليش؟
+
+141
+00:14:32,030 --> 00:14:38,030
+لأن هذه IUPAC، إيش معنى IUPAC؟ إنه بتمشي على قواعد
+
+142
+00:14:38,030 --> 00:14:42,530
+مضطردة، المشكلة أحيانا اللي بتواجه الناس في ال
+
+143
+00:14:42,530 --> 00:14:47,360
+common namesالـ Common Names هي اللي ممكن تواجه
+
+144
+00:14:47,360 --> 00:14:51,820
+الناس إنهم مش عارفين و الله هذا ال common name شو
+
+145
+00:14:51,820 --> 00:14:56,240
+هو لما نقول glutaric acid فاتشها في المخ شولك ..
+
+146
+00:14:56,240 --> 00:15:00,640
+واضح؟ لكن التسمية اللي بتمشي على قواعد مضطردة ليست
+
+147
+00:15:00,640 --> 00:15:01,800
+صعبة
+
+148
+00:15:22,990 --> 00:15:27,670
+طبعا اكدنا و بنود نذكر انه من ال A stars كيف
+
+149
+00:15:27,670 --> 00:15:32,410
+بتحضروا من تفاعل ال substitution للاحماض
+
+150
+00:15:32,410 --> 00:15:37,870
+الكربوكسيلية ال alcohol بيهاجم على الحامض و بيطرد
+
+151
+00:15:39,110 --> 00:15:43,410
+الـ OH و بيصير عند ال E star نفس الاشي هنا alcohol
+
+152
+00:15:43,410 --> 00:15:48,390
+بيهاجم على الحامض و بيطرد ال OH هذا تأكيد بس ان ال
+
+153
+00:15:48,390 --> 00:15:53,410
+E star من alcohol و من حامض و ان التفاعل هذا هجوم
+
+154
+00:15:53,410 --> 00:15:58,110
+و خروج هو تفاعل substitution لما نيجي نقولكوا ان
+
+155
+00:15:58,110 --> 00:16:03,870
+ال main reaction of E stars is substitution او ال
+
+156
+00:16:03,870 --> 00:16:09,070
+assets او كل المشتقات هذه substitutionاستخدم يكل
+
+157
+00:16:09,070 --> 00:16:15,010
+البلاد؟ اكيد، اكيد، اكيد، مش minus بس عليها زوج
+
+158
+00:16:15,010 --> 00:16:18,330
+electronic، ال neutral ال neutral
+
+159
+00:16:22,140 --> 00:16:27,100
+يعني اللي بدها Easter إيش بدها تعمل كحول و حامض بس
+
+160
+00:16:27,100 --> 00:16:30,440
+طبعا لاحظوا هنا في لقطة دائما بتجينا في الموضوع
+
+161
+00:16:30,440 --> 00:16:36,060
+إنه حقيقة هذا تفاعل ال Easter هو تفاعل التزان يعني
+
+162
+00:16:36,060 --> 00:16:41,200
+بيضال عند الحامض مع الكحول مع ال Easter مع الميه
+
+163
+00:16:41,200 --> 00:16:45,700
+الآن لما بدنا يمشي أكتر باتجاه تكوين ال Easter
+
+164
+00:16:45,700 --> 00:16:52,170
+بنستعمل أي مبدأ في الكيميانستعمل مبدأ لتشاتليلة
+
+165
+00:16:52,170 --> 00:16:56,170
+لحرف الإتزال طب كيف بتدخل ال Easter يطلع بشكل
+
+166
+00:16:56,170 --> 00:17:05,990
+كبير؟ بنزيد تركيز متفاعل هنا أو بشيل
+
+167
+00:17:05,990 --> 00:17:11,120
+واحد من هناك، شو اللي بدنا نشيله عادة؟المية يعني
+
+168
+00:17:11,120 --> 00:17:15,840
+بيكونوا عاملين التفاعل بطريقة يسحبوا المية فكل ما
+
+169
+00:17:15,840 --> 00:17:19,860
+بيسحبوا المية التفاعل بيظل يمشي بهذا الاتجاه فممكن
+
+170
+00:17:19,860 --> 00:17:23,400
+نمشي حتى النهاية حسب قاعدة Le Chatelet أنه أنا لما
+
+171
+00:17:23,400 --> 00:17:29,160
+بشيل متفاعل من هنا بوجه الإتزان لتعديل التفاعل مرة
+
+172
+00:17:29,160 --> 00:17:34,280
+أخرى واضح هذا من الأشياء المعروفة
+
+173
+00:17:36,590 --> 00:17:43,550
+الان هال easters سويانة كلها التعب نص
+
+174
+00:17:43,550 --> 00:17:50,050
+عيلنا في ال easters الجواب اه ليش لان ال easters
+
+175
+00:17:50,050 --> 00:17:57,640
+مواد ذات روائحعطرية و ذات طعم و ما إلى ذلك والدليل
+
+176
+00:17:57,640 --> 00:18:01,860
+على هيك إذا أنتوا بتكونوا تشوفوا كل أنواع الفواكه
+
+177
+00:18:01,860 --> 00:18:07,240
+الروائح تبعتها الجميلة هي عبارة عن Easter's هي
+
+178
+00:18:07,240 --> 00:18:11,480
+عبارة عن Easter's فمثلا هذا ال Easter الأول اللي
+
+179
+00:18:11,480 --> 00:18:17,540
+هو مثل بيوتانويت هو Easter التفاح في ريحة إيش؟
+
+180
+00:18:18,020 --> 00:18:23,000
+الطفاح ال Easter التاني اللي هو مثل ثيو مثل ثيو
+
+181
+00:18:23,000 --> 00:18:29,660
+لما تكون S متصلة ب مثل بتعرفوا sulfur ثيو مثل ثيو
+
+182
+00:18:29,660 --> 00:18:38,140
+CH3S مثل ثيو بيوتانويت هذا Easter الفراولة ال
+
+183
+00:18:38,140 --> 00:18:43,760
+strawberry الآن هذا ال Easter اللي بيكبر شوية اثل
+
+184
+00:18:43,760 --> 00:18:47,020
+بيوتانويت Easter
+
+185
+00:18:49,320 --> 00:18:55,440
+البني بالز الاناناس Easter الاناناس اه وهذا ال
+
+186
+00:18:55,440 --> 00:19:00,020
+Easter اللي هو فيه بنتي الخمس ذرات كربون مع بيوتها
+
+187
+00:19:00,020 --> 00:19:07,100
+نويت Easter اه
+
+188
+00:19:07,100 --> 00:19:12,820
+جامر الدينليش؟ هو جمر الدين من إيش بيجيبوه؟ مش من
+
+189
+00:19:12,820 --> 00:19:18,380
+المشمش، هو الخلاصة أو العصير تبع المشمش و بيجففوه
+
+190
+00:19:18,380 --> 00:19:22,620
+جمر الدين الابريكوت .. ابريكوت بالالماني شو
+
+191
+00:19:22,620 --> 00:19:28,140
+بيقولوله؟ Apricosenمش مش واضح فلهذا السبب ال
+
+192
+00:19:28,140 --> 00:19:30,940
+Easter's مهمة وكتير من الروائح اللي بيحطوها
+
+193
+00:19:30,940 --> 00:19:36,020
+بالتوفي وما إلى ذلك هي روائح Easter's الان مثل هذه
+
+194
+00:19:36,020 --> 00:19:40,760
+ال Easter's في تجربة عملية بسيطة الطلاب ممكن
+
+195
+00:19:40,760 --> 00:19:46,300
+ياخدوا في المختبر مثلا ال methanol مع ال butanoic
+
+196
+00:19:46,300 --> 00:19:50,510
+acidو يسخلوهم شوية صغيرة في test tube و يعمل زي
+
+197
+00:19:50,510 --> 00:19:55,290
+هيك شم بشم ريحة التفاح او ريحة الفراولة او
+
+198
+00:19:55,290 --> 00:20:03,570
+الاناناس بسهولة يعني ممكن نحضر هذه المركبات واضح؟
+
+199
+00:20:03,570 --> 00:20:11,530
+الان احنا اتفقنا ال Easter عبارة عن ايش؟كحول و
+
+200
+00:20:11,530 --> 00:20:17,070
+Acid ايش ماله؟ كحول و Acid الان لما اجيب انا كحول
+
+201
+00:20:17,070 --> 00:20:20,210
+من هنا و Acid من هنا و يتفاعلوا و يعملوا ال Easter
+
+202
+00:20:20,210 --> 00:20:24,790
+هذا التفاعل بنقول عنه Intermolecular reaction هو
+
+203
+00:20:24,790 --> 00:20:29,850
+تفاعل بين جزء من هنا و جزء تاني من هنا ممكن في
+
+204
+00:20:29,850 --> 00:20:37,590
+جزيئات معينة اكون ال alcohol و الحامض بنفس الجزيئة
+
+205
+00:20:38,830 --> 00:20:42,770
+وبالتالي التفاعل يتم في داخل الجزء اللي بنسميه
+
+206
+00:20:42,770 --> 00:20:47,350
+Intramolecular reaction مثلا لو اتطلعنا على هذا
+
+207
+00:20:47,350 --> 00:20:55,340
+المركب1,2,3,4 إذا هذا بيوتانويك أسد هذا
+
+208
+00:20:55,340 --> 00:21:00,120
+البيوتانويك أسد على موقع أربعة شو موجود عليه
+
+209
+00:21:00,120 --> 00:21:07,440
+هيدروكسي four hydroxy butanoic acid لما أجي أسخنه
+
+210
+00:21:07,440 --> 00:21:13,720
+في وجود حامض بيعطيني cyclic esterلحظوا هذا ال
+
+211
+00:21:13,720 --> 00:21:17,540
+Easter Cyclic طبعا مرات لما يكون مرسومي بهذا الشكل
+
+212
+00:21:17,540 --> 00:21:23,340
+بيغلبكم لكن ممكن نفس المركب يكون رسمي و احنا سيضة
+
+213
+00:21:23,340 --> 00:21:31,140
+بال bond O OH هي carbon تنتين تلاتة اربعة واحد
+
+214
+00:21:31,140 --> 00:21:39,860
+اتنين تلاتة اربعة و انا عندك ال OH هذا نفس المركب1
+
+215
+00:21:39,860 --> 00:21:44,740
+,2,3,4,4 هيدروكسيبيوتانوك أسد الان عندما أثخن يعمل
+
+216
+00:21:44,740 --> 00:21:53,940
+ال E star الكحول سيهاجم هنا و سيطرد ال O H و بعدها
+
+217
+00:21:53,940 --> 00:21:58,380
+ستفقد ال H لأن ال O H مع ال H من هنا سيصبح ميه إذا
+
+218
+00:21:58,380 --> 00:22:03,550
+أعطاني في هذه الحالة Cyclic E starأعطاني في هذه
+
+219
+00:22:03,550 --> 00:22:07,550
+الحالة Cyclic Easter أكيد ال reaction هو عبارة عن
+
+220
+00:22:07,550 --> 00:22:13,370
+Intramolecular إيش يعني Intramolecular ان الجزئين
+
+221
+00:22:13,370 --> 00:22:16,990
+اللي متفاعلوا موجودين في داخل جزئ واحد يعني ما
+
+222
+00:22:16,990 --> 00:22:22,720
+استعملتش جزئينواضح؟ ما استعملتش جزيئين مجموعة
+
+223
+00:22:22,720 --> 00:22:27,160
+الكحول و مجموعة الحامض موجودة في جزئ واحد، ماجيبتش
+
+224
+00:22:27,160 --> 00:22:32,700
+الكحول من جزئ و الحامض من جزئ تاني فبيعطونا اللي
+
+225
+00:22:32,700 --> 00:22:37,540
+هو ال cyclic esters، C double bond O موجودة جوا
+
+226
+00:22:37,540 --> 00:22:44,040
+cycle أو جوا حلقة هذه ال cyclic esters كعائلة
+
+227
+00:22:44,040 --> 00:22:51,310
+بيسموها lactonesواضح؟ الـ Cyclic E Stars كعائلة
+
+228
+00:22:51,310 --> 00:22:55,230
+بيسموها Lactones كيف بعرف إنه هذه عائلة اللاكتون؟
+
+229
+00:22:55,230 --> 00:22:58,650
+كيف بعرف إنه هذه عائلة اللاكتون؟ بدي أشوف C double
+
+230
+00:22:58,650 --> 00:23:03,810
+bond O و جنبها O في داخل حلقة، إذا هذه العائلة
+
+231
+00:23:03,810 --> 00:23:09,670
+كعائلة بيكون اسمها إيش؟ Lactone واضح؟بكون اسمها
+
+232
+00:23:09,670 --> 00:23:15,250
+lactone طبعا عشان الأمور اللي ضالها متذكرينها
+
+233
+00:23:15,250 --> 00:23:20,570
+انتوا بالمقارنة الحقيقية ممكن يكون عندى غير ال
+
+234
+00:23:20,570 --> 00:23:24,910
+cyclic ester اللي هي اسم عائلة lactone ممكن يكون
+
+235
+00:23:24,910 --> 00:23:29,150
+عندى cyclic amide ايش ال cyclic amide
+
+236
+00:23:36,810 --> 00:23:40,970
+لأن C double bond O N في مركب مفتوح أمد لما تصير
+
+237
+00:23:40,970 --> 00:23:44,430
+في حلقة طبعا غالبا بتكون N H او اش ما كان يكون
+
+238
+00:23:44,430 --> 00:23:47,990
+بتصير Cyclic Amide اذا انا في عندى في الدنيا
+
+239
+00:23:47,990 --> 00:23:54,410
+Cyclic E star C double bond O O و Cyclic Amide C
+
+240
+00:23:54,410 --> 00:23:59,930
+double bond O N عائلة ال Cyclic E stars ايش اسمها
+
+241
+00:23:59,930 --> 00:24:06,090
+Lactones طب عائلة ال Cyclic Amides شو اسمها
+
+242
+00:24:08,600 --> 00:24:14,000
+Lactam عشان الإسمين زي بعض ماتخربوش بينهم مرات
+
+243
+00:24:14,000 --> 00:24:18,880
+بتجروا lactone و مرات بتجروا lactam فلو إجينا بدنا
+
+244
+00:24:18,880 --> 00:24:23,580
+نسألكوا سؤال صح و غلط نقولكم lactams are cyclic
+
+245
+00:24:23,580 --> 00:24:30,640
+esters lactams are cyclic amides lactons are
+
+246
+00:24:30,640 --> 00:24:38,860
+cyclic esters ال lactons هم اللي عبارة عنEasters
+
+247
+00:24:38,860 --> 00:24:45,800
+طبعا ال lactams هذه الحقيقة مهمة كتير ال lactams
+
+248
+00:24:45,800 --> 00:24:53,220
+مهمة كتير ليش؟ لأنه من أهم عائلات الأدوية بالذات
+
+249
+00:24:53,220 --> 00:24:58,220
+للي بيدرسوا تحاليل طبية زي جزء كبير منكم عائلة
+
+250
+00:24:58,220 --> 00:25:04,680
+بيقولولها ال beta lactams إذا عمركم سمعتوا beta
+
+251
+00:25:04,680 --> 00:25:11,070
+lactamsهذه ال beta lactams مهمة جدا جدا جدا
+
+252
+00:25:11,070 --> 00:25:16,130
+فبتلاقوا مكتوب عنوان كامل و كتب كاملة و أبحاث
+
+253
+00:25:16,130 --> 00:25:20,330
+كاملة اشي اسمه beta lactam antibiotics
+
+254
+00:25:23,580 --> 00:25:29,040
+Antibiotics هي عائلة مضادات حيوية وهي تحديدا عائلة
+
+255
+00:25:29,040 --> 00:25:34,280
+البنسالين ومشتقاته البنسالين والسفلوسبورين وكل هذه
+
+256
+00:25:34,280 --> 00:25:40,400
+العائلة بيكون فيهامع c double bond o في حلقة
+
+257
+00:25:40,400 --> 00:25:44,940
+رباعية طبعا ليش بيقولوا beta إذا أنا قلت هاي
+
+258
+00:25:44,940 --> 00:25:48,280
+الموضوع alpha بعد c double bond o هاي الموضوع beta
+
+259
+00:25:48,280 --> 00:25:52,520
+هاي alpha هاي beta فال nitrogen اللي هنا متصل في
+
+260
+00:25:52,520 --> 00:25:57,960
+أي موقع في beta بالنسبة للحمض الأصلي طبعا هنا في
+
+261
+00:25:57,960 --> 00:26:03,480
+عائلة البنسالين في عائلة البنسالين بيكون مع الحلقة
+
+262
+00:26:03,480 --> 00:26:09,400
+الرباعية هذه حلقة خماسيةيعني هذا الإطار العام لشكل
+
+263
+00:26:09,400 --> 00:26:14,580
+أدوية البنسالين واضح؟ الآن طوروا البنسالين ..
+
+264
+00:26:14,580 --> 00:26:18,980
+طوروا البنسالين للعائلات التانية الـ cephalosporin
+
+265
+00:26:18,980 --> 00:26:24,420
+والمضادات الحيوية الجديدة مع الحلقة الربعية صار
+
+266
+00:26:24,420 --> 00:26:30,120
+يحطوا حلقة إيش؟سداسية الاصل البنسلي الحلقة
+
+267
+00:26:30,120 --> 00:26:36,520
+الرباعية وخماسية طوروا ضالت هذه رباعية وهذه سداسية
+
+268
+00:26:36,520 --> 00:26:41,760
+ودائما عندهم قناعة ان الحلقة الرباعية لا مفر من
+
+269
+00:26:41,760 --> 00:26:45,840
+وجودها عشان هذه المضادات الحيوية تكون بتشتغل
+
+270
+00:26:45,840 --> 00:26:49,820
+الحلقة الخماسية مش مشكلة ممكن تصير سداسية وممكن
+
+271
+00:26:49,820 --> 00:26:54,260
+تكون مش حلقة بس الأساس في هذول المضادات الحيوية
+
+272
+00:26:54,260 --> 00:26:58,860
+كلهم ايشالحلقة الربعية وعشان هيك بنقول انه عندنا
+
+273
+00:26:58,860 --> 00:27:03,440
+عائلة كاملة من المضادات الحيوية اللي هي بيسموها ال
+
+274
+00:27:03,440 --> 00:27:09,240
+beta-lactam antibiotics اللي هي عائلة البنسالين
+
+275
+00:27:09,240 --> 00:27:13,960
+وأجياله ومشتقاته طبعا هنا انتبهوا لو كنتوا بتكون
+
+276
+00:27:13,960 --> 00:27:20,060
+تتطلعوا على اللاكتون هنا مثلا Alpha Beta Delta
+
+277
+00:27:20,060 --> 00:27:27,960
+Gamma نسميه Gamma Lactoneألفة بيتا جامعة هاي
+
+278
+00:27:27,960 --> 00:27:34,200
+الألفة هاي البيتا هاي الجامعة ال O جاية وين؟ جامعة
+
+279
+00:27:34,200 --> 00:27:42,460
+واضح؟ هيك احنا بنعد من ال C ضب ال point O تبعت
+
+280
+00:27:42,460 --> 00:27:46,640
+الحامض من بعدها لو كنا بنرقم في الأحمض من وين
+
+281
+00:27:46,640 --> 00:27:53,330
+بنرقم؟بنرقم من عند الـ C double bond O لكن لما
+
+282
+00:27:53,330 --> 00:28:00,130
+بنستعمل نظام Alpha و Beta من وان بنستعملها؟ من بعد
+
+283
+00:28:00,130 --> 00:28:01,870
+الـ C double bond O
+
+284
+00:28:05,460 --> 00:28:10,280
+على سبيل المثال ال amino acids الأحماض الأمينية ال
+
+285
+00:28:10,280 --> 00:28:14,480
+amino acids لما تاخدوا حامض زي هيك C double bond O
+
+286
+00:28:14,480 --> 00:28:19,440
+أو H وهنا تحطوا C بغض النظر إيش حاملة نفترض H و
+
+287
+00:28:19,440 --> 00:28:27,680
+حاملة R وهنا NH2 هذه العائلة شو بيسموها amino O
+
+288
+00:28:27,680 --> 00:28:35,210
+acid الآن هي ال alpha عشان هيك هذه بيسموهاالألفة
+
+289
+00:28:35,210 --> 00:28:40,330
+أمينو أسد اللي هي الألفة أمينو أسد اللي بتكون
+
+290
+00:28:40,330 --> 00:28:45,410
+لبروتينات الآن وقت إيش بتكون بيتا لو حطيت كمان
+
+291
+00:28:45,410 --> 00:28:50,310
+كربونا بعد الألفة والأمينو إجت عليها بيصير بيتا
+
+292
+00:28:50,310 --> 00:28:54,950
+أمينو أسد طبعا الأحماض الأمينية المكونة لبروتينات
+
+293
+00:28:54,950 --> 00:28:58,750
+في جسم الإنسان المشهورة
+
+294
+00:28:59,300 --> 00:29:02,240
+كلها عبارة عن أي نوع من الـ Amino Acids Alpha
+
+295
+00:29:02,240 --> 00:29:07,220
+بمعنى أن الـ Amino على أول كربونا بعد الكربونيل
+
+296
+00:29:07,220 --> 00:29:15,580
+group لكن لو كنت برقم وين واحد؟ اتنين هنا واضح؟ و
+
+297
+00:29:15,580 --> 00:29:20,600
+هذا الكلام السبق إن حكينا فيه فمافيش داعي نرد إن
+
+298
+00:29:20,600 --> 00:29:27,790
+هيالان هي انا امثلة و مكتوب اسمها بهمناش تحفظوا
+
+299
+00:29:27,790 --> 00:29:30,810
+اسمها بس حتى تكونوا بالصورة في مراكبات ذات
+
+300
+00:29:30,810 --> 00:29:37,290
+استعمالات و كلها عبارة عن ايش؟ كلها عبارة عن
+
+301
+00:29:37,290 --> 00:29:42,030
+lactones كل هذه المراكبات عبارة عن lactones ويلها
+
+302
+00:29:42,030 --> 00:29:48,530
+تطبيقات في الحياة بنجي
+
+303
+00:29:48,530 --> 00:29:59,610
+لموضوع الحقيقة مهم كتيرموضوع مهم كتير أن الزيوت
+
+304
+00:29:59,610 --> 00:30:05,670
+اللي هو الزيت و كمان بيجي زيه السمنة و الفات و ال
+
+305
+00:30:05,670 --> 00:30:11,930
+lipids و ما إلى ذلك هم عبارة عن .. بنسميهم ال tri
+
+306
+00:30:11,930 --> 00:30:17,370
+-glycerides أسترز of إجليسارين
+
+307
+00:30:18,400 --> 00:30:23,800
+يعني ال glycerin اللي بتعرفوه ال glycerin اللي
+
+308
+00:30:23,800 --> 00:30:27,400
+بيحطوه بيرطب الأيدين و ما إلى ذلك هو المركبة ده
+
+309
+00:30:27,400 --> 00:30:35,560
+اللي في تلت مجموعات OHs CH2OH CHOH CH2OH هذا عبارة
+
+310
+00:30:35,560 --> 00:30:43,000
+عن إيش؟ ال glycerin أو ال glycerol الآن هذا ال
+
+311
+00:30:43,000 --> 00:30:46,560
+glycerin لو تخيلته أنه بدنا نفعله مع حامض، لو
+
+312
+00:30:46,560 --> 00:30:50,720
+تخيلته أنه بدنا نفعله مع حامض، بنحضر ال Easter بس
+
+313
+00:30:50,720 --> 00:30:54,940
+بيكون عندى كام Easter؟التلاتة يعني هي أنا حامض
+
+314
+00:30:54,940 --> 00:30:59,900
+متصل ب OH تاعة alcohol و أنا حامض متصل ب OH تاعة
+
+315
+00:30:59,900 --> 00:31:04,340
+alcohol و أنا حامض متصل ب OH تاعة alcohol التلاتة
+
+316
+00:31:04,340 --> 00:31:07,840
+موجودين في جزء واحد ال OHS اللي هو جزء ال glycerin
+
+317
+00:31:07,840 --> 00:31:12,720
+عشانك هذه المركبات احنا بنسميها ال tri glycerides
+
+318
+00:31:12,720 --> 00:31:18,180
+هذا هو الزيت او السيرج او زيت الزيتون طب ايش بيفرق
+
+319
+00:31:18,180 --> 00:31:24,570
+زيت عن زيت؟يعني لما نقول زيرج، عباد الشمس، عن زيت
+
+320
+00:31:24,570 --> 00:31:29,270
+الصوية، عن زيت الزيتون، إيش بيفرجوا عن بعض؟ عن زيت
+
+321
+00:31:29,270 --> 00:31:37,450
+النخيل؟ بيفرجوا في الـR group اللي هنا هذه الـR
+
+322
+00:31:37,450 --> 00:31:42,290
+ممكن تكون في التلاتة نفس الأشياء وممكن تكون مختلفة
+
+323
+00:31:42,290 --> 00:31:47,030
+وغالبا هي سلسلة طويلة
+
+324
+00:31:48,700 --> 00:31:54,060
+ممكن تكون مشبعة مافيش فيها double bonds و ممكن
+
+325
+00:31:54,060 --> 00:32:00,680
+تكون فيها double bonds واضح؟ طبعا الزيوت اللي عادة
+
+326
+00:32:00,680 --> 00:32:07,050
+فيها double bonds بتكون سائلة ولا صلبة؟سائلة لما
+
+327
+00:32:07,050 --> 00:32:11,290
+يكون عندى double bonds بتكون الزيوت سائلة بنعمل
+
+328
+00:32:11,290 --> 00:32:15,610
+لها هدرجة سمعتوا عن هدرجة الزيوت؟ يعني بنحطها
+
+329
+00:32:15,610 --> 00:32:19,870
+هيدروجين بنلغط double bonds في هذه الحالة الزيوت
+
+330
+00:32:19,870 --> 00:32:24,190
+بتتحول إلى أيش؟ إلى زيوت صلبة اللى هي السمنة و
+
+331
+00:32:24,190 --> 00:32:29,110
+المارجرين و ما إلى ذلك يعني السمنة من وين في الآخر
+
+332
+00:32:29,110 --> 00:32:33,830
+بيجيبوها؟من الزيوت من السيرج وزيت عبادى الشمس
+
+333
+00:32:33,830 --> 00:32:37,790
+وغيره وغيرته بال هدرجة بيكون في عند double bonds
+
+334
+00:32:37,790 --> 00:32:44,150
+بألغى ال double bonds فبتحول الزيت السائل إلى زيت
+
+335
+00:32:44,150 --> 00:32:50,930
+صلب الآن هذه الزيوت كمان بيحضروا منها شغلة تانية
+
+336
+00:32:50,930 --> 00:32:57,540
+بيحضروا منها الصابونالصوب بيحضروا من الزيوت
+
+337
+00:32:57,540 --> 00:33:01,620
+الصابون مش دايما بنقول احنا الصابون النابولسي
+
+338
+00:33:01,620 --> 00:33:07,920
+بيحضروا من زيت الزيتون كيف بيحضروا الصابون من
+
+339
+00:33:07,920 --> 00:33:12,120
+الزيوت؟ بيجوا بيفعلوها مع ال sodium hydroxide
+
+340
+00:33:12,120 --> 00:33:16,900
+بشوية تسخين بيعملوا hydrolysis لهذا الزيت بيكسروا
+
+341
+00:33:16,900 --> 00:33:22,190
+من هنافبيطلع عندنا ال glycerin ال glycerin مش هو
+
+342
+00:33:22,190 --> 00:33:28,650
+فيت القصيد زائد ملح للأحماض بديش أنا أنسى أنه هذه
+
+343
+00:33:28,650 --> 00:33:33,030
+الأحماض أحماض أشمالها كبيرة fatty acids يعني مش
+
+344
+00:33:33,030 --> 00:33:36,970
+كربونتين تلاتة أربع طعش ست عشر تمن طعش فانتوا
+
+345
+00:33:36,970 --> 00:33:43,050
+تخيلوا هذا الحامض انه بهذا الشكل ست عشر كربونا مع
+
+346
+00:33:43,050 --> 00:33:48,840
+سيضة بالبندق O O minusالان هذه هي الصابونة
+
+347
+00:33:48,840 --> 00:33:54,620
+الصابونة زي ما بتلاحظوا مكونه من ايش؟ من شكلتين
+
+348
+00:33:54,620 --> 00:34:00,400
+الجزء اللي فيه ال minus هذا polar ولا non polar؟
+
+349
+00:34:00,400 --> 00:34:06,240
+polar bar و الجزء اللي فيه السلسلة الألفتية
+
+350
+00:34:06,240 --> 00:34:12,860
+الطويلةنان بولر إذا الصابون مكوّن من جزءين من
+
+351
+00:34:12,860 --> 00:34:18,380
+polar part و non polar part الفتك تشين طويلة 16
+
+352
+00:34:18,380 --> 00:34:23,360
+كربونا 18 كربونا هذه non polar والطرف أو الرأس
+
+353
+00:34:23,360 --> 00:34:30,360
+تبعه C double bond O O minus هذا الجزء polar الآن
+
+354
+00:34:30,360 --> 00:34:32,320
+كيف عد الصابون
+
+355
+00:34:35,560 --> 00:34:45,320
+بيقوم بعمله في التنظيف الصبون بنظف إيش؟ آه لازم
+
+356
+00:34:45,320 --> 00:34:50,840
+تكونوا عارفين يعني لو حد إيجي على إيديه سكر سكر
+
+357
+00:34:50,840 --> 00:34:54,560
+ميه و عليها سكر و ماء إلى ذلك مابلازمش يروح يغسل
+
+358
+00:34:54,560 --> 00:34:59,000
+بالصبون الصبون غالي اليوم الهواي ب 2.5 شكل بكفي
+
+359
+00:34:59,000 --> 00:35:05,480
+ميهالمية بتنظف السكر السكر بولر والمية بولر بولر
+
+360
+00:35:05,480 --> 00:35:08,660
+بدوب في بولر خلصنا المية بتنظف السكر بلزمش اروح
+
+361
+00:35:08,660 --> 00:35:12,660
+اغسل من السكر ايجي على ايدي بالصابون مافيش لزوم
+
+362
+00:35:12,660 --> 00:35:18,520
+الصابون لتنظيف ايش الدهون كيف بتتم عملية التنظيف
+
+363
+00:35:18,520 --> 00:35:23,920
+هذا الجزء اللي هو ال non-polar والدهون non-polar
+
+364
+00:35:23,920 --> 00:35:29,730
+والقاعدة العامةlike dissolve like فالدهون غير
+
+365
+00:35:29,730 --> 00:35:35,210
+القطبية ال non polar بتدوب فى هذا الجزء الطويل تبع
+
+366
+00:35:35,210 --> 00:35:40,450
+الزيت بدوبها بيحوط هذا الجزء الطويل اللى هو ال
+
+367
+00:35:40,450 --> 00:35:44,350
+chain او ال non polar part بيحوط نقطة الدهن او
+
+368
+00:35:44,350 --> 00:35:49,630
+الزيت و بعدين بتعمل اشي بنسميه كورا mycel و بتنزل
+
+369
+00:35:49,630 --> 00:35:55,620
+مع الميه وهى تحمل فى داخلهانقطة إيش الدهون زي ما
+
+370
+00:35:55,620 --> 00:36:01,340
+انتوا شايفين هنا في هذا المثال كيف بيشتغل الصابون
+
+371
+00:36:01,340 --> 00:36:06,000
+كيف بيشتغل الصابون هاي الجزء ال bowler هذا الجزء
+
+372
+00:36:06,000 --> 00:36:11,020
+ال bowler كله بيحمل شحنات سالبة بيصير للخارج هذه
+
+373
+00:36:11,020 --> 00:36:15,520
+البردجانية اللي في النص هي عبارة عن إيش هذه نقطة
+
+374
+00:36:15,520 --> 00:36:22,030
+الفاتأو الدهن اللي مدوبة في أطراف الـ non polar
+
+375
+00:36:22,030 --> 00:36:28,760
+part تبع الصبونواضح؟ فالصابون بدوّب نقطة الزيت في
+
+376
+00:36:28,760 --> 00:36:33,700
+الجزء غير القطب منه هذه كلها بتكون طبعا متنافرة مع
+
+377
+00:36:33,700 --> 00:36:36,880
+بعضها لإنها minus minus minus بتعمل اللي بنسميه
+
+378
+00:36:36,880 --> 00:36:42,340
+الميسل هذه بتصير زي كرة بتنزل وكل واحد بيغسل بتكون
+
+379
+00:36:42,340 --> 00:36:46,380
+الدهن في قلب هذه الكرة و بنفصله عن الميه و بنزله
+
+380
+00:36:46,380 --> 00:36:53,330
+مع إيش؟ مع الغسيل اللي هو الزيت مداب فيالـ non
+
+381
+00:36:53,330 --> 00:36:59,990
+-polar part تبع الصبون، واضح؟ هذا بالنسبة له
+
+382
+00:36:59,990 --> 00:37:05,170
+الصبون اللي هي جاية في الأساس من إيستر و الإيستر
+
+383
+00:37:05,170 --> 00:37:13,790
+هو إيش؟ الزيت، الإيستر هو الزيت نعم،
+
+384
+00:37:13,790 --> 00:37:20,430
+ما هي زي نفس الفكرة، هي زيت مهدرج بالصبون؟ لا،
+
+385
+00:37:20,430 --> 00:37:26,210
+بيكون الصبون كخربانلأ لأ لأ مش ممكن الصابون مضيعش
+
+386
+00:37:26,210 --> 00:37:32,970
+السمنة مش ممكن الصابون بضيع السمنة الصابون أكيد
+
+387
+00:37:32,970 --> 00:37:38,170
+بضيع السمنة بدون نقاش الآن خليكم معنا قبل ما نروح
+
+388
+00:37:38,170 --> 00:37:42,750
+على الكيميا شوية تفاعل مع green yard reagent احنا
+
+389
+00:37:42,750 --> 00:37:49,110
+ال seerage هذا او الزيت كان لنا تجربة قاسية معاه
+
+390
+00:37:49,110 --> 00:37:51,470
+وقتاش
+
+391
+00:37:53,280 --> 00:38:01,220
+أيام الحصار، بتذكروا لما السيارات صاروا يعبوا سيرش
+
+392
+00:38:01,220 --> 00:38:07,640
+سيارات المرسيدس و يشتغلوا عليه، إيش صار مع الناس؟
+
+393
+00:38:07,640 --> 00:38:17,700
+انخنجوامتذكرين ولا لأ؟ الناس لما صاروا يحطوا
+
+394
+00:38:17,700 --> 00:38:21,680
+searage .. يحطوا searage في motor السيارة و يشغلوا
+
+395
+00:38:21,680 --> 00:38:25,980
+السيارة الناس انخنقت طب ليش الناس صار عندها
+
+396
+00:38:25,980 --> 00:38:30,160
+الاختناق؟ ليش الناس صار عندها الاختناق؟ لسبب بسيط
+
+397
+00:38:30,160 --> 00:38:35,400
+انه هذا الزيت .. انه هذا الزيت بالتسخين ..
+
+398
+00:38:35,400 --> 00:38:38,300
+بالتسخين .. احنا أنا بطلنا مش حاطين bass احنا كلنا
+
+399
+00:38:38,300 --> 00:38:43,300
+حاطينحرارة اشتعال نحطه في الموتور نولعه إيش اللي
+
+400
+00:38:43,300 --> 00:38:48,300
+بيولع في الزيت أساساً اللي بيولع بالزيت هو هذا
+
+401
+00:38:48,300 --> 00:38:54,580
+الجزء اللي هو الالفاتيك بس مابدناش ننسى هانا نقطة
+
+402
+00:38:54,580 --> 00:39:01,420
+إنه الزيت مكوّن من جزءين جزء لجليسرين و الجزء
+
+403
+00:39:01,420 --> 00:39:09,120
+الالفاتيك الآن اللي بيصلح كوقود fuel هو هذا الجزء
+
+404
+00:39:10,110 --> 00:39:16,810
+الأليفاتيك والجليساريل هو المصيبة اللى كانت تطلع
+
+405
+00:39:16,810 --> 00:39:23,010
+الرائحة فالرائحة أصلها من وين؟ من الجليساريل انه
+
+406
+00:39:23,010 --> 00:39:27,550
+الجليساريل بالحرارة بيفقد جزيئين ميه بيعطينا مركب
+
+407
+00:39:27,550 --> 00:39:33,070
+زي هيك السيطة بالبوند او اللى هو هذا الديهيد اللى
+
+408
+00:39:33,070 --> 00:39:41,210
+بنسميه اكريلديهيد هذا بالإش بطلعبالتسخين Acryl
+
+409
+00:39:41,210 --> 00:39:49,070
+Aldehyde واضح؟ هذا الجزء من أين جاية الرائحة؟ من
+
+410
+00:39:49,070 --> 00:39:52,810
+الجلسريل الجزء التاني هو اللي بيولع اللي فيه آر
+
+411
+00:39:52,810 --> 00:39:56,550
+كبيرة ما أنتوا ما تنسوش برضه أنه البنزين السيارة
+
+412
+00:39:56,550 --> 00:40:02,690
+أساسا هو عبارة عن إيش؟ مشوال كيل؟ لأ لأ شوف C6H6
+
+413
+00:40:02,690 --> 00:40:08,640
+الفيول اللي هو الجازولين بنسميهالجازولين تبع
+
+414
+00:40:08,640 --> 00:40:14,840
+السيارة أو البنزين هو عبارة عن إيش؟ مش هو عبارة عن
+
+415
+00:40:14,840 --> 00:40:21,080
+سلسلة ألكين خليط من الهبتين واحد، اتنين، تلات،
+
+416
+00:40:21,080 --> 00:40:27,400
+أربعة، خمسة، ستة، سبعة هبتين و Iso-Octane، هاي
+
+417
+00:40:27,400 --> 00:40:35,720
+مجموعة ال I's وهنا، وعدّه1,2,3,4,5,6,7,8 ايزو
+
+418
+00:40:35,720 --> 00:40:41,880
+اكتين مع هبتين بيعطينا ايش؟ بيعطينا الجازولين او
+
+419
+00:40:41,880 --> 00:40:45,300
+الوقود اللي احنا بنستعمله بنزين السيارات خليط من
+
+420
+00:40:45,300 --> 00:40:49,440
+الهبتين والايزو اكتين والايزو اكتين بنحط بنسبة
+
+421
+00:40:49,440 --> 00:40:55,150
+معينة وعشانك بيصير عندى رقم الاكتين واضح؟مش فيه
+
+422
+00:40:55,150 --> 00:40:58,970
+عندى بنزين تسعين و بنزين خمسة وتسعين و إذا اختل
+
+423
+00:40:58,970 --> 00:41:02,730
+البنزين بيصير خبط في الموتور و ما إلى ذلك ال
+
+424
+00:41:02,730 --> 00:41:06,430
+knocking فالجازولين هو عبارة عن aliphatic compound
+
+425
+00:41:06,430 --> 00:41:10,890
+الان هذا الجزء ال aliphatic اللي بيولع نفسه موجود
+
+426
+00:41:10,890 --> 00:41:17,580
+وين؟ في ال Easterالأليفاتيك بيولع و ال E star
+
+427
+00:41:17,580 --> 00:41:24,500
+بيولع و بيعطي طاقة و لذلك يمكن أن يستعمل ال E star
+
+428
+00:41:24,500 --> 00:41:29,280
+كوقود المشكلة وين بتصير؟
+
+429
+00:41:31,640 --> 00:41:36,100
+المشكلة بتصير من الـ acrylaldehyde من الريحة يعني
+
+430
+00:41:36,100 --> 00:41:40,540
+لما استعمل كوقود السيارات كانت تمشي طبيعي بس كانت
+
+431
+00:41:40,540 --> 00:41:45,900
+مشكلة الناس من الروائح اللي بتطلع اللي هي رائحة
+
+432
+00:41:45,900 --> 00:41:50,240
+الـ acrylaldehyde الآن هذه المشكلة مالهاش حل علمي
+
+433
+00:41:50,240 --> 00:41:57,200
+مش بإمكاني الآن أنا أجيب زيوت و أحولها إلى وقود
+
+434
+00:41:58,590 --> 00:42:03,390
+العالم شغال على هذا الكلام و بيحضروا اشي بيسموه
+
+435
+00:42:03,390 --> 00:42:10,150
+biodiesel الديزل الحيوي هنا في ال .. في الوقود،
+
+436
+00:42:10,150 --> 00:42:15,510
+بتتميزوا بين شغلتين، بين اشي بنسميه bio fuel
+
+437
+00:42:15,510 --> 00:42:21,570
+الوقود الحيوي و بين biodiesel
+
+438
+00:42:27,240 --> 00:42:31,080
+البيوفيول أول ما بدوا كانوا ياخدوا الاثانول
+
+439
+00:42:31,080 --> 00:42:36,760
+الاثانول بيولع ولا لأ؟ اللي هو ال ethyl-OH من وين
+
+440
+00:42:36,760 --> 00:42:42,330
+بيجيبوا الاثانول؟من الدورة و تخمورها و ما إلى ذلك
+
+441
+00:42:42,330 --> 00:42:46,450
+صاروا يزرعوا نص أمريكا و غيرها و غيراتها دورة و
+
+442
+00:42:46,450 --> 00:42:49,630
+يحولوا لإيثانول و الإيثانول بتمشي عليه السيارات
+
+443
+00:42:49,630 --> 00:42:54,750
+بدون أي مشكلة زمان كان كل بيت صغير عشان يعمل الصبح
+
+444
+00:42:54,750 --> 00:43:02,330
+فنجان جهوب يكون عنده إيش بابور إسبيرتو كنا نشتري
+
+445
+00:43:02,330 --> 00:43:05,810
+الإسبيرتو بجزازة و يكون بابور صغير هالجد إله في
+
+446
+00:43:05,810 --> 00:43:08,410
+طيلة يمكن الآن صار من الذكريات
+
+447
+00:43:10,700 --> 00:43:14,780
+أيوة بابور هيك صغير وهنا إله فتيلة، هذا كان يتعبى
+
+448
+00:43:14,780 --> 00:43:19,920
+Spirto إيثانول، كل دار كان عنده بابور Spirto،
+
+449
+00:43:19,920 --> 00:43:22,400
+بيعملوا عليه في انجان الجهوز الصبح لأنه بيولع
+
+450
+00:43:22,400 --> 00:43:28,320
+بإيش؟ بسهولة، فالإيثانول وقود، هذا bio fuel، لكن
+
+451
+00:43:28,320 --> 00:43:33,700
+إيش قصة ال biodiesel؟ايش قصة الـBiodiesel اللي
+
+452
+00:43:33,700 --> 00:43:37,220
+اليوم العالم شغالين عليه بشكل كبير؟ و لو
+
+453
+00:43:37,220 --> 00:43:42,640
+معلوماتكوا، بالـ2008 و بالـ2009 طيّرت Airbus
+
+454
+00:43:44,990 --> 00:43:49,710
+طائرات على الـ biodiesel مخلوط طبعا بوقود عادي
+
+455
+00:43:49,710 --> 00:43:55,270
+يعني شوفوا كذا رحلة عملوها رحلات تجربية طيرت طائرة
+
+456
+00:43:55,270 --> 00:43:59,750
+باستعمال ال biodiesel طب إيش بيعملوا في ال
+
+457
+00:43:59,750 --> 00:44:05,010
+biodiesel اللي بيعملوا في ال biodiesel بييجوا لهذا
+
+458
+00:44:05,010 --> 00:44:10,090
+الزيت طبعا مابياخدوش زيت يؤكل في أشجار معينة زي
+
+459
+00:44:10,090 --> 00:44:15,580
+القطروفة والنخيل زيوت بيسموها non edibleيعني زيوت
+
+460
+00:44:15,580 --> 00:44:19,120
+غير مأكولة بدل ما ياخدوا الزيت اللي بتاكل فيه
+
+461
+00:44:19,120 --> 00:44:23,600
+نبتات صحراوية و بتطلع زيت كتير بياخدوا هذا الزيت و
+
+462
+00:44:23,600 --> 00:44:30,100
+بيفعلون افترض مع الاثانول اثل او اتش ايش بديه يعمل
+
+463
+00:44:30,100 --> 00:44:36,380
+الاثانول هذا Easter بيهاجم هناوبيطرد هذا الجزء
+
+464
+00:44:36,380 --> 00:44:40,760
+لاحظوا بيبدل Easter ب Easter وعشان هي هذه العملية
+
+465
+00:44:40,760 --> 00:44:43,920
+بيسموها الاشي اللي بيبدل .. شو بنقول عنه
+
+466
+00:44:43,920 --> 00:44:50,140
+بالإنجليزي؟ اللي بيبدل الكهربا Trans .. Trans
+
+467
+00:44:50,140 --> 00:44:55,500
+فالعملية بيسموها Trans Sterification
+
+468
+00:45:07,630 --> 00:45:18,020
+تراستيرفيكشن تراستيرفيكشنأو اثل اثل
+
+469
+00:45:18,020 --> 00:45:22,500
+اثل
+
+470
+00:45:22,500 --> 00:45:24,100
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+471
+00:45:24,100 --> 00:45:24,140
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+472
+00:45:24,140 --> 00:45:24,960
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+473
+00:45:24,960 --> 00:45:25,160
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+474
+00:45:25,160 --> 00:45:33,380
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+475
+00:45:35,420 --> 00:45:39,620
+لكن ماباخدش الزيت مباشرة يعني الفرق بين العالم
+
+476
+00:45:39,620 --> 00:45:43,520
+اللي بيشتغل صح و اللي عندنا حرجوا الـ searage ان
+
+477
+00:45:43,520 --> 00:45:49,440
+اللي عندنا أخدوا هذا الزيت زي ما هو و سخنوه زي ما
+
+478
+00:45:49,440 --> 00:45:52,860
+هو فطلع المادة السامة اللي هي الـ acrylaldehyde
+
+479
+00:45:52,860 --> 00:45:57,000
+نتيجة حرق ال glycerin العالم لأ العالم بيقول ليش
+
+480
+00:45:57,000 --> 00:46:02,840
+أنا أخسر ال glycerin نمرا واحد و نمرا اتنين أحرجه
+
+481
+00:46:02,840 --> 00:46:09,470
+و أطلع منه رائحةسيئ أو irritant يعني بتشعط كلكوا
+
+482
+00:46:09,470 --> 00:46:13,710
+جربته يمكن كيف التجربة كانت سيئة قالوا لأ بنفعله
+
+483
+00:46:13,710 --> 00:46:18,450
+مع الاثانول بيعطينا E star زاد غليسارين الآن احنا
+
+484
+00:46:18,450 --> 00:46:24,410
+في بالراحة بنفصل الغليسارين لحاله بناخده و بنستعمل
+
+485
+00:46:24,410 --> 00:46:29,290
+استعمالاته المعهودة و بناخد هذه ال E stars اللي
+
+486
+00:46:29,290 --> 00:46:33,750
+فيها سلاسل طويلة و بنحطها في السيارات والطيارات
+
+487
+00:46:34,330 --> 00:46:38,970
+وبتشتغل كويس هذا هو ال biodiesel فال biodiesel
+
+488
+00:46:38,970 --> 00:46:44,290
+فكرته مش بعيدة كتير عن اللي عملوه الناس عندنا لكن
+
+489
+00:46:44,290 --> 00:46:49,770
+الناس عندنا أخدوا الزيت بكامله ب .. زي ما قال مين
+
+490
+00:46:49,770 --> 00:46:56,590
+طه حسين ولا مين علينا أن نأخد الثقافة الغربية
+
+491
+00:46:56,590 --> 00:47:04,760
+بحلوها ومرها انضرنا لأنهنتاج حرق الجليسرين كان
+
+492
+00:47:04,760 --> 00:47:11,460
+بضرنا بينما لما أخذوا حلوها صار biodiesel ومرها
+
+493
+00:47:11,460 --> 00:47:17,380
+برضه الجليسرين استفدنا منه في الصناعات الدوائية و
+
+494
+00:47:17,380 --> 00:47:20,300
+بنضاف على الشامبو و إشي مشكل الشامبوهات و غير و
+
+495
+00:47:20,300 --> 00:47:24,140
+غيراته بتلاقوا مكتوب عليها بالجليسرين بالجليسرين
+
+496
+00:47:24,140 --> 00:47:30,300
+واضح فاستفادوا بهذا الشكل و عملوا اللي هي بيسموها
+
+497
+00:47:30,300 --> 00:47:37,070
+ال biodieselالان يمكن يظل عندنا موضوع بس مش الآن
+
+498
+00:47:37,070 --> 00:47:40,190
+هأحكي عنه بس بكون مبسوط إذا انتوا روحتوا جيبتوا
+
+499
+00:47:40,190 --> 00:47:47,590
+معلومات عنه أنه الصابونة من الزيت، مظبوط؟ طب اليوم
+
+500
+00:47:47,590 --> 00:47:52,510
+الصوابين اللي موجودة هل هي من الزيت؟ اللي بنسميها
+
+501
+00:47:52,510 --> 00:47:58,010
+synthetic detergents المنظفات الصناعية الجديدة هذه
+
+502
+00:47:58,010 --> 00:48:01,730
+والصوابين وإشي ولا إفرجة شوية صغيرة؟
+
+503
+00:48:04,480 --> 00:48:08,380
+أفرجتي شوية صغيرة عن أنها تكون من الزيت بالمناسبة
+
+504
+00:48:08,380 --> 00:48:12,120
+صابونة الزيت زي صابونة الشكعة النبولسية وما إلى
+
+505
+00:48:12,120 --> 00:48:17,580
+ذلك على مية غزة المية المالحة اللي بنسميها ال hard
+
+506
+00:48:17,580 --> 00:48:22,500
+water ما بترغيش بالمرة الماء العصربينما اليوم
+
+507
+00:48:22,500 --> 00:48:26,420
+الصوابين بنجيبلها أملح ميه في الدنيا زي ميه البحر
+
+508
+00:48:26,420 --> 00:48:29,980
+بتجيبولنا إياها بترغي الصابونة ولا لأ؟ هذه مش
+
+509
+00:48:29,980 --> 00:48:34,740
+صابونة من الزيوت هذه صابونة صناعية بصير السؤال
+
+510
+00:48:34,740 --> 00:48:40,440
+بتقدر تروحوا و تبحثوا في الانترنت و تشوفوا قداش أو
+
+511
+00:48:40,440 --> 00:48:45,340
+في الكتب العلمية طبعا الفرق ما بينالـ Synthetic
+
+512
+00:48:45,340 --> 00:48:50,420
+detergents المنظفات الصناعية و ما بين الصابون
+
+513
+00:48:50,420 --> 00:48:54,340
+العادى لمن الزيت وين الفرق؟ و المرة الجاية إذا صار
+
+514
+00:48:54,340 --> 00:48:58,420
+فرصة ممكن نحكي في الموضوع أو نخلي حد منكم يحكينا
+
+515
+00:48:58,420 --> 00:49:03,920
+في الموضوع الفرق ما بين الصابون العادى و المنظفات
+
+516
+00:49:03,920 --> 00:49:06,500
+الصناعية ماشي؟
+
+517
+00:49:29,310 --> 00:49:32,490
+Tricloroethanol لما نقارنه مع ال Tricloroethanol
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..691f4b225afb90f4b2070bc9b4f50467b3895382
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2666, "start": 8.68, "end": 26.66, "text": "بسم الله الرحمن الرحيم اليوم بنكمل ان شاء الله في موضوع مشتقات الأحماض المرة الماضية أخدنا فكرة عن الأحماض ويمكن فكرة عامة عن المشتقات بشكل عام تحضيرها اليوم بنتوسع أكثر في هذا الموضوع", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 44945, 24793, 1211, 16472, 13412, 16606, 21984, 8978, 3714, 2407, 11242, 45367, 37893, 2655, 4587, 9307, 16247, 35571, 46958, 9673, 25720, 9673, 46958, 10632, 5551, 9778, 3215, 8315, 6156, 4117, 25720, 18871, 16247, 35571, 46958, 4032, 32640, 19452, 6156, 4117, 25720, 6225, 10943, 3660, 18871, 9673, 8592, 2655, 4587, 9307, 4724, 8592, 28820, 6225, 10943, 6055, 5016, 11242, 13546, 11296, 45595, 20498, 44945, 2655, 41779, 3615, 5551, 4117, 49115, 8978, 23758, 9673, 2407, 11242, 45367], "avg_logprob": -0.05783046156853095, "compression_ratio": 2.036363636363636, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 8.680000000000003, 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{"start": 615.22, "end": 615.98, "word": " بتكمل؟", "probability": 0.744873046875}, {"start": 615.98, "end": 617.62, "word": " سامعيني", "probability": 0.85390625}, {"start": 617.62, "end": 617.92, "word": " طيب", "probability": 0.9654947916666666}, {"start": 617.92, "end": 618.14, "word": " اه", "probability": 0.790771484375}, {"start": 618.14, "end": 619.22, "word": " ال", "probability": 0.60009765625}, {"start": 619.22, "end": 619.42, "word": " three", "probability": 0.6640625}, {"start": 619.42, "end": 619.96, "word": " five", "probability": 0.67333984375}], "temperature": 1.0}, {"id": 26, "seek": 64395, "start": 621.99, "end": 643.95, "text": "Dimethyl-4-hydroxy لحظوا ال Easter إيه له أولوية على إيش؟ على ال alcohol إذا أنا عندي three five dimethyl four hydroxyhexanoate كلمة واحدة", "tokens": [35, 332, 3293, 5088, 12, 19, 12, 21591, 340, 12876, 5296, 5016, 19913, 14407, 2423, 9403, 11933, 1829, 3224, 46740, 5551, 12610, 2407, 10632, 15844, 11933, 1829, 8592, 22807, 15844, 2423, 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626.67, "word": " أولوية", "probability": 0.917236328125}, {"start": 626.67, "end": 626.89, "word": " على", "probability": 0.5771484375}, {"start": 626.89, "end": 627.99, "word": " إيش؟", "probability": 0.71722412109375}, {"start": 627.99, "end": 628.81, "word": " على", "probability": 0.810546875}, {"start": 628.81, "end": 628.97, "word": " ال", "probability": 0.75537109375}, {"start": 628.97, "end": 629.43, "word": " alcohol", "probability": 0.634765625}, {"start": 629.43, "end": 630.73, "word": " إذا", "probability": 0.787353515625}, {"start": 630.73, "end": 631.03, "word": " أنا", "probability": 0.75732421875}, {"start": 631.03, "end": 631.39, "word": " عندي", "probability": 0.74951171875}, {"start": 631.39, "end": 631.75, "word": " three", "probability": 0.64599609375}, {"start": 631.75, "end": 632.55, "word": " five", "probability": 0.70556640625}, {"start": 632.55, "end": 635.09, "word": " dimethyl", "probability": 0.7560221354166666}, {"start": 635.09, "end": 637.51, "word": " four", "probability": 0.7099609375}, {"start": 637.51, "end": 643.05, "word": " hydroxyhexanoate", "probability": 0.813720703125}, {"start": 643.05, "end": 643.45, "word": " كلمة", "probability": 0.9130859375}, {"start": 643.45, "end": 643.95, "word": " واحدة", "probability": 0.9853515625}], "temperature": 1.0}, {"id": 27, "seek": 67333, "start": 645.01, "end": 673.33, "text": "لاحظوا الفراغ الوحيد اللي موجود بين كلمة isopropyl و هذه المجموعة بيقول isopropyl فراغ هدولة كلهم كلمة واحدة يعني لو على الكمبيوتر بتكتبوا المفروض ولا فراغ تسيبوا كلهم متصل ببعض و بدون ولا فراغ 3,5-dimethyl 4-hydroxyhexanoate ماشي طيب وانا سمية", "tokens": [15040, 5016, 19913, 14407, 27188, 2288, 5718, 118, 2423, 2407, 5016, 25708, 13672, 1829, 3714, 29245, 23328, 49374, 9122, 19528, 3660, 307, 404, 1513, 5088, 4032, 29538, 9673, 7435, 2304, 2407, 27884, 4724, 1829, 39648, 307, 404, 1513, 5088, 6156, 2288, 5718, 118, 8032, 3215, 12610, 3660, 28242, 16095, 9122, 19528, 3660, 36764, 24401, 3660, 37495, 22653, 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" بين", "probability": 0.9765625}, {"start": 647.15, "end": 647.75, "word": " كلمة", "probability": 0.8694661458333334}, {"start": 647.75, "end": 649.21, "word": " isopropyl", "probability": 0.78912353515625}, {"start": 649.21, "end": 649.29, "word": " و", "probability": 0.85986328125}, {"start": 649.29, "end": 649.51, "word": " هذه", "probability": 0.3017578125}, {"start": 649.51, "end": 650.07, "word": " المجموعة", "probability": 0.8990234375}, {"start": 650.07, "end": 650.37, "word": " بيقول", "probability": 0.59375}, {"start": 650.37, "end": 651.07, "word": " isopropyl", "probability": 0.8883056640625}, {"start": 651.07, "end": 651.47, "word": " فراغ", "probability": 0.9334716796875}, {"start": 651.47, "end": 651.91, "word": " هدولة", "probability": 0.7952880859375}, {"start": 651.91, "end": 652.19, "word": " كلهم", "probability": 0.951904296875}, {"start": 652.19, "end": 652.55, "word": " كلمة", "probability": 0.9334309895833334}, {"start": 652.55, "end": 652.85, "word": " واحدة", "probability": 0.9716796875}, {"start": 652.85, "end": 652.99, "word": " يعني", "probability": 0.90869140625}, {"start": 652.99, "end": 653.25, "word": " لو", "probability": 0.501953125}, {"start": 653.25, "end": 653.43, "word": " على", "probability": 0.5830078125}, {"start": 653.43, "end": 654.41, "word": " الكمبيوتر", "probability": 0.95869140625}, {"start": 654.41, "end": 655.41, "word": " بتكتبوا", "probability": 0.85849609375}, {"start": 655.41, "end": 655.87, "word": " المفروض", "probability": 0.9864501953125}, {"start": 655.87, "end": 656.27, "word": " ولا", "probability": 0.888671875}, {"start": 656.27, "end": 656.73, "word": " فراغ", "probability": 0.987060546875}, {"start": 656.73, "end": 657.37, "word": " تسيبوا", "probability": 0.8708984375}, {"start": 657.37, "end": 657.93, "word": " كلهم", "probability": 0.79443359375}, {"start": 657.93, "end": 658.37, "word": " متصل", "probability": 0.924560546875}, {"start": 658.37, "end": 658.81, "word": " ببعض", "probability": 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{"start": 694.17, "end": 694.41, "word": " double", "probability": 0.86572265625}, {"start": 694.41, "end": 694.93, "word": " bond", "probability": 0.93896484375}, {"start": 694.93, "end": 697.33, "word": " ايش", "probability": 0.73486328125}, {"start": 697.33, "end": 697.99, "word": " حيصير", "probability": 0.8408203125}, {"start": 697.99, "end": 699.91, "word": " بيوتين", "probability": 0.9371337890625}, {"start": 699.91, "end": 700.29, "word": " و", "probability": 0.9912109375}, {"start": 700.29, "end": 700.77, "word": " ويت", "probability": 0.842041015625}, {"start": 700.77, "end": 701.91, "word": " ال", "probability": 0.7060546875}, {"start": 701.91, "end": 702.15, "word": " double", "probability": 0.95068359375}, {"start": 702.15, "end": 702.43, "word": " bond", "probability": 0.91650390625}, {"start": 702.43, "end": 702.97, "word": " بحاجة", "probability": 0.9530029296875}, {"start": 702.97, "end": 703.23, "word": " الى", "probability": 0.542236328125}, {"start": 703.23, "end": 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بيوتين قوات حددت لي وين موقع ال double bond حددت لي وين موقع ال double bond ماشي اه الآن بدك تسميه تفضلي شو اسمك انت مروة", "tokens": [15040, 5016, 19913, 14407, 2423, 39184, 732, 29538, 6225, 8592, 7649, 6055, 24401, 3215, 32239, 4032, 9957, 3714, 30543, 3615, 6055, 1211, 4587, 9957, 50113, 1211, 732, 4724, 1829, 35473, 9957, 12174, 2407, 9307, 11331, 3215, 3215, 2655, 32239, 4032, 9957, 3714, 30543, 3615, 2423, 3834, 6086, 11331, 3215, 3215, 2655, 32239, 4032, 9957, 3714, 30543, 3615, 2423, 3834, 6086, 3714, 33599, 1829, 1975, 3224, 6024, 48506, 47525, 4117, 6055, 38251, 1829, 3224, 6055, 5172, 11242, 20292, 13412, 2407, 24525, 2304, 4117, 16472, 2655, 3714, 32887, 3660], "avg_logprob": -0.22265625711191783, "compression_ratio": 1.795031055900621, "no_speech_prob": 0.0, "words": [{"start": 734.09, "end": 734.69, "word": "لاحظوا", "probability": 0.86962890625}, {"start": 734.69, "end": 734.91, "word": " الـ", "probability": 0.759033203125}, {"start": 734.91, "end": 735.07, "word": " 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أبو دالو تفضلي هنا إيش المجموعات اللي عندك؟ اللي تحت؟ ماشي ابن عم اللي فوق إيش اللي عندك؟ تفضلي الإثل هو جزء الكحول خمسة تفضلي إيش هنسميه؟ إثل؟", "tokens": [2304, 9640, 2407, 3660, 5551, 3555, 2407, 11778, 6027, 2407, 6055, 5172, 11242, 20292, 3714, 9640, 2407, 3660, 5551, 3555, 2407, 11778, 6027, 2407, 6055, 5172, 11242, 20292, 34105, 11933, 1829, 8592, 9673, 7435, 2304, 45367, 9307, 13672, 1829, 43242, 4117, 22807, 13672, 1829, 6055, 33753, 22807, 3714, 33599, 1829, 48127, 1863, 6225, 2304, 13672, 1829, 6156, 30543, 11933, 1829, 8592, 13672, 1829, 43242, 4117, 22807, 6055, 5172, 11242, 20292, 33688, 12984, 1211, 31439, 10874, 11622, 38207, 33251, 5016, 12610, 16490, 2304, 3794, 3660, 6055, 5172, 11242, 20292, 11933, 1829, 8592, 8032, 1863, 38251, 1829, 3224, 22807, 11933, 12984, 1211, 22807], "avg_logprob": -0.1515012218379507, "compression_ratio": 2.026315789473684, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 761.06, "end": 761.52, "word": "ماروة", "probability": 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{"start": 1335.53, "end": 1335.95, "word": " جزئ", "probability": 0.8352864583333334}, {"start": 1335.95, "end": 1336.39, "word": " واحد", "probability": 0.99072265625}, {"start": 1336.39, "end": 1336.87, "word": " يعني", "probability": 0.80712890625}, {"start": 1336.87, "end": 1336.99, "word": " ما", "probability": 0.68017578125}, {"start": 1336.99, "end": 1337.77, "word": " استعملتش", "probability": 0.90146484375}, {"start": 1337.77, "end": 1338.55, "word": " جزئين", "probability": 0.841064453125}], "temperature": 1.0}, {"id": 56, "seek": 136586, "start": 1339.64, "end": 1365.86, "text": "واضح؟ ما استعملتش جزيئين مجموعة الكحول و مجموعة الحامض موجودة في جزئ واحد، ماجيبتش الكحول من جزئ و الحامض من جزئ تاني فبيعطونا اللي هو ال cyclic esters، C double bond O موجودة جوا cycle أو جوا حلقة هذه ال cyclic esters كعائلة بيسموها lactones", "tokens": [2407, 46958, 5016, 22807, 19446, 44713, 25957, 1211, 2655, 8592, 10874, 11622, 1829, 19986, 9957, 3714, 7435, 2304, 2407, 27884, 33251, 5016, 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1361.14, "end": 1361.52, "word": " ال", "probability": 0.951171875}, {"start": 1361.52, "end": 1362.18, "word": " cyclic", "probability": 0.79296875}, {"start": 1362.18, "end": 1363.02, "word": " esters", "probability": 0.96240234375}, {"start": 1363.02, "end": 1364.04, "word": " كعائلة", "probability": 0.9825439453125}, {"start": 1364.04, "end": 1365.1, "word": " بيسموها", "probability": 0.8978515625}, {"start": 1365.1, "end": 1365.86, "word": " lactones", "probability": 0.843505859375}], "temperature": 1.0}, {"id": 57, "seek": 138777, "start": 1367.75, "end": 1387.77, "text": "واضح؟ الـ Cyclic E Stars كعائلة بيسموها Lactones كيف بعرف إنه هذه عائلة اللاكتون؟ كيف بعرف إنه هذه عائلة اللاكتون؟ بدي أشوف C double bond O و جنبها O في داخل حلقة، إذا هذه العائلة كعائلة بيكون اسمها إيش؟ Lactone واضح؟", "tokens": [2407, 46958, 5016, 22807, 2423, 39184, 10295, 66, 1050, 462, 20957, 9122, 3615, 16373, 37977, 4724, 1829, 38251, 2407, 11296, 441, 578, 2213, 9122, 33911, 45030, 28480, 36145, 3224, 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"word": " O", "probability": 0.98583984375}, {"start": 1380.97, "end": 1381.47, "word": " في", "probability": 0.73583984375}, {"start": 1381.47, "end": 1381.87, "word": " داخل", "probability": 0.98046875}, {"start": 1381.87, "end": 1382.75, "word": " حلقة،", "probability": 0.8699951171875}, {"start": 1382.75, "end": 1382.95, "word": " إذا", "probability": 0.812744140625}, {"start": 1382.95, "end": 1383.27, "word": " هذه", "probability": 0.8203125}, {"start": 1383.27, "end": 1383.81, "word": " العائلة", "probability": 0.9962565104166666}, {"start": 1383.81, "end": 1384.41, "word": " كعائلة", "probability": 0.9871826171875}, {"start": 1384.41, "end": 1384.73, "word": " بيكون", "probability": 0.9527994791666666}, {"start": 1384.73, "end": 1385.17, "word": " اسمها", "probability": 0.9381510416666666}, {"start": 1385.17, "end": 1385.59, "word": " إيش؟", "probability": 0.8497314453125}, {"start": 1385.59, "end": 1386.65, "word": " Lactone", "probability": 0.80810546875}, {"start": 1386.65, "end": 1387.77, "word": " واضح؟", "probability": 0.84979248046875}], "temperature": 1.0}, {"id": 58, "seek": 140915, "start": 1388.57, "end": 1409.15, "text": "بكون اسمها lactone طبعا عشان الأمور اللي ضالها متذكرينها انتوا بالمقارنة الحقيقية ممكن يكون عندى غير ال cyclic ester اللي هي اسم عائلة lactone ممكن يكون عندى cyclic amide ايش ال cyclic amide", "tokens": [3555, 30544, 24525, 2304, 11296, 34042, 546, 23032, 3555, 3615, 995, 6225, 8592, 7649, 16247, 2304, 13063, 13672, 1829, 48812, 6027, 11296, 44650, 8848, 37983, 9957, 11296, 16472, 2655, 14407, 20666, 2304, 4587, 9640, 1863, 3660, 21542, 38436, 4587, 10632, 3714, 43020, 7251, 30544, 43242, 7578, 32771, 13546, 2423, 38154, 1050, 871, 260, 13672, 1829, 39896, 24525, 2304, 6225, 16373, 37977, 34042, 546, 3714, 43020, 7251, 30544, 43242, 7578, 38154, 1050, 669, 482, 1975, 1829, 8592, 2423, 38154, 1050, 669, 482], "avg_logprob": -0.24104420531813692, "compression_ratio": 1.6910112359550562, "no_speech_prob": 1.430511474609375e-06, 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"probability": 0.8165283203125}, {"start": 1397.77, "end": 1399.35, "word": " ممكن", "probability": 0.9619140625}, {"start": 1399.35, "end": 1399.69, "word": " يكون", "probability": 0.905029296875}, {"start": 1399.69, "end": 1400.09, "word": " عندى", "probability": 0.64453125}, {"start": 1400.09, "end": 1400.39, "word": " غير", "probability": 0.9873046875}, {"start": 1400.39, "end": 1400.57, "word": " ال", "probability": 0.76513671875}, {"start": 1400.57, "end": 1401.23, "word": " cyclic", "probability": 0.6600341796875}, {"start": 1401.23, "end": 1401.85, "word": " ester", "probability": 0.86328125}, {"start": 1401.85, "end": 1402.03, "word": " اللي", "probability": 0.744873046875}, {"start": 1402.03, "end": 1402.25, "word": " هي", "probability": 0.71728515625}, {"start": 1402.25, "end": 1402.67, "word": " اسم", "probability": 0.79345703125}, {"start": 1402.67, "end": 1403.17, "word": " عائلة", "probability": 0.9474283854166666}, {"start": 1403.17, "end": 1403.95, "word": " lactone", 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"seek": 164274, "start": 1615.66, "end": 1642.74, "text": "الحلقة الربعية وعشان هيك بنقول انه عندنا عائلة كاملة من المضادات الحيوية اللي هي بيسموها ال beta-lactam antibiotics اللي هي عائلة البنسالين وأجياله ومشتقاته طبعا هنا انتبهوا لو كنتوا بتكون تتطلعوا على اللاكتون هنا مثلا Alpha Beta Delta Gamma نسميه Gamma Lactone", "tokens": [6027, 5016, 1211, 28671, 34892, 3555, 3615, 10632, 4032, 3615, 8592, 7649, 39896, 4117, 44945, 39648, 16472, 3224, 43242, 8315, 6225, 16373, 37977, 9122, 10943, 37977, 9154, 9673, 11242, 18513, 9307, 21542, 1829, 2407, 10632, 13672, 1829, 39896, 4724, 1829, 38251, 2407, 11296, 2423, 9861, 12, 75, 578, 335, 26922, 13672, 1829, 39896, 6225, 16373, 37977, 29739, 1863, 3794, 6027, 9957, 36725, 7435, 1829, 6027, 3224, 4032, 2304, 8592, 2655, 4587, 9307, 3224, 23032, 3555, 3615, 995, 34105, 16472, 2655, 3555, 3224, 14407, 45164, 9122, 29399, 14407, 39894, 30544, 6055, 2655, 9566, 1211, 3615, 14407, 15844, 13672, 995, 4117, 2655, 11536, 34105, 50113, 15040, 20588, 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جامعة واضح؟ هيك احنا بنعد من ال C ضب ال point O تبعت الحامض من بعدها لو كنا بنرقم في الأحمض من وين بنرقم؟", "tokens": [10721, 46538, 3660, 4724, 36081, 995, 10874, 10943, 27884, 8032, 47302, 16247, 46538, 3660, 8032, 47302, 2423, 21292, 2655, 995, 8032, 47302, 25724, 10943, 27884, 2423, 422, 10874, 995, 10632, 4032, 9957, 22807, 10874, 10943, 27884, 4032, 46958, 5016, 22807, 39896, 4117, 1975, 5016, 8315, 44945, 22488, 9154, 2423, 383, 48812, 3555, 2423, 935, 422, 6055, 3555, 34268, 21542, 10943, 11242, 9154, 39182, 11296, 45164, 9122, 8315, 44945, 2288, 4587, 2304, 8978, 16247, 35571, 11242, 9154, 4032, 9957, 44945, 2288, 4587, 2304, 22807], "avg_logprob": -0.2777157656493641, "compression_ratio": 1.8616352201257862, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1644.58, "end": 1645.16, "word": "ألفة", "probability": 0.5413411458333334}, {"start": 1645.16, "end": 1645.7, "word": " بيتا", "probability": 0.5569661458333334}, {"start": 1645.7, "end": 1647.12, "word": " 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"probability": 0.79833984375}, {"start": 1878.18, "end": 1879.32, "word": " زيت", "probability": 0.970703125}, {"start": 1879.32, "end": 1879.56, "word": " عن", "probability": 0.96337890625}, {"start": 1879.56, "end": 1880.18, "word": " زيت؟", "probability": 0.94677734375}], "temperature": 1.0}, {"id": 78, "seek": 190703, "start": 1880.77, "end": 1907.03, "text": "يعني لما نقول زيرج، عباد الشمس، عن زيت الصوية، عن زيت الزيتون، إيش بيفرجوا عن بعض؟ عن زيت النخيل؟ بيفرجوا في الـR group اللي هنا هذه الـR ممكن تكون في التلاتة نفس الأشياء وممكن تكون مختلفة وغالبا هي سلسلة طويلة", "tokens": [40228, 22653, 5296, 15042, 8717, 39648, 30767, 13546, 7435, 12399, 6225, 3555, 18513, 25124, 2304, 3794, 12399, 18871, 30767, 36081, 31767, 2407, 10632, 12399, 18871, 30767, 36081, 6024, 110, 36081, 11536, 12399, 11933, 1829, 8592, 4724, 33911, 47341, 14407, 18871, 45030, 11242, 22807, 18871, 30767, 36081, 28239, 9778, 26895, 22807, 4724, 33911, 47341, 14407, 8978, 2423, 39184, 49, 1594, 13672, 1829, 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{"start": 2913.12, "end": 2913.98, "word": " بصير", "probability": 0.7718098958333334}, {"start": 2913.98, "end": 2914.74, "word": " السؤال", "probability": 0.9925130208333334}, {"start": 2914.74, "end": 2915.98, "word": " بتقدر", "probability": 0.8299153645833334}, {"start": 2915.98, "end": 2916.66, "word": " تروحوا", "probability": 0.86761474609375}, {"start": 2916.66, "end": 2917.18, "word": " و", "probability": 0.54736328125}, {"start": 2917.18, "end": 2917.72, "word": " تبحثوا", "probability": 0.9901123046875}, {"start": 2917.72, "end": 2917.84, "word": " في", "probability": 0.9248046875}, {"start": 2917.84, "end": 2918.46, "word": " الانترنت", "probability": 0.837353515625}, {"start": 2918.46, "end": 2918.64, "word": " و", "probability": 0.6357421875}, {"start": 2918.64, "end": 2919.04, "word": " تشوفوا", "probability": 0.9967041015625}, {"start": 2919.04, "end": 2919.66, "word": " قداش", "probability": 0.8107096354166666}, {"start": 2919.66, "end": 2920.44, "word": " أو", "probability": 0.67333984375}, {"start": 2920.44, "end": 2920.62, "word": " في", "probability": 0.96728515625}, {"start": 2920.62, "end": 2920.98, "word": " الكتب", "probability": 0.9851888020833334}, {"start": 2920.98, "end": 2921.56, "word": " العلمية", "probability": 0.9943033854166666}, {"start": 2921.56, "end": 2922.06, "word": " طبعا", "probability": 0.9879150390625}, {"start": 2922.06, "end": 2923.02, "word": " الفرق", "probability": 0.88330078125}, {"start": 2923.02, "end": 2923.26, "word": " ما", "probability": 0.966796875}, {"start": 2923.26, "end": 2923.76, "word": " بين", "probability": 0.98388671875}], "temperature": 1.0}, {"id": 121, "seek": 294650, "start": 2924.28, "end": 2946.5, "text": "الـ Synthetic detergents المنظفات الصناعية و ما بين الصابون العادى لمن الزيت وين الفرق؟ و المرة الجاية إذا صار فرصة ممكن نحكي في الموضوع أو نخلي حد منكم يحكينا في الموضوع الفرق ما بين الصابون العادى و المنظفات الصناعية ماشي؟", "tokens": [6027, 39184, 318, 18656, 3532, 15092, 70, 791, 9673, 1863, 19913, 5172, 9307, 31767, 8315, 3615, 10632, 4032, 19446, 49374, 31767, 16758, 11536, 18863, 18513, 7578, 5296, 27842, 6024, 110, 36081, 4032, 9957, 27188, 2288, 4587, 22807, 4032, 9673, 25720, 25724, 995, 10632, 11933, 15730, 20328, 9640, 6156, 2288, 9381, 3660, 3714, 43020, 8717, 5016, 4117, 1829, 8978, 9673, 2407, 11242, 45367, 34051, 8717, 9778, 20292, 11331, 3215, 9154, 24793, 7251, 5016, 4117, 1829, 8315, 8978, 9673, 2407, 11242, 45367, 27188, 2288, 4587, 19446, 49374, 31767, 16758, 11536, 18863, 18513, 7578, 4032, 9673, 1863, 19913, 5172, 9307, 31767, 8315, 3615, 10632, 3714, 33599, 1829, 22807], "avg_logprob": -0.14777417171676205, "compression_ratio": 1.989795918367347, "no_speech_prob": 0.0, "words": [{"start": 2924.28, "end": 2924.68, "word": "الـ", "probability": 0.44189453125}, {"start": 2924.68, "end": 2925.34, "word": " Synthetic", "probability": 0.841796875}, {"start": 2925.34, "end": 2926.46, "word": " detergents", "probability": 0.776611328125}, {"start": 2926.46, "end": 2927.34, "word": " المنظفات", "probability": 0.91533203125}, {"start": 2927.34, "end": 2928.16, "word": " الصناعية", "probability": 0.993408203125}, {"start": 2928.16, "end": 2928.68, "word": " و", "probability": 0.8408203125}, {"start": 2928.68, "end": 2928.76, "word": " ما", "probability": 0.241943359375}, {"start": 2928.76, "end": 2929.24, "word": " بين", "probability": 0.9931640625}, {"start": 2929.24, "end": 2930.42, "word": " الصابون", "probability": 0.919921875}, {"start": 2930.42, "end": 2930.98, "word": " العادى", "probability": 0.9103190104166666}, {"start": 2930.98, "end": 2931.34, "word": " لمن", "probability": 0.661376953125}, {"start": 2931.34, "end": 2931.76, "word": " الزيت", "probability": 0.9422200520833334}, {"start": 2931.76, "end": 2932.0, "word": " وين", "probability": 0.487060546875}, {"start": 2932.0, "end": 2932.94, "word": " الفرق؟", "probability": 0.85546875}, {"start": 2932.94, "end": 2933.16, "word": " و", "probability": 0.69775390625}, {"start": 2933.16, "end": 2933.48, "word": " المرة", "probability": 0.886962890625}, {"start": 2933.48, "end": 2933.86, "word": " الجاية", "probability": 0.8157552083333334}, {"start": 2933.86, "end": 2934.08, "word": " إذا", "probability": 0.746826171875}, {"start": 2934.08, "end": 2934.34, "word": " صار", "probability": 0.79248046875}, {"start": 2934.34, "end": 2934.74, "word": " فرصة", "probability": 0.9940185546875}, {"start": 2934.74, "end": 2935.04, "word": " ممكن", "probability": 0.96240234375}, {"start": 2935.04, "end": 2935.62, "word": " نحكي", "probability": 0.994140625}, {"start": 2935.62, "end": 2936.12, "word": " في", "probability": 0.90478515625}, {"start": 2936.12, "end": 2936.62, "word": " الموضوع", "probability": 0.998291015625}, {"start": 2936.62, "end": 2936.76, "word": " أو", "probability": 0.81396484375}, {"start": 2936.76, "end": 2937.16, "word": " نخلي", "probability": 0.9371744791666666}, {"start": 2937.16, "end": 2937.42, "word": " حد", "probability": 0.98046875}, {"start": 2937.42, "end": 2937.78, "word": " منكم", "probability": 0.8525390625}, {"start": 2937.78, "end": 2938.42, "word": " يحكينا", "probability": 0.90712890625}, {"start": 2938.42, "end": 2938.58, "word": " في", "probability": 0.9755859375}, {"start": 2938.58, "end": 2939.02, "word": " الموضوع", "probability": 0.9979248046875}, {"start": 2939.02, "end": 2939.5, "word": " الفرق", "probability": 0.9462890625}, {"start": 2939.5, "end": 2939.74, "word": " ما", "probability": 0.97119140625}, {"start": 2939.74, "end": 2940.1, "word": " بين", "probability": 0.99267578125}, {"start": 2940.1, "end": 2941.24, "word": " الصابون", "probability": 0.9921875}, {"start": 2941.24, "end": 2942.6, "word": " العادى", "probability": 0.8629557291666666}, {"start": 2942.6, "end": 2942.78, "word": " و", "probability": 0.7412109375}, {"start": 2942.78, "end": 2943.92, "word": " المنظفات", "probability": 0.98837890625}, {"start": 2943.92, "end": 2945.5, "word": " الصناعية", "probability": 0.9969482421875}, {"start": 2945.5, "end": 2946.5, "word": " ماشي؟", "probability": 0.82861328125}], "temperature": 1.0}, {"id": 122, "seek": 297249, "start": 2969.31, "end": 2972.49, "text": "Tricloroethanol لما نقارنه مع ال Tricloroethanol", "tokens": [51, 1341, 6746, 78, 3293, 282, 401, 5296, 15042, 8717, 4587, 9640, 1863, 3224, 20449, 2423, 314, 1341, 6746, 78, 3293, 282, 401], "avg_logprob": -0.3180338479578495, "compression_ratio": 1.0892857142857142, "no_speech_prob": 6.890296936035156e-05, "words": [{"start": 2969.31, "end": 2970.17, "word": "Tricloroethanol", "probability": 0.7595912388392857}, {"start": 2970.17, "end": 2970.55, "word": " لما", "probability": 0.55218505859375}, {"start": 2970.55, "end": 2971.03, "word": " نقارنه", "probability": 0.914453125}, {"start": 2971.03, "end": 2971.13, "word": " مع", "probability": 0.87548828125}, {"start": 2971.13, "end": 2971.25, "word": " ال", "probability": 0.484619140625}, {"start": 2971.25, "end": 2972.49, "word": " Tricloroethanol", "probability": 0.8610491071428571}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2974.38325, "duration_after_vad": 2853.677843749991}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1e9b0d2e1f4234f6c5140d70448dfcd943edc1d7
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/bv1DEtNB8GQ_raw.srt
@@ -0,0 +1,2072 @@
+1
+00:00:08,680 --> 00:00:13,980
+بسم الله الرحمن الرحيم اليوم بنكمل ان شاء الله في
+
+2
+00:00:13,980 --> 00:00:17,700
+موضوع مشتقات الأحماض المرة الماضية أخدنا فكرة عن
+
+3
+00:00:17,700 --> 00:00:23,100
+الأحماض ويمكن فكرة عامة عن المشتقات بشكل عام
+
+4
+00:00:23,100 --> 00:00:28,730
+تحضيرها اليوم بنتوسع أكثر في هذا الموضوعالمشتقة
+
+5
+00:00:28,730 --> 00:00:35,290
+الأولى للأحماض اللى هى ال E Stars واضح لما نتطلع
+
+6
+00:00:35,290 --> 00:00:39,230
+على شكل أي E Star لما نتطلع على شكل أي E Star
+
+7
+00:00:39,230 --> 00:00:46,230
+بنلاحظ أنه ال E Star بتكون من شقينبتكون من شق من
+
+8
+00:00:46,230 --> 00:00:50,550
+الحامض و شق من الكحول و هو عادة بتحضر التفاعل
+
+9
+00:00:50,550 --> 00:00:54,550
+الحامض و الكحول فمثلا لو بدى أطلع على ال Easter
+
+10
+00:00:54,550 --> 00:00:58,510
+اللى موجود عندى بلاحظ أنه عندى الشق اللى فيه C
+
+11
+00:00:58,510 --> 00:00:59,630
+double bond O
+
+12
+00:01:09,010 --> 00:01:14,010
+الشق التاني اللي مكون من تلت كربونات كانوا متصلين
+
+13
+00:01:14,010 --> 00:01:20,020
+بأكسجين هو الكحول البروبانولالان لما هدولة بدوا
+
+14
+00:01:20,020 --> 00:01:26,260
+يعملوا E star، ال E star اسمه بده يبين فيه الشقين،
+
+15
+00:01:26,260 --> 00:01:31,660
+شق الكحول و شق الحامض، عادة بتتم التسمية بهذا
+
+16
+00:01:31,660 --> 00:01:37,500
+الشكل، بنشوف ايش اسم المجموعة تبعت الكحوللما يكون
+
+17
+00:01:37,500 --> 00:01:42,300
+عندى تلت ذرات كربون المجموعة اسمها Eprobil Eprobil
+
+18
+00:01:42,300 --> 00:01:48,220
+و الحامض ابيوتانووك أسد بنستبدل كلمة ابيوتانووك
+
+19
+00:01:48,220 --> 00:01:53,340
+أسد ببيوتانويت فبصير كل هذا اسمه Eprobil
+
+20
+00:01:53,340 --> 00:02:00,620
+ابيوتانويت Eprobil اللى هو شغق الالكول وبيوتانويت
+
+21
+00:02:00,620 --> 00:02:05,860
+اللى هو شغق الديستر طبعا هنا بيكون شبيه بتسمية
+
+22
+00:02:05,860 --> 00:02:10,310
+الأيوناتالسالبة لأن ال أيونات السالبة إحنا اتفقنا
+
+23
+00:02:10,310 --> 00:02:19,150
+إننا بنسميها بالنهاية it الان لو بدنا نطلع على بعض
+
+24
+00:02:19,150 --> 00:02:25,520
+الأمثلة حتى نأكد طريقة التسميةأهم شيء .. أهم شيء
+
+25
+00:02:25,520 --> 00:02:32,420
+كنت أحدده جزء الكحول و جزء الكحول هو الجزء المتصل
+
+26
+00:02:32,420 --> 00:02:36,340
+بالـ O هذه الميثير ده بدون السيطة من bond O يعني
+
+27
+00:02:36,340 --> 00:02:39,280
+لو في كل هدولة قبل ما أشتغل بتقول إيش هو جزء
+
+28
+00:02:39,280 --> 00:02:44,560
+الكحول؟ هنا الميثل، هذه جاية من الميثانول، هنا
+
+29
+00:02:44,560 --> 00:02:46,960
+الاثل
+
+30
+00:02:48,900 --> 00:02:52,780
+مرة تانية مثل الجزء التاني اللي فيه صيغة و point O
+
+31
+00:02:52,780 --> 00:02:59,040
+هو جزء الحامض هنا الفنل
+
+32
+00:02:59,040 --> 00:03:09,060
+هنا مثل الآن هذا شق الألكول عادة احنا بنكتب اسم
+
+33
+00:03:09,060 --> 00:03:12,860
+المجموعة تبعته و بنسيب فراغ بعدها فبهذه الحالة
+
+34
+00:03:12,860 --> 00:03:19,640
+بنقول مثل الآن الحامض اللي من carbon 10أسيتك أسد
+
+35
+00:03:19,640 --> 00:03:26,100
+فبصير المركب مثل أسيتيت لو كنت بدي بالأيوبك المطلق
+
+36
+00:03:26,100 --> 00:03:32,420
+أثانوك أسد بدي يصير مثل أثانويت واضح نفس الفكرة
+
+37
+00:03:32,420 --> 00:03:40,500
+هنا اثل و كربونتين اذا أسيتك أسد اثل أسيتيت لو كنت
+
+38
+00:03:40,500 --> 00:03:44,820
+بتطلع المركب اللي بعده مثل كربونتين تلاتة أربعة
+
+39
+00:03:44,820 --> 00:03:52,740
+هيصير مثلبيوتانويت مثل بيوتانويت لما بدي أجي أطلع
+
+40
+00:03:52,740 --> 00:03:57,300
+هنا هذه المجموعة البنزين لما تكون جاية كمجموعة
+
+41
+00:03:57,300 --> 00:04:04,200
+اسمها فنل فنل وهذا كربونتين من الاسيتك أسيت حيزير
+
+42
+00:04:04,200 --> 00:04:11,380
+فنل أسيتيت فنل أسيتيت واضح؟ لو بدي أطلع هنا هذه
+
+43
+00:04:11,380 --> 00:04:18,100
+مثل و البنزين مع مجموعة الحامض اسمهبنزويك أسد
+
+44
+00:04:18,100 --> 00:04:23,540
+فبتصير كلها مثل بنزويت واضح؟ لاحظوا مثل هدول
+
+45
+00:04:23,540 --> 00:04:28,840
+المركبين ربما تلاحظوا نوعا ما شبه بينهم و أحيانا
+
+46
+00:04:28,840 --> 00:04:33,540
+كتيرة لما بنسأل سؤال الطلاب بيخربوا التنين في بعض
+
+47
+00:04:33,540 --> 00:04:37,680
+يعني ممكن يسموا هذا مثلا فين الأسيتين أو يسموا هذا
+
+48
+00:04:37,680 --> 00:04:43,040
+مثل بنزويت فبيلزم الانتباه أن الجزء اللي بيذكر في
+
+49
+00:04:43,040 --> 00:04:49,000
+الأول هو جزءالألكوهول الجزء المتصل بالأكسجين من
+
+50
+00:04:49,000 --> 00:04:54,720
+خلال single bond والجزء التاني هو جزء ال acid فهنا
+
+51
+00:04:54,720 --> 00:05:00,420
+هذه فينيل و ال acid هو ايش؟ acidic acid يعني حتى
+
+52
+00:05:00,420 --> 00:05:04,220
+لو قلنا لكم كيف بدنا نحضر هذا المركب على سبيل
+
+53
+00:05:04,220 --> 00:05:08,060
+المثال بتكون ال acid اللي تحضروا منه يكون ال
+
+54
+00:05:08,060 --> 00:05:13,630
+acidic acid والألكوهول يكونالفينول بينما لو بنقول
+
+55
+00:05:13,630 --> 00:05:18,010
+هذا كيف بدنا نحضر المركب بدنا بنزويك أسيت وهذا
+
+56
+00:05:18,010 --> 00:05:24,770
+بيكون الميثانول واضح فهذا الكلام بحاجة إلى انتباه
+
+57
+00:05:24,770 --> 00:05:30,850
+وباعتقد بهذا الشكل تسمية تسمية ال E-stars تسمية
+
+58
+00:05:30,850 --> 00:05:36,270
+سهلة طبعا ربما بتلاحظوا هنا انه احنا أخدنا تسمية
+
+59
+00:05:36,270 --> 00:05:40,390
+ال E-stars بدونSubstituents
+
+60
+00:06:12,740 --> 00:06:18,960
+Ethane واضح؟ الآن لاحظوا هنا الحقيقة في عندي
+
+61
+00:06:18,960 --> 00:06:26,160
+Easter سيضة بال bond O OR وفي عندي كيتون سيضة بال
+
+62
+00:06:26,160 --> 00:06:32,480
+bond O الأولوية لمين بتكون ال Easter علشان هيك هذا
+
+63
+00:06:32,480 --> 00:06:38,720
+كاسم هيكون فيه Ethane في البداية دائمااللي هو جزء
+
+64
+00:06:38,720 --> 00:06:42,640
+ال alcohol و اللي بدي يكون في البداية بعدين بعد
+
+65
+00:06:42,640 --> 00:06:48,100
+الحامض ابتداء من السيطب ال point O واحد اتنين
+
+66
+00:06:48,100 --> 00:06:57,320
+تلاتة اربعة واضح؟ الآن هذا الحامض عبارة عن ايش؟
+
+67
+00:06:57,320 --> 00:07:03,400
+بيوتانويك اسد لما بدي يصير Easter بيوتانويت هذا ال
+
+68
+00:07:03,400 --> 00:07:10,540
+بيوتانويت شو بيحمل مجموعات؟Chlorine و Oxygen اذا
+
+69
+00:07:10,540 --> 00:07:16,300
+لما انا بدي اسميه هقول Ethyl انسيب فراغ Two
+
+70
+00:07:16,300 --> 00:07:29,800
+Chlorine Three Oxygen بيوتنويت يعني
+
+71
+00:07:29,800 --> 00:07:34,380
+كأنه ال Easter Ethyl بيوتنويت و هدول ال
+
+72
+00:07:34,380 --> 00:07:39,980
+substituents ذكرناهمواضح ال E star مثل بيوتانويت
+
+73
+00:07:39,980 --> 00:07:46,980
+وبنذكر ال substituents الآن بدنا واحدة بشكل كامل
+
+74
+00:07:46,980 --> 00:07:54,540
+تسمينا المركب اللي بعده ولو
+
+75
+00:07:54,540 --> 00:07:59,000
+يبدو كبير بس مافيش اشي صعب Systematic بشكل متدرج
+
+76
+00:07:59,000 --> 00:08:05,630
+تفضلي شكلك حابة تسميهجارتك أشطر منك تفضلي ايس
+
+77
+00:08:05,630 --> 00:08:12,170
+المجموعة تبع ال alcohol؟ هذه المجموعة ال isopropyl
+
+78
+00:08:12,170 --> 00:08:18,450
+كويس؟ الآن باجي على جزء الحامض بشوف كم كربونا قبل
+
+79
+00:08:18,450 --> 00:08:23,720
+انتبهوا معايادائما و أبدا .. دائما و أبدا لا تبدأ
+
+80
+00:08:23,720 --> 00:08:27,620
+بـ 2-hydroxy أنا لم أضع أرقام ولا حددت الحامض ..
+
+81
+00:08:27,620 --> 00:08:30,960
+ماذا يعرفني انها 2-hydroxy او 3-hydroxy التسمية
+
+82
+00:08:30,960 --> 00:08:35,340
+دائما و أبدا تبدأ من الخلف للأمام .. لكي تحددوا
+
+83
+00:08:35,340 --> 00:08:39,420
+الـhydroxy هذي وين .. ماذا يلزمك في الأول؟ تريد ان
+
+84
+00:08:39,420 --> 00:08:43,660
+تعرف كم كربونا عندك؟ اتحددني هنا .. ماهو الحامض
+
+85
+00:08:43,660 --> 00:08:44,620
+أساسا .. 1
+
+86
+00:08:47,550 --> 00:08:55,630
+تلاتة أربعة خمسة ستة إذا أنا أمام هكسانويك أسد في
+
+87
+00:08:55,630 --> 00:09:00,590
+ال Easter هيصير هكسانويل شو اللي متفرع من هذا
+
+88
+00:09:00,590 --> 00:09:07,570
+الهكسانويك أسد مثل
+
+89
+00:09:07,570 --> 00:09:16,480
+و مثل و هيدروكسيواضح؟ إذا كأنه لو أنا بدي أسمي هذا
+
+90
+00:09:16,480 --> 00:09:25,200
+ك E star بدون المجموعات بدي أقول isopropyl وفي
+
+91
+00:09:25,200 --> 00:09:28,900
+الآخر هيكون عنده hexanoate
+
+92
+00:09:30,740 --> 00:09:33,340
+أيزو برو بالهجسانويت يعني لو شيلت كل هدول
+
+93
+00:09:33,340 --> 00:09:37,220
+المجموعات ايزو برو بالهجسانويت من الأخطاء الدارجة
+
+94
+00:09:37,220 --> 00:09:40,760
+للأسف الشديد انه كتير بعد ما يسموا بروحوا بيسموا
+
+95
+00:09:40,760 --> 00:09:46,060
+هذه أوكزو هذه جزء من ال Easter ال C double bond O
+
+96
+00:09:46,060 --> 00:09:52,040
+O بلقيهم كاتبين لكلمة أوكزو هي جزء من ال Easterما
+
+97
+00:09:52,040 --> 00:09:56,080
+بتاخدش اشي لحالها بينما لو كانت واحدة تانية بعيد
+
+98
+00:09:56,080 --> 00:09:59,200
+عنها هانا السيدة من البندقه هذي جزء من ال Easter
+
+99
+00:09:59,200 --> 00:10:03,500
+هذي زيادة سميناها اقزو بس هانا مابنشيش نقول one
+
+100
+00:10:03,500 --> 00:10:07,860
+اقزو كتير بنلاحظ انه كاتبين هذي one اقزو هذي جزء
+
+101
+00:10:07,860 --> 00:10:15,220
+من ال Easter ايش اللي موجود عندك؟ اتفضلي من اللي
+
+102
+00:10:15,220 --> 00:10:23,910
+بتكمل؟ سامعيني طيب اه ال three fiveDimethyl-4
+
+103
+00:10:23,910 --> 00:10:27,990
+-hydroxy لحظوا ال Easter إيه له أولوية على إيش؟
+
+104
+00:10:27,990 --> 00:10:35,090
+على ال alcohol إذا أنا عندي three five dimethyl
+
+105
+00:10:35,090 --> 00:10:43,050
+four hydroxyhexanoate
+
+106
+00:10:43,050 --> 00:10:47,750
+كلمة واحدةلاحظوا الفراغ الوحيد اللي موجود بين كلمة
+
+107
+00:10:47,750 --> 00:10:51,470
+isopropyl و هذه المجموعة بيقول isopropyl فراغ
+
+108
+00:10:51,470 --> 00:10:54,410
+هدولة كلهم كلمة واحدة يعني لو على الكمبيوتر
+
+109
+00:10:54,410 --> 00:10:58,890
+بتكتبوا المفروض ولا فراغ تسيبوا كلهم متصل ببعض و
+
+110
+00:10:58,890 --> 00:11:08,690
+بدون ولا فراغ 3,5-dimethyl 4-hydroxyhexanoate ماشي
+
+111
+00:11:08,690 --> 00:11:11,830
+طيب
+
+112
+00:11:11,830 --> 00:11:19,870
+وانا سميةيلا اذا
+
+113
+00:11:19,870 --> 00:11:28,490
+هذا مثل ايش الحامض اربع
+
+114
+00:11:28,490 --> 00:11:32,730
+ذرات كربون بيوتان
+
+115
+00:11:32,730 --> 00:11:40,770
+و ويت ايه جاله double bond ايش حيصير بيوتين و ويت
+
+116
+00:11:40,770 --> 00:11:43,610
+ال double bond بحاجة الى ايش
+
+117
+00:11:49,710 --> 00:11:55,170
+لو اتشت هانا او هانا اذا بتاخد مواقع ال double
+
+118
+00:11:55,170 --> 00:12:00,910
+bond لازم احدد نقطة البداية تبعتها اعطينا عدي
+
+119
+00:12:00,910 --> 00:12:05,070
+الاسم كامل مثل
+
+120
+00:12:05,070 --> 00:12:08,330
+تو
+
+121
+00:12:08,330 --> 00:12:11,730
+بيوتين
+
+122
+00:12:11,730 --> 00:12:20,050
+اويتلاحظوا الـ two هذه عشان تحدد لي وين موقع تلقين
+
+123
+00:12:20,050 --> 00:12:28,150
+مثل two بيوتين قوات حددت لي وين موقع ال double
+
+124
+00:12:28,150 --> 00:12:35,510
+bond حددت لي وين موقع ال double bond ماشي اه الآن
+
+125
+00:12:35,510 --> 00:12:40,090
+بدك تسميه تفضلي شو اسمك انت مروة
+
+126
+00:12:41,060 --> 00:12:46,320
+ماروة أبو دالو تفضلي ماروة أبو دالو تفضلي هنا إيش
+
+127
+00:12:46,320 --> 00:12:51,980
+المجموعات اللي عندك؟ اللي تحت؟ ماشي ابن عم اللي
+
+128
+00:12:51,980 --> 00:13:02,580
+فوق إيش اللي عندك؟ تفضلي الإثل هو جزء الكحول خمسة
+
+129
+00:13:02,580 --> 00:13:07,140
+تفضلي
+
+130
+00:13:07,140 --> 00:13:15,680
+إيش هنسميه؟ إثل؟ايوة اتل
+
+131
+00:13:15,680 --> 00:13:23,980
+تو بنتين حطينا البنتين هدى عشان تقوليله triple
+
+132
+00:13:23,980 --> 00:13:35,260
+point اويت مش ات اويت اتل تو بنتين اويت اتل تو
+
+133
+00:13:35,260 --> 00:13:44,760
+بنتين اويت واضح؟ ممتازيلا يا شايماء،
+
+134
+00:13:44,760 --> 00:13:49,120
+إيش المجموعتين الوظيفيات اللي هنا، حتى يترسخ مبدأ
+
+135
+00:13:49,120 --> 00:13:53,640
+التفاضل؟
+
+136
+00:13:53,640 --> 00:13:58,680
+هذا Easter، Easter وAldehyde، الأولوية لمين؟
+
+137
+00:13:58,680 --> 00:14:01,240
+للإيستر، و الجزء اللي للكل؟
+
+138
+00:14:09,080 --> 00:14:19,760
+فنل ثري اقزو ابروفانويت واضح
+
+139
+00:14:19,760 --> 00:14:26,120
+فنل ثري اقزو ابروفانويت زي ما بتلاحظوا طبعا انه
+
+140
+00:14:26,120 --> 00:14:32,030
+لما بنحلل تسمية المراكبات العضوية ليست صعبةليش؟
+
+141
+00:14:32,030 --> 00:14:38,030
+لأن هذه IUPAC، إيش معنى IUPAC؟ إنه بتمشي على قواعد
+
+142
+00:14:38,030 --> 00:14:42,530
+مضطردة، المشكلة أحيانا اللي بتواجه الناس في ال
+
+143
+00:14:42,530 --> 00:14:47,360
+common namesالـ Common Names هي اللي ممكن تواجه
+
+144
+00:14:47,360 --> 00:14:51,820
+الناس إنهم مش عارفين و الله هذا ال common name شو
+
+145
+00:14:51,820 --> 00:14:56,240
+هو لما نقول glutaric acid فاتشها في المخ شولك ..
+
+146
+00:14:56,240 --> 00:15:00,640
+واضح؟ لكن التسمية اللي بتمشي على قواعد مضطردة ليست
+
+147
+00:15:00,640 --> 00:15:01,800
+صعبة
+
+148
+00:15:22,990 --> 00:15:27,670
+طبعا اكدنا و بنود نذكر انه من ال A stars كيف
+
+149
+00:15:27,670 --> 00:15:32,410
+بتحضروا من تفاعل ال substitution للاحماض
+
+150
+00:15:32,410 --> 00:15:37,870
+الكربوكسيلية ال alcohol بيهاجم على الحامض و بيطرد
+
+151
+00:15:39,110 --> 00:15:43,410
+الـ OH و بيصير عند ال E star نفس الاشي هنا alcohol
+
+152
+00:15:43,410 --> 00:15:48,390
+بيهاجم على الحامض و بيطرد ال OH هذا تأكيد بس ان ال
+
+153
+00:15:48,390 --> 00:15:53,410
+E star من alcohol و من حامض و ان التفاعل هذا هجوم
+
+154
+00:15:53,410 --> 00:15:58,110
+و خروج هو تفاعل substitution لما نيجي نقولكوا ان
+
+155
+00:15:58,110 --> 00:16:03,870
+ال main reaction of E stars is substitution او ال
+
+156
+00:16:03,870 --> 00:16:09,070
+assets او كل المشتقات هذه substitutionاستخدم يكل
+
+157
+00:16:09,070 --> 00:16:15,010
+البلاد؟ اكيد، اكيد، اكيد، مش minus بس عليها زوج
+
+158
+00:16:15,010 --> 00:16:18,330
+electronic، ال neutral ال neutral
+
+159
+00:16:22,140 --> 00:16:27,100
+يعني اللي بدها Easter إيش بدها تعمل كحول و حامض بس
+
+160
+00:16:27,100 --> 00:16:30,440
+طبعا لاحظوا هنا في لقطة دائما بتجينا في الموضوع
+
+161
+00:16:30,440 --> 00:16:36,060
+إنه حقيقة هذا تفاعل ال Easter هو تفاعل التزان يعني
+
+162
+00:16:36,060 --> 00:16:41,200
+بيضال عند الحامض مع الكحول مع ال Easter مع الميه
+
+163
+00:16:41,200 --> 00:16:45,700
+الآن لما بدنا يمشي أكتر باتجاه تكوين ال Easter
+
+164
+00:16:45,700 --> 00:16:52,170
+بنستعمل أي مبدأ في الكيميانستعمل مبدأ لتشاتليلة
+
+165
+00:16:52,170 --> 00:16:56,170
+لحرف الإتزال طب كيف بتدخل ال Easter يطلع بشكل
+
+166
+00:16:56,170 --> 00:17:05,990
+كبير؟ بنزيد تركيز متفاعل هنا أو بشيل
+
+167
+00:17:05,990 --> 00:17:11,120
+واحد من هناك، شو اللي بدنا نشيله عادة؟المية يعني
+
+168
+00:17:11,120 --> 00:17:15,840
+بيكونوا عاملين التفاعل بطريقة يسحبوا المية فكل ما
+
+169
+00:17:15,840 --> 00:17:19,860
+بيسحبوا المية التفاعل بيظل يمشي بهذا الاتجاه فممكن
+
+170
+00:17:19,860 --> 00:17:23,400
+نمشي حتى النهاية حسب قاعدة Le Chatelet أنه أنا لما
+
+171
+00:17:23,400 --> 00:17:29,160
+بشيل متفاعل من هنا بوجه الإتزان لتعديل التفاعل مرة
+
+172
+00:17:29,160 --> 00:17:34,280
+أخرى واضح هذا من الأشياء المعروفة
+
+173
+00:17:36,590 --> 00:17:43,550
+الان هال easters سويانة كلها التعب نص
+
+174
+00:17:43,550 --> 00:17:50,050
+عيلنا في ال easters الجواب اه ليش لان ال easters
+
+175
+00:17:50,050 --> 00:17:57,640
+مواد ذات روائحعطرية و ذات طعم و ما إلى ذلك والدليل
+
+176
+00:17:57,640 --> 00:18:01,860
+على هيك إذا أنتوا بتكونوا تشوفوا كل أنواع الفواكه
+
+177
+00:18:01,860 --> 00:18:07,240
+الروائح تبعتها الجميلة هي عبارة عن Easter's هي
+
+178
+00:18:07,240 --> 00:18:11,480
+عبارة عن Easter's فمثلا هذا ال Easter الأول اللي
+
+179
+00:18:11,480 --> 00:18:17,540
+هو مثل بيوتانويت هو Easter التفاح في ريحة إيش؟
+
+180
+00:18:18,020 --> 00:18:23,000
+الطفاح ال Easter التاني اللي هو مثل ثيو مثل ثيو
+
+181
+00:18:23,000 --> 00:18:29,660
+لما تكون S متصلة ب مثل بتعرفوا sulfur ثيو مثل ثيو
+
+182
+00:18:29,660 --> 00:18:38,140
+CH3S مثل ثيو بيوتانويت هذا Easter الفراولة ال
+
+183
+00:18:38,140 --> 00:18:43,760
+strawberry الآن هذا ال Easter اللي بيكبر شوية اثل
+
+184
+00:18:43,760 --> 00:18:47,020
+بيوتانويت Easter
+
+185
+00:18:49,320 --> 00:18:55,440
+البني بالز الاناناس Easter الاناناس اه وهذا ال
+
+186
+00:18:55,440 --> 00:19:00,020
+Easter اللي هو فيه بنتي الخمس ذرات كربون مع بيوتها
+
+187
+00:19:00,020 --> 00:19:07,100
+نويت Easter اه
+
+188
+00:19:07,100 --> 00:19:12,820
+جامر الدينليش؟ هو جمر الدين من إيش بيجيبوه؟ مش من
+
+189
+00:19:12,820 --> 00:19:18,380
+المشمش، هو الخلاصة أو العصير تبع المشمش و بيجففوه
+
+190
+00:19:18,380 --> 00:19:22,620
+جمر الدين الابريكوت .. ابريكوت بالالماني شو
+
+191
+00:19:22,620 --> 00:19:28,140
+بيقولوله؟ Apricosenمش مش واضح فلهذا السبب ال
+
+192
+00:19:28,140 --> 00:19:30,940
+Easter's مهمة وكتير من الروائح اللي بيحطوها
+
+193
+00:19:30,940 --> 00:19:36,020
+بالتوفي وما إلى ذلك هي روائح Easter's الان مثل هذه
+
+194
+00:19:36,020 --> 00:19:40,760
+ال Easter's في تجربة عملية بسيطة الطلاب ممكن
+
+195
+00:19:40,760 --> 00:19:46,300
+ياخدوا في المختبر مثلا ال methanol مع ال butanoic
+
+196
+00:19:46,300 --> 00:19:50,510
+acidو يسخلوهم شوية صغيرة في test tube و يعمل زي
+
+197
+00:19:50,510 --> 00:19:55,290
+هيك شم بشم ريحة التفاح او ريحة الفراولة او
+
+198
+00:19:55,290 --> 00:20:03,570
+الاناناس بسهولة يعني ممكن نحضر هذه المركبات واضح؟
+
+199
+00:20:03,570 --> 00:20:11,530
+الان احنا اتفقنا ال Easter عبارة عن ايش؟كحول و
+
+200
+00:20:11,530 --> 00:20:17,070
+Acid ايش ماله؟ كحول و Acid الان لما اجيب انا كحول
+
+201
+00:20:17,070 --> 00:20:20,210
+من هنا و Acid من هنا و يتفاعلوا و يعملوا ال Easter
+
+202
+00:20:20,210 --> 00:20:24,790
+هذا التفاعل بنقول عنه Intermolecular reaction هو
+
+203
+00:20:24,790 --> 00:20:29,850
+تفاعل بين جزء من هنا و جزء تاني من هنا ممكن في
+
+204
+00:20:29,850 --> 00:20:37,590
+جزيئات معينة اكون ال alcohol و الحامض بنفس الجزيئة
+
+205
+00:20:38,830 --> 00:20:42,770
+وبالتالي التفاعل يتم في داخل الجزء اللي بنسميه
+
+206
+00:20:42,770 --> 00:20:47,350
+Intramolecular reaction مثلا لو اتطلعنا على هذا
+
+207
+00:20:47,350 --> 00:20:55,340
+المركب1,2,3,4 إذا هذا بيوتانويك أسد هذا
+
+208
+00:20:55,340 --> 00:21:00,120
+البيوتانويك أسد على موقع أربعة شو موجود عليه
+
+209
+00:21:00,120 --> 00:21:07,440
+هيدروكسي four hydroxy butanoic acid لما أجي أسخنه
+
+210
+00:21:07,440 --> 00:21:13,720
+في وجود حامض بيعطيني cyclic esterلحظوا هذا ال
+
+211
+00:21:13,720 --> 00:21:17,540
+Easter Cyclic طبعا مرات لما يكون مرسومي بهذا الشكل
+
+212
+00:21:17,540 --> 00:21:23,340
+بيغلبكم لكن ممكن نفس المركب يكون رسمي و احنا سيضة
+
+213
+00:21:23,340 --> 00:21:31,140
+بال bond O OH هي carbon تنتين تلاتة اربعة واحد
+
+214
+00:21:31,140 --> 00:21:39,860
+اتنين تلاتة اربعة و انا عندك ال OH هذا نفس المركب1
+
+215
+00:21:39,860 --> 00:21:44,740
+,2,3,4,4 هيدروكسيبيوتانوك أسد الان عندما أثخن يعمل
+
+216
+00:21:44,740 --> 00:21:53,940
+ال E star الكحول سيهاجم هنا و سيطرد ال O H و بعدها
+
+217
+00:21:53,940 --> 00:21:58,380
+ستفقد ال H لأن ال O H مع ال H من هنا سيصبح ميه إذا
+
+218
+00:21:58,380 --> 00:22:03,550
+أعطاني في هذه الحالة Cyclic E starأعطاني في هذه
+
+219
+00:22:03,550 --> 00:22:07,550
+الحالة Cyclic Easter أكيد ال reaction هو عبارة عن
+
+220
+00:22:07,550 --> 00:22:13,370
+Intramolecular إيش يعني Intramolecular ان الجزئين
+
+221
+00:22:13,370 --> 00:22:16,990
+اللي متفاعلوا موجودين في داخل جزئ واحد يعني ما
+
+222
+00:22:16,990 --> 00:22:22,720
+استعملتش جزئينواضح؟ ما استعملتش جزيئين مجموعة
+
+223
+00:22:22,720 --> 00:22:27,160
+الكحول و مجموعة الحامض موجودة في جزئ واحد، ماجيبتش
+
+224
+00:22:27,160 --> 00:22:32,700
+الكحول من جزئ و الحامض من جزئ تاني فبيعطونا اللي
+
+225
+00:22:32,700 --> 00:22:37,540
+هو ال cyclic esters، C double bond O موجودة جوا
+
+226
+00:22:37,540 --> 00:22:44,040
+cycle أو جوا حلقة هذه ال cyclic esters كعائلة
+
+227
+00:22:44,040 --> 00:22:51,310
+بيسموها lactonesواضح؟ الـ Cyclic E Stars كعائلة
+
+228
+00:22:51,310 --> 00:22:55,230
+بيسموها Lactones كيف بعرف إنه هذه عائلة اللاكتون؟
+
+229
+00:22:55,230 --> 00:22:58,650
+كيف بعرف إنه هذه عائلة اللاكتون؟ بدي أشوف C double
+
+230
+00:22:58,650 --> 00:23:03,810
+bond O و جنبها O في داخل حلقة، إذا هذه العائلة
+
+231
+00:23:03,810 --> 00:23:09,670
+كعائلة بيكون اسمها إيش؟ Lactone واضح؟بكون اسمها
+
+232
+00:23:09,670 --> 00:23:15,250
+lactone طبعا عشان الأمور اللي ضالها متذكرينها
+
+233
+00:23:15,250 --> 00:23:20,570
+انتوا بالمقارنة الحقيقية ممكن يكون عندى غير ال
+
+234
+00:23:20,570 --> 00:23:24,910
+cyclic ester اللي هي اسم عائلة lactone ممكن يكون
+
+235
+00:23:24,910 --> 00:23:29,150
+عندى cyclic amide ايش ال cyclic amide
+
+236
+00:23:36,810 --> 00:23:40,970
+لأن C double bond O N في مركب مفتوح أمد لما تصير
+
+237
+00:23:40,970 --> 00:23:44,430
+في حلقة طبعا غالبا بتكون N H او اش ما كان يكون
+
+238
+00:23:44,430 --> 00:23:47,990
+بتصير Cyclic Amide اذا انا في عندى في الدنيا
+
+239
+00:23:47,990 --> 00:23:54,410
+Cyclic E star C double bond O O و Cyclic Amide C
+
+240
+00:23:54,410 --> 00:23:59,930
+double bond O N عائلة ال Cyclic E stars ايش اسمها
+
+241
+00:23:59,930 --> 00:24:06,090
+Lactones طب عائلة ال Cyclic Amides شو اسمها
+
+242
+00:24:08,600 --> 00:24:14,000
+Lactam عشان الإسمين زي بعض ماتخربوش بينهم مرات
+
+243
+00:24:14,000 --> 00:24:18,880
+بتجروا lactone و مرات بتجروا lactam فلو إجينا بدنا
+
+244
+00:24:18,880 --> 00:24:23,580
+نسألكوا سؤال صح و غلط نقولكم lactams are cyclic
+
+245
+00:24:23,580 --> 00:24:30,640
+esters lactams are cyclic amides lactons are
+
+246
+00:24:30,640 --> 00:24:38,860
+cyclic esters ال lactons هم اللي عبارة عنEasters
+
+247
+00:24:38,860 --> 00:24:45,800
+طبعا ال lactams هذه الحقيقة مهمة كتير ال lactams
+
+248
+00:24:45,800 --> 00:24:53,220
+مهمة كتير ليش؟ لأنه من أهم عائلات الأدوية بالذات
+
+249
+00:24:53,220 --> 00:24:58,220
+للي بيدرسوا تحاليل طبية زي جزء كبير منكم عائلة
+
+250
+00:24:58,220 --> 00:25:04,680
+بيقولولها ال beta lactams إذا عمركم سمعتوا beta
+
+251
+00:25:04,680 --> 00:25:11,070
+lactamsهذه ال beta lactams مهمة جدا جدا جدا
+
+252
+00:25:11,070 --> 00:25:16,130
+فبتلاقوا مكتوب عنوان كامل و كتب كاملة و أبحاث
+
+253
+00:25:16,130 --> 00:25:20,330
+كاملة اشي اسمه beta lactam antibiotics
+
+254
+00:25:23,580 --> 00:25:29,040
+Antibiotics هي عائلة مضادات حيوية وهي تحديدا عائلة
+
+255
+00:25:29,040 --> 00:25:34,280
+البنسالين ومشتقاته البنسالين والسفلوسبورين وكل هذه
+
+256
+00:25:34,280 --> 00:25:40,400
+العائلة بيكون فيهامع c double bond o في حلقة
+
+257
+00:25:40,400 --> 00:25:44,940
+رباعية طبعا ليش بيقولوا beta إذا أنا قلت هاي
+
+258
+00:25:44,940 --> 00:25:48,280
+الموضوع alpha بعد c double bond o هاي الموضوع beta
+
+259
+00:25:48,280 --> 00:25:52,520
+هاي alpha هاي beta فال nitrogen اللي هنا متصل في
+
+260
+00:25:52,520 --> 00:25:57,960
+أي موقع في beta بالنسبة للحمض الأصلي طبعا هنا في
+
+261
+00:25:57,960 --> 00:26:03,480
+عائلة البنسالين في عائلة البنسالين بيكون مع الحلقة
+
+262
+00:26:03,480 --> 00:26:09,400
+الرباعية هذه حلقة خماسيةيعني هذا الإطار العام لشكل
+
+263
+00:26:09,400 --> 00:26:14,580
+أدوية البنسالين واضح؟ الآن طوروا البنسالين ..
+
+264
+00:26:14,580 --> 00:26:18,980
+طوروا البنسالين للعائلات التانية الـ cephalosporin
+
+265
+00:26:18,980 --> 00:26:24,420
+والمضادات الحيوية الجديدة مع الحلقة الربعية صار
+
+266
+00:26:24,420 --> 00:26:30,120
+يحطوا حلقة إيش؟سداسية الاصل البنسلي الحلقة
+
+267
+00:26:30,120 --> 00:26:36,520
+الرباعية وخماسية طوروا ضالت هذه رباعية وهذه سداسية
+
+268
+00:26:36,520 --> 00:26:41,760
+ودائما عندهم قناعة ان الحلقة الرباعية لا مفر من
+
+269
+00:26:41,760 --> 00:26:45,840
+وجودها عشان هذه المضادات الحيوية تكون بتشتغل
+
+270
+00:26:45,840 --> 00:26:49,820
+الحلقة الخماسية مش مشكلة ممكن تصير سداسية وممكن
+
+271
+00:26:49,820 --> 00:26:54,260
+تكون مش حلقة بس الأساس في هذول المضادات الحيوية
+
+272
+00:26:54,260 --> 00:26:58,860
+كلهم ايشالحلقة الربعية وعشان هيك بنقول انه عندنا
+
+273
+00:26:58,860 --> 00:27:03,440
+عائلة كاملة من المضادات الحيوية اللي هي بيسموها ال
+
+274
+00:27:03,440 --> 00:27:09,240
+beta-lactam antibiotics اللي هي عائلة البنسالين
+
+275
+00:27:09,240 --> 00:27:13,960
+وأجياله ومشتقاته طبعا هنا انتبهوا لو كنتوا بتكون
+
+276
+00:27:13,960 --> 00:27:20,060
+تتطلعوا على اللاكتون هنا مثلا Alpha Beta Delta
+
+277
+00:27:20,060 --> 00:27:27,960
+Gamma نسميه Gamma Lactoneألفة بيتا جامعة هاي
+
+278
+00:27:27,960 --> 00:27:34,200
+الألفة هاي البيتا هاي الجامعة ال O جاية وين؟ جامعة
+
+279
+00:27:34,200 --> 00:27:42,460
+واضح؟ هيك احنا بنعد من ال C ضب ال point O تبعت
+
+280
+00:27:42,460 --> 00:27:46,640
+الحامض من بعدها لو كنا بنرقم في الأحمض من وين
+
+281
+00:27:46,640 --> 00:27:53,330
+بنرقم؟بنرقم من عند الـ C double bond O لكن لما
+
+282
+00:27:53,330 --> 00:28:00,130
+بنستعمل نظام Alpha و Beta من وان بنستعملها؟ من بعد
+
+283
+00:28:00,130 --> 00:28:01,870
+الـ C double bond O
+
+284
+00:28:05,460 --> 00:28:10,280
+على سبيل المثال ال amino acids الأحماض الأمينية ال
+
+285
+00:28:10,280 --> 00:28:14,480
+amino acids لما تاخدوا حامض زي هيك C double bond O
+
+286
+00:28:14,480 --> 00:28:19,440
+أو H وهنا تحطوا C بغض النظر إيش حاملة نفترض H و
+
+287
+00:28:19,440 --> 00:28:27,680
+حاملة R وهنا NH2 هذه العائلة شو بيسموها amino O
+
+288
+00:28:27,680 --> 00:28:35,210
+acid الآن هي ال alpha عشان هيك هذه بيسموهاالألفة
+
+289
+00:28:35,210 --> 00:28:40,330
+أمينو أسد اللي هي الألفة أمينو أسد اللي بتكون
+
+290
+00:28:40,330 --> 00:28:45,410
+لبروتينات الآن وقت إيش بتكون بيتا لو حطيت كمان
+
+291
+00:28:45,410 --> 00:28:50,310
+كربونا بعد الألفة والأمينو إجت عليها بيصير بيتا
+
+292
+00:28:50,310 --> 00:28:54,950
+أمينو أسد طبعا الأحماض الأمينية المكونة لبروتينات
+
+293
+00:28:54,950 --> 00:28:58,750
+في جسم الإنسان المشهورة
+
+294
+00:28:59,300 --> 00:29:02,240
+كلها عبارة عن أي نوع من الـ Amino Acids Alpha
+
+295
+00:29:02,240 --> 00:29:07,220
+بمعنى أن الـ Amino على أول كربونا بعد الكربونيل
+
+296
+00:29:07,220 --> 00:29:15,580
+group لكن لو كنت برقم وين واحد؟ اتنين هنا واضح؟ و
+
+297
+00:29:15,580 --> 00:29:20,600
+هذا الكلام السبق إن حكينا فيه فمافيش داعي نرد إن
+
+298
+00:29:20,600 --> 00:29:27,790
+هيالان هي انا امثلة و مكتوب اسمها بهمناش تحفظوا
+
+299
+00:29:27,790 --> 00:29:30,810
+اسمها بس حتى تكونوا بالصورة في مراكبات ذات
+
+300
+00:29:30,810 --> 00:29:37,290
+استعمالات و كلها عبارة عن ايش؟ كلها عبارة عن
+
+301
+00:29:37,290 --> 00:29:42,030
+lactones كل هذه المراكبات عبارة عن lactones ويلها
+
+302
+00:29:42,030 --> 00:29:48,530
+تطبيقات في الحياة بنجي
+
+303
+00:29:48,530 --> 00:29:59,610
+لموضوع الحقيقة مهم كتيرموضوع مهم كتير أن الزيوت
+
+304
+00:29:59,610 --> 00:30:05,670
+اللي هو الزيت و كمان بيجي زيه السمنة و الفات و ال
+
+305
+00:30:05,670 --> 00:30:11,930
+lipids و ما إلى ذلك هم عبارة عن .. بنسميهم ال tri
+
+306
+00:30:11,930 --> 00:30:17,370
+-glycerides أسترز of إجليسارين
+
+307
+00:30:18,400 --> 00:30:23,800
+يعني ال glycerin اللي بتعرفوه ال glycerin اللي
+
+308
+00:30:23,800 --> 00:30:27,400
+بيحطوه بيرطب الأيدين و ما إلى ذلك هو المركبة ده
+
+309
+00:30:27,400 --> 00:30:35,560
+اللي في تلت مجموعات OHs CH2OH CHOH CH2OH هذا عبارة
+
+310
+00:30:35,560 --> 00:30:43,000
+عن إيش؟ ال glycerin أو ال glycerol الآن هذا ال
+
+311
+00:30:43,000 --> 00:30:46,560
+glycerin لو تخيلته أنه بدنا نفعله مع حامض، لو
+
+312
+00:30:46,560 --> 00:30:50,720
+تخيلته أنه بدنا نفعله مع حامض، بنحضر ال Easter بس
+
+313
+00:30:50,720 --> 00:30:54,940
+بيكون عندى كام Easter؟التلاتة يعني هي أنا حامض
+
+314
+00:30:54,940 --> 00:30:59,900
+متصل ب OH تاعة alcohol و أنا حامض متصل ب OH تاعة
+
+315
+00:30:59,900 --> 00:31:04,340
+alcohol و أنا حامض متصل ب OH تاعة alcohol التلاتة
+
+316
+00:31:04,340 --> 00:31:07,840
+موجودين في جزء واحد ال OHS اللي هو جزء ال glycerin
+
+317
+00:31:07,840 --> 00:31:12,720
+عشانك هذه المركبات احنا بنسميها ال tri glycerides
+
+318
+00:31:12,720 --> 00:31:18,180
+هذا هو الزيت او السيرج او زيت الزيتون طب ايش بيفرق
+
+319
+00:31:18,180 --> 00:31:24,570
+زيت عن زيت؟يعني لما نقول زيرج، عباد الشمس، عن زيت
+
+320
+00:31:24,570 --> 00:31:29,270
+الصوية، عن زيت الزيتون، إيش بيفرجوا عن بعض؟ عن زيت
+
+321
+00:31:29,270 --> 00:31:37,450
+النخيل؟ بيفرجوا في الـR group اللي هنا هذه الـR
+
+322
+00:31:37,450 --> 00:31:42,290
+ممكن تكون في التلاتة نفس الأشياء وممكن تكون مختلفة
+
+323
+00:31:42,290 --> 00:31:47,030
+وغالبا هي سلسلة طويلة
+
+324
+00:31:48,700 --> 00:31:54,060
+ممكن تكون مشبعة مافيش فيها double bonds و ممكن
+
+325
+00:31:54,060 --> 00:32:00,680
+تكون فيها double bonds واضح؟ طبعا الزيوت اللي عادة
+
+326
+00:32:00,680 --> 00:32:07,050
+فيها double bonds بتكون سائلة ولا صلبة؟سائلة لما
+
+327
+00:32:07,050 --> 00:32:11,290
+يكون عندى double bonds بتكون الزيوت سائلة بنعمل
+
+328
+00:32:11,290 --> 00:32:15,610
+لها هدرجة سمعتوا عن هدرجة الزيوت؟ يعني بنحطها
+
+329
+00:32:15,610 --> 00:32:19,870
+هيدروجين بنلغط double bonds في هذه الحالة الزيوت
+
+330
+00:32:19,870 --> 00:32:24,190
+بتتحول إلى أيش؟ إلى زيوت صلبة اللى هي السمنة و
+
+331
+00:32:24,190 --> 00:32:29,110
+المارجرين و ما إلى ذلك يعني السمنة من وين في الآخر
+
+332
+00:32:29,110 --> 00:32:33,830
+بيجيبوها؟من الزيوت من السيرج وزيت عبادى الشمس
+
+333
+00:32:33,830 --> 00:32:37,790
+وغيره وغيرته بال هدرجة بيكون في عند double bonds
+
+334
+00:32:37,790 --> 00:32:44,150
+بألغى ال double bonds فبتحول الزيت السائل إلى زيت
+
+335
+00:32:44,150 --> 00:32:50,930
+صلب الآن هذه الزيوت كمان بيحضروا منها شغلة تانية
+
+336
+00:32:50,930 --> 00:32:57,540
+بيحضروا منها الصابونالصوب بيحضروا من الزيوت
+
+337
+00:32:57,540 --> 00:33:01,620
+الصابون مش دايما بنقول احنا الصابون النابولسي
+
+338
+00:33:01,620 --> 00:33:07,920
+بيحضروا من زيت الزيتون كيف بيحضروا الصابون من
+
+339
+00:33:07,920 --> 00:33:12,120
+الزيوت؟ بيجوا بيفعلوها مع ال sodium hydroxide
+
+340
+00:33:12,120 --> 00:33:16,900
+بشوية تسخين بيعملوا hydrolysis لهذا الزيت بيكسروا
+
+341
+00:33:16,900 --> 00:33:22,190
+من هنافبيطلع عندنا ال glycerin ال glycerin مش هو
+
+342
+00:33:22,190 --> 00:33:28,650
+فيت القصيد زائد ملح للأحماض بديش أنا أنسى أنه هذه
+
+343
+00:33:28,650 --> 00:33:33,030
+الأحماض أحماض أشمالها كبيرة fatty acids يعني مش
+
+344
+00:33:33,030 --> 00:33:36,970
+كربونتين تلاتة أربع طعش ست عشر تمن طعش فانتوا
+
+345
+00:33:36,970 --> 00:33:43,050
+تخيلوا هذا الحامض انه بهذا الشكل ست عشر كربونا مع
+
+346
+00:33:43,050 --> 00:33:48,840
+سيضة بالبندق O O minusالان هذه هي الصابونة
+
+347
+00:33:48,840 --> 00:33:54,620
+الصابونة زي ما بتلاحظوا مكونه من ايش؟ من شكلتين
+
+348
+00:33:54,620 --> 00:34:00,400
+الجزء اللي فيه ال minus هذا polar ولا non polar؟
+
+349
+00:34:00,400 --> 00:34:06,240
+polar bar و الجزء اللي فيه السلسلة الألفتية
+
+350
+00:34:06,240 --> 00:34:12,860
+الطويلةنان بولر إذا الصابون مكوّن من جزءين من
+
+351
+00:34:12,860 --> 00:34:18,380
+polar part و non polar part الفتك تشين طويلة 16
+
+352
+00:34:18,380 --> 00:34:23,360
+كربونا 18 كربونا هذه non polar والطرف أو الرأس
+
+353
+00:34:23,360 --> 00:34:30,360
+تبعه C double bond O O minus هذا الجزء polar الآن
+
+354
+00:34:30,360 --> 00:34:32,320
+كيف عد الصابون
+
+355
+00:34:35,560 --> 00:34:45,320
+بيقوم بعمله في التنظيف الصبون بنظف إيش؟ آه لازم
+
+356
+00:34:45,320 --> 00:34:50,840
+تكونوا عارفين يعني لو حد إيجي على إيديه سكر سكر
+
+357
+00:34:50,840 --> 00:34:54,560
+ميه و عليها سكر و ماء إلى ذلك مابلازمش يروح يغسل
+
+358
+00:34:54,560 --> 00:34:59,000
+بالصبون الصبون غالي اليوم الهواي ب 2.5 شكل بكفي
+
+359
+00:34:59,000 --> 00:35:05,480
+ميهالمية بتنظف السكر السكر بولر والمية بولر بولر
+
+360
+00:35:05,480 --> 00:35:08,660
+بدوب في بولر خلصنا المية بتنظف السكر بلزمش اروح
+
+361
+00:35:08,660 --> 00:35:12,660
+اغسل من السكر ايجي على ايدي بالصابون مافيش لزوم
+
+362
+00:35:12,660 --> 00:35:18,520
+الصابون لتنظيف ايش الدهون كيف بتتم عملية التنظيف
+
+363
+00:35:18,520 --> 00:35:23,920
+هذا الجزء اللي هو ال non-polar والدهون non-polar
+
+364
+00:35:23,920 --> 00:35:29,730
+والقاعدة العامةlike dissolve like فالدهون غير
+
+365
+00:35:29,730 --> 00:35:35,210
+القطبية ال non polar بتدوب فى هذا الجزء الطويل تبع
+
+366
+00:35:35,210 --> 00:35:40,450
+الزيت بدوبها بيحوط هذا الجزء الطويل اللى هو ال
+
+367
+00:35:40,450 --> 00:35:44,350
+chain او ال non polar part بيحوط نقطة الدهن او
+
+368
+00:35:44,350 --> 00:35:49,630
+الزيت و بعدين بتعمل اشي بنسميه كورا mycel و بتنزل
+
+369
+00:35:49,630 --> 00:35:55,620
+مع الميه وهى تحمل فى داخلهانقطة إيش الدهون زي ما
+
+370
+00:35:55,620 --> 00:36:01,340
+انتوا شايفين هنا في هذا المثال كيف بيشتغل الصابون
+
+371
+00:36:01,340 --> 00:36:06,000
+كيف بيشتغل الصابون هاي الجزء ال bowler هذا الجزء
+
+372
+00:36:06,000 --> 00:36:11,020
+ال bowler كله بيحمل شحنات سالبة بيصير للخارج هذه
+
+373
+00:36:11,020 --> 00:36:15,520
+البردجانية اللي في النص هي عبارة عن إيش هذه نقطة
+
+374
+00:36:15,520 --> 00:36:22,030
+الفاتأو الدهن اللي مدوبة في أطراف الـ non polar
+
+375
+00:36:22,030 --> 00:36:28,760
+part تبع الصبونواضح؟ فالصابون بدوّب نقطة الزيت في
+
+376
+00:36:28,760 --> 00:36:33,700
+الجزء غير القطب منه هذه كلها بتكون طبعا متنافرة مع
+
+377
+00:36:33,700 --> 00:36:36,880
+بعضها لإنها minus minus minus بتعمل اللي بنسميه
+
+378
+00:36:36,880 --> 00:36:42,340
+الميسل هذه بتصير زي كرة بتنزل وكل واحد بيغسل بتكون
+
+379
+00:36:42,340 --> 00:36:46,380
+الدهن في قلب هذه الكرة و بنفصله عن الميه و بنزله
+
+380
+00:36:46,380 --> 00:36:53,330
+مع إيش؟ مع الغسيل اللي هو الزيت مداب فيالـ non
+
+381
+00:36:53,330 --> 00:36:59,990
+-polar part تبع الصبون، واضح؟ هذا بالنسبة له
+
+382
+00:36:59,990 --> 00:37:05,170
+الصبون اللي هي جاية في الأساس من إيستر و الإيستر
+
+383
+00:37:05,170 --> 00:37:13,790
+هو إيش؟ الزيت، الإيستر هو الزيت نعم،
+
+384
+00:37:13,790 --> 00:37:20,430
+ما هي زي نفس الفكرة، هي زيت مهدرج بالصبون؟ لا،
+
+385
+00:37:20,430 --> 00:37:26,210
+بيكون الصبون كخربانلأ لأ لأ مش ممكن الصابون مضيعش
+
+386
+00:37:26,210 --> 00:37:32,970
+السمنة مش ممكن الصابون بضيع السمنة الصابون أكيد
+
+387
+00:37:32,970 --> 00:37:38,170
+بضيع السمنة بدون نقاش الآن خليكم معنا قبل ما نروح
+
+388
+00:37:38,170 --> 00:37:42,750
+على الكيميا شوية تفاعل مع green yard reagent احنا
+
+389
+00:37:42,750 --> 00:37:49,110
+ال seerage هذا او الزيت كان لنا تجربة قاسية معاه
+
+390
+00:37:49,110 --> 00:37:51,470
+وقتاش
+
+391
+00:37:53,280 --> 00:38:01,220
+أيام الحصار، بتذكروا لما السيارات صاروا يعبوا سيرش
+
+392
+00:38:01,220 --> 00:38:07,640
+سيارات المرسيدس و يشتغلوا عليه، إيش صار مع الناس؟
+
+393
+00:38:07,640 --> 00:38:17,700
+انخنجوامتذكرين ولا لأ؟ الناس لما صاروا يحطوا
+
+394
+00:38:17,700 --> 00:38:21,680
+searage .. يحطوا searage في motor السيارة و يشغلوا
+
+395
+00:38:21,680 --> 00:38:25,980
+السيارة الناس انخنقت طب ليش الناس صار عندها
+
+396
+00:38:25,980 --> 00:38:30,160
+الاختناق؟ ليش الناس صار عندها الاختناق؟ لسبب بسيط
+
+397
+00:38:30,160 --> 00:38:35,400
+انه هذا الزيت .. انه هذا الزيت بالتسخين ..
+
+398
+00:38:35,400 --> 00:38:38,300
+بالتسخين .. احنا أنا بطلنا مش حاطين bass احنا كلنا
+
+399
+00:38:38,300 --> 00:38:43,300
+حاطينحرارة اشتعال نحطه في الموتور نولعه إيش اللي
+
+400
+00:38:43,300 --> 00:38:48,300
+بيولع في الزيت أساساً اللي بيولع بالزيت هو هذا
+
+401
+00:38:48,300 --> 00:38:54,580
+الجزء اللي هو الالفاتيك بس مابدناش ننسى هانا نقطة
+
+402
+00:38:54,580 --> 00:39:01,420
+إنه الزيت مكوّن من جزءين جزء لجليسرين و الجزء
+
+403
+00:39:01,420 --> 00:39:09,120
+الالفاتيك الآن اللي بيصلح كوقود fuel هو هذا الجزء
+
+404
+00:39:10,110 --> 00:39:16,810
+الأليفاتيك والجليساريل هو المصيبة اللى كانت تطلع
+
+405
+00:39:16,810 --> 00:39:23,010
+الرائحة فالرائحة أصلها من وين؟ من الجليساريل انه
+
+406
+00:39:23,010 --> 00:39:27,550
+الجليساريل بالحرارة بيفقد جزيئين ميه بيعطينا مركب
+
+407
+00:39:27,550 --> 00:39:33,070
+زي هيك السيطة بالبوند او اللى هو هذا الديهيد اللى
+
+408
+00:39:33,070 --> 00:39:41,210
+بنسميه اكريلديهيد هذا بالإش بطلعبالتسخين Acryl
+
+409
+00:39:41,210 --> 00:39:49,070
+Aldehyde واضح؟ هذا الجزء من أين جاية الرائحة؟ من
+
+410
+00:39:49,070 --> 00:39:52,810
+الجلسريل الجزء التاني هو اللي بيولع اللي فيه آر
+
+411
+00:39:52,810 --> 00:39:56,550
+كبيرة ما أنتوا ما تنسوش برضه أنه البنزين السيارة
+
+412
+00:39:56,550 --> 00:40:02,690
+أساسا هو عبارة عن إيش؟ مشوال كيل؟ لأ لأ شوف C6H6
+
+413
+00:40:02,690 --> 00:40:08,640
+الفيول اللي هو الجازولين بنسميهالجازولين تبع
+
+414
+00:40:08,640 --> 00:40:14,840
+السيارة أو البنزين هو عبارة عن إيش؟ مش هو عبارة عن
+
+415
+00:40:14,840 --> 00:40:21,080
+سلسلة ألكين خليط من الهبتين واحد، اتنين، تلات،
+
+416
+00:40:21,080 --> 00:40:27,400
+أربعة، خمسة، ستة، سبعة هبتين و Iso-Octane، هاي
+
+417
+00:40:27,400 --> 00:40:35,720
+مجموعة ال I's وهنا، وعدّه1,2,3,4,5,6,7,8 ايزو
+
+418
+00:40:35,720 --> 00:40:41,880
+اكتين مع هبتين بيعطينا ايش؟ بيعطينا الجازولين او
+
+419
+00:40:41,880 --> 00:40:45,300
+الوقود اللي احنا بنستعمله بنزين السيارات خليط من
+
+420
+00:40:45,300 --> 00:40:49,440
+الهبتين والايزو اكتين والايزو اكتين بنحط بنسبة
+
+421
+00:40:49,440 --> 00:40:55,150
+معينة وعشانك بيصير عندى رقم الاكتين واضح؟مش فيه
+
+422
+00:40:55,150 --> 00:40:58,970
+عندى بنزين تسعين و بنزين خمسة وتسعين و إذا اختل
+
+423
+00:40:58,970 --> 00:41:02,730
+البنزين بيصير خبط في الموتور و ما إلى ذلك ال
+
+424
+00:41:02,730 --> 00:41:06,430
+knocking فالجازولين هو عبارة عن aliphatic compound
+
+425
+00:41:06,430 --> 00:41:10,890
+الان هذا الجزء ال aliphatic اللي بيولع نفسه موجود
+
+426
+00:41:10,890 --> 00:41:17,580
+وين؟ في ال Easterالأليفاتيك بيولع و ال E star
+
+427
+00:41:17,580 --> 00:41:24,500
+بيولع و بيعطي طاقة و لذلك يمكن أن يستعمل ال E star
+
+428
+00:41:24,500 --> 00:41:29,280
+كوقود المشكلة وين بتصير؟
+
+429
+00:41:31,640 --> 00:41:36,100
+المشكلة بتصير من الـ acrylaldehyde من الريحة يعني
+
+430
+00:41:36,100 --> 00:41:40,540
+لما استعمل كوقود السيارات كانت تمشي طبيعي بس كانت
+
+431
+00:41:40,540 --> 00:41:45,900
+مشكلة الناس من الروائح اللي بتطلع اللي هي رائحة
+
+432
+00:41:45,900 --> 00:41:50,240
+الـ acrylaldehyde الآن هذه المشكلة مالهاش حل علمي
+
+433
+00:41:50,240 --> 00:41:57,200
+مش بإمكاني الآن أنا أجيب زيوت و أحولها إلى وقود
+
+434
+00:41:58,590 --> 00:42:03,390
+العالم شغال على هذا الكلام و بيحضروا اشي بيسموه
+
+435
+00:42:03,390 --> 00:42:10,150
+biodiesel الديزل الحيوي هنا في ال .. في الوقود،
+
+436
+00:42:10,150 --> 00:42:15,510
+بتتميزوا بين شغلتين، بين اشي بنسميه bio fuel
+
+437
+00:42:15,510 --> 00:42:21,570
+الوقود الحيوي و بين biodiesel
+
+438
+00:42:27,240 --> 00:42:31,080
+البيوفيول أول ما بدوا كانوا ياخدوا الاثانول
+
+439
+00:42:31,080 --> 00:42:36,760
+الاثانول بيولع ولا لأ؟ اللي هو ال ethyl-OH من وين
+
+440
+00:42:36,760 --> 00:42:42,330
+بيجيبوا الاثانول؟من الدورة و تخمورها و ما إلى ذلك
+
+441
+00:42:42,330 --> 00:42:46,450
+صاروا يزرعوا نص أمريكا و غيرها و غيراتها دورة و
+
+442
+00:42:46,450 --> 00:42:49,630
+يحولوا لإيثانول و الإيثانول بتمشي عليه السيارات
+
+443
+00:42:49,630 --> 00:42:54,750
+بدون أي مشكلة زمان كان كل بيت صغير عشان يعمل الصبح
+
+444
+00:42:54,750 --> 00:43:02,330
+فنجان جهوب يكون عنده إيش بابور إسبيرتو كنا نشتري
+
+445
+00:43:02,330 --> 00:43:05,810
+الإسبيرتو بجزازة و يكون بابور صغير هالجد إله في
+
+446
+00:43:05,810 --> 00:43:08,410
+طيلة يمكن الآن صار من الذكريات
+
+447
+00:43:10,700 --> 00:43:14,780
+أيوة بابور هيك صغير وهنا إله فتيلة، هذا كان يتعبى
+
+448
+00:43:14,780 --> 00:43:19,920
+Spirto إيثانول، كل دار كان عنده بابور Spirto،
+
+449
+00:43:19,920 --> 00:43:22,400
+بيعملوا عليه في انجان الجهوز الصبح لأنه بيولع
+
+450
+00:43:22,400 --> 00:43:28,320
+بإيش؟ بسهولة، فالإيثانول وقود، هذا bio fuel، لكن
+
+451
+00:43:28,320 --> 00:43:33,700
+إيش قصة ال biodiesel؟ايش قصة الـBiodiesel اللي
+
+452
+00:43:33,700 --> 00:43:37,220
+اليوم العالم شغالين عليه بشكل كبير؟ و لو
+
+453
+00:43:37,220 --> 00:43:42,640
+معلوماتكوا، بالـ2008 و بالـ2009 طيّرت Airbus
+
+454
+00:43:44,990 --> 00:43:49,710
+طائرات على الـ biodiesel مخلوط طبعا بوقود عادي
+
+455
+00:43:49,710 --> 00:43:55,270
+يعني شوفوا كذا رحلة عملوها رحلات تجربية طيرت طائرة
+
+456
+00:43:55,270 --> 00:43:59,750
+باستعمال ال biodiesel طب إيش بيعملوا في ال
+
+457
+00:43:59,750 --> 00:44:05,010
+biodiesel اللي بيعملوا في ال biodiesel بييجوا لهذا
+
+458
+00:44:05,010 --> 00:44:10,090
+الزيت طبعا مابياخدوش زيت يؤكل في أشجار معينة زي
+
+459
+00:44:10,090 --> 00:44:15,580
+القطروفة والنخيل زيوت بيسموها non edibleيعني زيوت
+
+460
+00:44:15,580 --> 00:44:19,120
+غير مأكولة بدل ما ياخدوا الزيت اللي بتاكل فيه
+
+461
+00:44:19,120 --> 00:44:23,600
+نبتات صحراوية و بتطلع زيت كتير بياخدوا هذا الزيت و
+
+462
+00:44:23,600 --> 00:44:30,100
+بيفعلون افترض مع الاثانول اثل او اتش ايش بديه يعمل
+
+463
+00:44:30,100 --> 00:44:36,380
+الاثانول هذا Easter بيهاجم هناوبيطرد هذا الجزء
+
+464
+00:44:36,380 --> 00:44:40,760
+لاحظوا بيبدل Easter ب Easter وعشان هي هذه العملية
+
+465
+00:44:40,760 --> 00:44:43,920
+بيسموها الاشي اللي بيبدل .. شو بنقول عنه
+
+466
+00:44:43,920 --> 00:44:50,140
+بالإنجليزي؟ اللي بيبدل الكهربا Trans .. Trans
+
+467
+00:44:50,140 --> 00:44:55,500
+فالعملية بيسموها Trans Sterification
+
+468
+00:45:07,630 --> 00:45:18,020
+تراستيرفيكشن تراستيرفيكشنأو اثل اثل
+
+469
+00:45:18,020 --> 00:45:22,500
+اثل
+
+470
+00:45:22,500 --> 00:45:24,100
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+471
+00:45:24,100 --> 00:45:24,100
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+472
+00:45:24,100 --> 00:45:24,140
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+473
+00:45:24,140 --> 00:45:24,960
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+474
+00:45:24,960 --> 00:45:25,160
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+475
+00:45:25,160 --> 00:45:33,380
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+476
+00:45:35,420 --> 00:45:39,620
+لكن ماباخدش الزيت مباشرة يعني الفرق بين العالم
+
+477
+00:45:39,620 --> 00:45:43,520
+اللي بيشتغل صح و اللي عندنا حرجوا الـ searage ان
+
+478
+00:45:43,520 --> 00:45:49,440
+اللي عندنا أخدوا هذا الزيت زي ما هو و سخنوه زي ما
+
+479
+00:45:49,440 --> 00:45:52,860
+هو فطلع المادة السامة اللي هي الـ acrylaldehyde
+
+480
+00:45:52,860 --> 00:45:57,000
+نتيجة حرق ال glycerin العالم لأ العالم بيقول ليش
+
+481
+00:45:57,000 --> 00:46:02,840
+أنا أخسر ال glycerin نمرا واحد و نمرا اتنين أحرجه
+
+482
+00:46:02,840 --> 00:46:09,470
+و أطلع منه رائحةسيئ أو irritant يعني بتشعط كلكوا
+
+483
+00:46:09,470 --> 00:46:13,710
+جربته يمكن كيف التجربة كانت سيئة قالوا لأ بنفعله
+
+484
+00:46:13,710 --> 00:46:18,450
+مع الاثانول بيعطينا E star زاد غليسارين الآن احنا
+
+485
+00:46:18,450 --> 00:46:24,410
+في بالراحة بنفصل الغليسارين لحاله بناخده و بنستعمل
+
+486
+00:46:24,410 --> 00:46:29,290
+استعمالاته المعهودة و بناخد هذه ال E stars اللي
+
+487
+00:46:29,290 --> 00:46:33,750
+فيها سلاسل طويلة و بنحطها في السيارات والطيارات
+
+488
+00:46:34,330 --> 00:46:38,970
+وبتشتغل كويس هذا هو ال biodiesel فال biodiesel
+
+489
+00:46:38,970 --> 00:46:44,290
+فكرته مش بعيدة كتير عن اللي عملوه الناس عندنا لكن
+
+490
+00:46:44,290 --> 00:46:49,770
+الناس عندنا أخدوا الزيت بكامله ب .. زي ما قال مين
+
+491
+00:46:49,770 --> 00:46:56,590
+طه حسين ولا مين علينا أن نأخد الثقافة الغربية
+
+492
+00:46:56,590 --> 00:47:04,760
+بحلوها ومرها انضرنا لأنهنتاج حرق الجليسرين كان
+
+493
+00:47:04,760 --> 00:47:11,460
+بضرنا بينما لما أخذوا حلوها صار biodiesel ومرها
+
+494
+00:47:11,460 --> 00:47:17,380
+برضه الجليسرين استفدنا منه في الصناعات الدوائية و
+
+495
+00:47:17,380 --> 00:47:20,300
+بنضاف على الشامبو و إشي مشكل الشامبوهات و غير و
+
+496
+00:47:20,300 --> 00:47:24,140
+غيراته بتلاقوا مكتوب عليها بالجليسرين بالجليسرين
+
+497
+00:47:24,140 --> 00:47:30,300
+واضح فاستفادوا بهذا الشكل و عملوا اللي هي بيسموها
+
+498
+00:47:30,300 --> 00:47:37,070
+ال biodieselالان يمكن يظل عندنا موضوع بس مش الآن
+
+499
+00:47:37,070 --> 00:47:40,190
+هأحكي عنه بس بكون مبسوط إذا انتوا روحتوا جيبتوا
+
+500
+00:47:40,190 --> 00:47:47,590
+معلومات عنه أنه الصابونة من الزيت، مظبوط؟ طب اليوم
+
+501
+00:47:47,590 --> 00:47:52,510
+الصوابين اللي موجودة هل هي من الزيت؟ اللي بنسميها
+
+502
+00:47:52,510 --> 00:47:58,010
+synthetic detergents المنظفات الصناعية الجديدة هذه
+
+503
+00:47:58,010 --> 00:48:01,730
+والصوابين وإشي ولا إفرجة شوية صغيرة؟
+
+504
+00:48:04,480 --> 00:48:08,380
+أفرجتي شوية صغيرة عن أنها تكون من الزيت بالمناسبة
+
+505
+00:48:08,380 --> 00:48:12,120
+صابونة الزيت زي صابونة الشكعة النبولسية وما إلى
+
+506
+00:48:12,120 --> 00:48:17,580
+ذلك على مية غزة المية المالحة اللي بنسميها ال hard
+
+507
+00:48:17,580 --> 00:48:22,500
+water ما بترغيش بالمرة الماء العصربينما اليوم
+
+508
+00:48:22,500 --> 00:48:26,420
+الصوابين بنجيبلها أملح ميه في الدنيا زي ميه البحر
+
+509
+00:48:26,420 --> 00:48:29,980
+بتجيبولنا إياها بترغي الصابونة ولا لأ؟ هذه مش
+
+510
+00:48:29,980 --> 00:48:34,740
+صابونة من الزيوت هذه صابونة صناعية بصير السؤال
+
+511
+00:48:34,740 --> 00:48:40,440
+بتقدر تروحوا و تبحثوا في الانترنت و تشوفوا قداش أو
+
+512
+00:48:40,440 --> 00:48:45,340
+في الكتب العلمية طبعا الفرق ما بينالـ Synthetic
+
+513
+00:48:45,340 --> 00:48:50,420
+detergents المنظفات الصناعية و ما بين الصابون
+
+514
+00:48:50,420 --> 00:48:54,340
+العادى لمن الزيت وين الفرق؟ و المرة الجاية إذا صار
+
+515
+00:48:54,340 --> 00:48:58,420
+فرصة ممكن نحكي في الموضوع أو نخلي حد منكم يحكينا
+
+516
+00:48:58,420 --> 00:49:03,920
+في الموضوع الفرق ما بين الصابون العادى و المنظفات
+
+517
+00:49:03,920 --> 00:49:06,500
+الصناعية ماشي؟
+
+518
+00:49:29,310 --> 00:49:32,490
+Tricloroethanol لما نقارنه مع ال Tricloroethanol
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..6cff19a4eb7b2a496f2c2399c6ee422ed97894da
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2816, "start": 9.38, "end": 28.16, "text": "بسم الله الرحمن الرحيم بنكمل اليوم ان شاء الله في موضوع ال alkanes وسنتطرق في هذه المحاضرة إلى ال cycle alkanes اللي هي المركبات الحلقية التي تحتوي على روابط أحدية", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 4724, 1863, 24793, 1211, 45595, 20498, 16472, 13412, 16606, 21984, 8978, 3714, 2407, 11242, 45367, 2423, 419, 5225, 279, 46952, 29399, 9566, 2288, 4587, 8978, 29538, 9673, 5016, 46958, 25720, 30731, 2423, 6586, 419, 5225, 279, 13672, 1829, 39896, 9673, 31747, 3555, 9307, 21542, 1211, 4587, 10632, 38392, 6055, 33753, 45865, 15844, 12602, 14407, 3555, 9566, 5551, 24401, 10632], "avg_logprob": -0.14730525275935297, "compression_ratio": 1.6352941176470588, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 9.379999999999999, "end": 10.24, "word": "بسم", "probability": 0.847900390625}, {"start": 10.24, "end": 10.4, "word": " الله", "probability": 0.95849609375}, {"start": 10.4, "end": 10.72, "word": " الرحمن", "probability": 0.97802734375}, {"start": 10.72, "end": 11.16, "word": " الرحيم", "probability": 0.9934895833333334}, {"start": 11.16, "end": 13.04, "word": " بنكمل", "probability": 0.777099609375}, {"start": 13.04, "end": 13.46, "word": " اليوم", "probability": 0.918701171875}, {"start": 13.46, "end": 13.64, "word": " ان", "probability": 0.658203125}, {"start": 13.64, "end": 13.86, "word": " شاء", "probability": 0.985595703125}, {"start": 13.86, "end": 13.94, "word": " الله", "probability": 0.95703125}, {"start": 13.94, "end": 14.16, "word": " في", "probability": 0.85009765625}, {"start": 14.16, "end": 14.58, "word": " موضوع", "probability": 0.995361328125}, {"start": 14.58, "end": 14.76, "word": " ال", "probability": 0.97998046875}, {"start": 14.76, "end": 15.46, "word": " alkanes", "probability": 0.6292724609375}, {"start": 15.46, "end": 17.52, "word": " وسنتطرق", "probability": 0.841796875}, {"start": 17.52, "end": 17.7, "word": " في", "probability": 0.98583984375}, {"start": 17.7, "end": 17.98, "word": " هذه", "probability": 0.962890625}, {"start": 17.98, "end": 18.9, "word": " المحاضرة", "probability": 0.983154296875}, {"start": 18.9, "end": 19.74, "word": " إلى", "probability": 0.73046875}, {"start": 19.74, "end": 20.52, "word": " ال", "probability": 0.92236328125}, {"start": 20.52, "end": 20.86, "word": " cycle", "probability": 0.3857421875}, {"start": 20.86, "end": 21.58, "word": " alkanes", "probability": 0.8748372395833334}, {"start": 21.58, "end": 21.8, "word": " اللي", "probability": 0.7890625}, {"start": 21.8, "end": 22.12, "word": " هي", "probability": 0.94873046875}, {"start": 22.12, "end": 23.54, "word": " المركبات", "probability": 0.92578125}, {"start": 23.54, "end": 24.62, "word": " الحلقية", "probability": 0.9810791015625}, {"start": 24.62, "end": 25.68, "word": " التي", "probability": 0.6923828125}, {"start": 25.68, "end": 26.3, "word": " تحتوي", "probability": 0.9684244791666666}, {"start": 26.3, "end": 26.56, "word": " على", "probability": 0.8857421875}, {"start": 26.56, "end": 27.32, "word": " روابط", "probability": 0.984619140625}, {"start": 27.32, "end": 28.16, "word": " أحدية", "probability": 0.76220703125}], "temperature": 1.0}, {"id": 2, "seek": 4570, "start": 29.34, "end": 45.7, "text": "إن شاء الله هنتعرض إلى الحلقات الثلاثية والرباعية والخماسية والسداسية المركب اللي مكوّن من تلت كربونات يعني حلقة ثلاثية بنسميه Cyclopropane اللي مكوّن من أربع كربونات على شكل حلقة", "tokens": [28814, 1863, 13412, 16606, 21984, 8032, 29399, 3615, 43042, 30731, 21542, 1211, 4587, 9307, 6024, 104, 1211, 5718, 104, 10632, 16070, 25513, 45761, 10632, 16070, 9778, 15042, 3794, 10632, 16070, 3794, 3215, 32277, 10632, 9673, 31747, 3555, 13672, 1829, 3714, 4117, 2407, 11703, 1863, 9154, 6055, 1211, 2655, 9122, 25513, 2407, 8315, 2655, 37495, 22653, 11331, 1211, 28671, 38637, 1211, 5718, 104, 10632, 44945, 38251, 1829, 3224, 49173, 404, 1513, 1929, 13672, 1829, 3714, 4117, 2407, 11703, 1863, 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والسداسية", "probability": 0.792578125}, {"start": 35.8, "end": 37.0, "word": " المركب", "probability": 0.8504231770833334}, {"start": 37.0, "end": 37.1, "word": " اللي", "probability": 0.69775390625}, {"start": 37.1, "end": 37.5, "word": " مكوّن", "probability": 0.7154296875}, {"start": 37.5, "end": 37.64, "word": " من", "probability": 0.994140625}, {"start": 37.64, "end": 38.0, "word": " تلت", "probability": 0.7928059895833334}, {"start": 38.0, "end": 38.54, "word": " كربونات", "probability": 0.88828125}, {"start": 38.54, "end": 38.72, "word": " يعني", "probability": 0.775634765625}, {"start": 38.72, "end": 39.06, "word": " حلقة", "probability": 0.9752604166666666}, {"start": 39.06, "end": 39.6, "word": " ثلاثية", "probability": 0.986328125}, {"start": 39.6, "end": 40.12, "word": " بنسميه", "probability": 0.7398681640625}, {"start": 40.12, "end": 41.1, "word": " Cyclopropane", "probability": 0.75701904296875}, {"start": 41.1, "end": 41.92, "word": " اللي", "probability": 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50.18, "word": " والمكوّن", "probability": 0.7638753255208334}, {"start": 50.18, "end": 50.34, "word": " من", "probability": 0.98583984375}, {"start": 50.34, "end": 50.92, "word": " ستة", "probability": 0.9676106770833334}, {"start": 50.92, "end": 52.42, "word": " Cyclohexane", "probability": 0.9579264322916666}, {"start": 52.42, "end": 53.06, "word": " طبعاً", "probability": 0.697021484375}, {"start": 53.06, "end": 53.5, "word": " بالتأكيد", "probability": 0.872998046875}, {"start": 53.5, "end": 53.64, "word": " لو", "probability": 0.779296875}, {"start": 53.64, "end": 54.36, "word": " استمرنا", "probability": 0.9163411458333334}, {"start": 54.36, "end": 54.56, "word": " يعني", "probability": 0.849609375}, {"start": 54.56, "end": 54.96, "word": " السبعة", "probability": 0.86962890625}, {"start": 54.96, "end": 55.5, "word": " بنسميها", "probability": 0.7412109375}, {"start": 55.5, "end": 56.32, "word": " Cycloheptane", "probability": 0.841552734375}, {"start": 56.32, "end": 56.84, "word": " التمانية", "probability": 0.70062255859375}, {"start": 56.84, "end": 57.28, "word": " Cyclo", "probability": 0.89501953125}, {"start": 57.28, "end": 57.72, "word": "-octane", "probability": 0.68206787109375}, {"start": 57.72, "end": 58.14, "word": " التسعة", "probability": 0.9547526041666666}, {"start": 58.14, "end": 58.6, "word": " Cyclo", "probability": 0.9060872395833334}, {"start": 58.6, "end": 59.02, "word": "-nonane", "probability": 0.8416341145833334}, {"start": 59.02, "end": 59.38, "word": " العشر", "probability": 0.89111328125}, {"start": 59.38, "end": 59.8, "word": " Cyclo", "probability": 0.85400390625}, {"start": 59.8, "end": 60.18, "word": "-decane", "probability": 0.6646321614583334}, {"start": 60.18, "end": 61.04, "word": " وهكذا", "probability": 0.73797607421875}], "temperature": 1.0}, {"id": 4, "seek": 9093, "start": 61.69, "end": 90.93, "text": "الان لو بدنا نطلع بالتفصيل للمركب الأول اللي هو الـ Cyclopropane هاي فيه معنى model أو شكل لـ Cyclopropane لاحظوا في هذا الشكل الـ Cyclopropane فيه تلت ذرات Carbon و عامل روابط اللي هي عاملة الحلقة الثلاثية إذا بنلاحظ احنا على كل Carbon حتى يكتمل الأربع روابط ذرتين هيدروجين", "tokens": [6027, 7649, 45164, 47525, 8315, 8717, 9566, 1211, 3615, 20666, 2655, 5172, 9381, 26895, 5296, 19528, 31747, 3555, 16247, 12610, 13672, 1829, 31439, 2423, 39184, 49173, 404, 1513, 1929, 8032, 47302, 8978, 3224, 20449, 1863, 7578, 2316, 34051, 13412, 28820, 5296, 39184, 49173, 404, 1513, 1929, 20193, 5016, 19913, 14407, 8978, 23758, 25124, 28820, 2423, 39184, 49173, 404, 1513, 1929, 8978, 3224, 6055, 1211, 2655, 29910, 2288, 9307, 31453, 4032, 6225, 10943, 1211, 12602, 14407, 3555, 9566, 13672, 1829, 39896, 6225, 10943, 37977, 21542, 1211, 28671, 6024, 104, 1211, 5718, 104, 10632, 11933, 15730, 44945, 15040, 5016, 19913, 1975, 5016, 8315, 15844, 28242, 31453, 11331, 49975, 7251, 4117, 39237, 1211, 16247, 25513, 3615, 12602, 14407, 3555, 9566, 29910, 43500, 9957, 8032, 25708, 2288, 29245, 9957], "avg_logprob": 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{"start": 68.43, "end": 69.05, "word": " هاي", "probability": 0.376953125}, {"start": 69.05, "end": 69.29, "word": " فيه", "probability": 0.6337890625}, {"start": 69.29, "end": 70.21, "word": " معنى", "probability": 0.9353841145833334}, {"start": 70.21, "end": 70.75, "word": " model", "probability": 0.521484375}, {"start": 70.75, "end": 71.09, "word": " أو", "probability": 0.775390625}, {"start": 71.09, "end": 71.51, "word": " شكل", "probability": 0.980712890625}, {"start": 71.51, "end": 71.79, "word": " لـ", "probability": 0.71240234375}, {"start": 71.79, "end": 72.87, "word": " Cyclopropane", "probability": 0.89697265625}, {"start": 72.87, "end": 73.85, "word": " لاحظوا", "probability": 0.9349365234375}, {"start": 73.85, "end": 74.03, "word": " في", "probability": 0.91015625}, {"start": 74.03, "end": 74.31, "word": " هذا", "probability": 0.94921875}, {"start": 74.31, "end": 74.91, "word": " الشكل", "probability": 0.989013671875}, {"start": 74.91, "end": 75.93, "word": " الـ", 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"word": " يعني", "probability": 0.554443359375}, {"start": 92.76, "end": 93.04, "word": " هذه", "probability": 0.49072265625}, {"start": 93.04, "end": 93.26, "word": " الـ", "probability": 0.4993896484375}, {"start": 93.26, "end": 93.52, "word": " carbon", "probability": 0.42919921875}, {"start": 93.52, "end": 93.76, "word": " لما", "probability": 0.8525390625}, {"start": 93.76, "end": 94.06, "word": " بنيجي", "probability": 0.7449951171875}, {"start": 94.06, "end": 94.6, "word": " نتطلع", "probability": 0.6837890625}, {"start": 94.6, "end": 94.92, "word": " عليها", "probability": 0.990966796875}, {"start": 94.92, "end": 95.0, "word": " و", "probability": 0.71044921875}, {"start": 95.0, "end": 95.34, "word": " نريها", "probability": 0.5747884114583334}, {"start": 95.34, "end": 95.58, "word": " تكون", "probability": 0.923583984375}, {"start": 95.58, "end": 96.3, "word": " مكتملة", "probability": 0.9149169921875}, {"start": 96.3, "end": 97.04, "word": " بنلاحظ", "probability": 0.8389892578125}, {"start": 97.04, "end": 97.4, "word": " عليها", "probability": 0.7939453125}, {"start": 97.4, "end": 97.74, "word": " أربع", "probability": 0.8136393229166666}, {"start": 97.74, "end": 98.22, "word": " روابط", "probability": 0.9755859375}, {"start": 98.22, "end": 98.9, "word": " رابطتين", "probability": 0.92109375}, {"start": 98.9, "end": 99.08, "word": " مع", "probability": 0.9404296875}, {"start": 99.08, "end": 99.32, "word": " الـ", "probability": 0.6002197265625}, {"start": 99.32, "end": 99.7, "word": " carbons", "probability": 0.84326171875}, {"start": 99.7, "end": 100.5, "word": " المجاورة", "probability": 0.98271484375}, {"start": 100.5, "end": 100.92, "word": " و", "probability": 0.97216796875}, {"start": 100.92, "end": 101.68, "word": " رابطتين", "probability": 0.98193359375}, {"start": 101.68, "end": 102.02, "word": " مع", "probability": 0.974609375}, {"start": 102.02, "end": 103.0, "word": " الهيدروجين", "probability": 0.8770751953125}], "temperature": 1.0}, {"id": 6, "seek": 14021, "start": 121.91, "end": 140.21, "text": "بنستنتج من هنا أن الصيغة العامة للـ Cycloalkanes CNNH2N يعني لما يكون عندى C3 الـ H6 لما يكون عندى C4 الـ H8 لما يكون عندى C5 الـ H10 و هكذا", "tokens": [3555, 1863, 14851, 29399, 7435, 9154, 34105, 14739, 31767, 1829, 17082, 3660, 18863, 10943, 3660, 24976, 39184, 10295, 66, 752, 667, 12779, 24859, 39, 17, 45, 37495, 22653, 5296, 15042, 7251, 30544, 43242, 7578, 383, 18, 2423, 39184, 389, 21, 5296, 15042, 7251, 30544, 43242, 7578, 383, 19, 2423, 39184, 389, 23, 5296, 15042, 7251, 30544, 43242, 7578, 383, 20, 2423, 39184, 389, 3279, 4032, 8032, 4117, 15730], "avg_logprob": -0.2247509127077849, "compression_ratio": 1.5172413793103448, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 121.91, "end": 123.03, "word": "بنستنتج", "probability": 0.89140625}, {"start": 123.03, "end": 123.23, "word": " من", "probability": 0.93212890625}, {"start": 123.23, "end": 123.57, "word": " هنا", "probability": 0.97412109375}, {"start": 123.57, "end": 124.15, "word": " أن", "probability": 0.389404296875}, {"start": 124.15, "end": 124.71, "word": " الصيغة", "probability": 0.85302734375}, {"start": 124.71, "end": 125.19, "word": " العامة", "probability": 0.9879557291666666}, {"start": 125.19, "end": 125.49, "word": " للـ", "probability": 0.6339111328125}, {"start": 125.49, "end": 126.41, "word": " Cycloalkanes", "probability": 0.6406005859375}, {"start": 126.41, "end": 128.45, "word": " CNNH2N", "probability": 0.6811065673828125}, {"start": 128.45, "end": 129.19, "word": " يعني", "probability": 0.750732421875}, {"start": 129.19, "end": 129.57, "word": " لما", "probability": 0.855712890625}, {"start": 129.57, "end": 129.87, "word": " يكون", "probability": 0.79833984375}, {"start": 129.87, "end": 130.23, "word": " عندى", "probability": 0.5858154296875}, {"start": 130.23, "end": 130.83, "word": " C3", "probability": 0.84375}, {"start": 130.83, "end": 131.67, "word": " الـ", "probability": 0.757568359375}, {"start": 131.67, "end": 132.71, "word": " H6", "probability": 0.801025390625}, {"start": 132.71, "end": 133.27, "word": " لما", "probability": 0.8330078125}, {"start": 133.27, "end": 133.45, "word": " يكون", "probability": 0.984619140625}, {"start": 133.45, "end": 133.75, "word": " عندى", "probability": 0.917724609375}, {"start": 133.75, "end": 134.47, "word": " C4", "probability": 0.98876953125}, {"start": 134.47, "end": 134.93, "word": " الـ", "probability": 0.95361328125}, {"start": 134.93, "end": 135.69, "word": " H8", "probability": 0.918701171875}, {"start": 135.69, "end": 136.21, "word": " لما", "probability": 0.934326171875}, {"start": 136.21, "end": 136.39, "word": " يكون", "probability": 0.987060546875}, {"start": 136.39, "end": 136.69, "word": " عندى", "probability": 0.889892578125}, {"start": 136.69, "end": 137.41, "word": " C5", "probability": 0.989013671875}, {"start": 137.41, "end": 137.83, "word": " الـ", "probability": 0.967529296875}, {"start": 137.83, "end": 139.07, "word": " H10", "probability": 0.895263671875}, {"start": 139.07, "end": 139.65, "word": " و", "probability": 0.63134765625}, {"start": 139.65, "end": 140.21, "word": " هكذا", "probability": 0.90478515625}], "temperature": 1.0}, {"id": 7, "seek": 15669, "start": 140.8, "end": 156.7, "text": "واضح؟ هذا بيفرج عن الألكانز العادية، الألكانز العادية كانت صيغتهم العامة بنذكر CNN H2N Plus 2 كانوا يزيدوا ذارتين، طبعا هدول الذارتين اختفوا لما عملنا اللي هي الرابطة الحلقية، لما سكرنا على حلقة", "tokens": [2407, 46958, 5016, 22807, 23758, 4724, 33911, 47341, 18871, 16247, 1211, 41361, 11622, 18863, 18513, 10632, 12399, 16247, 1211, 41361, 11622, 18863, 18513, 10632, 25961, 2655, 20328, 1829, 17082, 2655, 16095, 18863, 10943, 3660, 44945, 8848, 37983, 24859, 389, 17, 45, 7721, 568, 25961, 14407, 7251, 11622, 25708, 14407, 29910, 9640, 2655, 9957, 12399, 23032, 3555, 3615, 995, 8032, 3215, 12610, 32545, 9640, 2655, 9957, 1975, 46456, 5172, 14407, 5296, 15042, 6225, 42213, 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"probability": 0.7843424479166666}, {"start": 152.08, "end": 152.5, "word": " الذارتين", "probability": 0.918701171875}, {"start": 152.5, "end": 152.9, "word": " اختفوا", "probability": 0.953125}, {"start": 152.9, "end": 153.08, "word": " لما", "probability": 0.919921875}, {"start": 153.08, "end": 153.56, "word": " عملنا", "probability": 0.986328125}, {"start": 153.56, "end": 154.06, "word": " اللي", "probability": 0.818359375}, {"start": 154.06, "end": 154.2, "word": " هي", "probability": 0.9521484375}, {"start": 154.2, "end": 154.68, "word": " الرابطة", "probability": 0.846435546875}, {"start": 154.68, "end": 155.38, "word": " الحلقية،", "probability": 0.88330078125}, {"start": 155.38, "end": 155.56, "word": " لما", "probability": 0.98583984375}, {"start": 155.56, "end": 156.14, "word": " سكرنا", "probability": 0.8642578125}, {"start": 156.14, "end": 156.32, "word": " على", "probability": 0.87841796875}, {"start": 156.32, "end": 156.7, "word": " حلقة", "probability": 0.9736328125}], "temperature": 1.0}, {"id": 8, "seek": 17517, "start": 157.27, "end": 175.17, "text": "الان هذا الـ Cyclopropane لو اطلعت على ذرات الكربون التلات اللي موجودين فيه بلاحظ انهم في مستوى واحد فالـ Cyclopropane is a planar molecule يعني التلات الذرات هي هم عامل انا ايدي موجودين في مستوى واحد", "tokens": [6027, 7649, 23758, 2423, 39184, 49173, 404, 1513, 1929, 45164, 1975, 9566, 1211, 34268, 15844, 29910, 2288, 9307, 33251, 25513, 11536, 16712, 1211, 9307, 13672, 1829, 3714, 29245, 23328, 9957, 8978, 3224, 4724, 15040, 5016, 19913, 16472, 16095, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 6156, 6027, 39184, 49173, 404, 1513, 1929, 307, 257, 1393, 289, 15582, 37495, 22653, 16712, 1211, 9307, 32545, 2288, 9307, 39896, 8032, 2304, 6225, 10943, 1211, 1975, 8315, 1975, 1829, 16254, 3714, 29245, 23328, 9957, 8978, 3714, 14851, 2407, 7578, 36764, 24401], "avg_logprob": -0.18181818114085632, "compression_ratio": 1.7513513513513514, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 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"probability": 0.88671875}, {"start": 311.67, "end": 312.25, "word": " على", "probability": 0.91455078125}, {"start": 312.25, "end": 312.59, "word": " نفس", "probability": 0.991455078125}, {"start": 312.59, "end": 312.87, "word": " ذرة", "probability": 0.949462890625}, {"start": 312.87, "end": 313.45, "word": " الكربون", "probability": 0.9423828125}, {"start": 313.45, "end": 313.93, "word": " ولذلك", "probability": 0.8445638020833334}, {"start": 313.93, "end": 314.13, "word": " هذا", "probability": 0.95849609375}, {"start": 314.13, "end": 314.87, "word": " المركب", "probability": 0.8689778645833334}, {"start": 314.87, "end": 316.27, "word": " بسميه", "probability": 0.9718017578125}], "temperature": 1.0}, {"id": 16, "seek": 33636, "start": 318.84, "end": 336.36, "text": "one dichlorocyclopropane هذا ايش بسمي انا one one dichlorocyclopropane طبعا ممكن اتسأل ليش انا هنا حطيت الرقم لأنه من ال dichlorocompound في عند احتمال انه يكون عند غير ال one one ولذلك انا بحدده بالارقام", "tokens": 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{"start": 327.28, "end": 327.82, "word": " الرقم", "probability": 0.9895833333333334}, {"start": 327.82, "end": 328.62, "word": " لأنه", "probability": 0.8076171875}, {"start": 328.62, "end": 328.76, "word": " من", "probability": 0.99462890625}, {"start": 328.76, "end": 328.9, "word": " ال", "probability": 0.95458984375}, {"start": 328.9, "end": 330.92, "word": " dichlorocompound", "probability": 0.709912109375}, {"start": 330.92, "end": 331.38, "word": " في", "probability": 0.73095703125}, {"start": 331.38, "end": 331.7, "word": " عند", "probability": 0.78271484375}, {"start": 331.7, "end": 332.52, "word": " احتمال", "probability": 0.9036865234375}, {"start": 332.52, "end": 332.92, "word": " انه", "probability": 0.8203125}, {"start": 332.92, "end": 333.16, "word": " يكون", "probability": 0.98681640625}, {"start": 333.16, "end": 333.42, "word": " عند", "probability": 0.90625}, {"start": 333.42, "end": 333.82, "word": " غير", "probability": 0.9296875}, {"start": 333.82, "end": 333.98, "word": " ال", "probability": 0.97705078125}, {"start": 333.98, "end": 334.2, "word": " one", "probability": 0.83203125}, {"start": 334.2, "end": 334.44, "word": " one", "probability": 0.951171875}, {"start": 334.44, "end": 335.0, "word": " ولذلك", "probability": 0.8927408854166666}, {"start": 335.0, "end": 335.22, "word": " انا", "probability": 0.8994140625}, {"start": 335.22, "end": 335.74, "word": " بحدده", "probability": 0.955810546875}, {"start": 335.74, "end": 336.36, "word": " بالارقام", "probability": 0.9810791015625}], "temperature": 1.0}, {"id": 17, "seek": 34854, "start": 336.86, "end": 348.54, "text": "الان لو قلنا اعرفنا ان في عندنا مُركّب 1,1-dichlorocyclopropane وإجينا بدنا نشيل واحدة من هدول الـhydrogens اللي حُط مكانها إكلوري جديدة، لاحظوا معنا", "tokens": [6027, 7649, 45164, 12174, 1211, 8315, 1975, 3615, 28480, 8315, 16472, 8978, 43242, 8315, 3714, 10859, 31747, 11703, 3555, 502, 11, 16, 12, 67, 480, 6746, 31078, 3474, 404, 1513, 1929, 4032, 28814, 7435, 1829, 8315, 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521.38, "word": " ليس", "probability": 0.9736328125}, {"start": 521.38, "end": 521.54, "word": " في", "probability": 0.98779296875}, {"start": 521.54, "end": 522.02, "word": " مستوى", "probability": 0.9822998046875}, {"start": 522.02, "end": 522.4, "word": " واحد", "probability": 0.99658203125}, {"start": 522.4, "end": 523.12, "word": " وإنما", "probability": 0.9595947265625}, {"start": 523.12, "end": 523.34, "word": " في", "probability": 0.986328125}, {"start": 523.34, "end": 523.76, "word": " حالة", "probability": 0.9978841145833334}, {"start": 523.76, "end": 524.34, "word": " انثناء", "probability": 0.857666015625}, {"start": 524.34, "end": 524.86, "word": " بهذا", "probability": 0.94873046875}, {"start": 524.86, "end": 525.36, "word": " الشكل", "probability": 0.9912109375}], "temperature": 1.0}, {"id": 26, "seek": 54330, "start": 525.87, "end": 543.31, "text": "املاحظين واضحة الصورة كيف من ثني تماما بهذا الشكل احنا بنقدر نتخيله بهذا الشكل بنقدر نتخيله عامل زي هيك إذا بدنا نعطي اسم هذا اللي عامل زي هيك بسموه زي ال butterfly زي الفراشة", "tokens": [10943, 15040, 5016, 19913, 9957, 4032, 46958, 5016, 3660, 31767, 13063, 3660, 9122, 33911, 9154, 38637, 22653, 46811, 10943, 995, 39627, 15730, 25124, 28820, 1975, 5016, 8315, 44945, 28543, 2288, 8717, 2655, 9778, 26895, 3224, 39627, 15730, 25124, 28820, 44945, 28543, 2288, 8717, 2655, 9778, 26895, 3224, 6225, 10943, 1211, 30767, 1829, 39896, 4117, 11933, 15730, 47525, 8315, 8717, 3615, 9566, 1829, 24525, 2304, 23758, 13672, 1829, 6225, 10943, 1211, 30767, 1829, 39896, 4117, 4724, 38251, 2407, 3224, 30767, 1829, 2423, 22140, 30767, 1829, 27188, 2288, 33599, 3660], "avg_logprob": -0.11639747324954258, "compression_ratio": 1.8224852071005917, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 525.87, "end": 526.53, "word": "املاحظين", "probability": 0.843603515625}, {"start": 526.53, "end": 527.03, "word": " واضحة", "probability": 0.88330078125}, {"start": 527.03, "end": 527.35, "word": " الصورة", "probability": 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{"start": 533.95, "end": 534.49, "word": " نتخيله", "probability": 0.99345703125}, {"start": 534.49, "end": 534.83, "word": " عامل", "probability": 0.9811197916666666}, {"start": 534.83, "end": 535.11, "word": " زي", "probability": 0.98681640625}, {"start": 535.11, "end": 535.51, "word": " هيك", "probability": 0.972900390625}, {"start": 535.51, "end": 536.21, "word": " إذا", "probability": 0.851318359375}, {"start": 536.21, "end": 536.63, "word": " بدنا", "probability": 0.961669921875}, {"start": 536.63, "end": 537.07, "word": " نعطي", "probability": 0.996337890625}, {"start": 537.07, "end": 537.51, "word": " اسم", "probability": 0.91552734375}, {"start": 537.51, "end": 537.81, "word": " هذا", "probability": 0.9716796875}, {"start": 537.81, "end": 537.97, "word": " اللي", "probability": 0.98193359375}, {"start": 537.97, "end": 538.37, "word": " عامل", "probability": 0.9934895833333334}, {"start": 538.37, "end": 538.71, "word": " زي", "probability": 0.991455078125}, {"start": 538.71, "end": 539.15, "word": " هيك", "probability": 0.992431640625}, {"start": 539.15, "end": 540.37, "word": " بسموه", "probability": 0.8502197265625}, {"start": 540.37, "end": 540.81, "word": " زي", "probability": 0.98779296875}, {"start": 540.81, "end": 540.99, "word": " ال", "probability": 0.90283203125}, {"start": 540.99, "end": 541.67, "word": " butterfly", "probability": 0.638671875}, {"start": 541.67, "end": 542.39, "word": " زي", "probability": 0.937255859375}, {"start": 542.39, "end": 543.31, "word": " الفراشة", "probability": 0.961181640625}], "temperature": 1.0}, {"id": 27, "seek": 56707, "start": 543.91, "end": 567.07, "text": "عمل زي الفراشة كيف الفراشة لما بتكون عاملة جناحينها بزاوية فالـ Cyclobutane is not a planar molecule مش جزء في مستوى واحد مش عامل زي المربع اللي في مستوى واحد لأ جايب three dimensional زي ال butterfly زي الفراشة واضح طبعا اكيد", "tokens": [25957, 1211, 30767, 1829, 27188, 2288, 33599, 3660, 9122, 33911, 27188, 2288, 33599, 3660, 5296, 15042, 39894, 30544, 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"end": 545.77, "word": " الفراشة", "probability": 0.9759521484375}, {"start": 545.77, "end": 545.95, "word": " لما", "probability": 0.9541015625}, {"start": 545.95, "end": 546.57, "word": " بتكون", "probability": 0.97607421875}, {"start": 546.57, "end": 547.43, "word": " عاملة", "probability": 0.98486328125}, {"start": 547.43, "end": 548.13, "word": " جناحينها", "probability": 0.86611328125}, {"start": 548.13, "end": 548.79, "word": " بزاوية", "probability": 0.95966796875}, {"start": 548.79, "end": 549.83, "word": " فالـ", "probability": 0.6552734375}, {"start": 549.83, "end": 551.47, "word": " Cyclobutane", "probability": 0.725048828125}, {"start": 551.47, "end": 551.93, "word": " is", "probability": 0.8076171875}, {"start": 551.93, "end": 552.49, "word": " not", "probability": 0.9560546875}, {"start": 552.49, "end": 552.97, "word": " a", "probability": 0.947265625}, {"start": 552.97, "end": 553.51, "word": " planar", "probability": 0.90234375}, {"start": 553.51, "end": 554.19, "word": " molecule", "probability": 0.81103515625}, {"start": 554.19, "end": 555.13, "word": " مش", "probability": 0.958984375}, {"start": 555.13, "end": 555.69, "word": " جزء", "probability": 0.9265950520833334}, {"start": 555.69, "end": 555.91, "word": " في", "probability": 0.947265625}, {"start": 555.91, "end": 556.45, "word": " مستوى", "probability": 0.97900390625}, {"start": 556.45, "end": 556.87, "word": " واحد", "probability": 0.9853515625}, {"start": 556.87, "end": 557.35, "word": " مش", "probability": 0.8369140625}, {"start": 557.35, "end": 557.77, "word": " عامل", "probability": 0.9964192708333334}, {"start": 557.77, "end": 558.09, "word": " زي", "probability": 0.991455078125}, {"start": 558.09, "end": 558.79, "word": " المربع", "probability": 0.9825846354166666}, {"start": 558.79, "end": 558.97, "word": " اللي", "probability": 0.9365234375}, {"start": 558.97, "end": 559.11, "word": " في", "probability": 0.97021484375}, {"start": 559.11, "end": 559.55, "word": " مستوى", "probability": 0.9766845703125}, {"start": 559.55, "end": 559.89, "word": " واحد", "probability": 0.993408203125}, {"start": 559.89, "end": 560.31, "word": " لأ", "probability": 0.81884765625}, {"start": 560.31, "end": 560.85, "word": " جايب", "probability": 0.9269205729166666}, {"start": 560.85, "end": 561.11, "word": " three", "probability": 0.5966796875}, {"start": 561.11, "end": 561.83, "word": " dimensional", "probability": 0.529296875}, {"start": 561.83, "end": 562.49, "word": " زي", "probability": 0.99609375}, {"start": 562.49, "end": 562.61, "word": " ال", "probability": 0.919921875}, {"start": 562.61, "end": 563.15, "word": " butterfly", "probability": 0.7880859375}, {"start": 563.15, "end": 563.77, "word": " زي", "probability": 0.9619140625}, {"start": 563.77, "end": 564.97, "word": " الفراشة", "probability": 0.9749755859375}, {"start": 564.97, "end": 565.49, "word": " واضح", "probability": 0.9459635416666666}, {"start": 565.49, "end": 566.45, "word": " طبعا", "probability": 0.87030029296875}, {"start": 566.45, "end": 567.07, "word": " اكيد", "probability": 0.8267415364583334}], "temperature": 1.0}, {"id": 28, "seek": 59647, "start": 567.57, "end": 596.47, "text": "أكيد بنلاحظ هنا في الـ «Cycloprop-butane» أنه في عندى تمانية هيدروجينز والتمانية هيدروجينز هدولة متكافئات لكن لو بدى أعمل عمليات إبدال بلاحظ أنه بإمكاني أبدل على نفس الـCarbon تنتين أو تلاتة أو على الـCarbon اللي جنبها أو على الـCarbon اللي جبالها وممكن يكون عندى أشياء على نفس الاتجاه تعطيني «cis» وأشياء باتجاهات متعاكزة تعطيني «trans» فالخلاصة", "tokens": [10721, 4117, 25708, 44945, 15040, 5016, 19913, 34105, 8978, 2423, 39184, 4657, 34, 88, 3474, 404, 1513, 12, 5955, 1929, 5933, 14739, 3224, 8978, 43242, 7578, 46811, 7649, 10632, 8032, 25708, 2288, 29245, 9957, 11622, 16070, 39237, 7649, 10632, 8032, 25708, 2288, 29245, 9957, 11622, 8032, 3215, 12610, 3660, 44650, 4117, 31845, 19986, 9307, 44381, 45164, 47525, 7578, 5551, 25957, 1211, 6225, 2304, 20292, 9307, 11933, 44510, 6027, 4724, 15040, 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568.89, "word": " هنا", "probability": 0.931640625}, {"start": 568.89, "end": 569.53, "word": " في", "probability": 0.91796875}, {"start": 569.53, "end": 569.71, "word": " الـ", "probability": 0.7119140625}, {"start": 569.71, "end": 570.43, "word": " «Cycloprop", "probability": 0.6463216145833334}, {"start": 570.43, "end": 572.05, "word": "-butane»", "probability": 0.745361328125}, {"start": 572.05, "end": 572.35, "word": " أنه", "probability": 0.602294921875}, {"start": 572.35, "end": 572.45, "word": " في", "probability": 0.8251953125}, {"start": 572.45, "end": 572.79, "word": " عندى", "probability": 0.6629638671875}, {"start": 572.79, "end": 573.25, "word": " تمانية", "probability": 0.8048502604166666}, {"start": 573.25, "end": 574.23, "word": " هيدروجينز", "probability": 0.7653401692708334}, {"start": 574.23, "end": 575.15, "word": " والتمانية", "probability": 0.871826171875}, {"start": 575.15, "end": 575.79, "word": " هيدروجينز", "probability": 0.9119466145833334}, {"start": 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"word": " على", "probability": 0.90185546875}, {"start": 582.13, "end": 582.95, "word": " نفس", "probability": 0.88037109375}, {"start": 582.95, "end": 583.61, "word": " الـCarbon", "probability": 0.685272216796875}, {"start": 583.61, "end": 584.29, "word": " تنتين", "probability": 0.8536783854166666}, {"start": 584.29, "end": 584.51, "word": " أو", "probability": 0.9638671875}, {"start": 584.51, "end": 585.09, "word": " تلاتة", "probability": 0.9749755859375}, {"start": 585.09, "end": 585.47, "word": " أو", "probability": 0.96044921875}, {"start": 585.47, "end": 585.63, "word": " على", "probability": 0.6474609375}, {"start": 585.63, "end": 586.13, "word": " الـCarbon", "probability": 0.9075927734375}, {"start": 586.13, "end": 586.33, "word": " اللي", "probability": 0.718017578125}, {"start": 586.33, "end": 586.75, "word": " جنبها", "probability": 0.8812255859375}, {"start": 586.75, "end": 586.93, "word": " أو", "probability": 0.9775390625}, {"start": 586.93, "end": 587.07, "word": " على", "probability": 0.67236328125}, {"start": 587.07, "end": 587.47, "word": " الـCarbon", "probability": 0.960205078125}, {"start": 587.47, "end": 587.63, "word": " اللي", "probability": 0.98681640625}, {"start": 587.63, "end": 588.11, "word": " جبالها", "probability": 0.917724609375}, {"start": 588.11, "end": 589.07, "word": " وممكن", "probability": 0.97216796875}, {"start": 589.07, "end": 589.31, "word": " يكون", "probability": 0.982177734375}, {"start": 589.31, "end": 589.59, "word": " عندى", "probability": 0.874267578125}, {"start": 589.59, "end": 589.99, "word": " أشياء", "probability": 0.98828125}, {"start": 589.99, "end": 590.23, "word": " على", "probability": 0.958984375}, {"start": 590.23, "end": 590.53, "word": " نفس", "probability": 0.99658203125}, {"start": 590.53, "end": 591.21, "word": " الاتجاه", "probability": 0.9072265625}, {"start": 591.21, "end": 591.81, "word": " تعطيني", "probability": 0.844970703125}, {"start": 591.81, "end": 592.39, "word": " «cis»", "probability": 0.5337727864583334}, {"start": 592.39, "end": 593.01, "word": " وأشياء", "probability": 0.8609375}, {"start": 593.01, "end": 593.61, "word": " باتجاهات", "probability": 0.97021484375}, {"start": 593.61, "end": 594.21, "word": " متعاكزة", "probability": 0.7576904296875}, {"start": 594.21, "end": 594.61, "word": " تعطيني", "probability": 0.9365234375}, {"start": 594.61, "end": 595.53, "word": " «trans»", "probability": 0.9200846354166666}, {"start": 595.53, "end": 596.47, "word": " فالخلاصة", "probability": 0.9312337239583334}], "temperature": 1.0}, {"id": 29, "seek": 61648, "start": 596.92, "end": 616.48, "text": "إن لو أنا بدأ أقول Clorocyclobutane عند منه مركب واحد بشيل أي هيدروجينة التمانية زي بعض التمانية زي بعض و بحط Clor بصير عند Clorocyclobutane التمن هيدروجينز زي بعض لكن لو كنت بدأ أحط التانية", "tokens": [28814, 1863, 45164, 41850, 47525, 10721, 5551, 39648, 2033, 284, 31078, 3474, 996, 325, 1929, 43242, 9154, 3224, 3714, 31747, 3555, 36764, 24401, 4724, 8592, 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"words": [{"start": 673.46, "end": 674.28, "word": "بعد", "probability": 0.837646484375}, {"start": 674.28, "end": 674.72, "word": " الـ", "probability": 0.789306640625}, {"start": 674.72, "end": 675.82, "word": " Cyclopentane", "probability": 0.681060791015625}, {"start": 675.82, "end": 676.62, "word": " بننتقل", "probability": 0.782012939453125}, {"start": 676.62, "end": 677.26, "word": " للمُركّب", "probability": 0.8396402994791666}, {"start": 677.26, "end": 677.42, "word": " اللي", "probability": 0.943115234375}, {"start": 677.42, "end": 677.74, "word": " بعده", "probability": 0.920654296875}, {"start": 677.74, "end": 677.86, "word": " اللي", "probability": 0.904296875}, {"start": 677.86, "end": 678.06, "word": " فيه", "probability": 0.932373046875}, {"start": 678.06, "end": 678.44, "word": " خمس", "probability": 0.88037109375}, {"start": 678.44, "end": 679.2, "word": " كربونات", "probability": 0.930078125}, {"start": 679.2, "end": 679.44, "word": " واللي", "probability": 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"end": 693.16, "word": " ماشي", "probability": 0.7783203125}, {"start": 693.16, "end": 693.3, "word": " على", "probability": 0.96044921875}, {"start": 693.3, "end": 693.56, "word": " نفس", "probability": 0.994873046875}, {"start": 693.56, "end": 694.02, "word": " الصيغة", "probability": 0.9222412109375}, {"start": 694.02, "end": 695.96, "word": " CNH2N", "probability": 0.732470703125}, {"start": 695.96, "end": 696.76, "word": " فقط", "probability": 0.975341796875}, {"start": 696.76, "end": 697.78, "word": " الآن", "probability": 0.6932373046875}, {"start": 697.78, "end": 698.2, "word": " لو", "probability": 0.9287109375}, {"start": 698.2, "end": 698.5, "word": " قلنا", "probability": 0.828125}, {"start": 698.5, "end": 698.76, "word": " كيف", "probability": 0.9697265625}, {"start": 698.76, "end": 699.32, "word": " الشكل", "probability": 0.986328125}, {"start": 699.32, "end": 699.98, "word": " البعض", "probability": 0.9117838541666666}, {"start": 699.98, "end": 700.38, "word": " ربما", 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{"id": 34, "seek": 74879, "start": 733.69, "end": 748.79, "text": "لاحظوا هاي أربعة موجودين في مستوى واحد اللي هما تحديداً هايهم هنا عندنا واحد، اتنين، تلاتة، أربعة في مستوى واحد وهذه طالعة عنهم هذا الشكل يشبه ماذا؟", "tokens": [15040, 5016, 19913, 14407, 8032, 47302, 5551, 25513, 27884, 3714, 29245, 23328, 9957, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 13672, 1829, 8032, 15042, 6055, 5016, 16254, 28259, 14111, 8032, 47302, 16095, 34105, 43242, 8315, 36764, 24401, 12399, 1975, 2655, 1863, 9957, 12399, 6055, 1211, 9307, 3660, 12399, 5551, 25513, 27884, 8978, 3714, 14851, 2407, 7578, 36764, 24401, 37037, 24192, 23032, 6027, 27884, 18871, 16095, 23758, 25124, 28820, 7251, 8592, 3555, 3224, 3714, 45636, 995, 22807], "avg_logprob": -0.13230519016067704, "compression_ratio": 1.7647058823529411, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 733.69, "end": 734.25, "word": "لاحظوا", "probability": 0.942626953125}, {"start": 734.25, "end": 734.41, "word": " هاي", "probability": 0.3251953125}, {"start": 734.41, "end": 734.99, "word": " أربعة", "probability": 0.8287760416666666}, {"start": 734.99, "end": 735.91, "word": " موجودين", "probability": 0.98388671875}, {"start": 735.91, "end": 736.09, "word": " في", "probability": 0.98193359375}, {"start": 736.09, "end": 736.63, "word": " مستوى", "probability": 0.9765625}, {"start": 736.63, "end": 737.19, "word": " واحد", "probability": 0.98681640625}, {"start": 737.19, "end": 737.45, "word": " اللي", "probability": 0.94482421875}, {"start": 737.45, "end": 737.67, "word": " هما", "probability": 0.722412109375}, {"start": 737.67, "end": 739.27, "word": " تحديداً", "probability": 0.92646484375}, {"start": 739.27, "end": 739.69, "word": " هايهم", "probability": 0.6171061197916666}, {"start": 739.69, "end": 739.91, "word": " هنا", "probability": 0.89990234375}, {"start": 739.91, "end": 740.63, "word": " عندنا", "probability": 0.993408203125}, {"start": 740.63, "end": 742.71, "word": " واحد،", "probability": 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{"start": 748.19, "end": 748.79, "word": " ماذا؟", "probability": 0.964111328125}], "temperature": 1.0}, {"id": 35, "seek": 76634, "start": 749.42, "end": 766.34, "text": "يشبه اللي هو مظروف المكتوب المفتوح it is like an open envelope واضح؟ فاحنا اللي بنقوله ان الـcyclopentane is not a planar molecule it is like an open envelope", "tokens": [1829, 8592, 3555, 3224, 13672, 1829, 31439, 3714, 19913, 32887, 5172, 9673, 4117, 2655, 37746, 9673, 5172, 2655, 2407, 5016, 309, 307, 411, 364, 1269, 19989, 4032, 46958, 5016, 22807, 6156, 39319, 8315, 13672, 1829, 44945, 39648, 3224, 16472, 2423, 39184, 34080, 404, 317, 1929, 307, 406, 257, 1393, 289, 15582, 309, 307, 411, 364, 1269, 19989], "avg_logprob": -0.14924569145358843, "compression_ratio": 1.4421768707482994, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 749.42, "end": 750.76, "word": "يشبه", "probability": 0.952392578125}, {"start": 750.76, "end": 751.16, "word": " اللي", "probability": 0.736572265625}, {"start": 751.16, 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0.9189453125}, {"start": 765.18, "end": 765.68, "word": " open", "probability": 0.9228515625}, {"start": 765.68, "end": 766.34, "word": " envelope", "probability": 0.89501953125}], "temperature": 1.0}, {"id": 36, "seek": 79292, "start": 766.48, "end": 792.92, "text": "زي المكتوب المفتوح الآن بتلاحظوا معنى برضه أنه فيه عشر Hydrogens equivalent لكن لما بدنا نشيل أكتر من Hydrogens دنتين أو تلاتة بيصير عندى عدد كبير من ال isomers يمكن أنه تجربوها ع الورق وتحسبوها بشكل كامل لكن بشكل عام هذا هو شكل ال Cyclopentane it is like an open envelope", "tokens": [11622, 1829, 9673, 4117, 2655, 37746, 9673, 5172, 2655, 2407, 5016, 6024, 48506, 39894, 15040, 5016, 19913, 14407, 20449, 1863, 7578, 4724, 43042, 3224, 14739, 3224, 8978, 3224, 6225, 46309, 24231, 6675, 694, 10344, 44381, 5296, 15042, 47525, 8315, 8717, 8592, 26895, 5551, 4117, 2655, 2288, 9154, 24231, 6675, 694, 11778, 29399, 9957, 34051, 6055, 1211, 9307, 3660, 4724, 1829, 9381, 13546, 43242, 7578, 6225, 3215, 3215, 9122, 3555, 13546, 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781.36, "end": 781.88, "word": " تجربوها", "probability": 0.97578125}, {"start": 781.88, "end": 782.04, "word": " ع", "probability": 0.457763671875}, {"start": 782.04, "end": 782.46, "word": " الورق", "probability": 0.9759114583333334}, {"start": 782.46, "end": 783.38, "word": " وتحسبوها", "probability": 0.91982421875}, {"start": 783.38, "end": 784.4, "word": " بشكل", "probability": 0.9921875}, {"start": 784.4, "end": 785.24, "word": " كامل", "probability": 0.9973958333333334}, {"start": 785.24, "end": 785.9, "word": " لكن", "probability": 0.8798828125}, {"start": 785.9, "end": 786.82, "word": " بشكل", "probability": 0.97216796875}, {"start": 786.82, "end": 787.24, "word": " عام", "probability": 0.99853515625}, {"start": 787.24, "end": 787.8, "word": " هذا", "probability": 0.91162109375}, {"start": 787.8, "end": 788.14, "word": " هو", "probability": 0.98876953125}, {"start": 788.14, "end": 788.74, "word": " شكل", "probability": 0.977783203125}, {"start": 788.74, "end": 789.0, "word": " ال", "probability": 0.68798828125}, {"start": 789.0, "end": 789.98, "word": " Cyclopentane", "probability": 0.60272216796875}, {"start": 789.98, "end": 790.42, "word": " it", "probability": 0.75830078125}, {"start": 790.42, "end": 790.68, "word": " is", "probability": 0.9150390625}, {"start": 790.68, "end": 791.3, "word": " like", "probability": 0.94921875}, {"start": 791.3, "end": 791.72, "word": " an", "probability": 0.8701171875}, {"start": 791.72, "end": 792.28, "word": " open", "probability": 0.9248046875}, {"start": 792.28, "end": 792.92, "word": " envelope", "probability": 0.85546875}], "temperature": 1.0}, {"id": 37, "seek": 81289, "start": 793.05, "end": 812.89, "text": "هيكوا شايفين القاعدة وهذا الجزء اللي هو يمثل المظروف المفتوح الـ Open Envelope بننتقل الآن للشكل التالي اللي هو الـ Cyclohexane اللي فيه 6 ذرات كربون طبعا ربما البعض يعتقد ان الـ Cyclohexane", "tokens": [3224, 1829, 4117, 14407, 13412, 995, 33911, 9957, 25062, 995, 22488, 3660, 37037, 15730, 25724, 11622, 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الجزء", "probability": 0.9436848958333334}, {"start": 795.79, "end": 795.95, "word": " اللي", "probability": 0.803466796875}, {"start": 795.95, "end": 796.19, "word": " هو", "probability": 0.90234375}, {"start": 796.19, "end": 797.07, "word": " يمثل", "probability": 0.9288330078125}, {"start": 797.07, "end": 797.81, "word": " المظروف", "probability": 0.9833984375}, {"start": 797.81, "end": 798.51, "word": " المفتوح", "probability": 0.9947265625}, {"start": 798.51, "end": 798.71, "word": " الـ", "probability": 0.545654296875}, {"start": 798.71, "end": 799.01, "word": " Open", "probability": 0.442626953125}, {"start": 799.01, "end": 799.67, "word": " Envelope", "probability": 0.808349609375}, {"start": 799.67, "end": 802.33, "word": " بننتقل", "probability": 0.8597412109375}, {"start": 802.33, "end": 802.83, "word": " الآن", "probability": 0.76513671875}, {"start": 802.83, "end": 803.77, "word": " للشكل", "probability": 0.8914388020833334}, {"start": 803.77, "end": 804.55, "word": " 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"word": " البعض", "probability": 0.9765625}, {"start": 810.67, "end": 811.31, "word": " يعتقد", "probability": 0.9597981770833334}, {"start": 811.31, "end": 811.55, "word": " ان", "probability": 0.5263671875}, {"start": 811.55, "end": 811.91, "word": " الـ", "probability": 0.6817626953125}, {"start": 811.91, "end": 812.89, "word": " Cyclohexane", "probability": 0.9514973958333334}], "temperature": 1.0}, {"id": 38, "seek": 84160, "start": 813.26, "end": 841.6, "text": "ماخد الشكل البلانر زي ما بيبدو على الشاشة لكن الحقيقة في التجربة أو في الواقع لأ الشكل مابيجيش بلانر الـ 6 ذرات كربون مابيجيش بلانر لكن بياخد عدة أشكال من هذه الأشكال اللي ممكن ياخدها الـ Cyclohexane إذا بنركز احنا على ذرات الكربون اللي بيظهروا عندنا باللون الأسود هنا هاي واحد، اتنين، تلاتة", "tokens": [2304, 47283, 3215, 25124, 28820, 29739, 1211, 7649, 2288, 30767, 1829, 19446, 4724, 1829, 44510, 2407, 15844, 25124, 33599, 3660, 44381, 21542, 38436, 28671, 8978, 16712, 7435, 25513, 3660, 34051, 8978, 2423, 14407, 4587, 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1328.25, "word": " أكتر؟", "probability": 0.953515625}, {"start": 1328.25, "end": 1328.59, "word": " تكون", "probability": 0.6729736328125}, {"start": 1328.59, "end": 1329.35, "word": " equatorial", "probability": 0.962890625}, {"start": 1329.35, "end": 1329.55, "word": " ولا", "probability": 0.74853515625}, {"start": 1329.55, "end": 1330.83, "word": " Axial؟", "probability": 0.7687174479166666}, {"start": 1330.83, "end": 1331.41, "word": " بالتأكيد", "probability": 0.99140625}, {"start": 1331.41, "end": 1331.63, "word": " لما", "probability": 0.94970703125}, {"start": 1331.63, "end": 1331.99, "word": " بتكون", "probability": 0.8798828125}, {"start": 1331.99, "end": 1332.71, "word": " equatorial", "probability": 0.986328125}, {"start": 1332.71, "end": 1333.01, "word": " مافيش", "probability": 0.6932779947916666}, {"start": 1333.01, "end": 1333.15, "word": " إش", "probability": 0.72119140625}, {"start": 1333.15, "end": 1333.79, "word": " تصطدم", "probability": 0.8089599609375}, {"start": 1333.79, "end": 1334.17, "word": " معه،", "probability": 0.77783203125}, {"start": 1334.17, "end": 1334.69, "word": " تتنافر", "probability": 0.967578125}, {"start": 1334.69, "end": 1335.05, "word": " معه", "probability": 0.985595703125}, {"start": 1335.05, "end": 1335.55, "word": " لكن", "probability": 0.49609375}, {"start": 1335.55, "end": 1335.87, "word": " لما", "probability": 0.96826171875}, {"start": 1335.87, "end": 1336.39, "word": " كانت", "probability": 0.9375}, {"start": 1336.39, "end": 1337.11, "word": " Axial", "probability": 0.95849609375}, {"start": 1337.11, "end": 1337.77, "word": " شوفنا", "probability": 0.7010091145833334}, {"start": 1337.77, "end": 1337.99, "word": " إنها", "probability": 0.808349609375}, {"start": 1337.99, "end": 1338.39, "word": " جريبة", "probability": 0.9664713541666666}, {"start": 1338.39, "end": 1338.57, "word": " من", "probability": 0.978515625}, {"start": 1338.57, "end": 1338.73, "word": " two", "probability": 0.63720703125}, 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"word": "ولذلك", "probability": 0.8567708333333334}, {"start": 1340.95, "end": 1341.59, "word": " الـ", "probability": 0.6258544921875}, {"start": 1341.59, "end": 1343.35, "word": " methylcyclohexane", "probability": 0.8400181361607143}, {"start": 1343.35, "end": 1344.31, "word": " بفضل", "probability": 0.8603515625}, {"start": 1344.31, "end": 1344.71, "word": " يكون", "probability": 0.969482421875}, {"start": 1344.71, "end": 1345.37, "word": " بالـ", "probability": 0.852294921875}, {"start": 1345.37, "end": 1345.81, "word": " circle", "probability": 0.1270751953125}, {"start": 1345.81, "end": 1346.73, "word": " formation", "probability": 0.9580078125}, {"start": 1346.73, "end": 1347.47, "word": " والـ", "probability": 0.636962890625}, {"start": 1347.47, "end": 1347.75, "word": " methyl", "probability": 0.87158203125}, {"start": 1347.75, "end": 1348.21, "word": " group", "probability": 0.93359375}, {"start": 1348.21, "end": 1348.81, "word": " تكون", "probability": 0.89111328125}, {"start": 1348.81, "end": 1349.23, "word": " في", "probability": 0.94287109375}, {"start": 1349.23, "end": 1349.43, "word": " الـ", "probability": 0.829833984375}, {"start": 1349.43, "end": 1350.59, "word": " equatorial", "probability": 0.948486328125}, {"start": 1350.59, "end": 1351.15, "word": " position", "probability": 0.98974609375}, {"start": 1351.15, "end": 1352.09, "word": " بأكد", "probability": 0.8994140625}, {"start": 1352.09, "end": 1352.93, "word": " الـ", "probability": 0.61767578125}, {"start": 1352.93, "end": 1353.15, "word": " methyl", "probability": 0.9091796875}, {"start": 1353.15, "end": 1353.69, "word": " group", "probability": 0.98828125}, {"start": 1353.69, "end": 1354.23, "word": " وين", "probability": 0.7301025390625}, {"start": 1354.23, "end": 1354.69, "word": " أفضل", "probability": 0.9620361328125}, {"start": 1354.69, "end": 1355.55, "word": " تكون؟", "probability": 0.7859700520833334}, {"start": 1355.55, "end": 1355.77, "word": " في", "probability": 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equatorial position و فقط 5% من الوقت في الـ axial position لأنه لما بتكون في الـ axial position بتكون عملت نافر مع الـ hydrogen أو الـ two hydrogens اللي موجودين إقراب منها", "tokens": [41185, 2423, 39184, 10295, 66, 752, 675, 87, 1929, 39894, 30544, 13420, 4, 9154, 2423, 30543, 2655, 2423, 39184, 48441, 1594, 8978, 2423, 39184, 45544, 831, 2535, 4032, 6156, 47432, 1025, 4, 9154, 2423, 30543, 2655, 8978, 2423, 39184, 46851, 2535, 5296, 33456, 3224, 5296, 15042, 39894, 30544, 8978, 2423, 39184, 46851, 2535, 39894, 30544, 6225, 42213, 2655, 8717, 31845, 2288, 20449, 2423, 39184, 12697, 34051, 2423, 39184, 732, 5796, 6675, 694, 13672, 1829, 3714, 29245, 23328, 9957, 11933, 4587, 2288, 16758, 9154, 11296], "avg_logprob": -0.15560662045198329, "compression_ratio": 1.7142857142857142, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1373.74, "end": 1373.88, "word": "في", "probability": 0.806640625}, {"start": 1373.88, "end": 1374.1, "word": " الـ", "probability": 0.8203125}, 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او radical", "tokens": [2655, 7649, 10632, 4032, 39894, 2655, 5172, 995, 30241, 9122, 15730, 11933, 15730, 8032, 3215, 12610, 995, 33962, 9566, 35473, 9957, 44650, 37983, 2288, 9307, 28242, 3714, 25720, 4724, 44510, 10721, 4724, 1737, 12001, 1975, 2407, 4724, 39888, 12018, 4032, 39894, 2655, 5172, 995, 30241, 39894, 25957, 1211, 389, 9966, 50113, 1211, 35434, 4032, 4724, 9566, 1211, 3615, 39888, 12018, 3714, 25720, 6055, 7649, 10632, 1975, 2407, 12001], "avg_logprob": -0.25747283299763996, "compression_ratio": 1.5527950310559007, "no_speech_prob": 4.112720489501953e-06, "words": [{"start": 2011.35, "end": 2011.91, "word": "تانية", "probability": 0.6472981770833334}, {"start": 2011.91, "end": 2012.13, "word": " و", "probability": 0.4873046875}, {"start": 2012.13, "end": 2012.67, "word": " بتتفاعل", "probability": 0.832421875}, {"start": 2012.67, "end": 2013.07, "word": " كذا", "probability": 0.564697265625}, {"start": 2013.07, "end": 2013.55, "word": " إذا", "probability": 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أبدل الهيدروجين بكلورة ممكن الكلورة تيجي على الذرة الأولى ويصير عند المركب اللي هو وانكلوروبروبين", "tokens": [41185, 11331, 6027, 3660, 2423, 26890, 37746, 9957, 9122, 9640, 3555, 11536, 6055, 29399, 9957, 6055, 1211, 9307, 3660, 45164, 4724, 16254, 5551, 39648, 2423, 39184, 4713, 8997, 6746, 404, 2323, 349, 82, 37495, 22653, 45164, 4724, 3794, 4724, 16254, 5551, 44510, 1211, 2423, 3224, 25708, 2288, 29245, 9957, 4724, 28820, 13063, 3660, 3714, 43020, 2423, 28820, 13063, 3660, 6055, 1829, 7435, 1829, 15844, 32545, 25720, 16247, 12610, 7578, 4032, 1829, 9381, 13546, 43242, 9673, 31747, 3555, 13672, 1829, 31439, 4032, 7649, 4117, 1211, 13063, 2407, 26890, 37746, 9957], "avg_logprob": -0.25555555356873405, "compression_ratio": 1.687830687830688, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2195.45, "end": 2195.79, "word": "في", "probability": 0.3212890625}, {"start": 2195.79, "end": 2196.25, "word": " حالة", "probability": 0.9820963541666666}, {"start": 2196.25, "end": 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لو", "probability": 0.87744140625}, {"start": 2228.91, "end": 2229.19, "word": " بدأ", "probability": 0.45947265625}, {"start": 2229.19, "end": 2229.37, "word": " أقول", "probability": 0.85888671875}, {"start": 2229.37, "end": 2229.57, "word": " من", "probability": 0.990234375}, {"start": 2229.57, "end": 2230.19, "word": " البروبين", "probability": 0.83544921875}, {"start": 2230.19, "end": 2230.51, "word": " الـ", "probability": 0.73095703125}, {"start": 2230.51, "end": 2231.67, "word": " monochloroproducts", "probability": 0.8141043526785714}, {"start": 2231.67, "end": 2232.41, "word": " المتوقع", "probability": 0.9510498046875}, {"start": 2232.41, "end": 2232.75, "word": " كام", "probability": 0.916259765625}, {"start": 2232.75, "end": 2233.17, "word": " ناتج", "probability": 0.8761393229166666}, {"start": 2233.17, "end": 2233.69, "word": " اتنين", "probability": 0.83160400390625}, {"start": 2233.69, "end": 2234.01, "word": " ال", "probability": 0.95654296875}, {"start": 2234.01, "end": 2234.19, "word": " one", "probability": 0.41650390625}, {"start": 2234.19, "end": 2234.83, "word": "-chloroproduct", "probability": 0.7411702473958334}, {"start": 2234.83, "end": 2235.23, "word": " و", "probability": 0.69140625}, {"start": 2235.23, "end": 2235.35, "word": " ال", "probability": 0.8056640625}, {"start": 2235.35, "end": 2235.51, "word": " two", "probability": 0.89892578125}, {"start": 2235.51, "end": 2236.51, "word": "-chloroproduct", "probability": 0.943603515625}, {"start": 2236.51, "end": 2237.25, "word": " الآن", "probability": 0.5938720703125}, {"start": 2237.25, "end": 2237.43, "word": " لو", "probability": 0.9716796875}, {"start": 2237.43, "end": 2237.75, "word": " قلت", "probability": 0.85595703125}, {"start": 2237.75, "end": 2237.99, "word": " بدي", "probability": 0.5299072265625}, {"start": 2237.99, "end": 2238.39, "word": " أبدل", "probability": 0.8826497395833334}, {"start": 2238.39, "end": 2238.87, "word": " ذرتين", "probability": 0.549072265625}, {"start": 2238.87, "end": 2239.41, "word": " هيدروجين", "probability": 0.88701171875}, {"start": 2239.41, "end": 2239.93, "word": " بكلور", "probability": 0.9630533854166666}, {"start": 2239.93, "end": 2240.23, "word": " كام", "probability": 0.92578125}, {"start": 2240.23, "end": 2240.51, "word": " ناتج", "probability": 0.9803059895833334}, {"start": 2240.51, "end": 2240.77, "word": " ممكن", "probability": 0.971923828125}, {"start": 2240.77, "end": 2241.13, "word": " يطلع", "probability": 0.9913330078125}, {"start": 2241.13, "end": 2241.65, "word": " عنده؟", "probability": 0.8766276041666666}], "temperature": 1.0}, {"id": 103, "seek": 225108, "start": 2242.7, "end": 2251.08, "text": "ممكن ذرتين الكلور يجعل الكربون الأولى، بطلع one-one-dichloropropane، ممكن التنتين يجعل الكربون الثانية", "tokens": [2304, 43020, 29910, 2288, 2655, 9957, 33251, 1211, 13063, 7251, 7435, 30241, 33251, 25513, 11536, 16247, 12610, 7578, 12399, 4724, 9566, 1211, 3615, 472, 12, 546, 12, 67, 480, 6746, 404, 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2267.54, "end": 2269.28, "word": "-Dichlorobrobin", "probability": 0.93048095703125}, {"start": 2269.28, "end": 2269.76, "word": " إذا", "probability": 0.677490234375}, {"start": 2269.76, "end": 2270.3, "word": " عمال", "probability": 0.9475911458333334}, {"start": 2270.3, "end": 2270.46, "word": " من", "probability": 0.9853515625}, {"start": 2270.46, "end": 2270.66, "word": " الـ", "probability": 0.935546875}, {"start": 2270.66, "end": 2272.56, "word": " Dichlorobrobin", "probability": 0.8459123883928571}, {"start": 2272.56, "end": 2273.06, "word": " أنا", "probability": 0.87255859375}, {"start": 2273.06, "end": 2273.34, "word": " شايف", "probability": 0.986328125}, {"start": 2273.34, "end": 2273.66, "word": " أربع", "probability": 0.7473958333333334}, {"start": 2273.66, "end": 2274.5, "word": " مركبات", "probability": 0.831787109375}, {"start": 2274.5, "end": 2274.88, "word": " و", "probability": 0.95068359375}, {"start": 2274.88, "end": 2275.04, "word": " من", "probability": 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مواقع الروابط هان الكلور ع موقع واحد هان الكلور ع موقع اتنين او هان ذرتين كلور ع موقع واحد هان ذرتين كلور ع موقع اتنين هان ذرة ع واحد ذرة ع اتنين هان ذرة ع واحد ذرة ع تلاتة هاد هي ال isomers او ال structural isomers المفروض انه يصير عندكوا تدريب لو قلنالكوا اعملوا ابدال بذرة واحدة بذرتين على البيوتين مثلا ممكن تاخدوه ك homework", "tokens": [2407, 2423, 39184, 745, 1757, 1807, 1119, 298, 433, 4724, 1829, 46456, 46538, 14407, 8978, 3714, 14407, 4587, 3615, 34892, 14407, 3555, 9566, 8032, 7649, 2423, 28820, 13063, 6225, 3714, 30543, 3615, 36764, 24401, 8032, 7649, 2423, 28820, 13063, 6225, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 1975, 2407, 8032, 7649, 29910, 43500, 9957, 28242, 13063, 6225, 3714, 30543, 3615, 36764, 24401, 8032, 7649, 29910, 43500, 9957, 28242, 13063, 6225, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 8032, 7649, 29910, 25720, 6225, 36764, 24401, 29910, 25720, 6225, 1975, 2655, 1863, 9957, 8032, 7649, 29910, 25720, 6225, 36764, 24401, 29910, 25720, 6225, 6055, 1211, 9307, 3660, 8032, 18513, 39896, 2423, 307, 298, 433, 1975, 2407, 2423, 15067, 307, 298, 433, 9673, 5172, 32887, 11242, 16472, 3224, 7251, 9381, 13546, 43242, 4117, 14407, 6055, 3215, 16572, 3555, 45164, 12174, 1211, 8315, 23275, 14407, 1975, 25957, 1211, 14407, 1975, 44510, 6027, 4724, 8848, 25720, 36764, 24401, 3660, 4724, 8848, 43500, 9957, 15844, 2423, 21292, 35473, 9957, 50113, 15040, 3714, 43020, 6055, 47283, 3215, 2407, 3224, 9122, 14578], "avg_logprob": -0.1472321457522256, "compression_ratio": 2.326996197718631, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2280.6, "end": 2280.88, "word": "و", "probability": 0.60693359375}, {"start": 2280.88, "end": 2281.14, "word": " الـ", "probability": 0.56475830078125}, {"start": 2281.14, "end": 2281.76, "word": " Structural", "probability": 0.8889973958333334}, {"start": 2281.76, "end": 2282.46, "word": " Isomers", "probability": 0.8141276041666666}, {"start": 2282.46, "end": 2283.14, "word": " بيختلفوا", "probability": 0.8255859375}, {"start": 2283.14, "end": 2283.3, "word": " في", "probability": 0.92529296875}, {"start": 2283.3, "end": 2283.76, "word": " مواقع", "probability": 0.9886474609375}, {"start": 2283.76, "end": 2284.34, "word": " الروابط", "probability": 0.95849609375}, {"start": 2284.34, "end": 2284.56, "word": " هان", "probability": 0.2998046875}, {"start": 2284.56, "end": 2285.0, "word": " الكلور", "probability": 0.5904541015625}, {"start": 2285.0, "end": 2285.12, "word": " ع", "probability": 0.72705078125}, {"start": 2285.12, "end": 2285.48, "word": " موقع", "probability": 0.9763997395833334}, {"start": 2285.48, "end": 2285.78, "word": " واحد", "probability": 0.912841796875}, {"start": 2285.78, "end": 2285.92, "word": " هان", "probability": 0.686279296875}, {"start": 2285.92, "end": 2286.22, "word": " الكلور", "probability": 0.9324544270833334}, {"start": 2286.22, "end": 2286.34, "word": " ع", "probability": 0.96630859375}, {"start": 2286.34, "end": 2286.66, "word": " موقع", "probability": 0.9918619791666666}, {"start": 2286.66, "end": 2287.06, "word": " اتنين", "probability": 0.9654541015625}, {"start": 2287.06, "end": 2287.62, "word": " او", "probability": 0.779052734375}, {"start": 2287.62, "end": 2287.84, "word": " هان", "probability": 0.896728515625}, {"start": 2287.84, "end": 2288.2, "word": " ذرتين", "probability": 0.7584635416666666}, {"start": 2288.2, "end": 2288.52, "word": " كلور", "probability": 0.846435546875}, {"start": 2288.52, "end": 2288.62, "word": " ع", "probability": 0.97607421875}, {"start": 2288.62, "end": 2288.96, "word": " موقع", "probability": 0.9928385416666666}, {"start": 2288.96, "end": 2289.34, "word": " واحد", "probability": 0.97802734375}, {"start": 2289.34, "end": 2289.54, "word": " هان", "probability": 0.934326171875}, {"start": 2289.54, "end": 2289.88, "word": " ذرتين", "probability": 0.8977864583333334}, {"start": 2289.88, "end": 2290.16, "word": " كلور", "probability": 0.959228515625}, {"start": 2290.16, "end": 2290.28, "word": " ع", "probability": 0.98681640625}, {"start": 2290.28, "end": 2290.58, "word": " موقع", "probability": 0.9921875}, {"start": 2290.58, "end": 2291.02, "word": " اتنين", "probability": 0.9906005859375}, {"start": 2291.02, "end": 2291.5, "word": " هان", "probability": 0.9462890625}, {"start": 2291.5, "end": 2291.76, "word": " ذرة", "probability": 0.75341796875}, {"start": 2291.76, "end": 2291.88, "word": " ع", "probability": 0.96240234375}, {"start": 2291.88, "end": 2292.14, "word": " واحد", "probability": 0.973388671875}, {"start": 2292.14, "end": 2292.38, "word": " ذرة", "probability": 0.836669921875}, {"start": 2292.38, "end": 2292.5, "word": " ع", "probability": 0.9443359375}, {"start": 2292.5, "end": 2292.74, "word": " اتنين", "probability": 0.9400634765625}, {"start": 2292.74, "end": 2292.96, "word": " هان", "probability": 0.945556640625}, {"start": 2292.96, "end": 2293.18, "word": " ذرة", "probability": 0.987548828125}, {"start": 2293.18, "end": 2293.32, "word": " ع", "probability": 0.978515625}, {"start": 2293.32, "end": 2293.56, "word": " واحد", "probability": 0.978271484375}, {"start": 2293.56, "end": 2293.86, "word": " ذرة", "probability": 0.975830078125}, {"start": 2293.86, "end": 2294.0, "word": " ع", "probability": 0.9443359375}, {"start": 2294.0, "end": 2294.56, "word": " تلاتة", "probability": 0.95458984375}, {"start": 2294.56, "end": 2295.2, "word": " هاد", "probability": 0.62890625}, {"start": 2295.2, "end": 2295.44, "word": " هي", "probability": 0.73876953125}, {"start": 2295.44, "end": 2295.84, "word": " ال", "probability": 0.98681640625}, {"start": 2295.84, "end": 2296.64, "word": " isomers", "probability": 0.7752278645833334}, {"start": 2296.64, "end": 2297.16, "word": " او", "probability": 0.794677734375}, {"start": 2297.16, "end": 2297.3, "word": " ال", "probability": 0.97998046875}, {"start": 2297.3, "end": 2297.78, "word": " structural", "probability": 0.78271484375}, {"start": 2297.78, "end": 2298.52, "word": " isomers", "probability": 0.9895833333333334}, {"start": 2298.52, "end": 2299.42, "word": " المفروض", "probability": 0.99462890625}, {"start": 2299.42, "end": 2299.86, "word": " انه", "probability": 0.877197265625}, {"start": 2299.86, "end": 2300.32, "word": " يصير", "probability": 0.9796549479166666}, {"start": 2300.32, "end": 2300.7, "word": " عندكوا", "probability": 0.81982421875}, {"start": 2300.7, "end": 2301.3, "word": " تدريب", "probability": 0.99267578125}, {"start": 2301.3, "end": 2301.76, "word": " لو", "probability": 0.97802734375}, {"start": 2301.76, "end": 2302.36, "word": " قلنالكوا", "probability": 0.869921875}, {"start": 2302.36, "end": 2302.88, "word": " اعملوا", "probability": 0.9840087890625}, {"start": 2302.88, "end": 2303.42, "word": " ابدال", "probability": 0.7325846354166666}, {"start": 2303.42, "end": 2303.84, "word": " بذرة", "probability": 0.943359375}, {"start": 2303.84, "end": 2304.3, "word": " واحدة", "probability": 0.9560546875}, {"start": 2304.3, "end": 2304.88, "word": " بذرتين", "probability": 0.8857421875}, {"start": 2304.88, "end": 2305.12, "word": " على", "probability": 0.72265625}, {"start": 2305.12, "end": 2305.82, "word": " البيوتين", "probability": 0.9178466796875}, {"start": 2305.82, "end": 2306.3, "word": " مثلا", "probability": 0.9453125}, {"start": 2306.3, "end": 2306.9, "word": " ممكن", "probability": 0.9482421875}, {"start": 2306.9, "end": 2308.02, "word": " تاخدوه", "probability": 0.89892578125}, {"start": 2308.02, "end": 2308.1, "word": " ك", "probability": 0.8486328125}, {"start": 2308.1, "end": 2308.42, "word": " homework", "probability": 0.55859375}], "temperature": 1.0}, {"id": 106, "seek": 231829, "start": 2309.37, "end": 2318.29, "text": "كم Monochloroproduct وكم Diachloroproduct ممكن أتوقع من مُركّب البيوتين شكراً", "tokens": [24793, 4713, 8997, 6746, 404, 2323, 349, 4032, 24793, 8789, 608, 6746, 404, 2323, 349, 3714, 43020, 5551, 2655, 30543, 3615, 9154, 3714, 10859, 31747, 11703, 3555, 29739, 1829, 35473, 9957, 13412, 4117, 23557, 14111], "avg_logprob": -0.23025173279974195, "compression_ratio": 1.1666666666666667, "no_speech_prob": 0.0, "words": [{"start": 2309.37, "end": 2309.77, "word": "كم", "probability": 0.8779296875}, {"start": 2309.77, "end": 2311.83, "word": " Monochloroproduct", "probability": 0.7453206380208334}, {"start": 2311.83, "end": 2312.29, "word": " وكم", "probability": 0.86181640625}, {"start": 2312.29, "end": 2313.63, "word": " Diachloroproduct", "probability": 0.8328857421875}, {"start": 2313.63, "end": 2314.17, "word": " ممكن", "probability": 0.963134765625}, {"start": 2314.17, "end": 2314.99, "word": " أتوقع", "probability": 0.900634765625}, {"start": 2314.99, "end": 2315.33, "word": " من", "probability": 0.98486328125}, {"start": 2315.33, "end": 2316.01, "word": " مُركّب", "probability": 0.833447265625}, {"start": 2316.01, "end": 2316.99, "word": " البيوتين", "probability": 0.80712890625}, {"start": 2316.99, "end": 2318.29, "word": " شكراً", "probability": 0.80657958984375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2320.55575, "duration_after_vad": 2286.6940937499944}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..22c7b28a833e31cb368d9defc1b22b1952389ebf
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_raw.srt
@@ -0,0 +1,1924 @@
+1
+00:00:09,380 --> 00:00:14,160
+بسم الله الرحمن الرحيم بنكمل اليوم ان شاء الله في
+
+2
+00:00:14,160 --> 00:00:20,520
+موضوع ال alkanes وسنتطرق في هذه المحاضرة إلى ال
+
+3
+00:00:20,520 --> 00:00:26,300
+cycle alkanes اللي هي المركبات الحلقية التي تحتوي
+
+4
+00:00:26,300 --> 00:00:32,120
+على روابط أحديةإن شاء الله هنتعرض إلى الحلقات
+
+5
+00:00:32,120 --> 00:00:37,100
+الثلاثية والرباعية والخماسية والسداسية المركب اللي
+
+6
+00:00:37,100 --> 00:00:40,120
+مكوّن من تلت كربونات يعني حلقة ثلاثية بنسميه
+
+7
+00:00:40,120 --> 00:00:45,220
+Cyclopropane اللي مكوّن من أربع كربونات على شكل
+
+8
+00:00:45,220 --> 00:00:49,540
+حلقةCyclobutane المكوّن من خمسة Cycloبنتين
+
+9
+00:00:49,540 --> 00:00:53,640
+والمكوّن من ستة Cyclohexane طبعاً بالتأكيد لو
+
+10
+00:00:53,640 --> 00:00:56,840
+استمرنا يعني السبعة بنسميها Cycloheptane التمانية
+
+11
+00:00:56,840 --> 00:00:59,800
+Cyclo-octane التسعة Cyclo-nonane العشر Cyclo
+
+12
+00:00:59,800 --> 00:01:05,970
+-decane وهكذاالان لو بدنا نطلع بالتفصيل للمركب
+
+13
+00:01:05,970 --> 00:01:10,750
+الأول اللي هو الـ Cyclopropane هاي فيه معنى model
+
+14
+00:01:10,750 --> 00:01:15,930
+أو شكل لـ Cyclopropane لاحظوا في هذا الشكل الـ
+
+15
+00:01:15,930 --> 00:01:21,270
+Cyclopropane فيه تلت ذرات Carbon و عامل روابط اللي
+
+16
+00:01:21,270 --> 00:01:26,090
+هي عاملة الحلقة الثلاثية إذا بنلاحظ احنا على كل
+
+17
+00:01:26,090 --> 00:01:32,300
+Carbon حتى يكتمل الأربع روابط ذرتين هيدروجينواضح
+
+18
+00:01:32,300 --> 00:01:35,340
+يعني هذه الـ carbon لما بنيجي نتطلع عليها و نريها
+
+19
+00:01:35,340 --> 00:01:39,320
+تكون مكتملة بنلاحظ عليها أربع روابط رابطتين مع الـ
+
+20
+00:01:39,320 --> 00:01:43,000
+carbons المجاورة و رابطتين مع الهيدروجين
+
+21
+00:02:01,910 --> 00:02:06,410
+بنستنتج من هنا أن الصيغة العامة للـ Cycloalkanes
+
+22
+00:02:06,410 --> 00:02:13,750
+CNNH2N يعني لما يكون عندى C3 الـ H6 لما يكون عندى
+
+23
+00:02:13,750 --> 00:02:21,800
+C4 الـ H8 لما يكون عندى C5 الـ H10 و هكذاواضح؟ هذا
+
+24
+00:02:21,800 --> 00:02:25,340
+بيفرج عن الألكانز العادية، الألكانز العادية كانت
+
+25
+00:02:25,340 --> 00:02:30,540
+صيغتهم العامة بنذكر CNN H2N Plus 2 كانوا يزيدوا
+
+26
+00:02:30,540 --> 00:02:34,060
+ذارتين، طبعا هدول الذارتين اختفوا لما عملنا اللي
+
+27
+00:02:34,060 --> 00:02:38,670
+هي الرابطة الحلقية، لما سكرنا على حلقةالان هذا الـ
+
+28
+00:02:38,670 --> 00:02:42,490
+Cyclopropane لو اطلعت على ذرات الكربون التلات اللي
+
+29
+00:02:42,490 --> 00:02:46,730
+موجودين فيه بلاحظ انهم في مستوى واحد فالـ
+
+30
+00:02:46,730 --> 00:02:50,690
+Cyclopropane is a planar molecule يعني التلات
+
+31
+00:02:50,690 --> 00:02:55,170
+الذرات هي هم عامل انا ايدي موجودين في مستوى واحد
+
+32
+00:02:55,800 --> 00:02:59,580
+الان اذا انا بتطلع على الـhydrogens اللي محمولين
+
+33
+00:02:59,580 --> 00:03:02,700
+عليه ستة هيدروجين، واحد، اتنين، تلاتة، اربعة،
+
+34
+00:03:02,700 --> 00:03:06,400
+خمسة، ستة، الست ضرات هيدروجين اللي على
+
+35
+00:03:06,400 --> 00:03:10,880
+الـcyclopropane هدولة متكافئات، يعني لو بدأ أشيل
+
+36
+00:03:10,880 --> 00:03:15,240
+واحدة منهم مثلا أعمل لها إبدال، substitution بذرة
+
+37
+00:03:15,240 --> 00:03:20,690
+نفترض كلور، هاي ذرة كلورلو شيلت هادي أو هادي أو
+
+38
+00:03:20,690 --> 00:03:24,050
+هادي أو هادي أو هادي أو هادي نفس النتيجة بطلع عندى
+
+39
+00:03:24,050 --> 00:03:29,770
+فقط مُركّب واحد اللى هو اكلورو سايكلو بروبين ولو
+
+40
+00:03:29,770 --> 00:03:32,810
+رفعت اي واحدة وحطيت مكانها الكلور هيطلع نفس
+
+41
+00:03:32,810 --> 00:03:37,690
+المُركّب إذا لو أجينا سألنا كام اكلورو سايكلو
+
+42
+00:03:37,690 --> 00:03:42,910
+بروبين أنا فيه عندى واحد ايش السبب السبب انه اصلا
+
+43
+00:03:42,910 --> 00:03:48,410
+انه اصلا الهيدروجينات الستة ذرات الهيدروجينالست
+
+44
+00:03:48,410 --> 00:03:51,590
+اللي على ال cyclopropane they are equivalent أي
+
+45
+00:03:51,590 --> 00:03:56,250
+واحدة أشيلها زي التانية هذي زي هذي بقلب الجزية هذي
+
+46
+00:03:56,250 --> 00:04:01,320
+رجعت نفسها دي بلف ويك هذي نفسها دي واضح؟الان
+
+47
+00:04:01,320 --> 00:04:06,880
+لاحظوا معنى بيجينا شغلة لو قلنا بدنا نبدل واحدة
+
+48
+00:04:06,880 --> 00:04:11,720
+هيدروجين بكلور عند احتمال ناتج واحد طيب الان لو
+
+49
+00:04:11,720 --> 00:04:16,540
+بدأ ابدل واحدة تانية بكلور كام ناتج بده يطلع عنده
+
+50
+00:04:16,540 --> 00:04:21,820
+هذا المركب الواحد لو بدأ اسميه اكلورو سايكلو
+
+51
+00:04:21,820 --> 00:04:25,380
+بروبينو لأن كل الأماكن متساوية لازم أقول one
+
+52
+00:04:25,380 --> 00:04:29,140
+chlorocyclopropane لأ أبدا إكلورو سايكلو بروبين
+
+53
+00:04:29,140 --> 00:04:34,140
+الآن لو بدي أشيل كمان هيدروجينة جديدة بلاحظ ملاحظة
+
+54
+00:04:34,140 --> 00:04:38,710
+أن هذه الهيدروجينة اللي على الكربون اللي هناتمثل
+
+55
+00:04:38,710 --> 00:04:43,130
+نوع لأنها على كربون تحمل هيدروجين وهدول الأربعة
+
+56
+00:04:43,130 --> 00:04:48,990
+واحد اتنين تلاتة اربعة متكافئات اذا بهذه الحالة
+
+57
+00:04:48,990 --> 00:04:57,810
+انا عندي نوعين من الهيدروجين لو شلت هذه بعمل مركب
+
+58
+00:04:57,810 --> 00:05:01,870
+جديد هايو ايش بسمي هذا المركب جديد
+
+59
+00:05:03,790 --> 00:05:07,970
+Dichlorocyclopropane لكن وين موقع ذرتين لكلور على
+
+60
+00:05:07,970 --> 00:05:12,590
+نفس ذرة الكربون يعني أنا عند كلور وكلور على نفس
+
+61
+00:05:12,590 --> 00:05:16,270
+ذرة الكربون ولذلك هذا المركب بسميه
+
+62
+00:05:18,840 --> 00:05:23,040
+one dichlorocyclopropane هذا ايش بسمي انا one one
+
+63
+00:05:23,040 --> 00:05:26,860
+dichlorocyclopropane طبعا ممكن اتسأل ليش انا هنا
+
+64
+00:05:26,860 --> 00:05:31,700
+حطيت الرقم لأنه من ال dichlorocompound في عند
+
+65
+00:05:31,700 --> 00:05:35,740
+احتمال انه يكون عند غير ال one one ولذلك انا بحدده
+
+66
+00:05:35,740 --> 00:05:40,420
+بالارقامالان لو قلنا اعرفنا ان في عندنا مُركّب 1,1
+
+67
+00:05:40,420 --> 00:05:43,980
+-dichlorocyclopropane وإجينا بدنا نشيل واحدة من
+
+68
+00:05:43,980 --> 00:05:47,740
+هدول الـhydrogens اللي حُط مكانها إكلوري جديدة،
+
+69
+00:05:47,740 --> 00:05:51,950
+لاحظوا معنالو شيلنا هذه الـ Hydrogen اللي فوق
+
+70
+00:05:51,950 --> 00:05:58,490
+وحطينا مكانها Clor بصير المركب one two three طبعاً
+
+71
+00:05:58,490 --> 00:06:04,070
+one two dichlorocyclopropane إن ذرات الكلور واحدة
+
+72
+00:06:04,070 --> 00:06:08,330
+على موقع واحد والتاني على موقع اتنين إذن هذا one
+
+73
+00:06:08,330 --> 00:06:13,450
+two dichlorocyclopropane بنلاحظ كمان ملاحظة إضافية
+
+74
+00:06:13,450 --> 00:06:17,650
+في هذا المركب إن ذرتين الكلور هدول جايين على جهة
+
+75
+00:06:17,650 --> 00:06:21,870
+واحدة من الجزيءولمّا تكون على جهة واحدة من الجزئ
+
+76
+00:06:21,870 --> 00:06:28,470
+بنستعمل البادئة sis إذن هذا لما بدي أسميه تسمية
+
+77
+00:06:28,470 --> 00:06:34,570
+كاملة بدي أسميه sis بمعنى أنه ذرتين على جهة واحدة
+
+78
+00:06:34,570 --> 00:06:41,730
+sis one two dichlorocyclopropane واضح؟إذن أنا حددت
+
+79
+00:06:41,730 --> 00:06:46,210
+اتجاه الذرتين من خلال الـBody Assets اللي بتعني
+
+80
+00:06:46,210 --> 00:06:50,330
+إنهم على جهة واحدة أو مع بعض وحددت مواقعهم إذا
+
+81
+00:06:50,330 --> 00:06:52,890
+واحدة منهم على موقع واحد، التانية على موقع اتنين
+
+82
+00:06:52,890 --> 00:06:58,250
+فهذا المُركّب المُجمل Sys 1,2-Dichlorocyclopropane
+
+83
+00:06:58,250 --> 00:07:02,610
+الآن، كان بالإمكان، كان بالإمكان إن نحط الـChlor
+
+84
+00:07:02,610 --> 00:07:06,670
+على نفس الذرة اتنين، لكن نحطها بشكل معاكس
+
+85
+00:07:09,100 --> 00:07:14,140
+هي الكلور هذه على واحد وهذه على اتنين اذا هذا one
+
+86
+00:07:14,140 --> 00:07:18,160
+two one two هي one two three one two
+
+87
+00:07:18,160 --> 00:07:23,600
+dichlorocyclopropane لكن هنا مجموعات الكلور كيف
+
+88
+00:07:23,600 --> 00:07:28,290
+بنشوفهم احنا؟عكس بعض لما يكونوا عكس بعض بنستخدم
+
+89
+00:07:28,290 --> 00:07:32,870
+البادئة أو ال prefix ال Trans فهذا المركب أنا
+
+90
+00:07:32,870 --> 00:07:38,870
+بسميه ال Trans 1,2-dichlorocyclopropane
+
+91
+00:07:40,350 --> 00:07:46,090
+كأن أنا اللي بلخصه أنه لما بدي أحط مرتين لكلور كان
+
+92
+00:07:46,090 --> 00:07:51,410
+عنده احتمال أن أعمل الـ 1,1-dichlorocyclopropane و
+
+93
+00:07:51,410 --> 00:07:54,670
+الـ 1,2-dichlorocyclopropane الـ 1,2 في منه
+
+94
+00:07:54,670 --> 00:07:58,070
+مركبين، يا بيكونوا ذرتين لكلور مع بعض، بس هم
+
+95
+00:07:58,070 --> 00:08:03,100
+المركبSES، يا بيكونوا ذرتين لكلور عكس بعض وبسمي
+
+96
+00:08:03,100 --> 00:08:07,000
+المركّب Trans تقريبا هذه خلّيني أقول الأشياء
+
+97
+00:08:07,000 --> 00:08:12,200
+المهمة اللي ممكن نحكيها عن الـCyclopropane الآن
+
+98
+00:08:12,200 --> 00:08:15,960
+إذا انتقلنا للمركّب اللي بعده اللي هو
+
+99
+00:08:15,960 --> 00:08:22,380
+الـCycloputane اللي مكوّن من أربع ذراتربما يخطر
+
+100
+00:08:22,380 --> 00:08:28,380
+على بالكوا إن ذرات الكربون الأربعة يكونوا في مستوى
+
+101
+00:08:28,380 --> 00:08:32,340
+واحد بمعنى إن هذا الجزء يكون planner يعني جاي في
+
+102
+00:08:32,340 --> 00:08:40,280
+مستوى واحد لكن حقيقة بالتجربة العملية اللي لوحظ إن
+
+103
+00:08:40,280 --> 00:08:44,340
+هذا الجزء ليس في مستوى واحد وإنما في حالة انثناء
+
+104
+00:08:44,340 --> 00:08:49,050
+بهذا الشكلاملاحظين واضحة الصورة كيف من ثني تماما
+
+105
+00:08:49,050 --> 00:08:53,950
+بهذا الشكل احنا بنقدر نتخيله بهذا الشكل بنقدر
+
+106
+00:08:53,950 --> 00:08:58,370
+نتخيله عامل زي هيك إذا بدنا نعطي اسم هذا اللي عامل
+
+107
+00:08:58,370 --> 00:09:04,570
+زي هيك بسموه زي ال butterfly زي الفراشةعمل زي
+
+108
+00:09:04,570 --> 00:09:08,130
+الفراشة كيف الفراشة لما بتكون عاملة جناحينها
+
+109
+00:09:08,130 --> 00:09:14,190
+بزاوية فالـ Cyclobutane is not a planar molecule
+
+110
+00:09:14,190 --> 00:09:19,110
+مش جزء في مستوى واحد مش عامل زي المربع اللي في
+
+111
+00:09:19,110 --> 00:09:22,610
+مستوى واحد لأ جايب three dimensional زي ال
+
+112
+00:09:22,610 --> 00:09:28,890
+butterfly زي الفراشة واضح طبعا اكيدأكيد بنلاحظ هنا
+
+113
+00:09:28,890 --> 00:09:33,250
+في الـ «Cycloprop-butane» أنه في عندى تمانية
+
+114
+00:09:33,250 --> 00:09:37,670
+هيدروجينز والتمانية هيدروجينز هدولة متكافئات لكن
+
+115
+00:09:37,670 --> 00:09:41,930
+لو بدى أعمل عمليات إبدال بلاحظ أنه بإمكاني أبدل
+
+116
+00:09:41,930 --> 00:09:46,130
+على نفس الـCarbon تنتين أو تلاتة أو على الـCarbon
+
+117
+00:09:46,130 --> 00:09:49,310
+اللي جنبها أو على الـCarbon اللي جبالها وممكن يكون
+
+118
+00:09:49,310 --> 00:09:53,010
+عندى أشياء على نفس الاتجاه تعطيني «cis» وأشياء
+
+119
+00:09:53,010 --> 00:09:57,540
+باتجاهات متعاكزة تعطيني «trans» فالخلاصةإن لو أنا
+
+120
+00:09:57,540 --> 00:10:02,620
+بدأ أقول Clorocyclobutane
+
+121
+00:10:02,620 --> 00:10:07,200
+عند منه مركب واحد بشيل أي هيدروجينة التمانية زي
+
+122
+00:10:07,200 --> 00:10:10,680
+بعض التمانية زي بعض و بحط Clor بصير عند
+
+123
+00:10:10,680 --> 00:10:15,200
+Clorocyclobutane التمن هيدروجينز زي بعض لكن لو كنت
+
+124
+00:10:15,200 --> 00:10:20,420
+بدأ أحط التانيةالعدد بيكبر عندى، ليش؟ لأن أنا ممكن
+
+125
+00:10:20,420 --> 00:10:23,940
+أحط التاني على نفس هذه الكربونة، ممكن أحطها على
+
+126
+00:10:23,940 --> 00:10:26,580
+هذه الكربونة باتجاه الأولى أو على هذه الكربونة
+
+127
+00:10:26,580 --> 00:10:29,160
+باتجاه التانية، ممكن أحطها على الكربونة على موقع
+
+128
+00:10:29,160 --> 00:10:32,680
+تلاتة، يعني هنا بيصير عندى one two لو حطيتها هنا،
+
+129
+00:10:32,680 --> 00:10:36,380
+لو حطيتها هنا one two three، one three باتجاه
+
+130
+00:10:36,380 --> 00:10:39,540
+واحد، six، one three باتجاه متعاكس، trans،
+
+131
+00:10:39,540 --> 00:10:43,120
+فالخلاصة أنه بيصير عندى أكتر من isomers ال one one
+
+132
+00:10:44,290 --> 00:10:49,210
+و الـ 1,2-cis و الـ 1,2-trans و الـ 1,3-cis و الـ
+
+133
+00:10:49,210 --> 00:10:55,930
+1,3-trans كل هدولة المركبات ممكن أن نلاحظ وجودهم
+
+134
+00:10:55,930 --> 00:11:01,110
+في الـcyclobutane اللي عامل زي الـ butterfly and
+
+135
+00:11:01,110 --> 00:11:04,570
+it is not a planar molecule هي مرة تانية بنفرجيكوا
+
+136
+00:11:04,570 --> 00:11:10,230
+إياها كيف هو بكر مطعوج يعني عامل زي الفراشة واضح
+
+137
+00:11:10,230 --> 00:11:17,260
+هذا الكلام؟بعد الـ Cyclopentane بننتقل للمُركّب
+
+138
+00:11:17,260 --> 00:11:19,840
+اللي بعده اللي فيه خمس كربونات واللي اسمه
+
+139
+00:11:19,840 --> 00:11:23,560
+Cyclopentane إذا بدنا نتطلع على الشكل العام اللي
+
+140
+00:11:23,560 --> 00:11:28,080
+موجود فيه طبعاً بتلاحظ وهيوا أمامكم أنه فيه خمس
+
+141
+00:11:28,080 --> 00:11:33,560
+ذرات كربون عشر ذرات هيدروجين C5H10 ماشي على نفس
+
+142
+00:11:33,560 --> 00:11:40,380
+الصيغة CNH2N فقط الآن لو قلنا كيف الشكل البعض ربما
+
+143
+00:11:40,380 --> 00:11:44,690
+يتخيل أنه Cyclopentane بلانريعني يكون في مستوى
+
+144
+00:11:44,690 --> 00:11:50,510
+واحد لكن الجواب برضه لأ بالتجربة الـ Cyclopentane
+
+145
+00:11:50,510 --> 00:11:54,690
+is not a planar إذا بتطلعوا ماخد هذا الشكل لو
+
+146
+00:11:54,690 --> 00:11:59,790
+بنطلع على هذا الشكل بنلاحظ إنه هنا في عند ما يشبه
+
+147
+00:11:59,790 --> 00:12:06,710
+المستوى وهذا الـ Carbon طالع عن المستوى في هذه
+
+148
+00:12:06,710 --> 00:12:11,830
+الحالة مين يعطينا أقرب تشبيه ممكن يشبه من الحياة
+
+149
+00:12:11,830 --> 00:12:17,190
+لهذا الشكل؟لاحظوا هاي أربعة موجودين في مستوى واحد
+
+150
+00:12:17,190 --> 00:12:23,210
+اللي هما تحديداً هايهم هنا عندنا واحد، اتنين،
+
+151
+00:12:23,210 --> 00:12:27,270
+تلاتة، أربعة في مستوى واحد وهذه طالعة عنهم هذا
+
+152
+00:12:27,270 --> 00:12:33,800
+الشكل يشبه ماذا؟يشبه اللي هو مظروف المكتوب المفتوح
+
+153
+00:12:33,800 --> 00:12:38,700
+it is like an open envelope واضح؟ فاحنا اللي
+
+154
+00:12:38,700 --> 00:12:43,720
+بنقوله ان الـcyclopentane is not a planar molecule
+
+155
+00:12:43,720 --> 00:12:48,820
+it is like an open envelopeزي المكتوب المفتوح الآن
+
+156
+00:12:48,820 --> 00:12:52,520
+بتلاحظوا معنى برضه أنه فيه عشر Hydrogens
+
+157
+00:12:52,520 --> 00:12:56,000
+equivalent لكن لما بدنا نشيل أكتر من Hydrogens
+
+158
+00:12:56,000 --> 00:13:00,420
+دنتين أو تلاتة بيصير عندى عدد كبير من ال isomers
+
+159
+00:13:00,420 --> 00:13:05,900
+يمكن أنه تجربوها ع الورق وتحسبوها بشكل كامل لكن
+
+160
+00:13:05,900 --> 00:13:11,720
+بشكل عام هذا هو شكل ال Cyclopentane it is like an
+
+161
+00:13:11,720 --> 00:13:15,950
+open envelopeهيكوا شايفين القاعدة وهذا الجزء اللي
+
+162
+00:13:15,950 --> 00:13:22,330
+هو يمثل المظروف المفتوح الـ Open Envelope بننتقل
+
+163
+00:13:22,330 --> 00:13:27,930
+الآن للشكل التالي اللي هو الـ Cyclohexane اللي فيه
+
+164
+00:13:27,930 --> 00:13:31,910
+6 ذرات كربون طبعا ربما البعض يعتقد ان الـ
+
+165
+00:13:31,910 --> 00:13:36,620
+Cyclohexaneماخد الشكل البلانر زي ما بيبدو على
+
+166
+00:13:36,620 --> 00:13:40,800
+الشاشة لكن الحقيقة في التجربة أو في الواقع لأ
+
+167
+00:13:40,800 --> 00:13:44,780
+الشكل مابيجيش بلانر الـ 6 ذرات كربون مابيجيش بلانر
+
+168
+00:13:44,780 --> 00:13:50,440
+لكن بياخد عدة أشكال من هذه الأشكال اللي ممكن
+
+169
+00:13:50,440 --> 00:13:54,940
+ياخدها الـ Cyclohexane إذا بنركز احنا على ذرات
+
+170
+00:13:54,940 --> 00:13:59,440
+الكربون اللي بيظهروا عندنا باللون الأسود هنا هاي
+
+171
+00:13:59,440 --> 00:14:04,980
+واحد، اتنين، تلاتةأربعة، خمسة، ستة يعني نتخيل
+
+172
+00:14:04,980 --> 00:14:08,160
+الهيكل الكربوني اللي هو الذرات السود اللي محمولين
+
+173
+00:14:08,160 --> 00:14:13,300
+بالروابط البيضة إذا بنلاحظ هذا الشكل اللي موجود هو
+
+174
+00:14:13,300 --> 00:14:17,560
+شكل بهذا الشكل و بهذا الشكل و بهذا الشكل طالع لفوق
+
+175
+00:14:17,560 --> 00:14:22,380
+هيواضح واحد، اتنين، تلاتة الآن مين يقولنا هذا
+
+176
+00:14:22,380 --> 00:14:26,350
+الشكل يشبه ماذا؟خلّي تركيزنا فقط على الكرات
+
+177
+00:14:26,350 --> 00:14:31,850
+السوداء والروابط البيضاء هذا الشكل حقيقة هو شكل
+
+178
+00:14:31,850 --> 00:14:37,530
+يشبه القارب يشبه القارب تماما بهذا الشكل واضح؟
+
+179
+00:14:37,530 --> 00:14:44,070
+ولذلك الـ Cyclohexane بهذه الهيئة اللي مرسوم فيها
+
+180
+00:14:44,070 --> 00:14:51,340
+بنسميه احناماخد الـ Boat Conformation هيئة القارب
+
+181
+00:14:51,340 --> 00:14:55,160
+ماخد الـ Boat Conformation لاحظوا هذا الـ Boat
+
+182
+00:14:55,160 --> 00:15:00,360
+Conformation اللي ماخده الـ Cyclohexane فيه مشكلة
+
+183
+00:15:00,360 --> 00:15:04,320
+ايش المشكلة اللي فيه؟المشكلة اللي فيه إذا نظرنا
+
+184
+00:15:04,320 --> 00:15:08,380
+للهيدروجين و أنا .. أنا حاطه بألوان مختلفة بلاحظ
+
+185
+00:15:08,380 --> 00:15:12,520
+إنه الهيدروجين اللي على هذا الرأس للقارب و
+
+186
+00:15:12,520 --> 00:15:16,180
+الهيدروجين اللي على هذا الرأس نوعا ما قريب من بعض
+
+187
+00:15:16,180 --> 00:15:23,400
+يعني بنقدر نسمع صوتهم يعني ممكن يخبطوا في بعض هدول
+
+188
+00:15:23,400 --> 00:15:27,300
+الهيدروجين قريب من بعض إيش معنى الهيدروجين قريب من
+
+189
+00:15:27,300 --> 00:15:34,330
+بعض؟إنه بيخلّي شكل الـ Bot Conformation شكل الثبات
+
+190
+00:15:34,330 --> 00:15:38,990
+عنده مش عالي It is not stable confirmation طيب،
+
+191
+00:15:38,990 --> 00:15:44,690
+كيف ممكن أعمل شكل أبعد هدول عن بعض؟ بتعرفوا دائما،
+
+192
+00:15:44,690 --> 00:15:48,910
+المبدأ في الأشكال الهندسية في الكيميا قدر الإمكان
+
+193
+00:15:48,910 --> 00:15:53,930
+إن الذرات تتبعد عن بعض، تتفسحزي ما بتقول الآية
+
+194
+00:15:53,930 --> 00:15:57,230
+أيها الذين آمنوا إذا قيل لكم تفسحوا في المجالس
+
+195
+00:15:57,230 --> 00:16:02,470
+فافسحوا يفسح الله لكم الآن بحركوا بهذا الشكل
+
+196
+00:16:02,470 --> 00:16:07,810
+بحاولوا من هيئة القارب اللي إحنا شايفينها واضحة
+
+197
+00:16:07,810 --> 00:16:12,390
+تماما الهيئة التانية هذه الهيئة التانية إذا بنتطلع
+
+198
+00:16:12,390 --> 00:16:19,950
+عليها بنلاحظ إنها مميزة بالآتي إن أنا في عندهطبعا
+
+199
+00:16:19,950 --> 00:16:23,590
+ال models نوعا ما بتساعد و بأمل أنها بتساعد في
+
+200
+00:16:23,590 --> 00:16:28,690
+عندي ما يشبه القاعدة في عندي ما يشبه الظهر و في
+
+201
+00:16:28,690 --> 00:16:33,430
+عندي ما يشبه الرجلين إذا أنا صرت أمام هيئة شبيهة
+
+202
+00:16:33,430 --> 00:16:37,670
+بهيئة الكرسي هذا الكرسي إذا بتلاحظوا الإيد الشمال
+
+203
+00:16:37,670 --> 00:16:43,230
+اللي عندي ماسك الظهر تبعه الإيد اليمين ماسك الرجل
+
+204
+00:16:43,230 --> 00:16:50,480
+تبعتهاللي موجود في الوسط هو المكان الجلوس في
+
+205
+00:16:50,480 --> 00:16:55,900
+الكرسي هذه الهيئة بيسموها الـ Chair Conformation
+
+206
+00:16:55,900 --> 00:16:59,580
+هذه الهيئة بيسموها الـ Chair Conformation هيئة
+
+207
+00:16:59,580 --> 00:17:04,640
+الكرسي طبعا موجودة عندكم على الشاشة هيئة القارب
+
+208
+00:17:04,640 --> 00:17:07,740
+الـ Boat Conformation موجود عندكم على الشاشة هيئة
+
+209
+00:17:07,740 --> 00:17:13,730
+الكرسي الآن إذا أنا بتطلع على هيئة الكرسيلاحظوا أن
+
+210
+00:17:13,730 --> 00:17:18,630
+الـ 12 هيدروجينة لأن الـ Cyclohexane C6H12 مقسمين
+
+211
+00:17:18,630 --> 00:17:24,660
+إلى نوعين من الهيدروجينالـ 12 هيدروجينة مقسمين إلى
+
+212
+00:17:24,660 --> 00:17:29,740
+نوعين في هيئة الكرسي في عندي الـ Hydrogens اللي
+
+213
+00:17:29,740 --> 00:17:34,720
+لونهم أخضر باللاحظ أنه موجودين تلاتة للأعلى و
+
+214
+00:17:34,720 --> 00:17:38,580
+تلاتة للأسفل طبعا بزام عموديات سواء للأعلى أو
+
+215
+00:17:38,580 --> 00:17:43,660
+للأسفل بقول عنهم Axial Axial يعني عموديات إذا أنا
+
+216
+00:17:43,660 --> 00:17:52,960
+عندي6 Axial Hydrogen 3 above the molecule 1 2 3
+
+217
+00:17:52,960 --> 00:17:58,260
+and 3 below the molecule 1 2 3 الباقيين اللي هم
+
+218
+00:17:58,260 --> 00:18:03,190
+ماخدين اللون البرتقالي هدول بشكل عامجايين باتجاه
+
+219
+00:18:03,190 --> 00:18:08,830
+جانبي الـ 6، 1، 2، 3، 4، 5، 6، نوعًا ما ماخدين
+
+220
+00:18:08,830 --> 00:18:12,750
+الوضع الجانبي لكن لما تتطلعوا بوضوح وين التلاتة
+
+221
+00:18:12,750 --> 00:18:17,490
+اللي هم أكتر عموديات للأعلى، بالذات لما يكون ثابت
+
+222
+00:18:17,490 --> 00:18:20,730
+الشكل ما بيغلبناش، هايهم، شايفين التلاتة الخضر؟
+
+223
+00:18:21,290 --> 00:18:25,510
+واضحين جداً هدولة التلاتة الخضر اللي هما الـ axial
+
+224
+00:18:25,510 --> 00:18:30,370
+تلاتة فوق و تلاتة تحت والباقيين الستة equatorial
+
+225
+00:18:30,370 --> 00:18:36,550
+إذا الـ 12 هيدروجين يقسموا إلى 6 axial hydrogens 3
+
+226
+00:18:36,550 --> 00:18:39,710
+above the molecule and 3 below the molecule and
+
+227
+00:18:39,710 --> 00:18:45,110
+another 6 equatorial hydrogens let's say in the
+
+228
+00:18:45,110 --> 00:18:49,710
+plane of the moleculeالان هذا الشكل اللي انا عمال
+
+229
+00:18:49,710 --> 00:18:54,230
+رسمه و بقول هي الظاهر تبعه موجود بإيد الشمال انا
+
+230
+00:18:54,230 --> 00:18:59,890
+ماسكه و القاعدة موجودة باليد اليمنى يمكن ان اعمله
+
+231
+00:18:59,890 --> 00:19:03,350
+flipping اجلبه زي ما بتجلب الشمسية بتلاعبوا كيف
+
+232
+00:19:03,350 --> 00:19:06,870
+بتجلب الشمسية في الهواء ممكن اجلبه هذا الظاهر
+
+233
+00:19:06,870 --> 00:19:14,230
+اخليه يمثل الرجلين اللي تحت وهذا الرجلين اجلبهم
+
+234
+00:19:14,230 --> 00:19:18,800
+يمثلوا الظاهر اللي الاعلىلاحظوا هنا أنا جلبتهم
+
+235
+00:19:18,800 --> 00:19:23,680
+بهذا الشكل الجميل صار عندى هي اليد اليمين ماسكة
+
+236
+00:19:23,680 --> 00:19:28,120
+الظهر واليد الشمال ماسكة الرجل اللى تحت هنا
+
+237
+00:19:28,120 --> 00:19:32,480
+بتلاحظوا ملاحظة ان ال hydrogens الخضر اللى كانوا
+
+238
+00:19:32,480 --> 00:19:37,120
+axial صاروا equatorial و ال hydrogens اللى مبينين
+
+239
+00:19:37,120 --> 00:19:40,560
+بورتغاني اللى كانوا مبينين على الجنب equatorial
+
+240
+00:19:40,560 --> 00:19:46,370
+صاروا axial تلاتة فوقالتلاتة تحت، إذا عملية الـ
+
+241
+00:19:46,370 --> 00:19:50,010
+flipping هنا في هذا الجزء بتغلب الهيدروجينز الـ
+
+242
+00:19:50,010 --> 00:19:53,230
+axial hydrogen will be equatorial and the
+
+243
+00:19:53,230 --> 00:19:57,630
+equatorial hydrogen will be axial املاحظين هنا وين
+
+244
+00:19:57,630 --> 00:20:02,010
+ال axial؟ التلاتة البوردجانياتوين الـ equatorial
+
+245
+00:20:02,010 --> 00:20:07,210
+صاروا النوع الأخضر لما بعمله flipping بنعكسه الآن
+
+246
+00:20:07,210 --> 00:20:11,990
+أي الأشكال أثبت لـ Chair Conformation هيئة الكرسي
+
+247
+00:20:11,990 --> 00:20:16,370
+و لا هيئة القارب؟ خلّيني أكد عليه السؤال، هذا سؤال
+
+248
+00:20:16,370 --> 00:20:20,600
+مهم أي الأشكال أثبتالـ Chair Conformation اللي
+
+249
+00:20:20,600 --> 00:20:23,340
+احنا عاملا مسكين و هيظهر و هيرجلين ولا الـ Boat
+
+250
+00:20:23,340 --> 00:20:27,000
+Conformation؟ احنا قلنا الـ Boat Conformation في
+
+251
+00:20:27,000 --> 00:20:31,820
+استدام لذرات الهيدروجين ببعض، إقراب من بعض ولذلك
+
+252
+00:20:31,820 --> 00:20:37,340
+يعتبر الـ Chair Conformation more stable than الـ
+
+253
+00:20:37,340 --> 00:20:41,220
+Boat Conformation واضح؟ الـ Chair Conformation of
+
+254
+00:20:41,220 --> 00:20:45,750
+Cyclohexane is more stablethan the bot
+
+255
+00:20:45,750 --> 00:20:51,090
+confirmation الان لو اتخيلنا ان احنا كل اللي موجود
+
+256
+00:20:51,090 --> 00:20:55,810
+عندنا هيدروجين و بدنا نرفع هيدروجين و نحط بدالها
+
+257
+00:20:55,810 --> 00:21:02,170
+مجموعة مثل جروب هاي مجموعة مثل انماسكا CH3 مش هذه
+
+258
+00:21:02,170 --> 00:21:07,850
+مجموعة المثل الان لاحظوا لو شيلت هذه الهيدروجين و
+
+259
+00:21:07,850 --> 00:21:16,140
+حطيت بدالهامجموعة الميثل CH3 وهي ماسك الجزء،
+
+260
+00:21:16,140 --> 00:21:20,100
+لاحظوا هيظهر على الإيد اليمين والرجل في الإيد
+
+261
+00:21:20,100 --> 00:21:24,780
+اليسرى، إيش بتلاحظوا هنا في هذا الشكل؟ إن الميثل
+
+262
+00:21:24,780 --> 00:21:32,360
+جروب لو كانت Axial، بتبدأ تصير قريبة من
+
+263
+00:21:32,360 --> 00:21:38,910
+الـHydrogensولذلك لاحظوا هاي التلاتة axials H وH
+
+264
+00:21:38,910 --> 00:21:43,210
+ومثل لكن المثل أجمالها صارت قريبة من ال hydrogens
+
+265
+00:21:43,210 --> 00:21:48,910
+طيب لو لفيت الجزيق لو لفيت الجزيق بهذا الشكل
+
+266
+00:21:48,910 --> 00:21:55,370
+هينرجعت الذرات اللي لونهم أخضر يكونوا axialزي ما
+
+267
+00:21:55,370 --> 00:21:59,430
+بتلاحظوا هيوم التلاتة الخضر انبينين أقرب شق لكم
+
+268
+00:21:59,430 --> 00:22:03,070
+Axial وين صارت الـ Methyl group؟ صارت الـ Methyl
+
+269
+00:22:03,070 --> 00:22:06,950
+group equatorial الآن وين الـ Methyl group عاملة
+
+270
+00:22:06,950 --> 00:22:11,410
+مشاكل أكتر؟ تكون equatorial ولا Axial؟ بالتأكيد
+
+271
+00:22:11,410 --> 00:22:14,690
+لما بتكون equatorial مافيش إش تصطدم معه، تتنافر
+
+272
+00:22:14,690 --> 00:22:18,730
+معه لكن لما كانت Axial شوفنا إنها جريبة من two
+
+273
+00:22:18,730 --> 00:22:24,310
+other hydrogensولذلك الـ methylcyclohexane بفضل
+
+274
+00:22:24,310 --> 00:22:28,810
+يكون بالـ circle formation والـ methyl group تكون
+
+275
+00:22:28,810 --> 00:22:33,690
+في الـ equatorial position بأكد الـ methyl group
+
+276
+00:22:33,690 --> 00:22:37,750
+وين أفضل تكون؟ في ال axial ولا في ال equatorial؟
+
+277
+00:22:38,500 --> 00:22:42,380
+الـ methyl group بتفضل تكون في الـ equatorial
+
+278
+00:22:42,380 --> 00:22:46,080
+position هي شايفين أين جاية؟ على الجانب في ال
+
+279
+00:22:46,080 --> 00:22:49,860
+equatorial position مش في ال Axial position ولذلك
+
+280
+00:22:49,860 --> 00:22:55,100
+هدول الشكلين النسبة بينهم حقيقةفي الـ Cyclohexane
+
+281
+00:22:55,100 --> 00:22:59,680
+بتكون 95% من الوقت الـ methyl group في الـ
+
+282
+00:22:59,680 --> 00:23:04,280
+equatorial position و فقط 5% من الوقت في الـ axial
+
+283
+00:23:04,280 --> 00:23:07,220
+position لأنه لما بتكون في الـ axial position
+
+284
+00:23:07,220 --> 00:23:12,680
+بتكون عملت نافر مع الـ hydrogen أو الـ two
+
+285
+00:23:12,680 --> 00:23:17,370
+hydrogens اللي موجودين إقراب منهاطبعًا انتبهوا معي
+
+286
+00:23:17,370 --> 00:23:21,190
+في أكبر من الـ methyl group يعني لو أنا بدي أشيل
+
+287
+00:23:21,190 --> 00:23:25,970
+الـ methyl group هذه وأحط بدالها أكبر group في الـ
+
+288
+00:23:25,970 --> 00:23:28,910
+organic chemistry اللي هي tertiary-butyl الأربع
+
+289
+00:23:28,910 --> 00:23:35,270
+كربونات سبق أخدناها كربون متفرع منها مثل و مثل و
+
+290
+00:23:35,270 --> 00:23:39,290
+مثل هذه إيش بنسميها المجموعة هي موجودة tertiary
+
+291
+00:23:39,290 --> 00:23:44,750
+-butyl أربع كربونات واحد اتنين تلاتة أربعةهذه
+
+292
+00:23:44,750 --> 00:23:49,530
+المجموعة ترتشير بيوتل لما بدأت أحطها اتخيلوا قداش
+
+293
+00:23:49,530 --> 00:23:54,390
+انا بتريح لو حطيت هذه المجموعة في ال equatorial
+
+294
+00:23:54,390 --> 00:23:58,590
+position بتعملش عندي مشاكل هاي الشكل اللي عنده
+
+295
+00:23:58,590 --> 00:24:04,410
+واضح تماما التلت مجموعات ال axial اللي هي واحدة
+
+296
+00:24:04,410 --> 00:24:08,370
+تنتين تلاتة الآن هنا هذه ال tertiary butyl في أي
+
+297
+00:24:08,370 --> 00:24:12,480
+مستوىفي الـ equatorial هي في مستوى الجزيئة مش جاية
+
+298
+00:24:12,480 --> 00:24:18,000
+عمودية ولذلك هذا الجزيئ بيكون بنسبة مية في المية
+
+299
+00:24:18,000 --> 00:24:21,440
+tertiary butyl group جاية على ال equatorial
+
+300
+00:24:21,440 --> 00:24:25,740
+position اتخيلوا لو كنا بدنا نلفه و نحطها على ال
+
+301
+00:24:25,740 --> 00:24:29,880
+axial position خليني نعمل يعني هذا بدل ما هو ظهر
+
+302
+00:24:29,880 --> 00:24:33,980
+الكرسي نخليه رجل و هذا بدل ما هو رجل الكرسي اللي
+
+303
+00:24:33,980 --> 00:24:40,070
+لتحت نخليها ظهر هي ده خلينها ظهر و هذهخلناها الـ
+
+304
+00:24:40,070 --> 00:24:44,340
+«ريتشار»الان اتخيلوا هذه الـ tertiary-butyl group
+
+305
+00:24:44,340 --> 00:24:50,100
+هى هى إيش عاملة هنا مشاكل؟ وإيش عاملة هنا مشاكل؟
+
+306
+00:24:50,100 --> 00:24:54,320
+بتبدأ تصطدم .. بتبدأ تصطدم مع الـhydrogens اللى
+
+307
+00:24:54,320 --> 00:24:59,180
+موجودين هنا وهنا ولذلك هل يفضل إنه هذه .. هى الشكل
+
+308
+00:24:59,180 --> 00:25:03,460
+الكرسي ممتاز جدا بهذا الشكل؟ والـtertiary-butyl
+
+309
+00:25:03,460 --> 00:25:07,040
+على الـaxial؟ هنا على الـaxial نسبتها 0% لإنها
+
+310
+00:25:07,040 --> 00:25:12,640
+بتعمل مشاكل مع الـhydrogens لجرابسمعين؟ هاي مع الـ
+
+311
+00:25:12,640 --> 00:25:18,140
+hydrogen لغريبة بتعمل مشاكل واضح؟ ولذلك بتكون الـ
+
+312
+00:25:18,140 --> 00:25:22,900
+tertiary-butyl بنسبة 0% بهذا الشكل الأكسي لغريبة
+
+313
+00:25:22,900 --> 00:25:29,120
+هي عمال بتصطدم بالـhydrogens وبتفضل أن الجزء ألف
+
+314
+00:25:29,120 --> 00:25:35,550
+نفسه بحيث أنه هي تصيرفي الـ equatorial position هي
+
+315
+00:25:35,550 --> 00:25:38,430
+الآن لما راحت على ال equatorial position وهي دهر
+
+316
+00:25:38,430 --> 00:25:42,270
+الكرسي لاحظوا هنا عاملة مشاكل في ال equatorial
+
+317
+00:25:42,270 --> 00:25:47,110
+position لأ وين بتعمل مشاكل لما تكون في ال axial
+
+318
+00:25:47,110 --> 00:25:49,670
+position هي ال equatorial position
+
+319
+00:25:53,290 --> 00:25:56,190
+هي الـ equatorial position الـ tertiary butyl
+
+320
+00:25:56,190 --> 00:26:01,450
+طالعة فيه لبرا مش عاملة عندي مشاكل ولذلك لما بدأ
+
+321
+00:26:01,450 --> 00:26:04,490
+أقول قداش نسبة ال tertiary butyl في ال equatorial
+
+322
+00:26:04,490 --> 00:26:10,150
+و ال axial بقول في ال equatorial 100% بال axial 0%
+
+323
+00:26:10,150 --> 00:26:15,830
+لأنها بتعمل تنافرمع ذرات الهيدروجين التانيات اللي
+
+324
+00:26:15,830 --> 00:26:20,310
+موجودين عنده لو كانت في الـ Axial Position هذا
+
+325
+00:26:20,310 --> 00:26:25,870
+بشكل عام ملخص عن الـ Cycloalkanes هذا بشكل عام
+
+326
+00:26:25,870 --> 00:26:29,470
+ملخص عن الـ Cycloalkanes أخدنا فيه الـ
+
+327
+00:26:29,470 --> 00:26:34,430
+Cyclopropane الـ Cyclobutane الـ Cyclopentane والـ
+
+328
+00:26:34,430 --> 00:26:35,610
+Cyclohexane
+
+329
+00:26:37,740 --> 00:26:43,920
+طبعاً بنختم بشغلة بسيطة أنه بشكل عام الـ alkanes و
+
+330
+00:26:43,920 --> 00:26:50,560
+الـ cycloalkanes هل لهم تفاعلات؟ الجواب أنه بشكل
+
+331
+00:26:50,560 --> 00:26:54,240
+عام يعتبروا الـ alkanes و الـ cycloalkanes inert
+
+332
+00:26:54,240 --> 00:26:58,680
+يعني تفاعلاتهم قليلة جدا و لذلك كثيرا ما تستخدم
+
+333
+00:26:58,680 --> 00:27:03,900
+الـ alkanes و الـ cycloalkanes as solventsمشهور
+
+334
+00:27:03,900 --> 00:27:09,380
+لهم تفاعلين فقط للـ Alkanes اللي هو تفاعل الـ
+
+335
+00:27:09,380 --> 00:27:14,440
+Combustion انه احنا الـ Alkanes بنحرقهم بنطلع ثانو
+
+336
+00:27:14,440 --> 00:27:19,060
+أكسيد كربون وميه و الناتج الأهم ربما اللي مش مكتوب
+
+337
+00:27:19,060 --> 00:27:24,210
+هنا هو حرارةبديش أنا أنسى إنه البنزين تبع السيارات
+
+338
+00:27:24,210 --> 00:27:28,110
+الجازولين أو ال fuel هو عبارة عن خليط من الهيبتين
+
+339
+00:27:28,110 --> 00:27:31,810
+والأيزو أكتين لما أنا بحرقه بموتور السيارة بطلع
+
+340
+00:27:31,810 --> 00:27:36,490
+عندي ثانوكسيد كربون ومية وحرارة الناتج المهم إليه
+
+341
+00:27:36,490 --> 00:27:41,860
+في موتور السيارة شو هو؟الحرارة الناتج الدار واللي
+
+342
+00:27:41,860 --> 00:27:45,300
+بيعمل الـ greenhouse effect المشكلة البيئية
+
+343
+00:27:45,300 --> 00:27:50,420
+الكبيرة هو ثاني أكسيد الكربون واضح؟ طبعا احنا
+
+344
+00:27:50,420 --> 00:27:55,440
+مضطرين نستعمل الجازولين كوقود للسيارات لأن احنا
+
+345
+00:27:55,440 --> 00:27:59,870
+بدنا ال energy أو الطاقةهذا بالنسبة لتفاعل ال
+
+346
+00:27:59,870 --> 00:28:04,230
+combustion ومعنى combustion burning in the
+
+347
+00:28:04,230 --> 00:28:09,310
+presence of oxygen الحرق في وجود ال oxygen يعني في
+
+348
+00:28:09,310 --> 00:28:12,890
+السيارة لما أنا بحرق البنزين بحرق البنزين لحاله
+
+349
+00:28:12,890 --> 00:28:17,310
+ولا فيه oxygenلأ في Oxygen و لازم تكون النسبة
+
+350
+00:28:17,310 --> 00:28:22,330
+دقيقة جدا ما بين البنزين و ما بين الهواء اللي فيه
+
+351
+00:28:22,330 --> 00:28:25,930
+ال Oxygen و الجزء في السيارة اللي بنظم هذا الكلام
+
+352
+00:28:25,930 --> 00:28:28,650
+أكيد نسبة كبيرة منكم بتعرف اللي بيسموه ال
+
+353
+00:28:28,650 --> 00:28:34,490
+Carburetor و لو صار في خلل ما بين نسبة الوقودوالـ
+
+354
+00:28:34,490 --> 00:28:40,330
+Oxygen بيصير مشاكل ممكن يؤدي إلى عدم احتراق كامل
+
+355
+00:28:40,330 --> 00:28:45,270
+للبنزين ويصير يطلع من السيارة دخان أسود دليل على
+
+356
+00:28:45,270 --> 00:28:49,930
+أنه البنزين لم يتم أو الوقود لم يتم حرقه بشكل
+
+357
+00:28:49,930 --> 00:28:53,570
+كامل، واضح؟ فالتفاعل الأول لل Alkanes هو ال
+
+358
+00:28:53,570 --> 00:28:57,440
+combustion، الحرق في وجود ال Oxygenالان التفاعل
+
+359
+00:28:57,440 --> 00:29:01,640
+الثاني الـ halogenation ان انا اي الكان يعني لو
+
+360
+00:29:01,640 --> 00:29:05,660
+افترضت مثلا انه عندى ميثين هذا الميثين اللى انا
+
+361
+00:29:05,660 --> 00:29:11,820
+ماسكه الان بايدى ممكن اعمله ابدال بذرات معينة يعني
+
+362
+00:29:11,820 --> 00:29:16,940
+ممكن ابدله مثلا بذرة كلورين يعني اشيل هيدروجين
+
+363
+00:29:16,940 --> 00:29:22,120
+وابدله بكلور صار ايش اسمه كلور وميثين ممكن اشيل
+
+364
+00:29:22,120 --> 00:29:25,650
+الهيدروجين التانى وابدله بكمان كلورصار
+
+365
+00:29:25,650 --> 00:29:29,630
+دايكلوروميثين ممكن أشيل الهيدروجين التالتة وأبدل
+
+366
+00:29:29,630 --> 00:29:33,330
+بكلور صار تريكلوروميثين اللي إله اسم شورا
+
+367
+00:29:33,330 --> 00:29:37,290
+كلوروفورم CHCl3
+
+368
+00:29:37,290 --> 00:29:42,810
+وممكن أشيل الهيدروجين الرابعة وأبدل مثلا بكلور صار
+
+369
+00:29:42,810 --> 00:29:48,130
+ال carbon tetrachloride أو ال tetrachlorocarbon
+
+370
+00:29:48,430 --> 00:29:52,550
+أذا تفاعل تاني مشهور عن الـ Alkanes اللي هو تفاعل
+
+371
+00:29:52,550 --> 00:29:55,830
+الـ Substitution لما أنا بفعل الـ Alkanes مع الـ
+
+372
+00:29:55,830 --> 00:30:02,790
+Halogens و هذا التفاعل بيلزم وجود حرارة أو ضوء شمس
+
+373
+00:30:02,790 --> 00:30:06,790
+حتى يتم التفاعل إذا الـ Alkanes بتفاعل مع الـ
+
+374
+00:30:06,790 --> 00:30:11,330
+Halogens في وجود الضوء أو الحرارة بيصير عندى إبدال
+
+375
+00:30:11,330 --> 00:30:14,490
+و ممكن أكتر من إبدال يعني ممكن إبدال اتنين تلاتة
+
+376
+00:30:14,490 --> 00:30:20,170
+أربعة و طبعالما يكون الجزء الكبير بيصير عندى عدد
+
+377
+00:30:20,170 --> 00:30:26,280
+كبير من المتشكلات اللى يمكن أن تنتجهذه عملية
+
+378
+00:30:26,280 --> 00:30:31,020
+الـhalogenation طبعاً في إلها آلية في إلها آلية
+
+379
+00:30:31,020 --> 00:30:35,960
+بتتم فيها هذه الآلية بتفترض الآتي إذا إحنا بدنا
+
+380
+00:30:35,960 --> 00:30:42,040
+باختصار نحكي عن الـ mechanism of halogenation يعني
+
+381
+00:30:42,040 --> 00:30:46,680
+كيف بتتم عملية الـhalogenation الـhalogenation
+
+382
+00:30:46,680 --> 00:30:50,160
+خلينا نفترض إن هو إننا الميثين وفي عندنا
+
+383
+00:30:50,160 --> 00:30:58,770
+الـhalogen اللي هو الكلورهذا الكلور موجود كجزء على
+
+384
+00:30:58,770 --> 00:31:05,530
+شكل Cl2 هاي عندي الميثين وهي عندي جزء الكلور إيش
+
+385
+00:31:05,530 --> 00:31:10,910
+اللي بتتم؟ في الخطوة الأولى الحرارة بتكسر جزء
+
+386
+00:31:10,910 --> 00:31:16,270
+الكلور من النص الحرارة إيش بتعمل؟بتكسر جزء الكلور
+
+387
+00:31:16,270 --> 00:31:20,550
+من النص بيطلع إلكترون هنا و إلكترون هنا يعني كأنه
+
+388
+00:31:20,550 --> 00:31:24,910
+بيصير two free radical هذه كلور معقد إلكترون وهذه
+
+389
+00:31:24,910 --> 00:31:29,630
+كلور معقد إلكترون إذا الخطوة الأولى في الميكانزم
+
+390
+00:31:29,630 --> 00:31:35,920
+الحرارة أو الضوء بيكسربيكسر جزء الكلور بيعمله
+
+391
+00:31:35,920 --> 00:31:40,520
+homolysis كسر متجانس الرابطة إلكترونين هن بيجي
+
+392
+00:31:40,520 --> 00:31:44,680
+إلكترون و هن بيجي إلكترون بيطلع عنده two CL
+
+393
+00:31:44,680 --> 00:31:48,640
+radical معنى radical a carbon carrying an odd
+
+394
+00:31:48,640 --> 00:31:52,640
+electron او an atom carrying an odd electron ذرة
+
+395
+00:31:52,640 --> 00:31:56,660
+بتحمل إلكترون مفرد هين كانوا إلكترونين هن أجي واحد
+
+396
+00:31:56,660 --> 00:32:05,790
+و هن أجي واحدهذا الـ radical يتفاعل
+
+397
+00:32:05,790 --> 00:32:11,010
+مع الميثين ويأخذ منه هيدروجين لما يأخذ منه
+
+398
+00:32:11,010 --> 00:32:18,370
+هيدروجين لحظه يكلوره H إيش اتكون عنده جزء HClأول
+
+399
+00:32:18,370 --> 00:32:24,370
+شيء يتكوّن عندي جزء الـ HCl وباقي الجزء سارت
+
+400
+00:32:24,370 --> 00:32:27,530
+كاربون حاملة هيدروجين وهيدروجين وهيدروجين وقد
+
+401
+00:32:27,530 --> 00:32:29,970
+إلكترون يتفاعل مثل الـ Radical
+
+402
+00:32:37,530 --> 00:32:43,170
+Methyl Radical وHCl هذا الـ Methyl Radical بيجي
+
+403
+00:32:43,170 --> 00:32:47,910
+على جزء كلور تاني، هاي جزء كلور تاني، بياخد منه
+
+404
+00:32:47,910 --> 00:32:53,790
+ذرة كلور، بيكوّل لكلور وميثين في الخطوة التانية،
+
+405
+00:32:53,790 --> 00:32:56,330
+اتكوّل لكلور وميثين في الخطوة التانية، شو ضال
+
+406
+00:32:56,330 --> 00:33:03,010
+عنده؟ CL Radical، واضح؟ الـ CL Radical بيتفاعل من
+
+407
+00:33:03,010 --> 00:33:07,870
+أول وجديد مع جزء ميثين تاني، أنا هين كوّنت؟لاحظوا
+
+408
+00:33:07,870 --> 00:33:13,210
+الناتج اللي .. هاي خلاصة النواتج الأولى HCl زائد
+
+409
+00:33:13,210 --> 00:33:18,110
+Methylchloride خلصناه وطلع عنده CR Radical بتفعل
+
+410
+00:33:18,110 --> 00:33:21,630
+مع جزء Methane تاني بعيد نفس الكلام بيكون في الأول
+
+411
+00:33:21,630 --> 00:33:25,990
+HCl و Methyl Radical بعدين Methylchloride و بطلع
+
+412
+00:33:25,990 --> 00:33:32,670
+جزء Free Radical او Chlorine Atomتانية و بتتفاعل
+
+413
+00:33:32,670 --> 00:33:38,270
+كذا إذا هدولا الخطوتين متكررات كل مرة ببدأ ب free
+
+414
+00:33:38,270 --> 00:33:44,170
+radical او ب chlorine atom و بتتفاعل بتعمل HCl مثل
+
+415
+00:33:44,170 --> 00:33:48,510
+chloride و بطلع chlorine atom مرة تانية او radical
+
+416
+00:33:49,220 --> 00:33:53,060
+بتتفاعل مرة تانية و هكذا و هكذا هذا التفاعل ممكن
+
+417
+00:33:53,060 --> 00:33:58,240
+يتكرر أربع خمس تلاف مرة قبل ما يوقف بأي طريقة
+
+418
+00:33:58,240 --> 00:34:02,440
+بنسميها termination لاحظوا معي أن هذا التفاعل آلي
+
+419
+00:34:02,440 --> 00:34:06,980
+تمكون من تلت شغلات الشغلة الأولى أنه أنا كان أكون
+
+420
+00:34:06,980 --> 00:34:12,260
+عندي جزء كلورين إذا بتذكره أو أكسره لـ two
+
+421
+00:34:12,260 --> 00:34:15,060
+chlorine atoms هذه الخطوة بسميها أنا إيش؟
+
+422
+00:34:15,570 --> 00:34:20,370
+Initiation خطوة تحضيرية الشيء الثاني خطوتين
+
+423
+00:34:20,370 --> 00:34:26,070
+يتكرروا اللي بيعملوا الـHCl والـMethylchloride
+
+424
+00:34:26,070 --> 00:34:29,110
+وبيطلع Radical وبيعيد وبيعيد وبيعيد هذه خطوة
+
+425
+00:34:29,110 --> 00:34:33,690
+متكررة بنسميها chain propagating step خطوة متوالدة
+
+426
+00:34:33,690 --> 00:34:40,170
+متكاثرةبعد هيك في النهاية ممكن أنه يتم termination
+
+427
+00:34:40,170 --> 00:34:45,390
+للتفاعل من خلال تفاعل X radical مع X radical تاني
+
+428
+00:34:45,390 --> 00:34:48,950
+يعطيني X2 أو R radical مثلا مثل Radical مع مثل
+
+429
+00:34:48,950 --> 00:34:54,770
+Radical تاني يعطيني Ethaneأو R radical مع X
+
+430
+00:34:54,770 --> 00:34:58,790
+radical تانية من عدة دوائر بيكون موجود عنده طبعاً
+
+431
+00:34:58,790 --> 00:35:03,850
+في التفاعل يعطيني R X واضح؟ وبالتالي هذه الخطوات
+
+432
+00:35:03,850 --> 00:35:08,390
+بتوقف سلسلة تكاتر التفاعل بيسميها termination إذا
+
+433
+00:35:08,390 --> 00:35:12,670
+ال mechanism of reaction امكونة من تلت شغلات
+
+434
+00:35:13,410 --> 00:35:17,790
+Initiation خطوة تحضيرية تكوين الـ Free Radicals
+
+435
+00:35:17,790 --> 00:35:22,450
+Propagation الخطوة التكاثر والشغلة التالتة
+
+436
+00:35:22,450 --> 00:35:26,970
+Termination الخطوة انهاء التفاعل
+
+437
+00:35:29,620 --> 00:35:32,700
+الـ mechanism of the reaction لاحظوا مع الـ
+
+438
+00:35:32,700 --> 00:35:36,180
+mechanism هي خطوات تفصيلية احنا بنشوفهاش يعني
+
+439
+00:35:36,180 --> 00:35:40,460
+المعادلة بتكون عامة لكن جوا المعادلة في خطوات
+
+440
+00:35:40,460 --> 00:35:44,440
+تفصيلية عادة لا تكتب في المعادلة هي التي تسمى
+
+441
+00:35:44,440 --> 00:35:50,180
+mechanism فمعنى mechanism الـ detailed stepsCannot
+
+442
+00:35:50,180 --> 00:35:53,360
+be seen in the equation يعني لما انا بدي المعادلة
+
+443
+00:35:53,360 --> 00:35:58,340
+بقول Cl زي ميثين Cl و ميثين زي HCl هي المعادلة لكن
+
+444
+00:35:58,340 --> 00:36:01,680
+كيف اتكسر ال Cl؟ ايش اللي اتكون في الأول؟ ايش اللي
+
+445
+00:36:01,680 --> 00:36:04,740
+اتكون في التاني؟ هذه الخطوات التفصيلية اللي احنا
+
+446
+00:36:04,740 --> 00:36:09,260
+مابنشوفهاش بنسميها mechanism of the reaction
+
+447
+00:36:11,760 --> 00:36:16,120
+أخر شغل بنحكيها أنه لو أنا كنت بدأ أعمل إبدال على
+
+448
+00:36:16,120 --> 00:36:21,600
+مُركّب غير الميثين، يعني إيثين، بروبين، وأبدل one
+
+449
+00:36:21,600 --> 00:36:26,580
+hydrogen by إكلورين أو إبرومين أتم، two hydrogens
+
+450
+00:36:26,580 --> 00:36:31,780
+ممكن، للأصل يكون واضح عندكم تماماً إنه إحنا بنتوقع
+
+451
+00:36:31,780 --> 00:36:36,250
+أكثر من ناتج، يعني لو بننظر هنا إلى الشاشةفي حالة
+
+452
+00:36:36,250 --> 00:36:40,490
+البروبين كاربون تنتين تلاتة لو بدي أقول الـ
+
+453
+00:36:40,490 --> 00:36:43,450
+Monochloroproducts يعني لو بس بدي أبدل الهيدروجين
+
+454
+00:36:43,450 --> 00:36:47,170
+بكلورة ممكن الكلورة تيجي على الذرة الأولى ويصير
+
+455
+00:36:47,170 --> 00:36:52,830
+عند المركب اللي هو وانكلوروبروبينو ممكن الكلور
+
+456
+00:36:52,830 --> 00:36:56,170
+تيجي على الذرع الثانية و يصير عند المُركّب اللي
+
+457
+00:36:56,170 --> 00:37:00,970
+اسمه two-chloropropen طبعا ك common names هذا اسمه
+
+458
+00:37:00,970 --> 00:37:03,850
+anipropyl لأنه دي مجموعة لبروبيل anipropyl
+
+459
+00:37:03,850 --> 00:37:09,190
+chloride و هذا اسمه isopropyl chloride إذا لو بدأ
+
+460
+00:37:09,190 --> 00:37:12,410
+أقول من البروبين الـ monochloroproducts المتوقع
+
+461
+00:37:12,410 --> 00:37:15,510
+كام ناتج اتنين ال one-chloroproduct و ال two
+
+462
+00:37:15,510 --> 00:37:19,410
+-chloroproduct الآن لو قلت بدي أبدل ذرتين هيدروجين
+
+463
+00:37:19,410 --> 00:37:24,100
+بكلور كام ناتج ممكن يطلع عنده؟ممكن ذرتين الكلور
+
+464
+00:37:24,100 --> 00:37:28,760
+يجعل الكربون الأولى، بطلع one-one-dichloropropane،
+
+465
+00:37:28,760 --> 00:37:33,680
+ممكن التنتين يجعل الكربون الثانيةبطلع 2-2
+
+466
+00:37:33,680 --> 00:37:37,260
+-Dichlorobrobin ممكن واحدة تيجي على الـ Carbon
+
+467
+00:37:37,260 --> 00:37:41,580
+الأولى و واحدة على التانية بطلع 1-2-Dichlorobrobin
+
+468
+00:37:41,580 --> 00:37:45,160
+و ممكن واحدة تيجي على الـ Carbon الأولى و التانية
+
+469
+00:37:45,160 --> 00:37:49,760
+على الـ Carbon التالتة بطلع 1-3-Dichlorobrobin إذا
+
+470
+00:37:49,760 --> 00:37:54,880
+عمال من الـ Dichlorobrobin أنا شايف أربع مركبات و
+
+471
+00:37:54,880 --> 00:37:59,020
+من الـ 1-Chlorobrobin شايف مركبين طبعا واضح أن
+
+472
+00:37:59,020 --> 00:38:03,300
+هدولة Isomersو الـ Structural Isomers بيختلفوا في
+
+473
+00:38:03,300 --> 00:38:06,340
+مواقع الروابط هان الكلور ع موقع واحد هان الكلور ع
+
+474
+00:38:06,340 --> 00:38:09,880
+موقع اتنين او هان ذرتين كلور ع موقع واحد هان ذرتين
+
+475
+00:38:09,880 --> 00:38:12,960
+كلور ع موقع اتنين هان ذرة ع واحد ذرة ع اتنين هان
+
+476
+00:38:12,960 --> 00:38:17,300
+ذرة ع واحد ذرة ع تلاتة هاد هي ال isomers او ال
+
+477
+00:38:17,300 --> 00:38:21,300
+structural isomers المفروض انه يصير عندكوا تدريب
+
+478
+00:38:21,300 --> 00:38:25,120
+لو قلنالكوا اعملوا ابدال بذرة واحدة بذرتين على
+
+479
+00:38:25,120 --> 00:38:29,770
+البيوتين مثلا ممكن تاخدوه ك homeworkكم
+
+480
+00:38:29,770 --> 00:38:34,990
+Monochloroproduct وكم Diachloroproduct ممكن أتوقع
+
+481
+00:38:34,990 --> 00:38:38,290
+من مُركّب البيوتين شكراً
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c417358df3cef16f0b1e16ee1ba4a9e78a07f56a
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_postprocess.srt
@@ -0,0 +1,1640 @@
+1
+00:00:11,180 --> 00:00:16,920
+بسم الله الرحمن الرحيم المرة
+
+2
+00:00:16,920 --> 00:00:21,300
+الماضية أخدنا فكرة عن الأحماض وتسميتهم و عن تحديدا
+
+3
+00:00:21,300 --> 00:00:28,610
+يمكن كمانالحمضية و تأثرها بعاملين أساسيين اللي هم
+
+4
+00:00:28,610 --> 00:00:33,070
+ال resonance effect و ال inductive effect واضح؟
+
+5
+00:00:33,510 --> 00:00:39,550
+الان بسبب الحامضية خلّيني أقول العالية نسبيا لل
+
+6
+00:00:39,550 --> 00:00:44,490
+carboxylic acids بنلاحظ أنهم يتفاعلوا مع ال bases
+
+7
+00:00:44,490 --> 00:00:49,870
+و مع weak bases كمان هذا الكلام مختلف عن الكحولات
+
+8
+00:00:49,870 --> 00:00:55,010
+يعني الكحولات لما كنا نقول الكحولvery weak acid
+
+9
+00:00:55,010 --> 00:00:58,590
+لما كنا نيجي نفعله مع sodium hydroxide مايتفعلش
+
+10
+00:00:58,590 --> 00:01:02,950
+كنا بدنا very strong base زي ال sodium metal بينما
+
+11
+00:01:02,950 --> 00:01:08,590
+الأحماض لو بنفعلها مع bases حتى لو كانت من مستوى
+
+12
+00:01:08,590 --> 00:01:13,610
+خلينا نقول ال sodium carbonateيعني الكربونة
+
+13
+00:01:13,610 --> 00:01:20,010
+العادية اللي هي تعتبر weak base بتتفاعل واضح؟ فمن
+
+14
+00:01:20,010 --> 00:01:23,390
+باب أولى بالتأكيد الأحماض هيتفاعلوا مع ال sodium
+
+15
+00:01:23,390 --> 00:01:29,790
+hydroxide التفاعل مشهور هو تفاعل حمض وقاعدة ملح
+
+16
+00:01:29,790 --> 00:01:36,070
+وماء فلو كان عندى أي carboxylic acid مع strong
+
+17
+00:01:36,070 --> 00:01:40,250
+base وحتى مع weak base كمان هلاحظ انه بتتفاعل
+
+18
+00:01:41,100 --> 00:01:45,440
+بيعطينا ال salt في هذه الحالة ال salt هذا بنسميه
+
+19
+00:01:45,440 --> 00:01:51,800
+sodium carboxylate لحظوا النهاية ate هذه ate
+
+20
+00:01:51,800 --> 00:01:58,300
+مرتبطة بالأيونات السالبة يعني الأيونات السالبة
+
+21
+00:01:58,300 --> 00:02:03,700
+نهايتها ate فاذكروا أنتم مثلا في عندكم ايون ال
+
+22
+00:02:03,700 --> 00:02:11,760
+nitrateوالسلفات و الأجزالات و الأسيتات كل الأيونات
+
+23
+00:02:11,760 --> 00:02:16,400
+السالبة بشكل عام نهيتها إيش بيكون؟ ات .. الأيونات
+
+24
+00:02:16,400 --> 00:02:18,620
+الموجبة شو بيكون نهيتها؟
+
+25
+00:02:20,790 --> 00:02:26,690
+اونيوم اونيوم زي امونيوم اوكزونيوم هايدرونيوم واضح
+
+26
+00:02:26,690 --> 00:02:31,870
+فهنا لانه عندى هذا ايون سالب مثلا نفترض من الاسيتك
+
+27
+00:02:31,870 --> 00:02:37,360
+اسيد بيكون صوديوم اسيتيت من البنزويك اسيدسوديوم
+
+28
+00:02:37,360 --> 00:02:42,260
+بنزويت و هكذا على سبيل مثال اي مثال محدد هذا جاي
+
+29
+00:02:42,260 --> 00:02:46,140
+من ال acetic acid هذي ال acetate group بصير سوديوم
+
+30
+00:02:46,140 --> 00:02:50,860
+أسيتاتي المثال التاني من ال benzoic acid مع ال
+
+31
+00:02:50,860 --> 00:02:57,820
+potassium بصير potassium بنزويت هذا من ال provenic
+
+32
+00:02:57,820 --> 00:03:03,560
+acidفبدوا يكون مع ال calcium طبعا بنسبة 2 ل 1
+
+33
+00:03:03,560 --> 00:03:10,560
+التفاعل calcium بروبانيت و هكذا فالخلاصة انه نتيجة
+
+34
+00:03:10,560 --> 00:03:16,420
+للحمضية خلينا نقول المرتفعة نسبية للأحماض
+
+35
+00:03:16,420 --> 00:03:21,980
+الكربوكسيلية بتفاعلوا مع ال bases و بيقدروا لتكوين
+
+36
+00:03:21,980 --> 00:03:29,840
+الأملاح و الماءالان لو اجينا نقول كيف تحضر ال
+
+37
+00:03:29,840 --> 00:03:35,000
+carboxylic acidsبإمكاننا نعمل الكلام بسبعة slides
+
+38
+00:03:35,000 --> 00:03:41,440
+أو تمانية و بإمكاننا نختصره ب slide واحدة واضح؟
+
+39
+00:03:41,440 --> 00:03:45,380
+هذه ال slide تقريبا بتحط لنا طريقة تنتين، تلاتة،
+
+40
+00:03:45,380 --> 00:03:50,400
+أربعة، خمسة، ستة، سبعة، كل هذه الطرق لتحضير
+
+41
+00:03:50,400 --> 00:03:54,060
+الأحماض الكربوكسيلية فالطرق زي ما بتعرفوا كثيرا
+
+42
+00:03:54,060 --> 00:04:02,300
+هتلاحظوا أن بعض هذه الطرقدرسناها احنا سابقا، بعض
+
+43
+00:04:02,300 --> 00:04:06,700
+هذه الطرق لتحضير ال carboxylic acids درسناها
+
+44
+00:04:06,700 --> 00:04:13,540
+سابقا، والبعض بيمر علينا لأول مرة خلينا نشوف مثلا
+
+45
+00:04:13,540 --> 00:04:17,640
+الأشياء اللي درسناها سابقا، الأشياء اللي درسناها
+
+46
+00:04:17,640 --> 00:04:23,320
+سابقامثلًا هذه الطريقة التانية لما بكون عندى ال
+
+47
+00:04:23,320 --> 00:04:27,020
+keen .. لما بكون عندى ال keen و بعمله انا
+
+48
+00:04:27,020 --> 00:04:34,340
+ozonolysis followed by oxidation واضح؟ اذا كان هنا
+
+49
+00:04:34,340 --> 00:04:39,950
+في عندىالديهيد اتكون في المرحلة الأولى، هذا ال
+
+50
+00:04:39,950 --> 00:04:45,610
+الديهيد بعد هيك بتأكسد بخطوة إضافية لإيش؟ للحمض،
+
+51
+00:04:45,610 --> 00:04:49,710
+لو كانوا هدولة التلتين R-groups بيظلوا عنده كيتون
+
+52
+00:04:49,710 --> 00:04:55,270
+و أخدنا في تفاعلات الالكينز أمثلة على هذا النوع و
+
+53
+00:04:55,270 --> 00:04:59,070
+بتذكروا لو كان عندنا two hydrogens كنا مرات نقول
+
+54
+00:04:59,070 --> 00:05:04,780
+ممكن نصل لثانو أكسيد كاربون في الآخر يعنيفمثل هذا
+
+55
+00:05:04,780 --> 00:05:11,880
+التفاعل اللي هو ال ozoneolysis أخدناه الآن نفس
+
+56
+00:05:11,880 --> 00:05:15,060
+الفكرة زي ما بيصير ال ozoneolysis في ال double
+
+57
+00:05:15,060 --> 00:05:18,980
+bond برضه بيصير في ال triple bond وبهذا الحالة
+
+58
+00:05:18,980 --> 00:05:25,050
+بيعطينا أحمدمن التفاعلات اللي أخدناها أنه ال
+
+59
+00:05:25,050 --> 00:05:30,290
+primary alcohols بس بشرط يكون ال oxidizing agent
+
+60
+00:05:30,290 --> 00:05:36,830
+strong بتأكسده لحد ما يصلوا ل ال carboxylic acid
+
+61
+00:05:36,830 --> 00:05:40,590
+إذا بتحاولوا تتذكروا هنا مهم أن نتذكر نوع ال
+
+62
+00:05:40,590 --> 00:05:45,670
+oxidizing agent لأن كان في عندنا oxidizing agent
+
+63
+00:05:46,810 --> 00:05:51,590
+بيوصلني بس لل الديهيد اللي هي مثل البريدينيا
+
+64
+00:05:51,590 --> 00:05:55,750
+ميكلورو كروميت وفي اكسيدايزينج ايجانت بيحول ال
+
+65
+00:05:55,750 --> 00:06:04,350
+primary alcohol لاسس مثل الكيامان O4 و ال K2
+
+66
+00:06:04,350 --> 00:06:10,210
+كروميوم 2 O7 و الكروميوم O3 كل هذا الكلام أخدناه
+
+67
+00:06:10,210 --> 00:06:14,110
+اللي هي ال strong oxidizing agents they convert
+
+68
+00:06:14,110 --> 00:06:16,230
+primary alcohols
+
+69
+00:06:21,150 --> 00:06:28,570
+الـ BCC كان يحول هذا البرايمري الكهول الى الديهيد
+
+70
+00:06:28,570 --> 00:06:33,210
+الواضح فإذا كنت بدى ال acid وعندي ال primary
+
+71
+00:06:33,210 --> 00:06:35,730
+alcohol لازم استخدم ال
+
+72
+00:06:39,640 --> 00:06:45,320
+بالتأكيد لو اتكون عندى ال الديهيد هنا نفس الاشي
+
+73
+00:06:45,320 --> 00:06:48,920
+ممكن نتخيل ان هذا ال الديهيد يتكون من هنا باستعمال
+
+74
+00:06:48,920 --> 00:06:54,720
+ال BCC البريدينيا الكلورو كروميت ال الديهيد نفسه
+
+75
+00:06:54,720 --> 00:07:02,040
+ممكن ان اكسته مرة تانية لل acid باستعمال اى واحدمن
+
+76
+00:07:02,040 --> 00:07:05,820
+هذه الـ strong oxidizing agent فسواء أنا بدأت ب
+
+77
+00:07:05,820 --> 00:07:09,560
+primary alcohol أو بدأت ب aldehyde إذا كان ال
+
+78
+00:07:09,560 --> 00:07:14,720
+oxidizing agent اللي عندي من فئة ال camon O4 أو ال
+
+79
+00:07:14,720 --> 00:07:18,620
+keto chromium 2 O7 أو ال chromium O3 الكروميك أسد
+
+80
+00:07:18,620 --> 00:07:24,840
+بهاد الحالة بتحول إلى carboxylic acid واضح؟ فزي
+
+81
+00:07:24,840 --> 00:07:30,180
+هيك بنلاحظ احنا ان هذا الطريقة سبق مرت علينا و هذا
+
+82
+00:07:30,180 --> 00:07:33,740
+الطريقةو ممكن نسألكوا ياها بسؤال صح و غلط أنه
+
+83
+00:07:33,740 --> 00:07:38,280
+primary alcohols are oxidized to carboxylic acids
+
+84
+00:07:38,280 --> 00:07:42,800
+using strong oxidizing agents أو الديهيد are
+
+85
+00:07:42,800 --> 00:07:47,180
+oxidized to carboxylic acids using strong
+
+86
+00:07:47,180 --> 00:07:53,940
+oxidizing agentsإذا بيظل ربما كجديد علينا .. بيظل
+
+87
+00:07:53,940 --> 00:07:57,720
+كجديد علينا في هذه المنطقة هذه الطريقة و هذه
+
+88
+00:07:57,720 --> 00:08:01,900
+الطريقة و هذه الطريقة ربما ماسبقش مرة علينا ك
+
+89
+00:08:01,900 --> 00:08:05,580
+method for the preparation of carboxylic acids
+
+90
+00:08:05,580 --> 00:08:12,300
+ممكن نبدأ ناخد آخر method هذه بيسموها oxidation of
+
+91
+00:08:12,300 --> 00:08:17,680
+the aliphatic sided chain on an aromatic ring يعني
+
+92
+00:08:18,380 --> 00:08:21,540
+هذه الطريقة بتقول القاتل انه انا لما بكون عندى
+
+93
+00:08:21,540 --> 00:08:27,620
+aromatic ring نفترض زى البنزين واضح؟ و بتحمل هنا
+
+94
+00:08:27,620 --> 00:08:31,400
+aliphatic sided chain نفترض هذه الـsided chain
+
+95
+00:08:31,400 --> 00:08:36,560
+كانت CH3 على سبيل المثال واضح؟ اذا صار في عندى
+
+96
+00:08:36,560 --> 00:08:42,440
+aromatic ring و ال aromatic ring حاملة aliphatic
+
+97
+00:08:42,440 --> 00:08:48,960
+sided chain واضح؟ هذى اش هذى؟أليفاتك صيدتشين
+
+98
+00:08:48,960 --> 00:08:55,780
+محمولة على اروماتك رينج لما يكون عندى أليفاتك
+
+99
+00:08:55,780 --> 00:09:00,420
+صيدتشين محمولة على اروماتك رينج بنعمل لها اكسيداشن
+
+100
+00:09:00,420 --> 00:09:05,900
+عادة بالكيامان او فور بالبوتاسيوم
+
+101
+00:09:05,900 --> 00:09:12,120
+بيرمانجانيد بيحول هذه المجموعة الأليفاتك الى
+
+102
+00:09:12,120 --> 00:09:19,590
+كربوكسليك أسدبدل ما هي مثل بتصير c double bond o o
+
+103
+00:09:19,590 --> 00:09:25,860
+hالان هذا الكلام له شرط هل الكلام باسمع المثل؟ لأ
+
+104
+00:09:25,860 --> 00:09:31,760
+اي aliphatic sided chain وان كبرت بس بشرط انه ال
+
+105
+00:09:31,760 --> 00:09:36,100
+carbon المتصلة مباشرة هنا في ال aromatic ring تكون
+
+106
+00:09:36,100 --> 00:09:41,040
+حاملة هيدروجين اقل اشي هيدروجين تنتين بمشي تلاتة
+
+107
+00:09:41,040 --> 00:09:46,260
+بمشي بس اقل اشي هيدروجين في هذه الحالة بيعطينا
+
+108
+00:09:46,260 --> 00:09:50,910
+carboxylic acidالان هذه منطقة خلينا نقول منطقة
+
+109
+00:09:50,910 --> 00:09:56,750
+أحيانا خطأ عند الطلاب و لذلك خلينا نوضحها يعني لو
+
+110
+00:09:56,750 --> 00:10:06,330
+افترضنا مثلا عنده بنزين و حامل مثل و بنزين تاني و
+
+111
+00:10:06,330 --> 00:10:06,910
+حامل
+
+112
+00:10:09,350 --> 00:10:14,130
+Ethyl كبرت الـ aliphatic side chain واضح؟ الآن هذا
+
+113
+00:10:14,130 --> 00:10:19,290
+و هذا بيعطوا نفس الناتج ماحدش يجي يحط ال acid هنا
+
+114
+00:10:19,290 --> 00:10:25,890
+لأ في الحالتين أيا كانت ال aliphatic side chain
+
+115
+00:10:25,890 --> 00:10:29,830
+وإن كبرت حتى لو كانت عشر كربونات في الآخر بتعطي
+
+116
+00:10:29,830 --> 00:10:34,950
+acid واحدواضحة هذه النقطة الكثير من الجمال اللي
+
+117
+00:10:34,950 --> 00:10:37,310
+ميكملوا المسألة كانوا بيروحوا بيحطوا أسد على
+
+118
+00:10:37,310 --> 00:10:41,150
+الكاربون الطرفية مثلا لو كان عندي خمس كاربونات هنا
+
+119
+00:10:41,150 --> 00:10:46,830
+الخمسة كلهم بدهم ينشالوا ويجي مكانهم مجموعة أسد
+
+120
+00:10:46,830 --> 00:10:53,250
+واحدة وقت إيش ما بيصيرش التفاعل إذا كانت الكاربون
+
+121
+00:10:53,250 --> 00:10:59,170
+هذه الأولى مافيش عليها هيدروجين لكن مثلا تكون مثل
+
+122
+00:11:00,620 --> 00:11:04,160
+مثلًا مثلبنزين اللي هو الطلوين أو الاثلبنزين أو
+
+123
+00:11:04,160 --> 00:11:08,480
+البروبلبنزين أو البيوتلبنزين أو الايزوبروبلبنزين
+
+124
+00:11:08,480 --> 00:11:15,640
+كل هدولة بيعطوني بنزويك أسد كلهم بيعطوا نفس الناتج
+
+125
+00:11:15,640 --> 00:11:24,000
+إيش اللي مابيعطيش زي ال tertiary butyl group مثلًا
+
+126
+00:11:24,000 --> 00:11:26,120
+يعني لو أخدنا هذا المركب
+
+127
+00:11:33,110 --> 00:11:36,930
+هذه مجموعة الـ tertiary-butyl الأربعة المجموعة
+
+128
+00:11:36,930 --> 00:11:40,670
+المزدحمة لأن هذا الكربون اللي هنا مش حملة هيدروجين
+
+129
+00:11:40,670 --> 00:11:44,370
+هذا لو كنت اعمله oxidation بالكمان O4 مابيعطينيش
+
+130
+00:11:44,370 --> 00:11:51,890
+acid واضح؟ لكن لو كان المركب H
+
+131
+00:11:51,890 --> 00:11:56,830
+اه
+
+132
+00:11:56,830 --> 00:11:58,950
+واضح؟
+
+133
+00:12:00,070 --> 00:12:03,770
+الان مثل هذا السؤال عشان نذكركوا شوية في العلم لو
+
+134
+00:12:03,770 --> 00:12:09,810
+كنا بدنا نسألكوا فيه بالصح والغلط شو بنقولكوا؟
+
+135
+00:12:09,810 --> 00:12:17,060
+اكيومينتذكروا ان هذا اسمه كيومين، كيومين can be
+
+136
+00:12:17,060 --> 00:12:23,080
+oxidized to benzoic acid، صح الترث شربيوت البنزين
+
+137
+00:12:23,080 --> 00:12:28,200
+can be oxidized to benzoic acid، غلط طبعا مشكلة لو
+
+138
+00:12:28,200 --> 00:12:33,260
+قلنالكم both كيومين and ترث شربيوت البنزين can be
+
+139
+00:12:33,260 --> 00:12:36,640
+oxidized to carboxylic acid، لأ مش التنين، واحد
+
+140
+00:12:36,640 --> 00:12:41,920
+منهم اللي بيكون فيه at least one hydrogenواضح هذه
+
+141
+00:12:41,920 --> 00:12:46,160
+الفكرة؟ at least بيكون عندى one hydrogen كل ال
+
+142
+00:12:46,160 --> 00:12:49,160
+side chain بتكون تشيلوها مش تشوفوها كبيرة
+
+143
+00:12:49,160 --> 00:12:53,660
+تتخلونكوا شوية منها لأ بتكون تجيبوا مساحة تمسحوها
+
+144
+00:12:53,660 --> 00:13:02,120
+و تحطوا مكانها COOH Carboxylic Acid اذا هذا ال
+
+145
+00:13:02,120 --> 00:13:06,800
+method السابع اللى هنا اللى بنسميه oxidation of a
+
+146
+00:13:06,800 --> 00:13:12,660
+sided chainon aromatic ring اللي هو اكسدت السلسلة
+
+147
+00:13:12,660 --> 00:13:16,960
+الالفاتية ال alphatic sided chain attached to
+
+148
+00:13:16,960 --> 00:13:19,000
+aromatic rings
+
+149
+00:13:25,440 --> 00:13:30,320
+بيجينا كمان طريقتين لتحضير ال carboxylic acids
+
+150
+00:13:30,320 --> 00:13:36,880
+الطريقة الأولى بتبدأ من ال RX الطريقة الأولى بتبدأ
+
+151
+00:13:36,880 --> 00:13:43,400
+من ال RX يمكن إذا بدنا نذكركوا أكتر ال RX عادة
+
+152
+00:13:43,400 --> 00:13:49,440
+ممكن إحنا نحضرها من ال ROH ال alcohol واضح؟ يعني
+
+153
+00:13:49,440 --> 00:13:56,030
+في الأساس يكون عندكROH بتعطينا Rx لو كانت برايبر
+
+154
+00:13:56,030 --> 00:14:01,510
+مع ال بي إكس ثري بتعطينا Rx ليش أنا رجعت كهانة
+
+155
+00:14:01,510 --> 00:14:05,710
+خطوة لورا عشان أذكركم بالجملة اللي كنا نقولها
+
+156
+00:14:08,040 --> 00:14:11,980
+الكيميائي لو كان في الصحراء لو كان في الصحراء و
+
+157
+00:14:11,980 --> 00:14:16,040
+معه alcohol بيحضر منه كل إشي لاحظوا ال alcohol هنا
+
+158
+00:14:16,040 --> 00:14:20,500
+بإمكان احضر منه RX RX بعد شوية بيحضر منه Green
+
+159
+00:14:20,500 --> 00:14:23,740
+يعني if it's green يعني بيحضر منه ال acid ال acid
+
+160
+00:14:23,740 --> 00:14:27,400
+هتلاحظوا بيحضر منه كل مشتقات ال acid ال Easter و
+
+161
+00:14:27,400 --> 00:14:29,780
+ال Amid و ال Acid chloride و ال acid anhydride
+
+162
+00:14:29,780 --> 00:14:33,960
+اللي بدهم يمروا علينا المشتقات واضح؟بس مبدئيا احنا
+
+163
+00:14:33,960 --> 00:14:39,340
+بنقول انه لو عندنا الكهول ممكن بسهولة يصير RX ال
+
+164
+00:14:39,340 --> 00:14:43,620
+RX مع المغنيسيوم أخدنا تفاعل شهير اللي هو ال green
+
+165
+00:14:43,620 --> 00:14:51,380
+yard reaction بيعطينا RMGX ال RMGX اتفقنا ان هو
+
+166
+00:14:51,380 --> 00:14:55,980
+يمثل enucleophile ولا electrophile? enucleophile
+
+167
+00:14:55,980 --> 00:15:05,370
+هو عبارة عن R معمع زوج الإلكترونات تبعها الآن ثاني
+
+168
+00:15:05,370 --> 00:15:11,030
+أكسيد الكربون ثاني أكسيد الكربون يمثل very strong
+
+169
+00:15:11,030 --> 00:15:15,230
+electrophile ليش ثاني أكسيد الكربون يمثل
+
+170
+00:15:15,230 --> 00:15:19,890
+electrophile؟ خلّينا نفصلوا هنا تنسوش أن تقولوا
+
+171
+00:15:19,890 --> 00:15:20,990
+ثاني أكسيد الكربون
+
+172
+00:15:23,630 --> 00:15:28,110
+CW.O وين السالبية اعلى على ال carbon ولا على ال
+
+173
+00:15:28,110 --> 00:15:31,310
+oxygen على ال oxygen اذا هنا عند partially
+
+174
+00:15:31,310 --> 00:15:37,270
+negative هنا partially positive و هنا partially
+
+175
+00:15:37,270 --> 00:15:44,570
+negative فال carbon هذه تبعت ال carbon dioxide is
+
+176
+00:15:46,130 --> 00:15:50,530
+Electrophile واضح ولهذا السبب ال carbon dioxide
+
+177
+00:15:50,530 --> 00:15:54,650
+احنا بنعمله على انه acid anhydride يعني في النهاية
+
+178
+00:15:54,650 --> 00:16:00,650
+لو بدنا ندوبه في الميه بيديه يعطينا حامض ثانوكسيد
+
+179
+00:16:00,650 --> 00:16:04,410
+كربون في الميه مش بيعطينا الكربون ال carbonic acid
+
+180
+00:16:04,410 --> 00:16:13,110
+فال R هذه بتيجي بتهاجم على ال positive carbonما
+
+181
+00:16:13,110 --> 00:16:16,970
+طلعناش على فكرة الـ negative بدوا يهاجم على ال
+
+182
+00:16:16,970 --> 00:16:21,270
+positive و بتتحرك زوج الإلكترونات هذا على ال
+
+183
+00:16:21,270 --> 00:16:28,750
+oxygen بيعطينا O minus فبصير عندك كمرحلة أولى R C
+
+184
+00:16:28,750 --> 00:16:34,850
+double bond O O minus لما في خطوة تانية انفعله مع
+
+185
+00:16:34,850 --> 00:16:41,980
+أي حامضبتصير OH فالخلاصة انه تفاعل ل green yard
+
+186
+00:16:41,980 --> 00:16:48,260
+ray agent مع ثاني أكسيد الكربون كخطوة أولى و بعدين
+
+187
+00:16:48,260 --> 00:16:54,280
+مع حامض مخفف كخطوة تانية بيعطيلي الحامض الآن انا
+
+188
+00:16:54,280 --> 00:16:59,500
+بتكون تنتبهوا لطريقة و منطق الكتابة هذا التفاعل لا
+
+189
+00:16:59,500 --> 00:17:04,540
+يجري على مرة واحدةهذا التفاعل يجرى على مرتين المرة
+
+190
+00:17:04,540 --> 00:17:09,180
+الأولى ان انا لجرينيرد رياجينت بده فاعله مع ثانو
+
+191
+00:17:09,180 --> 00:17:17,660
+أكسيد الكربون بعد ما يتفاعل وينتهي التفاعل تحديدا
+
+192
+00:17:17,660 --> 00:17:21,560
+لما بده ينتهي التفاعل هيعطيني هذا الناتج اذا حابين
+
+193
+00:17:21,560 --> 00:17:24,220
+تشوفوه هيعطينا هذا الناتج
+
+194
+00:17:27,190 --> 00:17:34,930
+وهنا بيصير عندكم C double bond O O M G B R بالظبط
+
+195
+00:17:34,930 --> 00:17:41,850
+بيكون O minus M G B R plus ليش؟ لأن ال M G plus
+
+196
+00:17:41,850 --> 00:17:49,780
+two و ال B Rالـ plus 2 و الـ minus 1 كلهم plus one
+
+197
+00:17:49,780 --> 00:17:58,520
+الـ Mg2 plus الـ Br minus one فكل الـ MgBr بتكون
+
+198
+00:17:58,520 --> 00:18:05,460
+plus وهنا O minus الآن هذا بنضيف عليه الـ H plus
+
+199
+00:18:05,460 --> 00:18:11,170
+أو اللي هنا رمزي له H3O plus بيعطينا ال acidفهذا
+
+200
+00:18:11,170 --> 00:18:16,290
+التفاعل على خطوة ولا على خطوتين؟ على خطوتين عشان
+
+201
+00:18:16,290 --> 00:18:21,370
+ايه؟ لما بنعبّل عن تفاعل على خطوتين بنكتب one و
+
+202
+00:18:21,370 --> 00:18:25,990
+two الان هذا بختلف .. هذا بختلف عن طريقة كتابة ال
+
+203
+00:18:25,990 --> 00:18:28,630
+reaction على السهم و لازم تكونوا منتمهين انتوا
+
+204
+00:18:28,630 --> 00:18:33,970
+بختلف كتير ان اكون كاتب .. ان اكون كاتب على السهم
+
+205
+00:18:33,970 --> 00:18:38,110
+بهذا الشكل CO2
+
+206
+00:18:38,110 --> 00:18:44,380
+فاصلةالـ H plus معناه ذلك هدولة التنتين نضافوا مرة
+
+207
+00:18:44,380 --> 00:18:48,920
+واحدة هنا لما أقول نمرة واحد كذا نمرة اتنين كذا
+
+208
+00:18:48,920 --> 00:18:54,200
+هدولة نضافوا بشكل متتالي طبعا لو هدولة بدوني نحطوا
+
+209
+00:18:54,200 --> 00:18:59,460
+مع بعض مش هيطلع نفس الناتج عارفين ليش؟ لأنه احنا
+
+210
+00:18:59,460 --> 00:19:03,920
+اتعلمنا شغل ان الـ H plus بتخرب Greenyard reagent
+
+211
+00:19:03,920 --> 00:19:10,760
+الـ H plus بتتفاعل مع Greenyard وبتعطيني RHمشقولنا
+
+212
+00:19:10,760 --> 00:19:16,380
+الميه و ال H plus و ال D2O كلهم لو شافوا green
+
+213
+00:19:16,380 --> 00:19:20,220
+yard reagent يعني green yard reagent بدل ما يتعب
+
+214
+00:19:20,220 --> 00:19:24,180
+حاله لو شاف ال H plus من أولها و يروح على ال
+
+215
+00:19:24,180 --> 00:19:27,800
+carbon الموجة بتاع ال ثانو أكسيد الكربون بيروح على
+
+216
+00:19:27,800 --> 00:19:33,720
+ال H plus أسله و أقربله واضح؟فلذلك عليكم ان
+
+217
+00:19:33,720 --> 00:19:39,140
+تنتبهوا كويس ان هذا التفاعل على مرحل تاني انا مش
+
+218
+00:19:39,140 --> 00:19:44,680
+كتير بهمني ان تكتبوا الناتج الوسطاني و بعدين
+
+219
+00:19:44,680 --> 00:19:48,220
+تطلعوا طالما هدول موجودين بشكل سليم نمر واحد نمر
+
+220
+00:19:48,220 --> 00:19:53,560
+اتنين اذا ال RMGX في الأخر بتعطيني RC double point
+
+221
+00:19:53,560 --> 00:20:00,500
+O OH واضح؟ لكن هذا لعملية التوضيح
+
+222
+00:20:03,250 --> 00:20:13,990
+الان هنا بفيدكم بصراحة انه تنتبهوا إلى مقارنة ما
+
+223
+00:20:13,990 --> 00:20:18,810
+بين الطرق .. تنتبهوا مقارنة ما بين الطرق ممكن
+
+224
+00:20:18,810 --> 00:20:24,530
+واحدة تقول طالما ان انا عند ال alcohol و باكسده
+
+225
+00:20:24,530 --> 00:20:32,660
+مباشرة للحمضواضح؟ انتبهوا معاك كويس دايما اختصار
+
+226
+00:20:32,660 --> 00:20:38,040
+بفيد ولا مابفيدش انا توقولت ال RX من وين جاياكم؟
+
+227
+00:20:38,040 --> 00:20:42,140
+من ال alcohol و انا عندي alcohol طيب اذا عندي هنا
+
+228
+00:20:42,140 --> 00:20:48,400
+alcohol و بأكسد هذا ال alcohol مباشرة للحمض ليش
+
+229
+00:20:48,400 --> 00:20:54,860
+اعمل؟ ليش اعمل؟ انه يكون عندي alcohol alcohol R-O
+
+230
+00:20:54,860 --> 00:21:02,350
+-H نفترضو بعدين ال alcohol يصير RX و ال RX جرينيرد
+
+231
+00:21:02,350 --> 00:21:08,190
+و جرينيرد بده ظروف صعبة بده very dry solvents يعني
+
+232
+00:21:08,190 --> 00:21:10,930
+يمكن في غزة عندنا مابظبطش لإن احنا عندنا رطوبة
+
+233
+00:21:10,930 --> 00:21:14,930
+البحر كتير يعني الرطوبة اللي في الجو بتخربه و
+
+234
+00:21:14,930 --> 00:21:19,390
+بعدين مع تاني أكسيد كربون كخطوة أولى و بعدين مع
+
+235
+00:21:19,390 --> 00:21:25,310
+الميه كخطوة ثانية ملاحظين انتوا؟ طب ليش .. ليش كل
+
+236
+00:21:25,310 --> 00:21:26,250
+هاللفة؟
+
+237
+00:21:30,650 --> 00:21:36,870
+على فرض انه عندى primary alcohol
+
+238
+00:21:36,870 --> 00:21:41,110
+طلع
+
+239
+00:21:41,110 --> 00:21:43,490
+عليهم كويس بفرجوا هدول عن بعض
+
+240
+00:21:48,010 --> 00:21:53,550
+في هذه الحالة في هذه الحالة هتلاحظ ان اي alcohol
+
+241
+00:21:53,550 --> 00:21:59,130
+موجود عنده انا بزيد على عدد الكربونات اللي موجودين
+
+242
+00:21:59,130 --> 00:22:05,550
+فيه ذرة كربون جديدة بينما في هذه الحالة انا بحتفظ
+
+243
+00:22:05,550 --> 00:22:11,490
+بنفس عدد الكربونات خلينا ناخد الكلام بمثال لو
+
+244
+00:22:11,490 --> 00:22:15,870
+افترضنا انه بدنا نبدأ بالاثانول و ننتقل على هذه
+
+245
+00:22:15,870 --> 00:22:22,280
+الجهةهي عندكم الاثانول CH3CH2OH
+
+246
+00:22:22,280 --> 00:22:29,120
+وقلنا بدنا نعمله oxidation مباشر بال KMnO4
+
+247
+00:22:29,120 --> 00:22:33,300
+شو هيطلع عندنا
+
+248
+00:22:33,300 --> 00:22:40,080
+ال primary alcohol oxidation CH3CW
+
+249
+00:22:40,080 --> 00:22:48,190
+bond Oحيطلع عندى acid الار الكحول هنا مكون من كام
+
+250
+00:22:48,190 --> 00:22:54,150
+carbon ال acid اللى هنا تكون مكون من كام carbon
+
+251
+00:22:54,150 --> 00:23:01,830
+مكون من two carbons طيب لو هدا إجينا حولنا بال BX3
+
+252
+00:23:01,830 --> 00:23:13,110
+ل RX يعني نفترض صار CH3 CH2 خلينا نقول CLو بعد ما
+
+253
+00:23:13,110 --> 00:23:28,330
+حولناه ل CL بدنا نفعله مع جرينيرد صار CH3CH2MgBr
+
+254
+00:23:28,330 --> 00:23:32,910
+إثل ميبروميد
+
+255
+00:23:32,910 --> 00:23:38,330
+الجرينيرد بعدين بدنا نفعله مع إيش؟
+
+256
+00:23:38,330 --> 00:23:47,750
+نمرة واحدةمع الـ CO2 و نمرة 2 H3O بلس في هذه
+
+257
+00:23:47,750 --> 00:23:53,730
+الحالة يوجد انديكاربون 2 موجودين والـ CO2 يمثل
+
+258
+00:23:53,730 --> 00:23:57,630
+الكاربون التالتة فهو يزيد انديكاربون يعني لو
+
+259
+00:23:57,630 --> 00:24:06,940
+أستخدم الألوان سيصبح CH3 و CH2 موجودينهدول موجودين
+
+260
+00:24:06,940 --> 00:24:10,840
+أصلا، الآن ثاني أكسيد الكربون، بده يجيبلي مجموعة
+
+261
+00:24:10,840 --> 00:24:20,840
+ال acid من برا، سيضة بال bond OH إذا لو أنا ابتدأت
+
+262
+00:24:20,840 --> 00:24:25,340
+بال acidic acid وعملت direct oxidation، بحصل على
+
+263
+00:24:25,340 --> 00:24:30,180
+الحامض المكون من كربون تينعفوًا لو بدأت بالإيثانول
+
+264
+00:24:30,180 --> 00:24:35,440
+بالإيثانول وعملت أكسدة مباشرة بحصل على ال acetic
+
+265
+00:24:35,440 --> 00:24:39,680
+acid على الخلق بينما لو مشيت بال green yard
+
+266
+00:24:39,680 --> 00:24:44,120
+reagent method طريقة green yard reagent قداش كان
+
+267
+00:24:44,120 --> 00:24:49,020
+عندي carbon هنا في ال alcohol او في ال RX انا بزيد
+
+268
+00:24:49,020 --> 00:24:52,580
+عليه كربونا من وين اجت الكربونا من ثانوكسيد
+
+269
+00:24:52,580 --> 00:24:58,980
+الكربون اذا هنا بدأت ال two carbons انتهيتبتلاتة
+
+270
+00:24:58,980 --> 00:25:04,400
+هنا بدأت ب two carbons انتهيت بتلتين هاي الفرق بين
+
+271
+00:25:04,400 --> 00:25:09,840
+الطريقتين صح أنا ببدأ ب alcohol بس هذا alcohol ال
+
+272
+00:25:09,840 --> 00:25:14,180
+direct oxidation بيزيدش عدد الكربون بمقدار ذرة
+
+273
+00:25:14,180 --> 00:25:18,700
+بينما لما بدي أزيد عدد الكربون بمقدار ذرة من وين
+
+274
+00:25:18,700 --> 00:25:23,380
+بدي أجيب هالذرة هذه؟في النهاية ميثانوكسيد الكربون
+
+275
+00:25:23,380 --> 00:25:26,980
+عبر اللي هي ال green yard reagent method
+
+276
+00:25:32,200 --> 00:25:40,300
+بهذا المثال سؤالك منطقي ان انا لو كنت بدي تلاتة
+
+277
+00:25:40,300 --> 00:25:48,120
+مكان بإمكاني استعمل بروبانول و اعمله oxidation هذا
+
+278
+00:25:48,120 --> 00:25:53,220
+الكلام متعلق بـ simple compounds موجودة اثانول و
+
+279
+00:25:53,220 --> 00:25:57,880
+بروبانول و ما إلى ذلكالان مش دائما في الكيميا لما
+
+280
+00:25:57,880 --> 00:26:01,740
+تكبر كل اشي موجود عندك و بتحتاجها في اماكن تانية
+
+281
+00:26:01,740 --> 00:26:05,700
+لكن في هذه المنطقة لو انا بدي اجي لطالب او ادخله
+
+282
+00:26:05,700 --> 00:26:10,580
+على المختبر و اقول حضري لي بروبانويك اسد مثلا و
+
+283
+00:26:10,580 --> 00:26:14,940
+لجت عندها ايثانول و لجت عندها بروبانولبإمكانها
+
+284
+00:26:14,940 --> 00:26:18,800
+تستعمل الاثانول بطريقة طويلة و بإمكانها تستعمل
+
+285
+00:26:18,800 --> 00:26:22,320
+البروبانول تبدأ في تلاتة و تطلع الحمض تلاتة هذا
+
+286
+00:26:22,320 --> 00:26:26,980
+لأنه موجود بس هذا بالفيش ان هذه طريقة كيميائية
+
+287
+00:26:26,980 --> 00:26:31,940
+موجودة في مركبات معينة بظروف معينة بتلزمناه واضح
+
+288
+00:26:31,940 --> 00:26:37,220
+يعني مش دائما بيكون ال starting عنده موجود و ال
+
+289
+00:26:37,220 --> 00:26:42,540
+starting عنده متوفر مش دائما ال starting موجود و
+
+290
+00:26:42,540 --> 00:26:53,040
+متوفر عندهعشان اشتغل عليه واضح
+
+291
+00:26:53,040 --> 00:26:55,280
+الفرق بين هدول الطريقتين؟
+
+292
+00:27:04,100 --> 00:27:08,860
+أخر طريقة نحن ناخدها لتحضير الـ Carboxylic Acids
+
+293
+00:27:08,860 --> 00:27:14,860
+خلّينا نقول شبيهة بطريقة Greenyard Reagent شبيهة
+
+294
+00:27:14,860 --> 00:27:19,680
+بطريقة Greenyard Reagent برضه في هذه الطريقة ..
+
+295
+00:27:19,680 --> 00:27:25,780
+برضه في هذه الطريقة ممكن أنا أبدأ بالـ ROH
+
+296
+00:27:26,800 --> 00:27:30,720
+في طريقة Greenyard بدأت بال R O H و حولتها ل R X
+
+297
+00:27:30,720 --> 00:27:37,420
+وهنا ممكن احولها ل R X وهنا كاتب R ال G طبعا اول
+
+298
+00:27:37,420 --> 00:27:43,300
+ما انتوا بتشوفوا ال G كستات ايش بيغطر ع بالكوا ال
+
+299
+00:27:43,300 --> 00:27:47,020
+washing machine الغسالة ال L G لكن هنا ال L G مش
+
+300
+00:27:47,020 --> 00:27:50,000
+غسالة ايش ال L G؟
+
+301
+00:27:53,730 --> 00:27:59,460
+لو ولا تلاجة طبعا لا غسله ولا تلاجةالـ LG is a
+
+302
+00:27:59,460 --> 00:28:03,000
+leaving group مجموعة مغادرة يعني مجموعة بتطلع
+
+303
+00:28:03,000 --> 00:28:08,240
+بسهولة وأنسب leaving group ال X يعني لو نخلها ال X
+
+304
+00:28:08,240 --> 00:28:13,680
+ر X برضه بمشي لأن ال CL أخدنا أنها بتطلع بسهولة
+
+305
+00:28:13,680 --> 00:28:17,480
+والدليل على هيك أخدنا شبتر كامل اسمه ال الكل
+
+306
+00:28:17,480 --> 00:28:20,980
+هيلايتز وقلنا ال الكل هيلايتز بيصير عليهم ال
+
+307
+00:28:20,980 --> 00:28:26,500
+substitution بشكل سهلهنا كأنه أنا مشترك في الخطوة
+
+308
+00:28:26,500 --> 00:28:31,400
+الأولى لو خدت roh مع ال bcl3 مثلا او ال bx3 بشكل
+
+309
+00:28:31,400 --> 00:28:36,140
+عام هيعطيني rx ممكن اكمله بطريقتى gradient الان ال
+
+310
+00:28:36,140 --> 00:28:43,440
+rx نفسه ممكن اجي افعله مع ال cyanide CN minus زى
+
+311
+00:28:43,440 --> 00:28:47,940
+sodium cyanide مثلا او potassium cyanide ال CN بدى
+
+312
+00:28:47,940 --> 00:28:53,960
+تيجي تهاجم هذا substitutionأسأل 1 و أسأل 2
+
+313
+00:28:53,960 --> 00:28:57,940
+substitution هذا يجب أن يتاجم وتطرد ال X بناء على
+
+314
+00:28:57,940 --> 00:29:05,020
+ذلك سيصبح لدي Rcn لاحظوا هنا أن ال R موجودة ماذا
+
+315
+00:29:05,020 --> 00:29:09,140
+زاد عليها في هذه الحالة كربونه من أين أتيت
+
+316
+00:29:09,140 --> 00:29:14,680
+الكربونه هذه من ال Cn ال Rcn لو أخدته و أعملت له
+
+317
+00:29:14,680 --> 00:29:22,200
+هيدروليسيس بمصادر أساذيكيةيعني حطيته بحامض أو كمان
+
+318
+00:29:22,200 --> 00:29:26,420
+ممكن ال basic media بس نمرة واحد بنحط OH minus
+
+319
+00:29:26,420 --> 00:29:32,260
+ونمرة اتنين H plus هيعطيل الحامض فبنقول احنا ان ال
+
+320
+00:29:32,260 --> 00:29:36,640
+cyanidecan be hydrolyzed يعني بتتمييق بالمية
+
+321
+00:29:36,640 --> 00:29:42,120
+بتتحول إلى حامض إما بإضافة كربوكسيلك أسد إما
+
+322
+00:29:42,120 --> 00:29:45,380
+بإضافة أسد زي الـ sulphuric acid مثلا أو ما إلى
+
+323
+00:29:45,380 --> 00:29:50,880
+ذلك أو بإضافة قاعدة base زي ال sodium hydroxide
+
+324
+00:29:50,880 --> 00:29:56,400
+وبعدين الفعلها مع H plus سواء مشينا زي هيك أو هيك
+
+325
+00:29:56,400 --> 00:30:02,760
+فال RCN بتتحول إلى أسد الآن هذا ال acid إيش ميزته؟
+
+326
+00:30:04,340 --> 00:30:13,460
+الو زايد كربونا واحدة عن ال RX واضح زايد كربونا
+
+327
+00:30:13,460 --> 00:30:17,500
+واحدة عن ال RX طبعا لو انا كنت معاطيكم ال RCN
+
+328
+00:30:17,500 --> 00:30:20,960
+الكربونا خلاص فيها يعني مثلا لو جيبنالكم في
+
+329
+00:30:20,960 --> 00:30:24,300
+الامتحان المعادلة القاتية قولناكم complete the
+
+330
+00:30:24,300 --> 00:30:26,920
+following equation وهذه أحيانا تجربة بيعملوها في
+
+331
+00:30:26,920 --> 00:30:33,100
+المختبر انتوا لسه مااخدتوش المختبر ولا لأ؟الكتير
+
+332
+00:30:33,100 --> 00:30:40,340
+بياخدوا بنزو
+
+333
+00:30:40,340 --> 00:30:45,120
+نيترال أو سيانو بنزين وبعدين بيفعلوا نمرة واحد مع
+
+334
+00:30:45,120 --> 00:30:48,480
+سوديوم هيدروكسيد بتاخدوا في المختبر بتاخدوا كمية
+
+335
+00:30:48,480 --> 00:30:52,560
+منه بتغلو مع سوديوم هيدروكسيد نص ساعة ساعة وبعدين
+
+336
+00:30:52,560 --> 00:30:56,600
+بتضيفوا عليه نقطة حمض شو المحصلة اللي لازم
+
+337
+00:30:56,600 --> 00:30:57,560
+تكتبوها؟
+
+338
+00:31:01,670 --> 00:31:09,950
+النيترالز هيدروليز لأسدين النيترالز CNN بتتحول
+
+339
+00:31:09,950 --> 00:31:17,650
+لأحمر سواء كان هذا الهيدروليز باسيديك ميديامأو كان
+
+340
+00:31:17,650 --> 00:31:22,390
+في basic media يعني الشغلتين موجودين .. الشغلتين
+
+341
+00:31:22,390 --> 00:31:27,110
+موجودين و ممكن يتم التفاعل فيهم أهم شيء بديكوا
+
+342
+00:31:27,110 --> 00:31:32,070
+تنتبهوله ان هذول الطريقتين مقارنة بطريقة ال
+
+343
+00:31:32,070 --> 00:31:36,870
+alcohol و ال aldehyde فيهم زيادة carbon لو كنا
+
+344
+00:31:36,870 --> 00:31:44,030
+بنبدأ من ال RX واضح؟ ال carbon في الحالة الأولى
+
+345
+00:31:44,030 --> 00:31:47,960
+إيش مصدرها؟الثانو أكسيد الكربون و في الحالة
+
+346
+00:31:47,960 --> 00:31:51,800
+التانية من وين إجت الكربون على ال R؟ من ال CN ..
+
+347
+00:31:51,800 --> 00:32:02,300
+ال C فيها C الحمد لله أنها CN مش CNN ولا cancel من
+
+348
+00:32:02,300 --> 00:32:07,120
+أمام محطة أخضرية كل هذه
+
+349
+00:32:07,120 --> 00:32:13,060
+طرق لتحضير الكربوكسيليك أسيد كم
+
+350
+00:32:13,060 --> 00:32:18,060
+طريقة؟سبعة ..الان انا مرة جبت للطلاب في الامتحان
+
+351
+00:32:18,060 --> 00:32:24,600
+حامض و قلتله محضروه ب تلات طرق معقول السؤال؟ احنا
+
+352
+00:32:24,600 --> 00:32:29,460
+معطينكوا سبعة طرق تامدوا
+
+353
+00:32:29,460 --> 00:32:35,880
+انتوا لازم كله full markلاحظوا هذه الـ slide كيف
+
+354
+00:32:35,880 --> 00:32:38,900
+الـ green yard reagent .. هذه شرحناها كيف الـ
+
+355
+00:32:38,900 --> 00:32:41,900
+green yard reagent بتفاعل مع تاني أكسيد الكربون
+
+356
+00:32:41,900 --> 00:32:46,500
+بيعطينا الايون السالف والموجب وفي حالة إضافة الـ H
+
+357
+00:32:46,500 --> 00:32:51,300
+بلس بيعطينا ال acid بتاعة دي فصلناها على الجانب
+
+358
+00:32:51,300 --> 00:32:58,480
+اللي احنا بنحكيه الآن بنجي لموضوع جديد اللي هو ال
+
+359
+00:32:58,480 --> 00:33:03,860
+reactions of carboxylic acidsreactions of
+
+360
+00:33:03,860 --> 00:33:09,800
+carboxylic acids طبعا ال carboxylic acid لما
+
+361
+00:33:09,800 --> 00:33:14,860
+بتفاعل بيعطي ال derivatives of carboxylic acids
+
+362
+00:33:14,860 --> 00:33:19,520
+اللي هي المشتقات لاحظوا هنا هتحسوا أن ال organic
+
+363
+00:33:19,520 --> 00:33:23,860
+صارت سهلة ليش؟ لأنه احنا في هذا ال chapter بدنا
+
+364
+00:33:23,860 --> 00:33:31,180
+ندرس الأحماض و بعد هيكمشتقاتها الان هيجيكوا كيف
+
+365
+00:33:31,180 --> 00:33:37,680
+بنحضر المشتقات تفاعل الحامض هو طريقة تحضير ال
+
+366
+00:33:37,680 --> 00:33:42,060
+derivative يعني لما نقول مثلا ال acid مع ال
+
+367
+00:33:42,060 --> 00:33:47,900
+thionyl chloride ال S O C L 2 بيعطيني R C O O O O
+
+368
+00:33:47,900 --> 00:33:48,520
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+369
+00:33:48,520 --> 00:33:50,220
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+370
+00:33:50,220 --> 00:33:54,200
+O O
+
+371
+00:33:54,200 --> 00:33:54,380
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+372
+00:33:54,380 --> 00:33:54,420
+O O O O O O O O O O O O O O O O O O O O O O
+
+373
+00:33:57,400 --> 00:34:03,400
+derivative الاسدكلوريد كيف بتحضر من الاسد بالتفاعل
+
+374
+00:34:03,400 --> 00:34:11,800
+مع ال SOCl2 ال Easter هو أحد مشتقات الأحماض كيف
+
+375
+00:34:11,800 --> 00:34:19,840
+بنحضره تفاعل شئ لده أن حمض زاد كحول بيعطينا Easter
+
+376
+00:34:19,840 --> 00:34:26,850
+بمعنىهذا الـ ROH يتهاجم هنا وتطرد الـ OH وهنا
+
+377
+00:34:26,850 --> 00:34:32,430
+التفاعل الأساسي هو تفاعل substitution هذا الـ ROH
+
+378
+00:34:32,430 --> 00:34:38,670
+هاجمت هنا وطلعت الـ OH فبصير عندي R سيضع بالبند O
+
+379
+00:34:38,670 --> 00:34:44,710
+ومن الكحول ايش اتجه عندي OR بلس كأن ال Easter
+
+380
+00:34:44,710 --> 00:34:51,780
+انكون من جزئين جزء جاي من الحامض و جزء جاىمن
+
+381
+00:34:51,780 --> 00:34:56,920
+الكحول هذا الجزء اللي هو جاي من إيش؟ من الحمض ال
+
+382
+00:34:56,920 --> 00:35:03,580
+acid part وهذا الجزء ال OR plus من ال alcohol okay
+
+383
+00:35:03,580 --> 00:35:09,520
+إذا تفاعل الأحماض مع الكحولات بيعطينا Easter هيصير
+
+384
+00:35:09,520 --> 00:35:18,020
+عندك طريقة لتحضير؟تفاعل الحامض مع نفسه أو مع حامض
+
+385
+00:35:18,020 --> 00:35:22,760
+آخر ضمن ظروف معينة الحامضين بيفقدوا جزء ميه
+
+386
+00:35:22,760 --> 00:35:26,460
+بيعطونا اللي بنسميه ال acid anhydride
+
+387
+00:35:31,070 --> 00:35:34,830
+مرة تانية ناخدهم بالتفصيل لما ناخد طرق التحضير بس
+
+388
+00:35:34,830 --> 00:35:39,410
+الان عشان يكون عندكم فكرة ان الحامض اذا سخنته مع
+
+389
+00:35:39,410 --> 00:35:42,430
+نفسه و سحبت الميه او سخنته مع حامض تاني و سحبت
+
+390
+00:35:42,430 --> 00:35:49,910
+الميه بيعطيني ال acid anhydride اذا
+
+391
+00:35:49,910 --> 00:35:53,070
+كأن انا من الحامض حضرت ال derivative ال acid
+
+392
+00:35:53,070 --> 00:35:58,110
+chloride ال acid anhydrideالإيستر لو فعلته مع
+
+393
+00:35:58,110 --> 00:36:03,190
+أمونيا أو أي أمين مركب فيه نيتروجين نفس الفكرة
+
+394
+00:36:03,190 --> 00:36:07,730
+برضه هيعمل ال substitution هدف اتهاجم هنا و تطرد
+
+395
+00:36:07,730 --> 00:36:13,930
+ال OH بسرعه DRC double bond O NR2 ممكن تكون NH2,
+
+396
+00:36:14,070 --> 00:36:20,490
+NHR, whatever هذا أو هذا المشتقة شو بنسميها امت
+
+397
+00:36:23,560 --> 00:36:28,200
+أمد فمن الحامض عمال حضرت ال acid chloride ال acid
+
+398
+00:36:28,200 --> 00:36:31,940
+anhydride ال aster الامد و هدولة هم الأربعة
+
+399
+00:36:31,940 --> 00:36:35,280
+derivatives اللي بدنا ندرسهم في باقية ال chapter
+
+400
+00:36:35,280 --> 00:36:40,520
+عن مشتقات الأحمض فمشتقات الحامض يعني منطق الكلام
+
+401
+00:36:40,520 --> 00:36:45,660
+ليش أنا بقول أنا مشتقات للحامض لأن أنا بحضرها من
+
+402
+00:36:45,660 --> 00:36:49,880
+الحامض التفاعل الأخير أن الحامض لو فعلناه مع base
+
+403
+00:36:49,880 --> 00:36:55,330
+بيعطينا ال salt هذا أخدناه في أول المحاضرة هذهحمض
+
+404
+00:36:55,330 --> 00:37:01,590
+وقاعدة بيعطينا هنا نفترض r-c-o-o and a plus salt
+
+405
+00:37:01,590 --> 00:37:05,890
+زائد ماء هذا اللي هو التفاعل اللي ابتدينا في
+
+406
+00:37:05,890 --> 00:37:10,270
+المحاضرة مرة علينا فكأنه التفاعلات الأساسية
+
+407
+00:37:10,270 --> 00:37:17,280
+الأربعة للحمضهي التفاعلات الأربعة اللي بنحضر من
+
+408
+00:37:17,280 --> 00:37:23,260
+خلالها مشتقات الحامض يضاف إنهم تفاعل خامس اللي هو
+
+409
+00:37:23,260 --> 00:37:30,600
+إن الحمض زائد قاعدة ملح زائد ماء وبهيك بننهي اليوم
+
+410
+00:37:30,600 --> 00:37:34,460
+المحاضرة وإن شاء الله بنتابع فيه مرات قادمة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f8ec642c0ce50d85ab6b8f0978af7dd7e212c846
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg.srt
@@ -0,0 +1,2081 @@
+1
+00:00:06,990 --> 00:00:13,110
+اليوم إن شاء الله بدنا نبدأ الفصل الثالث في مساقنا
+
+2
+00:00:13,110 --> 00:00:18,870
+الكيميا الضوئية الفصل الثالث بيحكي عن عائلتين من
+
+3
+00:00:18,870 --> 00:00:24,370
+المركبات الضوئية، الـ alkenes المركبات اللي فيهم 
+
+4
+00:00:25,430 --> 00:00:29,470
+double bonds و الـ alkynes المركبات اللي فيهم
+
+5
+00:00:29,470 --> 00:00:35,530
+triple bonds واضح؟ هناخدهم من ناحية التسمية من 
+
+6
+00:00:35,530 --> 00:00:41,370
+ناحية الخواص ومن ناحية التفاعلات واضح؟ هي الأشياء
+
+7
+00:00:41,370 --> 00:00:43,970
+الأساسية اللي بدنا ندرسها في الموضوع التسمية و
+
+8
+00:00:43,970 --> 00:00:49,770
+الخواص والتفاعلات طبعًا حتى إن عود نتذكر بوقعهم في
+
+9
+00:00:49,770 --> 00:00:53,430
+الـ organic chemistry بتذكروا احنا لما اتكلمنا عن
+
+10
+00:00:53,430 --> 00:00:56,870
+الـ hydrocarbons قولنا فيه إن hydrocarbons
+
+11
+00:00:56,870 --> 00:01:00,670
+saturated بـ single bonds بأقصى ما يمكن من الـ
+
+12
+00:01:00,670 --> 00:01:04,470
+hydrogen وفي hydrocarbons unsaturated
+
+13
+00:01:04,470 --> 00:01:08,710
+..unsaturated يعني شيلنا منهم الـ hydrogen هم غير 
+
+14
+00:01:08,710 --> 00:01:17,140
+مشبعين بالـ hydrogen ومنهم الـ alkenes ومنهم 
+
+15
+00:01:17,140 --> 00:01:20,400
+الـ alkynes اللي فيهم الـ triple bond ولهم الصيغة 
+
+16
+00:01:20,400 --> 00:01:27,360
+العامة Cn H2n-2 طبعًا هذه الصيغة لما يكون عنده
+
+17
+00:01:27,360 --> 00:01:33,300
+رابطة زوجية واحدة أو رابطة ثلاثية واحدة بمعنى لو 
+
+18
+00:01:33,300 --> 00:01:38,100
+عندك الـ alkene في رابطتين زوجيتين هتلاحظوا تلقائيًا
+
+19
+00:01:38,100 --> 00:01:43,080
+إن صيغة العامة تبعته هتصبح Cn H2n-4 يعني مقابل كل 
+
+20
+00:01:43,080 --> 00:01:48,320
+رابطة إضافية أنا بخصم ذرتين هيدروجين مقابل كل
+
+21
+00:01:48,320 --> 00:01:51,660
+رابطة إضافية أنا بخصم ذرتين هيدروجين وسبق أنا
+
+22
+00:01:51,660 --> 00:01:55,280
+قلنالكوا كمان في الـ cyclic alkene إن احنا مقابل
+
+23
+00:01:55,280 --> 00:02:00,870
+تكوين كل حلقة احنا بنخصم برضه ذرتين هيدروجين من 
+
+24
+00:02:00,870 --> 00:02:07,190
+الصيغة المشبعة الآن إذا بدنا بعض المعلومات واللي
+
+25
+00:02:07,190 --> 00:02:11,610
+بتحتوي مقارنات عن الـ single bonds و الـ double
+
+26
+00:02:11,610 --> 00:02:17,030
+bonds و الـ triple bonds هنلاحظ الآتي بالنسبة للـ
+
+27
+00:02:17,030 --> 00:02:21,910
+single bonds الجيومتري حوالين الـ carbon atom
+
+28
+00:02:22,320 --> 00:02:25,540
+الجيومتري حوالين الـ carbon atom في الـ single bond
+
+29
+00:02:25,540 --> 00:02:30,440
+ما زلتم بتذكروها بهذا الشكل أربع روابط أزاوية
+
+30
+00:02:30,440 --> 00:02:36,920
+كده؟ 109.5 والشكل حوالين الـ carbon تتراهيدرال والـ
+
+31
+00:02:36,920 --> 00:02:39,700
+hybridization لهذا الـ carbon
+
+32
+00:02:47,500 --> 00:02:53,880
+الزاوية تبعتها حوالين الكربون 109.5 الـ hybridization
+
+33
+00:02:53,880 --> 00:03:00,080
+للـ carbon sp3 واضح؟ والشكل تتراهيدرال تتراهيدرال لو بنتطلع
+
+34
+00:03:00,080 --> 00:03:04,220
+على مركب فيه double bond لو بنتطلع على مركب فيه
+
+35
+00:03:04,220 --> 00:03:08,040
+double bond هلاحظ إن حوالين الـ carbon المكونة من الـ
+
+36
+00:03:08,040 --> 00:03:10,000
+double bond الـ hybridization كان
+
+37
+00:03:17,150 --> 00:03:22,130
+الآن الـ double bond الترابطة اللي مكونة من رابطتين
+
+38
+00:03:22,130 --> 00:03:27,530
+اللي هي الـ sigma bond الرابطة الـ head to head اللي
+
+39
+00:03:27,530 --> 00:03:32,870
+جاي بين الرأس و الـ double bond اللي هي الـ pi bond
+
+40
+00:03:32,870 --> 00:03:35,850
+الـ second bond الـ pi bond اللي بتكون above and
+
+41
+00:03:35,850 --> 00:03:42,510
+below الـ sigma bond هذي بتكون عبارة عن باي bond إذا 
+
+42
+00:03:42,510 --> 00:03:45,990
+الـ Double bond عبارة عن نوعين من الـ bonds Sigma
+
+43
+00:03:45,990 --> 00:03:51,930
+bond أساسية والـ pi bond فوق وتحت مستوى الجزئية
+
+44
+00:03:51,930 --> 00:03:58,030
+العاملة اللي هي الـ electronic cloud و الـ 720 لو 
+
+45
+00:03:58,030 --> 00:04:05,630
+بنطلع احنا على الـ alkynes الـ alkynes بنلاحظ إن
+
+46
+00:04:05,630 --> 00:04:08,750
+الـ carbonات اللي بيكونوا الـ triple bond هنا في 
+
+47
+00:04:08,750 --> 00:04:15,970
+الـ carbon وهنا في الـ carbon الـ hybridization لهم sp
+
+48
+00:04:15,970 --> 00:04:19,750
+الـ hybridization للـ carbons اللي بتكون لـ triple bond sp
+
+49
+00:04:19,750 --> 00:04:25,870
+طبعًا بيكون عندي one sigma bond وإيه كم pi bond؟
+
+50
+00:04:25,870 --> 00:04:30,070
+two pi bonds فالـ triple bond مكونة من one sigma
+
+51
+00:04:30,070 --> 00:04:34,190
+bond و two pi bonds الـ pi bonds وين بيكونوا
+
+52
+00:04:34,190 --> 00:04:42,670
+كإلكترونات فوق وتحت تمامًا أنتم تتخيلوا إن أنا عندي
+
+53
+00:04:42,670 --> 00:04:47,850
+فوق وتحت وأمام وخلف صار عندي اللي بنسميه 
+
+54
+00:04:47,850 --> 00:04:52,710
+cylindrical electronic cloud يعني سحابة إلكترونية
+
+55
+00:04:52,710 --> 00:04:59,130
+أسطوانية زي الأسطوانة واضح؟ الإلكترونات زي
+
+56
+00:04:59,130 --> 00:05:03,650
+الأسطوانة بتكون محاوطة الجزء إذا هذه الـ electronic
+
+57
+00:05:03,650 --> 00:05:07,470
+cloud ولو احنا رسمناها بهذا الشكل على السطورة لكن 
+
+58
+00:05:07,470 --> 00:05:13,260
+هي حقيقة فوق وتحت وأمام وخلف فبنحكي عن
+
+59
+00:05:13,260 --> 00:05:19,260
+cylindrical electronic
+
+60
+00:05:19,260 --> 00:05:26,640
+cloud يعني سحابة إلكترونية أسطوانية محاوطة الجزء من
+
+61
+00:05:26,640 --> 00:05:34,310
+كل الجهات واضح؟ الزاوية طبعًا في الجزئية 180
+
+62
+00:05:34,310 --> 00:05:38,630
+وبهذا.. وبهذا الشكل الجزء اللي فيه triple bond زي
+
+63
+00:05:38,630 --> 00:05:43,810
+ما احنا شايفينه هنا بيكون linear الجزء اللي فيه
+
+64
+00:05:43,810 --> 00:05:48,630
+triple bond بيكون linear والجزء اللي فيه double
+
+65
+00:05:48,630 --> 00:05:53,350
+bonds بده يكون planar وحوالين كل carbon اترايجونا
+
+66
+00:05:53,350 --> 00:05:57,590
+لـ planar الجزء كله في مستوى واحد لحظة لما بنحطه في 
+
+67
+00:05:57,590 --> 00:06:02,330
+إيدنا الجزء في مستوى واحد بينما الجزء التتراهيدرال
+
+68
+00:06:02,330 --> 00:06:07,630
+three-dimensional كان مش في مستوى واحد واضح؟ هذا 
+
+69
+00:06:07,630 --> 00:06:11,350
+الجزء three-dimensional لكن هذا بيكون في مستوى 
+
+70
+00:06:11,350 --> 00:06:16,210
+واحد واللي بعده بيكون linear هذا بالنسبة للشكل للـ
+
+71
+00:06:16,210 --> 00:06:20,210
+single bond للـ double bond للـ triple bond الآن
+
+72
+00:06:20,210 --> 00:06:27,060
+بيجينا شغلتين قوة الرابطة وطول الرابطة، قوة الرابطة
+
+73
+00:06:27,060 --> 00:06:33,260
+وطول الرابطة الـ single bond عادة هي أضعف واحدة
+
+74
+00:06:33,260 --> 00:06:37,980
+فيهم الـ single bond أضعف واحدة، ليش؟ لأن أنا عندي
+
+75
+00:06:37,980 --> 00:06:43,360
+سيجما، هنا الرابط أقوى، سيجما زاد عليها باي، هنا
+
+76
+00:06:43,360 --> 00:06:47,280
+الرابط أقوى وأقوى، سيجما وزاد عليها اتنين باي،
+
+77
+00:06:47,280 --> 00:06:54,260
+واضح؟ دائمًا الرابط القوية بتكون أقصر، واضح؟ عشان 
+
+78
+00:06:54,260 --> 00:06:57,160
+هيك لما نقدر نتطلع على طول الروابط في الـ 
+
+79
+00:06:57,160 --> 00:06:57,900
+picometer
+
+80
+00:07:02,680 --> 00:07:06,600
+طلع طول الروابط بالبيكوميتر بالمتوسط الـ single
+
+81
+00:07:06,600 --> 00:07:12,540
+bond بتكون 154 بيكوميتر الـ double bond بتكون 134
+
+82
+00:07:12,540 --> 00:07:19,780
+بيكوميتر الـ triple bond بتكون 121 بيكوميتر إذن
+
+83
+00:07:19,780 --> 00:07:25,920
+أيهما الأقصر الـ triple bond واضح؟ أيهما الأطول الـ
+
+84
+00:07:25,920 --> 00:07:30,820
+single bond إذن بنقدر احنا نقول إن الـ triple bond
+
+85
+00:07:30,820 --> 00:07:40,790
+هي shortest and strongest وبنفس الوقت strongest هي
+
+86
+00:07:40,790 --> 00:07:46,390
+الأقصر والأقوى هي الأقصر والأقوى الآن لما بدنا نجي
+
+87
+00:07:46,390 --> 00:07:50,670
+بالعكس على الـ single bond إيش هنقول؟ طولها longest
+
+88
+00:07:50,670 --> 00:07:57,810
+and weakest واضح؟ هذه الأطول والأضعف فديك الأقصر
+
+89
+00:07:57,810 --> 00:08:04,040
+والأقوى واضح؟ هذا الكلام بيتبعوا شغلة بيتبعوا شغلة
+
+90
+00:08:04,040 --> 00:08:08,320
+أنه أنا لو كان عندي جزء في single bond لو كان عندي
+
+91
+00:08:08,320 --> 00:08:12,720
+جزء وهذا الجزء في single bond وأخذناه في الـ
+
+92
+00:08:12,720 --> 00:08:16,940
+conformations في إمكانية rotation ودوران حوالي الـ
+
+93
+00:08:16,940 --> 00:08:22,260
+single bond ملاحظين؟ في عندي إمكانية للدوران حوالي 
+
+94
+00:08:22,260 --> 00:08:28,090
+الـ single bond لأنها رابطة ضعيفة الآن لو صار عندي 
+
+95
+00:08:28,090 --> 00:08:32,450
+الـ triple bond الـ rotation بصير restricted ممنوع
+
+96
+00:08:32,450 --> 00:08:39,330
+لو جربنا نمسك جزء زي هذا بدنا نلفه مستحيل، واضح؟
+
+97
+00:08:39,330 --> 00:08:42,590
+الرابطة أصبحت أقوى، لو بدأت أحكي rotation حوالين
+
+98
+00:08:42,590 --> 00:08:47,450
+الـ triple bond، برضه مستحيل، إذا الـ rotation أو 
+
+99
+00:08:47,450 --> 00:08:52,630
+الدوران يكون حول الرابطة الواحدية possible،
+
+100
+00:08:52,630 --> 00:08:58,370
+restricted around or about double bond و triple
+
+101
+00:08:58,370 --> 00:09:02,260
+bond، واضح؟ الشكل زي ما قلنا هنا تتراهيدرال 
+
+102
+00:09:02,260 --> 00:09:06,060
+تتراهيدرال البلانر ومعناها Linear الـ hybridization
+
+103
+00:09:06,060 --> 00:09:11,560
+حكينا عندنا هنا sp3 وحكينا عندنا sp2 وحكينا عندنا
+
+104
+00:09:11,560 --> 00:09:17,780
+sp تقريبًا هذه كلها معلومات تلخيصية مقارنة بدكم
+
+105
+00:09:17,780 --> 00:09:21,880
+تهتموا فيها يعني لو طالب منكم بده يعمل quiz بأسئلة
+
+106
+00:09:21,880 --> 00:09:22,600
+صح و غلط
+
+107
+00:09:27,010 --> 00:09:30,430
+مقارنات أنه أقول أنه أصغر، إيش نوع الـ Geometry،
+
+108
+00:09:30,430 --> 00:09:32,630
+إيش نوع الـ hybridization، واضح؟
+
+109
+00:09:56,120 --> 00:10:03,310
+الآن السؤال كيف بنسمي الالكينز والالكاينز؟ تقريبًا
+
+110
+00:10:03,310 --> 00:10:08,010
+المبدأ العام في التسمية شبيه لتسمية الالكانز لكن 
+
+111
+00:10:08,010 --> 00:10:13,830
+في حالة الالكانز كان الجزء بينتهي بالنهاية A and E
+
+112
+00:10:13,830 --> 00:10:19,310
+الكانب، اوبين، بيوتين، هكسين، الاتدر.. في الـ
+
+113
+00:10:19,310 --> 00:10:23,710
+double bond بيصير الجزء ينتهي بالنهاية Ene النهاية
+
+114
+00:10:23,710 --> 00:10:29,670
+Ene معناها جزء في double bond بعد شوية حين
+
+115
+00:10:29,670 --> 00:10:36,550
+اتعلم لو كان فيه اثنتين double bond بدو يصير داين و
+
+116
+00:10:36,550 --> 00:10:40,690
+لو في ثلاثة double bonds تريين فـ ene معناها
+
+117
+00:10:40,690 --> 00:10:46,730
+double bond إذا كانوا اثنتين، داين، ثلاثة، تريين،
+
+118
+00:10:46,730 --> 00:10:53,810
+أربعة، تتراين وهكذا وإذا كان عند الـ alkyne يعني في
+
+119
+00:10:53,810 --> 00:10:57,010
+triple bond بحط النهاية yne
+
+120
+00:10:59,830 --> 00:11:03,810
+النهاية yne بتعبر عن جزئية triple bond إذا أنتم ممكن 
+
+121
+00:11:03,810 --> 00:11:12,490
+تشوفوا هكسين وهكسين وهكساين الهكسين single bonds
+
+122
+00:11:12,490 --> 00:11:19,510
+الهكسين double bond الهكساين triple bond لما بنجي
+
+123
+00:11:19,510 --> 00:11:23,530
+بنسمي بنبحث مرة ثانية عن أطول سلسلة
+
+124
+00:11:29,040 --> 00:11:33,580
+هذه السلسلة يجب أن تحتوي.. مرة ثانية.. يجب أن 
+
+125
+00:11:33,580 --> 00:11:39,920
+تحتوي على اللي هو الـ double bond أو الـ triple bond
+
+126
+00:11:39,920 --> 00:11:45,560
+يعني لو بدكم تتطلعوا مثلًا على هذا الجزء ممكن
+
+127
+00:11:45,560 --> 00:11:49,800
+تشوفوا إن هاي سلسلة واحد اثنين ثلاثة أربعة خمسة
+
+128
+00:11:49,800 --> 00:11:53,840
+ستة والـ double bond جزء منها الـ double bond مش
+
+129
+00:11:53,840 --> 00:11:55,040
+بطرف واحد
+
+130
+00:11:58,570 --> 00:12:02,630
+لكن لو أخدت السلسلة منها إن واحد اثنين ثلاثة أربعة 
+
+131
+00:12:02,630 --> 00:12:07,530
+خمسة ستة سبعة ثمانية اثنين اثنين اثنين اثنين
+
+132
+00:12:07,530 --> 00:12:07,770
+اثنين اثنين اثنين اثنين اثنين اثنين اثنين اثنين
+
+133
+00:12:07,770 --> 00:12:08,910
+اثنين اثنين اثنين اثنين اثنين اثنين اثنين اثنين
+
+134
+00:12:08,910 --> 00:12:08,970
+اثنين اثنين اثنين اثنين اثنين اثنين اثنين اثنين
+
+135
+00:12:08,970 --> 00:12:12,690
+اثنين اثنين اثنين اثنين اثنين اثنين اثنين اثنين
+
+136
+00:12:12,690 --> 00:12:15,570
+اثنين اثنين اثنين اثنين اثنين اثنين اثنين اثنين
+
+137
+00:12:15,570 --> 00:12:27,690
+اثنين اثنين
+
+138
+00:12:30,410 --> 00:12:34,810
+لما بعمل الترقيم، الترقيم لازم يمول أسرع ما يمكن
+
+139
+00:12:34,810 --> 00:12:40,810
+بالـ double bond أو بالـ triple bond بالضبط أقرب
+
+140
+00:12:40,810 --> 00:12:45,010
+ما يمكن في الترقيم طيب، لما بدي أحدد موقعها، هل 
+
+141
+00:12:45,010 --> 00:12:52,450
+بنحدد موقعها بإعطاء رقم 1 ولا 2؟ بنعطي بس رقم
+
+142
+00:12:52,450 --> 00:12:57,680
+البداية تبعها يعني هذه الرابطة جاية بين ذرة واحد و
+
+143
+00:12:57,680 --> 00:13:02,200
+اثنين لكن أنا لما أبدأ أسمي بس بقول one عشان هي
+
+144
+00:13:02,200 --> 00:13:05,900
+كان الاسم بدون ما نأخذ هذه نعتبرها substituent من
+
+145
+00:13:05,900 --> 00:13:09,480
+ذرة تلاتة اثنين ثلاثة الـ substituent اللي من تلات ذرات شو
+
+146
+00:13:09,480 --> 00:13:16,530
+اسمها؟ propyl كمجموعة فهذا two propyl لاحظوا one 
+
+147
+00:13:16,530 --> 00:13:21,630
+hexyl إيش معناه one hexyl؟ إنه رابطة الزوجية تبتدأ
+
+148
+00:13:21,630 --> 00:13:26,030
+من نقطة واحد ما بحطش نقطة البداية والنهاية تبعها بس
+
+149
+00:13:26,030 --> 00:13:30,250
+بحدد نقطة البداية أكيد بتكون هي من واحد رايحة
+
+150
+00:13:30,250 --> 00:13:35,050
+لاثنين لو كنت مثلًا بدي المركب two hexyl وين هتكون
+
+151
+00:13:35,050 --> 00:13:36,370
+الرابطة الزوجية؟
+
+152
+00:13:40,710 --> 00:13:49,610
+تمامًا لو جت الـ رابطة الزوجية هتتغير السلسلة كذلك
+
+153
+00:13:49,610 --> 00:13:54,070
+لو بدنا نشوف مثلًا هذا المركب نحاول نسميه مع بعض
+
+154
+00:13:54,070 --> 00:13:58,710
+هتلاحظوا فيه عندنا هاي سلسلة واحد اثنين ثلاثة
+
+155
+00:13:58,710 --> 00:14:02,490
+أربعة خمسة واحد اثنين ثلاثة أربعة خمسة
+
+156
+00:14:06,580 --> 00:14:11,080
+وحاولت أطول سلسلة تحتوي على الـ double bond واحد
+
+157
+00:14:11,080 --> 00:14:15,120
+اثنين ثلاثة أربعة خمسة لاحظوا بدنا الترقيم من هذه
+
+158
+00:14:15,120 --> 00:14:20,300
+الجهة لأن بداية الـ double bond هنا بتكون على رقم
+
+159
+00:14:20,300 --> 00:14:25,900
+اثنين لو بدأت الترقيم من هنا تكون على رقم ثلاثة 
+
+160
+00:14:25,900 --> 00:14:29,300
+اثنين ثلاثة بتكون على رقم ثلاثة إن هو الأنسب اثنين
+
+161
+00:14:29,300 --> 00:14:34,690
+بتكون على رقم اثنين عشان هذا المركب two pentene هذا
+
+162
+00:14:34,690 --> 00:14:38,370
+الأساس فيه two pentene بعدين الـ substituents بنذكرهم
+
+163
+00:14:38,370 --> 00:14:41,930
+بالطريقة اللي اتعلمناها السابقة عندنا propyl وعندنا
+
+164
+00:14:41,930 --> 00:14:46,610
+مثل مين؟ alphabetical في الأول الـ propyl كده هذا
+
+165
+00:14:46,610 --> 00:14:54,250
+المركب four propyl two مثل two pentene four propyl two 
+
+166
+00:14:54,250 --> 00:15:00,310
+مثل two pentene الكلام نفسه بيتم لو كان في عندنا الـ
+
+167
+00:15:00,310 --> 00:15:05,960
+alkynes بس بتصير النهاية yne يعني لو هذا المركب بدي أحط
+
+168
+00:15:05,960 --> 00:15:11,020
+هنا كمان bond، بدي يكون بنفس الاسم، بنفس الاسم،
+
+169
+00:15:11,020 --> 00:15:15,420
+ما عدا بنتين، one head side، ما بحطش فيه substituent
+
+170
+00:15:15,420 --> 00:15:22,040
+once وبتصير yne أو.. وبنشوف الـ alkyne الآن في
+
+171
+00:15:22,040 --> 00:15:26,580
+الـ Alkenes تحديدًا بتيجينا ظاهرة جديدة، ظاهرة
+
+172
+00:15:26,580 --> 00:15:32,800
+متشكلات فراغية، ظاهرة متشكلات فراغية، وبيجيني كمان
+
+173
+00:15:32,800 --> 00:15:36,580
+للـ Alkenes مجموعات، بتعرفوا أنتم لما أخذنا
+
+174
+00:15:36,580 --> 00:15:40,800
+الـ Alkanes، قلنا ميثين، منه مجموعة؟ الـ Methane
+
+175
+00:15:40,800 --> 00:15:43,360
+الـ Methane، الـ Ethane منه مجموعة؟ الـ Ethane
+
+176
+00:15:43,360
+
+201
+00:17:49,920 --> 00:17:58,720
+اسم، شو بنسميها؟ أليل، أليل، واضح؟ بنسميها أليل، ولو
+
+202
+00:17:58,720 --> 00:18:02,200
+كانت متصلة بالكلور، شو بتصير؟ أليل الكلوريد، أليل 
+
+203
+00:18:02,200 --> 00:18:06,420
+الكلورايد، لو متصلة بالـ OH مثلا، الـ OH المجموعة
+
+204
+00:18:06,420 --> 00:18:09,520
+اللي واقف فيها للكحول، بيصير أليل الكحول
+
+205
+00:18:15,200 --> 00:18:20,460
+الـ CR بتصير OH، لو هذه OH بيصير عندك أليل الكحول،
+
+206
+00:18:20,460 --> 00:18:25,760
+واضح؟ الأليل هذه كتسمية من الناحية خلينا نقول
+
+207
+00:18:25,760 --> 00:18:29,580
+التاريخية جاية من عائلة نباتية بيسموها عائلة
+
+208
+00:18:29,580 --> 00:18:36,220
+الأليوم، والأليوم هي العائلة تبعت الطومة/الـ Garlic
+
+209
+00:18:36,220 --> 00:18:41,880
+ليش؟ لأن الطومة من مكوناتها بتكون مجموعة الأليل هذه
+
+210
+00:18:41,880 --> 00:18:47,140
+مع ذرة كبريت وذرّة كبريت وأليل ثانية داى أليل داى
+
+211
+00:18:47,140 --> 00:18:50,500
+سالفايت هذا مركب أساسي في الطومة، لكن وجود
+
+212
+00:18:50,500 --> 00:18:53,660
+الكبريت في الطومة هو اللي بيطلع الرائحة السيئة
+
+213
+00:18:53,660 --> 00:18:58,320
+إلها، تعرفوا الكبريت دائما مرتبط بإيش؟ بالرائحة
+
+214
+00:18:58,320 --> 00:19:01,480
+السيئة، السيئة، فلأن العائلة النباتية كلها تحت
+
+215
+00:19:01,480 --> 00:19:07,710
+الطومة الأليوم منها إجتكلمة الـ allyl group كتسمية طيب
+
+216
+00:19:07,710 --> 00:19:10,870
+هذا الأليل الكلوريد لو بدنا نسميها 
+
+217
+00:19:10,870 --> 00:19:19,610
+إياها بالـ IUPAC Nomenclature أمين
+
+218
+00:19:19,610 --> 00:19:27,630
+اجتهد فضلي لأ
+
+219
+00:19:27,630 --> 00:19:34,800
+ليش؟ لأن أولوية الترقيم البداية بتاعتها عند الـ
+
+220
+00:19:34,800 --> 00:19:40,360
+double bond أنا هنا بقدر أخلّي الـ double bond تمثل
+
+221
+00:19:40,360 --> 00:19:45,420
+نقطة واحد بدايتها ولو بترقمها ابتدات تكون اثنين
+
+222
+00:19:45,420 --> 00:19:50,900
+فالأصل الترقيم اللي عندي يكون واحد اثنين ثلاثة
+
+223
+00:19:50,900 --> 00:19:58,000
+فهذا لما أنا بدي أسميه الآن 3 chloro
+
+224
+00:20:00,490 --> 00:20:05,670
+1 propene دائما احنا بنقول الأولوية في إعطاء
+
+225
+00:20:05,670 --> 00:20:09,910
+الأرقام لإيش؟ الأولوية في إعطاء الأرقام للطابق
+
+226
+00:20:09,910 --> 00:20:13,350
+الجدران مش للـ substituent in another 3 chloro
+
+227
+00:20:13,350 --> 00:20:15,210
+1 propene
+
+228
+00:20:25,140 --> 00:20:30,420
+طبعا بعد الـ propene لو بدي أجي لجزء اللي بعد اللي
+
+229
+00:20:30,420 --> 00:20:35,920
+بقى أربع ذرات كربون هلاحظ أنه هيصير أمامي ظاهرة
+
+230
+00:20:35,920 --> 00:20:40,780
+جديدة أنه أنا لما يصير عندي أربع ذرات كربون الـ
+
+231
+00:20:40,780 --> 00:20:45,060
+double bond ممكن أحطها بين واحد واثنين وممكن أحطها
+
+232
+00:20:45,060 --> 00:20:49,690
+بين اثنين وثلاثة واضح؟ لو حطيت الـ double bond بين
+
+233
+00:20:49,690 --> 00:20:53,290
+الذرة واحد واثنين بيصير الجزء اسمه واحد اثنين
+
+234
+00:20:53,290 --> 00:20:59,550
+ثلاثة أربعة وهي نقطة البداية what a beauty طب
+
+235
+00:20:59,550 --> 00:21:03,210
+ممكن أحط الـ double bond هنا بين الذرة اثنين و
+
+236
+00:21:03,210 --> 00:21:09,230
+ثلاثة ممكن أحط الـ clone بين الذرة اثنين و ثلاثة
+
+237
+00:21:09,230 --> 00:21:16,860
+لما أجي حقيقة أطبق هذا الكلام لما نطبق هذا الكلام و
+
+238
+00:21:16,860 --> 00:21:20,220
+نتخيل أنه عندنا الـ butene، معناه الـ butene أنه عندي
+
+239
+00:21:20,220 --> 00:21:24,200
+كم ذرة carbon؟ أربعة أو هيّني بتحط بين اثنين و
+
+240
+00:21:24,200 --> 00:21:29,590
+ثلاثة، هذه الذرات السمرة، ذرات الـ carbon هي واحد،
+
+241
+00:21:29,590 --> 00:21:34,370
+اثنين، ثلاثة، أربعة، وهي الـ Double bond هدول
+
+242
+00:21:34,370 --> 00:21:39,030
+عبارة عن مجموعتين CH3 حاملين Hydrogens، مظبوط ولا
+
+243
+00:21:39,030 --> 00:21:44,430
+لا؟ okay الآن بلاحظ وأنا بعمل الجزء أنه بإمكاني
+
+244
+00:21:44,430 --> 00:21:50,510
+أخلي مجموعتين الـCH3 على جهة واحدة اه وممكن أخلي
+
+245
+00:21:50,510 --> 00:21:57,140
+مجموعتين الـCH3 على جهتين متعاكستين بلاحظين كيف
+
+246
+00:21:57,140 --> 00:22:02,300
+الجزء مجموعتين الـCH3 ممكن يكونوا على جهة واحدة
+
+247
+00:22:02,300 --> 00:22:08,140
+وممكن يكونوا على جهتين متعاكستين إذا الـ 2 butene
+
+248
+00:22:08,140 --> 00:22:12,860
+مش مركب واحد عبارة عن مركبين، عبارة عن
+
+249
+00:22:12,860 --> 00:22:16,560
+مركبين يا بيكون الـmethyl groups at the same
+
+250
+00:22:16,560 --> 00:22:21,500
+side وبالتالي بيقول إن مركب الـ IUPAC 2 butene يا
+
+251
+00:22:21,500 --> 00:22:25,260
+بيكونوا على جهتين متعاكستين
+
+252
+00:22:29,210 --> 00:22:34,430
+إذا من الأربع ذرات كربون اللي ورا بعض لتشيل كان
+
+253
+00:22:34,430 --> 00:22:40,050
+بإمكانه يكون عندي 1 butane أو cis 2 butane أو
+
+254
+00:22:40,050 --> 00:22:43,630
+trans 2 butane طب واحدة بتقول هو الـ cis ما بيصيرش
+
+255
+00:22:43,630 --> 00:22:48,890
+الـ trans الجواب لأ، ليش ما بيصيرش Trans؟ لأن الدوران
+
+256
+00:22:48,890 --> 00:22:53,230
+ممنوح حول الرابطة الزوجية، عشانك لما بتحول السلسلة
+
+257
+00:22:53,230 --> 00:22:59,170
+لـ Trans، هل يا ترى بالـ rotation بيمشي؟ تطلع عليّ، هي
+
+258
+00:22:59,170 --> 00:23:02,510
+اللي بتحول بالـ rotation، ظابط؟ لأ، طب كيف السلسلة
+
+259
+00:23:02,510 --> 00:23:05,950
+بيصير Trans؟ لازم أكسر هذه الرابطة، أكسر هذه
+
+260
+00:23:05,950 --> 00:23:10,560
+الرابطة، وأكوّن روابط من أول وجديد إذا هذا مركب
+
+261
+00:23:10,560 --> 00:23:14,920
+ وهذا مركب بخواص فيزيائية مختلفة ولذلك لو واحدة
+
+262
+00:23:14,920 --> 00:23:19,360
+منكم بدأت تشتري مركب اسمه 2-butane وبتروح على
+
+263
+00:23:19,360 --> 00:23:21,940
+مخزن الكيميائيات وبتقولوا بدي 2-butane بيقولها
+
+264
+00:23:21,940 --> 00:23:26,060
+مافيش مركب في الدنيا اسمه 2-butane فيه cis 2
+
+265
+00:23:26,060 --> 00:23:32,080
+-butane أو trans 2-butane واضح؟ فيه cis 2
+
+266
+00:23:32,080 --> 00:23:38,130
+-butane أو trans 2-butane لكن مافيش ... مركب اسمه
+
+267
+00:23:38,130 --> 00:23:41,890
+2 butane زي ما واحدة بيجيها ولد، بيقوله أجهز لي 
+
+268
+00:23:41,890 --> 00:23:45,730
+آدم، بينفعش أجهز لي آدم، يا ولد، يا بنت، يا بنت، يا
+
+269
+00:23:45,730 --> 00:23:49,050
+بنت،
+
+270
+00:23:49,050 --> 00:23:49,590
+بنت، يا بنت، يا بنت، يا بنت، يا بنت، يا بنت، يا
+
+271
+00:23:49,590 --> 00:23:49,610
+بنت، يا بنت، يا بنت، يا بنت، يا بنت، يا بنت، يا
+
+272
+00:23:49,610 --> 00:23:56,070
+بنت، يا بنت، يا بنت، يا بنت،
+
+273
+00:24:06,030 --> 00:24:11,650
+أربع ذرات كربون وتكون إيش مالها؟ تكون متفرعة
+
+274
+00:24:11,650 --> 00:24:16,790
+براشد، بهذه الحالة لو كنت بدأت أعمل double bond على
+
+275
+00:24:16,790 --> 00:24:22,570
+جهة ما منها، هحصل على مركب رابع من أربع ذرات
+
+276
+00:24:22,570 --> 00:24:28,930
+كربون، بيكون اسمه isobutene بالـ common nomenclature
+
+277
+00:24:28,930 --> 00:24:34,650
+لأنه وهو كله single bonds، شو سمينا المركب؟
+
+278
+00:24:37,650 --> 00:24:43,490
+Isobutane لما كان كله single bonds لما بنعمل
+
+279
+00:24:43,490 --> 00:24:46,630
+double bond طبعا بنعملها على هذا الموقع زي هذا زي
+
+280
+00:24:46,630 --> 00:24:52,010
+هذا بدي يصير Isobutene طب لو كنا بدنا نسميه في الـ
+
+281
+00:24:52,010 --> 00:24:55,630
+IUPAC nomenclature بده أشوف أين أطول سلسلة تحتوي
+
+282
+00:24:55,630 --> 00:25:00,720
+على 1,2,3 إذا 1-propene وهذا الـ 1-
+
+283
+00:25:00,720 --> 00:25:05,700
+propene على موقع اثنين إيش حامل مثيل إذا لو بدنا
+
+284
+00:25:05,700 --> 00:25:10,740
+نجيب لكم سؤال صح و غلط هنقول لكم Isobutene is also
+
+285
+00:25:10,740 --> 00:25:16,340
+called 2 methyl 1-propene مظلوم الـ
+
+286
+00:25:16,340 --> 00:25:22,660
+Isobutene is 2 methyl 1-propene واضح؟ الآن
+
+287
+00:25:22,660 --> 00:25:27,970
+ممكن واحدة تيجي تسأل سؤال تقول يا دكتور، ليش أنا صار
+
+288
+00:25:27,970 --> 00:25:31,890
+عندي ظاهرة cis و trans في الـ 2 butene، حوالين
+
+289
+00:25:31,890 --> 00:25:36,130
+الـdouble bond؟ طب هي أنا في الـ 1 butene، عند
+
+290
+00:25:36,130 --> 00:25:41,710
+double bond، هل منها cis و trans؟ في الـIso
+
+291
+00:25:41,710 --> 00:25:47,570
+butene، عند double bond، هل منها cis و trans؟ واضح؟
+
+292
+00:25:47,570 --> 00:25:50,890
+إذا السؤال كأنه بالضبط ورتيش بيكون
+
+293
+00:25:55,200 --> 00:25:59,500
+وبقتاش بيكون من المركب اثنين ووبقتاش لأ ما بيكونش
+
+294
+00:25:59,500 --> 00:26:03,660
+من المركب اثنين ضالة الـ Sexual Trans ابتدوا
+
+295
+00:26:03,660 --> 00:26:08,620
+يوجد إذا كان حوالين الطرفين تبع الـ double bond
+
+296
+00:26:08,620 --> 00:26:12,940
+كل double bond عبارة عن كم طرف؟ طرفين high carbon
+
+297
+00:26:12,940 --> 00:26:17,300
+و high carbon هنا high carbon و high carbon هنا high
+
+298
+00:26:17,300 --> 00:26:20,300
+carbon high carbon high carbon high carbon لازم
+
+299
+00:26:20,300 --> 00:26:24,280
+حوالين كل طرف من الـ double bond يكون عنده مجموعتين
+
+300
+00:26:24,280 --> 00:26:30,810
+مختلفة لاحظوا هنا هذا الطرف شو عليه؟ هيدروجين
+
+301
+00:26:30,810 --> 00:26:35,550
+وهيدروجين طالما هذول المجموعتين زي بعض إذا مافيش
+
+302
+00:26:35,550 --> 00:26:40,090
+عندي طارد السيس والترانس مافيش من المركب إلا واحد،
+
+303
+00:26:40,090 --> 00:26:43,990
+هنا مظبوط في عندي هيدروجين ومجموعة ثانية، هذه
+
+304
+00:26:43,990 --> 00:26:48,250
+الكربون حولها مجموعتين مختلفتين، بس هذه الكربون
+
+305
+00:26:48,250 --> 00:26:50,250
+حولها نفس
+
+306
+00:26:58,830 --> 00:27:03,010
+CH3 مثل، إذا المجموعتين مختلفتين، هي الكلام، هذا
+
+307
+00:27:03,010 --> 00:27:07,890
+الـ carbon، شو حولها؟ CH3 مثل، إذا هذا الجزء فيه
+
+308
+00:27:07,890 --> 00:27:12,490
+نضمنه مركب ثاني، كيف برسم المركب الثاني؟ بثبت
+
+309
+00:27:12,490 --> 00:27:16,670
+كل الجزء، كإن في الناسخ واللاصق، بنسخ وبحطه هنا،
+
+310
+00:27:16,670 --> 00:27:21,870
+بخلي الجهة ثابتة وبعكس الجهة الثانية يعني لما أكون
+
+311
+00:27:21,870 --> 00:27:25,370
+راسم هذا الجزء بأقول لكم ارسموا لي الـ Iso مرة ثانية
+
+312
+00:27:25,370 --> 00:27:30,770
+بتاخذوا أنتو زي نسخ بتحطوها هنا هذا بتثبت جهة
+
+313
+00:27:30,770 --> 00:27:35,690
+بتعكس الجهة الثانية بيصير عندكم الـ Iso مرة ثانية
+
+314
+00:27:35,690 --> 00:27:41,850
+لاحظوا هنا هذا في منه مركب ولا اثنين الـ Iso butane
+
+315
+00:27:41,850 --> 00:27:47,590
+هذا الـ carbon شو حواليها؟ CH3 زي بعض وهذا الـ
+
+316
+00:27:47,590 --> 00:27:53,290
+carbon مثل ومثل برضه زي بعض والـ Trans كظاهرة
+
+317
+00:27:53,290 --> 00:27:58,850
+وحوالي كل Carbon مجموعتين مختلفة واضح؟ فهذه
+
+318
+00:27:58,850 --> 00:28:06,130
+الحالة بيكون من المركب اثنين واحد cis واحد trans
+
+319
+00:28:06,130 --> 00:28:09,170
+واضح؟
+
+320
+00:28:09,170 --> 00:28:20,730
+طيب بيجينا سؤال جديد بيجينا
+
+321
+00:28:20,730 --> 00:28:27,280
+سؤال جديد لو يا دكتور إذا مركب من المركبات كان عندي 
+
+322
+00:28:27,280 --> 00:28:32,680
+double bond و triple bond مركب إيش بيحتوي على
+
+323
+00:28:32,680 --> 00:28:37,860
+double bond و triple bond كيف بدي أسمي هذا المركب
+
+324
+00:28:37,860 --> 00:28:40,580
+اللي فيه double bond و triple bond يعني two
+
+325
+00:28:40,580 --> 00:28:45,580
+functional groups هل يا دكتور بدي اعتبره
+
+326
+00:28:54,450 --> 00:29:00,810
+الجواب بالشكل القاتل لو عندي double bond و triple
+
+327
+00:29:00,810 --> 00:29:09,250
+bond بنبدأ الترقيم من الجهة اللي بتكون أقرب لأ
+
+328
+00:29:09,250 --> 00:29:13,110
+الرابطة، بغض النظر كانت ثلاثية أو ثنائية، يعني
+
+329
+00:29:13,110 --> 00:29:17,550
+بجرب أرقم عن اليمين، بجرب أرقم عن الشمال، وين
+
+330
+00:29:17,550 --> 00:29:23,190
+الترقيم بيجي أسرع ما يمكن على double bond أو
+
+331
+00:29:23,190 --> 00:29:26,070
+triple bond بتكون الأولوية الترقيم بهذا الاتجاه،
+
+332
+00:29:26,070 --> 00:29:31,660
+يعني لو طلعنا هنا على هذا الجزء اللي موجود فوق ..
+
+333
+00:29:31,660 --> 00:29:35,160
+الجزء اللي موجود فوق وأنا متحير هي في double
+
+334
+00:29:35,160 --> 00:29:40,040
+bond أو triple bond مظبوط ولا لأ؟ من وين بدي أبدأ
+
+335
+00:29:40,040 --> 00:29:45,840
+أرقم .. من وين بدي أبدأ أرقم؟ بجرب هنا واحد فلحظة
+
+336
+00:29:45,840 --> 00:29:50,260
+اثنين مريت على multiple bond بغض النظر شو هي الآن
+
+337
+00:29:50,260 --> 00:29:53,700
+لو رقمت منها واحد اثنين ثلاثة ثلاثة ثلاثة ثلاثة
+
+338
+00:29:53,700 --> 00:29:56,040
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+339
+00:29:56,040 --> 00:29:56,240
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+340
+00:29:56,240 --> 00:29:58,780
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+341
+00:29:58,780 --> 00:30:07,900
+ثلاثة
+
+342
+00:30:07,900 --> 00:30:14,780
+ثلاثة
+
+343
+00:30:14,780 --> 00:30:22,420
+ثلاثة بعد ما حطيت الترقيم دائما بأذكر .. دائما
+
+344
+00:30:22,420 --> 00:30:30,130
+بأذكر من ناحية كتابية الـ Ene قبل الـ Yne في كل الحالات
+
+345
+00:30:30,130 --> 00:30:35,770
+دائما الـ Ene بتذكر قبل الـ Yne فالمشكلة عندي حقيقة
+
+346
+00:30:35,770 --> 00:30:39,550
+مش مين أذكره في الأول ومين في الثاني لأ دائما قولا
+
+347
+00:30:39,550 --> 00:30:44,390
+واحدا بأذكر أنا الـ Ene قبل الـ Yne لكن من وين أبدأ
+
+348
+00:30:44,390 --> 00:30:48,610
+الترقيم هنا المشكلة واضح؟ عشان هيك هذا المركب
+
+349
+00:30:57,690 --> 00:31:02,350
+لازم نحدد أين موقع الـ double bond من خلال نقطة
+
+350
+00:31:02,350 --> 00:31:06,050
+بدايتها وأين موقع الـ triple bond من خلال نقطة
+
+351
+00:31:06,050 --> 00:31:12,610
+بدايتها نقطة بداية الـ double bond موقع 4
+
+352
+00:31:13,790 --> 00:31:17,610
+واضح؟ الآن المركب هذا بيزن فيه double bond و triple
+
+353
+00:31:17,610 --> 00:31:22,690
+bond إذا هو in-line اتكون من مقطعين زي ما بيكون
+
+354
+00:31:22,690 --> 00:31:25,790
+عندكم course من الفيزياء والكيمياء، شو بنسميه؟
+
+355
+00:31:27,530 --> 00:31:30,870
+physical chemistry هذا في double bond و triple
+
+356
+00:31:30,870 --> 00:31:36,690
+bond إيش بدي أسميه؟ in, in, in, in, in, in, in, in,
+
+357
+00:31:36,690 --> 00:31:37,690
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+358
+00:31:37,690 --> 00:31:37,710
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+359
+00:31:37,730 --> 00:31:37,810
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+360
+00:31:37,810 --> 00:31:38,110
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+361
+00:31:38,110 --> 00:31:40,530
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+362
+00:31:40,530 --> 00:31:40,570
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+363
+00:31:40,570 --> 00:31:42,210
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+364
+00:31:42,210 --> 00:31:42,650
+in, in, in, in, in, in, in, in, in,
+
+365
+00:31:45,330 --> 00:31:53,250
+in, in
+
+366
+00:31:54,030 --> 00:32:00,230
+من الموقع اثنين وبعد هيك 4-yne والـ yne اللي هي للـ
+
+367
+00:32:00,230 --> 00:32:04,870
+triple point بتبدأ من موقع أربعة إذا أنا قطعت الاسم
+
+368
+00:32:04,870 --> 00:32:11,370
+عشان أقدر أوضح بالضبط وين موقع كل مجموعة واضح؟
+
+369
+00:32:11,370 --> 00:32:17,360
+الآن لو طلعتوا على الجزء شوية صغير انعكس لاحظوا
+
+370
+00:32:17,360 --> 00:32:20,920
+مرة ثانية لما بدأت أبدأ الترقيم واحد اثنين هي نقطة
+
+371
+00:32:20,920 --> 00:32:24,500
+البداية واحد اثنين ثلاثة إذا الترقيم من وين لازم
+
+372
+00:32:24,50
+
+401
+00:34:53,210 --> 00:34:57,290
+تكتبه بصيغة the one بيوتاين يعني ما تضطروش انكم 
+
+402
+00:34:57,290 --> 00:35:00,990
+تقطعوا الاسم و تحطوا الرقم في وسطه إلا في الحالات
+
+403
+00:35:00,990 --> 00:35:05,530
+اللي زي هذه اللي بكون عندي مجموعتين فبكون حطيت
+
+404
+00:35:05,530 --> 00:35:11,850
+لواحدة الرقم جبل و لواحدة الرقم في نص الاسم واضح
+
+405
+00:35:11,850 --> 00:35:17,650
+هذا المركب هذا المركب إذا بتطلع عليه فيه ال triple
+
+406
+00:35:17,650 --> 00:35:23,290
+bond و double bond، في triple bond و في double
+
+407
+00:35:23,290 --> 00:35:28,710
+bond، الآن من وين بدي أبدأ؟ بدي أقول من اللي بتكون
+
+408
+00:35:28,710 --> 00:35:32,430
+أقرب للترقيم، هنا ال triple bond بنمره واحد بتبدأ،
+
+409
+00:35:32,430 --> 00:35:35,610
+هنا ال double bond اثنين، إذا أنا مضطر أبدأ من
+
+410
+00:35:35,610 --> 00:35:38,610
+هنا، one, two, three, four, five، الآن إيش اللي
+
+411
+00:35:38,610 --> 00:35:43,310
+بيذكر قبل؟ een ولا ein؟ alphabetically الـ E قبل الـ
+
+412
+00:35:43,310 --> 00:35:48,750
+Y عشان هيك هذا لما بدوا يسموه بيسموه بنت بنت three
+
+413
+00:35:48,750 --> 00:35:52,490
+in one ein يعني كأنه هو بيقول إن الـ in بتبدأ في
+
+414
+00:35:52,490 --> 00:35:56,350
+موقع ثلاثة و الـ ein بتبدأ في موقع واحد هذا كان
+
+415
+00:35:56,350 --> 00:36:00,250
+ممكن يسميه بطريقة شبه من اللي هنا تقول three بنتين
+
+416
+00:36:00,250 --> 00:36:06,750
+one ein برضه بيمشي و هذا أنا بفضله three بنتين
+
+417
+00:36:06,750 --> 00:36:09,790
+one 
+
+418
+00:36:11,620 --> 00:36:18,480
+يمكن تبين ألطف من أنه نقطعه مرتين المثال اللي
+
+419
+00:36:18,480 --> 00:36:23,020
+بعده بتلاحظوا أن ال triple bond و double bond على
+
+420
+00:36:23,020 --> 00:36:30,700
+مسافتين متساويتين وجدتها نقطة البداية في الترقيم
+
+421
+00:36:30,700 --> 00:36:36,320
+بتكون حوالين ال double bond مش ال triple bond الـ E
+
+422
+00:36:36,320 --> 00:36:37,960
+مش الـ I
+
+423
+00:36:54,940 --> 00:36:59,260
+هنا في عندنا أمثلة إضافية بتوضح لنا لو كان عندنا
+
+424
+00:36:59,260 --> 00:37:04,360
+أكثر من double bond أو أكثر من triple bond يعني
+
+425
+00:37:04,360 --> 00:37:09,330
+هذا الجزء مثلًا كام double bond فيه؟ تن تن هيكون
+
+426
+00:37:09,330 --> 00:37:14,530
+ضايقين و بنحدد مواقعهم وين موقعهم لما نحط هاي نقطة
+
+427
+00:37:14,530 --> 00:37:20,650
+بداية و نقطة بداية one three بيوته ضايقين one
+
+428
+00:37:20,650 --> 00:37:24,370
+three بيوته ضايقين بيوته لإنه أربعة فبدون الأربعة
+
+429
+00:37:24,370 --> 00:37:28,270
+وين نقطة بداية ال double bonds على واحد و الثلاثة
+
+430
+00:37:28,270 --> 00:37:31,630
+إذا في substitute one زي هذه بنقول two مثل one
+
+431
+00:37:31,630 --> 00:37:37,070
+three بيوته ضايقين لو المركب اللي عندي cyclic حلقي
+
+432
+00:37:37,870 --> 00:37:45,290
+بدل ما كنت بسميه cycle بنتين بصير أقول cycle بنتين
+
+433
+00:37:45,290 --> 00:37:51,110
+.. in .. واضح؟ cycle بنتين لما بأبدأ الترقيم ..
+
+434
+00:37:51,110 --> 00:37:55,230
+لما بأبدأ الترقيم بلاحظ أنه بإمكاني أقول one two أو
+
+435
+00:37:55,230 --> 00:37:59,730
+one two .. واضح؟ لكن هذه ال one two بتمرنني على
+
+436
+00:37:59,730 --> 00:38:04,100
+المثلبتصير نمرة ثلاثة، لو قلت منها أنا one, two,
+
+437
+00:38:04,300 --> 00:38:08,380
+three, four, five، أنه أحسن، أقول لكم دائماً في
+
+438
+00:38:08,380 --> 00:38:12,320
+التسمية بنسعى نحو ال lower number إذا هذا ثلاثة
+
+439
+00:38:12,320 --> 00:38:18,540
+مثل Cyclopentane طبعًا
+
+440
+00:38:18,540 --> 00:38:21,060
+اللي بيقول حدد موقع هدول لأنه حاطينها دي ثلاثة
+
+441
+00:38:21,060 --> 00:38:26,860
+لاحظوا أنا Cyclohexane، لكن كام double bond فيه؟
+
+442
+00:38:26,860 --> 00:38:29,900
+إذا حيصير Cyclohexa
+
+443
+00:38:32,140 --> 00:38:35,080
+cyclohexadiene هنا لما بكون عندي اثنتين double
+
+444
+00:38:35,080 --> 00:38:39,060
+bonds بدوا يكون واضح عندكم أنه لازم أمر في اثنتين
+
+445
+00:38:39,060 --> 00:38:43,620
+double bonds كأولوية يعني كان بالإمكان واحدة تفكر
+
+446
+00:38:43,620 --> 00:38:46,680
+و تقول بدي أمشي من هنا واحد اثنين و أخلي لك روم
+
+447
+00:38:46,680 --> 00:38:50,380
+ثلاثة و بعدين طيب كويس لو ماشي من هنا هاي الـ
+
+448
+00:38:50,380 --> 00:38:53,860
+double bond عن أمر واحد اثنين ثلاثة أربعة خمسة
+
+449
+00:38:53,860 --> 00:38:58,280
+هذه وين بدأ تجيني على خمسة طب في عندي احتمال ثاني
+
+450
+00:38:58,280 --> 00:39:02,820
+أن أقول واحد اثنين ثلاثة .. لاحظوا هنا نقاط البداية
+
+451
+00:39:02,820 --> 00:39:05,480
+لل double bond .. ستين تان .. لازم أمر عنهم ..
+
+452
+00:39:05,480 --> 00:39:10,800
+اثنين تان .. واحد و ثلاثة .. و لبرومي بتجينا على
+
+453
+00:39:10,800 --> 00:39:14,900
+خمسة .. واحدة كان ممكن تفكر تقول واحد اثنين ثلاثة
+
+454
+00:39:14,900 --> 00:39:18,790
+..السنة متحيرين هاي واحد اثنين ثلاثة أو هاي واحد
+
+455
+00:39:18,790 --> 00:39:22,990
+اثنين ثلاثة يعني هيك one three و هيك one three بس الـ
+
+456
+00:39:22,990 --> 00:39:26,850
+one three اللي هنا بيجيب ليله بوم على five ال one
+
+457
+00:39:26,850 --> 00:39:31,250
+three اللي هنا one two three four five six شوفتوا
+
+458
+00:39:31,250 --> 00:39:35,670
+كيف؟ فأولويتي أن أمر على ال double points أسرع ما
+
+459
+00:39:35,670 --> 00:39:40,510
+يمكن بعدها إذا تساوى الاحتمالين بتطلع على ..
+
+460
+00:39:40,510 --> 00:39:44,470
+بتطلع على ال substitute الإضافية إذا هذا بدي يصف
+
+461
+00:39:44,470 --> 00:39:51,050
+.. بدي يصف five probe one three cyclohexa دينفس
+
+462
+00:39:51,050 --> 00:39:55,670
+الشيء هنا ثلاثة bonds هتشوفوا النهاية اثنين و
+
+463
+00:39:55,670 --> 00:39:59,770
+بتحددوا مواقعهم هنا cyclic ثلاثة double bonds
+
+464
+00:39:59,770 --> 00:40:05,870
+هيكون cyclo-octa اترايين و بنحدد مواقعهم و لاحظوا
+
+465
+00:40:05,870 --> 00:40:09,550
+مرت على كل ال double bonds one two three four five
+
+466
+00:40:09,550 --> 00:40:15,610
+على واحد بداية على ثلاثة على خمسة one three five cyclo
+
+467
+00:40:15,610 --> 00:40:24,830
+-octa اترايين لأنهم ثمان ثمان كربونات واضح؟ الآن
+
+468
+00:40:24,830 --> 00:40:30,450
+نرجع أكثر .. نرجع أكثر شويّة و توسع صغير لظاهرة ال
+
+469
+00:40:30,450 --> 00:40:35,010
+cisuelectrons اللي حكينا عنها زي ما حكينا احنا زي
+
+470
+00:40:35,010 --> 00:40:37,950
+ما الـ بيوتين الـ two-butene تحديدا فيه منه
+
+471
+00:40:37,950 --> 00:40:41,170
+cisuelectrons يعني مجموعتين الميثل ممكن يكونوا على
+
+472
+00:40:41,170 --> 00:40:46,050
+جهة واحدة أو على جهات متعاكسة الكلام ممكن يكون مع
+
+473
+00:40:46,050 --> 00:40:50,840
+غير مجموعات الميثل يعني ممكن يكون مع كلورين يعني لو
+
+474
+00:40:50,840 --> 00:40:55,260
+بدأ أحط الـ chlor على موقعين في جزء الـ ethane نفسه
+
+475
+00:40:55,260 --> 00:41:00,600
+ممكن أحط الـ chlor هنا و هنا و ممكن أحطه هنا و هنا
+
+476
+00:41:00,600 --> 00:41:06,840
+واضح؟ طبعًا ممكن أحط الـ chlor على ذرة واحدة يعني لو
+
+477
+00:41:06,840 --> 00:41:10,840
+كان عندي في الأساس جزء ethane بأربعة hydrogens لو
+
+478
+00:41:10,840 --> 00:41:14,220
+حاطيت ذرتين الـ chlor هنا، بيكون عندي من المركب واحد
+
+479
+00:41:14,220 --> 00:41:16,820
+ولا اثنين؟ واحد، واحد، واحد، واحد، واحد، واحد،
+
+480
+00:41:16,820 --> 00:41:17,660
+واحد، واحد، واحد، واحد، واحد، واحد، واحد، واحد،
+
+481
+00:41:17,660 --> 00:41:17,740
+واحد، واحد، واحد، واحد، واحد، واحد، واحد، واحد،
+
+482
+00:41:17,740 --> 00:41:19,780
+واحد، واحد، واحد، واحد، واحد اللي هو هذا المركب
+
+483
+00:41:19,780 --> 00:41:28,280
+تحديدًا أكلور أكلور أتش أتش هذا one-one
+
+484
+00:41:28,280 --> 00:41:34,400
+-dichloroethane وفيش منه غير مركب واحد ليش؟ لأن
+
+485
+00:41:34,400 --> 00:41:37,740
+هنا الذرتين زي بعض و هنا الذرتين زي بعض لكن لما
+
+486
+00:41:37,740 --> 00:41:42,140
+باجي بعمل ال one-two-dichloroethane بلاحظ منه cis
+
+487
+00:41:42,980 --> 00:41:48,120
+و منه ال trans .. منه ال cis ومنه ال trans .. واضح؟
+
+488
+00:41:48,120 --> 00:41:52,640
+فهذه ظاهرة ال cis و ال trans عبارة عن ظاهرة عامة
+
+489
+00:41:52,640 --> 00:41:59,320
+.. الآن في هذا المجال زي ما بتلاحظوا أن هدول
+
+490
+00:41:59,320 --> 00:42:04,280
+اثنتين زي بعض قولنا cis .. هدول اثنتين زي بعض قولنا
+
+491
+00:42:04,280 --> 00:42:10,560
+trans .. الأمور ممكن تصعب شويّة معنى ممكن تصعب شويّة
+
+492
+00:42:10,560 --> 00:42:15,760
+معناه زي المثال اللي موجود عندي هنا اتطلعوا معه
+
+493
+00:42:15,760 --> 00:42:20,620
+لو جيت اتطلعت على هذا الجزء هنا في عندي carbon
+
+494
+00:42:20,620 --> 00:42:25,840
+اليود و الـ chlor زي بعض لأ مجموعتين مختلفتين و هنا
+
+495
+00:42:25,840 --> 00:42:32,700
+عندي ال brom و الميثل زي بعض مجموعتين مختلفتين إذا
+
+496
+00:42:32,700 --> 00:42:39,370
+هذا الجزء منه منه مركبين .. منه مركبين .. كويس؟ لما
+
+497
+00:42:39,370 --> 00:42:42,790
+بدي أرسم المركب الثاني باخد هذا بانسخه زي ما هو و
+
+498
+00:42:42,790 --> 00:42:48,330
+بعكس هدول الاثنين .. الآن ازمنتكوا حكت هيك على
+
+499
+00:42:48,330 --> 00:42:52,910
+السريع قالت كلمة cis و trans لكن لو أنا بدي
+
+500
+00:42:52,910 --> 00:42:56,250
+أسألكم كيف بدي أعرف إنه cis و trans؟ لما كان يكون
+
+501
+00:42:56,250 --> 00:42:58,690
+عندي chlorine و chlorine أقول هدول زي بعض و
+
+502
+00:42:58,690 --> 00:43:02,190
+الموضوع سهل .. هذا المركب لما بدي أطلع عليه فيه
+
+503
+00:43:02,190 --> 00:43:07,060
+iod و probe و chlorine و methyl ولا واحدة بتشبه
+
+504
+00:43:07,060 --> 00:43:10,060
+الثانية عشان أقدر أقول أن هدول زي بعض و لا مش زي
+
+505
+00:43:10,060 --> 00:43:16,660
+بعض فبيصير صعب شويّة عليّ أن بسهولة أجاوب على السؤال
+
+506
+00:43:16,660 --> 00:43:19,940
+شو هو هذا المركب ال archive بيجيبوا عليه بيجوا
+
+507
+00:43:19,940 --> 00:43:22,580
+بتطلعوا على ال carbon الأولى بيقولوا تطلعوا على
+
+508
+00:43:22,580 --> 00:43:26,560
+أول ذرة متصلة فيها إيش إلها ال atomic number العدد
+
+509
+00:43:26,560 --> 00:43:30,800
+الذرعي وعلى أول ذرة هنا وشوفوا مين أعلى الآن كلكم
+
+510
+00:43:30,800 --> 00:43:35,800
+تذكرين الجدول الدوري اللي هو chlorine الكلور .. البروم
+
+511
+00:43:35,800 --> 00:43:39,280
+.. اليود .. أيه هو أعلى واحد فيهم؟ اليود .. اليود
+
+512
+00:43:39,280 --> 00:43:42,840
+.. إذا لما بدي أقارن اليود مع الكلور .. مين أعلى
+
+513
+00:43:42,840 --> 00:43:45,400
+في ال atomic number؟ اليود .. اليود .. بقول هي
+
+514
+00:43:45,400 --> 00:43:49,400
+الأعلى ..الآن بعد هيك بدي أجعل طلع .. في عند بروم
+
+515
+00:43:49,400 --> 00:43:53,040
+و المتصلة مباشرة carbon .. أيه هو أعلى في الـ
+
+516
+00:43:53,040 --> 00:43:57,120
+atomic number؟ البروم ولا ال carbon؟ كلهم حافظين
+
+517
+00:43:57,120 --> 00:44:00,600
+الشكل العام تبع الجدول الدوري .. البروم أعلى ..
+
+518
+00:44:00,600 --> 00:44:05,270
+إذا كأنه أنا قدرت أقول أن هذه أعلى و هذه أعلى الآن
+
+519
+00:44:05,270 --> 00:44:08,590
+المجموعتين الأعلى في ال atomic number اللي لهم
+
+520
+00:44:08,590 --> 00:44:12,510
+priority أو أولوية يجوا على جهة واحدة في هذه
+
+521
+00:44:12,510 --> 00:44:17,570
+الحالة كأنه المركب cis لاحظوا في الحالة الثانية لو
+
+522
+00:44:17,570 --> 00:44:22,550
+قلت chlorine و iod من الأعلى brom و carbon من
+
+523
+00:44:22,550 --> 00:44:29,030
+الأعلى لبروم الأعلى يجوا عكس بعض كأنه المركب trans
+
+524
+00:44:29,030 --> 00:44:32,770
+لكن في هذه الحالة اللي المجموعات مش زي بعض
+
+525
+00:44:32,770 --> 00:44:37,950
+بيستخدموش كلمة cis و trans بيستعملوا حروف جاية من
+
+526
+00:44:37,950 --> 00:44:42,270
+اللغة الألمانية حروف من وين جاية؟ من اللغة
+
+527
+00:44:42,270 --> 00:44:46,270
+الألمانية اللغة الألمانية فيها كلمة it's zusammen
+
+528
+00:44:46,270 --> 00:44:51,530
+it's zusammen يعني مع بعض جايين مع بعض فالأشياء
+
+529
+00:44:51,530 --> 00:44:56,470
+اللي جايين مع بعض بيستخدمولهم بدل كلمة cis حرف
+
+530
+00:44:56,470 --> 00:45:01,230
+الـ Z كأنه الـ Z الآن بنقدر نقول أن هو من ناحية
+
+531
+00:45:01,230 --> 00:45:06,550
+المبدأ موازي لل cis لكن ال cis حالة خاصة لما تكون
+
+532
+00:45:06,550 --> 00:45:10,430
+المجموعات زي بعض بنستعمل ال cis لما الحالة تصعب
+
+533
+00:45:10,430 --> 00:45:14,490
+شويّة الـ Z، لكن لو أنا بدأ أترجم ال cis معناها أنه
+
+534
+00:45:14,490 --> 00:45:18,230
+مع بعض أو من جهة واحدة و الـ zed معناها من جهة
+
+535
+00:45:18,230 --> 00:45:23,250
+واحدة، لكن أنيّ الحالة الأعام الـ Z لأن الـ Z بتجيب
+
+536
+00:45:23,250 --> 00:45:27,410
+لمجموعات مختلفة فبدي أعمل شويّة تحليل و أسأل نفسي
+
+537
+00:45:27,410 --> 00:45:31,610
+عن ال atomic numbers قبل ما أقدر أحط الجواب واضح؟
+
+538
+00:45:31,610 --> 00:45:36,930
+ولذلك أنا بظنهم زي بعض واستعملوا Z ولا التعاكس في
+
+539
+00:45:36,930 --> 00:45:42,560
+عندهم كلمة entgagen .. entgagen ضد بعض انت جاجل
+
+540
+00:45:42,560 --> 00:45:47,480
+فبيستعملوا البادئة E الآن كإنها البادئة E من ناحية
+
+541
+00:45:47,480 --> 00:45:53,200
+المبدأ موازية لل Trans لكن احنا كاستعمال احنا
+
+542
+00:45:53,200 --> 00:45:58,880
+كاستعمال بدنا نستعمل المجموعات اللي كلها مختلفة
+
+543
+00:45:58,880 --> 00:46:04,640
+نظام Z و E لما يكون الجزء بسيط زي الـ بيوتين مثل و
+
+544
+00:46:04,640 --> 00:46:09,240
+مثل زي دايكلور و كلور و كلور مبينين بسهولة نستعمل
+
+545
+00:46:09,240 --> 00:46:12,740
+cis و Trans ف الـ Z و الـ E هي الأعام و الـ cis و الـ
+
+546
+00:46:12,740 --> 00:46:19,440
+Trans بنبدأ نعتبرها حالة خاصة الـ Z موازية لل cis و
+
+547
+00:46:19,440 --> 00:46:26,340
+الـ E موازية لل Trans حتى لو الجزء كبر بضلني على نفس
+
+548
+00:46:26,340 --> 00:46:29,880
+الشيء يعني هنا مثلًا هاي double bond هذه متصلة بـ
+
+549
+00:46:29,880 --> 00:46:34,400
+CH3 و هذه متصلة بـ CH2 CH3 أنهي أكبر في الآخر في الـ
+
+550
+00:46:34,400 --> 00:46:39,660
+atomic number هذه لأن هنا H و H و H هنا H و H و
+
+551
+00:46:39,660 --> 00:46:44,400
+Carbon اللي بعد يعني أول atom carbon carbon على
+
+552
+00:46:44,400 --> 00:46:47,160
+العين والرأس بس اللي بعد هنا في carbon فكل هذه
+
+553
+00:46:47,160 --> 00:46:50,800
+المجموعة كأنه اللي بتصير الأعلى الآن لو أتيت طلعت
+
+554
+00:46:50,800 --> 00:46:57,910
+هذه carbon متصلة بإيش؟ بـ H و CH3 و O واحدة هذه
+
+555
+00:46:57,910 --> 00:47:05,470
+carbon متصلة بـ إيش؟ هذه اللي هنا بـ C و O و O الـ
+
+556
+00:47:05,470 --> 00:47:10,490
+double bond عملوها إيش؟ O مرتل فالآن carbon متصلة
+
+557
+00:47:10,490 --> 00:47:15,830
+بـ C و H و O ولا carbon متصلة بـ C و O و O أنيّ
+
+558
+00:47:15,830 --> 00:47:22,510
+أعلى؟ هذه ولذلك هذه المجموعة أعلى من هذه واضح؟ باجي
+
+559
+00:47:22,510 --> 00:47:29,310
+بتطلع على هذه الذرع، إيش متصلة؟ بـ C O O، هنا بـ C H
+
+560
+00:47:29,310 --> 00:47:33,110
+O، أنهي اللي أعلى؟ أكيد هذه، واضح؟ الآن هدول
+
+561
+00:47:33,110 --> 00:47:37,910
+المجمعتين زي بعض، إذا هذا المركب إيش بدو يكون؟ Z
+
+562
+00:47:37,910 --> 00:47:44,470
+كذلك الحال هنا، لو إجيت طلعت U DuClor أنه الأعلى؟
+
+563
+00:47:44,470 --> 00:47:48,530
+اليود واضح طب هنا لما أجهز طلع على مثل حلقة بنزين
+
+564
+00:47:48,530 --> 00:47:52,290
+مرة ثانية يعتبروا هذه carbon عادية و هذه carbon
+
+565
+00:47:52,290 --> 00:47:56,650
+الآن هنا carbon و carbon زي بعض بنطلع لمبعد هذه الـ
+
+566
+00:47:56,650 --> 00:48:02,750
+carbon متصلة بإيش؟ بـ carbon و carbon و H هذه الـ
+
+567
+00:48:02,750 --> 00:48:08,510
+carbon متصلة بإيش؟ بـ carbon و carbon و carbon إذا
+
+568
+00:48:08,510 --> 00:48:15,450
+أنهي هي الأعلى أنا لاحظوا معي ما باخدش الوزن الكلي للقطع
+
+569
+00:48:15,450 --> 00:48:19,710
+المتصل هنا لأ بمشي بالتدرج اللي بوضح لكم إياه هذه
+
+570
+00:48:19,710 --> 00:48:26,170
+متصلة بـ carbon و carbon واضح؟ مش واحدة تيجي تجمع
+
+571
+00:48:26,170 --> 00:48:31,170
+المجموعة جمع حسابي و تجتها بترتكب خطأ كبير يعني
+
+572
+00:48:31,170 --> 00:48:34,870
+بدي أعطيكم مثل لو كان عندكم double bonds مثلًا و
+
+573
+00:48:34,870 --> 00:48:38,810
+هنا
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..d6c0acd4990104a2bc1024a35682508647bd5e68
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg_raw.json
@@ -0,0 +1 @@
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الخواص و من ناحية التفاعلات واضح؟ هي الأشياء الأساسية اللي بدنا ندرسها في الموضوع التسمية و الخواص و التفاعلات طبعا حتى إن عود نتذكر بوقعهم في ال organ ال chemistry", "tokens": [67, 33147, 14713, 4032, 2423, 419, 4133, 4081, 9673, 23557, 4117, 3555, 9307, 13672, 1829, 8978, 16095, 15508, 14713, 4032, 46958, 5016, 22807, 8032, 1863, 47283, 3215, 16095, 9154, 8717, 39319, 10632, 16712, 38251, 10632, 9154, 8717, 39319, 10632, 33962, 2407, 33546, 4032, 9154, 8717, 39319, 10632, 16712, 5172, 995, 30241, 9307, 4032, 46958, 5016, 22807, 39896, 16247, 8592, 1829, 16606, 16247, 3794, 32277, 10632, 13672, 1829, 47525, 8315, 8717, 3215, 2288, 3794, 11296, 8978, 9673, 2407, 11242, 45367, 16712, 38251, 10632, 4032, 33962, 2407, 33546, 4032, 16712, 5172, 995, 30241, 9307, 23032, 3555, 3615, 995, 11331, 49975, 36145, 6225, 23328, 8717, 2655, 8848, 37983, 4724, 30543, 3615, 16095, 8978, 2423, 1798, 2423, 12558], "avg_logprob": -0.15679347100465194, "compression_ratio": 1.9, "no_speech_prob": 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"end": 144.88, "word": " ال", "probability": 0.783203125}, {"start": 144.88, "end": 145.18, "word": " single", "probability": 0.83837890625}, {"start": 145.18, "end": 145.54, "word": " bond", "probability": 0.81689453125}, {"start": 145.54, "end": 145.72, "word": " ما", "probability": 0.64599609375}, {"start": 145.72, "end": 146.08, "word": " زلتوا", "probability": 0.7596435546875}, {"start": 146.08, "end": 146.9, "word": " بتذكروها", "probability": 0.8271484375}, {"start": 146.9, "end": 147.36, "word": " بهذا", "probability": 0.923583984375}, {"start": 147.36, "end": 147.96, "word": " الشكل", "probability": 0.990966796875}, {"start": 147.96, "end": 149.14, "word": " أربع", "probability": 0.790771484375}, {"start": 149.14, "end": 149.78, "word": " روابط", "probability": 0.9757080078125}, {"start": 149.78, "end": 150.44, "word": " أزاوية", "probability": 0.72392578125}, {"start": 150.44, "end": 151.06, "word": " كده؟", "probability": 0.744140625}, {"start": 151.06, "end": 152.36, "word": " 109", "probability": 0.668212890625}, {"start": 152.36, "end": 152.82, "word": ".5", "probability": 0.800048828125}, {"start": 152.82, "end": 153.18, "word": " و", "probability": 0.480712890625}, {"start": 153.18, "end": 153.6, "word": " الشكل", "probability": 0.734375}, {"start": 153.6, "end": 154.12, "word": " حوالين", "probability": 0.981201171875}, {"start": 154.12, "end": 154.26, "word": " ال", "probability": 0.67138671875}, {"start": 154.26, "end": 154.76, "word": " carbon", "probability": 0.9599609375}, {"start": 154.76, "end": 156.32, "word": " تتراهيدرال", "probability": 0.8386579241071429}, {"start": 156.32, "end": 156.92, "word": " وال", "probability": 0.434326171875}, {"start": 156.92, "end": 158.38, "word": " hybridization", "probability": 0.935302734375}, {"start": 158.38, "end": 159.02, "word": " لهذا", "probability": 0.737060546875}, {"start": 159.02, "end": 159.16, "word": " ال", "probability": 0.7255859375}, {"start": 159.16, "end": 159.7, "word": " carbon", 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كان عندي جزء و هذا الجزء في single bond و أخدناه في ال conformations في إمكانية rotation و دوران حوالي ال single bond ملاحظين؟ في عندي إمكانية للدوران حوالي ال single bond لأنها رابطة ضعيفة", "tokens": [3224, 15730, 2423, 28820, 10943, 4724, 36081, 3555, 3615, 14407, 13412, 17082, 37977, 4724, 36081, 3555, 3615, 14407, 13412, 17082, 37977, 14739, 3224, 41850, 45164, 25961, 18871, 16254, 10874, 11622, 38207, 8978, 2167, 6086, 45164, 25961, 18871, 16254, 10874, 11622, 38207, 4032, 23758, 25724, 11622, 38207, 8978, 2167, 6086, 4032, 5551, 9778, 3215, 8315, 3224, 8978, 2423, 18975, 763, 8978, 11933, 2304, 41361, 10632, 12447, 4032, 11778, 13063, 7649, 11331, 2407, 6027, 1829, 2423, 2167, 6086, 3714, 15040, 5016, 19913, 9957, 22807, 8978, 18871, 16254, 11933, 2304, 41361, 10632, 24976, 3215, 13063, 7649, 11331, 2407, 6027, 1829, 2423, 2167, 6086, 5296, 33456, 11296, 12602, 16758, 9566, 3660, 48812, 3615, 33911, 3660], "avg_logprob": -0.16224887767540558, "compression_ratio": 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{"start": 503.02, "end": 503.38, "word": " لأنها", "probability": 0.8984375}, {"start": 503.38, "end": 504.02, "word": " رابطة", "probability": 0.989013671875}, {"start": 504.02, "end": 505.12, "word": " ضعيفة", "probability": 0.994384765625}], "temperature": 1.0}, {"id": 21, "seek": 51607, "start": 506.11, "end": 516.07, "text": "الان لو صار عندى ال triple bond ال rotation بصير restricted ممنوع لو جربنا نمسك جزء زى هذا بدنا نلفه", "tokens": [6027, 7649, 45164, 20328, 9640, 43242, 7578, 2423, 15508, 6086, 2423, 12447, 4724, 9381, 13546, 20608, 3714, 27842, 45367, 45164, 10874, 25513, 8315, 8717, 2304, 3794, 4117, 10874, 11622, 38207, 30767, 7578, 23758, 47525, 8315, 8717, 46538, 3224], "avg_logprob": -0.2443910225843772, "compression_ratio": 1.2142857142857142, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 506.11, "end": 506.71, "word": "الان", "probability": 0.780029296875}, {"start": 506.71, "end": 507.13, "word": " لو", "probability": 0.78173828125}, {"start": 507.13, 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" three", "probability": 0.53076171875}, {"start": 1212.49, "end": 1213.35, "word": " chloro", "probability": 0.6103515625}, {"start": 1213.35, "end": 1213.71, "word": " one", "probability": 0.8544921875}, {"start": 1213.71, "end": 1215.21, "word": " ibropine", "probability": 0.89599609375}], "temperature": 1.0}, {"id": 49, "seek": 124635, "start": 1225.14, "end": 1246.36, "text": "طبعا بعد البروبين لو بدي أجي لجزء اللي بعد اللي بقى أربع ذرات كربون هلاحظ أنه هيصير أمامي ظاهرة جديدة أنه أنا لما يصير عندي أربع ذرات كربون ال double bond ممكن أحطها بين واحد واتنين وممكن أحطها بين اتنين وتلاتة", "tokens": [9566, 3555, 3615, 995, 39182, 2423, 26890, 37746, 9957, 45164, 4724, 16254, 5551, 7435, 1829, 5296, 7435, 11622, 38207, 13672, 1829, 39182, 13672, 1829, 4724, 4587, 7578, 5551, 25513, 3615, 29910, 2288, 9307, 9122, 25513, 11536, 8032, 15040, 5016, 19913, 14739, 3224, 39896, 9381, 13546, 5551, 2304, 10943, 1829, 1357, 116, 40294, 25720, 10874, 16254, 41891, 14739, 3224, 41850, 5296, 15042, 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واحد و اتنين بيصير الجزء اسم واحد اتنين تلاتة اربعة و هي نقطة البداية what a beauty طب ممكن احط ال double bolt هنا بين الذرة اتنين و تلاتة ممكن احط ال clone بين الذرة اتنين و تلاتة لما اجي حقيقة اطبق هذا الكلام", "tokens": [2407, 46958, 5016, 22807, 45164, 11331, 9566, 36081, 2423, 3834, 13436, 49374, 32545, 25720, 36764, 24401, 4032, 1975, 2655, 1863, 9957, 4724, 1829, 9381, 13546, 25724, 11622, 38207, 24525, 2304, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 1975, 25513, 27884, 4032, 39896, 8717, 47432, 3660, 29739, 28259, 10632, 437, 257, 6643, 23032, 3555, 3714, 43020, 1975, 5016, 9566, 2423, 3834, 13436, 34105, 49374, 32545, 25720, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 3660, 3714, 43020, 1975, 5016, 9566, 2423, 26506, 49374, 32545, 25720, 1975, 2655, 1863, 9957, 4032, 6055, 1211, 9307, 3660, 5296, 15042, 1975, 7435, 1829, 11331, 38436, 28671, 1975, 9566, 3555, 4587, 23758, 2423, 28820, 10943], "avg_logprob": -0.16012168352582815, "compression_ratio": 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0.8478190104166666}, {"start": 1464.21, "end": 1465.11, "word": " اسمه", "probability": 0.943359375}, {"start": 1465.11, "end": 1466.87, "word": " isobutene", "probability": 0.69549560546875}, {"start": 1466.87, "end": 1467.63, "word": " بال", "probability": 0.8759765625}, {"start": 1467.63, "end": 1467.95, "word": " common", "probability": 0.270751953125}, {"start": 1467.95, "end": 1468.93, "word": " nucleation", "probability": 0.3804931640625}, {"start": 1468.93, "end": 1471.23, "word": " لأنه", "probability": 0.84130859375}, {"start": 1471.23, "end": 1471.81, "word": " و", "probability": 0.218994140625}, {"start": 1471.81, "end": 1472.01, "word": " هو", "probability": 0.96728515625}, {"start": 1472.01, "end": 1472.41, "word": " كله", "probability": 0.98974609375}, {"start": 1472.41, "end": 1472.75, "word": " single", "probability": 0.96142578125}, {"start": 1472.75, "end": 1473.27, "word": " bonds،", "probability": 0.8359375}, {"start": 1473.27, "end": 1473.41, "word": " شو", "probability": 0.9677734375}, {"start": 1473.41, "end": 1473.93, "word": " سمناه", "probability": 0.83642578125}, {"start": 1473.93, "end": 1474.65, "word": " المركب؟", "probability": 0.92236328125}], "temperature": 1.0}, {"id": 59, "seek": 149581, "start": 1477.65, "end": 1495.81, "text": "Isobutane لما كان كله single bonds لما بنعمل double bond طبعا نعملها على هذا الموقع زي هذا زي هذا بدي يصير Isobutane طب لو كنا بدنا نسميه في ال-iobaconomenclature بده أشوف أين أطول سلسلة تحتوي على", "tokens": [40, 539, 5955, 1929, 5296, 15042, 25961, 28242, 3224, 2167, 14713, 5296, 15042, 44945, 25957, 1211, 3834, 6086, 23032, 3555, 3615, 995, 8717, 25957, 1211, 11296, 15844, 23758, 9673, 30543, 3615, 30767, 1829, 23758, 30767, 1829, 23758, 47525, 1829, 7251, 9381, 13546, 286, 539, 5955, 1929, 23032, 3555, 45164, 9122, 8315, 47525, 8315, 8717, 38251, 1829, 3224, 8978, 2423, 12, 72, 996, 18181, 4726, 3474, 1503, 47525, 3224, 5551, 8592, 38688, 5551, 9957, 5551, 9566, 12610, 8608, 1211, 3794, 37977, 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"probability": 0.7935791015625}, {"start": 1489.05, "end": 1489.49, "word": " طب", "probability": 0.810791015625}, {"start": 1489.49, "end": 1489.67, "word": " لو", "probability": 0.96826171875}, {"start": 1489.67, "end": 1489.91, "word": " كنا", "probability": 0.6331787109375}, {"start": 1489.91, "end": 1490.23, "word": " بدنا", "probability": 0.8857421875}, {"start": 1490.23, "end": 1490.89, "word": " نسميه", "probability": 0.983642578125}, {"start": 1490.89, "end": 1491.21, "word": " في", "probability": 0.64208984375}, {"start": 1491.21, "end": 1492.01, "word": " ال", "probability": 0.40185546875}, {"start": 1492.01, "end": 1493.55, "word": "-iobaconomenclature", "probability": 0.5234898158482143}, {"start": 1493.55, "end": 1494.11, "word": " بده", "probability": 0.49560546875}, {"start": 1494.11, "end": 1494.29, "word": " أشوف", "probability": 0.8497721354166666}, {"start": 1494.29, "end": 1494.47, "word": " أين", "probability": 0.513427734375}, {"start": 1494.47, "end": 1494.83, "word": " أطول", "probability": 0.9845377604166666}, {"start": 1494.83, "end": 1495.27, "word": " سلسلة", "probability": 0.9208984375}, {"start": 1495.27, "end": 1495.63, "word": " تحتوي", "probability": 0.8723958333333334}, {"start": 1495.63, "end": 1495.81, "word": " على", "probability": 0.8193359375}], "temperature": 1.0}, {"id": 60, "seek": 152518, "start": 1495.98, "end": 1525.18, "text": "1,2,3 إذا one of propane و هذا ال one of propane على موقع اتنين إيش حامل مثل إذا لو بدنا نجيبلكوا سؤال صح و غلط هنقولكوا isobutene is also called two methyl one of propane مظلوم ال isobutene is two methyl one of propane واضح؟ الآن ممكن واحدة تيجي تسأل سؤال", "tokens": [16, 11, 17, 11, 18, 11933, 15730, 472, 295, 2365, 1929, 4032, 23758, 2423, 472, 295, 2365, 1929, 15844, 3714, 30543, 3615, 1975, 2655, 1863, 9957, 11933, 1829, 8592, 11331, 10943, 1211, 50113, 1211, 11933, 15730, 45164, 47525, 8315, 8717, 7435, 1829, 3555, 23275, 14407, 8608, 33604, 6027, 20328, 5016, 4032, 32771, 1211, 9566, 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propane", "probability": 0.5517578125}, {"start": 1499.58, "end": 1500.04, "word": " و", "probability": 0.67041015625}, {"start": 1500.04, "end": 1500.28, "word": " هذا", "probability": 0.83349609375}, {"start": 1500.28, "end": 1500.44, "word": " ال", "probability": 0.84326171875}, {"start": 1500.44, "end": 1500.56, "word": " one", "probability": 0.7607421875}, {"start": 1500.56, "end": 1500.72, "word": " of", "probability": 0.97705078125}, {"start": 1500.72, "end": 1501.08, "word": " propane", "probability": 0.9521484375}, {"start": 1501.08, "end": 1501.32, "word": " على", "probability": 0.79052734375}, {"start": 1501.32, "end": 1501.72, "word": " موقع", "probability": 0.9881184895833334}, {"start": 1501.72, "end": 1502.06, "word": " اتنين", "probability": 0.826904296875}, {"start": 1502.06, "end": 1502.32, "word": " إيش", "probability": 0.781982421875}, {"start": 1502.32, "end": 1502.76, "word": " حامل", "probability": 0.96337890625}, {"start": 1502.76, "end": 1504.06, "word": " مثل", "probability": 0.6973876953125}, {"start": 1504.06, "end": 1504.72, "word": " إذا", "probability": 0.8583984375}, {"start": 1504.72, "end": 1505.4, "word": " لو", "probability": 0.61474609375}, {"start": 1505.4, "end": 1505.7, "word": " بدنا", "probability": 0.9501953125}, {"start": 1505.7, "end": 1506.16, "word": " نجيبلكوا", "probability": 0.8636881510416666}, {"start": 1506.16, "end": 1506.46, "word": " سؤال", "probability": 0.9488932291666666}, {"start": 1506.46, "end": 1506.76, "word": " صح", "probability": 0.994384765625}, {"start": 1506.76, "end": 1506.86, "word": " و", "probability": 0.9326171875}, {"start": 1506.86, "end": 1507.22, "word": " غلط", "probability": 0.9529622395833334}, {"start": 1507.22, "end": 1508.02, "word": " هنقولكوا", "probability": 0.80556640625}, {"start": 1508.02, "end": 1509.5, "word": " isobutene", "probability": 0.7208251953125}, {"start": 1509.5, "end": 1510.0, "word": " is", "probability": 0.93359375}, {"start": 1510.0, "end": 1510.74, "word": " also", "probability": 0.86279296875}, {"start": 1510.74, "end": 1511.52, "word": " called", "probability": 0.92138671875}, {"start": 1511.52, "end": 1511.96, "word": " two", "probability": 0.72998046875}, {"start": 1511.96, "end": 1512.32, "word": " methyl", "probability": 0.70703125}, {"start": 1512.32, "end": 1512.56, "word": " one", "probability": 0.8662109375}, {"start": 1512.56, "end": 1512.72, "word": " of", "probability": 0.560546875}, {"start": 1512.72, "end": 1513.24, "word": " propane", "probability": 0.96630859375}, {"start": 1513.24, "end": 1514.88, "word": " مظلوم", "probability": 0.71490478515625}, {"start": 1514.88, "end": 1516.34, "word": " ال", "probability": 0.865234375}, {"start": 1516.34, "end": 1517.42, "word": " isobutene", "probability": 0.91552734375}, {"start": 1517.42, "end": 1518.02, "word": " is", "probability": 0.93505859375}, {"start": 1518.02, "end": 1518.5, "word": " two", "probability": 0.931640625}, {"start": 1518.5, "end": 1518.94, "word": " methyl", "probability": 0.9033203125}, {"start": 1518.94, "end": 1519.44, "word": " one", "probability": 0.95166015625}, {"start": 1519.44, "end": 1519.64, "word": " of", "probability": 0.98388671875}, {"start": 1519.64, "end": 1520.12, "word": " propane", "probability": 0.965087890625}, {"start": 1520.12, "end": 1521.2, "word": " واضح؟", "probability": 0.852294921875}, {"start": 1521.2, "end": 1522.66, "word": " الآن", "probability": 0.7105712890625}, {"start": 1522.66, "end": 1523.04, "word": " ممكن", "probability": 0.97509765625}, {"start": 1523.04, "end": 1523.66, "word": " واحدة", "probability": 0.9733072916666666}, {"start": 1523.66, "end": 1524.18, "word": " تيجي", "probability": 0.9742431640625}, {"start": 1524.18, "end": 1524.64, "word": " تسأل", "probability": 0.981689453125}, {"start": 1524.64, "end": 1525.18, "word": " سؤال", "probability": 0.9345703125}], "temperature": 1.0}, {"id": 61, "seek": 155089, "start": 1525.75, "end": 1550.89, "text": "تقول يا تورا، ليش أنا صار 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ISO مرة تانية لاحظوا هنا هذا في منه مركب ولا اتنين ال ISO butane هذا ال carbon شو حواليها أكترات زي بعض و هذا ال carbon مثل و مثل برضه زي بعض", "tokens": [40228, 22653, 5296, 15042, 5551, 30544, 12602, 32277, 2304, 23758, 25724, 11622, 38207, 5551, 39648, 4117, 14407, 1975, 2288, 38251, 12610, 1829, 2423, 25042, 3714, 25720, 6055, 7649, 10632, 48127, 2655, 9778, 3215, 14407, 16472, 2655, 14407, 30767, 1829, 8717, 3794, 9778, 39894, 5016, 9566, 2407, 11296, 34105, 23758, 39894, 12984, 3555, 2655, 10874, 3224, 3660, 39894, 3615, 4117, 3794, 25724, 3224, 3660, 16712, 7649, 10632, 4724, 9381, 13546, 43242, 4117, 14407, 2423, 25042, 3714, 25720, 6055, 7649, 10632, 20193, 5016, 19913, 14407, 34105, 23758, 8978, 9154, 3224, 3714, 31747, 3555, 49429, 1975, 2655, 1863, 9957, 2423, 25042, 457, 1929, 23758, 2423, 5954, 13412, 2407, 11331, 2407, 6027, 1829, 11296, 5551, 4117, 2655, 2288, 9307, 30767, 1829, 45030, 11242, 4032, 23758, 2423, 5954, 50113, 1211, 4032, 50113, 1211, 4724, 43042, 3224, 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1747.59, "text": "الجواب بالشكل القاتل لو عندى double bond و triple bond بنبدأ الترقيم من الجهة اللى بتكون اقرب", "tokens": [6027, 7435, 14407, 3555, 20666, 8592, 28820, 25062, 9307, 1211, 45164, 43242, 7578, 3834, 6086, 4032, 15508, 6086, 44945, 44510, 10721, 16712, 2288, 4587, 32640, 9154, 25724, 3224, 3660, 13672, 7578, 39894, 30544, 1975, 4587, 25513], "avg_logprob": -0.20080236003205582, "compression_ratio": 1.271186440677966, "no_speech_prob": 1.2516975402832031e-06, "words": [{"start": 1734.45, "end": 1735.77, "word": "الجواب", "probability": 0.766571044921875}, {"start": 1735.77, "end": 1736.43, "word": " بالشكل", "probability": 0.9168294270833334}, {"start": 1736.43, "end": 1737.07, "word": " القاتل", "probability": 0.83935546875}, {"start": 1737.07, "end": 1737.87, "word": " لو", "probability": 0.5224609375}, {"start": 1737.87, "end": 1739.65, "word": " عندى", "probability": 0.639892578125}, {"start": 1739.65, "end": 1740.05, "word": " double", "probability": 0.8857421875}, 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نحو ال lower number اذا هذا three مثل Cyclopentane طبعا اللي بيقول حدد موقع هدولة انه حاطينها دي three لاحظوا انا Cyclohexane، لكن كام double bond فيه؟ اذا حيصير Cyclohexa", "tokens": [3555, 2655, 9381, 13546, 8717, 2304, 25720, 6055, 1211, 9307, 3660, 12399, 45164, 12174, 1211, 2655, 9154, 11296, 1975, 8315, 472, 11, 732, 11, 1045, 11, 1451, 11, 1732, 12399, 16472, 3224, 1975, 5016, 3794, 1863, 12399, 1975, 39648, 5296, 4117, 14407, 11778, 16373, 15042, 8978, 16712, 38251, 10632, 44945, 3794, 3615, 7578, 8717, 5016, 2407, 2423, 3126, 1230, 1975, 15730, 23758, 1045, 50113, 1211, 49173, 404, 317, 1929, 23032, 3555, 3615, 995, 13672, 1829, 4724, 1829, 39648, 11331, 3215, 3215, 3714, 30543, 3615, 8032, 3215, 12610, 3660, 16472, 3224, 11331, 41193, 9957, 11296, 11778, 1829, 1045, 20193, 5016, 19913, 14407, 1975, 8315, 10295, 66, 752, 675, 87, 1929, 12399, 44381, 9122, 10943, 3834, 6086, 8978, 3224, 22807, 1975, 15730, 11331, 1829, 9381, 13546, 10295, 66, 752, 675, 36852], "avg_logprob": 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"probability": 0.9886474609375}, {"start": 2982.31, "end": 2982.93, "word": " باستعمل", "probability": 0.99443359375}, {"start": 2982.93, "end": 2983.55, "word": " Z", "probability": 0.9013671875}, {"start": 2983.55, "end": 2983.77, "word": " و", "probability": 0.1536865234375}, {"start": 2983.77, "end": 2983.95, "word": " E", "probability": 0.51025390625}, {"start": 2983.95, "end": 2984.73, "word": " المرة", "probability": 0.942626953125}, {"start": 2984.73, "end": 2985.03, "word": " الجاية", "probability": 0.75830078125}, {"start": 2985.03, "end": 2985.13, "word": " ان", "probability": 0.716796875}, {"start": 2985.13, "end": 2985.29, "word": " شاء", "probability": 0.960205078125}, {"start": 2985.29, "end": 2985.35, "word": " الله", "probability": 0.9580078125}, {"start": 2985.35, "end": 2985.83, "word": " بنبدأ", "probability": 0.9217122395833334}, {"start": 2985.83, "end": 2986.19, "word": " فيه", "probability": 0.736572265625}, {"start": 2986.19, "end": 2987.39, "word": " تفاعلات", "probability": 0.9314453125}, {"start": 2987.39, "end": 2988.71, "word": " ال", "probability": 0.96533203125}, {"start": 2988.71, "end": 2988.93, "word": " ال", "probability": 0.1531982421875}, {"start": 2988.93, "end": 2989.21, "word": " keys", "probability": 0.4599609375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2989.7085, "duration_after_vad": 2818.1131249999844}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2d4b163d58942966bb7c29e625ef1998c1699d9f
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo.srt
@@ -0,0 +1,1741 @@
+1
+00:00:08,680 --> 00:00:13,720
+المرة الماضية اتكلمنا عن بداية تفاعلات الـ E-stars
+
+2
+00:00:13,720 --> 00:00:18,040
+وقلنا الـ E-stars ومشتقات الأحماض بشكل عام تفاعلها
+
+3
+00:00:18,040 --> 00:00:22,440
+الأساسي هو تفاعل إيش؟ الـ Substitution الـ
+
+4
+00:00:22,440 --> 00:00:26,920
+Nucleophilic Substitution بمعنى مجموعة الـ OR
+
+5
+00:00:26,920 --> 00:00:33,080
+بتطلع، و بيدخل عندنا مجموعة النوكليوفيل أيًّا كانت
+
+6
+00:00:33,080 --> 00:00:37,960
+الآن المرة هذه بناخد تفاعل الـ E-stars مع متفاعل
+
+7
+00:00:37,960 --> 00:00:43,080
+Grignard وبشكل عام بيحطوا متفاعل Grignard بزيادة
+
+8
+00:00:43,080 --> 00:00:48,850
+طبعًا بتكونوا متذكرين أن Grignard Reagent سابقًا أن
+
+9
+00:00:48,850 --> 00:00:55,090
+اتكلمنا عنه أن هو عبارة عن R مع أزواج إلكترونات
+
+10
+00:00:55,090 --> 00:00:59,150
+بمعنى الـ Grignard Reagent هو عبارة عن الـ
+
+11
+00:00:59,150 --> 00:01:02,970
+Nucleophile واضح؟ بناء على ذلك طالما الـ Grignard
+
+12
+00:01:02,970 --> 00:01:07,130
+Reagent بالنسبة لي بيمثل هذه الشغلة، ما عدا
+
+13
+00:01:07,130 --> 00:01:11,530
+ذلك، مش مهم، R مع أزواج إلكترونات الـ Nucleophile
+
+14
+00:01:11,530 --> 00:01:14,770
+إذا إيش تفاعل الأساسي مع الـ E-star؟ 
+
+15
+00:01:23,040 --> 00:01:28,620
+هذه الـ R تبعت لجرينيار ده أنا حاطط لها R'' على
+
+16
+00:01:28,620 --> 00:01:32,640
+أساس أنه يميزها عن الـ R اللي موجودين يعني أيًا
+
+17
+00:01:32,640 --> 00:01:37,820
+كانت مثل إيثيل فينيل الخلاصة المجموعة الـ R كلها أو الـ R
+
+18
+00:01:37,820 --> 00:01:43,870
+اللي مع جرينيار بتيجي محل الـ OR فبيصير عندك كيتون
+
+19
+00:01:43,870 --> 00:01:48,350
+هذا كيف يتم التفاعل بالنصف مش كثير موضوع لكن
+
+20
+00:01:48,350 --> 00:01:54,150
+الاستبدال سهل أنه الـ Grignard nucleophile بتيجي
+
+21
+00:01:54,150 --> 00:01:58,350
+محل الـ OR الآن لاحظوا هنا في الخطوة الأولى صار
+
+22
+00:01:58,350 --> 00:02:04,280
+عندك كيتون إذا رجعتوا لتفاعلات الـ ketones مع
+
+23
+00:02:04,280 --> 00:02:07,740
+Grignard هتلاحظوا أن الكيتون بتفاعل مع Grignard
+
+24
+00:02:07,740 --> 00:02:11,760
+بناءً على ذلك لو كان عندي كمان كمية إضافية من
+
+25
+00:02:11,760 --> 00:02:18,580
+Grignard بمعنى عندي كمان كمية إضافية من الـ R تبع
+
+26
+00:02:18,580 --> 00:02:22,360
+الـ Grignard في هذه الحالة الكمية الإضافية هتتفاعل
+
+27
+00:02:22,360 --> 00:02:26,680
+مع إيش؟ مع الكيتون الكيتون تفاعله
+
+28
+00:02:29,720 --> 00:02:35,060
+addition إضافة واضح؟ إذا بيصير عندنا التفاعلين هاي
+
+29
+00:02:35,060 --> 00:02:39,060
+النتج النهائي مرة ثانية أنه دخلت R group ثانية والـ
+
+30
+00:02:39,060 --> 00:02:44,580
+O صارت OH إذا بتذكروا كنا بهذا الشكل نعمل
+
+31
+00:02:44,580 --> 00:02:49,360
+التفاعل متذكرين؟ إذا الـ Grignard بنقدر نقول أنه
+
+32
+00:02:49,360 --> 00:02:54,160
+بيتفاعل على مرحلتين مع الـ ester لما يكون بكمية
+
+33
+00:02:54,160 --> 00:03:00,790
+مضاعفة بمكافئ مضاعف التفاعل الأول substitution
+
+34
+00:03:00,790 --> 00:03:07,190
+استبدال بيؤدي إلى تكوين الكيتون ثم يتفاعل مباشرة
+
+35
+00:03:07,190 --> 00:03:11,810
+بتفاعل إضافة يؤدي إلى تكوين هذا الكحول هذا
+
+36
+00:03:11,810 --> 00:03:16,090
+الكحول إذا بتطلع عليه، Tertiary alcohol عشانكم 
+
+37
+00:03:16,090 --> 00:03:21,750
+متعودين احنا نقول الآن أنه تفاعل الـ ester مع كمية
+
+38
+00:03:21,750 --> 00:03:27,050
+مضاعفة من الـ Grignard في المحصلة بيعطيني Tertiary
+
+39
+00:03:27,050 --> 00:03:30,970
+Alcohol هذا الـ tertiary alcohol المتكون بيكون
+
+40
+00:03:30,970 --> 00:03:36,230
+فيه مجموعتين زي بعض ليش المجموعتين زي بعض؟ لأنهم
+
+41
+00:03:36,230 --> 00:03:41,930
+إجوا من الـ Grignard على مرتين إجوا من الـ Grignard
+
+42
+00:03:41,930 --> 00:03:45,650
+reaction على مرتين المرة الأولى إجت R double
+
+43
+00:03:45,650 --> 00:03:50,150
+prime وطردت الـ OR والمرة الثانية أضيفة الـ R
+
+44
+00:03:50,150 --> 00:03:54,850
+double prime و C double point O صارت OH فكمحصلة
+
+45
+00:03:57,060 --> 00:04:00,840
+التجارب الأساسية لتجارب الـ Grignard Reagent هي
+
+46
+00:04:00,840 --> 00:04:02,240
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+47
+00:04:02,240 --> 00:04:02,660
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+48
+00:04:02,660 --> 00:04:07,960
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+49
+00:04:07,960 --> 00:04:09,180
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+50
+00:04:09,180 --> 00:04:11,240
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+51
+00:04:11,240 --> 00:04:12,320
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+52
+00:04:12,320 --> 00:04:16,560
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+53
+00:04:16,560 --> 00:04:21,030
+تجارب التجارب الأسكيف ممكن تحضروا الـ tertiary
+
+54
+00:04:21,030 --> 00:04:24,790
+alcohol؟ بأي طريقة أنتم عارفينها تريدون أن تبدأ
+
+55
+00:04:24,790 --> 00:04:28,910
+بالـ ester وتفعلوا مع Grignard مرتين ممكن
+
+56
+00:04:28,910 --> 00:04:31,710
+ما يكونش معطيكم تبدأ من الـ ester ممكن تبدأ من الـ
+
+57
+00:04:31,710 --> 00:04:36,450
+acid فهذه الحالة الـ acid بتحوله لـ ester والـ
+
+58
+00:04:36,450 --> 00:04:44,410
+ester بتفعل مع Grignard مرتين واضح؟ لكن طالما
+
+59
+00:04:44,410 --> 00:04:50,070
+أنه معطيكم هنا لـ Grignard بنسبة مضاعفة أو
+
+60
+00:04:50,070 --> 00:04:55,230
+كاتب excess المفروض لو بدي أجيب إكمال معادلة شغلة
+
+61
+00:04:55,230 --> 00:04:59,590
+زي هيك بس يكون عندي هذا الجواب اللي هنا أنه Grignard
+
+62
+00:04:59,590 --> 00:05:05,090
+reagent اتفعل مرتين كل هذه الأشياء بهمنيش أشوفها واضح
+
+63
+00:05:05,090 --> 00:05:08,650
+كل هذه الأشياء بهمنيش أشوفها لما أقول لكم complete
+
+64
+00:05:08,650 --> 00:05:12,170
+the following equation حط لكم فراغ Grignard مع
+
+65
+00:05:12,170 --> 00:05:16,670
+ester Grignard excess مع ester Tertiary alcohol
+
+66
+00:05:16,670 --> 00:05:22,130
+بمجموعتين الـ R اللي جايين من الـ Grignard reagent
+
+67
+00:05:34,010 --> 00:05:38,590
+من تفاعلات الـ E-stars اللي هي أيضًا تفاعلات إبدال
+
+68
+00:05:38,590 --> 00:05:42,310
+اللي بنسميها الـ ammonolysis التفاعل مع الـ ammonia
+
+69
+00:05:42,310 --> 00:05:46,190
+لو اتطلعنا الـ ammonia nucleophile بنفس المبدأ
+
+70
+00:05:46,190 --> 00:05:50,730
+بتتفاعل وتبرد الـ OR حيث أن عندي RC ضو الـ bond O
+
+71
+00:05:50,730 --> 00:05:55,290
+and H2 من الـ ammonia بناء على ذلك الـ E-star مع الـ
+
+72
+00:05:55,290 --> 00:06:02,030
+ammonia بيعطيني الاميد واضح؟ أيًا كان، هذا مثال إضافي
+
+73
+00:06:02,030 --> 00:06:08,610
+هذا E-star مع ammonia بيعطينا الاميد وهذا تفاعل زي
+
+74
+00:06:08,610 --> 00:06:14,770
+ما بتلاحظ أنه تكراري يعني بنكرر احنا تقريبًا نفس
+
+75
+00:06:14,770 --> 00:06:21,030
+الكلام الـ nucleophile بحل محل الـ OR من
+
+76
+00:06:21,030 --> 00:06:26,630
+تفاعلات الـ E-stars من تفاعلات الـ E-stars اللي هو
+
+77
+00:06:26,630 --> 00:06:34,670
+تفاعل الـ reduction of E-stars حقيقة
+
+78
+00:06:34,670 --> 00:06:39,910
+تفاعل الـ reduction of E-stars مع الـ lithium
+
+79
+00:06:39,910 --> 00:06:44,430
+aluminum hydride مع الـ lithium aluminum hydride
+
+80
+00:06:44,430 --> 00:06:48,330
+هذا الـ hydride احنا اتفقنا كـ reducing agent هو
+
+81
+00:06:48,330 --> 00:06:49,550
+مصدر لإيش؟
+
+82
+00:06:52,520 --> 00:06:55,960
+الـ H مع أزواج الإلكترونات
+
+83
+00:07:04,840 --> 00:07:09,480
+Hydride anion الليثيوم الومنوم هيدرايد هذا مصدر
+
+84
+00:07:09,480 --> 00:07:13,360
+الهيدرايد أيون إيش اللي بيعملوا في الـ reduction؟
+
+85
+00:07:13,360 --> 00:07:18,500
+إذا بتقدروا تطلعوا عمل شبيه جدًّا بمتفاعل جرينيار
+
+86
+00:07:18,500 --> 00:07:24,900
+اتذكروا في إيه؟ الـ Grignard اتفاعل الـ E-star اتفاعل
+
+87
+00:07:24,900 --> 00:07:33,260
+الـ E-star مع الـ R minus مرتين والـ O صارت هنا نفس
+
+88
+00:07:33,260 --> 00:07:39,160
+الشيء كأن الـ H- تهاجم في الخطوة الأولى تطرد الـ
+
+89
+00:07:39,160 --> 00:07:44,600
+OR والـ H- تهاجم في الخطوة الثانية تحول هذه إلى
+
+90
+00:07:44,600 --> 00:07:50,440
+OH فبالمحصّلة لهذا التفاعل موازٍ موازاة تفاعل
+
+91
+00:07:50,440 --> 00:07:55,380
+جرينيار أن أنا فعلت مع الـ nucleophile مرتين يعني لما
+
+92
+00:07:55,380 --> 00:08:01,000
+أجي في الخطوة الأولى أقول زي هيك حصّل عندك R
+
+93
+00:08:19,040 --> 00:08:24,520
+بناءً على ذلك مرة ثانية كان محصلة الـ reduction of E
+
+94
+00:08:24,520 --> 00:08:31,080
+stars with hydrides produces primary alcohols تبقى
+
+95
+00:08:31,080 --> 00:08:37,270
+صحيحة بمعنى أن هذه الـ C double bond O مكانها بجي
+
+96
+00:08:37,270 --> 00:08:46,010
+بتطلع في عندي C double bond O لأ مش OH CH2 OH ناس
+
+97
+00:08:46,010 --> 00:08:48,690
+كثير لما يحطولي الجواب، مهّمش ليش الغلطة هذه و
+
+98
+00:08:48,690 --> 00:08:54,310
+بعتبرها خطأ بيروح وبيحط لي R OH هي خلطة وين راحت
+
+99
+00:08:54,310 --> 00:09:00,390
+الـ C؟ يعني بيكونوا طرّسوا نوعًا ما ويعرفوا أنه الـ E-
+
+100
+00:09:00,390 --> 00:09:03,070
+star بالليثيوم ألومنيوم هيدرايد بيصير له reduction
+
+101
+00:09:03,070 --> 00:09:07,630
+وبيصير alcohol لكن لما ييجي ينفذ الجواب بيكتبش
+
+102
+00:09:07,630 --> 00:09:15,890
+RCH2OH بيروح بيكتب R OH طب هون راحت الـ C إذا الجواب
+
+103
+00:09:15,890 --> 00:09:22,510
+الصحيح R والـ C نفسها بتصير CH2 لأن الـ C موجودة و
+
+104
+00:09:22,510 --> 00:09:26,270
+أضيف عليها الـ H mark دين فبتصير
+
+105
+00:09:28,630 --> 00:09:34,170
+CH2OH R CH2OH إذا بنقدر نقول ببساطة إنه reduction
+
+106
+00:09:34,170 --> 00:09:40,770
+of esters produces primary alcohols الآن هذا
+
+107
+00:09:40,770 --> 00:09:44,890
+الكلام للي بيحبوا الأسئلة بنقدر نسأل عنه بسؤال صح
+
+108
+00:09:44,890 --> 00:09:48,010
+وغلط نقول reduction of esters produces aldehydes
+
+109
+00:09:48,010 --> 00:09:58,400
+أو كيتون أو كربوكسيليك أسيد primary alcohol primary
+
+110
+00:09:58,400 --> 00:10:06,240
+alcohol primary alcohol primary alcohol primary
+
+111
+00:10:06,240 --> 00:10:07,180
+alcohol primary alcohol primary alcohol alcohol
+
+112
+00:10:07,180 --> 00:10:07,280
+primary alcohol primary alcohol primary alcohol primary
+
+113
+00:10:07,280 --> 00:10:07,540
+alcohol primary alcohol primary alcohol primary alcohol
+
+114
+00:10:07,540 --> 00:10:10,900
+primary alcohol primary alcohol primary alcohol primary
+
+115
+00:10:10,900 --> 00:10:15,620
+alcohol
+
+116
+00:10:15,620 --> 00:10:22,360
+بالليثيوم ألومنيوم هايدريد بس بيشتغل على الـ double
+
+117
+00:10:22,360 --> 00:10:28,260
+bonds بيسبقه من الـ double bonds بناءً على ذلك الـ C
+
+118
+00:10:28,260 --> 00:10:34,860
+double bond O شو هتصير؟ شوفوا 
+
+119
+00:10:34,860 --> 00:10:39,080
+الناس اللي بتتغلبوا لما يكتبوا النواتج كل شيء
+
+120
+00:10:39,080 --> 00:10:42,500
+بتيجي زي ما هو في النهاية الـ production of ester
+
+121
+00:10:42,500 --> 00:10:53,960
+بيحول الـ C double bond O بحول الـ CH2OH إلى CH2OH
+
+122
+00:11:03,740 --> 00:11:10,800
+في تفاعل لـ الـ E-stars موازٍ بشكل كبير جدًّا للتفاعل
+
+123
+00:11:10,800 --> 00:11:14,660
+اللي أخذناه اللي قلنا عنه الـ aldol reaction في
+
+124
+00:11:14,660 --> 00:11:19,620
+الـ aldol reaction كنت آخذ جزيئين ألدهيد وأفعلهم مع
+
+125
+00:11:19,620 --> 00:11:23,840
+base واحد يصير الـ nucleophile وبعدين يعمل
+
+126
+00:11:23,840 --> 00:11:29,080
+addition على الجزء الثاني إذا رجعتوا بذاكرتكم الآن في
+
+127
+00:11:29,080 --> 00:11:33,860
+الـ E-stars بعمل نفس الشيء بآخذ جزئين من الـ E-
+
+128
+00:11:33,860 --> 00:11:38,760
+stars بفعلهم مع واحد من الـ base الـ base هتيجي على
+
+129
+00:11:38,760 --> 00:11:42,800
+مكان الـ alpha hydrogen اللي هي الـ hydrogen اللي
+
+130
+00:11:42,800 --> 00:11:47,880
+جانب الـ C double bond O هتشيل الـ hydrogen هتصير هذه
+
+131
+00:11:47,880 --> 00:11:55,670
+الـ CH2 شحنة سالبة أيون سالب صارت nucleophile الآن
+
+132
+00:11:55,670 --> 00:12:01,370
+صارت تفاعل ببساطة nucleophile بتفاعل مع ester شو
+
+133
+00:12:01,370 --> 00:12:06,450
+تفاعل nucleophile مع الـ ester Substitution
+
+134
+00:12:06,450 --> 00:12:14,510
+إبدال بمعنى هذا بيجي يهاجم زي هيك وهذا تطلع واضح؟
+
+135
+00:12:16,290 --> 00:12:21,690
+بناءً على ذلك الناتج اللي عندي هيكون CH3CWbO هذه
+
+136
+00:12:21,690 --> 00:12:26,510
+اللي في المربع الأزرق هذه جاية من الـ ester الأول
+
+137
+00:12:26,510 --> 00:12:31,810
+ومن الـ ester الثاني CH2CWbO O CH2 CH3 بحطها زي ما
+
+138
+00:12:31,810 --> 00:12:38,370
+هي لاحظوا هذا التفاعل موازٍ لتفاعل الدول تفاعل الدول
+
+139
+00:12:38,370 --> 00:12:43,770
+كنت آخذ جزيئين ألدهيد واحد أخليه أيون لما يتفاعل
+
+140
+00:12:43,770 --> 00:12:48,360
+مع الثاني شو التفاعل اللي كان يعمله؟ إضافة
+
+141
+00:12:48,360 --> 00:12:52,580
+الـ nucleophile مع الديهيد أو كيتون إضافة الـ nucleophile
+
+142
+00:12:52,580 --> 00:12:53,540
+مع الـ E-star
+
+143
+00:13:01,720 --> 00:13:07,960
+substitution إبدال بينما الـ aldol reaction is an
+
+144
+00:13:07,960 --> 00:13:12,180
+addition reaction واضح؟ هذا السؤال صح و غلط الـ aldol
+
+145
+00:13:12,180 --> 00:13:20,400
+reaction is an addition reaction because الـ aldol
+
+146
+00:13:20,400 --> 00:13:26,520
+بتعامل مع الـ aldehydes الـ aldol بتعامل مع الـ
+
+147
+00:13:26,520 --> 00:13:31,970
+aldehydes والـ ketones تفاعلها الأساسي الـ Claisen
+
+148
+00:13:31,970 --> 00:13:36,970
+reaction بتعمل مع الـ E-stars والـ E-stars تفاعلها
+
+149
+00:13:36,970 --> 00:13:38,890
+الأساسي substitution
+
+150
+00:13:40,780 --> 00:13:45,300
+هي مثلًا مثال ثاني هذا الجزء لو بده يعمل Claisen
+
+151
+00:13:45,300 --> 00:13:49,280
+condensation الآن احنا اتفقنا سابقًا إيش أفضل طريقة
+
+152
+00:13:49,280 --> 00:13:54,180
+لكتابة ناتج Claisen أو aldol أن احط جزئين جان بعض
+
+153
+00:13:54,180 --> 00:13:57,320
+بالضبط زي ما حكت زميلتكم بناء على ذلك هان أنا
+
+154
+00:13:57,320 --> 00:14:03,220
+بتخيل أن عندي صيبة بالـ bond O O CH2 CH3 وهنا احط
+
+155
+00:14:03,220 --> 00:14:10,180
+CH2 وهنا احط CH3 هي جزء وجزء واحد منهم بده يصير
+
+156
+00:14:11,800 --> 00:14:16,300
+أيّون ويهاجم على الثاني الآن من وين بيصير أيون ويحذف
+
+157
+00:14:16,300 --> 00:14:20,420
+بروتون؟ من جانب الـ C double bond O من الـ alpha
+
+158
+00:14:20,420 --> 00:14:25,260
+hydrogen، إذا هنا حيصير عنده negative، هذا الايون
+
+159
+00:14:25,260 --> 00:14:31,900
+هذا اللي صار nucleophile بيهاجم على الجزء هذا
+
+160
+00:14:31,900 --> 00:14:33,120
+ويطرد
+
+161
+00:14:37,260 --> 00:14:42,280
+بناءً على ذلك بيصير عندكم هذا الجزء اللي هو مبين
+
+162
+00:14:42,280 --> 00:14:50,920
+باللون الأصفر CH3CH2C double bond O وهذا من وين
+
+163
+00:14:50,920 --> 00:14:58,240
+بيكون التصل من الـ CH اللي هنا إذا هنا المجموعة
+
+164
+00:14:58,240 --> 00:15:03,310
+الميثيل هتكون لا تحت أو لا فوق مش مشكلة المهم هو بتصل
+
+165
+00:15:03,310 --> 00:15:06,810
+من الـ C اللي جنب الكربون هذه المسألة في معظم
+
+166
+00:15:06,810 --> 00:15:10,430
+المرات لما بيصير خطأ فيها بيجي الطالب بيروح بيعمل
+
+167
+00:15:10,430 --> 00:15:15,590
+الـ minus هنا ويحط هدول بشكل مستقيم هنا محور
+
+168
+00:15:15,590 --> 00:15:21,350
+الخطأ في هذا السؤال فالـ minus دائمًا وين بيكون؟ على
+
+169
+00:15:21,350 --> 00:15:27,090
+الـ alpha-hydrogen المركب اللي أنت لازم تفعله أنت
+
+170
+00:15:27,090 --> 00:15:32,080
+أخذت الكربون اللي بتفرق بالـ R اللي جنب الـ O هي
+
+171
+00:15:32,080 --> 00:15:41,560
+الـ C double bond O من جنبها شيلنا بروتون الهجوم
+
+172
+00:15:41,560 --> 00:15:44,160
+على الكربونة المتصلة بالـ O في كل الـ E-stars
+
+173
+00:15:47,770 --> 00:15:52,110
+هذا من أساس أساس كيمياء الـ ester هذا أساس الإبدال
+
+174
+00:15:52,110 --> 00:15:57,670
+في الـ ester أن المجموعة اللي بتفقد هي الـ OR هذا
+
+175
+00:15:57,670 --> 00:16:01,830
+
+201
+00:18:18,920 --> 00:18:22,900
+كنت أكون ماشيًا على أي اسم إيثانويك أسد
+
+202
+00:18:22,900 --> 00:18:29,780
+إيثانويل كلوريد بس طبعًا شهرته أنه عندي أسيتيك أسد
+
+203
+00:18:29,780 --> 00:18:34,920
+وبنزويل كلوريد طب لو قلت لكم بده مركب بنزويل كلوريد
+
+204
+00:18:37,610 --> 00:18:49,270
+بنزويك أسد مع Cl يعني ارسموا لي شكل بنزويل Cl هذه
+
+205
+00:18:49,270 --> 00:18:57,710
+الـCOO جاية من بنزويك أسد مع Cl إذًا أين مجموعة 
+
+206
+00:18:57,710 --> 00:18:58,810
+البنزويل؟
+
+207
+00:19:01,040 --> 00:19:05,660
+هذه المجموعة ماذا اسمها؟ Benzoyl طب لو قلنا لكم بدنا 
+
+208
+00:19:05,660 --> 00:19:10,600
+بنزيل كلوريد بنزيل
+
+209
+00:19:10,600 --> 00:19:18,160
+كلوريد مجموعة البنزيل هي عبارة عن الفنل
+
+210
+00:19:28,890 --> 00:19:38,950
+بنزيل وبنزويل بنزيل بنزيل بنزيل بنزويل بنزيل 
+
+211
+00:19:38,950 --> 00:19:42,410
+الكلورايد غير البنزيل الكلورايد يعني لو في
+
+212
+00:19:42,410 --> 00:19:46,110
+المختبر اشتغلتم وعندكم في مكان العمل تجربة هات
+
+213
+00:19:46,110 --> 00:19:49,290
+اثنين جرام بنزيل كلوريد تروح الواحدة على
+
+214
+00:19:49,290 --> 00:19:52,850
+المختبر بدون انتباه اجيب بنزيل كلوريد هذا مركب
+
+215
+00:19:52,850 --> 00:19:57,810
+وهذا مركب هذا كيمياء وهذا كيمياء مختلفة تمامًا
+
+216
+00:19:57,810 --> 00:20:03,750
+بنزيل كلوريد أشهر وبنزيل كلوريد أشهر ثانيًا
+
+217
+00:20:03,750 --> 00:20:09,200
+تمامًا واضح فاختبر التوضيح
+
+218
+00:20:15,000 --> 00:20:21,900
+أهم شيء في الـ benzoyl chlorides كخواص أو الـ acid 
+
+219
+00:20:21,900 --> 00:20:27,720
+chlorides بشكل عام اللي هي نوكليوفيلية يعني بتتحرك و
+
+220
+00:20:27,720 --> 00:20:33,760
+لأن الجزء الكبير منها يستخدم كـ tear gases كغازات
+
+221
+00:20:33,760 --> 00:20:40,960
+مصيلة للدموع يعني الـ benzoyl chloride نفسه الذي تو
+
+222
+00:20:40,960 --> 00:20:44,660
+كتبناه هذا يستخدم كغاز مصيل
+
+223
+00:20:50,930 --> 00:20:56,130
+الآن كيف يعمل هذا يعني القاعدية التي يعمل فيها
+
+224
+00:20:56,130 --> 00:21:01,510
+كغاز مثيل للدموع؟ يأتي على المناطق في الجسم التي 
+
+225
+00:21:01,510 --> 00:21:06,980
+فيها ماء بناء على ذلك لو أحد كنا مسكرين رأسه وجاء
+
+226
+00:21:06,980 --> 00:21:10,360
+غاز المسيل للدموع على رجله أو على يده بدون ماء
+
+227
+00:21:10,360 --> 00:21:16,520
+ما فيه مشكلة أين تأثيره؟ على العينين والمنخر
+
+228
+00:21:16,520 --> 00:21:24,140
+والزجاج إذا هو بتفاعل مع الماء طب بتفاعل مع الماء 
+
+229
+00:21:24,140 --> 00:21:28,180
+ماذا بده يعمل؟ مرتين بده يعمل Substitution أن الماء
+
+230
+00:21:28,180 --> 00:21:34,550
+تُهاجم هنا وتُطرد الـ Cl بناء على ذلك الذي سيحصل
+
+231
+00:21:34,550 --> 00:21:41,750
+عندي هذا سيعود إلى C double bond O OH للحمض دل من
+
+232
+00:21:41,750 --> 00:21:50,470
+هنا عندي H ومن هنا Cl زائد HCl هذا 
+
+233
+00:21:50,470 --> 00:21:54,090
+الـ HCl الذي يخرج من تفاعل البنزويل كلوريد مع
+
+234
+00:21:54,090 --> 00:21:56,710
+الماء هو الذي يسبب الحرقة هو الحمض المعروف
+
+235
+00:21:56,710 --> 00:22:02,270
+بالنسبة لكم ملاحظين؟ إذا هم بدل ما يرشوا الإنسان
+
+236
+00:22:02,270 --> 00:22:07,410
+بـHCL يروحون يرشونه بنزويل كلوريد، يتفاعل مع ماء
+
+237
+00:22:07,410 --> 00:22:11,930
+العين أو الفم، يعطي بنزويك أسد، هذا حمض ضعيف،
+
+238
+00:22:11,930 --> 00:22:15,650
+خليني أقول بنزويك أسد، لكن يعطي أيضًا HCL هو الذي
+
+239
+00:22:15,650 --> 00:22:20,190
+يسبب المشاكل، واضح؟  لأن هيك، لو كنتم تسألون 
+
+240
+00:22:20,190 --> 00:22:23,290
+الناس الذين أكثر منكم عاشوا الغازات المثيلة 
+
+241
+00:22:23,290 --> 00:22:29,150
+للدموع، كانت الإشكالية فيها أين؟ أن الإنسان يتعرض
+
+242
+00:22:29,150 --> 00:22:33,670
+للغاز، انتهى، انتهينا من العينين وإشي، لابس نص كم و
+
+243
+00:22:33,670 --> 00:22:37,390
+وجهه، كله يكون ملطخ عليه الـ Benzoyl chloride،
+
+244
+00:22:37,390 --> 00:22:41,530
+لكن ليس متأثر، بس إذا راح يتوضأ أو غسل شوية صغيرة 
+
+245
+00:22:41,530 --> 00:22:45,490
+بماء أو نزل عليه ماء، سيحدث التفاعل وسيحدث
+
+246
+00:22:45,490 --> 00:22:51,970
+جلده يحرقه، فكانت المشكلة أن الواحد يتوضأ بعد
+
+247
+00:22:51,970 --> 00:22:58,590
+مظاهرة لازم ماذا يعمل الإنسان؟ يغسل نفسه بصابون و
+
+248
+00:22:58,590 --> 00:23:03,190
+بماء كبير وبشكر هكذا مع صابون ومياه كبيرة بحيث 
+
+249
+00:23:03,190 --> 00:23:07,190
+ينتهي كل هذا أما وضوء عادي بماء خفيف أو الماء
+
+250
+00:23:07,190 --> 00:23:12,750
+ينزل على الجسم الذي عليه بنزويل كلوريد وجد الإنسان
+
+251
+00:23:12,750 --> 00:23:21,870
+يصبح في ماذا؟ في الحرق والله يعفيكم الشر إن شاء الله إذا
+
+252
+00:23:21,870 --> 00:23:25,850
+تلاحظون هنا أن الـ acid chlorides they react
+
+253
+00:23:25,850 --> 00:23:29,630
+violently with water يعني يتفاعلون مع الماء بشكل
+
+254
+00:23:29,630 --> 00:23:37,390
+كبير جداً لما يتفاعلون مع الماء ماذا يعطون؟ الحمض 
+
+255
+00:23:37,390 --> 00:23:47,810
+الكربوكسيلي زائد HCl وHCl هو سبب المشاكل بالمجمّل الـ
+
+256
+00:23:47,810 --> 00:23:51,570
+acid chloride هي من مشتقات الأحماض لأن تتفاعلها مع
+
+257
+00:23:51,570 --> 00:23:56,150
+أي نيوكليوفيل هو بمثابة يعني هنا تلخيص للكلام الذي 
+
+258
+00:23:56,150 --> 00:24:01,310
+حكينا لو بدأ يتفاعل مع الماء بدأ تهاجم وتُطرد الـ
+
+259
+00:24:01,310 --> 00:24:06,130
+CL لو بدأ يتفاعل مع الايثانول بدأ تهاجم وتُطرد الـ
+
+260
+00:24:06,130 --> 00:24:10,310
+CL لو بدأ تتفاعل مع الأمونيا بدأ تهاجم وتُطرد الـ
+
+261
+00:24:10,310 --> 00:24:13,450
+CL بناءً على ذلك الـ acid chloride مع الماء ماذا 
+
+262
+00:24:13,450 --> 00:24:19,780
+يعطيني؟ الحمض الذي حكينا عنه الحمض كلوريد مع
+
+263
+00:24:19,780 --> 00:24:26,540
+الايثانول سيضع بدل الـ CL OR أو O Ethan في هذه الحالة
+
+264
+00:24:26,540 --> 00:24:32,440
+إذا كنا مُحددينها يعطينا الـ T star والتفاعل مع
+
+265
+00:24:32,440 --> 00:24:38,000
+الأمونيا الاميد إذا الحمض كلوريد مع الماء يعطينا
+
+266
+00:24:38,000 --> 00:24:42,140
+حمض الحمض كلوريد مع الـ alcohol T star الحمض 
+
+267
+00:24:42,140 --> 00:24:46,720
+كلوريد مع الأمونيا حمض، لاحظوا أنه إحنا كإينا 
+
+268
+00:24:46,720 --> 00:24:51,770
+ندور بسلسلة مُفرّقة واضح؟ يعني لو رجعت أخذت الـ E
+
+269
+00:24:51,770 --> 00:24:58,610
+star نفرض مع BCL3  سيُرضي يعطينا ماذا؟ حمض كلوريد أو 
+
+270
+00:24:58,610 --> 00:25:03,870
+أخذت الحمض مثلًا مع الـ ..  زي ما شفنا قبل شوية مع
+
+271
+00:25:03,870 --> 00:25:10,090
+الـ BCL3 سيُرضي يعطينا ماذا؟ حمض كلوريد فكأنه يعني في 
+
+272
+00:25:10,090 --> 00:25:13,430
+كل هذا الـ chapter عمال بنلف حوالين فكرة واحدة هي
+
+273
+00:25:13,430 --> 00:25:23,630
+فكرة ماذا؟ كلمة واحدة Substitution هي فكرة الـ
+
+274
+00:25:23,630 --> 00:25:32,250
+Substitution طيب 
+
+275
+00:25:32,250 --> 00:25:37,430
+لو قلنا بدنا الحمض كلوريد تفاعل مع Green Yard 
+
+276
+00:25:37,430 --> 00:25:38,230
+reagent
+
+277
+00:25:43,960 --> 00:25:48,580
+مثل الـ E star بالضبط موجودة في الـ slide عندكم مثل الـ 
+
+278
+00:25:48,580 --> 00:25:54,160
+E star بالضبط أن الـ green yard بده يتفاعل عنده على 
+
+279
+00:25:54,160 --> 00:26:00,700
+مرتين الـ green yard مصدر للـ R مع إلكتروناته بناءً
+
+280
+00:26:00,700 --> 00:26:04,800
+على ذلك الـ R بده تهاجم والـ CL بده تطلع في مرحلته
+
+281
+00:26:04,800 --> 00:26:12,420
+الأولى ماذا يعطيني؟ كيتون بعد ذلك الـ R تهاجم مرة 
+
+282
+00:26:12,420 --> 00:26:18,540
+ثانية على الكيتون وتعمل إضافة في مرحلته التالية 
+
+283
+00:26:18,540 --> 00:26:21,360
+يعطي الـ tertiary alcohol سيبكم الأشياء التي في
+
+284
+00:26:21,360 --> 00:26:26,540
+النص التوضيحية إذا مثل ما الـ Easter بتتفاعل مع
+
+285
+00:26:26,540 --> 00:26:30,080
+Greenyard على مرتين يعطي في الأول كيتون وبعدين 
+
+286
+00:26:30,080 --> 00:26:33,960
+tertiary alcohol الحمض كلوريد بتفاعل بنفس
+
+287
+00:26:33,960 --> 00:26:40,700
+الطريقة على مرتين يعطي في الأول كيتون وبعدين الفرق
+
+288
+00:26:40,700 --> 00:26:43,660
+بين الـ Easter والـ Acid Chloride أنه في حالة الـ
+
+289
+00:26:43,660 --> 00:26:46,840
+Easter كانت تفقد OR في حالة الـ Acid Chloride تفقد
+
+290
+00:26:46,840 --> 00:26:54,880
+CL مع ذلك نفس النتيجة إذا نحن نقدر نقول تفاعل الـ
+
+291
+00:26:54,880 --> 00:26:59,360
+Acid Chloride مع excess green yard reagent
+
+292
+00:26:59,360 --> 00:27:04,800
+produces finally Tertiary Alcohol والتفاعل 
+
+293
+00:27:04,800 --> 00:27:09,320
+يمر عبر تكوين الكيتون تكوين الكيتون هو تفاعل 
+
+294
+00:27:09,320 --> 00:27:13,220
+إبدال تكوين الـ alcohol من الكيتون هو تفاعل 
+
+295
+00:27:13,220 --> 00:27:19,180
+addition أو إضافة إذا هذا التفاعل موازي تمامًا
+
+296
+00:27:19,180 --> 00:27:22,420
+لتفاعل الـ Easter eggs
+
+297
+00:27:31,100 --> 00:27:38,970
+مشتقة جديدة من مشتقات الأحماض الحمض Anhydrates 
+
+298
+00:27:38,970 --> 00:27:44,150
+الحمض Anhydrates الحمض Anhydrates نحصل عليها من 
+
+299
+00:27:44,150 --> 00:27:49,970
+خلال أن نفعل جزيئين من الحمض جزيئين من الحمض مع 
+
+300
+00:27:49,970 --> 00:27:54,870
+بعضهما البعض واضح؟ واحد منهم يعمل كمستقبل وواحد 
+
+301
+00:27:54,870 --> 00:27:59,190
+منهم يعمل كأنه النيوكليوفيل بناءً على ذلك هذا الذي
+
+302
+00:27:59,190 --> 00:28:03,490
+أنتم شايفينه مثلًا جزيء واحد من الحمض تخيلوا أنه
+
+303
+00:28:03,490 --> 00:28:11,570
+يتفاعل مع نفسه واضح؟ إذا أنا أفاعل جزيئين من الحمض
+
+304
+00:28:11,570 --> 00:28:16,050
+مع بعض أسخن الحمض طبعًا أنا أجيب الجزئية أجيب كمية
+
+305
+00:28:16,050 --> 00:28:22,210
+حمض أسخنها في وجود H plus إضافة من الخارج شوية
+
+306
+00:28:22,210 --> 00:28:26,450
+الآن التفاعل الذي بده يتم هو تفاعل مرة ثانية إبدال 
+
+307
+00:28:26,450 --> 00:28:34,750
+أن واحد من الحمض بيجي يهاجم هنا ويُطرد الـ OH يعني 
+
+308
+00:28:34,750 --> 00:28:39,190
+كإن واحد يعمل كـ Nucleophile والثاني يعمل كـ
+
+309
+00:28:39,190 --> 00:28:43,290
+Electrophile أو مستقبل لما يُطرد الـ OH سيصبح عند 
+
+310
+00:28:43,290 --> 00:28:50,020
+هذا الجزء الأولاني CH3CW.O ومن الحمض التالي بيجيني
+
+311
+00:28:50,020 --> 00:28:56,580
+OCH3 هذا الشكل أو هذه المجموعة هي مجموعة الـ
+
+312
+00:28:56,580 --> 00:29:00,960
+Anhydrate لماذا نقول Anhydrate لأن لما طردت
+
+313
+00:29:00,960 --> 00:29:07,940
+هذه الـ OH مع الـ H الذي من هنا، ماذا أعطوني؟ ماء فكأنه
+
+314
+00:29:07,940 --> 00:29:13,120
+أنا في تفاعل الـ Anhydrate خلطت جزيئين حمض مع بعض 
+
+315
+00:29:13,120 --> 00:29:19,160
+شبكتهم في بعض وخرجت برة ماء فمعنى Anhydrate أن هذا 
+
+316
+00:29:19,160 --> 00:29:25,110
+مخصوم منه ماء مخصوم منه ماء الصيغة العامة في شكل 
+
+317
+00:29:25,110 --> 00:29:31,030
+عام للـ Anhydrate للـ Anhydrate C double bond O أو C
+
+318
+00:29:31,030 --> 00:29:35,450
+double bond O يعني لما أريد أخرج كمجموعة وظيفية
+
+319
+00:29:35,450 --> 00:29:39,930
+أجلب لكم مركب في C double bond O أو C double bond O
+
+320
+00:29:39,930 --> 00:29:45,790
+أقول لكم ما عائلة هذا المركب Anhydrate واضح
+
+321
+00:29:45,790 --> 00:29:50,510
+فالمجموعة الوظيفية تبع الـ Anhydride C double bond O
+
+322
+00:29:50,510 --> 00:29:57,390
+O C double bond O الآن يبقى على الأطراف الـ R التي
+
+323
+00:29:57,390 --> 00:30:03,330
+جاءت من الحمض في هذه الحالة ستلاحظون أن 
+
+324
+00:30:03,330 --> 00:30:09,270
+الكيميائيين عندهم طرق فنية ممكن يخلون الحمض يتفاعل 
+
+325
+00:30:09,270 --> 00:30:13,690
+مع نفسه إذا الحمض تفاعل مع نفسه ستكون مجموعتي الـ
+
+326
+00:30:13,690 --> 00:30:19,320
+R هذول زي بعض نفسهم يصبح عندي symmetrical 
+
+327
+00:30:19,320 --> 00:30:23,980
+Anhydride يعني Anhydride ماذا به متماثل إذا كان
+
+328
+00:30:23,980 --> 00:30:28,760
+هذا اسم الحمض acetic acid الـ Anhydride الذي منه
+
+329
+00:30:28,760 --> 00:30:37,780
+ماذا يكون اسمه؟ acetic Anhydride طبعًا هو كاتبه بصيغة
+
+330
+00:30:37,780 --> 00:30:41,900
+ethanoic acid ethanoic Anhydride نفس الفكرة بس 
+
+331
+00:30:41,900 --> 00:30:49,970
+الأشهر أن هذا الحمض حمض ماذا اسمه؟ Acetic Acid 
+
+332
+00:30:49,970 --> 00:30:55,530
+والـ Anhydride الذي ينشأ منه Acetic Anhydride الآن 
+
+333
+00:30:55,530 --> 00:31:00,310
+الـ Acetic Anhydride is a symmetrical Anhydride ماذا 
+
+334
+00:31:00,310 --> 00:31:04,550
+يعني symmetrical Anhydride؟ متماثل يعني مجموعتي الـ
+
+335
+00:31:04,550 --> 00:31:12,530
+R التي موجودة عليه نفس الشيء مجموعتي الـ R التي 
+
+336
+00:31:12,530 --> 00:31:16,650
+موجودة عليه نفس الشيء فتسميته سهلة نأخذ اسم 
+
+337
+00:31:16,650 --> 00:31:23,370
+الحمض acidic بس بدل كلمة acid نستبدل كلمة acid
+
+338
+00:31:23,370 --> 00:31:29,070
+بكلمة Anhydride هذا في حالة ما أُحكي عن Anhydride
+
+339
+00:31:29,070 --> 00:31:37,630
+متماثل بشيل كلمة acid وبحط مكانها Anhydride
+
+340
+00:31:50,350 --> 00:31:55,330
+لاحظوا أنه في التفاعل السابق كان عندي جزيئين حمض
+
+341
+00:31:55,330 --> 00:31:58,510
+مُنفصلين عن بعض، لأن ذلك التفاعل نسميه
+
+342
+00:31:58,510 --> 00:32:02,750
+Intermolecular أو Intramolecular؟ Intermolecular،
+
+343
+00:32:02,750 --> 00:32:05,930
+بين جزيئين مختلفين، يعني هذه حمض وهذه حمض،
+
+344
+00:32:05,930 --> 00:32:13,250
+وتفاعلوا مع بعض وفقدوا الآن ممكن يكون عندي حمض أو
+
+345
+00:32:13,250 --> 00:32:18,430
+مركب فيه جزيئين الحمض مع بعض ومر عليّ أمثلة مثلًا 
+
+346
+00:32:18,430 --> 00:32:22,070
+هذا المركب الذي فيه ذرة الكربون 1 2
+
+347
+00:32:22,070 --> 00:32:28,210
+3 4 مر عليّ الحمض ماذا اسمه؟ malic أسد بناءً 
+
+348
+00:32:28,210 --> 00:32:32,970
+على ذلك هذا malic أسد لو سخنته 135 درجة ماء هذه
+
+349
+00:32:32,970 --> 00:32:37,730
+تتفاعل هنا وتُطرد الـ OH طبعًا الـ OH مع الـ H التي 
+
+350
+00:32:37,730 --> 00:32:42,350
+هنا سيكون لها ماء بتكون هذا المركب ماذا اسم هذا
+
+351
+00:32:42,350 --> 00:32:48,670
+المركب؟ malic Anhydride إذا malic أسد الذي هو 
+
+352
+00:32:48,670 --> 00:32:53,510
+عبارة عن داى أسد تفاعل مع بعضه يعطيني malic Anhydride 
+
+353
+00:32:53,510 --> 00:32:56,710
+هذا الـ reaction الآن Intermolecular أو
+
+354
+00:32:58,580 --> 00:33:02,440
+Intramolecular يعني جوه الجزئية الشغلتين المتفاعلات
+
+355
+00:33:02,440 --> 00:33:08,200
+Intramolecular reaction واضح؟ وشبيه تمامًا في ..
+
+356
+00:33:08,200 --> 00:33:11,660
+شبيه تمامًا في هذا الحمض الذي هو البنزين الذي عليه
+
+357
+00:33:11,660 --> 00:33:15,760
+مجموعتين حمض جنب بعض أخذنا اسمه .. من تذكر 
+
+358
+00:33:15,760 --> 00:33:19,740
+اسمه؟
+
+359
+00:33:19,740 --> 00:33:24,680
+من تذكر؟ Phthalic Anhydride 
+
+360
+00:33:27,800 --> 00:33:32,080
+الآن ارجعوا على البنزين فتاليك أسد ارجعوا على
+
+361
+00:33:32,080 --> 00:33:35,140
+البنزين بتلاقوا أخذنا الحمض إذا المجموعتين جنب
+
+362
+00:33:35,140 --> 00:33:40,380
+بعض اسمه فتاليك أسد وإذا بِنَظر على الميتا 
+
+363
+00:33:40,380 --> 00:33:44,900
+ايزوفتاليك أسد وإذا على البارا تيرفتاليك أسد نحن 
+
+364
+00:33:44,900 --> 00:33:49,640
+قلنا أقل تقدير لازم تحفظوا شكل الفتاليك أسد الآن
+
+365
+00:33:49,640 --> 00:33:53,060
+لو قلنا لكم في الامتحان ورسمنا فتاليك انهايدريد
+
+366
+00:33:53,060 --> 00:34:00,150
+كيف سترسمونه؟ سيأتي لكم سؤال ارسم أفثاليك أنهيدريد 
+
+367
+00:34:00,150 --> 00:34:06,250
+واحدة من هذول بده تهاجم على الـ CW Bond O وتُطرد 
+
+368
+00:34:06,250 --> 00:34:14,450
+الـ OH بناءً على ذلك سيكون شبيه جداً 
+
+369
+00:34:14,450 --> 00:34:16,890
+في المركب الذي فوق CW Bond O
+
+370
+00:34:19,460 --> 00:34:24,460
+هو high-lithalic anhydride، إذن، Lithalic acid
+
+371
+00:34:24,460 --> 00:34:27,440
+
+401
+00:36:50,720 --> 00:36:58,290
+وحيد إنها تاجم هنا و تطلط الـ CL تحضير الـ Mixed
+
+402
+00:36:58,290 --> 00:37:02,750
+Anhydride من خلال تفاعل الـ Acid Chloride مع
+
+403
+00:37:02,750 --> 00:37:08,350
+الكربوكسيلات أنيون هذا ليس اسمه كربوكسيلات أنيون
+
+404
+00:37:08,350 --> 00:37:13,390
+يعني هذا الصوديوم إيش بنسميها؟ أسيتات خلّات 
+
+405
+00:37:13,390 --> 00:37:17,390
+الصوديوم صوديوم أسيتات من أين جايبنا من الأسيتك
+
+406
+00:37:17,390 --> 00:37:20,490
+أسد مع الصوديوم هيدروكسيد يعطينا صوديوم أسيتات
+
+407
+00:37:20,490 --> 00:37:27,150
+تحضير الـ Mixed Anhydride من خلال تفاعل أسد كلوريد
+
+408
+00:37:27,150 --> 00:37:34,950
+بنفعل E star بنفعل E star لأن أنا سواء طردت CL ولا
+
+409
+00:37:34,950 --> 00:37:43,470
+طردت OR مفرد 100 أنتِ مع الكربوكسيلات أنيون اللي
+
+410
+00:37:43,470 --> 00:37:49,630
+هو الأيون السالب الأيون السالب للحمد في هذه الحالة
+
+411
+00:37:49,630 --> 00:37:50,710
+بنقول بنفعل
+
+412
+00:37:53,630 --> 00:37:57,470
+اللي هو الـ butanoic acid اللي هو الـ butanoic
+
+413
+00:37:57,470 --> 00:38:03,550
+كلوريد .. ال butanoil كلوريد مع مثلا ال sodium
+
+414
+00:38:03,550 --> 00:38:07,810
+acetate هذا بيعمل ال nucleophile وهذا بيعمل ال
+
+415
+00:38:07,810 --> 00:38:13,210
+substitution بيطلع عنده ال unsymmetrical anhydride
+
+416
+00:38:13,210 --> 00:38:18,950
+أو مجرد بيسموه إيش mixed anhydride يعني مش جاي من
+
+417
+00:38:18,950 --> 00:38:23,920
+نفس النوع، هاي هذا أزرق و أزرق، هذا Symmetrical لكن
+
+418
+00:38:23,920 --> 00:38:29,660
+لما نعمل زي هيك mixed anhydride واضح فالمixed
+
+419
+00:38:29,660 --> 00:38:35,700
+anhydride ما أقدرش أحضره أنه أخد الحمضين و أسخنهم في
+
+420
+00:38:35,700 --> 00:38:42,420
+وجود H plus و إلا بيطلع عندي كم ناتج زي الـ
+
+421
+00:38:42,420 --> 00:38:45,840
+unsymmetrical ether، لو أخذتي الكحولين و سخنتيهم مع
+
+422
+00:38:45,840 --> 00:38:49,880
+بعض، كم نتيجة كانت بتطلع عندك؟ تلاتة، بتلاحظوا أن
+
+423
+00:38:49,880 --> 00:38:53,300
+الأفكار في ال organic chemistry نوعا ما بتصير،
+
+424
+00:38:53,300 --> 00:38:57,920
+بتتكرر بعض، بس المهم نتذكرها
+
+425
+00:39:08,420 --> 00:39:13,040
+طبعا لو كنا بدنا نسمي .. لو كنا بدنا نسمي ال mixed
+
+426
+00:39:13,040 --> 00:39:19,140
+anhydride إحنا سمينا ال symmetrical مثلا هذا جاي
+
+427
+00:39:19,140 --> 00:39:22,960
+من ال benzoic acid هاي ال anhydride group جاي من
+
+428
+00:39:22,960 --> 00:39:27,940
+benzoic acid شو بنسميه؟ Benzoic anhydride هذا جاي
+
+429
+00:39:28,810 --> 00:39:35,530
+كربون 1 2 3 من البروبانويك أسد بروبانويك
+
+430
+00:39:35,530 --> 00:39:38,290
+أنهيدريد هذا الـ symmetrical أخذنا طب لما يكون
+
+431
+00:39:38,290 --> 00:39:47,170
+unsymmetrical بصير عندي غير أنهيدريد مجموعتين
+
+432
+00:39:48,640 --> 00:39:52,740
+بهذه الحالة بدي أذكر المجموعتين أو الحمضين اللي
+
+433
+00:39:52,740 --> 00:39:59,160
+اتكون منهم هذا الحمض شو أصله؟ CH3C أسيتيك وهذا
+
+434
+00:39:59,160 --> 00:40:04,520
+الحمض C double bond O بنزويك فكله بنقول أسيتيك
+
+435
+00:40:04,520 --> 00:40:09,480
+بنزويك أنهيدريد أنه هو الأنهايدريد اللي جاي من
+
+436
+00:40:09,480 --> 00:40:14,660
+الأسيتيك أسد و البنزويك أسد و بنذكرهم alphabetical
+
+437
+00:40:14,660 --> 00:40:21,730
+يعني A قبل ال B acetic benzoic anhydride إذا بنذكر
+
+438
+00:40:21,730 --> 00:40:25,910
+في حالة ما يكون متماثل اسم الحمض مرة واحدة طب غير
+
+439
+00:40:25,910 --> 00:40:32,150
+متماثل بنذكر الحمضين alphabetical فإذا كان مكون
+
+440
+00:40:32,150 --> 00:40:36,370
+من ال acetic acid مع ال benzoic acid بيكون acetic
+
+441
+00:40:36,370 --> 00:40:39,950
+benzoic anhydride الآن لو قلت لكم هذا كيف نحطه
+
+442
+00:40:39,950 --> 00:40:43,930
+يعني جبناه في الامتحان وقلنا لكم how can you
+
+443
+00:40:43,930 --> 00:40:47,030
+prepare this compound شو هتعمله؟
+
+444
+00:40:49,660 --> 00:40:58,580
+واحد منهم هتاخده على شكل كلوريد والتاني على شكل
+
+445
+00:40:58,580 --> 00:41:07,100
+أيون سالب مش قولنا كلوريد مع أيون سالب واعدي
+
+446
+00:41:07,100 --> 00:41:11,580
+كلوريد والتاني أيون سالب هذه بتهاجم هنا وبتطرد
+
+447
+00:41:14,410 --> 00:41:18,870
+كلوريد زائد أيون كلوريد زائد أيون بيعطينا
+
+448
+00:41:18,870 --> 00:41:28,290
+ال mix anhydride عشان
+
+449
+00:41:28,290 --> 00:41:32,010
+بس نقف عند ال amides المرعن هادر هي تفاعل ال
+
+450
+00:41:32,010 --> 00:41:40,430
+anhydride هتلاحظوا شغل إن تفاعل ال anhydride موازي
+
+451
+00:41:41,910 --> 00:41:45,490
+للتفاعلات السابقة، تفاعل الـ anhydride موازي
+
+452
+00:41:45,490 --> 00:41:50,030
+للتفاعلات السابقة، يعني ممكن أفعل مع الميه، مع
+
+453
+00:41:50,030 --> 00:41:53,110
+الكحول، مع الأمونيا، في كل الأحوال، شو التفاعل
+
+454
+00:41:53,110 --> 00:41:56,710
+اللي بيعمل إياه؟ Substitution، يعني كأني بجيب هذه،
+
+455
+00:41:56,710 --> 00:42:01,470
+تهاجم هنا، و بتطرد هذه أو بجيب ال R هذي تاجم هنا
+
+456
+00:42:01,470 --> 00:42:05,410
+و بطرد هذي أو بجيب ال ammonia تاجم هنا و بطرد كل
+
+457
+00:42:05,410 --> 00:42:12,590
+المجموعة اللي هي OCH3 بناء عدلك ال anhydride مع
+
+458
+00:42:12,590 --> 00:42:17,010
+الميه برجع acid مع ال alcohol بصير ester مع ال
+
+459
+00:42:17,010 --> 00:42:22,850
+ammonia بصير amide لاعظم التفاعلات بشكل كبير
+
+460
+00:42:22,850 --> 00:42:31,740
+متوازية آخر تفاعل اللي بنحكيه اللي هو تفاعل تحضير
+
+461
+00:42:31,740 --> 00:42:36,840
+الأسبرين وربما مر معكم في المعمل أنتم أخذتوها 
+
+462
+00:42:36,840 --> 00:42:41,320
+معمل الأسبرين بيحضروه من خلال تفاعل الأسيتك
+
+463
+00:42:41,320 --> 00:42:45,580
+أنهيدريد مع هذا الحمض اللي اسمه salicylic acid
+
+464
+00:42:45,580 --> 00:42:50,000
+بالمحصلة هذا الحمض يمثل ال nucleophile هذا ال
+
+465
+00:42:50,000 --> 00:42:56,190
+nucleophile بيجي يهاجم هنا ويطرد هذه المجموعة فبصير
+
+466
+00:42:56,190 --> 00:43:02,250
+عند ال salicylic acid C double bond O CH3 فبنسمي
+
+467
+00:43:02,250 --> 00:43:09,790
+الأسبرين أسيتو ساليسيليك أسيتو ساليسيليك
+
+468
+00:43:09,790 --> 00:43:14,730
+أسيتو ساليسيليك أسيتو ساليسيليك
+
+469
+00:43:14,730 --> 00:43:18,510
+ساليسيليك أسيتو ساليسيليك أسيتو أسيتو أسيتو أسيتو
+
+470
+00:43:18,510 --> 00:43:18,670
+أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو
+
+471
+00:43:18,670 --> 00:43:18,730
+أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو
+
+472
+00:43:18,730 --> 00:43:19,840
+أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتشبيهة
+
+473
+00:43:19,840 --> 00:43:25,220
+بكلمة الصفصاف هذا ال salicylic acid بيطلعوا من شجر
+
+474
+00:43:25,220 --> 00:43:30,600
+الصفصاف وهو اللي بيستخدم كدواء ضد الصداع لكن بيكون
+
+475
+00:43:30,600 --> 00:43:35,860
+بيشعّط المعدة أو بيحرق المعدة فعشان يحسنوا خواصه
+
+476
+00:43:35,860 --> 00:43:39,280
+بفعلوه مع ال acidic anhydride بدل ما ياخذوا
+
+477
+00:43:39,280 --> 00:43:45,520
+salicylic acid مباشرة بياخذوه على شكل أسيتو
+
+478
+00:43:45,520 --> 00:43:48,940
+ساليسيليك أسد يدخل على الأمعاء و يبقى أسيتو
+
+479
+00:43:48,940 --> 00:43:52,440
+ساليسيليك أسد أو على المعدة أول من ينزل على
+
+480
+00:43:52,440 --> 00:43:56,780
+الأمعاء في وسط قلوي بيرجع بيرجع ل ساليسيليك أسد و
+
+481
+00:43:56,780 --> 00:44:01,300
+الساليسيليك أسد هو اللي بعالج الصداع واضح؟ إذا أنا
+
+482
+00:44:01,300 --> 00:44:06,580
+كأني حولت الساليسيليك أسد لأسبرين ليش؟ لأن
+
+483
+00:44:06,580 --> 00:44:10,500
+الساليسيليك أسد بيحرق المعدة بناء على ذلك بحاوله
+
+484
+00:44:10,500 --> 00:44:15,520
+لإيش؟ لأسبرين أخذت الأسبرين بنزل على المعدة بيضل
+
+485
+00:44:15,520 --> 00:44:20,980
+أسبرين بيروح على المعاق بيرجع ساليسيليك أسد و
+
+486
+00:44:20,980 --> 00:44:26,620
+الساليسيليك أسد اللي بعالج الصداع واضح فلاحظوا بس
+
+487
+00:44:26,620 --> 00:44:30,820
+لأن المرور في المعدة حساس بنشعه يحرج المعدة بنحول
+
+488
+00:44:30,820 --> 00:44:34,720
+الساليسيليك أسد إلى أسبرين أو أسيتو ساليسيليك أسد
+
+489
+00:44:34,720 --> 00:44:40,680
+في الأمعاء بيرجع بيصير برجع بيصير salicylic acid
+
+490
+00:44:40,680 --> 00:44:46,420
+بهيك بنقف إحنا عند ال amides ماشي؟ 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..531f9bec264b1490de0eff80170a770065225328
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3178, "start": 9.0, "end": 31.78, "text": "بنبدأ اليوم بالفصل التاسع، العنوان هو الـ aldehydes والكيتوز الان الفصل التاسع و الفصل العاشر بيتكلم عن المركبات اللي فيها رابطة C double bond O هذه المجموعة الـ C double bond O في أي مكان كانت", "tokens": [3555, 1863, 44510, 10721, 45595, 20498, 20666, 5172, 36520, 16712, 32277, 3615, 12399, 18863, 1863, 2407, 7649, 31439, 2423, 39184, 16798, 68, 3495, 14792, 16070, 4117, 36081, 2407, 11622, 2423, 7649, 27188, 36520, 16712, 32277, 3615, 4032, 27188, 36520, 18863, 33599, 2288, 4724, 36081, 4117, 19528, 18871, 9673, 31747, 3555, 9307, 13672, 1829, 8978, 11296, 12602, 16758, 9566, 3660, 383, 3834, 6086, 422, 29538, 9673, 7435, 2304, 2407, 27884, 2423, 39184, 383, 3834, 6086, 422, 8978, 36632, 3714, 41361, 25961, 2655], "avg_logprob": -0.2412347631846986, "compression_ratio": 1.6649214659685865, "no_speech_prob": 6.556510925292969e-07, "words": [{"start": 9.0, "end": 9.96, "word": "بنبدأ", "probability": 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{"start": 16.98, "end": 17.42, "word": " الفصل", "probability": 0.88134765625}, {"start": 17.42, "end": 18.24, "word": " العاشر", "probability": 0.9296875}, {"start": 18.24, "end": 19.48, "word": " بيتكلم", "probability": 0.9439697265625}, {"start": 19.48, "end": 19.76, "word": " عن", "probability": 0.955078125}, {"start": 19.76, "end": 20.94, "word": " المركبات", "probability": 0.8768310546875}, {"start": 20.94, "end": 21.36, "word": " اللي", "probability": 0.813720703125}, {"start": 21.36, "end": 21.96, "word": " فيها", "probability": 0.973876953125}, {"start": 21.96, "end": 23.84, "word": " رابطة", "probability": 0.92626953125}, {"start": 23.84, "end": 24.08, "word": " C", "probability": 0.328857421875}, {"start": 24.08, "end": 24.32, "word": " double", "probability": 0.37890625}, {"start": 24.32, "end": 24.86, "word": " bond", "probability": 0.91650390625}, {"start": 24.86, "end": 25.58, "word": " O", "probability": 0.9033203125}, {"start": 25.58, "end": 26.78, "word": " هذه", "probability": 0.44482421875}, {"start": 26.78, "end": 28.1, "word": " المجموعة", "probability": 0.96787109375}, {"start": 28.1, "end": 28.64, "word": " الـ", "probability": 0.4688720703125}, {"start": 28.64, "end": 28.74, "word": " C", "probability": 0.6640625}, {"start": 28.74, "end": 28.94, "word": " double", "probability": 0.9228515625}, {"start": 28.94, "end": 29.3, "word": " bond", "probability": 0.966796875}, {"start": 29.3, "end": 29.7, "word": " O", "probability": 0.974609375}, {"start": 29.7, "end": 30.38, "word": " في", "probability": 0.92919921875}, {"start": 30.38, "end": 30.66, "word": " أي", "probability": 0.87060546875}, {"start": 30.66, "end": 31.06, "word": " مكان", "probability": 0.99462890625}, {"start": 31.06, "end": 31.78, "word": " كانت", "probability": 0.993896484375}], "temperature": 1.0}, {"id": 2, "seek": 4391, "start": 32.21, "end": 43.91, "text": "بسموها الـ carbonyl group يعني المجموعة نفسها الـ C double bond O لحالها بيقولوا عنها ال carbonyl group الآن المركبات اللي فيهم", "tokens": [3555, 38251, 2407, 11296, 2423, 39184, 12143, 2526, 75, 1594, 37495, 22653, 9673, 7435, 2304, 2407, 27884, 8717, 36178, 11296, 2423, 39184, 383, 3834, 6086, 422, 5296, 5016, 6027, 11296, 4724, 1829, 39648, 14407, 18871, 11296, 2423, 12143, 2526, 75, 1594, 6024, 48506, 9673, 31747, 3555, 9307, 13672, 1829, 8978, 16095], "avg_logprob": -0.3191105889586302, "compression_ratio": 1.3928571428571428, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 32.21, "end": 33.03, "word": "بسموها", "probability": 0.69476318359375}, {"start": 33.03, "end": 33.59, "word": " الـ", "probability": 0.4071044921875}, {"start": 33.59, "end": 34.27, "word": " carbonyl", "probability": 0.6981608072916666}, {"start": 34.27, "end": 34.73, "word": " group", "probability": 0.97607421875}, {"start": 34.73, "end": 35.45, "word": " يعني", "probability": 0.71875}, {"start": 35.45, "end": 36.05, "word": " المجموعة", "probability": 0.8865234375}, {"start": 36.05, "end": 36.53, 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بيكون عندي C double bond O OH في ال E stars بيكون عندي C double bond O OR في الأبد C double bond O NH2 في ال acid chlorides C double bond O Cl بيجي كمان عائلة ال acid anhydrides بتمر علينا في الفصل العاشر مع هدول المجموعة", "tokens": [41185, 2423, 39184, 14979, 2213, 2423, 39184, 383, 3834, 6086, 422, 10874, 1863, 3555, 34051, 49374, 732, 497, 3935, 8978, 16247, 35571, 46958, 2423, 39184, 1032, 4995, 88, 1050, 21667, 4724, 1829, 30544, 43242, 1829, 383, 3834, 6086, 422, 13931, 8978, 2423, 462, 6105, 4724, 1829, 30544, 43242, 1829, 383, 3834, 6086, 422, 19654, 8978, 16247, 44510, 383, 3834, 6086, 422, 31118, 17, 8978, 2423, 8258, 18178, 1875, 383, 3834, 6086, 422, 2033, 4724, 1829, 7435, 1829, 9122, 2304, 7649, 6225, 16373, 37977, 2423, 8258, 364, 3495, 16753, 1875, 39894, 29973, 25894, 8315, 8978, 27188, 36520, 18863, 33599, 2288, 20449, 8032, 3215, 12610, 9673, 7435, 2304, 45367, 3660], "avg_logprob": -0.2432626168662255, "compression_ratio": 1.804255319148936, "no_speech_prob": 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"word": " ما", "probability": 0.51123046875}, {"start": 175.33, "end": 175.49, "word": " شاء", "probability": 0.9697265625}, {"start": 175.49, "end": 175.61, "word": " الله", "probability": 0.9619140625}, {"start": 175.61, "end": 175.95, "word": " عنكوا", "probability": 0.599609375}, {"start": 175.95, "end": 176.65, "word": " اتخرجتوا", "probability": 0.90673828125}, {"start": 176.65, "end": 176.75, "word": " و", "probability": 0.85498046875}, {"start": 176.75, "end": 177.01, "word": " بتكونوا", "probability": 0.5415445963541666}, {"start": 177.01, "end": 177.37, "word": " دخلوا", "probability": 0.8712158203125}, {"start": 177.37, "end": 178.25, "word": " مسابقة", "probability": 0.94677734375}, {"start": 178.25, "end": 179.55, "word": " توظيف", "probability": 0.92822265625}], "temperature": 1.0}, {"id": 10, "seek": 20284, "start": 181.1, "end": 202.84, "text": "مش معقول نجيبلكوا ورقة و جلم و أنتوا تدخلين امتحان شفه و نقعد نقولكوا عيدوا و زيدوا نسألكوا سؤالين تلاتة عامين جدا بنعرفكوا بتفهموا كيميا عضوية ولا لأ لو أجينا قولنالكوا مثلا ايش التفاعل الأساسي على الalkenes لازم أسمع addition و electrophilic addition على الalkalites", "tokens": [2304, 8592, 20449, 39648, 8717, 7435, 1829, 3555, 23275, 14407, 4032, 2288, 28671, 4032, 10874, 19528, 4032, 14739, 2655, 14407, 6055, 3215, 9778, 1211, 9957, 1975, 2304, 2655, 5016, 7649, 13412, 5172, 3224, 4032, 8717, 4587, 22488, 8717, 39648, 4117, 14407, 6225, 25708, 14407, 4032, 30767, 25708, 14407, 8717, 3794, 10721, 23275, 14407, 8608, 33604, 6027, 9957, 6055, 1211, 9307, 3660, 6225, 10943, 9957, 10874, 28259, 44945, 3615, 28480, 4117, 14407, 39894, 5172, 16095, 14407, 9122, 32640, 25528, 6225, 11242, 2407, 10632, 49429, 5296, 10721, 45164, 5551, 7435, 1829, 8315, 12174, 12610, 8315, 23275, 14407, 50113, 15040, 1975, 1829, 8592, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 15844, 2423, 667, 25973, 5296, 31377, 2304, 5551, 38251, 3615, 4500, 4032, 2185, 11741, 388, 299, 4500, 15844, 2423, 667, 304, 3324], 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تانية لأنه في اختلاف جوهري في التفاعل الأساسي لهدول العائلتين واحد بتفعل بالإضافة والثاني بتفعل بالإبدال", "tokens": [3555, 3794, 23758, 11331, 49975, 7251, 30544, 43242, 24793, 44713, 40228, 16758, 32239, 8592, 8032, 3215, 12610, 9673, 31747, 3555, 9957, 7251, 2304, 12984, 1211, 14407, 4724, 24401, 29910, 9307, 16095, 6225, 16373, 37977, 46599, 995, 38436, 9673, 31747, 3555, 9307, 29538, 46811, 12984, 1211, 6225, 16373, 37977, 6055, 7649, 10632, 5296, 33456, 3224, 8978, 1975, 46456, 15040, 5172, 10874, 2407, 3224, 16572, 8978, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 5296, 3224, 3215, 12610, 18863, 16373, 1211, 2655, 9957, 36764, 24401, 39894, 5172, 30241, 20666, 28814, 11242, 31845, 3660, 16070, 12984, 7649, 1829, 39894, 5172, 30241, 20666, 28814, 44510, 6027], "avg_logprob": -0.18082524300778954, "compression_ratio": 1.9533678756476685, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 225.16, "end": 225.46, "word": "بس", "probability": 0.760009765625}, 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المجموعة بس في ال الديهايد عمره لا أحد يحط وان بيوتنال خلاص بيوتنال هي لا تكون إلا على موقع واحد واضح هذه الفكرة؟ سنشوف أمثل إضافية الآن جزء من الاروماتيك كومباونز مر علينا هذا المركب ال pins الديهايد", "tokens": [1829, 7435, 3555, 14739, 8717, 11242, 3615, 5551, 2288, 4587, 10943, 8978, 11331, 6027, 3660, 2423, 39184, 14979, 546, 11933, 15730, 25961, 5296, 16254, 8315, 5296, 3555, 3794, 8978, 3714, 30543, 3615, 9673, 7435, 2304, 2407, 27884, 4724, 3794, 8978, 2423, 2423, 16254, 11296, 25708, 6225, 29973, 3224, 20193, 5551, 24401, 7251, 5016, 9566, 4032, 7649, 4724, 1829, 35473, 1863, 6027, 16490, 1211, 33546, 4724, 1829, 35473, 1863, 6027, 39896, 20193, 6055, 30544, 11933, 15040, 15844, 3714, 30543, 3615, 36764, 24401, 4032, 46958, 5016, 29538, 27188, 4117, 25720, 22807, 8608, 1863, 8592, 38688, 5551, 2304, 12984, 1211, 11933, 11242, 31845, 10632, 6024, 48506, 10874, 11622, 38207, 9154, 2423, 9640, 20498, 9307, 1829, 4117, 9122, 20498, 3555, 995, 11536, 11622, 3714, 2288, 25894, 8315, 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0.9501953125}, {"start": 767.95, "end": 768.43, "word": " لدينا", "probability": 0.6654459635416666}, {"start": 768.43, "end": 768.81, "word": " لبس", "probability": 0.9070638020833334}, {"start": 768.81, "end": 768.97, "word": " في", "probability": 0.30078125}, {"start": 768.97, "end": 769.51, "word": " موقع", "probability": 0.8006184895833334}, {"start": 769.51, "end": 770.07, "word": " المجموعة", "probability": 0.91044921875}, {"start": 770.07, "end": 770.57, "word": " بس", "probability": 0.5782470703125}, {"start": 770.57, "end": 770.71, "word": " في", "probability": 0.8564453125}, {"start": 770.71, "end": 770.81, "word": " ال", "probability": 0.9658203125}, {"start": 770.81, "end": 771.35, "word": " الديهايد", "probability": 0.58624267578125}, {"start": 771.35, "end": 771.69, "word": " عمره", "probability": 0.5865885416666666}, {"start": 771.69, "end": 771.83, "word": " لا", "probability": 0.3818359375}, {"start": 771.83, "end": 771.97, "word": " أحد", "probability": 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{"start": 776.91, "end": 777.69, "word": " واضح", "probability": 0.94091796875}, {"start": 777.69, "end": 777.91, "word": " هذه", "probability": 0.65625}, {"start": 777.91, "end": 778.81, "word": " الفكرة؟", "probability": 0.84027099609375}, {"start": 778.81, "end": 780.11, "word": " سنشوف", "probability": 0.72607421875}, {"start": 780.11, "end": 780.45, "word": " أمثل", "probability": 0.79571533203125}, {"start": 780.45, "end": 781.01, "word": " إضافية", "probability": 0.9659423828125}, {"start": 781.01, "end": 781.73, "word": " الآن", "probability": 0.6739501953125}, {"start": 781.73, "end": 781.87, "word": " جزء", "probability": 0.7635091145833334}, {"start": 781.87, "end": 781.87, "word": " من", "probability": 0.98974609375}, {"start": 781.87, "end": 782.47, "word": " الاروماتيك", "probability": 0.7914835611979166}, {"start": 782.47, "end": 783.11, "word": " كومباونز", "probability": 0.7888997395833334}, {"start": 783.11, "end": 785.17, "word": " مر", "probability": 0.66162109375}, {"start": 785.17, "end": 785.81, "word": " علينا", "probability": 0.930908203125}, {"start": 785.81, "end": 786.77, "word": " هذا", "probability": 0.6845703125}, {"start": 786.77, "end": 787.43, "word": " المركب", "probability": 0.8312174479166666}, {"start": 787.43, "end": 787.63, "word": " ال", "probability": 0.66357421875}, {"start": 787.63, "end": 787.95, "word": " pins", "probability": 0.392578125}, {"start": 787.95, "end": 788.85, "word": " الديهايد", "probability": 0.8997802734375}], "temperature": 1.0}, {"id": 36, "seek": 81815, "start": 789.63, "end": 818.15, "text": "مر علينا و بتعرفوا لو كان في substitution تاني علمناكوا كيف نسميه هذا المركب مثلا هي في aldehyde و OH لمن أولويته في التسمية لل aldehyde اذا انا هرقم منها و همر أسرع ما يمكن على ال OH فبدي يكون المركب 2-hydroxybenzaldehyde يعني لو كتبتوا 2-hydroxybenzaldehyde it's okay", "tokens": [29973, 25894, 8315, 4032, 39894, 3615, 28480, 14407, 45164, 25961, 8978, 35827, 6055, 7649, 1829, 11203, 2304, 8315, 4117, 14407, 9122, 33911, 8717, 38251, 1829, 3224, 23758, 9673, 31747, 3555, 50113, 15040, 39896, 8978, 16798, 68, 3495, 1479, 4032, 13931, 5296, 27842, 5551, 12610, 45865, 47395, 8978, 16712, 38251, 10632, 24976, 16798, 68, 3495, 1479, 1975, 15730, 1975, 8315, 8032, 2288, 4587, 2304, 9154, 11296, 4032, 8032, 29973, 5551, 3794, 2288, 3615, 19446, 7251, 43020, 15844, 2423, 13931, 6156, 3555, 16254, 7251, 30544, 9673, 31747, 3555, 568, 12, 21591, 340, 12876, 1799, 89, 304, 1479, 3495, 1479, 37495, 22653, 45164, 9122, 2655, 3555, 2655, 14407, 568, 12, 21591, 340, 12876, 1799, 89, 304, 1479, 3495, 1479, 309, 311, 1392], "avg_logprob": -0.18789061841865382, "compression_ratio": 1.6762295081967213, "no_speech_prob": 7.152557373046875e-07, "words": [{"start": 789.63, "end": 789.95, "word": "مر", "probability": 0.51171875}, {"start": 789.95, "end": 790.41, "word": " علينا", "probability": 0.972412109375}, {"start": 790.41, "end": 790.51, "word": " و", "probability": 0.6689453125}, {"start": 790.51, "end": 790.95, "word": " بتعرفوا", "probability": 0.918212890625}, {"start": 790.95, "end": 791.07, "word": " لو", "probability": 0.95947265625}, {"start": 791.07, "end": 791.29, "word": " كان", "probability": 0.98681640625}, {"start": 791.29, "end": 791.43, "word": " في", "probability": 0.88427734375}, {"start": 791.43, "end": 791.99, "word": " substitution", "probability": 0.78369140625}, {"start": 791.99, "end": 792.61, "word": " تاني", "probability": 0.8922526041666666}, {"start": 792.61, "end": 793.19, "word": " علمناكوا", "probability": 0.92392578125}, {"start": 793.19, "end": 793.41, "word": " كيف", "probability": 0.968994140625}, {"start": 793.41, "end": 794.25, "word": " نسميه", "probability": 0.9534912109375}, {"start": 794.25, "end": 795.71, "word": " هذا", "probability": 0.85205078125}, {"start": 795.71, "end": 796.45, "word": " المركب", "probability": 0.8572591145833334}, {"start": 796.45, "end": 796.87, "word": " مثلا", "probability": 0.98388671875}, {"start": 796.87, "end": 797.11, "word": " هي", "probability": 0.305419921875}, {"start": 797.11, "end": 797.27, "word": " في", "probability": 0.84716796875}, {"start": 797.27, "end": 797.91, "word": " aldehyde", "probability": 0.731414794921875}, {"start": 797.91, "end": 798.03, "word": " و", "probability": 0.93359375}, {"start": 798.03, "end": 798.63, "word": " OH", "probability": 0.818359375}, {"start": 798.63, "end": 799.95, "word": " لمن", "probability": 0.627685546875}, {"start": 799.95, "end": 800.73, "word": " أولويته", "probability": 0.803955078125}, {"start": 800.73, "end": 800.87, "word": " في", "probability": 0.87451171875}, {"start": 800.87, "end": 801.69, "word": " التسمية", "probability": 0.96337890625}, {"start": 801.69, "end": 802.65, "word": " لل", "probability": 0.397705078125}, {"start": 802.65, "end": 803.21, "word": " aldehyde", "probability": 0.8953857421875}, {"start": 803.21, "end": 803.37, "word": " اذا", "probability": 0.6473388671875}, {"start": 803.37, "end": 803.61, "word": " انا", "probability": 0.885498046875}, {"start": 803.61, "end": 804.11, "word": " هرقم", "probability": 0.801513671875}, {"start": 804.11, "end": 804.39, "word": " منها", "probability": 0.7734375}, {"start": 804.39, "end": 804.51, "word": " و", "probability": 0.87255859375}, {"start": 804.51, "end": 804.83, "word": " همر", "probability": 0.772216796875}, {"start": 804.83, "end": 805.35, "word": " أسرع", "probability": 0.84759521484375}, {"start": 805.35, "end": 805.53, "word": " ما", "probability": 0.8916015625}, {"start": 805.53, "end": 806.11, "word": " يمكن", "probability": 0.90234375}, {"start": 806.11, "end": 808.03, "word": " على", "probability": 0.89404296875}, {"start": 808.03, "end": 808.33, "word": " ال", "probability": 0.984375}, {"start": 808.33, "end": 808.77, "word": " OH", "probability": 0.90185546875}, {"start": 808.77, "end": 809.15, "word": " فبدي", "probability": 0.654296875}, {"start": 809.15, "end": 809.39, "word": " يكون", "probability": 0.8896484375}, {"start": 809.39, "end": 810.17, "word": " المركب", "probability": 0.9881184895833334}, {"start": 810.17, "end": 810.91, "word": " 2", "probability": 0.74853515625}, {"start": 810.91, "end": 813.99, "word": "-hydroxybenzaldehyde", "probability": 0.8560546875}, {"start": 813.99, "end": 814.83, "word": " يعني", "probability": 0.737548828125}, {"start": 814.83, "end": 815.01, "word": " لو", "probability": 0.9833984375}, {"start": 815.01, "end": 815.43, "word": " كتبتوا", "probability": 0.94462890625}, {"start": 815.43, "end": 815.59, "word": " 2", "probability": 0.7119140625}, {"start": 815.59, "end": 817.57, "word": "-hydroxybenzaldehyde", "probability": 0.948046875}, {"start": 817.57, "end": 817.83, "word": " it's", "probability": 0.795166015625}, {"start": 817.83, "end": 818.15, "word": " okay", "probability": 0.83544921875}], "temperature": 1.0}, {"id": 37, "seek": 84451, "start": 818.91, "end": 844.51, "text": "الان مرات بيقولوله بنزين carbaldehyde لكن الأشهر بنز aldehyde زي ماذا بيسميه بنز aldehyde هذا two hydroxy benz aldehyde هذا المرتب حاطيله مش عشان تحفظوا شكله بس على أساس تشوفوا ان انا عندى aldehyde و alcohol و مثل", "tokens": [6027, 7649, 3714, 2288, 9307, 4724, 1829, 39648, 12610, 3224, 44945, 11622, 9957, 1032, 2645, 1479, 3495, 1479, 44381, 16247, 8592, 3224, 2288, 44945, 11622, 16798, 68, 3495, 1479, 30767, 1829, 3714, 45636, 995, 4724, 1829, 38251, 1829, 3224, 44945, 11622, 16798, 68, 3495, 1479, 23758, 732, 15435, 12876, 44335, 16798, 68, 3495, 1479, 23758, 9673, 43500, 3555, 11331, 41193, 26895, 3224, 37893, 6225, 8592, 7649, 6055, 5016, 5172, 19913, 14407, 13412, 28820, 3224, 4724, 3794, 15844, 5551, 3794, 32277, 6055, 8592, 38688, 14407, 16472, 1975, 8315, 43242, 7578, 16798, 68, 3495, 1479, 4032, 7658, 4032, 50113, 1211], "avg_logprob": -0.2402146425512102, "compression_ratio": 1.6446700507614214, "no_speech_prob": 0.0, "words": [{"start": 818.91, "end": 819.35, "word": "الان", "probability": 0.80322265625}, {"start": 819.35, "end": 819.75, "word": " مرات", "probability": 0.8767903645833334}, {"start": 819.75, "end": 820.19, "word": " بيقولوله", "probability": 0.92412109375}, {"start": 820.19, "end": 820.59, "word": " بنزين", "probability": 0.8650716145833334}, {"start": 820.59, "end": 821.27, "word": " carbaldehyde", "probability": 0.6795166015625}, {"start": 821.27, "end": 821.49, "word": " لكن", "probability": 0.703125}, {"start": 821.49, "end": 822.39, "word": " الأشهر", "probability": 0.940673828125}, {"start": 822.39, "end": 823.65, "word": " بنز", "probability": 0.7369384765625}, {"start": 823.65, "end": 824.15, "word": " aldehyde", "probability": 0.77325439453125}, {"start": 824.15, "end": 824.35, "word": " زي", "probability": 0.89208984375}, {"start": 824.35, "end": 824.59, "word": " ماذا", "probability": 0.7501627604166666}, {"start": 824.59, "end": 824.95, "word": " بيسميه", "probability": 0.82529296875}, {"start": 824.95, "end": 825.29, "word": " بنز", "probability": 0.91064453125}, {"start": 825.29, "end": 825.91, "word": " aldehyde", "probability": 0.908935546875}, {"start": 825.91, "end": 826.49, "word": " هذا", "probability": 0.5908203125}, {"start": 826.49, "end": 826.83, "word": " two", "probability": 0.3115234375}, {"start": 826.83, "end": 827.69, "word": " hydroxy", "probability": 0.76708984375}, {"start": 827.69, "end": 828.53, "word": " benz", "probability": 0.84375}, {"start": 828.53, "end": 829.15, "word": " aldehyde", "probability": 0.9405517578125}, {"start": 829.15, "end": 835.23, "word": " هذا", "probability": 0.3935546875}, {"start": 835.23, "end": 836.09, "word": " المرتب", "probability": 0.92431640625}, {"start": 836.09, "end": 836.83, "word": " حاطيله", "probability": 0.785888671875}, {"start": 836.83, "end": 837.05, "word": " مش", "probability": 0.97998046875}, {"start": 837.05, "end": 837.45, "word": " عشان", "probability": 0.9427083333333334}, {"start": 837.45, "end": 838.25, "word": " تحفظوا", "probability": 0.9453125}, {"start": 838.25, "end": 839.01, "word": " شكله", "probability": 0.9879557291666666}, {"start": 839.01, "end": 839.59, "word": " بس", "probability": 0.95654296875}, {"start": 839.59, "end": 839.83, "word": " على", "probability": 0.67578125}, {"start": 839.83, "end": 840.29, "word": " أساس", "probability": 0.8113606770833334}, {"start": 840.29, "end": 840.83, "word": " تشوفوا", "probability": 0.986572265625}, {"start": 840.83, "end": 840.93, "word": " ان", "probability": 0.2890625}, {"start": 840.93, "end": 841.03, "word": " انا", "probability": 0.60247802734375}, {"start": 841.03, "end": 841.49, "word": " عندى", "probability": 0.5732421875}, {"start": 841.49, "end": 842.51, "word": " aldehyde", "probability": 0.94775390625}, {"start": 842.51, "end": 842.67, "word": " و", "probability": 0.91748046875}, {"start": 842.67, "end": 843.29, "word": " alcohol", "probability": 0.45751953125}, {"start": 843.29, "end": 843.67, "word": " و", "probability": 0.8740234375}, {"start": 843.67, "end": 844.51, "word": " مثل", "probability": 0.590576171875}], "temperature": 1.0}, {"id": 38, "seek": 86797, "start": 844.95, "end": 867.97, "text": "و بنزين تقولوا إيش الكيميا هذه في النهاية هذا المركب هو ال vanilla اللي بيعملوا فيها ال cake ال vanilla اللي بيعملوا فيها ال cake الأن لو مجموعة ال aldehyde .. لو مجموعة ال aldehyde إجت على حلقة و بدي أسميها كمجموعة يعني هذه كلها Cyclopentane", "tokens": [2407, 44945, 11622, 9957, 6055, 39648, 14407, 11933, 1829, 8592, 33251, 32640, 25528, 29538, 8978, 28239, 11296, 10632, 23758, 9673, 31747, 3555, 31439, 2423, 17528, 13672, 1829, 4724, 1829, 25957, 1211, 14407, 8978, 11296, 2423, 5908, 2423, 17528, 13672, 1829, 4724, 1829, 25957, 1211, 14407, 8978, 11296, 2423, 5908, 16247, 1863, 45164, 3714, 7435, 2304, 2407, 27884, 2423, 16798, 68, 3495, 1479, 4386, 45164, 3714, 7435, 2304, 2407, 27884, 2423, 16798, 68, 3495, 1479, 11933, 7435, 2655, 15844, 11331, 1211, 28671, 4032, 4724, 16254, 5551, 38251, 1829, 11296, 9122, 2304, 7435, 2304, 2407, 27884, 37495, 22653, 29538, 28242, 11296, 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"end": 897.02, "text": "مظبوط ولا لأ؟ لو كان ديهايد و بعد شوية لما يجيني أسد بنقول Cyclopentane و بالصيغة بالبندق OH لما بتيجي كلها كمجموعة ملتصقة بالحلقات خمسية سدسية واطفات بنقول عنها carbaldehyde يعني هذه الأن أصبحت كأنها مجموعة ملتصقة بcyclopentane فهذا المركب اللي همنن نسميه بنقول Cyclopentane", "tokens": [2304, 19913, 3555, 2407, 9566, 49429, 5296, 10721, 22807, 45164, 25961, 11778, 1829, 11296, 25708, 4032, 39182, 13412, 2407, 10632, 5296, 15042, 7251, 7435, 9957, 1829, 5551, 3794, 3215, 44945, 39648, 49173, 404, 317, 1929, 4032, 20666, 9381, 1829, 17082, 3660, 20666, 3555, 41260, 4587, 13931, 5296, 15042, 39894, 1829, 7435, 1829, 28242, 11296, 9122, 2304, 7435, 2304, 2407, 27884, 3714, 1211, 2655, 9381, 28671, 20666, 5016, 1211, 4587, 9307, 16490, 2304, 3794, 10632, 8608, 3215, 3794, 10632, 4032, 41193, 5172, 9307, 44945, 39648, 18871, 11296, 12143, 304, 1479, 3495, 1479, 37495, 22653, 29538, 16247, 1863, 5551, 9381, 3555, 33753, 9122, 33456, 11296, 3714, 7435, 2304, 2407, 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"probability": 0.87060546875}, {"start": 872.02, "end": 872.2, "word": " لما", "probability": 0.79638671875}, {"start": 872.2, "end": 872.66, "word": " يجيني", "probability": 0.77581787109375}, {"start": 872.66, "end": 873.16, "word": " أسد", "probability": 0.7910970052083334}, {"start": 873.16, "end": 873.96, "word": " بنقول", "probability": 0.859619140625}, {"start": 873.96, "end": 875.3, "word": " Cyclopentane", "probability": 0.698028564453125}, {"start": 875.3, "end": 875.56, "word": " و", "probability": 0.771484375}, {"start": 875.56, "end": 876.04, "word": " بالصيغة", "probability": 0.601513671875}, {"start": 876.04, "end": 876.5, "word": " بالبندق", "probability": 0.59454345703125}, {"start": 876.5, "end": 876.92, "word": " OH", "probability": 0.62646484375}, {"start": 876.92, "end": 877.18, "word": " لما", "probability": 0.89892578125}, {"start": 877.18, "end": 877.52, "word": " بتيجي", "probability": 0.79541015625}, {"start": 877.52, "end": 877.84, "word": " كلها", "probability": 0.8037109375}, {"start": 877.84, "end": 878.42, "word": " كمجموعة", "probability": 0.8970947265625}, {"start": 878.42, "end": 879.06, "word": " ملتصقة", "probability": 0.87236328125}, {"start": 879.06, "end": 879.96, "word": " بالحلقات", "probability": 0.79970703125}, {"start": 879.96, "end": 880.44, "word": " خمسية", "probability": 0.7772216796875}, {"start": 880.44, "end": 880.92, "word": " سدسية", "probability": 0.729248046875}, {"start": 880.92, "end": 881.4, "word": " واطفات", "probability": 0.69171142578125}, {"start": 881.4, "end": 882.02, "word": " بنقول", "probability": 0.809326171875}, {"start": 882.02, "end": 882.34, "word": " عنها", "probability": 0.992919921875}, {"start": 882.34, "end": 884.06, "word": " carbaldehyde", "probability": 0.6577880859375}, {"start": 884.06, "end": 884.72, "word": " يعني", "probability": 0.89599609375}, {"start": 884.72, "end": 884.98, "word": " هذه", "probability": 0.78515625}, {"start": 884.98, "end": 885.26, "word": " الأن", "probability": 0.699951171875}, {"start": 885.26, "end": 885.74, "word": " أصبحت", "probability": 0.9530029296875}, {"start": 885.74, "end": 886.08, "word": " كأنها", "probability": 0.8927408854166666}, {"start": 886.08, "end": 887.24, "word": " مجموعة", "probability": 0.92490234375}, {"start": 887.24, "end": 888.52, "word": " ملتصقة", "probability": 0.93251953125}, {"start": 888.52, "end": 890.82, "word": " بcyclopentane", "probability": 0.8056640625}, {"start": 890.82, "end": 892.04, "word": " فهذا", "probability": 0.9661458333333334}, {"start": 892.04, "end": 892.94, "word": " المركب", "probability": 0.8196614583333334}, {"start": 892.94, "end": 893.12, "word": " اللي", "probability": 0.932861328125}, {"start": 893.12, "end": 893.48, "word": " همنن", "probability": 0.3944091796875}, {"start": 893.48, "end": 894.14, "word": " نسميه", "probability": 0.86224365234375}, {"start": 894.14, "end": 894.8, "word": " بنقول", "probability": 0.878662109375}, {"start": 894.8, "end": 897.02, "word": " Cyclopentane", "probability": 0.81085205078125}], "temperature": 1.0}, {"id": 40, "seek": 92238, "start": 897.14, "end": 922.38, "text": "وهذه المجموعة كرب أنديهيد بيصير كله Cyclopentane Carbohydrate من وين ال Clor؟ لو حطيت هنا Clor، هاي واحد، اتنين، تلاتة الأولوية لل Carbohydrate", "tokens": [2407, 3224, 24192, 9673, 7435, 2304, 2407, 27884, 9122, 25513, 14739, 16254, 3224, 25708, 4724, 1829, 9381, 13546, 28242, 3224, 10295, 3474, 404, 317, 1929, 2741, 65, 1445, 6655, 4404, 9154, 4032, 9957, 2423, 2033, 284, 22807, 45164, 11331, 9566, 36081, 34105, 2033, 284, 12399, 8032, 47302, 36764, 24401, 12399, 1975, 2655, 1863, 9957, 12399, 6055, 1211, 9307, 3660, 16247, 12610, 2407, 10632, 24976, 2741, 65, 1445, 6655, 4404], "avg_logprob": -0.41495534266744344, "compression_ratio": 1.3496932515337423, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 897.14, "end": 897.94, "word": "وهذه", "probability": 0.3654988606770833}, {"start": 897.94, "end": 901.12, "word": " المجموعة", "probability": 0.845166015625}, {"start": 901.12, "end": 902.2, "word": " كرب", "probability": 0.3800048828125}, {"start": 902.2, "end": 903.06, "word": " أنديهيد", "probability": 0.65582275390625}, {"start": 903.06, "end": 903.66, "word": " بيصير", "probability": 0.7686767578125}, {"start": 903.66, "end": 904.32, "word": " كله", "probability": 0.901611328125}, {"start": 904.32, "end": 905.5, "word": " Cyclopentane", "probability": 0.6263916015625}, {"start": 905.5, "end": 906.58, "word": " Carbohydrate", "probability": 0.706884765625}, {"start": 906.58, "end": 911.06, "word": " من", "probability": 0.6396484375}, {"start": 911.06, "end": 914.0, "word": " وين", "probability": 0.835205078125}, {"start": 914.0, "end": 914.12, "word": " ال", "probability": 0.87646484375}, {"start": 914.12, "end": 915.88, "word": " Clor؟", "probability": 0.5334065755208334}, {"start": 915.88, "end": 916.86, "word": " لو", "probability": 0.7041015625}, {"start": 916.86, "end": 917.32, "word": " حطيت", "probability": 0.92822265625}, {"start": 917.32, "end": 917.58, "word": " هنا", "probability": 0.85400390625}, {"start": 917.58, "end": 918.32, "word": " Clor،", "probability": 0.8170572916666666}, {"start": 918.32, "end": 918.58, "word": " هاي", "probability": 0.4383544921875}, {"start": 918.58, "end": 919.06, "word": " واحد،", "probability": 0.7618815104166666}, {"start": 919.06, "end": 919.68, "word": " اتنين،", "probability": 0.82470703125}, {"start": 919.68, "end": 920.82, "word": " تلاتة", "probability": 0.960205078125}, {"start": 920.82, "end": 921.62, "word": " الأولوية", "probability": 0.873291015625}, {"start": 921.62, "end": 921.84, "word": " لل", "probability": 0.5546875}, {"start": 921.84, "end": 922.38, "word": " Carbohydrate", "probability": 0.87470703125}], "temperature": 1.0}, {"id": 41, "seek": 95354, "start": 924.52, "end": 953.54, "text": "ثلاثة كلورو سايكلوبنتين كربالديهيد وين ال double bond؟ بتصير سايكلوبنتين و بنحدد موقع ال double bond ببدأ من عند ال aldehyde ببدأ من عند ال aldehyde one واضح؟ ببدأ ال one من عند ال aldehyde يعني لو double bond هنا بقول one, two, three و بمشي بهذا الشكل واضح؟ بنبدأ من عند ال aldehyde", "tokens": [12984, 1211, 5718, 104, 3660, 9122, 1211, 13063, 2407, 8608, 47302, 28820, 2407, 3555, 29399, 9957, 9122, 25513, 6027, 16254, 3224, 25708, 4032, 9957, 2423, 3834, 6086, 22807, 39894, 9381, 13546, 8608, 47302, 28820, 2407, 3555, 29399, 9957, 4032, 44945, 24401, 3215, 3714, 30543, 3615, 2423, 3834, 6086, 4724, 44510, 10721, 9154, 43242, 2423, 16798, 68, 3495, 1479, 4724, 44510, 10721, 9154, 43242, 2423, 16798, 68, 3495, 1479, 472, 4032, 46958, 5016, 22807, 4724, 44510, 10721, 2423, 472, 9154, 43242, 2423, 16798, 68, 3495, 1479, 37495, 22653, 45164, 3834, 6086, 34105, 4724, 39648, 472, 11, 732, 11, 1045, 4032, 4724, 2304, 8592, 1829, 39627, 15730, 25124, 28820, 4032, 46958, 5016, 22807, 44945, 44510, 10721, 9154, 43242, 2423, 16798, 68, 3495, 1479], "avg_logprob": -0.2590932257351328, "compression_ratio": 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احتمالين، لاحظوا الـ c double bond إذا إجت على أول موقع فمركبه الدماغ، إذا إجت على الموقع التاني two pentanol، إذا إجت على الموقع الثالث", "tokens": [3555, 3794, 1975, 33753, 2304, 6027, 9957, 12399, 20193, 5016, 19913, 14407, 2423, 39184, 269, 3834, 6086, 11933, 15730, 11933, 7435, 2655, 15844, 5551, 12610, 3714, 30543, 3615, 6156, 29973, 4117, 3555, 3224, 32748, 2304, 5718, 118, 12399, 11933, 15730, 11933, 7435, 2655, 15844, 9673, 30543, 3615, 16712, 7649, 1829, 732, 16834, 282, 401, 12399, 11933, 15730, 11933, 7435, 2655, 15844, 9673, 30543, 3615, 6024, 104, 6027, 12984], "avg_logprob": -0.29098731365756714, "compression_ratio": 1.65, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 1089.23, "end": 1089.55, "word": "بس", "probability": 0.6204833984375}, {"start": 1089.55, "end": 1090.43, "word": " احتمالين،", "probability": 0.7644856770833334}, {"start": 1090.43, "end": 1091.01, "word": " لاحظوا", "probability": 0.9422607421875}, {"start": 1091.01, "end": 1091.65, "word": 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1196.75, "word": " nomenclature", "probability": 0.9322509765625}, {"start": 1196.75, "end": 1196.89, "word": " اللي", "probability": 0.666748046875}, {"start": 1196.89, "end": 1196.99, "word": " هي", "probability": 0.86572265625}, {"start": 1196.99, "end": 1197.65, "word": " التسمية", "probability": 0.9637044270833334}, {"start": 1197.65, "end": 1198.97, "word": " الشعبية", "probability": 0.994384765625}], "temperature": 1.0}, {"id": 52, "seek": 121783, "start": 1201.36, "end": 1217.84, "text": "الأساس في تسمية ال الديهيدز حرفين والأساس في تسمية ال ketones تلت حروف ال الديهيدز لما بنسميه بنضيف نهاية A لل ketones on", "tokens": [6027, 10721, 3794, 32277, 8978, 6055, 38251, 10632, 2423, 2423, 16254, 3224, 25708, 11622, 11331, 28480, 9957, 16070, 10721, 3794, 32277, 8978, 6055, 38251, 10632, 2423, 14979, 2213, 6055, 1211, 2655, 11331, 32887, 5172, 2423, 2423, 16254, 3224, 25708, 11622, 5296, 15042, 44945, 38251, 1829, 3224, 44945, 11242, 33911, 8717, 11296, 10632, 316, 24976, 14979, 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"word": " هو", "probability": 0.98291015625}, {"start": 1225.69, "end": 1226.93, "word": " الديهايد", "probability": 0.777587890625}, {"start": 1226.93, "end": 1227.67, "word": " والنهايته", "probability": 0.78818359375}, {"start": 1227.67, "end": 1228.17, "word": " on", "probability": 0.88671875}, {"start": 1228.17, "end": 1228.91, "word": " إذا", "probability": 0.96337890625}, {"start": 1228.91, "end": 1229.33, "word": " هو", "probability": 0.97998046875}, {"start": 1229.33, "end": 1230.17, "word": " كيتون", "probability": 0.8289388020833334}, {"start": 1230.17, "end": 1231.23, "word": " هنا", "probability": 0.379150390625}, {"start": 1231.23, "end": 1231.69, "word": " مثلا", "probability": 0.967529296875}, {"start": 1231.69, "end": 1231.99, "word": " هذا", "probability": 0.9169921875}, {"start": 1231.99, "end": 1232.61, "word": " المركب", "probability": 0.98583984375}, {"start": 1232.61, "end": 1235.29, "word": " Cyclohexane", "probability": 0.809814453125}, {"start": 1235.29, "end": 1235.89, "word": " بيصير", "probability": 0.8299560546875}, {"start": 1235.89, "end": 1238.27, "word": " Cyclohexanone", "probability": 0.9199916294642857}, {"start": 1238.27, "end": 1238.91, "word": " بيلزم", "probability": 0.822900390625}, {"start": 1238.91, "end": 1239.21, "word": " نيجي", "probability": 0.950439453125}, {"start": 1239.21, "end": 1239.47, "word": " نقول", "probability": 0.987060546875}, {"start": 1239.47, "end": 1239.87, "word": " one", "probability": 0.91796875}, {"start": 1239.87, "end": 1242.63, "word": " Cyclohexanone؟", "probability": 0.83636474609375}, {"start": 1242.63, "end": 1243.59, "word": " مابيلزم", "probability": 0.77568359375}, {"start": 1243.59, "end": 1243.81, "word": " لأن", "probability": 0.718505859375}, {"start": 1243.81, "end": 1244.43, "word": " كل", "probability": 0.826171875}, {"start": 1244.43, "end": 1245.17, "word": " المواقع", "probability": 0.9910888671875}, {"start": 1245.17, "end": 1245.63, "word": " في", "probability": 0.8916015625}, {"start": 1245.63, "end": 1246.45, "word": " Cyclohexane", "probability": 0.8960774739583334}, {"start": 1246.45, "end": 1246.93, "word": " تعتبر", "probability": 0.675537109375}, {"start": 1246.93, "end": 1247.57, "word": " مواقع", "probability": 0.9920654296875}, {"start": 1247.57, "end": 1248.47, "word": " متساوية", "probability": 0.95126953125}], "temperature": 1.0}, {"id": 54, "seek": 126492, "start": 1250.3, "end": 1264.92, "text": "هذا الـ Ketone أخدتوله اسم انتوا لما تكون مجموعة الاسيتا على البنزين سمناه اسيتوفينون وممكن نسميه برضه على أساس أن هذا كيتون، هاي مجموعة أو هاي مجموعة", "tokens": [3224, 15730, 2423, 39184, 591, 302, 546, 5551, 9778, 3215, 2655, 12610, 3224, 24525, 2304, 16472, 2655, 14407, 5296, 15042, 6055, 30544, 3714, 7435, 2304, 2407, 27884, 2423, 32277, 36081, 995, 15844, 29739, 1863, 11622, 9957, 8608, 2304, 8315, 3224, 24525, 36081, 38688, 9957, 11536, 4032, 2304, 43020, 8717, 38251, 1829, 3224, 4724, 43042, 3224, 15844, 5551, 3794, 32277, 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{"start": 1254.9, "end": 1255.88, "word": " الاسيتا", "probability": 0.6085205078125}, {"start": 1255.88, "end": 1256.2, "word": " على", "probability": 0.490234375}, {"start": 1256.2, "end": 1256.8, "word": " البنزين", "probability": 0.963623046875}, {"start": 1256.8, "end": 1257.6, "word": " سمناه", "probability": 0.66796875}, {"start": 1257.6, "end": 1259.6, "word": " اسيتوفينون", "probability": 0.7197509765625}, {"start": 1259.6, "end": 1260.4, "word": " وممكن", "probability": 0.7249348958333334}, {"start": 1260.4, "end": 1261.04, "word": " نسميه", "probability": 0.91650390625}, {"start": 1261.04, "end": 1261.7, "word": " برضه", "probability": 0.8199055989583334}, {"start": 1261.7, "end": 1262.06, "word": " على", "probability": 0.9326171875}, {"start": 1262.06, "end": 1262.52, "word": " أساس", "probability": 0.9378255208333334}, {"start": 1262.52, "end": 1262.64, "word": " أن", "probability": 0.3291015625}, {"start": 1262.64, "end": 1262.84, "word": " هذا", "probability": 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{"start": 1685.83, "end": 1686.49, "word": " الكيتون", "probability": 0.89794921875}, {"start": 1686.49, "end": 1687.25, "word": " مُركّبي", "probability": 0.95869140625}, {"start": 1687.25, "end": 1687.85, "word": " بأنسبه", "probability": 0.9873046875}, {"start": 1687.85, "end": 1688.67, "word": " للالديهيد", "probability": 0.9365234375}, {"start": 1688.67, "end": 1689.15, "word": " إذا", "probability": 0.90380859375}, {"start": 1689.15, "end": 1689.61, "word": " نهاية", "probability": 0.9265950520833334}, {"start": 1689.61, "end": 1690.41, "word": " مُركّبي", "probability": 0.9484375}, {"start": 1690.41, "end": 1692.43, "word": " ال", "probability": 0.330322265625}, {"start": 1692.43, "end": 1692.85, "word": " ..", "probability": 0.22412109375}, {"start": 1692.85, "end": 1693.55, "word": " واضح؟", "probability": 0.8990478515625}, {"start": 1693.55, "end": 1693.93, "word": " إذا", "probability": 0.868408203125}, {"start": 1693.93, "end": 1694.19, "word": " هنا", "probability": 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"end": 2670.65, "word": " اكلوراي", "probability": 0.58056640625}, {"start": 2670.65, "end": 2673.13, "word": " بالايوباد", "probability": 0.65966796875}, {"start": 2673.13, "end": 2677.69, "word": " هلأ", "probability": 0.500732421875}, {"start": 2677.69, "end": 2678.93, "word": " مصطلقة", "probability": 0.63330078125}, {"start": 2678.93, "end": 2681.89, "word": " إيش؟", "probability": 0.6522216796875}, {"start": 2681.89, "end": 2682.91, "word": " مثيل،", "probability": 0.7239583333333334}, {"start": 2682.91, "end": 2683.51, "word": " بس", "probability": 0.981689453125}, {"start": 2683.51, "end": 2684.23, "word": " كرمولة", "probability": 0.70966796875}, {"start": 2684.23, "end": 2685.15, "word": " واحدة،", "probability": 0.8861083984375}, {"start": 2685.15, "end": 2685.43, "word": " شو", "probability": 0.98095703125}, {"start": 2685.43, "end": 2686.07, "word": " بيحمل", "probability": 0.9490966796875}, {"start": 2686.07, "end": 2687.59, "word": " المثيل؟", "probability": 0.9132080078125}, {"start": 2687.59, "end": 2689.15, "word": " اكلورا", "probability": 0.740185546875}, {"start": 2689.15, "end": 2690.33, "word": " ثانل", "probability": 0.5013020833333334}, {"start": 2690.33, "end": 2691.15, "word": " مثيل", "probability": 0.98095703125}], "temperature": 1.0}, {"id": 109, "seek": 270080, "start": 2693.1, "end": 2700.8, "text": "كأنه أصله CH4 شيلنا H وعطينا Cl وشيلنا H وعطينا Ph إذا هو مشتقة مثيل", "tokens": [4117, 33456, 3224, 5551, 36520, 3224, 5995, 19, 13412, 26895, 8315, 389, 4032, 3615, 9566, 1829, 8315, 2033, 4032, 8592, 26895, 8315, 389, 4032, 3615, 9566, 1829, 8315, 2623, 11933, 15730, 31439, 37893, 2655, 28671, 50113, 26895], "avg_logprob": -0.3638980216101596, "compression_ratio": 1.2696629213483146, "no_speech_prob": 0.0, "words": [{"start": 2693.1, "end": 2693.6, "word": "كأنه", "probability": 0.7701822916666666}, {"start": 2693.6, "end": 2694.08, "word": " أصله", "probability": 0.84423828125}, {"start": 2694.08, "end": 2694.92, "word": " CH4", "probability": 0.91064453125}, {"start": 2694.92, "end": 2695.32, "word": " شيلنا", "probability": 0.7173258463541666}, {"start": 2695.32, "end": 2695.52, "word": " H", "probability": 0.68408203125}, {"start": 2695.52, "end": 2696.02, "word": " وعطينا", "probability": 0.793994140625}, {"start": 2696.02, "end": 2696.24, "word": " Cl", "probability": 0.25439453125}, {"start": 2696.24, "end": 2697.3, "word": " وشيلنا", "probability": 0.7362060546875}, {"start": 2697.3, "end": 2697.48, "word": " H", "probability": 0.87548828125}, {"start": 2697.48, "end": 2698.02, "word": " وعطينا", "probability": 0.96416015625}, {"start": 2698.02, "end": 2698.26, "word": " Ph", "probability": 0.81591796875}, {"start": 2698.26, "end": 2698.6, "word": " إذا", "probability": 0.69921875}, {"start": 2698.6, "end": 2698.76, "word": " هو", "probability": 0.67236328125}, {"start": 2698.76, "end": 2699.52, "word": " مشتقة", "probability": 0.6663411458333334}, {"start": 2699.52, "end": 2700.8, "word": " مثيل", "probability": 0.67333984375}], "temperature": 1.0}, {"id": 110, "seek": 273239, "start": 2704.27, "end": 2732.39, "text": "مثل بنزل إكلورايد فلما نقول بنزل إكلورايد مُركّب و لما نقول بنزايل إكلورايد مُركّب تاني مختلف رجال ما تخلطوش بينهم بنزايل و بنزل مُركّبين مختلفين H-formyl سيضاو المندقو مثل أسيتل و سيضاو بالمندقو فينل بنزايد", "tokens": [2304, 12984, 1211, 44945, 11622, 1211, 11933, 4117, 1211, 13063, 995, 25708, 6156, 1211, 15042, 8717, 39648, 44945, 11622, 1211, 11933, 4117, 1211, 13063, 995, 25708, 3714, 10859, 31747, 11703, 3555, 4032, 5296, 15042, 8717, 39648, 44945, 11622, 995, 26895, 11933, 4117, 1211, 13063, 995, 25708, 3714, 10859, 31747, 11703, 3555, 6055, 7649, 1829, 3714, 46456, 46538, 12602, 7435, 6027, 19446, 6055, 9778, 1211, 9566, 2407, 8592, 49374, 16095, 44945, 11622, 995, 26895, 4032, 44945, 11622, 1211, 3714, 10859, 31747, 11703, 3555, 9957, 3714, 46456, 46538, 9957, 389, 12, 837, 5088, 8608, 1829, 11242, 995, 2407, 9673, 41260, 4587, 2407, 50113, 1211, 5551, 3794, 36081, 1211, 4032, 8608, 1829, 11242, 995, 2407, 20666, 2304, 41260, 4587, 2407, 8978, 1863, 1211, 44945, 11622, 995, 25708], "avg_logprob": -0.2747500114440918, "compression_ratio": 2.1502890173410405, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2704.27, "end": 2704.95, "word": "مثل", "probability": 0.6851806640625}, {"start": 2704.95, "end": 2706.03, "word": " بنزل", "probability": 0.7296549479166666}, {"start": 2706.03, "end": 2706.75, "word": " إكلورايد", "probability": 0.8041178385416666}, {"start": 2706.75, "end": 2707.33, "word": " فلما", "probability": 0.590087890625}, {"start": 2707.33, "end": 2707.65, "word": " نقول", "probability": 0.976318359375}, {"start": 2707.65, "end": 2708.19, "word": " بنزل", "probability": 0.9775390625}, {"start": 2708.19, "end": 2708.87, "word": " إكلورايد", "probability": 0.8873697916666666}, {"start": 2708.87, "end": 2709.63, "word": " مُركّب", "probability": 0.799169921875}, {"start": 2709.63, "end": 2710.05, "word": " و", "probability": 0.8525390625}, {"start": 2710.05, "end": 2710.31, "word": " لما", "probability": 0.76123046875}, {"start": 2710.31, "end": 2710.67, "word": " نقول", "probability": 0.9921875}, {"start": 2710.67, "end": 2711.71, "word": " بنزايل", "probability": 0.705108642578125}, {"start": 2711.71, "end": 2712.69, "word": " إكلورايد", "probability": 0.9029134114583334}, {"start": 2712.69, "end": 2714.05, "word": " مُركّب", "probability": 0.97802734375}, {"start": 2714.05, "end": 2714.59, "word": " تاني", "probability": 0.86181640625}, {"start": 2714.59, "end": 2715.17, "word": " مختلف", "probability": 0.8504231770833334}, {"start": 2715.17, "end": 2715.69, "word": " رجال", "probability": 0.7076822916666666}, {"start": 2715.69, "end": 2716.89, "word": " ما", "probability": 0.54345703125}, {"start": 2716.89, "end": 2717.55, "word": " تخلطوش", "probability": 0.9615885416666666}, {"start": 2717.55, "end": 2718.23, "word": " بينهم", "probability": 0.97265625}, {"start": 2718.23, "end": 2719.49, "word": " بنزايل", "probability": 0.9444580078125}, {"start": 2719.49, "end": 2720.15, "word": " و", "probability": 0.5517578125}, {"start": 2720.15, "end": 2720.77, "word": " بنزل", "probability": 0.9786783854166666}, {"start": 2720.77, "end": 2721.99, "word": " مُركّبين", "probability": 0.9483235677083334}, {"start": 2721.99, "end": 2722.99, "word": " مختلفين", "probability": 0.9700927734375}, {"start": 2722.99, "end": 2725.27, "word": " H", "probability": 0.560546875}, {"start": 2725.27, "end": 2725.91, "word": "-formyl", "probability": 0.5390625}, {"start": 2725.91, "end": 2726.31, "word": " سيضاو", "probability": 0.508203125}, {"start": 2726.31, "end": 2726.85, "word": " المندقو", "probability": 0.408294677734375}, {"start": 2726.85, "end": 2727.49, "word": " مثل", "probability": 0.881591796875}, {"start": 2727.49, "end": 2728.25, "word": " أسيتل", "probability": 0.7177734375}, {"start": 2728.25, "end": 2728.65, "word": " و", "probability": 0.59814453125}, {"start": 2728.65, "end": 2729.03, "word": " سيضاو", "probability": 0.94326171875}, {"start": 2729.03, "end": 2729.77, "word": " بالمندقو", "probability": 0.815380859375}, {"start": 2729.77, "end": 2730.59, "word": " فينل", "probability": 0.5511067708333334}, {"start": 2730.59, "end": 2732.39, "word": " بنزايد", "probability": 0.861328125}], "temperature": 1.0}, {"id": 111, "seek": 273996, "start": 2735.4, "end": 2739.96, "text": "بهيك بننتهي اليوم في موضوع التسمية", "tokens": [3555, 3224, 1829, 4117, 44945, 29399, 3224, 1829, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 16712, 38251, 10632], "avg_logprob": -0.13106497181089302, "compression_ratio": 1.0161290322580645, "no_speech_prob": 0.0, "words": [{"start": 2735.4, "end": 2735.9, "word": "بهيك", "probability": 0.752899169921875}, {"start": 2735.9, "end": 2736.68, "word": " بننتهي", "probability": 0.9163818359375}, {"start": 2736.68, "end": 2737.34, "word": " اليوم", "probability": 0.951171875}, {"start": 2737.34, "end": 2737.52, "word": " في", "probability": 0.9453125}, {"start": 2737.52, "end": 2738.72, "word": " موضوع", "probability": 0.992919921875}, {"start": 2738.72, "end": 2739.96, "word": " التسمية", "probability": 0.94189453125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2778.2675, "duration_after_vad": 2636.8931249999896}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e145b24756d57a9a9aff9ced30651e05d9e08070
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_raw.srt
@@ -0,0 +1,2076 @@
+1
+00:00:09,000 --> 00:00:12,660
+بنبدأ اليوم بالفصل التاسع، العنوان هو الـ
+
+2
+00:00:12,660 --> 00:00:17,420
+aldehydes والكيتوز الان الفصل التاسع و الفصل
+
+3
+00:00:17,420 --> 00:00:24,320
+العاشر بيتكلم عن المركبات اللي فيها رابطة C double
+
+4
+00:00:24,320 --> 00:00:31,060
+bond O هذه المجموعة الـ C double bond O في أي مكان
+
+5
+00:00:31,060 --> 00:00:36,530
+كانتبسموها الـ carbonyl group يعني المجموعة نفسها
+
+6
+00:00:36,530 --> 00:00:40,410
+الـ C double bond O لحالها بيقولوا عنها ال
+
+7
+00:00:40,410 --> 00:00:45,170
+carbonyl group الآن المركبات اللي فيهمC double
+
+8
+00:00:45,170 --> 00:00:50,570
+bond O بنقول عنهم Carbonyl compounds واضح؟ إذا في
+
+9
+00:00:50,570 --> 00:00:54,290
+عندي Carbonyl group و Carbonyl compounds ال
+
+10
+00:00:54,290 --> 00:00:58,130
+Carbonyl compounds أنواع كتيرة يعني موجود في كتير
+
+11
+00:00:58,130 --> 00:01:02,890
+موجود في كتير C double bond O يعني مثلا في ال
+
+12
+00:01:02,890 --> 00:01:07,960
+aldehydes ال C double bond O جنب hydrogenفي الـ
+
+13
+00:01:07,960 --> 00:01:11,560
+ketones الـ C double bond O جنب أو بين two R
+
+14
+00:01:11,560 --> 00:01:16,580
+groups في الأحماض الـ carboxylic acids بيكون عندي
+
+15
+00:01:16,580 --> 00:01:20,340
+C double bond O OH في ال E stars بيكون عندي C
+
+16
+00:01:20,340 --> 00:01:25,060
+double bond O OR في الأبد C double bond O NH2 في
+
+17
+00:01:25,060 --> 00:01:29,300
+ال acid chlorides C double bond O Cl بيجي كمان
+
+18
+00:01:29,300 --> 00:01:33,440
+عائلة ال acid anhydrides بتمر علينا في الفصل
+
+19
+00:01:33,440 --> 00:01:37,800
+العاشر مع هدول المجموعةالان هذه ال carbonyl
+
+20
+00:01:37,800 --> 00:01:43,640
+compounds كلها بجسمها نوعين وبناء على ذلك كمان
+
+21
+00:01:43,640 --> 00:01:48,600
+بتبين في تقسيم الفصول في الكتاب يعني ال aldehydes
+
+22
+00:01:48,600 --> 00:01:54,460
+و ال ketones يعتبروا نوعو ال acid و بيقولوا عن هذه
+
+23
+00:01:54,460 --> 00:01:58,880
+الأشياء كلها مشتقات ال acid طالعة من الحامض بتيجي
+
+24
+00:01:58,880 --> 00:02:04,540
+نوع تاني، الآن ليش هذا التصنيف؟ ليش ال aldehydes و
+
+25
+00:02:04,540 --> 00:02:08,800
+ال ketones؟ نوع و بنفسله عادة في جميع كتب ال
+
+26
+00:02:08,800 --> 00:02:13,730
+organic تقريبابفصلوه في فصل مستقل لحاله والأحماض
+
+27
+00:02:13,730 --> 00:02:18,230
+ومشتقاتها بتلاقوها بفصل تاني لحالها لأن هدولة
+
+28
+00:02:18,230 --> 00:02:24,360
+باختلفوا اختلاف كبير في طريقة التفاعلفي المحصلة
+
+29
+00:02:24,360 --> 00:02:29,280
+هتتعلموا كلمتين اللي بيدقن هدولا الكلمتين عن فهم
+
+30
+00:02:29,280 --> 00:02:34,320
+بيكون استوعب المادة كلها اللي هي الفصل التاسع
+
+31
+00:02:34,320 --> 00:02:39,720
+والفصل العاشر ان ال الديهايتس والكيتونز التفاعل
+
+32
+00:02:39,720 --> 00:02:46,650
+الأساسي تبعهم هو تفاعل إضافة additionوالأحماض
+
+33
+00:02:46,650 --> 00:02:51,430
+ومشتقاتها التفاعل الأساسي تبعهم تفاعل إبدال
+
+34
+00:02:51,430 --> 00:02:55,950
+substitution واضح؟ يعني لو أنتوا ما شاء الله عنكوا
+
+35
+00:02:55,950 --> 00:03:01,800
+اتخرجتوا و بتكونوا دخلوا مسابقة توظيفمش معقول
+
+36
+00:03:01,800 --> 00:03:04,600
+نجيبلكوا ورقة و جلم و أنتوا تدخلين امتحان شفه و
+
+37
+00:03:04,600 --> 00:03:08,320
+نقعد نقولكوا عيدوا و زيدوا نسألكوا سؤالين تلاتة
+
+38
+00:03:08,320 --> 00:03:12,300
+عامين جدا بنعرفكوا بتفهموا كيميا عضوية ولا لأ لو
+
+39
+00:03:12,300 --> 00:03:15,700
+أجينا قولنالكوا مثلا ايش التفاعل الأساسي على
+
+40
+00:03:15,700 --> 00:03:21,180
+الalkenes لازم أسمع addition و electrophilic
+
+41
+00:03:21,180 --> 00:03:26,140
+addition على الalkalitesلازم أسمع substitution و
+
+42
+00:03:26,140 --> 00:03:30,200
+nucleophilic على الـ aromatic compounds مثلًا
+
+43
+00:03:30,200 --> 00:03:36,320
+Electrophilic substitution على الألديهيدس
+
+44
+00:03:36,320 --> 00:03:41,640
+والكيتونز تفاعلنا addition على الأحماض ومشتقاتها
+
+45
+00:03:41,640 --> 00:03:46,240
+تفاعلنا substitution هذا هنشوفه بالأمثلةبس هذا حتى
+
+46
+00:03:46,240 --> 00:03:50,720
+يكون عندكم استيعاب ليش هدول المركبين يمثلوا بحد
+
+47
+00:03:50,720 --> 00:03:56,640
+ذاتهم عائلة وباقي المركبات هذه تمثل عائلة تانية
+
+48
+00:03:56,640 --> 00:04:00,740
+لأنه في اختلاف جوهري في التفاعل الأساسي لهدول
+
+49
+00:04:00,740 --> 00:04:03,480
+العائلتين واحد بتفعل بالإضافة والثاني بتفعل
+
+50
+00:04:03,480 --> 00:04:04,420
+بالإبدال
+
+51
+00:04:07,820 --> 00:04:11,840
+بالنسبة لبعض الخواص لـ aldehydes و الـ ketones
+
+52
+00:04:11,840 --> 00:04:17,300
+طبعا واضح ان الرابط السيطب الـ bond O نسبيا polar
+
+53
+00:04:17,300 --> 00:04:21,360
+بس مافيش فيه hydrogen bonding يعني لما أطلع انا
+
+54
+00:04:21,360 --> 00:04:24,700
+على ال oxygen و ال carbon ال oxygen is more
+
+55
+00:04:24,700 --> 00:04:29,800
+electronegative than carbon و عشان هيك هتلاحظوا
+
+56
+00:04:29,800 --> 00:04:36,040
+دائما ان في عندى طرف سالب عند ال oxygen و طرفموجب
+
+57
+00:04:36,040 --> 00:04:43,620
+عند الكربون هذا الطرف الموجب عند الكربون هو أساس
+
+58
+00:04:43,620 --> 00:04:48,710
+الكيميا تبع الكربوني ال compounds كلهايعني دائما
+
+59
+00:04:48,710 --> 00:04:52,230
+لما بدأ أفكر في carbonyl compound بدأ أفكر أنه
+
+60
+00:04:52,230 --> 00:04:57,170
+الرابطة مستقطبة فيها طرف سالب اللي هو ال oxygen
+
+61
+00:04:57,170 --> 00:05:02,110
+وطرف موجب اللي هو ال carbon الآن التفاعل الأساسي
+
+62
+00:05:02,110 --> 00:05:07,310
+هتلاحظوا مركز على هذا الكربون اللي موجود في ال
+
+63
+00:05:07,310 --> 00:05:13,990
+carbonyl compounds طالما هذا الطرف موجب معناه ذلك
+
+64
+00:05:13,990 --> 00:05:16,490
+شو اللي بنتوقع بده يهاجم عليه بعد شو اللي مصير
+
+65
+00:05:16,490 --> 00:05:21,010
+التفاعلات؟إيش يعني سالب؟ Enucleophile عشانك
+
+66
+00:05:21,010 --> 00:05:24,630
+هتلاقوا على ال الديهيدس والكيتونز Enucleophilic
+
+67
+00:05:24,630 --> 00:05:27,050
+addition و هتلاقوا على العائلة التانية
+
+68
+00:05:27,050 --> 00:05:30,850
+Enucleophilic substitution في كل الأحوال طالما هذا
+
+69
+00:05:30,850 --> 00:05:35,810
+موجب اللي بده يهاجم عليه لازم يكون سالب واضح؟
+
+70
+00:05:35,810 --> 00:05:40,150
+بالنسبة لل boiling points طبعا بتلاحظوا أن ال
+
+71
+00:05:40,150 --> 00:05:44,030
+الديهيدس والكيتونز مافيهم hydrogen bonding لأن شرط
+
+72
+00:05:44,030 --> 00:05:49,630
+ال hydrogen bonding أن يكون عندههيدروجين مرتبطة
+
+73
+00:05:49,630 --> 00:05:55,030
+باكسوجين او نيتروجين او فلور واحدة من التلات ذرات
+
+74
+00:05:55,030 --> 00:05:59,790
+الان هنا مافي اشي مرتبط بالاكسوجين ولذلك نقطة
+
+75
+00:05:59,790 --> 00:06:05,470
+غليانهم اقل من الكحولات واضح؟ يعني مثلا الاسيتون
+
+76
+00:06:05,470 --> 00:06:08,810
+اللى هو عبارة عن تلات ذرات كربون وذرة اكسوجين
+
+77
+00:06:08,810 --> 00:06:15,240
+بيغلي عند 56 لو بدى اقارنه بالبروبانولممكن بيغلي
+
+78
+00:06:15,240 --> 00:06:20,840
+بالتسعينات أو جري بالمية، واضح؟ فليش هدول ال
+
+79
+00:06:20,840 --> 00:06:26,180
+aldehydes و ال ketones لهم نقاط غليان أقل من ال
+
+80
+00:06:26,180 --> 00:06:31,080
+alcohols because they don't have hydrogen bonds
+
+81
+00:06:31,080 --> 00:06:37,460
+السليوبيلية بشكل عام ضعيفة جدا في الميه، يعني
+
+82
+00:06:37,460 --> 00:06:40,900
+مافيش غير اللي بنسميهم ال lower aldehydes and
+
+83
+00:06:40,900 --> 00:06:47,260
+ketones تعرف إيش يعني ال lower؟الـ Lower Aldehydes
+
+84
+00:06:47,260 --> 00:06:52,780
+and Ketones اللي هم فيهم عدد كربونات جليل يعني أول
+
+85
+00:06:52,780 --> 00:06:56,380
+Aldehydes و Ketones في السلسلة هدولة اللي بيدوبوا
+
+86
+00:06:56,380 --> 00:07:00,380
+في الميه يعني مثلا ال Acetaldehyde بيدوب في الميه
+
+87
+00:07:00,380 --> 00:07:04,620
+ال Formaldehyde بيدوب في الميه ال Acetone كأبسط
+
+88
+00:07:04,620 --> 00:07:07,560
+Ketone بيدوب في الميه بعد هيك ال R group بتصير
+
+89
+00:07:07,560 --> 00:07:11,200
+كبيرة المركبات مابيدوبوش في الميهيعني اللي بدنا
+
+90
+00:07:11,200 --> 00:07:15,700
+نقول مثلا three-hexanone ولا three-cyclopentanone
+
+91
+00:07:15,700 --> 00:07:19,780
+هذه الكيتونات إذا كبرت خلاص مابتدوب في الميه فبس
+
+92
+00:07:19,780 --> 00:07:23,320
+اللي هم ال low molecular weight species يعني
+
+93
+00:07:23,320 --> 00:07:27,140
+الأشياء اللي ال molecular weight تبعها صغير اللي
+
+94
+00:07:27,140 --> 00:07:31,380
+هم أوائل الألدهيات والكيتون فقط اللي بيدوبوا في
+
+95
+00:07:31,380 --> 00:07:38,500
+الميه بعد ذلك مافيش شيء ذوبانفي الميه لأنه مافيش
+
+96
+00:07:38,500 --> 00:07:44,140
+عنده hydrogen bonding كمان تساعد على الضوابان الان
+
+97
+00:07:44,140 --> 00:07:48,940
+بالنسبة لتسمية هذه المركبات بالنسبة لتسمية هذه
+
+98
+00:07:48,940 --> 00:07:55,060
+المركبات احنا في ال IUPAC Nomenclature اتفقنا ان
+
+99
+00:07:55,060 --> 00:08:02,520
+بناخد اسم ال الكان و بنزيد عليه نهايةيعني مثلا لو
+
+100
+00:08:02,520 --> 00:08:07,860
+فكرنا بذرتين carbon لو فكرنا بذرتين carbon الاصل
+
+101
+00:08:07,860 --> 00:08:12,360
+لما يكون عندى ذرتين carbon ايش المركب اثان اثان
+
+102
+00:08:12,360 --> 00:08:17,020
+okay الان لو صار المركب فيه double bond ايش بيصير
+
+103
+00:08:17,020 --> 00:08:22,340
+اثين اثين لو صار فيه triple bond اثان اثان لو صار
+
+104
+00:08:22,340 --> 00:08:28,890
+فيه OH اثانولواضح فالتغيير في الآخر طيب الأن لو
+
+105
+00:08:28,890 --> 00:08:33,270
+صار في الديهايد و لو صار في المركب بعد هيك كيتون
+
+106
+00:08:33,270 --> 00:08:40,250
+إذا صار في الديهايد بنضيف له النهاية ال فهذا بيصير
+
+107
+00:08:40,250 --> 00:08:46,770
+methanol يبدو للأسف ناقصة كتابة ال a هنا قبل ال L
+
+108
+00:08:49,330 --> 00:08:54,070
+ليش؟ لأنه كم كربونا عندي هنا؟ واحدة كربونا واحدة
+
+109
+00:08:54,070 --> 00:09:00,190
+يعني ميثين الآن لما بيصير الديهايد ميثانال كربونا
+
+110
+00:09:00,190 --> 00:09:08,830
+واحد كربونتين اتين ايثانال تلاتة بروبانال اربعة
+
+111
+00:09:08,830 --> 00:09:15,520
+بيوتانال فال الديهايد بشكل عام تاخد النهاية ALالـ
+
+112
+00:09:15,520 --> 00:09:20,540
+ANL واضح؟ طبعا هذا ما بيمنعش ان المراكبات الصغيرة
+
+113
+00:09:20,540 --> 00:09:25,020
+فيها أسماء شهرة و الناس كتير برات بتتعامل مع أسماء
+
+114
+00:09:25,020 --> 00:09:29,920
+شهرة بتاعتهم يعني الميثانال اسمه formaldehyde
+
+115
+00:09:29,920 --> 00:09:37,000
+الإيثانال هو الacetaldehyde البروبانال بيسموه مرات
+
+116
+00:09:37,000 --> 00:09:38,740
+البروبيونالديهيد
+
+117
+00:09:45,930 --> 00:09:49,590
+البيوتنال بيسموه butyraldehyde
+
+118
+00:09:51,670 --> 00:09:57,070
+و مع الممارسة هتحسوا ان الشغلة مش .. مش هتكون صعبة
+
+119
+00:09:57,070 --> 00:10:02,950
+كتير عليكم الان لو صار على المركب substituents
+
+120
+00:10:02,950 --> 00:10:08,610
+كتيرة انتوا هتلاقوا حالكم ملزمين تلقائيا انكوا
+
+121
+00:10:08,610 --> 00:10:13,230
+تستعملوا ال .. واضح؟
+
+122
+00:10:13,230 --> 00:10:20,330
+يعني لو بنسأل عن مركب وفيه substituentsتلقائيًا
+
+123
+00:10:20,330 --> 00:10:27,050
+تستعمل أي نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+124
+00:10:27,050 --> 00:10:27,770
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+125
+00:10:27,770 --> 00:10:28,010
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+126
+00:10:28,010 --> 00:10:30,450
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+127
+00:10:30,450 --> 00:10:32,690
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+128
+00:10:32,690 --> 00:10:39,530
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+129
+00:10:39,530 --> 00:10:45,770
+نومنكليتشر أيوبك نومنكليتشر أيوبك نشو بدكم تسموه
+
+130
+00:10:45,770 --> 00:10:50,290
+butyraldehyde؟ وقتها لازم تيجي تسمو هذا المركب
+
+131
+00:10:50,290 --> 00:10:57,180
+كمشتقةبيوتنال واضح هنا بتكون تتذكروا القواعد اللي
+
+132
+00:10:57,180 --> 00:11:02,420
+أعطيناكوا إياها حال التقاء أكثر من مجموعة وظيفية
+
+133
+00:11:02,420 --> 00:11:07,000
+من إله أولوية يعني هذا المركب مثلا في مجموعة ال
+
+134
+00:11:07,000 --> 00:11:12,220
+الديهايد وفي مجموعة ال alcohol ال الديهايد أولويته
+
+135
+00:11:12,220 --> 00:11:15,800
+أعلى من ال alcohol عشانك لما تترقب تقول واحد اتنين
+
+136
+00:11:15,800 --> 00:11:21,700
+تلاتةاربع one two three four اذا كام substitute
+
+137
+00:11:21,700 --> 00:11:28,200
+عندى هنا تلتان واضح لما بدى اسم هذا المركب تسمية
+
+138
+00:11:28,200 --> 00:11:34,600
+كاملة شو بدى يصير اسمه two chloro three hydroxy
+
+139
+00:11:34,600 --> 00:11:45,420
+butanate اه two chloro three hydroxy butanate الآن
+
+140
+00:11:45,420 --> 00:11:51,780
+السؤالبيلزم أن أقول one butanane لأن الالدهايد لا
+
+141
+00:11:51,780 --> 00:11:57,530
+تكون إلا طرفية على الموضوع واحدواضح؟ يعني دائما في
+
+142
+00:11:57,530 --> 00:12:00,710
+ال الديهايد بلزم .. أنا قلت هذا المركب الديهايد
+
+143
+00:12:00,710 --> 00:12:05,150
+إذا الـ C double bond O تبعته بتكون طرفية فإذا
+
+144
+00:12:05,150 --> 00:12:09,210
+المركب منسوب لل الديهايد مابلزمش أني أجي أحط one
+
+145
+00:12:09,210 --> 00:12:14,510
+butanol بعد شوية لما ناخد كيتون مثلا 6 كربونات و
+
+146
+00:12:14,510 --> 00:12:17,190
+فيه C double bond O ممكن تكون والله على موقع اتنين
+
+147
+00:12:17,300 --> 00:12:21,700
+ممكن تكون على موقع تلاتة بيصير ملزم ان احدد وين
+
+148
+00:12:21,700 --> 00:12:25,620
+موقع الـ C double bond O في الكيتون لان لو عندي
+
+149
+00:12:25,620 --> 00:12:29,220
+سلسلة طويلة في ال الديهايد دائما بتكون على نمرة
+
+150
+00:12:29,220 --> 00:12:32,420
+واحدة ده ميزة ال الديهايد ان ال C double bond O
+
+151
+00:12:32,420 --> 00:12:36,440
+على نمرة واحدة بس لو صار عندك كيتون بعشر ذرات
+
+152
+00:12:36,440 --> 00:12:39,700
+كربون هل ال C double bond O على موقع اتنين تلاتة
+
+153
+00:12:39,700 --> 00:12:46,250
+اربعة خمسة احنا مش عارفين ولذلكيجب أن نضع أرقام في
+
+154
+00:12:46,250 --> 00:12:50,070
+حالة الـ ketone إذا كان لدينا لبس في موقع المجموعة
+
+155
+00:12:50,070 --> 00:12:54,110
+بس في ال الديهايد عمره لا أحد يحط وان بيوتنال خلاص
+
+156
+00:12:54,110 --> 00:12:57,910
+بيوتنال هي لا تكون إلا على موقع واحد واضح هذه
+
+157
+00:12:57,910 --> 00:13:02,470
+الفكرة؟ سنشوف أمثل إضافية الآن جزء من الاروماتيك
+
+158
+00:13:02,470 --> 00:13:09,950
+كومباونز مر علينا هذا المركب ال pins الديهايدمر
+
+159
+00:13:09,950 --> 00:13:12,610
+علينا و بتعرفوا لو كان في substitution تاني
+
+160
+00:13:12,610 --> 00:13:17,910
+علمناكوا كيف نسميه هذا المركب مثلا هي في aldehyde
+
+161
+00:13:17,910 --> 00:13:23,610
+و OH لمن أولويته في التسمية لل aldehyde اذا انا
+
+162
+00:13:23,610 --> 00:13:29,390
+هرقم منها و همر أسرع ما يمكن على ال OH فبدي يكون
+
+163
+00:13:29,390 --> 00:13:33,990
+المركب 2-hydroxybenzaldehyde
+
+164
+00:13:33,990 --> 00:13:39,350
+يعني لو كتبتوا 2-hydroxybenzaldehyde it's okayالان
+
+165
+00:13:39,350 --> 00:13:43,650
+مرات بيقولوله بنزين carbaldehyde لكن الأشهر بنز
+
+166
+00:13:43,650 --> 00:13:46,830
+aldehyde زي ماذا بيسميه بنز aldehyde هذا two
+
+167
+00:13:46,830 --> 00:13:55,230
+hydroxy benz aldehyde هذا
+
+168
+00:13:55,230 --> 00:14:00,290
+المرتب حاطيله مش عشان تحفظوا شكله بس على أساس
+
+169
+00:14:00,290 --> 00:14:06,190
+تشوفوا ان انا عندى aldehyde و alcohol و مثلو بنزين
+
+170
+00:14:06,190 --> 00:14:12,010
+تقولوا إيش الكيميا هذه في النهاية هذا المركب هو ال
+
+171
+00:14:12,010 --> 00:14:15,850
+vanilla اللي بيعملوا فيها ال cake ال vanilla اللي
+
+172
+00:14:15,850 --> 00:14:19,690
+بيعملوا فيها ال cake الأن لو مجموعة ال aldehyde ..
+
+173
+00:14:19,690 --> 00:14:23,670
+لو مجموعة ال aldehyde إجت على حلقة و بدي أسميها
+
+174
+00:14:23,670 --> 00:14:30,800
+كمجموعة يعني هذه كلها Cyclopentaneمظبوط ولا لأ؟ لو
+
+175
+00:14:30,800 --> 00:14:33,960
+كان ديهايد و بعد شوية لما يجيني أسد بنقول
+
+176
+00:14:33,960 --> 00:14:37,840
+Cyclopentane و بالصيغة بالبندق OH لما بتيجي كلها
+
+177
+00:14:37,840 --> 00:14:42,020
+كمجموعة ملتصقة بالحلقات خمسية سدسية واطفات بنقول
+
+178
+00:14:42,020 --> 00:14:47,240
+عنها carbaldehyde يعني هذه الأن أصبحت كأنها مجموعة
+
+179
+00:14:47,240 --> 00:14:54,140
+ملتصقة بcyclopentane فهذا المركب اللي همنن نسميه
+
+180
+00:14:54,140 --> 00:15:01,120
+بنقول Cyclopentaneوهذه المجموعة
+
+181
+00:15:01,120 --> 00:15:11,060
+كرب أنديهيد بيصير كله Cyclopentane Carbohydrate من
+
+182
+00:15:11,060 --> 00:15:19,680
+وين ال Clor؟ لو حطيت هنا Clor، هاي واحد، اتنين،
+
+183
+00:15:19,680 --> 00:15:25,880
+تلاتة الأولوية لل Carbohydrateثلاثة كلورو
+
+184
+00:15:25,880 --> 00:15:32,440
+سايكلوبنتين كربالديهيد وين ال double bond؟ بتصير
+
+185
+00:15:32,440 --> 00:15:40,800
+سايكلوبنتين و بنحدد موقع ال double bond ببدأ
+
+186
+00:15:40,800 --> 00:15:43,920
+من عند ال aldehyde ببدأ من عند ال aldehyde one
+
+187
+00:15:43,920 --> 00:15:46,860
+واضح؟ ببدأ ال one من عند ال aldehyde يعني لو
+
+188
+00:15:46,860 --> 00:15:50,460
+double bond هنا بقول one, two, three و بمشي بهذا
+
+189
+00:15:50,460 --> 00:15:55,500
+الشكل واضح؟ بنبدأ من عند ال aldehydeبيصير
+
+190
+00:15:55,500 --> 00:16:01,820
+Cyclopentene Carb Antihydrate و بنحدد موقع double
+
+191
+00:16:01,820 --> 00:16:07,220
+bond بنحدد موقع double bond الان
+
+192
+00:16:07,220 --> 00:16:14,940
+بالنسبة لكيتون افضل كيتون من تلت ذرات كربون اللي
+
+193
+00:16:14,940 --> 00:16:23,120
+هو Evropanol بنحط النهاية ايش للكيتون onكل مراكبات
+
+194
+00:16:23,120 --> 00:16:26,200
+الكيتون لما بتعبر عنها بال أيو بكنوميكليتشار هذا
+
+195
+00:16:26,200 --> 00:16:30,820
+السطر اللي فوق في كل المراكبات هو تعبير عن ال أيو
+
+196
+00:16:30,820 --> 00:16:35,640
+بكنوميكليتشار بنحط نهاية on طبعا هذا البروبانون
+
+197
+00:16:35,640 --> 00:16:39,220
+اسمه أسيتون ممكن بعض يقول ليش ما سمناه two
+
+198
+00:16:39,220 --> 00:16:43,000
+-probanon على أساس ان ال on ع موقع اتنين هو طالما
+
+199
+00:16:43,000 --> 00:16:48,420
+كيتون طالما كيتون مافيش إله الاحتمال واحد دائما
+
+200
+00:16:48,420 --> 00:16:51,260
+الأرقام وانتش احنا بنحطها
+
+201
+00:16:53,240 --> 00:16:59,500
+إذا صار عنده أكثر من احتمال دائما الأرقام بتلحط
+
+202
+00:16:59,500 --> 00:17:02,580
+إذا في عنده أكثر من احتمال عشان هي اللي بيكون
+
+203
+00:17:02,580 --> 00:17:06,300
+لحاله ومافيش احتمالات كتيرة مابياخدش أرقام يعني
+
+204
+00:17:06,300 --> 00:17:12,420
+أعطيكوا مثال في القردن مثلا الملك عبدالله بيكون
+
+205
+00:17:12,420 --> 00:17:19,710
+أبوه ولا سيده للملك حسين؟ لأ طبعا سيدهلأ الملك عبد
+
+206
+00:17:19,710 --> 00:17:23,650
+الله سيده للملك إحسين، الملك الحسين ابنه طلال، بس
+
+207
+00:17:23,650 --> 00:17:28,810
+أبوه طلال ماخلهوش ياخد الحكم غير حوالي كام من شهر
+
+208
+00:17:28,810 --> 00:17:32,510
+و بعدين شلوه و حطوا للملك إحسين بداله، كان اسمه بس
+
+209
+00:17:32,510 --> 00:17:37,290
+الملك عبد الله، ليش؟ لأنه مافيش منافس تاني، الآن
+
+210
+00:17:37,290 --> 00:17:42,130
+لما إجه حفيدهبعد ذلك سنقول عبدالله الثاني وقت انا
+
+211
+00:17:42,130 --> 00:17:46,890
+بدأت استعمل الأرقام إذا صار في عندى احتمال اللبس
+
+212
+00:17:46,890 --> 00:17:50,110
+واضح؟ الان هنا مافيش غير موقع واحد تيجي فيه الـ C
+
+213
+00:17:50,110 --> 00:17:53,770
+double bond وعشان يبين كيتون ولذلك مش كتير مهم
+
+214
+00:17:53,770 --> 00:17:59,610
+اكتب to Probanon لكن مثلا هذا المركب اللى هنا لو
+
+215
+00:17:59,610 --> 00:18:05,750
+بتطلعى 1,2,3,4,5 كم احتمال ممكن يكون فيه كيتون في
+
+216
+00:18:05,750 --> 00:18:11,970
+هذا المركب؟ لابس احتمالين، لاحظوا الـ c double
+
+217
+00:18:11,970 --> 00:18:17,330
+bond إذا إجت على أول موقع فمركبه الدماغ، إذا إجت
+
+218
+00:18:17,330 --> 00:18:23,870
+على الموقع التاني two pentanol، إذا إجت على الموقع
+
+219
+00:18:23,870 --> 00:18:28,760
+الثالث3 pentanone إذا أتيت عن موقع هذا اللي هنا
+
+220
+00:18:28,760 --> 00:18:32,980
+بتصير 2 pentanone من الجهة التانية لأنه دائما لازم
+
+221
+00:18:32,980 --> 00:18:36,960
+ناخد أقل ترقيم مابتتصلش أربعة pentanone لأنه لو
+
+222
+00:18:36,960 --> 00:18:40,680
+عديت واحدة منها واحد اتنين بترجع يشتوق pentanone
+
+223
+00:18:40,680 --> 00:18:46,120
+في هذه الحالة أنا ملزم أن أحط أرقام لأن في عندي
+
+224
+00:18:46,120 --> 00:18:50,560
+خوف في هذه الحالة مثلا في الأربع ذرات كربون هل أنا
+
+225
+00:18:50,560 --> 00:18:57,090
+كتير ملزم أن أحط أرقاملما أقول butanol، أساسا
+
+226
+00:18:57,090 --> 00:18:59,510
+مافيش شيء، لو هنا اتنين وهنا اتنين، يعني هذا
+
+227
+00:18:59,510 --> 00:19:04,550
+محطوطة في النهاية زيادة، واضح؟ احنا مش كتير بنحاسب
+
+228
+00:19:04,550 --> 00:19:08,570
+لما طالبة تحطها بزيادة، لكن الخلاصة أن الشيء
+
+229
+00:19:08,570 --> 00:19:14,460
+الواضح، اللي مافيش فيه منافسة، يمكن أن يُتركالان
+
+230
+00:19:14,460 --> 00:19:18,660
+مرات هذه الـ Ketones بيسموها common names كيف
+
+231
+00:19:18,660 --> 00:19:22,500
+بيسموها common names؟ بيجوا جنب الـ CWO و بياخدوا
+
+232
+00:19:22,500 --> 00:19:26,220
+المجموعات اللي محوطين، هذه مجموعة و هذه مجموعة هذه
+
+233
+00:19:26,220 --> 00:19:28,840
+المجموعة اللي هنا على اليمين أو على الشمال، شو
+
+234
+00:19:28,840 --> 00:19:35,520
+اسمها؟ carbon-10-ethyl، هذه مثل، فالمراكب بنسميه
+
+235
+00:19:35,520 --> 00:19:41,990
+Ethyl Methyl Ketoneواضح اثل مثل كيتون لو هذا بدنا
+
+236
+00:19:41,990 --> 00:19:47,970
+نتطلع مثلا هذه المجموعة اثل وهذه المجموعة اثل فهذا
+
+237
+00:19:47,970 --> 00:19:53,510
+بيسموه داي اثل كيتون داي اثل كيتون هذا نوع من ال
+
+238
+00:19:53,510 --> 00:19:56,750
+common nomenclature نوع من ال common nomenclature
+
+239
+00:19:56,750 --> 00:19:58,970
+اللي هي التسمية الشعبية
+
+240
+00:20:01,360 --> 00:20:08,020
+الأساس في تسمية ال الديهيدز حرفين والأساس في تسمية
+
+241
+00:20:08,020 --> 00:20:13,960
+ال ketones تلت حروف ال الديهيدز لما بنسميه بنضيف
+
+242
+00:20:13,960 --> 00:20:17,840
+نهاية A لل ketones on
+
+243
+00:20:20,550 --> 00:20:25,690
+on واضح؟ إذا كل مركب حتشوفه نهايته ال إذا هو
+
+244
+00:20:25,690 --> 00:20:31,990
+الديهايد والنهايته on إذا هو كيتون هنا مثلا هذا
+
+245
+00:20:31,990 --> 00:20:39,210
+المركب Cyclohexane بيصير Cyclohexanone بيلزم نيجي
+
+246
+00:20:39,210 --> 00:20:45,630
+نقول one Cyclohexanone؟ مابيلزم لأن كل المواقع في
+
+247
+00:20:45,630 --> 00:20:51,560
+Cyclohexane تعتبر مواقع متساويةهذا الـ Ketone
+
+248
+00:20:51,560 --> 00:20:56,200
+أخدتوله اسم انتوا لما تكون مجموعة الاسيتا على
+
+249
+00:20:56,200 --> 00:21:02,520
+البنزين سمناه اسيتوفينون وممكن نسميه برضه على أساس
+
+250
+00:21:02,520 --> 00:21:06,040
+أن هذا كيتون، هاي مجموعة أو هاي مجموعةماذا يسمى
+
+251
+00:21:06,040 --> 00:21:12,420
+هذه المجموعة؟ فنل فبصير مثل فنل كيتون أو لأن كل
+
+252
+00:21:12,420 --> 00:21:17,540
+هذه المجموعة أسيتل بيصير أسيتوفيلون أخدناها في
+
+253
+00:21:17,540 --> 00:21:22,920
+الاروماتيك كومباونز أسيتوفيلون المركب هذا الداي
+
+254
+00:21:22,920 --> 00:21:24,060
+فنل كيتون
+
+255
+00:21:28,880 --> 00:21:33,840
+Diphenylketone برضه بياخد اسم شهرة بنزوفينون هو
+
+256
+00:21:33,840 --> 00:21:37,200
+يعامل ك أيوبك حتى بنزوفينون خلاص يعني بيصيروا
+
+257
+00:21:37,200 --> 00:21:43,160
+عارفينه إيش اسمه بنزوفينون إذا بنزوفينون
+
+258
+00:21:43,160 --> 00:21:47,180
+أسيتوفينون كل المركبات هذه عبارة عن يعني خليني
+
+259
+00:21:47,180 --> 00:21:53,120
+أقول simple compounds مافيش فيها substitute
+
+260
+00:21:55,560 --> 00:21:58,680
+يعني تغلب في التسميه مافيش فيها substituency تغلب
+
+261
+00:21:58,680 --> 00:22:04,700
+في التسميه لكن احنا بالتأكيد بإمكاننا الآن نعطي
+
+262
+00:22:04,700 --> 00:22:08,920
+مركبات أعقد بتحتوي على أكثر من مجموعة وظيفية
+
+263
+00:22:08,920 --> 00:22:12,680
+ونقولكوا كيف بنسميها ومن أمثال هذه المركبات احنا
+
+264
+00:22:12,680 --> 00:22:16,320
+لو كنا بدنا نسأل في الامتحان يعني هذه كلها تعتبر
+
+265
+00:22:16,320 --> 00:22:21,660
+مقدمة الخلاصة عشان نذكركم قولنا النهاية قال
+
+266
+00:22:26,730 --> 00:22:30,930
+الأولويات إذا التقت في الجزء أكتر من مجموعة
+
+267
+00:22:30,930 --> 00:22:36,970
+الألكيين أقل من الألكيين أقل من الالكول أقل من
+
+268
+00:22:36,970 --> 00:22:41,280
+الكيتونأقل من ال الديهايد، أقل من الاسد، أقل من ال
+
+269
+00:22:41,280 --> 00:22:46,760
+إيستر يعني الجزء لو التقف فيه كيتون مع الديهايد
+
+270
+00:22:46,760 --> 00:22:51,020
+الأولوية لمن؟ لل الديهايد، بداية الترقيم من أين؟
+
+271
+00:22:51,020 --> 00:22:59,300
+نهاية الإسم ال مش on، لما المركب يكون في ال و on،
+
+272
+00:22:59,300 --> 00:23:07,070
+نهايته ال ال و all القال يعني الديهايد و all
+
+273
+00:23:07,070 --> 00:23:12,230
+الكهول قال و all يعني زي هذا المركب لو حطيناها
+
+274
+00:23:12,230 --> 00:23:16,230
+نقاش طبعا لاحظوا أكيد كلكم مش لازم تقلطوا على
+
+275
+00:23:16,230 --> 00:23:18,930
+الغلطة لما هذا أنا أكون سايبها مش كاتب فيها إشي
+
+276
+00:23:18,930 --> 00:23:24,630
+إيش معناها CH3 في ناس كتير للأسف بيقلطوا يعني في
+
+277
+00:23:24,630 --> 00:23:28,710
+الامتحان اللي عملوا بصلحوا عندكم مركب بنتين يمكن
+
+278
+00:23:28,710 --> 00:23:32,030
+تلت بنات كاتبين بنتين رغم إن كلكم بنات كلكم
+
+279
+00:23:32,030 --> 00:23:37,780
+عاملينه بيوتينطب مبين فيه خمس كربونات واضح يعني
+
+280
+00:23:37,780 --> 00:23:41,880
+هذا لما بتعده هذي كربونا طالما انا اتركها مش كاتب
+
+281
+00:23:41,880 --> 00:23:45,860
+جنبها H بتظهر كربونا لكن في مثل هذه الحالة بتصير
+
+282
+00:23:45,860 --> 00:23:51,880
+ايش الان لو بدنا نسمي هذا المركب ايش اللي موجود
+
+283
+00:23:51,880 --> 00:23:57,300
+عندى هنا الديهايد و كلوروميثيل بيظهر للاصل
+
+284
+00:23:57,300 --> 00:24:04,450
+الديهايد واحد اتنين تلاتة اربع اذا هذابيوتانال
+
+285
+00:24:04,450 --> 00:24:05,770
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+286
+00:24:05,770 --> 00:24:09,670
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+287
+00:24:09,670 --> 00:24:14,690
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+288
+00:24:14,690 --> 00:24:15,130
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+289
+00:24:15,130 --> 00:24:15,170
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+290
+00:24:15,170 --> 00:24:15,190
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+291
+00:24:15,190 --> 00:24:15,190
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+292
+00:24:15,190 --> 00:24:15,190
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+293
+00:24:15,190 --> 00:24:22,210
+بيوتانال بيوتانال بيوتانال بيوتان
+
+294
+00:24:24,200 --> 00:24:29,380
+طبعاً بدنا نشوف أقل ترقيم يعني إذا قدنا 1,2,3,4,1
+
+295
+00:24:29,380 --> 00:24:34,020
+,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2
+
+296
+00:24:34,020 --> 00:24:35,460
+,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3
+
+297
+00:24:35,460 --> 00:24:35,460
+,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4
+
+298
+00:24:35,460 --> 00:24:40,120
+,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,لما كان
+
+299
+00:24:40,120 --> 00:24:45,440
+عندى هنا ال ماحطتش رقم هي دائما و أبدا واحد لكن
+
+300
+00:24:45,440 --> 00:24:51,200
+لما كان عندى on حددت ال on ايش هي ال on وين موقعها
+
+301
+00:24:51,200 --> 00:24:56,340
+جاى على موقع تلاتة وعلى اتنين و أربعة ايش عندكم
+
+302
+00:24:56,340 --> 00:25:01,320
+دايمثل اذا هذا المركب two four dimethyl three
+
+303
+00:25:01,320 --> 00:25:07,840
+hexanol واضح الان هذا المركب ايش اللى بيلتقى فيه
+
+304
+00:25:08,300 --> 00:25:13,780
+acid و .. وين ال acid احنا أخدنا ال acid جيبنا
+
+305
+00:25:13,780 --> 00:25:20,120
+سيرة ال acid ال acid لما يكون من نفس الكربونة طالع
+
+306
+00:25:20,120 --> 00:25:25,820
+استيظة بال bond O و ال OH و هذا موضوع chapter 10
+
+307
+00:25:25,820 --> 00:25:30,180
+احنا ولا جيبنا سيرته استيظة بال bond O و ال OH لما
+
+308
+00:25:30,180 --> 00:25:34,800
+يكونوا طالعين من نفس الكربونة بنحكي عن acid الان
+
+309
+00:25:34,800 --> 00:25:39,750
+هذولا من الكربوناتمختلفة هذا مش asset إطلاقا هذا
+
+310
+00:25:39,750 --> 00:25:46,770
+مركب فيه own و own الأولوية له ال own إذا نهاية
+
+311
+00:25:46,770 --> 00:25:51,150
+المركب own والترقيم بيمور أسرع ما يمكن على ال seed
+
+312
+00:25:51,150 --> 00:25:54,350
+of ال bond أو ال ketone كتابة ال ketone one two
+
+313
+00:25:54,350 --> 00:26:00,890
+three four five إذا هذا عبارة عن two بالتنون ال
+
+314
+00:26:00,890 --> 00:26:08,720
+two بتحدد موقع ال ownموقع الكيتون وإيش جاي فيه على
+
+315
+00:26:08,720 --> 00:26:17,760
+موقع أربعة for hydroxy-2-bentanone for hydroxy-2
+
+316
+00:26:17,760 --> 00:26:22,620
+-bentanone لان التقاء الكحول مع الكيتون الأولوية
+
+317
+00:26:22,620 --> 00:26:29,360
+فيه بالترقيم التسمية للكيتون المثال اللي بعيد
+
+318
+00:26:29,360 --> 00:26:37,230
+عبارة عن التقاءالدهايدو كيتون خليني بس أنوح هنا
+
+319
+00:26:37,230 --> 00:26:46,170
+لنقطة ال OH ال OH لما تكون مجموع مركب يعني المركب
+
+320
+00:26:46,170 --> 00:26:50,870
+كله منسوب إليها هي شو بيصير؟ بيقول عنها هيدروكسي
+
+321
+00:26:50,870 --> 00:26:57,520
+إذا أناالـ OH بتعامل معها بمسمى Hydroxy إذا أصبحت
+
+322
+00:26:57,520 --> 00:27:02,940
+مجموعة لكن إذا المركب منسوب إلها بيكون كل المركب
+
+323
+00:27:02,940 --> 00:27:13,140
+نهايته O الـ A هيجيبنا الكلام نفسه مع الـ C double
+
+324
+00:27:13,140 --> 00:27:19,820
+bond O الـ C double bond O لو كانت الديهيد بتكون
+
+325
+00:27:21,010 --> 00:27:27,510
+أقل، لو كانت كيتون All، الآن، لو في أعلى منها،
+
+326
+00:27:27,510 --> 00:27:31,790
+هترجع مجموعة،
+
+327
+00:27:31,790 --> 00:27:35,970
+واضح؟ يعني لو إنه كان مع acid، وعنكم C double bond
+
+328
+00:27:35,970 --> 00:27:40,610
+O كيتونية و C double bond O كمان، تبعت aldehyde،
+
+329
+00:27:40,610 --> 00:27:45,970
+بس أنا اللي عنديا acid، هيرجعوا لاسمهم الأصلي، شو
+
+330
+00:27:45,970 --> 00:27:54,410
+اسمهم الأصلي؟ Oxoأكزو من الـ Oxygen واضح؟ بناء على
+
+331
+00:27:54,410 --> 00:27:57,790
+ذلك لما طلع هذا المُركّب هاي الالديهيد وهي الكيتون
+
+332
+00:27:57,790 --> 00:28:02,970
+الالديهيد كان جنبه H مُركّبي بأنسبه لإيش؟
+
+333
+00:28:02,970 --> 00:28:07,850
+للالديهيد الالديهيد أقوى من الكيتون مُركّبي بأنسبه
+
+334
+00:28:07,850 --> 00:28:14,190
+للالديهيد إذا نهاية مُركّبي ال .. واضح؟ إذا هنا
+
+335
+00:28:14,190 --> 00:28:19,770
+بعد واحد اتنين تلاتة أربعة هذا المُركّب بيوتهالان
+
+336
+00:28:19,770 --> 00:28:23,830
+هذا
+
+337
+00:28:23,830 --> 00:28:29,370
+الـ butanol على موقع تلاتة بيحمل الـ C double bond
+
+338
+00:28:29,370 --> 00:28:34,330
+O هنا بطلت كيتون لأنه خلاص هو المُركّب بيُنسب
+
+339
+00:28:34,330 --> 00:28:38,550
+لمجموعة وظيفية واحدة نصف ال الديهايد خلصت إذن هنا
+
+340
+00:28:38,550 --> 00:28:42,630
+ال C double bond O رجعت لأصل اسمها ايش أصل اسمها
+
+341
+00:28:42,630 --> 00:28:50,490
+اقزو اقزوواضح؟ أصلها أوكزو فبصير هذا three
+
+342
+00:28:50,490 --> 00:28:58,070
+-oxobutanol واضح؟
+
+343
+00:28:58,070 --> 00:29:01,170
+كذلك الحال لو بعد شوية مثلا باخد acid ومعه
+
+344
+00:29:01,170 --> 00:29:05,450
+aldehyde مركب يحب يقول عنه acid ال aldehyde شو
+
+345
+00:29:05,450 --> 00:29:12,200
+هتصير اسمها؟ أوكزو، هنبطل نقول عنها الفإذا أصبحت
+
+346
+00:29:12,200 --> 00:29:16,200
+الـ C double bond O عبارة عن مجموعة عادية المركب
+
+347
+00:29:16,200 --> 00:29:21,180
+مش منسوب إلها بنعبر عنها F-oxo و الـ OH إذا كان
+
+348
+00:29:21,180 --> 00:29:27,460
+المركب مش منسوب إلها بنسميها Hydroxy واضح؟ المركب
+
+349
+00:29:27,460 --> 00:29:32,040
+اللي بعد مين تحكيلنا عنه؟ تتأملوا فيه هيك شوية إيش
+
+350
+00:29:32,040 --> 00:29:38,220
+اللي موجود في هذا آخر مركب؟ كيتون و إيش؟ مؤلقين
+
+351
+00:29:40,460 --> 00:29:44,360
+كيتون و ألكين الكيتون أقوى من الألكين إذا هو
+
+352
+00:29:44,360 --> 00:29:51,360
+كعائلة آخر إشي بده يظهر في اسمه الـ on والترقيم
+
+353
+00:29:51,360 --> 00:29:57,940
+بده يمر أسرع ما يمكن برضه على ال on عن كيتون لما
+
+354
+00:29:57,940 --> 00:30:04,060
+نيجي نقول one two three four five six هذا عبارة عن
+
+355
+00:30:04,060 --> 00:30:13,080
+هكسانون الآن هذا الهكسانون واحد منه صارفبصير هي
+
+356
+00:30:13,080 --> 00:30:17,920
+موقعها بالرقم و ال double point كان ممكن تكون هان
+
+357
+00:30:17,920 --> 00:30:22,740
+او هان او هان اذا يجب تحديد نقطة بدايتها كمان
+
+358
+00:30:22,740 --> 00:30:27,740
+بالرقم ايش نقطة بدايتها هاد ال double point تلاتة
+
+359
+00:30:27,740 --> 00:30:34,560
+اذا هنا يجب نقطة او نقطة نقطة نقطة نقطة نقطة نقطة
+
+360
+00:30:34,560 --> 00:30:40,600
+نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة
+
+361
+00:30:40,600 --> 00:30:42,050
+نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطةثالث
+
+362
+00:30:42,050 --> 00:30:47,790
+ثالث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث
+
+363
+00:30:47,790 --> 00:30:47,790
+ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث
+
+364
+00:30:47,790 --> 00:30:54,010
+ثلاث ثلاث ثلاث تلات تلات تلات تلات تلات تلات تلات
+
+365
+00:30:54,010 --> 00:30:56,550
+تلات تلات تلات تلات تلات تلات تلات تلات تلات تلات
+
+366
+00:30:56,550 --> 00:30:56,830
+تلات تلات تلات تلات تلات تلات تلات تلات تلات تلات
+
+367
+00:30:56,830 --> 00:30:56,830
+تلات تلات تلات تلات تلات تلات تلات تلات تلات تلات
+
+368
+00:30:56,830 --> 00:31:04,690
+تلات تلات تلات تلات تلات تلات توانقولكوا ارسمولنا
+
+369
+00:31:04,690 --> 00:31:09,970
+هذا المُركّب، بتحطوا 6 carbonate، بعدين هتيجوا على
+
+370
+00:31:09,970 --> 00:31:21,090
+موقع 2، تحطوا on، وعلى موقع 3، تحطوا double
+
+371
+00:31:21,090 --> 00:31:23,490
+bond، واضح؟
+
+372
+00:31:36,430 --> 00:31:41,810
+في هذا الـ slide عندكم مجموعة برضه إضافية من
+
+373
+00:31:41,810 --> 00:31:47,250
+الأمثلة خلّينا نقول أمثلة إثرائية حتى يعني تتقنوا
+
+374
+00:31:47,250 --> 00:31:52,370
+موضوع التسمية بشكل كبير لأنه أول ما بتكونوا
+
+375
+00:31:52,370 --> 00:31:55,450
+تتعاملوا مع عائلة إذا بتعرفوش يتسموها كيف بتكونوا
+
+376
+00:31:55,450 --> 00:32:00,130
+تتعاملوا معها؟ مظبوط ولا لا؟ لازم نكون نتقن موضوع
+
+377
+00:32:00,130 --> 00:32:05,710
+التسمية إذا مرّينا عليهم بسرعة المركب الأول
+
+378
+00:32:06,820 --> 00:32:12,380
+بيوتانال مر علينا او butyraldehyd مظبوط ولا لا
+
+379
+00:32:12,380 --> 00:32:18,240
+المركب الثاني لاحظوا فيه الديهيدر كو أتش تري
+
+380
+00:32:18,240 --> 00:32:27,360
+هيدروكسي بيوتانال الان في تسمية قديمة مرات بتمر
+
+381
+00:32:27,360 --> 00:32:34,780
+معاكم من باب التاريخ لأن المشكلة انه مرات لازم
+
+382
+00:32:34,780 --> 00:32:42,690
+تعرفوايعني الأسماء زي ما كانت يعني تذكر ملزمين
+
+383
+00:32:42,690 --> 00:32:46,990
+أنتوا تعرفوها، يعني مثلا لما ييجوا يقولوا شيخ
+
+384
+00:32:46,990 --> 00:32:49,930
+الإسلام، يعني أنتوا بتقراوا كان اتلاقوا واحد قال
+
+385
+00:32:49,930 --> 00:32:54,630
+وقال شيخ الإسلام في هذه المسألةإذا كنتوا ما
+
+386
+00:32:54,630 --> 00:32:59,910
+بتعرفوش إنه ابن تيمية هتتغلبوا، مظبوط ولا لأ؟ إذا
+
+387
+00:32:59,910 --> 00:33:04,890
+ما بتعرفوش إنه ابن تيمية هتتغلبوا أو واحد شاعر
+
+388
+00:33:04,890 --> 00:33:10,390
+شعبي مثلا كتير وفي الشعر الشعبي تبعه وقال الختيار
+
+389
+00:33:10,390 --> 00:33:15,790
+وقال .. شو يعني الختيار؟ إذا ما بتعرفوش هذه
+
+390
+00:33:15,790 --> 00:33:20,470
+الأشياء مش هتمشي الدنيا معكم إذا لو شغلة سمت بميت
+
+391
+00:33:20,470 --> 00:33:26,390
+تسميةانتم مضطرين تعرفوا الميتة اسمها يعني لو واحد
+
+392
+00:33:26,390 --> 00:33:31,370
+ايجيه جالي الختيار، شو بتقوله؟ وده جالي الياسر وده
+
+393
+00:33:31,370 --> 00:33:36,320
+جالي الكاسرمش بيقولوا الياسر، الكاسر، أبو عمار،
+
+394
+00:33:36,320 --> 00:33:41,200
+الختيار، عرفات كل هذه الأسماء المفروض تكون عندكم
+
+395
+00:33:41,200 --> 00:33:45,080
+في ذهنكم أن هي تعبير عن نفس الشخص الآن قولوا ليش
+
+396
+00:33:45,080 --> 00:33:50,100
+بتسمى الأشي بأكثر من اسم هذا حال الدنيا يعني هذا
+
+397
+00:33:50,100 --> 00:33:54,060
+نوع من خلينا أقول التاريخ بس المفروض الواحد يعرفه
+
+398
+00:33:54,060 --> 00:33:59,560
+الآن زمان كانوا يسموا .. يحددوا مواقع المجموعات
+
+399
+00:33:59,560 --> 00:34:05,030
+الإضافية مش بأرقاممش بأرقام يعني هنا أنا لما بتعمل
+
+400
+00:34:05,030 --> 00:34:08,490
+نظام الترقيم ولا أسهل منه في ال IOPAC هذا الكلام
+
+401
+00:34:08,490 --> 00:34:12,570
+صحيح هاي واحد اتنين تلاتة أربعة و ال OH هذه اللي
+
+402
+00:34:12,570 --> 00:34:16,690
+عاملها لمشكلة وين جاية؟ ع موقع تلاتة قولت three
+
+403
+00:34:16,690 --> 00:34:21,370
+hydroxybutanol في نظام تاني كان يستعمل كان يقولوا
+
+404
+00:34:21,370 --> 00:34:25,990
+سيبوا المجموعة الأصلية اللي هيالـ C double bond O
+
+405
+00:34:25,990 --> 00:34:29,770
+سيبوا المجموعة الأصلية الـ C double bond O و ابدوا
+
+406
+00:34:29,770 --> 00:34:34,330
+اعطوا حروف من بعدها لاتينية Alpha, Beta, Gamma,
+
+407
+00:34:34,390 --> 00:34:38,450
+Delta واضح بعد الـ C double bond O الان اذا
+
+408
+00:34:38,450 --> 00:34:42,270
+اعطيتها انا Alpha وانا Beta وين جاية الـ OH على
+
+409
+00:34:42,270 --> 00:34:47,270
+موقع Beta فكانوا يقولوا Beta Hydroxybutyraldehyde
+
+410
+00:34:49,380 --> 00:34:52,800
+common name هذا common name الايوبك بيظله three
+
+411
+00:34:52,800 --> 00:34:56,900
+-hydroxybutanol لكن انتوا لو قرأته beta
+
+412
+00:34:56,900 --> 00:35:01,300
+-hydroxybutyraldehyde بتكون تسيبوا مجموعة الـ C
+
+413
+00:35:01,300 --> 00:35:05,960
+double bond O و تبدأوا تحطوا من بعدها Alpha Beta
+
+414
+00:35:05,960 --> 00:35:11,720
+Delta Gamma بصريش كل الكلام Alpha Beta Gamma Delta
+
+415
+00:35:11,720 --> 00:35:15,540
+Gamma لو اجت هنا نفس الاشي لو اجت هنا واضح
+
+416
+00:35:19,360 --> 00:35:26,940
+هذا المركب ما شاء الله عنه صدقوني
+
+417
+00:35:26,940 --> 00:35:31,860
+مش صعب يعني لو جيبناه في الامتحان و قولنا لوحده
+
+418
+00:35:31,860 --> 00:35:36,180
+فيكوا تحلله ولا إشي تقول هذه المجموعة إيش اسمها؟
+
+419
+00:35:36,180 --> 00:35:41,820
+فنل و هذه المجموعة؟ أكلور و هذا C double bond O
+
+420
+00:35:41,820 --> 00:35:47,380
+aldehyde كام ذرع عندكم؟ اتنين، تلاتة إذا المركب
+
+421
+00:35:47,380 --> 00:35:47,780
+إيه؟
+
+422
+00:35:50,640 --> 00:35:57,120
+بس لإنه في double bond بتبدأ من موقع اتنين إبروبين
+
+423
+00:35:57,120 --> 00:36:02,360
+ال إذا هنا لما أنا أقول ال two إبروبين ال ال two
+
+424
+00:36:02,360 --> 00:36:07,980
+تعبر عن إيش؟ عن موقع ال double bond إن هذا المركب
+
+425
+00:36:07,980 --> 00:36:11,980
+إبروبين ال في double bond و في ال ال مابنسمها
+
+426
+00:36:11,980 --> 00:36:17,640
+ترقيم دائما و أبدا يا مخدر رقم واحد إذا هذه ال two
+
+427
+00:36:17,640 --> 00:36:23,140
+بتحدد لموقع إيش؟بوقع الرابطة الثنائية نهجية على E
+
+428
+00:36:23,140 --> 00:36:28,680
+الان بعد ذلك اتيت عندكم ثلاثة كلورو ثلاثة فينيل
+
+429
+00:36:28,680 --> 00:36:33,120
+ثلاثة كلورو ثلاثة فينيل ثلاثة كلورو ثلاثة كلورو
+
+430
+00:36:33,120 --> 00:36:33,120
+ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو
+
+431
+00:36:33,120 --> 00:36:33,120
+ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو
+
+432
+00:36:33,120 --> 00:36:33,120
+ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو
+
+433
+00:36:33,120 --> 00:36:42,680
+ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو
+
+434
+00:36:50,250 --> 00:36:57,510
+كمجموعة مش مانا متصل C هنا carbon متصل CL متصل
+
+435
+00:36:57,510 --> 00:37:02,070
+carbon إذا المجموعة تلك بار على جهة واحدة فهذا
+
+436
+00:37:02,070 --> 00:37:10,630
+المركب إيش بيصير Z ثلاثة كلوروز ثلاثة كلوروز ثلاثة
+
+437
+00:37:10,630 --> 00:37:12,270
+كلوروز ثلاثة كلوروز ثلاثة كلوروز ثلاثة كلوروز
+
+438
+00:37:12,270 --> 00:37:12,330
+ثلاثة كلوروز ثلاثة كلوروز ثلاثة كلوروز
+
+439
+00:37:16,880 --> 00:37:23,340
+هذا سبوب الأحمر بنزالديهيد على موقع بارا إيش عليه
+
+440
+00:37:23,340 --> 00:37:28,660
+بارا نايترو بنزالديهيد ما تستغربوش إذا لجيتوا في
+
+441
+00:37:28,660 --> 00:37:33,140
+كتاب قديم كاتبه بارا نايترو بنزيل كاربالديهيد
+
+442
+00:37:33,140 --> 00:37:36,700
+بتاية اللي قبل شوية حكيتلكوا عنها لكن الأسهل
+
+443
+00:37:36,700 --> 00:37:45,620
+بنزالديهيد هذا سايكلوبنتين كاربالديهيد
+
+444
+00:37:47,090 --> 00:37:50,570
+مشغولنا لما بيحمل مجموعة الـ C double bond OH
+
+445
+00:37:50,570 --> 00:37:55,510
+بنقول عنها carb-aldehyde هذه المجموعة إذا هي carb
+
+446
+00:37:55,510 --> 00:38:01,050
+-aldehyde وهذا عبارة عن Cyclopentane
+
+447
+00:38:01,050 --> 00:38:04,730
+-carb-aldehyde حامل على موقع اتنين، لاحظوا ترقيمي
+
+448
+00:38:04,730 --> 00:38:07,230
+بدأته من وين؟ من ال الديهايد، إيش حامل على موقع
+
+449
+00:38:07,230 --> 00:38:11,730
+اتنين؟ two ethyl وعمللكوا الأسهم باتجاهكم، إذا
+
+450
+00:38:11,730 --> 00:38:18,380
+التنتين على جهة واحدة من حلقة، إذا مركبة سسواضح؟
+
+451
+00:38:18,380 --> 00:38:22,560
+زي السؤال اللي إجاكمه في الامتحان سيس ولا واحدة
+
+452
+00:38:22,560 --> 00:38:27,720
+جايبها غلط كله جبته صح طبعا هنا
+
+453
+00:38:27,720 --> 00:38:33,620
+الديهايد و الديهايد على الطرفين ضرة تنتين، تلاتة،
+
+454
+00:38:33,620 --> 00:38:39,880
+أربعة، خمسة، بنسميه بنتين دايالمش لو كان OH OH
+
+455
+00:38:39,880 --> 00:38:45,620
+بدنا نقول diol اه هنا الديهايد و الديهايد الديهايد
+
+456
+00:38:45,620 --> 00:38:49,920
+اسمه الشهرة glutaraldehyde ماعناه و ماعناه هدولة
+
+457
+00:38:49,920 --> 00:38:54,400
+كلهم من عيلة ال الديهايد امثلة اثرائية زي ما قولنا
+
+458
+00:38:54,400 --> 00:38:59,000
+هنا الاسيتون او الروبانون اخدناه الاسيتوفينون
+
+459
+00:38:59,000 --> 00:39:06,070
+اخدناهمشتقة Cyclohexanone انتوا المهم تحددوا الاصل
+
+460
+00:39:06,070 --> 00:39:11,210
+تبعه هذا كله مشتقة Cyclohexanone وحطوا واحد اتنين
+
+461
+00:39:11,210 --> 00:39:14,930
+تلاتة اربعة و بعدين اعطوا ارقام هذا Cyclohexanone
+
+462
+00:39:14,930 --> 00:39:21,450
+على ال two في برومو وعلى ال four ديمثل اذا two
+
+463
+00:39:21,450 --> 00:39:28,270
+برومو four four دايمثل Cyclohexanone هذا المركب
+
+464
+00:39:28,270 --> 00:39:32,770
+اللي شايفينه مين تقولي كيف بده تسميه؟بزان بنزين
+
+465
+00:39:32,770 --> 00:39:37,010
+حملة أشياء كتيرة انسوها كبنزين عملوها على أنها
+
+466
+00:39:37,010 --> 00:39:45,310
+مجموعة فنل واعتبروا أن هذا المركب تبعي كام كربونا؟
+
+467
+00:39:45,310 --> 00:39:53,930
+لأ بيجي كمان واحدة هنا عشان تصير أطول سلسلةثلاث
+
+468
+00:39:53,930 --> 00:39:58,990
+كربونات وهذه جاية بين مجموعتين الكل يعتبر اللي
+
+469
+00:39:58,990 --> 00:40:05,910
+عندك كيتون يعتبر اللي عندك كيتون بروبانون الان هنا
+
+470
+00:40:05,910 --> 00:40:10,390
+بينا نقول one two three على ال one في عندنا phenyl
+
+471
+00:40:10,390 --> 00:40:17,330
+وعلى ال two مثل و مثل اذا two two die مثل one
+
+472
+00:40:17,330 --> 00:40:22,770
+phenyl بروبانونتو تو داي مثل وان فيل البروبانون او
+
+473
+00:40:22,770 --> 00:40:30,870
+كان ممكن تقول وان بروبانون مش مشكلة كبيرة هذا
+
+474
+00:40:30,870 --> 00:40:36,330
+المركب one two three four five سايكلو بنتين سايكلو
+
+475
+00:40:36,330 --> 00:40:44,140
+بنتان on on ولا on ondie on اذا هذا بيصير one
+
+476
+00:40:44,140 --> 00:40:48,080
+three ليش؟ لأن ال die on هدولة تنتين ال on وين
+
+477
+00:40:48,080 --> 00:40:52,100
+موجودين؟ ع واحد و تلت اذا هذا one three
+
+478
+00:40:52,100 --> 00:40:58,300
+cyclobentain die on اش
+
+479
+00:40:58,300 --> 00:41:07,000
+عليه غير ال die on؟ two two die مثل عليه two two
+
+480
+00:41:07,000 --> 00:41:16,370
+die مثل نشوف اخر مركبهذه الحلقة عملوها Substitute
+
+481
+00:41:16,370 --> 00:41:21,410
+Cyclobutane هي عندك ذرة تنتين تلاتة هذا المجموعات
+
+482
+00:41:21,410 --> 00:41:27,850
+الوظيفية عليها تلت كربونات شو هما الديهايد
+
+483
+00:41:27,850 --> 00:41:35,550
+وكيتون مركب لإيش بنسبه الديهايد إذا هذا عبارة عن
+
+484
+00:41:35,550 --> 00:41:44,130
+مشتقة Probanal Probanal على موقع تلاتةالسبب اللي
+
+485
+00:41:44,130 --> 00:41:48,510
+بتقولها لما ترجع لأصلها شو اسمها اقزو اذا three
+
+486
+00:41:48,510 --> 00:41:55,770
+oxo-probanal وعلى three أيضا cyclobutyl اذا three
+
+487
+00:41:55,770 --> 00:42:04,150
+oxo-cyclobutyl-probanal three oxo-cyclobutyl
+
+488
+00:42:04,150 --> 00:42:11,880
+-probanal واضح بتيألي هيكلأ بديش أشرح غير التسمية
+
+489
+00:42:11,880 --> 00:42:14,640
+اليوم يعني إذا بدكوا و لابد بعطيكوا مركب أنتوا
+
+490
+00:42:14,640 --> 00:42:22,620
+تسموه لكن أكتر من هيك المرة الجاية هذه ال slide
+
+491
+00:42:22,620 --> 00:42:26,820
+تاب على التسمية هذه ال slide تاب على التسمية لازم
+
+492
+00:42:26,820 --> 00:42:31,660
+نمر عليها بدقيقة انتبهوا معايا اتعلمناهم مثل
+
+493
+00:42:31,660 --> 00:42:35,600
+اثلبروبل ايزوبروبل ترتشر بيوت الواطفار لما أخدنا
+
+494
+00:42:35,600 --> 00:42:43,140
+الالكينزقلنا في عندنا بعض المجموعات الشهيرة الفينل
+
+495
+00:42:43,140 --> 00:42:51,560
+والألل الان في ال .. مجموعات
+
+496
+00:42:51,560 --> 00:42:58,440
+يعني السبب اللي قلت OH كمجموعة
+
+497
+00:42:58,440 --> 00:43:05,310
+بيكون اسمها formalو الـ C double bond O CH3 بيكون
+
+498
+00:43:05,310 --> 00:43:10,870
+اسمها Acetyl و الـ C double bond O Phenyl بيكون
+
+499
+00:43:10,870 --> 00:43:17,570
+اسمها Benzyl لأ مش Benzyl انتبهوا معايا، هذه
+
+500
+00:43:17,570 --> 00:43:22,410
+Benzyl ليش احنا بنركز انها مش Benzyl لأن حقيقة في
+
+501
+00:43:22,410 --> 00:43:26,050
+مجموعة تانية في ال organ ال chemistry اسمها Benzyl
+
+502
+00:43:26,830 --> 00:43:32,550
+واضح؟ المجموعة ال بنزل بنطعم هذه المجموعة اللي هي
+
+503
+00:43:32,550 --> 00:43:39,330
+زي هيك و CH2 هذه المجموعة اسمها بنزل فماحدش خربت
+
+504
+00:43:39,330 --> 00:43:52,630
+كلمة بنزل بنزل وبنزايل وحطيت هنا CH2CL وقلتلكوا
+
+505
+00:43:52,630 --> 00:43:57,980
+سمولي هذا المركببال common nomenclature بنزل
+
+506
+00:43:57,980 --> 00:44:07,540
+إكلورايد لأن هذه المجموعة كلها إسم بنزل بنزل تبني
+
+507
+00:44:07,540 --> 00:44:15,460
+في المركز المركب صوفي برمضان و بارك يعني تبني في
+
+508
+00:44:15,460 --> 00:44:22,260
+المركب المركب الصوفي برمضان و بارك
+
+509
+00:44:24,810 --> 00:44:30,650
+بنزيل بنزيل اكلوراي
+
+510
+00:44:30,650 --> 00:44:37,690
+بالايوباد هلأ
+
+511
+00:44:37,690 --> 00:44:46,070
+مصطلقة إيش؟ مثيل، بس كرمولة واحدة، شو بيحمل
+
+512
+00:44:46,070 --> 00:44:55,520
+المثيل؟ اكلورا ثانل مثيلكأنه أصله CH4 شيلنا H
+
+513
+00:44:55,520 --> 00:45:00,800
+وعطينا Cl وشيلنا H وعطينا Ph إذا هو مشتقة مثيل
+
+514
+00:45:04,270 --> 00:45:10,050
+مثل بنزل إكلورايد فلما نقول بنزل إكلورايد مُركّب و
+
+515
+00:45:10,050 --> 00:45:16,890
+لما نقول بنزايل إكلورايد مُركّب تاني مختلف رجال ما
+
+516
+00:45:16,890 --> 00:45:25,270
+تخلطوش بينهم بنزايل و بنزل مُركّبين مختلفين H
+
+517
+00:45:25,270 --> 00:45:29,770
+-formyl سيضاو المندقو مثل أسيتل و سيضاو بالمندقو
+
+518
+00:45:29,770 --> 00:45:32,390
+فينل بنزايد
+
+519
+00:45:35,400 --> 00:45:39,960
+بهيك بننتهي اليوم في موضوع التسمية
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d07bc2e073f2865b8d7ad8fe8bd93d10f7ea437c
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_postprocess.srt
@@ -0,0 +1,1876 @@
+1
+00:00:07,830 --> 00:00:13,090
+بسم الله الرحمن الرحيم زي ما بتعرفوا احنا بدأنا في
+
+2
+00:00:13,090 --> 00:00:19,470
+الفصل السادس اللي هو كان الكلهيلايتس بشكل أساسي
+
+3
+00:00:19,470 --> 00:00:24,950
+بنحكي عن نوعين من التفاعلات، تفاعلات الإبدال
+
+4
+00:00:24,950 --> 00:00:30,430
+وتفاعلات الحذف، إذا بدي أمر عالسريع معكم مرات
+
+5
+00:00:30,430 --> 00:00:35,070
+الواحد بحب أنه يذكركم بالأشياء اللي حكيناها، ليش؟
+
+6
+00:00:36,210 --> 00:00:41,870
+بنذكر الطلاب بما شرح في محاضرة ربما بدقيقة أو
+
+7
+00:00:41,870 --> 00:00:46,750
+دقيقتين بيحسوا كدهش أنه الموضوع مش صعب لما يُأخذ
+
+8
+00:00:47,480 --> 00:00:52,980
+كصورة كلية احنا اللي حكيناه ان اتعرفنا ببساطة على
+
+9
+00:00:52,980 --> 00:00:57,020
+انواع ال الكلهيلهيتز ال primary و ال secondary و
+
+10
+00:00:57,020 --> 00:01:02,020
+ال tertiary بعد هيك اتعرفنا على قوة الروابط مع ال
+
+11
+00:01:02,020 --> 00:01:06,420
+الكلهيلهيتز قلنا انه اضعف الروابط مع اليود و بعدها
+
+12
+00:01:06,420 --> 00:01:11,200
+مع البروم وبالتالي اكثر رابطة معرضة للكسر و
+
+13
+00:01:11,200 --> 00:01:15,280
+للابدال بسهولة اللي هي مع اليود و بعدها مع البروم
+
+14
+00:01:15,280 --> 00:01:19,790
+اصعب الروابطمع ال floor و لذلك احنا مابندرسش floor
+
+15
+00:01:19,790 --> 00:01:28,430
+يعني هذه شغلة صعبة بعد هيك قلنا انه عشان تم إبدال
+
+16
+00:01:29,250 --> 00:01:33,990
+لازم يكون في عند نيوكليوفايل لأن الكربون مع ال X
+
+17
+00:01:33,990 --> 00:01:36,890
+أو ال carbon مع ال CL اللي بيقارعي ايش الكربون
+
+18
+00:01:36,890 --> 00:01:40,430
+نوعا ما positive ايش اللي بيهاجم على ال positive و
+
+19
+00:01:40,430 --> 00:01:45,170
+يطرد ال X بإلكتروناتها بيكون إما negative أو بيحمي
+
+20
+00:01:45,170 --> 00:01:49,910
+الإلكترونات اللي بنسميه نيوكليوفايل النيوكليوفايل
+
+21
+00:01:49,910 --> 00:01:54,870
+أخدتوا عنها أنه ممكن تكون neutralو ممكن تكون
+
+22
+00:01:54,870 --> 00:01:59,810
+charged لتشارج نيوكليوفايل شحنه سالبة بيجي سالب
+
+23
+00:01:59,810 --> 00:02:05,530
+يدخل على التفاعل و بيطرد X سالب واضح يعني بدخل
+
+24
+00:02:05,530 --> 00:02:11,470
+نيوكليوفايل سالب و بتطلع X سالبة الأمر بسيط الان
+
+25
+00:02:11,470 --> 00:02:15,230
+لنيوترا لنيوكليوفايل بيجي لنيوكليوفايل بيتفاعل و
+
+26
+00:02:15,230 --> 00:02:20,710
+بعد ذلك بيفقد H plus فدائما اللي بيكون عندى كنتج
+
+27
+00:02:20,710 --> 00:02:25,090
+هو لنيوكليوفايل minusH plus يعني لو كان
+
+28
+00:02:25,090 --> 00:02:29,450
+النيكليوفييل مية H2O شو المجبع اللي بده تحطها؟ OH
+
+29
+00:02:29,450 --> 00:02:33,430
+لو كان النيكليوفييل إيثانول إيثل OH شو المجبع اللي
+
+30
+00:02:33,430 --> 00:02:39,090
+بده تحطها؟ إيثل O إيثوكسايد لو كان النيكليوفييل
+
+31
+00:02:39,090 --> 00:02:45,510
+أمونيا and H3شو النيوكليوفايل اللي بتحطها NH2 هي
+
+32
+00:02:45,510 --> 00:02:50,610
+بتتفاعل في مرحلتها الأولى على شكل NH3 ثم مباشرة
+
+33
+00:02:50,610 --> 00:02:56,730
+بتفقد H بلس برضه اتعرفنا انه شيء أساسي عشان نفهم
+
+34
+00:02:56,730 --> 00:03:01,450
+التفاعلات ان نعرف قوة النيوكليوفايل بتكون واجتش
+
+35
+00:03:01,450 --> 00:03:04,830
+strong وواجتش weak قولنا دائما ال charge
+
+36
+00:03:04,830 --> 00:03:08,520
+النيوكليوفايل they are stronger thanالـ neutral
+
+37
+00:03:08,520 --> 00:03:14,340
+ones وقلنا إنه كل ما اتحركنا في الدورة إلى اليسار
+
+38
+00:03:14,340 --> 00:03:18,040
+أو في المجموعة إلى أسفل الـ nucleophilic power
+
+39
+00:03:18,040 --> 00:03:22,500
+بتزيد دائما لما أعمل مقارنة بقارن charged
+
+40
+00:03:22,500 --> 00:03:26,380
+nucleophile مع charged nucleophile أو neutral مع
+
+41
+00:03:26,380 --> 00:03:31,920
+neutral أخدنا أمثلة على أنواع ال nucleophile بمعنى
+
+42
+00:03:31,920 --> 00:03:35,420
+إن ال nucleophile ممكن الذر المهاجمة اللي عليها
+
+43
+00:03:35,420 --> 00:03:41,130
+زوجمن الإلكترونات تكون أكسوجين ممكن تكون نيتروجين
+
+44
+00:03:41,130 --> 00:03:45,970
+ممكن تكون كاربون ممكن تكون سالفر ممكن تكون هالوجين
+
+45
+00:03:45,970 --> 00:03:53,990
+كلهم القاسم المشترك بينهم إيش وجود زوج الإلكترونات
+
+46
+00:03:53,990 --> 00:03:58,410
+واضح؟ ولذلك في النهاية الكيميا مرات كتيرة لما
+
+47
+00:03:58,410 --> 00:04:03,290
+الواحد بده يفهمها بلاحظ إنه كلما تعمق الإنسان في
+
+48
+00:04:03,290 --> 00:04:09,360
+فهم الكيميا بيرجع لإيش؟للإلكترونات لأن الإلكترونات
+
+49
+00:04:09,360 --> 00:04:13,580
+هي اللي بتعمل التفاعلات و الأشياء ولذلك لو يعني
+
+50
+00:04:13,580 --> 00:04:17,640
+شوية صغيرة بدنا نخرج على الموضوع لو كنت تستعرضه
+
+51
+00:04:17,640 --> 00:04:23,240
+تعريف مثلا الأحماض والقواعدأول ما بدوا يعرفوا
+
+52
+00:04:23,240 --> 00:04:27,020
+الحمض والقاعدة Arrhenius قال الحمض اللي بيعطي H
+
+53
+00:04:27,020 --> 00:04:32,100
+plus والقاعدة اللي بتعطي OH minus إجا بعد هيك
+
+54
+00:04:32,100 --> 00:04:35,060
+Laurie Bronsted قال الحمض اللي بيعطي H plus
+
+55
+00:04:35,060 --> 00:04:39,340
+والقاعدة اللي بتكتسب H plus خلاصني من مشكلة OH
+
+56
+00:04:39,340 --> 00:04:44,780
+minus إجا بعدين Lewis لما اتعمق أكتر إيش قال؟الحمض
+
+57
+00:04:44,780 --> 00:04:47,680
+اللي بيكتسب إلكترونات والقاعدة اللي بتعطي
+
+58
+00:04:47,680 --> 00:04:51,060
+إلكترونات فالعلم في قمة التطور وصل لوين؟
+
+59
+00:04:51,060 --> 00:04:55,360
+للإلكترونات فاللي بيفهم هذا القاسم المشترك بيصير
+
+60
+00:04:55,360 --> 00:04:59,240
+الموضوع سهل عليه يعني ممكن واحدة تنظر لجدول زي هذا
+
+61
+00:04:59,240 --> 00:05:04,730
+تقول شو هالمصيبة ويقطع الكيمياوحدة تانية بتقول كل
+
+62
+00:05:04,730 --> 00:05:09,090
+اللي موجود بالجدول هذا هو فكرة واحدة أن أي ذرة
+
+63
+00:05:09,090 --> 00:05:15,210
+عليها زوج من الإلكترونات بسمها نيوكليوفايل بييجي
+
+64
+00:05:15,210 --> 00:05:18,490
+هذا زوج الإلكترونات بيهجم على الكربون و بطرد ال X
+
+65
+00:05:18,490 --> 00:05:22,930
+مع زوج إلكتروناتها إذا هنا أنا صار عند المعادلة
+
+66
+00:05:22,930 --> 00:05:31,390
+العامة اللي هي لنيوكليوفايلمرات بيقولوا Z زوج
+
+67
+00:05:31,390 --> 00:05:35,530
+الإلكترونات كل الفكرة فيه زوج الإلكترونات زائد ال
+
+68
+00:05:35,530 --> 00:05:43,110
+R X ال X سالب ال R موجة وين بدو ييجي السالب هذا
+
+69
+00:05:43,110 --> 00:05:50,270
+بده ييجي هنا يهاجم ويطرد ال X مع الإلكترونات خلصنا
+
+70
+00:05:50,270 --> 00:05:55,260
+كل المعادلات اللي موجودةبتلخصوا بهذه المعادلة
+
+71
+00:05:55,260 --> 00:05:58,640
+العامة كل المعادلات اللي موجودة بيصير عندكم في
+
+72
+00:05:58,640 --> 00:06:06,040
+النهاية RZ زائد X minus واضح فشوفوا كيف لما يصير
+
+73
+00:06:06,040 --> 00:06:08,580
+عندكم قاعدة كلية بيبطل الواحد يخاف ان
+
+74
+00:06:08,580 --> 00:06:12,920
+النيكوليوفايل Oxygen نيتروجين واطبار مش مش المشكلة
+
+75
+00:06:12,920 --> 00:06:19,660
+واضح المهم في النيكوليوفايل وجود زوج الالكترونات
+
+76
+00:06:20,450 --> 00:06:25,590
+هذه ال slide أخدناها برضه إذا بتذكروا و بيكون
+
+77
+00:06:25,590 --> 00:06:29,590
+رجعنا كويس كل اللي أخدتهوا في المحاضرة الماضية أنه
+
+78
+00:06:29,590 --> 00:06:33,270
+لما كان عند ال enucleophile يكون مشحون زي OH-,
+
+79
+00:06:33,270 --> 00:06:41,160
+التفاعل ببساطة بتدخل OH-, تطلع PR-, خلصنالما يكون
+
+80
+00:06:41,160 --> 00:06:46,320
+الـ nucleophile متعدد تدخل الميّه و تصبح PR- بعد
+
+81
+00:06:46,320 --> 00:06:50,520
+ذلك هذا الميّه اللي دخلت هنا ماذا ستفقد؟ هيدروجين
+
+82
+00:06:50,520 --> 00:06:55,400
+هيدروجين عشان تصفؤه H واضح؟ عشان تصفؤه H
+
+83
+00:06:55,400 --> 00:06:59,600
+هالهيدروجين هذا اللي طلعت في الآخر مع ال PR- بتطلع
+
+84
+00:06:59,600 --> 00:07:05,120
+على شكل HBR الان لما أجينا نشرح ال mechanisms أو
+
+85
+00:07:05,120 --> 00:07:12,780
+قليات التفاعلقلنا إنه في عندنا إما ممكن نصنف SN1
+
+86
+00:07:12,780 --> 00:07:19,620
+ميكانيزم أو SN2 ميكانيزم ال SN1 حطنا لها شروط و
+
+87
+00:07:19,620 --> 00:07:26,260
+SN2 حطنا لها شروط شروط ال SN2 كانت عبارة عنstrong
+
+88
+00:07:26,260 --> 00:07:31,040
+nucleophile و primary alkyl halide يعني لما يكون
+
+89
+00:07:31,040 --> 00:07:34,360
+عندي strong nucleophile ال primary alkyl halide
+
+90
+00:07:34,360 --> 00:07:40,920
+غالبا بيصير ميكانيزم مكونة من جزئين يعني ال
+
+91
+00:07:40,920 --> 00:07:45,560
+nucleophile بيهاجم و بيبدأ يعمل رابطة ال PR بتبدأ
+
+92
+00:07:45,560 --> 00:07:48,880
+تنكسر بيصير عندى هذا ال transition state اللي
+
+93
+00:07:48,880 --> 00:07:54,880
+سمناهابـ Intervalent خمسية الإرتباط بعد ذلك يكتمل
+
+94
+00:07:54,880 --> 00:07:58,840
+تكوين هذا الرابط أو يكتمل كسر الـ PR minus طبعاً
+
+95
+00:07:58,840 --> 00:08:02,880
+بتلاحظوا أنه بسرعة ال inversion ولا لأ ال PR كانت
+
+96
+00:08:02,880 --> 00:08:07,700
+باتجاه الـ nucleophile جاء بالاتجاه المعاكس إيش
+
+97
+00:08:07,700 --> 00:08:12,380
+اللي بيسمح لل nucleophile أنه يهاجم Hannah بسهولة؟
+
+98
+00:08:12,880 --> 00:08:17,200
+ووجود وسع انه هذه ال carbon تكون primary لو كان ال
+
+99
+00:08:17,200 --> 00:08:22,580
+tertiary الوسع مغلق مافيش مكان يدخل ال nucleophile
+
+100
+00:08:22,580 --> 00:08:27,360
+من خلاله فأفضل شئ لهذه ال mechanism انه يكون هذا
+
+101
+00:08:27,360 --> 00:08:31,400
+ال nucleophile strong ويلاجى وسع يلاجى primary
+
+102
+00:08:31,400 --> 00:08:33,020
+carbon
+
+103
+00:08:34,870 --> 00:08:39,270
+أعملنا ملحنة طاقة للتفاعل هذه المتفاعلات لـ
+
+104
+00:08:39,270 --> 00:08:42,270
+Transition State Intervalent دائما لـ Transition
+
+105
+00:08:42,270 --> 00:08:49,010
+State الطاقة تبعتها أعلى من ال reactants و ال
+
+106
+00:08:49,010 --> 00:08:53,190
+products بعد ذلك لما تفقد ال PR بيكتمل هنا تكوين
+
+107
+00:08:53,190 --> 00:08:58,310
+الرابطة تكوين الرابطة بيفقد من خلاله طاقة فبينزل
+
+108
+00:08:58,310 --> 00:09:02,030
+التفاعلسواء كان exothermic أو endothermic مش مشكلة
+
+109
+00:09:02,030 --> 00:09:07,610
+كل هذا الكلام تقريبا شرحناه هذه ال slide اللي
+
+110
+00:09:07,610 --> 00:09:11,930
+موجودة عندنا ربما أضفناها مافيش فيها أي إشي غير
+
+111
+00:09:11,930 --> 00:09:17,680
+التأكيد على فكرة أنه لما يكون عندهprimary
+
+112
+00:09:17,680 --> 00:09:23,220
+الكلهيلايد هجوم لليوكليوفايل اللي هنا بين Z مرسوم
+
+113
+00:09:23,220 --> 00:09:27,900
+بالأزرق بيكون أسهل يعني أبسط مثال لو كان عندى مثل
+
+114
+00:09:27,900 --> 00:09:32,080
+برمايد مثلا حيكون عندى اتش و اتش و اتش لاحظوا ال
+
+115
+00:09:32,080 --> 00:09:37,280
+hydrogens ايش حجمهم صغير ففي وسع لل Z تيجي من هنا
+
+116
+00:09:37,280 --> 00:09:41,200
+وهذه تبدأ تطلع فصار في احتمال ان يكون هنا عندى خمس
+
+117
+00:09:41,200 --> 00:09:47,700
+روابطبسهولة في ال transition state طبعا لو صار
+
+118
+00:09:47,700 --> 00:09:52,600
+عندى primary بدى يكون عندى ارتباط مع carbon واحدة
+
+119
+00:09:52,600 --> 00:09:56,720
+برضه ما زال عندى two hydrogens و ال two hydrogens
+
+120
+00:09:56,720 --> 00:10:00,880
+ايش بيكونوا صغار الان لو صار secondary هي
+
+121
+00:10:00,880 --> 00:10:05,080
+secondary هي مرتبطة ب two carbons بدأ يكبر الحجم
+
+122
+00:10:05,080 --> 00:10:09,300
+اللى هنا بتبدأ الزد يصير حواليها ايش نوع من
+
+123
+00:10:09,300 --> 00:10:14,250
+الصعوبة لو صار tertiaryهذه ال carbon بيصير حواليها
+
+124
+00:10:14,250 --> 00:10:18,050
+مثل و مثل و مثل طبعا انتوا تخيلوا هدولة تلت طبب
+
+125
+00:10:18,050 --> 00:10:23,590
+لكبار و كل مثل طالع منها اتش و اتش و اتش و اتش و
+
+126
+00:10:23,590 --> 00:10:27,510
+اتش و اتش يعني لو بدكم تتخيلوها ان هذي carbon
+
+127
+00:10:27,510 --> 00:10:29,990
+هيطلع اتش وكمان اتش وكمان اتش وكمان اتش وكمان اتش
+
+128
+00:10:29,990 --> 00:10:30,610
+وكمان اتش وكمان اتش وكمان اتش وكمان اتش وكمان اتش
+
+129
+00:10:30,610 --> 00:10:34,110
+وكمان اتش وكمان اتش وكمان اتش وكمان اتش وكمان اتش
+
+130
+00:10:34,110 --> 00:10:35,470
+وكمان اتش وكمان اتش وكمان اتش وكمان اتش وكمان اتش
+
+131
+00:10:35,470 --> 00:10:38,900
+وكمان اتش وكمانفعشان هيك ال S and two reactions
+
+132
+00:10:38,900 --> 00:10:44,600
+مابتصيرش مع ال tertiary السبب هنا بنسميه steric
+
+133
+00:10:44,600 --> 00:10:50,360
+factor، steric يعني متعلق بعمل إيش لاستحام، إنه
+
+134
+00:10:50,360 --> 00:10:57,050
+مافيش وسع، steric factorماشي عن hysteric factor
+
+135
+00:10:57,050 --> 00:11:03,050
+سبب متعلق بعمل الازدحام انه مفيش او مرات بيسموه
+
+136
+00:11:03,050 --> 00:11:08,410
+hysteric hindrance اش يعني hindrance ممانعة انه
+
+137
+00:11:08,410 --> 00:11:13,250
+مافيش وسع انه يجي يتفاعل واضح فلما نقول ليش افضل
+
+138
+00:11:13,250 --> 00:11:19,690
+اشي الاسئن to reaction مع ال primary الجواب بنقول
+
+139
+00:11:19,690 --> 00:11:22,750
+due to hysteric factor
+
+140
+00:11:25,410 --> 00:11:29,770
+يعني لو بدى أجيبلكوا سؤال صح و غلط في الامتحان
+
+141
+00:11:29,770 --> 00:11:35,730
+أقولكم الله أسئلتو reactions occurs with the
+
+142
+00:11:35,730 --> 00:11:40,110
+primary alkyl halides due to electronic factors
+
+143
+00:11:40,110 --> 00:11:45,450
+أسباب تتعلق بالإلكترونات وش .. لأ due to steric
+
+144
+00:11:45,450 --> 00:11:50,290
+factor أسباب تتعلق بالفراغ بالوسع واضحة النقطة
+
+145
+00:11:50,290 --> 00:11:51,310
+هذه؟ أه
+
+146
+00:11:55,600 --> 00:12:00,380
+الان بنبدأ في الدارس الجديد اللى بنكمل فيه اليوم
+
+147
+00:12:00,380 --> 00:12:05,860
+اللى هو لو كان عندى tertiary alkalites هانا بصير
+
+148
+00:12:05,860 --> 00:12:13,000
+بحكي عن ميكانيزم جديدة اللى بنسميها ايش S-N-1
+
+149
+00:12:13,000 --> 00:12:17,520
+والان بنشوف ليش بنسميها S-N-1 في ال tertiary
+
+150
+00:12:17,520 --> 00:12:22,860
+alkalites اخر شغلة قبل شوية حكيناها احنا ان ال
+
+151
+00:12:22,860 --> 00:12:29,800
+tertiary صعب يصيرمع الـ SN2 لأنه مافيش شيء وسع
+
+152
+00:12:29,800 --> 00:12:34,820
+لأنه في اندستيرك فاكتر بناء على ذلك لما بيكون عنده
+
+153
+00:12:34,820 --> 00:12:38,660
+tertiary alkyl halide زي هذا المركب اللي هو
+
+154
+00:12:38,660 --> 00:12:44,500
+tertiary butyl bromide شايفينه؟ ويكون بالذات كمان
+
+155
+00:12:44,500 --> 00:12:48,860
+ال nucleophile اضعيف يعني مش قادر يهاجم ولا له
+
+156
+00:12:48,860 --> 00:12:54,300
+وسعي يهاجمماذا سيحصل؟ الـ Nucleophile سيفعل الحياد
+
+157
+00:12:54,300 --> 00:13:00,920
+يستنى لحد ما تطلع ال PR مع إلكتروناتها يعني اللي
+
+158
+00:13:00,920 --> 00:13:03,760
+بيصير أنه بدأ تطلع ال PR مع إلكتروناتها طيب لما
+
+159
+00:13:03,760 --> 00:13:09,240
+تطلع ال PR مع إلكتروناتها بيصير وسعبالتأكيد،
+
+160
+00:13:09,240 --> 00:13:12,700
+بالتأكيد بيصير واسع لإن أنا هنا كان عندي حوالين ال
+
+161
+00:13:12,700 --> 00:13:18,200
+carbon أربع مجموعات بيصير حوالين ال carbon تلت
+
+162
+00:13:18,200 --> 00:13:22,560
+مجموعات، إذا صار في عندي وسع يعني لو تخيلنا مثلا
+
+163
+00:13:22,560 --> 00:13:30,680
+إن هذه هي ال carbon المعنية هذه تلت ذرات carbon،
+
+164
+00:13:30,680 --> 00:13:34,560
+شايفينهم؟ نعمل كل الروابط باللون الأصفر
+
+165
+00:13:38,620 --> 00:13:42,240
+هذا هو الكاربو كاتيون اللي بيطلع عندى، طلعوا
+
+166
+00:13:42,240 --> 00:13:46,580
+معايا، هدولة صاروا في مستوى واحد، صار عندى فراغ من
+
+167
+00:13:46,580 --> 00:13:50,420
+هنا و من هنا لأي مجموعة من الخارج بدأ تيجي تهاجم
+
+168
+00:13:51,090 --> 00:13:57,110
+إنها تيجي تتفاعل، واضح؟ إذا هانا كخطوة أولى لإنه
+
+169
+00:13:57,110 --> 00:14:03,010
+عندي تلت مجموعات مثل اكبار اللي بيصير انه بتطلع ال
+
+170
+00:14:03,010 --> 00:14:06,130
+halogen atom لما تطلع ال halogen atom مع
+
+171
+00:14:06,130 --> 00:14:10,750
+إلكتروناتها، شو بده تترك مكانها؟الـ positive هذا
+
+172
+00:14:10,750 --> 00:14:17,030
+على الكربون شو بنسميه كربو كتاين ايون كربون موجر
+
+173
+00:14:17,030 --> 00:14:23,410
+هذا الكربو كتاين هذا الكربو كتاين كيف شكله بلانر
+
+174
+00:14:23,410 --> 00:14:29,470
+بلانر ملاحظين انتوا و بناء على ان هذا الكربو كتاين
+
+175
+00:14:29,470 --> 00:14:34,370
+اللي عند انا بلانر لما بدى تيجي النيوكليوفايل او
+
+176
+00:14:34,370 --> 00:14:39,630
+يجي النيوكليوفايل يهاجم عليهبيقدر يهاجم منها أنا
+
+177
+00:14:39,630 --> 00:14:43,870
+وبيقدر يهاجم منها أنا، إذا الهجوم يتم من جهة ولا
+
+178
+00:14:43,870 --> 00:14:49,490
+من جهتين؟ من جهتين طبعا بيكون في اعتباركوا أنه
+
+179
+00:14:49,490 --> 00:14:55,410
+مابيطلعوش هدول الجهتين متساويتين الهجوم عليهم، ليش
+
+180
+00:14:55,410 --> 00:15:00,760
+مابيطلعوش متساويتين؟لأنه انا لو افترضت ان عندي هذه
+
+181
+00:15:00,760 --> 00:15:05,980
+ذرة و قاعدة بتنكسر و انكسرت و صار عندي زي هذا و
+
+182
+00:15:05,980 --> 00:15:10,440
+لسه قاعدة بتبعد، شايفين المنظر؟ يعني لما كانوا
+
+183
+00:15:10,440 --> 00:15:15,100
+أربعة كانوا بهذا الشكل، الآن هذه انكسرت و قاعدة
+
+184
+00:15:15,100 --> 00:15:20,820
+بتبعد و هذا صار بلا نار، لكن مازالت موجودة إجريب
+
+185
+00:15:21,710 --> 00:15:26,170
+وين الاحتمال اسهل؟ رغم ان هذا الاحتمال انفتح و هذا
+
+186
+00:15:26,170 --> 00:15:31,650
+الاحتمال انفتح لكن هذه ما زالت نوعا ما جريبة فبناء
+
+187
+00:15:31,650 --> 00:15:37,190
+على ذلك لو كان في احتمال نفترض 60% او 70% ييجي من
+
+188
+00:15:37,190 --> 00:15:43,130
+العكس بكل احتمال 30% او 40% انه ييجي من مكان خروج
+
+189
+00:15:43,130 --> 00:15:48,520
+هذهإيش السبب؟ إن هذه ما زالت موجودة، يعني أنا
+
+190
+00:15:48,520 --> 00:15:52,380
+أتخيلها هنا، لو ذرة جاية من هنا، ممكن تخبط فيها؟
+
+191
+00:15:52,380 --> 00:15:58,580
+ممكن، من هنا، اتجوزتها، ولذلك صح بيصير التفاعل من
+
+192
+00:15:58,580 --> 00:16:04,260
+الجهتين، لكن من أي جهة بيصير أكتر؟ من الجهة
+
+193
+00:16:04,260 --> 00:16:09,620
+المعاكسة أكتر، السبب إن هذه ما زالت لسه قريبة،
+
+194
+00:16:09,620 --> 00:16:16,110
+يعني ماصارش الوضع بهذا الشكل تماماًطلعوا كيف؟ هذه
+
+195
+00:16:16,110 --> 00:16:21,030
+طلعت و ما زالت قريبة، الآن من وين؟ الأفضل أنه يتم
+
+196
+00:16:21,030 --> 00:16:24,270
+التفاعل من الجهة المفتوحة، لكن هذه الجهة برضه إيش
+
+197
+00:16:24,270 --> 00:16:28,330
+مالها؟ مفتوحة، ولذلك احنا بنقول أن التفاعل بيتم صح
+
+198
+00:16:28,330 --> 00:16:34,700
+من الجهتين، لكنwith more inversion عشان هيك لما
+
+199
+00:16:34,700 --> 00:16:39,020
+بيجوا بيحكوا عن هذا التفاعل كيف النيوكليوفال بده
+
+200
+00:16:39,020 --> 00:16:43,900
+ييجي بيقولوا بيصير عند راسيمايزيشن راسيمايزيشن
+
+201
+00:16:43,900 --> 00:16:47,520
+معناه أنه يتم التفاعل من الجهتين with more
+
+202
+00:16:47,520 --> 00:16:52,980
+inversion يعني نفترض 70% inversion 30% من نفس
+
+203
+00:16:52,980 --> 00:16:56,820
+الاتجاه واضح فال stereo chemistry هانا إيش بنقول
+
+204
+00:16:56,820 --> 00:17:02,280
+عنهاracimization لكن هل يا تورا هو complete
+
+205
+00:17:02,280 --> 00:17:06,700
+racimization؟ complete racimization يعني خمسين في
+
+206
+00:17:06,700 --> 00:17:12,960
+المية خمسين في المية الواقع لأ racimization with
+
+207
+00:17:12,960 --> 00:17:22,300
+اش more inversion ليش more inversion؟ because
+
+208
+00:17:22,300 --> 00:17:25,880
+of the presence of the living group
+
+209
+00:17:32,840 --> 00:17:37,920
+السبب هو وجود المجموعة المغادرة، و لو بعددها عشرين
+
+210
+00:17:37,920 --> 00:17:43,020
+كيلوولو بعدت الى عشرين كيلو، لكن بيظل انه ممكن
+
+211
+00:17:43,020 --> 00:17:46,780
+تيجي منها وممكن منها، لكن من وين الأسهل؟ من الجهة
+
+212
+00:17:46,780 --> 00:17:51,060
+اللي فاضية مية في المية، بتشوفوا الآن المعارك على
+
+213
+00:17:51,060 --> 00:17:55,380
+التلفزيون ولا لأ؟ الجيش اللي طالع، الناس بفضله
+
+214
+00:17:55,380 --> 00:17:59,920
+ييجوا من منطقته ولا بييجوا بالعكس تماما، ولو هو
+
+215
+00:17:59,920 --> 00:18:06,020
+بعيد، لكن ما زالت آثارهموجودة، واضح؟ إذا بيصير
+
+216
+00:18:06,020 --> 00:18:10,740
+عندك Rassimization with more inversion والسبب due
+
+217
+00:18:10,740 --> 00:18:14,620
+to the presence of the leaving group in the nearby
+
+218
+00:18:14,620 --> 00:18:20,700
+space في الفراغ القريب ما زالت ال leaving group
+
+219
+00:18:20,700 --> 00:18:26,940
+موجودة واضح هذا الكلام؟ الآن لو بدنا نتعمق بهذه ال
+
+220
+00:18:26,940 --> 00:18:34,540
+mechanism هلاحظ أن هذه ال mechanism كام خطوةخطوتين
+
+221
+00:18:34,540 --> 00:18:41,440
+هذه الخطوة الأولى وهذه الخطوة الثانية الخطوة
+
+222
+00:18:41,440 --> 00:18:47,340
+الأولى كسر الهالوجين بوند لتكوين بلانر كاربو كتاين
+
+223
+00:18:47,340 --> 00:18:53,760
+موجب والخطوة الثانية اتكون و خلص بيجي ال
+
+224
+00:18:53,760 --> 00:19:01,300
+نيوكليوفايل يتفاعل ويعطيني ال الكلهيلايتأيهما
+
+225
+00:19:01,300 --> 00:19:06,200
+أصعب؟ الخطوة الأولى ولا الخطوة الثانية؟ الخطوة
+
+226
+00:19:06,200 --> 00:19:11,240
+الأولى .. مش دايما .. الخطوة الأولى هنا على أقل
+
+227
+00:19:11,240 --> 00:19:19,550
+تقدير أصعب .. ليش؟لأنه انا .. انتبهوا معي بلغة
+
+228
+00:19:19,550 --> 00:19:25,750
+الشحنات في الخطوة الأولى .. في الخطوة الأولى قاعد
+
+229
+00:19:25,750 --> 00:19:31,390
+بافصل موجب عن سالب امسكوا موجب و سالب و افصلوهم عن
+
+230
+00:19:31,390 --> 00:19:37,110
+بعض ايش بدكم؟ energy في الخطوة الثانية قاعد بجيب
+
+231
+00:19:37,110 --> 00:19:43,620
+سالب على موجبداعمًا الـ revulsion هذا والـ
+
+232
+00:19:43,620 --> 00:19:47,900
+separation of positive and negative charges، it
+
+233
+00:19:47,900 --> 00:19:51,840
+needs energy، اللي بيفصل مغناطسين و لا شحنتين
+
+234
+00:19:51,840 --> 00:19:57,400
+متجاذبتين، بده طاقة، و اللي بيمسك مغناطسين شمالي
+
+235
+00:19:57,400 --> 00:20:01,000
+وجنوبي و بجربهم مع بعض، هم بتجربوا قبل ما إيده
+
+236
+00:20:01,000 --> 00:20:05,320
+تيجي، هم بصحبوله إيده، مظبوط ولا لأ؟صح ولا لأ؟
+
+237
+00:20:05,320 --> 00:20:08,900
+عشان هيك لما بيكون عندنا يعني عفوا في المشاكل
+
+238
+00:20:08,900 --> 00:20:13,680
+العائلية لما يصير و بدهم يفصلوا الولد عن أمه
+
+239
+00:20:13,680 --> 00:20:19,320
+بتحسوا كيف بيجيبوا المنظر و هم قاعدين بيفصلوه و ما
+
+240
+00:20:19,320 --> 00:20:24,540
+إلى ذلك وبصعوبة و في آخر الفيلم لما يجيبولكم أن
+
+241
+00:20:24,540 --> 00:20:30,940
+الولد رجع لأمه بيدي جراي ملاحظين أنتوا كيف؟ هنا
+
+242
+00:20:30,940 --> 00:20:36,140
+نفس الاشي أنا بفصل موجب عن سالبواضح وبالتالي بحتاج
+
+243
+00:20:36,140 --> 00:20:41,000
+طاقة ولذلك هذه الخطوة هي الخطوة الصعبة هي الخطوة
+
+244
+00:20:41,000 --> 00:20:46,060
+الصعبة خطوة خروج ال PR minus ونفس الاشي كان عندنا
+
+245
+00:20:46,060 --> 00:20:49,740
+نبقى نحكي على الواقع تباعنا لما اليهود طلعوا من
+
+246
+00:20:49,740 --> 00:20:54,760
+غزة كان طلوعهم من المستوطنات الخطوة الصعبة هذا
+
+247
+00:20:54,760 --> 00:21:04,190
+الطلوع أخد من سنة 67 ل 2005 اه 38 سنةطيب بعد ما
+
+248
+00:21:04,190 --> 00:21:10,910
+طلعوا قداش لزم للناس عشان يدخلوا المستوطنات؟ عشر
+
+249
+00:21:10,910 --> 00:21:14,530
+ثواني يعني هم كانوا ماعدهم يطلعوا ع ال 12 في الليل
+
+250
+00:21:14,530 --> 00:21:17,770
+واحد زميل بيكلمنا 12 و 5 بيقول أنا في المستوطنة
+
+251
+00:21:18,600 --> 00:21:22,740
+الملاحظين انتوا الخطوة الصعبة و السهلة هذا جزء من
+
+252
+00:21:22,740 --> 00:21:28,480
+الكيميا ان احنا بنقول هذه slow step و هذه fast
+
+253
+00:21:28,480 --> 00:21:33,320
+step اذا انا امام two steps واحدة منهم slow واحدة
+
+254
+00:21:33,320 --> 00:21:39,200
+منهم fastfast لما انا اسألكوا ال first step in SN1
+
+255
+00:21:39,200 --> 00:21:44,580
+reactions is a fast step it is the slow step و ال
+
+256
+00:21:44,580 --> 00:21:48,620
+second step fast step الان ال slow step بيعطوها
+
+257
+00:21:48,620 --> 00:21:52,680
+اسم بيقولوا عنها ال rate determining step هي
+
+258
+00:21:52,680 --> 00:21:58,820
+الخطوة المحددة لسرعة التفاعلكل الموضوع بيعتمد
+
+259
+00:21:58,820 --> 00:22:05,240
+عليها الخطوة التانية إيش بنسميها تحصيل حاصل، واضح؟
+
+260
+00:22:05,240 --> 00:22:10,580
+إذا هذه ال slow step هي إيش بنسميها إحنا كمان rate
+
+261
+00:22:10,580 --> 00:22:18,500
+determining step يعني هي الخطوة المحددة لسرعة
+
+262
+00:22:18,500 --> 00:22:25,080
+التفاعلواضح؟ انتوا ممكن شوية ماوعتوش الحواجز اللي
+
+263
+00:22:25,080 --> 00:22:28,660
+كانت ع طريق غزة خانيونس و اللي مازالت موجودة في
+
+264
+00:22:28,660 --> 00:22:32,700
+الضفة لما واحد الان بدو يطلع ما بين مدينتين في
+
+265
+00:22:32,700 --> 00:22:38,260
+عندهم حاجز بيكلم جماعة و أنا جاي ان شاء الله ..
+
+266
+00:22:38,260 --> 00:22:43,830
+واضح؟ليش؟ وين عنده الخطوة الصعبة؟ لحد ما يقطع
+
+267
+00:22:43,830 --> 00:22:47,670
+الحاجز، بعد ما يقطع الحاجز، لو بده يكلم البيت،
+
+268
+00:22:47,670 --> 00:22:52,450
+بيكلمهم، بيقولهم جهزوا الأكل، أنا وصلت خلاص ضمن ..
+
+269
+00:22:52,450 --> 00:22:58,030
+قطع الحاجز هو الخطوة إيش؟ الصعبة، بعد هيك الخطوة
+
+270
+00:22:58,030 --> 00:23:02,930
+التانية هي خطوة إيش مالها سهلة، واضح؟ الآن لاحظوا
+
+271
+00:23:02,930 --> 00:23:06,970
+مع الخطوة الصعبة هذه اعتمدت على متفاعل ولا
+
+272
+00:23:06,970 --> 00:23:11,830
+متفاعلين؟متفاعل، إيش شايفين فيها انتوا بس؟
+
+273
+00:23:11,830 --> 00:23:17,230
+الكلهيلايت، ال nucleophile إيش ماله؟ أضعيف، قاعد
+
+274
+00:23:17,230 --> 00:23:21,250
+باستنى، زي أحوالنا، ال nucleophile أضعيف، ولذلك
+
+275
+00:23:21,250 --> 00:23:26,870
+هنا سرقة التفاعل كلها بتعتمد على إيش؟على متفاعل
+
+276
+00:23:26,870 --> 00:23:32,170
+واحد مش على متفاعلين ولذلك هذي الميكانيزم بيسموها
+
+277
+00:23:32,170 --> 00:23:37,790
+substitution in nucleophilic unimolecular يعني
+
+278
+00:23:37,790 --> 00:23:42,790
+بتعتمد على متفاعل واحد اللي هو ال R X مش على
+
+279
+00:23:42,790 --> 00:23:47,810
+متفاعلين واضح؟ فلو أنا بدي أحط ال rate of this
+
+280
+00:23:47,810 --> 00:23:56,960
+reaction شو بتساوي ال rate؟ K في التركيزالـ RX هل
+
+281
+00:23:56,960 --> 00:24:01,600
+بيظهر عند النيكليوفايل؟ لأ قبل شوية لما كنا نحكي
+
+282
+00:24:01,600 --> 00:24:06,840
+SN2 إيش كنا نقول ال rate؟ rate بتساوي كيف؟ RX في
+
+283
+00:24:06,840 --> 00:24:11,100
+نيكليوفايل كانوا التنين بيتصارعوا هنا بس التفاعل
+
+284
+00:24:11,100 --> 00:24:17,240
+معتمد على ال RX ولذلك اسمها substitution in
+
+285
+00:24:17,240 --> 00:24:21,830
+nucleophilic unimolecularإذن لو أنا بدأتش أسألكوا
+
+286
+00:24:21,830 --> 00:24:24,310
+the rate of S and 1 reactions depends on the
+
+287
+00:24:24,310 --> 00:24:29,050
+concentration of nucleophile and RX لأ it depends
+
+288
+00:24:29,050 --> 00:24:32,990
+on the concentration of RX ماشي لو بدنا نسألها
+
+289
+00:24:32,990 --> 00:24:37,530
+بطريقة تانية S and 1 reactions are first order
+
+290
+00:24:37,530 --> 00:24:42,810
+reactions first order معتمدين على ال RX و ال RX ال
+
+291
+00:24:42,810 --> 00:24:49,270
+factor تبعها واحد بينما ال S and 2 they areSecond
+
+292
+00:24:49,270 --> 00:24:54,490
+order reactions أو لو بدنا نسألهم، بيعتمدوا على
+
+293
+00:24:54,490 --> 00:25:01,490
+تركيز أيش؟ المتفاعلين الـ RX و النيوكليوفايل واضح؟
+
+294
+00:25:01,490 --> 00:25:08,290
+طبعا احنا دائما بنهتم بالخطوة الاشاللي هي البطيئة
+
+295
+00:25:08,290 --> 00:25:12,670
+ال slow step الخطوة التانية تحصيل حاصل الان لاحظوا
+
+296
+00:25:12,670 --> 00:25:17,710
+معي ان انتوا هنا أخدتوا معلومات كتيرة متعلقة بال
+
+297
+00:25:17,710 --> 00:25:22,790
+SN1 reactions بتذكروا المرة الماضية أعطيناكم ال
+
+298
+00:25:22,790 --> 00:25:29,250
+SN2 reactions و أعطيناكم عليها شوية أشياء الان لما
+
+299
+00:25:29,250 --> 00:25:34,550
+بدي أجي SN1 reactions و أبدأ أذكركم أفضل إشي بتمشي
+
+300
+00:25:34,550 --> 00:25:34,950
+معه
+
+301
+00:25:37,940 --> 00:25:43,560
+أسانوان reactions ال tertiary أفضل من ال secondary
+
+302
+00:25:43,560 --> 00:25:46,820
+أفضل من ال primary حتى ال primary ما بيصيرش نمرة
+
+303
+00:25:46,820 --> 00:25:53,300
+تانية بتفضل ال weak ال nucleophile نمرة تلاتة one
+
+304
+00:25:53,300 --> 00:25:58,380
+or two steps two steps و بتكون تعرفوا أنية السريعة
+
+305
+00:25:58,380 --> 00:26:06,300
+فيهم التانية البطيقة الأولى نمرة أربع بتكون فيها
+
+306
+00:26:08,880 --> 00:26:12,020
+الكاربو كاتيون هنا بنسمي الكاربو كاتيون
+
+307
+00:26:12,020 --> 00:26:17,080
+intermediate مش transition state لترانزيشن state
+
+308
+00:26:17,080 --> 00:26:20,160
+أثناء تكون intermediate يعني بين هذا و هذا في
+
+309
+00:26:20,160 --> 00:26:23,540
+transition state و بين هذه و هذه في transition
+
+310
+00:26:23,540 --> 00:26:29,240
+state واضح؟ بس هذا الكاربو كاتيون شو بنسميه احنا؟
+
+311
+00:26:29,240 --> 00:26:34,660
+intermediate الكائنة
+
+312
+00:26:36,860 --> 00:26:40,840
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+313
+00:26:40,840 --> 00:26:41,080
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+314
+00:26:41,080 --> 00:26:41,120
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+315
+00:26:41,120 --> 00:26:41,320
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+316
+00:26:41,320 --> 00:26:41,560
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+317
+00:26:41,560 --> 00:26:51,280
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+318
+00:26:51,280 --> 00:27:02,860
+أولا أو
+
+319
+00:27:02,860 --> 00:27:10,630
+ثانويةب S and 1 طبعا ممكن هنا يجيني سؤال طب لو
+
+320
+00:27:10,630 --> 00:27:18,430
+عندي secondary ال secondary بين بين ال secondary
+
+321
+00:27:18,430 --> 00:27:24,710
+مع ال strong ال nucleophile شو هيمشي؟ S and 2 و ال
+
+322
+00:27:24,710 --> 00:27:29,570
+secondary مع ال weak بيمشي ب S and 1 واضح؟
+
+323
+00:27:32,690 --> 00:27:38,230
+هذا منحنى هذا منحنى للتفاعل الآن دائما اهتموا
+
+324
+00:27:38,230 --> 00:27:43,990
+بالمقارنات يعني لما بتدرسوا احنا قبل شوية رسمنالكم
+
+325
+00:27:43,990 --> 00:27:49,950
+منحنى لل SN2 reaction ايش كانت ميزة منحنى ال SN2
+
+326
+00:27:49,950 --> 00:27:55,910
+دائما منحنى الطاقة لتفاعل معين منحنى الطاقة لأي
+
+327
+00:27:55,910 --> 00:27:59,930
+تفاعل في عندي reactants ال transition state بتعلق
+
+328
+00:27:59,930 --> 00:28:07,200
+product فكلبيك زي هذه بلغة المنحنيات تمثل إيش step
+
+329
+00:28:07,200 --> 00:28:12,300
+أو خطوة بناء على ذلك لما أنا هنا باجي بقى أطلع على
+
+330
+00:28:12,300 --> 00:28:17,960
+هذا التفاعل أكم step؟ one step reactants؟ ال
+
+331
+00:28:17,960 --> 00:28:21,840
+transition state of products الآن لما بدي أجي أرسم
+
+332
+00:28:21,840 --> 00:28:28,040
+منحنى لأسئلة one reaction شو بتكون تتوقعوا يكون
+
+333
+00:28:28,040 --> 00:28:32,560
+عنده؟بدي أصير عندي two steps مش one step يعني
+
+334
+00:28:32,560 --> 00:28:38,000
+الملحنة مرتين قمتين لكن لو بدنا نيجي نسأل أي قمة
+
+335
+00:28:38,000 --> 00:28:42,200
+يا تورا اللي بده تكون الأعلى و الأصعب أي قمة
+
+336
+00:28:42,200 --> 00:28:46,920
+الأعلى و الأصعب الأولى عشان هيك انتوا تطلعوا معنا
+
+337
+00:28:46,920 --> 00:28:51,360
+لما تشوفوا هي عندكم reactants وهي ال transition
+
+338
+00:28:51,360 --> 00:28:56,520
+state اللي هو ال carbocation هنا لو بتشوفوا ال
+
+339
+00:28:56,520 --> 00:29:03,330
+transition state الأولى كدهكبيرة جدا يعني بدو يقفز
+
+340
+00:29:03,330 --> 00:29:06,970
+قفزة كبيرة جدا الان هذا الكربوكاتين بعد هيك لما
+
+341
+00:29:06,970 --> 00:29:11,550
+بدو يتفاعل ويعطينا ال product النهائي هنا ماخد
+
+342
+00:29:11,550 --> 00:29:17,650
+تفاعل الماءمع الـ .. هو الـ tertiary-butyl bromide
+
+343
+00:29:17,650 --> 00:29:21,370
+الـ reactant هو tertiary-butyl bromide هنا بيعطينا
+
+344
+00:29:21,370 --> 00:29:24,490
+الـ carbocation لحاله نفس المعادلة اللي انتوا
+
+345
+00:29:24,490 --> 00:29:29,270
+شوفتوها بعدين بيجي ال PR .. زاد ال PR minus بتيجي
+
+346
+00:29:29,270 --> 00:29:35,190
+الميه تتفاعل بضيف OH2 plus وبعدين بتفقد ال H plus
+
+347
+00:29:35,190 --> 00:29:39,670
+الان فقد ال H plus موضوع بسيط مش موضوعنا لكن هنا
+
+348
+00:29:39,670 --> 00:29:44,060
+لما ابدا اطلع كام خطوة هذا التفاعلخطوة تانية هي
+
+349
+00:29:44,060 --> 00:29:48,700
+الخطوة الأولى طلع معي reactant transition state ل
+
+350
+00:29:48,700 --> 00:29:50,960
+product ال carbocation الخطوة التانية ال
+
+351
+00:29:50,960 --> 00:29:57,230
+carbocation مع الميههذه الخطوة التانية البعض يشوف
+
+352
+00:29:57,230 --> 00:29:59,610
+الخطوة التالتة الخطوة التالتة ليست أساسية في
+
+353
+00:29:59,610 --> 00:30:03,330
+الميكانيزم الخطوة التالتة ان المياه تدخل مع
+
+354
+00:30:03,330 --> 00:30:08,230
+البروتن ويفقد البروتن منها تدخل OH2 ويفقد ال OH
+
+355
+00:30:08,230 --> 00:30:14,210
+لكن كميكانيزم أساسي كم خطوة التفاعل؟ خطوتين واضح؟
+
+356
+00:30:14,210 --> 00:30:18,390
+دائما نقول ال reaction is a two step
+
+357
+00:30:25,980 --> 00:30:33,100
+أيهم أصعب؟ هذه القفزة أو هذه القفزة؟ هذه الصعوبة
+
+358
+00:30:33,100 --> 00:30:39,840
+التي هي ال activation energyالفرق ما بين ال
+
+359
+00:30:39,840 --> 00:30:43,080
+transition state و ال reactant اي activation هنا
+
+360
+00:30:43,080 --> 00:30:47,520
+عالي اي activation هنا قليل جدا و لذلك ال first
+
+361
+00:30:47,520 --> 00:30:52,180
+step is the difficult step لازم يكون عندكم فهم
+
+362
+00:30:52,180 --> 00:30:57,280
+لطريقة رسم المنحنيات يعني هذا المنحنى مجرد ما
+
+363
+00:30:57,280 --> 00:31:01,780
+تشوفوه يقول لطالبة منكوا اتفضلي اشرحيلنا ماذا يعني
+
+364
+00:31:01,780 --> 00:31:06,820
+هذا المنحنى لو رسلنا لحدين هتقول هذا منحنى تفاعل
+
+365
+00:31:06,820 --> 00:31:13,370
+من خطوتينهي خطوة؟ هى خطوة الخطوة الأولى صعبة
+
+366
+00:31:13,370 --> 00:31:18,470
+والخطوة الثانية سهلة والتفاعل بمجمله اذا شوفت هى
+
+367
+00:31:18,470 --> 00:31:21,710
+ال reactants وهى ال final products اكزو ثرميك ولا
+
+368
+00:31:21,710 --> 00:31:32,670
+اندو ثرميك هى ال reactant الأصلى فقط
+
+369
+00:31:32,670 --> 00:31:39,540
+طاقة طاقة النواتج اقل اذا فقدت طاقةهذا Exothermic
+
+370
+00:31:39,540 --> 00:31:46,990
+بامتيازدائما التفاعل لما بيكونوا ال products أقل
+
+371
+00:31:46,990 --> 00:31:51,190
+من ال reactants في الطاقة، شو بيكون؟ Exothermic،
+
+372
+00:31:51,190 --> 00:31:55,350
+نرجع للتفاعل تبع قبل شوية، المنحنة الواحد، هذا
+
+373
+00:31:55,350 --> 00:31:59,250
+المنحنة Exo ولا Endothermic؟ Exothermic،
+
+374
+00:31:59,250 --> 00:32:03,750
+Exothermic، كانت نفترض طاقة ال reactants خلينا
+
+375
+00:32:03,750 --> 00:32:09,310
+تجاوزا، نقول رقم عشرة، عشرة مثلا، تجاوزا، مع العلم
+
+376
+00:32:09,310 --> 00:32:16,120
+الطاقة لا تحددصارت ستة تجاوزا اذا هنا ايش صار عندى
+
+377
+00:32:16,120 --> 00:32:20,800
+نقص في الطاقة اذا فقدت الطاقة فهذا التفاعل ايش
+
+378
+00:32:20,800 --> 00:32:24,320
+اكسو ثيرميك لو بدى يكون اندو ثيرميك كيف بده ينتهي؟
+
+379
+00:32:24,320 --> 00:32:29,540
+بدي يكون زي هي يعني لو اصف التفاعل بهذا الشكل
+
+380
+00:32:29,540 --> 00:32:34,160
+بنقول هذا اندو ثيرميك لكن بزامو هاي مستوى ال
+
+381
+00:32:34,160 --> 00:32:39,950
+reactants زي هيexothermic هذا exothermic هذا
+
+382
+00:32:39,950 --> 00:32:43,870
+endothermic هنا طاقة النواتج أعلى من طاقة
+
+383
+00:32:43,870 --> 00:32:48,990
+المتفاعلات إذا هو اكتسب طاقة و بقيت هذه الطاقة
+
+384
+00:32:48,990 --> 00:32:53,530
+المكتسبة في النواتج هذا المفروض يعني تكون اتعلمتها
+
+385
+00:32:53,530 --> 00:33:00,890
+منحنيات التفاعل لو مثلا بدي أجي أقولكم إذا بتسمحوا
+
+386
+00:33:00,890 --> 00:33:05,830
+أرسمولي منحنة لتفاعل من خطوتين
+
+387
+00:33:15,210 --> 00:33:18,590
+والتفاعل كله اندو ثيرميك
+
+388
+00:33:21,290 --> 00:33:24,910
+ممكن أجيبلكم سؤال في الامتحان بس زي هيك ارسمولي
+
+389
+00:33:24,910 --> 00:33:31,470
+منحنى لتفاعل من خطواتين الخطوة الأولى سهلة و
+
+390
+00:33:31,470 --> 00:33:36,770
+الخطوة الثانية صعبة و التفاعل بمجمله into thermic
+
+391
+00:33:36,770 --> 00:33:40,610
+لما تريدون أن تأتيوا ترسموا بتعملوا زي هيك و زي
+
+392
+00:33:40,610 --> 00:33:47,650
+هيك هاي منحنى حطوا هذه reactantsإيش أنا قاعد بقول؟
+
+393
+00:33:47,650 --> 00:33:52,690
+الخطوة الأولى سهلة بعمل ال activation energy بسيط
+
+394
+00:33:52,690 --> 00:34:02,750
+و الخطوة الثانية صعبة إيش بعمللها؟ و التفاعل
+
+395
+00:34:02,750 --> 00:34:08,130
+endothermic هاي خط ال reactance هذا الملحانة بيمثل
+
+396
+00:34:08,130 --> 00:34:15,940
+هذه المواصفات هاي تفاعل من خطوتين هاي خطوةالخطوة
+
+397
+00:34:15,940 --> 00:34:20,860
+الأولى، الخطوة الثانية صعبة التفاعل بمجمله
+
+398
+00:34:20,860 --> 00:34:25,180
+endothermic لو كنت جاي التفاعل بمجمله exothermic،
+
+399
+00:34:25,180 --> 00:34:30,440
+شو هيحصل في المنحنة؟ هينزلها تحت، واضح؟ فاحنا
+
+400
+00:34:30,440 --> 00:34:35,620
+الخطوات بنقدر نعبر عنها بمنحنيات طاقة زي ما انتوا
+
+401
+00:34:35,620 --> 00:34:41,800
+شايفينالان بديكوا تكونوا متذكرين على السريع
+
+402
+00:34:41,800 --> 00:34:45,880
+شغلتين، لما بتكون Carbocation أخدنا إحنا إذا
+
+403
+00:34:45,880 --> 00:34:49,300
+بتدخلوا ال stability of carbocation، بقولنا أنه
+
+404
+00:34:49,300 --> 00:34:56,740
+أكتر carbocation stable، ال tertiary، شو السبب؟إنه
+
+405
+00:34:56,740 --> 00:35:01,600
+في حواليه electron donating groups، يعني في ال
+
+406
+00:35:01,600 --> 00:35:06,600
+tertiary، هذا موجة، حواليه تلت مجموعات بيعطوا
+
+407
+00:35:06,600 --> 00:35:11,280
+إلكترونات، فتقل الشحن الموجة بقى، في ال secondary،
+
+408
+00:35:11,280 --> 00:35:15,600
+مجموعتين، هذا ال slide أخدناها إحنا لما أخدنا ال
+
+409
+00:35:15,600 --> 00:35:21,820
+stability of carbocation سابقا، أخدنا إش زيهاهنا
+
+410
+00:35:21,820 --> 00:35:27,980
+في ال primary مجموعة واحدة بس، اذا وين اكتر انقاص
+
+411
+00:35:27,980 --> 00:35:34,160
+لشحنة الموجبة وكل ما نقصت الشحنة زادة، الثبات، اذا
+
+412
+00:35:34,160 --> 00:35:40,340
+اكتر اشي ثابت اللي هو ال tertiary carbohydrate
+
+413
+00:35:40,340 --> 00:35:45,060
+فاسهل اشي بتكونال torture الثابت هو اللي بتكون
+
+414
+00:35:45,060 --> 00:35:48,880
+بسهولة، وعشانك احنا بنقول انه في ال questions و ال
+
+415
+00:35:48,880 --> 00:35:53,260
+reactions ال torture أفضل من ال secondary أفضل من
+
+416
+00:35:53,260 --> 00:35:57,900
+ال primary، متذكرين هذا الكلام؟ ال torture أفضل من
+
+417
+00:35:57,900 --> 00:36:02,780
+ال secondary أفضل من ال primaryبرضه لما أخدتوا ال
+
+418
+00:36:02,780 --> 00:36:06,960
+carbon-cation نتذكروا شغلة أخدناها قولنا لو اتكون
+
+419
+00:36:06,960 --> 00:36:10,800
+carbon-cation ونفترض كان secondary وفيه إمكانية
+
+420
+00:36:10,800 --> 00:36:15,600
+يعمل rearrangement تصير tertiary بتصير ولا لأ؟
+
+421
+00:36:15,600 --> 00:36:19,460
+بتصير بيعمل rearrangement مشكول بني آدم بيحس نوضعه
+
+422
+00:36:19,460 --> 00:36:26,690
+عشان هيك لو أنا مثلا بدي أجي أخدهذا المركب هنا فيه
+
+423
+00:36:26,690 --> 00:36:31,810
+primary X لو بدها تمشي بتفاعل SN2 اتخيلوا ايش اللي
+
+424
+00:36:31,810 --> 00:36:35,850
+بيصير بيصير positive هنا هذا الكربو كاتيون ايش
+
+425
+00:36:35,850 --> 00:36:42,430
+ماله ال primary ابتنق ال H من هنا بيصير secondary
+
+426
+00:36:42,430 --> 00:36:46,270
+ف ال Z ل نيوكليوفايد بدل ميجي محل ال X وين بيجي
+
+427
+00:36:46,270 --> 00:36:52,060
+محل ال secondaryملاحظين معي الكاربو كاتيون اول ما
+
+428
+00:36:52,060 --> 00:36:55,660
+يتكون بتكون هنا على ال primary صار متكون على ال
+
+429
+00:36:55,660 --> 00:37:00,700
+primary ايش بيصير ناقل هيدرايت شفت بيصير الكاربو
+
+430
+00:37:00,700 --> 00:37:05,080
+كاتيون secondary ال Z بتيجي هنا او لو هذا المركب
+
+431
+00:37:05,080 --> 00:37:09,680
+هاي X فقدت ايش صار هنا الكاربو كاتيون عنده لما
+
+432
+00:37:09,680 --> 00:37:17,070
+فقدت هذه ال X ال primary شو بيصيرتنتقل high drive
+
+433
+00:37:17,070 --> 00:37:22,430
+تصبح DCH3 و هنا الفراغ اين تأتي الـ Z كأن ال
+
+434
+00:37:22,430 --> 00:37:28,130
+primary في خطوته المولى صار tertiary و ال Z جاءت
+
+435
+00:37:28,130 --> 00:37:30,710
+على ال tertiary لاحظوا هنا ال range مت من ال
+
+436
+00:37:30,710 --> 00:37:34,310
+primary إلى secondary هنا من ال primary إلى
+
+437
+00:37:34,310 --> 00:37:40,630
+tertiary لو فترضت هنا راحت ال X صار كربوكاتا يلمج
+
+438
+00:37:40,630 --> 00:37:45,500
+على العين والرأس بعد ذلك ماذا يحصل؟الأكشف تنتقل و
+
+439
+00:37:45,500 --> 00:37:49,340
+يصبح كاربو كاتيون هنا، شو نوعه؟ ترشر، الزد بتيجي
+
+440
+00:37:49,340 --> 00:37:53,240
+عليه، هل ملاحظين؟ هذه هي ال rearrangement اللي سبق
+
+441
+00:37:53,240 --> 00:37:57,240
+أنه أعطينا أمثلة زيها، يعني مش كتير هنركز بهذا
+
+442
+00:37:57,240 --> 00:38:00,300
+المسافة عليها، بس حتى لما تسمعوا كلمة
+
+443
+00:38:00,300 --> 00:38:03,520
+rearrangement يكون واضح عندكم، أنه لو كان عندى
+
+444
+00:38:03,520 --> 00:38:07,860
+primary كاربو كاتيون بيمكنه يصير secondary؟بصير،
+
+445
+00:38:07,860 --> 00:38:12,020
+لو كان secondary بإمكانه يصير tertiary، بصير، يعني
+
+446
+00:38:12,020 --> 00:38:15,820
+اللي معدله سبعين بده تخليه تمانين، و اللي معدله
+
+447
+00:38:15,820 --> 00:38:19,560
+تمانين بده تخليه تسعين، و لو معدله سبعين و بتخليه
+
+448
+00:38:19,560 --> 00:38:27,290
+تسعين، نور على نور، نور على نورهذه الـ slide
+
+449
+00:38:27,290 --> 00:38:31,650
+أخدناها قولنا إنه لو عندي سكاندري التفاعل بشكل
+
+450
+00:38:31,650 --> 00:38:35,790
+كبير بيعتمد على قوة الـ nucleophile فلما يكون ال
+
+451
+00:38:35,790 --> 00:38:42,610
+nucleophile strong بيشجع SN2 لما يكون weak بيشجع
+
+452
+00:38:42,610 --> 00:38:47,370
+SN1 ال solvent له تأثير لكن خارج مستوى دراستنا هذه
+
+453
+00:38:47,370 --> 00:38:51,010
+ال slide بنختم المحاضرة اليوم فيها بإمكانكوا
+
+454
+00:38:51,010 --> 00:38:56,610
+تقرؤوها بهدوء هي مقارنةأحنا كتبناها على الجانب
+
+455
+00:38:56,610 --> 00:39:02,170
+مرتين وبسيبها مكتوبة الآن و بنخلص المحاضرة هي
+
+456
+00:39:02,170 --> 00:39:08,270
+مقارنة ما بين ال SN2 و SN1 ال SN2 second order
+
+457
+00:39:08,270 --> 00:39:12,430
+أخدناها فيها complete inversion مش فيها
+
+458
+00:39:12,430 --> 00:39:15,390
+rearrangement ال reactivity براعي ما ليه أكتر من
+
+459
+00:39:15,390 --> 00:39:21,340
+secondary أكتر من tertiary الآن ال SN1first order
+
+460
+00:39:21,340 --> 00:39:25,800
+فيها رسميزيشن و في ال inversion زيادة فيها
+
+461
+00:39:25,800 --> 00:39:29,780
+rearrangement و ال tertiary افضل من ال secondary
+
+462
+00:39:29,780 --> 00:39:34,320
+افضل من ال primary و زيدوا هنا ان هذه one step و
+
+463
+00:39:34,320 --> 00:39:40,680
+هذه two step و ال two steps اللي هنا الاولة slow
+
+464
+00:39:40,680 --> 00:39:45,680
+التانية fast الان مثل هذه المقارنة بنقدر نجيب
+
+465
+00:39:45,680 --> 00:39:50,630
+عليها كام سؤال صح و غلطعشرين سؤال صح و غلط و
+
+466
+00:39:50,630 --> 00:39:57,350
+بتلخصنا كل المحاضرتين اللي فاتوا مثل هذه المقارنة
+
+467
+00:39:57,350 --> 00:40:00,390
+بتلخص المحاضرتين اللي فاتوا و أنا بتهيأ ليه أنه
+
+468
+00:40:00,390 --> 00:40:05,990
+أخدنا احنا يعني أخدناهم يعني بشكل بعتقد أنه كافي
+
+469
+00:40:05,990 --> 00:40:06,710
+شكرا
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..5a074b7ebf83501182571f213307de72fc55ad17
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3507, "start": 7.83, "end": 35.07, "text": "بسم الله الرحمن الرحيم زي ما بتعرفوا احنا بدأنا في الفصل السادس اللي هو كان الكلهيلايتس بشكل أساسي بنحكي عن نوعين من التفاعلات، تفاعلات الإبدال وتفاعلات الحذف، إذا بدي أمر عالسريع معكم مرات الواحد بحب أنه يذكركم بالأشياء اللي حكيناها، ليش؟", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 30767, 1829, 19446, 39894, 3615, 28480, 14407, 1975, 5016, 8315, 47525, 10721, 8315, 8978, 27188, 36520, 21136, 18513, 3794, 13672, 1829, 31439, 25961, 2423, 28820, 3224, 26895, 995, 36081, 3794, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 44945, 5016, 4117, 1829, 18871, 8717, 45367, 9957, 9154, 16712, 5172, 995, 30241, 9307, 12399, 6055, 5172, 995, 30241, 9307, 33688, 44510, 6027, 34683, 5172, 995, 30241, 9307, 21542, 8848, 5172, 12399, 11933, 15730, 4724, 16254, 5551, 29973, 6225, 6027, 3794, 16572, 3615, 20449, 24793, 3714, 2288, 9307, 2423, 14407, 24401, 4724, 5016, 3555, 14739, 3224, 7251, 8848, 37983, 24793, 20666, 10721, 8592, 1829, 16606, 13672, 1829, 11331, 4117, 1829, 8315, 11296, 12399, 32239, 8592, 22807], "avg_logprob": -0.21366869942928718, "compression_ratio": 1.9466666666666668, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 7.83, "end": 8.15, "word": "بسم", "probability": 0.922119140625}, {"start": 8.15, "end": 8.33, "word": " الله", "probability": 0.97705078125}, {"start": 8.33, "end": 8.63, "word": " الرحمن", "probability": 0.9220377604166666}, {"start": 8.63, "end": 8.97, "word": " الرحيم", "probability": 0.9889322916666666}, {"start": 8.97, "end": 10.81, "word": " زي", "probability": 0.718505859375}, {"start": 10.81, "end": 10.91, "word": " ما", "probability": 0.96044921875}, {"start": 10.91, "end": 11.39, "word": " بتعرفوا", "probability": 0.9864501953125}, {"start": 11.39, "end": 11.73, "word": " احنا", "probability": 0.8883463541666666}, {"start": 11.73, "end": 12.83, "word": " بدأنا", "probability": 0.7145182291666666}, {"start": 12.83, 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"word": " رابطة", "probability": 0.9798583984375}, {"start": 464.14, "end": 464.64, "word": " ال", "probability": 0.93115234375}, {"start": 464.64, "end": 465.0, "word": " PR", "probability": 0.88916015625}, {"start": 465.0, "end": 465.56, "word": " بتبدأ", "probability": 0.8798828125}, {"start": 465.56, "end": 466.1, "word": " تنكسر", "probability": 0.95908203125}, {"start": 466.1, "end": 466.48, "word": " بيصير", "probability": 0.83416748046875}, {"start": 466.48, "end": 466.82, "word": " عندى", "probability": 0.760986328125}, {"start": 466.82, "end": 467.02, "word": " هذا", "probability": 0.52099609375}, {"start": 467.02, "end": 467.2, "word": " ال", "probability": 0.9404296875}, {"start": 467.2, "end": 467.68, "word": " transition", "probability": 0.916015625}, {"start": 467.68, "end": 468.36, "word": " state", "probability": 0.88916015625}, {"start": 468.36, "end": 468.88, "word": " اللي", "probability": 0.83544921875}, {"start": 468.88, "end": 469.7, "word": " سمناها", "probability": 0.9019775390625}], "temperature": 1.0}, {"id": 21, "seek": 49238, "start": 470.66, "end": 492.38, "text": "بـ Intervalent خمسية الإرتباط بعد ذلك يكتمل تكوين هذا الرابط أو يكتمل كسر الـ PR minus طبعاً بتلاحظوا أنه بسرعة ال inversion ولا لأ ال PR كانت باتجاه الـ nucleophile جاء بالاتجاه المعاكس إيش اللي بيسمح لل nucleophile أنه يهاجم Hannah بسهولة؟", "tokens": [3555, 39184, 5751, 3337, 317, 16490, 2304, 3794, 10632, 33688, 43500, 3555, 41193, 39182, 29910, 23275, 7251, 4117, 39237, 1211, 6055, 4117, 2407, 9957, 23758, 34892, 16758, 9566, 34051, 7251, 4117, 39237, 1211, 9122, 3794, 2288, 2423, 39184, 11568, 3175, 23032, 3555, 3615, 995, 14111, 39894, 15040, 5016, 19913, 14407, 14739, 3224, 4724, 3794, 2288, 27884, 2423, 43576, 49429, 5296, 10721, 2423, 11568, 25961, 2655, 4724, 9307, 7435, 40294, 2423, 39184, 14962, 49242, 10874, 16606, 20666, 9307, 7435, 40294, 9673, 3615, 995, 4117, 3794, 11933, 1829, 8592, 13672, 1829, 4724, 1829, 38251, 5016, 24976, 14962, 49242, 14739, 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الرابط", "probability": 0.9265950520833334}, {"start": 476.18, "end": 476.3, "word": " أو", "probability": 0.7841796875}, {"start": 476.3, "end": 476.74, "word": " يكتمل", "probability": 0.942626953125}, {"start": 476.74, "end": 477.12, "word": " كسر", "probability": 0.9630533854166666}, {"start": 477.12, "end": 477.32, "word": " الـ", "probability": 0.71484375}, {"start": 477.32, "end": 477.58, "word": " PR", "probability": 0.342041015625}, {"start": 477.58, "end": 478.12, "word": " minus", "probability": 0.1700439453125}, {"start": 478.12, "end": 478.84, "word": " طبعاً", "probability": 0.778369140625}, {"start": 478.84, "end": 479.46, "word": " بتلاحظوا", "probability": 0.915625}, {"start": 479.46, "end": 479.62, "word": " أنه", "probability": 0.706298828125}, {"start": 479.62, "end": 480.02, "word": " بسرعة", "probability": 0.758544921875}, {"start": 480.02, "end": 480.18, "word": " ال", "probability": 0.53125}, {"start": 480.18, "end": 480.74, "word": " inversion", "probability": 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{"start": 487.7, "end": 487.88, "word": " اللي", "probability": 0.962890625}, {"start": 487.88, "end": 488.84, "word": " بيسمح", "probability": 0.991943359375}, {"start": 488.84, "end": 489.08, "word": " لل", "probability": 0.499755859375}, {"start": 489.08, "end": 490.12, "word": " nucleophile", "probability": 0.84912109375}, {"start": 490.12, "end": 490.5, "word": " أنه", "probability": 0.727783203125}, {"start": 490.5, "end": 491.1, "word": " يهاجم", "probability": 0.9844970703125}, {"start": 491.1, "end": 491.46, "word": " Hannah", "probability": 0.1934814453125}, {"start": 491.46, "end": 492.38, "word": " بسهولة؟", "probability": 0.9794921875}], "temperature": 1.0}, {"id": 22, "seek": 51302, "start": 492.88, "end": 513.02, "text": "ووجود وسع انه هذه ال carbon تكون primary لو كان ال tertiary الوسع مغلق مافيش مكان يدخل ال nucleophile من خلاله فأفضل شئ لهذه ال mechanism انه يكون هذا ال nucleophile strong ويلاجى وسع يلاجى primary carbon", "tokens": [2407, 29245, 23328, 46952, 3615, 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"probability": 0.75390625}, {"start": 501.82, "end": 502.58, "word": " nucleophile", "probability": 0.8330078125}, {"start": 502.58, "end": 502.8, "word": " من", "probability": 0.9931640625}, {"start": 502.8, "end": 503.2, "word": " خلاله", "probability": 0.9906005859375}, {"start": 503.2, "end": 503.96, "word": " فأفضل", "probability": 0.868359375}, {"start": 503.96, "end": 504.48, "word": " شئ", "probability": 0.683837890625}, {"start": 504.48, "end": 505.96, "word": " لهذه", "probability": 0.654052734375}, {"start": 505.96, "end": 506.1, "word": " ال", "probability": 0.89404296875}, {"start": 506.1, "end": 506.6, "word": " mechanism", "probability": 0.83642578125}, {"start": 506.6, "end": 506.96, "word": " انه", "probability": 0.59033203125}, {"start": 506.96, "end": 507.18, "word": " يكون", "probability": 0.987548828125}, {"start": 507.18, "end": 507.36, "word": " هذا", "probability": 0.744140625}, {"start": 507.36, "end": 507.48, "word": " ال", "probability": 0.92724609375}, {"start": 507.48, "end": 508.26, "word": " nucleophile", "probability": 0.958740234375}, {"start": 508.26, "end": 508.82, "word": " strong", "probability": 0.896484375}, {"start": 508.82, "end": 509.42, "word": " ويلاجى", "probability": 0.699951171875}, {"start": 509.42, "end": 509.88, "word": " وسع", "probability": 0.9697265625}, {"start": 509.88, "end": 510.68, "word": " يلاجى", "probability": 0.867431640625}, {"start": 510.68, "end": 511.4, "word": " primary", "probability": 0.8359375}, {"start": 511.4, "end": 513.02, "word": " carbon", "probability": 0.890625}], "temperature": 1.0}, {"id": 23, "seek": 53897, "start": 514.87, "end": 538.97, "text": "أعملنا ملحنة طاقة للتفاعل هذه المتفاعلات لـ Transition State Intervalent دائما لـ Transition State الطاقة تبعتها أعلى من ال reactants و ال products بعد ذلك لما تفقد ال PR بيكتمل هنا تكوين الرابطة تكوين الرابطة بيفقد من خلاله طاقة فبينزل التفاعل", "tokens": [10721, 25957, 1211, 8315, 3714, 1211, 5016, 1863, 3660, 23032, 995, 28671, 24976, 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فبينزل", "probability": 0.850830078125}, {"start": 538.31, "end": 538.97, "word": " التفاعل", "probability": 0.95703125}], "temperature": 1.0}, {"id": 24, "seek": 55609, "start": 539.21, "end": 556.09, "text": "سواء كان exothermic أو endothermic مش مشكلة كل هذا الكلام تقريبا شرحناه هذه ال slide اللي موجودة عندنا ربما أضفناها مافيش فيها أي إشي غير التأكيد على فكرة أنه لما يكون عنده", "tokens": [3794, 2407, 16606, 25961, 454, 802, 13195, 34051, 917, 802, 13195, 37893, 37893, 28820, 3660, 28242, 23758, 2423, 28820, 10943, 6055, 4587, 16572, 3555, 995, 13412, 2288, 5016, 8315, 3224, 29538, 2423, 4137, 13672, 1829, 3714, 29245, 23328, 3660, 43242, 8315, 12602, 3555, 15042, 5551, 11242, 5172, 8315, 11296, 19446, 41185, 8592, 8978, 11296, 36632, 11933, 8592, 1829, 32771, 13546, 16712, 10721, 4117, 25708, 15844, 6156, 4117, 25720, 14739, 3224, 5296, 15042, 7251, 30544, 43242, 3224], "avg_logprob": -0.13707386286227735, "compression_ratio": 1.5265957446808511, "no_speech_prob": 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reactions occurs with the primary alkyl halides due to electronic factors أسباب تتعلق بالإلكترونات وش .. لأ due to steric factor أسباب تتعلق بالفراغ بالوسع واضحة النقطة هذه؟ أه", "tokens": [40228, 22653, 45164, 47525, 7578, 5551, 7435, 1829, 3555, 23275, 14407, 8608, 33604, 6027, 20328, 5016, 4032, 32771, 1211, 9566, 8978, 2423, 10943, 2655, 5016, 7649, 5551, 39648, 24793, 21984, 5551, 3794, 19986, 1211, 2655, 2407, 12215, 11843, 365, 264, 6194, 419, 4133, 75, 7523, 1875, 3462, 281, 10092, 6771, 5551, 35457, 16758, 6055, 2655, 30241, 4587, 20666, 28814, 23275, 2655, 2288, 11536, 9307, 4032, 8592, 4386, 5296, 10721, 3462, 281, 18924, 299, 5952, 5551, 35457, 16758, 6055, 2655, 30241, 4587, 20666, 5172, 2288, 5718, 118, 20666, 41779, 3615, 4032, 46958, 5016, 3660, 28239, 47432, 3660, 29538, 22807, 5551, 3224], "avg_logprob": -0.22617574080382244, "compression_ratio": 1.4917355371900827, "no_speech_prob": 0.0, "words": [{"start": 685.41, "end": 685.83, "word": "يعني", "probability": 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bromide شايفينه؟ ويكون بالذات كمان ال nucleophile اضعيف يعني مش قادر يهاجم ولا له وسعي يهاجم", "tokens": [2304, 3615, 2423, 39184, 13955, 17, 5296, 33456, 3224, 19446, 41185, 8592, 44049, 38207, 4032, 3794, 3615, 5296, 33456, 3224, 8978, 16472, 3215, 14851, 13546, 4117, 6156, 995, 4117, 2655, 2288, 44945, 16606, 15844, 29910, 23275, 5296, 15042, 4724, 1829, 30544, 43242, 3224, 38726, 29104, 419, 4133, 75, 7523, 482, 30767, 1829, 23758, 9673, 31747, 3555, 13672, 1829, 31439, 38726, 29104, 457, 5088, 50134, 482, 13412, 995, 33911, 9957, 3224, 22807, 4032, 1829, 30544, 20666, 8848, 9307, 9122, 2304, 7649, 2423, 14962, 49242, 1975, 11242, 3615, 33911, 37495, 22653, 37893, 12174, 18513, 2288, 7251, 3224, 26108, 2304, 49429, 46740, 46952, 3615, 1829, 7251, 3224, 26108, 2304], "avg_logprob": -0.2962908967633114, "compression_ratio": 1.550420168067227, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 745.62, "end": 745.96, "word": "مع", "probability": 0.742919921875}, {"start": 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الماضية أعطيناكم ال SN2 reactions و أعطيناكم عليها شوية أشياء الان لما بدي أجي SN1 reactions و أبدأ أذكركم أفضل إشي بتمشي معه", "tokens": [6027, 20292, 39896, 29739, 9566, 1829, 19986, 3660, 2423, 2964, 1823, 33962, 9566, 2407, 3660, 16712, 7649, 10632, 6055, 5016, 9381, 26895, 11331, 33546, 1211, 2423, 7649, 20193, 5016, 19913, 14407, 20449, 1829, 16472, 16472, 2655, 14407, 34105, 5551, 9778, 3215, 2655, 14407, 20449, 1211, 20498, 9307, 9122, 2655, 48923, 44650, 30241, 28671, 20666, 13955, 16, 12215, 39894, 8848, 37983, 14407, 9673, 25720, 9673, 46958, 10632, 5551, 3615, 9566, 1829, 8315, 24793, 2423, 13955, 17, 12215, 4032, 5551, 3615, 9566, 1829, 8315, 24793, 25894, 11296, 13412, 2407, 10632, 5551, 8592, 1829, 16606, 2423, 7649, 5296, 15042, 4724, 16254, 5551, 7435, 1829, 13955, 16, 12215, 4032, 5551, 44510, 10721, 5551, 8848, 37983, 24793, 5551, 5172, 11242, 1211, 11933, 8592, 1829, 39894, 2304, 8592, 1829, 20449, 3224], "avg_logprob": -0.1820436575346523, "compression_ratio": 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activation energy بسيط و الخطوة الثانية صعبة إيش بعمللها؟ و التفاعل endothermic هاي خط ال reactance هذا الملحانة بيمثل هذه المواصفات هاي تفاعل من خطوتين هاي خطوة", "tokens": [28814, 1829, 8592, 41850, 12174, 995, 22488, 4724, 39648, 22807, 33962, 9566, 2407, 3660, 16247, 12610, 7578, 8608, 3224, 37977, 4724, 25957, 1211, 2423, 24433, 2281, 4724, 3794, 1829, 9566, 4032, 33962, 9566, 2407, 3660, 6024, 104, 7649, 10632, 20328, 3615, 49401, 11933, 1829, 8592, 4724, 25957, 1211, 1211, 11296, 22807, 4032, 16712, 5172, 995, 30241, 917, 802, 13195, 8032, 47302, 16490, 9566, 2423, 4515, 719, 23758, 9673, 1211, 5016, 7649, 3660, 4724, 32640, 12984, 1211, 29538, 9673, 2407, 33546, 5172, 9307, 8032, 47302, 6055, 5172, 995, 30241, 9154, 16490, 9566, 35473, 9957, 8032, 47302, 16490, 9566, 2407, 3660], "avg_logprob": -0.21171874970197677, "compression_ratio": 1.6813725490196079, "no_speech_prob": 0.0, "words": [{"start": 2025.93, "end": 2026.27, "word": "إيش", "probability": 0.6685791015625}, 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التانية fast الان مثل هذه المقارنة بنقدر نجيب عليها كام سؤال صح و غلط", "tokens": [29581, 1668, 8978, 11296, 12602, 38251, 1829, 11622, 1829, 8592, 1863, 4032, 8978, 2423, 43576, 30767, 1829, 18513, 3660, 8978, 11296, 39568, 518, 4032, 2423, 38726, 29104, 1975, 5172, 11242, 1211, 9154, 2423, 11396, 1975, 5172, 11242, 1211, 9154, 2423, 6194, 4032, 30767, 25708, 14407, 34105, 16472, 29538, 472, 1823, 4032, 29538, 732, 1823, 4032, 2423, 732, 4439, 13672, 1829, 34105, 42963, 12610, 3660, 2964, 16712, 7649, 10632, 2370, 2423, 7649, 50113, 1211, 29538, 9673, 4587, 9640, 1863, 3660, 44945, 28543, 2288, 8717, 7435, 1829, 3555, 25894, 11296, 9122, 10943, 8608, 33604, 6027, 20328, 5016, 4032, 32771, 1211, 9566], "avg_logprob": -0.25437500327825546, "compression_ratio": 1.6680497925311204, "no_speech_prob": 0.0, "words": [{"start": 2360.2, "end": 2360.64, "word": "first", "probability": 0.1251220703125}, {"start": 2360.64, "end": 2361.34, "word": " order", "probability": 0.91552734375}, {"start": 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\ No newline at end of file
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new file mode 100644
index 0000000000000000000000000000000000000000..9dd56785da8a5eee7c452d7405b57dabc04e43c6
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8.srt
@@ -0,0 +1,1489 @@
+1
+00:00:05,200 --> 00:00:09,580
+اليوم نحن في تفاعل الـ aldehydes والـ ketones
+
+2
+00:00:09,580 --> 00:00:15,280
+المرة الماضية حكينا شغل أساسية قلنا إنه في عندنا
+
+3
+00:00:15,280 --> 00:00:20,920
+تفاعل عام للـ aldehydes والـ ketones بيعتمد على
+
+4
+00:00:20,920 --> 00:00:26,940
+إنه الـ carbon تبعت الـ carbonyl group is an
+
+5
+00:00:26,940 --> 00:00:30,820
+electrophile يعني positive، واضح؟ سواء كانت
+
+6
+00:00:31,150 --> 00:00:35,190
+positive كامل أو كانت positive جزء في النهاية
+
+7
+00:00:35,190 --> 00:00:38,870
+بيصير عليها تفاعل الـ nucleophile التفاعل في شكل
+
+8
+00:00:38,870 --> 00:00:42,070
+عام للـ nucleophile لما بيتهاجم على الكربون الـ O
+
+9
+00:00:42,070 --> 00:00:47,930
+في نهاية بيصير OH، واضح؟ إذا التفاعل الأساسي
+
+10
+00:00:47,930 --> 00:00:54,500
+للالدهايتز والكيتون هو مهاجمة الـ nucleophile وزي
+
+11
+00:00:54,500 --> 00:00:58,900
+ما اتفقنا الـ O إيش بتصير؟ OH هذا الكلام أخدنا
+
+12
+00:00:58,900 --> 00:01:03,360
+مثال عليه هذا الكلام أخدنا مثال عليه في تفاعل
+
+13
+00:01:03,360 --> 00:01:07,920
+الميه وإن كان تفاعل الميه محدود يعني مش مع مراكبات
+
+14
+00:01:07,920 --> 00:01:11,900
+كثير بيصير اللي هي عملية إضافة الميه بنسميها
+
+15
+00:01:11,900 --> 00:01:16,360
+hydration فلما نضيف الميه هذه الـ OH اللي شايفينها
+
+16
+00:01:16,360 --> 00:01:22,040
+باللون الأحمر هي بتضيف وهذه ال Oxygen بتصير OH هذا
+
+17
+00:01:22,040 --> 00:01:26,920
+المركب اللي على نفسه اللي على نفس ال carbon فيه
+
+18
+00:01:26,920 --> 00:01:33,800
+مجموعتين OH بنسميه hydrate واضح مع ال formaldehyde
+
+19
+00:01:33,800 --> 00:01:38,600
+بيتكون و بيقولنا كمان بتكون مع ال chloral واضح
+
+20
+00:01:38,600 --> 00:01:42,160
+بيكون اسم هذا formaldehyde hydrate لو ال aldehyde
+
+21
+00:01:42,160 --> 00:01:47,380
+اللي عندي كان chloral بيكون chloral hydrate الآن
+
+22
+00:01:47,380 --> 00:01:54,290
+بدنا ناخد أمثلة تانية بس نغير فيهاللـ nucleophile
+
+23
+00:01:54,290 --> 00:01:59,610
+اللي بيهاجمها لكن نفس الشكل للتفاعل هنلاحظ أنه
+
+24
+00:01:59,610 --> 00:02:06,070
+بيستمر مثلا عملية إضافة ال alcohols ال alcohols R
+
+25
+00:02:06,070 --> 00:02:13,170
+O H واضح؟ لما بنضيف ال alcohol اللي هضيف can
+
+26
+00:02:13,170 --> 00:02:20,890
+nucleophile ال R O والـ CW.O بدأ تصير OH الان هنا
+
+27
+00:02:20,890 --> 00:02:25,810
+بتلاحظوا ان انتوا على carbon واحدة عندكم مجموعتين
+
+28
+00:02:25,810 --> 00:02:34,410
+وظيفيتين عندكم alcohol وعندكم ether هذه ال R C O
+
+29
+00:02:34,410 --> 00:02:38,210
+R او ال C O R هذا ether واضح؟
+
+30
+00:02:40,670 --> 00:02:44,450
+الالكهول الان هدولة المجمعتين الوظيفيتين موجودين
+
+31
+00:02:44,450 --> 00:02:48,350
+على كاربون واحدة ال ether والالكهول هذه التوليفة
+
+32
+00:02:48,350 --> 00:02:54,110
+او هذا الشكل بنقول عن المركب hemiacetal فال
+
+33
+00:02:54,110 --> 00:02:57,770
+hemiacetal هو المركب اللي على الكاربون الواحدة
+
+34
+00:02:57,770 --> 00:03:04,410
+موجود عند كحول وموجود ether بمعنى على الكاربون OR
+
+35
+00:03:04,410 --> 00:03:11,590
+وOH واضح؟ بناء على ذلك، لو افترضت مثلا انه انا كنت
+
+36
+00:03:11,590 --> 00:03:17,350
+بادي هنا بمجموعة مثل CH3 في هذه الحالة، شو هيكون
+
+37
+00:03:17,350 --> 00:03:21,010
+اسم ال الديهيد؟
+
+38
+00:03:21,010 --> 00:03:28,290
+أسيتالديهيد، بعد هيك لو ضفت عليه إيثانون، هيصير
+
+39
+00:03:28,290 --> 00:03:32,890
+أسيتالديهيد هيمي أسيتال of إيثانول، أنا بتحدد كمان
+
+40
+00:03:34,800 --> 00:03:40,720
+واضح فبصير acetaldehyde hemiacetal خلّيني أقول ال
+
+41
+00:03:40,720 --> 00:03:45,940
+hemiacetal في نهاية هو اسم عائلة زي ما الكحول اسم
+
+42
+00:03:45,940 --> 00:03:50,080
+عائلة و ال ether اسم عائلة و ال ketone اسم عائلة
+
+43
+00:03:50,080 --> 00:03:54,780
+فال hemiacetal بيظل اسم عائلة، العائلة فيها على
+
+44
+00:03:54,780 --> 00:04:02,580
+الكربون الواحدة OH و OR هذا التفاعل واضح تماما أنه
+
+45
+00:04:02,580 --> 00:04:06,560
+تفاعل addition ليش تفاعل addition لأنه أنا على ال
+
+46
+00:04:06,560 --> 00:04:09,720
+double bond لما تيجي و انت تتطلع هذه كانت double
+
+47
+00:04:09,720 --> 00:04:15,820
+bond ضفت OR وضفت H وحولت ال double إلى single
+
+48
+00:04:15,820 --> 00:04:20,180
+bond وبناء على ذلك هذا التفاعل هو تفاعل addition
+
+49
+00:04:20,840 --> 00:04:27,580
+الآن إذا كان عندي الكحول موجود بنسبة كبيرة .. إذا
+
+50
+00:04:27,580 --> 00:04:31,960
+الكحول عندي موجود بنسبة كبيرة بيصير تفاعل ثاني
+
+51
+00:04:31,960 --> 00:04:36,640
+إضافي بعد ما نخلص تفاعل ال addition بتيجي الكمية
+
+52
+00:04:36,640 --> 00:04:43,430
+الإضافية من الكحول بتهاجم هنا وبتطرد ال OH لاحظوا
+
+53
+00:04:43,430 --> 00:04:47,570
+هنا مجموعة اجت ومجموعة طلعت إذا إيش هذا التفاعل
+
+54
+00:04:47,570 --> 00:04:53,570
+إبدال مجموعة بتحل محل مجموعة substitution فبصير
+
+55
+00:04:53,570 --> 00:04:59,770
+عند مدل ال OH و OR في هذه الحالة صار عند مركب على
+
+56
+00:04:59,770 --> 00:05:05,050
+نفس ال carbon مجمعتين ether يعني على ال carbon OR
+
+57
+00:05:05,050 --> 00:05:12,430
+و OR هذه العائلة بنسميها acetal إذا أنا في عندي
+
+58
+00:05:12,430 --> 00:05:17,390
+hemacetal يعني نص أسيتال لأنه OR واحدة والثانية OH
+
+59
+00:05:17,390 --> 00:05:24,230
+وفي عندي أسيتال كامل الأسيتال الكامل OR و OR واضح
+
+60
+00:05:24,230 --> 00:05:29,430
+بنصير كام مرة اتفاعل الكحول مرتين الآن هنا بدكم
+
+61
+00:05:29,430 --> 00:05:37,720
+تنتبهوا جيدا لتوصيف التفاعل الخطوة
+
+62
+00:05:37,720 --> 00:05:41,280
+الأولى لما بدنا نتكلم عنها ال formation of
+
+63
+00:05:41,280 --> 00:05:47,580
+hemiacetal is in nucleophilic addition reaction
+
+64
+00:05:48,700 --> 00:05:53,880
+واضح؟ لما أنا بدأت أسألكم تكوين الـ hemiacetal هل
+
+65
+00:05:53,880 --> 00:05:57,460
+هو a nucleophilic addition reaction ولا
+
+66
+00:05:57,460 --> 00:06:01,380
+substitution reaction؟ a nucleophilic addition
+
+67
+00:06:01,380 --> 00:06:06,720
+reaction لكن ال formation of acetal from
+
+68
+00:06:06,720 --> 00:06:14,420
+hemiacetal acetal from hemiacetal is a
+
+69
+00:06:14,420 --> 00:06:16,400
+substitution reaction
+
+70
+00:06:18,100 --> 00:06:21,900
+واضح؟ إذا أنا لما بحول الهيمي أسيتال لأسيتال بعمل
+
+71
+00:06:21,900 --> 00:06:26,100
+إبدال لما بحول ال الديهايد أو الكيتون لهيمي أسيتال
+
+72
+00:06:26,100 --> 00:06:30,700
+بعمل إضافة الآن لو أنا كنت بدأ اتفلسف أكثر عليكم و
+
+73
+00:06:30,700 --> 00:06:37,260
+اجي أسألكم أقول لكم تكوين الأسيتال من ال الديهايد أو
+
+74
+00:06:37,260 --> 00:06:44,680
+الكيتون هو عبارة عن عمليتين متتابعتين الأولى
+
+75
+00:06:45,710 --> 00:06:50,630
+addition والثانية substitution واضح فبتكونوا
+
+76
+00:06:50,630 --> 00:06:54,250
+دقيقين في توصيف هذه العملية أول شيء بيصير عندي
+
+77
+00:06:54,250 --> 00:06:58,650
+addition to form the hemiacetal then substitution
+
+78
+00:06:58,650 --> 00:07:03,860
+of the OH to form the acetal واضحة هذه الفكرة، هذا
+
+79
+00:07:03,860 --> 00:07:08,400
+الكلام بيعتمد على قداش أنا عندي كمية كحول، بمعنى
+
+80
+00:07:08,400 --> 00:07:12,540
+لو حطيت الكحول بنسبة واحد إلى واحد فقط هيتكون عندي
+
+81
+00:07:12,540 --> 00:07:17,120
+ال hemiacetal لو حطيت بنسبة اثنين إلى واحد أو أكثر
+
+82
+00:07:17,120 --> 00:07:20,880
+هيتكون عندي في النهاية ال acetal
+
+83
+00:07:31,600 --> 00:07:38,260
+ممكن الكحول والالديهيد يكونوا موجودين في داخل جزء
+
+84
+00:07:38,260 --> 00:07:43,360
+واحد يعني لاحظوا في المثال السابق الكحول عبارة عن
+
+85
+00:07:43,360 --> 00:07:48,340
+جزء والالديهيد جزء منفصلين وبيجوا يتفاعلوا مع بعض
+
+86
+00:07:48,340 --> 00:07:54,420
+الآن لو كان عندي مثل هذا المركب مثلا واضح؟ اللي هو
+
+87
+00:07:54,420 --> 00:07:58,780
+الـ 5-hydroxybenthanol نعرف كيف نسميه، هاي واحد،
+
+88
+00:07:58,780 --> 00:08:01,640
+اثنين، ثلاثة، أربعة، خمسة، هذا penthanol على
+
+89
+00:08:01,640 --> 00:08:06,020
+مجموعة خمسة إيش عندكم؟ OH إذًا هذا 5
+
+90
+00:08:06,020 --> 00:08:10,180
+-hydroxybenthanol الآن لاحظوا هنا، في عند ال
+
+91
+00:08:10,180 --> 00:08:14,080
+الديهايد وفي عند ال OH تبع الكحول اللي بدأت تتفاعل
+
+92
+00:08:14,080 --> 00:08:18,620
+وعشان كذا لما بنعمله بـ H plus يعني في وجود حامض
+
+93
+00:08:19,160 --> 00:08:23,020
+ممكن التفاعل يحدث في داخل الجزء، بنسميه
+
+94
+00:08:23,020 --> 00:08:29,120
+Intramolecular Intramolecular إن المتفاعلين يكونوا
+
+95
+00:08:29,120 --> 00:08:36,260
+داخل الجزء، مش يجي الألديهيد قطعة والألكوهول قطعة
+
+96
+00:08:36,260 --> 00:08:40,900
+ثانية، لا هنا التلتين موجودات في داخل الجزء فبتعمل
+
+97
+00:08:40,900 --> 00:08:46,420
+تفاعل وهذا بتصير OH
+
+98
+00:08:48,710 --> 00:08:53,310
+اللي هو تكوين الـ hemiacetal هذا التفاعل اللي بيكون
+
+99
+00:08:53,310 --> 00:08:57,050
+المتفاعلين تبعه في داخل الجزء شو بنسميه؟
+
+100
+00:08:57,050 --> 00:09:01,970
+Intramolecular within the molecule لكن لما أنا
+
+101
+00:09:01,970 --> 00:09:05,970
+بجيب جزيئين منفصلين يتفاعلوا مع بعض شو بوصف
+
+102
+00:09:05,970 --> 00:09:12,550
+التفاعل؟ Intermolecular فبيتميزوا ما بين تفاعل زي
+
+103
+00:09:12,550 --> 00:09:16,290
+هذا Intramolecular
+
+104
+00:09:17,300 --> 00:09:22,980
+إن الرأسين المتفاعلين في داخل الجزيئة وعندما أحضر
+
+105
+00:09:22,980 --> 00:09:27,440
+جزيئين X و Y ويتفاعلوا مع بعض هما مفصلين هذا
+
+106
+00:09:27,440 --> 00:09:32,800
+التفاعل شو بنسميه Intermolecular وهذا مصطلح دائما
+
+107
+00:09:32,800 --> 00:09:33,900
+نستعمله
+
+108
+00:09:35,940 --> 00:09:40,020
+التفاعل فيه عند Intramolecular و Intermolecular
+
+109
+00:09:40,020 --> 00:09:44,700
+ففي هذا المثال لما بنوجد الـ OH والـ aldehyde
+
+110
+00:09:44,700 --> 00:09:48,360
+بتفاعلوا مع بعض ولو إنهم الاثنين موجودين في جزء
+
+111
+00:09:48,360 --> 00:09:51,820
+واحد هيعطينا اللي هو الـ ether مع الـ OH
+
+112
+00:09:51,820 --> 00:09:56,460
+- hemiacetal واضح؟ فبتكون عندنا اللي هو
+
+113
+00:09:56,460 --> 00:10:01,680
+الـ hemiacetal-O5-Hydroxybintanate هذا الحقيقة
+
+114
+00:10:01,680 --> 00:10:06,380
+التفاعل بالذات هذا يعتبر مهم كثير يعتبر مهم كثير
+
+115
+00:10:06,380 --> 00:10:11,040
+ليش مهم؟ لأنه لما تدرسوا أنتم في ال biochemistry
+
+116
+00:10:11,040 --> 00:10:19,660
+هتأخذوا تركيب الجلوكوز الجلوكوز عبارة عن 6 ذرات
+
+117
+00:10:19,660 --> 00:10:26,000
+كربون موجود فيهم موجود فيهم الديهيد وموجود و H
+
+118
+00:10:26,000 --> 00:10:33,540
+وكتار وبيكون مرات بشكل acyclic يعني فاتح ومرات
+
+119
+00:10:33,540 --> 00:10:41,510
+بشكل cyclic أي cyclic يعني؟ مش حلقي non-cyclic أي
+
+120
+00:10:41,510 --> 00:10:47,590
+تبعته؟ أيش هذه؟ النفة مش ال a بتيجي حرف نفة a
+
+121
+00:10:47,590 --> 00:10:52,530
+-cyclic asymmetric يعني غير متماثل غير حلقي فبيكون
+
+122
+00:10:52,530 --> 00:10:57,370
+مرات بالشكل الفاتح وبيكون مرات بالشكل المسكر وهذا
+
+123
+00:10:57,370 --> 00:11:04,240
+الأزال موجود في السكريات وموجود في الجلوكوز فبهذا
+
+124
+00:11:04,240 --> 00:11:08,960
+الشكل بيصير هذا التفاعل بالنسبة لنا تفاعل مهم واضح
+
+125
+00:11:08,960 --> 00:11:12,960
+لأن أحد التفاعلات اللي بتأخذوها بالتفصيل في
+
+126
+00:11:12,960 --> 00:11:16,260
+الكيميا الحيوية بيصير عند هذا الجلوكوز طبعا
+
+127
+00:11:16,260 --> 00:11:20,440
+هتتعلموا كيف تسمو إيش معنى بيتا وإيش معنى دي إيش
+
+128
+00:11:20,440 --> 00:11:25,230
+لوكوبيرانوس كل هذا الكلام وين ما كان في course
+
+129
+00:11:25,230 --> 00:11:29,330
+Biochemistry على الـ Carbohydrate لكن أهم شيء
+
+130
+00:11:29,330 --> 00:11:33,510
+عندنا الآن أنه مثل هذا التفاعل بالضبط هو اللي
+
+131
+00:11:33,510 --> 00:11:38,110
+بيصير لما بتتم عملية الإغلاق للجلوكوز هو تفاعل
+
+132
+00:11:38,110 --> 00:11:43,970
+hemiacetal formation تفاعل تكوين hemiacetal
+
+133
+00:11:43,970 --> 00:11:47,270
+Intramolecular hemiacetal formation
+
+134
+00:11:54,130 --> 00:12:00,390
+ممكن واجهنا الموضوع بصورة ثانية احنا قلنا لو بدنا
+
+135
+00:12:00,390 --> 00:12:06,450
+نضيف كحول واحد بيصير عندنا hemiacetal لما نكمل كمان
+
+136
+00:12:06,450 --> 00:12:11,690
+كحول بيصير acetal الآن لاحظوا في مثل هذا التفاعل
+
+137
+00:12:11,690 --> 00:12:16,770
+يعني لو فعلنا ال acetone مع ال ethylene glycol هذا
+
+138
+00:12:16,770 --> 00:12:25,090
+كيتون ال ethylene glycol هو حقيقة diol يعني في
+
+139
+00:12:25,090 --> 00:12:30,670
+مجموعتين alcohol ألاحظون؟ في مجموعتين OAC يعني
+
+140
+00:12:30,670 --> 00:12:36,410
+كأنه بيمثل diol بناء على ذلك هذا الـ
+
+141
+00:12:36,410 --> 00:12:40,290
+ethylene glycol لو اجا بده يتفاعل بيتفاعل على
+
+142
+00:12:40,290 --> 00:12:44,810
+مرتين بيكوّن في المرة الأولى يعني بإمكاننا نتطلع
+
+143
+00:12:44,810 --> 00:12:48,110
+احنا أنه في المرة الأولى هذه تيجي تتفاعل وهذا تصير
+
+144
+00:12:48,980 --> 00:12:59,640
+هذه الحالة ستعطيك حالة وثيقة OH وهنا OH ثم
+
+145
+00:12:59,640 --> 00:13:05,780
+التفاعل الأول اللي هو كحول مع الكيتون أعطانا
+
+146
+00:13:05,780 --> 00:13:12,400
+hemiacetal الآن لأن الـ OH الثانية موجودة تكمل
+
+147
+00:13:12,400 --> 00:13:19,310
+التفاعل substitution بتكون ال acetal فهنا مجموعتين ال
+
+148
+00:13:19,310 --> 00:13:24,150
+OH موجودين في جزء واحد قبل شوية لما أخذنا الفكرة
+
+149
+00:13:24,150 --> 00:13:28,270
+العامة كنا نقول إنه two alcohol molecules react
+
+150
+00:13:28,270 --> 00:13:32,730
+the first one and then the second one الآن اللي
+
+151
+00:13:32,730 --> 00:13:39,260
+قاعد بيصير إن هذا الجزء نفسهموجود فيه مجموعتين
+
+152
+00:13:39,260 --> 00:13:43,240
+ألكوهول فبتفاعلوا بشكل متتالي أول تفاعل بتفاعل
+
+153
+00:13:43,240 --> 00:13:49,020
+واحدة منهم وبتعمل addition هذه العملية بهذا الشكل
+
+154
+00:13:49,020 --> 00:13:54,380
+هي عملية إيش addition وبعد هيك لما بدأت العملية
+
+155
+00:13:54,380 --> 00:14:02,740
+الثانية substitution إبدال فبتكون عندنا ال acetone
+
+156
+00:14:02,740 --> 00:14:08,410
+ليش acetone؟ لأن هذا أصلا جاي من الأسيتون إيثيلين
+
+157
+00:14:08,410 --> 00:14:13,990
+غلايكول acetal لما بنيجي نسميه على الشقين تبعونه
+
+158
+00:14:13,990 --> 00:14:20,170
+هذا الجزء كان اسيتون هذا الجزء كان إيثيلين غلايكول
+
+159
+00:14:20,170 --> 00:14:27,030
+فصار عند اسيتون إيثيلين غلايكول acetal ليش acetal؟
+
+160
+00:14:27,030 --> 00:14:32,830
+لأنه متصل ب OR و ب OR لكن مثل هذا المركب لو كنتوا
+
+161
+00:14:32,830 --> 00:14:37,690
+بتكونوا تسموه، شو هتسموه؟ هتقولوا اسيتون، هاي جزء
+
+162
+00:14:37,690 --> 00:14:44,750
+الاسيتون، إيثيلين غلايكول، hemiacetal لأن هذا متصل
+
+163
+00:14:44,750 --> 00:14:51,300
+في الكاربون OH و OR هذا hemiacetal فهي ال acetone
+
+164
+00:14:51,300 --> 00:14:55,780
+إيثيلين جلايكول hemiacetal هداك acetone إيثيلين
+
+165
+00:14:55,780 --> 00:15:03,820
+جلايكول acetal كامل لا
+
+166
+00:15:03,820 --> 00:15:08,840
+لا لا نسبة لأبوه
+
+167
+00:15:12,530 --> 00:15:17,890
+نسبة لأبوه خلينا نوضح السؤال اللي بتسأله زميلتكم ..
+
+168
+00:15:17,890 --> 00:15:23,870
+السؤال اللي بتسأله زميلتكم كثير أشياء .. كثير أشياء
+
+169
+00:15:23,870 --> 00:15:31,030
+بتتسمى .. بتتسمى في الدنيا نسبة للأصل وكثير أشياء
+
+170
+00:15:31,030 --> 00:15:38,150
+في الدنيا بتتسمى نسبة للفرع واضح؟ يعني الأشياء ممكن
+
+171
+00:15:38,150 --> 00:15:44,390
+تتسمى نسبة للأصل والأشياء يمكن أن تسمى أيضا نسبة
+
+172
+00:15:44,390 --> 00:15:51,050
+لإيش؟ للفرع حسب ما بده الإنسان .. حسب ما بده
+
+173
+00:15:51,050 --> 00:15:56,190
+الإنسان يوضح شيء معين، يعني هذا .. هذا المفهوم
+
+174
+00:15:56,190 --> 00:16:02,130
+بالحياة شوية بنطلع عن الكيميا، يعني مثلا عائلة ..
+
+175
+00:16:02,130 --> 00:16:06,910
+عائلة محترمة، خلينا هيك نحكي، عائلة محترمة، لها
+
+176
+00:16:06,910 --> 00:16:13,490
+ابن .. لها ابن بيروح اللي هو بده يشتغل في مهنة غير
+
+177
+00:16:13,490 --> 00:16:18,050
+جائزة شرعان، مهنة محرمة، بدو يشتغلوا في مصنع خمرة
+
+178
+00:16:18,0
+
+201
+00:18:20,360 --> 00:18:25,910
+الإيثيلين لما عملنا منه polymer في وجود ال ROR
+
+202
+00:18:25,910 --> 00:18:30,330
+البروكسايد الـ free radical polymerization شو صار
+
+203
+00:18:30,330 --> 00:18:41,140
+عندي صار عندي CH2 CH2 to the N من الإيثيلين في الـ
+
+204
+00:18:41,140 --> 00:18:44,660
+polymer ولا راحت الـ double bond؟ راحت طب إيش
+
+205
+00:18:44,660 --> 00:18:49,700
+سميناها؟ poly.. polyethylene ولا polyethylene؟
+
+206
+00:18:49,700 --> 00:18:54,040
+polyethylene على الأصل فكل هذه المركبات مسمية على
+
+207
+00:18:54,040 --> 00:18:54,940
+الأصل
+
+208
+00:18:59,340 --> 00:19:04,780
+فاحنا كثير بنسمي شغلات على الأصل اللي اجت منه،
+
+209
+00:19:04,780 --> 00:19:09,280
+كثير بنسمي شغلات على الأصل اللي اجت منه، نفس الشيء
+
+210
+00:19:09,280 --> 00:19:12,660
+هنا لو بدك تجي تقولي ليش هذا سميته، هو هذا ضايل
+
+211
+00:19:12,660 --> 00:19:13,500
+الأسيتون
+
+212
+00:19:16,340 --> 00:19:20,640
+هذا ضايل أسيتون وهذا ضايل إيثيلين جلايكول بهذا
+
+213
+00:19:20,640 --> 00:19:24,520
+الشكل هذه أسيتون وهذه إيثيلين جلايكول بس هذه القطعة
+
+214
+00:19:24,520 --> 00:19:27,780
+جاية من أسيتون وهذه القطعة جايه من إيثيلين جلايكول
+
+215
+00:19:27,780 --> 00:19:33,820
+فسمينا كله أسيتون نسبة للأصل إيثيلين جلايكول نسبة 
+
+216
+00:19:33,820 --> 00:19:43,240
+للأصل أو أسيتون واضح؟ فكثير احنا بنسمي نسبة
+
+217
+00:19:44,100 --> 00:19:51,180
+للأصل و مرات بنسمي نسبة للفرع والأمثلة في ذلك في
+
+218
+00:19:51,180 --> 00:19:52,400
+العلوم الإنسانية
+
+219
+00:19:59,860 --> 00:20:04,980
+هنا عندكم مجموعة إثرائية من الأمثلة مجموعة إثرائية
+
+220
+00:20:04,980 --> 00:20:10,400
+من الأمثلة لاحظوا مثلا في المثال الأول مش كله يعني
+
+221
+00:20:10,400 --> 00:20:14,980
+ضروري احنا نتطلع عليها لأنه المفروض أنه تتدربوا في
+
+222
+00:20:14,980 --> 00:20:19,020
+البيت تكتبوا الشغل ولاحظوا يعني دائما في الـ organ
+
+223
+00:20:19,020 --> 00:20:23,420
+الـ chemistry مشكلة .. مشكلة عند الطلاب لما يدرسوا
+
+224
+00:20:23,420 --> 00:20:29,310
+الكيميا من slides و بس بيقرأها في الليل واضحة بيجي
+
+225
+00:20:29,310 --> 00:20:32,110
+في الامتحان بيده يعيد كتابة شغلة بيلاقي حاله
+
+226
+00:20:32,110 --> 00:20:35,410
+ما بيعرفش يكتب انا كثير كان عندي احساس وانا بصلح
+
+227
+00:20:35,410 --> 00:20:39,150
+الامتحان لكوا ولا غيركوا ان انتوا فاهمين تماما
+
+228
+00:20:39,150 --> 00:20:45,610
+لكن ولا مرة اجيتوا وطبقتوا بالورقة والقلم و
+
+229
+00:20:45,610 --> 00:20:48,590
+عدتوا الشغلة تلات مرات لحد ما أتقنتوا انكم بتقدروا
+
+230
+00:20:48,590 --> 00:20:51,410
+ترسموها عشان هيك الشغلة اللي فاهمينها ما قدرتوش
+
+231
+00:20:51,410 --> 00:20:57,130
+يتعبروا وما قدرتوش يتعبروا عنها ودائما انا يعني بذكر
+
+232
+00:20:57,130 --> 00:21:01,390
+مقولة أستاذي ويمكن حكيتهلكوا اياها الدكتور عادي
+
+233
+00:21:01,390 --> 00:21:04,230
+الجرار علمناه في الجامعة الأردنية كان يقولنا
+
+234
+00:21:04,230 --> 00:21:08,430
+الكيميائي الشاطر هو الكيميائي اللي عن يمينه ورق
+
+235
+00:21:08,430 --> 00:21:14,810
+خرطوش وعن شماله سلة محملات وكل شغلة بيكتب و
+
+236
+00:21:14,810 --> 00:21:20,610
+بيرمي بيكتب و بيرمي بتصير الإيد تبعته متعودة إنها
+
+237
+00:21:20,610 --> 00:21:28,080
+تنفذ ما بعد ذلك خلاص هو بده يحتفظ بالورق بيستعمل
+
+238
+00:21:28,080 --> 00:21:33,740
+الخبز ولا إيش ما كان واضح؟ الآن لاحظوا هذا المثال
+
+239
+00:21:33,740 --> 00:21:37,760
+أي مثال من هدول كان ممكن نجيب الكياب بسهولة في
+
+240
+00:21:37,760 --> 00:21:41,860
+امتحان بس المهم أنه لازم تكتبوا بيدكم عشان تتقنوا
+
+241
+00:21:41,860 --> 00:21:45,840
+الـ organ chemistry هنا عندي الديهيد مع two
+
+242
+00:21:45,840 --> 00:21:50,910
+alcohols شو اللي بده يتكون عندي في هذه الحالة الـ
+
+243
+00:21:50,910 --> 00:21:56,330
+final product أسيتال بمعنى هتصير OR و الـ OH
+
+244
+00:21:56,330 --> 00:22:00,650
+التانية برضه هتصير OR Oethyl و Oethyl هي شكل
+
+245
+00:22:00,650 --> 00:22:07,450
+الأسيتال هي شكل الأسيتال هنا عندي مثال شبيه في
+
+246
+00:22:07,450 --> 00:22:11,910
+اللي حكيناه قبل شوي Cyclohexanone كيتون وهذا
+
+247
+00:22:13,750 --> 00:22:19,790
+ethylene glycol هيتفاعل مرتين إذا هانا هيعمل O O
+
+248
+00:22:19,790 --> 00:22:24,010
+بهذا الشكل الآن صدقوني هذه إذا في المثال السابق
+
+249
+00:22:24,010 --> 00:22:28,170
+وفي هذا المثال ما دربتوش ايدكم عليها بسهولة لو
+
+250
+00:22:28,170 --> 00:22:32,250
+اجتكم في الامتحان مش هتعرفوا ترسموها رغم أنه واضح
+
+251
+00:22:32,250 --> 00:22:40,130
+أن نتيل الـ OH's يتفاعلوا ورا بعض واضح؟ هانا إيش
+
+252
+00:22:40,130 --> 00:22:41,850
+المثال إذا بتلاحظوا
+
+253
+00:22:46,590 --> 00:22:53,810
+هذا مثال مزدوج .. هذا مثال مزدوج في عندي ketone و
+
+254
+00:22:53,810 --> 00:23:00,130
+في عندي OH إيش بتعمل الـ OH هذه؟ بدها تعمل
+
+255
+00:23:00,130 --> 00:23:05,150
+intramolecular reaction طبعا تحاولوا تسكروا المركب
+
+256
+00:23:05,150 --> 00:23:11,710
+حيصير هذا O وهذا الـ O تتحول إلى OH بعد هي تلاحظوا
+
+257
+00:23:11,710 --> 00:23:17,430
+إيش ضاف؟ ضاف كمان كحول خارج يعني كأنه في هذه
+
+258
+00:23:17,430 --> 00:23:21,490
+المسألة عمل كحول داخل اللي هو أول تفاعل الـ
+
+259
+00:23:21,490 --> 00:23:27,210
+formation of hemiacetal من الـ OH الداخلية اتفاعلت
+
+260
+00:23:27,210 --> 00:23:31,310
+بعد هيك راح جاب كحول من الخارج methanol الميثانول
+
+261
+00:23:31,310 --> 00:23:38,250
+حل محل الـ OH فأعطانا هذا المركب بعرفش إذا واضح ولا
+
+262
+00:23:38,250 --> 00:23:45,300
+بيلزم نعمله تفصيل إضافة واضح هذا المثال؟ تطلعوا
+
+263
+00:23:45,300 --> 00:23:49,660
+مرات وين بتصير المشكلة .. مرات وين بتصير المشكلة
+
+264
+00:23:49,660 --> 00:23:54,860
+أنه كيف ارتب الأشياء بحيث تكون المتفاعلات جايه
+
+265
+00:23:54,860 --> 00:23:59,760
+بشكل قريب على بعضها البعض، يعني نفس هذا .. نفس هذا
+
+266
+00:23:59,760 --> 00:24:05,040
+اللي موجود هنا، لو أنا كتبته بهذه الصيغة CH3 C
+
+267
+00:24:05,040 --> 00:24:07,180
+double bond O وبعدين عملت 
+
+268
+00:24:14,200 --> 00:24:18,520
+هذا نفس هذا كاربون اتنين تلاتة اربعة خمسة كاربون
+
+269
+00:24:18,520 --> 00:24:22,000
+اتنين تلاتة اربعة خمسة وحاملة أو اتش وهذا ممكن
+
+270
+00:24:22,000 --> 00:24:27,520
+نخليه هكذا بشكل انا انا صار واضح عندي ان هاي
+
+271
+00:24:27,520 --> 00:24:33,400
+الكحول وهاي كيتون بناء على ذلك شو التفاعل اللي
+
+272
+00:24:33,400 --> 00:24:39,040
+احنا بنتوقعه في هذه الحالة ان هذه بتهاجم هنا وهذه
+
+273
+00:24:40,430 --> 00:24:44,770
+بنتيجة هنا تصير OH فالنتج اللي بده يتكون بهذه
+
+274
+00:24:44,770 --> 00:24:52,910
+الحالة كنتج مرحلة في نص الطريق هذه
+
+275
+00:24:52,910 --> 00:25:04,480
+CH3 وهذه OH إذا هذا التفاعل عمل هيمي أسيتال هذا
+
+276
+00:25:04,480 --> 00:25:09,520
+التفاعل عمل هيمي أسيتال الآن راحوا لحقوا هذا
+
+277
+00:25:09,520 --> 00:25:13,960
+التفاعل بتفاعل ثاني فعلوه كمان مرة مع الميثانول
+
+278
+00:25:15,000 --> 00:25:19,980
+ماذا تفعل الميثانول؟ تحل محل الـ OH وتطرد الـ OH و
+
+279
+00:25:19,980 --> 00:25:23,860
+تحل محلها وتظهر النتج اللي عندكم إذا النتج اللي
+
+280
+00:25:23,860 --> 00:25:28,900
+عندكم هو نتاج خطوتين حقيقة التفاعل الأول اللي هو
+
+281
+00:25:28,900 --> 00:25:33,760
+الـ intramolecular reaction to form the hemiacetal
+
+282
+00:25:33,760 --> 00:25:38,540
+وبعد هيك الـ substitution reaction to form the
+
+283
+00:25:38,540 --> 00:25:44,060
+acetal أول تفاعل Intramolecular هي الـ OH والـ C
+
+284
+00:25:44,060 --> 00:25:48,160
+double bond O في نفس الجزيء Intramolecular هذا
+
+285
+00:25:48,160 --> 00:25:51,720
+بنوصفه مظبوط ولا لا؟ بعد ذلك التفاعل التالي لما
+
+286
+00:25:51,720 --> 00:25:56,720
+اجيب هذا كله جزيء والميثانول جزيء This is
+
+287
+00:25:56,720 --> 00:26:01,500
+intermolecular reaction
+
+288
+00:26:01,500 --> 00:26:05,360
+واضح المثال هذا؟
+
+289
+00:26:08,510 --> 00:26:15,310
+بس بالتأكيد بيلزم تتدربوا عليه الآن المثال اللي
+
+290
+00:26:15,310 --> 00:26:24,930
+بعده شوية بدون ورقة وقلم انا بأكدلكوا أنه صعب
+
+291
+00:26:24,930 --> 00:26:29,550
+انكم تصلوله يعني لاحظوا كيف مرات الأمثلة بتكون
+
+292
+00:26:29,550 --> 00:26:36,050
+موجودة ومرسومة وإيش الناتج كيف هذا الناتج طلع من
+
+293
+00:26:36,050 --> 00:26:42,690
+هذا المثال انا حقيقة بهذا المثال وببساطة عندي C
+
+294
+00:26:42,690 --> 00:26:51,330
+double bond O وعندي نتين OH OH إذا هيتم تفاعل على
+
+295
+00:26:51,330 --> 00:26:57,770
+مرتين مرة مع الـ OH الأولى ويعمل لي هيمي أسيتال ومرة
+
+296
+00:26:57,770 --> 00:27:03,230
+مع الـ OH الثانية ويعمل أسيتال فقط اللي بيلزم فقط
+
+297
+00:27:03,230 --> 00:27:07,670
+اللي بيلزم عاد كيف نكون مرتبين الجزء بحيث نعمله
+
+298
+00:27:08,400 --> 00:27:12,480
+بالشكل الناتج اللي هو انا الحلقة ثانية يعني لو
+
+299
+00:27:12,480 --> 00:27:16,880
+أخدنا هذه الـ carbon لو أخدنا هذه الـ carbon اللي هي
+
+300
+00:27:16,880 --> 00:27:23,240
+الرابطة بالـ bond الرابطة بالـ bond O بهذا الشكل بعد
+
+301
+00:27:23,240 --> 00:27:27,080
+ذلك بدنا نتحرك بشكل متعاكس عشان نحط باقي الـ carbon
+
+302
+00:27:27,080 --> 00:27:31,620
+كم carbon عندي غيرها؟ واحد اتنين تلاتة اربعة والـ
+
+303
+00:27:31,620 --> 00:27:43,850
+O هاي واحد اتنين تلاتة اربعة وهنا الـ O هي O H هي ده
+
+304
+00:27:43,850 --> 00:27:50,630
+الجزء الآن على الجهة الثانية على
+
+305
+00:27:50,630 --> 00:27:54,710
+الجهة الثانية كم carbon عندي برضه اربعة واحد
+
+306
+00:27:54,710 --> 00:28:02,010
+اتنين تلاتة اربعة و
+
+307
+00:28:02,010 --> 00:28:02,830
+الـ O هذه
+
+308
+00:28:08,700 --> 00:28:15,980
+أو اتش هذا نفس هذا بس غيرنا طريقة الرسم الآن لو
+
+309
+00:28:15,980 --> 00:28:19,220
+كنتوا تقولوا كيف تم التفاعل وممكن هذه عشان كمان
+
+310
+00:28:19,220 --> 00:28:24,580
+المنظر اللي خليكي بشكل مستقيم هاي أو اتش كيف بتم
+
+311
+00:28:24,580 --> 00:28:31,160
+التفاعل أول تفاعل هذه الـ أو اتش بتهاجم هنا وهذه
+
+312
+00:28:31,160 --> 00:28:36,660
+بتصير أو اتش ثاني تفاعل نعمله باللون الأزرق، هاي
+
+313
+00:28:36,660 --> 00:28:42,020
+أول تفاعل صار واضح، ثاني تفاعل هذه الـ OH بتهاجم
+
+314
+00:28:42,020 --> 00:28:49,620
+هنا وبتطرد كل الـ OH اللي اتكونت هنا، صار النتيجة
+
+315
+00:28:52,470 --> 00:28:57,590
+هذا هو نفس هذا فقط طريقة الرسم اختلفت عندكم OH
+
+316
+00:28:57,590 --> 00:29:02,510
+بدأت تتفاعل لأول مرة و OH بدأت تتفاعل لثاني مرة
+
+317
+00:29:02,510 --> 00:29:07,150
+التفاعل على إيش؟ على مرتين هذه الـ OH لما تتفاعل
+
+318
+00:29:07,150 --> 00:29:11,250
+بيصير عندها hemacetal التفاعل اللي ماشرله بالأحمر
+
+319
+00:29:11,250 --> 00:29:16,150
+بتيجي الـ OH الثانية بتطرد الـ OH الأولى بتكون عند
+
+320
+00:29:16,150 --> 00:29:18,870
+الـ acetal بيصير عند هذا المركب
+
+321
+00:29:22,460 --> 00:29:30,940
+آخر تفاعل سهل وبسيط بدل ما كان عندي ethylene
+
+322
+00:29:30,940 --> 00:29:38,880
+glycol OH OH ممكن استعمل الـ thio compound اللي هو بدل
+
+323
+00:29:38,880 --> 00:29:46,120
+الـ OH SH SH ما هي الـ SH والـ OH بيتفاعلوا زي بعض
+
+324
+00:29:46,120 --> 00:29:51,600
+الآن كيف هذا التفاعل هنا تنتهي الـ OHS أعطانا هذا
+
+325
+00:29:51,600 --> 00:29:55,100
+النتج تفاعله على مرتين نفس الشيء الـ SH هاتيجي
+
+326
+00:29:55,100 --> 00:30:01,820
+تتفاعل هنا SS ولما يكون عنده جزئين هيتفاعلوها
+
+327
+00:30:01,820 --> 00:30:10,460
+هيتفاعلوها ملاحظين هاي هذا الجزء زي هذا الجزء
+
+328
+00:30:10,460 --> 00:30:16,480
+تماماً فقط الـ oxygen بدل ما هي oxygen صارت sulfur
+
+329
+00:30:16,480 --> 00:30:21,520
+الآن عندنا C double bond O ثاني على الجهة هذه بنكرر
+
+330
+00:30:21,520 --> 00:30:28,860
+التفاعل على الجهة الثانية، واضح؟ شوية هذه أمثلة
+
+331
+00:30:28,860 --> 00:30:35,770
+متطورة، هي الفكرة في الـ organ chemistry ان انتوا
+
+332
+00:30:35,770 --> 00:30:39,770
+بتتعلموا التفاعل البسيط ان انتوا بتتعلموا التفاعل
+
+333
+00:30:39,770 --> 00:30:44,310
+البسيط إذا أتقنتوا بعدك لو حطيناها في مكان كبير
+
+334
+00:30:44,310 --> 00:30:49,230
+وواسع مع جزئ كبير زي هيك بتغير التفاعل البسيط؟
+
+335
+00:30:49,230 --> 00:30:54,290
+ما بتغيرش يعني هذا التفاعل هو نفس التفاعل كل هذه
+
+336
+00:30:54,290 --> 00:30:57,170
+نفس التفاعلات البسيطة اللي أخذناها بس هنا الجزئيات
+
+337
+00:30:57,170 --> 00:31:02,690
+إيش مالها؟ كبرت، زي أي انسان أو انسانة مثلا بتعلم
+
+338
+00:31:02,690 --> 00:31:07,050
+سواقة السيارات، هو بتعلمهم بشوارع صغيرة في منطقة
+
+339
+00:31:07,050 --> 00:31:10,470
+هادئة، الآن هيدلوا طول عمره بشوارع صغيرة في منطقة
+
+340
+00:31:10,470 --> 00:31:13,910
+هادئة؟ ولا لو بعثناه بعد ذلك على الـ New York، بده
+
+341
+00:31:13,910 --> 00:31:19,570
+يعرف يسوق السيارة فيها؟ هي نفس المبادئ، مظبوط؟
+
+342
+00:31:19,570 --> 00:31:23,630
+فانتوا في الأول بتتعلموا المبادئ وهنا بيصير انه
+
+343
+00:31:23,630 --> 00:31:27,310
+يعني كيف الكيميا هي علم بيكبر وعلم أبحاث انه
+
+344
+00:31:27,310 --> 00:31:30,850
+انتوا اللي زيكوا بياخد المبادئ طب طالب الماجستير
+
+345
+00:31:30,850 --> 00:31:36,630
+شو بيعمل؟ بيروح على جزئيات اكبر كثير و بفاعل OH
+
+346
+00:31:36,630 --> 00:31:40,130
+مع C double bond O وبيعمل hemacetal بس المشكلة ان
+
+347
+00:31:40,130 --> 00:31:45,360
+الجزئيات اللي بيشتغل فيهم اكبر، لكن التفاعل هو
+
+348
+00:31:45,360 --> 00:31:50,760
+اللي درسوا بسنة أولى عشان هيك يعني بيكفي بيكفي
+
+349
+00:31:50,760 --> 00:31:55,200
+لطلاب مثلا التربية أو اللي هم التحاليل الطبية انه
+
+350
+00:31:55,200 --> 00:31:58,780
+احنا نعطيهم مساق واحد مبادئ زي بني آدم علمناه يسوق
+
+351
+00:31:58,780 --> 00:32:04,900
+سيارة بعد هيك لو حضرتوا مؤتمر كيميا هتلاقوا انه
+
+352
+00:32:04,900 --> 00:32:09,060
+الإنسان اللي بيشرح مثلا ممكن يمر عليه كيف تعملوا
+
+353
+00:32:09,060 --> 00:32:13,140
+hemacetal لكن بيكون الجزيئات اللي بتعامل معها
+
+354
+00:32:13,990 --> 00:32:19,970
+جزيئات كبيرة جزيئات كبيرة ولا البنا اللي بيبني
+
+355
+00:32:19,970 --> 00:32:24,750
+البرج مش هو نفسه اللي بتتربى على بنا حيطه مظبوط ولا
+
+356
+00:32:24,750 --> 00:32:29,270
+لأ؟ وهذا هو اللي بيصير هنا انه جد ما تكبر الجزيئات
+
+357
+00:32:29,270 --> 00:32:34,070
+لكن المبدأ هذا اللي احنا قاعدين بنشرح عليه اتغير
+
+358
+00:32:34,070 --> 00:32:42,170
+hemacetal بعدين acetal addition بعدين substitution
+
+359
+00:32:42,170 --> 00:32:43,610
+ولو الجزيئة
+
+360
+00:32:58,740 --> 00:33:03,340
+الآن على نفس المبدأ بناخد الـ nucleophile ثاني
+
+361
+00:33:03,340 --> 00:33:10,140
+يعني مش معقول الحصة كلها بس نضيع على الكحول يعني
+
+362
+00:33:10,140 --> 00:33:13,260
+لو أتينا بعد كل هالتعب بدنا نقول إيش اللي أخذته
+
+363
+00:33:14,520 --> 00:33:20,380
+بسطر واحد الكحول بيعمل addition ويتبع في
+
+364
+00:33:20,380 --> 00:33:24,680
+substitution خلصنا ما فيش أكثر من هيك الآن الـ
+
+365
+00:33:24,680 --> 00:33:28,120
+addition of hydrogen cyanide الـ hydrogen cyanide
+
+366
+00:33:28,120 --> 00:33:32,060
+النيوكليوفيل اللي فيه اللي بتفعل في النهاية هو الـ
+
+367
+00:33:32,060 --> 00:33:37,180
+CN وبتفعل من خلال الكربون الآن نفس التفاعل تماما
+
+368
+00:33:37,180 --> 00:33:44,750
+الـ CN بدها تهاجم والـ O بدها تصير OH الـ CN بدأت تهاجم
+
+369
+00:33:44,750 --> 00:33:50,130
+والـ O بدأت تصير OH الآن لو اتينا واطلعنا مثلا هنا
+
+370
+00:33:50,130 --> 00:33:54,270
+هذا أسيتون هذا أسيتالديهيد لاحظوا التفاعل بيتكرر
+
+371
+00:33:54,270 --> 00:33:59,950
+ولو الجزئيات شمالها بتكبر هاي الـ CN بتهاجم والـ O
+
+372
+00:33:59,9
+
+401
+00:36:35,840 --> 00:36:42,750
+موجود عندي CN و OH فالأصل Acetaldehyde لما يتفاعل مع
+
+402
+00:36:42,750 --> 00:36:46,610
+الـ HCN أعطاني Acetaldehyde-Cyanohydride الآن
+
+403
+00:36:46,610 --> 00:36:53,510
+المركب التالي كلكم هتسموه بسهولة شو هيكون اسمه؟
+
+404
+00:36:53,510 --> 00:37:03,190
+أسيتون سيانوهيدرين المركب الثالث هذا
+
+405
+00:37:05,160 --> 00:37:10,420
+Cyclohexanone بنقولش Cyclohexane ممكن واحدة لما 
+
+406
+00:37:10,420 --> 00:37:13,720
+تيجي تسميه هنا تشوف هذا Cyclohexane وين
+
+407
+00:37:13,720 --> 00:37:17,260
+Cyclohexanone هذا Cyclohexanone تروح تسميه
+
+408
+00:37:17,260 --> 00:37:20,720
+Cyclohexane-Cyanohydrin لأ إحنا بنسميه 
+
+409
+00:37:20,720 --> 00:37:26,660
+Cyclohexanone-Cyanohydrin طب فيه هنا Cyclohexanone نسبة للأصل
+
+410
+00:37:26,660 --> 00:37:32,240
+Cyclohexanone-Cyanohydrin هذا آخر مركب اللي موجود
+
+411
+00:37:32,240 --> 00:37:32,580
+هنا
+
+412
+00:37:36,320 --> 00:37:47,700
+شو اسم هذا المركب؟ بنزين ألدهيد بنزالدهايد
+
+413
+00:37:47,700 --> 00:37:52,660
+بنزالدهايد 
+
+414
+00:37:52,660 --> 00:37:55,840
+سيانوهيدرين بنزالدهايد سيانوهيدرين ولو
+
+415
+00:37:55,840 --> 00:38:00,880
+هذه صارت CH3 لو
+
+416
+00:38:00,880 --> 00:38:05,740
+هذه صارت CH3 هيصير أسيتوفينون 
+
+417
+00:38:07,050 --> 00:38:11,550
+Cyanohydrin إذا أنا زي ما بتلاحظوا بتعلم قواعد 
+
+418
+00:38:11,550 --> 00:38:16,690
+عامة سواء في التفاعل أو حتى في نظام التسمية
+
+419
+00:38:16,690 --> 00:38:21,910
+والقواعد العامة قاعدة بتتكرر ولا لأ نفس المنطق
+
+420
+00:38:21,910 --> 00:38:26,670
+يعني أنا أنا بأعيد نفس المنطق في كل الأحوال هذه حتى
+
+421
+00:38:26,670 --> 00:38:31,450
+طريقة التسمية أنه أنا بأسمي الالديهايد أو الـ ketone و
+
+422
+00:38:31,450 --> 00:38:35,090
+بتبعه بكلمات cyanohydrin
+
+423
+00:38:43,950 --> 00:38:46,450
+خلاص اليوم صيف الله يعطيكم العافية 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..259e6f8280c35c675f980e1d4a57e3dcbe457afb
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3082, "start": 5.2, "end": 30.82, "text": "اليوم نحن في تفاعل الـ aldehydes و الـ ketones المرة الماضية حكينا شغل أساسية قلنا إنه في عندنا تفاعل عام للـ aldehydes و الـ ketones بيعتمد على إنه الـ carbon تبعت الـ carbonyl group is an electrophile يعني positive، واضح؟ سواء كانت", "tokens": [6027, 1829, 20498, 8717, 5016, 1863, 8978, 6055, 5172, 995, 30241, 2423, 39184, 16798, 68, 3495, 14792, 4032, 2423, 39184, 14979, 2213, 9673, 25720, 9673, 46958, 10632, 11331, 4117, 1829, 8315, 13412, 17082, 1211, 5551, 3794, 32277, 10632, 12174, 1211, 8315, 36145, 3224, 8978, 43242, 8315, 6055, 5172, 995, 30241, 6225, 10943, 24976, 39184, 16798, 68, 3495, 14792, 4032, 2423, 39184, 14979, 2213, 4724, 1829, 34268, 2304, 3215, 15844, 36145, 3224, 2423, 39184, 5954, 6055, 3555, 34268, 2423, 39184, 12143, 2526, 75, 1594, 307, 364, 2185, 11741, 794, 37495, 22653, 3353, 12399, 4032, 46958, 5016, 22807, 8608, 2407, 16606, 25961, 2655], "avg_logprob": -0.18167892828875898, "compression_ratio": 1.6203703703703705, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 5.2, "end": 5.62, "word": "اليوم", "probability": 0.91259765625}, {"start": 5.62, "end": 5.86, "word": " نحن", "probability": 0.7623697916666666}, {"start": 5.86, "end": 6.12, "word": " في", "probability": 0.876953125}, {"start": 6.12, "end": 7.24, "word": " تفاعل", "probability": 0.9193115234375}, {"start": 7.24, "end": 7.58, "word": " الـ", "probability": 0.718994140625}, {"start": 7.58, "end": 8.5, "word": " aldehydes", "probability": 0.7210693359375}, {"start": 8.5, "end": 8.7, "word": " و", "probability": 0.55078125}, {"start": 8.7, "end": 8.94, "word": " الـ", "probability": 0.772705078125}, {"start": 8.94, "end": 9.58, "word": " ketones", "probability": 0.7349853515625}, {"start": 9.58, "end": 11.1, "word": " المرة", "probability": 0.830078125}, {"start": 11.1, "end": 11.54, "word": " الماضية", "probability": 0.9837239583333334}, {"start": 11.54, "end": 11.92, "word": " حكينا", "probability": 0.974853515625}, {"start": 11.92, "end": 12.28, "word": " شغل", "probability": 0.8269856770833334}, {"start": 12.28, "end": 13.08, "word": " أساسية", "probability": 0.9168701171875}, {"start": 13.08, "end": 14.28, "word": " قلنا", "probability": 0.8072916666666666}, {"start": 14.28, "end": 14.56, "word": " إنه", "probability": 0.652099609375}, {"start": 14.56, "end": 14.68, "word": " في", "probability": 0.90087890625}, {"start": 14.68, "end": 15.28, "word": " عندنا", "probability": 0.9853515625}, {"start": 15.28, "end": 16.66, "word": " تفاعل", "probability": 0.9501953125}, {"start": 16.66, "end": 17.36, "word": " عام", "probability": 0.998291015625}, {"start": 17.36, "end": 17.92, "word": " للـ", "probability": 0.666259765625}, {"start": 17.92, "end": 18.46, "word": " aldehydes", "probability": 0.9176025390625}, {"start": 18.46, "end": 18.62, "word": " و", "probability": 0.96337890625}, {"start": 18.62, "end": 18.8, "word": " الـ", "probability": 0.83349609375}, 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على", "probability": 0.96044921875}, {"start": 83.04, "end": 83.44, "word": " نفسه", "probability": 0.8566080729166666}], "temperature": 1.0}, {"id": 4, "seek": 11158, "start": 83.48, "end": 111.58, "text": "اللي على نفس ال carbon فيه مجموعتين OH بنسميه hydrate واضح مع ال formaldehyde بيتكون و بيقولنا كمان بتكون مع ال chloral واضح بيكون اسم هذا formaldehyde hydrate لو ال aldehyde اللي عندي كان chloral بيكون chloral hydrate الآن بدنا ناخد أمثلة تانية بس نغير فيها", "tokens": [6027, 20292, 15844, 8717, 36178, 2423, 5954, 8978, 3224, 3714, 7435, 2304, 45367, 2655, 9957, 13931, 44945, 38251, 1829, 3224, 5796, 4404, 4032, 46958, 5016, 20449, 2423, 9860, 1479, 3495, 1479, 4724, 36081, 30544, 4032, 4724, 1829, 39648, 8315, 9122, 2304, 7649, 39894, 30544, 20449, 2423, 18178, 304, 4032, 46958, 5016, 4724, 1829, 30544, 24525, 2304, 23758, 9860, 1479, 3495, 1479, 5796, 4404, 45164, 2423, 16798, 68, 3495, 1479, 13672, 1829, 18871, 16254, 25961, 18178, 304, 4724, 1829, 30544, 18178, 304, 5796, 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{"start": 308.01, "end": 308.95, "word": " بنسميها", "probability": 0.9176025390625}, {"start": 308.95, "end": 310.15, "word": " acetal", "probability": 0.6326904296875}], "temperature": 1.0}, {"id": 13, "seek": 33023, "start": 310.87, "end": 330.23, "text": "إذا أنا في عندى hemacetal يعني نص أسيتال لإنه OR واحدة والتانية OH وفي عندى أسيتال كامل الأسيتال الكامل OR و OR واضح بنصير كام مرة اتفاعل الكحول مرتين الآن هنا بدكوا تنتبهوا", "tokens": [28814, 15730, 41850, 8978, 43242, 7578, 8636, 326, 302, 304, 37495, 22653, 8717, 9381, 5551, 3794, 36081, 6027, 5296, 28814, 1863, 3224, 19654, 36764, 24401, 3660, 16070, 2655, 7649, 10632, 13931, 4032, 41185, 43242, 7578, 5551, 3794, 36081, 6027, 9122, 10943, 1211, 16247, 3794, 36081, 6027, 33251, 10943, 1211, 19654, 4032, 19654, 4032, 46958, 5016, 44945, 9381, 13546, 9122, 10943, 3714, 25720, 1975, 2655, 5172, 995, 30241, 33251, 5016, 12610, 3714, 43500, 9957, 6024, 48506, 34105, 47525, 4117, 14407, 6055, 29399, 3555, 3224, 14407], 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0.9318033854166666}, {"start": 316.15, "end": 316.99, "word": " والتانية", "probability": 0.72967529296875}, {"start": 316.99, "end": 317.39, "word": " OH", "probability": 0.76611328125}, {"start": 317.39, "end": 317.91, "word": " وفي", "probability": 0.892333984375}, {"start": 317.91, "end": 318.19, "word": " عندى", "probability": 0.787353515625}, {"start": 318.19, "end": 318.85, "word": " أسيتال", "probability": 0.950439453125}, {"start": 318.85, "end": 319.47, "word": " كامل", "probability": 0.9952799479166666}, {"start": 319.47, "end": 320.77, "word": " الأسيتال", "probability": 0.892333984375}, {"start": 320.77, "end": 321.37, "word": " الكامل", "probability": 0.96826171875}, {"start": 321.37, "end": 321.97, "word": " OR", "probability": 0.92724609375}, {"start": 321.97, "end": 322.87, "word": " و", "probability": 0.5341796875}, {"start": 322.87, "end": 323.33, "word": " OR", "probability": 0.65673828125}, {"start": 323.33, "end": 324.23, "word": " واضح", "probability": 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hemeacetal is in eucleophilic addition reaction", "tokens": [7435, 25708, 995, 5296, 2655, 2407, 9381, 33911, 16712, 5172, 995, 30241, 33962, 9566, 2407, 3660, 16247, 12610, 7578, 5296, 15042, 47525, 8315, 8717, 2655, 4117, 19528, 18871, 11296, 2423, 11723, 295, 415, 1398, 326, 302, 304, 307, 294, 308, 1311, 306, 5317, 388, 299, 4500, 5480], "avg_logprob": -0.27587891804675263, "compression_ratio": 1.2238805970149254, "no_speech_prob": 0.0, "words": [{"start": 331.02, "end": 331.96, "word": "جيدا", "probability": 0.6439208984375}, {"start": 331.96, "end": 332.88, "word": " لتوصيف", "probability": 0.94921875}, {"start": 332.88, "end": 333.56, "word": " التفاعل", "probability": 0.9019775390625}, {"start": 333.56, "end": 337.72, "word": " الخطوة", "probability": 0.78485107421875}, {"start": 337.72, "end": 338.26, "word": " الأولى", "probability": 0.95654296875}, {"start": 338.26, "end": 338.48, "word": " لما", "probability": 0.71923828125}, {"start": 338.48, "end": 338.7, "word": " بدنا", "probability": 0.56549072265625}, {"start": 338.7, "end": 339.18, "word": " نتكلم", "probability": 0.982177734375}, {"start": 339.18, "end": 339.58, "word": " عنها", "probability": 0.978271484375}, {"start": 339.58, "end": 340.04, "word": " ال", "probability": 0.355224609375}, {"start": 340.04, "end": 340.74, "word": " formation", "probability": 0.361572265625}, {"start": 340.74, "end": 341.28, "word": " of", "probability": 0.9697265625}, {"start": 341.28, "end": 343.14, "word": " hemeacetal", "probability": 0.7396484375}, {"start": 343.14, "end": 344.58, "word": " is", "probability": 0.56982421875}, {"start": 344.58, "end": 345.48, "word": " in", "probability": 0.63623046875}, {"start": 345.48, "end": 346.4, "word": " eucleophilic", "probability": 0.8162434895833334}, {"start": 346.4, "end": 346.78, "word": " addition", "probability": 0.85107421875}, {"start": 346.78, "end": 347.58, "word": " reaction", "probability": 0.92822265625}], "temperature": 1.0}, {"id": 15, "seek": 37640, "start": 348.7, "end": 376.4, "text": "واضح؟ لما أنا بدأت أسألكم تكوين الـ hemeacetal هل هو a nucleophilic addition reaction ولا substitution reaction؟ a nucleophilic addition reaction لكن ال formation of acetal from hemeacetal acetal from hemeacetal is a substitution reaction", "tokens": [2407, 46958, 5016, 22807, 5296, 15042, 41850, 47525, 10721, 2655, 5551, 3794, 10721, 23275, 2304, 6055, 4117, 2407, 9957, 2423, 39184, 415, 1398, 326, 302, 304, 8032, 1211, 31439, 257, 14962, 5317, 388, 299, 4500, 5480, 49429, 35827, 5480, 22807, 257, 14962, 5317, 388, 299, 4500, 5480, 44381, 2423, 11723, 295, 37848, 304, 490, 415, 1398, 326, 302, 304, 37848, 304, 490, 415, 1398, 326, 302, 304, 307, 257, 35827, 5480], "avg_logprob": -0.2734375024835269, "compression_ratio": 1.7610062893081762, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 348.7, "end": 349.66, "word": "واضح؟", "probability": 0.80413818359375}, {"start": 349.66, "end": 350.12, "word": " لما", "probability": 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{"start": 356.8, "end": 357.46, "word": " ولا", "probability": 0.5751953125}, {"start": 357.46, "end": 358.18, "word": " substitution", "probability": 0.611328125}, {"start": 358.18, "end": 359.54, "word": " reaction؟", "probability": 0.6429443359375}, {"start": 359.54, "end": 360.14, "word": " a", "probability": 0.2191162109375}, {"start": 360.14, "end": 361.0, "word": " nucleophilic", "probability": 0.9534912109375}, {"start": 361.0, "end": 361.38, "word": " addition", "probability": 0.9306640625}, {"start": 361.38, "end": 361.9, "word": " reaction", "probability": 0.9482421875}, {"start": 361.9, "end": 362.66, "word": " لكن", "probability": 0.6357421875}, {"start": 362.66, "end": 363.74, "word": " ال", "probability": 0.69091796875}, {"start": 363.74, "end": 364.38, "word": " formation", "probability": 0.59814453125}, {"start": 364.38, "end": 365.12, "word": " of", "probability": 0.97900390625}, {"start": 365.12, "end": 366.3, "word": " acetal", "probability": 0.875732421875}, 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الاسيتال من ال الديهايد او الكيتون هو عبارة عن عمليتين متتابعتين الاولى", "tokens": [2407, 46958, 5016, 22807, 1975, 15730, 1975, 8315, 5296, 15042, 4724, 5016, 12610, 2423, 3224, 32640, 1829, 5551, 3794, 36081, 6027, 5296, 10721, 3794, 36081, 6027, 4724, 25957, 1211, 11933, 3555, 28259, 1211, 5296, 15042, 4724, 5016, 12610, 2423, 2423, 16254, 11296, 25708, 1975, 2407, 33251, 36081, 11536, 5296, 3224, 32640, 1829, 5551, 3794, 36081, 6027, 4724, 25957, 1211, 11933, 11242, 31845, 3660, 2423, 7649, 45164, 1975, 8315, 9122, 29399, 47525, 10721, 1975, 2655, 5172, 1211, 3794, 5172, 1975, 4117, 49115, 25894, 24793, 4032, 1975, 7435, 1829, 24525, 10721, 23275, 2304, 1975, 39648, 24793, 6055, 4117, 2407, 9957, 2423, 32277, 36081, 6027, 9154, 2423, 2423, 16254, 11296, 25708, 1975, 2407, 33251, 36081, 11536, 31439, 6225, 3555, 9640, 3660, 18871, 6225, 2304, 20292, 2655, 9957, 44650, 2655, 16758, 34268, 9957, 42963, 12610, 7578], "avg_logprob": -0.20488721490802622, "compression_ratio": 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substitution of the OH to form the acetal", "tokens": [25224, 849, 16070, 2655, 7649, 10632, 35827, 4032, 46958, 5016, 6156, 3555, 2655, 30544, 14407, 11778, 38436, 4587, 9957, 8978, 33427, 9381, 33911, 29538, 18863, 42213, 10632, 5551, 12610, 11933, 8592, 1829, 4724, 1829, 9381, 13546, 43242, 7578, 4500, 281, 1254, 264, 415, 3057, 326, 302, 304, 550, 35827, 295, 264, 13931, 281, 1254, 264, 37848, 304], "avg_logprob": -0.2221174589518843, "compression_ratio": 1.4161490683229814, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 405.71, "end": 406.53, "word": "addition", "probability": 0.60650634765625}, {"start": 406.53, "end": 407.57, "word": " والتانية", "probability": 0.826904296875}, {"start": 407.57, "end": 408.67, "word": " substitution", "probability": 0.916015625}, {"start": 408.67, "end": 409.49, "word": " واضح", "probability": 0.797607421875}, {"start": 409.49, "end": 410.63, "word": " فبتكونوا", "probability": 0.8251953125}, {"start": 410.63, "end": 411.33, 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1518.18, "word": " محل", "probability": 0.7781575520833334}, {"start": 1518.18, "end": 1518.34, "word": " الـ", "probability": 0.664306640625}, {"start": 1518.34, "end": 1518.74, "word": " OH", "probability": 0.46484375}, {"start": 1518.74, "end": 1519.48, "word": " وتطرد", "probability": 0.72869873046875}, {"start": 1519.48, "end": 1519.62, "word": " الـ", "probability": 0.91015625}, {"start": 1519.62, "end": 1519.86, "word": " OH", "probability": 0.87548828125}, {"start": 1519.86, "end": 1519.98, "word": " و", "probability": 0.39990234375}, {"start": 1519.98, "end": 1520.22, "word": " تحل", "probability": 0.8707682291666666}, {"start": 1520.22, "end": 1520.6, "word": " المحلة", "probability": 0.6881103515625}, {"start": 1520.6, "end": 1520.72, "word": " و", "probability": 0.2296142578125}, {"start": 1520.72, "end": 1520.9, "word": " تظهر", "probability": 0.67926025390625}, {"start": 1520.9, "end": 1521.4, "word": " النتج", "probability": 0.617919921875}, {"start": 1521.4, "end": 1521.56, "word": " اللي", "probability": 0.699951171875}, {"start": 1521.56, "end": 1522.14, "word": " عندكم", "probability": 0.90869140625}, {"start": 1522.14, "end": 1522.84, "word": " إذا", "probability": 0.5047607421875}, {"start": 1522.84, "end": 1523.68, "word": " النتج", "probability": 0.7398274739583334}, {"start": 1523.68, "end": 1523.86, "word": " اللي", "probability": 0.97900390625}, {"start": 1523.86, "end": 1524.18, "word": " عندكم", "probability": 0.95361328125}, {"start": 1524.18, "end": 1524.34, "word": " هو", "probability": 0.951171875}, {"start": 1524.34, "end": 1524.76, "word": " نتاج", "probability": 0.91064453125}, {"start": 1524.76, "end": 1525.48, "word": " خطوتين", "probability": 0.85821533203125}, {"start": 1525.48, "end": 1526.26, "word": " حقيقة", "probability": 0.8751627604166666}, {"start": 1526.26, "end": 1527.8, "word": " التفاعل", "probability": 0.8892822265625}, {"start": 1527.8, "end": 1528.48, "word": " الأول", "probability": 0.96484375}, {"start": 1528.48, "end": 1528.78, "word": " اللي", "probability": 0.875732421875}, {"start": 1528.78, "end": 1528.9, "word": " هو", "probability": 0.966796875}, {"start": 1528.9, "end": 1529.04, "word": " الـ", "probability": 0.68212890625}, {"start": 1529.04, "end": 1529.98, "word": " intramolecular", "probability": 0.82061767578125}, {"start": 1529.98, "end": 1530.78, "word": " reaction", "probability": 0.9248046875}, {"start": 1530.78, "end": 1531.26, "word": " to", "probability": 0.599609375}, {"start": 1531.26, "end": 1531.82, "word": " form", "probability": 0.95849609375}, {"start": 1531.82, "end": 1532.6, "word": " the", "probability": 0.859375}, {"start": 1532.6, "end": 1533.76, "word": " hemiacetal", "probability": 0.8408203125}, {"start": 1533.76, "end": 1534.18, "word": " و", "probability": 0.57666015625}, {"start": 1534.18, "end": 1534.5, "word": " بعد", "probability": 0.79833984375}, {"start": 1534.5, "end": 1534.96, "word": " هيك", "probability": 0.743408203125}, {"start": 1534.96, "end": 1535.18, "word": " ال", "probability": 0.82763671875}, {"start": 1535.18, "end": 1535.66, "word": " substitution", "probability": 0.81494140625}, {"start": 1535.66, "end": 1536.82, "word": " reaction", "probability": 0.9296875}, {"start": 1536.82, "end": 1537.24, "word": " to", "probability": 0.8173828125}, {"start": 1537.24, "end": 1537.72, "word": " form", "probability": 0.94677734375}, {"start": 1537.72, "end": 1538.54, "word": " the", "probability": 0.8857421875}, {"start": 1538.54, "end": 1539.18, "word": " acetal", "probability": 0.812744140625}], "temperature": 1.0}, {"id": 63, "seek": 156536, "start": 1540.48, "end": 1565.36, "text": "أول تفاعل Intramolecular هي الـ OH والـ C double bond O في نفس الجزيء Intramolecular هذا بنوصفه مظبوط ولا لا؟ بعد ذلك التفاعل التالي لما أجيب هذا كله جزيء والميطانول جزيء This is intramolecular reaction واضح المثال هذا؟", "tokens": [10721, 12610, 6055, 5172, 995, 30241, 5681, 2356, 4812, 17792, 39896, 2423, 39184, 13931, 16070, 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0.88427734375}, {"start": 1553.32, "end": 1554.56, "word": " والميطانول", "probability": 0.678466796875}, {"start": 1554.56, "end": 1555.42, "word": " جزيء", "probability": 0.947509765625}, {"start": 1555.42, "end": 1556.38, "word": " This", "probability": 0.243896484375}, {"start": 1556.38, "end": 1556.72, "word": " is", "probability": 0.95751953125}, {"start": 1556.72, "end": 1557.92, "word": " intramolecular", "probability": 0.787017822265625}, {"start": 1557.92, "end": 1561.5, "word": " reaction", "probability": 0.94287109375}, {"start": 1561.5, "end": 1564.32, "word": " واضح", "probability": 0.8502604166666666}, {"start": 1564.32, "end": 1564.82, "word": " المثال", "probability": 0.9680989583333334}, {"start": 1564.82, "end": 1565.36, "word": " هذا؟", "probability": 0.943603515625}], "temperature": 1.0}, {"id": 64, "seek": 159709, "start": 1568.51, "end": 1597.09, "text": "بس بالتأكيد بيلزم تتدربوا عليه الآن المثال اللي بعده شوية بدون ورقة وقلم انا بأكدلكوا انه صعب انكوا تصلوله يعني لاحظوا كيف مرات الأمثلة بتكون موجودة ومرسومة وإيش الناتج كيف هذا الناتج طلع من هذا المثال", "tokens": [3555, 3794, 20666, 2655, 10721, 4117, 25708, 4724, 26895, 11622, 2304, 6055, 2655, 3215, 25513, 14407, 47356, 6024, 48506, 9673, 12984, 6027, 13672, 1829, 39182, 3224, 13412, 2407, 10632, 47525, 11536, 4032, 2288, 28671, 4032, 4587, 19528, 1975, 8315, 4724, 10721, 4117, 3215, 23275, 14407, 16472, 3224, 20328, 3615, 3555, 16472, 4117, 14407, 6055, 36520, 12610, 3224, 37495, 22653, 20193, 5016, 19913, 14407, 9122, 33911, 3714, 2288, 9307, 16247, 2304, 12984, 37977, 39894, 30544, 3714, 29245, 23328, 3660, 4032, 29973, 3794, 20498, 3660, 4032, 28814, 1829, 8592, 2423, 8315, 2655, 7435, 9122, 33911, 23758, 2423, 8315, 2655, 7435, 23032, 1211, 3615, 9154, 23758, 9673, 12984, 6027], "avg_logprob": -0.11645735883824179, "compression_ratio": 1.8724489795918366, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1568.51, "end": 1568.85, "word": "بس", "probability": 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"word": " وقلم", "probability": 0.84716796875}, {"start": 1580.81, "end": 1581.97, "word": " انا", "probability": 0.748291015625}, {"start": 1581.97, "end": 1582.69, "word": " بأكدلكوا", "probability": 0.914794921875}, {"start": 1582.69, "end": 1583.35, "word": " انه", "probability": 0.907470703125}, {"start": 1583.35, "end": 1584.93, "word": " صعب", "probability": 0.99072265625}, {"start": 1584.93, "end": 1585.23, "word": " انكوا", "probability": 0.8326822916666666}, {"start": 1585.23, "end": 1585.89, "word": " تصلوله", "probability": 0.8828125}, {"start": 1585.89, "end": 1586.13, "word": " يعني", "probability": 0.79150390625}, {"start": 1586.13, "end": 1586.91, "word": " لاحظوا", "probability": 0.942626953125}, {"start": 1586.91, "end": 1587.25, "word": " كيف", "probability": 0.96337890625}, {"start": 1587.25, "end": 1588.47, "word": " مرات", "probability": 0.95751953125}, {"start": 1588.47, "end": 1589.13, "word": " الأمثلة", "probability": 0.958251953125}, {"start": 1589.13, "end": 1589.55, "word": " بتكون", "probability": 0.9482421875}, {"start": 1589.55, "end": 1590.23, "word": " موجودة", "probability": 0.989990234375}, {"start": 1590.23, "end": 1591.25, "word": " ومرسومة", "probability": 0.9251953125}, {"start": 1591.25, "end": 1592.45, "word": " وإيش", "probability": 0.79986572265625}, {"start": 1592.45, "end": 1593.11, "word": " الناتج", "probability": 0.8372802734375}, {"start": 1593.11, "end": 1593.89, "word": " كيف", "probability": 0.81591796875}, {"start": 1593.89, "end": 1594.17, "word": " هذا", "probability": 0.966796875}, {"start": 1594.17, "end": 1594.91, "word": " الناتج", "probability": 0.92529296875}, {"start": 1594.91, "end": 1595.61, "word": " طلع", "probability": 0.9876302083333334}, {"start": 1595.61, "end": 1596.05, "word": " من", "probability": 0.9931640625}, {"start": 1596.05, "end": 1596.41, "word": " هذا", "probability": 0.97412109375}, {"start": 1596.41, "end": 1597.09, "word": " المثال", "probability": 0.9842122395833334}], "temperature": 1.0}, {"id": 65, "seek": 162767, "start": 1598.85, "end": 1627.67, "text": "أنا حقيقة بهذا المثال وببساطة عندي C double bond O وعندي تنتين OH OH إذا هيتم تفاعل على مرتين مرة مع ال OH الأولى ويعمل ليهمي أسيتال ومرة مع ال OH التانية ويعمل أسيتال فقط اللي بيلزم فقط اللي بيلزم عاد كيف نكون مرتبين الجزء بحيث نعمله", "tokens": [10721, 8315, 11331, 38436, 28671, 4724, 3224, 15730, 9673, 12984, 6027, 46599, 3555, 3794, 41193, 3660, 18871, 16254, 383, 3834, 6086, 422, 4032, 3615, 1863, 16254, 6055, 29399, 9957, 13931, 13931, 11933, 15730, 8032, 36081, 2304, 6055, 5172, 995, 30241, 15844, 3714, 43500, 9957, 3714, 25720, 20449, 2423, 13931, 16247, 12610, 7578, 4032, 1829, 25957, 1211, 32239, 3224, 2304, 1829, 5551, 3794, 36081, 6027, 4032, 2304, 25720, 20449, 2423, 13931, 16712, 7649, 10632, 4032, 1829, 25957, 1211, 5551, 3794, 36081, 6027, 6156, 47432, 13672, 1829, 4724, 26895, 11622, 2304, 6156, 47432, 13672, 1829, 4724, 26895, 11622, 2304, 6225, 18513, 9122, 33911, 8717, 30544, 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بعدين قلتلكم مع ال hcn و لو الجزء كبر لكن التفاعل المبدأ نفسه ان هذي بتهاجم", "tokens": [2407, 11331, 9566, 36081, 34105, 596, 4032, 11331, 9566, 36081, 34105, 417, 18, 4032, 39182, 9957, 12174, 1211, 2655, 23275, 2304, 20449, 2423, 276, 16279, 4032, 45164, 25724, 11622, 38207, 9122, 26890, 44381, 16712, 5172, 995, 30241, 9673, 44510, 10721, 8717, 36178, 3224, 16472, 8032, 8848, 1829, 39894, 3224, 26108, 2304], "avg_logprob": -0.3635817365004466, "compression_ratio": 1.4173228346456692, "no_speech_prob": 1.0132789611816406e-06, "words": [{"start": 2081.14, "end": 2081.36, "word": "و", "probability": 0.77099609375}, {"start": 2081.36, "end": 2081.78, "word": " حطيت", "probability": 0.6400146484375}, {"start": 2081.78, "end": 2081.98, "word": " هنا", "probability": 0.499755859375}, {"start": 2081.98, "end": 2082.4, "word": " cl", "probability": 0.2548828125}, {"start": 2082.4, "end": 2082.62, "word": " و", "probability": 0.8759765625}, {"start": 2082.62, "end": 2082.98, "word": " حطيت", 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0.85302734375}, {"start": 2276.46, "end": 2277.22, "word": " CH3", "probability": 0.9306640625}, {"start": 2277.22, "end": 2280.88, "word": " لو", "probability": 0.2470703125}, {"start": 2280.88, "end": 2281.1, "word": " هذه", "probability": 0.9423828125}, {"start": 2281.1, "end": 2281.44, "word": " صارت", "probability": 0.9635416666666666}, {"start": 2281.44, "end": 2282.24, "word": " CH3", "probability": 0.990478515625}, {"start": 2282.24, "end": 2283.82, "word": " هيصير", "probability": 0.66845703125}, {"start": 2283.82, "end": 2285.74, "word": " أسيتوفينون", "probability": 0.8572591145833334}], "temperature": 1.0}, {"id": 91, "seek": 231509, "start": 2287.05, "end": 2315.09, "text": "Cyanohydrin إذا أنا زي ما بتلاحظوا بتعلم قواعد عامة سواء في التفاعل أو حتى في نظام التسمية والقواعد العامة جاعدة بتتكرر ولا لأ نفس المنطق يعني أنا أنا بعيد نفس المنطق في كل الأحوال هذه حتى طريقة التسمية أنه أنا بسمل الديهايد أو ال ketone و باتبعه بكلمات cyanohydrin", "tokens": [34, 6277, 1445, 6655, 12629, 11933, 15730, 41850, 30767, 1829, 19446, 39894, 15040, 5016, 19913, 14407, 39894, 3615, 19528, 12174, 14407, 22488, 6225, 10943, 3660, 8608, 2407, 16606, 8978, 16712, 5172, 995, 30241, 34051, 11331, 49975, 8978, 8717, 19913, 10943, 16712, 38251, 10632, 16070, 4587, 14407, 22488, 18863, 10943, 3660, 10874, 995, 22488, 3660, 39894, 2655, 37983, 2288, 49429, 5296, 10721, 8717, 36178, 9673, 1863, 9566, 4587, 37495, 22653, 41850, 41850, 45030, 25708, 8717, 36178, 9673, 1863, 9566, 4587, 8978, 28242, 16247, 5016, 2407, 6027, 29538, 11331, 49975, 23032, 16572, 28671, 16712, 38251, 10632, 14739, 3224, 41850, 4724, 38251, 1211, 2423, 16254, 11296, 25708, 34051, 2423, 803, 41656, 4032, 4724, 9307, 3555, 3615, 3224, 4724, 4117, 19528, 9307, 47463, 1445, 6655, 12629], "avg_logprob": -0.1604420722015505, "compression_ratio": 1.853061224489796, "no_speech_prob": 4.112720489501953e-06, "words": [{"start": 2287.05, "end": 2288.09, "word": "Cyanohydrin", "probability": 0.6677734375}, {"start": 2288.09, "end": 2289.03, "word": " إذا", "probability": 0.558349609375}, {"start": 2289.03, "end": 2289.39, "word": " أنا", "probability": 0.83837890625}, {"start": 2289.39, "end": 2289.83, "word": " زي", "probability": 0.904052734375}, {"start": 2289.83, "end": 2289.93, "word": " ما", "probability": 0.9619140625}, {"start": 2289.93, "end": 2290.45, "word": " بتلاحظوا", "probability": 0.97890625}, {"start": 2290.45, "end": 2290.95, "word": " بتعلم", "probability": 0.9025065104166666}, {"start": 2290.95, "end": 2291.55, "word": " قواعد", "probability": 0.9767252604166666}, {"start": 2291.55, "end": 2292.11, "word": " عامة", "probability": 0.99658203125}, {"start": 2292.11, "end": 2292.87, "word": " سواء", "probability": 0.9482421875}, {"start": 2292.87, "end": 2293.07, "word": " في", "probability": 0.9658203125}, {"start": 2293.07, "end": 2293.95, "word": " التفاعل", "probability": 0.9202880859375}, {"start": 2293.95, "end": 2294.77, "word": " أو", "probability": 0.951171875}, {"start": 2294.77, "end": 2295.11, "word": " حتى", "probability": 0.941650390625}, {"start": 2295.11, "end": 2295.41, "word": " في", "probability": 0.95654296875}, {"start": 2295.41, "end": 2296.01, "word": " نظام", "probability": 0.998046875}, {"start": 2296.01, "end": 2296.69, "word": " التسمية", "probability": 0.962890625}, {"start": 2296.69, "end": 2297.59, "word": " والقواعد", "probability": 0.8577880859375}, {"start": 2297.59, "end": 2298.01, "word": " العامة", "probability": 0.9921875}, {"start": 2298.01, "end": 2298.35, "word": " جاعدة", "probability": 0.777587890625}, {"start": 2298.35, "end": 2298.89, "word": " بتتكرر", "probability": 0.9615478515625}, {"start": 2298.89, "end": 2299.11, "word": " ولا", "probability": 0.865234375}, {"start": 2299.11, "end": 2299.49, "word": " لأ", "probability": 0.937744140625}, {"start": 2299.49, "end": 2301.35, "word": " نفس", "probability": 0.92578125}, {"start": 2301.35, "end": 2301.91, "word": " المنطق", "probability": 0.9775390625}, {"start": 2301.91, "end": 2302.11, "word": " يعني", "probability": 0.915771484375}, {"start": 2302.11, "end": 2302.35, "word": " أنا", "probability": 0.85302734375}, {"start": 2302.35, "end": 2302.55, "word": " أنا", "probability": 0.6376953125}, {"start": 2302.55, "end": 2303.15, "word": " بعيد", "probability": 0.919677734375}, {"start": 2303.15, "end": 2303.89, "word": " نفس", "probability": 0.993408203125}, {"start": 2303.89, "end": 2304.45, "word": " المنطق", "probability": 0.994873046875}, {"start": 2304.45, "end": 2304.65, "word": " في", "probability": 0.9736328125}, {"start": 2304.65, "end": 2304.89, "word": " كل", "probability": 0.994140625}, {"start": 2304.89, "end": 2305.61, "word": " الأحوال", "probability": 0.9921875}, {"start": 2305.61, "end": 2306.23, "word": " هذه", "probability": 0.5673828125}, {"start": 2306.23, "end": 2306.67, "word": " حتى", "probability": 0.939208984375}, {"start": 2306.67, "end": 2307.03, "word": " طريقة", "probability": 0.892578125}, {"start": 2307.03, 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0.792388916015625}], "temperature": 1.0}, {"id": 92, "seek": 232644, "start": 2323.95, "end": 2326.45, "text": "خلاص اليوم صيف الله يعطيكوا العافية", "tokens": [9778, 1211, 33546, 45595, 20498, 20328, 33911, 21984, 37495, 9566, 1829, 4117, 14407, 18863, 31845, 10632], "avg_logprob": -0.16475183823529413, "compression_ratio": 1.0483870967741935, "no_speech_prob": 1.8656253814697266e-05, "words": [{"start": 2323.95, "end": 2324.75, "word": "خلاص", "probability": 0.7137044270833334}, {"start": 2324.75, "end": 2325.15, "word": " اليوم", "probability": 0.930908203125}, {"start": 2325.15, "end": 2325.47, "word": " صيف", "probability": 0.86962890625}, {"start": 2325.47, "end": 2325.63, "word": " الله", "probability": 0.8271484375}, {"start": 2325.63, "end": 2326.03, "word": " يعطيكوا", "probability": 0.88828125}, {"start": 2326.03, "end": 2326.45, "word": " العافية", "probability": 0.9661458333333334}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..66e9a6f2b9c1247de28aa44b943a6cfb60f7387e
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_raw.srt
@@ -0,0 +1,1692 @@
+1
+00:00:05,200 --> 00:00:09,580
+اليوم نحن في تفاعل الـ aldehydes و الـ ketones
+
+2
+00:00:09,580 --> 00:00:15,280
+المرة الماضية حكينا شغل أساسية قلنا إنه في عندنا
+
+3
+00:00:15,280 --> 00:00:20,920
+تفاعل عام للـ aldehydes و الـ ketones بيعتمد على
+
+4
+00:00:20,920 --> 00:00:26,940
+إنه الـ carbon تبعت الـ carbonyl group is an
+
+5
+00:00:26,940 --> 00:00:30,820
+electrophile يعني positive، واضح؟ سواء كانت
+
+6
+00:00:31,150 --> 00:00:35,190
+Positive كامل أو كانت positive جزء في النهاية
+
+7
+00:00:35,190 --> 00:00:38,870
+بيصير عليها تفاعل الـ Eucleophile التفاعل في شكل
+
+8
+00:00:38,870 --> 00:00:42,070
+عام للـ Eucleophile لما بيتهاجم على الكربون الـ O
+
+9
+00:00:42,070 --> 00:00:47,930
+في نهاية بيصير OH، واضح؟ إذا التفاعل الأساسي
+
+10
+00:00:47,930 --> 00:00:54,500
+للالدهايتز والكيتون هو مهاجمة الـ Eucleophileوزي
+
+11
+00:00:54,500 --> 00:00:58,900
+ما اتفقنا الـ O إيش بتصير؟ OH هذا الكلام أخدنا
+
+12
+00:00:58,900 --> 00:01:03,360
+مثال عليه هذا الكلام أخدنا مثال عليه في تفاعل
+
+13
+00:01:03,360 --> 00:01:07,920
+الميه وإن كان تفاعل الميه محدود يعني مش مع مراكبات
+
+14
+00:01:07,920 --> 00:01:11,900
+كثير بيصير اللي هي عملية إضافة الميه بنسميها
+
+15
+00:01:11,900 --> 00:01:16,360
+hydration فلما نضيف الميه هذه الـ OH اللي شايفينها
+
+16
+00:01:16,360 --> 00:01:22,040
+باللون الأحمر هي بتضيف وهذه ال Oxygen بتصير OH هذا
+
+17
+00:01:22,040 --> 00:01:26,920
+المراكب اللي على نفسهاللي على نفس ال carbon فيه
+
+18
+00:01:26,920 --> 00:01:33,800
+مجموعتين OH بنسميه hydrate واضح مع ال formaldehyde
+
+19
+00:01:33,800 --> 00:01:38,600
+بيتكون و بيقولنا كمان بتكون مع ال chloral واضح
+
+20
+00:01:38,600 --> 00:01:42,160
+بيكون اسم هذا formaldehyde hydrate لو ال aldehyde
+
+21
+00:01:42,160 --> 00:01:47,380
+اللي عندي كان chloral بيكون chloral hydrate الآن
+
+22
+00:01:47,380 --> 00:01:54,290
+بدنا ناخد أمثلة تانية بس نغير فيهاللـ nucleophile
+
+23
+00:01:54,290 --> 00:01:59,610
+اللي بيهاجمها لكن نفس الشكل للتفاعل هنلاحظ أنه
+
+24
+00:01:59,610 --> 00:02:06,070
+بيستمر مثلا عملية إضافة ال alcohols ال alcohols R
+
+25
+00:02:06,070 --> 00:02:13,170
+O H واضح؟ لما بنضيف ال alcohol اللي هضيف can
+
+26
+00:02:13,170 --> 00:02:20,890
+nucleophile ال R Oو الـ CW.O بدأ تصير OH الان هنا
+
+27
+00:02:20,890 --> 00:02:25,810
+بتلاحظوا ان انتوا على carbon واحدة عندكم مجموعتين
+
+28
+00:02:25,810 --> 00:02:34,410
+وظيفيتين عندكم alcohol و عندكم ether هذه ال R C O
+
+29
+00:02:34,410 --> 00:02:38,210
+R او ال C O R هذا ether واضح؟
+
+30
+00:02:40,670 --> 00:02:44,450
+الالكهول الان هدولة المجمعتين الوظيفيتين موجودين
+
+31
+00:02:44,450 --> 00:02:48,350
+على كاربون واحدة ال ether والالكهول هذه التوليفة
+
+32
+00:02:48,350 --> 00:02:54,110
+او هذا الشكل بنقول عن المركب hemiacetal فال
+
+33
+00:02:54,110 --> 00:02:57,770
+hemiacetal هو المركب اللي على الكاربون الواحدة
+
+34
+00:02:57,770 --> 00:03:04,410
+موجود عند كحول وموجود ether بمعنى على الكاربون OR
+
+35
+00:03:04,410 --> 00:03:11,590
+وOH واضح؟بناء على ذلك، لو افترضت مثلا انه انا كنت
+
+36
+00:03:11,590 --> 00:03:17,350
+بادي هنا بمجموعة مثل CH3 في هذه الحالة، شو هيكون
+
+37
+00:03:17,350 --> 00:03:21,010
+اسم ال الديهيد؟
+
+38
+00:03:21,010 --> 00:03:28,290
+أسيتالديهيد، بعد هيك لو ضفت عليه إيثانون، هيصير
+
+39
+00:03:28,290 --> 00:03:32,890
+أسيتالديهيد هيمي أسيتال of إيثانول، أنا بتحدد كمان
+
+40
+00:03:34,800 --> 00:03:40,720
+واضح فبصير acetaldehyde hemiacetal خلّيني أقول ال
+
+41
+00:03:40,720 --> 00:03:45,940
+hemiacetal في نهاية هو اسم عائلة زي ما الكحول اسم
+
+42
+00:03:45,940 --> 00:03:50,080
+عائلة و ال ether اسم عائلة و ال ketone اسم عائلة
+
+43
+00:03:50,080 --> 00:03:54,780
+فال hemiacetal بيظل اسم عائلة، العائلة فيها على
+
+44
+00:03:54,780 --> 00:04:02,580
+الكربون الواحدة OH و ORهذا التفاعل واضح تماما انه
+
+45
+00:04:02,580 --> 00:04:06,560
+تفاعل addition ليش تفاعل addition لأنه انا على ال
+
+46
+00:04:06,560 --> 00:04:09,720
+double bond لما تيجي و انت تتطلع هذه كانت double
+
+47
+00:04:09,720 --> 00:04:15,820
+bond ضفت OR وضفت H و حولت ال double إلى single
+
+48
+00:04:15,820 --> 00:04:20,180
+bond وبناء على ذلك هذا التفاعل هو تفاعل addition
+
+49
+00:04:20,840 --> 00:04:27,580
+الان اذا كان عندى الكحول موجود بنسبة كبيرة .. اذا
+
+50
+00:04:27,580 --> 00:04:31,960
+الكحول عندى موجود بنسبة كبيرة بيصير تفاعل تاني
+
+51
+00:04:31,960 --> 00:04:36,640
+إضافي بعد ما نخلص تفاعل ال addition بتيجي الكمية
+
+52
+00:04:36,640 --> 00:04:43,430
+الإضافية من الكحول بتهاجم هنا و بتطرد ال OHلاحظوا
+
+53
+00:04:43,430 --> 00:04:47,570
+هنا مجموعة إجت و مجموعة طلعت إذا إيش هذا التفاعل
+
+54
+00:04:47,570 --> 00:04:53,570
+إبتال مجموعة بتحل محال مجموعة substitution فبصير
+
+55
+00:04:53,570 --> 00:04:59,770
+عند مدل ال OH و OR في هذه الحالة صار عند مركب على
+
+56
+00:04:59,770 --> 00:05:05,050
+نفس ال carbon مجمعتين ether يعني على ال carbon OR
+
+57
+00:05:05,050 --> 00:05:12,430
+و OR هذه العائلة بنسميها acetalإذا أنا في عندى
+
+58
+00:05:12,430 --> 00:05:17,390
+hemacetal يعني نص أسيتال لإنه OR واحدة والتانية OH
+
+59
+00:05:17,390 --> 00:05:24,230
+وفي عندى أسيتال كامل الأسيتال الكامل OR و OR واضح
+
+60
+00:05:24,230 --> 00:05:29,430
+بنصير كام مرة اتفاعل الكحول مرتين الآن هنا بدكوا
+
+61
+00:05:29,430 --> 00:05:37,720
+تنتبهواجيدا لتوصيف التفاعل الخطوة
+
+62
+00:05:37,720 --> 00:05:41,280
+الأولى لما بدنا نتكلم عنها ال formation of
+
+63
+00:05:41,280 --> 00:05:47,580
+hemeacetal is in eucleophilic addition reaction
+
+64
+00:05:48,700 --> 00:05:53,880
+واضح؟ لما أنا بدأت أسألكم تكوين الـ hemeacetal هل
+
+65
+00:05:53,880 --> 00:05:57,460
+هو a nucleophilic addition reaction ولا
+
+66
+00:05:57,460 --> 00:06:01,380
+substitution reaction؟ a nucleophilic addition
+
+67
+00:06:01,380 --> 00:06:06,720
+reaction لكن ال formation of acetal from
+
+68
+00:06:06,720 --> 00:06:14,420
+hemeacetal acetal from hemeacetal is a
+
+69
+00:06:14,420 --> 00:06:16,400
+substitution reaction
+
+70
+00:06:18,100 --> 00:06:21,900
+واضح؟ اذا انا لما بحول الهيمي أسيتال لأسيتال بعمل
+
+71
+00:06:21,900 --> 00:06:26,100
+إبدال لما بحول ال الديهايد او الكيتون لهيمي أسيتال
+
+72
+00:06:26,100 --> 00:06:30,700
+بعمل إضافة الان لو انا كنت بدأ اتفلسف اكثر عليكم و
+
+73
+00:06:30,700 --> 00:06:37,260
+اجي اسألكم اقولكم تكوين الاسيتال من ال الديهايد او
+
+74
+00:06:37,260 --> 00:06:44,680
+الكيتون هو عبارة عن عمليتين متتابعتين الاولى
+
+75
+00:06:45,710 --> 00:06:50,630
+addition والتانية substitution واضح فبتكونوا
+
+76
+00:06:50,630 --> 00:06:54,250
+دقيقين في توصيف هذه العملية أول إشي بيصير عندى
+
+77
+00:06:54,250 --> 00:06:58,650
+addition to form the hemiacetal then substitution
+
+78
+00:06:58,650 --> 00:07:03,860
+of the OH to form the acetalواضحة هذه الفكرة، هذا
+
+79
+00:07:03,860 --> 00:07:08,400
+الكلام بيعتمد على قداش أنا عندى كمية كحول، بمعنى
+
+80
+00:07:08,400 --> 00:07:12,540
+لو حطيت الكحول بنسبة واحد الى واحد فقط هيتكون عندى
+
+81
+00:07:12,540 --> 00:07:17,120
+ال hemacetal لو حطيت بنسبة اتنين الى واحد او اكثر
+
+82
+00:07:17,120 --> 00:07:20,880
+هيتكون عندى في النهاية الacetal
+
+83
+00:07:31,600 --> 00:07:38,260
+ممكن الكحول والالديهيد يكونوا موجودين في داخل جزء
+
+84
+00:07:38,260 --> 00:07:43,360
+واحد يعني لاحظوا في المثال السابق الكحول عبارة عن
+
+85
+00:07:43,360 --> 00:07:48,340
+جزء والالديهيد جزء منفصلين وبيجوا يتفاعلوا مع بعض
+
+86
+00:07:48,340 --> 00:07:54,420
+الان لو كان عندى مثل هذا المركب مثلاواضح؟ اللي هو
+
+87
+00:07:54,420 --> 00:07:58,780
+الـ 5-hydroxybenthanol نعرف كيف نسميه، هاي واحد،
+
+88
+00:07:58,780 --> 00:08:01,640
+اتنين، تلاتة، أربعة، خمسة، هذا penthanol على
+
+89
+00:08:01,640 --> 00:08:06,020
+مجموعة خمسة إيش عندكم؟ OH إذاً هذا 5
+
+90
+00:08:06,020 --> 00:08:10,180
+-hydroxybenthanol الآن لاحظوا هنا، في عند ال
+
+91
+00:08:10,180 --> 00:08:14,080
+الديهايد وفي عند ال OH تبع الكحول اللي بدأت تتفاعل
+
+92
+00:08:14,080 --> 00:08:18,620
+وعشان كذا لما بنعمله بـH plus يعني في وجود حامض
+
+93
+00:08:19,160 --> 00:08:23,020
+ممكن التفاعل يحدث في داخل الجزء، بنسميه
+
+94
+00:08:23,020 --> 00:08:29,120
+Intramolecular Intramolecular إن المتفاعلين يكونوا
+
+95
+00:08:29,120 --> 00:08:36,260
+داخل الجزء، مش يجي الألديهيد قطعة والألكوهول قطعة
+
+96
+00:08:36,260 --> 00:08:40,900
+تانية، لأ هنا التلتين موجودات في داخل الجزء فبتم
+
+97
+00:08:40,900 --> 00:08:46,420
+تفاعل وهذا بتصير OH
+
+98
+00:08:48,710 --> 00:08:53,310
+اللي هو تكوين الـ Hemacetal هذا التفاعل اللي بيكون
+
+99
+00:08:53,310 --> 00:08:57,050
+المتفاعلين تبعله في داخل الجزء شو بنسميه؟
+
+100
+00:08:57,050 --> 00:09:01,970
+Intramolecular within the molecule لكن لما أنا
+
+101
+00:09:01,970 --> 00:09:05,970
+بجيب جزيئين منفصلين يتفاعلوا مع بعض شو بوصف
+
+102
+00:09:05,970 --> 00:09:12,550
+التفاعل؟ Intermolecular فبيتميزوا ما بين تفاعل زي
+
+103
+00:09:12,550 --> 00:09:16,290
+هذا Intramolecular
+
+104
+00:09:17,300 --> 00:09:22,980
+إن الرأسين المتفاعلين في تاخر الجزيئة وعندما أحضر
+
+105
+00:09:22,980 --> 00:09:27,440
+جزيئين X وY ويتفاعلوا مع بعض هما مفصلين هذا
+
+106
+00:09:27,440 --> 00:09:32,800
+التفاعل شو بنسميه Intermolecular وهذا مصطلح دائما
+
+107
+00:09:32,800 --> 00:09:33,900
+نستعمله
+
+108
+00:09:35,940 --> 00:09:40,020
+التفاعل فيه عند Intramolecular و Intermolecular
+
+109
+00:09:40,020 --> 00:09:44,700
+ففي هذا المثال لما بنوجد الـ OH و الـ Aldehyde
+
+110
+00:09:44,700 --> 00:09:48,360
+بتفاعلوا مع بعض ولو انهم الاتنين موجودين في جزء
+
+111
+00:09:48,360 --> 00:09:51,820
+واحد هيعطيين اللي هو الـ Ether مع الـ OH
+
+112
+00:09:51,820 --> 00:09:56,460
+-Hemiacetal واضح؟ فبتكون عندنا اللي هو
+
+113
+00:09:56,460 --> 00:10:01,680
+الـHemiacetal-O5-Hydroxybintanate هذا الحقيقة
+
+114
+00:10:01,680 --> 00:10:06,380
+التفاعل بالذات هذا يعتبر مهم كتيريعتبر مهم كتير
+
+115
+00:10:06,380 --> 00:10:11,040
+ليش مهم؟ لأنه لما تدرسوا انتوا في ال biochemistry
+
+116
+00:10:11,040 --> 00:10:19,660
+هتاخدوا تركيب الجولوكوز الجولوكوز عبارة عن 6 ذرات
+
+117
+00:10:19,660 --> 00:10:26,000
+كربون موجود فيهم موجود فيهم الديهيد وموجود و H
+
+118
+00:10:26,000 --> 00:10:33,540
+زكتار وبيكون مرات بشكل a cyclic يعني فاتح ومرات
+
+119
+00:10:33,540 --> 00:10:41,510
+بشكلcyclic ايه cyclic يعني؟ مش حلقي non-cyclic ايه
+
+120
+00:10:41,510 --> 00:10:47,590
+تبعت؟ ايش هذه؟ النفة مش ال a بتيجي حرف نفة a
+
+121
+00:10:47,590 --> 00:10:52,530
+-cyclic أسيمتريك يعني غير متماثل غير حلقي فبيكون
+
+122
+00:10:52,530 --> 00:10:57,370
+مرات بالشكل الفاتح و بيكون مرات بالشكل المسكر وهذا
+
+123
+00:10:57,370 --> 00:11:04,240
+اتزال موجودفي السكريات وموجود في الجولوكوز فبهذا
+
+124
+00:11:04,240 --> 00:11:08,960
+الشكل بيصير هذا التفاعل بالنسبة لنا تفاعل مهم واضح
+
+125
+00:11:08,960 --> 00:11:12,960
+لإن أحد التفاعلات اللي بتاخدوها بالتفصيل في
+
+126
+00:11:12,960 --> 00:11:16,260
+الكيميا الحيوية بيصير عند هذا الجولوكوز طبعا
+
+127
+00:11:16,260 --> 00:11:20,440
+هتتعلموا كيف تسمو إيش معنا بيتا وإيش معنا دي إيش
+
+128
+00:11:20,440 --> 00:11:25,230
+لوكو بيرانوس كل هذا الكلام وين ماكانهفي course
+
+129
+00:11:25,230 --> 00:11:29,330
+Biochemistry على الـ Carbohydrate لكن أهم شيء
+
+130
+00:11:29,330 --> 00:11:33,510
+عندنا الآن أنه مثل هذا التفاعل بالظبط هو اللي
+
+131
+00:11:33,510 --> 00:11:38,110
+بيصير لما بتتم عملية الإغلاق للجولوكوز هو تفاعل
+
+132
+00:11:38,110 --> 00:11:43,970
+Hemacetal Formation تفاعل تكوين Hemacetal
+
+133
+00:11:43,970 --> 00:11:47,270
+Intramolecular Hemacetal Formation
+
+134
+00:11:54,130 --> 00:12:00,390
+ممكن واجهنا الموضوع بصورة تانية احنا قلنا لو بدنا
+
+135
+00:12:00,390 --> 00:12:06,450
+نضيف كحول واحد بيصير عندنا hemacetal لما نكمل كمان
+
+136
+00:12:06,450 --> 00:12:11,690
+كحول بيصير acetal الان لاحظوا في مثل هذا التفاعل
+
+137
+00:12:11,690 --> 00:12:16,770
+يعني لو فعلنا ال acetone مع الethylene glycol هذا
+
+138
+00:12:16,770 --> 00:12:25,090
+كيتون الethylene glycolهو حقيقة die all يعني في
+
+139
+00:12:25,090 --> 00:12:30,670
+مجموعتين alcohol ألاحظون؟ في مجموعتين OAC يعني
+
+140
+00:12:30,670 --> 00:12:36,410
+كأنه بيمثل die alcohol بناء على ذلك هذا الـ
+
+141
+00:12:36,410 --> 00:12:40,290
+ethylene glycol لو إجا بده يتفاعل بيتفاعل على
+
+142
+00:12:40,290 --> 00:12:44,810
+مرتين بيكوّن في المرة الأولى يعني بإمكاننا نتطلع
+
+143
+00:12:44,810 --> 00:12:48,110
+إحنا أنه في المرة الأولى هذه تيجي تتفاعل وهذا تصير
+
+144
+00:12:48,980 --> 00:12:59,640
+هذه الحالة ستعطيك حالة وثيقة OH وهنا OH ثم
+
+145
+00:12:59,640 --> 00:13:05,780
+التفاعل الأول اللي هو كحول مع الكيتون أعطانا
+
+146
+00:13:05,780 --> 00:13:12,400
+hemiacetal الأن لأن الـ OH التانية موجودة تكمل
+
+147
+00:13:12,400 --> 00:13:19,310
+التفاعلsubstitution بتكون الacetal فهنا مجمعتين ال
+
+148
+00:13:19,310 --> 00:13:24,150
+OH موجودين في جزء واحد قبل شوية لما أخدنا الفكرة
+
+149
+00:13:24,150 --> 00:13:28,270
+العامة كنا نقول انه two alcohol molecules react
+
+150
+00:13:28,270 --> 00:13:32,730
+the first one and then the second one الان اللي
+
+151
+00:13:32,730 --> 00:13:39,260
+قاعد بيصير ان هذا الجزء نفسهموجود فيه مجموعتين
+
+152
+00:13:39,260 --> 00:13:43,240
+ألكوهول فبتفاعلوا بشكل متتالي أول تفاعل بتفاعل
+
+153
+00:13:43,240 --> 00:13:49,020
+واحدة منهم و بتعمل addition هذه العملية بهذا الشكل
+
+154
+00:13:49,020 --> 00:13:54,380
+هي عملية ايش addition وبعد هيك لما بدأت العملية
+
+155
+00:13:54,380 --> 00:14:02,740
+التانية substitution إبدال فبتكون عندنا ال acetone
+
+156
+00:14:02,740 --> 00:14:08,410
+ليش acetone لأن هذا أصلاجاي من الاسيتون اثيلين
+
+157
+00:14:08,410 --> 00:14:13,990
+غلايكول أسيتال لما بنيجي نسميه على الشقين تبعونه
+
+158
+00:14:13,990 --> 00:14:20,170
+هذا الجزء كان اسيتون هذا الجزء كان اثيلين غلايكول
+
+159
+00:14:20,170 --> 00:14:27,030
+فصار عند اسيتون اثيلين غلايكولأسيتال ليش أسيتال؟
+
+160
+00:14:27,030 --> 00:14:32,830
+لأنه متصل ب OR و ب OR لكن مثل هذا المركب لو كنتوا
+
+161
+00:14:32,830 --> 00:14:37,690
+بتكونوا تسموه، شو هتسموه؟ هتقولوا أسيتون، هاي جزء
+
+162
+00:14:37,690 --> 00:14:44,750
+الأسيتون، إثالين غلايكول، هيمي أسيتال لأن هذا متصل
+
+163
+00:14:44,750 --> 00:14:51,300
+في الكاربون OHو OR هذا hemacetal فهي ال acetone
+
+164
+00:14:51,300 --> 00:14:55,780
+إيثيلين جلايكل hemacetal هداك acetone إيثيلين
+
+165
+00:14:55,780 --> 00:15:03,820
+جلايكل acetal كامل لأ
+
+166
+00:15:03,820 --> 00:15:08,840
+لأ لأ نسبة لأبوه
+
+167
+00:15:12,530 --> 00:15:17,890
+نسبة لأبوه خلينا نوضح السؤال اللي بتسأله زملتكم ..
+
+168
+00:15:17,890 --> 00:15:23,870
+السؤال اللي بتسأله زملتكم كتير أشياء .. كتير أشياء
+
+169
+00:15:23,870 --> 00:15:31,030
+بتتسمى .. بتتسمى في الدنيا نسبة للأصل و كتير أشياء
+
+170
+00:15:31,030 --> 00:15:38,150
+في الدنيا بتتسمى نسبة للفرعواضح؟ يعني الأشياء ممكن
+
+171
+00:15:38,150 --> 00:15:44,390
+تتسمى نسبة للأصل والأشياء يمكن أن تسمى أيضا نسبة
+
+172
+00:15:44,390 --> 00:15:51,050
+لإيش؟ للفرعحسب ما بده الإنسان .. حسب ما بده
+
+173
+00:15:51,050 --> 00:15:56,190
+الإنسان يوضح شيء معين، يعني هذا .. هذا المفهوم
+
+174
+00:15:56,190 --> 00:16:02,130
+بالحياة شوية بنطلع عن الكيميا، يعني مثلا عائلة ..
+
+175
+00:16:02,130 --> 00:16:06,910
+عائلة محترمة، خلينا هيك نحكي، عائلة محترمة، إلها
+
+176
+00:16:06,910 --> 00:16:13,490
+إبن .. إلها إبن بيروح اللي هو بده يشتغل في مهنةغير
+
+177
+00:16:13,490 --> 00:16:18,050
+جائزة شرعان، مهنة محرمة، بدّو يشتغلوا في مصنع خمرة
+
+178
+00:16:18,050 --> 00:16:23,710
+بيسألوا أبوه إيش بتشتغل؟ أبوه راجل اتقل، محترم،
+
+179
+00:16:23,710 --> 00:16:29,190
+بيسألوا إيش بتشتغل؟ بيقولوا أنا بعصر عنب بعصر عنب،
+
+180
+00:16:29,190 --> 00:16:33,790
+الكلامتين حلال، العصر حلال والعنب حلال كان أبوه
+
+181
+00:16:33,790 --> 00:16:38,250
+بسرعة بيقولوا أنت بتعصر خمر هو بعصر خمر ولا بعصر
+
+182
+00:16:38,250 --> 00:16:43,910
+عنب؟لكن العناب يؤدي إلى ماذا؟ إلى الخمر فالأب
+
+183
+00:16:43,910 --> 00:16:48,510
+الفهمان بيقول و الله شغلتك ما هي صابطة ماتزينهاش و
+
+184
+00:16:48,510 --> 00:16:54,390
+لذلك إني أراني أعصره خمرا ملاحظين الآية إيش حكت؟
+
+185
+00:16:54,390 --> 00:16:58,270
+حكت هو الواحد بيوصل الخمر ولا بيوصل العناب هانا
+
+186
+00:16:58,270 --> 00:17:02,630
+سامة علىالفرع مش على الأصل الان اللي بتسألوا
+
+187
+00:17:02,630 --> 00:17:07,530
+زملتكم انه هذا ليش سميناه إيثالين glycol طب هو
+
+188
+00:17:07,530 --> 00:17:11,530
+مرمعنا تلت أربع مرات زي هيك مرمعنا تلت أربع مرات
+
+189
+00:17:11,530 --> 00:17:16,370
+زي هيك هاي ال إيثالين أفندي هاي الإيثالين هذا
+
+190
+00:17:16,370 --> 00:17:20,370
+اعملنا منه أكتر من شغله في كل الأحوال فقط خواصه
+
+191
+00:17:20,370 --> 00:17:24,630
+كإيثالين بس لما سميناه سميناه على أساسه إيش المثال
+
+192
+00:17:24,630 --> 00:17:30,010
+الأول اللي أخدناه؟لما كنا نعمله oxidation كان صير
+
+193
+00:17:30,010 --> 00:17:38,890
+زي هيك، ضال إيثالين ولا .. هانا الأصل، بس هذا إيش
+
+194
+00:17:38,890 --> 00:17:46,710
+سميته؟ إيثالين Oxide سميته على إيش؟ سميته على
+
+195
+00:17:46,710 --> 00:17:51,050
+الأصل تبعه، نفس الإيثالين هذا، لو أخدته مع الكئمن
+
+196
+00:17:51,050 --> 00:17:51,870
+O4
+
+197
+00:17:55,360 --> 00:18:02,240
+و OH في basic medium مثلا إيش صار؟ بطل إيثالين لكن
+
+198
+00:18:02,240 --> 00:18:08,140
+أنا لما بسمي إيثالين إيجليكول نسبة إلى إيش؟ نسبة
+
+199
+00:18:08,140 --> 00:18:15,520
+للأصل بس هو هنا مش إيثالين إيثالين إيجليكول بعد
+
+200
+00:18:15,520 --> 00:18:20,360
+هيك ممكن كمان تيجي تتذكر كمان شغلة إنه هذا
+
+201
+00:18:20,360 --> 00:18:25,910
+الإيثالين لما عملنا منه polymerفي وجود ال ROR
+
+202
+00:18:25,910 --> 00:18:30,330
+البروكسايد ال free radical polymerization شو صار
+
+203
+00:18:30,330 --> 00:18:41,140
+عندى صار عندى CH2 CH2 to the Nضال إثيلين في الـ
+
+204
+00:18:41,140 --> 00:18:44,660
+polymer ولا راحت ال double bond؟ راحت طب إيش
+
+205
+00:18:44,660 --> 00:18:49,700
+سمناها؟ poly .. polyethylene ولا polyethylene؟
+
+206
+00:18:49,700 --> 00:18:54,040
+polyethylene على الأصل فكل هذه المراكبات مسمية على
+
+207
+00:18:54,040 --> 00:18:54,940
+الأصل
+
+208
+00:18:59,340 --> 00:19:04,780
+فاحنا كتير بنسمي شغلات على الأصل اللي إجت منه،
+
+209
+00:19:04,780 --> 00:19:09,280
+كتير بنسمي شغلات على الأصل اللي إجت منه، نفس الأشي
+
+210
+00:19:09,280 --> 00:19:12,660
+هنا لو بدكتيجي تقولي ليش هذا سميته، هو هذا ضاي
+
+211
+00:19:12,660 --> 00:19:13,500
+الأسيتون
+
+212
+00:19:16,340 --> 00:19:20,640
+هذا ضايل أسيتون وهذا ضايل إثيلين غلايكون بهذا
+
+213
+00:19:20,640 --> 00:19:24,520
+الشكل هذه أسيتون وهذه إثيلين غلايكون بس هذه القطعة
+
+214
+00:19:24,520 --> 00:19:27,780
+جاية من أسيتون وهذه القطعة جاية من إثيلين غلايكون
+
+215
+00:19:27,780 --> 00:19:33,820
+فسمينا كله أسيتون نسبة للأصل إثيلين غلايكون نسبة
+
+216
+00:19:33,820 --> 00:19:43,240
+للأصل أو أسيتون واضح؟ فكثير احنا بنسمي نسبة
+
+217
+00:19:44,100 --> 00:19:51,180
+للاصل و مرات بنسمي نسبة للفرع و الأمثلة في ذلك في
+
+218
+00:19:51,180 --> 00:19:52,400
+العلوم الإنسانية
+
+219
+00:19:59,860 --> 00:20:04,980
+هنا عندكم مجموعة إثرائية من الأمثلة مجموعة إثرائية
+
+220
+00:20:04,980 --> 00:20:10,400
+من الأمثلة لاحظوا مثلا في المثال الأول مش كله يعني
+
+221
+00:20:10,400 --> 00:20:14,980
+ضروري احنا نتطلع عليها لأنه المفروض أنه تتدربوا في
+
+222
+00:20:14,980 --> 00:20:19,020
+البيت تكتبوا الشغل ولاحظوا يعني دائما في ال organ
+
+223
+00:20:19,020 --> 00:20:23,420
+ال chemistry مشكلة .. مشكلة عند الطلاب لما يدرسوا
+
+224
+00:20:23,420 --> 00:20:29,310
+الكيميا من slides و بس بيقرأها في الليل واضحةبييجي
+
+225
+00:20:29,310 --> 00:20:32,110
+في الامتحان بيده يعيد كتابة شغلة بيلاقي حاله
+
+226
+00:20:32,110 --> 00:20:35,410
+مابيعرفش يكتب انا كتير كان عندى احساس و انا بصلح
+
+227
+00:20:35,410 --> 00:20:39,150
+الامتحان لكوا و لا غيركوا ان انتوا فاهمين تماما
+
+228
+00:20:39,150 --> 00:20:45,610
+لكن ولا مرة اجيتوا و طبقتوا بالورقة و الجلم و
+
+229
+00:20:45,610 --> 00:20:48,590
+عدتوا الشغلة تلت مرات لحد ما أتقنتوا انكوا بتقدروا
+
+230
+00:20:48,590 --> 00:20:51,410
+ترسموها عشان هيك الشغلة اللي فاهمينها ماجدرتوش
+
+231
+00:20:51,410 --> 00:20:57,130
+يتعبرواماقدرتوش يتعبروا عنها و دائما أنا يعني بذكر
+
+232
+00:20:57,130 --> 00:21:01,390
+مقولة أستاذي و يمكن حكيتهلكوا إياها الدكتور عادي
+
+233
+00:21:01,390 --> 00:21:04,230
+الجرار علمناه في الجامعة الأردنية كان يقولنا
+
+234
+00:21:04,230 --> 00:21:08,430
+الكيميائي الشاطر هو الكيميائي اللي عن يمينه ورق
+
+235
+00:21:08,430 --> 00:21:14,810
+خرطوش و عن شماله سلة محملات و كل شغلة بيكتب و
+
+236
+00:21:14,810 --> 00:21:20,610
+بيرمى بيكتب و بيرمى بتصير الإيد تبعته متعودة إنها
+
+237
+00:21:20,610 --> 00:21:28,080
+اتنفذماعد ذلك خلاص هو بده يحتفظ بالورق بستعمل
+
+238
+00:21:28,080 --> 00:21:33,740
+الخبز ولا إيش ماكان واضح؟ الآن لاحظوا هذا المثال
+
+239
+00:21:33,740 --> 00:21:37,760
+أي مثال من هدول كان ممكن نجيب الكياب سهولة في
+
+240
+00:21:37,760 --> 00:21:41,860
+امتحان بس المهم أنه لازم تكتبوا بيدكوا عشان تتقنوا
+
+241
+00:21:41,860 --> 00:21:45,840
+ال organ chemistry هنا عندي الديهيد مع two
+
+242
+00:21:45,840 --> 00:21:50,910
+alcoholsشو اللي بدى يتكون عندى في هذه الحالة ال
+
+243
+00:21:50,910 --> 00:21:56,330
+final product أسيتال بمعنى هتصير OR و ال OH
+
+244
+00:21:56,330 --> 00:22:00,650
+التانية برضه هتصير OR Oethyl و Oethyl هى شكل
+
+245
+00:22:00,650 --> 00:22:07,450
+الأسيتال هى شكل الأسيتال هنا عندى مثال شبيه في
+
+246
+00:22:07,450 --> 00:22:11,910
+اللى حكيناه قبل شوية Cyclohexanone كيتون وهذا
+
+247
+00:22:13,750 --> 00:22:19,790
+ethylene glycol هيتفاعل مرتين إذا هانا هيعمل O O
+
+248
+00:22:19,790 --> 00:22:24,010
+بهذا الشكل الآن صدقوني هذه إذا في المثال السابق
+
+249
+00:22:24,010 --> 00:22:28,170
+وفي هذا المثال ما دربتوش إيدكوا عليها بسهولة لو
+
+250
+00:22:28,170 --> 00:22:32,250
+أجتكوا في الامتحان مش هتعرفوا ترسموها رغم أنه واضح
+
+251
+00:22:32,250 --> 00:22:40,130
+أن تنتيل O H's يتفاعلوا ورا بعض واضح؟ هانا إيش
+
+252
+00:22:40,130 --> 00:22:41,850
+المثال إذا بتلاحظوا
+
+253
+00:22:46,590 --> 00:22:53,810
+هذا مثال مزدوج .. هذا مثال مزدوج فى عندى ketone و
+
+254
+00:22:53,810 --> 00:23:00,130
+فى عندى OH ايش بتعمل ال OH هذه؟ بدى تعمل
+
+255
+00:23:00,130 --> 00:23:05,150
+intramolecular reaction طبعا تحاولوا تسكر المركب
+
+256
+00:23:05,150 --> 00:23:11,710
+حيصير هذا O و هذا ال O تتحول إلى OH بعد هي تلاحظوا
+
+257
+00:23:11,710 --> 00:23:17,430
+ايش ضاف؟ضاف كمان كحول خارج يعني كأنه في هذه
+
+258
+00:23:17,430 --> 00:23:21,490
+المسألة عمل كحول داخل اللي هو أول تفاعل ال
+
+259
+00:23:21,490 --> 00:23:27,210
+formation of hemiacetal من ال OH الداخلية اتفاعلت
+
+260
+00:23:27,210 --> 00:23:31,310
+بعد هيك راح جاب كحول من الخارج methanol الميثانول
+
+261
+00:23:31,310 --> 00:23:38,250
+حل محل ال OH فأعطانا هذا المركب بعرفش إذا واضح ولا
+
+262
+00:23:38,250 --> 00:23:45,300
+بيلزم نعمله تفصيل إضافة واضح هذا المثال؟تطلعوا
+
+263
+00:23:45,300 --> 00:23:49,660
+مرات وين بتصير المشكلة .. مرات وين بتصير المشكلة
+
+264
+00:23:49,660 --> 00:23:54,860
+أنه كيف أرتب الأشياء بحيث تكون المتفاعلات جاية
+
+265
+00:23:54,860 --> 00:23:59,760
+بشكل قريب على بعضها البعض، يعني نفس هذا .. نفس هذا
+
+266
+00:23:59,760 --> 00:24:05,040
+اللي موجود هنا، لو أنا كتبته بهذه الصيغة CH3 C
+
+267
+00:24:05,040 --> 00:24:07,180
+double bond O و بعدين اعملت
+
+268
+00:24:14,200 --> 00:24:18,520
+هذا نفس هذا كاربون اتنين تلاتة اربعة خمسة كاربون
+
+269
+00:24:18,520 --> 00:24:22,000
+اتنين تلاتة اربعة خمسة و حملة أو أتش و هذا ممكن
+
+270
+00:24:22,000 --> 00:24:27,520
+نخليه هكذا بشكل انا انا صار واضح عندى ان هاي
+
+271
+00:24:27,520 --> 00:24:33,400
+الكهول و هاي كيتل بناء على ذلك شو التفاعل اللى
+
+272
+00:24:33,400 --> 00:24:39,040
+احنا بنتوقعه في هذه الحالة ان هذه بتهاجم هنا و هذه
+
+273
+00:24:40,430 --> 00:24:44,770
+بنتيجة هنا تصير OH فالنتج اللي بده يتكون بهذه
+
+274
+00:24:44,770 --> 00:24:52,910
+الحالة كنتج مرحلة في نص الطريق هذه
+
+275
+00:24:52,910 --> 00:25:04,480
+CH3 وهذه OH إذا هذا التفاعل عمل لكهيمي أسيتال هذا
+
+276
+00:25:04,480 --> 00:25:09,520
+التفاعل عمل هيمي أسيتال الآن راحوا لحقوا هذا
+
+277
+00:25:09,520 --> 00:25:13,960
+التفاعل بتفاعل تاني فعلوه كمان مرة مع الميثانون
+
+278
+00:25:15,000 --> 00:25:19,980
+ماذا تفعل الميثانول؟ تحل محل الـ OH وتطرد الـ OH و
+
+279
+00:25:19,980 --> 00:25:23,860
+تحل المحلة و تظهر النتج اللي عندكم إذا النتج اللي
+
+280
+00:25:23,860 --> 00:25:28,900
+عندكم هو نتاج خطوتين حقيقة التفاعل الأول اللي هو
+
+281
+00:25:28,900 --> 00:25:33,760
+الـ intramolecular reaction to form the hemiacetal
+
+282
+00:25:33,760 --> 00:25:38,540
+و بعد هيك ال substitution reaction to form the
+
+283
+00:25:38,540 --> 00:25:44,060
+acetalأول تفاعل Intramolecular هي الـ OH والـ C
+
+284
+00:25:44,060 --> 00:25:48,160
+double bond O في نفس الجزيء Intramolecular هذا
+
+285
+00:25:48,160 --> 00:25:51,720
+بنوصفه مظبوط ولا لا؟ بعد ذلك التفاعل التالي لما
+
+286
+00:25:51,720 --> 00:25:56,720
+أجيب هذا كله جزيء والميطانول جزيء This is
+
+287
+00:25:56,720 --> 00:26:01,500
+intramolecular reaction
+
+288
+00:26:01,500 --> 00:26:05,360
+واضح المثال هذا؟
+
+289
+00:26:08,510 --> 00:26:15,310
+بس بالتأكيد بيلزم تتدربوا عليه الآن المثال اللي
+
+290
+00:26:15,310 --> 00:26:24,930
+بعده شوية بدون ورقة وقلم انا بأكدلكوا انه صعب
+
+291
+00:26:24,930 --> 00:26:29,550
+انكوا تصلوله يعني لاحظوا كيف مرات الأمثلة بتكون
+
+292
+00:26:29,550 --> 00:26:36,050
+موجودة ومرسومة وإيش الناتج كيف هذا الناتج طلع من
+
+293
+00:26:36,050 --> 00:26:42,690
+هذا المثالأنا حقيقة بهذا المثال وببساطة عندي C
+
+294
+00:26:42,690 --> 00:26:51,330
+double bond O وعندي تنتين OH OH إذا هيتم تفاعل على
+
+295
+00:26:51,330 --> 00:26:57,770
+مرتين مرة مع ال OH الأولى ويعمل ليهمي أسيتال ومرة
+
+296
+00:26:57,770 --> 00:27:03,230
+مع ال OH التانية ويعمل أسيتال فقط اللي بيلزم فقط
+
+297
+00:27:03,230 --> 00:27:07,670
+اللي بيلزم عاد كيف نكون مرتبين الجزء بحيث نعمله
+
+298
+00:27:08,400 --> 00:27:12,480
+بالشكل الناتج اللي هو أنا الحلقة تانية يعني لو
+
+299
+00:27:12,480 --> 00:27:16,880
+أخدنا هذه ال carbon لو أخدنا هذه ال carbon اللي هي
+
+300
+00:27:16,880 --> 00:27:23,240
+السيضة بال bond السيضة بال bond O بهذا الشكل بعد
+
+301
+00:27:23,240 --> 00:27:27,080
+ذلك بدنا نتحرك بشكل متعاكس عشان نحط باقي ال carbon
+
+302
+00:27:27,080 --> 00:27:31,620
+كام carbon عندي غيرها؟ واحد اتنين تلاتة اربعة و ال
+
+303
+00:27:31,620 --> 00:27:43,850
+O هاي واحد اتنين تلاتة اربعةوهنا ال O هى O H هى ده
+
+304
+00:27:43,850 --> 00:27:50,630
+الجزء الآن على الجهة التانية على
+
+305
+00:27:50,630 --> 00:27:54,710
+الجهة التانية كام carbon عندى برضه اربعة واحد
+
+306
+00:27:54,710 --> 00:28:02,010
+اتنين تلاتة اربعة و
+
+307
+00:28:02,010 --> 00:28:02,830
+ال O هذه
+
+308
+00:28:08,700 --> 00:28:15,980
+أو أتش هذا نفس هذا بس غيرنا طريقة الرسم الآن لو
+
+309
+00:28:15,980 --> 00:28:19,220
+كنتوا تقولوا كيف تم التفاعل وممكن هذه عشان كمان
+
+310
+00:28:19,220 --> 00:28:24,580
+المنظر اللي خليكي بشكل مستقيم هاي أو أتش كيف بتم
+
+311
+00:28:24,580 --> 00:28:31,160
+التفاعل أول تفاعل هذه ال أو أتش بتهاجم هنا وهذه
+
+312
+00:28:31,160 --> 00:28:36,660
+بتصير أو أتش تاني تفاعلنعمله باللون الأزرق، هاي
+
+313
+00:28:36,660 --> 00:28:42,020
+أول تفاعل صار واضح، تاني تفاعل هذه الـ OH بتهاجم
+
+314
+00:28:42,020 --> 00:28:49,620
+هنا وبتطرد كل الـ OH اللي اتكونت هنا، صار النتيجة
+
+315
+00:28:52,470 --> 00:28:57,590
+هذا هو نفس هذا فقط طريقة الرسم اختلفت عندكم OH
+
+316
+00:28:57,590 --> 00:29:02,510
+بدأت تتفاعل لأول مرة و OH بدأت تتفاعل لتانى مرة
+
+317
+00:29:02,510 --> 00:29:07,150
+التفاعل على ايش؟ على مرتين هذه ال OH لما تتفاعل
+
+318
+00:29:07,150 --> 00:29:11,250
+بيصير عنده hemacetal التفاعل اللى ماشرله بالأحمر
+
+319
+00:29:11,250 --> 00:29:16,150
+بتيجى ال OH التانية بتطرد ال OH الأولى بتكون عند
+
+320
+00:29:16,150 --> 00:29:18,870
+ال acetal بيصير عند هذا المركب
+
+321
+00:29:22,460 --> 00:29:30,940
+أخر تفاعل سهل و بسيط بدل ما كان عندى ethylene
+
+322
+00:29:30,940 --> 00:29:38,880
+glycol OH OH ممكن استعمل التيو كومباوند الهو بدل
+
+323
+00:29:38,880 --> 00:29:46,120
+ال OH SH SH ما هي ال SH و ال OH بتفاعلوا زي بعض
+
+324
+00:29:46,120 --> 00:29:51,600
+الان كيف هذا التفاعل هنا تنتهي ال OHSأعطانا هذا
+
+325
+00:29:51,600 --> 00:29:55,100
+النتج تفاعله على مرتين نفس الشيء الـSH هاتيجي
+
+326
+00:29:55,100 --> 00:30:01,820
+تتفاعل هنا SS ولمّا يكون عنده جزايين هيتفاعلوها
+
+327
+00:30:01,820 --> 00:30:10,460
+هيتفاعلوها ملاحظين هاي هذا الجزء زي هذا الجزء
+
+328
+00:30:10,460 --> 00:30:16,480
+تماما فقط ال oxygen بدل ما هي oxygen صارت sulfur
+
+329
+00:30:16,480 --> 00:30:21,520
+الآن عندنا C double bond O تاني على الجهة هذهبنكرر
+
+330
+00:30:21,520 --> 00:30:28,860
+التفاعل على الجهة التانية، واضح؟ شوية هذه أمثلة
+
+331
+00:30:28,860 --> 00:30:35,770
+متطورة، هي الفكرة في الأورجان الكيميستريان انتوا
+
+332
+00:30:35,770 --> 00:30:39,770
+بتتعلموا التفاعل البسيط ان انتوا بتتعلموا التفاعل
+
+333
+00:30:39,770 --> 00:30:44,310
+البسيط اذا أتقنتوا بعدك لو حطناها في مكان كبير
+
+334
+00:30:44,310 --> 00:30:49,230
+وواسع مع جزائي كبير زي هيك بتغير التفاعل البسيط؟
+
+335
+00:30:49,230 --> 00:30:54,290
+مابتغيرش يعني هذا التفاعل هو نفس التفاعل كل هذه
+
+336
+00:30:54,290 --> 00:30:57,170
+نفس التفاعلات البسيطة اللي أخدناها بس هنا الجزيات
+
+337
+00:30:57,170 --> 00:31:02,690
+إيش مالها؟كبرت، زي أي إنسان أو إنسانة مثلا بتعلم
+
+338
+00:31:02,690 --> 00:31:07,050
+سواج السيارات، هو بتعلمهم بشوارع صغار في منطقة
+
+339
+00:31:07,050 --> 00:31:10,470
+هادئة، الآن هيدلوا طول عمره بشوارع صغار في منطقة
+
+340
+00:31:10,470 --> 00:31:13,910
+هادئة؟ ولا لو بعتناه بعد ذلك على الـNew York، بده
+
+341
+00:31:13,910 --> 00:31:19,570
+يعرف يسوج السيارة فيها؟هي نفس المبادئ، مظبوط؟
+
+342
+00:31:19,570 --> 00:31:23,630
+فانتوا في الأول بتتعلموا المبادئ وهنا بيصير انه
+
+343
+00:31:23,630 --> 00:31:27,310
+يعني كيف الكيميا هي علم بيكبر و علم أبحاث انه
+
+344
+00:31:27,310 --> 00:31:30,850
+انتوا اللي زيكوا بياخد المبادئ طب طالب الماجستير
+
+345
+00:31:30,850 --> 00:31:36,630
+شو بيعمل؟ بيروح على جزايين اكبار كتير و بفاعل OH
+
+346
+00:31:36,630 --> 00:31:40,130
+مع C double bond O و بيعمل hemacetal بس المشكلة ان
+
+347
+00:31:40,130 --> 00:31:45,360
+الجزايين اللي بيشتغل فيهم اكبار، لكن التفاعلهو
+
+348
+00:31:45,360 --> 00:31:50,760
+اللي درسوا بسنة أولى عشان هيك يعني بيكفى بيكفى
+
+349
+00:31:50,760 --> 00:31:55,200
+لطلاب مثلا التربية أو اللي هم التحاليل الطبية أنه
+
+350
+00:31:55,200 --> 00:31:58,780
+احنا نعطيهم مساق واحد مبادئ زي بني أدم علمناه يسوق
+
+351
+00:31:58,780 --> 00:32:04,900
+سيارة بعد هيك لو حضرتوا مؤتمر كيميا هتلاقوا أنه
+
+352
+00:32:04,900 --> 00:32:09,060
+الإنسان اللي بيشرح مثلا ممكن يمر عليه كيف تعملوا
+
+353
+00:32:09,060 --> 00:32:13,140
+hemacetal لكن بيكون الجزيئات اللي بتعامل معها
+
+354
+00:32:13,990 --> 00:32:19,970
+جزيئات كبيرة جزيئات كبيرة ولا البنا اللي بيبني
+
+355
+00:32:19,970 --> 00:32:24,750
+البرج مش هو نفسه اللي بتترب على بنا حيطة مظبوط ولا
+
+356
+00:32:24,750 --> 00:32:29,270
+لأ؟ وهذا هو اللي بيصير هنا انه جد ما تكبر الجزيئات
+
+357
+00:32:29,270 --> 00:32:34,070
+لكن المبدأ هذا اللي احنا قاعدين بنقشر عليه اتغير
+
+358
+00:32:34,070 --> 00:32:42,170
+hemacetal بعدين acetal addition بعدين substitution
+
+359
+00:32:42,170 --> 00:32:43,610
+ولو الجزيئة
+
+360
+00:32:58,740 --> 00:33:03,340
+الان على نفس المبدأ بناخد الـ nucleophile تاني
+
+361
+00:33:03,340 --> 00:33:10,140
+يعني مش معقول الحصة كلها بس نضيع على الكحول يعني
+
+362
+00:33:10,140 --> 00:33:13,260
+لو أتينا بعد كل هالتعب بدنا نقول إيش اللي أخدته
+
+363
+00:33:14,520 --> 00:33:20,380
+بسطر واحد الكحول بيعمل addition و يتبع في
+
+364
+00:33:20,380 --> 00:33:24,680
+substitution خلصنا مافيش اكتر من هيك الان ال
+
+365
+00:33:24,680 --> 00:33:28,120
+addition of hydrogen cyanide ال hydrogen cyanide
+
+366
+00:33:28,120 --> 00:33:32,060
+النيوكليوفايل اللي فيه اللي بتفعل في النهاية هو ال
+
+367
+00:33:32,060 --> 00:33:37,180
+CN و بتفعل من خلال الكربون الان نفس التفاعل تماما
+
+368
+00:33:37,180 --> 00:33:44,750
+ال CN بده تهاجم و ال O بده تصير OHالـCN بدأ تهاجم
+
+369
+00:33:44,750 --> 00:33:50,130
+والـO بدأ تصير OH الان لو اتينا واطلعنا مثلا هنا
+
+370
+00:33:50,130 --> 00:33:54,270
+هذا أسيتون هذا أسيتالديهيد لاحظوا التفاعل بتكرر
+
+371
+00:33:54,270 --> 00:33:59,950
+ولو الجزيئات اشمالها بتكبر هاي الـCN بتهاجم والـO
+
+372
+00:33:59,950 --> 00:34:05,110
+بتصير OH أو التفاعل أسيتالديهيد اللي بعده أسيتون
+
+373
+00:34:05,110 --> 00:34:11,210
+طب هذا Cyclohexanone نفس الفكرة تماما الـCN بتهاجم
+
+374
+00:34:12,020 --> 00:34:17,220
+و ال O بتصير OH الان لازم تكونوا متأكدين 100% انه
+
+375
+00:34:17,220 --> 00:34:20,920
+انا لو بدأ اسألكوا في الامتحان لأ هجيب
+
+376
+00:34:20,920 --> 00:34:26,900
+Acetaldehyde ولا Acetone ولا Cyclohexanone لإن
+
+377
+00:34:26,900 --> 00:34:31,520
+انا علمتكوا مبدأ مش علمتكوا جزاء لإن انا علمتكوا
+
+378
+00:34:31,520 --> 00:34:36,480
+مبدأ الان لو اجيت جبتلكوا مثل زي C double bond OH
+
+379
+00:34:36,480 --> 00:34:44,080
+CH2 و حطيت هنا بنزينةو حطيت هنا cl و حطيت هنا ch3
+
+380
+00:34:44,080 --> 00:34:53,300
+و بعدين قلتلكم مع ال hcn و
+
+381
+00:34:53,300 --> 00:35:00,540
+لو الجزء كبر لكن التفاعل المبدأ نفسه ان هذي بتهاجم
+
+382
+00:35:01,530 --> 00:35:04,890
+وهذا يحصل في بعض الأحيان، ونضع النتجة المشكلة
+
+383
+00:35:04,890 --> 00:35:09,990
+الكتير عندكم مرات ان انتوا ماانتبهتوش للرؤوس
+
+384
+00:35:09,990 --> 00:35:16,490
+المتفاعلة دائما في الكيميا، ما تخافوش من الجزء
+
+385
+00:35:16,490 --> 00:35:21,320
+الكبيرأهم شيء في الجزية الكبيرة أن تفهموا أين
+
+386
+00:35:21,320 --> 00:35:24,180
+الرأس اللي بدي يتفاعل فيه انتوا عندكوا هنا CL
+
+387
+00:35:24,180 --> 00:35:28,480
+وعندكوا هنا C double bond O بس هدولة الرأسين اللي
+
+388
+00:35:28,480 --> 00:35:33,060
+بتفاعلوا زي ما نيجي نقول و الله عملية المصافحة إيش
+
+389
+00:35:33,060 --> 00:35:37,800
+عملية المصافحة التقاء التان تان تان الان ممكن
+
+390
+00:35:37,800 --> 00:35:42,490
+المصافحة تكون بين طفلينممكن تكون بين طفل وإنسان
+
+391
+00:35:42,490 --> 00:35:46,910
+كبير، ممكن تكون بين زعيمين بيوضعوا بعض قبل ما
+
+392
+00:35:46,910 --> 00:35:53,010
+يفقدوا العرش، كله ممكن، واضح؟ الان لاحظوا حتى في
+
+393
+00:35:53,010 --> 00:35:57,930
+التسمية، الان هذا Acetaldehyde بيعطيني Cl و OH،
+
+394
+00:35:57,930 --> 00:36:01,930
+هذه المجموعة اللي فيها المركبات اللي حاملة على
+
+395
+00:36:01,930 --> 00:36:07,810
+الكربون الواحدة Cl و OH بيسموها cyanohydrins
+
+396
+00:36:08,620 --> 00:36:13,060
+فالمُركّب إذا كان أصله Acetaldehyde هانا تسميه على
+
+397
+00:36:13,060 --> 00:36:17,520
+إيش؟ على الأصل إذا أصله Acetaldehyde بنسميه
+
+398
+00:36:17,520 --> 00:36:26,580
+Acetaldehyde و بنضيف عليه Cyanohedrin
+
+399
+00:36:26,580 --> 00:36:30,060
+Acetaldehyde
+
+400
+00:36:30,060 --> 00:36:35,840
+Cyanohedrin إيش يعني Cyanohedrin؟ إنه على الكربون
+
+401
+00:36:35,840 --> 00:36:42,750
+موجود عندي CNو OH فالأصل Acetaldehyde لما اتفعل مع
+
+402
+00:36:42,750 --> 00:36:46,610
+ال HCN أعطاني Acetaldehyde-Cyanohydride الأن
+
+403
+00:36:46,610 --> 00:36:53,510
+المركب التالي كلكوا هيتسموه بسهولة شو هيكون اسمه؟
+
+404
+00:36:53,510 --> 00:37:03,190
+أسيتون سيانوهيدرين المركب التالت هذا
+
+405
+00:37:05,160 --> 00:37:10,420
+Cyclohexanone بنقولش Cyclohexane ممكن واحدة لما
+
+406
+00:37:10,420 --> 00:37:13,720
+تيجي تسميه هنا تشوف هذا Cyclohexane وين
+
+407
+00:37:13,720 --> 00:37:17,260
+Cyclohexanone هذا Cyclohexanone تروح تسميه
+
+408
+00:37:17,260 --> 00:37:20,720
+Cyclohexane-Cyanohydrin لأ احنا بنسميه
+
+409
+00:37:20,720 --> 00:37:26,660
+Cyclohexanone طب فيه هنا Cyclohexanone نسبة للأصل
+
+410
+00:37:26,660 --> 00:37:32,240
+Cyclohexanone-Cyanohydrin هذا أخر مركب اللي موجود
+
+411
+00:37:32,240 --> 00:37:32,580
+هنا
+
+412
+00:37:36,320 --> 00:37:47,700
+شو اسم هذا المُركّب؟ بنزين بقالدهايد بنزالدهايد
+
+413
+00:37:47,700 --> 00:37:52,660
+بنزالدهايد
+
+414
+00:37:52,660 --> 00:37:55,840
+سيانوهيدرين بنزالدهايد بنزالدهايد سيانوهيدرين و لو
+
+415
+00:37:55,840 --> 00:38:00,880
+هذه صارت CH3 لو
+
+416
+00:38:00,880 --> 00:38:05,740
+هذه صارت CH3 هيصير أسيتوفينون
+
+417
+00:38:07,050 --> 00:38:11,550
+Cyanohydrin إذا أنا زي ما بتلاحظوا بتعلم قواعد
+
+418
+00:38:11,550 --> 00:38:16,690
+عامة سواء في التفاعل أو حتى في نظام التسمية
+
+419
+00:38:16,690 --> 00:38:21,910
+والقواعد العامة جاعدة بتتكرر ولا لأ نفس المنطق
+
+420
+00:38:21,910 --> 00:38:26,670
+يعني أنا أنا بعيد نفس المنطق في كل الأحوال هذه حتى
+
+421
+00:38:26,670 --> 00:38:31,450
+طريقة التسمية أنه أنا بسمل الديهايد أو ال ketone و
+
+422
+00:38:31,450 --> 00:38:35,090
+باتبعه بكلمات cyanohydrin
+
+423
+00:38:43,950 --> 00:38:46,450
+خلاص اليوم صيف الله يعطيكوا العافية
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/mxpHX6Gn5_w_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/mxpHX6Gn5_w_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e3a56b883ac06606d0b99c14396d62fc53f47190
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/mxpHX6Gn5_w_postprocess.srt
@@ -0,0 +1,1720 @@
+1
+00:00:14,980 --> 00:00:20,280
+بسم الله الرحمن الرحيم بنبدأ اليوم إن شاء الله في
+
+2
+00:00:20,280 --> 00:00:26,140
+إعطاء مقدمة لمساق الكيمية العضوية لطلبة العلوم
+
+3
+00:00:26,140 --> 00:00:33,660
+الحياتيةطبعاً بشكل عام أي مقدمة بتكون عادة يعني في
+
+4
+00:00:33,660 --> 00:00:40,200
+غالبها تذكير بموضوعات سبق وإنه يعني درست في مساقات
+
+5
+00:00:40,200 --> 00:00:43,200
+الكيميا العامة سواء المساق الأول أو الثاني
+
+6
+00:00:43,200 --> 00:00:46,520
+فهيلزمنا
+
+7
+00:00:46,520 --> 00:00:51,000
+مفهوم ال bonding أو الارتباط يعني كيف بتتكون
+
+8
+00:00:51,000 --> 00:00:57,150
+الروابط في مساق الكيميا العضويةلو بدنا نذكر بهذا
+
+9
+00:00:57,150 --> 00:01:02,090
+الموضوع طبعا الموضوع مرتبط في الذرّة كلنا بنكون
+
+10
+00:01:02,090 --> 00:01:07,350
+عارفين أن الذرّة بشكل عام كانت بتتكون من النواء
+
+11
+00:01:07,350 --> 00:01:13,070
+الموجبة و هذه النواء الموجبة بتحتوي على البروتونات
+
+12
+00:01:13,070 --> 00:01:17,970
+و بتحتوي على النيوترونات طبعا ليش النواء بشكل عام
+
+13
+00:01:17,970 --> 00:01:24,490
+موجبة؟ لأن البروتونات موجبةوحول النواء تدور
+
+14
+00:01:24,490 --> 00:01:28,790
+الإلكترونات السالبة بناء على ذلك ولأنه بشكل عام
+
+15
+00:01:28,790 --> 00:01:33,470
+البروتونات والإلكترونات متساوية في العدد طبعا كنا
+
+16
+00:01:33,470 --> 00:01:41,130
+نقول أنه ذرة متعادلة بشكل عام العناصر بتعرف من عدد
+
+17
+00:01:41,130 --> 00:01:46,330
+البروتونات الموجبة اللي موجودة مثلا في الهيدروجين
+
+18
+00:01:46,330 --> 00:01:52,050
+في عندنا one proton في ال helium-2 وهكذاطيب
+
+19
+00:01:52,050 --> 00:01:57,770
+الإلكترونات احنا قلنا بتدور حول النوال موجبة لما
+
+20
+00:01:57,770 --> 00:02:02,290
+نيجي نسأل كيف الإلكترونات بتدور أخدنا شيء اسمه
+
+21
+00:02:02,290 --> 00:02:06,810
+Electronic Configuration و بنراجعه هنا بسرعة كبيرة
+
+22
+00:02:06,810 --> 00:02:11,930
+لحقيقة لأنه زي ما حكينا احنا هو فقط يعني تذكير
+
+23
+00:02:11,930 --> 00:02:17,830
+سريع احنا اتفقنا أنه في عندناللتوزيع الإلكتروني
+
+24
+00:02:17,830 --> 00:02:22,670
+مدارات رئيسية Shales المدار الأول المدار التاني
+
+25
+00:02:22,670 --> 00:02:28,710
+المدار التالت المدار الرابع ولمخدة الرمز N كل مدار
+
+26
+00:02:28,710 --> 00:02:34,590
+رئيسي بيقسم إلى مجموعة من المدارات الفرعية عدد
+
+27
+00:02:34,590 --> 00:02:41,190
+المدارات الفرعية بشكل عام بساوياللي هو رقم المدار
+
+28
+00:02:41,190 --> 00:02:46,170
+الرئيسي مثلا المدار الأول بيكون فيه مدار فرعي واحد
+
+29
+00:02:46,170 --> 00:02:51,710
+هو المدار الفرعي S ال sub shell S المدار التاني
+
+30
+00:02:51,710 --> 00:02:55,990
+بيكون فيه اتنين sub shells مدارات فرعية اللي هم S
+
+31
+00:02:55,990 --> 00:03:01,630
+و B المدار التالت بيكون فيه تلاتة sub shells S و B
+
+32
+00:03:01,630 --> 00:03:05,780
+و D و هكذابعد ما عرفنا أنه في عندنا المدارات
+
+33
+00:03:05,780 --> 00:03:09,500
+الرئيسية الـ shells المدارات الفرعية الـ subshells
+
+34
+00:03:09,500 --> 00:03:16,000
+في عندنا ال orbitals ال orbitals هي المكان بالفراغ
+
+35
+00:03:16,000 --> 00:03:21,320
+اللي بتوجد فيه الإلكترونات وكل orbital بشكل عام
+
+36
+00:03:21,320 --> 00:03:28,400
+بيحتوي على two electrons فال ال S subshell بيكون
+
+37
+00:03:28,400 --> 00:03:33,050
+فيه بس orbital واحد اللي هو ال Sالـ B-subshell
+
+38
+00:03:33,050 --> 00:03:39,250
+بيكون فيه تلاتة orbitals اللي هم متعامدات على بعض
+
+39
+00:03:39,250 --> 00:03:44,790
+سبق أننا درسناهم اللي بنسميهم BX وBY وBZ الـ D
+
+40
+00:03:44,790 --> 00:03:49,730
+-subshell بيكون فيه
+
+41
+00:03:49,730 --> 00:03:57,070
+خمسة orbitals اللي اسمها DXY DXY DYZ DXZ DZ² DX²
+
+42
+00:03:57,070 --> 00:04:02,820
+-Y² إحنا اللي بهمنا في هذه المرحلةانه كل orbital
+
+43
+00:04:02,820 --> 00:04:07,420
+بيحتوي على إلكترونين فبناء على ذلك ال S orbital
+
+44
+00:04:07,420 --> 00:04:12,140
+بيكون فيه two electrons ال BX two electrons ال BY
+
+45
+00:04:12,140 --> 00:04:16,460
+two electrons ال BZ two electrons عشانك لما انا
+
+46
+00:04:16,460 --> 00:04:22,480
+بده اقول ان ال B بالمجمل كام orbital تلاتة بتحتوي
+
+47
+00:04:22,480 --> 00:04:29,520
+كام إلكترون ستة ال D orbitalsأو الـ D-sub shell
+
+48
+00:04:29,520 --> 00:04:33,660
+مكوّن من خمسة orbitals كل orbital بياخد إلكترونين
+
+49
+00:04:33,660 --> 00:04:37,660
+بناء على ذلك عدد الإلكترونات في الـ D-sub shell
+
+50
+00:04:37,660 --> 00:04:41,780
+بيكون عشرة عدد ال orbitals في الـ D-sub shell
+
+51
+00:04:41,780 --> 00:04:50,960
+بيكون خمسة على هذا الأساس ممكن أنهانتبع بتدرج
+
+52
+00:04:50,960 --> 00:04:55,180
+التوزيع الإلكتروني مثلا الذرة اللي فيها one
+
+53
+00:04:55,180 --> 00:04:59,240
+electron اللي هي الهيدروجين بنقول توزيع الإلكتروني
+
+54
+00:04:59,240 --> 00:05:03,400
+one S one الذرة اللي فيها two electrons الهيليام
+
+55
+00:05:03,400 --> 00:05:09,040
+بنقول one S two الآن ال S أقصى تحمل إليه I orbital
+
+56
+00:05:09,040 --> 00:05:13,740
+أقصى تحمل إليه إلكترونين بناء على ذلك هنا بنكون
+
+57
+00:05:13,740 --> 00:05:17,900
+خلصنا one S one الهيدروجين one S two الهيليام لو
+
+58
+00:05:17,900 --> 00:05:23,550
+إجينا للليفيامالليثيام بـ 3 إلكترونات أول اتنين
+
+59
+00:05:23,550 --> 00:05:27,670
+هيروحوا على الـ 1S2 بعدين الإلكترون التالت هيروح
+
+60
+00:05:27,670 --> 00:05:33,930
+على الـ 2S1 بعده البريليام بيروح 2S2 الآن الـ 2S
+
+61
+00:05:33,930 --> 00:05:38,950
+سكر بنبدأ في الـ B-Orbitals الـ B-Orbitals بياخدوا
+
+62
+00:05:38,950 --> 00:05:43,070
+بحد أقصى 6 إلكترونات بناء على ذلك البرون بيكون
+
+63
+00:05:43,070 --> 00:05:48,690
+تركيبه الإلكتروني 1S2 → 2S2 → 2B1 الكربون اللي هو
+
+64
+00:05:48,690 --> 00:05:54,080
+العنصر الأهم عندنافي أساس الـ organic chemistry
+
+65
+00:05:54,080 --> 00:05:59,060
+الكربون ست إلكترونات ضروري نتبه للكربون عدد
+
+66
+00:05:59,060 --> 00:06:03,560
+الإلكترونات في الكربون ست إلكترونات الان لو قلنا
+
+67
+00:06:03,560 --> 00:06:07,220
+ايش التوزيع الإلكتروني للكربون التوزيع الإلكتروني
+
+68
+00:06:07,220 --> 00:06:13,140
+للكربون 1S2 2S2 2B2 واضح؟
+
+69
+00:06:16,500 --> 00:06:20,540
+وهكذا لو بدنا نشوف توزيع الـ Nitrogen والـ Oxygen
+
+70
+00:06:20,540 --> 00:06:24,780
+وكل العناصر سبق أنه درس يعني بشكل عام التوزيع
+
+71
+00:06:24,780 --> 00:06:28,360
+الإلكتروني في مساخات الكيميا العامة لكن هذه عملية
+
+72
+00:06:28,360 --> 00:06:33,200
+التذكير لاحظوا هنا لو بدنا نتطلع على الإرتباطات
+
+73
+00:06:33,200 --> 00:06:38,320
+اللي بتعملها العناصر الـ hydrogen بيكون عامل أو
+
+74
+00:06:38,320 --> 00:06:42,140
+بيكون موجود في one electron وبناء على ذلك الـ
+
+75
+00:06:42,140 --> 00:06:46,770
+hydrogenمستعد إنه يعمل رابط كمان عشان يجيب
+
+76
+00:06:46,770 --> 00:06:51,850
+الإلكترون التاني الهيليام بتو إلكترون one as two
+
+77
+00:06:51,850 --> 00:06:58,210
+مسكر فبشكل عام ما بيعملش bonding لو إجينا الليثيام
+
+78
+00:06:58,210 --> 00:07:01,950
+ب one إلكترون بده يعمل one bond البريليام ب two
+
+79
+00:07:01,950 --> 00:07:06,090
+إلكترون بده يعمل two bonds البرون ب three إلكترون
+
+80
+00:07:06,090 --> 00:07:11,230
+بده يعمل three bonds الكربون ب four إلكترون بده
+
+81
+00:07:11,230 --> 00:07:15,580
+يعملFour bonds وهذا سنركز عليه مرة تانية الـ
+
+82
+00:07:15,580 --> 00:07:19,760
+Carbon في حالة الـ Nitrogen صح عندي خمس إلكترونات
+
+83
+00:07:19,760 --> 00:07:23,580
+لكن اتنين منهم بيكونوا في الـ S بيكونوا عاملين الـ
+
+84
+00:07:23,580 --> 00:07:26,840
+Bearing فبيظل ان الـ Nitrogen فيه تلت إلكترونات
+
+85
+00:07:26,840 --> 00:07:31,600
+مفردة بيعمل تلت روابط والأكسجين فيه إلكترونين
+
+86
+00:07:31,600 --> 00:07:36,400
+مفردين بيعمل رابطتين والفلورين بيعمل رابط واحدة
+
+87
+00:07:36,670 --> 00:07:40,610
+إذاً بدنا نكون إحنا منتبهين لهدول العناصر الأربعة
+
+88
+00:07:40,610 --> 00:07:43,030
+اللي أنا وماما بشكل عام بيمروا معنى في الـ Organ
+
+89
+00:07:43,030 --> 00:07:46,230
+الchemistry يعني الـ Lithium و البريليوم و البرون
+
+90
+00:07:46,230 --> 00:07:49,470
+عادة بيمروش معنى في الـ Organ الchemistry إلا ما
+
+91
+00:07:49,470 --> 00:07:53,550
+ندر لكن اللي بيمروا بشكل كبير الـ Carbon، الـ
+
+92
+00:07:53,550 --> 00:07:56,750
+Nitrogen، الـ Oxygen، الـ Fluor لما بنيجي بنعمل
+
+93
+00:07:56,750 --> 00:08:02,010
+روابط دائما الـ Carbon بيكون عامل أربعة bonds الـ
+
+94
+00:08:02,010 --> 00:08:06,470
+Nitrogen بيكون عامل تلاتة bondsوفيه زوج واحد من
+
+95
+00:08:06,470 --> 00:08:11,170
+الإلكترونات الـ Oxygen بيكون عامل تنتين bonds وفيه
+
+96
+00:08:11,170 --> 00:08:15,430
+زوجين من الإلكترونات و ال halogens لفلور و لكلور
+
+97
+00:08:15,430 --> 00:08:20,790
+بيكونوا عاملين رابطة واحدة و فيهم تلت أزواج من
+
+98
+00:08:20,790 --> 00:08:28,570
+الإلكترونات الآن هذه فكرة عن التوزيع الإلكتروني لو
+
+99
+00:08:28,570 --> 00:08:34,170
+إجينا نقول كيف بتتكون الروابط الروابط إما أن تكون
+
+100
+00:08:35,240 --> 00:08:41,920
+زي ما اتعلمتوا في الكيميا العامة Ionic bonds و
+
+101
+00:08:41,920 --> 00:08:45,940
+بتقدي إلى Ionic compounds أو Covalent bonds و
+
+102
+00:08:45,940 --> 00:08:50,340
+بتقدي إلى ال molecular compounds بشكل عام ال Ionic
+
+103
+00:08:50,340 --> 00:08:56,060
+bonds بتكون ما بين ذرات
+
+104
+00:08:56,830 --> 00:09:02,650
+من المجموعات الأولى المعدنية الـ Metals مع ذرات من
+
+105
+00:09:02,650 --> 00:09:06,470
+الـ Non-metals مثلا لو أخدنا الصوديوم الصوديوم فيه
+
+106
+00:09:06,470 --> 00:09:11,890
+one electron بده كمان electron والكلور بشكل عام
+
+107
+00:09:11,890 --> 00:09:16,090
+برضه فيه one electron في هذه الحالة يمكن أن
+
+108
+00:09:16,090 --> 00:09:19,970
+الصوديوم هذا يفقد ال electron عشان يرجع إلى تركيب
+
+109
+00:09:19,970 --> 00:09:25,870
+ثمانيهذا الـ Sodium بيفقد الإلكترون ويرجع إلى
+
+110
+00:09:25,870 --> 00:09:30,670
+تركيب ثماني فبصير Na Plus الكلور بيكتسب الإلكترون
+
+111
+00:09:30,670 --> 00:09:36,890
+بيصير Cl- Na Plus مع Cl- بيعطينا المركب نتيجة
+
+112
+00:09:36,890 --> 00:09:40,110
+تجاذب الأيونات اللي هو Sodium Chloride أو ملح
+
+113
+00:09:40,110 --> 00:09:44,660
+الطعامالان ممكن نتطلع على مُركّب زي الـ Magnesium
+
+114
+00:09:44,660 --> 00:09:48,220
+Fluoride، المغنيسيام عنده إلكترونين إزيادة،
+
+115
+00:09:48,220 --> 00:09:52,060
+بيفقدهم عشان يرجع إلى تركيب ثماني، الفلور بده
+
+116
+00:09:52,060 --> 00:09:56,120
+إلكترون، بناءً على ذلك، المغنيسيام بيكون بده
+
+117
+00:09:56,120 --> 00:09:59,700
+يتفاعل مع ذرتين فلور، بيفقد إلكترون لذرة، بيفقد
+
+118
+00:09:59,700 --> 00:10:04,670
+الإلكترون التانيلذرة تانية بيصير Mg2 plus مع
+
+119
+00:10:04,670 --> 00:10:08,610
+أيونين floor minus بيتجاذب كلهم مع بعض بيصير عند
+
+120
+00:10:08,610 --> 00:10:15,310
+المركب اللي ماخد ال .. بشكل عام الصيغة الجزائية
+
+121
+00:10:15,310 --> 00:10:24,310
+اللي هي MgF2 ionic compound في حالة الـ covalent
+
+122
+00:10:24,310 --> 00:10:30,410
+compounds بنلاحظ أنه عملية الفقد هي عملية صعبة
+
+123
+00:10:31,510 --> 00:10:36,510
+وبناء على ذلك تتم أو يتم تكوين الـ Covalent bonds
+
+124
+00:10:36,510 --> 00:10:41,130
+من خلال المشاركة مش من خلال الفقد مثلا لو بدنا
+
+125
+00:10:41,130 --> 00:10:45,550
+نطلع على جزء الهيدروجين الهيدروجين فيه واحد
+
+126
+00:10:45,550 --> 00:10:49,290
+إلكترون وهيدروجين تاني واحد إلكترون بيشتركوا بدول
+
+127
+00:10:49,290 --> 00:10:52,970
+الإلكترونين بيعملوا Covalent bond بيصير عند
+
+128
+00:10:52,970 --> 00:10:58,910
+الهيدروجين moleculeكذلك الحال لو بدنا نتطلع مثلا
+
+129
+00:10:58,910 --> 00:11:03,870
+على الكلور الكلور في one electron لكن هذا الكلور
+
+130
+00:11:03,870 --> 00:11:08,710
+صعب أنه يفقد هذا ال electron مثلا لو بدنا نتخيل أن
+
+131
+00:11:08,710 --> 00:11:11,570
+واحدة من الكلور بدها تفقد ال electron للذرّة
+
+132
+00:11:11,570 --> 00:11:14,870
+التانية المشكلة هيصير فيها 6 electron هي عندها
+
+133
+00:11:14,870 --> 00:11:20,270
+سبعة بتستنى تصير تمانية مش بتستنى ترجع للستة بناء
+
+134
+00:11:20,270 --> 00:11:24,820
+على ذلك ذرتين الكلور هنابشتركوا بالإلكترونات
+
+135
+00:11:24,820 --> 00:11:28,020
+بيعملوا اللي هي الرابطة التساومية أو التشاركية
+
+136
+00:11:28,020 --> 00:11:35,580
+اللي هي عبارة عن جزء الـ CL2 بيكون عنده CL و رابطة
+
+137
+00:11:35,580 --> 00:11:40,820
+أحدية من إلكترونين و CL و كل ذرة CL بيكون عليها
+
+138
+00:11:40,820 --> 00:11:45,760
+تلت أزواج من الإلكترونات يعني ست إلكترونات زاد
+
+139
+00:11:45,760 --> 00:11:49,400
+إلكترونية الرابطة هنا بيقدر نتخيلإن عندنا 8
+
+140
+00:11:49,400 --> 00:11:53,540
+إلكترون حوالين هذه و 8 إلكترون حوالين الذرة
+
+141
+00:11:53,540 --> 00:11:57,840
+التانية طبعا سبق إن اتعلمنا إن الذرة إلها طاقة و
+
+142
+00:11:57,840 --> 00:12:03,520
+إلها طول و كل هذا الكلام دوريس أهم الأشياء اللي
+
+143
+00:12:03,520 --> 00:12:07,020
+ربما بيلزم أن نكون منتبهين إلها إحنا في ال organ
+
+144
+00:12:07,020 --> 00:12:10,560
+ال chemistry اللي هي عدد الروابط اللي بتعملها
+
+145
+00:12:10,560 --> 00:12:16,860
+العناصرالهيدروجين يعمل روابط واحدة تشاركية،
+
+146
+00:12:16,860 --> 00:12:22,600
+الكربون يعمل أربع روابط تشاركية، النيتروجين يعمل
+
+147
+00:12:22,600 --> 00:12:24,740
+تلاتة روابط تشاركية، الأكسجين يعمل تنتين روابط
+
+148
+00:12:24,740 --> 00:12:28,080
+تشاركية، الفلورين والهالوجين، زيكلورين، برومين،
+
+149
+00:12:28,080 --> 00:12:31,560
+أيودين، كلهم يعملوا رابط واحدة تشاركية، لاحظون
+
+150
+00:12:31,560 --> 00:12:37,250
+احنا رسميا جزء كبير كتيرلكن هذا الجزء إذا بدنا
+
+151
+00:12:37,250 --> 00:12:41,530
+نتطلع هل تتحقق في أعداد الروابط اللي بتعملها كل
+
+152
+00:12:41,530 --> 00:12:45,830
+ذرع الجواب آه مثلا هذه الهيدروجين عاملة رابطة هنا
+
+153
+00:12:45,830 --> 00:12:50,150
+هنا هنا في كل المواقع عاملة كام رابطة؟ رابطة واحدة
+
+154
+00:12:50,150 --> 00:12:53,590
+لو بدنا نتطلع على الكاربون اللي هنا عاملة رابطة مع
+
+155
+00:12:53,590 --> 00:12:57,570
+الكاربون التاني اتنين تلاتة اربعةالان لو اجينا
+
+156
+00:12:57,570 --> 00:13:00,970
+تطلعنا على الـ Carbon اللي موجودة هنا، هذه الـ
+
+157
+00:13:00,970 --> 00:13:05,670
+Carbon برضه عاملة أربع روابط، لكن مرات كتيرة لما
+
+158
+00:13:05,670 --> 00:13:11,070
+يكون عندى Hydrogen باختصر كتابتهم، يعني حقيقة هذه
+
+159
+00:13:11,070 --> 00:13:17,060
+الـهذا الكربون اللي في الوسط وهذا الكربون اللي في
+
+160
+00:13:17,060 --> 00:13:21,320
+الوسط هي عبارة عن CH2 يعني هي عاملة رابطتين مع
+
+161
+00:13:21,320 --> 00:13:26,940
+الكربون لكن بنفس الوقت هي برضه عاملة رابطتين مع
+
+162
+00:13:26,940 --> 00:13:31,940
+الهيدروجين لكن مختصرات في الرسم لكن المفروض أي
+
+163
+00:13:31,940 --> 00:13:36,840
+طالب organic يعرف إن هنا في عنده ذرتين هيدروجين
+
+164
+00:13:36,840 --> 00:13:41,850
+وإحنا متعودين نختصرهمكذلك الحال مثلا هذه الكربون
+
+165
+00:13:41,850 --> 00:13:46,610
+ممكن البعض يظن انها عاملة هذه الكربون البعض يظن
+
+166
+00:13:46,610 --> 00:13:51,490
+انها عاملة تلت روابط الحقيقة لأ هذه الكربون بتعمل
+
+167
+00:13:51,490 --> 00:13:56,670
+اربع روابط بس في هيدروجين هنا احنا بنختصرها زي ما
+
+168
+00:13:56,670 --> 00:14:00,410
+قلنا ان هذه الكربون بتعمل برضه اربع روابط
+
+169
+00:14:00,410 --> 00:14:04,710
+الهيدروجين اختصرناهم احنا ممكن هذه مرات تشوفوها
+
+170
+00:14:04,710 --> 00:14:08,660
+مختصرة وممكن هذه تشوفوها مختصرةالخلاصة ان اي
+
+171
+00:14:08,660 --> 00:14:14,780
+carbon عليها عدد من الروابط اقل من الاربعة بتكونوا
+
+172
+00:14:14,780 --> 00:14:20,820
+فاهمين تلقائيا ان باقي الروابط موجودة ولكن اختصرت
+
+173
+00:14:20,820 --> 00:14:25,490
+من ناحية الكتابةالان ال oxygen هنا بيعمل رابطتين
+
+174
+00:14:25,490 --> 00:14:30,890
+سواء كانوا على شكل double bond او او single bond
+
+175
+00:14:30,890 --> 00:14:33,610
+single bond يعني هذا ال oxygen عاملة double bond
+
+176
+00:14:33,610 --> 00:14:37,150
+مع الكربون مهم عاملة رابطتين هذا ال oxygen عاملة
+
+177
+00:14:37,150 --> 00:14:40,070
+single bond مع هذا الكربون و single bond مع هذا
+
+178
+00:14:40,070 --> 00:14:43,630
+الكربون ممكن بعض يتطلع على هذا الكربون كام رابطة
+
+179
+00:14:43,630 --> 00:14:48,870
+عاملةطبعا بالتأكيد أربعة المبينين تلاتة رابطة مع
+
+180
+00:14:48,870 --> 00:14:51,350
+الـ Oxygen و رابطة مع الـ Carbon و رابطة مع الـ
+
+181
+00:14:51,350 --> 00:14:55,750
+Carbon الرابعة موجودة ولكنها مختصرة هي رابطة
+
+182
+00:14:55,750 --> 00:15:01,700
+Carbon-Hydrogenهاي كلور هنا عامل بس رابطة واحدة،
+
+183
+00:15:01,700 --> 00:15:05,660
+هاي نيتروجين هنا كام رابطة بيعمل تلاتة، لاحظوا هذا
+
+184
+00:15:05,660 --> 00:15:10,180
+النيتروجين عامل تلت روابط، الكاربون اللي هنا واحد،
+
+185
+00:15:10,180 --> 00:15:13,520
+اتنين، تلاتة، اربع، بيعمل اربع روابط، فدائما
+
+186
+00:15:13,520 --> 00:15:17,780
+الـvalences of the common elements in organic
+
+187
+00:15:17,780 --> 00:15:22,580
+chemistry لازم نكون منتبهين لهم، بنركز عليهم كتير،
+
+188
+00:15:22,580 --> 00:15:27,090
+لما بنرسم الأشكالالهيدروجين بيعمل رابطة الكاربون
+
+189
+00:15:27,090 --> 00:15:30,490
+أربعة نيتروجين تلاتة الأكسجين رابطتين والهالوجين
+
+190
+00:15:30,490 --> 00:15:35,810
+رابطة واحدة
+
+191
+00:15:35,810 --> 00:15:41,570
+الآن
+
+192
+00:15:43,550 --> 00:15:47,630
+بنجي لموضوع تذكير جديد، احنا قلنا كل هذه مقدمة
+
+193
+00:15:47,630 --> 00:15:52,670
+المفروض انه سبق انها درست لكن احنا بنذكر فيها اللي
+
+194
+00:15:52,670 --> 00:15:57,450
+هي الـ polarity of bonds بشكل عام الـ polarity of
+
+195
+00:15:57,450 --> 00:16:01,810
+bonds ان الرابط يكون لها طرف موجة بطرف سالب، هاي
+
+196
+00:16:01,810 --> 00:16:06,210
+معناه الـ polarity ببساطة وهذه بتعتمد على الفرق
+
+197
+00:16:06,210 --> 00:16:10,200
+السالبية الـ polarity of bondsDepends on the
+
+198
+00:16:10,200 --> 00:16:13,700
+electronegativity difference الآن في السالبية لما
+
+199
+00:16:13,700 --> 00:16:20,380
+درسناها أخدنا قيم للعناصر في السالبية بموجودة
+
+200
+00:16:20,380 --> 00:16:24,820
+ملخصة في هذا الجدول وكنا بنتذكر أن أعلى عنصر في
+
+201
+00:16:24,820 --> 00:16:29,700
+السالبية كان لفلوري بسالبية تقريبا أربعةوبعد ذلك
+
+202
+00:16:29,700 --> 00:16:32,640
+من العناصر العالية في السالبية الأكسجين
+
+203
+00:16:32,640 --> 00:16:37,380
+والنيتروجين والكلور والعناصر التانية السالبية
+
+204
+00:16:37,380 --> 00:16:43,700
+قليلة تبعتها الان عندما يحدث رابط ما بين عنصرين
+
+205
+00:16:43,700 --> 00:16:49,190
+مثلا لو افترضنا الفلور مع الكاربون عامل رابطةأى
+
+206
+00:16:49,190 --> 00:16:54,050
+طرف بدى يكون نسبيا سالب جزئيا سالب أو أى طرف بدى
+
+207
+00:16:54,050 --> 00:16:58,710
+يكون جزئيا موجب طبعا الفلور أعلى سالبية من الكربون
+
+208
+00:16:58,710 --> 00:17:03,110
+فبناء على ذلك رابطة الفلور والكربون الفلور هيكون
+
+209
+00:17:03,110 --> 00:17:06,650
+partially negative والكربون هيكون partially
+
+210
+00:17:06,650 --> 00:17:11,590
+positive واضح؟ و هكذا لو قولنا مثلا الchlor مع
+
+211
+00:17:11,590 --> 00:17:15,770
+الكربونالكلور يكون بارشالي نيجاتيف والكربون
+
+212
+00:17:15,770 --> 00:17:20,730
+بارشالي بوزيتيف لأن فرق السالبيةلصالح الكلور
+
+213
+00:17:20,730 --> 00:17:24,290
+الكلور أعلى سلبية من الكربون فلما نيجي نقول أنه في
+
+214
+00:17:24,290 --> 00:17:28,770
+عندنا رابطة carbon chlorine bond هل هذه الرابطة
+
+215
+00:17:28,770 --> 00:17:33,370
+polar الجواب أه بتكون الرابطة مش polar لما يكون
+
+216
+00:17:33,370 --> 00:17:37,370
+السلبية متساوية يعني مثلا لو الكلور عمل مع الكلور
+
+217
+00:17:37,370 --> 00:17:42,090
+بشكل عام بنقول الرابطة non polar لكن الكلور مع
+
+218
+00:17:42,090 --> 00:17:46,810
+الكربونالكلور الـ electronegativity تبعته 3.2
+
+219
+00:17:46,810 --> 00:17:51,490
+والكربون 2.5 فيه فرق سالبية لصالح الكلور إذا في
+
+220
+00:17:51,490 --> 00:17:54,210
+هذه الحالة الكلور بيكون partially negative
+
+221
+00:17:54,210 --> 00:18:01,510
+والكربون partially positiveهذه في عندي أمثلة مثلا
+
+222
+00:18:01,510 --> 00:18:07,410
+الـ H مع الـ CL واضح أن الـ polarity أعلى أو
+
+223
+00:18:07,410 --> 00:18:12,610
+السالبية أكتر عند الـ CL فبنعبر احنا بعدة طرق يعني
+
+224
+00:18:12,610 --> 00:18:17,230
+ممكن نعملسهم ويله طرف كأنه موجب يعني كأنه هذا
+
+225
+00:18:17,230 --> 00:18:20,450
+الطرف الموجب و هذا الطرف السالب او ممكن نكتب
+
+226
+00:18:20,450 --> 00:18:24,230
+partially negative charge و partially positive
+
+227
+00:18:24,230 --> 00:18:28,270
+charge فالخلاص ان هذا الكلام او هذا الكلام بيدلنا
+
+228
+00:18:28,270 --> 00:18:33,250
+على ان ال chlorine هو اللي بيمثل الطرف السالب و ال
+
+229
+00:18:33,250 --> 00:18:36,710
+hydrogen هو اللي بيمثل الطرف الموجب الان عندنا
+
+230
+00:18:36,710 --> 00:18:39,570
+روابط اخرى مثلا ال carbon و ال nitrogen او ال
+
+231
+00:18:39,570 --> 00:18:42,950
+carbon و ال oxygen ال nitrogen و ال oxygen بمثل
+
+232
+00:18:43,700 --> 00:18:47,960
+الطرف السالب الكاربون الطرف الموجب الكاربون مع
+
+233
+00:18:47,960 --> 00:18:51,060
+الكلور و البروم الكلور و البروم طرف سالب و
+
+234
+00:18:51,060 --> 00:18:54,640
+الكاربون طرف موجب الهيدروجين مع الأكسجن و السلفر
+
+235
+00:18:54,640 --> 00:18:58,220
+الأكسجن و السلفر طرف سالب الهيدروجين طرف موجب
+
+236
+00:18:58,220 --> 00:19:02,800
+البروم مع الكلور الكلور سالبيته أعلى بيكون الكلور
+
+237
+00:19:02,800 --> 00:19:09,740
+نسبيا سالب البروم موجب السيليكون مع الكاربونتقريبا
+
+238
+00:19:09,740 --> 00:19:13,880
+إذا بنرجع للجدول لاحظوا أن الكربون أعلى من
+
+239
+00:19:13,880 --> 00:19:17,480
+السيليكون الكربون اتنين و نص السيليكون واحد وتسعة
+
+240
+00:19:17,480 --> 00:19:21,860
+عشر بناء على ذلك الكربون بدي يكون نسبيا هو السالب
+
+241
+00:19:21,860 --> 00:19:29,640
+والسيليكون هو الموجب الآن الكلام اللي حكيناه هو
+
+242
+00:19:29,640 --> 00:19:34,160
+حقيقة بيعبر عن ال polarity of bonds لكن هذه
+
+243
+00:19:34,160 --> 00:19:41,320
+الروابط لو إجت في جزئالجزيق يحتوي على عدة روابط هل
+
+244
+00:19:41,320 --> 00:19:46,700
+الجزيق بمجمله يكون قطبي ولا غير قطبي قطبية الجزيق
+
+245
+00:19:46,700 --> 00:19:52,180
+بتعتمد على شكله الهندسي معنى كلمة الشكل الهندسي
+
+246
+00:19:52,180 --> 00:19:57,240
+اللي هو مجموع الـ polarity of bonds مثلا لو
+
+247
+00:19:57,240 --> 00:20:01,160
+افترضنا فيه جزيق linear وهذه رابطة قطبية وهذه
+
+248
+00:20:01,160 --> 00:20:07,810
+قطبية لكن التنتين عكس بعض بشطب بعضفهذا الجزء بيكون
+
+249
+00:20:07,810 --> 00:20:13,210
+non-polar الـ linear molecule non-polar لو كان
+
+250
+00:20:13,210 --> 00:20:19,710
+عندي جزء triangular planner رابطة، اتنين، تلاتة
+
+251
+00:20:19,710 --> 00:20:24,110
+وكل رابطة فيهم قطبية هل الجزء بمجمله قطبي ولا غير
+
+252
+00:20:24,110 --> 00:20:31,410
+قطبي الحقيقة أن الجزء بمجمله بيكون غير قطبي لأن
+
+253
+00:20:31,410 --> 00:20:35,720
+محصلة هدولة تشتب مع محصلة هذهفهذا الجزء بيكون
+
+254
+00:20:35,720 --> 00:20:40,280
+عندنا هنا non-polar بينما لو كان في عندي جزء مكون
+
+255
+00:20:40,280 --> 00:20:44,950
+بس من رابطتين bent بيكون الجزء polarهنا
+
+256
+00:20:44,950 --> 00:20:50,490
+التتراهيدرال التتراهيدرال رجاءً يعني الكل ينتبه
+
+257
+00:20:50,490 --> 00:20:57,550
+لأنه هنا للأسف مكتوبة خطأ التتراهيدرال بيكون non
+
+258
+00:20:57,550 --> 00:21:01,010
+-polar molecule لأن محاصلة القطبية لهدولة
+
+259
+00:21:01,010 --> 00:21:05,530
+الرابطتين عكس المحاصلة للرابطتين التانيات فهذا
+
+260
+00:21:05,530 --> 00:21:09,550
+التتراهيدرال structure حقيقة زي الميثين
+
+261
+00:21:09,550 --> 00:21:11,210
+والتتراكلوروكاربون
+
+262
+00:21:12,810 --> 00:21:18,610
+non-polar molecule ضروري ننتبه لها هذا الشكل non
+
+263
+00:21:18,610 --> 00:21:23,890
+-polar molecule وبشكل عام بإمكاننا نتطلع على هذا
+
+264
+00:21:23,890 --> 00:21:28,570
+الجدول و نتذكر و ننتبه أن نحسب صح ال polarity of
+
+265
+00:21:28,570 --> 00:21:32,010
+molecules الخلاصة أن ال polarity of molecules
+
+266
+00:21:32,010 --> 00:21:38,790
+بتعتمد على محصلة القطبية للروابط المنفردة ال
+
+267
+00:21:38,790 --> 00:21:43,530
+polarity of molecules بتعتمد علىمحصلة قطبية
+
+268
+00:21:43,530 --> 00:21:48,150
+للروابط المنفردة هذا الكلام ضروري أن ننتبهله إذا
+
+269
+00:21:48,150 --> 00:21:52,690
+مرة تانية بأكد أن الـ polarity of bonds بتعتمد على
+
+270
+00:21:52,690 --> 00:21:56,390
+فرق السالبية لكن ال polarity of molecule بتعتمد
+
+271
+00:21:56,390 --> 00:22:03,650
+على ال geometry أو محصلة الروابط الآن
+
+272
+00:22:03,650 --> 00:22:09,500
+الجزيئات العضوية فيها ظاهرة مشهورةاللي هي ظاهرة
+
+273
+00:22:09,500 --> 00:22:13,520
+المتشكلات أو ال isomers هذه الظاهرة احنا هندل
+
+274
+00:22:13,520 --> 00:22:19,440
+نتدرج معاها أثناء دراستنا لكن بشكل عام مش هنشرح كل
+
+275
+00:22:19,440 --> 00:22:24,220
+هذا ال scheme لان لأن هذا بيجي بوقته لكن لما نقول
+
+276
+00:22:24,220 --> 00:22:30,280
+ايش هم ال isomers ال isomers هم مركباتالهم نفس الـ
+
+277
+00:22:30,280 --> 00:22:33,600
+molecular formula لكن بيختلفوا في الشكل البناء
+
+278
+00:22:33,600 --> 00:22:38,620
+they have different structures واضح؟ فبيكون ال
+
+279
+00:22:38,620 --> 00:22:41,380
+isomers different compounds that have the same
+
+280
+00:22:41,380 --> 00:22:44,440
+molecular formula but they have different
+
+281
+00:22:44,440 --> 00:22:48,140
+structures طبعا هنتعلم أنه بتقسم إلى
+
+282
+00:22:48,140 --> 00:22:51,900
+constitutional isomers و stereo isomers و هذا
+
+283
+00:22:51,900 --> 00:22:56,880
+الكلام بيدرس بالتفصيل بحينه لكن الآن احنا اللي
+
+284
+00:22:56,880 --> 00:23:01,930
+بنقوله ببساطةإنه لما بنيجي بنحكي عن الـ isomers،
+
+285
+00:23:01,930 --> 00:23:06,750
+الـ isomers هم مركبات امكونين من نفس العناصر لكن
+
+286
+00:23:06,750 --> 00:23:11,550
+امركبين بطرق مختلفة، انا يعني ممكن اعطي مثال، يعني
+
+287
+00:23:11,550 --> 00:23:15,310
+لو افترضت مثلا إنه عنده مركب امكون من هذه التلات
+
+288
+00:23:15,310 --> 00:23:19,430
+عناصر،و أتخيل هذه الأقلام التلاتة أحمر و أزرق و
+
+289
+00:23:19,430 --> 00:23:24,090
+أسود الآن هدولة بهذا الشكل عاملين مُركّب و هذا
+
+290
+00:23:24,090 --> 00:23:28,910
+المُركّب ترتيبه أحمر أزرق أسود أنا ممكن أعمل تغيير
+
+291
+00:23:28,910 --> 00:23:33,630
+بهذا الشكل صار عندي أسود أحمر أزرق أكيد أن الشكل
+
+292
+00:23:33,630 --> 00:23:38,070
+الأول و الشكل التاني مش نفس الاشيء فبنقول أنه أنا
+
+293
+00:23:38,070 --> 00:23:41,790
+انا امكون من نفس العناصر عندى نفس الصيغة الجزائية
+
+294
+00:23:41,790 --> 00:23:48,150
+لكن بنائياأحمر أسود أحمر أزرق غير عن أحمر أزرق
+
+295
+00:23:48,150 --> 00:23:52,990
+أسود فبصير عنده شكلين مختلفين على أي حال موضوع الـ
+
+296
+00:23:52,990 --> 00:23:57,490
+isomers زي ما قولته أنواعها موضوع بنضلنا نستمر في
+
+297
+00:23:57,490 --> 00:24:03,380
+التدرج فيه وبفهمه خطوة خطوةفيه منه نوعين أساسيًا
+
+298
+00:24:03,380 --> 00:24:07,300
+Constitutional Isomers بندرسهم في الفصول اتنين
+
+299
+00:24:07,300 --> 00:24:13,340
+وتلاتة تقريبًا وأربعة وفي عند استيريو Isomers
+
+300
+00:24:13,340 --> 00:24:17,940
+بنفرض لها فصل كامل أثناء دراستنا اللي هو الفصل
+
+301
+00:24:17,940 --> 00:24:18,980
+الخامس
+
+302
+00:24:24,320 --> 00:24:29,700
+الان بشكل عام كيف يرسم الجزء العضوى الجزء العضوى
+
+303
+00:24:29,700 --> 00:24:34,860
+ممكن نرسمه من خلال ان نكتب عدد الذرات كاملا يعني
+
+304
+00:24:34,860 --> 00:24:41,060
+مثلا اقول CH3 CH2 CH2 OH هذه رسمة و ممكن نختصره
+
+305
+00:24:41,060 --> 00:24:46,300
+بهذا الشكل فقط نحط خطوط الان ايش معنى هذه النقطة
+
+306
+00:24:46,300 --> 00:24:49,680
+معنى هذه النقطة ان هذه carbon طب يا ال carbon كام
+
+307
+00:24:49,680 --> 00:24:56,830
+رابطة بتعمل اربعة اذا هذهالنقطة عبارة عن CH3 طب
+
+308
+00:24:56,830 --> 00:25:00,230
+هذه النقطة التانية عاملة رابطتين إذن هي عبارة عن
+
+309
+00:25:00,230 --> 00:25:03,350
+CH2 يعني كأن أنا أنا مختصر أتشين هاي معناه
+
+310
+00:25:03,350 --> 00:25:07,490
+abbreviated يعني أنه شكل مختصر هذه النقطة برضه
+
+311
+00:25:07,490 --> 00:25:11,390
+معناها CH2 لإنه رابطتين إذن أكيد في two hydrogens
+
+312
+00:25:11,390 --> 00:25:15,340
+ممكن أدول أو يكونوا مضحو يعني أنا حاطيتهم هناالان
+
+313
+00:25:15,340 --> 00:25:18,660
+في الـ Organic Chemistry احنا احب الأشكال اللي لنا
+
+314
+00:25:18,660 --> 00:25:22,420
+اللي هو هذا الشكل الوسطاني الشكل المختصر وبنصير
+
+315
+00:25:22,420 --> 00:25:27,080
+متعودين نعرف انه كل رأس عندنا يمثل Carbon ودائما
+
+316
+00:25:27,080 --> 00:25:31,500
+وابدا منكمل ال Hydrogen بحيث يكون عدد الذرات على
+
+317
+00:25:31,500 --> 00:25:37,250
+Carbon أربعة مثلا لو بدعم المركبcyclopentane يعني
+
+318
+00:25:37,250 --> 00:25:42,190
+في حلقاء من خمس درات carbon لو بتحطه بالشكل غير
+
+319
+00:25:42,190 --> 00:25:47,510
+المختصر بتقول CH2 CH2 CH2 CH2 CH2 وصيغته العامة
+
+320
+00:25:47,510 --> 00:25:52,590
+C5H10 لكن أنا لما بتعمله بالشكل المختصر بحطه بهذا
+
+321
+00:25:52,590 --> 00:25:57,830
+الشكل الآن كل رأس يمثل carbon فلو سألتهذا الشكل
+
+322
+00:25:57,830 --> 00:26:02,330
+كام carbon في واحد تانين تلاتة أربعة خمسة إذا نادى
+
+323
+00:26:02,330 --> 00:26:06,510
+خمسة carbons طب وين ال hydrogens كل carbon بزام
+
+324
+00:26:06,510 --> 00:26:09,990
+عاملة رابطتين إذا بنكمل عليها هيدروجينتين فكأنه
+
+325
+00:26:09,990 --> 00:26:13,830
+هذه CH2 حاملة هيدروجنتين وهذه CH2 حاملة هيدروجنتين
+
+326
+00:26:13,830 --> 00:26:17,510
+وهذه CH2 حاملة هيدروجنتين وهكذا فبتصير الصيغة
+
+327
+00:26:17,510 --> 00:26:24,060
+العامة C5H10زي ما قلت أكثر شكل إحنا هنستعمله في
+
+328
+00:26:24,060 --> 00:26:28,360
+أثناء دراستنا اللي هو الشكل المختصر اللي بنحط رؤوس
+
+329
+00:26:28,360 --> 00:26:33,240
+هذه الرؤوس تمثل الـCarbons هذه الرؤوس تمثل
+
+330
+00:26:33,240 --> 00:26:36,860
+الـCarbons ودائما بنفترض أن أي شيء غير موجود هو
+
+331
+00:26:36,860 --> 00:26:42,160
+عبارة عن Hydrogen آخر
+
+332
+00:26:42,160 --> 00:26:50,090
+شغلة في المحاضرة التقديمية المختصرة اليوم أنهأخدنا
+
+333
+00:26:50,090 --> 00:26:54,230
+شيء اسمه Formal Charges أو الشحنات الظاهرية اللى
+
+334
+00:26:54,230 --> 00:26:57,830
+موجودة على العناصر لما احنا بنعمل organic
+
+335
+00:26:57,830 --> 00:27:01,570
+structure كل ذرة بيكون عليها شحنة هذه الشحنة
+
+336
+00:27:01,570 --> 00:27:05,570
+بنسميها Formal Charge ال Formal Charge بشكل عام
+
+337
+00:27:05,570 --> 00:27:09,070
+بتساوي ال Valence Electrons عدد الإلكترونات
+
+338
+00:27:09,070 --> 00:27:14,050
+الخارجية للعنصر طبعا البعض اللى مابيعرفشماذا يعني
+
+339
+00:27:14,050 --> 00:27:17,730
+Valence Electrons؟ نحن نقول Valence Electrons هو
+
+340
+00:27:17,730 --> 00:27:23,790
+رقم المجموعة Valence Electrons هو رقم المجموعة
+
+341
+00:27:23,790 --> 00:27:28,090
+يعني لو رجعنا للجدول اللي مارمعناه قبل شوية ولو
+
+342
+00:27:28,090 --> 00:27:32,510
+كان جدول للسالبية لاحظوا ان Valence Electrons في
+
+343
+00:27:32,510 --> 00:27:36,550
+المجموعة الأولى زي الهيدروجين واحد البريليام اتنين
+
+344
+00:27:36,550 --> 00:27:40,220
+البرون تلاتةلو بد الـ valence electrons للكربون
+
+345
+00:27:40,220 --> 00:27:45,000
+أربعة رقم المجموعة للنيتروجين خمسة رقم المجموعة
+
+346
+00:27:45,000 --> 00:27:50,080
+للأكسجين والسلفر ستة للهالوجين فلوري كلوري بروم
+
+347
+00:27:50,080 --> 00:27:55,540
+يود سبعة فالـ valence electrons هي رقم المجموعة
+
+348
+00:27:55,540 --> 00:28:01,000
+بنطرح منها عدد الروابط اللي متصلة بهذه النقطة
+
+349
+00:28:01,000 --> 00:28:04,680
+المحددة أو الذرع المحددة زاد عدد الإلكترونات اللي
+
+350
+00:28:04,680 --> 00:28:09,490
+محمولين على الذرعكمثال مثلًا هنا في عندنا
+
+351
+00:28:09,490 --> 00:28:14,650
+الكربونات انايون هذه الكربون عاملة رابطة 2 3 4 لو
+
+352
+00:28:14,650 --> 00:28:18,010
+قلت ايش ال formal charge عليها الكربون في المجموعة
+
+353
+00:28:18,010 --> 00:28:23,250
+الرابعة فبقول أربعة ناقص كام رابطة 1 2 3 4 ناقص
+
+354
+00:28:23,250 --> 00:28:27,370
+أربعة ناقص كام إلكترون إذا أنا هنا بتطلع مافيش على
+
+355
+00:28:27,370 --> 00:28:30,750
+الكربون إلكترونات حسب اللي هو ال structure فبتكون
+
+356
+00:28:30,750 --> 00:28:37,510
+هذه الكربون أربعة ناقص أربعة ناقص سفر بتصفى سفرلو
+
+357
+00:28:37,510 --> 00:28:40,290
+بدي اجي أطلع على الـ Oxygen اللي هنا، الـ Oxygen
+
+358
+00:28:40,290 --> 00:28:44,410
+في المجموعة السادسة، فالـ Formal Charge تبعتها 6
+
+359
+00:28:44,410 --> 00:28:50,350
+ناقص كام رابطة؟ 2، ناقص كام إلكترون؟ 1، 2، 3، 4،
+
+360
+00:28:50,350 --> 00:28:56,260
+6، ناقص 2، ناقص 4، بتكون 0هنا الـ Oxygen هذه اللي
+
+361
+00:28:56,260 --> 00:29:01,440
+مرسومة بشكل آخر هنقول برضه ستة ناقص كام رابطة واحد
+
+362
+00:29:01,440 --> 00:29:06,000
+ناقص كام إلكترون ستة ستة ناقص رابطة ناقص ست
+
+363
+00:29:06,000 --> 00:29:10,780
+إلكترونات بتكون minus one بناء على ذلك هذه minus
+
+364
+00:29:10,780 --> 00:29:14,300
+one وهذه ال Oxygen زي minus one طبعا كلنا عارفين
+
+365
+00:29:14,300 --> 00:29:20,200
+أن آيون الكربونيت بيكون minus two CO3الان ايش
+
+366
+00:29:20,200 --> 00:29:22,900
+فادتني ال formal charge؟ ال formal charge بتقوللي
+
+367
+00:29:22,900 --> 00:29:26,840
+ان الشحنتين السلبات اللي على ايون الكربون مع ال
+
+368
+00:29:26,840 --> 00:29:30,600
+oxygen و ال oxygen طبعا احنا ممكن نعمل resonance
+
+369
+00:29:30,600 --> 00:29:34,700
+structure يعني لو حركنا زوج إلكترونية بتصير double
+
+370
+00:29:34,700 --> 00:29:38,620
+bond و حركنا هذه بتصير ال O minus هنا و minus هنا
+
+371
+00:29:39,570 --> 00:29:43,810
+لو افترضنا التحريك من هنا وهذه صارت نيوتر، لكن ما
+
+372
+00:29:43,810 --> 00:29:47,970
+زال عندي minus، الآن لو عملنا كمان تحريك زوج
+
+373
+00:29:47,970 --> 00:29:51,770
+إلكترونات بهذا الشكل وزوج إلكترونات بهذا الشكل،
+
+374
+00:29:51,770 --> 00:29:55,390
+بيصير ال minus و ال minus هنا، لاحظوا معنى أنه
+
+375
+00:29:55,390 --> 00:29:59,830
+احنا هنا لما بنعمل resonance structuresبنعبّر عنها
+
+376
+00:29:59,830 --> 00:30:09,130
+بسهم له رأسين بنسميه double headed arrow وهو
+
+377
+00:30:09,130 --> 00:30:13,410
+يمثل حركة إلكترونات يعني الفرق بين هذا الشكل اللي
+
+378
+00:30:13,410 --> 00:30:18,000
+هو ال resonance structureوهذا الشكل هو فقط ان زوج
+
+379
+00:30:18,000 --> 00:30:22,000
+الالكترونات هذا اتحرك بهذا الشكل وهذا اتحمل على
+
+380
+00:30:22,000 --> 00:30:25,440
+الاكسجين او زوج الالكترونات هذا اتحرك بهذا الشكل
+
+381
+00:30:25,440 --> 00:30:29,620
+وهذا اتحمل على الاكسجين فمافيش عندى انا اطلاقا نقص
+
+382
+00:30:29,620 --> 00:30:34,140
+او زيادة في ازواج الالكترونات لكن حقيقة اللى موجود
+
+383
+00:30:34,140 --> 00:30:39,440
+عندى حركة الالكتروناتفالـ resonance بيصير or
+
+384
+00:30:39,440 --> 00:30:42,540
+resonance arises whenever we can write two or more
+
+385
+00:30:42,540 --> 00:30:45,420
+structures for a molecule with different
+
+386
+00:30:45,420 --> 00:30:48,500
+arrangement of electrons but identical arrangement
+
+387
+00:30:48,500 --> 00:30:52,120
+of atoms لاحظوا مهم كتير نعرف إيش معناه resonance
+
+388
+00:30:52,120 --> 00:30:56,180
+الذرات carbon و تلاتة oxygen ماتغيروش ولا تغير
+
+389
+00:30:56,180 --> 00:31:01,400
+مواقعهم بس اللي بتغير الإلكترونات اللي حواليهمهنا
+
+390
+00:31:01,400 --> 00:31:04,800
+كانوا الالكترونات بشكل اخر وهنا الالكترونات بشكل
+
+391
+00:31:04,800 --> 00:31:08,340
+ثاني وهنا الالكترونات بشكل تالت فلو قلنا ان ال
+
+392
+00:31:08,340 --> 00:31:12,840
+resonance فيه تغير في ال atoms لأ الذرات زي ما هما
+
+393
+00:31:12,840 --> 00:31:19,800
+ايش فيه تغير فيه ترتيبالإلكترونات وبشكل عام ال
+
+394
+00:31:19,800 --> 00:31:24,160
+resonance بنعبر عنه بهذا السهم اللي بنسميه double
+
+395
+00:31:24,160 --> 00:31:28,940
+headed arrows هذا الكلام بيقودنا إلى نقطة أن
+
+396
+00:31:28,940 --> 00:31:34,070
+الأسهم في ال organ ال chemistry لها معنىوبتلاحظوا
+
+397
+00:31:34,070 --> 00:31:38,630
+أن عندي أنواع كثيرة من الأسهم مثلا هذا السهم
+
+398
+00:31:38,630 --> 00:31:42,630
+العادل اللي احنا متعودين عليه اسمه straight arrow
+
+399
+00:31:42,630 --> 00:31:45,970
+هذا الـ straight arrow بنعبر فيه عن ال reaction
+
+400
+00:31:45,970 --> 00:31:49,530
+يعني هنا بيكون متفاعلات نواتج بنحط straight arrow
+
+401
+00:31:49,530 --> 00:31:54,970
+في السهمين اللي بيكونوا فوق فوق بعض هدولة pair of
+
+402
+00:31:54,970 --> 00:31:59,550
+straight arrowswith half heads كل سام بيكون عليه
+
+403
+00:31:59,550 --> 00:32:05,630
+نص راس هذا بنعبر فيه عن تفاعلات الإتزان لما يكون
+
+404
+00:32:05,630 --> 00:32:09,870
+عنده تفاعل فيه اتزان بعد نهاية التفاعل موجودة
+
+405
+00:32:09,870 --> 00:32:15,850
+المتفاعلات وموجودة النواتج بنعبر بال pair of
+
+406
+00:32:15,850 --> 00:32:20,410
+straight arrowsالسهم التالت اللي يتولس عمال اللي
+
+407
+00:32:20,410 --> 00:32:24,470
+بنحكي عنه اللي هو الـ Double Headed Strait أو
+
+408
+00:32:24,470 --> 00:32:29,910
+السهم برأسين هذا بنعبر فيه عن الـ Resonance اللي
+
+409
+00:32:29,910 --> 00:32:35,150
+هو فقط عملية تحرك إلكتروناتيالسهم اللى بيكون سهم
+
+410
+00:32:35,150 --> 00:32:39,870
+عادي لكن مائل بنسميه curved arrow هذا يعبر عن حركة
+
+411
+00:32:39,870 --> 00:32:43,630
+زوج من الإلكترونات يعني لما بقول هذا زوج
+
+412
+00:32:43,630 --> 00:32:47,790
+الإلكترونات تتحرك من هان لهان بعبر باستخدام هذا
+
+413
+00:32:47,790 --> 00:32:54,930
+السهم في عندى سهمبكون بس بـ half head يعني بنص رأس
+
+414
+00:32:54,930 --> 00:32:58,690
+وعشان هيك بنسميه fish hook يعني سهم زي السنارة
+
+415
+00:32:58,690 --> 00:33:02,990
+يعني هنا بس فيه نص رأس زي السنارة اللي بنصيد فيها
+
+416
+00:33:02,990 --> 00:33:08,770
+السمك فال fish hook arrow اللي هو سهم السنارة اللي
+
+417
+00:33:08,770 --> 00:33:13,550
+فيه half head نص رأس هذا بيعبر عن movement of one
+
+418
+00:33:13,550 --> 00:33:17,740
+electronلاحظوا الفرق بين الـ Curved Arrow اللي
+
+419
+00:33:17,740 --> 00:33:22,340
+مبين فيه رأسين يعبر عن حركة إلكترونين الـ Fish
+
+420
+00:33:22,340 --> 00:33:28,120
+Hook مبين فيه رأس واحد يعبر عن حركة إلكترون واحد
+
+421
+00:33:28,120 --> 00:33:31,700
+مثلا لو تخيلنا أنه عندنا رابطة، الرابطة متكونة
+
+422
+00:33:31,700 --> 00:33:35,340
+بشكل عام من إلكترونين بدا أكسرهم بحيث إلكترون يروح
+
+423
+00:33:35,340 --> 00:33:40,450
+على مجموعة مثل هذه وإلكترون على مجموعة مثل هذهالان
+
+424
+00:33:40,450 --> 00:33:44,090
+انا انا بحرك electron و بحرك electron فبستعمل ال
+
+425
+00:33:44,090 --> 00:33:48,890
+fish hook arrow و ال fish hook arrow فبيعطيني مثلا
+
+426
+00:33:48,890 --> 00:33:53,610
+two methyl groups حاملين one electron كل مجموعة
+
+427
+00:33:53,610 --> 00:33:57,450
+مثل منهم هذا اللي هو استعمال ال fish hook arrow
+
+428
+00:33:57,450 --> 00:34:02,750
+ابهيك بنكون انهينا الجزء الأول من العرض التقديمي
+
+429
+00:34:02,750 --> 00:34:06,890
+أو التذكيري لمساق ال organ chemistry و بنكمل ان
+
+430
+00:34:06,890 --> 00:34:08,850
+شاء الله في المرة القادمة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/mxpHX6Gn5_w_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/mxpHX6Gn5_w_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e3a56b883ac06606d0b99c14396d62fc53f47190
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/mxpHX6Gn5_w_raw.srt
@@ -0,0 +1,1720 @@
+1
+00:00:14,980 --> 00:00:20,280
+بسم الله الرحمن الرحيم بنبدأ اليوم إن شاء الله في
+
+2
+00:00:20,280 --> 00:00:26,140
+إعطاء مقدمة لمساق الكيمية العضوية لطلبة العلوم
+
+3
+00:00:26,140 --> 00:00:33,660
+الحياتيةطبعاً بشكل عام أي مقدمة بتكون عادة يعني في
+
+4
+00:00:33,660 --> 00:00:40,200
+غالبها تذكير بموضوعات سبق وإنه يعني درست في مساقات
+
+5
+00:00:40,200 --> 00:00:43,200
+الكيميا العامة سواء المساق الأول أو الثاني
+
+6
+00:00:43,200 --> 00:00:46,520
+فهيلزمنا
+
+7
+00:00:46,520 --> 00:00:51,000
+مفهوم ال bonding أو الارتباط يعني كيف بتتكون
+
+8
+00:00:51,000 --> 00:00:57,150
+الروابط في مساق الكيميا العضويةلو بدنا نذكر بهذا
+
+9
+00:00:57,150 --> 00:01:02,090
+الموضوع طبعا الموضوع مرتبط في الذرّة كلنا بنكون
+
+10
+00:01:02,090 --> 00:01:07,350
+عارفين أن الذرّة بشكل عام كانت بتتكون من النواء
+
+11
+00:01:07,350 --> 00:01:13,070
+الموجبة و هذه النواء الموجبة بتحتوي على البروتونات
+
+12
+00:01:13,070 --> 00:01:17,970
+و بتحتوي على النيوترونات طبعا ليش النواء بشكل عام
+
+13
+00:01:17,970 --> 00:01:24,490
+موجبة؟ لأن البروتونات موجبةوحول النواء تدور
+
+14
+00:01:24,490 --> 00:01:28,790
+الإلكترونات السالبة بناء على ذلك ولأنه بشكل عام
+
+15
+00:01:28,790 --> 00:01:33,470
+البروتونات والإلكترونات متساوية في العدد طبعا كنا
+
+16
+00:01:33,470 --> 00:01:41,130
+نقول أنه ذرة متعادلة بشكل عام العناصر بتعرف من عدد
+
+17
+00:01:41,130 --> 00:01:46,330
+البروتونات الموجبة اللي موجودة مثلا في الهيدروجين
+
+18
+00:01:46,330 --> 00:01:52,050
+في عندنا one proton في ال helium-2 وهكذاطيب
+
+19
+00:01:52,050 --> 00:01:57,770
+الإلكترونات احنا قلنا بتدور حول النوال موجبة لما
+
+20
+00:01:57,770 --> 00:02:02,290
+نيجي نسأل كيف الإلكترونات بتدور أخدنا شيء اسمه
+
+21
+00:02:02,290 --> 00:02:06,810
+Electronic Configuration و بنراجعه هنا بسرعة كبيرة
+
+22
+00:02:06,810 --> 00:02:11,930
+لحقيقة لأنه زي ما حكينا احنا هو فقط يعني تذكير
+
+23
+00:02:11,930 --> 00:02:17,830
+سريع احنا اتفقنا أنه في عندناللتوزيع الإلكتروني
+
+24
+00:02:17,830 --> 00:02:22,670
+مدارات رئيسية Shales المدار الأول المدار التاني
+
+25
+00:02:22,670 --> 00:02:28,710
+المدار التالت المدار الرابع ولمخدة الرمز N كل مدار
+
+26
+00:02:28,710 --> 00:02:34,590
+رئيسي بيقسم إلى مجموعة من المدارات الفرعية عدد
+
+27
+00:02:34,590 --> 00:02:41,190
+المدارات الفرعية بشكل عام بساوياللي هو رقم المدار
+
+28
+00:02:41,190 --> 00:02:46,170
+الرئيسي مثلا المدار الأول بيكون فيه مدار فرعي واحد
+
+29
+00:02:46,170 --> 00:02:51,710
+هو المدار الفرعي S ال sub shell S المدار التاني
+
+30
+00:02:51,710 --> 00:02:55,990
+بيكون فيه اتنين sub shells مدارات فرعية اللي هم S
+
+31
+00:02:55,990 --> 00:03:01,630
+و B المدار التالت بيكون فيه تلاتة sub shells S و B
+
+32
+00:03:01,630 --> 00:03:05,780
+و D و هكذابعد ما عرفنا أنه في عندنا المدارات
+
+33
+00:03:05,780 --> 00:03:09,500
+الرئيسية الـ shells المدارات الفرعية الـ subshells
+
+34
+00:03:09,500 --> 00:03:16,000
+في عندنا ال orbitals ال orbitals هي المكان بالفراغ
+
+35
+00:03:16,000 --> 00:03:21,320
+اللي بتوجد فيه الإلكترونات وكل orbital بشكل عام
+
+36
+00:03:21,320 --> 00:03:28,400
+بيحتوي على two electrons فال ال S subshell بيكون
+
+37
+00:03:28,400 --> 00:03:33,050
+فيه بس orbital واحد اللي هو ال Sالـ B-subshell
+
+38
+00:03:33,050 --> 00:03:39,250
+بيكون فيه تلاتة orbitals اللي هم متعامدات على بعض
+
+39
+00:03:39,250 --> 00:03:44,790
+سبق أننا درسناهم اللي بنسميهم BX وBY وBZ الـ D
+
+40
+00:03:44,790 --> 00:03:49,730
+-subshell بيكون فيه
+
+41
+00:03:49,730 --> 00:03:57,070
+خمسة orbitals اللي اسمها DXY DXY DYZ DXZ DZ² DX²
+
+42
+00:03:57,070 --> 00:04:02,820
+-Y² إحنا اللي بهمنا في هذه المرحلةانه كل orbital
+
+43
+00:04:02,820 --> 00:04:07,420
+بيحتوي على إلكترونين فبناء على ذلك ال S orbital
+
+44
+00:04:07,420 --> 00:04:12,140
+بيكون فيه two electrons ال BX two electrons ال BY
+
+45
+00:04:12,140 --> 00:04:16,460
+two electrons ال BZ two electrons عشانك لما انا
+
+46
+00:04:16,460 --> 00:04:22,480
+بده اقول ان ال B بالمجمل كام orbital تلاتة بتحتوي
+
+47
+00:04:22,480 --> 00:04:29,520
+كام إلكترون ستة ال D orbitalsأو الـ D-sub shell
+
+48
+00:04:29,520 --> 00:04:33,660
+مكوّن من خمسة orbitals كل orbital بياخد إلكترونين
+
+49
+00:04:33,660 --> 00:04:37,660
+بناء على ذلك عدد الإلكترونات في الـ D-sub shell
+
+50
+00:04:37,660 --> 00:04:41,780
+بيكون عشرة عدد ال orbitals في الـ D-sub shell
+
+51
+00:04:41,780 --> 00:04:50,960
+بيكون خمسة على هذا الأساس ممكن أنهانتبع بتدرج
+
+52
+00:04:50,960 --> 00:04:55,180
+التوزيع الإلكتروني مثلا الذرة اللي فيها one
+
+53
+00:04:55,180 --> 00:04:59,240
+electron اللي هي الهيدروجين بنقول توزيع الإلكتروني
+
+54
+00:04:59,240 --> 00:05:03,400
+one S one الذرة اللي فيها two electrons الهيليام
+
+55
+00:05:03,400 --> 00:05:09,040
+بنقول one S two الآن ال S أقصى تحمل إليه I orbital
+
+56
+00:05:09,040 --> 00:05:13,740
+أقصى تحمل إليه إلكترونين بناء على ذلك هنا بنكون
+
+57
+00:05:13,740 --> 00:05:17,900
+خلصنا one S one الهيدروجين one S two الهيليام لو
+
+58
+00:05:17,900 --> 00:05:23,550
+إجينا للليفيامالليثيام بـ 3 إلكترونات أول اتنين
+
+59
+00:05:23,550 --> 00:05:27,670
+هيروحوا على الـ 1S2 بعدين الإلكترون التالت هيروح
+
+60
+00:05:27,670 --> 00:05:33,930
+على الـ 2S1 بعده البريليام بيروح 2S2 الآن الـ 2S
+
+61
+00:05:33,930 --> 00:05:38,950
+سكر بنبدأ في الـ B-Orbitals الـ B-Orbitals بياخدوا
+
+62
+00:05:38,950 --> 00:05:43,070
+بحد أقصى 6 إلكترونات بناء على ذلك البرون بيكون
+
+63
+00:05:43,070 --> 00:05:48,690
+تركيبه الإلكتروني 1S2 → 2S2 → 2B1 الكربون اللي هو
+
+64
+00:05:48,690 --> 00:05:54,080
+العنصر الأهم عندنافي أساس الـ organic chemistry
+
+65
+00:05:54,080 --> 00:05:59,060
+الكربون ست إلكترونات ضروري نتبه للكربون عدد
+
+66
+00:05:59,060 --> 00:06:03,560
+الإلكترونات في الكربون ست إلكترونات الان لو قلنا
+
+67
+00:06:03,560 --> 00:06:07,220
+ايش التوزيع الإلكتروني للكربون التوزيع الإلكتروني
+
+68
+00:06:07,220 --> 00:06:13,140
+للكربون 1S2 2S2 2B2 واضح؟
+
+69
+00:06:16,500 --> 00:06:20,540
+وهكذا لو بدنا نشوف توزيع الـ Nitrogen والـ Oxygen
+
+70
+00:06:20,540 --> 00:06:24,780
+وكل العناصر سبق أنه درس يعني بشكل عام التوزيع
+
+71
+00:06:24,780 --> 00:06:28,360
+الإلكتروني في مساخات الكيميا العامة لكن هذه عملية
+
+72
+00:06:28,360 --> 00:06:33,200
+التذكير لاحظوا هنا لو بدنا نتطلع على الإرتباطات
+
+73
+00:06:33,200 --> 00:06:38,320
+اللي بتعملها العناصر الـ hydrogen بيكون عامل أو
+
+74
+00:06:38,320 --> 00:06:42,140
+بيكون موجود في one electron وبناء على ذلك الـ
+
+75
+00:06:42,140 --> 00:06:46,770
+hydrogenمستعد إنه يعمل رابط كمان عشان يجيب
+
+76
+00:06:46,770 --> 00:06:51,850
+الإلكترون التاني الهيليام بتو إلكترون one as two
+
+77
+00:06:51,850 --> 00:06:58,210
+مسكر فبشكل عام ما بيعملش bonding لو إجينا الليثيام
+
+78
+00:06:58,210 --> 00:07:01,950
+ب one إلكترون بده يعمل one bond البريليام ب two
+
+79
+00:07:01,950 --> 00:07:06,090
+إلكترون بده يعمل two bonds البرون ب three إلكترون
+
+80
+00:07:06,090 --> 00:07:11,230
+بده يعمل three bonds الكربون ب four إلكترون بده
+
+81
+00:07:11,230 --> 00:07:15,580
+يعملFour bonds وهذا سنركز عليه مرة تانية الـ
+
+82
+00:07:15,580 --> 00:07:19,760
+Carbon في حالة الـ Nitrogen صح عندي خمس إلكترونات
+
+83
+00:07:19,760 --> 00:07:23,580
+لكن اتنين منهم بيكونوا في الـ S بيكونوا عاملين الـ
+
+84
+00:07:23,580 --> 00:07:26,840
+Bearing فبيظل ان الـ Nitrogen فيه تلت إلكترونات
+
+85
+00:07:26,840 --> 00:07:31,600
+مفردة بيعمل تلت روابط والأكسجين فيه إلكترونين
+
+86
+00:07:31,600 --> 00:07:36,400
+مفردين بيعمل رابطتين والفلورين بيعمل رابط واحدة
+
+87
+00:07:36,670 --> 00:07:40,610
+إذاً بدنا نكون إحنا منتبهين لهدول العناصر الأربعة
+
+88
+00:07:40,610 --> 00:07:43,030
+اللي أنا وماما بشكل عام بيمروا معنى في الـ Organ
+
+89
+00:07:43,030 --> 00:07:46,230
+الchemistry يعني الـ Lithium و البريليوم و البرون
+
+90
+00:07:46,230 --> 00:07:49,470
+عادة بيمروش معنى في الـ Organ الchemistry إلا ما
+
+91
+00:07:49,470 --> 00:07:53,550
+ندر لكن اللي بيمروا بشكل كبير الـ Carbon، الـ
+
+92
+00:07:53,550 --> 00:07:56,750
+Nitrogen، الـ Oxygen، الـ Fluor لما بنيجي بنعمل
+
+93
+00:07:56,750 --> 00:08:02,010
+روابط دائما الـ Carbon بيكون عامل أربعة bonds الـ
+
+94
+00:08:02,010 --> 00:08:06,470
+Nitrogen بيكون عامل تلاتة bondsوفيه زوج واحد من
+
+95
+00:08:06,470 --> 00:08:11,170
+الإلكترونات الـ Oxygen بيكون عامل تنتين bonds وفيه
+
+96
+00:08:11,170 --> 00:08:15,430
+زوجين من الإلكترونات و ال halogens لفلور و لكلور
+
+97
+00:08:15,430 --> 00:08:20,790
+بيكونوا عاملين رابطة واحدة و فيهم تلت أزواج من
+
+98
+00:08:20,790 --> 00:08:28,570
+الإلكترونات الآن هذه فكرة عن التوزيع الإلكتروني لو
+
+99
+00:08:28,570 --> 00:08:34,170
+إجينا نقول كيف بتتكون الروابط الروابط إما أن تكون
+
+100
+00:08:35,240 --> 00:08:41,920
+زي ما اتعلمتوا في الكيميا العامة Ionic bonds و
+
+101
+00:08:41,920 --> 00:08:45,940
+بتقدي إلى Ionic compounds أو Covalent bonds و
+
+102
+00:08:45,940 --> 00:08:50,340
+بتقدي إلى ال molecular compounds بشكل عام ال Ionic
+
+103
+00:08:50,340 --> 00:08:56,060
+bonds بتكون ما بين ذرات
+
+104
+00:08:56,830 --> 00:09:02,650
+من المجموعات الأولى المعدنية الـ Metals مع ذرات من
+
+105
+00:09:02,650 --> 00:09:06,470
+الـ Non-metals مثلا لو أخدنا الصوديوم الصوديوم فيه
+
+106
+00:09:06,470 --> 00:09:11,890
+one electron بده كمان electron والكلور بشكل عام
+
+107
+00:09:11,890 --> 00:09:16,090
+برضه فيه one electron في هذه الحالة يمكن أن
+
+108
+00:09:16,090 --> 00:09:19,970
+الصوديوم هذا يفقد ال electron عشان يرجع إلى تركيب
+
+109
+00:09:19,970 --> 00:09:25,870
+ثمانيهذا الـ Sodium بيفقد الإلكترون ويرجع إلى
+
+110
+00:09:25,870 --> 00:09:30,670
+تركيب ثماني فبصير Na Plus الكلور بيكتسب الإلكترون
+
+111
+00:09:30,670 --> 00:09:36,890
+بيصير Cl- Na Plus مع Cl- بيعطينا المركب نتيجة
+
+112
+00:09:36,890 --> 00:09:40,110
+تجاذب الأيونات اللي هو Sodium Chloride أو ملح
+
+113
+00:09:40,110 --> 00:09:44,660
+الطعامالان ممكن نتطلع على مُركّب زي الـ Magnesium
+
+114
+00:09:44,660 --> 00:09:48,220
+Fluoride، المغنيسيام عنده إلكترونين إزيادة،
+
+115
+00:09:48,220 --> 00:09:52,060
+بيفقدهم عشان يرجع إلى تركيب ثماني، الفلور بده
+
+116
+00:09:52,060 --> 00:09:56,120
+إلكترون، بناءً على ذلك، المغنيسيام بيكون بده
+
+117
+00:09:56,120 --> 00:09:59,700
+يتفاعل مع ذرتين فلور، بيفقد إلكترون لذرة، بيفقد
+
+118
+00:09:59,700 --> 00:10:04,670
+الإلكترون التانيلذرة تانية بيصير Mg2 plus مع
+
+119
+00:10:04,670 --> 00:10:08,610
+أيونين floor minus بيتجاذب كلهم مع بعض بيصير عند
+
+120
+00:10:08,610 --> 00:10:15,310
+المركب اللي ماخد ال .. بشكل عام الصيغة الجزائية
+
+121
+00:10:15,310 --> 00:10:24,310
+اللي هي MgF2 ionic compound في حالة الـ covalent
+
+122
+00:10:24,310 --> 00:10:30,410
+compounds بنلاحظ أنه عملية الفقد هي عملية صعبة
+
+123
+00:10:31,510 --> 00:10:36,510
+وبناء على ذلك تتم أو يتم تكوين الـ Covalent bonds
+
+124
+00:10:36,510 --> 00:10:41,130
+من خلال المشاركة مش من خلال الفقد مثلا لو بدنا
+
+125
+00:10:41,130 --> 00:10:45,550
+نطلع على جزء الهيدروجين الهيدروجين فيه واحد
+
+126
+00:10:45,550 --> 00:10:49,290
+إلكترون وهيدروجين تاني واحد إلكترون بيشتركوا بدول
+
+127
+00:10:49,290 --> 00:10:52,970
+الإلكترونين بيعملوا Covalent bond بيصير عند
+
+128
+00:10:52,970 --> 00:10:58,910
+الهيدروجين moleculeكذلك الحال لو بدنا نتطلع مثلا
+
+129
+00:10:58,910 --> 00:11:03,870
+على الكلور الكلور في one electron لكن هذا الكلور
+
+130
+00:11:03,870 --> 00:11:08,710
+صعب أنه يفقد هذا ال electron مثلا لو بدنا نتخيل أن
+
+131
+00:11:08,710 --> 00:11:11,570
+واحدة من الكلور بدها تفقد ال electron للذرّة
+
+132
+00:11:11,570 --> 00:11:14,870
+التانية المشكلة هيصير فيها 6 electron هي عندها
+
+133
+00:11:14,870 --> 00:11:20,270
+سبعة بتستنى تصير تمانية مش بتستنى ترجع للستة بناء
+
+134
+00:11:20,270 --> 00:11:24,820
+على ذلك ذرتين الكلور هنابشتركوا بالإلكترونات
+
+135
+00:11:24,820 --> 00:11:28,020
+بيعملوا اللي هي الرابطة التساومية أو التشاركية
+
+136
+00:11:28,020 --> 00:11:35,580
+اللي هي عبارة عن جزء الـ CL2 بيكون عنده CL و رابطة
+
+137
+00:11:35,580 --> 00:11:40,820
+أحدية من إلكترونين و CL و كل ذرة CL بيكون عليها
+
+138
+00:11:40,820 --> 00:11:45,760
+تلت أزواج من الإلكترونات يعني ست إلكترونات زاد
+
+139
+00:11:45,760 --> 00:11:49,400
+إلكترونية الرابطة هنا بيقدر نتخيلإن عندنا 8
+
+140
+00:11:49,400 --> 00:11:53,540
+إلكترون حوالين هذه و 8 إلكترون حوالين الذرة
+
+141
+00:11:53,540 --> 00:11:57,840
+التانية طبعا سبق إن اتعلمنا إن الذرة إلها طاقة و
+
+142
+00:11:57,840 --> 00:12:03,520
+إلها طول و كل هذا الكلام دوريس أهم الأشياء اللي
+
+143
+00:12:03,520 --> 00:12:07,020
+ربما بيلزم أن نكون منتبهين إلها إحنا في ال organ
+
+144
+00:12:07,020 --> 00:12:10,560
+ال chemistry اللي هي عدد الروابط اللي بتعملها
+
+145
+00:12:10,560 --> 00:12:16,860
+العناصرالهيدروجين يعمل روابط واحدة تشاركية،
+
+146
+00:12:16,860 --> 00:12:22,600
+الكربون يعمل أربع روابط تشاركية، النيتروجين يعمل
+
+147
+00:12:22,600 --> 00:12:24,740
+تلاتة روابط تشاركية، الأكسجين يعمل تنتين روابط
+
+148
+00:12:24,740 --> 00:12:28,080
+تشاركية، الفلورين والهالوجين، زيكلورين، برومين،
+
+149
+00:12:28,080 --> 00:12:31,560
+أيودين، كلهم يعملوا رابط واحدة تشاركية، لاحظون
+
+150
+00:12:31,560 --> 00:12:37,250
+احنا رسميا جزء كبير كتيرلكن هذا الجزء إذا بدنا
+
+151
+00:12:37,250 --> 00:12:41,530
+نتطلع هل تتحقق في أعداد الروابط اللي بتعملها كل
+
+152
+00:12:41,530 --> 00:12:45,830
+ذرع الجواب آه مثلا هذه الهيدروجين عاملة رابطة هنا
+
+153
+00:12:45,830 --> 00:12:50,150
+هنا هنا في كل المواقع عاملة كام رابطة؟ رابطة واحدة
+
+154
+00:12:50,150 --> 00:12:53,590
+لو بدنا نتطلع على الكاربون اللي هنا عاملة رابطة مع
+
+155
+00:12:53,590 --> 00:12:57,570
+الكاربون التاني اتنين تلاتة اربعةالان لو اجينا
+
+156
+00:12:57,570 --> 00:13:00,970
+تطلعنا على الـ Carbon اللي موجودة هنا، هذه الـ
+
+157
+00:13:00,970 --> 00:13:05,670
+Carbon برضه عاملة أربع روابط، لكن مرات كتيرة لما
+
+158
+00:13:05,670 --> 00:13:11,070
+يكون عندى Hydrogen باختصر كتابتهم، يعني حقيقة هذه
+
+159
+00:13:11,070 --> 00:13:17,060
+الـهذا الكربون اللي في الوسط وهذا الكربون اللي في
+
+160
+00:13:17,060 --> 00:13:21,320
+الوسط هي عبارة عن CH2 يعني هي عاملة رابطتين مع
+
+161
+00:13:21,320 --> 00:13:26,940
+الكربون لكن بنفس الوقت هي برضه عاملة رابطتين مع
+
+162
+00:13:26,940 --> 00:13:31,940
+الهيدروجين لكن مختصرات في الرسم لكن المفروض أي
+
+163
+00:13:31,940 --> 00:13:36,840
+طالب organic يعرف إن هنا في عنده ذرتين هيدروجين
+
+164
+00:13:36,840 --> 00:13:41,850
+وإحنا متعودين نختصرهمكذلك الحال مثلا هذه الكربون
+
+165
+00:13:41,850 --> 00:13:46,610
+ممكن البعض يظن انها عاملة هذه الكربون البعض يظن
+
+166
+00:13:46,610 --> 00:13:51,490
+انها عاملة تلت روابط الحقيقة لأ هذه الكربون بتعمل
+
+167
+00:13:51,490 --> 00:13:56,670
+اربع روابط بس في هيدروجين هنا احنا بنختصرها زي ما
+
+168
+00:13:56,670 --> 00:14:00,410
+قلنا ان هذه الكربون بتعمل برضه اربع روابط
+
+169
+00:14:00,410 --> 00:14:04,710
+الهيدروجين اختصرناهم احنا ممكن هذه مرات تشوفوها
+
+170
+00:14:04,710 --> 00:14:08,660
+مختصرة وممكن هذه تشوفوها مختصرةالخلاصة ان اي
+
+171
+00:14:08,660 --> 00:14:14,780
+carbon عليها عدد من الروابط اقل من الاربعة بتكونوا
+
+172
+00:14:14,780 --> 00:14:20,820
+فاهمين تلقائيا ان باقي الروابط موجودة ولكن اختصرت
+
+173
+00:14:20,820 --> 00:14:25,490
+من ناحية الكتابةالان ال oxygen هنا بيعمل رابطتين
+
+174
+00:14:25,490 --> 00:14:30,890
+سواء كانوا على شكل double bond او او single bond
+
+175
+00:14:30,890 --> 00:14:33,610
+single bond يعني هذا ال oxygen عاملة double bond
+
+176
+00:14:33,610 --> 00:14:37,150
+مع الكربون مهم عاملة رابطتين هذا ال oxygen عاملة
+
+177
+00:14:37,150 --> 00:14:40,070
+single bond مع هذا الكربون و single bond مع هذا
+
+178
+00:14:40,070 --> 00:14:43,630
+الكربون ممكن بعض يتطلع على هذا الكربون كام رابطة
+
+179
+00:14:43,630 --> 00:14:48,870
+عاملةطبعا بالتأكيد أربعة المبينين تلاتة رابطة مع
+
+180
+00:14:48,870 --> 00:14:51,350
+الـ Oxygen و رابطة مع الـ Carbon و رابطة مع الـ
+
+181
+00:14:51,350 --> 00:14:55,750
+Carbon الرابعة موجودة ولكنها مختصرة هي رابطة
+
+182
+00:14:55,750 --> 00:15:01,700
+Carbon-Hydrogenهاي كلور هنا عامل بس رابطة واحدة،
+
+183
+00:15:01,700 --> 00:15:05,660
+هاي نيتروجين هنا كام رابطة بيعمل تلاتة، لاحظوا هذا
+
+184
+00:15:05,660 --> 00:15:10,180
+النيتروجين عامل تلت روابط، الكاربون اللي هنا واحد،
+
+185
+00:15:10,180 --> 00:15:13,520
+اتنين، تلاتة، اربع، بيعمل اربع روابط، فدائما
+
+186
+00:15:13,520 --> 00:15:17,780
+الـvalences of the common elements in organic
+
+187
+00:15:17,780 --> 00:15:22,580
+chemistry لازم نكون منتبهين لهم، بنركز عليهم كتير،
+
+188
+00:15:22,580 --> 00:15:27,090
+لما بنرسم الأشكالالهيدروجين بيعمل رابطة الكاربون
+
+189
+00:15:27,090 --> 00:15:30,490
+أربعة نيتروجين تلاتة الأكسجين رابطتين والهالوجين
+
+190
+00:15:30,490 --> 00:15:35,810
+رابطة واحدة
+
+191
+00:15:35,810 --> 00:15:41,570
+الآن
+
+192
+00:15:43,550 --> 00:15:47,630
+بنجي لموضوع تذكير جديد، احنا قلنا كل هذه مقدمة
+
+193
+00:15:47,630 --> 00:15:52,670
+المفروض انه سبق انها درست لكن احنا بنذكر فيها اللي
+
+194
+00:15:52,670 --> 00:15:57,450
+هي الـ polarity of bonds بشكل عام الـ polarity of
+
+195
+00:15:57,450 --> 00:16:01,810
+bonds ان الرابط يكون لها طرف موجة بطرف سالب، هاي
+
+196
+00:16:01,810 --> 00:16:06,210
+معناه الـ polarity ببساطة وهذه بتعتمد على الفرق
+
+197
+00:16:06,210 --> 00:16:10,200
+السالبية الـ polarity of bondsDepends on the
+
+198
+00:16:10,200 --> 00:16:13,700
+electronegativity difference الآن في السالبية لما
+
+199
+00:16:13,700 --> 00:16:20,380
+درسناها أخدنا قيم للعناصر في السالبية بموجودة
+
+200
+00:16:20,380 --> 00:16:24,820
+ملخصة في هذا الجدول وكنا بنتذكر أن أعلى عنصر في
+
+201
+00:16:24,820 --> 00:16:29,700
+السالبية كان لفلوري بسالبية تقريبا أربعةوبعد ذلك
+
+202
+00:16:29,700 --> 00:16:32,640
+من العناصر العالية في السالبية الأكسجين
+
+203
+00:16:32,640 --> 00:16:37,380
+والنيتروجين والكلور والعناصر التانية السالبية
+
+204
+00:16:37,380 --> 00:16:43,700
+قليلة تبعتها الان عندما يحدث رابط ما بين عنصرين
+
+205
+00:16:43,700 --> 00:16:49,190
+مثلا لو افترضنا الفلور مع الكاربون عامل رابطةأى
+
+206
+00:16:49,190 --> 00:16:54,050
+طرف بدى يكون نسبيا سالب جزئيا سالب أو أى طرف بدى
+
+207
+00:16:54,050 --> 00:16:58,710
+يكون جزئيا موجب طبعا الفلور أعلى سالبية من الكربون
+
+208
+00:16:58,710 --> 00:17:03,110
+فبناء على ذلك رابطة الفلور والكربون الفلور هيكون
+
+209
+00:17:03,110 --> 00:17:06,650
+partially negative والكربون هيكون partially
+
+210
+00:17:06,650 --> 00:17:11,590
+positive واضح؟ و هكذا لو قولنا مثلا الchlor مع
+
+211
+00:17:11,590 --> 00:17:15,770
+الكربونالكلور يكون بارشالي نيجاتيف والكربون
+
+212
+00:17:15,770 --> 00:17:20,730
+بارشالي بوزيتيف لأن فرق السالبيةلصالح الكلور
+
+213
+00:17:20,730 --> 00:17:24,290
+الكلور أعلى سلبية من الكربون فلما نيجي نقول أنه في
+
+214
+00:17:24,290 --> 00:17:28,770
+عندنا رابطة carbon chlorine bond هل هذه الرابطة
+
+215
+00:17:28,770 --> 00:17:33,370
+polar الجواب أه بتكون الرابطة مش polar لما يكون
+
+216
+00:17:33,370 --> 00:17:37,370
+السلبية متساوية يعني مثلا لو الكلور عمل مع الكلور
+
+217
+00:17:37,370 --> 00:17:42,090
+بشكل عام بنقول الرابطة non polar لكن الكلور مع
+
+218
+00:17:42,090 --> 00:17:46,810
+الكربونالكلور الـ electronegativity تبعته 3.2
+
+219
+00:17:46,810 --> 00:17:51,490
+والكربون 2.5 فيه فرق سالبية لصالح الكلور إذا في
+
+220
+00:17:51,490 --> 00:17:54,210
+هذه الحالة الكلور بيكون partially negative
+
+221
+00:17:54,210 --> 00:18:01,510
+والكربون partially positiveهذه في عندي أمثلة مثلا
+
+222
+00:18:01,510 --> 00:18:07,410
+الـ H مع الـ CL واضح أن الـ polarity أعلى أو
+
+223
+00:18:07,410 --> 00:18:12,610
+السالبية أكتر عند الـ CL فبنعبر احنا بعدة طرق يعني
+
+224
+00:18:12,610 --> 00:18:17,230
+ممكن نعملسهم ويله طرف كأنه موجب يعني كأنه هذا
+
+225
+00:18:17,230 --> 00:18:20,450
+الطرف الموجب و هذا الطرف السالب او ممكن نكتب
+
+226
+00:18:20,450 --> 00:18:24,230
+partially negative charge و partially positive
+
+227
+00:18:24,230 --> 00:18:28,270
+charge فالخلاص ان هذا الكلام او هذا الكلام بيدلنا
+
+228
+00:18:28,270 --> 00:18:33,250
+على ان ال chlorine هو اللي بيمثل الطرف السالب و ال
+
+229
+00:18:33,250 --> 00:18:36,710
+hydrogen هو اللي بيمثل الطرف الموجب الان عندنا
+
+230
+00:18:36,710 --> 00:18:39,570
+روابط اخرى مثلا ال carbon و ال nitrogen او ال
+
+231
+00:18:39,570 --> 00:18:42,950
+carbon و ال oxygen ال nitrogen و ال oxygen بمثل
+
+232
+00:18:43,700 --> 00:18:47,960
+الطرف السالب الكاربون الطرف الموجب الكاربون مع
+
+233
+00:18:47,960 --> 00:18:51,060
+الكلور و البروم الكلور و البروم طرف سالب و
+
+234
+00:18:51,060 --> 00:18:54,640
+الكاربون طرف موجب الهيدروجين مع الأكسجن و السلفر
+
+235
+00:18:54,640 --> 00:18:58,220
+الأكسجن و السلفر طرف سالب الهيدروجين طرف موجب
+
+236
+00:18:58,220 --> 00:19:02,800
+البروم مع الكلور الكلور سالبيته أعلى بيكون الكلور
+
+237
+00:19:02,800 --> 00:19:09,740
+نسبيا سالب البروم موجب السيليكون مع الكاربونتقريبا
+
+238
+00:19:09,740 --> 00:19:13,880
+إذا بنرجع للجدول لاحظوا أن الكربون أعلى من
+
+239
+00:19:13,880 --> 00:19:17,480
+السيليكون الكربون اتنين و نص السيليكون واحد وتسعة
+
+240
+00:19:17,480 --> 00:19:21,860
+عشر بناء على ذلك الكربون بدي يكون نسبيا هو السالب
+
+241
+00:19:21,860 --> 00:19:29,640
+والسيليكون هو الموجب الآن الكلام اللي حكيناه هو
+
+242
+00:19:29,640 --> 00:19:34,160
+حقيقة بيعبر عن ال polarity of bonds لكن هذه
+
+243
+00:19:34,160 --> 00:19:41,320
+الروابط لو إجت في جزئالجزيق يحتوي على عدة روابط هل
+
+244
+00:19:41,320 --> 00:19:46,700
+الجزيق بمجمله يكون قطبي ولا غير قطبي قطبية الجزيق
+
+245
+00:19:46,700 --> 00:19:52,180
+بتعتمد على شكله الهندسي معنى كلمة الشكل الهندسي
+
+246
+00:19:52,180 --> 00:19:57,240
+اللي هو مجموع الـ polarity of bonds مثلا لو
+
+247
+00:19:57,240 --> 00:20:01,160
+افترضنا فيه جزيق linear وهذه رابطة قطبية وهذه
+
+248
+00:20:01,160 --> 00:20:07,810
+قطبية لكن التنتين عكس بعض بشطب بعضفهذا الجزء بيكون
+
+249
+00:20:07,810 --> 00:20:13,210
+non-polar الـ linear molecule non-polar لو كان
+
+250
+00:20:13,210 --> 00:20:19,710
+عندي جزء triangular planner رابطة، اتنين، تلاتة
+
+251
+00:20:19,710 --> 00:20:24,110
+وكل رابطة فيهم قطبية هل الجزء بمجمله قطبي ولا غير
+
+252
+00:20:24,110 --> 00:20:31,410
+قطبي الحقيقة أن الجزء بمجمله بيكون غير قطبي لأن
+
+253
+00:20:31,410 --> 00:20:35,720
+محصلة هدولة تشتب مع محصلة هذهفهذا الجزء بيكون
+
+254
+00:20:35,720 --> 00:20:40,280
+عندنا هنا non-polar بينما لو كان في عندي جزء مكون
+
+255
+00:20:40,280 --> 00:20:44,950
+بس من رابطتين bent بيكون الجزء polarهنا
+
+256
+00:20:44,950 --> 00:20:50,490
+التتراهيدرال التتراهيدرال رجاءً يعني الكل ينتبه
+
+257
+00:20:50,490 --> 00:20:57,550
+لأنه هنا للأسف مكتوبة خطأ التتراهيدرال بيكون non
+
+258
+00:20:57,550 --> 00:21:01,010
+-polar molecule لأن محاصلة القطبية لهدولة
+
+259
+00:21:01,010 --> 00:21:05,530
+الرابطتين عكس المحاصلة للرابطتين التانيات فهذا
+
+260
+00:21:05,530 --> 00:21:09,550
+التتراهيدرال structure حقيقة زي الميثين
+
+261
+00:21:09,550 --> 00:21:11,210
+والتتراكلوروكاربون
+
+262
+00:21:12,810 --> 00:21:18,610
+non-polar molecule ضروري ننتبه لها هذا الشكل non
+
+263
+00:21:18,610 --> 00:21:23,890
+-polar molecule وبشكل عام بإمكاننا نتطلع على هذا
+
+264
+00:21:23,890 --> 00:21:28,570
+الجدول و نتذكر و ننتبه أن نحسب صح ال polarity of
+
+265
+00:21:28,570 --> 00:21:32,010
+molecules الخلاصة أن ال polarity of molecules
+
+266
+00:21:32,010 --> 00:21:38,790
+بتعتمد على محصلة القطبية للروابط المنفردة ال
+
+267
+00:21:38,790 --> 00:21:43,530
+polarity of molecules بتعتمد علىمحصلة قطبية
+
+268
+00:21:43,530 --> 00:21:48,150
+للروابط المنفردة هذا الكلام ضروري أن ننتبهله إذا
+
+269
+00:21:48,150 --> 00:21:52,690
+مرة تانية بأكد أن الـ polarity of bonds بتعتمد على
+
+270
+00:21:52,690 --> 00:21:56,390
+فرق السالبية لكن ال polarity of molecule بتعتمد
+
+271
+00:21:56,390 --> 00:22:03,650
+على ال geometry أو محصلة الروابط الآن
+
+272
+00:22:03,650 --> 00:22:09,500
+الجزيئات العضوية فيها ظاهرة مشهورةاللي هي ظاهرة
+
+273
+00:22:09,500 --> 00:22:13,520
+المتشكلات أو ال isomers هذه الظاهرة احنا هندل
+
+274
+00:22:13,520 --> 00:22:19,440
+نتدرج معاها أثناء دراستنا لكن بشكل عام مش هنشرح كل
+
+275
+00:22:19,440 --> 00:22:24,220
+هذا ال scheme لان لأن هذا بيجي بوقته لكن لما نقول
+
+276
+00:22:24,220 --> 00:22:30,280
+ايش هم ال isomers ال isomers هم مركباتالهم نفس الـ
+
+277
+00:22:30,280 --> 00:22:33,600
+molecular formula لكن بيختلفوا في الشكل البناء
+
+278
+00:22:33,600 --> 00:22:38,620
+they have different structures واضح؟ فبيكون ال
+
+279
+00:22:38,620 --> 00:22:41,380
+isomers different compounds that have the same
+
+280
+00:22:41,380 --> 00:22:44,440
+molecular formula but they have different
+
+281
+00:22:44,440 --> 00:22:48,140
+structures طبعا هنتعلم أنه بتقسم إلى
+
+282
+00:22:48,140 --> 00:22:51,900
+constitutional isomers و stereo isomers و هذا
+
+283
+00:22:51,900 --> 00:22:56,880
+الكلام بيدرس بالتفصيل بحينه لكن الآن احنا اللي
+
+284
+00:22:56,880 --> 00:23:01,930
+بنقوله ببساطةإنه لما بنيجي بنحكي عن الـ isomers،
+
+285
+00:23:01,930 --> 00:23:06,750
+الـ isomers هم مركبات امكونين من نفس العناصر لكن
+
+286
+00:23:06,750 --> 00:23:11,550
+امركبين بطرق مختلفة، انا يعني ممكن اعطي مثال، يعني
+
+287
+00:23:11,550 --> 00:23:15,310
+لو افترضت مثلا إنه عنده مركب امكون من هذه التلات
+
+288
+00:23:15,310 --> 00:23:19,430
+عناصر،و أتخيل هذه الأقلام التلاتة أحمر و أزرق و
+
+289
+00:23:19,430 --> 00:23:24,090
+أسود الآن هدولة بهذا الشكل عاملين مُركّب و هذا
+
+290
+00:23:24,090 --> 00:23:28,910
+المُركّب ترتيبه أحمر أزرق أسود أنا ممكن أعمل تغيير
+
+291
+00:23:28,910 --> 00:23:33,630
+بهذا الشكل صار عندي أسود أحمر أزرق أكيد أن الشكل
+
+292
+00:23:33,630 --> 00:23:38,070
+الأول و الشكل التاني مش نفس الاشيء فبنقول أنه أنا
+
+293
+00:23:38,070 --> 00:23:41,790
+انا امكون من نفس العناصر عندى نفس الصيغة الجزائية
+
+294
+00:23:41,790 --> 00:23:48,150
+لكن بنائياأحمر أسود أحمر أزرق غير عن أحمر أزرق
+
+295
+00:23:48,150 --> 00:23:52,990
+أسود فبصير عنده شكلين مختلفين على أي حال موضوع الـ
+
+296
+00:23:52,990 --> 00:23:57,490
+isomers زي ما قولته أنواعها موضوع بنضلنا نستمر في
+
+297
+00:23:57,490 --> 00:24:03,380
+التدرج فيه وبفهمه خطوة خطوةفيه منه نوعين أساسيًا
+
+298
+00:24:03,380 --> 00:24:07,300
+Constitutional Isomers بندرسهم في الفصول اتنين
+
+299
+00:24:07,300 --> 00:24:13,340
+وتلاتة تقريبًا وأربعة وفي عند استيريو Isomers
+
+300
+00:24:13,340 --> 00:24:17,940
+بنفرض لها فصل كامل أثناء دراستنا اللي هو الفصل
+
+301
+00:24:17,940 --> 00:24:18,980
+الخامس
+
+302
+00:24:24,320 --> 00:24:29,700
+الان بشكل عام كيف يرسم الجزء العضوى الجزء العضوى
+
+303
+00:24:29,700 --> 00:24:34,860
+ممكن نرسمه من خلال ان نكتب عدد الذرات كاملا يعني
+
+304
+00:24:34,860 --> 00:24:41,060
+مثلا اقول CH3 CH2 CH2 OH هذه رسمة و ممكن نختصره
+
+305
+00:24:41,060 --> 00:24:46,300
+بهذا الشكل فقط نحط خطوط الان ايش معنى هذه النقطة
+
+306
+00:24:46,300 --> 00:24:49,680
+معنى هذه النقطة ان هذه carbon طب يا ال carbon كام
+
+307
+00:24:49,680 --> 00:24:56,830
+رابطة بتعمل اربعة اذا هذهالنقطة عبارة عن CH3 طب
+
+308
+00:24:56,830 --> 00:25:00,230
+هذه النقطة التانية عاملة رابطتين إذن هي عبارة عن
+
+309
+00:25:00,230 --> 00:25:03,350
+CH2 يعني كأن أنا أنا مختصر أتشين هاي معناه
+
+310
+00:25:03,350 --> 00:25:07,490
+abbreviated يعني أنه شكل مختصر هذه النقطة برضه
+
+311
+00:25:07,490 --> 00:25:11,390
+معناها CH2 لإنه رابطتين إذن أكيد في two hydrogens
+
+312
+00:25:11,390 --> 00:25:15,340
+ممكن أدول أو يكونوا مضحو يعني أنا حاطيتهم هناالان
+
+313
+00:25:15,340 --> 00:25:18,660
+في الـ Organic Chemistry احنا احب الأشكال اللي لنا
+
+314
+00:25:18,660 --> 00:25:22,420
+اللي هو هذا الشكل الوسطاني الشكل المختصر وبنصير
+
+315
+00:25:22,420 --> 00:25:27,080
+متعودين نعرف انه كل رأس عندنا يمثل Carbon ودائما
+
+316
+00:25:27,080 --> 00:25:31,500
+وابدا منكمل ال Hydrogen بحيث يكون عدد الذرات على
+
+317
+00:25:31,500 --> 00:25:37,250
+Carbon أربعة مثلا لو بدعم المركبcyclopentane يعني
+
+318
+00:25:37,250 --> 00:25:42,190
+في حلقاء من خمس درات carbon لو بتحطه بالشكل غير
+
+319
+00:25:42,190 --> 00:25:47,510
+المختصر بتقول CH2 CH2 CH2 CH2 CH2 وصيغته العامة
+
+320
+00:25:47,510 --> 00:25:52,590
+C5H10 لكن أنا لما بتعمله بالشكل المختصر بحطه بهذا
+
+321
+00:25:52,590 --> 00:25:57,830
+الشكل الآن كل رأس يمثل carbon فلو سألتهذا الشكل
+
+322
+00:25:57,830 --> 00:26:02,330
+كام carbon في واحد تانين تلاتة أربعة خمسة إذا نادى
+
+323
+00:26:02,330 --> 00:26:06,510
+خمسة carbons طب وين ال hydrogens كل carbon بزام
+
+324
+00:26:06,510 --> 00:26:09,990
+عاملة رابطتين إذا بنكمل عليها هيدروجينتين فكأنه
+
+325
+00:26:09,990 --> 00:26:13,830
+هذه CH2 حاملة هيدروجنتين وهذه CH2 حاملة هيدروجنتين
+
+326
+00:26:13,830 --> 00:26:17,510
+وهذه CH2 حاملة هيدروجنتين وهكذا فبتصير الصيغة
+
+327
+00:26:17,510 --> 00:26:24,060
+العامة C5H10زي ما قلت أكثر شكل إحنا هنستعمله في
+
+328
+00:26:24,060 --> 00:26:28,360
+أثناء دراستنا اللي هو الشكل المختصر اللي بنحط رؤوس
+
+329
+00:26:28,360 --> 00:26:33,240
+هذه الرؤوس تمثل الـCarbons هذه الرؤوس تمثل
+
+330
+00:26:33,240 --> 00:26:36,860
+الـCarbons ودائما بنفترض أن أي شيء غير موجود هو
+
+331
+00:26:36,860 --> 00:26:42,160
+عبارة عن Hydrogen آخر
+
+332
+00:26:42,160 --> 00:26:50,090
+شغلة في المحاضرة التقديمية المختصرة اليوم أنهأخدنا
+
+333
+00:26:50,090 --> 00:26:54,230
+شيء اسمه Formal Charges أو الشحنات الظاهرية اللى
+
+334
+00:26:54,230 --> 00:26:57,830
+موجودة على العناصر لما احنا بنعمل organic
+
+335
+00:26:57,830 --> 00:27:01,570
+structure كل ذرة بيكون عليها شحنة هذه الشحنة
+
+336
+00:27:01,570 --> 00:27:05,570
+بنسميها Formal Charge ال Formal Charge بشكل عام
+
+337
+00:27:05,570 --> 00:27:09,070
+بتساوي ال Valence Electrons عدد الإلكترونات
+
+338
+00:27:09,070 --> 00:27:14,050
+الخارجية للعنصر طبعا البعض اللى مابيعرفشماذا يعني
+
+339
+00:27:14,050 --> 00:27:17,730
+Valence Electrons؟ نحن نقول Valence Electrons هو
+
+340
+00:27:17,730 --> 00:27:23,790
+رقم المجموعة Valence Electrons هو رقم المجموعة
+
+341
+00:27:23,790 --> 00:27:28,090
+يعني لو رجعنا للجدول اللي مارمعناه قبل شوية ولو
+
+342
+00:27:28,090 --> 00:27:32,510
+كان جدول للسالبية لاحظوا ان Valence Electrons في
+
+343
+00:27:32,510 --> 00:27:36,550
+المجموعة الأولى زي الهيدروجين واحد البريليام اتنين
+
+344
+00:27:36,550 --> 00:27:40,220
+البرون تلاتةلو بد الـ valence electrons للكربون
+
+345
+00:27:40,220 --> 00:27:45,000
+أربعة رقم المجموعة للنيتروجين خمسة رقم المجموعة
+
+346
+00:27:45,000 --> 00:27:50,080
+للأكسجين والسلفر ستة للهالوجين فلوري كلوري بروم
+
+347
+00:27:50,080 --> 00:27:55,540
+يود سبعة فالـ valence electrons هي رقم المجموعة
+
+348
+00:27:55,540 --> 00:28:01,000
+بنطرح منها عدد الروابط اللي متصلة بهذه النقطة
+
+349
+00:28:01,000 --> 00:28:04,680
+المحددة أو الذرع المحددة زاد عدد الإلكترونات اللي
+
+350
+00:28:04,680 --> 00:28:09,490
+محمولين على الذرعكمثال مثلًا هنا في عندنا
+
+351
+00:28:09,490 --> 00:28:14,650
+الكربونات انايون هذه الكربون عاملة رابطة 2 3 4 لو
+
+352
+00:28:14,650 --> 00:28:18,010
+قلت ايش ال formal charge عليها الكربون في المجموعة
+
+353
+00:28:18,010 --> 00:28:23,250
+الرابعة فبقول أربعة ناقص كام رابطة 1 2 3 4 ناقص
+
+354
+00:28:23,250 --> 00:28:27,370
+أربعة ناقص كام إلكترون إذا أنا هنا بتطلع مافيش على
+
+355
+00:28:27,370 --> 00:28:30,750
+الكربون إلكترونات حسب اللي هو ال structure فبتكون
+
+356
+00:28:30,750 --> 00:28:37,510
+هذه الكربون أربعة ناقص أربعة ناقص سفر بتصفى سفرلو
+
+357
+00:28:37,510 --> 00:28:40,290
+بدي اجي أطلع على الـ Oxygen اللي هنا، الـ Oxygen
+
+358
+00:28:40,290 --> 00:28:44,410
+في المجموعة السادسة، فالـ Formal Charge تبعتها 6
+
+359
+00:28:44,410 --> 00:28:50,350
+ناقص كام رابطة؟ 2، ناقص كام إلكترون؟ 1، 2، 3، 4،
+
+360
+00:28:50,350 --> 00:28:56,260
+6، ناقص 2، ناقص 4، بتكون 0هنا الـ Oxygen هذه اللي
+
+361
+00:28:56,260 --> 00:29:01,440
+مرسومة بشكل آخر هنقول برضه ستة ناقص كام رابطة واحد
+
+362
+00:29:01,440 --> 00:29:06,000
+ناقص كام إلكترون ستة ستة ناقص رابطة ناقص ست
+
+363
+00:29:06,000 --> 00:29:10,780
+إلكترونات بتكون minus one بناء على ذلك هذه minus
+
+364
+00:29:10,780 --> 00:29:14,300
+one وهذه ال Oxygen زي minus one طبعا كلنا عارفين
+
+365
+00:29:14,300 --> 00:29:20,200
+أن آيون الكربونيت بيكون minus two CO3الان ايش
+
+366
+00:29:20,200 --> 00:29:22,900
+فادتني ال formal charge؟ ال formal charge بتقوللي
+
+367
+00:29:22,900 --> 00:29:26,840
+ان الشحنتين السلبات اللي على ايون الكربون مع ال
+
+368
+00:29:26,840 --> 00:29:30,600
+oxygen و ال oxygen طبعا احنا ممكن نعمل resonance
+
+369
+00:29:30,600 --> 00:29:34,700
+structure يعني لو حركنا زوج إلكترونية بتصير double
+
+370
+00:29:34,700 --> 00:29:38,620
+bond و حركنا هذه بتصير ال O minus هنا و minus هنا
+
+371
+00:29:39,570 --> 00:29:43,810
+لو افترضنا التحريك من هنا وهذه صارت نيوتر، لكن ما
+
+372
+00:29:43,810 --> 00:29:47,970
+زال عندي minus، الآن لو عملنا كمان تحريك زوج
+
+373
+00:29:47,970 --> 00:29:51,770
+إلكترونات بهذا الشكل وزوج إلكترونات بهذا الشكل،
+
+374
+00:29:51,770 --> 00:29:55,390
+بيصير ال minus و ال minus هنا، لاحظوا معنى أنه
+
+375
+00:29:55,390 --> 00:29:59,830
+احنا هنا لما بنعمل resonance structuresبنعبّر عنها
+
+376
+00:29:59,830 --> 00:30:09,130
+بسهم له رأسين بنسميه double headed arrow وهو
+
+377
+00:30:09,130 --> 00:30:13,410
+يمثل حركة إلكترونات يعني الفرق بين هذا الشكل اللي
+
+378
+00:30:13,410 --> 00:30:18,000
+هو ال resonance structureوهذا الشكل هو فقط ان زوج
+
+379
+00:30:18,000 --> 00:30:22,000
+الالكترونات هذا اتحرك بهذا الشكل وهذا اتحمل على
+
+380
+00:30:22,000 --> 00:30:25,440
+الاكسجين او زوج الالكترونات هذا اتحرك بهذا الشكل
+
+381
+00:30:25,440 --> 00:30:29,620
+وهذا اتحمل على الاكسجين فمافيش عندى انا اطلاقا نقص
+
+382
+00:30:29,620 --> 00:30:34,140
+او زيادة في ازواج الالكترونات لكن حقيقة اللى موجود
+
+383
+00:30:34,140 --> 00:30:39,440
+عندى حركة الالكتروناتفالـ resonance بيصير or
+
+384
+00:30:39,440 --> 00:30:42,540
+resonance arises whenever we can write two or more
+
+385
+00:30:42,540 --> 00:30:45,420
+structures for a molecule with different
+
+386
+00:30:45,420 --> 00:30:48,500
+arrangement of electrons but identical arrangement
+
+387
+00:30:48,500 --> 00:30:52,120
+of atoms لاحظوا مهم كتير نعرف إيش معناه resonance
+
+388
+00:30:52,120 --> 00:30:56,180
+الذرات carbon و تلاتة oxygen ماتغيروش ولا تغير
+
+389
+00:30:56,180 --> 00:31:01,400
+مواقعهم بس اللي بتغير الإلكترونات اللي حواليهمهنا
+
+390
+00:31:01,400 --> 00:31:04,800
+كانوا الالكترونات بشكل اخر وهنا الالكترونات بشكل
+
+391
+00:31:04,800 --> 00:31:08,340
+ثاني وهنا الالكترونات بشكل تالت فلو قلنا ان ال
+
+392
+00:31:08,340 --> 00:31:12,840
+resonance فيه تغير في ال atoms لأ الذرات زي ما هما
+
+393
+00:31:12,840 --> 00:31:19,800
+ايش فيه تغير فيه ترتيبالإلكترونات وبشكل عام ال
+
+394
+00:31:19,800 --> 00:31:24,160
+resonance بنعبر عنه بهذا السهم اللي بنسميه double
+
+395
+00:31:24,160 --> 00:31:28,940
+headed arrows هذا الكلام بيقودنا إلى نقطة أن
+
+396
+00:31:28,940 --> 00:31:34,070
+الأسهم في ال organ ال chemistry لها معنىوبتلاحظوا
+
+397
+00:31:34,070 --> 00:31:38,630
+أن عندي أنواع كثيرة من الأسهم مثلا هذا السهم
+
+398
+00:31:38,630 --> 00:31:42,630
+العادل اللي احنا متعودين عليه اسمه straight arrow
+
+399
+00:31:42,630 --> 00:31:45,970
+هذا الـ straight arrow بنعبر فيه عن ال reaction
+
+400
+00:31:45,970 --> 00:31:49,530
+يعني هنا بيكون متفاعلات نواتج بنحط straight arrow
+
+401
+00:31:49,530 --> 00:31:54,970
+في السهمين اللي بيكونوا فوق فوق بعض هدولة pair of
+
+402
+00:31:54,970 --> 00:31:59,550
+straight arrowswith half heads كل سام بيكون عليه
+
+403
+00:31:59,550 --> 00:32:05,630
+نص راس هذا بنعبر فيه عن تفاعلات الإتزان لما يكون
+
+404
+00:32:05,630 --> 00:32:09,870
+عنده تفاعل فيه اتزان بعد نهاية التفاعل موجودة
+
+405
+00:32:09,870 --> 00:32:15,850
+المتفاعلات وموجودة النواتج بنعبر بال pair of
+
+406
+00:32:15,850 --> 00:32:20,410
+straight arrowsالسهم التالت اللي يتولس عمال اللي
+
+407
+00:32:20,410 --> 00:32:24,470
+بنحكي عنه اللي هو الـ Double Headed Strait أو
+
+408
+00:32:24,470 --> 00:32:29,910
+السهم برأسين هذا بنعبر فيه عن الـ Resonance اللي
+
+409
+00:32:29,910 --> 00:32:35,150
+هو فقط عملية تحرك إلكتروناتيالسهم اللى بيكون سهم
+
+410
+00:32:35,150 --> 00:32:39,870
+عادي لكن مائل بنسميه curved arrow هذا يعبر عن حركة
+
+411
+00:32:39,870 --> 00:32:43,630
+زوج من الإلكترونات يعني لما بقول هذا زوج
+
+412
+00:32:43,630 --> 00:32:47,790
+الإلكترونات تتحرك من هان لهان بعبر باستخدام هذا
+
+413
+00:32:47,790 --> 00:32:54,930
+السهم في عندى سهمبكون بس بـ half head يعني بنص رأس
+
+414
+00:32:54,930 --> 00:32:58,690
+وعشان هيك بنسميه fish hook يعني سهم زي السنارة
+
+415
+00:32:58,690 --> 00:33:02,990
+يعني هنا بس فيه نص رأس زي السنارة اللي بنصيد فيها
+
+416
+00:33:02,990 --> 00:33:08,770
+السمك فال fish hook arrow اللي هو سهم السنارة اللي
+
+417
+00:33:08,770 --> 00:33:13,550
+فيه half head نص رأس هذا بيعبر عن movement of one
+
+418
+00:33:13,550 --> 00:33:17,740
+electronلاحظوا الفرق بين الـ Curved Arrow اللي
+
+419
+00:33:17,740 --> 00:33:22,340
+مبين فيه رأسين يعبر عن حركة إلكترونين الـ Fish
+
+420
+00:33:22,340 --> 00:33:28,120
+Hook مبين فيه رأس واحد يعبر عن حركة إلكترون واحد
+
+421
+00:33:28,120 --> 00:33:31,700
+مثلا لو تخيلنا أنه عندنا رابطة، الرابطة متكونة
+
+422
+00:33:31,700 --> 00:33:35,340
+بشكل عام من إلكترونين بدا أكسرهم بحيث إلكترون يروح
+
+423
+00:33:35,340 --> 00:33:40,450
+على مجموعة مثل هذه وإلكترون على مجموعة مثل هذهالان
+
+424
+00:33:40,450 --> 00:33:44,090
+انا انا بحرك electron و بحرك electron فبستعمل ال
+
+425
+00:33:44,090 --> 00:33:48,890
+fish hook arrow و ال fish hook arrow فبيعطيني مثلا
+
+426
+00:33:48,890 --> 00:33:53,610
+two methyl groups حاملين one electron كل مجموعة
+
+427
+00:33:53,610 --> 00:33:57,450
+مثل منهم هذا اللي هو استعمال ال fish hook arrow
+
+428
+00:33:57,450 --> 00:34:02,750
+ابهيك بنكون انهينا الجزء الأول من العرض التقديمي
+
+429
+00:34:02,750 --> 00:34:06,890
+أو التذكيري لمساق ال organ chemistry و بنكمل ان
+
+430
+00:34:06,890 --> 00:34:08,850
+شاء الله في المرة القادمة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..0ac62fae78065956f44e8a845532cae4a937a56c
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3588, "start": 10.44, "end": 35.88, "text": "اليوم ان شاء الله بدنا نستمر في الفصل السادس اللى كان عنوانه و أعطينا فيه مقدمة صغيرة إذا بتذكروا Alkyl Halides طبعا بتذكروا نقولنا ال Alkyl Halides المركبات اللى هم R X وال X عبارة عن Halogen, Chlor, Brom, Mute, Fluor هذه المركبات هناخد إليها", "tokens": [6027, 1829, 20498, 16472, 13412, 16606, 21984, 47525, 8315, 8717, 14851, 29973, 8978, 27188, 36520, 21136, 18513, 3794, 13672, 7578, 25961, 18871, 2407, 7649, 3224, 4032, 5551, 3615, 9566, 1829, 8315, 8978, 3224, 3714, 28543, 46007, 20328, 17082, 48923, 11933, 15730, 39894, 8848, 37983, 14407, 967, 4133, 75, 13896, 1875, 23032, 3555, 3615, 995, 39894, 8848, 37983, 14407, 8717, 39648, 8315, 2423, 967, 4133, 75, 13896, 1875, 9673, 31747, 3555, 9307, 13672, 7578, 8032, 2304, 497, 1783, 16070, 1783, 6225, 3555, 9640, 3660, 18871, 13896, 8799, 11, 761, 6746, 11, 1603, 298, 11, 376, 1169, 11, 33612, 284, 29538, 9673, 31747, 3555, 9307, 8032, 1863, 47283, 3215, 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"end": 136.3, "word": " ما", "probability": 0.33251953125}, {"start": 136.3, "end": 136.8, "word": " بتحسوش", "probability": 0.9109375}, {"start": 136.8, "end": 137.24, "word": " أنه", "probability": 0.81689453125}, {"start": 137.24, "end": 138.12, "word": " في", "probability": 0.953125}, {"start": 138.12, "end": 138.86, "word": " مشاكل", "probability": 0.9734700520833334}], "temperature": 1.0}, {"id": 6, "seek": 15526, "start": 140.2, "end": 155.26, "text": "الان هنبدأ درسنا الجديد اللى بنسميه احنا ال nucleophilic substitution in general ان اللى بده يهاجم على ال RX لازم يكون nucleophile", "tokens": [6027, 7649, 8032, 1863, 44510, 10721, 11778, 2288, 3794, 8315, 25724, 16254, 3215, 13672, 7578, 44945, 38251, 1829, 3224, 1975, 5016, 8315, 2423, 14962, 5317, 388, 299, 35827, 294, 2674, 16472, 13672, 7578, 47525, 3224, 7251, 3224, 26108, 2304, 15844, 2423, 46197, 5296, 31377, 2304, 7251, 30544, 14962, 49242], "avg_logprob": -0.24515625357627868, "compression_ratio": 1.3310344827586207, "no_speech_prob": 0.0, "words": [{"start": 140.2, "end": 140.98, "word": "الان", "probability": 0.814208984375}, {"start": 140.98, "end": 141.84, "word": " هنبدأ", "probability": 0.9129638671875}, {"start": 141.84, "end": 142.86, "word": " درسنا", "probability": 0.9063720703125}, {"start": 142.86, "end": 143.68, "word": " الجديد", "probability": 0.91845703125}, {"start": 143.68, "end": 144.14, "word": " اللى", "probability": 0.769775390625}, {"start": 144.14, "end": 144.76, "word": " بنسميه", "probability": 0.8848876953125}, {"start": 144.76, "end": 145.02, "word": " احنا", "probability": 0.7589518229166666}, {"start": 145.02, "end": 145.32, "word": " ال", "probability": 0.82763671875}, {"start": 145.32, "end": 146.2, "word": " nucleophilic", "probability": 0.7048263549804688}, {"start": 146.2, "end": 147.2, "word": " substitution", "probability": 0.91748046875}, {"start": 147.2, "end": 147.56, "word": " in", "probability": 0.8525390625}, {"start": 147.56, "end": 148.16, "word": " general", "probability": 0.9375}, {"start": 148.16, "end": 149.04, "word": " ان", "probability": 0.3486328125}, {"start": 149.04, "end": 149.84, "word": " اللى", "probability": 0.93310546875}, {"start": 149.84, "end": 150.18, "word": " بده", "probability": 0.7158203125}, {"start": 150.18, "end": 151.1, "word": " يهاجم", "probability": 0.980224609375}, {"start": 151.1, "end": 151.82, "word": " على", "probability": 0.6640625}, {"start": 151.82, "end": 152.0, "word": " ال", "probability": 0.94287109375}, {"start": 152.0, "end": 152.8, "word": " RX", "probability": 0.48583984375}, {"start": 152.8, "end": 153.6, "word": " لازم", "probability": 0.97998046875}, {"start": 153.6, "end": 154.1, "word": " يكون", "probability": 0.993408203125}, {"start": 154.1, "end": 155.26, "word": " nucleophile", "probability": 0.5882568359375}], "temperature": 1.0}, {"id": 7, "seek": 17421, "start": 155.89, "end": 174.21, "text": "سبق انه ربما عرفنا اشي اللي بنقصده احنا بال New Cleophile اللي هو عبارة عن Species او اشهر اما بيحمل شحنة سالبة او إلكترونات في كل الأحوال لازم يكون عليه أزواج من الإلكترونات يعني هو يمثل", "tokens": [35457, 4587, 16472, 3224, 12602, 3555, 15042, 6225, 28480, 8315, 1975, 8592, 1829, 13672, 1829, 44945, 4587, 9381, 3215, 3224, 1975, 5016, 8315, 20666, 1873, 8834, 49242, 13672, 1829, 31439, 6225, 3555, 9640, 3660, 18871, 3550, 4629, 1975, 2407, 1975, 8592, 3224, 2288, 1975, 15042, 4724, 1829, 35571, 1211, 13412, 5016, 1863, 3660, 8608, 6027, 49401, 1975, 2407, 11933, 23275, 2655, 2288, 11536, 9307, 8978, 28242, 16247, 5016, 2407, 6027, 5296, 31377, 2304, 7251, 30544, 47356, 5551, 11622, 2407, 26108, 9154, 33688, 23275, 2655, 2288, 11536, 9307, 37495, 22653, 31439, 7251, 2304, 12984, 1211], "avg_logprob": -0.1776315798884944, "compression_ratio": 1.6161616161616161, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 155.89, "end": 156.41, "word": "سبق", "probability": 0.694091796875}, {"start": 156.41, "end": 156.97, "word": " انه", "probability": 0.7047119140625}, {"start": 156.97, "end": 157.55, "word": " ربما", "probability": 0.9527994791666666}, {"start": 157.55, "end": 158.15, "word": " عرفنا", "probability": 0.8889973958333334}, {"start": 158.15, "end": 158.43, "word": " اشي", "probability": 0.6090494791666666}, {"start": 158.43, "end": 158.51, "word": " اللي", "probability": 0.806396484375}, {"start": 158.51, "end": 159.17, "word": " بنقصده", "probability": 0.92490234375}, {"start": 159.17, "end": 159.39, "word": " احنا", "probability": 0.9482421875}, {"start": 159.39, "end": 159.59, "word": " بال", "probability": 0.53955078125}, {"start": 159.59, "end": 159.81, "word": " New", "probability": 0.181640625}, {"start": 159.81, "end": 160.57, "word": " Cleophile", "probability": 0.525390625}, {"start": 160.57, "end": 161.39, "word": " اللي", "probability": 0.91552734375}, {"start": 161.39, "end": 161.61, "word": " هو", "probability": 0.98046875}, {"start": 161.61, "end": 162.05, "word": " عبارة", "probability": 0.9898681640625}, {"start": 162.05, "end": 162.27, "word": " عن", "probability": 0.98486328125}, {"start": 162.27, "end": 162.99, "word": " Species", "probability": 0.6337890625}, {"start": 162.99, "end": 163.35, "word": " او", "probability": 0.92041015625}, {"start": 163.35, "end": 164.39, "word": " اشهر", "probability": 0.77783203125}, {"start": 164.39, "end": 164.79, "word": " اما", "probability": 0.893310546875}, {"start": 164.79, "end": 166.13, "word": " بيحمل", "probability": 0.9869384765625}, {"start": 166.13, "end": 167.07, "word": " شحنة", "probability": 0.9185791015625}, {"start": 167.07, "end": 167.55, "word": " سالبة", "probability": 0.9134114583333334}, {"start": 167.55, "end": 168.07, "word": " او", "probability": 0.93359375}, {"start": 168.07, "end": 169.33, "word": " إلكترونات", "probability": 0.7992960611979166}, {"start": 169.33, "end": 169.47, "word": " في", "probability": 0.44384765625}, {"start": 169.47, "end": 169.67, "word": " كل", "probability": 0.98486328125}, {"start": 169.67, "end": 170.13, "word": " الأحوال", "probability": 0.9583740234375}, {"start": 170.13, "end": 170.45, "word": " لازم", "probability": 0.9851888020833334}, {"start": 170.45, "end": 170.71, "word": " يكون", "probability": 0.9931640625}, {"start": 170.71, "end": 170.99, "word": " عليه", "probability": 0.9755859375}, {"start": 170.99, "end": 171.69, "word": " أزواج", "probability": 0.9312744140625}, {"start": 171.69, "end": 172.01, "word": " من", "probability": 0.99365234375}, {"start": 172.01, "end": 173.09, "word": " الإلكترونات", "probability": 0.95166015625}, {"start": 173.09, "end": 173.27, "word": " يعني", "probability": 0.82373046875}, {"start": 173.27, "end": 173.45, "word": " هو", "probability": 0.95556640625}, {"start": 173.45, "end": 174.21, "word": " يمثل", "probability": 0.9918212890625}], "temperature": 1.0}, {"id": 8, "seek": 19749, "start": 175.11, "end": 197.49, "text": "كثافة إلكترونية يمكن هذا الـ nucleophile أن يكون مشحون يعني تظهر عليه الشحنة السالبة ويمكن أن يكون متعادل لو بدنا ناخد أمثلة مثلا ال OH- هذا الشكل تبعها ال structure لل OH- فبتلاحظوا هنا إيش بتكون", "tokens": [4117, 12984, 31845, 3660, 11933, 23275, 2655, 2288, 11536, 10632, 7251, 43020, 23758, 2423, 39184, 14962, 49242, 14739, 7251, 30544, 37893, 5016, 11536, 37495, 22653, 6055, 19913, 3224, 2288, 47356, 25124, 5016, 1863, 3660, 21136, 6027, 49401, 4032, 32640, 19452, 14739, 7251, 30544, 44650, 3615, 18513, 1211, 45164, 47525, 8315, 8717, 47283, 3215, 5551, 2304, 12984, 37977, 50113, 15040, 2423, 13931, 12, 23758, 25124, 28820, 6055, 3555, 3615, 11296, 2423, 3877, 24976, 13931, 12, 6156, 3555, 2655, 15040, 5016, 19913, 14407, 34105, 11933, 1829, 8592, 39894, 30544], "avg_logprob": -0.18767756020480936, "compression_ratio": 1.6067961165048543, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 175.11, "end": 176.07, "word": "كثافة", "probability": 0.81536865234375}, {"start": 176.07, "end": 177.51, "word": " إلكترونية", "probability": 0.917724609375}, 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{"start": 185.69, "end": 186.55, "word": " ويمكن", "probability": 0.8756510416666666}, {"start": 186.55, "end": 186.75, "word": " أن", "probability": 0.8984375}, {"start": 186.75, "end": 187.13, "word": " يكون", "probability": 0.984619140625}, {"start": 187.13, "end": 187.95, "word": " متعادل", "probability": 0.877197265625}, {"start": 187.95, "end": 188.43, "word": " لو", "probability": 0.8505859375}, {"start": 188.43, "end": 188.67, "word": " بدنا", "probability": 0.9306640625}, {"start": 188.67, "end": 189.01, "word": " ناخد", "probability": 0.9894205729166666}, {"start": 189.01, "end": 189.65, "word": " أمثلة", "probability": 0.9576416015625}, {"start": 189.65, "end": 190.45, "word": " مثلا", "probability": 0.94384765625}, {"start": 190.45, "end": 190.65, "word": " ال", "probability": 0.80810546875}, {"start": 190.65, "end": 190.97, "word": " OH", "probability": 0.32763671875}, {"start": 190.97, "end": 191.77, "word": "-", "probability": 0.401611328125}, {"start": 191.77, "end": 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"start": 198.68, "end": 218.24, "text": "مشحونة تظهر عليها شحنة سالبة ويوجد على الأكسجين عدة أزواج من الإلكترونات لما بتم التفاعل بتم التفاعل من خلال الهجوم من أزواج الإلكترونات كذلك الحالة لو بتقطل على ال CN- برضه بتكون", "tokens": [2304, 8592, 5016, 11536, 3660, 6055, 19913, 3224, 2288, 25894, 11296, 13412, 5016, 1863, 3660, 8608, 6027, 49401, 4032, 1829, 29245, 3215, 15844, 16247, 4117, 3794, 7435, 9957, 6225, 41891, 5551, 11622, 2407, 26108, 9154, 33688, 23275, 2655, 2288, 11536, 9307, 5296, 15042, 4724, 39237, 16712, 5172, 995, 30241, 4724, 39237, 16712, 5172, 995, 30241, 9154, 16490, 1211, 6027, 2423, 3224, 7435, 20498, 9154, 5551, 11622, 2407, 26108, 33688, 23275, 2655, 2288, 11536, 9307, 9122, 8848, 23275, 2423, 5016, 6027, 3660, 45164, 39894, 47432, 1211, 15844, 2423, 14589, 12, 4724, 43042, 3224, 39894, 30544], "avg_logprob": -0.2120065748691559, "compression_ratio": 1.894736842105263, "no_speech_prob": 1.9669532775878906e-06, "words": [{"start": 198.68, "end": 199.56, "word": "مشحونة", "probability": 0.758740234375}, {"start": 199.56, "end": 200.5, "word": " تظهر", "probability": 0.9400634765625}, {"start": 200.5, "end": 200.8, "word": " عليها", "probability": 0.976806640625}, {"start": 200.8, "end": 201.26, "word": " شحنة", "probability": 0.943115234375}, {"start": 201.26, "end": 201.84, "word": " سالبة", "probability": 0.8889973958333334}, {"start": 201.84, "end": 203.42, "word": " ويوجد", "probability": 0.8416748046875}, {"start": 203.42, "end": 203.66, "word": " على", "probability": 0.74072265625}, {"start": 203.66, "end": 204.42, "word": " الأكسجين", "probability": 0.84794921875}, {"start": 204.42, "end": 204.78, "word": " عدة", "probability": 0.931396484375}, {"start": 204.78, "end": 205.34, "word": " أزواج", "probability": 0.9671630859375}, {"start": 205.34, "end": 205.52, "word": " من", "probability": 0.98095703125}, {"start": 205.52, "end": 206.42, "word": " الإلكترونات", "probability": 0.8573404947916666}, {"start": 206.42, "end": 206.94, "word": " لما", "probability": 0.77880859375}, {"start": 206.94, "end": 207.28, "word": " بتم", "probability": 0.51678466796875}, {"start": 207.28, "end": 207.9, "word": " التفاعل", "probability": 0.951416015625}, {"start": 207.9, "end": 208.2, "word": " بتم", "probability": 0.58367919921875}, {"start": 208.2, "end": 208.8, "word": " التفاعل", "probability": 0.9420166015625}, {"start": 208.8, "end": 208.96, "word": " من", "probability": 0.9931640625}, {"start": 208.96, "end": 209.54, "word": " خلال", "probability": 0.9903971354166666}, {"start": 209.54, "end": 210.58, "word": " الهجوم", "probability": 0.9293212890625}, {"start": 210.58, "end": 210.84, "word": " من", "probability": 0.98876953125}, {"start": 210.84, "end": 211.46, "word": " أزواج", "probability": 0.9595947265625}, {"start": 211.46, "end": 212.7, "word": " الإلكترونات", "probability": 0.9524739583333334}, {"start": 212.7, "end": 214.14, "word": " كذلك", "probability": 0.9625651041666666}, {"start": 214.14, "end": 214.64, 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هي ال substitution إشي بيحقق المحل إشي بناء على ذلك النتج هنا إيش متوقع يصير R C triple bond C وهنا CH3 شوفتوا كيف عملية ال substitution", "tokens": [3555, 1863, 15040, 5016, 19913, 9957, 9122, 33911, 16712, 5172, 995, 30241, 39896, 2423, 35827, 11933, 8592, 1829, 4724, 1829, 5016, 4587, 4587, 9673, 5016, 1211, 11933, 8592, 1829, 44945, 16606, 15844, 29910, 23275, 28239, 2655, 7435, 34105, 11933, 1829, 8592, 44650, 30543, 3615, 7251, 9381, 13546, 497, 383, 15508, 6086, 383, 37037, 8315, 5995, 18, 13412, 38688, 2655, 14407, 9122, 33911, 6225, 42213, 10632, 2423, 35827], "avg_logprob": -0.2787224159521215, "compression_ratio": 1.432748538011696, "no_speech_prob": 0.0, "words": [{"start": 1191.09, "end": 1191.69, "word": "بنلاحظين", "probability": 0.6928914388020834}, {"start": 1191.69, "end": 1191.89, "word": " كيف", "probability": 0.957275390625}, {"start": 1191.89, "end": 1192.33, "word": " التفاعل", "probability": 0.816650390625}, {"start": 1192.33, "end": 1192.51, "word": " هي", 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بنعملهان انه ال nuclear file بها .. الان بدياكوا تنتبهوا لشغلة احنا عامال مرات بنعطيكم ال nuclear file اقوى الشارع", "tokens": [5172, 1211, 10721, 1829, 36764, 24401, 9154, 8032, 3215, 12610, 2423, 8179, 7098, 45164, 12174, 12610, 8315, 23275, 14407, 1975, 24793, 1211, 14407, 9673, 3615, 18513, 37977, 6055, 4587, 16572, 3555, 995, 4724, 8592, 28820, 13412, 21292, 3224, 8978, 13672, 1829, 1975, 5016, 8315, 44945, 25957, 43761, 7649, 16472, 3224, 2423, 8179, 3991, 4724, 11296, 4386, 2423, 7649, 47525, 25528, 4117, 14407, 6055, 29399, 3555, 3224, 14407, 5296, 8592, 17082, 37977, 1975, 5016, 8315, 6225, 10943, 6027, 3714, 2288, 9307, 44945, 3615, 9566, 1829, 24793, 2423, 8179, 3991, 1975, 4587, 2407, 7578, 25124, 9640, 3615], "avg_logprob": -0.21337890919918814, "compression_ratio": 1.72, "no_speech_prob": 0.0, "words": [{"start": 1237.7, "end": 1238.62, "word": "فلأي", "probability": 0.7763671875}, {"start": 1238.62, "end": 1239.02, "word": " واحد", "probability": 0.994140625}, {"start": 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1292.36, "text": "المراتب اللي أعطيكم بيها بكل بيش ال neutral كيف أكتب نتيجة التفاعل، كيف أكتب المعادلة، إذا كان نيكليوفاعل، it's charged", "tokens": [45340, 2288, 9307, 3555, 13672, 1829, 5551, 3615, 9566, 1829, 24793, 4724, 1829, 11296, 4724, 28820, 4724, 1829, 8592, 2423, 10598, 9122, 33911, 5551, 4117, 2655, 3555, 8717, 31371, 7435, 3660, 16712, 5172, 995, 30241, 12399, 9122, 33911, 5551, 4117, 2655, 3555, 9673, 3615, 18513, 37977, 12399, 11933, 15730, 25961, 8717, 1829, 4117, 20292, 38688, 995, 30241, 12399, 309, 311, 11109], "avg_logprob": -0.3434979958880332, "compression_ratio": 1.425531914893617, "no_speech_prob": 5.066394805908203e-06, "words": [{"start": 1267.8, "end": 1268.76, "word": "المراتب", "probability": 0.69134521484375}, {"start": 1268.76, "end": 1268.96, "word": " اللي", "probability": 0.896240234375}, {"start": 1268.96, "end": 1269.58, "word": " أعطيكم", "probability": 0.68447265625}, {"start": 1269.58, "end": 1270.12, "word": " بيها", "probability": 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"probability": 0.891357421875}, {"start": 1287.98, "end": 1288.7, "word": " كان", "probability": 0.99560546875}, {"start": 1288.7, "end": 1291.2, "word": " نيكليوفاعل،", "probability": 0.6137542724609375}, {"start": 1291.2, "end": 1291.66, "word": " it's", "probability": 0.770263671875}, {"start": 1291.66, "end": 1292.36, "word": " charged", "probability": 0.73974609375}], "temperature": 1.0}, {"id": 55, "seek": 131999, "start": 1292.99, "end": 1319.99, "text": "وإذا كان الـ nucleophile الـ neutral كيف بتم التفاعد؟ خلّينا في الأول ناخد الـ charged nucleophile لو أخدنا كان الـ nucleophile الـ OH minus هذه عبارة عن نيجاتيف أنيون ولا لأ؟ ايون سالف هذا الـ OH minus بدو يحل محل", "tokens": [2407, 28814, 15730, 25961, 2423, 39184, 14962, 49242, 2423, 39184, 10598, 9122, 33911, 4724, 39237, 16712, 5172, 995, 22488, 22807, 16490, 1211, 11703, 9957, 995, 8978, 16247, 12610, 8717, 47283, 3215, 2423, 39184, 11109, 14962, 49242, 45164, 5551, 9778, 3215, 8315, 25961, 2423, 39184, 14962, 49242, 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يعني مجمل التفاعل كان هذا الجزء المتعادل مع", "tokens": [6027, 39184, 11568, 3175, 20449, 11933, 23275, 2655, 2288, 11536, 9307, 11296, 34105, 16712, 5172, 995, 30241, 4032, 9122, 2655, 16758, 47395, 4724, 3794, 1829, 9566, 19446, 41185, 8592, 8978, 3224, 36632, 37893, 28820, 3660, 8608, 6027, 3555, 47525, 3224, 7251, 5016, 1211, 3714, 5016, 1211, 8608, 6027, 3555, 13931, 3175, 47525, 3224, 6055, 1829, 7435, 1829, 6055, 5016, 1211, 3714, 5016, 1211, 2423, 11568, 20449, 5551, 11622, 2407, 26108, 33688, 23275, 2655, 2288, 11536, 9307, 6055, 3555, 3615, 11296, 4032, 46958, 5016, 22807, 37495, 22653, 3714, 7435, 42213, 16712, 5172, 995, 30241, 25961, 23758, 25724, 11622, 38207, 9673, 2655, 3615, 18513, 1211, 20449], "avg_logprob": -0.18735118934086392, "compression_ratio": 1.7462686567164178, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1320.94, "end": 1321.32, "word": "الـ", "probability": 0.631591796875}, {"start": 1321.32, "end": 1321.74, "word": " PR", "probability": 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" الميه", "probability": 0.9444986979166666}, {"start": 1676.68, "end": 1677.3, "word": " والـ", "probability": 0.5457763671875}, {"start": 1677.3, "end": 1677.48, "word": " OH", "probability": 0.86767578125}, {"start": 1677.48, "end": 1678.22, "word": " minus", "probability": 0.5400390625}, {"start": 1678.22, "end": 1678.42, "word": " شو", "probability": 0.82470703125}, {"start": 1678.42, "end": 1678.88, "word": " المجموعة", "probability": 0.875341796875}, {"start": 1678.88, "end": 1679.0, "word": " اللي", "probability": 0.882568359375}, {"start": 1679.0, "end": 1679.82, "word": " بيدخلوها؟", "probability": 0.9115513392857143}], "temperature": 1.0}, {"id": 70, "seek": 169576, "start": 1681.72, "end": 1695.76, "text": "كنتج الناتج مابختلفش بمعنى لما افعل انا ال RX مع OH minus ولا ال RX مع H2O الناتج هو ادخال مجموعة ال OH", "tokens": [4117, 29399, 7435, 2423, 8315, 2655, 7435, 3714, 16758, 46456, 46538, 8592, 4724, 2304, 3615, 1863, 7578, 5296, 15042, 1975, 5172, 30241, 1975, 8315, 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"temperature": 1.0}, {"id": 112, "seek": 276079, "start": 2737.43, "end": 2760.79, "text": "first order و لا second order second order ال rate هنا بتساوت تعتمد أخدتوا قوانين ال rate K في تركيز ال nucleophile في تركيز ال RX التانيين دخلين في التفاعل", "tokens": [29581, 1668, 4032, 20193, 1150, 1668, 1150, 1668, 2423, 3314, 34105, 39894, 3794, 995, 35473, 6055, 34268, 2304, 3215, 5551, 9778, 3215, 2655, 14407, 12174, 2407, 7649, 9957, 2423, 3314, 591, 8978, 6055, 31747, 1829, 11622, 2423, 14962, 49242, 8978, 6055, 31747, 1829, 11622, 2423, 46197, 16712, 7649, 1829, 9957, 11778, 9778, 1211, 9957, 8978, 16712, 5172, 995, 30241], "avg_logprob": -0.33385416070620216, "compression_ratio": 1.5165562913907285, "no_speech_prob": 0.0, "words": [{"start": 2737.43, "end": 2737.93, "word": "first", "probability": 0.1761474609375}, {"start": 2737.93, "end": 2738.75, "word": " order", "probability": 0.96044921875}, {"start": 2738.75, "end": 2739.33, "word": " و", "probability": 0.2646484375}, 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alkyl halide إذا عنده strong nucleophile و primary alkyl halide هذه الميكانيزم الأولى، الآن لو مرة تانية بدي ألخص مواصفاتها اللي سمناها إيش احنا؟", "tokens": [28814, 15730, 25961, 43242, 3224, 2068, 14962, 49242, 4032, 6194, 419, 4133, 75, 7523, 482, 11933, 15730, 43242, 3224, 2068, 14962, 49242, 4032, 6194, 419, 4133, 75, 7523, 482, 29538, 9673, 1829, 41361, 1829, 11622, 2304, 16247, 12610, 7578, 12399, 6024, 48506, 45164, 3714, 25720, 6055, 7649, 10632, 4724, 16254, 5551, 1211, 9778, 9381, 3714, 2407, 33546, 5172, 9307, 11296, 13672, 1829, 8608, 2304, 8315, 11296, 11933, 1829, 8592, 1975, 5016, 8315, 22807], "avg_logprob": -0.24704391730798259, "compression_ratio": 1.5930232558139534, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2809.28, "end": 2809.64, "word": "إذا", "probability": 0.6751708984375}, {"start": 2809.64, "end": 2809.94, "word": " كان", "probability": 0.93603515625}, {"start": 2809.94, "end": 2810.32, "word": " عنده", "probability": 0.825927734375}, 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{"start": 2915.5, "end": 2916.52, "word": " اللي", "probability": 0.642333984375}, {"start": 2916.52, "end": 2917.12, "word": " بتتم", "probability": 0.7244873046875}, {"start": 2917.12, "end": 2917.34, "word": " لما", "probability": 0.8515625}, {"start": 2917.34, "end": 2917.64, "word": " يكون", "probability": 0.98291015625}, {"start": 2917.64, "end": 2918.04, "word": " عنده", "probability": 0.6065673828125}, {"start": 2918.04, "end": 2918.36, "word": " strong", "probability": 0.431396484375}, {"start": 2918.36, "end": 2919.42, "word": " nucleophile", "probability": 0.77734375}, {"start": 2919.42, "end": 2919.92, "word": " مع", "probability": 0.927734375}, {"start": 2919.92, "end": 2920.48, "word": " primary", "probability": 0.443115234375}, {"start": 2920.48, "end": 2920.68, "word": " و", "probability": 0.6953125}, {"start": 2920.68, "end": 2921.16, "word": " أحيانا", "probability": 0.90615234375}, {"start": 2921.16, "end": 2921.3, "word": " مع", "probability": 0.955078125}, {"start": 2921.3, "end": 2921.82, "word": " secondary", "probability": 0.9189453125}, {"start": 2921.82, "end": 2922.24, "word": " alkyl", "probability": 0.6650797526041666}, {"start": 2922.24, "end": 2922.62, "word": " halides", "probability": 0.7122802734375}, {"start": 2922.62, "end": 2923.3, "word": " بتتم", "probability": 0.5845947265625}, {"start": 2923.3, "end": 2923.88, "word": " التفاعل", "probability": 0.970703125}, {"start": 2923.88, "end": 2924.02, "word": " ب", "probability": 0.37451171875}, {"start": 2924.02, "end": 2924.22, "word": " one", "probability": 0.43115234375}, {"start": 2924.22, "end": 2924.64, "word": " step", "probability": 0.85888671875}, {"start": 2924.64, "end": 2925.56, "word": " بالتفاعل", "probability": 0.8740234375}, {"start": 2925.56, "end": 2926.42, "word": " داخل", "probability": 0.9671223958333334}, {"start": 2926.42, "end": 2926.58, "word": " في", "probability": 0.861328125}, {"start": 2926.58, "end": 2927.16, "word": " الكائنات", "probability": 0.8155517578125}, {"start": 2927.16, "end": 2927.38, "word": " X", "probability": 0.60498046875}, {"start": 2927.38, "end": 2927.78, "word": " تبعه", "probability": 0.7991943359375}, {"start": 2927.78, "end": 2928.66, "word": " المتفاعلين", "probability": 0.94384765625}, {"start": 2928.66, "end": 2928.86, "word": " لل", "probability": 0.347412109375}, {"start": 2928.86, "end": 2929.58, "word": " nucleophile", "probability": 0.6856689453125}, {"start": 2929.58, "end": 2929.76, "word": " و", "probability": 0.556640625}, {"start": 2929.76, "end": 2929.82, "word": " ال", "probability": 0.462646484375}, {"start": 2929.82, "end": 2930.32, "word": " RX", "probability": 0.61767578125}, {"start": 2930.32, "end": 2930.84, "word": " ل", "probability": 0.79931640625}, {"start": 2930.84, "end": 2931.48, "word": " Transition", "probability": 0.6182861328125}, {"start": 2931.48, "end": 2932.04, "word": " Statement", "probability": 0.75048828125}, {"start": 2932.04, "end": 2932.68, "word": " Avalant", "probability": 0.4906412760416667}, {"start": 2932.68, "end": 2932.82, "word": " ل", "probability": 0.81201171875}, {"start": 2932.82, "end": 2933.82, "word": " Stereochemistry", "probability": 0.8144775390625}, {"start": 2933.82, "end": 2934.58, "word": " Invergent", "probability": 0.8548177083333334}], "temperature": 1.0}, {"id": 120, "seek": 295855, "start": 2935.15, "end": 2958.55, "text": "الان لاحظوا هدول الست مواصفات المحاضرة اللى جاية ان شاء الله لما نحكي على نوع تاني من التفاعلات هنعود نتطلع عليهم كيف بيختلفوا يعني حيصير كإنه عندي جدول مقارنة إن هاي الميكانيزم الأولى، هاي مواصفاتها طب الميكانيزم التانى، إيش مواصفاتها بالنسبة للـ nucleophile، للـ RX؟", "tokens": [6027, 7649, 20193, 5016, 19913, 14407, 8032, 3215, 12610, 2423, 14851, 3714, 2407, 33546, 5172, 9307, 9673, 5016, 46958, 25720, 13672, 7578, 10874, 995, 10632, 16472, 13412, 16606, 21984, 5296, 15042, 8717, 5016, 4117, 1829, 15844, 8717, 45367, 6055, 7649, 1829, 9154, 16712, 5172, 995, 30241, 9307, 8032, 1863, 3615, 23328, 8717, 2655, 9566, 1211, 3615, 25894, 16095, 9122, 33911, 4724, 1829, 46456, 46538, 14407, 37495, 22653, 11331, 1829, 9381, 13546, 9122, 28814, 1863, 3224, 18871, 16254, 10874, 3215, 12610, 3714, 4587, 9640, 1863, 3660, 36145, 8032, 47302, 9673, 1829, 41361, 1829, 11622, 2304, 16247, 12610, 7578, 12399, 8032, 47302, 3714, 2407, 33546, 5172, 9307, 11296, 23032, 3555, 9673, 1829, 41361, 1829, 11622, 2304, 16712, 7649, 7578, 12399, 11933, 1829, 8592, 3714, 2407, 33546, 5172, 9307, 11296, 20666, 1863, 35457, 3660, 24976, 39184, 14962, 49242, 12399, 24976, 39184, 46197, 22807], "avg_logprob": -0.2088874134611576, "compression_ratio": 1.8565891472868217, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2935.15, "end": 2935.53, "word": "الان", "probability": 0.84716796875}, {"start": 2935.53, "end": 2935.97, "word": " لاحظوا", "probability": 0.9805908203125}, {"start": 2935.97, "end": 2936.23, "word": " هدول", "probability": 0.7386067708333334}, {"start": 2936.23, "end": 2936.57, "word": " الست", "probability": 0.5372314453125}, {"start": 2936.57, "end": 2937.45, "word": " مواصفات", "probability": 0.97333984375}, {"start": 2937.45, "end": 2938.65, "word": " المحاضرة", "probability": 0.8507080078125}, {"start": 2938.65, "end": 2938.79, "word": " اللى", "probability": 0.617431640625}, {"start": 2938.79, "end": 2938.99, "word": " جاية", "probability": 0.7921549479166666}, {"start": 2938.99, "end": 2939.11, "word": " ان", "probability": 0.57958984375}, {"start": 2939.11, "end": 2939.25, "word": " شاء", "probability": 0.97705078125}, {"start": 2939.25, "end": 2939.35, "word": " الله", "probability": 0.93994140625}, {"start": 2939.35, "end": 2939.59, "word": " لما", "probability": 0.929443359375}, {"start": 2939.59, "end": 2940.01, "word": " نحكي", "probability": 0.9678955078125}, {"start": 2940.01, "end": 2940.19, "word": " على", "probability": 0.57373046875}, {"start": 2940.19, "end": 2940.55, "word": " نوع", "probability": 0.818603515625}, {"start": 2940.55, "end": 2941.01, "word": " تاني", "probability": 0.8312174479166666}, {"start": 2941.01, "end": 2941.17, "word": " من", "probability": 0.97607421875}, {"start": 2941.17, "end": 2942.09, "word": " التفاعلات", "probability": 0.91435546875}, {"start": 2942.09, "end": 2942.89, "word": " هنعود", "probability": 0.890380859375}, {"start": 2942.89, "end": 2943.43, "word": " نتطلع", "probability": 0.823779296875}, {"start": 2943.43, "end": 2943.77, "word": " عليهم", "probability": 0.98193359375}, {"start": 2943.77, "end": 2944.03, "word": " كيف", "probability": 0.962646484375}, {"start": 2944.03, "end": 2944.87, "word": " بيختلفوا", "probability": 0.949609375}, {"start": 2944.87, "end": 2945.51, "word": " يعني", "probability": 0.763671875}, {"start": 2945.51, "end": 2945.97, "word": " حيصير", "probability": 0.6851806640625}, {"start": 2945.97, "end": 2946.33, "word": " كإنه", "probability": 0.8074951171875}, {"start": 2946.33, "end": 2946.65, "word": " عندي", "probability": 0.81591796875}, {"start": 2946.65, "end": 2947.25, "word": " جدول", "probability": 0.97314453125}, {"start": 2947.25, "end": 2949.05, "word": " مقارنة", "probability": 0.98623046875}, {"start": 2949.05, "end": 2949.55, "word": " إن", "probability": 0.2373046875}, {"start": 2949.55, "end": 2949.77, "word": " هاي", "probability": 0.697265625}, {"start": 2949.77, "end": 2950.45, "word": " الميكانيزم", "probability": 0.8857421875}, {"start": 2950.45, "end": 2951.37, "word": " الأولى،", "probability": 0.8485107421875}, {"start": 2951.37, "end": 2951.53, "word": " هاي", "probability": 0.858642578125}, {"start": 2951.53, "end": 2952.63, "word": " مواصفاتها", "probability": 0.9440104166666666}, {"start": 2952.63, "end": 2953.07, "word": " طب", "probability": 0.75}, {"start": 2953.07, "end": 2953.77, "word": " الميكانيزم", "probability": 0.9654134114583334}, {"start": 2953.77, "end": 2954.27, "word": " التانى،", "probability": 0.62274169921875}, {"start": 2954.27, "end": 2954.47, "word": " إيش", "probability": 0.8479817708333334}, {"start": 2954.47, "end": 2955.21, "word": " مواصفاتها", "probability": 0.9293619791666666}, {"start": 2955.21, "end": 2955.79, "word": " بالنسبة", "probability": 0.9864501953125}, {"start": 2955.79, "end": 2956.25, "word": " للـ", "probability": 0.331787109375}, {"start": 2956.25, "end": 2957.33, "word": " nucleophile،", "probability": 0.5393880208333334}, {"start": 2957.33, "end": 2957.79, "word": " للـ", "probability": 0.857421875}, {"start": 2957.79, "end": 2958.55, "word": " RX؟", "probability": 0.7139892578125}], "temperature": 1.0}, {"id": 121, "seek": 296979, "start": 2958.59, "end": 2969.79, "text": "لل .. ال rate، لل inversion، لل stereo chemistry، لعدد الخطوات، هذا الكلام كله بندرسه المحاضرة الجاية ان شاء الله", "tokens": [1211, 1211, 4386, 2423, 3314, 12399, 24976, 43576, 12399, 24976, 29029, 12558, 12399, 5296, 22488, 3215, 33962, 9566, 2407, 9307, 12399, 23758, 2423, 28820, 10943, 28242, 3224, 44945, 3215, 2288, 3794, 3224, 9673, 5016, 46958, 25720, 25724, 995, 10632, 16472, 13412, 16606, 21984], "avg_logprob": -0.16699218885465103, "compression_ratio": 1.2919708029197081, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2958.59, "end": 2959.29, "word": "لل", "probability": 0.86865234375}, {"start": 2959.29, "end": 2959.29, "word": " ..", "probability": 0.3017578125}, {"start": 2959.29, "end": 2959.79, "word": " ال", "probability": 0.87451171875}, {"start": 2959.79, "end": 2960.69, "word": " rate،", "probability": 0.594482421875}, {"start": 2960.69, "end": 2960.95, "word": " لل", "probability": 0.80078125}, {"start": 2960.95, "end": 2962.17, "word": " inversion،", "probability": 0.84228515625}, {"start": 2962.17, "end": 2962.29, "word": " لل", "probability": 0.70458984375}, {"start": 2962.29, "end": 2962.65, "word": " stereo", "probability": 0.5693359375}, {"start": 2962.65, "end": 2963.45, "word": " chemistry،", "probability": 0.81884765625}, {"start": 2963.45, "end": 2963.87, "word": " لعدد", "probability": 0.97021484375}, {"start": 2963.87, "end": 2964.91, "word": " الخطوات،", "probability": 0.9052734375}, {"start": 2964.91, "end": 2965.09, "word": " هذا", "probability": 0.9599609375}, {"start": 2965.09, "end": 2965.51, "word": " الكلام", "probability": 0.9619140625}, {"start": 2965.51, "end": 2965.79, "word": " كله", "probability": 0.98095703125}, {"start": 2965.79, "end": 2966.57, "word": " بندرسه", "probability": 0.95947265625}, {"start": 2966.57, "end": 2968.41, "word": " المحاضرة", "probability": 0.948974609375}, {"start": 2968.41, "end": 2969.33, "word": " الجاية", "probability": 0.8759765625}, {"start": 2969.33, "end": 2969.49, "word": " ان", "probability": 0.6279296875}, {"start": 2969.49, "end": 2969.69, "word": " شاء", "probability": 0.991943359375}, {"start": 2969.69, "end": 2969.79, "word": " الله", "probability": 0.9580078125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2974.151, "duration_after_vad": 2863.9487499999905}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..da35681e320cab1ae23d240ec7018acb4df5a1dd
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_postprocess.srt
@@ -0,0 +1,1660 @@
+1
+00:00:08,560 --> 00:00:15,180
+بسم الله الرحمن الرحيم اليوم إن شاء الله بتكون
+
+2
+00:00:15,180 --> 00:00:20,020
+المحاضرة الأخيرة في هذا المساق وهي محاضرة سهلة
+
+3
+00:00:20,020 --> 00:00:28,550
+وبسيطة عن بعض تفاعلات ال Amiensطبعا سبق ان اتكلمنا
+
+4
+00:00:28,550 --> 00:00:35,230
+انه يعني شعرة شمشوم الجبار خلينا نقول اللي في ال
+
+5
+00:00:35,230 --> 00:00:42,110
+amines هي إيش زوج الإلكترونات يعني سر ال amines
+
+6
+00:00:42,110 --> 00:00:47,350
+زوج الإلكترونات طالما ال amines زي ما بتلاحظوا
+
+7
+00:00:47,350 --> 00:00:51,390
+مانا فيهم هذا الزوج من الإلكترونات إذا هم ممكن
+
+8
+00:00:51,390 --> 00:00:56,660
+يتفاعلوا can you kill your filesأي تفاعل أخدناه
+
+9
+00:00:56,660 --> 00:01:00,900
+بيلزمه الـ nucleophile الأمين ممكن يتفاعله على
+
+10
+00:01:00,900 --> 00:01:05,200
+سبيل المثال مثلا مع ال acid halides ممكن الأمين
+
+11
+00:01:05,200 --> 00:01:08,380
+ييجي يتفاعل اللي هو تفاعل ال substitution الشهير
+
+12
+00:01:08,380 --> 00:01:15,460
+لأنه هذا acid halide يهاجم بهذا الشكل ويطلط
+
+13
+00:01:16,310 --> 00:01:21,690
+الـ CR يعطينا الأمل الآن طالما الكلام مع الـ Acid
+
+14
+00:01:21,690 --> 00:01:28,770
+Chloride بيمشي إذا بالتأكيد موازقله تماماً لو كان
+
+15
+00:01:28,770 --> 00:01:32,770
+عنده مشتقة زي الـ Acid Chloride وتحديداً الـ E
+
+16
+00:01:32,770 --> 00:01:37,210
+Star أو الـ Anhydride يعني في كل الأحوال لو كانت
+
+17
+00:01:37,210 --> 00:01:41,530
+هذه RC double bond O O-ethyl هيعمل نفس التفاعل
+
+18
+00:01:41,530 --> 00:01:45,870
+ويطرد الـ O-ethyl لو كانت RC double bond OOC
+
+19
+00:01:45,870 --> 00:01:50,270
+double bond OR مثلاً unhydrate هيتفعل بنفس الطريقة
+
+20
+00:01:50,270 --> 00:01:55,070
+وهذا الكلام يعني لما بندرسه احنا بندرسه كتكرار
+
+21
+00:01:55,070 --> 00:01:58,210
+لأنه حقيقة لما خدنا تفاعل ال acid chlorides و
+
+22
+00:01:58,210 --> 00:02:02,990
+الesters و الunhydrates كنا ناخد تفاعلهم مع ال
+
+23
+00:02:02,990 --> 00:02:07,730
+amines تقريبا كل الأمثلة اللي هنا أمثلة متوازية
+
+24
+00:02:07,730 --> 00:02:12,400
+تماماانه في عندى هجوم و substitution انه في عندى
+
+25
+00:02:12,400 --> 00:02:16,300
+هجوم و substitution لحظة اللى بيتقن مبدأ بغض النظر
+
+26
+00:02:16,300 --> 00:02:20,580
+عن كبر الجزية انا بتعامل مع مبدأ زوج إلكترونات
+
+27
+00:02:20,580 --> 00:02:26,560
+بيهاجم على ال positive carbon بيطرد ايش ال CL طبعا
+
+28
+00:02:26,560 --> 00:02:31,000
+بالتأكيد بدكوا تكونوا متذاكرين ان هذه ال amines لو
+
+29
+00:02:31,000 --> 00:02:35,680
+كانت بتهاجم على الديهيد او كيتون هتعمل ابدال
+
+30
+00:02:38,930 --> 00:02:42,570
+إيش هتعمل؟ addition هتعمل addition و تحولها إلى
+
+31
+00:02:42,570 --> 00:02:46,370
+watch و ال addition ممكن يتبع ب elimination هاي
+
+32
+00:02:46,370 --> 00:02:51,150
+هنا في مثال مثلا تفاعل أمين مع anhydride بالتأكيد
+
+33
+00:02:51,150 --> 00:02:55,410
+برضه مرة تانية الأمين بده يهاجم على ال CW bond O و
+
+34
+00:02:55,410 --> 00:03:01,030
+بده يطرد المجموعة هذه كلها فجميع هذه التفاعلات
+
+35
+00:03:01,030 --> 00:03:06,550
+الحقيقة هي تفاعلاتمتوازية تفاعلات substitution
+
+36
+00:03:06,550 --> 00:03:12,910
+بهذه التفاعلات the amines act as enucleophile
+
+37
+00:03:24,260 --> 00:03:28,380
+السؤال ممكن يصير، لو كان هذا un-symmetrical، يعني
+
+38
+00:03:28,380 --> 00:03:32,020
+نفترض أن هذه كانت مثل وهذه فنل، بده يروح هنا أو
+
+39
+00:03:32,020 --> 00:03:36,020
+هنا، غالباً هيروح على الجهتين و هيعطي ناتجين، بأي
+
+40
+00:03:36,020 --> 00:03:41,080
+نسب بيعتمد على تجربة؟بس لو كان هذا غير متماثل،
+
+41
+00:03:41,080 --> 00:03:43,980
+يعني السيد أبو البون تقول هنا نفترض مثل الهانافينل
+
+42
+00:03:43,980 --> 00:03:48,760
+ممكن جزء يتفاعل على هذه وجزء على هذه وبيطلع نوات
+
+43
+00:03:48,760 --> 00:03:53,480
+يجيب نسب مختلفة لا تحدد إلا بإيش؟ إلا بالتجربة،
+
+44
+00:03:53,480 --> 00:03:56,200
+لأنه في النهاية الكيمياء بتضال زي ما حكينا كتير
+
+45
+00:03:56,200 --> 00:04:04,880
+علم تجريبي، علم تجريبي، واضح؟الان اخر تفاعل ل ال
+
+46
+00:04:04,880 --> 00:04:10,720
+aromatic amines عادة بيكون فعال هو تفاعل مهم جدا
+
+47
+00:04:10,720 --> 00:04:15,360
+ان ال aromatic amines اللي هو الانيلينو مشتقاته
+
+48
+00:04:15,360 --> 00:04:22,420
+الانيلينو مشتقاته بيتفاعلوا مع ال nitrous acid ال
+
+49
+00:04:22,420 --> 00:04:27,560
+nitrous acid اذا بتذكروا HNO2 ليش؟ اتذكروا ال
+
+50
+00:04:27,560 --> 00:04:36,040
+nitric acid ايش كان؟HNO3 Nitric Acid HNO2 Nitrous
+
+51
+00:04:36,040 --> 00:04:40,660
+اللي بيكون أعلى في ال Oxygen Nitric اللي بيكون أقل
+
+52
+00:04:40,660 --> 00:04:46,880
+Nitrous هذا الكلام سبق مرة عليكم الخلاصة ال
+
+53
+00:04:46,880 --> 00:04:50,400
+aromatic amines زي ال Aniline بتفعل مع ال Nitrous
+
+54
+00:04:50,400 --> 00:04:57,830
+Acid في وجود HCl بيعطونا أملاحبيكون سرعة البنزين
+
+55
+00:04:57,830 --> 00:05:02,470
+N2 plus Cl minus هذه عبارة عن أيونين يعني هذا
+
+56
+00:05:02,470 --> 00:05:09,570
+لحاله هيك بيكون plus وجنبه Cl minus زي Na Cl
+
+57
+00:05:09,570 --> 00:05:16,300
+تذكروا Na إيش بيكونplus CL minus نفس الفكرة إذا
+
+58
+00:05:16,300 --> 00:05:22,560
+NACL is a salt و هذا salt موازي له تماما plus
+
+59
+00:05:22,560 --> 00:05:27,040
+minus plus minus إذا أنا بحكي عن salt الآن هذا ال
+
+60
+00:05:27,040 --> 00:05:32,280
+salt في كام نيتروجينة؟ تنتين إيش اسم غاز
+
+61
+00:05:32,280 --> 00:05:37,840
+النيتروجين غير النيتروجين؟ لأ غير النيتروجين
+
+62
+00:05:37,840 --> 00:05:39,720
+الازوت
+
+63
+00:05:40,940 --> 00:05:44,640
+وعشان يقطعون البيئة مرات لما بيقولوا انه في أكاسيد
+
+64
+00:05:44,640 --> 00:05:49,800
+نيتروجين بتلوث الجو بيقولوا أكاسيد الأزوت وبناء
+
+65
+00:05:49,800 --> 00:05:53,320
+على ذلك في كتير في التسميات لما بدنا نختصر التعبير
+
+66
+00:05:53,320 --> 00:05:57,680
+عن ال nitrogen في الكيبية الحلقية بنستعمل بدل كلمة
+
+67
+00:05:57,680 --> 00:06:02,220
+nitrogen أزا أزا يعني نيتروجين، di-aza يعني
+
+68
+00:06:02,220 --> 00:06:06,140
+نيتروجين تاني، tri-azaيعني تلت نيتروجينات يعني
+
+69
+00:06:06,140 --> 00:06:09,240
+مثلا لما بدنا نسمي مركب فيه تلت نيتروجينات وحلقة
+
+70
+00:06:09,240 --> 00:06:15,140
+خمسية بنقول try as all معناه حلقة خمسية فيها تلت
+
+71
+00:06:15,140 --> 00:06:21,340
+نيتروجينات فكلمة as مرتبطة بإيش؟ من نيتروجين is
+
+72
+00:06:21,340 --> 00:06:27,500
+it؟ الآن هذا بيسموه die as لأنه فيه تنتين ولأنه
+
+73
+00:06:27,500 --> 00:06:35,990
+موجب الأيون الموجب إيش نهايته؟ onion والسالبإيت ..
+
+74
+00:06:35,990 --> 00:06:41,710
+إيت وولاد عمها إيت
+
+75
+00:06:41,710 --> 00:06:46,770
+وولاد عمها، إيش ولاد عم ال إيت؟ لأ ال أويتها دي
+
+76
+00:06:46,770 --> 00:06:50,550
+كانت تبعت ال E star لأ ال إيت نفسها مش هي لل أيون
+
+77
+00:06:50,550 --> 00:06:56,730
+السالب، و إيش كمان بيجي لل أيون السالب؟ ايت ..
+
+78
+00:06:56,730 --> 00:07:03,970
+إنتوا اتذكروا ال .. لما يكون عندكوا كلوريتمش فيه
+
+79
+00:07:03,970 --> 00:07:11,190
+chloride؟ برضه ال-ite ايون سالب نيتريت سالب نيتريت
+
+80
+00:07:11,190 --> 00:07:16,930
+سالب في ال chloride و ال chloride ايش كمان عندكم؟
+
+81
+00:07:16,930 --> 00:07:24,310
+بير اكلوريت و hypo اكلوريت كل هدول السالبين يعني
+
+82
+00:07:24,310 --> 00:07:28,430
+ال بير اكلوريت و ال .. و ال chloride و ال
+
+83
+00:07:28,430 --> 00:07:33,150
+hypochlorite كلها ايوناتسالبة لكن بشكل عام لما
+
+84
+00:07:33,150 --> 00:07:37,670
+يكون عندى بس ايون واحد يعني زي ال acetate مافيش
+
+85
+00:07:37,670 --> 00:07:41,910
+غير شكل واحد في ال oxygen اللى مستعمل اكتر اللى هو
+
+86
+00:07:41,910 --> 00:07:46,570
+الاش it لكن لما بصير عندى زيادة ونقص في عدد ال
+
+87
+00:07:46,570 --> 00:07:51,630
+oxygen ممكن نستعمل per it, it, it, it, it
+
+88
+00:07:54,800 --> 00:07:58,180
+فشوية احنا بنضل نطلع عن الموضوع بس بنذكركم في
+
+89
+00:07:58,180 --> 00:08:00,960
+أشياء في الكيميا العامة، فعشان هيك هذا المركب
+
+90
+00:08:00,960 --> 00:08:06,020
+بيسموه بنزين، هي بنزين داياز يعني في نيتروجنتين
+
+91
+00:08:06,020 --> 00:08:11,640
+اونيوم، يعني ايون موجب، salt، اشوة كلورايت، فبصير
+
+92
+00:08:11,640 --> 00:08:14,480
+كل هذا اسمه بنزين دايازونيوم
+
+93
+00:08:18,580 --> 00:08:23,040
+العائلة هذه كلها من المُركّبات بيسموها Diazonium
+
+94
+00:08:23,040 --> 00:08:27,520
+salts أو Diazonium compounds أو أملاح الـDiazonium
+
+95
+00:08:27,520 --> 00:08:35,750
+الآن يا تورا هل أملاح الـDiazonium هذه مفيدة؟بحد
+
+96
+00:08:35,750 --> 00:08:42,310
+ذاتها مش مفيدة وبتتكون ما بين 0 إلى 5 درجات مهوية
+
+97
+00:08:42,310 --> 00:08:45,510
+زي ما انتوا شايفين ولو الحرارة ارتفعت عن هيك
+
+98
+00:08:45,510 --> 00:08:50,770
+بتخرب، بتتكسر طب هوين الفائدة بتاعتها؟ الفائدة
+
+99
+00:08:50,770 --> 00:08:55,390
+بتاعتها مش بذاتها الفائدة تبعت ال diazonium salts
+
+100
+00:08:55,390 --> 00:09:01,090
+هذه إنها بتتحول إلى مراكبات تانية يعني هي bridge
+
+101
+00:09:01,090 --> 00:09:07,480
+للتحول أو جسرللتحول حلقة واصل اسمها زي ما بدكم
+
+102
+00:09:07,480 --> 00:09:13,580
+للتحول إلى مجموعة من المركبات التانية تحضر من
+
+103
+00:09:13,580 --> 00:09:18,400
+خلالها يعني هي نقطة انطلاق لإش جديد بس هي بحد
+
+104
+00:09:18,400 --> 00:09:23,180
+ذاتها مش كتير مهمة لأنها مش ثابتة تتكون أثناء
+
+105
+00:09:23,180 --> 00:09:28,300
+التفاعل لو الحرارة ارتفعت بتخرب لكن هي نقطة إش
+
+106
+00:09:29,260 --> 00:09:33,240
+انطلاق الان عشان تشوفوا نقطة انطلاق اتطلعوا على
+
+107
+00:09:33,240 --> 00:09:37,560
+هذا ال slide هاي نحط لكوا diazonium salt ومحضرين
+
+108
+00:09:37,560 --> 00:09:42,280
+منها كام مركب واحد اتنين تلاتة اربع خمسة ستة سبعة
+
+109
+00:09:42,280 --> 00:09:46,760
+كل هدولة بنحضرهم من وين من ال diazonium salt وهي
+
+110
+00:09:46,760 --> 00:09:52,500
+معناه ان هي تعتبر نقطة انطلاق واضح؟فعلى سبيل
+
+111
+00:09:52,500 --> 00:10:00,000
+المثال، ممكن الـDiazolium salt الفاعل مع HCl وكبر
+
+112
+00:10:00,000 --> 00:10:05,940
+كلوري يبدل محل الـDiazolium chloride، واضح؟ هذا
+
+113
+00:10:05,940 --> 00:10:09,120
+التفاعل بالمناسبة يسموه Sand Meier reaction
+
+114
+00:10:11,940 --> 00:10:18,400
+Sandmeier أكيد إن البد المحل الانتوا إيش CL طبعا
+
+115
+00:10:18,400 --> 00:10:21,700
+البعض هيقول إنه ما إحنا بنقدر نحضر ال CL من
+
+116
+00:10:21,700 --> 00:10:26,880
+البنزين بألومينيوم كلورايد و .. و كلورين بالعكس
+
+117
+00:10:26,880 --> 00:10:32,480
+هذا التحضير أسهل لسبب بسيط إنه مرات أنتوا بتاخدوا
+
+118
+00:10:32,480 --> 00:10:40,170
+التفاعل بدون ما تحسوا خليني أقول بإيشبغلبته، يعني
+
+119
+00:10:40,170 --> 00:10:45,570
+لما نيجي يقول CL2 ألومنيوم إكلورايد زي اللي بيحكي
+
+120
+00:10:45,570 --> 00:10:50,530
+جملة مثلا امبارح يمكن كان ذكرا النكبة كل ناس بيجي
+
+121
+00:10:50,530 --> 00:10:55,730
+ويقولوا سانو حرروا فلسطين و تحرروا فلسطين لعبة ولا
+
+122
+00:10:55,730 --> 00:10:59,510
+الكلمة لها موراقها لحظو انا مثلا لما تقولوا احنا
+
+123
+00:10:59,510 --> 00:11:06,490
+بنفعل مع CL2 ألومنيوم إكلورايد الـCL2 غاز وغاز سام
+
+124
+00:11:07,590 --> 00:11:14,050
+معنى ذلك لو أنا بدى أستعمله، بدى حذر لما باشتريه
+
+125
+00:11:14,050 --> 00:11:21,350
+في استوانات، غاز مؤكسدلما بدي أحطله منظم للأنبوبة
+
+126
+00:11:21,350 --> 00:11:25,790
+الغاز مابحطلوش منظم عادي بياكله خلال يوم منظم
+
+127
+00:11:25,790 --> 00:11:30,510
+انحاس .. إله منظم بشتريه خصوصي بمبالغ غالية جدا ..
+
+128
+00:11:30,510 --> 00:11:35,710
+واضح؟ لما بدي أمشي بمشي بمواسير معدنية خاصة مش في
+
+129
+00:11:35,710 --> 00:11:40,710
+plastic و بعد يومين قب اللي هو .. واضح؟ و بنفس
+
+130
+00:11:40,710 --> 00:11:44,050
+الوقت لما بدي أشتغل بدي شفات جو يشفط كل الغاز اللي
+
+131
+00:11:44,050 --> 00:11:49,830
+بيزيد لإن أنا بتعامل مع غاز .. ساممظبوط ولا لأ؟
+
+132
+00:11:49,830 --> 00:11:55,290
+مرة صار في القردن هيك اتسرب غاز .. غاز كلورين كل
+
+133
+00:11:55,290 --> 00:11:59,770
+مدينة الزرقه شردت و نزل ايامها الملك حسين في الليل
+
+134
+00:12:00,040 --> 00:12:07,220
+تابع الحادث فهنا أنا بأتعامل مع غاز و بأتعامل مع
+
+135
+00:12:07,220 --> 00:12:13,460
+غاز سام فما تتوقعوش أن الموضوع التعامل معاه بسهولة
+
+136
+00:12:13,460 --> 00:12:16,860
+اللي أنتم بتخيلوها ال aluminum chloride ال
+
+137
+00:12:16,860 --> 00:12:21,720
+aluminum chloride Lewis acidتمام؟ بناء على ذلك هو
+
+138
+00:12:21,720 --> 00:12:26,660
+شريه جدا للميّه وانا بوزنه .. وانا بوزنه و بنجله
+
+139
+00:12:26,660 --> 00:12:30,560
+من مكان لمكان بياخد من ميّه الجو و باتفاعل معها
+
+140
+00:12:30,560 --> 00:12:36,020
+تخيل لحد وين؟وبالتالي ممكن يخرب يعني بده شروط
+
+141
+00:12:36,020 --> 00:12:39,660
+شديدة من الجفاف أثناء ما بكون بشتغل في المختبر
+
+142
+00:12:39,660 --> 00:12:45,220
+فعمليا لا هذا مريح في التعامل ولا هذا مريح في
+
+143
+00:12:45,220 --> 00:12:50,360
+التعامل يعني بده احتياطات مخبرية مش بس .. مش
+
+144
+00:12:50,360 --> 00:12:56,400
+بسهولة الكتيرة يعني تتخيلوا التعامل معاه طبعا مرات
+
+145
+00:12:56,400 --> 00:12:59,160
+كتير لما احنا بنشرحلكم نكتبلكم المعادلة وما
+
+146
+00:12:59,160 --> 00:13:03,100
+بنجيبلكم مش هذه الأشياء لسبب بسيط أن انتوا بتظلوا
+
+147
+00:13:04,620 --> 00:13:07,940
+general organic course لكن لو نزلتوا على المعمل
+
+148
+00:13:07,940 --> 00:13:11,100
+الكلام اللي بتفكروا بنعمله بثانية حتى تكتشفوا أنه
+
+149
+00:13:11,100 --> 00:13:14,440
+بدكوا أسبوع تجهزوا لتشتريوا الأنبوبة و الغاز و
+
+150
+00:13:14,440 --> 00:13:20,000
+تظبطوا الشفافات و تشتريوا المنظم ليست عملية سهلة و
+
+151
+00:13:20,000 --> 00:13:23,620
+بنت دقيقة فهذه العملية اللي لسه بستعمل فيها على
+
+152
+00:13:23,620 --> 00:13:28,500
+HCL و cover chloride تعتبر أسهل إليه من أن أستعمل
+
+153
+00:13:28,500 --> 00:13:32,340
+غاز سام واضح؟
+
+154
+00:13:32,340 --> 00:13:39,590
+هذهأحدى التفاعلات نشوف تفاعل تاني موازي التفاعل
+
+155
+00:13:39,590 --> 00:13:44,770
+التاني الموازي تقريبا أن نضع PR هذه موازية تماما و
+
+156
+00:13:44,770 --> 00:13:52,370
+بنفس الاسم الفاعل HPR مع كبر بروميد بحط لنا إيش ال
+
+157
+00:13:52,370 --> 00:13:58,970
+PR تفاعل تالت أن نضع ال CN برضه مع كبر سيانايت
+
+158
+00:13:58,970 --> 00:14:06,940
+بنشيل ال N2 و بنضعالـ CN و بنحط إيش مكانها الـ CN
+
+159
+00:14:06,940 --> 00:14:13,980
+برضه هي التفاعل التالت تفاعل رابع إننا نحط الـ U
+
+160
+00:14:13,980 --> 00:14:21,020
+يعني هيحطينا كل الـ halogens إننا
+
+161
+00:14:21,020 --> 00:14:27,120
+نحط الـ U باستعمال KI تفاعل خامس بحط ال floor
+
+162
+00:14:27,120 --> 00:14:32,500
+باستعمال HPF4 مع حرارة لاحظوا ال halogen ال floor
+
+163
+00:14:34,410 --> 00:14:41,090
+كلور، إبران، يود، كلهم ممكن أحطهم محل ايش؟ محل
+
+164
+00:14:41,090 --> 00:14:44,130
+الديازونيوم سولت و سيقان، إيش قعدت بيجي سؤالك؟
+
+165
+00:14:44,130 --> 00:14:47,590
+السيقان سبب الانتموجة؟ أكيد طب إحنا ممكن نبدلها
+
+166
+00:14:47,590 --> 00:14:50,430
+بالسيناد السلب، ممكنش الانتموجة في محل الموجة،
+
+167
+00:14:50,430 --> 00:14:54,990
+السرب في محل السلب؟ يعني ماقلناش نبدلها بالسيناد
+
+168
+00:14:54,990 --> 00:14:57,750
+السلب ولا حكينا عن الميكانيزم اللي بتم فيها
+
+169
+00:14:57,750 --> 00:15:02,880
+الإبدال، أنت حكيت من عندك، مش أناانت قلت انك بدك
+
+170
+00:15:02,880 --> 00:15:08,960
+تبدن ..الان هذا كله HCl مع كبر كلورايد او KCl مع
+
+171
+00:15:08,960 --> 00:15:12,540
+كبر كلورايد هذا كله بيجيب CL positive زي ما كنت
+
+172
+00:15:12,540 --> 00:15:15,760
+انا مع الكلورين و الالومنيوم كلورايد، شو اللي كنت
+
+173
+00:15:15,760 --> 00:15:24,400
+اتعامل معاه؟ اه okay الان في تفاعل كتير مهم، تفاعل
+
+174
+00:15:24,400 --> 00:15:29,340
+تحضير الفينوللاحظوا ان الفينول يمكن المرة الماضية
+
+175
+00:15:29,340 --> 00:15:34,500
+سابقة حكيتلكوا مابقدرش أحضره مباشرة لأنه لو بدي
+
+176
+00:15:34,500 --> 00:15:38,420
+أجيب OH- على البنزينة ممكن أنه ينفعش minus على
+
+177
+00:15:38,420 --> 00:15:42,860
+minus طبعا كيف بنحضره؟ بنحضره من ديازونيوم سولت مع
+
+178
+00:15:42,860 --> 00:15:46,440
+ميه و حامض يعني هذا الديازونيوم سولت لو حاطينا
+
+179
+00:15:46,440 --> 00:15:51,940
+عليه ميه عليها نقاط من الحامض بيتحول إلى فينولإذا
+
+180
+00:15:51,940 --> 00:15:56,280
+لو ده نيجي نسألكم عن الفينول ماحدش يكتب لبنزين زاد
+
+181
+00:15:56,280 --> 00:16:01,660
+OH minus ولا بنزين زاد NaOH لأ لازم تكون ال
+
+182
+00:16:01,660 --> 00:16:06,660
+diazonium salt ال diazonium salt من وين إجا؟ من ال
+
+183
+00:16:06,660 --> 00:16:12,950
+aniline ال anilineمن ال nitro benzene و ال nitro
+
+184
+00:16:12,950 --> 00:16:16,650
+benzene من ال benzene فكأنه صار عنده يعني سلسلة
+
+185
+00:16:16,650 --> 00:16:22,070
+benzene, nitro benzene بال reduction بصير aniline،
+
+186
+00:16:22,070 --> 00:16:25,270
+ال aniline بال sodium nitrite أو ال nitrous acid
+
+187
+00:16:25,270 --> 00:16:30,270
+بصير diazonium salt، ال diazonium salt مع H plus,
+
+188
+00:16:30,330 --> 00:16:36,770
+H2O بصير phylonالشغلة الأخيرة أنه احنا ممكن محل ال
+
+189
+00:16:36,770 --> 00:16:43,310
+N2 plus هذه ممكن محل ال N2 plus هذه نحط هيدروجين
+
+190
+00:16:43,310 --> 00:16:50,010
+ممكن محل ال N2 plus اللي موجودة عندنا هنا نحط
+
+191
+00:16:50,010 --> 00:16:58,510
+هيدروجين واضح؟ إذا ال diazonium salt أهميته أن هو
+
+192
+00:16:58,510 --> 00:17:06,410
+يمثل نقطةنقطة انطلاق لتحضير أشياء جديدة، نقطة
+
+193
+00:17:06,410 --> 00:17:11,310
+انطلاق لتحضير أشياء جديدة، هذه الأشياء ممكن تكون
+
+194
+00:17:11,310 --> 00:17:16,790
+halogens، CN، ممكن تنسوا مثلا إن ال CN هو نقطة
+
+195
+00:17:16,790 --> 00:17:22,190
+انطلاق لتحضير إيش؟
+
+196
+00:17:22,190 --> 00:17:31,690
+أخدناها، الحامض ال CN يبقى H plus oroh minus و
+
+197
+00:17:31,690 --> 00:17:40,430
+بعدين h plus على خطوتين كان يعطينا يعني انا لما
+
+198
+00:17:40,430 --> 00:17:44,130
+بدأ اجي اقولكوا حضرولي حامض كيف بدكوا تحطوا الحامض
+
+199
+00:17:44,130 --> 00:17:52,230
+انطلاقكوا من ال cn واضح؟ بنزوك أسد بنزوك أسد مثلا
+
+200
+00:17:52,230 --> 00:17:58,140
+نقطة الانطلاق شو بده تكون ال cnنقطة الإنطلاق
+
+201
+00:17:58,140 --> 00:18:04,620
+تبعتكم بدأ تكون الـ CL واضح؟ الآن بحاول أعطيكم
+
+202
+00:18:04,620 --> 00:18:08,760
+مثال أو اتنين تأكيديات على الاستفادة من هذه
+
+203
+00:18:08,760 --> 00:18:11,840
+الطريقة في ال organic synthesis لأن هذا موضوع
+
+204
+00:18:11,840 --> 00:18:18,460
+دائما نسأل عنه لكن خلّينا ناخد آخر slide موجودة
+
+205
+00:18:18,460 --> 00:18:24,040
+معناأخر slide أن الـ diazonium salts نفسها ممكن
+
+206
+00:18:24,040 --> 00:18:28,480
+تتفاعل مع الفينول، هنا بتكون تلاحظوا أن ال
+
+207
+00:18:28,480 --> 00:18:33,280
+diazonium salt موجبة، الفينول وين بيودّي؟ على موقع
+
+208
+00:18:33,280 --> 00:18:39,740
+Orthoو موقع بارا يعني لو جيبت فين والجاهز ال OH
+
+209
+00:18:39,740 --> 00:18:44,680
+كsubstituent سبقنا حكينا انا activating group و
+
+210
+00:18:44,680 --> 00:18:48,700
+orthobara directing group فلما نيجي نفعلها مع موجة
+
+211
+00:18:48,700 --> 00:18:52,220
+بهذا الموجة بوين بنتوقع ييجي يهاجم على ال بارا و
+
+212
+00:18:52,220 --> 00:18:56,800
+على ال orthobara لو أخدنا ناتجالبارا لو أخدنا ناتج
+
+213
+00:18:56,800 --> 00:18:59,880
+تبع البارا بيصير عندنا هذا المركب اللي هو ال
+
+214
+00:18:59,880 --> 00:19:06,200
+phenol, phenol, phenol هذه عبارة عن مركبات سبغات
+
+215
+00:19:06,200 --> 00:19:08,900
+هي السبغات الملونة اللي أنتوا بتشوفوها الصفرة
+
+216
+00:19:08,900 --> 00:19:17,140
+والبردجانية بنسميها diazo dyes سبغاتالنيتروجين
+
+217
+00:19:17,140 --> 00:19:22,420
+اللي هو الثنائي داي ازو ايش يعني داي ازو يعني وجود
+
+218
+00:19:22,420 --> 00:19:29,220
+نيتروجين تاني داي صبغة فالصبغات اللي فيها نيتروجين
+
+219
+00:19:29,220 --> 00:19:33,360
+تاني طبعا في صبغات من مركبات تانية مختلفة تماما في
+
+220
+00:19:33,360 --> 00:19:37,040
+الشكل ومشكلة بصراحة
+
+221
+00:19:38,970 --> 00:19:47,960
+مشكلة الصباغات حقيقة أنه للأسف الشديد طبعابدها نوع
+
+222
+00:19:47,960 --> 00:19:53,900
+من الحذر يعني بيشتغلوا صبغة بنزلوها على السوق
+
+223
+00:19:53,900 --> 00:20:00,680
+باستعملوها الناس و بعد هيك بيثبت انه لها كتير
+
+224
+00:20:00,680 --> 00:20:05,360
+تأثيرات ضارة على الشعر و ما إلى ذلك خصوصا يعني
+
+225
+00:20:05,360 --> 00:20:08,380
+الأبحاث الكتيرة اللي هي الشغل اللي بيشتغلون نساء
+
+226
+00:20:08,380 --> 00:20:13,380
+اللي بيكتروا من السبق كتير معرضين كتير بشكل كبير
+
+227
+00:20:13,380 --> 00:20:18,540
+جدالأ cancer و ما إلى ذلك يعني اليوم الجيل القديم
+
+228
+00:20:18,540 --> 00:20:23,200
+من الصبغات مثلا كان من مركبات pyrazoles في الغالب
+
+229
+00:20:23,200 --> 00:20:29,840
+معظمها pyrazoles دراسات مهولة .. دراسات مهولة طلعت
+
+230
+00:20:29,840 --> 00:20:34,340
+أنه هذه المركبات carcinogenic طبعا الشركات بتبدأ
+
+231
+00:20:34,340 --> 00:20:37,920
+تعرف قبل الناس يعني نفس الشركات اللي بتعمل الصبغات
+
+232
+00:20:37,920 --> 00:20:42,820
+بتبدأ تعرففينها لما تعرف شو بدها تسوي بتروح بتحضر
+
+233
+00:20:42,820 --> 00:20:46,320
+أجيال جديدة، طب و المحضر عندها و المصانع اللي
+
+234
+00:20:46,320 --> 00:20:50,860
+شغالة و ما إلى ذلك و بنزل الجديم عرض خدوا في
+
+235
+00:20:50,860 --> 00:20:54,540
+العالم الثالث و الرابع و الخامس بيروحوا ببيعوهم كل
+
+236
+00:20:54,540 --> 00:20:59,810
+الجديم و بيعملواأشياء جديدة، يعني الـ Pyrazoles من
+
+237
+00:20:59,810 --> 00:21:05,310
+حوالي 15 سنة أو أقل بدوا يستعملوها بالـ Triazines،
+
+238
+00:21:05,310 --> 00:21:08,210
+يعني بدل ما هي حلقات خمسية بنيتروجينتين صار حلقات
+
+239
+00:21:08,210 --> 00:21:13,970
+ستاسية بتلت نيتروجينات، لكن مين اللي عنده تفاصيل
+
+240
+00:21:13,970 --> 00:21:20,370
+العمل هذا اللي قاعد بنشغل؟ الشركات، الشركات، ولذلك
+
+241
+00:21:20,370 --> 00:21:25,120
+هذه المناطق كلها تعتبر مناطقأقل ما يُقال فيها أنه
+
+242
+00:21:25,120 --> 00:21:29,140
+تحت التجربة، لكن ثابت بحالات كثيرة أنه في شغلات
+
+243
+00:21:29,140 --> 00:21:33,960
+منها فعلًا كانت بمعنى الكلمة carcinogenic وسُحِبت
+
+244
+00:21:33,960 --> 00:21:37,980
+من الأسواق، عدمين اللي اتبع، على أي حال، هذا نوع
+
+245
+00:21:37,980 --> 00:21:41,340
+من الصبغات اللي بنحضره احنا اللي هو الـdiazodide
+
+246
+00:21:41,340 --> 00:21:46,450
+اللي هي الصبغاتاللي فيها two nitrogels هذي yellow
+
+247
+00:21:46,450 --> 00:21:52,370
+leaflets اللي أول ما بتتكون بتتكون يعني بشكل أصفر
+
+248
+00:21:52,370 --> 00:21:56,470
+high melting point اللي هو بندوّب شوية بethanol أو
+
+249
+00:21:56,470 --> 00:22:06,050
+إيش هو بنحصل على هالألوان ويا ما أحلاها لكن على
+
+250
+00:22:06,050 --> 00:22:12,290
+أي حال خلّينا يمكن نظل محافظين على الإضاءة إذا
+
+251
+00:22:12,290 --> 00:22:13,450
+بنعمل زي هيك
+
+252
+00:22:18,620 --> 00:22:24,100
+بإمكاننا الفكرة الأخيرة نعطيكوا عليها .. نعطيكوا
+
+253
+00:22:24,100 --> 00:22:29,700
+عليها بعض الأمثلة مثلا لو جيبنالكم أنه بدنا
+
+254
+00:22:29,700 --> 00:22:34,300
+اتحضرولنا هذا
+
+255
+00:22:34,300 --> 00:22:35,480
+المركب
+
+256
+00:22:47,410 --> 00:22:54,010
+ليش طفل هذا؟ لو بدنا نحضر هذا و نبتدأ من البنزين
+
+257
+00:22:54,010 --> 00:23:00,730
+نحضر هذا و نبتدأ من إيش؟ من البنزين لاحظوا أن
+
+258
+00:23:00,730 --> 00:23:05,410
+انتوا اتعلمتوا .. اتعلمتوا تحضير مجموعة المثل
+
+259
+00:23:05,410 --> 00:23:14,740
+بنقدر نحط ال .. بنقدر نحط المثل من خلالCH3Cl لكن
+
+260
+00:23:14,740 --> 00:23:18,900
+لو قلنا مجموعة الحامض أخدتوا الطريقة نحط الحامض أه
+
+261
+00:23:18,900 --> 00:23:25,060
+إذا المفروض وانتوا بتفكروا تقولوا احنا بنرجع
+
+262
+00:23:25,060 --> 00:23:29,100
+بالجوا برس معادة السهم بهذه الطريقة شايفين هذا
+
+263
+00:23:29,100 --> 00:23:33,900
+السهم هذا السهم اللي بنقول عنه احنا سهم ال retro
+
+264
+00:23:33,900 --> 00:23:40,620
+synthesis يعني انا لو كنتretro synthesis يعني لو
+
+265
+00:23:40,620 --> 00:23:45,680
+كنت برجع برجوع المفروض ان اقول ان ال COOH من وين
+
+266
+00:23:45,680 --> 00:23:58,000
+جاية من ال CNI كأنه صار عندك CH3 و CN ماشي بداجة
+
+267
+00:23:58,000 --> 00:24:04,760
+اقول ال CN من وين جاية واضح؟
+
+268
+00:24:06,910 --> 00:24:17,610
+طوي لسه أخدنا ال CN من وين جاية؟ من النيازو ال 2
+
+269
+00:24:17,610 --> 00:24:32,890
+plus، مظبوط؟ النيازو من وين جاية؟ من ال N H 2 ممكن
+
+270
+00:24:32,890 --> 00:24:38,950
+في الأصل ال 9يا تورا بقدر انا اكون بدي بالمثل و
+
+271
+00:24:38,950 --> 00:24:43,250
+احط ال N-H2 ما هي ال N-H2 من وين بتيجي؟ من ال
+
+272
+00:24:43,250 --> 00:24:54,170
+Nitro يعني كأنه هذا بدي يكون CH3 و NO2 CH3 و NO2
+
+273
+00:24:54,170 --> 00:24:58,770
+طيب هي لسه مازال عندى مجموع تان CH3 و NO2 مين اللي
+
+274
+00:24:58,770 --> 00:25:04,530
+بدي أحطها بالأول؟ لو بديك بالمثل وين هتودى؟
+
+275
+00:25:05,280 --> 00:25:10,720
+Orthopara لو بدت بالنيترو ميدا، اذا انا المفروض لو
+
+276
+00:25:10,720 --> 00:25:20,880
+بدي ابدأ اكون بدء من النيترو on
+
+277
+00:25:20,880 --> 00:25:24,420
+O2 و بعدين النيترو من وين بجيبه؟
+
+278
+00:25:26,910 --> 00:25:33,670
+من البنزين الان كل هذا ارجع بالتفكير عشان ذلك احنا
+
+279
+00:25:33,670 --> 00:25:38,790
+ايش بنسميه retro synthesis لو كنت عاد بدي ابدأ
+
+280
+00:25:38,790 --> 00:25:42,750
+اعمل المسألة من اول و جديد بقول بنزين ايش اللي بدي
+
+281
+00:25:42,750 --> 00:25:48,370
+يخليه نيترو بصير احط الاسم زي هيك مديش اعيد كتابة
+
+282
+00:25:48,370 --> 00:25:52,590
+كل إشي بس انتوا المفروض تعدوا بدي احطله HNO3
+
+283
+00:26:00,060 --> 00:26:08,860
+النيترو لما بدى حاوله النيترو
+
+284
+00:26:08,860 --> 00:26:13,840
+لما بدى حاوله النيترو لما بدى حاوله النيترو لما
+
+285
+00:26:13,840 --> 00:26:15,600
+بدى حاوله النيترو لما بدى حاوله النيترو لما بدى
+
+286
+00:26:15,600 --> 00:26:16,780
+حاوله النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+287
+00:26:16,780 --> 00:26:17,560
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+288
+00:26:17,560 --> 00:26:20,580
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+289
+00:26:20,580 --> 00:26:23,200
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+290
+00:26:23,200 --> 00:26:23,360
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+291
+00:26:23,360 --> 00:26:23,380
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+292
+00:26:23,380 --> 00:26:28,960
+النيترو لما بدىDiazonium HNO2
+
+293
+00:26:28,960 --> 00:26:35,580
+مرات من اللي بيستعملوا ال HNO2 بيستعملوا ال sodium
+
+294
+00:26:35,580 --> 00:26:38,720
+nitrite مع حمض ال sodium nitrite مع حمض بتفعل و
+
+295
+00:26:38,720 --> 00:26:45,200
+بتطلع HNO2 يعني لو قولنا HNO2 ولا قولنا NA NO2
+
+296
+00:26:45,200 --> 00:26:51,150
+زائد H plus هدولة معناهم برضه HNO2لأن ال sodium
+
+297
+00:26:51,150 --> 00:26:55,730
+nitrate بتفعل مع الحمض بتطلع HNO2 مش المشكلة okay
+
+298
+00:26:55,730 --> 00:27:06,990
+ال L2 plus كي بدأ تصير CNO KCN كبرتو ال CN ايش
+
+299
+00:27:06,990 --> 00:27:13,470
+اللي بيبقى يخليها COH ملاحظين؟
+
+300
+00:27:19,510 --> 00:27:25,330
+فهذا اللي هو يعني مثال على ال retro synthesis كيف
+
+301
+00:27:25,330 --> 00:27:30,910
+الأمور اللي واحد بتعامل معها بتعامل معها بهدوء
+
+302
+00:27:30,910 --> 00:27:34,550
+ممكن نشرح كمان مثال واحد أخير
+
+303
+00:27:44,680 --> 00:27:49,080
+طبعا في كتير أشياء أسهل من هيك و هذا مش صعب بس
+
+304
+00:27:49,080 --> 00:27:56,520
+متدرج لأ متدرج مش صعب مش في ولا خطوة صعبة بس متدرج
+
+305
+00:27:56,520 --> 00:28:01,320
+ناخد
+
+306
+00:28:01,320 --> 00:28:07,460
+كمان مثال ناخد كمان مثال لو جيبناكوا هذا المركب
+
+307
+00:28:07,460 --> 00:28:11,100
+اللي
+
+308
+00:28:11,100 --> 00:28:18,070
+موجود في PRPR PR
+
+309
+00:28:18,070 --> 00:28:25,270
+وقلنالكم كيف بتكون تحضروه انطلاقا من البنزين how
+
+310
+00:28:25,270 --> 00:28:29,310
+can you prepare this compound this compound
+
+311
+00:28:29,310 --> 00:28:36,770
+starting from بنزين لاحظوا
+
+312
+00:28:36,770 --> 00:28:43,750
+معي لو أنا كنت بدي أبدأ تحضير عادي يعني البنزينو
+
+313
+00:28:43,750 --> 00:28:51,250
+بعدين اقول PR2 مثلا و Aluminium Bromide او FeBr3
+
+314
+00:28:51,250 --> 00:28:56,490
+مثلا بيمشي
+
+315
+00:28:56,490 --> 00:29:03,130
+المفروض
+
+316
+00:29:03,130 --> 00:29:06,330
+لو بدنا نعمل هذا ال synthesis اول اشي بده تيجي ايش
+
+317
+00:29:06,330 --> 00:29:13,320
+اول PR بكويس لو افترضنا اجت اول PRبعد ذلك تجب أن
+
+318
+00:29:13,320 --> 00:29:17,740
+تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد
+
+319
+00:29:17,740 --> 00:29:18,900
+ذلك تجب أن تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة
+
+320
+00:29:18,900 --> 00:29:18,960
+أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد ذلك تجب أن
+
+321
+00:29:18,960 --> 00:29:19,540
+تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد
+
+322
+00:29:19,540 --> 00:29:20,320
+ذلك تجب أن تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة
+
+323
+00:29:20,320 --> 00:29:20,380
+أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد ذلك تجب أن
+
+324
+00:29:20,380 --> 00:29:26,980
+تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة
+
+325
+00:29:26,980 --> 00:29:39,080
+أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد ذ
+
+326
+00:29:39,210 --> 00:29:42,950
+ال bar .. ال bar هل بيعطيني هذا الشكل اللي موجود
+
+327
+00:29:42,950 --> 00:29:47,510
+هنا؟ إذا ال multi substitution يعني أنه يصير إبدال
+
+328
+00:29:47,510 --> 00:29:51,170
+و بعده كمان إبدال و بعده كمان إبدال مش هيعطيني هذا
+
+329
+00:29:51,170 --> 00:29:56,310
+.. مش هيعطيني هذا بناء على ذلك أنا بحاجة .. أنا
+
+330
+00:29:56,310 --> 00:30:02,510
+بحاجة إلى استراتيجية جديدة أنا بحاجة إلى
+
+331
+00:30:02,510 --> 00:30:05,890
+استراتيجية جديدة أشغل عليها
+
+332
+00:30:08,930 --> 00:30:13,190
+هذه الاستراتيجية الجديدة اللى عملوها بالشكل القادر
+
+333
+00:30:13,190 --> 00:30:19,530
+البنزين مش صعب عليهم يحولوه الى نيترو بنزين هاذي
+
+334
+00:30:19,530 --> 00:30:26,710
+صعبة ولا لا بستعملوا HNO3 H2SO4
+
+335
+00:30:26,710 --> 00:30:34,750
+النيترو بنزين برضه مش صعب عليهم يخلوه أنيلين يعني
+
+336
+00:30:34,750 --> 00:30:35,750
+NH2
+
+337
+00:30:39,370 --> 00:30:44,670
+نكل ممتازة الآن الانيلين is an activating group ال
+
+338
+00:30:44,670 --> 00:30:49,230
+amino group اللي على الانيلين is an activating
+
+339
+00:30:49,230 --> 00:30:56,230
+group و orthoparadirecting و الآن أناشيطة هذه لو
+
+340
+00:30:56,230 --> 00:31:04,370
+فعلناها مع ال PR2 بكمية كبيرة بتحط PR هنا و هنا و
+
+341
+00:31:04,370 --> 00:31:11,000
+هنا على التلت أماكن بتحط وين؟على التلت أماكن يعني
+
+342
+00:31:11,000 --> 00:31:22,780
+بتحط لي nh2 وpr وpr وpr طيب الآن أوصلنا لها
+
+343
+00:31:22,780 --> 00:31:28,480
+المرحلة المركب موجود بس فيه مشكلة ايش هي المشكلة
+
+344
+00:31:28,480 --> 00:31:36,380
+اللي فيه nh2 بدا نتخلص منها بنقدر نتخلص منها كيف
+
+345
+00:31:36,380 --> 00:31:38,780
+نلغيها
+
+346
+00:31:40,390 --> 00:31:45,390
+عند الروضة بيلغوها بالمساحة مش فيه جلم لرصاص وإنه
+
+347
+00:31:45,390 --> 00:31:53,950
+مساحة بيمسحوها بدي أحولها ل H كيف؟
+
+348
+00:31:53,950 --> 00:31:59,010
+طول لسه أنا أخدت أن H2 بتصير دايزونيا يعني لما
+
+349
+00:31:59,010 --> 00:32:02,690
+نقول HNO2
+
+350
+00:32:02,690 --> 00:32:06,150
+بيصير
+
+351
+00:32:06,150 --> 00:32:16,340
+هنا N2 plus وهنا PRو PR و PR ال N2 plus بإيش أخدنا
+
+352
+00:32:16,340 --> 00:32:29,540
+ال HbO3 H3bO2 ال acid هذا بتصير H واضح؟
+
+353
+00:32:29,540 --> 00:32:39,520
+لأن أنا عند PR PR PR واضح
+
+354
+00:32:39,520 --> 00:32:46,280
+ولا لأ؟هذه المسائل الأخيرة اللي احنا عمال بناخدها،
+
+355
+00:32:46,280 --> 00:32:54,520
+هذه قمة الكيميا ولا لأ؟ لازم لما تكون آخر محاضرة،
+
+356
+00:32:54,520 --> 00:33:00,080
+تصلوا لإيش؟ لقمة الكيميا، بس عارفين لما تصلوا لقمة
+
+357
+00:33:00,080 --> 00:33:07,060
+الكيميا، بتكتشفوا أنه وصلتوا لإيش؟ما هي العلوم في
+
+358
+00:33:07,060 --> 00:33:11,460
+الآخر انتبهوا معي العلوم في الآخر بتلاقوها بترجع
+
+359
+00:33:11,460 --> 00:33:18,040
+بتصب في مصاب واحد بتكتشفوا انكم وصلتوا لقمة المنطق
+
+360
+00:33:18,040 --> 00:33:23,700
+الإنساني والعلوم الإنسانية هذه الفكرة هذه الفكرة
+
+361
+00:33:23,700 --> 00:33:30,860
+قبل ما تكون فكرة كيميائية هي فكرة إنسانية بحتة بكل
+
+362
+00:33:30,860 --> 00:33:36,150
+معنى الكلمة موجودة في حياتنا الطبيعيةولما تفهموها
+
+363
+00:33:36,150 --> 00:33:39,750
+بالشكل بتحسوا قداش أنه الدنيا بتكبر .. بتكبر ..
+
+364
+00:33:39,750 --> 00:33:44,050
+بتكبر و بتعود إيش؟ تصغر إحنا إيش اللي عملنا بهذه
+
+365
+00:33:44,050 --> 00:33:52,310
+الفكرة؟ إحنا جبنا مجموعة الأمينو .. مجموعة الأمينو
+
+366
+00:33:52,310 --> 00:33:59,090
+اللي جبناها هنا استفدنا منها أي مستفادة ولا لأ؟ صح
+
+367
+00:33:59,090 --> 00:34:06,280
+ولا لأ؟ فدتنا بشغلتينفدتنا بشغل تاني الشغلة الأولى
+
+368
+00:34:06,280 --> 00:34:09,760
+انها activating يعني بتخلي البروم يتفعل تلت مرات
+
+369
+00:34:09,760 --> 00:34:14,740
+بسرعة والشغلة التانية انها orthoparadirectal group
+
+370
+00:34:14,740 --> 00:34:19,640
+اذا انا انا نمرة واحد بقول الان اتش تو اكتفات
+
+371
+00:34:19,640 --> 00:34:24,140
+اكتفات
+
+372
+00:34:24,140 --> 00:34:25,340
+اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات
+
+373
+00:34:25,340 --> 00:34:27,320
+اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات
+
+374
+00:34:27,320 --> 00:34:33,120
+اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات اكخدمات
+
+375
+00:34:33,120 --> 00:34:41,040
+أو خدمات أو خدمات تجمع كتير هذه الكلمة جليلة ليه
+
+376
+00:34:41,040 --> 00:34:49,120
+جليلة؟ صفة للمنصوب و المنصوب ليش مكسور؟ لأنه
+
+377
+00:34:49,120 --> 00:34:53,400
+جماعه، اه مانزلت طيب بعد ما قدمت إن الخدمات
+
+378
+00:34:53,400 --> 00:35:01,130
+الجليلة هذه إيش عملنا؟ اتخلصنا منهاخلصنا منها، هذه
+
+379
+00:35:01,130 --> 00:35:06,390
+الفكرة إنسانية ولا لأ؟ مين أكتر ناس بيقدموا خدمات
+
+380
+00:35:06,390 --> 00:35:13,710
+جليلة وبعدين بتخلصوا منهم؟ هم
+
+381
+00:35:13,710 --> 00:35:19,880
+العملاءالعملاء بكافة أنواعهم، الواحد بيزيل حاله،
+
+382
+00:35:19,880 --> 00:35:23,620
+بيقدم خدمات جليلة لليهود، وفي الآخر بيحرجوه،
+
+383
+00:35:23,620 --> 00:35:27,440
+بيتخلصوا منه، بيرموه في قرية بدوية، بيعملوا فيه كل
+
+384
+00:35:27,440 --> 00:35:34,000
+العمايل، والأصعب من هيك أننا خمسة عشر سنة أو أكتر
+
+385
+00:35:34,000 --> 00:35:38,160
+بندرس و بنقول العملاء و بيرموهم في الدهنية بقى،
+
+386
+00:35:38,160 --> 00:35:41,100
+تعرفوها الدهنية؟ القرية العملاء اللي عملوها عند
+
+387
+00:35:41,100 --> 00:35:47,350
+رفح سابقة، لموا كل العملاء فيها و سكروا عليهمخمسة
+
+388
+00:35:47,350 --> 00:35:51,650
+عشر سنة واحنا بنقول ان العملاء يقدموا خدمات جليلة
+
+389
+00:35:51,650 --> 00:35:56,730
+ثم يرميهم الأعداء السنة هذه في عندنا ميزة إضافية،
+
+390
+00:35:56,730 --> 00:36:04,430
+شو هي؟ ان العملاء الكبار قدموا برضه خدمات جليلة و
+
+391
+00:36:04,430 --> 00:36:11,230
+بعدين ارتموا في السجونفاللي بيقدّم خدمة جليلة
+
+392
+00:36:11,230 --> 00:36:14,910
+للأسف جزء من السلوك الإنساني أحياناً أنه ممكن
+
+393
+00:36:14,910 --> 00:36:20,850
+نرميه في مثال شهير عاد في الحياة الإنسانية مين
+
+394
+00:36:20,850 --> 00:36:25,970
+اتذكرنا فيه؟ بيعطيها علامة للي
+
+395
+00:36:25,970 --> 00:36:33,950
+بيقدّم خدمة جليلة ثم يرمى غيره،
+
+396
+00:36:33,950 --> 00:36:37,350
+لأ لأ لأ أنه بيكون جزاء الرمى
+
+397
+00:36:39,910 --> 00:36:44,590
+بدأ أحكي أول كلمة باخد أنا العلامة أنا حكيت
+
+398
+00:36:44,590 --> 00:36:55,330
+بالمناسبة أول كلمة المثال بيقول هذا جزاءه cinema
+
+399
+00:36:55,330 --> 00:37:01,450
+لا لازم تكونوا عارفين ومين تحكينا إيش القصة
+
+400
+00:37:01,450 --> 00:37:08,500
+بتاعتهاوزار سليمار هدف فيه أحد الملوك كان طلب من
+
+401
+00:37:08,500 --> 00:37:12,880
+واحد يبنيه قصر يعني ماحدش قيله قصر ازاي فكان هذا
+
+402
+00:37:12,880 --> 00:37:17,220
+المهندس او بناء اسمه سليمار ثم بنى قصر القصر هذا
+
+403
+00:37:17,220 --> 00:37:21,960
+كان عجيب غريب فالملك خيب انه انه اي حد ييجي سليمار
+
+404
+00:37:21,960 --> 00:37:25,360
+يبني مثل هذا القصر فاشفع حرماه من باب مصر لألا
+
+405
+00:37:25,360 --> 00:37:30,640
+يبدن لأحد مثل هذا يعني بعد ما بناله القصرقتله حتى
+
+406
+00:37:30,640 --> 00:37:36,960
+لا يبني مثله للآخرين ودرجة مثلا هذا جزاءه cinema
+
+407
+00:37:36,960 --> 00:37:42,300
+بيعمل معروف زي ال Amino group في الآخر بنرد نخليها
+
+408
+00:37:42,300 --> 00:37:48,180
+hydrogen حال الدنيا هذا على أي حال يعني احنا بنأمل
+
+409
+00:37:48,180 --> 00:37:51,400
+بنأمل انكوا تكونوا استمتعتوا بمساق الكيميا العضوية
+
+410
+00:37:51,400 --> 00:37:56,420
+بنعتذر شويه ان المساق كان رسمي لأنه كان فيه تصوير
+
+411
+00:37:57,870 --> 00:38:03,330
+لأ لأ لأ المساقات التانية صغيرة مش هذا كبير في
+
+412
+00:38:03,330 --> 00:38:06,790
+الجامعة هيك لازم يكون المساق إنما إذا في مساقات
+
+413
+00:38:06,790 --> 00:38:10,830
+بتاخدوها عشرين صفعة ده موضوع تاني ان شاء الله ربنا
+
+414
+00:38:10,830 --> 00:38:15,710
+يوفقكوا بالامتحان، الامتحان يوم التلاتة القادم وأن
+
+415
+00:38:15,710 --> 00:38:19,510
+يحشر الناس وضحا، ما أطيب أمنيات التوفير
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c06165d96029b64f3bed812e5c1d4112725f5a98
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_raw.srt
@@ -0,0 +1,1664 @@
+1
+00:00:08,560 --> 00:00:15,180
+بسم الله الرحمن الرحيم اليوم إن شاء الله بتكون
+
+2
+00:00:15,180 --> 00:00:20,020
+المحاضرة الأخيرة في هذا المساق وهي محاضرة سهلة
+
+3
+00:00:20,020 --> 00:00:28,550
+وبسيطة عن بعض تفاعلات ال Amiensطبعا سبق ان اتكلمنا
+
+4
+00:00:28,550 --> 00:00:35,230
+انه يعني شعرة شمشوم الجبار خلينا نقول اللي في ال
+
+5
+00:00:35,230 --> 00:00:42,110
+amines هي إيش زوج الإلكترونات يعني سر ال amines
+
+6
+00:00:42,110 --> 00:00:47,350
+زوج الإلكترونات طالما ال amines زي ما بتلاحظوا
+
+7
+00:00:47,350 --> 00:00:51,390
+مانا فيهم هذا الزوج من الإلكترونات إذا هم ممكن
+
+8
+00:00:51,390 --> 00:00:56,660
+يتفاعلوا can you kill your filesأي تفاعل أخدناه
+
+9
+00:00:56,660 --> 00:01:00,900
+بيلزمه الـ nucleophile الأمين ممكن يتفاعله على
+
+10
+00:01:00,900 --> 00:01:05,200
+سبيل المثال مثلا مع ال acid halides ممكن الأمين
+
+11
+00:01:05,200 --> 00:01:08,380
+ييجي يتفاعل اللي هو تفاعل ال substitution الشهير
+
+12
+00:01:08,380 --> 00:01:15,460
+لأنه هذا acid halide يهاجم بهذا الشكل ويطلط
+
+13
+00:01:16,310 --> 00:01:21,690
+الـ CR يعطينا الأمل الآن طالما الكلام مع الـ Acid
+
+14
+00:01:21,690 --> 00:01:28,770
+Chloride بيمشي إذا بالتأكيد موازقله تماماً لو كان
+
+15
+00:01:28,770 --> 00:01:32,770
+عنده مشتقة زي الـ Acid Chloride وتحديداً الـ E
+
+16
+00:01:32,770 --> 00:01:37,210
+Star أو الـ Anhydride يعني في كل الأحوال لو كانت
+
+17
+00:01:37,210 --> 00:01:41,530
+هذه RC double bond O O-ethyl هيعمل نفس التفاعل
+
+18
+00:01:41,530 --> 00:01:45,870
+ويطرد الـ O-ethyl لو كانت RC double bond OOC
+
+19
+00:01:45,870 --> 00:01:50,270
+double bond OR مثلاً unhydrate هيتفعل بنفس الطريقة
+
+20
+00:01:50,270 --> 00:01:55,070
+وهذا الكلام يعني لما بندرسه احنا بندرسه كتكرار
+
+21
+00:01:55,070 --> 00:01:58,210
+لأنه حقيقة لما خدنا تفاعل ال acid chlorides و
+
+22
+00:01:58,210 --> 00:02:02,990
+الesters و الunhydrates كنا ناخد تفاعلهم مع ال
+
+23
+00:02:02,990 --> 00:02:07,730
+amines تقريبا كل الأمثلة اللي هنا أمثلة متوازية
+
+24
+00:02:07,730 --> 00:02:12,400
+تماماانه في عندى هجوم و substitution انه في عندى
+
+25
+00:02:12,400 --> 00:02:16,300
+هجوم و substitution لحظة اللى بيتقن مبدأ بغض النظر
+
+26
+00:02:16,300 --> 00:02:20,580
+عن كبر الجزية انا بتعامل مع مبدأ زوج إلكترونات
+
+27
+00:02:20,580 --> 00:02:26,560
+بيهاجم على ال positive carbon بيطرد ايش ال CL طبعا
+
+28
+00:02:26,560 --> 00:02:31,000
+بالتأكيد بدكوا تكونوا متذاكرين ان هذه ال amines لو
+
+29
+00:02:31,000 --> 00:02:35,680
+كانت بتهاجم على الديهيد او كيتون هتعمل ابدال
+
+30
+00:02:38,930 --> 00:02:42,570
+إيش هتعمل؟ addition هتعمل addition و تحولها إلى
+
+31
+00:02:42,570 --> 00:02:46,370
+watch و ال addition ممكن يتبع ب elimination هاي
+
+32
+00:02:46,370 --> 00:02:51,150
+هنا في مثال مثلا تفاعل أمين مع anhydride بالتأكيد
+
+33
+00:02:51,150 --> 00:02:55,410
+برضه مرة تانية الأمين بده يهاجم على ال CW bond O و
+
+34
+00:02:55,410 --> 00:03:01,030
+بده يطرد المجموعة هذه كلها فجميع هذه التفاعلات
+
+35
+00:03:01,030 --> 00:03:06,550
+الحقيقة هي تفاعلاتمتوازية تفاعلات substitution
+
+36
+00:03:06,550 --> 00:03:12,910
+بهذه التفاعلات the amines act as enucleophile
+
+37
+00:03:24,260 --> 00:03:28,380
+السؤال ممكن يصير، لو كان هذا un-symmetrical، يعني
+
+38
+00:03:28,380 --> 00:03:32,020
+نفترض أن هذه كانت مثل وهذه فنل، بده يروح هنا أو
+
+39
+00:03:32,020 --> 00:03:36,020
+هنا، غالباً هيروح على الجهتين و هيعطي ناتجين، بأي
+
+40
+00:03:36,020 --> 00:03:41,080
+نسب بيعتمد على تجربة؟بس لو كان هذا غير متماثل،
+
+41
+00:03:41,080 --> 00:03:43,980
+يعني السيد أبو البون تقول هنا نفترض مثل الهانافينل
+
+42
+00:03:43,980 --> 00:03:48,760
+ممكن جزء يتفاعل على هذه وجزء على هذه وبيطلع نوات
+
+43
+00:03:48,760 --> 00:03:53,480
+يجيب نسب مختلفة لا تحدد إلا بإيش؟ إلا بالتجربة،
+
+44
+00:03:53,480 --> 00:03:56,200
+لأنه في النهاية الكيمياء بتضال زي ما حكينا كتير
+
+45
+00:03:56,200 --> 00:04:04,880
+علم تجريبي، علم تجريبي، واضح؟الان اخر تفاعل ل ال
+
+46
+00:04:04,880 --> 00:04:10,720
+aromatic amines عادة بيكون فعال هو تفاعل مهم جدا
+
+47
+00:04:10,720 --> 00:04:15,360
+ان ال aromatic amines اللي هو الانيلينو مشتقاته
+
+48
+00:04:15,360 --> 00:04:22,420
+الانيلينو مشتقاته بيتفاعلوا مع ال nitrous acid ال
+
+49
+00:04:22,420 --> 00:04:27,560
+nitrous acid اذا بتذكروا HNO2 ليش؟ اتذكروا ال
+
+50
+00:04:27,560 --> 00:04:36,040
+nitric acid ايش كان؟HNO3 Nitric Acid HNO2 Nitrous
+
+51
+00:04:36,040 --> 00:04:40,660
+اللي بيكون أعلى في ال Oxygen Nitric اللي بيكون أقل
+
+52
+00:04:40,660 --> 00:04:46,880
+Nitrous هذا الكلام سبق مرة عليكم الخلاصة ال
+
+53
+00:04:46,880 --> 00:04:50,400
+aromatic amines زي ال Aniline بتفعل مع ال Nitrous
+
+54
+00:04:50,400 --> 00:04:57,830
+Acid في وجود HCl بيعطونا أملاحبيكون سرعة البنزين
+
+55
+00:04:57,830 --> 00:05:02,470
+N2 plus Cl minus هذه عبارة عن أيونين يعني هذا
+
+56
+00:05:02,470 --> 00:05:09,570
+لحاله هيك بيكون plus وجنبه Cl minus زي Na Cl
+
+57
+00:05:09,570 --> 00:05:16,300
+تذكروا Na إيش بيكونplus CL minus نفس الفكرة إذا
+
+58
+00:05:16,300 --> 00:05:22,560
+NACL is a salt و هذا salt موازي له تماما plus
+
+59
+00:05:22,560 --> 00:05:27,040
+minus plus minus إذا أنا بحكي عن salt الآن هذا ال
+
+60
+00:05:27,040 --> 00:05:32,280
+salt في كام نيتروجينة؟ تنتين إيش اسم غاز
+
+61
+00:05:32,280 --> 00:05:37,840
+النيتروجين غير النيتروجين؟ لأ غير النيتروجين
+
+62
+00:05:37,840 --> 00:05:39,720
+الازوت
+
+63
+00:05:40,940 --> 00:05:44,640
+وعشان يقطعون البيئة مرات لما بيقولوا انه في أكاسيد
+
+64
+00:05:44,640 --> 00:05:49,800
+نيتروجين بتلوث الجو بيقولوا أكاسيد الأزوت وبناء
+
+65
+00:05:49,800 --> 00:05:53,320
+على ذلك في كتير في التسميات لما بدنا نختصر التعبير
+
+66
+00:05:53,320 --> 00:05:57,680
+عن ال nitrogen في الكيبية الحلقية بنستعمل بدل كلمة
+
+67
+00:05:57,680 --> 00:06:02,220
+nitrogen أزا أزا يعني نيتروجين، di-aza يعني
+
+68
+00:06:02,220 --> 00:06:06,140
+نيتروجين تاني، tri-azaيعني تلت نيتروجينات يعني
+
+69
+00:06:06,140 --> 00:06:09,240
+مثلا لما بدنا نسمي مركب فيه تلت نيتروجينات وحلقة
+
+70
+00:06:09,240 --> 00:06:15,140
+خمسية بنقول try as all معناه حلقة خمسية فيها تلت
+
+71
+00:06:15,140 --> 00:06:21,340
+نيتروجينات فكلمة as مرتبطة بإيش؟ من نيتروجين is
+
+72
+00:06:21,340 --> 00:06:27,500
+it؟ الآن هذا بيسموه die as لأنه فيه تنتين ولأنه
+
+73
+00:06:27,500 --> 00:06:35,990
+موجب الأيون الموجب إيش نهايته؟ onion والسالبإيت ..
+
+74
+00:06:35,990 --> 00:06:41,710
+إيت وولاد عمها إيت
+
+75
+00:06:41,710 --> 00:06:46,770
+وولاد عمها، إيش ولاد عم ال إيت؟ لأ ال أويتها دي
+
+76
+00:06:46,770 --> 00:06:50,550
+كانت تبعت ال E star لأ ال إيت نفسها مش هي لل أيون
+
+77
+00:06:50,550 --> 00:06:56,730
+السالب، و إيش كمان بيجي لل أيون السالب؟ ايت ..
+
+78
+00:06:56,730 --> 00:07:03,970
+إنتوا اتذكروا ال .. لما يكون عندكوا كلوريتمش فيه
+
+79
+00:07:03,970 --> 00:07:11,190
+chloride؟ برضه ال-ite ايون سالب نيتريت سالب نيتريت
+
+80
+00:07:11,190 --> 00:07:16,930
+سالب في ال chloride و ال chloride ايش كمان عندكم؟
+
+81
+00:07:16,930 --> 00:07:24,310
+بير اكلوريت و hypo اكلوريت كل هدول السالبين يعني
+
+82
+00:07:24,310 --> 00:07:28,430
+ال بير اكلوريت و ال .. و ال chloride و ال
+
+83
+00:07:28,430 --> 00:07:33,150
+hypochlorite كلها ايوناتسالبة لكن بشكل عام لما
+
+84
+00:07:33,150 --> 00:07:37,670
+يكون عندى بس ايون واحد يعني زي ال acetate مافيش
+
+85
+00:07:37,670 --> 00:07:41,910
+غير شكل واحد في ال oxygen اللى مستعمل اكتر اللى هو
+
+86
+00:07:41,910 --> 00:07:46,570
+الاش it لكن لما بصير عندى زيادة ونقص في عدد ال
+
+87
+00:07:46,570 --> 00:07:51,630
+oxygen ممكن نستعمل per it, it, it, it, it
+
+88
+00:07:54,800 --> 00:07:58,180
+فشوية احنا بنضل نطلع عن الموضوع بس بنذكركم في
+
+89
+00:07:58,180 --> 00:08:00,960
+أشياء في الكيميا العامة، فعشان هيك هذا المركب
+
+90
+00:08:00,960 --> 00:08:06,020
+بيسموه بنزين، هي بنزين داياز يعني في نيتروجنتين
+
+91
+00:08:06,020 --> 00:08:11,640
+اونيوم، يعني ايون موجب، salt، اشوة كلورايت، فبصير
+
+92
+00:08:11,640 --> 00:08:14,480
+كل هذا اسمه بنزين دايازونيوم
+
+93
+00:08:18,580 --> 00:08:23,040
+العائلة هذه كلها من المُركّبات بيسموها Diazonium
+
+94
+00:08:23,040 --> 00:08:27,520
+salts أو Diazonium compounds أو أملاح الـDiazonium
+
+95
+00:08:27,520 --> 00:08:35,750
+الآن يا تورا هل أملاح الـDiazonium هذه مفيدة؟بحد
+
+96
+00:08:35,750 --> 00:08:42,310
+ذاتها مش مفيدة وبتتكون ما بين 0 إلى 5 درجات مهوية
+
+97
+00:08:42,310 --> 00:08:45,510
+زي ما انتوا شايفين ولو الحرارة ارتفعت عن هيك
+
+98
+00:08:45,510 --> 00:08:50,770
+بتخرب، بتتكسر طب هوين الفائدة بتاعتها؟ الفائدة
+
+99
+00:08:50,770 --> 00:08:55,390
+بتاعتها مش بذاتها الفائدة تبعت ال diazonium salts
+
+100
+00:08:55,390 --> 00:09:01,090
+هذه إنها بتتحول إلى مراكبات تانية يعني هي bridge
+
+101
+00:09:01,090 --> 00:09:07,480
+للتحول أو جسرللتحول حلقة واصل اسمها زي ما بدكم
+
+102
+00:09:07,480 --> 00:09:13,580
+للتحول إلى مجموعة من المركبات التانية تحضر من
+
+103
+00:09:13,580 --> 00:09:18,400
+خلالها يعني هي نقطة انطلاق لإش جديد بس هي بحد
+
+104
+00:09:18,400 --> 00:09:23,180
+ذاتها مش كتير مهمة لأنها مش ثابتة تتكون أثناء
+
+105
+00:09:23,180 --> 00:09:28,300
+التفاعل لو الحرارة ارتفعت بتخرب لكن هي نقطة إش
+
+106
+00:09:29,260 --> 00:09:33,240
+انطلاق الان عشان تشوفوا نقطة انطلاق اتطلعوا على
+
+107
+00:09:33,240 --> 00:09:37,560
+هذا ال slide هاي نحط لكوا diazonium salt ومحضرين
+
+108
+00:09:37,560 --> 00:09:42,280
+منها كام مركب واحد اتنين تلاتة اربع خمسة ستة سبعة
+
+109
+00:09:42,280 --> 00:09:46,760
+كل هدولة بنحضرهم من وين من ال diazonium salt وهي
+
+110
+00:09:46,760 --> 00:09:52,500
+معناه ان هي تعتبر نقطة انطلاق واضح؟فعلى سبيل
+
+111
+00:09:52,500 --> 00:10:00,000
+المثال، ممكن الـDiazolium salt الفاعل مع HCl وكبر
+
+112
+00:10:00,000 --> 00:10:05,940
+كلوري يبدل محل الـDiazolium chloride، واضح؟ هذا
+
+113
+00:10:05,940 --> 00:10:09,120
+التفاعل بالمناسبة يسموه Sand Meier reaction
+
+114
+00:10:11,940 --> 00:10:18,400
+Sandmeier أكيد إن البد المحل الانتوا إيش CL طبعا
+
+115
+00:10:18,400 --> 00:10:21,700
+البعض هيقول إنه ما إحنا بنقدر نحضر ال CL من
+
+116
+00:10:21,700 --> 00:10:26,880
+البنزين بألومينيوم كلورايد و .. و كلورين بالعكس
+
+117
+00:10:26,880 --> 00:10:32,480
+هذا التحضير أسهل لسبب بسيط إنه مرات أنتوا بتاخدوا
+
+118
+00:10:32,480 --> 00:10:40,170
+التفاعل بدون ما تحسوا خليني أقول بإيشبغلبته، يعني
+
+119
+00:10:40,170 --> 00:10:45,570
+لما نيجي يقول CL2 ألومنيوم إكلورايد زي اللي بيحكي
+
+120
+00:10:45,570 --> 00:10:50,530
+جملة مثلا امبارح يمكن كان ذكرا النكبة كل ناس بيجي
+
+121
+00:10:50,530 --> 00:10:55,730
+ويقولوا سانو حرروا فلسطين و تحرروا فلسطين لعبة ولا
+
+122
+00:10:55,730 --> 00:10:59,510
+الكلمة لها موراقها لحظو انا مثلا لما تقولوا احنا
+
+123
+00:10:59,510 --> 00:11:06,490
+بنفعل مع CL2 ألومنيوم إكلورايد الـCL2 غاز وغاز سام
+
+124
+00:11:07,590 --> 00:11:14,050
+معنى ذلك لو أنا بدى أستعمله، بدى حذر لما باشتريه
+
+125
+00:11:14,050 --> 00:11:21,350
+في استوانات، غاز مؤكسدلما بدي أحطله منظم للأنبوبة
+
+126
+00:11:21,350 --> 00:11:25,790
+الغاز مابحطلوش منظم عادي بياكله خلال يوم منظم
+
+127
+00:11:25,790 --> 00:11:30,510
+انحاس .. إله منظم بشتريه خصوصي بمبالغ غالية جدا ..
+
+128
+00:11:30,510 --> 00:11:35,710
+واضح؟ لما بدي أمشي بمشي بمواسير معدنية خاصة مش في
+
+129
+00:11:35,710 --> 00:11:40,710
+plastic و بعد يومين قب اللي هو .. واضح؟ و بنفس
+
+130
+00:11:40,710 --> 00:11:44,050
+الوقت لما بدي أشتغل بدي شفات جو يشفط كل الغاز اللي
+
+131
+00:11:44,050 --> 00:11:49,830
+بيزيد لإن أنا بتعامل مع غاز .. ساممظبوط ولا لأ؟
+
+132
+00:11:49,830 --> 00:11:55,290
+مرة صار في القردن هيك اتسرب غاز .. غاز كلورين كل
+
+133
+00:11:55,290 --> 00:11:59,770
+مدينة الزرقه شردت و نزل ايامها الملك حسين في الليل
+
+134
+00:12:00,040 --> 00:12:07,220
+تابع الحادث فهنا أنا بأتعامل مع غاز و بأتعامل مع
+
+135
+00:12:07,220 --> 00:12:13,460
+غاز سام فما تتوقعوش أن الموضوع التعامل معاه بسهولة
+
+136
+00:12:13,460 --> 00:12:16,860
+اللي أنتم بتخيلوها ال aluminum chloride ال
+
+137
+00:12:16,860 --> 00:12:21,720
+aluminum chloride Lewis acidتمام؟ بناء على ذلك هو
+
+138
+00:12:21,720 --> 00:12:26,660
+شريه جدا للميّه وانا بوزنه .. وانا بوزنه و بنجله
+
+139
+00:12:26,660 --> 00:12:30,560
+من مكان لمكان بياخد من ميّه الجو و باتفاعل معها
+
+140
+00:12:30,560 --> 00:12:36,020
+تخيل لحد وين؟وبالتالي ممكن يخرب يعني بده شروط
+
+141
+00:12:36,020 --> 00:12:39,660
+شديدة من الجفاف أثناء ما بكون بشتغل في المختبر
+
+142
+00:12:39,660 --> 00:12:45,220
+فعمليا لا هذا مريح في التعامل ولا هذا مريح في
+
+143
+00:12:45,220 --> 00:12:50,360
+التعامل يعني بده احتياطات مخبرية مش بس .. مش
+
+144
+00:12:50,360 --> 00:12:56,400
+بسهولة الكتيرة يعني تتخيلوا التعامل معاه طبعا مرات
+
+145
+00:12:56,400 --> 00:12:59,160
+كتير لما احنا بنشرحلكم نكتبلكم المعادلة وما
+
+146
+00:12:59,160 --> 00:13:03,100
+بنجيبلكم مش هذه الأشياء لسبب بسيط أن انتوا بتظلوا
+
+147
+00:13:04,620 --> 00:13:07,940
+general organic course لكن لو نزلتوا على المعمل
+
+148
+00:13:07,940 --> 00:13:11,100
+الكلام اللي بتفكروا بنعمله بثانية حتى تكتشفوا أنه
+
+149
+00:13:11,100 --> 00:13:14,440
+بدكوا أسبوع تجهزوا لتشتريوا الأنبوبة و الغاز و
+
+150
+00:13:14,440 --> 00:13:20,000
+تظبطوا الشفافات و تشتريوا المنظم ليست عملية سهلة و
+
+151
+00:13:20,000 --> 00:13:23,620
+بنت دقيقة فهذه العملية اللي لسه بستعمل فيها على
+
+152
+00:13:23,620 --> 00:13:28,500
+HCL و cover chloride تعتبر أسهل إليه من أن أستعمل
+
+153
+00:13:28,500 --> 00:13:32,340
+غاز سام واضح؟
+
+154
+00:13:32,340 --> 00:13:39,590
+هذهأحدى التفاعلات نشوف تفاعل تاني موازي التفاعل
+
+155
+00:13:39,590 --> 00:13:44,770
+التاني الموازي تقريبا أن نضع PR هذه موازية تماما و
+
+156
+00:13:44,770 --> 00:13:52,370
+بنفس الاسم الفاعل HPR مع كبر بروميد بحط لنا إيش ال
+
+157
+00:13:52,370 --> 00:13:58,970
+PR تفاعل تالت أن نضع ال CN برضه مع كبر سيانايت
+
+158
+00:13:58,970 --> 00:14:06,940
+بنشيل ال N2 و بنضعالـ CN و بنحط إيش مكانها الـ CN
+
+159
+00:14:06,940 --> 00:14:13,980
+برضه هي التفاعل التالت تفاعل رابع إننا نحط الـ U
+
+160
+00:14:13,980 --> 00:14:21,020
+يعني هيحطينا كل الـ halogens إننا
+
+161
+00:14:21,020 --> 00:14:27,120
+نحط الـ U باستعمال KI تفاعل خامس بحط ال floor
+
+162
+00:14:27,120 --> 00:14:32,500
+باستعمال HPF4 مع حرارة لاحظوا ال halogen ال floor
+
+163
+00:14:34,410 --> 00:14:41,090
+كلور، إبران، يود، كلهم ممكن أحطهم محل ايش؟ محل
+
+164
+00:14:41,090 --> 00:14:44,130
+الديازونيوم سولت و سيقان، إيش قعدت بيجي سؤالك؟
+
+165
+00:14:44,130 --> 00:14:47,590
+السيقان سبب الانتموجة؟ أكيد طب إحنا ممكن نبدلها
+
+166
+00:14:47,590 --> 00:14:50,430
+بالسيناد السلب، ممكنش الانتموجة في محل الموجة،
+
+167
+00:14:50,430 --> 00:14:54,990
+السرب في محل السلب؟ يعني ماقلناش نبدلها بالسيناد
+
+168
+00:14:54,990 --> 00:14:57,750
+السلب ولا حكينا عن الميكانيزم اللي بتم فيها
+
+169
+00:14:57,750 --> 00:15:02,880
+الإبدال، أنت حكيت من عندك، مش أناانت قلت انك بدك
+
+170
+00:15:02,880 --> 00:15:08,960
+تبدن ..الان هذا كله HCl مع كبر كلورايد او KCl مع
+
+171
+00:15:08,960 --> 00:15:12,540
+كبر كلورايد هذا كله بيجيب CL positive زي ما كنت
+
+172
+00:15:12,540 --> 00:15:15,760
+انا مع الكلورين و الالومنيوم كلورايد، شو اللي كنت
+
+173
+00:15:15,760 --> 00:15:24,400
+اتعامل معاه؟ اه okay الان في تفاعل كتير مهم، تفاعل
+
+174
+00:15:24,400 --> 00:15:29,340
+تحضير الفينوللاحظوا ان الفينول يمكن المرة الماضية
+
+175
+00:15:29,340 --> 00:15:34,500
+سابقة حكيتلكوا مابقدرش أحضره مباشرة لأنه لو بدي
+
+176
+00:15:34,500 --> 00:15:38,420
+أجيب OH- على البنزينة ممكن أنه ينفعش minus على
+
+177
+00:15:38,420 --> 00:15:42,860
+minus طبعا كيف بنحضره؟ بنحضره من ديازونيوم سولت مع
+
+178
+00:15:42,860 --> 00:15:46,440
+ميه و حامض يعني هذا الديازونيوم سولت لو حاطينا
+
+179
+00:15:46,440 --> 00:15:51,940
+عليه ميه عليها نقاط من الحامض بيتحول إلى فينولإذا
+
+180
+00:15:51,940 --> 00:15:56,280
+لو ده نيجي نسألكم عن الفينول ماحدش يكتب لبنزين زاد
+
+181
+00:15:56,280 --> 00:16:01,660
+OH minus ولا بنزين زاد NaOH لأ لازم تكون ال
+
+182
+00:16:01,660 --> 00:16:06,660
+diazonium salt ال diazonium salt من وين إجا؟ من ال
+
+183
+00:16:06,660 --> 00:16:12,950
+aniline ال anilineمن ال nitro benzene و ال nitro
+
+184
+00:16:12,950 --> 00:16:16,650
+benzene من ال benzene فكأنه صار عنده يعني سلسلة
+
+185
+00:16:16,650 --> 00:16:22,070
+benzene, nitro benzene بال reduction بصير aniline،
+
+186
+00:16:22,070 --> 00:16:25,270
+ال aniline بال sodium nitrite أو ال nitrous acid
+
+187
+00:16:25,270 --> 00:16:30,270
+بصير diazonium salt، ال diazonium salt مع H plus,
+
+188
+00:16:30,330 --> 00:16:36,770
+H2O بصير phylonالشغلة الأخيرة أنه احنا ممكن محل ال
+
+189
+00:16:36,770 --> 00:16:43,310
+N2 plus هذه ممكن محل ال N2 plus هذه نحط هيدروجين
+
+190
+00:16:43,310 --> 00:16:50,010
+ممكن محل ال N2 plus اللي موجودة عندنا هنا نحط
+
+191
+00:16:50,010 --> 00:16:58,510
+هيدروجين واضح؟ إذا ال diazonium salt أهميته أن هو
+
+192
+00:16:58,510 --> 00:17:06,410
+يمثل نقطةنقطة انطلاق لتحضير أشياء جديدة، نقطة
+
+193
+00:17:06,410 --> 00:17:11,310
+انطلاق لتحضير أشياء جديدة، هذه الأشياء ممكن تكون
+
+194
+00:17:11,310 --> 00:17:16,790
+halogens، CN، ممكن تنسوا مثلا إن ال CN هو نقطة
+
+195
+00:17:16,790 --> 00:17:22,190
+انطلاق لتحضير إيش؟
+
+196
+00:17:22,190 --> 00:17:31,690
+أخدناها، الحامض ال CN يبقى H plus oroh minus و
+
+197
+00:17:31,690 --> 00:17:40,430
+بعدين h plus على خطوتين كان يعطينا يعني انا لما
+
+198
+00:17:40,430 --> 00:17:44,130
+بدأ اجي اقولكوا حضرولي حامض كيف بدكوا تحطوا الحامض
+
+199
+00:17:44,130 --> 00:17:52,230
+انطلاقكوا من ال cn واضح؟ بنزوك أسد بنزوك أسد مثلا
+
+200
+00:17:52,230 --> 00:17:58,140
+نقطة الانطلاق شو بده تكون ال cnنقطة الإنطلاق
+
+201
+00:17:58,140 --> 00:18:04,620
+تبعتكم بدأ تكون الـ CL واضح؟ الآن بحاول أعطيكم
+
+202
+00:18:04,620 --> 00:18:08,760
+مثال أو اتنين تأكيديات على الاستفادة من هذه
+
+203
+00:18:08,760 --> 00:18:11,840
+الطريقة في ال organic synthesis لأن هذا موضوع
+
+204
+00:18:11,840 --> 00:18:18,460
+دائما نسأل عنه لكن خلّينا ناخد آخر slide موجودة
+
+205
+00:18:18,460 --> 00:18:24,040
+معناأخر slide أن الـ diazonium salts نفسها ممكن
+
+206
+00:18:24,040 --> 00:18:28,480
+تتفاعل مع الفينول، هنا بتكون تلاحظوا أن ال
+
+207
+00:18:28,480 --> 00:18:33,280
+diazonium salt موجبة، الفينول وين بيودّي؟ على موقع
+
+208
+00:18:33,280 --> 00:18:39,740
+Orthoو موقع بارا يعني لو جيبت فين والجاهز ال OH
+
+209
+00:18:39,740 --> 00:18:44,680
+كsubstituent سبقنا حكينا انا activating group و
+
+210
+00:18:44,680 --> 00:18:48,700
+orthobara directing group فلما نيجي نفعلها مع موجة
+
+211
+00:18:48,700 --> 00:18:52,220
+بهذا الموجة بوين بنتوقع ييجي يهاجم على ال بارا و
+
+212
+00:18:52,220 --> 00:18:56,800
+على ال orthobara لو أخدنا ناتجالبارا لو أخدنا ناتج
+
+213
+00:18:56,800 --> 00:18:59,880
+تبع البارا بيصير عندنا هذا المركب اللي هو ال
+
+214
+00:18:59,880 --> 00:19:06,200
+phenol, phenol, phenol هذه عبارة عن مركبات سبغات
+
+215
+00:19:06,200 --> 00:19:08,900
+هي السبغات الملونة اللي أنتوا بتشوفوها الصفرة
+
+216
+00:19:08,900 --> 00:19:17,140
+والبردجانية بنسميها diazo dyes سبغاتالنيتروجين
+
+217
+00:19:17,140 --> 00:19:22,420
+اللي هو الثنائي داي ازو ايش يعني داي ازو يعني وجود
+
+218
+00:19:22,420 --> 00:19:29,220
+نيتروجين تاني داي صبغة فالصبغات اللي فيها نيتروجين
+
+219
+00:19:29,220 --> 00:19:33,360
+تاني طبعا في صبغات من مركبات تانية مختلفة تماما في
+
+220
+00:19:33,360 --> 00:19:37,040
+الشكل ومشكلة بصراحة
+
+221
+00:19:38,970 --> 00:19:47,960
+مشكلة الصباغات حقيقة أنه للأسف الشديد طبعابدها نوع
+
+222
+00:19:47,960 --> 00:19:53,900
+من الحذر يعني بيشتغلوا صبغة بنزلوها على السوق
+
+223
+00:19:53,900 --> 00:20:00,680
+باستعملوها الناس و بعد هيك بيثبت انه لها كتير
+
+224
+00:20:00,680 --> 00:20:05,360
+تأثيرات ضارة على الشعر و ما إلى ذلك خصوصا يعني
+
+225
+00:20:05,360 --> 00:20:08,380
+الأبحاث الكتيرة اللي هي الشغل اللي بيشتغلون نساء
+
+226
+00:20:08,380 --> 00:20:13,380
+اللي بيكتروا من السبق كتير معرضين كتير بشكل كبير
+
+227
+00:20:13,380 --> 00:20:18,540
+جدالأ cancer و ما إلى ذلك يعني اليوم الجيل القديم
+
+228
+00:20:18,540 --> 00:20:23,200
+من الصبغات مثلا كان من مركبات pyrazoles في الغالب
+
+229
+00:20:23,200 --> 00:20:29,840
+معظمها pyrazoles دراسات مهولة .. دراسات مهولة طلعت
+
+230
+00:20:29,840 --> 00:20:34,340
+أنه هذه المركبات carcinogenic طبعا الشركات بتبدأ
+
+231
+00:20:34,340 --> 00:20:37,920
+تعرف قبل الناس يعني نفس الشركات اللي بتعمل الصبغات
+
+232
+00:20:37,920 --> 00:20:42,820
+بتبدأ تعرففينها لما تعرف شو بدها تسوي بتروح بتحضر
+
+233
+00:20:42,820 --> 00:20:46,320
+أجيال جديدة، طب و المحضر عندها و المصانع اللي
+
+234
+00:20:46,320 --> 00:20:50,860
+شغالة و ما إلى ذلك و بنزل الجديم عرض خدوا في
+
+235
+00:20:50,860 --> 00:20:54,540
+العالم الثالث و الرابع و الخامس بيروحوا ببيعوهم كل
+
+236
+00:20:54,540 --> 00:20:59,810
+الجديم و بيعملواأشياء جديدة، يعني الـ Pyrazoles من
+
+237
+00:20:59,810 --> 00:21:05,310
+حوالي 15 سنة أو أقل بدوا يستعملوها بالـ Triazines،
+
+238
+00:21:05,310 --> 00:21:08,210
+يعني بدل ما هي حلقات خمسية بنيتروجينتين صار حلقات
+
+239
+00:21:08,210 --> 00:21:13,970
+ستاسية بتلت نيتروجينات، لكن مين اللي عنده تفاصيل
+
+240
+00:21:13,970 --> 00:21:20,370
+العمل هذا اللي قاعد بنشغل؟ الشركات، الشركات، ولذلك
+
+241
+00:21:20,370 --> 00:21:25,120
+هذه المناطق كلها تعتبر مناطقأقل ما يُقال فيها أنه
+
+242
+00:21:25,120 --> 00:21:29,140
+تحت التجربة، لكن ثابت بحالات كثيرة أنه في شغلات
+
+243
+00:21:29,140 --> 00:21:33,960
+منها فعلًا كانت بمعنى الكلمة carcinogenic وسُحِبت
+
+244
+00:21:33,960 --> 00:21:37,980
+من الأسواق، عدمين اللي اتبع، على أي حال، هذا نوع
+
+245
+00:21:37,980 --> 00:21:41,340
+من الصبغات اللي بنحضره احنا اللي هو الـdiazodide
+
+246
+00:21:41,340 --> 00:21:46,450
+اللي هي الصبغاتاللي فيها two nitrogels هذي yellow
+
+247
+00:21:46,450 --> 00:21:52,370
+leaflets اللي أول ما بتتكون بتتكون يعني بشكل أصفر
+
+248
+00:21:52,370 --> 00:21:56,470
+high melting point اللي هو بندوّب شوية بethanol أو
+
+249
+00:21:56,470 --> 00:22:06,050
+إيش هو بنحصل على هالألوان ويا ما أحلاها لكن على
+
+250
+00:22:06,050 --> 00:22:12,290
+أي حال خلّينا يمكن نظل محافظين على الإضاءة إذا
+
+251
+00:22:12,290 --> 00:22:13,450
+بنعمل زي هيك
+
+252
+00:22:18,620 --> 00:22:24,100
+بإمكاننا الفكرة الأخيرة نعطيكوا عليها .. نعطيكوا
+
+253
+00:22:24,100 --> 00:22:29,700
+عليها بعض الأمثلة مثلا لو جيبنالكم أنه بدنا
+
+254
+00:22:29,700 --> 00:22:34,300
+اتحضرولنا هذا
+
+255
+00:22:34,300 --> 00:22:35,480
+المركب
+
+256
+00:22:47,410 --> 00:22:54,010
+ليش طفل هذا؟ لو بدنا نحضر هذا و نبتدأ من البنزين
+
+257
+00:22:54,010 --> 00:23:00,730
+نحضر هذا و نبتدأ من إيش؟ من البنزين لاحظوا أن
+
+258
+00:23:00,730 --> 00:23:05,410
+انتوا اتعلمتوا .. اتعلمتوا تحضير مجموعة المثل
+
+259
+00:23:05,410 --> 00:23:14,740
+بنقدر نحط ال .. بنقدر نحط المثل من خلالCH3Cl لكن
+
+260
+00:23:14,740 --> 00:23:18,900
+لو قلنا مجموعة الحامض أخدتوا الطريقة نحط الحامض أه
+
+261
+00:23:18,900 --> 00:23:25,060
+إذا المفروض وانتوا بتفكروا تقولوا احنا بنرجع
+
+262
+00:23:25,060 --> 00:23:29,100
+بالجوا برس معادة السهم بهذه الطريقة شايفين هذا
+
+263
+00:23:29,100 --> 00:23:33,900
+السهم هذا السهم اللي بنقول عنه احنا سهم ال retro
+
+264
+00:23:33,900 --> 00:23:40,620
+synthesis يعني انا لو كنتretro synthesis يعني لو
+
+265
+00:23:40,620 --> 00:23:45,680
+كنت برجع برجوع المفروض ان اقول ان ال COOH من وين
+
+266
+00:23:45,680 --> 00:23:58,000
+جاية من ال CNI كأنه صار عندك CH3 و CN ماشي بداجة
+
+267
+00:23:58,000 --> 00:24:04,760
+اقول ال CN من وين جاية واضح؟
+
+268
+00:24:06,910 --> 00:24:17,610
+طوي لسه أخدنا ال CN من وين جاية؟ من النيازو ال 2
+
+269
+00:24:17,610 --> 00:24:32,890
+plus، مظبوط؟ النيازو من وين جاية؟ من ال N H 2 ممكن
+
+270
+00:24:32,890 --> 00:24:38,950
+في الأصل ال 9يا تورا بقدر انا اكون بدي بالمثل و
+
+271
+00:24:38,950 --> 00:24:43,250
+احط ال N-H2 ما هي ال N-H2 من وين بتيجي؟ من ال
+
+272
+00:24:43,250 --> 00:24:54,170
+Nitro يعني كأنه هذا بدي يكون CH3 و NO2 CH3 و NO2
+
+273
+00:24:54,170 --> 00:24:58,770
+طيب هي لسه مازال عندى مجموع تان CH3 و NO2 مين اللي
+
+274
+00:24:58,770 --> 00:25:04,530
+بدي أحطها بالأول؟ لو بديك بالمثل وين هتودى؟
+
+275
+00:25:05,280 --> 00:25:10,720
+Orthopara لو بدت بالنيترو ميدا، اذا انا المفروض لو
+
+276
+00:25:10,720 --> 00:25:20,880
+بدي ابدأ اكون بدء من النيترو on
+
+277
+00:25:20,880 --> 00:25:24,420
+O2 و بعدين النيترو من وين بجيبه؟
+
+278
+00:25:26,910 --> 00:25:33,670
+من البنزين الان كل هذا ارجع بالتفكير عشان ذلك احنا
+
+279
+00:25:33,670 --> 00:25:38,790
+ايش بنسميه retro synthesis لو كنت عاد بدي ابدأ
+
+280
+00:25:38,790 --> 00:25:42,750
+اعمل المسألة من اول و جديد بقول بنزين ايش اللي بدي
+
+281
+00:25:42,750 --> 00:25:48,370
+يخليه نيترو بصير احط الاسم زي هيك مديش اعيد كتابة
+
+282
+00:25:48,370 --> 00:25:52,590
+كل إشي بس انتوا المفروض تعدوا بدي احطله HNO3
+
+283
+00:26:00,060 --> 00:26:08,860
+النيترو لما بدى حاوله النيترو
+
+284
+00:26:08,860 --> 00:26:13,840
+لما بدى حاوله النيترو لما بدى حاوله النيترو لما
+
+285
+00:26:13,840 --> 00:26:15,600
+بدى حاوله النيترو لما بدى حاوله النيترو لما بدى
+
+286
+00:26:15,600 --> 00:26:16,780
+حاوله النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+287
+00:26:16,780 --> 00:26:17,560
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+288
+00:26:17,560 --> 00:26:20,580
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+289
+00:26:20,580 --> 00:26:23,200
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+290
+00:26:23,200 --> 00:26:23,360
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+291
+00:26:23,360 --> 00:26:23,380
+النيترو لما بدى حاوله النيترو لما بدى حاوله
+
+292
+00:26:23,380 --> 00:26:28,960
+النيترو لما بدىDiazonium HNO2
+
+293
+00:26:28,960 --> 00:26:35,580
+مرات من اللي بيستعملوا ال HNO2 بيستعملوا ال sodium
+
+294
+00:26:35,580 --> 00:26:38,720
+nitrite مع حمض ال sodium nitrite مع حمض بتفعل و
+
+295
+00:26:38,720 --> 00:26:45,200
+بتطلع HNO2 يعني لو قولنا HNO2 ولا قولنا NA NO2
+
+296
+00:26:45,200 --> 00:26:51,150
+زائد H plus هدولة معناهم برضه HNO2لأن ال sodium
+
+297
+00:26:51,150 --> 00:26:55,730
+nitrate بتفعل مع الحمض بتطلع HNO2 مش المشكلة okay
+
+298
+00:26:55,730 --> 00:27:06,990
+ال L2 plus كي بدأ تصير CNO KCN كبرتو ال CN ايش
+
+299
+00:27:06,990 --> 00:27:13,470
+اللي بيبقى يخليها COH ملاحظين؟
+
+300
+00:27:19,510 --> 00:27:25,330
+فهذا اللي هو يعني مثال على ال retro synthesis كيف
+
+301
+00:27:25,330 --> 00:27:30,910
+الأمور اللي واحد بتعامل معها بتعامل معها بهدوء
+
+302
+00:27:30,910 --> 00:27:34,550
+ممكن نشرح كمان مثال واحد أخير
+
+303
+00:27:44,680 --> 00:27:49,080
+طبعا في كتير أشياء أسهل من هيك و هذا مش صعب بس
+
+304
+00:27:49,080 --> 00:27:56,520
+متدرج لأ متدرج مش صعب مش في ولا خطوة صعبة بس متدرج
+
+305
+00:27:56,520 --> 00:28:01,320
+ناخد
+
+306
+00:28:01,320 --> 00:28:07,460
+كمان مثال ناخد كمان مثال لو جيبناكوا هذا المركب
+
+307
+00:28:07,460 --> 00:28:11,100
+اللي
+
+308
+00:28:11,100 --> 00:28:18,070
+موجود في PRPR PR
+
+309
+00:28:18,070 --> 00:28:25,270
+وقلنالكم كيف بتكون تحضروه انطلاقا من البنزين how
+
+310
+00:28:25,270 --> 00:28:29,310
+can you prepare this compound this compound
+
+311
+00:28:29,310 --> 00:28:36,770
+starting from بنزين لاحظوا
+
+312
+00:28:36,770 --> 00:28:43,750
+معي لو أنا كنت بدي أبدأ تحضير عادي يعني البنزينو
+
+313
+00:28:43,750 --> 00:28:51,250
+بعدين اقول PR2 مثلا و Aluminium Bromide او FeBr3
+
+314
+00:28:51,250 --> 00:28:56,490
+مثلا بيمشي
+
+315
+00:28:56,490 --> 00:29:03,130
+المفروض
+
+316
+00:29:03,130 --> 00:29:06,330
+لو بدنا نعمل هذا ال synthesis اول اشي بده تيجي ايش
+
+317
+00:29:06,330 --> 00:29:13,320
+اول PR بكويس لو افترضنا اجت اول PRبعد ذلك تجب أن
+
+318
+00:29:13,320 --> 00:29:17,740
+تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد
+
+319
+00:29:17,740 --> 00:29:18,900
+ذلك تجب أن تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة
+
+320
+00:29:18,900 --> 00:29:18,960
+أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد ذلك تجب أن
+
+321
+00:29:18,960 --> 00:29:19,540
+تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد
+
+322
+00:29:19,540 --> 00:29:20,320
+ذلك تجب أن تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة
+
+323
+00:29:20,320 --> 00:29:20,380
+أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد ذلك تجب أن
+
+324
+00:29:20,380 --> 00:29:26,980
+تتفعل مرة أخرى بعد ذلك تجب أن تتفعل مرة
+
+325
+00:29:26,980 --> 00:29:39,080
+أخرى بعد ذلك تجب أن تتفعل مرة أخرى بعد ذ
+
+326
+00:29:39,210 --> 00:29:42,950
+ال bar .. ال bar هل بيعطيني هذا الشكل اللي موجود
+
+327
+00:29:42,950 --> 00:29:47,510
+هنا؟ إذا ال multi substitution يعني أنه يصير إبدال
+
+328
+00:29:47,510 --> 00:29:51,170
+و بعده كمان إبدال و بعده كمان إبدال مش هيعطيني هذا
+
+329
+00:29:51,170 --> 00:29:56,310
+.. مش هيعطيني هذا بناء على ذلك أنا بحاجة .. أنا
+
+330
+00:29:56,310 --> 00:30:02,510
+بحاجة إلى استراتيجية جديدة أنا بحاجة إلى
+
+331
+00:30:02,510 --> 00:30:05,890
+استراتيجية جديدة أشغل عليها
+
+332
+00:30:08,930 --> 00:30:13,190
+هذه الاستراتيجية الجديدة اللى عملوها بالشكل القادر
+
+333
+00:30:13,190 --> 00:30:19,530
+البنزين مش صعب عليهم يحولوه الى نيترو بنزين هاذي
+
+334
+00:30:19,530 --> 00:30:26,710
+صعبة ولا لا بستعملوا HNO3 H2SO4
+
+335
+00:30:26,710 --> 00:30:34,750
+النيترو بنزين برضه مش صعب عليهم يخلوه أنيلين يعني
+
+336
+00:30:34,750 --> 00:30:35,750
+NH2
+
+337
+00:30:39,370 --> 00:30:44,670
+نكل ممتازة الآن الانيلين is an activating group ال
+
+338
+00:30:44,670 --> 00:30:49,230
+amino group اللي على الانيلين is an activating
+
+339
+00:30:49,230 --> 00:30:56,230
+group و orthoparadirecting و الآن أناشيطة هذه لو
+
+340
+00:30:56,230 --> 00:31:04,370
+فعلناها مع ال PR2 بكمية كبيرة بتحط PR هنا و هنا و
+
+341
+00:31:04,370 --> 00:31:11,000
+هنا على التلت أماكن بتحط وين؟على التلت أماكن يعني
+
+342
+00:31:11,000 --> 00:31:22,780
+بتحط لي nh2 وpr وpr وpr طيب الآن أوصلنا لها
+
+343
+00:31:22,780 --> 00:31:28,480
+المرحلة المركب موجود بس فيه مشكلة ايش هي المشكلة
+
+344
+00:31:28,480 --> 00:31:36,380
+اللي فيه nh2 بدا نتخلص منها بنقدر نتخلص منها كيف
+
+345
+00:31:36,380 --> 00:31:38,780
+نلغيها
+
+346
+00:31:40,390 --> 00:31:45,390
+عند الروضة بيلغوها بالمساحة مش فيه جلم لرصاص وإنه
+
+347
+00:31:45,390 --> 00:31:53,950
+مساحة بيمسحوها بدي أحولها ل H كيف؟
+
+348
+00:31:53,950 --> 00:31:59,010
+طول لسه أنا أخدت أن H2 بتصير دايزونيا يعني لما
+
+349
+00:31:59,010 --> 00:32:02,690
+نقول HNO2
+
+350
+00:32:02,690 --> 00:32:06,150
+بيصير
+
+351
+00:32:06,150 --> 00:32:16,340
+هنا N2 plus وهنا PRو PR و PR ال N2 plus بإيش أخدنا
+
+352
+00:32:16,340 --> 00:32:29,540
+ال HbO3 H3bO2 ال acid هذا بتصير H واضح؟
+
+353
+00:32:29,540 --> 00:32:39,520
+لأن أنا عند PR PR PR واضح
+
+354
+00:32:39,520 --> 00:32:46,280
+ولا لأ؟هذه المسائل الأخيرة اللي احنا عمال بناخدها،
+
+355
+00:32:46,280 --> 00:32:54,520
+هذه قمة الكيميا ولا لأ؟ لازم لما تكون آخر محاضرة،
+
+356
+00:32:54,520 --> 00:33:00,080
+تصلوا لإيش؟ لقمة الكيميا، بس عارفين لما تصلوا لقمة
+
+357
+00:33:00,080 --> 00:33:07,060
+الكيميا، بتكتشفوا أنه وصلتوا لإيش؟ما هي العلوم في
+
+358
+00:33:07,060 --> 00:33:11,460
+الآخر انتبهوا معي العلوم في الآخر بتلاقوها بترجع
+
+359
+00:33:11,460 --> 00:33:18,040
+بتصب في مصاب واحد بتكتشفوا انكم وصلتوا لقمة المنطق
+
+360
+00:33:18,040 --> 00:33:23,700
+الإنساني والعلوم الإنسانية هذه الفكرة هذه الفكرة
+
+361
+00:33:23,700 --> 00:33:30,860
+قبل ما تكون فكرة كيميائية هي فكرة إنسانية بحتة بكل
+
+362
+00:33:30,860 --> 00:33:36,150
+معنى الكلمة موجودة في حياتنا الطبيعيةولما تفهموها
+
+363
+00:33:36,150 --> 00:33:39,750
+بالشكل بتحسوا قداش أنه الدنيا بتكبر .. بتكبر ..
+
+364
+00:33:39,750 --> 00:33:44,050
+بتكبر و بتعود إيش؟ تصغر إحنا إيش اللي عملنا بهذه
+
+365
+00:33:44,050 --> 00:33:52,310
+الفكرة؟ إحنا جبنا مجموعة الأمينو .. مجموعة الأمينو
+
+366
+00:33:52,310 --> 00:33:59,090
+اللي جبناها هنا استفدنا منها أي مستفادة ولا لأ؟ صح
+
+367
+00:33:59,090 --> 00:34:06,280
+ولا لأ؟ فدتنا بشغلتينفدتنا بشغل تاني الشغلة الأولى
+
+368
+00:34:06,280 --> 00:34:09,760
+انها activating يعني بتخلي البروم يتفعل تلت مرات
+
+369
+00:34:09,760 --> 00:34:14,740
+بسرعة والشغلة التانية انها orthoparadirectal group
+
+370
+00:34:14,740 --> 00:34:19,640
+اذا انا انا نمرة واحد بقول الان اتش تو اكتفات
+
+371
+00:34:19,640 --> 00:34:24,140
+اكتفات
+
+372
+00:34:24,140 --> 00:34:25,340
+اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات
+
+373
+00:34:25,340 --> 00:34:25,340
+اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات
+
+374
+00:34:25,340 --> 00:34:27,320
+اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات
+
+375
+00:34:27,320 --> 00:34:33,120
+اكتفات اكتفات اكتفات اكتفات اكتفات اكتفات اكخدمات
+
+376
+00:34:33,120 --> 00:34:41,040
+أو خدمات أو خدمات تجمع كتير هذه الكلمة جليلة ليه
+
+377
+00:34:41,040 --> 00:34:49,120
+جليلة؟ صفة للمنصوب و المنصوب ليش مكسور؟ لأنه
+
+378
+00:34:49,120 --> 00:34:53,400
+جماعه، اه مانزلت طيب بعد ما قدمت إن الخدمات
+
+379
+00:34:53,400 --> 00:35:01,130
+الجليلة هذه إيش عملنا؟ اتخلصنا منهاخلصنا منها، هذه
+
+380
+00:35:01,130 --> 00:35:06,390
+الفكرة إنسانية ولا لأ؟ مين أكتر ناس بيقدموا خدمات
+
+381
+00:35:06,390 --> 00:35:13,710
+جليلة وبعدين بتخلصوا منهم؟ هم
+
+382
+00:35:13,710 --> 00:35:19,880
+العملاءالعملاء بكافة أنواعهم، الواحد بيزيل حاله،
+
+383
+00:35:19,880 --> 00:35:23,620
+بيقدم خدمات جليلة لليهود، وفي الآخر بيحرجوه،
+
+384
+00:35:23,620 --> 00:35:27,440
+بيتخلصوا منه، بيرموه في قرية بدوية، بيعملوا فيه كل
+
+385
+00:35:27,440 --> 00:35:34,000
+العمايل، والأصعب من هيك أننا خمسة عشر سنة أو أكتر
+
+386
+00:35:34,000 --> 00:35:38,160
+بندرس و بنقول العملاء و بيرموهم في الدهنية بقى،
+
+387
+00:35:38,160 --> 00:35:41,100
+تعرفوها الدهنية؟ القرية العملاء اللي عملوها عند
+
+388
+00:35:41,100 --> 00:35:47,350
+رفح سابقة، لموا كل العملاء فيها و سكروا عليهمخمسة
+
+389
+00:35:47,350 --> 00:35:51,650
+عشر سنة واحنا بنقول ان العملاء يقدموا خدمات جليلة
+
+390
+00:35:51,650 --> 00:35:56,730
+ثم يرميهم الأعداء السنة هذه في عندنا ميزة إضافية،
+
+391
+00:35:56,730 --> 00:36:04,430
+شو هي؟ ان العملاء الكبار قدموا برضه خدمات جليلة و
+
+392
+00:36:04,430 --> 00:36:11,230
+بعدين ارتموا في السجونفاللي بيقدّم خدمة جليلة
+
+393
+00:36:11,230 --> 00:36:14,910
+للأسف جزء من السلوك الإنساني أحياناً أنه ممكن
+
+394
+00:36:14,910 --> 00:36:20,850
+نرميه في مثال شهير عاد في الحياة الإنسانية مين
+
+395
+00:36:20,850 --> 00:36:25,970
+اتذكرنا فيه؟ بيعطيها علامة للي
+
+396
+00:36:25,970 --> 00:36:33,950
+بيقدّم خدمة جليلة ثم يرمى غيره،
+
+397
+00:36:33,950 --> 00:36:37,350
+لأ لأ لأ أنه بيكون جزاء الرمى
+
+398
+00:36:39,910 --> 00:36:44,590
+بدأ أحكي أول كلمة باخد أنا العلامة أنا حكيت
+
+399
+00:36:44,590 --> 00:36:55,330
+بالمناسبة أول كلمة المثال بيقول هذا جزاءه cinema
+
+400
+00:36:55,330 --> 00:37:01,450
+لا لازم تكونوا عارفين ومين تحكينا إيش القصة
+
+401
+00:37:01,450 --> 00:37:08,500
+بتاعتهاوزار سليمار هدف فيه أحد الملوك كان طلب من
+
+402
+00:37:08,500 --> 00:37:12,880
+واحد يبنيه قصر يعني ماحدش قيله قصر ازاي فكان هذا
+
+403
+00:37:12,880 --> 00:37:17,220
+المهندس او بناء اسمه سليمار ثم بنى قصر القصر هذا
+
+404
+00:37:17,220 --> 00:37:21,960
+كان عجيب غريب فالملك خيب انه انه اي حد ييجي سليمار
+
+405
+00:37:21,960 --> 00:37:25,360
+يبني مثل هذا القصر فاشفع حرماه من باب مصر لألا
+
+406
+00:37:25,360 --> 00:37:30,640
+يبدن لأحد مثل هذا يعني بعد ما بناله القصرقتله حتى
+
+407
+00:37:30,640 --> 00:37:36,960
+لا يبني مثله للآخرين ودرجة مثلا هذا جزاءه cinema
+
+408
+00:37:36,960 --> 00:37:42,300
+بيعمل معروف زي ال Amino group في الآخر بنرد نخليها
+
+409
+00:37:42,300 --> 00:37:48,180
+hydrogen حال الدنيا هذا على أي حال يعني احنا بنأمل
+
+410
+00:37:48,180 --> 00:37:51,400
+بنأمل انكوا تكونوا استمتعتوا بمساق الكيميا العضوية
+
+411
+00:37:51,400 --> 00:37:56,420
+بنعتذر شويه ان المساق كان رسمي لأنه كان فيه تصوير
+
+412
+00:37:57,870 --> 00:38:03,330
+لأ لأ لأ المساقات التانية صغيرة مش هذا كبير في
+
+413
+00:38:03,330 --> 00:38:06,790
+الجامعة هيك لازم يكون المساق إنما إذا في مساقات
+
+414
+00:38:06,790 --> 00:38:10,830
+بتاخدوها عشرين صفعة ده موضوع تاني ان شاء الله ربنا
+
+415
+00:38:10,830 --> 00:38:15,710
+يوفقكوا بالامتحان، الامتحان يوم التلاتة القادم وأن
+
+416
+00:38:15,710 --> 00:38:19,510
+يحشر الناس وضحا، ما أطيب أمنيات التوفير
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6d49a3fe9be120efc0ab4569b642f77acb98256f
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_raw.srt
@@ -0,0 +1,2084 @@
+1
+00:00:15,180 --> 00:00:19,600
+بسم الله الرحمن الرحيم بنكمل اليوم ان شاء الله في
+
+2
+00:00:19,600 --> 00:00:25,620
+موضوع ال amends المحاضرة الماضية أخدنا تسمية ال
+
+3
+00:00:25,620 --> 00:00:30,580
+amends و أخدنا بشكل عام طريقتيناللي هم ال iobac
+
+4
+00:00:30,580 --> 00:00:36,840
+method وال common method لو مثلا بدنا نأكد على
+
+5
+00:00:36,840 --> 00:00:41,400
+هالكلام ونضيف أنه في طريقة ثالثة أحيانا موجودة
+
+6
+00:00:41,400 --> 00:00:46,140
+أيضا في الاستعمال حتى إذا يعني قرأت اسمباستعمالها
+
+7
+00:00:46,140 --> 00:00:50,660
+ما يكونش غريب عليكم لو أخدنا مثلا أربع ذرات كربون
+
+8
+00:00:50,660 --> 00:00:54,740
+عليهم amino group و بدنا نسمي بال Iopac
+
+9
+00:00:54,740 --> 00:00:58,200
+Nomenclature بنقول one amino بيوتين احنا اتفقنا ان
+
+10
+00:00:58,200 --> 00:01:03,660
+ال amino تعمل كمجموعة ك substitute لو بدنا نسمي
+
+11
+00:01:03,660 --> 00:01:07,420
+بال common نامي بناخد هذه المجموعة بيوتل و بنقول
+
+12
+00:01:07,420 --> 00:01:13,320
+بيوتلأمين هذا ال iopic name هذا ال common name في
+
+13
+00:01:13,320 --> 00:01:19,340
+طريقة تالتة للتسمية بيسموها chemical abstract name
+
+14
+00:01:19,340 --> 00:01:26,340
+ال CA هذه اختصار لإيش؟ ل chemical abstract
+
+15
+00:01:30,350 --> 00:01:35,090
+ال chemical abstracts هي الفهارس اللي بتلخص الجديد
+
+16
+00:01:35,090 --> 00:01:38,110
+في علم الكيميا و بتصدرها الجامعية الكيميائية
+
+17
+00:01:38,110 --> 00:01:42,290
+الأمريكية واضح فهدول لما بيعملوا ملخصات و ما إلى
+
+18
+00:01:42,290 --> 00:01:47,250
+ذلك بيسموا ال a means بطريقة غير ال I opinion و
+
+19
+00:01:47,250 --> 00:01:50,880
+غير ال common nameبيسموها ال chemical abstract
+
+20
+00:01:50,880 --> 00:01:56,740
+name بهاد الطريقة بيحاولوا يخلوا مجموعة الأمين زي
+
+21
+00:01:56,740 --> 00:02:00,660
+تماما ما كانت مجموعة ال alcohol يعني لما كانت
+
+22
+00:02:00,660 --> 00:02:03,660
+مجموعة ال alcohol كانت تعتبر functional group
+
+23
+00:02:03,660 --> 00:02:08,780
+وبتعطي النهايةall فلو كان انا عندى اربع معقوقات شو
+
+24
+00:02:08,780 --> 00:02:14,480
+كنت اسم المركب بيوتان all هم بيقولوا كمان ال amine
+
+25
+00:02:14,480 --> 00:02:19,860
+مش اقل يعنى قيمة من ال alcohol فسموا المركب بيوتان
+
+26
+00:02:19,860 --> 00:02:25,980
+amineواضح؟ فكأنه بيعملوا الامين كإنها functional
+
+27
+00:02:25,980 --> 00:02:30,500
+group اسمها امين لاحظوا بتخنف عن ال common name ال
+
+28
+00:02:30,500 --> 00:02:35,740
+common name احنا بنحط اسم المجموعة انا بيوت الامين
+
+29
+00:02:35,740 --> 00:02:42,640
+هنا بيحط اسم الألكان بيوتانأمين تماما زى ما كنا
+
+30
+00:02:42,640 --> 00:02:49,180
+نقول للألكول بيوتان all ولا ال الديهايد بيوتان ال
+
+31
+00:02:49,180 --> 00:02:54,600
+ولا الأمين بيقول يكون بيوتان أمين فكأنه الألكول
+
+32
+00:02:54,600 --> 00:02:58,620
+بهذه الحالة .. الأمين عفوا بهذه الحالة بيمثل
+
+33
+00:02:58,620 --> 00:03:03,050
+functional group بنسميها إيش أمينمابدناش ناخد كل
+
+34
+00:03:03,050 --> 00:03:07,350
+الأمثلة ممكن ناخد مثال او اتنين تأكيديين مثلا هنا
+
+35
+00:03:07,350 --> 00:03:11,650
+لو بدي هذا المركب واحد اتنين تلاتة اذا هذا إبروبان
+
+36
+00:03:11,650 --> 00:03:17,450
+في أي بكنومينكليتشر على موقع اتنين عند امينو وعند
+
+37
+00:03:17,450 --> 00:03:24,410
+مثل فبصير two amino two مثل إبروبان لو بدي ال
+
+38
+00:03:24,410 --> 00:03:27,430
+common name باخد هذه كلها كمجموعة اربع ذرات
+
+39
+00:03:27,430 --> 00:03:32,600
+الكربون اللي فيهم تشبهفي جعبات الـ tertiary بيوت
+
+40
+00:03:32,600 --> 00:03:37,120
+الأمين الان لو كنت بدى أسميه على ال chemical
+
+41
+00:03:37,120 --> 00:03:42,840
+abstract nomenclature هذا بدى يكون to بروبان أمين
+
+42
+00:03:42,840 --> 00:03:47,660
+و بنحط عليه وجود مجموعة الاش المثل يعنى اي واحد
+
+43
+00:03:47,660 --> 00:03:54,340
+اتنين تلاتة لو كان OH قولنا to بروبان all هنا أمين
+
+44
+00:03:54,340 --> 00:04:02,180
+to بروبان أمين to مثل to بروبانأمين و هكذا
+
+45
+00:04:02,180 --> 00:04:08,400
+بإمكانكوا تشوفوا التسميات الأشكال اللي تحت هذه هي
+
+46
+00:04:08,400 --> 00:04:12,500
+بعض المركبات اللي موجودة في التطبيق و ما عدا
+
+47
+00:04:12,500 --> 00:04:17,900
+المركب الأول كله بنسميها احنا مركبات حلقية غير
+
+48
+00:04:17,900 --> 00:04:22,300
+متجانسة ايش يعني غير متجانسة يعني الحلقة مش كلها
+
+49
+00:04:22,300 --> 00:04:26,760
+كربون الحلقة فيها كربون و ذرات غير الكربون من هنا
+
+50
+00:04:26,760 --> 00:04:33,820
+جاء عدمالتجانس واضح وهذه لها الحقيقة استعمالات
+
+51
+00:04:33,820 --> 00:04:37,380
+كثيرة في التطبيق لكن احنا في الكيميا بندرسها بمساق
+
+52
+00:04:37,380 --> 00:04:42,400
+كامل بسنة رابعة بنسميه heterocyclic chemistry فإذا
+
+53
+00:04:42,400 --> 00:04:46,480
+سمعتوا مركبات من هالصلف اندول بيريديل بيريديل
+
+54
+00:04:46,480 --> 00:04:50,840
+بيريميديل بايروليديل بايرول اميدازول واطفة كل هذه
+
+55
+00:04:50,840 --> 00:04:56,840
+برضه مركبات تحتوي علىاللي هي ال nitrogen موجودة
+
+56
+00:04:56,840 --> 00:05:01,580
+لكن مش هنا مجال دراستها البنزين اللي عليه أن أجتوت
+
+57
+00:05:01,580 --> 00:05:10,540
+علمناها ده أنالين ومشتقاته الآن لو إجينا ل ال
+
+58
+00:05:10,540 --> 00:05:15,780
+physical properties of a means طبعا إذا بنركز على
+
+59
+00:05:16,740 --> 00:05:20,720
+الـ boiling point إذا بنركز على ال boiling point
+
+60
+00:05:20,720 --> 00:05:28,100
+بنلاحظ إنه ال amines بشكل عام ممكن تعمل مع نفسها
+
+61
+00:05:28,100 --> 00:05:33,820
+نوع من ال hydrogen bondingيعني أتش من أمين بتعمل
+
+62
+00:05:33,820 --> 00:05:40,100
+hydrogen bonding مع أمين تاني ولذلك إذا يعني بنطلع
+
+63
+00:05:40,100 --> 00:05:45,520
+أحيانا بنلاحظ أنه نسبيا ممكن تكون عالية بعض ال
+
+64
+00:05:45,520 --> 00:05:49,100
+amines ال boiling point لكن مش كثير مش زي ال
+
+65
+00:05:49,100 --> 00:05:53,940
+alcohol يعني مش بقوة ال hydrogen bonding تبعت ال
+
+66
+00:05:53,940 --> 00:05:59,570
+alcoholلو .. يعني بتكون تنظروا مثلا إلى تلت
+
+67
+00:05:59,570 --> 00:06:03,950
+مراكبات تقريبا التلت مراكبات ماخدين نفس ال
+
+68
+00:06:03,950 --> 00:06:06,970
+molecular weight يعني ال molecular weight تلتين و
+
+69
+00:06:06,970 --> 00:06:10,910
+واحد و تلتين اتنين و تلتين لاحظوا ال Ethan ب
+
+70
+00:06:10,910 --> 00:06:14,790
+molecular weight تلتين ال boiling point تبعته ناقص
+
+71
+00:06:14,790 --> 00:06:22,020
+تمانية و تمانينواضح؟ الان ال مثلول ال molecular
+
+72
+00:06:22,020 --> 00:06:27,200
+weight 32 قريب منه ال boiling point plus 65 الان
+
+73
+00:06:27,200 --> 00:06:30,080
+ايش اللي رفعوا؟ يعني نفترض ان التلاتة دول ال
+
+74
+00:06:30,080 --> 00:06:33,800
+molecular weight متساوي، شو اللي رفعوا؟ 88 درجة و
+
+75
+00:06:33,800 --> 00:06:40,060
+65 يعني بحكي انا عن حوالي 140، 150 درجة ارتفاع
+
+76
+00:06:40,780 --> 00:06:44,960
+الهيدروجين البوندغ اللى بتعملها الالكوهول واضح؟
+
+77
+00:06:44,960 --> 00:06:49,160
+الان لو اجينا واطلعنا على الميثل أمين باللاحظ
+
+78
+00:06:49,160 --> 00:06:55,020
+الميثل أمين minus 6.3 برضه نسبيا مرتفع فوق ال 80
+
+79
+00:06:55,020 --> 00:07:00,260
+درجة عن الاثانإيش السبب؟ برضه الـ hydrogen
+
+80
+00:07:00,260 --> 00:07:03,000
+bonding، لكن إحنا اللي بنقوله إنه الـ hydrogen
+
+81
+00:07:03,000 --> 00:07:08,020
+bonding في الألكوهولز أعلى منه في الأمينز، بس
+
+82
+00:07:08,020 --> 00:07:12,060
+بالتأكيد في بالأمينز hydrogen bonding عمال رفعتها
+
+83
+00:07:12,060 --> 00:07:16,240
+عن مُركّب موازي مع دوم الـ hydrogen bonding هنا في
+
+84
+00:07:16,240 --> 00:07:21,360
+الـ إيثين 80 درجة، واضح؟ فدول الـ 80 درجة من وين
+
+85
+00:07:21,360 --> 00:07:28,900
+إجوا؟هيدروجين بوندنج هيدروجين
+
+86
+00:07:28,900 --> 00:07:29,500
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+87
+00:07:29,500 --> 00:07:31,920
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+88
+00:07:31,920 --> 00:07:34,160
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+89
+00:07:34,160 --> 00:07:38,140
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+90
+00:07:38,140 --> 00:07:42,820
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+91
+00:07:42,820 --> 00:07:50,160
+بوندنج هيدروجين بوندنج هيدروجين
+
+92
+00:07:50,160 --> 00:07:54,400
+بوندنجيعني مثلا لو بدنا ناخد مقارنة .. لو بدنا
+
+93
+00:07:54,400 --> 00:07:57,680
+ناخد مقارنة بين هذا المركب اللي هو الـ
+
+94
+00:07:57,680 --> 00:08:01,620
+dimethylamine و هذا المركب اللي هو ال
+
+95
+00:08:01,620 --> 00:08:05,340
+trimethylamine رغم أن هذا عمال بيزيد في ال
+
+96
+00:08:05,340 --> 00:08:09,480
+molecular weight لكن الdimethylamine ما زال فيه
+
+97
+00:08:09,480 --> 00:08:13,380
+hydrogen، ال trimethylamine مافيش فيه hydrogen،
+
+98
+00:08:13,380 --> 00:08:17,170
+رغم أن هذا أصغرفي الوزن في ال molecular weight
+
+99
+00:08:17,170 --> 00:08:21,570
+أصغر بجمعة مثل لكن لاحظوا ال boiling point تبعته
+
+100
+00:08:21,570 --> 00:08:25,550
+سبع درجات تقريبا بينما ال boiling point هنا تلت
+
+101
+00:08:25,550 --> 00:08:30,990
+درجات ليش ال trimethylamine كان أقل من ال
+
+102
+00:08:30,990 --> 00:08:34,650
+diamethylamine
+
+103
+00:08:34,650 --> 00:08:40,350
+لأن ال trimethylamine مافيش فيه hydrogen bonding
+
+104
+00:08:40,350 --> 00:08:47,110
+واضح لأنه مافيش فيه hydrogen bondingطبعاً الميثل
+
+105
+00:08:47,110 --> 00:08:51,050
+أمين بيعمل hydrogen bonding لكن في شكل عام هو
+
+106
+00:08:51,050 --> 00:08:57,030
+بيكون غاز يلاحظوا minus 6.3 و الغازات بتقدروا
+
+107
+00:08:57,030 --> 00:09:01,550
+تتذكروا العلاقة الأساسية بينها أنه تعامل كأنها
+
+108
+00:09:01,550 --> 00:09:06,770
+جزيئات منفصلة لأنه خفيف كتير و بحكومها ال kinetic
+
+109
+00:09:06,770 --> 00:09:11,890
+theory جزيئات بتتحرك و بتتصادم في جدار الإناء لكن
+
+110
+00:09:11,890 --> 00:09:16,240
+المقارنة هنا واضحة بين الداي ميثل أمينوالـ Tri
+
+111
+00:09:16,240 --> 00:09:21,480
+-methylamine أعلى في الـ boiling point بسبب انه
+
+112
+00:09:21,480 --> 00:09:24,500
+عنده إمكانية hydrogen bonding وهذه الإمكانية غير
+
+113
+00:09:24,500 --> 00:09:31,640
+موجودة في الـ Tri-methylamineالان كيف تحضر ال
+
+114
+00:09:31,640 --> 00:09:37,040
+amines هتلاحظوا انه في مجموعة من الطرق احنا مرت
+
+115
+00:09:37,040 --> 00:09:41,760
+علينا مثلا الطريقة الأولى انه احنا بنحطر ال amine
+
+116
+00:09:41,760 --> 00:09:45,760
+من خلال reduction of amides بليثيوم ألومينوم
+
+117
+00:09:45,760 --> 00:09:50,280
+هيدرايد هذه
+
+118
+00:09:50,280 --> 00:09:54,480
+الطريقة مرت علينا لما درسنا ال amides قلنا بنحول
+
+119
+00:09:54,480 --> 00:10:03,390
+السيطة بال bond O إلىCH2 يعني بيتم إضافة H- على
+
+120
+00:10:03,390 --> 00:10:09,430
+مرتين وهذه دوري ست في ال chemistry of amides أنه
+
+121
+00:10:09,430 --> 00:10:17,000
+amides are reduced to aminesالطريقة التانية لو
+
+122
+00:10:17,000 --> 00:10:20,720
+بدنا نتطلع على الـ Nitro Compounds لو بدنا نتطلع
+
+123
+00:10:20,720 --> 00:10:23,640
+على الـ Nitro Compounds و خلّيني أذكركوا أن الـ
+
+124
+00:10:23,640 --> 00:10:27,740
+Nitro Compounds كنا بنجيبهم احنا من البنزين يعني
+
+125
+00:10:27,740 --> 00:10:30,820
+لو بدنا نيترو بنزين الـ Nitro aromatic Compounds
+
+126
+00:10:30,820 --> 00:10:39,420
+كنت استعمل البنزين استعمل Nitric Acid و H2SO4
+
+127
+00:10:39,420 --> 00:10:45,850
+فبناء على ذلك البنزينممكن نعمله نيتراشن الان ال
+
+128
+00:10:45,850 --> 00:10:49,450
+Nitro برضه بنعمل لها reduction و عادة ال reduction
+
+129
+00:10:49,450 --> 00:10:55,530
+هنا ب hydrogenزائد مثل مثل زي nickel او platinum
+
+130
+00:10:55,530 --> 00:11:02,430
+هذا ال reduction بيحول ال NO2 الى NH2 لاحظوا معنى
+
+131
+00:11:02,430 --> 00:11:07,050
+شغلة مهمة جدا و خطأ كتير بيجعوا فيه الطلاب انه لما
+
+132
+00:11:07,050 --> 00:11:12,290
+نيجي نقولهم كيف يحضر ال aniline كتير كتير بيعملوا
+
+133
+00:11:12,290 --> 00:11:16,030
+غلطة هم بيوصوا ان الواحد مايكتبش الاشي الغلط بلاش
+
+134
+00:11:16,030 --> 00:11:20,110
+تروح يرسخ في ذهن الناس بس هذا إذا صرتم علمات
+
+135
+00:11:20,110 --> 00:11:26,620
+للمرحلة الابتدائيةممنوع تكتبوا الغلط واضح؟ للمراحل
+
+136
+00:11:26,620 --> 00:11:29,260
+الابتدائية و الاعدادية بيقولوا ما تكتبش الغلط ما
+
+137
+00:11:29,260 --> 00:11:35,080
+تكتبش قدامه الا الصح في مرحلة جامعية ممكن الواحد
+
+138
+00:11:35,080 --> 00:11:38,320
+يكتب الغلط الغلط اللي دايما بيناعمل انه لما نقول
+
+139
+00:11:38,320 --> 00:11:44,760
+كيف تحضر الانيلين بيجيوا ناس بيقولنا بنزين مع NH3
+
+140
+00:11:44,760 --> 00:11:48,480
+و بيحطوا اش اللي بيجي على بالهم و بيعطي انيلين هذا
+
+141
+00:11:48,480 --> 00:11:54,870
+ايش؟ قبل ما تشوفوا الكاميراهذا أخطاء مش خطأ واحد
+
+142
+00:11:54,870 --> 00:11:58,650
+بنعتبره الانيلين بتحضرش من البنزين مع الأمونيا
+
+143
+00:11:58,650 --> 00:12:02,890
+طبعا لو بدنا نقول ليش طيب هذا يعني مستحيل و بنخوف
+
+144
+00:12:02,890 --> 00:12:09,430
+و بنشطله أربع أخطاء لأنهإتفقنا إحنا أن التفاعل
+
+145
+00:12:09,430 --> 00:12:15,390
+الأساسي تبع البنزين هو أن نضيف عليه إشي موجب و ال
+
+146
+00:12:15,390 --> 00:12:24,090
+ammonia هذه ال N-H3 بتحمل زوج من الإلكترونات وهنا
+
+147
+00:12:24,090 --> 00:12:28,690
+في عندي أزواج من الإلكترونات هل يا تورا بقدر أجيب
+
+148
+00:12:28,690 --> 00:12:34,690
+أنا إلكترونات على إلكترونات؟لأ لذلك دائما اللي بده
+
+149
+00:12:34,690 --> 00:12:38,250
+ييجي يهاجم على البنسي اللي بده يكون بشكل عام موجة
+
+150
+00:12:38,250 --> 00:12:41,810
+عشانك لما درسنا ال nutrition قولنا ان هدولا
+
+151
+00:12:41,810 --> 00:12:47,770
+الحامضين مع بعض بيعطونا NO2 plus هي اللي بتهاجم
+
+152
+00:12:47,770 --> 00:12:52,750
+على ال minusولذلك هذا التحضير ان انا بتحضر
+
+153
+00:12:52,750 --> 00:12:57,370
+الانيلين مباشرة بأمونيا مع بنزين هذا كلام لا يجوز
+
+154
+00:12:57,370 --> 00:13:01,990
+والسبب ان انا مابقدرش اضيف سالب على سالب انا اللي
+
+155
+00:13:01,990 --> 00:13:06,210
+بدي اضيف بدي اضيف موجب على سالب ولذلك اذا بدنا
+
+156
+00:13:06,210 --> 00:13:10,630
+نسألكوا كيف بتحضروا الانيلين او ممكن نكون مصعبين
+
+157
+00:13:10,630 --> 00:13:17,830
+السؤال المثل انيلين مثلا كيف بدكوا تمشيه بدنا
+
+158
+00:13:20,160 --> 00:13:25,360
+بنبقى من البنزين ونستعمل عملية الـ Nitration طبعا
+
+159
+00:13:25,360 --> 00:13:29,940
+كأنيلين بنحوّل لنيترو بعدين هالانيلين بال
+
+160
+00:13:29,940 --> 00:13:34,260
+reduction الآن لو كان في عندك أكتر من Substituent
+
+161
+00:13:34,260 --> 00:13:41,400
+في هذه الحالة لازم أنتبه لعملية الترتيب أي واحدة
+
+162
+00:13:41,400 --> 00:13:46,540
+نحطها في الأول يعني مثلا لو كان السؤال عندكم ان
+
+163
+00:13:46,540 --> 00:13:53,260
+كيف بدي أحضرالـ NH2CH3
+
+164
+00:13:53,260 --> 00:13:58,540
+واضح؟
+
+165
+00:13:58,540 --> 00:14:03,920
+قدر
+
+166
+00:14:03,920 --> 00:14:09,140
+الإمكان تعتبر أن الـ NH2 أصلها إيش؟ يعني هذه جاية
+
+167
+00:14:09,140 --> 00:14:19,420
+من إيش؟ أصلها نيترو هذه أصلهابناء على ذلك، لو كنت
+
+168
+00:14:19,420 --> 00:14:23,760
+بتبدأ بالمثل، المثل بتوجه بارا، لو كنت بتبدأ
+
+169
+00:14:23,760 --> 00:14:31,500
+بالنيترو، النيترو بتوجه ميتا، النيترو is a
+
+170
+00:14:31,500 --> 00:14:35,580
+metadirecting group، الاماينو بارا directing
+
+171
+00:14:35,580 --> 00:14:38,920
+group، بس النيترو ميتا، انتبهوا معايا، هذي
+
+172
+00:14:38,920 --> 00:14:42,280
+activating و بارا directing group، هذي
+
+173
+00:14:42,280 --> 00:14:47,380
+deactivating وميتا directing groupواضح فبناء على
+
+174
+00:14:47,380 --> 00:14:51,480
+ذلك لو بدأ ابدأ بالبنزين ممكن اعمل اول اشي مثيلاشن
+
+175
+00:14:51,480 --> 00:14:58,880
+احط المثل و بعدين نيتراشن اذا البنزين اول اشي بنحط
+
+176
+00:14:58,880 --> 00:15:02,640
+المثل مثل كلورايد مثلا مع الومنيوم كلورايد و
+
+177
+00:15:02,640 --> 00:15:08,740
+الخطوة التانية نيتراشن بصير عند بارا نيترو طولوين
+
+178
+00:15:08,740 --> 00:15:15,840
+و بعدين بنعملهreduction واضح النيترو لما يصير امين
+
+179
+00:15:15,840 --> 00:15:19,300
+بده ينعمل reduction اذا هذا لو كان بده الخطوات
+
+180
+00:15:19,300 --> 00:15:26,960
+كاملة ابتداء من البنزين كيف بده اعمل بنزين CH3
+
+181
+00:15:26,960 --> 00:15:30,560
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+182
+00:15:30,560 --> 00:15:34,840
+CH3 CH3
+
+183
+00:15:34,840 --> 00:15:39,040
+CH3 CH3
+
+184
+00:15:40,460 --> 00:15:47,660
+بعدين reduction طبعا هنا نيتريشن HRO3H2SO4
+
+185
+00:15:47,660 --> 00:15:52,500
+هنا reduction HRO3H2SO4
+
+186
+00:15:52,500 --> 00:15:56,880
+HRO3H2SO4
+
+187
+00:15:56,880 --> 00:15:57,280
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+188
+00:15:57,280 --> 00:15:57,800
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+189
+00:15:57,800 --> 00:15:58,140
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+190
+00:15:58,140 --> 00:15:58,540
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+191
+00:15:58,540 --> 00:16:01,760
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+192
+00:16:01,760 --> 00:16:10,610
+HRO3H2SO4 HRO3H2فالخلاصة انه مابتنحطش ال amino
+
+193
+00:16:10,610 --> 00:16:16,810
+group مباشرة لازم تيجي من وين؟ من ال nitro في مركب
+
+194
+00:16:16,810 --> 00:16:21,130
+الحقيقة شبيه ايضا .. شبيه ايضا ومابديش ياكوا
+
+195
+00:16:21,130 --> 00:16:26,630
+تغلطوا، هنعود نركز عليه شبيه ايضا بال .. بالانيلين
+
+196
+00:16:26,630 --> 00:16:32,650
+لا يحضر مباشرة اللي هو مركب الفينول واضح؟ لما
+
+197
+00:16:32,650 --> 00:16:35,810
+بيكون عندكم فينول هنا OH
+
+198
+00:16:38,750 --> 00:16:45,090
+مش معقول ان واحدة تيجي تعمللنا بنزين مع OH minus
+
+199
+00:16:45,090 --> 00:16:52,310
+ليش لان هتحط minus على minus هذا الكلام لا يجوز
+
+200
+00:16:52,310 --> 00:16:58,900
+الفينول لا يحضر مباشرة من البنزينالفينول بقدرش
+
+201
+00:16:58,900 --> 00:17:03,620
+أقول بنزين مع OH- اللي هو ماعطيني الفينول هنتعلم
+
+202
+00:17:03,620 --> 00:17:08,920
+طريقة ان شاء الله كيف نحضر الفينول بطريق غير مباشر
+
+203
+00:17:08,920 --> 00:17:13,220
+بس مانقدرش نحضره بمباشر فإذا سئلته عن الانيلين أو
+
+204
+00:17:13,220 --> 00:17:20,100
+الفينول الطريقة غير مباشرة الطريقة غير مباشرة
+
+205
+00:17:20,100 --> 00:17:22,660
+لعملية التحضير
+
+206
+00:17:34,790 --> 00:17:41,210
+الان في كمان طريقة ممكن من خلالها انحضر
+
+207
+00:17:42,430 --> 00:17:47,790
+الأ means إن نعمل reduction للـ neutrals طبعا
+
+208
+00:17:47,790 --> 00:17:53,410
+انتبهوا معي إنه الـ neutral اللي هي ال Rcn من وين
+
+209
+00:17:53,410 --> 00:17:59,870
+أنا ممكن أجيبها بشكل عام من ال Rcl يعني لو كان
+
+210
+00:17:59,870 --> 00:18:04,390
+عندي مثل أن أنا مثل neutral بدي أحضرها المفروض
+
+211
+00:18:04,390 --> 00:18:09,690
+بحضرها من CH3 CL مع CN minus
+
+212
+00:18:11,570 --> 00:18:17,450
+واضح؟ CH3Cl مع Cl- لو بدنا نقول أكتر ال CH3Cl من
+
+213
+00:18:17,450 --> 00:18:28,870
+وين بنحضرها؟ من ال alcohol CH3OH مثلا مع BCl3 و
+
+214
+00:18:28,870 --> 00:18:32,010
+هذا الكلام اللي كنا دايما بنحكيه أن ال alcohol
+
+215
+00:18:32,010 --> 00:18:36,030
+يمثل نقطة إيش؟ انطلاق في ال organic synthesis
+
+216
+00:18:37,380 --> 00:18:40,400
+فالخلاص لو عندى alcohol ممكن احوله لchloride
+
+217
+00:18:40,400 --> 00:18:45,860
+لchloride ل نيترال بعمله hydrogenation reduction
+
+218
+00:18:45,860 --> 00:18:49,760
+سواء هذا ال reduction بليثيوم ألومنوم هيدرايد ممكن
+
+219
+00:18:49,760 --> 00:18:55,040
+أو بهيدروجينوميتال طبعا
+
+220
+00:18:55,040 --> 00:18:57,960
+المقصود بال reduction انه على الكابون و النيتروجين
+
+221
+00:18:57,960 --> 00:19:07,970
+هذه بضيف H وH وكمان H وH هى صار CH3 CH2un-atched
+
+222
+00:19:07,970 --> 00:19:15,970
+لاحظوا هذه الطريقة فيها ميزة انه انا في المركب
+
+223
+00:19:15,970 --> 00:19:21,310
+الأول سواء كان alcohol او كان chloride عدد ذرات
+
+224
+00:19:21,310 --> 00:19:26,350
+الكربون اللي عنده بتكون اقل بواحد من الأمين الناتج
+
+225
+00:19:26,350 --> 00:19:29,210
+يعني هنا لما يكون عندى مثل chloride كام كربون
+
+226
+00:19:29,210 --> 00:19:33,810
+عنده؟ واحد لو كنت بدأ أقولكوا حضرولي اث الأمين
+
+227
+00:19:33,810 --> 00:19:38,850
+الآن هنا زادتكربونة يعني هي المثل هذه هي المثل هذه
+
+228
+00:19:38,850 --> 00:19:43,090
+طب من وين إجت الكربونة لزيادة من ال cyan .. ال
+
+229
+00:19:43,090 --> 00:19:49,090
+cyanide واضح فهذه الطريقة بتحتمل زيادة كربونة على
+
+230
+00:19:49,090 --> 00:19:52,030
+عدد الكربونات الأصلية أنا كان عندي كربونة واحدة
+
+231
+00:19:52,030 --> 00:19:58,000
+هناك بيصير عنده two carbon atoms واضحوالـ Carbon
+
+232
+00:19:58,000 --> 00:20:03,280
+الجديدة مصدرها من مجموعة الـ CNI زي ما حكينا إن
+
+233
+00:20:03,280 --> 00:20:06,560
+إضافة الهيدروجين أو الـ reduction يابليثيوم
+
+234
+00:20:06,560 --> 00:20:10,500
+ألومنوم هيدرايديا بإضافة غاز الهيدروجين في وجود
+
+235
+00:20:10,500 --> 00:20:26,020
+متل بيعطينا الأمين الطريقة
+
+236
+00:20:26,790 --> 00:20:31,570
+التالتة او الرابعة لتحضير ال amines الطريقة
+
+237
+00:20:31,570 --> 00:20:37,110
+الرابعة لتحضير ال amines عمليا او تطبيقيا هذه
+
+238
+00:20:37,110 --> 00:20:43,090
+الطريقة لها تفاصيل كتيرة لكن على أرض الواقع ممكن
+
+239
+00:20:43,090 --> 00:20:47,470
+تفهموها بسهولة اذا انا أخدت الalkyl halide
+
+240
+00:20:50,810 --> 00:20:58,170
+وفعلته مع الأمونيا أو أي أمين تاني بس حطيت عند شرط
+
+241
+00:20:58,170 --> 00:21:05,670
+ضروري جدا ان هذه الأمونيا تكون excess واضح؟
+
+242
+00:21:05,670 --> 00:21:13,210
+يعني RX زائد أمونيا excess بيعطينا الأمين زائد
+
+243
+00:21:13,210 --> 00:21:19,450
+طبعا أمونيومبروميد ليش فكرة ال excess هذه بنحطها
+
+244
+00:21:19,450 --> 00:21:25,470
+احنا؟ليش بنحط ال .. ال ammonia تكون زيادة؟ على
+
+245
+00:21:25,470 --> 00:21:29,750
+أساس انه اللي ممكن يصير عندى .. اللي ممكن يصير
+
+246
+00:21:29,750 --> 00:21:34,730
+عندى انه لو ماحطيتش انا ال ammonia هذه excess ممكن
+
+247
+00:21:34,730 --> 00:21:39,290
+بعد ما نحول الى ال amine الأول هيصار عندى amine
+
+248
+00:21:39,290 --> 00:21:44,540
+تمام؟ يجي ال amine هذا الأول اللي ..هو يتفاعل مع
+
+249
+00:21:44,540 --> 00:21:48,500
+جزيئات تانية من البروم يعمل secondary compound
+
+250
+00:21:48,500 --> 00:21:52,280
+وممكن هذا المركب بعد ما ينتج يتفاعل كمان مرة
+
+251
+00:21:52,280 --> 00:21:57,660
+يعطينا tertiary الخلاصة كل الغلبة والمعادلات انا
+
+252
+00:21:57,660 --> 00:22:01,820
+هذه مابديش اغص معاكم فيها انا اللي بدي اياه منكم
+
+253
+00:22:01,820 --> 00:22:06,840
+في هذه اللحظة ان الalkyl halides مع ال ammonia
+
+254
+00:22:06,840 --> 00:22:12,470
+excess بيعطيناأمين بدون مشاكل يعني زي هيك المعادلة
+
+255
+00:22:12,470 --> 00:22:20,610
+بتكون ايش بدون مشاكل واضح؟ وهذه بيكون تكملتها زائد
+
+256
+00:22:20,610 --> 00:22:28,190
+طبعا HPRإذا ما حطيناش هذا excess بصير مشاكل كتير
+
+257
+00:22:28,190 --> 00:22:31,930
+كل المعادلات اللي قدامكوا ان التفاعل بتمر تين و
+
+258
+00:22:31,930 --> 00:22:35,650
+تلاتة و بيصير فيه غلبة واضح؟ خلينا احنا على
+
+259
+00:22:35,650 --> 00:22:40,470
+المعادلة اللي بدون مشاكل انه الalkyl heli مع ال
+
+260
+00:22:40,470 --> 00:22:44,230
+ammonia excess بيعطينا ال amine زي ال HBr اللي هي
+
+261
+00:22:44,230 --> 00:22:47,990
+المعادلة البسيطة اللي مافيش فيها مشاكل وين بتصير
+
+262
+00:22:47,990 --> 00:22:53,440
+المشاكل؟إذا هذا كان مش excess بيصير عندكوا صفحتين
+
+263
+00:22:53,440 --> 00:22:57,960
+معادلات بهذه المرحلة أنا بعتقد أنه أنا في غنى عنهم
+
+264
+00:22:57,960 --> 00:23:02,620
+واضح؟ وفي غنى عن الصفحة هذه الأخيرة اللي فيها text
+
+265
+00:23:02,620 --> 00:23:09,100
+بيشرح ليش بتصير المشاكل واضح؟ فكل اللي بيلزمنا
+
+266
+00:23:09,100 --> 00:23:12,620
+نكون عارفينه أنه تفاعل ال alkyl halide مع ال
+
+267
+00:23:12,620 --> 00:23:17,040
+ammonia excess مباشرة بيعطيني الأمين بدون مشاكل
+
+268
+00:23:17,040 --> 00:23:23,310
+اللي بدهوا مشاكليستعمل مش إكسس
+
+269
+00:23:34,410 --> 00:23:38,790
+تقريبا هذا مثال تطبيقه على نفس الفكرة .. هذا مثال
+
+270
+00:23:38,790 --> 00:23:43,330
+تطبيقه على نفس الفكرة لو أخدت أنا الأليلين مثلا مع
+
+271
+00:23:43,330 --> 00:23:46,770
+ال methyl iodide بصير عندي تفاعل إفدال، هاي
+
+272
+00:23:46,770 --> 00:23:51,570
+الأليلين بيهاجم هنا و بيطرد اليود بيعطيني methyl
+
+273
+00:23:51,570 --> 00:23:56,010
+-allylene لو ال methyl-allylene بيدفعله كمان مرة
+
+274
+00:23:56,010 --> 00:23:59,030
+أنا مع ال methyl-iodide، هاي زوج الألكترونات،
+
+275
+00:23:59,030 --> 00:24:02,450
+أفعله يهاجم و يطرد اليود، بيصير عندي
+
+276
+00:24:06,360 --> 00:24:15,800
+المثال الأخير في هذا المجال أن نيتروجين بتحل محل
+
+277
+00:24:16,880 --> 00:24:21,060
+البروم بس احنا كنا نجيب ال nitrogen بجزيق و البروم
+
+278
+00:24:21,060 --> 00:24:25,700
+بجزيق تاني هل ممكن يكون ال nitrogen و البروم بنفس
+
+279
+00:24:25,700 --> 00:24:30,500
+الجزيق بمعنى التفاعل يكون intra-molecular؟ الجواب
+
+280
+00:24:30,500 --> 00:24:34,200
+اه في هذا المثال اللي عندى اللي في حلقة بيريدين
+
+281
+00:24:34,200 --> 00:24:41,310
+هنا H1H مثل مع PR بتهاجم ال nitrogen و بتطردالبر
+
+282
+00:24:41,310 --> 00:24:46,370
+هو SM2 substitution غالبا فتعطينا هذا المُركّب
+
+283
+00:24:46,370 --> 00:24:49,510
+اللي فيه حلقة خمسية فيها نيتروجين وحلقة سوداسية
+
+284
+00:24:49,510 --> 00:24:56,570
+فيها نيتروجين وحلقة البريدين وحلقة بيروليدين
+
+285
+00:24:56,570 --> 00:25:03,060
+المُركّب كله هو نيكوتين السجائرواضح؟ المراكب كله
+
+286
+00:25:03,060 --> 00:25:06,600
+وانا كنت انسى كده الفكرة ليش احنا جيبنا هذا المثال
+
+287
+00:25:06,600 --> 00:25:13,300
+هنا حتى نفرجيكوا انه ال nitrogen بتحل محل لبروم
+
+288
+00:25:13,300 --> 00:25:17,840
+اللي هو موضوعنا تحضير ال amines من خلال ان ال
+
+289
+00:25:17,840 --> 00:25:20,860
+nitrogen تحل محل لبروم
+
+290
+00:25:34,040 --> 00:25:39,800
+الآن الـ Amines زي ما احنا اتفقنا وكل مركبات الـ
+
+291
+00:25:39,800 --> 00:25:44,830
+nitrogen عادة بيكون عليهم زوج منالإلكترونات ولذلك
+
+292
+00:25:44,830 --> 00:25:49,550
+يُعاملوا على إنهم bases وفي المُركّبات الـnatural
+
+293
+00:25:49,550 --> 00:25:53,530
+اللي فيها الـNitrogen هذه بالذات على حلقات بيسموها
+
+294
+00:25:53,530 --> 00:25:58,290
+الـAlkaloids ومن هذه الـAlkaloids بالمناسبة زي هذا
+
+295
+00:25:58,290 --> 00:26:01,490
+المُركّب النيكوتين بسبب وجود الـNitrogen هنا اللي
+
+296
+00:26:01,490 --> 00:26:04,710
+لها زوج إلكترونات والـNitrogen هنا اللي لها زوج
+
+297
+00:26:04,710 --> 00:26:11,260
+إلكترونات بيقولوا هذا مُركّب قاعدي بياخدالاسم
+
+298
+00:26:11,260 --> 00:26:14,320
+العائلة العام في المراكبات أو المنتجات الطبيعية
+
+299
+00:26:14,320 --> 00:26:19,560
+بنسمي احنا ايش ال Calorie فالمهم في ال Amines
+
+300
+00:26:19,560 --> 00:26:26,000
+حقيقة هو زوج الإلكترونات هذا زوج الإلكترونات بيخلي
+
+301
+00:26:26,000 --> 00:26:31,140
+ال Amines بشكل عام مش دائما بالمطلق بشكل عام
+
+302
+00:26:31,140 --> 00:26:41,480
+يتفاعلوا as bases وقتاش ممكن يتفاعلوامش كباسإذا
+
+303
+00:26:41,480 --> 00:26:46,100
+بنجيب base أقوى منهم واضح؟ ليش؟ زي ما بتقول أهو
+
+304
+00:26:46,100 --> 00:26:51,260
+فوق كل ذي علم عليم يعني أي حامض ممكن أحاوله ل base
+
+305
+00:26:51,260 --> 00:26:56,300
+ب .. بإيش؟ بتجيب حامض أقوى منه و ال base ممكن
+
+306
+00:26:56,300 --> 00:26:59,680
+أخليها تبين كإنها acid بتجيب قاعدة أقوى منها
+
+307
+00:26:59,680 --> 00:27:04,800
+بتصيريا كإنها acid و القاعدة الأقوى .. أه لكن بشكل
+
+308
+00:27:04,800 --> 00:27:10,020
+عام ال amines و ال ammonia they are considered as
+
+309
+00:27:10,600 --> 00:27:17,400
+basis بشكل عام basis عشان ات لو مثلا احنا بناخد ال
+
+310
+00:27:17,400 --> 00:27:23,740
+ammonia على سبيل المثال مع H plus خلينا نفترضها
+
+311
+00:27:23,740 --> 00:27:30,900
+انها كانت H3O plus يعني حامض مدوب في ميه واضح فال
+
+312
+00:27:30,900 --> 00:27:32,660
+ammonia منها انا هتاخد
+
+313
+00:27:39,080 --> 00:27:43,440
+الحامض اللي مدوب في مياه أسد بيعطينا الامونيوم ايو
+
+314
+00:27:43,440 --> 00:27:48,080
+الان اتش فور بلس زائد الميه اهم في الموضوع ان
+
+315
+00:27:48,080 --> 00:27:53,850
+الامونيا هنا تعاملت كإنها ايشبس و نفس الاشي لو انا
+
+316
+00:27:53,850 --> 00:27:59,430
+باخد حتى بالحالة الغازية مش بالحالة السائلة و يمكن
+
+317
+00:27:59,430 --> 00:28:04,790
+كان عندكم او مرات بيكون في تجربة او في مساق
+
+318
+00:28:04,790 --> 00:28:12,130
+الكيميا العامة تجربة بتوضح كده يمشوا الجزيئات
+
+319
+00:28:12,130 --> 00:28:21,360
+بيجيبواأربوبة بهذا الشكل وبحط هنا نقطة من الأمونيا
+
+320
+00:28:21,830 --> 00:28:26,150
+سوليوشن و بيحطوه هنا نقطة من ال HCl بيحطوه مبعد
+
+321
+00:28:26,150 --> 00:28:30,710
+طبعا هنا هتتبخر أمونيا وهنا هتتبخر HCl هيبدو
+
+322
+00:28:30,710 --> 00:28:35,230
+يجربوا مع بعض لحظة ما بتتفاعل الأمونيا بشكلها
+
+323
+00:28:35,230 --> 00:28:40,450
+الغازي مع ال HCl بشكله الغازي بيعطينا ال H4Cl
+
+324
+00:28:40,450 --> 00:28:44,990
+الأمونيوم الكلورايد والأمونيوم الكلورايد دائما
+
+325
+00:28:44,990 --> 00:28:50,630
+بتذكروا في المدارس إيش كنتوا تسموه كلوريد
+
+326
+00:28:50,630 --> 00:28:51,450
+الأمونيوم
+
+327
+00:28:55,250 --> 00:28:59,770
+اليوم مشي كتير الدنيا شتاء بيقولوا عنه صحوب بيضاء
+
+328
+00:28:59,770 --> 00:29:03,910
+من كلوريد الأمونيوم يعني أول ما بتحدوا مع بعض
+
+329
+00:29:03,910 --> 00:29:08,810
+بيعملوا لون أبيض زي السحابة البيضاء فإذا التقى غاز
+
+330
+00:29:08,810 --> 00:29:15,950
+الأمونيا مع غاز ال HCl مش مع المحليل بيعطينا white
+
+331
+00:29:15,950 --> 00:29:19,110
+clouds أو صحوب بيضاء من الأمونيوم الكلوريد طبعا
+
+332
+00:29:19,110 --> 00:29:23,560
+هذه بتيجي في منطقة معينة هنااللي هي ال ammonia و
+
+333
+00:29:23,560 --> 00:29:28,440
+ال chloride و قعدت بحسبه قداشه بيمشي كل جزيق نسبة
+
+334
+00:29:28,440 --> 00:29:33,540
+لوزنه مين اللي بده يمشي أسرع الجزيق الخفيف بناء
+
+335
+00:29:33,540 --> 00:29:37,780
+على ذلك هنكون احنا بعاد عن الجزيق الخفيف و grab
+
+336
+00:29:37,780 --> 00:29:46,120
+للجزيق التجيل واضحة ولا نوضحها أكتر بلاش نوضحها
+
+337
+00:29:46,120 --> 00:29:53,060
+أكتر هالجيتا لو حطينا .. لو حطينا ولد صغيرمع ال M
+
+338
+00:29:53,060 --> 00:29:57,920
+مثلا و بينهم عشرين متر و تركناهم ال M أكم خطوة
+
+339
+00:29:57,920 --> 00:30:02,140
+بتمشي؟ هذا إذا مشيت تلت خطوات و الولد لما بيجي
+
+340
+00:30:02,140 --> 00:30:06,340
+جراي أكم خطوة بمشي؟ يمكن خمستاشر خطوة هل بيمشوا
+
+341
+00:30:06,340 --> 00:30:10,460
+بنفس الإشي الخفيف مع اللي تجيل؟ نفس الإشي فلو
+
+342
+00:30:10,460 --> 00:30:13,920
+بتخيلوا أنه زي هيك هنا بدو يكون عندي مثلا ال HCl
+
+343
+00:30:13,920 --> 00:30:19,400
+هنا بدو يكون عندي ال ammonia ليش؟ لأن ال HClبنحكي
+
+344
+00:30:19,400 --> 00:30:22,180
+احنا عن خمسة و تلاتين و نص، ستة و تلاتين و نص
+
+345
+00:30:22,180 --> 00:30:26,180
+الوزن، هنا بنحكي عن سبعتاشر، اربعتاشر تلاتة، إذا
+
+346
+00:30:26,180 --> 00:30:29,860
+من الأدقال و اللي بيمشي أقل، إله علاقة عكسية مع
+
+347
+00:30:29,860 --> 00:30:33,820
+المسافة و بيعملوها تجربة و بيجيسوا كدهش المسافة
+
+348
+00:30:33,820 --> 00:30:37,680
+هنا و المسافة هنا و بيحققوا هذه العلاقة، واضح؟
+
+349
+00:30:41,600 --> 00:30:48,040
+الخلاصة أن تفاعل الـ Ammonia gas مع الـ HCl gas هو
+
+350
+00:30:48,040 --> 00:30:54,540
+حقيقة تفاعل acid-base أن زوج الإلكترونات بتاع الـ
+
+351
+00:30:54,540 --> 00:30:59,660
+Ammonia هو اللي بده يتفاعل مع الـ H plus بيكوّن
+
+352
+00:30:59,660 --> 00:31:03,840
+للأيون الموجة بأمونيوم طبعا عندي كلور بده يكون
+
+353
+00:31:03,840 --> 00:31:04,500
+أمونيوم
+
+354
+00:31:09,870 --> 00:31:16,990
+الان لو اتينا نتطلع على ال basicity of a means زي
+
+355
+00:31:16,990 --> 00:31:21,610
+ما اتفقنا احنا ان ال a means are basis ال a means
+
+356
+00:31:21,610 --> 00:31:26,670
+are basis وسبب
+
+357
+00:31:26,670 --> 00:31:34,750
+ال basicity زوج ال electronic لاحظوا هنا حاططعدة
+
+358
+00:31:34,750 --> 00:31:39,770
+أشياء من خلالها ممكن احنا نعمل مقارنة وقت إيش
+
+359
+00:31:39,770 --> 00:31:45,350
+بتزيد ال basicity وقت إيش بتقل الجواب بسيط كل ما
+
+360
+00:31:45,350 --> 00:31:49,990
+زادت الكثافة الإلكترونية كل ما زادت الكثافة
+
+361
+00:31:49,990 --> 00:31:56,550
+الإلكترونية بيكون المركب basic أكتر ولا أقل وكل ما
+
+362
+00:31:56,550 --> 00:32:02,870
+سحبنا منه إلكتروناتبكون less basic بناء على ذلك لو
+
+363
+00:32:02,870 --> 00:32:07,990
+احنا بناجي بنطلع هو أنا للأسف مش كاتبلكوا ال BKB
+
+364
+00:32:08,810 --> 00:32:14,490
+كاتب ال BKA للحمض المرافق يعني الأمونيا الحامض
+
+365
+00:32:14,490 --> 00:32:20,110
+المرافق تبعها الاناتش فور بلس هو كاتب ال BKA
+
+366
+00:32:20,110 --> 00:32:24,610
+للأمونيوم أيون اللي أسهل إلي في المقارنة كان ممكن
+
+367
+00:32:24,610 --> 00:32:30,010
+أكتب ال BKB لنفس الأمونيا الآن مش مشكلة كبيرة لما
+
+368
+00:32:30,010 --> 00:32:34,090
+بدي أحسبها بدي أقول 14 ناقص هذي يعني لو بدي أحكي
+
+369
+00:32:34,090 --> 00:32:36,590
+هنا بدي أحكي عن four point
+
+370
+00:32:39,290 --> 00:32:45,330
+seven على سبيل المثال و لو بدي أحكي هنا في حالة
+
+371
+00:32:45,330 --> 00:32:53,900
+الانالين بدي أحكي عنه9.3 تقريبا و هكذا يعني مش صعب
+
+372
+00:32:53,900 --> 00:32:59,900
+ان نحسب .. مش صعب ان نحسب ال BKB مش صعب ان نحسب ال
+
+373
+00:32:59,900 --> 00:33:04,260
+BKB طبعا بتكونوا انتوا متذاكرين شغلة انه كل ما ال
+
+374
+00:33:04,260 --> 00:33:10,120
+BKB بتقل معنى ذلك ال basicity بده تكون اعلى بناء
+
+375
+00:33:10,120 --> 00:33:14,360
+على ذلك لو بده في الأول المقارنة الأولى بين ألفاتك
+
+376
+00:33:14,360 --> 00:33:19,920
+أمين زي ال بيث الأمين أو ال دايمة الأمين مطفاتأي
+
+377
+00:33:19,920 --> 00:33:22,900
+اروماتيك كومباون من الأعلى الالفاتك ولا
+
+378
+00:33:22,900 --> 00:33:28,260
+الاروماتيك؟ الالفاتك
+
+379
+00:33:30,660 --> 00:33:34,740
+هذا من ناحية القيمة واضح أن الـ aliphatic الـ
+
+380
+00:33:34,740 --> 00:33:40,300
+basicity لهم أعلى السؤال لماذا؟ لسبب بسيط أن زوج
+
+381
+00:33:40,300 --> 00:33:44,340
+الألكترونات في الـ aliphatic compounds جاهز إنه
+
+382
+00:33:44,340 --> 00:33:47,620
+يتفاعل جاهز إنه يكون كأنه base بينما في ال
+
+383
+00:33:47,620 --> 00:33:51,960
+aromatic compounds بيعمل resonanceوبالتالي هو غير
+
+384
+00:33:51,960 --> 00:33:57,080
+جاهز للتفاعل الخارجي واضح في السبب حقيقة هو ال
+
+385
+00:33:57,080 --> 00:34:01,220
+resonance نفس الأشياء هنا لو أنا مثلا بدي أجي أطلع
+
+386
+00:34:01,220 --> 00:34:06,560
+على ال aniline و ال cyclohexane hexamine اللي
+
+387
+00:34:06,560 --> 00:34:11,370
+بيكون أعلى ك baseالـCyclohexyl، هذا الـaliphatic،
+
+388
+00:34:11,370 --> 00:34:16,030
+هذا الـaromatic، ما هو السبب؟ السبب هنا إن هذا زوج
+
+389
+00:34:16,030 --> 00:34:22,770
+الإلكترونات عشان يكون base لزمنه وين يتفاعل؟ برا،
+
+390
+00:34:22,770 --> 00:34:27,710
+اللي بده يثبت قوته، وين بده يثبت قوته؟ برا ولا
+
+391
+00:34:27,710 --> 00:34:33,610
+جوا؟ برا، واضح؟ عشان هيك الرجال اللي عن جد هو مين؟
+
+392
+00:34:34,700 --> 00:34:37,940
+اللي بيثبت قوته برا مش علي ولادنا صغار في الدار و
+
+393
+00:34:37,940 --> 00:34:44,140
+بيعمل مشاكل و .. واضح؟ اه ف .. عشان يكون بياس معنى
+
+394
+00:34:44,140 --> 00:34:47,680
+ذلك هو جاهز للتفاعل برا مش جاهز انه يضل يتفاعل مع
+
+395
+00:34:47,680 --> 00:34:52,220
+نفسه و يضحن نفسه الآن هنا في حالة الـ aromatic
+
+396
+00:34:52,220 --> 00:34:56,520
+amine هذا زوج الإلكترونات في resonance effect ممكن
+
+397
+00:34:56,520 --> 00:35:00,260
+يتحرك زي هيك تيجي هذه ال minus تصير محمولة هنا
+
+398
+00:35:00,260 --> 00:35:04,920
+كمان حركة تصير هنا كمان حركة تصير هنا الخلاصةهل
+
+399
+00:35:04,920 --> 00:35:25,060
+هذا زوج الالكترونات جاهز للتفاعل مع الخارج؟ هل
+
+400
+00:35:25,060 --> 00:35:30,800
+هذا زوج الالكترونات جاهز للتفاعل مع الخارج؟
+
+401
+00:35:34,210 --> 00:35:39,890
+بتشكل جوا الحلقة، واضح؟ ولذلك الـ aliphatic amines
+
+402
+00:35:39,890 --> 00:35:44,010
+بشكل عام they are more basic than aromatic amines
+
+403
+00:35:44,010 --> 00:35:47,910
+لأن ال aromatic amines بتعمل resonance فبدل ما زوج
+
+404
+00:35:47,910 --> 00:35:50,870
+الإلكترونات هيوا عن نيتروجين في أحد ال resonance
+
+405
+00:35:50,870 --> 00:35:54,750
+structure شو صارت ال nitrogen؟ positive، بطل عليها
+
+406
+00:35:54,750 --> 00:36:00,650
+زوج الإلكترونات، واضح؟ فلو بدنا نيجي نسأل كقاعدة
+
+407
+00:36:00,650 --> 00:36:06,910
+عامةوهي أكثر أساسية ألفاتيك أو أروماتيك أمين
+
+408
+00:36:06,910 --> 00:36:13,410
+الجواب ألفاتيك أمين بسبب ريزونانس الألفاتيك أمين
+
+409
+00:36:13,410 --> 00:36:18,430
+هم أعلى والسبب أن الأروماتيك أمين بيعملوا ريزونانس
+
+410
+00:36:18,430 --> 00:36:23,890
+الألفاتيك أمين بيعملوش ريزونانس هذه النقطة الأولى
+
+411
+00:36:23,890 --> 00:36:31,530
+الآن لو رجعنا شوية صغيرة للجدول وعملنا كمان مقارنة
+
+412
+00:36:32,150 --> 00:36:38,970
+يا تورا، مين بيكون more basic؟ الأمين اللي عليه
+
+413
+00:36:38,970 --> 00:36:44,890
+مثلا R1 أو R2 أو R3 لحظة، أنا عندي مثل أمين، المثل
+
+414
+00:36:44,890 --> 00:36:51,030
+بتعطي إلكترونات، هنا die مثل أمين، مجموعة المثل،
+
+415
+00:36:51,030 --> 00:37:00,110
+هنا try مثل أمينواضح؟ قلية أعلى واحدة فيهم الـ
+
+416
+00:37:00,110 --> 00:37:05,790
+trimethylamine is more basic than الـ
+
+417
+00:37:05,790 --> 00:37:11,170
+dimethylamine بمعنى أنه أنا كل ما بيكون عندي .. كل
+
+418
+00:37:11,170 --> 00:37:15,700
+ما بيكون عندي electrondonating groups المفروض ال
+
+419
+00:37:15,700 --> 00:37:21,120
+basicity ايش يصير لها اتزيد هذا الكلام نفسه ممكن
+
+420
+00:37:21,120 --> 00:37:28,300
+تلاحظوه لو بدكوا تعمله مقارنة مثلا المثال اللي تحت
+
+421
+00:37:28,300 --> 00:37:34,140
+aromatic احنا قولنا ال aromatic بشكل عام ليس basic
+
+422
+00:37:34,140 --> 00:37:40,640
+لكن خليني اقارن aromatic مع aromatic مع aromatic
+
+423
+00:37:41,600 --> 00:37:47,820
+واضح؟ كله ضعيف، لكن مين فيهم؟ الأضعف، الأن لو حطيت
+
+424
+00:37:47,820 --> 00:37:52,440
+هنا مجموعة مثل، مجموعة المثل، بتعطي إلكترونات،
+
+425
+00:37:52,440 --> 00:37:56,800
+خليني اعتبر الـ H حلق وسط، وهنا مجموعة نيترو بتسحب
+
+426
+00:37:56,800 --> 00:38:03,100
+الإلكترونات، أنه بنتوقع يكون more basicاللي فيه
+
+427
+00:38:03,100 --> 00:38:06,860
+زيادة الإلكترونات لأن ال basicity هي قصة
+
+428
+00:38:06,860 --> 00:38:09,980
+الإلكترونات، إيش اللي بيزيدها، واضح؟ اللي فيه
+
+429
+00:38:09,980 --> 00:38:13,740
+زيادة الإلكترونات، واضح؟ نفس الأشياء لو كنتوا
+
+430
+00:38:13,740 --> 00:38:16,980
+تاخدوها مثلا، لو أخدتوا ال etheramine، هاي زوج
+
+431
+00:38:16,980 --> 00:38:22,800
+إلكترونات، شايفينه؟ طيب، لو عملت chloroethelamine
+
+432
+00:38:24,060 --> 00:38:27,660
+هذا نفس زوج الإلكترونات لكن الكلور ماذا يعمل؟
+
+433
+00:38:27,660 --> 00:38:32,740
+بيسحب شوية من الإلكترونات إذا وين الإلكترونات أكتر
+
+434
+00:38:32,740 --> 00:38:37,600
+هتكون؟ في ال إيثالأمين ولا في الكلورو؟ إيثالأمين
+
+435
+00:38:37,600 --> 00:38:41,300
+في الإيثالأمين إذا هذا الإيثالأمين is more basic
+
+436
+00:38:41,300 --> 00:38:46,060
+فكأنه أنا قاعد بقول كلمة إن ال electron donating
+
+437
+00:38:46,060 --> 00:38:52,230
+groups المجموعات المعطية increaseبسيسيتي و ال
+
+438
+00:38:52,230 --> 00:38:56,850
+electron with drawing groups decrease basicity و
+
+439
+00:38:56,850 --> 00:39:01,430
+هذا كلام بسيط إن أنا عندي زوج electronic إذا حطيت
+
+440
+00:39:01,430 --> 00:39:04,990
+electron donating بزيد الكثافة الإلكترونية بصير
+
+441
+00:39:04,990 --> 00:39:10,070
+more basic إذا حطيت electron with drawing groups
+
+442
+00:39:10,070 --> 00:39:15,940
+بجلل الكثافة الإلكترونية بصيرless basic فوصفيا
+
+443
+00:39:15,940 --> 00:39:20,000
+العملية سهلة طبعا مش مطلوب مني ان انا اقعد احفظ
+
+444
+00:39:20,000 --> 00:39:24,980
+الجداول و الأرقام لكن مطلوب مني في ال basicity ان
+
+445
+00:39:24,980 --> 00:39:30,160
+اكون عارف أشياء كمبادئ عامة ان ال aliphatic amines
+
+446
+00:39:30,160 --> 00:39:35,480
+they are more basic than aromatic amines الآن سواء
+
+447
+00:39:35,480 --> 00:39:38,620
+على aliphatic amines او على aromatic amines اذا
+
+448
+00:39:38,620 --> 00:39:43,800
+حطيت مجموعات معطيةبتزيد القاعدية، وإذا حطيت
+
+449
+00:39:43,800 --> 00:39:48,360
+مجموعات ساحبة، بتقل القاعدية، واضح؟ هاي التلات
+
+450
+00:39:48,360 --> 00:39:51,860
+حاجات اللي بدي أقولها ألفاتك أمينs are more basic
+
+451
+00:39:51,860 --> 00:39:55,140
+than aromatic amines، electron donating groups
+
+452
+00:39:55,140 --> 00:40:00,720
+increase basicity، and electron withdrawing groups
+
+453
+00:40:00,720 --> 00:40:03,760
+decrease basicity، واضح؟
+
+454
+00:40:08,850 --> 00:40:12,430
+لأ ما هاد ال slide برضه على ال basicity و ال
+
+455
+00:40:12,430 --> 00:40:21,850
+acidity هاد
+
+456
+00:40:21,850 --> 00:40:28,430
+ال slide بتجيبلنا .. بتجيبلنا مثال عادة بيعملوا
+
+457
+00:40:28,430 --> 00:40:32,050
+تجربة في المختبر بعرفش إيه ممكن تعملوه برضه إنتوا
+
+458
+00:40:32,050 --> 00:40:38,260
+إذا أخدتوا المختبر أو لأ إنهم بياخدواالبارا مثل
+
+459
+00:40:38,260 --> 00:40:43,980
+أنيلين اللي هو البارا تولدين هذا والبارا نيترو
+
+460
+00:40:43,980 --> 00:40:51,360
+طولوين لاحظوا أنا عند مثل و مثل مجموعةأمينو
+
+461
+00:40:51,360 --> 00:40:58,700
+ومجموعة نيترو ممكن ان البعض يفكر ان النيترو جروب
+
+462
+00:40:58,700 --> 00:41:04,660
+basic من اي منطلق من منطلق ان تشوفه النيتروجين لكن
+
+463
+00:41:04,660 --> 00:41:10,500
+انتبهوا معي ان النيتروجين هذه تبعت مجموعة النيترو
+
+464
+00:41:10,500 --> 00:41:16,360
+ماعليهاش أزواج إلكترونات هي نيتروجين موجبةبمعنى
+
+465
+00:41:16,360 --> 00:41:19,420
+هذه النيتروجين تعطي الانيلين على العين والرأس
+
+466
+00:41:19,420 --> 00:41:23,180
+عليها زوج من الإلكترونات بس هذه لما بدنا نرسمها
+
+467
+00:41:23,180 --> 00:41:26,160
+حقيقة بترسم بهذا الشكل
+
+468
+00:41:32,930 --> 00:41:37,630
+وهنا O بتكون minus وهنا plus فالنيترو جينها دي
+
+469
+00:41:37,630 --> 00:41:41,670
+ماعليهاش إلكترونات النيترو كمجموعة بنرسمها بالشكل
+
+470
+00:41:41,670 --> 00:41:44,990
+اللي موجود عندكم بناء على ذلك لو بدأ أقول هذا
+
+471
+00:41:44,990 --> 00:41:48,750
+المركب اللي فيه ال amino ولا فيه ال nitro which is
+
+472
+00:41:48,750 --> 00:41:55,250
+more basicأكيد هذا اللي هو البارا طول يديك طيب لو
+
+473
+00:41:55,250 --> 00:41:59,170
+كان عندي خليط من المركبين مخلوطين مع بعض و بدي
+
+474
+00:41:59,170 --> 00:42:04,970
+طريقة كيميائية في المعمل اني افصلهم عن بعض واضح
+
+475
+00:42:04,970 --> 00:42:09,810
+ايش التجربة انه انا عندي اللي هو ال nitro مع ال
+
+476
+00:42:09,810 --> 00:42:14,290
+amino و بدي افصلهم طبعا ممكن ناس ممكن ناس منكوا
+
+477
+00:42:14,290 --> 00:42:20,250
+يقولوا ما هو احنا ليش في الأساس نخلطهمعشان في
+
+478
+00:42:20,250 --> 00:42:25,890
+الآخر نتغلب بفصلهم يعني لو من الاصل ما خلطناهم مش
+
+479
+00:42:25,890 --> 00:42:31,050
+بلزمناش تجربة اننا نفصلهم اه بس اتذكروا نقطة
+
+480
+00:42:31,050 --> 00:42:35,930
+اتذكروا نقطة انه انا هذا المركب اللي فيه ال amino
+
+481
+00:42:35,930 --> 00:42:40,920
+حضرته من هذامظبوط ولا لأ؟ قبل شوية احنا كنا
+
+482
+00:42:40,920 --> 00:42:44,880
+نقولكوا انه مركب الـ Nitro هذا بالـ hydrogenation
+
+483
+00:42:44,880 --> 00:42:48,620
+مع الـmetal بيعطينا الـ Amino الان فالاتنين
+
+484
+00:42:48,620 --> 00:42:53,040
+موجودين مع بعض ممكن التفاعل لا يصل الى النهاية
+
+485
+00:42:53,040 --> 00:42:58,300
+وبالتالي صار عنده متكون الـ Amino compound وصار
+
+486
+00:42:58,300 --> 00:43:03,720
+عنده الـ Nitroوالاتنين صاروا مخلوطين مع بعض كيف
+
+487
+00:43:03,720 --> 00:43:09,720
+ممكن افصل المركبين؟ بيقول الات لو اجينا .. ضفنا له
+
+488
+00:43:09,720 --> 00:43:17,420
+محمض HCl ال HCl هيتفاعل مع مين؟ بس مع ال basic مع
+
+489
+00:43:17,420 --> 00:43:21,580
+هذا مش هيتفاعل مع هذا بناء على ذلك هذا المركب اللي
+
+490
+00:43:21,580 --> 00:43:25,990
+هو ال Nitro Toluene هيظل زي ما هومش هيتفاعل مع ال
+
+491
+00:43:25,990 --> 00:43:31,550
+HCl بينما ال باراتوليدين هيتفاعل مع ال HCl هتصير
+
+492
+00:43:31,550 --> 00:43:40,350
+هذي N-H3+, النيتروجين هتاخد H+, N-H3+, و Cl-, اللي
+
+493
+00:43:40,350 --> 00:43:45,770
+هو ال chloride لاحظوا معنى ان هذا المركب صار plus
+
+494
+00:43:45,770 --> 00:43:51,730
+minus ايش يعني plus minus Salt ملح مش الأملح plus
+
+495
+00:43:51,730 --> 00:43:54,250
+minus و ال salt بيكون بيدوب
+
+496
+00:44:04,640 --> 00:44:10,740
+بناء على ذلك بنقدر نعمل عملية extraction نضيف
+
+497
+00:44:10,740 --> 00:44:15,820
+organic solvent وميّه هذا المُركّب وين بده يروح؟
+
+498
+00:44:15,820 --> 00:44:18,900
+على الميّه هذا بده يروح على ال organic solvent لو
+
+499
+00:44:18,900 --> 00:44:23,020
+افترضنا ال organic solvent إيثر بعدين إذا بخرنا ال
+
+500
+00:44:23,020 --> 00:44:27,470
+etherبيظل هذا المُركّب نقي طب هذا اللي ضال دايب في
+
+501
+00:44:27,470 --> 00:44:32,590
+الميّه .. بيضيف
+
+502
+00:44:32,590 --> 00:44:37,350
+نقاط NaOH لاحظوا الـ NaOH strong base بتروح بتسحب
+
+503
+00:44:37,350 --> 00:44:42,330
+الـ HCl اللي اتفاعل هنا بتتفاعل معه بتعطينا NaCl
+
+504
+00:44:42,330 --> 00:44:47,150
+زاد H2O وبرجع هذا ل organic بزامه رجع ل organic في
+
+505
+00:44:47,150 --> 00:44:52,770
+الميّه شو بيعمل؟ بترسبهو بيدوب في الميه لما يكون
+
+506
+00:44:52,770 --> 00:45:01,210
+Salt فإذا أنا نقطت نقط NaOH على الميه هتسحب منه ال
+
+507
+00:45:01,210 --> 00:45:05,330
+HCl هيرجع Organic وإذا ما رجع Organic بترسب كمادة
+
+508
+00:45:05,330 --> 00:45:11,530
+صلبة وبنعمله filtration واضح فالفكرة في فصل هدول
+
+509
+00:45:11,530 --> 00:45:15,990
+المركبين اللي هي الفكرة الأساسية أن هذا بتفعل as a
+
+510
+00:45:15,990 --> 00:45:18,950
+base هذا ما بتفعلش هذا ما بتفعل as a base بيعمل
+
+511
+00:45:18,950 --> 00:45:23,370
+عندكSalt هذا بيطلق organic، organic بنفصله
+
+512
+00:45:23,370 --> 00:45:27,270
+وبنبخره، طب هذا ال salt كيف بدنا نسترده؟ بنضيف
+
+513
+00:45:27,270 --> 00:45:32,050
+عليه Sodium Hydroxide بيرودي يتحول إلى ال aniline
+
+514
+00:45:32,050 --> 00:45:37,110
+و بنعمله filtration و بنفصله على أي حال إذا هذه
+
+515
+00:45:37,110 --> 00:45:44,430
+مرت عليكوا تجربة في الجزء العملي بإمكانكوا تشوفوا
+
+516
+00:45:44,430 --> 00:45:50,390
+بالمناسبة ال organic العملي نازل بالصيفنازل بالصيف
+
+517
+00:45:50,390 --> 00:45:53,630
+يعني الناس اللي عندهم فضاوة أنا شخصيا بنصحهم
+
+518
+00:45:53,630 --> 00:45:58,170
+ياخدوه بالصيف لإنه بالفصل الأول أعدادي كبيرة و
+
+519
+00:45:58,170 --> 00:46:02,230
+برضه انتوا عندكوا شغلكوا بالفصل الأول فال organic
+
+520
+00:46:02,230 --> 00:46:11,030
+العملي نازل بالصيف و ممكنكم تاخدوه على أي حال ابنه
+
+521
+00:46:11,030 --> 00:46:13,110
+و جفهان العملي
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/sCPLeVK9zQ0_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/sCPLeVK9zQ0_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..254223e8adc3fb1f89d9031feeb429d7ff9d4991
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/sCPLeVK9zQ0_postprocess.srt
@@ -0,0 +1,1764 @@
+1
+00:00:16,660 --> 00:00:23,000
+خلّيكم معنا إذا بتسمحوا .. لو سمحت .. لو سمحت ..
+
+2
+00:00:23,000 --> 00:00:29,020
+اليوم
+
+3
+00:00:29,020 --> 00:00:37,120
+إن شاء الله هنبدأ في درس تفاعلات ال alkanes واضح؟
+
+4
+00:00:37,120 --> 00:00:39,920
+طبعا إنتوا متذكرين من الحصة الماضية ال alkanes
+
+5
+00:00:39,920 --> 00:00:46,370
+المركبات اللي فيهمdouble bonds روابط زوجية طالما
+
+6
+00:00:46,370 --> 00:00:53,850
+المركب في double bond فتفاعله الأساسي هيكون تفاعل
+
+7
+00:00:53,850 --> 00:00:58,730
+إضافة معنى تفاعل إضافة أنه أنا ألغي ال double bond
+
+8
+00:00:58,730 --> 00:01:04,750
+هذه و أضيف مكانها دارتين واضح فدائما بنيجي بنقول
+
+9
+00:01:04,750 --> 00:01:11,040
+إحنا أنه لو كان في عندنا ال cans و ال cans مشبعةلو
+
+10
+00:01:11,040 --> 00:01:14,480
+كان فينا Alkenes والـ Alkenes مشبعة تفاعلها
+
+11
+00:01:14,480 --> 00:01:19,120
+الأساسي إبدال لأن أنا عندي أربع ذرات على الـ
+
+12
+00:01:19,120 --> 00:01:23,600
+Carbon مش ممكن أن أعمل أي إضافة لكن في حالة الـ
+
+13
+00:01:23,600 --> 00:01:27,100
+Alkenes اللي فيهم Double Bonds وفي حالة الـ
+
+14
+00:01:27,100 --> 00:01:30,340
+Alkynes اللي فيهم Triple Bond هتلاحظوا أن التفاعل
+
+15
+00:01:30,340 --> 00:01:35,220
+الأساسي هو تفاعل إضافة معنى تفاعل الإضافة معنى
+
+16
+00:01:35,220 --> 00:01:39,080
+تفاعل الإضافة أنه أنا بألغي Double Bond و بحط
+
+17
+00:01:39,080 --> 00:01:39,820
+مكانها
+
+18
+00:01:49,000 --> 00:01:55,470
+الان في موضوع التفاعلاتهتلاحظوا القاتل ان احنا
+
+19
+00:01:55,470 --> 00:01:58,850
+بنتعامل مع الكين ال الكين هو اللي بيتم عليه
+
+20
+00:01:58,850 --> 00:02:05,170
+التفاعل و بنتعامل بنفس الوقت مع reagent ال reagent
+
+21
+00:02:05,170 --> 00:02:09,970
+هو المادة اللي فيها ذرتين هدول الذرتين بنضيفه على
+
+22
+00:02:09,970 --> 00:02:14,650
+ال الكين يعني احنا لما بنعمل عملية الإضافة الإضافة
+
+23
+00:02:14,650 --> 00:02:22,080
+مكونة من شغلتين الكين و reagentالـ Reagent لازم
+
+24
+00:02:22,080 --> 00:02:27,440
+يكون فيه ذرتين مثلا ممكن يكون هيدروجين برومين مية
+
+25
+00:02:27,440 --> 00:02:31,880
+HCL على أساس أن ذرة منهم بتضيف هان لما بلغت double
+
+26
+00:02:31,880 --> 00:02:36,500
+bond وذرة منهم بتضيف هان هذه عملية ال addition
+
+27
+00:02:36,500 --> 00:02:41,580
+واضح؟ إذا ال addition المكونات تبعت عبارة عن إيش؟
+
+28
+00:02:43,950 --> 00:02:50,250
+الان المفروض تتطلعوا انتوا شوية على مواصفات
+
+29
+00:02:50,250 --> 00:02:56,710
+الالكين ومواصفات ال الرياجين اللى بتطلع بانتباه هى
+
+30
+00:02:56,710 --> 00:03:02,750
+في عندى الكين معين اللى هو الاثين او الاثلين وهى
+
+31
+00:03:02,750 --> 00:03:08,550
+في عندى الكين تانى الكين تانى اللى هو البروبيل
+
+32
+00:03:09,440 --> 00:03:15,800
+بتذكرين ال probine CH2 CH3
+
+33
+00:03:15,800 --> 00:03:22,580
+هذا الكين وهذا الكين هذا إيثين وهذا ال probine
+
+34
+00:03:22,580 --> 00:03:27,140
+الآن إذا بتطلعوا بنظرة فاحصة على هدول ال two
+
+35
+00:03:27,140 --> 00:03:32,640
+alkenes هتلاحظوا شغلة أن ال الكين يمكن أن يكون
+
+36
+00:03:32,640 --> 00:03:37,800
+متماثلمن الجهتين يعني إذا بتطلع على ال aethene هذا
+
+37
+00:03:37,800 --> 00:03:41,020
+او ال aethylene و اتخيلتوا انتوا ان عندكم مراية
+
+38
+00:03:41,020 --> 00:03:48,500
+هيك من النص هذا الجزء زي هذا الجزء واضح؟ اذا ال
+
+39
+00:03:48,500 --> 00:03:54,340
+aethylene عبارة عن symmetrical ال keen هو ال keen
+
+40
+00:03:54,340 --> 00:03:58,960
+متماثل هاي لو حطيت مراية هدول نفسهم هيبينوا اين؟
+
+41
+00:03:58,960 --> 00:04:05,350
+على الجهة التانيةواضح؟ الان لو اجينا اتطلعنا .. لو
+
+42
+00:04:05,350 --> 00:04:10,170
+اجينا اتطلعنا على لبروبيين و اتخيلوا انه بتكون ..
+
+43
+00:04:10,170 --> 00:04:13,370
+هي ال double bond و حطه مرايا زي هيك .. هل
+
+44
+00:04:13,370 --> 00:04:18,950
+لبروبيين جزء متماثل ولا غير متماثل؟ لأ .. اه ..
+
+45
+00:04:18,950 --> 00:04:24,140
+اذا الالكين يقسم الى ..نوعين يمكن أن يكون الالكين
+
+46
+00:04:24,140 --> 00:04:28,520
+متماثل جزءه اليمين صورة الجزء الثاني في المرأة
+
+47
+00:04:28,520 --> 00:04:34,340
+ويمكن أن يكون الالكين غير متماثل الاثين is
+
+48
+00:04:34,340 --> 00:04:41,360
+asymmetrical الكين البروبين is unsymmetrical الكين
+
+49
+00:04:41,360 --> 00:04:47,040
+واضح هذه النقطة؟ الآن لو اجينا تطلعنا على المكون
+
+50
+00:04:47,040 --> 00:04:51,840
+التاني لمكونات الإضافة اللي هو ال reagentممكن انا
+
+51
+00:04:51,840 --> 00:04:57,640
+اضيف مثلا الهيدروجين الهيدروجين جزء H single bond
+
+52
+00:04:57,640 --> 00:05:03,380
+H اتطلع عليه بنفس المنطق هل يا ترى هذا الهيدروجين
+
+53
+00:05:03,380 --> 00:05:10,240
+متماثل ولا غير متماثل اذا الهيدروجين متماثل ممكن
+
+54
+00:05:10,240 --> 00:05:23,210
+اضيف انا جزء كلورين Cl2 Cl single bondالـ HCL ممكن
+
+55
+00:05:23,210 --> 00:05:29,750
+اضيف الـ HCL
+
+56
+00:05:29,750 --> 00:05:35,190
+ممكن
+
+57
+00:05:35,190 --> 00:05:38,990
+اضيف الـ HCL ممكن اضيف الـ HCL
+
+58
+00:05:45,800 --> 00:05:51,700
+ممكن اضيف الميه الميه لما بتضيف بتضيف كجزء اين H
+
+59
+00:05:51,700 --> 00:06:01,720
+جزء و OH هذا الصغير هذا جزء OHالميّه بنعملها كإنها
+
+60
+00:06:01,720 --> 00:06:06,720
+H or OH الان هل الميّه بهذا الشكل symmetrical ولا
+
+61
+00:06:06,720 --> 00:06:12,400
+unsymmetrical الميّه unsymmetrical اذا بنا ننتبه
+
+62
+00:06:12,400 --> 00:06:15,920
+لشغله انه احنا لما بنعمل تفاعل ال الكين مع
+
+63
+00:06:15,920 --> 00:06:20,540
+reagents معينة في عندنا احتمالين في ال الكين وفي
+
+64
+00:06:20,540 --> 00:06:23,340
+عندنا احتمالين في ال reagent ال الكين can be
+
+65
+00:06:23,340 --> 00:06:27,740
+symmetrical or unsymmetrical و ال reagent can be
+
+66
+00:06:30,170 --> 00:06:37,350
+الان ممكن اضيف simetrical reagent على simetrical
+
+67
+00:06:37,350 --> 00:06:44,040
+alkene زي هيكواطلعوا انتوا معاه بشكل هادئ لو ضفته
+
+68
+00:06:44,040 --> 00:06:47,980
+وحطيتها نقاتش وها نقاتش بيفرق هذا ال reagent لو
+
+69
+00:06:47,980 --> 00:06:52,780
+مسكته زي هيك ولا مسكته زي هيك هل متوقع يطلع اكتر
+
+70
+00:06:52,780 --> 00:06:58,600
+من جزيء اذا اضافة ال symmetrical reagent ع ال
+
+71
+00:06:58,600 --> 00:07:06,070
+symmetrical ال keen بطلع لكم product كم جزيءواحد
+
+72
+00:07:06,070 --> 00:07:13,990
+واضح اذا لو احنا بدنا نحاول يعني نعمل ملخص صغير
+
+73
+00:07:13,990 --> 00:07:20,690
+نضيع هذا شوية نعمل ملخص صغير يعني بدنا نتخيل ان
+
+74
+00:07:20,690 --> 00:07:28,330
+احنا عندنا ال keen و في عندنا reagent لما ال keen
+
+75
+00:07:28,330 --> 00:07:32,690
+يكون symmetric و ال reagent يكون symmetric هكا
+
+76
+00:07:32,690 --> 00:07:34,330
+product فيطلع عندنا
+
+77
+00:07:38,540 --> 00:07:43,240
+لما يكون ال الكين سيمتريك و ال reactant سيمتريك
+
+78
+00:07:43,240 --> 00:07:47,860
+عنده product او احتمال واحد طيب لو اخدت هذا ال
+
+79
+00:07:47,860 --> 00:07:54,390
+reactant السيمتريك و قلت بدي افعله على البروبينو
+
+80
+00:07:54,390 --> 00:07:59,090
+احنا اتفقنا ان البروبين is unsymmetric هل يا تورا
+
+81
+00:07:59,090 --> 00:08:02,510
+لما بدي اضيف الهيدروجين بهذا الشكل تيجي اتشان و
+
+82
+00:08:02,510 --> 00:08:07,530
+اتشان، هيفرق انه هيك اضيفه ولا هيك ولا حد؟ اذا
+
+83
+00:08:07,530 --> 00:08:16,490
+برضه هيطلع ناتج واحد فإضافة ال symmetrical reagent
+
+84
+00:08:16,490 --> 00:08:20,630
+على ال unsymmetrical alkene برضه بيطلعلي إيش؟ one
+
+85
+00:08:20,630 --> 00:08:29,050
+productطب ممكن نفكر نضيف unsymmetrical reagent زي
+
+86
+00:08:29,050 --> 00:08:35,790
+ال HCl على symmetrical alkene بده احط HCl احط هنا
+
+87
+00:08:35,790 --> 00:08:41,510
+H وهنا Cl ولا هنا H وهنا Cl؟لأ و الله ناتج واحد
+
+88
+00:08:41,510 --> 00:08:47,670
+حيطلع عندكوا ع الجهة CH3 وعالتانية CH2CL لو عملنا
+
+89
+00:08:47,670 --> 00:08:54,650
+هيك CH3 وCH2CL و لو عملنا هيك CH3 وCH2CL ناتج واحد
+
+90
+00:08:54,650 --> 00:09:01,730
+اذا لما انا باجي باضيف symmetrical ال key
+
+91
+00:09:07,150 --> 00:09:11,150
+ناتج واحد برضه المتوقع اندي ناتج واحد ضال شغلة
+
+92
+00:09:11,150 --> 00:09:16,910
+اخيرة ان انا اجي اضيف unsymmetrical reagent على
+
+93
+00:09:16,910 --> 00:09:21,110
+unsymmetrical alkene ال reagent غير متماثل
+
+94
+00:09:21,110 --> 00:09:25,770
+والalkene غير متماثل الان اتطلع لو بدى اضيف بهذا
+
+95
+00:09:25,770 --> 00:09:30,870
+الشكل اذا مسكت reagent زي هيك هذه هتصير الطرف CH3
+
+96
+00:09:33,780 --> 00:09:37,980
+الـCl يعني الـCl وين إجت؟ عن نُص، على الكربون
+
+97
+00:09:37,980 --> 00:09:44,760
+الوسطانية، لو مسكته زي هيك، حيطلع عندي CH2Cl و هنا
+
+98
+00:09:44,760 --> 00:09:49,780
+في الوسط حيصير CH2 واضح تباماً بهذه الحالة أنه
+
+99
+00:09:49,780 --> 00:09:55,280
+بيطلع عندكم إيش؟ كم ناتج؟ ناتجين، من ناحية النظرية
+
+100
+00:09:55,280 --> 00:09:59,060
+البحثة، إذا أنا في الحالة اللي باضيف فيها
+
+101
+00:09:59,060 --> 00:10:01,500
+Unsymmetrical
+
+102
+00:10:04,160 --> 00:10:09,380
+الـ Keen و Unsymmetrical الـ Pre-agent متوقع يطلع
+
+103
+00:10:09,380 --> 00:10:14,700
+عنده نتيجة الان هذا التوقع هو توقع نظري في التجربة
+
+104
+00:10:14,700 --> 00:10:21,470
+يطلع واحد او اتنين مابنعرفشواضح؟ تماما زي إنسان في
+
+105
+00:10:21,470 --> 00:10:25,170
+عنده طريقين متفرعين، هو عنده احتمالين، بعدين يمشي
+
+106
+00:10:25,170 --> 00:10:28,570
+منها و لا يمشي منها، هذا موضوع إيش؟ تاني، لكن من
+
+107
+00:10:28,570 --> 00:10:32,690
+ناحية الاحتمالات، ممكن يطلع هيك و ممكن يطلع هيك،
+
+108
+00:10:32,690 --> 00:10:39,910
+واضح؟ إذا، وكتش بيطلع عنده احتمالين أو ناتجين، لما
+
+109
+00:10:39,910 --> 00:10:44,550
+أنا بفعل unsymmetrical مع unsymmetricalواضح؟ هذه
+
+110
+00:10:44,550 --> 00:10:48,570
+الحالة الوحيدة انه اذا انا فعلت unsymmetrical
+
+111
+00:10:48,570 --> 00:10:53,070
+reagent على unsymmetrical alkene متوقع يطلع عندي
+
+112
+00:10:53,070 --> 00:10:58,610
+نتيجة اذا بدها انتباه اكتر وبدها دراسة اكتر، واضح؟
+
+113
+00:10:58,610 --> 00:11:03,530
+هذه مقدمة، الآن احنا هنبدأ ناخد امثلة، ناخد مثلا
+
+114
+00:11:03,530 --> 00:11:07,790
+إضافة الهيدروجين عكذا، إضافة Cl2، إضافة HCl، إضافة
+
+115
+00:11:07,790 --> 00:11:14,370
+H2O، في كل حالةبدنا نحلل و احنا بنعمل التفاعل هل
+
+116
+00:11:14,370 --> 00:11:18,790
+المتوقع يطلع عندى ناتج او اتنين اذا المتوقع يطلع
+
+117
+00:11:18,790 --> 00:11:22,970
+ناتج الامر بيكون ايش اسهل اذا المتوقع يطلع ناتجين
+
+118
+00:11:22,970 --> 00:11:29,330
+الامر بيكون شوية بده تفصيلات مافيش اشي صعب لكن فيه
+
+119
+00:11:29,330 --> 00:11:34,850
+اشي بيكون بحاجة الى تفصيل يعني مافيش اشي صعب في
+
+120
+00:11:34,850 --> 00:11:35,790
+الدنيا او مستحيل
+
+121
+00:11:41,220 --> 00:12:05,220
+بحاجة إلى تفاصيلات أداء
+
+122
+00:12:05,220 --> 00:12:10,000
+المقدم على تحديث طبيعة الألكين وطبيعة الـ Reagent
+
+123
+00:12:10,420 --> 00:12:16,840
+بصير أسهل علينا أن ناخد أمثلة متنوعة النوع الأول
+
+124
+00:12:16,840 --> 00:12:21,900
+اللي بدنا ناخده اللي هو إضافة جزء هيدروجين على
+
+125
+00:12:21,900 --> 00:12:25,700
+الألكين واضح؟ هذه العملية بنسميها احنا reduction
+
+126
+00:12:25,700 --> 00:12:31,380
+بمعنى تحويل الألكين إلى ألكين هي عملية reduction
+
+127
+00:12:31,380 --> 00:12:36,680
+واضح؟ تحويل الألكين إلى الألكين هي عملية reduction
+
+128
+00:12:36,680 --> 00:12:41,970
+إضافة الهيدروجين بشكل عامما بتتمش لحاله، يعني لو
+
+129
+00:12:41,970 --> 00:12:46,010
+أنا جبت الكيل وخلطت معه هيدروجين وبدأ أستنهم
+
+130
+00:12:46,010 --> 00:12:50,450
+يتفاعلوا، مابتفاعلوش بسهولة، لأ، بده من وجود
+
+131
+00:12:50,450 --> 00:12:56,750
+catalyst، ال catalyst غالبا هو معدن، metalواضح؟
+
+132
+00:12:56,750 --> 00:13:00,210
+مثل البلاتين مثل ال .. مثل ال nickel مثل ال
+
+133
+00:13:00,210 --> 00:13:04,070
+palladium في عدة catalyst البلاتين وال nickel من
+
+134
+00:13:04,070 --> 00:13:08,810
+ال catalyst أو العوامل المساعدة المشهورة بهذه
+
+135
+00:13:08,810 --> 00:13:12,070
+الحالة ال hydrogen في وجود ال metal بنضيف على
+
+136
+00:13:12,070 --> 00:13:16,930
+الجهتين واحنا قلنا في النهاية المتوقع كام ناتج
+
+137
+00:13:16,930 --> 00:13:22,310
+عندنا إضافة ال hydrogen على ال alkene متوقع منه
+
+138
+00:13:22,310 --> 00:13:28,600
+ناتج واحدالان اللي لاحظوه انه ذرتين الهيدروجين
+
+139
+00:13:28,600 --> 00:13:32,280
+ذرتين الهيدروجين لما بيضيفوا على القلقين بيعملوا
+
+140
+00:13:32,280 --> 00:13:35,800
+شغلة بيسميها sin addition ايش يعني sin addition؟
+
+141
+00:13:35,800 --> 00:13:39,940
+يعني الذرتين بييجوا من جهة واحدة بيضيفوا يعني
+
+142
+00:13:39,940 --> 00:13:43,860
+مابيجوش لو بدي اتخيل ان عندي ذرتين هيدروجين هيك
+
+143
+00:13:43,860 --> 00:13:50,260
+واحدة من اليمين واحدة من الشمال هذا الإضافة بهذا
+
+144
+00:13:50,260 --> 00:13:55,760
+الشكل ذرة وبهذا الشكل ذرةكأنهم ذرتين مفصلات هذا
+
+145
+00:13:55,760 --> 00:14:01,560
+بنسميها Anti-addition إضافة متعاكسة الآن إضافة
+
+146
+00:14:01,560 --> 00:14:07,200
+الذرتين من جهة واحدة بنسميها Sin addition فللاحظوا
+
+147
+00:14:07,200 --> 00:14:15,230
+إن إضافة الهيدروجين على السن اديشن و بتنفي وجود
+
+148
+00:14:15,230 --> 00:14:21,330
+متل surface على سطح معدن الان ليش بتصير اضافة
+
+149
+00:14:21,330 --> 00:14:26,410
+الهيدروجين سن اديشن مش انت اديشن اللي بيصير ان
+
+150
+00:14:26,410 --> 00:14:32,430
+الهيدروجين كجزاء عشان الضيف بده ينكسروا الرابط
+
+151
+00:14:32,430 --> 00:14:36,080
+اللي بين الذرتينمش هم ذرتين الهيدروجين هيوم ممسكين
+
+152
+00:14:36,080 --> 00:14:40,220
+برابطة بدا تنكسر هذه الرابطة اللى بين ذرتين
+
+153
+00:14:40,220 --> 00:14:42,900
+الهيدروجين عشان هذه بتضيف على جهة و هذه بتضيف على
+
+154
+00:14:42,900 --> 00:14:51,650
+جهة تانية فالهيدروجين بيلتصق بسطح المعدنملاحظين
+
+155
+00:14:51,650 --> 00:14:56,410
+بهذا الشكل الهيدروجين يلتصق في سطح المعدن لما بتتم
+
+156
+00:14:56,410 --> 00:15:00,350
+الإضافة بتقدر تقول ان هذه الرابطة انكسرت هذه
+
+157
+00:15:00,350 --> 00:15:04,270
+الهيدروجين مع ال bond بتلف بهذا الشكل و هذا ال
+
+158
+00:15:04,270 --> 00:15:07,990
+bond بتلف بهذا الشكل بيصير عندي رابطتين اجدادا
+
+159
+00:15:07,990 --> 00:15:13,390
+لاحظوا كيف هى عندى ال double bond بتبقى single
+
+160
+00:15:13,390 --> 00:15:17,330
+bond الان هذه الرابطة و الهيدروجين نفسه ملتصق في
+
+161
+00:15:17,330 --> 00:15:23,460
+المعدن بتلف بهذا الشكلهذه الرابطة دلت مع
+
+162
+00:15:23,460 --> 00:15:27,160
+الهيدروجين عملت handle طبعا أنا مستحيل أصيره خمسة،
+
+163
+00:15:27,160 --> 00:15:31,520
+إيش بيصير على طول؟ هذي بتنزل، الحركتين بتتموا بنفس
+
+164
+00:15:31,520 --> 00:15:34,760
+الوقت عشان يظل عندي كام رابطة في النهاية؟ أربع
+
+165
+00:15:34,760 --> 00:15:38,420
+رابط، شوفتوا كيف بتتم ال addition؟ فالهيدروجين هنا
+
+166
+00:15:38,420 --> 00:15:43,660
+طالما أنه ممسوك على سطح المعدن، التنتين، إذا لازم
+
+167
+00:15:43,660 --> 00:15:49,460
+التنتين يضيفوا؟ من جهة واحدةمش ممكن يكونوا ممسكين
+
+168
+00:15:49,460 --> 00:15:53,480
+الهيدروجينتين على سطح المعدن و ييجوا يضيفوا واحدة
+
+169
+00:15:53,480 --> 00:15:55,820
+من جهة و اتانية من جهة تانية هين انا امسكهم لو
+
+170
+00:15:55,820 --> 00:15:58,580
+اتخيلت انا ال double bond هل ممكن اضيف واحدة من
+
+171
+00:15:58,580 --> 00:16:01,280
+هنا و واحدة من هنا و انا امسكهم زي هيك و بتعمل
+
+172
+00:16:01,280 --> 00:16:06,480
+الإضافة مستحيل واضح فطالما ان الهيدروجين بيقول
+
+173
+00:16:06,480 --> 00:16:10,100
+عنهم they are absorbed at the metal surface ايش
+
+174
+00:16:10,100 --> 00:16:11,280
+يعني absorbed؟
+
+175
+00:16:13,700 --> 00:16:17,300
+ملتصقة .. ملتصقة التصاق .. بتكون .. اتفرجوا بين
+
+176
+00:16:17,300 --> 00:16:21,500
+كلمتين في الكيميا .. بين كلمة absorption وكلمة
+
+177
+00:16:21,500 --> 00:16:26,400
+adsorption .. adsorption بال D .. absorption بال B
+
+178
+00:16:26,400 --> 00:16:30,300
+.. absorption هو التصاقش على السطح .. زي هيك
+
+179
+00:16:30,920 --> 00:16:35,640
+الملاحظين هذه العملية التصاق على السطح ايش بنسميها
+
+180
+00:16:35,640 --> 00:16:39,900
+احنا absorption فالهيدروجين بيكون على سطح المعدن
+
+181
+00:16:39,900 --> 00:16:42,960
+زي هيك لو تخيلنا هذا معدن الهيدروجين بيكون
+
+182
+00:16:42,960 --> 00:16:49,360
+absorbed على ال surface لكن absorption هي عملية
+
+183
+00:16:49,360 --> 00:16:53,660
+بيدخل فيها الهيدروجين جوا المعدن واضح؟ يعني لو
+
+184
+00:16:53,660 --> 00:16:57,840
+تخيلنا زي هيك هذه الآن ذرة الهيدروجين شو صير لها؟
+
+185
+00:16:59,170 --> 00:17:04,710
+absorption جوا المعدن هل يا تورا المعدن سهل ان
+
+186
+00:17:04,710 --> 00:17:09,490
+الهيدروجين يدخل في جلبه مستحيل دائما اي شي على
+
+187
+00:17:09,490 --> 00:17:14,230
+المعدن بالتصق من الخارج مش ممكن يصير absorption
+
+188
+00:17:14,230 --> 00:17:18,550
+جوا المعدن واضح فالهيدروجين لانه بيكون absorbed at
+
+189
+00:17:18,550 --> 00:17:23,670
+the metal surface بيعمل sin addition الهيدروجين
+
+190
+00:17:23,670 --> 00:17:27,210
+بيعمل sin addition فلو تخيلتوا مثلا انه كان عندكم
+
+191
+00:17:29,970 --> 00:17:39,330
+التو هيدروجينز بيضيفه من جهة واحدة
+
+192
+00:17:39,330 --> 00:17:46,310
+عندنا هنا كتير امثلة احنا حاطينها طبعا مركبات
+
+193
+00:17:46,310 --> 00:17:50,330
+كبيرة صغيرة مش مشكلة المهم انه في عندى double bond
+
+194
+00:17:51,220 --> 00:17:56,320
+و في عندى hydrogen و بدأتم عملية الاضافة فبالمثال
+
+195
+00:17:56,320 --> 00:18:02,140
+الاول مثلا هنا بتضاف دين hydrogen لاحظوا ان ال
+
+196
+00:18:02,140 --> 00:18:06,880
+alkene ال double bond ايش صارت؟ اركان هو اختصر ال
+
+197
+00:18:06,880 --> 00:18:12,100
+hydrogen برسم همش بس واضح انه صارت تفاعل ليش؟ لان
+
+198
+00:18:12,100 --> 00:18:13,020
+ال double bond
+
+199
+00:18:29,410 --> 00:18:33,710
+بتلاحظوا لما بورسم ال hydrogen عملوا قاعد بيعطيكم
+
+200
+00:18:34,420 --> 00:18:38,440
+هل هم ضيفين من جهة واحدة ولا لا .. واضح .. sin
+
+201
+00:18:38,440 --> 00:18:42,480
+addition .. وكذلك الحال في هذا المثال .. هذا
+
+202
+00:18:42,480 --> 00:18:46,600
+Cyclopentane وعليه مجموعتين مثل .. لما بده يضيف
+
+203
+00:18:46,600 --> 00:18:50,320
+الهيدروجيل .. بيضيف من جهة واحدة .. فلو افترض انه
+
+204
+00:18:50,320 --> 00:18:53,700
+مثلا اتي الهيدروجيل buff من تحت .. فعلى الحلقة
+
+205
+00:18:56,860 --> 00:19:01,780
+بيصيروا لفوق للأعلى ومجمعتين الهيدروجين لتحت في
+
+206
+00:19:01,780 --> 00:19:06,040
+هذه الحالة بينتج عند ال cis ولا ال trans ايزو مار
+
+207
+00:19:06,040 --> 00:19:11,140
+ال cis ايزو مار واضح ال cis ايزو مار في الجزيء
+
+208
+00:19:11,140 --> 00:19:15,860
+الأصلي كانوا مجموعات ال مثل هنا في نفس مستوى
+
+209
+00:19:15,860 --> 00:19:20,630
+الجزيءهدولة في نفس مستوى الرابطة اللى هنا يعنى ..
+
+210
+00:19:20,630 --> 00:19:24,810
+هدى المنطقة .. هدى المنطقة مش كل الجزء بلانر احنا
+
+211
+00:19:24,810 --> 00:19:28,110
+نقول هدى المنطقة في الـ cyclopentane عاملة زى إيش؟
+
+212
+00:19:28,110 --> 00:19:31,310
+زى ال envelope .. هدى الجزء إذا ما تذكرينه لكن
+
+213
+00:19:31,310 --> 00:19:37,610
+حوالين هدى الرابطة .. هدى بلانر فالمثل والمثل و
+
+214
+00:19:37,610 --> 00:19:40,770
+هدى الرابطة و هدى الرابطة في نفس المستوى لما يجى
+
+215
+00:19:40,770 --> 00:19:44,860
+هيدروجين يضيف من جهة واحدة تنتينشو بيصير في
+
+216
+00:19:44,860 --> 00:19:48,220
+المجموعتين التانيين؟ هيروح على الجهة التانية
+
+217
+00:19:48,220 --> 00:19:54,140
+فالاضافة على ال one two dimethylcyclobentane
+
+218
+00:19:54,140 --> 00:19:57,680
+بتعطينا ال sis ولا ال trans؟ one two
+
+219
+00:19:57,680 --> 00:20:01,560
+dimethylcyclobentane ال sis because the addition
+
+220
+00:20:01,560 --> 00:20:06,980
+of hydrogen is sin addition كم ناتج متوقع في كل
+
+221
+00:20:06,980 --> 00:20:12,790
+الحلات؟ واحد، ليش؟لأنه بيكفين أنه الهيدروجين
+
+222
+00:20:12,790 --> 00:20:18,130
+symmetrical بغض النظر عن التاني الآن الكلام نفسه
+
+223
+00:20:18,130 --> 00:20:22,850
+بتكرر ومافيش داعي نكتر كلام فيه لو كنا بنضيف جزء
+
+224
+00:20:22,850 --> 00:20:31,000
+زي الchlor Cl2 أو زي ال brom Br2 واضح؟فاذا ضيفت
+
+225
+00:20:31,000 --> 00:20:36,700
+انا لبرومين او لكلورين كام ناتج متوقع ناتج واحد
+
+226
+00:20:36,700 --> 00:20:42,820
+لكن اللي لاحظوه في حالة اضافة لبرومين انه ذرتين
+
+227
+00:20:42,820 --> 00:20:47,340
+لبروم بيضيفوا anti addition مش sin addition
+
+228
+00:20:47,340 --> 00:20:52,360
+بيضيفوا جهتين مختلفتين طيب تعالوا فاكروا فيها كيف
+
+229
+00:20:52,360 --> 00:20:56,320
+ممكن تصير ان هاي بروم و بروم هدول افترضوهم كيف
+
+230
+00:20:56,320 --> 00:21:01,190
+بدهم يضيفوا anti additionلابد إلا في الأول يصير
+
+231
+00:21:01,190 --> 00:21:07,250
+انكسار بينهم عشان هذه .. لو انهم يضيفوا و يضيفوا و
+
+232
+00:21:07,250 --> 00:21:10,070
+يضيفوا زي هيك و لآخر لحظة يتم الكسر .. لازم يضيفوا
+
+233
+00:21:10,070 --> 00:21:14,870
+إيش؟ تضيفوا sin addition .. لكن لما يصير كسر زي
+
+234
+00:21:14,870 --> 00:21:20,390
+هيك .. لما يصير عندك نمط ما من الكسر .. بتقدر هذا
+
+235
+00:21:20,390 --> 00:21:23,230
+يضيف من هنا و هذا يضيف من هنا .. بيقدر يصير عندك
+
+236
+00:21:23,230 --> 00:21:28,080
+ال anti addition .. واضح؟فاللي لوحظ بالتجربة ان
+
+237
+00:21:28,080 --> 00:21:34,160
+إضافة لبروم is trans or anti-additional يعني بتضيف
+
+238
+00:21:34,160 --> 00:21:40,580
+من جهتين متعاكستين الآن كيف القالية .. كيف القالية
+
+239
+00:21:40,580 --> 00:21:46,060
+اللي بتتم فيها عملية الإضافة جزء لبرومين هذا جزء
+
+240
+00:21:46,060 --> 00:21:50,560
+لبرومين زي ما انتوا عارفينه non-polar واضح؟ لكن
+
+241
+00:21:50,560 --> 00:21:56,290
+ممكنفي لحظة من اللحظات يصير polarized يعني يصير
+
+242
+00:21:56,290 --> 00:22:00,490
+فيه نوع من الخطبية الأصل أنه الإلكترونات في
+
+243
+00:22:00,490 --> 00:22:06,010
+البرومين موجودة بالتساوي ما بين ذرتين البروم
+
+244
+00:22:06,010 --> 00:22:10,440
+إلكترونات الرابطةموجودة بالتساوم بين ذرتين البروم
+
+245
+00:22:10,440 --> 00:22:16,760
+لكن لما جزء البروم هذا لما جزء البروم بيجي بيقترب
+
+246
+00:22:16,760 --> 00:22:20,860
+بيجي بيقترب من double bond هذا double bond كثافة
+
+247
+00:22:20,860 --> 00:22:25,540
+إلكترونية الإلكترونات اللي هنا بدهم يبعدوا ولا
+
+248
+00:22:25,540 --> 00:22:30,920
+بدهم يقربوا دايما الإلكترونات ع بعض بتتنافع فبناء
+
+249
+00:22:30,920 --> 00:22:34,180
+على ذلك لما هذا الجزء بيجي يتفعل بهذا الشكل
+
+250
+00:22:34,180 --> 00:22:37,080
+إلكترونات الرابطة كانوا بدهم يروحوا على جهة إيش
+
+251
+00:22:37,860 --> 00:22:43,080
+البروم فبصير كأنه صار عند بروم سالب كله بيشهد من
+
+252
+00:22:43,080 --> 00:22:48,420
+الإلكترونات و بروم موجب واضح هذا البروم الموجب هو
+
+253
+00:22:48,420 --> 00:22:54,320
+اللي بيضيف هنا بيعمل على شكل حلقة رابطتين وبالتالي
+
+254
+00:22:54,320 --> 00:22:58,380
+بيصير البرومين positive لأن البروم عادة في الوضع
+
+255
+00:22:58,380 --> 00:23:02,910
+الطبيعي بيعمل كام رابطةرابطة واحدة إذا عمل رابطتين
+
+256
+00:23:02,910 --> 00:23:06,630
+و بدنا نحسب ال formal charge تبعته هلاحظ ان هو
+
+257
+00:23:06,630 --> 00:23:11,290
+برومين positive الان هذا البرومين positive مش ثابت
+
+258
+00:23:11,290 --> 00:23:17,070
+يعني يتكون لجزء من الثانية طالما هذا البرومين
+
+259
+00:23:17,070 --> 00:23:23,290
+positive انوجد زي هيكو مش ثابت ضال عنده البرومين
+
+260
+00:23:23,290 --> 00:23:28,090
+negative البرومين negative طالما هذه مسكرة بروابط
+
+261
+00:23:28,090 --> 00:23:33,980
+من وين مضطر ييجي يضيفمن الجهة المعاكسة إذا عملية
+
+262
+00:23:33,980 --> 00:23:38,140
+إضافة البروم هنا تتم على مرحلة ولا على مرحلتين؟
+
+263
+00:23:38,140 --> 00:23:41,720
+على مرحلتين المرحلة الأولى بيصير فيها نوع من
+
+264
+00:23:41,720 --> 00:23:47,100
+الاستقطاب يعني كأنه أنا جسمت الجزئة موجب و سالب
+
+265
+00:23:47,100 --> 00:23:51,920
+بضيف الموجب بيعمل ايون بروم موجب و دايما الايونات
+
+266
+00:23:51,920 --> 00:23:59,200
+الموجبة بنسميها onion ions ايش يعني onion؟Ion موجب
+
+267
+00:23:59,200 --> 00:24:02,900
+بتذكروا مثلا كانوا يمروا عليكم كلمة ammonium
+
+268
+00:24:02,900 --> 00:24:07,900
+امونيوم
+
+269
+00:24:07,900 --> 00:24:11,960
+ايون موجب لو مع ال oxygen ايون موجب شو بتسميه
+
+270
+00:24:11,960 --> 00:24:18,060
+اكزونيوم لو مع ال chlorine اكلورونيوم لو مع البروم
+
+271
+00:24:18,060 --> 00:24:24,400
+ابرومونيوم واضح؟فدائما النهاية onium بتعني ايون
+
+272
+00:24:24,400 --> 00:24:33,340
+موجب فعشان يتحول إلى جزء
+
+273
+00:24:33,340 --> 00:24:37,160
+موجب يضيف في البداية بيعمل البرومونيوم ايون بهذا
+
+274
+00:24:37,160 --> 00:24:42,770
+الشكل ثم يكتمل التفاعل من الجهة المعاكسةبإضافة
+
+275
+00:24:42,770 --> 00:24:46,790
+الجزء السالب طبعا مستحيل إنه يبقى جهة تريف من هنا
+
+276
+00:24:46,790 --> 00:24:50,830
+و جهة أشمالها مبلوغ مجرد ما يجي السالب هذا هنا
+
+277
+00:24:50,830 --> 00:24:54,970
+بترجع الرابط على البروم و بيكون لي رابط احدية بحصل
+
+278
+00:24:54,970 --> 00:25:02,850
+على جزء متعدل بهيك إيش بتلاحظه ان البروم أو
+
+279
+00:25:02,850 --> 00:25:08,870
+البرومين addition is Anti addition Anti يعني يتم
+
+280
+00:25:08,870 --> 00:25:14,470
+من جهتينيتم من جهتين مختلفتين واضح إيش الفرق بين
+
+281
+00:25:14,470 --> 00:25:19,030
+إضافة الهيدروجين وإضافة البرومين الهيدروجين is a
+
+282
+00:25:19,030 --> 00:25:22,370
+one step addition يعني التنتير بيضيفه من جهة واحدة
+
+283
+00:25:22,370 --> 00:25:27,190
+البرومين is a two step يعني طالما صارت الإضافة من
+
+284
+00:25:27,190 --> 00:25:31,010
+جهتين إذا لازم واحد اضاف من الأول والتان إجا بعدين
+
+285
+00:25:31,010 --> 00:25:35,850
+فهنا بتلاحظ اي step واي ناتج النهائيطبعا هل هذا
+
+286
+00:25:35,850 --> 00:25:39,710
+ابن ميسكو احنا و لا هدى شغل اثناء التفاعل بتصير
+
+287
+00:25:39,710 --> 00:25:45,230
+بسرعة احنا ايش ناتج الابن ميسكو؟ هذا عشان سبق ان
+
+288
+00:25:45,230 --> 00:25:47,970
+حكينا قولنالكوا انكوا تميزوا بين شغلتين بين
+
+289
+00:25:47,970 --> 00:25:53,010
+reaction اللى هو reactants و product و بين ميكانزم
+
+290
+00:25:53,010 --> 00:25:57,250
+اللى هي خطوات تفصيلية بتتم لكن احنا مش شايفينها
+
+291
+00:25:57,250 --> 00:26:03,470
+واضح؟ اذا فى عندنا reaction اللى هوreactants بتصير
+
+292
+00:26:03,470 --> 00:26:07,830
+product وفي عندى detailed steps لكن هل بفصل نواتيش
+
+293
+00:26:07,830 --> 00:26:12,090
+هال detailed steps بس من خلالها أنا بشرح شو اللي
+
+294
+00:26:12,090 --> 00:26:19,590
+صار عندى هي أنا عندنا عدة أمثلة لإضافة لبرومين في
+
+295
+00:26:19,590 --> 00:26:25,810
+كل الأحوال هنلاحظ أنه لازم نضيف لبرومين من جهتين
+
+296
+00:26:25,810 --> 00:26:30,630
+مختلفتين يعني لو بدنا نلاحظ الحلول اللى بنعملها هى
+
+297
+00:26:30,630 --> 00:26:35,230
+لبرومين كيف عاملAnti-addition هي هنا .. Anti
+
+298
+00:26:35,230 --> 00:26:39,850
+-addition هي هنا .. Anti-addition واضح؟ فلما بنعمل
+
+299
+00:26:39,850 --> 00:26:43,390
+.. هي هنا مثال إضافي Anti-addition لما بنعمل إضافة
+
+300
+00:26:43,390 --> 00:26:48,290
+برومين على double bond ال addition بتصير من جهتين
+
+301
+00:26:48,290 --> 00:26:54,850
+مختلفتين إضافة الهيدروجين وإضافة الكلورين وإضافة
+
+302
+00:26:54,850 --> 00:27:00,130
+البرومين كلها كان كام ناتج متوقع فيها؟ واحدليش؟
+
+303
+00:27:00,130 --> 00:27:04,610
+لأن هادي symmetrical reagents خلصنا منها، الآن لو
+
+304
+00:27:04,610 --> 00:27:10,690
+إجينا بدنا نضيف الميه، الميه، هاي الميه، هاي H،
+
+305
+00:27:10,690 --> 00:27:16,210
+OH، بدأ أضيفه على ال Kبصير عندى احتمالية و الله
+
+306
+00:27:16,210 --> 00:27:19,690
+اذا بدى اضيفها انا على symmetrical ال key نحط هنا
+
+307
+00:27:19,690 --> 00:27:24,490
+H و هنا OH العملية سهلة كام ناتج متوقع ناتج واحد
+
+308
+00:27:24,490 --> 00:27:28,690
+زي هذا المثال يعني لو اتخيلت ان هذا عندى اثنين بدي
+
+309
+00:27:28,690 --> 00:27:33,370
+احط H و OH و نفس الناتج لو حطيت H و H مافيش فيها
+
+310
+00:27:33,370 --> 00:27:40,260
+مشكلة واضح؟ وين بتبدأ تصير المشكلة؟لو اجيت انا
+
+311
+00:27:40,260 --> 00:27:45,120
+اضيف الميه اللى هى unsymmetrical reagent على
+
+312
+00:27:45,120 --> 00:27:48,780
+unsymmetrical alkene يعني لو اخدت هذا المركب اللى
+
+313
+00:27:48,780 --> 00:27:55,560
+هو ال isobutyl بتذكرينه؟ isobutyl هى CH2 ضب البوند
+
+314
+00:27:55,560 --> 00:28:02,340
+C وانا CH3 وانا CH3 هنا اش في عندكم؟ H وH هل هذا
+
+315
+00:28:02,340 --> 00:28:08,270
+الجزء متماثل؟خيّلوا هي عندكم اتش و اتش هل هذا النص
+
+316
+00:28:08,270 --> 00:28:13,610
+من الجزيء زي هذا اه اذا الميه لو ضافت الاتش هنا و
+
+317
+00:28:13,610 --> 00:28:17,450
+ال او اتش هنا بيطلع ناتج و لو ضافت الاتش هنا و ال
+
+318
+00:28:17,450 --> 00:28:23,910
+او اتش هنا بيطلع ناتج تاني واضح بيطلع ناتج تاني
+
+319
+00:28:23,910 --> 00:28:31,150
+مختلف اللي لوحظ في هذه الحالة ان الميه يمكن ان تتم
+
+320
+00:28:31,150 --> 00:28:37,480
+اضافتها بعدة طرق واضحبحيث انه مرة بتضيف بهذا
+
+321
+00:28:37,480 --> 00:28:41,240
+الاتجاه بحيث ان الهيدروجين تيجي على الكربون اللي
+
+322
+00:28:41,240 --> 00:28:44,640
+حامله هيدروجين كتير و مرة بتضيف باتجاه معاكس
+
+323
+00:28:44,640 --> 00:28:48,000
+اعتمادا على الطريقة اللي انا بجري فيها التفاعل
+
+324
+00:28:48,000 --> 00:28:53,860
+واضح؟ اول طريقة بنسميها acid-catalyzed hydration
+
+325
+00:28:53,860 --> 00:29:01,000
+of alkenes معنى hydration اضافة ماء اضافة ماء
+
+326
+00:29:01,000 --> 00:29:08,250
+اضافة الماء في وجود الحامضبالتم بطريقة معينة
+
+327
+00:29:08,250 --> 00:29:15,350
+الحامض هذا catalyst الحامض عبارة عن ايش H plus اول
+
+328
+00:29:15,350 --> 00:29:19,750
+ما بيبدأ التفاعل بتيجي ال H plus بيضيف على احدى
+
+329
+00:29:19,750 --> 00:29:26,810
+دول الجانب اي H plus مش تحت الميه تحت الحامض يعني
+
+330
+00:29:26,810 --> 00:29:33,110
+انا ضايف H2O و جايب من فره كمان H plus بلاحظينهذه
+
+331
+00:29:33,110 --> 00:29:38,990
+الـ H2O وهذه الـ H Plus شايفين هذه الـ H Plus؟ بدي
+
+332
+00:29:38,990 --> 00:29:41,910
+أعلمها شوية الـ H Plus بدي أعلمها شوية الـ H Plus
+
+333
+00:29:41,910 --> 00:29:41,930
+بدي أعلمها شوية الـ H Plus بدي أعلمها شوية الـ H
+
+334
+00:29:41,930 --> 00:29:41,970
+Plus بدي أعلمها شوية الـ H Plus بدي أعلمها شوية
+
+335
+00:29:41,970 --> 00:29:42,210
+الـ H Plus بدي أعلمها شوية الـ H Plus بدي أعلمها
+
+336
+00:29:42,210 --> 00:29:43,310
+شوية الـ H Plus بدي أعلمها شوية الـ H Plus بدي
+
+337
+00:29:43,310 --> 00:29:45,170
+أعلمها شوية الـ H Plus بدي أعلمها شوية الـ H Plus
+
+338
+00:29:45,170 --> 00:29:50,650
+بدي أعلمها شوية الـ H Plus بدي أعلمها شوية الـ H
+
+339
+00:29:50,650 --> 00:29:57,090
+Plus بدي أعلمها شوية الـ H Plus بدي أعلمها شوية
+
+340
+00:29:57,090 --> 00:30:04,750
+الـ H Plus بدي أعلمهابعيدة وهي الكين نفترض زي هذا
+
+341
+00:30:04,750 --> 00:30:09,530
+الالكين بتيجي ال H بلس بده اضيف ال H بلس لما بده
+
+342
+00:30:09,530 --> 00:30:12,650
+اضيف بتضيف على الكربون اللي حامله هيدروجينز اكتر
+
+343
+00:30:12,650 --> 00:30:19,050
+بتفلت هذه الرابطة هذه الإلكترونات الرابطة و بتتصل
+
+344
+00:30:19,050 --> 00:30:28,280
+بال إيش؟ بتتصل بال H هاي صارت هذه CH3واضح؟ إذن
+
+345
+00:30:28,280 --> 00:30:35,560
+اللي صار أنه اتحركت الرابطة وضافت على الـ H plus
+
+346
+00:30:35,560 --> 00:30:41,100
+الرابطة إلكترونات وهذه موجبة الكلام منطقي فهذه
+
+347
+00:30:41,100 --> 00:30:45,860
+صارت عبارة عن إيش؟ CH3 طب تطلعولي على الكاربون
+
+348
+00:30:45,860 --> 00:30:51,800
+الوسطانية كام رابطة ضال عليها بعد ما هذه راحت؟ اه
+
+349
+00:30:51,800 --> 00:30:56,560
+ضال تلت روابط فالكاربون الوسطانية صارت موجبةصارت
+
+350
+00:30:56,560 --> 00:31:03,460
+ايون كربون موجب ايون الكربون الموجب بنسمي احنا ايش
+
+351
+00:31:03,460 --> 00:31:11,560
+كاربو كتاين اذا بهذه الحالة اتكون عندى كاربو كتاين
+
+352
+00:31:11,560 --> 00:31:17,440
+ايش يعني كاربو كتاين ايون كربون موجب هنا انا ضفت
+
+353
+00:31:17,440 --> 00:31:21,660
+الهيدروجين تبعت الحامض وصارت هذه عندى CH3 وصارت
+
+354
+00:31:21,660 --> 00:31:28,120
+هذه الكربون موجبةالان هذه الكربون الموجبة بتيجي
+
+355
+00:31:28,120 --> 00:31:31,160
+عليها ال oxygen مش ال oxygen عليها كثافة إلكترونية
+
+356
+00:31:31,160 --> 00:31:35,200
+بتضيف .. بتبدأ تضيف الميه .. لو بدأت تضيف الميه كم
+
+357
+00:31:35,200 --> 00:31:41,760
+رابط .. هيصير على ال .. على هذه ال oxygenة .. طلع
+
+358
+00:31:41,760 --> 00:31:46,260
+عليه .. على ال oxygenة .. في الأساس عليها تنتن ..
+
+359
+00:31:46,260 --> 00:31:51,130
+لما تبدأ تيجي تضيف هناصار عليها تلاتة ال oxygen
+
+360
+00:31:51,130 --> 00:31:55,350
+إذا عليها تلت روابط بتكون موجبة مباشرة مجرد ما
+
+361
+00:31:55,350 --> 00:32:02,470
+تصير ضايفة زيك شو بتروح بتعمل بتفقد هيدروجينة عشان
+
+362
+00:32:02,470 --> 00:32:08,490
+تصفه OH واضح؟ إذا هنا الإضافة مرة تانية حاول
+
+363
+00:32:08,490 --> 00:32:13,480
+اللخصها بتتم علىمرحلتين المرحلة الأولى إضافة H
+
+364
+00:32:13,480 --> 00:32:18,660
+plus من الحامض بيعمل رابطة مع ال double bond وصارت
+
+365
+00:32:18,660 --> 00:32:22,640
+هذه ال CH3 واتكون ايون كربون موجب بعد ذلك مجرد ما
+
+366
+00:32:22,640 --> 00:32:26,020
+الميه تيجي بدت تتفاعل زي هيك هل معقول يصير على
+
+367
+00:32:26,020 --> 00:32:31,300
+الميه تلت روابط إذا الميه من حد ما بتيجي هيك طلعت
+
+368
+00:32:31,300 --> 00:32:39,260
+هيدروجينة إيش طلع عندك H plus انتبهوا معي الآن لو
+
+369
+00:32:39,260 --> 00:32:44,520
+إجيت سألتفي المحصلة .. في المحصلة إيش تم عندك؟
+
+370
+00:32:44,520 --> 00:32:50,900
+تضافة H هنا و OH هنا اللي هي ضافة الميّه لكن هل يا
+
+371
+00:32:50,900 --> 00:32:54,420
+تورا ال H و ال OH اللي هنا إيجوا من جزء الميّه؟
+
+372
+00:32:54,420 --> 00:33:00,660
+هذا ال H إجت من الحامض و هذا ال OH إجت من الميّه و
+
+373
+00:33:00,660 --> 00:33:04,100
+في الآخر بيطلع H plus عشان هذا catalyst بيدخل و
+
+374
+00:33:04,100 --> 00:33:07,160
+بيطلع لكن هل نفس ال H plus تعطي ال catalyst ولا
+
+375
+00:33:07,160 --> 00:33:11,340
+بتطلع واحدة تانية من الميّه؟واحدة تانية من الميّه
+
+376
+00:33:11,340 --> 00:33:15,700
+تلاحظين انتوا النقطة ان الـ H plus تبع الحامض
+
+377
+00:33:15,700 --> 00:33:20,880
+انضافت واتفعلت هنا بعد هي طلعت H plus من وين الـ H
+
+378
+00:33:20,880 --> 00:33:25,980
+plus اللي طلعت؟ من الميّه واضح؟ إذا إضافة جزء
+
+379
+00:33:25,980 --> 00:33:33,620
+الميّه بتتم على خطوتين الخطوة الأولى منهم إضافة H
+
+380
+00:33:33,620 --> 00:33:40,120
+plusمن الحامض وتكوين ايون كربون موجب والخطوة
+
+381
+00:33:40,120 --> 00:33:45,380
+الثانية منهم إضافة الـ H2O بالتالي على طول بتفقد H
+
+382
+00:33:45,380 --> 00:33:49,800
+بلس عشان يظلوا روابط زي ما احنا عارفين الأكسجين
+
+383
+00:33:49,800 --> 00:33:55,380
+برابطتين وبطلع عندك H بلس الآن إذا هذا الكلام صار
+
+384
+00:33:55,380 --> 00:34:01,160
+الـ H بلس اللي طلعت إيش بتعمل؟بتعيد التفاعل مرة
+
+385
+00:34:01,160 --> 00:34:04,480
+تانية عشانك احنا بنقول ان ال acid عبارة عن
+
+386
+00:34:04,480 --> 00:34:08,700
+catalyst ايش معنى catalyst موجود بكمية صغيرة بمعنى
+
+387
+00:34:08,700 --> 00:34:15,520
+لو انا بدأت بس ب H plus واحدة واتفاعلت هيها راحت
+
+388
+00:34:15,520 --> 00:34:21,420
+بعد شوية لما اكتمل التفاعل طلعت H plus جديدة بتبدأ
+
+389
+00:34:21,420 --> 00:34:25,990
+تفاعل مرة تانيةبتعاود تطلع H plus جديدة و بتطلع H
+
+390
+00:34:25,990 --> 00:34:29,590
+plus جديدة إذا أنا قاعد بكرر التفاعل بكرر التفاعل
+
+391
+00:34:29,590 --> 00:34:34,150
+بكرر التفاعل بس على أكم H plus على واحدة ولذلك ال
+
+392
+00:34:34,150 --> 00:34:38,990
+catalyst means to أنه بيكون موجود بكمية قليلة
+
+393
+00:34:38,990 --> 00:34:44,030
+واضح؟ زي تماما إذا بتكون تتخيلوها القصة زي مثلا
+
+394
+00:34:44,030 --> 00:34:48,690
+ولاد مدارس مروحين بدهم يقطعوا الشارع في شرطي واحد
+
+395
+00:34:49,900 --> 00:34:55,780
+الشرط الواحد بيجيه بمسيك الولد بيوديه و بيرجع هل
+
+396
+00:34:55,780 --> 00:35:02,120
+بالذمن لو بده .. خمسين طالب يقطعوا ال .. لو خمسين
+
+397
+00:35:02,120 --> 00:35:05,280
+طالب بدهم يقطعوا الشارع بدهوا يلزمني خمسين شرطة؟
+
+398
+00:35:05,280 --> 00:35:10,620
+لأ هو شرطة واحد بيروحوا بيجيه هنا H plus واحدة
+
+399
+00:35:10,620 --> 00:35:15,320
+بدأت فيها عوقلي عند H plus برود بكمل .. برود بكمل
+
+400
+00:35:15,320 --> 00:35:23,690
+.. واضح؟طبعا هنا هيجينا سؤال اكيد الطالبات اللي
+
+401
+00:35:23,690 --> 00:35:29,250
+منتبهات منكم ممكن انهم يسألوا وحقهم انهم يسألوا
+
+402
+00:35:29,250 --> 00:35:34,970
+هذا السؤال لو ارجعنا اتخيلنا الالكين ال un
+
+403
+00:35:34,970 --> 00:35:41,810
+-symmetrical هذا بهذا الشكل مظبوط احنا قلنا بدا
+
+404
+00:35:41,810 --> 00:35:46,230
+تيجي من الخارج ايشالـ H Plus و الـ Double Bond ده
+
+405
+00:35:46,230 --> 00:35:52,930
+بتتحرك زي هيك و تضيف الـ H هنا هي صارت CH3 واحدة
+
+406
+00:35:52,930 --> 00:35:58,070
+شاطرة منكم بتقول طب ليش ماتنكسر الرابط من هنا و
+
+407
+00:35:58,070 --> 00:36:04,970
+تضيف الـ H Plus هنا على الوسطبمعنى كأنه أنا هنا في
+
+408
+00:36:04,970 --> 00:36:10,290
+عندى رابطة بدها تتحرك يا بدها تتحرك هيك و تعمل هنا
+
+409
+00:36:10,290 --> 00:36:14,190
+لارتباط بإمكانها برضه تتحرك بالشكل القاتل و تضيف
+
+410
+00:36:14,190 --> 00:36:19,630
+الهيدروجين وين عن نص لو هذا الكلام صار وين هيصير
+
+411
+00:36:19,630 --> 00:36:24,130
+ال positive carbocation على ال carbon اللي على
+
+412
+00:36:24,130 --> 00:36:31,190
+الطرف ودتها لو بدها تيجي ال OH تكمل التفاعل هتيجي
+
+413
+00:36:31,190 --> 00:36:37,960
+على الطرففيش مشكلة السؤال عاد ليش التفاعل لما هذه
+
+414
+00:36:37,960 --> 00:36:42,260
+بدها تنكسر هي عندها احتمالين يا تنكسر من هنا زي
+
+415
+00:36:42,260 --> 00:36:48,740
+هيك يا تنكسر من هنا زي هيك وبالتالي لو انكسرت من
+
+416
+00:36:48,740 --> 00:36:51,940
+هنا الايون الموجة بوين بده يكون؟ على الكاربون
+
+417
+00:36:51,940 --> 00:36:56,100
+الوصطانية لو انكسرت من هنا الايون الموجة بحيكون
+
+418
+00:36:56,100 --> 00:36:59,920
+على الكاربون الطرفاني اش معنى انه تنكسر بشكل معين
+
+419
+00:36:59,920 --> 00:37:05,740
+مش بالشكل التاني؟هذا الكسر هو اللي بيخلّي في هذه
+
+420
+00:37:05,740 --> 00:37:08,960
+الحالة يطلع عنده ناتج حقيقة احنا اللي كنا نقولكوا
+
+421
+00:37:08,960 --> 00:37:13,820
+انه متوقع كام ناتج ناتجين في هذه الحالة ناتجين لو
+
+422
+00:37:13,820 --> 00:37:18,680
+تمت انه الكسر من هنا هي H وهنا إجت ال OH أو بالعكس
+
+423
+00:37:18,680 --> 00:37:23,340
+هي H وهنا إجت ال OH إذا التفاعل من ناحية النظرية
+
+424
+00:37:23,340 --> 00:37:27,360
+البحتة طالما هذه رابطة بكان يكسر من هنا أو من هنا
+
+425
+00:37:27,360 --> 00:37:32,670
+وبالتالي ممكن يكوّن ناتجين على أرض الواقعاختار
+
+426
+00:37:32,670 --> 00:37:37,410
+واحد من الطريقين .. واضح؟ زي البني آدم بالظبط ..
+
+427
+00:37:37,410 --> 00:37:42,390
+ربنا إيش بيقول .. وهديناه .. إنا إشديه .. لكن في
+
+428
+00:37:42,390 --> 00:37:48,750
+ناس زي العقيدبيختار طريق الله بيعلم وفي ناس بيختار
+
+429
+00:37:48,750 --> 00:37:51,350
+طريق .. فيه بيختاروا طريق الصح وفيه بيختاروا طريق
+
+430
+00:37:51,350 --> 00:37:56,510
+الغلط لكن البني آدم نفسه في عنده إيش مصارين و هنا
+
+431
+00:37:56,510 --> 00:38:00,330
+نفس الفكرة تماما انا في اندي احتمالين صيروا هذا
+
+432
+00:38:00,330 --> 00:38:03,990
+أحدهم وفي الاحتمال التاني الآن التفاعل اختار
+
+433
+00:38:03,990 --> 00:38:11,810
+احتمال من التانين بيصير السؤال ليش التفاعل بيختار
+
+434
+00:38:11,810 --> 00:38:17,250
+الاحتمال اللي كتبناه هناوإن الكاربو كتاين يكون على
+
+435
+00:38:17,250 --> 00:38:21,910
+الوسط مش الاحتمال التاني و الكاربو كتاين يكون على
+
+436
+00:38:21,910 --> 00:38:27,370
+الطرف واضح الفكرة؟
+
+437
+00:38:27,370 --> 00:38:31,430
+خلصته؟
+
+438
+00:38:31,430 --> 00:38:36,050
+خلوا هذا السؤال .. خلوا هذا السؤال للمرة الجاية ..
+
+439
+00:38:36,050 --> 00:38:38,950
+خلوا هذا السؤال للمرة الجاية .. بس هنبدأ من عنده
+
+440
+00:38:38,950 --> 00:38:45,450
+لأنه بحاجة إلى تفصيلفكروا فيه كويس انه في احتمالين
+
+441
+00:38:45,450 --> 00:38:49,830
+اختار واحد و المرة الجاية ان شاء الله بنبدأ الشغل
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/sCPLeVK9zQ0_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/sCPLeVK9zQ0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..254223e8adc3fb1f89d9031feeb429d7ff9d4991
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/sCPLeVK9zQ0_raw.srt
@@ -0,0 +1,1764 @@
+1
+00:00:16,660 --> 00:00:23,000
+خلّيكم معنا إذا بتسمحوا .. لو سمحت .. لو سمحت ..
+
+2
+00:00:23,000 --> 00:00:29,020
+اليوم
+
+3
+00:00:29,020 --> 00:00:37,120
+إن شاء الله هنبدأ في درس تفاعلات ال alkanes واضح؟
+
+4
+00:00:37,120 --> 00:00:39,920
+طبعا إنتوا متذكرين من الحصة الماضية ال alkanes
+
+5
+00:00:39,920 --> 00:00:46,370
+المركبات اللي فيهمdouble bonds روابط زوجية طالما
+
+6
+00:00:46,370 --> 00:00:53,850
+المركب في double bond فتفاعله الأساسي هيكون تفاعل
+
+7
+00:00:53,850 --> 00:00:58,730
+إضافة معنى تفاعل إضافة أنه أنا ألغي ال double bond
+
+8
+00:00:58,730 --> 00:01:04,750
+هذه و أضيف مكانها دارتين واضح فدائما بنيجي بنقول
+
+9
+00:01:04,750 --> 00:01:11,040
+إحنا أنه لو كان في عندنا ال cans و ال cans مشبعةلو
+
+10
+00:01:11,040 --> 00:01:14,480
+كان فينا Alkenes والـ Alkenes مشبعة تفاعلها
+
+11
+00:01:14,480 --> 00:01:19,120
+الأساسي إبدال لأن أنا عندي أربع ذرات على الـ
+
+12
+00:01:19,120 --> 00:01:23,600
+Carbon مش ممكن أن أعمل أي إضافة لكن في حالة الـ
+
+13
+00:01:23,600 --> 00:01:27,100
+Alkenes اللي فيهم Double Bonds وفي حالة الـ
+
+14
+00:01:27,100 --> 00:01:30,340
+Alkynes اللي فيهم Triple Bond هتلاحظوا أن التفاعل
+
+15
+00:01:30,340 --> 00:01:35,220
+الأساسي هو تفاعل إضافة معنى تفاعل الإضافة معنى
+
+16
+00:01:35,220 --> 00:01:39,080
+تفاعل الإضافة أنه أنا بألغي Double Bond و بحط
+
+17
+00:01:39,080 --> 00:01:39,820
+مكانها
+
+18
+00:01:49,000 --> 00:01:55,470
+الان في موضوع التفاعلاتهتلاحظوا القاتل ان احنا
+
+19
+00:01:55,470 --> 00:01:58,850
+بنتعامل مع الكين ال الكين هو اللي بيتم عليه
+
+20
+00:01:58,850 --> 00:02:05,170
+التفاعل و بنتعامل بنفس الوقت مع reagent ال reagent
+
+21
+00:02:05,170 --> 00:02:09,970
+هو المادة اللي فيها ذرتين هدول الذرتين بنضيفه على
+
+22
+00:02:09,970 --> 00:02:14,650
+ال الكين يعني احنا لما بنعمل عملية الإضافة الإضافة
+
+23
+00:02:14,650 --> 00:02:22,080
+مكونة من شغلتين الكين و reagentالـ Reagent لازم
+
+24
+00:02:22,080 --> 00:02:27,440
+يكون فيه ذرتين مثلا ممكن يكون هيدروجين برومين مية
+
+25
+00:02:27,440 --> 00:02:31,880
+HCL على أساس أن ذرة منهم بتضيف هان لما بلغت double
+
+26
+00:02:31,880 --> 00:02:36,500
+bond وذرة منهم بتضيف هان هذه عملية ال addition
+
+27
+00:02:36,500 --> 00:02:41,580
+واضح؟ إذا ال addition المكونات تبعت عبارة عن إيش؟
+
+28
+00:02:43,950 --> 00:02:50,250
+الان المفروض تتطلعوا انتوا شوية على مواصفات
+
+29
+00:02:50,250 --> 00:02:56,710
+الالكين ومواصفات ال الرياجين اللى بتطلع بانتباه هى
+
+30
+00:02:56,710 --> 00:03:02,750
+في عندى الكين معين اللى هو الاثين او الاثلين وهى
+
+31
+00:03:02,750 --> 00:03:08,550
+في عندى الكين تانى الكين تانى اللى هو البروبيل
+
+32
+00:03:09,440 --> 00:03:15,800
+بتذكرين ال probine CH2 CH3
+
+33
+00:03:15,800 --> 00:03:22,580
+هذا الكين وهذا الكين هذا إيثين وهذا ال probine
+
+34
+00:03:22,580 --> 00:03:27,140
+الآن إذا بتطلعوا بنظرة فاحصة على هدول ال two
+
+35
+00:03:27,140 --> 00:03:32,640
+alkenes هتلاحظوا شغلة أن ال الكين يمكن أن يكون
+
+36
+00:03:32,640 --> 00:03:37,800
+متماثلمن الجهتين يعني إذا بتطلع على ال aethene هذا
+
+37
+00:03:37,800 --> 00:03:41,020
+او ال aethylene و اتخيلتوا انتوا ان عندكم مراية
+
+38
+00:03:41,020 --> 00:03:48,500
+هيك من النص هذا الجزء زي هذا الجزء واضح؟ اذا ال
+
+39
+00:03:48,500 --> 00:03:54,340
+aethylene عبارة عن symmetrical ال keen هو ال keen
+
+40
+00:03:54,340 --> 00:03:58,960
+متماثل هاي لو حطيت مراية هدول نفسهم هيبينوا اين؟
+
+41
+00:03:58,960 --> 00:04:05,350
+على الجهة التانيةواضح؟ الان لو اجينا اتطلعنا .. لو
+
+42
+00:04:05,350 --> 00:04:10,170
+اجينا اتطلعنا على لبروبيين و اتخيلوا انه بتكون ..
+
+43
+00:04:10,170 --> 00:04:13,370
+هي ال double bond و حطه مرايا زي هيك .. هل
+
+44
+00:04:13,370 --> 00:04:18,950
+لبروبيين جزء متماثل ولا غير متماثل؟ لأ .. اه ..
+
+45
+00:04:18,950 --> 00:04:24,140
+اذا الالكين يقسم الى ..نوعين يمكن أن يكون الالكين
+
+46
+00:04:24,140 --> 00:04:28,520
+متماثل جزءه اليمين صورة الجزء الثاني في المرأة
+
+47
+00:04:28,520 --> 00:04:34,340
+ويمكن أن يكون الالكين غير متماثل الاثين is
+
+48
+00:04:34,340 --> 00:04:41,360
+asymmetrical الكين البروبين is unsymmetrical الكين
+
+49
+00:04:41,360 --> 00:04:47,040
+واضح هذه النقطة؟ الآن لو اجينا تطلعنا على المكون
+
+50
+00:04:47,040 --> 00:04:51,840
+التاني لمكونات الإضافة اللي هو ال reagentممكن انا
+
+51
+00:04:51,840 --> 00:04:57,640
+اضيف مثلا الهيدروجين الهيدروجين جزء H single bond
+
+52
+00:04:57,640 --> 00:05:03,380
+H اتطلع عليه بنفس المنطق هل يا ترى هذا الهيدروجين
+
+53
+00:05:03,380 --> 00:05:10,240
+متماثل ولا غير متماثل اذا الهيدروجين متماثل ممكن
+
+54
+00:05:10,240 --> 00:05:23,210
+اضيف انا جزء كلورين Cl2 Cl single bondالـ HCL ممكن
+
+55
+00:05:23,210 --> 00:05:29,750
+اضيف الـ HCL
+
+56
+00:05:29,750 --> 00:05:35,190
+ممكن
+
+57
+00:05:35,190 --> 00:05:38,990
+اضيف الـ HCL ممكن اضيف الـ HCL
+
+58
+00:05:45,800 --> 00:05:51,700
+ممكن اضيف الميه الميه لما بتضيف بتضيف كجزء اين H
+
+59
+00:05:51,700 --> 00:06:01,720
+جزء و OH هذا الصغير هذا جزء OHالميّه بنعملها كإنها
+
+60
+00:06:01,720 --> 00:06:06,720
+H or OH الان هل الميّه بهذا الشكل symmetrical ولا
+
+61
+00:06:06,720 --> 00:06:12,400
+unsymmetrical الميّه unsymmetrical اذا بنا ننتبه
+
+62
+00:06:12,400 --> 00:06:15,920
+لشغله انه احنا لما بنعمل تفاعل ال الكين مع
+
+63
+00:06:15,920 --> 00:06:20,540
+reagents معينة في عندنا احتمالين في ال الكين وفي
+
+64
+00:06:20,540 --> 00:06:23,340
+عندنا احتمالين في ال reagent ال الكين can be
+
+65
+00:06:23,340 --> 00:06:27,740
+symmetrical or unsymmetrical و ال reagent can be
+
+66
+00:06:30,170 --> 00:06:37,350
+الان ممكن اضيف simetrical reagent على simetrical
+
+67
+00:06:37,350 --> 00:06:44,040
+alkene زي هيكواطلعوا انتوا معاه بشكل هادئ لو ضفته
+
+68
+00:06:44,040 --> 00:06:47,980
+وحطيتها نقاتش وها نقاتش بيفرق هذا ال reagent لو
+
+69
+00:06:47,980 --> 00:06:52,780
+مسكته زي هيك ولا مسكته زي هيك هل متوقع يطلع اكتر
+
+70
+00:06:52,780 --> 00:06:58,600
+من جزيء اذا اضافة ال symmetrical reagent ع ال
+
+71
+00:06:58,600 --> 00:07:06,070
+symmetrical ال keen بطلع لكم product كم جزيءواحد
+
+72
+00:07:06,070 --> 00:07:13,990
+واضح اذا لو احنا بدنا نحاول يعني نعمل ملخص صغير
+
+73
+00:07:13,990 --> 00:07:20,690
+نضيع هذا شوية نعمل ملخص صغير يعني بدنا نتخيل ان
+
+74
+00:07:20,690 --> 00:07:28,330
+احنا عندنا ال keen و في عندنا reagent لما ال keen
+
+75
+00:07:28,330 --> 00:07:32,690
+يكون symmetric و ال reagent يكون symmetric هكا
+
+76
+00:07:32,690 --> 00:07:34,330
+product فيطلع عندنا
+
+77
+00:07:38,540 --> 00:07:43,240
+لما يكون ال الكين سيمتريك و ال reactant سيمتريك
+
+78
+00:07:43,240 --> 00:07:47,860
+عنده product او احتمال واحد طيب لو اخدت هذا ال
+
+79
+00:07:47,860 --> 00:07:54,390
+reactant السيمتريك و قلت بدي افعله على البروبينو
+
+80
+00:07:54,390 --> 00:07:59,090
+احنا اتفقنا ان البروبين is unsymmetric هل يا تورا
+
+81
+00:07:59,090 --> 00:08:02,510
+لما بدي اضيف الهيدروجين بهذا الشكل تيجي اتشان و
+
+82
+00:08:02,510 --> 00:08:07,530
+اتشان، هيفرق انه هيك اضيفه ولا هيك ولا حد؟ اذا
+
+83
+00:08:07,530 --> 00:08:16,490
+برضه هيطلع ناتج واحد فإضافة ال symmetrical reagent
+
+84
+00:08:16,490 --> 00:08:20,630
+على ال unsymmetrical alkene برضه بيطلعلي إيش؟ one
+
+85
+00:08:20,630 --> 00:08:29,050
+productطب ممكن نفكر نضيف unsymmetrical reagent زي
+
+86
+00:08:29,050 --> 00:08:35,790
+ال HCl على symmetrical alkene بده احط HCl احط هنا
+
+87
+00:08:35,790 --> 00:08:41,510
+H وهنا Cl ولا هنا H وهنا Cl؟لأ و الله ناتج واحد
+
+88
+00:08:41,510 --> 00:08:47,670
+حيطلع عندكوا ع الجهة CH3 وعالتانية CH2CL لو عملنا
+
+89
+00:08:47,670 --> 00:08:54,650
+هيك CH3 وCH2CL و لو عملنا هيك CH3 وCH2CL ناتج واحد
+
+90
+00:08:54,650 --> 00:09:01,730
+اذا لما انا باجي باضيف symmetrical ال key
+
+91
+00:09:07,150 --> 00:09:11,150
+ناتج واحد برضه المتوقع اندي ناتج واحد ضال شغلة
+
+92
+00:09:11,150 --> 00:09:16,910
+اخيرة ان انا اجي اضيف unsymmetrical reagent على
+
+93
+00:09:16,910 --> 00:09:21,110
+unsymmetrical alkene ال reagent غير متماثل
+
+94
+00:09:21,110 --> 00:09:25,770
+والalkene غير متماثل الان اتطلع لو بدى اضيف بهذا
+
+95
+00:09:25,770 --> 00:09:30,870
+الشكل اذا مسكت reagent زي هيك هذه هتصير الطرف CH3
+
+96
+00:09:33,780 --> 00:09:37,980
+الـCl يعني الـCl وين إجت؟ عن نُص، على الكربون
+
+97
+00:09:37,980 --> 00:09:44,760
+الوسطانية، لو مسكته زي هيك، حيطلع عندي CH2Cl و هنا
+
+98
+00:09:44,760 --> 00:09:49,780
+في الوسط حيصير CH2 واضح تباماً بهذه الحالة أنه
+
+99
+00:09:49,780 --> 00:09:55,280
+بيطلع عندكم إيش؟ كم ناتج؟ ناتجين، من ناحية النظرية
+
+100
+00:09:55,280 --> 00:09:59,060
+البحثة، إذا أنا في الحالة اللي باضيف فيها
+
+101
+00:09:59,060 --> 00:10:01,500
+Unsymmetrical
+
+102
+00:10:04,160 --> 00:10:09,380
+الـ Keen و Unsymmetrical الـ Pre-agent متوقع يطلع
+
+103
+00:10:09,380 --> 00:10:14,700
+عنده نتيجة الان هذا التوقع هو توقع نظري في التجربة
+
+104
+00:10:14,700 --> 00:10:21,470
+يطلع واحد او اتنين مابنعرفشواضح؟ تماما زي إنسان في
+
+105
+00:10:21,470 --> 00:10:25,170
+عنده طريقين متفرعين، هو عنده احتمالين، بعدين يمشي
+
+106
+00:10:25,170 --> 00:10:28,570
+منها و لا يمشي منها، هذا موضوع إيش؟ تاني، لكن من
+
+107
+00:10:28,570 --> 00:10:32,690
+ناحية الاحتمالات، ممكن يطلع هيك و ممكن يطلع هيك،
+
+108
+00:10:32,690 --> 00:10:39,910
+واضح؟ إذا، وكتش بيطلع عنده احتمالين أو ناتجين، لما
+
+109
+00:10:39,910 --> 00:10:44,550
+أنا بفعل unsymmetrical مع unsymmetricalواضح؟ هذه
+
+110
+00:10:44,550 --> 00:10:48,570
+الحالة الوحيدة انه اذا انا فعلت unsymmetrical
+
+111
+00:10:48,570 --> 00:10:53,070
+reagent على unsymmetrical alkene متوقع يطلع عندي
+
+112
+00:10:53,070 --> 00:10:58,610
+نتيجة اذا بدها انتباه اكتر وبدها دراسة اكتر، واضح؟
+
+113
+00:10:58,610 --> 00:11:03,530
+هذه مقدمة، الآن احنا هنبدأ ناخد امثلة، ناخد مثلا
+
+114
+00:11:03,530 --> 00:11:07,790
+إضافة الهيدروجين عكذا، إضافة Cl2، إضافة HCl، إضافة
+
+115
+00:11:07,790 --> 00:11:14,370
+H2O، في كل حالةبدنا نحلل و احنا بنعمل التفاعل هل
+
+116
+00:11:14,370 --> 00:11:18,790
+المتوقع يطلع عندى ناتج او اتنين اذا المتوقع يطلع
+
+117
+00:11:18,790 --> 00:11:22,970
+ناتج الامر بيكون ايش اسهل اذا المتوقع يطلع ناتجين
+
+118
+00:11:22,970 --> 00:11:29,330
+الامر بيكون شوية بده تفصيلات مافيش اشي صعب لكن فيه
+
+119
+00:11:29,330 --> 00:11:34,850
+اشي بيكون بحاجة الى تفصيل يعني مافيش اشي صعب في
+
+120
+00:11:34,850 --> 00:11:35,790
+الدنيا او مستحيل
+
+121
+00:11:41,220 --> 00:12:05,220
+بحاجة إلى تفاصيلات أداء
+
+122
+00:12:05,220 --> 00:12:10,000
+المقدم على تحديث طبيعة الألكين وطبيعة الـ Reagent
+
+123
+00:12:10,420 --> 00:12:16,840
+بصير أسهل علينا أن ناخد أمثلة متنوعة النوع الأول
+
+124
+00:12:16,840 --> 00:12:21,900
+اللي بدنا ناخده اللي هو إضافة جزء هيدروجين على
+
+125
+00:12:21,900 --> 00:12:25,700
+الألكين واضح؟ هذه العملية بنسميها احنا reduction
+
+126
+00:12:25,700 --> 00:12:31,380
+بمعنى تحويل الألكين إلى ألكين هي عملية reduction
+
+127
+00:12:31,380 --> 00:12:36,680
+واضح؟ تحويل الألكين إلى الألكين هي عملية reduction
+
+128
+00:12:36,680 --> 00:12:41,970
+إضافة الهيدروجين بشكل عامما بتتمش لحاله، يعني لو
+
+129
+00:12:41,970 --> 00:12:46,010
+أنا جبت الكيل وخلطت معه هيدروجين وبدأ أستنهم
+
+130
+00:12:46,010 --> 00:12:50,450
+يتفاعلوا، مابتفاعلوش بسهولة، لأ، بده من وجود
+
+131
+00:12:50,450 --> 00:12:56,750
+catalyst، ال catalyst غالبا هو معدن، metalواضح؟
+
+132
+00:12:56,750 --> 00:13:00,210
+مثل البلاتين مثل ال .. مثل ال nickel مثل ال
+
+133
+00:13:00,210 --> 00:13:04,070
+palladium في عدة catalyst البلاتين وال nickel من
+
+134
+00:13:04,070 --> 00:13:08,810
+ال catalyst أو العوامل المساعدة المشهورة بهذه
+
+135
+00:13:08,810 --> 00:13:12,070
+الحالة ال hydrogen في وجود ال metal بنضيف على
+
+136
+00:13:12,070 --> 00:13:16,930
+الجهتين واحنا قلنا في النهاية المتوقع كام ناتج
+
+137
+00:13:16,930 --> 00:13:22,310
+عندنا إضافة ال hydrogen على ال alkene متوقع منه
+
+138
+00:13:22,310 --> 00:13:28,600
+ناتج واحدالان اللي لاحظوه انه ذرتين الهيدروجين
+
+139
+00:13:28,600 --> 00:13:32,280
+ذرتين الهيدروجين لما بيضيفوا على القلقين بيعملوا
+
+140
+00:13:32,280 --> 00:13:35,800
+شغلة بيسميها sin addition ايش يعني sin addition؟
+
+141
+00:13:35,800 --> 00:13:39,940
+يعني الذرتين بييجوا من جهة واحدة بيضيفوا يعني
+
+142
+00:13:39,940 --> 00:13:43,860
+مابيجوش لو بدي اتخيل ان عندي ذرتين هيدروجين هيك
+
+143
+00:13:43,860 --> 00:13:50,260
+واحدة من اليمين واحدة من الشمال هذا الإضافة بهذا
+
+144
+00:13:50,260 --> 00:13:55,760
+الشكل ذرة وبهذا الشكل ذرةكأنهم ذرتين مفصلات هذا
+
+145
+00:13:55,760 --> 00:14:01,560
+بنسميها Anti-addition إضافة متعاكسة الآن إضافة
+
+146
+00:14:01,560 --> 00:14:07,200
+الذرتين من جهة واحدة بنسميها Sin addition فللاحظوا
+
+147
+00:14:07,200 --> 00:14:15,230
+إن إضافة الهيدروجين على السن اديشن و بتنفي وجود
+
+148
+00:14:15,230 --> 00:14:21,330
+متل surface على سطح معدن الان ليش بتصير اضافة
+
+149
+00:14:21,330 --> 00:14:26,410
+الهيدروجين سن اديشن مش انت اديشن اللي بيصير ان
+
+150
+00:14:26,410 --> 00:14:32,430
+الهيدروجين كجزاء عشان الضيف بده ينكسروا الرابط
+
+151
+00:14:32,430 --> 00:14:36,080
+اللي بين الذرتينمش هم ذرتين الهيدروجين هيوم ممسكين
+
+152
+00:14:36,080 --> 00:14:40,220
+برابطة بدا تنكسر هذه الرابطة اللى بين ذرتين
+
+153
+00:14:40,220 --> 00:14:42,900
+الهيدروجين عشان هذه بتضيف على جهة و هذه بتضيف على
+
+154
+00:14:42,900 --> 00:14:51,650
+جهة تانية فالهيدروجين بيلتصق بسطح المعدنملاحظين
+
+155
+00:14:51,650 --> 00:14:56,410
+بهذا الشكل الهيدروجين يلتصق في سطح المعدن لما بتتم
+
+156
+00:14:56,410 --> 00:15:00,350
+الإضافة بتقدر تقول ان هذه الرابطة انكسرت هذه
+
+157
+00:15:00,350 --> 00:15:04,270
+الهيدروجين مع ال bond بتلف بهذا الشكل و هذا ال
+
+158
+00:15:04,270 --> 00:15:07,990
+bond بتلف بهذا الشكل بيصير عندي رابطتين اجدادا
+
+159
+00:15:07,990 --> 00:15:13,390
+لاحظوا كيف هى عندى ال double bond بتبقى single
+
+160
+00:15:13,390 --> 00:15:17,330
+bond الان هذه الرابطة و الهيدروجين نفسه ملتصق في
+
+161
+00:15:17,330 --> 00:15:23,460
+المعدن بتلف بهذا الشكلهذه الرابطة دلت مع
+
+162
+00:15:23,460 --> 00:15:27,160
+الهيدروجين عملت handle طبعا أنا مستحيل أصيره خمسة،
+
+163
+00:15:27,160 --> 00:15:31,520
+إيش بيصير على طول؟ هذي بتنزل، الحركتين بتتموا بنفس
+
+164
+00:15:31,520 --> 00:15:34,760
+الوقت عشان يظل عندي كام رابطة في النهاية؟ أربع
+
+165
+00:15:34,760 --> 00:15:38,420
+رابط، شوفتوا كيف بتتم ال addition؟ فالهيدروجين هنا
+
+166
+00:15:38,420 --> 00:15:43,660
+طالما أنه ممسوك على سطح المعدن، التنتين، إذا لازم
+
+167
+00:15:43,660 --> 00:15:49,460
+التنتين يضيفوا؟ من جهة واحدةمش ممكن يكونوا ممسكين
+
+168
+00:15:49,460 --> 00:15:53,480
+الهيدروجينتين على سطح المعدن و ييجوا يضيفوا واحدة
+
+169
+00:15:53,480 --> 00:15:55,820
+من جهة و اتانية من جهة تانية هين انا امسكهم لو
+
+170
+00:15:55,820 --> 00:15:58,580
+اتخيلت انا ال double bond هل ممكن اضيف واحدة من
+
+171
+00:15:58,580 --> 00:16:01,280
+هنا و واحدة من هنا و انا امسكهم زي هيك و بتعمل
+
+172
+00:16:01,280 --> 00:16:06,480
+الإضافة مستحيل واضح فطالما ان الهيدروجين بيقول
+
+173
+00:16:06,480 --> 00:16:10,100
+عنهم they are absorbed at the metal surface ايش
+
+174
+00:16:10,100 --> 00:16:11,280
+يعني absorbed؟
+
+175
+00:16:13,700 --> 00:16:17,300
+ملتصقة .. ملتصقة التصاق .. بتكون .. اتفرجوا بين
+
+176
+00:16:17,300 --> 00:16:21,500
+كلمتين في الكيميا .. بين كلمة absorption وكلمة
+
+177
+00:16:21,500 --> 00:16:26,400
+adsorption .. adsorption بال D .. absorption بال B
+
+178
+00:16:26,400 --> 00:16:30,300
+.. absorption هو التصاقش على السطح .. زي هيك
+
+179
+00:16:30,920 --> 00:16:35,640
+الملاحظين هذه العملية التصاق على السطح ايش بنسميها
+
+180
+00:16:35,640 --> 00:16:39,900
+احنا absorption فالهيدروجين بيكون على سطح المعدن
+
+181
+00:16:39,900 --> 00:16:42,960
+زي هيك لو تخيلنا هذا معدن الهيدروجين بيكون
+
+182
+00:16:42,960 --> 00:16:49,360
+absorbed على ال surface لكن absorption هي عملية
+
+183
+00:16:49,360 --> 00:16:53,660
+بيدخل فيها الهيدروجين جوا المعدن واضح؟ يعني لو
+
+184
+00:16:53,660 --> 00:16:57,840
+تخيلنا زي هيك هذه الآن ذرة الهيدروجين شو صير لها؟
+
+185
+00:16:59,170 --> 00:17:04,710
+absorption جوا المعدن هل يا تورا المعدن سهل ان
+
+186
+00:17:04,710 --> 00:17:09,490
+الهيدروجين يدخل في جلبه مستحيل دائما اي شي على
+
+187
+00:17:09,490 --> 00:17:14,230
+المعدن بالتصق من الخارج مش ممكن يصير absorption
+
+188
+00:17:14,230 --> 00:17:18,550
+جوا المعدن واضح فالهيدروجين لانه بيكون absorbed at
+
+189
+00:17:18,550 --> 00:17:23,670
+the metal surface بيعمل sin addition الهيدروجين
+
+190
+00:17:23,670 --> 00:17:27,210
+بيعمل sin addition فلو تخيلتوا مثلا انه كان عندكم
+
+191
+00:17:29,970 --> 00:17:39,330
+التو هيدروجينز بيضيفه من جهة واحدة
+
+192
+00:17:39,330 --> 00:17:46,310
+عندنا هنا كتير امثلة احنا حاطينها طبعا مركبات
+
+193
+00:17:46,310 --> 00:17:50,330
+كبيرة صغيرة مش مشكلة المهم انه في عندى double bond
+
+194
+00:17:51,220 --> 00:17:56,320
+و في عندى hydrogen و بدأتم عملية الاضافة فبالمثال
+
+195
+00:17:56,320 --> 00:18:02,140
+الاول مثلا هنا بتضاف دين hydrogen لاحظوا ان ال
+
+196
+00:18:02,140 --> 00:18:06,880
+alkene ال double bond ايش صارت؟ اركان هو اختصر ال
+
+197
+00:18:06,880 --> 00:18:12,100
+hydrogen برسم همش بس واضح انه صارت تفاعل ليش؟ لان
+
+198
+00:18:12,100 --> 00:18:13,020
+ال double bond
+
+199
+00:18:29,410 --> 00:18:33,710
+بتلاحظوا لما بورسم ال hydrogen عملوا قاعد بيعطيكم
+
+200
+00:18:34,420 --> 00:18:38,440
+هل هم ضيفين من جهة واحدة ولا لا .. واضح .. sin
+
+201
+00:18:38,440 --> 00:18:42,480
+addition .. وكذلك الحال في هذا المثال .. هذا
+
+202
+00:18:42,480 --> 00:18:46,600
+Cyclopentane وعليه مجموعتين مثل .. لما بده يضيف
+
+203
+00:18:46,600 --> 00:18:50,320
+الهيدروجيل .. بيضيف من جهة واحدة .. فلو افترض انه
+
+204
+00:18:50,320 --> 00:18:53,700
+مثلا اتي الهيدروجيل buff من تحت .. فعلى الحلقة
+
+205
+00:18:56,860 --> 00:19:01,780
+بيصيروا لفوق للأعلى ومجمعتين الهيدروجين لتحت في
+
+206
+00:19:01,780 --> 00:19:06,040
+هذه الحالة بينتج عند ال cis ولا ال trans ايزو مار
+
+207
+00:19:06,040 --> 00:19:11,140
+ال cis ايزو مار واضح ال cis ايزو مار في الجزيء
+
+208
+00:19:11,140 --> 00:19:15,860
+الأصلي كانوا مجموعات ال مثل هنا في نفس مستوى
+
+209
+00:19:15,860 --> 00:19:20,630
+الجزيءهدولة في نفس مستوى الرابطة اللى هنا يعنى ..
+
+210
+00:19:20,630 --> 00:19:24,810
+هدى المنطقة .. هدى المنطقة مش كل الجزء بلانر احنا
+
+211
+00:19:24,810 --> 00:19:28,110
+نقول هدى المنطقة في الـ cyclopentane عاملة زى إيش؟
+
+212
+00:19:28,110 --> 00:19:31,310
+زى ال envelope .. هدى الجزء إذا ما تذكرينه لكن
+
+213
+00:19:31,310 --> 00:19:37,610
+حوالين هدى الرابطة .. هدى بلانر فالمثل والمثل و
+
+214
+00:19:37,610 --> 00:19:40,770
+هدى الرابطة و هدى الرابطة في نفس المستوى لما يجى
+
+215
+00:19:40,770 --> 00:19:44,860
+هيدروجين يضيف من جهة واحدة تنتينشو بيصير في
+
+216
+00:19:44,860 --> 00:19:48,220
+المجموعتين التانيين؟ هيروح على الجهة التانية
+
+217
+00:19:48,220 --> 00:19:54,140
+فالاضافة على ال one two dimethylcyclobentane
+
+218
+00:19:54,140 --> 00:19:57,680
+بتعطينا ال sis ولا ال trans؟ one two
+
+219
+00:19:57,680 --> 00:20:01,560
+dimethylcyclobentane ال sis because the addition
+
+220
+00:20:01,560 --> 00:20:06,980
+of hydrogen is sin addition كم ناتج متوقع في كل
+
+221
+00:20:06,980 --> 00:20:12,790
+الحلات؟ واحد، ليش؟لأنه بيكفين أنه الهيدروجين
+
+222
+00:20:12,790 --> 00:20:18,130
+symmetrical بغض النظر عن التاني الآن الكلام نفسه
+
+223
+00:20:18,130 --> 00:20:22,850
+بتكرر ومافيش داعي نكتر كلام فيه لو كنا بنضيف جزء
+
+224
+00:20:22,850 --> 00:20:31,000
+زي الchlor Cl2 أو زي ال brom Br2 واضح؟فاذا ضيفت
+
+225
+00:20:31,000 --> 00:20:36,700
+انا لبرومين او لكلورين كام ناتج متوقع ناتج واحد
+
+226
+00:20:36,700 --> 00:20:42,820
+لكن اللي لاحظوه في حالة اضافة لبرومين انه ذرتين
+
+227
+00:20:42,820 --> 00:20:47,340
+لبروم بيضيفوا anti addition مش sin addition
+
+228
+00:20:47,340 --> 00:20:52,360
+بيضيفوا جهتين مختلفتين طيب تعالوا فاكروا فيها كيف
+
+229
+00:20:52,360 --> 00:20:56,320
+ممكن تصير ان هاي بروم و بروم هدول افترضوهم كيف
+
+230
+00:20:56,320 --> 00:21:01,190
+بدهم يضيفوا anti additionلابد إلا في الأول يصير
+
+231
+00:21:01,190 --> 00:21:07,250
+انكسار بينهم عشان هذه .. لو انهم يضيفوا و يضيفوا و
+
+232
+00:21:07,250 --> 00:21:10,070
+يضيفوا زي هيك و لآخر لحظة يتم الكسر .. لازم يضيفوا
+
+233
+00:21:10,070 --> 00:21:14,870
+إيش؟ تضيفوا sin addition .. لكن لما يصير كسر زي
+
+234
+00:21:14,870 --> 00:21:20,390
+هيك .. لما يصير عندك نمط ما من الكسر .. بتقدر هذا
+
+235
+00:21:20,390 --> 00:21:23,230
+يضيف من هنا و هذا يضيف من هنا .. بيقدر يصير عندك
+
+236
+00:21:23,230 --> 00:21:28,080
+ال anti addition .. واضح؟فاللي لوحظ بالتجربة ان
+
+237
+00:21:28,080 --> 00:21:34,160
+إضافة لبروم is trans or anti-additional يعني بتضيف
+
+238
+00:21:34,160 --> 00:21:40,580
+من جهتين متعاكستين الآن كيف القالية .. كيف القالية
+
+239
+00:21:40,580 --> 00:21:46,060
+اللي بتتم فيها عملية الإضافة جزء لبرومين هذا جزء
+
+240
+00:21:46,060 --> 00:21:50,560
+لبرومين زي ما انتوا عارفينه non-polar واضح؟ لكن
+
+241
+00:21:50,560 --> 00:21:56,290
+ممكنفي لحظة من اللحظات يصير polarized يعني يصير
+
+242
+00:21:56,290 --> 00:22:00,490
+فيه نوع من الخطبية الأصل أنه الإلكترونات في
+
+243
+00:22:00,490 --> 00:22:06,010
+البرومين موجودة بالتساوي ما بين ذرتين البروم
+
+244
+00:22:06,010 --> 00:22:10,440
+إلكترونات الرابطةموجودة بالتساوم بين ذرتين البروم
+
+245
+00:22:10,440 --> 00:22:16,760
+لكن لما جزء البروم هذا لما جزء البروم بيجي بيقترب
+
+246
+00:22:16,760 --> 00:22:20,860
+بيجي بيقترب من double bond هذا double bond كثافة
+
+247
+00:22:20,860 --> 00:22:25,540
+إلكترونية الإلكترونات اللي هنا بدهم يبعدوا ولا
+
+248
+00:22:25,540 --> 00:22:30,920
+بدهم يقربوا دايما الإلكترونات ع بعض بتتنافع فبناء
+
+249
+00:22:30,920 --> 00:22:34,180
+على ذلك لما هذا الجزء بيجي يتفعل بهذا الشكل
+
+250
+00:22:34,180 --> 00:22:37,080
+إلكترونات الرابطة كانوا بدهم يروحوا على جهة إيش
+
+251
+00:22:37,860 --> 00:22:43,080
+البروم فبصير كأنه صار عند بروم سالب كله بيشهد من
+
+252
+00:22:43,080 --> 00:22:48,420
+الإلكترونات و بروم موجب واضح هذا البروم الموجب هو
+
+253
+00:22:48,420 --> 00:22:54,320
+اللي بيضيف هنا بيعمل على شكل حلقة رابطتين وبالتالي
+
+254
+00:22:54,320 --> 00:22:58,380
+بيصير البرومين positive لأن البروم عادة في الوضع
+
+255
+00:22:58,380 --> 00:23:02,910
+الطبيعي بيعمل كام رابطةرابطة واحدة إذا عمل رابطتين
+
+256
+00:23:02,910 --> 00:23:06,630
+و بدنا نحسب ال formal charge تبعته هلاحظ ان هو
+
+257
+00:23:06,630 --> 00:23:11,290
+برومين positive الان هذا البرومين positive مش ثابت
+
+258
+00:23:11,290 --> 00:23:17,070
+يعني يتكون لجزء من الثانية طالما هذا البرومين
+
+259
+00:23:17,070 --> 00:23:23,290
+positive انوجد زي هيكو مش ثابت ضال عنده البرومين
+
+260
+00:23:23,290 --> 00:23:28,090
+negative البرومين negative طالما هذه مسكرة بروابط
+
+261
+00:23:28,090 --> 00:23:33,980
+من وين مضطر ييجي يضيفمن الجهة المعاكسة إذا عملية
+
+262
+00:23:33,980 --> 00:23:38,140
+إضافة البروم هنا تتم على مرحلة ولا على مرحلتين؟
+
+263
+00:23:38,140 --> 00:23:41,720
+على مرحلتين المرحلة الأولى بيصير فيها نوع من
+
+264
+00:23:41,720 --> 00:23:47,100
+الاستقطاب يعني كأنه أنا جسمت الجزئة موجب و سالب
+
+265
+00:23:47,100 --> 00:23:51,920
+بضيف الموجب بيعمل ايون بروم موجب و دايما الايونات
+
+266
+00:23:51,920 --> 00:23:59,200
+الموجبة بنسميها onion ions ايش يعني onion؟Ion موجب
+
+267
+00:23:59,200 --> 00:24:02,900
+بتذكروا مثلا كانوا يمروا عليكم كلمة ammonium
+
+268
+00:24:02,900 --> 00:24:07,900
+امونيوم
+
+269
+00:24:07,900 --> 00:24:11,960
+ايون موجب لو مع ال oxygen ايون موجب شو بتسميه
+
+270
+00:24:11,960 --> 00:24:18,060
+اكزونيوم لو مع ال chlorine اكلورونيوم لو مع البروم
+
+271
+00:24:18,060 --> 00:24:24,400
+ابرومونيوم واضح؟فدائما النهاية onium بتعني ايون
+
+272
+00:24:24,400 --> 00:24:33,340
+موجب فعشان يتحول إلى جزء
+
+273
+00:24:33,340 --> 00:24:37,160
+موجب يضيف في البداية بيعمل البرومونيوم ايون بهذا
+
+274
+00:24:37,160 --> 00:24:42,770
+الشكل ثم يكتمل التفاعل من الجهة المعاكسةبإضافة
+
+275
+00:24:42,770 --> 00:24:46,790
+الجزء السالب طبعا مستحيل إنه يبقى جهة تريف من هنا
+
+276
+00:24:46,790 --> 00:24:50,830
+و جهة أشمالها مبلوغ مجرد ما يجي السالب هذا هنا
+
+277
+00:24:50,830 --> 00:24:54,970
+بترجع الرابط على البروم و بيكون لي رابط احدية بحصل
+
+278
+00:24:54,970 --> 00:25:02,850
+على جزء متعدل بهيك إيش بتلاحظه ان البروم أو
+
+279
+00:25:02,850 --> 00:25:08,870
+البرومين addition is Anti addition Anti يعني يتم
+
+280
+00:25:08,870 --> 00:25:14,470
+من جهتينيتم من جهتين مختلفتين واضح إيش الفرق بين
+
+281
+00:25:14,470 --> 00:25:19,030
+إضافة الهيدروجين وإضافة البرومين الهيدروجين is a
+
+282
+00:25:19,030 --> 00:25:22,370
+one step addition يعني التنتير بيضيفه من جهة واحدة
+
+283
+00:25:22,370 --> 00:25:27,190
+البرومين is a two step يعني طالما صارت الإضافة من
+
+284
+00:25:27,190 --> 00:25:31,010
+جهتين إذا لازم واحد اضاف من الأول والتان إجا بعدين
+
+285
+00:25:31,010 --> 00:25:35,850
+فهنا بتلاحظ اي step واي ناتج النهائيطبعا هل هذا
+
+286
+00:25:35,850 --> 00:25:39,710
+ابن ميسكو احنا و لا هدى شغل اثناء التفاعل بتصير
+
+287
+00:25:39,710 --> 00:25:45,230
+بسرعة احنا ايش ناتج الابن ميسكو؟ هذا عشان سبق ان
+
+288
+00:25:45,230 --> 00:25:47,970
+حكينا قولنالكوا انكوا تميزوا بين شغلتين بين
+
+289
+00:25:47,970 --> 00:25:53,010
+reaction اللى هو reactants و product و بين ميكانزم
+
+290
+00:25:53,010 --> 00:25:57,250
+اللى هي خطوات تفصيلية بتتم لكن احنا مش شايفينها
+
+291
+00:25:57,250 --> 00:26:03,470
+واضح؟ اذا فى عندنا reaction اللى هوreactants بتصير
+
+292
+00:26:03,470 --> 00:26:07,830
+product وفي عندى detailed steps لكن هل بفصل نواتيش
+
+293
+00:26:07,830 --> 00:26:12,090
+هال detailed steps بس من خلالها أنا بشرح شو اللي
+
+294
+00:26:12,090 --> 00:26:19,590
+صار عندى هي أنا عندنا عدة أمثلة لإضافة لبرومين في
+
+295
+00:26:19,590 --> 00:26:25,810
+كل الأحوال هنلاحظ أنه لازم نضيف لبرومين من جهتين
+
+296
+00:26:25,810 --> 00:26:30,630
+مختلفتين يعني لو بدنا نلاحظ الحلول اللى بنعملها هى
+
+297
+00:26:30,630 --> 00:26:35,230
+لبرومين كيف عاملAnti-addition هي هنا .. Anti
+
+298
+00:26:35,230 --> 00:26:39,850
+-addition هي هنا .. Anti-addition واضح؟ فلما بنعمل
+
+299
+00:26:39,850 --> 00:26:43,390
+.. هي هنا مثال إضافي Anti-addition لما بنعمل إضافة
+
+300
+00:26:43,390 --> 00:26:48,290
+برومين على double bond ال addition بتصير من جهتين
+
+301
+00:26:48,290 --> 00:26:54,850
+مختلفتين إضافة الهيدروجين وإضافة الكلورين وإضافة
+
+302
+00:26:54,850 --> 00:27:00,130
+البرومين كلها كان كام ناتج متوقع فيها؟ واحدليش؟
+
+303
+00:27:00,130 --> 00:27:04,610
+لأن هادي symmetrical reagents خلصنا منها، الآن لو
+
+304
+00:27:04,610 --> 00:27:10,690
+إجينا بدنا نضيف الميه، الميه، هاي الميه، هاي H،
+
+305
+00:27:10,690 --> 00:27:16,210
+OH، بدأ أضيفه على ال Kبصير عندى احتمالية و الله
+
+306
+00:27:16,210 --> 00:27:19,690
+اذا بدى اضيفها انا على symmetrical ال key نحط هنا
+
+307
+00:27:19,690 --> 00:27:24,490
+H و هنا OH العملية سهلة كام ناتج متوقع ناتج واحد
+
+308
+00:27:24,490 --> 00:27:28,690
+زي هذا المثال يعني لو اتخيلت ان هذا عندى اثنين بدي
+
+309
+00:27:28,690 --> 00:27:33,370
+احط H و OH و نفس الناتج لو حطيت H و H مافيش فيها
+
+310
+00:27:33,370 --> 00:27:40,260
+مشكلة واضح؟ وين بتبدأ تصير المشكلة؟لو اجيت انا
+
+311
+00:27:40,260 --> 00:27:45,120
+اضيف الميه اللى هى unsymmetrical reagent على
+
+312
+00:27:45,120 --> 00:27:48,780
+unsymmetrical alkene يعني لو اخدت هذا المركب اللى
+
+313
+00:27:48,780 --> 00:27:55,560
+هو ال isobutyl بتذكرينه؟ isobutyl هى CH2 ضب البوند
+
+314
+00:27:55,560 --> 00:28:02,340
+C وانا CH3 وانا CH3 هنا اش في عندكم؟ H وH هل هذا
+
+315
+00:28:02,340 --> 00:28:08,270
+الجزء متماثل؟خيّلوا هي عندكم اتش و اتش هل هذا النص
+
+316
+00:28:08,270 --> 00:28:13,610
+من الجزيء زي هذا اه اذا الميه لو ضافت الاتش هنا و
+
+317
+00:28:13,610 --> 00:28:17,450
+ال او اتش هنا بيطلع ناتج و لو ضافت الاتش هنا و ال
+
+318
+00:28:17,450 --> 00:28:23,910
+او اتش هنا بيطلع ناتج تاني واضح بيطلع ناتج تاني
+
+319
+00:28:23,910 --> 00:28:31,150
+مختلف اللي لوحظ في هذه الحالة ان الميه يمكن ان تتم
+
+320
+00:28:31,150 --> 00:28:37,480
+اضافتها بعدة طرق واضحبحيث انه مرة بتضيف بهذا
+
+321
+00:28:37,480 --> 00:28:41,240
+الاتجاه بحيث ان الهيدروجين تيجي على الكربون اللي
+
+322
+00:28:41,240 --> 00:28:44,640
+حامله هيدروجين كتير و مرة بتضيف باتجاه معاكس
+
+323
+00:28:44,640 --> 00:28:48,000
+اعتمادا على الطريقة اللي انا بجري فيها التفاعل
+
+324
+00:28:48,000 --> 00:28:53,860
+واضح؟ اول طريقة بنسميها acid-catalyzed hydration
+
+325
+00:28:53,860 --> 00:29:01,000
+of alkenes معنى hydration اضافة ماء اضافة ماء
+
+326
+00:29:01,000 --> 00:29:08,250
+اضافة الماء في وجود الحامضبالتم بطريقة معينة
+
+327
+00:29:08,250 --> 00:29:15,350
+الحامض هذا catalyst الحامض عبارة عن ايش H plus اول
+
+328
+00:29:15,350 --> 00:29:19,750
+ما بيبدأ التفاعل بتيجي ال H plus بيضيف على احدى
+
+329
+00:29:19,750 --> 00:29:26,810
+دول الجانب اي H plus مش تحت الميه تحت الحامض يعني
+
+330
+00:29:26,810 --> 00:29:33,110
+انا ضايف H2O و جايب من فره كمان H plus بلاحظينهذه
+
+331
+00:29:33,110 --> 00:29:38,990
+الـ H2O وهذه الـ H Plus شايفين هذه الـ H Plus؟ بدي
+
+332
+00:29:38,990 --> 00:29:41,910
+أعلمها شوية الـ H Plus بدي أعلمها شوية الـ H Plus
+
+333
+00:29:41,910 --> 00:29:41,930
+بدي أعلمها شوية الـ H Plus بدي أعلمها شوية الـ H
+
+334
+00:29:41,930 --> 00:29:41,970
+Plus بدي أعلمها شوية الـ H Plus بدي أعلمها شوية
+
+335
+00:29:41,970 --> 00:29:42,210
+الـ H Plus بدي أعلمها شوية الـ H Plus بدي أعلمها
+
+336
+00:29:42,210 --> 00:29:43,310
+شوية الـ H Plus بدي أعلمها شوية الـ H Plus بدي
+
+337
+00:29:43,310 --> 00:29:45,170
+أعلمها شوية الـ H Plus بدي أعلمها شوية الـ H Plus
+
+338
+00:29:45,170 --> 00:29:50,650
+بدي أعلمها شوية الـ H Plus بدي أعلمها شوية الـ H
+
+339
+00:29:50,650 --> 00:29:57,090
+Plus بدي أعلمها شوية الـ H Plus بدي أعلمها شوية
+
+340
+00:29:57,090 --> 00:30:04,750
+الـ H Plus بدي أعلمهابعيدة وهي الكين نفترض زي هذا
+
+341
+00:30:04,750 --> 00:30:09,530
+الالكين بتيجي ال H بلس بده اضيف ال H بلس لما بده
+
+342
+00:30:09,530 --> 00:30:12,650
+اضيف بتضيف على الكربون اللي حامله هيدروجينز اكتر
+
+343
+00:30:12,650 --> 00:30:19,050
+بتفلت هذه الرابطة هذه الإلكترونات الرابطة و بتتصل
+
+344
+00:30:19,050 --> 00:30:28,280
+بال إيش؟ بتتصل بال H هاي صارت هذه CH3واضح؟ إذن
+
+345
+00:30:28,280 --> 00:30:35,560
+اللي صار أنه اتحركت الرابطة وضافت على الـ H plus
+
+346
+00:30:35,560 --> 00:30:41,100
+الرابطة إلكترونات وهذه موجبة الكلام منطقي فهذه
+
+347
+00:30:41,100 --> 00:30:45,860
+صارت عبارة عن إيش؟ CH3 طب تطلعولي على الكاربون
+
+348
+00:30:45,860 --> 00:30:51,800
+الوسطانية كام رابطة ضال عليها بعد ما هذه راحت؟ اه
+
+349
+00:30:51,800 --> 00:30:56,560
+ضال تلت روابط فالكاربون الوسطانية صارت موجبةصارت
+
+350
+00:30:56,560 --> 00:31:03,460
+ايون كربون موجب ايون الكربون الموجب بنسمي احنا ايش
+
+351
+00:31:03,460 --> 00:31:11,560
+كاربو كتاين اذا بهذه الحالة اتكون عندى كاربو كتاين
+
+352
+00:31:11,560 --> 00:31:17,440
+ايش يعني كاربو كتاين ايون كربون موجب هنا انا ضفت
+
+353
+00:31:17,440 --> 00:31:21,660
+الهيدروجين تبعت الحامض وصارت هذه عندى CH3 وصارت
+
+354
+00:31:21,660 --> 00:31:28,120
+هذه الكربون موجبةالان هذه الكربون الموجبة بتيجي
+
+355
+00:31:28,120 --> 00:31:31,160
+عليها ال oxygen مش ال oxygen عليها كثافة إلكترونية
+
+356
+00:31:31,160 --> 00:31:35,200
+بتضيف .. بتبدأ تضيف الميه .. لو بدأت تضيف الميه كم
+
+357
+00:31:35,200 --> 00:31:41,760
+رابط .. هيصير على ال .. على هذه ال oxygenة .. طلع
+
+358
+00:31:41,760 --> 00:31:46,260
+عليه .. على ال oxygenة .. في الأساس عليها تنتن ..
+
+359
+00:31:46,260 --> 00:31:51,130
+لما تبدأ تيجي تضيف هناصار عليها تلاتة ال oxygen
+
+360
+00:31:51,130 --> 00:31:55,350
+إذا عليها تلت روابط بتكون موجبة مباشرة مجرد ما
+
+361
+00:31:55,350 --> 00:32:02,470
+تصير ضايفة زيك شو بتروح بتعمل بتفقد هيدروجينة عشان
+
+362
+00:32:02,470 --> 00:32:08,490
+تصفه OH واضح؟ إذا هنا الإضافة مرة تانية حاول
+
+363
+00:32:08,490 --> 00:32:13,480
+اللخصها بتتم علىمرحلتين المرحلة الأولى إضافة H
+
+364
+00:32:13,480 --> 00:32:18,660
+plus من الحامض بيعمل رابطة مع ال double bond وصارت
+
+365
+00:32:18,660 --> 00:32:22,640
+هذه ال CH3 واتكون ايون كربون موجب بعد ذلك مجرد ما
+
+366
+00:32:22,640 --> 00:32:26,020
+الميه تيجي بدت تتفاعل زي هيك هل معقول يصير على
+
+367
+00:32:26,020 --> 00:32:31,300
+الميه تلت روابط إذا الميه من حد ما بتيجي هيك طلعت
+
+368
+00:32:31,300 --> 00:32:39,260
+هيدروجينة إيش طلع عندك H plus انتبهوا معي الآن لو
+
+369
+00:32:39,260 --> 00:32:44,520
+إجيت سألتفي المحصلة .. في المحصلة إيش تم عندك؟
+
+370
+00:32:44,520 --> 00:32:50,900
+تضافة H هنا و OH هنا اللي هي ضافة الميّه لكن هل يا
+
+371
+00:32:50,900 --> 00:32:54,420
+تورا ال H و ال OH اللي هنا إيجوا من جزء الميّه؟
+
+372
+00:32:54,420 --> 00:33:00,660
+هذا ال H إجت من الحامض و هذا ال OH إجت من الميّه و
+
+373
+00:33:00,660 --> 00:33:04,100
+في الآخر بيطلع H plus عشان هذا catalyst بيدخل و
+
+374
+00:33:04,100 --> 00:33:07,160
+بيطلع لكن هل نفس ال H plus تعطي ال catalyst ولا
+
+375
+00:33:07,160 --> 00:33:11,340
+بتطلع واحدة تانية من الميّه؟واحدة تانية من الميّه
+
+376
+00:33:11,340 --> 00:33:15,700
+تلاحظين انتوا النقطة ان الـ H plus تبع الحامض
+
+377
+00:33:15,700 --> 00:33:20,880
+انضافت واتفعلت هنا بعد هي طلعت H plus من وين الـ H
+
+378
+00:33:20,880 --> 00:33:25,980
+plus اللي طلعت؟ من الميّه واضح؟ إذا إضافة جزء
+
+379
+00:33:25,980 --> 00:33:33,620
+الميّه بتتم على خطوتين الخطوة الأولى منهم إضافة H
+
+380
+00:33:33,620 --> 00:33:40,120
+plusمن الحامض وتكوين ايون كربون موجب والخطوة
+
+381
+00:33:40,120 --> 00:33:45,380
+الثانية منهم إضافة الـ H2O بالتالي على طول بتفقد H
+
+382
+00:33:45,380 --> 00:33:49,800
+بلس عشان يظلوا روابط زي ما احنا عارفين الأكسجين
+
+383
+00:33:49,800 --> 00:33:55,380
+برابطتين وبطلع عندك H بلس الآن إذا هذا الكلام صار
+
+384
+00:33:55,380 --> 00:34:01,160
+الـ H بلس اللي طلعت إيش بتعمل؟بتعيد التفاعل مرة
+
+385
+00:34:01,160 --> 00:34:04,480
+تانية عشانك احنا بنقول ان ال acid عبارة عن
+
+386
+00:34:04,480 --> 00:34:08,700
+catalyst ايش معنى catalyst موجود بكمية صغيرة بمعنى
+
+387
+00:34:08,700 --> 00:34:15,520
+لو انا بدأت بس ب H plus واحدة واتفاعلت هيها راحت
+
+388
+00:34:15,520 --> 00:34:21,420
+بعد شوية لما اكتمل التفاعل طلعت H plus جديدة بتبدأ
+
+389
+00:34:21,420 --> 00:34:25,990
+تفاعل مرة تانيةبتعاود تطلع H plus جديدة و بتطلع H
+
+390
+00:34:25,990 --> 00:34:29,590
+plus جديدة إذا أنا قاعد بكرر التفاعل بكرر التفاعل
+
+391
+00:34:29,590 --> 00:34:34,150
+بكرر التفاعل بس على أكم H plus على واحدة ولذلك ال
+
+392
+00:34:34,150 --> 00:34:38,990
+catalyst means to أنه بيكون موجود بكمية قليلة
+
+393
+00:34:38,990 --> 00:34:44,030
+واضح؟ زي تماما إذا بتكون تتخيلوها القصة زي مثلا
+
+394
+00:34:44,030 --> 00:34:48,690
+ولاد مدارس مروحين بدهم يقطعوا الشارع في شرطي واحد
+
+395
+00:34:49,900 --> 00:34:55,780
+الشرط الواحد بيجيه بمسيك الولد بيوديه و بيرجع هل
+
+396
+00:34:55,780 --> 00:35:02,120
+بالذمن لو بده .. خمسين طالب يقطعوا ال .. لو خمسين
+
+397
+00:35:02,120 --> 00:35:05,280
+طالب بدهم يقطعوا الشارع بدهوا يلزمني خمسين شرطة؟
+
+398
+00:35:05,280 --> 00:35:10,620
+لأ هو شرطة واحد بيروحوا بيجيه هنا H plus واحدة
+
+399
+00:35:10,620 --> 00:35:15,320
+بدأت فيها عوقلي عند H plus برود بكمل .. برود بكمل
+
+400
+00:35:15,320 --> 00:35:23,690
+.. واضح؟طبعا هنا هيجينا سؤال اكيد الطالبات اللي
+
+401
+00:35:23,690 --> 00:35:29,250
+منتبهات منكم ممكن انهم يسألوا وحقهم انهم يسألوا
+
+402
+00:35:29,250 --> 00:35:34,970
+هذا السؤال لو ارجعنا اتخيلنا الالكين ال un
+
+403
+00:35:34,970 --> 00:35:41,810
+-symmetrical هذا بهذا الشكل مظبوط احنا قلنا بدا
+
+404
+00:35:41,810 --> 00:35:46,230
+تيجي من الخارج ايشالـ H Plus و الـ Double Bond ده
+
+405
+00:35:46,230 --> 00:35:52,930
+بتتحرك زي هيك و تضيف الـ H هنا هي صارت CH3 واحدة
+
+406
+00:35:52,930 --> 00:35:58,070
+شاطرة منكم بتقول طب ليش ماتنكسر الرابط من هنا و
+
+407
+00:35:58,070 --> 00:36:04,970
+تضيف الـ H Plus هنا على الوسطبمعنى كأنه أنا هنا في
+
+408
+00:36:04,970 --> 00:36:10,290
+عندى رابطة بدها تتحرك يا بدها تتحرك هيك و تعمل هنا
+
+409
+00:36:10,290 --> 00:36:14,190
+لارتباط بإمكانها برضه تتحرك بالشكل القاتل و تضيف
+
+410
+00:36:14,190 --> 00:36:19,630
+الهيدروجين وين عن نص لو هذا الكلام صار وين هيصير
+
+411
+00:36:19,630 --> 00:36:24,130
+ال positive carbocation على ال carbon اللي على
+
+412
+00:36:24,130 --> 00:36:31,190
+الطرف ودتها لو بدها تيجي ال OH تكمل التفاعل هتيجي
+
+413
+00:36:31,190 --> 00:36:37,960
+على الطرففيش مشكلة السؤال عاد ليش التفاعل لما هذه
+
+414
+00:36:37,960 --> 00:36:42,260
+بدها تنكسر هي عندها احتمالين يا تنكسر من هنا زي
+
+415
+00:36:42,260 --> 00:36:48,740
+هيك يا تنكسر من هنا زي هيك وبالتالي لو انكسرت من
+
+416
+00:36:48,740 --> 00:36:51,940
+هنا الايون الموجة بوين بده يكون؟ على الكاربون
+
+417
+00:36:51,940 --> 00:36:56,100
+الوصطانية لو انكسرت من هنا الايون الموجة بحيكون
+
+418
+00:36:56,100 --> 00:36:59,920
+على الكاربون الطرفاني اش معنى انه تنكسر بشكل معين
+
+419
+00:36:59,920 --> 00:37:05,740
+مش بالشكل التاني؟هذا الكسر هو اللي بيخلّي في هذه
+
+420
+00:37:05,740 --> 00:37:08,960
+الحالة يطلع عنده ناتج حقيقة احنا اللي كنا نقولكوا
+
+421
+00:37:08,960 --> 00:37:13,820
+انه متوقع كام ناتج ناتجين في هذه الحالة ناتجين لو
+
+422
+00:37:13,820 --> 00:37:18,680
+تمت انه الكسر من هنا هي H وهنا إجت ال OH أو بالعكس
+
+423
+00:37:18,680 --> 00:37:23,340
+هي H وهنا إجت ال OH إذا التفاعل من ناحية النظرية
+
+424
+00:37:23,340 --> 00:37:27,360
+البحتة طالما هذه رابطة بكان يكسر من هنا أو من هنا
+
+425
+00:37:27,360 --> 00:37:32,670
+وبالتالي ممكن يكوّن ناتجين على أرض الواقعاختار
+
+426
+00:37:32,670 --> 00:37:37,410
+واحد من الطريقين .. واضح؟ زي البني آدم بالظبط ..
+
+427
+00:37:37,410 --> 00:37:42,390
+ربنا إيش بيقول .. وهديناه .. إنا إشديه .. لكن في
+
+428
+00:37:42,390 --> 00:37:48,750
+ناس زي العقيدبيختار طريق الله بيعلم وفي ناس بيختار
+
+429
+00:37:48,750 --> 00:37:51,350
+طريق .. فيه بيختاروا طريق الصح وفيه بيختاروا طريق
+
+430
+00:37:51,350 --> 00:37:56,510
+الغلط لكن البني آدم نفسه في عنده إيش مصارين و هنا
+
+431
+00:37:56,510 --> 00:38:00,330
+نفس الفكرة تماما انا في اندي احتمالين صيروا هذا
+
+432
+00:38:00,330 --> 00:38:03,990
+أحدهم وفي الاحتمال التاني الآن التفاعل اختار
+
+433
+00:38:03,990 --> 00:38:11,810
+احتمال من التانين بيصير السؤال ليش التفاعل بيختار
+
+434
+00:38:11,810 --> 00:38:17,250
+الاحتمال اللي كتبناه هناوإن الكاربو كتاين يكون على
+
+435
+00:38:17,250 --> 00:38:21,910
+الوسط مش الاحتمال التاني و الكاربو كتاين يكون على
+
+436
+00:38:21,910 --> 00:38:27,370
+الطرف واضح الفكرة؟
+
+437
+00:38:27,370 --> 00:38:31,430
+خلصته؟
+
+438
+00:38:31,430 --> 00:38:36,050
+خلوا هذا السؤال .. خلوا هذا السؤال للمرة الجاية ..
+
+439
+00:38:36,050 --> 00:38:38,950
+خلوا هذا السؤال للمرة الجاية .. بس هنبدأ من عنده
+
+440
+00:38:38,950 --> 00:38:45,450
+لأنه بحاجة إلى تفصيلفكروا فيه كويس انه في احتمالين
+
+441
+00:38:45,450 --> 00:38:49,830
+اختار واحد و المرة الجاية ان شاء الله بنبدأ الشغل
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f0578cc9fe08321a2c3fbcc4fd492fb7c2b765c9
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_postprocess.srt
@@ -0,0 +1,1992 @@
+1
+00:00:09,630 --> 00:00:17,330
+اليوم موضوعنا فصل جديد و ممتع هو الفصل المعنوان
+
+2
+00:00:17,330 --> 00:00:25,020
+stereochemistry معنى stereochemistryدراسة شكل
+
+3
+00:00:25,020 --> 00:00:31,560
+الجزء في الفراغ في تلت أبعاد واضح؟ يعني دائما كلمة
+
+4
+00:00:31,560 --> 00:00:35,880
+stereo بتعني شيء بيطلع في تلت أبعاد حتى اللي
+
+5
+00:00:35,880 --> 00:00:41,300
+بتسموه ال stereo تبع الصوت بيطلع الصوت في تلت
+
+6
+00:00:41,300 --> 00:00:45,000
+أبعاد أو في كل الاتجاهات واضح؟ three-dimensional
+
+7
+00:00:45,000 --> 00:00:51,460
+هذا الحقيقة chapter ممتع
+
+8
+00:00:51,460 --> 00:00:59,400
+جداكمقدمة له .. كمقدمة له بدنا نذكر اللوحة اللي
+
+9
+00:00:59,400 --> 00:01:03,420
+مرت علينا وقولنا هتظل تتكرر علينا كتير اللي هي
+
+10
+00:01:03,420 --> 00:01:08,860
+فيها تصنيف لل isomers اللي فيها تصنيف لل isomers
+
+11
+00:01:08,860 --> 00:01:15,170
+يمكن أنا شوية صغيرة كبرتها أو قسمتها إلىجزئين
+
+12
+00:01:15,170 --> 00:01:24,630
+الجزء الفوق هذا طبعا معنى isomers هي مركبات تختلف
+
+13
+00:01:24,630 --> 00:01:31,350
+في الشكل البنائي لكن لها نفس ال molecular formula
+
+14
+00:01:31,350 --> 00:01:35,350
+الصيغة الجزائية طبعا طالما لها نفس الصيغة الجزائية
+
+15
+00:01:35,350 --> 00:01:38,510
+من باب او لا لها نفس ال empirical formula طبعا
+
+16
+00:01:38,510 --> 00:01:41,230
+تكونوا متذكرين انتوا انه لما أخدتوا الصيغة
+
+17
+00:01:41,230 --> 00:01:47,010
+الكيميائيةأخدت تلت صياغ empirical formula اللي هي
+
+18
+00:01:47,010 --> 00:01:52,450
+أبسط نسبة ال molecular formula اللي هي الأعداد
+
+19
+00:01:52,450 --> 00:01:57,890
+الحقيقية للجزء و ال structural formula كيف بيشبكوا
+
+20
+00:01:57,890 --> 00:02:04,310
+واضح يعني مثلا انا ممكن اقول ال chemical formula
+
+21
+00:02:04,310 --> 00:02:07,230
+العادية هدولة تلت أقلام لكن لما بدي structural
+
+22
+00:02:07,230 --> 00:02:11,470
+formula و بدي اعمل منهم شكل ممكن اعمله بأكتر من
+
+23
+00:02:11,470 --> 00:02:16,350
+طريقةهنا بصير في عند إيش؟ Structural formula فال
+
+24
+00:02:16,350 --> 00:02:19,730
+isomers they are as you can see different
+
+25
+00:02:19,730 --> 00:02:24,170
+compounds that have the same molecular formula،
+
+26
+00:02:24,170 --> 00:02:27,610
+اللي هو نفس ال molecular formula، but different
+
+27
+00:02:27,610 --> 00:02:32,500
+structuresthey differ in the structural formula
+
+28
+00:02:32,500 --> 00:02:40,520
+الآن بيقسموا ال isomers لنوعين أساسيين النوع الأول
+
+29
+00:02:40,520 --> 00:02:46,880
+بنسميه constitutional isomers يعني isomers مختلفة
+
+30
+00:02:46,880 --> 00:02:51,800
+في البناء أو في التكوين وعشان ايه كمان بتاخد اسم
+
+31
+00:02:51,800 --> 00:02:56,320
+تاني ال constitutional isomers نفسه بيسموها
+
+32
+00:02:56,320 --> 00:03:01,950
+structural isomersواضح فإذا قلنا constitutional
+
+33
+00:03:01,950 --> 00:03:10,150
+isomers أو قلنا structural isomers نفس المعنى they
+
+34
+00:03:10,150 --> 00:03:14,870
+differ in the bonding in the structure الان لو
+
+35
+00:03:14,870 --> 00:03:18,390
+بتكن تلاحظوا هدول ال constitutional isomers أو ال
+
+36
+00:03:18,390 --> 00:03:24,970
+structural isomers إيش تعريفهم بتلاقوا القاتلAtoms
+
+37
+00:03:24,970 --> 00:03:28,390
+are attached to one another in different ways
+
+38
+00:03:28,390 --> 00:03:33,610
+الذرات مرتبطة مع بعض البعض بطرق مختلفة يعني
+
+39
+00:03:33,610 --> 00:03:39,810
+بيختلفوا في ال bonding في الروابط واضح تماما زي ما
+
+40
+00:03:39,810 --> 00:03:43,470
+انا بدى امسك هدول الأقلام اقول في عندى أحمر أزرق
+
+41
+00:03:43,470 --> 00:03:48,010
+أسود هاني عملت إيش structure الآن ال bonding كيف
+
+42
+00:03:48,010 --> 00:03:51,530
+عندى هنا أحمر أزرق أسودأزرق ازرق ازرق ازرق ازرق
+
+43
+00:03:51,530 --> 00:04:05,290
+ازرق ازرق ازرق ازرق ازرق ازرق ازرق ازرق ازرق ازرق
+
+44
+00:04:05,800 --> 00:04:11,580
+وعاد التكوين بشكل جديد واضح من الأمثلة عليها لو
+
+45
+00:04:11,580 --> 00:04:15,820
+بتتطلع على المثال اللي موجود عندكم مثلا ال ethanol
+
+46
+00:04:15,820 --> 00:04:21,760
+و ال di-methyl ether كل جزء صيغته ال chemical
+
+47
+00:04:21,760 --> 00:04:26,260
+formula تبعته C2H6O
+
+48
+00:04:26,260 --> 00:04:32,260
+إذا هذول مشتركين في الصيغة وين الاختلاف تبعهم؟في
+
+49
+00:04:32,260 --> 00:04:36,520
+الارتباط يعني بعيدا عن الهيدروجين الجزء الأول
+
+50
+00:04:36,520 --> 00:04:41,980
+بتلاقي تركيبه carbon carbon oxygen الجزء التاني
+
+51
+00:04:41,980 --> 00:04:47,500
+بتلاقي تركيبه carbon oxygen carbon إذا هدولة they
+
+52
+00:04:47,500 --> 00:04:50,220
+differ in bonding
+
+53
+00:04:51,670 --> 00:04:54,950
+أو زي ما بتلاحظوا التعريف atoms are attached to
+
+54
+00:04:54,950 --> 00:04:58,290
+one another in different ways الذرات مرتبطة في بعض
+
+55
+00:04:58,290 --> 00:05:06,210
+البعض بطرق مختلفة هذا إنه حقيقة هو أسهل أنواع ال
+
+56
+00:05:06,210 --> 00:05:10,440
+isomersهذا النوع الـ structural isomers اللي
+
+57
+00:05:10,440 --> 00:05:16,020
+بيختلفه في مواقع الإرتباط هو أسهل أشكال ال isomers
+
+58
+00:05:16,020 --> 00:05:22,740
+يعني بنظرة بثانية بتقدروا تكتشفوا أن هذا مش زي هذا
+
+59
+00:05:23,370 --> 00:05:28,190
+واضح؟ سهل جدا ان نكتشف ال structural isomers يعني
+
+60
+00:05:28,190 --> 00:05:31,370
+مجرد ما بتطلعوا بتقولوا ان هدولة structural
+
+61
+00:05:31,370 --> 00:05:37,150
+isomers خليني اعطيكم مثال تاني تقولولي عنه انه
+
+62
+00:05:37,150 --> 00:05:40,630
+فعلا structural isomers ولا لا؟ لو تخيلتوا ان
+
+63
+00:05:40,630 --> 00:05:45,770
+عندكم بنزين وحطينا زي هيك كلور وكلور وبنزين تاني
+
+64
+00:05:45,770 --> 00:05:51,890
+وحطينا كلور وكلور هدولة الجزيين
+
+65
+00:05:55,640 --> 00:06:00,340
+Are they structural isomers؟ أكيد لأن هنا إذا
+
+66
+00:06:00,340 --> 00:06:03,300
+بتبتطلع الإرتباط، عندي chlorine، carbon، carbon،
+
+67
+00:06:03,300 --> 00:06:10,820
+chlorine، carbon، carbon، carbon، chlorine،
+
+68
+00:06:10,820 --> 00:06:12,600
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+69
+00:06:12,600 --> 00:06:12,800
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+70
+00:06:12,800 --> 00:06:16,060
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+71
+00:06:16,060 --> 00:06:16,840
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+72
+00:06:16,840 --> 00:06:16,860
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+73
+00:06:16,860 --> 00:06:16,880
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+74
+00:06:16,880 --> 00:06:19,960
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+75
+00:06:19,960 --> 00:06:20,440
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+76
+00:06:20,440 --> 00:06:20,460
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+77
+00:06:24,290 --> 00:06:30,030
+ميثانول المركب التاني داي مثل إيثر إذا ال
+
+78
+00:06:30,030 --> 00:06:37,610
+structural isomers they have different names ليش؟
+
+79
+00:06:37,610 --> 00:06:41,790
+لأن ال name أو الاسم للمركب بيعبر عن .. عن
+
+80
+00:06:41,790 --> 00:06:44,530
+structure عن ذرات طالما ال structure اختلف إذا
+
+81
+00:06:44,530 --> 00:06:50,580
+الاسم اختلف نفس الاشي هنالو كنتوا بتكونوا تسموا
+
+82
+00:06:50,580 --> 00:06:56,820
+هدولة المركبين هتقولوا ortho-dichlorobenzene او
+
+83
+00:06:56,820 --> 00:07:03,240
+one two dichlorobenzene هنا tara-dichlorobenzene
+
+84
+00:07:03,240 --> 00:07:07,700
+او one four dichlorobenzene ملاحظين انتوا ان مواقع
+
+85
+00:07:07,700 --> 00:07:11,920
+الارتباط كلها اختلفت البندج اختلف هذا أبسط نوع من
+
+86
+00:07:11,920 --> 00:07:15,680
+ال isomers اللي مر علينا كتير أمثلة زيه اللي
+
+87
+00:07:15,680 --> 00:07:20,730
+بنسميها ايشStructural isomers مش هذا موضوعنا اليوم
+
+88
+00:07:20,730 --> 00:07:25,190
+مش هذا موضوعنا اليوم ايش موضوعنا احنا اليوم النوع
+
+89
+00:07:25,190 --> 00:07:30,350
+التاني من ال isomers اللي اسمه ال stereo isomers
+
+90
+00:07:30,350 --> 00:07:37,830
+ال stereo isomers شوية بغلبه بدهم عينأو يمكن في
+
+91
+00:07:37,830 --> 00:07:41,530
+أول الأشياء ما تصدقوش ان هدول الأشياء مختلفين عن
+
+92
+00:07:41,530 --> 00:07:46,230
+بعضهم البعض مكتوب فيهم atoms have the same
+
+93
+00:07:46,230 --> 00:07:50,750
+substitution or constitution عفوا the same bonding
+
+94
+00:07:50,750 --> 00:07:54,970
+لهم نفس مواقع الارتباط but different arrangement
+
+95
+00:07:54,970 --> 00:08:00,290
+in space لكن كيف شكلهم بالفراغ بختلف بس مواقع
+
+96
+00:08:00,290 --> 00:08:06,480
+ارتباطهملا تختلف، فقط بيختلفوا بإيش؟ بالشكل اللي
+
+97
+00:08:06,480 --> 00:08:12,300
+موجود في الفراغ، كيف بالفراغ بيكون شكلهم، فللوحنة
+
+98
+00:08:12,300 --> 00:08:17,620
+الأولى الناس ممكن يخربطوا بينهم، الآن جرت العادة
+
+99
+00:08:17,620 --> 00:08:21,560
+أن الواحد قبل ما يشرح هذه الظاهرة كيميائيا، هذه
+
+100
+00:08:21,560 --> 00:08:27,040
+ظاهرة حياتيةيعني موجودة في الحياة كتير قد تكونوا
+
+101
+00:08:27,040 --> 00:08:30,620
+انتبهتوا إلها وقد لا تكونوا انتبهتوا إلها بس عليها
+
+102
+00:08:30,620 --> 00:08:35,060
+الأمثلة في الحياة كثيرة لا تعد ولا تحصى أنه أشياء
+
+103
+00:08:35,060 --> 00:08:41,560
+مبينة زي بعض لكن هي حقيقة مختلفة دائما أبدا المثال
+
+104
+00:08:41,560 --> 00:08:45,320
+اللي بيبدأوا فيه وبينطلقوا منه هو ال Eden تعون
+
+105
+00:08:45,320 --> 00:08:51,840
+البني آدمهدول الأيدين الآن السؤال هدول الأيدين زي
+
+106
+00:08:51,840 --> 00:08:59,900
+بعض ولا لأ؟ ملاحظين أنتوا؟ معنى زي بعض أنه أنا
+
+107
+00:08:59,900 --> 00:09:05,820
+بقدر أحط واحدة محل التانية يعني
+
+108
+00:09:05,820 --> 00:09:09,500
+لو بقدرة جادر بنفكه هدول التنتين بنقدر نحط هذه محل
+
+109
+00:09:09,500 --> 00:09:12,240
+هذه و هذه محل هذه إيش رأيكوا؟
+
+110
+00:09:15,510 --> 00:09:18,950
+طبعا انتوا صعب عليكوا تتخيلوا انه تعوني البني ادم
+
+111
+00:09:18,950 --> 00:09:22,730
+بنفكوا لكن معظمكوا في الطفولة اذا ماكانش في الكبر
+
+112
+00:09:22,730 --> 00:09:27,130
+كمان في عندهم العرايس لصغار لما تيجوا تركبوا
+
+113
+00:09:27,130 --> 00:09:31,490
+العروسة العروسة ايدين ورجلين لما تيجوا تركبوها
+
+114
+00:09:31,490 --> 00:09:35,670
+بتحسوا انه لازم احط اليد اليمين محلها و اليد
+
+115
+00:09:35,670 --> 00:09:40,770
+الشمال محلها لو حطته بالعكس بدل ما تكون اليد ال ..
+
+116
+00:09:42,080 --> 00:09:46,180
+الـ calf تبعها بيأشر لجوه جهة الجسم لو حاطيتها
+
+117
+00:09:46,180 --> 00:09:51,720
+بالعكس بيطلع لوره واضح؟ نفس الأشياء دول الأتين إذا
+
+118
+00:09:51,720 --> 00:09:56,060
+بتطلع عليهم شبههم كبير جدا يعني لو أنا اتخيلت أنه
+
+119
+00:09:56,060 --> 00:10:00,960
+عند مرايا هذه الإيد هي صورة هذه الإيد في المرأة
+
+120
+00:10:02,180 --> 00:10:06,020
+واضح؟ صورة بعض في المرأة لكن السؤال هل يا تورا
+
+121
+00:10:06,020 --> 00:10:08,800
+هدول الأشياء اللي صورت بعض في المرأة بينطبقوا ولا
+
+122
+00:10:08,800 --> 00:10:13,380
+لأ؟ بشكل عام لما بيكون عندى شغلتين صورة بعض في
+
+123
+00:10:13,380 --> 00:10:18,540
+المرأة ممكن ينطبقوا على بعض وممكن لا ينطبقوا على
+
+124
+00:10:18,540 --> 00:10:23,980
+بعض حسب كيف شكلهم بالفرق يعني مثلا لو مسكت هدولة
+
+125
+00:10:23,980 --> 00:10:30,720
+الكورتين الخضر مثلاكبر بس مش فيهم أي إشي هذه صورة
+
+126
+00:10:30,720 --> 00:10:34,780
+هذه في المرأة الآن هدولا كل إشي فيهم symmetric
+
+127
+00:10:34,780 --> 00:10:39,180
+بشكل كبير متماثلات بينطبقوا على بعض بمعنى لو كان
+
+128
+00:10:39,180 --> 00:10:42,680
+في جالب محطوطة هذه فيه وفيه فراغات عشان تقعد فيه
+
+129
+00:10:42,680 --> 00:10:48,380
+بالراحة هذه بتقعد زيها ولا لأ؟ بينطبقوا على بعض
+
+130
+00:10:48,380 --> 00:10:55,870
+واضح؟ بينطبقوا على بعض بسهولة جداواضح؟ الآن في
+
+131
+00:10:55,870 --> 00:11:00,350
+شغلات لأ مابتنطبقش ع بعض، يعني لو تخيلتوا مثلا
+
+132
+00:11:00,350 --> 00:11:05,010
+هدول الاتنين، لو أنا كنت بدي أشيل هذه الإيد و أجي
+
+133
+00:11:05,010 --> 00:11:10,410
+أحط هذه مكانها، لاحظوا الكف وين اتجاهه هنا؟ ع جهة
+
+134
+00:11:10,410 --> 00:11:15,150
+البني آدم، لو كنت بدي أحط هذه، بدي أحطها زي هيك،
+
+135
+00:11:15,150 --> 00:11:20,730
+إيش صار في هذا الأصبع؟رايح باتجاه هذا الأصبع رايح
+
+136
+00:11:20,730 --> 00:11:24,470
+باتجاه تاني، إذا هذه الإيد و هذه الإيد بنقدر نقول
+
+137
+00:11:24,470 --> 00:11:32,970
+عنهم صورة بعض في المرأة لكنها غير متطابقة صورة بعض
+
+138
+00:11:32,970 --> 00:11:39,450
+في المرأة لكنها غير متطابقة معنى صورة بعض في
+
+139
+00:11:39,450 --> 00:11:45,940
+المرأة mirror imagesمعنى غير متطابقة non-super
+
+140
+00:11:45,940 --> 00:11:51,720
+-imposable متطابق non-super-imposable غير متطابق
+
+141
+00:11:51,720 --> 00:11:56,880
+إذن إحنا بنقدر الآن نقول إن هدولة الـ two hands
+
+142
+00:11:56,880 --> 00:12:04,580
+الـ hands الإيدين non
+
+143
+00:12:04,580 --> 00:12:07,620
+-super
+
+144
+00:12:07,620 --> 00:12:08,800
+-imposable
+
+145
+00:12:13,170 --> 00:12:19,950
+mirror images يعني
+
+146
+00:12:19,950 --> 00:12:26,110
+صورة بعض في المرأة ولكنها غير متطابقةواضح؟ الان
+
+147
+00:12:26,110 --> 00:12:32,590
+هذا الاختلاف بالمناسبة هو اختلاف بس بالشكل الفراغي
+
+148
+00:12:32,590 --> 00:12:36,870
+بمعنى لو كنا بدنا نيجي مثلا على خاصية زي الكتلة و
+
+149
+00:12:36,870 --> 00:12:40,610
+أخدنا الإيد هادي و الإيد هادي هلاحظ إنهم نفس
+
+150
+00:12:40,610 --> 00:12:44,230
+الكتلة كإن أنا بدأت أجرب من الكيميا يعني لما بقول
+
+151
+00:12:44,230 --> 00:12:48,690
+the same molecular formula نفس الصيغة الجزائية
+
+152
+00:12:48,690 --> 00:12:51,330
+معناه the same molecular formula the same
+
+153
+00:12:51,330 --> 00:12:54,800
+molecular weightنفس الوزن، بس الاختلاف وين بده
+
+154
+00:12:54,800 --> 00:12:59,260
+يكون؟ بالشكل الفراغي الآن هذه الظاهرة، ظاهرة
+
+155
+00:12:59,260 --> 00:13:03,120
+الإيدين اللي بيكونوا صورة بعض في المراه و لكنها
+
+156
+00:13:03,120 --> 00:13:07,920
+غير متطابقة بيسموها ظاهرة ال handedness اللي هي
+
+157
+00:13:07,920 --> 00:13:11,700
+ظاهرة يعني مثل الإيدين handedness
+
+158
+00:13:17,380 --> 00:13:20,520
+إذا لو قلنا ظاهرة ال handedness أي شغل أصورة بعض
+
+159
+00:13:20,520 --> 00:13:25,640
+في المرأة غير متطابقة بتكون زي هيك الآن لو إجيتوا
+
+160
+00:13:25,640 --> 00:13:29,280
+تعطوا أمثلة .. لو إجيتوا تعطوا أمثلة على هذا
+
+161
+00:13:29,280 --> 00:13:35,000
+الموضوع من الحياة أمثلة كتيرة مين تعطينا مثل غير
+
+162
+00:13:35,000 --> 00:13:42,540
+الإيدين؟ خلصنا من الإيدين بنفع
+
+163
+00:13:42,540 --> 00:13:50,600
+رجلين؟ بنفع رجلينبنفع ما يوضع في الرجلين؟ الأحذية
+
+164
+00:13:50,600 --> 00:13:57,640
+الحذاء شوية كبير يعني معظمكم بتميزوه بس لاحظوا
+
+165
+00:13:57,640 --> 00:14:04,340
+دائما عندكم مشكلة مع الطفل الصغير بن سنة و سنتين
+
+166
+00:14:04,340 --> 00:14:09,580
+أكم مرة بتكونوا تقولوله اليمين لشمال بدلهم بياخدوا
+
+167
+00:14:09,580 --> 00:14:15,290
+الطفل ل 4 و 5 سنين و هو مش قادر يحس الفرقبين اللي
+
+168
+00:14:15,290 --> 00:14:19,710
+هو فردتي الحذاء ليش؟ لأنه بنطبق عليهم نفس الفكرة
+
+169
+00:14:19,710 --> 00:14:25,550
+هم صورة بعض في المرأة غير متطابقة فعشان يفهمها
+
+170
+00:14:25,550 --> 00:14:29,850
+الطفل قداش بده هذه الظاهرة، بده أربع أو خمس سنين
+
+171
+00:14:29,850 --> 00:14:37,030
+الأصعب منها الجرابين تلت ارباع الناس بخرف طينهم بس
+
+172
+00:14:37,030 --> 00:14:41,150
+لو بدكوا تيجيوا للحقيقة برضه فيهم شمال ويمين
+
+173
+00:14:41,150 --> 00:14:48,920
+الـQuantatتعون الأيد فيهم شمال ويمين الودنتين
+
+174
+00:14:48,920 --> 00:14:54,460
+اتخيلوا لو واحد هيك وودنتين ووجعه يعني اتجمده في
+
+175
+00:14:54,460 --> 00:14:58,360
+بارد شديد في روسيا ووجعه الجراح بده يربطله إياهم
+
+176
+00:14:58,360 --> 00:15:04,420
+لازم يكون عنده فكرة إن هدولة فيهم شمال ويمين واضح؟
+
+177
+00:15:04,420 --> 00:15:08,780
+الكلام وين بتكرر؟ عند الناس العاديين وبيفهموا هذه
+
+178
+00:15:08,780 --> 00:15:14,270
+الظاهرة كويس لو الباب تبع السيارة خرببروح الواحد
+
+179
+00:15:14,270 --> 00:15:18,690
+بيشتري باب بيقول لو سمحت في عندك باب مثلا Subaru
+
+180
+00:15:18,690 --> 00:15:23,150
+الباب اللي قداماني أول كلمة بيقولوا إياها يمين ولا
+
+181
+00:15:23,150 --> 00:15:27,070
+شمال لأن البابين تعون السيارة صورت بعض في المرأة
+
+182
+00:15:27,070 --> 00:15:32,410
+غير متطابقة واضح؟ فكل إشي قاعدين إحنا نشتغل عليه
+
+183
+00:15:32,410 --> 00:15:37,910
+الآن تخيلوا التعون البصريات الطبية لو إجوا يركبوا
+
+184
+00:15:37,910 --> 00:15:43,870
+هذه النضارةوكانت قطع هذه الأيد و هذه الأيد صورت
+
+185
+00:15:43,870 --> 00:15:48,710
+بعض في المرأة لكنها غير متطابقة هذا الجسم الصغير
+
+186
+00:15:48,710 --> 00:15:51,190
+اللي هنا وهذا الجسم الصغير اللي هنا صورت بعض في
+
+187
+00:15:51,190 --> 00:15:54,750
+المرأة لو انحط بالعكس بيطلع واحد لفوق واحد لتحت
+
+188
+00:15:54,750 --> 00:16:00,050
+غير متطابق هذه العدسة و هذه العدسة صورت بعض في
+
+189
+00:16:00,050 --> 00:16:03,570
+المرأة ولكنها غير متطابقة الآن اللي بيشتغل في
+
+190
+00:16:03,570 --> 00:16:07,970
+المجال لازم ينتبه لكل هذهينتبه لكل هذه الأمور كل
+
+191
+00:16:07,970 --> 00:16:13,330
+هذولا بيخضعوا لقاعدة إيش ال handedness الان الكلام
+
+192
+00:16:13,330 --> 00:16:19,150
+نفسه موجود في الكيميا الكلام نفسه موجود في الكيميا
+
+193
+00:16:19,150 --> 00:16:24,030
+و اكتشف بيصير موجود في الكيميا بيصير موجود في
+
+194
+00:16:24,030 --> 00:16:30,570
+الكيميا إذا كان عنده حول ذرة الكربون أربع مجموعات
+
+195
+00:16:30,570 --> 00:16:37,530
+مختلفةإذن الشرط عندى عشان يكون موجود في الكيمية
+
+196
+00:16:37,530 --> 00:16:42,210
+الكربون ما يبتعمل كام رابطة؟ أربعة بدوا يكونوا
+
+197
+00:16:42,210 --> 00:16:47,150
+الأربع مجموعات اللى موجودين على الكربون أربع
+
+198
+00:16:47,150 --> 00:16:53,190
+مجموعات مختلفة وقتها بيصير الجزء و صورته في
+
+199
+00:16:53,190 --> 00:16:59,510
+المرايا غير متطابقين الآن خلينا نعمل هذا الكلام
+
+200
+00:16:59,510 --> 00:17:05,210
+بهدوء باستعمالالموديلز okay بدنا نعمل جزيق هيكربون
+
+201
+00:17:05,210 --> 00:17:12,450
+okay ونحط عليه أربع ذرات خلينا نقول بدنا نحط عليه
+
+202
+00:17:12,450 --> 00:17:19,030
+يود اليود إيش لونه أزرق هيحطين هذه الزرقة تعبيرا
+
+203
+00:17:19,030 --> 00:17:26,790
+عن اليود وبدنا نحط عليه بروم البروم إيش لونه لا
+
+204
+00:17:26,790 --> 00:17:32,720
+بردجان البرومالبروم أحمر على برتقالي برتقالي
+
+205
+00:17:32,720 --> 00:17:36,900
+البروم برتقالي محلول البرومين لما بتعملوا تجربة
+
+206
+00:17:36,900 --> 00:17:40,560
+double bond و بيختفي لونه بيختفي من البرتقالي إلى
+
+207
+00:17:40,560 --> 00:17:45,720
+عديم اللون البروم برتقالي مظبوط ولا لأ الchlor
+
+208
+00:17:45,720 --> 00:17:51,280
+أخضر أخضر على أصفر إذا احفظوا اليوم الألوان هذا
+
+209
+00:17:51,280 --> 00:17:56,420
+الأزرق تعبير عن إيش يوت والبرتقالي البروم والأخضر
+
+210
+00:17:56,420 --> 00:18:02,690
+الchlor هذه السكنية نعتبرها هيدروجينOkay؟ الان يا
+
+211
+00:18:02,690 --> 00:18:09,990
+تورا لو انا اجيت اعملت لو انا اجيت اعملت صورة لهذا
+
+212
+00:18:09,990 --> 00:18:16,470
+الجزء في المرأة حطيت هنا hydrogen, brom, iod,
+
+213
+00:18:17,050 --> 00:18:21,530
+chlorine هاي هدول التينين صورة بعض في المرأة ولا
+
+214
+00:18:21,530 --> 00:18:26,790
+لأ؟ الان يا تورا هدول التينين بنطبقوا على بعض ولا
+
+215
+00:18:26,790 --> 00:18:33,060
+لأ؟واضح؟ انجرب معناه بنطبقوا على بعض كل ذرة بده
+
+216
+00:18:33,060 --> 00:18:37,840
+تيجي مكان التاني لو إجينا نجرب هنا حطينا البردجاني
+
+217
+00:18:37,840 --> 00:18:43,820
+على البردجاني البنة على البنة إيش بتلاحظوا؟ الأخضر
+
+218
+00:18:43,820 --> 00:18:48,660
+والأزرق مايجيوش على بعض لو بدنا نجرب نقول طب بنظبط
+
+219
+00:18:48,660 --> 00:18:54,340
+الأخضر والأزرق مش مشكلة نحاول نخلي الأزرق والأخضر
+
+220
+00:18:54,340 --> 00:18:58,060
+ييجوا على بعض هاي هاي حلينا المشكلة أزرق و أزرق
+
+221
+00:18:59,060 --> 00:19:07,740
+أخضر و أخضر صار البرتقالي إذا هدولة التنين حقيقة
+
+222
+00:19:07,740 --> 00:19:12,140
+غير مطابقين على بعضهم البعض رغم شدة التشابه اللي
+
+223
+00:19:12,140 --> 00:19:16,080
+بينهم و رغم إنهم صورة بعض في المرأة إذا هنا تتكرر
+
+224
+00:19:16,080 --> 00:19:22,060
+ظاهرة إيش ال handedness إن هدولة زي ال hands واضح؟
+
+225
+00:19:22,450 --> 00:19:26,890
+بالمناسبة كل الأشياء اللي فيها هذه الظاهرة بتكون
+
+226
+00:19:26,890 --> 00:19:30,510
+stereo isomers بمعنى نفس الذرات نفس ال molecular
+
+227
+00:19:30,510 --> 00:19:35,130
+weight كله نفس الاشياء لكن الإختلاف هنا وين بشكل
+
+228
+00:19:35,130 --> 00:19:40,060
+الفراغة بنسميهم enantiomersواضح؟ عشان هيك ال
+
+229
+00:19:40,060 --> 00:19:43,940
+stereo isomers بيقسموا إلى نوعين النوع اللي بنبدأ
+
+230
+00:19:43,940 --> 00:19:47,340
+في هذه المحاضرة و جزء من البعدة اسمه enantiomers و
+
+231
+00:19:47,340 --> 00:19:51,960
+النوع التاني بعدين بنتعرف عليه اسمه the stereomers
+
+232
+00:19:51,960 --> 00:19:56,700
+اليوم احنا بالإيش؟ بال enantiomers ال enantiomers
+
+233
+00:19:56,700 --> 00:20:00,880
+they are non sober invisible mirror image
+
+234
+00:20:00,880 --> 00:20:07,850
+stereoisomersزي شغل الإيدين هما Stereoisomers صورة
+
+235
+00:20:07,850 --> 00:20:12,530
+بعض في المرأة غير متطابقة باللغة الإنجليزية ببساطة
+
+236
+00:20:12,530 --> 00:20:16,650
+إيش بنقول ال Enosomers؟ none, super, imposible
+
+237
+00:20:16,650 --> 00:20:20,410
+يعني غير متطابقة mirror image stereoisomers صورة
+
+238
+00:20:20,410 --> 00:20:29,290
+بعض في المرأة ولكنها غير متطابقة مظبوط ولا لأ؟ مين
+
+239
+00:20:29,290 --> 00:20:35,000
+تعرفيلنا إياهم؟ إيش هما ال Enosomers؟تفضلي ..
+
+240
+00:20:35,000 --> 00:20:40,640
+تفضلي .. اه حاضر .. اه تفضلي .. non super .. non
+
+241
+00:20:40,640 --> 00:20:46,240
+super .. imposible .. non super imposible .. non
+
+242
+00:20:46,240 --> 00:20:47,940
+super imposible mirror image .. non super
+
+243
+00:20:47,940 --> 00:20:49,760
+imposible mirror image .. non super imposible
+
+244
+00:20:49,760 --> 00:20:50,040
+mirror image .. non super imposible mirror image
+
+245
+00:20:50,040 --> 00:20:50,140
+imposible mirror image .. non super imposible
+
+246
+00:20:50,140 --> 00:20:50,560
+mirror image .. non super imposible mirror image
+
+247
+00:20:50,560 --> 00:20:50,680
+.. non super imposible mirror image .. non super
+
+248
+00:20:50,680 --> 00:20:50,780
+imposible mirror image .. non super imposible
+
+249
+00:20:50,780 --> 00:20:51,140
+imposible mirror image .. non super imposible
+
+250
+00:20:51,140 --> 00:20:51,680
+mirror image .. non super imposible mirror image
+
+251
+00:20:51,680 --> 00:20:52,960
+imposible mirror image .. non super imposible
+
+252
+00:20:52,960 --> 00:20:55,620
+mirror image .. non super imposible mirror image
+
+253
+00:20:55,620 --> 00:20:58,040
+.. non super imposible mirror image .. non super
+
+254
+00:20:58,040 --> 00:21:02,780
+imposible mirror image .. non super imposible
+
+255
+00:21:02,780 --> 00:21:03,960
+mirror
+
+256
+00:21:07,430 --> 00:21:12,350
+آخر الحصة بدنا نعطيها إياه، ماشي الحال ولا لأ؟ ها
+
+257
+00:21:12,350 --> 00:21:16,910
+احنا أقولها لك، بدنا نعطيك إياه، الآن لو أجيت
+
+258
+00:21:16,910 --> 00:21:23,730
+سألتكم، في شرط عشان نعطيها إياه، عارفين شو هو
+
+259
+00:21:23,730 --> 00:21:27,290
+الشرط؟ إنها تحلف ليمين أي واحد اللي قلت لها بده
+
+260
+00:21:27,290 --> 00:21:27,850
+أعطيك إياه
+
+261
+00:21:32,320 --> 00:21:37,820
+لأ، يمين رسمي، مش تخميني أنه واحد فيهم اللي أنا
+
+262
+00:21:37,820 --> 00:21:43,180
+قلت لها بتعطيك إياه بثقة مائة في المائة هل تستطيع
+
+263
+00:21:43,180 --> 00:21:51,200
+أن تجيب؟ خلاص، راحت عليها الجائزة، مشكلة إذا أنا
+
+264
+00:21:51,200 --> 00:21:55,340
+بعد ما شُفت هدول اللي فيهم تشابه كبير صرت عندي
+
+265
+00:21:55,340 --> 00:22:00,260
+مشكلة جديدة إن كيف بدي أميزهم عن بعض؟عشان بعد شوية
+
+266
+00:22:00,260 --> 00:22:03,540
+لما تقول أبنان أعطيك إياها تتطلع، تقول خلاص، أعرف
+
+267
+00:22:03,540 --> 00:22:09,400
+أنا اللي بدي أاخده، واضح؟ إذا بيصير السؤال كيف بدي
+
+268
+00:22:09,400 --> 00:22:12,520
+أميز هذا عن هذا؟ أنا هلجأت هذا ماسكه بالإيدي
+
+269
+00:22:12,520 --> 00:22:15,360
+اليمين و هذا بالإيشمال؟ لو إن لفتك شوية و رجعت
+
+270
+00:22:15,360 --> 00:22:20,470
+ماسكهم، شو بدي أعرفكم؟كيف بدي اميزهم عن بعض؟ بس زي
+
+271
+00:22:20,470 --> 00:22:24,250
+ما انا بقول انه في بينهم نوع من الاختلاف ماانطبقوش
+
+272
+00:22:24,250 --> 00:22:27,990
+على بعض، اذا لازم يكون عنده القدرة على اني اميزهم
+
+273
+00:22:27,990 --> 00:22:33,550
+عن بعض، الان التمييز تبعهم عن بعض سهل، اتخيلوا
+
+274
+00:22:33,550 --> 00:22:38,200
+انهم سيكتوا اي واحدبدي اياكوا اترطبوا الذرات
+
+275
+00:22:38,200 --> 00:22:41,760
+تبعونه أولويات من الأعلى في الـ atomic weight
+
+276
+00:22:41,760 --> 00:22:48,060
+للأقل للأقل للأقل زي ما عملنا لما كنا ناخد الـ CIS
+
+277
+00:22:48,060 --> 00:22:52,360
+والـ Trans والـ Z والـEI زمارز متذاكرين هم ولا لأ؟
+
+278
+00:22:52,360 --> 00:22:56,900
+الآن احنا الأربع ذرات اللي عندنا لو تتذكروا الجدول
+
+279
+00:22:56,900 --> 00:23:04,150
+الدوري كل شيء كله كان عندي floor floor floorيهود
+
+280
+00:23:04,150 --> 00:23:10,350
+والهيدروجين الأقل واحد إذا أي مجموعة فيهم الأقل
+
+281
+00:23:10,350 --> 00:23:15,690
+الهيدروجين بعد هيك لو بدى أتحرك من الأكبر إلى
+
+282
+00:23:15,690 --> 00:23:23,090
+الأصغر أنه أعلى واحد بعده لبروم بعده لكلوب الآن
+
+283
+00:23:23,090 --> 00:23:27,890
+عشان أميزهم بمسك الجزيء بمسك الجزيء بخل المجموعة
+
+284
+00:23:27,890 --> 00:23:34,210
+الأقل الخلفهيتفقنا الهيدروجين للخلف، الآن بقاجي
+
+285
+00:23:34,210 --> 00:23:41,350
+أتحرك من الأعلى للأقل للأقل، وين الأعلى؟ اليود،
+
+286
+00:23:41,350 --> 00:23:46,910
+الأقل منه؟ البروم، الأقل منه؟ الكلور، الأقل منه؟
+
+287
+00:23:46,910 --> 00:23:47,050
+الكلور، الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+288
+00:23:47,050 --> 00:23:55,590
+الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+289
+00:23:55,590 --> 00:23:56,990
+الأقل منه؟ الكلور، الأقل منه؟ الكلور، الأقل منه؟
+
+290
+00:23:56,990 --> 00:23:57,510
+الكلور، الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+291
+00:23:57,510 --> 00:24:03,150
+الأقل منه؟ اليطلع زيه، خلّينا نمسك التاني، خلّينا
+
+292
+00:24:03,150 --> 00:24:08,610
+أقل مجموعة الهيدروجين للخلف، وبدأ اتحرك من الأعلى
+
+293
+00:24:08,610 --> 00:24:16,990
+للأقل اليود لبروم لكلور، مع قارب الساعة، إذا انا
+
+294
+00:24:16,990 --> 00:24:21,880
+اقدرت أحصل الاختلاف اللي بينهمكتير تحصل الاختلاف
+
+295
+00:24:21,880 --> 00:24:25,420
+اللي بينهم انه انا لما بحطه مبادية معينة بحس انه
+
+296
+00:24:25,420 --> 00:24:29,460
+أقل مجموعة للخلف و بعدين بنتقل من الأعلى للأقل
+
+297
+00:24:29,460 --> 00:24:37,540
+للأقل اما ان اتحرك مع عقارب الساعة او اتحرك عكس
+
+298
+00:24:37,540 --> 00:24:44,160
+عقارب الساعة الان اذا تحركت مع عقارب الساعة باعطي
+
+299
+00:24:44,160 --> 00:24:49,980
+للجزء الرمز R R جاية من ايش؟ من اليمين باللاتيني
+
+300
+00:24:50,990 --> 00:24:57,650
+بعطي إيش الرمز؟ R إذا تحركت مع عقارب الساعة بعطي R
+
+301
+00:24:57,650 --> 00:25:04,570
+إذا تحركت عكس عقارب الساعة بعطي S هذه ال S بس
+
+302
+00:25:04,570 --> 00:25:08,750
+مقدمة لكن لو إجيت الآن قولت أنا بدي أسمي هذا
+
+303
+00:25:08,750 --> 00:25:14,110
+المركب كاملاً هذا عبارة عن Carbon واحدة إذا هو
+
+304
+00:25:14,110 --> 00:25:20,570
+مشتقة Methaneالكربل الواحدة مشتقة مثين عليها تلت
+
+305
+00:25:20,570 --> 00:25:26,370
+مجموعات إبروم و كلور و أيود حسب الترتيب ال
+
+306
+00:25:26,370 --> 00:25:33,830
+alphabetical هذا المركب اسمه إبرومو إكلورو أيودو
+
+307
+00:25:33,830 --> 00:25:40,660
+مثينفي خلاف عليها؟ لأ ابدا ابرومو اكلورو ايودو
+
+308
+00:25:40,660 --> 00:25:45,260
+ميثين هاي من ناحية الذرات الآن لو اجيت للمركب
+
+309
+00:25:45,260 --> 00:25:50,360
+التاني ايش اسمه؟ نفس الاشي لاحظ هنا لأنهم متحدين
+
+310
+00:25:50,360 --> 00:25:55,260
+في الارتباط و في عدد الذراتabromo-chloro
+
+311
+00:25:55,260 --> 00:26:00,040
+-iodomethane إذا الإسم اللي بيحدد الأنواع الذرات
+
+312
+00:26:00,040 --> 00:26:04,320
+ومواقعها مختلفش بين هذا و هذا هذا abromo-chloro
+
+313
+00:26:04,320 --> 00:26:10,240
+-iodomethane وهذا abromo-chloro-iodomethane مافيش
+
+314
+00:26:10,240 --> 00:26:15,140
+بينهم اختلاف هوين الإختلاف بدي أبينه أن أحط بادئة
+
+315
+00:26:15,140 --> 00:26:19,160
+اتميز ليهم زي تماما حوالين ال double bond كنا نحط
+
+316
+00:26:19,160 --> 00:26:27,140
+البادئةSes و Trans أو انعبر عنهم ب Z و E الان هذا
+
+317
+00:26:27,140 --> 00:26:31,360
+اتطلع عليه مرة تانية اتذكر واحد اتنين تلاتة هذا
+
+318
+00:26:31,360 --> 00:26:36,540
+بنحط قدامه حرف ال S capital S بين قوسين بيصير S
+
+319
+00:26:36,540 --> 00:26:39,680
+-bromochloroiodomethane
+
+320
+00:26:39,680 --> 00:26:46,280
+وهذا بيصير R-bromochloroiodomethane
+
+321
+00:26:47,190 --> 00:26:51,190
+زي تماما ما كنتوا تقولوا اسم two بيوتين مشترك two
+
+322
+00:26:51,190 --> 00:26:56,090
+بيوتين و two بيوتين بإيش بنفرجهم عن بعض هذا بنحطله
+
+323
+00:26:56,090 --> 00:27:00,530
+بادئة cis هذا بنحطله بادئة trans الآن في حالة هدول
+
+324
+00:27:00,530 --> 00:27:05,210
+المراكبات اللي احنا بنسميهم enantiomers بنحط إيش
+
+325
+00:27:05,210 --> 00:27:10,790
+البادئة؟ R و S اللي مع عقارب الساعة R اللي ضد
+
+326
+00:27:10,790 --> 00:27:16,550
+عقارب الساعة S واضح؟الان هذا الكلام انا بتايعني
+
+327
+00:27:16,550 --> 00:27:21,290
+صرته انتوا أتقنتوه من خلال انه احنا مسكين الجزائر
+
+328
+00:27:21,290 --> 00:27:26,130
+لكن الإشكالية انه احنا لو بدنا نيجي نسألكوا حقيقة
+
+329
+00:27:26,130 --> 00:27:32,250
+في الامتحان ما بنخليكوا مش تمسكوا الجزائر بنرسملكم
+
+330
+00:27:33,930 --> 00:27:37,550
+نرسملكم على اللوح أو على الورقة و بنقولكوا حددونا
+
+331
+00:27:37,550 --> 00:27:42,890
+هذا المركب R ولا S إذا بصير سؤالي كيف بدي أحدد هذا
+
+332
+00:27:42,890 --> 00:27:47,790
+R ولا S لما أكون أنا راسمه خليني أاخد واحد منهم
+
+333
+00:27:47,790 --> 00:27:52,870
+وأتأكد منه في الأول بالشكل العام هل هو R ولا S هذا
+
+334
+00:27:52,870 --> 00:28:00,750
+اللي أنا ماسكه، شو هو؟ يود؟ إبروم؟ إكلور؟ هذا R
+
+335
+00:28:00,750 --> 00:28:06,800
+خلاص ال Sخلصت منه بديش أشوفه إذا أنا اللي ماسكه
+
+336
+00:28:06,800 --> 00:28:11,260
+يعني قادر أشوفه بالظبط أنه R ولا لأ؟ قادر أشوفه
+
+337
+00:28:11,260 --> 00:28:16,880
+أنه R بدي أرجع أرسمه على اللوح الآن أنا بإمكاني
+
+338
+00:28:16,880 --> 00:28:20,000
+أرسمه طرق مختلفة طبعا تكونوا أنتوا متذكري ان احنا
+
+339
+00:28:20,000 --> 00:28:24,460
+اتفقنا الجزء حوالين ال carbon نقول رابطتين زي هيك
+
+340
+00:28:24,460 --> 00:28:30,460
+للأمام و تنتين للخلف بنرسمه على شكل cross بس
+
+341
+00:28:30,460 --> 00:28:35,030
+المفهوم أن الويجيه أفقياتللأمام هيك رايحين و اللي
+
+342
+00:28:35,030 --> 00:28:40,870
+بيجوا رأسيات رايحين لوين؟ للخلف الآن يا تورا لو
+
+343
+00:28:40,870 --> 00:28:50,610
+هذا الجزء اجينا مسكناه زي هيك ممكن نرسمه زي هيك؟
+
+344
+00:28:50,610 --> 00:29:00,470
+إيش بدنا نحط هنا؟ claw هنا إبروم هنا هنا
+
+345
+00:29:02,270 --> 00:29:06,090
+ممكن نجرب نمسكه بطريقة تانية، حد مش ممنعنا كيف
+
+346
+00:29:06,090 --> 00:29:11,770
+نمسكه، أنا بمسكه بمليون طريقة، كويس؟ لكن لحظة أنا
+
+347
+00:29:11,770 --> 00:29:16,290
+ماسك جزيقه برسم يعني، المفروض أنه مايتغيرش، ايش
+
+348
+00:29:16,290 --> 00:29:21,270
+أنا بضحك؟ هاي الدرجان، كلاو، كلاو، كلاو، كلاو،
+
+349
+00:29:21,270 --> 00:29:23,090
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+350
+00:29:23,090 --> 00:29:25,170
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+351
+00:29:25,170 --> 00:29:25,770
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+352
+00:29:25,770 --> 00:29:31,290
+كلاو، كلاو،
+
+353
+00:29:39,820 --> 00:29:55,240
+ممكن أمسكه بطريقة رابعة هذا
+
+354
+00:29:55,240 --> 00:29:59,080
+كله أرسم لنفس الجذيل يعني الجذيل اللي أنا مازكه R
+
+355
+00:29:59,080 --> 00:30:05,280
+ولا S إذا أتوا مش متأكدين لسه أتأكدواR U دي بروم
+
+356
+00:30:05,280 --> 00:30:09,300
+نيجي
+
+357
+00:30:09,300 --> 00:30:14,080
+على اللوح احنا رسمنا ال R بطرق مختلفة انحدد اقل
+
+358
+00:30:14,080 --> 00:30:24,060
+مجموعة اقل مجموعة و
+
+359
+00:30:24,060 --> 00:30:28,700
+بعدين نيجي نتحرك من الأعلى للأقل للأقل و نشوف ايش
+
+360
+00:30:28,700 --> 00:30:35,230
+اللي بيطلع عندنا اذا اتحركنا نقع لوحدةيود بروم
+
+361
+00:30:35,230 --> 00:30:38,630
+بكلور
+
+362
+00:30:38,630 --> 00:30:43,410
+هينا ماشي هيك كيف أنا متحرك مع قرب الساعة اذا هذا
+
+363
+00:30:43,410 --> 00:30:48,970
+المركب R في عندي مشكلة زي ما بقينا على راسنا قصة
+
+364
+00:30:48,970 --> 00:30:54,950
+سهلة جدا نيجي هنا نتطلع كمان مرة و الأعلى واحدة
+
+365
+00:30:54,950 --> 00:31:01,030
+بعدها بعدها كيف
+
+366
+00:31:01,030 --> 00:31:06,960
+أنا متحركمع القرن الساعة، إذا هذا R نيجي على
+
+367
+00:31:06,960 --> 00:31:12,480
+المركب اللي بعده يود،
+
+368
+00:31:12,480 --> 00:31:20,020
+إبروم، حينيكا، إفلون، كيف صارت أتحرك؟ صار عندي
+
+369
+00:31:20,020 --> 00:31:23,840
+مشكلة، طب أنا اللي ماسكه راسمه R، الاسم، حطناه
+
+370
+00:31:23,840 --> 00:31:27,320
+بعيد عنه لحظة و أنا صار عندي مشكلة، تشوفها بتتكرر
+
+371
+00:31:27,320 --> 00:31:36,220
+ولا لأ؟ اه، لو يقولنا أشهر على حاجةبعدها بروم
+
+372
+00:31:36,220 --> 00:31:44,320
+بعدها كيف اتحركاني؟ أسقر بالساعة هل المركب صار S؟
+
+373
+00:31:44,320 --> 00:31:48,420
+انا ماسك و قاعد برسم و ليش صار عندى هذا التناقض
+
+374
+00:31:48,420 --> 00:31:53,960
+واضح؟ ليش صار عندى هذا التناقض إذا ابتلقوا نظرة
+
+375
+00:31:53,960 --> 00:31:59,820
+على الأربع رسمات كصورة كلية بتلاحظوا في الرسمة
+
+376
+00:31:59,820 --> 00:32:07,800
+الأولى و التانيةأقل مجموعة كانت مرسومة فوق أو تحت،
+
+377
+00:32:07,800 --> 00:32:15,260
+فوق أو تحت بمنطق الرسم، إيش معناه للخلف؟ واضح؟
+
+378
+00:32:15,260 --> 00:32:20,700
+يعني كأنه لو أنا ماسك زي هيك الجزاءهذه المجموعة
+
+379
+00:32:20,700 --> 00:32:25,180
+وين بتكون دائما اللي فوق وتحت؟ للخلف وانا الشرط
+
+380
+00:32:25,180 --> 00:32:31,100
+عندي أن تكون المجموعة للخلف ولذلك ال configuration
+
+381
+00:32:31,100 --> 00:32:33,900
+هذا بنسميه ال configuration تحديد ال R و ال S
+
+382
+00:32:33,900 --> 00:32:38,660
+بنسميه ال configuration طلع صحيح لأنه أقل مجموعة
+
+383
+00:32:38,660 --> 00:32:44,300
+موجودة أساسا للخلف بينما لو إجيتوا و طلعتوا على
+
+384
+00:32:44,300 --> 00:32:49,060
+واحد من هدول خلينا ناخد هذا المركب اللي كان زي ذلك
+
+385
+00:32:50,440 --> 00:32:56,280
+هذا هو بالظبط و لا لأ؟ شايفينه
+
+386
+00:32:56,280 --> 00:33:04,380
+اقلوم اقلوم اكتشوف الان هينماسكوا زي هيك هتبدوا
+
+387
+00:33:04,380 --> 00:33:07,800
+تلاحظوا انه في تناقض من عندكم امشولي من الأعلى
+
+388
+00:33:07,800 --> 00:33:15,480
+للأقل شوفوا ليه كيف مبين اقلوم اقلوم اكتشوف
+
+389
+00:33:16,850 --> 00:33:21,910
+انبين عندكم S، الآن احنا بالنسبة لي انا الوضع
+
+390
+00:33:21,910 --> 00:33:29,330
+مختلف، انا بطلع يود، ابروم، اكلور، انا شايفه R،
+
+391
+00:33:29,330 --> 00:33:34,410
+انتوا شايفينه؟ S، مين اللي بشوف صاحب؟ لأ دايما
+
+392
+00:33:34,410 --> 00:33:41,100
+الأستاذالأستاذ ليش أنا شايفه R كما هو في الحقيقة و
+
+393
+00:33:41,100 --> 00:33:46,920
+أنتوا شايفينه S لأن أنا مكان الوقوف تبعي خلّيت ال
+
+394
+00:33:46,920 --> 00:33:53,060
+H للخلف بالنسبة لي وهذا شرط تحديد ال configuration
+
+395
+00:33:53,060 --> 00:33:57,080
+قلنا لك أقل مجموعة أين يجب أن تكون للخلف الآن لما
+
+396
+00:33:57,080 --> 00:34:02,180
+رسمت على الجنب هي للأمام إذا المجموعة للأمام و
+
+397
+00:34:02,180 --> 00:34:05,200
+أنتوا بتتطلعوا من قدام طلع عندكم ال configuration
+
+398
+00:34:05,200 --> 00:34:09,540
+فيهأشكالية عشان كذا ال configuration لو كنتوا
+
+399
+00:34:09,540 --> 00:34:12,500
+بتكونوا تشوفوه صح المفروض تتخيلوا ان انتوا دخلتوا
+
+400
+00:34:12,500 --> 00:34:15,820
+ورا اللوحة طلعتوا من ورا بس المجموعة من الأمام
+
+401
+00:34:15,820 --> 00:34:20,140
+وانتوا من نفس الجهة بيصير عندكم مشكلة طب كيف بتحل
+
+402
+00:34:20,140 --> 00:34:23,380
+هذه المعضلة؟
+
+403
+00:34:23,380 --> 00:34:28,840
+بتعرفوا المثل اللي بيقول صدمة بتضيع صدمة؟ ولا
+
+404
+00:34:28,840 --> 00:34:34,160
+minus ضرب minus بيساوي زائد؟ الآن أنا هنافي عندي
+
+405
+00:34:34,160 --> 00:34:39,260
+خطأ إن المجموعة اللي أصل تكون الخلف مرسومة للأمام
+
+406
+00:34:39,260 --> 00:34:43,140
+طالما أنه على أحد الجانبين فهي للأمام بقول غلطة
+
+407
+00:34:43,140 --> 00:34:48,920
+بتضيع غلطة باجي لما أحدد ال configuration بقرا إيش
+
+408
+00:34:48,920 --> 00:34:53,640
+طلع عند ال configuration و بكتب عكسه كأن عملت عكس
+
+409
+00:34:53,640 --> 00:34:55,660
+في عكس بتطلع الجواب عندكم صح
+
+410
+00:34:58,290 --> 00:35:01,850
+بتكتش و تفهموها بشكل القاتل، إذا أقل مجموعة عندكم
+
+411
+00:35:01,850 --> 00:35:05,650
+موجودة لفور أو لتحت، امشوا من الأعلى للأقل و حطوا
+
+412
+00:35:05,650 --> 00:35:10,050
+الجواب مباشرة، بتكونوا اشتغلتوا صح. الآن، إذا أقل
+
+413
+00:35:10,050 --> 00:35:17,450
+مجموعة موجودة على أحد الجانبين،
+
+414
+00:35:17,450 --> 00:35:22,550
+افضوا من الأعلى للأقل و اكتبوا عكس الجواب، تتعبوش
+
+415
+00:35:22,550 --> 00:35:27,830
+أعصابكم؟امشوا زي ما احنا متفقين بس طالما أقل
+
+416
+00:35:27,830 --> 00:35:31,810
+مجموعة محطوطة على الجانب وكتبوا عكس الجواب بتكونوا
+
+417
+00:35:31,810 --> 00:35:36,890
+عملته الصح ليش؟ لأن هذه المجموعة للأمام معكوسة
+
+418
+00:35:36,890 --> 00:35:42,250
+فانتوا الجواب اللي بتطلعوه بتعكسه واضح؟ وعشانك لما
+
+419
+00:35:42,250 --> 00:35:46,030
+أنا هنا بمشي يود ال brom و الchloro وهذه أقل
+
+420
+00:35:46,030 --> 00:35:52,330
+مجموعة على الجانب بتبقى I ببينها S بتقول S بصوت
+
+421
+00:35:53,740 --> 00:35:58,680
+بصوت واطد و بحد يسمعه، بس لازم ينسمع الاسم، لأنه
+
+422
+00:35:58,680 --> 00:36:08,140
+إيش؟ لأنه من الحروف الصفير والهمس، مهموس و أفحته
+
+423
+00:36:08,140 --> 00:36:12,660
+شخص سكت، مظبوط ولا لأ؟ أه من الحروف الصفير والهمس،
+
+424
+00:36:12,660 --> 00:36:19,600
+بتسمعه، بتقول هي بصوت واطد، و بتكتبوه آه، بتكون
+
+425
+00:36:19,600 --> 00:36:25,160
+حطيته الجواب الصحكأنكوا اكتشفتوا ان في عندكوا غلطة
+
+426
+00:36:25,160 --> 00:36:29,840
+في المجموعة انها مش مرسومة للخلف مرسومة للأمام و
+
+427
+00:36:29,840 --> 00:36:34,080
+الشرط تكون مرسومة الخلف بتحط بناها هذا المركب نفس
+
+428
+00:36:34,080 --> 00:36:45,200
+الاشي باجي بقول you'd بقول كتابة
+
+429
+00:36:45,200 --> 00:36:52,660
+الصحي باضح؟و بهيك بنقدر احنا نحدد ال configuration
+
+430
+00:36:52,660 --> 00:36:58,980
+لأي جزء .. بهيك بنقدر احنا نحدد ال configuration
+
+431
+00:36:58,980 --> 00:37:08,100
+لأي جزء .. الان كتير كلام شرحناه لكم و احنا
+
+432
+00:37:08,100 --> 00:37:12,980
+واجفينه و جلبنا صفحات كتيرة خلينا نمشي عليها بسرعة
+
+433
+00:37:12,980 --> 00:37:16,260
+في ال computer و تشوف انه فعلا اخدنا هذه الأشياء
+
+434
+00:37:16,260 --> 00:37:21,480
+ولا لأباقي صفحة ال isomers هنعود نرجع لها في هدوء
+
+435
+00:37:21,480 --> 00:37:29,480
+الآن عرفنا إيش معنى pair of enantiomers واضح؟ لما
+
+436
+00:37:29,480 --> 00:37:34,020
+يكون عندي carbon بتحمل أربع مجموعات مختلفة الآن
+
+437
+00:37:34,020 --> 00:37:37,040
+هذه ال carbon اللي بتحمل أربع مجموعات مختلفة
+
+438
+00:37:37,040 --> 00:37:42,440
+بنسميها كايرال كاربون إيش معنى كايرال كاربون؟
+
+439
+00:37:42,440 --> 00:37:47,190
+بتحمل أربع مجموعات مختلفةإذا حصل هذا الكلام زي
+
+440
+00:37:47,190 --> 00:37:53,850
+الحالة اللي عندنا فالجزء و صورته في المرأة بيكونوا
+
+441
+00:37:53,850 --> 00:37:58,430
+غير متطابقين و بيطلع عندنا تعريف الانان شمارز
+
+442
+00:37:58,430 --> 00:38:05,110
+والانان شمارز دائما هي عبارة عن زوج واضح؟ زوج هذا
+
+443
+00:38:05,110 --> 00:38:11,350
+و هذا فردتين انان شمارز الآن شرط وجود الانان شمارز
+
+444
+00:38:11,350 --> 00:38:17,050
+زي ما قلنا أنه يكونيكون اربع روابط مختلفة على
+
+445
+00:38:17,050 --> 00:38:21,530
+كربونا واحدة عشان هيك دائما احنا بنعلم الكربونا
+
+446
+00:38:21,530 --> 00:38:26,490
+اللي عليهاأربع مجموعات مختلفة بنجمة وبنقول هنا في
+
+447
+00:38:26,490 --> 00:38:30,190
+عندي stereogenic center يعني مركز لل
+
+448
+00:38:30,190 --> 00:38:35,090
+stereochemistry أو chiral center أو chiral carbon
+
+449
+00:38:35,090 --> 00:38:38,950
+كله نفس الأشياء ال carbon اللي حامل أربع مجموعات
+
+450
+00:38:38,950 --> 00:38:42,690
+مختلفة شو بسميها؟ chiral carbon, chiral center,
+
+451
+00:38:42,910 --> 00:38:46,740
+stereogenic centerالان احنا حاطينلكوا هنا بعض
+
+452
+00:38:46,740 --> 00:38:49,960
+الرسومات تشوفوا اي carbon عليها اربع مجموعات
+
+453
+00:38:49,960 --> 00:38:53,840
+مختلفة اللي عليها اربع مجموعات مختلفة اللي حاطين
+
+454
+00:38:53,840 --> 00:38:59,600
+عليها نجمة يعني الجزء الاول بس carbon واحدة حاملة
+
+455
+00:38:59,600 --> 00:39:02,560
+اربع مجموعات مختلفة طبعا المبينين تلاتة الرابعة هي
+
+456
+00:39:02,560 --> 00:39:08,360
+ايش ال H و الجزء التاني نفس الاشي عليه كلور و عليه
+
+457
+00:39:08,360 --> 00:39:13,880
+مثل و عليه المجموعة الكبيرة الأخيرة و عليههذه فقط
+
+458
+00:39:13,880 --> 00:39:18,520
+الكاربون الكايرال كاربون اللي عليها كم مجموعة
+
+459
+00:39:18,520 --> 00:39:25,280
+مختلفة اربع مجموعات مختلفة نأجل هذا ال slide الان
+
+460
+00:39:25,280 --> 00:39:31,270
+كيف نحدد ال configurationالـ R و ال S أخدنا قولنا
+
+461
+00:39:31,270 --> 00:39:37,770
+أقل مجموعة بنخليها لورق و بعدين بنبدأ من الأعلى
+
+462
+00:39:37,770 --> 00:39:45,560
+للأقل للأقل و بنمشي علىإذا كان عندنا مع عقارب
+
+463
+00:39:45,560 --> 00:39:50,220
+الساعة بيكون عندي R باللاتيني rectus يعني إحنا
+
+464
+00:39:50,220 --> 00:39:54,740
+ماشيين مع عقارب الساعة أو right وإذا عندي عكس
+
+465
+00:39:54,740 --> 00:39:59,820
+عقارب الساعة بيكون عندي S sinister أو left ماشيين
+
+466
+00:39:59,820 --> 00:40:04,360
+عكس عقارب الساعة القواعد اللي بناخدها لإن نقول هذه
+
+467
+00:40:04,360 --> 00:40:08,600
+الأعلى و الأقل و الأقل أخدناها لما حددنا ال sexual
+
+468
+00:40:08,600 --> 00:40:14,370
+trance بتعتمد على ال atomicnumber وإذا أول مجموعة
+
+469
+00:40:14,370 --> 00:40:18,630
+ماحلتنيش بروح على اللي بعد هو أخدنا تفصيل كتير
+
+470
+00:40:18,630 --> 00:40:24,630
+فيها الآن هي عندكم مجموعة من الأمثلة حاطين احنا
+
+471
+00:40:24,630 --> 00:40:31,290
+لها كمساعدة لكم ال configuration ممكن نختم اليوم
+
+472
+00:40:31,290 --> 00:40:37,310
+ان نتطلع على بعض هذه الأمثلة اتطلعوا معاهإيش
+
+473
+00:40:37,310 --> 00:40:44,690
+بتلاحظوا؟ إنه أنا أقل مجموعة في المثال الأول اللي
+
+474
+00:40:44,690 --> 00:40:48,650
+هي ال H حاططها وين فوق أو تحت، إذا ال
+
+475
+00:40:48,650 --> 00:40:54,190
+configuration هيطلع مباشرة، ماعكسش، فلو بتتطلع على
+
+476
+00:40:54,190 --> 00:40:57,290
+المثال اللي فوق، أعلى مجموعة ال U بعدين ال brom،
+
+477
+00:40:57,290 --> 00:41:03,170
+بعدين ال chlorine، كيف ماشيين؟ R، الآن اتطلع على
+
+478
+00:41:03,170 --> 00:41:09,190
+المثال اللي تحت منهالـ H على الجانب إذا الجواب
+
+479
+00:41:09,190 --> 00:41:13,370
+اللي بيطلع عندى لازم أعكسه امشي و يدبرو مكلور
+
+480
+00:41:13,370 --> 00:41:22,190
+انبعينه R بكتب S خدوا المثال اللى بعد هذا المثال
+
+481
+00:41:22,190 --> 00:41:31,770
+إيش المجموعات اللى عندى عندى مثل إثل إبروم و H أقل
+
+482
+00:41:31,770 --> 00:41:37,020
+مجموعة الهيدروجينمحطوطة على الجانب إذا في نهاية
+
+483
+00:41:37,020 --> 00:41:40,900
+الجواب اللي عندي هينكس أنهي أعلى البروم ولا ال مثل
+
+484
+00:41:40,900 --> 00:41:45,060
+والإثل البروم لأن البروم هالوجي للمثل والإثل
+
+485
+00:41:45,060 --> 00:41:50,760
+كاربون في النهاية فالبروم أعلى واحدة بعد البروم
+
+486
+00:41:50,760 --> 00:41:55,040
+مين بيجي أعلى ال إثل ولا المثل ال إثل أعلى كاربون
+
+487
+00:41:55,040 --> 00:42:01,800
+و بعدها كاربون فبناء على ذلك بتكون عند بروم إثل
+
+488
+00:42:01,800 --> 00:42:11,380
+انبعيناS بكتب R لإيش؟ لأنه هذا على الجانب واضح؟ لو
+
+489
+00:42:11,380 --> 00:42:16,800
+تتطلع على .. بديش أخد أنا كل الأمثلة لكن خلّينا
+
+490
+00:42:16,800 --> 00:42:22,980
+نقول ننتهي بهذا المثال أقل
+
+491
+00:42:22,980 --> 00:42:28,060
+مجموعة الـ H الأن بعد ذلك إيش متصل عندي في ال
+
+492
+00:42:28,060 --> 00:42:35,630
+carbon؟ O و Carbonو carbon ان هو اعلى ال O بعدك
+
+493
+00:42:35,630 --> 00:42:38,910
+هذه ال carbon متصلة بتلاتة edges هذه ال carbon
+
+494
+00:42:38,910 --> 00:42:45,870
+متصلة ب O و ب O و ب CH3 هان .. هان ال carbon اللي
+
+495
+00:42:45,870 --> 00:42:52,210
+متصلة بال O اللي حملة A اذا ان هي اعلى A بناء على
+
+496
+00:42:52,210 --> 00:42:59,340
+ذلك التلتيب اللي عندى هاي واحد تنين تلاتة مبينأس
+
+497
+00:42:59,340 --> 00:43:04,340
+بكتب أ كل الأمثلة هذه بإمكانكوا بهدوء تعملوها في
+
+498
+00:43:04,340 --> 00:43:10,560
+البيت و بإمكانكوا تتحققوا من الإجابة شكرا لكم
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..13d14664446b867d0eecd1720053d362ea08e534
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_raw.srt
@@ -0,0 +1,2056 @@
+1
+00:00:09,630 --> 00:00:17,330
+اليوم موضوعنا فصل جديد و ممتع هو الفصل المعنوان
+
+2
+00:00:17,330 --> 00:00:25,020
+stereochemistry معنى stereochemistryدراسة شكل
+
+3
+00:00:25,020 --> 00:00:31,560
+الجزء في الفراغ في تلت أبعاد واضح؟ يعني دائما كلمة
+
+4
+00:00:31,560 --> 00:00:35,880
+stereo بتعني شيء بيطلع في تلت أبعاد حتى اللي
+
+5
+00:00:35,880 --> 00:00:41,300
+بتسموه ال stereo تبع الصوت بيطلع الصوت في تلت
+
+6
+00:00:41,300 --> 00:00:45,000
+أبعاد أو في كل الاتجاهات واضح؟ three-dimensional
+
+7
+00:00:45,000 --> 00:00:51,460
+هذا الحقيقة chapter ممتع
+
+8
+00:00:51,460 --> 00:00:59,400
+جداكمقدمة له .. كمقدمة له بدنا نذكر اللوحة اللي
+
+9
+00:00:59,400 --> 00:01:03,420
+مرت علينا وقولنا هتظل تتكرر علينا كتير اللي هي
+
+10
+00:01:03,420 --> 00:01:08,860
+فيها تصنيف لل isomers اللي فيها تصنيف لل isomers
+
+11
+00:01:08,860 --> 00:01:15,170
+يمكن أنا شوية صغيرة كبرتها أو قسمتها إلىجزئين
+
+12
+00:01:15,170 --> 00:01:24,630
+الجزء الفوق هذا طبعا معنى isomers هي مركبات تختلف
+
+13
+00:01:24,630 --> 00:01:31,350
+في الشكل البنائي لكن لها نفس ال molecular formula
+
+14
+00:01:31,350 --> 00:01:35,350
+الصيغة الجزائية طبعا طالما لها نفس الصيغة الجزائية
+
+15
+00:01:35,350 --> 00:01:38,510
+من باب او لا لها نفس ال empirical formula طبعا
+
+16
+00:01:38,510 --> 00:01:41,230
+تكونوا متذكرين انتوا انه لما أخدتوا الصيغة
+
+17
+00:01:41,230 --> 00:01:47,010
+الكيميائيةأخدت تلت صياغ empirical formula اللي هي
+
+18
+00:01:47,010 --> 00:01:52,450
+أبسط نسبة ال molecular formula اللي هي الأعداد
+
+19
+00:01:52,450 --> 00:01:57,890
+الحقيقية للجزء و ال structural formula كيف بيشبكوا
+
+20
+00:01:57,890 --> 00:02:04,310
+واضح يعني مثلا انا ممكن اقول ال chemical formula
+
+21
+00:02:04,310 --> 00:02:07,230
+العادية هدولة تلت أقلام لكن لما بدي structural
+
+22
+00:02:07,230 --> 00:02:11,470
+formula و بدي اعمل منهم شكل ممكن اعمله بأكتر من
+
+23
+00:02:11,470 --> 00:02:16,350
+طريقةهنا بصير في عند إيش؟ Structural formula فال
+
+24
+00:02:16,350 --> 00:02:19,730
+isomers they are as you can see different
+
+25
+00:02:19,730 --> 00:02:24,170
+compounds that have the same molecular formula،
+
+26
+00:02:24,170 --> 00:02:27,610
+اللي هو نفس ال molecular formula، but different
+
+27
+00:02:27,610 --> 00:02:32,500
+structuresthey differ in the structural formula
+
+28
+00:02:32,500 --> 00:02:40,520
+الآن بيقسموا ال isomers لنوعين أساسيين النوع الأول
+
+29
+00:02:40,520 --> 00:02:46,880
+بنسميه constitutional isomers يعني isomers مختلفة
+
+30
+00:02:46,880 --> 00:02:51,800
+في البناء أو في التكوين وعشان ايه كمان بتاخد اسم
+
+31
+00:02:51,800 --> 00:02:56,320
+تاني ال constitutional isomers نفسه بيسموها
+
+32
+00:02:56,320 --> 00:03:01,950
+structural isomersواضح فإذا قلنا constitutional
+
+33
+00:03:01,950 --> 00:03:10,150
+isomers أو قلنا structural isomers نفس المعنى they
+
+34
+00:03:10,150 --> 00:03:14,870
+differ in the bonding in the structure الان لو
+
+35
+00:03:14,870 --> 00:03:18,390
+بتكن تلاحظوا هدول ال constitutional isomers أو ال
+
+36
+00:03:18,390 --> 00:03:24,970
+structural isomers إيش تعريفهم بتلاقوا القاتلAtoms
+
+37
+00:03:24,970 --> 00:03:28,390
+are attached to one another in different ways
+
+38
+00:03:28,390 --> 00:03:33,610
+الذرات مرتبطة مع بعض البعض بطرق مختلفة يعني
+
+39
+00:03:33,610 --> 00:03:39,810
+بيختلفوا في ال bonding في الروابط واضح تماما زي ما
+
+40
+00:03:39,810 --> 00:03:43,470
+انا بدى امسك هدول الأقلام اقول في عندى أحمر أزرق
+
+41
+00:03:43,470 --> 00:03:48,010
+أسود هاني عملت إيش structure الآن ال bonding كيف
+
+42
+00:03:48,010 --> 00:03:51,530
+عندى هنا أحمر أزرق أسودأزرق ازرق ازرق ازرق ازرق
+
+43
+00:03:51,530 --> 00:04:05,290
+ازرق ازرق ازرق ازرق ازرق ازرق ازرق ازرق ازرق ازرق
+
+44
+00:04:05,800 --> 00:04:11,580
+وعاد التكوين بشكل جديد واضح من الأمثلة عليها لو
+
+45
+00:04:11,580 --> 00:04:15,820
+بتتطلع على المثال اللي موجود عندكم مثلا ال ethanol
+
+46
+00:04:15,820 --> 00:04:21,760
+و ال di-methyl ether كل جزء صيغته ال chemical
+
+47
+00:04:21,760 --> 00:04:26,260
+formula تبعته C2H6O
+
+48
+00:04:26,260 --> 00:04:32,260
+إذا هذول مشتركين في الصيغة وين الاختلاف تبعهم؟في
+
+49
+00:04:32,260 --> 00:04:36,520
+الارتباط يعني بعيدا عن الهيدروجين الجزء الأول
+
+50
+00:04:36,520 --> 00:04:41,980
+بتلاقي تركيبه carbon carbon oxygen الجزء التاني
+
+51
+00:04:41,980 --> 00:04:47,500
+بتلاقي تركيبه carbon oxygen carbon إذا هدولة they
+
+52
+00:04:47,500 --> 00:04:50,220
+differ in bonding
+
+53
+00:04:51,670 --> 00:04:54,950
+أو زي ما بتلاحظوا التعريف atoms are attached to
+
+54
+00:04:54,950 --> 00:04:58,290
+one another in different ways الذرات مرتبطة في بعض
+
+55
+00:04:58,290 --> 00:05:06,210
+البعض بطرق مختلفة هذا إنه حقيقة هو أسهل أنواع ال
+
+56
+00:05:06,210 --> 00:05:10,440
+isomersهذا النوع الـ structural isomers اللي
+
+57
+00:05:10,440 --> 00:05:16,020
+بيختلفه في مواقع الإرتباط هو أسهل أشكال ال isomers
+
+58
+00:05:16,020 --> 00:05:22,740
+يعني بنظرة بثانية بتقدروا تكتشفوا أن هذا مش زي هذا
+
+59
+00:05:23,370 --> 00:05:28,190
+واضح؟ سهل جدا ان نكتشف ال structural isomers يعني
+
+60
+00:05:28,190 --> 00:05:31,370
+مجرد ما بتطلعوا بتقولوا ان هدولة structural
+
+61
+00:05:31,370 --> 00:05:37,150
+isomers خليني اعطيكم مثال تاني تقولولي عنه انه
+
+62
+00:05:37,150 --> 00:05:40,630
+فعلا structural isomers ولا لا؟ لو تخيلتوا ان
+
+63
+00:05:40,630 --> 00:05:45,770
+عندكم بنزين وحطينا زي هيك كلور وكلور وبنزين تاني
+
+64
+00:05:45,770 --> 00:05:51,890
+وحطينا كلور وكلور هدولة الجزيين
+
+65
+00:05:55,640 --> 00:06:00,340
+Are they structural isomers؟ أكيد لأن هنا إذا
+
+66
+00:06:00,340 --> 00:06:03,300
+بتبتطلع الإرتباط، عندي chlorine، carbon، carbon،
+
+67
+00:06:03,300 --> 00:06:10,820
+chlorine، carbon، carbon، carbon، chlorine،
+
+68
+00:06:10,820 --> 00:06:10,820
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+69
+00:06:10,820 --> 00:06:10,820
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+70
+00:06:10,820 --> 00:06:12,600
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+71
+00:06:12,600 --> 00:06:12,800
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+72
+00:06:12,800 --> 00:06:12,800
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+73
+00:06:12,800 --> 00:06:16,060
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+74
+00:06:16,060 --> 00:06:16,840
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+75
+00:06:16,840 --> 00:06:16,860
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+76
+00:06:16,860 --> 00:06:16,860
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+77
+00:06:16,860 --> 00:06:16,880
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+78
+00:06:16,880 --> 00:06:16,880
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+79
+00:06:16,880 --> 00:06:16,880
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+80
+00:06:16,880 --> 00:06:19,960
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+81
+00:06:19,960 --> 00:06:20,440
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+82
+00:06:20,440 --> 00:06:20,460
+carbon، carbon، carbon، carbon، carbon، carbon،
+
+83
+00:06:24,290 --> 00:06:30,030
+ميثانول المركب التاني داي مثل إيثر إذا ال
+
+84
+00:06:30,030 --> 00:06:37,610
+structural isomers they have different names ليش؟
+
+85
+00:06:37,610 --> 00:06:41,790
+لأن ال name أو الاسم للمركب بيعبر عن .. عن
+
+86
+00:06:41,790 --> 00:06:44,530
+structure عن ذرات طالما ال structure اختلف إذا
+
+87
+00:06:44,530 --> 00:06:50,580
+الاسم اختلف نفس الاشي هنالو كنتوا بتكونوا تسموا
+
+88
+00:06:50,580 --> 00:06:56,820
+هدولة المركبين هتقولوا ortho-dichlorobenzene او
+
+89
+00:06:56,820 --> 00:07:03,240
+one two dichlorobenzene هنا tara-dichlorobenzene
+
+90
+00:07:03,240 --> 00:07:07,700
+او one four dichlorobenzene ملاحظين انتوا ان مواقع
+
+91
+00:07:07,700 --> 00:07:11,920
+الارتباط كلها اختلفت البندج اختلف هذا أبسط نوع من
+
+92
+00:07:11,920 --> 00:07:15,680
+ال isomers اللي مر علينا كتير أمثلة زيه اللي
+
+93
+00:07:15,680 --> 00:07:20,730
+بنسميها ايشStructural isomers مش هذا موضوعنا اليوم
+
+94
+00:07:20,730 --> 00:07:25,190
+مش هذا موضوعنا اليوم ايش موضوعنا احنا اليوم النوع
+
+95
+00:07:25,190 --> 00:07:30,350
+التاني من ال isomers اللي اسمه ال stereo isomers
+
+96
+00:07:30,350 --> 00:07:37,830
+ال stereo isomers شوية بغلبه بدهم عينأو يمكن في
+
+97
+00:07:37,830 --> 00:07:41,530
+أول الأشياء ما تصدقوش ان هدول الأشياء مختلفين عن
+
+98
+00:07:41,530 --> 00:07:46,230
+بعضهم البعض مكتوب فيهم atoms have the same
+
+99
+00:07:46,230 --> 00:07:50,750
+substitution or constitution عفوا the same bonding
+
+100
+00:07:50,750 --> 00:07:54,970
+لهم نفس مواقع الارتباط but different arrangement
+
+101
+00:07:54,970 --> 00:08:00,290
+in space لكن كيف شكلهم بالفراغ بختلف بس مواقع
+
+102
+00:08:00,290 --> 00:08:06,480
+ارتباطهملا تختلف، فقط بيختلفوا بإيش؟ بالشكل اللي
+
+103
+00:08:06,480 --> 00:08:12,300
+موجود في الفراغ، كيف بالفراغ بيكون شكلهم، فللوحنة
+
+104
+00:08:12,300 --> 00:08:17,620
+الأولى الناس ممكن يخربطوا بينهم، الآن جرت العادة
+
+105
+00:08:17,620 --> 00:08:21,560
+أن الواحد قبل ما يشرح هذه الظاهرة كيميائيا، هذه
+
+106
+00:08:21,560 --> 00:08:27,040
+ظاهرة حياتيةيعني موجودة في الحياة كتير قد تكونوا
+
+107
+00:08:27,040 --> 00:08:30,620
+انتبهتوا إلها وقد لا تكونوا انتبهتوا إلها بس عليها
+
+108
+00:08:30,620 --> 00:08:35,060
+الأمثلة في الحياة كثيرة لا تعد ولا تحصى أنه أشياء
+
+109
+00:08:35,060 --> 00:08:41,560
+مبينة زي بعض لكن هي حقيقة مختلفة دائما أبدا المثال
+
+110
+00:08:41,560 --> 00:08:45,320
+اللي بيبدأوا فيه وبينطلقوا منه هو ال Eden تعون
+
+111
+00:08:45,320 --> 00:08:51,840
+البني آدمهدول الأيدين الآن السؤال هدول الأيدين زي
+
+112
+00:08:51,840 --> 00:08:59,900
+بعض ولا لأ؟ ملاحظين أنتوا؟ معنى زي بعض أنه أنا
+
+113
+00:08:59,900 --> 00:09:05,820
+بقدر أحط واحدة محل التانية يعني
+
+114
+00:09:05,820 --> 00:09:09,500
+لو بقدرة جادر بنفكه هدول التنتين بنقدر نحط هذه محل
+
+115
+00:09:09,500 --> 00:09:12,240
+هذه و هذه محل هذه إيش رأيكوا؟
+
+116
+00:09:15,510 --> 00:09:18,950
+طبعا انتوا صعب عليكوا تتخيلوا انه تعوني البني ادم
+
+117
+00:09:18,950 --> 00:09:22,730
+بنفكوا لكن معظمكوا في الطفولة اذا ماكانش في الكبر
+
+118
+00:09:22,730 --> 00:09:27,130
+كمان في عندهم العرايس لصغار لما تيجوا تركبوا
+
+119
+00:09:27,130 --> 00:09:31,490
+العروسة العروسة ايدين ورجلين لما تيجوا تركبوها
+
+120
+00:09:31,490 --> 00:09:35,670
+بتحسوا انه لازم احط اليد اليمين محلها و اليد
+
+121
+00:09:35,670 --> 00:09:40,770
+الشمال محلها لو حطته بالعكس بدل ما تكون اليد ال ..
+
+122
+00:09:42,080 --> 00:09:46,180
+الـ calf تبعها بيأشر لجوه جهة الجسم لو حاطيتها
+
+123
+00:09:46,180 --> 00:09:51,720
+بالعكس بيطلع لوره واضح؟ نفس الأشياء دول الأتين إذا
+
+124
+00:09:51,720 --> 00:09:56,060
+بتطلع عليهم شبههم كبير جدا يعني لو أنا اتخيلت أنه
+
+125
+00:09:56,060 --> 00:10:00,960
+عند مرايا هذه الإيد هي صورة هذه الإيد في المرأة
+
+126
+00:10:02,180 --> 00:10:06,020
+واضح؟ صورة بعض في المرأة لكن السؤال هل يا تورا
+
+127
+00:10:06,020 --> 00:10:08,800
+هدول الأشياء اللي صورت بعض في المرأة بينطبقوا ولا
+
+128
+00:10:08,800 --> 00:10:13,380
+لأ؟ بشكل عام لما بيكون عندى شغلتين صورة بعض في
+
+129
+00:10:13,380 --> 00:10:18,540
+المرأة ممكن ينطبقوا على بعض وممكن لا ينطبقوا على
+
+130
+00:10:18,540 --> 00:10:23,980
+بعض حسب كيف شكلهم بالفرق يعني مثلا لو مسكت هدولة
+
+131
+00:10:23,980 --> 00:10:30,720
+الكورتين الخضر مثلاكبر بس مش فيهم أي إشي هذه صورة
+
+132
+00:10:30,720 --> 00:10:34,780
+هذه في المرأة الآن هدولا كل إشي فيهم symmetric
+
+133
+00:10:34,780 --> 00:10:39,180
+بشكل كبير متماثلات بينطبقوا على بعض بمعنى لو كان
+
+134
+00:10:39,180 --> 00:10:42,680
+في جالب محطوطة هذه فيه وفيه فراغات عشان تقعد فيه
+
+135
+00:10:42,680 --> 00:10:48,380
+بالراحة هذه بتقعد زيها ولا لأ؟ بينطبقوا على بعض
+
+136
+00:10:48,380 --> 00:10:55,870
+واضح؟ بينطبقوا على بعض بسهولة جداواضح؟ الآن في
+
+137
+00:10:55,870 --> 00:11:00,350
+شغلات لأ مابتنطبقش ع بعض، يعني لو تخيلتوا مثلا
+
+138
+00:11:00,350 --> 00:11:05,010
+هدول الاتنين، لو أنا كنت بدي أشيل هذه الإيد و أجي
+
+139
+00:11:05,010 --> 00:11:10,410
+أحط هذه مكانها، لاحظوا الكف وين اتجاهه هنا؟ ع جهة
+
+140
+00:11:10,410 --> 00:11:15,150
+البني آدم، لو كنت بدي أحط هذه، بدي أحطها زي هيك،
+
+141
+00:11:15,150 --> 00:11:20,730
+إيش صار في هذا الأصبع؟رايح باتجاه هذا الأصبع رايح
+
+142
+00:11:20,730 --> 00:11:24,470
+باتجاه تاني، إذا هذه الإيد و هذه الإيد بنقدر نقول
+
+143
+00:11:24,470 --> 00:11:32,970
+عنهم صورة بعض في المرأة لكنها غير متطابقة صورة بعض
+
+144
+00:11:32,970 --> 00:11:39,450
+في المرأة لكنها غير متطابقة معنى صورة بعض في
+
+145
+00:11:39,450 --> 00:11:45,940
+المرأة mirror imagesمعنى غير متطابقة non-super
+
+146
+00:11:45,940 --> 00:11:51,720
+-imposable متطابق non-super-imposable غير متطابق
+
+147
+00:11:51,720 --> 00:11:56,880
+إذن إحنا بنقدر الآن نقول إن هدولة الـ two hands
+
+148
+00:11:56,880 --> 00:12:04,580
+الـ hands الإيدين non
+
+149
+00:12:04,580 --> 00:12:07,620
+-super
+
+150
+00:12:07,620 --> 00:12:08,800
+-imposable
+
+151
+00:12:13,170 --> 00:12:19,950
+mirror images يعني
+
+152
+00:12:19,950 --> 00:12:26,110
+صورة بعض في المرأة ولكنها غير متطابقةواضح؟ الان
+
+153
+00:12:26,110 --> 00:12:32,590
+هذا الاختلاف بالمناسبة هو اختلاف بس بالشكل الفراغي
+
+154
+00:12:32,590 --> 00:12:36,870
+بمعنى لو كنا بدنا نيجي مثلا على خاصية زي الكتلة و
+
+155
+00:12:36,870 --> 00:12:40,610
+أخدنا الإيد هادي و الإيد هادي هلاحظ إنهم نفس
+
+156
+00:12:40,610 --> 00:12:44,230
+الكتلة كإن أنا بدأت أجرب من الكيميا يعني لما بقول
+
+157
+00:12:44,230 --> 00:12:48,690
+the same molecular formula نفس الصيغة الجزائية
+
+158
+00:12:48,690 --> 00:12:51,330
+معناه the same molecular formula the same
+
+159
+00:12:51,330 --> 00:12:54,800
+molecular weightنفس الوزن، بس الاختلاف وين بده
+
+160
+00:12:54,800 --> 00:12:59,260
+يكون؟ بالشكل الفراغي الآن هذه الظاهرة، ظاهرة
+
+161
+00:12:59,260 --> 00:13:03,120
+الإيدين اللي بيكونوا صورة بعض في المراه و لكنها
+
+162
+00:13:03,120 --> 00:13:07,920
+غير متطابقة بيسموها ظاهرة ال handedness اللي هي
+
+163
+00:13:07,920 --> 00:13:11,700
+ظاهرة يعني مثل الإيدين handedness
+
+164
+00:13:17,380 --> 00:13:20,520
+إذا لو قلنا ظاهرة ال handedness أي شغل أصورة بعض
+
+165
+00:13:20,520 --> 00:13:25,640
+في المرأة غير متطابقة بتكون زي هيك الآن لو إجيتوا
+
+166
+00:13:25,640 --> 00:13:29,280
+تعطوا أمثلة .. لو إجيتوا تعطوا أمثلة على هذا
+
+167
+00:13:29,280 --> 00:13:35,000
+الموضوع من الحياة أمثلة كتيرة مين تعطينا مثل غير
+
+168
+00:13:35,000 --> 00:13:42,540
+الإيدين؟ خلصنا من الإيدين بنفع
+
+169
+00:13:42,540 --> 00:13:50,600
+رجلين؟ بنفع رجلينبنفع ما يوضع في الرجلين؟ الأحذية
+
+170
+00:13:50,600 --> 00:13:57,640
+الحذاء شوية كبير يعني معظمكم بتميزوه بس لاحظوا
+
+171
+00:13:57,640 --> 00:14:04,340
+دائما عندكم مشكلة مع الطفل الصغير بن سنة و سنتين
+
+172
+00:14:04,340 --> 00:14:09,580
+أكم مرة بتكونوا تقولوله اليمين لشمال بدلهم بياخدوا
+
+173
+00:14:09,580 --> 00:14:15,290
+الطفل ل 4 و 5 سنين و هو مش قادر يحس الفرقبين اللي
+
+174
+00:14:15,290 --> 00:14:19,710
+هو فردتي الحذاء ليش؟ لأنه بنطبق عليهم نفس الفكرة
+
+175
+00:14:19,710 --> 00:14:25,550
+هم صورة بعض في المرأة غير متطابقة فعشان يفهمها
+
+176
+00:14:25,550 --> 00:14:29,850
+الطفل قداش بده هذه الظاهرة، بده أربع أو خمس سنين
+
+177
+00:14:29,850 --> 00:14:37,030
+الأصعب منها الجرابين تلت ارباع الناس بخرف طينهم بس
+
+178
+00:14:37,030 --> 00:14:41,150
+لو بدكوا تيجيوا للحقيقة برضه فيهم شمال ويمين
+
+179
+00:14:41,150 --> 00:14:48,920
+الـQuantatتعون الأيد فيهم شمال ويمين الودنتين
+
+180
+00:14:48,920 --> 00:14:54,460
+اتخيلوا لو واحد هيك وودنتين ووجعه يعني اتجمده في
+
+181
+00:14:54,460 --> 00:14:58,360
+بارد شديد في روسيا ووجعه الجراح بده يربطله إياهم
+
+182
+00:14:58,360 --> 00:15:04,420
+لازم يكون عنده فكرة إن هدولة فيهم شمال ويمين واضح؟
+
+183
+00:15:04,420 --> 00:15:08,780
+الكلام وين بتكرر؟ عند الناس العاديين وبيفهموا هذه
+
+184
+00:15:08,780 --> 00:15:14,270
+الظاهرة كويس لو الباب تبع السيارة خرببروح الواحد
+
+185
+00:15:14,270 --> 00:15:18,690
+بيشتري باب بيقول لو سمحت في عندك باب مثلا Subaru
+
+186
+00:15:18,690 --> 00:15:23,150
+الباب اللي قداماني أول كلمة بيقولوا إياها يمين ولا
+
+187
+00:15:23,150 --> 00:15:27,070
+شمال لأن البابين تعون السيارة صورت بعض في المرأة
+
+188
+00:15:27,070 --> 00:15:32,410
+غير متطابقة واضح؟ فكل إشي قاعدين إحنا نشتغل عليه
+
+189
+00:15:32,410 --> 00:15:37,910
+الآن تخيلوا التعون البصريات الطبية لو إجوا يركبوا
+
+190
+00:15:37,910 --> 00:15:43,870
+هذه النضارةوكانت قطع هذه الأيد و هذه الأيد صورت
+
+191
+00:15:43,870 --> 00:15:48,710
+بعض في المرأة لكنها غير متطابقة هذا الجسم الصغير
+
+192
+00:15:48,710 --> 00:15:51,190
+اللي هنا وهذا الجسم الصغير اللي هنا صورت بعض في
+
+193
+00:15:51,190 --> 00:15:54,750
+المرأة لو انحط بالعكس بيطلع واحد لفوق واحد لتحت
+
+194
+00:15:54,750 --> 00:16:00,050
+غير متطابق هذه العدسة و هذه العدسة صورت بعض في
+
+195
+00:16:00,050 --> 00:16:03,570
+المرأة ولكنها غير متطابقة الآن اللي بيشتغل في
+
+196
+00:16:03,570 --> 00:16:07,970
+المجال لازم ينتبه لكل هذهينتبه لكل هذه الأمور كل
+
+197
+00:16:07,970 --> 00:16:13,330
+هذولا بيخضعوا لقاعدة إيش ال handedness الان الكلام
+
+198
+00:16:13,330 --> 00:16:19,150
+نفسه موجود في الكيميا الكلام نفسه موجود في الكيميا
+
+199
+00:16:19,150 --> 00:16:24,030
+و اكتشف بيصير موجود في الكيميا بيصير موجود في
+
+200
+00:16:24,030 --> 00:16:30,570
+الكيميا إذا كان عنده حول ذرة الكربون أربع مجموعات
+
+201
+00:16:30,570 --> 00:16:37,530
+مختلفةإذن الشرط عندى عشان يكون موجود في الكيمية
+
+202
+00:16:37,530 --> 00:16:42,210
+الكربون ما يبتعمل كام رابطة؟ أربعة بدوا يكونوا
+
+203
+00:16:42,210 --> 00:16:47,150
+الأربع مجموعات اللى موجودين على الكربون أربع
+
+204
+00:16:47,150 --> 00:16:53,190
+مجموعات مختلفة وقتها بيصير الجزء و صورته في
+
+205
+00:16:53,190 --> 00:16:59,510
+المرايا غير متطابقين الآن خلينا نعمل هذا الكلام
+
+206
+00:16:59,510 --> 00:17:05,210
+بهدوء باستعمالالموديلز okay بدنا نعمل جزيق هيكربون
+
+207
+00:17:05,210 --> 00:17:12,450
+okay ونحط عليه أربع ذرات خلينا نقول بدنا نحط عليه
+
+208
+00:17:12,450 --> 00:17:19,030
+يود اليود إيش لونه أزرق هيحطين هذه الزرقة تعبيرا
+
+209
+00:17:19,030 --> 00:17:26,790
+عن اليود وبدنا نحط عليه بروم البروم إيش لونه لا
+
+210
+00:17:26,790 --> 00:17:32,720
+بردجان البرومالبروم أحمر على برتقالي برتقالي
+
+211
+00:17:32,720 --> 00:17:36,900
+البروم برتقالي محلول البرومين لما بتعملوا تجربة
+
+212
+00:17:36,900 --> 00:17:40,560
+double bond و بيختفي لونه بيختفي من البرتقالي إلى
+
+213
+00:17:40,560 --> 00:17:45,720
+عديم اللون البروم برتقالي مظبوط ولا لأ الchlor
+
+214
+00:17:45,720 --> 00:17:51,280
+أخضر أخضر على أصفر إذا احفظوا اليوم الألوان هذا
+
+215
+00:17:51,280 --> 00:17:56,420
+الأزرق تعبير عن إيش يوت والبرتقالي البروم والأخضر
+
+216
+00:17:56,420 --> 00:18:02,690
+الchlor هذه السكنية نعتبرها هيدروجينOkay؟ الان يا
+
+217
+00:18:02,690 --> 00:18:09,990
+تورا لو انا اجيت اعملت لو انا اجيت اعملت صورة لهذا
+
+218
+00:18:09,990 --> 00:18:16,470
+الجزء في المرأة حطيت هنا hydrogen, brom, iod,
+
+219
+00:18:17,050 --> 00:18:21,530
+chlorine هاي هدول التينين صورة بعض في المرأة ولا
+
+220
+00:18:21,530 --> 00:18:26,790
+لأ؟ الان يا تورا هدول التينين بنطبقوا على بعض ولا
+
+221
+00:18:26,790 --> 00:18:33,060
+لأ؟واضح؟ انجرب معناه بنطبقوا على بعض كل ذرة بده
+
+222
+00:18:33,060 --> 00:18:37,840
+تيجي مكان التاني لو إجينا نجرب هنا حطينا البردجاني
+
+223
+00:18:37,840 --> 00:18:43,820
+على البردجاني البنة على البنة إيش بتلاحظوا؟ الأخضر
+
+224
+00:18:43,820 --> 00:18:48,660
+والأزرق مايجيوش على بعض لو بدنا نجرب نقول طب بنظبط
+
+225
+00:18:48,660 --> 00:18:54,340
+الأخضر والأزرق مش مشكلة نحاول نخلي الأزرق والأخضر
+
+226
+00:18:54,340 --> 00:18:58,060
+ييجوا على بعض هاي هاي حلينا المشكلة أزرق و أزرق
+
+227
+00:18:59,060 --> 00:19:07,740
+أخضر و أخضر صار البرتقالي إذا هدولة التنين حقيقة
+
+228
+00:19:07,740 --> 00:19:12,140
+غير مطابقين على بعضهم البعض رغم شدة التشابه اللي
+
+229
+00:19:12,140 --> 00:19:16,080
+بينهم و رغم إنهم صورة بعض في المرأة إذا هنا تتكرر
+
+230
+00:19:16,080 --> 00:19:22,060
+ظاهرة إيش ال handedness إن هدولة زي ال hands واضح؟
+
+231
+00:19:22,450 --> 00:19:26,890
+بالمناسبة كل الأشياء اللي فيها هذه الظاهرة بتكون
+
+232
+00:19:26,890 --> 00:19:30,510
+stereo isomers بمعنى نفس الذرات نفس ال molecular
+
+233
+00:19:30,510 --> 00:19:35,130
+weight كله نفس الاشياء لكن الإختلاف هنا وين بشكل
+
+234
+00:19:35,130 --> 00:19:40,060
+الفراغة بنسميهم enantiomersواضح؟ عشان هيك ال
+
+235
+00:19:40,060 --> 00:19:43,940
+stereo isomers بيقسموا إلى نوعين النوع اللي بنبدأ
+
+236
+00:19:43,940 --> 00:19:47,340
+في هذه المحاضرة و جزء من البعدة اسمه enantiomers و
+
+237
+00:19:47,340 --> 00:19:51,960
+النوع التاني بعدين بنتعرف عليه اسمه the stereomers
+
+238
+00:19:51,960 --> 00:19:56,700
+اليوم احنا بالإيش؟ بال enantiomers ال enantiomers
+
+239
+00:19:56,700 --> 00:20:00,880
+they are non sober invisible mirror image
+
+240
+00:20:00,880 --> 00:20:07,850
+stereoisomersزي شغل الإيدين هما Stereoisomers صورة
+
+241
+00:20:07,850 --> 00:20:12,530
+بعض في المرأة غير متطابقة باللغة الإنجليزية ببساطة
+
+242
+00:20:12,530 --> 00:20:16,650
+إيش بنقول ال Enosomers؟ none, super, imposible
+
+243
+00:20:16,650 --> 00:20:20,410
+يعني غير متطابقة mirror image stereoisomers صورة
+
+244
+00:20:20,410 --> 00:20:29,290
+بعض في المرأة ولكنها غير متطابقة مظبوط ولا لأ؟ مين
+
+245
+00:20:29,290 --> 00:20:35,000
+تعرفيلنا إياهم؟ إيش هما ال Enosomers؟تفضلي ..
+
+246
+00:20:35,000 --> 00:20:40,640
+تفضلي .. اه حاضر .. اه تفضلي .. non super .. non
+
+247
+00:20:40,640 --> 00:20:46,240
+super .. imposible .. non super imposible .. non
+
+248
+00:20:46,240 --> 00:20:47,940
+super imposible mirror image .. non super
+
+249
+00:20:47,940 --> 00:20:49,760
+imposible mirror image .. non super imposible
+
+250
+00:20:49,760 --> 00:20:50,040
+mirror image .. non super imposible mirror image
+
+251
+00:20:50,040 --> 00:20:50,040
+.. non super imposible mirror image .. non super
+
+252
+00:20:50,040 --> 00:20:50,040
+imposible mirror image .. non super imposible
+
+253
+00:20:50,040 --> 00:20:50,040
+mirror image .. non super imposible mirror image
+
+254
+00:20:50,040 --> 00:20:50,040
+.. non super imposible mirror image .. non super
+
+255
+00:20:50,040 --> 00:20:50,140
+imposible mirror image .. non super imposible
+
+256
+00:20:50,140 --> 00:20:50,560
+mirror image .. non super imposible mirror image
+
+257
+00:20:50,560 --> 00:20:50,680
+.. non super imposible mirror image .. non super
+
+258
+00:20:50,680 --> 00:20:50,780
+imposible mirror image .. non super imposible
+
+259
+00:20:50,780 --> 00:20:50,780
+mirror image .. non super imposible mirror image
+
+260
+00:20:50,780 --> 00:20:50,780
+.. non super imposible mirror image .. non super
+
+261
+00:20:50,780 --> 00:20:51,140
+imposible mirror image .. non super imposible
+
+262
+00:20:51,140 --> 00:20:51,680
+mirror image .. non super imposible mirror image
+
+263
+00:20:51,680 --> 00:20:51,680
+.. non super imposible mirror image .. non super
+
+264
+00:20:51,680 --> 00:20:52,960
+imposible mirror image .. non super imposible
+
+265
+00:20:52,960 --> 00:20:55,620
+mirror image .. non super imposible mirror image
+
+266
+00:20:55,620 --> 00:20:58,040
+.. non super imposible mirror image .. non super
+
+267
+00:20:58,040 --> 00:21:02,780
+imposible mirror image .. non super imposible
+
+268
+00:21:02,780 --> 00:21:03,960
+mirror
+
+269
+00:21:07,430 --> 00:21:12,350
+آخر الحصة بدنا نعطيها إياه، ماشي الحال ولا لأ؟ ها
+
+270
+00:21:12,350 --> 00:21:16,910
+احنا أقولها لك، بدنا نعطيك إياه، الآن لو أجيت
+
+271
+00:21:16,910 --> 00:21:23,730
+سألتكم، في شرط عشان نعطيها إياه، عارفين شو هو
+
+272
+00:21:23,730 --> 00:21:27,290
+الشرط؟ إنها تحلف ليمين أي واحد اللي قلت لها بده
+
+273
+00:21:27,290 --> 00:21:27,850
+أعطيك إياه
+
+274
+00:21:32,320 --> 00:21:37,820
+لأ، يمين رسمي، مش تخميني أنه واحد فيهم اللي أنا
+
+275
+00:21:37,820 --> 00:21:43,180
+قلت لها بتعطيك إياه بثقة مائة في المائة هل تستطيع
+
+276
+00:21:43,180 --> 00:21:51,200
+أن تجيب؟ خلاص، راحت عليها الجائزة، مشكلة إذا أنا
+
+277
+00:21:51,200 --> 00:21:55,340
+بعد ما شُفت هدول اللي فيهم تشابه كبير صرت عندي
+
+278
+00:21:55,340 --> 00:22:00,260
+مشكلة جديدة إن كيف بدي أميزهم عن بعض؟عشان بعد شوية
+
+279
+00:22:00,260 --> 00:22:03,540
+لما تقول أبنان أعطيك إياها تتطلع، تقول خلاص، أعرف
+
+280
+00:22:03,540 --> 00:22:09,400
+أنا اللي بدي أاخده، واضح؟ إذا بيصير السؤال كيف بدي
+
+281
+00:22:09,400 --> 00:22:12,520
+أميز هذا عن هذا؟ أنا هلجأت هذا ماسكه بالإيدي
+
+282
+00:22:12,520 --> 00:22:15,360
+اليمين و هذا بالإيشمال؟ لو إن لفتك شوية و رجعت
+
+283
+00:22:15,360 --> 00:22:20,470
+ماسكهم، شو بدي أعرفكم؟كيف بدي اميزهم عن بعض؟ بس زي
+
+284
+00:22:20,470 --> 00:22:24,250
+ما انا بقول انه في بينهم نوع من الاختلاف ماانطبقوش
+
+285
+00:22:24,250 --> 00:22:27,990
+على بعض، اذا لازم يكون عنده القدرة على اني اميزهم
+
+286
+00:22:27,990 --> 00:22:33,550
+عن بعض، الان التمييز تبعهم عن بعض سهل، اتخيلوا
+
+287
+00:22:33,550 --> 00:22:38,200
+انهم سيكتوا اي واحدبدي اياكوا اترطبوا الذرات
+
+288
+00:22:38,200 --> 00:22:41,760
+تبعونه أولويات من الأعلى في الـ atomic weight
+
+289
+00:22:41,760 --> 00:22:48,060
+للأقل للأقل للأقل زي ما عملنا لما كنا ناخد الـ CIS
+
+290
+00:22:48,060 --> 00:22:52,360
+والـ Trans والـ Z والـEI زمارز متذاكرين هم ولا لأ؟
+
+291
+00:22:52,360 --> 00:22:56,900
+الآن احنا الأربع ذرات اللي عندنا لو تتذكروا الجدول
+
+292
+00:22:56,900 --> 00:23:04,150
+الدوري كل شيء كله كان عندي floor floor floorيهود
+
+293
+00:23:04,150 --> 00:23:10,350
+والهيدروجين الأقل واحد إذا أي مجموعة فيهم الأقل
+
+294
+00:23:10,350 --> 00:23:15,690
+الهيدروجين بعد هيك لو بدى أتحرك من الأكبر إلى
+
+295
+00:23:15,690 --> 00:23:23,090
+الأصغر أنه أعلى واحد بعده لبروم بعده لكلوب الآن
+
+296
+00:23:23,090 --> 00:23:27,890
+عشان أميزهم بمسك الجزيء بمسك الجزيء بخل المجموعة
+
+297
+00:23:27,890 --> 00:23:34,210
+الأقل الخلفهيتفقنا الهيدروجين للخلف، الآن بقاجي
+
+298
+00:23:34,210 --> 00:23:41,350
+أتحرك من الأعلى للأقل للأقل، وين الأعلى؟ اليود،
+
+299
+00:23:41,350 --> 00:23:46,910
+الأقل منه؟ البروم، الأقل منه؟ الكلور، الأقل منه؟
+
+300
+00:23:46,910 --> 00:23:47,050
+الكلور، الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+301
+00:23:47,050 --> 00:23:55,590
+الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+302
+00:23:55,590 --> 00:23:56,990
+الأقل منه؟ الكلور، الأقل منه؟ الكلور، الأقل منه؟
+
+303
+00:23:56,990 --> 00:23:57,510
+الكلور، الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+304
+00:23:57,510 --> 00:23:57,510
+الأقل منه؟ الكلور، الأقل منه؟ الكلور، الأقل منه؟
+
+305
+00:23:57,510 --> 00:23:57,510
+الكلور، الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+306
+00:23:57,510 --> 00:24:03,150
+الأقل منه؟ اليطلع زيه، خلّينا نمسك التاني، خلّينا
+
+307
+00:24:03,150 --> 00:24:08,610
+أقل مجموعة الهيدروجين للخلف، وبدأ اتحرك من الأعلى
+
+308
+00:24:08,610 --> 00:24:16,990
+للأقل اليود لبروم لكلور، مع قارب الساعة، إذا انا
+
+309
+00:24:16,990 --> 00:24:21,880
+اقدرت أحصل الاختلاف اللي بينهمكتير تحصل الاختلاف
+
+310
+00:24:21,880 --> 00:24:25,420
+اللي بينهم انه انا لما بحطه مبادية معينة بحس انه
+
+311
+00:24:25,420 --> 00:24:29,460
+أقل مجموعة للخلف و بعدين بنتقل من الأعلى للأقل
+
+312
+00:24:29,460 --> 00:24:37,540
+للأقل اما ان اتحرك مع عقارب الساعة او اتحرك عكس
+
+313
+00:24:37,540 --> 00:24:44,160
+عقارب الساعة الان اذا تحركت مع عقارب الساعة باعطي
+
+314
+00:24:44,160 --> 00:24:49,980
+للجزء الرمز R R جاية من ايش؟ من اليمين باللاتيني
+
+315
+00:24:50,990 --> 00:24:57,650
+بعطي إيش الرمز؟ R إذا تحركت مع عقارب الساعة بعطي R
+
+316
+00:24:57,650 --> 00:25:04,570
+إذا تحركت عكس عقارب الساعة بعطي S هذه ال S بس
+
+317
+00:25:04,570 --> 00:25:08,750
+مقدمة لكن لو إجيت الآن قولت أنا بدي أسمي هذا
+
+318
+00:25:08,750 --> 00:25:14,110
+المركب كاملاً هذا عبارة عن Carbon واحدة إذا هو
+
+319
+00:25:14,110 --> 00:25:20,570
+مشتقة Methaneالكربل الواحدة مشتقة مثين عليها تلت
+
+320
+00:25:20,570 --> 00:25:26,370
+مجموعات إبروم و كلور و أيود حسب الترتيب ال
+
+321
+00:25:26,370 --> 00:25:33,830
+alphabetical هذا المركب اسمه إبرومو إكلورو أيودو
+
+322
+00:25:33,830 --> 00:25:40,660
+مثينفي خلاف عليها؟ لأ ابدا ابرومو اكلورو ايودو
+
+323
+00:25:40,660 --> 00:25:45,260
+ميثين هاي من ناحية الذرات الآن لو اجيت للمركب
+
+324
+00:25:45,260 --> 00:25:50,360
+التاني ايش اسمه؟ نفس الاشي لاحظ هنا لأنهم متحدين
+
+325
+00:25:50,360 --> 00:25:55,260
+في الارتباط و في عدد الذراتabromo-chloro
+
+326
+00:25:55,260 --> 00:26:00,040
+-iodomethane إذا الإسم اللي بيحدد الأنواع الذرات
+
+327
+00:26:00,040 --> 00:26:04,320
+ومواقعها مختلفش بين هذا و هذا هذا abromo-chloro
+
+328
+00:26:04,320 --> 00:26:10,240
+-iodomethane وهذا abromo-chloro-iodomethane مافيش
+
+329
+00:26:10,240 --> 00:26:15,140
+بينهم اختلاف هوين الإختلاف بدي أبينه أن أحط بادئة
+
+330
+00:26:15,140 --> 00:26:19,160
+اتميز ليهم زي تماما حوالين ال double bond كنا نحط
+
+331
+00:26:19,160 --> 00:26:27,140
+البادئةSes و Trans أو انعبر عنهم ب Z و E الان هذا
+
+332
+00:26:27,140 --> 00:26:31,360
+اتطلع عليه مرة تانية اتذكر واحد اتنين تلاتة هذا
+
+333
+00:26:31,360 --> 00:26:36,540
+بنحط قدامه حرف ال S capital S بين قوسين بيصير S
+
+334
+00:26:36,540 --> 00:26:39,680
+-bromochloroiodomethane
+
+335
+00:26:39,680 --> 00:26:46,280
+وهذا بيصير R-bromochloroiodomethane
+
+336
+00:26:47,190 --> 00:26:51,190
+زي تماما ما كنتوا تقولوا اسم two بيوتين مشترك two
+
+337
+00:26:51,190 --> 00:26:56,090
+بيوتين و two بيوتين بإيش بنفرجهم عن بعض هذا بنحطله
+
+338
+00:26:56,090 --> 00:27:00,530
+بادئة cis هذا بنحطله بادئة trans الآن في حالة هدول
+
+339
+00:27:00,530 --> 00:27:05,210
+المراكبات اللي احنا بنسميهم enantiomers بنحط إيش
+
+340
+00:27:05,210 --> 00:27:10,790
+البادئة؟ R و S اللي مع عقارب الساعة R اللي ضد
+
+341
+00:27:10,790 --> 00:27:16,550
+عقارب الساعة S واضح؟الان هذا الكلام انا بتايعني
+
+342
+00:27:16,550 --> 00:27:21,290
+صرته انتوا أتقنتوه من خلال انه احنا مسكين الجزائر
+
+343
+00:27:21,290 --> 00:27:26,130
+لكن الإشكالية انه احنا لو بدنا نيجي نسألكوا حقيقة
+
+344
+00:27:26,130 --> 00:27:32,250
+في الامتحان ما بنخليكوا مش تمسكوا الجزائر بنرسملكم
+
+345
+00:27:33,930 --> 00:27:37,550
+نرسملكم على اللوح أو على الورقة و بنقولكوا حددونا
+
+346
+00:27:37,550 --> 00:27:42,890
+هذا المركب R ولا S إذا بصير سؤالي كيف بدي أحدد هذا
+
+347
+00:27:42,890 --> 00:27:47,790
+R ولا S لما أكون أنا راسمه خليني أاخد واحد منهم
+
+348
+00:27:47,790 --> 00:27:52,870
+وأتأكد منه في الأول بالشكل العام هل هو R ولا S هذا
+
+349
+00:27:52,870 --> 00:28:00,750
+اللي أنا ماسكه، شو هو؟ يود؟ إبروم؟ إكلور؟ هذا R
+
+350
+00:28:00,750 --> 00:28:06,800
+خلاص ال Sخلصت منه بديش أشوفه إذا أنا اللي ماسكه
+
+351
+00:28:06,800 --> 00:28:11,260
+يعني قادر أشوفه بالظبط أنه R ولا لأ؟ قادر أشوفه
+
+352
+00:28:11,260 --> 00:28:16,880
+أنه R بدي أرجع أرسمه على اللوح الآن أنا بإمكاني
+
+353
+00:28:16,880 --> 00:28:20,000
+أرسمه طرق مختلفة طبعا تكونوا أنتوا متذكري ان احنا
+
+354
+00:28:20,000 --> 00:28:24,460
+اتفقنا الجزء حوالين ال carbon نقول رابطتين زي هيك
+
+355
+00:28:24,460 --> 00:28:30,460
+للأمام و تنتين للخلف بنرسمه على شكل cross بس
+
+356
+00:28:30,460 --> 00:28:35,030
+المفهوم أن الويجيه أفقياتللأمام هيك رايحين و اللي
+
+357
+00:28:35,030 --> 00:28:40,870
+بيجوا رأسيات رايحين لوين؟ للخلف الآن يا تورا لو
+
+358
+00:28:40,870 --> 00:28:50,610
+هذا الجزء اجينا مسكناه زي هيك ممكن نرسمه زي هيك؟
+
+359
+00:28:50,610 --> 00:29:00,470
+إيش بدنا نحط هنا؟ claw هنا إبروم هنا هنا
+
+360
+00:29:02,270 --> 00:29:06,090
+ممكن نجرب نمسكه بطريقة تانية، حد مش ممنعنا كيف
+
+361
+00:29:06,090 --> 00:29:11,770
+نمسكه، أنا بمسكه بمليون طريقة، كويس؟ لكن لحظة أنا
+
+362
+00:29:11,770 --> 00:29:16,290
+ماسك جزيقه برسم يعني، المفروض أنه مايتغيرش، ايش
+
+363
+00:29:16,290 --> 00:29:21,270
+أنا بضحك؟ هاي الدرجان، كلاو، كلاو، كلاو، كلاو،
+
+364
+00:29:21,270 --> 00:29:23,090
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+365
+00:29:23,090 --> 00:29:25,170
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+366
+00:29:25,170 --> 00:29:25,770
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+367
+00:29:25,770 --> 00:29:31,290
+كلاو، كلاو،
+
+368
+00:29:31,290 --> 00:29:31,290
+كلاو، كلا
+
+369
+00:29:39,820 --> 00:29:55,240
+ممكن أمسكه بطريقة رابعة هذا
+
+370
+00:29:55,240 --> 00:29:59,080
+كله أرسم لنفس الجذيل يعني الجذيل اللي أنا مازكه R
+
+371
+00:29:59,080 --> 00:30:05,280
+ولا S إذا أتوا مش متأكدين لسه أتأكدواR U دي بروم
+
+372
+00:30:05,280 --> 00:30:09,300
+نيجي
+
+373
+00:30:09,300 --> 00:30:14,080
+على اللوح احنا رسمنا ال R بطرق مختلفة انحدد اقل
+
+374
+00:30:14,080 --> 00:30:24,060
+مجموعة اقل مجموعة و
+
+375
+00:30:24,060 --> 00:30:28,700
+بعدين نيجي نتحرك من الأعلى للأقل للأقل و نشوف ايش
+
+376
+00:30:28,700 --> 00:30:35,230
+اللي بيطلع عندنا اذا اتحركنا نقع لوحدةيود بروم
+
+377
+00:30:35,230 --> 00:30:38,630
+بكلور
+
+378
+00:30:38,630 --> 00:30:43,410
+هينا ماشي هيك كيف أنا متحرك مع قرب الساعة اذا هذا
+
+379
+00:30:43,410 --> 00:30:48,970
+المركب R في عندي مشكلة زي ما بقينا على راسنا قصة
+
+380
+00:30:48,970 --> 00:30:54,950
+سهلة جدا نيجي هنا نتطلع كمان مرة و الأعلى واحدة
+
+381
+00:30:54,950 --> 00:31:01,030
+بعدها بعدها كيف
+
+382
+00:31:01,030 --> 00:31:06,960
+أنا متحركمع القرن الساعة، إذا هذا R نيجي على
+
+383
+00:31:06,960 --> 00:31:12,480
+المركب اللي بعده يود،
+
+384
+00:31:12,480 --> 00:31:20,020
+إبروم، حينيكا، إفلون، كيف صارت أتحرك؟ صار عندي
+
+385
+00:31:20,020 --> 00:31:23,840
+مشكلة، طب أنا اللي ماسكه راسمه R، الاسم، حطناه
+
+386
+00:31:23,840 --> 00:31:27,320
+بعيد عنه لحظة و أنا صار عندي مشكلة، تشوفها بتتكرر
+
+387
+00:31:27,320 --> 00:31:36,220
+ولا لأ؟ اه، لو يقولنا أشهر على حاجةبعدها بروم
+
+388
+00:31:36,220 --> 00:31:44,320
+بعدها كيف اتحركاني؟ أسقر بالساعة هل المركب صار S؟
+
+389
+00:31:44,320 --> 00:31:48,420
+انا ماسك و قاعد برسم و ليش صار عندى هذا التناقض
+
+390
+00:31:48,420 --> 00:31:53,960
+واضح؟ ليش صار عندى هذا التناقض إذا ابتلقوا نظرة
+
+391
+00:31:53,960 --> 00:31:59,820
+على الأربع رسمات كصورة كلية بتلاحظوا في الرسمة
+
+392
+00:31:59,820 --> 00:32:07,800
+الأولى و التانيةأقل مجموعة كانت مرسومة فوق أو تحت،
+
+393
+00:32:07,800 --> 00:32:15,260
+فوق أو تحت بمنطق الرسم، إيش معناه للخلف؟ واضح؟
+
+394
+00:32:15,260 --> 00:32:20,700
+يعني كأنه لو أنا ماسك زي هيك الجزاءهذه المجموعة
+
+395
+00:32:20,700 --> 00:32:25,180
+وين بتكون دائما اللي فوق وتحت؟ للخلف وانا الشرط
+
+396
+00:32:25,180 --> 00:32:31,100
+عندي أن تكون المجموعة للخلف ولذلك ال configuration
+
+397
+00:32:31,100 --> 00:32:33,900
+هذا بنسميه ال configuration تحديد ال R و ال S
+
+398
+00:32:33,900 --> 00:32:38,660
+بنسميه ال configuration طلع صحيح لأنه أقل مجموعة
+
+399
+00:32:38,660 --> 00:32:44,300
+موجودة أساسا للخلف بينما لو إجيتوا و طلعتوا على
+
+400
+00:32:44,300 --> 00:32:49,060
+واحد من هدول خلينا ناخد هذا المركب اللي كان زي ذلك
+
+401
+00:32:50,440 --> 00:32:56,280
+هذا هو بالظبط و لا لأ؟ شايفينه
+
+402
+00:32:56,280 --> 00:33:04,380
+اقلوم اقلوم اكتشوف الان هينماسكوا زي هيك هتبدوا
+
+403
+00:33:04,380 --> 00:33:07,800
+تلاحظوا انه في تناقض من عندكم امشولي من الأعلى
+
+404
+00:33:07,800 --> 00:33:15,480
+للأقل شوفوا ليه كيف مبين اقلوم اقلوم اكتشوف
+
+405
+00:33:16,850 --> 00:33:21,910
+انبين عندكم S، الآن احنا بالنسبة لي انا الوضع
+
+406
+00:33:21,910 --> 00:33:29,330
+مختلف، انا بطلع يود، ابروم، اكلور، انا شايفه R،
+
+407
+00:33:29,330 --> 00:33:34,410
+انتوا شايفينه؟ S، مين اللي بشوف صاحب؟ لأ دايما
+
+408
+00:33:34,410 --> 00:33:41,100
+الأستاذالأستاذ ليش أنا شايفه R كما هو في الحقيقة و
+
+409
+00:33:41,100 --> 00:33:46,920
+أنتوا شايفينه S لأن أنا مكان الوقوف تبعي خلّيت ال
+
+410
+00:33:46,920 --> 00:33:53,060
+H للخلف بالنسبة لي وهذا شرط تحديد ال configuration
+
+411
+00:33:53,060 --> 00:33:57,080
+قلنا لك أقل مجموعة أين يجب أن تكون للخلف الآن لما
+
+412
+00:33:57,080 --> 00:34:02,180
+رسمت على الجنب هي للأمام إذا المجموعة للأمام و
+
+413
+00:34:02,180 --> 00:34:05,200
+أنتوا بتتطلعوا من قدام طلع عندكم ال configuration
+
+414
+00:34:05,200 --> 00:34:09,540
+فيهأشكالية عشان كذا ال configuration لو كنتوا
+
+415
+00:34:09,540 --> 00:34:12,500
+بتكونوا تشوفوه صح المفروض تتخيلوا ان انتوا دخلتوا
+
+416
+00:34:12,500 --> 00:34:15,820
+ورا اللوحة طلعتوا من ورا بس المجموعة من الأمام
+
+417
+00:34:15,820 --> 00:34:20,140
+وانتوا من نفس الجهة بيصير عندكم مشكلة طب كيف بتحل
+
+418
+00:34:20,140 --> 00:34:23,380
+هذه المعضلة؟
+
+419
+00:34:23,380 --> 00:34:28,840
+بتعرفوا المثل اللي بيقول صدمة بتضيع صدمة؟ ولا
+
+420
+00:34:28,840 --> 00:34:34,160
+minus ضرب minus بيساوي زائد؟ الآن أنا هنافي عندي
+
+421
+00:34:34,160 --> 00:34:39,260
+خطأ إن المجموعة اللي أصل تكون الخلف مرسومة للأمام
+
+422
+00:34:39,260 --> 00:34:43,140
+طالما أنه على أحد الجانبين فهي للأمام بقول غلطة
+
+423
+00:34:43,140 --> 00:34:48,920
+بتضيع غلطة باجي لما أحدد ال configuration بقرا إيش
+
+424
+00:34:48,920 --> 00:34:53,640
+طلع عند ال configuration و بكتب عكسه كأن عملت عكس
+
+425
+00:34:53,640 --> 00:34:55,660
+في عكس بتطلع الجواب عندكم صح
+
+426
+00:34:58,290 --> 00:35:01,850
+بتكتش و تفهموها بشكل القاتل، إذا أقل مجموعة عندكم
+
+427
+00:35:01,850 --> 00:35:05,650
+موجودة لفور أو لتحت، امشوا من الأعلى للأقل و حطوا
+
+428
+00:35:05,650 --> 00:35:10,050
+الجواب مباشرة، بتكونوا اشتغلتوا صح. الآن، إذا أقل
+
+429
+00:35:10,050 --> 00:35:17,450
+مجموعة موجودة على أحد الجانبين،
+
+430
+00:35:17,450 --> 00:35:22,550
+افضوا من الأعلى للأقل و اكتبوا عكس الجواب، تتعبوش
+
+431
+00:35:22,550 --> 00:35:27,830
+أعصابكم؟امشوا زي ما احنا متفقين بس طالما أقل
+
+432
+00:35:27,830 --> 00:35:31,810
+مجموعة محطوطة على الجانب وكتبوا عكس الجواب بتكونوا
+
+433
+00:35:31,810 --> 00:35:36,890
+عملته الصح ليش؟ لأن هذه المجموعة للأمام معكوسة
+
+434
+00:35:36,890 --> 00:35:42,250
+فانتوا الجواب اللي بتطلعوه بتعكسه واضح؟ وعشانك لما
+
+435
+00:35:42,250 --> 00:35:46,030
+أنا هنا بمشي يود ال brom و الchloro وهذه أقل
+
+436
+00:35:46,030 --> 00:35:52,330
+مجموعة على الجانب بتبقى I ببينها S بتقول S بصوت
+
+437
+00:35:53,740 --> 00:35:58,680
+بصوت واطد و بحد يسمعه، بس لازم ينسمع الاسم، لأنه
+
+438
+00:35:58,680 --> 00:36:08,140
+إيش؟ لأنه من الحروف الصفير والهمس، مهموس و أفحته
+
+439
+00:36:08,140 --> 00:36:12,660
+شخص سكت، مظبوط ولا لأ؟ أه من الحروف الصفير والهمس،
+
+440
+00:36:12,660 --> 00:36:19,600
+بتسمعه، بتقول هي بصوت واطد، و بتكتبوه آه، بتكون
+
+441
+00:36:19,600 --> 00:36:25,160
+حطيته الجواب الصحكأنكوا اكتشفتوا ان في عندكوا غلطة
+
+442
+00:36:25,160 --> 00:36:29,840
+في المجموعة انها مش مرسومة للخلف مرسومة للأمام و
+
+443
+00:36:29,840 --> 00:36:34,080
+الشرط تكون مرسومة الخلف بتحط بناها هذا المركب نفس
+
+444
+00:36:34,080 --> 00:36:45,200
+الاشي باجي بقول you'd بقول كتابة
+
+445
+00:36:45,200 --> 00:36:52,660
+الصحي باضح؟و بهيك بنقدر احنا نحدد ال configuration
+
+446
+00:36:52,660 --> 00:36:58,980
+لأي جزء .. بهيك بنقدر احنا نحدد ال configuration
+
+447
+00:36:58,980 --> 00:37:08,100
+لأي جزء .. الان كتير كلام شرحناه لكم و احنا
+
+448
+00:37:08,100 --> 00:37:12,980
+واجفينه و جلبنا صفحات كتيرة خلينا نمشي عليها بسرعة
+
+449
+00:37:12,980 --> 00:37:16,260
+في ال computer و تشوف انه فعلا اخدنا هذه الأشياء
+
+450
+00:37:16,260 --> 00:37:21,480
+ولا لأباقي صفحة ال isomers هنعود نرجع لها في هدوء
+
+451
+00:37:21,480 --> 00:37:29,480
+الآن عرفنا إيش معنى pair of enantiomers واضح؟ لما
+
+452
+00:37:29,480 --> 00:37:34,020
+يكون عندي carbon بتحمل أربع مجموعات مختلفة الآن
+
+453
+00:37:34,020 --> 00:37:37,040
+هذه ال carbon اللي بتحمل أربع مجموعات مختلفة
+
+454
+00:37:37,040 --> 00:37:42,440
+بنسميها كايرال كاربون إيش معنى كايرال كاربون؟
+
+455
+00:37:42,440 --> 00:37:47,190
+بتحمل أربع مجموعات مختلفةإذا حصل هذا الكلام زي
+
+456
+00:37:47,190 --> 00:37:53,850
+الحالة اللي عندنا فالجزء و صورته في المرأة بيكونوا
+
+457
+00:37:53,850 --> 00:37:58,430
+غير متطابقين و بيطلع عندنا تعريف الانان شمارز
+
+458
+00:37:58,430 --> 00:38:05,110
+والانان شمارز دائما هي عبارة عن زوج واضح؟ زوج هذا
+
+459
+00:38:05,110 --> 00:38:11,350
+و هذا فردتين انان شمارز الآن شرط وجود الانان شمارز
+
+460
+00:38:11,350 --> 00:38:17,050
+زي ما قلنا أنه يكونيكون اربع روابط مختلفة على
+
+461
+00:38:17,050 --> 00:38:21,530
+كربونا واحدة عشان هيك دائما احنا بنعلم الكربونا
+
+462
+00:38:21,530 --> 00:38:26,490
+اللي عليهاأربع مجموعات مختلفة بنجمة وبنقول هنا في
+
+463
+00:38:26,490 --> 00:38:30,190
+عندي stereogenic center يعني مركز لل
+
+464
+00:38:30,190 --> 00:38:35,090
+stereochemistry أو chiral center أو chiral carbon
+
+465
+00:38:35,090 --> 00:38:38,950
+كله نفس الأشياء ال carbon اللي حامل أربع مجموعات
+
+466
+00:38:38,950 --> 00:38:42,690
+مختلفة شو بسميها؟ chiral carbon, chiral center,
+
+467
+00:38:42,910 --> 00:38:46,740
+stereogenic centerالان احنا حاطينلكوا هنا بعض
+
+468
+00:38:46,740 --> 00:38:49,960
+الرسومات تشوفوا اي carbon عليها اربع مجموعات
+
+469
+00:38:49,960 --> 00:38:53,840
+مختلفة اللي عليها اربع مجموعات مختلفة اللي حاطين
+
+470
+00:38:53,840 --> 00:38:59,600
+عليها نجمة يعني الجزء الاول بس carbon واحدة حاملة
+
+471
+00:38:59,600 --> 00:39:02,560
+اربع مجموعات مختلفة طبعا المبينين تلاتة الرابعة هي
+
+472
+00:39:02,560 --> 00:39:08,360
+ايش ال H و الجزء التاني نفس الاشي عليه كلور و عليه
+
+473
+00:39:08,360 --> 00:39:13,880
+مثل و عليه المجموعة الكبيرة الأخيرة و عليههذه فقط
+
+474
+00:39:13,880 --> 00:39:18,520
+الكاربون الكايرال كاربون اللي عليها كم مجموعة
+
+475
+00:39:18,520 --> 00:39:25,280
+مختلفة اربع مجموعات مختلفة نأجل هذا ال slide الان
+
+476
+00:39:25,280 --> 00:39:31,270
+كيف نحدد ال configurationالـ R و ال S أخدنا قولنا
+
+477
+00:39:31,270 --> 00:39:37,770
+أقل مجموعة بنخليها لورق و بعدين بنبدأ من الأعلى
+
+478
+00:39:37,770 --> 00:39:45,560
+للأقل للأقل و بنمشي علىإذا كان عندنا مع عقارب
+
+479
+00:39:45,560 --> 00:39:50,220
+الساعة بيكون عندي R باللاتيني rectus يعني إحنا
+
+480
+00:39:50,220 --> 00:39:54,740
+ماشيين مع عقارب الساعة أو right وإذا عندي عكس
+
+481
+00:39:54,740 --> 00:39:59,820
+عقارب الساعة بيكون عندي S sinister أو left ماشيين
+
+482
+00:39:59,820 --> 00:40:04,360
+عكس عقارب الساعة القواعد اللي بناخدها لإن نقول هذه
+
+483
+00:40:04,360 --> 00:40:08,600
+الأعلى و الأقل و الأقل أخدناها لما حددنا ال sexual
+
+484
+00:40:08,600 --> 00:40:14,370
+trance بتعتمد على ال atomicnumber وإذا أول مجموعة
+
+485
+00:40:14,370 --> 00:40:18,630
+ماحلتنيش بروح على اللي بعد هو أخدنا تفصيل كتير
+
+486
+00:40:18,630 --> 00:40:24,630
+فيها الآن هي عندكم مجموعة من الأمثلة حاطين احنا
+
+487
+00:40:24,630 --> 00:40:31,290
+لها كمساعدة لكم ال configuration ممكن نختم اليوم
+
+488
+00:40:31,290 --> 00:40:37,310
+ان نتطلع على بعض هذه الأمثلة اتطلعوا معاهإيش
+
+489
+00:40:37,310 --> 00:40:44,690
+بتلاحظوا؟ إنه أنا أقل مجموعة في المثال الأول اللي
+
+490
+00:40:44,690 --> 00:40:48,650
+هي ال H حاططها وين فوق أو تحت، إذا ال
+
+491
+00:40:48,650 --> 00:40:54,190
+configuration هيطلع مباشرة، ماعكسش، فلو بتتطلع على
+
+492
+00:40:54,190 --> 00:40:57,290
+المثال اللي فوق، أعلى مجموعة ال U بعدين ال brom،
+
+493
+00:40:57,290 --> 00:41:03,170
+بعدين ال chlorine، كيف ماشيين؟ R، الآن اتطلع على
+
+494
+00:41:03,170 --> 00:41:09,190
+المثال اللي تحت منهالـ H على الجانب إذا الجواب
+
+495
+00:41:09,190 --> 00:41:13,370
+اللي بيطلع عندى لازم أعكسه امشي و يدبرو مكلور
+
+496
+00:41:13,370 --> 00:41:22,190
+انبعينه R بكتب S خدوا المثال اللى بعد هذا المثال
+
+497
+00:41:22,190 --> 00:41:31,770
+إيش المجموعات اللى عندى عندى مثل إثل إبروم و H أقل
+
+498
+00:41:31,770 --> 00:41:37,020
+مجموعة الهيدروجينمحطوطة على الجانب إذا في نهاية
+
+499
+00:41:37,020 --> 00:41:40,900
+الجواب اللي عندي هينكس أنهي أعلى البروم ولا ال مثل
+
+500
+00:41:40,900 --> 00:41:45,060
+والإثل البروم لأن البروم هالوجي للمثل والإثل
+
+501
+00:41:45,060 --> 00:41:50,760
+كاربون في النهاية فالبروم أعلى واحدة بعد البروم
+
+502
+00:41:50,760 --> 00:41:55,040
+مين بيجي أعلى ال إثل ولا المثل ال إثل أعلى كاربون
+
+503
+00:41:55,040 --> 00:42:01,800
+و بعدها كاربون فبناء على ذلك بتكون عند بروم إثل
+
+504
+00:42:01,800 --> 00:42:11,380
+انبعيناS بكتب R لإيش؟ لأنه هذا على الجانب واضح؟ لو
+
+505
+00:42:11,380 --> 00:42:16,800
+تتطلع على .. بديش أخد أنا كل الأمثلة لكن خلّينا
+
+506
+00:42:16,800 --> 00:42:22,980
+نقول ننتهي بهذا المثال أقل
+
+507
+00:42:22,980 --> 00:42:28,060
+مجموعة الـ H الأن بعد ذلك إيش متصل عندي في ال
+
+508
+00:42:28,060 --> 00:42:35,630
+carbon؟ O و Carbonو carbon ان هو اعلى ال O بعدك
+
+509
+00:42:35,630 --> 00:42:38,910
+هذه ال carbon متصلة بتلاتة edges هذه ال carbon
+
+510
+00:42:38,910 --> 00:42:45,870
+متصلة ب O و ب O و ب CH3 هان .. هان ال carbon اللي
+
+511
+00:42:45,870 --> 00:42:52,210
+متصلة بال O اللي حملة A اذا ان هي اعلى A بناء على
+
+512
+00:42:52,210 --> 00:42:59,340
+ذلك التلتيب اللي عندى هاي واحد تنين تلاتة مبينأس
+
+513
+00:42:59,340 --> 00:43:04,340
+بكتب أ كل الأمثلة هذه بإمكانكوا بهدوء تعملوها في
+
+514
+00:43:04,340 --> 00:43:10,560
+البيت و بإمكانكوا تتحققوا من الإجابة شكرا لكم
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3c5235145eb30afcc58722f607146dac5386b247
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_postprocess.srt
@@ -0,0 +1,1540 @@
+1
+00:00:06,550 --> 00:00:11,410
+اليوم بنكمل ان شاء الله في الفصل اللي بدأنا فيه
+
+2
+00:00:11,410 --> 00:00:17,150
+اللي هو بعنوان aldehydes and ketones المرة الماضية
+
+3
+00:00:17,150 --> 00:00:21,250
+اتكلمنا على تسمية ال aldehydes و ال ketones،
+
+4
+00:00:21,250 --> 00:00:26,980
+اتوسعنا في الموضوع سواء بال common names أوبال
+
+5
+00:00:26,980 --> 00:00:34,020
+Iopaque Names الآن بدنا نتعرض في البداية لبعض ال
+
+6
+00:00:34,020 --> 00:00:38,480
+aldehydes و ال ketones اللي مشهورة جدا و بشكل عام
+
+7
+00:00:38,480 --> 00:00:41,740
+كيف بيحطروها في الصناعة ليش؟ لأن هذه ال aldehydes
+
+8
+00:00:41,740 --> 00:00:46,900
+و ال ketones بتلزم بكميات كبيرة و بعدين بدنا ناخد
+
+9
+00:00:46,900 --> 00:00:50,600
+الطرق العامة لتحضير ال aldehydes و ال ketones بشكل
+
+10
+00:00:50,600 --> 00:00:52,700
+عام اللي هي الطرق المخبرية
+
+11
+00:00:55,800 --> 00:00:59,220
+إذا بتلاحظوا في ال common aldehydes and ketones
+
+12
+00:00:59,220 --> 00:01:02,200
+اللي بدنا ناخده من اللي هما أبسط ال aldehydes و ال
+
+13
+00:01:02,200 --> 00:01:05,820
+ketones، يعني ال formaldehyde أبسط ال aldehyde، ال
+
+14
+00:01:05,820 --> 00:01:11,320
+acetaldehyde اللي بيجي بعده ال aldehydeمازال
+
+15
+00:01:11,320 --> 00:01:16,800
+الديهايد الاسيتون أبسط كيتون الاسيتون أبسط كيتون
+
+16
+00:01:16,800 --> 00:01:21,180
+بالنسبة لل formaldehyde بالنسبة لل formaldehyde
+
+17
+00:01:21,180 --> 00:01:26,060
+اللي هو C double bond O مع H2O من الجهتين بيحضروه
+
+18
+00:01:26,060 --> 00:01:34,110
+عادة في الصناعة بعملية أكسدة للميثانونبوجود الفضة
+
+19
+00:01:34,110 --> 00:01:38,490
+مابيست 100 إلى 700 درجة موية، دائما شروط الصناعة
+
+20
+00:01:38,490 --> 00:01:43,410
+بتلاحظوا فيها الضغط والحرارة العالية، واضح؟ هذه
+
+21
+00:01:43,410 --> 00:01:46,890
+الأمور في المختبر مش متوفرة، في المختبر بشكل عام
+
+22
+00:01:47,200 --> 00:01:51,160
+اللي متوفر فلسكات و حرارة تمانين و تسعين و مية و
+
+23
+00:01:51,160 --> 00:01:55,420
+مية و أربعين فقط زيك لكن لما أنا بحكي على ستمية
+
+24
+00:01:55,420 --> 00:01:59,180
+لسبعمية درجة لما بحكي مثلا عن ضغط خمسة ولا عشرة
+
+25
+00:01:59,180 --> 00:02:06,100
+أتمسفير ولا ميت أتمسفير أكيد بيكون بد مجهزة صناعية
+
+26
+00:02:06,100 --> 00:02:10,500
+وأوعية مش اجزاز بتصير stainless steel ضغط و حرارة
+
+27
+00:02:10,500 --> 00:02:17,090
+بتعرفوا يعني لازم تكون ..الأجهزة بتحتمل بيطلع
+
+28
+00:02:17,090 --> 00:02:22,610
+عندنا ال .. ال formaldehyde والهيدروجين الآن بشكل
+
+29
+00:02:22,610 --> 00:02:29,540
+عام ال formaldehyde .. ال formaldehyde غازواضح ال
+
+30
+00:02:29,540 --> 00:02:34,600
+formaldehyde غاز لأن ال boiling point له ناقص واحد
+
+31
+00:02:34,600 --> 00:02:37,980
+وعشرين درجة مئوية بمعنى احنا لما تكون الحرارة
+
+32
+00:02:37,980 --> 00:02:41,260
+عندنا زي اليوم خمسة وعشرين او تلاتين درجة مئوية
+
+33
+00:02:41,260 --> 00:02:45,980
+لسه ال boiling point تبعته اقل بخمسين درجة من
+
+34
+00:02:45,980 --> 00:02:51,060
+حرارتنا اليوم واضح فهو موجود على شكل غاز لكن في
+
+35
+00:02:51,060 --> 00:02:55,600
+التطبيق معظم استعمالاتنا له بياخدوا هذا الغاز
+
+36
+00:02:55,600 --> 00:03:01,970
+بدوبوف ميةبصير محلول اسمه محلول ال formalin فال
+
+37
+00:03:01,970 --> 00:03:07,370
+formalin هو عبارة عن غاز ال formaldehyde امدوب في
+
+38
+00:03:07,370 --> 00:03:11,690
+ميا واضح ال formalin غاز ال formaldehyde امدوب في
+
+39
+00:03:11,690 --> 00:03:18,650
+ميا عادة بصل التركيز ل 37% عادة بصل التركيز ل 37%
+
+40
+00:03:18,650 --> 00:03:22,170
+وهذا ال formalin اللي بيستعملوه بالذات اللي
+
+41
+00:03:22,170 --> 00:03:25,270
+بيهتموا بهالكلام تعون ال biology وغيرها لحفظ
+
+42
+00:03:25,270 --> 00:03:30,750
+الأنسجةلما بدهم يحفظوا الأنسجة التحنيط مش هالشغلة
+
+43
+00:03:30,750 --> 00:03:35,650
+المهمة كتير خليني أقول لكن مثلا اليوم معظم أماكن
+
+44
+00:03:35,650 --> 00:03:39,870
+الجراحة لما بيكون عند الناس أنواع مختلفة من
+
+45
+00:03:39,870 --> 00:03:44,870
+الأورام جزء كبير منكوا تحاليل طبية أي ورم لازم
+
+46
+00:03:44,870 --> 00:03:48,750
+يطلعوه من البني آدم لازم يبعتوه على فحص الأنسجة
+
+47
+00:03:48,750 --> 00:03:54,550
+يشوفوا هذا الورمخبيث ولا حميد؟ مظبوط ولا لا؟ الان
+
+48
+00:03:54,550 --> 00:03:57,850
+هذا الورم طلعه الجراح لما يروح على مختبر فحص
+
+49
+00:03:57,850 --> 00:04:01,910
+الانسجاش بده يخليه زي ما هو يخرب مجرد ما هو بيطلع
+
+50
+00:04:01,910 --> 00:04:06,890
+اي ورم بيحطه بمحلول فورمالين بيروح علىمختبر
+
+51
+00:04:06,890 --> 00:04:10,850
+الهيستولوجي الفحص الأنسجة بالمحلول بطلو بيعملوا
+
+52
+00:04:10,850 --> 00:04:15,070
+فحص أنسجة بيشوفوا ان هل هذه الخلايا خلايا أو رام
+
+53
+00:04:15,070 --> 00:04:22,290
+من أي نوع واضح فلازم يحطوا محلول Formalin 37%
+
+54
+00:04:22,290 --> 00:04:28,170
+Formaldehyde لكن ال Formaldehyde نفسه مش سائل غاز
+
+55
+00:04:28,170 --> 00:04:33,360
+واضحالاسيتالديهيد اللي هو ال الديهيد اللي بعده
+
+56
+00:04:33,360 --> 00:04:36,720
+اللي بزيد كربونة يعني ال formaldehyde لما حتى
+
+57
+00:04:36,720 --> 00:04:41,220
+سمناه لأنه كربونة واحدة سمناه methanol
+
+58
+00:04:41,220 --> 00:04:45,700
+الاسيتالديهيد كربونتين يعني من الethane سمناه
+
+59
+00:04:45,700 --> 00:04:50,020
+ethanol طبعا اسم الشعورة تبعه اسيتالديهيد
+
+60
+00:04:50,020 --> 00:04:55,440
+الاسيتالديهيد سائل لكن برضه متطاير يعني ال boiling
+
+61
+00:04:55,440 --> 00:05:01,590
+point تبعته عشرينيعني مثل الجو تبعنا لو فتحنا عبوة
+
+62
+00:05:01,590 --> 00:05:05,170
+acetaldehyde و بعدين روحنا نكلم تليفون لو بدت عشر
+
+63
+00:05:05,170 --> 00:05:09,910
+دقايق ربع ساعة بنلاقيها كلها اتبخرت ولذلك عادة
+
+64
+00:05:09,910 --> 00:05:15,810
+يحفظ بالتلاجة لما بيبيعوه حتى مابيحطوش في bottle
+
+65
+00:05:15,810 --> 00:05:21,950
+إلها غطاية لأ بيحطوه في عبوة زجاج مسحوبة بيسموها
+
+66
+00:05:21,950 --> 00:05:27,540
+sealed بتعرفوا كيف؟إذا بتشوفوا الحقن اللي بيعطوها
+
+67
+00:05:27,540 --> 00:05:32,380
+للناس كيف بيكون الجزاز تبعها مسكر بتكون بهذا الشكل
+
+68
+00:05:32,380 --> 00:05:37,440
+و مسحوبة هيك من هنا و بيكسروها نفس الاشي ال
+
+69
+00:05:37,440 --> 00:05:41,620
+acetaldehyde لما بنشره بيكون ب sealed glass
+
+70
+00:05:41,620 --> 00:05:46,680
+bottles يعني مغلقة تماما لأنه لو بده يكون في عندنا
+
+71
+00:05:46,680 --> 00:05:51,020
+زي غطاية و ما إلى ذلك على boiling point عشرين درجة
+
+72
+00:05:51,020 --> 00:05:57,430
+مئويةبتطير عادة بتحضر ب synthesis بنسميه الwalker
+
+73
+00:05:57,430 --> 00:06:03,470
+synthesis بياخدوا القلكين مع أكسجين في وجود عامل
+
+74
+00:06:03,470 --> 00:06:07,770
+كتاليس بلاديام وكبر ودرجة حرارة مية لمية و تلاتين
+
+75
+00:06:07,770 --> 00:06:12,450
+درجة موية في كل هذا الجو بيصير ND في النهاية
+
+76
+00:06:13,340 --> 00:06:18,420
+Ethanol أو Acetaldehyde فعملية تفاعل الألكين مع
+
+77
+00:06:18,420 --> 00:06:22,840
+الأكسجين ضمن هذه الظروف اللي هو بنسميها احنا ايش
+
+78
+00:06:22,840 --> 00:06:27,360
+ال worker synthesis بنحض فيها الديهايد الحقيقة
+
+79
+00:06:27,360 --> 00:06:32,260
+بنفس العملية تماما لو ضفنا مش على ال إيثيلين على
+
+80
+00:06:32,260 --> 00:06:36,280
+البروبيلين اللي هو تلت كربونات بتيجي الأكسجين في
+
+81
+00:06:36,280 --> 00:06:39,860
+المص و بالتالي بطلع عنده ال ketone اللي هو
+
+82
+00:06:39,860 --> 00:06:44,560
+الأسيتونواضح؟ يعني كأنه هنا انا بدي أجيب C double
+
+83
+00:06:44,560 --> 00:06:47,480
+bond O وهنا الموقع نفس الاشي مافيش مشكلة وين ما
+
+84
+00:06:47,480 --> 00:06:53,540
+اجد لكن لو كنت بفعل مع تلت ذرات كربوني ال C double
+
+85
+00:06:53,540 --> 00:06:57,960
+bond O وين بتيجي على الموقع اللي في الوسط وبالتالي
+
+86
+00:06:57,960 --> 00:07:02,500
+بيطلع عندنا أسيتون الأسيتون استعمالته معروفة لكم
+
+87
+00:07:02,940 --> 00:07:06,520
+سواء له استعمالات في التحضيرات الكيميائية أو ك
+
+88
+00:07:06,520 --> 00:07:11,760
+solvent مذيب و عادة يعني هو solvent قوي يعني معظم
+
+89
+00:07:11,760 --> 00:07:14,080
+اللي يشتغلوا في ال organ ال chemistry أبحاث لما
+
+90
+00:07:14,080 --> 00:07:18,320
+يخلصوا كل غسل ال exhaust تبعهم بيغسلوه بإيش؟ بال
+
+91
+00:07:18,320 --> 00:07:23,100
+acetone بيغسلوه بال acetoneال boiling point له 56
+
+92
+00:07:23,100 --> 00:07:26,580
+درجة موية لاحظوا طبعا احنا قلنا ان ال boiling
+
+93
+00:07:26,580 --> 00:07:29,880
+point تبعته اقل من ال ethanol او اقل من ال
+
+94
+00:07:29,880 --> 00:07:35,660
+probanol لأن ال acetone مافيش فيه hydrogen bonding
+
+95
+00:07:35,660 --> 00:07:40,320
+يعني ال alcohol حتى لو كان اقل ب carbon في
+
+96
+00:07:40,320 --> 00:07:44,520
+hydrogen bonding يعني ممكن المقارنة تكون اسهل لما
+
+97
+00:07:44,520 --> 00:07:49,300
+تتذكروا ال alcohol اللي two carbons اللي هو ايش؟
+
+98
+00:07:49,850 --> 00:07:55,230
+الإيثانول CH3 CH2 OH لما بتكون قوله قداش ال
+
+99
+00:07:55,230 --> 00:08:01,070
+boiling point للإيثانول 78
+
+100
+00:08:01,070 --> 00:08:07,350
+أو 78 و نص بمعنى أنه أعلى كتير من ال aldehyde
+
+101
+00:08:07,350 --> 00:08:12,460
+السبباللي هو الـ hydrogen bonding عشان تشوفوا قداش
+
+102
+00:08:12,460 --> 00:08:16,020
+مهمة الـ hydrogen .. قداش مهمة الـ hydrogen
+
+103
+00:08:16,020 --> 00:08:20,360
+bonding في طريقة تانية غير الوكرسينثيس للأسيتون
+
+104
+00:08:20,360 --> 00:08:23,960
+إذا أخذوا هذا المُركّب إليه اسم شهره اللي هو الـ
+
+105
+00:08:23,960 --> 00:08:28,740
+isopropyl بنزينبتسمى ليكيومين اللي هو مُركّب
+
+106
+00:08:28,740 --> 00:08:33,900
+الكمون مع أكسوجين وديليوتسالفارك أسد بيكسر من هنا
+
+107
+00:08:33,900 --> 00:08:39,280
+بيعطي هنا الفينول وبيعطي هنا الأسيتون فالليكيومين
+
+108
+00:08:39,280 --> 00:08:44,080
+كأنه بيصير مصدر لتحضير الفينول ومصدر لتحضير
+
+109
+00:08:44,080 --> 00:08:50,860
+الأسيتون يعني فائدة تبعته أشملها مزدوجة أنا بحضر
+
+110
+00:08:50,860 --> 00:08:54,940
+منه شغلتين فينول وأسيتون
+
+111
+00:09:04,130 --> 00:09:10,610
+الان اذا بدنا نطلع على الطرق المخبرية لتحضير ال
+
+112
+00:09:10,610 --> 00:09:14,730
+الديهيدس والكيتونز في المختبر يعني في جزيئات كبيرة
+
+113
+00:09:14,730 --> 00:09:20,430
+هتلاحظوا ان كل الطرق اللي موجودة هنا احنا سبق
+
+114
+00:09:20,430 --> 00:09:26,170
+درسناهايعني هنا احنا مابنشرحش اشي جديد بس بنذكركوا
+
+115
+00:09:26,170 --> 00:09:31,230
+يعني مثلا البنذ الأول oxidation of alcohols اكسدة
+
+116
+00:09:31,230 --> 00:09:36,230
+الكحولات احنا أخدناها كنوع من تفاعلات الكحولات وهي
+
+117
+00:09:36,230 --> 00:09:41,710
+تؤدي إلى تحضير الديهيدز و ketones لما بدنا نيجي
+
+118
+00:09:41,710 --> 00:09:45,810
+نتذكر كنا نقول ان ال primary alcohols they give
+
+119
+00:09:45,810 --> 00:09:52,360
+aldehydes using BCC و they give acids withكيامان
+
+120
+00:09:52,360 --> 00:09:56,700
+او four اذا متذكرين ال secondary alcohol كانوا
+
+121
+00:09:56,700 --> 00:10:00,820
+بيعطوني ketones ال tertiary alcohol ما بيصيرلهمش
+
+122
+00:10:00,820 --> 00:10:06,900
+اكسدا فهذا الكلام كله درسنا لما درسنا ال alcohol
+
+123
+00:10:06,900 --> 00:10:12,480
+كتفاعل لل alcohol واضح الطريقة التانية لفريدلي
+
+124
+00:10:12,480 --> 00:10:17,440
+كرافت اسيلاشن لما بضحك كيتون هنا على حلقة بنزين
+
+125
+00:10:17,440 --> 00:10:22,530
+هاي كيتون هنا على حلقةبنزين هذا أخدناها في chapter
+
+126
+00:10:22,530 --> 00:10:26,910
+4 انه انا لو أخدت ال acid ال chloride مع aluminum
+
+127
+00:10:26,910 --> 00:10:29,390
+chloride كأنه ال aluminum chloride بدي ياخد ال
+
+128
+00:10:29,390 --> 00:10:33,690
+chloro يعمللي الجزء الموجب ال electrophile
+
+129
+00:10:33,690 --> 00:10:38,980
+والتفاعل هو عبارة عن electrophilicsubstitution
+
+130
+00:10:38,980 --> 00:10:43,540
+واضح فهذا التفاعل ايضا ادرسنا اضافة المال
+
+131
+00:10:43,540 --> 00:10:47,500
+للالكاينز هذا التفاعل مر عليكم وحتى نفس هذه
+
+132
+00:10:47,500 --> 00:10:51,420
+المعادلة كانت سؤال في الامتحان اللي انتم سألته لما
+
+133
+00:10:51,420 --> 00:10:57,780
+بتضيف الميه بضيف H O H بيصير عند in all بنحوله الى
+
+134
+00:10:57,780 --> 00:10:59,920
+ال key اضافة الميه
+
+135
+00:11:06,660 --> 00:11:12,240
+في وجود الحامض اللي هي Markovnikov's addition H O
+
+136
+00:11:12,240 --> 00:11:16,560
+H و بيصير عندي double bond double bond يعني إيه؟
+
+137
+00:11:16,560 --> 00:11:23,940
+وجبه O H All بيعمل tautomerism إلى ال keto form كل
+
+138
+00:11:23,940 --> 00:11:29,380
+هذا الكلام درسته هنا في شبطة البنزين هنا في شبطة
+
+139
+00:11:29,380 --> 00:11:34,290
+ال alcohol و هنا في شبطة ال alkais واضح؟فكل هذه
+
+140
+00:11:34,290 --> 00:11:39,450
+تعتبر طرق لتحضير ال الديهيدس والكيتونز طبعا إذا
+
+141
+00:11:39,450 --> 00:11:42,270
+واحدة منكم بتقول ليش يعني هالغلبة مغلبيننا
+
+142
+00:11:42,270 --> 00:11:45,890
+ومناشفين ريجنا في ال الديهيدس والكيتونز دائما و
+
+143
+00:11:45,890 --> 00:11:51,870
+أبدا بتبقى دالكوا متذكرين شكلها أن الكيميا وطبعا
+
+144
+00:11:51,870 --> 00:11:59,400
+بالتأكيد الرياضيات يعني مش رموز مش رموز لكنهاحياة
+
+145
+00:11:59,400 --> 00:12:04,660
+مش رموز واضح؟ لكنها حياة مثلا لو بدي أجي أطلع أنا
+
+146
+00:12:04,660 --> 00:12:07,340
+على بعض ال ال dehydes و ال ketones اللي مشهورة جدا
+
+147
+00:12:07,340 --> 00:12:15,380
+بحياتنا هذا اللي بنزل ال dehydes هو زيت اللوز له
+
+148
+00:12:15,380 --> 00:12:18,000
+استعمالات كتير موجود في نفس اللوز يعني احنا لما
+
+149
+00:12:18,000 --> 00:12:25,710
+بناكل لوز في ايش؟ في زيوت اه زيت اللوزماشي طب اللي
+
+150
+00:12:25,710 --> 00:12:30,390
+بعده هذا ال aldehyde اللي هنا اسمه cinema aldehyde
+
+151
+00:12:30,390 --> 00:12:37,610
+هيو aldehyde شايفينه؟ هذا أساس ال cinnamon بتعرفوا
+
+152
+00:12:37,610 --> 00:12:43,390
+ال cinnamon؟ ماحد بعرف ال cinnamon ولا حتى الصبح
+
+153
+00:12:43,390 --> 00:12:50,190
+يوم الجمعة لما بتعملوا شعرية بتحطوا عليها إيش؟
+
+154
+00:12:50,190 --> 00:12:56,260
+جرفة .. اه الجرفةالجرفة cinnamon والمركب
+
+155
+00:12:56,260 --> 00:13:00,300
+cinnamaldehyde ال cinnamon اللي هي الجرفة cinnamon
+
+156
+00:13:00,300 --> 00:13:04,320
+واضح فلاحظوا ان المركب اللي فيها هو عبارة عن ايش
+
+157
+00:13:04,320 --> 00:13:10,000
+ال dehyde بلاش صبح يوم الجمعة عصر يوم الجمعة لما
+
+158
+00:13:10,000 --> 00:13:13,820
+بدهم يشوفوا مضيوف بالليل شو بتعملوا لهم كيك و
+
+159
+00:13:13,820 --> 00:13:20,720
+الكيك بده vanilla ال dehyde واضح vanilla ال dehyde
+
+160
+00:13:21,980 --> 00:13:25,400
+طيب بعد ما الناس بتغدو يوم الجمعة بدهم شوية نعناع
+
+161
+00:13:25,400 --> 00:13:32,580
+بطيب رائحة التم كيتون sperminate oil هذا ال carbon
+
+162
+00:13:32,580 --> 00:13:37,840
+ال carbon اللي هو زيت النعناع زيت النعناع برضه
+
+163
+00:13:37,840 --> 00:13:44,020
+كيتون مع التعب المفاصلة بتتعب بدهم camphor الكفور
+
+164
+00:13:44,020 --> 00:13:49,760
+اللي بدهانه في هذا ال camphor كيتون بتعرف مش
+
+165
+00:13:49,760 --> 00:13:59,320
+بدهانه بكريمات و .. اهرائحة طيبة الياسمون الياسمين
+
+166
+00:13:59,320 --> 00:14:04,500
+برضه كيتون لاحظوا كيتون كيتون كيتون الديهايد
+
+167
+00:14:04,500 --> 00:14:09,240
+الديهايد الديهايد فهذه المراكبات يعني و الكيميا
+
+168
+00:14:09,240 --> 00:14:13,160
+بشكل عام هي عبارة عن نوع من الحياة يعني في نائلة
+
+169
+00:14:13,160 --> 00:14:16,880
+تطبيق صحيح بعض المراكبات يمكن مابنلاجلهاش تطبيق
+
+170
+00:14:16,880 --> 00:14:21,020
+لكن بنحضر منها مراكبات تانية إيها في الحياة إيش
+
+171
+00:14:21,590 --> 00:14:30,320
+تطبيقات كثيرةالان بنجي لتفاعلات
+
+172
+00:14:30,320 --> 00:14:34,640
+ال الديهيدس والكيتونز يمكن زي ما اتكلمنا معاكم ال
+
+173
+00:14:34,640 --> 00:14:39,100
+الديهيدس والكيتونز ومثلهم كمان ال assets ومشتقاتها
+
+174
+00:14:39,100 --> 00:14:43,240
+كلهم بمتازة بوجود ال carbonyl group ايش ال
+
+175
+00:14:43,240 --> 00:14:48,720
+carbonyl group؟ السيضة بال bond O هذا السيضة بال
+
+176
+00:14:48,720 --> 00:14:53,690
+bond O السيضة بال bond O اللي موجودة عندناقالما ال
+
+177
+00:14:53,690 --> 00:14:58,030
+oxygen و ال carbon مختلفات بالسالبية، إذا الرابط
+
+178
+00:14:58,030 --> 00:15:03,210
+هتكون polar bond قطبية، الآن مين ال
+
+179
+00:15:03,210 --> 00:15:07,650
+electronegativity إله أعلى؟ ال O كأنه ال O بتصير
+
+180
+00:15:07,650 --> 00:15:12,930
+تمثل طرف سالب، ال carbon طرف موجب، حتى لو تخيلنا
+
+181
+00:15:12,930 --> 00:15:16,470
+أن ال bond اتحركت هيك ب resonance structure، بتصير
+
+182
+00:15:16,470 --> 00:15:22,280
+ال carbon موجب كاملوالأكسجين سالب كامل الخلاصة كل
+
+183
+00:15:22,280 --> 00:15:26,280
+الكيميا .. كل الكيميا تبعت مجموعة C double bond O
+
+184
+00:15:26,280 --> 00:15:29,880
+معتمدة على شغل واحدة انه ال carbon سواء اعتبرناها
+
+185
+00:15:29,880 --> 00:15:34,600
+positive او اعتبرناها partially positive على انه
+
+186
+00:15:34,600 --> 00:15:39,820
+هال carbon موجبة سواء موجبة بشكل جزء او بشكل كامل
+
+187
+00:15:39,820 --> 00:15:44,360
+لو بدعم ال resonance المهم كل كيمياءالـ aldehydes
+
+188
+00:15:44,360 --> 00:15:48,360
+و ال ketones و ال acids و مشتقاتها معتمد على
+
+189
+00:15:48,360 --> 00:15:55,040
+الكربونة الموجبة و دائما و أبدا الموجب بده سالب
+
+190
+00:15:55,040 --> 00:15:58,300
+إذا التفاعل اللي هنا بده يكون enucleophil يعني بده
+
+191
+00:15:58,300 --> 00:16:01,920
+ييجي enucleophile بزم هالكربونة موجبة بتستنى إيش
+
+192
+00:16:01,920 --> 00:16:07,680
+ييجي عليها؟ enucleophile واضح؟طبعا بس بنذكر قبل ما
+
+193
+00:16:07,680 --> 00:16:11,400
+نستمر انه ال carbonyl group ال carbon هنا ال
+
+194
+00:16:11,400 --> 00:16:15,000
+hybridization تبع SB2 و بتكون ال carbonyl group
+
+195
+00:16:15,000 --> 00:16:21,920
+كلها planar بزوايا 120 120 120 واضح؟ يعني بتكون
+
+196
+00:16:21,920 --> 00:16:25,640
+بمستوى واحد يعني مابيكونوش هدول التنتين بمستوى
+
+197
+00:16:25,640 --> 00:16:29,440
+مثلا و هدي طالع زيك من مستوى اللوح لأ التلاتة
+
+198
+00:16:31,210 --> 00:16:35,790
+بيكونوا في مستوى واحد و طبعا هنا رسملكوا ال by
+
+199
+00:16:35,790 --> 00:16:39,170
+bond لأن هنا في عندكوا على ال carbon بي أوربيتال
+
+200
+00:16:39,170 --> 00:16:43,070
+على ال carbon هذي مش في عندي بي أوربيتال و على ال
+
+201
+00:16:43,070 --> 00:16:46,530
+oxygen بي أوربيتال هم اللي عاملين هم اللي عاملين
+
+202
+00:16:46,530 --> 00:16:49,810
+ال by bond اللي أنتوا شايفينها طلنا دائما ال by
+
+203
+00:16:49,810 --> 00:16:56,490
+bond من وين بتيجي من overlap of b orbitals overlap
+
+204
+00:16:56,490 --> 00:17:00,630
+بي أوربيتال زي هيك بيكونوا من فوق و من تحت
+
+205
+00:17:04,920 --> 00:17:10,240
+الان لو بدنا نطلع زي ما قلنا انه اساس التفاعلات
+
+206
+00:17:10,240 --> 00:17:15,340
+انه ال carbon positive او partial positive بتستنى
+
+207
+00:17:15,340 --> 00:17:18,660
+ال nucleophile لان ال nucleophile مباشرة وين بده
+
+208
+00:17:18,660 --> 00:17:25,460
+يهاجم؟ على ال carbon الركابة الرابطة على ال Oبتصير
+
+209
+00:17:25,460 --> 00:17:30,160
+ال oxygen minus ال oxygen مش هتظهر ال minus بتاخد
+
+210
+00:17:30,160 --> 00:17:32,980
+ال hydrogen من الميه او من ال solvent اللي عندك
+
+211
+00:17:32,980 --> 00:17:41,960
+فبصير Oاج الان هذا التفاعل تمر علينا يمكن انه عشر
+
+212
+00:17:41,960 --> 00:17:49,520
+تطبيقات كله ان غير بس في ال nucleophile فين هي ال
+
+213
+00:17:49,520 --> 00:17:57,320
+nucleophile هجم على الكربون و ال O صارتواضح؟ إذا
+
+214
+00:17:57,320 --> 00:18:03,080
+التفاعل الأساسي في ال الديهيدز والكيتونز هو الـ
+
+215
+00:18:03,080 --> 00:18:07,200
+Eucleophilic addition هو ضاف لاحظوا ماقلناش
+
+216
+00:18:07,200 --> 00:18:11,480
+substitution لأنه ما طردش إشييعني كلمة
+
+217
+00:18:11,480 --> 00:18:15,880
+Substitution وقت إيش بنحكيها؟ لما إيش يدخل ويطلع
+
+218
+00:18:15,880 --> 00:18:21,420
+حاجة تانية؟ الآن، هذا لما إجت فاعل طرد الأكسجين،
+
+219
+00:18:21,420 --> 00:18:25,700
+بس خلّاها single bond بدل ما كانت، مهمش، حرك روابط
+
+220
+00:18:25,700 --> 00:18:30,100
+مش مشكلة، لكن عمل إبدال لذرة، في ذرة طلعت، كان
+
+221
+00:18:30,100 --> 00:18:33,120
+الكربون متصل بأكسجين ب double bond، صار الكربون
+
+222
+00:18:33,120 --> 00:18:37,140
+متصلبـ OH هذه العملية عملية الـ addition الـ
+
+223
+00:18:37,140 --> 00:18:40,260
+nucleophilic addition بعد شوية لما بندرس تفاعلات
+
+224
+00:18:40,260 --> 00:18:43,340
+الأحماض و مشتقاتها بنلاقي لأ إنه في إنا
+
+225
+00:18:43,340 --> 00:18:47,860
+substitution إنه في أكسوجينة بتطلع أو أي إش تاني
+
+226
+00:18:47,860 --> 00:18:56,570
+بيطلع واضح؟طبعاً بشكل عام .. بشكل عام بيصير عملية
+
+227
+00:18:56,570 --> 00:19:00,690
+catalysis يعني هذا التفاعل أفضل ما يجرأ في وجود
+
+228
+00:19:00,690 --> 00:19:05,370
+كمية قليلة من الحامض الحامض بيعمل ايش؟ تسريع
+
+229
+00:19:05,370 --> 00:19:08,350
+للتفاعل يعني كل الناس اللي بيعملوا تفاعلات ال
+
+230
+00:19:08,350 --> 00:19:12,380
+aldiates و ال ketones لما يحطواsmall amount of an
+
+231
+00:19:12,380 --> 00:19:18,740
+acid H بيعمل عملية ايش؟ Catalysis تسريع للتفاعل
+
+232
+00:19:18,740 --> 00:19:23,380
+كيف عملية التسريع؟ انه انا لما بدي اضيف H plus
+
+233
+00:19:23,380 --> 00:19:27,240
+اللي هي الحامض اللي بسرع فيه التفاعل بتقدر تتخيل
+
+234
+00:19:27,240 --> 00:19:31,520
+ان هذه ال double bond اتجت هنا كأنها عملت O minus
+
+235
+00:19:31,520 --> 00:19:36,700
+ال O minus أخدت ال H plus صار عندى شغل زي هيك OH
+
+236
+00:19:36,700 --> 00:19:43,610
+الكربون شو هتصفى بهذه الحالة؟Full positive لاحظوا
+
+237
+00:19:43,610 --> 00:19:48,450
+يعني لو كنت أنا بتطلع هنا مع إضافة ال H plus في
+
+238
+00:19:48,450 --> 00:19:53,230
+البداية كأنه صارت عند الكربون positive charge
+
+239
+00:19:53,230 --> 00:19:58,740
+كاملة لو قلت أنا بدي أشغل بدون ال H plusالـ carbon
+
+240
+00:19:58,740 --> 00:20:03,280
+partially positive لأن هو أفضل للتفاعل يكون عندي
+
+241
+00:20:03,280 --> 00:20:09,460
+موجب كامل ولا موجب جزء موجب كامل عشان يصير التفاعل
+
+242
+00:20:09,460 --> 00:20:19,140
+سريع فعملية الحامض هي عملية catalysis انه احنا اول
+
+243
+00:20:19,140 --> 00:20:22,880
+ما بنبدأ نضيف الحامض اول ما بنبدأ بنضيف الحامض
+
+244
+00:20:24,190 --> 00:20:28,270
+واضح؟ بيعمل ان هنا OH بعد هيك لما بدو ييجي ال
+
+245
+00:20:28,270 --> 00:20:33,210
+enucleophile سالب على وجب كامل طبعا ممكن واحدة
+
+246
+00:20:33,210 --> 00:20:38,170
+تقول طيب ال catalyst بيدخل في التفاعل و بيطلع هنا
+
+247
+00:20:38,170 --> 00:20:44,250
+دخل ال H plus وين ال H plus؟ اللي .. اللي طلعت
+
+248
+00:20:45,050 --> 00:20:48,050
+املاحظين انتوا؟ يعني هانا جيبت انا H plus من
+
+249
+00:20:48,050 --> 00:20:51,710
+الحامض واتفاعلت ودخلت في التفاعل طب وين ال H plus
+
+250
+00:20:51,710 --> 00:20:54,950
+اللي طلعت؟ تنسوش انه النيوكليوفايل هذا اللي مكتوب
+
+251
+00:20:54,950 --> 00:20:59,150
+سالب هو أساسا في اشي سالب بنباعه بنشره
+
+252
+00:20:59,150 --> 00:21:03,250
+النيوكليوفايل نفسه بيكون معه H plus يعني مثلا
+
+253
+00:21:03,250 --> 00:21:08,570
+النيوكليوفايل ممكن يكون ايثانون اثل او H بالتالي
+
+254
+00:21:08,570 --> 00:21:13,670
+اللي هيتفاعل منه الاثل او هيطلع
+
+255
+00:21:15,020 --> 00:21:19,780
+H بلس اللي هي من وين كانت مع النيوكليوفايل أو مثلا
+
+256
+00:21:19,780 --> 00:21:25,800
+ممكن النيوكليوفايل يكون الميه اللي هي HO OH خلينا
+
+257
+00:21:25,800 --> 00:21:30,260
+نقول ال OH واحدة وهي ال H هذه ال H هي اللي بتعاود
+
+258
+00:21:30,260 --> 00:21:36,080
+تطلع فكأنه أنا صح جيبت H بلس من الحامض بس طلعت H
+
+259
+00:21:36,080 --> 00:21:40,860
+بلس المرافقة لإيش للنيوكليوفايل فجيبت H بلس طلعت H
+
+260
+00:21:40,860 --> 00:21:45,300
+بلس هاي ال catalystواضح مش ال catalyst بده يدخل و
+
+261
+00:21:45,300 --> 00:21:51,280
+يطلع من التفاعل طبعا مابدخلش نفس الذرع و بتطلع لأ
+
+262
+00:21:51,280 --> 00:21:55,440
+المهم انه دخل H بلصح من الحامض اللي طلعت مش من
+
+263
+00:21:55,440 --> 00:21:59,180
+الحامض من المي أو من ال إيثانول أو من الأمونيا زي
+
+264
+00:21:59,180 --> 00:22:04,290
+ما هنشوف بالأمثلة التفصيلية على أي حال هذه كلهاهذه
+
+265
+00:22:04,290 --> 00:22:09,450
+كلها عبارة عن المعادلة العامة، الآن المحاضرة هذه
+
+266
+00:22:09,450 --> 00:22:13,350
+أو جزء منها و المحاضرة الجاية بتصير كلها عبارة عن
+
+267
+00:22:13,350 --> 00:22:19,870
+عملية تطبيق، بس نغير ل nucleophile و نشوف إيش
+
+268
+00:22:19,870 --> 00:22:24,490
+النتج، نغير ل nucleophile و نشوف إيش النتج، واضح؟
+
+269
+00:22:28,550 --> 00:22:33,630
+أول تفاعل بدنا ناخده اللي هو تفاعل ال hydration
+
+270
+00:22:33,630 --> 00:22:40,030
+hydration معناه إضافة الماء أبسط ال nucleophile
+
+271
+00:22:40,030 --> 00:22:45,010
+لسه توي كنا نشرح عنه الميه الميه فيها أو تقدروا
+
+272
+00:22:45,010 --> 00:22:50,270
+تتخيلوا أنه فيها OH و فيه H طبعا لازم يكون واضح
+
+273
+00:22:50,270 --> 00:22:57,500
+عندكم تماما أن الميه مش مركب ايونيبمعنى الميه
+
+274
+00:22:57,500 --> 00:23:02,020
+molecular ولا ionic compound؟ molecular compound
+
+275
+00:23:02,020 --> 00:23:05,560
+HOH جزء واحد يعني لو تخيلتوا هاي قطعتين هدولة
+
+276
+00:23:05,560 --> 00:23:11,880
+بمثله ال OH .. OH زي هي قطعة واحدة لو كانت مركبة
+
+277
+00:23:11,880 --> 00:23:17,000
+ايون الميه .. لو كانت مركبة ايون هيكون زي هيكOH-
+
+278
+00:23:17,000 --> 00:23:21,400
+OH Plus المية عمرها ما كانت هذا خطأ شائع عند
+
+279
+00:23:21,400 --> 00:23:24,860
+الطلاب و أحيانا بنتقل عند المدارسين و بدرسوا غلط
+
+280
+00:23:24,860 --> 00:23:28,840
+للطلاب أنه أول ما نقول مية كان قالوا H Plus و OH
+
+281
+00:23:28,840 --> 00:23:34,560
+Minusلو الميه H plus و H minus كان صارت زي حمض
+
+282
+00:23:34,560 --> 00:23:37,460
+الكبريتيك و حمض الهيدروكلوريك و حرجت البني أدمين
+
+283
+00:23:37,460 --> 00:23:43,320
+الميه موليكيولر كومباوند قطعة واحدة مافيش فيها H
+
+284
+00:23:43,320 --> 00:23:50,880
+plus و H minus الدليل ع هيك ال Ionic compounds
+
+285
+00:23:50,880 --> 00:23:55,700
+عادة موصلة ممتازة للكهربا لأن فيها موجب و سالب
+
+286
+00:23:55,700 --> 00:24:03,350
+الان لو أخدت ميه نقيه 100% بتوصل كهربا؟و كذلك
+
+287
+00:24:03,350 --> 00:24:08,850
+الحال مثلا ال HCl كثير كثير منكوا بيعتقدوا اعتقادا
+
+288
+00:24:08,850 --> 00:24:14,730
+خاطئا ان ال HCl is an ionic compound انه H plus و
+
+289
+00:24:14,730 --> 00:24:20,930
+H minus ال HCl عمره ما كان H plus و H minus هو HCl
+
+290
+00:24:20,930 --> 00:24:26,900
+و اكتش بيعمل plus و minus لما ادوبه في الميهيعني
+
+291
+00:24:26,900 --> 00:24:32,820
+انتبهوا معاه كيف لو قولنا الميه لحالها ميه نقيه
+
+292
+00:24:32,820 --> 00:24:42,520
+هيه هو pure H2O فيلها conductivity ولا لا لو بتحكي
+
+293
+00:24:42,520 --> 00:24:47,370
+على ال conductivity في التواصل؟مالاش conductivity،
+
+294
+00:24:47,370 --> 00:24:51,210
+مابتوصلش ميّه، الآن لو الميّه .. طب ليش الناس
+
+295
+00:24:51,210 --> 00:24:54,570
+بتكهربوا من الميّه و بيموتوا النسوان من الغسلات؟
+
+296
+00:24:54,570 --> 00:25:02,870
+لأنه في عندي سولت أملاح في الميّه الأملاح ..
+
+297
+00:25:02,870 --> 00:25:06,250
+الميّه ملانة أملاح، الأملاح أيونات، و الأيونات
+
+298
+00:25:06,250 --> 00:25:10,030
+لأنه في سائل زي الميّه بتشرف فبصير توصيل الكهربا،
+
+299
+00:25:10,030 --> 00:25:15,280
+الميّه اللي فيها أملاح بتوصل كهرباواضح؟ الميه اللى
+
+300
+00:25:15,280 --> 00:25:18,820
+فيها أملح بتوصل الكهربا لكن لو حد أخد ميه نقية 100
+
+301
+00:25:18,820 --> 00:25:23,640
+% وشبك قطمين كهربا مش هتوصلهم فسبب توصيل الكهربا
+
+302
+00:25:23,640 --> 00:25:30,040
+الأملح اللى موجودة في الميه الآن الـHCL الـHCL
+
+303
+00:25:30,040 --> 00:25:38,540
+أساسا هو عبارة عن إيش؟ غاز الـHCL في أصله ..
+
+304
+00:25:38,540 --> 00:25:42,540
+بتكونوا تنتبهوا بالظبط للكلام الـHCL في أصله غاز
+
+305
+00:25:43,660 --> 00:25:50,980
+غاز واضح؟ الان طالما هذا غاز ممكن انا اكثفه و اعمل
+
+306
+00:25:50,980 --> 00:25:56,720
+منه hcl liquid اه يعني بيصير عندى في hcl gas و في
+
+307
+00:25:56,720 --> 00:26:05,560
+hcl liquid okay ال hcl liquid كسائل بيوصل كهربا؟
+
+308
+00:26:05,560 --> 00:26:11,890
+لأ لأ اطلاقاأطلاقا موليكيولار كومباوندر الـ HCl
+
+309
+00:26:11,890 --> 00:26:18,070
+موضوع ميّه ولا نقطة ميّه الان الـ HCl نفسه ممكن
+
+310
+00:26:18,070 --> 00:26:23,150
+أدوبه في ميّه بيصير HCl solution اللي احنا بنتعامل
+
+311
+00:26:23,150 --> 00:26:29,400
+معاه فاللي احنا بنتعامل معاه مش HCl liquidسوليوشن
+
+312
+00:26:29,400 --> 00:26:37,140
+محلول بيكون دايب بنسبة عادة المركز منه 37% الـ HCl
+
+313
+00:26:37,140 --> 00:26:43,760
+أكيوس HCl الـ aqueous بيوصل لإيش؟ لأنه هنا في هذه
+
+314
+00:26:43,760 --> 00:26:50,400
+الحالة بتصير تفاعل ان الـ HCl زائد الـ H2O بيعطينا
+
+315
+00:26:50,400 --> 00:26:57,750
+H3O plus زائد Cl minus كل هذه مراجعاتواضح؟ هانا
+
+316
+00:26:57,750 --> 00:27:02,530
+صار ايونات نتيجة ان ال HCl انحطت في الميه، لذلك
+
+317
+00:27:02,530 --> 00:27:08,510
+محلول الحامض عادة يوصل، ميه نقية بتوصلش، ميه فيها
+
+318
+00:27:08,510 --> 00:27:14,190
+ملح، ميه فيها حامض، بتوصل على طول، نقطة حامض واحدة
+
+319
+00:27:14,190 --> 00:27:17,850
+انحطت في الميه، بتصير توصل الكهربا، بس ميه نقية
+
+320
+00:27:17,850 --> 00:27:22,330
+مية في المية بتوصلش، واضح؟فهذه الأمور انتبهولها
+
+321
+00:27:22,330 --> 00:27:27,770
+عشانك احنا بنقول انه ماحدش يتخيل ان ال HOH is an
+
+322
+00:27:27,770 --> 00:27:32,950
+ionic compound HOH water is a molecular compound
+
+323
+00:27:32,950 --> 00:27:37,550
+مابيكونش مجسوم لايونات موجبة و سالبة مابيكونش
+
+324
+00:27:37,550 --> 00:27:42,210
+مجسوم لايونات موجبة و سالبة و لما عادة بتم التفاعل
+
+325
+00:27:42,210 --> 00:27:47,590
+.. بتم التفاعلمن خلال .. و هو كله ميّه .. و هو كله
+
+326
+00:27:47,590 --> 00:27:51,010
+ميّه من خلال زوج الإلكترونات اللي موجود على ال
+
+327
+00:27:51,010 --> 00:27:56,450
+Oxygen هذا زوج الإلكترونات بيجي هنا و الميّه عليها
+
+328
+00:27:56,450 --> 00:28:02,410
+ذرتين H بعدين بتفقد واحدة منهم بس مابيكونش عندي OH
+
+329
+00:28:02,410 --> 00:28:10,640
+minus لأ اللي بتهاجم الميّه كاملة HOH و بعدينبتفقد
+
+330
+00:28:10,640 --> 00:28:15,320
+H plus الخلاصة زي ما احنا اتفقنا قولنا انه ال
+
+331
+00:28:15,320 --> 00:28:19,980
+nucleophile بيجي بيتفاعل و ال c double bond O ايش
+
+332
+00:28:19,980 --> 00:28:28,100
+بتصير OH خلينا نلتزم بهذا الشكل اللي انتوا شايفينه
+
+333
+00:28:28,100 --> 00:28:32,740
+فكل مرة هتلاحظوا انه هنحطلكوا ال nucleophile بمربع
+
+334
+00:28:32,740 --> 00:28:40,660
+و ال c double bond Oبهذا الشكل ال circle نوعا ما
+
+335
+00:28:40,660 --> 00:28:47,020
+اللي هي بتصير OH زي ما قلنا المعادلة العامة
+
+336
+00:28:47,020 --> 00:28:50,620
+nucleophile بيهاجم و C double dot O بتصير إيش
+
+337
+00:28:50,620 --> 00:28:55,720
+عبارة عن OH هذا المركب لو بدي أحكي أنا مع ال
+
+338
+00:28:55,720 --> 00:29:02,870
+formaldehyde مع ال formaldehyde هو ال formalinيعني
+
+339
+00:29:02,870 --> 00:29:05,990
+هنا أنا إيش قاعد بحكي مع ال formaldehyde تحديدًا
+
+340
+00:29:05,990 --> 00:29:10,570
+بحط formaldehyde مع ميه بيعطينا ال formaldehyde
+
+341
+00:29:10,570 --> 00:29:14,150
+hydrate اللي هو ال formaldehyde اللي دايب في ميه
+
+342
+00:29:14,150 --> 00:29:17,310
+اللي هي شكله يعني لو بدنا نقولكوا ارسمولنا ال
+
+343
+00:29:17,310 --> 00:29:21,530
+formaldehyde hydrate هاي اللي موجود عندكم هو
+
+344
+00:29:21,530 --> 00:29:26,890
+formaldehyde متفاعل مع الميههو formaldehyde متفاعل
+
+345
+00:29:26,890 --> 00:29:32,150
+مع الميه الآن عد السؤال هل يا ترى كل ال aldehydes
+
+346
+00:29:32,150 --> 00:29:38,930
+بتتفاعل مع الميه و بيصير OH و هنا OH تانية الحقيقة
+
+347
+00:29:38,930 --> 00:29:43,090
+لأ يعني هذا التفاعل يكاد يكون محصور في عدد قليل من
+
+348
+00:29:43,090 --> 00:29:48,970
+ال aldehydes أشهرهم الميه بتعمل hydrate و في مركب
+
+349
+00:29:48,970 --> 00:29:56,000
+تاني في مركب تاني اللي هوالكلورال بنسميه كلورال
+
+350
+00:29:56,000 --> 00:30:03,980
+هيدريت هذا أصله هذا المركب أصله CHCCH3
+
+351
+00:30:03,980 --> 00:30:13,040
+الديهيد كان إيش CHCWOH و هذا CH3 الآن لو بدلت
+
+352
+00:30:13,040 --> 00:30:18,000
+التلاتة هيدروجين بكلور اللي هو ال
+
+353
+00:30:18,000 --> 00:30:21,680
+trichloroacetaldehyde
+
+354
+00:30:21,840 --> 00:30:30,960
+بيصير اسمه Cloride يعني هذا عبارة عن الديهايد لكن
+
+355
+00:30:30,960 --> 00:30:39,260
+ايش افضله؟ تلاتة هيدروجين بكلور فهذا لو كنا بنسميه
+
+356
+00:30:39,260 --> 00:30:48,560
+.. شو ممكن تسموه؟ الـ Trichloroacetaldehyde
+
+357
+00:30:48,560 --> 00:30:50,740
+وإله اسم شهرة
+
+358
+00:30:53,750 --> 00:30:58,730
+Echloral او الـ Trichloroacetal دي هادي هذا ال
+
+359
+00:30:58,730 --> 00:31:04,890
+Echloral لو فعلنا مع الميه بيعطينا ال Echloral
+
+360
+00:31:04,890 --> 00:31:14,290
+هايدريت هى اجت ال OH من الميه و ال OH اللى كانت
+
+361
+00:31:14,290 --> 00:31:21,200
+اصلا C double bond Oواضح؟ لكن لو بدنا نقول مثلا مع
+
+362
+00:31:21,200 --> 00:31:24,900
+ال .. propranaldehyde مع ال .. pentaldehyde
+
+363
+00:31:24,900 --> 00:31:31,340
+whatever بشكل عام التفاعل هذا عبارة عن اتزان بيظله
+
+364
+00:31:31,340 --> 00:31:36,040
+على هذا الشكل المنفصل يعني الاتزان بيكون أكثر
+
+365
+00:31:36,040 --> 00:31:42,000
+لليسار لل reactants منه لل products واضح؟ وين
+
+366
+00:31:42,000 --> 00:31:48,940
+بيكونوا ال products أكتر؟ في ال formaldehydeو فيه
+
+367
+00:31:48,940 --> 00:31:54,180
+ال chloral ال formaldehyde و ال chloral بالمناسبة
+
+368
+00:31:54,180 --> 00:32:01,080
+هذا ال chloral له تطبيق بيستعمل ك anesthetic مخدر
+
+369
+00:32:01,080 --> 00:32:08,220
+لكن مخدر لمين؟ للحيوانات اه تعون الطب ال بيطري
+
+370
+00:32:08,220 --> 00:32:12,180
+بيستعملوه يعني مخدر للحيوانات الخيول و الحصول لما
+
+371
+00:32:12,180 --> 00:32:17,980
+بيعملولهم عمليات و ما إلى ذلك اهفرغم إنها المعادلة
+
+372
+00:32:17,980 --> 00:32:22,300
+عامة تبع ال الديهايد والميّه لكن بشكل عام دائما
+
+373
+00:32:22,300 --> 00:32:25,940
+بيظلوا موجود أكتر على شكل الديهايد وين بيعمل ال
+
+374
+00:32:25,940 --> 00:32:30,960
+hydrate؟ بال formaldehyde و بال chloral في الحالات
+
+375
+00:32:30,960 --> 00:32:36,140
+التانية تقدر تقولوا كأنه ما صارش تفاعل الآن بعد
+
+376
+00:32:36,140 --> 00:32:43,120
+إضافة الميّه بدنا نبدأ نضيف أشياء تانية مثلا
+
+377
+00:32:43,120 --> 00:32:51,020
+الكحولات هتلاحظواهتلاحظوا أنه هيكون عندكم نفس
+
+378
+00:32:51,020 --> 00:32:58,300
+المنظر الـUQ file بتفاعل و الـCW.O بتصير OH يعني
+
+379
+00:32:58,300 --> 00:33:00,720
+لو كل مرة بدنا نقول Hi للـUQ file
+
+380
+00:33:03,200 --> 00:33:08,680
+بس خلصنا واضح؟ لكن احنا اليوم مش هنكمل في التفاعل
+
+381
+00:33:08,680 --> 00:33:13,540
+ال alcohols و توابعها بدنا نوقف لهذه اللحظة
+
+382
+00:33:13,540 --> 00:33:17,040
+المحاضرة الجاية ان شاء الله بنبدأ بنستمر كل
+
+383
+00:33:17,040 --> 00:33:21,820
+المحاضرة الجاية هتلاقوها على نفس النمط واضح؟ طبعا
+
+384
+00:33:21,820 --> 00:33:24,180
+احنا مش هنكمل اليوم عشان بدنا نعطيكوا براق
+
+385
+00:33:24,180 --> 00:33:24,900
+الامتحانات
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3c5235145eb30afcc58722f607146dac5386b247
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_raw.srt
@@ -0,0 +1,1540 @@
+1
+00:00:06,550 --> 00:00:11,410
+اليوم بنكمل ان شاء الله في الفصل اللي بدأنا فيه
+
+2
+00:00:11,410 --> 00:00:17,150
+اللي هو بعنوان aldehydes and ketones المرة الماضية
+
+3
+00:00:17,150 --> 00:00:21,250
+اتكلمنا على تسمية ال aldehydes و ال ketones،
+
+4
+00:00:21,250 --> 00:00:26,980
+اتوسعنا في الموضوع سواء بال common names أوبال
+
+5
+00:00:26,980 --> 00:00:34,020
+Iopaque Names الآن بدنا نتعرض في البداية لبعض ال
+
+6
+00:00:34,020 --> 00:00:38,480
+aldehydes و ال ketones اللي مشهورة جدا و بشكل عام
+
+7
+00:00:38,480 --> 00:00:41,740
+كيف بيحطروها في الصناعة ليش؟ لأن هذه ال aldehydes
+
+8
+00:00:41,740 --> 00:00:46,900
+و ال ketones بتلزم بكميات كبيرة و بعدين بدنا ناخد
+
+9
+00:00:46,900 --> 00:00:50,600
+الطرق العامة لتحضير ال aldehydes و ال ketones بشكل
+
+10
+00:00:50,600 --> 00:00:52,700
+عام اللي هي الطرق المخبرية
+
+11
+00:00:55,800 --> 00:00:59,220
+إذا بتلاحظوا في ال common aldehydes and ketones
+
+12
+00:00:59,220 --> 00:01:02,200
+اللي بدنا ناخده من اللي هما أبسط ال aldehydes و ال
+
+13
+00:01:02,200 --> 00:01:05,820
+ketones، يعني ال formaldehyde أبسط ال aldehyde، ال
+
+14
+00:01:05,820 --> 00:01:11,320
+acetaldehyde اللي بيجي بعده ال aldehydeمازال
+
+15
+00:01:11,320 --> 00:01:16,800
+الديهايد الاسيتون أبسط كيتون الاسيتون أبسط كيتون
+
+16
+00:01:16,800 --> 00:01:21,180
+بالنسبة لل formaldehyde بالنسبة لل formaldehyde
+
+17
+00:01:21,180 --> 00:01:26,060
+اللي هو C double bond O مع H2O من الجهتين بيحضروه
+
+18
+00:01:26,060 --> 00:01:34,110
+عادة في الصناعة بعملية أكسدة للميثانونبوجود الفضة
+
+19
+00:01:34,110 --> 00:01:38,490
+مابيست 100 إلى 700 درجة موية، دائما شروط الصناعة
+
+20
+00:01:38,490 --> 00:01:43,410
+بتلاحظوا فيها الضغط والحرارة العالية، واضح؟ هذه
+
+21
+00:01:43,410 --> 00:01:46,890
+الأمور في المختبر مش متوفرة، في المختبر بشكل عام
+
+22
+00:01:47,200 --> 00:01:51,160
+اللي متوفر فلسكات و حرارة تمانين و تسعين و مية و
+
+23
+00:01:51,160 --> 00:01:55,420
+مية و أربعين فقط زيك لكن لما أنا بحكي على ستمية
+
+24
+00:01:55,420 --> 00:01:59,180
+لسبعمية درجة لما بحكي مثلا عن ضغط خمسة ولا عشرة
+
+25
+00:01:59,180 --> 00:02:06,100
+أتمسفير ولا ميت أتمسفير أكيد بيكون بد مجهزة صناعية
+
+26
+00:02:06,100 --> 00:02:10,500
+وأوعية مش اجزاز بتصير stainless steel ضغط و حرارة
+
+27
+00:02:10,500 --> 00:02:17,090
+بتعرفوا يعني لازم تكون ..الأجهزة بتحتمل بيطلع
+
+28
+00:02:17,090 --> 00:02:22,610
+عندنا ال .. ال formaldehyde والهيدروجين الآن بشكل
+
+29
+00:02:22,610 --> 00:02:29,540
+عام ال formaldehyde .. ال formaldehyde غازواضح ال
+
+30
+00:02:29,540 --> 00:02:34,600
+formaldehyde غاز لأن ال boiling point له ناقص واحد
+
+31
+00:02:34,600 --> 00:02:37,980
+وعشرين درجة مئوية بمعنى احنا لما تكون الحرارة
+
+32
+00:02:37,980 --> 00:02:41,260
+عندنا زي اليوم خمسة وعشرين او تلاتين درجة مئوية
+
+33
+00:02:41,260 --> 00:02:45,980
+لسه ال boiling point تبعته اقل بخمسين درجة من
+
+34
+00:02:45,980 --> 00:02:51,060
+حرارتنا اليوم واضح فهو موجود على شكل غاز لكن في
+
+35
+00:02:51,060 --> 00:02:55,600
+التطبيق معظم استعمالاتنا له بياخدوا هذا الغاز
+
+36
+00:02:55,600 --> 00:03:01,970
+بدوبوف ميةبصير محلول اسمه محلول ال formalin فال
+
+37
+00:03:01,970 --> 00:03:07,370
+formalin هو عبارة عن غاز ال formaldehyde امدوب في
+
+38
+00:03:07,370 --> 00:03:11,690
+ميا واضح ال formalin غاز ال formaldehyde امدوب في
+
+39
+00:03:11,690 --> 00:03:18,650
+ميا عادة بصل التركيز ل 37% عادة بصل التركيز ل 37%
+
+40
+00:03:18,650 --> 00:03:22,170
+وهذا ال formalin اللي بيستعملوه بالذات اللي
+
+41
+00:03:22,170 --> 00:03:25,270
+بيهتموا بهالكلام تعون ال biology وغيرها لحفظ
+
+42
+00:03:25,270 --> 00:03:30,750
+الأنسجةلما بدهم يحفظوا الأنسجة التحنيط مش هالشغلة
+
+43
+00:03:30,750 --> 00:03:35,650
+المهمة كتير خليني أقول لكن مثلا اليوم معظم أماكن
+
+44
+00:03:35,650 --> 00:03:39,870
+الجراحة لما بيكون عند الناس أنواع مختلفة من
+
+45
+00:03:39,870 --> 00:03:44,870
+الأورام جزء كبير منكوا تحاليل طبية أي ورم لازم
+
+46
+00:03:44,870 --> 00:03:48,750
+يطلعوه من البني آدم لازم يبعتوه على فحص الأنسجة
+
+47
+00:03:48,750 --> 00:03:54,550
+يشوفوا هذا الورمخبيث ولا حميد؟ مظبوط ولا لا؟ الان
+
+48
+00:03:54,550 --> 00:03:57,850
+هذا الورم طلعه الجراح لما يروح على مختبر فحص
+
+49
+00:03:57,850 --> 00:04:01,910
+الانسجاش بده يخليه زي ما هو يخرب مجرد ما هو بيطلع
+
+50
+00:04:01,910 --> 00:04:06,890
+اي ورم بيحطه بمحلول فورمالين بيروح علىمختبر
+
+51
+00:04:06,890 --> 00:04:10,850
+الهيستولوجي الفحص الأنسجة بالمحلول بطلو بيعملوا
+
+52
+00:04:10,850 --> 00:04:15,070
+فحص أنسجة بيشوفوا ان هل هذه الخلايا خلايا أو رام
+
+53
+00:04:15,070 --> 00:04:22,290
+من أي نوع واضح فلازم يحطوا محلول Formalin 37%
+
+54
+00:04:22,290 --> 00:04:28,170
+Formaldehyde لكن ال Formaldehyde نفسه مش سائل غاز
+
+55
+00:04:28,170 --> 00:04:33,360
+واضحالاسيتالديهيد اللي هو ال الديهيد اللي بعده
+
+56
+00:04:33,360 --> 00:04:36,720
+اللي بزيد كربونة يعني ال formaldehyde لما حتى
+
+57
+00:04:36,720 --> 00:04:41,220
+سمناه لأنه كربونة واحدة سمناه methanol
+
+58
+00:04:41,220 --> 00:04:45,700
+الاسيتالديهيد كربونتين يعني من الethane سمناه
+
+59
+00:04:45,700 --> 00:04:50,020
+ethanol طبعا اسم الشعورة تبعه اسيتالديهيد
+
+60
+00:04:50,020 --> 00:04:55,440
+الاسيتالديهيد سائل لكن برضه متطاير يعني ال boiling
+
+61
+00:04:55,440 --> 00:05:01,590
+point تبعته عشرينيعني مثل الجو تبعنا لو فتحنا عبوة
+
+62
+00:05:01,590 --> 00:05:05,170
+acetaldehyde و بعدين روحنا نكلم تليفون لو بدت عشر
+
+63
+00:05:05,170 --> 00:05:09,910
+دقايق ربع ساعة بنلاقيها كلها اتبخرت ولذلك عادة
+
+64
+00:05:09,910 --> 00:05:15,810
+يحفظ بالتلاجة لما بيبيعوه حتى مابيحطوش في bottle
+
+65
+00:05:15,810 --> 00:05:21,950
+إلها غطاية لأ بيحطوه في عبوة زجاج مسحوبة بيسموها
+
+66
+00:05:21,950 --> 00:05:27,540
+sealed بتعرفوا كيف؟إذا بتشوفوا الحقن اللي بيعطوها
+
+67
+00:05:27,540 --> 00:05:32,380
+للناس كيف بيكون الجزاز تبعها مسكر بتكون بهذا الشكل
+
+68
+00:05:32,380 --> 00:05:37,440
+و مسحوبة هيك من هنا و بيكسروها نفس الاشي ال
+
+69
+00:05:37,440 --> 00:05:41,620
+acetaldehyde لما بنشره بيكون ب sealed glass
+
+70
+00:05:41,620 --> 00:05:46,680
+bottles يعني مغلقة تماما لأنه لو بده يكون في عندنا
+
+71
+00:05:46,680 --> 00:05:51,020
+زي غطاية و ما إلى ذلك على boiling point عشرين درجة
+
+72
+00:05:51,020 --> 00:05:57,430
+مئويةبتطير عادة بتحضر ب synthesis بنسميه الwalker
+
+73
+00:05:57,430 --> 00:06:03,470
+synthesis بياخدوا القلكين مع أكسجين في وجود عامل
+
+74
+00:06:03,470 --> 00:06:07,770
+كتاليس بلاديام وكبر ودرجة حرارة مية لمية و تلاتين
+
+75
+00:06:07,770 --> 00:06:12,450
+درجة موية في كل هذا الجو بيصير ND في النهاية
+
+76
+00:06:13,340 --> 00:06:18,420
+Ethanol أو Acetaldehyde فعملية تفاعل الألكين مع
+
+77
+00:06:18,420 --> 00:06:22,840
+الأكسجين ضمن هذه الظروف اللي هو بنسميها احنا ايش
+
+78
+00:06:22,840 --> 00:06:27,360
+ال worker synthesis بنحض فيها الديهايد الحقيقة
+
+79
+00:06:27,360 --> 00:06:32,260
+بنفس العملية تماما لو ضفنا مش على ال إيثيلين على
+
+80
+00:06:32,260 --> 00:06:36,280
+البروبيلين اللي هو تلت كربونات بتيجي الأكسجين في
+
+81
+00:06:36,280 --> 00:06:39,860
+المص و بالتالي بطلع عنده ال ketone اللي هو
+
+82
+00:06:39,860 --> 00:06:44,560
+الأسيتونواضح؟ يعني كأنه هنا انا بدي أجيب C double
+
+83
+00:06:44,560 --> 00:06:47,480
+bond O وهنا الموقع نفس الاشي مافيش مشكلة وين ما
+
+84
+00:06:47,480 --> 00:06:53,540
+اجد لكن لو كنت بفعل مع تلت ذرات كربوني ال C double
+
+85
+00:06:53,540 --> 00:06:57,960
+bond O وين بتيجي على الموقع اللي في الوسط وبالتالي
+
+86
+00:06:57,960 --> 00:07:02,500
+بيطلع عندنا أسيتون الأسيتون استعمالته معروفة لكم
+
+87
+00:07:02,940 --> 00:07:06,520
+سواء له استعمالات في التحضيرات الكيميائية أو ك
+
+88
+00:07:06,520 --> 00:07:11,760
+solvent مذيب و عادة يعني هو solvent قوي يعني معظم
+
+89
+00:07:11,760 --> 00:07:14,080
+اللي يشتغلوا في ال organ ال chemistry أبحاث لما
+
+90
+00:07:14,080 --> 00:07:18,320
+يخلصوا كل غسل ال exhaust تبعهم بيغسلوه بإيش؟ بال
+
+91
+00:07:18,320 --> 00:07:23,100
+acetone بيغسلوه بال acetoneال boiling point له 56
+
+92
+00:07:23,100 --> 00:07:26,580
+درجة موية لاحظوا طبعا احنا قلنا ان ال boiling
+
+93
+00:07:26,580 --> 00:07:29,880
+point تبعته اقل من ال ethanol او اقل من ال
+
+94
+00:07:29,880 --> 00:07:35,660
+probanol لأن ال acetone مافيش فيه hydrogen bonding
+
+95
+00:07:35,660 --> 00:07:40,320
+يعني ال alcohol حتى لو كان اقل ب carbon في
+
+96
+00:07:40,320 --> 00:07:44,520
+hydrogen bonding يعني ممكن المقارنة تكون اسهل لما
+
+97
+00:07:44,520 --> 00:07:49,300
+تتذكروا ال alcohol اللي two carbons اللي هو ايش؟
+
+98
+00:07:49,850 --> 00:07:55,230
+الإيثانول CH3 CH2 OH لما بتكون قوله قداش ال
+
+99
+00:07:55,230 --> 00:08:01,070
+boiling point للإيثانول 78
+
+100
+00:08:01,070 --> 00:08:07,350
+أو 78 و نص بمعنى أنه أعلى كتير من ال aldehyde
+
+101
+00:08:07,350 --> 00:08:12,460
+السبباللي هو الـ hydrogen bonding عشان تشوفوا قداش
+
+102
+00:08:12,460 --> 00:08:16,020
+مهمة الـ hydrogen .. قداش مهمة الـ hydrogen
+
+103
+00:08:16,020 --> 00:08:20,360
+bonding في طريقة تانية غير الوكرسينثيس للأسيتون
+
+104
+00:08:20,360 --> 00:08:23,960
+إذا أخذوا هذا المُركّب إليه اسم شهره اللي هو الـ
+
+105
+00:08:23,960 --> 00:08:28,740
+isopropyl بنزينبتسمى ليكيومين اللي هو مُركّب
+
+106
+00:08:28,740 --> 00:08:33,900
+الكمون مع أكسوجين وديليوتسالفارك أسد بيكسر من هنا
+
+107
+00:08:33,900 --> 00:08:39,280
+بيعطي هنا الفينول وبيعطي هنا الأسيتون فالليكيومين
+
+108
+00:08:39,280 --> 00:08:44,080
+كأنه بيصير مصدر لتحضير الفينول ومصدر لتحضير
+
+109
+00:08:44,080 --> 00:08:50,860
+الأسيتون يعني فائدة تبعته أشملها مزدوجة أنا بحضر
+
+110
+00:08:50,860 --> 00:08:54,940
+منه شغلتين فينول وأسيتون
+
+111
+00:09:04,130 --> 00:09:10,610
+الان اذا بدنا نطلع على الطرق المخبرية لتحضير ال
+
+112
+00:09:10,610 --> 00:09:14,730
+الديهيدس والكيتونز في المختبر يعني في جزيئات كبيرة
+
+113
+00:09:14,730 --> 00:09:20,430
+هتلاحظوا ان كل الطرق اللي موجودة هنا احنا سبق
+
+114
+00:09:20,430 --> 00:09:26,170
+درسناهايعني هنا احنا مابنشرحش اشي جديد بس بنذكركوا
+
+115
+00:09:26,170 --> 00:09:31,230
+يعني مثلا البنذ الأول oxidation of alcohols اكسدة
+
+116
+00:09:31,230 --> 00:09:36,230
+الكحولات احنا أخدناها كنوع من تفاعلات الكحولات وهي
+
+117
+00:09:36,230 --> 00:09:41,710
+تؤدي إلى تحضير الديهيدز و ketones لما بدنا نيجي
+
+118
+00:09:41,710 --> 00:09:45,810
+نتذكر كنا نقول ان ال primary alcohols they give
+
+119
+00:09:45,810 --> 00:09:52,360
+aldehydes using BCC و they give acids withكيامان
+
+120
+00:09:52,360 --> 00:09:56,700
+او four اذا متذكرين ال secondary alcohol كانوا
+
+121
+00:09:56,700 --> 00:10:00,820
+بيعطوني ketones ال tertiary alcohol ما بيصيرلهمش
+
+122
+00:10:00,820 --> 00:10:06,900
+اكسدا فهذا الكلام كله درسنا لما درسنا ال alcohol
+
+123
+00:10:06,900 --> 00:10:12,480
+كتفاعل لل alcohol واضح الطريقة التانية لفريدلي
+
+124
+00:10:12,480 --> 00:10:17,440
+كرافت اسيلاشن لما بضحك كيتون هنا على حلقة بنزين
+
+125
+00:10:17,440 --> 00:10:22,530
+هاي كيتون هنا على حلقةبنزين هذا أخدناها في chapter
+
+126
+00:10:22,530 --> 00:10:26,910
+4 انه انا لو أخدت ال acid ال chloride مع aluminum
+
+127
+00:10:26,910 --> 00:10:29,390
+chloride كأنه ال aluminum chloride بدي ياخد ال
+
+128
+00:10:29,390 --> 00:10:33,690
+chloro يعمللي الجزء الموجب ال electrophile
+
+129
+00:10:33,690 --> 00:10:38,980
+والتفاعل هو عبارة عن electrophilicsubstitution
+
+130
+00:10:38,980 --> 00:10:43,540
+واضح فهذا التفاعل ايضا ادرسنا اضافة المال
+
+131
+00:10:43,540 --> 00:10:47,500
+للالكاينز هذا التفاعل مر عليكم وحتى نفس هذه
+
+132
+00:10:47,500 --> 00:10:51,420
+المعادلة كانت سؤال في الامتحان اللي انتم سألته لما
+
+133
+00:10:51,420 --> 00:10:57,780
+بتضيف الميه بضيف H O H بيصير عند in all بنحوله الى
+
+134
+00:10:57,780 --> 00:10:59,920
+ال key اضافة الميه
+
+135
+00:11:06,660 --> 00:11:12,240
+في وجود الحامض اللي هي Markovnikov's addition H O
+
+136
+00:11:12,240 --> 00:11:16,560
+H و بيصير عندي double bond double bond يعني إيه؟
+
+137
+00:11:16,560 --> 00:11:23,940
+وجبه O H All بيعمل tautomerism إلى ال keto form كل
+
+138
+00:11:23,940 --> 00:11:29,380
+هذا الكلام درسته هنا في شبطة البنزين هنا في شبطة
+
+139
+00:11:29,380 --> 00:11:34,290
+ال alcohol و هنا في شبطة ال alkais واضح؟فكل هذه
+
+140
+00:11:34,290 --> 00:11:39,450
+تعتبر طرق لتحضير ال الديهيدس والكيتونز طبعا إذا
+
+141
+00:11:39,450 --> 00:11:42,270
+واحدة منكم بتقول ليش يعني هالغلبة مغلبيننا
+
+142
+00:11:42,270 --> 00:11:45,890
+ومناشفين ريجنا في ال الديهيدس والكيتونز دائما و
+
+143
+00:11:45,890 --> 00:11:51,870
+أبدا بتبقى دالكوا متذكرين شكلها أن الكيميا وطبعا
+
+144
+00:11:51,870 --> 00:11:59,400
+بالتأكيد الرياضيات يعني مش رموز مش رموز لكنهاحياة
+
+145
+00:11:59,400 --> 00:12:04,660
+مش رموز واضح؟ لكنها حياة مثلا لو بدي أجي أطلع أنا
+
+146
+00:12:04,660 --> 00:12:07,340
+على بعض ال ال dehydes و ال ketones اللي مشهورة جدا
+
+147
+00:12:07,340 --> 00:12:15,380
+بحياتنا هذا اللي بنزل ال dehydes هو زيت اللوز له
+
+148
+00:12:15,380 --> 00:12:18,000
+استعمالات كتير موجود في نفس اللوز يعني احنا لما
+
+149
+00:12:18,000 --> 00:12:25,710
+بناكل لوز في ايش؟ في زيوت اه زيت اللوزماشي طب اللي
+
+150
+00:12:25,710 --> 00:12:30,390
+بعده هذا ال aldehyde اللي هنا اسمه cinema aldehyde
+
+151
+00:12:30,390 --> 00:12:37,610
+هيو aldehyde شايفينه؟ هذا أساس ال cinnamon بتعرفوا
+
+152
+00:12:37,610 --> 00:12:43,390
+ال cinnamon؟ ماحد بعرف ال cinnamon ولا حتى الصبح
+
+153
+00:12:43,390 --> 00:12:50,190
+يوم الجمعة لما بتعملوا شعرية بتحطوا عليها إيش؟
+
+154
+00:12:50,190 --> 00:12:56,260
+جرفة .. اه الجرفةالجرفة cinnamon والمركب
+
+155
+00:12:56,260 --> 00:13:00,300
+cinnamaldehyde ال cinnamon اللي هي الجرفة cinnamon
+
+156
+00:13:00,300 --> 00:13:04,320
+واضح فلاحظوا ان المركب اللي فيها هو عبارة عن ايش
+
+157
+00:13:04,320 --> 00:13:10,000
+ال dehyde بلاش صبح يوم الجمعة عصر يوم الجمعة لما
+
+158
+00:13:10,000 --> 00:13:13,820
+بدهم يشوفوا مضيوف بالليل شو بتعملوا لهم كيك و
+
+159
+00:13:13,820 --> 00:13:20,720
+الكيك بده vanilla ال dehyde واضح vanilla ال dehyde
+
+160
+00:13:21,980 --> 00:13:25,400
+طيب بعد ما الناس بتغدو يوم الجمعة بدهم شوية نعناع
+
+161
+00:13:25,400 --> 00:13:32,580
+بطيب رائحة التم كيتون sperminate oil هذا ال carbon
+
+162
+00:13:32,580 --> 00:13:37,840
+ال carbon اللي هو زيت النعناع زيت النعناع برضه
+
+163
+00:13:37,840 --> 00:13:44,020
+كيتون مع التعب المفاصلة بتتعب بدهم camphor الكفور
+
+164
+00:13:44,020 --> 00:13:49,760
+اللي بدهانه في هذا ال camphor كيتون بتعرف مش
+
+165
+00:13:49,760 --> 00:13:59,320
+بدهانه بكريمات و .. اهرائحة طيبة الياسمون الياسمين
+
+166
+00:13:59,320 --> 00:14:04,500
+برضه كيتون لاحظوا كيتون كيتون كيتون الديهايد
+
+167
+00:14:04,500 --> 00:14:09,240
+الديهايد الديهايد فهذه المراكبات يعني و الكيميا
+
+168
+00:14:09,240 --> 00:14:13,160
+بشكل عام هي عبارة عن نوع من الحياة يعني في نائلة
+
+169
+00:14:13,160 --> 00:14:16,880
+تطبيق صحيح بعض المراكبات يمكن مابنلاجلهاش تطبيق
+
+170
+00:14:16,880 --> 00:14:21,020
+لكن بنحضر منها مراكبات تانية إيها في الحياة إيش
+
+171
+00:14:21,590 --> 00:14:30,320
+تطبيقات كثيرةالان بنجي لتفاعلات
+
+172
+00:14:30,320 --> 00:14:34,640
+ال الديهيدس والكيتونز يمكن زي ما اتكلمنا معاكم ال
+
+173
+00:14:34,640 --> 00:14:39,100
+الديهيدس والكيتونز ومثلهم كمان ال assets ومشتقاتها
+
+174
+00:14:39,100 --> 00:14:43,240
+كلهم بمتازة بوجود ال carbonyl group ايش ال
+
+175
+00:14:43,240 --> 00:14:48,720
+carbonyl group؟ السيضة بال bond O هذا السيضة بال
+
+176
+00:14:48,720 --> 00:14:53,690
+bond O السيضة بال bond O اللي موجودة عندناقالما ال
+
+177
+00:14:53,690 --> 00:14:58,030
+oxygen و ال carbon مختلفات بالسالبية، إذا الرابط
+
+178
+00:14:58,030 --> 00:15:03,210
+هتكون polar bond قطبية، الآن مين ال
+
+179
+00:15:03,210 --> 00:15:07,650
+electronegativity إله أعلى؟ ال O كأنه ال O بتصير
+
+180
+00:15:07,650 --> 00:15:12,930
+تمثل طرف سالب، ال carbon طرف موجب، حتى لو تخيلنا
+
+181
+00:15:12,930 --> 00:15:16,470
+أن ال bond اتحركت هيك ب resonance structure، بتصير
+
+182
+00:15:16,470 --> 00:15:22,280
+ال carbon موجب كاملوالأكسجين سالب كامل الخلاصة كل
+
+183
+00:15:22,280 --> 00:15:26,280
+الكيميا .. كل الكيميا تبعت مجموعة C double bond O
+
+184
+00:15:26,280 --> 00:15:29,880
+معتمدة على شغل واحدة انه ال carbon سواء اعتبرناها
+
+185
+00:15:29,880 --> 00:15:34,600
+positive او اعتبرناها partially positive على انه
+
+186
+00:15:34,600 --> 00:15:39,820
+هال carbon موجبة سواء موجبة بشكل جزء او بشكل كامل
+
+187
+00:15:39,820 --> 00:15:44,360
+لو بدعم ال resonance المهم كل كيمياءالـ aldehydes
+
+188
+00:15:44,360 --> 00:15:48,360
+و ال ketones و ال acids و مشتقاتها معتمد على
+
+189
+00:15:48,360 --> 00:15:55,040
+الكربونة الموجبة و دائما و أبدا الموجب بده سالب
+
+190
+00:15:55,040 --> 00:15:58,300
+إذا التفاعل اللي هنا بده يكون enucleophil يعني بده
+
+191
+00:15:58,300 --> 00:16:01,920
+ييجي enucleophile بزم هالكربونة موجبة بتستنى إيش
+
+192
+00:16:01,920 --> 00:16:07,680
+ييجي عليها؟ enucleophile واضح؟طبعا بس بنذكر قبل ما
+
+193
+00:16:07,680 --> 00:16:11,400
+نستمر انه ال carbonyl group ال carbon هنا ال
+
+194
+00:16:11,400 --> 00:16:15,000
+hybridization تبع SB2 و بتكون ال carbonyl group
+
+195
+00:16:15,000 --> 00:16:21,920
+كلها planar بزوايا 120 120 120 واضح؟ يعني بتكون
+
+196
+00:16:21,920 --> 00:16:25,640
+بمستوى واحد يعني مابيكونوش هدول التنتين بمستوى
+
+197
+00:16:25,640 --> 00:16:29,440
+مثلا و هدي طالع زيك من مستوى اللوح لأ التلاتة
+
+198
+00:16:31,210 --> 00:16:35,790
+بيكونوا في مستوى واحد و طبعا هنا رسملكوا ال by
+
+199
+00:16:35,790 --> 00:16:39,170
+bond لأن هنا في عندكوا على ال carbon بي أوربيتال
+
+200
+00:16:39,170 --> 00:16:43,070
+على ال carbon هذي مش في عندي بي أوربيتال و على ال
+
+201
+00:16:43,070 --> 00:16:46,530
+oxygen بي أوربيتال هم اللي عاملين هم اللي عاملين
+
+202
+00:16:46,530 --> 00:16:49,810
+ال by bond اللي أنتوا شايفينها طلنا دائما ال by
+
+203
+00:16:49,810 --> 00:16:56,490
+bond من وين بتيجي من overlap of b orbitals overlap
+
+204
+00:16:56,490 --> 00:17:00,630
+بي أوربيتال زي هيك بيكونوا من فوق و من تحت
+
+205
+00:17:04,920 --> 00:17:10,240
+الان لو بدنا نطلع زي ما قلنا انه اساس التفاعلات
+
+206
+00:17:10,240 --> 00:17:15,340
+انه ال carbon positive او partial positive بتستنى
+
+207
+00:17:15,340 --> 00:17:18,660
+ال nucleophile لان ال nucleophile مباشرة وين بده
+
+208
+00:17:18,660 --> 00:17:25,460
+يهاجم؟ على ال carbon الركابة الرابطة على ال Oبتصير
+
+209
+00:17:25,460 --> 00:17:30,160
+ال oxygen minus ال oxygen مش هتظهر ال minus بتاخد
+
+210
+00:17:30,160 --> 00:17:32,980
+ال hydrogen من الميه او من ال solvent اللي عندك
+
+211
+00:17:32,980 --> 00:17:41,960
+فبصير Oاج الان هذا التفاعل تمر علينا يمكن انه عشر
+
+212
+00:17:41,960 --> 00:17:49,520
+تطبيقات كله ان غير بس في ال nucleophile فين هي ال
+
+213
+00:17:49,520 --> 00:17:57,320
+nucleophile هجم على الكربون و ال O صارتواضح؟ إذا
+
+214
+00:17:57,320 --> 00:18:03,080
+التفاعل الأساسي في ال الديهيدز والكيتونز هو الـ
+
+215
+00:18:03,080 --> 00:18:07,200
+Eucleophilic addition هو ضاف لاحظوا ماقلناش
+
+216
+00:18:07,200 --> 00:18:11,480
+substitution لأنه ما طردش إشييعني كلمة
+
+217
+00:18:11,480 --> 00:18:15,880
+Substitution وقت إيش بنحكيها؟ لما إيش يدخل ويطلع
+
+218
+00:18:15,880 --> 00:18:21,420
+حاجة تانية؟ الآن، هذا لما إجت فاعل طرد الأكسجين،
+
+219
+00:18:21,420 --> 00:18:25,700
+بس خلّاها single bond بدل ما كانت، مهمش، حرك روابط
+
+220
+00:18:25,700 --> 00:18:30,100
+مش مشكلة، لكن عمل إبدال لذرة، في ذرة طلعت، كان
+
+221
+00:18:30,100 --> 00:18:33,120
+الكربون متصل بأكسجين ب double bond، صار الكربون
+
+222
+00:18:33,120 --> 00:18:37,140
+متصلبـ OH هذه العملية عملية الـ addition الـ
+
+223
+00:18:37,140 --> 00:18:40,260
+nucleophilic addition بعد شوية لما بندرس تفاعلات
+
+224
+00:18:40,260 --> 00:18:43,340
+الأحماض و مشتقاتها بنلاقي لأ إنه في إنا
+
+225
+00:18:43,340 --> 00:18:47,860
+substitution إنه في أكسوجينة بتطلع أو أي إش تاني
+
+226
+00:18:47,860 --> 00:18:56,570
+بيطلع واضح؟طبعاً بشكل عام .. بشكل عام بيصير عملية
+
+227
+00:18:56,570 --> 00:19:00,690
+catalysis يعني هذا التفاعل أفضل ما يجرأ في وجود
+
+228
+00:19:00,690 --> 00:19:05,370
+كمية قليلة من الحامض الحامض بيعمل ايش؟ تسريع
+
+229
+00:19:05,370 --> 00:19:08,350
+للتفاعل يعني كل الناس اللي بيعملوا تفاعلات ال
+
+230
+00:19:08,350 --> 00:19:12,380
+aldiates و ال ketones لما يحطواsmall amount of an
+
+231
+00:19:12,380 --> 00:19:18,740
+acid H بيعمل عملية ايش؟ Catalysis تسريع للتفاعل
+
+232
+00:19:18,740 --> 00:19:23,380
+كيف عملية التسريع؟ انه انا لما بدي اضيف H plus
+
+233
+00:19:23,380 --> 00:19:27,240
+اللي هي الحامض اللي بسرع فيه التفاعل بتقدر تتخيل
+
+234
+00:19:27,240 --> 00:19:31,520
+ان هذه ال double bond اتجت هنا كأنها عملت O minus
+
+235
+00:19:31,520 --> 00:19:36,700
+ال O minus أخدت ال H plus صار عندى شغل زي هيك OH
+
+236
+00:19:36,700 --> 00:19:43,610
+الكربون شو هتصفى بهذه الحالة؟Full positive لاحظوا
+
+237
+00:19:43,610 --> 00:19:48,450
+يعني لو كنت أنا بتطلع هنا مع إضافة ال H plus في
+
+238
+00:19:48,450 --> 00:19:53,230
+البداية كأنه صارت عند الكربون positive charge
+
+239
+00:19:53,230 --> 00:19:58,740
+كاملة لو قلت أنا بدي أشغل بدون ال H plusالـ carbon
+
+240
+00:19:58,740 --> 00:20:03,280
+partially positive لأن هو أفضل للتفاعل يكون عندي
+
+241
+00:20:03,280 --> 00:20:09,460
+موجب كامل ولا موجب جزء موجب كامل عشان يصير التفاعل
+
+242
+00:20:09,460 --> 00:20:19,140
+سريع فعملية الحامض هي عملية catalysis انه احنا اول
+
+243
+00:20:19,140 --> 00:20:22,880
+ما بنبدأ نضيف الحامض اول ما بنبدأ بنضيف الحامض
+
+244
+00:20:24,190 --> 00:20:28,270
+واضح؟ بيعمل ان هنا OH بعد هيك لما بدو ييجي ال
+
+245
+00:20:28,270 --> 00:20:33,210
+enucleophile سالب على وجب كامل طبعا ممكن واحدة
+
+246
+00:20:33,210 --> 00:20:38,170
+تقول طيب ال catalyst بيدخل في التفاعل و بيطلع هنا
+
+247
+00:20:38,170 --> 00:20:44,250
+دخل ال H plus وين ال H plus؟ اللي .. اللي طلعت
+
+248
+00:20:45,050 --> 00:20:48,050
+املاحظين انتوا؟ يعني هانا جيبت انا H plus من
+
+249
+00:20:48,050 --> 00:20:51,710
+الحامض واتفاعلت ودخلت في التفاعل طب وين ال H plus
+
+250
+00:20:51,710 --> 00:20:54,950
+اللي طلعت؟ تنسوش انه النيوكليوفايل هذا اللي مكتوب
+
+251
+00:20:54,950 --> 00:20:59,150
+سالب هو أساسا في اشي سالب بنباعه بنشره
+
+252
+00:20:59,150 --> 00:21:03,250
+النيوكليوفايل نفسه بيكون معه H plus يعني مثلا
+
+253
+00:21:03,250 --> 00:21:08,570
+النيوكليوفايل ممكن يكون ايثانون اثل او H بالتالي
+
+254
+00:21:08,570 --> 00:21:13,670
+اللي هيتفاعل منه الاثل او هيطلع
+
+255
+00:21:15,020 --> 00:21:19,780
+H بلس اللي هي من وين كانت مع النيوكليوفايل أو مثلا
+
+256
+00:21:19,780 --> 00:21:25,800
+ممكن النيوكليوفايل يكون الميه اللي هي HO OH خلينا
+
+257
+00:21:25,800 --> 00:21:30,260
+نقول ال OH واحدة وهي ال H هذه ال H هي اللي بتعاود
+
+258
+00:21:30,260 --> 00:21:36,080
+تطلع فكأنه أنا صح جيبت H بلس من الحامض بس طلعت H
+
+259
+00:21:36,080 --> 00:21:40,860
+بلس المرافقة لإيش للنيوكليوفايل فجيبت H بلس طلعت H
+
+260
+00:21:40,860 --> 00:21:45,300
+بلس هاي ال catalystواضح مش ال catalyst بده يدخل و
+
+261
+00:21:45,300 --> 00:21:51,280
+يطلع من التفاعل طبعا مابدخلش نفس الذرع و بتطلع لأ
+
+262
+00:21:51,280 --> 00:21:55,440
+المهم انه دخل H بلصح من الحامض اللي طلعت مش من
+
+263
+00:21:55,440 --> 00:21:59,180
+الحامض من المي أو من ال إيثانول أو من الأمونيا زي
+
+264
+00:21:59,180 --> 00:22:04,290
+ما هنشوف بالأمثلة التفصيلية على أي حال هذه كلهاهذه
+
+265
+00:22:04,290 --> 00:22:09,450
+كلها عبارة عن المعادلة العامة، الآن المحاضرة هذه
+
+266
+00:22:09,450 --> 00:22:13,350
+أو جزء منها و المحاضرة الجاية بتصير كلها عبارة عن
+
+267
+00:22:13,350 --> 00:22:19,870
+عملية تطبيق، بس نغير ل nucleophile و نشوف إيش
+
+268
+00:22:19,870 --> 00:22:24,490
+النتج، نغير ل nucleophile و نشوف إيش النتج، واضح؟
+
+269
+00:22:28,550 --> 00:22:33,630
+أول تفاعل بدنا ناخده اللي هو تفاعل ال hydration
+
+270
+00:22:33,630 --> 00:22:40,030
+hydration معناه إضافة الماء أبسط ال nucleophile
+
+271
+00:22:40,030 --> 00:22:45,010
+لسه توي كنا نشرح عنه الميه الميه فيها أو تقدروا
+
+272
+00:22:45,010 --> 00:22:50,270
+تتخيلوا أنه فيها OH و فيه H طبعا لازم يكون واضح
+
+273
+00:22:50,270 --> 00:22:57,500
+عندكم تماما أن الميه مش مركب ايونيبمعنى الميه
+
+274
+00:22:57,500 --> 00:23:02,020
+molecular ولا ionic compound؟ molecular compound
+
+275
+00:23:02,020 --> 00:23:05,560
+HOH جزء واحد يعني لو تخيلتوا هاي قطعتين هدولة
+
+276
+00:23:05,560 --> 00:23:11,880
+بمثله ال OH .. OH زي هي قطعة واحدة لو كانت مركبة
+
+277
+00:23:11,880 --> 00:23:17,000
+ايون الميه .. لو كانت مركبة ايون هيكون زي هيكOH-
+
+278
+00:23:17,000 --> 00:23:21,400
+OH Plus المية عمرها ما كانت هذا خطأ شائع عند
+
+279
+00:23:21,400 --> 00:23:24,860
+الطلاب و أحيانا بنتقل عند المدارسين و بدرسوا غلط
+
+280
+00:23:24,860 --> 00:23:28,840
+للطلاب أنه أول ما نقول مية كان قالوا H Plus و OH
+
+281
+00:23:28,840 --> 00:23:34,560
+Minusلو الميه H plus و H minus كان صارت زي حمض
+
+282
+00:23:34,560 --> 00:23:37,460
+الكبريتيك و حمض الهيدروكلوريك و حرجت البني أدمين
+
+283
+00:23:37,460 --> 00:23:43,320
+الميه موليكيولر كومباوند قطعة واحدة مافيش فيها H
+
+284
+00:23:43,320 --> 00:23:50,880
+plus و H minus الدليل ع هيك ال Ionic compounds
+
+285
+00:23:50,880 --> 00:23:55,700
+عادة موصلة ممتازة للكهربا لأن فيها موجب و سالب
+
+286
+00:23:55,700 --> 00:24:03,350
+الان لو أخدت ميه نقيه 100% بتوصل كهربا؟و كذلك
+
+287
+00:24:03,350 --> 00:24:08,850
+الحال مثلا ال HCl كثير كثير منكوا بيعتقدوا اعتقادا
+
+288
+00:24:08,850 --> 00:24:14,730
+خاطئا ان ال HCl is an ionic compound انه H plus و
+
+289
+00:24:14,730 --> 00:24:20,930
+H minus ال HCl عمره ما كان H plus و H minus هو HCl
+
+290
+00:24:20,930 --> 00:24:26,900
+و اكتش بيعمل plus و minus لما ادوبه في الميهيعني
+
+291
+00:24:26,900 --> 00:24:32,820
+انتبهوا معاه كيف لو قولنا الميه لحالها ميه نقيه
+
+292
+00:24:32,820 --> 00:24:42,520
+هيه هو pure H2O فيلها conductivity ولا لا لو بتحكي
+
+293
+00:24:42,520 --> 00:24:47,370
+على ال conductivity في التواصل؟مالاش conductivity،
+
+294
+00:24:47,370 --> 00:24:51,210
+مابتوصلش ميّه، الآن لو الميّه .. طب ليش الناس
+
+295
+00:24:51,210 --> 00:24:54,570
+بتكهربوا من الميّه و بيموتوا النسوان من الغسلات؟
+
+296
+00:24:54,570 --> 00:25:02,870
+لأنه في عندي سولت أملاح في الميّه الأملاح ..
+
+297
+00:25:02,870 --> 00:25:06,250
+الميّه ملانة أملاح، الأملاح أيونات، و الأيونات
+
+298
+00:25:06,250 --> 00:25:10,030
+لأنه في سائل زي الميّه بتشرف فبصير توصيل الكهربا،
+
+299
+00:25:10,030 --> 00:25:15,280
+الميّه اللي فيها أملاح بتوصل كهرباواضح؟ الميه اللى
+
+300
+00:25:15,280 --> 00:25:18,820
+فيها أملح بتوصل الكهربا لكن لو حد أخد ميه نقية 100
+
+301
+00:25:18,820 --> 00:25:23,640
+% وشبك قطمين كهربا مش هتوصلهم فسبب توصيل الكهربا
+
+302
+00:25:23,640 --> 00:25:30,040
+الأملح اللى موجودة في الميه الآن الـHCL الـHCL
+
+303
+00:25:30,040 --> 00:25:38,540
+أساسا هو عبارة عن إيش؟ غاز الـHCL في أصله ..
+
+304
+00:25:38,540 --> 00:25:42,540
+بتكونوا تنتبهوا بالظبط للكلام الـHCL في أصله غاز
+
+305
+00:25:43,660 --> 00:25:50,980
+غاز واضح؟ الان طالما هذا غاز ممكن انا اكثفه و اعمل
+
+306
+00:25:50,980 --> 00:25:56,720
+منه hcl liquid اه يعني بيصير عندى في hcl gas و في
+
+307
+00:25:56,720 --> 00:26:05,560
+hcl liquid okay ال hcl liquid كسائل بيوصل كهربا؟
+
+308
+00:26:05,560 --> 00:26:11,890
+لأ لأ اطلاقاأطلاقا موليكيولار كومباوندر الـ HCl
+
+309
+00:26:11,890 --> 00:26:18,070
+موضوع ميّه ولا نقطة ميّه الان الـ HCl نفسه ممكن
+
+310
+00:26:18,070 --> 00:26:23,150
+أدوبه في ميّه بيصير HCl solution اللي احنا بنتعامل
+
+311
+00:26:23,150 --> 00:26:29,400
+معاه فاللي احنا بنتعامل معاه مش HCl liquidسوليوشن
+
+312
+00:26:29,400 --> 00:26:37,140
+محلول بيكون دايب بنسبة عادة المركز منه 37% الـ HCl
+
+313
+00:26:37,140 --> 00:26:43,760
+أكيوس HCl الـ aqueous بيوصل لإيش؟ لأنه هنا في هذه
+
+314
+00:26:43,760 --> 00:26:50,400
+الحالة بتصير تفاعل ان الـ HCl زائد الـ H2O بيعطينا
+
+315
+00:26:50,400 --> 00:26:57,750
+H3O plus زائد Cl minus كل هذه مراجعاتواضح؟ هانا
+
+316
+00:26:57,750 --> 00:27:02,530
+صار ايونات نتيجة ان ال HCl انحطت في الميه، لذلك
+
+317
+00:27:02,530 --> 00:27:08,510
+محلول الحامض عادة يوصل، ميه نقية بتوصلش، ميه فيها
+
+318
+00:27:08,510 --> 00:27:14,190
+ملح، ميه فيها حامض، بتوصل على طول، نقطة حامض واحدة
+
+319
+00:27:14,190 --> 00:27:17,850
+انحطت في الميه، بتصير توصل الكهربا، بس ميه نقية
+
+320
+00:27:17,850 --> 00:27:22,330
+مية في المية بتوصلش، واضح؟فهذه الأمور انتبهولها
+
+321
+00:27:22,330 --> 00:27:27,770
+عشانك احنا بنقول انه ماحدش يتخيل ان ال HOH is an
+
+322
+00:27:27,770 --> 00:27:32,950
+ionic compound HOH water is a molecular compound
+
+323
+00:27:32,950 --> 00:27:37,550
+مابيكونش مجسوم لايونات موجبة و سالبة مابيكونش
+
+324
+00:27:37,550 --> 00:27:42,210
+مجسوم لايونات موجبة و سالبة و لما عادة بتم التفاعل
+
+325
+00:27:42,210 --> 00:27:47,590
+.. بتم التفاعلمن خلال .. و هو كله ميّه .. و هو كله
+
+326
+00:27:47,590 --> 00:27:51,010
+ميّه من خلال زوج الإلكترونات اللي موجود على ال
+
+327
+00:27:51,010 --> 00:27:56,450
+Oxygen هذا زوج الإلكترونات بيجي هنا و الميّه عليها
+
+328
+00:27:56,450 --> 00:28:02,410
+ذرتين H بعدين بتفقد واحدة منهم بس مابيكونش عندي OH
+
+329
+00:28:02,410 --> 00:28:10,640
+minus لأ اللي بتهاجم الميّه كاملة HOH و بعدينبتفقد
+
+330
+00:28:10,640 --> 00:28:15,320
+H plus الخلاصة زي ما احنا اتفقنا قولنا انه ال
+
+331
+00:28:15,320 --> 00:28:19,980
+nucleophile بيجي بيتفاعل و ال c double bond O ايش
+
+332
+00:28:19,980 --> 00:28:28,100
+بتصير OH خلينا نلتزم بهذا الشكل اللي انتوا شايفينه
+
+333
+00:28:28,100 --> 00:28:32,740
+فكل مرة هتلاحظوا انه هنحطلكوا ال nucleophile بمربع
+
+334
+00:28:32,740 --> 00:28:40,660
+و ال c double bond Oبهذا الشكل ال circle نوعا ما
+
+335
+00:28:40,660 --> 00:28:47,020
+اللي هي بتصير OH زي ما قلنا المعادلة العامة
+
+336
+00:28:47,020 --> 00:28:50,620
+nucleophile بيهاجم و C double dot O بتصير إيش
+
+337
+00:28:50,620 --> 00:28:55,720
+عبارة عن OH هذا المركب لو بدي أحكي أنا مع ال
+
+338
+00:28:55,720 --> 00:29:02,870
+formaldehyde مع ال formaldehyde هو ال formalinيعني
+
+339
+00:29:02,870 --> 00:29:05,990
+هنا أنا إيش قاعد بحكي مع ال formaldehyde تحديدًا
+
+340
+00:29:05,990 --> 00:29:10,570
+بحط formaldehyde مع ميه بيعطينا ال formaldehyde
+
+341
+00:29:10,570 --> 00:29:14,150
+hydrate اللي هو ال formaldehyde اللي دايب في ميه
+
+342
+00:29:14,150 --> 00:29:17,310
+اللي هي شكله يعني لو بدنا نقولكوا ارسمولنا ال
+
+343
+00:29:17,310 --> 00:29:21,530
+formaldehyde hydrate هاي اللي موجود عندكم هو
+
+344
+00:29:21,530 --> 00:29:26,890
+formaldehyde متفاعل مع الميههو formaldehyde متفاعل
+
+345
+00:29:26,890 --> 00:29:32,150
+مع الميه الآن عد السؤال هل يا ترى كل ال aldehydes
+
+346
+00:29:32,150 --> 00:29:38,930
+بتتفاعل مع الميه و بيصير OH و هنا OH تانية الحقيقة
+
+347
+00:29:38,930 --> 00:29:43,090
+لأ يعني هذا التفاعل يكاد يكون محصور في عدد قليل من
+
+348
+00:29:43,090 --> 00:29:48,970
+ال aldehydes أشهرهم الميه بتعمل hydrate و في مركب
+
+349
+00:29:48,970 --> 00:29:56,000
+تاني في مركب تاني اللي هوالكلورال بنسميه كلورال
+
+350
+00:29:56,000 --> 00:30:03,980
+هيدريت هذا أصله هذا المركب أصله CHCCH3
+
+351
+00:30:03,980 --> 00:30:13,040
+الديهيد كان إيش CHCWOH و هذا CH3 الآن لو بدلت
+
+352
+00:30:13,040 --> 00:30:18,000
+التلاتة هيدروجين بكلور اللي هو ال
+
+353
+00:30:18,000 --> 00:30:21,680
+trichloroacetaldehyde
+
+354
+00:30:21,840 --> 00:30:30,960
+بيصير اسمه Cloride يعني هذا عبارة عن الديهايد لكن
+
+355
+00:30:30,960 --> 00:30:39,260
+ايش افضله؟ تلاتة هيدروجين بكلور فهذا لو كنا بنسميه
+
+356
+00:30:39,260 --> 00:30:48,560
+.. شو ممكن تسموه؟ الـ Trichloroacetaldehyde
+
+357
+00:30:48,560 --> 00:30:50,740
+وإله اسم شهرة
+
+358
+00:30:53,750 --> 00:30:58,730
+Echloral او الـ Trichloroacetal دي هادي هذا ال
+
+359
+00:30:58,730 --> 00:31:04,890
+Echloral لو فعلنا مع الميه بيعطينا ال Echloral
+
+360
+00:31:04,890 --> 00:31:14,290
+هايدريت هى اجت ال OH من الميه و ال OH اللى كانت
+
+361
+00:31:14,290 --> 00:31:21,200
+اصلا C double bond Oواضح؟ لكن لو بدنا نقول مثلا مع
+
+362
+00:31:21,200 --> 00:31:24,900
+ال .. propranaldehyde مع ال .. pentaldehyde
+
+363
+00:31:24,900 --> 00:31:31,340
+whatever بشكل عام التفاعل هذا عبارة عن اتزان بيظله
+
+364
+00:31:31,340 --> 00:31:36,040
+على هذا الشكل المنفصل يعني الاتزان بيكون أكثر
+
+365
+00:31:36,040 --> 00:31:42,000
+لليسار لل reactants منه لل products واضح؟ وين
+
+366
+00:31:42,000 --> 00:31:48,940
+بيكونوا ال products أكتر؟ في ال formaldehydeو فيه
+
+367
+00:31:48,940 --> 00:31:54,180
+ال chloral ال formaldehyde و ال chloral بالمناسبة
+
+368
+00:31:54,180 --> 00:32:01,080
+هذا ال chloral له تطبيق بيستعمل ك anesthetic مخدر
+
+369
+00:32:01,080 --> 00:32:08,220
+لكن مخدر لمين؟ للحيوانات اه تعون الطب ال بيطري
+
+370
+00:32:08,220 --> 00:32:12,180
+بيستعملوه يعني مخدر للحيوانات الخيول و الحصول لما
+
+371
+00:32:12,180 --> 00:32:17,980
+بيعملولهم عمليات و ما إلى ذلك اهفرغم إنها المعادلة
+
+372
+00:32:17,980 --> 00:32:22,300
+عامة تبع ال الديهايد والميّه لكن بشكل عام دائما
+
+373
+00:32:22,300 --> 00:32:25,940
+بيظلوا موجود أكتر على شكل الديهايد وين بيعمل ال
+
+374
+00:32:25,940 --> 00:32:30,960
+hydrate؟ بال formaldehyde و بال chloral في الحالات
+
+375
+00:32:30,960 --> 00:32:36,140
+التانية تقدر تقولوا كأنه ما صارش تفاعل الآن بعد
+
+376
+00:32:36,140 --> 00:32:43,120
+إضافة الميّه بدنا نبدأ نضيف أشياء تانية مثلا
+
+377
+00:32:43,120 --> 00:32:51,020
+الكحولات هتلاحظواهتلاحظوا أنه هيكون عندكم نفس
+
+378
+00:32:51,020 --> 00:32:58,300
+المنظر الـUQ file بتفاعل و الـCW.O بتصير OH يعني
+
+379
+00:32:58,300 --> 00:33:00,720
+لو كل مرة بدنا نقول Hi للـUQ file
+
+380
+00:33:03,200 --> 00:33:08,680
+بس خلصنا واضح؟ لكن احنا اليوم مش هنكمل في التفاعل
+
+381
+00:33:08,680 --> 00:33:13,540
+ال alcohols و توابعها بدنا نوقف لهذه اللحظة
+
+382
+00:33:13,540 --> 00:33:17,040
+المحاضرة الجاية ان شاء الله بنبدأ بنستمر كل
+
+383
+00:33:17,040 --> 00:33:21,820
+المحاضرة الجاية هتلاقوها على نفس النمط واضح؟ طبعا
+
+384
+00:33:21,820 --> 00:33:24,180
+احنا مش هنكمل اليوم عشان بدنا نعطيكوا براق
+
+385
+00:33:24,180 --> 00:33:24,900
+الامتحانات
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e20fad6bdf70d2adc11137ae61d86ca14108c662
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54.srt
@@ -0,0 +1,1758 @@
+1
+00:00:07,220 --> 00:00:10,900
+اليوم إن شاء الله بنكمل في موضوع ال stereo
+
+2
+00:00:10,900 --> 00:00:17,860
+chemistry طبعًا إذا سألناكم كل الكلام اللي درسناه 
+
+3
+00:00:17,860 --> 00:00:23,100
+الحصة الماضية كان عبارة عن تعريف ال enantiomers
+
+4
+00:00:23,100 --> 00:00:28,300
+يعني قولنا إن ال stereo isomers نوعين النوع الأول
+
+5
+00:00:29,180 --> 00:00:34,280
+إنانشو مارز والإنانشو مارز بيمتازوا إنهم جزيئات
+
+6
+00:00:34,280 --> 00:00:37,640
+الواحد منهم صورة الثاني في المرأة لكنها غير 
+
+7
+00:00:37,640 --> 00:00:43,340
+متطابقة هذا ملخص تقريبًا لكل المحاضرة الماضية زدنا
+
+8
+00:00:43,340 --> 00:00:49,720
+على ذلك إنه الإنانشو مارز كيف نقدر نميزهم عن بعض
+
+9
+00:00:49,720 --> 00:00:53,620
+نعمل لهم configuration بنسميه بمعنى نقول إنه هذا R
+
+10
+00:00:54,200 --> 00:00:58,420
+و هذا S وكل هالأمور بتاعتي اللي أخدنا عليها تطبيق
+
+11
+00:00:58,420 --> 00:01:05,060
+كافي اتذكروا معي لما حكينا ال enantiomers كفكرة
+
+12
+00:01:05,060 --> 00:01:10,300
+كيميائية بدناها بفكرة من الحياة قولنا في عندي
+
+13
+00:01:10,300 --> 00:01:13,980
+إيدين في عندي باب سيارة في عندي نضارات كل هدولة
+
+14
+00:01:13,980 --> 00:01:17,820
+يمثلوا enantiomers من ناحية المبدأ كلهم ممكن
+
+15
+00:01:17,820 --> 00:01:22,520
+اعرفهم enantiomers صورة بعض في المرأة غير متطابقة
+
+16
+00:01:23,060 --> 00:01:28,260
+واضح؟ الآن بدنا ناخد النوع الثاني من ال stereo
+
+17
+00:01:28,260 --> 00:01:35,280
+isomers وممكن نبدأ بتعريفه برضه من الحياة إيش هما
+
+18
+00:01:35,280 --> 00:01:41,540
+ال diastereomers واضح؟ ال diastereomers سهلين لو 
+
+19
+00:01:41,540 --> 00:01:46,740
+اتخيلتوا إن أنتم كنتوا على سبيل المثال في الطابور
+
+20
+00:01:46,740 --> 00:01:52,660
+الصباحي في المدرسة الثانوية ماشي؟ أول ما تكونوا في 
+
+21
+00:01:52,660 --> 00:01:55,120
+الطابور الصباحي شو بيعملولكوا في التمرينات
+
+22
+00:01:55,120 --> 00:02:03,020
+الرياضية بيعملولكوا أمامًا جانبًا أعلى أسفل الآن
+
+23
+00:02:03,020 --> 00:02:07,980
+تخيلوا عندكوا صورة هي أمامًا هذه الصورة نفترض أن أحد
+
+24
+00:02:07,980 --> 00:02:14,460
+أخد صورة بالكاميرا هيك أمامًا الآن هذه جانبًا .. واحد
+
+25
+00:02:14,460 --> 00:02:19,740
+كمان أخد صورة وحطلكوا الصورتين قدامكم وقالكم ما
+
+26
+00:02:19,740 --> 00:02:26,800
+العلاقة بين هدول الصورتين لحظو إحنا بنحكي عن نفس
+
+27
+00:02:26,800 --> 00:02:32,960
+الشخص .. the same weight أو the same molecular
+
+28
+00:02:32,960 --> 00:02:38,880
+weight طيب كويس، هل الارتباط اتغير ولا نفس مواقع 
+
+29
+00:02:38,880 --> 00:02:44,480
+الارتباط؟ بمعنى أن الاثنين مشبوكين في الكتف، ما فيش
+
+30
+00:02:44,480 --> 00:02:47,540
+تغير في الارتباط، الإيدة دي ما فكتش إجت على مكان
+
+31
+00:02:47,540 --> 00:02:51,700
+ثاني من الجسم، إذا أنا بحكي عن نفس الجزء بنفس
+
+32
+00:02:51,700 --> 00:02:57,380
+مواقع الارتباط، أين الاختلاف؟ في الشكل بالفراغ هذا
+
+33
+00:02:57,380 --> 00:03:02,600
+الشكل بيختلف عن هذا الشكل إذا هدول الصورتين كمرحلة 
+
+34
+00:03:02,600 --> 00:03:05,620
+أولى أقل إشي بيقبلوا منكوا تقولوا إن they are
+
+35
+00:03:05,620 --> 00:03:10,770
+stereoisomers They have the same molecular weight
+
+36
+00:03:10,770 --> 00:03:15,470
+but different arrangement in space هذا التعريف
+
+37
+00:03:15,470 --> 00:03:20,170
+العام لإيش؟ لل stereo isomers، الآن أعطوني كمان
+
+38
+00:03:20,170 --> 00:03:25,530
+علاقة إضافية بينهم، إيش علاقتهم مع بعض في المرأة؟
+
+39
+00:03:26,850 --> 00:03:31,330
+مش صورة بعض في المرايا، non-mirror images، واضح؟
+
+40
+00:03:31,330 --> 00:03:36,210
+هدول اللي إحنا بنسميهم إيش؟ Diastereomers، واضح؟
+
+41
+00:03:36,210 --> 00:03:41,850
+فال diastereomers عبارة عن stereoisomers بيكونوا مش
+
+42
+00:03:41,850 --> 00:03:45,010
+صورة بعض في المرايا، non-mirror image
+
+43
+00:03:45,010 --> 00:03:48,270
+stereoisomers، هاي تعريفهم، إيش تعريف 
+
+44
+00:03:48,270 --> 00:03:52,630
+ال diastereomers؟ Non Mirror Image Stereoisomers
+
+45
+00:03:52,630 --> 00:03:57,270
+الآن لو بدي أمثلة تطبيقية من الحياة حتى نفهم
+
+46
+00:03:57,270 --> 00:04:01,850
+الظاهرة قبل ما ننتقل على إيش على الذرات والجزيئات
+
+47
+00:04:01,850 --> 00:04:06,550
+والكيمياء يومًا إلى ذلك لو يا ترى أمسكت نضارة هادي 
+
+48
+00:04:06,550 --> 00:04:12,830
+بهذا الشكل هينمسكها هذه النضارة أنا جبت مفكات 
+
+49
+00:04:12,830 --> 00:04:17,930
+وفكتها وغيرت فيها ال bonding للارتباط؟ طيب لو أخدت
+
+50
+00:04:17,930 --> 00:04:22,450
+صورة النضارة وهي مفتوحة و صورة النضارة وهي مسكرة
+
+51
+00:04:22,450 --> 00:04:30,030
+ما العلاقة بين هدول الشكلين؟ Diastereomers نفس 
+
+52
+00:04:30,030 --> 00:04:35,110
+النضارة بنفس مواقع الارتباط لاختلاف فقط في الشكل
+
+53
+00:04:35,110 --> 00:04:39,970
+الفراغي الشكل الأول والشكل الثاني العلاقة بينهم 
+
+54
+00:04:39,970 --> 00:04:45,170
+إنهم مش صورة بعض في المرأة واضح؟ إذن هالنضارة هذه
+
+55
+00:04:45,170 --> 00:04:48,970
+لما تكون مفتوحة ومسكرة بتمثل بالنسبة لإيش؟
+
+56
+00:04:48,970 --> 00:04:53,490
+Diastereomers لو افترضت مثلًا إنه عندي علبة ممكن 
+
+57
+00:04:53,490 --> 00:04:58,040
+أكون فاتحة أنا بزاوية 180 درجة بدون ما أغير
+
+58
+00:04:58,040 --> 00:05:01,360
+الارتباطية ده الغطا مرتبط بالعلبة من هنا خلتها
+
+59
+00:05:01,360 --> 00:05:04,720
+بتسعين إيش العلاقة بين هدول الصورتين ده stereo
+
+60
+00:05:04,720 --> 00:05:08,640
+isomers سكرتها على الآخر إيش العلاقة ده stereo isomers
+
+61
+00:05:08,640 --> 00:05:12,780
+واضح فده stereo isomers عبارة عن stereo isomers لكن
+
+62
+00:05:12,780 --> 00:05:17,410
+they are non mirror image stereo isomers واضح؟
+
+63
+00:05:17,410 --> 00:05:21,990
+بيكونوا مش صورة بعض في المرأة الآن .. وين ممكن 
+
+64
+00:05:21,990 --> 00:05:28,390
+نبدأ نشوف ال diastereomers قبل ما نطلع على مركبات
+
+65
+00:05:28,390 --> 00:05:33,550
+فيها chiral centers مر علينا إحنا diastereomers ..
+
+66
+00:05:33,550 --> 00:05:36,930
+مر علينا diastereomers لكن بعد ذلك الوقت لإنا كنا
+
+67
+00:05:36,930 --> 00:05:41,370
+مش ماخدين تعريف الـ Stereochemistry وما إلى ذلك ما
+
+68
+00:05:41,370 --> 00:05:44,970
+قلناش إن هدولة دي هي الـ stereoisomers لو اتذكروا 
+
+69
+00:05:44,970 --> 00:05:51,210
+مثلًا مر علينا المركبات اللي كان فيها cis و trans
+
+70
+00:05:51,210 --> 00:05:56,130
+حوالين ال double bond لو تخيلنا مثلًا هذا المركب
+
+71
+00:05:56,130 --> 00:06:00,490
+اللي كان فيه ذرتين كلور على جهة واحدة مع المركب 
+
+72
+00:06:02,540 --> 00:06:07,700
+اللي فيه ذرتين كلور متعاكسات هذا كنا إيش نسميه؟
+
+73
+00:06:07,700 --> 00:06:14,900
+cis-dichloroethane وهذا trans-dichloroethane الآن
+
+74
+00:06:14,900 --> 00:06:19,520
+لو اطلعتوا على هدولة المركبين ال cis والترانس، 
+
+75
+00:06:19,520 --> 00:06:24,920
+اللهم نفس ال molecular weight؟ اللهم نفس مواقع
+
+76
+00:06:24,920 --> 00:06:27,980
+الارتباط، إيش بقصد أنا بنفس مواقع الارتباط؟ لو 
+
+77
+00:06:27,980 --> 00:06:31,920
+قلت هذه ال carbon الأولى متصلة بماذا؟ بـ كلورو
+
+78
+00:06:31,920 --> 00:06:35,820
+هيدروجين وهذه الكاربون الثانية بـ كلورو هيدروجين طب 
+
+79
+00:06:35,820 --> 00:06:39,620
+لو هنا بدأتش أطلع الكاربون الأولى بـ كلورو هيدروجين
+
+80
+00:06:39,620 --> 00:06:44,740
+الكاربون الثانية بـ كلورو هيدروجين أين الاختلاف بشكل 
+
+81
+00:06:44,740 --> 00:06:49,740
+الفراغي لكن مواقع الارتباط نفسها إن هنا الاثنين
+
+82
+00:06:49,740 --> 00:06:55,000
+الكلور على جهة واحدة وفي الجزء الثاني الاثنين
+
+83
+00:06:55,000 --> 00:07:02,700
+الكلور على جهتين متعاكستين إذا هل هدول المركبين يا
+
+84
+00:07:02,700 --> 00:07:08,280
+ترى صورة بعض في المرأة ولا لأ إذا هدول ال cis
+
+85
+00:07:08,280 --> 00:07:12,080
+trans isomers they are non mirror image
+
+86
+00:07:12,080 --> 00:07:16,540
+stereoisomers they are diastereomers واضح فال cis
+
+87
+00:07:16,540 --> 00:07:21,800
+وال trans isomers they are diastereomers شفتوا
+
+88
+00:07:21,800 --> 00:07:26,340
+إنتم غير ال cis وال trans isomers في مكانين حوالين
+
+89
+00:07:26,340 --> 00:07:31,820
+ال double bond وفي الأشكال الحلقية طلعوا معي لما
+
+90
+00:07:31,820 --> 00:07:37,020
+كان مثلًا نكون عندنا cyclopentene cyclopentene عادي 
+
+91
+00:07:37,020 --> 00:07:40,900
+مش pentene cyclopentene نحط مثلًا ال chlorine لفوق 
+
+92
+00:07:40,900 --> 00:07:45,960
+و ال chlorine التالية لفوق و هاي hydrogens هذا إيه 
+
+93
+00:07:45,960 --> 00:07:50,420
+المركب؟ هذا ال cis compound الآن لو حطينا chlorine
+
+94
+00:07:50,420 --> 00:07:55,710
+لفوق و chlorine لتحت مثلًا ال Trans هدولة الشكلين 
+
+95
+00:07:55,710 --> 00:08:02,130
+أيضًا stereo isomers لكن non-mirror image stereo
+
+96
+00:08:02,130 --> 00:08:05,670
+isomers، this is trans isomers، so they are the 
+
+97
+00:08:05,670 --> 00:08:12,400
+stereoisomers، واضح؟ بنقدر نقول إن كمثال كمثال على
+
+98
+00:08:12,400 --> 00:08:16,620
+الدياستيريو مارز ال cis trans isomers سواء كانوا cis
+
+99
+00:08:16,620 --> 00:08:21,220
+trans isomers حوالين ال double bond أو كانوا cis
+
+100
+00:08:21,220 --> 00:08:26,420
+trans isomers حوالين حلقة يعني فوق وتحت مستوى
+
+101
+00:08:26,420 --> 00:08:32,680
+الحلقة هذا أحد الأنواع الآن بيجينا نوع تالي بيجينا
+
+102
+00:08:32,680 --> 00:08:37,240
+نوع تالي من ال cis trans من الدياستيريو مارز عفواً
+
+103
+00:08:37,770 --> 00:08:43,230
+اللي هو لما بتصير عندي في المركب مش chiral center
+
+104
+00:08:43,230 --> 00:08:48,330
+واحد أكثر من chiral center اتذكروا معي لما كان
+
+105
+00:08:48,330 --> 00:08:52,030
+المركب يكون في chiral center واحد يعني الكربون
+
+106
+00:08:52,030 --> 00:08:55,850
+عليها أربع روابط جداش كان يطلع عندي المركبات أو 
+
+107
+00:08:55,850 --> 00:09:03,910
+isomers اثنين ال R وال S لما بيكون عندي one chiral
+
+108
+00:09:03,910 --> 00:09:08,870
+center بيطلع عندي مركبين ال R وال S الآن السؤال
+
+109
+00:09:08,870 --> 00:09:13,450
+لما بيصير عندي أكثر من chiral center جداش بده يطلع
+
+110
+00:09:13,450 --> 00:09:19,470
+isomers يعني مثلًا نفترض اثنين إحنا بنقول القاعدة
+
+111
+00:09:19,470 --> 00:09:27,430
+في قاعدة بتحدد لعدد ال stereo isomers بتقول إن أقصى
+
+112
+00:09:27,430 --> 00:09:34,490
+شيء ممكن يطلع عنده two to the n واضح؟ أقصى شيء
+
+113
+00:09:34,490 --> 00:09:38,570
+ممكن يطلع عنده two to the n يعني لو عنده two
+
+114
+00:09:38,570 --> 00:09:43,150
+chiral centers، بدأ أقول اثنين أس اثنين، قداش
+
+115
+00:09:43,150 --> 00:09:49,030
+المجموع؟ أربعة بمعنى ممكن يكون عندي أربع مركبات
+
+116
+00:09:49,030 --> 00:09:53,850
+مختلفة وممكن يكون أقل، بس مش ممكن يكون أكثر، 
+
+117
+00:09:53,850 --> 00:10:00,470
+بمعنى أن القاعدة ما بتعطينيش العدد بالظبط، بتكون 
+
+118
+00:10:00,470 --> 00:10:07,060
+لأقصى شيء ممكن أربعة، ممكن يكون عندك أقل واضح
+
+119
+00:10:07,060 --> 00:10:11,860
+للكلام؟ إذا أنا عشان أعرف العدد بالظبط بدي شوية
+
+120
+00:10:11,860 --> 00:10:16,760
+شغل بدي أرسم بدي أتعلم أشياء إضافية الآن لو افترضت 
+
+121
+00:10:16,760 --> 00:10:22,020
+مثلًا إن عندي ثلاثة chiral centers موجودين في
+
+122
+00:10:22,020 --> 00:10:27,300
+جزئي قداش أقصى ما يمكن يكون عندي مركبات اثنين أقص
+
+123
+00:10:27,300 --> 00:10:32,300
+ثلاثة مش ثلاثة أقصى اثنين ثمانية اثنين أقصى ثلاثة
+
+124
+00:10:32,300 --> 00:10:37,080
+ثمانية اثنين في اثنين في اثنين واضح؟ ثمانية لحد
+
+125
+00:10:37,080 --> 00:10:43,300
+الأقصى خلينا نشوف لما يكونوا عندنا اثنين chiral
+
+126
+00:10:43,300 --> 00:10:49,000
+centers بلاش نصعب على حالنا الأمور ناخد مثلًا مركب 
+
+127
+00:10:49,000 --> 00:10:52,480
+زي هذا لو تخيلنا إننا لدينا ذرة كربون اثنين،
+
+128
+00:10:52,480 --> 00:10:56,880
+ثلاثة، أربعة، خمسة، هذا إثيل وحطينا على موقع اثنين
+
+129
+00:10:56,880 --> 00:11:02,250
+كلور وعلى موقع ثلاثة كلور إنتم الآن يمكن تستغربوا 
+
+130
+00:11:02,250 --> 00:11:06,450
+إن كنتوا تقولوا إن إيش اسم هذا المركب two three
+
+131
+00:11:06,450 --> 00:11:10,090
+dichlorobentane
+
+132
+00:11:10,090 --> 00:11:14,430
+زي اللي كنا نرسملكوا كاربون، اثنين، ثلاثة، أربعة، 
+
+133
+00:11:14,430 --> 00:11:18,610
+خمسة وببساطة نحط كلور وكلور ونام the following
+
+134
+00:11:18,610 --> 00:11:27,360
+compound إيش تسموه؟ 2,3-dichlorobentane واضح؟ اللي 
+
+135
+00:11:27,360 --> 00:11:32,000
+هتتفاجؤوا فيه الآن إن أنتم لو روحتوا على المخزن
+
+136
+00:11:32,000 --> 00:11:35,820
+تشتريوا 2,3-dichlorobentane هيقولكوا ما فيش عندي 2
+
+137
+00:11:35,820 --> 00:11:40,890
+,3-dichlorobentane هيك لوحده في عندي أربع مركبات
+
+138
+00:11:40,890 --> 00:11:45,530
+كلهم بنطبق عليهم two three dichlorobentano أنتم
+
+139
+00:11:45,530 --> 00:11:48,970
+حددوا إيش اللي بدكوا إياه ليش لأنه هذه ال carbon
+
+140
+00:11:48,970 --> 00:11:53,650
+chiral center خليني نطلع على رسمها لما أجي أطلع
+
+141
+00:11:53,650 --> 00:11:57,810
+على ال carbon رقم اثنين إيش المجموعات أقلها مثل
+
+142
+00:11:57,810 --> 00:12:02,710
+اتش كلور وكمان مجموعة كبيرة إذا هنا في عندي 
+
+143
+00:12:02,710 --> 00:12:06,810
+chiral center ولا لأ أكيد لو أجي أطلعك على ال 
+
+144
+00:12:06,810 --> 00:12:12,010
+carbon الثانية Chlore و H و إثل ومجموعة كبيرة برضه
+
+145
+00:12:12,010 --> 00:12:16,370
+كايرال سنتر إذا كام كايرال سنتر عندي في هذا الجزء؟
+
+146
+00:12:16,370 --> 00:12:21,750
+two كايرال سنتر لما أجي بدي أرسم الاحتمالات
+
+147
+00:12:21,750 --> 00:12:27,130
+الممكنة كلها خلينا نجرب نحط ال مثل لفوق وال إثل
+
+148
+00:12:27,130 --> 00:12:31,730
+لتحت ونحط ال chlore و ال H ذرتين لchlore البساطة
+
+149
+00:12:31,730 --> 00:12:38,380
+يبدو يكونوا عكس بعض يبدو يكونوا جانب بعض في غير هيك
+
+150
+00:12:38,380 --> 00:12:43,880
+له احتمال؟ يا إما عكس بعض، يا إما جانب بعض، لكن كل
+
+151
+00:12:43,880 --> 00:12:49,220
+واحد من هدول له صورة في المرآة، كل واحد من هدول له 
+
+152
+00:12:49,220 --> 00:12:52,880
+صورة في المرآة، بمعنى لو اتخيلت إن هذا المركب اللي
+
+153
+00:12:52,880 --> 00:12:59,080
+هو بيمثل المركب الأول صورته في المرآة هذا المركب،
+
+154
+00:12:59,080 --> 00:13:02,800
+واضح؟ هاي ال H عكس ال H، ال CL عكس ال CL، كل حاجة
+
+155
+00:13:02,800 --> 00:13:07,670
+عكس الثانية، نفس الشيء لو جيت تطلع تهانة على 
+
+156
+00:13:07,670 --> 00:13:15,330
+المركب هذا، واضح؟ إذن كمان هذا صورة الثالث في 
+
+157
+00:13:15,330 --> 00:13:19,690
+المرأة، الآن يا ترى، هل فعلاً معقول إن هدول
+
+158
+00:13:19,690 --> 00:13:25,070
+المركبات الأربع مختلفات؟ هل معقول إنهم مختلفات؟
+
+159
+00:13:25,070 --> 00:13:29,150
+أفضل شيء عشان أشوف الاختلاف إن على كل chiral
+
+160
+00:13:29,150 --> 00:13:32,910
+Center أحدد configuration أشوف ال configuration
+
+161
+00:13:32,910 --> 00:13:37,690
+اللي عندي R ولا S أشوف ال configuration اللي عندي 
+
+162
+00:13:37,690 --> 00:13:44,270
+R ولا S فلو أجيت مثلًا أنا كله حاطه هنا ممكن آخد 
+
+163
+00:13:44,270 --> 00:13:48,790
+مثلين ثلاثة نعملهم معاكم بسرعة لو أجينا هنا سألنا
+
+164
+00:13:48,790 --> 00:13:54,850
+مثلًا عن موقع اثنين أنهي أقل مجموعة الهيدروجين ممتاز
+
+165
+00:13:54,850 --> 00:13:59,790
+طيب لو بدي أبدأ أتحرك من الأعلى للأقل للأقل هاي ال 
+
+166
+00:13:59,790 --> 00:14:06,310
+carbon هذا متصل فيها كلور و carbon و carbon أنهي 
+
+167
+00:14:06,310 --> 00:14:11,290
+أعلى واحدة بعدها ال carbon اللي تحت اللي حاملة
+
+168
+00:14:11,290 --> 00:14:15,610
+كلور و إثل و اتش وبعدها اللي فوق إذا كيف الحركة
+
+169
+00:14:15,610 --> 00:14:17,790
+اللي موجودة عندي الآن هنا حوالينا
+
+170
+00:14:21,210 --> 00:14:29,050
+عكس عقارب الساعة فكأنه المركب S لكن لأنه هذه جاي 
+
+171
+00:14:29,050 --> 00:14:32,990
+على الجانب، شو بيطلع؟ R، هذا الكلام حكيناه بشكل
+
+172
+00:14:32,990 --> 00:14:39,890
+تفصيل الحصة الماضية، إذا هذا الموقع 2R، واضح؟ هذا
+
+173
+00:14:39,890 --> 00:14:44,790
+الموقع 2 ماخد ال configuration R، الآن لو جينا على
+
+174
+00:14:44,790 --> 00:14:55,020
+الموقع 3، والأقل مجموعة نمر واحد، اثنين، هذه
+
+201
+00:16:56,450 --> 00:17:01,450
+الجزء planner في مستوى واحد كان هذا و هذا بنطبقوا
+
+202
+00:17:01,450 --> 00:17:05,230
+على بعض لكن عدم الانطباق لأن هذا و هذا they are 
+
+203
+00:17:05,230 --> 00:17:09,910
+not planner مش في مستوى واحد، واضح الفكرة هنا؟
+
+204
+00:17:09,910 --> 00:17:12,930
+هدولة مش في مستوى واحد، إذن هدولة واحد واتنين
+
+205
+00:17:12,930 --> 00:17:16,430
+العلاقة بينهم هنا، مش مفهوم. الآن، لو إجينا
+
+206
+00:17:16,430 --> 00:17:21,990
+واطلعنا على تلاتة واربعة، برضه إذا حددنا هنا two
+
+207
+00:17:21,990 --> 00:17:29,650
+R، three S، وبعدين هنا two S، three R، R إقبالها
+
+208
+00:17:29,650 --> 00:17:35,980
+S، وS إقبالها R، بمعنى إنه في جزء كل نقطة عكس إيش؟
+
+209
+00:17:35,980 --> 00:17:39,740
+التانية، وهذا اللي بيصير في المرأة، يعني لما أنا
+
+210
+00:17:39,740 --> 00:17:44,840
+بجب في المرأة، بعمل زي هيك، الصورة كيف بتكون؟ كل
+
+211
+00:17:44,840 --> 00:17:48,400
+نقطة لازم تكون عكس التانية، كل نقطة في الصورة، لو
+
+212
+00:17:48,400 --> 00:17:52,720
+نقطة واحدة اختلت، بتبطل نحكي عن صورة في المرأة،
+
+213
+00:17:52,720 --> 00:17:57,560
+واضح؟ إذن، تلاتة وأربعة، برضه العلاقة بينهم
+
+214
+00:17:57,560 --> 00:18:01,820
+enantiomers، واضح؟ برضه العلاقة بين تلاتة وأربعة
+
+215
+00:18:01,820 --> 00:18:06,310
+enantiomers الآن لو يقترح إيجي تقولي ما العلاقة بين
+
+216
+00:18:06,310 --> 00:18:11,930
+المركب واحد و تلاتة اتطلعوا انتوا بالنظر شوفولي بس
+
+217
+00:18:11,930 --> 00:18:18,890
+مواقع ال CL هيك العلمة بالأحمد هل هدولا التنين
+
+218
+00:18:18,890 --> 00:18:23,950
+صورت بعض في المرأة بس هم مش صورت بعض في المرأة إذا
+
+219
+00:18:23,950 --> 00:18:27,970
+الواحد و تلاتة diastereomers طب لو قولت العلاقة
+
+220
+00:18:27,970 --> 00:18:29,170
+بين واحد و أربعة
+
+221
+00:18:33,380 --> 00:18:39,820
+طب لو قلت العلاقة بين اتنين و تلاتة لو قلت العلاقة
+
+222
+00:18:39,820 --> 00:18:45,900
+بين اتنين و اربعة diastereomers واضح؟ إذا هنا
+
+223
+00:18:45,900 --> 00:18:52,360
+لما انا بأعمل two chiral centers و بطلع اربع
+
+224
+00:18:52,360 --> 00:18:55,520
+مركبات في الحالة دي طلع عند اربع مركبات بعد شوية
+
+225
+00:18:55,520 --> 00:18:59,980
+بناخد حالة بصيروا المركبات فيها جديشأقل من أربعة
+
+226
+00:18:59,980 --> 00:19:03,480
+بلاحظ أنه فيهم مركبين enantiomers وفيهم مركبين
+
+227
+00:19:03,480 --> 00:19:07,240
+تانيين enantiomers لكن أي فرد من هذا ال enantiomers
+
+228
+00:19:07,240 --> 00:19:14,440
+مع المجموعة الثانية بيمثل diastereomers واضح فال
+
+229
+00:19:14,440 --> 00:19:17,580
+diastereomers زي تعريفهم they are non mirror image
+
+230
+00:19:17,580 --> 00:19:23,200
+stereoisomers زي ما قلنالكوا العدد الأقصى ما يمكن
+
+231
+00:19:24,610 --> 00:19:28,330
+في هذه الحالة two to the power two اتنين أقصى اتنين
+
+232
+00:19:28,330 --> 00:19:36,610
+بيساوي عندنا أربعة واضح؟ الان لو بتكنتيجوا من خلال
+
+233
+00:19:36,610 --> 00:19:40,650
+الرموز بعيدا عن الأشكال لو بتكنتيجوا من خلال
+
+234
+00:19:40,650 --> 00:19:45,110
+الرموز و تعرفوا ليه ان هل ياتورا هدولة بمثله
+
+235
+00:19:45,110 --> 00:19:49,550
+enantiomers ولا diastereomers نتطلع بنظرة أوسع
+
+236
+00:19:49,550 --> 00:19:57,460
+على الرموز إذا في الرموز اللي عندى كلمجموعة عكس
+
+237
+00:19:57,460 --> 00:20:04,700
+التانية كل واحدة عكس التانية 2R 2S 3R 3S أو في
+
+238
+00:20:04,700 --> 00:20:10,810
+الحالة دي 2R 2S, 3S, 3R إذا كل حاجة عكس التانية،
+
+239
+00:20:10,810 --> 00:20:15,490
+معنا ذلك العلاقة بين القطعتين المحددات enantiomers و
+
+240
+00:20:15,490 --> 00:20:20,470
+مارس، الآن لو شيء كان عكس التاني و شيء زي التاني،
+
+241
+00:20:20,470 --> 00:20:26,010
+معنا ذلك diastereomers، واضح؟ لو شيء عكس التاني و
+
+242
+00:20:26,010 --> 00:20:30,090
+شيء زي التاني، معنا ذلك diastereomers، طب لو كل
+
+243
+00:20:30,090 --> 00:20:36,910
+إشي زي بعض، بيكون the same compound واضح؟ انا هذا
+
+244
+00:20:36,910 --> 00:20:41,710
+الكلام .. هذا الكلام ليش بحكيه لكم؟ لأنه بصراحة مش
+
+245
+00:20:41,710 --> 00:20:45,950
+دائما .. مش دائما بنجيبلكوا الأمور وردية والرسمة
+
+246
+00:20:45,950 --> 00:20:51,550
+واضحة زي هال ويكون بإمكانكم على السبورة بسهولة
+
+247
+00:20:51,550 --> 00:20:57,610
+اتحددوا العلاقة ما بين قطعتين فبصير في هذه الحالة
+
+248
+00:20:57,610 --> 00:21:01,920
+أسهل شي عندكم أنكم اتحددوا إيش؟الـ configuration
+
+249
+00:21:01,920 --> 00:21:06,960
+حتى لو عندي one chiral center حتى لو عندي one
+
+250
+00:21:06,960 --> 00:21:11,360
+chiral center ممكن أرسمه إلكم بحيث لما تطلعوا أكون
+
+251
+00:21:11,360 --> 00:21:15,580
+رسمه بطرق مختلفة ما تقدروش تقولولي ما العلاقة بين
+
+252
+00:21:15,580 --> 00:21:20,800
+جزيين خلينا ناخد مثال لو تخيلنا إنه في عندنا هذا
+
+253
+00:21:20,800 --> 00:21:25,560
+المركب حطينا chlorine و H و Br
+
+254
+00:21:36,370 --> 00:21:40,930
+الان اللي مركزنا انك تشوف الأمور في المرايا
+
+255
+00:21:44,540 --> 00:21:49,740
+ولا عمرها شايفة إيش فيهم جايب سهولة في المرأة لكن
+
+256
+00:21:49,740 --> 00:21:54,060
+لو أنا قولت هذا المركب و هذا المركب إيش إسمهم؟ هذا
+
+257
+00:21:54,060 --> 00:21:58,300
+عبارة عن two carbon زي ال carbon الأولى حملة
+
+258
+00:21:58,300 --> 00:22:02,160
+bromochlor و ال carbon التانية مثل و هذه نفس
+
+259
+00:22:02,160 --> 00:22:04,840
+الإشعار carbon الأولى حملة bromochlor و ال carbon
+
+260
+00:22:04,840 --> 00:22:10,020
+التانية مثل إذا كل واحد من هدول إيش اسمه? one
+
+261
+00:22:10,020 --> 00:22:16,910
+bromo one chloroهي atom one وهي atom two وهي الجزء
+
+262
+00:22:16,910 --> 00:22:23,190
+البساطة وهي atom one وهي atom two one bromo one
+
+263
+00:22:23,190 --> 00:22:32,530
+chloro اثنين الاتنين هنا one bromo one chloro
+
+264
+00:22:32,530 --> 00:22:38,150
+اثنين نعم
+
+265
+00:22:39,580 --> 00:22:42,700
+ليش non-stereoisomers؟ نيجي نتفاهم معاك، إن الله
+
+266
+00:22:42,700 --> 00:22:45,840
+يحب الصابرين، قولنا الـ Stereoisomers فيهم نفس
+
+267
+00:22:45,840 --> 00:22:50,200
+الذرات، بس بيضال عندى قصة مواقع الارتباط، الآن هنا
+
+268
+00:22:50,200 --> 00:22:55,720
+إيش عندك؟ Carbon متصلة بماذا؟ أكلور و بروم و أتش و
+
+269
+00:22:55,720 --> 00:23:00,800
+مثل، وهنا إيش عندك؟ Carbon متصلة بماذا؟ أكلور و
+
+270
+00:23:00,800 --> 00:23:05,060
+بروم و أتش و مثل إذا ببساطة هدول الاتنين عندهم واحد
+
+271
+00:23:05,060 --> 00:23:10,000
+من احتمالين اما بيكونوا نفس المركب مرسوم بطرق
+
+272
+00:23:10,000 --> 00:23:13,020
+مختلفة و احنا مر علينا سابق ان المركب بنرسمه بطرق
+
+273
+00:23:13,020 --> 00:23:18,720
+كتيرة او بيكونوا enantiomers ولا ثالث لا دول
+
+274
+00:23:18,720 --> 00:23:21,580
+احتمالين يعني لما بيكون عندى one chiral center
+
+275
+00:23:21,580 --> 00:23:26,010
+هدول يا بيكونوا نفس المركب مرسوم بطرق مختلفة
+
+276
+00:23:26,010 --> 00:23:29,110
+يا بيكونوا enantiomers وقت إيش بيكونوا نفس المُركّب
+
+277
+00:23:29,110 --> 00:23:33,710
+إذا إتيت عملت configuration لجيت هذا R و هذا R بس
+
+278
+00:23:33,710 --> 00:23:37,170
+تنتج أنه the same compound إذا إتيت عملت
+
+279
+00:23:37,170 --> 00:23:41,230
+configuration لجيت هذا S و هذا S the same compound
+
+280
+00:23:41,230 --> 00:23:45,470
+إذا لجيت هذا R و هذا S بدهم يكونوا enantiomers
+
+281
+00:23:45,470 --> 00:23:50,470
+أو هذا S و هذا R واضح؟ إذا تحديد العلاقة بينهم
+
+282
+00:23:50,470 --> 00:23:56,860
+عشان أحددها لازم أحددالـ Configuration أسهلليش أحد
+
+283
+00:23:56,860 --> 00:24:00,400
+الـ Configuration هاي أقل مجموعة أنا حددتها أكيد
+
+284
+00:24:00,400 --> 00:24:04,480
+في منكناس ناشطين جدا بيقدروا يقولولي إيش هذا
+
+285
+00:24:04,480 --> 00:24:13,900
+المركب أين باتحرك أنا بـR بعدها اكلور بعدها مثل
+
+286
+00:24:13,900 --> 00:24:18,320
+ماشي عكس عقارة بسيارة نفسها إذا هذا S إذا هذا
+
+287
+00:24:18,320 --> 00:24:22,600
+المركب لو بدي أشوف إيش اسمه S one bromo one chloro
+
+288
+00:24:22,600 --> 00:24:28,920
+اثنين الآن لو اتيت على هذا المُركّب بطلّح هنا عند
+
+289
+00:24:28,920 --> 00:24:35,740
+بي ار اكلور مثل ماشي بهذا الشكل يتبين R و هذا على
+
+290
+00:24:35,740 --> 00:24:41,740
+الجانب S إذا هذا R إذا ما العلاقة بينهم they are
+
+291
+00:24:41,740 --> 00:24:46,320
+enantiomers شوفتوا كيف انا عرفت العلاقة بينهم من
+
+292
+00:24:46,320 --> 00:24:53,280
+خلال ال configuration واضح؟ طيب، الآن هذا الكلام
+
+293
+00:24:53,280 --> 00:24:57,400
+سهل، يعني لو بدنا نيجي نسهلكم في الامتحان مركبين ب
+
+294
+00:24:57,400 --> 00:25:00,840
+one chiral center، شو العلاقة بينهم؟ بدكم تحددوا
+
+295
+00:25:00,840 --> 00:25:04,440
+ال configuration، يا بيطلع نفس الاشي the same
+
+296
+00:25:04,440 --> 00:25:09,680
+compound، يا بيطلع enantiomers هذا الكلام مرتبط
+
+297
+00:25:09,680 --> 00:25:14,700
+لما يكون عندكم one chiral center لما يصير عندكم
+
+298
+00:25:14,700 --> 00:25:20,490
+two chiral centers بصير عندكم مش احتمالي الا المركب
+
+299
+00:25:20,490 --> 00:25:26,790
+تلاتة يا بيكونوا the same compound لما يطلع ال R و
+
+300
+00:25:26,790 --> 00:25:31,770
+ال S لتنتين نفس الاشي the same compound يا بيكونوا
+
+301
+00:25:31,770 --> 00:25:37,130
+enantiomers لما كل واحدة عكس التانية يا بيكونوا
+
+302
+00:25:37,130 --> 00:25:40,810
+diastereomers لما واحدة عكس التانية و واحدة زي
+
+303
+00:25:40,810 --> 00:25:46,560
+التانية واضح؟ زي هذا و هذا مثلا طلعوا هنا R و R زي
+
+304
+00:25:46,560 --> 00:25:53,040
+بعض أو عكس بعض كأن واحدة زي التانية واحدة عكس
+
+305
+00:25:53,040 --> 00:25:57,400
+التانية فكأنه جزء جزء منهم بين معكوس في المرايا
+
+306
+00:25:57,400 --> 00:26:01,720
+والجزء التاني نفس الاشي فبالمجمل بيكون مش صورة بعض
+
+307
+00:26:01,720 --> 00:26:05,540
+في المرايا بيكون عبارة عن diastereomers طبعا أكيد
+
+308
+00:26:05,540 --> 00:26:11,380
+بيلزم أن نعمل مثال الآن على هذه العلاقة نرسم أو
+
+309
+00:26:11,380 --> 00:26:19,360
+ناخد جزيئات ونقول ما العلاقة بين هذولا الشكلين
+
+310
+00:26:19,360 --> 00:26:31,280
+خلّينا
+
+311
+00:26:31,280 --> 00:26:38,120
+ننظر لهذه الأمثلة واضح؟
+
+312
+00:26:38,120 --> 00:26:42,240
+المركب الأول شبيه بالكلام اللي قبل شوية حكينا
+
+313
+00:26:42,240 --> 00:26:47,100
+ولاحظوا هنا لما بتيجوا تتطلعوا للوهلة الأولى
+
+314
+00:26:47,100 --> 00:26:51,680
+بتكونوا مش عارفين إيش أسهل إيش تعملوه تحددوا
+
+315
+00:26:51,680 --> 00:26:56,720
+configuration فهي أقل مجموعة وهي هنا أقل مجموعة من
+
+316
+00:26:56,720 --> 00:27:02,080
+تعطينا هذا المركب R ولا S أنا بتحرك بي R كلور مثل
+
+317
+00:27:02,080 --> 00:27:12,340
+R وهنا بتحرك بي R كلور مثل R طب دو S طب دو R طلع
+
+318
+00:27:12,340 --> 00:27:16,940
+هذا R و هذا R إذا هدولا بمثله نفس الجزيق مرسوم
+
+319
+00:27:16,940 --> 00:27:22,500
+بطرق مختلفة okay؟ الأن لو أخدنا المثال التاني لو
+
+320
+00:27:22,500 --> 00:27:26,840
+أخدنا المثال التاني هنا هذا عبارة عن جزيق إيش لو
+
+321
+00:27:26,840 --> 00:27:34,560
+بدي أسميه بالمجمل؟ فيه ذرة مثل كاربون كاربون مثل
+
+322
+00:27:34,560 --> 00:27:40,400
+إذا هذا جزيق بيوتين بيوتين على موقع اتنين في
+
+323
+00:27:40,400 --> 00:27:45,540
+البيوتين، شو عندكم؟ على موقع تلاتة، كلور، إذا هذا
+
+324
+00:27:45,540 --> 00:27:48,220
+لو أنا قولت، جايب بس هذا القطع الواحدة على
+
+325
+00:27:48,220 --> 00:27:52,300
+الامتحان و جايبكم name the following molecule إيش
+
+326
+00:27:52,300 --> 00:27:58,400
+هنقول عنه؟ two-chloro three
+
+327
+00:27:58,400 --> 00:28:06,620
+-chloro-butane الآن، ضال عندي مشكلتين، شو هم؟ إنه
+
+328
+00:28:06,620 --> 00:28:11,490
+في عندي two chiral centers كل واحد chiral center
+
+329
+00:28:11,490 --> 00:28:15,590
+لازم أحدد ال configuration حواليه كل chiral center
+
+330
+00:28:15,590 --> 00:28:19,730
+لازم أحدد ال configuration حواليه فلو أجيت على
+
+331
+00:28:19,730 --> 00:28:23,410
+موقع اتنين و قلت هي أقل مجموعة و على موقع تلاتة هي
+
+332
+00:28:23,410 --> 00:28:29,430
+أقل مجموعة كيف أنا بدي أتحرك أنا في ال ball ال
+
+333
+00:28:29,430 --> 00:28:32,650
+carbon هادم الكبير اللي حامل شغلاتي كتير على المثل
+
+334
+00:28:32,650 --> 00:28:36,170
+إذا
+
+335
+00:28:36,170 --> 00:28:43,640
+ال two أنا عبارة عن إيش؟ S مظبوط؟ لو جيت هنا الكلور
+
+336
+00:28:43,640 --> 00:28:53,120
+الكربون هادى المثلث من الأعلى إلى الأقل برضه 3S
+
+337
+00:28:53,120 --> 00:29:01,600
+إذا هذا المركب ال 2 فيه S و ال 3 فيه S إذا 2S 3S
+
+338
+00:29:01,600 --> 00:29:05,740
+نيجي للجزء التانى اللى هو نفس الشي طوف روم و 3
+
+339
+00:29:05,740 --> 00:29:06,680
+كلور و بيوتين
+
+340
+00:29:09,410 --> 00:29:17,430
+أقل مجموعة وهذا موقع تلاتة بعدين من واحد حركة الآن
+
+341
+00:29:17,430 --> 00:29:25,790
+بعدها الكاربون هادي بعدها
+
+342
+00:29:25,790 --> 00:29:35,410
+PR إذا PR لو جدت طلعت هناك load بعد الكاربون هادي
+
+343
+00:29:35,410 --> 00:29:37,910
+بعد الميتو
+
+344
+00:29:42,220 --> 00:29:50,020
+الان بعد هيك بدكم تتطلع على هدول الرموز وتسألوا
+
+345
+00:29:50,020 --> 00:29:52,820
+نفسكم ايش العلاقة بينهم
+
+346
+00:29:56,870 --> 00:30:02,330
+عكس التانية و واحدة زي التانية طالما مش كل إشي عكس
+
+347
+00:30:02,330 --> 00:30:07,410
+بعض إذا diastereomers لإن شرط ال enantiomers لو
+
+348
+00:30:07,410 --> 00:30:12,030
+عندى عشرة chiral centers كل واحد عكس التاني لإن
+
+349
+00:30:12,030 --> 00:30:15,630
+أنا تخيلوني مثلا هى قدام المرايا هى chiral center
+
+350
+00:30:15,630 --> 00:30:19,050
+هى اتنين هى تلاتة اربعاية خمسة هى ستة لما بقى قدام
+
+351
+00:30:19,050 --> 00:30:23,790
+المرايا كل نقطة بتكون عكس التانية ولا لأ شرط ال
+
+352
+00:30:23,790 --> 00:30:28,300
+enantiomers يعني لو كان عندكوا عشرة chiral centers
+
+353
+00:30:28,300 --> 00:30:31,980
+مركب فيه عشرة chiral centers والتاني فيه عشرة
+
+354
+00:30:31,980 --> 00:30:35,800
+chiral centers وقت إيش بيكونوا enantiomers؟ لما كل
+
+355
+00:30:35,800 --> 00:30:42,130
+نقطة عكس التانية، إذا واحدة منهم اختلت بتبطل الجزيئ
+
+356
+00:30:42,130 --> 00:30:45,110
+انها enantiomers لو كان عندى مركب فيه عشرة chiral
+
+357
+00:30:45,110 --> 00:30:49,410
+centers تسعة منهم كل واحدة عكس التانية عكس التانية
+
+358
+00:30:49,410 --> 00:30:53,670
+عكس التانية وواحدة زي التانية صار diastereomers
+
+359
+00:30:53,670 --> 00:30:57,930
+بطل صورة بعض في المرمى، واضح؟ إذا هدول عبارة عن diastereomers
+
+360
+00:30:57,930 --> 00:31:01,370
+شو سؤالك؟ مثلا، لو كان في احد
+
+361
+00:31:01,370 --> 00:31:05,330
+الثلاثين chiral center يعني .. ال chiral center ..
+
+362
+00:31:05,330 --> 00:31:12,710
+يعني اتصرف على كابونزين؟ أكيد، لا طبعا، منفعش، إذا
+
+363
+00:31:12,710 --> 00:31:15,910
+عندك two chiral centers، بدك تحدد إلى اتنين،
+
+364
+00:31:15,910 --> 00:31:18,870
+تانين، منفعش زي هذا المثال، هذا المثال كان فيه بس
+
+365
+00:31:18,870 --> 00:31:24,470
+one chiral center، لو عندك تلاتة، بدك تحدد إلى
+
+366
+00:31:24,470 --> 00:31:29,950
+تلاتة، واضح؟ على أي حال، هذه الأمثلة اللي هنا، هذه
+
+367
+00:31:29,950 --> 00:31:34,520
+الأمثلة اللي هنا برضه نفس الفكرة بإمكانكوا تعملوها
+
+368
+00:31:34,520 --> 00:31:37,680
+بهدوء و تحلوها في البيت صار عندكوا هاي المشاكل
+
+369
+00:31:37,680 --> 00:31:41,180
+بترجعونا اتحددوا ال configurations و ال
+
+370
+00:31:41,180 --> 00:31:45,360
+configurations و حسب ما علمناكم إذا عندكم two
+
+371
+00:31:45,360 --> 00:31:51,100
+chiral centers كام احتمال عندكم؟ لأ في العلاقة
+
+372
+00:31:51,100 --> 00:31:57,540
+بينهم يا the same compound، يا enantiomers، يا 
+
+373
+00:31:57,540 --> 00:32:01,980
+diastereomers، واضح؟ يا the same compound، يا enantiomers
+
+374
+00:32:01
+
+401
+00:34:07,570 --> 00:34:07,930
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+402
+00:34:07,930 --> 00:34:14,730
+اثل اثل اثل اثل اثل اثل
+
+403
+00:34:21,080 --> 00:34:28,280
+3S هدول إيش العلاقة بإنهم كل واحدة فيهم؟ عكس
+
+404
+00:34:28,280 --> 00:34:34,460
+التانية إذا هدول Enantiomers واضح؟ ابنجلة اللي
+
+405
+00:34:34,460 --> 00:34:46,040
+موجودين عندي هنا بتطلعوا هذي 2R 2S و هذي 3S 3R برضه
+
+406
+00:34:46,040 --> 00:34:50,420
+مبينين عكس بعض، بالتالي ممكن تبدو تفكروا ان هدول
+
+407
+00:34:50,420 --> 00:34:54,840
+يكونوا إيش In Animals حقيقة لو اعملنا models
+
+408
+00:34:54,840 --> 00:35:00,180
+وناقشنا هدول المركبين بتفاصيل هلاج انهم نفس
+
+409
+00:35:00,180 --> 00:35:06,060
+المركب مش In Animals طبعا حيصير السؤال ليش هذا
+
+410
+00:35:06,060 --> 00:35:12,320
+الكلام صار عندك؟ ليش هدول بصيروا نفس المركب رغم
+
+411
+00:35:12,320 --> 00:35:15,860
+أن احنا كنا نقول انه إذا كل واحد عكس التانية، بنكون 
+
+412
+00:35:15,860 --> 00:35:20,620
+نحكي عن Enantiomers هنا إحنا أمام جزيق مختلف عن
+
+413
+00:35:20,620 --> 00:35:26,100
+الجزيق السابق، هذا الجزيق جزيق متماثل داخليًا،
+
+414
+00:35:26,100 --> 00:35:30,200
+بمعنى إن النُص اللي فوق من الجزيق نفس النُص اللي
+
+415
+00:35:30,200 --> 00:35:33,900
+تحت، يعني لو تخيلتوا إن الجزيق مجسوم بمراية بهذا
+
+416
+00:35:33,900 --> 00:35:39,040
+الشكل، ملاحظين انتوا؟ إيش في عنكم فوق؟ Carbon،
+
+417
+00:35:39,040 --> 00:35:44,070
+حاملة، قدش كلور مثل، وتحت؟ Carbon، حمضة، أدشكلون،
+
+418
+00:35:44,070 --> 00:35:47,730
+مثل فهذا الجزء مختلف عن السابق في السابق لو كنت
+
+419
+00:35:47,730 --> 00:35:51,830
+بتحط مرايا هذه في النص كانت هذه مثله وهذه إثلا
+
+420
+00:35:51,830 --> 00:35:57,770
+وبالتالي كان الجزء غير متماثل داخلي يعني مش النص
+
+421
+00:35:57,770 --> 00:36:02,030
+اللي فوق منه زي النص اللي تحت هذا الجزء نفسه فيه
+
+422
+00:36:02,030 --> 00:36:05,410
+تماثل داخلي النص اللي فوق منه عكس النص اللي تحت
+
+423
+00:36:05,410 --> 00:36:11,150
+بناء على ذلك هذا بيقدر إيش؟ بيقدّي ان هذا و هذا
+
+424
+00:36:11,150 --> 00:36:15,210
+يكونوا نفس الشيء كيف انا ممكن اتخيلها بإمكانكوا
+
+425
+00:36:15,210 --> 00:36:20,670
+تتخيلوا ان انا حطيت هنا دبوس او مصمار و لفيت هذا
+
+426
+00:36:20,670 --> 00:36:27,110
+المركب .. لفيت هذا المركب بهذا الشكل و جبته هيك
+
+427
+00:36:27,110 --> 00:36:31,370
+منطبق عليهم ولا لا لاحظوا انا لما بلفه حوالين محور
+
+428
+00:36:31,370 --> 00:36:39,040
+هدول اللي متجهات للامام هل غيرتهم؟ مغيرتهم مش مظبوط
+
+429
+00:36:39,040 --> 00:36:43,700
+ولا لا؟ أنا بس حطيت هنا دبوس و لفيت الجزيق هذا
+
+430
+00:36:43,700 --> 00:36:46,840
+صاروا ال hydrogen زيك و ال chlorine اتجهت و حطيته
+
+431
+00:36:46,840 --> 00:36:51,140
+ينطبق هنا و انطبق على هذا و بناء على ذلك هذا و هذا
+
+432
+00:36:51,140 --> 00:36:54,660
+نفس الشيء طب كان ممكن واحدة تقول طب ليش قبل شوية
+
+433
+00:36:54,660 --> 00:36:59,980
+ما قلتش هالفكرة فزام احنا بنقدر نتخيل ان هنا محور
+
+434
+00:36:59,980 --> 00:37:06,740
+و اللف هذا و الخلية انطبق واضح؟ هاي المحور؟
+
+435
+00:37:11,610 --> 00:37:14,750
+والطبق على هذا .. ليش قبل شوية في المثال السابق
+
+436
+00:37:14,750 --> 00:37:20,310
+ما كانش هذا الكلام مصير؟ لأنه ما كانش الجزء اللي فوق
+
+437
+00:37:20,310 --> 00:37:24,390
+زي اللي تحت .. هذا الآن لما بلف فوق .. في عندي هذا
+
+438
+00:37:24,390 --> 00:37:28,750
+المثل .. وين بدأ تيجي؟ تحت .. و هذا المثل .. وين
+
+439
+00:37:28,750 --> 00:37:33,150
+بدأ تروح؟ فوق .. لأن هدول المجموعتين زي بعض ..
+
+440
+00:37:33,150 --> 00:37:36,390
+هذا بتيجي لتحت .. و هذا بتيجي لفوق .. بيجي بالطبق
+
+441
+00:37:36,390 --> 00:37:40,390
+هنا .. طيب لو رجعنا للمثال السابق .. إيش كان في
+
+442
+00:37:40,390 --> 00:37:46,510
+عندكم؟ مثل و إثل فبناء عذرك في المثال السابق لو
+
+443
+00:37:46,510 --> 00:37:53,330
+لفيته المثل بتيجي ع المثل و الإثل بتيجي ع المثل
+
+444
+00:37:53,330 --> 00:37:58,590
+إذا مش متطابق ما كانش هذا الكلام بينفع في المثال
+
+445
+00:37:58,590 --> 00:38:06,690
+السابق خليني أرجع للمثال السابق اللي هو اللهاماه
+
+446
+00:38:06,690 --> 00:38:10,610
+اتخيلوا لو انا عملت نفس الشغلة لو انا عملت نفس
+
+447
+00:38:10,610 --> 00:38:14,890
+الشغلة اتخيلت
+
+448
+00:38:14,890 --> 00:38:19,690
+في هذا الجزء انه هي عندي محوى و بدى الفه صح انا
+
+449
+00:38:19,690 --> 00:38:25,110
+جيبت ال chlorine على الجهة دي و ظّلوا للامام و جيبت
+
+450
+00:38:25,110 --> 00:38:29,270
+ال Ethyl على الجهة دي وظّلوا للامام اذا كل الجثة اللى
+
+451
+00:38:29,270 --> 00:38:34,830
+امامي صار فيه ايش ينطبق لكن ايش المشكلة؟ خليت ال
+
+452
+00:38:34,830 --> 00:38:39,970
+مثل تيجي هنا و ال Ethyl تيجي هنا إذا ما تنطبقوش شوفتوا
+
+453
+00:38:39,970 --> 00:38:44,950
+الفرق بين الحالتين؟ وبناء على ذلك في حالة التماثل
+
+454
+00:38:44,950 --> 00:38:50,910
+اللي إحنا شايفينها في ال 2,3 dichlorobentain
+
+455
+00:38:50,910 --> 00:38:57,350
+صاروا هدول عبارة عن نفس المُركّب إذا كام Isomers
+
+456
+00:38:57,350 --> 00:39:02,040
+طلع عنده؟ واحد، اتنين، و هدول دي are the same
+
+457
+00:39:02,040 --> 00:39:09,140
+compound، تلاتة، واضح؟ مش أربعة، تلاتة، طيب، الآن
+
+458
+00:39:09,140 --> 00:39:13,060
+واحدة ممكن تقول أنت قولتلنا انه لو كان كل واحدة
+
+459
+00:39:13,060 --> 00:39:17,480
+عكس التاني يعتبرهم Enantiomers مظبوط ولا لا؟ احنا
+
+460
+00:39:17,480 --> 00:39:20,900
+الآن بنحط شرط، بنقول لو كل واحدة عكس التانية،
+
+461
+00:39:20,900 --> 00:39:25,540
+اعتبرهم Enantiomers and Diastereomers بشرط، الا يكون الجزء متماثل
+
+462
+00:39:25,540 --> 00:39:31,380
+من نصه، يعني ما يكونش نصه زي نص التاني، هذا الجزء
+
+463
+00:39:31,380 --> 00:39:36,080
+ما بينطبقش على القاعدة، لأن هذا النص محتوياته زي
+
+464
+00:39:36,080 --> 00:39:40,970
+هذا النص، واضح؟ إذا القاعدة اللي قبل شوية كتبتها
+
+465
+00:39:40,970 --> 00:39:44,570
+إنه لو كل واحدة عكس التانية بعتبرهم Enantiomers
+
+466
+00:39:44,570 --> 00:39:50,570
+بشرط أن لا يكون الجزء متماثل طب إذا كان الجزء
+
+467
+00:39:50,570 --> 00:39:54,370
+متماثل شو بقول عنهم؟ the same compound حتى لو كل
+
+468
+00:39:54,370 --> 00:39:58,490
+واحدة عكس التانية واضح؟ في هذه الحالة هذا المركب
+
+469
+00:39:58,490 --> 00:40:03,870
+المتماثل داخليًا بسميه Mesostructure
+
+470
+00:40:05,280 --> 00:40:10,740
+الـ Mesostructure هو مركب متماثل داخليًا، عارفين
+
+471
+00:40:10,740 --> 00:40:15,520
+كيف صورة نص اللي فوق زي النص اللي تحت؟ بتعرفوا لما
+
+472
+00:40:15,520 --> 00:40:20,420
+بيلعبوا في الشدة؟ البعض منكم شايف الشدة؟ مشفير
+
+473
+00:40:20,420 --> 00:40:25,820
+رسومات فيها زي صورة بني آدم لفوق و بني آدم لتحت؟
+
+474
+00:40:25,820 --> 00:40:30,740
+هذا Mesostructure، ما اعرفش شو بيسموها بتكون الصورة
+
+475
+00:40:30,740 --> 00:40:35,320
+معكوسة، زي بني آدم له راسين من فوق و من تحت، هذا
+
+476
+00:40:35,320 --> 00:40:41,520
+عبارة عن Mesostructure، نصه اللي فوق زي النص اللي
+
+477
+00:40:41,520 --> 00:40:46,520
+تحت، إذا انا لما باجي بحدد لمركبات انهم، ايش
+
+478
+00:40:46,520 --> 00:40:50,140
+العلاقة بينهم، أول اشي دائما اسألوا نفسكم، هل يا
+
+479
+00:40:50,140 --> 00:40:55,040
+ترى الجزاء متماثل نصه زي نص التاني ولا لا؟ إذا نصه
+
+480
+00:40:55,040 --> 00:40:57,860
+زي نص التاني، معناه ذلك اللي بيكونوا عكس بعض
+
+481
+00:40:57,860 --> 00:41:01,160
+بيكونوا إيش؟ the same compound و بيمثلوا ال
+
+482
+00:41:01,160 --> 00:41:05,400
+Mesostructure إذا النص هذا مختلف عن نص هذا معناه
+
+483
+00:41:05,400 --> 00:41:09,960
+ذلك المتعاكسات بيكونوا Enantiomers طبعا بقصد
+
+484
+00:41:09,960 --> 00:41:12,980
+بالمتعاكسات لما تكون هذه R و هذه نفسها و هذه نفسها
+
+485
+00:41:12,980 --> 00:41:17,240
+هنا هدول متعاكسات بس طالما نفس الرمز هنا و نفسه
+
+486
+00:41:17,240 --> 00:41:22,360
+هنا هدول they are Enantiomers قولا واحد على أي
+
+487
+00:41:22,360 --> 00:41:27,560
+حال هذا الكلام راجعوهو حاولوا كتير أنكوا تطبقوا
+
+488
+00:41:27,560 --> 00:41:30,860
+بالورقة و القلم بتوقع الحصة اللي جاية تيجوا تسألوا
+
+489
+00:41:30,860 --> 00:41:42,120
+فيه و حلوا الأمثلة اللي موجودة عندكم طبعا
+
+490
+00:41:42,120 --> 00:41:48,360
+تنسوش اليوم مدعوين على المحاضرة اللي
+
+491
+00:41:48,360 --> 00:41:52,720
+بيجي أهلا وسهلا اللي ما بيجيش أهلا وسهلا اللي بيجي
+
+492
+00:41:52,720 --> 00:41:54,080
+و بيعمل report عن المحاضرة 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3f86a97d91b9bd28c8c7fa15b45bf712f7bb43c0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54_postprocess.srt
@@ -0,0 +1,1968 @@
+1
+00:00:07,220 --> 00:00:10,900
+اليوم ان شاء الله بنكمل في موضوع ال stereo
+
+2
+00:00:10,900 --> 00:00:17,860
+chemistry طبعا اذا سألناكم كل الكلام اللي درسناه
+
+3
+00:00:17,860 --> 00:00:23,100
+الحصة الماضية كان عبارة عن تعريف ال enantiomers
+
+4
+00:00:23,100 --> 00:00:28,300
+يعني قولنا ان ال stereo isomers نوعين النوع الأول
+
+5
+00:00:29,180 --> 00:00:34,280
+إنانشو مارز والإنانشو مارز بيمتازوا إنهم جزيئات
+
+6
+00:00:34,280 --> 00:00:37,640
+الواحد منهم صورة التاني في المرأة لكنها غير
+
+7
+00:00:37,640 --> 00:00:43,340
+متطابقة هذا ملخص تقريبا لكل المحاضرة الماضية زدنا
+
+8
+00:00:43,340 --> 00:00:49,720
+على ذلك إنه الإنانشو مارز كيف نقدر نميزهم عن بعض
+
+9
+00:00:49,720 --> 00:00:53,620
+نعمل لهم configuration بنسميه بمعنى نقول إنه هذا R
+
+10
+00:00:54,200 --> 00:00:58,420
+و هذا S و كل هالأمور بتاعي اللي أخدنا عليها تطبيق
+
+11
+00:00:58,420 --> 00:01:05,060
+كافي اتذكروا معي لما حكينا ال enantiomers كفكرة
+
+12
+00:01:05,060 --> 00:01:10,300
+كيميائية بدناها بفكرة من الحياة قولنا في عندى
+
+13
+00:01:10,300 --> 00:01:13,980
+إيدين في عندى باب سيارة في عندى نضارات كل هدولة
+
+14
+00:01:13,980 --> 00:01:17,820
+يمثلوا enantiomers من ناحية المبدأ كلهم ممكن
+
+15
+00:01:17,820 --> 00:01:22,520
+اعرفهم enantiomers صورة بعض في المرأة غير متطابقة
+
+16
+00:01:23,060 --> 00:01:28,260
+واضح؟ الان بدنا ناخد النوع التاني من ال stereo
+
+17
+00:01:28,260 --> 00:01:35,280
+isomers وممكن نبدأ بتعريفه برضه من الحياة اش هما
+
+18
+00:01:35,280 --> 00:01:41,540
+ال diastereomers واضح؟ ال diastereomers سهلين لو
+
+19
+00:01:41,540 --> 00:01:46,740
+اتخيلتوا ان انتوا كنتوا على سبيل المثال في الطابور
+
+20
+00:01:46,740 --> 00:01:52,660
+الصباحي في المدرسة الثانوية ماشي؟أول ما تكونوا في
+
+21
+00:01:52,660 --> 00:01:55,120
+الطابور الصباحي شو بيعملولكوا في التمرينات
+
+22
+00:01:55,120 --> 00:02:03,020
+الرياضية بيعملولكوا أماما جانبا أعلى أسفل الآن
+
+23
+00:02:03,020 --> 00:02:07,980
+تخيلوا عندكوا صورة هي أماما هذه الصورة نفترض أن حد
+
+24
+00:02:07,980 --> 00:02:14,460
+أخد صورة بالكاميرا هيك أماما الآن هذهجانبا .. واحد
+
+25
+00:02:14,460 --> 00:02:19,740
+كمان أخد صورة و حطلكوا الصورتين قدامكم و قالكم ما
+
+26
+00:02:19,740 --> 00:02:26,800
+العلاقة بين هدول الصورتين لحظو احنا بنحكي عن نفس
+
+27
+00:02:26,800 --> 00:02:32,960
+الشخص .. the same weightأو the same molecular
+
+28
+00:02:32,960 --> 00:02:38,880
+weight طيب كويس، هل الارتباط اتغير ولا نفس مواقع
+
+29
+00:02:38,880 --> 00:02:44,480
+الارتباط؟ بمعنى أن الاتين مشبوكين في الكتف، مافيش
+
+30
+00:02:44,480 --> 00:02:47,540
+تغير في الارتباط، الإيدة ده مافكتش إجت على مكان
+
+31
+00:02:47,540 --> 00:02:51,700
+تاني من الجسم، إذا أنا بحكي عن نفس الجزء بنفس
+
+32
+00:02:51,700 --> 00:02:57,380
+مواقع الارتباط، أين الاختلاف؟في الشكل بالفراغ هذا
+
+33
+00:02:57,380 --> 00:03:02,600
+الشكل بيختلف عن هذا الشكل إذا هدول الصورتين كمرحلة
+
+34
+00:03:02,600 --> 00:03:05,620
+أولى أقل إشي بقبلوا منكوا تقولوا ان they are
+
+35
+00:03:05,620 --> 00:03:10,770
+stereoisomersThey have the same molecular weight
+
+36
+00:03:10,770 --> 00:03:15,470
+but different arrangement in space هذا التعريف
+
+37
+00:03:15,470 --> 00:03:20,170
+العام لإيش؟ لل stereo isomers، الآن أعطوني كمان
+
+38
+00:03:20,170 --> 00:03:25,530
+علاقة إضافية بينهم، إيش علاقتهم مع بعض في المرأة؟
+
+39
+00:03:26,850 --> 00:03:31,330
+مش صورة بعض في المرايا، non-mirror images، واضح؟
+
+40
+00:03:31,330 --> 00:03:36,210
+هدول اللي احنا بنسميهم ايش؟ Diastereomars، واضح؟
+
+41
+00:03:36,210 --> 00:03:41,850
+فالdiastereomars عبارة عن stereoisomers بيكونوا مش
+
+42
+00:03:41,850 --> 00:03:45,010
+صورة بعض في المرايا، non-mirror image
+
+43
+00:03:45,010 --> 00:03:48,270
+stereoisomers، هاي تعريفهم، إيش تعريف
+
+44
+00:03:48,270 --> 00:03:52,630
+الdiastereomars؟Non Mirror Image Stereoisomers
+
+45
+00:03:52,630 --> 00:03:57,270
+الان لو بدى امثلة تطبيقية من الحياة حتى نفهم
+
+46
+00:03:57,270 --> 00:04:01,850
+الظاهرة قبل ما ننتقل على ايش على الذرات والجزيئات
+
+47
+00:04:01,850 --> 00:04:06,550
+والكيم يوما الى ذلك لو يا ترى امسكت نضارة هادي
+
+48
+00:04:06,550 --> 00:04:12,830
+بهذا الشكل هينمسكها هذه النضارة انا جبت مفكات
+
+49
+00:04:12,830 --> 00:04:17,930
+وفكتها وغيرت فيها ال bondingلارتباط؟ طيب لو أخدت
+
+50
+00:04:17,930 --> 00:04:22,450
+صورة النضارة و هي مفتوحة و صورة النضارة و هي مسكرة
+
+51
+00:04:22,450 --> 00:04:30,030
+ما العلاقة بين هدول الشكلين؟Diastereomers نفس
+
+52
+00:04:30,030 --> 00:04:35,110
+النضارة بنفس مواقع الإرتباط لاختلاف فقط في الشكل
+
+53
+00:04:35,110 --> 00:04:39,970
+الفراغي الشكل الأول والشكل التاني العلاقة بينهم
+
+54
+00:04:39,970 --> 00:04:45,170
+إنهم مش صورة بعض في المرأة واضح؟ إذن هالنضارة هذه
+
+55
+00:04:45,170 --> 00:04:48,970
+لما تكون مفتوحة ومسكرة بتمثل بالنسبة لإيش؟
+
+56
+00:04:48,970 --> 00:04:53,490
+Diastereomers لو افترضت مثلا إنه عندي علبة ممكن
+
+57
+00:04:53,490 --> 00:04:58,040
+أكون فاتحة أنا بزاوية 180 درجةبدون ما اغير
+
+58
+00:04:58,040 --> 00:05:01,360
+الارتباطية ده الغطا مرتبط بالعلبة من هنا خلتها
+
+59
+00:05:01,360 --> 00:05:04,720
+بتسعين ايش العلاقة بين هدول الصورتين ده stereo
+
+60
+00:05:04,720 --> 00:05:08,640
+Mars سكرتها على الآخر ايش العلاقة ده stereo Mars
+
+61
+00:05:08,640 --> 00:05:12,780
+واضح فده stereo Mars عبارة عن stereo isomers لكن
+
+62
+00:05:12,780 --> 00:05:17,410
+they are non mirror image stereo isomersواضح؟
+
+63
+00:05:17,410 --> 00:05:21,990
+بيكونوا مش صورة بعض في المرأة الان .. وين ممكن
+
+64
+00:05:21,990 --> 00:05:28,390
+نبدأ نشوف ال diastereomars قبل ما نطلع على مركبات
+
+65
+00:05:28,390 --> 00:05:33,550
+فيها chiral centers مر علينا احنا diastereomars ..
+
+66
+00:05:33,550 --> 00:05:36,930
+مر علينا diastereomars لكن بعد ذلك الوقت لإنا كنا
+
+67
+00:05:36,930 --> 00:05:41,370
+مش ماخدين تعريفالـ Stereochemistry وما إلى ذلك ما
+
+68
+00:05:41,370 --> 00:05:44,970
+قلناش أن هدولة دي هي الـ Stereomers لو ابتذكروا
+
+69
+00:05:44,970 --> 00:05:51,210
+مثلا مار علينا المركبات اللي كان فيها cis و trans
+
+70
+00:05:51,210 --> 00:05:56,130
+حوالين ال double bond لو تخيلنا مثلا هذا المركب
+
+71
+00:05:56,130 --> 00:06:00,490
+اللي كان فيه ذرتين كلور على جهة واحدة مع المركب
+
+72
+00:06:02,540 --> 00:06:07,700
+اللي فيه ذرتيل كلور متعاكسات هذا كنا إيش نسميه؟
+
+73
+00:06:07,700 --> 00:06:14,900
+cis-dichloroethane وهذا trans-dichloroethane الآن
+
+74
+00:06:14,900 --> 00:06:19,520
+لو اطلعتوا على هدولة المركبين ال cis والترانس،
+
+75
+00:06:19,520 --> 00:06:24,920
+اللهم نفس ال molecular weight؟ اللهم نفس مواقع
+
+76
+00:06:24,920 --> 00:06:27,980
+الارتباط، إيش بقصود أنا بنفس مواقع الارتباط؟ لو
+
+77
+00:06:27,980 --> 00:06:31,920
+قلت هذه ال carbon الأولى متصلة بماذا؟أكلورو
+
+78
+00:06:31,920 --> 00:06:35,820
+هيدروجين وهذه الكاربون التانية أكلورو هيدروجين طب
+
+79
+00:06:35,820 --> 00:06:39,620
+لو هنا بدأتش أطلع الكاربون الأولى أكلورو هيدروجين
+
+80
+00:06:39,620 --> 00:06:44,740
+الكاربون التانية أكلورو هيدروجين أين الاختلاف بشكل
+
+81
+00:06:44,740 --> 00:06:49,740
+الفراغي لكن مواقع الارتباط نفسها أنه هنا التنتين
+
+82
+00:06:49,740 --> 00:06:55,000
+الكلور على جهة واحدة وفي الجزء التاني التنتين
+
+83
+00:06:55,000 --> 00:07:02,700
+الكلور على جهتينمتعاكستين إذا هل هدول المركبين يا
+
+84
+00:07:02,700 --> 00:07:08,280
+ترى صورة بعض في المرأة ولا لأ إذا هدول ال cis
+
+85
+00:07:08,280 --> 00:07:12,080
+trans isomers they are non mirror image
+
+86
+00:07:12,080 --> 00:07:16,540
+stereoisomers they are diastereomers واضح فالcis
+
+87
+00:07:16,540 --> 00:07:21,800
+والtrans isomers they are diastereomers شفتوا
+
+88
+00:07:21,800 --> 00:07:26,340
+انتوا غيرة الcis والtrans isomers في مكانين حوالين
+
+89
+00:07:26,340 --> 00:07:31,820
+ال double bondو في الأشكال الحلقية طلعوا معي لما
+
+90
+00:07:31,820 --> 00:07:37,020
+كان مثلا نكون عندنا cyclopentene cyclopentene عادي
+
+91
+00:07:37,020 --> 00:07:40,900
+مش pentene cyclopentene نحط مثلا ال chlorine لفوق
+
+92
+00:07:40,900 --> 00:07:45,960
+و ال chlorine التالية لفوق و هاي hydrogens هذا أيه
+
+93
+00:07:45,960 --> 00:07:50,420
+المركب؟ هذا ال cis compound الآن لو حطينا chlorine
+
+94
+00:07:50,420 --> 00:07:55,710
+لفوق و chlorine لتحت مثلاالـ Trans هدولة الشكلين
+
+95
+00:07:55,710 --> 00:08:02,130
+أيضًا stereo isomers لكن non-mirror image stereo
+
+96
+00:08:02,130 --> 00:08:05,670
+isomers، this is trans isomers، so they are the
+
+97
+00:08:05,670 --> 00:08:12,400
+stereomers، واضح؟بنقدر نقول إنه كمثال كمثال على
+
+98
+00:08:12,400 --> 00:08:16,620
+الدياستيريو مارز ال CC trans isomers سواء كانوا CC
+
+99
+00:08:16,620 --> 00:08:21,220
+trans isomers حوالين ال double bond أو كانوا CC
+
+100
+00:08:21,220 --> 00:08:26,420
+trans isomers حوالين حلقة يعني فوق و تحت مستوى
+
+101
+00:08:26,420 --> 00:08:32,680
+الحلقة هذا أحد الأنواع الآن بيجينا نوع تالي بيجينا
+
+102
+00:08:32,680 --> 00:08:37,240
+نوع تالي من ال CC trans من الدياستيريو مارز عفوا
+
+103
+00:08:37,770 --> 00:08:43,230
+اللي هو لما بتصير عندى في المركب مش chiral center
+
+104
+00:08:43,230 --> 00:08:48,330
+واحد اكثر من chiral center اتذكروا معاى لما كان
+
+105
+00:08:48,330 --> 00:08:52,030
+المركب يكون في chiral center واحد يعني الكربون
+
+106
+00:08:52,030 --> 00:08:55,850
+عليها اربع روابط جديش كان يطلع عندى المركبات او
+
+107
+00:08:55,850 --> 00:09:03,910
+isomers اتنين ال R و ال Sلما بيكون عندى one chiral
+
+108
+00:09:03,910 --> 00:09:08,870
+center بيطلع عندى مركبين ال R و ال S الان السؤال
+
+109
+00:09:08,870 --> 00:09:13,450
+لما بيصير عندى اكتر من chiral center جداش بده يطلع
+
+110
+00:09:13,450 --> 00:09:19,470
+isomers يعني مثلا نفترض اتنين احنا بنقول القاعدة
+
+111
+00:09:19,470 --> 00:09:27,430
+في قاعدة بتحدد لعدد ال stereo isomersبتقول أن أقصى
+
+112
+00:09:27,430 --> 00:09:34,490
+شيء ممكن يطلع عنده two to the n واضح؟ أقصى شيء
+
+113
+00:09:34,490 --> 00:09:38,570
+ممكن يطلع عنده two to the n يعني لو عنده two
+
+114
+00:09:38,570 --> 00:09:43,150
+chiral centers، بدأ أقول اتنين أس اتنين، قداش
+
+115
+00:09:43,150 --> 00:09:49,030
+المجموع؟ أربعبمعنى ممكن يكون عندى أربع مركبات
+
+116
+00:09:49,030 --> 00:09:53,850
+مختلفة و ممكن يكون أقل، بس مش ممكن يكون أكثر،
+
+117
+00:09:53,850 --> 00:10:00,470
+بمعنى أن القاعدة مابتعطينيش العدد بالظبط، بتكون
+
+118
+00:10:00,470 --> 00:10:07,060
+لأقصى شئ ممكن أربعة، ممكن يكون عندك أقلواضح
+
+119
+00:10:07,060 --> 00:10:11,860
+للكلام؟ اذا انا عشان اعرف العدد بالظبط بدي شوية
+
+120
+00:10:11,860 --> 00:10:16,760
+شغل بدي ارسم بدي اتعلم اشياء اضافية الان لو افترضت
+
+121
+00:10:16,760 --> 00:10:22,020
+مثلا انه عندي تلاتة chiral centers موجودين في
+
+122
+00:10:22,020 --> 00:10:27,300
+جزائي جداش اقصى ما يمكن يكون عندى مركبات اتنين اقص
+
+123
+00:10:27,300 --> 00:10:32,300
+تلاتة مش تلاتة اقص اتنين تمانية اتنين اقص تلاتة
+
+124
+00:10:32,300 --> 00:10:37,080
+تمانية اتنين في اتنين في اتنينواضح؟ تمانية لحد
+
+125
+00:10:37,080 --> 00:10:43,300
+الأقصى خلّينا نشوف لما يكونوا عندنا اتنين chiral
+
+126
+00:10:43,300 --> 00:10:49,000
+centers بلاش نصعب على حالنا الأمور ناخد مثلا مركب
+
+127
+00:10:49,000 --> 00:10:52,480
+زي هذا لو تخيلنا أننا لدينا ذرة كربون تنتين،
+
+128
+00:10:52,480 --> 00:10:56,880
+تلاتة، أربعة، خمسة، هذا إفيل وحطينا على موقع اتنين
+
+129
+00:10:56,880 --> 00:11:02,250
+كلور وعلى موقع تلاتة كلورانتوا الان يمكن تستغربوا
+
+130
+00:11:02,250 --> 00:11:06,450
+انه كنتوا تقولوا انه ايش اسم هذا المركب two three
+
+131
+00:11:06,450 --> 00:11:10,090
+dichlorobentane
+
+132
+00:11:10,090 --> 00:11:14,430
+زي اللي كنا نرسملكوا كاربون، تنتين، تلاتة، اربعة،
+
+133
+00:11:14,430 --> 00:11:18,610
+خمسة و ببساطة نحط كلور و كلور و نام the following
+
+134
+00:11:18,610 --> 00:11:27,360
+compound ايش تسموه؟2,3-dichlorobentane واضح؟ اللي
+
+135
+00:11:27,360 --> 00:11:32,000
+هتتفاجأو فيه الآن انه انتوا لو روحتوا على المخزن
+
+136
+00:11:32,000 --> 00:11:35,820
+تشتريوا 2,3-dichlorobentane هيقولكوا مافيش عندي 2
+
+137
+00:11:35,820 --> 00:11:40,890
+,3-dichlorobentane هيك لوحدهفي عندى أربع مركبات
+
+138
+00:11:40,890 --> 00:11:45,530
+كلهم بنطبق عليهم two three dichlorobentano انتوا
+
+139
+00:11:45,530 --> 00:11:48,970
+حددوا إيش اللى بدكوا إياه ليش لأنه هذه ال carbon
+
+140
+00:11:48,970 --> 00:11:53,650
+chiral center خليني نطلع على رسمها لما أجي أطلع
+
+141
+00:11:53,650 --> 00:11:57,810
+على ال carbon رقم اتنين إيش المجموعات أقلالها مثل
+
+142
+00:11:57,810 --> 00:12:02,710
+اتش اتلور وكمان مجموعة كبيرة إذا هنا في عندى
+
+143
+00:12:02,710 --> 00:12:06,810
+chiral center ولا لأ أكيد لو أجي تطلعك على ال
+
+144
+00:12:06,810 --> 00:12:12,010
+carbon التانيةChlore و H و إثل و مجموعة كبيرة برضه
+
+145
+00:12:12,010 --> 00:12:16,370
+كايرال سنتر إذا كام كايرال سنتر عندى فى هذا الجزء؟
+
+146
+00:12:16,370 --> 00:12:21,750
+two كايرال سنتر لما أجى بدي أرسم الاحتمالات
+
+147
+00:12:21,750 --> 00:12:27,130
+الممكنة كلها خلينا نجرب نحط ال مثل لفوق و ال إثل
+
+148
+00:12:27,130 --> 00:12:31,730
+لتحت و نحط الchlore و ال H ذرتين لchlore البساطة
+
+149
+00:12:31,730 --> 00:12:38,380
+يبدو يكونوا عكس بعض يبدو يكونوا جانب بعضفي غير هيك
+
+150
+00:12:38,380 --> 00:12:43,880
+له محتمال؟ يا إما عكس بعض، يا إما جانب بعض، لكن كل
+
+151
+00:12:43,880 --> 00:12:49,220
+واحد من هدول له صورة في المرآة، كل واحد من هدول له
+
+152
+00:12:49,220 --> 00:12:52,880
+صورة في المرآة، بمعنى لو اتخيلت أن هذا المركب اللي
+
+153
+00:12:52,880 --> 00:12:59,080
+هو بيمثل المركب الأول صورته في المرآة هذا المركب،
+
+154
+00:12:59,080 --> 00:13:02,800
+واضح؟ هاي الـH عكس الـH، الـCL عكس الـCL، كل حاجة
+
+155
+00:13:02,800 --> 00:13:07,670
+عكس التانية، نفس الشيءلو جيت تطلع تهانة على
+
+156
+00:13:07,670 --> 00:13:15,330
+المُركّب هذا، واضح؟ إذن كمان هذا صورة التالت في
+
+157
+00:13:15,330 --> 00:13:19,690
+المرأة، الآن يا ترى، هل فعلا معقول إن هدول
+
+158
+00:13:19,690 --> 00:13:25,070
+المُركّبات الأربع مختلفات؟هل معقول انه مختلفات؟
+
+159
+00:13:25,070 --> 00:13:29,150
+افضل شي عشان اشوف الاختلاف انه على كل Cairol
+
+160
+00:13:29,150 --> 00:13:32,910
+Center احدد configuration اشوف ال configuration
+
+161
+00:13:32,910 --> 00:13:37,690
+اللي عندى R ولا S اشوف ال configuration اللي عندى
+
+162
+00:13:37,690 --> 00:13:44,270
+R ولا S فلو اجيت مثلا انا كله حاطه هنا ممكن اخد
+
+163
+00:13:44,270 --> 00:13:48,790
+مثلين تلاتة نعملهم معاكم بسرعة لو اجينا هنا سألنا
+
+164
+00:13:48,790 --> 00:13:54,850
+مثلا عن موقع اتلينأنهي أقل مجموعة الهيدروجين ممتاز
+
+165
+00:13:54,850 --> 00:13:59,790
+طيب لو بدى أبدأ أتحرك من الأعلى للأقل للأقل هاي ال
+
+166
+00:13:59,790 --> 00:14:06,310
+carbon هذا متصل فيها كلور و carbon و carbon أنهي
+
+167
+00:14:06,310 --> 00:14:11,290
+أعلى واحدة بعدها ال carbon اللى تحت اللى حاملة
+
+168
+00:14:11,290 --> 00:14:15,610
+كلور و إثلو اتش و بعدها اللى فوق إذا كيف الحركة
+
+169
+00:14:15,610 --> 00:14:17,790
+اللى موجودة عندى الآن هنا حوالينا
+
+170
+00:14:21,210 --> 00:14:29,050
+عكس عقارب الساعة فكأنه المركب S لكن لأنه هذي جاي
+
+171
+00:14:29,050 --> 00:14:32,990
+على الجانب، شو بيطلع؟ R، هذا الكلام حكيناه بشكل
+
+172
+00:14:32,990 --> 00:14:39,890
+تفصيل الحصة الماضية، إذا هذا الموقع 2R، واضح؟ هذا
+
+173
+00:14:39,890 --> 00:14:44,790
+الموقع 2 ماخد ال configuration R، الآن لو جينا على
+
+174
+00:14:44,790 --> 00:14:55,020
+الموقع 3، و الأقل مجموعةنمر واحد، اتنين، هذي ال
+
+175
+00:14:55,020 --> 00:14:59,620
+carbon، تلاتة، هذي ال ethylene تطلعوا كيف الحركة
+
+176
+00:14:59,620 --> 00:15:04,820
+تقعدتنا بينها؟ عكس، عكس، عكس، عكس، عكس، عكس، عكس،
+
+177
+00:15:04,820 --> 00:15:05,120
+عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس،
+
+178
+00:15:05,120 --> 00:15:06,660
+عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس،
+
+179
+00:15:06,660 --> 00:15:10,780
+عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكس،
+
+180
+00:15:10,780 --> 00:15:16,250
+عكس، عكس، عكس، عكس، عكس، عكس، عكس، عكإنه بالنسبة
+
+181
+00:15:16,250 --> 00:15:20,990
+للجزء الأول و صورته في المرايا كل نقطة عكس التانية
+
+182
+00:15:20,990 --> 00:15:24,910
+في المرايا و هذا كلام منطقي، مظبوط ولا لا؟ يعني
+
+183
+00:15:24,910 --> 00:15:32,520
+الـ2Rإجمالها 2S، هدول عكس بعض، وهنا الـ3R إجمالها
+
+184
+00:15:32,520 --> 00:15:38,380
+3S عكس بعض، بزن كل إشي عكس التاني، إذا هدول صاروا
+
+185
+00:15:38,380 --> 00:15:42,520
+صورة بعض في المرأة غير متطابقة، فلو سألت ما
+
+186
+00:15:42,520 --> 00:15:46,660
+العلاقة بين واحد واتنين، they are enantiomersصورة
+
+187
+00:15:46,660 --> 00:15:52,580
+بعض في المرآة، وهذه الصورة تكون غير متطابقة، بديش
+
+188
+00:15:52,580 --> 00:15:56,900
+ناس منكم يغلطوا، بديش ناس منكم يغلطوا يقولوا ليش
+
+189
+00:15:56,900 --> 00:16:01,780
+مش متطابقة، بمعنى أن البعض قد يتخيل، و هذا تخيل
+
+190
+00:16:01,780 --> 00:16:05,320
+خاطئ، أنه انا لو مسكت هذا الجزء و قلت جزيك، بده
+
+191
+00:16:05,320 --> 00:16:11,190
+ينطبق على اللهان، ليش هذه الفكرة خطأ؟لأن هذا الجزء
+
+192
+00:16:11,190 --> 00:16:15,170
+و هذا الجزء ليسوا في مستوى واحد ليسوا في مستوى
+
+193
+00:16:15,170 --> 00:16:20,450
+اللوح هذه المجموعات ال CL و ال H و ال CL و ال H
+
+194
+00:16:20,450 --> 00:16:25,850
+كيف بيكونوا؟ بيكونوا للأمام بديكوا تكونوا متخيلين
+
+195
+00:16:25,850 --> 00:16:30,510
+هذا الجزء صح أنا رسمه زي هيك لكن هو على أرض الواقع
+
+196
+00:16:30,510 --> 00:16:34,990
+ال CL و ال H هدول مجموعتين للأمام و اللي تحت منهم
+
+197
+00:16:34,990 --> 00:16:39,430
+كمان مجموعتين للأمام و ال CH3 و ال H المجموعات
+
+198
+00:16:39,690 --> 00:16:44,530
+للخلف نفس الاشي هذا هان عشانك لو وجدت جلبت هذا
+
+199
+00:16:44,530 --> 00:16:50,590
+هدولة بقشره لوين؟ للأمام لو وجدت الجزء التاني و
+
+200
+00:16:50,590 --> 00:16:56,450
+جلبته و لفه بصير للخلف هل حصل انطباق؟ لأ لو كان
+
+201
+00:16:56,450 --> 00:17:01,450
+الجزء planner في مستوى واحد كان هذا و هذا بنطبقوا
+
+202
+00:17:01,450 --> 00:17:05,230
+على بعض لكن عدم الانطباق لأن هذا و هذا they are
+
+203
+00:17:05,230 --> 00:17:09,910
+not plannerمش في مستوى واحد، واضح الفكرة هنا؟
+
+204
+00:17:09,910 --> 00:17:12,930
+هدولة مش في مستوى واحد، إذن هدولة واحد واتنين
+
+205
+00:17:12,930 --> 00:17:16,430
+العلاقة بينهم هنا، مش مفهوم. الآن، لو إجينا
+
+206
+00:17:16,430 --> 00:17:21,990
+واطلعنا على تلاتة واربعة، برضه إذا حددنا هنا two
+
+207
+00:17:21,990 --> 00:17:29,650
+R، three S، وبعدين هنا two S، three R، R إقبالها
+
+208
+00:17:29,650 --> 00:17:35,980
+S، وS إقبالها R، بمعنى إنه في جزء كل نقطةعكس إيش؟
+
+209
+00:17:35,980 --> 00:17:39,740
+التانية، وهذا اللي بيصير في المرأة، يعني لما أنا
+
+210
+00:17:39,740 --> 00:17:44,840
+بجب في المرأة، بعمل زي هيك، الصورة كيف بتكون؟ كل
+
+211
+00:17:44,840 --> 00:17:48,400
+نقطة لازم تكون عكس التانية، كل نقطة في الصورة، لو
+
+212
+00:17:48,400 --> 00:17:52,720
+نقطة واحدة اختلت، بتبطل نحكي عن صورة في المرأة،
+
+213
+00:17:52,720 --> 00:17:57,560
+واضح؟ إذن، تلاتة وأربعة، برضه العلاقة بينهم
+
+214
+00:17:57,560 --> 00:18:01,820
+Enansomers، واضح؟ برضه العلاقة بين تلاتة وأربعة
+
+215
+00:18:01,820 --> 00:18:06,310
+Enansomersالآن لو يقترح إيجي تقولي ما العلاقة بين
+
+216
+00:18:06,310 --> 00:18:11,930
+المركب واحد و تلاتة اتطلعوا انتوا بالنظر شوفولي بس
+
+217
+00:18:11,930 --> 00:18:18,890
+مواقع ال CL هيك العلمة بالأحمد هل هدولا التنين
+
+218
+00:18:18,890 --> 00:18:23,950
+صورت بعض في المرأة بس هم مش صورت بعض في المرأة إذا
+
+219
+00:18:23,950 --> 00:18:27,970
+الواحد و تلاتة ديستيريو مرسي طب لو قولت العلاقة
+
+220
+00:18:27,970 --> 00:18:29,170
+بين واحد و أربعة
+
+221
+00:18:33,380 --> 00:18:39,820
+طب لو قلت العلاقة بين اتنين و تلاتة لو قلت العلاقة
+
+222
+00:18:39,820 --> 00:18:45,900
+بين اتنين و اربعة دا ياس تيريو مارس واضح؟ اذا هنا
+
+223
+00:18:45,900 --> 00:18:52,360
+لما انا بأعمل two chiral centers و بطلع اربع
+
+224
+00:18:52,360 --> 00:18:55,520
+مركبات في الحالة دي طلع عند اربع مركبات بعد شوية
+
+225
+00:18:55,520 --> 00:18:59,980
+بناخد حالة بصيروا المركبات فيها جديشأقل من أربعة
+
+226
+00:18:59,980 --> 00:19:03,480
+بلاحظ أنه فيهم مركبين enansomers وفيهم مركبين
+
+227
+00:19:03,480 --> 00:19:07,240
+تانيين enansomers لكن أي فرد من هذا ال enansomers
+
+228
+00:19:07,240 --> 00:19:14,440
+مع المجموعة الثانية بيمثل diastereomers واضح فال
+
+229
+00:19:14,440 --> 00:19:17,580
+diastereomers زي تعريفهم they are non mirror image
+
+230
+00:19:17,580 --> 00:19:23,200
+stereoisomers زي ما قلنالكوا العدد الأقصى ما يمكن
+
+231
+00:19:24,610 --> 00:19:28,330
+في هذه الحالة two to the two اتنين أقصى اتنين
+
+232
+00:19:28,330 --> 00:19:36,610
+بيساوي عندنا أربعة واضح؟ الان لو بتكنتيجوا من خلال
+
+233
+00:19:36,610 --> 00:19:40,650
+الرموز بعيدا عن الأشكال لو بتكنتيجوا من خلال
+
+234
+00:19:40,650 --> 00:19:45,110
+الرموز و تعرفوا ليه ان هل ياتورا هدولة بمثله
+
+235
+00:19:45,110 --> 00:19:49,550
+انانشو مارس ولا داياستيرو مارس نتطلع بنظرة أوسع
+
+236
+00:19:49,550 --> 00:19:57,460
+على الرموز إذا في الرموز اللي عندى كلمجموعة عكس
+
+237
+00:19:57,460 --> 00:20:04,700
+التانية كل واحدة عكس التانية 2R 2S 3R 3S أو في
+
+238
+00:20:04,700 --> 00:20:10,810
+الحالة دي 2R2S, 3S, 3R إذا كل حاجة عكس التانية،
+
+239
+00:20:10,810 --> 00:20:15,490
+معنا ذلك العلاقة بين القطعتين المحددات انانش و
+
+240
+00:20:15,490 --> 00:20:20,470
+مارس، الآن لو شيء كان عكس التاني و شيء زي التاني،
+
+241
+00:20:20,470 --> 00:20:26,010
+معنا ذلك ديستيريو مارس، واضح؟ لو شيء عكس التاني و
+
+242
+00:20:26,010 --> 00:20:30,090
+شيء زي التاني، معنا ذلك ديستيريو مارس، طب لو كل
+
+243
+00:20:30,090 --> 00:20:36,910
+إشي زي بعض، بيكون the same compoundواضح؟ انا هذا
+
+244
+00:20:36,910 --> 00:20:41,710
+الكلام .. هذا الكلام ليش بحكيه لكم؟ لأنه بصراحة مش
+
+245
+00:20:41,710 --> 00:20:45,950
+دائما .. مش دائما بنجيبلكوا الأمور وردية والرسمة
+
+246
+00:20:45,950 --> 00:20:51,550
+واضحة زي هال ويكون بإمكانكم على السبورة بسهولة
+
+247
+00:20:51,550 --> 00:20:57,610
+اتحددوا العلاقة ما بين قطعتين فبصير في هذه الحالة
+
+248
+00:20:57,610 --> 00:21:01,920
+أسهل شي عندكم أنكم اتحددوا إيش؟الـ configuration
+
+249
+00:21:01,920 --> 00:21:06,960
+حتى لو عندي one chiral center حتى لو عندي one
+
+250
+00:21:06,960 --> 00:21:11,360
+chiral center ممكن أرسمه إلكم بحيث لما تطلعوا أكون
+
+251
+00:21:11,360 --> 00:21:15,580
+رسمه بطرق مختلفة ما تقدروش تقولولي ما العلاقة بين
+
+252
+00:21:15,580 --> 00:21:20,800
+جزيين خلينا ناخد مثال لو تخيلنا إنه في عندنا هذا
+
+253
+00:21:20,800 --> 00:21:25,560
+المركب حطينا chlorine و H و Br
+
+254
+00:21:36,370 --> 00:21:40,930
+الان اللي مركزنا انك تشوف الأمور في المرايا
+
+255
+00:21:44,540 --> 00:21:49,740
+ولا عمرها شايفة إيش فيهم جايب سهولة في المرأة لكن
+
+256
+00:21:49,740 --> 00:21:54,060
+لو أنا قولت هذا المركب و هذا المركب إيش إسمهم؟ هذا
+
+257
+00:21:54,060 --> 00:21:58,300
+عبارة عن two carbon زي ال carbon الأولى حملة
+
+258
+00:21:58,300 --> 00:22:02,160
+bromochlor و ال carbon التانية مثل و هذه نفس
+
+259
+00:22:02,160 --> 00:22:04,840
+الإشعار carbon الأولى حملة bromochlor و ال carbon
+
+260
+00:22:04,840 --> 00:22:10,020
+التانية مثل إذا كل واحد من هدول إيش اسمه? one
+
+261
+00:22:10,020 --> 00:22:16,910
+bromo one chloroهي atom one وهي atom two وهي الجزء
+
+262
+00:22:16,910 --> 00:22:23,190
+البساطة وهي atom one وهي atom two one bromo one
+
+263
+00:22:23,190 --> 00:22:32,530
+chloro اثنين الاتنين هنا one bromo one chloro
+
+264
+00:22:32,530 --> 00:22:38,150
+اثنين نعم
+
+265
+00:22:39,580 --> 00:22:42,700
+ليش non-stereoisomers؟ نيجي نتفاهم معاك، إن الله
+
+266
+00:22:42,700 --> 00:22:45,840
+يحب الصابرين، قولنا الـ Stereoisomers فيهم نفس
+
+267
+00:22:45,840 --> 00:22:50,200
+الذرات، بس بيضال عندى قصة مواقع الارتباط، الآن هنا
+
+268
+00:22:50,200 --> 00:22:55,720
+إيش عندك؟ Carbon متصلة بماذا؟ أكلور و بروم و أتش و
+
+269
+00:22:55,720 --> 00:23:00,800
+مثل، وهنا إيش عندك؟ Carbon متصلة بماذا؟ أكلور و
+
+270
+00:23:00,800 --> 00:23:05,060
+بروم و أتش و مثلإذا ببساطة هدول الاتنين عندهم واحد
+
+271
+00:23:05,060 --> 00:23:10,000
+من احتمالين اما بيكونوا نفس المركب مرسوم بطرق
+
+272
+00:23:10,000 --> 00:23:13,020
+مختلفة و احنا مر علينا سابق ان المركب بنرسمه بطرق
+
+273
+00:23:13,020 --> 00:23:18,720
+كتيرة او بيكونوا enantiomers ولا ثالث لا دول
+
+274
+00:23:18,720 --> 00:23:21,580
+احتمالين يعني لما بيكون عندى one chiral center
+
+275
+00:23:21,580 --> 00:23:26,010
+هدول يا بيكونوا نفس المركبمرسوم بطرق مختلفة
+
+276
+00:23:26,010 --> 00:23:29,110
+بيكونوا in and sumars وقت إيش بيكونوا نفس المُركّب
+
+277
+00:23:29,110 --> 00:23:33,710
+إذا إتيت عملت configuration لجيت هذا R و هذا R بس
+
+278
+00:23:33,710 --> 00:23:37,170
+تنتج أنه the same compound إذا إتيت عملت
+
+279
+00:23:37,170 --> 00:23:41,230
+configuration لجيت هذا S و هذا S the same compound
+
+280
+00:23:41,230 --> 00:23:45,470
+إذا لجيت هذا R و هذا S بدهم يكونوا in and sumars
+
+281
+00:23:45,470 --> 00:23:50,470
+أو هذا S و هذا R واضح؟ إذا تحديد العلاقة بينهم
+
+282
+00:23:50,470 --> 00:23:56,860
+عشان أحددها لازم أحددالـ Configuration أسهلليش أحد
+
+283
+00:23:56,860 --> 00:24:00,400
+الـ Configuration هاي أقل مجموعة أنا حددتها أكيد
+
+284
+00:24:00,400 --> 00:24:04,480
+في منكناس ناشطين جدا بيقدروا يقولولي إيش هذا
+
+285
+00:24:04,480 --> 00:24:13,900
+المركب أين باتحرك أنا بـR بعدها اكلور بعدها مثل
+
+286
+00:24:13,900 --> 00:24:18,320
+ماشي عكس عقارة بسيارة نفسها إذا هذا S إذا هذا
+
+287
+00:24:18,320 --> 00:24:22,600
+المركب لو بدي أشوف إيش اسمه S one bromo one cloro
+
+288
+00:24:22,600 --> 00:24:28,920
+اثنينالان لو اتيت على هذا المُركّب بطلّح هنا عند
+
+289
+00:24:28,920 --> 00:24:35,740
+بي ار اكلور مثل ماشي بهذا الشكل يتبين as و هذا على
+
+290
+00:24:35,740 --> 00:24:41,740
+الجانب ار اذا هذا ار اذا ما العلاقة بينهم they are
+
+291
+00:24:41,740 --> 00:24:46,320
+enantiomers شوفتوا كيف انا عرفت العلاقة بينهم من
+
+292
+00:24:46,320 --> 00:24:53,280
+خلال ال configurationواضح؟ طيب، الآن هذا الكلام
+
+293
+00:24:53,280 --> 00:24:57,400
+سهل، يعني لو بدنا نيجي نسهلكم في الامتحان مركبين ب
+
+294
+00:24:57,400 --> 00:25:00,840
+one chiral center، شو العلاقة بينهم؟ بدكم تحددوا
+
+295
+00:25:00,840 --> 00:25:04,440
+ال configuration، يا بيطلع نفس الاشي the same
+
+296
+00:25:04,440 --> 00:25:09,680
+compound، يا بيطلع enantiomers هذا الكلام مرتبط
+
+297
+00:25:09,680 --> 00:25:14,700
+لما يكون عندكم one chiral center لما يصير عندكم
+
+298
+00:25:14,700 --> 00:25:20,490
+two chiral centersبصير عندكم مش احتمالي الا المركب
+
+299
+00:25:20,490 --> 00:25:26,790
+تلاتة يا بيكونوا the same compound لما يطلع ال R و
+
+300
+00:25:26,790 --> 00:25:31,770
+ال S لتنتين نفس الاشي the same compound يا بيكونوا
+
+301
+00:25:31,770 --> 00:25:37,130
+enansomers لما كل واحدة عكس التانية يا بيكونوا
+
+302
+00:25:37,130 --> 00:25:40,810
+diastereomers لما واحدة عكس التانية و واحدة زي
+
+303
+00:25:40,810 --> 00:25:46,560
+التانية واضح؟ زي هذا و هذا مثلا طلعوا هنا R و Rزي
+
+304
+00:25:46,560 --> 00:25:53,040
+بعض أو عكس بعض كأن واحدة زي التانية واحدة عكس
+
+305
+00:25:53,040 --> 00:25:57,400
+التانية فكأنه جزء جزء منهم بين معكوس في المرايا
+
+306
+00:25:57,400 --> 00:26:01,720
+والجزء التاني نفس الاشي فبالمجمل بيكون مش صورة بعض
+
+307
+00:26:01,720 --> 00:26:05,540
+في المرايا بيكون عبارة عن diastereomers طبعا أكيد
+
+308
+00:26:05,540 --> 00:26:11,380
+بيلزم أن نعمل مثال الآن على هذه العلاقة نرسم أو
+
+309
+00:26:11,380 --> 00:26:19,360
+ناخد جزيئات ونقول ما العلاقةبين هذولا الشكلين
+
+310
+00:26:19,360 --> 00:26:31,280
+خلّينا
+
+311
+00:26:31,280 --> 00:26:38,120
+ننظر لهذه الأمثلة واضح؟
+
+312
+00:26:38,120 --> 00:26:42,240
+المركب الأول شبيه بالكلام اللي قبل شوية حكينا
+
+313
+00:26:42,240 --> 00:26:47,100
+ولاحظوا هنالما بتيجوا تتطلعوا للوهلة الأولى
+
+314
+00:26:47,100 --> 00:26:51,680
+بتكونوا مش عارفين إيش أسهل إيش تعملوه تحددوا
+
+315
+00:26:51,680 --> 00:26:56,720
+configuration فهي أقل مجموعة وهي هنا أقل مجموعة من
+
+316
+00:26:56,720 --> 00:27:02,080
+تعطينا هذا المركب R ولا S أنا بتحرك بي R كلور مثل
+
+317
+00:27:02,080 --> 00:27:12,340
+R وهنا بتحرك بي R كلور مثل Rطب دو أس طب دو أر طلع
+
+318
+00:27:12,340 --> 00:27:16,940
+هذا R و هذا R إذا هدولا بمثله نفس الجزيق مرسوم
+
+319
+00:27:16,940 --> 00:27:22,500
+بطرق مختلفة okay؟ الأن لو أخدنا المثال التاني لو
+
+320
+00:27:22,500 --> 00:27:26,840
+أخدنا المثال التاني هنا هذا عبارة عن جزيق إيش لو
+
+321
+00:27:26,840 --> 00:27:34,560
+بدي أسميه بالمجمل؟ فيه ذرة مثل كاربون كاربون مثل
+
+322
+00:27:34,560 --> 00:27:40,400
+إذا هذا جزيق بيوتين بيوتينعلى موقع اتنين في
+
+323
+00:27:40,400 --> 00:27:45,540
+البيوتين، شو عندكم؟ على موقع تلاتة، كلور، إذا هذا
+
+324
+00:27:45,540 --> 00:27:48,220
+لو أنا قولت، جايب بس هذا القطع الواحدة على
+
+325
+00:27:48,220 --> 00:27:52,300
+الامتحان و جايبكم name the following molecule إيش
+
+326
+00:27:52,300 --> 00:27:58,400
+هنقول عنه؟ two-chromo three
+
+327
+00:27:58,400 --> 00:28:06,620
+-chloro-butane الآن، ضال عندي مشكلتين، شو هم؟ إنه
+
+328
+00:28:06,620 --> 00:28:11,490
+في عنديtwo chiral centers كل واحد chiral center
+
+329
+00:28:11,490 --> 00:28:15,590
+لازم أحدد ال configuration حواليه كل chiral center
+
+330
+00:28:15,590 --> 00:28:19,730
+لازم أحدد ال configuration حواليه فلو أجيت على
+
+331
+00:28:19,730 --> 00:28:23,410
+موقع اتنين و قلت هي أقل مجموعة و على موقع تلاتة هي
+
+332
+00:28:23,410 --> 00:28:29,430
+أقل مجموعة كيف أنا بدي أتحرك أنا في ال ball ال
+
+333
+00:28:29,430 --> 00:28:32,650
+carbon هادم الكبير اللي حامل شغلاتي كتير على المثل
+
+334
+00:28:32,650 --> 00:28:36,170
+إذا
+
+335
+00:28:36,170 --> 00:28:43,640
+ال two أنا عبارة عن إيش؟S مظبوط؟ لو جيت هنا الكلور
+
+336
+00:28:43,640 --> 00:28:53,120
+الكربون هادى المثلث من الأعلى إلى الأقل برضه 3S
+
+337
+00:28:53,120 --> 00:29:01,600
+إذا هذا المركب ال 2 فيه S و ال 3 فيه S إذا 2S 3S
+
+338
+00:29:01,600 --> 00:29:05,740
+نيجي للجزء التانى اللى هو نفس الشي طوف روم و 3
+
+339
+00:29:05,740 --> 00:29:06,680
+كلور و بيوتين
+
+340
+00:29:09,410 --> 00:29:17,430
+أقل مجموعة وهذا موقع تلاتة بعدين من واحد حركة الآن
+
+341
+00:29:17,430 --> 00:29:25,790
+بعدها الكاربون هادي بعدها
+
+342
+00:29:25,790 --> 00:29:35,410
+PR إذا PR لو جدت طلعت هناك load بعد الكاربون هادي
+
+343
+00:29:35,410 --> 00:29:37,910
+بعد الميتو
+
+344
+00:29:42,220 --> 00:29:50,020
+الان بعد هيك بدكم تتطلع على هدول الرموز وتسألوا
+
+345
+00:29:50,020 --> 00:29:52,820
+نفسكم ايش العلاقة بينهم
+
+346
+00:29:56,870 --> 00:30:02,330
+عكس التانية و واحدة زي التانية طالما مش كل إشي عكس
+
+347
+00:30:02,330 --> 00:30:07,410
+بعض إذا ده يستيريو مارس لإن شرط ال enantiomars لو
+
+348
+00:30:07,410 --> 00:30:12,030
+عندى عشرة chiral centers كل واحد عكس التاني لإن
+
+349
+00:30:12,030 --> 00:30:15,630
+أنا تخيلوني مثلا هى قدام المرايا هى chiral center
+
+350
+00:30:15,630 --> 00:30:19,050
+هى اتنين هى تلاتة اربعاية خمسة هى ستة لما بقى قدام
+
+351
+00:30:19,050 --> 00:30:23,790
+المرايا كل نقطة بتكون عكس التانية ولا لأ شرط ال
+
+352
+00:30:23,790 --> 00:30:28,300
+enantiomarsيعني لو كان عندكوا عشرة chiral centers
+
+353
+00:30:28,300 --> 00:30:31,980
+مركب فيه عشرة chiral centers والتاني فيه عشرة
+
+354
+00:30:31,980 --> 00:30:35,800
+chiral centers وقت إيش بيكونوا enantiomers؟ لما كل
+
+355
+00:30:35,800 --> 00:30:42,130
+نقطة عكس التانية، إذا واحدة منهم اختلتبطل الجزيئ
+
+356
+00:30:42,130 --> 00:30:45,110
+انها شمازية لو كان عندى مركب فيه عشرة chiral
+
+357
+00:30:45,110 --> 00:30:49,410
+centers تسعة منهم كل واحدة عكس التانية عكس التانية
+
+358
+00:30:49,410 --> 00:30:53,670
+عكس التانية وواحدة زي التانية صار دا استيريو مارسي
+
+359
+00:30:53,670 --> 00:30:57,930
+بطل صورة بعض في المرمى، واضح؟ إذا هدول عبارة عن دا
+
+360
+00:30:57,930 --> 00:31:01,370
+استيريو مارسي، شو سؤالك؟ مثلا، لو كان في احد
+
+361
+00:31:01,370 --> 00:31:05,330
+الثلاثين chiral center يعني .. ال chiral center ..
+
+362
+00:31:05,330 --> 00:31:12,710
+يعني اتصرف على كابونزين؟أكيد، لا طبعا، منفعش، إذا
+
+363
+00:31:12,710 --> 00:31:15,910
+عندك two chiral centers، بدك تحدد إلى اتنين،
+
+364
+00:31:15,910 --> 00:31:18,870
+تانين، منفعش زي هذا المثال، هذا المثال كان فيه بس
+
+365
+00:31:18,870 --> 00:31:24,470
+one chiral center، لو عندك تلاتة، بدك تحدد إلى
+
+366
+00:31:24,470 --> 00:31:29,950
+تلاتة، واضح؟ على أي حال، هذه الأمثلة اللي هنا، هذه
+
+367
+00:31:29,950 --> 00:31:34,520
+الأمثلة اللي هنابرضه نفس الفكرة بإمكانكوا تعملوها
+
+368
+00:31:34,520 --> 00:31:37,680
+بهدوء و تحلوها في البيت صار عندكوا هاي المشاكل
+
+369
+00:31:37,680 --> 00:31:41,180
+بترجعونا اتحددوا ال configurations و ال
+
+370
+00:31:41,180 --> 00:31:45,360
+configurations و حسب ما علمناكم إذا عندكم two
+
+371
+00:31:45,360 --> 00:31:51,100
+chiral centers كام احتمال عندكم؟ لأ في العلاقة
+
+372
+00:31:51,100 --> 00:31:57,540
+بينهميا دي same compound، يا انان شو مارز، يا ده
+
+373
+00:31:57,540 --> 00:32:01,980
+يا ستيريو مارز، واضح؟ يا دي same compound، يا انان
+
+374
+00:32:01,980 --> 00:32:04,400
+شو مارز، يا ده يا ستيريو مارز، تعملوهم وخدوا
+
+375
+00:32:04,400 --> 00:32:09,840
+وقتكم، لأنه بصراحة هذا الكلام قد يبدو سهل، لكن
+
+376
+00:32:09,840 --> 00:32:12,880
+أصعب الشيء اللي هي ال stereo chemistry، بمعنى إذا
+
+377
+00:32:12,880 --> 00:32:17,640
+أنتم ماجعتوش في البيت تتخربشوا و تعملوا و تغلطوا و
+
+378
+00:32:17,640 --> 00:32:22,900
+انجابوا صح، مابتفهماش، واضح؟يعني الموضوع الـ
+
+379
+00:32:22,900 --> 00:32:27,380
+Stereochemistry مش هالموضوع ال .. سهل، أنا بعمل
+
+380
+00:32:27,380 --> 00:32:30,520
+الأشياء بسهولة لأنه عندي خبرة، بس إذا إنتوا ما
+
+381
+00:32:30,520 --> 00:32:34,560
+روحتوش على البيت و عملتوها، هتلاقوا إنه حد
+
+382
+00:32:34,560 --> 00:32:43,120
+يتمشكلوا، واضح؟ الآن نرجع لل slide التانية، يمكن
+
+383
+00:32:43,120 --> 00:32:49,130
+لاحظوا إنه إحنا حكينالاحظوا إنه إحنا حكينا لو كان
+
+384
+00:32:49,130 --> 00:32:52,910
+عندنا two chiral centers، الحد الأقصى المتوقع عندي
+
+385
+00:32:52,910 --> 00:32:59,930
+قداش؟ كام مركب مختلف؟ أربعة؟ قولنا ممكن يكون أقل،
+
+386
+00:32:59,930 --> 00:33:05,920
+بس مش ممكن يكون أكثر خلينا ناخد مثال على الأقللو
+
+387
+00:33:05,920 --> 00:33:10,620
+أخدنا نفس المثال السابق بس غيرنا فيه شغلة بسيطة
+
+388
+00:33:10,620 --> 00:33:14,840
+إذا بتذكروا المثال السابق أنا نسخته نسخته كان مثل
+
+389
+00:33:14,840 --> 00:33:17,420
+كاربون حاملة كلورو أتش كاربون حاملة كلورو أتش و
+
+390
+00:33:17,420 --> 00:33:23,500
+أنا إيش إثل نحط هنا مثل بمعنى إنه صار مركب two
+
+391
+00:33:23,500 --> 00:33:27,320
+three-dichlorobutane
+
+392
+00:33:27,320 --> 00:33:33,730
+قبل شوية شو كان؟two three dichloro بنتين كانوا
+
+393
+00:33:33,730 --> 00:33:41,650
+خمسة خليناهم أربعة two three dichloro بيتين بدل
+
+394
+00:33:41,650 --> 00:33:45,550
+two three dichloro بنتين وجربنا نفس الرسومات
+
+395
+00:33:45,550 --> 00:33:49,910
+وحطينا chlorine عكس بعض وصورتهم في المرقة وحطينا
+
+396
+00:33:49,910 --> 00:33:57,050
+chlorine زي بعض وصورتهم في المرقةفي المرقة واضح؟
+
+397
+00:33:57,050 --> 00:34:00,830
+يعني نفس الرسومات السابقة نفس الرسم السابق نسخناها
+
+398
+00:34:00,830 --> 00:34:04,530
+كاملة بدل ما احنا كاتبين اثل اثل اثل اثل اثل اثل
+
+399
+00:34:04,530 --> 00:34:06,470
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+400
+00:34:06,470 --> 00:34:07,570
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+401
+00:34:07,570 --> 00:34:07,930
+اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل اثل
+
+402
+00:34:07,930 --> 00:34:14,730
+اثل اثل اثل اثل اثل اثل
+
+403
+00:34:21,080 --> 00:34:28,280
+3S هدولة إيش العلاقة بإنهم كل واحدة فيهم؟ عكس
+
+404
+00:34:28,280 --> 00:34:34,460
+التانية إذا هدولة Enantiomers واضح؟ ابنجلة اللي
+
+405
+00:34:34,460 --> 00:34:46,040
+موجودين عندي هنا بتطلعوا هذي 2R 2S و هذي 3S 3Rبرضه
+
+406
+00:34:46,040 --> 00:34:50,420
+مبينين عكس بعض، بالتالي ممكن تبدو تفكروا ان هدوله
+
+407
+00:34:50,420 --> 00:34:54,840
+يكونوا إيش In Animals حقيقة لو اعملنا models
+
+408
+00:34:54,840 --> 00:35:00,180
+وناقشنا هدوله المركبين بتفاصيل هلاج انهم نفس
+
+409
+00:35:00,180 --> 00:35:06,060
+المركب مش In Animals طبعا حيصير السؤال ليش هذا
+
+410
+00:35:06,060 --> 00:35:12,320
+الكلام صار عندك؟ ليش هدوله بصيروا نفس المركب رغم
+
+411
+00:35:12,320 --> 00:35:15,860
+ان احنا كنا نقول انهإذا كل واحد عكس التانية، بنكون
+
+412
+00:35:15,860 --> 00:35:20,620
+نحكي عن initials هنا إحنا أمام جزيق مختلف عن
+
+413
+00:35:20,620 --> 00:35:26,100
+الجزيق السابق، هذا الجزيق جزيق متماثل داخليًا،
+
+414
+00:35:26,100 --> 00:35:30,200
+بمعنى إن النُص اللي فوق من الجزيق نفس النُص اللي
+
+415
+00:35:30,200 --> 00:35:33,900
+تحت، يعني لو تخيلتوا إن الجزيق مجسوم بمراية بهذا
+
+416
+00:35:33,900 --> 00:35:39,040
+الشكل، ملاحظين انتوا؟ إيش في عنكم فوق؟ Carbon،
+
+417
+00:35:39,040 --> 00:35:44,070
+حاملة، قدش كلور مثل، وتحت؟Carbon، حمضة، أدشكلون،
+
+418
+00:35:44,070 --> 00:35:47,730
+مثل فهذا الجزء مختلف عن السابق في السابق لو كنت
+
+419
+00:35:47,730 --> 00:35:51,830
+بتحط مرايا هذه في النص كانت هذه مثله وهذه إثلا
+
+420
+00:35:51,830 --> 00:35:57,770
+وبالتالي كان الجزء غير متماثل داخلي يعني مش النص
+
+421
+00:35:57,770 --> 00:36:02,030
+اللي فوق منه زي النص اللي تحت هذا الجزء نفسه فيه
+
+422
+00:36:02,030 --> 00:36:05,410
+تماثل داخلي النص اللي فوق منه عكس النص اللي تحت
+
+423
+00:36:05,410 --> 00:36:11,150
+بناء على ذلك هذا بيقدر إيش؟بقدّي ان هذا و هذا
+
+424
+00:36:11,150 --> 00:36:15,210
+يكونوا نفس الاشي كيف انا ممكن اتخيلها بإمكانكوا
+
+425
+00:36:15,210 --> 00:36:20,670
+تتخيلوا ان انا حطيت هنا دبوس او مصمار و لفيت هذا
+
+426
+00:36:20,670 --> 00:36:27,110
+المركب .. لفيت هذا المركب بهذا الشكل و جبته هيك
+
+427
+00:36:27,110 --> 00:36:31,370
+منطبق عليهم ولا لا لاحظوا انا لما بلفه حوالين محور
+
+428
+00:36:31,370 --> 00:36:39,040
+هدول اللي متجهات للامام هل غيرتهم؟ مغيرتهم مشمظبوط
+
+429
+00:36:39,040 --> 00:36:43,700
+ولا لا؟ أنا بس حطيت هنا دبوس و لفيت الجزيق هذا
+
+430
+00:36:43,700 --> 00:36:46,840
+صاروا ال hydrogen زيك و ال chlorine اتجهت و حطيته
+
+431
+00:36:46,840 --> 00:36:51,140
+ينطبق هنا و انطبق على هذا و بناء على ذلك هذا و هذا
+
+432
+00:36:51,140 --> 00:36:54,660
+نفس الشيء طب كان ممكن واحدة تقول طب ليش قبل شوية
+
+433
+00:36:54,660 --> 00:36:59,980
+ما قلتش هالفكرة فزام احنا بنقدر نتخيل ان هنا محور
+
+434
+00:36:59,980 --> 00:37:06,740
+و اللف هذا و الخلية انطبق واضح؟ هاي المحور؟
+
+435
+00:37:11,610 --> 00:37:14,750
+والطبق على هذا .. ليش قبل شوية في المثال السابق
+
+436
+00:37:14,750 --> 00:37:20,310
+ماكنش هذا الكلام مصير؟ لأنه ماكنش الجزء اللي فوق
+
+437
+00:37:20,310 --> 00:37:24,390
+زي اللي تحت .. هذا الآن لما بلف فوق .. في عندي هذا
+
+438
+00:37:24,390 --> 00:37:28,750
+المثل .. وين بدأ تيجي؟ تحت .. و هذا المثل .. وين
+
+439
+00:37:28,750 --> 00:37:33,150
+بدأ تروح؟ فوق .. لأن هدولا المجموعتين زي بعض ..
+
+440
+00:37:33,150 --> 00:37:36,390
+هذا بتيجي لتحت .. و هذا بتيجي لفوق .. بيجي بالطبق
+
+441
+00:37:36,390 --> 00:37:40,390
+هنا .. طيب لو رجعنا للمثال السابق .. إيش كان في
+
+442
+00:37:40,390 --> 00:37:46,510
+عندكم؟مثل و إثل فبناء عذرك في المثال السابق لو
+
+443
+00:37:46,510 --> 00:37:53,330
+لفيته المثل بتيجي ع المثل و الإثل بتيجي ع المثل
+
+444
+00:37:53,330 --> 00:37:58,590
+إذا مش متطابق ماكانش هذا الكلام بينفع في المثال
+
+445
+00:37:58,590 --> 00:38:06,690
+السابق خليني أرجع للمثال السابق اللي هو اللهاماه
+
+446
+00:38:06,690 --> 00:38:10,610
+اتخيلوا لو انا عملت نفس الشغلة لو انا عملت نفس
+
+447
+00:38:10,610 --> 00:38:14,890
+الشغلة اتخيلت
+
+448
+00:38:14,890 --> 00:38:19,690
+في هذا الجزء انه هي عندى محوى و بدى الفه صح انا
+
+449
+00:38:19,690 --> 00:38:25,110
+جيبت ال chlorine على الجهة دى وظلوا للامام و جيبت
+
+450
+00:38:25,110 --> 00:38:29,270
+ال ash على الجهة دى وظلوا للامام اذا كل الجثة اللى
+
+451
+00:38:29,270 --> 00:38:34,830
+امامي صار فيه ايشتنطبق لكن ايش المشكلة؟ خلّيت ال
+
+452
+00:38:34,830 --> 00:38:39,970
+مثل تيجي هنا والإفر تيجي هنا إذا ما تنطبقوش شوفتوا
+
+453
+00:38:39,970 --> 00:38:44,950
+الفرق بين الحالتين؟ وبناء على ذلك في حالة التماثل
+
+454
+00:38:44,950 --> 00:38:50,910
+اللي إحنا شايفينها في ال two three dichlorobentain
+
+455
+00:38:50,910 --> 00:38:57,350
+صاروا هدولة عبارة عن نفس المُركّب إذا كام isomers
+
+456
+00:38:57,350 --> 00:39:02,040
+طلع عنده؟واحد، اتنين، و هدول دي are the same
+
+457
+00:39:02,040 --> 00:39:09,140
+compound، تلاتة، واضح؟ مش اربعة، تلاتة، طيب، الان
+
+458
+00:39:09,140 --> 00:39:13,060
+واحدة ممكن تقول انت قولتلنا انه لو كان كل واحدة
+
+459
+00:39:13,060 --> 00:39:17,480
+عكس التاني يعتبرهم enantiomersمظبوط ولا لا؟ احنا
+
+460
+00:39:17,480 --> 00:39:20,900
+الآن بنحط شرط، بنقول لو كل واحدة عكس التانية،
+
+461
+00:39:20,900 --> 00:39:25,540
+اعتبرهم English وMars بشرط، الا يكون الجزء متماثل
+
+462
+00:39:25,540 --> 00:39:31,380
+من نصه، يعني مايكونش نصه زي نص التاني، هذا الجزء
+
+463
+00:39:31,380 --> 00:39:36,080
+مابتنطبقش على القاعدة، لأن هذا النص محتوياته زي
+
+464
+00:39:36,080 --> 00:39:40,970
+هذا النص، واضح؟إذا القاعدة اللي قبل شوية كتبتها
+
+465
+00:39:40,970 --> 00:39:44,570
+إنه لو كل واحدة عكس التانية بعتبرهم enansimars
+
+466
+00:39:44,570 --> 00:39:50,570
+بشرط أن لا يكون الجزء متماثل طب إذا كان الجزء
+
+467
+00:39:50,570 --> 00:39:54,370
+متماثل شو بقول عنهم؟ the same compound حتى لو كل
+
+468
+00:39:54,370 --> 00:39:58,490
+واحدة عكس التانية واضح؟ في هذه الحالة هذا المركب
+
+469
+00:39:58,490 --> 00:40:03,870
+المتماثل داخليا بسميه mesostructure
+
+470
+00:40:05,280 --> 00:40:10,740
+الـ Mesostructure هو مركب متماثل داخليًا، عارفين
+
+471
+00:40:10,740 --> 00:40:15,520
+كيف صورة نص اللي فوق زي النص اللي تحت؟ بتعرفوا لما
+
+472
+00:40:15,520 --> 00:40:20,420
+بيلعبوا في الشدة؟ البعض منكم شايف الشدة؟ مشفير
+
+473
+00:40:20,420 --> 00:40:25,820
+رسومات فيها زي صورة بني آدم لفوق و بني آدم لتحت؟
+
+474
+00:40:25,820 --> 00:40:30,740
+هذا Mesostructure، ماعرفش شو بيسموهابتكون الصورة
+
+475
+00:40:30,740 --> 00:40:35,320
+معكوسة، زي بني أدم له راسين من فوق و من تحت، هذا
+
+476
+00:40:35,320 --> 00:40:41,520
+عبارة عن mesostructure، نصه اللي فوق زي النص اللي
+
+477
+00:40:41,520 --> 00:40:46,520
+تحت، اذا انا لما باجي بحدد لمركبات انهم، ايش
+
+478
+00:40:46,520 --> 00:40:50,140
+العلاقة بينهم، اول اشي دائما اسألوا نفسكم، هل يا
+
+479
+00:40:50,140 --> 00:40:55,040
+ترى الجزاء متماثل نصه زي نص التاني ولا لا؟ اذا نصه
+
+480
+00:40:55,040 --> 00:40:57,860
+زي نص التاني، معناه ذلك اللي بيكونوا عكس بعض
+
+481
+00:40:57,860 --> 00:41:01,160
+بيكونوا إيش؟the same compound و بيمثلوا ال
+
+482
+00:41:01,160 --> 00:41:05,400
+mesostructure إذا النص هذا مختلف عن نص هذا معناه
+
+483
+00:41:05,400 --> 00:41:09,960
+ذلك المتعاكسات بيكونوا enantiomals طبعا بقصد
+
+484
+00:41:09,960 --> 00:41:12,980
+بالمتعاكسات لما تكون هذه R و هذه نفسها و هذه نفسها
+
+485
+00:41:12,980 --> 00:41:17,240
+هنا هدوله متعاكسات بس طالما نفس الرمز هنا و نفسه
+
+486
+00:41:17,240 --> 00:41:22,360
+هنا هدوله they are enantiomals قولا واحد على أي
+
+487
+00:41:22,360 --> 00:41:27,560
+حال هذا الكلام راجعوهو حاولوا كتير أنكوا تطبقوا
+
+488
+00:41:27,560 --> 00:41:30,860
+بالورقة و القلم بتوقع الحصة اللي جاية تيجوا تسألوا
+
+489
+00:41:30,860 --> 00:41:42,120
+فيه و حلوا الأمثلة اللي موجودة عندكم طبعا
+
+490
+00:41:42,120 --> 00:41:48,360
+تنسوش اليوم مدعوين على المحاضرة اللي
+
+491
+00:41:48,360 --> 00:41:52,720
+بيجي أهلا وسهلا اللي مابيجيش أهلا وسهلا اللي بيجي
+
+492
+00:41:52,720 --> 00:41:54,080
+و بيعمل report عن المحاضرة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..8a4367549389a87642ebd51b0a640aaa68c1195b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/w3pji2INV54_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2830, "start": 7.22, "end": 28.3, "text": "اليوم ان شاء الله بنكمل في موضوع ال stereo chemistry طبعا اذا سألناكم كل الكلام اللي درسناه الحصة الماضية كان عبارة عن تعريف ال enantiomers يعني قولنا ان ال stereo isomers نوعين النوع الأول", "tokens": [6027, 1829, 20498, 16472, 13412, 16606, 21984, 44945, 24793, 1211, 8978, 3714, 2407, 11242, 45367, 2423, 29029, 12558, 23032, 3555, 3615, 995, 1975, 15730, 8608, 10721, 1211, 8315, 24793, 28242, 2423, 28820, 10943, 13672, 1829, 11778, 2288, 3794, 8315, 3224, 21542, 9381, 3660, 9673, 46958, 10632, 25961, 6225, 3555, 9640, 3660, 18871, 37279, 16572, 5172, 2423, 465, 11520, 298, 433, 37495, 22653, 12174, 12610, 8315, 16472, 2423, 29029, 307, 298, 433, 8717, 45367, 9957, 28239, 45367, 16247, 12610], "avg_logprob": -0.11422072954570191, "compression_ratio": 1.577319587628866, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 7.220000000000001, "end": 8.34, "word": "اليوم", "probability": 0.7823079427083334}, {"start": 8.34, "end": 8.5, "word": " ان", "probability": 0.66162109375}, {"start": 8.5, "end": 8.68, "word": " شاء", "probability": 0.98388671875}, {"start": 8.68, "end": 8.78, "word": " الله", "probability": 0.95654296875}, {"start": 8.78, "end": 9.78, "word": " بنكمل", "probability": 0.9352213541666666}, {"start": 9.78, "end": 9.96, "word": " في", "probability": 0.865234375}, {"start": 9.96, "end": 10.42, "word": " موضوع", "probability": 0.98876953125}, {"start": 10.42, "end": 10.56, "word": " ال", "probability": 0.93359375}, {"start": 10.56, "end": 10.9, "word": " stereo", "probability": 0.3701171875}, {"start": 10.9, "end": 11.54, "word": " chemistry", "probability": 0.48486328125}, {"start": 11.54, "end": 13.22, "word": " طبعا", "probability": 0.9901123046875}, {"start": 13.22, "end": 14.22, "word": " اذا", "probability": 0.7685546875}, {"start": 14.22, "end": 15.16, "word": " سألناكم", "probability": 0.94482421875}, {"start": 15.16, "end": 15.76, "word": " كل", "probability": 0.99072265625}, {"start": 15.76, "end": 16.24, "word": " الكلام", "probability": 0.94140625}, {"start": 16.24, "end": 16.4, "word": " اللي", "probability": 0.870849609375}, {"start": 16.4, "end": 17.86, "word": " درسناه", "probability": 0.9474609375}, {"start": 17.86, "end": 18.38, "word": " الحصة", "probability": 0.9742838541666666}, {"start": 18.38, "end": 19.02, "word": " الماضية", "probability": 0.9934895833333334}, {"start": 19.02, "end": 19.8, "word": " كان", "probability": 0.9736328125}, {"start": 19.8, "end": 20.28, "word": " عبارة", "probability": 0.989990234375}, {"start": 20.28, "end": 20.7, "word": " عن", "probability": 0.9970703125}, {"start": 20.7, "end": 21.96, "word": " تعريف", "probability": 0.9892578125}, {"start": 21.96, "end": 22.12, "word": " ال", "probability": 0.962890625}, {"start": 22.12, "end": 23.1, "word": " enantiomers", "probability": 0.80126953125}, {"start": 23.1, "end": 24.0, "word": " يعني", "probability": 0.913330078125}, {"start": 24.0, "end": 24.32, "word": " قولنا", "probability": 0.83447265625}, {"start": 24.32, "end": 24.46, "word": " ان", "probability": 0.70751953125}, {"start": 24.46, "end": 24.6, "word": " ال", "probability": 0.81787109375}, {"start": 24.6, "end": 24.98, "word": " stereo", "probability": 0.85888671875}, {"start": 24.98, "end": 25.92, "word": " isomers", "probability": 0.939453125}, {"start": 25.92, "end": 26.64, "word": " نوعين", "probability": 0.9122721354166666}, {"start": 26.64, "end": 27.7, "word": " النوع", "probability": 0.9140625}, {"start": 27.7, "end": 28.3, "word": " الأول", "probability": 0.89208984375}], "temperature": 1.0}, {"id": 2, "seek": 5362, "start": 29.18, "end": 53.62, "text": "إنانشو مارز والإنانشو مارز بيمتازوا إنهم جزيئات الواحد منهم صورة التاني في المرأة لكنها غير متطابقة هذا ملخص تقريبا لكل المحاضرة الماضية زدنا على ذلك إنه الإنانشو مارز كيف نقدر نميزهم عن بعض نعمل لهم configuration بنسميه بمعنى نقول إنه هذا R", "tokens": [28814, 1863, 7649, 8592, 2407, 3714, 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"text": "في الشكل بالفراغ هذا الشكل بيختلف عن هذا الشكل إذا هدول الصورتين كمرحلة أولى أقل إشي بقبلوا منكوا تقولوا ان they are stereoisomers", "tokens": [41185, 25124, 28820, 20666, 5172, 2288, 5718, 118, 23758, 25124, 28820, 4724, 1829, 46456, 46538, 18871, 23758, 25124, 28820, 11933, 15730, 8032, 3215, 12610, 31767, 13063, 2655, 9957, 9122, 29973, 5016, 37977, 5551, 12610, 7578, 5551, 4587, 1211, 11933, 8592, 1829, 4724, 4587, 36150, 14407, 9154, 4117, 14407, 6055, 39648, 14407, 16472, 436, 366, 12730, 7376, 298, 433], "avg_logprob": -0.19650423375226683, "compression_ratio": 1.472972972972973, "no_speech_prob": 0.0, "words": [{"start": 175.62, "end": 175.82, "word": "في", "probability": 0.80517578125}, {"start": 175.82, "end": 176.2, "word": " الشكل", "probability": 0.920166015625}, {"start": 176.2, "end": 176.92, "word": " بالفراغ", "probability": 0.8626953125}, {"start": 176.92, "end": 177.38, "word": " هذا", "probability": 0.53271484375}, {"start": 177.38, "end": 177.92, "word": " 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254.67, "text": "Non Mirror Image Stereoisomers الان لو بدى امثلة تطبيقية من الحياة حتى نفهم الظاهرة قبل ما ننتقل على ايش على الذرات والجزيئات والكيم يوما الى ذلك لو يا ترى امسكت نضارة هادي بهذا الشكل هينمسكها هذه النضارة انا جبت مفكات وفكتها وغيرت فيها ال bonding", "tokens": [47914, 34452, 29903, 745, 323, 7376, 298, 433, 2423, 7649, 45164, 47525, 7578, 1975, 2304, 12984, 37977, 6055, 9566, 21292, 4587, 10632, 9154, 21542, 25528, 3660, 11331, 49975, 8717, 5172, 16095, 6024, 116, 40294, 25720, 12174, 36150, 19446, 8717, 29399, 4587, 1211, 15844, 1975, 1829, 8592, 15844, 32545, 2288, 9307, 16070, 7435, 11622, 1829, 19986, 9307, 16070, 4117, 32640, 7251, 20498, 995, 2423, 7578, 29910, 23275, 45164, 35186, 6055, 2288, 7578, 1975, 2304, 3794, 4117, 2655, 8717, 11242, 9640, 3660, 8032, 995, 16254, 39627, 15730, 25124, 28820, 8032, 9957, 2304, 3794, 4117, 11296, 29538, 28239, 11242, 9640, 3660, 1975, 8315, 10874, 3555, 2655, 3714, 5172, 4117, 9307, 4032, 5172, 4117, 2655, 11296, 4032, 17082, 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مفتوحة و صورة النضارة و هي مسكرة ما العلاقة بين هدول الشكلين؟", "tokens": [1211, 9640, 2655, 3555, 41193, 22807, 23032, 1829, 3555, 45164, 5551, 9778, 3215, 2655, 20328, 13063, 3660, 28239, 11242, 9640, 3660, 4032, 39896, 3714, 5172, 2655, 2407, 5016, 3660, 4032, 20328, 13063, 3660, 28239, 11242, 9640, 3660, 4032, 39896, 47524, 4117, 25720, 19446, 18863, 15040, 28671, 49374, 8032, 3215, 12610, 25124, 4117, 1211, 9957, 22807], "avg_logprob": -0.12458147880222116, "compression_ratio": 1.6017699115044248, "no_speech_prob": 1.1324882507324219e-06, "words": [{"start": 255.59, "end": 256.63, "word": "لارتباط؟", "probability": 0.7728271484375}, {"start": 256.63, "end": 257.33, "word": " طيب", "probability": 0.9510091145833334}, {"start": 257.33, "end": 257.49, "word": " لو", "probability": 0.62939453125}, {"start": 257.49, "end": 257.93, "word": " أخدت", "probability": 0.9700927734375}, {"start": 257.93, "end": 258.27, "word": " صورة", "probability": 0.9982096354166666}, {"start": 258.27, 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{"start": 364.54, "end": 365.66, "word": " متعاكسات", "probability": 0.9691569010416666}, {"start": 365.66, "end": 366.22, "word": " هذا", "probability": 0.63037109375}, {"start": 366.22, "end": 366.44, "word": " كنا", "probability": 0.973876953125}, {"start": 366.44, "end": 366.68, "word": " إيش", "probability": 0.8772786458333334}, {"start": 366.68, "end": 367.7, "word": " نسميه؟", "probability": 0.803271484375}, {"start": 367.7, "end": 368.36, "word": " cis", "probability": 0.09796142578125}, {"start": 368.36, "end": 370.62, "word": "-dichloroethane", "probability": 0.8397042410714286}, {"start": 370.62, "end": 371.44, "word": " وهذا", "probability": 0.6951904296875}, {"start": 371.44, "end": 372.74, "word": " trans", "probability": 0.8759765625}, {"start": 372.74, "end": 374.38, "word": "-dichloroethane", "probability": 0.9435686383928571}, {"start": 374.38, "end": 374.9, "word": " الآن", "probability": 0.6492919921875}, {"start": 374.9, "end": 375.08, "word": " لو", "probability": 0.97900390625}, {"start": 375.08, "end": 375.7, "word": " اطلعتوا", "probability": 0.7470703125}, {"start": 375.7, "end": 375.88, "word": " على", "probability": 0.90185546875}, {"start": 375.88, "end": 376.38, "word": " هدولة", "probability": 0.8363037109375}, {"start": 376.38, "end": 377.32, "word": " المركبين", "probability": 0.862548828125}, {"start": 377.32, "end": 377.9, "word": " ال", "probability": 0.81787109375}, {"start": 377.9, "end": 378.22, "word": " cis", "probability": 0.76220703125}, {"start": 378.22, "end": 379.52, "word": " والترانس،", "probability": 0.6649576822916666}, {"start": 379.52, "end": 379.78, "word": " اللهم", "probability": 0.70263671875}, {"start": 379.78, "end": 380.08, "word": " نفس", "probability": 0.99609375}, {"start": 380.08, "end": 380.2, "word": " ال", "probability": 0.84521484375}, {"start": 380.2, "end": 380.52, "word": " molecular", "probability": 0.91748046875}, {"start": 380.52, "end": 382.06, "word": " weight؟", "probability": 0.8486328125}, {"start": 382.06, "end": 383.64, "word": " اللهم", "probability": 0.9521484375}, {"start": 383.64, "end": 384.28, "word": " نفس", "probability": 0.992919921875}, {"start": 384.28, "end": 384.92, "word": " مواقع", "probability": 0.986328125}, {"start": 384.92, "end": 385.7, "word": " الارتباط،", "probability": 0.8246663411458334}, {"start": 385.7, "end": 385.88, "word": " إيش", "probability": 0.9178059895833334}, {"start": 385.88, "end": 386.24, "word": " بقصود", "probability": 0.9063720703125}, {"start": 386.24, "end": 386.42, "word": " أنا", "probability": 0.884765625}, {"start": 386.42, "end": 386.7, "word": " بنفس", "probability": 0.6806640625}, {"start": 386.7, "end": 387.04, "word": " مواقع", "probability": 0.972412109375}, {"start": 387.04, "end": 387.78, "word": " الارتباط؟", "probability": 0.9635416666666666}, {"start": 387.78, "end": 387.98, "word": " لو", "probability": 0.93603515625}, {"start": 387.98, "end": 388.32, "word": " قلت", "probability": 0.787353515625}, {"start": 388.32, "end": 388.52, "word": " هذه", "probability": 0.5361328125}, {"start": 388.52, "end": 388.7, "word": " ال", "probability": 0.658203125}, {"start": 388.7, "end": 389.06, "word": " carbon", "probability": 0.78564453125}, {"start": 389.06, "end": 389.54, "word": " الأولى", "probability": 0.9765625}, {"start": 389.54, "end": 390.12, "word": " متصلة", "probability": 0.8649088541666666}, {"start": 390.12, "end": 390.82, "word": " بماذا؟", "probability": 0.98515625}], "temperature": 1.0}, {"id": 18, "seek": 41790, "start": 391.26, "end": 417.9, "text": "أكلورو هيدروجين وهذه الكاربون التانية أكلورو هيدروجين طب لو هنا بدأتش أطلع الكاربون الأولى أكلورو هيدروجين الكاربون التانية أكلورو هيدروجين أين الاختلاف بشكل الفراغي لكن مواقع الارتباط نفسها أنه هنا التنتين الكلور على جهة واحدة وفي الجزء التاني التنتين الكلور على جهتين", "tokens": [10721, 4117, 1211, 13063, 2407, 8032, 25708, 2288, 29245, 9957, 37037, 24192, 33251, 9640, 3555, 11536, 16712, 7649, 10632, 5551, 4117, 1211, 13063, 2407, 8032, 25708, 2288, 29245, 9957, 23032, 3555, 45164, 34105, 47525, 10721, 2655, 8592, 5551, 9566, 1211, 3615, 33251, 9640, 3555, 11536, 16247, 12610, 7578, 5551, 4117, 1211, 13063, 2407, 8032, 25708, 2288, 29245, 9957, 33251, 9640, 3555, 11536, 16712, 7649, 10632, 5551, 4117, 1211, 13063, 2407, 8032, 25708, 2288, 29245, 9957, 5551, 9957, 2423, 47283, 2655, 15040, 5172, 4724, 8592, 28820, 27188, 2288, 5718, 118, 1829, 44381, 3714, 14407, 4587, 3615, 2423, 9640, 2655, 3555, 41193, 8717, 36178, 11296, 14739, 3224, 34105, 16712, 29399, 9957, 33251, 1211, 13063, 15844, 10874, 3224, 3660, 36764, 24401, 3660, 4032, 41185, 25724, 11622, 38207, 16712, 7649, 1829, 16712, 29399, 9957, 33251, 1211, 13063, 15844, 10874, 3224, 2655, 9957], "avg_logprob": -0.18918614850627433, "compression_ratio": 2.5487179487179485, "no_speech_prob": 4.351139068603516e-06, "words": [{"start": 391.26, "end": 391.92, "word": "أكلورو", "probability": 0.501025390625}, {"start": 391.92, "end": 392.54, "word": " هيدروجين", "probability": 0.85517578125}, {"start": 392.54, "end": 392.9, "word": " وهذه", "probability": 0.436279296875}, {"start": 392.9, "end": 393.42, "word": " الكاربون", "probability": 0.7547607421875}, {"start": 393.42, "end": 393.98, "word": " التانية", "probability": 0.8258463541666666}, {"start": 393.98, "end": 395.0, "word": " أكلورو", "probability": 0.79619140625}, {"start": 395.0, "end": 395.62, "word": " هيدروجين", "probability": 0.94482421875}, {"start": 395.62, "end": 395.82, "word": " طب", "probability": 0.75390625}, {"start": 395.82, "end": 395.96, "word": " لو", "probability": 0.97021484375}, {"start": 395.96, "end": 396.16, "word": " هنا", "probability": 0.50537109375}, {"start": 396.16, "end": 396.54, "word": " بدأتش", "probability": 0.6026611328125}, {"start": 396.54, "end": 396.92, "word": " أطلع", "probability": 0.76031494140625}, {"start": 396.92, "end": 397.46, "word": " الكاربون", "probability": 0.96044921875}, {"start": 397.46, "end": 398.08, "word": " الأولى", "probability": 0.958984375}, {"start": 398.08, "end": 399.04, "word": " أكلورو", "probability": 0.84833984375}, {"start": 399.04, "end": 399.62, "word": " هيدروجين", "probability": 0.96806640625}, {"start": 399.62, "end": 400.16, "word": " الكاربون", "probability": 0.9447021484375}, {"start": 400.16, "end": 400.66, "word": " التانية", "probability": 0.9391276041666666}, {"start": 400.66, "end": 401.6, "word": " أكلورو", "probability": 0.9478515625}, {"start": 401.6, "end": 402.16, "word": " هيدروجين", "probability": 0.97470703125}, {"start": 402.16, "end": 402.48, "word": " أين", "probability": 0.823486328125}, {"start": 402.48, "end": 403.36, "word": " الاختلاف", "probability": 0.89541015625}, {"start": 403.36, "end": 404.74, "word": " بشكل", "probability": 0.8221842447916666}, {"start": 404.74, "end": 405.56, "word": " الفراغي", "probability": 0.90791015625}, {"start": 405.56, "end": 406.64, "word": " لكن", "probability": 0.84375}, {"start": 406.64, "end": 407.16, "word": " مواقع", "probability": 0.983154296875}, {"start": 407.16, "end": 407.74, "word": " الارتباط", "probability": 0.92158203125}, {"start": 407.74, "end": 408.48, "word": " نفسها", "probability": 0.9650065104166666}, {"start": 408.48, "end": 408.86, "word": " أنه", "probability": 0.497314453125}, {"start": 408.86, "end": 409.18, "word": " هنا", "probability": 0.75634765625}, {"start": 409.18, "end": 409.74, "word": " التنتين", "probability": 0.8045247395833334}, {"start": 409.74, "end": 410.22, "word": " الكلور", "probability": 0.7915852864583334}, {"start": 410.22, "end": 410.44, "word": " على", "probability": 0.91064453125}, {"start": 410.44, "end": 410.86, "word": " جهة", "probability": 0.98583984375}, {"start": 410.86, "end": 411.56, "word": " واحدة", "probability": 0.9899088541666666}, {"start": 411.56, "end": 412.12, "word": " وفي", "probability": 0.810546875}, {"start": 412.12, "end": 413.4, "word": " الجزء", "probability": 0.9093424479166666}, {"start": 413.4, "end": 414.08, "word": " التاني", "probability": 0.8821614583333334}, {"start": 414.08, "end": 415.0, "word": " التنتين", "probability": 0.9523111979166666}, {"start": 415.0, "end": 415.72, "word": " الكلور", "probability": 0.9627278645833334}, {"start": 415.72, "end": 417.1, "word": " على", "probability": 0.93798828125}, {"start": 417.1, "end": 417.9, "word": " جهتين", "probability": 0.9805908203125}], "temperature": 1.0}, {"id": 19, "seek": 44720, "start": 418.98, "end": 447.2, "text": "متعاكستين إذا هل هدول المركبين يا ترى صورة بعض في المرأة ولا لأ إذا هدول ال cis trans isomers they are non mirror image stereoisomers they are diastereomers واضح فالcis والtrans isomers they are diastereomers شفتوا انتوا غيرة الcis والtrans isomers في مكانين حوالين ال double bond", "tokens": [2304, 2655, 3615, 995, 4117, 3794, 2655, 9957, 11933, 15730, 8032, 1211, 8032, 3215, 12610, 9673, 31747, 3555, 9957, 35186, 6055, 2288, 7578, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 10721, 3660, 49429, 5296, 10721, 11933, 15730, 8032, 3215, 12610, 2423, 37847, 1145, 307, 298, 433, 436, 366, 2107, 8013, 3256, 12730, 7376, 298, 433, 436, 366, 1026, 525, 323, 298, 433, 4032, 46958, 5016, 6156, 6027, 26720, 16070, 24999, 307, 298, 433, 436, 366, 1026, 525, 323, 298, 433, 13412, 5172, 2655, 14407, 16472, 2655, 14407, 32771, 13546, 3660, 2423, 26720, 16070, 24999, 307, 298, 433, 8978, 3714, 41361, 9957, 11331, 2407, 6027, 9957, 2423, 3834, 6086], "avg_logprob": -0.2832386241717772, "compression_ratio": 1.8246445497630333, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 418.97999999999996, "end": 420.02, "word": "متعاكستين", "probability": 0.768280029296875}, {"start": 420.02, "end": 420.64, "word": " إذا", "probability": 0.51239013671875}, {"start": 420.64, "end": 421.24, "word": " هل", "probability": 0.939697265625}, {"start": 421.24, "end": 421.62, "word": " هدول", "probability": 0.83447265625}, {"start": 421.62, "end": 422.54, "word": " المركبين", "probability": 0.7733154296875}, {"start": 422.54, "end": 422.7, "word": " يا", "probability": 0.354248046875}, {"start": 422.7, "end": 423.18, "word": " ترى", "probability": 0.7306315104166666}, {"start": 423.18, "end": 423.9, "word": " صورة", "probability": 0.9659830729166666}, {"start": 423.9, "end": 424.26, "word": " بعض", "probability": 0.9501953125}, {"start": 424.26, "end": 424.44, "word": " في", "probability": 0.9296875}, {"start": 424.44, "end": 424.98, "word": " المرأة", "probability": 0.8302001953125}, {"start": 424.98, "end": 425.2, "word": " ولا", "probability": 0.75048828125}, {"start": 425.2, "end": 425.64, "word": " لأ", "probability": 0.9052734375}, {"start": 425.64, "end": 427.4, "word": " إذا", "probability": 0.620849609375}, {"start": 427.4, "end": 427.9, "word": " هدول", "probability": 0.9755859375}, {"start": 427.9, "end": 428.12, "word": " ال", "probability": 0.79638671875}, {"start": 428.12, "end": 428.28, "word": " cis", "probability": 0.156982421875}, {"start": 428.28, "end": 428.82, "word": " trans", "probability": 0.1756591796875}, {"start": 428.82, "end": 429.74, "word": " isomers", "probability": 0.9427083333333334}, {"start": 429.74, "end": 430.24, "word": " they", "probability": 0.249755859375}, {"start": 430.24, "end": 430.68, "word": " are", "probability": 0.95361328125}, {"start": 430.68, "end": 431.24, "word": " non", "probability": 0.92529296875}, {"start": 431.24, "end": 431.6, "word": " mirror", "probability": 0.7158203125}, {"start": 431.6, "end": 432.08, "word": " image", "probability": 0.83837890625}, {"start": 432.08, "end": 433.16, "word": " stereoisomers", "probability": 0.8682861328125}, {"start": 433.16, "end": 433.38, "word": " they", "probability": 0.49853515625}, {"start": 433.38, "end": 433.58, "word": " are", "probability": 0.96044921875}, {"start": 433.58, "end": 434.48, "word": " diastereomers", "probability": 0.866796875}, {"start": 434.48, "end": 435.3, "word": " واضح", "probability": 0.9103190104166666}, {"start": 435.3, "end": 436.54, "word": " فالcis", "probability": 0.6761067708333334}, {"start": 436.54, "end": 437.26, "word": " والtrans", "probability": 0.3226318359375}, {"start": 437.26, "end": 438.36, "word": " isomers", "probability": 0.9490559895833334}, {"start": 438.36, "end": 438.86, "word": " they", "probability": 0.89697265625}, {"start": 438.86, "end": 439.42, "word": " are", "probability": 0.96044921875}, {"start": 439.42, "end": 441.12, "word": " diastereomers", "probability": 0.9154296875}, {"start": 441.12, "end": 441.8, "word": " شفتوا", "probability": 0.739501953125}, {"start": 441.8, "end": 442.06, "word": " انتوا", "probability": 0.7045084635416666}, {"start": 442.06, "end": 442.46, "word": " غيرة", "probability": 0.6324869791666666}, {"start": 442.46, "end": 442.76, "word": " الcis", "probability": 0.85546875}, {"start": 442.76, "end": 443.34, "word": " والtrans", "probability": 0.748779296875}, {"start": 443.34, "end": 444.08, "word": " isomers", "probability": 0.9697265625}, {"start": 444.08, "end": 444.24, "word": " في", "probability": 0.95068359375}, {"start": 444.24, "end": 444.92, "word": " مكانين", "probability": 0.9856770833333334}, {"start": 444.92, "end": 446.34, "word": " حوالين", "probability": 0.8665771484375}, {"start": 446.34, "end": 446.48, "word": " ال", "probability": 0.6328125}, {"start": 446.48, "end": 446.68, "word": " double", "probability": 0.8896484375}, {"start": 446.68, "end": 447.2, "word": " bond", "probability": 0.86474609375}], "temperature": 1.0}, {"id": 20, "seek": 47248, "start": 448.32, "end": 472.48, "text": "و في الأشكال الحلقية طلعوا معي لما كان مثلا نكون عندنا cyclopentene cyclopentene عادي مش pentene cyclopentene نحط مثلا ال chlorine لفوق و ال chlorine التالية لفوق و هاي hydrogens هذا أيه المركب؟ هذا ال cis compound الآن لو حطينا chlorine لفوق و chlorine لتحت مثلا", "tokens": [2407, 8978, 16247, 8592, 4117, 6027, 21542, 1211, 4587, 10632, 23032, 1211, 3615, 14407, 20449, 1829, 5296, 15042, 25961, 50113, 15040, 8717, 30544, 43242, 8315, 19474, 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نقول إنه كمثال كمثال على الدياستيريو مارز ال CC trans isomers سواء كانوا CC trans isomers حوالين ال double bond أو كانوا CC trans isomers حوالين حلقة يعني فوق و تحت مستوى الحلقة هذا أحد الأنواع الآن بيجينا نوع تالي بيجينا نوع تالي من ال CC trans من الدياستيريو مارز عفوا", "tokens": [3555, 1863, 28543, 2288, 8717, 39648, 36145, 3224, 9122, 2304, 12984, 6027, 9122, 2304, 12984, 6027, 15844, 2423, 16254, 995, 14851, 13546, 1829, 2407, 3714, 9640, 11622, 2423, 12630, 1145, 307, 298, 433, 8608, 2407, 16606, 25961, 14407, 12630, 1145, 307, 298, 433, 11331, 2407, 6027, 9957, 2423, 3834, 6086, 34051, 25961, 14407, 12630, 1145, 307, 298, 433, 11331, 2407, 6027, 9957, 11331, 1211, 28671, 37495, 22653, 6156, 30543, 4032, 6055, 33753, 3714, 14851, 2407, 7578, 21542, 1211, 28671, 23758, 5551, 24401, 16247, 1863, 14407, 3615, 6024, 48506, 4724, 1829, 7435, 1829, 8315, 8717, 45367, 6055, 6027, 1829, 4724, 1829, 7435, 1829, 8315, 8717, 45367, 6055, 6027, 1829, 9154, 2423, 12630, 1145, 9154, 2423, 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0.9807942708333334}, {"start": 507.4, "end": 507.92, "word": " هذا", "probability": 0.84814453125}, {"start": 507.92, "end": 508.24, "word": " أحد", "probability": 0.933837890625}, {"start": 508.24, "end": 508.92, "word": " الأنواع", "probability": 0.9854736328125}, {"start": 508.92, "end": 509.82, "word": " الآن", "probability": 0.7208251953125}, {"start": 509.82, "end": 510.5, "word": " بيجينا", "probability": 0.98017578125}, {"start": 510.5, "end": 510.96, "word": " نوع", "probability": 0.994873046875}, {"start": 510.96, "end": 511.84, "word": " تالي", "probability": 0.9724934895833334}, {"start": 511.84, "end": 512.68, "word": " بيجينا", "probability": 0.90712890625}, {"start": 512.68, "end": 512.88, "word": " نوع", "probability": 0.99755859375}, {"start": 512.88, "end": 513.46, "word": " تالي", "probability": 0.9837239583333334}, {"start": 513.46, "end": 513.86, "word": " من", "probability": 0.9853515625}, {"start": 513.86, "end": 514.02, "word": " ال", "probability": 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اقصى ما يمكن يكون عندى مركبات اتنين اقص تلاتة مش تلاتة اقص اتنين تمانية اتنين اقص تلاتة تمانية اتنين في اتنين في اتنين", "tokens": [2407, 46958, 5016, 24976, 28820, 10943, 22807, 1975, 15730, 1975, 8315, 6225, 8592, 7649, 1975, 3615, 28480, 18863, 3215, 3215, 20666, 19913, 3555, 9566, 4724, 16254, 13412, 2407, 10632, 13412, 17082, 1211, 4724, 16254, 1975, 2288, 38251, 4724, 16254, 1975, 2655, 3615, 19528, 1975, 8592, 1829, 16606, 1975, 11242, 31845, 10632, 2423, 7649, 45164, 1975, 5172, 2655, 43042, 2655, 50113, 15040, 16472, 3224, 18871, 16254, 6055, 1211, 9307, 3660, 23782, 304, 10898, 3714, 29245, 23328, 9957, 8978, 10874, 11622, 16373, 1829, 10874, 3215, 33599, 1975, 4587, 9381, 7578, 19446, 7251, 43020, 7251, 30544, 43242, 7578, 3714, 31747, 3555, 9307, 1975, 2655, 1863, 9957, 1975, 4587, 9381, 6055, 1211, 9307, 3660, 37893, 6055, 1211, 9307, 3660, 1975, 4587, 9381, 1975, 2655, 1863, 9957, 46811, 7649, 10632, 1975, 2655, 1863, 9957, 1975, 4587, 9381, 6055, 1211, 9307, 3660, 46811, 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نصعب", "probability": 0.9088134765625}, {"start": 644.74, "end": 644.88, "word": " على", "probability": 0.79736328125}, {"start": 644.88, "end": 645.36, "word": " حالنا", "probability": 0.98095703125}, {"start": 645.36, "end": 646.34, "word": " الأمور", "probability": 0.9431966145833334}, {"start": 646.34, "end": 647.28, "word": " ناخد", "probability": 0.9454752604166666}, {"start": 647.28, "end": 647.82, "word": " مثلا", "probability": 0.861328125}, {"start": 647.82, "end": 649.0, "word": " مركب", "probability": 0.7063802083333334}, {"start": 649.0, "end": 649.58, "word": " زي", "probability": 0.939453125}, {"start": 649.58, "end": 649.86, "word": " هذا", "probability": 0.93994140625}, {"start": 649.86, "end": 650.06, "word": " لو", "probability": 0.4345703125}, {"start": 650.06, "end": 650.72, "word": " تخيلنا", "probability": 0.87255859375}, {"start": 650.72, "end": 650.84, "word": " أننا", "probability": 0.349609375}, {"start": 650.84, "end": 651.06, "word": " لدينا", 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"end": 663.15, "word": " تقولوا", "probability": 0.9685872395833334}, {"start": 663.15, "end": 663.37, "word": " انه", "probability": 0.7314453125}, {"start": 663.37, "end": 663.53, "word": " ايش", "probability": 0.7843424479166666}, {"start": 663.53, "end": 663.85, "word": " اسم", "probability": 0.954833984375}, {"start": 663.85, "end": 664.13, "word": " هذا", "probability": 0.955078125}, {"start": 664.13, "end": 664.91, "word": " المركب", "probability": 0.8976236979166666}, {"start": 664.91, "end": 665.91, "word": " two", "probability": 0.396240234375}, {"start": 665.91, "end": 666.45, "word": " three", "probability": 0.64453125}, {"start": 666.45, "end": 670.09, "word": " dichlorobentane", "probability": 0.8140625}, {"start": 670.09, "end": 670.67, "word": " زي", "probability": 0.883056640625}, {"start": 670.67, "end": 670.85, "word": " اللي", "probability": 0.59814453125}, {"start": 670.85, "end": 670.99, "word": " كنا", "probability": 0.976806640625}, {"start": 670.99, "end": 671.73, "word": " نرسملكوا", "probability": 0.78349609375}, {"start": 671.73, "end": 672.55, "word": " كاربون،", "probability": 0.66064453125}, {"start": 672.55, "end": 673.31, "word": " تنتين،", "probability": 0.915771484375}, {"start": 673.31, "end": 673.89, "word": " تلاتة،", "probability": 0.92734375}, {"start": 673.89, "end": 674.43, "word": " اربعة،", "probability": 0.86474609375}, {"start": 674.43, "end": 675.05, "word": " خمسة", "probability": 0.96240234375}, {"start": 675.05, "end": 675.37, "word": " و", "probability": 0.353515625}, {"start": 675.37, "end": 675.91, "word": " ببساطة", "probability": 0.863623046875}, {"start": 675.91, "end": 676.21, "word": " نحط", "probability": 0.8961588541666666}, {"start": 676.21, "end": 676.67, "word": " كلور", "probability": 0.6534423828125}, {"start": 676.67, "end": 676.79, "word": " و", "probability": 0.99267578125}, {"start": 676.79, "end": 677.27, "word": " كلور", "probability": 0.869384765625}, {"start": 677.27, "end": 677.63, "word": " و", "probability": 0.95654296875}, {"start": 677.63, "end": 677.87, "word": " نام", "probability": 0.819580078125}, {"start": 677.87, "end": 678.01, "word": " the", "probability": 0.2391357421875}, {"start": 678.01, "end": 678.61, "word": " following", "probability": 0.88623046875}, {"start": 678.61, "end": 679.83, "word": " compound", "probability": 0.962890625}, {"start": 679.83, "end": 680.47, "word": " ايش", "probability": 0.80908203125}, {"start": 680.47, "end": 681.29, "word": " تسموه؟", "probability": 0.960546875}], "temperature": 1.0}, {"id": 30, "seek": 69784, "start": 681.92, "end": 697.84, "text": "2,3-dichlorobentane واضح؟ اللي هتتفاجأو فيه الآن انه انتوا لو روحتوا على المخزن تشتريوا 2,3-dichlorobentane هيقولكوا مافيش عندي 2,3-dichlorobentane هيك لوحده", "tokens": [17, 11, 18, 12, 67, 480, 6746, 996, 317, 1929, 4032, 46958, 5016, 22807, 13672, 1829, 8032, 2655, 2655, 5172, 26108, 10721, 2407, 8978, 3224, 6024, 48506, 16472, 3224, 16472, 2655, 14407, 45164, 12602, 2407, 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{"id": 53, "seek": 128556, "start": 1260.98, "end": 1285.56, "text": "الـ configuration حتى لو عندي one chiral center حتى لو عندي one chiral center ممكن أرسمه إلكم بحيث لما تطلعوا أكون رسمه بطرق مختلفة ما تقدروش تقولولي ما العلاقة بين جزيين خلينا ناخد مثال لو تخيلنا إنه في عندنا هذا المركب حطينا chlorine و H و Br", "tokens": [6027, 39184, 11694, 11331, 49975, 45164, 18871, 16254, 472, 23782, 304, 3056, 11331, 49975, 45164, 18871, 16254, 472, 23782, 304, 3056, 3714, 43020, 5551, 2288, 38251, 3224, 11933, 23275, 2304, 4724, 5016, 1829, 12984, 5296, 15042, 6055, 9566, 1211, 3615, 14407, 5551, 30544, 12602, 38251, 3224, 4724, 9566, 2288, 4587, 3714, 46456, 46538, 3660, 19446, 6055, 28543, 2288, 2407, 8592, 6055, 39648, 12610, 1829, 19446, 18863, 15040, 28671, 49374, 10874, 11622, 1829, 9957, 16490, 1211, 9957, 995, 8717, 47283, 3215, 50113, 6027, 45164, 6055, 9778, 26895, 8315, 36145, 3224, 8978, 43242, 8315, 23758, 9673, 31747, 3555, 11331, 9566, 1829, 8315, 39888, 4032, 389, 4032, 1603], 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1285.56, "word": " Br", "probability": 0.33203125}], "temperature": 1.0}, {"id": 54, "seek": 130093, "start": 1296.37, "end": 1300.93, "text": "الان اللي مركزنا انك تشوف الأمور في المرايا", "tokens": [6027, 7649, 13672, 1829, 3714, 31747, 11622, 8315, 16472, 4117, 6055, 8592, 38688, 16247, 2304, 13063, 8978, 9673, 23557, 25528], "avg_logprob": -0.43303571996234713, "compression_ratio": 1.144927536231884, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 1296.3700000000001, "end": 1297.47, "word": "الان", "probability": 0.5062255859375}, {"start": 1297.47, "end": 1297.79, "word": " اللي", "probability": 0.41729736328125}, {"start": 1297.79, "end": 1298.39, "word": " مركزنا", "probability": 0.70819091796875}, {"start": 1298.39, "end": 1299.13, "word": " انك", "probability": 0.404541015625}, {"start": 1299.13, "end": 1299.57, "word": " تشوف", "probability": 0.8141276041666666}, {"start": 1299.57, "end": 1300.07, "word": " الأمور", "probability": 0.87744140625}, {"start": 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{"start": 1323.42, "end": 1323.7, "word": " حملة", "probability": 0.9656575520833334}, {"start": 1323.7, "end": 1324.36, "word": " bromochlor", "probability": 0.90625}, {"start": 1324.36, "end": 1324.48, "word": " و", "probability": 0.99267578125}, {"start": 1324.48, "end": 1324.58, "word": " ال", "probability": 0.7763671875}, {"start": 1324.58, "end": 1324.84, "word": " carbon", "probability": 0.8349609375}, {"start": 1324.84, "end": 1325.22, "word": " التانية", "probability": 0.9720052083333334}, {"start": 1325.22, "end": 1325.54, "word": " مثل", "probability": 0.9677734375}, {"start": 1325.54, "end": 1326.08, "word": " إذا", "probability": 0.818603515625}, {"start": 1326.08, "end": 1326.56, "word": " كل", "probability": 0.916015625}, {"start": 1326.56, "end": 1326.86, "word": " واحد", "probability": 0.99365234375}, {"start": 1326.86, "end": 1327.06, "word": " من", "probability": 0.984375}, {"start": 1327.06, "end": 1327.42, "word": " هدول", "probability": 0.8421223958333334}, 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اتنين", "probability": 0.87060546875}, {"start": 1816.13, "end": 1816.33, "word": " هى", "probability": 0.9638671875}, {"start": 1816.33, "end": 1816.71, "word": " تلاتة", "probability": 0.7545166015625}, {"start": 1816.71, "end": 1817.21, "word": " اربعاية", "probability": 0.609814453125}, {"start": 1817.21, "end": 1817.51, "word": " خمسة", "probability": 0.7943115234375}, {"start": 1817.51, "end": 1817.59, "word": " هى", "probability": 0.848876953125}, {"start": 1817.59, "end": 1817.97, "word": " ستة", "probability": 0.9697265625}, {"start": 1817.97, "end": 1818.39, "word": " لما", "probability": 0.8642578125}, {"start": 1818.39, "end": 1818.63, "word": " بقى", "probability": 0.7926432291666666}, {"start": 1818.63, "end": 1819.05, "word": " قدام", "probability": 0.8636067708333334}, {"start": 1819.05, "end": 1819.61, "word": " المرايا", "probability": 0.8484700520833334}, {"start": 1819.61, "end": 1820.09, "word": " كل", "probability": 0.9560546875}, {"start": 1820.09, "end": 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منهم اختلت", "tokens": [40228, 22653, 45164, 25961, 43242, 4117, 14407, 6225, 8592, 25720, 23782, 304, 10898, 3714, 31747, 3555, 8978, 3224, 6225, 8592, 25720, 23782, 304, 10898, 16070, 2655, 7649, 1829, 8978, 3224, 6225, 8592, 25720, 23782, 304, 10898, 4032, 38149, 11933, 1829, 8592, 4724, 1829, 30544, 14407, 465, 11520, 298, 433, 22807, 5296, 15042, 28242, 8717, 47432, 3660, 6225, 4117, 3794, 16712, 7649, 10632, 12399, 11933, 15730, 36764, 24401, 3660, 9154, 16095, 1975, 46456, 1211, 2655], "avg_logprob": -0.23166666825612386, "compression_ratio": 1.6604938271604939, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 1825.54, "end": 1825.88, "word": "يعني", "probability": 0.884033203125}, {"start": 1825.88, "end": 1826.0, "word": " لو", "probability": 0.712890625}, {"start": 1826.0, "end": 1826.2, "word": " كان", "probability": 0.9853515625}, {"start": 1826.2, "end": 1826.56, "word": " عندكوا", "probability": 0.7596028645833334}, {"start": 1826.56, "end": 1827.0, "word": " 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"seek": 245878, "start": 2429.8, "end": 2458.78, "text": "بتكون الصورة معكوسة، زي بني أدم له راسين من فوق و من تحت، هذا عبارة عن mesostructure، نصه اللي فوق زي النص اللي تحت، اذا انا لما باجي بحدد لمركبات انهم، ايش العلاقة بينهم، اول اشي دائما اسألوا نفسكم، هل يا ترى الجزاء متماثل نصه زي نص التاني ولا لا؟ اذا نصه زي نص التاني، معناه ذلك اللي بيكونوا عكس بعض بيكونوا إيش؟", "tokens": [3555, 2655, 30544, 31767, 13063, 3660, 20449, 4117, 41779, 3660, 12399, 30767, 1829, 4724, 22653, 5551, 40448, 46740, 12602, 32277, 9957, 9154, 6156, 30543, 4032, 9154, 6055, 33753, 12399, 23758, 6225, 3555, 9640, 3660, 18871, 3813, 555, 2885, 12399, 8717, 9381, 3224, 13672, 1829, 6156, 30543, 30767, 1829, 28239, 9381, 13672, 1829, 6055, 33753, 12399, 1975, 15730, 1975, 8315, 5296, 15042, 4724, 26108, 1829, 4724, 24401, 3215, 32767, 31747, 3555, 9307, 16472, 16095, 12399, 1975, 1829, 8592, 18863, 15040, 28671, 49374, 16095, 12399, 1975, 12610, 1975, 8592, 1829, 11778, 16373, 15042, 24525, 10721, 1211, 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"word": " لمركبات", "probability": 0.802490234375}, {"start": 2445.54, "end": 2446.34, "word": " انهم،", "probability": 0.8248697916666666}, {"start": 2446.34, "end": 2446.52, "word": " ايش", "probability": 0.8572591145833334}, {"start": 2446.52, "end": 2447.06, "word": " العلاقة", "probability": 0.9654947916666666}, {"start": 2447.06, "end": 2447.78, "word": " بينهم،", "probability": 0.8995768229166666}, {"start": 2447.78, "end": 2448.14, "word": " اول", "probability": 0.92333984375}, {"start": 2448.14, "end": 2448.44, "word": " اشي", "probability": 0.8777669270833334}, {"start": 2448.44, "end": 2448.8, "word": " دائما", "probability": 0.8616536458333334}, {"start": 2448.8, "end": 2449.32, "word": " اسألوا", "probability": 0.813232421875}, {"start": 2449.32, "end": 2449.8, "word": " نفسكم،", "probability": 0.84356689453125}, {"start": 2449.8, "end": 2449.94, "word": " هل", "probability": 0.93701171875}, {"start": 2449.94, "end": 2450.14, "word": " يا", "probability": 0.395751953125}, {"start": 2450.14, "end": 2450.34, "word": " ترى", "probability": 0.8756510416666666}, {"start": 2450.34, "end": 2450.98, "word": " الجزاء", "probability": 0.71044921875}, {"start": 2450.98, "end": 2452.28, "word": " متماثل", "probability": 0.8037109375}, {"start": 2452.28, "end": 2452.66, "word": " نصه", "probability": 0.8894856770833334}, {"start": 2452.66, "end": 2452.86, "word": " زي", "probability": 0.993896484375}, {"start": 2452.86, "end": 2453.14, "word": " نص", "probability": 0.798095703125}, {"start": 2453.14, "end": 2453.5, "word": " التاني", "probability": 0.927734375}, {"start": 2453.5, "end": 2453.7, "word": " ولا", "probability": 0.79296875}, {"start": 2453.7, "end": 2454.44, "word": " لا؟", "probability": 0.813232421875}, {"start": 2454.44, "end": 2454.66, "word": " اذا", "probability": 0.822998046875}, {"start": 2454.66, "end": 2455.04, "word": " نصه", "probability": 0.99267578125}, {"start": 2455.04, "end": 2455.22, "word": " زي", "probability": 0.996826171875}, {"start": 2455.22, "end": 2455.52, "word": " نص", "probability": 0.957275390625}, {"start": 2455.52, "end": 2456.2, "word": " التاني،", "probability": 0.927734375}, {"start": 2456.2, "end": 2456.52, "word": " معناه", "probability": 0.8673502604166666}, {"start": 2456.52, "end": 2456.78, "word": " ذلك", "probability": 0.98828125}, {"start": 2456.78, "end": 2456.92, "word": " اللي", "probability": 0.942626953125}, {"start": 2456.92, "end": 2457.26, "word": " بيكونوا", "probability": 0.8460693359375}, {"start": 2457.26, "end": 2457.56, "word": " عكس", "probability": 0.9871419270833334}, {"start": 2457.56, "end": 2457.86, "word": " بعض", "probability": 0.994140625}, {"start": 2457.86, "end": 2458.3, "word": " بيكونوا", "probability": 0.8541259765625}, {"start": 2458.3, "end": 2458.78, "word": " إيش؟", "probability": 0.8355712890625}], "temperature": 1.0}, {"id": 99, "seek": 248464, "start": 2459.28, "end": 2484.64, "text": "the same compound و بيمثلوا ال mesostructure إذا النص هذا مختلف عن نص هذا معناه ذلك المتعاكسات بيكونوا enantiomals طبعا بقصد بالمتعاكسات لما تكون هذه R و هذه نفسها و هذه نفسها هنا هدوله متعاكسات بس طالما نفس الرمز هنا و نفسه هنا هدوله they are enantiomals قولا واحد على أي حال هذا الكلام راجعوه", "tokens": [3322, 912, 14154, 4032, 4724, 32640, 12984, 1211, 14407, 2423, 3813, 555, 2885, 11933, 15730, 28239, 9381, 23758, 3714, 46456, 46538, 18871, 8717, 9381, 23758, 20449, 8315, 3224, 29910, 23275, 9673, 2655, 3615, 995, 4117, 3794, 9307, 4724, 1829, 30544, 14407, 465, 11520, 298, 1124, 23032, 3555, 3615, 995, 4724, 4587, 9381, 3215, 20666, 2304, 2655, 3615, 995, 4117, 3794, 9307, 5296, 15042, 6055, 30544, 29538, 497, 4032, 29538, 8717, 36178, 11296, 4032, 29538, 8717, 36178, 11296, 34105, 8032, 3215, 12610, 3224, 44650, 3615, 995, 4117, 3794, 9307, 4724, 3794, 23032, 6027, 15042, 8717, 36178, 34892, 2304, 11622, 34105, 4032, 8717, 36178, 3224, 34105, 8032, 3215, 12610, 3224, 436, 366, 465, 11520, 298, 1124, 12174, 12610, 995, 36764, 24401, 15844, 36632, 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"probability": 0.72265625}, {"start": 2463.62, "end": 2464.02, "word": " مختلف", "probability": 0.9871419270833334}, {"start": 2464.02, "end": 2464.18, "word": " عن", "probability": 0.94384765625}, {"start": 2464.18, "end": 2464.42, "word": " نص", "probability": 0.830810546875}, {"start": 2464.42, "end": 2464.76, "word": " هذا", "probability": 0.9453125}, {"start": 2464.76, "end": 2465.4, "word": " معناه", "probability": 0.7607421875}, {"start": 2465.4, "end": 2465.64, "word": " ذلك", "probability": 0.975341796875}, {"start": 2465.64, "end": 2466.58, "word": " المتعاكسات", "probability": 0.9407087053571429}, {"start": 2466.58, "end": 2468.0, "word": " بيكونوا", "probability": 0.9400634765625}, {"start": 2468.0, "end": 2468.92, "word": " enantiomals", "probability": 0.7486572265625}, {"start": 2468.92, "end": 2469.48, "word": " طبعا", "probability": 0.9449462890625}, {"start": 2469.48, "end": 2469.96, "word": " بقصد", "probability": 0.9786376953125}, {"start": 2469.96, "end": 2471.08, "word": " بالمتعاكسات", "probability": 0.97259521484375}, {"start": 2471.08, "end": 2471.28, "word": " لما", "probability": 0.86669921875}, {"start": 2471.28, "end": 2471.54, "word": " تكون", "probability": 0.9521484375}, {"start": 2471.54, "end": 2471.72, "word": " هذه", "probability": 0.556640625}, {"start": 2471.72, "end": 2471.98, "word": " R", "probability": 0.5654296875}, {"start": 2471.98, "end": 2472.1, "word": " و", "probability": 0.83251953125}, {"start": 2472.1, "end": 2472.26, "word": " هذه", "probability": 0.7958984375}, {"start": 2472.26, "end": 2472.64, "word": " نفسها", "probability": 0.8250325520833334}, {"start": 2472.64, "end": 2472.78, "word": " و", "probability": 0.42626953125}, {"start": 2472.78, "end": 2472.78, "word": " هذه", "probability": 0.475341796875}, {"start": 2472.78, "end": 2472.98, "word": " نفسها", "probability": 0.9078776041666666}, {"start": 2472.98, "end": 2473.78, "word": " هنا", "probability": 0.1451416015625}, {"start": 2473.78, "end": 2474.26, "word": " هدوله", "probability": 0.7578125}, {"start": 2474.26, "end": 2475.04, "word": " متعاكسات", "probability": 0.9825846354166666}, {"start": 2475.04, "end": 2475.3, "word": " بس", "probability": 0.866455078125}, {"start": 2475.3, "end": 2475.64, "word": " طالما", "probability": 0.9814453125}, {"start": 2475.64, "end": 2475.98, "word": " نفس", "probability": 0.98681640625}, {"start": 2475.98, "end": 2476.46, "word": " الرمز", "probability": 0.8040364583333334}, {"start": 2476.46, "end": 2476.74, "word": " هنا", "probability": 0.96435546875}, {"start": 2476.74, "end": 2476.86, "word": " و", "probability": 0.990234375}, {"start": 2476.86, "end": 2477.24, "word": " نفسه", "probability": 0.9814453125}, {"start": 2477.24, "end": 2477.54, "word": " هنا", "probability": 0.97607421875}, {"start": 2477.54, "end": 2478.32, "word": " هدوله", "probability": 0.9166259765625}, {"start": 2478.32, "end": 2478.44, "word": " they", "probability": 0.72265625}, {"start": 2478.44, "end": 2478.64, "word": " are", "probability": 0.94677734375}, {"start": 2478.64, "end": 2479.48, "word": " enantiomals", "probability": 0.9205322265625}, {"start": 2479.48, "end": 2480.22, "word": " قولا", "probability": 0.8382161458333334}, {"start": 2480.22, "end": 2481.16, "word": " واحد", "probability": 0.942626953125}, {"start": 2481.16, "end": 2482.14, "word": " على", "probability": 0.6875}, {"start": 2482.14, "end": 2482.36, "word": " أي", "probability": 0.76904296875}, {"start": 2482.36, "end": 2482.54, "word": " حال", "probability": 0.9873046875}, {"start": 2482.54, "end": 2482.84, "word": " هذا", "probability": 0.92236328125}, {"start": 2482.84, "end": 2483.48, "word": " الكلام", "probability": 0.9638671875}, {"start": 2483.48, "end": 2484.64, "word": " راجعوه", "probability": 0.85419921875}], "temperature": 1.0}, {"id": 100, "seek": 251408, "start": 2485.28, "end": 2514.08, "text": "و حاولوا كتير أنكوا تطبقوا بالورقة و القلم بتوقع الحصة اللي جاية تيجوا تسألوا فيه و حلوا الأمثلة اللي موجودة عندكم طبعا تنسوش اليوم مدعوين على المحاضرة اللي بيجي أهلا وسهلا اللي مابيجيش أهلا وسهلا اللي بيجي و بيعمل report عن المحاضرة", "tokens": [2407, 11331, 995, 12610, 14407, 9122, 2655, 13546, 14739, 4117, 14407, 6055, 9566, 3555, 4587, 14407, 20666, 13063, 28671, 4032, 25062, 19528, 39894, 30543, 3615, 21542, 9381, 3660, 13672, 1829, 10874, 995, 10632, 6055, 1829, 7435, 14407, 6055, 3794, 10721, 1211, 14407, 8978, 3224, 4032, 11331, 1211, 14407, 16247, 2304, 12984, 37977, 13672, 1829, 3714, 29245, 23328, 3660, 43242, 24793, 23032, 3555, 3615, 995, 6055, 1863, 3794, 2407, 8592, 45595, 20498, 3714, 3215, 3615, 2407, 9957, 15844, 9673, 5016, 46958, 25720, 13672, 1829, 4724, 1829, 7435, 1829, 5551, 3224, 15040, 46952, 3224, 15040, 13672, 1829, 3714, 16758, 1829, 7435, 1829, 8592, 5551, 3224, 15040, 46952, 3224, 15040, 13672, 1829, 4724, 1829, 7435, 1829, 4032, 4724, 1829, 25957, 1211, 2275, 18871, 9673, 5016, 46958, 25720], "avg_logprob": -0.11718750095367432, "compression_ratio": 1.9952380952380953, "no_speech_prob": 5.125999450683594e-06, "words": [{"start": 2485.28, "end": 2485.52, "word": "و", "probability": 0.935546875}, {"start": 2485.52, "end": 2486.18, "word": " حاولوا", "probability": 0.900390625}, {"start": 2486.18, "end": 2486.66, "word": " كتير", "probability": 0.88037109375}, {"start": 2486.66, "end": 2487.06, "word": " أنكوا", "probability": 0.5626627604166666}, {"start": 2487.06, "end": 2487.56, "word": " تطبقوا", "probability": 0.97939453125}, {"start": 2487.56, "end": 2488.04, "word": " بالورقة", "probability": 0.9503580729166666}, {"start": 2488.04, "end": 2488.16, "word": " و", "probability": 0.72509765625}, {"start": 2488.16, "end": 2488.54, "word": " القلم", "probability": 0.942626953125}, {"start": 2488.54, "end": 2489.14, "word": " بتوقع", "probability": 0.7425130208333334}, {"start": 2489.14, "end": 2489.58, "word": " الحصة", "probability": 0.9913736979166666}, {"start": 2489.58, "end": 2489.7, "word": " اللي", "probability": 0.726318359375}, {"start": 2489.7, "end": 2489.96, "word": " جاية", "probability": 0.88671875}, {"start": 2489.96, "end": 2490.22, "word": " تيجوا", "probability": 0.8531494140625}, {"start": 2490.22, "end": 2490.86, "word": " تسألوا", "probability": 0.87314453125}, {"start": 2490.86, "end": 2491.36, "word": " فيه", "probability": 0.97802734375}, {"start": 2491.36, "end": 2492.24, "word": " و", "probability": 0.82177734375}, {"start": 2492.24, "end": 2492.6, "word": " حلوا", "probability": 0.9521484375}, {"start": 2492.6, "end": 2493.24, "word": " الأمثلة", "probability": 0.970703125}, {"start": 2493.24, "end": 2493.56, "word": " اللي", "probability": 0.959228515625}, {"start": 2493.56, "end": 2494.06, "word": " موجودة", "probability": 0.9910888671875}, {"start": 2494.06, "end": 2495.4, "word": " عندكم", "probability": 0.968994140625}, {"start": 2495.4, "end": 2502.12, "word": " طبعا", "probability": 0.979736328125}, {"start": 2502.12, "end": 2502.9, "word": " تنسوش", "probability": 0.95673828125}, {"start": 2502.9, "end": 2503.2, "word": " اليوم", "probability": 0.9521484375}, {"start": 2503.2, "end": 2503.74, "word": " مدعوين", "probability": 0.89423828125}, {"start": 2503.74, "end": 2503.92, "word": " على", "probability": 0.640625}, {"start": 2503.92, "end": 2504.72, "word": " المحاضرة", "probability": 0.9747314453125}, {"start": 2504.72, "end": 2508.36, "word": " اللي", "probability": 0.928955078125}, {"start": 2508.36, "end": 2508.78, "word": " بيجي", "probability": 0.966064453125}, {"start": 2508.78, "end": 2509.06, "word": " أهلا", "probability": 0.7819010416666666}, {"start": 2509.06, "end": 2509.5, "word": " وسهلا", "probability": 0.861328125}, {"start": 2509.5, "end": 2509.68, "word": " اللي", "probability": 0.84375}, {"start": 2509.68, "end": 2510.24, "word": " مابيجيش", "probability": 0.8334147135416666}, {"start": 2510.24, "end": 2510.5, "word": " أهلا", "probability": 0.9811197916666666}, {"start": 2510.5, "end": 2511.08, "word": " وسهلا", "probability": 0.98779296875}, {"start": 2511.08, "end": 2512.4, "word": " اللي", "probability": 0.931884765625}, {"start": 2512.4, "end": 2512.72, "word": " بيجي", "probability": 0.9942626953125}, {"start": 2512.72, "end": 2512.8, "word": " و", "probability": 0.900390625}, {"start": 2512.8, "end": 2513.1, "word": " بيعمل", "probability": 0.870361328125}, {"start": 2513.1, "end": 2513.4, "word": " report", "probability": 0.95166015625}, {"start": 2513.4, "end": 2513.66, "word": " عن", "probability": 0.9775390625}, {"start": 2513.66, "end": 2514.08, "word": " المحاضرة", "probability": 0.9923095703125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2514.00125, "duration_after_vad": 2451.0937499999927}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo.srt
new file mode 100644
index 0000000000000000000000000000000000000000..4d7e9b8545d1c88f81ca3715336ca5c04cd5c920
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo.srt
@@ -0,0 +1,1836 @@
+1
+00:00:05,650 --> 00:00:10,570
+المرة الماضية اتكلمنا على مقدمة لل aromatic
+
+2
+00:00:10,570 --> 00:00:16,570
+compounds وتسميتها واضح اليوم إن شاء الله بدنا 
+
+3
+00:00:16,570 --> 00:00:22,170
+ندرس تفاعلات ال aromatic compounds تفاعلات البنزين 
+
+4
+00:00:22,170 --> 00:00:29,310
+دائماً و أبداً دائماً و أبداً صورة كلية لأي موضوع
+
+5
+00:00:29,310 --> 00:00:35,010
+بيتريح واضح؟  والصورة الكلية دائماً أنك تكون فاهم 
+
+6
+00:00:35,010 --> 00:00:38,990
+ايش التفاعل العام يعني احنا الـ chapter أربعة
+
+7
+00:00:38,990 --> 00:00:44,270
+أربعة من أربعة عشر chapter يعني ثلث المنهج إذا أجيت 
+
+8
+00:00:44,270 --> 00:00:49,500
+سألتكم ايش اللي درسناه؟  الالكينز لما نقول الـ
+
+9
+00:00:49,500 --> 00:00:54,120
+Alkenes، شو تفاعلاتهم؟ بكلمة واحدة، بدو يكون 
+
+10
+00:00:54,120 --> 00:00:58,660
+الكلام بشكل أساسي Substitution Free Radical 
+
+11
+00:00:58,660 --> 00:01:02,520
+Substitution، مظبوط ولا لا؟ رغم أنه بشكل عام inert 
+
+12
+00:01:02,520 --> 00:01:06,920
+لكن لما بيعملوا Free Radical Substitution أو الـ
+
+13
+00:01:06,920 --> 00:01:13,060
+Thermolysis والتكسر بالحرارة الآن، لو جينا على الـ
+
+14
+00:01:13,060 --> 00:01:21,250
+Alkenes تفاعلهم الـ Addition الآن لو سألنا ايش نوع
+
+15
+00:01:21,250 --> 00:01:26,350
+ال addition اللي بتتم على ال الكينز ايش اللي كنا 
+
+16
+00:01:26,350 --> 00:01:30,170
+نبدأ فيه التفاعل موجب ولا سالب اللي بيجي وبيهاجم 
+
+17
+00:01:30,170 --> 00:01:35,350
+ال الكينز موجب H+ إذا نوع ال addition اللي 
+
+18
+00:01:35,350 --> 00:01:40,090
+على ال الكينز Electrophilic addition Electrophilic
+
+19
+00:01:40,090 --> 00:01:44,710
+لأنه بيجي Electrophile بيجي موجب ..لأن ليش بيجي 
+
+20
+00:01:44,710 --> 00:01:49,570
+الموجب؟ لأن هذا ال keen double bond .. هاي زيك 
+
+21
+00:01:49,570 --> 00:01:52,770
+double bond .. double bond يعني إلكترونات .. لأن
+
+22
+00:01:52,770 --> 00:01:57,520
+الإلكترونات شو اللي بيجي يهاجم عليها؟ positive ولا 
+
+23
+00:01:57,520 --> 00:02:02,360
+negative؟ positive إذا ال addition اللي بيصير على 
+
+24
+00:02:02,360 --> 00:02:07,680
+ال alkenes ومتلها ال alkynes is electrophilic 
+
+25
+00:02:07,680 --> 00:02:12,040
+addition يعني لو بدنا نيجي نجيبلكوا سؤال نقول 
+
+26
+00:02:12,040 --> 00:02:16,280
+والله ال alkenes undergo a nucleophilic addition
+
+27
+00:02:16,280 --> 00:02:22,180
+in general الجواب غلط التفاعل الأساسي Electrophilic 
+
+28
+00:02:22,180 --> 00:02:27,520
+addition هي إلكترونيات بجهة Electrophile موجّه، 
+
+29
+00:02:27,520 --> 00:02:32,600
+واضح؟ الآن الـ aromatic compounds، ايش التفاعل 
+
+30
+00:02:32,600 --> 00:02:37,960
+الأساسي؟ والله إذا الـalkenes فيهم double bond
+
+31
+00:02:37,960 --> 00:02:45,620
+واحدة البنزين فيه ثلاثة اللي عاملين resonance يعني 
+
+32
+00:02:45,620 --> 00:02:49,660
+اللي بدو ييجي يهاجم على البنزين كأنه بيهاجم على
+
+33
+00:02:49,660 --> 00:02:56,280
+حقل من الإلكترونات كأنه بيهاجم على سحابة إلكترونية 
+
+34
+00:02:56,280 --> 00:02:59,240
+الآن اللي بدو ييجي يهاجم على سحابة إلكترونية ايش 
+
+35
+00:02:59,240 --> 00:03:04,020
+شرطه؟ إنه بدو يكون .. هذه البنزين .. بدو يكون موجّه
+
+36
+00:03:05,250 --> 00:03:10,930
+واضح بيكون موجب اللي بيهاجم على البنزين على سحابة
+
+37
+00:03:10,930 --> 00:03:14,450
+إلكترونية كبيرة بيكون موجب وعشان هيك المسمى 
+
+38
+00:03:14,450 --> 00:03:20,760
+التفاعل electrophilic aromatic substitution هنا 
+
+39
+00:03:20,760 --> 00:03:27,240
+بيجينا اختلاف أساسي وجوهري كبير كبير ما بين ال
+
+40
+00:03:27,240 --> 00:03:31,840
+alkenes وما بين ال aromatic compounds ال alkenes
+
+41
+00:03:31,840 --> 00:03:34,360
+كانوا عبارة عن double bond وال double bond ايش 
+
+42
+00:03:34,360 --> 00:03:42,800
+نقول عنها؟ بتتكسر بتعمل إضافة إضافة رابطتين الآن
+
+43
+00:03:42,800 --> 00:03:46,800
+ربما يخطر على بال الناس للوهلة الأولى إنه إذا الـ
+
+44
+00:03:46,800 --> 00:03:50,500
+double bond بتعمل addition لما يكونوا ثلاثة ممكن 
+
+45
+00:03:50,500 --> 00:03:54,820
+نتخيلهم بهذا الشكل أو بالشكل ما شاء الله كم 
+
+46
+00:03:54,820 --> 00:03:58,760
+double bond عندي ثلاثة إنه نتخيل إنه بدو ييجي
+
+47
+00:03:58,760 --> 00:04:02,380
+electrophile متفقين عليها بدو يجيهم موجب لكن يعمل 
+
+48
+00:04:02,380 --> 00:04:06,620
+addition الواقع إنه بالتجربة ما بصيرش على 
+
+49
+00:04:06,620 --> 00:04:12,680
+البنزين addition ما بيصير عليه addition رغم وجود
+
+50
+00:04:12,680 --> 00:04:17,060
+ايش ثلاثة double bonds، عشان هيك بيقولوا أن ال double
+
+51
+00:04:17,060 --> 00:04:26,180
+bonds هدول تبعون البنزين لا يوجد فيهم مواصفات ال
+
+52
+00:04:26,180 --> 00:04:29,840
+double bond الواحدة، they don't have or they don't
+
+53
+00:04:29,840 --> 00:04:34,680
+show double bond character لأن أهم ميزة لل double
+
+54
+00:04:34,680 --> 00:04:39,480
+bond أنها بتعمل ايش؟ addition هدول ما بيرضوش يعملوا 
+
+55
+00:04:39,480 --> 00:04:44,560
+addition واضح؟ هدول ما بيرضوش يعملوا addition ليش 
+
+56
+00:04:44,560 --> 00:04:47,460
+هدول مش راضيين يعملوا addition هان، برا، وهان،
+
+57
+00:04:47,460 --> 00:04:51,220
+برا، وهان، برا؟ لأن هم مع بعضهم عاملين resonance 
+
+58
+00:04:51,220 --> 00:04:56,060
+egg عاملين دائرة مغلقة في بعض ومثبتين نفسهم
+
+59
+00:04:56,060 --> 00:05:01,520
+بنفسهم، ما بيحبوش يتفاعلوا برا رغم وجود ثلاثة
+
+60
+00:05:01,520 --> 00:05:05,400
+double bonds في البنزين لكن ما بيعملش تفاعل الـ
+
+61
+00:05:05,400 --> 00:05:10,760
+double bond إذا هذا الكلام شوية هيسهل علينا يعني
+
+62
+00:05:10,760 --> 00:05:14,360
+لما كنا ناخد ال double bonds ونبدأ نقول إضافة
+
+63
+00:05:14,360 --> 00:05:21,320
+نقول إضافة ال hydrogen ال halogen ال HBr ال HCl ال
+
+64
+00:05:21,320 --> 00:05:27,220
+H2O وكل ايش إضافات إضافات إضافات هنا ولا تفاعل
+
+65
+00:05:27,220 --> 00:05:31,420
+منهم باللغة ولا شيء بصير ولا كأنه عندي 
+
+66
+00:05:37,800 --> 00:05:41,800
+البنزين صح بحتوي على ثلاثة double bonds لكنه لا يتفاعل 
+
+67
+00:05:41,800 --> 00:05:48,220
+بدور double bonds بيعمل substitution ايش اللي 
+
+68
+00:05:48,220 --> 00:05:53,440
+بده يبدل اللي بده يبدل ببساطة ال H اللي موجودة هنا
+
+69
+00:05:53,440 --> 00:06:00,020
+بتبدأ تنشال ويجي بدالها ايش جديد شيلت H حطيت X أيّاً 
+
+70
+00:06:00,020 --> 00:06:04,460
+كانت هال X هذا التفاعل ايش يعتبر substitution إذا
+
+71
+00:06:04,460 --> 00:06:09,560
+التفاعل الأساسي لل aromatic compounds the main 
+
+72
+00:06:09,560 --> 00:06:16,010
+reaction of aromatic compounds is لـ Electrophilic
+
+73
+00:06:16,010 --> 00:06:19,850
+Substitution بدّيكم تتعودوا تحطوا الكلام بالظبط 
+
+74
+00:06:19,850 --> 00:06:23,790
+لأنه أنا برضه لما بدي أسألكم عنه بدي أسألكم
+
+75
+00:06:23,790 --> 00:06:30,490
+بالظبط في الألكينز كنا نقول free radical
+
+76
+00:06:30,490 --> 00:06:34,610
+substitution متذكرين؟ لما كنا نعمل الهالوجينيشن 
+
+77
+00:06:34,610 --> 00:06:38,370
+كان إبدال من خلال ال free radical اللي كان يهاجم 
+
+78
+00:06:38,370 --> 00:06:42,730
+CR radical هنا اللي بده يهاجم موجب إذا في عنده 
+
+79
+00:06:42,730 --> 00:06:47,170
+free radical substitution في عنده electrophilic 
+
+80
+00:06:47,170 --> 00:06:50,670
+substitution بعد ذلك بشابتر ستة في substitution
+
+81
+00:06:50,670 --> 00:06:53,850
+ثانية على الalkyl halide اللي بيهاجم ال nucleophile 
+
+82
+00:06:53,850 --> 00:06:59,260
+في nucleophilic substitution إذا أنا عندي أكثر من 
+
+83
+00:06:59,260 --> 00:07:03,380
+شغلة وكل حاجة بدنا نحفظها بالظبط ما بتبطلش أنا أجي
+
+84
+00:07:03,380 --> 00:07:07,200
+أقول ال alkanes وال aromatic compounds وبعد شوية 
+
+85
+00:07:07,200 --> 00:07:09,680
+وشنطر ستة ال alkyl halides they undergo 
+
+86
+00:07:09,680 --> 00:07:14,900
+substitution صح إبدال لكن في الثلاث حالات مختلفين
+
+87
+00:07:14,900 --> 00:07:18,140
+صرنا ماخذين احنا ال alkanes free radical
+
+88
+00:07:18,140 --> 00:07:20,620
+substitution الآن ال aromatic compounds 
+
+89
+00:07:20,620 --> 00:07:24,520
+electrophilic substitution بعد شوية ال alkyl
+
+90
+00:07:24,520 --> 00:07:28,790
+halides الـ Nucleophilic Substitution الطلاب اللي
+
+91
+00:07:28,790 --> 00:07:34,670
+أحياناً بيغلطوا بيكونوا مش مميزين هذه الشغلات فخلاص 
+
+92
+00:07:34,670 --> 00:07:38,370
+كله عندهم substitution بتجيب سؤال صح و غلط ولا
+
+93
+00:07:38,370 --> 00:07:43,680
+سؤالين على هذه تخربته فيهم، واضح؟ إذا هذا التفاعل 
+
+94
+00:07:43,680 --> 00:07:47,980
+Electrophilic Substitution إنه حيصير إبدال
+
+95
+00:07:47,980 --> 00:07:52,940
+و المهاجم Electrophile، الآن يمكن أن يتم أنواع
+
+96
+00:07:52,940 --> 00:07:57,520
+كثيرة من الإبدال، ممكن إنه يصير إبدال ب X، بحيث إن 
+
+97
+00:07:57,520 --> 00:08:04,970
+X هالوجين يعني Cl Br I واضح هذه العملية بنسميها
+
+98
+00:08:04,970 --> 00:08:09,130
+الهالوجينيشن الهالوجينيشن اللي بده يضيف ايش لازم 
+
+99
+00:08:09,130 --> 00:08:13,230
+يكون موجبة اللي بده يضيف عشان يعمل الإبدال يعني 
+
+100
+00:08:13,230 --> 00:08:17,390
+اللي بده يستخدم في الإبدال ممكن تتم إضافة أو إبدال
+
+101
+00:08:17,390 --> 00:08:22,970
+نترو جروب والنيترو ايش بتلاحظوها هنا موجبة
+
+102
+00:08:22,970 --> 00:08:28,660
+العملية نيتراشن بدل الأكشن نيترو نيتراشن بكس
+
+103
+00:08:28,660 --> 00:08:35,200
+هالوجيناشن ممكن تتم بـ HSO3+ سالفونيك أسد 
+
+104
+00:08:35,200 --> 00:08:44,180
+سالفوناشن ممكن تتم بـ R+ الكليجروب الـ Alkylation
+
+105
+00:08:44,180 --> 00:08:49,320
+ممكن يتم بـ RC=O+ في النهاية
+
+106
+00:08:49,320 --> 00:08:52,940
+RC=O+ هذه اسمها مجموعة
+
+107
+00:08:52,940 --> 00:08:57,600
+الاسيليجروب أسيلة الآن احنا هناخد هدول بالتفصيل
+
+108
+00:08:58,500 --> 00:09:01,340
+يعني هذا الـ scheme العام أو الصورة الكلية 
+
+109
+00:09:01,340 --> 00:09:04,140
+للتفاعلات بناخد الـ halogenation، بعدين الـ
+
+110
+00:09:04,140 --> 00:09:07,920
+nitration، sulfonation، alkylation، acylation، 
+
+111
+00:09:07,920 --> 00:09:12,720
+يعني ايش؟ بناخدهم بالتفصيل وكيف الـ mechanism اللي 
+
+112
+00:09:12,720 --> 00:09:16,460
+بتتم فيها التفاعل، كيف القالية اللي بتتم فيها 
+
+113
+00:09:16,460 --> 00:09:24,560
+التفاعل خلينا نبدأ في ال halogenation مثلاً، لو
+
+114
+00:09:24,560 --> 00:09:26,880
+اجينا نعمل تفاعل مع البرومين
+
+115
+00:09:29,240 --> 00:09:33,740
+بتكون تنتبه دائماً و أبداً لل reagents كاملة يعني ما 
+
+116
+00:09:33,740 --> 00:09:38,020
+تحفظوش بس الأشياء من طرفها يعني لما كنا زمان نفعل 
+
+117
+00:09:38,020 --> 00:09:43,860
+ال cane مع ال bromine كنا نقول ال cane مع ال
+
+118
+00:09:43,860 --> 00:09:48,220
+bromine نكتب على الصامولة وبعدين نحط تحت عشان يمشي 
+
+119
+00:09:48,220 --> 00:09:55,520
+التفاعل heat or light ضوء أو حرارة واضح؟ الآن هنا 
+
+120
+00:09:55,520 --> 00:10:01,380
+مع البنزين لو عملنا bromine وكتبنا heat or light ما 
+
+121
+00:10:01,380 --> 00:10:10,520
+بيصيرش تفاعل لازم البرومين يكون معه مركب FeBr3 أو
+
+122
+00:10:10,520 --> 00:10:14,760
+ممكن يكون Aluminum Br3 أو Aluminum Cl3 بمشي خلّاني
+
+123
+00:10:14,760 --> 00:10:21,180
+أقول أنسب وأشهر الـ FeBr3 واضح؟ هدول المادتين شيء 
+
+124
+00:10:21,180 --> 00:10:26,900
+بيعملوا مع بعض، بتيجوا تطلعوا تتذكرولي البرومين 
+
+125
+00:10:26,900 --> 00:10:32,420
+نفسه جزء من ذرتين بروم زي بعض، هاي وهاي نتخيل، هاي
+
+126
+00:10:32,420 --> 00:10:37,240
+بروم وهاي بروم، يتصور البرومين نفسه كجزء، بيكون 
+
+127
+00:10:37,240 --> 00:10:42,370
+قطبي ولا غير قطبي؟ بيكون غير قطبي لإن هذه بروم وهذه
+
+128
+00:10:42,370 --> 00:10:46,290
+بروم وال electronegativity متساوية مش زي ال HCl
+
+129
+00:10:46,290 --> 00:10:50,670
+انطارت ممكن يكون في فان دير فالز forces أو لندن
+
+130
+00:10:50,670 --> 00:10:53,930
+forces اللي هي حركة الإلكترونات يعني شوية تتركز 
+
+131
+00:10:53,930 --> 00:10:58,650
+لكن بشكل عام هو nonpolar لإن الذرتين أشكالهم زي 
+
+132
+00:10:58,650 --> 00:11:04,290
+بعض طب هذا الجزء ال nonpolar كيف أنا بدي أخليه
+
+133
+00:11:04,290 --> 00:11:11,220
+polar بحيث أنه أنا بدي اخذ منه Br+ لأنه المطلوب
+
+134
+00:11:11,220 --> 00:11:19,200
+لكي يتم التفاعل بـ Br+ واضح؟ كيف بدي أكسر الجزء 
+
+135
+00:11:19,200 --> 00:11:26,860
+اللي هو عبارة عن Br2 أخليه عبارة عن Br- وBr+، و
+
+136
+00:11:26,860 --> 00:11:32,460
+آخذ للتفاعل الـ Br+، واضح الفكرة؟ إذا أنا بدي
+
+137
+00:11:32,460 --> 00:11:38,460
+أكسر التماثل تبعه، بنجيب هذا المركب الـ FeBr3 الـ 
+
+138
+00:11:38,460 --> 00:11:46,070
+FeBr3 لو لاحظناه لوحده هنا زي هيك عبارة عن حديد 
+
+139
+00:11:46,070 --> 00:11:52,470
+متصل بكم بروم؟ ثلاثة بزّامه متصل بـ ثلاثة برومين، كم 
+
+140
+00:11:52,470 --> 00:11:58,250
+إلكترون حواليه؟ ستة الوضع الطبيعي للإلكترونات،
+
+141
+00:11:58,250 --> 00:12:02,230
+كذاش يكونوا؟ ثمانية، هذا فيه ناقص إلكترونات، 
+
+142
+00:12:02,230 --> 00:12:08,180
+electron deficient أو electron poor ايش يعني 
+
+143
+00:12:08,180 --> 00:12:13,160
+electron deficient أو poor؟ عنده نقص أو فقر أو عوز 
+
+144
+00:12:13,160 --> 00:12:16,560
+في الإلكترونات الأشياء اللي عندها نقص في
+
+145
+00:12:16,560 --> 00:12:21,300
+الإلكترونات حسب تعريف Lewis للأحمض والقواعد عبارة
+
+146
+00:12:21,300 --> 00:12:26,960
+عن Lewis acid ولا Lewis base Lewis acid acid is 
+
+147
+00:12:26,960 --> 00:12:31,700
+electron acceptor بده إلكترونات وال base is 
+
+148
+00:12:31,700 --> 00:12:36,900
+electron donor بتاعة الإلكترونات إذا هذا عبارة عن 
+
+149
+00:12:38,090 --> 00:12:47,270
+Lewis حمض حمض حمض
+
+150
+00:12:47,270 --> 00:12:49,290
+حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض 
+
+151
+00:12:49,290 --> 00:12:50,910
+حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض
+
+152
+00:12:50,910 --> 00:12:52,970
+حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض
+
+153
+00:12:52,970 --> 00:12:55,830
+حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض
+
+154
+00:12:55,830 --> 00:13:04,850
+حمض حمض حمض حمض حمض حمض حمض حمض حمض حمض أ
+
+155
+00:13:05,550 --> 00:13:10,430
+واضح؟ إذا وجود هذا الـ Lewis acid اللي بحاجة إلى
+
+156
+00:13:10,430 --> 00:13:15,830
+Br رابعة هو اللي بيخدمني في التفاعل لأنه بيعمل 
+
+157
+00:13:15,830 --> 00:13:22,270
+polarization أو استقطاب بيسحب من الـ Br2 Br خلّيني 
+
+158
+00:13:22,270 --> 00:13:26,550
+أقول مع with its pair of electrons and it leaves a
+
+159
+00:13:26,550 --> 00:13:32,070
+positive bromine بيسيّب لي bromine موجبة هذا ال
+
+160
+00:13:32,070 --> 00:13:35,680
+bromine الموجبة الآن هو اللي بتفاعل يعني في الـ
+
+161
+00:13:35,680 --> 00:13:39,000
+slide الجاية هتلاحظوا أنه بدأنا ببرومين مجبرة في
+
+162
+00:13:39,000 --> 00:13:43,640
+حدّ بدى يعود يسالنا من وين اجا؟ شوفنا من وين اجا، 
+
+163
+00:13:43,640 --> 00:13:53,020
+بمساعدة الـ Lewis acid الـ FeBr3 الآن
+
+164
+00:13:53,020 --> 00:13:57,520
+هذا الـ Br+ أول ما بيجي عندي خلينا نتخيل
+
+165
+00:13:57,520 --> 00:14:02,760
+أنه هنا كانت فيه double bond واضح؟ وفيه هيدروجين
+
+166
+00:14:03,560 --> 00:14:06,720
+هذه الـ double bonds إلكترونية وجايها موجبة .. ايش
+
+167
+00:14:06,720 --> 00:14:13,480
+بتعمل؟ بتعمل رابطة معه، هيها إذا تحركت واحدة من 
+
+168
+00:14:13,480 --> 00:14:17,720
+الـ double bonds ازاي كنت بتكون تتخيل؟ تحركت 
+
+169
+00:14:17,720 --> 00:14:23,280
+واحدة من الـ double bonds وعملت رابطة مع البرومين
+
+170
+00:14:23,280 --> 00:14:30,620
+لما تحركت هذه الـ double bonds شو سابت مكانها؟ هذا
+
+171
+00:14:30,620 --> 00:14:34,900
+الـ carbocation مش ضروري يظل ثابت مكانه، ممكن يعمل 
+
+172
+00:14:34,900 --> 00:14:38,760
+resonance، بمعنى لو هات تحركت زي هيك، وين حيصير
+
+173
+00:14:38,760 --> 00:14:42,740
+الموجبة؟ على هذا الموقع، لو هات تحركت زي هيك، وين 
+
+174
+00:14:42,740 --> 00:14:47,580
+حيصير الموجبة؟ على هذا الموقع، إذا أنا عمالة في عنده 
+
+175
+00:14:49,060 --> 00:14:53,8
+
+201
+00:17:25,700 --> 00:17:33,240
+FeBr3 بطلع زي ما هو إذا صار عندي بدل الفنزين برومو
+
+202
+00:17:33,240 --> 00:17:40,800
+بنزين زائد HBr يعني كأننا بنقول بنزين زائد Br2 في
+
+203
+00:17:40,800 --> 00:17:46,860
+وجود الـFeBr3 برومو بنزين زائد HBr، واضح؟ بس احنا
+
+204
+00:17:46,860 --> 00:17:50,920
+قعدنا شوفنا التفاصيل كيف بيتم التفاعل، الـmechanism
+
+205
+00:17:50,920 --> 00:17:55,620
+of the reaction وشوفنا إن ال reaction هنا بيمشي
+
+206
+00:17:55,620 --> 00:17:57,440
+بـelectrophilic aromatic
+
+207
+00:18:04,180 --> 00:18:09,000
+الآن اللي فهم هذا الكلام هيلاحظ أنه بعد هيك باقي 
+
+208
+00:18:09,000 --> 00:18:16,560
+التفاعلات بتصير تقريبا شبيهة جدا، يعني بنقدر نمشي
+
+209
+00:18:16,560 --> 00:18:20,420
+أسرع، واضح؟ بنقدر نمشي في الشارع أسرع
+
+210
+00:18:23,210 --> 00:18:28,810
+مثلًا لو بدنا نيجي نقول الـ Cl2 برضه بنستعمله Cl2
+
+211
+00:18:28,810 --> 00:18:33,430
+مع FeCl3 بطلع Cl positive و double bond و هذ بتعمل
+
+212
+00:18:33,430 --> 00:18:38,490
+resonance ونفس الكلام لو قلنا ال I2 بنستعمله
+
+213
+00:18:38,490 --> 00:18:44,050
+كلوريد في نهاية هدول بتطلعوله I positive
+
+214
+00:18:44,050 --> 00:18:47,650
+و بتضيف ال I positive و بيعمل resonance تفقد ال H
+
+215
+00:18:47,650 --> 00:18:55,170
+plus واضح؟ عملية سهلة، الآن لو اجينا ل ال
+
+216
+00:18:55,170 --> 00:19:00,670
+nitration لو اجينا ل ال nitration لو ضفنا على
+
+217
+00:19:00,670 --> 00:19:08,290
+البنزين nitric acid لحاله ما بيصيرش تفاعل يعني لو
+
+218
+00:19:08,290 --> 00:19:14,290
+جبت بنزين وحطيت فوق السهم بس nitric acid هاي
+
+219
+00:19:14,290 --> 00:19:21,780
+بنزين وبتحط فوق السهم ايش؟ HNO3 نيتريك أسيد لحاله
+
+220
+00:19:21,780 --> 00:19:26,920
+ما بيصيرش تفاعل عشان أعمل نيتريشن لازم أضيف نيتريك
+
+221
+00:19:26,920 --> 00:19:34,060
+أسيد مع سلفوريك أسيد H2SO4 لازم أضيف هدول الاتنين
+
+222
+00:19:34,060 --> 00:19:38,720
+مع بعض اللي بدأت تكمل معادلة جيوب سؤال امتحان لازم
+
+223
+00:19:38,720 --> 00:19:46,760
+تكتب ليه لـNitration HNO3 مع H2SO4 الآن في الخطوة
+
+224
+00:19:46,760 --> 00:19:51,400
+التحضيرية في الخطوة التحضيرية للتفاعل الـH2SO4 و
+
+225
+00:19:51,400 --> 00:19:55,180
+الـHNO3 هم اللي بيتفاعلوا بينهم وبين بعض بيعطوني
+
+226
+00:19:55,180 --> 00:20:00,840
+H2O زي HNO2 plus أنا اللي بهمني الـHNO2 plus اللي
+
+227
+00:20:00,840 --> 00:20:03,900
+هو الـelectrophile الآن إذا صار موجود
+
+228
+00:20:03,900 --> 00:20:10,150
+الـelectrophile خلاص انحلت المشكلة واضح؟ بنفس
+
+229
+00:20:10,150 --> 00:20:14,930
+المنطق السابق إذا خلطة الـ H2SO4 و الـ HNO3 هي
+
+230
+00:20:14,930 --> 00:20:20,330
+اللي بتطلع له الـ Electrophile الـ NO2 Plus هذا
+
+231
+00:20:20,330 --> 00:20:23,590
+الـ NO2 Plus لما يتفعل تتحرك Double Bond بيعمل
+
+232
+00:20:23,590 --> 00:20:27,770
+Carbocation ب Resonance وبعدين بيفقد H Plus
+
+233
+00:20:27,770 --> 00:20:31,410
+بيعطينا Nitro مش فيها المشكلة
+
+234
+00:20:34,510 --> 00:20:40,670
+طيب، لو إجينا لـ Sulphonation، كيف بنضيف الـ
+
+235
+00:20:40,670 --> 00:20:48,610
+Sulphonic Acid؟ اللي بنحطه حقيقة على السهم H2SO4،
+
+236
+00:20:48,610 --> 00:20:53,810
+الـ sulphuric acid، بس بيقولوا عنه fuming sulphuric acid
+
+237
+00:20:53,810 --> 00:20:57,370
+ايش يعني fuming sulphuric acid؟
+
+238
+00:20:57,370 --> 00:21:01,890
+fumes يعني أبخرة وfume hood اللي هو خزانة الأبخرة
+
+239
+00:21:01,890 --> 00:21:04,670
+اللي في المختبر اللي بتشفط البخار ال fuming هو
+
+240
+00:21:04,670 --> 00:21:10,030
+عبارة عن sulphuric acid وفيه كمية إضافية من غاز ال
+
+241
+00:21:10,030 --> 00:21:15,150
+SO3 اللي هو أساسا اللي لما بندوبه بالمية بيعمل
+
+242
+00:21:15,150 --> 00:21:18,450
+sulfuric acid بتذكرين انتوا كيف بنحضر ال sulfuric
+
+243
+00:21:18,450 --> 00:21:24,870
+acid؟ بندوب SO3 in water ولما بدنا نعمل ال
+
+244
+00:21:24,870 --> 00:21:34,170
+sulfurous acid ال H2SO3 نراجع
+
+245
+00:21:34,170 --> 00:21:45,930
+شوية كيميا SO3 زائد H2O و SO2 زائد H2O الـ
+
+246
+00:21:45,930 --> 00:21:52,590
+SO3 مع الـ H2O شو بيعطينا؟ الحمض الكبريتيك H2SO4
+
+247
+00:21:52,590 --> 00:21:56,850
+إذا من ثالث أكسيد الكبريت مع الميه بطلع الـ H2SO4
+
+248
+00:21:56,850 --> 00:21:59,890
+H2SO3
+
+249
+00:21:59,890 --> 00:22:05,530
+الـ Sulphurous و Sulphuric Sulphuric Acid و
+
+250
+00:22:05,530 --> 00:22:09,190
+Sulphurous Acid فالخلاصة إن إحنا هنا لما بنستعمل
+
+251
+00:22:09,190 --> 00:22:15,330
+نستعمل H2SO4 مع غاز SO3 يعني بيكون ال
+
+252
+00:22:15,330 --> 00:22:20,850
+sulfuric acid لما نفتح البوتل تبعه بيدخل محطوط فيه
+
+253
+00:22:20,850 --> 00:22:26,790
+كمية ايش زائدة من ال SO3 طيب خلينا قبل ما
+
+254
+00:22:26,790 --> 00:22:30,270
+نمحي هذه نقول لكم هذا المعادلة بإيش بتذكركم
+
+255
+00:22:30,270 --> 00:22:34,770
+التانية بلاش يقولوا
+
+256
+00:22:34,770 --> 00:22:44,120
+ايوة بإيش بالظبط ال acid rain الأمطار الحامضية لأن
+
+257
+00:22:44,120 --> 00:22:49,060
+المصانع .. المصانع بتطلع أبخرة SO2 .. أبخرة الـ
+
+258
+00:22:49,060 --> 00:22:54,280
+SO2 مع الميال في الجو والسحاب بتعمل H2SO3 هذا اللي
+
+259
+00:22:54,280 --> 00:22:57,520
+بينزل على الشجر و بيموته اللي بنسميه الـ acid rain
+
+260
+00:22:57,520 --> 00:23:02,520
+ال acid rain أو المطر الحامضي أو على المباني على
+
+261
+00:23:02,520 --> 00:23:06,980
+الحجر الجيري و المباني و ال .. الظواهر اللي بتصير
+
+262
+00:23:06,980 --> 00:23:10,520
+.. اكيد بتاعة ال .. ال acid rain
+
+263
+00:23:14,560 --> 00:23:21,140
+إذا خلطة ال H2SO4 و ال SO3 هي اللي بتطلع ليه؟ ال
+
+264
+00:23:21,140 --> 00:23:29,760
+SO3H كلها كلها SO3H بتكون positive ولا عن S
+
+265
+00:23:29,760 --> 00:23:34,780
+double bond O double bond O OH ومن هنا بتتفاعل
+
+266
+00:23:34,780 --> 00:23:38,060
+واضح؟
+
+267
+00:23:38,060 --> 00:23:41,560
+أنتم بتذكرين كيف شكل ال sulfuric acid في الكيميا
+
+268
+00:23:41,560 --> 00:24:04,650
+ولا لأ؟ التفصيل اللي هو الـ Sulphuric acid واضح؟
+
+269
+00:24:04,650 --> 00:24:07,930
+هذا اللي هو اللي بيكون الـ Sulphur هنا ال positive
+
+270
+00:24:07,930 --> 00:24:12,610
+وهو اللي بيجي يتفاعل هو اللي بده يجي يتفاعل
+
+271
+00:24:12,610 --> 00:24:19,910
+الإلكترونات بتتحرك عليه وبنفس المنطق بتتم استكمال
+
+272
+00:24:19,910 --> 00:24:26,010
+التفاعل بنفس المنطق بتتم عملية استكمال التفاعل
+
+273
+00:24:26,010 --> 00:24:30,390
+بنحصل على الـ Sulphonic acid هذا المركب اللي فيه
+
+274
+00:24:30,390 --> 00:24:38,450
+SO3H بيسموه ايش Sulphonic acid Sulphonic acid
+
+275
+00:24:40,460 --> 00:24:44,120
+أو مرات بيكتبوا بنزين salphonic acid حر ينام مش
+
+276
+00:24:44,120 --> 00:24:55,720
+مش مشكلة بنجي
+
+277
+00:24:55,720 --> 00:25:03,140
+لتفاعل إضافي كيف نحط R group طبعا بدي ال R تكون
+
+278
+00:25:04,620 --> 00:25:09,200
+بوزيتف أنا اتفقت هذه positive is a must لابد منها
+
+279
+00:25:09,200 --> 00:25:17,180
+لو جيبنا مثلًا CH3Cl اللي هي عبارة عن RCl مع
+
+280
+00:25:17,180 --> 00:25:20,860
+ألمنيوم كلوريد الالمنيوم كلوريد لاحظوا برضه
+
+281
+00:25:20,860 --> 00:25:26,690
+لويس اسيد لأنه كم كلور متصل فيه؟ تلاتة، إذا
+
+282
+00:25:26,690 --> 00:25:30,030
+الالمنيوم عادسة إلكترونات بده إلكترونات،
+
+283
+00:25:30,030 --> 00:25:35,690
+فالالمنيوم كلوريد بيسحب الكلورين مع إلكترونات
+
+284
+00:25:35,690 --> 00:25:39,810
+الرابطة على جهته، كل هذا الكلام بناشيه، أنا ايش
+
+285
+00:25:39,810 --> 00:25:45,030
+اللي بديه؟ إنه عمل polarization للجزء، خلال الـCH3
+
+286
+00:25:45,030 --> 00:25:49,150
+positive، خلال الـCH3 positive، هذا الـCH3
+
+287
+00:25:49,150 --> 00:25:54,150
+positive، هذا كله أنا؟ اتفقت؟ إنه مش مهم عندي المهم
+
+288
+00:25:54,150 --> 00:25:58,750
+إنه بقدر أخد ال CH3 positive عطول إذا أخدناها
+
+289
+00:25:58,750 --> 00:26:06,890
+التفاعل بيصير straightforward، تلقائي، واضح؟ إذا
+
+290
+00:26:06,890 --> 00:26:12,670
+ايش الشرط لإضافة ال L-Kilogram لما أنا بفعل RCL
+
+291
+00:26:12,670 --> 00:26:20,250
+ولا RX؟ وجود aluminium X3 عشان يسحب الـ X مع
+
+292
+00:26:20,250 --> 00:26:26,130
+إلكتروناتها و يسيب له الـ positive R واللي بدها
+
+293
+00:26:26,130 --> 00:26:31,510
+تتفاعل هي الـ positive R ممكن تكون CH3 ممكن تكون
+
+294
+00:26:31,510 --> 00:26:37,690
+إيثل ممكن تكون بروبيل المعادلة عامة يعني مش الزام بس
+
+295
+00:26:37,690 --> 00:26:43,390
+بالـCH3 لأ هي المعادلة بنقدر نعتبرها مع R المعادلة
+
+296
+00:26:43,390 --> 00:26:50,550
+نقدر نعتبرها مع R وبهيك بتتم عملية الـ alkylation
+
+297
+00:26:50,550 --> 00:26:58,470
+الـ alkylation اللي هو التفاعل مع الكيل جروب يعني
+
+298
+00:26:58,470 --> 00:27:01,970
+ألمنيوم بي ار ثري أو إش .. لأ هو المناسب و سعره
+
+299
+00:27:01,970 --> 00:27:05,970
+معقول يستعمل بهذا التفاعل ألمنيوم كلوريد ألمنيوم
+
+300
+00:27:05,970 --> 00:27:06,570
+كلوريد
+
+301
+00:27:13,620 --> 00:27:19,200
+الآن هنا احنا حاطين لكم بعض ال limitations اللي هو
+
+302
+00:27:19,200 --> 00:27:24,280
+محددات لـ Frédéric Raft's alkylation طبعا بيسموه
+
+303
+00:27:24,280 --> 00:27:28,060
+نسبة للعالم أو للعلماء Frédéric Raft هذي ال
+
+304
+00:27:28,060 --> 00:27:32,520
+alkylation شو بيسموها؟ Frédéric Raft's alkylation
+
+305
+00:27:32,520 --> 00:27:36,820
+على حسب الناس اللي اشتغلوا الشغل الآن في عندي بعض
+
+306
+00:27:36,820 --> 00:27:43,510
+المشاكل اللي ممكن بدنا نواجهها وهي أن التفاعل بتتم
+
+307
+00:27:43,510 --> 00:27:51,310
+مع الـ RCl بس ما بتتمش مع الـ ArCl ولا مع الـ
+
+308
+00:27:51,310 --> 00:27:56,790
+Vinyl Cl الـ Ar بمعنى أنه لو كان عندي حلقة بنزين
+
+309
+00:27:56,790 --> 00:28:00,870
+تانية فيها Cl هل يا ترى الـ الـ aluminium
+
+310
+00:28:00,870 --> 00:28:03,930
+chloride بياخد من البنزين التانية لكلورة و
+
+311
+00:28:03,930 --> 00:28:08,790
+بيسيبليها موجبة؟ لأ، لو كان عندي برضه vinyl
+
+312
+00:28:08,790 --> 00:28:14,070
+كلوريد الـ vinyl متذاكرينه؟ اه، يعني هنا الـ RCl
+
+313
+00:28:14,070 --> 00:28:22,170
+هي معروفة من R مثل، ايثل، بروبيل، ايش ما كان الـ ArCl
+
+314
+00:28:22,170 --> 00:28:28,050
+اللي هو aromatic يعني بنزين أو من جماعة البنزين
+
+315
+00:28:28,050 --> 00:28:34,370
+مشتقاته هنا ممكن أنه تفقد الـCl ويبقى عندي R
+
+316
+00:28:35,140 --> 00:28:39,300
+positive ما في عندي اي مشكلة هنا لأ ما بيصيرش
+
+317
+00:28:39,300 --> 00:28:45,960
+التفاعل واضح؟ و هنا Cl هل يا ترى يمكن أن تفقد من
+
+318
+00:28:45,960 --> 00:28:51,040
+هنا الـ Cl ويظل هذا positive لأ لأ ما بيصيرش إذا
+
+319
+00:28:51,040 --> 00:28:56,080
+التفاعل بس بيصير مع الالكايل هالايدز ما بيصيرش مع
+
+320
+00:28:56,080 --> 00:29:03,180
+الاريل هالايدز ولا بيصير مع الفينيل هالايدز
+
+321
+00:29:04,520 --> 00:29:12,700
+واضحة هذه النقطة هذه نقطة مهمة ال Rpg limitation
+
+322
+00:29:12,700 --> 00:29:19,060
+أو محدد تاني لهذا التفاعل بيعمل مشكلة إن حلقة
+
+323
+00:29:19,060 --> 00:29:25,280
+البنزين لو كان عليها بعض المجموعات المثبتة بنسميها
+
+324
+00:29:25,280 --> 00:29:31,520
+أو الساحبة للإلكترونات بيصير التفاعل بطيء تقريبا
+
+325
+00:29:31,520 --> 00:29:37,020
+ما بيمشيش والمجموعات يعني لو كان عليها مجموعة أصلا
+
+326
+00:29:37,020 --> 00:29:43,170
+وبيضيف كمان كل واضح؟ لو كان عليها أصلا مجموعة
+
+327
+00:29:43,170 --> 00:29:46,590
+وغير المجموعة بيضيف كمان كل اللي هنعود نتوسع
+
+328
+00:29:46,590 --> 00:29:50,030
+فيه هذه المجموعات اللي .. اللي لو كانت موجودة
+
+329
+00:29:50,030 --> 00:29:53,990
+أصلا على البنزين وبتثبت التفاعل ال Nitro،
+
+330
+00:29:53,990 --> 00:29:58,650
+السيانو، الـSO3H، الـCHO، الـCOR، الـCOH، الـC
+
+331
+00:29:58,650 --> 00:30:04,150
+double bond OR و الـNR3 هذه النقطة بالذات هنرجع لها
+
+332
+00:30:04,150 --> 00:30:09,540
+مرة ثانية إنه في مجموعات لو كانت أصلا موجودة على
+
+333
+00:30:09,540 --> 00:30:14,060
+الحلقة بتعمل deactivation، deactivation يعني بتثبت
+
+334
+00:30:14,060 --> 00:30:20,180
+الحلقة وبتبطل الحلقة تتفاعل، واضح؟ الشيء التاني إنه
+
+335
+00:30:20,180 --> 00:30:25,180
+لو ما كانش، بس كانت الكيل جروب و اجي اتفاعلت مع مثل
+
+336
+00:30:25,180 --> 00:30:29,640
+الكلوريد، ممكن التفاعل مش بس يحط مثل واحدة، ممكن
+
+337
+00:30:29,640 --> 00:30:34,590
+يحط اتنين أو تلاتة يعني يعمل multiple substitution
+
+338
+00:30:34,590 --> 00:30:39,550
+يعني يضيف أكثر من مجموعة في هذه الحالة كأنه بعد ما
+
+339
+00:30:39,550 --> 00:30:46,190
+يضيف اول مثل الحلقة ايش بتصير؟ Activated منشطة بحيث
+
+340
+00:30:46,190 --> 00:30:50,490
+انها تضيف المجموعة التانية والتالتة إذن كأنه هناخد
+
+341
+00:30:50,490 --> 00:30:55,270
+بعد شوية انه في ظاهرة اسمها activation حلقة منشطة
+
+342
+00:30:55,270 --> 00:31:00,290
+بدأت تتفاعل اكتر وفي deactivation في مجموعات بتعمل
+
+343
+00:31:00,290 --> 00:31:04,070
+activation بتشجع على المزيد من التفاعلات وفي
+
+344
+00:31:04,070 --> 00:31:09,170
+مجموعات بتعمل deactivation بتوقف التفاعلات واضح
+
+345
+00:31:09,170 --> 00:31:10,170
+هذا ال point؟
+
+346
+00:31:15,990 --> 00:31:21,450
+في عندنا كمان تفاعل اللي هو التفاعل مع الacetyl
+
+347
+00:31:21,450 --> 00:31:27,510
+groups انتوا مارة عليكم يمكن مجموعة ايش؟ الacetyl
+
+348
+00:31:27,510 --> 00:31:34,170
+اه متذكرين شو هي الacetyl؟ ال CH3C double bond اه
+
+349
+00:31:34,170 --> 00:31:42,270
+شو اسمها؟ Acetyl انتبهوا معايا في اسم عائلة وفي
+
+350
+00:31:42,270 --> 00:31:48,710
+اسم فرد دائما أسماء العائلات بنكون محددين شو
+
+351
+00:31:48,710 --> 00:31:54,080
+المجموعة اللي بنستخدمها R بنستخدم R يعني لو كنا
+
+352
+00:31:54,080 --> 00:32:00,820
+كاتببن احنا R C double bond O Cl هذه ال R C double
+
+353
+00:32:00,820 --> 00:32:05,740
+bond O اسمها Acyl group يمكن ال R فيها تكون مثل
+
+354
+00:32:05,740 --> 00:32:12,560
+ممكن ايثل ممكن بروبيل ممكن بيوتيل ايه ان كانت واضح؟
+
+355
+00:32:12,560 --> 00:32:16,960
+إذا هذه المجموعة العامة ال general group شو اسمها؟
+
+356
+00:32:17,540 --> 00:32:24,960
+Acyl group الـ A لو كانت حالة خاصة الـ R مثل ..
+
+357
+00:32:24,960 --> 00:32:33,860
+شو بيصير اسم المجموعة؟ Acetyl واضح الفكرة؟ فالـ
+
+358
+00:32:33,860 --> 00:32:39,920
+Acetyl هي مجموعة خاصة حددت فيها الـ R بأنها
+
+359
+00:32:42,590 --> 00:32:48,730
+واضح؟ فهذه اسيل وهذه استيل الاسيل المجموعة العامة
+
+360
+00:32:48,730 --> 00:32:53,330
+الآن احنا لما بندرس التفاعل بندرسه بشكل عام مع كل
+
+361
+00:32:53,330 --> 00:32:58,910
+انواع ال R ولذلك بنسمي التفاعل افريدي ل crafts
+
+362
+00:33:00,610 --> 00:33:05,170
+acetylation لو كنت بأقصد اني اخلي ال R مثل ممكن
+
+363
+00:33:05,170 --> 00:33:10,550
+أقول وجهتها Acetylation واضح؟ إذا ال Acetyl هي ال
+
+364
+00:33:10,550 --> 00:33:14,950
+general group اللي بنكتب فيها R ال Acetyl هي ال
+
+365
+00:33:14,950 --> 00:33:20,890
+specific group و ال R is CH3 على أي حال، هذا
+
+366
+00:33:20,890 --> 00:33:25,430
+التفاعل أيضًا بالزمن فيه positive كيف بجيب ال
+
+367
+00:33:25,430 --> 00:33:29,670
+positive؟ بجيب افاعل مثلًا كمثال الـ Acetachloride
+
+368
+00:33:29,670 --> 00:33:33,170
+مع الـ Aluminium Chloride الآن الـ Aluminium
+
+369
+00:33:33,170 --> 00:33:40,670
+Chloride بدي اخذ Cl مع إلكتروناتها، شو هيخليها
+
+370
+00:33:40,670 --> 00:33:45,050
+على الكربون اللي هي موجب؟ هذا الموجب طبعا ممكن
+
+371
+00:33:45,050 --> 00:33:49,490
+ينتقل بين الكربون والأكسجين يعني لو اتحرك زوج
+
+372
+00:33:49,490 --> 00:33:52,970
+إلكترونات من هنا يعني من الرابطة الثلاثية بيصير
+
+37
+
+401
+00:35:38,580 --> 00:35:42,000
+للهيدروجين هذا فقط القائمة هو وين بده يروح
+
+402
+00:35:42,000 --> 00:35:46,560
+الهيدروجين هذا اللي بده يفقد تنسوش أنه الهيدروجين
+
+403
+00:35:46,560 --> 00:35:51,700
+هذا لما بده يطلع بده يكون عنده Aluminium Cl3 مع Cl
+
+404
+00:35:51,700 --> 00:35:56,560
+إضافية minus  الـ H plus اللي بتطلع من هنا بدي أخد
+
+405
+00:35:56,560 --> 00:36:02,710
+الـ Cl minus لأقنعة Cl واضح؟ يعني الـ H plus اللي
+
+406
+00:36:02,710 --> 00:36:07,670
+بشجعه على الفقد موجود الـ Cl minus اللي ملتصقة
+
+407
+00:36:07,670 --> 00:36:11,250
+لحظيا في الالمنيوم الكلورايد فالـ Cl minus بتاخد
+
+408
+00:36:11,250 --> 00:36:15,930
+الـ H plus قبل الـ HCl شو رجع عنده؟ الومنيوم
+
+409
+00:36:15,930 --> 00:36:20,410
+الكلورايد، بعيد الدائرة، برجع عند الومنيوم
+
+410
+00:36:20,410 --> 00:36:29,070
+الكلورايد و بعيد الدائرة طيب الآن لو قلنا بدنا ننظر
+
+411
+00:36:29,070 --> 00:36:39,650
+لهذه الأمثلة ونقول لكم أكمل المعادلة لاحظوا
+
+412
+00:36:39,650 --> 00:36:46,370
+هذا التفاعل شو نوعه؟ Acetylation أو Acylation
+
+413
+00:36:46,370 --> 00:36:51,610
+الألومنيوم كلورايد بدي ياخد الـCl يصير عند ال
+
+414
+00:36:51,610 --> 00:36:57,310
+Electrophile شو النتيجة؟ تكوين الـ acetyl group،
+
+415
+00:36:57,310 --> 00:37:00,230
+لاحظوا بتكون مع عدد Cl، بس احنا دائما في ال
+
+416
+00:37:00,230 --> 00:37:04,290
+organic بنركز على ال organic product، يعني مرات
+
+417
+00:37:04,290 --> 00:37:07,330
+بنكتبش النواتج الثانية، أنا بهمني ال organic
+
+418
+00:37:07,330 --> 00:37:12,710
+product اسم
+
+419
+00:37:12,710 --> 00:37:16,360
+الشهير أسيتوفينون أخذناه المرة الماضية يعني كان
+
+420
+00:37:16,360 --> 00:37:23,760
+ممكن تسميته أسيت البنزين عادي بس طالما له اسم شهير
+
+421
+00:37:23,760 --> 00:37:27,620
+أشهر بدك تسميه أسيتوفينون بدك تسميه أسيتوفينون
+
+422
+00:37:27,620 --> 00:37:31,460
+واضح؟ بدك تسميه أسيتوفينون الآن لاحظوا في المرة
+
+423
+00:37:31,460 --> 00:37:36,060
+الثانية HNO3 وH2SO4 شوف كيف كتبت الـ agents بدقة
+
+424
+00:37:36,060 --> 00:37:40,760
+نيتريشن نيتريشن NO2 في المرة الثالثة
+
+425
+00:37:44,140 --> 00:37:47,300
+هالوجيناشن؟ بده يروح الالمنيوم الكلورايد، هذا
+
+426
+00:37:47,300 --> 00:37:51,880
+الكيلاشن، هذا مش هالوجيناشن، this reaction is
+
+427
+00:37:51,880 --> 00:37:56,020
+الكيلاشن، هذا ايزوبروبيل كلورايد، لما ييجي
+
+428
+00:37:56,020 --> 00:38:00,000
+الالمنيوم الكلورايد وياخد هذه الكلورين، وين هيسيب
+
+429
+00:38:00,000 --> 00:38:04,860
+له الـ positive؟ على الكاربون الوسطانية، محل ما
+
+430
+00:38:04,860 --> 00:38:07,040
+انشلت الـCl، محل ما بيتفاعل
+
+431
+00:38:09,680 --> 00:38:16,300
+محل ما انشالت الـ Cl محل ما بيتفاعل بالظبط واضح؟ طيب
+
+432
+00:38:16,300 --> 00:38:20,480
+خلينا ناخد أخر معادلة نكتبها بالقلم وننهي
+
+433
+00:38:20,480 --> 00:38:24,760
+المحاضرة اليوم لو اجينا فعلنا مش مع هذا
+
+434
+00:38:24,760 --> 00:38:29,220
+المركب لو اجينا عملنا كمان سهم وحطينا هذا
+
+435
+00:38:29,220 --> 00:38:35,400
+المركب في وجود H plus بروبين
+
+436
+00:38:45,690 --> 00:38:52,290
+شو بده يعمل هنا؟ لاحظوا هنا لما فقد من هذا المثال
+
+437
+00:38:52,290 --> 00:39:00,370
+الـCl، ايش صار عندي؟ CH2، CH موجبة، CH3 طيب، لما
+
+438
+00:39:00,370 --> 00:39:05,570
+أنا بحط و أخذناه في تفاعلات الإضافة للالكينز الكين
+
+439
+00:39:05,570 --> 00:39:11,390
+مع H Plus، ايش دائما و أبدا الخطوة الأولى؟ إضافة
+
+440
+00:39:11,390 --> 00:39:14,210
+الـH Plus على الـDouble bond وكسرها وتكوين
+
+441
+00:39:14,210 --> 00:39:21,180
+Carbocation إذاً، هدول الاثنين شو بيعملوا مع بعض؟ هي
+
+442
+00:39:21,180 --> 00:39:26,740
+الـ H ضافة هنا دي صارت CH3 وضّافة على الـ Bromine
+
+443
+00:39:26,740 --> 00:39:30,100
+والكربوكاتيون اتكون هنا نفس الكربوكاتيون اللي هنا
+
+444
+00:39:30,100 --> 00:39:37,660
+ولا لأ؟ نفسه نفس الاتكون هنا ممكن نكونه من خلال
+
+445
+00:39:37,660 --> 00:39:41,980
+تفاعل البروبين مع الـ H Plus صار نفس الكربوكاتيون
+
+446
+00:39:41,980 --> 00:39:47,400
+بكم اللي بيعطيني نفس النتيجة إذاً، هذا المركب
+
+447
+00:39:47,400 --> 00:39:52,240
+اللي أنتو شايفينه الآن بقدر أحضره بأكثر من طريقة
+
+448
+00:39:52,240 --> 00:39:56,980
+ممكن أخد Iso-Propyl chloride مع Aluminium chloride
+
+449
+00:39:56,980 --> 00:40:02,660
+بيعطوني Iso-Propyl-Cation وممكن أخد بروبين مع H
+
+450
+00:40:02,660 --> 00:40:06,760
+Plus بيعطوني برضه Iso-Propyl-Cation، نفس الـCation
+
+451
+00:40:06,760 --> 00:40:10,740
+إذاً التفاعل هيكمل لنفس الناتج
+
+452
+00:40:12,310 --> 00:40:16,830
+التفاعل هيكمل لنفس الناتج، لو أخدت reaction of
+
+453
+00:40:16,830 --> 00:40:21,210
+benzene with isopropyl chloride in presence of
+
+454
+00:40:21,210 --> 00:40:24,930
+aluminium chloride or reaction of benzene with
+
+455
+00:40:24,930 --> 00:40:29,370
+propene in presence of H plus produces سميليا، شو
+
+456
+00:40:29,370 --> 00:40:35,150
+اسم المركب؟ أنت رافع يدك، كنت بدك تجاوبي، شو اسمه
+
+457
+00:40:35,150 --> 00:40:37,610
+بس، احنا خلينا في اسمه؟
+
+458
+00:40:41,960 --> 00:40:47,620
+وأنا حد فيكم أفطر حمص عليه كمون؟ كايومين الـ
+
+459
+00:40:47,620 --> 00:40:56,940
+isopropyl بنزين له اسم شهير أخذناه كايومين كايومين
+
+460
+00:40:56,940 --> 00:41:00,120
+اسم الشهرة تبع الـ isopropyl بنزين اتفضل أسألك
+
+461
+00:41:00,120 --> 00:41:08,940
+عشانك
+
+462
+00:41:08,940 --> 00:41:13,700
+غيبتي جابلها بحصة ما غيبتيش؟ إذا نتذكر معه .. إذا
+
+463
+00:41:13,700 --> 00:41:17,160
+نتذكر معه لما باطيفه على الطرف شو نوع الـ
+
+464
+00:41:17,160 --> 00:41:23,280
+carbocation اللي بتكونه؟ secondary carbocation ..
+
+465
+00:41:23,280 --> 00:41:27,140
+مظبوط ولا لأ؟ ولو تفتح هنا شو نوع الـ carbocation
+
+466
+00:41:27,140 --> 00:41:39,450
+اللي بتكونه؟ برايمري كاربوكاتايون نختبر
+
+467
+00:41:39,450 --> 00:41:44,170
+ذكائكم ونعطيكم سؤال هوم ورك للحصة القادمة
+
+468
+00:41:47,150 --> 00:41:52,230
+انتبهوا هذا الكلام أنا متأكد أن الطالبات الممتازات
+
+469
+00:41:52,230 --> 00:41:55,370
+بالبسيطة على هيك أسئلة أنا متأكد أن الطالبات
+
+470
+00:41:55,370 --> 00:41:59,850
+الممتازات بالبسيطة على هيك أسئلة الآن لو جبنالكوا
+
+471
+00:41:59,850 --> 00:42:05,690
+في أكمل المعادلة هذا المركب CH2 double bond CH
+
+472
+00:42:05,690 --> 00:42:16,400
+حطينا هنا C وحطينا H وCH3 وCH3 وقلنا في وجود اتش
+
+473
+00:42:16,400 --> 00:42:24,020
+بلاس وهدول موجودين في اتش بلاس مع البنزين ايش بده
+
+474
+00:42:24,020 --> 00:42:29,160
+يكون النتيجة؟
+
+475
+00:42:29,160 --> 00:42:34,840
+عشان
+
+476
+00:42:34,840 --> 00:42:38,260
+انتوا بس تكتبوا صحيح، بناعطيكم الفكرة الفكرة كلمة
+
+477
+00:42:38,260 --> 00:42:41,100
+واللي بتقولي الكلمة هعطيها علامة على طول هالجيتها
+
+478
+00:42:41,100 --> 00:42:43,680
+هتنزلها على كشف الدرجات ايش الفكرة اللي في هذا
+
+479
+00:42:43,680 --> 00:42:48,070
+السؤال؟ في الرابط اللي .. ماجبتوش الفكرة اللي
+
+480
+00:42:48,070 --> 00:42:52,730
+بتاخدوا عليها علامة علامة هذه مش ببلاش ايش الفكرة
+
+481
+00:42:52,730 --> 00:42:57,210
+اللي بهدي السؤال ان الحديث في الرابط اللي مش هائل
+
+482
+00:42:57,210 --> 00:43:10,230
+نلعب في البنزينة فكرة
+
+483
+00:43:10,230 --> 00:43:11,090
+أخدناها
+
+484
+00:43:14,650 --> 00:43:22,890
+لأ لأ لأ لاتش بلس حطي فارقة خلصنا من هالموضوع أنا 
+
+485
+00:43:22,890 --> 00:43:26,750
+مش راضي أجاوبها احذروا ليش مش راضي أجاوبها لأنه
+
+486
+00:43:26,750 --> 00:43:29,410
+إذا جوابت أقول لكم هتزعلوا إنكم ضيعتوا أحكاركم
+
+487
+00:43:29,410 --> 00:43:35,090
+علامة هتزعلوا
+
+488
+00:43:36,060 --> 00:43:40,100
+مش مشكلة لأنه بعد هيك هيصير Rearrangement أول ما
+
+489
+00:43:40,100 --> 00:43:44,420
+أضيف الـ H plus هنا الكاربوكاتيون هنا secondary
+
+490
+00:43:44,420 --> 00:43:49,020
+مباشرة هيصير Hydride shift هيصير الكاربوكاتيون
+
+491
+00:43:49,020 --> 00:43:57,570
+هنا وهذه هتشبك من هنا مش من هنا واضح الفكرة؟ بيصير
+
+492
+00:43:57,570 --> 00:44:00,850
+Rearrangement الكلمة اللي كنت بدي أسمعها منكم
+
+493
+00:44:00,850 --> 00:44:04,850
+كلمة Rearrangement أنه أنا ضفت الـ H plus هنا وين
+
+494
+00:44:04,850 --> 00:44:10,370
+صار الـ carbocation؟ secondary في إمكانية تتحرك الـ
+
+495
+00:44:10,370 --> 00:44:15,970
+H هذه ويصير الـ carbocation tertiary ومحل ما صار الـ
+
+496
+00:44:15,970 --> 00:44:21,940
+carbocation tertiary بيكون عندي ايش؟ محل ما صار
+
+497
+00:44:21,940 --> 00:44:25,920
+الكربوكاتيون الـ tertiary بصير التفاعل، إذا هنا
+
+498
+00:44:25,920 --> 00:44:32,160
+صارت فكرة الـ Rearrangement في حالة الـ Alkyl
+
+499
+00:44:32,160 --> 00:44:35,740
+Halides بالمناسبة عاد الـ rearrangements هذه اللي
+
+500
+00:44:35,740 --> 00:44:38,980
+برضه هنا لو كنتوا بتفقدوا كلور مش ضروري من خلال
+
+501
+00:44:38,980 --> 00:44:43,880
+الالكين وعملة secondary وبإمكانه يتحول إلى
+
+502
+00:44:43,880 --> 00:44:48,760
+tertiary برضه بيصير Rearrangement بمعنى لو كان هذا
+
+503
+00:44:48,760 --> 00:44:56,460
+المركب زيك CH2 CH3 خليني أقول وهذه CHCl وهنا COH
+
+504
+00:44:56,460 --> 00:45:05,400
+و CH3 و CH3 وحطينا هنا الومنيوم كلورايد الومنيوم
+
+505
+00:45:05,400 --> 00:45:09,480
+كلورايد شو بدي أعمل؟ هيسحب السيارة ليكوّل السكاندر
+
+506
+00:45:09,480 --> 00:45:15,160
+كاربوكاتايون هذا بيعمل الـ arrangement والنتيجة أن
+
+507
+00:45:15,160 --> 00:45:20,540
+التفاعل لا يتم مكان الكلور إنما يتم هنا هذه الجملة
+
+508
+00:45:20,540 --> 00:45:23,840
+اللي قبل شوية أنا مشيت عليها بسرعة إذا بتتذكروا
+
+509
+00:45:23,840 --> 00:45:27,740
+هنا آخر كلمة ايش كان مكتوب عندكم
+
+510
+00:45:32,500 --> 00:45:38,820
+أنه في الـ alkylation لما بتكون carbocation وبده
+
+511
+00:45:38,820 --> 00:45:44,960
+يتفاعل لو صاحله أحسن وضعه بيحسن ولا لأ؟ لو صاحله
+
+512
+00:45:44,960 --> 00:45:48,900
+يعمل Rearrangement بيعمل ولا لأ؟ شكرا 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..91b4781baeeabe2442d9a26892b23698e160402b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_raw.json
@@ -0,0 +1 @@
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7780, "start": 48.68, "end": 77.8, "text": "لما نقول الـ Alkenes، شو تفاعلاتهم؟ بكلمة واحدة، بدو يكون الكلام بشكل أساسي Substitution Free Radical Substitution، مظبوط ولا لا؟ رغم أنه بشكل عام inert لكن لما بيعملوا Free Radical Substitution أو الـ Thermolysis والتكسر بالحرارة الآن، لو جينا على الـ Alkenes تفاعلهم الـ Addition", "tokens": [1211, 15042, 8717, 39648, 2423, 39184, 967, 2653, 279, 12399, 13412, 2407, 6055, 5172, 995, 30241, 9307, 16095, 22807, 4724, 4117, 19528, 3660, 36764, 24401, 3660, 12399, 47525, 2407, 7251, 30544, 2423, 28820, 10943, 4724, 8592, 28820, 5551, 3794, 32277, 1829, 42090, 6518, 11551, 9654, 804, 42090, 6518, 12399, 3714, 19913, 3555, 2407, 9566, 49429, 20193, 22807, 12602, 17082, 2304, 14739, 3224, 4724, 8592, 28820, 6225, 10943, 25832, 44381, 5296, 15042, 4724, 1829, 25957, 1211, 14407, 11551, 9654, 804, 42090, 6518, 34051, 2423, 39184, 38957, 16453, 17122, 16070, 2655, 4117, 3794, 2288, 20666, 5016, 2288, 9640, 3660, 6024, 48506, 12399, 45164, 10874, 1829, 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ال الكينز ايش اللى كنا نبدأ فيه التفاعل موجب ولا سالب اللى بيجي وبيهاجم ال الكينز موجب اتش بلس اذا نوع ال addition اللى على ال الكينز electrophilic addition", "tokens": [6027, 7649, 45164, 8608, 10721, 1211, 8315, 1975, 1829, 8592, 8717, 45367, 2423, 4500, 13672, 7578, 39894, 39237, 15844, 2423, 2423, 4117, 9957, 11622, 1975, 1829, 8592, 13672, 7578, 9122, 8315, 8717, 44510, 10721, 8978, 3224, 16712, 5172, 995, 30241, 3714, 29245, 3555, 49429, 8608, 6027, 3555, 13672, 7578, 4724, 1829, 7435, 1829, 4032, 21292, 3224, 26108, 2304, 2423, 2423, 4117, 9957, 11622, 3714, 29245, 3555, 1975, 2655, 8592, 4724, 1211, 3794, 1975, 15730, 8717, 45367, 2423, 4500, 13672, 7578, 15844, 2423, 2423, 4117, 9957, 11622, 2185, 11741, 388, 299, 4500], "avg_logprob": -0.19633152109125387, "compression_ratio": 1.9028571428571428, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 78.75, "end": 79.33, "word": "الان", "probability": 0.789794921875}, {"start": 79.33, "end": 79.69, "word": " لو", 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"word": " undergo", "probability": 0.84765625}, {"start": 133.9, "end": 134.44, "word": " a", "probability": 0.51611328125}, {"start": 134.44, "end": 135.62, "word": " eucleophilic", "probability": 0.8159993489583334}, {"start": 135.62, "end": 136.28, "word": " addition", "probability": 0.9658203125}, {"start": 136.28, "end": 137.02, "word": " in", "probability": 0.9521484375}, {"start": 137.02, "end": 137.48, "word": " general", "probability": 0.927734375}], "temperature": 1.0}, {"id": 7, "seek": 15868, "start": 138.24, "end": 158.68, "text": "الجواب غلط التفاعل الأساسي Electrophilic addition هي إلكترونيات بجهة Electrophile موجة، واضح؟ الآن الـ aromatic compounds، إيه التفاعل الأساسي؟ والله إذا الـalkenes فيهم double bond واحدة", "tokens": [6027, 7435, 14407, 3555, 32771, 1211, 9566, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 12575, 11741, 388, 299, 4500, 39896, 11933, 23275, 2655, 2288, 11536, 1829, 9307, 4724, 7435, 3224, 3660, 12575, 11741, 794, 3714, 29245, 3660, 12399, 4032, 46958, 5016, 22807, 6024, 48506, 2423, 39184, 45831, 21810, 12399, 11933, 1829, 3224, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 22807, 16070, 43761, 11933, 15730, 2423, 39184, 667, 25973, 8978, 16095, 3834, 6086, 36764, 24401, 3660], "avg_logprob": -0.2572115495418891, "compression_ratio": 1.4764397905759161, "no_speech_prob": 6.556510925292969e-07, "words": [{"start": 138.24, "end": 138.96, "word": "الجواب", "probability": 0.9542236328125}, {"start": 138.96, "end": 139.32, "word": " غلط", "probability": 0.96337890625}, {"start": 139.32, "end": 140.56, "word": " التفاعل", "probability": 0.651885986328125}, {"start": 140.56, "end": 141.22, "word": " الأساسي", "probability": 0.966796875}, {"start": 141.22, "end": 142.18, "word": " Electrophilic", "probability": 0.7705078125}, {"start": 142.18, "end": 142.64, "word": " addition", "probability": 0.78759765625}, {"start": 142.64, "end": 142.92, "word": " هي", "probability": 0.61767578125}, {"start": 142.92, "end": 144.0, "word": " إلكترونيات", "probability": 0.8143833705357143}, {"start": 144.0, "end": 145.0, "word": " بجهة", "probability": 0.9537353515625}, {"start": 145.0, "end": 146.68, "word": " Electrophile", "probability": 0.7444661458333334}, {"start": 146.68, "end": 147.52, "word": " موجة،", "probability": 0.719818115234375}, {"start": 147.52, "end": 148.68, "word": " واضح؟", "probability": 0.8839111328125}, {"start": 148.68, "end": 149.26, "word": " الآن", "probability": 0.705810546875}, {"start": 149.26, "end": 150.38, "word": " الـ", "probability": 0.705810546875}, {"start": 150.38, "end": 150.8, "word": " aromatic", "probability": 0.60546875}, {"start": 150.8, "end": 152.0, "word": " compounds،", "probability": 0.7015380859375}, {"start": 152.0, "end": 152.1, "word": " إيه", "probability": 0.6474609375}, {"start": 152.1, "end": 152.6, "word": " التفاعل", "probability": 0.9266357421875}, {"start": 152.6, "end": 154.6, "word": " الأساسي؟", "probability": 0.97666015625}, {"start": 154.6, "end": 155.0, "word": " والله", "probability": 0.7734375}, {"start": 155.0, "end": 155.22, "word": " إذا", "probability": 0.955810546875}, {"start": 155.22, "end": 156.18, "word": " الـalkenes", "probability": 0.536590576171875}, {"start": 156.18, "end": 157.12, "word": " فيهم", "probability": 0.95166015625}, {"start": 157.12, "end": 157.46, "word": " double", "probability": 0.71630859375}, {"start": 157.46, "end": 157.96, "word": " bond", "probability": 0.9111328125}, {"start": 157.96, "end": 158.68, "word": " واحدة", "probability": 0.9723307291666666}], "temperature": 1.0}, {"id": 8, "seek": 18402, "start": 160.32, "end": 184.02, "text": "البنزين فيه تلاتة اللي عاملين resonance يعني اللي بدو ييجي يهاجم على البنزين كأنه بيهاجم على حقل من الإلكترونات كأنه بيهاجم على سحابة إلكترونية الآن اللي بدو ييجي يهاجم على سحابة إلكترونية إيش شرطه؟ إنه بدو يكون .. هذه البنزين .. بدو يكون موجة", "tokens": [6027, 3555, 1863, 11622, 9957, 8978, 3224, 6055, 1211, 9307, 3660, 13672, 1829, 6225, 10943, 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"probability": 0.861328125}, {"start": 162.12, "end": 162.7, "word": " تلاتة", "probability": 0.9154052734375}, {"start": 162.7, "end": 163.18, "word": " اللي", "probability": 0.921630859375}, {"start": 163.18, "end": 163.56, "word": " عاملين", "probability": 0.9610595703125}, {"start": 163.56, "end": 164.08, "word": " resonance", "probability": 0.87255859375}, {"start": 164.08, "end": 165.62, "word": " يعني", "probability": 0.79736328125}, {"start": 165.62, "end": 166.16, "word": " اللي", "probability": 0.961181640625}, {"start": 166.16, "end": 166.7, "word": " بدو", "probability": 0.4515380859375}, {"start": 166.7, "end": 166.94, "word": " ييجي", "probability": 0.9102783203125}, {"start": 166.94, "end": 167.46, "word": " يهاجم", "probability": 0.93896484375}, {"start": 167.46, "end": 167.7, "word": " على", "probability": 0.78857421875}, {"start": 167.7, "end": 168.26, "word": " البنزين", "probability": 0.986083984375}, {"start": 168.26, "end": 168.74, "word": " كأنه", "probability": 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182.08, "end": 182.32, "word": " هذه", "probability": 0.290771484375}, {"start": 182.32, "end": 182.94, "word": " البنزين", "probability": 0.984619140625}, {"start": 182.94, "end": 183.1, "word": " ..", "probability": 0.501953125}, {"start": 183.1, "end": 183.34, "word": " بدو", "probability": 0.93212890625}, {"start": 183.34, "end": 183.56, "word": " يكون", "probability": 0.9912109375}, {"start": 183.56, "end": 184.02, "word": " موجة", "probability": 0.8600260416666666}], "temperature": 1.0}, {"id": 9, "seek": 19775, "start": 185.25, "end": 197.75, "text": "واضح بيكون موجب اللي بيهاجم على البنزين على سحابة إلكترونية كبيرة بيكون موجب وعشان هيك المسمى التفاعل electrophilic aromatic", "tokens": [2407, 46958, 5016, 4724, 1829, 30544, 3714, 29245, 3555, 13672, 1829, 4724, 1829, 3224, 26108, 2304, 15844, 29739, 1863, 11622, 9957, 15844, 8608, 5016, 16758, 3660, 11933, 23275, 2655, 2288, 11536, 10632, 9122, 3555, 48923, 4724, 1829, 30544, 3714, 29245, 3555, 4032, 3615, 8592, 7649, 39896, 4117, 9673, 38251, 7578, 16712, 5172, 995, 30241, 7072, 5317, 388, 299, 45831], "avg_logprob": -0.17278646007180215, "compression_ratio": 1.4513888888888888, "no_speech_prob": 2.3245811462402344e-06, "words": [{"start": 185.25, "end": 185.77, "word": "واضح", "probability": 0.9309895833333334}, {"start": 185.77, "end": 186.41, "word": " بيكون", "probability": 0.6200358072916666}, {"start": 186.41, "end": 187.15, "word": " موجب", "probability": 0.8665364583333334}, {"start": 187.15, "end": 187.77, "word": " اللي", "probability": 0.6666259765625}, {"start": 187.77, "end": 188.41, "word": " بيهاجم", "probability": 0.90712890625}, {"start": 188.41, "end": 188.61, "word": " على", "probability": 0.74169921875}, {"start": 188.61, "end": 189.37, "word": " البنزين", "probability": 0.9630126953125}, {"start": 189.37, "end": 190.13, "word": " على", "probability": 0.6123046875}, {"start": 190.13, "end": 190.93, "word": " سحابة", "probability": 0.9456787109375}, {"start": 190.93, "end": 191.55, "word": " إلكترونية", "probability": 0.8998209635416666}, {"start": 191.55, "end": 191.81, "word": " كبيرة", "probability": 0.9622395833333334}, {"start": 191.81, "end": 192.17, "word": " بيكون", "probability": 0.8888346354166666}, {"start": 192.17, "end": 192.51, "word": " موجب", "probability": 0.9793294270833334}, {"start": 192.51, "end": 193.15, "word": " وعشان", "probability": 0.8155517578125}, {"start": 193.15, "end": 193.43, "word": " هيك", "probability": 0.80126953125}, {"start": 193.43, "end": 194.45, "word": " المسمى", "probability": 0.8680013020833334}, {"start": 194.45, "end": 195.19, "word": " التفاعل", "probability": 0.938720703125}, {"start": 195.19, "end": 197.05, "word": " electrophilic", "probability": 0.767364501953125}, {"start": 197.05, "end": 197.75, "word": " aromatic", "probability": 0.87158203125}], "temperature": 1.0}, {"id": 10, "seek": 21762, "start": 198.82, "end": 217.62, "text": "substitution هنا بيجينا اختلاف أساسي وجوهري كبير كبير ما بين ال alkenes وما بين ال aromatic compounds ال alkenes كانوا عبارة عن double bond وال double bond إيش نقول عنها؟ بتكسر", "tokens": [30131, 372, 6518, 34105, 4724, 1829, 7435, 1829, 8315, 1975, 46456, 15040, 5172, 5551, 3794, 32277, 1829, 49610, 2407, 3224, 16572, 9122, 3555, 13546, 9122, 3555, 13546, 19446, 49374, 2423, 419, 2653, 279, 4032, 15042, 49374, 2423, 45831, 21810, 2423, 419, 2653, 279, 25961, 14407, 6225, 3555, 9640, 3660, 18871, 3834, 6086, 16070, 3834, 6086, 11933, 1829, 8592, 8717, 39648, 18871, 11296, 22807, 39894, 4117, 3794, 2288], "avg_logprob": -0.18589154499418595, "compression_ratio": 1.5146198830409356, "no_speech_prob": 9.059906005859375e-06, "words": [{"start": 198.82, "end": 199.9, "word": "substitution", "probability": 0.801513671875}, {"start": 199.9, "end": 200.76, "word": " هنا", "probability": 0.24169921875}, {"start": 200.76, "end": 201.42, "word": " بيجينا", "probability": 0.8978515625}, {"start": 201.42, "end": 202.46, "word": " اختلاف", "probability": 0.943359375}, 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210.6, "word": " compounds", "probability": 0.9013671875}, {"start": 210.6, "end": 211.22, "word": " ال", "probability": 0.88818359375}, {"start": 211.22, "end": 211.84, "word": " alkenes", "probability": 0.7975260416666666}, {"start": 211.84, "end": 212.16, "word": " كانوا", "probability": 0.837158203125}, {"start": 212.16, "end": 212.46, "word": " عبارة", "probability": 0.9935302734375}, {"start": 212.46, "end": 212.66, "word": " عن", "probability": 0.98046875}, {"start": 212.66, "end": 212.94, "word": " double", "probability": 0.91650390625}, {"start": 212.94, "end": 213.3, "word": " bond", "probability": 0.919921875}, {"start": 213.3, "end": 213.48, "word": " وال", "probability": 0.480224609375}, {"start": 213.48, "end": 213.76, "word": " double", "probability": 0.9208984375}, {"start": 213.76, "end": 214.08, "word": " bond", "probability": 0.94140625}, {"start": 214.08, "end": 214.36, "word": " إيش", "probability": 0.7661946614583334}, {"start": 214.36, "end": 214.7, "word": " 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{"start": 357.34, "end": 357.98, "word": " شيلت", "probability": 0.70458984375}, {"start": 357.98, "end": 358.36, "word": " H", "probability": 0.892578125}, {"start": 358.36, "end": 359.18, "word": " حطيت", "probability": 0.8468424479166666}, {"start": 359.18, "end": 359.64, "word": " X", "probability": 0.97021484375}, {"start": 359.64, "end": 360.02, "word": " أيا", "probability": 0.558349609375}, {"start": 360.02, "end": 360.54, "word": " كانت", "probability": 0.97412109375}, {"start": 360.54, "end": 360.68, "word": " هال", "probability": 0.691162109375}, {"start": 360.68, "end": 360.92, "word": " X", "probability": 0.83837890625}, {"start": 360.92, "end": 361.36, "word": " هذا", "probability": 0.499267578125}, {"start": 361.36, "end": 361.82, "word": " التفاعل", "probability": 0.930419921875}, {"start": 361.82, "end": 362.0, "word": " إيش", "probability": 0.9313151041666666}, {"start": 362.0, "end": 362.46, "word": " يعتبر", "probability": 0.85693359375}, {"start": 362.46, "end": 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"end": 376.01, "word": " Electrophilic", "probability": 0.7294921875}, {"start": 376.01, "end": 376.83, "word": " Substitution", "probability": 0.7142333984375}, {"start": 376.83, "end": 377.51, "word": " بديكوا", "probability": 0.6795654296875}, {"start": 377.51, "end": 378.07, "word": " تتعودوا", "probability": 0.975}, {"start": 378.07, "end": 378.73, "word": " تحطوا", "probability": 0.7781982421875}, {"start": 378.73, "end": 379.17, "word": " الكلام", "probability": 0.8561197916666666}, {"start": 379.17, "end": 379.85, "word": " بالظبط", "probability": 0.996337890625}, {"start": 379.85, "end": 381.41, "word": " لأنه", "probability": 0.6204427083333334}, {"start": 381.41, "end": 381.61, "word": " أنا", "probability": 0.62744140625}, {"start": 381.61, "end": 381.93, "word": " برضه", "probability": 0.9765625}, {"start": 381.93, "end": 382.11, "word": " لما", "probability": 0.951416015625}, {"start": 382.11, "end": 382.35, "word": " بدي", "probability": 0.6483154296875}, {"start": 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"probability": 0.8798828125}, {"start": 574.7, "end": 575.26, "word": " الأشياء", "probability": 0.9869384765625}, {"start": 575.26, "end": 575.42, "word": " من", "probability": 0.99560546875}, {"start": 575.42, "end": 576.12, "word": " طرفها", "probability": 0.9933268229166666}, {"start": 576.12, "end": 576.64, "word": " يعني", "probability": 0.84375}, {"start": 576.64, "end": 576.84, "word": " لما", "probability": 0.943115234375}, {"start": 576.84, "end": 577.12, "word": " كنا", "probability": 0.994140625}, {"start": 577.12, "end": 577.54, "word": " زمان", "probability": 0.97900390625}, {"start": 577.54, "end": 578.02, "word": " نفعل", "probability": 0.9729817708333334}, {"start": 578.02, "end": 578.46, "word": " ال", "probability": 0.8876953125}, {"start": 578.46, "end": 578.74, "word": " cane", "probability": 0.66162109375}, {"start": 578.74, "end": 579.02, "word": " مع", "probability": 0.951171875}, {"start": 579.02, "end": 579.26, "word": " ال", "probability": 0.83251953125}, {"start": 579.26, "end": 580.14, "word": " bromine", "probability": 0.9111328125}, {"start": 580.14, "end": 581.86, "word": " كنا", "probability": 0.771728515625}, {"start": 581.86, "end": 582.18, "word": " نقول", "probability": 0.914794921875}, {"start": 582.18, "end": 582.82, "word": " ال", "probability": 0.93212890625}, {"start": 582.82, "end": 583.32, "word": " cane", "probability": 0.9716796875}, {"start": 583.32, "end": 583.66, "word": " مع", "probability": 0.9921875}, {"start": 583.66, "end": 583.86, "word": " ال", "probability": 0.93310546875}, {"start": 583.86, "end": 584.32, "word": " bromine", "probability": 0.990478515625}, {"start": 584.32, "end": 584.7, "word": " نكتب", "probability": 0.9661865234375}, {"start": 584.7, "end": 584.84, "word": " ع", "probability": 0.66162109375}, {"start": 584.84, "end": 585.26, "word": " ساموش", "probability": 0.7657470703125}, {"start": 585.26, "end": 585.38, "word": " و", "probability": 0.5556640625}, {"start": 585.38, "end": 585.64, "word": " بعدين", "probability": 0.927490234375}, {"start": 585.64, "end": 585.98, "word": " نحط", "probability": 0.94775390625}, {"start": 585.98, "end": 586.4, "word": " تحت", "probability": 0.9912109375}, {"start": 586.4, "end": 587.94, "word": " عشان", "probability": 0.9449869791666666}, {"start": 587.94, "end": 588.22, "word": " يمشي", "probability": 0.993408203125}, {"start": 588.22, "end": 588.86, "word": " التفاعل", "probability": 0.958740234375}, {"start": 588.86, "end": 589.66, "word": " heat", "probability": 0.8408203125}, {"start": 589.66, "end": 590.58, "word": " or", "probability": 0.75634765625}, {"start": 590.58, "end": 591.12, "word": " light", "probability": 0.88818359375}, {"start": 591.12, "end": 592.5, "word": " ضوء", "probability": 0.8468424479166666}, {"start": 592.5, "end": 592.68, "word": " أو", "probability": 0.56396484375}, {"start": 592.68, "end": 593.36, "word": " حرارة", "probability": 0.9962158203125}, {"start": 593.36, "end": 594.46, "word": " واضح؟", "probability": 0.8458251953125}, {"start": 594.46, "end": 594.86, "word": " الآن", "probability": 0.758544921875}, {"start": 594.86, "end": 595.52, "word": " هنا", "probability": 0.701171875}, {"start": 595.52, "end": 595.82, "word": " مع", "probability": 0.98828125}, {"start": 595.82, "end": 596.64, "word": " البنزين", "probability": 0.9757080078125}, {"start": 596.64, "end": 597.1, "word": " لو", "probability": 0.89794921875}, {"start": 597.1, "end": 597.62, "word": " عملنا", "probability": 0.8180338541666666}, {"start": 597.62, "end": 598.56, "word": " bromine", "probability": 0.9677734375}], "temperature": 1.0}, {"id": 28, "seek": 61754, "start": 599.62, "end": 617.54, "text": "وكتبنا heat or light ما بصيرش تفاعل لازم البرومين يكون معه مركب FeBr3 او ممكن يكون aluminum Br3 او aluminum Cr3 بمشي خلاني اقول انسب اشهر ال FeBr3", "tokens": [2407, 4117, 2655, 3555, 8315, 3738, 420, 1442, 19446, 4724, 9381, 13546, 8592, 6055, 5172, 995, 30241, 5296, 31377, 2304, 2423, 26890, 20498, 9957, 7251, 30544, 20449, 3224, 3714, 31747, 3555, 3697, 22170, 18, 1975, 2407, 3714, 43020, 7251, 30544, 15656, 1603, 18, 1975, 2407, 15656, 4779, 18, 4724, 2304, 8592, 1829, 16490, 1211, 7649, 1829, 1975, 39648, 16472, 35457, 1975, 8592, 3224, 2288, 2423, 3697, 22170, 18], "avg_logprob": -0.2912137594775877, "compression_ratio": 1.4050632911392404, "no_speech_prob": 5.960464477539062e-07, "words": [{"start": 599.62, "end": 600.38, "word": "وكتبنا", "probability": 0.71884765625}, {"start": 600.38, "end": 600.6, "word": " heat", "probability": 0.76953125}, {"start": 600.6, "end": 600.92, "word": " or", "probability": 0.923828125}, {"start": 600.92, "end": 601.24, "word": " light", "probability": 0.88330078125}, {"start": 601.24, "end": 601.38, "word": " ما", "probability": 0.2406005859375}, {"start": 601.38, "end": 601.9, "word": " بصيرش", "probability": 0.6373291015625}, {"start": 601.9, "end": 602.56, "word": " تفاعل", "probability": 0.9285888671875}, {"start": 602.56, "end": 604.7, "word": " لازم", "probability": 0.9501953125}, {"start": 604.7, "end": 605.56, "word": " البرومين", "probability": 0.892333984375}, {"start": 605.56, "end": 606.32, "word": " يكون", "probability": 0.9794921875}, {"start": 606.32, "end": 606.88, "word": " معه", "probability": 0.910400390625}, {"start": 606.88, "end": 607.92, "word": " مركب", "probability": 0.802734375}, {"start": 607.92, "end": 609.7, "word": " FeBr3", "probability": 0.7349446614583334}, {"start": 609.7, "end": 610.52, "word": " او", "probability": 0.74365234375}, {"start": 610.52, "end": 611.1, "word": " ممكن", "probability": 0.91455078125}, {"start": 611.1, "end": 611.4, "word": " يكون", "probability": 0.923583984375}, {"start": 611.4, "end": 611.86, "word": " aluminum", "probability": 0.2291259765625}, {"start": 611.86, "end": 612.62, "word": " Br3", "probability": 0.791259765625}, {"start": 612.62, "end": 612.78, "word": " او", "probability": 0.857666015625}, {"start": 612.78, "end": 613.12, "word": " aluminum", "probability": 0.79541015625}, {"start": 613.12, "end": 613.66, "word": " Cr3", "probability": 0.805908203125}, {"start": 613.66, "end": 614.16, "word": " بمشي", "probability": 0.8529052734375}, {"start": 614.16, "end": 614.76, "word": " خلاني", "probability": 0.71484375}, {"start": 614.76, "end": 614.96, "word": " اقول", "probability": 0.74365234375}, {"start": 614.96, "end": 615.4, "word": " انسب", "probability": 0.64892578125}, {"start": 615.4, "end": 616.1, "word": " اشهر", "probability": 0.72021484375}, {"start": 616.1, "end": 616.3, "word": " ال", "probability": 0.497314453125}, {"start": 616.3, "end": 617.54, "word": " FeBr3", "probability": 0.8518880208333334}], "temperature": 1.0}, {"id": 29, "seek": 63886, "start": 618.1, "end": 638.86, "text": "واضح؟ هدولا الماديتين إشي بيعملوا مع بعض، بتيجوا تتطلعوا تتذكرولي البرومين نفسه جزء من ذاتين بروم زي بعض، هاي و ها نتخيل، هاي بروم و هاي بروم، يتورى البرومين نفسه كجزء، بيكون قطبي ولا غير قطبي؟", "tokens": [2407, 46958, 5016, 22807, 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"word": " بروم،", "probability": 0.944580078125}, {"start": 633.84, "end": 634.3, "word": " يتورى", "probability": 0.60577392578125}, {"start": 634.3, "end": 635.0, "word": " البرومين", "probability": 0.9642333984375}, {"start": 635.0, "end": 635.94, "word": " نفسه", "probability": 0.9920247395833334}, {"start": 635.94, "end": 636.78, "word": " كجزء،", "probability": 0.884423828125}, {"start": 636.78, "end": 637.24, "word": " بيكون", "probability": 0.9811197916666666}, {"start": 637.24, "end": 637.72, "word": " قطبي", "probability": 0.9109700520833334}, {"start": 637.72, "end": 638.0, "word": " ولا", "probability": 0.623046875}, {"start": 638.0, "end": 638.34, "word": " غير", "probability": 0.99755859375}, {"start": 638.34, "end": 638.86, "word": " قطبي؟", "probability": 0.9847412109375}], "temperature": 1.0}, {"id": 30, "seek": 66919, "start": 639.59, "end": 669.19, "text": "بيكون غير قطب لإن هذي بروم و هذي بروم و ال electronegativity متساوية مش زي ال HCL انطارت ممكن يكون في فاندرفالز forces أو لندن forces اللي هي حركة الإلكترونات يعني شوية تتركز لكن بشكل عام هو nonpolar لإن الدارتين أشمالهم زي بعض طب هذا الجزء ال nonpolar كيف أنا بدي أخليه polar بحيث أنه أنا بدي أخد منه PR plus", "tokens": [3555, 1829, 30544, 32771, 13546, 12174, 9566, 3555, 5296, 28814, 1863, 8032, 8848, 1829, 4724, 2288, 20498, 4032, 8032, 8848, 1829, 4724, 2288, 20498, 4032, 2423, 7072, 546, 70, 30142, 44650, 3794, 995, 2407, 10632, 37893, 30767, 1829, 2423, 389, 22458, 16472, 9566, 9640, 2655, 3714, 43020, 7251, 30544, 8978, 6156, 7649, 3215, 2288, 5172, 6027, 11622, 5874, 34051, 5296, 41260, 1863, 5874, 13672, 1829, 39896, 11331, 31747, 3660, 33688, 23275, 2655, 2288, 11536, 9307, 37495, 22653, 13412, 2407, 10632, 6055, 2655, 31747, 11622, 44381, 4724, 8592, 28820, 6225, 10943, 31439, 2107, 12892, 289, 5296, 28814, 1863, 32748, 9640, 2655, 9957, 5551, 8592, 2304, 6027, 16095, 30767, 1829, 45030, 11242, 23032, 3555, 23758, 25724, 11622, 38207, 2423, 2107, 12892, 289, 9122, 33911, 41850, 4724, 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{"start": 1087.58, "end": 1087.9, "word": " بعد", "probability": 0.93798828125}, {"start": 1087.9, "end": 1088.48, "word": " هيك", "probability": 0.962646484375}, {"start": 1088.48, "end": 1089.0, "word": " باقى", "probability": 0.861083984375}, {"start": 1089.0, "end": 1090.08, "word": " التفاعلات", "probability": 0.91044921875}, {"start": 1090.08, "end": 1091.66, "word": " بتصير", "probability": 0.9534505208333334}, {"start": 1091.66, "end": 1094.08, "word": " تقريبا", "probability": 0.9791015625}, {"start": 1094.08, "end": 1095.22, "word": " شبيهة", "probability": 0.8487548828125}, {"start": 1095.22, "end": 1095.64, "word": " جدا،", "probability": 0.7862141927083334}, {"start": 1095.64, "end": 1095.76, "word": " يعني", "probability": 0.884033203125}, {"start": 1095.76, "end": 1096.18, "word": " بنقدر", "probability": 0.9357096354166666}, {"start": 1096.18, "end": 1096.56, "word": " نمشي", "probability": 0.9949951171875}, {"start": 1096.56, "end": 1098.1, "word": " أسرع،", 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"seek": 142226, "start": 1394.56, "end": 1422.26, "text": "إذا خلطة ال H2SO4 و ال S O3 هي اللي بتطلع ليه؟ ال S O3 H كلها كلها S O3 H بتكون positive و لا عن S double bond O double bond O OH و من هنا بتتفاعل واضح؟ أنتم بتذكرين كيف شكل ال sulfuric acid في الكيميا ولا لأ؟", "tokens": [28814, 15730, 16490, 1211, 9566, 3660, 2423, 389, 17, 17188, 19, 4032, 2423, 318, 422, 18, 39896, 13672, 1829, 39894, 9566, 1211, 3615, 32239, 3224, 22807, 2423, 318, 422, 18, 389, 28242, 11296, 28242, 11296, 318, 422, 18, 389, 39894, 30544, 3353, 4032, 20193, 18871, 318, 3834, 6086, 422, 3834, 6086, 422, 13931, 4032, 9154, 34105, 39894, 2655, 5172, 995, 30241, 4032, 46958, 5016, 22807, 14739, 39237, 39894, 8848, 37983, 9957, 9122, 33911, 13412, 28820, 2423, 33831, 299, 8258, 8978, 33251, 32640, 25528, 49429, 5296, 10721, 22807], "avg_logprob": -0.26953126015988266, "compression_ratio": 1.502439024390244, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1394.56, "end": 1395.3, "word": "إذا", 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0.69189453125}, {"start": 1401.14, "end": 1401.42, "word": " S", "probability": 0.93798828125}, {"start": 1401.42, "end": 1402.2, "word": " O3", "probability": 0.912109375}, {"start": 1402.2, "end": 1403.66, "word": " H", "probability": 0.59765625}, {"start": 1403.66, "end": 1406.14, "word": " كلها", "probability": 0.702392578125}, {"start": 1406.14, "end": 1406.42, "word": " كلها", "probability": 0.707275390625}, {"start": 1406.42, "end": 1406.68, "word": " S", "probability": 0.94384765625}, {"start": 1406.68, "end": 1407.18, "word": " O3", "probability": 0.956787109375}, {"start": 1407.18, "end": 1407.72, "word": " H", "probability": 0.802734375}, {"start": 1407.72, "end": 1408.48, "word": " بتكون", "probability": 0.961181640625}, {"start": 1408.48, "end": 1409.02, "word": " positive", "probability": 0.7685546875}, {"start": 1409.02, "end": 1409.18, "word": " و", "probability": 0.1787109375}, {"start": 1409.18, "end": 1409.22, "word": " لا", "probability": 0.130859375}, {"start": 1409.22, "end": 1409.42, "word": " عن", "probability": 0.90869140625}, {"start": 1409.42, "end": 1409.76, "word": " S", "probability": 0.91650390625}, {"start": 1409.76, "end": 1410.02, "word": " double", "probability": 0.4140625}, {"start": 1410.02, "end": 1410.44, "word": " bond", "probability": 0.8935546875}, {"start": 1410.44, "end": 1410.7, "word": " O", "probability": 0.97607421875}, {"start": 1410.7, "end": 1410.98, "word": " double", "probability": 0.57275390625}, {"start": 1410.98, "end": 1411.38, "word": " bond", "probability": 0.98193359375}, {"start": 1411.38, "end": 1411.9, "word": " O", "probability": 0.9892578125}, {"start": 1411.9, "end": 1412.88, "word": " OH", "probability": 0.496826171875}, {"start": 1412.88, "end": 1413.06, "word": " و", "probability": 0.9580078125}, {"start": 1413.06, "end": 1413.2, "word": " من", "probability": 0.9404296875}, {"start": 1413.2, "end": 1413.4, "word": " هنا", "probability": 0.96142578125}, {"start": 1413.4, "end": 1414.78, "word": " بتتفاعل", "probability": 0.93466796875}, {"start": 1414.78, "end": 1418.06, "word": " واضح؟", "probability": 0.9078369140625}, {"start": 1418.06, "end": 1418.28, "word": " أنتم", "probability": 0.495361328125}, {"start": 1418.28, "end": 1418.86, "word": " بتذكرين", "probability": 0.8260498046875}, {"start": 1418.86, "end": 1419.02, "word": " كيف", "probability": 0.961181640625}, {"start": 1419.02, "end": 1419.28, "word": " شكل", "probability": 0.988037109375}, {"start": 1419.28, "end": 1419.46, "word": " ال", "probability": 0.81201171875}, {"start": 1419.46, "end": 1419.96, "word": " sulfuric", "probability": 0.745849609375}, {"start": 1419.96, "end": 1420.3, "word": " acid", "probability": 0.95068359375}, {"start": 1420.3, "end": 1420.46, "word": " في", "probability": 0.93603515625}, {"start": 1420.46, "end": 1421.56, "word": " الكيميا", "probability": 0.7076822916666666}, {"start": 1421.56, "end": 1421.78, "word": " ولا", "probability": 0.80810546875}, {"start": 1421.78, "end": 1422.26, "word": " لأ؟", "probability": 0.9112955729166666}], "temperature": 1.0}, {"id": 60, "seek": 145011, "start": 1424.43, "end": 1450.11, "text": "التفصيل اللي هو الـ Sulphuric acid الواضح؟ هذا اللي هو اللي بيكون الـ Sulphur هنا ال positive وهو اللي بيجي يتفاعل", "tokens": [6027, 2655, 5172, 9381, 26895, 13672, 1829, 31439, 2423, 39184, 35897, 950, 374, 299, 8258, 2423, 2407, 46958, 5016, 22807, 23758, 13672, 1829, 31439, 13672, 1829, 4724, 1829, 30544, 2423, 39184, 35897, 950, 374, 34105, 2423, 3353, 37037, 2407, 13672, 1829, 4724, 1829, 7435, 1829, 7251, 2655, 5172, 995, 30241], "avg_logprob": -0.4482230427218418, "compression_ratio": 1.5126050420168067, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1424.43, "end": 1425.27, "word": "التفصيل", "probability": 0.6476806640625}, {"start": 1425.27, "end": 1426.11, "word": " اللي", "probability": 0.5172119140625}, {"start": 1426.11, "end": 1427.27, "word": " هو", "probability": 0.443115234375}, {"start": 1427.27, "end": 1428.17, "word": " الـ", "probability": 0.291748046875}, {"start": 1428.17, "end": 1429.15, "word": " Sulphuric", "probability": 0.740966796875}, {"start": 1429.15, "end": 1429.15, "word": " acid", "probability": 0.7763671875}, {"start": 1429.15, "end": 1444.65, "word": " الواضح؟", "probability": 0.635107421875}, {"start": 1444.65, "end": 1445.01, "word": " هذا", "probability": 0.68359375}, {"start": 1445.01, "end": 1445.43, "word": " اللي", "probability": 0.936767578125}, {"start": 1445.43, "end": 1445.75, "word": " هو", "probability": 0.75732421875}, {"start": 1445.75, "end": 1446.05, "word": " اللي", "probability": 0.58673095703125}, {"start": 1446.05, "end": 1446.35, "word": " بيكون", "probability": 0.6472981770833334}, {"start": 1446.35, "end": 1446.59, "word": " الـ", "probability": 0.692626953125}, {"start": 1446.59, "end": 1447.01, "word": " Sulphur", "probability": 0.822265625}, {"start": 1447.01, "end": 1447.29, "word": " هنا", "probability": 0.34619140625}, {"start": 1447.29, "end": 1447.45, "word": " ال", "probability": 0.810546875}, {"start": 1447.45, "end": 1447.93, "word": " positive", "probability": 0.63671875}, {"start": 1447.93, "end": 1448.79, "word": " وهو", "probability": 0.7315673828125}, {"start": 1448.79, "end": 1448.95, "word": " اللي", "probability": 0.98876953125}, {"start": 1448.95, "end": 1449.35, "word": " بيجي", "probability": 0.8502197265625}, {"start": 1449.35, "end": 1450.11, "word": " يتفاعل", "probability": 0.94296875}], "temperature": 1.0}, {"id": 61, "seek": 147845, "start": 1451.33, "end": 1478.45, "text": "هو اللي بدو يجي يتفاعل الإلكترونات بتتحرك عليه وبنفس المنطق بتتم استكمال التفاعل بنفس المنطق بتتم عملية استكمال التفاعل بنحصل على الـ Sulphonic acid هذا المركب اللي فيه SO3H بيسموه إيش Sulphonic acid Sulphonic acid", "tokens": [3224, 2407, 13672, 1829, 47525, 2407, 7251, 7435, 1829, 7251, 2655, 5172, 995, 30241, 33688, 23275, 2655, 32887, 8315, 2655, 39894, 2655, 5016, 31747, 47356, 46599, 1863, 36178, 9673, 1863, 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"word": " الإلكترونات", "probability": 0.7972615559895834}, {"start": 1453.89, "end": 1454.63, "word": " بتتحرك", "probability": 0.9849853515625}, {"start": 1454.63, "end": 1455.17, "word": " عليه", "probability": 0.96826171875}, {"start": 1455.17, "end": 1456.79, "word": " وبنفس", "probability": 0.7896321614583334}, {"start": 1456.79, "end": 1457.57, "word": " المنطق", "probability": 0.9754638671875}, {"start": 1457.57, "end": 1459.03, "word": " بتتم", "probability": 0.4293212890625}, {"start": 1459.03, "end": 1459.91, "word": " استكمال", "probability": 0.9736328125}, {"start": 1459.91, "end": 1461.97, "word": " التفاعل", "probability": 0.9305419921875}, {"start": 1461.97, "end": 1462.39, "word": " بنفس", "probability": 0.8515625}, {"start": 1462.39, "end": 1462.93, "word": " المنطق", "probability": 0.9969482421875}, {"start": 1462.93, "end": 1463.33, "word": " بتتم", "probability": 0.8779296875}, {"start": 1463.33, "end": 1463.95, "word": " عملية", "probability": 0.9847005208333334}, {"start": 1463.95, "end": 1465.19, "word": " استكمال", "probability": 0.9837239583333334}, {"start": 1465.19, "end": 1466.01, "word": " التفاعل", "probability": 0.961181640625}, {"start": 1466.01, "end": 1466.99, "word": " بنحصل", "probability": 0.8660481770833334}, {"start": 1466.99, "end": 1467.41, "word": " على", "probability": 0.91748046875}, {"start": 1467.41, "end": 1467.77, "word": " الـ", "probability": 0.702880859375}, {"start": 1467.77, "end": 1468.27, "word": " Sulphonic", "probability": 0.6851806640625}, {"start": 1468.27, "end": 1468.73, "word": " acid", "probability": 0.5888671875}, {"start": 1468.73, "end": 1469.15, "word": " هذا", "probability": 0.91845703125}, {"start": 1469.15, "end": 1469.71, "word": " المركب", "probability": 0.826171875}, {"start": 1469.71, "end": 1469.87, "word": " اللي", "probability": 0.95458984375}, {"start": 1469.87, "end": 1470.39, "word": " فيه", "probability": 0.922607421875}, {"start": 1470.39, "end": 1471.37, "word": " SO3H", "probability": 0.8015950520833334}, {"start": 1471.37, "end": 1471.91, "word": " بيسموه", "probability": 0.9232421875}, {"start": 1471.91, "end": 1472.21, "word": " إيش", "probability": 0.7400716145833334}, {"start": 1472.21, "end": 1473.79, "word": " Sulphonic", "probability": 0.7903645833333334}, {"start": 1473.79, "end": 1474.51, "word": " acid", "probability": 0.86767578125}, {"start": 1474.51, "end": 1477.37, "word": " Sulphonic", "probability": 0.9099934895833334}, {"start": 1477.37, "end": 1478.45, "word": " acid", "probability": 0.9208984375}], "temperature": 1.0}, {"id": 62, "seek": 150314, "start": 1480.46, "end": 1503.14, "text": "أو مرات بكتبوا بنزين salphonic acid حر ينام مش مشكلة بنجي لتفاعل إضافي كيف نحط R group طبعا بدي ال R تكون", "tokens": [10721, 2407, 3714, 2288, 9307, 4724, 4117, 2655, 3555, 14407, 44945, 11622, 9957, 1845, 950, 11630, 8258, 11331, 2288, 7251, 8315, 2304, 37893, 37893, 28820, 3660, 44945, 7435, 1829, 5296, 2655, 5172, 995, 30241, 11933, 11242, 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1601.43, "word": " R", "probability": 0.96875}], "temperature": 1.0}, {"id": 67, "seek": 162657, "start": 1602.63, "end": 1626.57, "text": "المعادلة نقدر نعتبرها معارض وبهيك بتتم عملية الـ alkylation الـ alkylation اللي هو التفاعل مع الكل جروب يعني ألمنيوم بي آر ثري أو إش .. لأ هو المناسب و سعره معقول يستعمل بهذا التفاعل ألمنيوم كلورايد ألمنيوم كلورايد", "tokens": [45340, 3615, 18513, 37977, 8717, 28543, 2288, 8717, 34268, 26890, 11296, 20449, 9640, 11242, 46599, 3224, 1829, 4117, 39894, 39237, 6225, 42213, 10632, 2423, 39184, 419, 4133, 24278, 2423, 39184, 419, 4133, 24278, 13672, 1829, 31439, 16712, 5172, 995, 30241, 20449, 2423, 28820, 10874, 32887, 3555, 37495, 22653, 5551, 19528, 22653, 20498, 4724, 1829, 19753, 2288, 38637, 16572, 34051, 11933, 8592, 4386, 5296, 10721, 31439, 9673, 8315, 35457, 4032, 8608, 3615, 2288, 3224, 20449, 39648, 7251, 14851, 25957, 1211, 39627, 15730, 16712, 5172, 995, 30241, 5551, 19528, 22653, 20498, 9122, 1211, 13063, 995, 25708, 5551, 19528, 22653, 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"probability": 0.9515380859375}, {"start": 1623.73, "end": 1624.19, "word": " ألمنيوم", "probability": 0.9586181640625}, {"start": 1624.19, "end": 1624.77, "word": " كلورايد", "probability": 0.766015625}, {"start": 1624.77, "end": 1625.97, "word": " ألمنيوم", "probability": 0.8704833984375}, {"start": 1625.97, "end": 1626.57, "word": " كلورايد", "probability": 0.98876953125}], "temperature": 1.0}, {"id": 68, "seek": 165926, "start": 1633.62, "end": 1659.26, "text": "الآن هنا احنا حاطينلكم بعض ال limitations اللي هو محددات لـ Frédéric Raft's alkylation طبعا بيسموه نسبة للعالم أو للعلماء Frédéric Raft هذي ال alkylation شو بيسموها؟ Frédéric Raft's alkylation على حسب الناس اللي اشتغلوا الشغل الآن في عندى بعض المشاكل اللي ممكن بدنا نواجهها", "tokens": [6027, 148, 48506, 34105, 1975, 5016, 8315, 11331, 41193, 9957, 23275, 2304, 45030, 11242, 2423, 15705, 13672, 1829, 31439, 3714, 24401, 3215, 9307, 5296, 39184, 1526, 7811, 27578, 7591, 844, 311, 419, 4133, 24278, 23032, 3555, 3615, 995, 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1656.54, "end": 1656.82, "word": " بعض", "probability": 0.984375}, {"start": 1656.82, "end": 1657.64, "word": " المشاكل", "probability": 0.994873046875}, {"start": 1657.64, "end": 1657.94, "word": " اللي", "probability": 0.896484375}, {"start": 1657.94, "end": 1658.28, "word": " ممكن", "probability": 0.97216796875}, {"start": 1658.28, "end": 1658.58, "word": " بدنا", "probability": 0.825439453125}, {"start": 1658.58, "end": 1659.26, "word": " نواجهها", "probability": 0.957421875}], "temperature": 1.0}, {"id": 69, "seek": 168549, "start": 1660.19, "end": 1685.49, "text": "وهي أن التفاعل بتتم مع الـ RCl بس ما بتتمش مع الـ ArCl ولا مع الـ Vinyl Cl الـ Ar بمعنى أنه لو كان عندى حلقة بنزين تانية فيها Cl هل يا تورا ال .. ال aluminium chloride بياخد من البنزين التانية لكلورة و بيسيبليها موجبة؟", "tokens": [2407, 3224, 1829, 14739, 16712, 5172, 995, 30241, 39894, 39237, 20449, 2423, 39184, 497, 9966, 4724, 3794, 19446, 39894, 39237, 8592, 20449, 2423, 39184, 1587, 9966, 49429, 20449, 2423, 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أخدناه اكيومين اكيومين اسم الشهرة تبع ال isopropyl بنزين اتفضل أسألك عشانك غيبتي جابلها بحصة", "tokens": [2407, 10721, 8315, 11331, 3215, 8978, 4117, 14407, 5551, 5172, 9566, 2288, 11331, 2304, 9381, 47356, 9122, 2304, 11536, 22807, 1975, 4117, 1829, 20498, 9957, 2423, 307, 404, 1513, 5088, 44945, 11622, 9957, 46740, 24525, 2304, 13412, 3224, 25720, 5551, 9778, 3215, 8315, 3224, 1975, 4117, 1829, 20498, 9957, 1975, 4117, 1829, 20498, 9957, 24525, 2304, 25124, 3224, 25720, 6055, 3555, 3615, 2423, 307, 404, 1513, 5088, 44945, 11622, 9957, 1975, 2655, 5172, 11242, 1211, 5551, 3794, 10721, 23275, 6225, 8592, 7649, 4117, 32771, 1829, 3555, 31371, 10874, 16758, 1211, 11296, 4724, 5016, 9381, 3660], "avg_logprob": -0.26822916387269896, "compression_ratio": 1.680473372781065, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2441.96, "end": 2442.3, "word": "وأنا", "probability": 0.5616048177083334}, {"start": 2442.3, "end": 2442.5, "word": " حد", "probability": 0.78564453125}, 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2609.41, "end": 2609.95, "word": " علامة", "probability": 0.7975260416666666}, {"start": 2609.95, "end": 2615.09, "word": " هتزعلوا", "probability": 0.963671875}], "temperature": 1.0}, {"id": 108, "seek": 263256, "start": 2616.06, "end": 2632.56, "text": "مش مشكلة لأنه بعد هيك هيصير rearrangement أول ما أضيف ال H plus هنا الكاربو كاتيون هنا secondary مباشرة هيصير hydride shift هيصير الكاربو كاتيون هنا وهذه هتشبك من هنا مش من هنا", "tokens": [2304, 8592, 37893, 28820, 3660, 5296, 33456, 3224, 39182, 39896, 4117, 39896, 9381, 13546, 39568, 518, 5551, 12610, 19446, 5551, 11242, 33911, 2423, 389, 1804, 34105, 33251, 9640, 3555, 2407, 9122, 9307, 1829, 11536, 34105, 11396, 3714, 3555, 33599, 25720, 39896, 9381, 13546, 5796, 25502, 5513, 39896, 9381, 13546, 33251, 9640, 3555, 2407, 9122, 9307, 1829, 11536, 34105, 37037, 24192, 8032, 2655, 8592, 3555, 4117, 9154, 34105, 37893, 9154, 34105], "avg_logprob": -0.2876320439325252, "compression_ratio": 1.6529411764705881, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2616.06, "end": 2616.34, "word": "مش", "probability": 0.4732666015625}, {"start": 2616.34, "end": 2617.0, "word": " مشكلة", "probability": 0.9737955729166666}, {"start": 2617.0, "end": 2617.86, "word": " لأنه", "probability": 0.5347493489583334}, {"start": 2617.86, "end": 2618.1, "word": " بعد", "probability": 0.9462890625}, {"start": 2618.1, "end": 2618.4, "word": " هيك", "probability": 0.880615234375}, {"start": 2618.4, "end": 2618.84, "word": " هيصير", "probability": 0.7825520833333334}, {"start": 2618.84, "end": 2619.68, "word": " rearrangement", "probability": 0.815673828125}, {"start": 2619.68, "end": 2619.96, "word": " أول", "probability": 0.7060546875}, {"start": 2619.96, "end": 2620.1, "word": " ما", "probability": 0.77392578125}, {"start": 2620.1, "end": 2620.4, "word": " أضيف", "probability": 0.7791341145833334}, {"start": 2620.4, "end": 2620.56, "word": " ال", "probability": 0.79833984375}, {"start": 2620.56, "end": 2620.74, "word": " H", "probability": 0.732421875}, {"start": 2620.74, "end": 2621.16, "word": " plus", "probability": 0.0906982421875}, {"start": 2621.16, "end": 2621.72, "word": " هنا", "probability": 0.93798828125}, {"start": 2621.72, "end": 2622.86, "word": " الكاربو", "probability": 0.71435546875}, {"start": 2622.86, "end": 2623.3, "word": " كاتيون", "probability": 0.740478515625}, {"start": 2623.3, "end": 2623.6, "word": " هنا", "probability": 0.77099609375}, {"start": 2623.6, "end": 2624.42, "word": " secondary", "probability": 0.79931640625}, {"start": 2624.42, "end": 2626.12, "word": " مباشرة", "probability": 0.962890625}, {"start": 2626.12, "end": 2626.6, "word": " هيصير", "probability": 0.7791341145833334}, {"start": 2626.6, "end": 2627.48, "word": " hydride", "probability": 0.4813232421875}, {"start": 2627.48, "end": 2627.74, "word": " shift", "probability": 0.9775390625}, {"start": 2627.74, "end": 2628.18, "word": " هيصير", "probability": 0.794921875}, {"start": 2628.18, "end": 2628.62, "word": " الكاربو", "probability": 0.9727783203125}, {"start": 2628.62, "end": 2629.02, "word": " كاتيون", "probability": 0.9713134765625}, {"start": 2629.02, "end": 2629.34, "word": " هنا", "probability": 0.9580078125}, {"start": 2629.34, "end": 2629.98, "word": " وهذه", "probability": 0.5712890625}, {"start": 2629.98, "end": 2630.6, "word": " هتشبك", "probability": 0.745556640625}, {"start": 2630.6, "end": 2630.86, "word": " من", "probability": 0.98583984375}, {"start": 2630.86, "end": 2631.26, "word": " هنا", "probability": 0.89892578125}, {"start": 2631.26, "end": 2632.14, "word": " مش", "probability": 0.6259765625}, {"start": 2632.14, "end": 2632.36, "word": " من", "probability": 0.9765625}, {"start": 2632.36, "end": 2632.56, "word": " هنا", "probability": 0.97265625}], "temperature": 1.0}, {"id": 109, "seek": 266019, "start": 2635.27, "end": 2660.19, "text": "واضح الفكرة؟ بيصير rearrangement الكلمة اللى كنت بدى أسمعها منكوا كلمة rearrangement أنه أنا ضفت ال H plus هنا وين صار ال carbocation؟ secondary فى إمكانية تتحرك ال H هذه ويصير ال carbocation tertiary ومحل ما صار ال carbocation tertiary بيكون عندى إيش؟", "tokens": [2407, 46958, 5016, 27188, 4117, 25720, 22807, 4724, 1829, 9381, 13546, 39568, 518, 2423, 28820, 46007, 13672, 7578, 9122, 29399, 47525, 7578, 5551, 38251, 3615, 11296, 9154, 4117, 14407, 9122, 19528, 3660, 39568, 518, 14739, 3224, 41850, 48812, 5172, 2655, 2423, 389, 1804, 34105, 4032, 9957, 20328, 9640, 2423, 12143, 27943, 22807, 11396, 6156, 7578, 11933, 2304, 41361, 10632, 6055, 2655, 5016, 31747, 2423, 389, 29538, 4032, 1829, 9381, 13546, 2423, 12143, 27943, 38726, 29104, 4032, 2304, 5016, 1211, 19446, 20328, 9640, 2423, 12143, 27943, 38726, 29104, 4724, 1829, 30544, 43242, 7578, 11933, 1829, 8592, 22807], "avg_logprob": -0.19716494845360824, "compression_ratio": 1.6756756756756757, "no_speech_prob": 5.364418029785156e-07, "words": [{"start": 2635.27, "end": 2635.67, "word": "واضح", "probability": 0.9913736979166666}, {"start": 2635.67, "end": 2636.49, "word": " الفكرة؟", "probability": 0.7733154296875}, {"start": 2636.49, "end": 2637.57, "word": " بيصير", "probability": 0.9061279296875}, {"start": 2637.57, "end": 2638.51, "word": " rearrangement", "probability": 0.857421875}, {"start": 2638.51, "end": 2638.99, "word": " الكلمة", "probability": 0.627685546875}, {"start": 2638.99, "end": 2639.13, "word": " اللى", "probability": 0.7646484375}, {"start": 2639.13, "end": 2639.33, "word": " كنت", "probability": 0.97509765625}, {"start": 2639.33, "end": 2639.65, "word": " بدى", "probability": 0.73974609375}, {"start": 2639.65, "end": 2640.53, "word": " أسمعها", "probability": 0.8699951171875}, {"start": 2640.53, "end": 2640.85, "word": " منكوا", "probability": 0.88916015625}, {"start": 2640.85, "end": 2641.17, "word": " كلمة", "probability": 0.8302408854166666}, {"start": 2641.17, "end": 2642.17, "word": " rearrangement", "probability": 0.903076171875}, {"start": 2642.17, "end": 2642.65, "word": " أنه", "probability": 0.6044921875}, {"start": 2642.65, "end": 2642.83, "word": " أنا", "probability": 0.72607421875}, {"start": 2642.83, "end": 2643.15, "word": " ضفت", "probability": 0.8883463541666666}, {"start": 2643.15, "end": 2643.25, "word": " ال", "probability": 0.9521484375}, {"start": 2643.25, "end": 2643.41, "word": " H", "probability": 0.7451171875}, {"start": 2643.41, "end": 2643.73, "word": " plus", "probability": 0.1368408203125}, {"start": 2643.73, "end": 2644.17, "word": " هنا", "probability": 0.9423828125}, {"start": 2644.17, "end": 2644.85, "word": " وين", "probability": 0.804443359375}, {"start": 2644.85, "end": 2645.05, "word": " صار", "probability": 0.98876953125}, {"start": 2645.05, "end": 2645.21, "word": " ال", "probability": 0.58984375}, {"start": 2645.21, "end": 2646.67, "word": " carbocation؟", "probability": 0.7333984375}, {"start": 2646.67, "end": 2648.31, "word": " secondary", "probability": 0.91357421875}, {"start": 2648.31, "end": 2648.95, "word": " فى", "probability": 0.61962890625}, {"start": 2648.95, "end": 2649.53, "word": " إمكانية", "probability": 0.9339599609375}, {"start": 2649.53, "end": 2650.15, "word": " تتحرك", "probability": 0.9781494140625}, {"start": 2650.15, "end": 2650.37, "word": " ال", "probability": 0.96240234375}, {"start": 2650.37, "end": 2650.73, "word": " H", "probability": 0.97900390625}, {"start": 2650.73, "end": 2651.35, "word": " هذه", "probability": 0.36474609375}, {"start": 2651.35, "end": 2652.77, "word": " ويصير", "probability": 0.9061279296875}, {"start": 2652.77, "end": 2652.91, "word": " ال", "probability": 0.7919921875}, {"start": 2652.91, "end": 2653.61, "word": " carbocation", "probability": 0.873046875}, {"start": 2653.61, "end": 2654.29, "word": " tertiary", "probability": 0.980712890625}, {"start": 2654.29, "end": 2655.39, "word": " ومحل", "probability": 0.930419921875}, {"start": 2655.39, "end": 2655.53, "word": " ما", "probability": 0.96728515625}, {"start": 2655.53, "end": 2655.83, "word": " صار", "probability": 0.946044921875}, {"start": 2655.83, "end": 2655.97, "word": " ال", "probability": 0.7216796875}, {"start": 2655.97, "end": 2656.75, "word": " carbocation", "probability": 0.939208984375}, {"start": 2656.75, "end": 2657.65, "word": " tertiary", "probability": 0.871826171875}, {"start": 2657.65, "end": 2659.27, "word": " بيكون", "probability": 0.8662109375}, {"start": 2659.27, "end": 2659.67, "word": " عندى", "probability": 0.81396484375}, {"start": 2659.67, "end": 2660.19, "word": " إيش؟", "probability": 0.859130859375}], "temperature": 1.0}, {"id": 110, "seek": 266984, "start": 2661.1, "end": 2669.84, "text": "محل ما صار الكربوكاتيون الـ tertiary بصير التفاعل، إذا هنا صارت فكرة الـ rearrangement", "tokens": [2304, 5016, 1211, 19446, 20328, 9640, 33251, 25513, 2407, 4117, 9307, 1829, 11536, 2423, 39184, 38726, 29104, 4724, 9381, 13546, 16712, 5172, 995, 30241, 12399, 11933, 15730, 34105, 20328, 9640, 2655, 6156, 4117, 25720, 2423, 39184, 39568, 518], "avg_logprob": -0.2694310928002382, "compression_ratio": 1.2, "no_speech_prob": 0.0, "words": [{"start": 2661.1, "end": 2661.52, "word": "محل", "probability": 0.54296875}, {"start": 2661.52, "end": 2661.66, "word": " ما", "probability": 0.97216796875}, {"start": 2661.66, "end": 2661.94, "word": " صار", "probability": 0.7939453125}, {"start": 2661.94, "end": 2662.96, "word": " الكربوكاتيون", "probability": 0.7330147879464286}, {"start": 2662.96, "end": 2663.22, "word": " الـ", "probability": 0.6292724609375}, {"start": 2663.22, "end": 2663.86, "word": " tertiary", "probability": 0.906982421875}, {"start": 2663.86, "end": 2664.56, "word": " بصير", "probability": 0.8030598958333334}, {"start": 2664.56, "end": 2665.32, "word": " التفاعل،", "probability": 0.8458984375}, {"start": 2665.32, "end": 2665.52, "word": " إذا", "probability": 0.677490234375}, {"start": 2665.52, "end": 2665.92, "word": " هنا", "probability": 0.86962890625}, {"start": 2665.92, "end": 2667.62, "word": " صارت", "probability": 0.9593098958333334}, {"start": 2667.62, "end": 2668.14, "word": " فكرة", "probability": 0.9918619791666666}, {"start": 2668.14, "end": 2668.88, "word": " الـ", "probability": 0.89599609375}, {"start": 2668.88, "end": 2669.84, "word": " rearrangement", "probability": 0.6702880859375}], "temperature": 1.0}, {"id": 111, "seek": 269936, "start": 2671.06, "end": 2699.36, "text": "في حالة الـ Alkyl Halides بالمناسبة عاد الـ rearrangements هذه اللي برضه هنا لو كنتوا بتفقدوا كلور مش ضروري من خلال الالكين وعملة secondary و بإمكانه يتحول إلى tertiary برضه بيصير rearrangement بمعنى لو كان هذا المركب زيك CH2 CH3 خليني أقول و هذه CHCL و هنا COH و CH3 و CH3", "tokens": [41185, 11331, 6027, 3660, 2423, 39184, 967, 4133, 75, 13896, 1875, 20666, 2304, 8315, 35457, 3660, 6225, 18513, 2423, 39184, 39568, 1117, 29538, 13672, 1829, 4724, 43042, 3224, 34105, 45164, 9122, 29399, 14407, 39894, 5172, 28543, 14407, 28242, 13063, 37893, 48812, 2288, 13063, 1829, 9154, 16490, 1211, 6027, 2423, 6027, 4117, 9957, 4032, 25957, 37977, 11396, 4032, 4724, 28814, 2304, 41361, 3224, 7251, 2655, 5016, 12610, 30731, 38726, 29104, 4724, 43042, 3224, 4724, 1829, 9381, 13546, 39568, 518, 4724, 2304, 3615, 1863, 7578, 45164, 25961, 23758, 9673, 31747, 3555, 30767, 1829, 4117, 5995, 17, 5995, 18, 16490, 1211, 9957, 1829, 5551, 39648, 4032, 29538, 5995, 22458, 4032, 34105, 3002, 39, 4032, 5995, 18, 4032, 5995, 18], "avg_logprob": -0.20539529252256084, "compression_ratio": 1.5789473684210527, "no_speech_prob": 9.834766387939453e-06, "words": [{"start": 2671.06, "end": 2671.28, "word": "في", "probability": 0.6796875}, {"start": 2671.28, "end": 2671.68, "word": " حالة", "probability": 0.9964192708333334}, {"start": 2671.68, "end": 2671.86, "word": " الـ", "probability": 0.577880859375}, {"start": 2671.86, "end": 2672.16, "word": " Alkyl", "probability": 0.6571451822916666}, {"start": 2672.16, "end": 2672.6, "word": " Halides", "probability": 0.79248046875}, {"start": 2672.6, "end": 2673.7, "word": " بالمناسبة", "probability": 0.957421875}, {"start": 2673.7, "end": 2673.96, "word": " عاد", "probability": 0.465576171875}, {"start": 2673.96, "end": 2674.4, "word": " الـ", "probability": 0.65380859375}, {"start": 2674.4, "end": 2675.28, "word": " rearrangements", "probability": 0.700439453125}, {"start": 2675.28, "end": 2675.58, "word": " هذه", "probability": 0.75537109375}, {"start": 2675.58, "end": 2675.74, "word": " اللي", "probability": 0.6380615234375}, {"start": 2675.74, "end": 2676.1, "word": " برضه", "probability": 0.9635416666666666}, {"start": 2676.1, "end": 2676.38, "word": " هنا", "probability": 0.5478515625}, {"start": 2676.38, "end": 2676.62, "word": " لو", "probability": 0.92529296875}, {"start": 2676.62, "end": 2676.94, "word": " كنتوا", "probability": 0.9650065104166666}, {"start": 2676.94, "end": 2677.48, "word": " بتفقدوا", "probability": 0.9547119140625}, {"start": 2677.48, "end": 2677.88, "word": " كلور", "probability": 0.6715087890625}, {"start": 2677.88, "end": 2678.1, "word": " مش", "probability": 0.98046875}, {"start": 2678.1, "end": 2678.48, "word": " ضروري", "probability": 0.9403076171875}, {"start": 2678.48, "end": 2678.6, "word": " من", "probability": 0.99658203125}, {"start": 2678.6, "end": 2678.98, "word": " خلال", "probability": 0.9915364583333334}, {"start": 2678.98, "end": 2679.66, "word": " الالكين", "probability": 0.69329833984375}, {"start": 2679.66, "end": 2680.46, "word": " وعملة", "probability": 0.6927083333333334}, {"start": 2680.46, "end": 2681.26, "word": " secondary", "probability": 0.8935546875}, {"start": 2681.26, "end": 2681.76, "word": " و", "probability": 0.88232421875}, {"start": 2681.76, "end": 2682.78, "word": " بإمكانه", "probability": 0.9435546875}, {"start": 2682.78, "end": 2683.62, "word": " يتحول", "probability": 0.9930419921875}, {"start": 2683.62, "end": 2683.88, "word": " إلى", "probability": 0.54443359375}, {"start": 2683.88, "end": 2684.62, "word": " tertiary", "probability": 0.964111328125}, {"start": 2684.62, "end": 2686.48, "word": " برضه", "probability": 0.9200846354166666}, {"start": 2686.48, "end": 2686.76, "word": " بيصير", "probability": 0.90478515625}, {"start": 2686.76, "end": 2687.44, "word": " rearrangement", "probability": 0.932373046875}, {"start": 2687.44, "end": 2688.12, "word": " بمعنى", "probability": 0.97265625}, {"start": 2688.12, "end": 2688.3, "word": " لو", "probability": 0.86865234375}, {"start": 2688.3, "end": 2688.54, "word": " كان", "probability": 0.9912109375}, {"start": 2688.54, "end": 2688.76, "word": " هذا", "probability": 0.91015625}, {"start": 2688.76, "end": 2689.3, "word": " المركب", "probability": 0.7890625}, {"start": 2689.3, "end": 2689.68, "word": " زيك", "probability": 0.91796875}, {"start": 2689.68, "end": 2690.54, "word": " CH2", "probability": 0.913818359375}, {"start": 2690.54, "end": 2691.4, "word": " CH3", "probability": 0.702392578125}, {"start": 2691.4, "end": 2691.8, "word": " خليني", "probability": 0.8653564453125}, {"start": 2691.8, "end": 2692.16, "word": " أقول", "probability": 0.841796875}, {"start": 2692.16, "end": 2692.6, "word": " و", "probability": 0.66552734375}, {"start": 2692.6, "end": 2692.84, "word": " هذه", "probability": 0.470458984375}, {"start": 2692.84, "end": 2694.76, "word": " CHCL", "probability": 0.6103515625}, {"start": 2694.76, "end": 2694.96, "word": " و", "probability": 0.845703125}, {"start": 2694.96, "end": 2695.2, "word": " هنا", "probability": 0.85986328125}, {"start": 2695.2, "end": 2696.46, "word": " COH", "probability": 0.851318359375}, {"start": 2696.46, "end": 2696.8, "word": " و", "probability": 0.83984375}, {"start": 2696.8, "end": 2697.78, "word": " CH3", "probability": 0.8525390625}, {"start": 2697.78, "end": 2698.48, "word": " و", "probability": 0.92041015625}, {"start": 2698.48, "end": 2699.36, "word": " CH3", "probability": 0.909423828125}], "temperature": 1.0}, {"id": 112, "seek": 272774, "start": 2700.96, "end": 2727.74, "text": "وحطينا هنا الومنيوم كلورايت الومنيوم كلورايت شو بدي اعمل؟ هيسحب السيارة ليكوّل السكاندر كاربو كاتايل هذا بيعمل ال arrangement والنتيجة ان التفاعل لا يتم مكان الكلور انما يتم هنا هذه الجملة اللي قبل شوية انا امشيت عليها بسرعة اذا بتتذكروا هنا اخر كلمة ايش كان مكتوب عندكم", "tokens": [2407, 5016, 9566, 1829, 8315, 34105, 2423, 20498, 22653, 20498, 9122, 1211, 13063, 995, 36081, 2423, 20498, 22653, 20498, 9122, 1211, 13063, 995, 36081, 13412, 2407, 4724, 16254, 1975, 25957, 1211, 22807, 39896, 3794, 5016, 3555, 21136, 1829, 9640, 3660, 32239, 4117, 2407, 11703, 1211, 21136, 41361, 3215, 2288, 9122, 9640, 3555, 2407, 9122, 9307, 995, 26895, 23758, 4724, 1829, 25957, 1211, 2423, 17620, 16070, 29399, 1829, 7435, 3660, 16472, 16712, 5172, 995, 30241, 20193, 7251, 39237, 3714, 41361, 33251, 1211, 13063, 16472, 15042, 7251, 39237, 34105, 29538, 25724, 2304, 37977, 13672, 1829, 12174, 36150, 13412, 2407, 10632, 1975, 8315, 1975, 2304, 8592, 36081, 25894, 11296, 4724, 3794, 2288, 27884, 1975, 15730, 39894, 2655, 8848, 37983, 14407, 34105, 1975, 34740, 9122, 19528, 3660, 1975, 1829, 8592, 25961, 3714, 4117, 2655, 37746, 43242, 24793], "avg_logprob": -0.2298274212586346, "compression_ratio": 1.932, "no_speech_prob": 1.0132789611816406e-06, "words": [{"start": 2700.96, "end": 2701.7, "word": "وحطينا", "probability": 0.8099609375}, {"start": 2701.7, "end": 2701.94, "word": " هنا", "probability": 0.77587890625}, {"start": 2701.94, "end": 2702.56, "word": " الومنيوم", "probability": 0.5866851806640625}, {"start": 2702.56, "end": 2703.38, "word": " كلورايت", "probability": 0.645361328125}, {"start": 2703.38, "end": 2705.4, "word": " الومنيوم", "probability": 0.7989501953125}, {"start": 2705.4, "end": 2705.92, "word": " كلورايت", "probability": 0.94638671875}, {"start": 2705.92, "end": 2706.08, "word": " شو", "probability": 0.75048828125}, {"start": 2706.08, "end": 2706.26, "word": " بدي", "probability": 0.607177734375}, {"start": 2706.26, "end": 2706.92, "word": " اعمل؟", "probability": 0.763916015625}, {"start": 2706.92, "end": 2708.14, "word": " هيسحب", "probability": 0.78143310546875}, {"start": 2708.14, "end": 2708.46, "word": " السيارة", "probability": 0.6976318359375}, {"start": 2708.46, "end": 2708.86, "word": " ليكوّل", "probability": 0.612548828125}, {"start": 2708.86, "end": 2709.48, "word": " السكاندر", "probability": 0.6600341796875}, {"start": 2709.48, "end": 2709.96, "word": " كاربو", "probability": 0.9014892578125}, {"start": 2709.96, "end": 2710.46, "word": " كاتايل", "probability": 0.7548828125}, {"start": 2710.46, "end": 2711.82, "word": " هذا", "probability": 0.71435546875}, {"start": 2711.82, "end": 2713.58, "word": " بيعمل", "probability": 0.91943359375}, {"start": 2713.58, "end": 2713.66, "word": " ال", "probability": 0.86376953125}, {"start": 2713.66, "end": 2714.12, "word": " arrangement", "probability": 0.27001953125}, {"start": 2714.12, "end": 2714.98, "word": " والنتيجة", "probability": 0.89921875}, {"start": 2714.98, "end": 2715.16, "word": " ان", "probability": 0.61669921875}, {"start": 2715.16, "end": 2715.7, "word": " التفاعل", "probability": 0.913818359375}, {"start": 2715.7, "end": 2715.94, "word": " لا", "probability": 0.85400390625}, {"start": 2715.94, "end": 2716.3, "word": " يتم", "probability": 0.92578125}, {"start": 2716.3, "end": 2716.72, "word": " مكان", "probability": 0.96826171875}, {"start": 2716.72, "end": 2717.22, "word": " الكلور", "probability": 0.7469889322916666}, {"start": 2717.22, "end": 2717.52, "word": " انما", "probability": 0.80615234375}, {"start": 2717.52, "end": 2717.84, "word": " يتم", "probability": 0.985595703125}, {"start": 2717.84, "end": 2718.14, "word": " هنا", "probability": 0.98681640625}, {"start": 2718.14, "end": 2720.14, "word": " هذه", "probability": 0.7646484375}, {"start": 2720.14, "end": 2720.54, "word": " الجملة", "probability": 0.9381510416666666}, {"start": 2720.54, "end": 2720.68, "word": " اللي", "probability": 0.861328125}, {"start": 2720.68, "end": 2720.92, "word": " قبل", "probability": 0.9345703125}, {"start": 2720.92, "end": 2721.32, "word": " شوية", "probability": 0.927734375}, {"start": 2721.32, "end": 2721.64, "word": " انا", "probability": 0.8017578125}, {"start": 2721.64, "end": 2722.1, "word": " امشيت", "probability": 0.885009765625}, {"start": 2722.1, "end": 2722.42, "word": " عليها", "probability": 0.99072265625}, {"start": 2722.42, "end": 2722.84, "word": " بسرعة", "probability": 0.991455078125}, {"start": 2722.84, "end": 2723.04, "word": " اذا", "probability": 0.779052734375}, {"start": 2723.04, "end": 2723.84, "word": " بتتذكروا", "probability": 0.9421875}, {"start": 2723.84, "end": 2724.04, "word": " هنا", "probability": 0.87841796875}, {"start": 2724.04, "end": 2724.88, "word": " اخر", "probability": 0.78125}, {"start": 2724.88, "end": 2726.36, "word": " كلمة", "probability": 0.9641927083333334}, {"start": 2726.36, "end": 2726.56, "word": " ايش", "probability": 0.7955729166666666}, {"start": 2726.56, "end": 2726.78, "word": " كان", "probability": 0.9951171875}, {"start": 2726.78, "end": 2727.18, "word": " مكتوب", "probability": 0.9884033203125}, {"start": 2727.18, "end": 2727.74, "word": " عندكم", "probability": 0.986083984375}], "temperature": 1.0}, {"id": 113, "seek": 274890, "start": 2732.5, "end": 2748.9, "text": "إنه في ال alkylation لما بتكون carbocation و بده يتفاعل لو صاحله احسن وضعه بيحسن ولا لأ؟ لو صاحله يعمل rearrangement بيعمل ولا لأ؟ شكرا", "tokens": [28814, 1863, 3224, 8978, 2423, 419, 4133, 24278, 5296, 15042, 39894, 30544, 12143, 27943, 4032, 47525, 3224, 7251, 2655, 5172, 995, 30241, 45164, 20328, 39319, 43761, 1975, 5016, 3794, 1863, 4032, 11242, 3615, 3224, 4724, 1829, 5016, 3794, 1863, 49429, 5296, 10721, 22807, 45164, 20328, 39319, 43761, 7251, 25957, 1211, 39568, 518, 4724, 1829, 25957, 1211, 49429, 5296, 10721, 22807, 13412, 4117, 23557], "avg_logprob": -0.20617676340043545, "compression_ratio": 1.452054794520548, "no_speech_prob": 3.814697265625e-06, "words": [{"start": 2732.5, "end": 2732.84, "word": "إنه", "probability": 0.6769612630208334}, {"start": 2732.84, "end": 2732.94, "word": " في", "probability": 0.96044921875}, {"start": 2732.94, "end": 2733.08, "word": " ال", "probability": 0.9814453125}, {"start": 2733.08, "end": 2734.1, "word": " alkylation", "probability": 0.68853759765625}, {"start": 2734.1, "end": 2736.42, "word": " لما", "probability": 0.8974609375}, {"start": 2736.42, "end": 2737.02, "word": " بتكون", "probability": 0.831787109375}, {"start": 2737.02, "end": 2738.1, "word": " carbocation", "probability": 0.508056640625}, {"start": 2738.1, "end": 2738.56, "word": " و", "probability": 0.89794921875}, {"start": 2738.56, "end": 2738.82, "word": " بده", "probability": 0.537109375}, {"start": 2738.82, "end": 2739.5, "word": " يتفاعل", "probability": 0.97080078125}, {"start": 2739.5, "end": 2739.8, "word": " لو", "probability": 0.68505859375}, {"start": 2739.8, "end": 2740.62, "word": " صاحله", "probability": 0.83056640625}, {"start": 2740.62, "end": 2741.88, "word": " احسن", "probability": 0.8319091796875}, {"start": 2741.88, "end": 2742.5, "word": " وضعه", "probability": 0.9873046875}, {"start": 2742.5, "end": 2743.16, "word": " بيحسن", "probability": 0.8443359375}, {"start": 2743.16, "end": 2743.38, "word": " ولا", "probability": 0.90283203125}, {"start": 2743.38, "end": 2744.28, "word": " لأ؟", "probability": 0.8846028645833334}, {"start": 2744.28, "end": 2744.56, "word": " لو", "probability": 0.916015625}, {"start": 2744.56, "end": 2744.96, "word": " صاحله", "probability": 0.9890950520833334}, {"start": 2744.96, "end": 2745.28, "word": " يعمل", "probability": 0.9713541666666666}, {"start": 2745.28, "end": 2746.06, "word": " rearrangement", "probability": 0.952392578125}, {"start": 2746.06, "end": 2746.48, "word": " بيعمل", "probability": 0.905517578125}, {"start": 2746.48, "end": 2746.66, "word": " ولا", "probability": 0.96337890625}, {"start": 2746.66, "end": 2747.84, "word": " لأ؟", "probability": 0.9798177083333334}, {"start": 2747.84, "end": 2748.9, "word": " شكرا", "probability": 0.9134114583333334}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2751.79675, "duration_after_vad": 2625.740624999989}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e242de5cc4e2639b151a878af96beeeb5eac4ba0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_raw.srt
@@ -0,0 +1,2064 @@
+1
+00:00:05,650 --> 00:00:10,570
+المرة الماضية اتكلمنا على مقدمة لل aromatic
+
+2
+00:00:10,570 --> 00:00:16,570
+compounds وتسميتها واضح اليوم ان شاء الله بدنا
+
+3
+00:00:16,570 --> 00:00:22,170
+ندرس تفاعلات ال aromatic compounds تفاعلات البنزين
+
+4
+00:00:22,170 --> 00:00:29,310
+دائما و ابدا دائما و ابداصورة كلية لأي موضوع
+
+5
+00:00:29,310 --> 00:00:35,010
+بيتريح واضح؟ و الصورة الكلية دائما انك تكون فاهم
+
+6
+00:00:35,010 --> 00:00:38,990
+ايش التفاعل العام يعني احنا الالف chapter اربعة
+
+7
+00:00:38,990 --> 00:00:44,270
+اربعة من اتناشر chapter يعني تلت المنهج اذا اجيت
+
+8
+00:00:44,270 --> 00:00:49,500
+سألتكم ايش اللي درسناه؟ الالكينزلما نقول الـ
+
+9
+00:00:49,500 --> 00:00:54,120
+Alkenes، شو تفاعلاتهم؟ بكلمة واحدة، بدو يكون
+
+10
+00:00:54,120 --> 00:00:58,660
+الكلام بشكل أساسي Substitution Free Radical
+
+11
+00:00:58,660 --> 00:01:02,520
+Substitution، مظبوط ولا لا؟ رغم أنه بشكل عام inert
+
+12
+00:01:02,520 --> 00:01:06,920
+لكن لما بيعملوا Free Radical Substitution أو الـ
+
+13
+00:01:06,920 --> 00:01:13,060
+Thermolysis والتكسر بالحرارة الآن، لو جينا على الـ
+
+14
+00:01:13,060 --> 00:01:21,250
+Alkenes تفاعلهم الـ Additionالان لو سألنا ايش نوع
+
+15
+00:01:21,250 --> 00:01:26,350
+ال addition اللى بتتم على ال الكينز ايش اللى كنا
+
+16
+00:01:26,350 --> 00:01:30,170
+نبدأ فيه التفاعل موجب ولا سالب اللى بيجي وبيهاجم
+
+17
+00:01:30,170 --> 00:01:35,350
+ال الكينز موجب اتش بلس اذا نوع ال addition اللى
+
+18
+00:01:35,350 --> 00:01:40,090
+على ال الكينز electrophilic additionElectrophilic
+
+19
+00:01:40,090 --> 00:01:44,710
+لإنه بيجي Electrophile بيجي موجب ..لأن ليش بيجي
+
+20
+00:01:44,710 --> 00:01:49,570
+الموجب؟ لأن هذا ال keen double bond .. هاي زيك
+
+21
+00:01:49,570 --> 00:01:52,770
+double bond .. double bond يعني إلكترونات .. لأن
+
+22
+00:01:52,770 --> 00:01:57,520
+الإلكترونات شو اللي بيجي يهاجم عليها؟positive ولا
+
+23
+00:01:57,520 --> 00:02:02,360
+negative؟ positive إذا ال addition اللي بيصير على
+
+24
+00:02:02,360 --> 00:02:07,680
+ال alkenes ومتلها ال alkynes is electrophilic
+
+25
+00:02:07,680 --> 00:02:12,040
+addition يعني لو بدنا نيجي نجيبلكوا سؤال نقول
+
+26
+00:02:12,040 --> 00:02:16,280
+والله ال alkenes undergo a eucleophilic addition
+
+27
+00:02:16,280 --> 00:02:22,180
+in generalالجواب غلط التفاعل الأساسي Electrophilic
+
+28
+00:02:22,180 --> 00:02:27,520
+addition هي إلكترونيات بجهة Electrophile موجة،
+
+29
+00:02:27,520 --> 00:02:32,600
+واضح؟ الآن الـ aromatic compounds، إيه التفاعل
+
+30
+00:02:32,600 --> 00:02:37,960
+الأساسي؟ والله إذا الـalkenes فيهم double bond
+
+31
+00:02:37,960 --> 00:02:45,620
+واحدةالبنزين فيه تلاتة اللي عاملين resonance يعني
+
+32
+00:02:45,620 --> 00:02:49,660
+اللي بدو ييجي يهاجم على البنزين كأنه بيهاجم على
+
+33
+00:02:49,660 --> 00:02:56,280
+حقل من الإلكترونات كأنه بيهاجم على سحابة إلكترونية
+
+34
+00:02:56,280 --> 00:02:59,240
+الآن اللي بدو ييجي يهاجم على سحابة إلكترونية إيش
+
+35
+00:02:59,240 --> 00:03:04,020
+شرطه؟ إنه بدو يكون .. هذه البنزين .. بدو يكون موجة
+
+36
+00:03:05,250 --> 00:03:10,930
+واضح بيكون موجب اللي بيهاجم على البنزين على سحابة
+
+37
+00:03:10,930 --> 00:03:14,450
+إلكترونية كبيرة بيكون موجب وعشان هيك المسمى
+
+38
+00:03:14,450 --> 00:03:20,760
+التفاعل electrophilic aromaticsubstitution هنا
+
+39
+00:03:20,760 --> 00:03:27,240
+بيجينا اختلاف أساسي وجوهري كبير كبير ما بين ال
+
+40
+00:03:27,240 --> 00:03:31,840
+alkenes وما بين ال aromatic compounds ال alkenes
+
+41
+00:03:31,840 --> 00:03:34,360
+كانوا عبارة عن double bond وال double bond إيش
+
+42
+00:03:34,360 --> 00:03:42,800
+نقول عنها؟ بتكسروبتعمل إضافة إضافة دارتين الآن
+
+43
+00:03:42,800 --> 00:03:46,800
+ربما يخطر على بال الناس للوهلة الأولى إنه إذا الـ
+
+44
+00:03:46,800 --> 00:03:50,500
+double bond بتعمل addition لما يكونوا تلاتة ممكن
+
+45
+00:03:50,500 --> 00:03:54,820
+نتخيلهم بهذا الشكل أو بالشكل ما شاء الله كام
+
+46
+00:03:54,820 --> 00:03:58,760
+double bond عندى تلاتة إنه نتخيل إنه بدو ييجي
+
+47
+00:03:58,760 --> 00:04:02,380
+electrophile متفقين عليها بدو يجيهم موجب لكن يعمل
+
+48
+00:04:02,380 --> 00:04:06,620
+addition الواقع إنه بالتجربة لاجو مابصيرش على
+
+49
+00:04:06,620 --> 00:04:12,680
+البنزين additionما بيصير عليه addition رغم وجود
+
+50
+00:04:12,680 --> 00:04:17,060
+ايشتلاتة double bonds، عشانك بيقولوا ان ال double
+
+51
+00:04:17,060 --> 00:04:26,180
+bonds هدولة تبعون البنزين لا يوجد فيهم مواصفات ال
+
+52
+00:04:26,180 --> 00:04:29,840
+double bond الواحدة، they don't have or they don't
+
+53
+00:04:29,840 --> 00:04:34,680
+show double bond character لأن أهم ميزة لل double
+
+54
+00:04:34,680 --> 00:04:39,480
+bond انها بتعمل ايش؟ addition هدولة مابرضوش يعملوا
+
+55
+00:04:39,480 --> 00:04:44,560
+additionواضح؟ هدولة ما بيرضوش يعملوا addition ليش
+
+56
+00:04:44,560 --> 00:04:47,460
+هدولة مش راضيين يعملوا addition هان، برا، و هان،
+
+57
+00:04:47,460 --> 00:04:51,220
+برا، و هان، برا؟ لأن هم مع بعضهم عاملين resonance
+
+58
+00:04:51,220 --> 00:04:56,060
+egg عاملين دائرة مغلقة في بعض ومثبتين نفسهم
+
+59
+00:04:56,060 --> 00:05:01,520
+بنفسهم، مابيحبوش يتفاعلوا برا فرغم وجود تلاتة
+
+60
+00:05:01,520 --> 00:05:05,400
+double bonds في البنزين لكن مابيعملش تفاعل الـ
+
+61
+00:05:05,400 --> 00:05:10,760
+double bond إذا هذا الكلام شوية هيسهل علينايعني
+
+62
+00:05:10,760 --> 00:05:14,360
+لما كنا ناخد ال double bonds و نبدأ نقول إضافة
+
+63
+00:05:14,360 --> 00:05:21,320
+نقول إضافة ال hydrogen ال halogen ال hbr ال hcl ال
+
+64
+00:05:21,320 --> 00:05:27,220
+h2o و كل إيش إضافات إضافات إضافات هنا ولا تفاعل
+
+65
+00:05:27,220 --> 00:05:31,420
+منهم باللغة ولا إشي بصير ولا كأنه عندى
+
+66
+00:05:37,800 --> 00:05:41,800
+البنزين صح بحتوى ع تلاتة double bonds لكنه لايتفعل
+
+67
+00:05:41,800 --> 00:05:48,220
+دفعولات double bondsبيعمل substitution إيش اللي
+
+68
+00:05:48,220 --> 00:05:53,440
+بده يبدل اللي بده يبدل ببساطة ال H اللي موجودة هنا
+
+69
+00:05:53,440 --> 00:06:00,020
+بدأ تنشال و يجي بدالها إش جديد شيلت H حطيت X أيا
+
+70
+00:06:00,020 --> 00:06:04,460
+كانت هال X هذا التفاعل إيش يعتبر substitution إذا
+
+71
+00:06:04,460 --> 00:06:09,560
+التفاعل الأساسي لل aromatic compounds the main
+
+72
+00:06:09,560 --> 00:06:16,010
+reaction of aromatic compounds isلأ Electrophilic
+
+73
+00:06:16,010 --> 00:06:19,850
+Substitution بديكوا تتعودوا تحطوا الكلام بالظبط
+
+74
+00:06:19,850 --> 00:06:23,790
+لأنه أنا برضه لما بدي أسالكوا عنه بدي أسالكوا
+
+75
+00:06:23,790 --> 00:06:30,490
+بالظبط في الألكينزكننا نقول free radical
+
+76
+00:06:30,490 --> 00:06:34,610
+substitution متذكرين؟ لما كنا نعمل الهالوجينيشن
+
+77
+00:06:34,610 --> 00:06:38,370
+كان إبدال من خلال ال free radical اللي كان يهاجم
+
+78
+00:06:38,370 --> 00:06:42,730
+CR radical هنا اللي بده يهاجم موجب إذا في عنده
+
+79
+00:06:42,730 --> 00:06:47,170
+free radical substitution في عنده electrophilic
+
+80
+00:06:47,170 --> 00:06:50,670
+substitution بعد ذلك بشبتر ستة في substitution
+
+81
+00:06:50,670 --> 00:06:53,850
+تاني على الalkyl halide اللي بيهاجم ال nucleophile
+
+82
+00:06:53,850 --> 00:06:59,260
+في nucleophilic substitutionإذا أنا عندي أكتر من
+
+83
+00:06:59,260 --> 00:07:03,380
+شغلة وكل حاجة بدنا نحفظها بالظبط ماببتيش أنا أجي
+
+84
+00:07:03,380 --> 00:07:07,200
+أقول ال alkanes و ال aromatic compounds و بعد شوية
+
+85
+00:07:07,200 --> 00:07:09,680
+و شنطر ستة ال alkyl halides they undergo
+
+86
+00:07:09,680 --> 00:07:14,900
+substitution صح إبدال لكن في التلت حالات مختلفين
+
+87
+00:07:14,900 --> 00:07:18,140
+صرنا ماخدين إحنا ال alkanes free radical
+
+88
+00:07:18,140 --> 00:07:20,620
+substitution الآن ال aromatic compounds
+
+89
+00:07:20,620 --> 00:07:24,520
+electrophilic substitution بعد شوية ال alkyl
+
+90
+00:07:24,520 --> 00:07:28,790
+halidesالـ Eucleophilic Substitution الطلاب اللي
+
+91
+00:07:28,790 --> 00:07:34,670
+أحيانا بيغلطوا بيكونوا مش مميزين هذه الشغلات فخلاص
+
+92
+00:07:34,670 --> 00:07:38,370
+كله عندهم substitution بتجيب سؤال صح و غلط ولا
+
+93
+00:07:38,370 --> 00:07:43,680
+سؤالين على هذهتخربته فيهم، واضح؟ إذا هذا التفاعل
+
+94
+00:07:43,680 --> 00:07:47,980
+Electrophilic Substitution إنه حيصير إبدال
+
+95
+00:07:47,980 --> 00:07:52,940
+والمهاجم Electrophile، الآن يمكن أن يتم أنواع
+
+96
+00:07:52,940 --> 00:07:57,520
+كثيرة من الإبدال، ممكن إنه يصير إبدال ب X، بحيث إن
+
+97
+00:07:57,520 --> 00:08:04,970
+X هالوجينيعني CL VR U واضح هذه العملية بنسميها
+
+98
+00:08:04,970 --> 00:08:09,130
+الهالوجينيشن الهالوجينيشن اللي بده يضيف إيش لازم
+
+99
+00:08:09,130 --> 00:08:13,230
+يكون موجبة اللي بده يضيف عشان يعمل الإبدال يعني
+
+100
+00:08:13,230 --> 00:08:17,390
+اللي بده يستم في الإبدال ممكن تتم إضافة أو إبدال
+
+101
+00:08:17,390 --> 00:08:22,970
+نيترو جروب و النيترو إيش بتلاحظوها هنا موجبة
+
+102
+00:08:22,970 --> 00:08:28,660
+العمليةنيتراشن بدل الأكشن نيترو نيتراشن بكس
+
+103
+00:08:28,660 --> 00:08:35,200
+هالوجيناشن ممكن تم ب HSO3 plus سالفونك أسد
+
+104
+00:08:35,200 --> 00:08:44,180
+سالفوناشن ممكن تم ب R plusالكليجروب الـ chelation
+
+105
+00:08:44,180 --> 00:08:49,320
+ممكن يتم بـ R C double bond O positive في النهاية
+
+106
+00:08:49,320 --> 00:08:52,940
+R C double bond O positive هذه اسمها مجموعة
+
+107
+00:08:52,940 --> 00:08:57,600
+الاسيليجروب اسيليشن الآن احنا هناخد هدولة بالتفصيل
+
+108
+00:08:58,500 --> 00:09:01,340
+يعني هذا الـ scheme العام أو الصورة الكلية
+
+109
+00:09:01,340 --> 00:09:04,140
+للتفاعلات بناخد الـ halogenation، بعدين الـ
+
+110
+00:09:04,140 --> 00:09:07,920
+nitration، sulfonation، alkylation، acylation،
+
+111
+00:09:07,920 --> 00:09:12,720
+يعني إيه؟ بناخدهم بالتفصيل وكيف الـ mechanism اللي
+
+112
+00:09:12,720 --> 00:09:16,460
+بتيم فيها التفاعل، كيف القالية اللي بتيم فيها
+
+113
+00:09:16,460 --> 00:09:24,560
+التفاعل خلينا نبدأ في ال halogenation مثلا، لو
+
+114
+00:09:24,560 --> 00:09:26,880
+إجينا نعمل تفاعل مع البرومين
+
+115
+00:09:29,240 --> 00:09:33,740
+بتكن تنتبه دائما و أبدا لل reagents كاملة يعني ما
+
+116
+00:09:33,740 --> 00:09:38,020
+تحفظوش بس الأشياء من طرفها يعني لما كنا زمان نفعل
+
+117
+00:09:38,020 --> 00:09:43,860
+ال cane مع ال bromine كنا نقول ال cane مع ال
+
+118
+00:09:43,860 --> 00:09:48,220
+bromine نكتب ع ساموش و بعدين نحط تحت عشان يمشي
+
+119
+00:09:48,220 --> 00:09:55,520
+التفاعل heat or light ضوء أو حرارة واضح؟ الآن هنا
+
+120
+00:09:55,520 --> 00:10:01,380
+مع البنزين لو عملنا bromineوكتبنا heat or light ما
+
+121
+00:10:01,380 --> 00:10:10,520
+بصيرش تفاعل لازم البرومين يكون معه مركب FeBr3 او
+
+122
+00:10:10,520 --> 00:10:14,760
+ممكن يكون aluminum Br3 او aluminum Cr3 بمشي خلاني
+
+123
+00:10:14,760 --> 00:10:21,180
+اقول انسب اشهر ال FeBr3واضح؟ هدولا الماديتين إشي
+
+124
+00:10:21,180 --> 00:10:26,900
+بيعملوا مع بعض، بتيجوا تتطلعوا تتذكرولي البرومين
+
+125
+00:10:26,900 --> 00:10:32,420
+نفسه جزء من ذاتين بروم زي بعض، هاي و ها نتخيل، هاي
+
+126
+00:10:32,420 --> 00:10:37,240
+بروم و هاي بروم، يتورى البرومين نفسه كجزء، بيكون
+
+127
+00:10:37,240 --> 00:10:42,370
+قطبي ولا غير قطبي؟بيكون غير قطب لإن هذي بروم و هذي
+
+128
+00:10:42,370 --> 00:10:46,290
+بروم و ال electronegativity متساوية مش زي ال HCL
+
+129
+00:10:46,290 --> 00:10:50,670
+انطارت ممكن يكون في فاندرفالز forces أو لندن
+
+130
+00:10:50,670 --> 00:10:53,930
+forces اللي هي حركة الإلكترونات يعني شوية تتركز
+
+131
+00:10:53,930 --> 00:10:58,650
+لكن بشكل عام هو nonpolar لإن الدارتين أشمالهم زي
+
+132
+00:10:58,650 --> 00:11:04,290
+بعض طب هذا الجزء ال nonpolar كيف أنا بدي أخليه
+
+133
+00:11:04,290 --> 00:11:11,220
+polar بحيث أنه أنا بدي أخد منه PR plusلأنه المطلوب
+
+134
+00:11:11,220 --> 00:11:19,200
+لكي يتم التفاعل بـ R Plusواضح؟ كيف بدي أكسر الجزء
+
+135
+00:11:19,200 --> 00:11:26,860
+اللي هو عبارة عن PR2 أخليه عبارة عن PR- و PR+, و
+
+136
+00:11:26,860 --> 00:11:32,460
+أاخد للتفاعل الـ PR+. واضح الفكرة؟ إذا أنا بدي
+
+137
+00:11:32,460 --> 00:11:38,460
+أكسر التماثل تبعه، بنجيب هذا المركب الـ FeBr3 الـ
+
+138
+00:11:38,460 --> 00:11:46,070
+FeBr3 لو لاحظناه لوحده هنازي هيك عبارة عن حديد
+
+139
+00:11:46,070 --> 00:11:52,470
+متصل بكم بروم؟ تلاتة بزامه متصل ب تلاتة برومين، كم
+
+140
+00:11:52,470 --> 00:11:58,250
+إلكترون حواليه؟ ستة الوضع الطبيعي للإلكترونات،
+
+141
+00:11:58,250 --> 00:12:02,230
+كداش يكونوا؟ تمانية، هذا في ناقص إلكترونات،
+
+142
+00:12:02,230 --> 00:12:08,180
+electron deficient أو electron poorإيش يعني
+
+143
+00:12:08,180 --> 00:12:13,160
+electron deficient أو poor؟ عنده نقص أو فقر أو عوز
+
+144
+00:12:13,160 --> 00:12:16,560
+في الإلكترونات الأشياء اللي عندها نقص في
+
+145
+00:12:16,560 --> 00:12:21,300
+الإلكترونات حسب تعريف Lewis للأحمض والقواعد عبارة
+
+146
+00:12:21,300 --> 00:12:26,960
+عن Lewis acid ولا Lewis base Lewis acid acid is
+
+147
+00:12:26,960 --> 00:12:31,700
+electron acceptor بده إلكترونات وال base is
+
+148
+00:12:31,700 --> 00:12:36,900
+electron donor بتاعة الإلكترونات إذا هذا عبارة عن
+
+149
+00:12:38,090 --> 00:12:47,270
+Lewis أسد أسد أسد
+
+150
+00:12:47,270 --> 00:12:49,290
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+151
+00:12:49,290 --> 00:12:49,290
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+152
+00:12:49,290 --> 00:12:50,910
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+153
+00:12:50,910 --> 00:12:52,970
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+154
+00:12:52,970 --> 00:12:55,830
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+155
+00:12:55,830 --> 00:13:04,850
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أس
+
+156
+00:13:05,550 --> 00:13:10,430
+واضح؟ إذا وجود هذا الـ Lewis acid اللي بحاجة إلى
+
+157
+00:13:10,430 --> 00:13:15,830
+PR رابعة هو اللي بيخدمني في التفاعل لأنه بيعمل
+
+158
+00:13:15,830 --> 00:13:22,270
+polarization أو استخطاف بيسحب من الـ PR2 PR خلّيني
+
+159
+00:13:22,270 --> 00:13:26,550
+أقول مع with its pair of electrons and it leaves a
+
+160
+00:13:26,550 --> 00:13:32,070
+positive bromine بيسيبلي bromine موجة هذا ال
+
+161
+00:13:32,070 --> 00:13:35,680
+bromine الموجة بالأن هو اللي بتفاعليعني في الـ
+
+162
+00:13:35,680 --> 00:13:39,000
+slide الجاية هتلاحظوا أنه بدأنا ببرومين مجبرة في
+
+163
+00:13:39,000 --> 00:13:43,640
+حد بدى عودي يسألنا من وين إجا؟ شوفنا من وين إجا،
+
+164
+00:13:43,640 --> 00:13:53,020
+بمساعدة الـ Lewis acid الـ FABR3 الآن
+
+165
+00:13:53,020 --> 00:13:57,520
+هذا الـ PR positive أول ما بيجي عندى خلينا نتخيل
+
+166
+00:13:57,520 --> 00:14:02,760
+أنه هنا كانت فيه double bond واضح؟ وفيه هيدروجين
+
+167
+00:14:03,560 --> 00:14:06,720
+هذه الـ double bonds إلكترونة و جايها موجة .. إيش
+
+168
+00:14:06,720 --> 00:14:13,480
+بتعمل؟ بتعمل رابطة معه، هيها إذا اتحركت واحدة من
+
+169
+00:14:13,480 --> 00:14:17,720
+الـ double bonds إزاي كنت بتكون تتخيل؟ اتحركت
+
+170
+00:14:17,720 --> 00:14:23,280
+واحدة من الـ double bonds و عملت رابطة مع البرومين
+
+171
+00:14:23,280 --> 00:14:30,620
+لما اتحركت هذه الـ double bonds شو سابت مكانها؟هذا
+
+172
+00:14:30,620 --> 00:14:34,900
+الـ carbocation مش ضروري يظل ثابت مكانه، ممكن يعمل
+
+173
+00:14:34,900 --> 00:14:38,760
+resonance، بمعنى لو هات اتحركت زي هيك، وين هيصير
+
+174
+00:14:38,760 --> 00:14:42,740
+الموجة؟ على هذا الموقع، لو هات اتحركت زي هيك، وين
+
+175
+00:14:42,740 --> 00:14:47,580
+هصير الموجة؟ على هذا الموقع، اذا انا عمالة في عنده
+
+176
+00:14:49,060 --> 00:14:53,860
+positive charge in resonance متنقلة بين أكتر من
+
+177
+00:14:53,860 --> 00:14:56,840
+مكان، معناه ذلك هذي positive charge stable ولا
+
+178
+00:14:56,840 --> 00:15:01,020
+unstable؟ بنتحر
+
+179
+00:15:01,020 --> 00:15:06,520
+بعدين ال resonance أساسي stability، مظبوط ولا لأ؟
+
+180
+00:15:06,520 --> 00:15:10,120
+الاشي لما بيكون متنقل بين أكتر من شغل الحمل إذا
+
+181
+00:15:10,120 --> 00:15:18,010
+توزعماذا نقول؟ الحمل إذا توزع ان شال و هذا حمل
+
+182
+00:15:18,010 --> 00:15:23,290
+موزع على تلت أماكن إذا ليست شحنة مركزة شحنة موزعة
+
+183
+00:15:23,290 --> 00:15:29,130
+بال resonance إذا هذا stable واضح؟ الآن عشان يكتمل
+
+184
+00:15:29,130 --> 00:15:33,570
+التفاعل .. عشان يكتمل التفاعل كل اللي بدو يصير أنه
+
+185
+00:15:33,570 --> 00:15:39,390
+تفقد هذه الـ H plus لحالها وهذه ترد تتحرك هنا
+
+186
+00:15:42,760 --> 00:15:47,420
+واضح؟ طبعا إنتوا هتيجيوا تسأله فقدت ال H plus على
+
+187
+00:15:47,420 --> 00:15:51,420
+العين و الرأس وين بدها تروح ال H plus؟ هتظل هكذا و
+
+188
+00:15:51,420 --> 00:15:58,760
+إحنا موجبة؟ لأ بتروح في PR minus لزقة حلوين في ال
+
+189
+00:15:58,760 --> 00:16:08,820
+FEPR 3 صارت FEPR 4 بتردده لما تيجي ال H plus بتقول
+
+190
+00:16:08,820 --> 00:16:09,760
+أنا بد ال PR
+
+191
+00:16:28,370 --> 00:16:29,810
+هيرجع مرة تانية
+
+192
+00:16:33,100 --> 00:16:37,120
+هنرجع للـ slide هيرجع مرة تانية مع جزء البرومين
+
+193
+00:16:37,120 --> 00:16:42,680
+ويعمل نفس الكلام ياخد منه PR- ويسيب لبر بوزيتف إذا
+
+194
+00:16:42,680 --> 00:16:48,960
+كأنه أنا البرومين يطلع الموجبة و بعدين السالب في
+
+195
+00:16:48,960 --> 00:16:53,120
+نهاية التفاعل بيرود ياخد هال إيش الـ H plus ويرجع
+
+196
+00:16:53,120 --> 00:16:56,420
+هذا في EPR3 و بعيد الكرة و بعيد الكرة و بعيد الكرة
+
+197
+00:16:56,420 --> 00:17:00,580
+و بعيد الكرة هذا هو اللي عملتش
+
+198
+00:17:02,440 --> 00:17:09,420
+الـ Catalyst هذا هو عمل الـ Catalyst إنه بكمية
+
+199
+00:17:09,420 --> 00:17:15,760
+قليلة بيكون موجود و بيبقى .. يعيد التفاعل يعيد
+
+200
+00:17:15,760 --> 00:17:21,820
+التفاعل يعيد التفاعل إذا حقيقة محصلة التفاعل لو
+
+201
+00:17:21,820 --> 00:17:25,700
+أنا في نهاية التفاعل بدي أشوف إيش المحصلة الـ
+
+202
+00:17:25,700 --> 00:17:33,240
+FeBr3 بطلع زي ما هو إذا صار عندى بدل الفنزينبرومو
+
+203
+00:17:33,240 --> 00:17:40,800
+بنزين زائد HBR يعني كأنا بنقول بنزين زائد PR2 في
+
+204
+00:17:40,800 --> 00:17:46,860
+وجود الـFeBr3 برومو بنزين زائد HBR، واضح؟ بس إحنا
+
+205
+00:17:46,860 --> 00:17:50,920
+قعدت شوفنا التفاصيل كيف بيتم التفاعل، الـmechanism
+
+206
+00:17:50,920 --> 00:17:55,620
+of the reaction وشوفنا إن ال reaction هنا بيمشي
+
+207
+00:17:55,620 --> 00:17:57,440
+بـelectrophilic aromatic
+
+208
+00:18:04,180 --> 00:18:09,000
+الان اللى فهم هذا الكلام هيلاحظ انه بعد هيك باقى
+
+209
+00:18:09,000 --> 00:18:16,560
+التفاعلات بتصير تقريبا شبيهة جدا، يعني بنقدر نمشي
+
+210
+00:18:16,560 --> 00:18:20,420
+أسرع، واضح؟ بنقدر نمشي في الشارع أسرع
+
+211
+00:18:23,210 --> 00:18:28,810
+مثلًا لو بدنا نيجي نقول الـ Cl2 برضه بنستعمله Cl2
+
+212
+00:18:28,810 --> 00:18:33,430
+مع FeCl3 بطلع Cl positive و double bond و هد بتعمل
+
+213
+00:18:33,430 --> 00:18:38,490
+resonance و نفس الكلام لو قولنا ال I2 بنستعمله
+
+214
+00:18:38,490 --> 00:18:44,050
+cover إكلورايد في نهاية هدولة بتطلعوله I positive
+
+215
+00:18:44,050 --> 00:18:47,650
+و بتضيف ال I positive و بيعمل resonance تفقد ال H
+
+216
+00:18:47,650 --> 00:18:55,170
+plus واضح؟ سهل عملية سهلةالان لو اجينا ل ال
+
+217
+00:18:55,170 --> 00:19:00,670
+nitration لو اجينا ل ال nitration لو ضفنا على
+
+218
+00:19:00,670 --> 00:19:08,290
+البنزين nitric acid لحاله مابصيرش تفاعل يعني لو
+
+219
+00:19:08,290 --> 00:19:14,290
+جيبت بنزين و حطيت فوق السهم بس nitric acid هاي
+
+220
+00:19:14,290 --> 00:19:21,780
+بنزين و بتحط فوق السهم ايش؟HNO3 نيتريك أسد لحاله
+
+221
+00:19:21,780 --> 00:19:26,920
+ما بيصيرش تفاعل عشان أعمل نيتريشن لازم أضيف نيتريك
+
+222
+00:19:26,920 --> 00:19:34,060
+أسد مع سالفاريك أسد H2SO4 لازم أضيف هدولة التنتين
+
+223
+00:19:34,060 --> 00:19:38,720
+مع بعضاللي بدأت تكمل معادلة جيوب سؤال امتحان لازم
+
+224
+00:19:38,720 --> 00:19:46,760
+تكتب ليه لـNitration HNO3 مع H2SO4 الآن في الخطوة
+
+225
+00:19:46,760 --> 00:19:51,400
+التحضيرية في الخطوة التحضيرية للتفاعل الـH2SO4 و
+
+226
+00:19:51,400 --> 00:19:55,180
+الـHNO3 هم اللي بتفاعلوا بينهم وبين بعض بيعطوني
+
+227
+00:19:55,180 --> 00:20:00,840
+H2O زي HNO2 plus أنا اللي بهمني الـHNO2 plus اللي
+
+228
+00:20:00,840 --> 00:20:03,900
+هو الـelectrophile الآن إذا صار موجود
+
+229
+00:20:03,900 --> 00:20:10,150
+الـelectrophileخلاص انحلت المشكلة واضح؟ بنفس
+
+230
+00:20:10,150 --> 00:20:14,930
+المنطق السابق إذا خلطة الـ H2SO4 و الـ HNO3 هي
+
+231
+00:20:14,930 --> 00:20:20,330
+اللي بتطلع له الـ Electrophile الـ NO2 Plus هذا
+
+232
+00:20:20,330 --> 00:20:23,590
+الـ NO2 Plus لما اتفعل تتحرك Double Bond بيعمل
+
+233
+00:20:23,590 --> 00:20:27,770
+Carbocation ب Resonance و بعدين بيفقد H Plus
+
+234
+00:20:27,770 --> 00:20:31,410
+بيعطينا Nitro مش فيها المشكلة
+
+235
+00:20:34,510 --> 00:20:40,670
+طيب، لو إجينا لـ Sulphonation، كيف بنضيف الـ
+
+236
+00:20:40,670 --> 00:20:48,610
+Sulphonic Acid؟ اللي بنحطه حقيقة على السهم H2SO4،
+
+237
+00:20:48,610 --> 00:20:53,810
+الـ sulphuric acid، بس بيقولوا عنه effumingfuming
+
+238
+00:20:53,810 --> 00:20:57,370
+sulphuric acid إيش يعني fuming sulphuric acid؟
+
+239
+00:20:57,370 --> 00:21:01,890
+fumes يعني أبخرة وfume hood اللي هو خزانة الأبخرة
+
+240
+00:21:01,890 --> 00:21:04,670
+اللي في المختبر اللي بتشفط البخار ال fuming هو
+
+241
+00:21:04,670 --> 00:21:10,030
+عبارة عن sulphuric acid وفيه كمية إضافية من غاز ال
+
+242
+00:21:10,030 --> 00:21:15,150
+S O 3 اللي هو أساسا اللي لما بندوبهبالميه بيعمل
+
+243
+00:21:15,150 --> 00:21:18,450
+sulfuric acid بتذكرين انتوا كيف بنحضر ال sulfuric
+
+244
+00:21:18,450 --> 00:21:24,870
+acid؟ بندوب S O 3 in water و لما بدنا نعمل ال
+
+245
+00:21:24,870 --> 00:21:34,170
+sulfurous acid ال H 2 S O 3 نراجع
+
+246
+00:21:34,170 --> 00:21:45,930
+شوية كيميا S O 3 زائد H 2 O و S O 2 زائدH2O الـ
+
+247
+00:21:45,930 --> 00:21:52,590
+SO3 مع الـ H2O شو بيعطينا؟ الحمض الكابريتيك H2SO4
+
+248
+00:21:52,590 --> 00:21:56,850
+إذا من ثالث أكسيد الكابريت مع الميه بطلع الـ H2SO4
+
+249
+00:21:56,850 --> 00:21:59,890
+H2SO3
+
+250
+00:21:59,890 --> 00:22:05,530
+الـ Sulphurous و Sulphuric Sulphuric Acid و
+
+251
+00:22:05,530 --> 00:22:09,190
+Sulphurous Acid فالخلاصة إن إحنا هنا لما بنستعمل
+
+252
+00:22:09,190 --> 00:22:15,330
+نستعمل H2SO4 مع غازاس او ثري يعني بيكون ال
+
+253
+00:22:15,330 --> 00:22:20,850
+sulfuric acid لما نفتح البوتل تبعه بيدخل محطوط فيه
+
+254
+00:22:20,850 --> 00:22:26,790
+كمية ايش زائدة من الاس او ثري طيب خلينا قبل ما
+
+255
+00:22:26,790 --> 00:22:30,270
+نمحي هذه نقولكوا هذا المعادلة بإيش بتذكركوا
+
+256
+00:22:30,270 --> 00:22:34,770
+التانية بلاش يقولوا
+
+257
+00:22:34,770 --> 00:22:44,120
+ايوة بإيش بالظبط ال acid rainالأمطار الحامضية لأن
+
+258
+00:22:44,120 --> 00:22:49,060
+المصانع .. المصانع بتطلع أبخرة SO2 .. أبخرة الـ
+
+259
+00:22:49,060 --> 00:22:54,280
+SO2 مع الميال في الجو والسحاب بتعمل H2SO3 هذا اللي
+
+260
+00:22:54,280 --> 00:22:57,520
+بنزل على الشجر و بيموته اللي بنسميه الـ acid rain
+
+261
+00:22:57,520 --> 00:23:02,520
+ال acid rain أو المطر الحامضي أو على المباني على
+
+262
+00:23:02,520 --> 00:23:06,980
+الحجر الجيري و المباني و ال .. الظواهر اللي بتصير
+
+263
+00:23:06,980 --> 00:23:10,520
+.. اكيد بتاعة ال .. ال acid rain
+
+264
+00:23:14,560 --> 00:23:21,140
+إذا خلطة ال H2SO4 و ال S O3 هي اللي بتطلع ليه؟ ال
+
+265
+00:23:21,140 --> 00:23:29,760
+S O3 H كلها كلها S O3 H بتكون positive و لا عن S
+
+266
+00:23:29,760 --> 00:23:34,780
+double bond O double bond O OH و من هنا بتتفاعل
+
+267
+00:23:34,780 --> 00:23:38,060
+واضح؟
+
+268
+00:23:38,060 --> 00:23:41,560
+أنتم بتذكرين كيف شكل ال sulfuric acid في الكيميا
+
+269
+00:23:41,560 --> 00:24:04,650
+ولا لأ؟التفصيل اللي هو الـ Sulphuric acid الواضح؟
+
+270
+00:24:04,650 --> 00:24:07,930
+هذا اللي هو اللي بيكون الـ Sulphur هنا ال positive
+
+271
+00:24:07,930 --> 00:24:12,610
+وهو اللي بيجي يتفاعلهو اللي بدو يجي يتفاعل
+
+272
+00:24:12,610 --> 00:24:19,910
+الإلكترونات بتتحرك عليه وبنفس المنطق بتتم استكمال
+
+273
+00:24:19,910 --> 00:24:26,010
+التفاعل بنفس المنطق بتتم عملية استكمال التفاعل
+
+274
+00:24:26,010 --> 00:24:30,390
+بنحصل على الـ Sulphonic acid هذا المركب اللي فيه
+
+275
+00:24:30,390 --> 00:24:38,450
+SO3H بيسموه إيش Sulphonic acid Sulphonic acid
+
+276
+00:24:40,460 --> 00:24:44,120
+أو مرات بكتبوا بنزين salphonic acid حر ينام مش
+
+277
+00:24:44,120 --> 00:24:55,720
+مشكلة بنجي
+
+278
+00:24:55,720 --> 00:25:03,140
+لتفاعل إضافي كيف نحط R group طبعا بدي ال R تكون
+
+279
+00:25:04,620 --> 00:25:09,200
+بوزيتف انا اتفقت هذه positive is a must لابد منها
+
+280
+00:25:09,200 --> 00:25:17,180
+لو جيبنا مثلا CH3Cl اللي هي عبارة عن RCl مع
+
+281
+00:25:17,180 --> 00:25:20,860
+ألومينيوميكلورايد الألومينيوميكلورايد لاحظوا برضه
+
+282
+00:25:20,860 --> 00:25:26,690
+لويسالوث أسد لأنه كام كلور متصل فيه؟ تلاتة، إذا
+
+283
+00:25:26,690 --> 00:25:30,030
+الألمنيوم عادسة إلكترونات بده إلكترونات،
+
+284
+00:25:30,030 --> 00:25:35,690
+فالألمنيوم الكلورايد بيسحب الكلورين مع إلكترونات
+
+285
+00:25:35,690 --> 00:25:39,810
+الرابطة على جهته، كل هذا الكلام بناشيه، أنا إيش
+
+286
+00:25:39,810 --> 00:25:45,030
+اللي بديه؟ إنه عمل polarization للجزء، خلال الـCH3
+
+287
+00:25:45,030 --> 00:25:49,150
+positive، خلال الـCH3 positive، هذا الـCH3
+
+288
+00:25:49,150 --> 00:25:54,150
+positive، هذا كله أنا؟ اتفقت؟إنه مش مهم عندي المهم
+
+289
+00:25:54,150 --> 00:25:58,750
+إنه بقدر أخد ال CH3 positive عطول إذا أخدناها
+
+290
+00:25:58,750 --> 00:26:06,890
+التفاعل بيصير straightforward، تلقائي، واضح؟ إذا
+
+291
+00:26:06,890 --> 00:26:12,670
+إيش الشرط لإضافة ال L-Kilogram لما أنا بفعل RCL
+
+292
+00:26:12,670 --> 00:26:20,250
+ولا RX؟وجود aluminium X3 عشان يسحب الـ X مع
+
+293
+00:26:20,250 --> 00:26:26,130
+إلكتروناتها ويسيب له الـ positive R واللي بدها
+
+294
+00:26:26,130 --> 00:26:31,510
+تتفاعل هي الـ positive R ممكن تكون CH3 ممكن تكون
+
+295
+00:26:31,510 --> 00:26:37,690
+إثل ممكن تكون بروبل المعادلة عامة يعني مش الزام بس
+
+296
+00:26:37,690 --> 00:26:43,390
+بالـCH3 لأ هي المعادلة بنقدر نعتبرها مع Rالمعادلة
+
+297
+00:26:43,390 --> 00:26:50,550
+نقدر نعتبرها معارض وبهيك بتتم عملية الـ alkylation
+
+298
+00:26:50,550 --> 00:26:58,470
+الـ alkylation اللي هو التفاعل مع الكل جروب يعني
+
+299
+00:26:58,470 --> 00:27:01,970
+ألمنيوم بي آر ثري أو إش .. لأ هو المناسب و سعره
+
+300
+00:27:01,970 --> 00:27:05,970
+معقول يستعمل بهذا التفاعل ألمنيوم كلورايد ألمنيوم
+
+301
+00:27:05,970 --> 00:27:06,570
+كلورايد
+
+302
+00:27:13,620 --> 00:27:19,200
+الآن هنا احنا حاطينلكم بعض ال limitations اللي هو
+
+303
+00:27:19,200 --> 00:27:24,280
+محددات لـ Frédéric Raft's alkylation طبعا بيسموه
+
+304
+00:27:24,280 --> 00:27:28,060
+نسبة للعالم أو للعلماء Frédéric Raft هذي ال
+
+305
+00:27:28,060 --> 00:27:32,520
+alkylation شو بيسموها؟ Frédéric Raft's alkylation
+
+306
+00:27:32,520 --> 00:27:36,820
+على حسب الناس اللي اشتغلوا الشغل الآن في عندى بعض
+
+307
+00:27:36,820 --> 00:27:43,510
+المشاكل اللي ممكن بدنا نواجههاوهي أن التفاعل بتتم
+
+308
+00:27:43,510 --> 00:27:51,310
+مع الـ RCl بس ما بتتمش مع الـ ArCl ولا مع الـ
+
+309
+00:27:51,310 --> 00:27:56,790
+Vinyl Cl الـ Ar بمعنى أنه لو كان عندى حلقة بنزين
+
+310
+00:27:56,790 --> 00:28:00,870
+تانية فيها Cl هل يا تورا ال .. ال aluminium
+
+311
+00:28:00,870 --> 00:28:03,930
+chloride بياخد من البنزين التانية لكلورة و
+
+312
+00:28:03,930 --> 00:28:08,790
+بيسيبليها موجبة؟لأ، لو كان عندى برضه vinyl
+
+313
+00:28:08,790 --> 00:28:14,070
+اكلورايد الـ vinyl متذاكرينه؟ اه، يعني هنا الـ RCl
+
+314
+00:28:14,070 --> 00:28:22,170
+هي معروفة من R مثل، إثل، بروبل، إش ما كان الـ ArCl
+
+315
+00:28:22,170 --> 00:28:28,050
+اللى هو aromatic يعني بنزين أو من جماعة البنزين
+
+316
+00:28:28,050 --> 00:28:34,370
+مشتقاته هنا ممكن أنه تفقد الـCl ويبقى عندى R
+
+317
+00:28:35,140 --> 00:28:39,300
+positive مافيش عندى اي مشكلة هنا لأ مابصيرش
+
+318
+00:28:39,300 --> 00:28:45,960
+التفاعل واضح؟ و هنا CL هل يا تورا يمكن أن تفقد من
+
+319
+00:28:45,960 --> 00:28:51,040
+هنا ال CL و يظل هذا positive لأ لأ مابصيرش اذا
+
+320
+00:28:51,040 --> 00:28:56,080
+التفاعل بس بيصير مع القلك ال highlights مابصيرش مع
+
+321
+00:28:56,080 --> 00:29:03,180
+القرق ال highlights و لا بيصير مع الدفين الهيمان
+
+322
+00:29:04,520 --> 00:29:12,700
+واضحة هذه النقطة هذه نقطة مهمة ال Rpg limitation
+
+323
+00:29:12,700 --> 00:29:19,060
+أو محدد تاني لهذا التفاعل بيعمل مشكلة ان حلقة
+
+324
+00:29:19,060 --> 00:29:25,280
+البنزين لو كان عليها بعض المجموعات المثبتة بنسميها
+
+325
+00:29:25,280 --> 00:29:31,520
+أو الساحبة للإلكترونات بيصير التفاعل بطيء تقريبا
+
+326
+00:29:31,520 --> 00:29:37,020
+ما بيمشيشوالمجموعات يعني لو كان عليها مجموعة أصلاً
+
+327
+00:29:37,020 --> 00:29:43,170
+وبيضيف كمان الكلواضح؟ لو كان عليها أصلاً مجموعة
+
+328
+00:29:43,170 --> 00:29:46,590
+وغير المجموعة بتضيف كمان الكلوة اللي هنعود نتوسع
+
+329
+00:29:46,590 --> 00:29:50,030
+فيه هذه المجموعات اللي .. اللي لو كانت موجودة
+
+330
+00:29:50,030 --> 00:29:53,990
+أصلاً على البنزين وبثبت التفاعل الـ Nitro،
+
+331
+00:29:53,990 --> 00:29:58,650
+السيانو، الـSO3H، الـCHO، الـCOR، الـCOH، الـC
+
+332
+00:29:58,650 --> 00:30:04,150
+double bond OR والـNR3 هذا النقطة بالذات هنرجعلها
+
+333
+00:30:04,150 --> 00:30:09,540
+مرة ثانيةإنه في مجموعات لو كانت أصلاً موجودة على
+
+334
+00:30:09,540 --> 00:30:14,060
+الحلقة بتعمل deactivation، deactivation يعني بتثبت
+
+335
+00:30:14,060 --> 00:30:20,180
+الحلقة وتبطل الحلقة تتفاعل، واضح؟ الشيء التاني أنه
+
+336
+00:30:20,180 --> 00:30:25,180
+لو ماكنش، بس كانت الكل جروب وإجي اتفاعلت مع مثل
+
+337
+00:30:25,180 --> 00:30:29,640
+الكلوريد، ممكن التفاعل مش بس يحط مثل واحدة، ممكن
+
+338
+00:30:29,640 --> 00:30:34,590
+يحط إتين أو تلاتةيعني يعمل multiple substitution
+
+339
+00:30:34,590 --> 00:30:39,550
+يعني يضيف أكثر من مجموعة في هذه الحالة كأنه بعد ما
+
+340
+00:30:39,550 --> 00:30:46,190
+يضيف أول مثل الحلقة إيش بتصير؟ Activatedمنشطة بحيث
+
+341
+00:30:46,190 --> 00:30:50,490
+أنها تضيف المجموعة التانية والتالتة إذن كأنه هناخد
+
+342
+00:30:50,490 --> 00:30:55,270
+بعد شوية أنه في ظاهرة اسمها activation حلقة منشطة
+
+343
+00:30:55,270 --> 00:31:00,290
+بدأت تتفاعل أكتر وفي deactivation في مجموعات بتعمل
+
+344
+00:31:00,290 --> 00:31:04,070
+activation بتشجع على المزيد من التفاعلات وفي
+
+345
+00:31:04,070 --> 00:31:09,170
+مجموعات بتعمل deactivation بتوقف التفاعلات واضح
+
+346
+00:31:09,170 --> 00:31:10,170
+هذا ال point؟
+
+347
+00:31:15,990 --> 00:31:21,450
+في عندنا كمان تفاعل اللي هو التفاعل مع الacetyl
+
+348
+00:31:21,450 --> 00:31:27,510
+groups انتوا مارة عليكم يمكن مجموعة إيش؟ الacetyl
+
+349
+00:31:27,510 --> 00:31:34,170
+اه متذكرين شو هي الacetyl؟ ال CH3C double bond اه
+
+350
+00:31:34,170 --> 00:31:42,270
+شو اسمها؟ Acetyl انتبهوا معايا في اسم عائلة وفي
+
+351
+00:31:42,270 --> 00:31:48,710
+اسم فرددايماً أسماء العائلات بنكون محددين شو
+
+352
+00:31:48,710 --> 00:31:54,080
+المجموعة اللي بنستخدم Rبنستخدم R يعني لو كنا
+
+353
+00:31:54,080 --> 00:32:00,820
+كاتبين احنا R C double bond O CL هذه ال R C double
+
+354
+00:32:00,820 --> 00:32:05,740
+bond O اسمها Ethyl group يمكن ال R فيها تكون مثل
+
+355
+00:32:05,740 --> 00:32:12,560
+ممكن إثل ممكن بروبل ممكن بيوتل أيه ان كانت واضح؟
+
+356
+00:32:12,560 --> 00:32:16,960
+اذا هذه المجموعة العامة ال general group شو اسمها؟
+
+357
+00:32:17,540 --> 00:32:24,960
+acetyl group الـ A لو كانت حالة خاصة الـ R مثل ..
+
+358
+00:32:24,960 --> 00:32:33,860
+شو بيصير اسم المجموعة؟ Acetyl واضح الفكرة؟ فالـ
+
+359
+00:32:33,860 --> 00:32:39,920
+Acetyl هي مجموعة خاصة حُددت فيها الـ R بإنها
+
+360
+00:32:42,590 --> 00:32:48,730
+واضح؟ فهذه أسل وهذه أستل الأسل المجموعة العامة
+
+361
+00:32:48,730 --> 00:32:53,330
+الآن إحنا لما بندرس التفاعل بندرسه بشكل عام مع كل
+
+362
+00:32:53,330 --> 00:32:58,910
+أنواع ال R ولذلك بنسمي التفاعل افريدي ل crafts
+
+363
+00:33:00,610 --> 00:33:05,170
+acetylation لو كنت بأقصد أني أخلي ال R مثل ممكن
+
+364
+00:33:05,170 --> 00:33:10,550
+أقول وجهتها Acetylation واضح؟ إذا ال Acetyl هي ال
+
+365
+00:33:10,550 --> 00:33:14,950
+general group اللي بنكتب فيها R ال Acetyl هي ال
+
+366
+00:33:14,950 --> 00:33:20,890
+specific group و ال R is CH3على أي حال، هذا
+
+367
+00:33:20,890 --> 00:33:25,430
+التفاعل أيضًا بالزمن فيه positive كيف بجيب ال
+
+368
+00:33:25,430 --> 00:33:29,670
+positive؟ بجيب افاعل مثلًا كمثال الـ Acetachloride
+
+369
+00:33:29,670 --> 00:33:33,170
+مع الـ Aluminium Chloride الآن الـ Aluminium
+
+370
+00:33:33,170 --> 00:33:40,670
+Chloride بدي أخد Cl مع إلكتروناتها، شو هيخليلها
+
+371
+00:33:40,670 --> 00:33:45,050
+على الكربون اللي هي موجب؟ هذا الموجب طبعًا ممكن
+
+372
+00:33:45,050 --> 00:33:49,490
+ينتقل بين الكربون والأكسجنيعني لو اتحرك زوج
+
+373
+00:33:49,490 --> 00:33:52,970
+إلكترونات من هنا يعني من الرابط التلاثية بيصير
+
+374
+00:33:52,970 --> 00:33:56,250
+الموجب على الـ Oxygen لو ضالت زي ما فقدت، بيكون
+
+375
+00:33:56,250 --> 00:33:59,250
+على الـ Carbon هو هنرسم أحد الـ Resonance
+
+376
+00:33:59,250 --> 00:34:03,210
+Structures له بشكل عام تعتبره في الأساس وين الـ
+
+377
+00:34:03,210 --> 00:34:07,610
+Positive موجود؟ على الـ Carbon يعني بمثل هذا الشكل
+
+378
+00:34:07,610 --> 00:34:11,250
+وفقدت الـCl، ضالت الـ Carbon positive الآن هذا الـ
+
+379
+00:34:11,250 --> 00:34:14,190
+Carbon الـ Positive هذا الـ Carbon الـ Positive
+
+380
+00:34:14,190 --> 00:34:22,270
+اللي هناوهي هتجي تتفاعل مع الحلقة بنفس المنطقة الـ
+
+381
+00:34:22,270 --> 00:34:26,630
+bond من الحلقة اتحركت عليها على الكربون الـ
+
+382
+00:34:26,630 --> 00:34:31,430
+positive و بعدين تفقد الهيدروجين إذا التفاعل بتم
+
+383
+00:34:31,430 --> 00:34:35,570
+بنفس الطريقة لاحظوا في جميع التفاعلات أنا عمال
+
+384
+00:34:35,570 --> 00:34:40,410
+الهدف الأساسي اللي بيضمنني أن التفاعل مشهي هو
+
+385
+00:34:40,410 --> 00:34:45,480
+تكوين الـ Electrophileوبشكل عام، في معظم الحالات
+
+386
+00:34:45,480 --> 00:34:49,640
+عامال عشان نكون الـ Electrophile شو كنا نضيف؟
+
+387
+00:34:49,640 --> 00:34:56,920
+Lewis acid مع الـ halogens ومع الـ الـ الـ RCL ومع
+
+388
+00:34:56,920 --> 00:35:02,980
+الـ Acyl halides في كل الأحوال، قاعدين نضيف احنا
+
+389
+00:35:02,980 --> 00:35:07,300
+Lewis acid عشان يكونلي الـ Electrophile اللي بدي
+
+390
+00:35:07,300 --> 00:35:12,860
+يعمل التفاعلبيكوّل ال electrified بيكوّل ال
+
+391
+00:35:12,860 --> 00:35:13,660
+electrified بيكوّل ال electrified بيكوّل ال
+
+392
+00:35:13,660 --> 00:35:13,660
+electrified بيكوّل ال electrified بيكوّل ال
+
+393
+00:35:13,660 --> 00:35:13,660
+electrified بيكوّل ال electrified بيكوّل ال
+
+394
+00:35:13,660 --> 00:35:14,240
+electrified بيكوّع ال electrified بيكوّع ال
+
+395
+00:35:14,240 --> 00:35:14,240
+electrified بيكوّع ال electrified بيكوّع ال
+
+396
+00:35:14,240 --> 00:35:14,300
+electrified بيكوّع ال electrified بيكوّع ال
+
+397
+00:35:14,300 --> 00:35:14,380
+electrified بيكوّع ال electrified بيكوّع ال
+
+398
+00:35:14,380 --> 00:35:14,440
+electrified بيكوّع ال electrified بيكوّع ال
+
+399
+00:35:14,440 --> 00:35:15,300
+electrified بيكوّع ال electrified بيكوّع ال
+
+400
+00:35:15,300 --> 00:35:18,360
+electrified بيكوّع ال electrified بيكوّع ال
+
+401
+00:35:18,360 --> 00:35:24,100
+electrified بيكوّع ال electrified بيكوّع
+
+402
+00:35:24,100 --> 00:35:30,540
+ال electrified
+
+403
+00:35:30,540 --> 00:35:34,560
+بيكوّع
+
+404
+00:35:34,560 --> 00:35:36,880
+ال electr
+
+405
+00:35:38,580 --> 00:35:42,000
+لأ الهيدروجين هذا فقط القائمة هو وين بده يروح
+
+406
+00:35:42,000 --> 00:35:46,560
+الهيدروجين هذا اللي بده يفقد تنسيش أنه الهيدروجين
+
+407
+00:35:46,560 --> 00:35:51,700
+هذا لما بده يطلع بده يكون عنده aluminium Cl3 مع Cl
+
+408
+00:35:51,700 --> 00:35:56,560
+إضافية minus ال H plus اللي بتطلع من هنا بدي أخد
+
+409
+00:35:56,560 --> 00:36:02,710
+ال Cl minus لأقنعة Clواضح؟ يعني الـ H بلس اللي
+
+410
+00:36:02,710 --> 00:36:07,670
+بشجعه على الفقد موجود الـ Cl ماينوس اللي ملتصقة
+
+411
+00:36:07,670 --> 00:36:11,250
+لحظيا في الالمنيوم الكلورايد فالـ Cl ماينوس بتاخد
+
+412
+00:36:11,250 --> 00:36:15,930
+الـ H بلس قبل الـ HCl شو رجع عنده؟ الومنيوم
+
+413
+00:36:15,930 --> 00:36:20,410
+الكلورايد، بعيد الدائرة، برجع عند الومنيوم
+
+414
+00:36:20,410 --> 00:36:29,070
+الكلورايد و بعيد الدائرةطيب الآن لو قلنا بدنا ننظر
+
+415
+00:36:29,070 --> 00:36:39,650
+لهذه الأمثلة ونقولكوا أكمل المعادلة لاحظوا
+
+416
+00:36:39,650 --> 00:36:46,370
+هذا التفاعل شو نوعه؟ Acetylation أو Acetylation
+
+417
+00:36:46,370 --> 00:36:51,610
+الألومنيوميكلورايد بدي ياخد الـCl يصير عند ال
+
+418
+00:36:51,610 --> 00:36:57,310
+Electrophile شو النتيجة؟تكوين الـ acetyl group،
+
+419
+00:36:57,310 --> 00:37:00,230
+لاحظوا بتكون مع عدد CL، بس احنا دايما في ال
+
+420
+00:37:00,230 --> 00:37:04,290
+organic بنركز على ال organic product، يعني مراتي
+
+421
+00:37:04,290 --> 00:37:07,330
+بنكتبش النواتج التانية، أنا بهمن ال organic
+
+422
+00:37:07,330 --> 00:37:12,710
+product اسم
+
+423
+00:37:12,710 --> 00:37:16,360
+الشهرة أسيتوفينون أخدناه المرة الماضيةيعني كان
+
+424
+00:37:16,360 --> 00:37:23,760
+ممكن تسميه أسيت البنزين عادي بس طالما إله اسم شمرة
+
+425
+00:37:23,760 --> 00:37:27,620
+أشهر بدك تسميه أسيتوفينون بدك تسميه أسيتوفينون
+
+426
+00:37:27,620 --> 00:37:31,460
+واضح؟ بدك تسميه أسيتوفينون الأن لاحظوا في المرة
+
+427
+00:37:31,460 --> 00:37:36,060
+التانية HNO3 وH2SO4 شوف كيف كتبت ال agents بدقة
+
+428
+00:37:36,060 --> 00:37:40,760
+نيتريشن نيتريشن NO2 في المرة التالتة
+
+429
+00:37:44,140 --> 00:37:47,300
+هالوجيناشن؟ بده يروح الالمنيوم الكلورايد، هذا
+
+430
+00:37:47,300 --> 00:37:51,880
+الكيلاشن، هذا مش هالوجيناشن، this reaction is
+
+431
+00:37:51,880 --> 00:37:56,020
+الكيلاشن، هذا ايزوبروبليكلورايد، لما ييجي
+
+432
+00:37:56,020 --> 00:38:00,000
+الالمنيوم الكلورايد وياخد هذه الكلورين، وين هيسيب
+
+433
+00:38:00,000 --> 00:38:04,860
+له ال positive؟ على الكاربون الوسطانية، محل ما
+
+434
+00:38:04,860 --> 00:38:07,040
+انشلت الـCl، محل ما بيتفاعل
+
+435
+00:38:09,680 --> 00:38:16,300
+محل ما انشالت ال CL محل ما بيتفعل بالظبط واضح؟ طيب
+
+436
+00:38:16,300 --> 00:38:20,480
+خلّينا ناخد أخر معادلة نكتبها بالقلم وننهي
+
+437
+00:38:20,480 --> 00:38:24,760
+المحاضرة اليوم لو يا تورا إجينا فعلنا مش مع هذا
+
+438
+00:38:24,760 --> 00:38:29,220
+المُركّب لو إجينا عملنا كمان سهم وحطينا هذا
+
+439
+00:38:29,220 --> 00:38:35,400
+المُركّب في وجود H plus بروبين
+
+440
+00:38:45,690 --> 00:38:52,290
+شو بده يعمل هنا؟لاحظوا هنا لما فقد من هذا المثال
+
+441
+00:38:52,290 --> 00:39:00,370
+الـCL، إيش صار عندى؟ CH2، CH موجبة، CH3 طيب، لما
+
+442
+00:39:00,370 --> 00:39:05,570
+أنا بحط و أخدناه في تفاعلات الإضافة للالكينز الكين
+
+443
+00:39:05,570 --> 00:39:11,390
+مع H Plus، إيش دائما و أبدا الخطوة الأولى؟ إضافة
+
+444
+00:39:11,390 --> 00:39:14,210
+الـH Plus على الـDouble bond وكسرها و تكوين
+
+445
+00:39:14,210 --> 00:39:21,180
+Carbocation إذا، هدول الاتنين شو بيعملوا مع بعض؟هي
+
+446
+00:39:21,180 --> 00:39:26,740
+الـ H ضافة هنا دي صارت CH3 وضافة على الـ Bromine
+
+447
+00:39:26,740 --> 00:39:30,100
+والكربوكاتين اتكون هنا نفس الكربوكاتين اللي هنا
+
+448
+00:39:30,100 --> 00:39:37,660
+ولا لأ؟ نفسه نفس الاتكون هنا ممكن نكونه من خلال
+
+449
+00:39:37,660 --> 00:39:41,980
+تفاعل البروبين مع الـ H Plus صار نفس الكربوكاتين
+
+450
+00:39:41,980 --> 00:39:47,400
+بكم اللي بيعطيني نفس النتيجةإذاً، هذا المُركّب
+
+451
+00:39:47,400 --> 00:39:52,240
+اللي أنتوا شايفينه الآن بقدر أحضره بأكتر من طريقة
+
+452
+00:39:52,240 --> 00:39:56,980
+ممكن أخد Iso-Propyl chloride مع Aluminium chloride
+
+453
+00:39:56,980 --> 00:40:02,660
+بيعطوني Iso-Propyl-Cation وممكن أخد بروبين مع H
+
+454
+00:40:02,660 --> 00:40:06,760
+Plus بيعطوني برضه Iso-Propyl-Cation، نفس الـCation
+
+455
+00:40:06,760 --> 00:40:10,740
+إذاً التفاعل هيكمل لنفس الناتج
+
+456
+00:40:12,310 --> 00:40:16,830
+التفاعل هيكمل لنفس الناتج، لو أخدت reaction of
+
+457
+00:40:16,830 --> 00:40:21,210
+benzene with isopropyl chloride in presence of
+
+458
+00:40:21,210 --> 00:40:24,930
+aluminium chloride or reaction of benzene with
+
+459
+00:40:24,930 --> 00:40:29,370
+propene in presence of H plus produces سميليا، شو
+
+460
+00:40:29,370 --> 00:40:35,150
+اسم المركب؟ انت رافعيدك، كنت بدك تجاوبي، شو اسمه
+
+461
+00:40:35,150 --> 00:40:37,610
+بس، احنا خلينا في اسمه؟
+
+462
+00:40:41,960 --> 00:40:47,620
+وأنا حد فيكوا أفطر حمص عليه كمون؟ اكيومين ال
+
+463
+00:40:47,620 --> 00:40:56,940
+isopropyl بنزين له اسم شهرة أخدناه اكيومين اكيومين
+
+464
+00:40:56,940 --> 00:41:00,120
+اسم الشهرة تبع ال isopropyl بنزين اتفضل أسألك
+
+465
+00:41:00,120 --> 00:41:08,940
+عشانك
+
+466
+00:41:08,940 --> 00:41:13,700
+غيبتي جابلها بحصةما غيبتيش؟ إذا نتذكر معاه .. إذا
+
+467
+00:41:13,700 --> 00:41:17,160
+نتذكر معاه لما باطيفه على الطرف شو نوع ال
+
+468
+00:41:17,160 --> 00:41:23,280
+carbocation اللي بتكونه؟ secondary carbocation ..
+
+469
+00:41:23,280 --> 00:41:27,140
+مظبوط ولا لأ؟ و لو تفتح هنا شو نوع ال carbocation
+
+470
+00:41:27,140 --> 00:41:39,450
+اللي بتكونه؟بريماري كاربو كاتاينو نختبر
+
+471
+00:41:39,450 --> 00:41:44,170
+ذكائكم ونعطيكم سؤال هوميرك للحصة القادمة
+
+472
+00:41:47,150 --> 00:41:52,230
+انتبهوا هذا الكلام انا متأكد ان الطالبات الممتازات
+
+473
+00:41:52,230 --> 00:41:55,370
+بالبسطه على هيك اسئلة انا متأكد ان الطالبات
+
+474
+00:41:55,370 --> 00:41:59,850
+الممتازات بالبسطه على هيك اسئلة الان لو جبنالكوا
+
+475
+00:41:59,850 --> 00:42:05,690
+في أكمل المعادلة هذا المركب CH2 double bond CH
+
+476
+00:42:05,690 --> 00:42:16,400
+حطينا هنا C وحطينا H وCH3 وCH3 وقلنا في وجودأتش
+
+477
+00:42:16,400 --> 00:42:24,020
+بلاس وهدولة موجودين في أتش بلاس مع البنزين إيش بده
+
+478
+00:42:24,020 --> 00:42:29,160
+يكون النتيجة؟
+
+479
+00:42:29,160 --> 00:42:34,840
+عشان
+
+480
+00:42:34,840 --> 00:42:38,260
+انتوا بس تكتبوا صحيح، بناعطيكوا الفكرة الفكرة كلمة
+
+481
+00:42:38,260 --> 00:42:41,100
+واللي بتقولي الكلمة هعطيها علامة على طول هالجيتها
+
+482
+00:42:41,100 --> 00:42:43,680
+هتنزلها على كشف الدرجات إيش الفكرة اللي في هذا
+
+483
+00:42:43,680 --> 00:42:48,070
+السؤال؟فى الرابط اللى .. ماجيبتوش الفكرة اللى
+
+484
+00:42:48,070 --> 00:42:52,730
+بتاخدوا عليها علامة علامة هذى مش ببلاش ايش الفكرة
+
+485
+00:42:52,730 --> 00:42:57,210
+اللى بهدى السؤال ان الحديث في الرابط اللى مش هايل
+
+486
+00:42:57,210 --> 00:43:10,230
+نلعب فى البنزينة فكرة
+
+487
+00:43:10,230 --> 00:43:11,090
+أخدناها
+
+488
+00:43:14,650 --> 00:43:22,890
+لأ لأ لأ لاتش بلس حطي فارقة خلصنا من هالموضوع انا
+
+489
+00:43:22,890 --> 00:43:26,750
+مش راضي اجاوبها احذروا ليش مش راضي اجاوبها لأنه
+
+490
+00:43:26,750 --> 00:43:29,410
+اذا جوابت أكلكوا هتزعلوا انكوا ضيعتوا أحاركوا
+
+491
+00:43:29,410 --> 00:43:35,090
+علامة هتزعلوا
+
+492
+00:43:36,060 --> 00:43:40,100
+مش مشكلة لأنه بعد هيك هيصير rearrangement أول ما
+
+493
+00:43:40,100 --> 00:43:44,420
+أضيف ال H plus هنا الكاربو كاتيون هنا secondary
+
+494
+00:43:44,420 --> 00:43:49,020
+مباشرة هيصير hydride shift هيصير الكاربو كاتيون
+
+495
+00:43:49,020 --> 00:43:57,570
+هنا وهذه هتشبك من هنا مش من هناواضح الفكرة؟ بيصير
+
+496
+00:43:57,570 --> 00:44:00,850
+rearrangement الكلمة اللى كنت بدى أسمعها منكوا
+
+497
+00:44:00,850 --> 00:44:04,850
+كلمة rearrangement أنه أنا ضفت ال H plus هنا وين
+
+498
+00:44:04,850 --> 00:44:10,370
+صار ال carbocation؟ secondary فى إمكانية تتحرك ال
+
+499
+00:44:10,370 --> 00:44:15,970
+H هذه ويصير ال carbocation tertiary ومحل ما صار ال
+
+500
+00:44:15,970 --> 00:44:21,940
+carbocation tertiary بيكون عندى إيش؟محل ما صار
+
+501
+00:44:21,940 --> 00:44:25,920
+الكربوكاتيون الـ tertiary بصير التفاعل، إذا هنا
+
+502
+00:44:25,920 --> 00:44:32,160
+صارت فكرة الـ rearrangementفي حالة الـ Alkyl
+
+503
+00:44:32,160 --> 00:44:35,740
+Halides بالمناسبة عاد الـ rearrangements هذه اللي
+
+504
+00:44:35,740 --> 00:44:38,980
+برضه هنا لو كنتوا بتفقدوا كلور مش ضروري من خلال
+
+505
+00:44:38,980 --> 00:44:43,880
+الالكين وعملة secondary و بإمكانه يتحول إلى
+
+506
+00:44:43,880 --> 00:44:48,760
+tertiary برضه بيصير rearrangement بمعنى لو كان هذا
+
+507
+00:44:48,760 --> 00:44:56,460
+المركب زيك CH2 CH3 خليني أقول و هذه CHCL و هنا COH
+
+508
+00:44:56,460 --> 00:45:05,400
+و CH3 و CH3وحطينا هنا الومنيوم كلورايت الومنيوم
+
+509
+00:45:05,400 --> 00:45:09,480
+كلورايت شو بدي اعمل؟ هيسحب السيارة ليكوّل السكاندر
+
+510
+00:45:09,480 --> 00:45:15,160
+كاربو كاتايل هذا بيعمل ال arrangement والنتيجة ان
+
+511
+00:45:15,160 --> 00:45:20,540
+التفاعل لا يتم مكان الكلور انما يتم هنا هذه الجملة
+
+512
+00:45:20,540 --> 00:45:23,840
+اللي قبل شوية انا امشيت عليها بسرعة اذا بتتذكروا
+
+513
+00:45:23,840 --> 00:45:27,740
+هنا اخر كلمة ايش كان مكتوب عندكم
+
+514
+00:45:32,500 --> 00:45:38,820
+إنه في ال alkylation لما بتكون carbocation و بده
+
+515
+00:45:38,820 --> 00:45:44,960
+يتفاعل لو صاحله احسن وضعه بيحسن ولا لأ؟ لو صاحله
+
+516
+00:45:44,960 --> 00:45:48,900
+يعمل rearrangement بيعمل ولا لأ؟ شكرا
+