diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b6e926a1ec963cd9a9f1c69a0bbcd87772d82261
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+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/-n566Oaohdc_raw.srt
@@ -0,0 +1,2092 @@
+1
+00:00:06,600 --> 00:00:12,560
+اليوم بنختتم ان شاء الله الفصل التالت هتلاحظوا انه
+
+2
+00:00:12,560 --> 00:00:18,220
+هنتكلم على reactions of alkynes تفاعلات الalkynes
+
+3
+00:00:18,220 --> 00:00:23,080
+و هتلاحظوا انه ان شاء الله هتكون بسيطة بالذات بعد
+
+4
+00:00:23,080 --> 00:00:28,520
+ما انتوا اتفهمتوا كويس تفاعلات الalkynes الان
+
+5
+00:00:28,520 --> 00:00:33,020
+الalkynes اللي فيها double bond كانت تفاعلها
+
+6
+00:00:33,020 --> 00:00:39,870
+الأساسيالـ addition الإضافة الalkynes أيضًا
+
+7
+00:00:39,870 --> 00:00:45,630
+تفاعلها الأساسي ال addition لأنه فيها triple bond
+
+8
+00:00:45,630 --> 00:00:51,670
+تقريبًا ال reagents اللي شفناهم بيتفاعلوا مع
+
+9
+00:00:51,670 --> 00:00:56,740
+الalkynes نفسهم بدنا نشوفهم كيف بيتفاعلوامع ال ال
+
+10
+00:00:56,740 --> 00:01:02,500
+kinds فعلى سبيل المثال ممكن ناخد ال addition of hx
+
+11
+00:01:02,500 --> 00:01:11,200
+hx يعني hcl او hbr to all kinds اللي لاحظوا انه
+
+12
+00:01:11,200 --> 00:01:19,260
+تفاعل ال hx لل ال kind بيضيف مرتين لان ال kind في
+
+13
+00:01:19,260 --> 00:01:25,660
+كام bubble bond تنتين تنتينغير الـ Sigma bond
+
+14
+00:01:25,660 --> 00:01:29,960
+الأصلية في أندت انتن بايبولز فبتتم عملية الإضافة
+
+15
+00:01:29,960 --> 00:01:35,780
+مرتين الإضافة الأولى بتضيف فيها HCl لأن لما بتضيف
+
+16
+00:01:35,780 --> 00:01:40,240
+HCl على مثل هذا الألكاين كيف بنتوقع تضيف
+
+17
+00:01:40,240 --> 00:01:44,940
+Markovnikov ولا Anti Markovnikov addition؟ بتضيف
+
+18
+00:01:44,940 --> 00:01:49,430
+Markovnikov additionواضح فهي زي ما بتلاحظوا في
+
+19
+00:01:49,430 --> 00:01:54,650
+عندي H إجت على هذه الذرع و CL الان هذا اللي بتكون
+
+20
+00:01:54,650 --> 00:02:00,610
+لما يكون عندى كمية زائدة من ال HCL مباشرة بستمر
+
+21
+00:02:00,610 --> 00:02:04,570
+التفاعل مرة تانية و بضيف كمان H تانية و كمان CL
+
+22
+00:02:04,570 --> 00:02:10,890
+تانية إذا في المحصلة بيصير عندى إضافتين HCL و كل
+
+23
+00:02:10,890 --> 00:02:16,650
+إضافة منهمMarkovnikov's addition واضح كل إضافة
+
+24
+00:02:16,650 --> 00:02:19,810
+منهم Markovnikov's addition كأنه بيجي هنا ذرتين
+
+25
+00:02:19,810 --> 00:02:25,910
+هيدروجين و بيجي هنا ذرتين كلورين ومثلها أيضا ال
+
+26
+00:02:25,910 --> 00:02:33,770
+HPR فال HPR وHCL بيضيفوا على حسب Markovnikov's
+
+27
+00:02:33,770 --> 00:02:38,550
+addition لكن two successive additions يعني إضافتين
+
+28
+00:02:38,550 --> 00:02:41,310
+متواليتين واضح
+
+29
+00:02:45,200 --> 00:02:49,960
+النوع التاني اللي أخدنا إضافة ال halogens إذا
+
+30
+00:02:49,960 --> 00:02:56,120
+متذكرين PR2 و CL2 برضه بنفس المنطق تماما ال
+
+31
+00:02:56,120 --> 00:03:01,660
+halogens بتضيف مرتين طبعا إنتوا متذكرين إن الإضافة
+
+32
+00:03:01,660 --> 00:03:07,070
+في ال halogens كانت Anti additionلكن لما بضيف كمان
+
+33
+00:03:07,070 --> 00:03:12,590
+مرة خلاص بيصير عندى تلتين PR و تلتين PR فبرتفع ال
+
+34
+00:03:12,590 --> 00:03:16,350
+halogens لما نضيف أفضل اشي بيضيف حقيقة لبرومين
+
+35
+00:03:16,350 --> 00:03:22,790
+بيصير عندى two successive additions مرتين بيضيف
+
+36
+00:03:22,790 --> 00:03:28,740
+لبرومبتكون عند اللي هي ال tetra bromocompounds
+
+37
+00:03:28,740 --> 00:03:31,860
+يعني لو انا بدي اجي في الامتحان اقولك و الله هي
+
+38
+00:03:31,860 --> 00:03:35,480
+tetra bromocompounds how can you prepare this
+
+39
+00:03:35,480 --> 00:03:39,560
+compound بدي يكون جزء من تفكيرك و لو كان عند
+
+40
+00:03:39,560 --> 00:03:46,060
+triple bond اعملت عليها اضافة برومين مرتين اعملت
+
+41
+00:03:46,060 --> 00:03:49,040
+عليها اضافة برومين على مرتين واضح
+
+42
+00:03:53,800 --> 00:04:01,040
+الان بنيجي للميه الميه عادة بيضيفوها في وجود حامض
+
+43
+00:04:01,040 --> 00:04:07,860
+و ذئبق على الكائن حامض و ذئبق كتير الان اللي بدو
+
+44
+00:04:07,860 --> 00:04:13,740
+يصير عندى انه بيتم إضافة الميه لمرة واحدة حسب
+
+45
+00:04:13,740 --> 00:04:17,440
+قاعدة Markovnikov's addition بمعنى هنا بدو ييجي
+
+46
+00:04:17,440 --> 00:04:24,300
+عندى H وهنا بدو ييجي عنده OH هاي إضافة الميه Hهذا
+
+47
+00:04:24,300 --> 00:04:26,980
+عبارة عن markovnikov addition
+
+48
+00:04:29,750 --> 00:04:35,070
+المركب اللى اتكون عندى فيه من ناحية المجموعات
+
+49
+00:04:35,070 --> 00:04:41,310
+الوظيفية مجموعتين ووظيفيتين فيه ال الكين اللى هو
+
+50
+00:04:41,310 --> 00:04:46,190
+ال double bond وفيه ال alcohol اللى هو ال OH ال
+
+51
+00:04:46,190 --> 00:04:51,550
+alcohol وعشانك بيسموه in all ايش يعني in all؟ in
+
+52
+00:04:51,550 --> 00:04:57,040
+المجموعة الوظيفية تبع ال الكين و ال allالمجموعة
+
+53
+00:04:57,040 --> 00:04:59,800
+الوظيفية بتاعتين الالكوهول مش بيقول ميثانول
+
+54
+00:04:59,800 --> 00:05:04,720
+ايثانول واضح فهذا عبارة عن in all في المجمعتين
+
+55
+00:05:04,720 --> 00:05:09,780
+الوظيفيتين هدول، الآن هذا ال in all في الaliphatic
+
+56
+00:05:09,780 --> 00:05:15,100
+compounds بشكل عام مش ثابت، مابيضلوش زي ما هو،
+
+57
+00:05:15,100 --> 00:05:23,100
+بتغيرواضح؟ يعني مابنفعش ان انا احطه حتى كنتيجة هذا
+
+58
+00:05:23,100 --> 00:05:30,240
+غير ثابت ال enol طب ايش بيعمل؟ بيتحول الى صيغة
+
+59
+00:05:30,240 --> 00:05:34,460
+تانية فهذه الصيغة بتنتقل ال bond هذه هنا و ال H
+
+60
+00:05:34,460 --> 00:05:36,680
+بتيجي على ال carbon لاحظوا ايش اللي انا قاعد
+
+61
+00:05:36,680 --> 00:05:43,590
+بحكيه؟ شغلتين بدهم يتحركوا، بدها تتحركهيدروجين و
+
+62
+00:05:43,590 --> 00:05:49,050
+بدأت تتحرك رابطة إذا حركة الإلكترونات و حركة
+
+63
+00:05:49,050 --> 00:05:54,950
+البروتونات ال H فلما تلاحظوا أن هذا بدأت تتحرك هنا
+
+64
+00:05:54,950 --> 00:05:59,290
+ال double bond والهيدروجين بدأ تيجي هنا كم حركة
+
+65
+00:05:59,290 --> 00:06:04,220
+عند ال atomsو Charge او Electrons لما اتم هذه
+
+66
+00:06:04,220 --> 00:06:08,520
+الحركة ال C هذا بتصير C double bond O و ال CH2
+
+67
+00:06:08,520 --> 00:06:13,960
+بتصير CH3 الان اذا بتطلع على المجموعة الوظيفية
+
+68
+00:06:13,960 --> 00:06:20,180
+اللي موجودة هنا شو هي كيتون ال C double bond O ال
+
+69
+00:06:20,180 --> 00:06:24,900
+C double bond O هذه كيتون فبدل ما كان عندى مجمعتين
+
+70
+00:06:24,900 --> 00:06:29,810
+وظيفيتين جان بعض اللي هم ال in و ال allالانول
+
+71
+00:06:29,810 --> 00:06:35,490
+اتحول الى كيتو form هذه العملية عملية التحول
+
+72
+00:06:35,490 --> 00:06:37,850
+بيسموها tautomerism
+
+73
+00:06:47,240 --> 00:06:54,700
+هي عبارة عن عملية بتتم فيها حركتين حركة ال charge
+
+74
+00:06:54,700 --> 00:06:59,820
+و حركة ال hydrogen واضح اذا انا بتحرك اندي
+
+75
+00:06:59,820 --> 00:07:06,320
+electrons زائد ال protons ال hydrogen واضح بتفرق
+
+76
+00:07:06,320 --> 00:07:10,560
+عن ال resonance يعني لو بدأ أقولكوا بلغة بسيطة ايش
+
+77
+00:07:10,560 --> 00:07:16,470
+الفرق ما بين ال resonance و الtautomerismالـ
+
+78
+00:07:16,470 --> 00:07:25,390
+Resonance كانت بس الإلكترونات بتتحرك و
+
+79
+00:07:25,390 --> 00:07:29,850
+بيكون موجود عنده الشغل تاني يعني بيكون مرة بهذا
+
+80
+00:07:29,850 --> 00:07:32,370
+الشكل مرة بهذا الشكل مرة بهذا الشكل مرة بهذا الشكل
+
+81
+00:07:32,370 --> 00:07:39,520
+التاوتوميرزم مختلفة التاوتوميرزم عبارة عن حركةشحنة
+
+82
+00:07:39,520 --> 00:07:47,720
+أو إلكترونات وحركة hydrogen atoms لو كنتوا
+
+83
+00:07:47,720 --> 00:07:51,580
+بتتذكروا ال resonance اللي هو حركة إلكترونات كيف
+
+84
+00:07:51,580 --> 00:07:55,360
+السهم اللي كنا نعبر فيه عن ال resonance double
+
+85
+00:07:55,360 --> 00:08:01,600
+headed arrows بهذا الشكل التوتوميرزم عبارة عن
+
+86
+00:08:01,600 --> 00:08:06,720
+اتزان equilibriumيعني بيكون عندى موجود من هذا و
+
+87
+00:08:06,720 --> 00:08:10,220
+بيكون عندى موجود من هذا بنسب معينة في المحلول
+
+88
+00:08:10,220 --> 00:08:13,620
+فالtautomerism يعبر عن equilibrium والسهم تبع ال
+
+89
+00:08:13,620 --> 00:08:18,440
+equilibrium كيف بيكون؟ عشان ايه كذا السهم بيديكم
+
+90
+00:08:18,440 --> 00:08:24,920
+بتصلحوا بهذا الشكل سهم اتزان واضح؟فلو انا بدي اجي
+
+91
+00:08:24,920 --> 00:08:29,740
+اقولكوا مثلا ارسملكوا هذا السهم اقولكوا this arrow
+
+92
+00:08:29,740 --> 00:08:34,060
+is used to indicate automerism .. no it is used to
+
+93
+00:08:34,060 --> 00:08:38,540
+indicate resonance however the equilibrium arrow
+
+94
+00:08:38,540 --> 00:08:40,280
+or the double arrows
+
+95
+00:08:45,030 --> 00:08:51,710
+Tautomerism هي عبارة عن حركة شحنات وحركة بروتونات
+
+96
+00:08:51,710 --> 00:08:56,350
+بيستخدم لتوضيحها سهم الاتزان الكيميائي لأنه هي
+
+97
+00:08:56,350 --> 00:08:59,710
+عملية اتزان يعني لو قلنا توتو ميريزم is an
+
+98
+00:08:59,710 --> 00:09:03,990
+equilibrium processالجواب صح غالبا اللي بيصير
+
+99
+00:09:03,990 --> 00:09:09,130
+كالاتي انه بيكون ال keto هذا بنسبة أحيانا تفوق ال
+
+100
+00:09:09,130 --> 00:09:17,670
+99% و ال enol بنسبة أقل من 1% واضح؟ هذا ال
+
+101
+00:09:17,670 --> 00:09:22,390
+tautomerism شو احنا بنسميها حسب الأطراف تبعونها
+
+102
+00:09:22,390 --> 00:09:28,210
+keto enol tautomerism إذا احنا أمام شغلة جديدة
+
+103
+00:09:28,210 --> 00:09:37,140
+قاعدين بنتعلمها ketoEnol توتو ميريزم فإذا كان عند
+
+104
+00:09:37,140 --> 00:09:41,880
+ال Enol فإنه يتحول الى ال ketone و هذا الكلام وين
+
+105
+00:09:41,880 --> 00:09:47,600
+بيكون في ال aliphatic compounds يعني بال aliphatic
+
+106
+00:09:47,600 --> 00:09:53,520
+compounds كشكل كيميائي مش مقبول ولا مرغوب ان عمرك
+
+107
+00:09:53,520 --> 00:10:00,600
+تشوفه double bond جنبها OH يعني كأنه هذا بشكل عام
+
+108
+00:10:01,690 --> 00:10:05,470
+بغض نظر عن بعض الأمثلة الخاصة اللي مش موضوعنا بشكل
+
+109
+00:10:05,470 --> 00:10:09,890
+عام ممنوع وانتوا بتعملوا structures انكوا تحاولوا
+
+110
+00:10:09,890 --> 00:10:15,050
+تعملونا double bond جنبها OH في الالفاتيك كومباونز
+
+111
+00:10:15,050 --> 00:10:20,870
+الان العكس بيصير في ال aromatic compounds في ال
+
+112
+00:10:20,870 --> 00:10:24,710
+aromatic compounds زي البنزين وغيرها مسموحوا مفضل
+
+113
+00:10:24,710 --> 00:10:31,410
+انكوا تعملوا double bond جنبها OH إذا بتذكرواهذا
+
+114
+00:10:31,410 --> 00:10:38,890
+المُركّب إذا رسمناه اللي فيه OH إيش اسمه؟ فينول
+
+115
+00:10:38,890 --> 00:10:51,510
+لاحظوا من اسمه it is an enol هو فيه الفينل اللي هي
+
+116
+00:10:51,510 --> 00:10:58,690
+حلقة البنزين وهي en وهي all موجودين جانب بعضواضح؟
+
+117
+00:10:58,690 --> 00:11:04,190
+فوجود ال in و ال all جنب بعض في ال aromatic
+
+118
+00:11:04,190 --> 00:11:09,530
+compounds مسموح، بال phenols مسموح، وجود ال in و
+
+119
+00:11:09,530 --> 00:11:15,970
+ال all جنب بعض في ال aliphatic compounds لأ، واضح؟
+
+120
+00:11:15,970 --> 00:11:18,650
+وجود ال in و ال all جنب بعض في ال aliphatic
+
+121
+00:11:18,650 --> 00:11:24,850
+compounds مش مسموح نهائيا، واضح؟ ولا فيها مشكلة
+
+122
+00:11:29,260 --> 00:11:32,860
+زي ما بتلاحظوا ان الخطوة الأولى في الأساس لما ضاف
+
+123
+00:11:32,860 --> 00:11:36,360
+ال H و ال OH قبل التوتوماريزم كانت حسب قاعدة
+
+124
+00:11:36,360 --> 00:11:39,000
+Markovnikov's addition ولا Anti Markovnikov's
+
+125
+00:11:39,000 --> 00:11:42,660
+addition Markovnikov's addition هذا في حالة انه
+
+126
+00:11:42,660 --> 00:11:47,640
+ضفنا H3O plus في وجود الزبق
+
+127
+00:11:49,610 --> 00:11:56,610
+ممكن تكون إضافة الميه في الخطوة الأولى و يتبعها
+
+128
+00:11:56,610 --> 00:11:58,070
+توتوماريزم
+
+129
+00:12:08,170 --> 00:12:11,970
+بهذا الشكل لو كان عندى بهذا الشكل الكاين و اجى
+
+130
+00:12:11,970 --> 00:12:16,430
+اضفة ال borane بال THF في الخطوة الاولى H2O2 و H-
+
+131
+00:12:16,430 --> 00:12:22,610
+متذاكرين هذه كانت شروط ايش اضافة الماء عكس قاعدة
+
+132
+00:12:22,610 --> 00:12:27,250
+Markovnikov Anti Markovnikov's addition فزى ما
+
+133
+00:12:27,250 --> 00:12:33,190
+بتلاحظوا زى ما بتلاحظوا ان هنا بتيجى ال H على هذا
+
+134
+00:12:33,190 --> 00:12:38,160
+الطرفوال OH على هذا الطرف هل هذا Markovnikov's و
+
+135
+00:12:38,160 --> 00:12:40,520
+لا Anti Markovnikov's Addition هذا Anti
+
+136
+00:12:40,520 --> 00:12:43,140
+Markovnikov's Addition ال H مايجتش على الكربون
+
+137
+00:12:43,140 --> 00:12:48,040
+اللي حاملة هيدروجين اجت بالعكس و ال OH اجت بهذا
+
+138
+00:12:48,040 --> 00:12:54,160
+الشكل طبعا هنا برضه نفس الاشي بيصير عند توتوميرزم
+
+139
+00:12:54,160 --> 00:12:59,700
+بمعنى ان هذا ال H هتيجي على هذا الموقع و ال bond
+
+140
+00:12:59,700 --> 00:13:06,330
+تبعتها بيجيتعمل C double bond O لكن زي ما بتلاحظوا
+
+141
+00:13:06,330 --> 00:13:09,890
+هنا ان المركب اللي اتكون هو الديهيد ولا كيتون في
+
+142
+00:13:09,890 --> 00:13:15,030
+هذه الحالة في هذه الحالة اتكون عندى الديهيد في
+
+143
+00:13:15,030 --> 00:13:19,190
+حالة مكان ال الكاين اللى عندى الكاين طرفى طبعا
+
+144
+00:13:19,190 --> 00:13:22,330
+الكاين طرفى او terminal الكاين بمعنى انه في على
+
+145
+00:13:22,330 --> 00:13:27,610
+طرفه hydrogen واضح عارفين ايش معنى terminal الكاين
+
+146
+00:13:30,270 --> 00:13:35,070
+طرف اه فلما نقول احنا فينا terminal alkyne بمعنى
+
+147
+00:13:35,070 --> 00:13:40,770
+انه ال triple bond موجودة على طرف الجزء في alkynes
+
+148
+00:13:40,770 --> 00:13:45,290
+تانية ال triple bond بتكون بنص الجزء و بالمناسبة
+
+149
+00:13:45,290 --> 00:13:49,010
+في ال alkyne اذا ال triple bond كانت بنص الجزء
+
+150
+00:13:49,010 --> 00:13:52,210
+خلاص مافيش احتمال يكون عليها هيدروجين نهائيا يعني
+
+151
+00:13:52,210 --> 00:13:57,290
+مابيكونش على ال triple bond هيدروجين الا اذا كانت
+
+152
+00:13:57,600 --> 00:14:03,940
+على طرف الجزائع إلا إذا كانت Terminal إذا
+
+153
+00:14:03,940 --> 00:14:07,440
+كانت Terminal بدي أضيف Anti Markovnikov's addition
+
+154
+00:14:07,440 --> 00:14:13,280
+طب لو كانت بواسط الجزائع ال triple bond حيكون عندي
+
+155
+00:14:13,280 --> 00:14:16,320
+خليط من التفاعلات يعني ممكن أضيف Markovnikov's و
+
+156
+00:14:16,320 --> 00:14:19,220
+Anti Markovnikov's مبطل واضح Markovnikov's
+
+157
+00:14:19,220 --> 00:14:24,460
+addition فممكن تتم الإضافة باتجاهين واضح؟خلّينا
+
+158
+00:14:24,460 --> 00:14:28,400
+على الوضع البسيط انه يكون اندي تيرمن ال الكاين بدي
+
+159
+00:14:28,400 --> 00:14:32,080
+اضيف عليه مية يا بدي احط ال اتشان وال او اتشانة
+
+160
+00:14:32,080 --> 00:14:35,900
+markovnikov's addition او بدي احط ال اتشانة وال او
+
+161
+00:14:35,900 --> 00:14:42,080
+اتشانة انتي markovnikov's addition واضح؟ الآن بغض
+
+162
+00:14:42,080 --> 00:14:46,500
+النظر إذا اتكون مركب للمركب اللي هيتكون إيش هيكون؟
+
+163
+00:14:46,500 --> 00:14:53,100
+in allالانول هيتحول أيضًا إلى ال keto form اللي هو
+
+164
+00:14:53,100 --> 00:14:56,260
+الـCWO المقصود، بغض النظر كونه الديادة أو الكيتو
+
+165
+00:14:56,260 --> 00:15:01,200
+المهم أنه يتحول إلى CWO،
+
+166
+00:15:01,200 --> 00:15:06,180
+يتحول إلى CWO، إذًا ظاهرة التوتومينزم في كل
+
+167
+00:15:06,180 --> 00:15:13,130
+الأحوال بتصيرطبعا هذا الكلام هو اللي ممكن تسأله
+
+168
+00:15:13,130 --> 00:15:17,410
+عنه انتوا يعني اتخيلوا ان انا لو جبتلكم مثلا أي ال
+
+169
+00:15:17,410 --> 00:15:21,930
+kind زي هذا و طلبت منكوا في النهاية انكوا تحضرولي
+
+170
+00:15:21,930 --> 00:15:27,910
+مركب في cw bond o هنا بنفع
+
+171
+00:15:27,910 --> 00:15:33,150
+بدكوا تضيفوا الميه في وجود hg2 plus و بتعمل
+
+172
+00:15:33,150 --> 00:15:37,430
+توتماريزم و لو طلبت منكوا تحطولي ال cw bond o هنا
+
+173
+00:15:38,450 --> 00:15:40,710
+بتكون تضيف الميّه بهذه الطريقة تطلعوا أنتوا إيش
+
+174
+00:15:40,710 --> 00:15:46,810
+المحاسلة النهائية الـCWBond O هان طب لو بدى هان
+
+175
+00:15:46,810 --> 00:15:57,450
+بدى أستعمل الطريقة السابقة H3O Plus مع الذئبك إذا
+
+176
+00:15:57,450 --> 00:16:04,870
+أنا بإمكاني على طرفي الرابط أن أحط CWBond Oبضل اني
+
+177
+00:16:04,870 --> 00:16:09,970
+انتقل ال reagent المناسب اذا بديها تكون هنا يتكون
+
+178
+00:16:09,970 --> 00:16:16,940
+عندي كيتونهنا بدأ استعمل H3O Plus في وجود HG2 Plus
+
+179
+00:16:16,940 --> 00:16:20,600
+إذا بديها هنا بدأ استعمل شروط الـ Anti
+
+180
+00:16:20,600 --> 00:16:23,420
+Markovnikov's addition اللي هو الـ Hydroboration
+
+181
+00:16:23,420 --> 00:16:26,220
+يعني إضافة البرون والهيدروجين followed by
+
+182
+00:16:26,220 --> 00:16:30,660
+Oxidation بالهيدروجين البروكسايد اللي اتعلمناه،
+
+183
+00:16:30,660 --> 00:16:36,940
+واضح؟ فالاحتمالين ممكنينالاحتمالين ممكنين ان اعمل
+
+184
+00:16:36,940 --> 00:16:39,340
+markovnikov's addition او anti markovnikov's
+
+185
+00:16:39,340 --> 00:16:44,780
+addition وفي الحالتين ال a0 بده يصير keto form
+
+186
+00:16:44,780 --> 00:16:49,120
+بمعنى ال OH بده تصير C double bond O و ال double
+
+187
+00:16:49,120 --> 00:16:54,560
+bond بده تصير single bond ال double bond بده تصير
+
+188
+00:16:54,560 --> 00:17:03,630
+single bond الان بنجي لإضافة جديدة وهي إضافة الـ
+
+189
+00:17:03,630 --> 00:17:08,530
+Hydrogenإضافة الهيدروجين طبعا إضافة الهيدروجين
+
+190
+00:17:08,530 --> 00:17:14,270
+احنا بنسميها reduction عملية اختزال عملية اختزال
+
+191
+00:17:14,270 --> 00:17:19,230
+لاحظوا معنى ممكن احنا يكون عندنا single bond ممكن
+
+192
+00:17:19,230 --> 00:17:24,010
+يكون عندنا double bond ممكن يكون عندنا triple bond
+
+193
+00:17:24,010 --> 00:17:29,330
+إذا أنا بتحرك من ال single bond لل double bond أو
+
+194
+00:17:29,330 --> 00:17:32,550
+من ال double bond لل triple bond العملية بسميها
+
+195
+00:17:32,550 --> 00:17:37,290
+oxidationواضح؟ يعني لو عندى alkane بدي أخليه
+
+196
+00:17:37,290 --> 00:17:42,290
+alkene بقول oxidation of alkanes to alkenes لو
+
+197
+00:17:42,290 --> 00:17:46,310
+عندى alkene بدي أخليه alkyne بقول oxidation of
+
+198
+00:17:46,310 --> 00:17:52,030
+alkenes to alkynes إذا بتحرك بالعكسالعملية إيش
+
+199
+00:17:52,030 --> 00:17:56,910
+بنسميها reduction، عملية اختزار، الآن إحنا اللي
+
+200
+00:17:56,910 --> 00:18:00,970
+بدنا نعمله إنه عندنا triple bond، معنى عندنا
+
+201
+00:18:00,970 --> 00:18:05,090
+triple bond، إنه هننزل يا ل double bond، يا ل
+
+202
+00:18:05,090 --> 00:18:09,900
+single bond، في كل الأحوال العملية reductionبكل
+
+203
+00:18:09,900 --> 00:18:13,680
+الأحوال العملية عملية reduction عشانك العنوان
+
+204
+00:18:13,680 --> 00:18:19,540
+تبعكم reduction of alkynes ال reduction of alkynes
+
+205
+00:18:19,540 --> 00:18:27,740
+مع الهيدروجين حقيقة له تلت احتمالات و تلت شروط
+
+206
+00:18:27,740 --> 00:18:34,520
+تفاعل و تلت نواتج مختلفة ال reduction of alkynes
+
+207
+00:18:35,450 --> 00:18:41,010
+باستعمال الهيدروجين بتتم بثلاث طرق و بتقدر تلت طرق
+
+208
+00:18:41,010 --> 00:18:48,010
+الى تلت نواتج مختلفة الطريقة الأولى إذا أنا بضيف
+
+209
+00:18:48,010 --> 00:18:52,610
+الهيدروجين في وجود metal catalyst زى البلاديم او
+
+210
+00:18:52,610 --> 00:18:57,630
+البلاتين او ال nickel طبعا البلاديم دائما بيكون
+
+211
+00:18:57,630 --> 00:19:02,930
+مخلوط بكاربون بيسموه بلاديم كاربون كاربون فحم ناعم
+
+212
+00:19:02,930 --> 00:19:08,680
+جدا واضحبس الأساس في ال catalyst اللي هو إيش ال
+
+213
+00:19:08,680 --> 00:19:13,080
+بالاديام فإضافة ال hydrogen مع ال بالاديام و عشان
+
+214
+00:19:13,080 --> 00:19:16,080
+أنا مش كاتبينهم لو أجيكوا في الامتحان مع ال nickel
+
+215
+00:19:16,080 --> 00:19:22,780
+أو مع ال platinumمع أي metal من هدولة بضيف مرتين
+
+216
+00:19:22,780 --> 00:19:27,100
+وبيعطيني الalkene بحصلش على ال double bond بنتقل
+
+217
+00:19:27,100 --> 00:19:32,620
+مباشرة من ال triple bond إلى ال single bond إذا
+
+218
+00:19:32,620 --> 00:19:37,760
+هيدروجين مع بلاديم أو nickel أو platinum بيحوللي
+
+219
+00:19:37,760 --> 00:19:43,890
+الalkene إلىالكين .. واضح؟ يعني لو جيبنالكم سؤال
+
+220
+00:19:43,890 --> 00:19:47,150
+صح و غلط مرات طلاب التخموا لما نجيب الأسئلة نقولوا
+
+221
+00:19:47,150 --> 00:19:52,190
+reduction of alkanes using hydrogen palladium
+
+222
+00:19:52,190 --> 00:20:00,110
+produces alkenes غلط it produces alkenes single
+
+223
+00:20:00,110 --> 00:20:06,110
+bonds .. واضح؟ هذا اللي هو التفاعل الأولالان
+
+224
+00:20:06,110 --> 00:20:13,050
+التفاعل التاني .. التفاعل التاني ممكن احنا نضيف بس
+
+225
+00:20:13,050 --> 00:20:17,670
+جزء واحد هيدروجين مش اتنين في الحالة الأولى كم
+
+226
+00:20:17,670 --> 00:20:22,550
+هيدروجين ضفنا؟ جزين ممكن نضيف جزء واحد هيدروجين
+
+227
+00:20:22,550 --> 00:20:26,810
+الان انتبهوا انا بتيجينا نقطة فنية كتير مهمة لما
+
+228
+00:20:26,810 --> 00:20:32,170
+بدي اضيف جزء واحد هيدروجين هحول ال triple bond الى
+
+229
+00:20:32,170 --> 00:20:39,180
+double bondواضح؟ هحوّل ال triple bond إلى double
+
+230
+00:20:39,180 --> 00:20:42,420
+bond .. ال double bond فيها ظاهرة ال cis و ال
+
+231
+00:20:42,420 --> 00:20:51,460
+trans .. ال alkanes مافيهم ظاهرة cis و trans ..فيش
+
+232
+00:20:51,460 --> 00:20:55,080
+فيهم ظاهرة ال cis و ال trans؟ واضح؟ ظاهرة ال cis و
+
+233
+00:20:55,080 --> 00:20:59,060
+ال trans مرتبطة بإيش؟ بال double bonds بال ال
+
+234
+00:20:59,060 --> 00:21:02,440
+alkenes أو بال cyclic alkenes لما يكون عندي حلقات
+
+235
+00:21:02,440 --> 00:21:08,340
+الآن طالما أنا بتحول الألكاين هذا إلى ال keen إذا
+
+236
+00:21:08,340 --> 00:21:12,480
+اللي بيصير عندي تساؤل هل يا ترى الأ ال keen اللي
+
+237
+00:21:12,480 --> 00:21:17,840
+بيطلع عندي هيكون بال cis form ولا بال trans form
+
+238
+00:21:17,840 --> 00:21:25,400
+واضحة الفكرة؟الان حسب نوع الطريقة المستخدمة ممكن
+
+239
+00:21:25,400 --> 00:21:30,500
+اطلع نواتج بحيث ان الهيدروجين يضيف من جهة واحدة
+
+240
+00:21:30,500 --> 00:21:34,980
+وينتج عند الـ cis compound او الهيدروجين يضيف من
+
+241
+00:21:34,980 --> 00:21:39,600
+جهتين متعاكستين وينتج عند ال trans compound اذا
+
+242
+00:21:39,600 --> 00:21:45,260
+الاحتمالين ممكنين لكن بتحكم فيهم من خلال ايش؟طريقة
+
+243
+00:21:45,260 --> 00:21:52,000
+التفاعل إذا ضيفت الهيدروجين في وجود كتاليست بنسميه
+
+244
+00:21:52,000 --> 00:21:58,460
+لندلارز كتاليست لندلارز كتاليست
+
+245
+00:21:58,460 --> 00:22:02,680
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+246
+00:22:02,680 --> 00:22:02,880
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+247
+00:22:02,880 --> 00:22:05,140
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+248
+00:22:05,140 --> 00:22:07,460
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+249
+00:22:07,460 --> 00:22:08,360
+لندلارز كتاليست لندلارز كتاليست لندلارز كتاليست
+
+250
+00:22:08,360 --> 00:22:11,520
+لندلارز كتاليست لندلارز كتاليست لندلار
+
+251
+00:22:13,220 --> 00:22:18,140
+هذا المُركّب اللي هو الـ diphenylacetylene هذا لو
+
+252
+00:22:18,140 --> 00:22:21,040
+بدنا نسميه diphenylacetylene هاي أسيتليلينه
+
+253
+00:22:21,040 --> 00:22:26,300
+كربونتين عليه فنل وفنل، مظبوط ولا لأ؟ بهذا
+
+254
+00:22:26,300 --> 00:22:28,940
+المُركّب الـ diphenylacetylene، بزام الهيدروجينز
+
+255
+00:22:28,940 --> 00:22:34,500
+إجوا من جهة واحدة، إذا الـ two phenyl groups
+
+256
+00:22:34,500 --> 00:22:40,680
+هيروحواعلى الجهة التانية المعاكسة واضح؟ هينتج عنده
+
+257
+00:22:40,680 --> 00:22:44,960
+ال cess compound
+
+258
+00:22:44,960 --> 00:22:54,040
+شايفينه هذا؟ الآن إيش هو ال landlord catalyst؟
+
+259
+00:23:03,700 --> 00:23:07,780
+ماذا يعني لندلار كتاليست؟ لندلار كتاليست هو عبارة
+
+260
+00:23:07,780 --> 00:23:14,200
+عن خليط موجود فيه 5% بالاديام مع كالسيام كربونيت
+
+261
+00:23:14,200 --> 00:23:19,600
+مع ليد أسيتيت مع إكوينولين، كل هذه الخلطة بتنبأ
+
+262
+00:23:19,600 --> 00:23:24,460
+بيشتريها الواحد، إيش اسمها؟ لندلار كتاليست، واضح؟
+
+263
+00:23:25,500 --> 00:23:30,200
+في بلاد يام لكن مع أشياء تانية فالان احنا بنقدر
+
+264
+00:23:30,200 --> 00:23:36,580
+نقول ان ال addition of hydrogen to alkynes using
+
+265
+00:23:36,580 --> 00:23:44,280
+Lindler's catalyst is a sin addition صح واضح؟
+
+266
+00:23:44,280 --> 00:23:49,700
+فالاضافة باستعمال Lindler's catalyst is a sin
+
+267
+00:23:49,700 --> 00:23:55,120
+additionبمعنى إضافة من جهة واحدة و في مرات كتيرة
+
+268
+00:23:55,120 --> 00:24:00,260
+بتطلعلي ال cess compound الان هل يا ترى بإمكاننا
+
+269
+00:24:00,260 --> 00:24:06,960
+ان نخلي ال hydrogen اضيف من جهتين متعاكستين ممكن
+
+270
+00:24:06,960 --> 00:24:13,900
+إذا غيرنا ال reagentإذا ضفنا الهيدروجين من خلال
+
+271
+00:24:13,900 --> 00:24:19,200
+إضافة معدل الليثيوم وال liquid ammonia لاحظوا
+
+272
+00:24:19,200 --> 00:24:22,740
+liquid ammonia مش solution يعني غاز الأمونيا بس
+
+273
+00:24:22,740 --> 00:24:28,160
+مبردينه بصير إيش؟ سائل بضف للهيدروجين من جهتين
+
+274
+00:24:28,160 --> 00:24:33,020
+متعاكستين بمعنى أخر بيعمل Anti-addition لاحظوا هنا
+
+275
+00:24:33,020 --> 00:24:38,690
+الهيدروجينكيف بيضيف؟ فلو كان عندى هذا المركب .. لو
+
+276
+00:24:38,690 --> 00:24:42,290
+كان عندى هذا المركب اللى هو two butane one two
+
+277
+00:24:42,290 --> 00:24:47,370
+three four هذا عبارة عن two butane او اى واحدة كان
+
+278
+00:24:47,370 --> 00:24:51,190
+ممكن بطريقة السابقة تتخيل ان هو dimethylacetylene
+
+279
+00:24:51,190 --> 00:24:55,550
+مظبوط ولا لأ؟ اه فلما تضيف hydrogen من هنا و
+
+280
+00:24:55,550 --> 00:24:59,990
+hydrogen من هنا يضيفه بطريقتين متعاكستين شو هيطلع
+
+281
+00:24:59,990 --> 00:25:06,060
+له؟ لtrans compound او لtrans two butaneواضح؟ إذا
+
+282
+00:25:06,060 --> 00:25:11,940
+لما نقول إحنا أنه هذا بندوّب معدن الليثيام في ال
+
+283
+00:25:11,940 --> 00:25:15,740
+liquid ammonia و بنضيفه على ال alkyne بده يعطينا
+
+284
+00:25:15,740 --> 00:25:21,560
+أي ناتج ل Trans أو ال Anti-addition product وبناء
+
+285
+00:25:21,560 --> 00:25:25,240
+على ذلك بإمكانكم أن تتخيلوا أن احنا ممكن نيجي
+
+286
+00:25:25,240 --> 00:25:32,960
+نسألكم نجيبلكم ال alkyne و نحطلكم تلت أسهموعلى كل
+
+287
+00:25:32,960 --> 00:25:42,240
+سهم reagent وكل سهم بيطلع ايش؟ وكل سهم بيطلع نتيجة
+
+288
+00:25:42,240 --> 00:25:46,360
+زي هذه الحالة مثلا، هاي بعد صفحتين بتلاحظوا انه
+
+289
+00:25:46,360 --> 00:25:50,340
+اتخيلوا ان هذا جاي سؤال في الامتحان دايفين
+
+290
+00:25:50,340 --> 00:25:55,620
+الacetylene الآن لو قلت انا مع hydrogen بالاديام
+
+291
+00:25:55,620 --> 00:26:01,840
+كاربون شو هيعطيني؟ الalkynwill be converted to
+
+292
+00:26:01,840 --> 00:26:07,780
+alkane إذا إضافتين هيدروجين طيب هنا مافيش cis و
+
+293
+00:26:07,780 --> 00:26:12,360
+trans طبعا بس هيك الرسمة لإنه single bonds ال cis
+
+294
+00:26:12,360 --> 00:26:15,520
+و ال trans وين موجودة كظاهرة حوالينا؟ أه طبعا ال
+
+295
+00:26:15,520 --> 00:26:19,040
+bonds الآن لو ضفنا هيدروجين في وجود ال lindlar
+
+296
+00:26:19,040 --> 00:26:19,640
+catalyst
+
+297
+00:26:32,660 --> 00:26:39,140
+دائما هذه المقارنات اهتموا فيهاوهذه المقارنات
+
+298
+00:26:39,140 --> 00:26:43,580
+بالمناسبة يعني تعتبر جيدة جدا في ال organ ال
+
+299
+00:26:43,580 --> 00:26:46,840
+chemistry يعني اي واحدة بدأت تدرس تفاعل فيه مقارنة
+
+300
+00:26:46,840 --> 00:26:50,060
+ما تحفظش تفاعل واحد تحفظ اكتر من تفاعل شوفته قبل
+
+301
+00:26:50,060 --> 00:26:58,150
+شوية اضافة الميه كانتعال Alkines بطريقتين .. هيك
+
+302
+00:26:58,150 --> 00:27:01,930
+افهموا الكلام اذا ذكروا إضافة الميه مثلا على ال
+
+303
+00:27:01,930 --> 00:27:05,950
+Alkines لما أخدناها .. أخدناها بكم طريقة؟ بتلات
+
+304
+00:27:05,950 --> 00:27:10,270
+طرق و كل طريقة تؤدي إلى ناتج بمعنى أنا بإمكان
+
+305
+00:27:10,270 --> 00:27:13,910
+أجيبلكوا Alkine و أحطلكوا إضافة الميه في وجود
+
+306
+00:27:13,910 --> 00:27:18,490
+الحامض .. بتكونوا تقولوا؟ماركوفنيكوفز اديشن مع
+
+307
+00:27:18,490 --> 00:27:21,850
+احتمال ال rearrangement إضافة الميه في وجود ال
+
+308
+00:27:21,850 --> 00:27:26,230
+mercury كأسيتات ماركوفنيكوفز اديشن بس مافيش
+
+309
+00:27:26,230 --> 00:27:30,730
+rearrangement إضافة الميه في وجود البورين
+
+310
+00:27:30,730 --> 00:27:33,910
+Hydroboration Oxidation Anti Markovnikov's
+
+311
+00:27:33,910 --> 00:27:37,810
+addition نفس الاشي لما خدتوا في ال الكينز مثلا HPR
+
+312
+00:27:37,810 --> 00:27:42,250
+في وجود الحامض HPR في وجود البروكسيل هنا مثلا
+
+313
+00:27:42,250 --> 00:27:47,750
+إضافة الهيدروجينمرة ال cane مرة cis ال cane مرة
+
+314
+00:27:47,750 --> 00:27:53,710
+trans ال cane واضح فدائما حاولوا تحفظوا هذه
+
+315
+00:27:53,710 --> 00:27:55,270
+المقارنات و تنتبهوها
+
+316
+00:28:00,970 --> 00:28:06,910
+أخر تفاعل .. أخر تفاعل بناخده في هذا chapter ..
+
+317
+00:28:06,910 --> 00:28:09,590
+chapter تلاتة من أكبر الفصول اللي معنا ان شاء الله
+
+318
+00:28:09,590 --> 00:28:15,230
+بنخلصه الآن اللي هو use of alkyne anion in a
+
+319
+00:28:15,230 --> 00:28:20,170
+substitution reaction ممكن نصيغه بطريقة أو بجملة
+
+320
+00:28:20,170 --> 00:28:27,540
+مختلفة تماما، نسميه acidity of alkynesحمضية
+
+321
+00:28:27,540 --> 00:28:31,260
+الalkynes طبعا لو كنا بدنا نكون دقيقين بدنا نقول
+
+322
+00:28:31,260 --> 00:28:43,560
+acidity of terminal alkynes terminal alkynes طبعا
+
+323
+00:28:43,560 --> 00:28:46,960
+لما نيجي نقول احنا الحامضية شو جابنا على الحامضية
+
+324
+00:28:46,960 --> 00:28:53,840
+في الalkynes اتذكروا انتوا الحامض حسب تعريف Lewis
+
+325
+00:28:57,090 --> 00:29:02,950
+هيدروجين دونار أو بروتون دونار مظبوط ولا لأ الحامض
+
+326
+00:29:02,950 --> 00:29:08,790
+حسب تعريف Lewis هو اللي بيعطينا إيش بروتون فأي إش
+
+327
+00:29:08,790 --> 00:29:14,170
+بده يفقد H بلس بده أعمله إنه حامض الحمض الآن في
+
+328
+00:29:14,170 --> 00:29:19,950
+الalkynes مين اللي فيهم هيدروجينالـ Terminal
+
+329
+00:29:19,950 --> 00:29:25,410
+Alkines لما تكون لـ Triple bond طرفية ملاحظين يعني
+
+330
+00:29:25,410 --> 00:29:28,870
+الـ Alkine إذا ماكانش Terminal مافيش هذا ال
+
+331
+00:29:28,870 --> 00:29:33,310
+section هذا ال section متعلق بإيش ال Terminal
+
+332
+00:29:33,310 --> 00:29:38,310
+Alkine اللي فيهم هيدروجين الآن هذه الهيدروجين اللي
+
+333
+00:29:38,310 --> 00:29:41,930
+جنب ال Alkine زي الهيدروجين اللي على ال OH في
+
+334
+00:29:41,930 --> 00:29:46,510
+الحامض إذا بنفعلها مع قاعدة قوية فإنها تفقد على
+
+335
+00:29:46,510 --> 00:29:51,260
+شكلالبروتون وبالتالي ال alkyne هنا can be
+
+336
+00:29:51,260 --> 00:29:57,480
+considered as an acid ممكن نعتبره حامض ممكن نعتبره
+
+337
+00:29:57,480 --> 00:30:04,740
+acid او حامض فمعنى حامض انه يفقد البروتون بدون
+
+338
+00:30:04,740 --> 00:30:11,100
+الالكتروناتبس فاقد البروتون عشان هيك هذا الالكاين
+
+339
+00:30:11,100 --> 00:30:14,860
+لو أخدنا مثلا هذا الالكاين وفعلنا مع very strong
+
+340
+00:30:14,860 --> 00:30:19,320
+base هذي ال strong base اسمها Sodamide زي ما في
+
+341
+00:30:19,320 --> 00:30:22,760
+عندكم Sodium Hydroxide Sodium Hydroxide إيش صيغته
+
+342
+00:30:22,760 --> 00:30:30,720
+العامة NaOH هذي ال base أقوى منه NaNH2 عبارة عن Na
+
+343
+00:30:32,290 --> 00:30:38,790
+و N H2- طبعا ال base اللي فيها هي عبارة عن إيش ال
+
+344
+00:30:38,790 --> 00:30:44,450
+N H2- زي في ال sodium hydroxide N A O H minus مين
+
+345
+00:30:44,450 --> 00:30:48,810
+اللي بياخد ال proton أثناء التفاعل ال O H minus ال
+
+346
+00:30:48,810 --> 00:30:52,450
+O H minus من ال N A O H لما تاخد ال proton و
+
+347
+00:30:52,450 --> 00:31:00,650
+بتتحول إلىالـ H2O الان هنا نفس الفكرة NA NH2-
+
+348
+00:31:00,650 --> 00:31:06,030
+بالنتيجة تاخد البروتون من هنا شو بده تصير الـ NH3
+
+349
+00:31:06,030 --> 00:31:14,610
+أمونيا واضح فهذا ايش اسمه Sodamide
+
+350
+00:31:14,610 --> 00:31:20,430
+زي Sodium Hydroxide بس هذا بيكون stronger base
+
+351
+00:31:20,430 --> 00:31:21,410
+than
+
+352
+00:31:32,450 --> 00:31:35,730
+هذا الكلام لو انتوا بتتطلعوا على الجدول الدوري و
+
+353
+00:31:35,730 --> 00:31:38,890
+كيف بتزيد القاعدية لما يكون عندي ال O هان او ال N
+
+354
+00:31:38,890 --> 00:31:43,490
+هان بهذا الشكل بتزيد القاعدية فكل اللي بيصير ان هو
+
+355
+00:31:43,490 --> 00:31:45,570
+ال N H 2 minus هتاخد H
+
+356
+00:31:48,910 --> 00:31:58,390
+أيون سالب بيسموه الacetylide anion بشكل
+
+357
+00:31:58,390 --> 00:32:04,070
+عام طبعا بيسموه ايون سالب شو ال ايون المرافق اللي
+
+358
+00:32:04,070 --> 00:32:06,150
+معاه هيكون ال anion
+
+359
+00:32:12,370 --> 00:32:19,910
+الان هذا ال ايون السالب لو اجيت فعلته مع مركب مثلا
+
+360
+00:32:19,910 --> 00:32:24,010
+مثل ال methyl iodide بيروح بهاجم على الكربون اللي
+
+361
+00:32:24,010 --> 00:32:29,370
+هال لأنها موجبة وبيطر دليوت هذا بعد ما اعملت انا
+
+362
+00:32:29,370 --> 00:32:35,330
+ايشبعد ما شيلت منه القدش و خلته ايون سالب قوي
+
+363
+00:32:35,330 --> 00:32:39,570
+بيصير strong nucleophile هال strong nucleophile
+
+364
+00:32:39,570 --> 00:32:43,510
+ممكن ييجي يهجم على مركب زي ال methyl iodide يطرد
+
+365
+00:32:43,510 --> 00:32:47,650
+منه اليود minus و يحل محله عشانك العنوان تبعكوا
+
+366
+00:32:47,650 --> 00:32:52,690
+ايش كان substitution ال substitution هي اي خطوة
+
+367
+00:32:52,690 --> 00:33:00,350
+التانية احنا الأساس عندنا اليوم ايشالـ Terminal
+
+368
+00:33:00,350 --> 00:33:08,830
+Alkines are Assets معناه Assets انهم بيفقدوه H
+
+369
+00:33:08,830 --> 00:33:12,750
+Plus لما بيفقدوه H Plus كوانولي ايون سالب الايون
+
+370
+00:33:12,750 --> 00:33:17,330
+السالب من طبيعته من تفاعلته انه بيحلم حال ايون
+
+371
+00:33:17,330 --> 00:33:22,840
+سالب تانيواضح؟ مثل هذا التفاعل بس الشيء الأساسي
+
+372
+00:33:22,840 --> 00:33:26,300
+عندنا احنا اليوم في موضوعنا الشيء الأساسي جدا في
+
+373
+00:33:26,300 --> 00:33:30,240
+موضوعنا ان ال terminal alkynes can be considered
+
+374
+00:33:30,240 --> 00:33:34,060
+as acids they lose their proton when reacted with
+
+375
+00:33:34,060 --> 00:33:38,660
+strong bases like Sodamate producing negative
+
+376
+00:33:38,660 --> 00:33:43,360
+anions or acetylide anions. Acetylide anions can
+
+377
+00:33:43,360 --> 00:33:56,600
+undergo substitutionlike this reaction واضح يعني
+
+378
+00:33:56,600 --> 00:34:00,000
+نجيب سؤال صح و غلط ان ال terminal alkines can be
+
+379
+00:34:00,000 --> 00:34:06,320
+considered as assets ولا بلاش ممكن نعتبرهم ممكن
+
+380
+00:34:06,320 --> 00:34:10,820
+فعلا نعتبرهم كأنهم كأنهم
+
+381
+00:34:12,830 --> 00:34:35,630
+بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+382
+00:34:35,630 --> 00:34:38,870
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+383
+00:34:38,870 --> 00:34:38,870
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+384
+00:34:38,870 --> 00:34:38,870
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+385
+00:34:38,870 --> 00:34:38,870
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+386
+00:34:38,870 --> 00:34:39,050
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+387
+00:34:39,050 --> 00:34:39,310
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+388
+00:34:39,310 --> 00:34:39,310
+بروتوز بيفقدوا بروتوز بيفقدوا بروتوز بيفقدوا
+
+389
+00:34:39,310 --> 00:34:43,840
+بروتوز بيفقدواهذا المُركّب .. هذا المُركّب .. إذا
+
+390
+00:34:43,840 --> 00:34:48,600
+بتطلع عليه symmetric الـ kind .. الآن لما بدأ أضيف
+
+391
+00:34:48,600 --> 00:34:54,300
+عليه أنا HCL .. اتفقنا أن HCL بدي أضيف على مرتين
+
+392
+00:34:54,300 --> 00:34:58,280
+.. الآن لو إجيتوا تطلع على أول مرة بزامه مش
+
+393
+00:34:58,280 --> 00:35:03,760
+terminalمافيش تحديد وين بده تيجي ال H وين بده تيجي
+
+394
+00:35:03,760 --> 00:35:07,700
+ال CL لإن بالمناسبة الموقعين هنا نفس الأشياء لإنه
+
+395
+00:35:07,700 --> 00:35:12,580
+متماثل لكن مجرد ما بتم التفاعل الأول هنا بتيجي ال
+
+396
+00:35:12,580 --> 00:35:18,340
+H وهنا ال CL التفاعل التانيهييجي بنفس الاتجاه،
+
+397
+00:35:18,340 --> 00:35:21,760
+هيصير Markov-Nikols addition واضح، بمعنى أول خطوة
+
+398
+00:35:21,760 --> 00:35:26,480
+هنا، لو أي واحد اجت تضيف، مش هتشوف hydrogen، بيقول
+
+399
+00:35:26,480 --> 00:35:29,000
+لا مش مشكلة، اضيفي كيف ما كان، اضيفي ال-H and و ال
+
+400
+00:35:29,000 --> 00:35:32,140
+-Cl هنا، الآن بعد ما تضيف هنا H و هنا ال-Cl، ماتيش
+
+401
+00:35:32,140 --> 00:35:36,720
+تعمل الخطوة التانية، صارت ملزمة أن ال hydrogen وين
+
+402
+00:35:36,720 --> 00:35:40,260
+بدها تضيفها، على الكربون اللي حامله، ال hydrogen و
+
+403
+00:35:40,260 --> 00:35:46,960
+ال-Cl هنا، بدو يطلع عندنا هذا المراجع، واضح؟المثال
+
+404
+00:35:46,960 --> 00:35:53,200
+التاني عند triple bond مع BH3 وTHF
+
+405
+00:35:53,200 --> 00:35:55,700
+وهيدروجينبروقسايد اللي سمناه Hydroboration
+
+406
+00:35:55,700 --> 00:36:00,080
+Oxidation هذا بده يضيف ايش؟ بدكوا تعرفوا انه بده
+
+407
+00:36:00,080 --> 00:36:05,500
+يضيف مية Anti Markovnikovs وبعدين تتحول الى السيضة
+
+408
+00:36:05,500 --> 00:36:12,330
+بال bond بمعنى حيضيف ال H هناو ال O H هنا طب مكان
+
+409
+00:36:12,330 --> 00:36:16,130
+ال O H شو حصل عندى فى النهاية C double bond هو اذا
+
+410
+00:36:16,130 --> 00:36:20,670
+انا لما بدى النتيجة صار عندى هنا C double bond هو
+
+411
+00:36:20,670 --> 00:36:27,650
+واضح فهذا إضافة Anti Markov Necomedition على طول
+
+412
+00:36:27,650 --> 00:36:33,510
+هتتخيلوا ان هنا ال H هنا ال O H و دائما هذا ناتج
+
+413
+00:36:34,340 --> 00:36:37,640
+الـ Transient Product يعني أثناء التفاعل، بس هالي
+
+414
+00:36:37,640 --> 00:36:42,160
+بنفصله؟ لأ، أه إيش اللي بنفصل؟ إن هذا تصير C
+
+415
+00:36:42,160 --> 00:36:49,200
+double bond O وهنا تصير CH2 ماشي الحاجة، الآن هذا
+
+416
+00:36:49,200 --> 00:36:58,040
+الكائن بدنا نضيف عليه Lithium و NH3 Terminal
+
+417
+00:36:58,040 --> 00:37:01,540
+الكائن هدولة إيش بيعملوا ال Lithium مع ال NH3؟
+
+418
+00:37:02,620 --> 00:37:06,420
+بضيفوا هيدروجينز .. بضيفوا هيدروجينز .. بضيفوهم
+
+419
+00:37:06,420 --> 00:37:10,640
+anti addition انتبهوا معاه .. يمكن انتوا بتضلكوا
+
+420
+00:37:10,640 --> 00:37:16,200
+مصرين و قولتوها خمس مرات او ستة او سبعة انكوا
+
+421
+00:37:16,200 --> 00:37:21,560
+تقولوا trans و في كل مرة بتسمعوني انا اش بقول anti
+
+422
+00:37:22,600 --> 00:37:28,320
+الان ايش ال .. الدقة او الفرق في الكلام؟ في فرق
+
+423
+00:37:28,320 --> 00:37:33,940
+بين شغلتين، شغلة بنسميها mood of addition بمعنى
+
+424
+00:37:33,940 --> 00:37:38,460
+طريقة التفاعل وشغلة بنسميها ال product of
+
+425
+00:37:38,460 --> 00:37:43,480
+addition، ناتج التفاعل الان ال mood of addition ان
+
+426
+00:37:43,480 --> 00:37:48,380
+ال hydrogen من هنا و من هنا بيجوا عكس بعضهذا كلام
+
+427
+00:37:48,380 --> 00:37:53,380
+مافيش فيه خلاف إذا كيف بتتم ال addition؟ Anti الان
+
+428
+00:37:53,380 --> 00:37:58,460
+الناتج باعتمد ايش أساسا عند أنا Substituent
+
+429
+00:37:58,460 --> 00:38:04,340
+بالتالي دائما و أبدا طريقة الإضافة جايين متعاكسات
+
+430
+00:38:04,340 --> 00:38:10,560
+Anti addition لكن هل يا تورا لازم يطلعواسيس و
+
+431
+00:38:10,560 --> 00:38:14,760
+ترانس هذا بيعتمد ايش في عندى substitutes يعني هنا
+
+432
+00:38:14,760 --> 00:38:18,740
+لما اجوا اضافة واحدة من فوق واحدة من تحت هذه
+
+433
+00:38:18,740 --> 00:38:23,620
+الكربون اللى كان عليها اتش شو صار عليها two
+
+434
+00:38:23,620 --> 00:38:29,600
+hydrogens بزام احدى الذارتين عليها احدى ذارتين
+
+435
+00:38:29,600 --> 00:38:32,560
+الكربون اللى هو الطرفين ال double bond عليها two
+
+436
+00:38:32,560 --> 00:38:39,150
+hydrogens موجودة كل ظاهرة السيس و الترانس؟ لأشرط
+
+437
+00:38:39,150 --> 00:38:42,850
+.. شرط ظاهرة الـ sexual trance .. شرط ظاهرة الـ
+
+438
+00:38:42,850 --> 00:38:46,970
+sexual trance عشان تكون موجودة انه على طرفين ال
+
+439
+00:38:46,970 --> 00:38:50,130
+double bond يكون هنا مجموعتين مختلفتين و هنا
+
+440
+00:38:50,130 --> 00:38:56,850
+مجموعتين مختلفتين فانا هنا صح اعملت anti addition
+
+441
+00:38:56,850 --> 00:39:00,010
+لكن بعد ما اعملت ال anti addition صار هذه عليها
+
+442
+00:39:00,010 --> 00:39:03,230
+two hydrogens مافيش كل ظاهرة ال sexual trance
+
+443
+00:39:04,390 --> 00:39:09,490
+وعشانك انا بقول انه ال mood of addition دائما انت
+
+444
+00:39:09,490 --> 00:39:12,870
+addition مش مختلف معاكوا فيه لكن يا تورا هل هيطلع
+
+445
+00:39:12,870 --> 00:39:18,610
+عندى cis او trans هذا بيعتمد ايش موجود اصلا على
+
+446
+00:39:18,610 --> 00:39:23,750
+الجزاء يعني مثلا انبسط عليكم الموضوع كتير انبسط
+
+447
+00:39:23,750 --> 00:39:28,330
+عليكم الموضوع كتير جدا لو احنا كنا جايبينلكم
+
+448
+00:39:28,330 --> 00:39:29,310
+أسيتيلية
+
+449
+00:39:34,340 --> 00:39:38,040
+و أنا بدي اتفتح مخكم كويس جدا عشان تفهموا هذا
+
+450
+00:39:38,040 --> 00:39:42,260
+الكلام إيش معنى mood of addition و إيش معنى
+
+451
+00:39:42,260 --> 00:39:47,800
+product of addition لو أنا جايبلكم أسيتلين و هذا
+
+452
+00:39:47,800 --> 00:39:54,680
+الاسيتلين قولت إنه بدي أضيف عليه هيدروجين بطريقتين
+
+453
+00:39:54,680 --> 00:40:02,460
+مختلفتين بدي أضيف عليه بطريقة .. ممكن هذا ..
+
+454
+00:40:04,520 --> 00:40:10,060
+بطريقة الـ Lithium مع الـ NH3 و ممكن نضيف بطريقة
+
+455
+00:40:10,060 --> 00:40:17,460
+الـ Hydrogen مع الـ Lindler's catalyst ماشي
+
+456
+00:40:17,460 --> 00:40:23,060
+الحالت؟ الان من ناحية المبدأ ك mood of addition
+
+457
+00:40:23,060 --> 00:40:27,740
+كطريقة إضافة الـ Hydrogen مع الـ Lindler's
+
+458
+00:40:27,740 --> 00:40:32,080
+catalyst كيف بيضيفوه؟
+
+459
+00:40:34,520 --> 00:40:40,060
+addition مظبوط ولا لأ؟ طيب إضافة الهيدروجين من
+
+460
+00:40:40,060 --> 00:40:46,100
+خلال الليثيام والليكود أمونيا Anti-addition في
+
+461
+00:40:46,100 --> 00:40:50,520
+خلاف في هالكلام؟ طيب خلينا نرسم النتيجة لو حطينا C
+
+462
+00:40:50,520 --> 00:40:57,260
+double bond C وحطينا هنا H وحطينا هنا H وحطينا
+
+463
+00:40:57,260 --> 00:41:02,600
+اللي ضفناهم باللون الأحمر بهذا الشكل إيش طلع عندى؟
+
+464
+00:41:05,070 --> 00:41:08,830
+إيثالين مافيش فيه cis و trans الإيثالين هل ال mood
+
+465
+00:41:08,830 --> 00:41:14,750
+of addition هل ادول ضافوا من جهة واحدة؟ أكيدضافوا
+
+466
+00:41:14,750 --> 00:41:19,010
+من جهة واحدة لكن هل يا ترى الناتج نفسه في
+
+467
+00:41:19,010 --> 00:41:22,770
+الاثيليين في ال sis و ال trans؟ لأ فالموضوع of
+
+468
+00:41:22,770 --> 00:41:26,410
+addition is in addition لكن الناتج مافيش فيه من
+
+469
+00:41:26,410 --> 00:41:29,850
+الأساس ظاهرة ال sis و ال trans طيب الآن لو اجينا و
+
+470
+00:41:29,850 --> 00:41:33,910
+قولنا هانا بدنا نحط الناتج هيئتش صارت لتحت و هيئتش
+
+471
+00:41:33,910 --> 00:41:41,210
+لفوق اللي ضفناهم كيف ضافوا؟ Anti addition ايش
+
+472
+00:41:41,210 --> 00:41:43,430
+طلعولي؟ اثيليين
+
+473
+00:41:47,930 --> 00:41:53,890
+ملاحظين؟ إذا لو أنا بدي أقولكم the mode of
+
+474
+00:41:53,890 --> 00:41:59,550
+addition of hydrogen to acetylene using hydrogen
+
+475
+00:41:59,550 --> 00:42:05,770
+and lindar catalyst and lithium ammonia is the
+
+476
+00:42:05,770 --> 00:42:13,350
+same غلطال mood of addition طريقة الإضافة مرة ضافه
+
+477
+00:42:13,350 --> 00:42:15,990
+من جهة واحدة مرة ضافه من جهتين هذا ال mood of
+
+478
+00:42:15,990 --> 00:42:21,070
+addition مابختلفش لكن the product of additionنفس
+
+479
+00:42:21,070 --> 00:42:24,070
+الأشياء لأن في الأساس مافيش انتظارة تسس ولا ترازى
+
+480
+00:42:24,070 --> 00:42:29,590
+عشانك انا دائما بفضل ان ايش اقول قدامكم ان طريقة
+
+481
+00:42:29,590 --> 00:42:35,250
+الإضافة من جهة واحدة او من جهتين متعاكستين الان
+
+482
+00:42:35,250 --> 00:42:39,990
+الناتج يكون فيه سس يكون فيه trans هذا باعتمد على
+
+483
+00:42:39,990 --> 00:42:42,810
+ايش المركب اللي عنده ايش ال substituents اللي
+
+484
+00:42:42,810 --> 00:42:49,010
+موجودة واضح الفكرة بمعنى لو أنا كان عند مثل و مثل
+
+485
+00:42:52,660 --> 00:42:55,740
+لأ طبعا .. ما هو .. بدك تكون مراجعة .. احنا قولنا
+
+486
+00:42:55,740 --> 00:43:00,880
+الـ cis و الترانس شرطه ان كل carbon من طرفين ال
+
+487
+00:43:00,880 --> 00:43:03,700
+double bond يكون عليها مجموعتين مختلفتين .. الان
+
+488
+00:43:03,700 --> 00:43:08,180
+هنا من الأساس مافيش شيء .. كله نفس الاشي .. لكن لو
+
+489
+00:43:08,180 --> 00:43:14,520
+افترضتوا هنا مثل و مثل .. هيصير يخلي مثل و مثل و
+
+490
+00:43:14,520 --> 00:43:19,360
+أتش و أتش .. cis .. و هيصير يخلي مثل و مثل و أتش و
+
+491
+00:43:19,360 --> 00:43:24,320
+أتش ..الـ Trans إذا في حالة ما كان عند ال
+
+492
+00:43:24,320 --> 00:43:28,920
+Acetylene ال mode of addition مختلف لكن الناتج
+
+493
+00:43:28,920 --> 00:43:33,520
+واحد في حالة ما كان عنده ال dye مثل ال Acetylene و
+
+494
+00:43:33,520 --> 00:43:36,480
+لا ال dye فين ال Acetylene ال mode of addition
+
+495
+00:43:36,480 --> 00:43:42,480
+برضه مختلف و ال ناتج مختلف عشانك احنا لما بدنا
+
+496
+00:43:42,480 --> 00:43:46,820
+نقول كمبدأ عام بنحكي عن الناتج و لا عن طريقة
+
+497
+00:43:46,820 --> 00:43:52,560
+الإضافةلما بدي احكي قاعدة عامة انا ماعنديش مش عارف
+
+498
+00:43:52,560 --> 00:43:58,400
+اللي بضيف عليه أساسا أسيتلين ولا بروبين ولا
+
+499
+00:43:58,400 --> 00:44:05,960
+توبيوتين في هاد الحالة انا الأفضل ان اقول ال mood
+
+500
+00:44:05,960 --> 00:44:09,700
+of addition ان في كل الأحوال ال hydrogen في وجود
+
+501
+00:44:09,700 --> 00:44:17,640
+لندلار كتاليست proceeds through sin additionالان
+
+502
+00:44:17,640 --> 00:44:21,840
+لو بدكم تاخدوها homework هتلاحظوا انه في حالة ال
+
+503
+00:44:21,840 --> 00:44:27,120
+acetylene الناتجين هيطلعوا نفس الاشي وفي حالة ال
+
+504
+00:44:27,120 --> 00:44:33,280
+bromine لما يكون عندكم تلت ذرات كربون الناتجين نفس
+
+505
+00:44:33,280 --> 00:44:40,100
+الاشي وفي حالة ال one butane الناتجين نفس الاشي
+
+506
+00:44:40,100 --> 00:44:46,270
+وفي حالة ال two butaneالنتيجين مختلفة .. الان بصير
+
+507
+00:44:46,270 --> 00:44:50,610
+عندكم بيمشي اعملوا اتعبوا فيه فكروا بديكوا تعملوا
+
+508
+00:44:50,610 --> 00:44:55,330
+اضافة الهيدروجين باستعمال ليثيام أمونيا و باستعمال
+
+509
+00:44:55,330 --> 00:45:01,270
+هيدروجين لندلارس كاتاليست للأسيتيلين واضح
+
+510
+00:45:01,270 --> 00:45:05,850
+للبروبيلين للبروباين
+
+511
+00:45:05,850 --> 00:45:07,810
+للوانبيوتاين
+
+512
+00:45:09,230 --> 00:45:17,590
+للتو بيوتين أكم مركب أربعة أستيلين بروبين وان
+
+513
+00:45:17,590 --> 00:45:22,870
+بيوتين تو بيوتين اعملوها المرة اللي جاي بتسلموني
+
+514
+00:45:22,870 --> 00:45:27,430
+إياها هتلاحظوا بس بحالة واحدة الناتج بختلف بس في
+
+515
+00:45:27,430 --> 00:45:30,970
+الأربع حالات لو بتستعملوا القلم الأحمر و أنتوا
+
+516
+00:45:30,970 --> 00:45:34,770
+بتحطوا الإضافة لازم هنا تعمله
+
+517
+00:45:37,140 --> 00:45:41,020
+Sin addition وهنا Anti addition فال mood of
+
+518
+00:45:41,020 --> 00:45:44,220
+addition في الأربع حالات لما تستعملون الجلم الأحمر
+
+519
+00:45:44,220 --> 00:45:48,880
+هيطلع نفس ال mood of addition بس الناتج بحالة
+
+520
+00:45:48,880 --> 00:45:52,560
+واحدة بيطلع في مرة ظاهرة تستثمر ل Trans ومرة لأ
+
+521
+00:45:52,560 --> 00:45:56,840
+عشان هيك احنا كنا نركز اننا دايما نقولكوا ال mood
+
+522
+00:45:56,840 --> 00:46:01,520
+of addition ال product بيعتمد على ايش؟ على ال
+
+523
+00:46:01,520 --> 00:46:02,940
+substituents اللي موجودة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..82970695e7e4abc85246623643e6cd8931b5ab17
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/037nYOZIi9o_raw.json
@@ -0,0 +1 @@
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البروتون، نفس البروتون، بس في كل حالة هيظل جزء سالب مختلف عن الجزء التاني، واضح؟ فبناء على ذلك، لما أنا بقارن قوة الأحماض، مابطلعش على البروتون", "tokens": [40228, 22653, 9673, 8592, 28820, 3660, 37893, 8978, 2423, 26890, 35473, 11536, 12399, 5296, 33456, 3224, 45164, 5551, 9778, 3215, 8315, 6225, 46309, 5551, 35571, 46958, 12399, 18863, 46309, 5551, 35571, 46958, 39896, 5172, 37983, 14407, 8717, 36178, 2423, 26890, 35473, 11536, 12399, 8717, 36178, 2423, 26890, 35473, 11536, 12399, 4724, 3794, 8978, 28242, 11331, 6027, 3660, 39896, 19913, 1211, 10874, 11622, 38207, 8608, 6027, 3555, 3714, 46456, 46538, 18871, 25724, 11622, 38207, 16712, 7649, 1829, 12399, 4032, 46958, 5016, 22807, 6156, 3555, 1863, 16606, 15844, 29910, 23275, 12399, 5296, 15042, 41850, 4724, 4587, 9640, 1863, 12174, 2407, 3660, 16247, 35571, 46958, 12399, 3714, 16758, 9566, 1211, 3615, 8592, 15844, 2423, 26890, 35473, 11536], "avg_logprob": -0.11175271946450939, "compression_ratio": 2.056122448979592, 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الأحماض،", "probability": 0.9158935546875}, {"start": 68.95, "end": 69.73, "word": " مابطلعش", "probability": 0.8709309895833334}, {"start": 69.73, "end": 69.93, "word": " على", "probability": 0.8916015625}, {"start": 69.93, "end": 70.73, "word": " البروتون", "probability": 0.987060546875}], "temperature": 1.0}, {"id": 4, "seek": 8906, "start": 71.26, "end": 89.06, "text": "أنا بتطلع على الجزء السالب هل يا ترى الجزء السالب اللي عندى قادر يتحمل الشحنة يحملها ولا لأ يعني مثلا لو بدنا بس كمراجعة بسيطة هتذكركوا في hbr و hcl التانين بيعملوا", "tokens": [10721, 8315, 39894, 9566, 1211, 3615, 15844, 25724, 11622, 38207, 21136, 6027, 3555, 8032, 1211, 35186, 6055, 2288, 7578, 25724, 11622, 38207, 21136, 6027, 3555, 13672, 1829, 43242, 7578, 12174, 18513, 2288, 7251, 2655, 35571, 1211, 25124, 5016, 1863, 3660, 7251, 35571, 1211, 11296, 49429, 5296, 10721, 37495, 22653, 50113, 15040, 45164, 47525, 8315, 4724, 3794, 9122, 29973, 26108, 27884, 4724, 3794, 1829, 9566, 3660, 8032, 2655, 8848, 37983, 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"word": " acid", "probability": 0.90966796875}, {"start": 1420.08, "end": 1421.38, "word": " وبناء", "probability": 0.8284505208333334}, {"start": 1421.38, "end": 1421.58, "word": " على", "probability": 0.6728515625}, {"start": 1421.58, "end": 1421.84, "word": " ذلك", "probability": 0.99609375}, {"start": 1421.84, "end": 1422.44, "word": " مابصيرش", "probability": 0.758056640625}, {"start": 1422.44, "end": 1423.1, "word": " تفاعل", "probability": 0.965087890625}], "temperature": 1.0}, {"id": 58, "seek": 143641, "start": 1424.85, "end": 1436.41, "text": "يعني مابتفعلش ال alcohol مع ال sodium hydroxide كان ممكن انتوا ايش اللي بتتوقعوا انه يعطينا RO minus and A plus بس مع ال sodium hydroxide ال alcohol مابتفعلش", "tokens": [40228, 22653, 3714, 16758, 2655, 5172, 30241, 8592, 2423, 7658, 20449, 2423, 20265, 15435, 34454, 25961, 3714, 43020, 16472, 2655, 14407, 1975, 1829, 8592, 13672, 1829, 39894, 2655, 30543, 3615, 14407, 16472, 3224, 37495, 9566, 1829, 8315, 9025, 3175, 293, 316, 1804, 4724, 3794, 20449, 2423, 20265, 15435, 34454, 2423, 7658, 3714, 16758, 2655, 5172, 30241, 8592], "avg_logprob": -0.2490570992231369, "compression_ratio": 1.5442176870748299, "no_speech_prob": 0.0, "words": [{"start": 1424.85, "end": 1425.53, "word": "يعني", "probability": 0.6240234375}, {"start": 1425.53, "end": 1426.21, "word": " مابتفعلش", "probability": 0.7521158854166666}, {"start": 1426.21, "end": 1426.45, "word": " ال", "probability": 0.8046875}, {"start": 1426.45, "end": 1426.93, "word": " alcohol", "probability": 0.486572265625}, {"start": 1426.93, "end": 1427.25, "word": " مع", "probability": 0.97509765625}, {"start": 1427.25, "end": 1427.41, "word": " ال", "probability": 0.82861328125}, {"start": 1427.41, "end": 1427.65, "word": " sodium", "probability": 0.82080078125}, {"start": 1427.65, "end": 1428.27, "word": " hydroxide", "probability": 0.9345703125}, {"start": 1428.27, "end": 1428.71, "word": " كان", "probability": 0.7421875}, {"start": 1428.71, "end": 1429.05, "word": " ممكن", "probability": 0.924560546875}, {"start": 1429.05, "end": 1429.37, "word": " انتوا", "probability": 0.6116536458333334}, {"start": 1429.37, "end": 1429.53, "word": " ايش", "probability": 0.76708984375}, {"start": 1429.53, "end": 1429.67, "word": " اللي", "probability": 0.873046875}, {"start": 1429.67, "end": 1430.35, "word": " بتتوقعوا", "probability": 0.97919921875}, {"start": 1430.35, "end": 1430.53, "word": " انه", "probability": 0.849365234375}, {"start": 1430.53, "end": 1430.95, "word": " يعطينا", "probability": 0.861572265625}, {"start": 1430.95, "end": 1431.33, "word": " RO", "probability": 0.34423828125}, {"start": 1431.33, "end": 1431.97, "word": " minus", "probability": 0.2271728515625}, {"start": 1431.97, "end": 1432.19, "word": " and", "probability": 0.634765625}, {"start": 1432.19, "end": 1432.33, "word": " A", "probability": 0.91015625}, {"start": 1432.33, "end": 1432.69, "word": " plus", "probability": 0.892578125}, {"start": 1432.69, "end": 1433.53, "word": " بس", "probability": 0.91259765625}, {"start": 1433.53, "end": 1433.71, "word": " مع", "probability": 0.98095703125}, {"start": 1433.71, "end": 1433.87, "word": " ال", "probability": 0.9169921875}, {"start": 1433.87, "end": 1434.15, "word": " sodium", "probability": 0.94970703125}, {"start": 1434.15, "end": 1434.85, "word": " hydroxide", "probability": 0.967529296875}, {"start": 1434.85, "end": 1434.97, "word": " ال", "probability": 0.73486328125}, {"start": 1434.97, "end": 1435.37, "word": " alcohol", "probability": 0.90478515625}, {"start": 1435.37, "end": 1436.41, "word": " مابتفعلش", "probability": 0.8685302734375}], "temperature": 1.0}, {"id": 59, "seek": 146079, "start": 1437.33, "end": 1460.79, "text": "واضح؟ بينما الـ thioalcohols بتعاملوا كأنهم acids RSH زي NAOH حمض زي قاعدة ملح زي دماغ RS minus and A plus هذا الملح زي H2O معدلة الحمض والقاعدة المعروفة عندكم ليس اتفاعل ال RSH مع ال sodium hydroxide", "tokens": [2407, 46958, 5016, 22807, 49374, 15042, 2423, 39184, 258, 1004, 304, 7210, 82, 39894, 3615, 10943, 1211, 14407, 9122, 33456, 16095, 21667, 25855, 39, 30767, 1829, 16585, 31187, 11331, 2304, 11242, 30767, 1829, 12174, 995, 22488, 3660, 3714, 1211, 5016, 30767, 1829, 11778, 2304, 5718, 118, 25855, 3175, 293, 316, 1804, 23758, 9673, 1211, 5016, 30767, 1829, 389, 17, 46, 20449, 3215, 37977, 21542, 2304, 11242, 16070, 4587, 995, 22488, 3660, 9673, 3615, 32887, 5172, 3660, 43242, 24793, 32239, 3794, 1975, 2655, 5172, 995, 30241, 2423, 25855, 39, 20449, 2423, 20265, 15435, 34454], "avg_logprob": -0.24168883517701575, "compression_ratio": 1.4428571428571428, "no_speech_prob": 0.0, "words": [{"start": 1437.33, "end": 1438.21, "word": "واضح؟", "probability": 0.710906982421875}, {"start": 1438.21, "end": 1439.03, "word": " بينما", "probability": 0.95166015625}, {"start": 1439.03, "end": 1439.93, "word": " الـ", "probability": 0.62353515625}, {"start": 1439.93, "end": 1441.35, "word": " thioalcohols", "probability": 0.5758544921875}, {"start": 1441.35, "end": 1442.39, "word": " بتعاملوا", "probability": 0.79462890625}, {"start": 1442.39, "end": 1442.79, "word": " كأنهم", "probability": 0.9270833333333334}, {"start": 1442.79, "end": 1443.37, "word": " acids", "probability": 0.431396484375}, {"start": 1443.37, "end": 1444.67, "word": " RSH", "probability": 0.6177978515625}, {"start": 1444.67, "end": 1444.95, "word": " زي", "probability": 0.4097900390625}, {"start": 1444.95, "end": 1445.75, "word": " NAOH", "probability": 0.7451171875}, {"start": 1445.75, "end": 1446.91, "word": " حمض", "probability": 0.8902994791666666}, {"start": 1446.91, "end": 1447.33, "word": " زي", "probability": 0.9501953125}, {"start": 1447.33, "end": 1448.11, "word": " قاعدة", "probability": 0.9720458984375}, {"start": 1448.11, "end": 1448.53, "word": " ملح", "probability": 0.9611002604166666}, {"start": 1448.53, "end": 1448.81, "word": " زي", "probability": 0.971435546875}, {"start": 1448.81, "end": 1449.07, "word": " دماغ", "probability": 0.731201171875}, {"start": 1449.07, "end": 1449.65, "word": " RS", "probability": 0.57568359375}, {"start": 1449.65, "end": 1450.27, "word": " minus", "probability": 0.2108154296875}, {"start": 1450.27, "end": 1450.59, "word": " and", "probability": 0.487060546875}, {"start": 1450.59, "end": 1450.79, "word": " A", "probability": 0.89208984375}, {"start": 1450.79, "end": 1451.07, "word": " plus", "probability": 0.8701171875}, {"start": 1451.07, "end": 1451.35, "word": " هذا", "probability": 0.76611328125}, {"start": 1451.35, "end": 1451.89, "word": " الملح", "probability": 0.9861653645833334}, {"start": 1451.89, "end": 1452.57, "word": " زي", "probability": 0.937255859375}, {"start": 1452.57, "end": 1453.95, "word": " H2O", "probability": 0.8170572916666666}, {"start": 1453.95, "end": 1454.61, "word": " معدلة", "probability": 0.8356119791666666}, {"start": 1454.61, "end": 1455.15, "word": " الحمض", "probability": 0.9889322916666666}, {"start": 1455.15, "end": 1455.71, "word": " والقاعدة", "probability": 0.9427734375}, {"start": 1455.71, "end": 1456.29, "word": " المعروفة", "probability": 0.9865234375}, {"start": 1456.29, "end": 1456.81, "word": " عندكم", "probability": 0.96337890625}, {"start": 1456.81, "end": 1457.97, "word": " ليس", "probability": 0.6009521484375}, {"start": 1457.97, "end": 1458.51, "word": " اتفاعل", "probability": 0.9056640625}, {"start": 1458.51, "end": 1458.67, "word": " ال", "probability": 0.64892578125}, {"start": 1458.67, "end": 1459.35, "word": " RSH", "probability": 0.82421875}, {"start": 1459.35, "end": 1459.57, "word": " مع", "probability": 0.9892578125}, {"start": 1459.57, "end": 1459.71, "word": " ال", "probability": 0.6357421875}, {"start": 1459.71, "end": 1459.93, "word": " sodium", "probability": 0.56689453125}, {"start": 1459.93, "end": 1460.79, "word": " hydroxide", "probability": 0.946533203125}], "temperature": 1.0}, {"id": 60, "seek": 148148, "start": 1462.08, "end": 1481.48, "text": "أكتر من ال ROH، ال ROH ما تفعلش بالمرة السبب أن هو more acidic than ال alcohol فالثيولز، الثيولز بنقول عنهم they react with sodium hydroxide producing salt and water however alcohols they don't react with", "tokens": [10721, 4117, 2655, 2288, 9154, 2423, 9025, 39, 12399, 2423, 9025, 39, 19446, 6055, 5172, 30241, 8592, 20666, 2304, 25720, 21136, 3555, 3555, 14739, 31439, 544, 39514, 813, 2423, 7658, 6156, 6027, 12984, 1829, 12610, 11622, 12399, 2423, 12984, 1829, 12610, 11622, 44945, 39648, 18871, 16095, 436, 4515, 365, 20265, 15435, 34454, 10501, 5139, 293, 1281, 4461, 7658, 82, 436, 500, 380, 4515, 365], "avg_logprob": -0.3752403846153846, "compression_ratio": 1.382198952879581, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 1462.08, "end": 1462.58, "word": "أكتر", "probability": 0.7640533447265625}, {"start": 1462.58, "end": 1462.78, "word": " من", "probability": 0.986328125}, {"start": 1462.78, "end": 1462.88, "word": " ال", "probability": 0.8857421875}, {"start": 1462.88, "end": 1463.5, "word": " ROH،", "probability": 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0.62255859375}, {"start": 1468.66, "end": 1469.14, "word": " alcohol", "probability": 0.4541015625}, {"start": 1469.14, "end": 1470.96, "word": " فالثيولز،", "probability": 0.5591169084821429}, {"start": 1470.96, "end": 1472.1, "word": " الثيولز", "probability": 0.85517578125}, {"start": 1472.1, "end": 1472.64, "word": " بنقول", "probability": 0.755126953125}, {"start": 1472.64, "end": 1472.9, "word": " عنهم", "probability": 0.950927734375}, {"start": 1472.9, "end": 1473.06, "word": " they", "probability": 0.46826171875}, {"start": 1473.06, "end": 1473.52, "word": " react", "probability": 0.953125}, {"start": 1473.52, "end": 1473.72, "word": " with", "probability": 0.927734375}, {"start": 1473.72, "end": 1474.14, "word": " sodium", "probability": 0.7060546875}, {"start": 1474.14, "end": 1475.28, "word": " hydroxide", "probability": 0.953857421875}, {"start": 1475.28, "end": 1476.46, "word": " producing", "probability": 0.48193359375}, {"start": 1476.46, "end": 1476.96, "word": " salt", "probability": 0.9072265625}, {"start": 1476.96, "end": 1477.28, "word": " and", "probability": 0.96630859375}, {"start": 1477.28, "end": 1477.66, "word": " water", "probability": 0.9150390625}, {"start": 1477.66, "end": 1478.26, "word": " however", "probability": 0.48779296875}, {"start": 1478.26, "end": 1479.24, "word": " alcohols", "probability": 0.571044921875}, {"start": 1479.24, "end": 1479.78, "word": " they", "probability": 0.875}, {"start": 1479.78, "end": 1480.28, "word": " don't", "probability": 0.969482421875}, {"start": 1480.28, "end": 1481.0, "word": " react", "probability": 0.95849609375}, {"start": 1481.0, "end": 1481.48, "word": " with", "probability": 0.93798828125}], "temperature": 1.0}, {"id": 61, "seek": 149295, "start": 1484.17, "end": 1492.95, "text": "واضح؟ رغم أن الـ Sodium Hydroxide عبارة عن مؤسسة قوية لكن ما زال مش قادر يسحب لبروتون", "tokens": [2407, 46958, 5016, 22807, 12602, 17082, 2304, 14739, 2423, 39184, 42059, 2197, 24231, 340, 34454, 6225, 3555, 9640, 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"end": 1488.67, "word": " مؤسسة", "probability": 0.5789306640625}, {"start": 1488.67, "end": 1488.79, "word": " قوية", "probability": 0.70849609375}, {"start": 1488.79, "end": 1489.93, "word": " لكن", "probability": 0.501953125}, {"start": 1489.93, "end": 1490.19, "word": " ما", "probability": 0.2164306640625}, {"start": 1490.19, "end": 1490.55, "word": " زال", "probability": 0.984619140625}, {"start": 1490.55, "end": 1490.71, "word": " مش", "probability": 0.462158203125}, {"start": 1490.71, "end": 1491.09, "word": " قادر", "probability": 0.9768880208333334}, {"start": 1491.09, "end": 1491.73, "word": " يسحب", "probability": 0.9459228515625}, {"start": 1491.73, "end": 1492.95, "word": " لبروتون", "probability": 0.7996826171875}], "temperature": 1.0}, {"id": 62, "seek": 151621, "start": 1494.31, "end": 1516.21, "text": "من الحامض لأن هذا الحامض ضعيف الآن بيظل شغلة انه زي ما بيقولوا وفوق كل ذي علم عليم يعني هذا ال alcohol الحامض الضعيف لو جبتله قاعدة أقوى من ال sodium hydroxide يعني very strong base لاحظوا التعبير تبعي أنا بقول ال sodium hydroxide is", "tokens": [27842, 21542, 10943, 11242, 5296, 33456, 23758, 21542, 10943, 11242, 48812, 3615, 33911, 6024, 48506, 4724, 1829, 19913, 1211, 13412, 17082, 37977, 16472, 3224, 30767, 1829, 19446, 4724, 1829, 39648, 14407, 4032, 5172, 30543, 28242, 29910, 1829, 11203, 2304, 11203, 32640, 37495, 22653, 23758, 2423, 7658, 21542, 10943, 11242, 6024, 114, 3615, 33911, 45164, 10874, 3555, 2655, 43761, 12174, 995, 22488, 3660, 5551, 4587, 2407, 7578, 9154, 2423, 20265, 15435, 34454, 37495, 22653, 588, 2068, 3096, 20193, 5016, 19913, 14407, 16712, 3615, 3555, 13546, 6055, 3555, 3615, 1829, 41850, 4724, 39648, 2423, 20265, 15435, 34454, 307], "avg_logprob": -0.12878543814432988, "compression_ratio": 1.6849315068493151, "no_speech_prob": 2.0265579223632812e-06, "words": [{"start": 1494.31, "end": 1494.71, "word": "من", "probability": 0.52978515625}, {"start": 1494.71, "end": 1495.39, "word": " الحامض", "probability": 0.96337890625}, 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"word": " بدي", "probability": 0.772216796875}, {"start": 2517.69, "end": 2517.99, "word": " اضيف", "probability": 0.9280598958333334}, {"start": 2517.99, "end": 2518.23, "word": " نوك", "probability": 0.5093587239583334}, {"start": 2518.23, "end": 2518.67, "word": " طلق", "probability": 0.70947265625}], "temperature": 1.0}, {"id": 103, "seek": 253948, "start": 2519.45, "end": 2539.49, "text": "لكن إنه عصير وعمل نسبة صغيرة أقل من هذه النسبة مقبول، لكن إنه يضاف متعمداً، لأ، واضح؟ هذا بالنسبة للإيثانول، بنحضره من التخمر، بهيك تقريبا بننهي المحاضرة اليوم", "tokens": [1211, 19452, 36145, 3224, 6225, 9381, 13546, 4032, 25957, 1211, 8717, 35457, 3660, 20328, 17082, 48923, 5551, 4587, 1211, 9154, 29538, 28239, 35457, 3660, 3714, 4587, 3555, 12610, 12399, 44381, 36145, 3224, 7251, 11242, 31845, 44650, 25957, 28259, 14111, 12399, 5296, 10721, 12399, 4032, 46958, 5016, 22807, 23758, 20666, 1863, 35457, 3660, 24976, 28814, 1829, 12984, 7649, 12610, 12399, 44945, 5016, 11242, 2288, 3224, 9154, 16712, 9778, 29973, 12399, 39627, 1829, 4117, 6055, 4587, 16572, 3555, 995, 44945, 1863, 3224, 1829, 9673, 5016, 46958, 25720, 45595, 20498], "avg_logprob": -0.14284446242858062, "compression_ratio": 1.7117647058823529, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 2519.45, "end": 2519.91, "word": "لكن", "probability": 0.7220458984375}, {"start": 2519.91, "end": 2520.13, "word": " إنه", "probability": 0.667236328125}, {"start": 2520.13, "end": 2520.73, "word": " عصير", "probability": 0.9881184895833334}, {"start": 2520.73, "end": 2522.25, "word": " وعمل", "probability": 0.8665364583333334}, {"start": 2522.25, "end": 2522.69, "word": " نسبة", "probability": 0.9853515625}, {"start": 2522.69, "end": 2523.17, "word": " صغيرة", "probability": 0.9925130208333334}, {"start": 2523.17, "end": 2523.77, "word": " أقل", "probability": 0.9495442708333334}, {"start": 2523.77, "end": 2523.95, "word": " من", "probability": 0.98193359375}, {"start": 2523.95, "end": 2524.19, "word": " هذه", "probability": 0.9423828125}, {"start": 2524.19, "end": 2524.71, "word": " النسبة", "probability": 0.9778645833333334}, {"start": 2524.71, "end": 2525.51, "word": " مقبول،", "probability": 0.8138671875}, {"start": 2525.51, "end": 2525.79, "word": " لكن", "probability": 0.9658203125}, {"start": 2525.79, "end": 2526.07, "word": " إنه", "probability": 0.800048828125}, {"start": 2526.07, "end": 2526.85, "word": " يضاف", "probability": 0.9265950520833334}, {"start": 2526.85, "end": 2528.83, "word": " متعمداً،", "probability": 0.757568359375}, {"start": 2528.83, "end": 2530.31, "word": " لأ،", "probability": 0.709228515625}, {"start": 2530.31, "end": 2531.09, "word": " واضح؟", "probability": 0.9376220703125}, {"start": 2531.09, "end": 2531.33, "word": " هذا", "probability": 0.92041015625}, {"start": 2531.33, "end": 2531.83, "word": " بالنسبة", "probability": 0.9862060546875}, {"start": 2531.83, "end": 2532.85, "word": " للإيثانول،", "probability": 0.7814592633928571}, {"start": 2532.85, "end": 2533.51, "word": " بنحضره", "probability": 0.894921875}, {"start": 2533.51, "end": 2534.51, "word": " من", "probability": 0.98779296875}, {"start": 2534.51, "end": 2535.69, "word": " التخمر،", "probability": 0.9598388671875}, {"start": 2535.69, "end": 2535.99, "word": " بهيك", "probability": 0.74267578125}, {"start": 2535.99, "end": 2536.73, "word": " تقريبا", "probability": 0.9974609375}, {"start": 2536.73, "end": 2537.83, "word": " بننهي", "probability": 0.892822265625}, {"start": 2537.83, "end": 2538.87, "word": " المحاضرة", "probability": 0.9854736328125}, {"start": 2538.87, "end": 2539.49, "word": " اليوم", "probability": 0.94775390625}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2541.842, "duration_after_vad": 2436.3906249999914}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..287de5f4dd5fe1e91c711bd995051800b599fdc5
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/03GtMDqeTr8.srt
@@ -0,0 +1,1674 @@
+1
+00:00:09,410 --> 00:00:15,770
+بسم الله الرحمن الرحيم اليوم نبدأ 
+
+2
+00:00:15,770 --> 00:00:21,610
+بفصل جديد هو الفصل الثامن بتعرفوا الفصل السابق كان
+
+3
+00:00:21,610 --> 00:00:27,930
+عن ال alcohols يعني R وH الآن نمشي خطوة للأمام لل
+
+4
+00:00:27,930 --> 00:00:35,390
+ethers بنصير R وR يعني الاختلاف أنه بدلنا H بR
+
+5
+00:00:37,440 --> 00:00:42,040
+بدل ما كان عندي في ال alcohols R.O.H في ال ethers
+
+6
+00:00:42,040 --> 00:00:49,980
+بيصير عندي R.O.R طبعا هذا التبديل الحقيقة بيجلب كل
+
+7
+00:00:49,980 --> 00:00:53,740
+شيء يعني ما بنعش نقول أنه تبديل بسيط لأ الخواص و
+
+8
+00:00:53,740 --> 00:00:58,740
+التحضير كل شيء بيختلف تماما نتيجة هذا التبديل
+
+9
+00:00:58,740 --> 00:01:05,380
+فالخلاصة ال ethers الصيغة العامة لهم إيش R.O.R
+
+10
+00:01:05,380 --> 00:01:12,130
+لاحظوا أول خاصية بتيجي على بالنا ال polarity لما
+
+11
+00:01:12,130 --> 00:01:19,830
+نيجي نقارنهم بال alcohol مثلا R O H ولا R O R؟ R O
+
+12
+00:01:19,830 --> 00:01:26,030
+H is more polar than ethers ليش؟ لأن هناك في عندي
+
+13
+00:01:26,030 --> 00:01:30,870
+hydrogen bonding فال ethers ال polarity تبعتهم أقل
+
+14
+00:01:30,870 --> 00:01:38,890
+من ال alcohol بشكل عام ال solubility برضه بيبطلوا
+
+15
+00:01:38,890 --> 00:01:42,910
+يدوبوا في الماء، ليش؟ لإن أساسا ذائبية ال alcohol
+
+16
+00:01:42,910 --> 00:01:46,290
+في الماء كانت معتمدة على إيش؟ على ال hydrogen
+
+17
+00:01:46,290 --> 00:01:54,060
+bonding، واضح؟ وعلى كبر ال alkyl group الآن يعني
+
+18
+00:01:54,060 --> 00:01:59,120
+ابتداء من ال diethyl ether ال diethyl ether بدوبش في
+
+19
+00:01:59,120 --> 00:02:03,660
+الماء و بيعمله extraction .. بيعمله extraction لل
+
+20
+00:02:03,660 --> 00:02:07,300
+organic compounds بيستعمله واضح؟ يعني إذا قلنا
+
+21
+00:02:07,300 --> 00:02:12,590
+ال dimethyl ether اللي هو أصغر ether هذا غاز لما نبدأ
+
+22
+00:02:12,590 --> 00:02:16,190
+في ال liquids أول liquid في ال ethers ال
+
+23
+00:02:16,190 --> 00:02:19,410
+Diethyl ether ال Diethyl ether لا تدوب في الماء
+
+24
+00:02:19,410 --> 00:02:24,150
+واضح؟ طبعا و باقي ال ethers بالتأكيد لا تدوب في
+
+25
+00:02:24,150 --> 00:02:27,690
+الماء ال melting points و ال boiling points
+
+26
+00:02:27,690 --> 00:02:31,590
+تبعونهم أقل كثير من الالكوهولز لأنهم بالالكوهولز
+
+27
+00:02:31,590 --> 00:02:35,470
+كانوا مرفوعين بال hydrogen bonding يعني ال 
+
+28
+00:02:35,470 --> 00:02:39,510
+Diethyl ether مثلا ال boiling point له ستة
+
+29
+00:02:39,510 --> 00:02:45,290
+و ثلاثين أو سبعة و ثلاثين بينما خدوا الايثانول كان
+
+30
+00:02:45,290 --> 00:02:51,670
+واحد و ثمانين لاحظوا مع العلم ان الايثانول لسه في
+
+31
+00:02:51,670 --> 00:02:57,790
+الوزن جد نصف ال diethyl ether يعني هناك عندي ethyl او
+
+32
+00:02:57,790 --> 00:03:04,150
+ethyl الايثانول ethyl او OH اذا مين أصغر كثير في الوزن
+
+33
+00:03:04,830 --> 00:03:08,950
+الإيثانول لكن في ال boiling point أعلى كثير شو
+
+34
+00:03:08,950 --> 00:03:13,110
+السبب ال hydrogen bonding إذا لاحظوا عما معظم
+
+35
+00:03:13,110 --> 00:03:17,530
+الخواص اللي قادرة تختلف نتيجة اختلاف هذه ال R بدل
+
+36
+00:03:17,530 --> 00:03:24,860
+ما كانت R صارت H واضح أيضا ال Alcohols كانوا
+
+37
+00:03:24,860 --> 00:03:28,240
+بالتفاعلات، اللي لهم عدد كبير من التفاعلات، مظبوط
+
+38
+00:03:28,240 --> 00:03:31,880
+ولا لأ؟ أخذتو تفاعلات substitution و تفاعلات
+
+39
+00:03:31,880 --> 00:03:37,240
+elimination و تفاعلات على حذف ال H مثلًا مع
+
+40
+00:03:37,240 --> 00:03:41,920
+الصوديوم as acids ال ethers they are generally
+
+41
+00:03:41,920 --> 00:03:47,070
+chemically inert، يعني خاملين كيميائيًا و لذلك
+
+42
+00:03:47,070 --> 00:03:53,870
+الكثير من ال ethers تستعمل ك solvent من المميزات
+
+43
+00:03:53,870 --> 00:03:59,990
+اللي لازم يتمتع بفيها ال solvent انه يكون محايد
+
+44
+00:03:59,990 --> 00:04:05,610
+ما يتفعلش يعني أنا بدي إياه وسط وسط لإجراء التفاعل
+
+45
+00:04:05,610 --> 00:04:12,010
+بإنفعش هو يدخل و
+
+46
+00:04:12,010 --> 00:04:16,830
+يتفاعل ال solvent لازم يكون فقط وسط لإجراء التفاعل
+
+47
+00:04:16,830 --> 00:04:22,050
+يكون محايد لا ميل مع هذه المادة ولا مع هذه المادة
+
+48
+00:04:22,050 --> 00:04:25,190
+يعني أنا بدي أدوب مادتين فيه أسيب المادتين
+
+49
+00:04:25,190 --> 00:04:30,490
+يتفاعلوا لحالهم مش هو يروح يتفاعل معهم واضح؟ و هذا
+
+50
+00:04:30,490 --> 00:04:34,570
+الكلام يعني له انعكاس حقيقة في حتى في الواقع
+
+51
+00:04:34,570 --> 00:04:39,850
+الإنساني لما نيجي نقول أنه بدنا شخص يكون واسطة يحل
+
+52
+00:04:39,850 --> 00:04:44,910
+مشكلة بين اثنين المفروض ما يكونش مرتبط لا مع هذا
+
+53
+00:04:44,910 --> 00:04:49,870
+ولا مع هذا أقل تقدير ارتباط male يعني ممكن يكون
+
+54
+00:04:49,870 --> 00:04:58,440
+مرتبط بصداقة بعائلة لكن لما ييجي حكم او وسط مش لازم
+
+55
+00:04:58,440 --> 00:05:03,720
+يميل هان ولا هان إيش مشكلة القضية الفلسطينية كلها؟
+
+56
+00:05:03,720 --> 00:05:10,710
+أن الحكام عوج من الحكام الأمم المتحدة و الاتحاد
+
+57
+00:05:10,710 --> 00:05:14,590
+الأوروبي و بريطانيا و روسيا اللي أسسوا إسرائيل، في
+
+58
+00:05:14,590 --> 00:05:18,070
+آخر بيجروا، بدهم يشرفوا على مفاوضات بين الفلسطينية
+
+59
+00:05:18,070 --> 00:05:22,990
+واليهود، هل هما محايدين؟ عشان هيك كل المسار تبعهم
+
+60
+00:05:24,540 --> 00:05:27,900
+اللي مش مصدق أنه فاشل يقول أنه مش فاشل ما أنتو
+
+61
+00:05:27,900 --> 00:05:31,900
+شايفين يعني ما مافيش بروح مكانه يعني مافيش
+
+62
+00:05:31,900 --> 00:05:35,880
+مفكر إلا بيقول قاعدين بتراوحوا مكانكم و بالعكس
+
+63
+00:05:35,880 --> 00:05:41,820
+بتلتهم الأرض و غيرها و غيرها لإن ال solvent مش
+
+64
+00:05:41,820 --> 00:05:46,100
+inert لازم ال solvent يكون inert ما يدخلش في
+
+65
+00:05:46,100 --> 00:05:52,450
+التفاعل أما نحط أمريكا solvent بنفعش بشكل عام ال 
+
+66
+00:05:52,450 --> 00:05:56,950
+ethers فيهم مشكلة انهم قابلين للاشتعال بمعنى سريع
+
+67
+00:05:56,950 --> 00:06:00,750
+الاشتعال و قابلين للاشتعال عشانك اللي بتعامل مع ال
+
+68
+00:06:00,750 --> 00:06:04,630
+ethers بالذات ال low boiling point ethers اللي هي
+
+69
+00:06:04,630 --> 00:06:09,130
+منخفضة درجة الغليان فبتطلع أبخرتها وين ما في نار في
+
+70
+00:06:09,130 --> 00:06:13,710
+المختبر ممكن تمسك و تولع واضح؟ و لذلك يجب أن يكون
+
+71
+00:06:13,710 --> 00:06:18,290
+عندكم حذر يعني أنا ما زلت بأذكر أنه اثنين زملاء
+
+72
+00:06:18,290 --> 00:06:22,310
+لنا في المختبر واحد مولع نار و بشتغل شغلة و الثاني
+
+73
+00:06:22,310 --> 00:06:26,290
+بعيد مترين منه بشتغل بال ether فجأة اللي مولع
+
+74
+00:06:26,290 --> 00:06:31,570
+النار لجى حاله نفسه مولع من الأبخرة تبع ال ether
+
+75
+00:06:31,570 --> 00:06:37,790
+اللي اجت من الشخص المقابل إذا تعاملتم في المختبر
+
+76
+00:06:37,790 --> 00:06:42,610
+مع ال Ether بتكون تتعاملوا بحذر مش تكونوا حاطين
+
+77
+00:06:42,610 --> 00:06:47,230
+مرتبان Ether مفتوح وعلى بعد عشرين، ثلاثين، أربعين
+
+78
+00:06:47,230 --> 00:06:52,190
+سنتيمتر، نص متر حاطين لبنزين burner أكيد هيعمل
+
+79
+00:06:52,190 --> 00:06:56,470
+حريقة و أكيد هيعمل مصيبة، واضح؟ فالتعامل مع
+
+80
+00:06:56,470 --> 00:07:01,570
+ال Ethers بده حذر لأن ال All are very flammable
+
+81
+00:07:01,570 --> 00:07:07,910
+قابلين للاشتعال و بتولع النار بسرعة الآن إذا بدنا
+
+82
+00:07:07,910 --> 00:07:16,000
+نحكي عن تسمية ال ethers في عندنا common name و
+
+83
+00:07:16,000 --> 00:07:21,540
+IUPAC names ال common name إن أجيب ال ether له
+
+84
+00:07:21,540 --> 00:07:27,540
+جناحين بظبط ولا لأ له مجمعتين إن أجيب الأسماء لل
+
+85
+00:07:27,540 --> 00:07:32,700
+ال alkyl groups و أذكرها يعني لو مثلا عندي هنا مثل و
+
+86
+00:07:32,700 --> 00:07:40,100
+مثل ether مثل و مثل شو بده أسميه؟ die methyl ether لو
+
+87
+00:07:40,100 --> 00:07:45,000
+كانت ethyl او ethyl مرات
+
+88
+00:07:45,000 --> 00:07:48,360
+حتى بيستغنوا عن ال die يعني بتلاقيهم كاتبين methyl
+
+89
+00:07:48,360 --> 00:07:52,120
+ether إذا جربتو methyl ether هو ال die methyl ether او
+
+90
+00:07:52,120 --> 00:07:56,420
+بتلاقيهم كاتبين ethyl ether يعني لو قلتلكم ارسموا ال
+
+91
+00:07:56,420 --> 00:08:02,300
+ethyl ether بتكونوا تحطولي ethyl او ethyl بس اختصارا و
+
+92
+00:08:02,300 --> 00:08:09,000
+خلاص يعني تقليديا صاروا يقولوا إيش بدون إيش؟ بدون
+
+93
+00:08:09,000 --> 00:08:15,420
+كلمة ال die هل يجوز إن الإنسان مثلا يذكر نصف الإسم؟
+
+94
+00:08:15,420 --> 00:08:22,320
+لا و الله إذا فهمت ضمنا يجوز ماشي يعني لو بدنا
+
+95
+00:08:22,320 --> 00:08:27,620
+نعطيكم مثال الناس اللي بيروحوا على الجنوب بيكونوا
+
+96
+00:08:27,620 --> 00:08:32,100
+يشوفوا السيارات بيقولوا ع الدير الكل بيقول ع الدير
+
+97
+00:08:32,100 --> 00:08:35,100
+وين طالع ع الدير ولا بيقول ع الدير البلح كل واحد
+
+98
+00:08:36,120 --> 00:08:41,800
+بنجيب نصف الإسم و يفهم ضمنا؟ أكيد .. اه .. و هنا لو
+
+99
+00:08:41,800 --> 00:08:46,480
+قلت methyl ether أو ethyl ether المقصود فيه die methyl
+
+100
+00:08:46,480 --> 00:08:50,400
+ether و مثلها بالمناسبة ال methyl sulfate كتير بتجروا
+
+101
+00:08:50,400 --> 00:08:55,780
+اسم methyl sulfate بيكون المقصود فيها die methyl sulfate اللي
+
+102
+00:08:55,780 --> 00:09:00,700
+هي مخدة الشكل اللي زيه بس double point او methyl methyl
+
+103
+00:09:00,700 --> 00:09:04,980
+فبنقول احنا die methyl sulfate و ممكن يتلاقوا ناس كثير
+
+104
+00:09:05,230 --> 00:09:11,250
+اختصارا نقولها methyl sulfate، واضح؟ إذا لما يكون هذه
+
+105
+00:09:11,250 --> 00:09:15,770
+المجموعتين زي بعض، خلّيني أقول methyl ether، methyl ether،
+
+106
+00:09:15,770 --> 00:09:19,310
+methyl ether، methyl ether، methyl ether، methyl ether، methyl ether،
+
+107
+00:09:19,310 --> 00:09:21,590
+methyl ether، methyl ether، methyl ether، methyl ether، methyl ether،
+
+108
+00:09:21,590 --> 00:09:23,590
+methyl ether، methyl ether، methyl ether، methyl ether، methyl ether،
+
+109
+00:09:23,590 --> 00:09:23,630
+methyl ether، methyl ether، methyl ether، methyl ether، methyl ether،
+
+110
+00:09:23,630 --> 00:09:25,010
+methyl ether، methyl ether، methyl ether، methyl ether، methyl ether،
+
+111
+00:09:25,010 --> 00:09:29,790
+methyl ether، methyl ether، methyl ether
+
+112
+00:09:48,720 --> 00:09:56,740
+مثلا اذا كان المجموعات مختلفة مثلا انا methyl و انا
+
+113
+00:09:56,740 --> 00:10:05,050
+CH2 CH2 ثم اذا كنت تحب ذكر المجموعتين اذا كنت تحب
+
+114
+00:10:05,050 --> 00:10:07,210
+ذكر المجموعتين اذا كنت تحب ذكر المجموعتين اذا
+
+115
+00:10:07,210 --> 00:10:07,890
+كنت تحب ذكر المجموعتين اذا كنت تحب ذكر
+
+116
+00:10:07,890 --> 00:10:09,510
+المجموعتين اذا كنت تحب ذكر المجموعتين اذا كنت
+
+117
+00:10:09,510 --> 00:10:10,590
+تحب ذكر المجموعتين اذا كنت تحب ذكر المجموعتين
+
+118
+00:10:10,590 --> 00:10:12,950
+اذا كنت تحب ذكر المجموعتين اذا كنت تحب ذكر
+
+119
+00:10:12,950 --> 00:10:14,390
+المجموعتين اذا كنت تحب ذكر المجموعتين اذا كنت
+
+120
+00:10:14,390 --> 00:10:16,130
+تحب ذكر المجموعتين اذا كنت تحب ذكر المجموعتين
+
+121
+00:10:16,130 --> 00:10:21,750
+اذا كنت تحب ذكر المجموعتين اذا كنت تحب ذكر
+
+122
+00:10:21,750 --> 00:10:28,850
+المجمCH3 CH2 ethyl فبصير كله chloromythin ethyl
+
+123
+00:10:28,850 --> 00:10:35,290
+ether واضح؟ الآن لاحظوا التسمية بهذه الطريقة ال
+
+124
+00:10:35,290 --> 00:10:40,030
+common name بتفترض شغلة أنه أنا أكون بسهولة بعرف
+
+125
+00:10:40,030 --> 00:10:42,070
+اسم المجموعة اللي هنا و اللي هنا اللي هنا و اللي
+
+126
+00:10:42,070 --> 00:10:46,990
+هنا اللي هنا اللي هنا مرات كثيرة بتصعب الأمور يعني
+
+127
+00:10:46,990 --> 00:10:51,840
+بمعنى أنه أنتو المجموعات اللي أخذتوها عدد قليل من
+
+128
+00:10:51,840 --> 00:10:55,180
+المجموعات، يعني لو تتذكروا في ال alkyl groups، أنتو
+
+129
+00:10:55,180 --> 00:10:59,100
+أخذتو الميثل، الاثل، البروبل، الايزوبروبل، ال
+
+130
+00:10:59,100 --> 00:11:04,840
+tert-butyl، الفنل، الفنل، الألل، مظبوط ولا لا؟
+
+131
+00:11:04,840 --> 00:11:12,400
+بعد ذلك sec-butyl، بعد ذلك ما أخذتو مجموعات
+
+132
+00:11:12,400 --> 00:11:16,720
+و بناء على ذلك لو إحدى المجموعات كانت كبيرة مالهاش
+
+133
+00:11:16,720 --> 00:11:23,340
+اسم بسيط كيف بدي أسمي يعني لما يجيني مثلا CH3 CH و
+
+134
+00:11:23,340 --> 00:11:28,240
+أحط هنا Cl و أحط هنا CH2 و أحط هنا CH3 ثاني و
+
+135
+00:11:28,240 --> 00:11:33,040
+بعدين أحط هنا O CH3 و أقول بدي أسمي هذا ال ether
+
+136
+00:11:33,040 --> 00:11:39,900
+هنا لاحظوا حاططين عندكم مشكلة أن هذه المجموعة CH3
+
+137
+00:11:40,830 --> 00:11:43,290
+معروفة اسمها مثلًا قابوهادي
+
+138
+00:11:46,370 --> 00:11:49,950
+مش من المجموعات اللي أخذناها و اللي الها اسم و
+
+139
+00:11:49,950 --> 00:11:54,850
+بناء على ذلك إذا كانت إحدى المجموعات مالهاش اسم
+
+140
+00:11:54,850 --> 00:11:59,350
+بسيط زي الأسماء اللي توي ذكرناها المطلوب نحول على
+
+141
+00:11:59,350 --> 00:12:03,910
+نظام ثاني في تسمية ال ethers واضح؟ يعني بتصير
+
+142
+00:12:03,910 --> 00:12:07,550
+المسألة صعبة، ما بقدرش أسميه و أعطي لهذه اسم
+
+143
+00:12:07,550 --> 00:12:12,280
+مجموعة، هذه ما الها نهائيا اسم مجموعة في هذه الحالة
+
+144
+00:12:12,280 --> 00:12:17,380
+ماذا نفعل؟ نستعمل IUPAC نظام of nomenclature
+
+145
+00:12:17,380 --> 00:12:27,580
+نستعمل نظام IUPAC لنومنكلتشر IUPAC يعمل ether مثل
+
+146
+00:12:27,580 --> 00:12:34,520
+ما كنا نتعامل مع الالكينز طبعا أنا ما بفضلش نقعد
+
+147
+00:12:34,520 --> 00:12:38,860
+نجري كل هذا الكلام لكن بإمكاننا ناخد تطبيق بسيط
+
+148
+00:12:38,860 --> 00:12:42,060
+بإمكاننا ناخد تطبيق بسيط بالتطبيق بتصير الأمور
+
+149
+00:12:42,060 --> 00:12:48,100
+سهلة اتخيلوا مثلا هنا عندي ال O و أنا عندي CH2 CH2
+
+150
+00:12:48,100 --> 00:12:54,840
+CH3 واضح ان هذا الصفر هي السلسلة الطويلة و هذا ال
+
+151
+00:12:54,840 --> 00:13:00,100
+O مع ال methyl السلسلة القصيرة الآن لو أنا افترض ان
+
+152
+00:13:00,100 --> 00:13:05,010
+أنا أعطيكم هذا الكلام و حاططلكم هنا Cl بدل الزرجة
+
+153
+00:13:05,010 --> 00:13:11,570
+شو هتسموا المركب؟ 1-chloro propane مظبوط ولا
+
+154
+00:13:11,570 --> 00:13:17,550
+لأ؟ لو حاطط Br 1-bromo propane الآن أنا مش
+
+155
+00:13:17,550 --> 00:13:25,250
+حاططه حاطط المجموعة OCH3 ال OCH3 نفسها الها اسم ..
+
+156
+00:13:25,250 --> 00:13:32,750
+شو اسمها؟ methoxy methoxy مظبوط ولا لأ؟ O methyl methoxy
+
+157
+00:13:33,800 --> 00:13:44,140
+أو ethyl ethoxy أو phenyl phenoxy phenoxy واضح ال O
+
+158
+00:13:44,140 --> 00:13:45,560
+phenyl phenoxy
+
+159
+00:13:49,340 --> 00:13:54,240
+بناء على ذلك ethyl ethoxy وبناء على ذلك ethyl ethoxy
+
+160
+00:13:54,240 --> 00:13:56,260
+وبناء على ذلك ethyl ethoxy وبناء على ذلك ethyl ethoxy
+
+161
+00:13:56,260 --> 00:13:57,040
+وبناء على ذلك ethyl ethoxy وبناء على ذلك ethyl ethoxy
+
+162
+00:13:57,040 --> 00:13:59,320
+وبناء على ذلك ethyl ethoxy وبناء على ذلك ethyl ethoxy
+
+163
+00:13:59,320 --> 00:13:59,960
+وبناء على ذلك ethyl ethoxy وبناء على ذلك ethyl ethoxy
+
+164
+00:13:59,960 --> 00:14:03,320
+وبناء على ذلك ethyl ethoxy وبناء على ذلك 
+
+165
+00:14:03,320 --> 00:14:09,020
+واضح؟ صرت أطول سلسلة عندي سلسلة ال propane و هو ال propane عليه مجموعة
+
+166
+00:14:09,020 --> 00:14:13,980
+ال methoxy الآن لو بدي أجي أطلع على هذا المركب
+
+167
+00:14:18,140 --> 00:14:22,300
+الآن هنا عندي كم كربونة؟ واحدة هنا عندي كم
+
+168
+00:14:22,300 --> 00:14:28,040
+كربونة؟ واحد، اثنين هدول الكربونتين شو عليهم ال
+
+169
+00:14:28,040 --> 00:14:32,520
+substituents؟ كلور على الذرة الأولى و إيش كمان؟
+
+170
+00:14:34,570 --> 00:14:42,850
+و methoxy عليه at n methoxy at n methoxy
+
+171
+00:14:42,850 --> 00:14:48,090
+at n methoxy at n methoxy at n methoxy at n methoxy
+
+172
+00:14:48,090 --> 00:14:50,590
+at n methoxy at n methoxy at n methoxy at n methoxy
+
+173
+00:14:50,590 --> 00:14:52,390
+at n methoxy at n methoxy at n methoxy at n methoxy
+
+174
+00:14:52,390 --> 00:14:53,070
+at n methoxy at n methoxy at n methoxy at n methoxy
+
+175
+00:14:53,070 --> 00:14:58,830
+at n methoxy at n methoxy at n methoxy
+
+176
+00:14:58,830 --> 00:15:06,770
+at n مياللي فوق على موقع at nيت شو شاب
+
+201
+00:16:47,710 --> 00:16:52,670
+ذلك هذه المجموعة لو أنها لحالة بدأ أسميها two
+
+202
+00:16:52,670 --> 00:16:58,420
+-prime-chloroethoxy ممكن نحطها برايم يكون أفضل لما
+
+203
+00:16:58,420 --> 00:17:03,360
+يكون عندكم أكثر من نظام ترقيم في المُركّب، ميزوهم،
+
+204
+00:17:03,360 --> 00:17:07,120
+حطوا شرطة على واحد منهم ف أنا عندي نظام ترقيم
+
+205
+00:17:07,120 --> 00:17:12,880
+للسلسلة الطويلة وعندي نظام ترقيم للسلسلة القصيرة
+
+206
+00:17:12,880 --> 00:17:16,340
+هذه واضح أنها إيثوكسي، بس على بوقع two prime
+
+207
+00:17:16,340 --> 00:17:21,800
+ابتداء من ال Oxygen، شو إجا عندي؟ chloro فصارت two
+
+208
+00:17:21,800 --> 00:17:27,200
+prime chloroethoxy فالمُركّب كله بيصير three two
+
+209
+00:17:27,200 --> 00:17:33,680
+prime chloroethoxy one butanol لأنه alcohol
+
+210
+00:17:33,680 --> 00:17:39,540
+والكحول بنتهي باسم  ol واضح؟ والكحول باسم ol
+
+211
+00:17:39,540 --> 00:17:45,720
+الآن هل يا ترى في واحدة لها مزاج تسمي هذا
+
+212
+00:17:45,720 --> 00:17:51,750
+المُركّب اللي هنا اللي رسمناه عشان نوضح لكم؟ مين
+
+213
+00:17:51,750 --> 00:17:55,270
+بدأت تفضلي؟
+
+214
+00:17:55,270 --> 00:18:00,490
+اتفضلي وين 
+
+215
+00:18:00,490 --> 00:18:07,090
+أطول السلسلة عندك؟ هنا؟
+
+216
+00:18:07,090 --> 00:18:14,290
+كويس، أقرب شيء على ال O وين؟ one two three four
+
+217
+00:18:14,290 --> 00:18:22,800
+ممكن نتخيلها زي هيك أو one two three four الخلاصة
+
+218
+00:18:22,800 --> 00:18:27,840
+أن ال substitutions اللي هنا على موقع اثنين و على
+
+219
+00:18:27,840 --> 00:18:32,560
+موقع ثلاثة على موقع اثنين شوفي عندك كلورو و على
+
+220
+00:18:32,560 --> 00:18:41,340
+موقع ثلاثة مثوكسي والمركب كله بيوتين إذا شو هتسمي
+
+221
+00:18:41,340 --> 00:18:48,560
+هذا المركب two chloro three methoxy
+
+222
+00:18:54,370 --> 00:19:02,530
+تو كلورو ثري ميثوكسي بيوتين واضح طبعًا المركبات لا
+
+223
+00:19:02,530 --> 00:19:06,730
+تنتهي لكن أهم شيء أن أنتم أخذتم المبادئ العامة في
+
+224
+00:19:06,730 --> 00:19:10,670
+التسمية أن في عندك common nomenclature لما تكون
+
+225
+00:19:10,670 --> 00:19:16,530
+المجموعات بسيطة وذات أسماء معروفة وعندك أي
+
+226
+00:19:16,530 --> 00:19:21,210
+IUPAC nomenclature إذا صارت المجموعات أسمائها معقدة
+
+227
+00:19:21,210 --> 00:19:30,680
+وبطل بسيطة هذا بالنسبة لتسمية الـ
+
+228
+00:19:30,680 --> 00:19:31,160
+Ethers
+
+229
+00:19:38,730 --> 00:19:43,890
+معلومة ثقافية عن الـ Ethers الـ Ethers ومشتقاتها
+
+230
+00:19:43,890 --> 00:19:49,470
+هي من أوائل المركبات اللي استعملت كمواد مخدرة
+
+231
+00:19:49,470 --> 00:19:54,410
+وعشانك برضه لا ينصح مثلًا أن طالب يكون بيشتغل بـ
+
+232
+00:19:54,410 --> 00:19:59,010
+Ether ويقعد يتحرك مركب والـ Ether بتبخر جامد منها
+
+233
+00:19:59,010 --> 00:20:03,770
+بيكر لمدة نصف ساعة ساعة وهي تشم Ether Ether Ether
+
+234
+00:20:03,770 --> 00:20:09,410
+ممكن أن هي إيش بشكل أو بآخر تدوخ أو تتخدّر، فالـ
+
+235
+00:20:09,410 --> 00:20:14,870
+ETHER is the first general anesthetic يعني استعمل
+
+236
+00:20:14,870 --> 00:20:21,920
+كمادة مخدرة الآن جزء من اللي بيستعملوه حتى في
+
+237
+00:20:21,920 --> 00:20:26,880
+التطبيق مش ال die-ethyl ether نفسه لكن المشتقات
+
+238
+00:20:26,880 --> 00:20:31,440
+فيه halogens يعني قبلت بعض الظرار ب halogens و
+
+239
+00:20:31,440 --> 00:20:35,300
+ماخد هذه أسماء شهرة يعني هنا مثلًا عندكوا  flurorane 
+
+240
+00:20:35,300 --> 00:20:38,980
+flurorane flurorane flurorane واضح؟ هذا اسمه
+
+241
+00:20:38,980 --> 00:20:44,010
+penthrin وهذا enthrin ما يهمناش نحفظهم، لكن في
+
+242
+00:20:44,010 --> 00:20:49,190
+النهاية هي عبارة عن مواد تستعمل في التخدير وفي
+
+243
+00:20:49,190 --> 00:20:55,610
+الطب اللي بيديه يتعامل مع ال ethers حكينا عن خطرين
+
+244
+00:20:55,610 --> 00:21:02,050
+لحتى الآن لهم وضايل الخطر الثالث الخطر الأول أنهم
+
+245
+00:21:02,050 --> 00:21:09,000
+they are flammable بيشتعلوا بسرعة، بدهم حذر، الخطر
+
+246
+00:21:09,000 --> 00:21:14,400
+الثاني أن جزء منهم have anesthetic properties، لهم 
+
+247
+00:21:14,400 --> 00:21:18,400
+خواص مخدرة وبالتالي الإنسان ما يحطش رأسه جانب ال
+
+248
+00:21:18,400 --> 00:21:23,220
+ether وقاعد .. يشتغلوا شيء ممكن يشيم كمية كبيرة منه
+
+249
+00:21:23,220 --> 00:21:30,080
+الخطر الثالث لل ethers أن الكثير من ال ethers اللي
+
+250
+00:21:30,080 --> 00:21:35,680
+بتكون متروكة لفترات قديمة يعني مخزن مثلًا محطوط فيه
+
+251
+00:21:35,680 --> 00:21:39,440
+ال ether سنتين ثلاث أربع راح الواحد طلب منه بوت
+
+252
+00:21:39,440 --> 00:21:44,860
+ال ether جاب له بوت ال ether ممكن يكون عامل مواد
+
+253
+00:21:44,860 --> 00:21:50,460
+متفجرة يجي البني آدم يشتغل في ال ether ما يسخنوه
+
+254
+00:21:50,460 --> 00:21:55,930
+شوية ولا يكبوا مع الحركة؟ يعمل فيه إيش؟ انفجار
+
+255
+00:21:55,930 --> 00:22:00,510
+ولذلك ال ethers القديمة خطيرة ممكن تكون عاملة
+
+256
+00:22:00,510 --> 00:22:05,530
+إيش؟ مواد متفجرة بتكون عاملة مواد متفجرة لأنها
+
+257
+00:22:05,530 --> 00:22:10,670
+بتعمل أشياء من الأكسجين البسيط اللي في الجو وعلى
+
+258
+00:22:10,670 --> 00:22:15,010
+المدى الزمن البعيد بنسميها إيش؟ peroxides هذه
+
+259
+00:22:15,010 --> 00:22:20,300
+الـ peroxides هي المواد اللي بتسبب الانفجارات في الـ
+
+260
+00:22:20,300 --> 00:22:24,480
+ethers والطلاب لازم يكونوا حذرين منها يعني لو
+
+261
+00:22:24,480 --> 00:22:27,720
+اشتغلتوا في المستقبل في مختبر طب في مختبر 
+
+262
+00:22:27,720 --> 00:22:32,540
+biochemistry whatever لما يجيكم ال ether بدّه
+
+263
+00:22:32,540 --> 00:22:38,140
+يكون في بالكم أن ممكن يكون فيه مشكلة الآن ممكن
+
+264
+00:22:38,140 --> 00:22:42,220
+يكون فيه مشكلة ثقافية هذا الكلام ما ينفعش كيف بدنا
+
+265
+00:22:42,220 --> 00:22:46,140
+نكون إحنا متأكدين أن المشكلة موجودة ولا لأ وإذا
+
+266
+00:22:46,140 --> 00:22:53,650
+موجودة بدنا نعالجها أول شيء كيف بتكون الـ peroxide
+
+267
+00:22:53,650 --> 00:22:58,130
+اللي هي المادة المتفجرة هذه لو مثلًا هذا ال die
+
+268
+00:22:58,130 --> 00:23:02,310
+ethyl ether هو أكثر المواد استعمالًا كـ solvent ترك
+
+269
+00:23:02,310 --> 00:23:06,870
+لفترة طويلة مع الأكسجين بيروح بيضيف لهنا OOH هذا
+
+270
+00:23:06,870 --> 00:23:10,790
+peroxide معنى peroxide يعني في أكسجين زيادة يعني
+
+271
+00:23:10,790 --> 00:23:21,500
+مش OH OOH واضح؟ والتكرار؟ دائمًا بعلم الشطار ويفيد
+
+272
+00:23:21,500 --> 00:23:27,880
+التأكيد اللي بده يكد أي جملة إيش بيعمل بيكرر وهنا
+
+273
+00:23:27,880 --> 00:23:32,320
+بنكرر لل oxygen كثير في الحديث النبوي بيجي تكرار
+
+274
+00:23:32,320 --> 00:23:37,200
+ولا لأ مثلًا في الحديث اللي بيقول فذلكم الرباط
+
+275
+00:23:37,200 --> 00:23:44,800
+فذلكم الرباط فذلكم الرباط مظبوط ولا لأ؟ ألا أدلكم
+
+276
+00:23:44,800 --> 00:23:47,900
+على ما يرفعوا الله به الدرجات ويمحوا به الخطايا
+
+277
+00:23:47,900 --> 00:23:53,280
+قالوا بلى يا رسول الله قال إسباغة الوضوء على
+
+278
+00:23:53,280 --> 00:23:58,280
+المكاري هو كثرة الخطاة إلى المساجد وانتظار الصلاة
+
+279
+00:23:58,280 --> 00:24:03,240
+إلى الصلاة فذلكم الرباط فذلكم الرباط فذلكم الرباط
+
+280
+00:24:03,240 --> 00:24:07,800
+هذا في الحديث النبوي التكرار مشهور كثير لما بده
+
+281
+00:24:07,800 --> 00:24:13,160
+قال أمك ثم أمك ثم أبيك
+
+282
+00:24:14,010 --> 00:24:18,070
+واضح؟ الله يعطيكم العافية من التعب اللي بتشوفوه و
+
+283
+00:24:18,070 --> 00:24:22,110
+الله لو غير كل الحمل والولادة بس مشاكل المناهج
+
+284
+00:24:22,110 --> 00:24:26,490
+الجديدة على الأمهات الله يعطيهم العافية العاملات
+
+285
+00:24:26,490 --> 00:24:28,710
+اللي هي هي وزارة التربية والتعليم واللي بيعلموا
+
+286
+00:24:28,710 --> 00:24:33,890
+صغار بيعرفوا كده الناس صاروا تعبانين بحياتهم من
+
+287
+00:24:33,890 --> 00:24:37,750
+ورا مناهج التربية والتعليم اللي عندها الأطفال
+
+288
+00:24:37,750 --> 00:24:43,110
+الصغار واضح؟
+
+289
+00:24:44,190 --> 00:24:50,490
+ما يهمناش خليهم يسمعونا يعني إحنا اليوم بنجيب لكم معادلة
+
+290
+00:24:50,490 --> 00:24:56,590
+أوزنوها إياها معادلة أكسدة واختزال من السبعين
+
+291
+00:24:56,590 --> 00:25:01,270
+طالبة يمكن خمسة عشر بيجاوبوا إياها صح وأنا لو
+
+292
+00:25:01,270 --> 00:25:04,330
+سألتكم هذا الموضوع وزن المعادلات الأكسدة والاختزال
+
+293
+00:25:04,330 --> 00:25:08,890
+الموضوع سهل ولا صعب جزء كبير منكم هيقول صعب الآن
+
+294
+00:25:08,890 --> 00:25:15,770
+لما بيجوا بيحطوا هذه المعادلة للصف التاسع ويطلبوا
+
+295
+00:25:15,770 --> 00:25:19,310
+منهم أنهم يوزنوها وحتى الأمثلة اللي بيحطوا لهم إياها
+
+296
+00:25:19,310 --> 00:25:25,030
+في الكتاب مش سهلة وأكثر من مدرس ومدرسة شفتهم
+
+297
+00:25:25,030 --> 00:25:30,050
+عاملينها غلط أو مش عارفين يعملوها وعاندين وزارة
+
+298
+00:25:30,050 --> 00:25:34,030
+التربية والتعليم لدرجة أنا مرة بعت لهم رسالة إذا
+
+299
+00:25:34,030 --> 00:25:37,550
+الطالب بيوزن معادلة أكسدة واختزال في ثالثة إعدادي
+
+300
+00:25:37,550 --> 00:25:42,130
+هياخد جائزة نوبل في الكيمياء في أولى ثانوي ومازال
+
+301
+00:25:42,130 --> 00:25:46,370
+الموضوع موجود غصب عنهم الطلاب في الآخر صفي
+
+302
+00:25:46,370 --> 00:25:52,710
+عندنا 15% علمي ولا 20% وباقي الطلاب كله أدبي و
+
+303
+00:25:52,710 --> 00:25:57,090
+ماحدش راضي يدخل الكليات العلمية مظبوط ولا لا؟
+
+304
+00:25:57,090 --> 00:26:01,310
+لأنهم كرهوا الناس في العلم اللي جابنا على هالكلام
+
+305
+00:26:01,310 --> 00:26:09,290
+كله التأكيد والمناهج إذا هذا أكسيد ولا بيروكسيد؟ آه
+
+306
+00:26:09,290 --> 00:26:14,090
+في كم أكسوجين، في أكسجين زيادة الآن هذا
+
+307
+00:26:14,090 --> 00:26:18,270
+البيروكسيد إذا تكون بكمية كبيرة يعني ال ether
+
+308
+00:26:18,270 --> 00:26:22,470
+انترك لفترة طويلة وأخد فترة ومفتوح البوت شوية و
+
+309
+00:26:22,470 --> 00:26:27,710
+دخلوا أكسجين بيصير عبارة عن مادة صلبة موجودة بيشوف
+
+310
+00:26:27,710 --> 00:26:33,950
+الإنسان بعينيه إذا شفتوا في أي بوت الاثر مادة صلبة
+
+311
+00:26:33,950 --> 00:26:37,870
+ارموه ما تستعملوهوش راجعوا ل الفن ولا للشركة
+
+312
+00:26:37,870 --> 00:26:42,950
+يتخلصوا منه منه بطريقتهم يعني ما لهوش علاج معنى ذلك
+
+313
+00:26:42,950 --> 00:26:48,910
+كمية كبيرة منه تحولت إلى بيروكسايد ويمثل خطورة
+
+314
+00:26:48,910 --> 00:26:53,370
+كبيرة الآن ممكن تكون كمية صغيرة تحولت لـ بيروكسايد
+
+315
+00:26:53,370 --> 00:26:59,860
+وذائبة في الاثر يعني أنا أشوفه صافي لكن هو حقيقة في
+
+316
+00:26:59,860 --> 00:27:04,600
+كمية صغيرة ذائبة فيه واضح؟ في هذه الحالة بنعمل له فحص
+
+317
+00:27:04,600 --> 00:27:08,720
+يعني اللي بده يعمل له فحص هو اللي بيكون clear
+
+318
+00:27:08,720 --> 00:27:13,200
+solution أما اللي فيه المادة الصلبة خلاص ما نلزمش
+
+319
+00:27:13,200 --> 00:27:18,840
+نعمل له فحص بلزم نعمل له فحص؟ لأ واضح؟ خلاص بنرجعه
+
+320
+00:27:18,840 --> 00:27:24,340
+الآن اللي فيه المادة ذائبة إيش بنعمل له؟ بنضيفوا
+
+321
+00:27:24,340 --> 00:27:30,580
+عليه FeSO4  فرك الصرفات
+
+322
+00:27:30,580 --> 00:27:36,500
+لأن هذا oxidizing agent بيعمل أكسد لـ Fe2 plus هنا
+
+323
+00:27:36,500 --> 00:27:42,800
+بتصير Fe3 plus ما هو هذا فيه أكسجين زيادة عامل مؤكسد
+
+324
+00:27:42,800 --> 00:27:44,980
+الـ peroxides مؤكسد عامل مؤكسد الـ peroxides مؤكسد
+
+325
+00:27:44,980 --> 00:27:49,500
+عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل
+
+326
+00:27:49,500 --> 00:27:53,580
+مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد
+
+327
+00:27:53,580 --> 00:27:58,000
+عامل مؤكسد
+
+328
+00:27:58,000 --> 00:28:02,680
+عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل
+
+329
+00:28:02,680 --> 00:28:03,660
+مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد عامل مؤكسد
+
+330
+00:28:03,660 --> 00:28:09,840
+عامل مؤكسد عامل مؤكسد الـ Fe3 Plus أخذناه test له
+
+331
+00:28:09,840 --> 00:28:15,800
+كيف بنفحصه؟ بنضيف عليه الـ SCN- بيعطينا اللون
+
+332
+00:28:15,800 --> 00:28:20,760
+الأحمر الدموي الـ red color واضح؟ إذا أنا بضيف
+
+333
+00:28:20,760 --> 00:28:25,820
+FeSO4 على الـ ether اللي بيكون clear بحركه شوية و
+
+334
+00:28:25,820 --> 00:28:32,540
+بحط بعدين فوقه SCN- إذا أعطاني لون أحمر إذا في عنده
+
+335
+00:28:32,540 --> 00:28:37,660
+Fe3+ طب من أين جاء الـ Fe3+، من الـ Fe2+ ما هو
+
+336
+00:28:37,660 --> 00:28:42,920
+بيكسد الـ Fe2+ لـ Fe3+؟ البيروكسايد، إذا أنا شفت
+
+337
+00:28:42,920 --> 00:28:47,890
+اللون الأحمر، معناه ذلك في عنده البيروكسايد واضح؟
+
+338
+00:28:47,890 --> 00:28:52,130
+واعتمدًا على غمق اللون أنا بقدر أقول أن البيروكسايد
+
+339
+00:28:52,130 --> 00:28:57,510
+اللي عندي كثير ولا قليل الآن طالما ال ether clear
+
+340
+00:28:57,510 --> 00:29:01,850
+solution مش راسب المادة كمادة صلبة ممكن أن أعمله
+
+341
+00:29:01,850 --> 00:29:07,510
+معالجة إيش المعالجة اللي بنعملها؟ بصير نضيف عليه
+
+342
+00:29:07,510 --> 00:29:14,790
+كميات أكبر من الـ FeSO4 فهو لما بيشتغل كعامل مؤكسد
+
+343
+00:29:14,790 --> 00:29:20,090
+بيشيل إيش؟ بيشيل هذا الـ Oxygen وبرجع لـ ether
+
+344
+00:29:20,090 --> 00:29:26,370
+عادي، واضح؟ فبن .. بن .. بنعمل له shaking إضافي بكمية
+
+345
+00:29:26,370 --> 00:29:32,310
+أكبر من الـ FeSO4 وبرود بنعمل فحص لحد ما في
+
+346
+00:29:32,310 --> 00:29:40,340
+النهاية أبطل أشوف اللون الأحمر بكون اتخلصت من كل
+
+347
+00:29:40,340 --> 00:29:44,500
+الـ peroxide .. بكون اتخلصت من كل الـ peroxide طبعًا
+
+348
+00:29:44,500 --> 00:29:49,780
+لما إحنا نعمل shaking بيكون هذا محلول مائي وهذا
+
+349
+00:29:49,780 --> 00:29:53,980
+محلول ether يعني ما بيخلطوش مع بعض .. shaking
+
+350
+00:29:53,980 --> 00:30:00,140
+بهدوء مش بقوة كبيرة والمياه بنفصلها بما حاولت مرتين
+
+351
+00:30:00,140 --> 00:30:05,540
+ثلاث بنعود نفحص ال ether بنلاقي رجع ether عادي
+
+352
+00:30:05,540 --> 00:30:15,400
+وبذلك بنتخلص إحنا من قصة اللي هي خطر الـ peroxide أو
+
+353
+00:30:15,400 --> 00:30:19,300
+خطر الانفجار إذا دائمًا وأنتم بتتعاملوا مع ال
+
+354
+00:30:19,300 --> 00:30:21,940
+ethers حطوا في بالكم ثلاث مخاطر
+
+355
+00:30:25,130 --> 00:30:30,130
+anesthetic properties له الشغلة الثانية can form
+
+356
+00:30:30,130 --> 00:30:35,470
+explosive peroxides
+
+357
+00:30:35,470 --> 00:30:40,490
+ممكن يعمل peroxides والـ peroxides هذه لا سمح الله
+
+358
+00:30:40,490 --> 00:30:49,030
+ينفجر واضح؟ بعد ما صار عندي Ether جاهز تمامًا أن أنا
+
+359
+00:30:49,030 --> 00:30:54,890
+أستعمله كـ solvent من أشهر استعمالات ال ether كـ
+
+360
+00:30:54,890 --> 00:31:00,010
+solvent بيستعملوه بتفاعل شهير اسمه Grignard
+
+361
+00:31:00,010 --> 00:31:04,750
+reaction بنحضر من خلاله Grignard reaction وهذا
+
+362
+00:31:04,750 --> 00:31:09,510
+Grignard التفاعل اللي عمله أخد عليه جائزة نوبل في
+
+363
+00:31:09,510 --> 00:31:14,930
+الكيمياء يمكن بالـ 1911 تمامًا قبل مائة سنة عشان
+
+364
+00:31:14,930 --> 00:31:19,210
+تشوفوا كده العالم كان بيشتغلوا متطور في الكيمياء
+
+365
+00:31:19,210 --> 00:31:25,570
+الآن إيش هو تفاعل Grignard reaction هذا تفاعل
+
+366
+00:31:25,570 --> 00:31:31,070
+Grignard reaction لو أنا أخدت RX أو حتى ArX
+
+367
+00:31:31,070 --> 00:31:38,570
+وفعلتها مع بودرة مغنيسيوم واضح؟ الـ RX Alkyl Halide
+
+368
+00:31:38,570 --> 00:31:45,930
+أو ArX يعني هنا يجوز أن تكون RX أو ArX وفعالة مع
+
+369
+00:31:45,930 --> 00:31:51,650
+بودرة مغنيسيوم الشرط في وجود Dry Ether يعني Ether
+
+370
+00:31:51,650 --> 00:31:56,790
+ما فيهوش فيه مية بنمرره على عوامل مجففة بيعطيني
+
+371
+00:31:56,790 --> 00:32:04,710
+هذا المركب RMgX هذا المركب RMgX هو اللي بنسميه
+
+372
+00:32:04,710 --> 00:32:10,85
+
+401
+00:34:36,930 --> 00:34:40,590
+بدأتش أسألكوا سؤال بسيط لو قلتلكوا Greenyard
+
+402
+00:34:40,590 --> 00:34:45,870
+reagent بالمجمل يمثللي Electrophile ولا 
+
+403
+00:34:45,870 --> 00:34:49,350
+Nucleophile؟ Nucleophile 
+
+404
+00:34:51,050 --> 00:34:56,190
+واضح؟ يعني كأنه صار عنده carbon nucleophile هذه
+
+405
+00:34:56,190 --> 00:35:00,190
+فائدة الـ Greenyard Reagent وهذه فائدة كبيرة
+
+406
+00:35:00,190 --> 00:35:05,250
+جداً طبعاً لأنه يمثل الـ nucleophile لأنه يمثل الـ
+
+407
+00:35:05,250 --> 00:35:11,030
+nucleophile وفي إلكترونات وين ما بيلاقي إشي موجب 
+
+408
+00:35:11,030 --> 00:35:18,710
+بده يتفاعل معه مش هو سالب إذا السالب وين ما بيلاقي 
+
+409
+00:35:18,710 --> 00:35:24,410
+موجب بده يتفاعل معاه يعني لو مثلا حطيت ميه أو
+
+410
+00:35:24,410 --> 00:35:29,770
+إيثانول أو حامض أو أمين كل هدولة فيهم ايش القاسم
+
+411
+00:35:29,770 --> 00:35:36,070
+المشترك بينهم الـ H plus بيروح بياخد مباشرة منهم H
+
+412
+00:35:36,070 --> 00:35:43,730
+plus وبيعطيني RH لأنه سالب وبيبحث عن الموجب طبعاً
+
+413
+00:35:43,730 --> 00:35:49,450
+هل يا ترى هذا يعتبر تفاعل؟ هو تفاعل لكنه تفاعل غير 
+
+414
+00:35:49,450 --> 00:35:57,380
+مرغوب لأن الـ R هذه لازماني لأمور أخرى .. الآن تيجي
+
+415
+00:35:57,380 --> 00:36:00,840
+طالبة تشتغل بـ flask يكون فيه شوية ميه وغيره و
+
+416
+00:36:00,840 --> 00:36:04,960
+غيراته وحضرت الـ R MgX ولازم لي لأمور أخرى .. و
+
+417
+00:36:04,960 --> 00:36:09,460
+الـ flask تبعها في ميه .. بتروح الـ R .. بتاخد H و
+
+418
+00:36:09,460 --> 00:36:14,710
+صارت RH .. هو أنا ناقصني RH .. أنا ناقصني الـ R أنا
+
+419
+00:36:14,710 --> 00:36:19,170
+بحضر الـ greenyard عشان في الآخر بده أحضر منه الـ
+
+420
+00:36:19,170 --> 00:36:23,210
+cane ولا لازمنا لتفاعلات تانية لازمنا لتفاعلات
+
+421
+00:36:23,210 --> 00:36:27,870
+تانية ولذلك الشرط هنا ايش يكون هذا الـ dry ether
+
+422
+00:36:27,870 --> 00:36:33,670
+مافيش فيه أي مصدر للـ H plus فكأننا بنقول إن الميه
+
+423
+00:36:33,670 --> 00:36:39,500
+بتخرب تفاعل الـ Greenyard الميّه والإيثانول و
+
+424
+00:36:39,500 --> 00:36:43,300
+الحامض كل شيء فيه H Plus حتى لو أخذنا الماء الثقيل
+
+425
+00:36:43,300 --> 00:36:52,460
+الـ D2O معه، سيعطينا RD إذا أنا مهتم أحضر RD على
+
+426
+00:36:52,460 --> 00:36:56,460
+العين والرأس، بيكون تفاعل إذا مش مهتم، معناه ذلك
+
+427
+00:36:56,460 --> 00:37:03,830
+يعمل بس بتخرّب إذا أنا مهتم أحضر RH على العين والرأس،
+
+428
+00:37:03,830 --> 00:37:07,290
+لكن إذا أنا مش مهتم إن أحضر RH، معناه ذلك الميه
+
+429
+00:37:07,290 --> 00:37:11,950
+هنا، بس بتخرّب علينا، واضح؟ بس بتخرّب علينا 
+
+430
+00:37:16,320 --> 00:37:21,100
+ناخد مثال لو مثلاً قلنا لكم كيف تحضروا هذا 
+
+431
+00:37:21,100 --> 00:37:25,080
+المركب اللي هو الـ isopropyl group اللي متصل 
+
+432
+00:37:25,080 --> 00:37:30,240
+بالديوتيريام الديوتيريام نظير الهيدروجين هتيجي 
+
+433
+00:37:30,240 --> 00:37:37,120
+تفكروا إن هذا من وين بده يكون إجا الديوتيريام بده 
+
+434
+00:37:37,120 --> 00:37:41,440
+يجي من a greenier reaction يعني كأنه الخطوة
+
+435
+00:37:41,440 --> 00:37:47,050
+السابقة بده يكون عندنا هذا المتفاعل مع Mg نفترض بي
+
+436
+00:37:47,050 --> 00:37:54,790
+أفعل هذه مع D2O شو بيعطينا بدل الـ MgBr؟ الـ 
+
+437
+00:37:54,790 --> 00:38:00,950
+Deuterium لو فعلته مع H2O شو بيعطينا بدالها؟ H 
+
+438
+00:38:00,950 --> 00:38:06,270
+رأيته اللي طلعت عنده الـ MgX فعلته مع مية بيعطينا
+
+439
+00:38:06,270 --> 00:38:11,160
+بدالها H فعلته مع D2O بيعطينا بدالها؟ D بناء على
+
+440
+00:38:11,160 --> 00:38:15,280
+ذلك لو أنا كان عندي مركب لبروم وعملت منه green 
+
+441
+00:38:15,280 --> 00:38:20,780
+yard نمرة واحد ونمرة اثنين فعلته مع D2O بحول مركب
+
+442
+00:38:20,780 --> 00:38:27,400
+لبروم إلى D بس كأنه أنا ماشي بخطوتين هي نمرة واحد
+
+443
+00:38:27,400 --> 00:38:33,680
+وهي نمرة اثنين نمرة واحد تتحول مركب بروم و compound
+
+444
+00:38:33,680 --> 00:38:38,000
+لبروم و compound إلى Greenyard نمرة اثنين لـ green 
+
+445
+00:38:38,000 --> 00:38:44,840
+yard إن فعلته مع الـ D2O بيجي مكانه ديوتيريام إذا لو
+
+446
+00:38:44,840 --> 00:38:49,360
+أنا قلتلكم من الـ isopropyl bromide بدي مركب 
+
+447
+00:38:49,360 --> 00:38:54,400
+لديوتيريام، بدنا نمشي كام خطوة؟ واحدة، اثنتين طيب،
+
+448
+00:38:54,400 --> 00:38:57,340
+لو ما عطيتكوش الـ isopropyl bromide، لو رجعت فيكوا
+
+449
+00:38:57,340 --> 00:39:00,740
+خطوة لورا، أراجع الـ synthesis اللي اتعلمتوا،
+
+450
+00:39:00,740 --> 00:39:07,660
+قلتلكوا بدي من الـ .. البروبيل، بنضيف HBr في وجود
+
+451
+00:39:08,980 --> 00:39:13,800
+الـ H plus بيحط H وبيقعد صار عندي هذا وبنكمل إذا 
+
+452
+00:39:13,800 --> 00:39:18,020
+نزلنا بس ايش خطوة لو كان عندي هنا الـ alcohol هذه
+
+453
+00:39:18,020 --> 00:39:20,740
+مش alcohol
+
+454
+00:39:22,380 --> 00:39:26,960
+Isopropyl Alcohol وقلتلكم من الـ Isopropyl Alcohol
+
+455
+00:39:26,960 --> 00:39:31,620
+سؤال في الامتحان How can you prepare this compound
+
+456
+00:39:31,620 --> 00:39:34,860
+starting from isopropyl alcohol أنتو حتيجوا
+
+457
+00:39:34,860 --> 00:39:37,180
+ترجعوا برجعوا لورا بتعملوا إشي بنسميه
+
+458
+00:39:37,180 --> 00:39:42,840
+Retrosynthesis بتقولوا هذه الـ D كانت MgBr الـ MgBr
+
+459
+00:39:42,840 --> 00:39:47,520
+كانت Br أنا ما عنديش Br أنا عندي OH هل تعلمنا 
+
+460
+00:39:47,520 --> 00:39:56,330
+طريقة أن أحول فيها الـ OH إلى Br أكيد كنا نفعل مع الـ
+
+461
+00:39:56,330 --> 00:40:01,990
+PBr3 أو الـ HBr في تفاعلات الـ alcohols لما أخذنا
+
+462
+00:40:01,990 --> 00:40:10,350
+reaction of alcohols with HBr أو PBr3 هنا الـ HBr 
+
+463
+00:40:10,350 --> 00:40:17,610
+بيمشي والـ PBr3 بيمشي واضح؟ لو كنا بنتحولها لـ Cl
+
+464
+00:40:17,610 --> 00:40:27,410
+بنفعل HCl الالكول بيتحول بسهولة باستعمال الـ HCl ولا 
+
+465
+00:40:27,410 --> 00:40:34,290
+لازم أستعمل reagent تاني؟ يا بتستعمل BCl3 يا 
+
+466
+00:40:34,290 --> 00:40:41,750
+ثيونيل كلوريد تذكروا آخر محاضرة قلنا الـ alcohols 
+
+467
+00:40:41,750 --> 00:40:47,690
+لما بتحولوا لـ alkyl halides كنا بنستعمل BX3 أو
+
+468
+00:40:47,690 --> 00:40:49,710
+ثيونيل كلوريد 
+
+469
+00:40:56,340 --> 00:41:00,700
+تذكرتكم؟ على أي حال بنقف عند هذا الموضوع وإن شاء
+
+470
+00:41:00,700 --> 00:41:04,720
+الله المحاضرة الجاية بنحكي فيه الـ preparation of
+
+471
+00:41:04,720 --> 00:41:07,380
+ethers and their reactions
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/0sNdGGE2F3c.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/0sNdGGE2F3c.srt
new file mode 100644
index 0000000000000000000000000000000000000000..782f7cef51ac1eb46dd7af5048b5f49dd8ad7896
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/0sNdGGE2F3c.srt
@@ -0,0 +1,1772 @@
+1
+00:00:05,480 --> 00:00:11,260
+اليوم إن شاء الله هنتهي من الفصل الخامس المتعلق
+
+2
+00:00:11,260 --> 00:00:17,080
+بالـStereochemistry وربما أيضًا هنا يعني نبدأ 
+
+3
+00:00:17,080 --> 00:00:24,540
+بإعطاء مقدمة للفصل السادس ربما نبدأ بإعطاء مقدمة 
+
+4
+00:00:24,540 --> 00:00:31,060
+للفصل السادس أخذنا احنا في الـStereochemistry اللي
+
+5
+00:00:31,060 --> 00:00:38,120
+هي تعريف الـStereoisomers وأنواعها الأساسية اللي
+
+6
+00:00:38,120 --> 00:00:41,140
+هي Enantiomers وDiastereomers وكيف نحدد
+
+7
+00:00:41,140 --> 00:00:45,300
+configuration وكيف نعرف العلاقة بين مركبين هل هما
+
+8
+00:00:45,300 --> 00:00:49,380
+Enantiomers أو Diastereomers أو نفس المركب من خلال
+
+9
+00:00:49,380 --> 00:00:54,020
+أن نحدد الـconfiguration أخذنا أيضًا الأمور
+
+10
+00:00:54,020 --> 00:00:56,920
+المتعلقة بالـphysical والـchemical properties
+
+11
+00:00:56,920 --> 00:01:01,040
+ربما من أهمها أن الـphysical properties لل
+
+12
+00:01:01,040 --> 00:01:07,230
+Enantiomers نفس الشيء ما عدا في خاصية الـrotation
+
+13
+00:01:07,230 --> 00:01:12,030
+of a plane polarized light direction of rotation
+
+14
+00:01:12,030 --> 00:01:17,850
+اليوم بناخد بعض التفاعلات متعلقة بالـstereo
+
+15
+00:01:17,850 --> 00:01:24,350
+isomers هتلاحظوا كيف أنه العلم كيف أنه العلم 
+
+16
+00:01:24,350 --> 00:01:30,810
+بيضلوا يتوسع يعني أنتم بتتعلموا نقطة صحيحة بتعتقدوا
+
+17
+00:01:30,810 --> 00:01:35,570
+لما تتعلموا النقطة أنه خلاص يعني أخذنا كل ما يتعلق
+
+18
+00:01:35,570 --> 00:01:41,110
+بهذا الموضوع للأسف أنه مرات احنا لما بندرسكم
+
+19
+00:01:41,110 --> 00:01:45,910
+بنضوّيلكوا على جزء من المعلومة بنعلمكوا إياها و
+
+20
+00:01:45,910 --> 00:01:51,530
+بنخفي جزء الآن يمكن يجئ وقت أشياء كنتوا تعتقدوها
+
+21
+00:01:51,530 --> 00:01:57,470
+بسيطة تلاحظوا أنه هي لأ مش بها البساطة واضح؟
+
+22
+00:01:57,470 --> 00:02:03,390
+هتلاحظوها من خلال إيش؟ من خلال تفاعلات المتعلقة 
+
+23
+00:02:03,390 --> 00:02:07,990
+بالـStereochemistry التفاعل الأول اللي بدنا ندرسه
+
+24
+00:02:07,990 --> 00:02:13,830
+بنسميه generation of a chiral center يعني ما كانش في
+
+25
+00:02:13,830 --> 00:02:18,350
+عندي أنا chiral center، بدأ أعمل تفاعل أصير chiral
+
+26
+00:02:18,350 --> 00:02:22,850
+center إيش معنى الحكي؟ معنى الحكي أنه ما كانش في 
+
+27
+00:02:22,850 --> 00:02:28,400
+عندي carbon عليها أربع مجموعات مختلفة لما بدأ أعمل 
+
+28
+00:02:28,400 --> 00:02:32,540
+تفاعل الـcarbon هذه بدأت تصير عليها أربع مجموعات
+
+29
+00:02:32,540 --> 00:02:38,240
+مختلفة فبدأت تصير في عندي chiral center واضح؟ ممكن
+
+30
+00:02:38,240 --> 00:02:43,340
+ناخد مثال على هذا الكلام لو أخذنا تفاعل أخذناه في 
+
+31
+00:02:43,340 --> 00:02:47,520
+الـalkanes لبيوتين العادي لما نعمله chlorination
+
+32
+00:02:47,520 --> 00:02:52,440
+كنا نقول نعمل chlorination احنا على موقع واحد وعلى
+
+33
+00:02:52,440 --> 00:02:56,520
+موقع اثنين مصبوط ولا لأ؟ لما نجي نعمل الـ
+
+34
+00:02:56,520 --> 00:02:59,760
+chlorination ونحط في البيوتين الاربع كربونات 
+
+35
+00:02:59,760 --> 00:03:06,540
+كلورة على موقع واحد، هل بنعمل chiral center جديد؟
+
+36
+00:03:06,540 --> 00:03:13,900
+ليش؟ لأنه موقع واحد CH3 ومتصل الباقي الجزء لما أشيل
+
+37
+00:03:13,900 --> 00:03:21,220
+منه H تصير CH2 وCl ومتصل الباقي الجزء إذا صار عندي
+
+38
+00:03:21,220 --> 00:03:25,360
+أربع مجموعات مختلفة لأ فإني لو عملت chlorination
+
+39
+00:03:25,360 --> 00:03:31,820
+على موقع واحد ما عملتش generation أو توليد لـchiral
+
+40
+00:03:31,820 --> 00:03:35,980
+center بيطلع عندي one compound الآن لما كنا نقولكم 
+
+41
+00:03:35,980 --> 00:03:39,420
+أعطونا ناتج ثاني كنتوا تقول والله الـchlorine بيجي
+
+42
+00:03:39,420 --> 00:03:43,410
+على موقع واحد يعني موقع اثنين إذا كم نتيجة بيطلع
+
+43
+00:03:43,410 --> 00:03:49,850
+عندك اثنين الآن دعنا ندرس موقع اثنين بالتفصيل لما 
+
+44
+00:03:49,850 --> 00:03:53,010
+يجي الـchlorine على موقع اثنين لاحظوا أنا موقع 
+
+45
+00:03:53,010 --> 00:03:59,030
+اثنين متصل بـmethyl وethyl وH وH مظبوط ولا لا
+
+46
+00:03:59,030 --> 00:04:03,830
+الآن لما أنا بدي أشيل واحدة من هدول الـhydrogens واحط
+
+47
+00:04:03,830 --> 00:04:08,050
+بدالها chlorine شوف صار موقع اثنين صار أربع
+
+48
+00:04:08,050 --> 00:04:13,260
+مجموعات مختلفة صار chiral center لاحظين؟ إذا نتذكر كيف 
+
+49
+00:04:13,260 --> 00:04:17,120
+كانت العملية تتم حسب الميكانيزم اللي أخذناها للـ
+
+50
+00:04:17,120 --> 00:04:21,120
+free radical substitution الـchlorine radical اللي
+
+51
+00:04:21,120 --> 00:04:24,840
+بياخد الـH بيصير عندي methyl radical هذا الـcarbon
+
+52
+00:04:24,840 --> 00:04:31,830
+radical اللي هو حامل مجموعة CH3 وethyl وH هذا الـ
+
+53
+00:04:31,830 --> 00:04:38,230
+radical ميزته أنه planar كيف يعني planar؟ بهذا
+
+54
+00:04:38,230 --> 00:04:41,950
+الشكل لو بتعمله model أنا زي ما هو مرسوم عندكم على
+
+55
+00:04:41,950 --> 00:04:47,930
+اللوح بهذا الشكل تماما طلعوا عليه هاي الـhydrogen
+
+56
+00:04:49,910 --> 00:04:56,650
+methyl CH3 كربونة هاي ethyl CH2CH3 وهذا إيش ماله الـ
+
+57
+00:04:56,650 --> 00:05:00,050
+planar لسه في نص الطريق الـplanar free radical
+
+58
+00:05:00,050 --> 00:05:05,810
+الآن هذه الكلور واقفة هنا وبدأ تيجي تتفاعل في عدة 
+
+59
+00:05:05,810 --> 00:05:11,230
+احتمالين إما أن تأتي من الأمام وهؤلاء بيرتدوا 
+
+60
+00:05:11,230 --> 00:05:16,630
+للخلف أو تأتي من الجهة الثانية إذاً لأن هذا planar
+
+61
+00:05:16,630 --> 00:05:21,970
+لأن هذا في مستوى واحد الكلور بيصير لإحتمالين عندها 
+
+62
+00:05:21,970 --> 00:05:24,950
+متساويات يا بتيجي من هنا يا من هنا أو لو مسكته زي 
+
+63
+00:05:24,950 --> 00:05:31,270
+هيك هاي الكلور إما بهذا الشكل أو بهذا الشكل واضح
+
+64
+00:05:31,270 --> 00:05:35,070
+هذا الكلام طالما الكلور بيمكنها تيجي من الأمام و
+
+65
+00:05:35,070 --> 00:05:38,490
+الخلف أو من الجنبين بيقدر إلى تكوين
+
+66
+00:05:41,030 --> 00:05:44,650
+two enantiomers لما بتقول واحد الكلور في بهذا الشكل
+
+67
+00:05:44,650 --> 00:05:50,850
+والثاني بهذا الشكل اتخيلهم كأنهم صورة مرآة لبعض و
+
+68
+00:05:50,850 --> 00:05:55,370
+من بعض إيش بتلاحظوا أنه عندي تكون two
+
+69
+00:05:55,370 --> 00:06:01,950
+enantiomers مش واحد الآن السؤال بأي نسبة لما تكون
+
+70
+00:06:01,950 --> 00:06:08,140
+هذه الكلور بعيدة وهذا بلا نار هل يتراخى هذا الموقع 
+
+71
+00:06:08,140 --> 00:06:14,510
+من هذا الاتجاه بيفرق عن هذا الموقع؟ كاحتمالات ما فيش
+
+72
+00:06:14,510 --> 00:06:19,050
+أي فرق بين هدول الاحتمالين ولذلك بتكون النسبة 
+
+73
+00:06:19,050 --> 00:06:24,570
+50% إلى 50% واضح؟ 50% إلى
+
+74
+00:06:24,570 --> 00:06:27,610
+50% هذا اللي بنسميه احنا إيش 
+
+75
+00:06:27,610 --> 00:06:35,150
+racemic mixture racemic mixture إذا عملية 
+
+76
+00:06:35,150 --> 00:06:39,930
+الإبدال على موقع اثنين كم ناتج بتطلع له ناتجين مش
+
+77
+00:06:39,930 --> 00:06:45,110
+ناتج واحد واضح؟ تنسوش أنه الإبدال على موقع واحد، 
+
+78
+00:06:45,110 --> 00:06:48,670
+كده كان يطلع عليه ناتج واحد، لأنه ما صار chiral
+
+79
+00:06:48,670 --> 00:06:53,390
+center إذا لو بدنا نيجي نسأل مرة جديدة، الـ
+
+80
+00:06:53,390 --> 00:06:57,610
+chlorination للي بيوتين بالمجمل كم ناتج بيطلع؟
+
+81
+00:06:59,810 --> 00:07:05,030
+ثلاثة على موقع واحد ناتج واحد على موقع اثنين بيطلع 
+
+82
+00:07:05,030 --> 00:07:09,570
+لـR-2-chlorobutane وS-2-chlorobutane شوفوا أنا و
+
+83
+00:07:09,570 --> 00:07:13,210
+R وأنا وS المهم اثنين إذا صار المجموع ثلاثة
+
+84
+00:07:13,210 --> 00:07:16,370
+لاحظوا احنا كنا نقول إيش كلام متناقض يعني أول ما 
+
+85
+00:07:16,370 --> 00:07:19,730
+كنا نعلمكوا في chapter تفاعلات الالكينز كنا
+
+86
+00:07:19,730 --> 00:07:24,240
+نقولكم بيطلع عندكم two products 1-chlorobutane 
+
+87
+00:07:24,240 --> 00:07:27,860
+و2-chlorobutane الآن قاعدين بنقولكم الـtwo
+
+88
+00:07:27,860 --> 00:07:33,900
+chlorobutane عبارة عن مركبين R-2-chlorobutane وS
+
+89
+00:07:33,900 --> 00:07:38,500
+-2-chlorobutane الحقيقة حسب طريقة الكلام يعني أنا
+
+90
+00:07:38,500 --> 00:07:42,660
+ما أعتقدش أنه الكلام متناقض ليش؟ لأنه لو احنا بنحكي
+
+91
+00:07:42,660 --> 00:07:46,520
+عن structural isomers بدون ما ناخد الـstereo
+
+92
+00:07:46,520 --> 00:07:50,540
+chemistry في عين الاعتبار بيطلع عندي two structural 
+
+93
+00:07:50,540 --> 00:07:55,940
+isomers الـone والـtwo هدول العلاقة بينهم إيش؟
+
+94
+00:07:55,940 --> 00:07:59,140
+structural isomers 1-chlorobutane يعني بنجيبلكوا
+
+95
+00:07:59,140 --> 00:08:02,640
+يا سؤال في الامتحان 1-chlorobutane is a
+
+96
+00:08:02,640 --> 00:08:06,780
+structural isomer of 2-chlorobutane لأنه
+
+97
+00:08:06,780 --> 00:08:12,980
+بيختلفوا بالاسم بيختلفوا بمواقع الارتباط لكن الـR-2
+
+98
+00:08:12,980 --> 00:08:16,540
+-chlorobutane والـS-2-chlorobutane they are
+
+99
+00:08:17,840 --> 00:08:20,880
+stereoisomers، إذا لو بدأت أقول كم structure الـ
+
+100
+00:08:20,880 --> 00:08:24,320
+isomers بتطلع عندي اثنين، لكن كم الـtotal
+
+101
+00:08:24,320 --> 00:08:29,320
+isomers ثلاثة، واضح؟ لأن الـ2-chlorobutane فيه 
+
+102
+00:08:29,320 --> 00:08:35,660
+منه مركبين الـR والـS، إذا هنا بنقدر نقول البساطة
+
+103
+00:08:35,660 --> 00:08:40,740
+إنّ generation of a chiral center produces a
+
+104
+00:08:40,740 --> 00:08:45,660
+racemic mixture ليش الـracemic mixture؟ لأنّ الـ
+
+105
+00:08:45,660 --> 00:08:49,020
+intermediate الـfree radical اللي تكون عندي بالنص
+
+106
+00:08:49,020 --> 00:08:52,740
+كان planar فصاروا الاحتمالات أنه يتفاعل من اليمين 
+
+107
+00:08:52,740 --> 00:08:59,340
+أو من الشمال نفس الاحتمالات واضح؟ هذا مثال ممكن
+
+108
+00:08:59,340 --> 00:09:04,150
+ناخد مثال ثاني والمثال الثاني مر علينا أيضًا لما 
+
+109
+00:09:04,150 --> 00:09:11,750
+كنا نجي نعمل عملية addition لـ1-butene إضافة
+
+110
+00:09:11,750 --> 00:09:18,010
+HBr على حسب قاعدة Markovnikov addition في وجود الـ
+
+111
+00:09:18,010 --> 00:09:24,390
+H+ متذكرينها؟ كانت العملية الإضافة نقطة
+
+112
+00:09:24,390 --> 00:09:28,630
+البداية تبعتها أنّ الـH+ يضيف على موقع واحد
+
+113
+00:09:28,630 --> 00:09:33,700
+عشان يتكون عندي carbocation على الموقع اثنين في هذه
+
+114
+00:09:33,700 --> 00:09:39,120
+الحالة، سيكون عنده مجموعة مثل الـCH3 واضافت عليها
+
+115
+00:09:39,120 --> 00:09:44,800
+H مجموعة ethyl، اللي هي باقي الجزيرة والـH اللي
+
+116
+00:09:44,800 --> 00:09:50,740
+موجودة أصلاً وcarbocation واضح؟ هذا الـ
+
+117
+00:09:50,740 --> 00:09:54,180
+carbocation أيضًا شكله بلنر زي الـfree 
+
+118
+00:09:54,180 --> 00:09:59,080
+radical بناءً على ذلك، لما يتم التفاعل الآن الـ
+
+119
+00:09:59,080 --> 00:10:04,900
+carbocation، ماذا يأتي له؟ سيال ماينص الفري راديكل
+
+120
+00:10:04,900 --> 00:10:08,440
+كان يجيله راديكل كان ياخذ راديكل لما يكون هذا موجب
+
+121
+00:10:08,440 --> 00:10:12,540
+شو بده يجيله؟ هي سيال ماينص مع إلكتروناته طالما 
+
+122
+00:10:12,540 --> 00:10:17,080
+أنه planar مرة ثانية ممكن ييجي عن اليمين أو ممكن 
+
+123
+00:10:17,080 --> 00:10:23,380
+ييجي عن الشمال وبناءً على ذلك هيطلع عنده الـtwo
+
+124
+00:10:23,380 --> 00:10:32,410
+products بيوتين لكن بيطلع منه اللي هو الـS والـR بيطلع 
+
+125
+00:10:32,410 --> 00:10:37,970
+منه الـS والـR isomers لاحظوا معنى عمل العلم
+
+126
+00:10:37,970 --> 00:10:41,630
+بتوسع احنا زمان كنا نقولكم ببساطة أنّ addition
+
+127
+00:10:41,630 --> 00:10:49,750
+of HBr to 1-butane produces 2-bromobutane 
+
+128
+00:10:49,750 --> 00:10:53,850
+مظبوط ولا لأ؟ الآن نكتشف أنه لأ هو ما بيطلعش مركب
+
+129
+00:10:53,850 --> 00:11:02,000
+واحد هو بيطلع الـR-2-bromobutane هذا والـS-2
+
+130
+00:11:02,000 --> 00:11:06,780
+-bromobutane اللي هو المركب هذا مرة ثانية بتلاحظوا 
+
+131
+00:11:06,780 --> 00:11:10,880
+أنه أنا هنا ما كانش عندي ولا chiral center في الجزء
+
+132
+00:11:10,880 --> 00:11:15,940
+اللي ابتديت منه صار في عندي chiral centers لما 
+
+133
+00:11:15,940 --> 00:11:19,300
+تكون chiral centers بتكون racemic mixture
+
+134
+00:11:19,300 --> 00:11:24,010
+بنسبة 50% إلى 50% بناءً على ذلك
+
+135
+00:11:24,010 --> 00:11:29,490
+لو جينا ندرس الـoptical activity لو جبت كل الـ
+
+136
+00:11:29,490 --> 00:11:33,070
+reactants اللي هنا قبل التفاعل وحطيته في الـ
+
+137
+00:11:33,070 --> 00:11:37,910
+polarimeter بيكون active ولا inactive؟ inactive لو 
+
+138
+00:11:37,910 --> 00:11:43,490
+جبت خليط النواتج وحطيته في الـpolarimeter؟ 
+
+139
+00:11:43,490 --> 00:11:48,610
+inactive لأنه بنسبة 50% إلى 50% صفر الـrotation تبعه
+
+140
+00:11:48,610 --> 00:11:53,220
+وهذا نفس الأشياء ما فيش chiral center inactive هنا 
+
+141
+00:11:53,220 --> 00:11:57,360
+racemic mixture والـracemic mixture inactive صار في 
+
+142
+00:11:57,360 --> 00:12:01,620
+عندنا قاعدة في الـstereo chemistry بتقول القاعدة
+
+143
+00:12:01,620 --> 00:12:07,620
+بتقول optically inactive reactants produces 
+
+144
+00:12:07,620 --> 00:12:13,340
+optically inactive products اللي بنقصده هنا أنّ كلّ
+
+145
+00:12:13,340 --> 00:12:17,600
+الناتج على بعضه لو بعدك بطريقة ما فصلت هذا لحاله و
+
+146
+00:12:17,600 --> 00:12:21,110
+بعد لحاله هذا بيكون active وهذا active لكن أنا
+
+147
+00:12:21,110 --> 00:12:26,230
+بحكي كنتج الناتج racemic mixture inactive عشانك
+
+148
+00:12:26,230 --> 00:12:31,070
+القاعدة العامة optically inactive reactants
+
+149
+00:12:31,070 --> 00:12:36,550
+produces optically inactive products طبعًا ما حدش 
+
+150
+00:12:36,550 --> 00:12:43,870
+يعتقد أنّ عكس هذه القاعدة بيكون صحيح ما بنقولش احنا 
+
+151
+00:12:43,870 --> 00:12:46,850
+optically active reactants produces optically
+
+152
+00:12:46,850 --> 00:12:50,330
+active products هذه الجملة المعاكسة مرات بتظبط
+
+153
+00:12:50,330 --> 00:12:55,270
+مرات لأ لكن الجملة الأكيدة optically inactive
+
+154
+00:12:55,270 --> 00:12:58,490
+reactants produces optically inactive products
+
+155
+00:12:58,490 --> 00:13:03,530
+واضح؟ هذه الجملة الأكيدة إذا استوعبتوا بالظبط إيش
+
+156
+00:13:03,530 --> 00:13:06,950
+اللي بيصير عندي لما نعمل generation of a chiral
+
+157
+00:13:06,950 --> 00:13:13,920
+center we produce simply a racemic mixture واضح؟
+
+158
+00:13:13,920 --> 00:13:17,840
+هذه النقطة الأولى أو النوع الأول من التفاعل النوع 
+
+159
+00:13:17,840 --> 00:13:24,460
+الثاني أسهل .. النوع الثاني أسهل بيقول القاعدة لو
+
+160
+00:13:24,460 --> 00:13:30,500
+عملنا تفاعل بعيدًا عن الـchiral center لو عملنا
+
+161
+00:13:30,500 --> 00:13:37,860
+تفاعل بعيدًا عن الـchiral center شو بيصير عنده؟ واضح
+
+162
+00:13:37,860 --> 00:13:42,060
+السؤال؟ خلّيني أعطيكم يا اب ببساطة، لو اتخيلت أنا
+
+163
+00:13:42,060 --> 00:13:45,300
+هنا كإنسان عندي chiral center، هاي اتجاه، هاي
+
+164
+00:13:45,300 --> 00:13:47,620
+الاتجاه الثاني، هاي الاتجاه الثالث، هاي الاتجاه
+
+165
+00:13:47,620 --> 00:13:52,940
+الرابع، وما أخذت هذه الاتجاهات بالظبط، وإجيت بعيدًا عن 
+
+166
+00:13:52,940 --> 00:13:55,380
+هذا الـchiral center، أعمل التفاعل، يعني مثلًا
+
+167
+00:13:55,380 --> 00:13:59,520
+نمسكت هذا هنا، هل يا ترى هذه الاتجاهات الأربعة
+
+168
+00:13:59,520 --> 00:14:04,080
+تغير فيها شيء؟ بمعنى لو أنا كنت شغال على برنامج
+
+169
+00:14:04,080 --> 00:14:09,080
+رسم وهذا الـreactant وبده أحط لـproduct، شو
+
+170
+00:14:09,080 --> 00:14:15,940
+بعمل؟ بعمل نسخ ولصق وبغير بس شغلة بسيطة على
+
+171
+00:14:15,940 --> 00:14:21,000
+الطرف لكن هل غيرت اتجاه المجموعات حول الـchiral
+
+172
+00:14:21,000 --> 00:14:26,600
+center؟ لأ إذا الـreaction لما بيكون away بعيدًا عن
+
+173
+00:14:26,600 --> 00:14:31,760
+الـchiral center away from على الـorientation يعني
+
+174
+00:14:31,760 --> 00:14:36,630
+نفس اتجاه المجموعات واضح؟ بيصير عندي شغلة بنسميها 
+
+175
+00:14:36,630 --> 00:14:40,930
+retention of configuration أنّ هذه المجموعة مثلًا
+
+176
+00:14:40,930 --> 00:14:44,
+
+201
+00:16:39,600 --> 00:16:44,640
+الـ reactant اللي عنده R، الـ product لازم يطلع R أو 
+
+202
+00:16:44,640 --> 00:16:48,060
+لو كان الـ reactant اللي عنده S، الـ product لازم
+
+203
+00:16:48,060 --> 00:16:50,920
+يطلع S، هذا مش هو المقصود بالـ retention of
+
+204
+00:16:50,920 --> 00:16:57,490
+configuration واضح؟ ليش؟ لأن الـ R و الـ S تحديدها ..
+
+205
+00:16:57,490 --> 00:17:02,690
+تحديدها على حسب أولوية المجموعات any أكبر any
+
+206
+00:17:02,690 --> 00:17:07,510
+again any again أنا لما بعمل مرات تفاعل بعيدا عن
+
+207
+00:17:07,510 --> 00:17:12,010
+الـ chiral center ممكن مجموعة كانت هي الأكبر تصير
+
+208
+00:17:12,010 --> 00:17:15,400
+أصغر واضح؟ اللي بيقصده بالـ retention و بالـ
+
+209
+00:17:15,400 --> 00:17:19,360
+configuration مش ان الـ R تظهر كـ R و الـ S تظهر ك
+
+210
+00:17:19,360 --> 00:17:24,720
+S لأ إن الاتجاهات في الفراغ تظهر كما هي واضح؟ لكن
+
+211
+00:17:24,720 --> 00:17:29,020
+الـR و الـS مرات بتظهر الـRR و الـSS مرات بنعكسه
+
+212
+00:17:29,020 --> 00:17:33,800
+هذا بيعتمد على إيش المجموعات الجديدة اللي اتفاعلت
+
+213
+00:17:33,800 --> 00:17:37,980
+فالـR و الـS هي قصة أولويات بينما اللي مقصود بالـ
+
+214
+00:17:37,980 --> 00:17:40,640
+retention of configuration اتجاهات أنه أنا عندي
+
+215
+00:17:40,640 --> 00:17:45,100
+هذا الاتجاه في الـ reactant واضح؟ بتحط المعادلة
+
+216
+00:17:45,100 --> 00:17:49,510
+product بيجيني هذا الاتجاه زي ما هو معتغيير في
+
+217
+00:17:49,510 --> 00:17:53,990
+الطرف اللي هنا واضح؟ فماحدش يفهم كلمة retention of
+
+218
+00:17:53,990 --> 00:17:59,360
+configuration أنه يكون معناها إن الـ R لازم تظل R و
+
+219
+00:17:59,360 --> 00:18:04,000
+الـ S لازم تظل S مرات أه و مرات لا معناها إن الـ
+
+220
+00:18:04,000 --> 00:18:08,260
+bonding بيظلوا in the same directions واضح إن
+
+221
+00:18:08,260 --> 00:18:11,560
+الارتباطات بيظلوا بنفس الاتجاه شايفين هنا كيف
+
+222
+00:18:11,560 --> 00:18:15,880
+كانوا هدول ماخدين أربع اتجاهات نسخت الجزء و حطيته
+
+223
+00:18:15,880 --> 00:18:19,740
+هل غيرت في الأربع اتجاهات هدول؟ لأ هذا المقصود
+
+224
+00:18:19,740 --> 00:18:23,320
+إنما قصة R و S تحتمل
+
+225
+00:18:27,250 --> 00:18:33,870
+التفاعل التالت برضه هو من التفاعلات اللي مرت عليكم
+
+226
+00:18:33,870 --> 00:18:38,730
+لو 
+
+227
+00:18:38,730 --> 00:18:43,670
+مثلا أخدنا المركب اللي موجود عندنا على السبورة
+
+228
+00:18:43,670 --> 00:18:48,370
+هتلاحظوا أنه في عندنا chiral center هنا تطلعوا إيش
+
+229
+00:18:48,370 --> 00:18:53,050
+عندكم؟ مثل و chlorine و مجموعة الـ vinyl هذه و الـ
+
+230
+00:18:53,050 --> 00:18:57,550
+ash إذا هنا في عندي chiral center ولا لأ أنا بدي
+
+231
+00:18:57,550 --> 00:19:02,330
+أعمل second chiral center يعني بدي أعمل chiral
+
+232
+00:19:02,330 --> 00:19:08,630
+center تاني غير الأول اللي موجود الآن لما أنا ..
+
+233
+00:19:08,630 --> 00:19:11,630
+انتبهوا معاكي في المنطقة لما أنا بعمل second
+
+234
+00:19:11,630 --> 00:19:14,450
+chiral center يعني هنا بدي أعمل chiral center
+
+235
+00:19:14,450 --> 00:19:18,870
+حقيقة أنا بكون قاعد بعمل تفاعل بالنسبة للـ chiral
+
+236
+00:19:18,870 --> 00:19:24,940
+center الأول إيش away from it، بعيد عنه و بناء على
+
+237
+00:19:24,940 --> 00:19:29,660
+ذلك لما بدي أخد الـ chiral center الأول هل يا ترى
+
+238
+00:19:29,660 --> 00:19:34,000
+بتتغير اتجاهاته؟ أه إذا جزء من هذه المسألة لما أنا
+
+239
+00:19:34,000 --> 00:19:37,940
+بعمل second chiral center إنه الـ chiral center
+
+240
+00:19:37,940 --> 00:19:42,260
+الأول أنا بعيد عنه طالما أنا بعيد عنه إذا أنا أعمل
+
+241
+00:19:42,260 --> 00:19:43,440
+عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة
+
+242
+00:19:43,440 --> 00:19:44,800
+عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن
+
+243
+00:19:44,800 --> 00:19:46,700
+عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة
+
+244
+00:19:46,700 --> 00:19:47,680
+عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن
+
+245
+00:19:47,680 --> 00:19:48,700
+عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة
+
+246
+00:19:48,700 --> 00:19:48,940
+عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن
+
+247
+00:19:48,940 --> 00:19:53,860
+عبارة عن عبارة عن عبارة عن عبارة عن عبارة عن عبارة
+
+248
+00:19:53,860 --> 00:20:00,990
+عن عبارة عن عبارة عن عبارة طب نيجي نسألنا في صناعات
+
+249
+00:20:00,990 --> 00:20:05,310
+لما بنجي بنعمل هذا التفاعل بدنا نضيف عليه HPR في
+
+250
+00:20:05,310 --> 00:20:10,390
+وجود الـ H Plus أول خطوة ربما بتذكروا بدنا نحط H
+
+251
+00:20:10,390 --> 00:20:15,490
+ويتكون عندي Carbocation هنا طالما اتكون عندي
+
+252
+00:20:15,490 --> 00:20:21,230
+Carbocation لبلانر إذا من وين هتتم الإضافة عليه؟
+
+253
+00:20:21,230 --> 00:20:26,350
+من الجهتين زي قبل شوية ما حكينا واضح؟ مجرد ما بضيف
+
+254
+00:20:26,350 --> 00:20:31,730
+هنا H و بيصير عندك كاربو كتاين لبلانر من أين تتم
+
+255
+00:20:31,730 --> 00:20:36,110
+الإضافة عليه؟ من الجهتين، إذا كأنه مرة يجي الـ PR
+
+256
+00:20:36,110 --> 00:20:43,250
+باتجاه و مرة بيجي الـ PR بالاتجاه الثاني، واضح؟ لكن
+
+257
+00:20:43,250 --> 00:20:47,630
+هنا بدكوا تنتبهوا لنقطة إن هدولة ما بيطلعوش بنسبة
+
+258
+00:20:47,630 --> 00:20:51,630
+خمسين في المية خمسين في المية احنا قبل شوية لما
+
+259
+00:20:51,630 --> 00:20:55,730
+كنا نعمل الـ first chiral center و نضيف من اتجاهين
+
+260
+00:20:55,730 --> 00:21:00,560
+كنا نقول بيطلعوا بخمسين في المية خمسين في المية ليش
+
+261
+00:21:00,560 --> 00:21:04,920
+في المرة الأولى بيطلعوا بنسبة متساوية و هنا بيقول
+
+262
+00:21:04,920 --> 00:21:08,700
+أنه بيطلع عندي diastereomers لما نطلع هدول التالية
+
+263
+00:21:08,700 --> 00:21:12,560
+علاقة بينهم ب diastereomers in unequal amounts في
+
+264
+00:21:12,560 --> 00:21:18,220
+مقادير غير متساوية السبب إن الجزء هنا مش متماثب
+
+265
+00:21:18,220 --> 00:21:23,200
+يعني هذه كانت بتحتمل أنها تكون R أو S لكن هي مخدة
+
+266
+00:21:23,200 --> 00:21:28,260
+stereo chemistry واحدة واضح الـ chiral center الأول
+
+267
+00:21:28,260 --> 00:21:34,690
+وجوده بيأثر على الإضافة الجديدة وجود الـ Chiral
+
+268
+00:21:34,690 --> 00:21:40,210
+Center الأول بيخلي أولوية لمجموعة نقروم تيجي من
+
+269
+00:21:40,210 --> 00:21:43,650
+جهة أكثر من الجهة الثانية فبناء على ذلك لما
+
+270
+00:21:43,650 --> 00:21:47,450
+بيتكون ديستيريو مارس عندما نجهز مجموعة ديستيريو
+
+271
+00:21:47,450 --> 00:21:49,470
+مارس عندما نجهز مجموعة ديستيريو مارس عندما نجهز
+
+272
+00:21:49,470 --> 00:21:54,370
+مجموعة ديستيريو مارس عندما نجهز مجموعة ديستيريو
+
+273
+00:21:54,370 --> 00:21:56,190
+مارس عندما نجهز مجموعة ديستيريو مارس عندما نجهز
+
+274
+00:21:56,190 --> 00:21:58,690
+مجموعة ديستيريو مارس عندما نجهز مجموعة ديستيريو
+
+275
+00:21:58,690 --> 00:22:03,530
+مارس عندما نج the presence of the fairs Cairo
+
+276
+00:22:03,530 --> 00:22:12,750
+Center وجود Cairo Center أول أثر على إيش؟ أثر على
+
+277
+00:22:12,750 --> 00:22:20,510
+اللي هو موقع جاية لبروم واضح؟ تماما زي لو كنا مثلا
+
+278
+00:22:20,510 --> 00:22:24,330
+بدنا نيجي نتخيل أن احنا بنقولكوا والله اتفضلوا هنا
+
+279
+00:22:25,610 --> 00:22:29,270
+أي حد واقف هنا ممكن يتخيل أنه بيجي عن اليمين أو
+
+280
+00:22:29,270 --> 00:22:33,490
+بيجي عن الشمال إذا الأمور متعادلة مافيش عنده أي
+
+281
+00:22:33,490 --> 00:22:38,630
+مشكلة الاحتمالية متساوية الآن لو حطيت هنا عقبة ما؟
+
+282
+00:22:38,630 --> 00:22:43,770
+ولو عقبة بسيطة بيصير اللي بيجي من هنا أكثر من اللي
+
+283
+00:22:43,770 --> 00:22:48,530
+بيجي من هنا فبتختل إيش؟ بتختل النسبة وهذه العقبة
+
+284
+00:22:48,530 --> 00:22:55,330
+هي وجود الـ Chiral Center الأول بيخلي جهة أفضل من
+
+285
+00:22:55,330 --> 00:22:58,790
+الثانية وبناء على ذلك صح أنا لما بعمل الـ second
+
+286
+00:22:58,790 --> 00:23:05,350
+chiral center بعمل الإضافة على الجهتين لكن بتكون
+
+287
+00:23:05,350 --> 00:23:12,730
+in unequal amounts في مقادير غير متساوية إذا الـ
+
+288
+00:23:12,730 --> 00:23:15,330
+generation of a second chiral center simply
+
+289
+00:23:15,330 --> 00:23:18,830
+produces the stereomeric products they are the
+
+290
+00:23:18,830 --> 00:23:22,290
+stereomers العلاقة بينهم at different rates بسرعة
+
+291
+00:23:22,290 --> 00:23:28,560
+مختلفة و in unequal amounts و بمقادير مختلفة
+
+292
+00:23:28,560 --> 00:23:35,580
+فالتفاعل سرعته مختلفة و مقداره مختلف واضح هذا
+
+293
+00:23:35,580 --> 00:23:39,820
+النوع الثالث من التفاعلات ألخصهم ببساطة أنا لما
+
+294
+00:23:39,820 --> 00:23:43,500
+بقول أهم التفاعلات المتعلقة بالـ stereo isomers إذا
+
+295
+00:23:43,500 --> 00:23:47,500
+بتعمل generation of a chiral center بيطلع عنده
+
+296
+00:23:47,500 --> 00:23:52,100
+racemic mixtures إذا بتعمل reaction away from a
+
+297
+00:23:52,100 --> 00:23:55,720
+chiral center في عندي retention of configuration
+
+298
+00:23:55,720 --> 00:23:59,660
+إذا بدي أعمل generation of a second chiral center في
+
+299
+00:23:59,660 --> 00:24:07,740
+عندي diastereomers in unequal amounts آخر شغلة
+
+300
+00:24:07,740 --> 00:24:14,180
+بنشرحها بشكل وصفي كبير جدا لأن العملية حقيقة
+
+301
+00:24:14,180 --> 00:24:21,060
+تفصيليا معقدة و تطبيقيا أو عمليا عملية صعبة كتير
+
+302
+00:24:22,180 --> 00:24:26,580
+اللي هي بسمها resolution of enantiomers إيش اللي
+
+303
+00:24:26,580 --> 00:24:32,320
+احنا بنقصده ب resolution of enantiomers فصل الـ
+
+304
+00:24:32,320 --> 00:24:36,300
+enantiomers قبل شوية احنا اخذنا لو عملنا تفاعل
+
+305
+00:24:36,300 --> 00:24:41,240
+generation of chiral center بيطلع عنده R و S خلط
+
+306
+00:24:41,240 --> 00:24:47,620
+السؤال هل يا ترى بنقدر نفصل الـ R عن الـ S واضح؟
+
+307
+00:24:48,170 --> 00:24:54,390
+الجواب إنه العملية صعبة جدا جدا .. العملية صعبة
+
+308
+00:24:54,390 --> 00:25:00,430
+جدا جدا .. السؤال ليش العملية صعبة؟ لأنه دائما و
+
+309
+00:25:00,430 --> 00:25:04,230
+أبدا .. دائما و أبدا .. احنا بنفصل الأشياء بناء
+
+310
+00:25:04,230 --> 00:25:12,210
+على الاختلافات بتاعتها مثلا، واحد عنده ولاد اثنين،
+
+311
+00:25:12,210 --> 00:25:16,900
+واحد قصير و واحد طويل، بده يميزهم عن بعض بسهولة
+
+312
+00:25:16,900 --> 00:25:20,220
+القصير اللي بتميز على الطويل، الآن تخيل واحد عنده
+
+313
+00:25:20,220 --> 00:25:25,860
+توائم سيامي، يمكن الأم تكون شاطرة، تقدر تميزهم، بس
+
+314
+00:25:25,860 --> 00:25:31,020
+أكيد مدرس، أكيد مدرس،
+
+315
+00:25:31,020 --> 00:25:38,080
+والاثنين بيشبهوا بعض تماما و بيشوفهم هيك مش هيقدر
+
+316
+00:25:38,080 --> 00:25:43,240
+يميزهم عن بعض تخيلوا مثلا لو كان عندكم اثنين توائم
+
+317
+00:25:43,240 --> 00:25:51,200
+و اثنين لاعبين في ملعب كرة قدم هل من الممكن أن يتم
+
+318
+00:25:51,200 --> 00:25:58,260
+تمييزهم عن بعض بسهولة لإنسان خارجي مش ممكن يتم
+
+319
+00:25:58,260 --> 00:26:03,810
+تمييزهم عن بعض بسهولة لأنهم متشابهين يعني أنا بأذكر
+
+320
+00:26:03,810 --> 00:26:10,050
+مرة قرأت عن اثنين متشابهين بيلعبوا كرة قدم كانوا
+
+321
+00:26:10,050 --> 00:26:14,050
+آه هاي زي ما بتقول اسمهم حسام حسن و إبراهيم حسن
+
+322
+00:26:14,050 --> 00:26:19,670
+هدولة متشابهين فمرة واحد منهم معه إنذار و في وسط
+
+323
+00:26:19,670 --> 00:26:23,270
+زحمة عمل غلطة ثانية بياخد إنذار ثاني إيش معنى ياخد
+
+324
+00:26:23,270 --> 00:26:28,870
+إنذار ثاني؟ إنه بده يطرد أخوه انتبه مباشرة و قريب
+
+325
+00:26:28,870 --> 00:26:32,430
+و المنطقة زحمة كرة فراح بسرعة دار ظهره للحكم إنه
+
+326
+00:26:32,430 --> 00:26:38,930
+أنا هاي رقم إيه و الحكم ما انتبهش و هم بيحكوا هذا
+
+327
+00:26:38,930 --> 00:26:43,030
+الكلام عن نفسهم هم بيحكوا هذا الكلام عن نفسهم يعني
+
+328
+00:26:43,030 --> 00:26:47,770
+أنا قرأته بجريدة ليش؟ لأن الاثنين بيشبهوا بعض جدا
+
+329
+00:26:47,770 --> 00:26:54,300
+إذا مبدأ الفصل هو إيش؟ الاختلاف، إذا مافيش اختلاف
+
+330
+00:26:54,300 --> 00:26:58,280
+كيف بدي أفصل أشياء عن بعض؟ العملية صعبة، الآن الـ
+
+331
+00:26:58,280 --> 00:27:01,920
+enantiomers اتذكروا مع الـ physical appropriatism
+
+332
+00:27:01,920 --> 00:27:06,300
+melting point لو كنت بدي أعمل crystallization نفس
+
+333
+00:27:06,300 --> 00:27:09,880
+الأشياء boiling point لو بدي أعمل distillation نفس
+
+334
+00:27:09,880 --> 00:27:13,360
+الأشياء polarity لو بدي أعمل chromatography مش هذي
+
+335
+00:27:13,360 --> 00:27:16,120
+ال طرق الفصل اللي انتوا تعلمتوها في الـ organic lab
+
+336
+00:27:16,690 --> 00:27:21,430
+ال فصل بالتقطير و الكريستاليزيشن و الكروماتوغراف،
+
+337
+00:27:21,430 --> 00:27:25,170
+و انتصرتوا و عملنا تجارب، الآن هم مشتركين بكل هذه
+
+338
+00:27:25,170 --> 00:27:31,970
+الصفات، إذن عملية الفصل صعبة، الآن التفكير العام
+
+339
+00:27:31,970 --> 00:27:35,070
+اللي بيعملوه كالاتي بيقولوا هدول enantiomers
+
+340
+00:27:35,070 --> 00:27:40,230
+متشابهين بييجوا بيفعلوهم مع مركب بيكون chiral و
+
+341
+00:27:40,230 --> 00:27:44,610
+بيور و غالبا هذا مأخوض من منتجات طبيعية لما
+
+342
+00:27:44,610 --> 00:27:48,710
+يفعلوهم مع مركب chiral و بيور بيعطينا ال diastereomers
+
+343
+00:27:48,710 --> 00:27:53,870
+ال diastereomers بتذكروا إيش كانت العلاقة
+
+344
+00:27:53,870 --> 00:27:55,730
+بينهم بالـ physical properties؟
+
+345
+00:27:59,900 --> 00:28:04,280
+اتطلعوا إيش ال diastereomers؟ they have different
+
+346
+00:28:04,280 --> 00:28:07,740
+physical properties ال enantiomers they have the
+
+347
+00:28:07,740 --> 00:28:11,000
+same physical properties بناء على ذلك لما أنا
+
+348
+00:28:11,000 --> 00:28:14,480
+بفعلهم مع chiral compound بصير عندي بدل ما هم two
+
+349
+00:28:14,480 --> 00:28:19,340
+enantiomers متشابهين بصير عندي ال diastereomers
+
+350
+00:28:19,340 --> 00:28:24,140
+مختلفات بالـ physical properties طالما أنهم مختلفات
+
+351
+00:28:24,140 --> 00:28:27,960
+بالـ physical properties إذا بإمكاني أفصلهم بالطرق
+
+352
+00:28:27,960 --> 00:28:32,640
+الكيميائية التقليدية بأفصل الـ chiral compound مع
+
+353
+00:28:32,640 --> 00:28:35,260
+المادة اللي فعلته معها و الـ chiral الثانية مع المادة
+
+354
+00:28:35,260 --> 00:28:40,960
+اللي فعلته معها بعد ذلك بلزمني تجربة أكسر المادة
+
+355
+00:28:40,960 --> 00:28:45,360
+اللي ضفتها و أرد أنقيهم الآن تطبيقيا هذه العملية
+
+356
+00:28:46,340 --> 00:28:49,580
+صعبة يعني أي واحد بيعمل رسالة ماجستير و عنده pair
+
+357
+00:28:49,580 --> 00:28:53,400
+of enantiomers بده يجي المتفاعلات الجيدة و
+
+358
+00:28:53,400 --> 00:28:57,840
+الطريقة الجيدة لفصلهم و الطريقة الجيدة لتكسيرهم و
+
+359
+00:28:57,840 --> 00:29:00,860
+بعد ما يكسروا يصيروا مركبين يعودوا يفكوا المركبين
+
+360
+00:29:00,860 --> 00:29:06,000
+عن بعض بياخدوا سنة سنتين شغل آه بحكي عن سنة سنتين
+
+361
+00:29:06,000 --> 00:29:11,480
+شغل و هو يعمل تجارب و يشتغل أحد زملاءنا دالوا
+
+362
+00:29:11,480 --> 00:29:17,930
+حوالي أربع سنين و هو بيفصل enantiomers العملية ليست
+
+363
+00:29:17,930 --> 00:29:22,930
+عملية سهلة أو عملية بسيطة لكن الفكرة الأساسية
+
+364
+00:29:22,930 --> 00:29:28,550
+تحويل ال enantiomers المتشابعة بالخواص الفيزيائية
+
+365
+00:29:28,550 --> 00:29:32,150
+إلى diastereomers مختلفة بالخواص الفيزيائية
+
+366
+00:29:32,150 --> 00:29:37,980
+التفصيل لطلاب يمكن يكونوا متخصصين أكثر منكوا و أنا
+
+367
+00:29:37,980 --> 00:29:40,760
+بأكد لكوا إنه مش في مرحلة الـ bachelor's لو واحد
+
+368
+00:29:40,760 --> 00:29:45,320
+بيشتغل بحث في مرحلة ماجستير لما يبدأ يعود يتطرق
+
+369
+00:29:45,320 --> 00:29:51,840
+لها الأمور هذه واضح؟ ابن هيك تقريبا بنكون أخذنا
+
+370
+00:29:51,840 --> 00:29:59,240
+خلينا نقول فكرة مقبولة أو جيدة في موضوع chapter 5
+
+371
+00:29:59,240 --> 00:30:01,420
+اللي هو ال stereo chemistry
+
+372
+00:30:04,850 --> 00:30:08,330
+لأ لأ بدنا نعمل .. بدنا نعمل مقدمة عشان المرة
+
+373
+00:30:08,330 --> 00:30:16,450
+الجاية نكون .. يعني نبدأ بشكل سريع مقدمة على الفصل
+
+37
+
+401
+00:32:31,180 --> 00:32:37,940
+متصلة بهذا الشكل بكربونة واحدة بنقول عندي primary
+
+402
+00:32:37,940 --> 00:32:42,140
+alkyl halide زي المركب الأول زي المركب الثاني
+
+403
+00:32:42,140 --> 00:32:46,700
+زي المركب الثالث فيهم كلهم الـ halogen متصلة
+
+404
+00:32:46,700 --> 00:32:51,860
+بكربونة واحدة و الكربونة عبارة عن CH2 هي في كل 
+
+405
+00:32:51,860 --> 00:32:54,280
+الأحوال الـ halogen متصلة بكربونة واحدة لكن
+
+406
+00:32:54,280 --> 00:32:59,720
+الكربونة بعد هيك متصلة بكم كربون؟ واحدة يعني هنا الـ
+
+407
+00:32:59,720 --> 00:33:04,540
+halogen الكربون تبعته متصلة بـ bond واحدة شايفين
+
+408
+00:33:04,540 --> 00:33:13,590
+اللون الأخضر هذا الكربون تعتبر الـ halogen
+
+409
+00:33:13,590 --> 00:33:15,870
+الهالوجين الهالوجين الهالوجين الهالوجين الهالوجين
+
+410
+00:33:15,870 --> 00:33:17,790
+الهالوجين الهالوجين الهالوجين الهالوجين الهالوجين
+
+411
+00:33:17,790 --> 00:33:17,850
+الهالوجين الهالوجين الهالوجين الهالوجين الهالوجين
+
+412
+00:33:17,850 --> 00:33:21,350
+الهالوجين الهالوجين الهالوجين الهالوجين  أه بتكون
+
+413
+00:33:21,350 --> 00:33:25,690
+إيش الـ alkyl halide نوعه؟ secondary alkyl halide
+
+414
+00:33:25,690 --> 00:33:31,110
+طيب وإذا الـ halogen متصل بكربونة متصلة بثلاث
+
+415
+00:33:31,110 --> 00:33:35,670
+كربونات شو بيكون عندك؟ tertiary alkyl halides إذا
+
+416
+00:33:35,670 --> 00:33:39,350
+الـ alkyl halides حسب الكربونة اللي حاملة الـ
+
+417
+00:33:39,350 --> 00:33:43,980
+halogen حسب الكربونة اللي حاملة الهالوجين ممكن نقول 
+
+418
+00:33:43,980 --> 00:33:49,300
+عنهم primary أو secondary أو tertiary وهذا الـ
+
+419
+00:33:49,300 --> 00:33:53,000
+classification أو التصنيف هيلزمنا كتير أثناء ما
+
+420
+00:33:53,000 --> 00:33:56,160
+بنشرح تفاعلات الـ alkyl halides بتلاقولنا بنقول إن
+
+421
+00:33:56,160 --> 00:33:58,640
+this is a primary alkyl halide, this is a
+
+422
+00:33:58,640 --> 00:34:01,920
+secondary alkyl halide, this is a tertiary alkyl
+
+423
+00:34:01,920 --> 00:34:08,440
+halide and so on في موضوع الـ alkyl halide بيجينا
+
+424
+00:34:08,440 --> 00:34:19,380
+نقطة لو يا ترى بدنا نتذكر القطبية تبعت الـ R X طبعا
+
+425
+00:34:19,380 --> 00:34:25,560
+الـ R متصلة بالـ X من خلال ذرة كربون الـ X هي الـ
+
+426
+00:34:25,560 --> 00:34:31,220
+halogen متصلة من خلال ذرة كربون إذا أنا ممكن يكون
+
+427
+00:34:31,220 --> 00:34:34,900
+عندي الكربون المتصل بالـ H دي في الالكيل لما بيصير
+
+428
+00:34:34,900 --> 00:34:40,330
+الـ halide يا كربون متصلة بفلورين، يا كربون متصلة
+
+429
+00:34:40,330 --> 00:34:44,290
+بكلورين، يا كربون متصلة ببرومي، يا كربون متصلة 
+
+430
+00:34:44,290 --> 00:34:49,890
+بايودين لو إجيت شوفت الـ polarity للـ bonds، بشكل
+
+431
+00:34:49,890 --> 00:34:55,270
+عام أقل polarity تقريبا اللي هو الكربون، الفلورين
+
+432
+00:34:55,270 --> 00:35:00,230
+أعلى polarity بأربعة أو أربعة وكسر صغير، والكلور
+
+433
+00:35:00,230 --> 00:35:03,230
+ثلاثة والبروم اثنين واتمان عشر اليوم تقريبا زي
+
+434
+00:35:03,230 --> 00:35:08,190
+الكربون، نوعا ما بناء على ذلك دائما لما ببدأ أجد
+
+435
+00:35:08,190 --> 00:35:12,090
+أشوف الـ carbon halogen bond وين اللي بده يكون
+
+436
+00:35:12,090 --> 00:35:18,170
+الطرف السالب الـ halogen و الطرف الموجب الـ carbon
+
+437
+00:35:18,170 --> 00:35:25,330
+فالرابط الـ carbon halogen bond is a polar bond the
+
+438
+00:35:25,330 --> 00:35:30,490
+positive end is the carbon end and the negative
+
+439
+00:35:30,490 --> 00:35:34,350
+end is the halogen end دائما لما بدنا نحط
+
+440
+00:35:45,790 --> 00:35:53,930
+قوة الروابط كاربون هيدروجين بوند 413 كجول لكل مول
+
+441
+00:35:55,050 --> 00:36:02,950
+الكاربون فلور 467 strong الكاربون كلور 346 بدأت
+
+442
+00:36:02,950 --> 00:36:09,850
+أقل تصير الرابطة تبعه الكاربون بروم 290 الكاربون
+
+443
+00:36:09,850 --> 00:36:13,810
+يود تقريبا non polar لحظة لأن الـ electronegativity
+
+444
+00:36:13,810 --> 00:36:20,610
+نوعا ما نفس الأشياء 228 إذن أنية أضعف رابطة
+
+445
+00:36:20,610 --> 00:36:28,150
+الكاربون مع اليود أضعف رابطة يعني بتنكسر بسهولة،
+
+446
+00:36:28,150 --> 00:36:33,830
+أضعف رابطة يعني بتنكسر بسهولة، عشان هيك المركبات
+
+447
+00:36:33,830 --> 00:36:39,670
+اللي فيها يود ممكن اليود بالحرارة العادية أو بطوء
+
+448
+00:36:39,670 --> 00:36:43,970
+الشمس العادي يكسر عن المركب، هذه رابطة ضعيفة،
+
+449
+00:36:43,970 --> 00:36:50,550
+رابطة الـ carbon مع اليود هي رابطة ضعيفة ممكن طبعا
+
+450
+00:36:50,550 --> 00:36:55,230
+احنا نفسر ضعف الرابطة ممكن نفسر ضعف الرابطة تنسوش
+
+451
+00:36:55,230 --> 00:36:58,570
+إن الـ carbon في أول الجدول الدوري الـ carbon في
+
+452
+00:36:58,570 --> 00:37:03,650
+أول الجدول الدوري ذرة إيه شمالها صغيرة ذرة صغيرة
+
+453
+00:37:03,650 --> 00:37:09,830
+اليود تحت ذرة كبيرة الآن بشكل عام احنا بنقول في
+
+454
+00:37:09,830 --> 00:37:13,960
+الكيميا في عندنا قاعدة بتقول الـ hard دائما تيجي مع
+
+455
+00:37:13,960 --> 00:37:18,440
+الـ hard، الكبير مع الكبير، والصغير مع الصغير، هذه
+
+456
+00:37:18,440 --> 00:37:23,540
+القاعدة مش بس كيميائية، هي قاعدة إنسانية، يعني لو
+
+457
+00:37:23,540 --> 00:37:27,240
+واحدة منكم في المستقبل راحت تزور صاحبتها بعد خمس
+
+458
+00:37:27,240 --> 00:37:30,720
+سنين، ما شاء الله عندها طفلين، وهذه عندها طفلين،
+
+459
+00:37:30,720 --> 00:37:34,780
+وقعدوا في الحديقة تحت المنزل، إيش الوضع الطبيعي؟
+
+460
+00:37:35,950 --> 00:37:39,010
+إنه الأمهات اثنين اثنين مع بعض و بيحكوا و إن شاء
+
+461
+00:37:39,010 --> 00:37:42,650
+الله مايحكوش إلا خير والأولاد الصغار مع بعض و
+
+462
+00:37:42,650 --> 00:37:45,950
+بيتمشكلوا وإن شاء الله مايعملوش مشاكل الكبير مع
+
+463
+00:37:45,950 --> 00:37:50,810
+الكبير والصغير مع الصغير هذا وضع طبيعي في الدنيا
+
+464
+00:37:50,810 --> 00:37:55,330
+وبالمناسبة لو أنتم لاحظتم مثلا رجل عمره خمسة و
+
+465
+00:37:55,330 --> 00:38:01,670
+خمسين ستين سنة ومصاحب ولد صغير ما حدا بيقبلها، يعني 
+
+466
+00:38:01,670 --> 00:38:06,190
+مافيش منطق، لازم يكون نوع من إيش؟ نوع من التكافؤ،
+
+467
+00:38:06,190 --> 00:38:09,730
+حتى التكافؤ مش بس بالصحبة، اليوم صاروا يخلوه
+
+468
+00:38:09,730 --> 00:38:14,170
+بالجيزة، بدي يكون السن متقارب، العقل متقارب، 
+
+469
+00:38:14,170 --> 00:38:17,330
+الحالة الاجتماعية متقاربة، لو اختلفت الحالة
+
+470
+00:38:17,330 --> 00:38:23,740
+الاجتماعية، 90% الأمور شمالها، ما بتمشيش حتى الناس
+
+471
+00:38:23,740 --> 00:38:28,540
+بيكون إيش؟ متقاربة يعني، كل ناس بيروح على الصينف
+
+472
+00:38:28,540 --> 00:38:32,300
+اللي زيهم، بيروح على الشيء اللي زيه، واضح؟ فالقالة
+
+473
+00:38:32,300 --> 00:38:38,180
+ما بحكي عن carbon صغير، يود كبيرة، هذا ارتباط غير
+
+474
+00:38:38,180 --> 00:38:42,380
+سليم وبناء على ذلك هو ارتباط إيش؟ ضعيف وعشان هيك لو
+
+475
+00:38:42,380 --> 00:38:46,940
+عندكم دواء في يود بتلاحظوا إنه في الصيدلية بيكون
+
+476
+00:38:46,940 --> 00:38:51,820
+محطوط في عبوة بنية عشان تحميه من ضوء الشمس
+
+477
+00:38:51,820 --> 00:38:57,400
+والمفروض يكون الصيدلي يضبه بخزانة أو بمكان بارد
+
+478
+00:38:57,400 --> 00:39:00,160
+بعيد عن الضوء لأنه هذا المركز اللي بيحطه في ضوء
+
+479
+00:39:00,160 --> 00:39:04,430
+الشمس بيفلط اليود منه بيخرب الدواء ملاحظين أنتم؟
+
+480
+00:39:04,430 --> 00:39:07,550
+يمكن بتلاحظوا هذه الشغلة فالارتباط مع اليود هو
+
+481
+00:39:07,550 --> 00:39:12,530
+أضعف ارتباط الآن هذا الكلام بيفيدني إنه أنا بعد
+
+482
+00:39:12,530 --> 00:39:17,150
+شوية لما ببدأ أعمل تفاعلات إبدال أسهل إيش أطلع وبعده
+
+483
+00:39:17,150 --> 00:39:22,970
+البروم الـ flour مش هناخد عنه أمثلة بالمرة
+
+484
+00:39:22,970 --> 00:39:27,850
+بتطلعش بسهولة يعني هناخد احنا تفاعلات إبدال، بدنا
+
+485
+00:39:27,850 --> 00:39:33,490
+نبض الزرار، هتلاحظوا معظم أمثلتنا يود أو بروم أو
+
+486
+00:39:33,490 --> 00:39:36,430
+انطلقت الكلور، بس ولا مثال هناخده عن الـ flour
+
+487
+00:39:36,430 --> 00:39:43,010
+لأنها الـ رابطة بتاعة الـ flour هي رابطة قوية فـ الـ
+
+488
+00:39:43,010 --> 00:39:48,290
+rate of reaction، سرعة التفاعلات، سرعة التفاعلات،
+
+489
+00:39:48,290 --> 00:39:54,900
+بيقول فيها الأكثر من الـ RBR أكثر من الـ RCL ليش الـ
+
+490
+00:39:54,900 --> 00:40:00,960
+RI أسرع في التفاعل لأن رابطته أضعف لأن رابطته أضعف
+
+491
+00:40:00,960 --> 00:40:06,440
+في عندي فرق في الـ size هملاحظين هنا كيف الفرق في
+
+492
+00:40:06,440 --> 00:40:11,280
+الـ size فرق في الـ size وطالما عندي فرق كبير في الـ
+
+493
+00:40:11,280 --> 00:40:18,880
+size معنى ذلك الارتباط غير سليم وغير ..بنجي لهذه
+
+494
+00:40:18,880 --> 00:40:24,480
+النقطة اليوم في المقدمة لـ Alkaline Calcium 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5fcb3cbaa799ae2b00b146864ef0665ad9159507
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w_postprocess.srt
@@ -0,0 +1,2040 @@
+1
+00:00:08,920 --> 00:00:14,050
+بسم الله الرحمن الرحيمالجزء الأخير من مشتقات
+
+2
+00:00:14,050 --> 00:00:19,090
+الأحماض اللي بدوا يمر علينا اليوم هو الامدز واضح؟
+
+3
+00:00:19,090 --> 00:00:23,890
+الآن إذا بدنا نشوف شو هما الامدز كمجموعة وظيفية
+
+4
+00:00:23,890 --> 00:00:29,370
+لما بنتقى عنده سيضة بالبند O وجنبها N سيضة بالبند
+
+5
+00:00:29,370 --> 00:00:36,710
+O N هذه اللي بتمثل مجموعة الامدز واضح؟ لو بدنا
+
+6
+00:00:36,710 --> 00:00:43,410
+نسمي الامدز بنرجع لالاصل اللى جاى منه ال amides
+
+7
+00:00:43,410 --> 00:00:46,990
+اللى بنفترض انه ال acid لأن هو مشتقة من مشتقات
+
+8
+00:00:46,990 --> 00:00:51,990
+الحامض مثلا هنا عندي كربونة تنتين تلاتة شو بيكون
+
+9
+00:00:51,990 --> 00:00:57,870
+اسم الحامض بروبانويك أسد بشيل اويك أسد وبكتب
+
+10
+00:00:57,870 --> 00:01:05,590
+بروبان امد اذا كان ال acid بروبان اويك أسد شيلت كل
+
+11
+00:01:05,590 --> 00:01:10,390
+اويك أسد بروبان امد مثلا هذا ال amide جاى من
+
+12
+00:01:11,430 --> 00:01:20,550
+البنزويك أسد فبصير اسمه بنز أمد و هكذا طبعا
+
+13
+00:01:20,550 --> 00:01:29,450
+بتلاحظوا انتوا ان الامد فيها CWO و فيها Mوالـ
+
+14
+00:01:29,450 --> 00:01:33,770
+Oxygen و الـ Nitrogen طبعا بالاضافة للـ Fluor هم
+
+15
+00:01:33,770 --> 00:01:38,070
+التلت عناصر اللي معروف انهم بيعملوا الـ hydrogen
+
+16
+00:01:38,070 --> 00:01:43,670
+bonding واضح؟ فبناء على ذلك جزيئات الأمد بينها و
+
+17
+00:01:43,670 --> 00:01:47,410
+بين نفسها ممكن تكون عاملة hydrogen bonding سواء
+
+18
+00:01:47,410 --> 00:01:51,610
+كان one hydrogen bond يعني الـمع الـ O تعمل
+
+19
+00:01:51,610 --> 00:01:55,390
+hydrogen bonding أو بترتيب معين ممكن يكون بين
+
+20
+00:01:55,390 --> 00:01:59,110
+الجزيئين two hydrogen bonds يعني زي ما اتخيل زي
+
+21
+00:01:59,110 --> 00:02:01,910
+هيك هاي حالة في عندي نيتروجين و أكسوجين و نيتروجين
+
+22
+00:02:01,910 --> 00:02:05,510
+و أكسوجين ممكن يصير اتحاد بس بهذا الشكل و ممكن
+
+23
+00:02:05,510 --> 00:02:11,350
+يصير اتحاد كل أكسوجين مع نيتروجين لكن الإمكانية لل
+
+24
+00:02:11,350 --> 00:02:16,010
+hydrogen bond قائمة و أساسية في ال amidesهذا
+
+25
+00:02:16,010 --> 00:02:20,890
+الكلام بينعكس على شغلة بينعكس على شغلة ان طالما
+
+26
+00:02:20,890 --> 00:02:25,350
+الامد مع نفسها بتعمل hydrogen bonding اذا بنتوقع
+
+27
+00:02:25,350 --> 00:02:29,690
+شو بيصير في ال boiling point نقاط غليانها مرتفعة
+
+28
+00:02:29,690 --> 00:02:34,990
+طبعا هنا لما بتيجوا بتتطلعوا على اي امد محدد حقيقة
+
+29
+00:02:34,990 --> 00:02:40,440
+الامد في Nأحنا قلنا بس ان بيصير امد لكن هذه الان
+
+30
+00:02:40,440 --> 00:02:44,520
+ممكن يكون عليها two hydrogens ممكن يكون عليها
+
+31
+00:02:44,520 --> 00:02:49,660
+hydrogen واحدة و R group و ممكن يكون عليها two R
+
+32
+00:02:49,660 --> 00:02:54,720
+groups واضح؟ يعني مش لازم دائما ال nitrogen هذه
+
+33
+00:02:54,720 --> 00:03:02,440
+تكون NH2 ممكن تكون هذه NH2 ممكن تكون NHR و ممكن
+
+34
+00:03:02,440 --> 00:03:03,460
+تكون NR
+
+35
+00:03:06,380 --> 00:03:10,120
+بناء على ذلك، وبناء على ذلك، كأنه في عندي
+
+36
+00:03:10,120 --> 00:03:14,880
+substituted amides وعندي unsubstituted amides يعني
+
+37
+00:03:14,880 --> 00:03:20,200
+هذا الامد اللي من كربونة واحدة جاي من أي حامض من
+
+38
+00:03:20,200 --> 00:03:25,040
+ال formic أو ال methanoic acid فبنسميه form امد
+
+39
+00:03:25,040 --> 00:03:29,900
+طيب، الآن لو اعملت إبدال لل two hydrogens اللي
+
+40
+00:03:29,900 --> 00:03:36,410
+تعون ال nitrogen هنا ال two مثل groupsبيصير ايش
+
+41
+00:03:36,410 --> 00:03:40,630
+اسمه؟ Dimethylformamide
+
+42
+00:03:40,630 --> 00:03:45,750
+طبعا مرات بيروحوا بيحطوا أن و أن لإيضاح بإن الميثل
+
+43
+00:03:45,750 --> 00:03:50,370
+هذي و الميثل هذي متصلات بالنيتروجين فممكن تلاقوا
+
+44
+00:03:50,370 --> 00:03:56,670
+هذا المركب باسم N-N-Dimethylformamide ممكن تلاقوا
+
+45
+00:03:56,670 --> 00:04:02,200
+باسم Dimethylformamide و يكونوا مختصرينالان ان
+
+46
+00:04:02,200 --> 00:04:06,440
+وغالبا هذا ال solvent ويلو تطبيقات كتير واستعمالات
+
+47
+00:04:06,440 --> 00:04:09,360
+كتير في ال organ ال chemistry بكتبوه مختصر على
+
+48
+00:04:09,360 --> 00:04:17,060
+الآخر بصيغة DMF فسواء قلنا DMF الاسم الاختصاري
+
+49
+00:04:17,060 --> 00:04:23,810
+تبعه dimethylformamine اوكتبناه بـ
+
+50
+00:04:23,810 --> 00:04:27,230
+dimethelformamide أو كتبناه بـ NN
+
+51
+00:04:27,230 --> 00:04:32,170
+-dimethelformamide احنا بنعبر عن نفس الشغلة فلو
+
+52
+00:04:32,170 --> 00:04:37,050
+قلنالكم في الامتحان والله ارسمونا شكل ال DMF بس
+
+53
+00:04:37,050 --> 00:04:41,670
+كتبنا DMF و ارسموا شكله فالمفروض انكوا تعرفوا ان
+
+54
+00:04:41,670 --> 00:04:48,510
+ال DMF اللي هو هذا الشكل الان لاحظوا عاد بين ال
+
+55
+00:04:48,510 --> 00:04:54,410
+formamide العادىوالان Anti-methyl formamide في فرق
+
+56
+00:04:54,410 --> 00:04:59,270
+كبير هذا الفرق ان ال two هيدروجين اللي موجوداتها
+
+57
+00:04:59,270 --> 00:05:04,270
+اختفوا وبناء على ذلك هنا في امكانية hydrogen
+
+58
+00:05:04,270 --> 00:05:08,590
+bonding هنا مافيش امكانية hydrogen bonding اذا ان
+
+59
+00:05:08,590 --> 00:05:13,550
+هو اللي بدو يكون اعلى في ال boiling pointالأول
+
+60
+00:05:13,550 --> 00:05:17,250
+اللي بيعمل hydrogen bonding الـ unsubstituted أميد
+
+61
+00:05:17,250 --> 00:05:20,290
+بناء على ذلك ال form أميد مثلا لو كنت تشوف نقطة
+
+62
+00:05:20,290 --> 00:05:25,990
+غليانه 210 بينما الان undimetered form أميد 153
+
+63
+00:05:25,990 --> 00:05:30,730
+رغم أن هذا بالوزن بال molecular weight أعلى من هذا
+
+64
+00:05:30,730 --> 00:05:34,830
+لكن هذا فقط خاصية مهمة جدا اللي هي خاصية ال
+
+65
+00:05:34,830 --> 00:05:39,360
+hydrogen bondingطبعا لو عندى مثل فورمامد واحدة
+
+66
+00:05:39,360 --> 00:05:42,060
+يعني بدل ما يعمل من جهتين hydrogen bonds بيعمل من
+
+67
+00:05:42,060 --> 00:05:47,060
+واحدة بيكون in between بينهم كذلك الحال لو أخدت
+
+68
+00:05:47,060 --> 00:05:50,900
+مثلا هذا المركب الشهير اللي اسمه acetamide من
+
+69
+00:05:50,900 --> 00:05:57,240
+الacetic acid two carbons acetic acid لما بيجي امد
+
+70
+00:05:57,240 --> 00:06:00,820
+بيصير acetamide لو كان في مثلا ال methyl groups
+
+71
+00:06:00,820 --> 00:06:03,680
+بيصير N N dimethyl
+
+72
+00:06:11,460 --> 00:06:16,080
+بالنسبة لهذا البرنامج موجود في الحالة الأولى ولم
+
+73
+00:06:16,080 --> 00:06:18,280
+يكن موجود في الحالة الثانية
+
+74
+00:06:22,670 --> 00:06:26,830
+دائما قلنا ما بنعملش مقارنة بين شغلتين مافيش بينهم
+
+75
+00:06:26,830 --> 00:06:32,190
+مشترك، بنطلع التجربة، نطلع التجربة، واضح؟ يعني
+
+76
+00:06:32,190 --> 00:06:38,070
+دائما في المقارنة مبدأ أساسي، بس تخلوا إيش؟ متغير
+
+77
+00:06:38,070 --> 00:06:43,650
+واحد، إذا صار أكتر من متغير، بدكوا تعمله تجارب،
+
+78
+00:06:43,650 --> 00:06:47,970
+وذكرتكوا سابقا بقوانين الغازات لما بيعملوا مقارنة،
+
+79
+00:06:47,970 --> 00:06:53,300
+بنقارن الضغطبالحجم عن ثبات عدد المولات و عن ثبات
+
+80
+00:06:53,300 --> 00:06:59,760
+درجة الحرارة و الهكذا الان كيف تحضر ال amides من
+
+81
+00:06:59,760 --> 00:07:03,660
+الحامض بتفاعل الحامض مع الأمونيا و الحرارة بيصير
+
+82
+00:07:03,660 --> 00:07:08,200
+عندي اميد و بتاع هيك شغلة مرت علينا من ال acid
+
+83
+00:07:08,200 --> 00:07:12,800
+chloride او من ال E star بتفاعله مع الأمونيا و
+
+84
+00:07:12,800 --> 00:07:17,840
+التفاعل اللي بيصيرالنكليوفيليك سبستيوشن الأمونيا
+
+85
+00:07:17,840 --> 00:07:23,240
+بتهاجم والكلورة بيطلع وبرضه مار علينا هذا التحضير
+
+86
+00:07:23,240 --> 00:07:31,100
+الان لو بدنا نتطلع على نقطة مهمة جدا حقيقة في ال
+
+87
+00:07:31,100 --> 00:07:37,060
+amides ال amide موجود في c double bond o وموجود في
+
+88
+00:07:37,060 --> 00:07:42,730
+نيتروجين عليها زوج إلكتروناتواضح؟ الآن الـ C
+
+89
+00:07:42,730 --> 00:07:48,330
+double bond O الـ C double bond O أخدنا عنها إنها
+
+90
+00:07:48,330 --> 00:07:54,450
+group very reactive والدليل ع هيك إنه إحنا قلنا
+
+91
+00:07:54,450 --> 00:07:58,030
+يمكن تلت أسابيع بناخد aldehydes وketones و acids
+
+92
+00:07:58,030 --> 00:08:02,950
+ومشتقاتها وكلهم عبارة عن تفاعلات على إيش على الـ C
+
+93
+00:08:02,950 --> 00:08:06,910
+double bond O ومحور ال reactivity في الـ C double
+
+94
+00:08:06,910 --> 00:08:11,900
+bond O إنه هذا الكربونpartially positive والأكسجين
+
+95
+00:08:11,900 --> 00:08:17,280
+partially negative فالتفاعل الأساسي للـ CW bond هو
+
+96
+00:08:17,280 --> 00:08:21,200
+أن يجيب نيجاتيف يهاجم عليها أو الـ nucleophile الـ
+
+97
+00:08:21,200 --> 00:08:24,080
+nucleophilic يا addition في حالة الألدهايتز
+
+98
+00:08:24,080 --> 00:08:28,700
+والكيتونز يا substitution في حالة الأحماض المشتقة
+
+99
+00:08:28,700 --> 00:08:31,480
+إذا أنا هنا الكاربون هذه مجموعة
+
+100
+00:08:36,660 --> 00:08:41,720
+السبب هو وجوده الـ positive برضه نيتروجين أخدنا عن
+
+101
+00:08:41,720 --> 00:08:45,020
+هوين ما كانت بتتفاعل يعني تطلع في المثال اللي قبل
+
+102
+00:08:45,020 --> 00:08:49,980
+هيكفي التحضيرات هذه الـ nitrogen زوج الإلكترونات
+
+103
+00:08:49,980 --> 00:08:53,040
+هذا بيخليها الـ nucleophile يعني كأنه أنشطتش في
+
+104
+00:08:53,040 --> 00:08:56,780
+التفاعل لما يكون شغلة positive ولا شغلة negative
+
+105
+00:08:56,780 --> 00:09:02,280
+سواء بشكل كامل أو جزء فالخلاص أن هنا في الأمد
+
+106
+00:09:02,280 --> 00:09:09,470
+بيلتقي مجمعتين وظيفيتين ناشطات جداًيعني الـ C
+
+107
+00:09:09,470 --> 00:09:13,870
+double bond O اللي فيها تلت أسبيع، chapter تسعة أو
+
+108
+00:09:13,870 --> 00:09:16,730
+عشر، الديهيدز، كيتونز، أسيتز، كلهم تفاعلاتها،
+
+109
+00:09:16,730 --> 00:09:20,250
+مظبوط ولا لأ؟ والنيتروجين لوحدها اللي هي الـ
+
+110
+00:09:20,250 --> 00:09:24,310
+amines عندنا ال chapter إحدى عشر كله بيدرس
+
+111
+00:09:24,310 --> 00:09:28,310
+تفاعلاتها الـ amines ولمّا أخدنا ال substitution
+
+112
+00:09:28,310 --> 00:09:33,330
+هي نيوكليوفال قوي، إذا أنا كإني هنا أمام أكتر
+
+113
+00:09:33,330 --> 00:09:37,420
+مجمعتين في ال organ الchemistry نشاطا وتفاعلاماذا
+
+114
+00:09:37,420 --> 00:09:43,580
+هم؟ الـ C double bond O والنيتروجين هدول الـ C
+
+115
+00:09:43,580 --> 00:09:46,860
+double bond O والنيتروجين من أكثر المجموعات
+
+116
+00:09:46,860 --> 00:09:50,960
+تفاعلاً بس للأسف الشديد في شرط عشان يكون أكثر
+
+117
+00:09:50,960 --> 00:09:55,600
+المجموعات تفاعلاً أن كل واحدة تكون لحالها طيب لما
+
+118
+00:09:55,600 --> 00:09:58,580
+بيصيروا جانب بعض في الأمد
+
+119
+00:10:01,120 --> 00:10:07,560
+لحظوا أنا صارت تنتين في جزء واحد جانب بعض بيصير
+
+120
+00:10:07,560 --> 00:10:10,380
+أقل جزء في التفاعلات
+
+121
+00:10:12,630 --> 00:10:17,110
+ليش؟ لأنه بيصير يتشغل بحاله بدل ما يكون جاهز أنه
+
+122
+00:10:17,110 --> 00:10:20,870
+يتفاعل للخارج هنا في عندي موجب و هنا سالب السالب
+
+123
+00:10:20,870 --> 00:10:24,810
+بده موجب و الموجب بده سالب فكأنه هذا السالب بنقدر
+
+124
+00:10:24,810 --> 00:10:28,270
+نتخيله بيجي على هذا الموجب بهذا الشكل بيعمل
+
+125
+00:10:28,270 --> 00:10:33,330
+resonance structures لا ضال هنا موجب ولا ضال هنا
+
+126
+00:10:33,330 --> 00:10:39,450
+سالب وبناء على ذلك بيصير الأمدvery very unreactive
+
+127
+00:10:39,450 --> 00:10:43,990
+ولا كأنه فيه C double bond O ولا كأنه فيه نيتروجين
+
+128
+00:10:43,990 --> 00:10:49,430
+ولذلك الآن مابناخدش تفاعلات كتيرة لـ AMIDS ليش؟
+
+129
+00:10:49,430 --> 00:10:52,590
+لأن الـ C double bond O بحاجة لألكترونات من وين
+
+130
+00:10:52,590 --> 00:10:58,150
+بتاخدهم؟ من داخل الجزء مابتروحش تستنى حاجة من برة
+
+131
+00:10:58,150 --> 00:11:01,490
+تيجي تهجم عليها وبصير هذا ال resonance structures
+
+132
+00:11:01,490 --> 00:11:09,170
+فبسببالـ Resonance يُعتبر الأمد Unreactive يعني
+
+133
+00:11:09,170 --> 00:11:16,530
+الأمد الـ Resonance يُعتبر أمداً غير ردوداً واضح؟
+
+134
+00:11:16,530 --> 00:11:19,950
+إذن إيش سبب الـ Unreactivity؟ اللي هو الأمد
+
+135
+00:11:19,950 --> 00:11:24,570
+Resonance رغم إن هالمجمعتين يُعتبروا زي ما اتفقنا
+
+136
+00:11:24,570 --> 00:11:28,550
+من إيش؟ من أنشط المجموعات لما يكونوا كل واحدة لحال
+
+137
+00:11:28,550 --> 00:11:34,290
+لكن إذا أتيوا مع بعض سبحان اللهبتشغلوا في بعض زي
+
+138
+00:11:34,290 --> 00:11:41,250
+هيك ربما مما يثبت هذا الكلام ان الامد is very
+
+139
+00:11:41,250 --> 00:11:49,210
+unreactive ان عندكم النيلون النيلون النيلون
+
+140
+00:11:49,210 --> 00:11:55,410
+الحقيقة هو عبارة عن امدالنيلون اللي احنا بنستعمله
+
+141
+00:11:55,410 --> 00:12:00,630
+عبارة عن أمد وهذا النيلون very unreactive في
+
+142
+00:12:00,630 --> 00:12:04,830
+الدليل ع هيك انه احنا مثلا لو دفننا عدة شغلات في
+
+143
+00:12:04,830 --> 00:12:08,750
+الأرض و اجينا بعد شهرين فحرنا الأرض بنلاقي فضلات
+
+144
+00:12:08,750 --> 00:12:12,790
+الطعام وأوراق الأشجار وما إلى ذلك كلها إشمالها
+
+145
+00:12:12,790 --> 00:12:17,670
+متحللة لكن كياس النيلون بتظل و بتعمل مشكلة بيئية
+
+146
+00:12:18,380 --> 00:12:22,540
+واضح؟ طبعا أي إشي ممكن يعمل .. أي إشي ممكن
+
+147
+00:12:22,540 --> 00:12:28,880
+بالمناسبة يعمل مشكلة وممكن يكون مفيد حسب الحالة
+
+148
+00:12:28,880 --> 00:12:32,860
+اللي أنا بتعامل فيها يعني تماما زي السكينة على
+
+149
+00:12:32,860 --> 00:12:36,840
+سبيل المثال لازمان عشان أقطع فيها أو عشان هيك
+
+150
+00:12:36,840 --> 00:12:40,900
+بجيبها بالدار لكن بنفس الوقت ممكن تجرح أو ..تقتل
+
+151
+00:12:40,900 --> 00:12:45,320
+بيعتمد على الاستعمال الان النيلون يوم ما اخلص من
+
+152
+00:12:45,320 --> 00:12:48,700
+استعماله زي الكياس اللي بنشتري منها و بدنا نتخلص
+
+153
+00:12:48,700 --> 00:12:52,020
+منها و هلوم مجرد هو يمثل مشكلة بيئية انا مش قادر
+
+154
+00:12:52,020 --> 00:12:56,420
+اتخلص منه لكن النيلون في مرات تانية لما بدي اشي
+
+155
+00:12:56,420 --> 00:13:03,340
+طول عندهبكون بحاجة إلى نيلون يعني مثلا في الدول
+
+156
+00:13:03,340 --> 00:13:07,240
+اللي بيمشوا فيها كوابل التليفونات أو كهربا في
+
+157
+00:13:07,240 --> 00:13:11,900
+الأرض على عمق متر بيحطوا الكابل في الأرض على عمق
+
+158
+00:13:11,900 --> 00:13:15,640
+متر و بطموا شوية على عمق نص متر بتجيبوا شريط
+
+159
+00:13:15,640 --> 00:13:20,210
+النيلون الأصفر إذا بتشوفوا إيش بيكون مكتوبانتبه
+
+160
+00:13:20,210 --> 00:13:25,210
+خطر الحفريات أو خطر الكهرباء وفوق السلك المدفون
+
+161
+00:13:25,210 --> 00:13:29,130
+بنص متر بيكونوا حاطين أشريطة نايلون عليها الكتابة
+
+162
+00:13:29,130 --> 00:13:32,590
+هذا الشريط مفترض أنه ممكن يظل عشر أو خمستاشر أو
+
+163
+00:13:32,590 --> 00:13:37,310
+عشرين سنة يعني لو واحد إيجي يفحر بجرافة أو إيش،
+
+164
+00:13:37,310 --> 00:13:42,510
+انابوله بعد نص متر هتلاقي إيش؟ كابل كهربا فبعد
+
+165
+00:13:42,510 --> 00:13:47,870
+الحلقة أنا بصير مستفيد من فكرة أن النايلونمابتحللش
+
+166
+00:13:47,870 --> 00:13:52,030
+فأي شغلة ممكن أن أستفيد منها إذا بديالها شغلة مهمة
+
+167
+00:13:52,030 --> 00:13:58,190
+مابهمني مايتحللش لكن إذا خلصت منه بصير مشكلة خصوصا
+
+168
+00:13:58,190 --> 00:14:01,110
+بتشومه لما الناس في الليل بيحرجوا النيلون وكيف
+
+169
+00:14:01,110 --> 00:14:06,310
+الريحة تبعته لأن النيلون مابتحللش طيب نرجع إلى ال
+
+170
+00:14:06,310 --> 00:14:11,550
+issue النيلونالنيلون عبارة عن داي أسيد كلورايد
+
+171
+00:14:11,550 --> 00:14:14,950
+يعني باخد ست كربونات غالبا النيلون الشهير من ست
+
+172
+00:14:14,950 --> 00:14:18,010
+كربونات واحد اتنين اتلات اربعة خمسة ست أسيد
+
+173
+00:14:18,010 --> 00:14:24,710
+كلورايد وبياخدوا داي أمين مكوّن من ست كربونات الآن
+
+174
+00:14:24,710 --> 00:14:28,770
+بيجوا يفعلوا مع بعض هذه النيتروجين بتهاجم هنا على
+
+175
+00:14:28,770 --> 00:14:34,050
+الكربون و تطرد الـCl إذا انصرت هذه النيتروجين
+
+176
+00:14:34,050 --> 00:14:40,530
+شابكةبالـ C double bond O عاملة قامت الأب هاد الـ
+
+177
+00:14:40,530 --> 00:14:46,630
+nitrogen التاني شو بتعمل ابتشفك مع الجزيء من الجهة
+
+178
+00:14:46,630 --> 00:14:52,970
+التانية و هلمه جرن فبصير عند حوالي تلتة اربع تلاف
+
+179
+00:14:53,720 --> 00:14:58,920
+قطعة امكونين من ايش من 6 ذرات كربون اجه من ال acid
+
+180
+00:14:58,920 --> 00:15:04,600
+و بعدين 6 ذرات كربون اجه من ال diamine عشان هي كده
+
+181
+00:15:04,600 --> 00:15:11,740
+النيلون بيسموه نيلون اللي زي 6 6 الان طبعا هل
+
+182
+00:15:11,740 --> 00:15:17,300
+بيمكن ان انا اعمل نيلون 6 4 يعني اجيب 6 ذرات من
+
+183
+00:15:17,300 --> 00:15:24,600
+الحامض و 4 كربون و اعمل نيلونمافيش مانع بقدر اعمل
+
+184
+00:15:24,600 --> 00:15:28,960
+نايلون 68 مافيش مانع بس بيصير في كل حالة من
+
+185
+00:15:28,960 --> 00:15:33,340
+الحالات فيها نايلون مواصفة معينة يعني ال polymer
+
+186
+00:15:33,340 --> 00:15:37,800
+شفافية ال نايلون انه بتكسر انه بنتعجب هذا بعتمد
+
+187
+00:15:37,800 --> 00:15:42,560
+على ان اشتغل بأي نوع من الذرات و بنفس الوجهة ال
+
+188
+00:15:42,560 --> 00:15:47,620
+polymer اللي اعمله هل يكون 2000 مرة متكررة 3000
+
+189
+00:15:47,620 --> 00:15:54,820
+3500 هذا بيصير شغل ايش؟صناعة بيصير شغل صناعة
+
+190
+00:15:54,820 --> 00:15:58,800
+هالأشياء المختلفة كتير من النيلون بس أهم اشي في
+
+191
+00:15:58,800 --> 00:16:03,780
+النيلون فكرة ال amide linkage اللي هو ارتباط الامد
+
+192
+00:16:03,780 --> 00:16:10,840
+اللي بتخليه unreactive طبعا لمعلوماتك هو الامد
+
+193
+00:16:10,840 --> 00:16:16,120
+النيلون عفوا حضر في تقريبا ال 1934
+
+194
+00:16:17,890 --> 00:16:22,590
+حضر في الـ 1934 وكان صارخة ليش؟ لأنه بدأت الخيوط
+
+195
+00:16:22,590 --> 00:16:26,630
+النيلون و الجوارب النيلون و كل العالم يعني صارخة
+
+196
+00:16:26,630 --> 00:16:30,910
+كبيرة و تعبوا لما حطولها الإسم الجذاب نيلون يعني
+
+197
+00:16:30,910 --> 00:16:38,250
+مخترع كان إشي كتير جدا طبعا اللي اخترعه بعد تلت
+
+198
+00:16:38,250 --> 00:16:40,710
+أربع سنين زهج من الدنيا فانتحر
+
+199
+00:16:43,150 --> 00:16:46,830
+الدنيا واسعة، روحوا اسألوا ليش وانتحروا أنا ما
+
+200
+00:16:46,830 --> 00:16:51,170
+بعرفش ليش وبعد ذلك للأسف فترة الحرب العالمية
+
+201
+00:16:51,170 --> 00:16:55,110
+التانية تقريبا كل استفادة من النيلون للصناعات اللي
+
+202
+00:16:55,110 --> 00:16:59,530
+بتفيد الناس أغلقت لأنه صار لازم أعمل منه خيام
+
+203
+00:16:59,530 --> 00:17:04,670
+وبراشوت وما إلى ذلك فكل شغل النيلون صار يتحول
+
+204
+00:17:04,670 --> 00:17:08,930
+لإيش؟ للحرب في الحرب العالمية التانية خلصت الحرب
+
+205
+00:17:08,930 --> 00:17:12,970
+رجعوا يستعملوا في الملابس النيلونالـ fibers،
+
+206
+00:17:12,970 --> 00:17:18,890
+الخطان، اليوم أفضل الملابس، أقل تقدير بالنسبة
+
+207
+00:17:18,890 --> 00:17:23,690
+للنساء يعني، اللي بيكون فيها نسبة إيش؟ نيلون، مين
+
+208
+00:17:23,690 --> 00:17:30,530
+بيقدر يتعامل اليوم مع قميص كله قطن؟ من ناحية
+
+209
+00:17:30,530 --> 00:17:36,210
+الكوي، من ناحية إيش؟بكو جميس القطن إلا يكون 60%
+
+210
+00:17:36,210 --> 00:17:42,550
+قطن و 40% نيلون، مظبوط ولا لأ؟ فالخلاصة هذا هو
+
+211
+00:17:42,550 --> 00:17:47,070
+النيلون اللي هو عبارة عن Amides الان احنا اللي
+
+212
+00:17:47,070 --> 00:17:53,700
+قلناه ان تفاعلات ال Amides هي تفاعلات قليلةمن
+
+213
+00:17:53,700 --> 00:17:57,460
+التفاعلات القليلة أنه في ظروف معينة ليست سهلة يعني
+
+214
+00:17:57,460 --> 00:18:03,120
+بلزم حرارة و بلزم زمان كتير الأمن مع المي أو حامض
+
+215
+00:18:03,120 --> 00:18:07,620
+أو قاعدة أو حرارة أو زمان ممكن يتحول إلى أسف بمعنى
+
+216
+00:18:07,620 --> 00:18:11,300
+أن ال O H تاعة المي أو المي كلها تهاجم و بعدين
+
+217
+00:18:11,300 --> 00:18:17,320
+تفقد H فالأمنبيصيرله عملية بيسميها hydrolysis،
+
+218
+00:18:17,320 --> 00:18:22,320
+hydrolysis ليش؟ لأنه هي تفاعل مع الميه، تفاعل
+
+219
+00:18:22,320 --> 00:18:26,480
+الشغل مع الميه، hydrolysis فالامد ممكن يصيرله
+
+220
+00:18:26,480 --> 00:18:31,280
+hydrolysis بس زي ما قلتلكوا، بدهوقت و بده حرارة و
+
+221
+00:18:31,280 --> 00:18:35,520
+ما إلى ذلك الشروط التفصيلية بتكون مكتوبة في الكتب
+
+222
+00:18:35,520 --> 00:18:40,680
+العملية الشغل التاني انه زي ما كان يحصل عندى لل
+
+223
+00:18:40,680 --> 00:18:45,360
+Easter's reduction القمد ممكن يحصل له reduction
+
+224
+00:18:45,360 --> 00:18:49,520
+اتذكروا معايا في حالة ال Easter عشان اتقارلوا
+
+225
+00:18:49,520 --> 00:18:53,740
+المعادلتين بالظبط لما كان يكون عندى ال Easter و
+
+226
+00:18:53,740 --> 00:18:57,460
+كنت اعمله reduction بدي احطه تحته بالظبط كان عندى
+
+227
+00:18:57,460 --> 00:19:04,300
+RCWBond O و أعمل ردكشن
+
+228
+00:19:19,800 --> 00:19:24,760
+الأمد بنفس المنطق تماما الـ C double bond O تبعته
+
+229
+00:19:24,760 --> 00:19:29,500
+في ال reduction بتصير CH2 إذا لما بيكون عندي R C
+
+230
+00:19:29,500 --> 00:19:32,100
+double bond O NH2 معناك أن أنا المنهم هيدرايت
+
+231
+00:19:32,100 --> 00:19:38,520
+بيصير R CH2 NH2 يعني كأنه في الحالتين أنا عمال
+
+232
+00:19:38,520 --> 00:19:43,800
+بخلي الـ C double bond O CH2 بس مابتروحش هذا،
+
+233
+00:19:43,800 --> 00:19:49,820
+مابنخصمش carbonواضح؟ فال ammots are reduced to
+
+234
+00:19:49,820 --> 00:19:56,380
+amines المركبات اللي فيهم بس N H2 هم عبارة عن ايش؟
+
+235
+00:19:56,380 --> 00:19:59,520
+ال ammons، بهيك احنا بنقول أخدنا طريقة لتحضير ال
+
+236
+00:19:59,520 --> 00:20:04,240
+ammons ولا لا؟ يعني لما نحكي في chapter 11
+
+237
+00:20:04,240 --> 00:20:10,080
+preparation of ammons هنقول by reduction of ammots
+
+238
+00:20:11,030 --> 00:20:15,510
+إذا هذا هو يمثل بالنسبة للأمت تفاعل، بس بالنسبة
+
+239
+00:20:15,510 --> 00:20:20,890
+للأمين طريقة تحضير، بالنسبة للأمت هو تفاعل،
+
+240
+00:20:20,890 --> 00:20:24,190
+بالنسبة للأمين هو طريقة تحضير
+
+241
+00:20:25,870 --> 00:20:33,390
+الان هذا ال slide بتفرجيكوا بعض الأدوية اللى فيها
+
+242
+00:20:33,390 --> 00:20:38,630
+من مشتقات الأحماض حتى تشوفوا انه مش الكيميا بس
+
+243
+00:20:38,630 --> 00:20:43,750
+رموز لكنها أشياء على أرضالواقع يمكن هذا المركب
+
+244
+00:20:43,750 --> 00:20:48,430
+اللي هنا اللي هو عبارة عن أسد وهنا E star ال
+
+245
+00:20:48,430 --> 00:20:52,850
+principle I see the word OOR هذا E star وهذا أسد
+
+246
+00:20:52,850 --> 00:20:58,390
+هذا ال Aspirin اللي سميناه أسد ال salicylic acid
+
+247
+00:20:58,390 --> 00:21:02,870
+الأسبرين والأسبرين اللي هو ال analgesics أو ال
+
+248
+00:21:02,870 --> 00:21:11,220
+pain killer اللي هو قاتل يعني بيشيل الألمالتانى
+
+249
+00:21:11,220 --> 00:21:17,540
+اللى بيمر علينا كتير اللى هو ال acetaminophen و
+
+250
+00:21:17,540 --> 00:21:22,620
+هذا إله أسماء كتيرة و دوة يمكن ماحدش شنطه مابكونش
+
+251
+00:21:22,620 --> 00:21:30,110
+فيها منهاللي هو ال Acamol Acamol بنادول Tylenol كل
+
+252
+00:21:30,110 --> 00:21:36,470
+دولة بطريقتها لكن الاسم العلمي تبعه Acetaminophen
+
+253
+00:21:36,470 --> 00:21:41,690
+ليش؟ لإن هذا Amino فينول بالاصل يعني لما ناخد
+
+254
+00:21:41,690 --> 00:21:47,490
+البنزين و OH هذا فينول لما يكون هنا نتش تو Amino
+
+255
+00:21:47,490 --> 00:21:52,890
+حطينا Acetyl أه فبتصير Acetaminophen
+
+256
+00:21:55,190 --> 00:22:01,090
+أمينوفينور فكله بيسموه أسيتامينوفين عرفتوا كيف
+
+257
+00:22:01,090 --> 00:22:05,990
+الاسم جاي؟ اللي هو ال Acamol أسيتامينوفينور هذا
+
+258
+00:22:05,990 --> 00:22:12,410
+فيناستين برضه pain killer و بنفس الوقت بنسميه
+
+259
+00:22:12,410 --> 00:22:21,090
+antibiotic antibiotic الاشياء المخفضة للحرارةواضح؟
+
+260
+00:22:21,090 --> 00:22:24,570
+يعني دايما إنتوا لما الصغار اللي عندكم يسخنوا، شو
+
+261
+00:22:24,570 --> 00:22:29,190
+بدكم تعطوهم؟ Antibiotic، هي أكامول، هي أكامول،
+
+262
+00:22:29,190 --> 00:22:33,310
+التحميل هي أكامول، واضح؟ بس لإن الولد الصغير ما
+
+263
+00:22:33,310 --> 00:22:40,910
+بيبلعش و ما إلى ذلك، فبتعطوه ال antibiotic ودايما
+
+264
+00:22:40,910 --> 00:22:49,120
+biotic كلمة مرتبطة بالإيشبالحرارة بيروليسي مثلا
+
+265
+00:22:49,120 --> 00:22:55,900
+إيش معناه بيروليسي بيروليسي
+
+266
+00:22:55,900 --> 00:22:58,220
+التكسر بالحرارة
+
+267
+00:23:02,080 --> 00:23:06,440
+واضح؟ يمكن .. يمكن لاحظت أن بعض الناس .. أن بعض
+
+268
+00:23:06,440 --> 00:23:12,720
+الناس بيخربطوا بين كلمتين باللغة العربية فبيلفظوا
+
+269
+00:23:12,720 --> 00:23:19,720
+كلمة بغير ما يجب أن تلفظ به فالجهاز بتاع الغواصة
+
+270
+00:23:19,720 --> 00:23:24,520
+.. الجهاز الغواصة اللي فيه مرايتين وبيشوفوا فيه من
+
+271
+00:23:24,520 --> 00:23:30,540
+الأعماق لفوق أو تحت، شو بيسموه؟بالظبط هي الغلط انك
+
+272
+00:23:30,540 --> 00:23:37,220
+تقول بيروسكوب بيروسكوب ال بيروسكوب جهاز قياس حرارة
+
+273
+00:23:37,220 --> 00:23:42,260
+تاني فلاحظوا انتوا بالعربي بتكتبوا زي هي بيروسكوب
+
+274
+00:23:42,260 --> 00:23:46,220
+تبع المرايات و اللي بنشوف فيه اللي بنستعمله
+
+275
+00:23:46,220 --> 00:23:48,680
+بالغواصة و الحرارة عارفينه اللي فيه مرايتين
+
+276
+00:23:48,680 --> 00:23:54,560
+متعاكسات هذا بيروسكوب ال بيروسكوب جهاز تاني له
+
+277
+00:23:54,560 --> 00:24:00,260
+علاقة بالحرارةبهمش، أنا ليش بنبخ؟ على أساس أنه
+
+278
+00:24:00,260 --> 00:24:04,460
+إنتوا لما تقولوها ما تقولوش بيروسكوب بيرو حراري،
+
+279
+00:24:04,460 --> 00:24:10,960
+antibiotic مضاد للحرارة إيش يعني fever reducer؟
+
+280
+00:24:10,960 --> 00:24:17,320
+إيش ال fever؟ الحمّة وقد توفي يا رسول الله صلى
+
+281
+00:24:17,320 --> 00:24:24,650
+الله عليه وسلم بالحمّة ولا ما بتعرفوش الحكي؟في
+
+282
+00:24:24,650 --> 00:24:29,710
+أمثلة إضافية وهي أخر الـ slide جزء من الـ
+
+283
+00:24:29,710 --> 00:24:35,510
+Pheromones مرت عليكم كلمة Pheromones الـ
+
+284
+00:24:35,510 --> 00:24:41,830
+Pheromonات بالعربي اللي هي خلّينا نقول المنبهاتهي
+
+285
+00:24:41,830 --> 00:24:47,190
+مواد منبهة تفرزها الحشرات للتواصل، أيًا كان نوع
+
+286
+00:24:47,190 --> 00:24:50,890
+التواصل، غالبًا اللي هو التواصل الجنسي بين الذكور
+
+287
+00:24:50,890 --> 00:24:56,010
+والإناث، بيفرزوا فرمونات، وهذا يعني لاحظوا العلماء
+
+288
+00:24:56,010 --> 00:25:00,410
+لما بيفهموا أي شغلة، سبحان الله، بيعملولها إيش
+
+289
+00:25:00,410 --> 00:25:05,230
+عطول؟تطبيق .. بيعملوله تطبيق .. النمل نفسه لما
+
+290
+00:25:05,230 --> 00:25:08,870
+بيلتقي مع بعضه و كيف بيديل بعض على الطرق و ما إلى
+
+291
+00:25:08,870 --> 00:25:12,910
+.. برضه بيفرس في رومونات .. الآن البني أدمين
+
+292
+00:25:12,910 --> 00:25:16,230
+معروفين ساكنين في دوره بيعرفوا بعض أبو محمد و
+
+293
+00:25:16,230 --> 00:25:20,330
+الاخري .. لكن انتوا تخيلوا الحشرات لما نكون احنا
+
+294
+00:25:20,330 --> 00:25:25,150
+بفضاء كبير واسعوفي نهاية الحشرات بدأوا يتم فيها
+
+295
+00:25:25,150 --> 00:25:29,110
+تزاوج وتايها في بعض في الفضاء فبتلاقوا أحد الأصناف
+
+296
+00:25:29,110 --> 00:25:32,410
+سواء كان الذكور أو الإناث بيفرز روائح معينة بيحس
+
+297
+00:25:32,410 --> 00:25:35,930
+فيها الصنف التاني الآن كيف بيئيا استفادوا من هذه
+
+298
+00:25:35,930 --> 00:25:36,570
+الفكرة؟
+
+299
+00:25:39,030 --> 00:25:43,410
+بدل ما يجوا يقتلوا الحشرة بالرش حضروا الفيرومونات
+
+300
+00:25:43,410 --> 00:25:47,830
+كيمية، هاي مثال لفيرومون مثلا، Isoamil acetate،
+
+301
+00:25:47,830 --> 00:25:53,230
+بيسموه honey bee alarm، منبه للنحل مثلا أو هذا
+
+302
+00:25:53,230 --> 00:26:00,510
+لدودة معينةالفيرومون بيجيب الجنس الآخر الآن هذه
+
+303
+00:26:00,510 --> 00:26:03,930
+المراكبات حضروها في المختبر بعد ما حضروها كل اللي
+
+304
+00:26:03,930 --> 00:26:09,950
+بيلزمهم القاتل بيجيبوا عود بهذا الشكل بيحطوا عليه
+
+305
+00:26:09,950 --> 00:26:18,270
+سمق وشوية فيرومون وبيحطوه بالحقل زي هيك بيجذب كل
+
+306
+00:26:18,270 --> 00:26:21,970
+الحشرات بتيجي ايش بتلازج بالسمق لا برش مبيدات
+
+307
+00:26:21,970 --> 00:26:27,260
+حشرية ولا ما يحزنونشوفتوا كيف؟ هذا بيسموها مكافحة
+
+308
+00:26:27,260 --> 00:26:33,020
+نظيفة أو حيوية أو بيئية بدل ما يرشوا ال pesticides
+
+309
+00:26:33,020 --> 00:26:39,560
+اللي هي DDT وغيره و يكون فيها كلورين و فوسفور زي
+
+310
+00:26:39,560 --> 00:26:44,360
+الغازات المثيلة للدموع و إشي ما يقل .. يمكن اعملنا
+
+311
+00:26:44,360 --> 00:26:48,930
+احنا محاضرة عن ال ..الغازات السامة وغيرها، معظم
+
+312
+00:26:48,930 --> 00:26:52,850
+المبيضات الحشرية هي كلورينية في الغالب، يعني فيها
+
+313
+00:26:52,850 --> 00:26:56,350
+كلوريا، فوسفورية، فيها فوسفور، الآن هذه الطريقة
+
+314
+00:26:56,350 --> 00:27:02,090
+نسبيا تعتبر إيش؟ يعني أكثر صداقة، خلّينا نقول مع
+
+315
+00:27:02,090 --> 00:27:12,530
+البيئة، إبهيك بننتهي من هذا الفصل، بننتقل على طول
+
+316
+00:27:12,530 --> 00:27:18,980
+طبعالأن أنا بحاجة لكل دقيقة إلى الفصل الأخير اللي
+
+317
+00:27:18,980 --> 00:27:24,180
+هو ال amines أنا مش عارف بالمناسبة يعني أنا بدرس
+
+318
+00:27:24,180 --> 00:27:28,680
+ال organic للطب عادة بخلص ال amines في الأسبوع
+
+319
+00:27:28,680 --> 00:27:32,540
+السابع و بياخدوا أربع شباتر biochemistry زيادة
+
+320
+00:27:32,540 --> 00:27:38,360
+حوال 150 صفحةلأ لأ مش أشطر منكوا و الله لأ لأ
+
+321
+00:27:38,360 --> 00:27:40,700
+انتوا كتير منكم بتجيب علامة كاملة و ممكن منهم
+
+322
+00:27:40,700 --> 00:27:43,080
+تنتين بيجيبوا علامات كاملة و الباقين ممكن يجيبوا
+
+323
+00:27:43,080 --> 00:27:48,320
+ستين و خمسين و يورس و بذاك و ذاك و
+
+324
+00:27:48,320 --> 00:27:51,040
+بعدين هم بتغلبوا سبع سنين و بيلاقوا الشغل انتوا
+
+325
+00:27:51,040 --> 00:27:55,920
+بعد أربع سنين بتلاقوا وظيفة الشيء
+
+326
+00:27:55,920 --> 00:28:00,200
+المؤكد ان كل خريجين طبعا بالذات التخصصات التدرسية
+
+327
+00:28:00,200 --> 00:28:06,440
+كيميا فيزيا هدولة بيلاقوا وظائفتربي علوم، بتلاقي
+
+328
+00:28:06,440 --> 00:28:14,260
+وظائف، تحاليل طبية أقل. الآن نجي على الموضوع
+
+329
+00:28:14,260 --> 00:28:19,640
+الجديد تبعنا ال Amines ال Amines هم مشتقات،
+
+330
+00:28:19,640 --> 00:28:24,240
+انتبهوا معي، ال Amines هم مشتقات الأمونيا، يعني
+
+331
+00:28:24,240 --> 00:28:29,420
+أبسط من ناحية المبدأ كأنه أبسط مركب عنده الأمونيا،
+
+332
+00:28:29,420 --> 00:28:35,450
+اللي هي الH3 طبعا الأمونيا ما بنعتبرهاش organic
+
+333
+00:28:35,450 --> 00:28:41,790
+compound لأنه مافيش فيها carbon لكن ممكن أبدل H
+
+334
+00:28:41,790 --> 00:28:48,350
+واحدة منها بR يصير R on H2 ممكن أبدل تنتين بR يصير
+
+335
+00:28:48,350 --> 00:28:53,530
+R2 on H3 ممكن أبدل تلاتة بR يصير R3 on H3 وممكن
+
+336
+00:28:53,530 --> 00:28:58,950
+على زوج الإلكترونات اللي مازال موجود هنالأن في كل
+
+337
+00:28:58,950 --> 00:29:03,050
+الأحوال الـ nitrogen عليها إيش؟ زوج من الإلكترونات
+
+338
+00:29:03,050 --> 00:29:06,210
+أحط ال R الرابعة في هذه الحالة بتصير ال nitrogen
+
+339
+00:29:06,210 --> 00:29:10,910
+موجبة و بتاخد جنب أيون سالب فبصير عندي ال ammonia
+
+340
+00:29:10,910 --> 00:29:17,450
+ال primary amine اللي فيه un-H2 secondary amine
+
+341
+00:29:17,450 --> 00:29:22,490
+اللي فيه un-H tertiary amine اللي فيه un لحظة
+
+342
+00:29:22,490 --> 00:29:28,570
+quaternary amineرباعي يعني يعني متصل باربعة R اللي
+
+343
+00:29:28,570 --> 00:29:33,830
+فيه الـN positive والأمينز أنتوا عارفين أنه أساسية
+
+344
+00:29:33,830 --> 00:29:37,330
+في جسم الإنسان في البروتينات في ال RNA في ال DNA
+
+345
+00:29:37,330 --> 00:29:42,130
+يعني كل إشي في ال biology بتلاقوا فيه دايما إيش
+
+346
+00:29:42,130 --> 00:29:47,870
+نيتروجين بتلاقوا فيه نيتروجين سواء أمين أو أمد في
+
+347
+00:29:47,870 --> 00:29:53,270
+الآخر بالمناسبة هو الأمد زي ما احنا قولنا النيلون
+
+348
+00:29:55,700 --> 00:29:59,660
+unreactive شو الأمد التاني اللي كتير مشهور
+
+349
+00:29:59,660 --> 00:30:02,840
+وunreactive
+
+350
+00:30:02,840 --> 00:30:11,340
+يعني بيغلب لما يتكسر أبدا ليش تبعدوه البروتينات
+
+351
+00:30:11,340 --> 00:30:11,960
+اللحمة
+
+352
+00:30:14,400 --> 00:30:18,680
+البروتينات ليش بتغلب في الهضم و بدواجة كتير و حامض
+
+353
+00:30:18,680 --> 00:30:24,540
+و لما تتكسر لأن البروتين هو عبارة عن قمد البروتين
+
+354
+00:30:24,540 --> 00:30:29,920
+اللحمة مين بيقدر ياكل اللحمة
+
+355
+00:30:29,920 --> 00:30:35,840
+في الليل الساعة 11 و 12 و ينام عملية صعبة جدا على
+
+356
+00:30:35,840 --> 00:30:42,180
+البني آدم لأنه في الهضم بتغلبالـ Properties of
+
+357
+00:30:42,180 --> 00:30:46,340
+Amines كما تعرفون أن النيتروجين هو أتوم إلكترو
+
+358
+00:30:46,340 --> 00:30:50,860
+نيجاتيف من التلاتة المشهورين اللي بيعملوا
+
+359
+00:30:50,860 --> 00:30:55,340
+الهيدروجين بوندنج بناء على ذلك الأمين بتعمل
+
+360
+00:30:55,340 --> 00:30:59,760
+هيدروجين بوندنج إذا كان فيها أتش لو كانت أمين بدون
+
+361
+00:30:59,760 --> 00:31:04,280
+أتش خلاص بتبطل تعمل هيدروجين بوندنج اللي فيها أتش
+
+362
+00:31:04,280 --> 00:31:08,860
+و بتعمل هيدروجين بوندنج بيصير فيهاHigh boiling
+
+363
+00:31:08,860 --> 00:31:15,600
+points فالأمين هم
+
+364
+00:31:15,600 --> 00:31:21,180
+عبارة عن organic bases لأنه دائما نيتروجين عليها
+
+365
+00:31:21,180 --> 00:31:23,180
+زوج الإلكترونات
+
+366
+00:31:26,270 --> 00:31:31,450
+Electron donor بتعطي إلكترونات فمن أهم ال organic
+
+367
+00:31:31,450 --> 00:31:35,790
+bases اللي هي مركبات ال نيتروجين واضح مركبات ال
+
+368
+00:31:35,790 --> 00:31:39,690
+نيتروجين من أهم ال organic bases حتى المركبات اللي
+
+369
+00:31:39,690 --> 00:31:43,230
+زي ال نيكوتين و الكفايين و إشي بيسموهم الكلويتس
+
+370
+00:31:43,230 --> 00:31:47,430
+الكلويتس يعني القاعدين ليش هدول يعتبروا الكلويتس
+
+371
+00:31:47,430 --> 00:31:52,930
+أو قاعدين لأن فيهم نيتروجين لما الواحد يتطلع الشكل
+
+372
+00:31:52,930 --> 00:31:59,820
+تبعهمالآن لو قلنا كيف بدنا نسمي الـ Amines الحقيقة
+
+373
+00:31:59,820 --> 00:32:05,200
+في أكتر من طريقة لتسمية الـ Amine في طرق Iopaque
+
+374
+00:32:05,200 --> 00:32:08,960
+وفي طرق مشهورة وفي طرق حسب الـ Chemical Abstract
+
+375
+00:32:08,960 --> 00:32:16,040
+ربما أسهل الطرق أنه نعامل الـ Amino group مثل أي
+
+376
+00:32:16,040 --> 00:32:18,860
+مجموعة بتيجي على الألكين يعني الألكين لما بيجي
+
+377
+00:32:18,860 --> 00:32:23,540
+عليه بروم، إيش بنقول عنها؟ والأمين نقول عنها Amino
+
+378
+00:32:24,120 --> 00:32:29,800
+فنعتبر أن الأساس اللي عندك الالكين وهذه أخدها
+
+379
+00:32:29,800 --> 00:32:36,500
+كمجموعة زي ما هذه اسمها Bromo وهذه اسمها Amino
+
+380
+00:32:36,500 --> 00:32:42,760
+بنقول الـ NH2 بس هي مجموعة واسمها Amino بناء على
+
+381
+00:32:42,760 --> 00:32:46,600
+ذلك لو مثلا أنا أطلع تايكاربونتينتين تلاتة أربعة
+
+382
+00:32:46,600 --> 00:32:54,860
+بيوتين لو اتصل ب OHالان عليك على موقع اتنين تبرم
+
+383
+00:32:54,860 --> 00:33:00,780
+على موقع اربعة امينو اذا هذا four amino two bromo
+
+384
+00:33:00,780 --> 00:33:06,000
+لحظة ال alphabetical ال a قبل ال b four amino two
+
+385
+00:33:06,000 --> 00:33:11,340
+bromo و ال butanolفي حالة الـ butanol الـ OH ممكن
+
+386
+00:33:11,340 --> 00:33:15,280
+تكون على أكتر من موقع، يجب أن يحدد موقعها، لكن لو
+
+387
+00:33:15,280 --> 00:33:20,780
+افترضت كان عندها نقل دهايد،
+
+388
+00:33:20,780 --> 00:33:24,860
+فبتقول واحد في هذه الحالة يقول خلاص butanol بدون
+
+389
+00:33:25,490 --> 00:33:31,410
+one إذا من أسهل التسميات .. من أسهل التسميات لأ ال
+
+390
+00:33:31,410 --> 00:33:35,530
+.. a means أن أقول ال N-H2 هي عبارة عن مجموعة
+
+391
+00:33:35,530 --> 00:33:41,330
+اسمها Amino طيب مرات بتكون موجودة المجموعة مش على
+
+392
+00:33:41,330 --> 00:33:45,330
+شكل N-H2 أنا قبل شوية قولت ال N-H2 على ن والرأس شو
+
+393
+00:33:45,330 --> 00:33:53,230
+سمناها؟ Amino طيب لو كانت N-H مثل مثلا شو بدي
+
+394
+00:33:53,230 --> 00:34:04,110
+أسميها؟مثل أمينو مثل أمينو مثل أمينو طيب لو كانت
+
+395
+00:34:04,110 --> 00:34:09,610
+أن مثل تو دايمثل
+
+396
+00:34:09,610 --> 00:34:14,050
+أمينو يعني لما يكون عندي هنا أن مثل او مثل شو
+
+397
+00:34:14,050 --> 00:34:18,950
+بيصير اسمها؟ دايمثل أمينو كجروب يعني لو أن هذه
+
+398
+00:34:18,950 --> 00:34:22,810
+مثلا كانت أن و عليها مثل و مثل بدي أقول four
+
+399
+00:34:25,040 --> 00:34:31,160
+Dimethylamino لو كانت أنه عليها مثل four مثل أمينو
+
+400
+00:34:31,160 --> 00:34:38,560
+إذا الان أتش two أمينو الان أتش مثل مثل أمينو طبعا
+
+401
+00:34:38,560 --> 00:34:42,320
+لو كانت R بنسمي ال R أثل أمينو واحدة بقى الان مثل
+
+402
+00:34:42,320 --> 00:34:45,780
+two dimethylamino
+
+403
+00:34:50,640 --> 00:34:54,920
+واضح؟ إيش كان السؤال؟
+
+404
+00:34:54,920 --> 00:35:01,330
+لا طبعا قدش واحدة، ما هو ده شابك بحاجة تانيةهيوغ
+
+405
+00:35:01,330 --> 00:35:05,150
+زي هانا هذا شابك بحاجة تانية أنا بحكي عنها كمجموعة
+
+406
+00:35:05,150 --> 00:35:11,110
+بمعنى أنها شابكة بشيء تاني يعني افترض مرتبطة بخمس
+
+407
+00:35:11,110 --> 00:35:14,810
+كربونات، شو بدي يكون؟ one على موقع واحد، one
+
+408
+00:35:14,810 --> 00:35:19,910
+aminobentain، one methylaminobentain، one
+
+409
+00:35:19,910 --> 00:35:24,490
+dimethylaminobentain، بهذا الشكل لأن هي هانا
+
+410
+00:35:24,490 --> 00:35:30,170
+كمجموعة، والمجموعة دائما إيش بتكون؟بتكون ناقص واحد
+
+411
+00:35:30,170 --> 00:35:37,110
+لما كنت أقول الميثين جزء CH4 الميثل مجموعة بتنقص
+
+412
+00:35:37,110 --> 00:35:42,530
+واحد دائما المجموعة هاي عندي أمثلة هنا لو فى عندي
+
+413
+00:35:42,530 --> 00:35:48,830
+مثلا تلت كاربونات على الذرع الأول NH2 إيش بنقول؟
+
+414
+00:35:48,830 --> 00:35:56,670
+one aminoborben هناك two aminoborben هنا ست ذراته
+
+415
+00:35:56,670 --> 00:36:03,900
+على موقع اتنينto a minor hexane طيب هاي هنا مثال
+
+416
+00:36:03,900 --> 00:36:08,020
+جديد لاحظوا هاي السلسلة دي واحد اتنين تلاتة هي
+
+417
+00:36:08,020 --> 00:36:14,420
+الأطول ماذا تحمل مجموعة الان مثل
+
+418
+00:36:18,240 --> 00:36:23,280
+أه اللي هي ال مثل أمينو طبعا بنقدر يقول .. هلأ
+
+419
+00:36:23,280 --> 00:36:26,520
+بيسموه بطرف تاني يعني ممكن يقول أ مثل و أمينو
+
+420
+00:36:26,520 --> 00:36:31,140
+بروبين والأسهل انه يقول one زي ما توي حكينالكوا
+
+421
+00:36:31,140 --> 00:36:38,860
+إيش اسم المجموعة مثل أمينو بروبين زي هيك بيكون إيش
+
+422
+00:36:38,860 --> 00:36:44,460
+أسهل one إيش اسم المجموعة مثل أمينو
+
+423
+00:36:47,250 --> 00:36:51,490
+Dimethyl Amino جاي على وين؟ على الـ Cyclohexane
+
+424
+00:36:51,490 --> 00:36:56,310
+فبنقول Dimethyl Amino Cyclohexane لو حط من عنده NN
+
+425
+00:36:56,310 --> 00:37:01,450
+عارفين شو معناه؟ يعني أن الميثلز متصلة بنيتروجين
+
+426
+00:37:01,450 --> 00:37:05,490
+وقبل شوية حكينا عنها بال form amides إذا أنتم
+
+427
+00:37:05,490 --> 00:37:12,210
+متذكرين، مظبوط؟ إذا زي ما قلنا الـNH2 اسمها Amino
+
+428
+00:37:12,210 --> 00:37:23,590
+الـNH Methylمثل امينو والان مثلتو دايمثل امينو هاي
+
+429
+00:37:23,590 --> 00:37:29,550
+عندى هنا كمان امثلة اضافية بإمكانكوا تقرؤوها بوضوء
+
+430
+00:37:29,550 --> 00:37:34,330
+او زى ما بدكم هاي هنا مثلا واحد اتنين تلاتة على
+
+431
+00:37:34,330 --> 00:37:40,340
+موقع واحد واتنين عندكوا امينو امينو ايش بيكون؟1,2
+
+432
+00:37:40,340 --> 00:37:43,800
+-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1
+
+433
+00:37:43,800 --> 00:37:44,040
+,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl
+
+434
+00:37:44,040 --> 00:37:46,720
+-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2
+
+435
+00:37:46,720 --> 00:37:49,400
+-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1
+
+436
+00:37:49,400 --> 00:37:50,360
+-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2
+
+437
+00:37:50,360 --> 00:37:57,840
+-dimethyl-1,2-dimethyl-1,2-dimethyl-1,2-dimethyl-1
+
+438
+00:37:57,840 --> 00:38:06,650
+,2-dimethyl-1,2-dimethyl-تو بيوتانول تو بيوتانول
+
+439
+00:38:06,650 --> 00:38:11,910
+هاي السلسلة الأساسية بيوتان بيوتانول تو بيوتانول
+
+440
+00:38:11,910 --> 00:38:21,850
+ثلاث أمينو ثلاث بثلاث واضح المركب اللي فوق لاحظوا
+
+441
+00:38:21,850 --> 00:38:27,230
+هذا ترد شري أمين هذا ترد شري أمين يمكن لو انفصلوا
+
+442
+00:38:27,230 --> 00:38:28,610
+بسهل
+
+443
+00:38:35,490 --> 00:38:39,870
+هنا CH3 وهنا CH2 وهنا CH3 وهنا CH3 وهنا CH3 وهنا
+
+444
+00:38:39,870 --> 00:38:43,830
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+445
+00:38:43,830 --> 00:38:43,970
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+446
+00:38:43,970 --> 00:38:45,530
+وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا
+
+447
+00:38:45,530 --> 00:38:46,390
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+448
+00:38:46,390 --> 00:38:47,270
+وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا
+
+449
+00:38:47,270 --> 00:38:48,450
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+450
+00:38:48,450 --> 00:38:51,790
+CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3 وهنا CH3
+
+451
+00:38:51,790 --> 00:38:57,730
+وهنا CH3للإيثيل هذا الإيثيل هاي واحد هاي اتنين ايش
+
+452
+00:38:57,730 --> 00:39:06,870
+موجود عليه على موقع واحد اتطلعوا أن إيثيل أن مثل
+
+453
+00:39:06,870 --> 00:39:11,790
+كل هذه المجموعة هاي اسمها هذه كلها تعتبر مجموعة
+
+454
+00:39:11,790 --> 00:39:14,570
+ايش اسمها أن إيثيل أن مثل
+
+455
+00:39:18,680 --> 00:39:23,980
+هذه ليست أن ضاي إثل ولا ضاي مثل عليها إثل و مثل
+
+456
+00:39:23,980 --> 00:39:34,220
+كإنها إثل مثل أمينو أو أن إثل أن مثل أمينو إثل فهو
+
+457
+00:39:34,220 --> 00:39:39,700
+قال أن إثل و أن مثل و الأمينو هو المتصلة على موقع
+
+458
+00:39:39,700 --> 00:39:45,220
+واحد one amino ethyl لو قال مثلا one ethyl مثل
+
+459
+00:39:45,220 --> 00:39:52,610
+أمينو إثلبرضه بمشي يعني مرات بتلاقوا يعني شغلة
+
+460
+00:39:52,610 --> 00:39:56,130
+بسيطة في اسم التغيير بس مافيش مشكلة يعني كل هذه
+
+461
+00:39:56,130 --> 00:40:01,570
+المجموعة اللي في الأزرق جاية على أي موقع واحد لو
+
+462
+00:40:01,570 --> 00:40:06,170
+كانت هذه unatched وشو كنت حاسب المركب one Amino
+
+463
+00:40:06,170 --> 00:40:16,570
+اثنى الان هذه Amino ولا اثنى مثل Amino
+
+464
+00:40:17,710 --> 00:40:22,330
+يعني هاي هذي كلها وان اثل مثل اماي دي مجموعة و كله
+
+465
+00:40:22,330 --> 00:40:29,270
+جاي على وين على اثين على موقع الواحد فلما تحللوا
+
+466
+00:40:29,270 --> 00:40:33,550
+اي اسم بتلاحظوا ان العملية او التسمية ليست أمرا
+
+467
+00:40:33,550 --> 00:40:35,450
+صعبة
+
+468
+00:40:47,010 --> 00:40:53,450
+الان ال amino ممكن تكون على ال aromatic ال NH2 هذه
+
+469
+00:40:53,450 --> 00:40:57,830
+ممكن تكون على ال aromatic المركب البنزيني اللي
+
+470
+00:40:57,830 --> 00:41:04,310
+عليه NH2 أخد اسم شهرة شو تسمى؟ أنيلين الأن لو صار
+
+471
+00:41:04,310 --> 00:41:10,290
+أنيلين مع طولوين يعني لو بس NH2 أنيلين لو بس مثل
+
+472
+00:41:10,290 --> 00:41:15,860
+طولوين طب لما ينخلطوا مع بعض؟زي ما بنخلط الكيميا
+
+473
+00:41:15,860 --> 00:41:21,080
+بالفيزيا ايش بنقول physical chemistry او
+
+474
+00:41:21,080 --> 00:41:26,520
+المغناطسية بالكهربائية ايش بنقول electromagnetic
+
+475
+00:41:26,520 --> 00:41:33,100
+او كهرومغناطسية هنا خلطنا التلوين بالانليل فبسموه
+
+476
+00:41:33,100 --> 00:41:41,810
+طبعا هذا بارا بارا توليدين هنا اورتو توليدينميتا
+
+477
+00:41:41,810 --> 00:41:46,750
+تولدين هؤلاء التولدين هم اللي جايين من خلطة
+
+478
+00:41:46,750 --> 00:41:52,130
+التلوين مع الأليلين فبيسموهم
+
+479
+00:41:52,130 --> 00:41:58,850
+بهذا الشكل بارا تولدين اورثو تولدين وميتا تولدين
+
+480
+00:41:58,850 --> 00:42:02,750
+لسه ضايل عندنا بس ال common names ان الله يحب
+
+481
+00:42:02,750 --> 00:42:08,930
+الصابرين إذا صبروا الآن لو إجينا قولنا ال common
+
+482
+00:42:08,930 --> 00:42:09,670
+names
+
+483
+00:42:12,800 --> 00:42:17,860
+زي ما كنا نسمي في حالة ال halogens يعني انا بدي
+
+484
+00:42:17,860 --> 00:42:22,060
+اعطيكوا مثال عشان بس انتوا تشوفوا الموازنة لما كان
+
+485
+00:42:22,060 --> 00:42:30,740
+كنت عندي CH3Cl شو كنت اسمي انا؟ أيوبك أو common؟
+
+486
+00:42:30,740 --> 00:42:35,860
+في ال أيوبك كنت اقول ال chloro مثين مثين يعني
+
+487
+00:42:35,860 --> 00:42:39,420
+الاصل اللي عندك مثين هذا أيوبك
+
+488
+00:42:41,940 --> 00:42:49,440
+اخد هذه المجموعة ما اسمها مثل مثل اكلورايد مثل
+
+489
+00:42:49,440 --> 00:42:53,960
+اكلورايد الان لو الكلام نفسه اتكرر عندي هذا common
+
+490
+00:42:53,960 --> 00:43:01,780
+name لو اتكرر عندي في ال amine هذا امينو مثل بال
+
+491
+00:43:01,780 --> 00:43:13,990
+أيوبك طب ال common مثل امين هذا دائم مثلأميل هدا
+
+492
+00:43:13,990 --> 00:43:19,190
+هى أميل وحمل إثل إثل أميل لو كنت بدي أقابل أيوبك
+
+493
+00:43:19,190 --> 00:43:29,270
+one aminoethane أو امينو إثل هدا مثل إثلمثل أمين
+
+494
+00:43:29,270 --> 00:43:39,350
+مثل أمين
+
+495
+00:43:39,350 --> 00:43:44,910
+مثل أمين
+
+496
+00:43:44,910 --> 00:43:48,850
+مثل أمين مثل أمين مثل أمين مثل أمين مثل أمين مثل
+
+497
+00:43:48,850 --> 00:43:51,370
+أمين مثل أمين مثل أميننفس ال isopropyl هاي ال
+
+498
+00:43:51,370 --> 00:43:55,790
+isopropyl كمجموعة و هاد ال amine هاد ال isopropyl
+
+499
+00:43:55,790 --> 00:43:59,050
+amine طب لو قولنا لو احنا سمينا يا بال ayobac
+
+500
+00:43:59,050 --> 00:44:02,390
+مظبوط
+
+501
+00:44:02,390 --> 00:44:08,270
+two aminopropane زي تماما لو كنت بتقوله بال
+
+502
+00:44:08,270 --> 00:44:12,290
+chlorine isopropyl chloride بيكون حاطين هنا
+
+503
+00:44:12,290 --> 00:44:16,210
+chlorine بال ayobac two chloro
+
+504
+00:44:34,690 --> 00:44:42,400
+Tropanol تقريبا تقريباما خلصناش التسمية بتضل slide
+
+505
+00:44:42,400 --> 00:44:46,440
+عشان تراجعوا كل موضوع التسمية فلما نشرحها بتجمع
+
+506
+00:44:46,440 --> 00:44:50,840
+ايش كل الموضوع بنذكر في التسمية في أول المحاضرة
+
+507
+00:44:50,840 --> 00:44:58,180
+القادمة ان شاء الله لا لا ان شاء الله يمكن ال ..
+
+508
+00:44:58,180 --> 00:45:02,660
+الاتنين اخر محاضرة انتوا لسه امتحانكوا التلاتة
+
+509
+00:45:02,660 --> 00:45:03,460
+اللي بعد يعني
+
+510
+00:45:16,180 --> 00:45:16,460
+أه
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..f84dfbce27f4493c72331907f7d995f79b5f2e15
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1Coj33khK7w_raw.json
@@ -0,0 +1 @@
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{"start": 645.11, "end": 645.39, "word": " الآن", "probability": 0.7108154296875}, {"start": 645.39, "end": 645.99, "word": " مابناخدش", "probability": 0.84423828125}, {"start": 645.99, "end": 646.61, "word": " تفاعلات", "probability": 0.93857421875}, {"start": 646.61, "end": 646.99, "word": " كتيرة", "probability": 0.85107421875}, {"start": 646.99, "end": 647.27, "word": " لـ", "probability": 0.31768798828125}, {"start": 647.27, "end": 647.75, "word": " AMIDS", "probability": 0.54638671875}, {"start": 647.75, "end": 649.43, "word": " ليش؟", "probability": 0.71826171875}, {"start": 649.43, "end": 649.85, "word": " لأن", "probability": 0.883544921875}, {"start": 649.85, "end": 650.07, "word": " الـ", "probability": 0.78662109375}, {"start": 650.07, "end": 650.21, "word": " C", "probability": 0.646484375}, {"start": 650.21, "end": 650.43, "word": " double", "probability": 0.828125}, {"start": 650.43, "end": 650.77, "word": " bond", "probability": 0.966796875}, {"start": 650.77, "end": 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657.79, "word": " من", "probability": 0.99462890625}, {"start": 657.79, "end": 658.15, "word": " برة", "probability": 0.720703125}, {"start": 658.15, "end": 658.47, "word": " تيجي", "probability": 0.982421875}, {"start": 658.47, "end": 658.95, "word": " تهجم", "probability": 0.9859619140625}, {"start": 658.95, "end": 659.53, "word": " عليها", "probability": 0.994873046875}, {"start": 659.53, "end": 660.29, "word": " وبصير", "probability": 0.7198893229166666}, {"start": 660.29, "end": 660.47, "word": " هذا", "probability": 0.8447265625}, {"start": 660.47, "end": 660.61, "word": " ال", "probability": 0.619140625}, {"start": 660.61, "end": 660.85, "word": " resonance", "probability": 0.53173828125}, {"start": 660.85, "end": 661.49, "word": " structures", "probability": 0.548828125}, {"start": 661.49, "end": 662.93, "word": " فبسبب", "probability": 0.8380126953125}], "temperature": 1.0}, {"id": 29, "seek": 69171, "start": 663.83, "end": 691.71, "text": "الـ Resonance يُعتبر الأمد Unreactive يعني الأمد الـ Resonance يُعتبر أمداً غير ردوداً واضح؟ إذن إيش سبب الـ Unreactivity؟ اللي هو الأمد Resonance رغم إن هالمجمعتين يُعتبروا زي ما اتفقنا من إيش؟ من أنشط المجموعات لما يكونوا كل واحدة لحال لكن إذا أتيوا مع بعض سبحان الله", "tokens": [6027, 39184, 5015, 266, 719, 7251, 10859, 34268, 26890, 16247, 2304, 3215, 1156, 265, 12596, 37495, 22653, 16247, 2304, 3215, 2423, 39184, 5015, 266, 719, 7251, 10859, 34268, 26890, 5551, 2304, 3215, 995, 14111, 32771, 13546, 12602, 3215, 23328, 995, 14111, 4032, 46958, 5016, 22807, 11933, 8848, 1863, 11933, 1829, 8592, 8608, 3555, 3555, 2423, 39184, 1156, 265, 578, 4253, 22807, 13672, 1829, 31439, 16247, 2304, 3215, 5015, 266, 719, 12602, 17082, 2304, 36145, 8032, 45340, 7435, 2304, 34268, 9957, 7251, 10859, 34268, 26890, 14407, 30767, 1829, 19446, 1975, 2655, 5172, 4587, 8315, 9154, 11933, 1829, 8592, 22807, 9154, 14739, 8592, 9566, 9673, 7435, 2304, 45367, 9307, 5296, 15042, 7251, 30544, 14407, 28242, 36764, 24401, 3660, 5296, 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{"start": 670.63, "end": 671.57, "word": " يُعتبر", "probability": 0.578369140625}, {"start": 671.57, "end": 674.03, "word": " أمداً", "probability": 0.487353515625}, {"start": 674.03, "end": 674.03, "word": " غير", "probability": 0.6527099609375}, {"start": 674.03, "end": 674.95, "word": " ردوداً", "probability": 0.487109375}, {"start": 674.95, "end": 676.53, "word": " واضح؟", "probability": 0.6575927734375}, {"start": 676.53, "end": 676.77, "word": " إذن", "probability": 0.7501627604166666}, {"start": 676.77, "end": 676.93, "word": " إيش", "probability": 0.8494466145833334}, {"start": 676.93, "end": 677.25, "word": " سبب", "probability": 0.98095703125}, {"start": 677.25, "end": 677.43, "word": " الـ", "probability": 0.86767578125}, {"start": 677.43, "end": 678.49, "word": " Unreactivity؟", "probability": 0.78154296875}, {"start": 678.49, "end": 679.09, "word": " اللي", "probability": 0.89013671875}, {"start": 679.09, "end": 679.31, "word": " هو", "probability": 0.98876953125}, {"start": 679.31, "end": 679.95, "word": " الأمد", "probability": 0.9542643229166666}, {"start": 679.95, "end": 681.01, "word": " Resonance", "probability": 0.7772623697916666}, {"start": 681.01, "end": 682.03, "word": " رغم", "probability": 0.8582356770833334}, {"start": 682.03, "end": 682.29, "word": " إن", "probability": 0.58642578125}, {"start": 682.29, "end": 683.25, "word": " هالمجمعتين", "probability": 0.8319091796875}, {"start": 683.25, "end": 683.83, "word": " يُعتبروا", "probability": 0.95947265625}, {"start": 683.83, "end": 683.99, "word": " زي", "probability": 0.734130859375}, {"start": 683.99, "end": 684.11, "word": " ما", "probability": 0.92138671875}, {"start": 684.11, "end": 684.57, "word": " اتفقنا", "probability": 0.9533203125}, {"start": 684.57, "end": 684.79, "word": " من", "probability": 0.8974609375}, {"start": 684.79, "end": 685.31, "word": " إيش؟", "probability": 0.75146484375}, {"start": 685.31, "end": 685.79, "word": " من", "probability": 0.97314453125}, {"start": 685.79, "end": 686.21, "word": " أنشط", "probability": 0.9749348958333334}, {"start": 686.21, "end": 686.85, "word": " المجموعات", "probability": 0.98330078125}, {"start": 686.85, "end": 687.05, "word": " لما", "probability": 0.905029296875}, {"start": 687.05, "end": 687.57, "word": " يكونوا", "probability": 0.9827473958333334}, {"start": 687.57, "end": 687.83, "word": " كل", "probability": 0.97021484375}, {"start": 687.83, "end": 688.17, "word": " واحدة", "probability": 0.9845377604166666}, {"start": 688.17, "end": 688.55, "word": " لحال", "probability": 0.9847005208333334}, {"start": 688.55, "end": 689.03, "word": " لكن", "probability": 0.386474609375}, {"start": 689.03, "end": 689.33, "word": " إذا", "probability": 0.985595703125}, {"start": 689.33, "end": 689.59, "word": " أتيوا", "probability": 0.6072591145833334}, {"start": 689.59, "end": 689.77, "word": " مع", "probability": 0.9931640625}, {"start": 689.77, "end": 690.27, "word": " بعض", "probability": 0.989501953125}, {"start": 690.27, "end": 691.47, "word": " سبحان", "probability": 0.8606770833333334}, {"start": 691.47, "end": 691.71, "word": " الله", "probability": 0.95703125}], "temperature": 1.0}, {"id": 30, "seek": 71239, "start": 692.77, "end": 712.39, "text": "بتشغلوا في بعض زي هيك ربما مما يثبت هذا الكلام ان الامد is very unreactive ان عندكم النيلون النيلون النيلون الحقيقة هو عبارة عن امد", "tokens": [3555, 2655, 8592, 17082, 1211, 14407, 8978, 45030, 11242, 30767, 1829, 39896, 4117, 12602, 3555, 15042, 3714, 15042, 7251, 12984, 3555, 2655, 23758, 2423, 28820, 10943, 16472, 2423, 10943, 3215, 307, 588, 20584, 12596, 16472, 43242, 24793, 2423, 22653, 1211, 11536, 2423, 22653, 1211, 11536, 2423, 22653, 1211, 11536, 21542, 38436, 28671, 31439, 6225, 3555, 9640, 3660, 18871, 1975, 2304, 3215], "avg_logprob": -0.12254284418398334, "compression_ratio": 1.5524475524475525, "no_speech_prob": 0.0, "words": [{"start": 692.77, "end": 693.37, "word": "بتشغلوا", "probability": 0.923828125}, {"start": 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antibiotic الاشياء المخفضة للحرارة", "tokens": [10721, 2304, 9957, 38688, 9957, 13063, 6156, 28820, 3224, 4724, 1829, 38251, 2407, 3224, 5551, 3794, 36081, 10943, 9957, 38688, 9957, 6225, 28480, 2655, 14407, 9122, 33911, 2423, 32277, 2304, 10874, 47302, 22807, 13672, 1829, 31439, 2423, 5097, 335, 401, 5551, 3794, 36081, 10943, 9957, 38688, 9957, 13063, 23758, 8978, 8315, 14851, 9957, 4724, 43042, 3224, 1822, 13364, 4032, 44945, 36178, 2423, 30543, 2655, 44945, 38251, 1829, 3224, 37828, 37828, 2423, 33599, 1829, 16606, 9673, 9778, 5172, 11242, 3660, 24976, 5016, 2288, 9640, 3660], "avg_logprob": -0.2654411652508904, "compression_ratio": 1.648936170212766, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1315.1899999999998, "end": 1316.59, "word": "أمينوفينور", "probability": 0.7059733072916666}, {"start": 1316.59, "end": 1317.25, "word": " فكله", "probability": 0.5398356119791666}, {"start": 1317.25, "end": 1318.13, "word": " بيسموه", "probability": 0.916015625}, {"start": 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إذا كان فيها أتش لو كانت أمين بدون أتش خلاص بتبطل تعمل هيدروجين بوندنج اللي فيها أتش و بتعمل هيدروجين بوندنج بيصير فيها", "tokens": [6027, 39184, 27627, 6097, 295, 2012, 1652, 9122, 15042, 37279, 28480, 11536, 14739, 28239, 36081, 2288, 29245, 9957, 31439, 5551, 2655, 20498, 11933, 23275, 2655, 32887, 8717, 1829, 7435, 9307, 33911, 9154, 16712, 1211, 9307, 3660, 9673, 8592, 3224, 13063, 9957, 13672, 1829, 4724, 1829, 25957, 1211, 14407, 2423, 3224, 25708, 2288, 29245, 9957, 4724, 2407, 1863, 3215, 1863, 7435, 44945, 16606, 15844, 29910, 23275, 16247, 2304, 9957, 39894, 25957, 1211, 8032, 25708, 2288, 29245, 9957, 4724, 2407, 41260, 1863, 7435, 11933, 15730, 25961, 8978, 11296, 5551, 2655, 8592, 45164, 25961, 2655, 5551, 2304, 9957, 47525, 11536, 5551, 2655, 8592, 16490, 1211, 33546, 39894, 3555, 9566, 1211, 6055, 25957, 1211, 8032, 25708, 2288, 29245, 9957, 4724, 2407, 41260, 1863, 7435, 13672, 1829, 8978, 11296, 5551, 2655, 8592, 4032, 39894, 25957, 1211, 8032, 25708, 2288, 29245, 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{"start": 1859.44, "end": 1859.76, "word": " بدون", "probability": 0.983642578125}, {"start": 1859.76, "end": 1860.3, "word": " أتش", "probability": 0.9650065104166666}, {"start": 1860.3, "end": 1861.42, "word": " خلاص", "probability": 0.8653971354166666}, {"start": 1861.42, "end": 1861.96, "word": " بتبطل", "probability": 0.7510986328125}, {"start": 1861.96, "end": 1862.36, "word": " تعمل", "probability": 0.9635416666666666}, {"start": 1862.36, "end": 1862.96, "word": " هيدروجين", "probability": 0.9275390625}, {"start": 1862.96, "end": 1863.36, "word": " بوندنج", "probability": 0.89931640625}, {"start": 1863.36, "end": 1863.74, "word": " اللي", "probability": 0.89697265625}, {"start": 1863.74, "end": 1864.02, "word": " فيها", "probability": 0.859619140625}, {"start": 1864.02, "end": 1864.28, "word": " أتش", "probability": 0.9677734375}, {"start": 1864.28, "end": 1864.42, "word": " و", "probability": 0.677734375}, {"start": 1864.42, "end": 1864.74, "word": " بتعمل", "probability": 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{"start": 2105.15, "end": 2105.83, "word": " بمعنى", "probability": 0.9689453125}, {"start": 2105.83, "end": 2106.09, "word": " أنها", "probability": 0.4237060546875}, {"start": 2106.09, "end": 2106.67, "word": " شابكة", "probability": 0.923828125}, {"start": 2106.67, "end": 2107.05, "word": " بشيء", "probability": 0.76202392578125}, {"start": 2107.05, "end": 2107.57, "word": " تاني", "probability": 0.97705078125}, {"start": 2107.57, "end": 2108.33, "word": " يعني", "probability": 0.709716796875}, {"start": 2108.33, "end": 2108.71, "word": " افترض", "probability": 0.9261474609375}, {"start": 2108.71, "end": 2110.41, "word": " مرتبطة", "probability": 0.9646484375}, {"start": 2110.41, "end": 2111.11, "word": " بخمس", "probability": 0.9306640625}, {"start": 2111.11, "end": 2111.81, "word": " كربونات،", "probability": 0.6893310546875}, {"start": 2111.81, "end": 2111.93, "word": " شو", "probability": 0.80078125}, {"start": 2111.93, "end": 2112.07, "word": " بدي", "probability": 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مجموعة بتنقص واحد دائما المجموعة هاي عندي أمثلة هنا لو فى عندي مثلا تلت كاربونات على الذرع الأول NH2 إيش بنقول؟ one aminoborben هناك two aminoborben هنا ست ذراته على موقع اتنين", "tokens": [3555, 2655, 30544, 8717, 995, 4587, 9381, 36764, 24401, 5296, 15042, 9122, 29399, 5551, 39648, 9673, 1829, 12984, 9957, 10874, 11622, 38207, 5995, 19, 9673, 1829, 12984, 1211, 3714, 7435, 2304, 2407, 27884, 39894, 1863, 4587, 9381, 36764, 24401, 11778, 16373, 15042, 9673, 7435, 2304, 2407, 27884, 8032, 47302, 18871, 16254, 5551, 2304, 12984, 37977, 34105, 45164, 6156, 7578, 18871, 16254, 50113, 15040, 6055, 1211, 2655, 9122, 9640, 3555, 11536, 9307, 15844, 32545, 2288, 3615, 16247, 12610, 31118, 17, 11933, 1829, 8592, 44945, 39648, 22807, 472, 669, 259, 996, 284, 1799, 34105, 4117, 732, 669, 259, 996, 284, 1799, 34105, 8608, 2655, 29910, 2288, 9307, 3224, 15844, 3714, 30543, 3615, 1975, 2655, 1863, 9957], "avg_logprob": -0.2615489197813946, "compression_ratio": 1.6933333333333334, "no_speech_prob": 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.. الاتنين اخر محاضرة انتوا لسه امتحانكوا التلاتة اللي بعد يعني", "tokens": [15042, 16490, 1211, 9381, 8315, 8592, 16712, 38251, 10632, 39894, 11242, 1211, 4137, 6225, 8592, 7649, 6055, 2288, 26108, 3615, 14407, 28242, 3714, 2407, 11242, 45367, 16712, 38251, 10632, 6156, 1211, 15042, 8717, 46309, 5016, 11296, 39894, 7435, 2304, 3615, 1975, 1829, 8592, 28242, 9673, 2407, 11242, 45367, 44945, 8848, 37983, 8978, 16712, 38251, 10632, 8978, 5551, 12610, 9673, 5016, 46958, 25720, 25062, 18513, 46007, 16472, 13412, 16606, 21984, 20193, 20193, 16472, 13412, 16606, 21984, 7251, 43020, 2423, 4386, 2423, 9307, 1863, 9957, 1975, 34740, 3714, 5016, 46958, 25720, 16472, 2655, 14407, 5296, 3794, 3224, 1975, 2304, 2655, 5016, 7649, 4117, 14407, 16712, 1211, 9307, 3660, 13672, 1829, 39182, 37495, 22653], "avg_logprob": -0.1452287874583687, "compression_ratio": 1.9262672811059909, "no_speech_prob": 0.0, "words": [{"start": 2679.34, "end": 2679.56, "word": "ما", "probability": 0.75390625}, {"start": 2679.56, "end": 2680.32, "word": " خلصناش", "probability": 0.82138671875}, {"start": 2680.32, "end": 2681.08, "word": " التسمية", "probability": 0.9827473958333334}, {"start": 2681.08, "end": 2681.72, "word": " بتضل", "probability": 0.5543619791666666}, {"start": 2681.72, "end": 2682.4, "word": " slide", "probability": 0.66357421875}, {"start": 2682.4, "end": 2682.96, "word": " عشان", "probability": 0.9658203125}, {"start": 2682.96, "end": 2683.44, "word": " تراجعوا", "probability": 0.8431640625}, {"start": 2683.44, "end": 2683.58, "word": " كل", "probability": 0.9814453125}, {"start": 2683.58, "end": 2683.92, "word": " موضوع", "probability": 0.9945068359375}, {"start": 2683.92, "end": 2684.64, "word": " التسمية", "probability": 0.9949544270833334}, {"start": 2684.64, "end": 2685.28, "word": " فلما", "probability": 0.8038736979166666}, {"start": 2685.28, "end": 2685.84, "word": " نشرحها", "probability": 0.9852294921875}, {"start": 2685.84, "end": 2686.44, "word": " بتجمع", "probability": 0.9737548828125}, {"start": 2686.44, "end": 2686.86, "word": " ايش", "probability": 0.78076171875}, {"start": 2686.86, "end": 2687.78, "word": " كل", "probability": 0.6474609375}, {"start": 2687.78, "end": 2688.38, "word": " الموضوع", "probability": 0.9969482421875}, {"start": 2688.38, "end": 2688.88, "word": " بنذكر", "probability": 0.7791341145833334}, {"start": 2688.88, "end": 2689.0, "word": " في", "probability": 0.86083984375}, {"start": 2689.0, "end": 2689.48, "word": " التسمية", "probability": 0.9947916666666666}, {"start": 2689.48, "end": 2689.64, "word": " في", "probability": 0.94384765625}, {"start": 2689.64, "end": 2689.98, "word": " أول", "probability": 0.87353515625}, {"start": 2689.98, "end": 2690.84, "word": " المحاضرة", "probability": 0.9830322265625}, {"start": 2690.84, "end": 2692.2, "word": " القادمة", "probability": 0.9921875}, {"start": 2692.2, "end": 2692.4, "word": " ان", "probability": 0.7607421875}, {"start": 2692.4, "end": 2692.62, "word": " شاء", "probability": 0.986572265625}, {"start": 2692.62, "end": 2693.56, "word": " الله", "probability": 0.95947265625}, {"start": 2693.56, "end": 2696.54, "word": " لا", "probability": 0.461181640625}, {"start": 2696.54, "end": 2696.8, "word": " لا", "probability": 0.64306640625}, {"start": 2696.8, "end": 2697.04, "word": " ان", "probability": 0.88525390625}, {"start": 2697.04, "end": 2697.22, "word": " شاء", "probability": 0.992431640625}, {"start": 2697.22, "end": 2697.32, "word": " الله", "probability": 0.95361328125}, {"start": 2697.32, "end": 2697.66, "word": " يمكن", "probability": 0.98193359375}, {"start": 2697.66, "end": 2698.18, "word": " ال", "probability": 0.66162109375}, {"start": 2698.18, "end": 2698.18, "word": " ..", "probability": 0.48876953125}, {"start": 2698.18, "end": 2698.92, "word": " الاتنين", "probability": 0.86181640625}, {"start": 2698.92, "end": 2699.28, "word": " اخر", "probability": 0.683349609375}, {"start": 2699.28, "end": 2700.04, "word": " محاضرة", "probability": 0.98486328125}, {"start": 2700.04, "end": 2701.58, "word": " انتوا", "probability": 0.8505859375}, {"start": 2701.58, "end": 2701.76, "word": " لسه", "probability": 0.92333984375}, {"start": 2701.76, "end": 2702.26, "word": " امتحانكوا", "probability": 0.8973563058035714}, {"start": 2702.26, "end": 2702.66, "word": " التلاتة", "probability": 0.9073486328125}, {"start": 2702.66, "end": 2702.82, "word": " اللي", "probability": 0.938232421875}, {"start": 2702.82, "end": 2703.08, "word": " بعد", "probability": 0.75537109375}, {"start": 2703.08, "end": 2703.46, "word": " يعني", "probability": 0.85205078125}], "temperature": 1.0}, {"id": 113, "seek": 271646, "start": 2716.18, "end": 2716.46, "text": "أه", "tokens": [10721, 3224], "avg_logprob": -0.17024739583333334, "compression_ratio": 0.3333333333333333, "no_speech_prob": 2.980232238769531e-07, "words": [{"start": 2716.18, "end": 2716.46, "word": "أه", "probability": 0.89990234375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2720.33375, "duration_after_vad": 2624.595968749988}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg.srt
new file mode 100644
index 0000000000000000000000000000000000000000..a54ef1a5085715f8354238b5db04ce9ec34ea4e5
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg.srt
@@ -0,0 +1,1838 @@
+1
+00:00:13,260 --> 00:00:17,620
+اليوم إن شاء الله بنبدأ الفصل الثاني الموضوع اللي 
+
+2
+00:00:17,620 --> 00:00:21,280
+عندنا زي ما أنتو شايفين اللي هي المجموعة الأولى
+
+3
+00:00:21,280 --> 00:00:25,000
+من المجموعات الوظيفية مجموعة الـ alkanes والـ
+
+4
+00:00:25,000 --> 00:00:28,600
+cycloalkanes والحصة الماضية احنا حكينا إن الـ
+
+5
+00:00:28,600 --> 00:00:35,830
+alkanes بيمتازوا إن موجود فيهم رابطة أحادية، الآن إذا
+
+6
+00:00:35,830 --> 00:00:40,730
+بدنا نطلع على تصنيف المركبات العضوية الـ alkanes 
+
+7
+00:00:40,730 --> 00:00:44,990
+حقيقة والـ cycloalkanes يعني المركبات الحلقية يعني
+
+8
+00:00:44,990 --> 00:00:49,750
+يا المركبات بيكون عبارة عن سلسلة مفتوحة يا إما 
+
+9
+00:00:49,750 --> 00:00:54,470
+بيكون عبارة عن حلقة، الحالتين بيكونوا كلهم روابط 
+
+10
+00:00:54,470 --> 00:00:59,950
+أحادية، الآن احنا المركبات اللي بتتكون من الـ
+
+11
+00:00:59,950 --> 00:01:04,950
+hydrogen والـ carbons بيسموها hydrocarbons، الآن الـ
+
+12
+00:01:04,950 --> 00:01:10,090
+hydrocarbons هذه بيقسموها إلى نوعين، إما إنّه تكون 
+
+13
+00:01:10,090 --> 00:01:14,970
+saturated بمعنى مشبعة، معنى saturated إنّ ما فيش 
+
+14
+00:01:14,970 --> 00:01:21,950
+فيها غير روابط وحادية single bonds، وunsaturated 
+
+15
+00:01:21,950 --> 00:01:25,390
+بيكون فيها multiple bonds، multiple bonds يعني
+
+16
+00:01:25,390 --> 00:01:28,830
+يبدوا يكونوا double bond يا triple bond، ما فيش أكثر
+
+17
+00:01:28,830 --> 00:01:34,690
+من هيك يعني يا رابطة زوجية يا رابطة ثلاثية، بشكل عام
+
+18
+00:01:34,690 --> 00:01:39,550
+هناك علاقة ما بين عدد الكربون وعدد الهيدروجين لأي
+
+19
+00:01:39,550 --> 00:01:44,950
+جزء الكان، ليش؟ لأنّ النسبة ثابتة، بمعنى زي ما حكي
+
+20
+00:01:44,950 --> 00:01:48,750
+الحصة الماضية الكربون دايمًا بياخد كام رابطة؟ أربعة،
+
+21
+00:01:48,750 --> 00:01:52,450
+الهيدروجين دايمًا بياخد رابطة، بناءً على ذلك لو بدنا 
+
+22
+00:01:52,450 --> 00:01:57,340
+نعمل أي الكان، بنلاحظ إنّ علاقة الكربون والهيدروجين 
+
+23
+00:01:57,340 --> 00:02:02,820
+نسبة ثابتة، هذه العلاقة هي عبارة عن CnH2n plus 2
+
+24
+00:02:02,820 --> 00:02:09,280
+مثلًا هي عندي أنا جزء عبارة عن كام كربون؟ C2، لما 
+
+25
+00:02:09,280 --> 00:02:14,580
+أقول اتنين في اتنين زائد اتنين، ستة، بتلاحظوا عندكم
+
+26
+00:02:14,580 --> 00:02:20,280
+ست ذرات هيدروجين، هذا جزء الـ E2، لو بدنا نتطلع مثلًا
+
+27
+00:02:20,280 --> 00:02:26,500
+على جزء البروبين، لو بدنا نطلع جزء البروبين عندنا
+
+28
+00:02:26,500 --> 00:02:33,580
+C3H، تقدروا تعدوهم تلاتة واتنين وتلاتة، تمانية، H8
+
+29
+00:02:33,580 --> 00:02:34,940
+فلو قولنا اتنين 
+
+30
+00:02:38,900 --> 00:02:45,480
+الصيغة العامة للالكينز CNH2N، الآن الـ Cycloalkane
+
+31
+00:02:45,480 --> 00:02:52,300
+مش مركبات حلقية، مش مركبات حلقية، مش مركبات مفتوحة
+
+32
+00:02:52,300 --> 00:02:58,070
+مركبات حلقية، بمعنى أنا بدي أشيل، بدي أشيل
+
+33
+00:02:58,070 --> 00:03:02,030
+هيدروجينتين من الألكين يعني عشان أعمل cycle ألكين،
+
+34
+00:03:02,030 --> 00:03:07,650
+عشان أعمل حلقة بدي أشيل هيدروجينتين وأسكر على شكل 
+
+35
+00:03:07,650 --> 00:03:13,740
+حلقة بهذا الشكل، لحظة أنا صار عندي مركب حلقي، أيش 
+
+36
+00:03:13,740 --> 00:03:17,820
+اللي عملته أنا لما سويت حلقة؟ شيلت هيدروجينتين مع 
+
+37
+00:03:17,820 --> 00:03:23,200
+رابطة واضح، فالصيغة العامة للـ Cycloalkanes أيش 
+
+38
+00:03:23,200 --> 00:03:28,180
+بتطلع في هذه الحالة؟ CNH2N، اللي بلفته راحت لأنّ أنا 
+
+39
+00:03:28,180 --> 00:03:32,980
+شيلت هيدروجينتين واضح، فالـ Cycloalkanes هي مثال
+
+40
+00:03:32,980 --> 00:03:37,680
+عليهم، هذا المركب بتكون عبارة عن CNH2N، يعني لما 
+
+41
+00:03:37,680 --> 00:03:43,290
+عندي C3F6، واضح؟ هاي الفرق الـ Cycloalkane على 
+
+42
+00:03:43,290 --> 00:03:48,190
+الـ alkane كصيغة عامة، الآن الـ unsaturated
+
+43
+00:03:48,190 --> 00:03:52,170
+hydrocarbons
+
+44
+00:03:52,170 --> 00:03:57,130
+منهم الـ alkenes، الـ alkenes اللي فيهم double bond، 
+
+45
+00:03:57,130 --> 00:04:00,430
+الآن لاحظوا لو بدي أعمل من هنا alkene يعني بدي
+
+46
+00:04:00,430 --> 00:04:06,000
+أشيل برضه رابطة مع هيدروجينة زي ما عملت في الـ cycle
+
+47
+00:04:06,000 --> 00:04:10,540
+alkane وأتني هذه بشكل معين بحيث أعمل double bond
+
+48
+00:04:10,540 --> 00:04:17,360
+هاي جزء الاثيلين، إذا الـ alkenes برضه عملته من
+
+49
+00:04:17,360 --> 00:04:21,340
+خلال أيش؟ إنّه شيلت هيدروجينتين، إذا أيش الصيغة
+
+50
+00:04:21,340 --> 00:04:25,960
+العامة بتاعتهم؟ CNH2N، بتلاحظوا بهاد الحالة إنّ 
+
+51
+00:04:25,960 --> 00:04:30,220
+الصيغة العامة للـ Cycloalkynes والصيغة العامة للـ
+
+52
+00:04:30,220 --> 00:04:35,140
+Alkenes نفس الشيء، عشان أكون double bond أو عشان 
+
+53
+00:04:35,140 --> 00:04:40,860
+أكون حلقة بيلزمني إن أشيل هيدروجينتين واضح، عشان 
+
+54
+00:04:40,860 --> 00:04:43,480
+أكون double bond أو أكون حلقة بيلزمني أشيل 
+
+55
+00:04:43,480 --> 00:04:48,780
+هيدروجينتين، الآن لو بدي أكون رابطة إضافية triple
+
+56
+00:04:48,780 --> 00:04:54,020
+bond عشان أحصل على الـ alkynes بدي أشيل كمان
+
+57
+00:04:54,020 --> 00:04:58,340
+هيدروجينتين، هي هيدروجينة مع رابطتها وهي الثانية و
+
+58
+00:04:58,340 --> 00:05:03,420
+بعد هيك إذا الـ model بيسمح، طب هيعملنا triple bond
+
+59
+00:05:03,420 --> 00:05:09,440
+واضح؟ إذا لتكوين أي رابطة إضافية بدّه أشيل
+
+60
+00:05:09,440 --> 00:05:12,620
+هيدروجينتين، لتكوين أي حلقة إضافية بدّه أشيل
+
+61
+00:05:12,620 --> 00:05:17,160
+هيدروجينتين، في هذه الحالة لو بدّه اطلع على الـ triple
+
+62
+00:05:17,160 --> 00:05:21,380
+bonds أو الـ alkines لما يكون عند one triple bond
+
+63
+00:05:21,380 --> 00:05:28,570
+شو الصيغة العامة بدها تكون؟ CNH2N-2، بمعنى لما يكون
+
+64
+00:05:28,570 --> 00:05:34,990
+عندي اتنين بدي أقول C2H2X2، أربع ناقص اتنين اتنين
+
+65
+00:05:34,990 --> 00:05:39,550
+إذا هذا المركب اللي هو أبسط الكاين، الاسيتيلين، بدي 
+
+66
+00:05:39,550 --> 00:05:48,510
+يكون C2H2، صيغته العامة CNH2N-2، واضح؟ هذه بالنسبة 
+
+67
+00:05:48,510 --> 00:05:53,930
+للصيغات من الـ hydrocarbons غير المشبعة، الـ aromatic
+
+68
+00:05:53,930 --> 00:05:57,070
+compounds اللي هم المركبات اللي زي البنزين اللي 
+
+69
+00:05:57,070 --> 00:06:01,590
+فيهم حلقة وعدة double bonds واضح؟ وهذول بناخدهم
+
+70
+00:06:01,590 --> 00:06:09,170
+احنا بفصل كامل اللي هو الفصل الرابع بنرجع لهم، الآن
+
+71
+00:06:09,170 --> 00:06:14,310
+لو اجينا نتعرف على الـ alkanes وأشكالها بنلاحظ إنّه
+
+72
+00:06:14,310 --> 00:06:20,090
+احنا ممكن يكون عندنا carbon اتنين تلاتة أربعة خمسة
+
+73
+00:06:20,090 --> 00:06:24,950
+العدد عندنا مفتوح، العدد عندنا مفتوح، لو عندنا one
+
+74
+00:06:24,950 --> 00:06:30,450
+carbon وبيكون المركب اسمه methane، وحسب القاعدة 
+
+75
+00:06:30,450 --> 00:06:33,950
+التسمية اللي .. حسب قاعدة العدد اللي أخدناها
+
+76
+00:06:33,950 --> 00:06:39,370
+الصيغة شو بدها تكون؟ CH4، carbon اتنين بيصير المركب 
+
+77
+00:06:39,370 --> 00:06:48,230
+اثان، تلاتة بروبان، أربعة بيوتان، خمسة هكسان
+
+78
+00:06:48,230 --> 00:06:54,370
+السبعة هبتان، التمانية أوكتان، التسعة نونان، والعشرة
+
+79
+00:06:54,370 --> 00:06:59,440
+ديكان واضح؟ الآن هذه المركبات بهذه الأسماء هي 
+
+80
+00:06:59,440 --> 00:07:04,280
+لمركبات الـ carbons تبعتها متسلسلة ورا بعض، الآن 
+
+81
+00:07:04,280 --> 00:07:07,660
+ممكن يصير عندي تفرعات، بتصير مركبات جديدة، يعني
+
+82
+00:07:07,660 --> 00:07:12,700
+لما أحط مثلًا set carbonate ورا بعض ع شكل سلسلة 
+
+83
+00:07:12,700 --> 00:07:16,600
+chain، هذا الـ hexane، الآن أنا ممكن أحط أربعة أو 
+
+84
+00:07:16,600 --> 00:07:20,480
+أعمل تفرع اتنين، بيصير مركب جديد، بنتعلم تسميته،
+
+85
+00:07:20,480 --> 00:07:26,450
+فهذه الأسماء للسلاسل المستقيمة، للسلاسل المستقيمة 
+
+86
+00:07:26,450 --> 00:07:31,210
+حقيقة هذه السلاسل برسموها على الشكل اللي بيسموه
+
+87
+00:07:31,210 --> 00:07:35,810
+الـ zigzag بتعرفوا الـ zigzag؟ في الخياطة بيعملوا 
+
+88
+00:07:35,810 --> 00:07:41,370
+غرزة zigzag هيك يعني، هي الـ zigzag هذا
+
+89
+00:07:41,370 --> 00:07:45,470
+الشكل zigzag يعني مش متعودين نعمله المركب زي هيك
+
+90
+00:07:45,470 --> 00:07:48,650
+بهذا الخط، لأ، في الـ organ chemistry بنعمل zigzag 
+
+91
+00:07:48,650 --> 00:07:52,190
+بين كل carbon والتانية، ولو أنتو حقيقة بتكونوا
+
+92
+00:07:52,190 --> 00:07:59,020
+اتلاحظوا Okay، هذا الشكل اللي هو الـ zigzag أو الشكل
+
+93
+00:07:59,020 --> 00:08:02,660
+المتعرج ودايمًا لما بدكوا ترسم على لو بدكوا تعملوا 
+
+94
+00:08:02,660 --> 00:08:08,220
+عشرة carbons بدكوا تمشوا بهذا الشكل واضح؟ بهذا
+
+95
+00:08:08,220 --> 00:08:08,660
+الشكل 
+
+96
+00:08:11,800 --> 00:08:15,880
+شغلة جديدة اللي هي الـ alkyl groups أو مجموعات الـ
+
+97
+00:08:15,880 --> 00:08:21,020
+alkyl، الآن كل جزء organic له شكل له عدد من الـ
+
+98
+00:08:21,020 --> 00:08:26,260
+carbons له عدد من الـ hydrogens، لو أي جزء من جزيئات
+
+99
+00:08:26,260 --> 00:08:31,220
+الـ organic شيلنا منه hydrogen واحدة، هذه الهيدروجين
+
+100
+00:08:31,220 --> 00:08:35,400
+هنشلناها شفتوها بيصير عند مجموعة الكل اش اللي
+
+101
+00:08:35,400 --> 00:08:40,300
+بقصده أنا بمجموعة الكل، مجموعة ممكن تركب أو تتحد في
+
+102
+00:08:40,300 --> 00:08:44,360
+أي مكان تاني، محل ما كانت متصلة مع الهيدروجين ممكن
+
+103
+00:08:44,360 --> 00:08:49,880
+تتحد مع شيء تاني، يعني لو مثلًا افترضت إنّه هذه ذرة
+
+104
+00:08:49,880 --> 00:08:54,940
+كلور ممكن تيجي هذه المجموعة الكل تتحد هنا مع الكلور
+
+105
+00:08:54,940 --> 00:09:01,650
+تتكون جزء مع إيش؟ مع الكلور، الآن الجزء أصلاً إيش كان 
+
+106
+00:09:01,650 --> 00:09:08,450
+اسمه وكلّه ملان هيدروجين؟ كان اسمه ميثان، الجزء هذا
+
+107
+00:09:08,450 --> 00:09:13,490
+أيّش كان اسمه؟ ميثان، الآن لما هذا الجزء احنا بنشيل
+
+108
+00:09:13,490 --> 00:09:18,030
+منه هيدروجين بتصير المجموعة اسمها مثل، إذا ميثان
+
+109
+00:09:18,030 --> 00:09:28,160
+بيعطيني مثل، طب لو شبكة هذه مثل مع كلور بصير مثل أو
+
+110
+00:09:28,160 --> 00:09:31,900
+كلورو ميثان، بالـ Iobacnium هناخد التسمية، واضح؟
+
+111
+00:09:31,900 --> 00:09:36,220
+إذا هذه الـ CH3 مش الـ CH4، شو بيصير اسمها 
+
+112
+00:09:36,220 --> 00:09:42,780
+كمجموعة؟ مثل، إذا الميثان بيعمل مجموعة المثل،
+
+113
+00:09:42,780 --> 00:09:47,320
+واضح؟ لما نشيل منه هيدروجينة، الآن بنفس الطريقة لو
+
+114
+00:09:47,320 --> 00:09:53,470
+إجينا طلعنا على الـ إيثان، لو شيلنا منه هيدروجينة بدل
+
+115
+00:09:53,470 --> 00:10:01,730
+C2H6 أو C3H3 بيصير CH3CH2، بينخص منه هيدروجينة، هذا 
+
+116
+00:10:01,730 --> 00:10:06,650
+إثن، المجموعة اللي بتطلع منه إيش اسمها؟ إثل واضح 
+
+117
+00:10:06,650 --> 00:10:12,890
+المجموعة اللي بتطلع منه إثل، الأمور للأسف ما بتضلش ..
+
+118
+00:10:12,890 --> 00:10:17,270
+ما بتضلش خليني أقول سهلة كثير .. ما بتضلش سهلة 
+
+119
+00:10:17,270 --> 00:10:22,390
+كثير، يعني مجرد ما بنصل لجزء البروبان بنلاقي إنّه 
+
+120
+00:10:22,390 --> 00:10:27,450
+بيبدأ يصير عندنا إشكالية، شو الإشكالية اللي بتبدأ 
+
+121
+00:10:27,450 --> 00:10:31,850
+تصير عندي لما أصل لجزء البروبان؟ بدي أشيل هيدروجينة 
+
+122
+00:10:31,850 --> 00:10:35,530
+بلاحظ إنّه الهيدروجين اللي في البروبان نوعين، هدول
+
+123
+00:10:35,530 --> 00:10:39,670
+التلاتة وهدول التلاتة زي بعض، بمعنى لو شيلت أي
+
+124
+00:10:39,670 --> 00:10:44,310
+هيدروجينة من هان، لو شيلت أي هيدروجينة من هذا الطرف 
+
+125
+00:10:44,310 --> 00:10:48,130
+وكنت بدي أشبكها بـ chlorine اتطلعوا معاكي كيف الجزء 
+
+126
+00:10:48,130 --> 00:10:54,650
+بيشبك من الطرف، carbon اتنين تلاتة، الآن طيب لو
+
+127
+00:10:54,650 --> 00:11:01,070
+شيلنا هيدروجينة مش من الطرف هذا من النص، بيصير جزء 
+
+128
+00:11:01,070 --> 00:11:05,330
+تاني، بيصير جزء تاني، اتطلعوا كيف صار متحد مع الـ
+
+129
+00:11:05,330 --> 00:11:09,690
+chlorine مثلًا، واضح؟ إذا في حالة البروبان أنا 
+
+130
+00:11:09,690 --> 00:11:12,570
+بإمكاني أشيل الهيدروجين من هذا الطرف وبإمكاني 
+
+131
+00:11:12,570 --> 00:11:15,750
+أشيل الهيدروجين من النص، طبعًا من الطرف هذا زي هذا 
+
+132
+00:11:15,750 --> 00:11:19,350
+فإذا شيلنا من الطرف هذا بنعمل المجموعة اللي 
+
+133
+00:11:19,350 --> 00:11:23,890
+بنسميها بروبيل، ومرات بيحطوا قدامها n بروبيل يعني 
+
+134
+00:11:23,890 --> 00:11:30,070
+normal بروبيل، بروبيل عادي، عبارة عن CH2CH2CH3، ولو
+
+135
+00:11:30,070 --> 00:11:34,630
+شيلنا الهيدروجينة من النص بيعمل مجموعة isopropyl، 
+
+136
+00:11:34,630 --> 00:11:37,850
+بيكون الاتصال تبع الـ isopropyl من أي كربون؟ من 
+
+137
+00:11:37,850 --> 00:11:43,370
+التلاتة الكربونات الوسطانية، مش الطرفية، واضح؟ إذا
+
+138
+00:11:43,370 --> 00:11:49,490
+البروبان له مجموعتين الكل اش هما البروبيل إذا اتصل
+
+139
+00:11:49,490 --> 00:11:55,970
+من الطرف، و isopropyl إذا اتصل من النص، الآن لو 
+
+140
+00:11:55,970 --> 00:12:02,720
+الأمور كبرت شوية صار في عندنا لبيوتان، لبيوتان 
+
+141
+00:12:02,720 --> 00:12:08,500
+مشكلته شوية .. مشكلته شوية أكبر، ليش بيوتان مشكلته 
+
+142
+00:12:08,500 --> 00:12:14,560
+أكبر؟ أساسًا أول ما باجي بدي أشيل هيدروجينة من 
+
+143
+00:12:14,560 --> 00:12:19,300
+بيوتان عشان أحط بدالها الكربونة الرابعة، مش هو تلت 
+
+144
+00:12:19,300 --> 00:12:22,940
+كربونات؟ بدي أخليه أربعة، أول ما بدي أجي أشيل
+
+145
+00:12:22,940 --> 00:12:28,800
+هيدروجينة ممكن أشيل من هان، وبالتالي الكربونات اللي 
+
+146
+00:12:28,800 --> 00:12:35,100
+عندي يكونوا ماخدين شكل السلسلة الـ chain ورا بعض 
+
+147
+00:12:35,100 --> 00:12:40,140
+جايين بدون تفرع، واحد، اتنين، تلاتة، أربعة، واضح؟
+
+148
+00:12:40,140 --> 00:12:45,940
+هذا مركب، لكن لو افترضنا مثلًا إنّه احنا شيلنا هذه
+
+149
+00:12:45,940 --> 00:12:48,320
+الهيدروجينة وحطينا بدلها كربون
+
+150
+00:12:51,680 --> 00:12:55,460
+برضه دول أربع كربونات، لكن هذا شكل مختلف، هذا صار
+
+151
+00:12:55,460 --> 00:13:01,000
+branched molecule، أيش يعني branched؟ متفرع، إذا 
+
+152
+00:13:01,000 --> 00:13:06,960
+البيوتان أصلاً في منه مركبين، المركب مش المجموعات 
+
+153
+00:13:06,960 --> 00:13:10,680
+المركب نفسه البيوتان في منه اتنين، إما بيكون على 
+
+154
+00:13:10,680 --> 00:13:15,540
+شكل a chain compound، a chain يعني إيه؟ على شكل
+
+155
+00:13:15,540 --> 00:13:20,040
+سلسلة، ويا إما بيكون branched، إيه كربون اتنين تلاتة؟
+
+156
+00:13:20,130 --> 00:13:25,790
+أربعة، الـ chain compound بنسميه بيوتان، الـ branch 
+
+157
+00:13:25,790 --> 00:13:32,230
+بنسميه ايزو بيوتان، واضح؟ إذا من مركب البيوتان نفسه
+
+158
+00:13:32,230 --> 00:13:36,530
+من مركب البيوتان نفسه أنا في عندي كام مركب؟ اتنين 
+
+159
+00:13:36,530 --> 00:13:40,710
+اللي هم الـ chain والـ branch، البيوتان وايزو 
+
+160
+00:13:40,710 --> 00:13:47,450
+بيوتان، الآن لما نيجي بدنا نعمل الكلي جروبز بنلاحظ
+
+161
+00:13:47,450 --> 00:13:52,190
+إنّه الـ بيوتان الأربعة ممكن تفقد هيدروجينة من هنا 
+
+162
+00:13:52,190 --> 00:13:56,850
+يعطيني مجموعة وممكن من هنا كمان يعطيني مجموعة، إذا 
+
+163
+00:13:56,850 --> 00:14:01,630
+فقدت الهيدروجينة من هنا بيصير عندي الـ product اسمه 
+
+164
+00:14:01,630 --> 00:14:08,910
+normal butyl group أو butylig group، واضح؟ لو حطيت
+
+165
+00:14:08,910 --> 00:14:14,730
+كلور هنا على الطرف بيصير butylchloride، واضح؟ لكن لو
+
+166
+00:14:14,730 --> 00:14:19,390
+فقدت الهيدروجينة من الموقع الثاني بنسمي الـ group
+
+167
+00:14:19,390 --> 00:14:2
+
+201
+00:17:20,850 --> 00:17:27,670
+مجموعة الـ ISO واضح؟ إذا هي الـ ISO group الـ ISO
+
+202
+00:17:27,670 --> 00:17:34,090
+butyl طيب لو شيلنا من النص الـ hydrogen لاحظوا
+
+203
+00:17:34,090 --> 00:17:38,630
+بيصير عندي carbon حاملة CH3 CH3 CH3 هذه مجموعة
+
+204
+00:17:38,630 --> 00:17:44,590
+كبيرة شايفين كيف؟ لو اتصلت بـ chlor بيصير المركب طيب
+
+205
+00:17:44,590 --> 00:17:48,610
+هذه المجموعة كلها كـ group شو بسميها أنا؟ Tertiary
+
+206
+00:17:48,610 --> 00:17:52,510
+Butyl لو اتحدت مع الكلور و جيبنالكم هذا المركب
+
+207
+00:17:52,510 --> 00:17:58,430
+قولنالكم إيش اسمه تيرتشاري بيوتل كل هذا الكربون
+
+208
+00:17:58,430 --> 00:18:03,430
+اللي حاملة تلاتة CH3 اسمها إيش تيرتشاري بيوتل لو
+
+209
+00:18:03,430 --> 00:18:10,550
+اتحدت مع الكلور تيرتشاري بيوتل كلوريد إذا حقيقة
+
+210
+00:18:10,550 --> 00:18:14,310
+من البيوتين بشقيها اللي هو البيوتين العادي و
+
+211
+00:18:14,310 --> 00:18:19,150
+الايزوبيوتين اكملك الـ group في عندي أربعة عند
+
+212
+00:18:19,150 --> 00:18:26,290
+بيوتل وسيكندر بيوتل من المركب لتشين وعندي ايزو بيوتل
+
+213
+00:18:26,290 --> 00:18:31,190
+و تيرتشر بيوتل من المركب لبرانشت هذه المجموعات
+
+214
+00:18:31,190 --> 00:18:35,650
+كلها المفروض أي طالب organic يكون إيش حافظها تماما
+
+215
+00:18:35,650 --> 00:18:40,850
+لأنه دائما بنسأل عنها يعني ممكن نجيب حلقة بنزين
+
+216
+00:18:40,850 --> 00:18:45,510
+على سبيل المثال متصلة فيها هذه المجموعة وقتها شو
+
+217
+00:18:45,510 --> 00:18:51,250
+بنسمي المركب؟ Tertiary-butylbenzene يعني لو إن
+
+218
+00:18:51,250 --> 00:18:56,190
+اتخيلت إن هنا حطيت حلقة بنزين زي هيك هي صار مركب
+
+219
+00:18:56,190 --> 00:19:01,590
+لما بدي اسميه لو كنت أنا حاطط بس كلور بسميه
+
+220
+00:19:01,590 --> 00:19:05,250
+chlorobenzene طب لما أحط هذه المجموعة كلها شو
+
+221
+00:19:05,250 --> 00:19:09,210
+بيصير اسمه tertiary-butylbenzene لو حطيت هنا
+
+222
+00:19:09,210 --> 00:19:13,270
+البنزين شو بيصير اسمه المركب isobutylbenzene لو
+
+223
+00:19:13,270 --> 00:19:19,030
+حطيته هنا isopropylbenzene لو حطيته هنا ethyl
+
+224
+00:19:19,030 --> 00:19:25,730
+benzene واضح الفكرة كيف؟ فهذه مجموعات الـ alkyl حقيقة
+
+225
+00:19:25,730 --> 00:19:30,390
+بدكم تكونوا حافظينها بشكل ممتاز 
+
+226
+00:19:33,570 --> 00:19:38,570
+هذه الـ alkanes البسيطة اللي احنا اتعرفنا عليها طب لو
+
+227
+00:19:38,570 --> 00:19:44,130
+كبر المركب بدنا طريقة عامة لتسمية أي مركب كبير
+
+228
+00:19:44,130 --> 00:19:48,230
+اللي هي Nomenclature of Substituted Alkanes
+
+229
+00:19:48,230 --> 00:19:52,530
+Nomenclature دائما إيش بتيجي .. تسمية المركبات
+
+230
+00:19:52,530 --> 00:19:57,830
+العضوية أو الـ alkanes الكبيرة عشان أسمي أي ألكين
+
+231
+00:19:57,830 --> 00:20:02,610
+المفروض أطلع على الـ carbons تعوني الألكين وأبحث
+
+232
+00:20:02,610 --> 00:20:09,130
+إلى أن أحصل على أطول سلسلة ذرات كربون، واضح؟ مثلا
+
+233
+00:20:09,130 --> 00:20:12,090
+في هذا المركب لو أطلعت أي واحد، اثنين، ثلاثة،
+
+234
+00:20:12,090 --> 00:20:17,140
+أربعة، خمسة، هذه الحمرة سلسلة إيش؟ الكربون، إذا
+
+235
+00:20:17,140 --> 00:20:20,960
+المركب اللي عندي مشتق من الخمسة، الخمسة عبارة عن
+
+236
+00:20:20,960 --> 00:20:25,760
+إيش؟ بنتين، بنتين، فالمركب اللي عندي هو مشتقة
+
+237
+00:20:25,760 --> 00:20:29,180
+بنتين، الآن الـ substituents اللي موجودة إيه لها
+
+238
+00:20:29,180 --> 00:20:35,300
+اسمها؟ الـ chlor اسمه chloro، الـ brom إيه اسمه؟ الـ
+
+239
+00:20:35,300 --> 00:20:41,640
+CH3 مثل الـ CH اللي متصلة ببنتين CH3 تو اتعلمناها
+
+240
+00:20:42,940 --> 00:20:48,720
+eyes of rubel على سبيل المثال فبنذكر المجموعات و
+
+241
+00:20:48,720 --> 00:20:52,660
+لما يكونوا أكثر من نوع بنذكرهم alphabetically
+
+242
+00:20:52,660 --> 00:20:59,400
+بمعنى الـ a قبل الـ b قبل الـ c قبل الـ d واضح لما
+
+243
+00:20:59,400 --> 00:21:03,680
+نيجي نرتب ذكر المجموعات هذا بنتين متصل في كم
+
+244
+00:21:03,680 --> 00:21:07,860
+مجموعة؟ بنتين brom و chlorine مين اللي بدي أذكره
+
+245
+00:21:07,860 --> 00:21:11,690
+في الأول الـ brom ولا الـ chlorine؟ للبروم طيب لما بدي
+
+246
+00:21:11,690 --> 00:21:16,010
+أحدد الموقع بدي أرقم و هنا بتجينا دائما مشكلة إن
+
+247
+00:21:16,010 --> 00:21:20,110
+أنا بقدر أقول الواحد من هذا الطرف أو من هذا الطرف
+
+248
+00:21:20,110 --> 00:21:23,890
+يعني ممكن أقول واحد اثنين ثلاثة أربعة خمسة وممكن
+
+249
+00:21:23,890 --> 00:21:29,470
+أقول واحد اثنين ثلاثة أربعة خمسة دائما في الـ
+
+250
+00:21:29,470 --> 00:21:32,910
+organic بنقول بنستعمل قاعدة الـ lower numbering
+
+251
+00:21:32,910 --> 00:21:39,070
+يعني لازم أحصل على أقل ترقيم فلاحظوا لو بدأت من هنا
+
+252
+00:21:39,070 --> 00:21:43,410
+الكلور ع اثنين والبروم ع ثلاثة اثنين وثلاثة خمسة
+
+253
+00:21:43,410 --> 00:21:46,730
+كمجموع لو بدأت من هنا واحد اثنين ثلاثة أربعة
+
+254
+00:21:46,730 --> 00:21:50,410
+البروم ع ثلاثة والكلور ع أربعة ثلاثة وأربعة سبعة
+
+255
+00:21:50,410 --> 00:21:54,770
+إذا إن أقل ترقيم الترقيم اللي احنا عاملينه من هنا
+
+256
+00:21:54,770 --> 00:22:00,050
+بناء على ذلك هذا المركب لما نشوف اسمه كاملا بيصير
+
+257
+00:22:00,050 --> 00:22:07,080
+three bromo two chlorobentane كلمة واحدة بدون ما
+
+258
+00:22:07,080 --> 00:22:09,880
+نقطع فراغات بينها لو كنا بنطبع على الكمبيوتر و
+
+259
+00:22:09,880 --> 00:22:16,660
+بنكتب بالإيد ودائما قبل الرقم بعده بنحط dash إذا
+
+260
+00:22:16,660 --> 00:22:21,760
+هذا المركب three promo two cloro بنتين وتكتب
+
+261
+00:22:21,760 --> 00:22:26,960
+ككلمة واحدة ودائما قبلها بعد الرقم dash ما لم يكن
+
+262
+00:22:26,960 --> 00:22:30,740
+في البداية بس بيكون إيش الـ dash بعده نعد من هنا
+
+263
+00:22:30,740 --> 00:22:37,020
+واحد اثنين ثلاثة بمشي واحد اثنين ثلاثة أربعة خمسة
+
+264
+00:22:37,020 --> 00:22:41,660
+بدا تتعب ممكن تعد من هنا واحد اثنين ثلاثة أربعة
+
+265
+00:22:41,660 --> 00:22:45,680
+خمسة لما نعمل أكثر من محاولة بنلاحظ إن هو أطول
+
+266
+00:22:45,680 --> 00:22:50,800
+السلسلة واحد اثنين ثلاثة أربعة خمسة ستة سبعة إذا
+
+267
+00:22:50,800 --> 00:22:57,280
+المركب اللي عندي مشتقة السبعة هبتين هبتين متصل في
+
+268
+00:22:57,280 --> 00:23:03,720
+مجموعة مثل ومجموعة مثل ثانية أقل ترقيم بيخلينا نرقم
+
+269
+00:23:03,720 --> 00:23:07,600
+من هنا مش من هنا لما يكون مجموعتين مثل إيش
+
+270
+00:23:07,600 --> 00:23:15,570
+بنستعمل لهم؟ die لو كانوا ثلاثة أربعة تترا خمسة بنتة
+
+271
+00:23:15,570 --> 00:23:20,810
+هكسة هبتة واضح إذا هذا وبنحدد مكانهم بنقول على
+
+272
+00:23:20,810 --> 00:23:25,370
+اثنين وعلى أربعة عندي مجموعتين مثل فلما بدي أحط
+
+273
+00:23:25,370 --> 00:23:33,010
+الاسم بقول two فاصلة كلمة four داش دائما بين الرقم
+
+274
+00:23:33,010 --> 00:23:37,310
+والاسم dimethyl heptane إذا هذا المركب two four
+
+275
+00:23:37,310 --> 00:23:38,370
+dimethyl
+
+276
+00:23:43,280 --> 00:23:49,260
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+277
+00:23:49,260 --> 00:23:50,120
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+278
+00:23:50,120 --> 00:23:53,500
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+279
+00:23:53,500 --> 00:23:56,620
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+280
+00:23:56,620 --> 00:24:02,520
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+281
+00:24:02,520 --> 00:24:10,940
+تختار أطول سلسلة تختار أبرضه إذا جرينا وراء أطول
+
+282
+00:24:10,940 --> 00:24:14,160
+سلسلة واحد، اثنين، ثلاثة، أربعة، خمسة، ستة، سبعة
+
+283
+00:24:14,160 --> 00:24:17,760
+ممكن ننظر احتمالات ثانية بنلاقيهم أقل، بنلاقيهم
+
+284
+00:24:17,760 --> 00:24:21,780
+أقل، إذا المركب اللي عندي سبعة إيش بيحمل على موقع
+
+285
+00:24:21,780 --> 00:24:28,060
+اثنين؟ مثل، على موقع خمسة؟ isopropyl، مين جاب الـ
+
+286
+00:24:28,060 --> 00:24:32,100
+alphabeticalيه؟ الـ isopropyl، إذا four على موقع
+
+287
+00:24:32,100 --> 00:24:37,120
+أربعة هان عفوا، four isopropyl, two methyl, هبتين
+
+288
+00:24:37,540 --> 00:24:44,380
+واضح؟ هذه هي طريقة التسمية أحيانا بتجينا إشكالية
+
+289
+00:24:44,380 --> 00:24:49,220
+صغيرة إن لما نيجي نفتش على أطول سلسلة في مركب
+
+290
+00:24:49,220 --> 00:24:55,160
+بنلاحظ إن ممكن يكون عنده نفس الطول جاي باتجاهين
+
+291
+00:24:55,160 --> 00:24:59,220
+مختلفين يعني لاحظوا هذا المركب نفسه وهذا المركب
+
+292
+00:24:59,220 --> 00:25:04,100
+نفسه وهذا المركب واضح؟ لما نيجي نعد من هنا واحد،
+
+293
+00:25:04,100 --> 00:25:07,940
+اثنين، ثلاثة، أربعة، خمسة، ستة، سبعة، هاي سلسلة
+
+294
+00:25:07,940 --> 00:25:14,000
+طولها سبعة، كم تفرع طالع منها؟ اثنين طيب لو عدينا
+
+295
+00:25:14,000 --> 00:25:17,300
+من هان، واحد، اثنين، ثلاثة، أربعة، خمسة، ستة،
+
+296
+00:25:17,300 --> 00:25:24,200
+سبعة، برضه سبعة، بصير كيف بدي اخذ؟ هادي السبعة ولا
+
+297
+00:25:24,200 --> 00:25:29,360
+هادي السبعة؟ وهنا في السابعة هذه منها تفرع واحد
+
+298
+00:25:29,360 --> 00:25:33,640
+فالقاعدة بتقولنا if there are two equally long
+
+299
+00:25:33,640 --> 00:25:37,820
+continuous chains it choose the one with most
+
+300
+00:25:37,820 --> 00:25:42,360
+branches اختار اللي فيها تفرعات أكثر هذه كم تفرع
+
+301
+00:25:42,360 --> 00:25:49,080
+طالع منها اثنين هذه كم تفرع طالع منها واحد واضح؟
+
+302
+00:25:49,080 --> 00:25:54,950
+إذا بنطلع احنا على هدول المركبين نفس طول السلسلة
+
+303
+00:25:54,950 --> 00:26:01,210
+سبعة وسبعة إذا تساوى طول السلسلة ما الحكم؟ عدد
+
+304
+00:26:01,210 --> 00:26:06,090
+التفرعات اللي أكثر تفرع هو اللي بنختاره ولذلك هذا
+
+305
+00:26:06,090 --> 00:26:11,430
+المركب لما نيجي نسميه في مجموعة مثل ومجموعة إيثل
+
+306
+00:26:11,430 --> 00:26:17,030
+والترقيم من هنا أنهي اللي بتذكره في الأول الـ إيثل إذا
+
+307
+00:26:17,030 --> 00:26:23,070
+عندي three إيثل two مثل هبتين ما بجيش أسميه هنا لو
+
+308
+00:26:23,070 --> 00:26:26,830
+اتخيلت إن هذه مجموعة واحدة isopropyl three
+
+309
+00:26:26,830 --> 00:26:31,730
+isopropyl هبتين كان ممكن واحدة أول ما يجي على بالها
+
+310
+00:26:31,730 --> 00:26:34,610
+تطلع زي هيك وتقولها يحمل مجموعة وحافظة
+
+311
+00:26:34,610 --> 00:26:38,430
+المجموعة isopropyl تسميها isopropyl heptane هذه
+
+312
+00:26:38,430 --> 00:26:43,650
+التسمية تعتبر تسمية خاطئة المركب بهذا الشكل بناخد
+
+313
+00:26:43,650 --> 00:26:52,000
+التفرعات الأكثر واضح بعد هذه المقدمة عن تسميات الـ
+
+314
+00:26:52,000 --> 00:26:56,680
+alkanes بننتقل إلى دراسة بعض الـ physical
+
+315
+00:26:56,680 --> 00:27:00,980
+properties للـ alkanes الخاصية الأولى الـ water
+
+316
+00:27:00,980 --> 00:27:05,240
+solubility الذوبان في الميه كلكم بتعرفوا البنزين
+
+317
+00:27:05,240 --> 00:27:10,320
+لو أخذنا بنزين السيارة على الميه ما بخلطش insoluble
+
+318
+00:27:10,320 --> 00:27:13,760
+واضح إذا الـ alkanes they are water insoluble شو
+
+319
+00:27:13,760 --> 00:27:21,840
+السبب؟ اللي هو إن البنزين وغيره وكل المركبات بنطبق
+
+320
+00:27:21,840 --> 00:27:27,160
+عليها قاعدة ذائبية like dissolve like يعني الـ
+
+321
+00:27:27,160 --> 00:27:30,060
+polar compounds دي are soluble in polar compounds
+
+322
+00:27:30,060 --> 00:27:33,260
+الـ non polar compounds in non polar compounds الآن
+
+323
+00:27:33,260 --> 00:27:37,060
+الـ alkenes دي are non polar لا فيهم hydrogen
+
+324
+00:27:37,060 --> 00:27:39,720
+bonding ولا إشي شو القوة اللي بتحكمهم زي ما حكت
+
+325
+00:27:39,720 --> 00:27:44,900
+زميلاتكم؟ اللي هي الـ London forces أو الـ Vanderwaals
+
+326
+00:27:44,900 --> 00:27:49,540
+forces هي اللي مربطاهم البعض وهذه قوة ضعيفة ولذلك
+
+327
+00:27:49,540 --> 00:27:53,320
+برضه الـ Alkanes هتلاحظوا ملاحظة إن نقاط غليانها
+
+328
+00:27:53,320 --> 00:27:58,400
+منخفضة لأن ارتباطها ضعيف يعني مثلا الـ methane يمكن
+
+329
+00:27:58,400 --> 00:28:03,500
+عند ناقص 168 بيغلي عبارة عن غاز الـ ethane غاز الـ
+
+330
+00:28:03,500 --> 00:28:10,140
+probane غاز الـ butane غاز بالمناسبة الميثين ..
+
+331
+00:28:10,140 --> 00:28:13,060
+الميثين عشان أنتم ما تخربطوش برضه وتتعلموا هذه
+
+332
+00:28:13,060 --> 00:28:18,360
+المعلومة الميثين هو الغاز الطبيعي بنسميه natural
+
+333
+00:28:18,360 --> 00:28:24,220
+gas وهذا الغاز الطبيعي بشكل عام بمشوب أنبوبة
+
+334
+00:28:24,220 --> 00:28:28,860
+عملية اسالته وتعبئته بإسطوانات زي الإسطوانات
+
+335
+00:28:28,860 --> 00:28:33,700
+المنزلية عملية صعبة واضح؟ بده تقنيات صعبة جدا، مش
+
+336
+00:28:33,700 --> 00:28:38,140
+هو الغاز اللي بيجينا في قنانيب الغاز، الميثين مش
+
+337
+00:28:38,140 --> 00:28:41,220
+هو الغاز اللي بيجينا في قنانيب الغاز، يمكن الميثين
+
+338
+00:28:41,220 --> 00:28:46,240
+هو الغاز اللي مصر بتبيعه لإسرائيل بس نفسه ماحدش
+
+339
+00:28:46,240 --> 00:28:48,800
+يجي يقول عبوا .. عبوا لنا يا أف قنانيب غاز مش هو
+
+340
+00:28:48,800 --> 00:28:52,220
+هذا الغاز تبع القنانيب الغاز بيشغلوا فيه محطات
+
+341
+00:28:52,220 --> 00:28:56,140
+توليد وجايبينه بقنانيب معينة وكل شيء هذا اللي هو
+
+342
+00:28:56,140 --> 00:29:01,060
+الـ natural gas الميثين لكن الغاز تبعنا وبيطلع من
+
+343
+00:29:01,060 --> 00:29:04,940
+التخمر بالمناسبة الميثين يعني الفضلات العضوية و
+
+344
+00:29:04,940 --> 00:29:09,870
+غيرها بتعرفوا الـ bio gases وجزء الـ energy طريقة من
+
+345
+00:29:09,870 --> 00:29:13,350
+خلال تخمير الفضلات إن نحصل على الميثين ونحصل على
+
+346
+00:29:13,350 --> 00:29:18,550
+الـ energy لكن الغاز المنزلي هو عبارة عن خليط من
+
+347
+00:29:18,550 --> 00:29:24,840
+البروبين والبيوتين فهو غاز بترولي شفتوا الفرق بين
+
+348
+00:29:24,840 --> 00:29:29,340
+الغاز الطبيعي والغاز البترولي، الميثين والبروبيني،
+
+349
+00:29:29,340 --> 00:29:32,940
+عفوا، البروبين والبيوتين اللي بتعبوا في الإسطوانات
+
+350
+00:29:32,940 --> 00:29:37,120
+وياسلوا بسهولة وبنضغطوا في الإسطوانة بسهولة اللي
+
+351
+00:29:37,120 --> 00:29:42,200
+هم الغاز البترولي اللي بيجي عندنا من عند البنتين
+
+352
+00:29:42,200 --> 00:29:47,020
+بيبدأ المركب يصير سائل لكن سهل التطاير بنتين،
+
+353
+00:29:47,020 --> 00:29:51,080
+هكسين، هبتين، لاحظوا بنزين السيارات دائما بنقول
+
+354
+00:29:51,080 --> 00:29:56,480
+عنه إيش؟ متطاير جدا، هو هكسين وهبتين إيش كل قصة
+
+355
+00:29:56,480 --> 00:30:01,480
+التطاير اللي موجودة في الـ Alcans؟ إيش سببها؟ إن
+
+356
+00:30:01,480 --> 00:30:05,940
+الروابط اللي فيه ضعيفة هي London Forces واضح؟ كل
+
+357
+00:30:05,940 --> 00:30:10,910
+قصة الارتباطات اللي .. لضعيفة في الـ alkanes هي اللي
+
+358
+00:30:10,910 --> 00:30:16,510
+بتأدي لـ boiling points منخفضة، إذا الـ alkanes لهم
+
+359
+00:30:16,510 --> 00:30:21,360
+low boiling point which increases upon increasing
+
+360
+00:30:21,360 --> 00:30:24,340
+the number of carbons in the alkane وهذا كلام منطق
+
+361
+00:30:24,340 --> 00:30:27,760
+إن الـ alkane بـ carbon واحدة بيكون الـ boiling
+
+362
+00:30:27,760 --> 00:30:31,120
+point أقل كتير من الـ alkane اللي بـ 7 carbons اللي
+
+363
+00:30:31,120 --> 00:30:34,720
+بـ 7 carbons سائل اللي بـ carbon واحدة الـ methane
+
+364
+00:30:34,720 --> 00:30:41,460
+عبارة عن غاز إذا كل ما زدنا احنا عدد الـ carbons في
+
+365
+00:30:41,460 --> 00:30:44,240
+الـ homologous series بتعرفوا homologous series
+
+366
+00:30:44,240 --> 00:30:46,980
+اللي هي المركبات اللي كل واحد بيكون بيفرج عن اللي
+
+367
+00:30:46,980 --> 00:30:54,280
+بعده بمقدار قداش CH2 لما أخذنا الجدول تبع الألكان
+
+368
+00:30:54,280 --> 00:30:58,940
+إذا رجعته شوية صغيرة جدول الألكان اللي هنطلع CH4
+
+369
+00:30:58,940 --> 00:31:04,900
+أول ألكان اللي بعده CH2 CH6 ما الفرق بينهما CH2 لو
+
+370
+00:31:04,900 --> 00:31:10,080
+أخذنا CH3 CH
+
+401
+00:33:37,910 --> 00:33:41,590
+قارنوا أشياء من نفس النوع، خمسة مع خمسة، ستة مع 
+
+402
+00:33:41,590 --> 00:33:44,350
+ستة، سبعة مع سبعة، وهكذا
+
+403
+00:33:48,530 --> 00:33:53,530
+بنجي لشغلة جديدة اللي هي ال conformations of ال
+
+404
+00:33:53,530 --> 00:33:58,230
+alkanes لما بدنا ندرس حقيقة ال conformations of ال
+
+405
+00:33:58,230 --> 00:34:02,650
+alkanes يفضل أننا ندرسها من خلال .. من خلال ال
+
+406
+00:34:02,650 --> 00:34:09,650
+models فلو عملنا احنا model لجزء ال ethane لو عملنا
+
+407
+00:34:09,650 --> 00:34:16,890
+model لجزء ال ethane وقلنا له إنه ما يغلّبنا، شطلعوا هذا
+
+408
+00:34:16,890 --> 00:34:21,550
+جزء ال ethane، إذا بتطلعوا أنا ماسكة بطريقة بحيث مخلي
+
+409
+00:34:21,550 --> 00:34:26,170
+كل ذرة قبال الثانية بظبط ولا لأ؟ طيب لو لفته شوية
+
+410
+00:34:26,170 --> 00:34:30,450
+بطلوا الذرات قبال بعض، هل يا ترى صار عندي جزء
+
+411
+00:34:30,450 --> 00:34:34,750
+جديد؟ لو لفته كمان شوية شكل جديد، كمان شوية شكل
+
+412
+00:34:34,750 --> 00:34:38,290
+جديد، ممكن أصل لو أنا بلفه إنه تصير هذه عكس هذه
+
+413
+00:34:38,290 --> 00:34:42,810
+يعني تطلعوا هذه لفوق وهذه لتحت، لو لفت كمان شوية
+
+414
+00:34:42,810 --> 00:34:48,780
+شكل جديد، شكل جديد، بعود يرجع؟ إجبال بعض، إذا هذه 
+
+415
+00:34:48,780 --> 00:34:54,200
+عبارة عن مجموعة أشكال ناشئة عن عملية إيش؟ الدوران
+
+416
+00:34:54,200 --> 00:34:57,720
+طب لو بدأ أقول قداش عدد الأشكال الناشئة عن الدوران؟
+
+417
+00:34:57,720 --> 00:35:03,480
+infinity، يعني لو بدأت ألف عشر عشر درجة وأزيد وأزيد
+
+418
+00:35:03,480 --> 00:35:06,940
+وأزيد وأزيد، عند عدد لا نهائي من الأشكال
+
+419
+00:35:06,940 --> 00:35:11,420
+تنتج عن الدوران، عند عدد لا نهائي من الأشكال تنتج
+
+420
+00:35:11,420 --> 00:35:18,220
+عن الدوران، طيب إذًا هل يطلع الأثين جزئ واحد ولا عدد لا
+
+421
+00:35:18,220 --> 00:35:22,660
+نهائي من الجزيئات؟ إذا أنا بقول هي جزئ، هي حاجة
+
+422
+00:35:22,660 --> 00:35:25,680
+جديدة، هي حاجة جديدة، هي حاجة جديدة، هو إيثين ولا
+
+423
+00:35:25,680 --> 00:35:31,980
+عدد لا نهائي من الإيثين؟ الحقيقة الموضوع بتقدر
+
+424
+00:35:31,980 --> 00:35:37,180
+تشبهه بالمروحة، المروحة لما بتلوف بتكون بعد لحظة
+
+425
+00:35:37,180 --> 00:35:40,820
+هيك، بعد لحظة هيك، بعد لحظة هيك، لكنها في حالة
+
+426
+00:35:40,820 --> 00:35:46,840
+دوران دائم فتبقى مروحة واحدة ولو بتمر بعدد لا نهائي
+
+427
+00:35:46,840 --> 00:35:50,860
+من الأشكال، وهناك في ال organic chemistry دوران
+
+428
+00:35:50,860 --> 00:35:54,760
+دائم أبدي لا يتوقف حول الرابطة الأحادية، يعني هذا
+
+429
+00:35:54,760 --> 00:35:59,900
+الجزء طول الوقت هو بلف زي هيك، لكن هو يبقى جزء
+
+430
+00:35:59,900 --> 00:36:04,580
+واحد، هذا الجزء يبقى إيش؟ جزء واحد اسمه إيثين، الآن
+
+431
+00:36:04,580 --> 00:36:08,580
+هذه الأشكال الناشئة عن الدوران بنسميها conformers،
+
+432
+00:36:08,580 --> 00:36:11,680
+conformers والظاهرة كلها بنقولها conformations
+
+433
+00:36:11,680 --> 00:36:16,340
+فال conformers they are stereoisomers، أشكال بس
+
+434
+00:36:16,340 --> 00:36:21,760
+اختلفت بالشكل الفراغي، هل نقلت رابطة من مكانها؟
+
+435
+00:36:21,760 --> 00:36:26,740
+أه، stereoisomers that are interconvertible،
+
+436
+00:36:26,740 --> 00:36:30,120
+بتتحولوا من واحد للتاني للتالت للرابع للخمس by؟
+
+437
+00:36:30,460 --> 00:36:35,160
+rotation، إذا ال conformers أشكال بتتحول من واحد
+
+438
+00:36:35,160 --> 00:36:39,760
+للثاني للثالث من خلال ال rotation، الآن هنا بدكم
+
+439
+00:36:39,760 --> 00:36:44,380
+تلاحظوا إنه أنا عندي إيثين واحد بعدد لا نهائي من
+
+440
+00:36:44,380 --> 00:36:49,500
+الدورانات زي ما عندي مروحة واحدة لكن ماخدة أشكال
+
+441
+00:36:49,500 --> 00:36:53,520
+لا نهائية وهي بتدور، في ال organic chemistry بالحب
+
+442
+00:36:53,520 --> 00:36:58,220
+احنا نرسم شكلين من هدول، الشكل اللي بيكونوا هدول
+
+443
+00:36:58,220 --> 00:37:02,700
+فيه جبال بعض بالظبط وبنعطيه اسم، والشكل اللي
+
+444
+00:37:02,700 --> 00:37:05,860
+بتكون كل واحدة عكس الثانية، يعني إذا بتلاحظوا الآن
+
+445
+00:37:05,860 --> 00:37:11,240
+هذه وهذه إيش مالهم؟ عكس بعض تماما، وهذه وهذه عكس
+
+446
+00:37:11,240 --> 00:37:15,500
+بعض، وهذه وهذه عكس بعض، كيف؟ الآن بنيجي بنرسم هذه
+
+447
+00:37:15,500 --> 00:37:19,920
+الأشكال، كيف؟ الآن بنيجي بنرسم هذه الأشكال بإمكاننا
+
+448
+00:37:19,920 --> 00:37:27,440
+احنا نطلع على الشكل بهذا زي ما أنا ماسكه تماما، في
+
+449
+00:37:27,440 --> 00:37:33,220
+عندكم رابطة هنا شايفينها؟ في عندي مجموعتين للأمام،
+
+450
+00:37:33,220 --> 00:37:38,720
+المجموعتين للأمام كيف بعملهم؟ ب solid wedge، وفي
+
+451
+00:37:38,720 --> 00:37:44,240
+عندي مجموعتين للخلف، كيف برسمهم؟ dash wedge، وفي
+
+452
+00:37:44,240 --> 00:37:48,930
+عندي هدول بيكونوا في مستوى اللوحة ملاحظين؟ إذا أنا
+
+453
+00:37:48,930 --> 00:37:53,530
+ممكن أرسم بهذه الطريقة، أنظر للجزء بهذا الشكل،
+
+454
+00:37:53,530 --> 00:37:57,670
+أقول، في عندي تنتين للأمام، solid wedge، تنتين
+
+455
+00:37:57,670 --> 00:38:02,450
+للخلف، dashed wedge، وعلى شكل الخط اللي موجودة في
+
+456
+00:38:02,450 --> 00:38:07,490
+مستوى اللوحة، هذا الشكل اللي فيه المجموعات قبال
+
+457
+00:38:07,490 --> 00:38:11,990
+بعض، بنسميه Eclipsed Conformation، إيش معناه Eclipsed؟
+
+458
+00:38:13,360 --> 00:38:18,260
+متطابق، الشكل المتطابق، حتى ال clips اللي بتمسكوا
+
+459
+00:38:18,260 --> 00:38:22,660
+فيه الدفاتر، ليش بيسموه Eclipsed؟ لأنه بيطبق ويجيب
+
+460
+00:38:22,660 --> 00:38:26,620
+الأشياء مع بعض واضح؟ يعني كلمة Eclipsed دائما
+
+461
+00:38:26,620 --> 00:38:30,260
+بنستعملها لإيش؟ للتطابق، الدبوس اللي بنشبك فيه
+
+462
+00:38:30,260 --> 00:38:34,180
+ورقتين شو بنسميه؟ clips، فهذا الشكل بنقول عنه
+
+463
+00:38:34,180 --> 00:38:38,840
+eclipsed confirmation، ممكن نرسمه بطريقة ال dash
+
+464
+00:38:38,840 --> 00:38:45,310
+wedge، ممكن ننظر له بزاوية أخرى، ممكن ننظر له بزاوية
+
+465
+00:38:45,310 --> 00:38:50,410
+أخرى، نرسمه بطريقة نتخيله أشبه ما يكون بالحصان
+
+466
+00:38:50,410 --> 00:38:54,950
+الخشبي اللي بيلعب عليه الجنباز، بتعرفوا الحصان
+
+467
+00:38:54,950 --> 00:38:58,910
+اللي بيلعب عليه الجنباز؟ لو حطينا هدول زي هيك،
+
+468
+00:38:58,910 --> 00:39:04,040
+انسوا هدول التنتين، إيش بيكون؟ هيو زي شكل الحصان،
+
+469
+00:39:04,040 --> 00:39:08,120
+له رجلتين، فاحنا ممكن نرسمه زي هيك، بهذه الحالة
+
+470
+00:39:08,120 --> 00:39:17,780
+بنرسم خط مائل وبنرسم مع خط اللوح، خطين لفوقي مثله
+
+471
+00:39:17,780 --> 00:39:22,900
+هدول الهيدروجينات، التنتين، وبننزل لتحت وتحت
+
+472
+00:39:23,340 --> 00:39:28,400
+مجموعتين، فلاحظوا هذه طريقة رسم غير عن هذه الطريقة
+
+473
+00:39:28,400 --> 00:39:31,700
+هذه الطريقة بنقول عنها ال saw horse، يعني بتصيروا
+
+474
+00:39:31,700 --> 00:39:34,900
+شايفينه أنتم هيك عن الجانب، وهاي المجموعتين اللي
+
+475
+00:39:34,900 --> 00:39:39,800
+لتحت زي تماما الحصان الخشبي لما بدكم تعملوها
+
+476
+00:39:39,800 --> 00:39:45,930
+بدكم ترسموا خط مائل، خطين لفوق بيعنوا المجموعتين
+
+477
+00:39:45,930 --> 00:39:49,310
+اللي قبل بعض بزام، هدول لفوق، إذا هدول التنتين وإن
+
+478
+00:39:49,310 --> 00:39:52,910
+بدهم يكونوا؟ لتحت، هدول التنتين وإن بدهم يكونوا؟
+
+479
+00:39:52,910 --> 00:39:56,290
+لتحت، إذا هذه طريقة ثانية لرسم ال eclipsed
+
+480
+00:39:56,290 --> 00:40:01,230
+confirmation باستعمال ال saw horse formula، ممكن
+
+481
+00:40:01,230 --> 00:40:05,290
+تنظروا للجزء بنظرة ثالثة تماما، بدل ما تنظرو له عن
+
+482
+00:40:05,290 --> 00:40:08,970
+الجانب زي هيك أو زي هيك، ممكن تنظرو له من الأمام
+
+483
+00:40:08,970 --> 00:40:14,960
+تخيلوا لو بتطلع عليه زي هيك، إيش بتشوفوا أنتم؟ بس
+
+484
+00:40:14,960 --> 00:40:21,800
+ثلاثة واللي ورا مخفيين وراهم اه، فبهذه الحالة ممكن
+
+485
+00:40:21,800 --> 00:40:27,200
+يرسموا بيعملوا دائرة بيطلع من المركز تبعها واحد
+
+486
+00:40:27,200 --> 00:40:31,120
+اتنين ثلاثة، هذه الدائرة بتعبر عن التلاتة اللي قدام
+
+487
+00:40:31,120 --> 00:40:36,360
+وبيطلع من المحيط تبعها كمان واحد اتنين ثلاثة من
+
+488
+00:40:36,360 --> 00:40:42,280
+جنب هدول، يعني إنهم وين جايين؟ خلف منها، واضح؟ هذه
+
+489
+00:40:42,280 --> 00:40:47,040
+الطريقة بيسموها طريقة Newman في رسم اللي هي ال
+
+490
+00:40:47,040 --> 00:40:50,840
+conformations of إيثين، لاحظوا كل هذا عبارة عن
+
+491
+00:40:50,840 --> 00:40:55,800
+الشكل إيش؟ المتطابق، الآن لو بدي أجي للشكل
+
+492
+00:40:55,800 --> 00:41:00,380
+المتعاكس بنسميه staggered conformation، خلينا نبدأ
+
+493
+00:41:00,380 --> 00:41:05,480
+من هنا لو خلينا هذا زي هيك، الآن أنتم بإمكانكم
+
+494
+00:41:05,480 --> 00:41:10,780
+تشوفوا قداش؟ ستة مش ثلاثة، لو رسمتوا التلاتة اللي
+
+495
+00:41:10,780 --> 00:41:16,580
+قدام من مركز الدائرة، هايهم، واحد، اثنين، ثلاثة،
+
+496
+00:41:16,580 --> 00:41:20,140
+التلاتة اللي من ورا من المحيط دائما بنرسمها،
+
+497
+00:41:20,140 --> 00:41:22,920
+التلاتة الهيدروجينات اللي قدام من المركز، التلاتة
+
+498
+00:41:22,920 --> 00:41:27,620
+اللي ورا من محيط الدائرة، فلاحظوا أنتم قادرين هنا
+
+499
+00:41:27,620 --> 00:41:33,490
+تشوفوا إيش؟ الستة، هي هدول بهذا الشكل، هذه طالعة من
+
+500
+00:41:33,490 --> 00:41:36,350
+الجانب اللي هان، هذه طالعة من الجانب اللي هان من
+
+501
+00:41:36,350 --> 00:41:39,530
+المحيط اللي بنرسمها، وهذه طالعة من الجانب اللي
+
+502
+00:41:39,530 --> 00:41:43,930
+موجود عندي، إذا هي طريقة رسم ال staggered
+
+503
+00:41:43,930 --> 00:41:49,050
+conformation بطريقة Newman، طيب، الآن لو هذه ال
+
+504
+00:41:49,050 --> 00:41:53,090
+staggered conformation بدكم ترسموها بطريقة مثلا
+
+505
+00:41:53,090 --> 00:42:00,500
+ال dash wedge، اتخيلوا هي الرابطة okay، خلينا نرسم زي
+
+506
+00:42:00,500 --> 00:42:07,000
+ما هي هان هيك، هاي الشكل، إيش بتلاحظوا عندكم هان
+
+507
+00:42:07,000 --> 00:42:13,600
+لفوق؟ على اتجاهكم؟ ال solid، وهادي؟ برضه على
+
+508
+00:42:13,600 --> 00:42:17,420
+اتجاهكم، بس واحدة لفوق واحدة لتحت، هاي نرسموا
+
+509
+00:42:17,420 --> 00:42:21,660
+واحدة لفوق واحدة لتحت، في الخلف إيش عندكم؟ ال dash
+
+510
+00:42:21,660 --> 00:42:25,960
+واحدة لفوق واحدة لتحت، وهدول اللي بيكونوا على
+
+511
+00:42:25,960 --> 00:42:31,660
+المستوى اللي برسمهم بخط عادي، ال H هادي وال H هادي
+
+512
+00:42:31,660 --> 00:42:37,100
+واضح؟ إذا أنا بهدوء بإمكاني أرسم الشكل باستعمال
+
+513
+00:42:37,100 --> 00:42:41,140
+Newman، باستعمال ال dash wedge، بإمكاني أرسمه بطريقة
+
+514
+00:42:41,140 --> 00:42:47,120
+الحصان أكيد، يعني لو حطيت هذا الخط بسمائل شوية بنزل
+
+515
+00:42:47,120 --> 00:42:52,200
+واحدة لتحت والتانية، إذا هذه نازلة لتحت، هذول
+
+516
+00:42:52,200 --> 00:42:56,840
+التنتين وين بيكونوا؟ وإذا هذه طالعة لفوق، هذول
+
+517
+00:42:56,840 --> 00:43:01,140
+التنتين وين بيكونوا؟ لتحت، هذه طريقة الرسم
+
+518
+00:43:01,140 --> 00:43:06,540
+باستعمال ال saw horse، إذا بإمكاني أنا أرسم ل eclipsed
+
+519
+00:43:06,540 --> 00:43:08,980
+confirmation ول staggered confirmation، وهذا
+
+520
+00:43:08,980 --> 00:43:12,300
+الكلام لازم تعمله عليه تدريب بإيديكم في البيت
+
+521
+00:43:12,300 --> 00:43:18,170
+باستعمال ال dash wedge أو ال saw horse أو ال Newman
+
+522
+00:43:18,170 --> 00:43:22,910
+projection اللي هو إسقاط ال Newman، لحد هيك بننتهي
+
+523
+00:43:22,910 --> 00:43:24,050
+اليوم إن شاء الله
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6129273e10e31a2c6072102a263dcce8ecce1c6a
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg_postprocess.srt
@@ -0,0 +1,2092 @@
+1
+00:00:13,260 --> 00:00:17,620
+اليوم ان شاء الله بنبدأ الفصل التاني الموضوع اللى
+
+2
+00:00:17,620 --> 00:00:21,280
+عندنا زى ما انتوا شايفين اللى هى المجموعة الاولى
+
+3
+00:00:21,280 --> 00:00:25,000
+من المجموعات الوظيفية مجموعة ال alkanes و ال
+
+4
+00:00:25,000 --> 00:00:28,600
+cycloalkanes و الحصة الماضية احنا حكينا ان ال
+
+5
+00:00:28,600 --> 00:00:35,830
+alkanes بيمتازوا ان موجود فيهم رابطة أحديةالان اذا
+
+6
+00:00:35,830 --> 00:00:40,730
+بدنا نطلع على تصنيف المراكبات العضوية ال alkanes
+
+7
+00:00:40,730 --> 00:00:44,990
+حقيقة و ال cycloalkanes يعني المراكبات حلقية يعني
+
+8
+00:00:44,990 --> 00:00:49,750
+يا المراكب بيكون عبارة عن سلسلة مفتوحة يا اما
+
+9
+00:00:49,750 --> 00:00:54,470
+بيكون عبارة عن حلقة الحالتين بيكونوا كلهم روابط
+
+10
+00:00:54,470 --> 00:00:59,950
+احدية الان احنا المراكبات الليبتتكون من ال
+
+11
+00:00:59,950 --> 00:01:04,950
+hydrogen و ال carbons بيسموها hydrocarbons الآن ال
+
+12
+00:01:04,950 --> 00:01:10,090
+hydrocarbons هذه بيقسموها إلى نوعين اما انه تكون
+
+13
+00:01:10,090 --> 00:01:14,970
+saturated بمعنى مشبعة معنى saturated انه مافيش
+
+14
+00:01:14,970 --> 00:01:21,950
+فيها غير روابط و حادية single bondsو unsaturated
+
+15
+00:01:21,950 --> 00:01:25,390
+بيكون فيها multiple bonds multiple bonds يعني
+
+16
+00:01:25,390 --> 00:01:28,830
+يبدوا يكونوا double bond يا triple bond مافيش اكثر
+
+17
+00:01:28,830 --> 00:01:34,690
+من هيك يعني يا رابطة زوجية يا رابطة ثلاثيةبشكل عام
+
+18
+00:01:34,690 --> 00:01:39,550
+هناك علاقة ما بين عدد الكربون وعدد الهيدروجين لأي
+
+19
+00:01:39,550 --> 00:01:44,950
+جزء الكان ليش لأنه النسبة ثابتة بمعنى زي ما حكي
+
+20
+00:01:44,950 --> 00:01:48,750
+الحصة الماضية الكربون دايما بياخد كام رابطة أربعة
+
+21
+00:01:48,750 --> 00:01:52,450
+الهيدروجين دايما بياخد رابطة بناء على ذلك لو بدنا
+
+22
+00:01:52,450 --> 00:01:57,340
+نعمل أي الكانهنلاحظ ان علاقة الكربون والهيدروجين
+
+23
+00:01:57,340 --> 00:02:02,820
+نسبة ثابت هذه العلاقة هي عبارة عن cn h2n plus 2
+
+24
+00:02:02,820 --> 00:02:09,280
+مثلا هي عندي انا جزء عبارة عن كام كربون C2 لما
+
+25
+00:02:09,280 --> 00:02:14,580
+اقول اتنين في اتنين زاد اتنين ستة بتلاحظوا عندكم
+
+26
+00:02:14,580 --> 00:02:20,280
+ست ذرات هيدروجين هذا جزء ال E2 لو بدنا نتطلع مثلا
+
+27
+00:02:20,280 --> 00:02:26,500
+على جزءالبروبين لو بدنا نطلع جزء البروبين عندنا
+
+28
+00:02:26,500 --> 00:02:33,580
+C3H تقدروا تعدوهم تلاتة و اتنين و تلاتة تمانية H8
+
+29
+00:02:33,580 --> 00:02:34,940
+فلو قولنا اتنين
+
+30
+00:02:38,900 --> 00:02:45,480
+الصيغة العامة للالكينز CNH2N الان ال Cycloalkane
+
+31
+00:02:45,480 --> 00:02:52,300
+مش مركبات حلقية مش مركبات حلقية مش مركبات مفتوحة
+
+32
+00:02:52,300 --> 00:02:58,070
+مركبات حلقية بمعنى انا بدي اشيلبدي أشيل
+
+33
+00:02:58,070 --> 00:03:02,030
+هيدروجينتين من الألكين يعني عشان أعمل cycle ألكين
+
+34
+00:03:02,030 --> 00:03:07,650
+عشان أعمل حلقة بدي أشيل هيدروجنتين و أسكر على شكل
+
+35
+00:03:07,650 --> 00:03:13,740
+حلقة بهذا الشكل لحظة انا صار عندي مركب حلقيأيش
+
+36
+00:03:13,740 --> 00:03:17,820
+اللي عملته انا لما سويت حلقة شيلت هيدروجينتين مع
+
+37
+00:03:17,820 --> 00:03:23,200
+رابطة واضح فالصيغة العامة لل Cycloalkanes ايش
+
+38
+00:03:23,200 --> 00:03:28,180
+بتطلع فى هذه الحالة CNH2N اللي بلفته راحت لإن انا
+
+39
+00:03:28,180 --> 00:03:32,980
+شيلت هيدروجنتين واضح فال Cycloalkanes هي مثال
+
+40
+00:03:32,980 --> 00:03:37,680
+عليهم هذا المركب بتكون عبارة عن CNH2N يعني لما
+
+41
+00:03:37,680 --> 00:03:43,290
+عندي C3F6 واضح هاي الفرق ال Cycloalkane على
+
+42
+00:03:43,290 --> 00:03:48,190
+الalkane كصيغة عامة الان ال unsaturated
+
+43
+00:03:48,190 --> 00:03:52,170
+hydrocarbons
+
+44
+00:03:52,170 --> 00:03:57,130
+منهم ال alkenes ال alkenes اللي فيهم double bond
+
+45
+00:03:57,130 --> 00:04:00,430
+الان لاحظوا لو بدى اعمل من هنا alkene يعني بدى
+
+46
+00:04:00,430 --> 00:04:06,000
+اشيل برضهرابطة مع هيدروجينة زي ما عملت في ال cycle
+
+47
+00:04:06,000 --> 00:04:10,540
+alkane و أتني هذه بشكل معين بحيث أعمل double bond
+
+48
+00:04:10,540 --> 00:04:17,360
+هاي جزء الاثيلين اذا ال alkenes برضه اعملته من
+
+49
+00:04:17,360 --> 00:04:21,340
+خلال ايش انه شيلت هيدروجينتين اذا ايش الصيغة
+
+50
+00:04:21,340 --> 00:04:25,960
+العامة بتاعتهم؟CNH2N بتلاحظوا بهاد الحالة ان
+
+51
+00:04:25,960 --> 00:04:30,220
+الصيغة العامة لل Cycloalkynes و الصيغة العامة لل
+
+52
+00:04:30,220 --> 00:04:35,140
+Alkenes نفس الاشي عشان اكون double bond او عشان
+
+53
+00:04:35,140 --> 00:04:40,860
+اكون حلقة بيلزمني ان اشيل هيدروجينتين واضح عشان
+
+54
+00:04:40,860 --> 00:04:43,480
+اكون double bond او اكون حلقة بيلزمني اشيل
+
+55
+00:04:43,480 --> 00:04:48,780
+هيدروجنتين الان لو بدى اكون رابطة اضافية triple
+
+56
+00:04:48,780 --> 00:04:54,020
+bond عشان احصل على الalkynes بدى اشيلكمان
+
+57
+00:04:54,020 --> 00:04:58,340
+هيدروجينتين هي هيدروجينة مع رابطتها و هي التانية و
+
+58
+00:04:58,340 --> 00:05:03,420
+بعد هيك اذا ال model بيسمح طب هيعملنا triple bond
+
+59
+00:05:03,420 --> 00:05:09,440
+واضح؟ اذا لتكوين اي رابطة اضافية بده اشيل
+
+60
+00:05:09,440 --> 00:05:12,620
+هيدروجينتين لتكوين اي حلقة اضافية بده اشيل
+
+61
+00:05:12,620 --> 00:05:17,160
+هيدروجنتين في هذا الحالة لو بده اطلع على ال triple
+
+62
+00:05:17,160 --> 00:05:21,380
+bonds او ال alkines لما يكون عند one triple bond
+
+63
+00:05:21,380 --> 00:05:28,570
+شو الصيغة العامة بدها تكون؟CNH2N-2 بمعنى لما يكون
+
+64
+00:05:28,570 --> 00:05:34,990
+عندى اتنين بدي اقول C2H2X2 اربع ناقص اتنين اتنين
+
+65
+00:05:34,990 --> 00:05:39,550
+اذا هذا المركب اللى هو أبسط الكاين الاسيتيلين بدي
+
+66
+00:05:39,550 --> 00:05:48,510
+يكون C2H2 صيغته العامة CNH2N-2 واضح هذه بالنسبة
+
+67
+00:05:48,510 --> 00:05:53,930
+للصيغاتمن ال hydrocarbons غير المشبعة ال aromatic
+
+68
+00:05:53,930 --> 00:05:57,070
+compounds اللي هم المركبات اللي زي البنزين اللي
+
+69
+00:05:57,070 --> 00:06:01,590
+فيهم حلقة و عدة double bonds واضح؟ و هدولة بناخدهم
+
+70
+00:06:01,590 --> 00:06:09,170
+احنا بفصل كامل اللي هو الفصل الرابع بنرجع لهم الان
+
+71
+00:06:09,170 --> 00:06:14,310
+لو اجينا نتعرف على ال alkanes و أشكالها بنلاحظ انه
+
+72
+00:06:14,310 --> 00:06:20,090
+احنا ممكن يكون عندنا carbonتنتين تلاتة أربعة خمسة
+
+73
+00:06:20,090 --> 00:06:24,950
+العدد عندنا مفتوح العدد عندنا مفتوح لو عندنا one
+
+74
+00:06:24,950 --> 00:06:30,450
+carbon و بيكون المركب اسمه methane و حسب القاعدة
+
+75
+00:06:30,450 --> 00:06:33,950
+التسمية اللي .. حسب قاعدة العدد اللي أخدناها
+
+76
+00:06:33,950 --> 00:06:39,370
+الصيغة شو بده تكون CH4 carbon تين بيصير المركب
+
+77
+00:06:39,370 --> 00:06:48,230
+اثان تلاتة بروبين أربعة بيوتين خمسةالستة هكسين
+
+78
+00:06:48,230 --> 00:06:54,370
+السبعة هبتين التمانية أكتين التسعة نونين والعشرة
+
+79
+00:06:54,370 --> 00:06:59,440
+ديكان واضح؟الان هذه المُركّبات بهذه الأسماء هي
+
+80
+00:06:59,440 --> 00:07:04,280
+لمُركّبات الـ carbons تبعتها متسلسلة ورا بعض، الان
+
+81
+00:07:04,280 --> 00:07:07,660
+ممكن يصير عندى تفرعات بتصير مُركّبات جديدة، يعني
+
+82
+00:07:07,660 --> 00:07:12,700
+لما أحط مثلا set carbonate ورا بعض عشكل سلسلة
+
+83
+00:07:12,700 --> 00:07:16,600
+chain، هذا الـ hexane، الان أنا ممكن أحط أربعة أو
+
+84
+00:07:16,600 --> 00:07:20,480
+أعمل تفرع اتنين، بيصير مُركّب جديد، بنتعلم تسميته،
+
+85
+00:07:20,480 --> 00:07:26,450
+فهذه الأسماء للسلاسلالمستقيمة للسلاسل المستقيمة
+
+86
+00:07:26,450 --> 00:07:31,210
+حقيقة هذه السلاسل بورسموها على الشكل اللي بيسموه
+
+87
+00:07:31,210 --> 00:07:35,810
+ال zigzag بتعرفوا ال zigzag؟ في الخياطة بيعملوا
+
+88
+00:07:35,810 --> 00:07:41,370
+غرزة zigzag هيك يعني هي ال zigzag هذا
+
+89
+00:07:41,370 --> 00:07:45,470
+الشكل zigzag يعني مش متعودين نعمله المركب زي هيك
+
+90
+00:07:45,470 --> 00:07:48,650
+بهذا الخط لأ في ال organ chemistry بنعمل zigzag
+
+91
+00:07:48,650 --> 00:07:52,190
+بين كل carbon والتانية ولو أنتوا حقيقة بتكونوا
+
+92
+00:07:52,190 --> 00:07:59,020
+اتلاحظواOkay هذا الشكل اللي هو ال zigzag او الشكل
+
+93
+00:07:59,020 --> 00:08:02,660
+المتعرج و دايما لما بدكوا ترسم على لو بدكوا تعملوا
+
+94
+00:08:02,660 --> 00:08:08,220
+عشرة carbons بدكوا تمشوا بهذا الشكل واضح؟ بهذا
+
+95
+00:08:08,220 --> 00:08:08,660
+الشكل
+
+96
+00:08:11,800 --> 00:08:15,880
+شغلة جديدة اللي هي ال alkyl groups او مجموعات ال
+
+97
+00:08:15,880 --> 00:08:21,020
+alkyl الان كل جزء organic له شكل له عدد من ال
+
+98
+00:08:21,020 --> 00:08:26,260
+carbons له عدد من ال hydrogens لو اي جزء من جزيئات
+
+99
+00:08:26,260 --> 00:08:31,220
+ال organic شيلنا منه hydrogen واحدةهذه الهيدروجين
+
+100
+00:08:31,220 --> 00:08:35,400
+هينشلناها شفتوها بيصير عند مجموعة الكل اش اللي
+
+101
+00:08:35,400 --> 00:08:40,300
+بقصده انا بمجموعة الكل مجموعة ممكن تركب او تتحد في
+
+102
+00:08:40,300 --> 00:08:44,360
+اي مكان تاني محل ما كانت متصلة مع الهيدروجين ممكن
+
+103
+00:08:44,360 --> 00:08:49,880
+تتحد مع شيء تاني يعني لو مثلا افترضت انه هذه درة
+
+104
+00:08:49,880 --> 00:08:54,940
+كلور ممكن تيجي هذه مجموعة الكل تتحد هنا مع الكلور
+
+105
+00:08:54,940 --> 00:09:01,650
+تتكون جزءمع إيش؟ مع الكلور الآن الجزء أصلا إيش كان
+
+106
+00:09:01,650 --> 00:09:08,450
+اسمه و كله ملان هيدروجين كان اسمه ميثين الجزء هذا
+
+107
+00:09:08,450 --> 00:09:13,490
+إيش كان اسمه؟ ميثين الآن لما هذا الجزء إحنا بنشيل
+
+108
+00:09:13,490 --> 00:09:18,030
+منه هيدروجين بتصير المجموعة اسمها مثل إذا ميثين
+
+109
+00:09:18,030 --> 00:09:28,160
+بيعطيني مثل طب لو شبكة هذه مثل مع كلور بصير مثلأو
+
+110
+00:09:28,160 --> 00:09:31,900
+كلورو ميثين بالـ Iobacnium هناخد التسمية، واضح؟
+
+111
+00:09:31,900 --> 00:09:36,220
+إذا هذه الـ CH3 مش الـ CH4، شو بيصير اسمها
+
+112
+00:09:36,220 --> 00:09:42,780
+كمجموعة؟ مثل، إذا الميثين بيعمل مجموعة المثل،
+
+113
+00:09:42,780 --> 00:09:47,320
+واضح؟ لما نشيل منه هيدروجينة، الآن بنفس الطريقة لو
+
+114
+00:09:47,320 --> 00:09:53,470
+إجينا طلعنا على ال إيثينلو شيلنا منه هيدروجينة بدل
+
+115
+00:09:53,470 --> 00:10:01,730
+C2H6 أو C3H3 بيصير CH3 CH2 بينخس منه هيدروجينة هذا
+
+116
+00:10:01,730 --> 00:10:06,650
+إثن المجموع اللي بتطلع منه إيش اسمها إثل واضح
+
+117
+00:10:06,650 --> 00:10:12,890
+المجموع اللي بتطلع منه إثل الأمور للأسفما بتضلش ..
+
+118
+00:10:12,890 --> 00:10:17,270
+ما بتضلش خلّيني أقول سهلة كتير .. ما بتضلش سهلة
+
+119
+00:10:17,270 --> 00:10:22,390
+كتير يعني مجرد ما بنصل لجزء البروبين بنلاقي أنه
+
+120
+00:10:22,390 --> 00:10:27,450
+بيبدأ يصير عندنا إشكالية شو الإشكالية اللي بتبدأ
+
+121
+00:10:27,450 --> 00:10:31,850
+تصير عندى لما أصل لجزء البروبين؟بدي أشيل هيدروجينة
+
+122
+00:10:31,850 --> 00:10:35,530
+بلاحظ أنه الهيدروجين اللي في البروبين نوعين هدولة
+
+123
+00:10:35,530 --> 00:10:39,670
+التلاتة و هدولة التلاتة زي بعض بمعنى لو شيلت أي
+
+124
+00:10:39,670 --> 00:10:44,310
+هيدروجينة من هان لو شيلت أي هيدروجينة من هذا الطرف
+
+125
+00:10:44,310 --> 00:10:48,130
+وكنت بدي أشبكها بchlor اتطلعوا معاكي كيف الجزء
+
+126
+00:10:48,130 --> 00:10:54,650
+بيشبك من الطرف carbon تنتين تلاتة الان طيب لو
+
+127
+00:10:54,650 --> 00:11:01,070
+شيلنا هيدروجينة مش من الطرف هذا من النصبصير جزء
+
+128
+00:11:01,070 --> 00:11:05,330
+تاني بصير جزء تاني اتطلعوا كيف صار متحد مع ال
+
+129
+00:11:05,330 --> 00:11:09,690
+chlorine مثلا واضح اذا في حالة البروبين انا
+
+130
+00:11:09,690 --> 00:11:12,570
+بإمكاني اشيل الهيدروجين من هذا الطرف و بإمكاني
+
+131
+00:11:12,570 --> 00:11:15,750
+اشيل الهيدروجين من النص طبعا من الطرف هذا زي هذا
+
+132
+00:11:15,750 --> 00:11:19,350
+فإذا شيلنا من الطرف هذا بنعمل المجموعة اللي
+
+133
+00:11:19,350 --> 00:11:23,890
+بنسميها بروبل و مرات بيحطوا قدامها N بروبل يعني
+
+134
+00:11:23,890 --> 00:11:30,070
+normal بروبل بروبل عادي عبارة عن CH2 CH2CH3 و لو
+
+135
+00:11:30,070 --> 00:11:34,630
+شيلنا الهيدروجينة من النص بيعمل مجموعة isopropyl
+
+136
+00:11:34,630 --> 00:11:37,850
+بيكون الاتصال تبع ال isopropyl من أي كربونا من
+
+137
+00:11:37,850 --> 00:11:43,370
+التلاتة الكربونا الوسطانية مش الطرفية واضح؟ اذا
+
+138
+00:11:43,370 --> 00:11:49,490
+البروبين له مجموعتين الكل شهما البروبيل اذا اتصل
+
+139
+00:11:49,490 --> 00:11:55,970
+من الطرف و isopropyl اذا اتصل من النص الان لو
+
+140
+00:11:55,970 --> 00:12:02,720
+الأمور كبرت شويةصار في عندنا لبيوتين لبيوتين
+
+141
+00:12:02,720 --> 00:12:08,500
+مشكلته شوية .. مشكلته شوية أكبر ليش لبيوتين مشكلته
+
+142
+00:12:08,500 --> 00:12:14,560
+أكبر؟ أساسا أول ما باجي بدي أشيل هيدروجينة من
+
+143
+00:12:14,560 --> 00:12:19,300
+لبيوتين عشان أحط بدالها الكربونة الرابعة مش هو تلت
+
+144
+00:12:19,300 --> 00:12:22,940
+كربونات؟ بدي أخليه أربعة أول ما بدي أجي أشيل
+
+145
+00:12:22,940 --> 00:12:28,800
+هيدروجينة ممكن أشيل من هانوبالتالي الكربونات اللى
+
+146
+00:12:28,800 --> 00:12:35,100
+عندى يكونوا ماخدين شكل السلسلة ال chain ورا بعض
+
+147
+00:12:35,100 --> 00:12:40,140
+جايين بدون تفرع واحد، اتنين، تلاتة، اربعة، واضح؟
+
+148
+00:12:40,140 --> 00:12:45,940
+هذا مركب لكن لو افترضنا مثلا انه احنا شيلنا هذه
+
+149
+00:12:45,940 --> 00:12:48,320
+الهيدروجينة وحطينا بدلها كربون
+
+150
+00:12:51,680 --> 00:12:55,460
+برضه دول اربع كاربونات لكن هذا شكل مختلف هذا صار
+
+151
+00:12:55,460 --> 00:13:01,000
+branched molecule ايش يعني branched؟ متفرع اذا
+
+152
+00:13:01,000 --> 00:13:06,960
+البيوتين اصلا في منه مركبين المركب مش المجموعات
+
+153
+00:13:06,960 --> 00:13:10,680
+المركب نفسه البيوتين في منه اتنين اما بيكون على
+
+154
+00:13:10,680 --> 00:13:15,540
+شكل a chain compound a chain يعني ايه؟ على شكل
+
+155
+00:13:15,540 --> 00:13:20,040
+سلسلة و اما بيكون branched ايه كاربون اتنين تلاتة؟
+
+156
+00:13:20,130 --> 00:13:25,790
+أربعة ال chain compound بنسميه بيوتين ال branch
+
+157
+00:13:25,790 --> 00:13:32,230
+بنسميه ايزو بيوتين واضح؟ اذا من مركب البيوتين نفسه
+
+158
+00:13:32,230 --> 00:13:36,530
+من مركب البيوتين نفسه انا في عندي كام مركب؟ اتنين
+
+159
+00:13:36,530 --> 00:13:40,710
+اللي هم ال chain و ال branch البيوتين و ايزو
+
+160
+00:13:40,710 --> 00:13:47,450
+بيوتين الان لما نيجي بدنا نعملالكلي جروبز بنلاحظ
+
+161
+00:13:47,450 --> 00:13:52,190
+أنه ال بيوتين الأربعة ممكن تفقد هيدروجينة من هنا
+
+162
+00:13:52,190 --> 00:13:56,850
+يعطيني مجموعة وممكن من هنا كمان يعطيني مجموعة إذا
+
+163
+00:13:56,850 --> 00:14:01,630
+فقدت الهيدروجينة من هنا بصير عندى ال product اسمه
+
+164
+00:14:01,630 --> 00:14:08,910
+normal butyl group أو butylig group واضح؟ لو حطيت
+
+165
+00:14:08,910 --> 00:14:14,730
+كلور هنا على الطرف بصير butylechloride واضح لكن لو
+
+166
+00:14:14,730 --> 00:14:19,390
+فقدت الهيدروجينة من الموقع التاني بنسمي ال group
+
+167
+00:14:19,390 --> 00:14:25,150
+secondary butyl واضح secondary butyl اذا الان
+
+168
+00:14:25,150 --> 00:14:29,590
+بيوتين منه مجموعتين butyl و secondary butyl ال
+
+169
+00:14:29,590 --> 00:14:32,630
+butyl من موقع واحد اتصالها ال secondary butyl من
+
+170
+00:14:32,630 --> 00:14:39,550
+موقع اتنين طيب لو اجينا ل .. ل branchedاللي موجود
+
+171
+00:14:39,550 --> 00:14:43,390
+عندنا هنا المتفرع بنلاحظ أنه يمكن أن تفقد
+
+172
+00:14:43,390 --> 00:14:47,170
+هيدروجينة من أي واحدة من هدول التلاتة زي بعض بتصير
+
+173
+00:14:47,170 --> 00:14:52,710
+المجموعة اسمها isobutyl واضح؟ بتصير المجموعة اللي
+
+174
+00:14:52,710 --> 00:14:56,350
+عنده اسمها isobutyl
+
+175
+00:14:59,100 --> 00:15:04,780
+المجموعة اللي احنا بنسميها ال isobutyl إذا فقدت ال
+
+176
+00:15:04,780 --> 00:15:09,780
+hydrogen من أحد الأطراف اللي موجودة عند هنا واضح؟
+
+177
+00:15:09,780 --> 00:15:13,460
+وإذا فقدت ال hydrogen من النص اللي هي هذه ال
+
+178
+00:15:13,460 --> 00:15:17,460
+hydrogen الوحيدة اللي هنا موجودة ممكن نكمل الجزء
+
+179
+00:15:17,460 --> 00:15:24,980
+حتى يعني الصورة عندكم تكون واضحة
+
+180
+00:15:24,980 --> 00:15:25,560
+تماما
+
+181
+00:15:28,630 --> 00:15:32,810
+هذا ال بيوتين شايفينه اللي هو المتفرع، الان لو
+
+182
+00:15:32,810 --> 00:15:37,370
+فقدنا هيدروجينة من اي CH3 زي بعض، يعني هادي زي
+
+183
+00:15:37,370 --> 00:15:40,450
+هادي زي هادي مافيش فيه مشكلة، الان لو فقدت
+
+184
+00:15:40,450 --> 00:15:44,750
+الهيدروجينة من هنا، شو بده يكون اسم المجموعة؟
+
+185
+00:15:44,750 --> 00:15:49,700
+Isobutyl، Isobutyl، لو حطيت هنا Clorشو بيصير اسم
+
+186
+00:15:49,700 --> 00:15:54,980
+المركب؟ Isobutyl chloride لاحظوا من الشكل الأول و
+
+187
+00:15:54,980 --> 00:16:00,400
+من الشكل التاني مجموعة ال ISO لما بنقول ISO معناه
+
+188
+00:16:00,400 --> 00:16:10,270
+ذلك ان في عندكم CH3 CH CH3يعني كلمة ISO فيها CH3
+
+189
+00:16:10,270 --> 00:16:18,050
+CH CH3 لما كانوا الكربونات تلاتة CH3 CH CH3 بس
+
+190
+00:16:18,050 --> 00:16:23,010
+تلات كربونات شو سمينا المجموعة؟ ISO بربل على
+
+191
+00:16:23,010 --> 00:16:29,410
+تلاتة، الآن لما بيصيروا أربعة CH3 CH CH3 وإجت هنا
+
+192
+00:16:29,410 --> 00:16:35,890
+كمان CH2بدي يصير المركب إيش؟ Isobutyl لكن التنين
+
+193
+00:16:35,890 --> 00:16:42,370
+بيمتازوا بهذه المجموعة اللي فوق CH3 CH CH3 إذا كان
+
+194
+00:16:42,370 --> 00:16:47,410
+العدد الكلي تلاتة Isopropyl إذا زدت هنا تنتين
+
+195
+00:16:47,410 --> 00:16:50,650
+Isobutyl
+
+196
+00:16:50,650 --> 00:16:58,260
+طب لو زدت كمان CH2 خمس كربوناتIsobentyl لو صار ستة
+
+197
+00:16:58,260 --> 00:17:04,520
+Isohexyl Isoheptyl Isooctyl ومنه ال Isooctane اللي
+
+198
+00:17:04,520 --> 00:17:09,760
+بيدخل في صناعة الوقود تبع السيارات، مكون وقود
+
+199
+00:17:09,760 --> 00:17:13,300
+السيارات، بس فيهم كلهم Isopropyl Isobutyl
+
+200
+00:17:13,300 --> 00:17:20,850
+Isobentyl Isohexyl الطرف تبعهم إيش؟CH3 CH CH3 هذه
+
+201
+00:17:20,850 --> 00:17:27,670
+مجموعة ال ISO واضح؟ اذا هي ال ISO group ال ISO
+
+202
+00:17:27,670 --> 00:17:34,090
+butyl طيب لو شيلنا من النص ال hydrogen لاحظوا
+
+203
+00:17:34,090 --> 00:17:38,630
+بيصير عندي carbon حاملة CH3 CH3 CH3 هذه مجموعة
+
+204
+00:17:38,630 --> 00:17:44,590
+كبيرة شايفين كيف؟ لو اتصلت بchlor بيصير المركب طيب
+
+205
+00:17:44,590 --> 00:17:48,610
+هذه المجموعة كلها ك group شو بسميها انا؟Tertiary
+
+206
+00:17:48,610 --> 00:17:52,510
+Butyl لو اتحدت مع الكلور و جيبنالكم هذا المركب
+
+207
+00:17:52,510 --> 00:17:58,430
+قولنالكم ايش اسمه تيرتشاري بيوتل كل هذا الكربون
+
+208
+00:17:58,430 --> 00:18:03,430
+اللي حملة تلاتة CH3 اسمها ايش تيرتشاري بيوتل لو
+
+209
+00:18:03,430 --> 00:18:10,550
+اتحدت مع الكلور تيرتشاري بيوتل اكلورايد اذا حقيقة
+
+210
+00:18:10,550 --> 00:18:14,310
+من البيوتين بشقيها اللي هو البيوتين العادي و
+
+211
+00:18:14,310 --> 00:18:19,150
+الايزوبيوتين اكملك ال group في عند اناأربعة عند
+
+212
+00:18:19,150 --> 00:18:26,290
+بيوتل وسكندر بيوتل من المركب لتشين وعند ايزو بيوتل
+
+213
+00:18:26,290 --> 00:18:31,190
+و تيرتشر بيوتل من المركب لبرانشت هذه المجموعات
+
+214
+00:18:31,190 --> 00:18:35,650
+كلها المفروض أي طالب organic يكون ايش حافظها تماما
+
+215
+00:18:35,650 --> 00:18:40,850
+لأنه دائما بنسأل عنها يعني ممكن نجيب حلقة بنزين
+
+216
+00:18:40,850 --> 00:18:45,510
+على سبيل المثال متصلة فيها هذه المجموعة وقتها شو
+
+217
+00:18:45,510 --> 00:18:51,250
+بنسمي المركب؟Tertiary-butylbenzene يعني لو ان
+
+218
+00:18:51,250 --> 00:18:56,190
+اتخيلت ان هنا حطيت حلقة بنزين زي هيك هى صار مركب
+
+219
+00:18:56,190 --> 00:19:01,590
+لما بدى اسميه لو كنت انا حاطط بس كلور بسميه
+
+220
+00:19:01,590 --> 00:19:05,250
+chlorobenzene طب لما احط هذه المجموعة كلها شو
+
+221
+00:19:05,250 --> 00:19:09,210
+بيصير اسمه tertiary-butylbenzene لو حطيت هنا
+
+222
+00:19:09,210 --> 00:19:13,270
+البنزين شو بيصير اسمه المركب isobutylbenzene لو
+
+223
+00:19:13,270 --> 00:19:19,030
+حطيته هنا isopropylbenzene لو حطيته هناethyl
+
+224
+00:19:19,030 --> 00:19:25,730
+benzene واضح الفكرة كيف؟ فهذه مجموعات القلكل حقيقة
+
+225
+00:19:25,730 --> 00:19:30,390
+بدكوا تكونوا حافظينها بشكل ممتاز
+
+226
+00:19:33,570 --> 00:19:38,570
+هذه الألكانز البسيطة اللي احنا اتعرفنا عليها طب لو
+
+227
+00:19:38,570 --> 00:19:44,130
+كبر المركبة بدنا طريقة عامة لتسمية أي مركب كبير
+
+228
+00:19:44,130 --> 00:19:48,230
+اللي هي Nomenclature of Substituted Alkanes
+
+229
+00:19:48,230 --> 00:19:52,530
+Nomenclature دائما ايش بتيجي .. تسمية المركبات
+
+230
+00:19:52,530 --> 00:19:57,830
+العضوية او الألكانز الكبيرةعشان أسمي أي ألكين
+
+231
+00:19:57,830 --> 00:20:02,610
+المفروض أطلع على ال carbons تعوني الألكين وأبحث
+
+232
+00:20:02,610 --> 00:20:09,130
+إلى أن أحصل على أطول سلسلة ذرات كربون، واضح؟ مثلا
+
+233
+00:20:09,130 --> 00:20:12,090
+في هذا المراكب لو أطلعت أي واحد، اتنين، تلاتة،
+
+234
+00:20:12,090 --> 00:20:17,140
+اربعة، خمسة، هذه الحمرة سلسلة إيش؟الكربون، إذا
+
+235
+00:20:17,140 --> 00:20:20,960
+المركب اللي عندى مشتق من الخمسة، الخمسة عبارة عن
+
+236
+00:20:20,960 --> 00:20:25,760
+إيش؟ بنتين، بنتين، فالمركب اللي عندى هو مشتقة
+
+237
+00:20:25,760 --> 00:20:29,180
+بنتين، الآن ال substituents اللي موجودة إيه لها
+
+238
+00:20:29,180 --> 00:20:35,300
+أسمها؟ الchlor اسمه chloro، ال brom إيه bromه؟ ال
+
+239
+00:20:35,300 --> 00:20:41,640
+CH3 مثل ال CH اللي متصلة بينتين CH3 تو اتعلمناها
+
+240
+00:20:42,940 --> 00:20:48,720
+eyes of rubel على سبيل المثال فبنذكر المجموعات و
+
+241
+00:20:48,720 --> 00:20:52,660
+لما يكونوا أكثر من نوع بنذكرهم alphabetically
+
+242
+00:20:52,660 --> 00:20:59,400
+بمعنى ال a قبل ال b قبل ال c قبل ال d واضح لما
+
+243
+00:20:59,400 --> 00:21:03,680
+نيجي نرتب ذكر المجموعات هذا بينتين متصل في كام
+
+244
+00:21:03,680 --> 00:21:07,860
+مجموعة؟ بينتين brom و chlorine مين اللي بدي أذكره
+
+245
+00:21:07,860 --> 00:21:11,690
+في الأول ال brom ولا ال chlorine؟لبروم طيب لما بدى
+
+246
+00:21:11,690 --> 00:21:16,010
+احدد الموقع بدى ارقم و هنا بتجينا دايما مشكلة انه
+
+247
+00:21:16,010 --> 00:21:20,110
+انا بقدر اقول الواحد من هذا الطرف او من هذا الطرف
+
+248
+00:21:20,110 --> 00:21:23,890
+يعني ممكن اقول واحد اتنين تلاتة اربعة خمسة و ممكن
+
+249
+00:21:23,890 --> 00:21:29,470
+اقول واحد اتنين تلاتة اربعة خمسة دائما في ال
+
+250
+00:21:29,470 --> 00:21:32,910
+organic بنقول بنستعمل قاعدة ال lower numbering
+
+251
+00:21:32,910 --> 00:21:39,070
+يعني لازم احصل على اقلترقيم فلاحظوا لو بدأت من هنا
+
+252
+00:21:39,070 --> 00:21:43,410
+الكلور ع اتنين و البروم ع تلاتة اتنين و تلاتة خمسة
+
+253
+00:21:43,410 --> 00:21:46,730
+كمجموع لو بدأت من هنا واحد اتنين تلاتة اربعة
+
+254
+00:21:46,730 --> 00:21:50,410
+البروم ع تلاتة و الكلور ع اربعة تلاتة و اربعة سبعة
+
+255
+00:21:50,410 --> 00:21:54,770
+اذا انه اقل ترقيم الترقيم اللي احنا عاملينه من هنا
+
+256
+00:21:54,770 --> 00:22:00,050
+بناء على ذلك هذا المركب لما نشوف اسمه كاملا بيصير
+
+257
+00:22:00,050 --> 00:22:07,080
+three bromo two chlorobentaneكلمة واحدة بدون ما
+
+258
+00:22:07,080 --> 00:22:09,880
+نقطع فراغات بينها لو كنا بنطبع على الكمبيوتر و
+
+259
+00:22:09,880 --> 00:22:16,660
+بنكتب بالإيد و دائما قبل الرقم بعده بنحط dash إذا
+
+260
+00:22:16,660 --> 00:22:21,760
+هذا المركب three promo two cloro بنتين و تكتب
+
+261
+00:22:21,760 --> 00:22:26,960
+ككلمة واحدة و دائما قبله بعد الرقم dash ما لم يكن
+
+262
+00:22:26,960 --> 00:22:30,740
+في البداية بس بيكون ايش ال dash بعده نعد من هنا
+
+263
+00:22:30,740 --> 00:22:37,020
+واحد اتنين تلاتة بمشيواحد اتنين تلاتة اربعة خمسة
+
+264
+00:22:37,020 --> 00:22:41,660
+بدا تتعب ممكن تعد من هنا واحد اتنين تلاتة اربعة
+
+265
+00:22:41,660 --> 00:22:45,680
+خمسة لما نعمل اكتر من محاولة بنلاحظ ان هو اطول
+
+266
+00:22:45,680 --> 00:22:50,800
+السلسلة واحد اتنين تلاتة اربعة خمسة ستة سبعة اذا
+
+267
+00:22:50,800 --> 00:22:57,280
+المركب اللي عند مشتقت السبعة هبتين هبتين متصل في
+
+268
+00:22:57,280 --> 00:23:03,720
+مجموعةمثل ومجموعة مثل تانية اقل ترقيم بيخلينا نرقم
+
+269
+00:23:03,720 --> 00:23:07,600
+من هنا مش من هنا لما يكون مجموعتين مثل ايش
+
+270
+00:23:07,600 --> 00:23:15,570
+بنستعمللهم؟ die لو كانوا تلاتةأربعة تترا خمسة بنتة
+
+271
+00:23:15,570 --> 00:23:20,810
+هكسة هبتة واضح اذا هذا و بنحدد مكانهم بنقول على
+
+272
+00:23:20,810 --> 00:23:25,370
+اتنين وعلى اربعة عندي مجموعتين مثل فلما بدي احط
+
+273
+00:23:25,370 --> 00:23:33,010
+الاسم بقول two فاصلة كمة four داش دائما بين الرقم
+
+274
+00:23:33,010 --> 00:23:37,310
+والاسم dimethyl heptane اذا هذا المركب two four
+
+275
+00:23:37,310 --> 00:23:38,370
+dimethyl
+
+276
+00:23:43,280 --> 00:23:49,260
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+277
+00:23:49,260 --> 00:23:50,120
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+278
+00:23:50,120 --> 00:23:53,500
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+279
+00:23:53,500 --> 00:23:56,620
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+280
+00:23:56,620 --> 00:24:02,520
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+281
+00:24:02,520 --> 00:24:10,940
+تختار أطول سلسلة تختار أبرضه إذا جرينا ورا أطول
+
+282
+00:24:10,940 --> 00:24:14,160
+سلسلة واحد، اتنين، تلاتة، أربعة، خمسة، ستة، سبعة
+
+283
+00:24:14,160 --> 00:24:17,760
+ممكن ننظر احتمالات تانية بنلاقيهم أقل، بنلاقيهم
+
+284
+00:24:17,760 --> 00:24:21,780
+أقل، إذا المركب اللي عندي سبعة إيش بيحمل على موقع
+
+285
+00:24:21,780 --> 00:24:28,060
+اتنين؟ مثل، على موقع خمسة؟ isopropyl، مين جاب ال
+
+286
+00:24:28,060 --> 00:24:32,100
+alpha بتيكاليه؟ ال isopropyl، إذا four على موقع
+
+287
+00:24:32,100 --> 00:24:37,120
+أربعة هان عفوا، four isopropyl, two methyl, هبتين
+
+288
+00:24:37,540 --> 00:24:44,380
+واضح؟ هذه هي طريقة التسمية أحياناً بتجينا إشكالية
+
+289
+00:24:44,380 --> 00:24:49,220
+صغيرة أنه لما نيجي نفتش على أطول سلسلة في مركب
+
+290
+00:24:49,220 --> 00:24:55,160
+بنلاحظ أنه ممكن يكون عنده نفس الطول جاي باتجاهين
+
+291
+00:24:55,160 --> 00:24:59,220
+مختلفين يعني لاحظوا هذا المركب نفسه و هذا المركب
+
+292
+00:24:59,220 --> 00:25:04,100
+نفسه و هذا المركبواضح؟ لما نيجي نعد من هنا واحد،
+
+293
+00:25:04,100 --> 00:25:07,940
+اتنين، تلاتة، اربعة، خمسة، ستة، سبعة، هاي سلسلة
+
+294
+00:25:07,940 --> 00:25:14,000
+طولها سبعة، كام تفرع طالع منها؟ اتنين طيب لو عدينا
+
+295
+00:25:14,000 --> 00:25:17,300
+من هان، واحد، اتنين، تلاتة، اربعة، خمسة، ستة،
+
+296
+00:25:17,300 --> 00:25:24,200
+سبعة، برضه سبعة، بصير كيف بدي اخد؟ هادي السبعة ولا
+
+297
+00:25:24,200 --> 00:25:29,360
+هادي السبعة؟وهنا في السابعة هذه منها تفرع واحد
+
+298
+00:25:29,360 --> 00:25:33,640
+فالقاعدة بتقولنا if there are two equally long
+
+299
+00:25:33,640 --> 00:25:37,820
+continuous chains it choose the one with most
+
+300
+00:25:37,820 --> 00:25:42,360
+branches اختار اللي فيها تفرعات اكتر هذه كام تفرع
+
+301
+00:25:42,360 --> 00:25:49,080
+طالع منها اتنين هذه كام تفرع طالع منها واحد واضح؟
+
+302
+00:25:49,080 --> 00:25:54,950
+اذا بنطلع احنا علىهدولة المركبين نفس طول السلسلة
+
+303
+00:25:54,950 --> 00:26:01,210
+سبعة وسبعة إذا تساوى طول السلسلة ما الحكم؟ عدد
+
+304
+00:26:01,210 --> 00:26:06,090
+التفرعات اللي أكثر تفرع هو اللي بنختاره ولذلك هذا
+
+305
+00:26:06,090 --> 00:26:11,430
+المركب لما نيجي نسميه في مجموعة مثل ومجموعة إثل
+
+306
+00:26:11,430 --> 00:26:17,030
+والترقيم من هنا أنهي اللي بتذكر في الأولال إثل إذا
+
+307
+00:26:17,030 --> 00:26:23,070
+عندي three إثل two مثل هبتين مابجيش أسميه هنا لو
+
+308
+00:26:23,070 --> 00:26:26,830
+اتخيلت أنه هذه مجموعة واحدة isopropyl three
+
+309
+00:26:26,830 --> 00:26:31,730
+isopropyl هبتين كان ممكن واحدة أول ما ييجي ع بالها
+
+310
+00:26:31,730 --> 00:26:34,610
+تتطلع زي هيك و تقولها يحامل مجموعة و حافظها
+
+311
+00:26:34,610 --> 00:26:38,430
+المجموعة isopropyl اتسميها isopropyl heptane هذه
+
+312
+00:26:38,430 --> 00:26:43,650
+التسمية تعتبر تسمية خاطئة المركب بهذا الشكل بناخد
+
+313
+00:26:43,650 --> 00:26:52,000
+التفرعاتالأكثر واضح بعد هذه المقدمة عن تسميات ال
+
+314
+00:26:52,000 --> 00:26:56,680
+alkanes بننتقل إلى دراسة بعض ال physical
+
+315
+00:26:56,680 --> 00:27:00,980
+properties لل alkanes الخاصية الأولى ال water
+
+316
+00:27:00,980 --> 00:27:05,240
+solubility الذوبان في الميه كلكم بتعرفوا البنزين
+
+317
+00:27:05,240 --> 00:27:10,320
+لو خدنا بنزين السيارة على الميه مابخلطش insoluble
+
+318
+00:27:10,320 --> 00:27:13,760
+واضح إذا ال alkanes they are water insoluble شو
+
+319
+00:27:13,760 --> 00:27:21,840
+السبب؟اللي هو انه البنزين وغيره وكل المركبات بنطبق
+
+320
+00:27:21,840 --> 00:27:27,160
+عليها قاعدة ذائبية like dissolve like يعني ال
+
+321
+00:27:27,160 --> 00:27:30,060
+polar compounds دي are soluble in polar compounds
+
+322
+00:27:30,060 --> 00:27:33,260
+ال non polar compounds in non polar compounds الآن
+
+323
+00:27:33,260 --> 00:27:37,060
+ال alkenes دي are non polar لا فيهم hydrogen
+
+324
+00:27:37,060 --> 00:27:39,720
+bonding ولا إشي شو القوة اللي بتحكمهم زي ما حكت
+
+325
+00:27:39,720 --> 00:27:44,900
+زملتكوا؟اللي هي ال London forces أو ال Vanderwaals
+
+326
+00:27:44,900 --> 00:27:49,540
+forces هي اللي مربطاهم البعض وهذه قوة ضعيفة ولذلك
+
+327
+00:27:49,540 --> 00:27:53,320
+برضه ال Alkanes هتلاحظوا ملاحظة ان نقاط غليانها
+
+328
+00:27:53,320 --> 00:27:58,400
+منخفضة لأن ارتباطها ضعيف يعني مثلا ال methane يمكن
+
+329
+00:27:58,400 --> 00:28:03,500
+عندناقص 168 بيغلي عبارة عن غاز ال ethane غاز ال
+
+330
+00:28:03,500 --> 00:28:10,140
+probane غاز ال butane غازبالمناسبة الميثين ..
+
+331
+00:28:10,140 --> 00:28:13,060
+الميثين عشان انتوا ما تخربطوش برضه و تتعلموا هذه
+
+332
+00:28:13,060 --> 00:28:18,360
+المعلومة الميثين هو الغاز الطبيعي بنسميه natural
+
+333
+00:28:18,360 --> 00:28:24,220
+gas وهذا الغاز الطبيعي بشكل عام بمشيوب أنبيبه
+
+334
+00:28:24,220 --> 00:28:28,860
+عملية إسالته وتعبئته بإستوانات زي الإستوانات
+
+335
+00:28:28,860 --> 00:28:33,700
+المنزلية عملية صعبةواضح؟ بده تقنيات صعبة جدا، مش
+
+336
+00:28:33,700 --> 00:28:38,140
+هو الغاز اللي بيجينا في قنابيب الغاز، الميثين مش
+
+337
+00:28:38,140 --> 00:28:41,220
+هو الغاز اللي بيجينا في قنابيب الغاز، يمكن الميثين
+
+338
+00:28:41,220 --> 00:28:46,240
+هو الغاز اللي مصر بتبيعه لإسرائيلبس نفسه ماحدش
+
+339
+00:28:46,240 --> 00:28:48,800
+ييجي يقول عبوا .. عبوا لنا ياف قنابيب غاز مش هو
+
+340
+00:28:48,800 --> 00:28:52,220
+هذا الغاز تبع القنابيب الغاز بيشغلوا فيه محطات
+
+341
+00:28:52,220 --> 00:28:56,140
+توليد و جايبينه بقنابيب معينة و كل شيء هذا اللي هو
+
+342
+00:28:56,140 --> 00:29:01,060
+ال natural gas الميثين لكن الغاز تبعنا و بيطلع من
+
+343
+00:29:01,060 --> 00:29:04,940
+التخمر بالمناسبة الميثين يعني الفضلات العضوية و
+
+344
+00:29:04,940 --> 00:29:09,870
+غيرها بتعرفوا ال bio gases و جزء ال energyطريقة من
+
+345
+00:29:09,870 --> 00:29:13,350
+خلال تخمير الفضلات ان نحصل على الميثين و نحصل على
+
+346
+00:29:13,350 --> 00:29:18,550
+ال energy لكن الغاز المنزلي هو عبارة عن خليط من
+
+347
+00:29:18,550 --> 00:29:24,840
+البروبين و البيوتين فهو غاز بتروليشفتوا الفرق بين
+
+348
+00:29:24,840 --> 00:29:29,340
+الغاز الطبيعي والغاز البترولي، الميثين و البروبين،
+
+349
+00:29:29,340 --> 00:29:32,940
+عفوا، البروبين و البيوتين اللي بتعبوا في الصوانات
+
+350
+00:29:32,940 --> 00:29:37,120
+و يسالوا بسهولة و بنضغطوا في الصوانة بسهولة اللي
+
+351
+00:29:37,120 --> 00:29:42,200
+هم الغاز البترولي اللي بيجي عندنامن عند البنتين
+
+352
+00:29:42,200 --> 00:29:47,020
+بيبدأ المركب يصير سائل لكن سهل التطاير بنتين،
+
+353
+00:29:47,020 --> 00:29:51,080
+هكسين، هبتين، لاحظوا بنزين السيارات دائما بنقول
+
+354
+00:29:51,080 --> 00:29:56,480
+عنه إيش؟ متطاير جدا، هو هكسين و هبتين إيش كل قصة
+
+355
+00:29:56,480 --> 00:30:01,480
+التطاير اللي موجودة في ال Alcans؟ إيش سببها؟ إن
+
+356
+00:30:01,480 --> 00:30:05,940
+الروابط اللي في ضعيفة هي London Forces واضح؟ كل
+
+357
+00:30:05,940 --> 00:30:10,910
+قصة الإرتباطات اللي ..لضعيفة في ال alkanes هي اللي
+
+358
+00:30:10,910 --> 00:30:16,510
+بتأدي ل boiling points منخفضة، إذا ال alkanes لهم
+
+359
+00:30:16,510 --> 00:30:21,360
+low boiling pointwhich increases upon increasing
+
+360
+00:30:21,360 --> 00:30:24,340
+the number of carbons in the alkane وهذا كلام منطق
+
+361
+00:30:24,340 --> 00:30:27,760
+انه ال alkane ب carbon واحدة بيكون ال boiling
+
+362
+00:30:27,760 --> 00:30:31,120
+point اقل كتير من ال alkane اللي ب 7 carbons اللي
+
+363
+00:30:31,120 --> 00:30:34,720
+ب 7 carbons سائل اللي ب carbon واحدة ال methane
+
+364
+00:30:34,720 --> 00:30:41,460
+عبارة عن غاز اذا كل ما زدنا احنا عدد ال carbons في
+
+365
+00:30:41,460 --> 00:30:44,240
+ال homologous series بتعرفوا homologous series
+
+366
+00:30:44,240 --> 00:30:46,980
+اللي هي المركبات اللي كل واحد بيكون بيفرج عن اللي
+
+367
+00:30:46,980 --> 00:30:54,280
+بعده بمقدار قداشCH2 لما أخدنا الجدول تبع الألكان
+
+368
+00:30:54,280 --> 00:30:58,940
+إذا رجعته شوية صغيرة جدول الألكان اللي هنطلع CH4
+
+369
+00:30:58,940 --> 00:31:04,900
+أول ألكان اللي بعده CH2 CH6 ما الفرق بينهما CH2 لو
+
+370
+00:31:04,900 --> 00:31:10,080
+أخدنا CH3 CH8 إيش الفرق بينهم؟CH2 CH2 هذه السلسلة
+
+371
+00:31:10,080 --> 00:31:13,920
+اللي كل مركب بيفرج عن اللي بعده CH2 بنسميها
+
+372
+00:31:13,920 --> 00:31:18,520
+homologous series واضح فكل ما بيزيد عدد ال carbons
+
+373
+00:31:18,520 --> 00:31:26,220
+بتزيد نقطة غليان الألكين الآن أحيانا الألكين في
+
+374
+00:31:26,220 --> 00:31:30,700
+جزء منها زي ما قلنا it's chain-like وفي جزء منها
+
+375
+00:31:30,700 --> 00:31:37,370
+branchedفلو طلعنا مثلا على البنتين، البنتين ممكن
+
+376
+00:31:37,370 --> 00:31:40,750
+يكون على شكل سلسل، واحد، اتنين، تلاتة، اربعة، خمسة
+
+377
+00:31:40,750 --> 00:31:44,250
+وممكن يكون على شكل تفرع كربونا وطالع منها اربع
+
+378
+00:31:44,250 --> 00:31:48,010
+كربونات هذا المركب اللي هو كربونا بالوسط وطالع
+
+379
+00:31:48,010 --> 00:31:55,590
+منها اربع مركبات بيسموه new بنتينالان هو اللي له
+
+380
+00:31:55,590 --> 00:32:01,230
+boiling point أعلى ال can ل ال chain ولا ل ال
+
+381
+00:32:01,230 --> 00:32:06,070
+branches مع الاختبار بإنه المقارنة تكون لنفس العدد
+
+382
+00:32:06,070 --> 00:32:10,030
+من ال carbons يعني لما نحكي عن خمسة هنا خمسة هنا
+
+383
+00:32:10,030 --> 00:32:15,450
+دائما و أبدا ال branches ال cans they have lower
+
+384
+00:32:15,450 --> 00:32:20,500
+boiling points than ال chain ال cansدائما الالكين
+
+385
+00:32:20,500 --> 00:32:26,800
+المتفرع نقطة غليانه اقل من الالكين المستقيم او
+
+386
+00:32:26,800 --> 00:32:31,980
+المتسلسل ايش السبب؟ السبب لو كنت تطلعوا كيف
+
+387
+00:32:31,980 --> 00:32:36,240
+الجزيئات بتيجي على بعض والارتباط بينها فإذا أنا
+
+388
+00:32:36,240 --> 00:32:40,500
+بتطلع مثلا في الالكين ال .. ال .. ال chain الكين
+
+389
+00:32:40,500 --> 00:32:46,600
+بتلاحظوا انه في ..مسافة ارتباط واتصاق كبيرة يعني
+
+390
+00:32:46,600 --> 00:32:52,380
+كله بالتصق ببعضه تماما زى ما اجى احط مثلا اربع
+
+391
+00:32:52,380 --> 00:32:57,260
+مكعبات فوق بعض بيجوا فوق بعض بسهولة المكعبات اه
+
+392
+00:32:57,260 --> 00:33:01,990
+لكن هذا الشكل صار أشفه ما يكونبالكورة لو تخيلتوا
+
+393
+00:33:01,990 --> 00:33:06,250
+تحطوا أربع كورات بين بعض جداش نسبة التلامس بين
+
+394
+00:33:06,250 --> 00:33:10,030
+الأربع كورات اللي بدها تعمل bonding إذا بتطلعوا
+
+395
+00:33:10,030 --> 00:33:13,650
+هاي هدول الجزيات بس من هنا و من هنا الارتباط بينما
+
+396
+00:33:13,650 --> 00:33:19,230
+في هذه الحالةكل هذه مسافة ارتباط، اذا وين الارتباط
+
+397
+00:33:19,230 --> 00:33:22,870
+بيكون اكتر؟ في ال branched ولا في ال chain
+
+398
+00:33:22,870 --> 00:33:26,130
+compounds؟ في ال chain compounds فدائما ال chain
+
+399
+00:33:26,130 --> 00:33:34,410
+compounds بيكون لهم نقطة غليان اعلى من ال branched
+
+400
+00:33:34,410 --> 00:33:37,910
+compounds المقابلين لهم، يعني لما تقارنوا دائما
+
+401
+00:33:37,910 --> 00:33:41,590
+قارنوا أشياء من نفس النوع، خمسة مع خمسة، ستة مع
+
+402
+00:33:41,590 --> 00:33:44,350
+ستة، سبعة مع سبعة، و هكذا
+
+403
+00:33:48,530 --> 00:33:53,530
+بنجي لشغلة جديدة اللى هى ال conformations of ال
+
+404
+00:33:53,530 --> 00:33:58,230
+canes لما بدنا ندرس حقيقة ال conformations of ال
+
+405
+00:33:58,230 --> 00:34:02,650
+canes يفضل أننا ندرسها من خلال .. من خلال ال
+
+406
+00:34:02,650 --> 00:34:09,650
+models فلو عملنا احنا model لجزء ال E2 لو عملنا
+
+407
+00:34:09,650 --> 00:34:16,890
+model لجزء ال E2 وقلنا له انه ميغلبناشتطلعوا هذا
+
+408
+00:34:16,890 --> 00:34:21,550
+جزء ال A2 إذا بتطلعوا أنا ماسكه بطريقة بحيث مخلي
+
+409
+00:34:21,550 --> 00:34:26,170
+كل ذرّة قبالك تانية بظبط ولا لأ؟ طيب لو لفته شوية
+
+410
+00:34:26,170 --> 00:34:30,450
+بطلوا الذرات قبال بعض هل يا تورا صار عندي جزء
+
+411
+00:34:30,450 --> 00:34:34,750
+جديد؟ لو لفته كمان شوية شكل جديد، كمان شوية شكل
+
+412
+00:34:34,750 --> 00:34:38,290
+جديد ممكن أصل لو أنا بلفه أنه تصير هذه عكس هذه
+
+413
+00:34:38,290 --> 00:34:42,810
+يعني تطلعوا هذه لفوق وهذه لتحت لو لفت كمان شوية
+
+414
+00:34:42,810 --> 00:34:48,780
+شكل جديد، شكل جديد، بعود يرجع؟إجبال بعض إذا هذه
+
+415
+00:34:48,780 --> 00:34:54,200
+عبارة عن مجموعة أشكال ناشئة عن عملية إيش الدوران
+
+416
+00:34:54,200 --> 00:34:57,720
+طب لو بدأ أقول قداش عدد الأشكال الناشئة عن الدوران
+
+417
+00:34:57,720 --> 00:35:03,480
+infinity يعني لو بدأت ألف عشر عشر درجة و أزيد و
+
+418
+00:35:03,480 --> 00:35:06,940
+أزيد و أزيد و أزيد عند عدد لا نهائي من الأشكال
+
+419
+00:35:06,940 --> 00:35:11,420
+تنتج عن الدوران عند عدد لا نهائي من الأشكال تنتج
+
+420
+00:35:11,420 --> 00:35:18,220
+عن الدوران طيب إذاهل يطر الأثين جزئ ولا عدد لا
+
+421
+00:35:18,220 --> 00:35:22,660
+نهائي من الجزيئات؟ إذا أنا بقول هاي جزئ، هاي حاجة
+
+422
+00:35:22,660 --> 00:35:25,680
+جديدة، هاي حاجة جديدة، هاي حاجة جديدة، هو أثين ولا
+
+423
+00:35:25,680 --> 00:35:31,980
+عدد لا نهائي من الأثين؟ الحقيقة الموضوع بتقدر
+
+424
+00:35:31,980 --> 00:35:37,180
+تشبهه بالمروحة، المروحة لما بتلوف بتكون بعد لحظة
+
+425
+00:35:37,180 --> 00:35:40,820
+هيك، بعد لحظة هيك، بعد لحظة هيك، لكنها في حالة
+
+426
+00:35:40,820 --> 00:35:46,840
+دوران دائم فتبقى مروحة واحدةولو بتمر بعدد لا نهاء
+
+427
+00:35:46,840 --> 00:35:50,860
+من الأشكال، وهناك في ال organic chemistry دوران
+
+428
+00:35:50,860 --> 00:35:54,760
+دائم أبدي لا يتوقف حول الرابطة الأحدية، يعني هذا
+
+429
+00:35:54,760 --> 00:35:59,900
+الجزء طول الوقت هو بلف زي هيك، لكن هو يبقى جزء
+
+430
+00:35:59,900 --> 00:36:04,580
+واحدهذا الجزء يبقى إيش؟ جزء واحد اسمه إثنين، الآن
+
+431
+00:36:04,580 --> 00:36:08,580
+هذه الأشكال الناشئة عن الدوران بنسميها conformers،
+
+432
+00:36:08,580 --> 00:36:11,680
+conformers و الظاهرة كلها بنقولها conformations
+
+433
+00:36:11,680 --> 00:36:16,340
+فال conformers they are stereoisomers أشكال بس
+
+434
+00:36:16,340 --> 00:36:21,760
+اختلفت بالشكل الفراغي، هل نقلت رابطه من مكانها؟
+
+435
+00:36:21,760 --> 00:36:26,740
+أه، stereoisomers that are interconvertible،
+
+436
+00:36:26,740 --> 00:36:30,120
+بتتحولوا من واحد للتاني للتالت للرابع للخمس by؟
+
+437
+00:36:30,460 --> 00:36:35,160
+rotation إذا ال conformers أشكال بتتحول من واحد
+
+438
+00:36:35,160 --> 00:36:39,760
+للثاني للتالت من خلال ال rotation الآن هنا بدكم
+
+439
+00:36:39,760 --> 00:36:44,380
+تلاحظوا أنه أنا عندي اثنين واحد بعدد لا نهائي من
+
+440
+00:36:44,380 --> 00:36:49,500
+الدورانات زي ما عندي مروحة واحدة لكن ماخدة أشكال
+
+441
+00:36:49,500 --> 00:36:53,520
+لا نهائية وهي بتدورفي ال organ chemistry بالحب
+
+442
+00:36:53,520 --> 00:36:58,220
+احنا نرسم شكلين من هدولة الشكل اللي بيكونوا هدولة
+
+443
+00:36:58,220 --> 00:37:02,700
+فيه جبال بعض بالظبط و بنعطيه اسم و الشكل اللي
+
+444
+00:37:02,700 --> 00:37:05,860
+بتكون كل واحدة عكس التانية يعني إذا بتلاحظوا الآن
+
+445
+00:37:05,860 --> 00:37:11,240
+هذه و هذه إيش مالهم عكس بعض تماما و هذه و هذه عكس
+
+446
+00:37:11,240 --> 00:37:15,500
+بعض و هذه و هذه عكس بعض كيف الآن بنيجي بنرسم هذه
+
+447
+00:37:15,500 --> 00:37:19,920
+الأشكال كيف الآن بنيجي بنرسم هذه الأشكال بإمكاننا
+
+448
+00:37:19,920 --> 00:37:27,440
+احنانتطلع على الشكل بهذا زي ما انا ماسكه تماما، في
+
+449
+00:37:27,440 --> 00:37:33,220
+عندكم رابطة هنا شايفينها؟ في عندي مجمعتين للأمام،
+
+450
+00:37:33,220 --> 00:37:38,720
+المجمعتين للأمام كيف بعملهم؟ ب solid wedge و في
+
+451
+00:37:38,720 --> 00:37:44,240
+عندي مجمعتين للخلف كيف برسمهم؟ dash wedge و في
+
+452
+00:37:44,240 --> 00:37:48,930
+عندي هدولة بيكونوا في مستوى اللوحةملاحظين؟ إذا أنا
+
+453
+00:37:48,930 --> 00:37:53,530
+ممكن أرسم بهذه الطريقة، أنظر للجزء بهذا الشكل،
+
+454
+00:37:53,530 --> 00:37:57,670
+أقول، في عندي تنتين للأمام، solid wedge، تنتين
+
+455
+00:37:57,670 --> 00:38:02,450
+للخلف، dashed wedge، وعلى شكل الخط اللي موجودة في
+
+456
+00:38:02,450 --> 00:38:07,490
+مستوى اللوحة هذا الشكل اللي فيه المجموعات قبال
+
+457
+00:38:07,490 --> 00:38:11,990
+بعض، بنسميه Clips Conformation، إيش معناه Clips؟
+
+458
+00:38:13,360 --> 00:38:18,260
+متطابق الشكل المتطابق حتى ال clips اللي بتمسكوا
+
+459
+00:38:18,260 --> 00:38:22,660
+فيه الدفاتر ليش بيسموه clips؟ لأنه بيطبق و بيجيب
+
+460
+00:38:22,660 --> 00:38:26,620
+الأشياء مع بعض واضح؟ يعني كلمة clips دائما
+
+461
+00:38:26,620 --> 00:38:30,260
+بنستعملها لإيش؟ للتطابق الدبوس اللي بنشبك فيه
+
+462
+00:38:30,260 --> 00:38:34,180
+ورقتين شو بنسميه؟ clips فهذا الشكل بنقول عنه
+
+463
+00:38:34,180 --> 00:38:38,840
+eclipse confirmation ممكن نرسمه بطريقة ال dash
+
+464
+00:38:38,840 --> 00:38:45,310
+wedgeممكن ننظرله بزاوية أخرى، ممكن ننظرله بزاوية
+
+465
+00:38:45,310 --> 00:38:50,410
+أخرى، نرسمه بطريقة نتخيله أشبه ما يكون بالحصان
+
+466
+00:38:50,410 --> 00:38:54,950
+الخشبي اللي بيلعب عليه الجنباز، بتعرفوا الحصان
+
+467
+00:38:54,950 --> 00:38:58,910
+اللي بيلعب عليه الجنباز؟ لو حطينا هدولة زي هيك،
+
+468
+00:38:58,910 --> 00:39:04,040
+انسوا هدولة التنتين، إيش بيكون؟هيو زي شكل الحصان،
+
+469
+00:39:04,040 --> 00:39:08,120
+له رجلتين، فاحنا ممكن نرسمه زي هيك، بهادي الحالة
+
+470
+00:39:08,120 --> 00:39:17,780
+بنرسم خط مائل وبنرسم مع خط اللوح، خطين لفوجي مثله
+
+471
+00:39:17,780 --> 00:39:22,900
+هدول الهيدروجينات، التنتين، وبننزل لتحت و لتحت
+
+472
+00:39:23,340 --> 00:39:28,400
+مجمعتين فلاحظوا هذه طريقة ترسم غير عن هذه الطريقة
+
+473
+00:39:28,400 --> 00:39:31,700
+هذه الطريقة بنقول عنها ال sew horse يعني بتصيروا
+
+474
+00:39:31,700 --> 00:39:34,900
+شايفينه انتوا هيك عن الجانب و هاي المجمعتين اللي
+
+475
+00:39:34,900 --> 00:39:39,800
+لتحت زي تماما الحصان الخشبي لما بدكوا تعملوها
+
+476
+00:39:39,800 --> 00:39:45,930
+بدكوا ترسموا خط مائل خطين لفوق بيعنوهالمجمعتين
+
+477
+00:39:45,930 --> 00:39:49,310
+اللي قبل بعض بزام هدول لفوق، اذا هدول التنتين وان
+
+478
+00:39:49,310 --> 00:39:52,910
+بدهم يكونوا؟ لتحت، هدول التنتين وان بدهم يكونوا؟
+
+479
+00:39:52,910 --> 00:39:56,290
+لتحت، اذا هذه طريقة تانية لرسم ال eclipse
+
+480
+00:39:56,290 --> 00:40:01,230
+confirmation باستعمال ال Sohur's formula ممكن
+
+481
+00:40:01,230 --> 00:40:05,290
+تنظروا للجزء بنظرة تالتة تماما، بدل ما تنظروله عن
+
+482
+00:40:05,290 --> 00:40:08,970
+الجنب زي هيك او زي هيك ممكن تنظروله من الأمام
+
+483
+00:40:08,970 --> 00:40:14,960
+تخيلوا لو بتطلع عليه زي هيك، ايش بتشوفوا انتوا؟بس
+
+484
+00:40:14,960 --> 00:40:21,800
+تلاتة واللي ورا مخفيين وراهم اه فبهذه الحالة ممكن
+
+485
+00:40:21,800 --> 00:40:27,200
+يرسموا بيعملوا دائرة بيطلع من المركز تبعها واحد
+
+486
+00:40:27,200 --> 00:40:31,120
+اتنين تلاتة هذه الدائرة بتعبر عن التلاتة اللي قدام
+
+487
+00:40:31,120 --> 00:40:36,360
+وبيطلع من المحيط تبعها كمان واحد اتنين تلاتة من
+
+488
+00:40:36,360 --> 00:40:42,280
+جنب هدولة يعني انهم وين جايين خلف منهاواضح؟ هذه
+
+489
+00:40:42,280 --> 00:40:47,040
+الطريقة بيسموها طريقة in human في رسم اللي هي ال
+
+490
+00:40:47,040 --> 00:40:50,840
+conformations of إيثين لاحظوا كل هذا عبارة عن
+
+491
+00:40:50,840 --> 00:40:55,800
+الشكل إيش؟ المتطابق، الآن لو بدي أجي للشكل
+
+492
+00:40:55,800 --> 00:41:00,380
+المتعاكس بنسميه staggered conformation خلينا نبدأ
+
+493
+00:41:00,380 --> 00:41:05,480
+من هنا لو خلينا هذا زي هيك، الآن انتوا بإمكانكوا
+
+494
+00:41:05,480 --> 00:41:10,780
+تشوفوا قداش؟ ستة مش تلاتةلو رسمتوا التلاتة اللي
+
+495
+00:41:10,780 --> 00:41:16,580
+قدام من مركز الدائرة، هايهم، واحد، اتنين، تلاتة،
+
+496
+00:41:16,580 --> 00:41:20,140
+التلاتة اللي من ورا من المحيط دايما بنرسمها،
+
+497
+00:41:20,140 --> 00:41:22,920
+التلاتة الهيدروجينات اللي قدام من المركز، التلاتة
+
+498
+00:41:22,920 --> 00:41:27,620
+اللي ورا من محيط الدائرة، فلاحظوا انتوا قادرين هنا
+
+499
+00:41:27,620 --> 00:41:33,490
+تشوفوا أيش؟ الستةهي هدولة بهذا الشكل، هذه طالعة من
+
+500
+00:41:33,490 --> 00:41:36,350
+الجانب اللي هان، هذه طالعة من الجانب اللي هان من
+
+501
+00:41:36,350 --> 00:41:39,530
+المحيط اللي بنرسمها، وهذه طالعة من الجانب اللي
+
+502
+00:41:39,530 --> 00:41:43,930
+موجود عندى، اذا هى طريقة رسم ال staggered
+
+503
+00:41:43,930 --> 00:41:49,050
+conformation بطريقة in human طيب، الان لو هذه ال
+
+504
+00:41:49,050 --> 00:41:53,090
+staggered conformation بدكوا ترسموها بطريقة مثلا
+
+505
+00:41:53,090 --> 00:42:00,500
+ال dash wedge اتخيلوا هى الرابطة okayخلينا نرسم زي
+
+506
+00:42:00,500 --> 00:42:07,000
+ما هي هان هيك، هاي الشكل، إيش بتلاحظوا عندكوا هان
+
+507
+00:42:07,000 --> 00:42:13,600
+لفوق؟ على اتجاهكم؟ ال solid و هادى؟ برضه على
+
+508
+00:42:13,600 --> 00:42:17,420
+اتجاهكم، بس واحدة لفوق واحدة لتحت، هاي نرسموا
+
+509
+00:42:17,420 --> 00:42:21,660
+واحدة لفوق واحدة لتحت، في الخلف إيش عندكم؟ ال dash
+
+510
+00:42:21,660 --> 00:42:25,960
+واحدة لفوقواحدة لتحت وهدولة اللي بيكونوا على
+
+511
+00:42:25,960 --> 00:42:31,660
+المستوى اللي برسمهم بخط عادى ال H هدى و ال H هدى
+
+512
+00:42:31,660 --> 00:42:37,100
+واضح؟ اذا انا بهدوء بإمكاني ارسم الشكل باستعمال
+
+513
+00:42:37,100 --> 00:42:41,140
+Newman باستعمال ال dash wedge بإمكاني ارسمه بطريقة
+
+514
+00:42:41,140 --> 00:42:47,120
+الحصان اكيد يعني لو حطيت هذا الخط بسمائل شوية بنزل
+
+515
+00:42:47,120 --> 00:42:52,200
+واحدة لتحتوالتانية إذا هذه نزلة لتحت، هذولة
+
+516
+00:42:52,200 --> 00:42:56,840
+التنتين وين بيكونوا؟ وإذا هذه طالعة لفوق، هذولة
+
+517
+00:42:56,840 --> 00:43:01,140
+التنتين وين بيكونوا؟ لتحت، هذه طريقة الرسم
+
+518
+00:43:01,140 --> 00:43:06,540
+باستعمال ال saw horse إذا بإمكاني أنا أرسم ل clips
+
+519
+00:43:06,540 --> 00:43:08,980
+confirmation و ل staggered confirmation و هذا
+
+520
+00:43:08,980 --> 00:43:12,300
+الكلام لازم تعمله عليه تدريب بإيديكوا في البيت
+
+521
+00:43:12,300 --> 00:43:18,170
+باستعمال ال dash wedgeأو ال saw horse أو ال human
+
+522
+00:43:18,170 --> 00:43:22,910
+projection اللي هو أسقاط ال human لحد هيك بننتهي
+
+523
+00:43:22,910 --> 00:43:24,050
+اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6183d79f6752dac218448b5a9fd8615ed8d6f931
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/1v9tSZi7Fvg_raw.srt
@@ -0,0 +1,2100 @@
+1
+00:00:13,260 --> 00:00:17,620
+اليوم ان شاء الله بنبدأ الفصل التاني الموضوع اللى
+
+2
+00:00:17,620 --> 00:00:21,280
+عندنا زى ما انتوا شايفين اللى هى المجموعة الاولى
+
+3
+00:00:21,280 --> 00:00:25,000
+من المجموعات الوظيفية مجموعة ال alkanes و ال
+
+4
+00:00:25,000 --> 00:00:28,600
+cycloalkanes و الحصة الماضية احنا حكينا ان ال
+
+5
+00:00:28,600 --> 00:00:35,830
+alkanes بيمتازوا ان موجود فيهم رابطة أحديةالان اذا
+
+6
+00:00:35,830 --> 00:00:40,730
+بدنا نطلع على تصنيف المراكبات العضوية ال alkanes
+
+7
+00:00:40,730 --> 00:00:44,990
+حقيقة و ال cycloalkanes يعني المراكبات حلقية يعني
+
+8
+00:00:44,990 --> 00:00:49,750
+يا المراكب بيكون عبارة عن سلسلة مفتوحة يا اما
+
+9
+00:00:49,750 --> 00:00:54,470
+بيكون عبارة عن حلقة الحالتين بيكونوا كلهم روابط
+
+10
+00:00:54,470 --> 00:00:59,950
+احدية الان احنا المراكبات الليبتتكون من ال
+
+11
+00:00:59,950 --> 00:01:04,950
+hydrogen و ال carbons بيسموها hydrocarbons الآن ال
+
+12
+00:01:04,950 --> 00:01:10,090
+hydrocarbons هذه بيقسموها إلى نوعين اما انه تكون
+
+13
+00:01:10,090 --> 00:01:14,970
+saturated بمعنى مشبعة معنى saturated انه مافيش
+
+14
+00:01:14,970 --> 00:01:21,950
+فيها غير روابط و حادية single bondsو unsaturated
+
+15
+00:01:21,950 --> 00:01:25,390
+بيكون فيها multiple bonds multiple bonds يعني
+
+16
+00:01:25,390 --> 00:01:28,830
+يبدوا يكونوا double bond يا triple bond مافيش اكثر
+
+17
+00:01:28,830 --> 00:01:34,690
+من هيك يعني يا رابطة زوجية يا رابطة ثلاثيةبشكل عام
+
+18
+00:01:34,690 --> 00:01:39,550
+هناك علاقة ما بين عدد الكربون وعدد الهيدروجين لأي
+
+19
+00:01:39,550 --> 00:01:44,950
+جزء الكان ليش لأنه النسبة ثابتة بمعنى زي ما حكي
+
+20
+00:01:44,950 --> 00:01:48,750
+الحصة الماضية الكربون دايما بياخد كام رابطة أربعة
+
+21
+00:01:48,750 --> 00:01:52,450
+الهيدروجين دايما بياخد رابطة بناء على ذلك لو بدنا
+
+22
+00:01:52,450 --> 00:01:57,340
+نعمل أي الكانهنلاحظ ان علاقة الكربون والهيدروجين
+
+23
+00:01:57,340 --> 00:02:02,820
+نسبة ثابت هذه العلاقة هي عبارة عن cn h2n plus 2
+
+24
+00:02:02,820 --> 00:02:09,280
+مثلا هي عندي انا جزء عبارة عن كام كربون C2 لما
+
+25
+00:02:09,280 --> 00:02:14,580
+اقول اتنين في اتنين زاد اتنين ستة بتلاحظوا عندكم
+
+26
+00:02:14,580 --> 00:02:20,280
+ست ذرات هيدروجين هذا جزء ال E2 لو بدنا نتطلع مثلا
+
+27
+00:02:20,280 --> 00:02:26,500
+على جزءالبروبين لو بدنا نطلع جزء البروبين عندنا
+
+28
+00:02:26,500 --> 00:02:33,580
+C3H تقدروا تعدوهم تلاتة و اتنين و تلاتة تمانية H8
+
+29
+00:02:33,580 --> 00:02:34,940
+فلو قولنا اتنين
+
+30
+00:02:38,900 --> 00:02:45,480
+الصيغة العامة للالكينز CNH2N الان ال Cycloalkane
+
+31
+00:02:45,480 --> 00:02:52,300
+مش مركبات حلقية مش مركبات حلقية مش مركبات مفتوحة
+
+32
+00:02:52,300 --> 00:02:58,070
+مركبات حلقية بمعنى انا بدي اشيلبدي أشيل
+
+33
+00:02:58,070 --> 00:03:02,030
+هيدروجينتين من الألكين يعني عشان أعمل cycle ألكين
+
+34
+00:03:02,030 --> 00:03:07,650
+عشان أعمل حلقة بدي أشيل هيدروجنتين و أسكر على شكل
+
+35
+00:03:07,650 --> 00:03:13,740
+حلقة بهذا الشكل لحظة انا صار عندي مركب حلقيأيش
+
+36
+00:03:13,740 --> 00:03:17,820
+اللي عملته انا لما سويت حلقة شيلت هيدروجينتين مع
+
+37
+00:03:17,820 --> 00:03:23,200
+رابطة واضح فالصيغة العامة لل Cycloalkanes ايش
+
+38
+00:03:23,200 --> 00:03:28,180
+بتطلع فى هذه الحالة CNH2N اللي بلفته راحت لإن انا
+
+39
+00:03:28,180 --> 00:03:32,980
+شيلت هيدروجنتين واضح فال Cycloalkanes هي مثال
+
+40
+00:03:32,980 --> 00:03:37,680
+عليهم هذا المركب بتكون عبارة عن CNH2N يعني لما
+
+41
+00:03:37,680 --> 00:03:43,290
+عندي C3F6 واضح هاي الفرق ال Cycloalkane على
+
+42
+00:03:43,290 --> 00:03:48,190
+الalkane كصيغة عامة الان ال unsaturated
+
+43
+00:03:48,190 --> 00:03:52,170
+hydrocarbons
+
+44
+00:03:52,170 --> 00:03:57,130
+منهم ال alkenes ال alkenes اللي فيهم double bond
+
+45
+00:03:57,130 --> 00:04:00,430
+الان لاحظوا لو بدى اعمل من هنا alkene يعني بدى
+
+46
+00:04:00,430 --> 00:04:06,000
+اشيل برضهرابطة مع هيدروجينة زي ما عملت في ال cycle
+
+47
+00:04:06,000 --> 00:04:10,540
+alkane و أتني هذه بشكل معين بحيث أعمل double bond
+
+48
+00:04:10,540 --> 00:04:17,360
+هاي جزء الاثيلين اذا ال alkenes برضه اعملته من
+
+49
+00:04:17,360 --> 00:04:21,340
+خلال ايش انه شيلت هيدروجينتين اذا ايش الصيغة
+
+50
+00:04:21,340 --> 00:04:25,960
+العامة بتاعتهم؟CNH2N بتلاحظوا بهاد الحالة ان
+
+51
+00:04:25,960 --> 00:04:30,220
+الصيغة العامة لل Cycloalkynes و الصيغة العامة لل
+
+52
+00:04:30,220 --> 00:04:35,140
+Alkenes نفس الاشي عشان اكون double bond او عشان
+
+53
+00:04:35,140 --> 00:04:40,860
+اكون حلقة بيلزمني ان اشيل هيدروجينتين واضح عشان
+
+54
+00:04:40,860 --> 00:04:43,480
+اكون double bond او اكون حلقة بيلزمني اشيل
+
+55
+00:04:43,480 --> 00:04:48,780
+هيدروجنتين الان لو بدى اكون رابطة اضافية triple
+
+56
+00:04:48,780 --> 00:04:54,020
+bond عشان احصل على الalkynes بدى اشيلكمان
+
+57
+00:04:54,020 --> 00:04:58,340
+هيدروجينتين هي هيدروجينة مع رابطتها و هي التانية و
+
+58
+00:04:58,340 --> 00:05:03,420
+بعد هيك اذا ال model بيسمح طب هيعملنا triple bond
+
+59
+00:05:03,420 --> 00:05:09,440
+واضح؟ اذا لتكوين اي رابطة اضافية بده اشيل
+
+60
+00:05:09,440 --> 00:05:12,620
+هيدروجينتين لتكوين اي حلقة اضافية بده اشيل
+
+61
+00:05:12,620 --> 00:05:17,160
+هيدروجنتين في هذا الحالة لو بده اطلع على ال triple
+
+62
+00:05:17,160 --> 00:05:21,380
+bonds او ال alkines لما يكون عند one triple bond
+
+63
+00:05:21,380 --> 00:05:28,570
+شو الصيغة العامة بدها تكون؟CNH2N-2 بمعنى لما يكون
+
+64
+00:05:28,570 --> 00:05:34,990
+عندى اتنين بدي اقول C2H2X2 اربع ناقص اتنين اتنين
+
+65
+00:05:34,990 --> 00:05:39,550
+اذا هذا المركب اللى هو أبسط الكاين الاسيتيلين بدي
+
+66
+00:05:39,550 --> 00:05:48,510
+يكون C2H2 صيغته العامة CNH2N-2 واضح هذه بالنسبة
+
+67
+00:05:48,510 --> 00:05:53,930
+للصيغاتمن ال hydrocarbons غير المشبعة ال aromatic
+
+68
+00:05:53,930 --> 00:05:57,070
+compounds اللي هم المركبات اللي زي البنزين اللي
+
+69
+00:05:57,070 --> 00:06:01,590
+فيهم حلقة و عدة double bonds واضح؟ و هدولة بناخدهم
+
+70
+00:06:01,590 --> 00:06:09,170
+احنا بفصل كامل اللي هو الفصل الرابع بنرجع لهم الان
+
+71
+00:06:09,170 --> 00:06:14,310
+لو اجينا نتعرف على ال alkanes و أشكالها بنلاحظ انه
+
+72
+00:06:14,310 --> 00:06:20,090
+احنا ممكن يكون عندنا carbonتنتين تلاتة أربعة خمسة
+
+73
+00:06:20,090 --> 00:06:24,950
+العدد عندنا مفتوح العدد عندنا مفتوح لو عندنا one
+
+74
+00:06:24,950 --> 00:06:30,450
+carbon و بيكون المركب اسمه methane و حسب القاعدة
+
+75
+00:06:30,450 --> 00:06:33,950
+التسمية اللي .. حسب قاعدة العدد اللي أخدناها
+
+76
+00:06:33,950 --> 00:06:39,370
+الصيغة شو بده تكون CH4 carbon تين بيصير المركب
+
+77
+00:06:39,370 --> 00:06:48,230
+اثان تلاتة بروبين أربعة بيوتين خمسةالستة هكسين
+
+78
+00:06:48,230 --> 00:06:54,370
+السبعة هبتين التمانية أكتين التسعة نونين والعشرة
+
+79
+00:06:54,370 --> 00:06:59,440
+ديكان واضح؟الان هذه المُركّبات بهذه الأسماء هي
+
+80
+00:06:59,440 --> 00:07:04,280
+لمُركّبات الـ carbons تبعتها متسلسلة ورا بعض، الان
+
+81
+00:07:04,280 --> 00:07:07,660
+ممكن يصير عندى تفرعات بتصير مُركّبات جديدة، يعني
+
+82
+00:07:07,660 --> 00:07:12,700
+لما أحط مثلا set carbonate ورا بعض عشكل سلسلة
+
+83
+00:07:12,700 --> 00:07:16,600
+chain، هذا الـ hexane، الان أنا ممكن أحط أربعة أو
+
+84
+00:07:16,600 --> 00:07:20,480
+أعمل تفرع اتنين، بيصير مُركّب جديد، بنتعلم تسميته،
+
+85
+00:07:20,480 --> 00:07:26,450
+فهذه الأسماء للسلاسلالمستقيمة للسلاسل المستقيمة
+
+86
+00:07:26,450 --> 00:07:31,210
+حقيقة هذه السلاسل بورسموها على الشكل اللي بيسموه
+
+87
+00:07:31,210 --> 00:07:35,810
+ال zigzag بتعرفوا ال zigzag؟ في الخياطة بيعملوا
+
+88
+00:07:35,810 --> 00:07:41,370
+غرزة zigzag هيك يعني هي ال zigzag هذا
+
+89
+00:07:41,370 --> 00:07:45,470
+الشكل zigzag يعني مش متعودين نعمله المركب زي هيك
+
+90
+00:07:45,470 --> 00:07:48,650
+بهذا الخط لأ في ال organ chemistry بنعمل zigzag
+
+91
+00:07:48,650 --> 00:07:52,190
+بين كل carbon والتانية ولو أنتوا حقيقة بتكونوا
+
+92
+00:07:52,190 --> 00:07:59,020
+اتلاحظواOkay هذا الشكل اللي هو ال zigzag او الشكل
+
+93
+00:07:59,020 --> 00:08:02,660
+المتعرج و دايما لما بدكوا ترسم على لو بدكوا تعملوا
+
+94
+00:08:02,660 --> 00:08:08,220
+عشرة carbons بدكوا تمشوا بهذا الشكل واضح؟ بهذا
+
+95
+00:08:08,220 --> 00:08:08,660
+الشكل
+
+96
+00:08:11,800 --> 00:08:15,880
+شغلة جديدة اللي هي ال alkyl groups او مجموعات ال
+
+97
+00:08:15,880 --> 00:08:21,020
+alkyl الان كل جزء organic له شكل له عدد من ال
+
+98
+00:08:21,020 --> 00:08:26,260
+carbons له عدد من ال hydrogens لو اي جزء من جزيئات
+
+99
+00:08:26,260 --> 00:08:31,220
+ال organic شيلنا منه hydrogen واحدةهذه الهيدروجين
+
+100
+00:08:31,220 --> 00:08:35,400
+هينشلناها شفتوها بيصير عند مجموعة الكل اش اللي
+
+101
+00:08:35,400 --> 00:08:40,300
+بقصده انا بمجموعة الكل مجموعة ممكن تركب او تتحد في
+
+102
+00:08:40,300 --> 00:08:44,360
+اي مكان تاني محل ما كانت متصلة مع الهيدروجين ممكن
+
+103
+00:08:44,360 --> 00:08:49,880
+تتحد مع شيء تاني يعني لو مثلا افترضت انه هذه درة
+
+104
+00:08:49,880 --> 00:08:54,940
+كلور ممكن تيجي هذه مجموعة الكل تتحد هنا مع الكلور
+
+105
+00:08:54,940 --> 00:09:01,650
+تتكون جزءمع إيش؟ مع الكلور الآن الجزء أصلا إيش كان
+
+106
+00:09:01,650 --> 00:09:08,450
+اسمه و كله ملان هيدروجين كان اسمه ميثين الجزء هذا
+
+107
+00:09:08,450 --> 00:09:13,490
+إيش كان اسمه؟ ميثين الآن لما هذا الجزء إحنا بنشيل
+
+108
+00:09:13,490 --> 00:09:18,030
+منه هيدروجين بتصير المجموعة اسمها مثل إذا ميثين
+
+109
+00:09:18,030 --> 00:09:28,160
+بيعطيني مثل طب لو شبكة هذه مثل مع كلور بصير مثلأو
+
+110
+00:09:28,160 --> 00:09:31,900
+كلورو ميثين بالـ Iobacnium هناخد التسمية، واضح؟
+
+111
+00:09:31,900 --> 00:09:36,220
+إذا هذه الـ CH3 مش الـ CH4، شو بيصير اسمها
+
+112
+00:09:36,220 --> 00:09:42,780
+كمجموعة؟ مثل، إذا الميثين بيعمل مجموعة المثل،
+
+113
+00:09:42,780 --> 00:09:47,320
+واضح؟ لما نشيل منه هيدروجينة، الآن بنفس الطريقة لو
+
+114
+00:09:47,320 --> 00:09:53,470
+إجينا طلعنا على ال إيثينلو شيلنا منه هيدروجينة بدل
+
+115
+00:09:53,470 --> 00:10:01,730
+C2H6 أو C3H3 بيصير CH3 CH2 بينخس منه هيدروجينة هذا
+
+116
+00:10:01,730 --> 00:10:06,650
+إثن المجموع اللي بتطلع منه إيش اسمها إثل واضح
+
+117
+00:10:06,650 --> 00:10:12,890
+المجموع اللي بتطلع منه إثل الأمور للأسفما بتضلش ..
+
+118
+00:10:12,890 --> 00:10:17,270
+ما بتضلش خلّيني أقول سهلة كتير .. ما بتضلش سهلة
+
+119
+00:10:17,270 --> 00:10:22,390
+كتير يعني مجرد ما بنصل لجزء البروبين بنلاقي أنه
+
+120
+00:10:22,390 --> 00:10:27,450
+بيبدأ يصير عندنا إشكالية شو الإشكالية اللي بتبدأ
+
+121
+00:10:27,450 --> 00:10:31,850
+تصير عندى لما أصل لجزء البروبين؟بدي أشيل هيدروجينة
+
+122
+00:10:31,850 --> 00:10:35,530
+بلاحظ أنه الهيدروجين اللي في البروبين نوعين هدولة
+
+123
+00:10:35,530 --> 00:10:39,670
+التلاتة و هدولة التلاتة زي بعض بمعنى لو شيلت أي
+
+124
+00:10:39,670 --> 00:10:44,310
+هيدروجينة من هان لو شيلت أي هيدروجينة من هذا الطرف
+
+125
+00:10:44,310 --> 00:10:48,130
+وكنت بدي أشبكها بchlor اتطلعوا معاكي كيف الجزء
+
+126
+00:10:48,130 --> 00:10:54,650
+بيشبك من الطرف carbon تنتين تلاتة الان طيب لو
+
+127
+00:10:54,650 --> 00:11:01,070
+شيلنا هيدروجينة مش من الطرف هذا من النصبصير جزء
+
+128
+00:11:01,070 --> 00:11:05,330
+تاني بصير جزء تاني اتطلعوا كيف صار متحد مع ال
+
+129
+00:11:05,330 --> 00:11:09,690
+chlorine مثلا واضح اذا في حالة البروبين انا
+
+130
+00:11:09,690 --> 00:11:12,570
+بإمكاني اشيل الهيدروجين من هذا الطرف و بإمكاني
+
+131
+00:11:12,570 --> 00:11:15,750
+اشيل الهيدروجين من النص طبعا من الطرف هذا زي هذا
+
+132
+00:11:15,750 --> 00:11:19,350
+فإذا شيلنا من الطرف هذا بنعمل المجموعة اللي
+
+133
+00:11:19,350 --> 00:11:23,890
+بنسميها بروبل و مرات بيحطوا قدامها N بروبل يعني
+
+134
+00:11:23,890 --> 00:11:30,070
+normal بروبل بروبل عادي عبارة عن CH2 CH2CH3 و لو
+
+135
+00:11:30,070 --> 00:11:34,630
+شيلنا الهيدروجينة من النص بيعمل مجموعة isopropyl
+
+136
+00:11:34,630 --> 00:11:37,850
+بيكون الاتصال تبع ال isopropyl من أي كربونا من
+
+137
+00:11:37,850 --> 00:11:43,370
+التلاتة الكربونا الوسطانية مش الطرفية واضح؟ اذا
+
+138
+00:11:43,370 --> 00:11:49,490
+البروبين له مجموعتين الكل شهما البروبيل اذا اتصل
+
+139
+00:11:49,490 --> 00:11:55,970
+من الطرف و isopropyl اذا اتصل من النص الان لو
+
+140
+00:11:55,970 --> 00:12:02,720
+الأمور كبرت شويةصار في عندنا لبيوتين لبيوتين
+
+141
+00:12:02,720 --> 00:12:08,500
+مشكلته شوية .. مشكلته شوية أكبر ليش لبيوتين مشكلته
+
+142
+00:12:08,500 --> 00:12:14,560
+أكبر؟ أساسا أول ما باجي بدي أشيل هيدروجينة من
+
+143
+00:12:14,560 --> 00:12:19,300
+لبيوتين عشان أحط بدالها الكربونة الرابعة مش هو تلت
+
+144
+00:12:19,300 --> 00:12:22,940
+كربونات؟ بدي أخليه أربعة أول ما بدي أجي أشيل
+
+145
+00:12:22,940 --> 00:12:28,800
+هيدروجينة ممكن أشيل من هانوبالتالي الكربونات اللى
+
+146
+00:12:28,800 --> 00:12:35,100
+عندى يكونوا ماخدين شكل السلسلة ال chain ورا بعض
+
+147
+00:12:35,100 --> 00:12:40,140
+جايين بدون تفرع واحد، اتنين، تلاتة، اربعة، واضح؟
+
+148
+00:12:40,140 --> 00:12:45,940
+هذا مركب لكن لو افترضنا مثلا انه احنا شيلنا هذه
+
+149
+00:12:45,940 --> 00:12:48,320
+الهيدروجينة وحطينا بدلها كربون
+
+150
+00:12:51,680 --> 00:12:55,460
+برضه دول اربع كاربونات لكن هذا شكل مختلف هذا صار
+
+151
+00:12:55,460 --> 00:13:01,000
+branched molecule ايش يعني branched؟ متفرع اذا
+
+152
+00:13:01,000 --> 00:13:06,960
+البيوتين اصلا في منه مركبين المركب مش المجموعات
+
+153
+00:13:06,960 --> 00:13:10,680
+المركب نفسه البيوتين في منه اتنين اما بيكون على
+
+154
+00:13:10,680 --> 00:13:15,540
+شكل a chain compound a chain يعني ايه؟ على شكل
+
+155
+00:13:15,540 --> 00:13:20,040
+سلسلة و اما بيكون branched ايه كاربون اتنين تلاتة؟
+
+156
+00:13:20,130 --> 00:13:25,790
+أربعة ال chain compound بنسميه بيوتين ال branch
+
+157
+00:13:25,790 --> 00:13:32,230
+بنسميه ايزو بيوتين واضح؟ اذا من مركب البيوتين نفسه
+
+158
+00:13:32,230 --> 00:13:36,530
+من مركب البيوتين نفسه انا في عندي كام مركب؟ اتنين
+
+159
+00:13:36,530 --> 00:13:40,710
+اللي هم ال chain و ال branch البيوتين و ايزو
+
+160
+00:13:40,710 --> 00:13:47,450
+بيوتين الان لما نيجي بدنا نعملالكلي جروبز بنلاحظ
+
+161
+00:13:47,450 --> 00:13:52,190
+أنه ال بيوتين الأربعة ممكن تفقد هيدروجينة من هنا
+
+162
+00:13:52,190 --> 00:13:56,850
+يعطيني مجموعة وممكن من هنا كمان يعطيني مجموعة إذا
+
+163
+00:13:56,850 --> 00:14:01,630
+فقدت الهيدروجينة من هنا بصير عندى ال product اسمه
+
+164
+00:14:01,630 --> 00:14:08,910
+normal butyl group أو butylig group واضح؟ لو حطيت
+
+165
+00:14:08,910 --> 00:14:14,730
+كلور هنا على الطرف بصير butylechloride واضح لكن لو
+
+166
+00:14:14,730 --> 00:14:19,390
+فقدت الهيدروجينة من الموقع التاني بنسمي ال group
+
+167
+00:14:19,390 --> 00:14:25,150
+secondary butyl واضح secondary butyl اذا الان
+
+168
+00:14:25,150 --> 00:14:29,590
+بيوتين منه مجموعتين butyl و secondary butyl ال
+
+169
+00:14:29,590 --> 00:14:32,630
+butyl من موقع واحد اتصالها ال secondary butyl من
+
+170
+00:14:32,630 --> 00:14:39,550
+موقع اتنين طيب لو اجينا ل .. ل branchedاللي موجود
+
+171
+00:14:39,550 --> 00:14:43,390
+عندنا هنا المتفرع بنلاحظ أنه يمكن أن تفقد
+
+172
+00:14:43,390 --> 00:14:47,170
+هيدروجينة من أي واحدة من هدول التلاتة زي بعض بتصير
+
+173
+00:14:47,170 --> 00:14:52,710
+المجموعة اسمها isobutyl واضح؟ بتصير المجموعة اللي
+
+174
+00:14:52,710 --> 00:14:56,350
+عنده اسمها isobutyl
+
+175
+00:14:59,100 --> 00:15:04,780
+المجموعة اللي احنا بنسميها ال isobutyl إذا فقدت ال
+
+176
+00:15:04,780 --> 00:15:09,780
+hydrogen من أحد الأطراف اللي موجودة عند هنا واضح؟
+
+177
+00:15:09,780 --> 00:15:13,460
+وإذا فقدت ال hydrogen من النص اللي هي هذه ال
+
+178
+00:15:13,460 --> 00:15:17,460
+hydrogen الوحيدة اللي هنا موجودة ممكن نكمل الجزء
+
+179
+00:15:17,460 --> 00:15:24,980
+حتى يعني الصورة عندكم تكون واضحة
+
+180
+00:15:24,980 --> 00:15:25,560
+تماما
+
+181
+00:15:28,630 --> 00:15:32,810
+هذا ال بيوتين شايفينه اللي هو المتفرع، الان لو
+
+182
+00:15:32,810 --> 00:15:37,370
+فقدنا هيدروجينة من اي CH3 زي بعض، يعني هادي زي
+
+183
+00:15:37,370 --> 00:15:40,450
+هادي زي هادي مافيش فيه مشكلة، الان لو فقدت
+
+184
+00:15:40,450 --> 00:15:44,750
+الهيدروجينة من هنا، شو بده يكون اسم المجموعة؟
+
+185
+00:15:44,750 --> 00:15:49,700
+Isobutyl، Isobutyl، لو حطيت هنا Clorشو بيصير اسم
+
+186
+00:15:49,700 --> 00:15:54,980
+المركب؟ Isobutyl chloride لاحظوا من الشكل الأول و
+
+187
+00:15:54,980 --> 00:16:00,400
+من الشكل التاني مجموعة ال ISO لما بنقول ISO معناه
+
+188
+00:16:00,400 --> 00:16:10,270
+ذلك ان في عندكم CH3 CH CH3يعني كلمة ISO فيها CH3
+
+189
+00:16:10,270 --> 00:16:18,050
+CH CH3 لما كانوا الكربونات تلاتة CH3 CH CH3 بس
+
+190
+00:16:18,050 --> 00:16:23,010
+تلات كربونات شو سمينا المجموعة؟ ISO بربل على
+
+191
+00:16:23,010 --> 00:16:29,410
+تلاتة، الآن لما بيصيروا أربعة CH3 CH CH3 وإجت هنا
+
+192
+00:16:29,410 --> 00:16:35,890
+كمان CH2بدي يصير المركب إيش؟ Isobutyl لكن التنين
+
+193
+00:16:35,890 --> 00:16:42,370
+بيمتازوا بهذه المجموعة اللي فوق CH3 CH CH3 إذا كان
+
+194
+00:16:42,370 --> 00:16:47,410
+العدد الكلي تلاتة Isopropyl إذا زدت هنا تنتين
+
+195
+00:16:47,410 --> 00:16:50,650
+Isobutyl
+
+196
+00:16:50,650 --> 00:16:58,260
+طب لو زدت كمان CH2 خمس كربوناتIsobentyl لو صار ستة
+
+197
+00:16:58,260 --> 00:17:04,520
+Isohexyl Isoheptyl Isooctyl ومنه ال Isooctane اللي
+
+198
+00:17:04,520 --> 00:17:09,760
+بيدخل في صناعة الوقود تبع السيارات، مكون وقود
+
+199
+00:17:09,760 --> 00:17:13,300
+السيارات، بس فيهم كلهم Isopropyl Isobutyl
+
+200
+00:17:13,300 --> 00:17:20,850
+Isobentyl Isohexyl الطرف تبعهم إيش؟CH3 CH CH3 هذه
+
+201
+00:17:20,850 --> 00:17:27,670
+مجموعة ال ISO واضح؟ اذا هي ال ISO group ال ISO
+
+202
+00:17:27,670 --> 00:17:34,090
+butyl طيب لو شيلنا من النص ال hydrogen لاحظوا
+
+203
+00:17:34,090 --> 00:17:38,630
+بيصير عندي carbon حاملة CH3 CH3 CH3 هذه مجموعة
+
+204
+00:17:38,630 --> 00:17:44,590
+كبيرة شايفين كيف؟ لو اتصلت بchlor بيصير المركب طيب
+
+205
+00:17:44,590 --> 00:17:48,610
+هذه المجموعة كلها ك group شو بسميها انا؟Tertiary
+
+206
+00:17:48,610 --> 00:17:52,510
+Butyl لو اتحدت مع الكلور و جيبنالكم هذا المركب
+
+207
+00:17:52,510 --> 00:17:58,430
+قولنالكم ايش اسمه تيرتشاري بيوتل كل هذا الكربون
+
+208
+00:17:58,430 --> 00:18:03,430
+اللي حملة تلاتة CH3 اسمها ايش تيرتشاري بيوتل لو
+
+209
+00:18:03,430 --> 00:18:10,550
+اتحدت مع الكلور تيرتشاري بيوتل اكلورايد اذا حقيقة
+
+210
+00:18:10,550 --> 00:18:14,310
+من البيوتين بشقيها اللي هو البيوتين العادي و
+
+211
+00:18:14,310 --> 00:18:19,150
+الايزوبيوتين اكملك ال group في عند اناأربعة عند
+
+212
+00:18:19,150 --> 00:18:26,290
+بيوتل وسكندر بيوتل من المركب لتشين وعند ايزو بيوتل
+
+213
+00:18:26,290 --> 00:18:31,190
+و تيرتشر بيوتل من المركب لبرانشت هذه المجموعات
+
+214
+00:18:31,190 --> 00:18:35,650
+كلها المفروض أي طالب organic يكون ايش حافظها تماما
+
+215
+00:18:35,650 --> 00:18:40,850
+لأنه دائما بنسأل عنها يعني ممكن نجيب حلقة بنزين
+
+216
+00:18:40,850 --> 00:18:45,510
+على سبيل المثال متصلة فيها هذه المجموعة وقتها شو
+
+217
+00:18:45,510 --> 00:18:51,250
+بنسمي المركب؟Tertiary-butylbenzene يعني لو ان
+
+218
+00:18:51,250 --> 00:18:56,190
+اتخيلت ان هنا حطيت حلقة بنزين زي هيك هى صار مركب
+
+219
+00:18:56,190 --> 00:19:01,590
+لما بدى اسميه لو كنت انا حاطط بس كلور بسميه
+
+220
+00:19:01,590 --> 00:19:05,250
+chlorobenzene طب لما احط هذه المجموعة كلها شو
+
+221
+00:19:05,250 --> 00:19:09,210
+بيصير اسمه tertiary-butylbenzene لو حطيت هنا
+
+222
+00:19:09,210 --> 00:19:13,270
+البنزين شو بيصير اسمه المركب isobutylbenzene لو
+
+223
+00:19:13,270 --> 00:19:19,030
+حطيته هنا isopropylbenzene لو حطيته هناethyl
+
+224
+00:19:19,030 --> 00:19:25,730
+benzene واضح الفكرة كيف؟ فهذه مجموعات القلكل حقيقة
+
+225
+00:19:25,730 --> 00:19:30,390
+بدكوا تكونوا حافظينها بشكل ممتاز
+
+226
+00:19:33,570 --> 00:19:38,570
+هذه الألكانز البسيطة اللي احنا اتعرفنا عليها طب لو
+
+227
+00:19:38,570 --> 00:19:44,130
+كبر المركبة بدنا طريقة عامة لتسمية أي مركب كبير
+
+228
+00:19:44,130 --> 00:19:48,230
+اللي هي Nomenclature of Substituted Alkanes
+
+229
+00:19:48,230 --> 00:19:52,530
+Nomenclature دائما ايش بتيجي .. تسمية المركبات
+
+230
+00:19:52,530 --> 00:19:57,830
+العضوية او الألكانز الكبيرةعشان أسمي أي ألكين
+
+231
+00:19:57,830 --> 00:20:02,610
+المفروض أطلع على ال carbons تعوني الألكين وأبحث
+
+232
+00:20:02,610 --> 00:20:09,130
+إلى أن أحصل على أطول سلسلة ذرات كربون، واضح؟ مثلا
+
+233
+00:20:09,130 --> 00:20:12,090
+في هذا المراكب لو أطلعت أي واحد، اتنين، تلاتة،
+
+234
+00:20:12,090 --> 00:20:17,140
+اربعة، خمسة، هذه الحمرة سلسلة إيش؟الكربون، إذا
+
+235
+00:20:17,140 --> 00:20:20,960
+المركب اللي عندى مشتق من الخمسة، الخمسة عبارة عن
+
+236
+00:20:20,960 --> 00:20:25,760
+إيش؟ بنتين، بنتين، فالمركب اللي عندى هو مشتقة
+
+237
+00:20:25,760 --> 00:20:29,180
+بنتين، الآن ال substituents اللي موجودة إيه لها
+
+238
+00:20:29,180 --> 00:20:35,300
+أسمها؟ الchlor اسمه chloro، ال brom إيه bromه؟ ال
+
+239
+00:20:35,300 --> 00:20:41,640
+CH3 مثل ال CH اللي متصلة بينتين CH3 تو اتعلمناها
+
+240
+00:20:42,940 --> 00:20:48,720
+eyes of rubel على سبيل المثال فبنذكر المجموعات و
+
+241
+00:20:48,720 --> 00:20:52,660
+لما يكونوا أكثر من نوع بنذكرهم alphabetically
+
+242
+00:20:52,660 --> 00:20:59,400
+بمعنى ال a قبل ال b قبل ال c قبل ال d واضح لما
+
+243
+00:20:59,400 --> 00:21:03,680
+نيجي نرتب ذكر المجموعات هذا بينتين متصل في كام
+
+244
+00:21:03,680 --> 00:21:07,860
+مجموعة؟ بينتين brom و chlorine مين اللي بدي أذكره
+
+245
+00:21:07,860 --> 00:21:11,690
+في الأول ال brom ولا ال chlorine؟لبروم طيب لما بدى
+
+246
+00:21:11,690 --> 00:21:16,010
+احدد الموقع بدى ارقم و هنا بتجينا دايما مشكلة انه
+
+247
+00:21:16,010 --> 00:21:20,110
+انا بقدر اقول الواحد من هذا الطرف او من هذا الطرف
+
+248
+00:21:20,110 --> 00:21:23,890
+يعني ممكن اقول واحد اتنين تلاتة اربعة خمسة و ممكن
+
+249
+00:21:23,890 --> 00:21:29,470
+اقول واحد اتنين تلاتة اربعة خمسة دائما في ال
+
+250
+00:21:29,470 --> 00:21:32,910
+organic بنقول بنستعمل قاعدة ال lower numbering
+
+251
+00:21:32,910 --> 00:21:39,070
+يعني لازم احصل على اقلترقيم فلاحظوا لو بدأت من هنا
+
+252
+00:21:39,070 --> 00:21:43,410
+الكلور ع اتنين و البروم ع تلاتة اتنين و تلاتة خمسة
+
+253
+00:21:43,410 --> 00:21:46,730
+كمجموع لو بدأت من هنا واحد اتنين تلاتة اربعة
+
+254
+00:21:46,730 --> 00:21:50,410
+البروم ع تلاتة و الكلور ع اربعة تلاتة و اربعة سبعة
+
+255
+00:21:50,410 --> 00:21:54,770
+اذا انه اقل ترقيم الترقيم اللي احنا عاملينه من هنا
+
+256
+00:21:54,770 --> 00:22:00,050
+بناء على ذلك هذا المركب لما نشوف اسمه كاملا بيصير
+
+257
+00:22:00,050 --> 00:22:07,080
+three bromo two chlorobentaneكلمة واحدة بدون ما
+
+258
+00:22:07,080 --> 00:22:09,880
+نقطع فراغات بينها لو كنا بنطبع على الكمبيوتر و
+
+259
+00:22:09,880 --> 00:22:16,660
+بنكتب بالإيد و دائما قبل الرقم بعده بنحط dash إذا
+
+260
+00:22:16,660 --> 00:22:21,760
+هذا المركب three promo two cloro بنتين و تكتب
+
+261
+00:22:21,760 --> 00:22:26,960
+ككلمة واحدة و دائما قبله بعد الرقم dash ما لم يكن
+
+262
+00:22:26,960 --> 00:22:30,740
+في البداية بس بيكون ايش ال dash بعده نعد من هنا
+
+263
+00:22:30,740 --> 00:22:37,020
+واحد اتنين تلاتة بمشيواحد اتنين تلاتة اربعة خمسة
+
+264
+00:22:37,020 --> 00:22:41,660
+بدا تتعب ممكن تعد من هنا واحد اتنين تلاتة اربعة
+
+265
+00:22:41,660 --> 00:22:45,680
+خمسة لما نعمل اكتر من محاولة بنلاحظ ان هو اطول
+
+266
+00:22:45,680 --> 00:22:50,800
+السلسلة واحد اتنين تلاتة اربعة خمسة ستة سبعة اذا
+
+267
+00:22:50,800 --> 00:22:57,280
+المركب اللي عند مشتقت السبعة هبتين هبتين متصل في
+
+268
+00:22:57,280 --> 00:23:03,720
+مجموعةمثل ومجموعة مثل تانية اقل ترقيم بيخلينا نرقم
+
+269
+00:23:03,720 --> 00:23:07,600
+من هنا مش من هنا لما يكون مجموعتين مثل ايش
+
+270
+00:23:07,600 --> 00:23:15,570
+بنستعمللهم؟ die لو كانوا تلاتةأربعة تترا خمسة بنتة
+
+271
+00:23:15,570 --> 00:23:20,810
+هكسة هبتة واضح اذا هذا و بنحدد مكانهم بنقول على
+
+272
+00:23:20,810 --> 00:23:25,370
+اتنين وعلى اربعة عندي مجموعتين مثل فلما بدي احط
+
+273
+00:23:25,370 --> 00:23:33,010
+الاسم بقول two فاصلة كمة four داش دائما بين الرقم
+
+274
+00:23:33,010 --> 00:23:37,310
+والاسم dimethyl heptane اذا هذا المركب two four
+
+275
+00:23:37,310 --> 00:23:38,370
+dimethyl
+
+276
+00:23:43,280 --> 00:23:49,260
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+277
+00:23:49,260 --> 00:23:50,120
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+278
+00:23:50,120 --> 00:23:50,120
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+279
+00:23:50,120 --> 00:23:50,120
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+280
+00:23:50,120 --> 00:23:53,500
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+281
+00:23:53,500 --> 00:23:56,620
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+282
+00:23:56,620 --> 00:24:02,520
+تختار أطول سلسلة تختار أطول سلسلة تختار أطول سلسلة
+
+283
+00:24:02,520 --> 00:24:10,940
+تختار أطول سلسلة تختار أبرضه إذا جرينا ورا أطول
+
+284
+00:24:10,940 --> 00:24:14,160
+سلسلة واحد، اتنين، تلاتة، أربعة، خمسة، ستة، سبعة
+
+285
+00:24:14,160 --> 00:24:17,760
+ممكن ننظر احتمالات تانية بنلاقيهم أقل، بنلاقيهم
+
+286
+00:24:17,760 --> 00:24:21,780
+أقل، إذا المركب اللي عندي سبعة إيش بيحمل على موقع
+
+287
+00:24:21,780 --> 00:24:28,060
+اتنين؟ مثل، على موقع خمسة؟ isopropyl، مين جاب ال
+
+288
+00:24:28,060 --> 00:24:32,100
+alpha بتيكاليه؟ ال isopropyl، إذا four على موقع
+
+289
+00:24:32,100 --> 00:24:37,120
+أربعة هان عفوا، four isopropyl, two methyl, هبتين
+
+290
+00:24:37,540 --> 00:24:44,380
+واضح؟ هذه هي طريقة التسمية أحياناً بتجينا إشكالية
+
+291
+00:24:44,380 --> 00:24:49,220
+صغيرة أنه لما نيجي نفتش على أطول سلسلة في مركب
+
+292
+00:24:49,220 --> 00:24:55,160
+بنلاحظ أنه ممكن يكون عنده نفس الطول جاي باتجاهين
+
+293
+00:24:55,160 --> 00:24:59,220
+مختلفين يعني لاحظوا هذا المركب نفسه و هذا المركب
+
+294
+00:24:59,220 --> 00:25:04,100
+نفسه و هذا المركبواضح؟ لما نيجي نعد من هنا واحد،
+
+295
+00:25:04,100 --> 00:25:07,940
+اتنين، تلاتة، اربعة، خمسة، ستة، سبعة، هاي سلسلة
+
+296
+00:25:07,940 --> 00:25:14,000
+طولها سبعة، كام تفرع طالع منها؟ اتنين طيب لو عدينا
+
+297
+00:25:14,000 --> 00:25:17,300
+من هان، واحد، اتنين، تلاتة، اربعة، خمسة، ستة،
+
+298
+00:25:17,300 --> 00:25:24,200
+سبعة، برضه سبعة، بصير كيف بدي اخد؟ هادي السبعة ولا
+
+299
+00:25:24,200 --> 00:25:29,360
+هادي السبعة؟وهنا في السابعة هذه منها تفرع واحد
+
+300
+00:25:29,360 --> 00:25:33,640
+فالقاعدة بتقولنا if there are two equally long
+
+301
+00:25:33,640 --> 00:25:37,820
+continuous chains it choose the one with most
+
+302
+00:25:37,820 --> 00:25:42,360
+branches اختار اللي فيها تفرعات اكتر هذه كام تفرع
+
+303
+00:25:42,360 --> 00:25:49,080
+طالع منها اتنين هذه كام تفرع طالع منها واحد واضح؟
+
+304
+00:25:49,080 --> 00:25:54,950
+اذا بنطلع احنا علىهدولة المركبين نفس طول السلسلة
+
+305
+00:25:54,950 --> 00:26:01,210
+سبعة وسبعة إذا تساوى طول السلسلة ما الحكم؟ عدد
+
+306
+00:26:01,210 --> 00:26:06,090
+التفرعات اللي أكثر تفرع هو اللي بنختاره ولذلك هذا
+
+307
+00:26:06,090 --> 00:26:11,430
+المركب لما نيجي نسميه في مجموعة مثل ومجموعة إثل
+
+308
+00:26:11,430 --> 00:26:17,030
+والترقيم من هنا أنهي اللي بتذكر في الأولال إثل إذا
+
+309
+00:26:17,030 --> 00:26:23,070
+عندي three إثل two مثل هبتين مابجيش أسميه هنا لو
+
+310
+00:26:23,070 --> 00:26:26,830
+اتخيلت أنه هذه مجموعة واحدة isopropyl three
+
+311
+00:26:26,830 --> 00:26:31,730
+isopropyl هبتين كان ممكن واحدة أول ما ييجي ع بالها
+
+312
+00:26:31,730 --> 00:26:34,610
+تتطلع زي هيك و تقولها يحامل مجموعة و حافظها
+
+313
+00:26:34,610 --> 00:26:38,430
+المجموعة isopropyl اتسميها isopropyl heptane هذه
+
+314
+00:26:38,430 --> 00:26:43,650
+التسمية تعتبر تسمية خاطئة المركب بهذا الشكل بناخد
+
+315
+00:26:43,650 --> 00:26:52,000
+التفرعاتالأكثر واضح بعد هذه المقدمة عن تسميات ال
+
+316
+00:26:52,000 --> 00:26:56,680
+alkanes بننتقل إلى دراسة بعض ال physical
+
+317
+00:26:56,680 --> 00:27:00,980
+properties لل alkanes الخاصية الأولى ال water
+
+318
+00:27:00,980 --> 00:27:05,240
+solubility الذوبان في الميه كلكم بتعرفوا البنزين
+
+319
+00:27:05,240 --> 00:27:10,320
+لو خدنا بنزين السيارة على الميه مابخلطش insoluble
+
+320
+00:27:10,320 --> 00:27:13,760
+واضح إذا ال alkanes they are water insoluble شو
+
+321
+00:27:13,760 --> 00:27:21,840
+السبب؟اللي هو انه البنزين وغيره وكل المركبات بنطبق
+
+322
+00:27:21,840 --> 00:27:27,160
+عليها قاعدة ذائبية like dissolve like يعني ال
+
+323
+00:27:27,160 --> 00:27:30,060
+polar compounds دي are soluble in polar compounds
+
+324
+00:27:30,060 --> 00:27:33,260
+ال non polar compounds in non polar compounds الآن
+
+325
+00:27:33,260 --> 00:27:37,060
+ال alkenes دي are non polar لا فيهم hydrogen
+
+326
+00:27:37,060 --> 00:27:39,720
+bonding ولا إشي شو القوة اللي بتحكمهم زي ما حكت
+
+327
+00:27:39,720 --> 00:27:44,900
+زملتكوا؟اللي هي ال London forces أو ال Vanderwaals
+
+328
+00:27:44,900 --> 00:27:49,540
+forces هي اللي مربطاهم البعض وهذه قوة ضعيفة ولذلك
+
+329
+00:27:49,540 --> 00:27:53,320
+برضه ال Alkanes هتلاحظوا ملاحظة ان نقاط غليانها
+
+330
+00:27:53,320 --> 00:27:58,400
+منخفضة لأن ارتباطها ضعيف يعني مثلا ال methane يمكن
+
+331
+00:27:58,400 --> 00:28:03,500
+عندناقص 168 بيغلي عبارة عن غاز ال ethane غاز ال
+
+332
+00:28:03,500 --> 00:28:10,140
+probane غاز ال butane غازبالمناسبة الميثين ..
+
+333
+00:28:10,140 --> 00:28:13,060
+الميثين عشان انتوا ما تخربطوش برضه و تتعلموا هذه
+
+334
+00:28:13,060 --> 00:28:18,360
+المعلومة الميثين هو الغاز الطبيعي بنسميه natural
+
+335
+00:28:18,360 --> 00:28:24,220
+gas وهذا الغاز الطبيعي بشكل عام بمشيوب أنبيبه
+
+336
+00:28:24,220 --> 00:28:28,860
+عملية إسالته وتعبئته بإستوانات زي الإستوانات
+
+337
+00:28:28,860 --> 00:28:33,700
+المنزلية عملية صعبةواضح؟ بده تقنيات صعبة جدا، مش
+
+338
+00:28:33,700 --> 00:28:38,140
+هو الغاز اللي بيجينا في قنابيب الغاز، الميثين مش
+
+339
+00:28:38,140 --> 00:28:41,220
+هو الغاز اللي بيجينا في قنابيب الغاز، يمكن الميثين
+
+340
+00:28:41,220 --> 00:28:46,240
+هو الغاز اللي مصر بتبيعه لإسرائيلبس نفسه ماحدش
+
+341
+00:28:46,240 --> 00:28:48,800
+ييجي يقول عبوا .. عبوا لنا ياف قنابيب غاز مش هو
+
+342
+00:28:48,800 --> 00:28:52,220
+هذا الغاز تبع القنابيب الغاز بيشغلوا فيه محطات
+
+343
+00:28:52,220 --> 00:28:56,140
+توليد و جايبينه بقنابيب معينة و كل شيء هذا اللي هو
+
+344
+00:28:56,140 --> 00:29:01,060
+ال natural gas الميثين لكن الغاز تبعنا و بيطلع من
+
+345
+00:29:01,060 --> 00:29:04,940
+التخمر بالمناسبة الميثين يعني الفضلات العضوية و
+
+346
+00:29:04,940 --> 00:29:09,870
+غيرها بتعرفوا ال bio gases و جزء ال energyطريقة من
+
+347
+00:29:09,870 --> 00:29:13,350
+خلال تخمير الفضلات ان نحصل على الميثين و نحصل على
+
+348
+00:29:13,350 --> 00:29:18,550
+ال energy لكن الغاز المنزلي هو عبارة عن خليط من
+
+349
+00:29:18,550 --> 00:29:24,840
+البروبين و البيوتين فهو غاز بتروليشفتوا الفرق بين
+
+350
+00:29:24,840 --> 00:29:29,340
+الغاز الطبيعي والغاز البترولي، الميثين و البروبين،
+
+351
+00:29:29,340 --> 00:29:32,940
+عفوا، البروبين و البيوتين اللي بتعبوا في الصوانات
+
+352
+00:29:32,940 --> 00:29:37,120
+و يسالوا بسهولة و بنضغطوا في الصوانة بسهولة اللي
+
+353
+00:29:37,120 --> 00:29:42,200
+هم الغاز البترولي اللي بيجي عندنامن عند البنتين
+
+354
+00:29:42,200 --> 00:29:47,020
+بيبدأ المركب يصير سائل لكن سهل التطاير بنتين،
+
+355
+00:29:47,020 --> 00:29:51,080
+هكسين، هبتين، لاحظوا بنزين السيارات دائما بنقول
+
+356
+00:29:51,080 --> 00:29:56,480
+عنه إيش؟ متطاير جدا، هو هكسين و هبتين إيش كل قصة
+
+357
+00:29:56,480 --> 00:30:01,480
+التطاير اللي موجودة في ال Alcans؟ إيش سببها؟ إن
+
+358
+00:30:01,480 --> 00:30:05,940
+الروابط اللي في ضعيفة هي London Forces واضح؟ كل
+
+359
+00:30:05,940 --> 00:30:10,910
+قصة الإرتباطات اللي ..لضعيفة في ال alkanes هي اللي
+
+360
+00:30:10,910 --> 00:30:16,510
+بتأدي ل boiling points منخفضة، إذا ال alkanes لهم
+
+361
+00:30:16,510 --> 00:30:21,360
+low boiling pointwhich increases upon increasing
+
+362
+00:30:21,360 --> 00:30:24,340
+the number of carbons in the alkane وهذا كلام منطق
+
+363
+00:30:24,340 --> 00:30:27,760
+انه ال alkane ب carbon واحدة بيكون ال boiling
+
+364
+00:30:27,760 --> 00:30:31,120
+point اقل كتير من ال alkane اللي ب 7 carbons اللي
+
+365
+00:30:31,120 --> 00:30:34,720
+ب 7 carbons سائل اللي ب carbon واحدة ال methane
+
+366
+00:30:34,720 --> 00:30:41,460
+عبارة عن غاز اذا كل ما زدنا احنا عدد ال carbons في
+
+367
+00:30:41,460 --> 00:30:44,240
+ال homologous series بتعرفوا homologous series
+
+368
+00:30:44,240 --> 00:30:46,980
+اللي هي المركبات اللي كل واحد بيكون بيفرج عن اللي
+
+369
+00:30:46,980 --> 00:30:54,280
+بعده بمقدار قداشCH2 لما أخدنا الجدول تبع الألكان
+
+370
+00:30:54,280 --> 00:30:58,940
+إذا رجعته شوية صغيرة جدول الألكان اللي هنطلع CH4
+
+371
+00:30:58,940 --> 00:31:04,900
+أول ألكان اللي بعده CH2 CH6 ما الفرق بينهما CH2 لو
+
+372
+00:31:04,900 --> 00:31:10,080
+أخدنا CH3 CH8 إيش الفرق بينهم؟CH2 CH2 هذه السلسلة
+
+373
+00:31:10,080 --> 00:31:13,920
+اللي كل مركب بيفرج عن اللي بعده CH2 بنسميها
+
+374
+00:31:13,920 --> 00:31:18,520
+homologous series واضح فكل ما بيزيد عدد ال carbons
+
+375
+00:31:18,520 --> 00:31:26,220
+بتزيد نقطة غليان الألكين الآن أحيانا الألكين في
+
+376
+00:31:26,220 --> 00:31:30,700
+جزء منها زي ما قلنا it's chain-like وفي جزء منها
+
+377
+00:31:30,700 --> 00:31:37,370
+branchedفلو طلعنا مثلا على البنتين، البنتين ممكن
+
+378
+00:31:37,370 --> 00:31:40,750
+يكون على شكل سلسل، واحد، اتنين، تلاتة، اربعة، خمسة
+
+379
+00:31:40,750 --> 00:31:44,250
+وممكن يكون على شكل تفرع كربونا وطالع منها اربع
+
+380
+00:31:44,250 --> 00:31:48,010
+كربونات هذا المركب اللي هو كربونا بالوسط وطالع
+
+381
+00:31:48,010 --> 00:31:55,590
+منها اربع مركبات بيسموه new بنتينالان هو اللي له
+
+382
+00:31:55,590 --> 00:32:01,230
+boiling point أعلى ال can ل ال chain ولا ل ال
+
+383
+00:32:01,230 --> 00:32:06,070
+branches مع الاختبار بإنه المقارنة تكون لنفس العدد
+
+384
+00:32:06,070 --> 00:32:10,030
+من ال carbons يعني لما نحكي عن خمسة هنا خمسة هنا
+
+385
+00:32:10,030 --> 00:32:15,450
+دائما و أبدا ال branches ال cans they have lower
+
+386
+00:32:15,450 --> 00:32:20,500
+boiling points than ال chain ال cansدائما الالكين
+
+387
+00:32:20,500 --> 00:32:26,800
+المتفرع نقطة غليانه اقل من الالكين المستقيم او
+
+388
+00:32:26,800 --> 00:32:31,980
+المتسلسل ايش السبب؟ السبب لو كنت تطلعوا كيف
+
+389
+00:32:31,980 --> 00:32:36,240
+الجزيئات بتيجي على بعض والارتباط بينها فإذا أنا
+
+390
+00:32:36,240 --> 00:32:40,500
+بتطلع مثلا في الالكين ال .. ال .. ال chain الكين
+
+391
+00:32:40,500 --> 00:32:46,600
+بتلاحظوا انه في ..مسافة ارتباط واتصاق كبيرة يعني
+
+392
+00:32:46,600 --> 00:32:52,380
+كله بالتصق ببعضه تماما زى ما اجى احط مثلا اربع
+
+393
+00:32:52,380 --> 00:32:57,260
+مكعبات فوق بعض بيجوا فوق بعض بسهولة المكعبات اه
+
+394
+00:32:57,260 --> 00:33:01,990
+لكن هذا الشكل صار أشفه ما يكونبالكورة لو تخيلتوا
+
+395
+00:33:01,990 --> 00:33:06,250
+تحطوا أربع كورات بين بعض جداش نسبة التلامس بين
+
+396
+00:33:06,250 --> 00:33:10,030
+الأربع كورات اللي بدها تعمل bonding إذا بتطلعوا
+
+397
+00:33:10,030 --> 00:33:13,650
+هاي هدول الجزيات بس من هنا و من هنا الارتباط بينما
+
+398
+00:33:13,650 --> 00:33:19,230
+في هذه الحالةكل هذه مسافة ارتباط، اذا وين الارتباط
+
+399
+00:33:19,230 --> 00:33:22,870
+بيكون اكتر؟ في ال branched ولا في ال chain
+
+400
+00:33:22,870 --> 00:33:26,130
+compounds؟ في ال chain compounds فدائما ال chain
+
+401
+00:33:26,130 --> 00:33:34,410
+compounds بيكون لهم نقطة غليان اعلى من ال branched
+
+402
+00:33:34,410 --> 00:33:37,910
+compounds المقابلين لهم، يعني لما تقارنوا دائما
+
+403
+00:33:37,910 --> 00:33:41,590
+قارنوا أشياء من نفس النوع، خمسة مع خمسة، ستة مع
+
+404
+00:33:41,590 --> 00:33:44,350
+ستة، سبعة مع سبعة، و هكذا
+
+405
+00:33:48,530 --> 00:33:53,530
+بنجي لشغلة جديدة اللى هى ال conformations of ال
+
+406
+00:33:53,530 --> 00:33:58,230
+canes لما بدنا ندرس حقيقة ال conformations of ال
+
+407
+00:33:58,230 --> 00:34:02,650
+canes يفضل أننا ندرسها من خلال .. من خلال ال
+
+408
+00:34:02,650 --> 00:34:09,650
+models فلو عملنا احنا model لجزء ال E2 لو عملنا
+
+409
+00:34:09,650 --> 00:34:16,890
+model لجزء ال E2 وقلنا له انه ميغلبناشتطلعوا هذا
+
+410
+00:34:16,890 --> 00:34:21,550
+جزء ال A2 إذا بتطلعوا أنا ماسكه بطريقة بحيث مخلي
+
+411
+00:34:21,550 --> 00:34:26,170
+كل ذرّة قبالك تانية بظبط ولا لأ؟ طيب لو لفته شوية
+
+412
+00:34:26,170 --> 00:34:30,450
+بطلوا الذرات قبال بعض هل يا تورا صار عندي جزء
+
+413
+00:34:30,450 --> 00:34:34,750
+جديد؟ لو لفته كمان شوية شكل جديد، كمان شوية شكل
+
+414
+00:34:34,750 --> 00:34:38,290
+جديد ممكن أصل لو أنا بلفه أنه تصير هذه عكس هذه
+
+415
+00:34:38,290 --> 00:34:42,810
+يعني تطلعوا هذه لفوق وهذه لتحت لو لفت كمان شوية
+
+416
+00:34:42,810 --> 00:34:48,780
+شكل جديد، شكل جديد، بعود يرجع؟إجبال بعض إذا هذه
+
+417
+00:34:48,780 --> 00:34:54,200
+عبارة عن مجموعة أشكال ناشئة عن عملية إيش الدوران
+
+418
+00:34:54,200 --> 00:34:57,720
+طب لو بدأ أقول قداش عدد الأشكال الناشئة عن الدوران
+
+419
+00:34:57,720 --> 00:35:03,480
+infinity يعني لو بدأت ألف عشر عشر درجة و أزيد و
+
+420
+00:35:03,480 --> 00:35:06,940
+أزيد و أزيد و أزيد عند عدد لا نهائي من الأشكال
+
+421
+00:35:06,940 --> 00:35:11,420
+تنتج عن الدوران عند عدد لا نهائي من الأشكال تنتج
+
+422
+00:35:11,420 --> 00:35:18,220
+عن الدوران طيب إذاهل يطر الأثين جزئ ولا عدد لا
+
+423
+00:35:18,220 --> 00:35:22,660
+نهائي من الجزيئات؟ إذا أنا بقول هاي جزئ، هاي حاجة
+
+424
+00:35:22,660 --> 00:35:25,680
+جديدة، هاي حاجة جديدة، هاي حاجة جديدة، هو أثين ولا
+
+425
+00:35:25,680 --> 00:35:31,980
+عدد لا نهائي من الأثين؟ الحقيقة الموضوع بتقدر
+
+426
+00:35:31,980 --> 00:35:37,180
+تشبهه بالمروحة، المروحة لما بتلوف بتكون بعد لحظة
+
+427
+00:35:37,180 --> 00:35:40,820
+هيك، بعد لحظة هيك، بعد لحظة هيك، لكنها في حالة
+
+428
+00:35:40,820 --> 00:35:46,840
+دوران دائم فتبقى مروحة واحدةولو بتمر بعدد لا نهاء
+
+429
+00:35:46,840 --> 00:35:50,860
+من الأشكال، وهناك في ال organic chemistry دوران
+
+430
+00:35:50,860 --> 00:35:54,760
+دائم أبدي لا يتوقف حول الرابطة الأحدية، يعني هذا
+
+431
+00:35:54,760 --> 00:35:59,900
+الجزء طول الوقت هو بلف زي هيك، لكن هو يبقى جزء
+
+432
+00:35:59,900 --> 00:36:04,580
+واحدهذا الجزء يبقى إيش؟ جزء واحد اسمه إثنين، الآن
+
+433
+00:36:04,580 --> 00:36:08,580
+هذه الأشكال الناشئة عن الدوران بنسميها conformers،
+
+434
+00:36:08,580 --> 00:36:11,680
+conformers و الظاهرة كلها بنقولها conformations
+
+435
+00:36:11,680 --> 00:36:16,340
+فال conformers they are stereoisomers أشكال بس
+
+436
+00:36:16,340 --> 00:36:21,760
+اختلفت بالشكل الفراغي، هل نقلت رابطه من مكانها؟
+
+437
+00:36:21,760 --> 00:36:26,740
+أه، stereoisomers that are interconvertible،
+
+438
+00:36:26,740 --> 00:36:30,120
+بتتحولوا من واحد للتاني للتالت للرابع للخمس by؟
+
+439
+00:36:30,460 --> 00:36:35,160
+rotation إذا ال conformers أشكال بتتحول من واحد
+
+440
+00:36:35,160 --> 00:36:39,760
+للثاني للتالت من خلال ال rotation الآن هنا بدكم
+
+441
+00:36:39,760 --> 00:36:44,380
+تلاحظوا أنه أنا عندي اثنين واحد بعدد لا نهائي من
+
+442
+00:36:44,380 --> 00:36:49,500
+الدورانات زي ما عندي مروحة واحدة لكن ماخدة أشكال
+
+443
+00:36:49,500 --> 00:36:53,520
+لا نهائية وهي بتدورفي ال organ chemistry بالحب
+
+444
+00:36:53,520 --> 00:36:58,220
+احنا نرسم شكلين من هدولة الشكل اللي بيكونوا هدولة
+
+445
+00:36:58,220 --> 00:37:02,700
+فيه جبال بعض بالظبط و بنعطيه اسم و الشكل اللي
+
+446
+00:37:02,700 --> 00:37:05,860
+بتكون كل واحدة عكس التانية يعني إذا بتلاحظوا الآن
+
+447
+00:37:05,860 --> 00:37:11,240
+هذه و هذه إيش مالهم عكس بعض تماما و هذه و هذه عكس
+
+448
+00:37:11,240 --> 00:37:15,500
+بعض و هذه و هذه عكس بعض كيف الآن بنيجي بنرسم هذه
+
+449
+00:37:15,500 --> 00:37:19,920
+الأشكال كيف الآن بنيجي بنرسم هذه الأشكال بإمكاننا
+
+450
+00:37:19,920 --> 00:37:27,440
+احنانتطلع على الشكل بهذا زي ما انا ماسكه تماما، في
+
+451
+00:37:27,440 --> 00:37:33,220
+عندكم رابطة هنا شايفينها؟ في عندي مجمعتين للأمام،
+
+452
+00:37:33,220 --> 00:37:38,720
+المجمعتين للأمام كيف بعملهم؟ ب solid wedge و في
+
+453
+00:37:38,720 --> 00:37:44,240
+عندي مجمعتين للخلف كيف برسمهم؟ dash wedge و في
+
+454
+00:37:44,240 --> 00:37:48,930
+عندي هدولة بيكونوا في مستوى اللوحةملاحظين؟ إذا أنا
+
+455
+00:37:48,930 --> 00:37:53,530
+ممكن أرسم بهذه الطريقة، أنظر للجزء بهذا الشكل،
+
+456
+00:37:53,530 --> 00:37:57,670
+أقول، في عندي تنتين للأمام، solid wedge، تنتين
+
+457
+00:37:57,670 --> 00:38:02,450
+للخلف، dashed wedge، وعلى شكل الخط اللي موجودة في
+
+458
+00:38:02,450 --> 00:38:07,490
+مستوى اللوحة هذا الشكل اللي فيه المجموعات قبال
+
+459
+00:38:07,490 --> 00:38:11,990
+بعض، بنسميه Clips Conformation، إيش معناه Clips؟
+
+460
+00:38:13,360 --> 00:38:18,260
+متطابق الشكل المتطابق حتى ال clips اللي بتمسكوا
+
+461
+00:38:18,260 --> 00:38:22,660
+فيه الدفاتر ليش بيسموه clips؟ لأنه بيطبق و بيجيب
+
+462
+00:38:22,660 --> 00:38:26,620
+الأشياء مع بعض واضح؟ يعني كلمة clips دائما
+
+463
+00:38:26,620 --> 00:38:30,260
+بنستعملها لإيش؟ للتطابق الدبوس اللي بنشبك فيه
+
+464
+00:38:30,260 --> 00:38:34,180
+ورقتين شو بنسميه؟ clips فهذا الشكل بنقول عنه
+
+465
+00:38:34,180 --> 00:38:38,840
+eclipse confirmation ممكن نرسمه بطريقة ال dash
+
+466
+00:38:38,840 --> 00:38:45,310
+wedgeممكن ننظرله بزاوية أخرى، ممكن ننظرله بزاوية
+
+467
+00:38:45,310 --> 00:38:50,410
+أخرى، نرسمه بطريقة نتخيله أشبه ما يكون بالحصان
+
+468
+00:38:50,410 --> 00:38:54,950
+الخشبي اللي بيلعب عليه الجنباز، بتعرفوا الحصان
+
+469
+00:38:54,950 --> 00:38:58,910
+اللي بيلعب عليه الجنباز؟ لو حطينا هدولة زي هيك،
+
+470
+00:38:58,910 --> 00:39:04,040
+انسوا هدولة التنتين، إيش بيكون؟هيو زي شكل الحصان،
+
+471
+00:39:04,040 --> 00:39:08,120
+له رجلتين، فاحنا ممكن نرسمه زي هيك، بهادي الحالة
+
+472
+00:39:08,120 --> 00:39:17,780
+بنرسم خط مائل وبنرسم مع خط اللوح، خطين لفوجي مثله
+
+473
+00:39:17,780 --> 00:39:22,900
+هدول الهيدروجينات، التنتين، وبننزل لتحت و لتحت
+
+474
+00:39:23,340 --> 00:39:28,400
+مجمعتين فلاحظوا هذه طريقة ترسم غير عن هذه الطريقة
+
+475
+00:39:28,400 --> 00:39:31,700
+هذه الطريقة بنقول عنها ال sew horse يعني بتصيروا
+
+476
+00:39:31,700 --> 00:39:34,900
+شايفينه انتوا هيك عن الجانب و هاي المجمعتين اللي
+
+477
+00:39:34,900 --> 00:39:39,800
+لتحت زي تماما الحصان الخشبي لما بدكوا تعملوها
+
+478
+00:39:39,800 --> 00:39:45,930
+بدكوا ترسموا خط مائل خطين لفوق بيعنوهالمجمعتين
+
+479
+00:39:45,930 --> 00:39:49,310
+اللي قبل بعض بزام هدول لفوق، اذا هدول التنتين وان
+
+480
+00:39:49,310 --> 00:39:52,910
+بدهم يكونوا؟ لتحت، هدول التنتين وان بدهم يكونوا؟
+
+481
+00:39:52,910 --> 00:39:56,290
+لتحت، اذا هذه طريقة تانية لرسم ال eclipse
+
+482
+00:39:56,290 --> 00:40:01,230
+confirmation باستعمال ال Sohur's formula ممكن
+
+483
+00:40:01,230 --> 00:40:05,290
+تنظروا للجزء بنظرة تالتة تماما، بدل ما تنظروله عن
+
+484
+00:40:05,290 --> 00:40:08,970
+الجنب زي هيك او زي هيك ممكن تنظروله من الأمام
+
+485
+00:40:08,970 --> 00:40:14,960
+تخيلوا لو بتطلع عليه زي هيك، ايش بتشوفوا انتوا؟بس
+
+486
+00:40:14,960 --> 00:40:21,800
+تلاتة واللي ورا مخفيين وراهم اه فبهذه الحالة ممكن
+
+487
+00:40:21,800 --> 00:40:27,200
+يرسموا بيعملوا دائرة بيطلع من المركز تبعها واحد
+
+488
+00:40:27,200 --> 00:40:31,120
+اتنين تلاتة هذه الدائرة بتعبر عن التلاتة اللي قدام
+
+489
+00:40:31,120 --> 00:40:36,360
+وبيطلع من المحيط تبعها كمان واحد اتنين تلاتة من
+
+490
+00:40:36,360 --> 00:40:42,280
+جنب هدولة يعني انهم وين جايين خلف منهاواضح؟ هذه
+
+491
+00:40:42,280 --> 00:40:47,040
+الطريقة بيسموها طريقة in human في رسم اللي هي ال
+
+492
+00:40:47,040 --> 00:40:50,840
+conformations of إيثين لاحظوا كل هذا عبارة عن
+
+493
+00:40:50,840 --> 00:40:55,800
+الشكل إيش؟ المتطابق، الآن لو بدي أجي للشكل
+
+494
+00:40:55,800 --> 00:41:00,380
+المتعاكس بنسميه staggered conformation خلينا نبدأ
+
+495
+00:41:00,380 --> 00:41:05,480
+من هنا لو خلينا هذا زي هيك، الآن انتوا بإمكانكوا
+
+496
+00:41:05,480 --> 00:41:10,780
+تشوفوا قداش؟ ستة مش تلاتةلو رسمتوا التلاتة اللي
+
+497
+00:41:10,780 --> 00:41:16,580
+قدام من مركز الدائرة، هايهم، واحد، اتنين، تلاتة،
+
+498
+00:41:16,580 --> 00:41:20,140
+التلاتة اللي من ورا من المحيط دايما بنرسمها،
+
+499
+00:41:20,140 --> 00:41:22,920
+التلاتة الهيدروجينات اللي قدام من المركز، التلاتة
+
+500
+00:41:22,920 --> 00:41:27,620
+اللي ورا من محيط الدائرة، فلاحظوا انتوا قادرين هنا
+
+501
+00:41:27,620 --> 00:41:33,490
+تشوفوا أيش؟ الستةهي هدولة بهذا الشكل، هذه طالعة من
+
+502
+00:41:33,490 --> 00:41:36,350
+الجانب اللي هان، هذه طالعة من الجانب اللي هان من
+
+503
+00:41:36,350 --> 00:41:39,530
+المحيط اللي بنرسمها، وهذه طالعة من الجانب اللي
+
+504
+00:41:39,530 --> 00:41:43,930
+موجود عندى، اذا هى طريقة رسم ال staggered
+
+505
+00:41:43,930 --> 00:41:49,050
+conformation بطريقة in human طيب، الان لو هذه ال
+
+506
+00:41:49,050 --> 00:41:53,090
+staggered conformation بدكوا ترسموها بطريقة مثلا
+
+507
+00:41:53,090 --> 00:42:00,500
+ال dash wedge اتخيلوا هى الرابطة okayخلينا نرسم زي
+
+508
+00:42:00,500 --> 00:42:07,000
+ما هي هان هيك، هاي الشكل، إيش بتلاحظوا عندكوا هان
+
+509
+00:42:07,000 --> 00:42:13,600
+لفوق؟ على اتجاهكم؟ ال solid و هادى؟ برضه على
+
+510
+00:42:13,600 --> 00:42:17,420
+اتجاهكم، بس واحدة لفوق واحدة لتحت، هاي نرسموا
+
+511
+00:42:17,420 --> 00:42:21,660
+واحدة لفوق واحدة لتحت، في الخلف إيش عندكم؟ ال dash
+
+512
+00:42:21,660 --> 00:42:25,960
+واحدة لفوقواحدة لتحت وهدولة اللي بيكونوا على
+
+513
+00:42:25,960 --> 00:42:31,660
+المستوى اللي برسمهم بخط عادى ال H هدى و ال H هدى
+
+514
+00:42:31,660 --> 00:42:37,100
+واضح؟ اذا انا بهدوء بإمكاني ارسم الشكل باستعمال
+
+515
+00:42:37,100 --> 00:42:41,140
+Newman باستعمال ال dash wedge بإمكاني ارسمه بطريقة
+
+516
+00:42:41,140 --> 00:42:47,120
+الحصان اكيد يعني لو حطيت هذا الخط بسمائل شوية بنزل
+
+517
+00:42:47,120 --> 00:42:52,200
+واحدة لتحتوالتانية إذا هذه نزلة لتحت، هذولة
+
+518
+00:42:52,200 --> 00:42:56,840
+التنتين وين بيكونوا؟ وإذا هذه طالعة لفوق، هذولة
+
+519
+00:42:56,840 --> 00:43:01,140
+التنتين وين بيكونوا؟ لتحت، هذه طريقة الرسم
+
+520
+00:43:01,140 --> 00:43:06,540
+باستعمال ال saw horse إذا بإمكاني أنا أرسم ل clips
+
+521
+00:43:06,540 --> 00:43:08,980
+confirmation و ل staggered confirmation و هذا
+
+522
+00:43:08,980 --> 00:43:12,300
+الكلام لازم تعمله عليه تدريب بإيديكوا في البيت
+
+523
+00:43:12,300 --> 00:43:18,170
+باستعمال ال dash wedgeأو ال saw horse أو ال human
+
+524
+00:43:18,170 --> 00:43:22,910
+projection اللي هو أسقاط ال human لحد هيك بننتهي
+
+525
+00:43:22,910 --> 00:43:24,050
+اليوم ان شاء الله
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..22acc9872d92d88ba1af86d6dbefb9c937a338de
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_postprocess.srt
@@ -0,0 +1,2064 @@
+1
+00:00:06,190 --> 00:00:09,570
+بسم الله الرحمن الرحيم، اليوم إن شاء الله بدنا
+
+2
+00:00:09,570 --> 00:00:17,870
+نكمل في موضوع تفاعلات البنزين، المرة الماضية كل
+
+3
+00:00:17,870 --> 00:00:23,830
+كلامنا كان عن حلقة بنزين غير مبدلة، unsubstituted،
+
+4
+00:00:23,830 --> 00:00:27,680
+يعني مافيش عليهامافيش عليها ولا إشي وبنحط
+
+5
+00:00:27,680 --> 00:00:32,560
+Substituent واحدة طبعاً في هذه الحالة اللي بتطلع
+
+6
+00:00:32,560 --> 00:00:36,920
+على شكل حلقة البنزين المتماثل هيلاحظ أنه على أي
+
+7
+00:00:36,920 --> 00:00:41,140
+موقع من المواقع الستة بنقدر نحط ال Substituent
+
+8
+00:00:41,140 --> 00:00:46,020
+وبيطلع عندنا نفس الناتج طبعاً أخدنا طرق كتيرة
+
+9
+00:00:46,020 --> 00:00:49,860
+لإضافة Substituents أخدنا Alkylation, Acylation,
+
+10
+00:00:50,000 --> 00:00:55,720
+Halogenation, Nitration, Sulfonation وكل طريقةفي
+
+11
+00:00:55,720 --> 00:00:59,920
+إلها reagents معينة، خلاصة الموضوع إن ال reagents
+
+12
+00:00:59,920 --> 00:01:06,300
+لازم في النهاية يتوفر إلي electrophile لازم يتوفر
+
+13
+00:01:06,300 --> 00:01:12,100
+إلي إشي موجب عشان هذا الموجب يهاجم على حلقة
+
+14
+00:01:12,100 --> 00:01:15,280
+البنزين هذا الموضوع مافيش فيه خلاف، الآن إيش
+
+15
+00:01:15,280 --> 00:01:20,700
+الجديد اليوم في الموضوع تبعنا؟الجديد كالقاتل أنه
+
+16
+00:01:20,700 --> 00:01:27,000
+لو أنا كنت حاطط على ذرة البنزين مجموعة وبدأ أحط
+
+17
+00:01:27,000 --> 00:01:32,520
+المجموعة التانية بيصير عندي شغلتين بيصير عندي
+
+18
+00:01:32,520 --> 00:01:36,460
+شغلتين الآن
+
+19
+00:01:36,460 --> 00:01:41,420
+لما بدنا نعمل إضافة على حلقة بنزين في بالأساس
+
+20
+00:01:41,420 --> 00:01:47,670
+عليها مجموعة وبدنا نضيف المجموعة التانيةسنلاحظ
+
+21
+00:01:47,670 --> 00:01:53,150
+القادة أن المجموعة الأولى تتدخل في سرعة التفاعل
+
+22
+00:01:53,150 --> 00:01:57,210
+بمعنى يمكن بسبب وجود المجموعة الأولى أن حلقة
+
+23
+00:01:57,210 --> 00:02:04,430
+البنزين تتفاعل بسرعة تتفاعل بسرعةأبطأ في التفاعل
+
+24
+00:02:04,430 --> 00:02:09,130
+إذا إليها تأثير متعلق بشيء بنسميه ال reactivity أو
+
+25
+00:02:09,130 --> 00:02:14,790
+النشاط إذا هذه ال substituent الأولى في إليها إيش
+
+26
+00:02:14,790 --> 00:02:20,650
+reactivity effect يعني يا بتزيد السرعة لإبدال
+
+27
+00:02:20,650 --> 00:02:25,830
+المجموعة الثانية يا بتقلل السرعة واضح الشغل التاني
+
+28
+00:02:25,830 --> 00:02:31,800
+أن المجموعة الأولى بتكون أخدت موقعفاللي دائما
+
+29
+00:02:31,800 --> 00:02:34,960
+موجود في الأول بيصير يتحكم في اللي بيجي بعد هيك
+
+30
+00:02:34,960 --> 00:02:38,840
+اليوم .. يوم ما بده تيجي المجموعة التانية هل هتيجي
+
+31
+00:02:38,840 --> 00:02:41,780
+على الموقع المجاور إلها اللي هو بيكون بالنسبة إلها
+
+32
+00:02:41,780 --> 00:02:45,780
+ortho ولا هتيجي على بعض موقع meta ولا هتيجي على
+
+33
+00:02:45,780 --> 00:02:49,480
+الموقع اللي بعده bara برضه المجموعة اللي موجودة
+
+34
+00:02:49,480 --> 00:02:54,730
+بتتحكم إذا ..هنا صار عندى اشي جديد انا مهتم فيه
+
+35
+00:02:54,730 --> 00:02:59,570
+انه وجود مجموعة اثر على شغلتين اثر على ال
+
+36
+00:02:59,570 --> 00:03:04,090
+reactivity سرعة التفاعل و ال orientation ال
+
+37
+00:03:04,090 --> 00:03:08,570
+orientation يعني وين يروح او وين تروح المجموعة
+
+38
+00:03:08,570 --> 00:03:12,890
+التانية بالنسبة للمجموعة الاولى وهذا الكلام اللى
+
+39
+00:03:12,890 --> 00:03:17,970
+احنا بدنا ندرسه في التفصيل في محاضرة اليومإيش
+
+40
+00:03:17,970 --> 00:03:21,370
+التأثير بتاع المجموعة الأولى من ناحية reactivity
+
+41
+00:03:21,370 --> 00:03:26,850
+ومن ناحية orientation إذا لو بدنا نسألكوا المجموعة
+
+42
+00:03:26,850 --> 00:03:31,450
+أكم effect إلها ال reactivity تسريع أو تبطيق
+
+43
+00:03:31,450 --> 00:03:37,790
+orientation توجيه وين تروح المجموعة لجديدة الآن
+
+44
+00:03:37,790 --> 00:03:45,050
+بالنسبة لل band الأول المجموعات حقيقة تتراوح ما
+
+45
+00:03:45,050 --> 00:03:50,950
+بين مجموعاتبتزيد سرعة التفاعل بتزيد ال reactivity
+
+46
+00:03:50,950 --> 00:03:56,830
+بشكل كبير وبين مجموعات بتثبت سرعة التفاعل بشكل
+
+47
+00:03:56,830 --> 00:04:02,890
+كبير وفي عندنا هنا زي ما بتلاحظوا scheme واضح
+
+48
+00:04:02,890 --> 00:04:08,010
+بيوضح هذا الكلاميعني لو اتطلعتوا على افضل
+
+49
+00:04:08,010 --> 00:04:11,430
+المجموعات اللي بنزيد السرعه على التفاعل هتلاحظوا
+
+50
+00:04:11,430 --> 00:04:15,910
+مجموعة الـ NH2 يعني لو كان عندكم أنيلين و بدنا
+
+51
+00:04:15,910 --> 00:04:21,530
+نعمل عليه تفاعل تاني التفاعل سريع جدا مجموعة الـ
+
+52
+00:04:21,530 --> 00:04:28,760
+OHاللي هو لو كان عندكم Phenol البنزين .. الـ
+
+53
+00:04:28,760 --> 00:04:33,220
+Phenol نشير جداً في التفاعل لو كان عندكم مجموعة
+
+54
+00:04:33,220 --> 00:04:38,040
+الـ OCH3 البنزين اللي عليه OCH3 اسمه أنيزول
+
+55
+00:04:38,040 --> 00:04:43,700
+الانيزول سريع جداً في التفاعل لو كان في عندكم
+
+56
+00:04:43,700 --> 00:04:50,040
+مجموعة الميثل CH3 الطلوينسريع جدا في التفاعل لو
+
+57
+00:04:50,040 --> 00:04:57,260
+كان عندكم N H عليها OCH3 برضه تعتبر السريعة و
+
+58
+00:04:57,260 --> 00:05:00,200
+بالمناسبة الترتيب اللي موجود هنا برضه بيعني ان
+
+59
+00:05:00,200 --> 00:05:03,520
+واحدة أسرع من التانية يعني إذا بتلاحظوا ال O H
+
+60
+00:05:04,410 --> 00:05:10,210
+بتسرع أكتر من الميثل مثلا واضح أو ال N H2 أكتر من
+
+61
+00:05:10,210 --> 00:05:16,930
+ال OCH3 ال H اللي هو البنزين العادى تعتبر حالة وسط
+
+62
+00:05:16,930 --> 00:05:21,550
+في السرعة الأن من أبطأ الشغلات اللي بتوجهنا ال
+
+63
+00:05:21,550 --> 00:05:27,170
+Nitroالنيترو بنزين بيكون يعني generally
+
+64
+00:05:27,170 --> 00:05:33,150
+unreactive، التفاعل إيش ماله؟ بطيء كتير طبعا زيه
+
+65
+00:05:33,150 --> 00:05:37,730
+ال sulpholic acid و زيه ال COOH و ال CWBOR و ال
+
+66
+00:05:37,730 --> 00:05:41,770
+cyano و ال CHO اللي هي CWBOH ال aldehyde و ال
+
+67
+00:05:41,770 --> 00:05:46,210
+halogensكل هدولة من ناحية المبدأ في ال reactivity
+
+68
+00:05:46,210 --> 00:05:51,390
+أقل من إيش؟ أقل من البنزين، إذا أنا حد المقارنة
+
+69
+00:05:51,390 --> 00:05:54,710
+اللي عندي هو إيش؟ البنزين ال substitute اللي
+
+70
+00:05:54,710 --> 00:06:00,250
+موجودة فيه هي ال H، في أشياء أسرع من البنزينفي
+
+71
+00:06:00,250 --> 00:06:03,810
+أشياء أبطأ من البنزين، اللي مشهور في الأسرع من
+
+72
+00:06:03,810 --> 00:06:09,730
+البنزين الانيلين، الفينول، الطولوين، الاليزول،
+
+73
+00:06:09,730 --> 00:06:14,110
+اللي أبطأ من البنزين بشوية صغيرة الهالوجينز، فلورو
+
+74
+00:06:14,110 --> 00:06:18,870
+كلوري بروم، اللي أبطأ من البنزين كتير كتيرالـ
+
+75
+00:06:18,870 --> 00:06:23,250
+Nitro والـ Cyano يعني كأنه من أبطأ الأشياء في
+
+76
+00:06:23,250 --> 00:06:29,230
+التفاعلات الـ Nitro والـ Cyano واضح؟ هذا بالنسبة
+
+77
+00:06:29,230 --> 00:06:33,470
+للمجموعات إذا كأننا قسمنا المجموعات إلى strongly
+
+78
+00:06:33,470 --> 00:06:38,550
+activating groups يعني منشطة بشكل كبير و strongly
+
+79
+00:06:38,550 --> 00:06:46,130
+deactivating group مثبتة لسرعة التفاعل بشكل كبير
+
+80
+00:06:49,150 --> 00:06:55,330
+الآن بنجي لعامل التاني اللي حكينا عنه اللي هو الـ
+
+81
+00:06:55,330 --> 00:07:00,890
+Orientation، واضح؟ إذا بنطلع على نفس المجموعات،
+
+82
+00:07:00,890 --> 00:07:06,170
+لاحظوا القاتل، إنه بشكل عامالمجموعات اللي بتكون
+
+83
+00:07:06,170 --> 00:07:09,490
+activating .. المجموعات اللي بتكون activating
+
+84
+00:07:09,490 --> 00:07:14,270
+بتوجه المجموعات القادمة على موقع Orthopara
+
+85
+00:07:14,270 --> 00:07:21,050
+فبنسميها Orthopara Directing Groupsيعني مجموعات
+
+86
+00:07:21,050 --> 00:07:25,050
+لما تيجي مجموعة جديدة بتخليها وين تروح على موقع
+
+87
+00:07:25,050 --> 00:07:29,430
+Ortho وموقع Vara بيصير خليط عندى يعني لو افترضت
+
+88
+00:07:29,430 --> 00:07:34,650
+مثلا عندى 100 جزء بتفاعلوا ممكن 60 منهم 100 جزء
+
+89
+00:07:34,650 --> 00:07:39,230
+Phenol وقاعد بعمل عليهم مثلا Nitrogen ممكن 60 جزء
+
+90
+00:07:39,230 --> 00:07:43,110
+ييجي ال Nitro فيهم على موقع Ortho ممكن 40 جزء ييجي
+
+91
+00:07:43,110 --> 00:07:47,710
+ال Nitro فيهم على موقع Vara يعني بيطلع عنده خليط
+
+92
+00:07:47,710 --> 00:07:51,810
+من النواتج مش علىمش على نفس الجزء بيجي على
+
+93
+00:07:51,810 --> 00:07:55,410
+orthopara لأ ما انا مش جزء واحد اللي بفعله انا
+
+94
+00:07:55,410 --> 00:07:59,770
+بفعل ملايين الجزيات يعني لو كنت بفعل one mole مثلا
+
+95
+00:07:59,770 --> 00:08:03,170
+بكون بفعل six point oh two two في عشر أوس تلاتة
+
+96
+00:08:03,170 --> 00:08:09,990
+وعشرين عدد avocado فجزء منهم بيتفعل على ال orthoو
+
+97
+00:08:09,990 --> 00:08:16,130
+جزء منهم بتفعل وين؟ على ال para position فالقاعدة
+
+98
+00:08:16,130 --> 00:08:20,330
+بشكلها العام انه ال activating groups they are
+
+99
+00:08:20,330 --> 00:08:25,410
+generally ortho and para directing groups الآن ال
+
+100
+00:08:25,410 --> 00:08:28,770
+deactivating groups they are generally meta
+
+101
+00:08:28,770 --> 00:08:32,070
+directing groups يعني بيخلوا المجموعة الجديدة وين
+
+102
+00:08:32,070 --> 00:08:38,350
+تروح؟ على موقع meta بيجينا شغلة انه في النص
+
+103
+00:08:42,090 --> 00:08:45,250
+الهالوجينز الهالوجينز قبل شوية ايش قلنا عنهم احنا
+
+104
+00:08:45,250 --> 00:08:48,650
+طالما انهم اقل من الهيدروجيل activating ولا
+
+105
+00:08:48,650 --> 00:08:52,450
+deactivating؟ deactivating لكن بيكونوا
+
+106
+00:08:52,450 --> 00:08:58,110
+orthoparadirectic groupsواضح؟ إذا بشكل عام ال
+
+107
+00:08:58,110 --> 00:09:03,410
+activating groups أورثو بارا ال deactivating ميتا
+
+108
+00:09:03,410 --> 00:09:08,390
+ما عدا ال halogens they are deactivating groups
+
+109
+00:09:08,390 --> 00:09:13,390
+however أورثو بارا directing groups واضح؟ هذه
+
+110
+00:09:13,390 --> 00:09:18,130
+أشياء طبعا بنحصل عليها وعرفوها بالتجربة بعدين
+
+111
+00:09:18,130 --> 00:09:21,310
+بيحاولوا يعملوا تفسير على ان و الرأس لكن الأساس
+
+112
+00:09:21,310 --> 00:09:28,650
+فيها التجربةالأساس فيها التجربة، واضح؟ هذا اللي هو
+
+113
+00:09:28,650 --> 00:09:34,050
+تأثير الـ Substituent من ناحية الـ activity و من
+
+114
+00:09:34,050 --> 00:09:39,250
+ناحية الـ orientation من ناحية الـ activity و من
+
+115
+00:09:39,250 --> 00:09:44,850
+ناحية الـ orientation الآن ممكن نحاول نعطي تفسيرات
+
+116
+00:09:44,850 --> 00:09:51,460
+في الأساس احنا قلنا الـ activity من وين عرفناهامن
+
+117
+00:09:51,460 --> 00:09:56,980
+التجربة لكن بعد هيك بنقدر نحاول نعمل تفسير يعني
+
+118
+00:09:56,980 --> 00:10:03,340
+مثلا الميثيلي جروب او activating ليش يا ترى
+
+119
+00:10:03,340 --> 00:10:10,880
+الميثيلي جروب بيوده على موقعأورثو بارا مش على موقع
+
+120
+00:10:10,880 --> 00:10:16,260
+ميتا لما بدنا نيجي نعمل هذا الكلام بنيجي بنتخيل
+
+121
+00:10:16,260 --> 00:10:21,140
+مثلا بنقول خلينا ندرس الموقع بارا بنيجي بنحط
+
+122
+00:10:21,140 --> 00:10:24,900
+الكتروفايل على الموقع بارا هاي المثل واحد اتنين
+
+123
+00:10:24,900 --> 00:10:28,960
+تلاتةواحد اتنين تلاتة اربعة له موقع اربعة بالنسبة
+
+124
+00:10:28,960 --> 00:10:34,240
+للمثل او هاي ال ortho ميتا هاي ال para بالنسبة له
+
+125
+00:10:34,240 --> 00:10:39,400
+بنحط ال electro file هنا و بنشوف ايش اللي بينشق
+
+126
+00:10:39,400 --> 00:10:43,080
+عندنا بنحط ال electro file مجرد ما حطينا ال
+
+127
+00:10:43,080 --> 00:10:49,420
+electro file هنا حيصير في عندنا positiveعلى هذا
+
+128
+00:10:49,420 --> 00:10:54,760
+الموقع الان هذا ال positive بيعمل resonance ولا لأ
+
+129
+00:10:54,760 --> 00:10:58,220
+بيعمل resonance بمعنى ان هذه ممكن تتحرك تصير ال
+
+130
+00:10:58,220 --> 00:11:03,620
+positive على هذا الموقع وهذا كمان بيعمل resonance
+
+131
+00:11:03,620 --> 00:11:07,500
+ممكن تصير هنا اذا زي ما بتلاحظوا ان ال positive
+
+132
+00:11:07,500 --> 00:11:16,380
+بيكون بينقل واضح delocalized يعني مش مثبتمش متمركز
+
+133
+00:11:16,380 --> 00:11:19,560
+في موقع واحد، مين تقول هانه هانه هانه إذا أنا
+
+134
+00:11:19,560 --> 00:11:23,340
+بتطلع .. إذا أنا بتطلع عليهم، بلاحظ إنه أحد
+
+135
+00:11:23,340 --> 00:11:26,600
+الأشكال، يعني لو بدأ أشوف هذا ال carbocation هنا
+
+136
+00:11:26,600 --> 00:11:30,100
+secondary carbocation لو بدأ أشوف هذا ال
+
+137
+00:11:30,100 --> 00:11:35,930
+carbocationstill secondary لو بدأ أشوف هذا الكاربو
+
+138
+00:11:35,930 --> 00:11:40,850
+كاتيون tertiary لأن أحد ال resonance structures
+
+139
+00:11:40,850 --> 00:11:46,290
+اللي عملها tertiary بفضل هذا الموقع طبعا اللي بدو
+
+140
+00:11:46,290 --> 00:11:51,510
+يصير ان انتوا بعد هيك لو اجيتوا عملتوا على الميتا
+
+141
+00:11:51,510 --> 00:11:55,150
+هتلاحظوا انه مش هيكون في واحد tertiary
+
+142
+00:11:58,080 --> 00:12:03,500
+عشان تكونوا متأكدين مثل هذه الرسمة تلت مرات تحطوا
+
+143
+00:12:03,500 --> 00:12:08,780
+ال Electrophile على ال Ortho تحطوه على ال Meta
+
+144
+00:12:08,780 --> 00:12:14,520
+تحطوه على ال Para هتلاحظوا أنه في حالة ال Ortho و
+
+145
+00:12:14,520 --> 00:12:18,320
+في حالة ال Para أحد ال structures ال resonance
+
+146
+00:12:18,320 --> 00:12:21,540
+structures very stable هذا اللي بيشجع أنه يروح على
+
+147
+00:12:21,540 --> 00:12:24,820
+ال Ortho و ال Para في حالة ال Meta هتلاحظوا أنه
+
+148
+00:12:24,820 --> 00:12:31,030
+مافيش شيءCarbocation tertiary فالان اي توجه بيكون
+
+149
+00:12:31,030 --> 00:12:36,070
+احد اطرافه اللي بيعمله contribution يعني بيدخلوا
+
+150
+00:12:36,070 --> 00:12:39,630
+في ال resonance tertiary بيكون مفضل ان هو اللي
+
+151
+00:12:39,630 --> 00:12:44,270
+بيقدي ال tertiary عندى البارا وال اورثو لو عملته
+
+152
+00:12:44,270 --> 00:12:47,650
+لو روحتوا عملتوا الميتا في البيت هيك زي واجب
+
+153
+00:12:47,650 --> 00:12:51,150
+homework حطيتوا على الميتا H وelectrophile وعملتوا
+
+154
+00:12:51,150 --> 00:12:54,510
+بوستفانو نجلته ونجلته ونجلته هتلاحظوا انه مش هيجي
+
+155
+00:12:54,510 --> 00:13:02,030
+على ال tertiaryواضح فسبب التفضيل لل ortho وال para
+
+156
+00:13:02,030 --> 00:13:07,110
+positions هنا أنه بيكون أحد ال resonance
+
+157
+00:13:07,110 --> 00:13:12,010
+structures لل carbocation the stable tertiary
+
+158
+00:13:12,010 --> 00:13:19,520
+carbocation واضحلاحظوا كم عملية الثبات عملية مهمة،
+
+159
+00:13:19,520 --> 00:13:24,040
+واضح؟ كل الناس بتسأل إيش؟ للثبات التفاعل نتيجته
+
+160
+00:13:24,040 --> 00:13:28,140
+الآن بإيش محكومة؟ بالثبات وجود أحد ال resonance
+
+161
+00:13:28,140 --> 00:13:31,200
+structures، tertiary هو اللي بيخلي التفاعل يروح
+
+162
+00:13:31,200 --> 00:13:38,540
+على ال orthoو ال bara positions الآن لو اجينا
+
+163
+00:13:38,540 --> 00:13:43,400
+عملنا تجربة نشوف النتائج لو اجينا عملنا تجربة نشوف
+
+164
+00:13:43,400 --> 00:13:48,820
+النتائج بالظبط مثلا لو أخدنا التلوين التلوين
+
+165
+00:13:48,820 --> 00:13:55,820
+اتفقنا انه orthobaradirecting ال methyl group
+
+166
+00:13:55,820 --> 00:13:59,400
+orthobaradirecting group بناء على ذلك لو اجينا
+
+167
+00:13:59,400 --> 00:14:04,950
+عملنا nitration ال nitro وين هتروح؟يا إما على الـ
+
+168
+00:14:04,950 --> 00:14:10,230
+Ortho يا إما على الـ Para نشوف نتائج واقعية كيف
+
+169
+00:14:10,230 --> 00:14:15,670
+طلعت بالتجربة بالظبط لما عملوا هذا التفاعل لاحظوا
+
+170
+00:14:15,670 --> 00:14:22,610
+أنه 63% من الناتجأجت الـ Nitrofy على الـ
+
+171
+00:14:22,610 --> 00:14:29,110
+Orthoposition و 34% من الناتج أجت الـ Nitrofy على
+
+172
+00:14:29,110 --> 00:14:35,210
+الـ Paraposition و فقط 3% من الناتج اللي بنعتبره
+
+173
+00:14:35,210 --> 00:14:41,530
+إيش يعني negligible مهمل أجت فيه على الميتا واضح؟
+
+174
+00:14:42,410 --> 00:14:47,770
+أجت فيه علمية لاحظوا هنا بتكونوا برضه دقيقين بفهم
+
+175
+00:14:47,770 --> 00:14:52,130
+الدنيا بتكونوا دقيقين بفهم الدنيا يعني احنا بنحط
+
+176
+00:14:52,130 --> 00:14:57,210
+قوانين تمام؟ بس مش لازم الدنيا .. مش لازم الدنيا
+
+177
+00:14:57,210 --> 00:15:01,310
+مية في المية تكون ماشي على القوانين إلا يكون فيه
+
+178
+00:15:01,310 --> 00:15:06,530
+شوية انحراف يعني مثلا ربنا سبحانه وتعالى بيقول و
+
+179
+00:15:06,530 --> 00:15:10,770
+لا تقتلوا النفس التي حرم الله إلا بالحقالأصل في
+
+180
+00:15:10,770 --> 00:15:16,010
+المجتمع أنه مافيش قتل، لكن في السنة بنهز المجتمع
+
+181
+00:15:16,010 --> 00:15:20,510
+أربع أو خمس أو ست مرات بجرائم قتل مشعة، هي الـ3%
+
+182
+00:15:20,510 --> 00:15:27,370
+هذه، واضح؟فلما نقول أن مثلا هذا الشارع اتجاه واحد،
+
+183
+00:15:27,370 --> 00:15:31,630
+لازم كل السيارات تمشي بهذا الشكل، الآن بيصيرش
+
+184
+00:15:31,630 --> 00:15:36,630
+أربع، خمس، ست حالات في وقت ما يمشوا عكس القانون،
+
+185
+00:15:36,630 --> 00:15:40,570
+بيصير، واضح؟ فدائما هذه الأشياء ما تستغربوهاش، لأن
+
+186
+00:15:40,570 --> 00:15:44,830
+هذا حال الدنياالـ trend العام التوجه العام واضح
+
+187
+00:15:44,830 --> 00:15:49,570
+تماما ان الـ nitrate لما يكون عند طلوين مثل group
+
+188
+00:15:49,570 --> 00:15:53,630
+ortho para directing group واضحة نسبة تلاتة وستين
+
+189
+00:15:53,630 --> 00:15:57,070
+في المية واربعة وتلاتين في المية لكن بيصير أشياء
+
+190
+00:15:57,070 --> 00:16:02,870
+بسيطة تلاتة في المية ميتة بيصير مش معدوم يعني واضح
+
+191
+00:16:02,870 --> 00:16:07,850
+وهذه نتائج تجريبية
+
+192
+00:16:08,590 --> 00:16:14,770
+الآن لاحظوا في المقابل مجموعة السيانو إحنا إذا
+
+193
+00:16:14,770 --> 00:16:19,810
+بتطلعوا السيانو اعتبرناها Deactivating Ometa
+
+194
+00:16:19,810 --> 00:16:24,610
+Directing Group Deactivating Ometa Directing Group
+
+195
+00:16:24,610 --> 00:16:29,630
+لو أنا إجيت بدي أطلع على النتيجة الفعلية للتفاعل
+
+196
+00:16:29,630 --> 00:16:36,870
+النتيجة الفعلية هلاحظ إن الميتا لوحده ماخد 81%
+
+197
+00:16:36,870 --> 00:16:38,470
+واضح؟
+
+198
+00:16:40,760 --> 00:16:44,840
+الأورثو مازال مااخدله نسبة لكن بتضال بالنسبة
+
+199
+00:16:44,840 --> 00:16:49,800
+للواحد و ثمانين فالمية قليلة البارا اتنين فالمية
+
+200
+00:16:49,800 --> 00:16:56,170
+اذا ال major reaction هنا الميتةعشان هيك لما إحنا
+
+201
+00:16:56,170 --> 00:17:00,650
+بنيجي بنحكي إنه هذا التفاعل بيعطينا ال meta
+
+202
+00:17:00,650 --> 00:17:05,170
+product أو ال orthو زاد ال para product بنقول as
+
+203
+00:17:05,170 --> 00:17:10,090
+major products كلمة major products بتختلف عن
+
+204
+00:17:10,090 --> 00:17:14,830
+exclusive products exclusive يعني حصري يعني مافيش
+
+205
+00:17:14,830 --> 00:17:20,070
+نهائيا غيره أنا هنا مابقولش exclusive بشكل مطلق
+
+206
+00:17:20,070 --> 00:17:26,820
+أنا بقول بشكل عام واضح؟زي ما بنقول بشكل عام،
+
+207
+00:17:26,820 --> 00:17:32,440
+المسلم لا يغضب المسلم بشكل عام، بس حد بيقدر يقول
+
+208
+00:17:32,440 --> 00:17:38,140
+إنه هذه بشكل حصري؟ لأ، بشكل عام، بشكل عام التفاعل
+
+209
+00:17:38,140 --> 00:17:44,480
+ميته في حالة وجود الـ cyano group هذا ممنعش إنه في
+
+210
+00:17:44,480 --> 00:17:50,900
+أشياء تانية بتصير شدود عن القاعدة الآن
+
+211
+00:17:53,540 --> 00:17:57,920
+هكذا أصبح نوعا ما واضح لدي أنه لو كان في عندي
+
+212
+00:17:57,920 --> 00:18:01,920
+مجموعة .. لو كان في عندي مجموعة، كيف تأثيرها؟ من
+
+213
+00:18:01,920 --> 00:18:06,980
+ناحية الـ reactivity و من ناحية الـ orientation؟
+
+214
+00:18:06,980 --> 00:18:12,320
+الآن، يا تورا، لو كان في مجموعتين، مش مجموعة
+
+215
+00:18:12,320 --> 00:18:19,680
+واحدة، و بدأ تيجي التالتة، بيصير في إيش؟نوع من
+
+216
+00:18:19,680 --> 00:18:25,040
+التنافس لو في عندى مجموعتين و بدأ تيجي التالتة
+
+217
+00:18:25,040 --> 00:18:30,200
+بيصير في عندى نوعا ما نوع من التنافس خلينا ناخد
+
+218
+00:18:30,200 --> 00:18:37,280
+بعض الأمثلة الآن اتطلع عندى هنا ال CH3 و ال OCH3
+
+219
+00:18:37,280 --> 00:18:41,780
+نفترض هذا الجزء موجود مالناش فيه كيف يتكون مش صعب
+
+220
+00:18:41,780 --> 00:18:48,460
+يتكونواضح؟ لو بدأت أقولكم السؤال يا تورا كيف هذا
+
+221
+00:18:48,460 --> 00:18:54,020
+الجزء ممكن يكون اتكون؟ إيش أفضل طريقة عشان إحنا
+
+222
+00:18:54,020 --> 00:18:59,320
+نصنعه مبتدئين من البنزين؟
+
+223
+00:18:59,320 --> 00:19:05,260
+ارجعولي لنقطة، مين more activating؟
+
+224
+00:19:05,260 --> 00:19:12,660
+بنرجع و بنفرجيكوا إياها على الشاشةالـ OCH3 more
+
+225
+00:19:12,660 --> 00:19:19,700
+activating than CH3 واضح؟ بتعمل activation أكتر
+
+226
+00:19:19,700 --> 00:19:25,160
+بناء على ذلك لو أنا بدي أبدأ ببنزين إذا حطيت ال
+
+227
+00:19:25,160 --> 00:19:29,840
+OCH3 و بعدين بدي أكمل التفاعل أعمل methylation
+
+228
+00:19:29,840 --> 00:19:33,700
+هتيجي المثل على ال ortho و ال para position باخد
+
+229
+00:19:33,700 --> 00:19:37,180
+مركب ال para اللي أنا مهتم فيه و لو حطيت المثل
+
+230
+00:19:37,180 --> 00:19:42,330
+groupوبدي اضيف ال O مثل برضه هتيجي على ال ortho و
+
+231
+00:19:42,330 --> 00:19:47,490
+ال para لكن انا ولا اصح ان اعمله ان ابدأ ابتلوين
+
+232
+00:19:47,490 --> 00:19:48,830
+ولا ابدأ
+
+233
+00:19:52,350 --> 00:19:59,250
+بال OCH3 لأن ال OCH3 more activating واضح؟ تفاعلها
+
+234
+00:19:59,250 --> 00:20:04,290
+بيكون إيش أسرع الآن هذا مش شغلنا كيف حضروا هذا
+
+235
+00:20:04,290 --> 00:20:07,370
+الجزء إحنا شغلنا كيف هذا الجزء بدنا نعمل عليه
+
+236
+00:20:07,370 --> 00:20:13,040
+تفاعل إضافيمثلا بدنا نفعله مع البروميين ال مثل
+
+237
+00:20:13,040 --> 00:20:17,680
+group اورثو بارا directing group البارا تبعها مسكر
+
+238
+00:20:17,680 --> 00:20:24,760
+اش بيضللها ال اورثو و ال ا مثل اورثو بارا
+
+239
+00:20:24,760 --> 00:20:29,160
+directing group البارا مسكر اش بيضللها ال اورثو
+
+240
+00:20:29,160 --> 00:20:32,540
+position اللي جنبها هنا طيب لو اجينا ضفنا
+
+241
+00:20:32,540 --> 00:20:36,860
+البرومياطورة وين بده يروح التفاعل؟بدو ييجي على ال
+
+242
+00:20:36,860 --> 00:20:41,920
+ortho تبع ال مثل ولا على ال ortho تبع ال او مثل اه
+
+243
+00:20:41,920 --> 00:20:47,660
+هنا الأقوى بتغلب مين more activating ال OCH3
+
+244
+00:20:47,660 --> 00:20:52,260
+عشانيك بلاحظ ان بروم ايجي هنا مش على هذا الموقع
+
+245
+00:20:54,000 --> 00:20:58,340
+واضح؟ بهمش، هو بيكون Ortho بالنسبة لل CH3 لكن ليش
+
+246
+00:20:58,340 --> 00:21:03,520
+مايجياش Ortho لل CH3؟ لأنه مثل أسرع و more active
+
+247
+00:21:03,520 --> 00:21:09,160
+بالتفاعل، أنه أول ما ييجي لبروم، يروحياخدوا على ال
+
+248
+00:21:09,160 --> 00:21:13,660
+اورثو بالنسبة له إذا هنا اللي حكم نتيجة التفاعل ال
+
+249
+00:21:13,660 --> 00:21:17,880
+activating جداش هذا activating جداش هذا activating
+
+250
+00:21:17,880 --> 00:21:23,180
+واضح اللي هو ال reactivity النسبية relative
+
+251
+00:21:23,180 --> 00:21:27,920
+reactivity of both the O-methyl group and the CH3
+
+252
+00:21:27,920 --> 00:21:32,730
+group O-methyl group is more activating thanالـ
+
+253
+00:21:32,730 --> 00:21:36,930
+CH3 group عشان هيك الناتج تبعها اتغلب على الناتج
+
+254
+00:21:36,930 --> 00:21:42,970
+تبع ال CH3 واضح؟
+
+255
+00:21:42,970 --> 00:21:49,810
+هي هانا بيجي عندنا مثال تاني عندنا مجموعتين و بدنا
+
+256
+00:21:49,810 --> 00:21:57,040
+نحط التالتة عندنا أيش؟مجمعتين و بدنا نحط التالتة
+
+257
+00:21:57,040 --> 00:22:02,400
+الان هالمجمعتين اللي عندياهم انا المثل .. المثل
+
+258
+00:22:02,400 --> 00:22:08,040
+وين بتودى؟ على ال ortho .. البرة تبقى همسكتع
+
+259
+00:22:08,040 --> 00:22:12,200
+الأورثو والنيترو وين بتوده؟ على ال meta الان
+
+260
+00:22:12,200 --> 00:22:16,440
+لاحظوا معنى ال meta تبع النيترو هو نفس ال ortho
+
+261
+00:22:16,440 --> 00:22:19,540
+تبع ال methyl يعني كأنه صار عند بس ال tintel
+
+262
+00:22:19,540 --> 00:22:22,920
+بواجهه على هذا الموقع هذا الموقع نهائي اللي مافيش
+
+263
+00:22:22,920 --> 00:22:30,550
+إشي بيوده عليهواضح؟ الان O2 بتودع على الميتا
+
+264
+00:22:30,550 --> 00:22:35,050
+بالنسبة لها هاي الميتا one two three بتودع موقع
+
+265
+00:22:35,050 --> 00:22:39,550
+تلاتة بالنسبة لها والمثل بتودع على موقع اتنين
+
+266
+00:22:39,550 --> 00:22:43,730
+بالنسبة لها اورثو اذا كأنه المجمعتين بيودوا على
+
+267
+00:22:43,730 --> 00:22:49,910
+نفس الموقع عشانك بيصير عنده مجموعة النيترو الجديدة
+
+268
+00:22:49,910 --> 00:22:54,050
+هذه بتيجي على هذا الموقع ولو كان عندنا النيترو
+
+269
+00:22:54,050 --> 00:22:58,930
+كتير بتيجي اللي بعدهاكمان على هذا الموقع، على
+
+270
+00:22:58,930 --> 00:23:01,830
+الموقع التاني، يعني بيصير مرتين نيتراشن، بيصير
+
+271
+00:23:01,830 --> 00:23:08,390
+عندى الـ Trinitro تلوين اللي هو ال explosive TNT
+
+272
+00:23:08,390 --> 00:23:16,090
+المادة المتفجرة اللي بيسموها TNT، واضح؟
+
+273
+00:23:16,090 --> 00:23:24,210
+شفتوا كيف تجميع التأثيرات؟ يعني كأنه اتفقت مصالح
+
+274
+00:23:24,210 --> 00:23:30,940
+الـ Nitroوالمثل على هذا الموقع زي ما بيصير تماما
+
+275
+00:23:30,940 --> 00:23:38,320
+في السياسة هاي في عندنا كمان مثال ممتعة هذه
+
+276
+00:23:38,320 --> 00:23:41,900
+الأمثلة لإيه؟ لإنه بتفرجيكوا واقع الدنيا كيف
+
+277
+00:23:41,900 --> 00:23:47,660
+المصالح بتتفق كيف التنافس بيصير في عندكم مثل
+
+278
+00:23:47,660 --> 00:23:49,040
+وchlor
+
+279
+00:23:51,960 --> 00:23:57,640
+الان الميثل اكتفاط الكلور دي مش مشكلة مشكلتي انا
+
+280
+00:23:57,640 --> 00:24:02,940
+في ال orientation وين بيودي الميثل وين بيودي
+
+281
+00:24:02,940 --> 00:24:08,140
+الكلور الان الميثل الأحمر بيودي على موقع ارثو يعني
+
+282
+00:24:08,140 --> 00:24:13,470
+هذا الموقع او هذا الموقعأو بارا اورثو او بارا يعني
+
+283
+00:24:13,470 --> 00:24:16,610
+المثل ممكن يحط حسب اللون تبعه زي ما انتوا شايفين
+
+284
+00:24:16,610 --> 00:24:21,270
+اورثو اورثو او بارا يعني هذا الموقع متحقله هذا
+
+285
+00:24:21,270 --> 00:24:26,790
+الموقع متحقله هذا الموقع متحقله الكلور وين بيوده
+
+286
+00:24:26,790 --> 00:24:30,730
+بالنسباله بيودع ال اورثو وين ال اورثو تبع الكلور
+
+287
+00:24:30,730 --> 00:24:37,710
+هذا وهذا هاي واحد اتنين واحدالاتنين والبارة اللي
+
+288
+00:24:37,710 --> 00:24:42,550
+هنا إذا مرة تانية اتحدوا في التلت موادع يعني
+
+289
+00:24:42,550 --> 00:24:48,050
+الميثل والكلور بيواجهوا على التلت مواقع طيب خلينا
+
+290
+00:24:48,050 --> 00:24:54,770
+نشوف إيش نتيجة التجربة نشوف إيش نتيجة التجربة
+
+291
+00:24:54,770 --> 00:25:04,290
+الموقع هذا إيجي عليه كلور واضح؟ شايفينه؟ والموقع
+
+292
+00:25:05,470 --> 00:25:13,650
+هذا إيجي عليه chlorine و الموقع هذا إيش مكتوب
+
+293
+00:25:13,650 --> 00:25:19,010
+عندكم ال product not observed مابينش عليه chlorine
+
+294
+00:25:19,010 --> 00:25:23,770
+رغم إنه نظريا هنا و هنا و هنا متوقع ييجي ال
+
+295
+00:25:23,770 --> 00:25:28,430
+chlorine بس عمليا إيجي هنا و إيجي هنا ماإيجيش هنا
+
+296
+00:25:28,430 --> 00:25:34,030
+الآن لو قلنا لواحدة منكم ليش طيب تتوقع هذا الكلام
+
+297
+00:25:34,030 --> 00:25:34,450
+يصير؟
+
+298
+00:25:38,680 --> 00:25:43,340
+بكون ازدحام ازدحام تنسوش ان كل الـ Geometry لما
+
+299
+00:25:43,340 --> 00:25:47,800
+درستوها في الكيميا كانت مرتبطة بأي موضوع بالازدحام
+
+300
+00:25:47,800 --> 00:25:51,460
+لما كان يكون عندكم تلت ذرات ليش كنتوا تعملوا الجزء
+
+301
+00:25:51,460 --> 00:25:57,860
+Linear؟ عشان تخلوا الزاوية 180 فالجزيات بتشرط من
+
+302
+00:25:57,860 --> 00:26:02,920
+الازدحام الآن المجموعة اللي بدأ تيجي هنا تتخيلوا
+
+303
+00:26:02,920 --> 00:26:10,440
+ان الكلور مخد حيزوالمثل C ومخدة H وH وH مخدة حيز
+
+304
+00:26:10,440 --> 00:26:14,720
+لحد هنا بناء على ذلك هل من السهل أن تدخل لو
+
+305
+00:26:14,720 --> 00:26:18,860
+تخيلتوا أن هذه إليها حيز إلكتروني مظبوط ولا لأ؟
+
+306
+00:26:18,860 --> 00:26:23,360
+وهذه إليها حيز إيه؟ هل من السهل إنها تيجي هنا؟ صعب
+
+307
+00:26:23,360 --> 00:26:27,740
+إذن هنا اتدخل عامل الاستحاب بس من ناحية نظرية
+
+308
+00:26:27,740 --> 00:26:30,100
+المفروض أنه ممكن تيجي هنا وممكن تيجي هنا وممكن
+
+309
+00:26:30,100 --> 00:26:33,400
+تيجي هنا لكن هذا الموقع product not observed
+
+310
+00:26:35,480 --> 00:26:40,840
+توهندرد يعني مزدحم كثيرا هذا الموقع مزدحم كثيرا
+
+311
+00:26:40,840 --> 00:26:50,200
+واضح؟ هذا الموقع مزدحم كثيرا الآن
+
+312
+00:26:50,200 --> 00:26:55,100
+هنا في عندنا مجموعة من الأمثلة المحلولة بس نتأكد
+
+313
+00:26:55,100 --> 00:26:58,400
+انه ابتدقنوا انتوا الحال تبعها
+
+314
+00:27:02,010 --> 00:27:06,710
+بتطلع عندنا بدكوا تبدأوا بطولين نعمله chlorination
+
+315
+00:27:06,710 --> 00:27:12,690
+وين هيجي ال chlorine؟ على ال ortho و ال bara هنا
+
+316
+00:27:12,690 --> 00:27:17,890
+كتب ال bara و كتب الكزايد ال ortho product يعني
+
+317
+00:27:17,890 --> 00:27:24,750
+بتطلع خليط من الناتجين عندكم sulfonic acidالسيلفون
+
+318
+00:27:24,750 --> 00:27:28,670
+اللي قلنا عنها الـ Deactivating و Meta Directing
+
+319
+00:27:28,670 --> 00:27:33,130
+Group لما بتعمل البروميناتش مع FEPR3 وين هتيجي
+
+320
+00:27:33,130 --> 00:27:36,970
+بالنسبة لها على الميتا يعني على موقع تلاتة هاي ال
+
+321
+00:27:36,970 --> 00:27:45,730
+S 123 إجت لبرومين على موقع ميتا واضح إجت لبرومين
+
+322
+00:27:45,730 --> 00:27:50,700
+على موقع ميتا بالنسبة لالمجموعة اللى موجودة أصلا
+
+323
+00:27:50,700 --> 00:27:55,460
+كل المجموعات اللى بتيجي بتيجي بالنسبة للمجموعة
+
+324
+00:27:55,460 --> 00:28:00,860
+اللى موجودة أصلا الان هنا عندكم نيترو بدنا نعمل
+
+325
+00:28:00,860 --> 00:28:06,080
+ايو دي نيشت بدت تيجي وين النيترو ميتا ميتا
+
+326
+00:28:06,080 --> 00:28:08,760
+directing group وين ال meeta تبعها واحد اتنين
+
+327
+00:28:08,760 --> 00:28:12,060
+تلاتة او واحد اتنين تلاتة لاحظوا هي اتجت واحد
+
+328
+00:28:12,060 --> 00:28:17,220
+اتنين تلاتة اتجت فعلا على موقع تلاتة اللى هو ال
+
+329
+00:28:17,220 --> 00:28:24,370
+meetaأجت على موقع تلاتة اللي هو الميتا position
+
+330
+00:28:24,370 --> 00:28:30,390
+نتطلع
+
+331
+00:28:30,390 --> 00:28:33,730
+كمان
+
+332
+00:28:33,730 --> 00:28:40,640
+على هذه الأمثلة عندكم ال chlorineالكلورين وين
+
+333
+00:28:40,640 --> 00:28:47,180
+بيوده؟ اورثو بارا لما تحط SO3 H2SO4 اللي هو سمناه
+
+334
+00:28:47,180 --> 00:28:52,200
+sulfonation اخدناه سمناه sulfonation بناء العدالة
+
+335
+00:28:52,200 --> 00:28:57,120
+كاي كتب لكوا بارا product زائد الارثو ايزو مارز
+
+336
+00:28:57,120 --> 00:29:02,300
+لان هدولة ايزو مارز نفس الصيغة الجزائية لكن
+
+337
+00:29:02,300 --> 00:29:06,280
+الاختلاف في مواقع الروابط او في الصيغة البنائية
+
+338
+00:29:06,510 --> 00:29:12,270
+الان لو كان عندكم طلوين و حطينا excess HNO3 و
+
+339
+00:29:12,270 --> 00:29:17,770
+H2SO4 يجب ان يأتي على البارا و بعدين زي ما قبل
+
+340
+00:29:17,770 --> 00:29:21,750
+شوية فارجيناكوا بالمثال على ال اورثو و على ال
+
+341
+00:29:21,750 --> 00:29:26,310
+اورثو تلت مجموعات نيترو لان الطلوين اكتفت و حطينا
+
+342
+00:29:26,310 --> 00:29:34,460
+excess فبصير عندى tri-nitro طلوينلو كان عندكم هذا
+
+343
+00:29:34,460 --> 00:29:38,780
+المُركّب اللي هو اسمه إيش؟ مين اتذكرناه؟ الـ
+
+344
+00:29:38,780 --> 00:29:43,520
+isopropyl ع البنزين الكيومين
+
+345
+00:29:43,520 --> 00:29:48,420
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+346
+00:29:48,420 --> 00:29:48,540
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+347
+00:29:48,540 --> 00:29:48,840
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+348
+00:29:48,840 --> 00:29:53,440
+الكيومين الكيومين الكيومين الكيومين الكيوم
+
+349
+00:29:54,730 --> 00:29:59,570
+Orthopara directing groups or activating بناء ع
+
+350
+00:29:59,570 --> 00:30:03,950
+ذلك لو بدأ تيجي هذا المركب اللي فيه C double bond
+
+351
+00:30:03,950 --> 00:30:07,150
+OCL مع aluminium chloride واضح ال aluminium
+
+352
+00:30:07,150 --> 00:30:10,450
+chloride بده ياخد منه ال chlorine بده يعمل
+
+353
+00:30:10,450 --> 00:30:14,630
+oscillation بده يحط C double bond O مع الحلقة
+
+354
+00:30:14,630 --> 00:30:19,750
+تماما هذا المثال زي لو كان عندكم CH3C double bond
+
+355
+00:30:19,750 --> 00:30:25,030
+OCL شو كنتوا تحط OCL؟ شو كنتوا تحطوه؟الان انا لغيت
+
+356
+00:30:25,030 --> 00:30:29,550
+من هنا CH3 و حطيت Cyclopentane في مشكلة المهم
+
+357
+00:30:29,550 --> 00:30:34,650
+تفاعل وين بده يتم على هذه الكربون هذه ال الكلجروب
+
+358
+00:30:34,650 --> 00:30:40,750
+وين بتوده اورثو و بارا عشان ايه كانت بيانت على
+
+359
+00:30:40,750 --> 00:30:46,430
+البارا لاحظوا هنا يمكن تلاحظوا شغلة ماكتبش زائد
+
+360
+00:30:46,430 --> 00:30:52,750
+اورثو ايزو ماربتقدروا تتخيلوا عاد ليش ما كتبش زي
+
+361
+00:30:52,750 --> 00:30:59,610
+ات ارثو اي زمر لأن هذه المجموعة لسه CH لما يطلع
+
+362
+00:30:59,610 --> 00:31:06,110
+منها كCHHHH و من هنا CHHHH و بده يجيب كل هذه هانا
+
+363
+00:31:06,110 --> 00:31:12,080
+جنبهابصير ازدحام اذا وين الاريح اليها تروح؟ ع
+
+364
+00:31:12,080 --> 00:31:15,760
+البارا عشان هيك كما .. يعني كما يبدو انه انا بس
+
+365
+00:31:15,760 --> 00:31:19,960
+بيطلع عندكم البارا product لإن هذي لما افصلها
+
+366
+00:31:19,960 --> 00:31:24,280
+المجموعة لفوق و لتحت و هذي في ال .. بالذات كمان ال
+
+367
+00:31:24,280 --> 00:31:29,800
+cyclopentane مجموعة كبيرة بتصير هذه المنطقة مزدحمة
+
+368
+00:31:29,800 --> 00:31:32,620
+too hindered for a reaction to occur
+
+369
+00:31:35,750 --> 00:31:40,430
+بقول إنه من ناحية نظرية متوقع التفاعل يتم هان أو
+
+370
+00:31:40,430 --> 00:31:46,690
+هان أو هان هذا
+
+371
+00:31:46,690 --> 00:31:53,070
+هاي ال CH3 أول مجموعة وين بتيجي نفترض على البارة
+
+372
+00:31:53,070 --> 00:31:56,810
+بعد ما إجت على البارة where بتصير تودي هذه
+
+373
+00:31:56,810 --> 00:32:01,630
+المجموعةالـ Nitro اللى جاءت هنا على الميتا
+
+374
+00:32:01,630 --> 00:32:04,030
+بالنسبالي لو هذى وين بتودى على الأورتو بالنسبالي
+
+375
+00:32:04,030 --> 00:32:06,810
+هذا المثال الحكيناه قبل شوية بس انت حضرتك مش من
+
+376
+00:32:06,810 --> 00:32:09,810
+تبه .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+377
+00:32:09,810 --> 00:32:11,570
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+378
+00:32:11,570 --> 00:32:12,330
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+379
+00:32:12,330 --> 00:32:15,070
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+380
+00:32:15,070 --> 00:32:16,670
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+381
+00:32:16,670 --> 00:32:26,710
+بهمش .. بهمش .. بهمش .. بهمش .. بهم
+
+382
+00:32:28,530 --> 00:32:31,910
+هو نفس المثال بس هنا مفصل اكثر
+
+383
+00:32:40,100 --> 00:32:44,440
+هنا بيجينا بعض الأمثلة .. هنا بيجينا بعض الأمثلة
+
+384
+00:32:44,440 --> 00:32:49,580
+كيف ممكن اتحضروا و هذا دائما و أبدا في الامتحان
+
+385
+00:32:49,580 --> 00:32:53,660
+احنا إلا نسألكوا أسئلة زي هيك نجيبلكوا مركب ب two
+
+386
+00:32:53,660 --> 00:32:58,280
+substituents و نقولكم كيف ممكن تحضروا هذا المركب
+
+387
+00:32:58,280 --> 00:33:05,660
+الآن هنا بدكم تاخدوا بالكم من إيش؟ من عاملين عامل
+
+388
+00:33:05,660 --> 00:33:11,700
+ال orientationو عامل ال reactivity السؤال تركزه
+
+389
+00:33:11,700 --> 00:33:17,480
+أنه أي مجموعة أحط في الأول و أي مجموعة أحط في
+
+390
+00:33:17,480 --> 00:33:21,540
+التاني يعني أنا بدي أبدأ من البنزين لما بدي أبدأ
+
+391
+00:33:21,540 --> 00:33:26,100
+من البنزين مثلا في هذا المركب بدي أحط مجموعة ال
+
+392
+00:33:26,100 --> 00:33:29,260
+CH3 معروف بحطها من ال methyl chloride مع aluminium
+
+393
+00:33:29,260 --> 00:33:33,800
+chloride و بدي أحط مجموعة ال acetyl بحطها من ال
+
+394
+00:33:33,800 --> 00:33:37,780
+acetyl chloride مع aluminium chlorideلكن هدولة
+
+395
+00:33:37,780 --> 00:33:42,540
+خطوتين أنيا بدأ أعملها في الأول و أي واحدة بدأ
+
+396
+00:33:42,540 --> 00:33:46,640
+أعملها في التاني هذا هو السؤال واضح دائما لما
+
+397
+00:33:46,640 --> 00:33:52,320
+نجيبلكم سؤال بنزين عليه مجموعتين كأنا بقولكم أي
+
+398
+00:33:52,320 --> 00:33:56,020
+واحدة في الأول أي واحدة في التاني الآن بإمكانكوا
+
+399
+00:33:56,020 --> 00:34:01,680
+أنتوا تكتبوا البنزين وتعملوا الاحتمالينتقولوا
+
+400
+00:34:01,680 --> 00:34:05,400
+خلّينا في الأول نعمل ال methylation أو نعمل ال
+
+401
+00:34:05,400 --> 00:34:08,320
+acetylation و بعدين in turn نعمل الخطوة التانية
+
+402
+00:34:08,320 --> 00:34:11,700
+هان و الخطوة التانية هان على طول هتكتشفوا أن أحد
+
+403
+00:34:11,700 --> 00:34:18,420
+المسارين جيد و المسار الآخر غير جيد يعني لو مثلا
+
+404
+00:34:18,420 --> 00:34:24,730
+أنا بدأت بالبنزين اعملت الطلوينإذا الخطوة الأولى
+
+405
+00:34:24,730 --> 00:34:30,430
+بنزين عملت بعدها إيش؟ طلوين ممكن نعملها على هذه
+
+406
+00:34:30,430 --> 00:34:41,290
+السطورة هذه بنزين حطيت CH3Cl ألمنيوميكلورايد صار
+
+407
+00:34:41,290 --> 00:34:46,790
+عنده طلوين okay الآن في الخطوة التانية شو هأعمل؟
+
+408
+00:34:49,090 --> 00:34:55,190
+بدي أضيف الـ acetyl اللي هي CH3C double bond OCl
+
+409
+00:34:55,190 --> 00:35:01,630
+في وجود aluminium chloride مظبوط ولا لا؟ طيب لما
+
+410
+00:35:01,630 --> 00:35:05,770
+بعمل مين اللي بتحكم في نتيجة التفاعل؟ المجموعة
+
+411
+00:35:05,770 --> 00:35:09,290
+اللي already موجودة CH3 وين بتودي ال CH3؟ على ال
+
+412
+00:35:09,290 --> 00:35:14,270
+ortho و على ال para إذا في النهاية بتطلعلي المركب
+
+413
+00:35:14,270 --> 00:35:20,560
+اللي أنا بدياه ولا لأ؟بتطلعوا هاي CH3 بتطلع للبارة
+
+414
+00:35:20,560 --> 00:35:27,140
+اللي أنا عاوزه زاد ال ortho زاد ال ortho product
+
+415
+00:35:27,140 --> 00:35:32,540
+إذا هذا المسار بتطلع للناتج واضح؟ هذا المسار بتطلع
+
+416
+00:35:32,540 --> 00:35:38,220
+للناتج الآن اتخيلوا لو بدأت بالمسار التالي حطيت في
+
+417
+00:35:38,220 --> 00:35:44,560
+الأول ال CW bond OCH3 ال CW bond OCH3 لوين بتوده؟
+
+418
+00:35:44,560 --> 00:35:52,850
+للميجايعني لو حطيت هنا بنزين و قولت بتحط CW.O CH3
+
+419
+00:35:52,850 --> 00:36:00,990
+ممكن نعملها هنا CH3 CW.O Cl Aluminium Chloride و
+
+420
+00:36:00,990 --> 00:36:05,310
+خلّيني أحطها على نفس الموقع اللي مبين عليه مش
+
+421
+00:36:05,310 --> 00:36:16,190
+مشكلة حطت هنا CW.O CH3 الآن اعملولي ال second step
+
+422
+00:36:17,550 --> 00:36:22,930
+اللي هي CH3Cl زي الألومنيوم الكلوري وين هييجي
+
+423
+00:36:22,930 --> 00:36:30,810
+بالنسبة لهذه المجموعة؟ هل يعطي ناتج؟ لأ لأ واضح؟
+
+424
+00:36:30,810 --> 00:36:40,410
+إذا هذه الـC double bond O CH3 وهنا هل هذا قدّالي
+
+425
+00:36:40,410 --> 00:36:45,470
+لنفس الناتج؟ لكن يقصد بيعطي نفس الناتج لو CH3 وجهت
+
+426
+00:36:45,470 --> 00:36:50,710
+على الـRكيف؟ لأ طبعا ال ortho مش هو نفس النتيجة ده
+
+427
+00:36:50,710 --> 00:36:57,610
+ميتا لو بدأنا بال CH3 هاي بدأت بنزين CH3 بيعطينا
+
+428
+00:36:57,610 --> 00:37:01,270
+البارا زاد ال ortho انا باهتم بالبارا ال ortho
+
+429
+00:37:01,270 --> 00:37:05,450
+عليا و الرأس طالع عندي بس انا اللي بدياهالبارا
+
+430
+00:37:05,450 --> 00:37:08,770
+product انا اللي بدي اياه البارا product الان
+
+431
+00:37:08,770 --> 00:37:12,810
+بإمكانكوا كل مرة تحللوه زي هيك بس بإمكانكوا صدقوني
+
+432
+00:37:12,810 --> 00:37:16,730
+بنظرة سريعة جدا تنتبهوا انكوا متيجوا تقولوا المثل
+
+433
+00:37:16,730 --> 00:37:23,250
+لوين بتودي اورتو بارا اذا بتطلعلي هذا بتودي بارا
+
+434
+00:37:23,250 --> 00:37:28,050
+اذا ببدأ بالمثل و بثني بهذه المجموعة لو بدأت بهذه
+
+435
+00:37:28,050 --> 00:37:32,850
+لوين بتودي مثل بتطلع الناتج لأ اذا ايش اول خطوة في
+
+436
+00:37:32,850 --> 00:37:41,060
+هذا المثلالمثل بعدين الاسيتل لزميك الترتيب هذا
+
+437
+00:37:41,060 --> 00:37:47,040
+المصاد بمشيش عندك مثلاشن ثم اسيتلاشن الان واحدة
+
+438
+00:37:47,040 --> 00:37:52,540
+منكم منتبهة تيجي تطلعلي على هذا المثل تقولي إيش
+
+439
+00:37:52,540 --> 00:37:59,770
+اللي بدي أبدأ فيه إذا بدأتي ب CH3 وين بتودي؟أورتو
+
+440
+00:37:59,770 --> 00:38:07,050
+أورتو بارا هتظبط معاه؟ لأ طب إذا بدأت بنيترو كان
+
+441
+00:38:07,050 --> 00:38:11,230
+بدأت بنيترو بتحط للميثل ع الميتر إذا هذا المركب
+
+442
+00:38:11,230 --> 00:38:18,810
+كيف لازم أبدأ فيه؟ أول إشي نيتريشن ثم مثليشن لو
+
+443
+00:38:18,810 --> 00:38:21,410
+عملت مثليشن ثم نيتريشن مابظبطش
+
+444
+00:38:24,620 --> 00:38:29,120
+لأنه لو حطيت الميثل وين هيود النيترو؟ هان أو هان
+
+445
+00:38:29,120 --> 00:38:32,060
+أو هان، مش هيجيبها هان لو حطيت النيترو وين هتحط
+
+446
+00:38:32,060 --> 00:38:37,700
+الميثل؟ على الميتا بالنسبة لها الآن
+
+447
+00:38:37,700 --> 00:38:42,840
+هذا المُركّب، اتطلع عليه، عليه مجموعتين، هذه
+
+448
+00:38:42,840 --> 00:38:50,320
+الـCOCH3 إلى وين بتوده؟ لأ، دي activating
+
+449
+00:38:50,320 --> 00:38:56,920
+metadirecting group، تذكروهاالـ COCH3 Deactivating
+
+450
+00:38:56,920 --> 00:39:03,100
+Ometa Directing Group بتودي على الميتا ال PR
+
+451
+00:39:03,100 --> 00:39:07,700
+Orthopara إذا لو كنت أنا هذه موجودة عندى حطيتها في
+
+452
+00:39:07,700 --> 00:39:11,460
+الخطوة الأولى بتجيب للبرومين في الخطوة الثانية على
+
+453
+00:39:11,460 --> 00:39:17,440
+الميتا إذا في الأول ال first stepأضيف هذه وبعدها
+
+454
+00:39:17,440 --> 00:39:21,340
+برومينيشن لو عملت العكس وضعت البروم البرومين بتودي
+
+455
+00:39:21,340 --> 00:39:25,540
+اورثو اورثو بارا مش حتى عطيني الناتجة اذا هذا
+
+456
+00:39:25,540 --> 00:39:33,160
+المثال اسيلاشن او اسيتليشن ثم برومينيشن واضح؟ اخر
+
+457
+00:39:33,160 --> 00:39:40,440
+مثال لو بدأت ب PR و اين بتودي ال PR اورثو بارا
+
+458
+00:39:40,440 --> 00:39:43,140
+طلعت المركبة لو بدأت ب نيترو
+
+459
+00:39:47,510 --> 00:39:53,650
+promination then nitration
+
+460
+00:39:53,650 --> 00:40:01,070
+واضح كيف بصير التفكير بهذه المسائل؟أخر .. أخر جزء
+
+461
+00:40:01,070 --> 00:40:05,650
+اللي بدنا نحكيه اليوم على بعض المركبات .. على بعض
+
+462
+00:40:05,650 --> 00:40:09,810
+المركبات اللي هم عبارة عن أكثر من حلقة بنزين مش
+
+463
+00:40:09,810 --> 00:40:13,870
+هنتعمق بس بنقولكوا لما بيكون في عندى أكثر من حلقة
+
+464
+00:40:13,870 --> 00:40:18,530
+بنزين بنسمي المركبات polycyclic aromatic compounds
+
+465
+00:40:18,530 --> 00:40:23,810
+منهالو كانوا two benzene rings بصير المراكب اسمه
+
+466
+00:40:23,810 --> 00:40:28,050
+نفثالين، لو كانوا تلاتة benzene rings بهذا الشكل
+
+467
+00:40:28,050 --> 00:40:35,070
+أنثراسين، لو كانوا تلاتة مش بخط مستقيمفنانثرين لو
+
+468
+00:40:35,070 --> 00:40:39,690
+كانوا أربعة بهذا الشكل اللي موجود عندك بيكونوا
+
+469
+00:40:39,690 --> 00:40:45,310
+بايرين و لو كانوا خمسة بهذا الشكل اللي موجود هنا
+
+470
+00:40:45,310 --> 00:40:54,210
+بيكونوا بنزو ا بايرين هذا ال بنزو ا بايرين من
+
+471
+00:40:54,210 --> 00:41:00,960
+المركبات الخطيرةمن المراكبات الخطيرة جدا لما الناس
+
+472
+00:41:00,960 --> 00:41:05,260
+بدخن السجائر نتيجة الحرق بتتكون aromatic compounds
+
+473
+00:41:05,260 --> 00:41:11,200
+polycyclic هذا من المراكبات اللي بتتكون من السجائر
+
+474
+00:41:11,200 --> 00:41:15,590
+من حرق السجائروهذا المركب بنقول عنه carcinogenic
+
+475
+00:41:15,590 --> 00:41:19,830
+معنى carcinogenic مسبب للسرطان بس بدكوا تنتبهوا
+
+476
+00:41:19,830 --> 00:41:23,950
+لشغلة .. بدكوا تنتبهوا لشغلة أنه في مركبات بنقول
+
+477
+00:41:23,950 --> 00:41:29,570
+ممكن تسبب سرطان وفي مركبات بنقول أسبوعين و التالت
+
+478
+00:41:29,570 --> 00:41:34,510
+بتعمل سرطان هذا مش من المركبات المزح مش من اللي
+
+479
+00:41:34,510 --> 00:41:40,030
+ممكن يسبب سرطان هذا من اللي أكيد بيعمل سرطانبس
+
+480
+00:41:40,030 --> 00:41:44,970
+طبعا، ليش بتأخر السرطان أحيانا عند المدخنين؟ لأنه
+
+481
+00:41:44,970 --> 00:41:49,070
+بتكون الكميات قليلة، بس هذا لو أخدوه بتركيز كبير،
+
+482
+00:41:49,070 --> 00:41:52,810
+أعطوه لأي بني آدم، بعد أسبوعين عنده سرطان، مافيش
+
+483
+00:41:52,810 --> 00:41:56,910
+إمكانية، بتأخر عند المدخنين لأنه في نائب بيطلعي
+
+484
+00:41:56,910 --> 00:42:01,610
+بتركيز قليل، cumulative، ماصيروا يصلوا، يعني ال
+
+485
+00:42:01,610 --> 00:42:09,670
+80، 90% بيعود يصلوا، واضح؟ لكنلو أخذ بتركيز كبير
+
+486
+00:42:09,670 --> 00:42:13,650
+كتجربة يعني عندنا فار بدنا نعمل عليه تجربة نخليه
+
+487
+00:42:13,650 --> 00:42:18,550
+يصير عنده سرطان لو أعطينا نيتروزو كمباونز أو بنزو
+
+488
+00:42:18,550 --> 00:42:22,530
+إيه بايرين و أنتم غامضين استنوا عليه أسبوعين و
+
+489
+00:42:22,530 --> 00:42:26,910
+بتشوفوا صار عنده إيش صار عنده سرطان هذا المركب
+
+490
+00:42:26,910 --> 00:42:33,470
+بالمناسبة عشان تنتبهوا بينتج كمان بشكل تحديد من
+
+491
+00:42:33,470 --> 00:42:39,260
+عملية حرق الكاكاوةالكاكاو إذا انحرج مش إذا داب
+
+492
+00:42:39,260 --> 00:42:44,120
+وعملناه مشروب إذا انحرج يعني لو بتعمله كيك أو ما
+
+493
+00:42:44,120 --> 00:42:48,120
+إلى ذلك بكاكاو و الكاكاو بنحرج بيطلع البنزو إيه
+
+494
+00:42:48,120 --> 00:42:53,600
+بايرين و هذا حقيقة هو اللي موجود .. انتبهوا معاه
+
+495
+00:42:53,600 --> 00:42:57,760
+هو اللي موجود في السجائر لما بيقولولكوا نكهة كذا و
+
+496
+00:42:57,760 --> 00:43:03,560
+نكهة كذا و حقيقة بيضيفوا على التبغ كاكاووحرق
+
+497
+00:43:03,560 --> 00:43:07,500
+الكاكاو عشان يطلع ريحة و الناس ينبسط و بتعرف هذه
+
+498
+00:43:07,500 --> 00:43:10,140
+الأشياء اللي بيظلوا ميضيفوها و الناس اللي بياخدوا
+
+499
+00:43:10,140 --> 00:43:13,980
+الشيشة المصايب هذه و بيسموهم عسلو أشياء حلوة كلها
+
+500
+00:43:13,980 --> 00:43:19,420
+بتطلع روائح هذا الكاكاو هو اللي بيطلع لنا إيش؟ الـ
+
+501
+00:43:19,420 --> 00:43:23,380
+Benzo-A-Pyrene هذا الكاكاو اللي بيطلع الـ Benzo-A
+
+502
+00:43:23,380 --> 00:43:28,040
+-Pyrene اللي هو بيسموه نكهة كذا و بيجي في الدعاية
+
+503
+00:43:28,040 --> 00:43:36,980
+الانتخابية معتز بهذا الكلامأخر شغلة بنحكيهااللي هي
+
+504
+00:43:36,980 --> 00:43:41,640
+الفوليرين يمكن مرة حكينالكوا عنه انه غير الـ
+
+505
+00:43:41,640 --> 00:43:45,260
+diamond وغير ال graphite من الالوتروبز تبعون
+
+506
+00:43:45,260 --> 00:43:50,040
+الكربون لقوا الالوتروبز عبارة عن ستين ذرة كربون
+
+507
+00:43:50,040 --> 00:43:55,280
+لما عملوا ال structure تبعهم لقوا عبارة عن
+
+508
+00:43:55,280 --> 00:44:01,500
+aromatic structure تقريبا عبارة عن كرة هذه الكرة
+
+509
+00:44:01,500 --> 00:44:08,390
+موجود فيها طبعاحلقات سداسية و حلقات خمسية و double
+
+510
+00:44:08,390 --> 00:44:14,870
+bonds فكأنها تعتبر polycyclic aromatic ring هى أحد
+
+511
+00:44:14,870 --> 00:44:18,950
+الصور اللى ممكن تكون موجودة للكربون غير ال mass
+
+512
+00:44:18,950 --> 00:44:24,130
+غير ال graphite بيحكوا عن ال C60 كرة الكربون ستين
+
+513
+00:44:24,130 --> 00:44:27,550
+هذه الكرة لو بتعدوا الطوبة بالزرقة اللى فيها ستين
+
+514
+00:44:27,550 --> 00:44:36,230
+واحدة واضح ستين طوبة زرقة موجود فيهابسموها
+
+515
+00:44:36,230 --> 00:44:40,570
+الفوليري النسبة الى الشخص اللى اكتشفها لاسمه Book
+
+516
+00:44:40,570 --> 00:44:44,810
+Monster Fowler Book Monster Fowler
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1804e40a772e7537fe1c7ea179ecda31054f7b2b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/4gQi5v51wW0_raw.srt
@@ -0,0 +1,2088 @@
+1
+00:00:06,190 --> 00:00:09,570
+بسم الله الرحمن الرحيم، اليوم إن شاء الله بدنا
+
+2
+00:00:09,570 --> 00:00:17,870
+نكمل في موضوع تفاعلات البنزين، المرة الماضية كل
+
+3
+00:00:17,870 --> 00:00:23,830
+كلامنا كان عن حلقة بنزين غير مبدلة، unsubstituted،
+
+4
+00:00:23,830 --> 00:00:27,680
+يعني مافيش عليهامافيش عليها ولا إشي وبنحط
+
+5
+00:00:27,680 --> 00:00:32,560
+Substituent واحدة طبعاً في هذه الحالة اللي بتطلع
+
+6
+00:00:32,560 --> 00:00:36,920
+على شكل حلقة البنزين المتماثل هيلاحظ أنه على أي
+
+7
+00:00:36,920 --> 00:00:41,140
+موقع من المواقع الستة بنقدر نحط ال Substituent
+
+8
+00:00:41,140 --> 00:00:46,020
+وبيطلع عندنا نفس الناتج طبعاً أخدنا طرق كتيرة
+
+9
+00:00:46,020 --> 00:00:49,860
+لإضافة Substituents أخدنا Alkylation, Acylation,
+
+10
+00:00:50,000 --> 00:00:55,720
+Halogenation, Nitration, Sulfonation وكل طريقةفي
+
+11
+00:00:55,720 --> 00:00:59,920
+إلها reagents معينة، خلاصة الموضوع إن ال reagents
+
+12
+00:00:59,920 --> 00:01:06,300
+لازم في النهاية يتوفر إلي electrophile لازم يتوفر
+
+13
+00:01:06,300 --> 00:01:12,100
+إلي إشي موجب عشان هذا الموجب يهاجم على حلقة
+
+14
+00:01:12,100 --> 00:01:15,280
+البنزين هذا الموضوع مافيش فيه خلاف، الآن إيش
+
+15
+00:01:15,280 --> 00:01:20,700
+الجديد اليوم في الموضوع تبعنا؟الجديد كالقاتل أنه
+
+16
+00:01:20,700 --> 00:01:27,000
+لو أنا كنت حاطط على ذرة البنزين مجموعة وبدأ أحط
+
+17
+00:01:27,000 --> 00:01:32,520
+المجموعة التانية بيصير عندي شغلتين بيصير عندي
+
+18
+00:01:32,520 --> 00:01:36,460
+شغلتين الآن
+
+19
+00:01:36,460 --> 00:01:41,420
+لما بدنا نعمل إضافة على حلقة بنزين في بالأساس
+
+20
+00:01:41,420 --> 00:01:47,670
+عليها مجموعة وبدنا نضيف المجموعة التانيةسنلاحظ
+
+21
+00:01:47,670 --> 00:01:53,150
+القادة أن المجموعة الأولى تتدخل في سرعة التفاعل
+
+22
+00:01:53,150 --> 00:01:57,210
+بمعنى يمكن بسبب وجود المجموعة الأولى أن حلقة
+
+23
+00:01:57,210 --> 00:02:04,430
+البنزين تتفاعل بسرعة تتفاعل بسرعةأبطأ في التفاعل
+
+24
+00:02:04,430 --> 00:02:09,130
+إذا إليها تأثير متعلق بشيء بنسميه ال reactivity أو
+
+25
+00:02:09,130 --> 00:02:14,790
+النشاط إذا هذه ال substituent الأولى في إليها إيش
+
+26
+00:02:14,790 --> 00:02:20,650
+reactivity effect يعني يا بتزيد السرعة لإبدال
+
+27
+00:02:20,650 --> 00:02:25,830
+المجموعة الثانية يا بتقلل السرعة واضح الشغل التاني
+
+28
+00:02:25,830 --> 00:02:31,800
+أن المجموعة الأولى بتكون أخدت موقعفاللي دائما
+
+29
+00:02:31,800 --> 00:02:34,960
+موجود في الأول بيصير يتحكم في اللي بيجي بعد هيك
+
+30
+00:02:34,960 --> 00:02:38,840
+اليوم .. يوم ما بده تيجي المجموعة التانية هل هتيجي
+
+31
+00:02:38,840 --> 00:02:41,780
+على الموقع المجاور إلها اللي هو بيكون بالنسبة إلها
+
+32
+00:02:41,780 --> 00:02:45,780
+ortho ولا هتيجي على بعض موقع meta ولا هتيجي على
+
+33
+00:02:45,780 --> 00:02:49,480
+الموقع اللي بعده bara برضه المجموعة اللي موجودة
+
+34
+00:02:49,480 --> 00:02:54,730
+بتتحكم إذا ..هنا صار عندى اشي جديد انا مهتم فيه
+
+35
+00:02:54,730 --> 00:02:59,570
+انه وجود مجموعة اثر على شغلتين اثر على ال
+
+36
+00:02:59,570 --> 00:03:04,090
+reactivity سرعة التفاعل و ال orientation ال
+
+37
+00:03:04,090 --> 00:03:08,570
+orientation يعني وين يروح او وين تروح المجموعة
+
+38
+00:03:08,570 --> 00:03:12,890
+التانية بالنسبة للمجموعة الاولى وهذا الكلام اللى
+
+39
+00:03:12,890 --> 00:03:17,970
+احنا بدنا ندرسه في التفصيل في محاضرة اليومإيش
+
+40
+00:03:17,970 --> 00:03:21,370
+التأثير بتاع المجموعة الأولى من ناحية reactivity
+
+41
+00:03:21,370 --> 00:03:26,850
+ومن ناحية orientation إذا لو بدنا نسألكوا المجموعة
+
+42
+00:03:26,850 --> 00:03:31,450
+أكم effect إلها ال reactivity تسريع أو تبطيق
+
+43
+00:03:31,450 --> 00:03:37,790
+orientation توجيه وين تروح المجموعة لجديدة الآن
+
+44
+00:03:37,790 --> 00:03:45,050
+بالنسبة لل band الأول المجموعات حقيقة تتراوح ما
+
+45
+00:03:45,050 --> 00:03:50,950
+بين مجموعاتبتزيد سرعة التفاعل بتزيد ال reactivity
+
+46
+00:03:50,950 --> 00:03:56,830
+بشكل كبير وبين مجموعات بتثبت سرعة التفاعل بشكل
+
+47
+00:03:56,830 --> 00:04:02,890
+كبير وفي عندنا هنا زي ما بتلاحظوا scheme واضح
+
+48
+00:04:02,890 --> 00:04:08,010
+بيوضح هذا الكلاميعني لو اتطلعتوا على افضل
+
+49
+00:04:08,010 --> 00:04:11,430
+المجموعات اللي بنزيد السرعه على التفاعل هتلاحظوا
+
+50
+00:04:11,430 --> 00:04:15,910
+مجموعة الـ NH2 يعني لو كان عندكم أنيلين و بدنا
+
+51
+00:04:15,910 --> 00:04:21,530
+نعمل عليه تفاعل تاني التفاعل سريع جدا مجموعة الـ
+
+52
+00:04:21,530 --> 00:04:28,760
+OHاللي هو لو كان عندكم Phenol البنزين .. الـ
+
+53
+00:04:28,760 --> 00:04:33,220
+Phenol نشير جداً في التفاعل لو كان عندكم مجموعة
+
+54
+00:04:33,220 --> 00:04:38,040
+الـ OCH3 البنزين اللي عليه OCH3 اسمه أنيزول
+
+55
+00:04:38,040 --> 00:04:43,700
+الانيزول سريع جداً في التفاعل لو كان في عندكم
+
+56
+00:04:43,700 --> 00:04:50,040
+مجموعة الميثل CH3 الطلوينسريع جدا في التفاعل لو
+
+57
+00:04:50,040 --> 00:04:57,260
+كان عندكم N H عليها OCH3 برضه تعتبر السريعة و
+
+58
+00:04:57,260 --> 00:05:00,200
+بالمناسبة الترتيب اللي موجود هنا برضه بيعني ان
+
+59
+00:05:00,200 --> 00:05:03,520
+واحدة أسرع من التانية يعني إذا بتلاحظوا ال O H
+
+60
+00:05:04,410 --> 00:05:10,210
+بتسرع أكتر من الميثل مثلا واضح أو ال N H2 أكتر من
+
+61
+00:05:10,210 --> 00:05:16,930
+ال OCH3 ال H اللي هو البنزين العادى تعتبر حالة وسط
+
+62
+00:05:16,930 --> 00:05:21,550
+في السرعة الأن من أبطأ الشغلات اللي بتوجهنا ال
+
+63
+00:05:21,550 --> 00:05:27,170
+Nitroالنيترو بنزين بيكون يعني generally
+
+64
+00:05:27,170 --> 00:05:33,150
+unreactive، التفاعل إيش ماله؟ بطيء كتير طبعا زيه
+
+65
+00:05:33,150 --> 00:05:37,730
+ال sulpholic acid و زيه ال COOH و ال CWBOR و ال
+
+66
+00:05:37,730 --> 00:05:41,770
+cyano و ال CHO اللي هي CWBOH ال aldehyde و ال
+
+67
+00:05:41,770 --> 00:05:46,210
+halogensكل هدولة من ناحية المبدأ في ال reactivity
+
+68
+00:05:46,210 --> 00:05:51,390
+أقل من إيش؟ أقل من البنزين، إذا أنا حد المقارنة
+
+69
+00:05:51,390 --> 00:05:54,710
+اللي عندي هو إيش؟ البنزين ال substitute اللي
+
+70
+00:05:54,710 --> 00:06:00,250
+موجودة فيه هي ال H، في أشياء أسرع من البنزينفي
+
+71
+00:06:00,250 --> 00:06:03,810
+أشياء أبطأ من البنزين، اللي مشهور في الأسرع من
+
+72
+00:06:03,810 --> 00:06:09,730
+البنزين الانيلين، الفينول، الطولوين، الاليزول،
+
+73
+00:06:09,730 --> 00:06:14,110
+اللي أبطأ من البنزين بشوية صغيرة الهالوجينز، فلورو
+
+74
+00:06:14,110 --> 00:06:18,870
+كلوري بروم، اللي أبطأ من البنزين كتير كتيرالـ
+
+75
+00:06:18,870 --> 00:06:23,250
+Nitro والـ Cyano يعني كأنه من أبطأ الأشياء في
+
+76
+00:06:23,250 --> 00:06:29,230
+التفاعلات الـ Nitro والـ Cyano واضح؟ هذا بالنسبة
+
+77
+00:06:29,230 --> 00:06:33,470
+للمجموعات إذا كأننا قسمنا المجموعات إلى strongly
+
+78
+00:06:33,470 --> 00:06:38,550
+activating groups يعني منشطة بشكل كبير و strongly
+
+79
+00:06:38,550 --> 00:06:46,130
+deactivating group مثبتة لسرعة التفاعل بشكل كبير
+
+80
+00:06:49,150 --> 00:06:55,330
+الآن بنجي لعامل التاني اللي حكينا عنه اللي هو الـ
+
+81
+00:06:55,330 --> 00:07:00,890
+Orientation، واضح؟ إذا بنطلع على نفس المجموعات،
+
+82
+00:07:00,890 --> 00:07:06,170
+لاحظوا القاتل، إنه بشكل عامالمجموعات اللي بتكون
+
+83
+00:07:06,170 --> 00:07:09,490
+activating .. المجموعات اللي بتكون activating
+
+84
+00:07:09,490 --> 00:07:14,270
+بتوجه المجموعات القادمة على موقع Orthopara
+
+85
+00:07:14,270 --> 00:07:21,050
+فبنسميها Orthopara Directing Groupsيعني مجموعات
+
+86
+00:07:21,050 --> 00:07:25,050
+لما تيجي مجموعة جديدة بتخليها وين تروح على موقع
+
+87
+00:07:25,050 --> 00:07:29,430
+Ortho وموقع Vara بيصير خليط عندى يعني لو افترضت
+
+88
+00:07:29,430 --> 00:07:34,650
+مثلا عندى 100 جزء بتفاعلوا ممكن 60 منهم 100 جزء
+
+89
+00:07:34,650 --> 00:07:39,230
+Phenol وقاعد بعمل عليهم مثلا Nitrogen ممكن 60 جزء
+
+90
+00:07:39,230 --> 00:07:43,110
+ييجي ال Nitro فيهم على موقع Ortho ممكن 40 جزء ييجي
+
+91
+00:07:43,110 --> 00:07:47,710
+ال Nitro فيهم على موقع Vara يعني بيطلع عنده خليط
+
+92
+00:07:47,710 --> 00:07:51,810
+من النواتج مش علىمش على نفس الجزء بيجي على
+
+93
+00:07:51,810 --> 00:07:55,410
+orthopara لأ ما انا مش جزء واحد اللي بفعله انا
+
+94
+00:07:55,410 --> 00:07:59,770
+بفعل ملايين الجزيات يعني لو كنت بفعل one mole مثلا
+
+95
+00:07:59,770 --> 00:08:03,170
+بكون بفعل six point oh two two في عشر أوس تلاتة
+
+96
+00:08:03,170 --> 00:08:09,990
+وعشرين عدد avocado فجزء منهم بيتفعل على ال orthoو
+
+97
+00:08:09,990 --> 00:08:16,130
+جزء منهم بتفعل وين؟ على ال para position فالقاعدة
+
+98
+00:08:16,130 --> 00:08:20,330
+بشكلها العام انه ال activating groups they are
+
+99
+00:08:20,330 --> 00:08:25,410
+generally ortho and para directing groups الآن ال
+
+100
+00:08:25,410 --> 00:08:28,770
+deactivating groups they are generally meta
+
+101
+00:08:28,770 --> 00:08:32,070
+directing groups يعني بيخلوا المجموعة الجديدة وين
+
+102
+00:08:32,070 --> 00:08:38,350
+تروح؟ على موقع meta بيجينا شغلة انه في النص
+
+103
+00:08:42,090 --> 00:08:45,250
+الهالوجينز الهالوجينز قبل شوية ايش قلنا عنهم احنا
+
+104
+00:08:45,250 --> 00:08:48,650
+طالما انهم اقل من الهيدروجيل activating ولا
+
+105
+00:08:48,650 --> 00:08:52,450
+deactivating؟ deactivating لكن بيكونوا
+
+106
+00:08:52,450 --> 00:08:58,110
+orthoparadirectic groupsواضح؟ إذا بشكل عام ال
+
+107
+00:08:58,110 --> 00:09:03,410
+activating groups أورثو بارا ال deactivating ميتا
+
+108
+00:09:03,410 --> 00:09:08,390
+ما عدا ال halogens they are deactivating groups
+
+109
+00:09:08,390 --> 00:09:13,390
+however أورثو بارا directing groups واضح؟ هذه
+
+110
+00:09:13,390 --> 00:09:18,130
+أشياء طبعا بنحصل عليها وعرفوها بالتجربة بعدين
+
+111
+00:09:18,130 --> 00:09:21,310
+بيحاولوا يعملوا تفسير على ان و الرأس لكن الأساس
+
+112
+00:09:21,310 --> 00:09:28,650
+فيها التجربةالأساس فيها التجربة، واضح؟ هذا اللي هو
+
+113
+00:09:28,650 --> 00:09:34,050
+تأثير الـ Substituent من ناحية الـ activity و من
+
+114
+00:09:34,050 --> 00:09:39,250
+ناحية الـ orientation من ناحية الـ activity و من
+
+115
+00:09:39,250 --> 00:09:44,850
+ناحية الـ orientation الآن ممكن نحاول نعطي تفسيرات
+
+116
+00:09:44,850 --> 00:09:51,460
+في الأساس احنا قلنا الـ activity من وين عرفناهامن
+
+117
+00:09:51,460 --> 00:09:56,980
+التجربة لكن بعد هيك بنقدر نحاول نعمل تفسير يعني
+
+118
+00:09:56,980 --> 00:10:03,340
+مثلا الميثيلي جروب او activating ليش يا ترى
+
+119
+00:10:03,340 --> 00:10:10,880
+الميثيلي جروب بيوده على موقعأورثو بارا مش على موقع
+
+120
+00:10:10,880 --> 00:10:16,260
+ميتا لما بدنا نيجي نعمل هذا الكلام بنيجي بنتخيل
+
+121
+00:10:16,260 --> 00:10:21,140
+مثلا بنقول خلينا ندرس الموقع بارا بنيجي بنحط
+
+122
+00:10:21,140 --> 00:10:24,900
+الكتروفايل على الموقع بارا هاي المثل واحد اتنين
+
+123
+00:10:24,900 --> 00:10:28,960
+تلاتةواحد اتنين تلاتة اربعة له موقع اربعة بالنسبة
+
+124
+00:10:28,960 --> 00:10:34,240
+للمثل او هاي ال ortho ميتا هاي ال para بالنسبة له
+
+125
+00:10:34,240 --> 00:10:39,400
+بنحط ال electro file هنا و بنشوف ايش اللي بينشق
+
+126
+00:10:39,400 --> 00:10:43,080
+عندنا بنحط ال electro file مجرد ما حطينا ال
+
+127
+00:10:43,080 --> 00:10:49,420
+electro file هنا حيصير في عندنا positiveعلى هذا
+
+128
+00:10:49,420 --> 00:10:54,760
+الموقع الان هذا ال positive بيعمل resonance ولا لأ
+
+129
+00:10:54,760 --> 00:10:58,220
+بيعمل resonance بمعنى ان هذه ممكن تتحرك تصير ال
+
+130
+00:10:58,220 --> 00:11:03,620
+positive على هذا الموقع وهذا كمان بيعمل resonance
+
+131
+00:11:03,620 --> 00:11:07,500
+ممكن تصير هنا اذا زي ما بتلاحظوا ان ال positive
+
+132
+00:11:07,500 --> 00:11:16,380
+بيكون بينقل واضح delocalized يعني مش مثبتمش متمركز
+
+133
+00:11:16,380 --> 00:11:19,560
+في موقع واحد، مين تقول هانه هانه هانه إذا أنا
+
+134
+00:11:19,560 --> 00:11:23,340
+بتطلع .. إذا أنا بتطلع عليهم، بلاحظ إنه أحد
+
+135
+00:11:23,340 --> 00:11:26,600
+الأشكال، يعني لو بدأ أشوف هذا ال carbocation هنا
+
+136
+00:11:26,600 --> 00:11:30,100
+secondary carbocation لو بدأ أشوف هذا ال
+
+137
+00:11:30,100 --> 00:11:35,930
+carbocationstill secondary لو بدأ أشوف هذا الكاربو
+
+138
+00:11:35,930 --> 00:11:40,850
+كاتيون tertiary لأن أحد ال resonance structures
+
+139
+00:11:40,850 --> 00:11:46,290
+اللي عملها tertiary بفضل هذا الموقع طبعا اللي بدو
+
+140
+00:11:46,290 --> 00:11:51,510
+يصير ان انتوا بعد هيك لو اجيتوا عملتوا على الميتا
+
+141
+00:11:51,510 --> 00:11:55,150
+هتلاحظوا انه مش هيكون في واحد tertiary
+
+142
+00:11:58,080 --> 00:12:03,500
+عشان تكونوا متأكدين مثل هذه الرسمة تلت مرات تحطوا
+
+143
+00:12:03,500 --> 00:12:08,780
+ال Electrophile على ال Ortho تحطوه على ال Meta
+
+144
+00:12:08,780 --> 00:12:14,520
+تحطوه على ال Para هتلاحظوا أنه في حالة ال Ortho و
+
+145
+00:12:14,520 --> 00:12:18,320
+في حالة ال Para أحد ال structures ال resonance
+
+146
+00:12:18,320 --> 00:12:21,540
+structures very stable هذا اللي بيشجع أنه يروح على
+
+147
+00:12:21,540 --> 00:12:24,820
+ال Ortho و ال Para في حالة ال Meta هتلاحظوا أنه
+
+148
+00:12:24,820 --> 00:12:31,030
+مافيش شيءCarbocation tertiary فالان اي توجه بيكون
+
+149
+00:12:31,030 --> 00:12:36,070
+احد اطرافه اللي بيعمله contribution يعني بيدخلوا
+
+150
+00:12:36,070 --> 00:12:39,630
+في ال resonance tertiary بيكون مفضل ان هو اللي
+
+151
+00:12:39,630 --> 00:12:44,270
+بيقدي ال tertiary عندى البارا وال اورثو لو عملته
+
+152
+00:12:44,270 --> 00:12:47,650
+لو روحتوا عملتوا الميتا في البيت هيك زي واجب
+
+153
+00:12:47,650 --> 00:12:51,150
+homework حطيتوا على الميتا H وelectrophile وعملتوا
+
+154
+00:12:51,150 --> 00:12:54,510
+بوستفانو نجلته ونجلته ونجلته هتلاحظوا انه مش هيجي
+
+155
+00:12:54,510 --> 00:13:02,030
+على ال tertiaryواضح فسبب التفضيل لل ortho وال para
+
+156
+00:13:02,030 --> 00:13:07,110
+positions هنا أنه بيكون أحد ال resonance
+
+157
+00:13:07,110 --> 00:13:12,010
+structures لل carbocation the stable tertiary
+
+158
+00:13:12,010 --> 00:13:19,520
+carbocation واضحلاحظوا كم عملية الثبات عملية مهمة،
+
+159
+00:13:19,520 --> 00:13:24,040
+واضح؟ كل الناس بتسأل إيش؟ للثبات التفاعل نتيجته
+
+160
+00:13:24,040 --> 00:13:28,140
+الآن بإيش محكومة؟ بالثبات وجود أحد ال resonance
+
+161
+00:13:28,140 --> 00:13:31,200
+structures، tertiary هو اللي بيخلي التفاعل يروح
+
+162
+00:13:31,200 --> 00:13:38,540
+على ال orthoو ال bara positions الآن لو اجينا
+
+163
+00:13:38,540 --> 00:13:43,400
+عملنا تجربة نشوف النتائج لو اجينا عملنا تجربة نشوف
+
+164
+00:13:43,400 --> 00:13:48,820
+النتائج بالظبط مثلا لو أخدنا التلوين التلوين
+
+165
+00:13:48,820 --> 00:13:55,820
+اتفقنا انه orthobaradirecting ال methyl group
+
+166
+00:13:55,820 --> 00:13:59,400
+orthobaradirecting group بناء على ذلك لو اجينا
+
+167
+00:13:59,400 --> 00:14:04,950
+عملنا nitration ال nitro وين هتروح؟يا إما على الـ
+
+168
+00:14:04,950 --> 00:14:10,230
+Ortho يا إما على الـ Para نشوف نتائج واقعية كيف
+
+169
+00:14:10,230 --> 00:14:15,670
+طلعت بالتجربة بالظبط لما عملوا هذا التفاعل لاحظوا
+
+170
+00:14:15,670 --> 00:14:22,610
+أنه 63% من الناتجأجت الـ Nitrofy على الـ
+
+171
+00:14:22,610 --> 00:14:29,110
+Orthoposition و 34% من الناتج أجت الـ Nitrofy على
+
+172
+00:14:29,110 --> 00:14:35,210
+الـ Paraposition و فقط 3% من الناتج اللي بنعتبره
+
+173
+00:14:35,210 --> 00:14:41,530
+إيش يعني negligible مهمل أجت فيه على الميتا واضح؟
+
+174
+00:14:42,410 --> 00:14:47,770
+أجت فيه علمية لاحظوا هنا بتكونوا برضه دقيقين بفهم
+
+175
+00:14:47,770 --> 00:14:52,130
+الدنيا بتكونوا دقيقين بفهم الدنيا يعني احنا بنحط
+
+176
+00:14:52,130 --> 00:14:57,210
+قوانين تمام؟ بس مش لازم الدنيا .. مش لازم الدنيا
+
+177
+00:14:57,210 --> 00:15:01,310
+مية في المية تكون ماشي على القوانين إلا يكون فيه
+
+178
+00:15:01,310 --> 00:15:06,530
+شوية انحراف يعني مثلا ربنا سبحانه وتعالى بيقول و
+
+179
+00:15:06,530 --> 00:15:10,770
+لا تقتلوا النفس التي حرم الله إلا بالحقالأصل في
+
+180
+00:15:10,770 --> 00:15:16,010
+المجتمع أنه مافيش قتل، لكن في السنة بنهز المجتمع
+
+181
+00:15:16,010 --> 00:15:20,510
+أربع أو خمس أو ست مرات بجرائم قتل مشعة، هي الـ3%
+
+182
+00:15:20,510 --> 00:15:27,370
+هذه، واضح؟فلما نقول أن مثلا هذا الشارع اتجاه واحد،
+
+183
+00:15:27,370 --> 00:15:31,630
+لازم كل السيارات تمشي بهذا الشكل، الآن بيصيرش
+
+184
+00:15:31,630 --> 00:15:36,630
+أربع، خمس، ست حالات في وقت ما يمشوا عكس القانون،
+
+185
+00:15:36,630 --> 00:15:40,570
+بيصير، واضح؟ فدائما هذه الأشياء ما تستغربوهاش، لأن
+
+186
+00:15:40,570 --> 00:15:44,830
+هذا حال الدنياالـ trend العام التوجه العام واضح
+
+187
+00:15:44,830 --> 00:15:49,570
+تماما ان الـ nitrate لما يكون عند طلوين مثل group
+
+188
+00:15:49,570 --> 00:15:53,630
+ortho para directing group واضحة نسبة تلاتة وستين
+
+189
+00:15:53,630 --> 00:15:57,070
+في المية واربعة وتلاتين في المية لكن بيصير أشياء
+
+190
+00:15:57,070 --> 00:16:02,870
+بسيطة تلاتة في المية ميتة بيصير مش معدوم يعني واضح
+
+191
+00:16:02,870 --> 00:16:07,850
+وهذه نتائج تجريبية
+
+192
+00:16:08,590 --> 00:16:14,770
+الآن لاحظوا في المقابل مجموعة السيانو إحنا إذا
+
+193
+00:16:14,770 --> 00:16:19,810
+بتطلعوا السيانو اعتبرناها Deactivating Ometa
+
+194
+00:16:19,810 --> 00:16:24,610
+Directing Group Deactivating Ometa Directing Group
+
+195
+00:16:24,610 --> 00:16:29,630
+لو أنا إجيت بدي أطلع على النتيجة الفعلية للتفاعل
+
+196
+00:16:29,630 --> 00:16:36,870
+النتيجة الفعلية هلاحظ إن الميتا لوحده ماخد 81%
+
+197
+00:16:36,870 --> 00:16:38,470
+واضح؟
+
+198
+00:16:40,760 --> 00:16:44,840
+الأورثو مازال مااخدله نسبة لكن بتضال بالنسبة
+
+199
+00:16:44,840 --> 00:16:49,800
+للواحد و ثمانين فالمية قليلة البارا اتنين فالمية
+
+200
+00:16:49,800 --> 00:16:56,170
+اذا ال major reaction هنا الميتةعشان هيك لما إحنا
+
+201
+00:16:56,170 --> 00:17:00,650
+بنيجي بنحكي إنه هذا التفاعل بيعطينا ال meta
+
+202
+00:17:00,650 --> 00:17:05,170
+product أو ال orthو زاد ال para product بنقول as
+
+203
+00:17:05,170 --> 00:17:10,090
+major products كلمة major products بتختلف عن
+
+204
+00:17:10,090 --> 00:17:14,830
+exclusive products exclusive يعني حصري يعني مافيش
+
+205
+00:17:14,830 --> 00:17:20,070
+نهائيا غيره أنا هنا مابقولش exclusive بشكل مطلق
+
+206
+00:17:20,070 --> 00:17:26,820
+أنا بقول بشكل عام واضح؟زي ما بنقول بشكل عام،
+
+207
+00:17:26,820 --> 00:17:32,440
+المسلم لا يغضب المسلم بشكل عام، بس حد بيقدر يقول
+
+208
+00:17:32,440 --> 00:17:38,140
+إنه هذه بشكل حصري؟ لأ، بشكل عام، بشكل عام التفاعل
+
+209
+00:17:38,140 --> 00:17:44,480
+ميته في حالة وجود الـ cyano group هذا ممنعش إنه في
+
+210
+00:17:44,480 --> 00:17:50,900
+أشياء تانية بتصير شدود عن القاعدة الآن
+
+211
+00:17:53,540 --> 00:17:57,920
+هكذا أصبح نوعا ما واضح لدي أنه لو كان في عندي
+
+212
+00:17:57,920 --> 00:18:01,920
+مجموعة .. لو كان في عندي مجموعة، كيف تأثيرها؟ من
+
+213
+00:18:01,920 --> 00:18:06,980
+ناحية الـ reactivity و من ناحية الـ orientation؟
+
+214
+00:18:06,980 --> 00:18:12,320
+الآن، يا تورا، لو كان في مجموعتين، مش مجموعة
+
+215
+00:18:12,320 --> 00:18:19,680
+واحدة، و بدأ تيجي التالتة، بيصير في إيش؟نوع من
+
+216
+00:18:19,680 --> 00:18:25,040
+التنافس لو في عندى مجموعتين و بدأ تيجي التالتة
+
+217
+00:18:25,040 --> 00:18:30,200
+بيصير في عندى نوعا ما نوع من التنافس خلينا ناخد
+
+218
+00:18:30,200 --> 00:18:37,280
+بعض الأمثلة الآن اتطلع عندى هنا ال CH3 و ال OCH3
+
+219
+00:18:37,280 --> 00:18:41,780
+نفترض هذا الجزء موجود مالناش فيه كيف يتكون مش صعب
+
+220
+00:18:41,780 --> 00:18:48,460
+يتكونواضح؟ لو بدأت أقولكم السؤال يا تورا كيف هذا
+
+221
+00:18:48,460 --> 00:18:54,020
+الجزء ممكن يكون اتكون؟ إيش أفضل طريقة عشان إحنا
+
+222
+00:18:54,020 --> 00:18:59,320
+نصنعه مبتدئين من البنزين؟
+
+223
+00:18:59,320 --> 00:19:05,260
+ارجعولي لنقطة، مين more activating؟
+
+224
+00:19:05,260 --> 00:19:12,660
+بنرجع و بنفرجيكوا إياها على الشاشةالـ OCH3 more
+
+225
+00:19:12,660 --> 00:19:19,700
+activating than CH3 واضح؟ بتعمل activation أكتر
+
+226
+00:19:19,700 --> 00:19:25,160
+بناء على ذلك لو أنا بدي أبدأ ببنزين إذا حطيت ال
+
+227
+00:19:25,160 --> 00:19:29,840
+OCH3 و بعدين بدي أكمل التفاعل أعمل methylation
+
+228
+00:19:29,840 --> 00:19:33,700
+هتيجي المثل على ال ortho و ال para position باخد
+
+229
+00:19:33,700 --> 00:19:37,180
+مركب ال para اللي أنا مهتم فيه و لو حطيت المثل
+
+230
+00:19:37,180 --> 00:19:42,330
+groupوبدي اضيف ال O مثل برضه هتيجي على ال ortho و
+
+231
+00:19:42,330 --> 00:19:47,490
+ال para لكن انا ولا اصح ان اعمله ان ابدأ ابتلوين
+
+232
+00:19:47,490 --> 00:19:48,830
+ولا ابدأ
+
+233
+00:19:52,350 --> 00:19:59,250
+بال OCH3 لأن ال OCH3 more activating واضح؟ تفاعلها
+
+234
+00:19:59,250 --> 00:20:04,290
+بيكون إيش أسرع الآن هذا مش شغلنا كيف حضروا هذا
+
+235
+00:20:04,290 --> 00:20:07,370
+الجزء إحنا شغلنا كيف هذا الجزء بدنا نعمل عليه
+
+236
+00:20:07,370 --> 00:20:13,040
+تفاعل إضافيمثلا بدنا نفعله مع البروميين ال مثل
+
+237
+00:20:13,040 --> 00:20:17,680
+group اورثو بارا directing group البارا تبعها مسكر
+
+238
+00:20:17,680 --> 00:20:24,760
+اش بيضللها ال اورثو و ال ا مثل اورثو بارا
+
+239
+00:20:24,760 --> 00:20:29,160
+directing group البارا مسكر اش بيضللها ال اورثو
+
+240
+00:20:29,160 --> 00:20:32,540
+position اللي جنبها هنا طيب لو اجينا ضفنا
+
+241
+00:20:32,540 --> 00:20:36,860
+البرومياطورة وين بده يروح التفاعل؟بدو ييجي على ال
+
+242
+00:20:36,860 --> 00:20:41,920
+ortho تبع ال مثل ولا على ال ortho تبع ال او مثل اه
+
+243
+00:20:41,920 --> 00:20:47,660
+هنا الأقوى بتغلب مين more activating ال OCH3
+
+244
+00:20:47,660 --> 00:20:52,260
+عشانيك بلاحظ ان بروم ايجي هنا مش على هذا الموقع
+
+245
+00:20:54,000 --> 00:20:58,340
+واضح؟ بهمش، هو بيكون Ortho بالنسبة لل CH3 لكن ليش
+
+246
+00:20:58,340 --> 00:21:03,520
+مايجياش Ortho لل CH3؟ لأنه مثل أسرع و more active
+
+247
+00:21:03,520 --> 00:21:09,160
+بالتفاعل، أنه أول ما ييجي لبروم، يروحياخدوا على ال
+
+248
+00:21:09,160 --> 00:21:13,660
+اورثو بالنسبة له إذا هنا اللي حكم نتيجة التفاعل ال
+
+249
+00:21:13,660 --> 00:21:17,880
+activating جداش هذا activating جداش هذا activating
+
+250
+00:21:17,880 --> 00:21:23,180
+واضح اللي هو ال reactivity النسبية relative
+
+251
+00:21:23,180 --> 00:21:27,920
+reactivity of both the O-methyl group and the CH3
+
+252
+00:21:27,920 --> 00:21:32,730
+group O-methyl group is more activating thanالـ
+
+253
+00:21:32,730 --> 00:21:36,930
+CH3 group عشان هيك الناتج تبعها اتغلب على الناتج
+
+254
+00:21:36,930 --> 00:21:42,970
+تبع ال CH3 واضح؟
+
+255
+00:21:42,970 --> 00:21:49,810
+هي هانا بيجي عندنا مثال تاني عندنا مجموعتين و بدنا
+
+256
+00:21:49,810 --> 00:21:57,040
+نحط التالتة عندنا أيش؟مجمعتين و بدنا نحط التالتة
+
+257
+00:21:57,040 --> 00:22:02,400
+الان هالمجمعتين اللي عندياهم انا المثل .. المثل
+
+258
+00:22:02,400 --> 00:22:08,040
+وين بتودى؟ على ال ortho .. البرة تبقى همسكتع
+
+259
+00:22:08,040 --> 00:22:12,200
+الأورثو والنيترو وين بتوده؟ على ال meta الان
+
+260
+00:22:12,200 --> 00:22:16,440
+لاحظوا معنى ال meta تبع النيترو هو نفس ال ortho
+
+261
+00:22:16,440 --> 00:22:19,540
+تبع ال methyl يعني كأنه صار عند بس ال tintel
+
+262
+00:22:19,540 --> 00:22:22,920
+بواجهه على هذا الموقع هذا الموقع نهائي اللي مافيش
+
+263
+00:22:22,920 --> 00:22:30,550
+إشي بيوده عليهواضح؟ الان O2 بتودع على الميتا
+
+264
+00:22:30,550 --> 00:22:35,050
+بالنسبة لها هاي الميتا one two three بتودع موقع
+
+265
+00:22:35,050 --> 00:22:39,550
+تلاتة بالنسبة لها والمثل بتودع على موقع اتنين
+
+266
+00:22:39,550 --> 00:22:43,730
+بالنسبة لها اورثو اذا كأنه المجمعتين بيودوا على
+
+267
+00:22:43,730 --> 00:22:49,910
+نفس الموقع عشانك بيصير عنده مجموعة النيترو الجديدة
+
+268
+00:22:49,910 --> 00:22:54,050
+هذه بتيجي على هذا الموقع ولو كان عندنا النيترو
+
+269
+00:22:54,050 --> 00:22:58,930
+كتير بتيجي اللي بعدهاكمان على هذا الموقع، على
+
+270
+00:22:58,930 --> 00:23:01,830
+الموقع التاني، يعني بيصير مرتين نيتراشن، بيصير
+
+271
+00:23:01,830 --> 00:23:08,390
+عندى الـ Trinitro تلوين اللي هو ال explosive TNT
+
+272
+00:23:08,390 --> 00:23:16,090
+المادة المتفجرة اللي بيسموها TNT، واضح؟
+
+273
+00:23:16,090 --> 00:23:24,210
+شفتوا كيف تجميع التأثيرات؟ يعني كأنه اتفقت مصالح
+
+274
+00:23:24,210 --> 00:23:30,940
+الـ Nitroوالمثل على هذا الموقع زي ما بيصير تماما
+
+275
+00:23:30,940 --> 00:23:38,320
+في السياسة هاي في عندنا كمان مثال ممتعة هذه
+
+276
+00:23:38,320 --> 00:23:41,900
+الأمثلة لإيه؟ لإنه بتفرجيكوا واقع الدنيا كيف
+
+277
+00:23:41,900 --> 00:23:47,660
+المصالح بتتفق كيف التنافس بيصير في عندكم مثل
+
+278
+00:23:47,660 --> 00:23:49,040
+وchlor
+
+279
+00:23:51,960 --> 00:23:57,640
+الان الميثل اكتفاط الكلور دي مش مشكلة مشكلتي انا
+
+280
+00:23:57,640 --> 00:24:02,940
+في ال orientation وين بيودي الميثل وين بيودي
+
+281
+00:24:02,940 --> 00:24:08,140
+الكلور الان الميثل الأحمر بيودي على موقع ارثو يعني
+
+282
+00:24:08,140 --> 00:24:13,470
+هذا الموقع او هذا الموقعأو بارا اورثو او بارا يعني
+
+283
+00:24:13,470 --> 00:24:16,610
+المثل ممكن يحط حسب اللون تبعه زي ما انتوا شايفين
+
+284
+00:24:16,610 --> 00:24:21,270
+اورثو اورثو او بارا يعني هذا الموقع متحقله هذا
+
+285
+00:24:21,270 --> 00:24:26,790
+الموقع متحقله هذا الموقع متحقله الكلور وين بيوده
+
+286
+00:24:26,790 --> 00:24:30,730
+بالنسباله بيودع ال اورثو وين ال اورثو تبع الكلور
+
+287
+00:24:30,730 --> 00:24:37,710
+هذا وهذا هاي واحد اتنين واحدالاتنين والبارة اللي
+
+288
+00:24:37,710 --> 00:24:42,550
+هنا إذا مرة تانية اتحدوا في التلت موادع يعني
+
+289
+00:24:42,550 --> 00:24:48,050
+الميثل والكلور بيواجهوا على التلت مواقع طيب خلينا
+
+290
+00:24:48,050 --> 00:24:54,770
+نشوف إيش نتيجة التجربة نشوف إيش نتيجة التجربة
+
+291
+00:24:54,770 --> 00:25:04,290
+الموقع هذا إيجي عليه كلور واضح؟ شايفينه؟ والموقع
+
+292
+00:25:05,470 --> 00:25:13,650
+هذا إيجي عليه chlorine و الموقع هذا إيش مكتوب
+
+293
+00:25:13,650 --> 00:25:19,010
+عندكم ال product not observed مابينش عليه chlorine
+
+294
+00:25:19,010 --> 00:25:23,770
+رغم إنه نظريا هنا و هنا و هنا متوقع ييجي ال
+
+295
+00:25:23,770 --> 00:25:28,430
+chlorine بس عمليا إيجي هنا و إيجي هنا ماإيجيش هنا
+
+296
+00:25:28,430 --> 00:25:34,030
+الآن لو قلنا لواحدة منكم ليش طيب تتوقع هذا الكلام
+
+297
+00:25:34,030 --> 00:25:34,450
+يصير؟
+
+298
+00:25:38,680 --> 00:25:43,340
+بكون ازدحام ازدحام تنسوش ان كل الـ Geometry لما
+
+299
+00:25:43,340 --> 00:25:47,800
+درستوها في الكيميا كانت مرتبطة بأي موضوع بالازدحام
+
+300
+00:25:47,800 --> 00:25:51,460
+لما كان يكون عندكم تلت ذرات ليش كنتوا تعملوا الجزء
+
+301
+00:25:51,460 --> 00:25:57,860
+Linear؟ عشان تخلوا الزاوية 180 فالجزيات بتشرط من
+
+302
+00:25:57,860 --> 00:26:02,920
+الازدحام الآن المجموعة اللي بدأ تيجي هنا تتخيلوا
+
+303
+00:26:02,920 --> 00:26:10,440
+ان الكلور مخد حيزوالمثل C ومخدة H وH وH مخدة حيز
+
+304
+00:26:10,440 --> 00:26:14,720
+لحد هنا بناء على ذلك هل من السهل أن تدخل لو
+
+305
+00:26:14,720 --> 00:26:18,860
+تخيلتوا أن هذه إليها حيز إلكتروني مظبوط ولا لأ؟
+
+306
+00:26:18,860 --> 00:26:23,360
+وهذه إليها حيز إيه؟ هل من السهل إنها تيجي هنا؟ صعب
+
+307
+00:26:23,360 --> 00:26:27,740
+إذن هنا اتدخل عامل الاستحاب بس من ناحية نظرية
+
+308
+00:26:27,740 --> 00:26:30,100
+المفروض أنه ممكن تيجي هنا وممكن تيجي هنا وممكن
+
+309
+00:26:30,100 --> 00:26:33,400
+تيجي هنا لكن هذا الموقع product not observed
+
+310
+00:26:35,480 --> 00:26:40,840
+توهندرد يعني مزدحم كثيرا هذا الموقع مزدحم كثيرا
+
+311
+00:26:40,840 --> 00:26:50,200
+واضح؟ هذا الموقع مزدحم كثيرا الآن
+
+312
+00:26:50,200 --> 00:26:55,100
+هنا في عندنا مجموعة من الأمثلة المحلولة بس نتأكد
+
+313
+00:26:55,100 --> 00:26:58,400
+انه ابتدقنوا انتوا الحال تبعها
+
+314
+00:27:02,010 --> 00:27:06,710
+بتطلع عندنا بدكوا تبدأوا بطولين نعمله chlorination
+
+315
+00:27:06,710 --> 00:27:12,690
+وين هيجي ال chlorine؟ على ال ortho و ال bara هنا
+
+316
+00:27:12,690 --> 00:27:17,890
+كتب ال bara و كتب الكزايد ال ortho product يعني
+
+317
+00:27:17,890 --> 00:27:24,750
+بتطلع خليط من الناتجين عندكم sulfonic acidالسيلفون
+
+318
+00:27:24,750 --> 00:27:28,670
+اللي قلنا عنها الـ Deactivating و Meta Directing
+
+319
+00:27:28,670 --> 00:27:33,130
+Group لما بتعمل البروميناتش مع FEPR3 وين هتيجي
+
+320
+00:27:33,130 --> 00:27:36,970
+بالنسبة لها على الميتا يعني على موقع تلاتة هاي ال
+
+321
+00:27:36,970 --> 00:27:45,730
+S 123 إجت لبرومين على موقع ميتا واضح إجت لبرومين
+
+322
+00:27:45,730 --> 00:27:50,700
+على موقع ميتا بالنسبة لالمجموعة اللى موجودة أصلا
+
+323
+00:27:50,700 --> 00:27:55,460
+كل المجموعات اللى بتيجي بتيجي بالنسبة للمجموعة
+
+324
+00:27:55,460 --> 00:28:00,860
+اللى موجودة أصلا الان هنا عندكم نيترو بدنا نعمل
+
+325
+00:28:00,860 --> 00:28:06,080
+ايو دي نيشت بدت تيجي وين النيترو ميتا ميتا
+
+326
+00:28:06,080 --> 00:28:08,760
+directing group وين ال meeta تبعها واحد اتنين
+
+327
+00:28:08,760 --> 00:28:12,060
+تلاتة او واحد اتنين تلاتة لاحظوا هي اتجت واحد
+
+328
+00:28:12,060 --> 00:28:17,220
+اتنين تلاتة اتجت فعلا على موقع تلاتة اللى هو ال
+
+329
+00:28:17,220 --> 00:28:24,370
+meetaأجت على موقع تلاتة اللي هو الميتا position
+
+330
+00:28:24,370 --> 00:28:30,390
+نتطلع
+
+331
+00:28:30,390 --> 00:28:33,730
+كمان
+
+332
+00:28:33,730 --> 00:28:40,640
+على هذه الأمثلة عندكم ال chlorineالكلورين وين
+
+333
+00:28:40,640 --> 00:28:47,180
+بيوده؟ اورثو بارا لما تحط SO3 H2SO4 اللي هو سمناه
+
+334
+00:28:47,180 --> 00:28:52,200
+sulfonation اخدناه سمناه sulfonation بناء العدالة
+
+335
+00:28:52,200 --> 00:28:57,120
+كاي كتب لكوا بارا product زائد الارثو ايزو مارز
+
+336
+00:28:57,120 --> 00:29:02,300
+لان هدولة ايزو مارز نفس الصيغة الجزائية لكن
+
+337
+00:29:02,300 --> 00:29:06,280
+الاختلاف في مواقع الروابط او في الصيغة البنائية
+
+338
+00:29:06,510 --> 00:29:12,270
+الان لو كان عندكم طلوين و حطينا excess HNO3 و
+
+339
+00:29:12,270 --> 00:29:17,770
+H2SO4 يجب ان يأتي على البارا و بعدين زي ما قبل
+
+340
+00:29:17,770 --> 00:29:21,750
+شوية فارجيناكوا بالمثال على ال اورثو و على ال
+
+341
+00:29:21,750 --> 00:29:26,310
+اورثو تلت مجموعات نيترو لان الطلوين اكتفت و حطينا
+
+342
+00:29:26,310 --> 00:29:34,460
+excess فبصير عندى tri-nitro طلوينلو كان عندكم هذا
+
+343
+00:29:34,460 --> 00:29:38,780
+المُركّب اللي هو اسمه إيش؟ مين اتذكرناه؟ الـ
+
+344
+00:29:38,780 --> 00:29:43,520
+isopropyl ع البنزين الكيومين
+
+345
+00:29:43,520 --> 00:29:48,420
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+346
+00:29:48,420 --> 00:29:48,420
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+347
+00:29:48,420 --> 00:29:48,420
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+348
+00:29:48,420 --> 00:29:48,540
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+349
+00:29:48,540 --> 00:29:48,840
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+350
+00:29:48,840 --> 00:29:48,840
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+351
+00:29:48,840 --> 00:29:48,840
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+352
+00:29:48,840 --> 00:29:48,840
+الكيومين الكيومين الكيومين الكيومين الكيومين
+
+353
+00:29:48,840 --> 00:29:53,440
+الكيومين الكيومين الكيومين الكيومين الكيوم
+
+354
+00:29:54,730 --> 00:29:59,570
+Orthopara directing groups or activating بناء ع
+
+355
+00:29:59,570 --> 00:30:03,950
+ذلك لو بدأ تيجي هذا المركب اللي فيه C double bond
+
+356
+00:30:03,950 --> 00:30:07,150
+OCL مع aluminium chloride واضح ال aluminium
+
+357
+00:30:07,150 --> 00:30:10,450
+chloride بده ياخد منه ال chlorine بده يعمل
+
+358
+00:30:10,450 --> 00:30:14,630
+oscillation بده يحط C double bond O مع الحلقة
+
+359
+00:30:14,630 --> 00:30:19,750
+تماما هذا المثال زي لو كان عندكم CH3C double bond
+
+360
+00:30:19,750 --> 00:30:25,030
+OCL شو كنتوا تحط OCL؟ شو كنتوا تحطوه؟الان انا لغيت
+
+361
+00:30:25,030 --> 00:30:29,550
+من هنا CH3 و حطيت Cyclopentane في مشكلة المهم
+
+362
+00:30:29,550 --> 00:30:34,650
+تفاعل وين بده يتم على هذه الكربون هذه ال الكلجروب
+
+363
+00:30:34,650 --> 00:30:40,750
+وين بتوده اورثو و بارا عشان ايه كانت بيانت على
+
+364
+00:30:40,750 --> 00:30:46,430
+البارا لاحظوا هنا يمكن تلاحظوا شغلة ماكتبش زائد
+
+365
+00:30:46,430 --> 00:30:52,750
+اورثو ايزو ماربتقدروا تتخيلوا عاد ليش ما كتبش زي
+
+366
+00:30:52,750 --> 00:30:59,610
+ات ارثو اي زمر لأن هذه المجموعة لسه CH لما يطلع
+
+367
+00:30:59,610 --> 00:31:06,110
+منها كCHHHH و من هنا CHHHH و بده يجيب كل هذه هانا
+
+368
+00:31:06,110 --> 00:31:12,080
+جنبهابصير ازدحام اذا وين الاريح اليها تروح؟ ع
+
+369
+00:31:12,080 --> 00:31:15,760
+البارا عشان هيك كما .. يعني كما يبدو انه انا بس
+
+370
+00:31:15,760 --> 00:31:19,960
+بيطلع عندكم البارا product لإن هذي لما افصلها
+
+371
+00:31:19,960 --> 00:31:24,280
+المجموعة لفوق و لتحت و هذي في ال .. بالذات كمان ال
+
+372
+00:31:24,280 --> 00:31:29,800
+cyclopentane مجموعة كبيرة بتصير هذه المنطقة مزدحمة
+
+373
+00:31:29,800 --> 00:31:32,620
+too hindered for a reaction to occur
+
+374
+00:31:35,750 --> 00:31:40,430
+بقول إنه من ناحية نظرية متوقع التفاعل يتم هان أو
+
+375
+00:31:40,430 --> 00:31:46,690
+هان أو هان هذا
+
+376
+00:31:46,690 --> 00:31:53,070
+هاي ال CH3 أول مجموعة وين بتيجي نفترض على البارة
+
+377
+00:31:53,070 --> 00:31:56,810
+بعد ما إجت على البارة where بتصير تودي هذه
+
+378
+00:31:56,810 --> 00:32:01,630
+المجموعةالـ Nitro اللى جاءت هنا على الميتا
+
+379
+00:32:01,630 --> 00:32:04,030
+بالنسبالي لو هذى وين بتودى على الأورتو بالنسبالي
+
+380
+00:32:04,030 --> 00:32:06,810
+هذا المثال الحكيناه قبل شوية بس انت حضرتك مش من
+
+381
+00:32:06,810 --> 00:32:09,810
+تبه .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+382
+00:32:09,810 --> 00:32:11,570
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+383
+00:32:11,570 --> 00:32:12,330
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+384
+00:32:12,330 --> 00:32:15,070
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+385
+00:32:15,070 --> 00:32:15,070
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+386
+00:32:15,070 --> 00:32:16,670
+بهمش .. بهمش .. بهمش .. بهمش .. بهمش .. بهمش ..
+
+387
+00:32:16,670 --> 00:32:26,710
+بهمش .. بهمش .. بهمش .. بهمش .. بهم
+
+388
+00:32:28,530 --> 00:32:31,910
+هو نفس المثال بس هنا مفصل اكثر
+
+389
+00:32:40,100 --> 00:32:44,440
+هنا بيجينا بعض الأمثلة .. هنا بيجينا بعض الأمثلة
+
+390
+00:32:44,440 --> 00:32:49,580
+كيف ممكن اتحضروا و هذا دائما و أبدا في الامتحان
+
+391
+00:32:49,580 --> 00:32:53,660
+احنا إلا نسألكوا أسئلة زي هيك نجيبلكوا مركب ب two
+
+392
+00:32:53,660 --> 00:32:58,280
+substituents و نقولكم كيف ممكن تحضروا هذا المركب
+
+393
+00:32:58,280 --> 00:33:05,660
+الآن هنا بدكم تاخدوا بالكم من إيش؟ من عاملين عامل
+
+394
+00:33:05,660 --> 00:33:11,700
+ال orientationو عامل ال reactivity السؤال تركزه
+
+395
+00:33:11,700 --> 00:33:17,480
+أنه أي مجموعة أحط في الأول و أي مجموعة أحط في
+
+396
+00:33:17,480 --> 00:33:21,540
+التاني يعني أنا بدي أبدأ من البنزين لما بدي أبدأ
+
+397
+00:33:21,540 --> 00:33:26,100
+من البنزين مثلا في هذا المركب بدي أحط مجموعة ال
+
+398
+00:33:26,100 --> 00:33:29,260
+CH3 معروف بحطها من ال methyl chloride مع aluminium
+
+399
+00:33:29,260 --> 00:33:33,800
+chloride و بدي أحط مجموعة ال acetyl بحطها من ال
+
+400
+00:33:33,800 --> 00:33:37,780
+acetyl chloride مع aluminium chlorideلكن هدولة
+
+401
+00:33:37,780 --> 00:33:42,540
+خطوتين أنيا بدأ أعملها في الأول و أي واحدة بدأ
+
+402
+00:33:42,540 --> 00:33:46,640
+أعملها في التاني هذا هو السؤال واضح دائما لما
+
+403
+00:33:46,640 --> 00:33:52,320
+نجيبلكم سؤال بنزين عليه مجموعتين كأنا بقولكم أي
+
+404
+00:33:52,320 --> 00:33:56,020
+واحدة في الأول أي واحدة في التاني الآن بإمكانكوا
+
+405
+00:33:56,020 --> 00:34:01,680
+أنتوا تكتبوا البنزين وتعملوا الاحتمالينتقولوا
+
+406
+00:34:01,680 --> 00:34:05,400
+خلّينا في الأول نعمل ال methylation أو نعمل ال
+
+407
+00:34:05,400 --> 00:34:08,320
+acetylation و بعدين in turn نعمل الخطوة التانية
+
+408
+00:34:08,320 --> 00:34:11,700
+هان و الخطوة التانية هان على طول هتكتشفوا أن أحد
+
+409
+00:34:11,700 --> 00:34:18,420
+المسارين جيد و المسار الآخر غير جيد يعني لو مثلا
+
+410
+00:34:18,420 --> 00:34:24,730
+أنا بدأت بالبنزين اعملت الطلوينإذا الخطوة الأولى
+
+411
+00:34:24,730 --> 00:34:30,430
+بنزين عملت بعدها إيش؟ طلوين ممكن نعملها على هذه
+
+412
+00:34:30,430 --> 00:34:41,290
+السطورة هذه بنزين حطيت CH3Cl ألمنيوميكلورايد صار
+
+413
+00:34:41,290 --> 00:34:46,790
+عنده طلوين okay الآن في الخطوة التانية شو هأعمل؟
+
+414
+00:34:49,090 --> 00:34:55,190
+بدي أضيف الـ acetyl اللي هي CH3C double bond OCl
+
+415
+00:34:55,190 --> 00:35:01,630
+في وجود aluminium chloride مظبوط ولا لا؟ طيب لما
+
+416
+00:35:01,630 --> 00:35:05,770
+بعمل مين اللي بتحكم في نتيجة التفاعل؟ المجموعة
+
+417
+00:35:05,770 --> 00:35:09,290
+اللي already موجودة CH3 وين بتودي ال CH3؟ على ال
+
+418
+00:35:09,290 --> 00:35:14,270
+ortho و على ال para إذا في النهاية بتطلعلي المركب
+
+419
+00:35:14,270 --> 00:35:20,560
+اللي أنا بدياه ولا لأ؟بتطلعوا هاي CH3 بتطلع للبارة
+
+420
+00:35:20,560 --> 00:35:27,140
+اللي أنا عاوزه زاد ال ortho زاد ال ortho product
+
+421
+00:35:27,140 --> 00:35:32,540
+إذا هذا المسار بتطلع للناتج واضح؟ هذا المسار بتطلع
+
+422
+00:35:32,540 --> 00:35:38,220
+للناتج الآن اتخيلوا لو بدأت بالمسار التالي حطيت في
+
+423
+00:35:38,220 --> 00:35:44,560
+الأول ال CW bond OCH3 ال CW bond OCH3 لوين بتوده؟
+
+424
+00:35:44,560 --> 00:35:52,850
+للميجايعني لو حطيت هنا بنزين و قولت بتحط CW.O CH3
+
+425
+00:35:52,850 --> 00:36:00,990
+ممكن نعملها هنا CH3 CW.O Cl Aluminium Chloride و
+
+426
+00:36:00,990 --> 00:36:05,310
+خلّيني أحطها على نفس الموقع اللي مبين عليه مش
+
+427
+00:36:05,310 --> 00:36:16,190
+مشكلة حطت هنا CW.O CH3 الآن اعملولي ال second step
+
+428
+00:36:17,550 --> 00:36:22,930
+اللي هي CH3Cl زي الألومنيوم الكلوري وين هييجي
+
+429
+00:36:22,930 --> 00:36:30,810
+بالنسبة لهذه المجموعة؟ هل يعطي ناتج؟ لأ لأ واضح؟
+
+430
+00:36:30,810 --> 00:36:40,410
+إذا هذه الـC double bond O CH3 وهنا هل هذا قدّالي
+
+431
+00:36:40,410 --> 00:36:45,470
+لنفس الناتج؟ لكن يقصد بيعطي نفس الناتج لو CH3 وجهت
+
+432
+00:36:45,470 --> 00:36:50,710
+على الـRكيف؟ لأ طبعا ال ortho مش هو نفس النتيجة ده
+
+433
+00:36:50,710 --> 00:36:57,610
+ميتا لو بدأنا بال CH3 هاي بدأت بنزين CH3 بيعطينا
+
+434
+00:36:57,610 --> 00:37:01,270
+البارا زاد ال ortho انا باهتم بالبارا ال ortho
+
+435
+00:37:01,270 --> 00:37:05,450
+عليا و الرأس طالع عندي بس انا اللي بدياهالبارا
+
+436
+00:37:05,450 --> 00:37:08,770
+product انا اللي بدي اياه البارا product الان
+
+437
+00:37:08,770 --> 00:37:12,810
+بإمكانكوا كل مرة تحللوه زي هيك بس بإمكانكوا صدقوني
+
+438
+00:37:12,810 --> 00:37:16,730
+بنظرة سريعة جدا تنتبهوا انكوا متيجوا تقولوا المثل
+
+439
+00:37:16,730 --> 00:37:23,250
+لوين بتودي اورتو بارا اذا بتطلعلي هذا بتودي بارا
+
+440
+00:37:23,250 --> 00:37:28,050
+اذا ببدأ بالمثل و بثني بهذه المجموعة لو بدأت بهذه
+
+441
+00:37:28,050 --> 00:37:32,850
+لوين بتودي مثل بتطلع الناتج لأ اذا ايش اول خطوة في
+
+442
+00:37:32,850 --> 00:37:41,060
+هذا المثلالمثل بعدين الاسيتل لزميك الترتيب هذا
+
+443
+00:37:41,060 --> 00:37:47,040
+المصاد بمشيش عندك مثلاشن ثم اسيتلاشن الان واحدة
+
+444
+00:37:47,040 --> 00:37:52,540
+منكم منتبهة تيجي تطلعلي على هذا المثل تقولي إيش
+
+445
+00:37:52,540 --> 00:37:59,770
+اللي بدي أبدأ فيه إذا بدأتي ب CH3 وين بتودي؟أورتو
+
+446
+00:37:59,770 --> 00:38:07,050
+أورتو بارا هتظبط معاه؟ لأ طب إذا بدأت بنيترو كان
+
+447
+00:38:07,050 --> 00:38:11,230
+بدأت بنيترو بتحط للميثل ع الميتر إذا هذا المركب
+
+448
+00:38:11,230 --> 00:38:18,810
+كيف لازم أبدأ فيه؟ أول إشي نيتريشن ثم مثليشن لو
+
+449
+00:38:18,810 --> 00:38:21,410
+عملت مثليشن ثم نيتريشن مابظبطش
+
+450
+00:38:24,620 --> 00:38:29,120
+لأنه لو حطيت الميثل وين هيود النيترو؟ هان أو هان
+
+451
+00:38:29,120 --> 00:38:32,060
+أو هان، مش هيجيبها هان لو حطيت النيترو وين هتحط
+
+452
+00:38:32,060 --> 00:38:37,700
+الميثل؟ على الميتا بالنسبة لها الآن
+
+453
+00:38:37,700 --> 00:38:42,840
+هذا المُركّب، اتطلع عليه، عليه مجموعتين، هذه
+
+454
+00:38:42,840 --> 00:38:50,320
+الـCOCH3 إلى وين بتوده؟ لأ، دي activating
+
+455
+00:38:50,320 --> 00:38:56,920
+metadirecting group، تذكروهاالـ COCH3 Deactivating
+
+456
+00:38:56,920 --> 00:39:03,100
+Ometa Directing Group بتودي على الميتا ال PR
+
+457
+00:39:03,100 --> 00:39:07,700
+Orthopara إذا لو كنت أنا هذه موجودة عندى حطيتها في
+
+458
+00:39:07,700 --> 00:39:11,460
+الخطوة الأولى بتجيب للبرومين في الخطوة الثانية على
+
+459
+00:39:11,460 --> 00:39:17,440
+الميتا إذا في الأول ال first stepأضيف هذه وبعدها
+
+460
+00:39:17,440 --> 00:39:21,340
+برومينيشن لو عملت العكس وضعت البروم البرومين بتودي
+
+461
+00:39:21,340 --> 00:39:25,540
+اورثو اورثو بارا مش حتى عطيني الناتجة اذا هذا
+
+462
+00:39:25,540 --> 00:39:33,160
+المثال اسيلاشن او اسيتليشن ثم برومينيشن واضح؟ اخر
+
+463
+00:39:33,160 --> 00:39:40,440
+مثال لو بدأت ب PR و اين بتودي ال PR اورثو بارا
+
+464
+00:39:40,440 --> 00:39:43,140
+طلعت المركبة لو بدأت ب نيترو
+
+465
+00:39:47,510 --> 00:39:53,650
+promination then nitration
+
+466
+00:39:53,650 --> 00:40:01,070
+واضح كيف بصير التفكير بهذه المسائل؟أخر .. أخر جزء
+
+467
+00:40:01,070 --> 00:40:05,650
+اللي بدنا نحكيه اليوم على بعض المركبات .. على بعض
+
+468
+00:40:05,650 --> 00:40:09,810
+المركبات اللي هم عبارة عن أكثر من حلقة بنزين مش
+
+469
+00:40:09,810 --> 00:40:13,870
+هنتعمق بس بنقولكوا لما بيكون في عندى أكثر من حلقة
+
+470
+00:40:13,870 --> 00:40:18,530
+بنزين بنسمي المركبات polycyclic aromatic compounds
+
+471
+00:40:18,530 --> 00:40:23,810
+منهالو كانوا two benzene rings بصير المراكب اسمه
+
+472
+00:40:23,810 --> 00:40:28,050
+نفثالين، لو كانوا تلاتة benzene rings بهذا الشكل
+
+473
+00:40:28,050 --> 00:40:35,070
+أنثراسين، لو كانوا تلاتة مش بخط مستقيمفنانثرين لو
+
+474
+00:40:35,070 --> 00:40:39,690
+كانوا أربعة بهذا الشكل اللي موجود عندك بيكونوا
+
+475
+00:40:39,690 --> 00:40:45,310
+بايرين و لو كانوا خمسة بهذا الشكل اللي موجود هنا
+
+476
+00:40:45,310 --> 00:40:54,210
+بيكونوا بنزو ا بايرين هذا ال بنزو ا بايرين من
+
+477
+00:40:54,210 --> 00:41:00,960
+المركبات الخطيرةمن المراكبات الخطيرة جدا لما الناس
+
+478
+00:41:00,960 --> 00:41:05,260
+بدخن السجائر نتيجة الحرق بتتكون aromatic compounds
+
+479
+00:41:05,260 --> 00:41:11,200
+polycyclic هذا من المراكبات اللي بتتكون من السجائر
+
+480
+00:41:11,200 --> 00:41:15,590
+من حرق السجائروهذا المركب بنقول عنه carcinogenic
+
+481
+00:41:15,590 --> 00:41:19,830
+معنى carcinogenic مسبب للسرطان بس بدكوا تنتبهوا
+
+482
+00:41:19,830 --> 00:41:23,950
+لشغلة .. بدكوا تنتبهوا لشغلة أنه في مركبات بنقول
+
+483
+00:41:23,950 --> 00:41:29,570
+ممكن تسبب سرطان وفي مركبات بنقول أسبوعين و التالت
+
+484
+00:41:29,570 --> 00:41:34,510
+بتعمل سرطان هذا مش من المركبات المزح مش من اللي
+
+485
+00:41:34,510 --> 00:41:40,030
+ممكن يسبب سرطان هذا من اللي أكيد بيعمل سرطانبس
+
+486
+00:41:40,030 --> 00:41:44,970
+طبعا، ليش بتأخر السرطان أحيانا عند المدخنين؟ لأنه
+
+487
+00:41:44,970 --> 00:41:49,070
+بتكون الكميات قليلة، بس هذا لو أخدوه بتركيز كبير،
+
+488
+00:41:49,070 --> 00:41:52,810
+أعطوه لأي بني آدم، بعد أسبوعين عنده سرطان، مافيش
+
+489
+00:41:52,810 --> 00:41:56,910
+إمكانية، بتأخر عند المدخنين لأنه في نائب بيطلعي
+
+490
+00:41:56,910 --> 00:42:01,610
+بتركيز قليل، cumulative، ماصيروا يصلوا، يعني ال
+
+491
+00:42:01,610 --> 00:42:09,670
+80، 90% بيعود يصلوا، واضح؟ لكنلو أخذ بتركيز كبير
+
+492
+00:42:09,670 --> 00:42:13,650
+كتجربة يعني عندنا فار بدنا نعمل عليه تجربة نخليه
+
+493
+00:42:13,650 --> 00:42:18,550
+يصير عنده سرطان لو أعطينا نيتروزو كمباونز أو بنزو
+
+494
+00:42:18,550 --> 00:42:22,530
+إيه بايرين و أنتم غامضين استنوا عليه أسبوعين و
+
+495
+00:42:22,530 --> 00:42:26,910
+بتشوفوا صار عنده إيش صار عنده سرطان هذا المركب
+
+496
+00:42:26,910 --> 00:42:33,470
+بالمناسبة عشان تنتبهوا بينتج كمان بشكل تحديد من
+
+497
+00:42:33,470 --> 00:42:39,260
+عملية حرق الكاكاوةالكاكاو إذا انحرج مش إذا داب
+
+498
+00:42:39,260 --> 00:42:44,120
+وعملناه مشروب إذا انحرج يعني لو بتعمله كيك أو ما
+
+499
+00:42:44,120 --> 00:42:48,120
+إلى ذلك بكاكاو و الكاكاو بنحرج بيطلع البنزو إيه
+
+500
+00:42:48,120 --> 00:42:53,600
+بايرين و هذا حقيقة هو اللي موجود .. انتبهوا معاه
+
+501
+00:42:53,600 --> 00:42:57,760
+هو اللي موجود في السجائر لما بيقولولكوا نكهة كذا و
+
+502
+00:42:57,760 --> 00:43:03,560
+نكهة كذا و حقيقة بيضيفوا على التبغ كاكاووحرق
+
+503
+00:43:03,560 --> 00:43:07,500
+الكاكاو عشان يطلع ريحة و الناس ينبسط و بتعرف هذه
+
+504
+00:43:07,500 --> 00:43:10,140
+الأشياء اللي بيظلوا ميضيفوها و الناس اللي بياخدوا
+
+505
+00:43:10,140 --> 00:43:13,980
+الشيشة المصايب هذه و بيسموهم عسلو أشياء حلوة كلها
+
+506
+00:43:13,980 --> 00:43:19,420
+بتطلع روائح هذا الكاكاو هو اللي بيطلع لنا إيش؟ الـ
+
+507
+00:43:19,420 --> 00:43:23,380
+Benzo-A-Pyrene هذا الكاكاو اللي بيطلع الـ Benzo-A
+
+508
+00:43:23,380 --> 00:43:28,040
+-Pyrene اللي هو بيسموه نكهة كذا و بيجي في الدعاية
+
+509
+00:43:28,040 --> 00:43:36,980
+الانتخابية معتز بهذا الكلامأخر شغلة بنحكيهااللي هي
+
+510
+00:43:36,980 --> 00:43:41,640
+الفوليرين يمكن مرة حكينالكوا عنه انه غير الـ
+
+511
+00:43:41,640 --> 00:43:45,260
+diamond وغير ال graphite من الالوتروبز تبعون
+
+512
+00:43:45,260 --> 00:43:50,040
+الكربون لقوا الالوتروبز عبارة عن ستين ذرة كربون
+
+513
+00:43:50,040 --> 00:43:55,280
+لما عملوا ال structure تبعهم لقوا عبارة عن
+
+514
+00:43:55,280 --> 00:44:01,500
+aromatic structure تقريبا عبارة عن كرة هذه الكرة
+
+515
+00:44:01,500 --> 00:44:08,390
+موجود فيها طبعاحلقات سداسية و حلقات خمسية و double
+
+516
+00:44:08,390 --> 00:44:14,870
+bonds فكأنها تعتبر polycyclic aromatic ring هى أحد
+
+517
+00:44:14,870 --> 00:44:18,950
+الصور اللى ممكن تكون موجودة للكربون غير ال mass
+
+518
+00:44:18,950 --> 00:44:24,130
+غير ال graphite بيحكوا عن ال C60 كرة الكربون ستين
+
+519
+00:44:24,130 --> 00:44:27,550
+هذه الكرة لو بتعدوا الطوبة بالزرقة اللى فيها ستين
+
+520
+00:44:27,550 --> 00:44:36,230
+واحدة واضح ستين طوبة زرقة موجود فيهابسموها
+
+521
+00:44:36,230 --> 00:44:40,570
+الفوليري النسبة الى الشخص اللى اكتشفها لاسمه Book
+
+522
+00:44:40,570 --> 00:44:44,810
+Monster Fowler Book Monster Fowler
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5eda53c781f2e69bdb27d0c688ae356c9d782ce0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_postprocess.srt
@@ -0,0 +1,1860 @@
+1
+00:00:08,200 --> 00:00:13,540
+بسم الله الرحمن الرحيم بنستكمل اليوم في موضوع الـ
+
+2
+00:00:13,540 --> 00:00:18,080
+aldehydes و الـ ketones طبعا سبق إن أكدنا إنه they
+
+3
+00:00:18,080 --> 00:00:23,240
+are reactive compounds with so many different
+
+4
+00:00:23,240 --> 00:00:29,230
+reactionsبشكل أساسي التفاعل الأساسي اللي حكينا عنه
+
+5
+00:00:29,230 --> 00:00:33,190
+للـ aldehydes والـ ketones كان تفاعل الـ addition
+
+6
+00:00:33,710 --> 00:00:36,650
+حتى الـ reduction لما اتعاملنا معاه في النهاية كان
+
+7
+00:00:36,650 --> 00:00:40,470
+هو عبارة عن عملية addition حتى ال reduction لما
+
+8
+00:00:40,470 --> 00:00:45,150
+اتعاملنا معاه كان في نهاية عملية addition الآن
+
+9
+00:00:45,150 --> 00:00:50,350
+بناخد تفاعل ال oxidation of aldehydes and ketones
+
+10
+00:00:50,350 --> 00:00:55,310
+طبعا ال oxidation له معاني كثيرة خلينا ناخد أبسط
+
+11
+00:00:55,310 --> 00:00:58,550
+معنى بس اللي بدنا نتعامل معاه اليوم أنه بده يزيد
+
+12
+00:00:58,550 --> 00:01:02,610
+عندناعدد الروابط مع الـ Oxygen
+
+13
+00:01:05,370 --> 00:01:09,810
+فبنلاحظ إحنا إنه في الـ aldehyde فيه اندهيدروجين
+
+14
+00:01:09,810 --> 00:01:14,490
+يمكن أن تستبدل ويجي مكانها أكسوجين بينما في الـ
+
+15
+00:01:14,490 --> 00:01:17,790
+Ketone هذا الكلام غير متوفر يعني المجموعات اللي
+
+16
+00:01:17,790 --> 00:01:21,910
+موجودة مجموعات R-groups وبناء على ذلك اللي حقيقة
+
+17
+00:01:21,910 --> 00:01:26,990
+بيصيرله أكسدة الالدهيدس اللي حقيقة بيصيرله أكسدة
+
+18
+00:01:26,990 --> 00:01:31,650
+الالدهيد فالالدهيد بيصيرله أكسدة سواء في وسط حمضي
+
+19
+00:01:31,650 --> 00:01:37,860
+أو في وسط قاعديبعوامل مثل الـ KMnO4 برمجانات
+
+20
+00:01:37,860 --> 00:01:42,100
+البوتاسيوم وغيرها اللي سبق أننا أخدناه وهذا
+
+21
+00:01:42,100 --> 00:01:46,460
+التفاعل كله سبق أخدناه حقيقة فبيعطينا الحامض أو
+
+22
+00:01:46,460 --> 00:01:51,380
+ملح الحامض اللي عنده الملح مجرد ما يضيف عليه H بلس
+
+23
+00:01:51,380 --> 00:01:55,360
+بيحصل على إيش؟ على الحامض يعني لو عملنا الأكسد في
+
+24
+00:01:55,360 --> 00:02:00,100
+الـ Basic Medium بيطلع عندنا R C double bond O O
+
+25
+00:02:00,100 --> 00:02:05,110
+minus غالبا بيكون معها مثلاالـ A plus إذا ضفنا
+
+26
+00:02:05,110 --> 00:02:10,990
+عليه H plus بنحصل على الحامض ففي النهاية أكسدت ال
+
+27
+00:02:10,990 --> 00:02:15,810
+الديهيدز أكسدت ال الديهيدز سواء ب basic medium أو
+
+28
+00:02:15,810 --> 00:02:20,470
+ب acidic medium في النهاية تؤدي إلى تكوين ال
+
+29
+00:02:20,470 --> 00:02:23,970
+carboxylic acid لاحظوا هنا في عندى رابطتين مع ال
+
+30
+00:02:23,970 --> 00:02:29,530
+oxygen هنا في عندىثلاثة روابط مع الأكسجين وهذا جزء
+
+31
+00:02:29,530 --> 00:02:33,770
+من مفهوم الأكسدة أننا نقول أن تمت عملية أكسدة لا
+
+32
+00:02:33,770 --> 00:02:37,750
+نريد القول في هذا التفاعل لأنه سبق أننا اتكلمنا
+
+33
+00:02:37,750 --> 00:02:42,630
+عنه عندما أخذنا الكمية تبع الكحولات سبق أننا
+
+34
+00:02:42,630 --> 00:02:49,720
+اتكلمنا عنه، واضح؟الآن بيجينا تفاعل كتير جدا مشهور
+
+35
+00:02:49,720 --> 00:02:55,040
+وكتير جدا مهم للـ aldehydes و الـ ketones هذا
+
+36
+00:02:55,040 --> 00:03:01,860
+التفاعل هو التفاعل مع المراكبات اللي فيها NH2 هذا
+
+37
+00:03:01,860 --> 00:03:07,240
+التفاعل هو التفاعل مع المراكبات اللي فيها NH2 أو
+
+38
+00:03:07,240 --> 00:03:13,820
+طبعا NH3 بتعرفوا أبسط واحد فيهم الأمونياالأمونيا
+
+39
+00:03:13,820 --> 00:03:18,520
+إيش ماخدة؟ NH3 وفيها زوج إلكترونات فيتمثل
+
+40
+00:03:18,520 --> 00:03:23,540
+الـNucleophile لأن لما بيصير عندي جزيئين أمونيا مع
+
+41
+00:03:23,540 --> 00:03:28,380
+بعض المركب اللي هو NH2 NH2 هذا المركب بنسميها
+
+42
+00:03:28,380 --> 00:03:34,470
+هيدرازينواضح فالهيدرازين هو عبارة عن جزيئين
+
+43
+00:03:34,470 --> 00:03:37,650
+أمونيات تحدوا مع بعض و فقدوا هيدروجين and H2O and
+
+44
+00:03:37,650 --> 00:03:43,230
+H2O هيدرازين الهيدرازين ممكن يكون substituted
+
+45
+00:03:43,230 --> 00:03:50,270
+هيدرازين يعني أشيل H منه و أحط فينل بيصير فينل
+
+46
+00:03:50,270 --> 00:03:57,070
+هيدرازين لو حطيت مثلمثل هيدرازيل، لو حطيت إثل إثل
+
+47
+00:03:57,070 --> 00:04:05,210
+هيدرازيل، واضح؟ الآن، لو حطيت مجموعة كبيرة شوية زي
+
+48
+00:04:05,210 --> 00:04:10,230
+هذه، هذه المجموعة، لو قلنا one, two, three, four,
+
+49
+00:04:10,470 --> 00:04:15,650
+five, six, two, four, dinitrophilin، كلها اسمها
+
+50
+00:04:15,650 --> 00:04:25,950
+هذه2,4-dinitrophenyl 2,4-dinitrophenylhydrazine
+
+51
+00:04:37,000 --> 00:04:41,240
+أحنا بنيجي نتطلع كيف كل هذه المُركّبات بتتفاعل،
+
+52
+00:04:41,240 --> 00:04:47,340
+يعني وين المحور الأساسي لتفاعلها، المحور الأساسي
+
+53
+00:04:47,340 --> 00:04:51,700
+لتفاعلها هو زوج الإلكترونات اللي موجود على
+
+54
+00:04:51,700 --> 00:04:53,800
+الـNitrogen
+
+55
+00:04:55,400 --> 00:04:59,380
+واضح؟ المحور الأساسي لتفاعلها هو زوج الإلكترونات
+
+56
+00:04:59,380 --> 00:05:03,160
+الموجودة عن نيتروجين وطبعا هذا بتدل على أن كل هذه
+
+57
+00:05:03,160 --> 00:05:09,180
+عبارة عن enucleophiles .. enucleophiles طالما أن
+
+58
+00:05:09,180 --> 00:05:14,240
+هذه عبارة عن enucleophiles طالما أن هذه عبارة عن
+
+59
+00:05:14,240 --> 00:05:20,430
+enucleophiles إذا إيش التفاعل اللي بتعمله؟in
+
+60
+00:05:20,430 --> 00:05:24,950
+eucleophilic addition يعني لو بده أجي أطلع هنا
+
+61
+00:05:24,950 --> 00:05:29,410
+بنفس المنطق أقول هاي زوج الإلكترونات اللي عندى هاي
+
+62
+00:05:29,410 --> 00:05:33,370
+زوج الإلكترونات اللي عندى بده يهاجم هنا و ال O إيش
+
+63
+00:05:33,370 --> 00:05:40,670
+بده تصير؟ OH واضح؟ نفس التفاعل ولا لأ؟ لو إجينا
+
+64
+00:05:40,670 --> 00:05:49,130
+نعملوا هذا الناتج بدنا نقول هي عندنا carbon R R OH
+
+65
+00:05:50,750 --> 00:05:58,210
+ان هتفقد اتش بالتأكيد ان اتش كمان ان اتش وهذه ال
+
+66
+00:05:58,210 --> 00:06:03,630
+residue او الجزء المترقب الان
+
+67
+00:06:03,630 --> 00:06:08,070
+لاحظوا هنا احنا ما زلنا بنتكلم على نفس الفكرة ال
+
+68
+00:06:08,070 --> 00:06:14,690
+nucleophilic addition هي نضيفت هذا اذا بتذكروا و
+
+69
+00:06:14,690 --> 00:06:23,050
+ال اه صارت ohإذا أنا هنا بحكي عن الـ Nucleophilic
+
+70
+00:06:23,050 --> 00:06:27,570
+addition ولا لأ؟ أه طيب هذا التفاعل الآن إيش
+
+71
+00:06:27,570 --> 00:06:32,410
+بيختلف عن التفاعلات السابقة؟ في خطوة الأولى لا
+
+72
+00:06:32,410 --> 00:06:39,150
+يختلف شيء لكن عادة الخطوة الأولى تتبع مباشرة بخطوة
+
+73
+00:06:39,150 --> 00:06:44,410
+تانية إضافية في الخطوة التانية الإضافية بتم حدث
+
+74
+00:06:44,410 --> 00:06:48,870
+الـ OH هذه مع ال H اللى موجودة على الآن H و بعمله
+
+75
+00:06:48,870 --> 00:06:56,630
+double bondواضح؟ فبصير عندى عملية مركبة من عمليتين
+
+76
+00:06:56,630 --> 00:07:02,170
+العملية الأولى اللى احنا متعودين عليها ال addition
+
+77
+00:07:02,170 --> 00:07:07,950
+والعملية التانية عملية حدث جزاء مية elimination
+
+78
+00:07:07,950 --> 00:07:15,470
+ولذلك التفاعل مع هدول المركبات حقيقة بتنفي خطوتين
+
+79
+00:07:15,470 --> 00:07:21,240
+الخطوتين شو هما addition و eliminationهذا الكلام
+
+80
+00:07:21,240 --> 00:07:25,380
+addition و elimination لحد ما أصل للنتج النهائي
+
+81
+00:07:25,380 --> 00:07:29,840
+لحد ما أصل للنتج النهائي إذا أنا طلبت منكم تفصلوا
+
+82
+00:07:29,840 --> 00:07:33,760
+لي شو الكلام اللي بيصير لكن لو أنا باجي بسألكم في
+
+83
+00:07:33,760 --> 00:07:39,540
+امتحان أعطوني الجواب بسرعة و خلال ثانية أسهل طريقة
+
+84
+00:07:39,540 --> 00:07:43,420
+عشان تعطوا الجواب بسرعة و خلال ثانية إذا بنجيبلكم
+
+85
+00:07:43,420 --> 00:07:50,550
+تفعلوا anh2 من هدولة مع cw.oتجي تمسكوا الـ H2 مع
+
+86
+00:07:50,550 --> 00:07:57,610
+الـ O تشطبوهم و تمدوا الـ double bond واضح؟ حطوهم
+
+87
+00:07:57,610 --> 00:08:02,910
+جنب بعض الـ C double bond O جنب الـ N H2 واخدوا
+
+88
+00:08:02,910 --> 00:08:09,550
+H2O مياه فيها واضح؟
+
+89
+00:08:09,550 --> 00:08:13,250
+مافيش أسهل منه يعني كيف أكتب ناتج تفاعل
+
+90
+00:08:13,250 --> 00:08:18,590
+الديهيدوكيتون مع أي واحد من هدولةبدي أشيل الـ H2
+
+91
+00:08:18,590 --> 00:08:23,590
+مع الـ O و أعمل مكانهم double bond لكن بكون عارف
+
+92
+00:08:23,590 --> 00:08:28,830
+أن هذا الكلام نتاج خطوتين نتاج عملية addition
+
+93
+00:08:28,830 --> 00:08:34,870
+followed by elimination الآن في معظم الحلات احنا
+
+94
+00:08:34,870 --> 00:08:38,130
+بنقولكوا اكتبولنا الناتج الآن لما نقول اكتبوا
+
+95
+00:08:38,130 --> 00:08:41,650
+الناتج بديش أشوف الكلام هذا اللي في الوسط عطول
+
+96
+00:08:41,650 --> 00:08:48,200
+بتحطولي إيش؟ C double bond Nع طول بدنا نحط الـ C
+
+97
+00:08:48,200 --> 00:08:52,460
+double bond أن الناتج النهائي بحط الـ H2 جنب الـ O
+
+98
+00:08:52,460 --> 00:08:58,620
+وبشيلهم مع بعض هذه الطريقة العملية لكتابة الناتج
+
+99
+00:08:58,620 --> 00:09:04,800
+هذه العملية مركبة من عمليتين عملية addition وعملية
+
+100
+00:09:04,800 --> 00:09:11,660
+elimination إضافة وحدث واضح؟ وهذه الحقيقة من
+
+101
+00:09:11,660 --> 00:09:17,390
+العمليات الهامة أو المهمة والتي تتكررالان لاحظوا
+
+102
+00:09:17,390 --> 00:09:22,690
+هنا بنعطي نوعا ما تعميم عام أنه لو عندي nh2 متصلة
+
+103
+00:09:22,690 --> 00:09:29,130
+مع إيش مكان يكون يعني صرت جاي ال X أنا هال X هذه
+
+104
+00:09:29,130 --> 00:09:33,630
+ممكن تكون nh2 التانية زي الأمثلة اللي شوفناها ممكن
+
+105
+00:09:33,630 --> 00:09:40,590
+تكون nh-phenyl ممكن تكون R أمين يعني يعني مثلا
+
+106
+00:09:40,590 --> 00:09:46,950
+تكون CH2 أو تكون phenyl nh2 أنا لين ممكن تكون OHفي
+
+107
+00:09:46,950 --> 00:09:51,650
+كل الأحوال دائماً لما تيجي الـNH2 مع الـC double
+
+108
+00:09:51,650 --> 00:09:56,290
+bond O تبعت الألديهيد والكيتون دي ربالكوا لإنه بعد
+
+109
+00:09:56,290 --> 00:09:58,950
+هيك مع الـC double bond O تبعت الأحماض
+
+110
+00:09:58,950 --> 00:10:03,510
+الكربوكسيلية بصير تفاعل تاني أنا بحكي عن ألديهيد
+
+111
+00:10:03,510 --> 00:10:08,030
+وكيتون بدي أحدث الـhydrogens بتنتهي مع الـoxygen و
+
+112
+00:10:08,030 --> 00:10:13,170
+أعمل double bond هاي هنا الكلام واضح ولا أسهل منه
+
+113
+00:10:13,170 --> 00:10:19,110
+كمان هاي مع الـhydrazineشيلنا الـ H2O و كل إيش
+
+114
+00:10:19,110 --> 00:10:22,990
+أخدناه زي ما هو و عملنا double bond مع الفين
+
+115
+00:10:22,990 --> 00:10:30,470
+الهيدرازين شيلنا الـ H2O و عملنا double bond،
+
+116
+00:10:30,470 --> 00:10:35,990
+واضح؟ الآن، هدول عن المُركّبات إيش بنسميهم اللي
+
+117
+00:10:35,990 --> 00:10:43,340
+بينتجوا عندنا نفترض هذا المُركّب كانCH3 CH3 شو
+
+118
+00:10:43,340 --> 00:10:50,760
+بيكون اسمه أسيتون أسيتون طب الناتج أسيتون زائد هذا
+
+119
+00:10:50,760 --> 00:10:59,680
+ال NH2 NH2 هيدرازين إيش الناتج بيكون اسمه أسيتون
+
+120
+00:10:59,680 --> 00:11:08,480
+هيدرازون بيبطل هيدرازين CH3 CH3 بنكتب اسم ال
+
+121
+00:11:08,480 --> 00:11:11,180
+ketone في الأول و بعدين
+
+122
+00:11:14,180 --> 00:11:17,620
+هيدرازون، فبصير كأنه عندي قاعدة عامة، القاعدة
+
+123
+00:11:17,620 --> 00:11:22,820
+العامة بتقول إن الـhydrazines react with aldehydes
+
+124
+00:11:22,820 --> 00:11:26,900
+and ketones producing hydrazones، شو هما
+
+125
+00:11:26,900 --> 00:11:29,940
+الـhydrazones المركبات اللي فيهم C double bond N
+
+126
+00:11:29,940 --> 00:11:34,440
+and H2و، هذه عائلة الإيش؟ الـhydrazones، C double
+
+127
+00:11:34,440 --> 00:11:36,300
+bond N، N تانية
+
+128
+00:11:44,500 --> 00:11:47,680
+يعني ليش بننسب إله؟ لما كان فيه مجموعة فينيل وكان
+
+129
+00:11:47,680 --> 00:11:51,120
+مجموعة نايترو، في النهاية تسبنا إله، جبل يعني، جبل
+
+130
+00:11:51,120 --> 00:11:54,280
+متخدر. خليني أشوف الأمثلة التانية، مش فاهم سؤالك،
+
+131
+00:11:54,280 --> 00:11:57,960
+أنا مش واضح. لو افترضنا هذا أسيتون اتفاعل مع فين
+
+132
+00:11:57,960 --> 00:12:01,520
+الهيدرازين، شو هسميه؟ الناتج.
+
+133
+00:12:04,140 --> 00:12:08,220
+لو هذا أسيتون مثل ومثل، شو هكون اسم هذا الناتج؟
+
+134
+00:12:08,220 --> 00:12:16,480
+أسيتونفينيل هيدرازون لو حطينا الـdinitro أسيتون
+
+135
+00:12:16,480 --> 00:12:29,220
+two four dinitro فينيل هيدرازون إيش المشكلة؟
+
+136
+00:12:29,220 --> 00:12:34,090
+هيك اسمهدائما لما تتغلبوا في شغلة أسماء و يقعد
+
+137
+00:12:34,090 --> 00:12:37,430
+بالك و يروح شماله يمينه شره و غرب تتذكروا أن
+
+138
+00:12:37,430 --> 00:12:41,210
+القرآن الكريم بيقول وعلم آدم الأسماء كلها ثم عرضهم
+
+139
+00:12:41,210 --> 00:12:44,430
+على الملائكة فقال أنبئوني بأسماء هؤلاء إن كنتم
+
+140
+00:12:44,430 --> 00:12:51,030
+صادقين واضح؟ فقال أنبئوني بأسماء هؤلاء إن كنتم
+
+141
+00:12:51,030 --> 00:12:54,600
+صادقين بالتسهيلبدناش ندخل في الهمزات كيف لما
+
+142
+00:12:54,600 --> 00:12:59,100
+بلتقيهم في كتير أشياء هيك اتسمت و اتسمية زي ما
+
+143
+00:12:59,100 --> 00:13:03,440
+حكيتلكوا أنا سابقا بدخل فيها مرات عوامل تاريخية و
+
+144
+00:13:03,440 --> 00:13:08,240
+مرات عوامل اشتقاقية، مظبوط ولا لا؟ common names
+
+145
+00:13:08,240 --> 00:13:14,480
+وغيره وغيراته، الآن لو افترضنا اللي كان عندنا NH2
+
+146
+00:13:14,480 --> 00:13:21,640
+مع OHهذا المُركّب بنسميه Hydroxyl Amine الـ NH2
+
+147
+00:13:21,640 --> 00:13:26,920
+OH2 شو بيسموه؟ Hydroxyl شايفين الـ Hydroxyl و الـ
+
+148
+00:13:26,920 --> 00:13:34,440
+NH2 Amine فبصير Hydroxyl Amine الأن لو اتفعل مع
+
+149
+00:13:34,440 --> 00:13:38,580
+كيتون نفترض أسيتون أسيتوفينون سايكلوهيكسانون
+
+150
+00:13:38,580 --> 00:13:44,830
+بنتانون أي الناتج اللي بيطلع شو بنسميه؟خلّينا نحط
+
+151
+00:13:44,830 --> 00:13:48,310
+هدولة مثيل وفينيل، إيش المركب اللي فيه مثيل
+
+152
+00:13:48,310 --> 00:13:56,790
+وفينيل؟ هنا فينيل وهنا CH3، فينيل سيضاو البندق و
+
+153
+00:13:56,790 --> 00:14:03,790
+CH3، أخدتوله لما تقلبته أسيتوفينون،
+
+154
+00:14:03,790 --> 00:14:10,140
+أسيتوفينون الكيتون هذا إيش اسمه؟أسيتوفينون
+
+155
+00:14:10,140 --> 00:14:15,540
+أسيتوفينون
+
+156
+00:14:15,540 --> 00:14:25,900
+أكزيم أسيتوفينون
+
+157
+00:14:25,900 --> 00:14:29,060
+أكزيم
+
+158
+00:14:29,060 --> 00:14:33,360
+أسيتوفينون
+
+159
+00:14:33,360 --> 00:14:37,060
+أكزيم أسيتوفينون أكزيم
+
+160
+00:14:40,040 --> 00:14:45,180
+أسيتوفينون أكزيم فال أكزيم لما نقول عائلة أكزيم
+
+161
+00:14:45,180 --> 00:14:51,080
+مجرد ما تشوفه مركب C double bond N OH هذا أكزيم
+
+162
+00:14:51,080 --> 00:14:55,760
+مجرد ما تشوفه مركب C double bond N N تانية
+
+163
+00:14:55,760 --> 00:15:00,820
+هيدرازون الأن لو كان NH2 بيكون simple hydrazone NH
+
+164
+00:15:00,820 --> 00:15:04,600
+phenylفين الهيدرازون؟ مثل هيدرازون؟ two-four
+
+165
+00:15:04,600 --> 00:15:07,320
+-dinitro؟ فين الهيدرازون؟ ماعرفش إذا في المختبر
+
+166
+00:15:07,320 --> 00:15:14,400
+صرتوا واصلي لتجربة الالديهيدس والكيتونز ولا لسه؟
+
+167
+00:15:14,400 --> 00:15:17,660
+أنتوا فاصل تاني ماخدين المادة؟ إذا
+
+168
+00:15:22,550 --> 00:15:27,570
+انتبهوا معي في المشتقات .. في المشتقات تبعت اللي
+
+169
+00:15:27,570 --> 00:15:32,730
+هي الأن H2O مار عليكم الهيدرازين مار عليكم
+
+170
+00:15:32,730 --> 00:15:37,670
+الهيدروكس الأمين ونفس التفاعل اللي هو تفاعل فقد
+
+171
+00:15:37,670 --> 00:15:40,210
+الماء اللي هي عملية ال addition elimination
+
+172
+00:15:40,210 --> 00:15:49,440
+وبيجيكوا كمان أشياء تانية لكن كلها نفس الفكرةاللي
+
+173
+00:15:49,440 --> 00:15:57,260
+هي formation of امين امين امين الآن المركبات
+
+174
+00:15:57,260 --> 00:16:05,700
+الامين لما بيكون عنده مركب RNH2 اي RNH2 بنسمي
+
+175
+00:16:05,700 --> 00:16:10,480
+المركب ايش امين هذه عائلة اللي هندرسها في الفصل ال
+
+176
+00:16:10,480 --> 00:16:19,100
+11 كل عائلة ال Rالـ H2 هذه عائلة الـ Amines وهذه
+
+177
+00:16:19,100 --> 00:16:22,760
+بناخد عليها فصل كامل إيش اسم هذه العائلة؟ Amine
+
+178
+00:16:22,760 --> 00:16:27,900
+يعني لو كانت هذه مثلا مثل .. شو بيصير اسم المركب؟
+
+179
+00:16:27,900 --> 00:16:33,460
+مثل Amine and so on الأن لما تيجي تتفاعل هذه مع
+
+180
+00:16:33,460 --> 00:16:40,960
+الـ C double bond O شو هتعمل؟ نفس الفكرة تماما
+
+181
+00:16:40,960 --> 00:16:50,510
+هتيجي الـ H2و يحذفه على شكل جزء ميّه الـ
+
+182
+00:16:50,510 --> 00:16:58,250
+elimination process ويصير عندنا R N double bond C
+
+183
+00:16:58,250 --> 00:17:03,570
+الـ C double bond N المتصل بالـ R كعائلة بنسميها
+
+184
+00:17:03,570 --> 00:17:08,650
+عائلة الامين فالامين
+
+185
+00:17:08,650 --> 00:17:17,320
+بيعطينا ايش؟ امينلاحظوا الأن أنتوا من أنواع الـNH2
+
+186
+00:17:17,320 --> 00:17:23,140
+في النهاية كلهم NH2 نبدأ نلخص NH2 خلّينا نقول X
+
+187
+00:17:23,140 --> 00:17:28,180
+التفاعل، مظبوط ولا لأ؟ زاد الديهيد أو الكيتون لما
+
+188
+00:17:28,180 --> 00:17:37,980
+كانت ال X هذه NH2 NH2 كان .. خلّينا نكتب الناتج،
+
+189
+00:17:37,980 --> 00:17:39,900
+زي هيك، شو كان الناتج؟
+
+190
+00:17:45,520 --> 00:17:50,280
+هيدرازون هيدرازون لما كان يكون عندك سيطة بالبند N
+
+191
+00:17:50,280 --> 00:17:57,300
+O H شو الناتج؟ أكزين لما بيصير عندكوا سيطة بالبند
+
+192
+00:17:57,300 --> 00:18:04,420
+M R امين واضح؟
+
+193
+00:18:04,420 --> 00:18:08,980
+إيش اللي كان يعطيني الهيدرازون؟
+
+194
+00:18:08,980 --> 00:18:11,260
+الهيدرازين
+
+195
+00:18:12,640 --> 00:18:17,100
+الهيدرازين لما فعلوا مع الدايدو كيتون شو بيعطيني؟
+
+196
+00:18:17,100 --> 00:18:25,860
+هيدرازون شو اللي بيعطيلي الأكزين؟ هيدروكسل أمين
+
+197
+00:18:25,860 --> 00:18:29,700
+إذا الهيدروكسل أمين بيعطي أكزين شو اللي بيعطي
+
+198
+00:18:29,700 --> 00:18:39,560
+الامين؟ الامينواضح؟ إذا الهيدرازين بيعطي هيدرازون،
+
+199
+00:18:39,560 --> 00:18:46,040
+الهيدروكس الأمين بيعطي أكزين، الأمين بيعطي إمين،
+
+200
+00:18:46,040 --> 00:18:52,780
+في غيرهم؟ لا الله كريم فيه كمان، على أي حالهذه
+
+201
+00:18:52,780 --> 00:18:57,740
+المُركّبات اللي فيها C double bond N متصلة مع R
+
+202
+00:18:57,740 --> 00:19:02,620
+هنا مرات بتاخد كمان اسم تاني بيسموها shift bases
+
+203
+00:19:02,620 --> 00:19:07,300
+قواعد shift بالنسبة للعالم shift هم نفسه بالإمينز
+
+204
+00:19:07,300 --> 00:19:10,720
+بس لو سمعتوا اسم shift base اللي هي نفس هذه
+
+205
+00:19:10,720 --> 00:19:16,100
+المُركّبات الإمينز اللي فيها C double bond N واضح؟
+
+206
+00:19:16,100 --> 00:19:22,980
+الآن نشوف من هذه الأمثلة اللي موجودة عندناأي مثال
+
+207
+00:19:22,980 --> 00:19:30,700
+اللي أخدنا زيه هان هيندي كيتون مع RNH2 إذا كيتون
+
+208
+00:19:30,700 --> 00:19:38,900
+زائد امين شو هيعطيلي امين امين ممتاز هيندي كيتون
+
+209
+00:19:38,900 --> 00:19:46,160
+زائد هيدروكسل امينماذا يعطيني؟ اكزين هي أنا عندي
+
+210
+00:19:46,160 --> 00:19:50,740
+كيتون زائد سيمبل هيدرازين سيمبل يعني انا انا انا
+
+211
+00:19:50,740 --> 00:19:52,320
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+212
+00:19:52,320 --> 00:19:52,580
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+213
+00:19:52,580 --> 00:19:53,580
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+214
+00:19:53,580 --> 00:19:53,760
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+215
+00:19:53,760 --> 00:19:55,480
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+216
+00:19:55,480 --> 00:20:08,640
+انا انا انا انا انا انا
+
+217
+00:20:08,640 --> 00:20:15,410
+اناهذه الأخيرة ما مرتش عليكم لسه ايش هو هذا اخر
+
+218
+00:20:15,410 --> 00:20:24,050
+جزء موجود عندى N-H2C-O-N-H-N-H2 طلع عليها مرة
+
+219
+00:20:24,050 --> 00:20:36,630
+تانية نكبرها شوية C-O-N-H2-N-H2-N-H2 هذا المركب
+
+220
+00:20:36,630 --> 00:20:45,300
+بنسميه semi carbazideهذا المُركّب بيسميه
+
+221
+00:20:45,300 --> 00:20:49,760
+سيمي Carbazai اللي هي صيغة بالبنط O من جهة متصلة
+
+222
+00:20:49,760 --> 00:20:56,960
+بـ NH2 وحدة ومن جهة متصلة بـ NH NH2 الآن لو إيجينا
+
+223
+00:20:56,960 --> 00:21:00,020
+قولنا هذه من وين بدها تتفاعل بدها تتفاعل من الـ
+
+224
+00:21:00,020 --> 00:21:02,820
+NH2 هتيجي تتطلع كم NH2
+
+225
+00:21:09,020 --> 00:21:13,820
+هل يا تورا في إمكانية من الجهتين ولا التفاعل بيتم
+
+226
+00:21:13,820 --> 00:21:21,020
+فقط من جهة واحدة التفاعل فقط يتم من جهة واحدة اللي
+
+227
+00:21:21,020 --> 00:21:26,020
+هي جهة ال hydrazine اللي هي جهة ال NH NH2 من هنا
+
+228
+00:21:26,020 --> 00:21:31,500
+مابصيرش التفاعل إطلاقا واضح؟
+
+229
+00:21:32,300 --> 00:21:38,960
+هذه نسميها أميد نيتروجين هناخد عنها شوية بقى في
+
+230
+00:21:38,960 --> 00:21:42,900
+شبط 10 هذه غير متفاعلة Unreactive بالمرة
+
+231
+00:22:04,260 --> 00:22:08,320
+أن أتش ان أتش تو فعله مع هادي و حذف الأكسجين و
+
+232
+00:22:08,320 --> 00:22:13,620
+النادج عمل c double bond n ان أتش c double bond o
+
+233
+00:22:13,620 --> 00:22:18,440
+ان أتش تو دلت يمكن كان رايحكوا شوية لو انه كان
+
+234
+00:22:18,440 --> 00:22:23,840
+عاكس واحدة من هدولمش مشكلة، بأي طريقة يُكتب
+
+235
+00:22:23,840 --> 00:22:28,640
+التفاعل وين بيتم على الـ Amid Nitrogen ولا على الـ
+
+236
+00:22:28,640 --> 00:22:32,460
+Hydrazine Nitrogen؟ على الـ Hydrazine نحنا دائما و
+
+237
+00:22:32,460 --> 00:22:36,200
+أبداً لما نجيبلكوا سؤال في الامتحان، بنحطه قريب
+
+238
+00:22:36,200 --> 00:22:40,820
+على الـ Amid Nitrogen عشان نشوف كوكبكوا تفعلوه على
+
+239
+00:22:40,820 --> 00:22:44,940
+التانية مش على طول تقولوا أنا H2GammaC double bond
+
+240
+00:22:44,940 --> 00:22:50,910
+O، نحذف ميهواضح؟ يعني هنا كان كتير أي واحدة بتتيجي
+
+241
+00:22:50,910 --> 00:22:56,090
+تاخد هدولة مع بعض وتحذفهم وتعمل double bond احنا
+
+242
+00:22:56,090 --> 00:23:01,070
+بيقول مابتفعلش على ال nitrogen اللي مباشرة جنب ال
+
+243
+00:23:01,070 --> 00:23:03,990
+C double bond او بتفعل على التانية اللي هي ال
+
+244
+00:23:03,990 --> 00:23:07,710
+hydrogen ال nitrogen الآن هذا semi-carbazide شو
+
+245
+00:23:07,710 --> 00:23:13,280
+بيعطيني؟سيمي كربازون، يعني لو هذا كان مثلا أسيتون،
+
+246
+00:23:13,280 --> 00:23:19,940
+شو المُركّب الناتج؟ أسيتون سيمي كربازون، إذن هنا
+
+247
+00:23:19,940 --> 00:23:25,360
+كمان غير الأمين إيمين، بتكون تضيفوا عندكم تحت،
+
+248
+00:23:25,360 --> 00:23:30,800
+سيمي كربازايد، سيمي كربازون، كل هذه عبارة عن
+
+249
+00:23:30,800 --> 00:23:37,830
+مشتقات الألديهيد والكيتون مع الـNH2إذا الـ NH2
+
+250
+00:23:37,830 --> 00:23:41,350
+موجودة على أنواع مختلفة موجودة على شكل أمين على
+
+251
+00:23:41,350 --> 00:23:46,850
+شكل هيدرازين على شكل أكزيم على شكل سيمي كربازايد
+
+252
+00:23:46,850 --> 00:23:53,570
+بتعطينا هيدرازون أكزيم أمين سيمي كربازون وأسهل
+
+253
+00:23:53,570 --> 00:23:57,130
+أشياء تطبقوه وتتمنوا أن يجيكوا سؤال عليه في
+
+254
+00:23:57,130 --> 00:24:03,390
+الامتحانات لأن كله عبارة عن أنكوا تحذفوا مياهكله
+
+255
+00:24:03,390 --> 00:24:07,210
+عبارة عن أنكوا تحذفوا مياه مافيش غلبة غير بحالة
+
+256
+00:24:07,210 --> 00:24:10,910
+واحدة في الـSemi-Carb إزايد تعرفوا من أي نيتروجين
+
+257
+00:24:10,910 --> 00:24:15,930
+التفاعل بده يتم وانا بعتقد أنه وضحناها بما فيه
+
+258
+00:24:15,930 --> 00:24:16,470
+التفاعل
+
+259
+00:24:34,870 --> 00:24:43,310
+بنجي لظاهرة جديدة حقيقة سبق إنها مرت علينا، اللي
+
+260
+00:24:43,310 --> 00:24:48,810
+هي الظاهرات الـ keto-enol-tautomerism، وين مرت
+
+261
+00:24:48,810 --> 00:24:53,560
+علينا إذا بتذكروا هذه الظاهرة؟لما كنا نفعل الـ
+
+262
+00:24:53,560 --> 00:24:57,540
+triple bond و نضيف عليهم ميه من خلال الـ mercuric
+
+263
+00:24:57,540 --> 00:25:01,920
+acetate و ما إلى ذلك كان يتكون عندى in or كنت أضيف
+
+264
+00:25:01,920 --> 00:25:06,980
+H و OH كنا دائما نقولكم ال in all هي in يعني
+
+265
+00:25:06,980 --> 00:25:11,560
+double bond all ألكمل ف in all يعني فيها double
+
+266
+00:25:11,560 --> 00:25:15,760
+bond و فيها ألكمل بتحول إلى ال keto form إيش هذه
+
+267
+00:25:15,760 --> 00:25:19,880
+العملية بيصير فيها حقيقة بيصير فيها نقل إلكترونات
+
+268
+00:25:19,880 --> 00:25:25,310
+و نقل بروتوناتيعني الشحنة بتتحرك و البروتونات
+
+269
+00:25:25,310 --> 00:25:29,610
+بتتحرك لأن هذا البروتون هذا البروتون وين بده ينقل؟
+
+270
+00:25:29,610 --> 00:25:34,650
+بده يجي على ال CH2 و هذا ال double bond بده تيجي
+
+271
+00:25:34,650 --> 00:25:39,330
+هنا فعندي عملية نقل بروتونات و نقل شحنات هذه
+
+272
+00:25:39,330 --> 00:25:44,170
+العملية سمنها احنا Tautomerism وقولنا السهم تبع ال
+
+273
+00:25:44,170 --> 00:25:48,610
+Tautomerism هوالـ double arrows it is an
+
+274
+00:25:48,610 --> 00:25:53,570
+equilibrium process إفراجناها عن ال resonance ال
+
+275
+00:25:53,570 --> 00:25:59,250
+resonance كان بس نقل شحنات أو إلكترونات و كنا
+
+276
+00:25:59,250 --> 00:26:07,130
+بنستعمله أي سهم ال ذكر ال
+
+277
+00:26:07,130 --> 00:26:10,590
+resonance زي البنزين مثلا لما كنا نعمل فيه
+
+278
+00:26:10,590 --> 00:26:12,930
+resonance نقل الإلكترونات
+
+279
+00:26:15,920 --> 00:26:20,420
+double headed arrows هذا اسمه double headed arrows
+
+280
+00:26:20,420 --> 00:26:24,980
+يعني سهم أبو راسين هذا اسمهم double arrows يعني
+
+281
+00:26:24,980 --> 00:26:29,580
+سهمين double arrow و double headed arrow مرات
+
+282
+00:26:29,580 --> 00:26:33,140
+البعض منكم بيروح بحفظ نص الكلام و يوم ما ييجي نسأل
+
+283
+00:26:33,140 --> 00:26:39,020
+في الموضوع مخابط هذا ايش اسمه double headed يعني
+
+284
+00:26:39,020 --> 00:26:44,760
+كام راس له يعني هذا صيني زي التنين في غير التنين
+
+285
+00:26:44,760 --> 00:26:49,430
+له راسينمش كان التنين يكونوا يلو راسين يطيروا سمو
+
+286
+00:26:49,430 --> 00:26:52,990
+و بتقطع راس و بتضرب راس التاني اه هذا أسهم أبو
+
+287
+00:26:52,990 --> 00:26:57,150
+راسين البلد فيها كتير أبو راسين و أبو عجلين و تلو
+
+288
+00:26:57,150 --> 00:27:05,590
+كل إشي اه و هذا إيش اسمه double أرز هذا سهمين اللي
+
+289
+00:27:05,590 --> 00:27:10,690
+هو equilibrium أرز اللي هي أسهم الاتزان
+
+290
+00:27:11,910 --> 00:27:16,070
+أسهم الاتزان، واضح فالتوتمريزم is an equilibrium
+
+291
+00:27:16,070 --> 00:27:19,490
+process
+
+292
+00:27:19,490 --> 00:27:24,230
+which is indicated by double arrows، no by double
+
+293
+00:27:24,230 --> 00:27:28,410
+arrows، resonance is indicated by double headed
+
+294
+00:27:28,410 --> 00:27:32,550
+arrows، هاي سؤال انصحه غلط، التوتمريزم is
+
+295
+00:27:32,550 --> 00:27:37,680
+indicated byDouble arrows. Resonance is indicated
+
+296
+00:27:37,680 --> 00:27:41,700
+by double headed arrows. In resonance there is
+
+297
+00:27:41,700 --> 00:27:45,620
+only charge transfer or electron transfer.
+
+298
+00:27:46,260 --> 00:27:51,200
+However, in automerism we have transfer of charge
+
+299
+00:27:51,200 --> 00:27:54,720
+and atoms mainly protons.
+
+300
+00:27:57,020 --> 00:28:02,080
+هذه العملية مرت معنا لكن احنا هنا بنذكركوا فيها
+
+301
+00:28:02,080 --> 00:28:04,680
+سبق انه مرت
+
+302
+00:28:08,670 --> 00:28:15,830
+الآن بنجي لنقطة مهمة كتير في كيميا الألديهيدس
+
+303
+00:28:15,830 --> 00:28:22,570
+والكيتونز وبتعمل نوعا ما شغلة جديدة في تفاعلاتهم
+
+304
+00:28:22,570 --> 00:28:27,070
+اللي هي بنسميها ال acidity of alpha hydrogen
+
+305
+00:28:27,070 --> 00:28:32,850
+انتبهوا معي موضوع ال acidity ال acidity بشكل عام
+
+306
+00:28:32,850 --> 00:28:36,830
+لو أجينا نذكر فيه إيش كان ال acid؟
+
+307
+00:28:39,290 --> 00:28:46,530
+حسب خلّيني أقول الوري برونستيد definition اللي
+
+308
+00:28:46,530 --> 00:28:52,730
+بيفقد بروتون اتش بلس ال acid is the one that loses
+
+309
+00:28:52,730 --> 00:29:01,930
+اتش بلس مش هذا بروتون دونر بيفقد اتش بلس و ال base
+
+310
+00:29:04,240 --> 00:29:09,560
+Proton Acceptor الأن أنواع الـ Assets .. أنواع الـ
+
+311
+00:29:09,560 --> 00:29:13,620
+Assets كتيرة أسهل
+
+312
+00:29:13,620 --> 00:29:20,220
+إشي أنه يكون عند حامض أنه الـ H Plus لما تفقد زي
+
+313
+00:29:20,220 --> 00:29:25,940
+ما سبق اتكلمت عنه بدا تترك مكانها شحنة سالبة
+
+314
+00:29:25,940 --> 00:29:31,710
+هالشحنة السالبة بدا يكون في قدرةعلى حملها و لذلك
+
+315
+00:29:31,710 --> 00:29:36,070
+أفضل شيء الأحماط الكربوكسيلية لما تفقد ال H بيصير
+
+316
+00:29:36,070 --> 00:29:42,810
+عندك R C double bond O O minus هذه فقدت H مظبوط
+
+317
+00:29:42,810 --> 00:29:46,810
+ولا لأ؟ ليش هذه كانت ثابتة كتير؟ لأنها بتعمل
+
+318
+00:29:46,810 --> 00:29:50,930
+resonance هذه بتتحرك هنا و هذه بتتحرك هنا فشحنة
+
+319
+00:29:50,930 --> 00:29:55,230
+سالمة سهل التعامل معها هذا في الأحماط الكربوكسيلية
+
+320
+00:29:55,230 --> 00:30:00,970
+أخدنا أنه يمكن ال H أن تفقد من إيش كمان؟من ال
+
+321
+00:30:00,970 --> 00:30:06,070
+alcohols بس من ال alcohols شو بيكونوا أقوى ولا
+
+322
+00:30:06,070 --> 00:30:11,030
+أضعف من الأحماض الكربوكسية؟ أضعف لإيش؟ لأنه هنا
+
+323
+00:30:11,030 --> 00:30:16,790
+مافيش شيء .. resonance الحمض
+
+324
+00:30:16,790 --> 00:30:21,150
+الكربوكسيلي قوي لإيش؟ لأنه يصير minus ب resonance
+
+325
+00:30:21,150 --> 00:30:26,670
+ال alcohol is a weak acid قلنا زي و زي الميه لكن
+
+326
+00:30:26,670 --> 00:30:31,280
+ال alcohol فقد ال protonوالحمض الكربوكسيلي فقد
+
+327
+00:30:31,280 --> 00:30:38,780
+بروتون مش هذا في الأساس كان RCH2OH في وجود ال base
+
+328
+00:30:38,780 --> 00:30:47,180
+فقط بروتون وهذا RCH2OH في وجود ال base برضه فقط
+
+329
+00:30:47,180 --> 00:30:52,680
+بروتون الآن هدولة أخدناهم أخدنا كمان نوع من ال ..
+
+330
+00:30:52,680 --> 00:30:55,860
+من ال hydrogens اللي قولنا عنها بتكون acidic
+
+331
+00:30:55,860 --> 00:30:58,840
+hydrogen مين تتذكرها؟
+
+332
+00:31:02,090 --> 00:31:05,590
+كمان الهيدروجين يمكن أن تفقد في وجود الـ Base
+
+333
+00:31:05,590 --> 00:31:09,410
+وشرحنا عنها المحاضرة الماضية وجيبناها السؤال في
+
+334
+00:31:09,410 --> 00:31:13,210
+الامتحان الهيدروجين
+
+335
+00:31:13,210 --> 00:31:20,490
+تبعت الـ terminal الكاين لما بيكون عنده R C triple
+
+336
+00:31:20,490 --> 00:31:24,690
+bond C وهذه الـ H هذه الهيدروجين يمكن أن تفقد في
+
+337
+00:31:24,690 --> 00:31:30,310
+وجود الـ Base وبتعطينا الـ acetylide anion R C
+
+338
+00:31:30,310 --> 00:31:31,450
+triple bond C
+
+339
+00:31:35,040 --> 00:31:39,920
+minus إذا كام نوع مار علينا إحنا الهيدروجين تبعت
+
+340
+00:31:39,920 --> 00:31:43,560
+الحامض يمكن أن تفقد تبعت الكحول لكن بيكون weak
+
+341
+00:31:43,560 --> 00:31:46,720
+acid تبعت الacetylide تفقد برضه بصعوبة بيبقى
+
+342
+00:31:46,720 --> 00:31:53,020
+strong base الآن بيجي ناخد النوع الرابع أيش هو
+
+343
+00:31:53,020 --> 00:31:56,580
+النوع الرابع؟ في الـ Ketone و الـ Aldehyde
+
+344
+00:31:56,580 --> 00:32:01,260
+الهيدروجين اللي جنب الـ C double bond O بنقول عنها
+
+345
+00:32:01,260 --> 00:32:06,120
+acidic hydrogenيعني لما نقول هي السيطة بالـ bond O
+
+346
+00:32:06,120 --> 00:32:10,360
+أول كربونة بالنسبة لها بيقولوا عنها الـ alpha
+
+347
+00:32:10,360 --> 00:32:15,790
+carbonمش نمر واحد بنستعمله احنا Alpha إذا لما ناخد
+
+348
+00:32:15,790 --> 00:32:19,130
+احنا هاي الـ C double bond O أول كربونا بالنسبة
+
+349
+00:32:19,130 --> 00:32:23,150
+لها إيش بنقول عنها Alpha Carbon الهيدروجين اللي
+
+350
+00:32:23,150 --> 00:32:26,710
+بتحملها أول كربونا جنب الـ C double bond O بنقول
+
+351
+00:32:26,710 --> 00:32:30,230
+عنها Alpha Hydrogen هذه Alpha Carbon وهذه Alpha
+
+352
+00:32:30,230 --> 00:32:37,190
+Hydrogen الآن الـ Alpha Hydrogen is acidic في وجود
+
+353
+00:32:37,190 --> 00:32:45,050
+strong base بتفقدهنا نفترض أنه عندما يكون عندك C
+
+354
+00:32:45,050 --> 00:32:51,770
+double bond O نفترض هذا R وهنا عندكم CH وخلّيني
+
+355
+00:32:51,770 --> 00:32:56,610
+أقول كمان H2 هذه الهيدروجين اللي هي بعد الـ C
+
+356
+00:32:56,610 --> 00:33:01,410
+double bond O مباشرة، شو بنسميها؟ Alpha-hydrogen
+
+357
+00:33:01,410 --> 00:33:03,790
+هذه بتفقد و بتعطي
+
+358
+00:33:21,940 --> 00:33:26,620
+الألف هيدروجين هو أسدك هيدروجين
+
+359
+00:33:31,650 --> 00:33:36,450
+عادة بيستخدموا المركب اللي اسمه sodium ethoxide
+
+360
+00:33:48,440 --> 00:33:53,220
+أذا كل هذه عبارة عن أنواع من الـhydrogens
+
+361
+00:33:53,220 --> 00:33:55,980
+الـacidic hydrogens اللي في الحامض و اللي في
+
+362
+00:33:55,980 --> 00:33:59,700
+الكحول و اللي في الـterminal alkyne و الـalpha
+
+363
+00:33:59,700 --> 00:34:03,940
+hydrogen of aldehydes and ketones، they are
+
+364
+00:34:03,940 --> 00:34:10,150
+acidic، أيش بيفرجوا أن أقوى واحدة فيهم؟تبعت الحامض
+
+365
+00:34:10,150 --> 00:34:13,430
+يعني هذا ب Sodium Carbonate بتفقد which is a weak
+
+366
+00:34:13,430 --> 00:34:16,890
+base لكن هنا أنا بدي Sodium Metal هنا بدي Sodium
+
+367
+00:34:16,890 --> 00:34:22,350
+Ethoxide يعني هنا بدي strong bases واضح؟ هنا weak
+
+368
+00:34:22,350 --> 00:34:25,450
+base أي حامض اللي حط عليه كربونا بفقد ال nitrogen
+
+369
+00:34:25,450 --> 00:34:29,670
+ولا لأ؟ أو بيصير .. حتى لو كان حمض لمون حطه عليه
+
+370
+00:34:29,670 --> 00:34:33,970
+كربونا بتشوفوه بيصير يعمل bubbling و بفقد ال .. أه
+
+371
+00:34:33,970 --> 00:34:34,470
+بسهولة
+
+372
+00:34:39,350 --> 00:34:44,290
+فاللي بنقوله إحنا إنه لو إجت أي base بتاخد الـ H
+
+373
+00:34:44,290 --> 00:34:50,450
+هذه لوحدها بدون زوج الإلكترونات وبيبقى زوج
+
+374
+00:34:50,450 --> 00:34:54,510
+الإلكترونات عامل minus على الكاربون الآن في واحدة
+
+375
+00:34:54,510 --> 00:35:00,450
+ممكن تسأل طيب هل الكاربون يستطيع أن يحمل الشحنة
+
+376
+00:35:00,450 --> 00:35:08,490
+السالبة؟ الأصل؟ لألأنه ليس إلكترو نيجاتيف ولأنه
+
+377
+00:35:08,490 --> 00:35:15,630
+ضارة صغيرة يعني الكاربون لوحده .. الكاربون لوحده
+
+378
+00:35:15,630 --> 00:35:19,790
+مش من قدرة نهائية .. نهائية أن يحمل شحنة سالبة
+
+379
+00:35:19,790 --> 00:35:24,430
+يعني لو أن أنا أخد المثالين هدولة تحت بعض عشان
+
+380
+00:35:24,430 --> 00:35:30,490
+أنتوا تنتبهوا و تفهموا كويس لما أخد أنا CH3 جنب C
+
+381
+00:35:30,490 --> 00:35:31,590
+double bond O
+
+382
+00:35:36,660 --> 00:35:42,880
+يجب ان انا
+
+383
+00:35:42,880 --> 00:35:50,160
+افقد البروتون من هنا و اعمل CH2- و خلّيني اقول انا
+
+384
+00:35:50,160 --> 00:35:56,700
+افقد البروتون من هنا و اعمل CH2- هذولا مبينين فيهم
+
+385
+00:35:56,700 --> 00:36:02,780
+موزالة بعض ولا لا؟ لكن حقيقة ان هذا الكلام
+
+386
+00:36:08,010 --> 00:36:11,910
+النقطة ليست إن الكربون قادر تحمل الـ Minus Charge
+
+387
+00:36:11,910 --> 00:36:15,430
+لو إن الكربون قادر تحمل الـ Minus Charge المفروض
+
+388
+00:36:15,430 --> 00:36:18,930
+هدول المثلين زي بعض المفروض في الحالتين يكون فيه
+
+389
+00:36:18,930 --> 00:36:24,330
+بالإمكان أن تفقد الهيدروجين طب ليش فقدت هنا ولم
+
+390
+00:36:24,330 --> 00:36:27,570
+تفقد هنا؟ هذا هو السؤال
+
+391
+00:36:31,660 --> 00:36:37,380
+في الدنيا كتير في ناس .. في الدنيا كتير في ناس
+
+392
+00:36:37,380 --> 00:36:39,020
+بيستجوه
+
+393
+00:36:41,160 --> 00:36:47,100
+بجيرانهم و أحياناً بيستجوى بتنظيماتهم يعني بتكونوا
+
+394
+00:36:47,100 --> 00:36:51,080
+عارفين ان انتوا على مدى عشرين سنة اضعيف اجاله جار
+
+395
+00:36:51,080 --> 00:36:55,480
+جوي ولا أخو جوي ولا تنظيم جوي بيصير يستجوى فيه بس
+
+396
+00:36:55,480 --> 00:37:02,740
+هو بحد ذاته اضعيف وهنا نفس الفكرة تماما هذه بتعمل
+
+397
+00:37:02,740 --> 00:37:06,600
+بتستفيد من ال oxygen اللي بتساعدها في الحمل بتعمل
+
+398
+00:37:06,600 --> 00:37:12,230
+resonance بلفها تزوج الالكترونات هناوهذا بيجي هنا
+
+399
+00:37:12,230 --> 00:37:15,610
+بيحمل على الـ O minus بيصير بدل ما هو ال minus على
+
+400
+00:37:15,610 --> 00:37:19,310
+ال carbon على ال oxygen مرة على ال oxygen مرة على
+
+401
+00:37:19,310 --> 00:37:21,030
+ال carbon على ال oxygen على ال carbon على ال
+
+402
+00:37:21,030 --> 00:37:25,110
+oxygen على ال carbon اتوزع الحمل هذه عملية إيش ال
+
+403
+00:37:25,110 --> 00:37:29,030
+resonance إذا هذا زوج الإلكترونات لما يتحرك بهذا
+
+404
+00:37:29,030 --> 00:37:32,650
+الشكل وهذا تصير O minus هذه ال minus كان هنا على
+
+405
+00:37:32,650 --> 00:37:37,910
+ال carbon صار على ال oxygen رايح جاي هذه العملية
+
+406
+00:37:37,910 --> 00:37:43,840
+عملية resonanceهذه العملية عملية Resonance وهي سهم
+
+407
+00:37:43,840 --> 00:37:48,520
+الـ Resonance ولذلك بيصير هنا عملية فقد البروتون
+
+408
+00:37:48,520 --> 00:37:55,040
+الآن هنا فيه جار أساعد معاه؟ مافيش ولذلك هذه
+
+409
+00:37:55,040 --> 00:38:03,660
+العملية لا تتم هنا واضح؟ بتتم بس هنا وهذا يمكن
+
+410
+00:38:03,660 --> 00:38:06,880
+يعني الواحد لما يفلسف الأمور شوية أو يحاول يوضحها
+
+411
+00:38:06,880 --> 00:38:16,550
+أكتر لما تسمع حديث المؤمنمين يكمل؟ لأ
+
+412
+00:38:16,550 --> 00:38:20,490
+أنا بدي إيش يخدم موضوعي إعبّر عن إنكم فهمتم
+
+413
+00:38:20,490 --> 00:38:31,970
+الموضوع تماما المؤمن إيش ماله؟ قوي بإيش؟ بإخوانه
+
+414
+00:38:31,970 --> 00:38:38,970
+نبدأ؟ قارنوا دائما المناظر والصور المشتركة يعني
+
+415
+00:38:38,970 --> 00:38:45,610
+الاسد شو اللي خلّاه قوي؟نفس إمكانية الـ Resonance
+
+416
+00:38:45,610 --> 00:38:51,910
+مظبوط ولا لا؟ بتلاحظوا كيف المنظر هنا مشترك؟ إذا
+
+417
+00:38:51,910 --> 00:38:59,500
+الـ Acid صار حامضبسبب وجود C double bond O الالكول
+
+418
+00:38:59,500 --> 00:39:04,480
+كانت موازية لإيش؟ للمراكب التاني، لأنه مافيش جنبها
+
+419
+00:39:04,480 --> 00:39:09,480
+C double bond O اتساعدها طبعا ممكن نجي نسأل سؤال
+
+420
+00:39:09,480 --> 00:39:17,410
+الآن، نقول أنه أقوى كحمض، ال acidولا هذا المُركّب
+
+421
+00:39:17,410 --> 00:39:23,190
+اللي هو CₒO جنبه CH2- الاسد، عارفين ليش؟ لأنه في
+
+422
+00:39:23,190 --> 00:39:27,510
+النهاية في عندي مساعدة بحمل الـ minus لكن الـ O
+
+423
+00:39:27,510 --> 00:39:33,990
+نفسها كذرع أقدر على حمل الـ minus من الكربون ولذلك
+
+424
+00:39:33,990 --> 00:39:38,850
+هنا أنا ممكن ب base صغيرة أتم عملية فقد لبروتن، بس
+
+425
+00:39:38,850 --> 00:39:44,070
+أنا بدي base قويةواضح؟ يعني هذا الجزء جزء ال
+
+426
+00:39:44,070 --> 00:39:49,030
+resonance وجزء مشترك لكن بيضل أنه ال minus هذا
+
+427
+00:39:49,030 --> 00:39:52,410
+يحمل على carbon في نص ال resonance ولا يحمل على
+
+428
+00:39:52,410 --> 00:39:59,010
+Oxygen؟ وين أفضل؟ يحمل على Oxygen ولذلك الحامض هذا
+
+429
+00:39:59,010 --> 00:40:04,490
+بيكون أقوى من الحامض اللي هو ناشئ عن Alpha
+
+430
+00:40:04,490 --> 00:40:07,510
+Hydrogen أقوى من الحامض اللي ناشئ عن Alpha
+
+431
+00:40:07,510 --> 00:40:08,650
+Hydrogen
+
+432
+00:40:12,700 --> 00:40:16,580
+الان اتطلع بس مهتمش ان الله حب الصابرين والصابرات
+
+433
+00:40:16,580 --> 00:40:22,780
+كمان ان المؤمنين والمؤمنات والصادقين والصادقات
+
+434
+00:40:22,780 --> 00:40:25,740
+والقانتين والقانتات والمنفقين والمنفقات
+
+435
+00:40:25,740 --> 00:40:30,120
+والمستغفرين والمستغفرات والصابرين والصابرات
+
+436
+00:40:30,120 --> 00:40:35,780
+والصادقين والصادقات والصائمين والصائماتأو .. انا
+
+437
+00:40:35,780 --> 00:40:39,660
+رايح بالصابرة انتبهوا معاه عاد .. الآن بعد إذنكوا
+
+438
+00:40:39,660 --> 00:40:45,420
+في المقارنة لما تيجوا تعملوا مثلا مقارنة هنا ل ال
+
+439
+00:40:45,420 --> 00:40:51,260
+cane مع acetone يعني مركب فيه سيضا بالبندقو مركب
+
+440
+00:40:51,260 --> 00:40:55,540
+مافيش فيه سيضا بالبندقو اتخيلوا قداش ال BKA هنا
+
+441
+00:40:55,540 --> 00:41:01,060
+حوالي التسعة عشر هنا تقريبا خمسين إذا هذا أقوى
+
+442
+00:41:02,260 --> 00:41:05,100
+ملايين المطلوب .. لأ لأ مش سالك تقريبا .. هذه
+
+443
+00:41:05,100 --> 00:41:11,300
+تقريبا خمسين مش سالك خمسين .. تقريبا خمسين .. يعني
+
+444
+00:41:11,300 --> 00:41:15,760
+ان هذا ..very very very very weak acid لا يُعتبر
+
+445
+00:41:15,760 --> 00:41:20,160
+acid الألكان اللى تاوه رسمناه تقريباً خمسين فلما
+
+446
+00:41:20,160 --> 00:41:24,180
+تقولوا خمسين للتسعة عشر بتقدروا تحسوا كده الفرق؟
+
+447
+00:41:24,180 --> 00:41:29,360
+بتقدروا تحسوه الآن إذا لو كان هذا carboxylic acid
+
+448
+00:41:29,360 --> 00:41:32,620
+الكربوكسيليك أسد لما تاخدوا ال acetic acid كده
+
+449
+00:41:32,620 --> 00:41:37,720
+كانت ال PKA له؟ متذكرينها؟
+
+450
+00:41:39,490 --> 00:41:43,450
+لأ الـKA اللي هي الـ 1.8 في عشرة أث ناقص خمسة الـ
+
+451
+00:41:43,450 --> 00:41:47,170
+BKA أربعة وسبعة بالعشرة أو هيك إشي كتير حاليتوا
+
+452
+00:41:47,170 --> 00:41:52,190
+عليها مثال اتزان لاحظوا الحامض أربعة وسبعة من عشرة
+
+453
+00:41:52,190 --> 00:42:00,930
+هذا تسعة عشر الألكين خمسين شوفتوا كيف اللي هو تدرج
+
+454
+00:42:00,930 --> 00:42:05,670
+الحامضية إذا الحامض أقوى كتير من هذا الحامض حوالي
+
+455
+00:42:05,670 --> 00:42:07,430
+خمسة هذا
+
+456
+00:42:10,730 --> 00:42:15,930
+الالكين بالمرة لا يعتبر حامض إذا بهيك قدرتوا
+
+457
+00:42:15,930 --> 00:42:20,730
+تشوفوا انتوا ان الالفا هيدروجين is an acid لكن
+
+458
+00:42:20,730 --> 00:42:24,610
+weak acid بزامها weak acid ال base اللي بدها
+
+459
+00:42:24,610 --> 00:42:29,590
+تسحبها it should be a strong base من أنسب ال bases
+
+460
+00:42:29,590 --> 00:42:34,810
+ال sodium ethoxide يعني انا لما بدنا نحط ال base
+
+461
+00:42:34,810 --> 00:42:36,270
+المناسبة NA
+
+462
+00:42:38,920 --> 00:42:45,280
+السوديوم إثوكسايد بيسحب بروتون من جنب السيضة
+
+463
+00:42:45,280 --> 00:42:49,640
+بالبوند O فالألفا هيدروجين هو الهيدروجين الاسوديكي
+
+464
+00:42:49,640 --> 00:42:54,780
+الاسوديكي الاسوديكي ابنني لحد هان وللكلامي بقية ان
+
+465
+00:42:54,780 --> 00:42:55,240
+شاء الله
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..ea74f49b20ca2302b77c2ce33a837f4aa7a5b5a3
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2412, "start": 8.2, "end": 24.12, "text": "بسم الله الرحمن الرحيم بنستكمل اليوم في موضوع الـ aldehydes و الـ ketones طبعا سبق إن أكدنا إنه they are reactive compounds with so many different reactions", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 44945, 14851, 24793, 1211, 45595, 20498, 8978, 3714, 2407, 11242, 45367, 2423, 39184, 16798, 68, 3495, 14792, 4032, 2423, 39184, 14979, 2213, 23032, 3555, 3615, 995, 8608, 3555, 4587, 36145, 5551, 4117, 3215, 8315, 36145, 3224, 436, 366, 28897, 21810, 365, 370, 867, 819, 12215], "avg_logprob": -0.19630681547251613, "compression_ratio": 1.329268292682927, "no_speech_prob": 1.9073486328125e-06, "words": [{"start": 8.2, "end": 9.2, "word": "بسم", "probability": 0.74951171875}, {"start": 9.2, "end": 9.36, "word": " الله", "probability": 0.9736328125}, {"start": 9.36, "end": 9.66, "word": " الرحمن", "probability": 0.9775390625}, {"start": 9.66, "end": 10.06, "word": " الرحيم", 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aldehydes والـ ketones كان تفاعل الـ addition", "tokens": [3555, 8592, 28820, 5551, 3794, 32277, 1829, 16712, 5172, 995, 30241, 16247, 3794, 32277, 1829, 13672, 1829, 11331, 4117, 1829, 8315, 18871, 3224, 24976, 39184, 16798, 68, 3495, 14792, 16070, 39184, 14979, 2213, 25961, 6055, 5172, 995, 30241, 2423, 39184, 4500], "avg_logprob": -0.16127232036420278, "compression_ratio": 1.3211009174311927, "no_speech_prob": 0.0, "words": [{"start": 24.89, "end": 25.47, "word": "بشكل", "probability": 0.9524739583333334}, {"start": 25.47, "end": 26.35, "word": " أساسي", "probability": 0.96826171875}, {"start": 26.35, "end": 27.25, "word": " التفاعل", "probability": 0.906494140625}, {"start": 27.25, "end": 28.29, "word": " الأساسي", "probability": 0.9708251953125}, {"start": 28.29, "end": 28.41, "word": " اللي", "probability": 0.83154296875}, {"start": 28.41, "end": 28.89, "word": " حكينا", "probability": 0.9912109375}, {"start": 28.89, "end": 29.23, "word": " عنه", "probability": 0.981201171875}, {"start": 29.23, "end": 29.49, "word": " للـ", "probability": 0.617919921875}, {"start": 29.49, "end": 30.03, "word": " aldehydes", "probability": 0.69757080078125}, {"start": 30.03, "end": 30.31, "word": " والـ", "probability": 0.4661865234375}, {"start": 30.31, "end": 30.75, "word": " ketones", "probability": 0.83642578125}, {"start": 30.75, "end": 30.99, "word": " كان", "probability": 0.9443359375}, {"start": 30.99, "end": 31.65, "word": " تفاعل", "probability": 0.9368896484375}, {"start": 31.65, "end": 32.85, "word": " الـ", "probability": 0.749267578125}, {"start": 32.85, "end": 33.19, "word": " addition", "probability": 0.83203125}], "temperature": 1.0}, {"id": 3, "seek": 5915, "start": 33.71, "end": 59.15, "text": "حتى الـ reduction لما اتعاملنا معاه في النهاية كان هو عبارة عن عملية addition حتى ال reduction لما اتعاملنا معاه كان في نهاية عملية addition الآن بناخد تفاعل ال oxidation of aldehydes and ketones طبعا ال oxidation له معاني كثيرة خلينا ناخد أبسط معنى بس اللي بدنا 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هذا بتدل على أن كل هذه عبارة عن enucleophiles .. enucleophiles طالما أن هذه عبارة عن enucleophiles طالما أن هذه عبارة عن enucleophiles إذا إيش التفاعل اللي بتعمله؟", "tokens": [2407, 46958, 5016, 22807, 9673, 5016, 13063, 16247, 3794, 32277, 1829, 5296, 2655, 5172, 995, 30241, 11296, 31439, 30767, 29245, 33688, 23275, 2655, 32887, 8315, 2655, 9673, 29245, 23328, 3660, 18871, 8717, 36081, 2288, 29245, 9957, 4032, 9566, 3555, 3615, 995, 23758, 39894, 3215, 1211, 15844, 14739, 28242, 29538, 6225, 3555, 9640, 3660, 18871, 465, 1311, 306, 5317, 4680, 4386, 465, 1311, 306, 5317, 4680, 23032, 6027, 15042, 14739, 29538, 6225, 3555, 9640, 3660, 18871, 465, 1311, 306, 5317, 4680, 23032, 6027, 15042, 14739, 29538, 6225, 3555, 9640, 3660, 18871, 465, 1311, 306, 5317, 4680, 11933, 15730, 11933, 1829, 8592, 16712, 5172, 995, 30241, 13672, 1829, 39894, 25957, 43761, 22807], "avg_logprob": -0.16202139693337517, "compression_ratio": 2.0, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 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امين امين امين الآن المركبات الامين لما بيكون عنده مركب RNH2 اي RNH2 بنسمي المركب ايش امين هذه عائلة اللي هندرسها في الفصل ال 11 كل عائلة ال R", "tokens": [6027, 20292, 39896, 11723, 295, 1975, 2304, 9957, 1975, 2304, 9957, 1975, 2304, 9957, 6024, 48506, 9673, 31747, 3555, 9307, 2423, 10943, 9957, 5296, 15042, 4724, 1829, 30544, 43242, 3224, 3714, 31747, 3555, 497, 45, 39, 17, 1975, 1829, 497, 45, 39, 17, 44945, 38251, 1829, 9673, 31747, 3555, 1975, 1829, 8592, 1975, 2304, 9957, 29538, 6225, 16373, 37977, 13672, 1829, 8032, 41260, 2288, 3794, 11296, 8978, 27188, 36520, 2423, 2975, 28242, 6225, 16373, 37977, 2423, 497], "avg_logprob": -0.3016826861943954, "compression_ratio": 1.7, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 949.08, "end": 949.44, "word": "اللي", "probability": 0.760009765625}, {"start": 949.44, "end": 949.8, "word": " هي", "probability": 0.89208984375}, {"start": 949.8, "end": 950.74, "word": " formation", "probability": 0.65673828125}, {"start": 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{"start": 1438.87, "end": 1439.29, "word": " عبارة", "probability": 0.9952392578125}, {"start": 1439.29, "end": 1439.51, "word": " عن", "probability": 0.97900390625}, {"start": 1439.51, "end": 1439.81, "word": " أنكوا", "probability": 0.7849934895833334}, {"start": 1439.81, "end": 1440.45, "word": " تحذفوا", "probability": 0.898828125}, {"start": 1440.45, "end": 1441.75, "word": " مياه", "probability": 0.7716471354166666}], "temperature": 1.0}, {"id": 58, "seek": 145647, "start": 1443.03, "end": 1456.47, "text": "كله عبارة عن أنكوا تحذفوا مياه مافيش غلبة غير بحالة واحدة في الـSemi-Carb إزايد تعرفوا من أي نيتروجين التفاعل بده يتم وانا بعتقد أنه وضحناها بما فيه التفاعل", "tokens": [28820, 3224, 6225, 3555, 9640, 3660, 18871, 14739, 4117, 14407, 6055, 5016, 8848, 5172, 14407, 3714, 25528, 3224, 19446, 41185, 8592, 32771, 46152, 3660, 32771, 13546, 4724, 5016, 6027, 3660, 36764, 24401, 3660, 8978, 2423, 39184, 50, 13372, 12, 24437, 65, 11933, 11622, 995, 25708, 37279, 28480, 14407, 9154, 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مرت علينا إذا بتذكروا هذه الظاهرة؟", "tokens": [3555, 1863, 7435, 1829, 5296, 19913, 40294, 25720, 10874, 16254, 41891, 11331, 38436, 28671, 8608, 3555, 4587, 36145, 11296, 3714, 43500, 25894, 8315, 12399, 13672, 1829, 39896, 6024, 116, 40294, 2288, 9307, 2423, 39184, 44299, 12, 268, 401, 12, 83, 1375, 14301, 1434, 12399, 4032, 9957, 3714, 43500, 25894, 8315, 11933, 15730, 39894, 8848, 37983, 14407, 29538, 6024, 116, 40294, 25720, 22807], "avg_logprob": -0.19196427861849466, "compression_ratio": 1.4133333333333333, "no_speech_prob": 0.0, "words": [{"start": 1474.87, "end": 1475.59, "word": "بنجي", "probability": 0.7659912109375}, {"start": 1475.59, "end": 1476.57, "word": " لظاهرة", "probability": 0.978759765625}, {"start": 1476.57, "end": 1477.37, "word": " جديدة", "probability": 0.9851888020833334}, {"start": 1477.37, "end": 1479.13, "word": " حقيقة", "probability": 0.8001302083333334}, {"start": 1479.13, "end": 1480.71, "word": " سبق", "probability": 0.8860677083333334}, {"start": 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0.9638671875}, {"start": 1506.98, "end": 1507.22, "word": " double", "probability": 0.89697265625}, {"start": 1507.22, "end": 1507.66, "word": " bond", "probability": 0.96630859375}, {"start": 1507.66, "end": 1508.22, "word": " all", "probability": 0.4296875}, {"start": 1508.22, "end": 1509.7, "word": " ألكمل", "probability": 0.535125732421875}, {"start": 1509.7, "end": 1510.06, "word": " ف", "probability": 0.74658203125}, {"start": 1510.06, "end": 1510.36, "word": " in", "probability": 0.70361328125}, {"start": 1510.36, "end": 1510.66, "word": " all", "probability": 0.91845703125}, {"start": 1510.66, "end": 1510.98, "word": " يعني", "probability": 0.942626953125}, {"start": 1510.98, "end": 1511.28, "word": " فيها", "probability": 0.97314453125}, {"start": 1511.28, "end": 1511.56, "word": " double", "probability": 0.9560546875}, {"start": 1511.56, "end": 1511.88, "word": " bond", "probability": 0.9423828125}, {"start": 1511.88, "end": 1512.0, "word": " و", "probability": 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"word": " الacetylide", "probability": 0.7703857421875}, {"start": 1905.36, "end": 1905.78, "word": " تفقد", "probability": 0.9230143229166666}, {"start": 1905.78, "end": 1906.08, "word": " برضه", "probability": 0.9305013020833334}, {"start": 1906.08, "end": 1906.52, "word": " بصعوبة", "probability": 0.9845703125}, {"start": 1906.52, "end": 1906.72, "word": " بيبقى", "probability": 0.613818359375}, {"start": 1906.72, "end": 1907.18, "word": " strong", "probability": 0.8671875}, {"start": 1907.18, "end": 1907.58, "word": " base", "probability": 0.89404296875}, {"start": 1907.58, "end": 1908.22, "word": " الآن", "probability": 0.669189453125}, {"start": 1908.22, "end": 1908.6, "word": " بيجي", "probability": 0.851318359375}, {"start": 1908.6, "end": 1909.06, "word": " ناخد", "probability": 0.97900390625}, {"start": 1909.06, "end": 1909.44, "word": " النوع", "probability": 0.971435546875}, {"start": 1909.44, "end": 1911.66, "word": " الرابع", "probability": 0.9851888020833334}, {"start": 1911.66, "end": 1912.84, "word": " أيش", "probability": 0.6524658203125}, {"start": 1912.84, "end": 1913.02, "word": " هو", "probability": 0.94873046875}, {"start": 1913.02, "end": 1913.24, "word": " النوع", "probability": 0.946533203125}, {"start": 1913.24, "end": 1914.28, "word": " الرابع؟", "probability": 0.8421630859375}, {"start": 1914.28, "end": 1914.46, "word": " في", "probability": 0.9228515625}, {"start": 1914.46, "end": 1914.72, "word": " الـ", "probability": 0.599609375}, {"start": 1914.72, "end": 1915.12, "word": " Ketone", "probability": 0.6789957682291666}, {"start": 1915.12, "end": 1915.3, "word": " و", "probability": 0.740234375}, {"start": 1915.3, "end": 1915.5, "word": " الـ", "probability": 0.5760498046875}, {"start": 1915.5, "end": 1916.58, "word": " Aldehyde", "probability": 0.7833251953125}, {"start": 1916.58, "end": 1918.34, "word": " الهيدروجين", "probability": 0.94287109375}, {"start": 1918.34, "end": 1918.86, "word": " اللي", "probability": 0.914794921875}, {"start": 1918.86, "end": 1919.38, "word": " جنب", "probability": 0.9431966145833334}, {"start": 1919.38, "end": 1919.66, "word": " الـ", "probability": 0.8486328125}, {"start": 1919.66, "end": 1919.76, "word": " C", "probability": 0.43505859375}, {"start": 1919.76, "end": 1920.0, "word": " double", "probability": 0.30078125}, {"start": 1920.0, "end": 1920.42, "word": " bond", "probability": 0.921875}, {"start": 1920.42, "end": 1920.64, "word": " O", "probability": 0.9375}, {"start": 1920.64, "end": 1920.98, "word": " بنقول", "probability": 0.81201171875}, {"start": 1920.98, "end": 1921.26, "word": " عنها", "probability": 0.9736328125}, {"start": 1921.26, "end": 1921.7, "word": " acidic", "probability": 0.85205078125}, {"start": 1921.7, "end": 1922.52, "word": " hydrogen", "probability": 0.92822265625}], "temperature": 1.0}, {"id": 75, "seek": 193104, "start": 1923.6, "end": 1931.04, "text": "يعني لما نقول هي السيطة بالـ bond O أول كربونة بالنسبة لها بيقولوا عنها الـ alpha carbon", "tokens": [40228, 22653, 5296, 15042, 8717, 39648, 39896, 21136, 1829, 9566, 3660, 20666, 39184, 6086, 422, 5551, 12610, 9122, 25513, 11536, 3660, 20666, 1863, 35457, 3660, 5296, 11296, 4724, 1829, 39648, 14407, 18871, 11296, 2423, 39184, 8961, 5954], "avg_logprob": -0.28412829966921554, "compression_ratio": 1.2972972972972974, "no_speech_prob": 0.0, "words": [{"start": 1923.6, "end": 1923.98, "word": "يعني", "probability": 0.748291015625}, {"start": 1923.98, "end": 1924.2, "word": " لما", "probability": 0.792724609375}, {"start": 1924.2, "end": 1924.46, "word": " نقول", "probability": 0.943115234375}, {"start": 1924.46, "end": 1924.7, "word": " هي", "probability": 0.45654296875}, {"start": 1924.7, "end": 1925.24, "word": " السيطة", "probability": 0.7967529296875}, {"start": 1925.24, "end": 1925.52, "word": " بالـ", "probability": 0.49365234375}, {"start": 1925.52, "end": 1925.8, "word": " bond", "probability": 0.541015625}, {"start": 1925.8, "end": 1926.12, "word": " O", "probability": 0.33935546875}, {"start": 1926.12, "end": 1926.88, "word": " أول", "probability": 0.7958984375}, {"start": 1926.88, "end": 1927.86, "word": " كربونة", "probability": 0.8067626953125}, {"start": 1927.86, "end": 1928.5, "word": " بالنسبة", "probability": 0.9847412109375}, {"start": 1928.5, "end": 1928.96, "word": " لها", "probability": 0.790771484375}, {"start": 1928.96, "end": 1929.6, "word": " بيقولوا", "probability": 0.814697265625}, {"start": 1929.6, "end": 1929.84, "word": " عنها", "probability": 0.9931640625}, {"start": 1929.84, "end": 1930.06, "word": " الـ", "probability": 0.88427734375}, {"start": 1930.06, "end": 1930.36, "word": " alpha", "probability": 0.421630859375}, {"start": 1930.36, "end": 1931.04, "word": " carbon", "probability": 0.94140625}], "temperature": 1.0}, {"id": 76, "seek": 195911, "start": 1931.97, "end": 1959.11, "text": "مش نمر واحد بنستعمله احنا Alpha إذا لما ناخد احنا هاي الـ C double bond O أول كربونا بالنسبة لها إيش بنقول عنها Alpha Carbon الهيدروجين اللي بتحملها أول كربونا جنب الـ C double bond O بنقول عنها Alpha Hydrogen هذه Alpha Carbon وهذه Alpha Hydrogen الآن الـ Alpha Hydrogen is acidic في وجود strong base بتفقد", "tokens": [2304, 8592, 8717, 29973, 36764, 24401, 44945, 14851, 25957, 43761, 1975, 5016, 8315, 20588, 11933, 15730, 5296, 15042, 8717, 47283, 3215, 1975, 5016, 8315, 8032, 47302, 2423, 39184, 383, 3834, 6086, 422, 5551, 12610, 9122, 25513, 2407, 8315, 20666, 1863, 35457, 3660, 5296, 11296, 11933, 1829, 8592, 44945, 39648, 18871, 11296, 20588, 31453, 2423, 3224, 25708, 2288, 29245, 9957, 13672, 1829, 39894, 35571, 1211, 11296, 5551, 12610, 9122, 25513, 2407, 8315, 10874, 1863, 3555, 2423, 39184, 383, 3834, 6086, 422, 44945, 39648, 18871, 11296, 20588, 24231, 7747, 29538, 20588, 31453, 37037, 24192, 20588, 24231, 7747, 6024, 48506, 2423, 39184, 20588, 24231, 7747, 307, 39514, 8978, 49610, 23328, 2068, 3096, 39894, 5172, 28543], "avg_logprob": -0.21957965023749698, "compression_ratio": 1.8285714285714285, 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"end": 1941.19, "word": " Alpha", "probability": 0.4423828125}, {"start": 1941.19, "end": 1941.79, "word": " Carbon", "probability": 0.5556640625}, {"start": 1941.79, "end": 1942.97, "word": " الهيدروجين", "probability": 0.829345703125}, {"start": 1942.97, "end": 1943.15, "word": " اللي", "probability": 0.91796875}, {"start": 1943.15, "end": 1943.81, "word": " بتحملها", "probability": 0.92724609375}, {"start": 1943.81, "end": 1944.19, "word": " أول", "probability": 0.945556640625}, {"start": 1944.19, "end": 1944.85, "word": " كربونا", "probability": 0.9676513671875}, {"start": 1944.85, "end": 1945.17, "word": " جنب", "probability": 0.947265625}, {"start": 1945.17, "end": 1945.33, "word": " الـ", "probability": 0.7861328125}, {"start": 1945.33, "end": 1945.45, "word": " C", "probability": 0.826171875}, {"start": 1945.45, "end": 1945.59, "word": " double", "probability": 0.85986328125}, {"start": 1945.59, "end": 1945.95, "word": " bond", "probability": 0.96923828125}, {"start": 1945.95, "end": 1946.15, "word": " O", "probability": 0.96044921875}, {"start": 1946.15, "end": 1946.71, "word": " بنقول", "probability": 0.896240234375}, {"start": 1946.71, "end": 1946.99, "word": " عنها", "probability": 0.99365234375}, {"start": 1946.99, "end": 1947.37, "word": " Alpha", "probability": 0.91357421875}, {"start": 1947.37, "end": 1948.19, "word": " Hydrogen", "probability": 0.888916015625}, {"start": 1948.19, "end": 1948.99, "word": " هذه", "probability": 0.193115234375}, {"start": 1948.99, "end": 1949.27, "word": " Alpha", "probability": 0.923828125}, {"start": 1949.27, "end": 1949.71, "word": " Carbon", "probability": 0.97900390625}, {"start": 1949.71, "end": 1949.97, "word": " وهذه", "probability": 0.8359375}, {"start": 1949.97, "end": 1950.23, "word": " Alpha", "probability": 0.93359375}, {"start": 1950.23, "end": 1950.69, "word": " Hydrogen", "probability": 0.938720703125}, {"start": 1950.69, "end": 1951.47, "word": " الآن", "probability": 0.6932373046875}, {"start": 1951.47, "end": 1952.23, "word": " الـ", "probability": 0.76904296875}, {"start": 1952.23, "end": 1952.51, "word": " Alpha", "probability": 0.83056640625}, {"start": 1952.51, "end": 1953.73, "word": " Hydrogen", "probability": 0.9384765625}, {"start": 1953.73, "end": 1954.31, "word": " is", "probability": 0.814453125}, {"start": 1954.31, "end": 1955.15, "word": " acidic", "probability": 0.91455078125}, {"start": 1955.15, "end": 1956.65, "word": " في", "probability": 0.8720703125}, {"start": 1956.65, "end": 1957.19, "word": " وجود", "probability": 0.96337890625}, {"start": 1957.19, "end": 1957.79, "word": " strong", "probability": 0.62646484375}, {"start": 1957.79, "end": 1958.37, "word": " base", "probability": 0.91455078125}, {"start": 1958.37, "end": 1959.11, "word": " بتفقد", "probability": 0.9466145833333334}], "temperature": 1.0}, {"id": 77, "seek": 198379, "start": 1960.51, "end": 1983.79, "text": "هنا نفترض أنه عندما يكون عندك C double bond O نفترض هذا R وهنا عندكم CH وخلّيني أقول كمان H2 هذه الهيدروجين اللي هي بعد الـ C double bond O مباشرة، شو بنسميها؟ Alpha-hydrogen هذه بتفقد و بتعطي", "tokens": [3224, 8315, 8717, 5172, 2655, 43042, 14739, 3224, 43242, 15042, 7251, 30544, 43242, 4117, 383, 3834, 6086, 422, 8717, 5172, 2655, 43042, 23758, 497, 4032, 3224, 8315, 43242, 24793, 5995, 4032, 9778, 1211, 11703, 9957, 1829, 5551, 39648, 9122, 2304, 7649, 389, 17, 29538, 2423, 3224, 25708, 2288, 29245, 9957, 13672, 1829, 39896, 39182, 2423, 39184, 383, 3834, 6086, 422, 3714, 3555, 33599, 25720, 12399, 13412, 2407, 44945, 38251, 1829, 11296, 22807, 20588, 12, 21591, 7747, 29538, 39894, 5172, 28543, 4032, 39894, 3615, 9566, 1829], "avg_logprob": -0.5170784925305566, "compression_ratio": 1.4901960784313726, "no_speech_prob": 1.4781951904296875e-05, "words": [{"start": 1960.51, "end": 1961.47, "word": "هنا", "probability": 0.3876953125}, {"start": 1961.47, "end": 1962.19, "word": " نفترض", "probability": 0.624725341796875}, {"start": 1962.19, "end": 1962.95, "word": 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المنظر هنا مشترك؟ إذا الـ Acid صار حامض", "tokens": [1863, 36178, 11933, 2304, 41361, 10632, 2423, 39184, 5015, 266, 719, 3714, 19913, 3555, 2407, 9566, 49429, 20193, 22807, 39894, 15040, 5016, 19913, 14407, 9122, 33911, 9673, 1863, 19913, 2288, 34105, 37893, 2655, 31747, 22807, 11933, 15730, 2423, 39184, 5097, 327, 20328, 9640, 11331, 10943, 11242], "avg_logprob": -0.2636303128080165, "compression_ratio": 1.1923076923076923, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 2322.07, "end": 2322.55, "word": "نفس", "probability": 0.6119384765625}, {"start": 2322.55, "end": 2323.59, "word": " إمكانية", "probability": 0.9228515625}, {"start": 2323.59, "end": 2325.01, "word": " الـ", "probability": 0.3675537109375}, {"start": 2325.01, "end": 2325.61, "word": " Resonance", "probability": 0.7969563802083334}, {"start": 2325.61, "end": 2328.61, "word": " مظبوط", "probability": 0.7000244140625}, {"start": 2328.61, "end": 2328.77, "word": " ولا", "probability": 0.83544921875}, 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الالفا هيدروجين is an acid لكن weak acid بزامها weak acid ال base اللي بدها تسحبها it should be a strong base من أنسب ال bases ال sodium ethoxide يعني انا لما بدنا نحط ال base المناسبة NA", "tokens": [6027, 6027, 4117, 9957, 20666, 2304, 25720, 20193, 7251, 34268, 26890, 11331, 10943, 11242, 11933, 15730, 39627, 1829, 4117, 12174, 3215, 2288, 2655, 14407, 6055, 8592, 38688, 14407, 16472, 2655, 14407, 16472, 2423, 6027, 5172, 995, 8032, 25708, 2288, 29245, 9957, 307, 364, 8258, 44381, 5336, 8258, 4724, 11622, 10943, 11296, 5336, 8258, 2423, 3096, 13672, 1829, 47525, 11296, 6055, 3794, 5016, 3555, 11296, 309, 820, 312, 257, 2068, 3096, 9154, 14739, 35457, 2423, 17949, 2423, 20265, 1030, 1289, 34454, 37495, 22653, 1975, 8315, 5296, 15042, 47525, 8315, 8717, 5016, 9566, 2423, 3096, 9673, 8315, 35457, 3660, 16585], "avg_logprob": -0.33270202381442293, "compression_ratio": 1.619047619047619, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2530.73, "end": 2531.65, "word": 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2537.91, "end": 2538.79, "word": " هيدروجين", "probability": 0.88154296875}, {"start": 2538.79, "end": 2539.35, "word": " is", "probability": 0.175537109375}, {"start": 2539.35, "end": 2539.75, "word": " an", "probability": 0.74072265625}, {"start": 2539.75, "end": 2540.21, "word": " acid", "probability": 0.94091796875}, {"start": 2540.21, "end": 2540.73, "word": " لكن", "probability": 0.90087890625}, {"start": 2540.73, "end": 2541.25, "word": " weak", "probability": 0.88525390625}, {"start": 2541.25, "end": 2541.79, "word": " acid", "probability": 0.94189453125}, {"start": 2541.79, "end": 2542.59, "word": " بزامها", "probability": 0.71038818359375}, {"start": 2542.59, "end": 2542.89, "word": " weak", "probability": 0.9912109375}, {"start": 2542.89, "end": 2543.35, "word": " acid", "probability": 0.951171875}, {"start": 2543.35, "end": 2543.61, "word": " ال", "probability": 0.86669921875}, {"start": 2543.61, "end": 2544.15, "word": " base", "probability": 0.89208984375}, {"start": 2544.15, "end": 2544.35, "word": " اللي", "probability": 0.79345703125}, {"start": 2544.35, "end": 2544.61, "word": " بدها", "probability": 0.6337890625}, {"start": 2544.61, "end": 2545.21, "word": " تسحبها", "probability": 0.90380859375}, {"start": 2545.21, "end": 2545.39, "word": " it", "probability": 0.82470703125}, {"start": 2545.39, "end": 2545.59, "word": " should", "probability": 0.98095703125}, {"start": 2545.59, "end": 2546.03, "word": " be", "probability": 0.95068359375}, {"start": 2546.03, "end": 2547.33, "word": " a", "probability": 0.56689453125}, {"start": 2547.33, "end": 2547.79, "word": " strong", "probability": 0.92333984375}, {"start": 2547.79, "end": 2548.11, "word": " base", "probability": 0.904296875}, {"start": 2548.11, "end": 2548.33, "word": " من", "probability": 0.966796875}, {"start": 2548.33, "end": 2548.89, "word": " أنسب", "probability": 0.93017578125}, {"start": 2548.89, "end": 2549.09, "word": " ال", "probability": 0.990234375}, {"start": 2549.09, "end": 2549.59, "word": " bases", "probability": 0.9208984375}, {"start": 2549.59, "end": 2550.09, "word": " ال", "probability": 0.455078125}, {"start": 2550.09, "end": 2552.21, "word": " sodium", "probability": 0.57080078125}, {"start": 2552.21, "end": 2553.13, "word": " ethoxide", "probability": 0.8377278645833334}, {"start": 2553.13, "end": 2553.39, "word": " يعني", "probability": 0.939697265625}, {"start": 2553.39, "end": 2553.63, "word": " انا", "probability": 0.6141357421875}, {"start": 2553.63, "end": 2553.83, "word": " لما", "probability": 0.941162109375}, {"start": 2553.83, "end": 2554.11, "word": " بدنا", "probability": 0.5023193359375}, {"start": 2554.11, "end": 2554.39, "word": " نحط", "probability": 0.9427083333333334}, {"start": 2554.39, "end": 2554.57, "word": " ال", "probability": 0.98681640625}, {"start": 2554.57, "end": 2554.81, "word": " base", "probability": 0.888671875}, {"start": 2554.81, "end": 2555.65, "word": " المناسبة", "probability": 0.9927978515625}, {"start": 2555.65, "end": 2556.27, "word": " NA", "probability": 0.281982421875}], "temperature": 1.0}, {"id": 101, "seek": 257523, "start": 2558.92, "end": 2575.24, "text": "السوديوم إثوكسايد بيسحب بروتون من جنب السيضة بالبوند O فالألفا هيدروجين هو الهيدروجين الاسوديكي الاسوديكي الاسوديكي ابنني لحد هان وللكلامي بقية ان شاء الله", "tokens": [6027, 3794, 2407, 16254, 20498, 11933, 12984, 2407, 4117, 3794, 995, 25708, 4724, 1829, 3794, 5016, 3555, 4724, 32887, 2655, 11536, 9154, 10874, 1863, 3555, 21136, 1829, 11242, 3660, 20666, 3555, 11536, 3215, 422, 6156, 6027, 10721, 46538, 995, 8032, 25708, 2288, 29245, 9957, 31439, 2423, 3224, 25708, 2288, 29245, 9957, 2423, 32277, 23328, 1829, 4117, 1829, 2423, 32277, 23328, 1829, 4117, 1829, 2423, 32277, 23328, 1829, 4117, 1829, 48127, 1863, 22653, 5296, 24401, 8032, 7649, 35525, 23275, 37440, 1829, 4724, 4587, 10632, 16472, 13412, 16606, 21984], "avg_logprob": -0.45809658989310265, "compression_ratio": 1.881578947368421, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 2558.92, "end": 2560.06, "word": "السوديوم", "probability": 0.5508544921875}, {"start": 2560.06, "end": 2561.06, "word": " إثوكسايد", "probability": 0.7168317522321429}, {"start": 2561.06, "end": 2563.36, "word": " بيسحب", "probability": 0.70093994140625}, {"start": 2563.36, "end": 2564.12, "word": " بروتون", "probability": 0.8924560546875}, {"start": 2564.12, "end": 2564.4, "word": " من", "probability": 0.97021484375}, {"start": 2564.4, "end": 2564.8, "word": " جنب", "probability": 0.94384765625}, {"start": 2564.8, "end": 2565.28, "word": " السيضة", "probability": 0.555999755859375}, {"start": 2565.28, "end": 2565.76, "word": " بالبوند", "probability": 0.72576904296875}, {"start": 2565.76, "end": 2565.98, "word": " O", "probability": 0.3427734375}, {"start": 2565.98, "end": 2567.02, "word": " فالألفا", "probability": 0.659912109375}, {"start": 2567.02, "end": 2567.64, "word": " هيدروجين", "probability": 0.8580078125}, {"start": 2567.64, "end": 2568.16, "word": " هو", "probability": 0.52197265625}, {"start": 2568.16, "end": 2568.78, "word": " الهيدروجين", "probability": 0.8016764322916666}, {"start": 2568.78, "end": 2569.64, "word": " الاسوديكي", "probability": 0.51068115234375}, {"start": 2569.64, "end": 2569.66, "word": " الاسوديكي", "probability": 0.662628173828125}, {"start": 2569.66, "end": 2570.4, "word": " الاسوديكي", "probability": 0.7948710123697916}, {"start": 2570.4, "end": 2571.36, "word": " ابنني", "probability": 0.549072265625}, {"start": 2571.36, "end": 2571.74, "word": " لحد", "probability": 0.9267578125}, {"start": 2571.74, "end": 2572.18, "word": " هان", "probability": 0.5595703125}, {"start": 2572.18, "end": 2573.74, "word": " وللكلامي", "probability": 0.58587646484375}, {"start": 2573.74, "end": 2574.54, "word": " بقية", "probability": 0.796875}, {"start": 2574.54, "end": 2574.78, "word": " ان", "probability": 0.75146484375}, {"start": 2574.78, "end": 2575.08, "word": " شاء", "probability": 0.971435546875}, {"start": 2575.08, "end": 2575.24, "word": " الله", "probability": 0.95458984375}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2585.542, "duration_after_vad": 2457.500968749987}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..60c3d052498a1e2a9f70304c1f4cf27eca6a3a90
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/6aN00PBBXS8_raw.srt
@@ -0,0 +1,1868 @@
+1
+00:00:08,200 --> 00:00:13,540
+بسم الله الرحمن الرحيم بنستكمل اليوم في موضوع الـ
+
+2
+00:00:13,540 --> 00:00:18,080
+aldehydes و الـ ketones طبعا سبق إن أكدنا إنه they
+
+3
+00:00:18,080 --> 00:00:23,240
+are reactive compounds with so many different
+
+4
+00:00:23,240 --> 00:00:29,230
+reactionsبشكل أساسي التفاعل الأساسي اللي حكينا عنه
+
+5
+00:00:29,230 --> 00:00:33,190
+للـ aldehydes والـ ketones كان تفاعل الـ addition
+
+6
+00:00:33,710 --> 00:00:36,650
+حتى الـ reduction لما اتعاملنا معاه في النهاية كان
+
+7
+00:00:36,650 --> 00:00:40,470
+هو عبارة عن عملية addition حتى ال reduction لما
+
+8
+00:00:40,470 --> 00:00:45,150
+اتعاملنا معاه كان في نهاية عملية addition الآن
+
+9
+00:00:45,150 --> 00:00:50,350
+بناخد تفاعل ال oxidation of aldehydes and ketones
+
+10
+00:00:50,350 --> 00:00:55,310
+طبعا ال oxidation له معاني كثيرة خلينا ناخد أبسط
+
+11
+00:00:55,310 --> 00:00:58,550
+معنى بس اللي بدنا نتعامل معاه اليوم أنه بده يزيد
+
+12
+00:00:58,550 --> 00:01:02,610
+عندناعدد الروابط مع الـ Oxygen
+
+13
+00:01:05,370 --> 00:01:09,810
+فبنلاحظ إحنا إنه في الـ aldehyde فيه اندهيدروجين
+
+14
+00:01:09,810 --> 00:01:14,490
+يمكن أن تستبدل ويجي مكانها أكسوجين بينما في الـ
+
+15
+00:01:14,490 --> 00:01:17,790
+Ketone هذا الكلام غير متوفر يعني المجموعات اللي
+
+16
+00:01:17,790 --> 00:01:21,910
+موجودة مجموعات R-groups وبناء على ذلك اللي حقيقة
+
+17
+00:01:21,910 --> 00:01:26,990
+بيصيرله أكسدة الالدهيدس اللي حقيقة بيصيرله أكسدة
+
+18
+00:01:26,990 --> 00:01:31,650
+الالدهيد فالالدهيد بيصيرله أكسدة سواء في وسط حمضي
+
+19
+00:01:31,650 --> 00:01:37,860
+أو في وسط قاعديبعوامل مثل الـ KMnO4 برمجانات
+
+20
+00:01:37,860 --> 00:01:42,100
+البوتاسيوم وغيرها اللي سبق أننا أخدناه وهذا
+
+21
+00:01:42,100 --> 00:01:46,460
+التفاعل كله سبق أخدناه حقيقة فبيعطينا الحامض أو
+
+22
+00:01:46,460 --> 00:01:51,380
+ملح الحامض اللي عنده الملح مجرد ما يضيف عليه H بلس
+
+23
+00:01:51,380 --> 00:01:55,360
+بيحصل على إيش؟ على الحامض يعني لو عملنا الأكسد في
+
+24
+00:01:55,360 --> 00:02:00,100
+الـ Basic Medium بيطلع عندنا R C double bond O O
+
+25
+00:02:00,100 --> 00:02:05,110
+minus غالبا بيكون معها مثلاالـ A plus إذا ضفنا
+
+26
+00:02:05,110 --> 00:02:10,990
+عليه H plus بنحصل على الحامض ففي النهاية أكسدت ال
+
+27
+00:02:10,990 --> 00:02:15,810
+الديهيدز أكسدت ال الديهيدز سواء ب basic medium أو
+
+28
+00:02:15,810 --> 00:02:20,470
+ب acidic medium في النهاية تؤدي إلى تكوين ال
+
+29
+00:02:20,470 --> 00:02:23,970
+carboxylic acid لاحظوا هنا في عندى رابطتين مع ال
+
+30
+00:02:23,970 --> 00:02:29,530
+oxygen هنا في عندىثلاثة روابط مع الأكسجين وهذا جزء
+
+31
+00:02:29,530 --> 00:02:33,770
+من مفهوم الأكسدة أننا نقول أن تمت عملية أكسدة لا
+
+32
+00:02:33,770 --> 00:02:37,750
+نريد القول في هذا التفاعل لأنه سبق أننا اتكلمنا
+
+33
+00:02:37,750 --> 00:02:42,630
+عنه عندما أخذنا الكمية تبع الكحولات سبق أننا
+
+34
+00:02:42,630 --> 00:02:49,720
+اتكلمنا عنه، واضح؟الآن بيجينا تفاعل كتير جدا مشهور
+
+35
+00:02:49,720 --> 00:02:55,040
+وكتير جدا مهم للـ aldehydes و الـ ketones هذا
+
+36
+00:02:55,040 --> 00:03:01,860
+التفاعل هو التفاعل مع المراكبات اللي فيها NH2 هذا
+
+37
+00:03:01,860 --> 00:03:07,240
+التفاعل هو التفاعل مع المراكبات اللي فيها NH2 أو
+
+38
+00:03:07,240 --> 00:03:13,820
+طبعا NH3 بتعرفوا أبسط واحد فيهم الأمونياالأمونيا
+
+39
+00:03:13,820 --> 00:03:18,520
+إيش ماخدة؟ NH3 وفيها زوج إلكترونات فيتمثل
+
+40
+00:03:18,520 --> 00:03:23,540
+الـNucleophile لأن لما بيصير عندي جزيئين أمونيا مع
+
+41
+00:03:23,540 --> 00:03:28,380
+بعض المركب اللي هو NH2 NH2 هذا المركب بنسميها
+
+42
+00:03:28,380 --> 00:03:34,470
+هيدرازينواضح فالهيدرازين هو عبارة عن جزيئين
+
+43
+00:03:34,470 --> 00:03:37,650
+أمونيات تحدوا مع بعض و فقدوا هيدروجين and H2O and
+
+44
+00:03:37,650 --> 00:03:43,230
+H2O هيدرازين الهيدرازين ممكن يكون substituted
+
+45
+00:03:43,230 --> 00:03:50,270
+هيدرازين يعني أشيل H منه و أحط فينل بيصير فينل
+
+46
+00:03:50,270 --> 00:03:57,070
+هيدرازين لو حطيت مثلمثل هيدرازيل، لو حطيت إثل إثل
+
+47
+00:03:57,070 --> 00:04:05,210
+هيدرازيل، واضح؟ الآن، لو حطيت مجموعة كبيرة شوية زي
+
+48
+00:04:05,210 --> 00:04:10,230
+هذه، هذه المجموعة، لو قلنا one, two, three, four,
+
+49
+00:04:10,470 --> 00:04:15,650
+five, six, two, four, dinitrophilin، كلها اسمها
+
+50
+00:04:15,650 --> 00:04:25,950
+هذه2,4-dinitrophenyl 2,4-dinitrophenylhydrazine
+
+51
+00:04:37,000 --> 00:04:41,240
+أحنا بنيجي نتطلع كيف كل هذه المُركّبات بتتفاعل،
+
+52
+00:04:41,240 --> 00:04:47,340
+يعني وين المحور الأساسي لتفاعلها، المحور الأساسي
+
+53
+00:04:47,340 --> 00:04:51,700
+لتفاعلها هو زوج الإلكترونات اللي موجود على
+
+54
+00:04:51,700 --> 00:04:53,800
+الـNitrogen
+
+55
+00:04:55,400 --> 00:04:59,380
+واضح؟ المحور الأساسي لتفاعلها هو زوج الإلكترونات
+
+56
+00:04:59,380 --> 00:05:03,160
+الموجودة عن نيتروجين وطبعا هذا بتدل على أن كل هذه
+
+57
+00:05:03,160 --> 00:05:09,180
+عبارة عن enucleophiles .. enucleophiles طالما أن
+
+58
+00:05:09,180 --> 00:05:14,240
+هذه عبارة عن enucleophiles طالما أن هذه عبارة عن
+
+59
+00:05:14,240 --> 00:05:20,430
+enucleophiles إذا إيش التفاعل اللي بتعمله؟in
+
+60
+00:05:20,430 --> 00:05:24,950
+eucleophilic addition يعني لو بده أجي أطلع هنا
+
+61
+00:05:24,950 --> 00:05:29,410
+بنفس المنطق أقول هاي زوج الإلكترونات اللي عندى هاي
+
+62
+00:05:29,410 --> 00:05:33,370
+زوج الإلكترونات اللي عندى بده يهاجم هنا و ال O إيش
+
+63
+00:05:33,370 --> 00:05:40,670
+بده تصير؟ OH واضح؟ نفس التفاعل ولا لأ؟ لو إجينا
+
+64
+00:05:40,670 --> 00:05:49,130
+نعملوا هذا الناتج بدنا نقول هي عندنا carbon R R OH
+
+65
+00:05:50,750 --> 00:05:58,210
+ان هتفقد اتش بالتأكيد ان اتش كمان ان اتش وهذه ال
+
+66
+00:05:58,210 --> 00:06:03,630
+residue او الجزء المترقب الان
+
+67
+00:06:03,630 --> 00:06:08,070
+لاحظوا هنا احنا ما زلنا بنتكلم على نفس الفكرة ال
+
+68
+00:06:08,070 --> 00:06:14,690
+nucleophilic addition هي نضيفت هذا اذا بتذكروا و
+
+69
+00:06:14,690 --> 00:06:23,050
+ال اه صارت ohإذا أنا هنا بحكي عن الـ Nucleophilic
+
+70
+00:06:23,050 --> 00:06:27,570
+addition ولا لأ؟ أه طيب هذا التفاعل الآن إيش
+
+71
+00:06:27,570 --> 00:06:32,410
+بيختلف عن التفاعلات السابقة؟ في خطوة الأولى لا
+
+72
+00:06:32,410 --> 00:06:39,150
+يختلف شيء لكن عادة الخطوة الأولى تتبع مباشرة بخطوة
+
+73
+00:06:39,150 --> 00:06:44,410
+تانية إضافية في الخطوة التانية الإضافية بتم حدث
+
+74
+00:06:44,410 --> 00:06:48,870
+الـ OH هذه مع ال H اللى موجودة على الآن H و بعمله
+
+75
+00:06:48,870 --> 00:06:56,630
+double bondواضح؟ فبصير عندى عملية مركبة من عمليتين
+
+76
+00:06:56,630 --> 00:07:02,170
+العملية الأولى اللى احنا متعودين عليها ال addition
+
+77
+00:07:02,170 --> 00:07:07,950
+والعملية التانية عملية حدث جزاء مية elimination
+
+78
+00:07:07,950 --> 00:07:15,470
+ولذلك التفاعل مع هدول المركبات حقيقة بتنفي خطوتين
+
+79
+00:07:15,470 --> 00:07:21,240
+الخطوتين شو هما addition و eliminationهذا الكلام
+
+80
+00:07:21,240 --> 00:07:25,380
+addition و elimination لحد ما أصل للنتج النهائي
+
+81
+00:07:25,380 --> 00:07:29,840
+لحد ما أصل للنتج النهائي إذا أنا طلبت منكم تفصلوا
+
+82
+00:07:29,840 --> 00:07:33,760
+لي شو الكلام اللي بيصير لكن لو أنا باجي بسألكم في
+
+83
+00:07:33,760 --> 00:07:39,540
+امتحان أعطوني الجواب بسرعة و خلال ثانية أسهل طريقة
+
+84
+00:07:39,540 --> 00:07:43,420
+عشان تعطوا الجواب بسرعة و خلال ثانية إذا بنجيبلكم
+
+85
+00:07:43,420 --> 00:07:50,550
+تفعلوا anh2 من هدولة مع cw.oتجي تمسكوا الـ H2 مع
+
+86
+00:07:50,550 --> 00:07:57,610
+الـ O تشطبوهم و تمدوا الـ double bond واضح؟ حطوهم
+
+87
+00:07:57,610 --> 00:08:02,910
+جنب بعض الـ C double bond O جنب الـ N H2 واخدوا
+
+88
+00:08:02,910 --> 00:08:09,550
+H2O مياه فيها واضح؟
+
+89
+00:08:09,550 --> 00:08:13,250
+مافيش أسهل منه يعني كيف أكتب ناتج تفاعل
+
+90
+00:08:13,250 --> 00:08:18,590
+الديهيدوكيتون مع أي واحد من هدولةبدي أشيل الـ H2
+
+91
+00:08:18,590 --> 00:08:23,590
+مع الـ O و أعمل مكانهم double bond لكن بكون عارف
+
+92
+00:08:23,590 --> 00:08:28,830
+أن هذا الكلام نتاج خطوتين نتاج عملية addition
+
+93
+00:08:28,830 --> 00:08:34,870
+followed by elimination الآن في معظم الحلات احنا
+
+94
+00:08:34,870 --> 00:08:38,130
+بنقولكوا اكتبولنا الناتج الآن لما نقول اكتبوا
+
+95
+00:08:38,130 --> 00:08:41,650
+الناتج بديش أشوف الكلام هذا اللي في الوسط عطول
+
+96
+00:08:41,650 --> 00:08:48,200
+بتحطولي إيش؟ C double bond Nع طول بدنا نحط الـ C
+
+97
+00:08:48,200 --> 00:08:52,460
+double bond أن الناتج النهائي بحط الـ H2 جنب الـ O
+
+98
+00:08:52,460 --> 00:08:58,620
+وبشيلهم مع بعض هذه الطريقة العملية لكتابة الناتج
+
+99
+00:08:58,620 --> 00:09:04,800
+هذه العملية مركبة من عمليتين عملية addition وعملية
+
+100
+00:09:04,800 --> 00:09:11,660
+elimination إضافة وحدث واضح؟ وهذه الحقيقة من
+
+101
+00:09:11,660 --> 00:09:17,390
+العمليات الهامة أو المهمة والتي تتكررالان لاحظوا
+
+102
+00:09:17,390 --> 00:09:22,690
+هنا بنعطي نوعا ما تعميم عام أنه لو عندي nh2 متصلة
+
+103
+00:09:22,690 --> 00:09:29,130
+مع إيش مكان يكون يعني صرت جاي ال X أنا هال X هذه
+
+104
+00:09:29,130 --> 00:09:33,630
+ممكن تكون nh2 التانية زي الأمثلة اللي شوفناها ممكن
+
+105
+00:09:33,630 --> 00:09:40,590
+تكون nh-phenyl ممكن تكون R أمين يعني يعني مثلا
+
+106
+00:09:40,590 --> 00:09:46,950
+تكون CH2 أو تكون phenyl nh2 أنا لين ممكن تكون OHفي
+
+107
+00:09:46,950 --> 00:09:51,650
+كل الأحوال دائماً لما تيجي الـNH2 مع الـC double
+
+108
+00:09:51,650 --> 00:09:56,290
+bond O تبعت الألديهيد والكيتون دي ربالكوا لإنه بعد
+
+109
+00:09:56,290 --> 00:09:58,950
+هيك مع الـC double bond O تبعت الأحماض
+
+110
+00:09:58,950 --> 00:10:03,510
+الكربوكسيلية بصير تفاعل تاني أنا بحكي عن ألديهيد
+
+111
+00:10:03,510 --> 00:10:08,030
+وكيتون بدي أحدث الـhydrogens بتنتهي مع الـoxygen و
+
+112
+00:10:08,030 --> 00:10:13,170
+أعمل double bond هاي هنا الكلام واضح ولا أسهل منه
+
+113
+00:10:13,170 --> 00:10:19,110
+كمان هاي مع الـhydrazineشيلنا الـ H2O و كل إيش
+
+114
+00:10:19,110 --> 00:10:22,990
+أخدناه زي ما هو و عملنا double bond مع الفين
+
+115
+00:10:22,990 --> 00:10:30,470
+الهيدرازين شيلنا الـ H2O و عملنا double bond،
+
+116
+00:10:30,470 --> 00:10:35,990
+واضح؟ الآن، هدول عن المُركّبات إيش بنسميهم اللي
+
+117
+00:10:35,990 --> 00:10:43,340
+بينتجوا عندنا نفترض هذا المُركّب كانCH3 CH3 شو
+
+118
+00:10:43,340 --> 00:10:50,760
+بيكون اسمه أسيتون أسيتون طب الناتج أسيتون زائد هذا
+
+119
+00:10:50,760 --> 00:10:59,680
+ال NH2 NH2 هيدرازين إيش الناتج بيكون اسمه أسيتون
+
+120
+00:10:59,680 --> 00:11:08,480
+هيدرازون بيبطل هيدرازين CH3 CH3 بنكتب اسم ال
+
+121
+00:11:08,480 --> 00:11:11,180
+ketone في الأول و بعدين
+
+122
+00:11:14,180 --> 00:11:17,620
+هيدرازون، فبصير كأنه عندي قاعدة عامة، القاعدة
+
+123
+00:11:17,620 --> 00:11:22,820
+العامة بتقول إن الـhydrazines react with aldehydes
+
+124
+00:11:22,820 --> 00:11:26,900
+and ketones producing hydrazones، شو هما
+
+125
+00:11:26,900 --> 00:11:29,940
+الـhydrazones المركبات اللي فيهم C double bond N
+
+126
+00:11:29,940 --> 00:11:34,440
+and H2و، هذه عائلة الإيش؟ الـhydrazones، C double
+
+127
+00:11:34,440 --> 00:11:36,300
+bond N، N تانية
+
+128
+00:11:44,500 --> 00:11:47,680
+يعني ليش بننسب إله؟ لما كان فيه مجموعة فينيل وكان
+
+129
+00:11:47,680 --> 00:11:51,120
+مجموعة نايترو، في النهاية تسبنا إله، جبل يعني، جبل
+
+130
+00:11:51,120 --> 00:11:54,280
+متخدر. خليني أشوف الأمثلة التانية، مش فاهم سؤالك،
+
+131
+00:11:54,280 --> 00:11:57,960
+أنا مش واضح. لو افترضنا هذا أسيتون اتفاعل مع فين
+
+132
+00:11:57,960 --> 00:12:01,520
+الهيدرازين، شو هسميه؟ الناتج.
+
+133
+00:12:04,140 --> 00:12:08,220
+لو هذا أسيتون مثل ومثل، شو هكون اسم هذا الناتج؟
+
+134
+00:12:08,220 --> 00:12:16,480
+أسيتونفينيل هيدرازون لو حطينا الـdinitro أسيتون
+
+135
+00:12:16,480 --> 00:12:29,220
+two four dinitro فينيل هيدرازون إيش المشكلة؟
+
+136
+00:12:29,220 --> 00:12:34,090
+هيك اسمهدائما لما تتغلبوا في شغلة أسماء و يقعد
+
+137
+00:12:34,090 --> 00:12:37,430
+بالك و يروح شماله يمينه شره و غرب تتذكروا أن
+
+138
+00:12:37,430 --> 00:12:41,210
+القرآن الكريم بيقول وعلم آدم الأسماء كلها ثم عرضهم
+
+139
+00:12:41,210 --> 00:12:44,430
+على الملائكة فقال أنبئوني بأسماء هؤلاء إن كنتم
+
+140
+00:12:44,430 --> 00:12:51,030
+صادقين واضح؟ فقال أنبئوني بأسماء هؤلاء إن كنتم
+
+141
+00:12:51,030 --> 00:12:54,600
+صادقين بالتسهيلبدناش ندخل في الهمزات كيف لما
+
+142
+00:12:54,600 --> 00:12:59,100
+بلتقيهم في كتير أشياء هيك اتسمت و اتسمية زي ما
+
+143
+00:12:59,100 --> 00:13:03,440
+حكيتلكوا أنا سابقا بدخل فيها مرات عوامل تاريخية و
+
+144
+00:13:03,440 --> 00:13:08,240
+مرات عوامل اشتقاقية، مظبوط ولا لا؟ common names
+
+145
+00:13:08,240 --> 00:13:14,480
+وغيره وغيراته، الآن لو افترضنا اللي كان عندنا NH2
+
+146
+00:13:14,480 --> 00:13:21,640
+مع OHهذا المُركّب بنسميه Hydroxyl Amine الـ NH2
+
+147
+00:13:21,640 --> 00:13:26,920
+OH2 شو بيسموه؟ Hydroxyl شايفين الـ Hydroxyl و الـ
+
+148
+00:13:26,920 --> 00:13:34,440
+NH2 Amine فبصير Hydroxyl Amine الأن لو اتفعل مع
+
+149
+00:13:34,440 --> 00:13:38,580
+كيتون نفترض أسيتون أسيتوفينون سايكلوهيكسانون
+
+150
+00:13:38,580 --> 00:13:44,830
+بنتانون أي الناتج اللي بيطلع شو بنسميه؟خلّينا نحط
+
+151
+00:13:44,830 --> 00:13:48,310
+هدولة مثيل وفينيل، إيش المركب اللي فيه مثيل
+
+152
+00:13:48,310 --> 00:13:56,790
+وفينيل؟ هنا فينيل وهنا CH3، فينيل سيضاو البندق و
+
+153
+00:13:56,790 --> 00:14:03,790
+CH3، أخدتوله لما تقلبته أسيتوفينون،
+
+154
+00:14:03,790 --> 00:14:10,140
+أسيتوفينون الكيتون هذا إيش اسمه؟أسيتوفينون
+
+155
+00:14:10,140 --> 00:14:15,540
+أسيتوفينون
+
+156
+00:14:15,540 --> 00:14:25,900
+أكزيم أسيتوفينون
+
+157
+00:14:25,900 --> 00:14:29,060
+أكزيم
+
+158
+00:14:29,060 --> 00:14:33,360
+أسيتوفينون
+
+159
+00:14:33,360 --> 00:14:37,060
+أكزيم أسيتوفينون أكزيم
+
+160
+00:14:40,040 --> 00:14:45,180
+أسيتوفينون أكزيم فال أكزيم لما نقول عائلة أكزيم
+
+161
+00:14:45,180 --> 00:14:51,080
+مجرد ما تشوفه مركب C double bond N OH هذا أكزيم
+
+162
+00:14:51,080 --> 00:14:55,760
+مجرد ما تشوفه مركب C double bond N N تانية
+
+163
+00:14:55,760 --> 00:15:00,820
+هيدرازون الأن لو كان NH2 بيكون simple hydrazone NH
+
+164
+00:15:00,820 --> 00:15:04,600
+phenylفين الهيدرازون؟ مثل هيدرازون؟ two-four
+
+165
+00:15:04,600 --> 00:15:07,320
+-dinitro؟ فين الهيدرازون؟ ماعرفش إذا في المختبر
+
+166
+00:15:07,320 --> 00:15:14,400
+صرتوا واصلي لتجربة الالديهيدس والكيتونز ولا لسه؟
+
+167
+00:15:14,400 --> 00:15:17,660
+أنتوا فاصل تاني ماخدين المادة؟ إذا
+
+168
+00:15:22,550 --> 00:15:27,570
+انتبهوا معي في المشتقات .. في المشتقات تبعت اللي
+
+169
+00:15:27,570 --> 00:15:32,730
+هي الأن H2O مار عليكم الهيدرازين مار عليكم
+
+170
+00:15:32,730 --> 00:15:37,670
+الهيدروكس الأمين ونفس التفاعل اللي هو تفاعل فقد
+
+171
+00:15:37,670 --> 00:15:40,210
+الماء اللي هي عملية ال addition elimination
+
+172
+00:15:40,210 --> 00:15:49,440
+وبيجيكوا كمان أشياء تانية لكن كلها نفس الفكرةاللي
+
+173
+00:15:49,440 --> 00:15:57,260
+هي formation of امين امين امين الآن المركبات
+
+174
+00:15:57,260 --> 00:16:05,700
+الامين لما بيكون عنده مركب RNH2 اي RNH2 بنسمي
+
+175
+00:16:05,700 --> 00:16:10,480
+المركب ايش امين هذه عائلة اللي هندرسها في الفصل ال
+
+176
+00:16:10,480 --> 00:16:19,100
+11 كل عائلة ال Rالـ H2 هذه عائلة الـ Amines وهذه
+
+177
+00:16:19,100 --> 00:16:22,760
+بناخد عليها فصل كامل إيش اسم هذه العائلة؟ Amine
+
+178
+00:16:22,760 --> 00:16:27,900
+يعني لو كانت هذه مثلا مثل .. شو بيصير اسم المركب؟
+
+179
+00:16:27,900 --> 00:16:33,460
+مثل Amine and so on الأن لما تيجي تتفاعل هذه مع
+
+180
+00:16:33,460 --> 00:16:40,960
+الـ C double bond O شو هتعمل؟ نفس الفكرة تماما
+
+181
+00:16:40,960 --> 00:16:50,510
+هتيجي الـ H2و يحذفه على شكل جزء ميّه الـ
+
+182
+00:16:50,510 --> 00:16:58,250
+elimination process ويصير عندنا R N double bond C
+
+183
+00:16:58,250 --> 00:17:03,570
+الـ C double bond N المتصل بالـ R كعائلة بنسميها
+
+184
+00:17:03,570 --> 00:17:08,650
+عائلة الامين فالامين
+
+185
+00:17:08,650 --> 00:17:17,320
+بيعطينا ايش؟ امينلاحظوا الأن أنتوا من أنواع الـNH2
+
+186
+00:17:17,320 --> 00:17:23,140
+في النهاية كلهم NH2 نبدأ نلخص NH2 خلّينا نقول X
+
+187
+00:17:23,140 --> 00:17:28,180
+التفاعل، مظبوط ولا لأ؟ زاد الديهيد أو الكيتون لما
+
+188
+00:17:28,180 --> 00:17:37,980
+كانت ال X هذه NH2 NH2 كان .. خلّينا نكتب الناتج،
+
+189
+00:17:37,980 --> 00:17:39,900
+زي هيك، شو كان الناتج؟
+
+190
+00:17:45,520 --> 00:17:50,280
+هيدرازون هيدرازون لما كان يكون عندك سيطة بالبند N
+
+191
+00:17:50,280 --> 00:17:57,300
+O H شو الناتج؟ أكزين لما بيصير عندكوا سيطة بالبند
+
+192
+00:17:57,300 --> 00:18:04,420
+M R امين واضح؟
+
+193
+00:18:04,420 --> 00:18:08,980
+إيش اللي كان يعطيني الهيدرازون؟
+
+194
+00:18:08,980 --> 00:18:11,260
+الهيدرازين
+
+195
+00:18:12,640 --> 00:18:17,100
+الهيدرازين لما فعلوا مع الدايدو كيتون شو بيعطيني؟
+
+196
+00:18:17,100 --> 00:18:25,860
+هيدرازون شو اللي بيعطيلي الأكزين؟ هيدروكسل أمين
+
+197
+00:18:25,860 --> 00:18:29,700
+إذا الهيدروكسل أمين بيعطي أكزين شو اللي بيعطي
+
+198
+00:18:29,700 --> 00:18:39,560
+الامين؟ الامينواضح؟ إذا الهيدرازين بيعطي هيدرازون،
+
+199
+00:18:39,560 --> 00:18:46,040
+الهيدروكس الأمين بيعطي أكزين، الأمين بيعطي إمين،
+
+200
+00:18:46,040 --> 00:18:52,780
+في غيرهم؟ لا الله كريم فيه كمان، على أي حالهذه
+
+201
+00:18:52,780 --> 00:18:57,740
+المُركّبات اللي فيها C double bond N متصلة مع R
+
+202
+00:18:57,740 --> 00:19:02,620
+هنا مرات بتاخد كمان اسم تاني بيسموها shift bases
+
+203
+00:19:02,620 --> 00:19:07,300
+قواعد shift بالنسبة للعالم shift هم نفسه بالإمينز
+
+204
+00:19:07,300 --> 00:19:10,720
+بس لو سمعتوا اسم shift base اللي هي نفس هذه
+
+205
+00:19:10,720 --> 00:19:16,100
+المُركّبات الإمينز اللي فيها C double bond N واضح؟
+
+206
+00:19:16,100 --> 00:19:22,980
+الآن نشوف من هذه الأمثلة اللي موجودة عندناأي مثال
+
+207
+00:19:22,980 --> 00:19:30,700
+اللي أخدنا زيه هان هيندي كيتون مع RNH2 إذا كيتون
+
+208
+00:19:30,700 --> 00:19:38,900
+زائد امين شو هيعطيلي امين امين ممتاز هيندي كيتون
+
+209
+00:19:38,900 --> 00:19:46,160
+زائد هيدروكسل امينماذا يعطيني؟ اكزين هي أنا عندي
+
+210
+00:19:46,160 --> 00:19:50,740
+كيتون زائد سيمبل هيدرازين سيمبل يعني انا انا انا
+
+211
+00:19:50,740 --> 00:19:52,320
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+212
+00:19:52,320 --> 00:19:52,580
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+213
+00:19:52,580 --> 00:19:53,580
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+214
+00:19:53,580 --> 00:19:53,760
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+215
+00:19:53,760 --> 00:19:53,760
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+216
+00:19:53,760 --> 00:19:53,760
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+217
+00:19:53,760 --> 00:19:55,480
+انا انا انا انا انا انا انا انا انا انا انا انا
+
+218
+00:19:55,480 --> 00:20:08,640
+انا انا انا انا انا انا
+
+219
+00:20:08,640 --> 00:20:15,410
+اناهذه الأخيرة ما مرتش عليكم لسه ايش هو هذا اخر
+
+220
+00:20:15,410 --> 00:20:24,050
+جزء موجود عندى N-H2C-O-N-H-N-H2 طلع عليها مرة
+
+221
+00:20:24,050 --> 00:20:36,630
+تانية نكبرها شوية C-O-N-H2-N-H2-N-H2 هذا المركب
+
+222
+00:20:36,630 --> 00:20:45,300
+بنسميه semi carbazideهذا المُركّب بيسميه
+
+223
+00:20:45,300 --> 00:20:49,760
+سيمي Carbazai اللي هي صيغة بالبنط O من جهة متصلة
+
+224
+00:20:49,760 --> 00:20:56,960
+بـ NH2 وحدة ومن جهة متصلة بـ NH NH2 الآن لو إيجينا
+
+225
+00:20:56,960 --> 00:21:00,020
+قولنا هذه من وين بدها تتفاعل بدها تتفاعل من الـ
+
+226
+00:21:00,020 --> 00:21:02,820
+NH2 هتيجي تتطلع كم NH2
+
+227
+00:21:09,020 --> 00:21:13,820
+هل يا تورا في إمكانية من الجهتين ولا التفاعل بيتم
+
+228
+00:21:13,820 --> 00:21:21,020
+فقط من جهة واحدة التفاعل فقط يتم من جهة واحدة اللي
+
+229
+00:21:21,020 --> 00:21:26,020
+هي جهة ال hydrazine اللي هي جهة ال NH NH2 من هنا
+
+230
+00:21:26,020 --> 00:21:31,500
+مابصيرش التفاعل إطلاقا واضح؟
+
+231
+00:21:32,300 --> 00:21:38,960
+هذه نسميها أميد نيتروجين هناخد عنها شوية بقى في
+
+232
+00:21:38,960 --> 00:21:42,900
+شبط 10 هذه غير متفاعلة Unreactive بالمرة
+
+233
+00:22:04,260 --> 00:22:08,320
+أن أتش ان أتش تو فعله مع هادي و حذف الأكسجين و
+
+234
+00:22:08,320 --> 00:22:13,620
+النادج عمل c double bond n ان أتش c double bond o
+
+235
+00:22:13,620 --> 00:22:18,440
+ان أتش تو دلت يمكن كان رايحكوا شوية لو انه كان
+
+236
+00:22:18,440 --> 00:22:23,840
+عاكس واحدة من هدولمش مشكلة، بأي طريقة يُكتب
+
+237
+00:22:23,840 --> 00:22:28,640
+التفاعل وين بيتم على الـ Amid Nitrogen ولا على الـ
+
+238
+00:22:28,640 --> 00:22:32,460
+Hydrazine Nitrogen؟ على الـ Hydrazine نحنا دائما و
+
+239
+00:22:32,460 --> 00:22:36,200
+أبداً لما نجيبلكوا سؤال في الامتحان، بنحطه قريب
+
+240
+00:22:36,200 --> 00:22:40,820
+على الـ Amid Nitrogen عشان نشوف كوكبكوا تفعلوه على
+
+241
+00:22:40,820 --> 00:22:44,940
+التانية مش على طول تقولوا أنا H2GammaC double bond
+
+242
+00:22:44,940 --> 00:22:50,910
+O، نحذف ميهواضح؟ يعني هنا كان كتير أي واحدة بتتيجي
+
+243
+00:22:50,910 --> 00:22:56,090
+تاخد هدولة مع بعض وتحذفهم وتعمل double bond احنا
+
+244
+00:22:56,090 --> 00:23:01,070
+بيقول مابتفعلش على ال nitrogen اللي مباشرة جنب ال
+
+245
+00:23:01,070 --> 00:23:03,990
+C double bond او بتفعل على التانية اللي هي ال
+
+246
+00:23:03,990 --> 00:23:07,710
+hydrogen ال nitrogen الآن هذا semi-carbazide شو
+
+247
+00:23:07,710 --> 00:23:13,280
+بيعطيني؟سيمي كربازون، يعني لو هذا كان مثلا أسيتون،
+
+248
+00:23:13,280 --> 00:23:19,940
+شو المُركّب الناتج؟ أسيتون سيمي كربازون، إذن هنا
+
+249
+00:23:19,940 --> 00:23:25,360
+كمان غير الأمين إيمين، بتكون تضيفوا عندكم تحت،
+
+250
+00:23:25,360 --> 00:23:30,800
+سيمي كربازايد، سيمي كربازون، كل هذه عبارة عن
+
+251
+00:23:30,800 --> 00:23:37,830
+مشتقات الألديهيد والكيتون مع الـNH2إذا الـ NH2
+
+252
+00:23:37,830 --> 00:23:41,350
+موجودة على أنواع مختلفة موجودة على شكل أمين على
+
+253
+00:23:41,350 --> 00:23:46,850
+شكل هيدرازين على شكل أكزيم على شكل سيمي كربازايد
+
+254
+00:23:46,850 --> 00:23:53,570
+بتعطينا هيدرازون أكزيم أمين سيمي كربازون وأسهل
+
+255
+00:23:53,570 --> 00:23:57,130
+أشياء تطبقوه وتتمنوا أن يجيكوا سؤال عليه في
+
+256
+00:23:57,130 --> 00:24:03,390
+الامتحانات لأن كله عبارة عن أنكوا تحذفوا مياهكله
+
+257
+00:24:03,390 --> 00:24:07,210
+عبارة عن أنكوا تحذفوا مياه مافيش غلبة غير بحالة
+
+258
+00:24:07,210 --> 00:24:10,910
+واحدة في الـSemi-Carb إزايد تعرفوا من أي نيتروجين
+
+259
+00:24:10,910 --> 00:24:15,930
+التفاعل بده يتم وانا بعتقد أنه وضحناها بما فيه
+
+260
+00:24:15,930 --> 00:24:16,470
+التفاعل
+
+261
+00:24:34,870 --> 00:24:43,310
+بنجي لظاهرة جديدة حقيقة سبق إنها مرت علينا، اللي
+
+262
+00:24:43,310 --> 00:24:48,810
+هي الظاهرات الـ keto-enol-tautomerism، وين مرت
+
+263
+00:24:48,810 --> 00:24:53,560
+علينا إذا بتذكروا هذه الظاهرة؟لما كنا نفعل الـ
+
+264
+00:24:53,560 --> 00:24:57,540
+triple bond و نضيف عليهم ميه من خلال الـ mercuric
+
+265
+00:24:57,540 --> 00:25:01,920
+acetate و ما إلى ذلك كان يتكون عندى in or كنت أضيف
+
+266
+00:25:01,920 --> 00:25:06,980
+H و OH كنا دائما نقولكم ال in all هي in يعني
+
+267
+00:25:06,980 --> 00:25:11,560
+double bond all ألكمل ف in all يعني فيها double
+
+268
+00:25:11,560 --> 00:25:15,760
+bond و فيها ألكمل بتحول إلى ال keto form إيش هذه
+
+269
+00:25:15,760 --> 00:25:19,880
+العملية بيصير فيها حقيقة بيصير فيها نقل إلكترونات
+
+270
+00:25:19,880 --> 00:25:25,310
+و نقل بروتوناتيعني الشحنة بتتحرك و البروتونات
+
+271
+00:25:25,310 --> 00:25:29,610
+بتتحرك لأن هذا البروتون هذا البروتون وين بده ينقل؟
+
+272
+00:25:29,610 --> 00:25:34,650
+بده يجي على ال CH2 و هذا ال double bond بده تيجي
+
+273
+00:25:34,650 --> 00:25:39,330
+هنا فعندي عملية نقل بروتونات و نقل شحنات هذه
+
+274
+00:25:39,330 --> 00:25:44,170
+العملية سمنها احنا Tautomerism وقولنا السهم تبع ال
+
+275
+00:25:44,170 --> 00:25:48,610
+Tautomerism هوالـ double arrows it is an
+
+276
+00:25:48,610 --> 00:25:53,570
+equilibrium process إفراجناها عن ال resonance ال
+
+277
+00:25:53,570 --> 00:25:59,250
+resonance كان بس نقل شحنات أو إلكترونات و كنا
+
+278
+00:25:59,250 --> 00:26:07,130
+بنستعمله أي سهم ال ذكر ال
+
+279
+00:26:07,130 --> 00:26:10,590
+resonance زي البنزين مثلا لما كنا نعمل فيه
+
+280
+00:26:10,590 --> 00:26:12,930
+resonance نقل الإلكترونات
+
+281
+00:26:15,920 --> 00:26:20,420
+double headed arrows هذا اسمه double headed arrows
+
+282
+00:26:20,420 --> 00:26:24,980
+يعني سهم أبو راسين هذا اسمهم double arrows يعني
+
+283
+00:26:24,980 --> 00:26:29,580
+سهمين double arrow و double headed arrow مرات
+
+284
+00:26:29,580 --> 00:26:33,140
+البعض منكم بيروح بحفظ نص الكلام و يوم ما ييجي نسأل
+
+285
+00:26:33,140 --> 00:26:39,020
+في الموضوع مخابط هذا ايش اسمه double headed يعني
+
+286
+00:26:39,020 --> 00:26:44,760
+كام راس له يعني هذا صيني زي التنين في غير التنين
+
+287
+00:26:44,760 --> 00:26:49,430
+له راسينمش كان التنين يكونوا يلو راسين يطيروا سمو
+
+288
+00:26:49,430 --> 00:26:52,990
+و بتقطع راس و بتضرب راس التاني اه هذا أسهم أبو
+
+289
+00:26:52,990 --> 00:26:57,150
+راسين البلد فيها كتير أبو راسين و أبو عجلين و تلو
+
+290
+00:26:57,150 --> 00:27:05,590
+كل إشي اه و هذا إيش اسمه double أرز هذا سهمين اللي
+
+291
+00:27:05,590 --> 00:27:10,690
+هو equilibrium أرز اللي هي أسهم الاتزان
+
+292
+00:27:11,910 --> 00:27:16,070
+أسهم الاتزان، واضح فالتوتمريزم is an equilibrium
+
+293
+00:27:16,070 --> 00:27:19,490
+process
+
+294
+00:27:19,490 --> 00:27:24,230
+which is indicated by double arrows، no by double
+
+295
+00:27:24,230 --> 00:27:28,410
+arrows، resonance is indicated by double headed
+
+296
+00:27:28,410 --> 00:27:32,550
+arrows، هاي سؤال انصحه غلط، التوتمريزم is
+
+297
+00:27:32,550 --> 00:27:37,680
+indicated byDouble arrows. Resonance is indicated
+
+298
+00:27:37,680 --> 00:27:41,700
+by double headed arrows. In resonance there is
+
+299
+00:27:41,700 --> 00:27:45,620
+only charge transfer or electron transfer.
+
+300
+00:27:46,260 --> 00:27:51,200
+However, in automerism we have transfer of charge
+
+301
+00:27:51,200 --> 00:27:54,720
+and atoms mainly protons.
+
+302
+00:27:57,020 --> 00:28:02,080
+هذه العملية مرت معنا لكن احنا هنا بنذكركوا فيها
+
+303
+00:28:02,080 --> 00:28:04,680
+سبق انه مرت
+
+304
+00:28:08,670 --> 00:28:15,830
+الآن بنجي لنقطة مهمة كتير في كيميا الألديهيدس
+
+305
+00:28:15,830 --> 00:28:22,570
+والكيتونز وبتعمل نوعا ما شغلة جديدة في تفاعلاتهم
+
+306
+00:28:22,570 --> 00:28:27,070
+اللي هي بنسميها ال acidity of alpha hydrogen
+
+307
+00:28:27,070 --> 00:28:32,850
+انتبهوا معي موضوع ال acidity ال acidity بشكل عام
+
+308
+00:28:32,850 --> 00:28:36,830
+لو أجينا نذكر فيه إيش كان ال acid؟
+
+309
+00:28:39,290 --> 00:28:46,530
+حسب خلّيني أقول الوري برونستيد definition اللي
+
+310
+00:28:46,530 --> 00:28:52,730
+بيفقد بروتون اتش بلس ال acid is the one that loses
+
+311
+00:28:52,730 --> 00:29:01,930
+اتش بلس مش هذا بروتون دونر بيفقد اتش بلس و ال base
+
+312
+00:29:04,240 --> 00:29:09,560
+Proton Acceptor الأن أنواع الـ Assets .. أنواع الـ
+
+313
+00:29:09,560 --> 00:29:13,620
+Assets كتيرة أسهل
+
+314
+00:29:13,620 --> 00:29:20,220
+إشي أنه يكون عند حامض أنه الـ H Plus لما تفقد زي
+
+315
+00:29:20,220 --> 00:29:25,940
+ما سبق اتكلمت عنه بدا تترك مكانها شحنة سالبة
+
+316
+00:29:25,940 --> 00:29:31,710
+هالشحنة السالبة بدا يكون في قدرةعلى حملها و لذلك
+
+317
+00:29:31,710 --> 00:29:36,070
+أفضل شيء الأحماط الكربوكسيلية لما تفقد ال H بيصير
+
+318
+00:29:36,070 --> 00:29:42,810
+عندك R C double bond O O minus هذه فقدت H مظبوط
+
+319
+00:29:42,810 --> 00:29:46,810
+ولا لأ؟ ليش هذه كانت ثابتة كتير؟ لأنها بتعمل
+
+320
+00:29:46,810 --> 00:29:50,930
+resonance هذه بتتحرك هنا و هذه بتتحرك هنا فشحنة
+
+321
+00:29:50,930 --> 00:29:55,230
+سالمة سهل التعامل معها هذا في الأحماط الكربوكسيلية
+
+322
+00:29:55,230 --> 00:30:00,970
+أخدنا أنه يمكن ال H أن تفقد من إيش كمان؟من ال
+
+323
+00:30:00,970 --> 00:30:06,070
+alcohols بس من ال alcohols شو بيكونوا أقوى ولا
+
+324
+00:30:06,070 --> 00:30:11,030
+أضعف من الأحماض الكربوكسية؟ أضعف لإيش؟ لأنه هنا
+
+325
+00:30:11,030 --> 00:30:16,790
+مافيش شيء .. resonance الحمض
+
+326
+00:30:16,790 --> 00:30:21,150
+الكربوكسيلي قوي لإيش؟ لأنه يصير minus ب resonance
+
+327
+00:30:21,150 --> 00:30:26,670
+ال alcohol is a weak acid قلنا زي و زي الميه لكن
+
+328
+00:30:26,670 --> 00:30:31,280
+ال alcohol فقد ال protonوالحمض الكربوكسيلي فقد
+
+329
+00:30:31,280 --> 00:30:38,780
+بروتون مش هذا في الأساس كان RCH2OH في وجود ال base
+
+330
+00:30:38,780 --> 00:30:47,180
+فقط بروتون وهذا RCH2OH في وجود ال base برضه فقط
+
+331
+00:30:47,180 --> 00:30:52,680
+بروتون الآن هدولة أخدناهم أخدنا كمان نوع من ال ..
+
+332
+00:30:52,680 --> 00:30:55,860
+من ال hydrogens اللي قولنا عنها بتكون acidic
+
+333
+00:30:55,860 --> 00:30:58,840
+hydrogen مين تتذكرها؟
+
+334
+00:31:02,090 --> 00:31:05,590
+كمان الهيدروجين يمكن أن تفقد في وجود الـ Base
+
+335
+00:31:05,590 --> 00:31:09,410
+وشرحنا عنها المحاضرة الماضية وجيبناها السؤال في
+
+336
+00:31:09,410 --> 00:31:13,210
+الامتحان الهيدروجين
+
+337
+00:31:13,210 --> 00:31:20,490
+تبعت الـ terminal الكاين لما بيكون عنده R C triple
+
+338
+00:31:20,490 --> 00:31:24,690
+bond C وهذه الـ H هذه الهيدروجين يمكن أن تفقد في
+
+339
+00:31:24,690 --> 00:31:30,310
+وجود الـ Base وبتعطينا الـ acetylide anion R C
+
+340
+00:31:30,310 --> 00:31:31,450
+triple bond C
+
+341
+00:31:35,040 --> 00:31:39,920
+minus إذا كام نوع مار علينا إحنا الهيدروجين تبعت
+
+342
+00:31:39,920 --> 00:31:43,560
+الحامض يمكن أن تفقد تبعت الكحول لكن بيكون weak
+
+343
+00:31:43,560 --> 00:31:46,720
+acid تبعت الacetylide تفقد برضه بصعوبة بيبقى
+
+344
+00:31:46,720 --> 00:31:53,020
+strong base الآن بيجي ناخد النوع الرابع أيش هو
+
+345
+00:31:53,020 --> 00:31:56,580
+النوع الرابع؟ في الـ Ketone و الـ Aldehyde
+
+346
+00:31:56,580 --> 00:32:01,260
+الهيدروجين اللي جنب الـ C double bond O بنقول عنها
+
+347
+00:32:01,260 --> 00:32:06,120
+acidic hydrogenيعني لما نقول هي السيطة بالـ bond O
+
+348
+00:32:06,120 --> 00:32:10,360
+أول كربونة بالنسبة لها بيقولوا عنها الـ alpha
+
+349
+00:32:10,360 --> 00:32:15,790
+carbonمش نمر واحد بنستعمله احنا Alpha إذا لما ناخد
+
+350
+00:32:15,790 --> 00:32:19,130
+احنا هاي الـ C double bond O أول كربونا بالنسبة
+
+351
+00:32:19,130 --> 00:32:23,150
+لها إيش بنقول عنها Alpha Carbon الهيدروجين اللي
+
+352
+00:32:23,150 --> 00:32:26,710
+بتحملها أول كربونا جنب الـ C double bond O بنقول
+
+353
+00:32:26,710 --> 00:32:30,230
+عنها Alpha Hydrogen هذه Alpha Carbon وهذه Alpha
+
+354
+00:32:30,230 --> 00:32:37,190
+Hydrogen الآن الـ Alpha Hydrogen is acidic في وجود
+
+355
+00:32:37,190 --> 00:32:45,050
+strong base بتفقدهنا نفترض أنه عندما يكون عندك C
+
+356
+00:32:45,050 --> 00:32:51,770
+double bond O نفترض هذا R وهنا عندكم CH وخلّيني
+
+357
+00:32:51,770 --> 00:32:56,610
+أقول كمان H2 هذه الهيدروجين اللي هي بعد الـ C
+
+358
+00:32:56,610 --> 00:33:01,410
+double bond O مباشرة، شو بنسميها؟ Alpha-hydrogen
+
+359
+00:33:01,410 --> 00:33:03,790
+هذه بتفقد و بتعطي
+
+360
+00:33:21,940 --> 00:33:26,620
+الألف هيدروجين هو أسدك هيدروجين
+
+361
+00:33:31,650 --> 00:33:36,450
+عادة بيستخدموا المركب اللي اسمه sodium ethoxide
+
+362
+00:33:48,440 --> 00:33:53,220
+أذا كل هذه عبارة عن أنواع من الـhydrogens
+
+363
+00:33:53,220 --> 00:33:55,980
+الـacidic hydrogens اللي في الحامض و اللي في
+
+364
+00:33:55,980 --> 00:33:59,700
+الكحول و اللي في الـterminal alkyne و الـalpha
+
+365
+00:33:59,700 --> 00:34:03,940
+hydrogen of aldehydes and ketones، they are
+
+366
+00:34:03,940 --> 00:34:10,150
+acidic، أيش بيفرجوا أن أقوى واحدة فيهم؟تبعت الحامض
+
+367
+00:34:10,150 --> 00:34:13,430
+يعني هذا ب Sodium Carbonate بتفقد which is a weak
+
+368
+00:34:13,430 --> 00:34:16,890
+base لكن هنا أنا بدي Sodium Metal هنا بدي Sodium
+
+369
+00:34:16,890 --> 00:34:22,350
+Ethoxide يعني هنا بدي strong bases واضح؟ هنا weak
+
+370
+00:34:22,350 --> 00:34:25,450
+base أي حامض اللي حط عليه كربونا بفقد ال nitrogen
+
+371
+00:34:25,450 --> 00:34:29,670
+ولا لأ؟ أو بيصير .. حتى لو كان حمض لمون حطه عليه
+
+372
+00:34:29,670 --> 00:34:33,970
+كربونا بتشوفوه بيصير يعمل bubbling و بفقد ال .. أه
+
+373
+00:34:33,970 --> 00:34:34,470
+بسهولة
+
+374
+00:34:39,350 --> 00:34:44,290
+فاللي بنقوله إحنا إنه لو إجت أي base بتاخد الـ H
+
+375
+00:34:44,290 --> 00:34:50,450
+هذه لوحدها بدون زوج الإلكترونات وبيبقى زوج
+
+376
+00:34:50,450 --> 00:34:54,510
+الإلكترونات عامل minus على الكاربون الآن في واحدة
+
+377
+00:34:54,510 --> 00:35:00,450
+ممكن تسأل طيب هل الكاربون يستطيع أن يحمل الشحنة
+
+378
+00:35:00,450 --> 00:35:08,490
+السالبة؟ الأصل؟ لألأنه ليس إلكترو نيجاتيف ولأنه
+
+379
+00:35:08,490 --> 00:35:15,630
+ضارة صغيرة يعني الكاربون لوحده .. الكاربون لوحده
+
+380
+00:35:15,630 --> 00:35:19,790
+مش من قدرة نهائية .. نهائية أن يحمل شحنة سالبة
+
+381
+00:35:19,790 --> 00:35:24,430
+يعني لو أن أنا أخد المثالين هدولة تحت بعض عشان
+
+382
+00:35:24,430 --> 00:35:30,490
+أنتوا تنتبهوا و تفهموا كويس لما أخد أنا CH3 جنب C
+
+383
+00:35:30,490 --> 00:35:31,590
+double bond O
+
+384
+00:35:36,660 --> 00:35:42,880
+يجب ان انا
+
+385
+00:35:42,880 --> 00:35:50,160
+افقد البروتون من هنا و اعمل CH2- و خلّيني اقول انا
+
+386
+00:35:50,160 --> 00:35:56,700
+افقد البروتون من هنا و اعمل CH2- هذولا مبينين فيهم
+
+387
+00:35:56,700 --> 00:36:02,780
+موزالة بعض ولا لا؟ لكن حقيقة ان هذا الكلام
+
+388
+00:36:08,010 --> 00:36:11,910
+النقطة ليست إن الكربون قادر تحمل الـ Minus Charge
+
+389
+00:36:11,910 --> 00:36:15,430
+لو إن الكربون قادر تحمل الـ Minus Charge المفروض
+
+390
+00:36:15,430 --> 00:36:18,930
+هدول المثلين زي بعض المفروض في الحالتين يكون فيه
+
+391
+00:36:18,930 --> 00:36:24,330
+بالإمكان أن تفقد الهيدروجين طب ليش فقدت هنا ولم
+
+392
+00:36:24,330 --> 00:36:27,570
+تفقد هنا؟ هذا هو السؤال
+
+393
+00:36:31,660 --> 00:36:37,380
+في الدنيا كتير في ناس .. في الدنيا كتير في ناس
+
+394
+00:36:37,380 --> 00:36:39,020
+بيستجوه
+
+395
+00:36:41,160 --> 00:36:47,100
+بجيرانهم و أحياناً بيستجوى بتنظيماتهم يعني بتكونوا
+
+396
+00:36:47,100 --> 00:36:51,080
+عارفين ان انتوا على مدى عشرين سنة اضعيف اجاله جار
+
+397
+00:36:51,080 --> 00:36:55,480
+جوي ولا أخو جوي ولا تنظيم جوي بيصير يستجوى فيه بس
+
+398
+00:36:55,480 --> 00:37:02,740
+هو بحد ذاته اضعيف وهنا نفس الفكرة تماما هذه بتعمل
+
+399
+00:37:02,740 --> 00:37:06,600
+بتستفيد من ال oxygen اللي بتساعدها في الحمل بتعمل
+
+400
+00:37:06,600 --> 00:37:12,230
+resonance بلفها تزوج الالكترونات هناوهذا بيجي هنا
+
+401
+00:37:12,230 --> 00:37:15,610
+بيحمل على الـ O minus بيصير بدل ما هو ال minus على
+
+402
+00:37:15,610 --> 00:37:19,310
+ال carbon على ال oxygen مرة على ال oxygen مرة على
+
+403
+00:37:19,310 --> 00:37:21,030
+ال carbon على ال oxygen على ال carbon على ال
+
+404
+00:37:21,030 --> 00:37:25,110
+oxygen على ال carbon اتوزع الحمل هذه عملية إيش ال
+
+405
+00:37:25,110 --> 00:37:29,030
+resonance إذا هذا زوج الإلكترونات لما يتحرك بهذا
+
+406
+00:37:29,030 --> 00:37:32,650
+الشكل وهذا تصير O minus هذه ال minus كان هنا على
+
+407
+00:37:32,650 --> 00:37:37,910
+ال carbon صار على ال oxygen رايح جاي هذه العملية
+
+408
+00:37:37,910 --> 00:37:43,840
+عملية resonanceهذه العملية عملية Resonance وهي سهم
+
+409
+00:37:43,840 --> 00:37:48,520
+الـ Resonance ولذلك بيصير هنا عملية فقد البروتون
+
+410
+00:37:48,520 --> 00:37:55,040
+الآن هنا فيه جار أساعد معاه؟ مافيش ولذلك هذه
+
+411
+00:37:55,040 --> 00:38:03,660
+العملية لا تتم هنا واضح؟ بتتم بس هنا وهذا يمكن
+
+412
+00:38:03,660 --> 00:38:06,880
+يعني الواحد لما يفلسف الأمور شوية أو يحاول يوضحها
+
+413
+00:38:06,880 --> 00:38:16,550
+أكتر لما تسمع حديث المؤمنمين يكمل؟ لأ
+
+414
+00:38:16,550 --> 00:38:20,490
+أنا بدي إيش يخدم موضوعي إعبّر عن إنكم فهمتم
+
+415
+00:38:20,490 --> 00:38:31,970
+الموضوع تماما المؤمن إيش ماله؟ قوي بإيش؟ بإخوانه
+
+416
+00:38:31,970 --> 00:38:38,970
+نبدأ؟ قارنوا دائما المناظر والصور المشتركة يعني
+
+417
+00:38:38,970 --> 00:38:45,610
+الاسد شو اللي خلّاه قوي؟نفس إمكانية الـ Resonance
+
+418
+00:38:45,610 --> 00:38:51,910
+مظبوط ولا لا؟ بتلاحظوا كيف المنظر هنا مشترك؟ إذا
+
+419
+00:38:51,910 --> 00:38:59,500
+الـ Acid صار حامضبسبب وجود C double bond O الالكول
+
+420
+00:38:59,500 --> 00:39:04,480
+كانت موازية لإيش؟ للمراكب التاني، لأنه مافيش جنبها
+
+421
+00:39:04,480 --> 00:39:09,480
+C double bond O اتساعدها طبعا ممكن نجي نسأل سؤال
+
+422
+00:39:09,480 --> 00:39:17,410
+الآن، نقول أنه أقوى كحمض، ال acidولا هذا المُركّب
+
+423
+00:39:17,410 --> 00:39:23,190
+اللي هو CₒO جنبه CH2- الاسد، عارفين ليش؟ لأنه في
+
+424
+00:39:23,190 --> 00:39:27,510
+النهاية في عندي مساعدة بحمل الـ minus لكن الـ O
+
+425
+00:39:27,510 --> 00:39:33,990
+نفسها كذرع أقدر على حمل الـ minus من الكربون ولذلك
+
+426
+00:39:33,990 --> 00:39:38,850
+هنا أنا ممكن ب base صغيرة أتم عملية فقد لبروتن، بس
+
+427
+00:39:38,850 --> 00:39:44,070
+أنا بدي base قويةواضح؟ يعني هذا الجزء جزء ال
+
+428
+00:39:44,070 --> 00:39:49,030
+resonance وجزء مشترك لكن بيضل أنه ال minus هذا
+
+429
+00:39:49,030 --> 00:39:52,410
+يحمل على carbon في نص ال resonance ولا يحمل على
+
+430
+00:39:52,410 --> 00:39:59,010
+Oxygen؟ وين أفضل؟ يحمل على Oxygen ولذلك الحامض هذا
+
+431
+00:39:59,010 --> 00:40:04,490
+بيكون أقوى من الحامض اللي هو ناشئ عن Alpha
+
+432
+00:40:04,490 --> 00:40:07,510
+Hydrogen أقوى من الحامض اللي ناشئ عن Alpha
+
+433
+00:40:07,510 --> 00:40:08,650
+Hydrogen
+
+434
+00:40:12,700 --> 00:40:16,580
+الان اتطلع بس مهتمش ان الله حب الصابرين والصابرات
+
+435
+00:40:16,580 --> 00:40:22,780
+كمان ان المؤمنين والمؤمنات والصادقين والصادقات
+
+436
+00:40:22,780 --> 00:40:25,740
+والقانتين والقانتات والمنفقين والمنفقات
+
+437
+00:40:25,740 --> 00:40:30,120
+والمستغفرين والمستغفرات والصابرين والصابرات
+
+438
+00:40:30,120 --> 00:40:35,780
+والصادقين والصادقات والصائمين والصائماتأو .. انا
+
+439
+00:40:35,780 --> 00:40:39,660
+رايح بالصابرة انتبهوا معاه عاد .. الآن بعد إذنكوا
+
+440
+00:40:39,660 --> 00:40:45,420
+في المقارنة لما تيجوا تعملوا مثلا مقارنة هنا ل ال
+
+441
+00:40:45,420 --> 00:40:51,260
+cane مع acetone يعني مركب فيه سيضا بالبندقو مركب
+
+442
+00:40:51,260 --> 00:40:55,540
+مافيش فيه سيضا بالبندقو اتخيلوا قداش ال BKA هنا
+
+443
+00:40:55,540 --> 00:41:01,060
+حوالي التسعة عشر هنا تقريبا خمسين إذا هذا أقوى
+
+444
+00:41:02,260 --> 00:41:05,100
+ملايين المطلوب .. لأ لأ مش سالك تقريبا .. هذه
+
+445
+00:41:05,100 --> 00:41:11,300
+تقريبا خمسين مش سالك خمسين .. تقريبا خمسين .. يعني
+
+446
+00:41:11,300 --> 00:41:15,760
+ان هذا ..very very very very weak acid لا يُعتبر
+
+447
+00:41:15,760 --> 00:41:20,160
+acid الألكان اللى تاوه رسمناه تقريباً خمسين فلما
+
+448
+00:41:20,160 --> 00:41:24,180
+تقولوا خمسين للتسعة عشر بتقدروا تحسوا كده الفرق؟
+
+449
+00:41:24,180 --> 00:41:29,360
+بتقدروا تحسوه الآن إذا لو كان هذا carboxylic acid
+
+450
+00:41:29,360 --> 00:41:32,620
+الكربوكسيليك أسد لما تاخدوا ال acetic acid كده
+
+451
+00:41:32,620 --> 00:41:37,720
+كانت ال PKA له؟ متذكرينها؟
+
+452
+00:41:39,490 --> 00:41:43,450
+لأ الـKA اللي هي الـ 1.8 في عشرة أث ناقص خمسة الـ
+
+453
+00:41:43,450 --> 00:41:47,170
+BKA أربعة وسبعة بالعشرة أو هيك إشي كتير حاليتوا
+
+454
+00:41:47,170 --> 00:41:52,190
+عليها مثال اتزان لاحظوا الحامض أربعة وسبعة من عشرة
+
+455
+00:41:52,190 --> 00:42:00,930
+هذا تسعة عشر الألكين خمسين شوفتوا كيف اللي هو تدرج
+
+456
+00:42:00,930 --> 00:42:05,670
+الحامضية إذا الحامض أقوى كتير من هذا الحامض حوالي
+
+457
+00:42:05,670 --> 00:42:07,430
+خمسة هذا
+
+458
+00:42:10,730 --> 00:42:15,930
+الالكين بالمرة لا يعتبر حامض إذا بهيك قدرتوا
+
+459
+00:42:15,930 --> 00:42:20,730
+تشوفوا انتوا ان الالفا هيدروجين is an acid لكن
+
+460
+00:42:20,730 --> 00:42:24,610
+weak acid بزامها weak acid ال base اللي بدها
+
+461
+00:42:24,610 --> 00:42:29,590
+تسحبها it should be a strong base من أنسب ال bases
+
+462
+00:42:29,590 --> 00:42:34,810
+ال sodium ethoxide يعني انا لما بدنا نحط ال base
+
+463
+00:42:34,810 --> 00:42:36,270
+المناسبة NA
+
+464
+00:42:38,920 --> 00:42:45,280
+السوديوم إثوكسايد بيسحب بروتون من جنب السيضة
+
+465
+00:42:45,280 --> 00:42:49,640
+بالبوند O فالألفا هيدروجين هو الهيدروجين الاسوديكي
+
+466
+00:42:49,640 --> 00:42:54,780
+الاسوديكي الاسوديكي ابنني لحد هان وللكلامي بقية ان
+
+467
+00:42:54,780 --> 00:42:55,240
+شاء الله
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/7JGOVMt_BfA.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/7JGOVMt_BfA.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6cc58d0b171be2139dd6670684aa6c84cfb5aae9
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/7JGOVMt_BfA.srt
@@ -0,0 +1,1786 @@
+1
+00:00:06,440 --> 00:00:10,800
+بسم الله الرحمن الرحيم المحاضرة الماضية إذا 
+
+2
+00:00:10,800 --> 00:00:16,700
+بتذكروا آخر شغلة اتكلمنا عنها كانت على عملية ال
+
+3
+00:00:16,700 --> 00:00:22,620
+oxidation للـ alcohols اتكلمنا عنها بشكل عام إيش 
+
+4
+00:00:22,620 --> 00:00:26,800
+معنى الـ oxidation وإيش الـ oxidation اللي بيصير على
+
+5
+00:00:26,800 --> 00:00:30,100
+الـ ethanol في الجسم لحد ما يطلع في النهاية على شكل
+
+6
+00:00:31,520 --> 00:00:36,320
+ثاني أكسيد الكربون الآن لما بدون ما نطلع على الـ
+
+7
+00:00:36,320 --> 00:00:39,780
+oxidation من ناحية كيميائية و من ناحية معادلات
+
+8
+00:00:39,780 --> 00:00:45,320
+عشان أنا بدي ازيد الروابط مع الـ oxygen بدي أَمْحِي عنده
+
+9
+00:00:45,320 --> 00:00:50,190
+في عملية الـ oxidation حذف ذرتين هيدروجين وبالتالي 
+
+10
+00:00:50,190 --> 00:00:55,150
+تحويل هذا الـ carbon-oxygen single bond إلى carbon
+
+11
+00:00:55,150 --> 00:00:58,850
+-oxygen double bond فبدل ما كان عندي رابطة مع الـ
+
+12
+00:00:58,850 --> 00:01:02,950
+oxygen صار عندي كام رابطة تنتهي؟ إذا هنا في عندي 
+
+13
+00:01:02,950 --> 00:01:08,130
+عملية oxidation إذا بتتطلع على المثال الأول على
+
+14
+00:01:08,130 --> 00:01:13,130
+المثال الأول بتلاحظ أن هذا الكحول عبارة عن primary
+
+15
+00:01:13,130 --> 00:01:18,210
+alcohol الديهيد لو افترضنا أن هذا كان إيثانون بيصير
+
+16
+00:01:18,210 --> 00:01:22,630
+أسيتالديهيد لكن القاعدة العامة أن الـ primary
+
+17
+00:01:22,630 --> 00:01:27,090
+alcohols و الـ oxidize are converted to الديهيدز
+
+18
+00:01:27,090 --> 00:01:31,170
+واضح؟ الـ primary alcohols لما بنعملوا oxidation
+
+19
+00:01:31,170 --> 00:01:35,430
+بيصيروا الديهيدز الآن هنا بالذات في حالة الـ
+
+20
+00:01:35,430 --> 00:01:38,770
+primary alcohols في عندنا مشكلة بدنا نيجي في إلها
+
+21
+00:01:39,560 --> 00:01:47,260
+هذا الـ الديهيد ممكن يعمل عملية أكسدة إضافية تتحول
+
+22
+00:01:47,260 --> 00:01:50,640
+الـ H الموجودة في هذا الـ الديهيد إلى OH وبالتالي 
+
+23
+00:01:50,640 --> 00:01:55,360
+يصير acid إذا أنا صار عندي الـ primary alcohol ممكن
+
+24
+00:01:55,360 --> 00:01:58,760
+يصير الديهيد بس الـ الديهيد هذا إذا كانت أكسدة 
+
+25
+00:01:58,760 --> 00:02:05,040
+إضافية ممكن يصير acid الآن يصبح السؤال ما الذي
+
+26
+00:02:05,040 --> 00:02:09,680
+يجعلني أتحكم بالأكسدة؟ هل بدأ تجف بنص الطريق ولا 
+
+27
+00:02:09,680 --> 00:02:14,560
+بدأ تستمر للآخر؟ ما يساعدنا في هذا المكان هو
+
+28
+00:02:14,560 --> 00:02:20,040
+التحكم في العامل المؤكسد بمعنى في عندي عامل مؤكسد
+
+29
+00:02:20,040 --> 00:02:25,460
+اسمه PCC اختصاره PCC  بيريدينيا ميكلورا كروميت اسمه
+
+30
+00:02:25,460 --> 00:02:29,620
+هذا العامل المؤكسد إذا احنا بنستعمله بعملنا نص
+
+31
+00:02:29,620 --> 00:02:34,300
+الأكسدة بمشينا من الـ primer alcohol للـ الديهيد و
+
+32
+00:02:34,300 --> 00:02:42,660
+الـ البيوكفال PCC الآن إذا استعملت stronger oxidizing
+
+33
+00:02:42,660 --> 00:02:46,700
+agent عوامل مؤكسدة أقوى زي ما نستعمل برمنجنات
+
+34
+00:02:46,700 --> 00:02:53,500
+البوتاسيوم أو كيميان أوفور أو بوتاسيوم دايكروميت 
+
+35
+00:02:53,500 --> 00:02:58,980
+أو كروميك أسيد مدفّأ بسلفوريك أسيد كروميو تريوكسيد
+
+36
+00:02:58,980 --> 00:03:03,060
+مدفّأ بسلفوريك أسيد كله بنقول كروميك أسيد هذه عوامل 
+
+37
+00:03:03,060 --> 00:03:08,140
+مؤكسدة قوية لو استعملتهاللـ Primary Alcohol
+
+38
+00:03:08,140 --> 00:03:13,120
+مابتوقفش شوين عند الـ Aldehyde بتطلعني من الـ
+
+39
+00:03:13,120 --> 00:03:18,820
+Primary Alcohol للـ Acid على طول طبعا بالتأكيد لو 
+
+40
+00:03:18,820 --> 00:03:23,000
+الـ Aldehyde نفسه أخدته يعني أكسدته للـ Aldehyde و
+
+41
+00:03:23,000 --> 00:03:26,560
+فصلته و بعدين أخدته و بدى أكمل الأكسدة برضه لو
+
+42
+00:03:26,560 --> 00:03:30,960
+استعملت أي واحد من هدول بيكملني للـ Acid إذا أي
+
+43
+00:03:30,960 --> 00:03:38,710
+واحد من هدول التلاتة نفترض نقول KMnO4 سواء بدأت من
+
+44
+00:03:38,710 --> 00:03:43,950
+الـ primary alcohol أو بدأت من الـ aldehyde بيوصلني
+
+45
+00:03:43,950 --> 00:03:49,070
+لإيش؟ للـ acid، واضح؟ إذن بنقدر احنا نقول الآن أن
+
+46
+00:03:49,070 --> 00:03:54,090
+primary alcohols are oxidized to carboxylic acid
+
+47
+00:03:54,090 --> 00:04:02,300
+acids using مثلا KMnO4 بوتاسيوم برمنجنات أو
+
+48
+00:04:02,300 --> 00:04:05,920
+بوتاسيوم دايكروميت أو كروميك أسيد وبنفس الوقت
+
+49
+00:04:05,920 --> 00:04:11,800
+الديهيدز هم  أكسدتهم للأحماض باستخدام الاختصارات
+
+50
+00:04:11,800 --> 00:04:16,600
+اللازمة واضح؟ إذا أنا هنا متحكم في الأكسدة إذا 
+
+51
+00:04:16,600 --> 00:04:21,680
+بدي أوقف عند الـ الديهيد لوحده بدي الـ PCC بدي أمشي
+
+52
+00:04:21,680 --> 00:04:26,500
+عنه سواء مباشرة من الـ الكحول للأحماض أو من الـ الديهيد
+
+53
+00:04:26,500 --> 00:04:31,320
+اللي هو نص الطريق للأحماض باستعمل stronger oxidizing
+
+54
+00:04:31,320 --> 00:04:36,860
+agent واضحة هذه الفكرة؟ فلما تكملوا معادلة أكسدة
+
+55
+00:04:36,860 --> 00:04:41,100
+إذا لازم تتطلعوا إيش اللي موجود عندكم هل هو الـ
+
+56
+00:04:41,100 --> 00:04:45,680
+primary alcohol ولا لا؟ لحد الآن الكلام كله على إيش؟
+
+57
+00:04:45,680 --> 00:04:51,040
+الـ primary alcohol الآن لو أجينا للـ secondary
+
+58
+00:04:51,040 --> 00:04:55,380
+alcohol اتطلعوا على عيادة الـ alcohol secondary هاي الـ
+
+59
+00:04:55,380 --> 00:04:57,160
+carbon متصلة بكم carbon؟
+
+60
+00:04:59,830 --> 00:05:03,810
+وبنتابع نفس عملية الأكسدة نشيل الـ H والـ H
+
+61
+00:05:03,810 --> 00:05:07,570
+التانية ويصير عندي سي دبل بوند O بتكون عندي 
+
+62
+00:05:07,570 --> 00:05:13,250
+Ketone إذا الـ secondary alcohols بيعطوني Ketones
+
+63
+00:05:13,250 --> 00:05:15,710
+الـ Ketone اللي هي السي دبل بوند O اللي متصلة
+
+64
+00:05:15,710 --> 00:05:20,990
+بمجموعتين R الـ aldehyde بتكون متصلة بـ R و H الآن
+
+65
+00:05:20,990 --> 00:05:24,730
+أنا في الـ ketone مش ضايع hydrogen تم إبدالها
+
+66
+00:05:24,730 --> 00:05:29,820
+يعني مافيش عملية أكسدة تانية واضح؟ مافيش عندي خوف 
+
+67
+00:05:29,820 --> 00:05:33,940
+من أكسدة تانية فالعامل المؤكسد اللي عادة بيستعمله 
+
+68
+00:05:33,940 --> 00:05:39,320
+بالمرأة الـ KMnO4 و أخواتها زي الكروميك و أخواتها 
+
+69
+00:05:39,320 --> 00:05:44,960
+عارفين هم؟ فأكسدة الـ secondary alcohol بتعطينا 
+
+70
+00:05:44,960 --> 00:05:51,480
+كيتون ومافيش إمكانية لأكسدة إضافية لشئ إضافي
+
+71
+00:05:52,800 --> 00:05:55,940
+بتطلعوا معايا؟ الـ primary alcohol كان عندي كام 
+
+72
+00:05:55,940 --> 00:05:59,940
+هيدروجين على الكربون؟ واحدة تنتين والـ H اللي على
+
+73
+00:05:59,940 --> 00:06:03,200
+الأكسجين لما شيلنا تنتين طلعت H عشان هيك عملنا
+
+74
+00:06:03,200 --> 00:06:07,600
+أكسدة للـ الديهيد و بعدين بدلنا الـ H بـ أسيد الـ 
+
+75
+00:06:07,600 --> 00:06:12,660
+secondary alcohol two هيدروجين صار عندي كيتون و خلصت 
+
+76
+00:06:12,660 --> 00:06:18,540
+في الـ tertiary alcohol مافيش عندي غير الـ هيدروجين 
+
+77
+00:06:18,540 --> 00:06:24,470
+اللي على الـ O-H مافيش هيدروجين تاني طلعوا معايا؟
+
+78
+00:06:24,470 --> 00:06:27,270
+مافيش هيدروجين تاني أشيله وبناء على ذلك الـ
+
+79
+00:06:27,270 --> 00:06:31,310
+tertiary alcohol بيصيرلوش أكسدة عشان بدي أكسد أقل
+
+80
+00:06:31,310 --> 00:06:36,590
+شيء بدي أشيل two hydrogens هيدروجين مولكيول أو
+
+81
+00:06:36,590 --> 00:06:39,830
+يكون عندي هيدروجين على الكربون بعد هيك أعملها
+
+82
+00:06:39,830 --> 00:06:45,210
+إبداله فالـ tertiary alcohols don't undergo
+
+83
+00:06:45,210 --> 00:06:51,830
+oxidation مابيصيرلهاش أكسدة واضح؟ بيصير الإجمال
+
+84
+00:06:51,830 --> 00:06:56,580
+عندكم سهل من ذكرنا فيهم لما نقول الـ Oxidation of
+
+85
+00:06:56,580 --> 00:07:03,180
+alcohols، إيش بدنا نقول؟ الـ primary alcohols are
+
+86
+00:07:03,180 --> 00:07:08,820
+oxidized to aldehydes and then to acids
+
+87
+00:07:11,660 --> 00:07:15,060
+الناس مبصرلهمش للكيتونات مبصرلهمش للكيتونات مبصرلهمش 
+
+88
+00:07:15,060 --> 00:07:19,360
+للكيتونات مبصرلهمش للكيتونات مبصرلهمش للكيتونات
+
+89
+00:07:19,360 --> 00:07:23,160
+مبصرلهمش
+
+90
+00:07:23,160 --> 00:07:24,380
+للكيتونات مبصرلهمش للكيتونات مبصرلهمش للكيتونات
+
+91
+00:07:24,380 --> 00:07:27,860
+مبصرلهمش للكيتونات مبصرلهمش للكيتونات مبصرلهمش
+
+92
+00:07:27,860 --> 00:07:30,640
+للكيتونات مبصرلهمش للكيتونات مبصرلهمش للكيتونات
+
+93
+00:07:30,640 --> 00:07:37,100
+مبصرلهمش للكيتونات مبصرلهمش
+
+94
+00:07:37,100 --> 00:07:42,250
+للكيتونات مبصرلهمش لـ أشياء مهمة جدا في الكيمياء
+
+95
+00:07:42,250 --> 00:07:45,510
+العضوية وقبل شوية التفاعل اللي أخدناه قبل عشان 
+
+96
+00:07:45,510 --> 00:07:51,350
+تكونوا متذكرين لما كنا ناخد الـ alcohol نحوله لـ RX
+
+97
+00:07:51,350 --> 00:08:00,490
+الـ ROH كنا نحولها لـ RX آه أكيد والـ RX أخدنا الفصل 
+
+98
+00:08:00,490 --> 00:08:05,130
+السادس كله عن تفاعلات الـ RX واضح؟ يعني نص الـ
+
+99
+00:08:05,130 --> 00:08:09,530
+organic chemistry من وين بتطلع من الـ RX لأ كل الـ
+
+100
+00:08:09,530 --> 00:08:12,510
+organic chemistry من الـ alcohol احنا بنقول نصها من
+
+101
+00:08:12,510 --> 00:08:17,170
+الـ RX لإنه بتعمل SN1 و SN2 reaction الـ RX نفسها من
+
+102
+00:08:17,170 --> 00:08:20,270
+وين بتجيبها؟ الـ alcohol الـ aldehyde من وين ممكن
+
+103
+00:08:20,270 --> 00:08:23,470
+نجيبه؟ الـ alcohol الـ ketone من وين ممكن نجيبه؟ الـ
+
+104
+00:08:23,470 --> 00:08:27,820
+alcohol الـ acid من وين ممكن نجيبه؟ الـ alcohol فدائما
+
+105
+00:08:27,820 --> 00:08:32,240
+كان في مقولة عند الكيميائيين أنه إذا أخدت كيميائي
+
+106
+00:08:32,240 --> 00:08:35,580
+وحطيته بالصحراء هو والـ alcohol بيحضر منه كل
+
+107
+00:08:35,580 --> 00:08:41,120
+الأشياء الثانية فالـ alcohol يعتبر منطلق الـ organic
+
+108
+00:08:41,120 --> 00:08:44,980
+synthesis starting point يعني بإمكاني أحضر منه 
+
+109
+00:08:45,520 --> 00:08:49,520
+شغلات كتيرة واضح؟ وايكوا شايفين التفاعل طالما الـ 
+
+110
+00:08:49,520 --> 00:08:52,920
+alcohol حولته لـ RX لـ aldehyde لـ ketone لـ acid والـ 
+
+111
+00:08:52,920 --> 00:08:57,040
+RX بتتحول لـ 100 شغلة طبعا الـ acid بعدين بتتحول لـ 
+
+112
+00:08:57,040 --> 00:09:00,360
+ester الـ aldehyde بتتحول لـ أشياء تانية الـ ketone 
+
+113
+00:09:00,360 --> 00:09:04,120
+بتتحول لأشياء تانية كل هذا الكلام معتمد على إيش؟
+
+114
+00:09:04,120 --> 00:09:10,910
+أن أنا انطلقت من الـ alcohol هنا بنستعرض بس مجرد
+
+115
+00:09:10,910 --> 00:09:16,590
+استعراض بعض المركبات اللي فيهم dihydroxy or more
+
+116
+00:09:16,590 --> 00:09:22,630
+compounds يعني مش بس OH واحدة ممكن يكون عنده أكتر
+
+117
+00:09:22,630 --> 00:09:27,450
+من OH يعني مثلا لو كانوا تنتين معنا ذلك بتحكي عن 
+
+118
+00:09:27,450 --> 00:09:30,550
+ديول in general لو كانوا تلاتة
+
+119
+00:09:48,920 --> 00:09:55,520
+مار عليكم استعملناه في الـ antifreeze؟ لما كنا
+
+120
+00:09:55,520 --> 00:09:59,340
+نخلطه مع المية و يعمل melting point depression
+
+121
+00:09:59,340 --> 00:10:05,060
+لرديتر السيارة للمبردات أو السيارة الآن لاحظوا ليش
+
+122
+00:10:05,060 --> 00:10:10,660
+احنا بينفع هذا نستعمله مع المية و نحطه في رديتر
+
+123
+00:10:10,660 --> 00:10:14,320
+السيارة و بيعمل melting point depression لأن درجة
+
+124
+00:10:14,320 --> 00:10:18,140
+غليانه عالية مابتطيرش يعني ميزته لأنه بدي استعمله
+
+125
+00:10:18,140 --> 00:10:23,660
+في مية السيارة مطلوب منه عدة شغلات يكون رخيص أهم 
+
+126
+00:10:23,660 --> 00:10:27,880
+شيء بده يكون رخيص لأن أنا بستعمله للاستهلاك، شغلة 
+
+127
+00:10:27,880 --> 00:10:32,930
+تانية بده ما يتبخرش، شغلة تالتة بده ما يعمل مشاكل في
+
+128
+00:10:32,930 --> 00:10:37,830
+الموتور، بده ما يكون سام لاستعمال البشر العاديين كل
+
+129
+00:10:37,830 --> 00:10:41,410
+هذه المواصفات موجودة فيه فبخلطوا إيثيلين جليكول مع 
+
+130
+00:10:41,410 --> 00:10:45,070
+المية في الدول الباردة كتير خوف أن المية اللي في
+
+131
+00:10:45,070 --> 00:10:49,710
+السيارة تتجمد وبالتالي كل نظام التبريد ونظام 
+
+132
+00:10:49,710 --> 00:10:55,890
+التشغيل بختل تعرفوا طبعا ليش السيارات لازم نحطلها 
+
+133
+00:10:55,890 --> 00:11:00,120
+ميه ولا لأ؟ وحدة بده تشرحلنا ليش .. ليش بنحط 
+
+134
+00:11:00,120 --> 00:11:05,420
+للـ سيارة ميه؟ طب 
+
+135
+00:11:05,420 --> 00:11:10,940
+ليش المحرك بيسخن؟
+
+136
+00:11:10,940 --> 00:11:16,040
+طب أنا بديش .. أنا بديش .. بديش حرارة أنا بدي حركة
+
+137
+00:11:16,040 --> 00:11:21,200
+ليش .. ليش الطاقة ماكلها أحولها إلى حركة؟ أنا الآن 
+
+138
+00:11:21,200 --> 00:11:26,360
+ناجسني حرارة؟ ناجسني حرارة والسيارة تولع نار و
+
+139
+00:11:26,360 --> 00:11:31,780
+هتلوم مجرم ولا المطلوب مني الحركة؟ مطلوب مني
+
+140
+00:11:31,780 --> 00:11:37,040
+الحركة، مظبوط ولا لا؟ اه لكن هل بنقدر .. هل بنقدر 
+
+141
+00:11:37,040 --> 00:11:42,660
+احنا نحول كل الطاقة اللي في الوقود إلى طاقة يعني
+
+142
+00:11:42,660 --> 00:11:48,640
+..إلى شغل بدون ما يطلع عندي thermal energy تذكروا
+
+143
+00:11:48,640 --> 00:11:51,420
+الـ thermodynamic اللي أخدته فالحرارة بتطلع مش
+
+144
+00:11:51,420 --> 00:11:56,380
+بخاطرنا غصب عنها يعني بيقولوا أحسن motor يمكن
+
+145
+00:11:56,380 --> 00:12:01,020
+يشتغل على أربعين لخمسين في المية من المتوقع منه 
+
+146
+00:12:01,020 --> 00:12:06,600
+بعد ذلك كل الطاقة وين بتروح؟ بتطلع حرارة فالحرارة
+
+147
+00:12:06,600 --> 00:12:09,840
+عاملة عندي شغلتين مشكلتين المشكلة الأولى أن هي
+
+148
+00:12:09,840 --> 00:12:15,350
+بتخسرني وقود لأن أنا مابديش الحرارة والمشكلة 
+
+149
+00:12:15,350 --> 00:12:18,350
+الثانية أن أنا بدي أعالج الحرارة عشان السيارة ما 
+
+150
+00:12:18,350 --> 00:12:22,670
+تسخنش وما إلى ذلك فبنعمل نظام التبريد اللي هو نظام
+
+151
+00:12:22,670 --> 00:12:27,290
+المية اللي بتدور وبتاخد الحرارة وبتعرضها للهوا و
+
+152
+00:12:27,290 --> 00:12:31,810
+المروحة بتعمل عملية إشعال تبريد فالحرارة بالإجمال 
+
+153
+00:12:31,810 --> 00:12:35,520
+اللي في السيارة طالعة غصبًا عن الناس مش بخاطرهم
+
+154
+00:12:35,520 --> 00:12:39,920
+ياريت العلماء يقدروا يطلعوا كل الطاقة ناتجة من
+
+155
+00:12:39,920 --> 00:12:44,640
+الحرق يحولوها إلى حركة وما يطلعش عندهم حرارة مناهم
+
+156
+00:12:44,640 --> 00:12:50,060
+للعلماء بس مستحيل لا يمكن تحويل كل الطاقة إلى شغل
+
+157
+00:12:50,060 --> 00:12:53,480
+تذكروا الطاقة مش كانت تتحول إلى طاقة حرارة وطاقة
+
+158
+00:12:53,480 --> 00:13:00,660
+شغل بالمناسبة يمكن تحويل كل الطاقة إلى حرارة بقدر
+
+159
+00:13:00,660 --> 00:13:06,080
+بمعنى لو أنا جيبت مصباح ثابت وشغلته على طاقة معينة 
+
+160
+00:13:06,080 --> 00:13:09,380
+المصباح طاقة حرارية مافيش عندي ولا نوع من الحركة 
+
+161
+00:13:09,380 --> 00:13:14,820
+لحد ما تفضل بطارية بنقدر نفضل بطارية بشكل كامل بس
+
+162
+00:13:14,820 --> 00:13:18,200
+طلع عندي حرارة يعني كل الطاقة ممكن أحولها 100%
+
+163
+00:13:18,200 --> 00:13:22,420
+لحرارة بس الإشكالية الآن لو بدي أشغل موتور هل كل
+
+164
+00:13:22,420 --> 00:13:27,600
+الطاقة اللي في البطارية بقدر أحولها إلى طاقة حركة؟
+
+165
+00:13:28,330 --> 00:13:32,650
+الدليل هي أن لو حسيت بالموتور بعد شوية بلاقيه سخن 
+
+166
+00:13:32,650 --> 00:13:37,810
+إذا جزء من الطاقة بدون إرادة الإنسان اتحول إلى
+
+167
+00:13:37,810 --> 00:13:42,150
+حرارة هذه الحرارة هي اللي بتطلب من الإنسان دائمًا
+
+168
+00:13:42,150 --> 00:13:46,050
+مراوح بتلاقي الكمبيوتر فيه مروحة و مرات بتحسواها
+
+169
+00:13:46,050 --> 00:13:51,470
+بتطلع له الهواء السخن السيارة لها مروحة الآن نظام 
+
+170
+00:13:51,470 --> 00:13:54,850
+التبريد تبع المياه في الدول الباردة ماذا يحصل؟
+
+171
+00:13:54,850 --> 00:13:58,53
+
+201
+00:16:22,300 --> 00:16:28,140
+والـ resource lone عن ميتا والهيدروكينون على
+
+202
+00:16:28,140 --> 00:16:34,700
+البارا ولما يصيروا ثلاثة الـ بيروجالول المهم أنه 
+
+203
+00:16:34,700 --> 00:16:38,000
+تعرفوا في كثير مركبات وإلا في التطبيقات وإلا في
+
+204
+00:16:38,000 --> 00:16:40,800
+الـ biological system بالذات الكاتيكول دائما
+
+205
+00:16:40,800 --> 00:16:44,450
+هتصيروا تسمعوا في كورسات البيولوجيا عن كاتيكولامين
+
+206
+00:16:44,450 --> 00:16:49,730
+وما إلى ذلك لكن أقل تقدير اللي فوق بديكوا تكونوا
+
+207
+00:16:49,730 --> 00:16:55,190
+إيش؟ عارفين هم الموضوع
+
+208
+00:16:55,190 --> 00:17:01,450
+اللي هنا على تفاعلات الـ phenols مش الـ alcohols الـ
+
+209
+00:17:01,450 --> 00:17:05,570
+phenols أهم شيء تعرفوا أنه لما بيكون عندي أنا
+
+210
+00:17:05,570 --> 00:17:10,970
+phenol الـ OH أخذته مواصفات إليه إيش مواصفات الـ
+
+211
+00:17:10,970 --> 00:17:20,270
+OH؟ activating ولا deactivating؟ activating
+
+212
+00:17:20,270 --> 00:17:23,430
+والشغل
+
+213
+00:17:23,430 --> 00:17:30,110
+الثاني ortho para directing group  الـ OH
+
+214
+00:17:30,110 --> 00:17:33,990
+-Activating و Ortho-para-directing group بعد ذلك
+
+215
+00:17:33,990 --> 00:17:37,590
+تعمل التفاعلات الاروماتيك سبستيوشن عادي يعني لو
+
+216
+00:17:37,590 --> 00:17:40,390
+استعملت أثيل كلوريد أو ألومنيوم كلوريد سيضع
+
+217
+00:17:40,390 --> 00:17:42,590
+مجموعة أثيل كلوريد أو أثيل كلوريد أو أثيل
+
+218
+00:17:42,590 --> 00:17:44,310
+كلوريد أو أثيل كلوريد أو أثيل كلوريد أو أثيل
+
+219
+00:17:44,310 --> 00:17:45,030
+كلوريد أو أثيل كلوريد أو أثيل كلوريد أو أثيل
+
+220
+00:17:45,030 --> 00:17:45,150
+كلوريد أو أثيل كلوريد أو أثيل كلوريد أو أثيل
+
+221
+00:17:45,150 --> 00:17:45,410
+كلوريد أو أثيل كلوريد أو أثيل كلوريد أو أثيل
+
+222
+00:17:45,410 --> 00:17:45,730
+كلوريد أو أثيل كلوريد أو 
+
+223
+00:17:50,500 --> 00:17:54,740
+وممكن تضيف الـ H2SO4 وتضيف الـ Nitro على البارا
+
+224
+00:17:54,740 --> 00:17:59,440
+لو ضيفت الـ Br من كثر ما هي activating بتضيف على
+
+225
+00:17:59,440 --> 00:18:05,860
+الثلاث مواقع كمان مش على موقع واحد واضح؟ فلو جيبنا
+
+226
+00:18:05,860 --> 00:18:10,500
+لكم إكمال أي معادلة منطلقين من الـ phenol اللي هو
+
+227
+00:18:10,500 --> 00:18:15,020
+المركب اللي فيه الـ OH بتكون تتذكر أن التفاعل سريع و
+
+228
+00:18:15,020 --> 00:18:18,260
+التفاعل Ortho-para
+
+229
+00:18:19,660 --> 00:18:25,460
+directing group موجودة فيه على الفينولز الآن هنا
+
+230
+00:18:25,460 --> 00:18:31,840
+بيجينا شغل أن مركبات الفينولز مركبات الفينولز لها
+
+231
+00:18:31,840 --> 00:18:37,480
+تطبيق كثير مهم جدا لها تطبيق كثير مهم جدا لو بس
+
+232
+00:18:37,480 --> 00:18:40,560
+بدكم تضربوا على الإنترنت في الـ google search
+
+233
+00:18:40,560 --> 00:18:47,400
+هيطلع لكم عشرات الآلاف من الأبحاث بس اكتبوا Antioxidant
+
+234
+00:18:47,400 --> 00:18:52,800
+Phenols هي مواد مضادة للأكسدة وموجودة في مصادر
+
+235
+00:18:52,800 --> 00:18:57,180
+طبيعية ومحضر منها مواد صناعية يعني لما بدنا الأكل
+
+236
+00:18:57,180 --> 00:19:01,260
+ما يخربش المعلبات ما تخربش كل هذا الكلام بدنا نحط
+
+237
+00:19:01,260 --> 00:19:07,780
+عليه إيش؟ مادة مضادة للتأكسد Antioxidant من أشهر
+
+238
+00:19:07,780 --> 00:19:13,240
+الـ Antioxidants على الإطلاق الفينولز واضح؟ عادة
+
+239
+00:19:13,240 --> 00:19:16,140
+الفينولز لو بده يتطلع على هذا الهيدروكينون
+
+240
+00:19:16,140 --> 00:19:20,960
+الهيدروكينون واجأه فعله مع مادة مؤكسدة مع مادة
+
+241
+00:19:20,960 --> 00:19:24,820
+مؤكسدة بتأكسد بيفقد طبعا هيدروجنتين بيصير بهذا
+
+242
+00:19:24,820 --> 00:19:29,120
+الشكل 1,4-benzoquinone و1,4-benzoquinone
+
+243
+00:19:29,120 --> 00:19:35,000
+إذا لاحظوا هنا أن الفينولز الفينولز they undergo
+
+244
+00:19:35,000 --> 00:19:36,220
+oxidation
+
+245
+00:19:38,450 --> 00:19:45,110
+وين بتصير فكرة أن هم مواد مضادين للأكسدة يعني كيف
+
+246
+00:19:45,110 --> 00:19:52,010
+بيشتغل الفينول كمادة مضادة للأكسدة هو بيحب يتأكسد
+
+247
+00:19:52,010 --> 00:19:56,810
+بسرعة واضح بيحب يتأكسد بسرعة بناء على ذلك لو كان
+
+248
+00:19:56,810 --> 00:20:02,910
+عندي مثلا الطعام نفترض مرتدلة أو علبة لحمة ومحطوط
+
+249
+00:20:02,910 --> 00:20:08,580
+فيها مادة فينول اللي هي المادة المضادة للأكسدة أو
+
+250
+00:20:08,580 --> 00:20:13,760
+علبة لحمة أو مرتدلة ولا يوجد فيها مادة فينول نحن
+
+251
+00:20:13,760 --> 00:20:18,040
+نعلبها وما إلى ذلك لكن نفترض أن دخلت عوامل مؤكسدة
+
+252
+00:20:18,040 --> 00:20:22,900
+أو حتى أكسجين الجو الأكسجين هذا تبع الجو أو غيره
+
+253
+00:20:22,900 --> 00:20:30,160
+لو أكسد اللحمة هيطلع لي مواد سامة ذات رائحة سيئة
+
+254
+00:20:30,160 --> 00:20:35,040
+الآن إذا ما فيش غير اللحمة هي Oxidize وهيطلع المواد
+
+255
+00:20:35,040 --> 00:20:38,500
+السامة والرائحة السيئة وكل هذا الكلام طب لو كنا
+
+256
+00:20:38,500 --> 00:20:45,140
+خلطينها بشوية Antioxidant الـ Antioxidant بيحب الـ Oxidize
+
+257
+00:20:45,140 --> 00:20:49,340
+أكثر من اللحمة بناء على ذلك لو اجت شوية مادة م
+
+258
+00:20:49,340 --> 00:20:54,620
+Oxidize أو دخل شوية Oxygen وين هتصير الـ Oxidize على
+
+259
+00:20:54,620 --> 00:20:59,300
+الفينول الفينول هتعطي هيدروكينون أو مشتقاتها الآن
+
+260
+00:20:59,300 --> 00:21:03,620
+انتبهوا معي إيش اللي بيصير عندكم لما أنا بدي آجي
+
+261
+00:21:03,620 --> 00:21:07,940
+أقول أن في عندي مرتدلة نفترض المرتدلة أو اللحمة
+
+262
+00:21:07,940 --> 00:21:13,520
+كويس مفيدة حطيت عليها مادة antioxidant المادة الـ
+
+263
+00:21:13,520 --> 00:21:16,600
+antioxidant لازم تكون إيش safe
+
+264
+00:21:19,140 --> 00:21:23,680
+لازم تكون آمنة ما تضرّش الصحة طب لو دخل شوية أكسجين
+
+265
+00:21:23,680 --> 00:21:28,240
+وهذه أكسدة لمادة ثانية المادة الثانية هتصير برضه
+
+266
+00:21:28,240 --> 00:21:34,080
+جوا الأكل إذا إيش لازم تكون برضه تكون safe بمعنى
+
+267
+00:21:34,080 --> 00:21:38,460
+أن المفروض الـ antioxidant لا يكون له ريحة ولا له
+
+268
+00:21:38,460 --> 00:21:45,820
+ضرر والناتج عن عملية أكسدته إذا حصل لا يكون له ضرر
+
+269
+00:21:45,820 --> 00:21:51,340
+ولا له ريحة واضح؟ هذا ما يحدث بالظبط عندما نضع
+
+270
+00:21:51,340 --> 00:21:55,300
+فينوليك كومباوندز محددة سواء من مصادر طبيعية أو
+
+271
+00:21:55,300 --> 00:22:00,060
+صناعية فهي تتلجأ صدمة الأكسدة لما تتحول لمواد
+
+272
+00:22:00,060 --> 00:22:03,860
+المواد اللي بتتحول إليها ليست مواد ضارة أو ذات
+
+273
+00:22:03,860 --> 00:22:08,760
+رائحة واللحوم أو المواد اللي بنعلبها بتبقى بدون
+
+274
+00:22:08,760 --> 00:22:15,160
+ما يحصل عليها عملية الأكسدة من المراكبات الموجودة
+
+275
+00:22:15,160 --> 00:22:20,550
+في السوق وتستعمل واضح؟ من المركبات الموجودة في
+
+276
+00:22:20,550 --> 00:22:24,810
+السوق وتستعمل مرات لو كنت تتطلع على بعض المعلبات
+
+277
+00:22:24,810 --> 00:22:28,650
+تجد مكتوب اسم هذه المواد المواد اللي بيسميها
+
+278
+00:22:28,650 --> 00:22:35,330
+الـ BHA والـ BHT إيش الـ BHA؟ إذا بتطلعوا هنا هذا
+
+279
+00:22:35,330 --> 00:22:40,370
+مركب فيه شايفين؟ هذا المحور الأساسي عليه O
+
+280
+00:22:40,370 --> 00:22:43,670
+-Methyl أو عليه Tert-butyl group هذه إيش
+
+281
+00:22:43,670 --> 00:22:46,730
+المجموعة؟ C حاملة ثلاثة Tert-butyl
+
+282
+00:22:52,140 --> 00:22:57,700
+هيدروكسي لأنه في الـ OH والـ  ether في الـ anisole
+
+283
+00:22:57,700 --> 00:23:03,200
+فنصير كله Butylated hydroxyanisole نسفنا للـ
+
+284
+00:23:03,200 --> 00:23:08,740
+anisole للـ ether Butylated وهيدروكسي والمركب
+
+285
+00:23:08,740 --> 00:23:09,500
+اللي عندي إيش
+
+286
+00:23:14,060 --> 00:23:19,000
+المركبات اللي هناك برضه فيها Butyl group وفيها
+
+287
+00:23:19,000 --> 00:23:24,080
+الهيدروكس لكن لو أخذت الحلقة ما عدا ذلك هنا إيش
+
+288
+00:23:24,080 --> 00:23:29,180
+الحلقة؟ هنا الحلقة كانت anisole وعليها الـ butyl والـ
+
+289
+00:23:29,180 --> 00:23:34,020
+هيدروكس هنا toluene وbutyl وهيدروكس فبيصير اسمه
+
+290
+00:23:34,020 --> 00:23:42,670
+Butylated hydroxytoluene باختصار BHT هذه المركبات كثير
+
+291
+00:23:42,670 --> 00:23:48,450
+الاستعمالات كـ Antioxidants غالب الكلام بالنسبة لـ
+
+292
+00:23:48,450 --> 00:23:53,570
+90% وأكثر أنها آمنة وSafe بعض الأبحاث بتقول أنه
+
+293
+00:23:53,570 --> 00:24:01,130
+يمكن أنها مخاطر واضح؟ لكن لحد الآن وجهة النظر أقوى
+
+294
+00:24:01,130 --> 00:24:08,000
+مع أنه ما فيش مخاطر مؤكدة 100% طالعة منها في البعض
+
+295
+00:24:08,000 --> 00:24:12,500
+بيقول والله يمكن المخاطر طالع منه طبعا ليش العلماء
+
+296
+00:24:12,500 --> 00:24:18,180
+ما بيقدروش يكون عندهم جواب يكون عندهم جواب نهائي
+
+297
+00:24:18,180 --> 00:24:22,760
+أحيانا على بعض الشغلات لسبب بسيط أنه يعني بني آدم
+
+298
+00:24:22,760 --> 00:24:29,260
+مثلا صار عنده سرطان اللي بيصير أنه ممكن بعض الناس
+
+299
+00:24:29,260 --> 00:24:33,150
+يقول أكيد هذا من الـ Antioxidant لكن الناس الثانية
+
+300
+00:24:33,150 --> 00:24:35,990
+اللي بيقولوا هو بس أخذ في الدنيا Antioxidants مع
+
+301
+00:24:35,990 --> 00:24:39,770
+المرتدين اللي هو اللي بيأكل ميت شغلة بيشرب شراب
+
+302
+00:24:39,770 --> 00:24:45,870
+عليه مواد ملونة وبيستنشق سجائر وما إلى ذلك.. فبيصير
+
+303
+00:24:45,870 --> 00:24:50,370
+عندي عوامل كثيرة، الآن هنا بتصير الصعوبة أنه هل
+
+304
+00:24:50,370 --> 00:24:55,710
+المشكلة فعلا اجت عنده؟ من الـ Antioxidant ولا من
+
+305
+00:24:55,710 --> 00:25:00,070
+أشياء ثانية وهذا الكلام اللي بده كثير تجارب وكثير
+
+306
+00:25:00,070 --> 00:25:06,650
+دراسات طبعا برضه صعب ديروا بالكم التعميم يعني مرات
+
+307
+00:25:06,650 --> 00:25:11,810
+بيجي عالم بيروح بيجيب له شوية فئران ولا شوية قرود وكل 
+
+308
+00:25:11,810 --> 00:25:16,870
+يوم بيعطيهم جرعة عالية منها الـ Antioxidant عمدا
+
+309
+00:25:16,870 --> 00:25:20,170
+شهرين، ثلاثة، أربعة في الآخر بيقول والله هيوم
+
+310
+00:25:20,170 --> 00:25:25,430
+يصيبه بالسرطان، كويس هل البني آدم يا ترى لما بياخد
+
+311
+00:25:25,430 --> 00:25:30,270
+هذه بنسبة محددة قليلة جدا وعلى فترات بعيدة هيكون
+
+312
+00:25:30,270 --> 00:25:36,090
+لها الأثر زي ما كل يوم تعالَى؟ وبالتالي لما تسمعوا
+
+313
+00:25:36,090 --> 00:25:40,650
+أن العلماء في كثير.. في كثير مواد مش واصلين إلى 
+
+314
+00:25:40,650 --> 00:25:44,870
+نتيجة نهائية هل هي فعلا ضارة أو لأ بسبب مثل هذه
+
+315
+00:25:44,870 --> 00:25:47,910
+الدراسات يعني بتلاقوا ناس بيجوا.. بيحكوا عن
+
+316
+00:25:47,910 --> 00:25:54,930
+السكرين ولا يمكن السكرين له أثر ضار لكن لليوم
+
+317
+00:25:54,930 --> 00:26:02,470
+السكرين في السوق ولا لأ لأنه مش ثابت بشكل قاطع أنه
+
+318
+00:26:02,470 --> 00:26:09,710
+فيه سمية أو نوع عالي من الضرر واضح؟ ما حدش بيقدر
+
+319
+00:26:09,710 --> 00:26:14,310
+ينفي 100% لكن كثير ناس بتقدر تنفي فوق نسبة 90 أو
+
+320
+00:26:14,310 --> 00:26:21,310
+95% إنه لحتى الأقل تعتبر بمنطق العلم هذه الأشياء
+
+321
+00:26:21,310 --> 00:26:25,970
+إيش مالها؟ safe safe خلّيني أقول.. ما بنعش نقول
+
+322
+00:26:25,970 --> 00:26:29,750
+مفيدة، نقول آمنة يعني يمكن مش كتير إلا فائدة غير
+
+323
+00:26:29,750 --> 00:26:32,850
+أنه تمنع الـ accident بس يعني مش زي الـ vitamin ولا
+
+324
+00:26:32,850 --> 00:26:38,310
+شيء أن بدها تفيدني أنا كجسم، لا يعني لما أنا بأكل
+
+325
+00:26:38,310 --> 00:26:43,130
+الطعام الطازج أنا بكون بحاجة لها يعني اللي عنده
+
+326
+00:26:43,130 --> 00:26:49,130
+مثلا لحم طازجة وبده يتناولها ويعمل همبرجر من
+
+327
+00:26:49,130 --> 00:26:53,510
+لحم طازجة ويأكل بلزم ويكون ضايف Antioxidant لا
+
+328
+00:26:53,510 --> 00:26:57,310
+مابلزمش أنا ما فيش منها فائدة بس أنا بحطها لتجنب
+
+329
+00:26:57,310 --> 00:27:03,410
+أضرار إذا بتلاحظوا من المركبات الطبيعية مثلا الـ
+
+330
+00:27:03,410 --> 00:27:09,700
+Vitamin E وإذا بتلاحظوا الـ Vitamin E بغض النظر عن
+
+331
+00:27:09,700 --> 00:27:13,320
+كبر الجزء تبعه جزء الـ Antioxidation اللي فيه
+
+332
+00:27:13,320 --> 00:27:18,360
+مرتبط بوجود الـ OH اللي عليه أن هو يعتبر Phenolic
+
+333
+00:27:18,360 --> 00:27:24,400
+Compound هم لاحظين هنا يعني هو صح كبير وما إلى
+
+334
+00:27:24,400 --> 00:27:32,280
+ذلك لكن بيسموه Natural Phenolic Antioxidant فمحور
+
+335
+00:27:32,280 --> 00:27:42,250
+عمله كـ Antioxidant في وجود الـ OH تبع الفينول ننتقل
+
+336
+00:27:42,250 --> 00:27:50,210
+إلى العائلة الثانية من المركبات اسمها الـ Thiols
+
+337
+00:27:53,800 --> 00:27:59,600
+Sulfur بدل الـ O S H واضح فلاحظوا التسمية البسيطة
+
+338
+00:27:59,600 --> 00:28:04,600
+لما كان أكون عندي CH3OH إيش كنت أسامي المركب مثال
+
+339
+00:28:04,600 --> 00:28:11,520
+عليه لو صارت S H بسميه ميثان ثيول وهنا مثلا بيوتان
+
+340
+00:28:11,520 --> 00:28:19,080
+ثيول هذا الفينول بيصير ثيوفينول اسم ثاني بيستعملوه
+
+341
+00:28:19,080 --> 00:28:23,730
+لهذه المركبات لو كنا بدنا ناخذه بالـ common name لو
+
+342
+00:28:23,730 --> 00:28:29,790
+كانت هنا مثل أو OH كنا نقول مثل Alcohol مثل
+
+343
+00:28:29,790 --> 00:28:33,550
+alcohol الآن بدنا الـ alcohol أنا بحطه مركبتان
+
+344
+00:28:33,550 --> 00:28:41,050
+مركبتان فبيصير هذا مثل مركبتان بيوتيل مركبتان فينول
+
+345
+00:28:42,190 --> 00:28:46,710
+مركبتان وهكذا دائما وأبدا إذا قرأته اسم أي مركب
+
+346
+00:28:46,710 --> 00:28:51,130
+لاحظته الاسم فيه كلمة ثيول أو مركبتان اعرف أن هذا
+
+347
+00:28:51,130 --> 00:28:56,530
+مركب Sulfur واضح يعني لما نقول ثيو compounds أو
+
+348
+00:28:56,530 --> 00:29:00,170
+مركبتان compounds معناه ذلك احنا بنحكي عن مركبات
+
+349
+00:29:00,170 --> 00:29:06,460
+إيش الكبريت الشغلتين بتلاقوهم ثيول ومركبتان ثيول
+
+350
+00:29:06,460 --> 00:29:14,120
+مركبتان إذا قلنا مركبتان مركبات مركبات مركبات مركبات
+
+351
+00:29:14,120 --> 00:29:14,260
+مركبات مركبات مركبات مركبات مركبات مركبات مركبات
+
+352
+00:29:14,260 --> 00:29:15,020
+مركبات مركبات مركبات مركبات مركبات مركبات مركبات
+
+353
+00:29:15,020 --> 00:29:16,080
+مركبات مركبات مركبات مركبات مركبات مركبات مركبات
+
+354
+00:29:16,080 --> 00:29:29,320
+مركبات مركبات مركبات مركبات مركبات 
+
+355
+00:29:29,430 --> 00:29:34,150
+Sulfide Sulfide في إيثيل وإيثيل شو بيصير اسم المركب
+
+356
+00:29:34,150 --> 00:29:39,910
+إيثيل Sulfide أو داى إيثيل Sulfide مرات كثير الداى
+
+357
+00:29:39,910 --> 00:29:47,150
+بالعربية يعني لو كان هذا إيثر بالـ O إيش بيسموه؟ داى
+
+358
+00:29:47,150 --> 00:29:53,000
+إيثيل إيثر ومرات كثير بيقولوا عنه إيثيل إيثر واضح؟ لما
+
+359
+00:29:53,000 --> 00:29:57,180
+يكون المركبات متماثل بيسموه Diethyl ether أو
+
+360
+00:29:57,180 --> 00:30:00,660
+ethyl ether نفس الشيء مثلا في الـ Dimethyl
+
+361
+00:30:00,660 --> 00:30:04,580
+sulfate ومرات بيسموها نفسها methyl sulfate يعني
+
+362
+00:30:04,580 --> 00:30:14,900
+بالعربية الـ Die في الـ common nomenclature لأ
+
+363
+00:30:14,900 --> 00:30:19,660
+هو بيكون S double bond O CH3CH3 اللي هو الـ Die
+
+364
+00:30:19,660 --> 00:30:20,080
+methyl
+
+365
+00:30:26,440 --> 00:30:33,020
+بناخد الـ RX مع SH- بيعطينا RSH العملية سهلة
+
+366
+00:30:33,020 --> 00:30:39,820
+الـ RX مع SH- بيصير Substitution ولما نقول الـ RX
+
+367
+00:30:39,820 --> 00:30:43,620
+primary مثلا والـ SH- negative strong nucleophile
+
+368
+00:30:43,620 --> 00:30:49,230
+شو الميكانزم اللي تتوقعوها SN2 لو كان مصدر مع
+
+369
+00:30:49,230 --> 00:30:53,390
+نيوكليوفيل قوية بتتوقعوا أنه يتم عندي SN2
+
+370
+00:30:53,390 --> 00:30:58,610
+ميكانيزم واضح؟ أخذنا احنا كمان شغلة قولنا أن
+
+371
+00:30:58,610 --> 00:31:03,790
+الـ Thiols
+
+401
+00:33:35,340 --> 00:33:39,840
+هو المسؤول for the odor of garlic هو المسؤول عن
+
+402
+00:33:39,840 --> 00:33:47,190
+رائحة الثوم لـ  garlic family تبعتها الأليوم واضح؟ الآن
+
+403
+00:33:47,190 --> 00:33:53,270
+لاحظوا معايا، إذا أنا أكسدت الـ .. الـ .. التيول
+
+404
+00:33:53,270 --> 00:33:57,370
+بيصير دايسلفايت، طب إذا عملتي العملية المعاكسة،
+
+405
+00:33:57,370 --> 00:34:01,410
+reduction، بارود بيكسروا، الـ دايسلفايت are reduced
+
+406
+00:34:01,410 --> 00:34:06,970
+to thyols، الـ thiols are oxidized to دايسلفايت،
+
+407
+00:34:06,970 --> 00:34:13,290
+هذه بالمناسبة انتبهوا معايا أكثر أكثر أكثر أكثر أكثر
+
+408
+00:34:13,290 --> 00:34:15,350
+أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر
+
+409
+00:34:15,350 --> 00:34:15,430
+أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر
+
+410
+00:34:15,430 --> 00:34:15,970
+أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر أكثر
+
+411
+00:34:15,970 --> 00:34:23,230
+أكثر أكثر أكثر أكثر أكثر أكثر أكثر 
+
+412
+00:34:24,580 --> 00:34:30,100
+ليش؟ لأن اللي بيمسك الجزيئات زي البروتينات وغيرها
+
+413
+00:34:30,100 --> 00:34:34,500
+نوعين من الـ bonding الـ hydrogen bonding و الـ
+
+414
+00:34:34,500 --> 00:34:37,880
+disulfide bonding يعني لما يكون البروتين عامل زي
+
+415
+00:34:37,880 --> 00:34:42,100
+هيك زي helix مثلا بيكون طالع من هنا SH و من هنا
+
+416
+00:34:42,100 --> 00:34:47,020
+SH بيعملوا oxidation بيعملوا disulfide bond
+
+417
+00:34:47,020 --> 00:34:52,960
+فبيصير اللي ممسك البروتينات هو إيش؟ الـ disulfide
+
+418
+00:34:52,960 --> 00:34:57,800
+bond واضح اللي ممسك البروتينات هو الـ disulfide
+
+419
+00:34:57,800 --> 00:35:03,780
+bond  طبين مهمين جدا هذا الكلام له تطبيقين و
+
+420
+00:35:03,780 --> 00:35:10,240
+تطبيقين مهمين جدا اتخيلوا شغل ممسك بروابط لو يا
+
+421
+00:35:10,240 --> 00:35:17,420
+تورا الروابط فك جزء منها شو بده يصير؟ بتفرد بتفرد
+
+422
+00:35:17,420 --> 00:35:24,490
+هيك عن بعض بتشوفوا الخشب زي الـ Sandwich هذا اللي
+
+423
+00:35:24,490 --> 00:35:28,710
+بيعملوا منه الخزانات وما إلى ذلك أحياناً بتشوفوا
+
+424
+00:35:28,710 --> 00:35:34,610
+لما يتعرض للميه كيف بيفشفش هيك أو بيلفش وما إلى
+
+425
+00:35:34,610 --> 00:35:39,930
+ذلك تقريبا تقريبا نفس الشغلة تقريبا نفس الشغلة وين
+
+426
+00:35:39,930 --> 00:35:47,140
+بتصير في العين في العين في القرنية تبعون العين وما
+
+427
+00:35:47,140 --> 00:35:52,460
+إلى ذلك اللي بيصير بالظبط كأنه هذه ممسكة
+
+428
+00:35:52,460 --> 00:35:57,820
+نفترض ماخدة مساحها الجد وممسكة بـ sponge كلها
+
+429
+00:35:57,820 --> 00:36:02,080
+ممسكة بـ sponge الآن لو يا ترى الـ sponge
+
+430
+00:36:02,080 --> 00:36:08,500
+تبعتها اتكسرت شو بيصير فيها كانت زي هيك شايفين
+
+431
+00:36:08,500 --> 00:36:14,900
+انتوا معاه اتكسرت الـ sponge بتنفش وما إلى ذلك
+
+432
+00:36:14,900 --> 00:36:20,240
+طبعا كونهم هدولة من خلالهم الأشعة بدأت تمشي معناه
+
+433
+00:36:20,240 --> 00:36:24,980
+ذلك هو عملية الإبصار اختلت لو أنا بدي أرجع الوضع
+
+434
+00:36:24,980 --> 00:36:31,840
+الطبيعي إيش بدي أعمل؟ إيش بدي أعمل؟ بدي أرجع أكون
+
+435
+00:36:31,840 --> 00:36:37,550
+هذه الروابط بدي أرجع أكون هذه الروابط مظبوط ولا لا؟
+
+436
+00:36:37,550 --> 00:36:43,210
+أنا عشان أكون زي هيك ممسكين بـ SS bonds اختلطت الـ SS
+
+437
+00:36:43,210 --> 00:36:48,810
+bonds نفخت بدي أرجع أكونهم بترجع طبيعية الآن
+
+438
+00:36:48,810 --> 00:36:53,580
+السؤال كيف بدهم يرجعوا يكونوهم؟ هذه من أحدث من أحدث
+
+439
+00:36:53,580 --> 00:36:59,940
+الطرق في علاج المشاكل للعين والآن لدينا بلازر مع
+
+440
+00:36:59,940 --> 00:37:05,420
+أوزون بالأشعة بيضغطوا عليها أوزون الـ أوزون عامل
+
+441
+00:37:05,420 --> 00:37:10,160
+مؤكسد بيعملولها أكسدة هذه من أحدث الطرق اللي صار
+
+442
+00:37:10,160 --> 00:37:15,580
+في غزة طبيب أخصائي وبيشتغلها في مركز البصريات اللي
+
+443
+00:37:15,580 --> 00:37:19,830
+عملوا اللي عملته أظن منظمة المؤتمر الإسلامي يعني
+
+444
+00:37:19,830 --> 00:37:24,810
+شغل حديث جدا أن أنت تيجي تقول ليش هذه نفشت و أفرجت
+
+445
+00:37:24,810 --> 00:37:29,990
+لأن الـ di-sulfate sponge إيش صارلها؟ اتكسرت كيف
+
+446
+00:37:29,990 --> 00:37:35,990
+بدي أرجعها؟ بدي أعمل oxidation بدي أرجع الـ thiol إلى
+
+447
+00:37:35,990 --> 00:37:42,290
+الـ di-sulfate هذا تطبيق في العينين في تطبيق تاني بس
+
+448
+00:37:42,290 --> 00:37:47,830
+مش في العينين عادي في النساء معظمها اه وين هذا
+
+449
+00:37:47,830 --> 00:37:53,210
+التطبيق التاني؟ وين التطبيق التاني في الشعر؟ الشعر
+
+450
+00:37:53,210 --> 00:37:58,630
+إذا بتحسوا أنه مش زي الخيط مرات في أشياء أنتو
+
+451
+00:37:58,630 --> 00:38:02,850
+بتنتبهوا الـ hash بمعنى لو أنا أخدت شعرة .. شعرة
+
+452
+00:38:02,850 --> 00:38:07,090
+طولها خمسة سنتيم ما بديش أقول أنها طويلة كثير أربعة
+
+453
+00:38:07,090 --> 00:38:10,490
+خمسة سنتيم مرات و .. و مثل كأنه واحد زي هيك ممكن
+
+454
+00:38:10,490 --> 00:38:14,730
+الشعرة تكون بهذا الشكل بتبقى عدل مظبوط ولا لأ؟
+
+455
+00:38:14,730 --> 00:38:18,310
+شعرها طوله خمسة سنتي وأنا ماسكها مظبوط ولا لأ؟
+
+456
+00:38:18,310 --> 00:38:22,970
+أربع خمسة سنتي أو لو هيك ممكن تكون عدل اتخيلوا لو
+
+457
+00:38:22,970 --> 00:38:28,610
+أنتم جيبتوا خيط طوله أربع سنتي بتقدروا تمسكوه
+
+458
+00:38:28,610 --> 00:38:34,290
+يكون عدل لفوق؟ إذا في فرق بين الشعر والخيط العادي
+
+459
+00:38:34,290 --> 00:38:39,190
+أن أجوى الشعرة ولا الخيط الشعرة الشعرة بتظهر بهذا
+
+460
+00:38:39,190 --> 00:38:43,890
+الشكل مظبوط ولا لأ؟ طب إيش اللي ممسك الشعرة بهذا
+
+461
+00:38:43,890 --> 00:38:48,130
+الشكل أن الشعرة فيها الـ di sulfide point بتيجي من
+
+462
+00:38:48,130 --> 00:38:51,570
+اللي هو الـ amino acid السبيل اللي فيه SOS
+
+463
+00:38:51,570 --> 00:38:55,170
+فالبروتينات تبعت الشعرة بتقدروا تتخيلوا هيك
+
+464
+00:38:55,170 --> 00:39:00,690
+البروتين في الشعرة ممسك بـ di sulfide point هذا اللي
+
+465
+00:39:00,690 --> 00:39:05,430
+بيجوّشه إيش اللي بيجوّش شعر .. الآن شوفوا إيش اللي
+
+466
+00:39:05,430 --> 00:39:10,230
+بيصير عندنا .. ماحدش في الدنيا راضي بنصيبه .. إيش
+
+467
+00:39:10,230 --> 00:39:13,510
+يعني ماحدش راضي بنصيبه؟ اللي شعرهم .. ما شاء الله
+
+468
+00:39:13,510 --> 00:39:17,930
+عنه يا محلاه .. عدل وما .. إلى ذلك بدهم يخلوهم لو
+
+469
+00:39:17,930 --> 00:39:23,890
+لو .. كرلي والـ .. curly .. و الشعرهم الـ curly هذا
+
+470
+00:39:23,890 --> 00:39:28,590
+بده بيخلوه عدل بتلاقوا الناس وكله برزق الكوافير
+
+471
+00:39:28,590 --> 00:39:32,750
+الشعر عدل بيروح على الكوافير بيقولوا بالله لو لو
+
+472
+00:39:32,750 --> 00:39:37,390
+ليه والشعرهم لو لو بيروح بيعمل عملية إيش كوي الشعر
+
+473
+00:39:37,390 --> 00:39:41,510
+بيسموها مظبوط ولا لأ؟ بتشوف ناس هيك مربين شعرهم طب
+
+474
+00:39:41,510 --> 00:39:46,260
+أنتم شعركم كله هيك كان؟ إيش اللي بيصير هنا؟
+
+475
+00:39:46,260 --> 00:39:50,440
+بيشتغلوا عملية كيميائية بحتة للكوافير بيشتغلوا
+
+476
+00:39:50,440 --> 00:39:55,840
+عملية كيميائية بحتة نفترض إنه شعر كان عدل، بييجوا
+
+477
+00:39:55,840 --> 00:40:02,200
+ويحطوا عليه reducing agent عامل مختزل، بيروحوا و
+
+478
+00:40:02,200 --> 00:40:08,610
+بيكسروا لما يكسروا .. شو بتصير الشعرة؟ رخوة،
+
+479
+00:40:08,610 --> 00:40:13,510
+بياخدوها على النار و بيلووها، بيعملوها شكل جديد
+
+480
+00:40:13,510 --> 00:40:17,110
+لأنه بالوضع الطبيعي مش سهل أنهم يعملوا أنهم
+
+481
+00:40:17,110 --> 00:40:21,350
+يلووها، لازم يكسروا المحتوى تبعها، يكسروا هذه
+
+482
+00:40:21,350 --> 00:40:25,450
+الروابط، بعد ما يكسروها بيلووها، الآن صاروا
+
+483
+00:40:25,450 --> 00:40:28,970
+عاملينها كملولة وما إلى ذلك، إيش بعدين بدهم
+
+484
+00:40:28,970 --> 00:40:36,000
+يعملوا؟ بدهم يظبطوها بالشكل الجديد بدهم يعودوا
+
+485
+00:40:36,000 --> 00:40:43,220
+يرجعوا الـ SS bonds اللي كسروهم بدهم يعودوا يرجعوا
+
+486
+00:40:43,220 --> 00:40:48,420
+الـ SS bonds اللي كسرهم كيف بيرجعوهم؟ بالأكسدة
+
+487
+00:40:48,420 --> 00:40:54,620
+وعشان هيك الكوافير دائما عندهم إيش؟ ماء أكسجين مش
+
+488
+00:40:54,620 --> 00:40:57,980
+دائما عندهم ماء الأكسجين انتبهوا معايا خليني
+
+489
+00:40:57,980 --> 00:41:01,860
+أحاول .. يعني أرسملكوا إياها بشكل سريع حتى تتخيلوا
+
+490
+00:41:01,860 --> 00:41:05,000
+أنتم هاي الشعرة إنمسكت بإيش؟
+
+491
+00:41:07,950 --> 00:41:17,450
+الخطوة الأولى بتخليها ضعيفة SH SH SH SH SH SH هذه
+
+492
+00:41:17,450 --> 00:41:22,090
+العملية Reduction بعد ما عملت لها Reduction شو
+
+493
+00:41:22,090 --> 00:41:28,250
+بدي أعمل فيها؟ بدي S
+
+494
+00:41:28,250 --> 00:41:37,630
+H SH هي لفيتها، بس ما زالت قاشر الشعراء طريقة
+
+495
+00:41:37,630 --> 00:41:50,870
+بتروح تثبتها بهذا الشكل الجديد Oxidation إذا كأن
+
+496
+00:41:50,870 --> 00:41:57,730
+فكيت القوة تبعها، لفيتها، وعودي رجعتها كيف فكيت
+
+497
+00:41:57,730 --> 00:42:02,640
+القوة؟ بالـ reduction كيف رجعتها؟ بالـ oxidation
+
+498
+00:42:02,640 --> 00:42:06,440
+تلاحظين كيف العملية بالتمام؟ هذا الكلام كله بيعملوا
+
+499
+00:42:06,440 --> 00:42:10,620
+في شعر البشر مين؟
+
+500
+00:42:10,620 --> 00:42:17,550
+الكوافير، معمل كيميائي لا لا لما يعود ينمو يعود
+
+501
+00:42:17,550 --> 00:42:21,470
+ينمو على الأصل يعني بتكون لفترة معينة أسبوع
+
+502
+00:42:21,470 --> 00:42:27,030
+أسبوعين شغلة شغلة بسيطة واضح؟ فلاحظوا أنتم كيف
+
+503
+00:42:27,030 --> 00:42:33,290
+يعني أن تطبيقات كثيرة في الحيوان أصلها في الكيميا
+
+504
+00:42:33,290 --> 00:42:39,430
+بتمنالكوا التوفيق بكرا الساعة 11 في امتحان الـ
+
+505
+00:42:39,430 --> 00:42:41,170
+organic chemistry exam 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/7JGOVMt_BfA_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/7JGOVMt_BfA_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..72f6c655be1d32a78fd21a73b4e32604c91bcb77
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/7JGOVMt_BfA_raw.srt
@@ -0,0 +1,2028 @@
+1
+00:00:06,440 --> 00:00:10,800
+بسم الله الرحمن الرحيم المحاضرة الماضية إذا
+
+2
+00:00:10,800 --> 00:00:16,700
+بتذكروا آخر شغلة اتكلمنا عنها كانت على عملية ال
+
+3
+00:00:16,700 --> 00:00:22,620
+oxidation لل alcohols اتكلمنا عنها بشكل عام إيش
+
+4
+00:00:22,620 --> 00:00:26,800
+معنى ال oxidation وإيش ال oxidation اللي بيصير على
+
+5
+00:00:26,800 --> 00:00:30,100
+ال ethanol في الجسم لحد ما يطلع في النهاية على شكل
+
+6
+00:00:31,520 --> 00:00:36,320
+ثانو أكسيد الكربون الآن لما بدونيش نطلع على ال
+
+7
+00:00:36,320 --> 00:00:39,780
+oxidation من ناحية كيميائية و من ناحية معادلات
+
+8
+00:00:39,780 --> 00:00:45,320
+عشان انا بدي ازيد الروابط مع ال oxygen بدي تم عنده
+
+9
+00:00:45,320 --> 00:00:50,190
+في عملية ال oxidationحذف دارتين هيدروجين وبالتالي
+
+10
+00:00:50,190 --> 00:00:55,150
+تحويل هذا ال carbon-oxygen single bond إلى carbon
+
+11
+00:00:55,150 --> 00:00:58,850
+-oxygen double bond فبدل ما كان عندي رابطة مع ال
+
+12
+00:00:58,850 --> 00:01:02,950
+oxygen صار عندي كام رابطة تنتهي اذا هنا في عندي
+
+13
+00:01:02,950 --> 00:01:08,130
+عملية oxidation إذا بتتطلع على المثال الأول على
+
+14
+00:01:08,130 --> 00:01:13,130
+المثال الأول بتلاحظ أن هذا الكحول عبارة عن primary
+
+15
+00:01:13,130 --> 00:01:18,210
+alcoholالديهيد لو افترضنا ان هذا كان إيثانون بيصير
+
+16
+00:01:18,210 --> 00:01:22,630
+أسيتالديهيد لكن القاعدة العامة ان ال primary
+
+17
+00:01:22,630 --> 00:01:27,090
+alcohols و ال oxidize are converted to الديهيدز
+
+18
+00:01:27,090 --> 00:01:31,170
+واضح؟ ال primary alcohols لما بنعملوا oxidation
+
+19
+00:01:31,170 --> 00:01:35,430
+بيصيروا الديهيدز الآن هنا بالذات في حالة ال
+
+20
+00:01:35,430 --> 00:01:38,770
+primary alcohols في عندنا مشكلة بدنا نجي في إلها
+
+21
+00:01:39,560 --> 00:01:47,260
+هذا ال الديهيد ممكن يعمل عملية أكسدة إضافية تتحول
+
+22
+00:01:47,260 --> 00:01:50,640
+ال H الموجودة في هذا ال الديهيد إلى OH وبالتالي
+
+23
+00:01:50,640 --> 00:01:55,360
+يصير acid إذا أنا صار عند ال primary alcohol ممكن
+
+24
+00:01:55,360 --> 00:01:58,760
+يصير الديهيد بس ال الديهيد هذا إذا كانت أكسدة
+
+25
+00:01:58,760 --> 00:02:05,040
+إضافية ممكن يصيرacid الآن يصبح السؤال ما الذي
+
+26
+00:02:05,040 --> 00:02:09,680
+يجعلني أتحكم بالأكسيد هل بدأ تجف بنص الطريق ولا
+
+27
+00:02:09,680 --> 00:02:14,560
+بدأ تستمر للآخر؟ ما يساعدنا في هذا المكان هو
+
+28
+00:02:14,560 --> 00:02:20,040
+التحكم في العامل المؤكسد بمعنىفي عند عامل مؤكسد
+
+29
+00:02:20,040 --> 00:02:25,460
+اسمه BCC اختصاره BCC ميريدينيا ميكلورا كروميت اسمه
+
+30
+00:02:25,460 --> 00:02:29,620
+هذا العامل المؤكسد اذا احنا بنستعمله بعملنا نص
+
+31
+00:02:29,620 --> 00:02:34,300
+الأكسدا بمشينا من ال primer alcohol للالديهيد و
+
+32
+00:02:34,300 --> 00:02:42,660
+البيوكفالـ BCC الآن إذا استعملت stronger oxidizing
+
+33
+00:02:42,660 --> 00:02:46,700
+agent عوامل مؤكسدة أقوى زي ما نستعمل برمجنة
+
+34
+00:02:46,700 --> 00:02:53,500
+البوتاسيوم أو كيامان أوفور أو بوتاسيوم داي كروميت
+
+35
+00:02:53,500 --> 00:02:58,980
+أو كروميك أسد مدوّف بسلفريك أسد كروميو تريوكسيد
+
+36
+00:02:58,980 --> 00:03:03,060
+مدوّف بسلفريك أسد كله بنقول كروميك أسد هذه عوامل
+
+37
+00:03:03,060 --> 00:03:08,140
+مؤكسدة قوية لو استعملتهاللـ Primary Alcohol
+
+38
+00:03:08,140 --> 00:03:13,120
+مابتواقفى شوين عند ال Aldehyde بتطلعني من ال
+
+39
+00:03:13,120 --> 00:03:18,820
+Primary Alcohol لل Acid على طول طبعا بالتأكيد لو
+
+40
+00:03:18,820 --> 00:03:23,000
+ال Aldehyde نفسه أخدته يعني أكسدتها لل Aldehyde و
+
+41
+00:03:23,000 --> 00:03:26,560
+فصلته و بعدين أخدته و بدى أكمل الأكسدة برضه لو
+
+42
+00:03:26,560 --> 00:03:30,960
+استعملت أي واحد من هدولة بيكملني لل Acid إذا أي
+
+43
+00:03:30,960 --> 00:03:38,710
+واحد من هدولة التلاتةنفترض نقول KmnO4 سواء بدأت من
+
+44
+00:03:38,710 --> 00:03:43,950
+ال primary alcohol أو بدأت من ال aldehyde بيوصلني
+
+45
+00:03:43,950 --> 00:03:49,070
+لإيش؟ لل acid، واضح؟ إذن بنقدر احنا نقول الآن ان
+
+46
+00:03:49,070 --> 00:03:54,090
+primary alcohols are oxidized to carboxylic acid
+
+47
+00:03:54,090 --> 00:04:02,300
+acids using مثلا KmnO4 بتاسيومبالمجانات او
+
+48
+00:04:02,300 --> 00:04:05,920
+بوتاسيوم داي كروميت او كروميك اسد وبنفس الوقت
+
+49
+00:04:05,920 --> 00:04:11,800
+الديهيدز هم اكسيدزتوا الاسدز باستخدام الاختصارات
+
+50
+00:04:11,800 --> 00:04:16,600
+اللاسينية واضح؟ اذا انا هنا متحكم في الاكسيد اذا
+
+51
+00:04:16,600 --> 00:04:21,680
+بدي اجف عند ال الديهيد لوحده بدي ال VCC بدي امشي
+
+52
+00:04:21,680 --> 00:04:26,500
+عنه سواء مباشرة من الالكو للاسد او من ال الديهيد
+
+53
+00:04:26,500 --> 00:04:31,320
+اللي هو نص الطريق للاسد بستعمل strongeroxidizing
+
+54
+00:04:31,320 --> 00:04:36,860
+agent واضحة هذه الفكرة فلما تكملوا معادلة أكسدة
+
+55
+00:04:36,860 --> 00:04:41,100
+إذا لازم تتطلعوا إيش اللي موجود عندكم هل هو ال
+
+56
+00:04:41,100 --> 00:04:45,680
+primary alcohol ولا لا لحد الآن الكلام كله على إيش
+
+57
+00:04:45,680 --> 00:04:51,040
+ال primary alcohol الآن لو أجينا لل secondary
+
+58
+00:04:51,040 --> 00:04:55,380
+alcohol اتطلعوا عيادة ال alcohol secondary هاي ال
+
+59
+00:04:55,380 --> 00:04:57,160
+carbon متصلة بكم carbon
+
+60
+00:04:59,830 --> 00:05:03,810
+وبتناقب نفس عملية الأكسدة نشيل الـ H والـ H
+
+61
+00:05:03,810 --> 00:05:07,570
+التانية ويصير أندي سيضة بال bond O بتكون عندى
+
+62
+00:05:07,570 --> 00:05:13,250
+Ketone إذا ال secondary alcohols بيعطوني Ketones
+
+63
+00:05:13,250 --> 00:05:15,710
+ال Ketone اللى هى السيضة بال bond O اللى متصلة
+
+64
+00:05:15,710 --> 00:05:20,990
+بمجموعتين R ال aldehyde بتكون متصلة ب R و H الآن
+
+65
+00:05:20,990 --> 00:05:24,730
+أنا فى ال ketone مش ضاي ال hydrogen تم إبدالها
+
+66
+00:05:24,730 --> 00:05:29,820
+يعني مافيش عملية أكسدة تانيةواضح؟ مافيش عندي خوف
+
+67
+00:05:29,820 --> 00:05:33,940
+من أكسدة تانية فالعمل المؤكسد اللي عادة بيستعمله
+
+68
+00:05:33,940 --> 00:05:39,320
+بالمرأة الـ KMnO4 و أخواتها زي كأنا و أخواتها
+
+69
+00:05:39,320 --> 00:05:44,960
+عارفين هم؟ فأكسدة ال secondary alcohol بتعطينا
+
+70
+00:05:44,960 --> 00:05:51,480
+كيتون و مافيش إمكانية لأكسدة إضافية لشئ إضافي
+
+71
+00:05:52,800 --> 00:05:55,940
+بتطلعوا معاه ال primary alcohol كان عندى كام
+
+72
+00:05:55,940 --> 00:05:59,940
+هيدروجين على الكرب واحدة تنتين والأتش اللى على
+
+73
+00:05:59,940 --> 00:06:03,200
+الأكسجين لما شيلنا تنتين طلت أتش عشان هيك عملنا
+
+74
+00:06:03,200 --> 00:06:07,600
+أكسة ده الديهايد و بعدين بدلنا الأتش باسد ال
+
+75
+00:06:07,600 --> 00:06:12,660
+secondary alcohol two هيدروجين صار عند كيتر و خلصت
+
+76
+00:06:12,660 --> 00:06:18,540
+في ال tertiary alcohol مافيش عندى غير الهيدروجين
+
+77
+00:06:18,540 --> 00:06:24,470
+اللى على ال O-H مافيش هيدروجين تانىطلعوا معايا؟
+
+78
+00:06:24,470 --> 00:06:27,270
+مافيش هيدروجين تاني أشيله وبناء على ذلك ال
+
+79
+00:06:27,270 --> 00:06:31,310
+tertiary alcohol بيصيرلوش أكسدة عشان بدي أكسد أقل
+
+80
+00:06:31,310 --> 00:06:36,590
+تقدير بدي أشيل two hydrogens هيدروجين موليكيول أو
+
+81
+00:06:36,590 --> 00:06:39,830
+يكون عندى هيدروجين على الكربون بعد هيك أعملها
+
+82
+00:06:39,830 --> 00:06:45,210
+ابداله فال tertiary alcohols don't undergo
+
+83
+00:06:45,210 --> 00:06:51,830
+oxidation مابيصيرلهاش أكسدة واضح؟ بيصير الإجمال
+
+84
+00:06:51,830 --> 00:06:56,580
+عندكم سهلمن الذكرنا فيهم لما نقول ال Oxidation of
+
+85
+00:06:56,580 --> 00:07:03,180
+alcohols، ايش بدنا نقول؟ ال primary alcohols are
+
+86
+00:07:03,180 --> 00:07:08,820
+oxidized to aldehydes and then to acids
+
+87
+00:07:11,660 --> 00:07:15,060
+الناس مبصرلهمش لكيتونات مبصرلهمش لكيتونات مبصرلهمش
+
+88
+00:07:15,060 --> 00:07:19,360
+لكيتونات مبصرلهمش لكيتونات مبصرلهمش لكيتونات
+
+89
+00:07:19,360 --> 00:07:23,160
+مبصرلهمش
+
+90
+00:07:23,160 --> 00:07:24,380
+لكيتونات مبصرلهمش لكيتونات مبصرلهمش لكيتونات
+
+91
+00:07:24,380 --> 00:07:27,860
+مبصرلهمش لكيتونات مبصرلهمش لكيتونات مبصرلهمش
+
+92
+00:07:27,860 --> 00:07:30,640
+لكيتونات مبصرلهمش لكيتونات مبصرلهمش لكيتونات
+
+93
+00:07:30,640 --> 00:07:37,100
+مبصرلهمش لكيتونات مبصرلهمش
+
+94
+00:07:37,100 --> 00:07:42,250
+لكيتونات مبصرلهمش لكيتأشياء مهمة جدا في الكيميا
+
+95
+00:07:42,250 --> 00:07:45,510
+العضوية و قبل شوية التفاعل اللى أخدناه قبل عشان
+
+96
+00:07:45,510 --> 00:07:51,350
+تكونوا متذكرين لما كنا ناخد ال alcohol نحوله ل RX
+
+97
+00:07:51,350 --> 00:08:00,490
+ال ROH كنا نحولها ل RX اه اكيد و ال RX أخدنا الفصل
+
+98
+00:08:00,490 --> 00:08:05,130
+السادس كله عن تفاعلات ال RXواضح؟ يعني نص ال
+
+99
+00:08:05,130 --> 00:08:09,530
+organic chemistry من ون بتطلع من ال RX لأ كل ال
+
+100
+00:08:09,530 --> 00:08:12,510
+organic chemistry من ال alcohol احنا بنقول نصها من
+
+101
+00:08:12,510 --> 00:08:17,170
+ال RX لإنه بتعمل SN1 و SN2 reaction ال RX نفسها من
+
+102
+00:08:17,170 --> 00:08:20,270
+ون بتجيبها؟ ال alcohol ال aldehyde من ون ممكن
+
+103
+00:08:20,270 --> 00:08:23,470
+نجيبه؟ ال alcohol ال ketone من ون ممكن نجيبه؟ ال
+
+104
+00:08:23,470 --> 00:08:27,820
+alcohol ال acid من ون ممكن نجيبه؟ ال alcoholفدائما
+
+105
+00:08:27,820 --> 00:08:32,240
+كان في مقولة عند الكيميائيين أنه إذا أخدت كيميائي
+
+106
+00:08:32,240 --> 00:08:35,580
+و حطيته بالصحراء هو و ال alcohol بيحضر منه كل
+
+107
+00:08:35,580 --> 00:08:41,120
+الأشياء التانية فال alcohol يعتبر منطق ال organic
+
+108
+00:08:41,120 --> 00:08:44,980
+synthesis starting point يعني بإمكاني أحضر منه
+
+109
+00:08:45,520 --> 00:08:49,520
+شغلات كتيرة واضح؟ وايكوا شايفين التفاعل طالما ال
+
+110
+00:08:49,520 --> 00:08:52,920
+alcohol حولته ل RX ل aldehyde ل ketone ل acid و ال
+
+111
+00:08:52,920 --> 00:08:57,040
+RX بتتحول ل 100 شغلة طبعا ال acid بعدين بتتحول ل
+
+112
+00:08:57,040 --> 00:09:00,360
+ester ال aldehyde بتتحول ل أشياء تانية ال ketone
+
+113
+00:09:00,360 --> 00:09:04,120
+بتتحول ل أشياء تانية كل هذا الكلام معتمد على إيش؟
+
+114
+00:09:04,120 --> 00:09:10,910
+ان انا انطلقت من ال alcoholهنا بنستعرض بس مجرد
+
+115
+00:09:10,910 --> 00:09:16,590
+استعراض بعض المراكبات اللي فيهم dihydroxy or more
+
+116
+00:09:16,590 --> 00:09:22,630
+compounds يعني مش بس OH واحدة ممكن يكون عنده أكتر
+
+117
+00:09:22,630 --> 00:09:27,450
+من OH يعني مثلا لو كانوا تنتين معنا ذلك بتحكي عن
+
+118
+00:09:27,450 --> 00:09:30,550
+ديول in general لو كانوا تلاتة
+
+119
+00:09:48,920 --> 00:09:55,520
+مار عليكم استعمالته في الـ antifreeze؟لما كنا
+
+120
+00:09:55,520 --> 00:09:59,340
+نخلطه مع الميه و يعمل melting point depression
+
+121
+00:09:59,340 --> 00:10:05,060
+لرداتر السيارة للمبردات او السيارة الان لاحظوا ليش
+
+122
+00:10:05,060 --> 00:10:10,660
+احنا بينفع هذا نستعمله مع الميه و نحطه في رداتر
+
+123
+00:10:10,660 --> 00:10:14,320
+السيارة و بيعمل melting point depression لان درجة
+
+124
+00:10:14,320 --> 00:10:18,140
+غليانه عالية مابتطيرش يعني ميزته لانه بدي استعمله
+
+125
+00:10:18,140 --> 00:10:23,660
+في ميه السيارة مطلوب منه عدة شغلات يكون رخيصأهم
+
+126
+00:10:23,660 --> 00:10:27,880
+إشي بده يكون رخيص لإن أنا بستعمله للاستهلاك، شغلة
+
+127
+00:10:27,880 --> 00:10:32,930
+تانية بدهش يتبخرشغل تالتا بدوش يعمل مشاكل في
+
+128
+00:10:32,930 --> 00:10:37,830
+الموتور بدوش يكون سام لإستعمال البشر العاديين كل
+
+129
+00:10:37,830 --> 00:10:41,410
+هذه المواصفات موجودة فيه فبخلطوا إثليل جليكول مع
+
+130
+00:10:41,410 --> 00:10:45,070
+الميه في الدول الباردة كتير خوف أنه الميه اللي في
+
+131
+00:10:45,070 --> 00:10:49,710
+السيارة تتجمد وبالتالي كل نظام التبريد ونظام
+
+132
+00:10:49,710 --> 00:10:55,890
+التشغيل بختلط تعرفين طبعا ليش السيارات لازم نحطلها
+
+133
+00:10:55,890 --> 00:11:00,120
+ميه ولا لأ؟لوحدة بده تشرحلنا ليش .. ليش بنحط
+
+134
+00:11:00,120 --> 00:11:05,420
+للسيارة ميه؟ طب
+
+135
+00:11:05,420 --> 00:11:10,940
+ليش المحرك يسخن؟
+
+136
+00:11:10,940 --> 00:11:16,040
+طب أنا بديش .. أنا بديش .. بديش حرارة أنا بدي حركة
+
+137
+00:11:16,040 --> 00:11:21,200
+ليش .. ليش الطاقة ماكلها أحولها إلى حركة؟ أنا الأن
+
+138
+00:11:21,200 --> 00:11:26,360
+ناجسني حرارة؟ناجسني حرارة و السيارة تولع نار و
+
+139
+00:11:26,360 --> 00:11:31,780
+هلوم مجرن ولا المطلوب مني الحركة؟ مطلوب مني
+
+140
+00:11:31,780 --> 00:11:37,040
+الحركة، مظبوط ولا لا؟ اه لكن هل بنقدر .. هل بنقدر
+
+141
+00:11:37,040 --> 00:11:42,660
+احنا نحول كل الطاقة اللي في الوقود إلى طاقة يعني
+
+142
+00:11:42,660 --> 00:11:48,640
+..الى شغل بدون ما يطلع عندي thermal energy تذكروا
+
+143
+00:11:48,640 --> 00:11:51,420
+ال thermodynamic اللي أخدته فالحرارة بتطلع مش
+
+144
+00:11:51,420 --> 00:11:56,380
+بخاطرنا غصب عنها يعني بيقولوا أحسن أحسن motor يمكن
+
+145
+00:11:56,380 --> 00:12:01,020
+يشتغل على أربعين لخمسين في المية من المتوقع منه
+
+146
+00:12:01,020 --> 00:12:06,600
+بعد ذلك كل الطاقة وين بتروح؟ بتطلع حرارة فالحرارة
+
+147
+00:12:06,600 --> 00:12:09,840
+عاملة عندي شغلتين مشكلتين المشكلة الأولى ان هي
+
+148
+00:12:09,840 --> 00:12:15,350
+بتخسرنيوقود لان انا مابديش الحرارة والمشكلة
+
+149
+00:12:15,350 --> 00:12:18,350
+التانية ان انا بدي اعالج الحرارة عشان السيارة ما
+
+150
+00:12:18,350 --> 00:12:22,670
+تسخنش وما إلى ذلك فبنعمل نظام التبريد اللي هو نظام
+
+151
+00:12:22,670 --> 00:12:27,290
+الميه اللي بتدور و بتاخد الحرارة و بتعرضها للهوا و
+
+152
+00:12:27,290 --> 00:12:31,810
+المروحة بتعمل عملية إش تبريد فالحرارة بالإجمال
+
+153
+00:12:31,810 --> 00:12:35,520
+اللي في السيارة طالعة غصبا عنالناس مش بخاطرهم
+
+154
+00:12:35,520 --> 00:12:39,920
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+155
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+156
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+157
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+158
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+159
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+160
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+161
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+162
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+163
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+164
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+الطاقة اللى في البطارية بقدر أحولها إلى طاقة حركة
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+165
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+166
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+167
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+168
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+مراوح بتلاقي الكمبيوتر فيه مروحة و مرات بتحسوها
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+169
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+170
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+171
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+173
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+174
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+175
+00:14:14,650 --> 00:14:23,510
+الحسابات بتحياليDelta T بيساوي K في ال mass Delta
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+176
+00:14:23,510 --> 00:14:27,370
+T مقدار الانخفاض في درجة الحرارة melting point
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+177
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+depression K في ال morality أيوة
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+178
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+179
+00:14:37,570 --> 00:14:44,900
+الامتحان الآن مادة تانيةاللي فيها تلت مجموعات OH
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+180
+00:14:44,900 --> 00:14:50,300
+123-propanetriol 123-propanetriol اللي هو ال
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+181
+00:14:50,300 --> 00:14:53,480
+glycerol أو ال glycerin هذا اللي بيحطوه على
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+182
+00:14:53,480 --> 00:14:57,700
+الإيدين و مرتب و بيدخل في صناعة الصوابين و
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+183
+00:14:57,700 --> 00:15:01,620
+الشامبوحات لحظة هذا ال boiling point تبعه 290
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+184
+00:15:01,620 --> 00:15:06,300
+عالية جدا ليش؟ لأنه في تلت مجموعات OH بتعمل
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+185
+00:15:08,860 --> 00:15:17,180
+السوربي طول المادة المطهرة 123456 hexane hexaol
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+186
+00:15:17,180 --> 00:15:24,460
+يعني في ست مجموعات OH عشانك بتلاحظوا ان ال boiling
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+187
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+point بترتفع كتير لدرجة ان هو في الآخر بصير solid
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+188
+00:15:29,640 --> 00:15:33,080
+لحظة انا ما بحكيش عن boiling point melting point
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+189
+00:15:33,080 --> 00:15:37,600
+يعني اتحول الى solid هنا بيقول انه المركب نوعا ما
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+190
+00:15:37,600 --> 00:15:42,940
+بيصير oil و viscous مش مش زي الميه وهنا اعلى هنا
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+191
+00:15:42,940 --> 00:15:46,080
+ال boiling point يمكن تصل ال 400 500 بس بيصير
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+192
+00:15:46,080 --> 00:15:49,840
+يتكسر فالمركب كله بتحول الى solid كونه صار solid
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+193
+00:15:49,840 --> 00:15:55,470
+من وين هذا صار solid من ال hydrogen bondingهدولة
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+194
+00:15:55,470 --> 00:15:59,570
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+195
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+علوم تكون عارفة هم، يعني لو انسألت ايش ال
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+196
+00:16:01,890 --> 00:16:05,790
+glycerin، تكون عارفة ايش ال glycerin، لو انسألت
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+197
+00:16:05,790 --> 00:16:08,850
+ايش ال ethylene glycol، تكون عارفة، لو انسألت ايش
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+198
+00:16:08,850 --> 00:16:14,120
+ال sorbitol، تكون عارفةفي مراكبات polyhydroxy
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+199
+00:16:14,120 --> 00:16:17,820
+compounds aromatic ما بطلبش منكوا تحفظوهم بس
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+200
+00:16:17,820 --> 00:16:22,300
+تكونوا عارفين هم الكاتيكول بمجموعتين OH عن أورثو
+
+201
+00:16:22,300 --> 00:16:28,140
+وال resource lone عن ميتا والهيدروكوينون على
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+202
+00:16:28,140 --> 00:16:34,700
+البارا ولمّا يصيروا تلاتة ال بيروجالون المهم انه
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+203
+00:16:34,700 --> 00:16:38,000
+تعرفوا في كتير مراكبات وإلا في التطبيقات وإلا في
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+204
+00:16:38,000 --> 00:16:40,800
+ال biological system بالذات الكاتيكول دايما
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+205
+00:16:40,800 --> 00:16:44,450
+هتصيروا تسمعوافي كورسات البيولوجيا عن كاتيكولامين
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+206
+00:16:44,450 --> 00:16:49,730
+و ما إلى ذلك لكن أقل تقدير اللي فوق بديكوا تكونوا
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+207
+00:16:49,730 --> 00:16:55,190
+إيش؟ عارفين هم الموضوع
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+208
+00:16:55,190 --> 00:17:01,450
+اللي هنا على تفاعلات ال phenols مش ال alcohols ال
+
+209
+00:17:01,450 --> 00:17:05,570
+phenols أهم شيء تعرفوا أنه لما بيكون عند أنا
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+210
+00:17:05,570 --> 00:17:10,970
+phenol ال OH أخدته مواصفات إليها إيش مواصفات ال
+
+211
+00:17:10,970 --> 00:17:20,270
+OH؟activating ولا deactivating؟ اكتفيتنج
+
+212
+00:17:20,270 --> 00:17:23,430
+والشغل
+
+213
+00:17:23,430 --> 00:17:30,110
+التاني اورثو بارا ديركتر جروبالان الـ OH
+
+214
+00:17:30,110 --> 00:17:33,990
+-Activating و Orthobaradirecting group بعد ذلك
+
+215
+00:17:33,990 --> 00:17:37,590
+تعمل التفاعلات الاروماتيك سبستيوشن عادي يعني لو
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+216
+00:17:37,590 --> 00:17:40,390
+استعملت أثري كلورايت أو ألومنيوم كلورايت سيضع
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+217
+00:17:40,390 --> 00:17:42,590
+مجموعة أثري كلورايت أو أثري كلورايت أو أثري
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+218
+00:17:42,590 --> 00:17:44,310
+كلورايت أو أثري كلورايت أو أثري كلورايت أو أثري
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+219
+00:17:44,310 --> 00:17:45,030
+كلورايت أو أثري كلورايت أو أثري كلورايت أو أثري
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+220
+00:17:45,030 --> 00:17:45,150
+كلورايت أو أثري كلورايت أو أثري كلورايت أو أثري
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+221
+00:17:45,150 --> 00:17:45,410
+كلورايت أو أثري كلورايت أو أثري كلورايت أو أثري
+
+222
+00:17:45,410 --> 00:17:45,730
+كلورايت أو أثري كلورايت أو أ
+
+223
+00:17:50,500 --> 00:17:54,740
+و ممكن تضيف الـ H2SO4 و تضيف الـ Nitro على البارة
+
+224
+00:17:54,740 --> 00:17:59,440
+لو ضيفت الـ PR من كتر مية activating بتضيف على
+
+225
+00:17:59,440 --> 00:18:05,860
+التلت مواقع كمان مش على موقع واحد واضح؟ فلو جيبنا
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+226
+00:18:05,860 --> 00:18:10,500
+لكم اكمال اي معادلة منطلقين من ال phenol اللي هو
+
+227
+00:18:10,500 --> 00:18:15,020
+المركب اللي في ال OH بتكون تتذكر ان التفاعل سريع و
+
+228
+00:18:15,020 --> 00:18:18,260
+التفاعل Orthobara
+
+229
+00:18:19,660 --> 00:18:25,460
+دركتين جروب موجودة فيه على الفينولز الان هنا
+
+230
+00:18:25,460 --> 00:18:31,840
+بيجينا شغل انه مركبات الفينولز مركبات الفينولز لها
+
+231
+00:18:31,840 --> 00:18:37,480
+تطبيق كتير مهم جدا لها تطبيق كتير مهم جدا لو بس
+
+232
+00:18:37,480 --> 00:18:40,560
+بدكوا تضربوا على الانترنت في ال google search
+
+233
+00:18:40,560 --> 00:18:47,400
+هيطلعلكوا عشرات ألاف الأبحاثبس اكتبوا Antioxidant
+
+234
+00:18:47,400 --> 00:18:52,800
+Phenols هي مواد مضادة للأكسدة وموجودة في مصادر
+
+235
+00:18:52,800 --> 00:18:57,180
+طبيعية ومحضر منها مواد صناعية يعني لما بدنا الأكل
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+236
+00:18:57,180 --> 00:19:01,260
+ما يخربش المعلبات ما تخربش كل هذا الكلام بدنا نحط
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+237
+00:19:01,260 --> 00:19:07,780
+عليه إيش؟ مادة مضادة للتأكسد Antioxidant من أشهر
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+238
+00:19:07,780 --> 00:19:13,240
+الـ Antioxidants على الإطلاقالفينولز واضح ؟ عادة
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+239
+00:19:13,240 --> 00:19:16,140
+الفينولز لو بده يتطلع على هذا الهيدروكوينون
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+240
+00:19:16,140 --> 00:19:20,960
+الهيدروكوينون واجأه فعله مع مادة مؤكسدة مع مادة
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+241
+00:19:20,960 --> 00:19:24,820
+مؤكسدة بتأكسد بيفقد طبعا هيدروجنتين بيصير بهذا
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+242
+00:19:24,820 --> 00:19:29,120
+الشكل دابلفوندهان ودابلفوندهان و 4 بنزو اكوينون
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+243
+00:19:29,120 --> 00:19:35,000
+اذا لاحظوا هنا ان الفينولز الفينولز they undergo
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+244
+00:19:35,000 --> 00:19:36,220
+oxidation
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+245
+00:19:38,450 --> 00:19:45,110
+وين بتصير فكرة ان هم مواد مضادين للأكسد يعني كيف
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+246
+00:19:45,110 --> 00:19:52,010
+بيشتغل الفينول كمادة مضادة للأكسد هو بحب يتأكسد
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+247
+00:19:52,010 --> 00:19:56,810
+بسرعة واضح بحب يتأكسد بسرعة بناء على ذلك لو كان
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+248
+00:19:56,810 --> 00:20:02,910
+عندي مثلا الطعام نفترض مرتدلة او علبة لحمة ومحطوط
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+249
+00:20:02,910 --> 00:20:08,580
+فيها مادة فينول اللي هي المادة المضادة للأكسدأو
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+250
+00:20:08,580 --> 00:20:13,760
+علبة لحمة أو مرتدالة و لا يوجد فيها مادة فينول نحن
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+251
+00:20:13,760 --> 00:20:18,040
+نعلبها و ما إلى ذلك لكن نفترض ان داخلت عوالمؤسدة
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+252
+00:20:18,040 --> 00:20:22,900
+أو حتى أكسوجين الجو الأكسوجين هذا تبع الجو أو غيره
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+253
+00:20:22,900 --> 00:20:30,160
+لو أكسد اللحمةهيطلع لي مواد سامة ذات رائحة سيئة
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+254
+00:20:30,160 --> 00:20:35,040
+الآن إذا مافيش غير اللحمة هي Oxida و هيطلع المواد
+
+255
+00:20:35,040 --> 00:20:38,500
+السامة و الرائحة السيئة و كل هذا الكلام طب لو كنا
+
+256
+00:20:38,500 --> 00:20:45,140
+خلطينها بشوية antioxid ال antioxid بحب ال Oxida
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+257
+00:20:45,140 --> 00:20:49,340
+أكتر من اللحمة بناء على ذلك لو إجت شوية مادة م
+
+258
+00:20:49,340 --> 00:20:54,620
+Oxida أو دخل شوية Oxygen وين هتصير ال Oxidaعلى
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+259
+00:20:54,620 --> 00:20:59,300
+الفينون الفينون هتعطي هيدروكوينون او مشتقاتها الان
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+260
+00:20:59,300 --> 00:21:03,620
+انتبهوا معي ايش اللي بيصير عندكم لما انا بدي اجي
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+261
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+اقول ان في عندى مرتدالة نفترض المرتدالة او اللحمة
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+262
+00:21:07,940 --> 00:21:13,520
+كويس مفيدة حطيت عليها مادة antioxidant المادة ال
+
+263
+00:21:13,520 --> 00:21:16,600
+antioxidant لازم تكون ايش safe
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+264
+00:21:19,140 --> 00:21:23,680
+لازم تكون آمنة مابتضرش الصحة طب لو دخل شوية أكسجين
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+265
+00:21:23,680 --> 00:21:28,240
+وهذه أكسدة لمادة تانية المادة التانية هتصير برضه
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+266
+00:21:28,240 --> 00:21:34,080
+جوا الأكل إذا إيش لازم تكون برضه تكون safe بمعنى
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+267
+00:21:34,080 --> 00:21:38,460
+أن المفروض ال antioxidant لا يكون له ريحة ولا له
+
+268
+00:21:38,460 --> 00:21:45,820
+ضرر والناتج عن عملية أكسدته إذا حصل لا يكون له ضرر
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+269
+00:21:45,820 --> 00:21:51,340
+ولا له ريحة واضح؟هذا ما يحدث بالظبط عندما نضع
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+270
+00:21:51,340 --> 00:21:55,300
+فنوليك كومباونز محددة سواء من مصادر طبيعية أو
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+271
+00:21:55,300 --> 00:22:00,060
+صناعية فهي تتلجأ صدمة الأكسدا لما تتحول لمواد
+
+272
+00:22:00,060 --> 00:22:03,860
+المواد اللي بتتحول إليها ليست مواد ضارة أو ذات
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+273
+00:22:03,860 --> 00:22:08,760
+رائحة و اللحوم أو المواد اللي بنعلبها بتبقى بدون
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+274
+00:22:08,760 --> 00:22:15,160
+ما يحصل عليها عملية الأكسدا من المراكبات الموجودة
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+275
+00:22:15,160 --> 00:22:20,550
+في السوق وتستعملواضح؟ من المُركّبات الموجودة في
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+276
+00:22:20,550 --> 00:22:24,810
+السوق وتستعمل مرات لو كنت تتطلع على بعض المعلبات
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+277
+00:22:24,810 --> 00:22:28,650
+تجد مكتوب اسم هذه المواد المواد اللي بيسميها
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+278
+00:22:28,650 --> 00:22:35,330
+الـBHA و الـBHT إيش الـBHA؟ إذا بتطلعوا هنا هذا
+
+279
+00:22:35,330 --> 00:22:40,370
+مُركّب فيه شايفين؟ هذا المحور الأساسي عليه O
+
+280
+00:22:40,370 --> 00:22:43,670
+-Methyl أو عليه Ter-Cerbutyl group هذي إيش
+
+281
+00:22:43,670 --> 00:22:46,730
+المجموعة؟ C حملة تلاتة Ter-Cerbutyl
+
+282
+00:22:52,140 --> 00:22:57,700
+هيدروكسي لأنه في ال OH و ال omethin في ال anisole
+
+283
+00:22:57,700 --> 00:23:03,200
+فنصير كله putilated هيدروكسي أنيزول نسفنا لل
+
+284
+00:23:03,200 --> 00:23:08,740
+أنيزول لل omethin putilated و هيدروكسي و المركب
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+285
+00:23:08,740 --> 00:23:09,500
+اللي عندى إيش
+
+286
+00:23:14,060 --> 00:23:19,000
+البركبات اللي هناك برضه فيها بيوتل جروب و فيها
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+287
+00:23:19,000 --> 00:23:24,080
+الهيدروكس لكن لو أخدت الحلقة ما عدا ذلك هنا إيش
+
+288
+00:23:24,080 --> 00:23:29,180
+الحلقة؟ هنا الحلقة كانت أنيزول و عليها البيوتل و
+
+289
+00:23:29,180 --> 00:23:34,020
+الهيدروكس هنا تلوين و بيوتل و هيدروكس فبصير اسمه
+
+290
+00:23:34,020 --> 00:23:42,670
+بيوتليت هيدروكس تلوين باختصار BHT هذه البركباتكثير
+
+291
+00:23:42,670 --> 00:23:48,450
+الاستعمالات ك Antioxidants غالب الكلام بالنسبة ل
+
+292
+00:23:48,450 --> 00:23:53,570
+90% و أكتر أنها آمنة و Safe بعض الأبحاث بتقول أنه
+
+293
+00:23:53,570 --> 00:24:01,130
+يمكن أنها مخاطر واضح؟ لكن لحد الآن وجهة النظر أقوى
+
+294
+00:24:01,130 --> 00:24:08,000
+مع أنه مافيش مخاطر مؤكدة 100% طالعة منهافى البعض
+
+295
+00:24:08,000 --> 00:24:12,500
+بيقول والله يمكن المخاطر طالع منه طبعا ليش العلماء
+
+296
+00:24:12,500 --> 00:24:18,180
+مابيقدروش يكون عندهم جواب يكون عندهم جواب نهائى
+
+297
+00:24:18,180 --> 00:24:22,760
+أحيانا على بعض الشغلات لسبب بسيط انه يعني بني آدم
+
+298
+00:24:22,760 --> 00:24:29,260
+مثلا صار عنده صراطن اللى بيصير انه ممكن بعض الناس
+
+299
+00:24:29,260 --> 00:24:33,150
+يقول أكيد هذا من ال antioxidantلكن الناس التانية
+
+300
+00:24:33,150 --> 00:24:35,990
+اللي بيقولوا هو بس أخد في الدنيا Antioxidants مع
+
+301
+00:24:35,990 --> 00:24:39,770
+المرتدين اللي هو اللي بيأكل ميت شغلة بيشرب شراب
+
+302
+00:24:39,770 --> 00:24:45,870
+عليه مواد ملونة و بيستنشق سجائر و ما إلى .. فبصير
+
+303
+00:24:45,870 --> 00:24:50,370
+عندي عوامل كتيرة، الآن هنا بتصير الصعوبة انه هل
+
+304
+00:24:50,370 --> 00:24:55,710
+المشكلة فعلا اجت عنده؟من ال antioxidant ولا من
+
+305
+00:24:55,710 --> 00:25:00,070
+أشياء تانية وهذا الكلام اللي بده كثير تجارب و كثير
+
+306
+00:25:00,070 --> 00:25:06,650
+دراسات طبعا برضه صعب ديروا بالكم التعميم يعني مرات
+
+307
+00:25:06,650 --> 00:25:11,810
+بيجي عالم بيروح بجيبله شوية فران ولا شوية قرانب و
+
+308
+00:25:11,810 --> 00:25:16,870
+كل يوم بيعطيهم جرعة عاليةمنها الـ Antioxidant عمدا
+
+309
+00:25:16,870 --> 00:25:20,170
+شهرين، تلاتة، أربعة في الآخر بيقول والله هيوم
+
+310
+00:25:20,170 --> 00:25:25,430
+أصيبه بالسرطان، كويس هل البني آدم يا ترى لما بياخد
+
+311
+00:25:25,430 --> 00:25:30,270
+هذه بنسبة محددة قليلة جدا وعلى فترات بعيدة هيكون
+
+312
+00:25:30,270 --> 00:25:36,090
+لها الأثر زي ما كل يوم تعالى؟وبالتالي لما تسمعوا
+
+313
+00:25:36,090 --> 00:25:40,650
+ان العلماء في كتير .. في كتير مواد مش وصلين الى
+
+314
+00:25:40,650 --> 00:25:44,870
+نتيجة نهائية هل هي فعلا ضارة او لأ بسبب مثل هذه
+
+315
+00:25:44,870 --> 00:25:47,910
+الدراسات يعني بتلاقوا ناس بيجوا .. بيحكوا عن
+
+316
+00:25:47,910 --> 00:25:54,930
+السكارين ولا يمكن السكارين له أثر ضارة لكن لليوم
+
+317
+00:25:54,930 --> 00:26:02,470
+السكارين في السوق ولا لأ لأنه مش ثابت بشكل قطعيإنه
+
+318
+00:26:02,470 --> 00:26:09,710
+فيه سمية أو نوع عالي من الضرر واضح؟ ماحدش بيقدر
+
+319
+00:26:09,710 --> 00:26:14,310
+ينفي 100% لكن كتير ناس بتقدر تنفي فوق نسبة 90 أو
+
+320
+00:26:14,310 --> 00:26:21,310
+95% إنه لحتى الأقل تعتبر بمنطق العلم هذه الأشياء
+
+321
+00:26:21,310 --> 00:26:25,970
+إيش مالها؟safe safe خلّيني أقول .. مابنعش نقول
+
+322
+00:26:25,970 --> 00:26:29,750
+مفيدة، نقول آمنة يعني يمكن مش كتير إلا فائدة غير
+
+323
+00:26:29,750 --> 00:26:32,850
+أنه تمنع ال accident بس يعني مش زي ال vitamin ولا
+
+324
+00:26:32,850 --> 00:26:38,310
+إشي أنه بدها تفيدني أنا كجسم، لأيعني لما أنا بأكل
+
+325
+00:26:38,310 --> 00:26:43,130
+الطعام الطازج أنا بكون بحاجة إلها يعني اللي عنده
+
+326
+00:26:43,130 --> 00:26:49,130
+مثلا لحم طازجة و بده يتناولها و يعمل هامبورجر من
+
+327
+00:26:49,130 --> 00:26:53,510
+لحمة طازجة و يأكل بلزم و يكون ضايف Antioxidant لأ
+
+328
+00:26:53,510 --> 00:26:57,310
+مابلزمش أنا مافيش منها فائدة بس أنا بحطها لتجنب
+
+329
+00:26:57,310 --> 00:27:03,410
+أضرار إذا بتلاحظوا من المراكبات الطبيعية مثلا ال
+
+330
+00:27:03,410 --> 00:27:09,700
+vitamin Eوإذا بتلاحظوا الـ Vitamin E بغض النظر عن
+
+331
+00:27:09,700 --> 00:27:13,320
+كبر الجزء تبعه جزء الـ Antioxidation اللي فيه
+
+332
+00:27:13,320 --> 00:27:18,360
+مرتبط بوجود الـ OH اللي عليه أن هو يعتبر Phenolic
+
+333
+00:27:18,360 --> 00:27:24,400
+Compound هم لاحظين هنا يعني هو صح كبير و ما إلى
+
+334
+00:27:24,400 --> 00:27:32,280
+ذلك لكن بيسموه Natural Phenolic Antioxidant فمحور
+
+335
+00:27:32,280 --> 00:27:42,250
+عمله ك Antioxidant في وجودالـ OH تبع الفينول ننتقل
+
+336
+00:27:42,250 --> 00:27:50,210
+الى العائلة التانية من المُركّبات اسمها الـ Thions
+
+337
+00:27:53,800 --> 00:27:59,600
+Sulphur بدل ال O S H واضح فلاحظوا التسمية البسيطة
+
+338
+00:27:59,600 --> 00:28:04,600
+لما كان اكون عندي CH3OH ايش كنت سام المركب مثال
+
+339
+00:28:04,600 --> 00:28:11,520
+اون لو صارت S H بسميه مثان ثيون وهنا مثلا بيوتان
+
+340
+00:28:11,520 --> 00:28:19,080
+ثيون هذا الفيلون بيصير ثيوفيلون اسم تاني بيستعملوا
+
+341
+00:28:19,080 --> 00:28:23,730
+لهذه المركباتلو كنا بدنا ناخده بال common name لو
+
+342
+00:28:23,730 --> 00:28:29,790
+كانت هنا مثل او اتش كنا نقول مثل alcohol مثل
+
+343
+00:28:29,790 --> 00:28:33,550
+alcohol الان بدنا ال alcohol انا بحطه مركبتان
+
+344
+00:28:33,550 --> 00:28:41,050
+مركبتان فبصير هذا مثل مركبتان بيوتل مركبتان فنل
+
+345
+00:28:42,190 --> 00:28:46,710
+مركبتان و هكذا دائما و أبدا إذا قرأته اسم أي مركب
+
+346
+00:28:46,710 --> 00:28:51,130
+لاحظته الاسم في كلمة ثيو أو مركبتوا اعرف ان هذا
+
+347
+00:28:51,130 --> 00:28:56,530
+مركب سلفر واضح يعني لما نقول ثيو compounds او
+
+348
+00:28:56,530 --> 00:29:00,170
+مركبتوا compounds معناه ذلك احنا بنحكي عن مركبات
+
+349
+00:29:00,170 --> 00:29:06,460
+إيش الكابريت الشغلتين بتلاقوهم ثيوو مركبته ثيول
+
+350
+00:29:06,460 --> 00:29:14,120
+مركبته إذا قلنا مركبته مركبات مركبات مركبات مركبات
+
+351
+00:29:14,120 --> 00:29:14,120
+مركبات مركبات مركبات مركبات مركبات مركبات مركبات
+
+352
+00:29:14,120 --> 00:29:14,260
+مركبات مركبات مركبات مركبات مركبات مركبات مركبات
+
+353
+00:29:14,260 --> 00:29:15,020
+مركبات مركبات مركبات مركبات مركبات مركبات مركبات
+
+354
+00:29:15,020 --> 00:29:16,080
+مركبات مركبات مركبات مركبات مركبات مركبات مركبات
+
+355
+00:29:16,080 --> 00:29:29,320
+مركبات مركبات مركبات مركبات مركبات
+
+356
+00:29:29,430 --> 00:29:34,150
+سلفايت سلفايت في إثل و إثل شو بيصير اسم المُركّب
+
+357
+00:29:34,150 --> 00:29:39,910
+إثل سلفايت أو داي إثل سلفايت مرات كتير الداي
+
+358
+00:29:39,910 --> 00:29:47,150
+بالغوة يعني لو كان هذا إيثر بال O إيش بيسموه؟ داي
+
+359
+00:29:47,150 --> 00:29:53,000
+إثل إيثر و مرات كتير بيقولوا عنه إثل إيثرواضح؟ لما
+
+360
+00:29:53,000 --> 00:29:57,180
+يكون المراكب متماثل بيسموه die ethyl ether او
+
+361
+00:29:57,180 --> 00:30:00,660
+ethyl ether نفس الاشي مثلا في ال die methyl
+
+362
+00:30:00,660 --> 00:30:04,580
+sulfate و مرات بيسموها نفسها methyl sulfate يعني
+
+363
+00:30:04,580 --> 00:30:14,900
+بلغو ال die في ال common nomenclature لأ
+
+364
+00:30:14,900 --> 00:30:19,660
+هو بيكون S double bond O CH3CH3 اللي هو ال die
+
+365
+00:30:19,660 --> 00:30:20,080
+methyl
+
+366
+00:30:26,440 --> 00:30:33,020
+بناخد الاركس مع sh- بيعطينا rsh العملية سهلة
+
+367
+00:30:33,020 --> 00:30:39,820
+الاركس مع sh- بيصير substitution و لما نقول الاركس
+
+368
+00:30:39,820 --> 00:30:43,620
+primary مثلا و ال sh- negative strong nucleophile
+
+369
+00:30:43,620 --> 00:30:49,230
+شو الميكانزم اللي تتوقعوهاSN2 لو كان مصادر مع
+
+370
+00:30:49,230 --> 00:30:53,390
+نيوكليوفايل قوية بتتوقعوا انه يتم عندى SN2
+
+371
+00:30:53,390 --> 00:30:58,610
+ميكانيزم واضح؟ اخدنا احنا كمان شغلة قولنا ان
+
+372
+00:30:58,610 --> 00:31:03,790
+الثيولز هم أسود أقوى من الألكوهولز هذه المعادلة
+
+373
+00:31:03,790 --> 00:31:07,650
+اللى أخدناها وبناء على ذلك بيتفاعلوا كأنهم أحماض
+
+374
+00:31:07,650 --> 00:31:13,190
+مع ال N A O H بيعطوهن Salt زائد Water متذكرين
+
+375
+00:31:13,190 --> 00:31:19,260
+قولنافي ال acidity فيولز مصادر أسود أكثر من الكحول
+
+376
+00:31:19,260 --> 00:31:25,560
+لذلك لو حطينا هنا roh زي ال eoh ايش كان الجواب
+
+377
+00:31:25,560 --> 00:31:30,480
+ايوة كان الجواب انه مابصيرش عندى معادلة no
+
+378
+00:31:30,480 --> 00:31:37,400
+reaction لكن مع ال فيولز بيصير عندى تفاعل okay
+
+379
+00:31:37,400 --> 00:31:43,990
+الآن تيجينا شغلة لو أخدت ال فيولزوعملت لهم
+
+380
+00:31:43,990 --> 00:31:48,710
+Oxidation كل اتنين ثيول بيفقدوا هيدروجين بكونه
+
+381
+00:31:48,710 --> 00:31:55,690
+مركب فيه two sulfur atoms بنسميه disulfide يعني لو
+
+382
+00:31:55,690 --> 00:31:59,930
+كانت هذه مثلا مثل و مثل شو بده يصير اسم المركب؟
+
+383
+00:31:59,930 --> 00:32:04,130
+disulfide
+
+384
+00:32:04,130 --> 00:32:08,450
+ارجعوا معاه لل slide اللي قبل لما يكون عندكم S
+
+385
+00:32:08,450 --> 00:32:14,890
+واحدةسالفايد لما يكون عندكم two sulfur atoms هذا
+
+386
+00:32:14,890 --> 00:32:20,530
+داي سالفايد ماتخربطوش لما يكون عندك two R groups
+
+387
+00:32:20,530 --> 00:32:25,550
+هذا داي سالفايد هذا داي سالفايد عشان ايه مثلا لو
+
+388
+00:32:25,550 --> 00:32:28,590
+انا بدنا ناخد هذه ال group مرة عليكم شو اسمها
+
+389
+00:32:30,090 --> 00:32:36,370
+بالتعامل الفنل مش الفنل قلل الفنل CH2 CH كجروب لما
+
+390
+00:32:36,370 --> 00:32:41,210
+يجيها كمان CH2 بتصير إيه؟ قلل بناء على ذلك هذا شو
+
+391
+00:32:41,210 --> 00:32:49,970
+بيصير اسمه؟ Dialyl disulfide واضح؟
+
+392
+00:32:49,970 --> 00:32:57,370
+هذا ال dialyl disulfide مركب موجود في التومةمُركّب
+
+393
+00:32:57,370 --> 00:33:01,050
+موجود في الطومة والطومة بالمناسبة من عائلة نباتية
+
+394
+00:33:01,050 --> 00:33:05,290
+اللي هي عائلة الاليوم وبناء على ذلك مجموعة الألل
+
+395
+00:33:05,290 --> 00:33:10,930
+أخدتها الإسم لأن المُركّب تبعها موجود في الطومة
+
+396
+00:33:10,930 --> 00:33:15,330
+ولاحظوا الطومة ليش الرائحة المزعجة تبعتها من
+
+397
+00:33:15,330 --> 00:33:19,140
+الكبريت اللي فيهاماشي الطومة اللي لها رائحة مزعجة
+
+398
+00:33:19,140 --> 00:33:21,900
+واللي بياكل طومة ومايروحش يصلي جماعة وسط الناس
+
+399
+00:33:21,900 --> 00:33:26,400
+ويزعج الجامعه وكل هذا الكلام كله وين ما مشكلته
+
+400
+00:33:26,400 --> 00:33:31,040
+طالعة من الكابريت اللي موجود في الطومة واضح؟ اللي
+
+401
+00:33:31,040 --> 00:33:35,340
+هو هذا المركب الدايقاليل دايسلفايت هذا responsible
+
+402
+00:33:35,340 --> 00:33:39,840
+هو المسئول for the odor of garlic هو المسئول عن
+
+403
+00:33:39,840 --> 00:33:47,190
+رائحة الثوم لبلاد family تبعتها الأليوم واضح؟الان
+
+404
+00:33:47,190 --> 00:33:53,270
+لاحظوا معايا، اذا انا اكسدت ال .. ال .. التيول
+
+405
+00:33:53,270 --> 00:33:57,370
+بيصير داي سالفايت، طب اذا عملتي العملية المعاكسة،
+
+406
+00:33:57,370 --> 00:34:01,410
+reduction، بارود بيكسروا، الدي سالفايت are reduced
+
+407
+00:34:01,410 --> 00:34:06,970
+to thyols، الثيولs are oxidized to داي سالفايت،
+
+408
+00:34:06,970 --> 00:34:13,290
+هذه بالمناسبةانتبهوا معاي اكتر اكتر اكتر اكتر اكتر
+
+409
+00:34:13,290 --> 00:34:15,350
+اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر
+
+410
+00:34:15,350 --> 00:34:15,430
+اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر
+
+411
+00:34:15,430 --> 00:34:15,430
+اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر
+
+412
+00:34:15,430 --> 00:34:15,970
+اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر اكتر
+
+413
+00:34:15,970 --> 00:34:23,230
+اكتر اكتر اكتر اكتر اكتر اكتر اكتر
+
+414
+00:34:24,580 --> 00:34:30,100
+ليش؟ لأن اللي بيمسك الجزيئات زي البروتينات وغيرها
+
+415
+00:34:30,100 --> 00:34:34,500
+نوعين من ال bonding ال hydrogen bonding و ال
+
+416
+00:34:34,500 --> 00:34:37,880
+disulfide bonding يعني لما يكون البروتين عامل زي
+
+417
+00:34:37,880 --> 00:34:42,100
+هيك زي helix مثلا بيكون طالع من هنا أسأتش و من هنا
+
+418
+00:34:42,100 --> 00:34:47,020
+أسأتش بيعملوا oxidation بيعملوا disulfide bond
+
+419
+00:34:47,020 --> 00:34:52,960
+فبصير اللي ممسك البروتينات هو إيش؟الـ disulfide
+
+420
+00:34:52,960 --> 00:34:57,800
+bond واضح اللي ممسك البروتينات هو الـ disulfide
+
+421
+00:34:57,800 --> 00:35:03,780
+bond تقين مهمين جدا هذا الكلام له تطبيقين و
+
+422
+00:35:03,780 --> 00:35:10,240
+تطبيقين مهمين جدا اتخيلوا شغل ممسك بروابط لو يا
+
+423
+00:35:10,240 --> 00:35:17,420
+تورا الروابط فك جزء منها شو بده يصير؟ بتفرد بتفرد
+
+424
+00:35:17,420 --> 00:35:24,490
+هيك عن بعض بتشوفوا الخشبزي الـ Sandwich هذا اللي
+
+425
+00:35:24,490 --> 00:35:28,710
+بيعملوا منه الخزانات و ما إلى ذلك أحياناً بتشوفوا
+
+426
+00:35:28,710 --> 00:35:34,610
+لما يتعرض للميه كيف بيفشفش هيك أو بيلفش و ما إلى
+
+427
+00:35:34,610 --> 00:35:39,930
+ذلك تقريبا تقريبا نفس الشغلة تقريبا نفس الشغلة وين
+
+428
+00:35:39,930 --> 00:35:47,140
+بتصيرالعين في العين في القرنيات تبعون العين وما
+
+429
+00:35:47,140 --> 00:35:52,460
+إلى ذلك اللي بيصير بالظبط كالقاتل انه هذه اممسكة
+
+430
+00:35:52,460 --> 00:35:57,820
+نفترض ماخدة مساحها الجد واممسكة باس اسبونز كلها
+
+431
+00:35:57,820 --> 00:36:02,080
+اممسكة باس اسبونز الان لو يا ترى الاس اسبونز
+
+432
+00:36:02,080 --> 00:36:08,500
+تبعتها اتكسرت شو بيصير فيها كانت زي هيك شايفين
+
+433
+00:36:08,500 --> 00:36:14,900
+انتوا معاه اتكسروا الاس اسبونزبتنفش و ما إلى ذلك
+
+434
+00:36:14,900 --> 00:36:20,240
+طبعا كونهم هدولة من خلالهم الأشعة بدأ تمشي معناه
+
+435
+00:36:20,240 --> 00:36:24,980
+ذلك هو عملية الإبصار اختلت لو أنا بدي أرجع الوضع
+
+436
+00:36:24,980 --> 00:36:31,840
+الطبيعي إيش بدي أعمل؟ إيش بدي أعمل؟ بدي أرجع أكون
+
+437
+00:36:31,840 --> 00:36:37,550
+هذه الروابطبدي ارجع اكول هذه الروابط مظبوط ولا لا؟
+
+438
+00:36:37,550 --> 00:36:43,210
+انا عشان اكون زي هيك ممسكين ب SS bonds اختلط ال SS
+
+439
+00:36:43,210 --> 00:36:48,810
+bonds نفخت بدي ارجع اكونهم بترجع طبيعية الان
+
+440
+00:36:48,810 --> 00:36:53,580
+السؤال كيف بدهم يرجعوا يكونوهم؟هذه من أحدث من أحدث
+
+441
+00:36:53,580 --> 00:36:59,940
+الطرق في علاج المشاكل للعين والان لدينا بلازر مع
+
+442
+00:36:59,940 --> 00:37:05,420
+أوزون بالأشعة بيضغطوا عليها أوزون ال أوزون عامل
+
+443
+00:37:05,420 --> 00:37:10,160
+مؤكسل بيعملولها أكسدا هذه من أحدث الطرق اللي صار
+
+444
+00:37:10,160 --> 00:37:15,580
+في غزة طبيب أخصائي وبيشتغلها في مركز البصريات اللي
+
+445
+00:37:15,580 --> 00:37:19,830
+عملوااللي عملته اظن منظمة المؤتمر الإسلامي يعني
+
+446
+00:37:19,830 --> 00:37:24,810
+شغل حديث جدا ان انت تيجي تقول ليش هذه نفشت و افرجت
+
+447
+00:37:24,810 --> 00:37:29,990
+لأن ال di-sulfate sponge ايش صارلها؟ اتكسرت كيف
+
+448
+00:37:29,990 --> 00:37:35,990
+بدي ارجعها؟ بدي اعمل oxidation بدي ارجع الثيون الى
+
+449
+00:37:35,990 --> 00:37:42,290
+ال di-sulfate هذا تطبيق في العنين في تطبيق تاني بس
+
+450
+00:37:42,290 --> 00:37:47,830
+مش في العنين عادي في النسوان معظمهأه وين هذا
+
+451
+00:37:47,830 --> 00:37:53,210
+التطبيق التاني؟ وين التطبيق التاني في الشعر؟ الشعر
+
+452
+00:37:53,210 --> 00:37:58,630
+إذا بتحسوا أنه مش زي الخيط مرات في أشياء أنتوا
+
+453
+00:37:58,630 --> 00:38:02,850
+بتنتبهوا ال hash بمعنى لو أنا أخدت شعرة .. شعرة
+
+454
+00:38:02,850 --> 00:38:07,090
+طولها خمسة سانتم مابديش أقول أنها طويلة كتير أربعة
+
+455
+00:38:07,090 --> 00:38:10,490
+خمسة سانتم مرات و .. و مثل كالواحد زي هيك ممكن
+
+456
+00:38:10,490 --> 00:38:14,730
+الشعرة تكون بهذا الشكلبتبقى عدل مظبوط ولا لأ؟
+
+457
+00:38:14,730 --> 00:38:18,310
+شعرها طوله خمسة سانتي وانا ماسكها مظبوط ولا لأ؟
+
+458
+00:38:18,310 --> 00:38:22,970
+اربع خمسة سانتي او لو هيك ممكن تكون عدل اتخيلوا لو
+
+459
+00:38:22,970 --> 00:38:28,610
+انتوا جيبتوا خيط طوله اربع سانتي بتقدروا تمسكوه
+
+460
+00:38:28,610 --> 00:38:34,290
+يكون عدل لفوق؟ اذا في فرق بين الشعروالخيط العادى
+
+461
+00:38:34,290 --> 00:38:39,190
+انه اجوى الشعره ولا الخيط الشعره الشعره بتظهر بهذا
+
+462
+00:38:39,190 --> 00:38:43,890
+الشكل مظبوط ولا لأ طب ايش اللي ممسك الشعره بهذا
+
+463
+00:38:43,890 --> 00:38:48,130
+الشكل ان الشعره فيها ال di sulfide point بتتيجي من
+
+464
+00:38:48,130 --> 00:38:51,570
+اللي هو ال amino acid التسبيل اللي فيه SOS
+
+465
+00:38:51,570 --> 00:38:55,170
+فالبروتينات تبعت الشعره بتقدروا تتخيلوا هيك
+
+466
+00:38:55,170 --> 00:39:00,690
+البروتين في الشعره ممسك بdi sulfide point هذا اللي
+
+467
+00:39:00,690 --> 00:39:05,430
+بيجوه ايشاللي بيجوّش شعر .. الآن شوفوا إيش اللي
+
+468
+00:39:05,430 --> 00:39:10,230
+بيصير عندنا .. ماحدش في الدنيا راضي بنصيبه .. إيش
+
+469
+00:39:10,230 --> 00:39:13,510
+يعني ماحدش راضي بنصيبه؟ اللي شعرهم .. ما شاء الله
+
+470
+00:39:13,510 --> 00:39:17,930
+عنه يا محلاه .. عدل و ما .. إلى ذلك بدهم يخلوهم لو
+
+471
+00:39:17,930 --> 00:39:23,890
+لو .. كرلةو ال .. curly .. و الشعرهم ال curly هذا
+
+472
+00:39:23,890 --> 00:39:28,590
+بده بيخلوه عدل بتلاقوا الناس و كله برزق الكوافير
+
+473
+00:39:28,590 --> 00:39:32,750
+الشعر عدل بيروح على الكوافير بيقولوا بالله لو لو
+
+474
+00:39:32,750 --> 00:39:37,390
+ليه و الشعرهم لو لو بيروح بيعمل عملية إيش كو الشعر
+
+475
+00:39:37,390 --> 00:39:41,510
+بيسموها مظبوط ولا لأ؟ بتشوف ناس هيك مربين شعرهم طب
+
+476
+00:39:41,510 --> 00:39:46,260
+إنتوا شعركوا كله هيك كان؟أيش اللي بيصير هنا؟
+
+477
+00:39:46,260 --> 00:39:50,440
+بيشتغلوا عملية كيميائية بحتة لكوافرية بيشتغلوا
+
+478
+00:39:50,440 --> 00:39:55,840
+عملية كيميائية بحتة نفترض إنه شعر كان عدل، بييجوا
+
+479
+00:39:55,840 --> 00:40:02,200
+و بيحطوا عليه reducing agent عامل مختزن، بيروحوا و
+
+480
+00:40:02,200 --> 00:40:08,610
+بيكسروالما يكسروا .. شو بتصير الشعرة؟ رخوة،
+
+481
+00:40:08,610 --> 00:40:13,510
+بياخدوها على النار و بيلووها، بيعملوها شكل جديد
+
+482
+00:40:13,510 --> 00:40:17,110
+لأنه بالوضع الطبيعي مش سهل أنهم يعملوا أنهم
+
+483
+00:40:17,110 --> 00:40:21,350
+يلووها، لازم اكسروا المحتوى تبعها، يكسروا هذه
+
+484
+00:40:21,350 --> 00:40:25,450
+الروابط، بعد ما يكسروها بيلووها، الآن صاروا
+
+485
+00:40:25,450 --> 00:40:28,970
+عاملينها كملولة و ما إلى ذلك، إيش بعدين بدهم
+
+486
+00:40:28,970 --> 00:40:36,000
+يعملوا؟ بدهم يظبطوها بالشكل الجديدبدهم يعودوا
+
+487
+00:40:36,000 --> 00:40:43,220
+يرجعوا الأس أسبونز اللي كسروهم بدهم يعودوا يرجعوا
+
+488
+00:40:43,220 --> 00:40:48,420
+الأس أسبونز اللي كسرهم كيف بيرجعوهم؟ بالأكسدة
+
+489
+00:40:48,420 --> 00:40:54,620
+وعشان هيك الكوفرية دايما عندهم إيش؟ ميّة أكسجين مش
+
+490
+00:40:54,620 --> 00:40:57,980
+دايما عندهم ميّة الأكسجين انتبهوا معايا خليني
+
+491
+00:40:57,980 --> 00:41:01,860
+أحاول .. يعني أرسملكوا ياها بشكل سريع حتى تتخيلوا
+
+492
+00:41:01,860 --> 00:41:05,000
+انتوا هاي الشعرة انمسكة بإيش؟
+
+493
+00:41:07,950 --> 00:41:17,450
+الخطوة الأولى بتخليها ضعيفة S H S H S H S H هذه
+
+494
+00:41:17,450 --> 00:41:22,090
+العملية Reduction بعد ما اعملت لها Reduction شو
+
+495
+00:41:22,090 --> 00:41:28,250
+بدى اعمل فيها؟ بدى S
+
+496
+00:41:28,250 --> 00:41:37,630
+H S Hهي نلويتها، بس ما زالت قاشر الشعراء طريقة
+
+497
+00:41:37,630 --> 00:41:50,870
+بتروح تثبتها بهذا الشكل الجديد Oxidation إذا كأن
+
+498
+00:41:50,870 --> 00:41:57,730
+فكيت القوة تبعتها، لفيتها، و عودي ترجعتها كيف فكيت
+
+499
+00:41:57,730 --> 00:42:02,640
+القوة؟بال reduction كيف رجعتها؟ بال oxidation
+
+500
+00:42:02,640 --> 00:42:06,440
+تلاحظين كيف العملية بالتم؟ هذا الكلام كله بيعملوا
+
+501
+00:42:06,440 --> 00:42:10,620
+في شعور البشر مين؟
+
+502
+00:42:10,620 --> 00:42:17,550
+الكوافرية، معمل كيميائيلا لا لما يعود ينمو يعود
+
+503
+00:42:17,550 --> 00:42:21,470
+ينمو على الأصل يعني بتكون لفترة معينة أسبوع
+
+504
+00:42:21,470 --> 00:42:27,030
+أسبوعين شغلة شغلة بسيطة واضح فلاحظوا انتوا كيف
+
+505
+00:42:27,030 --> 00:42:33,290
+يعني انه تطبيقات كتيرة في الحيوان أصلها في الكيميا
+
+506
+00:42:33,290 --> 00:42:39,430
+بتمنالكوا التوفيق بكرا الساعة 11 في امتحان ال
+
+507
+00:42:39,430 --> 00:42:41,170
+organic milk exam
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc.srt
new file mode 100644
index 0000000000000000000000000000000000000000..2987943caf37e5ae1cd79ff8b044a469a65ff9be
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc.srt
@@ -0,0 +1,1801 @@
+1
+00:00:08,760 --> 00:00:15,860
+اليوم بنكمل في موضوع الأحماض وتحديدا 
+
+2
+00:00:15,860 --> 00:00:20,600
+لسه ما زلنا في موضوع تسمية الأحماض، الفكرة الأساسية
+
+3
+00:00:20,600 --> 00:00:24,620
+اللي حكيناها المرة الماضية أنه تسمية حامض تسمية
+
+4
+00:00:24,620 --> 00:00:30,240
+حامض بالتم بإضافة المقطع oic acid وبعد هيك شوفي
+
+5
+00:00:30,240 --> 00:00:35,620
+عندنا مجموعات substituents بنذكرها، استعرضنا
+
+6
+00:00:35,620 --> 00:00:43,030
+استعرضنا الأحماض من واحد إلى عشرة باسمها ال IUPAC
+
+7
+00:00:43,030 --> 00:00:47,170
+وال common names، يمكن هذه ال slide تكون شوية أهم
+
+8
+00:00:47,170 --> 00:00:54,450
+هنا كيف نسمي مركبات مختلفة لأحماض بتحتوي على 
+
+9
+00:00:54,450 --> 00:00:57,590
+substituents
+
+10
+00:00:57,590 --> 00:01:03,310
+مثلا في هذا المثال الأول بتلاحظوا أن عندكم حامض
+
+11
+00:01:03,310 --> 00:01:10,730
+بكم كربونة؟ أربعة، بيوتانويك أسد، لبيوتانويك أسد ع
+
+12
+00:01:10,730 --> 00:01:16,110
+موقع تلاتة في بروم، لاحظوا الترقيم من وين بيبدأ؟ من
+
+13
+00:01:16,110 --> 00:01:20,430
+الكاربون اللي حامل السيدة بالبندقة مش من بعيدها، لو
+
+14
+00:01:20,430 --> 00:01:24,030
+كنا مرات بنستعمل نظام Alpha و Beta بيكون من اللي 
+
+15
+00:01:24,030 --> 00:01:29,970
+بعيدها، هذا الحامض واحد، اتنين، تلاتة، أربعة، خمسة، إذا
+
+16
+00:01:29,970 --> 00:01:36,230
+احنا بنحكي عن بنتانويك أسد على تلاتة واربعة داي
+
+17
+00:01:36,230 --> 00:01:41,530
+كلورو وعلى خمسة، ع تلاتة واربعة داي كلورو بس تلاتة 
+
+18
+00:01:41,530 --> 00:01:47,070
+واربعة داي كلورو بنتانويك أسد، طبعا الحامض اللي على
+
+19
+00:01:47,070 --> 00:01:52,150
+البنزين شو اسمه؟ بنزويك أسد، إذا هذا بقرا كلورو 
+
+20
+00:01:52,150 --> 00:01:59,050
+بنزويك أسد، مثل هذا الحامض واحد، اتنين، لاحظوا أنا
+
+21
+00:01:59,050 --> 00:01:59,570
+عندكم
+
+22
+00:02:05,530 --> 00:02:09,090
+الآن المجموعة اللي بيكون حاملها هذا الحامض اي
+
+23
+00:02:09,090 --> 00:02:16,210
+مجموعة إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل
+
+24
+00:02:16,210 --> 00:02:16,530
+إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل
+
+25
+00:02:16,530 --> 00:02:17,930
+إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل
+
+26
+00:02:17,930 --> 00:02:19,290
+إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل
+
+27
+00:02:19,290 --> 00:02:19,850
+إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، إيثل
+
+28
+00:02:19,850 --> 00:02:25,410
+إيثل، إيثل، إيثل، إيثل، إيثل، إيثل، يمكن الأمثلة اللي بعد
+
+29
+00:02:25,410 --> 00:02:30,550
+هنا جزء منها بيحتوي على أكثر من مجموعة وظيفية،
+
+30
+00:02:30,550 --> 00:02:34,290
+يعني غير مجموعة الحامض، ممكن تلاقوا ال keen، ممكن
+
+31
+00:02:34,290 --> 00:02:39,210
+تلاقوا أو أتش، ممكن تلاقوا double bond، وأخدنا
+
+32
+00:02:39,210 --> 00:02:44,450
+احنا أولويات، والحمض تقريبا من أعلى الأولويات
+
+33
+00:02:45,440 --> 00:02:50,860
+المثال الأول بسيط اللي هو 2-bromopropanoic acid و
+
+34
+00:02:50,860 --> 00:02:54,300
+بالمنطق اللي مرات بيستعملوا فيه Alpha هذا منطق
+
+35
+00:02:54,300 --> 00:02:58,700
+common name Alpha-bromo بيستعملوا propionic acid
+
+36
+00:02:58,700 --> 00:03:03,960
+لأنه common name، هذا المثال فيه مجموعتين وظيفيتين
+
+37
+00:03:03,960 --> 00:03:10,210
+اللي هو الحامض وال double bond الكين و acid مع بعض
+
+38
+00:03:10,210 --> 00:03:14,790
+الأولوية لمن؟ لل acid فبالترقيم هنبدأ من عند
+
+39
+00:03:14,790 --> 00:03:18,790
+الكاربون تحت ال acid وفي التسمية بيبين عند أوك
+
+40
+00:03:18,790 --> 00:03:26,450
+أسد في الآخر، طبعا هنا 3-butenoic acid ملاحظين
+
+41
+00:03:26,450 --> 00:03:27,030
+انتوا؟
+
+42
+00:03:29,550 --> 00:03:34,890
+الآن هذا السؤال أنه ال acid دائما على الطرف، ال
+
+43
+00:03:34,890 --> 00:03:38,550
+acid دائما على الطرف، ما بلزمش نحددله موقعه، ليش
+
+44
+00:03:38,550 --> 00:03:44,730
+ما قلناش هنا to a propionic acid؟ هذا هو السؤال
+
+45
+00:03:47,320 --> 00:03:51,200
+ما فيش احتمالات، لو كنت أنا بحكي، لو كنت بحكي عن ست
+
+46
+00:03:51,200 --> 00:03:55,900
+ذرات كربون مثلا C double bond OH وعندي ست ذرات 
+
+47
+00:03:55,900 --> 00:04:00,000
+كربون، واحد، اتنين، تلاتة، أربعة، خمسة، ستة، الآن
+
+48
+00:04:00,000 --> 00:04:06,730
+هنا ممكن تكون ال double bond هنا، هيكون 2-hexenoic 
+
+49
+00:04:06,730 --> 00:04:11,630
+acid، ممكن تكون هنا 3-hexenoic acid، 4-hexenoic acid
+
+50
+00:04:11,630 --> 00:04:15,570
+5-hexenoic acid، هنا فيه احتمالات، بس هنا ما فيش غير
+
+51
+00:04:15,570 --> 00:04:21,510
+هذا الاحتمال، فمع علم ما بنزيدش كلام عليه، واضح؟
+
+52
+00:04:21,510 --> 00:04:25,410
+بينما هنا أنا مضطر، مثل هذا المركب لما بدي اسميه، 1
+
+53
+00:04:25,410 --> 00:04:33,310
+2، 3، 4، 5، 6 لازم أقول 3-hexene، الآن ال 3 بتكون 
+
+54
+00:04:33,310 --> 00:04:43,330
+بتحدد موقع إيش ال double bond وبكمل oic acid، ال
+
+55
+00:04:43,330 --> 00:04:51,510
+مركب
+
+56
+00:04:51,510 --> 00:04:59,730
+اللي بعده فيه كحول O H O Acid، الأولوية لإيش؟ للـ
+
+57
+00:04:59,730 --> 00:05:04,690
+acid، في الترقيم هيكون واحد، اتنين، تلاتة، أربعة، هيكون
+
+58
+00:05:04,690 --> 00:05:14,630
+3-hydroxybutanoic acid، لأنه ما بنسبوش للكحول
+
+59
+00:05:14,630 --> 00:05:19,850
+ال acid أعلى أولوية من الكحول، هذا المركب
+
+60
+00:05:19,850 --> 00:05:24,510
+المجموعتين الوظيفيتين اللي فيه، الديهيد و ال acid
+
+61
+00:05:24,510 --> 00:05:26,690
+الديهيد و ال acid
+
+62
+00:05:30,590 --> 00:05:34,790
+بروبانويك أسد على موقع تلاتة الالديهايد لما يكون
+
+63
+00:05:34,790 --> 00:05:40,890
+تعامل كمجموعة شو بنسميها؟ 3-formylpropanoic
+
+64
+00:05:40,890 --> 00:05:47,010
+أسد، ها نفس الشيء، واحد، اتنين، تلاتة، أربعة، خمسة، على 
+
+65
+00:05:47,010 --> 00:05:53,370
+موقع اتنين برومو، على موقع اتنين برومو وعلى موقع
+
+66
+00:05:53,370 --> 00:05:59,380
+اربعة الكيتون، مين له أولوية؟ الكيتون ولا الأسد؟ الأسد
+
+67
+00:05:59,380 --> 00:06:04,020
+فعشان هي كانت بترجع 3-oxo to 4-bromo, 3-oxo
+
+68
+00:06:04,020 --> 00:06:10,160
+pentanoic acid، واضح؟ هنا بتلاحظوا أمثلة بنتقف فيها أكثر
+
+69
+00:06:10,160 --> 00:06:15,800
+من مجموعة وظيفية والأسد
+
+70
+00:06:15,800 --> 00:06:23,340
+طبعا أولويته عالية، يمكن هنا كمان مزيد من الأمثلة
+
+71
+00:06:24,680 --> 00:06:28,020
+هذا المثال بسيط لأنه ما فيش ليه غير ال acid وبعدين ال
+
+72
+00:06:28,020 --> 00:06:33,020
+الكلجروكس، المهم تفتشوا على ال longest chain، هذا
+
+73
+00:06:33,020 --> 00:06:39,260
+المثال فيه حامض ومجموعة ال amino ومجموعة ال
+
+74
+00:06:39,260 --> 00:06:46,220
+hydroxy، 2-amino, 3-hydroxybutanoic acid، طبعا إله
+
+75
+00:06:46,220 --> 00:06:50,140
+اسم شهرة لأن هذا amino acid بيمر مع الناس في ال
+
+76
+00:06:50,140 --> 00:06:52,840
+biochemistry، ثريونين
+
+77
+00:06:53,980 --> 00:06:57,860
+مش موضوع طبعا، لو بديجي زي هي تقلكوا سؤال واحد
+
+78
+00:06:57,860 --> 00:07:02,600
+اتنين، ثلاثة، أربعة، المفروض تحددوا هذه R ولا S وهذه
+
+79
+00:07:02,600 --> 00:07:08,060
+R ولا S، فزي ما بتلاحظوا إن هنا هو بيقول إن عندنا
+
+80
+00:07:08,060 --> 00:07:15,060
+two S، لو بدنا نذكركم، هاي موقع اتنين وين؟ أقل مجموعة
+
+81
+00:07:15,060 --> 00:07:21,480
+ال H، هذه أنا بتحرك ال nitrogen بعدين الكربون اللي 
+
+82
+00:07:21,480 --> 00:07:24,140
+حامله oxygen بعدين الكربون اللي حامله وانا oxygen
+
+83
+00:07:24,140 --> 00:07:30,980
+إذا it seems to be R الـH I'm trying to assign it to S
+
+84
+00:07:30,980 --> 00:07:35,360
+هذه نفس الشيء، لو إننا ناخدها ال box أعلى مجموعة ال
+
+85
+00:07:35,360 --> 00:07:42,680
+O بعدين هذه بعدين هذه أنا بتحرك بهذا الشكل، 3S it
+
+86
+00:07:42,680 --> 00:07:51,870
+is 3R, not 3S، واضح؟ هذا مثال بسيط، هذا لما تكون
+
+87
+00:07:51,870 --> 00:07:57,170
+مجموعة ال acid على حلقات بنستعمل لها carboxylic
+
+88
+00:07:57,170 --> 00:08:01,690
+acid، زي ال aldehyde لما يكون على حلقة، إذا بتذكرون
+
+89
+00:08:01,690 --> 00:08:07,150
+إيش كنا بنقول؟ Carbaldehyde، هذا بنقول carboxylic
+
+90
+00:08:07,150 --> 00:08:12,350
+acid، فيه نتنتين شو بيصير عندك؟ Dicarboxylic acid
+
+91
+00:08:12,350 --> 00:08:19,600
+فهذا عبارة عن Cyclohexane، دايكربوكسليك أسد، الـ داى
+
+92
+00:08:19,600 --> 00:08:23,980
+كربوكسليك أسد وين موجودين؟ بتعتبر أنها دي واحد،
+
+93
+00:08:23,980 --> 00:08:30,020
+اتنين، تلاتة، على واحد وتلاتة، وكيف اتجاههم؟ 
+
+94
+00:08:30,020 --> 00:08:36,100
+طالعوا على جهة واحدة للأمام، إذا هم سيس، سيس، وان
+
+95
+00:08:36,100 --> 00:08:42,840
+ثري سايكلوهكسين دايكربوكسليك أسد، سيس وان ثري
+
+96
+00:08:42,840 --> 00:08:45,380
+سايكلوهكسين دايكربوكسليك أسد
+
+97
+00:08:57,370 --> 00:09:04,170
+واضح؟ ها نفس الشيء أمثلة إضافية، Cyclopentane بحمل
+
+98
+00:09:04,170 --> 00:09:11,270
+acid شو بنسميه؟ Cyclopentane carboxylic acid، لو
+
+99
+00:09:11,270 --> 00:09:12,530
+كان حامل الـ ديهايد
+
+100
+00:09:15,590 --> 00:09:19,790
+Cyclobutane carbaldehyde، وهذا Cyclobutane
+
+101
+00:09:19,790 --> 00:09:23,870
+Carboxylic Acid، طبعا بتفيه على موقع تلاتة كلورو
+
+102
+00:09:23,870 --> 00:09:28,090
+مجموعة للأمام، للخلف أو لفوق وتحت، بتستعمله
+
+103
+00:09:28,090 --> 00:09:35,170
+Cis, trans Benzoic Acid، Para-chlorobenzoic Acid، Hana
+
+104
+00:09:35,170 --> 00:09:39,590
+Toluic Acid، لأن هنا المجموعة من طلوين جاي، هذا اسم
+
+105
+00:09:39,590 --> 00:09:45,040
+شهرة، لكن ممكن نسميه one, two, two مثلبنزين
+
+106
+00:09:45,040 --> 00:09:50,540
+كاربوكسليك أسد أو 2-methylbenzoic acid، هذا
+
+107
+00:09:50,540 --> 00:09:54,140
+المركب من النفثالين، بتذكروا حلقتين بنزين؟ شو 
+
+108
+00:09:54,140 --> 00:09:58,980
+بنسميهم؟ نفثالين، لو كان الحامض على هذا الموقع واحد
+
+109
+00:09:58,980 --> 00:10:04,060
+بنسميه 1-naphthalic acid، لما نكون على موقع اتنين
+
+110
+00:10:04,060 --> 00:10:12,570
+2-naphthalic acid، لو أجي هنا لأ 2 لو حطيت 
+
+111
+00:10:12,570 --> 00:10:17,190
+الأصل هنا، شو بدأ أسميه؟ 2 ولا 3؟ بنبدأ من 
+
+112
+00:10:17,190 --> 00:10:23,090
+تحت، تصير واحد، اتنين، برجع 2، لو حطيت هنا 1،
+
+113
+00:10:23,090 --> 00:10:28,490
+إذا في نفس الموقع اصل حقيقة عندي بس حامضين منه، يا ال
+
+114
+00:10:28,490 --> 00:10:33,030
+1 يا ال 2 لأن هذا الموقع وهذا وهذا وهذا نفس 
+
+115
+00:10:33,030 --> 00:10:37,220
+الشيء، وهذا الموقع وهذا وهذا وهذا نفس الشيء، يعني
+
+116
+00:10:37,220 --> 00:10:40,720
+لو جبتلكوا نفثالين وقولتلكوا بقى كام حامض بقدر 
+
+117
+00:10:40,720 --> 00:10:44,800
+أعمل منه؟ بس حامضين ال 1-naphthalic acid وال 2-
+
+118
+00:10:44,800 --> 00:10:48,740
+naphthalic acid، ولو المواقع اتبعتوا كتيرة لكن
+
+119
+00:10:48,740 --> 00:10:55,080
+مواقعه أشمالها متماثلة، هذا وهذا وهذا وهذا نفس
+
+120
+00:10:55,080 --> 00:11:02,000
+الموقع، هذا وهذا وهذا وهذا نفس الموقع، واضح؟
+
+121
+00:11:05,190 --> 00:11:09,950
+مي كان بدو يسأل هان؟ لا
+
+122
+00:11:09,950 --> 00:11:17,430
+لا، دائما في الحلقات، دائما في الحلقات العطرية، في
+
+123
+00:11:17,430 --> 00:11:20,230
+الحلقة البطاسية اللي هيك بتسمى viewsdrags اللي
+
+124
+00:11:20,230 --> 00:11:21,830
+بيجي من الموقع اللي جامبل
+
+125
+00:11:28,730 --> 00:11:32,410
+مثلًا، اللي قبل هذا، هم .. هم .. هم .. هم .. هم ..
+
+126
+00:11:32,410 --> 00:11:32,810
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+127
+00:11:32,810 --> 00:11:34,890
+.. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم ..
+
+128
+00:11:34,890 --> 00:11:36,030
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+129
+00:11:36,030 --> 00:11:43,150
+.. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم ..
+
+130
+00:11:43,150 --> 00:11:46,250
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+131
+00:11:46,250 --> 00:11:46,310
+هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم .. هم
+
+132
+00:11:46,310 --> 00:11:56,250
+.. هم .. هم .. هم .. هم .. هم ..
+
+133
+00:11:56,250 --> 00:12:02,260
+هم الـ D مش حرف علة، فليش .. ها هي السؤال تحديداً
+
+134
+00:12:02,260 --> 00:12:10,920
+هنا إن هذا حرف ال E موجود، طبعا ليش احنا ما حذفناش
+
+135
+00:12:10,920 --> 00:12:15,520
+لأنه بعده D، بعده مش حرف علة، بس مثلا لما بيكون عندي
+
+136
+00:12:15,520 --> 00:12:18,720
+دائما فعلا أنا دي قاعدة في الكيميا لما بيكون عندي
+
+137
+00:12:18,720 --> 00:12:23,740
+حرفين علة ورا بعض، بحذف الأول منهم، بنحذف الأول من
+
+138
+00:12:23,740 --> 00:12:27,180
+حرفين العلة، واضح؟
+
+139
+00:12:31,240 --> 00:12:35,540
+هي كتيرة الأمثلة هيك، لكن بلاش نطلع منكم أو نطلع عن 
+
+140
+00:12:35,540 --> 00:12:41,060
+الموضوع تبعنا، يعني مثلا لو بدكم تقولوا Isoxazole
+
+141
+00:12:41,060 --> 00:12:46,380
+for example، أو oxazole
+
+142
+00:12:46,380 --> 00:12:50,680
+أصلها oxazole
+
+143
+00:12:50,680 --> 00:12:52,160
+مثلا هذا مركب الآن
+
+144
+00:12:57,210 --> 00:13:01,170
+بشير الأولى دي قاعدة عامة، بس هنا ما فيش عندي التقاء
+
+145
+00:13:01,170 --> 00:13:10,010
+حرفين أو التقاء حرفين إلا طبعا
+
+146
+00:13:10,010 --> 00:13:16,010
+طبعا طبعا طبعا alphabetical، الآن بننتقل ل ال die
+
+147
+00:13:16,010 --> 00:13:21,210
+acids، احنا قلنا إن أي سلسلة عادية ممكن يكون لها
+
+148
+00:13:21,210 --> 00:13:25,390
+طرفين، وأحيانا ممكن يكونوا أكثر من طرفين، طبعا الآن
+
+149
+00:13:26,520 --> 00:13:32,000
+لو على الطرفين كان عندي حامض بيصير عنده داى أسد
+
+150
+00:13:32,000 --> 00:13:35,260
+يعني مثلا هنا هي carbon و carbon وهنا في عندي 
+
+151
+00:13:35,260 --> 00:13:40,400
+حامض وحامض، إيش صار عندي؟ داى أسد، هي carbon نتنتين
+
+152
+00:13:40,400 --> 00:13:46,360
+تلاتة حامض و carbon و حامض، داى أسد، هنا داى أسد
+
+153
+00:13:46,360 --> 00:13:50,160
+أربعة داى أسد، خمسة، الآن هدولة لما بدنا نسميهم كم
+
+154
+00:13:50,160 --> 00:13:55,360
+بنسميهم، بنعد كم carbon عندنا؟ نتنتين، نتنتين يعني إيش؟
+
+155
+00:13:55,990 --> 00:14:02,150
+ethane، إذا بنقول إيثان أو ethanedioic acid، إيثان
+
+156
+00:14:02,150 --> 00:14:08,010
+داى أويك أسد، لأنه للأسد احنا بنحط ال أويك، هنا عندي 
+
+157
+00:14:08,010 --> 00:14:14,310
+تلاتة شو بيصير اسم المركب؟ بروبين داى أويك كل
+
+158
+00:14:14,310 --> 00:14:18,830
+هدولة داى أويك أسد فيهم حامضين على الجانب، هنا عندي
+
+159
+00:14:18,830 --> 00:14:23,350
+أربعة بيوتين داى أويك أسد، بنتين داى أويك أسد،
+
+160
+00:14:23,350 --> 00:14:30,450
+هيكسين داى أويك أسد، واضح؟ الآن هذا ما يمنعش إن هؤلاء
+
+161
+00:14:30,450 --> 00:14:35,310
+الأحماض لهم أصل، أول ما اكتشفوهم وأخرجوهم من مصادر
+
+162
+00:14:35,310 --> 00:14:39,270
+أحيانا نباتية، أحيانا حيوانية وبالتالي لهم أسماء 
+
+163
+00:14:39,270 --> 00:14:45,550
+شهرة، وأسماء الشهرة غالبا مرتبطة بالعائلات 
+
+164
+00:14:45,550 --> 00:14:48,790
+الاستخراجوها منها، مثلا الحمض الأول بيسموه oxalic
+
+165
+00:14:48,790 --> 00:14:56,130
+acid من نبات سوريل، للأوكزاليك family، التاني مالونك 
+
+166
+00:14:56,130 --> 00:15:08,150
+أسد من المالون، التالت، التالت
+
+167
+00:15:08,150 --> 00:15:14,070
+succinic acid، الغلوتاريك أسد، خمس ذرات كربون،
+
+168
+00
+
+201
+00:18:42,890 --> 00:18:48,810
+البيوتين يكون بيوتين بمعنى double bond مش triple
+
+202
+00:18:48,810 --> 00:18:53,720
+لاحظوا في حالة الـ double bond بتجيني ظاهرة 
+
+203
+00:18:53,720 --> 00:18:56,320
+غير موجودة في الـ triple bond اللي هي ظاهرة الـ
+
+204
+00:18:56,320 --> 00:18:59,880
+cis والـ trans ال triple bond linear اتفقنا احنا
+
+205
+00:18:59,880 --> 00:19:04,420
+أن ال triple bond linear دائما حوالين ال triple
+
+206
+00:19:04,420 --> 00:19:10,440
+bond ازاوي كده؟ 180 يعني أي جزء ولو هنا تنور اسمه
+
+207
+00:19:10,440 --> 00:19:16,530
+إكمال لكن حقيقة أي جزء دبل بوند هو عبارة عن linear
+
+208
+00:19:16,530 --> 00:19:20,530
+molecule بس لما بيصير عندي double bond وبيكونها
+
+209
+00:19:20,530 --> 00:19:24,130
+مجموعات مختلفة ومع المجموعات المختلفة بيصير عندي
+
+210
+00:19:24,130 --> 00:19:29,090
+إمكانية لظاهرة الـ cis والـ trans فلو إجينا على
+
+211
+00:19:29,090 --> 00:19:34,790
+هذا الحامض اللي هو الـ 2-butyldioic acid أو الـ
+
+212
+00:19:34,790 --> 00:19:40,010
+butyldioic acid واطلعنا على مجموعات الحامض هنا كيف
+
+213
+00:19:40,010 --> 00:19:46,330
+اتجاهها؟ فيه عنده cis وفيه عنده trans فيه عنده cis
+
+214
+00:19:46,330 --> 00:19:55,210
+وفي عنده trans الآن الـ cis بيسموه malic acid
+
+215
+00:19:55,210 --> 00:20:03,750
+شو بيسموه ماليك أسد والترانس fumaric acid لاحظوا 
+
+216
+00:20:03,750 --> 00:20:09,610
+بدياكم نميزه عن التلات كربونات اسمها مالونك في
+
+217
+00:20:09,610 --> 00:20:13,150
+التلات كربونات الاسم الـ common malonic الآن هنا
+
+218
+00:20:13,150 --> 00:20:23,200
+الاسم ماليك malic acid الآن الترانس منه fumaric acid
+
+219
+00:20:23,200 --> 00:20:29,340
+هدول حقيقة الإسمين جايين من أسماء التفاح وبعض
+
+220
+00:20:29,340 --> 00:20:34,520
+الأعشاب اللاتينية من الأحماض الشهيرة والمفصولة
+
+221
+00:20:34,520 --> 00:20:38,780
+الزمان وإذا حتى يعني مش مصدقين إذا ناس اشتروا كتاب
+
+222
+00:20:38,780 --> 00:20:43,320
+الـ organic chemistry بلاحظوا أن صفحة الغلاف تبعته
+
+223
+00:20:43,320 --> 00:20:47,620
+مرسوم عليها تفاحة خضراء لأن التفاحة الخضراء أو
+
+224
+00:20:47,620 --> 00:20:52,000
+التفاح أساس هذا الحامض شايفين التفاحة اللي هيك
+
+225
+00:20:52,000 --> 00:20:57,700
+خضرة عصفار اللي اشتروا الكتاب Malic and fumaric
+
+226
+00:20:57,700 --> 00:21:02,080
+acid طبعا الماليك والـ fumaric acid أسماء common
+
+227
+00:21:02,080 --> 00:21:08,500
+names مطلوب نحفظهم بالذات هدول وبتالي مرات في
+
+228
+00:21:08,500 --> 00:21:11,560
+تجربة في المختبر بيمروا عليك وماعرفش إذا أخدت
+
+229
+00:21:11,560 --> 00:21:15,520
+ماليك أو fumaric
+
+230
+00:21:15,520 --> 00:21:19,460
+أسد المفروض في طالبة organic تحفظهم الآن لما بيكون
+
+231
+00:21:19,460 --> 00:21:25,240
+عنده حامضين على البنزين بيستعملوا إذا كانوا على
+
+232
+00:21:25,240 --> 00:21:29,300
+الـ ortho position of phthalic acid على الميتا
+
+233
+00:21:29,300 --> 00:21:39,540
+isophthalic acid وعلى الـ para terephthalic acid واضح؟ إذا 
+
+234
+00:21:39,540 --> 00:21:43,860
+في عندي الـ Phthalic Acid والـ Iso-Phthalic Acid والـ
+
+235
+00:21:43,860 --> 00:21:48,760
+Tere-Phthalic Acid أقل تقدير لازم تكونوا عارفين
+
+236
+00:21:48,760 --> 00:21:51,780
+وحافظين الـ Phthalic Acid لأنه بعد شوية هتتعلموا
+
+237
+00:21:51,780 --> 00:21:56,160
+أن الـ Malic Acid والـ Phthalic Acid بنعمل منهم
+
+238
+00:21:56,160 --> 00:22:00,680
+anhydrates بينما بنعملهم مش من مركبات تانية يعني
+
+239
+00:22:00,680 --> 00:22:07,260
+هدول المركبات تحديداً الـ Malic Acid والـ isophthalic
+
+240
+00:22:07,260 --> 00:22:11,120
+acid لما نأخذ الـ anhydrates هنتعلم أنه they can
+
+241
+00:22:11,120 --> 00:22:15,020
+form anhydrates ممكن يعملوا anhydrates التاليين
+
+242
+00:22:15,020 --> 00:22:20,520
+ما بيعملهمش بس هدول المركبين في عامل مشترك بينهم أنه
+
+243
+00:22:20,520 --> 00:22:25,360
+they can form anhydrates يعني بيفقدوا الميه و
+
+244
+00:22:25,360 --> 00:22:30,000
+بيعملوا شكل معين لما نأخذ الـ anhydrates بنركز عليه
+
+245
+00:22:30,000 --> 00:22:30,380
+أكثر
+
+246
+00:22:52,220 --> 00:22:57,060
+الآن نجي لـ Physical Properties of Acids زي ما
+
+247
+00:22:57,060 --> 00:23:02,020
+اتفقنا أننا عادة بناخد العائلات العضوية تسمية،
+
+248
+00:23:02,020 --> 00:23:08,660
+خواص، تحضير، تفاعلات، واضح؟ دائماً تسمية، خواص،
+
+249
+00:23:08,660 --> 00:23:14,360
+تحضير، تفاعلات، هذا اللي بنمشي عليه أهم شغلة بتميز
+
+250
+00:23:14,360 --> 00:23:19,820
+الأحماض قصة حقيقة الـ hydrogen bonding يعني الـ
+
+251
+00:23:19,820 --> 00:23:23,020
+hydrogen bonding اللي هي الـ H اللي موجودة على
+
+252
+00:23:23,020 --> 00:23:26,360
+الـ COOH دي مهمة كثير ممكن يعملوا hydrogen bonding
+
+253
+00:23:26,360 --> 00:23:30,700
+بطرق كثيرة وفعلاً ممكن نطلع على حامضين كيف بيعملوا
+
+254
+00:23:30,700 --> 00:23:37,420
+hydrogen bonding يعني هذا يعتبر حامض وهذا يعتبر حامض
+
+255
+00:23:37,420 --> 00:23:43,020
+ثاني لاحظوا بين هذه الـ H والـ O في الرابطة الـ .. ال
+
+256
+00:23:43,020 --> 00:23:47,220
+dash المقطعة هذه عبارة عن hydrogen bond وهنا في
+
+257
+00:23:47,220 --> 00:23:52,060
+كمان hydrogen bond هذا الكلام بيؤدي إلى إيش؟ بيؤدي
+
+258
+00:23:52,060 --> 00:23:57,820
+إلى أن الـ boiling point لهذه الأحماض تصير مرتفعة
+
+259
+00:23:57,820 --> 00:24:01,420
+جداً لأنها عاملة intramolecular forces فإذا بتطلع
+
+260
+00:24:01,420 --> 00:24:09,010
+مثلاً على الـ formic acid أبسط حامض فيه واحد قارنوا
+
+261
+00:24:09,010 --> 00:24:12,270
+أنتوا بالميثان اللي هو كربونة واحدة بس ما فيه
+
+262
+00:24:12,270 --> 00:24:15,230
+hydrogen bonding ناقص مائتين وستين يعني الفرق بينهم
+
+263
+00:24:15,230 --> 00:24:20,030
+حوالي مائتين وستين درجة إيش اللي خلى هذا يكون
+
+264
+00:24:20,030 --> 00:24:25,470
+مرتفع جداً زي وزي الميه تقريباً الـ acetic acid مائة و
+
+265
+00:24:25,470 --> 00:24:32,930
+ثمانية وتمانين الـ acetic acid 118 عالي جداً لما أجيب propanoic
+
+266
+00:24:32,930 --> 00:24:43,770
+acid 141، 164، 205 زي ما بتلاحظوا أنه الـ
+
+267
+00:24:43,770 --> 00:24:48,650
+boiling point عالية الـ solubility تقريباً نفس
+
+268
+00:24:48,650 --> 00:24:52,290
+الفكرة اللي حكيناها في الـ alcohols أن الـ lower
+
+269
+00:24:52,290 --> 00:24:57,180
+acids are soluble ليش؟ لأنه بيكون متغلب فيه جانب
+
+270
+00:24:57,180 --> 00:25:03,260
+الـ OH لكن لما الحمض بيكبر زي الـ hexanoic acid
+
+271
+00:25:03,260 --> 00:25:08,440
+بيصير جزء الـ OH هذا اللي هو جزء الذوبان في الميه
+
+272
+00:25:08,440 --> 00:25:12,840
+أو الـ hydrophilic اللي بيدوب في الميه مقارنة
+
+273
+00:25:12,840 --> 00:25:20,250
+بالجزء اللي ما بيدوبش في الميه هذا ولذلك الأحماض
+
+274
+00:25:20,250 --> 00:25:24,010
+الصغيرة زي الـ formic acid والـ acetic acid والـ
+
+275
+00:25:24,010 --> 00:25:27,910
+propanoic acid والـ butanoic acid هم سولوبلين
+
+276
+00:25:27,910 --> 00:25:31,290
+لما أجعل الـ hexanoic acid بلاحظ السولوبيلية واحد
+
+277
+00:25:31,290 --> 00:25:35,430
+جرام في كل مائة من الميه خلاص بيبطل يدوب تقريباً
+
+278
+00:25:36,450 --> 00:25:42,550
+ليش؟ لأنه بيصير الـ non-polar part أكبر كثير من الـ
+
+279
+00:25:42,550 --> 00:25:48,690
+polar part فهذه الأحماض مكونة من شغلتين، non-polar
+
+280
+00:25:48,690 --> 00:25:54,850
+part والـ polar part واضح؟ فبالأحماض الصغيرة الـ polar
+
+281
+00:25:54,850 --> 00:25:59,030
+part غالب، بالأحماض الكبيرة الـ non-polar part
+
+282
+00:25:59,030 --> 00:26:04,230
+affects the solubility and makes them insoluble in
+
+283
+00:26:04,230 --> 00:26:11,740
+water هذا بالنسبة للـ boiling point بالنسبة للـ
+
+284
+00:26:11,740 --> 00:26:20,340
+solubility بتيجي شغلة بالنسبة للـ acidity
+
+285
+00:26:20,340 --> 00:26:25,220
+الحامضية بهيئالي احنا لما حكينا على الـ alcohols
+
+286
+00:26:25,220 --> 00:26:30,060
+أكثر من مرة ركزنا على الـ acidity قلنا أن هدول
+
+287
+00:26:30,060 --> 00:26:34,100
+الأحماض بالنسبة للـ alcohols تعتبر الـ acidity
+
+288
+00:26:34,100 --> 00:26:39,230
+تبعتهم أعلى بكثير يعني الـ alcohol الـ pKa كذا كان
+
+289
+00:26:39,230 --> 00:26:45,530
+تقريباً 17 و18 و16 الأحماض زي الـ acetic acid
+
+290
+00:26:45,530 --> 00:26:51,690
+أربعة وخمسة فهدول أعلى كثير كثير من الـ alcohol
+
+291
+00:26:51,690 --> 00:26:55,410
+في الـ acidity شو هو السبب أنهم أعلى كثير كثير من
+
+292
+00:26:55,410 --> 00:26:59,370
+الـ alcohol في الـ acidity أنه لما بيفقد هذا الـ
+
+293
+00:26:59,370 --> 00:27:03,170
+proton لما بيفقد هذا الـ proton فيه عنده هنا الـ
+
+294
+00:27:03,170 --> 00:27:08,410
+minus charge ممكن تكون على هذه الأكسجينة وممكن تلف
+
+295
+00:27:08,410 --> 00:27:12,590
+بهذا الشكل وتصير على الأكسجينة الثانية إذا السبب
+
+296
+00:27:12,590 --> 00:27:18,100
+هو الـ resonance واضح؟ الـ stability لـ negative ion
+
+297
+00:27:18,100 --> 00:27:22,360
+is due to resonance stability of the negative ion
+
+298
+00:27:22,360 --> 00:27:27,720
+is due to resonance فالـ acids they are .. يعني
+
+299
+00:27:27,720 --> 00:27:32,260
+their acidity is high due to resonance هذه الفكرة
+
+300
+00:27:32,260 --> 00:27:37,040
+الأساسية لما أبدأ أقارن أنا حامض بكحول يعني لما أبدأ
+
+301
+00:27:37,040 --> 00:27:42,320
+أقارن مثلاً الإيثانول بيعمل الايون الـ minus CH2 O
+
+302
+00:27:42,320 --> 00:27:51,820
+minus CH3 مع الـ acid C double bond O O minus CH3
+
+303
+00:27:51,820 --> 00:27:58,960
+هنا الـ pKa تقريباً كانت لإيثانول 17 هنا الـ pKa
+
+304
+00:27:58,960 --> 00:28:04,940
+أربعة ونصف واضح؟ ليه شد أعلى بكثير من هذا؟ لأن هنا
+
+305
+00:28:04,940 --> 00:28:09,500
+الـ charge بيقولوا عنها localized يعني متموضعة في
+
+306
+00:28:09,500 --> 00:28:14,140
+مكانها ما بتتغيرش زي واحد حامل شغلة طول الطريق
+
+307
+00:28:14,140 --> 00:28:17,780
+بإيد واحدة شو بيصير له إيده؟ بتتعب لكن واحد عنده
+
+308
+00:28:17,780 --> 00:28:22,880
+إثنين بيكون بيعمل resonance فهنا عندي localized
+
+309
+00:28:22,880 --> 00:28:28,280
+charge وهنا في عند الـ charged إيش بتكون؟
+
+310
+00:28:28,280 --> 00:28:32,650
+delocalized مرة هنا ومرة هنا يعني هذا الـ resonance
+
+311
+00:28:32,650 --> 00:28:38,970
+structure الثاني تبعه كيف بده يكون CH3C
+
+312
+00:28:38,970 --> 00:28:44,550
+لو حركنا هذا الـ minus هيك وهذه هنا بهذا الشكل O
+
+313
+00:28:44,550 --> 00:28:48,750
+minus double bond O فزي ما بتلاحظوا الـ minus هذه
+
+314
+00:28:48,750 --> 00:28:52,590
+مرة موجودة على هذه الـ oxygen مرة موجودة على هذه الـ
+
+315
+00:28:52,590 --> 00:28:55,370
+oxygen فالـ minus charge is
+
+316
+00:29:00,220 --> 00:29:03,860
+والـ delocalization هو أحد أسباب الـ stability of
+
+317
+00:29:03,860 --> 00:29:08,720
+its charge دائماً زي ما قلنا الحمل إذا توزع
+
+318
+00:29:08,720 --> 00:29:12,940
+ينشد هملاحظين؟ هذه محمولة على جهتين الـ negative
+
+319
+00:29:12,940 --> 00:29:16,640
+charge مش على جهة واحدة delocalized وبالتالي الـ
+
+320
+00:29:16,640 --> 00:29:20,940
+ion السالب بتبات وبيزيد الحامض بيصير أقوى هذا
+
+321
+00:29:20,940 --> 00:29:26,950
+الكلام لو أنا كنت بقارن حامض مع كحول لو كنت بقارن
+
+322
+00:29:26,950 --> 00:29:36,170
+حامض مع كحول لكن في وعشانك لاحظوا في الأحماض
+
+323
+00:29:36,170 --> 00:29:45,370
+بشكل عام لما تطلعوا على الـ pKa معظمها
+
+324
+00:29:45,370 --> 00:29:51,720
+في منطقة التلاتة والاربعة واضح؟ إتنين، أربع، أربع،
+
+325
+00:29:51,720 --> 00:29:55,840
+أربع، تلاتة، إتنين واطفر فمعظمها بينما لو بدأ
+
+326
+00:29:55,840 --> 00:30:02,820
+أقارن بالإيثانول والميه هذا كحول تقريباً وهذا
+
+327
+00:30:02,820 --> 00:30:09,260
+ميه 16 و15 واضح؟ الفينول بدأ يصير فيه resonance
+
+328
+00:30:09,260 --> 00:30:13,900
+بس الـ resonance على أكسوجين و Carbon بينزل لعشرة
+
+329
+00:30:13,900 --> 00:30:19,050
+لكن وين ما فيش resonance نهائي هدول التلات اللي تحت
+
+330
+00:30:19,050 --> 00:30:23,730
+الإيثانول والميه ما فيش إمكانية وبالتالي هدول
+
+331
+00:30:23,730 --> 00:30:27,790
+بنلاقيهم احنا إيش في دايل الخيبة بينما بشكل عام
+
+332
+00:30:27,790 --> 00:30:36,670
+الأحماض كلهم لهم pKa عالية due to resonance pKa
+
+333
+00:30:36,670 --> 00:30:41,610
+منخفضة acidity عالية ما كل ما الـ pKa نزلت الحمضية
+
+334
+00:30:41,610 --> 00:30:46,520
+أقوى بيكون الـ Ka أعلى وهذا الـ resonance بتالي
+
+335
+00:30:46,520 --> 00:30:50,700
+المرض حانة بشكل جيد الآن إذا اتبع هذا الـ
+
+336
+00:30:50,700 --> 00:30:56,890
+resonance نقطة أنه في نفس الحامض في نفس الحامض لو
+
+337
+00:30:56,890 --> 00:31:01,470
+حطيت electron withdrawing group أو electron
+
+338
+00:31:01,470 --> 00:31:05,530
+donating group شو بتأثر على الـ acidity؟ يعني مثلاً
+
+339
+00:31:05,530 --> 00:31:10,570
+هي الـ acetic acid وفي resonance طب لو حطيت
+
+340
+00:31:10,570 --> 00:31:15,470
+chloroacetic acid وبعدك حطيت dichloroacetic acid
+
+341
+00:31:15,470 --> 00:31:19,690
+وبعدك حطيت trichloroacetic acid وسؤالك which is
+
+342
+00:31:19,690 --> 00:31:26,830
+more acidic؟ الـ trichloroacetic acid في عملية
+
+343
+00:31:26,830 --> 00:31:31,930
+electron withdrawing يعني فيه inductive effect
+
+344
+00:31:31,930 --> 00:31:36,910
+فلاحظوا هنا لما أنا بحكي عن الـ acetic acid هذا
+
+345
+00:31:36,910 --> 00:31:43,210
+التنقل اللي هنا شو احنا سميناه؟ resonance effect
+
+346
+00:31:43,210 --> 00:31:47,390
+الآن هذا الـ resonance موجود فيهم كلهم إن زاد على
+
+347
+00:31:47,390 --> 00:31:54,130
+الـ resonance الـ resonance ما زال موجود زاد عليه الـ
+
+348
+00:31:54,130 --> 00:31:58,210
+inductive effect أنه فيه مجموعة بتسحب الإلكترونات
+
+349
+00:31:58,210 --> 00:32:02,570
+بتساعد في حمل الإلكترونات فصار عندي تأثيرين صار
+
+350
+00:32:02,570 --> 00:32:07,030
+عندي بدل التأثير إتنين inductive effect plus
+
+351
+00:32:07,030 --> 00:32:11,370
+resonance effect وبالتالي هذا الحامض اللي هو الـ
+
+352
+00:32:11,370 --> 00:32:16,130
+trichloroacetic acid بتكون الـ acidity تبعته أقوى
+
+353
+00:32:16,130 --> 00:32:22,560
+كثير من الـ acetic acid أو من الـ طبعاً لو اجيتوا و
+
+354
+00:32:22,560 --> 00:32:26,660
+قارنتوا الـ trifluoroacetic acid مع الـ trichloro الـ
+
+355
+00:32:26,660 --> 00:32:31,400
+trifluoro أقوى كثير ما بعرفش إذا أنا حاطين لكم هاي
+
+356
+00:32:31,400 --> 00:32:35,780
+القيم هنا لما بدكم تحديدا للـ acetic acid مع الـ
+
+357
+00:32:35,780 --> 00:32:39,920
+trichloroacetic acid أنه اللي قلنا عنه أعلى
+
+358
+00:32:39,920 --> 00:32:44,340
+واحد هاي الـ trichloroacetic acid شايفينه؟ وهاي الـ
+
+359
+00:32:44,340 --> 00:32:50,230
+acetic acid الـ acetic acid 4.7 لـ
+
+360
+00:32:50,230 --> 00:32:56,470
+trichloroacetic acid 0.7 ملاحظين قد ايش صار أقوى
+
+361
+00:32:56,470 --> 00:33:01,150
+كحامض بالتالي لو بدو ييجي على الجلد ولا إيش بدو
+
+362
+00:33:01,150 --> 00:33:04,770
+يحرقهم الـ Acetic acid بحرق الجلد بس لما يكون مخفف
+
+363
+00:33:04,770 --> 00:33:09,590
+بالميه ممكن الناس يعني ييجي على الجلد إذا فيه جرح
+
+364
+00:33:09,590 --> 00:33:13,710
+بيحرق بس إذا خفف بميه كثير بيمسكون الناس اللي خلوه
+
+365
+00:33:13,710 --> 00:33:19,380
+بيشربوه كمان بالمناسبة بس لازم يكون مخفف وأفضل ما
+
+366
+00:33:19,380 --> 00:33:25,340
+تداويتم بيه الخل واضح؟ ليش؟ لأنه لما تدرسوا
+
+367
+00:33:25,340 --> 00:33:28,440
+biochemistry هتلاحظوا أن هذا الخل المكون من
+
+368
+00:33:28,440 --> 00:33:32,640
+كربونتين هو مصدر للمركبات الأكبر يعني الإتنين
+
+369
+00:33:32,640 --> 00:33:35,080
+بيصيروا أربعة الأربعة بيصيروا ستة الستة بيصيروا
+
+370
+00:33:35,080 --> 00:33:38,160
+ثمانية الثمانية بيصيروا عشرة بيصير عندي تفاعل
+
+371
+00:33:38,160 --> 00:33:42,240
+متتالي بيزيد لعدد الكربونات وبهيك بتتكون المركبات
+
+372
+00:33:42,240 --> 00:33:46,700
+في جسم الإنسان فنقطة الانطلاق تبعها إيش؟ الـ two
+
+373
+00:33:46,700 --> 00:33:50,120
+carbons ولذلك كثير من المركبات الطبيعية بتلاقوها
+
+374
+00:33:50,120 --> 
+
+401
+00:36:04,770 --> 00:36:11,870
+فيه مجتمع دائما إذا .. إذا اختلفت .. إذا اختلفت 
+
+402
+00:36:11,870 --> 00:36:16,690
+الأشياء بيصير المقارنة من خلال إنه نبحث عن القيم
+
+403
+00:36:16,690 --> 00:36:21,630
+الحقيقية بالتجربة بقدرش أعطي جواب بقدرش أعطي جواب
+
+404
+00:36:21,630 --> 00:36:24,930
+وجدها واضح؟ يعني ممكن
+
+405
+00:36:26,980 --> 00:36:31,940
+كيف .. كيف يصير السؤال؟ يعني لو أنت .. إجينا و
+
+406
+00:36:31,940 --> 00:36:38,220
+سألناكي أيهما أقوى الـ trifluoroacetic acid ولا 
+
+407
+00:36:38,220 --> 00:36:42,940
+الـ trifluoroacetic acid؟ الآن أنا .. أنا بسهولة
+
+408
+00:36:42,940 --> 00:36:47,400
+بقدر أقول أنه الـ trifluoro لأنه الـ acid مشترك
+
+409
+00:36:48,140 --> 00:36:53,380
+وثلاثة مشتركين سالبية الفلورو صح كل الإلكترونات
+
+410
+00:36:53,380 --> 00:36:58,620
+أعلى من سالبية الكلور طيب لو أتيت أسألك بهذا الشكل
+
+411
+00:36:58,620 --> 00:37:07,140
+كانتلك سيضة بالبنط OOH CH2 وفلورو واحدة الفلورو
+
+412
+00:37:07,140 --> 00:37:14,830
+أسيتك أسد ولا تريكلورو أسيتك أسد؟ صار عندي أنا
+
+413
+00:37:14,830 --> 00:37:19,530
+متغيرين مش متغير واحد صار المتغير الأول اللي عندي
+
+414
+00:37:19,530 --> 00:37:22,890
+عدد الذرات اللي هنا والمتغير بتاع الـ
+
+415
+00:37:22,890 --> 00:37:27,770
+electronegativity في هذه الحالة أنا بقول ما بعرفش
+
+416
+00:37:27,770 --> 00:37:33,370
+الجواب لازم أشوف التجربة وانتش أنا بسهولة كان بعرف 
+
+417
+00:37:33,370 --> 00:37:37,430
+الجواب لو كان السؤال زي هي صيدم الـ point O O H
+
+418
+00:37:41,640 --> 00:37:48,400
+هنا المتغير الواحد عندي asset عندي one one atom بس
+
+419
+00:37:48,400 --> 00:37:50,600
+اتغير الـ flour و الـ chlorine مين more electro
+
+420
+00:37:50,600 --> 00:37:58,280
+negative الـ flour لكن لو صاروا هدول اثنين يمكن
+
+421
+00:37:58,280 --> 00:38:02,800
+يكون مجموعة دول الاثنين مغطية الزيادة اللي بسببها
+
+422
+00:38:02,800 --> 00:38:07,340
+الـ flour فانها لازم أعمل تجربة يعني ما بقدرش أعطي 
+
+423
+00:38:07,340 --> 00:38:13,220
+الجواب مباشر إذا كان عندي أكثر من شيء وهذا الكلام
+
+424
+00:38:13,220 --> 00:38:18,040
+بالمناسبة يعني من مبادئ العلم الأساسية .. من مبادئ
+
+425
+00:38:18,040 --> 00:38:21,260
+العلم الأساسية جدا أنه أنتو إذا بدكوا تقارنوا
+
+426
+00:38:21,260 --> 00:38:27,420
+شغلات .. إذا بدكوا تقارنوا شغلات بدكوا توحدوا جميع
+
+427
+00:38:27,420 --> 00:38:34,940
+الظروف .. بدكوا توحدوا جميع الظروف ما عدا متغير
+
+428
+00:38:34,940 --> 00:38:42,420
+واحد بتكون تواحده جميع الظروف مع دقاش، متغير واحد،
+
+429
+00:38:42,420 --> 00:38:45,460
+هذا الكلام ممكن أعطيكم عليه مثال من العلم، من
+
+430
+00:38:45,460 --> 00:38:49,120
+الكيميا وممكن مثال من السياسة، من الدنيا، الآن لما
+
+431
+00:38:49,120 --> 00:38:54,860
+أخذتوا قوانين الغازات الغاز محكوم بإيش؟ بالضغط
+
+432
+00:38:54,860 --> 00:39:00,160
+والحجم ودرجة الحرارة والمولات كان عندي أربع
+
+433
+00:39:00,160 --> 00:39:06,160
+متغيرات لما كنت بعمل مقارنة كيف كنت أنا أقارن كنت
+
+434
+00:39:06,160 --> 00:39:11,120
+أثبت متغيرات وأقارن متغيرات ثانية بس ما بقدرش أسيب
+
+435
+00:39:11,120 --> 00:39:16,780
+الأربعة يتغيروا وهذا الغاز بضغط معين، بحجم معين،
+
+436
+00:39:16,780 --> 00:39:19,900
+number of moles معين، temperature معينة وهذاك
+
+437
+00:39:19,900 --> 00:39:24,800
+بالأربع أشياء مختلفة، بتصير العملية إيش صعبة،
+
+438
+00:39:24,800 --> 00:39:29,680
+فالإنسان العلمي لما بده يقارن، بده يوحد الظروف ..
+
+439
+00:39:29,680 --> 00:39:35,200
+بده يوحد الظروف وبعدين بده ييجي يقارن أما نيجي
+
+440
+00:39:35,200 --> 00:39:39,420
+نعمل حالنا شاطرين .. نعمل حالنا شاطرين وبدنا 
+
+441
+00:39:39,420 --> 00:39:46,180
+نقارن بظروف مختلفة فالكلام ما بيصيرش ربما مثلا يعني
+
+442
+00:39:46,180 --> 00:39:51,460
+أعطيكوا مثال إيش منطق التفكير الغربي .. إيش منطق
+
+443
+00:39:51,460 --> 00:39:58,680
+التفكير الغربي التفكير الغربي فكر بشكل آتي إنه بدوا
+
+444
+00:39:58,680 --> 00:40:04,180
+يوقع مثلا الفلسطينيين بإشكالية
+
+445
+00:40:04,180 --> 00:40:07,960
+مع الإسلاميين ومع الحكومات الإسلامية وما إلى ذلك
+
+446
+00:40:07,960 --> 00:40:14,580
+فإنها بدوا يثبت فشل كل الإسلام مش حركة معينة
+
+447
+00:40:14,580 --> 00:40:21,440
+العداوة عامة صار في حكومة بشكل أو بآخر اسمها حكومة
+
+448
+00:40:21,440 --> 00:40:24,380
+حركة إسلامية إيش الحل اللي بدوا يعملوا؟ بدوا يثبت
+
+449
+00:40:24,380 --> 00:40:28,790
+للناس إن هدول سواد وجه ما جاش منهم غير الفلس
+
+450
+00:40:28,790 --> 00:40:31,930
+والإسفاف في الشوارع وهلوم هلوم هلوم هلوم هلوم
+
+451
+00:40:31,930 --> 00:40:38,310
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+452
+00:40:38,310 --> 00:40:38,390
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+453
+00:40:38,390 --> 00:40:38,750
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+454
+00:40:38,750 --> 00:40:40,590
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+455
+00:40:40,590 --> 00:40:46,350
+هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم هلوم
+
+456
+00:40:46,350 --> 00:40:53,710
+هلوم
+
+457
+00:40:54,720 --> 00:40:59,480
+ما فيش إمكانية للمقارنة كيف .. كيف أنا بدي أقارن
+
+458
+00:40:59,480 --> 00:41:04,480
+تمامًا ممكن واحدة منكم تكون ذكية كثير لكن هذه أمها
+
+459
+00:41:04,480 --> 00:41:08,740
+الله يرحمها توفت عندها ستة إخوة في الدار وواحدة
+
+460
+00:41:08,740 --> 00:41:11,520
+فاضية وعامليني لا فاصليني لا أقضي لحالة وأقعد
+
+461
+00:41:11,520 --> 00:41:14,900
+أدرسي وما إلى ذلك هل بقدر أنا أعمل مقارنة بينهم
+
+462
+00:41:14,900 --> 00:41:19,870
+في الذكاء ولا .. ما الظروف إيش؟ الظروف مختلفة،
+
+463
+00:41:19,870 --> 00:41:23,670
+فاللي بده يقارن، يعني لو بده أقول مين فيهم أذكى من
+
+464
+00:41:23,670 --> 00:41:28,990
+التانية، بده أجي لأختين الاثنتين توأم خلّينا نقول
+
+465
+00:41:28,990 --> 00:41:32,590
+ساكنين بنفس البيت، كل واحدة معطينها غرفة، معطينها 
+
+466
+00:41:32,590 --> 00:41:36,390
+كمبيوتر، معطينها كتاب، معطينها مصروف، معطينها أكل،
+
+467
+00:41:36,390 --> 00:41:40,550
+وفي الآخر هذه بتيجي اللي هي جايبالي 90% وهذه
+
+468
+00:41:40,550 --> 00:41:44,910
+بالعافية بتجيبي الـ 60% وأجتا بقول أكيد هذه مخها
+
+469
+00:41:44,910 --> 00:41:51,030
+أنضف شوية من هذه، لأن أنا وحدت كل إيش كل الظروف
+
+470
+00:41:51,030 --> 00:41:56,850
+فهنا نفس الفكرة واضح؟ لما بدي أقارن بدي أوحد
+
+471
+00:41:56,850 --> 00:42:02,710
+الظروف ما عدا المتغير اللي بندرسه بالمناسبة هذا
+
+472
+00:42:02,710 --> 00:42:07,730
+الكلام هو سبب إشكالية في العلم إنه كثير شغلات لحد
+
+473
+00:42:07,730 --> 00:42:13,610
+الآن الناس مش قادرين بالضبط يحكموا عليها يعني مثلا
+
+474
+00:42:13,610 --> 00:42:17,150
+كثير من الأشياء بيجوا بيقولوا لكوا والله هالشغلة
+
+475
+00:42:17,150 --> 00:42:24,180
+بتسبب سرطان ولا لأ؟ أو بتسبب مشاكل صحية ولا لأ؟ طب
+
+476
+00:42:24,180 --> 00:42:27,700
+ليش احنا مش قادرين نحكم؟ لسبب بسيط أن البني آدم
+
+477
+00:42:27,700 --> 00:42:33,180
+اللي بندرسه حقيقة هو مش بس معرض مش بس معرض مثلا
+
+478
+00:42:33,180 --> 00:42:37,790
+للكيمويات اللي ارتشت على الفراولة ما هو المشكلة لو
+
+479
+00:42:37,790 --> 00:42:43,030
+أن البني آدم محطوط في جو معزول تماما وبس بياكل
+
+480
+00:42:43,030 --> 00:42:47,010
+فراولة مرشوشة والتاني بياكل فراولة مش مرشوشة و
+
+481
+00:42:47,010 --> 00:42:50,670
+هذا مرض وهذا لأ بقول أنه السبب من الفراولة لكن
+
+482
+00:42:50,670 --> 00:42:55,630
+البني آدم معرض ممكن واحد يكون ساكن عند ساحة
+
+483
+00:42:55,630 --> 00:43:00,450
+التكسيات، بشم رصاص في البنزين، وهالومة جرّان
+
+484
+00:43:00,450 --> 00:43:03,910
+كثير، والتاني ساكن في منطقة رفيعة. هاي متغير ثاني
+
+485
+00:43:03,910 --> 00:43:09,230
+صار عنده. ممكن هذا بياكل بندورة مرشوشة وهذا لأ، و
+
+486
+00:43:09,230 --> 00:43:11,670
+هذا بياكل سبانخ مرشوشة وهذا لأ، وبياكل فراولة
+
+487
+00:43:11,670 --> 00:43:15,270
+مرشوشة وهذا لأ. الآن السؤال عاد، بقدر أنا أحلف
+
+488
+00:43:15,270 --> 00:43:20,530
+يمين أن هذا سبب مشكلته الفراولة؟ طب ما هو ..
+
+489
+00:43:20,790 --> 00:43:25,530
+الاختلاف بينهم بالهوى والمية اللي بيشربوها، هذا
+
+490
+00:43:25,530 --> 00:43:28,510
+بيشرب من البيرو، هذا بيشرب الهوى والمية و
+
+491
+00:43:28,510 --> 00:43:31,550
+البندورة والخيار والفراولة بكل ما تحويه من
+
+492
+00:43:31,550 --> 00:43:37,130
+مبيدات، شو عرفنا أن الفراولة هي السبب نفس الشيء
+
+493
+00:43:37,130 --> 00:43:41,550
+مشكلة مثلا أمواج الجوال لليوم لما ييجوا يركبوا
+
+494
+00:43:41,550 --> 00:43:45,290
+برج جوال على دار ناس بيصيروا الجيران يتقاتلوا و
+
+495
+00:43:45,290 --> 00:43:50,550
+الله هذا برج الجوال بيسبب مشاكل ولا لأ وكل القصص
+
+496
+00:43:50,550 --> 00:43:54,910
+ليش احنا مش عارفين ومش قادرين لأنه كثير متغيرات
+
+497
+00:43:54,910 --> 00:44:00,810
+هي بس أنا عندي أمواج الجوال عندي جوال على كيمويات
+
+498
+00:44:00,810 --> 00:44:05,910
+على هوا ملوث يمكن يوصل إشعاع ذرعي كمان من فوكوشيما
+
+499
+00:44:07,890 --> 00:44:13,270
+تستغربوش، هذه دنيا واسعة يعني التاني يوم أو تالت 
+
+500
+00:44:13,270 --> 00:44:16,530
+يوم من مفاعل Fukushima كل الأسماك اللي 
+
+501
+00:44:16,530 --> 00:44:22,110
+بـ California ماتت شوفتوا الصور بتاعتها؟ اكتبوا على
+
+502
+00:44:22,110 --> 00:44:28,030
+Google بس موت الأسماك في California بعد تسنامي
+
+503
+00:44:28,030 --> 00:44:32,200
+اليابان جدّاش المسافة بين اليابان وكاليفورنيا
+
+504
+00:44:32,200 --> 00:44:38,800
+هتشوفوا جرفات عدد كبير من الجرفات بس بزيه سمك ميت
+
+505
+00:44:38,800 --> 00:44:43,060
+البحر ممكن البناء آدمين يمشوا عليه لأن كل السمك 
+
+506
+00:44:43,060 --> 00:44:48,160
+مات وكان طاف فوق سطح البحر الدنيا يعني التأثيرات
+
+507
+00:44:48,160 --> 00:44:53,220
+هذه بتنتقل لما صارت شيرنوبيل مثلا هو شيرنوبيل
+
+508
+00:44:53,220 --> 00:44:59,330
+localized ولا de-localized عليها البنجف على ال
+
+509
+00:44:59,330 --> 00:45:03,310
+preparation of carboxylic acids
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..61555f57a17faa579892895b5119009be7e5f18e
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/93h7sZkWsgc_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 1848, "start": 8.76, "end": 18.48, "text": "اليوم بنكمل في موضوع الأحماض وتحديدا لسه ما زلنا في موضوع تسمية الأحماض", "tokens": [6027, 1829, 20498, 44945, 24793, 1211, 8978, 3714, 2407, 11242, 45367, 16247, 35571, 46958, 34683, 5016, 16254, 28259, 5296, 3794, 3224, 19446, 30767, 1211, 8315, 8978, 3714, 2407, 11242, 45367, 6055, 38251, 10632, 16247, 35571, 46958], "avg_logprob": -0.09670608188654925, "compression_ratio": 1.4606741573033708, "no_speech_prob": 0.0, "words": [{"start": 8.759999999999996, "end": 9.519999999999998, "word": "اليوم", "probability": 0.9412434895833334}, {"start": 9.519999999999998, "end": 10.28, "word": " بنكمل", "probability": 0.94091796875}, {"start": 10.28, "end": 10.44, "word": " في", "probability": 0.92333984375}, {"start": 10.44, "end": 10.82, "word": " موضوع", "probability": 0.994140625}, {"start": 10.82, "end": 11.6, "word": " الأحماض", "probability": 0.9620768229166666}, {"start": 11.6, "end": 15.86, "word": " وتحديدا", "probability": 0.790283203125}, {"start": 15.86, "end": 16.18, "word": " لسه", "probability": 0.8429361979166666}, {"start": 16.18, "end": 16.32, "word": " ما", "probability": 0.5078125}, {"start": 16.32, "end": 16.6, "word": " زلنا", "probability": 0.9537760416666666}, {"start": 16.6, "end": 16.72, "word": " في", "probability": 0.853515625}, {"start": 16.72, "end": 17.06, "word": " موضوع", "probability": 0.95751953125}, {"start": 17.06, "end": 17.68, "word": " تسمية", "probability": 0.9912109375}, {"start": 17.68, "end": 18.48, "word": " الأحماض", "probability": 0.9905598958333334}], "temperature": 1.0}, {"id": 2, "seek": 3944, "start": 19.34, "end": 39.44, "text": "الفكرة الأساسية اللي حكيناها المرة الماضية أنه تسمية حامض تسمية حامض بالتم بإضافة المقطع oic acid و بعد هيك شوفي عندنا مجموعات substituents بنذكرها استعرضنا استعرضنا الأحماض من واحد إلى", "tokens": [6027, 5172, 4117, 25720, 16247, 3794, 32277, 10632, 13672, 1829, 11331, 4117, 1829, 8315, 11296, 9673, 25720, 9673, 46958, 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موقعه، ليش ماقلناش هنا to a propionic acid؟ هذا هو السؤال", "tokens": [6027, 148, 48506, 23758, 21136, 33604, 6027, 14739, 3224, 2423, 8258, 11778, 16373, 15042, 15844, 41950, 28480, 12399, 2423, 8258, 11778, 16373, 15042, 15844, 41950, 28480, 12399, 4724, 1211, 11622, 2304, 8592, 8717, 24401, 3215, 43761, 3714, 30543, 3615, 3224, 12399, 32239, 8592, 19446, 4587, 1211, 1863, 33599, 34105, 281, 257, 2365, 313, 299, 8258, 22807, 23758, 31439, 21136, 33604, 6027], "avg_logprob": -0.29233871304219766, "compression_ratio": 1.6083916083916083, "no_speech_prob": 0.0, "words": [{"start": 209.55, "end": 210.23, "word": "الآن", "probability": 0.5682373046875}, {"start": 210.23, "end": 210.47, "word": " هذا", "probability": 0.591796875}, {"start": 210.47, "end": 211.25, "word": " السؤال", "probability": 0.97119140625}, {"start": 211.25, "end": 212.17, "word": " أنه", "probability": 0.410888671875}, {"start": 212.17, "end": 212.73, "word": " ال", "probability": 0.98291015625}, {"start": 212.73, "end": 213.07, "word": " acid", "probability": 0.9091796875}, {"start": 213.07, "end": 213.55, "word": " دائما", "probability": 0.8343098958333334}, {"start": 213.55, "end": 213.81, "word": " على", "probability": 0.88623046875}, {"start": 213.81, "end": 214.77, "word": " الطرف،", "probability": 0.7902018229166666}, {"start": 214.77, "end": 214.89, "word": " ال", "probability": 0.98291015625}, {"start": 214.89, "end": 215.17, "word": " acid", "probability": 0.9951171875}, {"start": 215.17, "end": 215.51, "word": " دائما", "probability": 0.9329427083333334}, {"start": 215.51, "end": 215.67, "word": " على", "probability": 0.91552734375}, {"start": 215.67, "end": 216.09, "word": " الطرف،", "probability": 0.8268229166666666}, {"start": 216.09, "end": 216.51, "word": " بلزمش", "probability": 0.8130859375}, {"start": 216.51, "end": 217.01, "word": " نحددله", "probability": 0.9083251953125}, {"start": 217.01, "end": 217.99, "word": " موقعه،", "probability": 0.822119140625}, {"start": 217.99, 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عليه واضح؟ بينما هنا انا مضطر مثل هذا المركب لما بدي اسميه 1 2 3 4 5 6 لازم اقول three", "tokens": [3224, 1829, 30544, 568, 12, 675, 87, 3730, 299, 8258, 3714, 43020, 6055, 30544, 34105, 805, 12, 675, 87, 3730, 299, 8258, 1017, 12, 675, 87, 3730, 299, 8258, 1025, 12, 675, 87, 3730, 299, 8258, 34105, 8978, 3224, 1975, 33753, 2304, 6027, 9307, 4724, 3794, 34105, 19446, 41185, 8592, 32771, 13546, 23758, 42963, 33753, 2304, 6027, 6156, 2304, 3615, 11203, 2304, 19446, 44945, 11622, 25708, 8592, 28242, 10943, 47356, 4032, 46958, 5016, 22807, 49374, 15042, 34105, 1975, 8315, 3714, 11242, 9566, 2288, 50113, 1211, 23758, 9673, 31747, 3555, 5296, 15042, 4724, 16254, 24525, 2304, 1829, 3224, 502, 568, 805, 1017, 1025, 1386, 5296, 31377, 2304, 1975, 39648, 1045], "avg_logprob": -0.21406250447034836, "compression_ratio": 1.7230046948356808, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 244.47, "end": 245.15, "word": "هيكون", "probability": 0.6586100260416666}, {"start": 245.15, 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499.6, "word": " الداي", "probability": 0.7353515625}, {"start": 499.6, "end": 500.26, "word": " كربوكسليك", "probability": 0.9946986607142857}, {"start": 500.26, "end": 500.56, "word": " أسد", "probability": 0.984375}, {"start": 500.56, "end": 500.76, "word": " وين", "probability": 0.6483154296875}, {"start": 500.76, "end": 502.5, "word": " موجودين؟", "probability": 0.892578125}, {"start": 502.5, "end": 503.04, "word": " تتعتبر", "probability": 0.6710205078125}, {"start": 503.04, "end": 503.28, "word": " أنها", "probability": 0.526123046875}, {"start": 503.28, "end": 503.44, "word": " دي", "probability": 0.6219482421875}, {"start": 503.44, "end": 503.98, "word": " واحد،", "probability": 0.7980143229166666}, {"start": 503.98, "end": 504.58, "word": " اتنين،", "probability": 0.928125}, {"start": 504.58, "end": 505.08, "word": " تلاتة", "probability": 0.9671630859375}, {"start": 505.08, "end": 505.3, "word": " على", "probability": 0.56396484375}, {"start": 505.3, "end": 505.72, "word": " واحد", "probability": 0.978515625}, {"start": 505.72, "end": 505.86, "word": " و", "probability": 0.86181640625}, {"start": 505.86, "end": 507.4, "word": " تلاتة،", "probability": 0.782763671875}, {"start": 507.4, "end": 507.94, "word": " وكيف", "probability": 0.9044596354166666}, {"start": 507.94, "end": 510.02, "word": " اتجاههم؟", "probability": 0.9532877604166666}, {"start": 510.02, "end": 510.84, "word": " تطلعوا", "probability": 0.81611328125}, {"start": 510.84, "end": 511.78, "word": " على", "probability": 0.53955078125}, {"start": 511.78, "end": 512.14, "word": " جهة", "probability": 0.9493815104166666}, {"start": 512.14, "end": 512.7, "word": " واحدة", "probability": 0.9925130208333334}, {"start": 512.7, "end": 513.5, "word": " للأمام،", "probability": 0.907421875}, {"start": 513.5, "end": 513.66, "word": " إذا", "probability": 0.779052734375}, {"start": 513.66, "end": 514.02, "word": " هم", "probability": 0.780029296875}, {"start": 514.02, "end": 514.92, "word": " سيس", "probability": 0.5214436848958334}, {"start": 514.92, "end": 515.78, "word": " سيس", "probability": 0.6943155924479166}, {"start": 515.78, "end": 516.1, "word": " وان", "probability": 0.705810546875}, {"start": 516.1, "end": 516.54, "word": " ثري", "probability": 0.70703125}, {"start": 516.54, "end": 518.86, "word": " سايكلوهكسين", "probability": 0.79180908203125}, {"start": 518.86, "end": 519.6, "word": " داي", "probability": 0.667724609375}, {"start": 519.6, "end": 520.54, "word": " كربوكسليك", "probability": 0.9958147321428571}, {"start": 520.54, "end": 521.1, "word": " أسد", "probability": 0.9884440104166666}, {"start": 521.1, "end": 522.26, "word": " سيس", "probability": 0.8533528645833334}, {"start": 522.26, "end": 522.5, "word": " وان", "probability": 0.9892578125}, {"start": 522.5, "end": 522.84, "word": " ثري", "probability": 0.9345703125}, {"start": 522.84, "end": 523.76, "word": " سايكلوهكسين", "probability": 0.95428466796875}, {"start": 523.76, "end": 524.02, "word": " داي", "probability": 0.9326171875}, {"start": 524.02, "end": 524.84, "word": " كربوكسليك", "probability": 0.9967912946428571}, {"start": 524.84, "end": 525.38, "word": " أسد", "probability": 0.9944661458333334}], "temperature": 1.0}, {"id": 22, "seek": 55253, "start": 537.37, "end": 552.53, "text": "واضح؟ ها نفس الاشي أمثلة إضافية Cyclopentane بحمل acid شو بنا نسميه؟ Cyclopentane carboxylic acid لو كان حامل الديهايد", "tokens": [2407, 46958, 5016, 22807, 8032, 995, 8717, 36178, 2423, 33599, 1829, 5551, 2304, 12984, 37977, 11933, 11242, 31845, 10632, 10295, 3474, 404, 317, 1929, 4724, 35571, 1211, 8258, 13412, 2407, 4724, 8315, 8717, 38251, 1829, 3224, 22807, 10295, 3474, 404, 317, 1929, 1032, 4995, 88, 1050, 8258, 45164, 25961, 11331, 10943, 1211, 2423, 16254, 11296, 25708], "avg_logprob": -0.2346491207156265, "compression_ratio": 1.2753623188405796, "no_speech_prob": 0.0, "words": [{"start": 537.3699999999999, "end": 538.3299999999999, "word": "واضح؟", "probability": 0.8834228515625}, {"start": 538.3299999999999, "end": 539.29, "word": " ها", "probability": 0.582763671875}, {"start": 539.29, "end": 539.59, "word": " نفس", "probability": 0.990234375}, {"start": 539.59, "end": 539.99, "word": " الاشي", "probability": 0.8292643229166666}, {"start": 539.99, "end": 540.43, "word": " أمثلة", "probability": 0.8936767578125}, {"start": 540.43, "end": 541.23, "word": " إضافية", "probability": 0.9881591796875}, {"start": 541.23, "end": 543.69, "word": " Cyclopentane", "probability": 0.717822265625}, {"start": 543.69, "end": 544.17, "word": " بحمل", "probability": 0.8958333333333334}, {"start": 544.17, "end": 544.51, "word": " acid", "probability": 0.716796875}, {"start": 544.51, "end": 544.73, "word": " شو", "probability": 0.656982421875}, {"start": 544.73, "end": 544.87, "word": " بنا", "probability": 0.4697265625}, {"start": 544.87, "end": 547.63, "word": " نسميه؟", "probability": 0.94677734375}, {"start": 547.63, "end": 549.03, "word": " Cyclopentane", "probability": 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للخلف", "probability": 0.80078125}, {"start": 565.77, "end": 565.97, "word": " أو", "probability": 0.71923828125}, {"start": 565.97, "end": 566.31, "word": " لفوق", "probability": 0.9375}, {"start": 566.31, "end": 566.45, "word": " و", "probability": 0.568359375}, {"start": 566.45, "end": 566.85, "word": " تحت", "probability": 0.868896484375}, {"start": 566.85, "end": 568.09, "word": " بتستعمله", "probability": 0.77093505859375}, {"start": 568.09, "end": 569.81, "word": " Cystrans", "probability": 0.4031168619791667}, {"start": 569.81, "end": 571.29, "word": " Benzoic", "probability": 0.91455078125}, {"start": 571.29, "end": 571.73, "word": " Acid", "probability": 0.81201171875}, {"start": 571.73, "end": 573.19, "word": " Parachlorobenzoic", "probability": 0.7296549479166666}, {"start": 573.19, "end": 574.45, "word": " Acid", "probability": 0.94921875}, {"start": 574.45, "end": 575.17, "word": " Hana", "probability": 0.1865234375}, {"start": 575.17, "end": 576.11, "word": " Toluic", 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" بيستعملوا", "probability": 0.8475748697916666}, {"start": 1284.48, "end": 1284.8, "word": " إذا", "probability": 0.91064453125}, {"start": 1284.8, "end": 1285.12, "word": " كانوا", "probability": 0.98779296875}, {"start": 1285.12, "end": 1285.24, "word": " على", "probability": 0.85986328125}, {"start": 1285.24, "end": 1285.38, "word": " الـ", "probability": 0.52813720703125}, {"start": 1285.38, "end": 1286.24, "word": " orthoposition", "probability": 0.5299479166666666}, {"start": 1286.24, "end": 1286.42, "word": " of", "probability": 0.360107421875}, {"start": 1286.42, "end": 1286.92, "word": " phthalic", "probability": 0.73388671875}, {"start": 1286.92, "end": 1287.48, "word": " acid", "probability": 0.9384765625}, {"start": 1287.48, "end": 1288.46, "word": " على", "probability": 0.78564453125}, {"start": 1288.46, "end": 1289.3, "word": " الميتا", "probability": 0.78759765625}, {"start": 1289.3, "end": 1291.4, "word": " ايزوفتاليك", "probability": 0.7305068969726562}, {"start": 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unhydrates هنتعلم انه they can form unhydrates ممكن يعملوا unhydrates التاليين مابيعملوش بس هدول المركبين في عامل مشترك بينهم انه they can form unhydrates يعني بيفقدوا الميه و بيعملوا شكل معين لما ناخد ال unhydrates بنركز عليه اكثر", "tokens": [2407, 2423, 1030, 3495, 1050, 8258, 5296, 15042, 8717, 47283, 3215, 2423, 517, 21591, 12507, 8032, 29399, 3615, 19528, 16472, 3224, 436, 393, 1254, 517, 21591, 12507, 3714, 43020, 7251, 25957, 1211, 14407, 517, 21591, 12507, 16712, 6027, 1829, 9957, 3714, 16758, 1829, 25957, 1211, 2407, 8592, 4724, 3794, 8032, 3215, 12610, 9673, 31747, 3555, 9957, 8978, 6225, 10943, 1211, 37893, 2655, 31747, 49374, 16095, 16472, 3224, 436, 393, 1254, 517, 21591, 12507, 37495, 22653, 4724, 33911, 28543, 14407, 9673, 1829, 3224, 4032, 4724, 1829, 25957, 1211, 14407, 13412, 28820, 20449, 9957, 5296, 15042, 8717, 47283, 3215, 2423, 517, 21591, 12507, 44945, 31747, 11622, 47356, 1975, 4117, 49115], "avg_logprob": -0.1568234016042237, "compression_ratio": 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boiling", "probability": 0.58251953125}, {"start": 1484.07, "end": 1484.53, "word": " point", "probability": 0.9814453125}, {"start": 1484.53, "end": 1485.11, "word": " عالية", "probability": 0.9698893229166666}, {"start": 1485.11, "end": 1485.89, "word": " ال", "probability": 0.444580078125}, {"start": 1485.89, "end": 1486.83, "word": " solubility", "probability": 0.8099772135416666}, {"start": 1486.83, "end": 1488.37, "word": " تقريبا", "probability": 0.98662109375}, {"start": 1488.37, "end": 1488.65, "word": " نفس", "probability": 0.983642578125}, {"start": 1488.65, "end": 1489.15, "word": " الفكرة", "probability": 0.99365234375}, {"start": 1489.15, "end": 1489.31, "word": " اللي", "probability": 0.939697265625}, {"start": 1489.31, "end": 1489.83, "word": " حكيناها", "probability": 0.92685546875}, {"start": 1489.83, "end": 1489.97, "word": " في", "probability": 0.96142578125}, {"start": 1489.97, "end": 1490.13, "word": " ال", "probability": 0.669921875}, {"start": 1490.13, "end": 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{"start": 1510.98, "end": 1511.3, "word": " بيدوب", "probability": 0.7789713541666666}, {"start": 1511.3, "end": 1511.42, "word": " في", "probability": 0.9892578125}, {"start": 1511.42, "end": 1511.84, "word": " الميه", "probability": 0.9912109375}, {"start": 1511.84, "end": 1512.84, "word": " مقارنة", "probability": 0.96787109375}, {"start": 1512.84, "end": 1513.52, "word": " بالجزء", "probability": 0.9862060546875}, {"start": 1513.52, "end": 1514.76, "word": " اللي", "probability": 0.976806640625}, {"start": 1514.76, "end": 1515.38, "word": " بيدوبش", "probability": 0.8746337890625}, {"start": 1515.38, "end": 1515.54, "word": " في", "probability": 0.9921875}, {"start": 1515.54, "end": 1515.96, "word": " الميه", "probability": 0.9930013020833334}, {"start": 1515.96, "end": 1516.4, "word": " هذا", "probability": 0.94140625}], "temperature": 1.0}, {"id": 59, "seek": 153543, "start": 1517.47, "end": 1535.43, "text": "و لذلك الأحماط الصغيرة زي ال formic acid و ال acetic acid و ال propanoic acid و ال butanoic acid هم سوليوبيلين لما أجعل الhexanoic acid بلاحظة السوليوبيلية واحد جرام في كل مائة من الميه خلاص بيبطل يدوب تقريبا", "tokens": [2407, 5296, 8848, 23275, 16247, 35571, 41193, 31767, 17082, 48923, 30767, 1829, 2423, 1254, 299, 8258, 4032, 2423, 696, 3532, 8258, 4032, 2423, 2365, 3730, 299, 8258, 4032, 2423, 457, 3730, 299, 8258, 8032, 2304, 8608, 12610, 1829, 2407, 21292, 1211, 9957, 5296, 15042, 5551, 7435, 30241, 2423, 675, 87, 3730, 299, 8258, 4724, 15040, 5016, 19913, 3660, 21136, 12610, 1829, 2407, 21292, 1211, 10632, 36764, 24401, 10874, 2288, 10943, 8978, 28242, 3714, 16373, 3660, 9154, 9673, 1829, 3224, 16490, 1211, 33546, 4724, 1829, 3555, 9566, 1211, 7251, 3215, 37746, 6055, 4587, 16572, 3555, 995], "avg_logprob": -0.3935546784972151, "compression_ratio": 1.6894736842105262, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1517.47, "end": 1518.31, "word": "و", "probability": 0.29443359375}, {"start": 1518.31, "end": 1519.01, "word": " 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ال", "probability": 0.93310546875}, {"start": 1524.01, "end": 1524.69, "word": " propanoic", "probability": 0.6048787434895834}, {"start": 1524.69, "end": 1525.13, "word": " acid", "probability": 0.91357421875}, {"start": 1525.13, "end": 1525.27, "word": " و", "probability": 0.97216796875}, {"start": 1525.27, "end": 1525.45, "word": " ال", "probability": 0.90185546875}, {"start": 1525.45, "end": 1526.09, "word": " butanoic", "probability": 0.9436848958333334}, {"start": 1526.09, "end": 1526.47, "word": " acid", "probability": 0.9599609375}, {"start": 1526.47, "end": 1527.25, "word": " هم", "probability": 0.48577880859375}, {"start": 1527.25, "end": 1527.91, "word": " سوليوبيلين", "probability": 0.5590471540178571}, {"start": 1527.91, "end": 1528.31, "word": " لما", "probability": 0.661376953125}, {"start": 1528.31, "end": 1528.73, "word": " أجعل", "probability": 0.8258463541666666}, {"start": 1528.73, "end": 1529.51, "word": " الhexanoic", "probability": 0.6566650390625}, {"start": 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"temperature": 1.0}, {"id": 107, "seek": 270331, "start": 2696.91, "end": 2703.31, "text": "de-localized عليها البنجف على ال preparation of carboxylic acids", "tokens": [1479, 12, 5842, 304, 1602, 25894, 11296, 29739, 1863, 7435, 5172, 15844, 2423, 13081, 295, 1032, 4995, 88, 1050, 21667], "avg_logprob": -0.41741070293244864, "compression_ratio": 0.975609756097561, "no_speech_prob": 0.0, "words": [{"start": 2696.91, "end": 2697.17, "word": "de", "probability": 0.03717041015625}, {"start": 2697.17, "end": 2697.81, "word": "-localized", "probability": 0.7672119140625}, {"start": 2697.81, "end": 2698.55, "word": " عليها", "probability": 0.66552734375}, {"start": 2698.55, "end": 2698.99, "word": " البنجف", "probability": 0.7154541015625}, {"start": 2698.99, "end": 2699.19, "word": " على", "probability": 0.429443359375}, {"start": 2699.19, "end": 2699.33, "word": " ال", "probability": 0.78515625}, {"start": 2699.33, "end": 2699.93, "word": " preparation", "probability": 0.77099609375}, {"start": 2699.93, "end": 2700.51, "word": " of", "probability": 0.9716796875}, {"start": 2700.51, "end": 2702.87, "word": " carboxylic", "probability": 0.893310546875}, {"start": 2702.87, "end": 2703.31, "word": " acids", "probability": 0.80078125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2706.03025, "duration_after_vad": 2560.3959687499914}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f238e20af054edc0b4e41126e077f172657d7d2d
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM.srt
@@ -0,0 +1,1933 @@
+1
+00:00:15,470 --> 00:00:22,450
+اليوم إن شاء الله هنبدأ بفصل جديد الفصل السابع زي
+
+2
+00:00:22,450 --> 00:00:26,410
+ما بتلاحظوا على السطر العنوان اللي عندنا
+
+3
+00:00:26,410 --> 00:00:33,410
+alcohols, phenols and thiols يعني كأنه في هذا
+
+4
+00:00:33,410 --> 00:00:38,690
+الفصل بدأ نستعرض تلات أنواع من المركبات بس أكيد
+
+5
+00:00:38,690 --> 00:00:44,530
+أكيد دول الأنواع التلاتة في بينهم شبه وفي بينهم 
+
+6
+00:00:45,220 --> 00:00:52,240
+قواسم مشتركة ولذلك يعني بيوضعوا مع بعض ربما عدد
+
+7
+00:00:52,240 --> 00:00:55,840
+كبير منكم خليني أقول عارفين الـ alcohol المركبات
+
+8
+00:00:55,840 --> 00:01:00,280
+اللي فيها اللي هم اللي بنقول عنهم R-OH بالظبط
+
+9
+00:01:00,280 --> 00:01:06,080
+المركبات اللي فيهم OH الآن الـ phenols برضه فيهم OH
+
+10
+00:01:06,080 --> 00:01:10,840
+لكن محمول على حلقة أروماتية زي البنزين يعني بدل ما
+
+11
+00:01:10,840 --> 00:01:17,550
+نقول R إيش بنقول؟ Ar-OH AromaticOH هذه عائلة
+
+12
+00:01:17,550 --> 00:01:23,330
+الـ phenols الـ thiols زي الـ alcohols بالظبط بس بدل ما
+
+13
+00:01:23,330 --> 00:01:28,310
+يكون عندي OH بيصير عندي SH يعني الـ thiols إيش بتكون
+
+14
+00:01:28,310 --> 00:01:36,710
+بيصير عندي ه؟ SH واضح؟ وأكيد أنه قادرين تلاحظوا
+
+15
+00:01:36,710 --> 00:01:41,950
+العلاقة بين هدول الأنواع التلاتة من المركبات هنبدأ 
+
+16
+00:01:41,950 --> 00:01:47,500
+طبعًا بالـ Alcohols بشكل قليل بالـ Phenols وبعدين 
+
+17
+00:01:47,500 --> 00:01:52,460
+بنمر على الـ RSH لكن أكيد الموضوع الأساس عندنا
+
+18
+00:01:52,460 --> 00:01:58,320
+أكتر شيء عليه تركيز اللي هو الـ Alcohols إيش بتعني
+
+19
+00:01:58,320 --> 00:02:01,600
+الـ Alcohols في الكيميا العضوية؟ طبعاً في منهجية
+
+20
+00:02:01,600 --> 00:02:05,780
+دائما للدراسة في الكيميا العضوية لما بناخد الـ
+
+21
+00:02:05,780 --> 00:02:09,020
+functional groups و العائلات لإن أحنا في الأول
+
+22
+00:02:09,020 --> 00:02:14,020
+بدنا نتعلم نسمي المركبات بعد هيك بدنا نتعلم نحضرها
+
+23
+00:02:14,020 --> 00:02:19,360
+و بعدين ندرس تفاعلاتها يعني دائما اللي بده ياخد 
+
+24
+00:02:19,360 --> 00:02:24,720
+مجموعة وظيفية معينة بده يعرف تلت شغلات تسمية،
+
+25
+00:02:24,720 --> 00:02:31,350
+تحضير، تفاعلات واضح تسمية و تحضير و تفاعلات الآن لو
+
+26
+00:02:31,350 --> 00:02:37,170
+اجينا لموضوع التسمية الـ alcohols تسمى مثل الـ
+
+27
+00:02:37,170 --> 00:02:42,190
+alkanes المناظرة بس بزيادة النهاية -ol
+
+28
+00:02:47,130 --> 00:02:53,810
+-e في الآخر يعني بس -ol ما بنقولش -ole هذا الكلام
+
+29
+00:02:53,810 --> 00:02:57,230
+يمكن يكون منه فائدة لأنه لما بتقرأ أحيانا أسماء
+
+30
+00:02:57,230 --> 00:03:03,070
+مركبات و نهايتها -ole معناه ذلك مش alcohols هذه 
+
+31
+00:03:03,070 --> 00:03:07,050
+يعني لو أنا مثلاً بدي أقول cholesterol هي نهايته 
+
+32
+00:03:07,050 --> 00:03:14,800
+-ol هذا -ol هذا -ol بصنفه alcohol finally لكن لو بدأ
+
+33
+00:03:14,800 --> 00:03:19,520
+أقول مثلاً نترايزول تترازول أكزازول بيرازول هذه
+
+34
+00:03:19,520 --> 00:03:25,160
+منطقة تانية حلقات غير متجانس نهايتها -ole وإيها معنى
+
+35
+00:03:25,160 --> 00:03:31,500
+بعيد تماماً عن المعنى تبعه يعني في الكيميا الحلقية
+
+36
+00:03:31,500 --> 00:03:39,200
+هذه الـ -ole اللي هي بتعطي نهاية -ol برضه معناها أنه
+
+37
+00:03:39,200 --> 00:03:44,500
+مركب في حلقة خماسية يعني الـ -ole في الكيميا
+
+38
+00:03:44,500 --> 00:03:49,620
+الحلقية بتتعني لإيش؟ حلقة خماسية و هدول مركبات
+
+39
+00:03:49,620 --> 00:03:54,820
+اللي هم تطبيقات كتيرة كمضادات للفطريات معظم الناس 
+
+40
+00:03:54,820 --> 00:03:57,760
+اللي عندهم فطريات بين أصابعهم أو ش زيك بتلاقيهم
+
+41
+00:03:57,760 --> 00:04:00,480
+بيستعملوا Dactazol و Fluconazol
+
+42
+00:04:02,730 --> 00:04:06,990
+انيزول لأ .. انيزول is a phenol .. انيزول ..
+
+43
+00:04:06,990 --> 00:04:10,370
+انيزول is a phenol .. خلينا نمر الآن بالتدريج و
+
+44
+00:04:10,370 --> 00:04:17,170
+نشوف الموقع الانيزول مش فينول حتى O-methyl ether
+
+45
+00:04:17,170 --> 00:04:25,690
+نمشي فيهم بهدوء أبسط الكان كان الميثين لما بدي أعمل 
+
+46
+00:04:25,690 --> 00:04:30,210
+منه أنا alcohol بدي يصير بالـ IUPAC Nomenclature
+
+47
+00:04:30,210 --> 00:04:33,410
+Methanol
+
+48
+00:04:33,410 --> 00:04:38,990
+واضح؟ إذا هذه التسمية اللي محطوطة فوق هي أي تسمية؟
+
+49
+00:04:38,990 --> 00:04:45,810
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+50
+00:04:45,810 --> 00:04:50,210
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+51
+00:04:50,210 --> 00:04:50,910
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+52
+00:04:50,910 --> 00:04:50,930
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+53
+00:04:50,930 --> 00:04:53,650
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC I
+
+54
+00:04:54,100 --> 00:04:59,380
+ميثانول إذا عندي إيثين إيثانول إذا عندي بروبين
+
+55
+00:04:59,380 --> 00:05:04,300
+بروبانول لكن أنا متوقع تيجي على موقعين بس عندي one
+
+56
+00:05:04,300 --> 00:05:09,200
+بروبانول و two بروبانول يعني لازم أحدد وين جاية
+
+57
+00:05:09,200 --> 00:05:17,440
+مجموعة الـ OH الآن لو هذه المركبات بدي أسميها بالـ
+
+58
+00:05:17,440 --> 00:05:21,300
+common nomenclature بدي أجيب اسم المجموعة يعني في 
+
+59
+00:05:21,300 --> 00:05:25,280
+كل مرة بدي أشوف إيش المجموعة اللي عندي أذكر اسمها
+
+60
+00:05:25,280 --> 00:05:32,280
+و أتبعها بالكحول يعني هنا هذه المجموعة CH3 هنا هذه
+
+61
+00:05:32,280 --> 00:05:34,780
+واضح؟
+
+62
+00:05:35,880 --> 00:05:40,780
+فبأدخل على اسم المجموعة و بيجي بعدها alcohol فهذه
+
+63
+00:05:40,780 --> 00:05:44,700
+المجموعة مثل بيصير المركب بالـ common nomenclature
+
+64
+00:05:44,700 --> 00:05:51,800
+مثل methyl alcohol إيثل .. إيثيل كحول إبروبل كحول هذه
+
+65
+00:05:51,800 --> 00:05:56,700
+المجموعة الـ CH اللي طالع منها تنتهي CH3-isopropyl
+
+66
+00:05:56,700 --> 00:06:02,740
+واضح؟ يعني حتى الـ common nomenclature هنا بتلاحظوا 
+
+67
+00:06:02,740 --> 00:06:07,370
+كأنها تصير برضه على إيش؟ على قاعدة وعلى نمط محدد
+
+68
+00:06:07,370 --> 00:06:12,790
+أنكم تذكرون الـ Alkyl group و بعدها تضعون alcohol
+
+69
+00:06:12,790 --> 00:06:17,710
+و في كل هذه المركبات لو كان عندي مثلاً halogen ليس
+
+70
+00:06:17,710 --> 00:06:20,310
+alcohol يعني لو افترضت في يوم كله مبدأ للـ OH عند 
+
+71
+00:06:20,310 --> 00:06:24,330
+الـ bromide كان يقول نعم مثل methyl bromide إيثيل بروميد بروميد
+
+72
+00:06:24,330 --> 00:06:28,990
+isopropyl bromide isobutyl bromide و هكذا و كل 
+
+73
+00:06:28,990 --> 00:06:33,070
+هذه الأسماء اللي بتبدأ بالـ alkyl group كمجموعة هي
+
+74
+00:06:33,070 --> 00:06:40,680
+عبارة عن common names الآن هذا المركز اللي بدي أطلع
+
+75
+00:06:40,680 --> 00:06:45,440
+عليه هذه المجموعة برضه مرت علينا إذا كنا بدنا ..
+
+76
+00:06:45,440 --> 00:06:48,040
+أن نكون متابعين شوية في الـ common nomenclatures
+
+77
+00:06:48,040 --> 00:06:52,720
+هذه اللي هي مجموعة الـ isobutyl لأن واحد اتنين
+
+78
+00:06:52,720 --> 00:06:59,240
+تلاتة أربعة فـ isobutyl isobutyl بصير isobutyl
+
+79
+00:06:59,240 --> 00:07:05,860
+alcohol اللي بعدها هذه المجموعة الكربون اللي حاملة 
+
+80
+00:07:05,860 --> 00:07:12,460
+تلاتة CH3 tert-butyl alcohol واضح؟ و المجموعة
+
+81
+00:07:12,460 --> 00:07:16,620
+اللي هنا لما
+
+82
+00:07:16,620 --> 00:07:20,720
+أخدنا الالكينز أخدنا مجموعتين اللي لهم أسماء 
+
+83
+00:07:20,720 --> 00:07:26,500
+الـ vinyl و الـ allyl هذا عبارة عن مجموعة الـ allyl إذا هذا 
+
+84
+00:07:26,500 --> 00:07:32,540
+عبارة عن allyl alcohol إذا هذا عبارة عن allyl alcohol
+
+85
+00:07:32,540 --> 00:07:37,700
+الآن لو بدأ أرجع للتلاتة اللي تحت نتأكد من تسميتهم
+
+86
+00:07:37,700 --> 00:07:41,960
+في الـ common في عفواً في الـ IUPAC nomenclature في
+
+87
+00:07:41,960 --> 00:07:46,260
+الـ IUPAC nomenclature بدنا نشوف أطول سلسلة و نبدأ 
+
+88
+00:07:46,260 --> 00:07:53,640
+من عند الـ OH واحد اتنين تلاتة إذا هذا 1-propanol
+
+89
+00:07:53,640 --> 00:07:58,160
+هذا الـ 1-propanol إيش حامل على موقع اتنين مثل 
+
+90
+00:07:58,160 --> 00:08:05,210
+إذا هذا 2-methyl-1-propanol 1 2 3 1-propanol 2-methyl
+
+91
+00:08:05,210 --> 00:08:09,730
+1-propanol الآن لو بدي أجعل هذا المركب على فرض
+
+92
+00:08:09,730 --> 00:08:12,450
+أن هو يعدي 1 2 3 هذا إيش بدي يصير
+
+93
+00:08:12,450 --> 00:08:16,210
+المركب 2-propanol أكيد نفس الشي 1 2 
+
+94
+00:08:16,210 --> 00:08:20,190
+3 1 2 3 خلينا نمشي زي كذا مثلاً 1
+
+95
+00:08:20,190 --> 00:08:24,030
+2 3 2-propanol إيش حامل الـ 2-
+
+96
+00:08:24,030 --> 00:08:31,620
+propanol 2-methyl إذا هذا 2-methyl-2-propanol
+
+97
+00:08:31,620 --> 00:08:37,360
+-2-propanol okay؟ الآن المركب الثالث
+
+98
+00:08:37,360 --> 00:08:44,040
+المركب الثالث بيلتقي فيه أكثر من مجموعة وظيفية في
+
+99
+00:08:44,040 --> 00:08:48,060
+الـ double bond كمجموعة وظيفية اللي هي بتاخد 
+
+100
+00:08:48,060 --> 00:08:53,760
+النهاية -ene و الـ alcohol كمجموعة وظيفية بتاخد النهاية 
+
+101
+00:08:53,760 --> 00:08:59,540
+-ol إذا بيلتقوا مجمعتين وظيفيتين بيصير التفكير يا
+
+102
+00:08:59,540 --> 00:09:07,400
+بتسمي -ene-ol يا -ol-ene واضح؟ و بتهيألي سابقًا إحنا
+
+103
+00:09:07,400 --> 00:09:13,420
+عملنا أولوية أنه بيكون أعلى في الأولويات قلنا أقل
+
+104
+00:09:13,420 --> 00:09:19,370
+أولويات الـ Alkanes بعدها الـ Alkenes بعدها الـ
+
+105
+00:09:19,370 --> 00:09:23,730
+alcohols بعدها الـ ketones الـ aldehydes الـ acids
+
+106
+00:09:23,730 --> 00:09:28,970
+الـ esters فمين أولويته أعلى أنه ينسب له الجزء الـ
+
+107
+00:09:28,970 --> 00:09:33,390
+-OH أعلى من الـ double bond و أعلى من الـ triple bond
+
+108
+00:09:33,390 --> 00:09:39,500
+عشان هيك لازم يكون المركب نهايته -ol بترجع له في 
+
+109
+00:09:39,500 --> 00:09:43,820
+تسمية الـ aromatic compounds أخدنا سلسلة إيش
+
+110
+00:09:43,820 --> 00:09:49,000
+الأولويات؟ فهذا المركب عبارة عن -ol و الترقيم بيبدأ 
+
+111
+00:09:49,000 --> 00:09:56,080
+من وين؟ من الـ alcohol بزام طالما أنه صرت أنا ناسبه
+
+112
+00:09:56,080 --> 00:09:59,980
+للـ -ol إذا كل الاحترام و الثقة و التخدير لمين؟ للـ
+
+113
+00:09:59,980 --> 00:10:03,820
+-ol هو بيكون اسم العائلة للمركب و من عنده يبدأ 
+
+114
+00:10:03,820 --> 00:10:09,950
+الترقيم فعيكون عندي 1 2 3 خلاص مركب -ol الـ
+
+115
+00:10:09,950 --> 00:10:14,450
+double bond بتيجي تحصيل حاصل واضح؟ ولذلك هذا لما
+
+116
+00:10:14,450 --> 00:10:20,230
+بدنا نيجي نسميه في -ene-ol فبنقول 2-propene إيش
+
+117
+00:10:20,230 --> 00:10:25,670
+معناه 2-propene؟ إنه مجموعة الـ -ene فهذه الـ 2
+
+118
+00:10:25,670 --> 00:10:30,590
+بتحدد موقع الـ double bond وين بدايتها؟ طب 1-ol
+
+119
+00:10:33,080 --> 00:10:38,620
+جاى على موقع واحد ف أنا لما بكتبه بهذا الاسم 2
+
+120
+00:10:38,620 --> 00:10:46,120
+propene-1-ol اللي بحكي بالظبط إن الـ alcohol على 
+
+121
+00:10:46,120 --> 00:10:52,880
+موقع واحد و الـ double bond بدايتها على موقع اتنين 
+
+122
+00:10:52,880 --> 00:11:01,240
+واضح؟ 2-propene-1-ol الآن ممكن على السريع نأكد
+
+123
+00:11:01,240 --> 00:11:08,880
+هذا الكلام بمثال شبيه و طالب منكم تعطينا الجواب 
+
+124
+00:11:08,880 --> 00:11:18,140
+نكتبه هنا لو كتبنا مثلاً CH3CCH2OH
+
+125
+00:11:18,140 --> 00:11:25,980
+و قلنا بتناقش إيش المجموعات الموجودة
+
+126
+00:11:27,010 --> 00:11:34,090
+الـ -ene, الـ -yne و الـ -ol لمن الأولوية؟ للـ -ol إذا أنا
+
+127
+00:11:34,090 --> 00:11:40,930
+لازم أبدأ أرقم 1،
+
+128
+00:11:40,930 --> 00:11:48,930
+2، 3، 4، واضح؟ إذا هذا هيكون butene
+
+129
+00:11:48,930 --> 00:11:52,730
+-ol butene-ol
+
+130
+00:12:02,230 --> 00:12:09,350
+but-3-ene-1-ol واضح؟ لأن الـ alcohol له أولوية على 
+
+131
+00:12:09,350 --> 00:12:14,930
+الـ double و الـ triple bonds الـ alcohol له أولوية 
+
+132
+00:12:14,930 --> 00:12:18,330
+على الـ double و الـ triple bonds فبيصير هو يمثل قيم
+
+133
+00:12:18,330 --> 00:12:24,970
+شغلتين هذه الأولوية بتعني إيش؟ شغلتين أنه يمثل اسم 
+
+134
+00:12:24,970 --> 00:12:28,170
+العائلة في النهاية دائمًا اسم العيلة في الأول ولا 
+
+135
+00:12:28,170 --> 00:12:33,130
+في الآخر؟ مظبوط ولا لا؟ آه اسم العيلة دائمًا في الـ
+
+136
+00:12:33,130 --> 00:12:38,630
+... آخر و من عنده يبدأ بالترقيم
+
+137
+00:12:51,960 --> 00:12:58,300
+هذه أمثلة إضافية .. هذه أمثلة إضافية .. الآن لو
+
+138
+00:12:58,300 --> 00:13:05,600
+كان عندي Alcohol على Cycloalkane هذا Cyclopentane
+
+139
+00:13:05,600 --> 00:13:10,520
+إيه جعله Alcohol؟ إيش بيصير؟ Cyclopentanol اسم 
+
+140
+00:13:10,520 --> 00:13:17,360
+منطقي ولا لأ؟ شيلنا الـ .. الـ .. الـ Alcohol الـ -OH
+
+141
+00:13:17,360 --> 00:13:25,290
+-O لو كانت اتنين diol لو صاروا تلاتة triol أربعة
+
+142
+00:13:25,290 --> 00:13:32,490
+tetraol الجزء اللي عندنا هنا كام -ol فيه اتنين
+
+143
+00:13:32,490 --> 00:13:39,290
+إذا هذا diol cyclopentane diol لكن لما بيكونوا 
+
+144
+00:13:39,290 --> 00:13:45,250
+اتنين لازم أحدد مواقعهم في الأول بالنسبة لبعض 
+
+145
+00:13:45,250 --> 00:13:49,390
+ممكن يكونوا جايين ورا بعض واحد و اتنين و ممكن واحد
+
+146
+00:13:49,390 --> 00:13:53,610
+و تلاتة، مظبوط ولا لا؟ إذا كأنه أنا عندي 1, 2,
+
+147
+00:13:54,010 --> 00:14:00,750
+3, 4, 5 فهذا لازم أحط عنه 1, 2,
+
+148
+00:14:01,250 --> 00:14:05,870
+cyclopentane-1,2-diol لأن لو الـ -OH إجت هنا، إيش بدي
+
+149
+00:14:05,870 --> 00:14:11,930
+يصير؟ 1, 3-cyclopentane-1,3-diol لو إجت هنا الـ
+
+150
+00:14:11,930 --> 00:14:17,470
+1 و 3 من الجهات التانية دائمًا بتكون تسعة
+
+151
+00:14:17,470 --> 00:14:22,850
+و را اقل ترقيم آه الآن في كمان شغلة إن إحنا قلنا 
+
+152
+00:14:22,850 --> 00:14:28,170
+الـ double points الـ double bonds و الحلقات هذه
+
+153
+00:14:28,170 --> 00:14:32,190
+double bonds شايفينها؟ فيهم ظاهرة إيش؟ الـ cis و 
+
+154
+00:14:32,190 --> 00:14:37,770
+الـ trans إنه المجموعات مع بعض ولا عكس بعض، في هذه
+
+155
+00:14:37,770 --> 00:14:41,830
+الحالة هم مرسومين الـ wedges مع بعض ولا لأ؟ جايين
+
+156
+00:14:41,830 --> 00:14:46,010
+هيك للأمام باتجاهنا، إذا هذا cis-1,2-
+
+157
+00:14:46,010 --> 00:14:50,920
+cyclopentane-1,2-diol إذاً هذا الـ cis compound لو كنت
+
+158
+00:14:50,920 --> 00:14:55,360
+بدي الـ trans compound بدو ييجي السهم أو الـ .. الـ 
+
+159
+00:14:55,360 --> 00:15:00,140
+أسفين هذا dashed إيش معناه dashed؟ إنه بديل على
+
+160
+00:15:00,140 --> 00:15:07,340
+إنه رايح للخلف okay الآن لو إجينا للمركب اللي بعده 
+
+161
+00:15:07,340 --> 00:15:12,100
+المركب اللي بعده بتلاحظه فيه حلقة بنزين لكن لو أنا 
+
+162
+00:15:12,100 --> 00:15:16,600
+بدي أنسبه للبنزين هذه المجموعة كلها مالهاش اسم
+
+163
+00:15:16,600 --> 00:15:22,340
+مشهور في مثل هذه الحالة ممكن نرجع إحنا للالكين، 
+
+164
+00:15:22,340 --> 00:15:26,620
+نقول الالكين اللي موجود عندي، كم كربونة عليه؟
+
+165
+00:15:26,620 --> 00:15:32,880
+اتنين، هاي كربونة اتنين، كأنه هذا هو الأساس اللي
+
+166
+00:15:32,880 --> 00:15:36,740
+موجود عندي، هاي 1, 2، الآن إيش بيحمل هذا 
+
+167
+00:15:36,740 --> 00:15:43,180
+الالكين؟ مجموعتين البنزين و الـ -OH طبعًا الأولوية في
+
+168
+00:15:43,180 --> 00:15:46,540
+هذه الحالة للـ -OH البنزين تصبح كأنها مجموعة 
+
+169
+00:15:46,540 --> 00:15:51,960
+و البنزين لما تكون مجموعة إيش اسمها؟ phenyl phenyl ما
+
+170
+00:15:51,960 --> 00:15:59,720
+تقولوش phenol phenol لأن الـ phenol double bond إذا هذا صار
+
+171
+00:15:59,720 --> 00:16:08,860
+كأنه اللي موجود عندي ethanol CH2OH CH2phenyl إذا هذا 
+
+172
+00:16:08,860 --> 00:16:
+
+201
+00:19:18,780 --> 00:19:28,300
+أسداللي بيقول له اسمه common salicylic acid وهذا ال
+
+202
+00:19:28,300 --> 00:19:36,380
+salicylic acid كثير كثير مهم في حد بيعرفه ليش مهم؟
+
+203
+00:19:36,380 --> 00:19:44,960
+أه لأن هو اللي منه بتحضر ال aspirin من شجر الصفصاف
+
+204
+00:19:46,380 --> 00:19:50,340
+من شجر الصفصاف يعني هذا ال salicylic acid بس
+
+205
+00:19:50,340 --> 00:19:55,660
+بيعملوا فيه تغيير بسيط بيصير aspirin ال analgesic
+
+206
+00:19:55,660 --> 00:19:59,800
+اللي هو الدواء بتاع الصداع بس أنا بحطه صيدلية من ال
+
+207
+00:19:59,800 --> 00:20:06,560
+bond O CH3 بدل هذه ال H بيصير aspirin واضح؟ ولذلك
+
+208
+00:20:06,560 --> 00:20:09,240
+هذا ال salicylic acid مهم وواجهته ب salicylic
+
+209
+00:20:09,240 --> 00:20:15,280
+acid ال aspirin واضح؟ هنا إيش المجموعتين اللي
+
+210
+00:20:15,280 --> 00:20:21,820
+التقوا بهذا الجزء الديهايد ال CHO معناها C double
+
+211
+00:20:21,820 --> 00:20:27,320
+bond O و H الجهة الثانية الديهايد مين له أولوية
+
+212
+00:20:27,320 --> 00:20:33,500
+في التسمية الديهايد إذا هذا بنزالديهايد هذا
+
+213
+00:20:33,500 --> 00:20:37,580
+المركب بنزالديهايد يعني واحد اثنين ثلاثة أربعة 
+
+214
+00:20:37,580 --> 00:20:38,060
+خمسة
+
+215
+00:20:41,550 --> 00:20:46,150
+الـ 3-hydroxybenzaldehyde أو الـ
+
+216
+00:20:46,150 --> 00:20:49,470
+metahydroxybenzaldehyde
+
+217
+00:21:07,580 --> 00:21:12,060
+هكذا تقريباً بيكون أخذنا فكرة معقولة خلّينا نقول عن
+
+218
+00:21:12,060 --> 00:21:18,240
+تسمية ال alcohols بندرج لبعض الخواص اللي متعلقة
+
+219
+00:21:18,240 --> 00:21:24,220
+فيهم وبعد هيك بندخل أكثر على تحضيرهم إن شاء الله من
+
+220
+00:21:24,220 --> 00:21:27,840
+أكثر الأشياء اللي بتميز ال alcohol ال hydrogen
+
+221
+00:21:27,840 --> 00:21:34,240
+bonding واضح؟ وبالمناسبة هتلاحظوا أن ال alcohol ال
+
+222
+00:21:34,240 --> 00:21:42,320
+alcohol ربما أكثر شيء بيشبه إيش؟ المية ال Alcohol
+
+223
+00:21:42,320 --> 00:21:47,780
+أكثر شيء بيشبه المية طبعاً بيشبهها من ناحية كيميا
+
+224
+00:21:47,780 --> 00:21:53,280
+بيشبهها من ناحية كيميا بس من ناحية دين وشريعة لأ
+
+225
+00:21:53,280 --> 00:21:59,040
+بالمرة يعني المية ربنا قال وجعلنا من الماء كل
+
+226
+00:21:59,040 --> 00:22:03,990
+شيء حي لكن ال alcohol لو أخذنا الإيثانول منهيا أيها
+
+227
+00:22:03,990 --> 00:22:07,110
+الذين آمنوا إنما الخمر والميسر والأنصاب و
+
+228
+00:22:07,110 --> 00:22:11,590
+الأصنام رخصها من عمل الشيطان فاجتنبوه الآن لاحظوا
+
+229
+00:22:11,590 --> 00:22:17,150
+ليش إحنا بنقول أنه المية يعني فلسفياً ممكن تمثل
+
+230
+00:22:17,150 --> 00:22:21,750
+أبسط كحول ممكن تمثل أبسط كحول لو أنا أخذت
+
+231
+00:22:21,750 --> 00:22:26,630
+عائلة.. أنا عندي هاي OH متصلة  أبقى أشد هي كان
+
+232
+00:22:26,630 --> 00:22:29,430
+بيصير عندي OH متصلة
+
+233
+00:22:34,020 --> 00:22:40,100
+مثال وهذا مثال
+
+234
+00:22:40,100 --> 00:22:46,060
+هذا مثال هذا مثال هذا مثال
+
+235
+00:22:50,390 --> 00:22:57,570
+متصلة بـ ethyl مثل الـ OH ولذلك بتلاحظوا أن محور
+
+236
+00:22:57,570 --> 00:23:02,130
+الشبه بين المية.. محور الشبه بين المية والـ..
+
+237
+00:23:02,130 --> 00:23:08,730
+وال alcohol هو وجود مجموعة الـ OH واضح؟ محور
+
+238
+00:23:08,730 --> 00:23:12,870
+الشبه بين المية و ال alcohol هو وجود مجموعة الـ
+
+239
+00:23:12,870 --> 00:23:16,830
+OH هذا الكلام اللي بي.. اللي بيخلي صفة مشتركة
+
+240
+00:23:16,830 --> 00:23:22,210
+بينهم اللي هي الـ polarity إن المية قطبية
+
+241
+00:23:22,210 --> 00:23:28,930
+والكحولات برضه عبارة عن قطبية الـ OH
+
+242
+00:23:28,930 --> 00:23:36,320
+بتعمل هيدروجين بوندنج بتخلي نقطة الغليان عالية
+
+243
+00:23:36,320 --> 00:23:40,800
+نسبياً واضح؟ مثل هدول مثلاً المركبات المية
+
+244
+00:23:40,800 --> 00:23:44,600
+بالوضع الطبيعي بتغلي عندها كم؟ عند مية الميثانول
+
+245
+00:23:44,600 --> 00:23:48,860
+عند حوالي ستين أو واحد وستين الإيثانول عند حوالي
+
+246
+00:23:48,860 --> 00:23:55,660
+ثمانين أو ثمانية وسبعين ملاحظين؟ طبعاً المية أعلى
+
+247
+00:23:55,660 --> 0:24:02,400
+منهم لأنه بتعمل اثنين hydrogen bonding ومر علينا
+
+248
+00:24:02,400 --> 00:24:08,120
+كيف المية بتعمل hydrogen bonding واضح؟ فالشبه بينهم
+
+249
+00:24:08,120 --> 00:24:14,240
+في ال boiling point المرتفعة هو وجود ال OH
+
+250
+00:24:14,240 --> 00:24:21,420
+القطبية جروب اللي بتعمل hydrogen bonding واضح هاي
+
+251
+00:24:21,420 --> 00:24:25,380
+يمكن ال boiling point الدقيقة هنا 65 إذا بدكم
+
+252
+00:24:25,380 --> 00:24:36,840
+الميثانول 65 المية الإيثانول 78.5% البروبانول 97%
+
+253
+00:24:36,840 --> 00:24:42,260
+البيوتانول 117% زي ما بتلاحظوا هنا زي ما بتلاحظوا
+
+254
+00:24:42,260 --> 00:24:48,260
+هنا أنه بشكل عام وجود ال OH وجود ال OH بيخلي ال
+
+255
+00:24:48,260 --> 00:24:52,950
+boiling point مرتفعة، لكن بنفس الوقت إحنا عندنا
+
+256
+00:24:52,950 --> 00:24:58,110
+قاعدة عامة كل ما الجزء كبر الـ R group كبرت برضه
+
+257
+00:24:58,110 --> 00:25:03,310
+نقاط الغليان إيش بصير لها؟ بتعلى، يعني إذا بتذكروا
+
+258
+00:25:03,310 --> 00:25:09,890
+مثلاً في ال الألكانات الميثان كان تقريباً ناقص 160 وكان
+
+259
+00:25:09,890 --> 00:25:16,860
+غاز، والإيثان غاز البروبان غاز بس بيصير ال boiling
+
+260
+00:25:16,860 --> 00:25:22,800
+point أعلى البيوتان غاز البنتان بيبدأ يصير سائل
+
+261
+00:25:22,800 --> 00:25:29,160
+boiling point حوالي 36 الهكسان سائل أكيد بعدين
+
+262
+00:25:29,160 --> 00:25:32,480
+بيصير سوائل ال boiling point أعلى فإحنا كل ما
+
+263
+00:25:32,480 --> 00:25:37,060
+بتزيد العدد الكربونات أو ال R groups كل ما بترتفع
+
+264
+00:25:37,750 --> 00:25:42,070
+نقطة الغليان فهنا واضح تماماً في السلسلة إن عندك
+
+265
+00:25:42,070 --> 00:25:45,750
+كربونة تلتين ثلاث أربع خمس ست ونقاط الغليان
+
+266
+00:25:45,750 --> 00:25:49,210
+عاملة بترجع لكن بشكل عام إحنا بنقول كل هذه النقاط
+
+267
+00:25:49,210 --> 00:25:56,470
+نسبياً مرتفعة جداً كل هذه النقاط مرتفعة جداً والسبب
+
+268
+00:25:56,470 --> 00:26:03,790
+هو وجود الـ OH طبعاً مرتفعة جداً الأمر نسبة يعني
+
+269
+00:26:03,790 --> 00:26:09,850
+قارنوها لما بنقول مرتفعة جداً بالالكان يعني مثلاً هذا
+
+270
+00:26:09,850 --> 00:26:14,770
+الميثانول قارنوه بال إيثين مثلاً أو الميثان بتلاقي
+
+271
+00:26:14,770 --> 00:26:19,210
+نقطة الغليان حوالي ناقص 160 ناقص 140 الآن أنا لما
+
+272
+00:26:19,210 --> 00:26:25,590
+أصير أحكي عن 65 يعني أنا مرتفع كم درجة مئوية يعني
+
+273
+00:26:25,590 --> 00:26:30,550
+لو بدأنا أخذ مركب نفس ال molecular weight ثلاث خمس
+
+274
+00:26:30,550 --> 00:26:36,570
+عشر وست عشر و H اثنين وثلاثين اثنين وثلاثين
+
+275
+00:26:36,570 --> 00:26:42,670
+لو أتيت مثلاً أخذت ال C2 خمس عشر وخمس عشر ثلاثين
+
+276
+00:26:42,670 --> 00:26:47,810
+تقريباً متساويات في ال molecular weight لكن ال C2
+
+277
+00:26:47,810 --> 00:26:53,160
+لم تدرس ال boiling point تبعها ناقص مائة وأربعين
+
+278
+00:26:53,160 --> 00:26:58,200
+يمكن هنا المثال
+
+279
+00:26:58,200 --> 00:27:01,920
+هو الخمسة والستين لو بدأنا أقول مائة وأربعين لخمسة و
+
+280
+00:27:01,920 --> 00:27:05,940
+ستين مائة وأربعين ناقص لخمسة وستين كده الفرق؟
+
+281
+00:27:05,940 --> 00:27:14,740
+مئتين درجة مئوية من ناقص مائة وأربعين إلى خمسة و
+
+282
+00:27:14,740 --> 00:27:18,320
+ستين من ناقص مائة وأربعين إلى خمسة وستين كده
+
+283
+00:27:18,320 --> 00:27:24,230
+الفرق تقريباً حوالي 200 درجة أعلى، من أين أتت هذه
+
+284
+00:27:24,230 --> 00:27:30,450
+الـ 200 درجة؟ من الـ hydrogen bonding، واضح؟ هذه
+
+285
+00:27:30,450 --> 00:27:33,350
+الـ 200 درجة أتت من الـ hydrogen bonding اللي
+
+286
+00:27:33,350 --> 00:27:37,310
+موجود في الكحول وليست موجودة في مركب له نفس الوزن
+
+287
+00:27:37,310 --> 00:27:38,430
+زي الـ إيثان
+
+288
+00:27:41,220 --> 00:27:47,240
+غير قصة اللي هي ال boiling point ذائبية ال alcohol
+
+289
+00:27:47,240 --> 00:27:54,660
+في المية ذائبية ال alcohol في المية الآن هنا بدكم
+
+290
+00:27:54,660 --> 00:27:59,000
+تنتبهوا ال boiling point لما بتعمل ال alcohol
+
+291
+00:27:59,000 --> 00:28:03,600
+هيدروجين بوندنج مع
+
+292
+00:28:03,600 --> 00:28:13,020
+إيش؟ مع نفسها مع نفسها يعني أنا لما أقول methanol و
+
+293
+00:28:13,020 --> 00:28:20,140
+عامل hydrogen bonding كأن هنا بقول بالضبط CH3OH و
+
+294
+00:28:20,140 --> 00:28:26,360
+من هنا عامل hydrogen bonding مع واحد ثاني هاي
+
+295
+00:28:26,360 --> 00:28:35,030
+hydrogen bonding هيك مقطعة H OCH3 فهي عندي جزء وجزء
+
+296
+00:28:35,030 --> 00:28:39,890
+هذا الـ hydrogen bonding ما بين جزيئات نفس المادة
+
+297
+00:28:39,890 --> 00:28:46,250
+بيعمل الارتفاع في نقطة الغليان الآن بيجيني
+
+298
+00:28:46,250 --> 00:28:51,190
+الذائبية الذائبية ال alcohol في المية الذائبية ال
+
+299
+00:28:51,190 --> 00:28:55,830
+alcohol في المية الذائبية برضه عبارة عن hydrogen
+
+300
+00:28:55,830 --> 00:28:59,450
+bonding بس المرة هذه ال hydrogen bonding بتكون
+
+301
+00:28:59,450 --> 00:29:04,300
+مع المية مع المية بمعنى خلّيني أتخيل أنه عندي نفس الجزء
+
+302
+00:29:04,300 --> 00:29:09,840
+الكحول هذا CH3OH وهي أزواج إلكترونات عليه وبعدين
+
+303
+00:29:09,840 --> 00:29:15,800
+بده يجي يعمل hydrogen bonding مع المية
+
+304
+00:29:15,800 --> 00:29:17,900
+واضح؟
+
+305
+00:29:19,840 --> 00:29:25,120
+هنا بتلاحظوا إن الكحول مع الكحول عملوا hydrogen
+
+306
+00:29:25,120 --> 00:29:27,980
+bonding هذه ال hydrogen bonding اللي ما بين
+
+307
+00:29:27,980 --> 00:29:33,620
+الكحول مع نفسه بين أثرها وين؟ في ال boiling point
+
+308
+00:29:33,620 --> 00:29:38,920
+المرتفعة إن الجزيئات مرتبطة عشان أفصلها عن بعض
+
+309
+00:29:38,920 --> 00:29:44,380
+الغليان عبارة عن عملية فصل كامل إن أنا بدي
+
+310
+00:29:44,380 --> 00:29:48,680
+الجزء أفصله وبطير من المحلول وبطلع برا وعشان هيك
+
+311
+00:29:48,680 --> 00:29:56,320
+بده طاقة كبيرة وعضلة فال boiling point هي إنها
+
+312
+00:29:56,320 --> 00:30:01,660
+تكسير hydrogen bonding ما بين جزيئات alcohol مع
+
+313
+00:30:01,660 --> 00:30:07,440
+بعض الآن ال solubility إنهم يخلطوا مع بعض هي عبارة
+
+314
+00:30:07,440 --> 00:30:10,420
+عن hydrogen bonding ما بين alcohol
+
+315
+00:30:14,190 --> 00:30:17,270
+الهيدروجين بوندنج بين الكحول والمية هي اللي
+
+316
+00:30:17,270 --> 00:30:24,890
+بتتحكم في ال solubility إذا بتتطلعوا أنتو
+
+317
+00:30:24,890 --> 00:30:27,850
+هتلاحظوا ملاحظة
+
+318
+00:30:30,060 --> 00:30:34,100
+الجزيئات الأولى في ال alcohols اللي هم أبسط
+
+319
+00:30:34,100 --> 00:30:40,140
+alcohols هدول عادة بيسموهم ال lower alcohols يعني
+
+320
+00:30:40,140 --> 00:30:44,900
+ال alcohols الصغيرة اللي هم الميثانول والإيثانول
+
+321
+00:30:44,900 --> 00:30:52,360
+والبروبانول إيش بيسموهم هدول؟ lower alcohols
+
+322
+00:30:53,510 --> 00:30:57,190
+اللي هم أول الكحولات اللي were alcohol هدول
+
+323
+00:30:57,190 --> 00:31:03,130
+بتلاقوهم بيدوبوا في المية 100% completely miscible
+
+324
+00:31:03,130 --> 00:31:07,410
+إيش معنى كلمة miscible؟ بيخلط مع المية تماماً يعني
+
+325
+00:31:07,410 --> 00:31:11,750
+لما حطيت methanol فوق المية وبأي نسبة ما بيصيرش
+
+326
+00:31:11,750 --> 00:31:17,870
+عنده طبقتين كلّه بنخلط بيبين قطعة واحدة نفس الشيء
+
+327
+00:31:17,870 --> 00:31:20,790
+ال ethanol نفس الشيء ال propanol هدول اللي were
+
+328
+00:31:20,790 --> 00:31:27,810
+alcohol بعد شوية لما ال R group بتكبر إيش بيصير ال
+
+329
+00:31:27,810 --> 00:31:32,390
+solubility؟ بطل يخلطوا بأي نسبة لو رحت على ال
+
+330
+00:31:32,390 --> 00:31:36,590
+pentanol اثنين وسبعة من عشرة جرام بيدوب في ال
+
+331
+00:31:36,590 --> 00:31:39,830
+water بعده بيصير يفصل طبقة ثانية لو رحت على
+
+332
+00:31:39,830 --> 00:31:48,410
+ال hexanol حوالي نص جرام بس بيدوب والباقي بيفصل إذا
+
+333
+00:31:48,410 --> 00:31:51,830
+كل ما أنا بزيد الـ
+
+334
+00:31:53,670 --> 00:31:59,190
+وفي higher alcohols شو بيصير في الذائبية اللي
+
+335
+00:31:59,190 --> 00:32:04,850
+عنده بتقل كل ما بنروح على ال higher alcohols ال
+
+336
+00:32:04,850 --> 00:32:14,470
+solubility بتقل واضح هذه الفكرة السؤال ليش؟ ليش كل
+
+337
+00:32:14,470 --> 00:32:19,230
+ما بنروح على ال higher alcohols ال solubility
+
+338
+00:32:19,230 --> 00:32:20,450
+بتقل؟
+
+339
+00:32:23,860 --> 00:32:28,700
+الآن هذا الـ hydrogen bonding نفسه هنا ما فيش عندي
+
+340
+00:32:28,700 --> 00:32:33,540
+تغيير هو وين التغيير بيجيني قاعد أنا أزيد هنا قاعد
+
+341
+00:32:33,540 --> 00:32:40,140
+أزيد هنا قاعد أزيد هنا لاحظوا معه تطلعوا لي على ال
+
+342
+00:32:40,140 --> 00:32:46,280
+alcohol هذا ال alcohol هذا ال alcohol
+
+343
+00:32:52,840 --> 00:32:58,980
+جزء الـ OH اللي بنقول عنه الـ Polar part اللي
+
+344
+00:32:58,980 --> 00:33:05,920
+بيدوب في إيش؟ في المية وجزء ال alkyl part اللي
+
+345
+00:33:05,920 --> 00:33:11,320
+هو الـ Non Polar إذا هذا ال alcohol جاي خليط من
+
+346
+00:33:11,320 --> 00:33:19,080
+شغلتين موجودات مع بعض Polar part و Non Polar part
+
+347
+00:33:25,120 --> 00:33:31,680
+العامة جداً اللي في الذائبية ممتاز ممتاز ممتاز
+
+348
+00:33:31,680 --> 00:33:36,880
+حافظوا ماني like like dissolve
+
+349
+00:33:38,730 --> 00:33:44,050
+like الأشياء اللي زي بعض بدوب بعض ال polar بدوب في
+
+350
+00:33:44,050 --> 00:33:48,850
+ال polar و ال non polar بدوب في ال non polar الآن
+
+351
+00:33:48,850 --> 00:33:53,310
+هذه المشكلة إن هذا ال alcohol المياه خليني أعتبرها
+
+352
+00:33:53,310 --> 00:34:00,990
+طولاً واحداً polar المياه هذه polar الآن ال alcohol
+
+353
+00:34:00,990 --> 00:34:05,850
+يبني آدم بالضبط بيعمل حسناته وسيئات في الآخر إيش
+
+354
+00:34:05,850 --> 00:34:11,770
+بيقول الله مزاد؟ في حسنات هنا مشاكل الناس بيدعوا فيش
+
+355
+00:34:11,770 --> 00:34:16,730
+حدّ ما هيعمل سيئات لكن المهم إنّه آه يعني في تنافس
+
+356
+00:34:16,730 --> 00:34:27,010
+فلما تكون هذه حميدة نقول السيئات لأن هذه بتسبب عدم
+
+357
+00:34:27,010 --> 00:34:31,930
+الرضا وهذه بتسبب الرضا لما تكون صغيرة الجزء
+
+358
+00:34:31,930 --> 00:34:48,290
+يبدو كأنه أكثر polar كبرت كبرت كبرت كبرت كبرت
+
+359
+00:34:48,290 --> 00:34:48,870
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+360
+00:34:48,870 --> 00:34:49,710
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+361
+00:34:49,710 --> 00:34:49,750
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+362
+00:34:49,750 --> 00:34:49,850
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+363
+00:34:49,850 --> 00:34:50,450
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+364
+00:34:50,450 --> 00:34:51,550
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+365
+00:34:51,550 --> 00:34:54,830
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبر
+
+366
+00:34:56,180 --> 00:35:02,400
+يعني بقدر أعتبره كأنه polar زي لما بدنا نقيم أي
+
+367
+00:35:02,400 --> 00:35:07,440
+شخص في عنده حسنات حسنات على العين والرأس والله
+
+368
+00:35:07,440 --> 00:35:13,000
+في سيئتين ثلاث كل بني آدم كل ابن آدمه خطأ واختاروا
+
+369
+00:35:13,000 --> 00:35:16,720
+الخطأين لكن إذا زادت زادت زادت زادت في الآخر
+
+370
+00:35:16,720 --> 00:35:21,000
+الواحد بي بطل يطيقوا هذا البني آدم بيصير المفروض
+
+371
+00:35:21,000 --> 00:35:27,780
+إنّه ما يصحبوش لكن على إيش صغير بي بطل الإنسان الصحبة
+
+372
+00:35:27,780 --> 00:35:34,280
+من يجيبنا بيت شعير الواحد بي بطل صحبته على إيش
+
+373
+00:35:34,280 --> 00:35:37,980
+صغير إنها
+
+374
+00:35:37,980 --> 00:35:44,540
+بيغذي بياني أو الذبياني ولست بمستبق أخاً لا تلمه
+
+375
+00:35:44,
+
+401
+00:38:27,980 --> 00:38:31,600
+bonding هذه الـ hydrogen bonding هي اللي بتزيد ال
+
+402
+00:38:31,600 --> 00:38:35,900
+boiling point بين الألكوهول والألكوهول مسئولة عن
+
+403
+00:38:35,900 --> 00:38:41,200
+الـ boiling point بين الألكوهول والميّه مسئولة عن
+
+404
+00:38:41,200 --> 00:38:48,600
+الـ solubility أو الذائبية بيجينا موضوع جديد دائما
+
+405
+00:38:48,600 --> 00:38:54,360
+و أبدا متعلق بالالكوهولز اللي هو موضوع ال acidity
+
+406
+00:38:54,360 --> 00:39:00,810
+أو الحامضية هنا الـ Acidity احنا بنتعامل معها بإنه
+
+407
+00:39:00,810 --> 00:39:06,830
+حسب تعريف الـ Laurie-Bronsted Definition الـ Acid
+
+408
+00:39:06,830 --> 00:39:14,870
+هو اللي بيفقد H+. الـ Acid هو اللي بيفقد H+. بناء
+
+409
+00:39:14,870 --> 00:39:19,330
+على ذلك الكحول لما بدي أعمله ك Acid بدي أقول إن
+
+410
+00:39:19,330 --> 00:39:26,870
+الـ ROH يا ترى، بينفع عصير R O minus زائد H plus هي
+
+411
+00:39:26,870 --> 00:39:31,850
+معادلة الحامض أو لو قلت مع الميه R O H مع الميه
+
+412
+00:39:31,850 --> 00:39:37,690
+بتصير R O minus زائد H3O plus واضح؟ فهذا
+
+413
+00:39:37,690 --> 00:39:43,630
+مفهوم ال acid أنه بده يفقد بروتون ال acid the
+
+414
+00:39:43,630 --> 00:39:50,900
+substance that loses  إيه بروتون؟ الآن قوة الأحماض
+
+415
+00:39:50,900 --> 00:39:55,840
+إيش اللي بتحكم فيها؟ لما بدأ أقول هذا الحامض أقوى
+
+416
+00:39:55,840 --> 00:40:00,450
+من هذا الحامض و بدأ أدخل في منطقة التعليل إيش اللي
+
+417
+00:40:00,450 --> 00:40:05,010
+بتتحكم في قوة الأحماض؟ يعني لما بدي أجي أسأل طالبة
+
+418
+00:40:05,010 --> 00:40:08,350
+في الامتحان بديها تعرف بأي منطقة تفكر بيقولها
+
+419
+00:40:08,350 --> 00:40:12,690
+which one of the following assets is stronger؟ ها
+
+420
+00:40:12,690 --> 00:40:21,330
+الحمضين أيهما أقوى؟ وين بديها تروح تتطلع؟ الـ KA هي
+
+421
+00:40:21,330 --> 00:40:29,520
+عبارة عن جواب غلط ما فهمتوش سؤالي ما فهمتوش سؤالي
+
+422
+00:40:29,520 --> 00:40:33,820
+بالمرة انتوا لسه الـ K.A هي اللي بتكون جايلا لإنه
+
+423
+00:40:33,820 --> 00:40:37,720
+هذا أقوى من هذا أنا بسألش مين أقوى أنا بسأل على
+
+424
+00:40:37,720 --> 00:40:42,600
+التعليل بمعنى لما أقولكوا هذا أقوى من هذا معنى ذلك
+
+425
+00:40:42,600 --> 00:40:47,520
+إن الـ K.A لهذا أعلى من هذا أو الـ P.K.A لهذا أقل من 
+
+426
+00:40:47,520 --> 00:40:53,780
+هذا هذه أشياء مفهومة ضمنها شو اللي بيخليه يفقد
+
+427
+00:40:53,780 --> 00:41:00,580
+أكتر؟ هنا السؤال، وين المحور اللي بدي أطلع عليه؟
+
+428
+00:41:00,580 --> 00:41:07,000
+لما بدي أحكي عن قوة أحماض لو كان عندى أربع أحماض
+
+429
+00:41:07,000 --> 00:41:11,640
+وقاعد بدي أعملهم ionization الأربع أحماض، كل واحد
+
+430
+00:41:11,640 --> 00:41:17,980
+فيهم هيفقد H+, H+, H+, هل في خلاف عندى في الـ H+,
+
+431
+00:41:17,980 --> 00:41:23,580
+اللي فوقدت؟ هو وين الخلاف؟ في الـ minus اللي بده
+
+432
+00:41:23,580 --> 00:41:29,800
+يفهم قوة حامض بده يطلع على الـ Ion السالب يعني لو
+
+433
+00:41:29,800 --> 00:41:34,040
+كان عندي .. هتقولكوا أنا سبع أنواع من الأحماض كلهم
+
+434
+00:41:34,040 --> 00:41:39,050
+قاعدوني سالب زاد H plus سالب زاد H plus سالب زاد H
+
+435
+00:41:39,050 --> 00:41:42,970
+plus الـ H plus مشتركة مش هي محور الخلاف المشترك
+
+436
+00:41:42,970 --> 00:41:46,790
+مش هو محور الخلاف هوين المختلف الـ minus اللي هان
+
+437
+00:41:46,790 --> 00:41:48,870
+غير الـ minus اللي هان غير الـ minus اللي هان غير
+
+438
+00:41:48,870 --> 00:41:52,670
+الـ minus اللي هان إذا أنا دائما لما بدي أدرس قوة
+
+439
+00:41:52,670 --> 00:41:58,550
+الأحماض بدي أطلع وين؟ على الـ minus الـ minus لازم
+
+440
+00:41:58,550 --> 00:42:03,550
+يكون ثابت ثبات الشحنة يكون بماذا؟
+
+441
+00:42:06,080 --> 00:42:12,740
+لما بدي أقول شحنة ثابتة ثبات الشحنة دائما بتقليلها 
+
+442
+00:42:12,740 --> 00:42:19,380
+دائما و أبدا دائما و أبدا لما بدي أحكي عن ثبات
+
+443
+00:42:19,380 --> 00:42:26,490
+للشحنة ثبات الشحنة بماذا؟ بتقليلها واضح؟ ثبات
+
+444
+00:42:26,490 --> 00:42:33,130
+الشحنة بتقليل هذا قولا واحدا عشان هيك مثلا لو
+
+445
+00:42:33,130 --> 00:42:38,910
+افترضنا أن بني آدم زعلان كتير عنده شحنة غضب بيكون
+
+446
+00:42:38,910 --> 00:42:45,350
+ثابت بيرجف و .. إيش بيجيبوله؟ بيجيبوله طبيب نفسي
+
+447
+00:42:45,350 --> 00:42:49,230
+الطبيب النفسي بقعد يحكي معاه بيفرغ .. بيفرغ ..
+
+448
+00:42:49,230 --> 00:42:54,900
+بيفرغ بيفرق كل الشحنة اللي عنده، مصبوط ولا لأ؟ أه
+
+449
+00:42:54,900 --> 00:43:00,100
+إذا، ثبات الشحنة بتقليلها حتى لو كنتي تقول الشحنة
+
+450
+00:43:00,100 --> 00:43:06,480
+بالمفهوم الديني الشحنة أو الغضب عبارة عن إيش؟ نار
+
+451
+00:43:07,510 --> 00:43:10,650
+الرسول عليه الصلاة والسلام بيقول أما رأيتم إلح
+
+452
+00:43:10,650 --> 00:43:17,030
+مرار أوداجه وانتفاخ عينيه وكأنه رأس شيطان غضبان،
+
+453
+00:43:17,030 --> 00:43:21,470
+الآن صار ملال نار، شحنة نار، هذا الغضبان إيش بده
+
+454
+00:43:21,470 --> 00:43:28,370
+يعمله؟ بدي أضيع النار بإيش بضيعها بالميه؟ أنسى بإيش
+
+455
+00:43:28,370 --> 00:43:32,610
+بالمية؟ جد ما يكون البني آدم غضبان، هتشوفوا وشه
+
+456
+00:43:32,610 --> 00:43:37,130
+أحمر وما إلى ذلك، لو اتودى، بروح الغضب، شوف بني
+
+457
+00:43:37,130 --> 00:43:40,550
+آدم عامل توشة جد الدنيا، خلوه يتودى أو خلوه ياخدوش
+
+458
+00:43:40,550 --> 00:43:47,060
+مية باردة هذه طاقة شحنة كلها إيش بيصيرلها؟ بتفقد من
+
+459
+00:43:47,060 --> 00:43:51,880
+البني آدم فثبات الشحنة دائما بإيش؟ بتقليلها هذا
+
+460
+00:43:51,880 --> 00:43:55,660
+مفهوم أساسي بتكون دالكوا عارفينه وانا بعتبره هو
+
+461
+00:43:55,660 --> 00:44:00,400
+المفهوم الأهم على الإطلاق في فهم الكيميا العضوية
+
+462
+00:44:02,030 --> 00:44:07,930
+و بفهم الدنيا ثبات الشحنة بإيش؟ بتقليلها، الآن بصير
+
+463
+00:44:07,930 --> 00:44:12,450
+سؤال جديد كيف بدي أقلل شحنة؟
+
+464
+00:44:14,770 --> 00:44:21,750
+واضح؟ كيف أنا في عندى شحنة معينة وبدى أجى أقلل هذه
+
+465
+00:44:21,750 --> 00:44:27,270
+الشحنة خلّيني أعطيكم مثال بسيط خلّيني أعطيكم مثال
+
+466
+00:44:27,270 --> 00:44:29,750
+بسيط من واقع الحياة اللي بيفهم الأمور بالحياة
+
+467
+00:44:29,750 --> 00:44:34,270
+بيفهمها بين؟ بالكيميا كويس لو افترضنا ان واحد هيك
+
+468
+00:44:34,270 --> 00:44:39,690
+اول يوم ما استلم الراتب نزل على السوق شرا أغراض
+
+469
+00:44:39,690 --> 00:44:47,610
+مثلًا حطها هيك بكيس عشرة كيلو نفترض رز ومشي الآن
+
+470
+00:44:47,610 --> 00:44:51,030
+العشرة كيلو هدولة إيش يمثلوا بالنسبة لهذا البني
+
+471
+00:44:51,030 --> 00:44:58,190
+آدم شحنة تعب بيتعب فيهم كيف بده يتخلص من شحنة
+
+472
+00:44:58,190 --> 00:45:05,630
+التعب هذا عنده احتمالين عنده احتمالين اما انه بده
+
+473
+00:45:05,630 --> 00:45:09,490
+يجي ولاد مقدّب وان شاء الله كل كويس وولادكوا في
+
+474
+00:45:09,490 --> 00:45:14,130
+المستقبل يكونوا مقدّبين ويقولوا بدي اساعد معاك
+
+475
+00:45:14,130 --> 00:45:19,670
+بيصير نوع من المشاركة واضح؟ بيجي إشي يحمل معه من
+
+476
+00:45:19,670 --> 00:45:25,070
+الخارج واضح؟ بيجي ولاد بيحمل معه الكيس هذا بيمسك
+
+477
+00:45:25,070 --> 00:45:31,350
+بإيد هذا بيمسك بإيد الآن قلل الحمل بمساعدة خارجية
+
+478
+00:45:31,350 --> 00:45:35,130
+واضح؟ وهذا تقليل الحمل بمساعدة خارجية بعد شوية
+
+479
+00:45:35,130 --> 00:45:39,110
+هنلاقي إنه له موازي في الكيميا وبنسميه inductive
+
+480
+00:45:39,110 --> 00:45:43,490
+effect إنه ييجي إشي يحمل معي من هالشحنة طيب
+
+481
+00:45:43,490 --> 00:45:50,330
+ما إيجاش هالولد الشاطر إيش بيصير يعمل؟ صوروا بيمشي
+
+482
+00:45:50,330 --> 00:45:53,990
+له عشر خطوات و حملي للكيس بهذه الإيد بعدين بهذه
+
+483
+00:45:53,990 --> 00:45:57,950
+الإيد بعدين بهذه الإيد بعدين بهذه الإيد هذه
+
+484
+00:45:57,950 --> 00:46:01,490
+العملية شو بنسميها احنا في الكيميا resonance اه
+
+485
+00:46:01,490 --> 00:46:07,830
+اذا انا لما بدي اقلل الشحنة يعني انتبهوا معي to
+
+486
+00:46:07,830 --> 00:46:14,690
+stabilize a charge اذا انا بدي اثبت الشحنة إيش
+
+487
+00:46:14,690 --> 00:46:24,680
+لازم نقول we must decrease it لازم إيش؟ نقللها اللي
+
+488
+00:46:24,680 --> 00:46:30,460
+بده يثبت شحنه بده يقللها كيف؟ by two ways نمرا
+
+489
+00:46:30,460 --> 00:46:36,200
+واحد اللي بنسميها inductive effect انه يجيجيش من
+
+490
+00:46:36,200 --> 00:46:41,420
+الخارج يحمل معه شحنه وشغلة تانية انه يصير ينجلها
+
+491
+00:46:41,420 --> 00:46:48,320
+من شغلتين اللي هو ال resonance effect resonance
+
+492
+00:46:48,320 --> 00:46:58,760
+effect إذا أنا لما بدي أخفف شحنة بدي أمشي بأحد
+
+493
+00:46:58,760 --> 00:47:06,200
+مصارين يا inductive effect يا resonance effect كل
+
+494
+00:47:06,200 --> 00:47:10,500
+ما كان بإمكاني أستوعب الشحنة أكتر بتكون أثبت بيكون
+
+495
+00:47:10,500 --> 00:47:18,170
+الحامض إيش ماله أقوى إذا الشحنة لا جادر إيش يحملها
+
+496
+00:47:18,170 --> 00:47:22,390
+من برا ولا في إمكانية resonance بيكون الوضع وضع
+
+497
+00:47:22,390 --> 00:47:26,130
+ثابت يعني تخيلوا بني آدم مثلا عنده إيد مريضة
+
+498
+00:47:26,130 --> 00:47:29,910
+مابقدرش يستعملها و بس عنده إيد واحدة و عنده عشر
+
+499
+00:47:29,910 --> 00:47:36,130
+تقرة واضح؟ الحقيقة هذا الكلام إحنا بنشوفه لما
+
+500
+00:47:36,130 --> 00:47:41,830
+بندرس ال acidity لالكحولات والميه وغيرها وغيراتها
+
+501
+00:47:41,830 --> 00:47:48,660
+إذا بتطلعوا تقريبا ال PKA اللي هي التعبير عن
+
+502
+00:47:48,660 --> 00:47:58,100
+الحمضية وال PKA كل ما قلت الحمضية
+
+503
+00:47:58,100 --> 00:48:07,800
+إيش بيصير منها؟ بتزيد عندكوا
+
+504
+00:48:07,800 --> 00:48:14,920
+قاعد أخدتوا .. لما أخدتوا ال PKA و PKA تذكروها كل
+
+505
+00:48:14,920 --> 00:48:22,200
+ما الـ Ka زادت الحمضية بتزيد وكل ما الـ Pka قلت
+
+506
+00:48:22,200 --> 00:48:29,620
+الحمضية بتزيد إذا بنجيب نتطلع للميه والميثانون
+
+507
+00:48:29,620 --> 00:48:36,000
+والإيثانون وتقريباً لبيوتانون أو الـ tetrabutanol
+
+508
+00:48:36,000 --> 00:48:42,080
+لاحظوا الـ Pka في كل هدول المركبات إيش مالها؟ عالية
+
+509
+00:48:43,050 --> 00:48:47,690
+الـ PKA عالية كثير إذا هدولة كلهم عبارة عن weak
+
+510
+00:48:47,690 --> 00:48:54,510
+acids أحماض ضعيفة عليهم شحنة الـ Oxygen اللي بدأ
+
+511
+00:48:54,510 --> 00:49:00,430
+تحمل الشحنة صغيرة لا تستطيع أن تحمل شحنة مش ال
+
+512
+00:49:00,430 --> 00:49:05,810
+Oxygen ذرة صغيرة ما بتقدرش تحمل شحنة إذا كل هدولة
+
+513
+00:49:05,810 --> 00:49:12,990
+يعتبروا أحماض لأنه ما فيش إمكانية لحمل الشحنة وقد
+
+514
+00:49:12,990 --> 00:49:17,830
+استغربوا أن حمضية الميه تقريبا زي حمضية الإيثانول
+
+515
+00:49:23,920 --> 00:49:28,060
+15 9 من 10 إذا الإيثانول مش حامض زيه زي الميّه
+
+516
+00:49:28,060 --> 00:49:32,220
+الدليل ع هيك لو اشتغلتوا في المستقبل بالتحاليل
+
+517
+00:49:32,220 --> 00:49:35,880
+الطبية وعملتوا مزرعة بكتيريا أو ما إلى ذلك بعد ما
+
+518
+00:49:35,880 --> 00:49:39,080
+تخلصوا عشان تقتلوا الجراثيم بتغسلوا بإيش
+
+519
+00:49:39,080 --> 00:49:42,260
+بالإيثانول بالإيثانول
+
+520
+00:49:43,720 --> 00:49:47,160
+بنغسل عادي بالإيثانول وبعده بالمية والصابونة لأن
+
+521
+00:49:47,160 --> 00:49:50,200
+الإيثانول هو اللي بيقتل الجرافيب، الآن هل لما أنا
+
+522
+00:49:50,200 --> 00:49:55,540
+بغسل بالكحول الإيثانول إيديا بيتقرح وما إلا، بقدر
+
+523
+00:49:55,540 --> 00:50:01,200
+أغسل بالـ HCL؟ مستحيل، لكن بقدر أغسل بالإيثانول؟
+
+524
+00:50:01,200 --> 00:50:07,280
+أه، حمضية الإيثانول زي حمضية الميه عشان هيك اللي
+
+525
+00:50:07,280 --> 00:50:10,860
+بيشتغل في مختبر تحاليل طبية أول .. جابل ما .. بعد
+
+526
+00:50:10,860 --> 00:50:13,760
+ما يخلص أي تحاليل و جابل ما يروح كمان مرة لازم
+
+527
+00:50:13,760 --> 00:50:18,060
+يغسل كل إيديه بالإيثانول و كأنه بيغسل بميه ما
+
+528
+00:50:18,060 --> 00:50:21,940
+بيصيرش لها عنده حرق ولا إشي يوميا بيغسل بالإيثانول
+
+529
+00:50:21,940 --> 00:50:28,750
+لأن حامضية الإيثانول زي حامضية إيش؟ الميه احنا لسه
+
+530
+00:50:28,750 --> 00:50:32,730
+خلّينا نقول في أول الموضوع، اليوم المحاضرة خلصت،
+
+531
+00:50:32,730 --> 00:50:36,030
+لكن الموضوع الحمضية كبير، اللي صرنا ماخدينه أنه
+
+532
+00:50:36,030 --> 00:50:40,410
+اتذكرنا شوية معلومات عن الحمضية وقلنا أنه الميه
+
+533
+00:50:40,410 --> 00:50:45,830
+والميثانول والإيثانول كلهم عبارة عن weak acids،
+
+534
+00:50:45,830 --> 00:50:49,630
+very weak acids كمان، وبنغسل وجوهنا فيهم وإيدينا
+
+535
+00:50:49,630 --> 00:50:55,110
+ولا بنحرج ولا إشي مصبوط ولا لا؟ بعد هيك هنتوسع في
+
+536
+00:50:55,110 --> 00:50:57,990
+الموضوع يعني يمكن بدنا في ال acidity كمان نص ساعة
+
+537
+00:50:57,990 --> 00:51:00,590
+ان شاء الله في المحاضرة القادمة
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..7e74b7f22d5c35585ee6a635180ccbd46211c248
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/FE-_4OFiwAM_raw.srt
@@ -0,0 +1,2160 @@
+1
+00:00:15,470 --> 00:00:22,450
+اليوم إن شاء الله هنبدأ بفصل جديد الفصل السابع زي
+
+2
+00:00:22,450 --> 00:00:26,410
+ما بتلاحظوا على السطورة العنوان اللي عندنا
+
+3
+00:00:26,410 --> 00:00:33,410
+alcohols, phenols and thiols يعني كأنه في هذا
+
+4
+00:00:33,410 --> 00:00:38,690
+الفصل بدأ نستعرض تلت أنواع من المركبات بس أكيد
+
+5
+00:00:38,690 --> 00:00:44,530
+أكيد دول الأنواع التلاتة في بينهم شبه وفي بينهم
+
+6
+00:00:45,220 --> 00:00:52,240
+قواسم مشتركة ولذلك يعني بيوضعوا مع بعض ربما عدد
+
+7
+00:00:52,240 --> 00:00:55,840
+كبير منكوا خليني أقول عارفين ال alcohol المركبات
+
+8
+00:00:55,840 --> 00:01:00,280
+اللي فيها اللي هم اللي بنقول عنهم R-OH بالظبط
+
+9
+00:01:00,280 --> 00:01:06,080
+المركبات اللي فيهم OH الآن ال phenols برضه فيهم OH
+
+10
+00:01:06,080 --> 00:01:10,840
+لكن محمول على حلقة أروماتية زي البنزين يعني بدل ما
+
+11
+00:01:10,840 --> 00:01:17,550
+نقول R إيش بنقول؟ A-R AromaticOH هذه عائلة
+
+12
+00:01:17,550 --> 00:01:23,330
+الفينولز الثيولز زي الألكوهول بالظبط بس بدل ما
+
+13
+00:01:23,330 --> 00:01:28,310
+يكون عندي OH بيصير عندي SH يعني الثيولز إيش بتكون
+
+14
+00:01:28,310 --> 00:01:36,710
+بيصير عندي ه؟ SH واضح؟ وأكيد أنه قادرين تلاحظوا
+
+15
+00:01:36,710 --> 00:01:41,950
+العلاقة بين هدول الأنواع التلاتة من المركبات هنبدأ
+
+16
+00:01:41,950 --> 00:01:47,500
+طبعابالـ Alcohols بشكل قليل بالـ Phenols وبعدين
+
+17
+00:01:47,500 --> 00:01:52,460
+بنمر على الـ RSH لكن أكيد الموضوع الأساس عندنا
+
+18
+00:01:52,460 --> 00:01:58,320
+أكتر شيء عليه تركيز اللي هو الـ Alcohols إيش بتعني
+
+19
+00:01:58,320 --> 00:02:01,600
+ال Alcohols في الكيميا العضوية؟ طبعاً في منهجية
+
+20
+00:02:01,600 --> 00:02:05,780
+دائما للدراسة في الكيميا العضوية لما بناخد ال
+
+21
+00:02:05,780 --> 00:02:09,020
+functional groups و العائلات لإن أحنا في الأول
+
+22
+00:02:09,020 --> 00:02:14,020
+بدنا نتعلم نسمي المركباتبعد هيك بدنا نتعلم نحضرها
+
+23
+00:02:14,020 --> 00:02:19,360
+و بعدين ندرس تفاعلاتها يعني دائما اللي بده ياخد
+
+24
+00:02:19,360 --> 00:02:24,720
+مجموعة وظيفية معينة بده يعرف تلت شغلات تسمية،
+
+25
+00:02:24,720 --> 00:02:31,350
+تحضير، تفاعلات واضح تسمية و تحضير و تفاعلاتالان لو
+
+26
+00:02:31,350 --> 00:02:37,170
+اجينا لموضوع التسمية ال alcohols تسمى مثل ال
+
+27
+00:02:37,170 --> 00:02:42,190
+alkanes المناظرة بس بزيادة النهاية all
+
+28
+00:02:47,130 --> 00:02:53,810
+E في الآخر يعني بس OL ما بنقولش OLE هذا الكلام
+
+29
+00:02:53,810 --> 00:02:57,230
+يمكن يكون منه فائدة لأنه لما بتقرأ أحيانا أسماء
+
+30
+00:02:57,230 --> 00:03:03,070
+مركبات و نهايتها OLE معناه ذلك مش alcohols هذه
+
+31
+00:03:03,070 --> 00:03:07,050
+يعني لو أنا مثلا بدي أقول cholesterol هي نهايته
+
+32
+00:03:07,050 --> 00:03:14,800
+all هذا OL هذا OLبصنفه alcohol finally لكن لو بدأ
+
+33
+00:03:14,800 --> 00:03:19,520
+اقول مثلا نترايزول تترازول أكزازول بيرازول هذه
+
+34
+00:03:19,520 --> 00:03:25,160
+منطقة تانية حلقات غير متجانس نهيتها OLE وإيها معنى
+
+35
+00:03:25,160 --> 00:03:31,500
+بعيد تماما عن المعنى تبعه يعني في الكيميا الحلقية
+
+36
+00:03:31,500 --> 00:03:39,200
+هذه ال OLEاللي هي بتعطي نهاية all برضه معناها أنه
+
+37
+00:03:39,200 --> 00:03:44,500
+مُركّب في حلقة خماسية يعني ال OLE في الكيميا
+
+38
+00:03:44,500 --> 00:03:49,620
+الحلقية بتتعني لإيش؟ حلقة خماسية و هدولة مُركّبات
+
+39
+00:03:49,620 --> 00:03:54,820
+اللي هم تطبيقات كتيرة كمضادات للفطريات معظم الناس
+
+40
+00:03:54,820 --> 00:03:57,760
+اللي عندهم فطريات بين أصابعهم أوش زيك بتلاقيهم
+
+41
+00:03:57,760 --> 00:04:00,480
+بيستعملوا Dactazol و Fluconazol
+
+42
+00:04:02,730 --> 00:04:06,990
+انيزول لأ .. انيزول is a phenol .. انيزول ..
+
+43
+00:04:06,990 --> 00:04:10,370
+انيزول is a phenol .. خلّينا نمر الآن بالتدريج و
+
+44
+00:04:10,370 --> 00:04:17,170
+نشوف الموقع الانيزول مش فينول حتى O-methyl ether
+
+45
+00:04:17,170 --> 00:04:25,690
+نمشي فيهم بهدوء أبسط الكان كان الميثينلما بدى اعمل
+
+46
+00:04:25,690 --> 00:04:30,210
+منه انا alcohol بدى يصير بال IUPAC Nomenclature
+
+47
+00:04:30,210 --> 00:04:33,410
+Methanol
+
+48
+00:04:33,410 --> 00:04:38,990
+واضح؟ اذا هذه التسمية اللى محطوطة فوق هي اي تسمية؟
+
+49
+00:04:38,990 --> 00:04:45,810
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+50
+00:04:45,810 --> 00:04:50,210
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+51
+00:04:50,210 --> 00:04:50,910
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+52
+00:04:50,910 --> 00:04:50,910
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+53
+00:04:50,910 --> 00:04:50,930
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+54
+00:04:50,930 --> 00:04:50,930
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC
+
+55
+00:04:50,930 --> 00:04:53,650
+IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC IUPAC I
+
+56
+00:04:54,100 --> 00:04:59,380
+ميثانول إذا عندي إيثين إيثانول إذا عندي بروبين
+
+57
+00:04:59,380 --> 00:05:04,300
+بروبانول لكن أنا متوقع تيجي على موقعين بس عندي one
+
+58
+00:05:04,300 --> 00:05:09,200
+بروبانول و two بروبانول يعني لازم أحدد وين جاية
+
+59
+00:05:09,200 --> 00:05:17,440
+مجموعة ال OH الآن لو هذه المركبات بدي أسميهابال
+
+60
+00:05:17,440 --> 00:05:21,300
+common nomenclature بدي اجيب اسم المجموعة يعني في
+
+61
+00:05:21,300 --> 00:05:25,280
+كل مرة بدي اشوف ايش المجموعة اللي عندى اذكر اسمها
+
+62
+00:05:25,280 --> 00:05:32,280
+و اتبعها بالكهول يعني هنا هذه المجموعة CH3 هنا هذه
+
+63
+00:05:32,280 --> 00:05:34,780
+واضح؟
+
+64
+00:05:35,880 --> 00:05:40,780
+فبأدخل على اسم المجموعة و بيجي بعدها alcohol فهذه
+
+65
+00:05:40,780 --> 00:05:44,700
+المجموعة مثل بيصير المركب بال common nomenclature
+
+66
+00:05:44,700 --> 00:05:51,800
+مثل alcohol إثل .. إثلالكهول إبروبلالكهول هذه
+
+67
+00:05:51,800 --> 00:05:56,700
+المجموعة ال CH اللي طالع منها تنتهي CH3-isopropyl
+
+68
+00:05:56,700 --> 00:06:02,740
+واضح؟ يعني حتى ال common nomenclature هنا بتلاحظوا
+
+69
+00:06:02,740 --> 00:06:07,370
+كأنها تصير برضه على إيش؟على قاعدة وعلى نمط محدد
+
+70
+00:06:07,370 --> 00:06:12,790
+أنكم تذكرون الـ Alkyl group و بعدها تضعون alcohol
+
+71
+00:06:12,790 --> 00:06:17,710
+و في كل هذه المراكبات لو كان عندي مثلا halogen ليس
+
+72
+00:06:17,710 --> 00:06:20,310
+alcohol يعني لو افترضت في يوم كله مبدأ للـ OH عند
+
+73
+00:06:20,310 --> 00:06:24,330
+ال brom كان يقول نعم مثل bromide إثلبروميد بروميد
+
+74
+00:06:24,330 --> 00:06:28,990
+بروميد إيزوبروميد بروميد إيزوبروميد و هكذا و كل
+
+75
+00:06:28,990 --> 00:06:33,070
+هذه الأسماء اللي بتبدأ بالـ alkyl group كمجموعة هي
+
+76
+00:06:33,070 --> 00:06:40,680
+عبارة عنcommon names الان هذا المركز اللى بدى أطلع
+
+77
+00:06:40,680 --> 00:06:45,440
+عليه هذه المجموعة برضه مرت علينا اذا كنا بدنا ..
+
+78
+00:06:45,440 --> 00:06:48,040
+ان دلنا متابعين شوية في ال common nomenclatures
+
+79
+00:06:48,040 --> 00:06:52,720
+هذه اللى هى مجموعة ال isobutyl لأن واحد اتنين
+
+80
+00:06:52,720 --> 00:06:59,240
+تلاتة اربعة ف isobutyl isobutyl بصير isobutyl
+
+81
+00:06:59,240 --> 00:07:05,860
+alcohol اللى بعدههذه المجموعة الكربون اللي حملة
+
+82
+00:07:05,860 --> 00:07:12,460
+ثلاثة CH3 تيرتشاريبيوتل ألكوهول واضح؟ والمجموعة
+
+83
+00:07:12,460 --> 00:07:16,620
+اللي هنا لما
+
+84
+00:07:16,620 --> 00:07:20,720
+أخدنا الالكينز أخدنا مجموعتين اللي لهم أسماء
+
+85
+00:07:20,720 --> 00:07:26,500
+الفينل والألل هذا عبارة عن مجموعة الألل إذا هذا
+
+86
+00:07:26,500 --> 00:07:32,540
+عبارة عن ألل ألكوهول إذا هذا عبارة عنألل ألكوه
+
+87
+00:07:32,540 --> 00:07:37,700
+الان لو بدأ أرجع للتلاتة اللي تحت نتأكد من تسميتهم
+
+88
+00:07:37,700 --> 00:07:41,960
+في ال common في عفوا في ال iopac nomenclature في
+
+89
+00:07:41,960 --> 00:07:46,260
+ال iopac nomenclature بدنا نشوف أطول سلسلة ونبدأ
+
+90
+00:07:46,260 --> 00:07:53,640
+من عند ال OH واحد اتنين تلاتة اذا هذا one-probanol
+
+91
+00:07:53,640 --> 00:07:58,160
+هذا ال one-probanol ايش حامل على موقع اتنين مثل
+
+92
+00:07:58,160 --> 00:08:05,210
+اذا هذا two مثلone two three one pro panol two مثل
+
+93
+00:08:05,210 --> 00:08:09,730
+one pro panol الان لو بدى اجعل هذا المركب على فرض
+
+94
+00:08:09,730 --> 00:08:12,450
+ان هو يعدي واحد اتنين تلاتة هذا ايش بدى يصير
+
+95
+00:08:12,450 --> 00:08:16,210
+المركب two pro panol اكيد نفس الشي واحد اتنين
+
+96
+00:08:16,210 --> 00:08:20,190
+تلاتة واحد اتنين تلاتة خلينا نمشي زيك مثلا واحد
+
+97
+00:08:20,190 --> 00:08:24,030
+اتنين تلاتة two pro panol ايش حامل ال two pro
+
+98
+00:08:24,030 --> 00:08:31,620
+panol two مثل اذا هذا two مثل two pro panoltwo
+
+99
+00:08:31,620 --> 00:08:37,360
+-methyl two-propanol okay؟ الآن المركب التالت
+
+100
+00:08:37,360 --> 00:08:44,040
+المركب التالت بيلتقي فيه أكثر من مجموعة وظيفية في
+
+101
+00:08:44,040 --> 00:08:48,060
+ال double bond كمجموعة وظيفية اللي هي بتاخد
+
+102
+00:08:48,060 --> 00:08:53,760
+النهاية inوالألكهول كمجموعة وظيفية بتاخد النهاية
+
+103
+00:08:53,760 --> 00:08:59,540
+All إذا بزموا مجمعتين وظيفيتين بيصير التفكير يا
+
+104
+00:08:59,540 --> 00:09:07,400
+بتسمي In All يا All In واضح؟ وبتهيألي سابقا إحنا
+
+105
+00:09:07,400 --> 00:09:13,420
+عملنا أولوية أنه بيكون أعلى في الأولويات قولنا أقل
+
+106
+00:09:13,420 --> 00:09:19,370
+أولويات الـ Alkanes بعدها الـ Alkanesبعدها ال
+
+107
+00:09:19,370 --> 00:09:23,730
+alcohols وبعدها ال ketones ال aldehydes ال acids
+
+108
+00:09:23,730 --> 00:09:28,970
+ال esters فمين أولويته أعلى أنه ينسب له الجزء ال
+
+109
+00:09:28,970 --> 00:09:33,390
+OH أعلى من ال double bond و أعلى من ال triple bond
+
+110
+00:09:33,390 --> 00:09:39,500
+عشان هيك لازم يكون المركب نهايتهall بترجعوله في
+
+111
+00:09:39,500 --> 00:09:43,820
+تسمية الـ aromatic compounds أخدنا سلسلة إيش
+
+112
+00:09:43,820 --> 00:09:49,000
+الأولويات؟ فهذا المركب عبارة عن all والترقيم بيبدأ
+
+113
+00:09:49,000 --> 00:09:56,080
+من وين؟ من ال alcohol بزام طالما أنه صرت أنا ناسبه
+
+114
+00:09:56,080 --> 00:09:59,980
+لل all إذا كل الاحترام والثقة والتخدير لمين؟ لل
+
+115
+00:09:59,980 --> 00:10:03,820
+all هو بيكون اسم العائلة للمركب ومن عنده يبدأ
+
+116
+00:10:03,820 --> 00:10:09,950
+الترقيمفعيكون عندي one two three خلاص مركبة all ال
+
+117
+00:10:09,950 --> 00:10:14,450
+double bond بتيجي تحصيل حاصل واضح؟ ولذلك هذا لما
+
+118
+00:10:14,450 --> 00:10:20,230
+بدنا نيجي نسميه في in all فبنقول two probine إيش
+
+119
+00:10:20,230 --> 00:10:25,670
+معناه two probine؟ إنه مجموعة ال in فهذه ال two
+
+120
+00:10:25,670 --> 00:10:30,590
+تحدد موقع ال double bond وين بدايتها؟ طب one all
+
+121
+00:10:33,080 --> 00:10:38,620
+جاى على موقع واحد فانا لما بكتبوا بهذا الاسم two
+
+122
+00:10:38,620 --> 00:10:46,120
+propene one all اللي بحكي بالظبط ان ال alcohol على
+
+123
+00:10:46,120 --> 00:10:52,880
+موقع واحد و ال double bond بدايتها على موقع اتنين
+
+124
+00:10:52,880 --> 00:11:01,240
+واضح؟ two propene one allالان ممكن على السريع نأكد
+
+125
+00:11:01,240 --> 00:11:08,880
+هذا الكلام بمثال شبيه وطالب منكم تعطينا الجواب
+
+126
+00:11:08,880 --> 00:11:18,140
+نكتبه هنا لو كتبنا مثلا CH3CCH2OH
+
+127
+00:11:18,140 --> 00:11:25,980
+وقلنا بتناقش ايش المجموعات الموجودة
+
+128
+00:11:27,010 --> 00:11:34,090
+الـ Kind, I'm و All لمن الأولوية؟ لل All إذا أنا
+
+129
+00:11:34,090 --> 00:11:40,930
+لازم أبدأ أرقم واحد،
+
+130
+00:11:40,930 --> 00:11:48,930
+اتنين، تلاتة، أربعة، واضح؟ إذا هذا هيكون بيوتاين
+
+131
+00:11:48,930 --> 00:11:52,730
+All بيوتاين All
+
+132
+00:12:02,230 --> 00:12:09,350
+توبيوتين وان قول واضح؟ لأن الألكوهول له أولوية على
+
+133
+00:12:09,350 --> 00:12:14,930
+الـ double و ال triple bonds الألكوهول له أولوية
+
+134
+00:12:14,930 --> 00:12:18,330
+على الـ double و ال triple bonds فبصير هو يمثل قيم
+
+135
+00:12:18,330 --> 00:12:24,970
+شغلتين هذه الأولوية بتعني إيش؟ شغلتين أنه يمثل اسم
+
+136
+00:12:24,970 --> 00:12:28,170
+العائلة في النهاية دايما اسم العيلة في الأول ولا
+
+137
+00:12:28,170 --> 00:12:33,130
+في الآخر؟ مظبوط ولا لا؟أه اسم العيلة دائما في ال
+
+138
+00:12:33,130 --> 00:12:38,630
+.. أخو و من عنده يد بالطريقة
+
+139
+00:12:51,960 --> 00:12:58,300
+هذه أمثلة إضافية .. هذه أمثلة إضافية .. الان لو
+
+140
+00:12:58,300 --> 00:13:05,600
+كان عندي Alcohol على Cycloalkane هذا Cyclopentane
+
+141
+00:13:05,600 --> 00:13:10,520
+ايه جعله Alcohol؟ ايش بيصير؟ Cyclopentanol اسم
+
+142
+00:13:10,520 --> 00:13:17,360
+منطقي ولا لأ؟ شيلنا ال .. ال .. ال Alcohol الـ O-H
+
+143
+00:13:17,360 --> 00:13:25,290
+-O لو كانت انتينDiol لو صاروا تلاتة تترايول اربعة
+
+144
+00:13:25,290 --> 00:13:32,490
+تترا اول الجزء اللي عندنا هنا كام اول فيه تنتين
+
+145
+00:13:32,490 --> 00:13:39,290
+اذا هذا ديول سايكلو بين تين ديول لكن لما بيكونوا
+
+146
+00:13:39,290 --> 00:13:45,250
+تنتين لازم احددو المواقعهم في الأول بالنسبة لبعض
+
+147
+00:13:45,250 --> 00:13:49,390
+ممكن يكونوا جايين ورا بعض واحد و اتنين و ممكن واحد
+
+148
+00:13:49,390 --> 00:13:53,610
+و تلاتة، مظبوط ولا لا؟ اذا كأنه انا عندي one, two,
+
+149
+00:13:54,010 --> 00:14:00,750
+three, four, five فهذا لازم احط عنه one, two,
+
+150
+00:14:01,250 --> 00:14:05,870
+cyclopentane, diol لان لو الـ OH إجت هنا، إيش بدي
+
+151
+00:14:05,870 --> 00:14:11,930
+يصير؟ one, three, cyclopentane, diol لو إجت هنالأ
+
+152
+00:14:11,930 --> 00:14:17,470
+one and three من الجهات التانية دائما بتكون تسع
+
+153
+00:14:17,470 --> 00:14:22,850
+ورا اقل ترقيم اه الان في كمان شغلة انه احنا قولنا
+
+154
+00:14:22,850 --> 00:14:28,170
+ال double pointsالـ double bonds و الحلقات هذه
+
+155
+00:14:28,170 --> 00:14:32,190
+double bonds شايفينها؟ فيهم ظاهرة إيش؟ ال cis و
+
+156
+00:14:32,190 --> 00:14:37,770
+الtrans إنه المجموعات مع بعض ولا عكس بعض، في هذه
+
+157
+00:14:37,770 --> 00:14:41,830
+الحالة هم مرسومين ال wedges مع بعض ولا لأ؟ جايين
+
+158
+00:14:41,830 --> 00:14:46,010
+هيك للأمام باتجاهنا، إذا هذا cis one two
+
+159
+00:14:46,010 --> 00:14:50,920
+cyclopentane diolإذاً هذا ال sis compound لو كنت
+
+160
+00:14:50,920 --> 00:14:55,360
+بدّي ال trans compound بدو ييجي السهم أو ال .. ال
+
+161
+00:14:55,360 --> 00:15:00,140
+أسفين هذا dashed إيش معناه dashed؟ إنه بديل على
+
+162
+00:15:00,140 --> 00:15:07,340
+إنه رايح للخلف okay الآن لو إجينا للمركب اللي بعده
+
+163
+00:15:07,340 --> 00:15:12,100
+المركب اللي بعده بتلاحظه فيه حلقة بنزين لكن لو أنا
+
+164
+00:15:12,100 --> 00:15:16,600
+بدي أنسبه للبنزين هذه المجموعة كلها مالهاش اسم
+
+165
+00:15:16,600 --> 00:15:22,340
+مشهورفي مثل هذه الحالة ممكن نرجع احنا للالكين،
+
+166
+00:15:22,340 --> 00:15:26,620
+نقول الالكين اللي موجود عندى، كم كربونا عليه؟
+
+167
+00:15:26,620 --> 00:15:32,880
+تنتل، هاي كربونا تنتل، كأنه هذا هو الأساس اللي
+
+168
+00:15:32,880 --> 00:15:36,740
+موجود عندى، هاي one, two، الآن إيش بيحمل هذا
+
+169
+00:15:36,740 --> 00:15:43,180
+الالكين؟مجموعتين البنزين وال OH طبعا الأولوية في
+
+170
+00:15:43,180 --> 00:15:46,540
+هذه الحالة لل OH البنزين تصبح كأنها مجموعة
+
+171
+00:15:46,540 --> 00:15:51,960
+والبنزين لما تكون مجموعة ايش اسمها؟ فنل فنل ما
+
+172
+00:15:51,960 --> 00:15:59,720
+تقولوش فنل فنل لأن الفنل double bond اذا هذا صار
+
+173
+00:15:59,720 --> 00:16:08,860
+كأنه اللي موجود عند ايثانول CH2 OH CH2فنل إذا هذا
+
+174
+00:16:08,860 --> 00:16:17,100
+فعلاً two phenyl إيثانول ممكن يعني لو بدنا نأكد
+
+175
+00:16:17,100 --> 00:16:23,120
+التسمية و نقول two phenyl one إيثانول ممكن
+
+176
+00:16:23,120 --> 00:16:28,600
+نقول two phenyl one إيثانول ليش خلف من اللي يجينا
+
+177
+00:16:28,600 --> 00:16:33,640
+إذا بدنا ناخد بالموازاة تماما مركب برضه زي هيك من
+
+178
+00:16:33,640 --> 00:16:40,240
+ضغطين تظهر هاديCH3 ويكون عندي غنى OH وغنى فينيل
+
+179
+00:16:40,240 --> 00:16:46,860
+وقت لو بدى أسمي هذا المركب شو هسميه ايه ايه ايه
+
+180
+00:16:46,860 --> 00:16:51,800
+ايه ايه ايه
+
+181
+00:16:51,800 --> 00:16:52,200
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+182
+00:16:52,200 --> 00:16:52,780
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+183
+00:16:52,780 --> 00:16:57,800
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+184
+00:16:57,800 --> 00:16:57,800
+ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه ايه
+
+185
+00:16:57,800 --> 00:17:01,260
+ايه ايه ايه ايه ايه ايه ايه ايه اي
+
+186
+00:17:17,900 --> 00:17:25,340
+والثالث يعني الذرة رقم الكاربور رقم 3
+
+187
+00:17:29,150 --> 00:17:34,510
+تقريباً كل هادولة alcohols الفينول الأبسط فينول
+
+188
+00:17:34,510 --> 00:17:38,690
+اللي هو ال parent compound اللي بيكون بنزينة و
+
+189
+00:17:38,690 --> 00:17:39,170
+عليها
+
+190
+00:17:48,560 --> 00:17:53,240
+بارا نيترو فينول الأولوية طبعا لل all
+
+191
+00:18:01,670 --> 00:18:06,770
+الـ Nitro مع الـ Halogens، أه منخفضة لكن لما كنا
+
+192
+00:18:06,770 --> 00:18:13,250
+ناخد ال All مع ال Acid مين أعلى في الأولوية؟ ال
+
+193
+00:18:13,250 --> 00:18:18,990
+Acid أعلى من ال All عشان كان المركب لو كنت بدى
+
+194
+00:18:18,990 --> 00:18:26,290
+أطلع عليه لأى عائلة يُنسب للحمض ولا للكحول؟ للحمض،
+
+195
+00:18:26,290 --> 00:18:30,870
+بدى يُنسب لهذه العائلة و ترقيمه من وين هيكون؟من
+
+196
+00:18:30,870 --> 00:18:36,590
+هنا و بالمرة أسرع ما يمكن على
+
+197
+00:18:36,590 --> 00:18:42,570
+المجموعة هذه إذا هذا عبارة عن بنزويك أسد إيش موجود
+
+198
+00:18:42,570 --> 00:18:47,710
+على بنزويك أسد على موقع اتنين مجموعة الـ OH طالما
+
+199
+00:18:47,710 --> 00:18:53,500
+هي مش اسم العائلة بترجع لاسمها الأصل هيدروكسيأسد
+
+200
+00:18:53,500 --> 00:19:00,440
+واضح فال OH لما تكون مش اسم عائلة للمُركّب و هذا
+
+201
+00:19:00,440 --> 00:19:04,000
+الكلام بيكون إذا كان في المُركّب مجموعة كيتون أو
+
+202
+00:19:04,000 --> 00:19:13,680
+الديهيد أو أسد أو إيستر هي ترجع لإيش للعصل تبعها
+
+203
+00:19:13,680 --> 00:19:18,780
+اللي هو اسمها هيدروكسي فهذا الارتوهيدروكسي بنزويك
+
+204
+00:19:18,780 --> 00:19:28,300
+أسداللي بيقله اسم common salicylic acid و هذا ال
+
+205
+00:19:28,300 --> 00:19:36,380
+salicylic acid كتير كتير مهم في حد بيعرفه ليش مهم؟
+
+206
+00:19:36,380 --> 00:19:44,960
+اه لأن هو اللي منه بتحضر ال aspirin من شجر الصفصاف
+
+207
+00:19:46,380 --> 00:19:50,340
+من شجر الصفسار يعني هذا ال salicylic acid بس
+
+208
+00:19:50,340 --> 00:19:55,660
+بيعمله فيه تغييره بسيطه بيصير aspirin ال analgetic
+
+209
+00:19:55,660 --> 00:19:59,800
+اللي هو الدواء بتاع الصدار بس أنا بحطه صيده من ال
+
+210
+00:19:59,800 --> 00:20:06,560
+bond O CH3 بدل هذه ال H بيصير aspirin واضح؟ و لذلك
+
+211
+00:20:06,560 --> 00:20:09,240
+هذا ال salicylic acid مهم و واجهته ب salicylic
+
+212
+00:20:09,240 --> 00:20:15,280
+acid ال aspirin واضح؟هنا إيش المجموعتين اللي
+
+213
+00:20:15,280 --> 00:20:21,820
+إلتقوا بهذا الجزء الديهايد ال CHO معناها C double
+
+214
+00:20:21,820 --> 00:20:27,320
+bond O و H الجهة التانية الديهايد مين إله أولوية
+
+215
+00:20:27,320 --> 00:20:33,500
+في التسمية الديهايد إذا هذا بنزا الديهايد هذا
+
+216
+00:20:33,500 --> 00:20:37,580
+المركب بنزا الديهايد يعني واحد اتنين تلاتة اربعة
+
+217
+00:20:37,580 --> 00:20:38,060
+خمسة
+
+218
+00:20:41,550 --> 00:20:46,150
+الـ 3-hydroxybenzaldehyde أو الـ
+
+219
+00:20:46,150 --> 00:20:49,470
+metahydroxybenzaldehyde
+
+220
+00:21:07,580 --> 00:21:12,060
+هك تقريبا بيكون أخدنا فكرة معقولة خلّينا نقول عن
+
+221
+00:21:12,060 --> 00:21:18,240
+تسمية ال alcohols ابنجي لبعض الخواص اللي متعلقة
+
+222
+00:21:18,240 --> 00:21:24,220
+فيهم وبعد هيك بندخل أكثر على تحضيرهم ان شاء اللهمن
+
+223
+00:21:24,220 --> 00:21:27,840
+أكتر الأشياء اللي بتميز ال alcohol ال hydrogen
+
+224
+00:21:27,840 --> 00:21:34,240
+bonding واضح؟ وبالمناسبة هتلاحظوا أن ال alcohol ال
+
+225
+00:21:34,240 --> 00:21:42,320
+alcohol ربما أكتر إشي بيشبه إيش؟ الميّهالـ Alcohol
+
+226
+00:21:42,320 --> 00:21:47,780
+أكتر إشي بيشبه الميّه طبعا بيشبهها من ناحية كيميا
+
+227
+00:21:47,780 --> 00:21:53,280
+بيشبهها من ناحية كيميا بس من ناحية دين و شريعة لأ
+
+228
+00:21:53,280 --> 00:21:59,040
+بالمرة يعني الميّه ربنا قال و جعلنا من الماء كل
+
+229
+00:21:59,040 --> 00:22:03,990
+شيء حي لكن ال alcohol لو أخدنا الاثانول منهيا أيها
+
+230
+00:22:03,990 --> 00:22:07,110
+الذين آمنوا إنما الخمر و الميسر و الأنصاب و
+
+231
+00:22:07,110 --> 00:22:11,590
+الأسلام رشسوا من عمل الشيطان فاجتنبوه الان لاحظوا
+
+232
+00:22:11,590 --> 00:22:17,150
+ليش احنا بنقول أنه الميه يعني فلسفيا ممكن تمثل
+
+233
+00:22:17,150 --> 00:22:21,750
+أبسط ألكوهل ممكن تمثل أبسط ألكوهل لو أنا أخدت
+
+234
+00:22:21,750 --> 00:22:26,630
+عائلة .. انا عندي هاي OH متصلة ابقاش بعد هي كان
+
+235
+00:22:26,630 --> 00:22:29,430
+بيصير عندي OH متصلة
+
+236
+00:22:34,020 --> 00:22:40,100
+مثالول هذا مثالول
+
+237
+00:22:40,100 --> 00:22:46,060
+هذا مثالول هذا مثالول هذا مثالول
+
+238
+00:22:50,390 --> 00:22:57,570
+متصلة بـ ethyl مثل الـ OH ولذلك بتلاحظوا أن محور
+
+239
+00:22:57,570 --> 00:23:02,130
+الشبه بين الميّه .. محور الشبه بين الميّه و ال ..
+
+240
+00:23:02,130 --> 00:23:08,730
+و ال alcohol هو وجود مجموعة الـ OH واضح؟ محور
+
+241
+00:23:08,730 --> 00:23:12,870
+الشبه بين الميّه و ال alcohol هو وجود مجموعة الـ
+
+242
+00:23:12,870 --> 00:23:16,830
+OH هذا الكلام اللي بي .. اللي بيخلي صفة مشتركة
+
+243
+00:23:16,830 --> 00:23:22,210
+بينهم اللي هي الـ polarityإن الميّه مصممة بولارية
+
+244
+00:23:22,210 --> 00:23:28,930
+والألكوهولز برضه عبارة عن مصممة بولارية الـ OH
+
+245
+00:23:28,930 --> 00:23:36,320
+بتعمل هيدروجين بوندينج بتخلي نقطة الغليانعالية
+
+246
+00:23:36,320 --> 00:23:40,800
+نسبياً واضح؟ مثل هدولة مثلا المُركّبات الميّه
+
+247
+00:23:40,800 --> 00:23:44,600
+بالوضع الطبيعي بتغني عندها كم؟ عند مية الميثانول
+
+248
+00:23:44,600 --> 00:23:48,860
+عند حوالي ستين أو واحد وستين الإثانول عند حوالي
+
+249
+00:23:48,860 --> 00:23:55,660
+تمانين أو تمانية وسبعين ملاحظين؟ طبعا الميّه أعلى
+
+250
+00:23:55,660 --> 00:24:02,400
+منهم لأنه بتعمل تنتين hydrogen bonding ومر علينا
+
+251
+00:24:02,400 --> 00:24:08,120
+كيف الميّه بتعمل hydrogen bondingواضح فالشبه بينهم
+
+252
+00:24:08,120 --> 00:24:14,240
+في ال boiling point المرتفعة هو وجود ال OH
+
+253
+00:24:14,240 --> 00:24:21,420
+البولاري جروب اللي بتعمل hydrogen bonding واضح هاي
+
+254
+00:24:21,420 --> 00:24:25,380
+يمكن ال boiling point الدقيقة هنا 65 إذا بدكم
+
+255
+00:24:25,380 --> 00:24:36,840
+الميثانول 65 الميهالإيثانول 78.5% البروبانون 97%
+
+256
+00:24:36,840 --> 00:24:42,260
+البيوتانون 117% زي ما بتلاحظوا هنا زي ما بتلاحظوا
+
+257
+00:24:42,260 --> 00:24:48,260
+هنا انه بشكل عام وجود ال OH وجود ال OH بيخلي ال
+
+258
+00:24:48,260 --> 00:24:52,950
+boiling pointمرتفعة، لكن بنفس الوقت إحنا عندنا
+
+259
+00:24:52,950 --> 00:24:58,110
+قاعدة عامة كل ما الجزء كبر الـ R group كبرت برضه
+
+260
+00:24:58,110 --> 00:25:03,310
+نقاط الغليان إيش بصيرلها؟ ابتعلى، يعني إذا بتذكروا
+
+261
+00:25:03,310 --> 00:25:09,890
+مثلا في ال الكنز الميثين كان تقريبا ناقص 160 وكان
+
+262
+00:25:09,890 --> 00:25:16,860
+غاز، والإيثينغاز البروبين غاز بس بيصير ال boiling
+
+263
+00:25:16,860 --> 00:25:22,800
+point أعلى البيوتين غاز البنتين بيبدأ يصير سائل
+
+264
+00:25:22,800 --> 00:25:29,160
+boiling point حوالي 36 الهكسين سائل أكيد بعدين
+
+265
+00:25:29,160 --> 00:25:32,480
+بيصير سوائل ال boiling point أعلى فإحنا كل ما
+
+266
+00:25:32,480 --> 00:25:37,060
+بتزيد العدد الكربونات أو ال R groups كل ما بترتفع
+
+267
+00:25:37,750 --> 00:25:42,070
+نقطة الغليان فهنا واضح تماما في السلسلة ان عندك
+
+268
+00:25:42,070 --> 00:25:45,750
+كربونة تلتين تلاتة اربعة خمسة ستة ونقاط الغليان
+
+269
+00:25:45,750 --> 00:25:49,210
+عاملا بترجع لكن بشكل عام احنا بنقول كل هذه النقاط
+
+270
+00:25:49,210 --> 00:25:56,470
+نسبيا مرتفعة جداكل هذه النقاط مرتفعة جداً والسبب
+
+271
+00:25:56,470 --> 00:26:03,790
+هو وجود الـ OH طبعا مرتفعة جدا الأمر نسبة يعني
+
+272
+00:26:03,790 --> 00:26:09,850
+قارنوها لما بنقول مرتفعة جدا بالكان يعني مثلا هذا
+
+273
+00:26:09,850 --> 00:26:14,770
+الميثانول قارنوه بال إيثين مثلا أو الميثين بتلاقي
+
+274
+00:26:14,770 --> 00:26:19,210
+نقطة الغليان حوالي ناقص 160 ناقص 140 الآن أنا لما
+
+275
+00:26:19,210 --> 00:26:25,590
+أصير أحكي عن 65 يعني أنا مرتفع كام درجةمتين يعني
+
+276
+00:26:25,590 --> 00:26:30,550
+لو بدأ أخد مركب نفس ال molecular weight تلاتة خمس
+
+277
+00:26:30,550 --> 00:26:36,570
+عشر و ست عشر و اتش اتنين و تلاتين اتنين و تلاتين
+
+278
+00:26:36,570 --> 00:26:42,670
+لو اتيت مثلا أخدت ال A2 خمس عشر و خمس عشر تلاتين
+
+279
+00:26:42,670 --> 00:26:47,810
+تقريبا متساويات في ال molecular weight لكن ال A2
+
+280
+00:26:47,810 --> 00:26:53,160
+لم تدرس ال boiling point تبعهنقص مائة و أربعين
+
+281
+00:26:53,160 --> 00:26:58,200
+يمكن هنا المثال
+
+282
+00:26:58,200 --> 00:27:01,920
+هو الخمسة و ستين لو بدأ أقول مائة و أربعين لخمسة و
+
+283
+00:27:01,920 --> 00:27:05,940
+ستين مائة و أربعين بناقص لخمسة و ستين كده الفرق؟
+
+284
+00:27:05,940 --> 00:27:14,740
+متين درجة مئوية من ناقص مائة و أربعين إلى خمسة و
+
+285
+00:27:14,740 --> 00:27:18,320
+ستين من ناقص مائة و أربعين إلى خمسة و ستين كده
+
+286
+00:27:18,320 --> 00:27:24,230
+الفرق تقريباحوالي 200 درجة أعلى، من أين أتوا هؤلاء
+
+287
+00:27:24,230 --> 00:27:30,450
+الـ 200 درجة؟ من الـ hydrogen bonding، واضح؟ هؤلاء
+
+288
+00:27:30,450 --> 00:27:33,350
+الـ 200 درجة أتوا من الـ hydrogen bonding اللي
+
+289
+00:27:33,350 --> 00:27:37,310
+موجود في الكحول ولي مش موجود في مركب له نفس الوزن
+
+290
+00:27:37,310 --> 00:27:38,430
+زي الـ إيثان
+
+291
+00:27:41,220 --> 00:27:47,240
+غير قصة اللي هي ال boiling point ذائبية ال alcohol
+
+292
+00:27:47,240 --> 00:27:54,660
+في الميه ذائبية ال alcohol في الميه الآن هنا بدكوا
+
+293
+00:27:54,660 --> 00:27:59,000
+تنتبهوا ال boiling point لما بتعمل ال alcohol
+
+294
+00:27:59,000 --> 00:28:03,600
+هيدروجيلبون مع
+
+295
+00:28:03,600 --> 00:28:13,020
+ايش؟ مع نفسهامع نفسها يعني انا لما اقول methanol و
+
+296
+00:28:13,020 --> 00:28:20,140
+عامل hydrogen bonding كأن هنا بقول بالظبط CH3OH و
+
+297
+00:28:20,140 --> 00:28:26,360
+من هنا عامل hydrogen bonding مع واحد تاني هاي
+
+298
+00:28:26,360 --> 00:28:35,030
+hydrogen bonding هيك مقطعة H OCH3 فهي عندي جزءوجزء
+
+299
+00:28:35,030 --> 00:28:39,890
+هذا الـ hydrogen bonding ما بين جزيئات نفس المادة
+
+300
+00:28:39,890 --> 00:28:46,250
+بيعمل الارتفاع في نقطة الغليان الآن بيجيني
+
+301
+00:28:46,250 --> 00:28:51,190
+الذائبية الذائبية ال alcohol في الميه الذائبية ال
+
+302
+00:28:51,190 --> 00:28:55,830
+alcohol في الميه الذائبية برضه عبارة عن hydrogen
+
+303
+00:28:55,830 --> 00:28:59,450
+bonding بس المرة هذه ال hydrogen bonding بتكون
+
+304
+00:28:59,450 --> 00:29:04,300
+معاشرمع الميّه بمعنى خلّيني أتخيل أنه عندى نفس جزء
+
+305
+00:29:04,300 --> 00:29:09,840
+الالكوهون هذا CH3OH وهي أزواج إلكترونات عليه و
+
+306
+00:29:09,840 --> 00:29:15,800
+بعدين بده يجي يعمل hydrogen bonding مع الميّه
+
+307
+00:29:15,800 --> 00:29:17,900
+واضح؟
+
+308
+00:29:19,840 --> 00:29:25,120
+هنا بتلاحظوا ان الالكول مع الالكول عملوا hydrogen
+
+309
+00:29:25,120 --> 00:29:27,980
+bonding هذه ال hydrogen bonding اللي ما بين
+
+310
+00:29:27,980 --> 00:29:33,620
+الالكول مع نفسه بين أثرها وين؟ في ال boiling point
+
+311
+00:29:33,620 --> 00:29:38,920
+المرتفعة ان الجزيات مرتبطة عشان أفصلها عن بعض
+
+312
+00:29:38,920 --> 00:29:44,380
+الغليان عبارة عن عملية ashفصل كامل انه انا بدي
+
+313
+00:29:44,380 --> 00:29:48,680
+الجزء افصل و بطير من المحلول و بطلع برا و عشان هيك
+
+314
+00:29:48,680 --> 00:29:56,320
+بده طاقة كبيرة و عضلة فال boiling point هي انها
+
+315
+00:29:56,320 --> 00:30:01,660
+تجميل hydrogen bonding ما بين جزيئات alcohol مع
+
+316
+00:30:01,660 --> 00:30:07,440
+بعض الان ال solubility انهم يخلطوا مع بعض هي عبارة
+
+317
+00:30:07,440 --> 00:30:10,420
+عن hydrogen bonding ما بين alcohol
+
+318
+00:30:14,190 --> 00:30:17,270
+الهيدروجي البُنّج بين الالكول والميّه هي اللي
+
+319
+00:30:17,270 --> 00:30:24,890
+بتتحكم في ال solubility إذا بتتطلعوا انتوا
+
+320
+00:30:24,890 --> 00:30:27,850
+هتلاحظوا ملاحظة
+
+321
+00:30:30,060 --> 00:30:34,100
+الجزيئات الأولى في ال alcohols اللى هم أبسط
+
+322
+00:30:34,100 --> 00:30:40,140
+alcohols هدولة عادة بيسموهم ال lower alcohols يعني
+
+323
+00:30:40,140 --> 00:30:44,900
+ال alcohols الصغيرة اللى هم الميثانول والإيثانول
+
+324
+00:30:44,900 --> 00:30:52,360
+والبروبانول ايش بيسموهم هدولة؟ lower alcohols
+
+325
+00:30:53,510 --> 00:30:57,190
+اللي هم أول الكحولات اللي were alcohol هدولة
+
+326
+00:30:57,190 --> 00:31:03,130
+بتلاقوهم بيدوبوا في الميه 100% completely miscible
+
+327
+00:31:03,130 --> 00:31:07,410
+ايش معناه كلمة miscible؟ بيخلط مع الميه تماما يعني
+
+328
+00:31:07,410 --> 00:31:11,750
+لما حط ال methanol فوق الميه وبأي نسبة مابصيرش
+
+329
+00:31:11,750 --> 00:31:17,870
+عنده طبقتين كله بنخلط بيبين قطعة واحدة نفس الاشي
+
+330
+00:31:17,870 --> 00:31:20,790
+ال ethanol نفس الاشي ال probanol هدول اللي were
+
+331
+00:31:20,790 --> 00:31:27,810
+alcoholبعد شوية لما ال R group بتكبر ايش بيصير ال
+
+332
+00:31:27,810 --> 00:31:32,390
+solubility؟ بطل يخلطوا بأي نسبة لو روحت على ال
+
+333
+00:31:32,390 --> 00:31:36,590
+pentanol اتنين و سبعة من عشرة جرام بيدوب في ال
+
+334
+00:31:36,590 --> 00:31:39,830
+meat meal بعدك بيصير يفصل طبقة تانية لو روحت على
+
+335
+00:31:39,830 --> 00:31:48,410
+الhexanol حوالي نص جرام بس بيدوب و البقى بيفصل إذا
+
+336
+00:31:48,410 --> 00:31:51,830
+كل ما أنا بحتاجي
+
+337
+00:31:53,670 --> 00:31:59,190
+و في higher alcohols شو بيصير في الذائبية اللي
+
+338
+00:31:59,190 --> 00:32:04,850
+عنده بتقل كل ما بنروح على ال higher alcohols ال
+
+339
+00:32:04,850 --> 00:32:14,470
+solubility بتقل واضح هذه الفكرة السؤال ليش؟ ليش كل
+
+340
+00:32:14,470 --> 00:32:19,230
+ما بنروح على ال higher alcohols ال solubility
+
+341
+00:32:19,230 --> 00:32:20,450
+بتقل؟
+
+342
+00:32:23,860 --> 00:32:28,700
+الأن هذا الـ hydrogen bonding نفسه هنا مافيش عندي
+
+343
+00:32:28,700 --> 00:32:33,540
+تغيير هو وين التغيير بيجيني قاعد أنا أزيد هنا قاعد
+
+344
+00:32:33,540 --> 00:32:40,140
+أزيد هنا قاعد أزيد هنا لاحظوا معاه اتطلعولي على ال
+
+345
+00:32:40,140 --> 00:32:46,280
+alcohol هذا ال alcohol هذا ال alcohol
+
+346
+00:32:52,840 --> 00:32:58,980
+جزء الـ OH اللي بنقول عنه الـ Polar part اللي
+
+347
+00:32:58,980 --> 00:33:05,920
+بيدوب في إيه؟ في الميه و جزء ال Alcohol part اللي
+
+348
+00:33:05,920 --> 00:33:11,320
+هو الـ Non Polar إذا هذا ال Alcohol جاي خليط من
+
+349
+00:33:11,320 --> 00:33:19,080
+شغلتين موجودات مع بعض Polar part و Non Polar part
+
+350
+00:33:25,120 --> 00:33:31,680
+العامة جدا اللي في الذائبية ممتاز ممتاز ممتاز
+
+351
+00:33:31,680 --> 00:33:36,880
+حافظي ماني like like dissolve
+
+352
+00:33:38,730 --> 00:33:44,050
+like الأشياء اللي زي بعض بدوب بعض ال polar بدوب في
+
+353
+00:33:44,050 --> 00:33:48,850
+ال polar و ال non polar بدوب في ال non polar الآن
+
+354
+00:33:48,850 --> 00:33:53,310
+هذه المشكلة أن هذا ال alcohol المياه خليني اعتبرها
+
+355
+00:33:53,310 --> 00:34:00,990
+طولا واحدا polar المياه هذه polar الآن ال alcohol
+
+356
+00:34:00,990 --> 00:34:05,850
+يبني آدم بالظبط يعمل حسناته سيئات في الآخر ايش
+
+357
+00:34:05,850 --> 00:34:11,770
+بيقول الله مزد؟في حسنات هنا مشاكل الناس بيدعو فيش
+
+358
+00:34:11,770 --> 00:34:16,730
+حد مش هيعمل سيئات لكن المهم انه اه يعني فيه تنافس
+
+359
+00:34:16,730 --> 00:34:27,010
+فلما تكون هذه حمينا نقول السيئات لأن هذه بتسبب عدم
+
+360
+00:34:27,010 --> 00:34:31,930
+الثوابان هذه بتسبب الثوابان لما تكون صغيرة الجزء
+
+361
+00:34:31,930 --> 00:34:48,290
+يبدو كأنه أكتر polar كبرتكبرت كبرت كبرت كبرت كبرت
+
+362
+00:34:48,290 --> 00:34:48,870
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+363
+00:34:48,870 --> 00:34:49,710
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+364
+00:34:49,710 --> 00:34:49,750
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+365
+00:34:49,750 --> 00:34:49,850
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+366
+00:34:49,850 --> 00:34:50,450
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+367
+00:34:50,450 --> 00:34:51,550
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت
+
+368
+00:34:51,550 --> 00:34:54,830
+كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبرت كبر
+
+369
+00:34:56,180 --> 00:35:02,400
+يعني بقدر اعتبره كإنه polar زي لما بدنا نقيّم أي
+
+370
+00:35:02,400 --> 00:35:07,440
+شخص في عنده حسنات حسنات على العين و الرأس و الله
+
+371
+00:35:07,440 --> 00:35:13,000
+في سيئتين تلاتة كل بني آدم كل ابن آدمه خطأ واخيروا
+
+372
+00:35:13,000 --> 00:35:16,720
+الخطأين لكن إذا زادت زادت زادت زادت في الآخر
+
+373
+00:35:16,720 --> 00:35:21,000
+الواحد بيبطل يطيقوا هذا البني آدم بيصير المفروض
+
+374
+00:35:21,000 --> 00:35:27,780
+إنه مايصحبوش لكن على إيش صغيربيبطل الإنسان الصحبة
+
+375
+00:35:27,780 --> 00:35:34,280
+من يجيبنا بيت شعير الواحد بيبطل الصحبته على إش
+
+376
+00:35:34,280 --> 00:35:37,980
+صغير إنها
+
+377
+00:35:37,980 --> 00:35:44,540
+بيغذ بياني أو الذبياني و لست بمستبق أخا لا تلمه
+
+378
+00:35:44,540 --> 00:35:49,980
+على شعث أي رجال المهذبوا يعني عنده شوية غلطات
+
+379
+00:35:49,980 --> 00:35:54,500
+صغيرة خلاص يعني بدنا نحكم عليه بالاعدامو هنا نفس
+
+380
+00:35:54,500 --> 00:36:01,140
+الاشي عند بولر و شوية نانبولر يعمل كإنه بولر يدوب
+
+381
+00:36:01,140 --> 00:36:07,680
+زاد ال نانبولر زاد زاد زاد في الآخر بنصير نعتبره
+
+382
+00:36:07,680 --> 00:36:11,640
+نانبولر يعني عند ال one-hexanol لما أجي أقولكوا
+
+383
+00:36:11,640 --> 00:36:15,520
+بتكنوا تعتبروه polar ولا nonpolar؟ almost nonpolar
+
+384
+00:36:15,520 --> 00:36:19,140
+طاغي في جزء ال alkyl group عشان هيك بطل يدوب في
+
+385
+00:36:19,140 --> 00:36:24,470
+الميه بينما الميثانولcompletely miscible فك
+
+386
+00:36:24,470 --> 00:36:28,950
+solvent الميثانول بيبين كإنه polar واضح الفكرة
+
+387
+00:36:28,950 --> 00:36:36,850
+وجود شغلتين في داخل الجزء طبعا منطق الحب والكره
+
+388
+00:36:36,850 --> 00:36:40,390
+للمي هذا الكلام برضه بيستعملوله مصطلحات مين
+
+389
+00:36:40,390 --> 00:36:47,730
+اتذكرنا فيهم هذا الجزء الأولاني بيقول عنهم وحبهم
+
+390
+00:36:48,550 --> 00:36:54,410
+للماء ايش المصطلح اللي بيستعملوله هيدروفليك يعني
+
+391
+00:36:54,410 --> 00:37:03,750
+محب للماء هذا جزء الهيدروفليك وهذا الجزء بكره
+
+392
+00:37:03,750 --> 00:37:08,750
+الميه هيدروفوبيك
+
+393
+00:37:08,750 --> 00:37:10,450
+كارهن لل
+
+394
+00:37:16,240 --> 00:37:21,300
+بيصير محب ل الدهول بدل ما هو محب ل الميه ليبوفيليك
+
+395
+00:37:21,300 --> 00:37:32,640
+من ال limits انا بدي اقول الكاره للماء محب ل
+
+396
+00:37:32,640 --> 00:37:36,440
+الدهول هيدروفوبك
+
+397
+00:37:36,440 --> 00:37:44,670
+كاره للميهليموفليك محبل الدهون أو الـ non-polar
+
+398
+00:37:44,670 --> 00:37:54,490
+solvents واضحة كشغلة الذائبية الآن بالنسبة لكم؟
+
+399
+00:37:54,490 --> 00:38:00,950
+أو
+
+400
+00:38:00,950 --> 00:38:07,190
+حصلته من المساقات اللي في سنة أولى من الجامعة بس
+
+401
+00:38:09,360 --> 00:38:14,780
+يعتبر .. قولوا في الكيميا في الحياة .. okay هنا
+
+402
+00:38:14,780 --> 00:38:21,080
+مجرد فقط توضيح .. مجرد توضيح بتاع اللي حكيناها
+
+403
+00:38:21,080 --> 00:38:27,980
+بالظبط كيف أنه ألكوهول مع ألكوهول بيعملوا hydrogen
+
+404
+00:38:27,980 --> 00:38:31,600
+bonding هذه الـ hydrogen bonding هي اللي بتزيد ال
+
+405
+00:38:31,600 --> 00:38:35,900
+boilingpoint بين الألكوهول والألكوهول مسئولة عن
+
+406
+00:38:35,900 --> 00:38:41,200
+الـ boiling point بين الألكوهول والميّه مسئولة عن
+
+407
+00:38:41,200 --> 00:38:48,600
+الـ solubility أو الذائبية بيجينا موضوع جديد دائما
+
+408
+00:38:48,600 --> 00:38:54,360
+و أبدا متعلق بالالكوهولز اللي هو موضوع ال acidity
+
+409
+00:38:54,360 --> 00:39:00,810
+أو الحامضيةهنا الـ Acidity احنا بنتعامل معها بإنه
+
+410
+00:39:00,810 --> 00:39:06,830
+حسب تعريف الـ Laurie-Bronsted Definition الـ Acid
+
+411
+00:39:06,830 --> 00:39:14,870
+هو اللي بيفقد H+. الـ Acid هو اللي بيفقد H+. بناء
+
+412
+00:39:14,870 --> 00:39:19,330
+على ذلك الكحول لما بدي أعمله ك Acid بدي أقول إن
+
+413
+00:39:19,330 --> 00:39:26,870
+الـ ROH يا ترى، بينفع عصيرR O minus زائد H plus هي
+
+414
+00:39:26,870 --> 00:39:31,850
+معادلة الحامض أو لو قلت مع الميه R O H مع الميه
+
+415
+00:39:31,850 --> 00:39:37,690
+بتصير R O minus زائد H three O plus واضح؟ فهذا
+
+416
+00:39:37,690 --> 00:39:43,630
+مفهوم ال acid أنه بده يفقد بروتون ال acid the
+
+417
+00:39:43,630 --> 00:39:50,900
+substance that losesإيه بروتون؟ الآن قوة الأحماض
+
+418
+00:39:50,900 --> 00:39:55,840
+إيش اللي بتحكم فيها؟ لما بدأ أقول هذا الحامض أقوى
+
+419
+00:39:55,840 --> 00:40:00,450
+من هذا الحامض و بدأ أدخل في منطقة التعليلأيش اللي
+
+420
+00:40:00,450 --> 00:40:05,010
+بتتحكم في قوة الأحماض؟ يعني لما بدي أجي أسأل طالبة
+
+421
+00:40:05,010 --> 00:40:08,350
+في الامتحان بديها تعرف بأي منطقة تفكر بيقولها
+
+422
+00:40:08,350 --> 00:40:12,690
+which one of the following assets is stronger؟ ها
+
+423
+00:40:12,690 --> 00:40:21,330
+الحمضين أيهما أقوى؟ وين بديها تروح تتطلع؟ الـKA هي
+
+424
+00:40:21,330 --> 00:40:29,520
+عبارة عن جواب غلطمافهمتوش سؤالي مافهمتوش سؤالي
+
+425
+00:40:29,520 --> 00:40:33,820
+بالمرة انتوا لسه الـK.A هي اللي بتكون جايلا لإنه
+
+426
+00:40:33,820 --> 00:40:37,720
+هذا أقوى من هذا أنا بسألش مين أقوى أنا بسأل على
+
+427
+00:40:37,720 --> 00:40:42,600
+التعليل بمعنى لما أقولكوا هذا أقوى من هذا معنى ذلك
+
+428
+00:40:42,600 --> 00:40:47,520
+إن الـK.A لهذا أعلى من هذا أو الـP.K.A لهذا أقل من
+
+429
+00:40:47,520 --> 00:40:53,780
+هذا هذه أشياء مفهومة ضمنها شو اللي بيخليه يفقد
+
+430
+00:40:53,780 --> 00:41:00,580
+أكتر؟هنا السؤال، وين المحور اللي بدي أطلع عليه؟
+
+431
+00:41:00,580 --> 00:41:07,000
+لما بدي أحكي عن قوة أحماض لو كان عندى أربع أحماض
+
+432
+00:41:07,000 --> 00:41:11,640
+وقاعد بدي أعملهم ionization الأربع أحماض، كل واحد
+
+433
+00:41:11,640 --> 00:41:17,980
+فيهم هيفقد H+, H+, H+, هل في خلاف عندى في الـH+,
+
+434
+00:41:17,980 --> 00:41:23,580
+اللي فوقدت؟ هو وين الخلاف؟ في الـminusاللي بده
+
+435
+00:41:23,580 --> 00:41:29,800
+يفهم قوة حامض بده يطلع على الـ Ion السالب يعني لو
+
+436
+00:41:29,800 --> 00:41:34,040
+كان عندي .. هتقولكوا أنا سبع أنواع من الأحماض كلهم
+
+437
+00:41:34,040 --> 00:41:39,050
+قاعدوني سالبزاد H plus سالب زاد H plus سالب زاد H
+
+438
+00:41:39,050 --> 00:41:42,970
+plus الـ H plus مشتركة مش هي محور الخلاف المشترك
+
+439
+00:41:42,970 --> 00:41:46,790
+مش هو محور الخلاف هوين المختلف الـ minus اللي هان
+
+440
+00:41:46,790 --> 00:41:48,870
+غير الـ minus اللي هان غير الـ minus اللي هان غير
+
+441
+00:41:48,870 --> 00:41:52,670
+الـ minus اللي هان إذا أنا دائما لما بدي أدرس قوة
+
+442
+00:41:52,670 --> 00:41:58,550
+الأحمار بدي أطلع وين؟ على الـ minus الـ minus لازم
+
+443
+00:41:58,550 --> 00:42:03,550
+يكون ثابت ثبات الشحنة يكون بماذا؟
+
+444
+00:42:06,080 --> 00:42:12,740
+لما بدي أقول شحنة ثابتة ثبات الشحنة دائما بتقليلها
+
+445
+00:42:12,740 --> 00:42:19,380
+دائما و أبدا دائما و أبدا لما بدي أحكي عن ثبات
+
+446
+00:42:19,380 --> 00:42:26,490
+للشحنة ثبات الشحنة بماذا؟ بتقليلهاواضح؟ ثبات
+
+447
+00:42:26,490 --> 00:42:33,130
+الشحنة بتقليل هذا قولا واحدا عشان هيك مثلا لو
+
+448
+00:42:33,130 --> 00:42:38,910
+افترضنا ان بني ادم زعلان كتير عنده شحنة غضب بيكون
+
+449
+00:42:38,910 --> 00:42:45,350
+ثابت بيرجف و .. ايش بيجيبوله؟ بيجيبوله طبيب نفسي
+
+450
+00:42:45,350 --> 00:42:49,230
+الطبيب النفسي بقعد يحكي معاه بيفرغ .. بيفرغ ..
+
+451
+00:42:49,230 --> 00:42:54,900
+بيفرغبفرق كل الشحنة اللي عنده، مصبوط ولا لأ؟ أه
+
+452
+00:42:54,900 --> 00:43:00,100
+إذا، ثابت الشحنة بتقليلها حتى لو كنتي تقول الشحنة
+
+453
+00:43:00,100 --> 00:43:06,480
+بالمفهوم الديني الشحنة أو الغضب عبارة عن إيش؟ نار
+
+454
+00:43:07,510 --> 00:43:10,650
+الرسول عليه الصلاة والسلام بيقول أما رأيتم إلح
+
+455
+00:43:10,650 --> 00:43:17,030
+مرار أوداجه وانتفاخ عينيه وكأنه رأس شيطان الغضبان،
+
+456
+00:43:17,030 --> 00:43:21,470
+الآن صار ملال نار، شحنة نار، هذا الغضبان إيش بده
+
+457
+00:43:21,470 --> 00:43:28,370
+أعمله؟بدي أضيع النار بإيش بضيعها بالمية؟ أنسى بإيش
+
+458
+00:43:28,370 --> 00:43:32,610
+بالمية؟ جد ما يكون البني آدم غضبان، هتشوفوا وشه
+
+459
+00:43:32,610 --> 00:43:37,130
+أحمر وما إلى ذلك، لو اتودى، بروح الغضب، شوف بني
+
+460
+00:43:37,130 --> 00:43:40,550
+آدم عامل توشة جد الدنيا، خلوه يتودى أو خلوه ياخدوش
+
+461
+00:43:40,550 --> 00:43:47,060
+مية باردةهذه طاقة شحنة كلها إيش بيصيرلها؟ بتفقد من
+
+462
+00:43:47,060 --> 00:43:51,880
+البني آدم فثبات الشحنة دائما بإيش؟ بتقليلها هذا
+
+463
+00:43:51,880 --> 00:43:55,660
+مفهوم أساسي بتكون دالكوا عارفينه وانا بعتبره هو
+
+464
+00:43:55,660 --> 00:44:00,400
+المفهوم الأهم على الإطلاق في فهم الكيميا العضوية
+
+465
+00:44:02,030 --> 00:44:07,930
+وبفهم الدنيا ثبات الشحنة بإيش؟ بتقليلها، الآن بصير
+
+466
+00:44:07,930 --> 00:44:12,450
+سؤال جديد كيف بدي أقلل شحنة؟
+
+467
+00:44:14,770 --> 00:44:21,750
+واضح؟ كيف أنا في عندى شحنة معينة وبدى أجى أقلل هذه
+
+468
+00:44:21,750 --> 00:44:27,270
+الشحنة خلّيني أعطيكم مثال بسيط خلّيني أعطيكم مثال
+
+469
+00:44:27,270 --> 00:44:29,750
+بسيط من واقع الحياة اللى بيفهم الأمور بالحياة
+
+470
+00:44:29,750 --> 00:44:34,270
+بيفهمها بين؟ بالكيميا كويس لو افترضنا ان واحد هيك
+
+471
+00:44:34,270 --> 00:44:39,690
+اول يوم ما استلم الراتب نزل على السوق شراأغراض
+
+472
+00:44:39,690 --> 00:44:47,610
+مثلًا حطها هيك بكيس عشرة كيلو نفترض رز ومشي الآن
+
+473
+00:44:47,610 --> 00:44:51,030
+العشرة كيلو هدولة إيش يمثلوا بالنسبة لهذا البني
+
+474
+00:44:51,030 --> 00:44:58,190
+آدم شحنة تعب بيتعب فيهم كيف بده يتخلص من شحنة
+
+475
+00:44:58,190 --> 00:45:05,630
+التعب هذا عنده احتمالينعنده احتمالين اما انه بده
+
+476
+00:45:05,630 --> 00:45:09,490
+ييجي ولاد مقدّب وان شاء الله كل كويس وولادكوا في
+
+477
+00:45:09,490 --> 00:45:14,130
+المستقبل يكونوا مقدّبين ويقولوا بدي اساعد معاك
+
+478
+00:45:14,130 --> 00:45:19,670
+بيصير نوع من المشاركة واضح؟ بيجي إشي يحمل معه من
+
+479
+00:45:19,670 --> 00:45:25,070
+الخارج واضح؟ بيجي ولاد بيحمل معه الكيس هذا بيمسك
+
+480
+00:45:25,070 --> 00:45:31,350
+بإيد هذا بيمسك بإيد الآن قلل الحمل بمساعدةخارجية
+
+481
+00:45:31,350 --> 00:45:35,130
+واضح؟ وهذا تقليل الحمل بمساعدة خارجية بعد شوية
+
+482
+00:45:35,130 --> 00:45:39,110
+هنلاقي إنه له موازي في الكيميا وبنسميه inductive
+
+483
+00:45:39,110 --> 00:45:43,490
+effect إنه ييجي إشي يحمل معي من هالشحنة طيب
+
+484
+00:45:43,490 --> 00:45:50,330
+ماإيجاش هالولد الشاطر إيش بيصير يعمل؟صوروا بيمشي
+
+485
+00:45:50,330 --> 00:45:53,990
+له عشر خطوات و حملي للكيس بهذه الإيد بعدين بهذه
+
+486
+00:45:53,990 --> 00:45:57,950
+الإيد بعدين بهذه الإيد بعدين بهذه الإيد هذه
+
+487
+00:45:57,950 --> 00:46:01,490
+العملية شو بنسميها احنا في الكيميا resonance اه
+
+488
+00:46:01,490 --> 00:46:07,830
+اذا انا لما بدي اقلل الشحنة يعني انتبهوا معي to
+
+489
+00:46:07,830 --> 00:46:14,690
+stabilize a charge اذا انا بدي اثبت الشحنة ايش
+
+490
+00:46:14,690 --> 00:46:24,680
+لازم نقول we mustdecrease it لازم ايش؟ نقللها اللي
+
+491
+00:46:24,680 --> 00:46:30,460
+بده يثبت شحنه بده يقللها كيف؟ by two ways نمرا
+
+492
+00:46:30,460 --> 00:46:36,200
+واحد اللي بنسميها inductive effect انه يجيجيش من
+
+493
+00:46:36,200 --> 00:46:41,420
+الخارج يحمل معه شحنه وشغلة تانية انه يصير ينجلها
+
+494
+00:46:41,420 --> 00:46:48,320
+من شغلتين اللي هو ال resonance effectresonance
+
+495
+00:46:48,320 --> 00:46:58,760
+effect إذا أنا لما بدي أخفف شحنة بدي أمشي بأحد
+
+496
+00:46:58,760 --> 00:47:06,200
+مصارين يا inductive effect يا resonance effect كل
+
+497
+00:47:06,200 --> 00:47:10,500
+ما كان بإمكاني أستوعب الشحنة أكتر بتكون أثبت بيكون
+
+498
+00:47:10,500 --> 00:47:18,170
+الحامض إيش ماله أقوى إذا الشحنةلا جادر إيش يحملها
+
+499
+00:47:18,170 --> 00:47:22,390
+من برا ولا في إمكانية resonance بيكون الوضع وضع
+
+500
+00:47:22,390 --> 00:47:26,130
+ثابت يعني تخيلوا بني آدم مثلا عنده إيد مريضة
+
+501
+00:47:26,130 --> 00:47:29,910
+مابقدرش يستعملها و بس عنده إيد واحدة و عنده عشر
+
+502
+00:47:29,910 --> 00:47:36,130
+تقرة واضح؟ الحقيقة هذا الكلام إحنا بنشوفه لما
+
+503
+00:47:36,130 --> 00:47:41,830
+بندرس ال acidity لالكحولات والميه وغيرها وغيراتها
+
+504
+00:47:41,830 --> 00:47:48,660
+إذا بتطلعواتقريبا ال PKA اللي هي التعبير عن
+
+505
+00:47:48,660 --> 00:47:58,100
+الحمضية وال PKA كل ما قلت الحمضية
+
+506
+00:47:58,100 --> 00:48:07,800
+ايش بيصير منها؟ بتزيد عندكوا
+
+507
+00:48:07,800 --> 00:48:14,920
+قاعد أخدتوا .. لما أخدتوا ال PKA و PKAتذكروها كل
+
+508
+00:48:14,920 --> 00:48:22,200
+ما الـKa زادت الحمضية بتزيد وكل ما الـPka قلت
+
+509
+00:48:22,200 --> 00:48:29,620
+الحمضية بتزيد إذا بنجيب نتطلع للميه والميثانون
+
+510
+00:48:29,620 --> 00:48:36,000
+والإيثانون وتقريباً لبيوتانون أو الـtetrabutanol
+
+511
+00:48:36,000 --> 00:48:42,080
+لاحظوا الـPka في كل هدول المركبات إيش مالها؟ عارية
+
+512
+00:48:43,050 --> 00:48:47,690
+الـ PKA عالية كثير إذا هدولة كلهم عبارة عن weak
+
+513
+00:48:47,690 --> 00:48:54,510
+acids أحماض ضعيفة عليهم شحنة الـ Oxygen اللي بدأ
+
+514
+00:48:54,510 --> 00:49:00,430
+تحمل الشحنة صغيرة لا تستطيع أن تحمل شحنة مش ال
+
+515
+00:49:00,430 --> 00:49:05,810
+Oxygen ذرة صغيرة مابتقدرش تحمل شحنة إذا كل هدولة
+
+516
+00:49:05,810 --> 00:49:12,990
+يعتبروا أحماضلأنه مافيش إمكانية لحمل الشحنة وقد
+
+517
+00:49:12,990 --> 00:49:17,830
+استغربوا أن حمضية الميه تقريبا زي حمضية الإيثانول
+
+518
+00:49:23,920 --> 00:49:28,060
+15 9 من 10 إذا الإيثانول مش حامض زيه زي الميّه
+
+519
+00:49:28,060 --> 00:49:32,220
+الدليل ع هيك لو اشتغلتوا في المستقبل بالتحاليل
+
+520
+00:49:32,220 --> 00:49:35,880
+الطبية وعملتوا مزرعة بكتيريا أو ما إلى ذلك بعد ما
+
+521
+00:49:35,880 --> 00:49:39,080
+تخلصوا عشان تقتلوا الجراثيم بتغسلوا بإيش
+
+522
+00:49:39,080 --> 00:49:42,260
+بالإيثانول بالإيثانول
+
+523
+00:49:43,720 --> 00:49:47,160
+بنغسل عادي بالإيثانول وبعده بالمية والصابونة لأن
+
+524
+00:49:47,160 --> 00:49:50,200
+الإيثانول هو اللي بيقتل الجرافيب، الآن هل لما أنا
+
+525
+00:49:50,200 --> 00:49:55,540
+بغسل بالكحول الإيثانول إيديا بيتقرح وما إلا، بقدر
+
+526
+00:49:55,540 --> 00:50:01,200
+أغسل بالـ HCL؟ مستحيل، لكن بقدر أغسل بالإيثانول؟
+
+527
+00:50:01,200 --> 00:50:07,280
+أه، حمضية الإيثانول زي حمضية الميةعشان هيك اللي
+
+528
+00:50:07,280 --> 00:50:10,860
+بيشتغل في مختبر تحاليل طبية أول .. جابل ما .. بعد
+
+529
+00:50:10,860 --> 00:50:13,760
+ما يخلص أي تحاليل و جابل ما يروح كمان مرة لازم
+
+530
+00:50:13,760 --> 00:50:18,060
+يغسل كل إيديه بالإيثانول و كأنه بيغسل بميه ما
+
+531
+00:50:18,060 --> 00:50:21,940
+بيصيرش لها عنده حرق ولا إشي يوميا بيغسل بالإيثانول
+
+532
+00:50:21,940 --> 00:50:28,750
+لأن حامضية الإيثانول زي حامضية إيش؟ الميهأحنا لسه
+
+533
+00:50:28,750 --> 00:50:32,730
+خلّينا نقول في أول الموضوع، اليوم المحاضرة خلصت،
+
+534
+00:50:32,730 --> 00:50:36,030
+لكن الموضوع الحمضية كبير، اللي صرنا ماخدينه أنه
+
+535
+00:50:36,030 --> 00:50:40,410
+اتذكرنا شوية معلومات عن الحمضية وقلنا أنه الميه
+
+536
+00:50:40,410 --> 00:50:45,830
+والميثانول والإيثانول كلهم عبارة عن weak acids،
+
+537
+00:50:45,830 --> 00:50:49,630
+very weak acids كمان، وبنغسل وجوهنا فيهم وإيدينا
+
+538
+00:50:49,630 --> 00:50:55,110
+ولا بنحرج ولا إشيمصبوط ولا لا؟ بعد هيك هنتوسع في
+
+539
+00:50:55,110 --> 00:50:57,990
+الموضوع يعني يمكن بدنا في ال acidity كمان نص ساعة
+
+540
+00:50:57,990 --> 00:51:00,590
+ان شاء الله في المحاضرة القادمة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..41ff08d4fe01498ddb46a9f74b870f31a4595ab3
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_postprocess.srt
@@ -0,0 +1,2252 @@
+1
+00:00:08,820 --> 00:00:14,060
+إذا بتسمحوا أخر
+
+2
+00:00:14,060 --> 00:00:19,200
+نقطة المرة الماضية اتكلمنا عنها كانت إضافة الماء
+
+3
+00:00:19,200 --> 00:00:24,140
+للالكينز وقولنا إنه في عدة طرق من خلالها بتتم
+
+4
+00:00:24,140 --> 00:00:28,510
+عملية إضافة الماء، الطريقة الأولىإضافة الماء في
+
+5
+00:00:28,510 --> 00:00:34,170
+وجود حامض اللي سمناه احنا acid-catalyzed hydration
+
+6
+00:00:34,170 --> 00:00:38,910
+of alkenes إذا بنذكر في الكلام اللي حكيناه قولنا
+
+7
+00:00:38,910 --> 00:00:44,030
+وظيفة الحامض أنه يبدأ التفاعل الحامض اللي بيعطينا
+
+8
+00:00:44,030 --> 00:00:48,290
+الـ H plus وظيفته أنه يبدأ التفاعل بتتحرك ال
+
+9
+00:00:48,290 --> 00:00:54,390
+double bond بهذا الشكل بتضيف هنا بتترك عندنا
+
+10
+00:00:54,390 --> 00:00:58,970
+Carbocation موجببتترك انه كاربو كاتاين موجب،
+
+11
+00:00:58,970 --> 00:01:03,310
+الكاربو كاتاين الموجب هذا بعد هيك بتضيف عليه الميه
+
+12
+00:01:03,310 --> 00:01:08,010
+و بتفقد بروتون فبصير في المحصل عالي إضافة هيدروجين
+
+13
+00:01:08,010 --> 00:01:15,430
+OH واضح؟ إذا المحصل هي إضافة إيش؟ماء المحص لإضافة
+
+14
+00:01:15,430 --> 00:01:19,830
+ماء كان التساؤل .. كان التساؤل أنه أنا في عندى
+
+15
+00:01:19,830 --> 00:01:23,510
+احتمالين لحركة ال double bond يعني كان ممكن ال
+
+16
+00:01:23,510 --> 00:01:27,050
+double bond تتحرك بهذا الشكل و تعمل carbocation
+
+17
+00:01:27,050 --> 00:01:30,530
+على هذه الكربونة أو تتحرك بهذا الشكل و تعمل
+
+18
+00:01:30,530 --> 00:01:35,110
+carbocation على هذه الكربونة واضح السؤال ليش
+
+19
+00:01:35,110 --> 00:01:40,670
+بتتحرك باتجاه معين مش بالاتجاه الثانيالان إذا هذا
+
+20
+00:01:40,670 --> 00:01:45,910
+الكلام بدنا نأكده خلينا نقول ال .. نوضح الاحتمالين
+
+21
+00:01:45,910 --> 00:01:50,410
+هدول بالظبط لما نيجي نتخيل أنه عندنا هذا الألكيد و
+
+22
+00:01:50,410 --> 00:01:53,870
+بدنا نضيف عليه H plus هذا ال H plus اللي اللون
+
+23
+00:01:53,870 --> 00:01:59,250
+أحمر من وين جاية؟ جاية من الحامض ال H plus هذه
+
+24
+00:01:59,250 --> 00:02:04,690
+ممكن تضيف على هذا الطرف و بالتالي تعمل أيون كربون
+
+25
+00:02:04,690 --> 00:02:10,220
+موجب على أي كربون؟ على الكربون الأولىو ممكن تضيف
+
+26
+00:02:10,220 --> 00:02:14,800
+على هذا الطرف وبالتالي تعمل ايون كربون موجب على
+
+27
+00:02:14,800 --> 00:02:19,520
+هذا الكربون واضح هاي الاحتمالين انه كأنه هذه
+
+28
+00:02:19,520 --> 00:02:25,500
+اتحركت بهذا الشكل او هذه اتحركت بهذا الشكل الآن
+
+29
+00:02:25,500 --> 00:02:30,380
+اذا بنيجي بنطلع احنا على ايون الكربون اللي اتكون
+
+30
+00:02:30,380 --> 00:02:36,380
+لاحظوا هنا هذه الكربون متصلة بكم كربونمتصلة ب اتش
+
+31
+00:02:36,380 --> 00:02:41,000
+و اتش و بكربون واحدة بناء على ذلك بنسمي ايون
+
+32
+00:02:41,000 --> 00:02:46,420
+الكربون تبعها ال primary carbocation يعني ايون
+
+33
+00:02:46,420 --> 00:02:53,360
+كربون موجب اول يعني متصل بكم كربون بواحدة الآن لو
+
+34
+00:02:53,360 --> 00:02:57,500
+صار عند الشغل التاني هذه الكربون اللي هنا اللي
+
+35
+00:02:57,500 --> 00:03:00,620
+بتحمل ال positive charge متصلة بكم كربون
+
+36
+00:03:03,650 --> 00:03:07,990
+بناء على ذلك هذا الكاربو كتايون بيكون اسمه
+
+37
+00:03:07,990 --> 00:03:12,310
+secondary carbocation، واضح؟ إذا الايون الموجب
+
+38
+00:03:12,310 --> 00:03:16,850
+ممكن يكون primary يعني الكاربون متصلة بكاربون
+
+39
+00:03:16,850 --> 00:03:21,030
+واحدة، ممكن يكون secondary يعني الكاربون متصلة
+
+40
+00:03:21,030 --> 00:03:27,010
+بكاربون واحدةالان بعد هيك بتيجي الميه تضيف إذا كان
+
+41
+00:03:27,010 --> 00:03:31,590
+ال positive موجود عندنا هنا بدي أضيف الميه و تفقد
+
+42
+00:03:31,590 --> 00:03:36,870
+H plus بصير عندي OH ملاحظين انتوا؟ لاحظوا في إضافة
+
+43
+00:03:36,870 --> 00:03:41,370
+الميه، طلعوا على الألوان كويس ال H من وين إجت؟ من
+
+44
+00:03:41,370 --> 00:03:46,770
+الحامض ال OH من وين إجت؟ من الميه فال H OH ما إجتش
+
+45
+00:03:46,770 --> 00:03:51,690
+من الميهالـ H إجت من الحمض والـ OH إجت من الميض لو
+
+46
+00:03:51,690 --> 00:03:56,230
+هذا التفاعل بده يكمل هنا بده يجي محل ال positive
+
+47
+00:03:56,230 --> 00:04:00,770
+في نهاية OH و تطلع H plus اللي بتخلي سلسلة التفاعل
+
+48
+00:04:00,770 --> 00:04:06,070
+تستمر الواقع اللي بيصير أن هذا الناتج لا يتكون
+
+49
+00:04:07,280 --> 00:04:10,820
+واضح؟ الناتج اللى بيمر من خلال ال primary
+
+50
+00:04:10,820 --> 00:04:14,540
+carbocation بتكونش بتكون الناتج اللى بيمر من خلال
+
+51
+00:04:14,540 --> 00:04:19,340
+ال secondary carbocation هنا بتكونوا تلاحظوا نقطة
+
+52
+00:04:19,340 --> 00:04:26,610
+كتير مهمة ان هذا التفاعل كام خطوةخطوتين أساسيتين
+
+53
+00:04:26,610 --> 00:04:29,690
+الخطوة الأولى إضافة لبروتون الخطوة الأولى التانية
+
+54
+00:04:29,690 --> 00:04:36,150
+أكمل التفاعل أي خطوة هي اللي بتتحمل أو يعني مسئولة
+
+55
+00:04:36,150 --> 00:04:42,340
+عن تحديدوين تيجي ال H وين تيجي ال OH هل هي الخطوة
+
+56
+00:04:42,340 --> 00:04:45,900
+الأولى ولا الخطوة التانية الخطوة الأولى لأن الخطوة
+
+57
+00:04:45,900 --> 00:04:50,260
+الأولى فيها اختيار يعني هنا ال H plus واقفة في
+
+58
+00:04:50,260 --> 00:04:53,420
+عنده احتمالين اما هذا الاحتمال او هذا الاحتمال
+
+59
+00:04:53,420 --> 00:04:57,520
+مظبوط ولا لا لكن لو صار هذا الاحتمال ال H two أولى
+
+60
+00:04:57,520 --> 00:05:01,350
+مامده تيجيفيش هنا غير احتمال واحد، غير مكان واحد
+
+61
+00:05:01,350 --> 00:05:05,570
+هنا تيجي عليه، واضح؟ فاللي بيتحكم في التفاعل من
+
+62
+00:05:05,570 --> 00:05:13,170
+ناحية وين موضع الإضافة هو حقيقة الخطوة الأولى مش
+
+63
+00:05:13,170 --> 00:05:18,190
+الخطوة الثانية، الخطوة التانية ملزمة، تحصيل حاصل،
+
+64
+00:05:18,190 --> 00:05:21,830
+واضح؟ تماما هذا الكلام لو بدى .. يعني أعمللكوا
+
+65
+00:05:21,830 --> 00:05:26,050
+تشبيه عشان تفهموه لو افترضنا مثلا انه في طالبات
+
+66
+00:05:26,050 --> 00:05:30,910
+مغتربات إيجوا بدهم يسكنوافي سكن طالبة تسكن غرفتين
+
+67
+00:05:30,910 --> 00:05:37,790
+واضح؟ إجت أول طالبة وصلت السكن الساعة سبعة الصبح و
+
+68
+00:05:37,790 --> 00:05:41,690
+بدها تحط أغراضها في غرفة الآن هي عندها غرفتين هي
+
+69
+00:05:41,690 --> 00:05:45,890
+بتختار ولا لأ؟ هي بتختار عندها احتمال تحط هنا أو
+
+70
+00:05:45,890 --> 00:05:50,650
+تحط هنا حطت أغراضها في هذه الغرفة الساعة عشرة إجت
+
+71
+00:05:50,650 --> 00:05:56,640
+زملتهافي عند اختيار لجت المكان الأول مشغول فأصبحت
+
+72
+00:05:56,640 --> 00:05:59,340
+ملزمة بالمكان الثاني فعملية الاختيار شو اللي
+
+73
+00:05:59,340 --> 00:06:03,230
+بيحكمها؟الخطوة الأولى مش الخطوة الثانية الآن
+
+74
+00:06:03,230 --> 00:06:08,410
+بيضلوا السؤال قائم ليش في الخطوة الأولى الهيدروج
+
+75
+00:06:08,410 --> 00:06:13,670
+الفضل ييجي هنا وبالتالي يعمل secondary carbocation
+
+76
+00:06:13,670 --> 00:06:18,330
+من إنه ييجي هنا ويعمل primary carbocation هذا
+
+77
+00:06:18,330 --> 00:06:21,850
+الكلام متعلق في إيش بنسميه ال stability of
+
+78
+00:06:21,850 --> 00:06:26,010
+carbocation ثبات ال carbocation واضح؟
+
+79
+00:06:28,220 --> 00:06:31,860
+ثبات الكربوكاتيون بالشكل اللى موجود عندنا فوق
+
+80
+00:06:31,860 --> 00:06:37,160
+التيرتشاري كربوكاتيون اللى متصل بتلت كربونات بيكون
+
+81
+00:06:37,160 --> 00:06:42,660
+أثبت من ال secondary أثبت من ال primary أثبت من ال
+
+82
+00:06:42,660 --> 00:06:46,100
+CH3 اللى مش متصل ولا بكربونات المثل كربوكاتيون
+
+83
+00:06:46,100 --> 00:06:50,300
+واضح؟ اذا the stability of kerbocation's tertiary
+
+84
+00:06:50,300 --> 00:06:52,620
+is more stable than the secondary is more stable
+
+85
+00:06:52,620 --> 00:06:58,520
+than the primary ممكن واحد تسأل ليش؟واضح؟ هذه
+
+86
+00:06:58,520 --> 00:07:02,300
+النتيجة انه احنا علميا بنقول ال tertiary
+
+87
+00:07:02,300 --> 00:07:06,740
+carbocation أثبت من ال secondary و ال secondary
+
+88
+00:07:06,740 --> 00:07:12,240
+أثبت من ال primary و الاشي الثابت هو اللي ايش؟ هو
+
+89
+00:07:12,240 --> 00:07:16,880
+اللي بيتكون صارت الشغل سهل لكن ليش ال tertiary
+
+90
+00:07:16,880 --> 00:07:20,700
+أثبت من ال secondary و ال secondary أثبت من ال
+
+91
+00:07:20,700 --> 00:07:25,680
+primary؟ واضح السؤال؟ ثبات الشحنة دائما يكون
+
+92
+00:07:25,680 --> 00:07:26,680
+بتقليلها
+
+93
+00:07:31,890 --> 00:07:39,930
+أي شحنة بدنا نثبتها لازم تكون قليلة إذا زادت
+
+94
+00:07:39,930 --> 00:07:47,710
+الشحنةقل الثبات، وإذا قلت الشحنة زاد الثبات، واضح؟
+
+95
+00:07:47,710 --> 00:07:52,470
+هذا الكلام قاعدة عامة حتى لو كنتوا يعني بدكم تحكوا
+
+96
+00:07:52,470 --> 00:07:56,170
+في موضوع الغضب، اعتبروا الغضب شحنة، اعتبروا الغضب
+
+97
+00:07:56,170 --> 00:07:59,890
+شحنة، الآن اللي عنده شحنة عالية من الغضب، بيكون
+
+98
+00:07:59,890 --> 00:08:04,200
+ثابت ولا بيقاتل في حاله؟بكون مش ثابت .. unstable
+
+99
+00:08:04,200 --> 00:08:08,480
+.. واضح .. حتى لما بيروح بيتعالج .. إيش بيسووا؟
+
+100
+00:08:08,480 --> 00:08:11,860
+بيقللوا الشحنة اللي عنده .. البني آدم اللي بيقولوا
+
+101
+00:08:11,860 --> 00:08:15,300
+بتزيد عنده الكهربا .. بتشوفوا كيف بعض الناس عندهم
+
+102
+00:08:15,300 --> 00:08:18,720
+مشكلة .. زيادة الكهربا .. هذه زيادة الشحنة بتعمل
+
+103
+00:08:18,720 --> 00:08:22,980
+ثابت ولا عدم ثابت؟ بتعمل عدم ثابت .. وقت إيش بيصير
+
+104
+00:08:22,980 --> 00:08:29,520
+الثابت؟إذا قلت الشحنة .. إذا قلت الشحنة .. واضح
+
+105
+00:08:29,520 --> 00:08:33,700
+كيف؟ عشان يك .. حتى البني آدم .. حتى البني آدم لو
+
+106
+00:08:33,700 --> 00:08:39,420
+عنده شحنة حزن مثلا .. أي شخص كان عنده مناسبة توفى
+
+107
+00:08:39,420 --> 00:08:43,260
+قريب أو عزيزه .. صار عنده شحنة كبيرة من الحزن ..
+
+108
+00:08:43,260 --> 00:08:48,240
+إيش الناس بيعملوا؟بيجوا بعزوه لما بيجوا بعزوه إيش
+
+109
+00:08:48,240 --> 00:08:52,740
+بيسووا؟ كأنه هذا أخد منه شوية حزن و هذا أخد شوية و
+
+110
+00:08:52,740 --> 00:08:56,320
+هذا أخد شوية و هذا أخد شوية واضح أو اللي عنده
+
+111
+00:08:56,320 --> 00:09:01,240
+مصيبة كبيرة مثلا نفترض داره انهدت بالحرب بيجي هذا
+
+112
+00:09:01,240 --> 00:09:05,700
+بيجيبله مساعدة هذا بيعمله هذا بيعمله فإيش بيصير
+
+113
+00:09:05,700 --> 00:09:10,680
+للشحنة اللي عنده؟ بتخلق الكلام نفسه بتكرر في ال
+
+114
+00:09:10,680 --> 00:09:17,100
+positive chargeال R group بتعطي إلكترونات لما أكون
+
+115
+00:09:17,100 --> 00:09:20,380
+عندي positive charge افترضوا هذا ال positive بس
+
+116
+00:09:20,380 --> 00:09:26,500
+كعدد عشوائي إنها عشر وحدات عشر وحدات هذه تمثل إيش
+
+117
+00:09:26,500 --> 00:09:31,680
+ثقل أو شحنة الآن لما تيجي ال R group ال R group
+
+118
+00:09:31,680 --> 00:09:38,500
+بتعطي إلكترونات يعني بتعطي إيشبتعطي سالب السالب شو
+
+119
+00:09:38,500 --> 00:09:42,680
+بيعمل في الموجة بيقلله يعني لو افترضت انه شحن
+
+120
+00:09:42,680 --> 00:09:46,500
+الموجة بعشر وحدات لجت اي اشي ساعده لما يكون عنده
+
+121
+00:09:46,500 --> 00:09:50,780
+تلت هيدروجينات لأ طيب لو افترضنا ان ال R group
+
+122
+00:09:50,780 --> 00:09:55,720
+بتعطي اتنين سالب وهذه عشرة موجة شو بتعمل ال R
+
+123
+00:09:55,720 --> 00:09:59,440
+group في الموجة في هذه الحالة؟بتعدل تنتين منه، كم
+
+124
+00:09:59,440 --> 00:10:03,160
+يصف الموجب؟ تمانية، إذا هنا الموجب قلت، هنا الشحنة
+
+125
+00:10:03,160 --> 00:10:09,680
+قلت طيب، لو كان عندي تنتين R-groups، إيش بيصي
+
+126
+00:10:09,680 --> 00:10:12,880
+لشحنة الموجب بقى؟ بتقل أكثر وأكثر، يعني لو افترضت
+
+127
+00:10:12,880 --> 00:10:17,340
+هذه عشرة، وهذه نقصت اتنين، عدلت اتنين، وهذه عدلت
+
+128
+00:10:17,340 --> 00:10:21,760
+اتنين، كم هيصف الموجب؟ ستة إذا، قاعد التباك بزيد،
+
+129
+00:10:21,760 --> 00:10:27,360
+لو افترضت هنا تلت مجموعات Rترضو هذه عشرة هذه بتعطي
+
+130
+00:10:27,360 --> 00:10:30,240
+اتنين سالب و اتنين سالب و اتنين سالب كده اش ضال
+
+131
+00:10:30,240 --> 00:10:35,320
+الموجب عنده اربع اذا الموجب عمله بقل كأن انا بقدر
+
+132
+00:10:35,320 --> 00:10:39,660
+اقول ان ال electron donating groups المجموعات
+
+133
+00:10:39,660 --> 00:10:44,020
+المعطية للالكترونات المعطية للشحنة السالبة ماذا
+
+134
+00:10:44,020 --> 00:10:46,960
+تفعل في شحنة الموجبة؟ decreases
+
+135
+00:11:02,800 --> 00:11:06,380
+معنى شحنة جلة شحنة صارت more stable
+
+136
+00:11:09,360 --> 00:11:14,660
+معنى إن هالشحنة جلت إنه شحنة صارت more stable إذا
+
+137
+00:11:14,660 --> 00:11:19,620
+اقدرنا نفهم إيش سبب هذا ل trend of stability إنه
+
+138
+00:11:19,620 --> 00:11:22,160
+ال tertiary is more stable than the secondary is
+
+139
+00:11:22,160 --> 00:11:25,800
+more stable than the primary because of the
+
+140
+00:11:25,800 --> 00:11:32,100
+presence of more electron donating groups بسبب
+
+141
+00:11:32,100 --> 00:11:37,600
+وجود مجموعات معطية للإلكترونات بتقللالـ positive
+
+142
+00:11:37,600 --> 00:11:43,640
+is charged واضح؟ الآن في عندي شغلة مهمة جدا ال
+
+143
+00:11:43,640 --> 00:11:46,500
+rate of formation of carbocation زي ما هي ال
+
+144
+00:11:46,500 --> 00:11:50,000
+stability of carbocation ال tertiary أفضل من
+
+145
+00:11:50,000 --> 00:11:53,120
+الsecondary أفضل من ال primary سرعة التكوين بتكون
+
+146
+00:11:53,120 --> 00:11:57,900
+حسب الثباتبرضه ال tertiary أفضل من ال secondary
+
+147
+00:11:57,900 --> 00:12:03,200
+أفضل من ال primary واضح هذا الكلام بناء على ذلك
+
+148
+00:12:03,200 --> 00:12:07,200
+بنقدر نفهم الكلام اللي في ال slide السابق ببساطة
+
+149
+00:12:07,200 --> 00:12:13,340
+ليش بتكون هذا مش هذا لأن هنا الكربوكاتيون primary
+
+150
+00:12:13,340 --> 00:12:17,880
+هنا الكربوكاتيون secondary the more stable
+
+151
+00:12:17,880 --> 00:12:22,890
+secondary كربوكاتيون will formالكاربوكاتيون اللى
+
+152
+00:12:22,890 --> 00:12:26,890
+هو more stable ال secondary بتكون الآن الخطوة اللى
+
+153
+00:12:26,890 --> 00:12:33,030
+بعيدها تحصل حاصل اكمل التفاعل لكن التفاعل وين
+
+154
+00:12:33,030 --> 00:12:38,290
+انحكم ال reaction is controlled by the first or by
+
+155
+00:12:38,290 --> 00:12:43,870
+the second step by the first step واضح التفاعل
+
+156
+00:12:43,870 --> 00:12:48,390
+بينحكم بالخطوة الأولى انه ايش اللى أثبت بتكون
+
+157
+00:12:50,880 --> 00:12:56,440
+Stability أو ثبات واضح؟ الآن لو في تفاعل تاني كنت
+
+158
+00:12:56,440 --> 00:13:01,020
+بعمل إضافة وعندي تنافس ما بين إمكانية tertiary
+
+159
+00:13:01,020 --> 00:13:06,140
+-carbocation وsecondary الهيدروجين بيضيف بحيث يكون
+
+160
+00:13:06,140 --> 00:13:10,500
+ال tertiary-carbocation مش ال secondary الهيدروجين
+
+161
+00:13:10,500 --> 00:13:16,450
+بيضيف بحيث يكون ال tertiary-carbocationهنا ابتدينا
+
+162
+00:13:16,450 --> 00:13:24,630
+شغلة إضافية والحقيقة جميلة جدا لو بدنا نطلع على
+
+163
+00:13:24,630 --> 00:13:28,710
+المثال هذا لو بدنا نطلع على المثال هذا عندكم CH2
+
+164
+00:13:28,710 --> 00:13:38,320
+CH وهنا CH3 CH3 لو قلنا بدنا نضيف H Plusزي ما
+
+165
+00:13:38,320 --> 00:13:42,000
+اتفقنا ال H plus ممكن تيجي على هذا الموقع تكون
+
+166
+00:13:42,000 --> 00:13:46,040
+لإيش؟ secondary carbocation أو تيجي على هذا الموقع
+
+167
+00:13:46,040 --> 00:13:49,600
+تكون primary carbocation وبعد هيك ال reaction
+
+168
+00:13:49,600 --> 00:13:54,840
+يكتمل، الآن من أول لحظة secondary ولا primary؟
+
+169
+00:13:54,840 --> 00:13:59,630
+secondary، إذا هذا الاحتمال ألغىاللي بتكون عندى ال
+
+170
+00:13:59,630 --> 00:14:04,590
+secondary لاحظوا هنا ال secondary هتلاحظوا فيه
+
+171
+00:14:04,590 --> 00:14:11,230
+jumbo carbon حاملة CH3 و CH3OH بيصير عندى شغل جديد
+
+172
+00:14:11,230 --> 00:14:16,230
+ان ال secondary نفسه قبل ما يكمل التفاعل ممكن
+
+173
+00:14:16,230 --> 00:14:23,350
+يتحول إلى tertiaryإذا هو يتجه إلى مزيد من الثبات
+
+174
+00:14:23,350 --> 00:14:26,750
+يعني لما مايصارش ال primary صار ال secondary هذا
+
+175
+00:14:26,750 --> 00:14:31,270
+توجه نحو إيش الثبات الآن ال secondary ممكن يتجه
+
+176
+00:14:31,270 --> 00:14:35,230
+إلى مزيد من الثبات كيف كيف ال secondary بتحول ل
+
+177
+00:14:35,230 --> 00:14:41,490
+tertiary بتيجي ال H مع زوج الإلكترونات تبعها ال H
+
+178
+00:14:41,490 --> 00:14:47,660
+مع زوج الإلكترونات تبعها بنسميها hydride ionلاحظوا
+
+179
+00:14:47,660 --> 00:14:54,300
+ال H بلس بدون إلكترونات شو اسمها بروتون انتبهوا
+
+180
+00:14:54,300 --> 00:15:00,400
+معايا ال H يبدأ تكون ذرة متعادلة يبدأ تكون موجبة
+
+181
+00:15:00,400 --> 00:15:06,220
+ال H كذرة متعادلة شو موجود فيها؟Electron واحد إذا
+
+182
+00:15:06,220 --> 00:15:11,620
+بدت تصير ال H تفقدها ال Electron شو بتصير؟ H plus
+
+183
+00:15:11,620 --> 00:15:16,620
+وإذا ال H بدت تكتسب Electron تصير عليها Electronين
+
+184
+00:15:16,620 --> 00:15:22,200
+شو بتصير؟ H minus واضح؟ إذا ال H بوضعها الطبيعي
+
+185
+00:15:22,200 --> 00:15:28,740
+كذرة عليهايابتفقد هذا ال electron بتصير H بلس،
+
+186
+00:15:28,740 --> 00:15:34,980
+يابتكون مكتسبة فوقه كمان electron بتصير H مينوس ال
+
+187
+00:15:34,980 --> 00:15:40,640
+H بلس اسمها بروتون لأنه
+
+188
+00:15:40,640 --> 00:15:46,140
+خلاص دل عندي موجب و electron، راح ال electron، شو
+
+189
+00:15:46,140 --> 00:15:51,200
+دل؟الموجة بظل لبروتون فال H بلس اسمها بروتون ال H
+
+190
+00:15:51,200 --> 00:15:56,260
+ماينوس شو اسمها هيدرايد ايون شفتوا الفرق بين
+
+191
+00:15:56,260 --> 00:15:57,960
+الهيدرايد ايون و البروتون
+
+192
+00:16:05,370 --> 00:16:08,730
+الخطوة الأولى عندما يضيف من الحامض ماذا يضيف عنده
+
+193
+00:16:08,730 --> 00:16:15,330
+؟ H بلس بروتون بروتون اللي بضيف عنده هنا بصير
+
+194
+00:16:15,330 --> 00:16:26,560
+انتقال أو shiftلـ H- الهيدرايد انايون الهيدرايد
+
+195
+00:16:26,560 --> 00:16:33,320
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+196
+00:16:33,320 --> 00:16:35,120
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+197
+00:16:35,120 --> 00:16:35,780
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+198
+00:16:35,780 --> 00:16:36,000
+انايون الهيدرايد انايون الهيدرايد انايون الهيدرايد
+
+199
+00:16:36,000 --> 00:16:43,960
+انايون الهيدرايد انايون الهيدIon موجة positive
+
+200
+00:16:43,960 --> 00:16:48,000
+اتطلعوا الآن على هذا ال ion الموجة اللي تركته
+
+201
+00:16:48,000 --> 00:16:53,260
+مكانها هل يتورا secondary ولا tertiary؟ لاحظوا
+
+202
+00:16:53,260 --> 00:17:00,200
+carbon تنتين تلاتةصار تيرتشاري هذه العملية بنسميها
+
+203
+00:17:00,200 --> 00:17:05,540
+rearrangement أو إعادة ترتيب Rearrangement إن الـ
+
+204
+00:17:05,540 --> 00:17:10,760
+H بتنتقل أو الهيدرايد أنايون بنتقل بحيث يحولني إذا
+
+205
+00:17:10,760 --> 00:17:14,260
+في إمكانية في التفاعل زي هذا المثال ال secondary
+
+206
+00:17:14,260 --> 00:17:20,200
+carbocation إلى tertiary carbocation بعد هيك لما
+
+207
+00:17:20,200 --> 00:17:24,710
+بتيجي المياه تضيف، بتضيف مكانالموجة في مكان ال
+
+208
+00:17:24,710 --> 00:17:30,150
+tertiary تحط OH لاحظوا هنا ال H اللي ضفناها وين
+
+209
+00:17:30,150 --> 00:17:36,360
+إجت؟ على موقع واحد ال OH اللي من الميهع موقع تلاتة
+
+210
+00:17:36,360 --> 00:17:40,820
+ملاحظين يعني بدل ما تيجي ال H هنا و ال O H هنا
+
+211
+00:17:40,820 --> 00:17:45,400
+بتلاحظوا أن ال O H نجلة موقعها هذه عملية ال
+
+212
+00:17:45,400 --> 00:17:49,140
+rearrangement أو إعادة الترتيب اللي موجودة في
+
+213
+00:17:49,140 --> 00:17:53,820
+الجزء ليش تم تقول هذه العملية عملية إعادة الترتيب؟
+
+214
+00:17:53,820 --> 00:18:00,540
+عشان أنتقل من السكندري كاربو كاتايون إلىالـ
+
+215
+00:18:00,540 --> 00:18:03,700
+tertiary carbocation عشان ننتقل من
+
+216
+00:18:03,700 --> 00:18:08,160
+السكندريكاربوكاتيون الى التيرتشاريكاربوكاتيون بتم
+
+217
+00:18:08,160 --> 00:18:12,340
+هنا rearrangement من خلال عملية إيش بنسميها؟
+
+218
+00:18:12,340 --> 00:18:18,260
+Hydride shift يعني تحرك هيدروجين مع إلكتروناته
+
+219
+00:18:18,260 --> 00:18:23,920
+كلام منطقي ليش؟ لأن هذا موجب الموجب إيش بيكون بده؟
+
+220
+00:18:23,920 --> 00:18:29,400
+بده سالب إيش السالب؟الهيدروجين و إلكتروناته هما
+
+221
+00:18:29,400 --> 00:18:34,240
+السالب هما الانيون الهيدروجين مع الإلكترونات تبعته
+
+222
+00:18:38,050 --> 00:18:42,330
+من مميزات الـ Acid Catalyzed Addition of Water أنه
+
+223
+00:18:42,330 --> 00:18:45,910
+في إمكانية طالما بتكون عندي Carbocation في إمكانية
+
+224
+00:18:45,910 --> 00:18:49,530
+لل rearrangement معنى إمكانية ال rearrangement أنه
+
+225
+00:18:49,530 --> 00:18:54,390
+ممكن ال secondary يصير أحيانا في أمثلة معينة فيها
+
+226
+00:18:54,390 --> 00:18:58,910
+primary برضه ممكن يتحول إلى tertiary واضح؟ هنا
+
+227
+00:18:58,910 --> 00:19:04,450
+عملية ال rearrangement تمت من خلال إيش؟الحقيقة
+
+228
+00:19:04,450 --> 00:19:08,810
+اللى لاحظوا انه مش بس من خلال ال hydride shift
+
+229
+00:19:08,810 --> 00:19:12,330
+يعني لو انه بدل ما عندى هنا hydrogen خلتها دول
+
+230
+00:19:12,330 --> 00:19:16,690
+تلاتة methyls لاحظوا المثال السابق هدى إيش كانت؟
+
+231
+00:19:17,340 --> 00:19:22,460
+أتش خلّيتهم تلاتة مثلًا لو الآن بدأ أضيف H بلاص زي
+
+232
+00:19:22,460 --> 00:19:25,720
+ما اتفقنا يا بنضيفها هنا بنكون primary يا بنضيفها
+
+233
+00:19:25,720 --> 00:19:30,420
+هنا بنكون secondary أن هو الاحتمال الملغي ال
+
+234
+00:19:30,420 --> 00:19:35,700
+primary بيظل عنده ال secondary الآن بالإمكان تتحرك
+
+235
+00:19:35,700 --> 00:19:42,940
+مجموعة CH3 كاملة مع إلكتروناتها كل CH3 تنتقل هذه
+
+236
+00:19:42,940 --> 00:19:48,000
+بنسميها إيش إحنا ال kill shiftلما كانت H مع
+
+237
+00:19:48,000 --> 00:19:53,160
+إلكتروناتها هيدرايتشفت لما تكون CH3 مع إلكتروناتها
+
+238
+00:19:53,160 --> 00:19:58,800
+الكلشفت واضح؟ ممكن يصير عنده الكلشفت تنتقل كل ال
+
+239
+00:19:58,800 --> 00:20:01,700
+CH3 هان لحظة الجزء كله بتغير و ال positive وين
+
+240
+00:20:01,700 --> 00:20:06,080
+بيصير؟ هان عشان هذا تيرتشاريكاربوكاتيون بعدين لما
+
+241
+00:20:06,080 --> 00:20:10,690
+الميه بتضيف تحط OH وين بتحطها؟عادة الموقع، لاحظوا
+
+242
+00:20:10,690 --> 00:20:14,010
+كده إعادة الترتيب اللي صارت في الجزيرة، إن الـH
+
+243
+00:20:14,010 --> 00:20:19,210
+إجت هنا كويس، الـOH ماجتش جنبها، انتقلت الـCH3
+
+244
+00:20:19,210 --> 00:20:22,070
+والـOH إجت على الموقع اللي بعدها، هذه عملية
+
+245
+00:20:22,070 --> 00:20:24,830
+rearrangement، هنا ال rearrangement from the
+
+246
+00:20:24,830 --> 00:20:28,550
+secondary كربوكاتيون to the tertiary كربوكاتيون is
+
+247
+00:20:28,550 --> 00:20:35,220
+through ال kill shift، واضح؟ففي ميزة دائما في ال
+
+248
+00:20:35,220 --> 00:20:38,680
+carbocations بزام الكربوكاتيونز بتسعى لل stability
+
+249
+00:20:38,680 --> 00:20:44,300
+إذا في إمكانية لإيش لل rearrangement واضح؟ هذا عمر
+
+250
+00:20:44,300 --> 00:20:49,500
+بسيط يعني تماما تماما اتخيلوه بشكل الآتي ممكن يكون
+
+251
+00:20:49,500 --> 00:20:52,720
+عندكوا إحساس أن أفضل ناس عندهم ثبات و بيشوفوا كويس
+
+252
+00:20:52,720 --> 00:20:56,620
+اللي قاعدين هنا واضح؟ لو افترضنا أن الأخت اللي هنا
+
+253
+00:20:56,620 --> 00:21:03,660
+طلعت، شو بيصير؟بتناجح عملية ال rearrangement إذا
+
+254
+00:21:03,660 --> 00:21:08,020
+الناس دايما بتسعى نحوها مزيد من الثبات ولا لأ تسعى
+
+255
+00:21:08,020 --> 00:21:14,460
+نحوها مزيد من الثبات الآن
+
+256
+00:21:14,460 --> 00:21:20,900
+بنجي لطريقة تانية غير إضافة الماء في وجود الحامض
+
+257
+00:21:20,900 --> 00:21:28,360
+في طريقة إضافة الماء في وجود الحامضالزقبق وتحديدا
+
+258
+00:21:28,360 --> 00:21:32,700
+المركب اللي احنا بنستعمله اللي اسمه ال mercuryic
+
+259
+00:21:32,700 --> 00:21:37,020
+acetate mercuryic acetate يعني mercuryic acetate
+
+260
+00:21:37,020 --> 00:21:42,480
+اللي بنسميه احنا ايش خلات الزقبق ال acetic acid
+
+261
+00:21:42,480 --> 00:21:48,540
+حمضالخل .. حمض الخل و ال mercury acetate خلات
+
+262
+00:21:48,540 --> 00:21:53,700
+الزبا .. الآن إذا كان في عندي double bond .. إذا
+
+263
+00:21:53,700 --> 00:21:58,270
+كان في عندي double bondضيفت عليها على خطوتين
+
+264
+00:21:58,270 --> 00:22:03,110
+متتاليتين الخطوة الأولى ميركوريك أسيتيت في وجود
+
+265
+00:22:03,110 --> 00:22:07,190
+الميه دايب في الميه الخطوة التانية مركّب بنسميه
+
+266
+00:22:07,190 --> 00:22:11,510
+sodium borohydride هدولة مع بعض بقالية معينة مش
+
+267
+00:22:11,510 --> 00:22:15,930
+هنتطرق لها حتى ما نتوسعش كتير بضيفوا ميه يعني
+
+268
+00:22:15,930 --> 00:22:21,730
+محصلة هذا ال reagent كله هي عملية إضافة إيش إضافة
+
+269
+00:22:21,730 --> 00:22:27,790
+ميه الآن الميه هنا كيف بتضيفبتضيف حسب قاعدة
+
+270
+00:22:27,790 --> 00:22:34,430
+Markovnikov زي ما الحامض كان يعمل بمعنى على هذا
+
+271
+00:22:34,430 --> 00:22:40,410
+الموقع شو بده يجيني H ولا OH؟ وع هذا الموقع OH ليش
+
+272
+00:22:40,410 --> 00:22:43,350
+هنا بيجيني ال H؟ إذا بتلاحظوا هنا كام هيدروجين
+
+273
+00:22:43,350 --> 00:22:50,070
+عندى؟ في الأساس10-10 هنا كم هيدروجين عندى؟ واحدة
+
+274
+00:22:50,070 --> 00:22:53,570
+احنا المرة الماضية قولنا انه في الإضافة في وجود
+
+275
+00:22:53,570 --> 00:22:58,010
+الحامض و ايضا في وجود ال mercury acetate بتمشي على
+
+276
+00:22:58,010 --> 00:23:02,230
+حسب قاعدة ماركوفنيكوف انه الهيدروجين بتيجي على اي
+
+277
+00:23:02,230 --> 00:23:07,590
+كاربون على حاملة هيدروجين اكتر بلاحظين انتوا بناء
+
+278
+00:23:07,590 --> 00:23:12,150
+على ذلك الهيدروجين بتضيف هنا و ال OH بتضيف على هذا
+
+279
+00:23:12,150 --> 00:23:17,900
+الموقعممكن الآن واحدة تسأل طب إيش هدى بتختلف عن
+
+280
+00:23:17,900 --> 00:23:24,220
+الإضافة في وجود الحامض؟
+
+281
+00:23:24,220 --> 00:23:28,560
+واضح الكلام؟ الإضافة في وجود الحامض Markovnikov
+
+282
+00:23:28,560 --> 00:23:34,620
+addition والإضافة في وجود الذئبق برضه Markovnikov
+
+283
+00:23:34,620 --> 00:23:40,590
+addition طب إيش ده بتفرق؟بتفرق أن الإضافة في وجود
+
+284
+00:23:40,590 --> 00:23:46,050
+الذئبق لا يحصل فيها rearrangement،
+
+285
+00:23:46,050 --> 00:23:49,890
+الإضافة في وجود الذئبق ما بيصيرش فيها
+
+286
+00:23:49,890 --> 00:23:53,130
+rearrangement، بتضيف على الطرفي الرابط الزوجية،
+
+287
+00:23:53,130 --> 00:23:57,170
+الإضافة في وجود الحامض قبل شوية، لاحظنا أن فيها
+
+288
+00:23:57,170 --> 00:24:03,090
+إيش؟ rearrangementبس في وجود الذئبق ما بيصيرش
+
+289
+00:24:03,090 --> 00:24:07,870
+rearrangement يعني لو رجعنا للمثال السابق اللي
+
+290
+00:24:07,870 --> 00:24:12,530
+عندنا هنا و بقولنا لكوا هاي هذا المثال بدنا نضيف H
+
+291
+00:24:12,530 --> 00:24:18,650
+plus H to O اعطونا الناتج شو هتعطونا هتعطونا ان ال
+
+292
+00:24:18,650 --> 00:24:22,590
+H بيضيف هنا secondary carbocation بيصير tertiary
+
+293
+00:24:22,590 --> 00:24:27,130
+ال O H بيضيف هنا هاي الناتج طيب لو كنت حاططركم ال
+
+294
+00:24:27,130 --> 00:24:32,560
+reagent هنا مش H plusزئبق ميركوريك أسيتيت وميه و
+
+295
+00:24:32,560 --> 00:24:36,560
+بعدين صوديوم بورو هايدرايد شو النتج اللي هتعطونيه؟
+
+296
+00:24:36,560 --> 00:24:41,860
+بده يضيف ال H و ال OH على الطرفين الرابط بحيث ان
+
+297
+00:24:41,860 --> 00:24:45,020
+ال H تيجي على أكتر و ال OH هنا، بده يطلع هذا النتج
+
+298
+00:24:47,610 --> 00:24:51,410
+واضح؟ يعني لو ال reagent اللى عندى mercury acetate
+
+299
+00:24:51,410 --> 00:24:55,210
+بدي يطلع هذا النتج لو ال reagent اللى عندى H plus
+
+300
+00:24:55,210 --> 00:25:00,190
+H2O بدي يطلع هذا النتج شوفت وين الفرق ما بين
+
+301
+00:25:00,190 --> 00:25:06,490
+الشغلتين؟واضح هذا هو الفرق بين إضافة الميه في وجود
+
+302
+00:25:06,490 --> 00:25:09,990
+حامض إنه فيه إمكانية ل rearrangement إضافة الميه
+
+303
+00:25:09,990 --> 00:25:15,370
+في وجود الذئبق لأ بتضيف حسب Markovnikov rule بدون
+
+304
+00:25:15,370 --> 00:25:19,810
+عملية ال rearrangement عشانك حتى لو بترجع يمكن لل
+
+305
+00:25:19,810 --> 00:25:24,650
+slides لل slides بتلاحظوا في عندنا هنا كلمة إنه ال
+
+306
+00:25:24,650 --> 00:25:29,470
+addition Markovnikov regiochemistry is observedإن
+
+307
+00:25:29,470 --> 00:25:33,850
+الإضافة حسب قاعدة ماركوف نيكوف وهذا ال reaction
+
+308
+00:25:33,850 --> 00:25:40,870
+إيش ماله؟ Rearrangements do not occur إذا لو احنا
+
+309
+00:25:40,870 --> 00:25:47,770
+كنا بنسألكوا سؤال صح و غلط مثلا، بنقولكم in the
+
+310
+00:25:47,770 --> 00:25:52,070
+acid-catalyzed hydration of alkenes, rearrangement
+
+311
+00:25:52,070 --> 00:25:53,030
+is possible
+
+312
+00:25:55,370 --> 00:25:58,810
+صح في ال acid catalyzed addition rearrangement is
+
+313
+00:25:58,810 --> 00:26:02,970
+possible in oxymercuration طبعا هذا بنسمي
+
+314
+00:26:02,970 --> 00:26:06,190
+oxymercuration لأنه بضيف الزبق و ال oxygen اللي هي
+
+315
+00:26:06,190 --> 00:26:09,430
+إضافة من خلال الزبق in oxymercuration
+
+316
+00:26:09,430 --> 00:26:13,790
+rearrangement is possible rearrangement does not
+
+317
+00:26:13,790 --> 00:26:18,770
+occur in oxymercuration شفتوا الفرق بين الإضافتين
+
+318
+00:26:18,770 --> 00:26:25,230
+للميه؟الان هي هذا مثال لو قلنا لكوا بدنا نضيف عليه
+
+319
+00:26:25,230 --> 00:26:29,410
+ميركوريك أسيتات في وجود الميه وبعدين صوديوم بورو
+
+320
+00:26:29,410 --> 00:26:33,930
+هيدرايد الإضافة على الطرفين الرابطة لو أنتوا بدكوا
+
+321
+00:26:33,930 --> 00:26:36,970
+تحللوا المثال هتلاحظوا أن هنا في شغل مفقود هشوية
+
+322
+00:26:36,970 --> 00:26:43,170
+هادى الهيدروجين إذا اللي بده أرسمها هنا بالأحمر هي
+
+323
+00:26:43,170 --> 00:26:46,750
+اللي كانت موجودة أصلا إذا لما بده اضيف الميه اضيف
+
+324
+00:26:46,750 --> 00:26:52,610
+H و OH وين هتيجي ال H؟على هذه اللي حاملة هيدروجين
+
+325
+00:26:52,610 --> 00:26:56,610
+وين هتيجي ال OH؟ على هذه اللي حاملة هيدروجين وين
+
+326
+00:26:56,610 --> 00:26:56,730
+هتيجي ال OH؟ على هذه اللي حاملة هيدروجين وين هتيجي
+
+327
+00:26:56,730 --> 00:26:57,310
+ال OH؟ على هذه اللي حاملة هيدروجين وين هتيجي ال
+
+328
+00:26:57,310 --> 00:27:00,450
+OH؟ على هذه اللي حاملة هيدروجين وين هتيجي ال OH؟
+
+329
+00:27:00,450 --> 00:27:01,030
+على هذه اللي حاملة هيدروجين وين هتيجي ال OH؟ على
+
+330
+00:27:01,030 --> 00:27:04,130
+هذه اللي حاملة هيدروجين وين هتيجي ال OH؟ على هذه
+
+331
+00:27:04,130 --> 00:27:05,490
+اللي حاملة هيدروجين وين هتيجي ال OH؟ على هذه اللي
+
+332
+00:27:05,490 --> 00:27:09,790
+حاملة هيدروجين وين هتيجي ال OH؟ على هذه اللي حاملة
+
+333
+00:27:09,790 --> 00:27:14,130
+هيدروجين وين هتيجي ال OH؟ على هذه اللي حاملة
+
+334
+00:27:14,130 --> 00:27:19,510
+هيدروجين
+
+335
+00:27:19,510 --> 00:27:26,840
+وهن بحط ال H و هن بحط ال OH طبعا
+
+336
+00:27:26,840 --> 00:27:30,760
+في هذا المثال الحقيقة مافيش إمكانية برضه ل
+
+337
+00:27:30,760 --> 00:27:34,120
+rearrangement يعني لو كنت هذا المثال تحديدا بدي
+
+338
+00:27:34,120 --> 00:27:39,460
+أكمله في وجود H plus وH to O برضه هيعطي نفس النتجة
+
+339
+00:27:40,250 --> 00:27:43,350
+يعني احنا دايما بنقول ان ال rearrangement possible
+
+340
+00:27:43,350 --> 00:27:46,830
+بس مش دايما ممكن ال rearrangement يعني لما يكون
+
+341
+00:27:46,830 --> 00:27:51,450
+فيه امكانية انه اي carbocation يتحسن لاشي افضل
+
+342
+00:27:51,450 --> 00:27:56,010
+بيصير طب لو مافيش امكانية مابصيرش يعني لو على هذا
+
+343
+00:27:56,010 --> 00:28:01,870
+المثال انا كنت بده اضيف H plus H2O الخطوة الأولى
+
+344
+00:28:01,870 --> 00:28:08,100
+شو هتكون؟إضافة الـ H plus تخيلوا إضافت هنا صار
+
+345
+00:28:08,100 --> 00:28:14,080
+Carbocation هنا شو نوع هذا Carbocation؟
+
+346
+00:28:14,080 --> 00:28:19,280
+طيب tertiary هيعمل rearrangement؟ في أحسن من ال
+
+347
+00:28:19,280 --> 00:28:23,080
+tertiary؟ بناء على ذلك هيكمل بدون rearrangement
+
+348
+00:28:23,080 --> 00:28:26,300
+وبالتالي في هذا المثال تحديدًا في هذا المثال
+
+349
+00:28:26,300 --> 00:28:29,760
+تحديدًا بأي شكل من الأشكال ضفت أنا
+
+350
+00:28:33,200 --> 00:28:37,800
+بال ميركوريك أسيتيت بيختلف الناتج لأ بينما لاحظوا
+
+351
+00:28:37,800 --> 00:28:43,240
+لو بدنا نحكي بهذا المثال خليني أكملكم الهيدروجين
+
+352
+00:28:43,240 --> 00:28:49,320
+كلها للجزيء باللون الأحمر وهنا
+
+353
+00:28:49,320 --> 00:28:54,240
+في عندي كمان هيدروجين الان أول ما بده ييجي اضيف
+
+354
+00:28:54,240 --> 00:28:57,600
+ميه في وجود الحامض مش في وجود الزئبق بتكونوا
+
+355
+00:28:57,600 --> 00:29:02,950
+تتخيلوا okay لما نقول ان هذا بده يضيف في وجودH
+
+356
+00:29:02,950 --> 00:29:10,370
+plus H2O وين هتيجي الهيدروجين على هذا الموقع واضح
+
+357
+00:29:10,370 --> 00:29:13,650
+هاي الهيدروجين اجت على هذا الموقع ال double bond
+
+358
+00:29:13,650 --> 00:29:19,550
+راحت وشو صار عندى هنا انتبهوا معاه لسه كاربو
+
+359
+00:29:19,550 --> 00:29:26,930
+كاتايون هذا الكاربو كاتاين إذا بتطلع عليه في
+
+360
+00:29:26,930 --> 00:29:32,090
+إمكانية انه ينقل Hإنه يعمل rearrangement هذا نفس
+
+361
+00:29:32,090 --> 00:29:36,610
+المثال السابق اللي احنا شرحناه لكوا واضح؟ بتلقى
+
+362
+00:29:36,610 --> 00:29:41,790
+الكل هادي هنا و أين بتيجي ال OH بيصير ال positive
+
+363
+00:29:41,790 --> 00:29:45,670
+هنا و ال OH بتيجي هنا مثل هذه المعادلة، لو كنا
+
+364
+00:29:45,670 --> 00:29:52,410
+جايليني أكمل المعادلة في وجود H plus H2O، شو
+
+365
+00:29:52,410 --> 00:29:56,230
+الناتج اللي بتتوقعوه؟ مش اللي انتوا شايفينه على
+
+366
+00:29:56,230 --> 00:29:56,530
+اللوحة
+
+367
+00:30:00,950 --> 00:30:05,470
+هنا هتيجي ال H في البداية تكون كاربو كتاين على هذا
+
+368
+00:30:05,470 --> 00:30:11,790
+الموقع السكندري بينقل هاي
+
+369
+00:30:11,790 --> 00:30:17,340
+الناتج شوفتوا الفرق بين الطريقتين؟إذا في هذا
+
+370
+00:30:17,340 --> 00:30:23,100
+المثال يختلف عندي إذا أضيف الميه باستعمال الحامض
+
+371
+00:30:23,100 --> 00:30:26,760
+أو باستعمال الذئبق باستعمال الذئبق لا يوجد نقاش
+
+372
+00:30:26,760 --> 00:30:32,000
+أتيت ال H هنا و ال O هنا التفاعل هذا لا يوجد فيه
+
+373
+00:30:32,000 --> 00:30:35,980
+rearrangement على الطرفين الرامض لا يوجد
+
+374
+00:30:35,980 --> 00:30:40,200
+rearrangement في وجود الحامض أول ما تأتي ال H هنا
+
+375
+00:30:40,200 --> 00:30:45,490
+و تعمل positiveشو بيصير عندى؟ بيصير عندى الـ
+
+376
+00:30:45,490 --> 00:30:47,810
+hydrate shift rearrangement الـ positive بيصير على
+
+377
+00:30:47,810 --> 00:30:51,810
+هذا الموقع و الـ OH بتيجي على هذا الموقع إذا هنا
+
+378
+00:30:51,810 --> 00:30:57,250
+الناتج مختلف تماما ولا لأ؟ أه فوجود طريقتين،
+
+379
+00:30:57,250 --> 00:31:01,870
+الطريقتين لا يعطوا نفس الناتج مرات بيعطوا إذا
+
+380
+00:31:01,870 --> 00:31:04,490
+مافيش إمكانية لل rearrangement لكن لو في إمكانية
+
+381
+00:31:04,490 --> 00:31:08,070
+لل rearrangement ال rearrangement بتصير في وجود
+
+382
+00:31:08,070 --> 00:31:11,950
+الحامض مابتصيرش في وجود الذئبق
+
+383
+00:31:15,420 --> 00:31:18,400
+يعني ال arrangement بتصير في وجود الحامض و
+
+384
+00:31:18,400 --> 00:31:22,940
+مابتصيرش في وجود الذئب اكتر يعني دكتور انا احنا
+
+385
+00:31:22,940 --> 00:31:28,800
+لما نيجي نعملها بيصير مثلا كاربوكاتيا على سكنها
+
+386
+00:31:28,800 --> 00:31:32,240
+بتعملوله ال arrangement هو نفسه كأنه بدور من اقرب
+
+387
+00:31:32,240 --> 00:31:38,370
+واحدة يعني ممكن تيرشفإذا فيه بيصير tertiary واضح؟
+
+388
+00:31:38,370 --> 00:31:41,370
+لو .. لو كان tertiary مش هيعمل rearrangement لو
+
+389
+00:31:41,370 --> 00:31:46,730
+كان secondary ونقل مجموعة H minus أو مجموعة مثل
+
+390
+00:31:46,730 --> 00:31:52,530
+بتخليه tertiary هيعمل واضح؟ بيعتمد على نوع المثال
+
+391
+00:31:52,530 --> 00:31:57,550
+إذا هنا في وجود الحامض هل تستطيعون تكتبوا الجواب
+
+392
+00:31:57,550 --> 00:32:02,050
+مباشرة ولا لازم تعملوا ميكانيزم للتفاعل؟المفروض
+
+393
+00:32:02,050 --> 00:32:05,430
+تعملوا mechanism يعني لو واحدة بس بدا ت .. بدا ت
+
+394
+00:32:05,430 --> 00:32:10,070
+.. تحط نتاج و تقول H O H و خلاص مابظبطش لازم تشتغل
+
+395
+00:32:10,070 --> 00:32:15,590
+تحليل للمسألة H اي الموجب بالامكان يتحسنها ده
+
+396
+00:32:15,590 --> 00:32:19,550
+secondary يصير tertiary بعدين ال O H بتضيف في حالة
+
+397
+00:32:19,550 --> 00:32:23,090
+الإضافة في وجود H plus و H plus و H plus و H plus
+
+398
+00:32:23,090 --> 00:32:23,150
+و H plus و H plus و H plus و H plus و H plus و H
+
+399
+00:32:23,150 --> 00:32:24,710
+plus و H plus و H plus و H plus و H plus و H plus
+
+400
+00:32:24,710 --> 00:32:25,170
+و H plus و H plus و H plus و H plus و H plus و H
+
+401
+00:32:25,170 --> 00:32:25,190
+plus و H plus و H plus و H plus و H plus و H plus
+
+402
+00:32:25,190 --> 00:32:25,210
+plus و H plus و H plus و H plus و H plus و H plus
+
+403
+00:32:25,210 --> 00:32:34,790
+و H plus و H plus و Hالان في طريقة تالتة لإضافة
+
+404
+00:32:34,790 --> 00:32:41,090
+الميّه طريقة
+
+405
+00:32:41,090 --> 00:32:47,710
+إضافة الميّه التالتة بنسميها hydroboration of an
+
+406
+00:32:47,710 --> 00:32:52,510
+alkene with oxidative workup أو مرات بيسموها
+
+407
+00:32:52,510 --> 00:32:57,110
+hydroboration oxidationواضح؟ اش معناه
+
+408
+00:32:57,110 --> 00:33:02,030
+hydroboration؟ في عندى عنصر فى الجدول الدورى اللى
+
+409
+00:33:02,030 --> 00:33:08,610
+اسمه ال boron عارفينه؟ العنصر اللى بيجينى بعد ال
+
+410
+00:33:08,610 --> 00:33:12,990
+helium تالت عنصر مش عندى اول عنصر ال hydrogen
+
+411
+00:33:12,990 --> 00:33:21,640
+التانى ال helium التالت ال boronالبرون موجود منه
+
+412
+00:33:21,640 --> 00:33:30,060
+مُركّب مع تلاتة هيدروجين بورين BH3 مُركّب بورين
+
+413
+00:33:30,060 --> 00:33:34,000
+BH3 مُركّب
+
+414
+00:33:34,000 --> 00:33:41,500
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+415
+00:33:41,500 --> 00:33:45,440
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+416
+00:33:45,440 --> 00:33:47,960
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+417
+00:33:47,960 --> 00:33:48,280
+بورين BH3 مُركّب بورين BH3 مُركّب بورين BH3 مُركّب
+
+418
+00:33:48,280 --> 00:33:53,280
+بكخطوة أولى و بعدين بالخطوة التانية ضيفنا له H2O2
+
+419
+00:33:53,280 --> 00:33:57,020
+مية الأكسجين اللى بنسميها إحنا إيش hydrogen
+
+420
+00:33:57,020 --> 00:34:04,800
+peroxide في basic medium في OH minus بضيف برضه
+
+421
+00:34:04,800 --> 00:34:09,080
+بالمحصلة مية لاحظوا هذه الأشياء عشان تحفظوا
+
+422
+00:34:09,080 --> 00:34:16,170
+أسماءها ال BH3 عبارة عن إيشالبرين ال THF هذا عبارة
+
+423
+00:34:16,170 --> 00:34:25,230
+عن solvent مذيب solvent ال H2O2 هيدروجين بيروكسايد
+
+424
+00:34:25,230 --> 00:34:28,870
+فوق أكسيد الهيدروجين هيدروجين بيروكسايد و ال OH
+
+425
+00:34:28,870 --> 00:34:33,570
+minus معنى ذلك أن التفاعل بتم في basic medium كل
+
+426
+00:34:33,570 --> 00:34:40,940
+هذا الكلام ايش بضيف عندهبيضيف H و OH، بيصير السؤال
+
+427
+00:34:40,940 --> 00:34:48,960
+طيب إيش بيختلف عن الإضافة في وجود الحامض و عن
+
+428
+00:34:48,960 --> 00:34:54,530
+الإضافة في وجود الذئبق؟الإضافة في وجود الحامد كانت
+
+429
+00:34:54,530 --> 00:34:59,370
+Markovnikov لكن ممكن ال rearrangement الإضافة في
+
+430
+00:34:59,370 --> 00:35:04,390
+وجود الذئبق Markovnikov بدون rearrangement الآن
+
+431
+00:35:04,390 --> 00:35:09,510
+الإضافة بهذه الطريقة Anti Markovnikov نتيجتها عكس
+
+432
+00:35:09,510 --> 00:35:16,230
+Markovnikov واضح؟ هذه الفرقAnti Markovnikov's
+
+433
+00:35:16,230 --> 00:35:22,290
+addition بضيف عكس قاعدة Markovnikov هم لاحظين هنا
+
+434
+00:35:22,290 --> 00:35:28,590
+إيش إحنا بنقول Anti Markovnikov's addition يعني
+
+435
+00:35:28,590 --> 00:35:33,090
+لما يكون في عندي رابطة مش متماثلة على جهة Hydrogen
+
+436
+00:35:33,090 --> 00:35:37,030
+أكتر ال H1 بتروح على اللحام ل Hydrogen أكتر ولا
+
+437
+00:35:37,030 --> 00:35:42,890
+أقل في هذه الحالة؟ أقل لأن عكس قاعدة Markovnikov
+
+438
+00:35:46,700 --> 00:35:52,820
+طبعا كميكانيزم أو آلية كيف يتم هذا التفاعل احنا زي
+
+439
+00:35:52,820 --> 00:35:56,880
+ما اتفقنا ان التفاعل هذا هو ممكن ناخده مع هذا
+
+440
+00:35:56,880 --> 00:36:01,280
+المركب ممكن ناخده مع هذا المركب بدنا نضيف هنا واضح
+
+441
+00:36:01,280 --> 00:36:07,400
+بدنا نضيف هنا اللي بده يضيف ال bhc3 اتخيلوا ال
+
+442
+00:36:07,400 --> 00:36:13,490
+bhc3 اتي بهذا الشكل بدأهذه الـ double bond تتحرك
+
+443
+00:36:13,490 --> 00:36:17,550
+وتعمل رابطة مع البورون؟ ليش الـ double bond بتعمل
+
+444
+00:36:17,550 --> 00:36:21,930
+رابطة مع البورون؟
+
+445
+00:36:21,930 --> 00:36:26,910
+اتذكروا البورون هنا في الـ BH3 أصلا، كام إلكترون
+
+446
+00:36:26,910 --> 00:36:30,910
+حوله؟ كام رابطة؟
+
+447
+00:36:35,600 --> 00:36:40,760
+البرون هل هو في الوضع الطبيعي اللي بيكون حوله تمان
+
+448
+00:36:40,760 --> 00:36:46,740
+إلكترونات ولا إلكترون deficient إلكترون poor نقصه
+
+449
+00:36:46,740 --> 00:36:52,020
+إلكترونات؟نقص إلكترونات الوضع الطبيعي كم حول الذر
+
+450
+00:36:52,020 --> 00:36:56,980
+يكون عنده إلكترونات 8 أربع روابط الآن هنا البرون
+
+451
+00:36:56,980 --> 00:37:02,900
+في هذا الجزء ال بي اتش تري كم أصلا حواليه ستة إذا
+
+452
+00:37:02,900 --> 00:37:07,420
+هو electron acceptor بده إلكترونات والإلكترون
+
+453
+00:37:07,420 --> 00:37:11,560
+acceptor حسب تعريف الحمض والقاعدة حسب Lewis
+
+454
+00:37:11,560 --> 00:37:16,440
+Definition اتذكروا تعريف Lewis للحمض والقاعدة ال
+
+455
+00:37:16,440 --> 00:37:22,190
+acid is electronacceptor و ال base is electron
+
+456
+00:37:22,190 --> 00:37:28,910
+donor إذا ال borane هنا عبارة عن إيش Lewis acid
+
+457
+00:37:28,910 --> 00:37:35,730
+حامض بمنطقه Lewis هو حامض هو بحاجة إلى إلكترونات
+
+458
+00:37:35,730 --> 00:37:40,210
+واضح و بناء على ذلك لما بيجي jump double bond ال
+
+459
+00:37:40,210 --> 00:37:44,220
+double bond بتبدأ تتحرك هناإيش .. إيش بتعمل لما
+
+460
+00:37:44,220 --> 00:37:47,360
+تجيله ال double bond هنا؟ إيش بتعمل؟ بتعطيه
+
+461
+00:37:47,360 --> 00:37:51,980
+إلكترونات هو بده إلكترونات و ال double bond تمثل
+
+462
+00:37:51,980 --> 00:37:56,980
+إلكترونات أو كثافة إلكترونية بتبدأ تتحرك زي هيك،
+
+463
+00:37:56,980 --> 00:37:59,980
+الآن مجرد ما تبدأ تتحرك زي هيك، الأكش مع
+
+464
+00:37:59,980 --> 00:38:04,940
+إلكتروناتها بتصير تتحرك .. لاحظوا هذا لما تتحرك
+
+465
+00:38:04,940 --> 00:38:10,160
+بهذا الاتجاه، هتترك مكانها إيش؟فراغ positive
+
+466
+00:38:10,160 --> 00:38:13,440
+charge أقل من الكربوكاتيون اقل شوية من
+
+467
+00:38:13,440 --> 00:38:16,600
+الكربوكاتيون partial charge الكربوكاتيون شحنة
+
+468
+00:38:16,600 --> 00:38:21,160
+كاملة موجب كامل هذا يعني سبعين أو ستين في المية
+
+469
+00:38:21,160 --> 00:38:25,900
+موجب بتترك هنا positive charge مباشرة بتيجي ال H
+
+470
+00:38:25,900 --> 00:38:30,180
+مع إلكتروناتها بالضيف إذا هنا في الخطوة الأولى
+
+471
+00:38:30,180 --> 00:38:37,700
+بيصير عندك H و BH2 هدولة اللي ضافواواضح؟ فعدك مجرد
+
+472
+00:38:37,700 --> 00:38:42,860
+ما تحط ال H2O2 و ال hydrogen peroxide مكان ال BH2
+
+473
+00:38:42,860 --> 00:38:47,780
+ال hydrogen peroxide بتطرد ال BH2 بتحط محلها OH
+
+474
+00:38:47,780 --> 00:38:53,840
+الان لاحظوا معي وين إجت ال H على اللي حمل ال
+
+475
+00:38:53,840 --> 00:38:59,710
+hydrogen أكتر ولا أقل حسب Markovnikovكان ال H لازم
+
+476
+00:38:59,710 --> 00:39:04,670
+تيجي هنا و ال O H هنا لكن هذا التفاعل Anti Markov
+
+477
+00:39:04,670 --> 00:39:10,850
+Nikov ال H إجت هنا و ال O H إجت بهذا الموقع واضح؟
+
+478
+00:39:10,850 --> 00:39:14,930
+إذا هنا النتيجة Anti Markov Nikov بمعنى لو أنا هذا
+
+479
+00:39:14,930 --> 00:39:19,830
+كنت المثال نفسه جايب و قايلكم H plus في وجود H2O
+
+480
+00:39:19,830 --> 00:39:28,420
+كيف كان هتحطوا النتيجة؟ هتحطوها بهذا الشكلهنا ال H
+
+481
+00:39:28,420 --> 00:39:37,660
+وهنا ال OH وهي ال H الأصلية وهي CH3 إذا لو احنا
+
+482
+00:39:37,660 --> 00:39:41,900
+بدنا نيجي نسألكوا نحط هذا المركب و نعمل سهمين سهم
+
+483
+00:39:41,900 --> 00:39:47,000
+نكتب عليه BH3, THF كذا كل هدول الأشياء هتحطوا H و
+
+484
+00:39:47,000 --> 00:39:51,500
+OH لو ساهمتان بدنا نعمل عليه H plus H2O هذه
+
+485
+00:39:51,500 --> 00:39:57,060
+الإضافةماركوفنيكوف هذه الإضافة أمتي ماركوفنيكوف
+
+486
+00:39:57,060 --> 00:40:00,780
+شوفت وين الفرق بين الإضافة باستعمال البورين
+
+487
+00:40:00,780 --> 00:40:07,020
+والإضافة باستعمال الحامض والميه؟ الآن بيجي السؤال
+
+488
+00:40:07,020 --> 00:40:15,810
+مرة تانية خلينا نحلل الأمور ولو بشكل مبسطالان هذا
+
+489
+00:40:15,810 --> 00:40:20,890
+التفاعل لما يمشي امتي ماركوف نيكوف اديشن ايش اللي
+
+490
+00:40:20,890 --> 00:40:23,770
+حكم التفاعل؟ هل هو الخطوة التانية او الخطوة
+
+491
+00:40:23,770 --> 00:40:28,690
+الاولى؟ الخطوة الاولى .. واضح؟ ليش؟ لان الخطوة
+
+492
+00:40:28,690 --> 00:40:31,810
+التانية تحصيل حاصل .. المحل ماعنديه بورون، بده
+
+493
+00:40:31,810 --> 00:40:37,250
+يصير OH لكن السؤال ان هذا الجزء كله لما اتفاعل
+
+494
+00:40:37,250 --> 00:40:40,550
+هنا، ايش كان فيه مانع انه يكون بهذا الشكل؟ تكون
+
+495
+00:40:40,550 --> 00:40:44,810
+البورون زي هيك؟والـ H هنا بمعنى تضيف الـ H هنا و
+
+496
+00:40:44,810 --> 00:40:49,090
+تضيف ال boron هنا واضح؟
+
+497
+00:40:49,090 --> 00:40:52,790
+يعني كأنه .. اتخيلوا ان هذه الحمرة .. هذه الغطاية
+
+498
+00:40:52,790 --> 00:40:56,570
+الحمرة هي ال H ماشي؟ و هنا ال boron الآن هذا جاي
+
+499
+00:40:56,570 --> 00:40:59,730
+يضيف ع ال double bond احنا قولنا بضيف زي هيك طب
+
+500
+00:40:59,730 --> 00:41:06,210
+السؤال ايش المانع انه يضيف زي هيك؟واضحة الفكرة؟ اه
+
+501
+00:41:06,210 --> 00:41:10,530
+الآن بنقدر نقول إيش المانع لو خلنا يضيف بهذا الشكل
+
+502
+00:41:10,530 --> 00:41:15,630
+أول ما هذه تتحرك هتكونلي شحنة موجبة، الآن شحنة
+
+503
+00:41:15,630 --> 00:41:21,790
+الموجبة هنا إيش نوعها؟ تيرشة طب الآن لو أعملنا
+
+504
+00:41:21,790 --> 00:41:27,390
+بالعكس خلينا هذه تتحرك زي هيك، وين هتتكون الشحنة
+
+505
+00:41:27,390 --> 00:41:33,820
+الموجبة؟ هنا إيش بيكون نوعها؟secondary متصلة
+
+506
+00:41:33,820 --> 00:41:38,640
+بcarbon 2 واضح؟ بيكون نوع الشحنة secondary إذا أن
+
+507
+00:41:38,640 --> 00:41:43,200
+هو أنسب لهذه double bond تبدأ تتحرك زي هيك و تترك
+
+508
+00:41:43,200 --> 00:41:48,100
+tertiary charge ولا تبدأ تتحرك زي هيك و تترك
+
+509
+00:41:48,100 --> 00:41:53,320
+secondary charge؟إذا الموضوع هنا يتعلق بإيش بال
+
+510
+00:41:53,320 --> 00:41:57,420
+stability ثبات الشحنة الجزئية الموجة ب stability
+
+511
+00:41:57,420 --> 00:42:02,480
+of the partial positive charge حركة معينة بتعملي
+
+512
+00:42:02,480 --> 00:42:07,540
+tertiary partial positive charge الحركة التانية لو
+
+513
+00:42:07,540 --> 00:42:12,460
+تمت لو تمت بهذا الشكل شو هتعملي؟ هتعملي برضه
+
+514
+00:42:12,460 --> 00:42:15,700
+positive charge partial لكن شو هيكون نوعها؟
+
+515
+00:42:15,700 --> 00:42:23,730
+secondary أن هو أفضلtertiary ولا secondary؟ اذا زي
+
+516
+00:42:23,730 --> 00:42:29,690
+ما بتلاحظوا .. زي ما بتلاحظوا انه النتيجة ..
+
+517
+00:42:29,690 --> 00:42:37,680
+النتيجة مختلفة بس روح الكلام واحديعني النتيجة
+
+518
+00:42:37,680 --> 00:42:42,940
+الإضافة في وجود ال H plus و ال H2O كنا نقول عنها
+
+519
+00:42:42,940 --> 00:42:48,940
+كنتيجة إيش Markovnikov addition في حالة ال borane
+
+520
+00:42:49,840 --> 00:42:54,360
+انت ماركوف نيكوف اديشن الان هذه نتيجة بالتأكيد
+
+521
+00:42:54,360 --> 00:43:00,920
+مختلفة تماما ولا لأ طيب لو اجينا سألنا ليش في حالة
+
+522
+00:43:00,920 --> 00:43:06,920
+ال H بلس مع المياء النتيجة ماركوف نيكوف اديشن
+
+523
+00:43:06,920 --> 00:43:14,870
+السبب تكوين ال more stableIntermediate تكوين الـ
+
+524
+00:43:14,870 --> 00:43:18,670
+intermediate اللي هي أثبت ما يمكن، مظبوط ولا لأ؟
+
+525
+00:43:18,670 --> 00:43:22,930
+طب و لو إجينا سألنا هنا ليش برضه صارت عند ال Anti
+
+526
+00:43:22,930 --> 00:43:27,810
+Markovnikov addition؟ إيش السبب؟ تكوين ال more
+
+527
+00:43:27,810 --> 00:43:33,730
+stable intermediate فحقيقة السبب يمكن أن يكون واحد
+
+528
+00:43:33,730 --> 00:43:37,710
+رغم إن النتيجة مختلفة
+
+529
+00:43:39,490 --> 00:43:44,450
+معقول أن السبب يكون واحد والنتيجة مختلفة؟ أعطيكم
+
+530
+00:43:44,450 --> 00:43:48,710
+مثال، أي واحدة فيكم عندها ولد صغير، عندها ولد
+
+531
+00:43:48,710 --> 00:43:57,650
+صغير، الان ممكن مرة اتكافئه، اتعززه، تعطيه شغله، و
+
+532
+00:43:57,650 --> 00:44:03,430
+مرة تانية اتعاقبه، الان هل المكافئةزي المعاقبة
+
+533
+00:44:03,430 --> 00:44:09,770
+كنتيجة عكس بعض تماما طب إيه السبب إنه هي قاعدة مرة
+
+534
+00:44:09,770 --> 00:44:16,930
+بتكافؤه ومرة بتعاقبه السعي ورا ثباته ومصلحته
+
+535
+00:44:16,930 --> 00:44:24,890
+لاحظين الأم ولا الأب إذا عزز فهو يسعى لمصلحت الطفل
+
+536
+00:44:24,890 --> 00:44:29,590
+وإذا عاقب فهو يسعى لمصلحت الطفل رغم إن هالنتيجة
+
+537
+00:44:29,590 --> 00:44:35,760
+تبدو إيشمختلفة، لكن الروح هي إيش؟ الساعة نحو
+
+538
+00:44:35,760 --> 00:44:39,680
+المصلحة، الآن نفس الفكرة تماما، إنه هنا طلعت نتيجة
+
+539
+00:44:39,680 --> 00:44:44,560
+مختلفة، لكن في الحالتين أنا مريت عبر ال more
+
+540
+00:44:44,560 --> 00:44:47,900
+stable intermediate، في الحالة الأولى كانت ال more
+
+541
+00:44:47,900 --> 00:44:52,480
+stable carbocation وفي حالة ال hydroboration ال
+
+542
+00:44:52,480 --> 00:45:00,270
+more stablepartial charge يعني شحنة جزئية، واضح؟
+
+543
+00:45:00,270 --> 00:45:05,750
+بناء على ذلك قبل ما ننتهي من هذا الموضوع و ننهي
+
+544
+00:45:05,750 --> 00:45:11,870
+المحاضرة فيه لو أعطناكم الآن homework، أعطناكم هذا
+
+545
+00:45:11,870 --> 00:45:18,530
+المثال و حطنالكم عليه تلت أسهمأكمل المعادلة في
+
+546
+00:45:18,530 --> 00:45:23,830
+وجود البركوريك أستيت أكمل المعادلة في وجود H بلس
+
+547
+00:45:23,830 --> 00:45:30,930
+H2O و أكمل المعادلة في وجود ال BH3 و كل الأشياء
+
+548
+00:45:30,930 --> 00:45:37,380
+اللي موجودة معهفى كل حالة حيطلع عندى ناتج فى
+
+549
+00:45:37,380 --> 00:45:41,560
+الحالة الأولى هنا اتفقنا بتضيف H و OH بدون
+
+550
+00:45:41,560 --> 00:45:45,260
+rearrangement فى الحالة التانية عملناها قبل شوية
+
+551
+00:45:45,260 --> 00:45:48,800
+بتضيف ال H هنا و بيصير rearrangement و فى الأخر ال
+
+552
+00:45:48,800 --> 00:45:55,480
+OH ون بتيجي هنا فى هذه الحالة الأخيرة Anti
+
+553
+00:45:55,480 --> 00:46:00,780
+Markovnikov addition وين هتيجي ال H و ال OH
+
+554
+00:46:03,670 --> 00:46:09,090
+عكس قاعدة ماركوفيكو .. إذا هذا المثال التلت طرق
+
+555
+00:46:09,090 --> 00:46:16,430
+إضافة فيه بتعطيه كام ناتج؟ تلت نواتج مختلفة و لذلك
+
+556
+00:46:16,430 --> 00:46:21,890
+بدكم مش بس تقولوا أن المية بتضيف تلت طرق لأ بدكم
+
+557
+00:46:21,890 --> 00:46:28,460
+تفهموا الفرق بين هذه الطرق التلاتةالحالة الأولى
+
+558
+00:46:28,460 --> 00:46:32,240
+Markovnikov addition with rearrangement مع الذئبق
+
+559
+00:46:32,240 --> 00:46:35,780
+Markovnikov addition without rearrangement مع
+
+560
+00:46:35,780 --> 00:46:41,220
+البورين Anti Markovnikov addition واضح هذا الكلام؟
+
+561
+00:46:41,220 --> 00:46:47,340
+هنا ضيعنا فيه محاضرة لما نسأل فيه سؤال واحد لازم
+
+562
+00:46:47,340 --> 00:46:51,660
+كلكوا تجاوبوه واضح؟ واللي مش فاهمه بتروح على
+
+563
+00:46:51,660 --> 00:46:53,460
+التسجيل بتسمعوا كمان مرة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..17b56db8bae865930f3c19c29e3a0302d196df75
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/L0JgtlTaovk_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2660, "start": 8.82, "end": 26.6, "text": "إذا بتسمحوا أخر نقطة المرة الماضية اتكلمنا عنها كانت إضافة الماء للالكينز وقولنا إنه في عدة طرق من خلالها بتتم عملية إضافة الماء، الطريقة الأولى", "tokens": [28814, 15730, 39894, 38251, 5016, 14407, 5551, 34740, 8717, 47432, 3660, 9673, 25720, 9673, 46958, 10632, 1975, 2655, 4117, 19528, 8315, 18871, 11296, 25961, 2655, 11933, 11242, 31845, 3660, 9673, 16606, 24976, 6027, 4117, 9957, 11622, 4032, 39648, 8315, 36145, 3224, 8978, 6225, 41891, 23032, 2288, 4587, 9154, 16490, 1211, 6027, 11296, 39894, 39237, 6225, 42213, 10632, 11933, 11242, 31845, 3660, 9673, 16606, 12399, 41950, 16572, 28671, 16247, 12610, 7578], "avg_logprob": -0.1489876777353421, "compression_ratio": 1.7483443708609272, "no_speech_prob": 7.212162017822266e-06, "words": [{"start": 8.82, "end": 9.22, "word": "إذا", "probability": 0.61016845703125}, {"start": 9.22, "end": 9.9, "word": " بتسمحوا", "probability": 0.9608154296875}, {"start": 9.9, 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"probability": 0.9306640625}, {"start": 21.9, "end": 22.26, "word": " عدة", "probability": 0.939208984375}, {"start": 22.26, "end": 22.86, "word": " طرق", "probability": 0.9739583333333334}, {"start": 22.86, "end": 23.3, "word": " من", "probability": 0.9873046875}, {"start": 23.3, "end": 23.74, "word": " خلالها", "probability": 0.9927978515625}, {"start": 23.74, "end": 24.14, "word": " بتتم", "probability": 0.65234375}, {"start": 24.14, "end": 24.58, "word": " عملية", "probability": 0.99267578125}, {"start": 24.58, "end": 25.08, "word": " إضافة", "probability": 0.99560546875}, {"start": 25.08, "end": 25.5, "word": " الماء،", "probability": 0.8238932291666666}, {"start": 25.5, "end": 25.98, "word": " الطريقة", "probability": 0.9811197916666666}, {"start": 25.98, "end": 26.6, "word": " الأولى", "probability": 0.9884440104166666}], "temperature": 1.0}, {"id": 2, "seek": 5605, "start": 27.37, "end": 56.05, "text": "إضافة الماء في وجود حامض اللي سمناه احنا acid-catalyzed hydration of alkenes إذا بنذكر في الكلام اللي حكيناه قولنا وظيفة الحامض أنه يبدأ التفاعل الحامض اللي بيعطينا الـ H plus وظيفته أنه يبدأ التفاعل بتتحرك ال double bond بهذا الشكل بتضيف هنا بتترك عندنا Carbocation موجب", "tokens": [28814, 11242, 31845, 3660, 9673, 16606, 8978, 49610, 23328, 11331, 10943, 11242, 13672, 1829, 8608, 2304, 8315, 3224, 1975, 5016, 8315, 8258, 12, 18035, 5222, 11312, 43631, 295, 419, 2653, 279, 11933, 15730, 44945, 8848, 37983, 8978, 2423, 28820, 10943, 13672, 1829, 11331, 4117, 1829, 8315, 3224, 12174, 12610, 8315, 4032, 19913, 33911, 3660, 21542, 10943, 11242, 14739, 3224, 7251, 44510, 10721, 16712, 5172, 995, 30241, 21542, 10943, 11242, 13672, 1829, 4724, 40228, 9566, 1829, 8315, 2423, 39184, 389, 1804, 4032, 19913, 33911, 47395, 14739, 3224, 7251, 44510, 10721, 16712, 5172, 995, 30241, 39894, 2655, 5016, 31747, 2423, 3834, 6086, 39627, 15730, 25124, 28820, 39894, 11242, 33911, 34105, 39894, 2655, 31747, 43242, 8315, 2741, 65, 27943, 3714, 29245, 3555], "avg_logprob": 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{"start": 833.46, "end": 834.84, "word": " primary؟", "probability": 0.871826171875}, {"start": 834.84, "end": 835.4, "word": " secondary،", "probability": 0.701171875}, {"start": 835.4, "end": 835.54, "word": " إذا", "probability": 0.82568359375}, {"start": 835.54, "end": 835.76, "word": " هذا", "probability": 0.74951171875}, {"start": 835.76, "end": 836.34, "word": " الاحتمال", "probability": 0.896728515625}, {"start": 836.34, "end": 836.86, "word": " ألغى", "probability": 0.898193359375}], "temperature": 1.0}, {"id": 37, "seek": 85871, "start": 837.37, "end": 858.71, "text": "اللي بتكون عندى ال secondary لاحظوا هنا ال secondary هتلاحظوا فيه jumbo carbon حاملة CH3 و CH3OH بيصير عندى شغل جديد ان ال secondary نفسه قبل ما يكمل التفاعل ممكن يتحول إلى tertiary", "tokens": [6027, 20292, 39894, 30544, 43242, 7578, 2423, 11396, 20193, 5016, 19913, 14407, 34105, 2423, 11396, 8032, 2655, 15040, 5016, 19913, 14407, 8978, 3224, 29067, 1763, 5954, 11331, 10943, 37977, 5995, 18, 4032, 5995, 18, 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"end": 1057.5, "word": " ملاحظين", "probability": 0.8287841796875}, {"start": 1057.5, "end": 1058.32, "word": " يعني", "probability": 0.6856689453125}, {"start": 1058.32, "end": 1058.64, "word": " بدل", "probability": 0.9794921875}, {"start": 1058.64, "end": 1058.78, "word": " ما", "probability": 0.73291015625}, {"start": 1058.78, "end": 1059.12, "word": " تيجي", "probability": 0.9754638671875}, {"start": 1059.12, "end": 1059.24, "word": " ال", "probability": 0.810546875}, {"start": 1059.24, "end": 1059.54, "word": " H", "probability": 0.3544921875}, {"start": 1059.54, "end": 1059.82, "word": " هنا", "probability": 0.88134765625}, {"start": 1059.82, "end": 1059.94, "word": " و", "probability": 0.60888671875}, {"start": 1059.94, "end": 1060.06, "word": " ال", "probability": 0.7392578125}, {"start": 1060.06, "end": 1060.2, "word": " O", "probability": 0.87255859375}, {"start": 1060.2, "end": 1060.46, "word": " H", "probability": 0.23388671875}, {"start": 1060.46, "end": 1060.82, "word": " هنا", "probability": 0.91455078125}, {"start": 1060.82, "end": 1061.6, "word": " بتلاحظوا", "probability": 0.82978515625}, {"start": 1061.6, "end": 1061.68, "word": " أن", "probability": 0.33203125}, {"start": 1061.68, "end": 1061.78, "word": " ال", "probability": 0.9306640625}, {"start": 1061.78, "end": 1061.94, "word": " O", "probability": 0.8798828125}, {"start": 1061.94, "end": 1062.28, "word": " H", "probability": 0.77880859375}, {"start": 1062.28, "end": 1063.06, "word": " نجلة", "probability": 0.8304036458333334}, {"start": 1063.06, "end": 1064.22, "word": " موقعها", "probability": 0.82415771484375}, {"start": 1064.22, "end": 1064.48, "word": " هذه", "probability": 0.59912109375}, {"start": 1064.48, "end": 1065.14, "word": " عملية", "probability": 0.94482421875}, {"start": 1065.14, "end": 1065.4, "word": " ال", "probability": 0.8642578125}, {"start": 1065.4, "end": 1066.2, "word": " rearrangement", "probability": 0.9130859375}, {"start": 1066.2, "end": 1066.44, "word": " أو", "probability": 0.73681640625}, {"start": 1066.44, "end": 1067.1, "word": " إعادة", "probability": 0.9794921875}, {"start": 1067.1, "end": 1067.9, "word": " الترتيب", "probability": 0.9652099609375}, {"start": 1067.9, "end": 1068.46, "word": " اللي", "probability": 0.811767578125}, {"start": 1068.46, "end": 1069.0, "word": " موجودة", "probability": 0.9775390625}, {"start": 1069.0, "end": 1069.14, "word": " في", "probability": 0.974609375}, {"start": 1069.14, "end": 1069.68, "word": " الجزء", "probability": 0.7666829427083334}, {"start": 1069.68, "end": 1070.58, "word": " ليش", "probability": 0.862548828125}, {"start": 1070.58, "end": 1070.8, "word": " تم", "probability": 0.986328125}, {"start": 1070.8, "end": 1071.14, "word": " تقول", "probability": 0.6533203125}, {"start": 1071.14, "end": 1071.4, "word": " هذه", "probability": 0.8779296875}, {"start": 1071.4, "end": 1071.92, "word": " العملية", "probability": 0.970703125}, {"start": 1071.92, "end": 1072.3, "word": " عملية", "probability": 0.9619140625}, {"start": 1072.3, "end": 1072.84, "word": " إعادة", "probability": 0.98974609375}, {"start": 1072.84, "end": 1073.82, "word": " الترتيب؟", "probability": 0.8255859375}, {"start": 1073.82, "end": 1075.26, "word": " عشان", "probability": 0.92724609375}, {"start": 1075.26, "end": 1076.08, "word": " أنتقل", "probability": 0.92138671875}, {"start": 1076.08, "end": 1076.48, "word": " من", "probability": 0.9921875}, {"start": 1076.48, "end": 1077.82, "word": " السكندري", "probability": 0.69951171875}, {"start": 1077.82, "end": 1078.28, "word": " كاربو", "probability": 0.80401611328125}, {"start": 1078.28, "end": 1078.9, "word": " كاتايون", "probability": 0.688232421875}, {"start": 1078.9, "end": 1079.36, "word": " إلى", "probability": 0.87548828125}], "temperature": 1.0}, {"id": 49, "seek": 110632, "start": 1080.08, "end": 1106.32, "text": "الـ tertiary carbocation عشان ننتقل من السكندريكاربوكاتيون الى التيرتشاريكاربوكاتيون بتم هنا rearrangement من خلال عملية إيش بنسميها؟ Hydride shift يعني تحرك هيدروجين مع إلكتروناته كلام منطقي ليش؟ لأن هذا موجب الموجب إيش بيكون بده؟ بده سالب إيش السالب؟", "tokens": [6027, 39184, 38726, 29104, 12143, 27943, 6225, 8592, 7649, 8717, 29399, 4587, 1211, 9154, 21136, 19452, 3215, 16572, 4117, 9640, 3555, 2407, 4117, 9307, 1829, 11536, 2423, 7578, 16712, 13546, 2655, 8592, 9640, 1829, 4117, 9640, 3555, 2407, 4117, 9307, 1829, 11536, 4724, 39237, 34105, 39568, 518, 9154, 16490, 1211, 6027, 6225, 42213, 10632, 11933, 1829, 8592, 44945, 38251, 1829, 11296, 22807, 24231, 25502, 5513, 37495, 22653, 6055, 5016, 31747, 8032, 25708, 2288, 29245, 9957, 20449, 11933, 23275, 2655, 2288, 11536, 9307, 3224, 28242, 10943, 9154, 9566, 38436, 32239, 8592, 22807, 5296, 33456, 23758, 3714, 29245, 3555, 9673, 29245, 3555, 11933, 1829, 8592, 4724, 1829, 30544, 47525, 3224, 22807, 47525, 3224, 8608, 6027, 3555, 11933, 1829, 8592, 21136, 6027, 3555, 22807], "avg_logprob": -0.20940061658620834, "compression_ratio": 1.6785714285714286, "no_speech_prob": 9.179115295410156e-06, "words": [{"start": 1080.08, "end": 1080.54, "word": "الـ", "probability": 0.50262451171875}, {"start": 1080.54, "end": 1081.1, "word": " tertiary", "probability": 0.87548828125}, {"start": 1081.1, "end": 1082.26, "word": " carbocation", "probability": 0.82958984375}, {"start": 1082.26, "end": 1083.0, "word": " عشان", "probability": 0.9539388020833334}, {"start": 1083.0, "end": 1083.52, "word": " ننتقل", "probability": 0.98291015625}, {"start": 1083.52, "end": 1083.7, "word": " من", "probability": 0.98779296875}, {"start": 1083.7, "end": 1085.38, "word": " السكندريكاربوكاتيون", "probability": 0.7603352864583334}, {"start": 1085.38, "end": 1085.94, "word": " الى", "probability": 0.71435546875}, {"start": 1085.94, "end": 1087.38, "word": " التيرتشاريكاربوكاتيون", "probability": 0.8760288783482143}, {"start": 1087.38, "end": 1088.16, "word": " بتم", "probability": 0.653564453125}, {"start": 1088.16, "end": 1088.42, "word": " هنا", "probability": 0.10272216796875}, {"start": 1088.42, "end": 1089.36, "word": " rearrangement", "probability": 0.8212890625}, {"start": 1089.36, "end": 1089.54, "word": " من", "probability": 0.99267578125}, {"start": 1089.54, "end": 1089.9, "word": " خلال", "probability": 0.9923502604166666}, {"start": 1089.9, "end": 1090.56, "word": " عملية", "probability": 0.9833984375}, {"start": 1090.56, "end": 1091.04, "word": " إيش", "probability": 0.708740234375}, {"start": 1091.04, "end": 1092.34, "word": " بنسميها؟", "probability": 0.85166015625}, {"start": 1092.34, "end": 1093.94, "word": " Hydride", "probability": 0.4820556640625}, {"start": 1093.94, "end": 1094.42, "word": " shift", "probability": 0.71240234375}, {"start": 1094.42, "end": 1094.8, "word": " يعني", "probability": 0.77587890625}, {"start": 1094.8, "end": 1095.7, "word": " تحرك", "probability": 0.97509765625}, {"start": 1095.7, "end": 1097.06, "word": " هيدروجين", "probability": 0.9234375}, {"start": 1097.06, "end": 1097.28, "word": " مع", "probability": 0.994140625}, {"start": 1097.28, "end": 1098.26, "word": " إلكتروناته", "probability": 0.8846958705357143}, {"start": 1098.26, "end": 1098.9, "word": " كلام", "probability": 0.881103515625}, {"start": 1098.9, "end": 1099.48, "word": " منطقي", "probability": 0.9147135416666666}, {"start": 1099.48, "end": 1100.38, "word": " ليش؟", "probability": 0.760009765625}, {"start": 1100.38, "end": 1100.56, "word": " لأن", "probability": 0.81591796875}, {"start": 1100.56, "end": 1100.96, "word": " هذا", "probability": 0.875}, {"start": 1100.96, "end": 1101.66, "word": " موجب", "probability": 0.96435546875}, {"start": 1101.66, "end": 1102.34, "word": " الموجب", "probability": 0.9007161458333334}, {"start": 1102.34, "end": 1102.52, "word": " إيش", "probability": 0.962890625}, {"start": 1102.52, "end": 1102.8, "word": " بيكون", "probability": 0.9153645833333334}, {"start": 1102.8, "end": 1103.92, "word": " بده؟", "probability": 0.8797200520833334}, {"start": 1103.92, "end": 1104.66, "word": " بده", "probability": 0.91162109375}, {"start": 1104.66, "end": 1105.1, "word": " سالب", "probability": 0.6739908854166666}, {"start": 1105.1, "end": 1105.38, "word": " إيش", "probability": 0.8527018229166666}, {"start": 1105.38, "end": 1106.32, "word": " السالب؟", "probability": 0.95751953125}], "temperature": 1.0}, {"id": 50, "seek": 111424, "start": 1107.2, "end": 1114.24, "text": "الهيدروجين و إلكتروناته هما السالب هما الانيون الهيدروجين مع الإلكترونات تبعته", "tokens": [6027, 3224, 25708, 2288, 29245, 9957, 4032, 11933, 23275, 2655, 2288, 11536, 9307, 3224, 8032, 15042, 21136, 6027, 3555, 8032, 15042, 2423, 7649, 1829, 11536, 2423, 3224, 25708, 2288, 29245, 9957, 20449, 33688, 23275, 2655, 2288, 11536, 9307, 6055, 3555, 34268, 3224], "avg_logprob": -0.24981830702271574, "compression_ratio": 1.6781609195402298, "no_speech_prob": 1.9073486328125e-06, "words": [{"start": 1107.2, "end": 1108.2, "word": "الهيدروجين", "probability": 0.8675130208333334}, {"start": 1108.2, "end": 1108.3, "word": " و", "probability": 0.29248046875}, {"start": 1108.3, "end": 1109.14, "word": " إلكتروناته", "probability": 0.7947998046875}, {"start": 1109.14, "end": 1109.4, "word": " هما", "probability": 0.724609375}, {"start": 1109.4, "end": 1109.96, "word": " السالب", "probability": 0.90380859375}, {"start": 1109.96, "end": 1110.24, "word": " هما", "probability": 0.64892578125}, {"start": 1110.24, "end": 1110.98, "word": " الانيون", "probability": 0.8134765625}, {"start": 1110.98, "end": 1112.2, "word": " الهيدروجين", "probability": 0.9225260416666666}, {"start": 1112.2, "end": 1112.74, "word": " مع", "probability": 0.96630859375}, {"start": 1112.74, "end": 1113.6, "word": " الإلكترونات", "probability": 0.9158528645833334}, {"start": 1113.6, "end": 1114.24, "word": " تبعته", "probability": 0.81787109375}], "temperature": 1.0}, {"id": 51, "seek": 114181, "start": 1118.05, "end": 1141.81, "text": "من مميزات الـ Acid Catalyzed Addition of Water أنه في إمكانية طالما بتكون عندي Carbocation في إمكانية لل rearrangement معنى إمكانية ال rearrangement أنه ممكن ال secondary يصير أحيانا في أمثلة معينة فيها primary برضه ممكن يتحول إلى tertiary واضح؟ هنا عملية ال rearrangement تمت من خلال إيش؟", "tokens": [27842, 3714, 2304, 1829, 11622, 9307, 2423, 39184, 5097, 327, 9565, 5222, 11312, 5349, 849, 295, 8772, 14739, 3224, 8978, 11933, 2304, 41361, 10632, 23032, 6027, 15042, 39894, 30544, 43242, 1829, 2741, 65, 27943, 8978, 11933, 2304, 41361, 10632, 24976, 39568, 518, 20449, 1863, 7578, 11933, 2304, 41361, 10632, 2423, 39568, 518, 14739, 3224, 3714, 43020, 2423, 11396, 7251, 9381, 13546, 5551, 5016, 1829, 7649, 995, 8978, 5551, 2304, 12984, 37977, 20449, 9957, 3660, 8978, 11296, 6194, 4724, 43042, 3224, 3714, 43020, 7251, 2655, 5016, 12610, 30731, 38726, 29104, 4032, 46958, 5016, 22807, 34105, 6225, 42213, 10632, 2423, 39568, 518, 46811, 2655, 9154, 16490, 1211, 6027, 11933, 1829, 8592, 22807], "avg_logprob": -0.17891328748282012, "compression_ratio": 1.67578125, "no_speech_prob": 7.152557373046875e-07, "words": [{"start": 1118.05, "end": 1118.31, "word": "من", "probability": 0.7919921875}, {"start": 1118.31, "end": 1119.33, "word": " مميزات", "probability": 0.9931640625}, {"start": 1119.33, "end": 1119.67, "word": " الـ", "probability": 0.761474609375}, {"start": 1119.67, "end": 1120.13, "word": " Acid", "probability": 0.7249755859375}, {"start": 1120.13, "end": 1120.89, "word": " Catalyzed", "probability": 0.684814453125}, {"start": 1120.89, "end": 1121.39, "word": " Addition", "probability": 0.87744140625}, {"start": 1121.39, "end": 1121.55, "word": " of", "probability": 0.82373046875}, {"start": 1121.55, "end": 1121.97, "word": " Water", "probability": 0.8427734375}, {"start": 1121.97, "end": 1122.33, "word": " أنه", "probability": 0.555419921875}, {"start": 1122.33, "end": 1122.41, "word": " في", "probability": 0.8330078125}, {"start": 1122.41, "end": 1123.25, "word": " إمكانية", "probability": 0.9034423828125}, {"start": 1123.25, "end": 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{"start": 1472.48, "end": 1472.56, "word": " و", "probability": 0.716796875}, {"start": 1472.56, "end": 1472.92, "word": " بعدين", "probability": 0.892333984375}, {"start": 1472.92, "end": 1473.38, "word": " صوديوم", "probability": 0.72998046875}, {"start": 1473.38, "end": 1473.72, "word": " بورو", "probability": 0.8981119791666666}, {"start": 1473.72, "end": 1474.34, "word": " هايدرايد", "probability": 0.6595703125}, {"start": 1474.34, "end": 1474.74, "word": " شو", "probability": 0.7255859375}, {"start": 1474.74, "end": 1475.1, "word": " النتج", "probability": 0.81201171875}, {"start": 1475.1, "end": 1475.22, "word": " اللي", "probability": 0.886962890625}, {"start": 1475.22, "end": 1476.56, "word": " هتعطونيه؟", "probability": 0.81036376953125}, {"start": 1476.56, "end": 1477.96, "word": " بده", "probability": 0.475341796875}, {"start": 1477.96, "end": 1478.36, "word": " يضيف", "probability": 0.9798177083333334}, {"start": 1478.36, "end": 1478.64, "word": " ال", "probability": 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شوفت وين الفرق ما بين الشغلتين؟", "tokens": [2407, 46958, 5016, 22807, 37495, 22653, 45164, 2423, 26949, 317, 13672, 7578, 43242, 7578, 33307, 37848, 473, 4724, 16254, 7251, 9566, 1211, 3615, 23758, 28239, 2655, 7435, 45164, 2423, 26949, 317, 13672, 7578, 43242, 7578, 389, 1804, 389, 17, 46, 4724, 16254, 7251, 9566, 1211, 3615, 23758, 28239, 2655, 7435, 13412, 38688, 2655, 4032, 9957, 27188, 2288, 4587, 19446, 49374, 25124, 17082, 1211, 2655, 9957, 22807], "avg_logprob": -0.24440298685387, "compression_ratio": 1.6375838926174497, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 1487.61, "end": 1488.27, "word": "واضح؟", "probability": 0.640960693359375}, {"start": 1488.27, "end": 1488.57, "word": " يعني", "probability": 0.886474609375}, {"start": 1488.57, "end": 1488.77, "word": " لو", "probability": 0.703125}, {"start": 1488.77, "end": 1488.89, "word": " ال", "probability": 0.94580078125}, {"start": 1488.89, "end": 1489.51, "word": " reagent", "probability": 0.871826171875}, 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"probability": 0.8603515625}, {"start": 1499.91, "end": 1500.19, "word": " بين", "probability": 0.99267578125}, {"start": 1500.19, "end": 1501.17, "word": " الشغلتين؟", "probability": 0.93505859375}], "temperature": 1.0}, {"id": 68, "seek": 152851, "start": 1502.51, "end": 1528.51, "text": "واضح هذا هو الفرق بين إضافة الميه في وجود حامض إنه فيه إمكانية ل rearrangement إضافة الميه في وجود الذئبق لأ بتضيف حسب Markovnikov rule بدون عملية ال rearrangement عشانك حتى لو بترجع يمكن لل slides لل slides بتلاحظوا في عندنا هنا كلمة إنه ال addition Markovnikov regiochemistry is observed", "tokens": [2407, 46958, 5016, 23758, 31439, 27188, 2288, 4587, 49374, 11933, 11242, 31845, 3660, 9673, 1829, 3224, 8978, 49610, 23328, 11331, 10943, 11242, 36145, 3224, 8978, 3224, 11933, 2304, 41361, 10632, 5296, 39568, 518, 11933, 11242, 31845, 3660, 9673, 1829, 3224, 8978, 49610, 23328, 32545, 19986, 3555, 4587, 5296, 10721, 39894, 11242, 33911, 11331, 35457, 3934, 5179, 13123, 5179, 4978, 47525, 11536, 6225, 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"probability": 0.980224609375}, {"start": 1510.51, "end": 1511.15, "word": " الذئبق", "probability": 0.8201904296875}, {"start": 1511.15, "end": 1511.69, "word": " لأ", "probability": 0.823974609375}, {"start": 1511.69, "end": 1512.43, "word": " بتضيف", "probability": 0.8898111979166666}, {"start": 1512.43, "end": 1513.01, "word": " حسب", "probability": 0.96728515625}, {"start": 1513.01, "end": 1513.81, "word": " Markovnikov", "probability": 0.811767578125}, {"start": 1513.81, "end": 1514.45, "word": " rule", "probability": 0.42236328125}, {"start": 1514.45, "end": 1515.37, "word": " بدون", "probability": 0.967041015625}, {"start": 1515.37, "end": 1516.17, "word": " عملية", "probability": 0.9833984375}, {"start": 1516.17, "end": 1517.11, "word": " ال", "probability": 0.64990234375}, {"start": 1517.11, "end": 1517.83, "word": " rearrangement", "probability": 0.951904296875}, {"start": 1517.83, "end": 1518.47, "word": " عشانك", "probability": 0.876708984375}, {"start": 1518.47, "end": 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1764.95, "word": " بتطلع", "probability": 0.854248046875}, {"start": 1764.95, "end": 1765.45, "word": " عليه", "probability": 0.9599609375}, {"start": 1765.45, "end": 1766.93, "word": " في", "probability": 0.775390625}, {"start": 1766.93, "end": 1767.47, "word": " إمكانية", "probability": 0.8072509765625}, {"start": 1767.47, "end": 1767.63, "word": " انه", "probability": 0.61669921875}, {"start": 1767.63, "end": 1767.93, "word": " ينقل", "probability": 0.9049072265625}, {"start": 1767.93, "end": 1768.33, "word": " H", "probability": 0.8388671875}], "temperature": 1.0}, {"id": 78, "seek": 179653, "start": 1769.61, "end": 1796.53, "text": "إنه يعمل rearrangement هذا نفس المثال السابق اللي احنا شرحناه لكوا واضح؟ بتلقى الكل هادي هنا و أين بتيجي ال OH بيصير ال positive هنا و ال OH بتيجي هنا مثل هذه المعادلة، لو كنا جايليني أكمل المعادلة في وجود H plus H2O، شو الناتج اللي بتتوقعوه؟ مش اللي انتوا شايفينه على اللوحة", "tokens": [28814, 1863, 3224, 7251, 25957, 1211, 39568, 518, 23758, 8717, 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0.9537760416666666}, {"start": 1787.05, "end": 1788.11, "word": " المعادلة", "probability": 0.983154296875}, {"start": 1788.11, "end": 1788.75, "word": " في", "probability": 0.8984375}, {"start": 1788.75, "end": 1789.25, "word": " وجود", "probability": 0.9775390625}, {"start": 1789.25, "end": 1789.63, "word": " H", "probability": 0.9150390625}, {"start": 1789.63, "end": 1790.25, "word": " plus", "probability": 0.17529296875}, {"start": 1790.25, "end": 1792.01, "word": " H2O،", "probability": 0.56585693359375}, {"start": 1792.01, "end": 1792.41, "word": " شو", "probability": 0.852294921875}, {"start": 1792.41, "end": 1792.87, "word": " الناتج", "probability": 0.8058268229166666}, {"start": 1792.87, "end": 1793.03, "word": " اللي", "probability": 0.92919921875}, {"start": 1793.03, "end": 1794.55, "word": " بتتوقعوه؟", "probability": 0.9163643973214286}, {"start": 1794.55, "end": 1795.29, "word": " مش", "probability": 0.90087890625}, {"start": 1795.29, "end": 1795.43, "word": " اللي", "probability": 0.973876953125}, {"start": 1795.43, "end": 1795.65, "word": " انتوا", "probability": 0.7661946614583334}, {"start": 1795.65, "end": 1796.07, "word": " شايفينه", "probability": 0.9892578125}, {"start": 1796.07, "end": 1796.23, "word": " على", "probability": 0.75}, {"start": 1796.23, "end": 1796.53, "word": " اللوحة", "probability": 0.941162109375}], "temperature": 1.0}, {"id": 79, "seek": 181535, "start": 1800.95, "end": 1815.35, "text": "هنا هتيجي ال H في البداية تكون كاربو كتاين على هذا الموقع السكندري بينقل هاي الناتج شوفتوا الفرق بين الطريقتين؟", "tokens": [3224, 8315, 8032, 31371, 7435, 1829, 2423, 389, 8978, 29739, 28259, 10632, 6055, 30544, 9122, 9640, 3555, 2407, 9122, 2655, 995, 9957, 15844, 23758, 9673, 30543, 3615, 21136, 19452, 3215, 16572, 4724, 9957, 4587, 1211, 8032, 47302, 28239, 9307, 7435, 13412, 38688, 2655, 14407, 27188, 2288, 4587, 49374, 41950, 16572, 38149, 9957, 22807], "avg_logprob": -0.32465277667398806, "compression_ratio": 1.5538461538461539, "no_speech_prob": 0.0, "words": [{"start": 1800.95, "end": 1801.35, "word": "هنا", "probability": 0.569580078125}, {"start": 1801.35, "end": 1801.79, "word": " هتيجي", "probability": 0.708160400390625}, {"start": 1801.79, "end": 1801.93, "word": " ال", "probability": 0.9072265625}, {"start": 1801.93, "end": 1802.17, "word": " H", "probability": 0.350341796875}, {"start": 1802.17, "end": 1802.35, "word": " في", "probability": 0.84716796875}, {"start": 1802.35, "end": 1803.09, "word": " البداية", "probability": 0.9811197916666666}, {"start": 1803.09, "end": 1804.15, "word": " تكون", "probability": 0.60791015625}, {"start": 1804.15, "end": 1804.65, "word": " كاربو", "probability": 0.78857421875}, {"start": 1804.65, "end": 1805.07, "word": " كتاين", "probability": 0.74774169921875}, {"start": 1805.07, "end": 1805.23, "word": " على", "probability": 0.5439453125}, {"start": 1805.23, "end": 1805.47, "word": " هذا", "probability": 0.7216796875}, {"start": 1805.47, "end": 1805.83, "word": " الموقع", "probability": 0.9695638020833334}, {"start": 1805.83, "end": 1806.43, "word": " السكندري", "probability": 0.70166015625}, {"start": 1806.43, "end": 1807.09, "word": " بينقل", "probability": 0.79107666015625}, {"start": 1807.09, "end": 1811.79, "word": " هاي", "probability": 0.409912109375}, {"start": 1811.79, "end": 1812.33, "word": " الناتج", "probability": 0.6936848958333334}, {"start": 1812.33, "end": 1813.71, "word": " شوفتوا", "probability": 0.7166748046875}, {"start": 1813.71, "end": 1814.05, "word": " الفرق", "probability": 0.98095703125}, {"start": 1814.05, "end": 1814.29, "word": " بين", "probability": 0.97216796875}, {"start": 1814.29, "end": 1815.35, "word": " الطريقتين؟", "probability": 0.94638671875}], "temperature": 1.0}, {"id": 80, "seek": 184110, "start": 1816.66, "end": 1841.1, "text": "إذا في هذا المثال يختلف عندي إذا أضيف الميه باستعمال الحامض أو باستعمال الذئبق باستعمال الذئبق لا يوجد نقاش أتيت ال H هنا و ال O هنا التفاعل هذا لا يوجد فيه rearrangement على الطرفين الرامض لا يوجد rearrangement في وجود الحامض أول ما تأتي ال H هنا و تعمل positive", "tokens": [28814, 15730, 8978, 23758, 9673, 12984, 6027, 7251, 46456, 46538, 18871, 16254, 11933, 15730, 5551, 11242, 33911, 9673, 1829, 3224, 4724, 995, 14851, 25957, 6027, 21542, 10943, 11242, 34051, 4724, 995, 14851, 25957, 6027, 32545, 19986, 3555, 4587, 4724, 995, 14851, 25957, 6027, 32545, 19986, 3555, 4587, 20193, 7251, 29245, 3215, 8717, 4587, 33599, 5551, 31371, 2655, 2423, 389, 34105, 4032, 2423, 422, 34105, 16712, 5172, 995, 30241, 23758, 20193, 7251, 29245, 3215, 8978, 3224, 39568, 518, 15844, 41950, 28480, 9957, 34892, 10943, 11242, 20193, 7251, 29245, 3215, 39568, 518, 8978, 49610, 23328, 21542, 10943, 11242, 5551, 12610, 19446, 6055, 10721, 31371, 2423, 389, 34105, 4032, 6055, 25957, 1211, 3353], "avg_logprob": -0.27547859930777335, "compression_ratio": 2.0514018691588785, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1816.66, "end": 1816.94, "word": "إذا", "probability": 0.5830078125}, {"start": 1816.94, "end": 1817.12, "word": " في", "probability": 0.54931640625}, {"start": 1817.12, "end": 1817.34, "word": " هذا", "probability": 0.8349609375}, {"start": 1817.34, "end": 1818.12, "word": " المثال", "probability": 0.9773763020833334}, {"start": 1818.12, "end": 1819.16, "word": " يختلف", "probability": 0.7469889322916666}, {"start": 1819.16, "end": 1819.72, "word": " عندي", "probability": 0.5592041015625}, {"start": 1819.72, "end": 1820.04, "word": " إذا", "probability": 0.68994140625}, {"start": 1820.04, "end": 1820.46, "word": " أضيف", "probability": 0.84619140625}, {"start": 1820.46, "end": 1820.88, "word": " الميه", "probability": 0.611572265625}, {"start": 1820.88, "end": 1821.7, "word": " باستعمال", "probability": 0.94033203125}, {"start": 1821.7, "end": 1823.1, "word": " الحامض", "probability": 0.9454752604166666}, {"start": 1823.1, "end": 1823.32, "word": " أو", "probability": 0.53173828125}, {"start": 1823.32, "end": 1824.36, 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"end": 1829.12, "word": " ال", "probability": 0.341064453125}, {"start": 1829.12, "end": 1829.26, "word": " O", "probability": 0.94921875}, {"start": 1829.26, "end": 1829.86, "word": " هنا", "probability": 0.430908203125}, {"start": 1829.86, "end": 1830.96, "word": " التفاعل", "probability": 0.7962646484375}, {"start": 1830.96, "end": 1831.28, "word": " هذا", "probability": 0.56201171875}, {"start": 1831.28, "end": 1831.58, "word": " لا", "probability": 0.478271484375}, {"start": 1831.58, "end": 1831.82, "word": " يوجد", "probability": 0.9396158854166666}, {"start": 1831.82, "end": 1832.0, "word": " فيه", "probability": 0.6329345703125}, {"start": 1832.0, "end": 1833.0, "word": " rearrangement", "probability": 0.55322265625}, {"start": 1833.0, "end": 1834.84, "word": " على", "probability": 0.740234375}, {"start": 1834.84, "end": 1835.34, "word": " الطرفين", "probability": 0.8995768229166666}, {"start": 1835.34, "end": 1835.74, "word": " الرامض", "probability": 0.8557942708333334}, {"start": 1835.74, "end": 1835.82, "word": " لا", "probability": 0.4833984375}, {"start": 1835.82, "end": 1835.98, "word": " يوجد", "probability": 0.8771158854166666}, {"start": 1835.98, "end": 1836.72, "word": " rearrangement", "probability": 0.9482421875}, {"start": 1836.72, "end": 1837.2, "word": " في", "probability": 0.900390625}, {"start": 1837.2, "end": 1837.7, "word": " وجود", "probability": 0.936279296875}, {"start": 1837.7, "end": 1838.44, "word": " الحامض", "probability": 0.9921875}, {"start": 1838.44, "end": 1838.98, "word": " أول", "probability": 0.93212890625}, {"start": 1838.98, "end": 1839.12, "word": " ما", "probability": 0.916015625}, {"start": 1839.12, "end": 1839.46, "word": " تأتي", "probability": 0.8229166666666666}, {"start": 1839.46, "end": 1839.6, "word": " ال", "probability": 0.84619140625}, {"start": 1839.6, "end": 1839.88, "word": " H", "probability": 0.93505859375}, {"start": 1839.88, "end": 1840.2, "word": " هنا", "probability": 0.931640625}, {"start": 1840.2, "end": 1840.34, "word": " و", "probability": 0.6328125}, {"start": 1840.34, "end": 1840.7, "word": " تعمل", "probability": 0.96533203125}, {"start": 1840.7, "end": 1841.1, "word": " positive", "probability": 0.84765625}], "temperature": 1.0}, {"id": 81, "seek": 187195, "start": 1843.07, "end": 1871.95, "text": "شو بيصير عندى؟ بيصير عندى الـ hydrate shift rearrangement الـ positive بيصير على هذا الموقع و الـ OH بتيجي على هذا الموقع إذا هنا الناتج مختلف تماما ولا لأ؟ أه فوجود طريقتين، الطريقتين لا يعطوا نفس الناتج مرات بيعطوا إذا مافيش إمكانية لل rearrangement لكن لو في إمكانية لل rearrangement ال rearrangement بتصير في وجود الحامض مابتصيرش في وجود الذئبق", "tokens": [8592, 2407, 4724, 1829, 9381, 13546, 43242, 7578, 22807, 4724, 1829, 9381, 13546, 43242, 7578, 2423, 39184, 5796, 4404, 5513, 39568, 518, 2423, 39184, 3353, 4724, 1829, 9381, 13546, 15844, 23758, 9673, 30543, 3615, 4032, 2423, 39184, 13931, 39894, 1829, 7435, 1829, 15844, 23758, 9673, 30543, 3615, 11933, 15730, 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0.9189453125}, {"start": 2073.01, "end": 2073.57, "word": " كل", "probability": 0.86474609375}, {"start": 2073.57, "end": 2073.85, "word": " هذا", "probability": 0.94580078125}, {"start": 2073.85, "end": 2074.39, "word": " الكلام", "probability": 0.9567057291666666}, {"start": 2074.39, "end": 2074.67, "word": " ايش", "probability": 0.6873372395833334}, {"start": 2074.67, "end": 2075.05, "word": " بضيف", "probability": 0.8048502604166666}, {"start": 2075.05, "end": 2075.57, "word": " عنده", "probability": 0.78955078125}], "temperature": 1.0}, {"id": 90, "seek": 209092, "start": 2077.04, "end": 2090.92, "text": "بيضيف H و OH، بيصير السؤال طيب إيش بيختلف عن الإضافة في وجود الحامض و عن الإضافة في وجود الذئبق؟", "tokens": [21292, 11242, 33911, 389, 4032, 13931, 12399, 4724, 1829, 9381, 13546, 21136, 33604, 6027, 23032, 1829, 3555, 11933, 1829, 8592, 4724, 1829, 46456, 46538, 18871, 33688, 11242, 31845, 3660, 8978, 49610, 23328, 21542, 10943, 11242, 4032, 18871, 33688, 11242, 31845, 3660, 8978, 49610, 23328, 32545, 19986, 3555, 4587, 22807], "avg_logprob": -0.12804687052965164, "compression_ratio": 1.5596330275229358, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 2077.04, "end": 2077.58, "word": "بيضيف", "probability": 0.7610677083333334}, {"start": 2077.58, "end": 2078.1, "word": " H", "probability": 0.81982421875}, {"start": 2078.1, "end": 2078.62, "word": " و", "probability": 0.875}, {"start": 2078.62, "end": 2079.72, "word": " OH،", "probability": 0.5069580078125}, {"start": 2079.72, "end": 2080.26, "word": " بيصير", "probability": 0.916748046875}, {"start": 2080.26, "end": 2080.94, "word": " السؤال", "probability": 0.9947916666666666}, {"start": 2080.94, "end": 2081.72, "word": " طيب", "probability": 0.8116861979166666}, {"start": 2081.72, "end": 2082.18, "word": " إيش", "probability": 0.8050944010416666}, {"start": 2082.18, "end": 2083.3, "word": " بيختلف", "probability": 0.98779296875}, {"start": 2083.3, "end": 2085.54, "word": " عن", "probability": 0.97607421875}, {"start": 2085.54, "end": 2086.36, "word": " الإضافة", "probability": 0.9852294921875}, {"start": 2086.36, "end": 2086.58, "word": " في", "probability": 0.98779296875}, {"start": 2086.58, "end": 2086.96, "word": " وجود", "probability": 0.984375}, {"start": 2086.96, "end": 2087.72, "word": " الحامض", "probability": 0.9514973958333334}, {"start": 2087.72, "end": 2088.78, "word": " و", "probability": 0.9150390625}, {"start": 2088.78, "end": 2088.96, "word": " عن", "probability": 0.86767578125}, {"start": 2088.96, "end": 2089.5, "word": " الإضافة", "probability": 0.9761962890625}, {"start": 2089.5, "end": 2089.66, "word": " في", "probability": 0.99560546875}, {"start": 2089.66, "end": 2090.02, "word": " وجود", "probability": 0.983154296875}, {"start": 2090.02, "end": 2090.92, "word": " الذئبق؟", "probability": 0.88203125}], "temperature": 1.0}, {"id": 91, "seek": 211273, "start": 2091.37, "end": 2112.73, "text": "الإضافة في وجود الحامد كانت Markovnikov لكن ممكن ال rearrangement الإضافة في وجود الذئبق Markovnikov بدون rearrangement الآن الإضافة بهذه الطريقة Anti Markovnikov نتيجتها عكس Markovnikov واضح؟ هذه الفرق", "tokens": [6027, 28814, 11242, 31845, 3660, 8978, 49610, 23328, 21542, 10943, 3215, 25961, 2655, 3934, 5179, 13123, 5179, 44381, 3714, 43020, 2423, 39568, 518, 33688, 11242, 31845, 3660, 8978, 49610, 23328, 32545, 19986, 3555, 4587, 3934, 5179, 13123, 5179, 47525, 11536, 39568, 518, 6024, 48506, 33688, 11242, 31845, 3660, 39627, 24192, 41950, 16572, 28671, 27757, 3934, 5179, 13123, 5179, 8717, 31371, 7435, 2655, 11296, 6225, 4117, 3794, 3934, 5179, 13123, 5179, 4032, 46958, 5016, 22807, 29538, 27188, 2288, 4587], "avg_logprob": -0.20510284093361866, "compression_ratio": 1.755813953488372, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 2091.37, "end": 2093.01, "word": "الإضافة", "probability": 0.743359375}, {"start": 2093.01, "end": 2093.15, "word": " في", "probability": 0.8359375}, {"start": 2093.15, "end": 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Markovnikov", "probability": 0.9764404296875}, {"start": 2110.53, "end": 2112.01, "word": " واضح؟", "probability": 0.79217529296875}, {"start": 2112.01, "end": 2112.27, "word": " هذه", "probability": 0.39208984375}, {"start": 2112.27, "end": 2112.73, "word": " الفرق", "probability": 0.8390299479166666}], "temperature": 1.0}, {"id": 92, "seek": 214289, "start": 2114.23, "end": 2142.89, "text": "Anti Markovnikov's addition بضيف عكس قاعدة Markovnikov هم لاحظين هنا إيش إحنا بنقول Anti Markovnikov's addition يعني لما يكون في عندي رابطة مش متماثلة على جهة Hydrogen أكتر ال H1 بتروح على اللحام ل Hydrogen أكتر ولا أقل في هذه الحالة؟ أقل لأن عكس قاعدة Markovnikov", "tokens": [35807, 72, 3934, 5179, 13123, 5179, 311, 4500, 4724, 11242, 33911, 6225, 4117, 3794, 12174, 995, 22488, 3660, 3934, 5179, 13123, 5179, 8032, 2304, 20193, 5016, 19913, 9957, 34105, 11933, 1829, 8592, 11933, 5016, 8315, 44945, 39648, 27757, 3934, 5179, 13123, 5179, 311, 4500, 37495, 22653, 5296, 15042, 7251, 30544, 8978, 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2748.62, "end": 2748.8, "word": " ال", "probability": 0.9599609375}, {"start": 2748.8, "end": 2749.1, "word": " OH", "probability": 0.74462890625}, {"start": 2749.1, "end": 2749.34, "word": " ون", "probability": 0.35205078125}, {"start": 2749.34, "end": 2749.82, "word": " بتيجي", "probability": 0.80712890625}, {"start": 2749.82, "end": 2750.42, "word": " هنا", "probability": 0.958984375}, {"start": 2750.42, "end": 2750.94, "word": " فى", "probability": 0.902587890625}, {"start": 2750.94, "end": 2751.3, "word": " هذه", "probability": 0.81982421875}, {"start": 2751.3, "end": 2752.24, "word": " الحالة", "probability": 0.9910481770833334}, {"start": 2752.24, "end": 2754.06, "word": " الأخيرة", "probability": 0.9557291666666666}, {"start": 2754.06, "end": 2755.48, "word": " Anti", "probability": 0.208251953125}, {"start": 2755.48, "end": 2756.48, "word": " Markovnikov", "probability": 0.8358154296875}, {"start": 2756.48, "end": 2757.08, "word": " addition", "probability": 0.77978515625}, 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2766.23, "word": " إذا", "probability": 0.597900390625}, {"start": 2766.23, "end": 2766.57, "word": " هذا", "probability": 0.74951171875}, {"start": 2766.57, "end": 2767.21, "word": " المثال", "probability": 0.9669596354166666}, {"start": 2767.21, "end": 2768.77, "word": " التلت", "probability": 0.6126302083333334}, {"start": 2768.77, "end": 2769.09, "word": " طرق", "probability": 0.97021484375}, {"start": 2769.09, "end": 2769.73, "word": " إضافة", "probability": 0.9815673828125}, {"start": 2769.73, "end": 2770.15, "word": " فيه", "probability": 0.979736328125}, {"start": 2770.15, "end": 2771.43, "word": " بتعطيه", "probability": 0.809716796875}, {"start": 2771.43, "end": 2772.97, "word": " كام", "probability": 0.602783203125}, {"start": 2772.97, "end": 2773.77, "word": " ناتج؟", "probability": 0.85321044921875}, {"start": 2773.77, "end": 2774.65, "word": " تلت", "probability": 0.92822265625}, {"start": 2774.65, "end": 2775.33, "word": " نواتج", "probability": 0.968505859375}, 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0.9934895833333334}, {"start": 2781.29, "end": 2781.67, "word": " لأ", "probability": 0.730712890625}, {"start": 2781.67, "end": 2781.89, "word": " بدكم", "probability": 0.63232421875}, {"start": 2781.89, "end": 2782.51, "word": " تفهموا", "probability": 0.987060546875}, {"start": 2782.51, "end": 2783.23, "word": " الفرق", "probability": 0.9851888020833334}, {"start": 2783.23, "end": 2784.03, "word": " بين", "probability": 0.9580078125}, {"start": 2784.03, "end": 2784.41, "word": " هذه", "probability": 0.7998046875}, {"start": 2784.41, "end": 2784.91, "word": " الطرق", "probability": 0.97607421875}, {"start": 2784.91, "end": 2785.77, "word": " التلاتة", "probability": 0.9718017578125}], "temperature": 1.0}, {"id": 120, "seek": 281346, "start": 2787.06, "end": 2813.46, "text": "الحالة الأولى Markovnikov addition with rearrangement مع الذئبق Markovnikov addition without rearrangement مع البورين Anti Markovnikov addition واضح هذا الكلام؟ هنا ضيعنا فيه محاضرة لما نسأل فيه سؤال واحد لازم 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{"start": 2787.66, "end": 2788.46, "word": " الأولى", "probability": 0.9742838541666666}, {"start": 2788.46, "end": 2789.3, "word": " Markovnikov", "probability": 0.8365478515625}, {"start": 2789.3, "end": 2789.64, "word": " addition", "probability": 0.87451171875}, {"start": 2789.64, "end": 2789.9, "word": " with", "probability": 0.9091796875}, {"start": 2789.9, "end": 2790.88, "word": " rearrangement", "probability": 0.865966796875}, {"start": 2790.88, "end": 2791.62, "word": " مع", "probability": 0.912109375}, {"start": 2791.62, "end": 2792.24, "word": " الذئبق", "probability": 0.818359375}, {"start": 2792.24, "end": 2793.08, "word": " Markovnikov", "probability": 0.96826171875}, {"start": 2793.08, "end": 2793.6, "word": " addition", "probability": 0.98095703125}, {"start": 2793.6, "end": 2794.1, "word": " without", "probability": 0.9208984375}, {"start": 2794.1, "end": 2795.16, "word": " rearrangement", "probability": 0.945556640625}, {"start": 2795.16, "end": 2795.78, "word": " مع", "probability": 0.94189453125}, {"start": 2795.78, "end": 2797.36, "word": " البورين", "probability": 0.7415364583333334}, {"start": 2797.36, "end": 2798.02, "word": " Anti", "probability": 0.2467041015625}, {"start": 2798.02, "end": 2799.06, "word": " Markovnikov", "probability": 0.8934326171875}, {"start": 2799.06, "end": 2799.42, "word": " addition", "probability": 0.93408203125}, {"start": 2799.42, "end": 2799.82, "word": " واضح", "probability": 0.9560546875}, {"start": 2799.82, "end": 2800.06, "word": " هذا", "probability": 0.97119140625}, {"start": 2800.06, "end": 2801.22, "word": " الكلام؟", "probability": 0.837158203125}, {"start": 2801.22, "end": 2801.46, "word": " هنا", "probability": 0.355224609375}, {"start": 2801.46, "end": 2801.86, "word": " ضيعنا", "probability": 0.7727864583333334}, {"start": 2801.86, "end": 2802.1, "word": " فيه", "probability": 0.8916015625}, {"start": 2802.1, "end": 2802.76, "word": " محاضرة", "probability": 0.9871826171875}, {"start": 2802.76, "end": 2804.0, "word": " لما", "probability": 0.7447509765625}, {"start": 2804.0, "end": 2804.48, "word": " نسأل", "probability": 0.9879150390625}, {"start": 2804.48, "end": 2804.72, "word": " فيه", "probability": 0.92578125}, {"start": 2804.72, "end": 2805.06, "word": " سؤال", "probability": 0.9959309895833334}, {"start": 2805.06, "end": 2805.68, "word": " واحد", "probability": 0.994873046875}, {"start": 2805.68, "end": 2807.34, "word": " لازم", "probability": 0.9459635416666666}, {"start": 2807.34, "end": 2807.68, "word": " كلكوا", "probability": 0.7411295572916666}, {"start": 2807.68, "end": 2808.4, "word": " تجاوبوه", "probability": 0.9490559895833334}, {"start": 2808.4, "end": 2809.6, "word": " واضح؟", "probability": 0.874267578125}, {"start": 2809.6, "end": 2809.74, "word": " واللي", "probability": 0.7718098958333334}, {"start": 2809.74, "end": 2809.92, "word": " مش", "probability": 0.99267578125}, {"start": 2809.92, "end": 2810.6, "word": " فاهمه", "probability": 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e761c8cc601ebb49eb31138f8d8ba63e9a6bf0ae
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ND0aZxwnAGI_postprocess.srt
@@ -0,0 +1,1836 @@
+1
+00:00:05,670 --> 00:00:13,010
+ما زلنا في موضوع تفاعلات الإضافة للـ aldehydes و
+
+2
+00:00:13,010 --> 00:00:17,250
+الـ ketones هذا الحقيقة التفاعل اللي لان بده يمر
+
+3
+00:00:17,250 --> 00:00:22,990
+علينا هو تفاعل ham
+
+4
+00:00:24,030 --> 00:00:28,550
+السوديوم الهيدروجين السلفيت للألديهيد والكيتون
+
+5
+00:00:28,550 --> 00:00:33,670
+طبعا السوديوم الهيدروجين السلفيت في النهاية
+
+6
+00:00:33,670 --> 00:00:40,330
+بيتفاعل مع سواء الألديهيد أو الكيتون هذا ألديهيد
+
+7
+00:00:40,330 --> 00:00:45,250
+وهذا كيتون زي ما انتوا شايفين من خلال السلفر اللي
+
+8
+00:00:45,250 --> 00:00:50,310
+موجود هنا بيصير عندنا رابطة S double bond O double
+
+9
+00:00:50,310 --> 00:00:57,590
+bond OO-NA+, بناءً على ذلك هو بيعطينا solved يعني
+
+10
+00:00:57,590 --> 00:01:03,050
+هذه الـ S O 3 minus NA plus هي عبارة عن هذا الشكل
+
+11
+00:01:03,050 --> 00:01:08,770
+S double bond O double bond O O minus NA plus
+
+12
+00:01:08,770 --> 00:01:15,950
+واضح؟ هي تفصيلها زي ما بتلاحظوا ان هذا المركب ان
+
+13
+00:01:15,950 --> 00:01:23,970
+هذا المركب الناتج هو عبارة عنIonic compound يعني
+
+14
+00:01:23,970 --> 00:01:30,050
+plus و minus عبارة عن ions وبناء على ذلك هذا
+
+15
+00:01:30,050 --> 00:01:35,430
+المركب الايوني بيكون عادة بدوب في الميه
+
+16
+00:01:38,750 --> 00:01:44,830
+نتطلع على ال .. طبعا ال .. ال lower aldehydes و
+
+17
+00:01:44,830 --> 00:01:48,670
+ketones زي ال acetaldehyde و زي ال acetone هدول
+
+18
+00:01:48,670 --> 00:01:52,630
+بدوبوا في الميه، لكن السؤال لو ال aldehyde كبر صار
+
+19
+00:01:52,630 --> 00:01:58,390
+خمس درات كربون، بيبطل يدوب في الميهالان فائدة هذا
+
+20
+00:01:58,390 --> 00:02:03,330
+التفاعل حقيقة انه بيستعمل في عملية تنقية ال
+
+21
+00:02:03,330 --> 00:02:07,630
+الديهيد والكيتون يعني هذا ال الديهيد او ال كيتون
+
+22
+00:02:07,630 --> 00:02:14,330
+خلينا نقول organic مركب أطوىو موجود مع أشياء تانية
+
+23
+00:02:14,330 --> 00:02:19,850
+كلها مخلوطة مع بعض مع organic compounds مخلوطين مع
+
+24
+00:02:19,850 --> 00:02:23,690
+بعض واضح أنا لما بفعله مع ال sodium hydrogen
+
+25
+00:02:23,690 --> 00:02:29,290
+sulfide هذا بحوله إلى salt ال salt بيكون بدوب في
+
+26
+00:02:29,290 --> 00:02:34,190
+الميه باقى المركبات بتظهر في ال solvent ال organic
+
+27
+00:02:34,190 --> 00:02:41,130
+باخد الميهوبعاود أضيف عليها base .. برجع للالدهايد
+
+28
+00:02:41,130 --> 00:02:46,610
+أو الكيتون النقي واضحة الفكرة؟ مرة تانية بيكون عند
+
+29
+00:02:46,610 --> 00:02:51,290
+أنا الالدهايد والكيتون مع other organic compounds
+
+30
+00:02:51,290 --> 00:02:57,310
+كيف بدي أنقيه، أفصله لوحده؟ الآن الالدهايد أو
+
+31
+00:02:57,310 --> 00:03:00,530
+الكيتون بتفاعل مع ال sodium hydrogen sulfide
+
+32
+00:03:00,530 --> 00:03:04,750
+وبيعطيني ionic compound هذا ال ionic compound إيش
+
+33
+00:03:04,750 --> 00:03:10,600
+إحنا بيقول عنه؟ water؟سوليومن بناء على ذلك أنا
+
+34
+00:03:10,600 --> 00:03:16,920
+باخد طبقة الميه بيكون بس اللي دايب فيها هذا المركب
+
+35
+00:03:16,920 --> 00:03:19,520
+اللي نشعل الدايد والكيتون باقي ال organic
+
+36
+00:03:19,520 --> 00:03:23,100
+compounds ال impurities كلها بتكون في ال organic
+
+37
+00:03:23,100 --> 00:03:27,440
+layer مابديش إياها باخد الميه بضيف عليها شوية base
+
+38
+00:03:28,120 --> 00:03:33,660
+أو أسد فبصير التفاعل العكسي برجع هذا بتكون و برجع
+
+39
+00:03:33,660 --> 00:03:37,960
+ال الديهيد والكيتون بتكون ك organic compound نقي
+
+40
+00:03:37,960 --> 00:03:42,740
+فهذه الطريقة اللي هي طريقة إضافة ال sodium
+
+41
+00:03:42,740 --> 00:03:48,040
+hydrogen sulfide is a method to purify الديهيد و
+
+42
+00:03:48,040 --> 00:03:53,830
+الكيتون by changing them toIonic compounds water
+
+43
+00:03:53,830 --> 00:03:58,850
+soluble Ionic compounds بناخد الميه بس بيكون فيها
+
+44
+00:03:58,850 --> 00:04:04,110
+مركب ال الديهايد او ال كيتون على شكل ايون بعدين
+
+45
+00:04:04,110 --> 00:04:09,390
+بتفاعل عكسي برجع ل الديهايد و كيتون نقي واضح هذه
+
+46
+00:04:09,390 --> 00:04:16,330
+قصة يعني تطبيقيةالأساس فيها اللي هو addition يعني
+
+47
+00:04:16,330 --> 00:04:19,810
+هنا في النهاية برضه اللي صار عملية addition هيكوا
+
+48
+00:04:19,810 --> 00:04:23,190
+شايفين ال nucleophile و السيدة و البندقش و سارة
+
+49
+00:04:23,190 --> 00:04:27,410
+الاساس فيها عملية addition
+
+50
+00:04:35,920 --> 00:04:42,080
+بعد هيك .. بعد هيك بنيجي لنوع تاني .. لنوع تاني من
+
+51
+00:04:42,080 --> 00:04:47,700
+تفاعلات ال الديهيدس والكيتونز طبعا ال الديهيدس
+
+52
+00:04:47,700 --> 00:04:52,720
+والكيتونز احنا بنقدر نعتبرهم مثل البني آدم اللي
+
+53
+00:04:52,720 --> 00:04:58,080
+واقف على نص الدرج واضح؟ يعني لو في عندنا درج معين
+
+54
+00:04:58,080 --> 00:05:02,060
+وفي بني آدم واقف على نص الدرج شو الاحتمالات اللي
+
+55
+00:05:02,060 --> 00:05:08,300
+عنده؟ اللي يطلع لفوق؟أو ينزل لتحت الان ايش قصته
+
+56
+00:05:08,300 --> 00:05:13,720
+هذا الدرج و ان ال aldehyde و ال ketone واقف على نص
+
+57
+00:05:13,720 --> 00:05:18,880
+الدرج هذا قصته بتجيني في موضوع الأكسدة و الاختزال
+
+58
+00:05:18,880 --> 00:05:25,520
+لما انا بحكي بقول في عندى alcohol R O H و في عندى
+
+59
+00:05:25,520 --> 00:05:28,960
+بعد هيك ال aldehydes و ال ketones اللي هم ال R C
+
+60
+00:05:28,960 --> 00:05:36,190
+double bond O H و ال R C double bond O Rواضح هذا
+
+61
+00:05:36,190 --> 00:05:41,970
+الكهول وهذا الديهايد وكيتون بعد ذلك يأتي ال R-C-O
+
+62
+00:05:41,970 --> 00:05:50,770
+-H الاسد الآن هذولا التلاتة احنا بنقدر نتحرك بينهم
+
+63
+00:05:50,770 --> 00:05:55,030
+وسبق مر علينا هذا الكلام من خلال عمليات الأكسدة
+
+64
+00:05:55,030 --> 00:05:59,610
+والاختزال بمعنى الالكهول انا ممكن اعمله oxidation
+
+65
+00:05:59,610 --> 00:06:03,950
+يصير الديهايد الديهايد ممكن اعمله oxidation
+
+66
+00:06:06,470 --> 00:06:11,510
+الاسد ممكن اعمله reduction يرجع الديهيد ممكن اعمله
+
+67
+00:06:11,510 --> 00:06:16,850
+reduction يرجع الكول لما بقاجي انا هنا للديهيد
+
+68
+00:06:16,850 --> 00:06:21,830
+والكيتون موجودين في نص الطريق بمعنى ممكن انا اعمل
+
+69
+00:06:21,830 --> 00:06:28,140
+عملية reduction اختزانبيرجع ال الديهايد في الكيتون
+
+70
+00:06:28,140 --> 00:06:32,700
+لالكهولز و ممكن اعمل لهم oxidation لل الديهايد من
+
+71
+00:06:32,700 --> 00:06:37,020
+اللي الكيتون مابتأكسدش لل الديهايد بيصير ايش؟ acid
+
+72
+00:06:37,020 --> 00:06:40,800
+هذه العملية oxidation واضح؟
+
+73
+00:06:43,500 --> 00:06:48,760
+إذا كأنه ال الديهيد اللي بنص الطريق أو بنعنو بنص
+
+74
+00:06:48,760 --> 00:06:54,640
+الدرج ممكن أنزل فيه أرجعه لالكهول و ممكن أعمله
+
+75
+00:06:54,640 --> 00:06:59,940
+أكسدة و يصير حامض و لذلك هدول التفاعلين بدنا
+
+76
+00:06:59,940 --> 00:07:04,880
+ندرسهم و نركز عليهم اللي هم reduction of aldehydes
+
+77
+00:07:04,880 --> 00:07:10,800
+و oxidation of aldehydes لإن هم جايين وين؟في نص
+
+78
+00:07:10,800 --> 00:07:14,920
+الطريق طبعا في عندى كمان reduction of ketones بس
+
+79
+00:07:14,920 --> 00:07:18,400
+مافيش عنده oxidation of ketones الكيتونز
+
+80
+00:07:18,400 --> 00:07:23,880
+مابتتأكسدش لحمض لكن اللي بتأكسد ال الديهايد واضح؟
+
+81
+00:07:23,880 --> 00:07:29,860
+عشان مافيش فيها H الكيتون الآن شو العوامل المؤكسدة
+
+82
+00:07:29,860 --> 00:07:33,960
+والمختزلة اللي بدها تدرس؟ أول اشي بندرس عملية
+
+83
+00:07:35,390 --> 00:07:43,690
+الاختزال اول اشهر العوامل المختزلة العاملين هدولة
+
+84
+00:07:43,690 --> 00:07:48,250
+اللي موجودين هنا اللي هم الليثيوم مع الالومنيوم و
+
+85
+00:07:48,250 --> 00:07:53,250
+4 ذرات هيدروجين على شكل هيدرايد فبسموه lithium
+
+86
+00:07:53,250 --> 00:07:56,450
+tetrahydroaluminate
+
+87
+00:07:56,940 --> 00:08:02,560
+الحقيقة بصراحة هذا الاسم يمكن مش كتير مستعمل في
+
+88
+00:08:02,560 --> 00:08:06,040
+اسم تاني أكثر شهرة و أكثر استعمالي يعني خلّيني
+
+89
+00:08:06,040 --> 00:08:08,580
+أقول يمكن عشرة في المية من الناس بيحكوا بهذا
+
+90
+00:08:08,580 --> 00:08:13,600
+الطريقة و الباقي بيقولوا عنه Lithium Aluminum
+
+91
+00:08:13,600 --> 00:08:18,460
+Hydride واضح؟ يعني هذا سواء شفتوا بهذا الاسم أو
+
+92
+00:08:18,460 --> 00:08:26,140
+بالاسم الأشهر Lithium Aluminum Hydride
+
+93
+00:08:26,570 --> 00:08:33,370
+هذا عبارة عن عامل مختصر و العامل التاني اللي كثير
+
+94
+00:08:33,370 --> 00:08:37,470
+الاستعمال برضه اللي هو ال sodium tetrahydride و
+
+95
+00:08:37,470 --> 00:08:44,130
+borate برضه هذا بيسموه sodium borohydride
+
+96
+00:08:44,130 --> 00:08:50,090
+sodium borohydride لما أنا كنت اسمع تانية مايعرفش
+
+97
+00:08:50,090 --> 00:08:52,990
+حوالين اللي ألقاني و مصر مايعرفش أكملت هدروجين
+
+98
+00:08:52,990 --> 00:08:58,890
+بالتحديدبظبط لكن في النهاية اسم شهرة يعني لما ينقل
+
+99
+00:08:58,890 --> 00:09:05,130
+lithium aluminium hydride صح مش مبين بس خبرة الناس
+
+100
+00:09:05,130 --> 00:09:11,110
+انه lithium AlH4 واضح؟ و لما بنقول sodium
+
+101
+00:09:11,110 --> 00:09:20,200
+borohydride NaBH4 واضح؟فسواء شفته بهذا الإسم أو
+
+102
+00:09:20,200 --> 00:09:25,560
+شفته بهذا الإسم هدولة هما أشهر العوامل المختزلة
+
+103
+00:09:25,560 --> 00:09:31,280
+اللي تستعمل لاختزال ال الديهيد والكيتون واضح؟ الآن
+
+104
+00:09:31,280 --> 00:09:35,740
+اللي بيصير عندي ببساطة لو أنا أخدت مثلا ال
+
+105
+00:09:35,740 --> 00:09:40,800
+acetaldehydeفعلته مع hydride لحظة انا حاطط اتنين
+
+106
+00:09:40,800 --> 00:09:43,900
+وبين جثين ال H اللي هي ال hydride اكيد انتوا
+
+107
+00:09:43,900 --> 00:09:48,060
+بتميزوا كلمة hydride عن ال proton ال hydride ايش
+
+108
+00:09:48,060 --> 00:09:53,660
+معناها H minus ال proton H plus مرة تانية بنذكر
+
+109
+00:09:53,660 --> 00:10:00,140
+فيها ال H plus ايش اسمها ال proton و ال H minus
+
+110
+00:10:05,660 --> 00:10:14,120
+هنا التفاعل ببساطة هو عبارة عن تفاعل addition و لو
+
+111
+00:10:14,120 --> 00:10:18,340
+احنا ماخدينه تحت عنوان reduction of aldehydes and
+
+112
+00:10:18,340 --> 00:10:23,220
+ketones انا في عندي ببساطة H مع أزواج إلكتروناد
+
+113
+00:10:23,220 --> 00:10:27,900
+يعني H minus الآن هذه عبارة عن النيوكليوفايل وهي
+
+114
+00:10:27,900 --> 00:10:31,920
+الـC double bond O شو التفاعل المتوقع؟ ان هذا
+
+115
+00:10:31,920 --> 00:10:37,890
+النيوكليوفايل بده نهاجم وهذهتصير OH واضح نفس
+
+116
+00:10:37,890 --> 00:10:41,770
+الكلام اللي كنا نحكيه المرة الماضية ان هاي ال
+
+117
+00:10:41,770 --> 00:10:46,870
+nucleophile و هاي ال C double bond O صارت OH
+
+118
+00:10:46,870 --> 00:10:54,590
+فحقيقة ضمن هذا المبدأ بتكون عملية ال reduction of
+
+119
+00:10:54,590 --> 00:10:58,770
+aldehydes and ketones using sodium or sodium
+
+120
+00:10:58,770 --> 00:11:01,950
+borohydride or lithium aluminum hydride is an
+
+121
+00:11:01,950 --> 00:11:07,340
+addition reactionفي محصلة هو addition reaction و
+
+122
+00:11:07,340 --> 00:11:13,000
+ال nucleophile is the hydride anion ال nucleophile
+
+123
+00:11:13,000 --> 00:11:19,260
+is the hydride anion واضح؟ طبعا ال hydride anion
+
+124
+00:11:19,260 --> 00:11:24,160
+لأنه ببساطة الألمنيوم بشكل عام بيكون حامل hydride
+
+125
+00:11:24,160 --> 00:11:28,500
+زايدة الألمنيوم عادة بيكون حامل تلت روابط بستة
+
+126
+00:11:28,500 --> 00:11:32,900
+عشان يصل تمانية بيحمل hydride زايدة لما بفقدها هذه
+
+127
+00:11:32,900 --> 00:11:38,930
+ال hydride زيادةبيجي بيعمل addition reaction
+
+128
+00:11:38,930 --> 00:11:49,470
+فبيتحول ال الديهيد إلى ال primary alcohol بلاحظين
+
+129
+00:11:49,470 --> 00:11:53,070
+انتوا ال الديهيد صار اي نوع من ال alcohol primary
+
+130
+00:11:53,070 --> 00:11:59,370
+ال الديهيد لما تطلع ICH2 ال primary alcohol بعد
+
+131
+00:11:59,370 --> 00:12:06,030
+شوية لما بنيجي نعمل reduction لل ketoneبيصير
+
+132
+00:12:06,030 --> 00:12:11,310
+بإمكانكم تتطلعوا هنا هي الكيتون و إجت ال H هاجمت و
+
+133
+00:12:11,310 --> 00:12:16,830
+صار عنده هي ال nucleophile و هي ال OH صار عنده
+
+134
+00:12:16,830 --> 00:12:21,330
+secondary alcohol إذا هذه من الجملة اللي أنتوا
+
+135
+00:12:21,330 --> 00:12:27,370
+بدكم تكونوا عارفينها أنه بال reduction بال
+
+136
+00:12:27,370 --> 00:12:33,710
+reduction ال aldehyde شو بده يصير ال primary
+
+137
+00:12:33,710 --> 00:12:34,250
+alcohol
+
+138
+00:12:38,420 --> 00:12:44,820
+بتصير secondary واضحة هذه النقطة هاي اللي هي عملية
+
+139
+00:12:44,820 --> 00:12:51,440
+ال reduction انا بقيالي مش عملية صعبة الكلام فيها
+
+140
+00:12:51,440 --> 00:12:56,340
+واضح بالذات اذا احنا بنفهمها ان هي عملية addition
+
+141
+00:12:56,340 --> 00:13:01,120
+of a hydride انا يعني بطلت مختلفة عن كل عمليات ال
+
+142
+00:13:01,120 --> 00:13:05,220
+additions السابقة مش مختلفة عن عمليات ال additions
+
+143
+00:13:05,220 --> 00:13:12,960
+السابقةطبعا هنا ممكن احاول اعمللكم ايش ال
+
+144
+00:13:12,960 --> 00:13:17,400
+mechanism ايش ال mechanism of addition مش كتير
+
+145
+00:13:17,400 --> 00:13:23,500
+بصراحة بهم عندى انه نتطلع عليها لكن لو بتطلعوا
+
+146
+00:13:23,500 --> 00:13:28,700
+الاساس فيها ان انتوا بتجيبوا ايون هيدرايد و تخلوه
+
+147
+00:13:28,700 --> 00:13:34,670
+اهاجم واضح؟ مش كتير مهتمين في هذهنفس الشيء إذا
+
+148
+00:13:34,670 --> 00:13:40,410
+استعملنا الـ Sodium Borohydride المحصلة تماما نفس
+
+149
+00:13:40,410 --> 00:13:44,810
+الشيء تماما، واضح؟ يعني سواء قلنا Lithium Aluminum
+
+150
+00:13:44,810 --> 00:13:51,590
+Hydride أو Sodium Borohydride النتيجة واحدة إضافة
+
+151
+00:13:51,590 --> 00:13:57,530
+H minus وتحويل الـ C double bond O إلى OH أو أكثر
+
+152
+00:13:57,530 --> 00:14:02,890
+من هيك، مابلزمناشواضح؟ عشان انا لما بتيجوا
+
+153
+00:14:02,890 --> 00:14:07,070
+بتتطلعوا على أمثلة هاي Lithium Aluminum Hydride،
+
+154
+00:14:07,070 --> 00:14:09,850
+هاي Sodium Borohydride، هاي Sodium Borohydride،
+
+155
+00:14:09,850 --> 00:14:17,430
+هاي Lithium Aluminum Hydride، هاي
+
+156
+00:14:17,430 --> 00:14:17,750
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+157
+00:14:17,750 --> 00:14:19,050
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+158
+00:14:19,050 --> 00:14:21,050
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+159
+00:14:21,050 --> 00:14:21,570
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+160
+00:14:21,570 --> 00:14:21,610
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+161
+00:14:21,610 --> 00:14:22,010
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+162
+00:14:22,010 --> 00:14:25,650
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+163
+00:14:25,650 --> 00:14:30,450
+Sodium Borohydride، هاي Sodium Borohydride، هاي
+
+164
+00:14:33,570 --> 00:14:38,070
+الكيتول صار secondary alcohol والالديهيد صار
+
+165
+00:14:38,070 --> 00:14:41,650
+primary alcohol والالديهيد اللي هان صار primary
+
+166
+00:14:41,650 --> 00:14:50,120
+alcoholطبعا .. ربما سهولة ال .. سهولة الكيميا وين
+
+167
+00:14:50,120 --> 00:14:55,720
+ان انتوا .. ايش ما بدوا يكبر الجزائع عندكم تكونوا
+
+168
+00:14:55,720 --> 00:14:59,520
+عارفين ان انتوا بتتعاملوا مع رأس للتفاعل يعني ايش
+
+169
+00:14:59,520 --> 00:15:03,380
+يكون المركب هنا .. هذا المركب هذا .. فيه اشي كتير
+
+170
+00:15:03,380 --> 00:15:08,020
+هنا .. كل هذا الكلام .. كل هذا الكلام بالنسبة لي
+
+171
+00:15:08,020 --> 00:15:13,120
+.. كل هذا الكلام بالنسبة لي هو يمثل عملية نسخ و
+
+172
+00:15:13,120 --> 00:15:13,520
+لاسخ
+
+173
+00:15:16,400 --> 00:15:20,580
+تلاحظون؟ كل هذا الكلام يمثل بالنسبة إلى عملية نسخ
+
+174
+00:15:20,580 --> 00:15:27,160
+و لصق لكن محور التفاعن الأساسي أنه .. أن هذه
+
+175
+00:15:27,160 --> 00:15:34,200
+المجموعة ستصبح CH2OH، فقط، خلّصنا الأن، إن شاء
+
+176
+00:15:34,200 --> 00:15:38,920
+الله بعد ذلك، هذه المجموعة نربطها بقطار هنا، ليس
+
+177
+00:15:38,920 --> 00:15:42,100
+لازم تخافوا من المسألة و تقولوا بيجينا سؤال في
+
+178
+00:15:42,100 --> 00:15:49,230
+جزيات معقدةواضح؟ هاي محور التفاعل هذا نفس الاشياء
+
+179
+00:15:49,230 --> 00:15:56,490
+لاحظوا مثلا حطلكم Cyclopropyl وحطلكم Methyl إيش ما
+
+180
+00:15:56,490 --> 00:15:59,730
+أحط و أحط ان شاء الله أحطون أشياء أنا عندي C
+
+181
+00:15:59,730 --> 00:16:04,690
+double bond O تبعت كيتون، هذا محور التفاعل، شو
+
+182
+00:16:04,690 --> 00:16:11,190
+بتصير؟ بتصير O H و بتجيل الـH من بره، باقي الأشياء
+
+183
+00:16:13,100 --> 00:16:20,020
+زي ما هي مش محور التفاعل يمكن بهذا التفاعل هانا
+
+184
+00:16:20,020 --> 00:16:25,620
+كان عامل Acetal هانا كان عامل Acetal وبإضافة الحمض
+
+185
+00:16:25,620 --> 00:16:33,580
+كسر ال Acetal كخطوة نهائية مش كثير مهم عندى هذه
+
+186
+00:16:33,580 --> 00:16:37,060
+الشغله لكن المهم برضه عندى هانا انها السيطه بال
+
+187
+00:16:37,060 --> 00:16:47,050
+bond OH هي محور التفاعل اللى صارتCH2OH واضح CH2OH
+
+188
+00:16:47,050 --> 00:16:53,130
+واضح هذا الاسيتال عادة بتنكسر في وجود الحمض في آخر
+
+189
+00:16:53,130 --> 00:17:01,170
+التفاعل مش الموضوع ها نفس الشيء ال CH2OH ال ketone
+
+190
+00:17:01,170 --> 00:17:08,240
+صارت CHالان لو كانت على حلقة خماسية او سوداسية او
+
+191
+00:17:08,240 --> 00:17:12,240
+سباعية او تمانية او حلقة كبيرة معجدة ايش ما كانت
+
+192
+00:17:12,240 --> 00:17:18,220
+تكون انا بيفرج عندى اه و هنا بيبدأ يصير انه ليش
+
+193
+00:17:18,220 --> 00:17:21,300
+بعض الناس بتعاملوا مع المعادلات الكيميائية بسهولة
+
+194
+00:17:21,300 --> 00:17:26,320
+و البعض مابتعاملش بسهولة اللي بيفهم المحور الأساسي
+
+195
+00:17:26,320 --> 00:17:30,590
+في السؤال هو اللي بتعامل بسهولةالمحور الأساسي أن
+
+196
+00:17:30,590 --> 00:17:35,570
+الكيميا عبارة عن قصة مجموعات وظيفية، يعني رؤوس
+
+197
+00:17:35,570 --> 00:17:41,050
+تتفاعل مع بعض، بس هذه الرؤوس، الآن باقي الأشياء
+
+198
+00:17:41,050 --> 00:17:46,410
+بتظهر زي ما هي، مابتصيرش فيها تغيير بشكل عام
+
+199
+00:17:59,610 --> 00:18:04,770
+بيجينا تفاعل إضافة جديد إحنا اتفقنا إن الـ
+
+200
+00:18:04,770 --> 00:18:10,930
+reduction في النهاية is an addition reaction تفاعل
+
+201
+00:18:10,930 --> 00:18:15,170
+كتير مهم اللي هو reaction with green yard reagent
+
+202
+00:18:15,170 --> 00:18:20,770
+تفاعل الألديهيدز والكيتونز مع green yard reagent
+
+203
+00:18:20,770 --> 00:18:26,750
+ربما البعض منكم ربما البعض منكم يكون نسي يكون نسي
+
+204
+00:18:26,750 --> 00:18:31,330
+ال green yard reagentمر علينا .. وين ال green يا
+
+205
+00:18:31,330 --> 00:18:37,430
+اردري ايه جد .. في chapter ال ethers .. في chapter
+
+206
+00:18:37,430 --> 00:18:43,710
+ال ethers احنا قلنا لما يكون عندنا RX انفعلها مع
+
+207
+00:18:43,710 --> 00:18:50,550
+ال MG في وجود ال dry ether بيعطينا R
+
+208
+00:19:00,220 --> 00:19:04,420
+مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس مجيكس
+
+209
+00:19:04,420 --> 00:19:08,360
+مجيكس
+
+210
+00:19:08,360 --> 00:19:11,900
+مجيكس
+
+211
+00:19:11,900 --> 00:19:18,380
+مجيكس مجيكس مجيكسمن خلاله، فللـ Green Yard Reagent
+
+212
+00:19:18,380 --> 00:19:23,580
+عبارة عن R نيوكليوفايل في الآخر بس زم أنا قلت لـ
+
+213
+00:19:23,580 --> 00:19:27,100
+Green Yard Reagent هو R نيوكليوفايل إذا خلصنا شغل
+
+214
+00:19:27,100 --> 00:19:31,300
+بدي أخد أي ألديهيدوكيتون و أتخيل إن أنا بفعله مع R
+
+215
+00:19:31,300 --> 00:19:36,960
+مع أزواج الإلكترونات تبعتها طبعا هي بتكون مرتبطة
+
+216
+00:19:36,960 --> 00:19:46,150
+بالـ MgBr بس كتفاعل R مع أزواج الإلكتروناتمرة
+
+217
+00:19:46,150 --> 00:19:49,930
+تانية هذا عبارة عن ال addition reaction بهذا الشكل
+
+218
+00:19:49,930 --> 00:19:55,690
+و هذا بتصير OH في النهاية طبعا احنا بنضيف لغرينيا
+
+219
+00:19:55,690 --> 00:20:01,770
+و بعد هيك بنضيف له حامض مع ميه فالنهاية لما
+
+220
+00:20:01,770 --> 00:20:05,690
+بتكتيجوا تتطلعوا هنا هاي لغرينيا بفادل مثال عبارة
+
+221
+00:20:05,690 --> 00:20:13,940
+عن مجموعة إيش ال R اللي هنا CH3 CH2في النتج انها
+
+222
+00:20:13,940 --> 00:20:20,300
+هتشوفوا CH3 CH2 إجت كمجموعة و الـ CW bond O صارت
+
+223
+00:20:20,300 --> 00:20:26,140
+OH هم لاحظين هذا المستطيل و ال .. هاي ال addition
+
+224
+00:20:26,140 --> 00:20:31,260
+هذا ال nuclear file و هاي ال CW bond O صارت OH
+
+225
+00:20:31,260 --> 00:20:33,660
+واضح؟
+
+226
+00:20:37,040 --> 00:20:44,380
+التفاعل مع الادهايط و الكيتون هو اتفاعل اضافي طبعا
+
+227
+00:20:44,380 --> 00:20:48,880
+كتطبيق ليس أسهل منه نحضر الـR و نفعلها و نضع الـc
+
+228
+00:20:48,880 --> 00:20:54,600
+double bond O من خلّيها O H لكن متعودين احنا الآن
+
+229
+00:20:54,600 --> 00:21:00,700
+نميز النواتج اللي بتطلع متعودين نميز النواتج اللي
+
+230
+00:21:00,700 --> 00:21:03,000
+بتطلع وهذا الكلام هتشوفوه هنا
+
+231
+00:21:08,360 --> 00:21:14,260
+إنه هذا الـ Greenyard Reagent ممكن نفعله مع أبسط
+
+232
+00:21:14,260 --> 00:21:18,320
+الديهيد في الدنيا اللي هو الـ Formal Dehyde ممكن
+
+233
+00:21:18,320 --> 00:21:22,780
+نفعله مع أي الديهيد تاني غير الـ Formal Dehyde و
+
+234
+00:21:22,780 --> 00:21:27,620
+ممكن نفعله مع الـ Ketone واضح؟
+
+235
+00:21:29,380 --> 00:21:33,220
+طريقة التفاعل أنه بدأ تأتي من مجموعة أتجرنيار و
+
+236
+00:21:33,220 --> 00:21:39,000
+الـ CWbO تصير OH هذا كلام متفق عليه مافيش فيه أي
+
+237
+00:21:39,000 --> 00:21:42,520
+مشكلة يعني هنا لما استعملنا مجموعة الاثل هاي
+
+238
+00:21:42,520 --> 00:21:47,720
+مجموعة الاثل حطناها بصندوق و الـ CWbO صارت OH و
+
+239
+00:21:47,720 --> 00:21:51,200
+نفس الاشي مع الاسيتالديهيد الو الديهيد أكبر هاي
+
+240
+00:21:51,200 --> 00:21:56,450
+مجموعة الاثل و الـ CWbO صارتأو أتش وهنا مع
+
+241
+00:21:56,450 --> 00:22:00,350
+الاسيتون هاي مجموعة ال إفل و ال C double bond O
+
+242
+00:22:00,350 --> 00:22:06,070
+صارت أو أتش إذا أنا بحكي عن addition و نفسي
+
+243
+00:22:06,070 --> 00:22:12,510
+التفاعل لكن لما أجي أطلع على نوع الناتج لما أجي
+
+244
+00:22:12,510 --> 00:22:16,870
+أطلع على نوع الناتج بلاحظ أنه انا لو فعلت ال green
+
+245
+00:22:16,870 --> 00:22:21,790
+yard مع ال formal دي هادي بيطلع عندى primary
+
+246
+00:22:21,790 --> 00:22:29,930
+alcoholتطلع هذا CH2OH إذا الناتج هنا primary
+
+247
+00:22:29,930 --> 00:22:35,970
+alcohol ولو فعلت ال green yard مع أي aldehyde تاني
+
+248
+00:22:35,970 --> 00:22:39,530
+أكبر من ال formaldehyde كمثال هنا الacetaldehyde
+
+249
+00:22:39,530 --> 00:22:46,010
+بيطلع عندى secondary alcohol ولو فعلت ال green
+
+250
+00:22:46,010 --> 00:22:51,210
+yard مع ال ketone بيطلع عندى tertiary alcohol
+
+251
+00:22:54,330 --> 00:23:00,270
+رغم ان انا بحكي على نفس التفاعل بنفس النمط لكن
+
+252
+00:23:00,270 --> 00:23:06,110
+النواتج عندى مختلفة ان التفاعل مع ال Formal Dehyde
+
+253
+00:23:06,110 --> 00:23:11,530
+بيعطينى Primary Alcohol التفاعل مع Any Other
+
+254
+00:23:11,530 --> 00:23:16,690
+Aldehyde بيعطينى Secondary Alcohol والتفاعل مع ال
+
+255
+00:23:16,690 --> 00:23:21,810
+Ketones بيعطينى Tertiary Alcoholهذا كلام طبعا
+
+256
+00:23:21,810 --> 00:23:27,350
+بالنسبة للكيميائيين أكثر من ممتاز لأنه بصير عند
+
+257
+00:23:27,350 --> 00:23:31,650
+الطرق من خلالها أقدر أحضر primary alcohol و
+
+258
+00:23:31,650 --> 00:23:36,090
+secondary alcohol و tertiary alcohol بمعنى لو أنا
+
+259
+00:23:36,090 --> 00:23:39,290
+في الامتحان بدي أجي أسأل الطلاب مثلا أو الطالبات
+
+260
+00:23:39,290 --> 00:23:43,770
+كيف بنحضر هذا المركب و المركب اللي أنا جايبله مياه
+
+261
+00:23:43,770 --> 00:23:48,690
+كحولمباشرة بيصير تفكيرهم أنه إيش نوع الكحول اللي
+
+262
+00:23:48,690 --> 00:23:54,290
+أنا باسأل عنه والله إذا tertiary بقدر أفعل كيتون
+
+263
+00:23:54,290 --> 00:24:01,310
+مع green yard إذا secondary الديهيد معي green yard
+
+264
+00:24:01,310 --> 00:24:09,370
+إذا primary form الديهيد معي green yard واضح؟ فإنه
+
+265
+00:24:09,370 --> 00:24:15,780
+يكون عندى تفاعل بيطلعلي كل الاحتمالات هذا إشأكتر
+
+266
+00:24:15,780 --> 00:24:18,720
+من ممتاز أحسن يبقى هذا التفاعل صحي من ال reduction
+
+267
+00:24:18,720 --> 00:24:22,760
+لأن ال reduction ماكانش طالع لنا tertiary، صح؟ لأ
+
+268
+00:24:22,760 --> 00:24:27,060
+ال reduction ماتطلعش منه tertiary alcohol من
+
+269
+00:24:27,060 --> 00:24:32,480
+الكيتون ال tertiary alcohol من الكيتون مع .. مع ال
+
+270
+00:24:32,480 --> 00:24:36,500
+green يعني .. مع ال green يعني لما أجيبلكم مثل how
+
+271
+00:24:36,500 --> 00:24:39,140
+can you prepare a tertiary alcohol ماعرفش إذا أنا
+
+272
+00:24:39,140 --> 00:24:44,840
+على ال slides حاطتلكم أمثلةهنا يمكن نحط أمثلة
+
+273
+00:24:44,840 --> 00:24:50,120
+اكمال المعادلة لكن احنا بالتأكيد بإمكاننا يعني لو
+
+274
+00:24:50,120 --> 00:24:54,680
+رجعنا على هذا ال slide الان انتبهوا معي لو مثلا
+
+275
+00:24:54,680 --> 00:25:00,460
+انا اجيت في الامتحان سألتكم هذا السؤال جبتلكوا هذا
+
+276
+00:25:00,460 --> 00:25:04,500
+المركب بنزين
+
+277
+00:25:04,500 --> 00:25:07,320
+COH
+
+278
+00:25:12,150 --> 00:25:19,250
+How can you prepare this compound؟
+
+279
+00:25:19,250 --> 00:25:24,810
+ممكن أسيب السؤال زي ما هو هيك How can you prepare
+
+280
+00:25:24,810 --> 00:25:30,730
+this compound؟ و ممكن أزيد عليه كلام طالما هذا
+
+281
+00:25:30,730 --> 00:25:35,010
+tertiary alcohol إذا انتوا بتكونوا تتخيلوا أن ال
+
+282
+00:25:35,010 --> 00:25:44,020
+OH هذه كانتC double bond O واتفاعلت مع كيتون الأن
+
+283
+00:25:44,020 --> 00:25:50,200
+أي واحدة لكيتون أي واحدة لكيتون و أي واحدة ل green
+
+284
+00:25:50,200 --> 00:25:54,260
+yard في عندكم الحقيقة احتمالين يعني انا لو اعملت
+
+285
+00:25:54,260 --> 00:26:03,320
+هذا التفاعل C double bond O CH3 هاي كيتون و هذا
+
+286
+00:26:03,320 --> 00:26:06,060
+كيتون مشهور وموجود في المختبر شو اسمه
+
+287
+00:26:10,670 --> 00:26:15,150
+أسيتوفينون رخيص وموجود في المختبر المحلى
+
+288
+00:26:15,150 --> 00:26:20,090
+أسيتوفينون طب لو بدى اعمل ال كيتون زيك بمجموعتين
+
+289
+00:26:20,090 --> 00:26:24,890
+مثل بمشي
+
+290
+00:26:24,890 --> 00:26:32,250
+ولا لأ؟هذا أي كيتون؟ أسيتون، أسيتون، أسيتون،
+
+291
+00:26:32,250 --> 00:26:34,730
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+292
+00:26:34,730 --> 00:26:36,910
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+293
+00:26:36,910 --> 00:26:43,610
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+294
+00:26:43,610 --> 00:26:49,770
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+295
+00:26:49,770 --> 00:26:52,370
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+296
+00:26:52,370 --> 00:26:52,530
+أسيتون، أسيتون، أسيتون، أسيتون، أسيتون، أسيتون،
+
+297
+00:26:52,530 --> 00:27:04,090
+أسيتون، أسيتون، أسيتون، أسيتون، أسمثل مثل
+
+298
+00:27:04,090 --> 00:27:08,950
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+299
+00:27:08,950 --> 00:27:09,010
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+300
+00:27:09,010 --> 00:27:10,010
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل
+
+301
+00:27:10,010 --> 00:27:14,150
+مثل مثل
+
+302
+00:27:14,150 --> 00:27:23,860
+مثل مثل مثل مثل مثل مثل مثل مثل مثل مثل مثأكتر من
+
+303
+00:27:23,860 --> 00:27:27,720
+احتمال طبعا وارد هنا نفس الأشياء لو كنا نجيب الـ
+
+304
+00:27:27,720 --> 00:27:32,580
+co-secondary الكهون راجعوا ال OH إلى CWO اعملوا
+
+305
+00:27:32,580 --> 00:27:37,320
+ALDEHYDE وفعلوه مع Greenyard لو كنا نطلب تحضير ال
+
+306
+00:27:37,320 --> 00:27:44,260
+primary الكهون في هذه الحالة من أيه نحضره من تفاعل
+
+307
+00:27:44,260 --> 00:27:49,040
+Greenyard معالـ Formaldehyde من تفاعلي Greenyard
+
+308
+00:27:49,040 --> 00:27:53,240
+مع الـ Formaldehyde فهذه المنطقة بتكونوا عارفينها
+
+309
+00:27:53,240 --> 00:27:57,880
+هي منطقة بالتأكيد .. بالتأكيد هي منطقة سؤال في
+
+310
+00:27:57,880 --> 00:28:01,460
+الامتحان من أي ناحية هذه منطقة سؤال في الامتحان
+
+311
+00:28:01,460 --> 00:28:04,980
+عشان تعرفوا ان الأساتذة بتغلبوش لما يحطوا الامتحان
+
+312
+00:28:04,980 --> 00:28:08,000
+بكم
+
+313
+00:28:08,000 --> 00:28:13,120
+طريقة هنا بنسأل على هذا الموضوع؟
+
+314
+00:28:13,120 --> 00:28:20,260
+ممكن نقولكوا أكمل معادلةممكن نقولكم كيف تحضر مركب،
+
+315
+00:28:20,260 --> 00:28:27,800
+وممكن نجيبلكم سؤال صح و غلط Formal Dehydrate acts
+
+316
+00:28:27,800 --> 00:28:31,920
+with the green yard reagent producing tertiary
+
+317
+00:28:31,920 --> 00:28:36,060
+alcohol واضح؟
+
+318
+00:28:36,060 --> 00:28:40,080
+أو مثلا، secondary alcohols can be prepared from
+
+319
+00:28:40,080 --> 00:28:43,000
+the reaction of ketones with the green yard
+
+320
+00:28:43,000 --> 00:28:48,460
+reagentواضح؟ مثل هذه الجملة اللي أحيانا بتغلب
+
+321
+00:28:48,460 --> 00:28:52,840
+فيكوا، لكن زي ما انتوا ملاحظين الموضوع سهل جدا ال
+
+322
+00:28:52,840 --> 00:28:55,620
+formal dehyde primary ال ال dehydes التانية
+
+323
+00:28:55,620 --> 00:29:00,600
+secondary ال ketone tertiary alcohol مع
+
+324
+00:29:17,340 --> 00:29:23,660
+هذه المعادلة العامة طبعا احنا عادة التفاعل مع
+
+325
+00:29:23,660 --> 00:29:26,980
+جرينيا نقول بالفعل نمرة واحد مع جرينيا نمرة اتنين
+
+326
+00:29:26,980 --> 00:29:31,620
+مع حامض يعني مابديش ياكوا تعملوها خطواتين هو
+
+327
+00:29:31,620 --> 00:29:35,440
+التفاعل في داخل نفسه يتم على خطواتين لكن احنا
+
+328
+00:29:35,440 --> 00:29:41,380
+متعودين ان نقولكوا نفعل مع RMGX نمرة واحد ونمرة
+
+329
+00:29:41,380 --> 00:29:48,190
+اتنين H3O plus بناء على ذلك ماذا تكتبونالـ Final
+
+330
+00:29:48,190 --> 00:29:53,790
+Product لكن أكيد التفاعل بيمشي على مراحل أنا مش
+
+331
+00:29:53,790 --> 00:29:58,650
+كتير مهتم بالمرحلة الوسطى أنه بيصير عندي O- MgBr
+
+332
+00:29:58,650 --> 00:30:03,950
+Plus و بعدين بالحمد بيعطينا نتيجة نهائية الآن إذا
+
+333
+00:30:03,950 --> 00:30:09,120
+بدنا نتطلع على الأمثلة الموجودة عندناهي عندنا مثلا
+
+334
+00:30:09,120 --> 00:30:14,800
+هذا المُركّب الـ Acetophenon شايفينه؟ بدفعله مع
+
+335
+00:30:14,800 --> 00:30:19,380
+إثل ميجنيسيا ميبروميدل إيش المجموعة اللي بده تيجي
+
+336
+00:30:19,380 --> 00:30:25,800
+عندك؟ الـ Ethyl إذا هاي الـ Acetophenon و الـ
+
+337
+00:30:25,800 --> 00:30:31,080
+Cedarwood O تبعته صارت OH و هاي المجموعة اللي هي
+
+338
+00:30:31,080 --> 00:30:34,180
+الـ Ethyl إجت من الـ Grenade واضح؟
+
+339
+00:30:39,400 --> 00:30:44,420
+هنا تفاعل تاني مش مع green yard مع metal تاني شبيه
+
+340
+00:30:44,420 --> 00:30:47,660
+ب green yard مع ال lithium لكن نفس فكرة green yard
+
+341
+00:30:47,660 --> 00:30:51,140
+بالظبط يعني هذا يمثل اللي هو المراكب اللي مع ال
+
+342
+00:30:51,140 --> 00:30:54,200
+lithium برضه زي و زي المراكب اللي مع ال green yard
+
+343
+00:30:54,200 --> 00:31:00,580
+مجموعة ال R مع إلكترونات بناء على ذلك كل هذه
+
+344
+00:31:00,580 --> 00:31:06,180
+المجموعة بنتيجة تهاجم هنا و ال O تصير أقصر هذي
+
+345
+00:31:06,180 --> 00:31:07,560
+المجموعة اللي هي
+
+346
+00:31:14,510 --> 00:31:24,190
+هنا بس أكيد إنه ناسي يحط ال CH3 هذا خطأ طيب يعني
+
+347
+00:31:24,190 --> 00:31:28,550
+هاي المجموعة هادي اللي هي إجت دخلت عندنا و هادي
+
+348
+00:31:28,550 --> 00:31:35,380
+صارت OHهنا مثلا هي الديهيد لاحظوا احنا ليش
+
+349
+00:31:35,380 --> 00:31:40,260
+بنجيبلكوا أحيانا أنفلة بجزيئات كبيرة؟ عشان في
+
+350
+00:31:40,260 --> 00:31:43,940
+النهاية تاخدوا الجزء الكبير زي ما هو و المحور
+
+351
+00:31:43,940 --> 00:31:46,920
+الأساسي تبع التفاعل اللي عندكم هو محور إيش؟
+
+352
+00:31:46,920 --> 00:31:52,780
+المجموعة الوظيفية يعني هي هنا جزء كبير أنا كل هذا
+
+353
+00:31:52,780 --> 00:31:57,790
+الجزء الكبير هيني بتحطه في دائرةاللي هو عبارة عن
+
+354
+00:31:57,790 --> 00:32:05,890
+CH CH3 CH3 إذا بتلاحظوا هذا كله نفسه مازال موجود
+
+355
+00:32:05,890 --> 00:32:11,590
+زي ما هو لكن إجت مجموعة الـCH اللي مع مغنيسيوم أو
+
+356
+00:32:11,590 --> 00:32:18,950
+مع ليثيا شبكت واسيطة بالبندغوش وصارت OH فقط هاي
+
+357
+00:32:18,950 --> 00:32:23,850
+هادي شبيه جرينيا درجة هنا هاي مجموعة مثلا كبيرة
+
+358
+00:32:23,850 --> 00:32:28,920
+هادي كلها المجموعة اللي هيتمثل الـ Grignard Ray
+
+359
+00:32:28,920 --> 00:32:37,700
+Agent هذا الجزء كله ماذا يعني؟ محور
+
+360
+00:32:37,700 --> 00:32:39,060
+التفاعل اللي عندك
+
+361
+00:32:42,440 --> 00:32:46,240
+دخلت المجموعة اللي عندنا و الـ C double bond O
+
+362
+00:32:46,240 --> 00:32:50,880
+صارت OH و كذلك الحال في الأمثلة اللي موجودة تحت
+
+363
+00:32:50,880 --> 00:32:56,640
+هذا الكلام طبعا لازم نبحكوا لشغله أنه مثل هذه
+
+364
+00:32:56,640 --> 00:33:01,500
+الأمثلة و كل دراسة ال organ chemistry إذا ماكنتوش
+
+365
+00:33:01,500 --> 00:33:05,220
+بتمسكوا ورقة و جلم و بتقيدوا كتابة التفاعل و
+
+366
+00:33:05,220 --> 00:33:08,480
+بتقيدوا كيف أن هذه المجموعة إجت كيف أن الـ C
+
+367
+00:33:08,480 --> 00:33:13,940
+double bond O في كل الأحوال عاملة بتصيرOH OH OH OH
+
+368
+00:33:13,940 --> 00:33:20,740
+OH OH OHتطلع عليها هي كرموز تبدو العملية متعبة
+
+369
+00:33:20,740 --> 00:33:27,400
+تتعاملوا معها بنوع من التحليل العملية بسيطة جدا
+
+370
+00:33:27,400 --> 00:33:31,000
+انه انا عندي جزء ان شاء الله يكون رسم ليهانا خريطة
+
+371
+00:33:31,000 --> 00:33:35,360
+فلسطين مش مواد كيميائية بدي اخده زي ما هو في
+
+372
+00:33:35,360 --> 00:33:39,380
+النهاية الـC double bond او شو هتصير؟ الـCOH و
+
+373
+00:33:39,380 --> 00:33:44,430
+المجموعة بتدخل كالله بيصير عليهمواضح؟ هذا الكلام
+
+374
+00:33:44,430 --> 00:33:48,810
+بالتأكيد إذا ما طبقتوش و عدتوا كتابته بالجلم لرصاص
+
+375
+00:33:48,810 --> 00:33:52,150
+و اتعودتوا عليه ابتديوا يوم الامتحان فاهمين
+
+376
+00:33:52,150 --> 00:34:00,350
+الموضوع بس مابتقدروش تطبقوه فلابد إلا إيش؟
+
+377
+00:34:00,350 --> 00:34:06,910
+لابد إلا إنكم تعملوا تطبيق كتير لأنه مش كل العلم
+
+378
+00:34:06,910 --> 00:34:16,110
+بالمناسبة مش كل العلم يُأخذنظريا في أشياء لابد ..
+
+379
+00:34:16,110 --> 00:34:22,530
+لابد فيها من الجزء العمل أو التطبيق أحكي ولا أظلني
+
+380
+00:34:22,530 --> 00:34:27,630
+ساكت؟ لأ خليني ساكت أحسن يعني الـ Geta لو بدنا
+
+381
+00:34:27,630 --> 00:34:32,230
+نيجي نقولكم كيف الناس بيعملوا الملخية بتكونوا
+
+382
+00:34:32,230 --> 00:34:36,590
+تقولوا بعد ما نجيها بنفرمها هيك؟ طب روحوا أظبطوها
+
+383
+00:34:39,960 --> 00:34:44,620
+إذا ما صارش عندكم تطبيق بدل المرة عشرة مش هتظبط
+
+384
+00:34:44,620 --> 00:34:49,580
+معاكم، هتقعدوا تتطلعوا بحالكوا و تلاقوا أنها إيش؟
+
+385
+00:34:49,580 --> 00:34:53,500
+أنها مش سابقة معاكم، لابد من عملية التطبيق الكثير
+
+386
+00:34:53,500 --> 00:35:01,640
+حتى تصيروا .. تتقنوا أي عملية، واضح؟ لابد من عملية
+
+387
+00:35:01,640 --> 00:35:05,540
+التطبيق الكثير حتى تتقنوا العمليات
+
+388
+00:35:08,610 --> 00:35:17,970
+هذا التفاعل 100% مش 99% موازي لتفاعل الـ Green
+
+389
+00:35:17,970 --> 00:35:24,110
+Yard Reagent نفس الفكرة تماما .. نفس فكرة Green
+
+390
+00:35:24,110 --> 00:35:29,430
+Yard Reagent تماما لكن الآن هنا النيوكليوفايل اللي
+
+391
+00:35:29,430 --> 00:35:35,810
+بنفاعل معه هو الـ Acetylide الآن يا تورا متذكرين
+
+392
+00:35:35,810 --> 00:35:44,660
+الـ Acetylide ولا لأ؟أنا بذكركوا فيه لما
+
+393
+00:35:44,660 --> 00:35:47,960
+درسنا ال ال kinds المركبات اللي فيهم ال travel
+
+394
+00:35:47,960 --> 00:35:55,130
+bondلأ مش ضروري أبسط واحد أي ألكاين بنقول عنه
+
+395
+00:35:55,130 --> 00:36:02,850
+terminal طرفي بمعنى في هنا C triple bond C وهنا H
+
+396
+00:36:02,850 --> 00:36:08,730
+هذا بزن في أحد أطرافه H إذا هو terminal الكاين
+
+397
+00:36:08,730 --> 00:36:14,010
+الآن هذا ال terminal الكاين قاعدي أحط هنا فيه إيش
+
+398
+00:36:14,010 --> 00:36:14,690
+بدكم؟
+
+399
+00:36:17,600 --> 00:36:24,840
+فنل بمشي مثل بمشي مجموعة من أربع ذرات بمشي إيش ما
+
+400
+00:36:24,840 --> 00:36:28,900
+كان بمشي بيبطل محور السؤال يعني خليني مثلا قد ما
+
+401
+00:36:28,900 --> 00:36:32,100
+بدي أكبر و أعمل زيك و زيك و زيك و زيك هذه كلها
+
+402
+00:36:32,100 --> 00:36:39,270
+ذرات carbon و في الآخر أجه أحط هنا فنلواضح؟ الآن
+
+403
+00:36:39,270 --> 00:36:44,410
+الـ Terminal Alkines أخدنا عنهم إن هما عبارة عن
+
+404
+00:36:44,410 --> 00:36:52,370
+Assets لمن فعلهممع ال NA مع ال Sodium بيفقد بروتون
+
+405
+00:36:52,370 --> 00:36:56,550
+و بيعطينا ال Acetylide إذا لما أنا .. هذا التفاعل
+
+406
+00:36:56,550 --> 00:36:59,410
+لسه اللي أخدته اللي بدأ أستفيد منه لما أجي بدأ
+
+407
+00:36:59,410 --> 00:37:03,090
+أتذكر هالكلام جزء كبير شوية الامتحان الصعب ولا
+
+408
+00:37:03,090 --> 00:37:07,310
+كبير ولا إشي هذه ال C ال triple bond C اللي جمّع H
+
+409
+00:37:07,310 --> 00:37:10,110
+لما أفعلها مع ال Sodium بدأ تشيلي ال H و تحطلي
+
+410
+00:37:10,110 --> 00:37:13,490
+Sodium معنا ذلك أنا إيش اللي بدأ أعمله لو أنا قاعد
+
+411
+00:37:13,490 --> 00:37:18,940
+على برنامج رسم و بعمل نسخ و لاصق؟بدي أخد هذه
+
+412
+00:37:18,940 --> 00:37:23,060
+المجموعة كلها و أحطها هنا فقط بدي أشيل الـH و أحط
+
+413
+00:37:23,060 --> 00:37:27,840
+الـNA ألاحظين كيف التعامل مع ال .. مع ال organic
+
+414
+00:37:27,840 --> 00:37:32,820
+problems C
+
+415
+00:37:32,820 --> 00:37:37,620
+triple bond C NA
+
+416
+00:37:37,620 --> 00:37:43,590
+بتصير هذه minus وهذه plusأيا كان الجزء اللي هنا
+
+417
+00:37:43,590 --> 00:37:49,110
+الان هنا محور المسألة انه هذا ال Acetylide
+
+418
+00:37:49,110 --> 00:37:52,610
+compound اللي سمناه Acetylide بيحتوي على ايه عشان
+
+419
+00:37:52,610 --> 00:37:59,850
+علمه بالأزرق كمان مرة بيحتوي على سالب اذا هو يمثل
+
+420
+00:37:59,850 --> 00:38:05,790
+ال nucleophile هذا الجزء كله يمثل ال nucleophile
+
+421
+00:38:05,790 --> 00:38:12,140
+كيف بتفاعل ال nucleophileمع الالديهال او الكيتون
+
+422
+00:38:12,140 --> 00:38:18,620
+اكيد بتفاعل الاديشن كل هذا بده ييجي يهجم على
+
+423
+00:38:18,620 --> 00:38:24,580
+الكربونة ويحول السيما بالبند أو إلى OH واضح؟ هاي
+
+424
+00:38:24,580 --> 00:38:29,840
+مثلا هنا أستيلايد صغير مش كبير زي هذا اللي بخوف
+
+425
+00:38:29,840 --> 00:38:35,030
+هاي أستيلايد صغير شايفينه؟بدو يتفاعل مع هذا الـ
+
+426
+00:38:35,030 --> 00:38:40,130
+Ketone وين المحور؟ إن هذا زوج الإلكترونات يجي
+
+427
+00:38:40,130 --> 00:38:45,450
+يتفاعل، هاد الكربون أو هاد تصير فزي ما بتلاحظوا
+
+428
+00:38:45,450 --> 00:38:50,590
+أنتوا، باقي الـ Ketone أو الـ aldehyde، ضالوا زي
+
+429
+00:38:50,590 --> 00:39:00,010
+ما هو، باقي الـ acetylide، ضالوا زي ما هو، طبعا،
+
+430
+00:39:00,010 --> 00:39:05,430
+إذا إيش التفاعل بيصف في النهاية؟حقيقة التفاعل
+
+431
+00:39:05,430 --> 00:39:09,470
+بالنهاية هو عبارة .. يعني لو كنتوا بتكونوا بسطوا
+
+432
+00:39:09,470 --> 00:39:13,410
+الموضوع جدا جدا هو عبارة عن زوج إلكترونات بيهاجم
+
+433
+00:39:13,410 --> 00:39:19,130
+هنا و بيحولها إلى OH هذه زوج الإلكترونات وهذه صارت
+
+434
+00:39:19,130 --> 00:39:24,610
+OH طب و باقي الكلام كله اللي هنا زي ما هو و باقي
+
+435
+00:39:24,610 --> 00:39:28,350
+الكلام كله اللي هنا مع هذا زوج الإلكترونات زي ما
+
+436
+00:39:28,350 --> 00:39:31,150
+هو واضح؟
+
+437
+00:39:36,120 --> 00:39:42,360
+الان انتبهوا مثلا على هذا المُركّب هاي مُركّب كبير
+
+438
+00:39:42,360 --> 00:39:49,900
+جد البحر شايفينه؟ في النهاية إيش موجود فيه؟ أسيطة
+
+439
+00:39:49,900 --> 00:39:53,780
+بالـ bond O كل هذا المُركّب هيظل زي ما هو بدا
+
+440
+00:39:53,780 --> 00:39:57,580
+أفعله أنا في هذه الحالة معي green يعني رجعت ل
+
+441
+00:39:57,580 --> 00:40:02,640
+green يعني هذه الـCH3 بنتيجة أنا وهذه الأسيطة بالـ
+
+442
+00:40:02,640 --> 00:40:03,580
+bond O تصير
+
+443
+00:40:07,570 --> 00:40:11,170
+الان هذا الناتج بعدين بيعمل عملية cyclization تخرج
+
+444
+00:40:11,170 --> 00:40:15,250
+الموضوع احنا هاي الناتج اللي ملاحظينه ان واحدة من
+
+445
+00:40:15,250 --> 00:40:22,190
+ال CH3 اتجت من برا وهي هذا الجزء كله اللي كان
+
+446
+00:40:22,190 --> 00:40:27,270
+موجود عندى عشانك مثلا هذا الجزء الأخير اللي مبين
+
+447
+00:40:27,270 --> 00:40:33,310
+كبير لو قلتلكوا بدي افعله مع benzaldehyde بقدر بدي
+
+448
+00:40:33,310 --> 00:40:41,640
+اقول زائد phenylC double bond OH كيف
+
+449
+00:40:41,640 --> 00:40:50,380
+هتعملوه هذي بده تاجم هنا و ال O بده تصير OH فقط
+
+450
+00:40:50,380 --> 00:40:57,980
+مجرد انكوا تجيبوا هذي هنا و هذي بتخلوها OH هنا و
+
+451
+00:40:57,980 --> 00:41:03,420
+رسموهطبعا أنا بصير جديش عندكم القدرة أنه بجلم
+
+452
+00:41:03,420 --> 00:41:07,240
+لرصاص تلسخه الأشياء زي ما هي ترسموها مش أكتر،
+
+453
+00:41:07,240 --> 00:41:13,280
+واضح؟فزي ما بتلاحظوا لما انا من محاضرتين قلتلكوا
+
+454
+00:41:13,280 --> 00:41:17,160
+انه في ال الديهيدس والكيتونز كل الشغل اللي عندكوا
+
+455
+00:41:17,160 --> 00:41:22,300
+تطبيق وقاعد انا بدور محاضرتين كاملين حوالي الفكرة
+
+456
+00:41:22,300 --> 00:41:26,220
+واحدة انه زوج إلكترونات بيهاجم على ال C double
+
+457
+00:41:26,220 --> 00:41:32,160
+bond O و بيحولها إلى OH مازدناش عن هذه الفكرة لكن
+
+458
+00:41:32,160 --> 00:41:38,950
+ايش عملنا؟عملنا أمثلة تطبيقية كتيرة بنجح عند موضوع
+
+459
+00:41:38,950 --> 00:41:43,390
+الـ oxidation of aldehydes and keto
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/Q0NFjYnX1Cw_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/Q0NFjYnX1Cw_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..970e45473d25ae7230d89fbfb5d86f62a978acc6
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/Q0NFjYnX1Cw_postprocess.srt
@@ -0,0 +1,2060 @@
+1
+00:00:05,900 --> 00:00:12,380
+اليوم ان شاء الله بدنا نكمل في موضوع ال stereo
+
+2
+00:00:12,380 --> 00:00:16,860
+chemistry زي ما قلتلكم يعني الموضوع بحاجة إلى
+
+3
+00:00:16,860 --> 00:00:23,480
+تعامل هادئ بحاجة إلى نوعا ما بعض التخيلات لكن بعد
+
+4
+00:00:23,480 --> 00:00:28,480
+ما الواحد يدرس الموضوع ويعاود ويعاود يشوف الموضوع
+
+5
+00:00:28,480 --> 00:00:34,530
+باختصار بلاقي برضه انه مش كبير كتير بلاقي انهمش
+
+6
+00:00:34,530 --> 00:00:38,390
+كبير كتير يعني لما أخدنا احنا أنواع ال stereo
+
+7
+00:00:38,390 --> 00:00:42,150
+isomers لما أخدنا أنواع ال stereo isomers اتكلمنا
+
+8
+00:00:42,150 --> 00:00:48,150
+على نوعين enantiomers و عرفناهم non-superimposable
+
+9
+00:00:48,150 --> 00:00:51,570
+mirror image stereo isomers و النوع التاني اللي
+
+10
+00:00:51,570 --> 00:00:55,890
+أخدنا ال diastereomers أخدنا أنواع منهم ال cis
+
+11
+00:00:55,890 --> 00:01:00,390
+-trans isomers و نوع تاني بصادفنا لما يكون عندنا
+
+12
+00:01:00,390 --> 00:01:07,250
+أكترمن chiral center يمكن اليوم بدي اكد على
+
+13
+00:01:07,250 --> 00:01:12,070
+المركبات اللى اتكلمنا عنهم المرة الماضية تلاتة
+
+14
+00:01:12,070 --> 00:01:17,210
+واربعةاللي موجودين عندنا ان هدولة بيكونوا
+
+15
+00:01:17,210 --> 00:01:22,170
+enantiomers بمعنى مابنطبقوش على بعضهم في المرأة
+
+16
+00:01:22,170 --> 00:01:25,870
+على أساس لما تعملولهم مقارنة بعد هيك في الصفحة
+
+17
+00:01:25,870 --> 00:01:29,930
+القادمة في نفس المراكبات تلاتة أو أربعة في مراكب
+
+18
+00:01:29,930 --> 00:01:33,150
+البيوتين تشوفوا ليش هدول بيصيروا the same compound
+
+19
+00:01:33,150 --> 00:01:38,870
+واضح؟ الان لو احنا امسكنا models لو امسكنا models
+
+20
+00:01:38,870 --> 00:01:43,150
+لهذه المراكبات وبهمنكوا تشوفوا كيف بتيجي ال models
+
+21
+00:01:43,590 --> 00:01:49,250
+يعني هذا المركب الأول زي ما انتوا شايفينه اللي فيه
+
+22
+00:01:49,250 --> 00:01:55,330
+two hydrogens وفيه chlorine طبعا بتلاحظوا ان في ال
+
+23
+00:01:55,330 --> 00:01:59,410
+stereo chemistry بيجوا الذرات وين للأمام اللي فوق
+
+24
+00:01:59,410 --> 00:02:03,230
+و اللي تحت هدولة بيرسمهم بيكونوا وين جايين للخلف
+
+25
+00:02:03,230 --> 00:02:09,190
+فهذا هو الجزء هذا هو المركب اللي ماخد الرقم تلاتة
+
+26
+00:02:09,190 --> 00:02:15,000
+اللي هو بينتين ال one هاي ال carbonstwo three four
+
+27
+00:02:15,000 --> 00:02:20,020
+five على اتنين و تلاتة ايش في عندكم؟ دايكلورة الان
+
+28
+00:02:20,020 --> 00:02:24,720
+هاي صورته فى المرأة ماحد بيختلف ان هدول الاتنين
+
+29
+00:02:24,720 --> 00:02:29,360
+صورت بعض فى المرأة الان السؤال هل يا ترى هدول
+
+30
+00:02:29,360 --> 00:02:32,860
+اتنين ال two three daikler و بين ten هدول اتنين
+
+31
+00:02:32,860 --> 00:02:38,740
+بينطبقوا على بعض ولا لأ اذا اجينا جربنا نحطهم بهذا
+
+32
+00:02:38,740 --> 00:02:44,180
+الشكلصح الجزء الخلفي بنطبق على بعضه اللي هو مثل
+
+33
+00:02:44,180 --> 00:02:49,920
+مثل و إثل إثل لكن بطل إنه هنا مافيش عملية إيش
+
+34
+00:02:49,920 --> 00:02:55,500
+انطباق الآن لو جربنا نعمل لهم دوران حول محور هنا
+
+35
+00:02:55,500 --> 00:02:59,560
+بس بندورهم يعني ما زالوا هدول الأمام كأنه هنا في
+
+36
+00:02:59,560 --> 00:03:04,120
+محور و أنا بدورهم و أجي أعمل انطباق هلاحظ إنه ال
+
+37
+00:03:04,120 --> 00:03:08,250
+chlorine و ال chlorineبنطبق على بعض والهيدروجين
+
+38
+00:03:08,250 --> 00:03:13,950
+والهيدروجين وين صارت المشكلة ان فوق في عند هنا مثل
+
+39
+00:03:13,950 --> 00:03:20,460
+هناEthylene فبرضه مافيش تطابق ولذلك هدولة احنا
+
+40
+00:03:20,460 --> 00:03:25,180
+بنقول عنهم they are enantiomers فبال two three
+
+41
+00:03:25,180 --> 00:03:29,120
+-dichlorobentين هدولة المركبين they are
+
+42
+00:03:29,120 --> 00:03:34,140
+enantiomers الآن عدنا الصورة لما اجينا نفهم ال
+
+43
+00:03:34,140 --> 00:03:40,580
+mesostructure لكن لغينا مجموعةمثل خلّينها 2,3
+
+44
+00:03:40,580 --> 00:03:46,160
+-dichloro بيوت تاني يعني قولنا هاي 1,2,3,4 راحت من
+
+45
+00:03:46,160 --> 00:03:49,340
+هنا مجموعة المثل زي الـ carbons المخدين اللي هو
+
+46
+00:03:49,340 --> 00:03:59,870
+الأصمر 1,2,3,4 2,3-dichloroبيوتين و هذا صار two
+
+47
+00:03:59,870 --> 00:04:05,270
+three dichloro بيوتين هاي هم هيك انبينين صورة بعض
+
+48
+00:04:05,270 --> 00:04:08,630
+فى المرقاة فبيبدأ يصير تفكير عند البعض انه ممكن
+
+49
+00:04:08,630 --> 00:04:15,030
+هدولة يكونوا enantiomers الان اذا عملنا نفس الحركة
+
+50
+00:04:15,030 --> 00:04:20,090
+هذه و لفناهم اعملنا دوران لواحد منهم هاي و هيك مية
+
+51
+00:04:20,090 --> 00:04:24,690
+و تمانين درجة لفناه و اجينا حطناهم ينطبقوا على بعض
+
+52
+00:04:25,390 --> 00:04:31,850
+بنطبقه، واضح؟ إذا هدولة نفس المُركّب، واضح؟ الـ 2
+
+53
+00:04:31,850 --> 00:04:38,110
+,3-dichloro-butane الـ 2R 3S و الـ 2S 3R they are
+
+54
+00:04:38,110 --> 00:04:44,270
+the same compound ممكن واحدة يظل عندها تساؤل تقول
+
+55
+00:04:44,270 --> 00:04:49,770
+طالما نفس المُركّب طالما نفس المُركّب إذا المفروض
+
+56
+00:04:49,770 --> 00:04:55,520
+ياخدهنفس التسمية و نفس الترقيم الجواب بنقول هذا
+
+57
+00:04:55,520 --> 00:04:59,460
+الكلام اللي بتحكيه صحيح و هم كذلك بياخدوا نفس
+
+58
+00:04:59,460 --> 00:05:03,140
+التسمية و نفس الترقيم وين بتصير المشكلة ان هذا
+
+59
+00:05:03,140 --> 00:05:06,680
+الجزء متماثل لاحظوا لما انا قلتلكم النص اللي فوق
+
+60
+00:05:06,680 --> 00:05:11,600
+منه زي النص اللي تحت الان لما انا اجي ابدأ لما انا
+
+61
+00:05:11,600 --> 00:05:17,240
+اجي ابدأ الترقيم عندى بدي اقول واحد تنين تلاتة
+
+62
+00:05:17,240 --> 00:05:25,790
+أربعة ممكنأقول كمان واحد اتنين تلاتة اربعة هل في
+
+63
+00:05:25,790 --> 00:05:31,430
+فرق بين هدول احتمالين؟ اطلاقا بمعنى يجوز ان ابدأ
+
+64
+00:05:31,430 --> 00:05:35,550
+الترقيم واحد اتنين تلاتة اربعة او واحد اتنين تلاتة
+
+65
+00:05:35,550 --> 00:05:40,570
+اربعة وبناء على ذلك لو احنا اتينا واطلعنا من وين
+
+66
+00:05:40,570 --> 00:05:45,310
+كنا عاملين ترقيم نفترض من هنا واحد اتنين تلاتة
+
+67
+00:05:47,000 --> 00:05:53,460
+أربعة بهذا الشكل نتأكد ان هذا كان هو two R هي واحد
+
+68
+00:05:53,460 --> 00:05:58,500
+اتنين تلاتة اثنين اس و هذا كان واحد اتنين تلاتة
+
+69
+00:05:58,500 --> 00:06:05,660
+اثنين اس الان احنا بتقول اننا متحيرين هذا كيف
+
+70
+00:06:05,660 --> 00:06:10,200
+نرقمه بمعنى قدرين نقول واحد اتنين تلاتة اربعة و في
+
+71
+00:06:10,200 --> 00:06:14,180
+هذه الحالة هذا ادى لهذه ال configurations انه
+
+72
+00:06:14,180 --> 00:06:19,930
+اتنين ماخدةS و تلاتة R في بيني المتعاكسات طيب لو
+
+73
+00:06:19,930 --> 00:06:27,110
+رقمنا هيك واحد ..تنين ..تلاتة ..اربعة في مانع؟ اه
+
+74
+00:06:27,110 --> 00:06:32,710
+في هذه الحالة الاتنين ايش بتاخد؟ R ..و التلاتة S
+
+75
+00:06:32,710 --> 00:06:39,070
+صارك هذه و هذه زي بعض واضح؟ و هذا بيأكد انه احنا
+
+76
+00:06:39,070 --> 00:06:46,610
+بنحكي على نفس الجزيةهذا الجزء المتمثل من النص هو
+
+77
+00:06:46,610 --> 00:06:51,270
+اللي بنسميه الـ meso compound فالميزو كومباوند
+
+78
+00:06:51,270 --> 00:06:55,690
+يمكن الجزء الأول من التعريف اللي بنرجعله بعد شوية
+
+79
+00:06:55,690 --> 00:06:59,970
+هو the stereomark of a compound with stereogenic
+
+80
+00:06:59,970 --> 00:07:05,210
+centers في كايرال سنترز بنقدر نحط عليهم نجمة،
+
+81
+00:07:05,210 --> 00:07:09,070
+تمام، تمام كايرال سنترز، كل واحد عليه أربع مجموعات
+
+82
+00:07:09,070 --> 00:07:13,160
+مختلفةIts stereogenic centers have opposite
+
+83
+00:07:13,160 --> 00:07:17,940
+configurations نحن هدول إيش بيكونوا؟ عكس بعض، بعض،
+
+84
+00:07:17,940 --> 00:07:22,440
+1R 1S هذا الكلام منطقي، ليش عكس بعض؟ لأنهم صورة
+
+85
+00:07:22,440 --> 00:07:25,940
+بعض في المرأة، كل إيش صورة بعض في المرأة بيكون عكس
+
+86
+00:07:25,940 --> 00:07:32,420
+بعض، فهذا منطق أنه هذا لما يكون R هذا يكون إيش؟ S،
+
+87
+00:07:32,420 --> 00:07:35,420
+ليش؟ لأن هذا و هذا صورة بعض في المرأة، وصورة بعض
+
+88
+00:07:35,420 --> 00:07:39,540
+في المرأة دائما متعكس، الواحد بيشوف نفسه بالمراية
+
+89
+00:07:40,350 --> 00:07:43,990
+بالعكس، يعني إذا إحنا هيك وقفين ونطلع على البحر في
+
+90
+00:07:43,990 --> 00:07:48,750
+المرايا، بتخلينا وين نطلع؟ على الاتجاه المعاكس،
+
+91
+00:07:48,750 --> 00:07:53,330
+مظبوط ولا لأ؟ دايما الصورة في المرأة معاكسة one
+
+92
+00:07:53,330 --> 00:07:59,250
+-half of the molecule is the mirror image of the
+
+93
+00:07:59,250 --> 00:07:59,490
+other
+
+94
+00:08:04,550 --> 00:08:10,470
+في المرأة واضح فهو عبارة عن جزء بمواصفة خاصة وهذا
+
+95
+00:08:10,470 --> 00:08:14,790
+اللي خلّى ال number of stereoisomers فهذا النوع من
+
+96
+00:08:14,790 --> 00:08:20,010
+المراكبات واحد اتنين تلاتة مش اربعة يعني ماوصلوش
+
+97
+00:08:20,010 --> 00:08:23,870
+ال maximum احنا قولنا ال maximum لما يكون عنده two
+
+98
+00:08:23,870 --> 00:08:28,110
+chiral centers اللي يكون عنده اربعة وشوفناهم في
+
+99
+00:08:28,110 --> 00:08:31,390
+مثال ال two three dichlorobentane لكن بال two
+
+100
+00:08:31,390 --> 00:08:36,270
+three dichlorobentaneبيتين؟ لأ العدد أقل من أربعة
+
+101
+00:08:36,270 --> 00:08:43,510
+العدد إيش؟ تلاتة واضح؟
+
+102
+00:08:43,510 --> 00:08:46,590
+الآن
+
+103
+00:08:46,590 --> 00:08:50,890
+صرنا متعرفين كويس على ال enantiomers و ال
+
+104
+00:08:50,890 --> 00:08:55,730
+diastereomers بنيجي إلى خواص ال enantiomers و ال
+
+105
+00:08:55,730 --> 00:09:02,170
+diastereomers طبعا الخواص تقسمإلى نوعين خواص
+
+106
+00:09:02,170 --> 00:09:07,610
+فيزيائية و خواص كيميائية الخواص الفيزيائية اللى
+
+107
+00:09:07,610 --> 00:09:12,490
+إحنا بنقيسها بدون ما نغير تركيب الجزء الجزء زى ما
+
+108
+00:09:12,490 --> 00:09:16,410
+هو يعني لو عندي جزء بنقيسله الكثافة و ال melting
+
+109
+00:09:16,410 --> 00:09:19,690
+point و ال boiling point هل بيتغير تركيبه
+
+110
+00:09:19,690 --> 00:09:25,630
+الكيميائي؟ و الخواص الكيميائية هي التفاعلات ببساطة
+
+111
+00:09:25,630 --> 00:09:33,640
+و التفاعلات تغير المادةواضح؟ الان لما بنيجي نقول
+
+112
+00:09:33,640 --> 00:09:37,960
+يا تورا لو عندى two enantiomers .. لو عندى two
+
+113
+00:09:37,960 --> 00:09:42,220
+enantiomers ايش العلاقة بين الخواص الفيزيائية
+
+114
+00:09:42,220 --> 00:09:47,480
+تبعتهم؟ الخواص الفيزيائية لل enantiomers بنقول ال
+
+115
+00:09:47,480 --> 00:09:54,320
+enantiomers بيشتركوا في كل الخواص الفيزيائية ما
+
+116
+00:09:54,320 --> 00:10:00,930
+عدا خصية واحدةواضح؟ اذا ال enantiomers they have
+
+117
+00:10:00,930 --> 00:10:05,070
+the same physical properties except for هالخاصية
+
+118
+00:10:05,070 --> 00:10:07,970
+الواحدة يمكن انتوا متعودتوش عليها او ماسمعتوش فيها
+
+119
+00:10:07,970 --> 00:10:12,030
+بنسميها direction of rotation of a plane polarized
+
+120
+00:10:12,030 --> 00:10:18,830
+light اتجاه تدوير او دوران الضوء المستقطب في مستوى
+
+121
+00:10:18,830 --> 00:10:30,520
+واحد واضح؟ الان لو قلتلكمR و S مجلدين لديهم نفس
+
+122
+00:10:30,520 --> 00:10:36,390
+الوضعهذه physical property have the same boiling
+
+123
+00:10:36,390 --> 00:10:44,210
+point؟ صح have the same density؟ صح طيب، هذي إيش
+
+124
+00:10:44,210 --> 00:10:49,270
+بيختلفوا؟ في زاوية بنسميها دوران الضوء المستقطب،
+
+125
+00:10:49,270 --> 00:10:54,690
+بيختلفوش بالمقدار، بيختلفوا بالاتجاه هنا بلزم نعاد
+
+126
+00:10:54,690 --> 00:11:00,150
+نتعرف أكتر إيش معنى الضوء المستقطبفي مستوى واحد و
+
+127
+00:11:00,150 --> 00:11:04,950
+إيش معنى دورانه؟ إيش هي هذه الخاصية اللي أنا متأكد
+
+128
+00:11:04,950 --> 00:11:11,270
+سابقا مامرتش عليكم في الكتب المدرسية واضح؟ بنرجع
+
+129
+00:11:11,270 --> 00:11:19,410
+شوية موجودة ال slide عندنا هذي ال slideإحنا لما
+
+130
+00:11:19,410 --> 00:11:24,250
+بيكون في عندنا ضوء، اول ما بيطلع الضوء عبارة عن
+
+131
+00:11:24,250 --> 00:11:29,590
+electromagnetic waves موجات كهرومغناطسية، الآن
+
+132
+00:11:29,590 --> 00:11:34,930
+الموجات طبيعة الموجة إيش بتعمل؟ بتعمل vibration،
+
+133
+00:11:34,930 --> 00:11:39,570
+بتعمل احتزاز، بهذا الشكل بتكون ماشية الموجة، بتعمل
+
+134
+00:11:39,570 --> 00:11:40,230
+vibration
+
+135
+00:11:42,660 --> 00:11:46,900
+الضوء اول ما بيطلع بيكون بيعمل vibration بكل
+
+136
+00:11:46,900 --> 00:11:51,480
+الاتجاهات، يعني لو بده يكون عنده مصدر ضوء و اقول
+
+137
+00:11:51,480 --> 00:11:55,360
+كيف الموجات تبقى بتتحرك، بنقول بيعمل vibration in
+
+138
+00:11:55,360 --> 00:11:59,360
+all directions، بمعنى بتكون موجة فيه بتمشي بهذا
+
+139
+00:11:59,360 --> 00:12:04,030
+الشكل، موجة تانية بتمشيبهذا الشكل الموجة تالتة
+
+140
+00:12:04,030 --> 00:12:09,050
+بتمشي بهذا الشكل الموجة رابعة بتمشي بهذا الشكل فلو
+
+141
+00:12:09,050 --> 00:12:13,010
+بدنا نعبر عنه انه في عندي هنا light source مصدر
+
+142
+00:12:13,010 --> 00:12:18,170
+للضوء و بده يطلع الضوء بيكون بيعمل vibration لفوق
+
+143
+00:12:18,170 --> 00:12:20,950
+و لتحت و على الجانب هذا و على الجوانب هذا و بكل
+
+144
+00:12:20,950 --> 00:12:27,220
+الزوايافهذا الضوء بنسميه unpolarized light بمعنى
+
+145
+00:12:27,220 --> 00:12:30,720
+ضوء غير مستقطب إيش معنى ضوء غير مستقطب؟ it
+
+146
+00:12:30,720 --> 00:12:36,700
+vibrates in all directions بتحرك ال vibrations
+
+147
+00:12:36,700 --> 00:12:41,800
+بتاعونه في كل الاتجاهات هذا الضوء إيش بيكون؟
+
+148
+00:12:41,800 --> 00:12:47,820
+unpolarized غير مستقطب يعني بيعمل ال vibrations in
+
+149
+00:12:47,820 --> 00:12:52,850
+all directionsالان هذا الضوء غير المستقبل لو حطينا
+
+150
+00:12:52,850 --> 00:12:57,570
+جدامه شغلة بنسميها polarizer شغلة بنسميها
+
+151
+00:12:57,570 --> 00:13:03,150
+polarizer هذا ال polarizer بإمكانكوا تتخيلوه كأنه
+
+152
+00:13:03,150 --> 00:13:07,990
+يمثل نوعا ما بنعمل من ال crystals كأنه يمثل فتحة
+
+153
+00:13:07,990 --> 00:13:12,730
+زي هي شايفين هذه الفتحة؟اللي بين الأصبعين، الآن لو
+
+154
+00:13:12,730 --> 00:13:16,890
+أنا عندي ضوء بتحرك زي هيك، بتحرك زي هيك، بتحرك زي
+
+155
+00:13:16,890 --> 00:13:20,990
+هيك وإجيت حاطيت قدامه هذه الفتحة، اللي بتحرك زي
+
+156
+00:13:20,990 --> 00:13:26,030
+هيك مش راح يمر، اللي بتحرك زي هيك مش راح يمر، اللي
+
+157
+00:13:26,030 --> 00:13:31,190
+بتحرك باتجاه الفتحة هو فقط اللي بيمربلاحظين، بناء
+
+158
+00:13:31,190 --> 00:13:35,270
+على ذلك، الضوء اللي قبل ال polarizer بتحرك بكل
+
+159
+00:13:35,270 --> 00:13:39,970
+الاتجاهات، بعد ال polarizer، بتحرك بس في مستوى
+
+160
+00:13:39,970 --> 00:13:45,790
+واحد، واضح؟ بنسميه إيش إحنا في هذه الحالة؟ plain
+
+161
+00:13:45,790 --> 00:13:51,090
+polarized lightفكان عندنا unpolarized light غير
+
+162
+00:13:51,090 --> 00:13:55,010
+مستقطب صار plain polarized light معنى plain
+
+163
+00:13:55,010 --> 00:13:58,650
+polarized light أنه مستقطب في مستوى واحد هاي
+
+164
+00:13:58,650 --> 00:14:04,990
+المستوى شايفينه فبصير يتحرك في مستوى واحد الآن هذا
+
+165
+00:14:04,990 --> 00:14:11,210
+الضوء بيجيوا بمرروه على أنبوبة تقريبا الانبوبة زي
+
+166
+00:14:11,210 --> 00:14:16,910
+هذا الجلم بالظبطوطولها حوالي عشرة صنطي بشكل عام في
+
+167
+00:14:16,910 --> 00:14:22,570
+معظم الأجهزة بتكون بالظبط عشرة صنطميتر و هذه
+
+168
+00:14:22,570 --> 00:14:27,670
+الأنبوبة بيحطوا فيها محلول للمركب اللي بدنا نقيس
+
+169
+00:14:27,670 --> 00:14:34,250
+إيش اللي هو الدوران تبعه الآن إذا حطينا نفترض
+
+170
+00:14:34,250 --> 00:14:40,330
+كنقطة بداية في هذه الأنبوبة ميةماشي الحال .. الضوء
+
+171
+00:14:40,330 --> 00:14:44,410
+ماشي بأي اتجاه .. بهذا الاتجاه .. هيدخل على الميه
+
+172
+00:14:44,410 --> 00:14:47,570
+.. هيظل ماشي بهذا الاتجاه .. الميه مابتعملش فيه
+
+173
+00:14:47,570 --> 00:14:53,010
+إشي .. الآن أنا قلتلكم .. البولارايزر يمثل .. فتحة
+
+174
+00:14:53,010 --> 00:14:56,470
+.. طيب .. لو تخيلتوا أنه فيه كمان فتحة بعده ..
+
+175
+00:14:56,470 --> 00:14:59,610
+يعني كإنكم بتكونوا تتخيلوا .. هاي الفتحتين جايين
+
+176
+00:14:59,610 --> 00:15:05,790
+يقبل بعض .. إيش موجود بينهم؟المحلول .. المادة ..
+
+177
+00:15:05,790 --> 00:15:10,970
+إذا المادة كانت مثل الميّه .. إذا المادة كانت مثل
+
+178
+00:15:10,970 --> 00:15:14,070
+الميّه .. الضوء بدخل بهذا الاتجاه و بيطلع بنفس
+
+179
+00:15:14,070 --> 00:15:17,930
+الاتجاه .. بناء على ذلك طالما الفتحتين قبل بعض دخل
+
+180
+00:15:17,930 --> 00:15:21,910
+من هنا .. بيظلوا ماشي عدل عدل عدل .. بيطلع من هذا
+
+181
+00:15:21,910 --> 00:15:26,530
+.. بنكون حاطين وراه شاشةإيه بتضوي الشاشة؟ مش
+
+182
+00:15:26,530 --> 00:15:30,270
+الشاشة لما يسقط عليها الضوء بتضوي؟ إذا هل الضوء
+
+183
+00:15:30,270 --> 00:15:38,110
+هذا صارله دوران بسبب مروره في المحلول؟ لأ طيب لو
+
+184
+00:15:38,110 --> 00:15:43,090
+حطينا عد في هذا المحلول كان محلول ل one in a
+
+185
+00:15:43,090 --> 00:15:50,830
+number يعني نفترض ر in a number هنلاحظ أنه مررنا
+
+186
+00:15:50,830 --> 00:15:55,420
+الضوءفي هذا الانان شمر كان هيوزاي هيك مررنا
+
+187
+00:15:55,420 --> 00:16:03,300
+وقاعدين بنطلع وين احنا؟ ع الشاشة الشاشة ماضوتش ايش
+
+188
+00:16:03,300 --> 00:16:07,280
+معناه ان الشاشة ماضوتش؟ ان الدوق بطل ماشي باتجاه
+
+189
+00:16:07,280 --> 00:16:14,180
+الفتحة الدوق عمل دوران صار مايخرجش من هذه الفتحة
+
+190
+00:16:21,470 --> 00:16:26,330
+بعد ما دخل ال solution صار بهذا الشكل ماطلعش من
+
+191
+00:16:26,330 --> 00:16:31,430
+الفتحة ماضواتش الشاشة الان لف بزاوية معينة خليني
+
+192
+00:16:31,430 --> 00:16:38,320
+افترض انه لف ب 30 درجة او 40 درجةزاوية محددة بيلف
+
+193
+00:16:38,320 --> 00:16:42,920
+فيها الضوء، واضح؟ طب لو أنا بدي الشاشة تضوي، إيش
+
+194
+00:16:42,920 --> 00:16:49,620
+بعمل؟ بإمكاني أكون مسبت هذه ال slit أو الفتحة على
+
+195
+00:16:49,620 --> 00:16:53,440
+منجلة و تكون إلي محور بتلف حوالين، مش أنا بقول
+
+196
+00:16:53,440 --> 00:16:58,100
+الضوء صار زي هيك؟بضلني ألف ألف ألف ألف لحظة ما
+
+197
+00:16:58,100 --> 00:17:03,120
+يصير هادف أتحطها مع اتجاه الضوء بيخترقها الضوء
+
+198
+00:17:03,120 --> 00:17:07,480
+بتضو الشاشة كانت هيك الزاوية لفت عشرين درجة تلاتين
+
+199
+00:17:07,480 --> 00:17:13,020
+درجة إذا بإمكان أجيس الزاوية واضح؟ ببساطة الآن لو
+
+200
+00:17:13,020 --> 00:17:19,540
+جبنا محلول من الانانشو مرة تانية بنفس التركيزو
+
+201
+00:17:19,540 --> 00:17:23,400
+جينا عدنا التجربة هلاحظ إذا المحلول الأول لف زي
+
+202
+00:17:23,400 --> 00:17:27,900
+هيك التاني بيلف بالاتجاه المعاكس و أجتا بيدلف هذه
+
+203
+00:17:27,900 --> 00:17:32,700
+بالعكس كأنه لو هذا لف زائد عشرين هذا بيكون لف إيش
+
+204
+00:17:32,700 --> 00:17:39,240
+ناقص عشرين إذا هم بس بيختلفوا ال enantiomers كيف
+
+205
+00:17:39,240 --> 00:17:45,380
+بيلفواالضوء، واحد بيلف فوق لليمين، التاني بيلف فوق
+
+206
+00:17:45,380 --> 00:17:52,740
+للشمال، لكن مقدار الدوران نفس الأشياء طبعا مقدار
+
+207
+00:17:52,740 --> 00:17:59,340
+الدوران نفس الأشياء، بشرط أن أستعمل نفس التركيز
+
+208
+00:18:00,100 --> 00:18:04,540
+ليش؟ لأن مقدار الدوران هذا اللي بيصير عندى يعتمد
+
+209
+00:18:04,540 --> 00:18:09,920
+على التركيز بمعنى كل ما بيزيد تركيز المحلول عند
+
+210
+00:18:09,920 --> 00:18:14,800
+الدوران بيزيد يعني لو عملت أربع محليل واحد point
+
+211
+00:18:14,800 --> 00:18:17,400
+one molar point two molar point three molar point
+
+212
+00:18:17,400 --> 00:18:22,580
+four molar وكنت قاعد بقيس مقدار الدوران كل ما
+
+213
+00:18:22,580 --> 00:18:27,700
+بيزيد مقدار الدوران إيش بيصير عنده؟كل ما بيزيد
+
+214
+00:18:27,700 --> 00:18:32,480
+التركيز بيزيد مقدار الدوران الـ A هذه الخاصية اللي
+
+215
+00:18:32,480 --> 00:18:36,100
+بتعتمد على المقدار اتعلمنا احنا في انواع الخواص
+
+216
+00:18:36,100 --> 00:18:40,120
+انها extensive و intensive بتكون extensive
+
+217
+00:18:40,120 --> 00:18:43,740
+بروبراطي هذه الخاصية احنا ايش بنسميها rotation
+
+218
+00:18:44,560 --> 00:18:50,980
+الدوران فال rotation is an extensive property
+
+219
+00:18:50,980 --> 00:18:56,640
+تعتمد على مقدار المادة جد ما بحط مادة جد ما بيصير
+
+220
+00:18:56,640 --> 00:19:03,880
+عنده ايش زيادة دوران تماما زي مثلا خاصية الوزن او
+
+221
+00:19:03,880 --> 00:19:08,760
+الحجم الحجم عبارة عن extensive property كل ما بحط
+
+222
+00:19:08,760 --> 00:19:15,490
+حديد زيادة كل ما الوزن ايش بزيدلكن الـ intensive
+
+223
+00:19:15,490 --> 00:19:21,270
+properties اتعلمنا انها لا تعتمد على المقدار و من
+
+224
+00:19:21,270 --> 00:19:25,330
+امثلة ال intensive properties اذا بتذكروا ال
+
+225
+00:19:25,330 --> 00:19:31,450
+melting point ال boiling point ال density مثلا
+
+226
+00:19:31,450 --> 00:19:35,950
+اعطيكم مثال لو افترضتوا الحجم extensive ولا
+
+227
+00:19:35,950 --> 00:19:41,450
+intensiveextensive يعتمد على المقدار الان اتخيلوا
+
+228
+00:19:41,450 --> 00:19:45,790
+مثلا ان انتوا جيبتوا 100 مل ميه بتغلي ايش يعني ميه
+
+229
+00:19:45,790 --> 00:19:52,670
+بتغلي؟ يعني درجة حرارتها مية وكمان 100 مل ميه
+
+230
+00:19:52,670 --> 00:20:00,760
+بتغلي وضفتوا الشغلتين على بعض شو بينتج عندكم؟ميتين
+
+231
+00:20:00,760 --> 00:20:07,580
+من الميه بتغلي الان الحجم جمعت في مية زائد مية،
+
+232
+00:20:07,580 --> 00:20:11,400
+قداش صار؟ ميتين، اذا الحجم is an extensive
+
+233
+00:20:11,400 --> 00:20:17,120
+property ال boiling point للميه الأولى مية، للميه
+
+234
+00:20:17,120 --> 00:20:22,140
+التانية مية، لإنتج مية، كإني بقول مية زائد مية
+
+235
+00:20:22,140 --> 00:20:27,570
+يساوي ميةكأني قاعد بقول مية زاد مية يساوي مية نفس
+
+236
+00:20:27,570 --> 00:20:33,070
+الاشي الكثافة لو جيبت مية برميل كثافته واحد مظبوط
+
+237
+00:20:33,070 --> 00:20:36,750
+ولا لأ one gram لكل centimeter و حطيته على برميل
+
+238
+00:20:36,750 --> 00:20:41,930
+كثافته واحد إيش هيصير عندى برميلين إذا الحجم
+
+239
+00:20:43,310 --> 00:20:47,230
+Extensive Property جمع كتافة الميه في البرميلين
+
+240
+00:20:47,230 --> 00:20:52,230
+واحد واضح الان ال rotation اللى احنا اخدناه هل هو
+
+241
+00:20:52,230 --> 00:20:55,930
+Extensive ولا Intensive Property Extensive
+
+242
+00:20:55,930 --> 00:21:00,330
+Property ال Extensive Property المشكلة بقدرش كتير
+
+243
+00:21:00,330 --> 00:21:04,390
+استفيد منها احطها بجداول و اعرف المادة من خلالها
+
+244
+00:21:04,980 --> 00:21:10,360
+يعني مثلاً للميه بتلاقوا ال boiling point خاصية
+
+245
+00:21:10,360 --> 00:21:13,900
+معروفة للميه كلكم بتعرفوها لأنها intensive ال
+
+246
+00:21:13,900 --> 00:21:19,240
+density كلكم بتعرفوها لأنها intensive ال melting
+
+247
+00:21:19,240 --> 00:21:24,080
+point كلكم بتعرفوها لأنها intensive لكن اتخيل لو
+
+248
+00:21:24,080 --> 00:21:29,260
+بدأتش اسألكوا سؤال ما هي كتلة الماء؟هذه خاصية
+
+249
+00:21:29,260 --> 00:21:32,540
+بتنحط في الكتب ولا بتتعرف من خلالها الماء؟ ليش؟
+
+250
+00:21:32,540 --> 00:21:35,260
+لأن كل كم مياه لها كتلة وكل كم مياه لها كتلة،
+
+251
+00:21:35,260 --> 00:21:39,320
+واضح؟ فأنا مابستفيدش من الكتلة و الحجم إن أتعرف
+
+252
+00:21:39,320 --> 00:21:43,590
+على المياه، دايما اللي بيفيدني القياشالـ intensive
+
+253
+00:21:43,590 --> 00:21:47,650
+property بناء على ذلك ضمن هذا المفهوم ال rotation
+
+254
+00:21:47,650 --> 00:21:53,290
+هيفيدني أن أتعرف على المادة لأ لأن لكل تركيز
+
+255
+00:21:53,290 --> 00:22:00,190
+rotation بمعنى للمادة هيكون عدد لا نهائي من ال
+
+256
+00:22:00,190 --> 00:22:07,030
+rotations لكن بإمكاني أعمل عمليات بسيطة جدا حسابات
+
+257
+00:22:07,030 --> 00:22:12,190
+بسيطة جدا أطلع خاصية تكون intensive تتعلق بالمادة
+
+258
+00:22:13,160 --> 00:22:17,140
+تماما زي ما احنا في حالة الميه بنقول ان الكتلة
+
+259
+00:22:17,140 --> 00:22:23,460
+extensive يوجد عدد لنهائة من الكتلة للميه الحجم
+
+260
+00:22:23,460 --> 00:22:28,020
+extensive يوجد عدد لنهائة من الحجوم للميه اجينا
+
+261
+00:22:28,020 --> 00:22:33,830
+جسمنا الكتلة على الحجمطلعت intensive بتذكروا أخدته
+
+262
+00:22:33,830 --> 00:22:37,070
+أن extensive على extensive بيساوي intensive
+
+263
+00:22:37,070 --> 00:22:40,990
+property إذا حصلنا على ال density اللي هي صفة
+
+264
+00:22:40,990 --> 00:22:44,990
+جوهرية أساسية للمي بقدر أكتبها في جداول و أحطها في
+
+265
+00:22:44,990 --> 00:22:50,130
+الكتب بنفس المنطق كان عندكم عشان نذكركم في الكيميا
+
+266
+00:22:50,130 --> 00:22:55,020
+ال heat capacity و ال specific heatالـ heat
+
+267
+00:22:55,020 --> 00:22:59,720
+capacity كل جطعة حديد لها heat capacity بمعنى
+
+268
+00:22:59,720 --> 00:23:06,140
+للحديد عندى عدد لانهائى من اللى هى بنسميها الحرارة
+
+269
+00:23:06,140 --> 00:23:11,580
+النوعى السعة الحرارية او ال heat capacity لما
+
+270
+00:23:11,580 --> 00:23:16,160
+بديها تكون خاصية جوهرية مثلا للميه للحديد للانحاس
+
+271
+00:23:16,160 --> 00:23:22,400
+الان لو قلتلكوا للميه قداش ال heat capacityمافيش
+
+272
+00:23:22,400 --> 00:23:26,620
+حسب كميتها عندي عدد لا نهائي طب ها إيش الخاصية
+
+273
+00:23:26,620 --> 00:23:31,940
+اللي بتفيد دي ال specific heat إن أقسم ال heat
+
+274
+00:23:31,940 --> 00:23:37,680
+capacity على الكتلة بتطلع عندي خاصية كل كوك و
+
+275
+00:23:37,680 --> 00:23:41,160
+أجدها بتقدروا تقولولي قداش قيمة ال specific heat
+
+276
+00:23:41,160 --> 00:23:45,220
+للميه 4
+
+277
+00:23:45,220 --> 00:23:53,800
+.18 جول لكل جراممظبوط ولا لأ؟ اه واضح فبتصير
+
+278
+00:23:53,800 --> 00:23:59,480
+العملية إيش مالها؟ سهلة الكلام نفسه بنعمله مع ال
+
+279
+00:23:59,480 --> 00:24:02,900
+rotation ال rotation is an extensive probability
+
+280
+00:24:02,900 --> 00:24:07,460
+بنعرف خاصية specific rotation بنحطها بين جثين
+
+281
+00:24:07,460 --> 00:24:11,960
+مربعين هذه intensive probability إيش بتساوي ال
+
+282
+00:24:11,960 --> 00:24:17,080
+specific rotation؟ ال observed rotation التفاق لإن
+
+283
+00:24:17,080 --> 00:24:21,040
+extensive ولا intensive؟extensive هذا ال rotation
+
+284
+00:24:21,040 --> 00:24:25,900
+العادل اللي بيطلع بالقياس مقصوم على طول الأنبوبة
+
+285
+00:24:25,900 --> 00:24:30,640
+بال decimeter بشكل عام إحنا بناخد الأنبوبة تكون
+
+286
+00:24:30,640 --> 00:24:34,880
+عشرة centimeter عشرة centimeter يعني إيش one
+
+287
+00:24:34,880 --> 00:24:39,060
+decimeter مقصوم على ال concentration ال
+
+288
+00:24:39,060 --> 00:24:44,480
+concentration التركيز فبصير عندي فادع على
+
+289
+00:24:44,480 --> 00:24:50,000
+extensive على extensive لإن عندي تركيزمختلفة
+
+290
+00:24:50,000 --> 00:24:56,020
+بستعمل تركيز اشملها مختلفةبصير عندى الـ specific
+
+291
+00:24:56,020 --> 00:25:01,920
+rotation خاصية للمادة تُكتب في الجداول بمعنى أي
+
+292
+00:25:01,920 --> 00:25:07,380
+مُركّب R لو مسكته و حاطيته في الـ polarimeter في
+
+293
+00:25:07,380 --> 00:25:11,920
+غزة و في أمريكا و في اليابان و في ألمانيا بجزله
+
+294
+00:25:11,920 --> 00:25:16,560
+rotation بطلع ال rotation مختلف بجسم rotation ع
+
+295
+00:25:16,560 --> 00:25:19,100
+التركيز rotation ع التركيز rotation ع التركيز على
+
+296
+00:25:19,100 --> 00:25:25,450
+أساس عفرضيته أن هذا بتسوي إيش؟ واحدبطلع نفس القيمة
+
+297
+00:25:25,450 --> 00:25:29,930
+specific rotation زي تماما واحد ماخد ميه أربع
+
+298
+00:25:29,930 --> 00:25:32,790
+أنواع من الكتل كتلة ع حجم كتلة ع حجم كتلة ع حجم
+
+299
+00:25:32,790 --> 00:25:37,050
+كتلة ع حجم بطلع ايش نفس ال density هنا rotation
+
+300
+00:25:37,050 --> 00:25:40,030
+rotation rotation rotation ميت نوع من ال rotation
+
+301
+00:25:40,030 --> 00:25:43,110
+بس كل rotation ع التركيز ع التركيز ع التركيز ع
+
+302
+00:25:43,110 --> 00:25:49,050
+التركيز وبيعطينا نفس القيمة فبصير في الكتب كل مركب
+
+303
+00:25:50,510 --> 00:25:54,510
+بيدور الضوء بنسميه كايرا الموليكيول إله specific
+
+304
+00:25:54,510 --> 00:25:59,090
+rotation بتلحق في الكتب زي ما إله melting point و
+
+305
+00:25:59,090 --> 00:26:02,450
+boiling point إله خاصية اسمها إيش ال specific
+
+306
+00:26:02,450 --> 00:26:08,890
+rotation هذا ال specific rotation يا بيكون plusيا
+
+307
+00:26:08,890 --> 00:26:13,510
+بيكون minus بمعنى أن المراكبات يا بتلف الضوء على
+
+308
+00:26:13,510 --> 00:26:18,170
+اليمين بنقول عنها dextrorotatory أو بتلفه على
+
+309
+00:26:18,170 --> 00:26:22,450
+الشمال بنقول عنها levorotatory إذا واحد من ال
+
+310
+00:26:22,450 --> 00:26:28,610
+enantiomers كان plus، التاني minus وبنفس المقدار
+
+311
+00:26:28,610 --> 00:26:34,360
+بالنسبة لإيش؟ لل specific rotationالمقدار ما
+
+312
+00:26:34,360 --> 00:26:37,660
+بيختلف بال specific rotation شو اللي بيختلف عنده
+
+313
+00:26:37,660 --> 00:26:42,600
+الاتجاه وهذا اللي احنا بنقصده و ضيعنا فيه وقت كبير
+
+314
+00:26:42,600 --> 00:26:47,060
+ان ال enantiomers they have the same physical
+
+315
+00:26:47,060 --> 00:26:53,720
+properties except for direction of rotation مش
+
+316
+00:26:53,720 --> 00:27:00,180
+amount of rotation او magnitude of rotation واضح؟
+
+317
+00:27:00,670 --> 00:27:03,930
+يعني لو بدنا نسألكوا في صح و غلط ان ال enantiomers
+
+318
+00:27:03,930 --> 00:27:07,250
+they have the same physical properties except for
+
+319
+00:27:07,250 --> 00:27:13,170
+the amount of rotation لأ ال direction of rotation
+
+320
+00:27:13,170 --> 00:27:17,730
+اللي بيختلف لكن ال specific rotation للتانين نفس
+
+321
+00:27:17,730 --> 00:27:21,490
+القيمة بس واحد منهم بيكون plus واحد بيكون إيش
+
+322
+00:27:21,490 --> 00:27:26,430
+minus طبعا هذا الكلام لو مركب R أو مركب S أو أي
+
+323
+00:27:26,430 --> 00:27:29,710
+مركب لو فيه أكتر من R و S بس المهم يكونوا إيش
+
+324
+00:27:30,610 --> 00:27:35,190
+انانشو مارس المهم يعني اي two انانشو مارس باخدهم
+
+325
+00:27:35,190 --> 00:27:37,850
+على البولاري متر واحد بيلوف على اليمين و واحد
+
+326
+00:27:37,850 --> 00:27:40,730
+بيلوف على الشمال ان شاء الله يكون فيه تلاتة اربعة
+
+327
+00:27:40,730 --> 00:27:44,370
+خمسة كايرال سنترز مش كتير بيفرق المهم يكونوا إياش
+
+328
+00:27:44,370 --> 00:27:52,090
+انانشو مارسطبعا هنا بحطوا حرف ال D، ال D يعني اللي
+
+329
+00:27:52,090 --> 00:27:55,150
+هو نوع الضوء المستخدم، ضوء الصوديوم، بيستعملوا
+
+330
+00:27:55,150 --> 00:27:58,910
+الخط اللي بيسموه D و مرات بكتبوا هنا 25 اللي هي
+
+331
+00:27:58,910 --> 00:28:03,330
+درجة الحرارة، هذه يعني معلومات إنه القياس على أي
+
+332
+00:28:03,330 --> 00:28:11,390
+شيء بيتمهنا بيجينا شغلة انه اي enantiomer بيلف
+
+333
+00:28:11,390 --> 00:28:16,690
+الضوء باتجاه معين بنسميه احنا ايش؟ chiral molecule
+
+334
+00:28:16,690 --> 00:28:20,270
+و بنقول عنه optically active ايش معنى optically
+
+335
+00:28:20,270 --> 00:28:25,630
+active؟ انه بيلف الضوء الآن الميه optically
+
+336
+00:28:25,630 --> 00:28:32,070
+inactive عشان المركب يكون optically active بدي
+
+337
+00:28:32,070 --> 00:28:37,480
+يكون ايش؟one enantiomer الكائرة الموليكيولز
+
+338
+00:28:37,480 --> 00:28:43,980
+بيكونوا optically active بينما مركب فيه أربع ذرات
+
+339
+00:28:43,980 --> 00:28:48,080
+هدولة لمختلفات أو زي أي نوع من ال enantiomers
+
+340
+00:28:48,080 --> 00:28:55,370
+بيكونinactive الآن لاحظوا معي أنا قلت لك لو أخدت
+
+341
+00:28:55,370 --> 00:28:59,190
+one in one شمار بلف بزاوية معينة موجبة لو أخدت
+
+342
+00:28:59,190 --> 00:29:04,810
+التاني بزاوية معينة سالبة طيب لو خلطتهم بنفس
+
+343
+00:29:04,810 --> 00:29:12,930
+النسبة و حطيتهم في ال polarimeter ايش بيكونوا؟
+
+344
+00:29:12,930 --> 00:29:18,380
+اهواحد بيودي و واحد بيجيب و إذا صاروا واحد يودي و
+
+345
+00:29:18,380 --> 00:29:24,770
+واحد يجيب المحاصلة الكلية إيش؟ صفرواضح؟ و هذا
+
+346
+00:29:24,770 --> 00:29:28,250
+المخلوط اللي بيكون خمسين في المية من هذا ال
+
+347
+00:29:28,250 --> 00:29:32,390
+enantiomer و خمسين في المية من هذا ال enantiomer
+
+348
+00:29:32,390 --> 00:29:37,030
+بيسمحنا racemic mixture أو racemic modification
+
+349
+00:29:37,030 --> 00:29:42,150
+بيكون ال rotation تبعه سفر فبنقول ال racemic
+
+350
+00:29:42,150 --> 00:29:45,770
+mixture or racemic modification is one with equal
+
+351
+00:29:45,770 --> 00:29:50,430
+ratios of enantiomers fifty fifty بيكون optically
+
+352
+00:29:50,430 --> 00:29:56,450
+active ولا inactive؟inactive هذا optically
+
+353
+00:29:56,450 --> 00:30:02,150
+inactive يعني لا بدور ال polarimeter شمال ولا يمين
+
+354
+00:30:03,560 --> 00:30:07,440
+واضح؟ أنا دائما بحب .. يعني أشبه للطلاب هذا
+
+355
+00:30:07,440 --> 00:30:13,180
+الموضوع زي أمة إذا كانت والله جهودها موحدة بتكون
+
+356
+00:30:13,180 --> 00:30:16,920
+active اتخيلوا عدد هذه الأمة لو كانت مجسومة جسمين
+
+357
+00:30:16,920 --> 00:30:20,840
+زي حالنا وحال تلت ارباع العرب هذا النص بضرب في هذا
+
+358
+00:30:20,840 --> 00:30:27,100
+النص، إيش المحاصلة؟ صفر، المحاصلة صفر حتى لو لو
+
+359
+00:30:27,100 --> 00:30:33,710
+كنت .. حتى لو لو كنت .. حتى لو لو كنت ..أه كويس
+
+360
+00:30:33,710 --> 00:30:38,530
+السؤال .. السؤال ازملتكوا كويس احنا بنقول إذا كان
+
+361
+00:30:38,530 --> 00:30:42,910
+one in nine شمار بيكون optically active إذا كان
+
+362
+00:30:42,910 --> 00:30:50,210
+fifty fifty بيكون optically inactive الآن ممكن يجي
+
+363
+00:30:50,210 --> 00:30:58,050
+السؤال لو كان خمسة وسبعين في المية مثلا من ال plus
+
+364
+00:30:58,050 --> 00:31:04,710
+I شمار وخمسة وعشرين في الميةمن الـ minus I زمان
+
+365
+00:31:04,710 --> 00:31:08,910
+جديش
+
+366
+00:31:08,910 --> 00:31:14,410
+بده يطلع يعني لو افترضت مركب انتبهوا معاه مركب
+
+367
+00:31:14,410 --> 00:31:20,350
+بصيغته النقية يعني لو حطيته بيكون plus 20 و بيكون
+
+368
+00:31:20,350 --> 00:31:27,410
+minus 20 لو أخدت منه ال plus النقى plus 20 لو أخدت
+
+369
+00:31:27,410 --> 00:31:34,260
+منه ال minus النقى-20 متساوية الان لو اعملت منه
+
+370
+00:31:34,260 --> 00:31:40,900
+خليط من ال plus و ال minus حطيت 75% من ال plus و
+
+371
+00:31:40,900 --> 00:31:45,720
+25% من ال minus قداش بيكون ال rotation لهذا الخليط
+
+372
+00:31:45,720 --> 00:31:57,510
+اعطوني قيمة كام درجة كام درجةشوفوا دائما لازم
+
+373
+00:31:57,510 --> 00:32:01,750
+الجواب يكون أقل من العشرين هذه لأن العشرين للنقي
+
+374
+00:32:01,750 --> 00:32:07,910
+هو أقل من النقي هو أقل من النقي العشرين لأعلى
+
+375
+00:32:07,910 --> 00:32:13,050
+مستوى زي بني آدم اللي محصل أعلى أعلى أنا بديت أخصم
+
+376
+00:32:13,050 --> 00:32:20,730
+منه جديش بده تكون زاويته كيف حسبتيها؟ اه الزاوية
+
+377
+00:32:20,730 --> 00:32:26,450
+أنا بقول النقيبكون plus 20 و الناقط تاني minus 20
+
+378
+00:32:26,450 --> 00:32:30,490
+أخدت من هذا point 7 five gram نفترض من هذا point 2
+
+379
+00:32:30,490 --> 00:32:33,690
+five gram أعملت محلول August وقدش بتطلع الزاوية
+
+380
+00:32:33,690 --> 00:32:37,750
+عشرة
+
+381
+00:32:37,750 --> 00:32:45,090
+عشرة مش خمس عشر ليش؟ لأنه بديكوا تتخيلوا أن هذه ال
+
+382
+00:32:45,090 --> 00:32:53,240
+minus 25 أجت على ال plus 75 عدلت منهم 25يعني كأنه
+
+383
+00:32:53,240 --> 00:32:58,600
+هذه عبارة عن plus خمسين و plus خمسة و عشرين هي
+
+384
+00:32:58,600 --> 00:33:02,620
+plus خمسة و سبعين و أنا إيش عندى؟ minus خمسة و
+
+385
+00:33:02,620 --> 00:33:09,680
+عشرين هدولة شطّبوا بعض جديد صار عندى plus خمسين
+
+386
+00:33:09,680 --> 00:33:16,580
+خمسين في المية من هدولة عشر هذا المحلول بيكون عشر
+
+387
+00:33:16,580 --> 00:33:19,440
+واضح؟
+
+388
+00:33:20,140 --> 00:33:24,660
+هذا المحلول زاويت وبتكون عشرة لأنه لما بتكون تيجي
+
+389
+00:33:24,660 --> 00:33:28,020
+و تعملوا الإحسابات بتقولوا أنه ال minus خمسة و
+
+390
+00:33:28,020 --> 00:33:33,880
+عشرين عادلت من هدولة plus خمسة و عشرين، كداش ضار
+
+391
+00:33:33,880 --> 00:33:38,240
+عندي زيادة في ال plus؟ نص ال plus، نص العشرين؟
+
+392
+00:33:38,240 --> 00:33:40,780
+عشرة، عشرة، عشرة، عشرة، عشرة، عشرة، عشرة، عشرة،
+
+393
+00:33:40,780 --> 00:33:40,960
+عشرة، عشرة، عشرة، عشرة، عشرة، عشرة، عشرة، عشرة،
+
+394
+00:33:40,960 --> 00:33:43,790
+عشرة، عشرة، عشرة، عشرة، عشرة، عشرة، عشرة، عشانه
+
+395
+00:33:43,790 --> 00:33:49,350
+انا النقي بيكون اعلى زاوية الار تنسوش انه احنا في
+
+396
+00:33:49,350 --> 00:33:54,510
+الرسمك شو قلنا ال plus خمسين و ال minus خمسين ايش
+
+397
+00:33:54,510 --> 00:34:00,150
+كانت الزاوية تبعتهم ال alpha او حتى الاسم صفر صفر
+
+398
+00:34:00,150 --> 00:34:05,790
+شطبوا بعض، مظبوط ولا لا؟ اه مابطلعوش خمسين في
+
+399
+00:34:05,790 --> 00:34:10,590
+المية من القيمة، خلاص شطبوا بعض، شطبوا بعض، فيا
+
+400
+00:34:10,590 --> 00:34:16,800
+بيكون نقييا بيكون مشطب على الآخر إذا equal amounts
+
+401
+00:34:16,800 --> 00:34:22,280
+اللي هو بسميه racemic mixtures هذا بيكون optically
+
+402
+00:34:22,280 --> 00:34:27,200
+inactive هذا أعلى optical activity هذا in between
+
+403
+00:34:27,200 --> 00:34:35,740
+بتيجي للمخلوط هذا بين بين واضح طبعا بتكون تقول
+
+404
+00:34:35,740 --> 00:34:42,390
+الإشارة دائما يعني لو نعطيكوا مثال تانيلو من نفس
+
+405
+00:34:42,390 --> 00:34:51,810
+هذا المحلول إجينا أخدنا minus تلاتين
+
+406
+00:34:51,810 --> 00:34:59,890
+و أخدنا بلاش minus سبعين و
+
+407
+00:34:59,890 --> 00:35:04,830
+plus تلاتين لما
+
+408
+00:35:04,830 --> 00:35:11,020
+بتيجوا بتحسبوا إيش بتقولوا ميل الزايدالسبعين، إذا
+
+409
+00:35:11,020 --> 00:35:16,560
+المحلول بالمجمل هيكون minus ولا plus؟ minus جداش
+
+410
+00:35:16,560 --> 00:35:22,240
+ال excess minus، مزيادة في ال minus، جداش؟ بيساوي
+
+411
+00:35:22,240 --> 00:35:28,400
+ناقص سبعين زائد تلاتين، بيساوي ناقص أربعين
+
+412
+00:35:28,400 --> 00:35:33,600
+الأربعين هذه بضربها في الزاوية النقية، إيش الزاوية
+
+413
+00:35:33,600 --> 00:35:37,640
+النقية؟ يعني كأنها بيقول أربعين عالمية ضارب عشرين
+
+414
+00:35:42,970 --> 00:35:49,450
+واضح؟ ممكنكوا تعملوا الاحسابات تمانية بالزال ..
+
+415
+00:35:49,450 --> 00:35:52,270
+بالزال .. بالزال .. بالزال .. بالزال .. بالزال ..
+
+416
+00:35:52,270 --> 00:35:52,670
+بالزال .. بالزال .. بالزال .. بالزال .. بالزال ..
+
+417
+00:35:52,670 --> 00:35:52,870
+بالزال .. بالزال .. بالزال .. بالزال .. بالزال ..
+
+418
+00:35:52,870 --> 00:35:55,590
+بالزال .. بالزال .. بالزال .. بالزال .. بالزال ..
+
+419
+00:35:55,590 --> 00:35:55,710
+بالزال .. بالزال .. بالزال .. بالزال .. بالزال ..
+
+420
+00:35:55,710 --> 00:35:57,350
+بالزال .. بالزال .. بالزال .. بالزال .. بالزال ..
+
+421
+00:35:57,350 --> 00:36:06,810
+بالزال .. بالزال .. بالزال .. بالزال
+
+422
+00:36:06,810 --> 00:36:15,020
+.. بالزال ..اللي بيختلفوا فيها ال .. ال
+
+423
+00:36:15,020 --> 00:36:19,160
+enantiomers من الخواص الفيزيائي، الآن نرجع لل
+
+424
+00:36:19,160 --> 00:36:25,200
+enantiomers من ناحية chemical probiotesisإذا
+
+425
+00:36:25,200 --> 00:36:28,820
+نفهمنا ال physical properties كويس ال enantiomers
+
+426
+00:36:28,820 --> 00:36:32,800
+لهم نفس ال physical properties ما عدا اتجاه تدوير
+
+427
+00:36:32,800 --> 00:36:37,020
+الضوء الآن بالنسبة ل ال chemical properties بنقول
+
+428
+00:36:37,020 --> 00:36:39,480
+ال enantiomers they have the same chemical
+
+429
+00:36:39,480 --> 00:36:43,120
+properties except for their reaction with other
+
+430
+00:36:43,120 --> 00:36:48,180
+chiral molecules وهذا تقريبا اللي شغاله موجود في
+
+431
+00:36:48,180 --> 00:36:54,850
+ال biological systems و في الأدوية أنه أناالانانشو
+
+432
+00:36:54,850 --> 00:37:02,270
+مارزا دولة بس بيختلفوا إذا تفاعلوا مع أشياء كايرال
+
+433
+00:37:02,270 --> 00:37:07,210
+زيهم كايرال يعني فيها شمال ويمين واضح؟ بعد ذلك
+
+434
+00:37:07,210 --> 00:37:12,610
+بيكونوا إيش؟ مابيختلفوش خليني أعطيكم تشبيه عشان
+
+435
+00:37:12,610 --> 00:37:18,690
+انتوا تستوعبوا لو اتخيلتوا مثلا هذا المفتاح هذا
+
+436
+00:37:18,690 --> 00:37:24,370
+المفتاح له فتحة على هذه الجهةمظبوط ولا لأ؟ ونفترض
+
+437
+00:37:24,370 --> 00:37:28,050
+إن هذا مفتاح انحاس، إيه له فتحة على هذه الجهة؟ ال
+
+438
+00:37:28,050 --> 00:37:35,090
+enantiomers تبعه مفتاح تاني، إيه له فتحة على الجهة
+
+439
+00:37:35,090 --> 00:37:40,050
+المقابلة أو المعاكسة؟ الآن لم أبدأ أقول كيميائيا
+
+440
+00:37:40,050 --> 00:37:42,810
+بإيش بيختلفوا هدول المفتاحين، هاي مفتاحين من
+
+441
+00:37:42,810 --> 00:37:45,810
+الانحاس نشبهم كإنهم عبارة عن إيش ال two
+
+442
+00:37:45,810 --> 00:37:52,860
+enantiomers واضح؟لو إجيت أنا هذا المفتاح بدي
+
+443
+00:37:52,860 --> 00:37:58,000
+أفعله، بدي أنفخ بلون، بدي أنحاس، بدي أحطه في حامض
+
+444
+00:37:58,000 --> 00:38:03,740
+و أطلعلي هيدروجين، وعند المفتاحين، بيفرق إن أحط
+
+445
+00:38:03,740 --> 00:38:07,660
+المفتاح اليمين ولا المفتاح في الشمال، الشمال في
+
+446
+00:38:07,660 --> 00:38:12,040
+الحامض عشان أطلعلي هيدروجين؟ الاتنين هيتفعلوا نفس
+
+447
+00:38:12,040 --> 00:38:18,070
+الاشي، أنا هنا بعمل تفاعل مالوش علاقةبالاتجاهات
+
+448
+00:38:18,070 --> 00:38:24,810
+طيب هدولة المفتاحين وين بيفرجوا؟ لشمال وليمين؟ بس
+
+449
+00:38:24,810 --> 00:38:29,510
+في الباب، في الزرفيل هتلاحظوا أنه في باب الإلسان
+
+450
+00:38:29,510 --> 00:38:34,330
+الداخلي تبعه بينطبق مع هذا فهذا بيفتح باب وهذا
+
+451
+00:38:34,330 --> 00:38:38,670
+بيفتح باب نيجي نخل هذا يفتح هذا أو هذا يفتح هذا؟
+
+452
+00:38:38,670 --> 00:38:41,910
+مابظبطش وهذا الكلام نفسه بتكرر في ال biological
+
+453
+00:38:41,910 --> 00:38:47,200
+systems اتخيلوا مثلا أن هذا enzyme بشكل معينأو في
+
+454
+00:38:47,200 --> 00:38:51,860
+عندى enzyme بشكل معين و هذا دوة بشكل معين الان هذا
+
+455
+00:38:51,860 --> 00:38:55,700
+ممكن ييجى يتفاعل معاه التانى بنيجى بيلاقي
+
+456
+00:38:55,700 --> 00:39:00,220
+مابيتفعلش معاه عشانك ممكن two enantiomers واحد
+
+457
+00:39:00,220 --> 00:39:06,240
+منهم يكون دوة والتانى يكون إيش عديم الفائدة يعني
+
+458
+00:39:06,240 --> 00:39:09,200
+مثلا الناس بيروحوا على المستشفى بياخدوا جولوكوز
+
+459
+00:39:09,200 --> 00:39:12,420
+مظبوط الجولوكوز اللى بياخدوه لازم يكون plus
+
+460
+00:39:12,420 --> 00:39:18,480
+جولوكوز لو أخدوا ال minus جولوكوزولا أي أثر شوف
+
+461
+00:39:18,480 --> 00:39:26,160
+لحد وين فممكن يكون .. ممكن يكون ال plus فعال تماما
+
+462
+00:39:26,160 --> 00:39:30,420
+وبيجي مع ال biological system اللي هو بيكون هذا
+
+463
+00:39:30,420 --> 00:39:33,280
+chiral و هذا chiral بمعنى هذا له اتجاهات و هذا له
+
+464
+00:39:33,280 --> 00:39:36,680
+اتجاهات بيجوا على بعض زي أي شغلتين اللي هم اتجاهات
+
+465
+00:39:36,680 --> 00:39:39,980
+احنا بنركبهم في بعض في الألعاب ال league او غيره
+
+466
+00:39:39,980 --> 00:39:46,800
+متخيلين انتوا كيف؟ والتاني ممكن يكونبتفعلش بالمرة
+
+467
+00:39:46,800 --> 00:39:52,160
+ممكن أحيانا قد تستغربوا أن واحد منهم يكون زي ما
+
+468
+00:39:52,160 --> 00:39:57,260
+بيسموه ترياق أو دوة والتاني يكون سم و بس بيختلفوا
+
+469
+00:39:57,260 --> 00:40:01,520
+بإيش أن واحد منهم ب plus واحد minus يعني نفس
+
+470
+00:40:01,520 --> 00:40:05,440
+المركب بنفس الذرات بنفس الشيء بس اتجاههم بالفراغ
+
+471
+00:40:05,440 --> 00:40:10,540
+بيختلف فبصير واحد منهم ممكن يصير دوة والتاني ممكن
+
+472
+00:40:10,540 --> 00:40:16,800
+يكون إيشسمك يمكن بتعرفوا أنواع من ال champignon
+
+473
+00:40:16,800 --> 00:40:21,900
+اذا بتعرفوا او شو بتسموه المشروم او الفطر او عشر
+
+474
+00:40:21,900 --> 00:40:28,560
+الغراب في منه نوعين في نوع اللي زي الشمسية هذا
+
+475
+00:40:28,560 --> 00:40:33,620
+اللي بتاكل لا اللي زي الشمسية هو تبع البيتزا هو
+
+476
+00:40:33,620 --> 00:40:38,910
+اللي بتاكل وفي نوع الهرامالبراميد هذا الـ SAM
+
+477
+00:40:38,910 --> 00:40:44,450
+هدولة بيختلفوا بمركب بس واحد plus واحد minus شوف
+
+478
+00:40:44,450 --> 00:40:49,310
+لحد وين هذا الاختلاف بيخلي واحد منهم يكون مفيد
+
+479
+00:40:49,310 --> 00:40:54,430
+والتاني منهم يصير ايش SAM إذا من ناحية المبدأ في
+
+480
+00:40:54,430 --> 00:40:59,090
+التفاعلات الكيميائية الاختلاف فقط إذا كان كايرة ال
+
+481
+00:40:59,090 --> 00:41:03,950
+molecule اتفاعل معكايرة الموليكيول التاني، بتكون
+
+482
+00:41:03,950 --> 00:41:09,090
+النتائج الكيميائية مختلفة، بعد ذلك they have the
+
+483
+00:41:09,090 --> 00:41:12,910
+same properties، the same chemical properties زي
+
+484
+00:41:12,910 --> 00:41:16,490
+المثال اللي جيبناه لكوا، إن إنحاس لو بده دوبه حامض
+
+485
+00:41:16,490 --> 00:41:19,870
+أو المفتاح بده دوبه حامض، بفرق مفتاح شمال أو يمين؟
+
+486
+00:41:20,300 --> 00:41:24,280
+الـ A نفس الفكرة خدوها إنتوا مثلا لو كان عندكم
+
+487
+00:41:24,280 --> 00:41:27,520
+المُركّبين، الواحد منهم يقولنا عنه دوة و الاتاني
+
+488
+00:41:27,520 --> 00:41:32,640
+يقولنا عنه سمك و كنا بدنا نفعلهم تفاعل احتراق، مش
+
+489
+00:41:32,640 --> 00:41:35,920
+هما نفس ال molecular weight كل إشي مشترك و إجيت
+
+490
+00:41:35,920 --> 00:41:41,760
+هذا حرقته مع ال oxygen و هذا حرقته مع ال oxygenو
+
+491
+00:41:41,760 --> 00:41:44,980
+طلع عندي هنا ثانو أكسيد كربون و ميا و أشياء تانية
+
+492
+00:41:44,980 --> 00:41:47,980
+و هنا ثانو أكسيد كربون و ميا و أشياء تانية هل يا
+
+493
+00:41:47,980 --> 00:41:51,500
+تورا بيفرق أني أحرق هذا ولا أحرق هذا؟ أنا .. أنا
+
+494
+00:41:51,500 --> 00:41:54,480
+مابعملش تفاعل مع chiral molecule وين بيصير
+
+495
+00:41:54,480 --> 00:41:59,620
+الاختلاف؟ when we make a reaction with another
+
+496
+00:41:59,620 --> 00:42:06,860
+chiral molecule واضح؟زي تماما المفتاحين بيفرقوا عن
+
+497
+00:42:06,860 --> 00:42:11,280
+بعض لما نجيب لهم زرفلين، الزرفلين لهم اتجاهات
+
+498
+00:42:11,280 --> 00:42:18,500
+والمفتاحين لهم اتجاهات الان نجي ل ال diastereomars
+
+499
+00:42:18,500 --> 00:42:23,700
+ال diastereomars بنقول عنهم they have different
+
+500
+00:42:23,700 --> 00:42:29,380
+physical properties خواصم الفيزيائية مختلفةكل
+
+501
+00:42:29,380 --> 00:42:33,260
+الخواص الفيزيائية و they have similar chemical
+
+502
+00:42:33,260 --> 00:42:37,380
+properties بس لاحظوا مش identical يعني خواصهم
+
+503
+00:42:37,380 --> 00:42:40,300
+متشابه بس بيختلفوا بس بس بس بس بس بس بس بس بس بس
+
+504
+00:42:40,300 --> 00:42:41,460
+بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس
+
+505
+00:42:41,460 --> 00:42:41,640
+بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس
+
+506
+00:42:41,640 --> 00:42:43,500
+بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس
+
+507
+00:42:43,500 --> 00:42:44,440
+بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس بس
+
+508
+00:42:44,440 --> 00:42:50,300
+بس بس بس بس بس بس بس بس بس بس بس بس بس ب
+
+509
+00:42:54,030 --> 00:42:59,750
+identical يعني ماحدش بيعرف ميزهم عن بعض في فرق بين
+
+510
+00:42:59,750 --> 00:43:04,730
+identical و similar فبين ال enantiomers خواصم
+
+511
+00:43:04,730 --> 00:43:10,550
+الفيزيائية مختلفة عن بعض خواصم الكيميائية متشابهة
+
+512
+00:43:10,550 --> 00:43:17,190
+واضح؟ خواصم الكيميائية متشابهة على اي حال لابد الا
+
+513
+00:43:17,190 --> 00:43:26,390
+بيضللنا شغلة ناخد reactions ofانانشو مارز تفاعلات
+
+514
+00:43:26,390 --> 00:43:30,850
+الانانشو مارز هذي بده تاخد منه محاضرة مافيش عنده
+
+515
+00:43:30,850 --> 00:43:31,550
+أي مشكلة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/Q0NFjYnX1Cw_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/Q0NFjYnX1Cw_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..02045a99414855c714671b6aa1d2e03b92179537
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/Q0NFjYnX1Cw_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 3350, "start": 5.9, "end": 33.5, "text": "اليوم ان شاء الله بدنا نكمل في موضوع ال stereo chemistry زي ما قلتلكم يعني الموضوع بحاجة إلى تعامل هادئ بحاجة إلى نوعا ما بعض التخيلات لكن بعد ما الواحد يدرس الموضوع ويعاود ويعاود يشوف الموضوع باختصار بلاقي برضه انه مش كبير كتير بلاقي انه", "tokens": [6027, 1829, 20498, 16472, 13412, 16606, 21984, 47525, 8315, 8717, 24793, 1211, 8978, 3714, 2407, 11242, 45367, 2423, 29029, 12558, 30767, 1829, 19446, 12174, 1211, 2655, 23275, 2304, 37495, 22653, 9673, 2407, 11242, 45367, 4724, 5016, 26108, 3660, 30731, 37279, 10943, 1211, 8032, 18513, 19986, 4724, 5016, 26108, 3660, 30731, 8717, 45367, 995, 19446, 45030, 11242, 16712, 9778, 26895, 9307, 44381, 39182, 19446, 2423, 14407, 24401, 7251, 3215, 2288, 3794, 9673, 2407, 11242, 45367, 4032, 40228, 995, 23328, 4032, 40228, 995, 23328, 7251, 8592, 38688, 9673, 2407, 11242, 45367, 4724, 47283, 2655, 9381, 9640, 4724, 15040, 38436, 4724, 43042, 3224, 16472, 3224, 37893, 9122, 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"word": " chemistry", "probability": 0.6103515625}, {"start": 12.96, "end": 13.26, "word": " زي", "probability": 0.923095703125}, {"start": 13.26, "end": 13.34, "word": " ما", "probability": 0.974609375}, {"start": 13.34, "end": 14.24, "word": " قلتلكم", "probability": 0.9208984375}, {"start": 14.24, "end": 15.52, "word": " يعني", "probability": 0.859619140625}, {"start": 15.52, "end": 16.06, "word": " الموضوع", "probability": 0.9959716796875}, {"start": 16.06, "end": 16.62, "word": " بحاجة", "probability": 0.984619140625}, {"start": 16.62, "end": 16.86, "word": " إلى", "probability": 0.7646484375}, {"start": 16.86, "end": 17.72, "word": " تعامل", "probability": 0.896484375}, {"start": 17.72, "end": 18.22, "word": " هادئ", "probability": 0.9148763020833334}, {"start": 18.22, "end": 18.84, "word": " بحاجة", "probability": 0.8775634765625}, {"start": 18.84, "end": 19.22, "word": " إلى", "probability": 0.81640625}, {"start": 19.22, "end": 19.8, "word": " نوعا", "probability": 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number of stereoisomers فهذا النوع من المراكبات واحد اتنين تلاتة مش اربعة يعني ماوصلوش ال maximum احنا قولنا ال maximum لما يكون عنده two chiral centers اللي يكون عنده اربعة وشوفناهم في مثال ال two three dichlorobentane لكن بال two three dichlorobentane", "tokens": [41185, 9673, 2288, 10721, 3660, 4032, 46958, 5016, 6156, 3224, 2407, 6225, 3555, 9640, 3660, 18871, 10874, 11622, 38207, 4724, 2304, 2407, 33546, 5172, 3660, 16490, 33546, 3660, 37037, 15730, 13672, 1829, 16490, 1211, 11703, 7578, 2423, 1230, 295, 12730, 7376, 298, 433, 6156, 3224, 15730, 28239, 45367, 9154, 9673, 23557, 4117, 3555, 9307, 36764, 24401, 1975, 2655, 1863, 9957, 6055, 1211, 9307, 3660, 37893, 1975, 25513, 27884, 37495, 22653, 19446, 2407, 36520, 2407, 8592, 2423, 6674, 1975, 5016, 8315, 12174, 12610, 8315, 2423, 6674, 5296, 15042, 7251, 30544, 43242, 3224, 732, 23782, 304, 10898, 13672, 1829, 7251, 30544, 43242, 3224, 1975, 25513, 27884, 4032, 8592, 38688, 8315, 16095, 8978, 50113, 6027, 2423, 732, 1045, 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"probability": 0.696533203125}, {"start": 984.91, "end": 985.35, "word": " الشكل", "probability": 0.976806640625}, {"start": 985.35, "end": 986.15, "word": " ماطلعش", "probability": 0.65078125}, {"start": 986.15, "end": 986.33, "word": " من", "probability": 0.9423828125}, {"start": 986.33, "end": 987.23, "word": " الفتحة", "probability": 0.962890625}, {"start": 987.23, "end": 988.35, "word": " ماضواتش", "probability": 0.46220703125}, {"start": 988.35, "end": 988.97, "word": " الشاشة", "probability": 0.9837239583333334}, {"start": 988.97, "end": 989.77, "word": " الان", "probability": 0.57244873046875}, {"start": 989.77, "end": 990.07, "word": " لف", "probability": 0.70458984375}, {"start": 990.07, "end": 990.57, "word": " بزاوية", "probability": 0.90439453125}, {"start": 990.57, "end": 991.07, "word": " معينة", "probability": 0.9718424479166666}, {"start": 991.07, "end": 991.43, "word": " خليني", "probability": 0.751953125}, {"start": 991.43, "end": 992.17, "word": " افترض", 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أكون", "probability": 0.96337890625}, {"start": 1005.82, "end": 1006.54, "word": " مسبت", "probability": 0.7421875}, {"start": 1006.54, "end": 1007.1, "word": " هذه", "probability": 0.496337890625}, {"start": 1007.1, "end": 1007.44, "word": " ال", "probability": 0.87841796875}, {"start": 1007.44, "end": 1007.92, "word": " slit", "probability": 0.61376953125}, {"start": 1007.92, "end": 1008.26, "word": " أو", "probability": 0.95654296875}, {"start": 1008.26, "end": 1009.12, "word": " الفتحة", "probability": 0.94970703125}, {"start": 1009.12, "end": 1009.62, "word": " على", "probability": 0.86865234375}, {"start": 1009.62, "end": 1010.32, "word": " منجلة", "probability": 0.8982747395833334}, {"start": 1010.32, "end": 1010.52, "word": " و", "probability": 0.63818359375}, {"start": 1010.52, "end": 1010.84, "word": " تكون", "probability": 0.935791015625}, {"start": 1010.84, "end": 1011.02, "word": " إلي", "probability": 0.6287841796875}, {"start": 1011.02, "end": 1011.44, "word": " محور", 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تلاتين درجة إذا بإمكان أجيس الزاوية واضح؟ ببساطة الآن لو جبنا محلول من الانانشو مرة تانية بنفس التركيز", "tokens": [3555, 11242, 1211, 22653, 5551, 46538, 5551, 46538, 5551, 46538, 5551, 46538, 5296, 5016, 19913, 3660, 19446, 7251, 9381, 13546, 8032, 18513, 5172, 5551, 2655, 5016, 9566, 11296, 20449, 1975, 2655, 7435, 40294, 6024, 114, 2407, 38207, 4724, 1829, 46456, 2288, 4587, 11296, 6024, 114, 2407, 38207, 39894, 11242, 2407, 25124, 33599, 3660, 25961, 2655, 39896, 4117, 6024, 110, 995, 2407, 10632, 5296, 5172, 2655, 6225, 46309, 9957, 11778, 47341, 3660, 6055, 1211, 9307, 9957, 11778, 47341, 3660, 11933, 15730, 4724, 28814, 2304, 41361, 5551, 7435, 1829, 3794, 6024, 110, 995, 2407, 10632, 4032, 46958, 5016, 22807, 4724, 3555, 3794, 41193, 3660, 6024, 48506, 45164, 10874, 3555, 8315, 3714, 5016, 1211, 12610, 9154, 2423, 7649, 7649, 8592, 2407, 3714, 25720, 6055, 7649, 10632, 44945, 36178, 16712, 31747, 1829, 11622], "avg_logprob": -0.16165864960505413, "compression_ratio": 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{"start": 1034.46, "end": 1034.68, "word": " من", "probability": 0.9912109375}, {"start": 1034.68, "end": 1035.42, "word": " الانانشو", "probability": 0.63114013671875}, {"start": 1035.42, "end": 1035.62, "word": " مرة", "probability": 0.930908203125}, {"start": 1035.62, "end": 1036.16, "word": " تانية", "probability": 0.9181315104166666}, {"start": 1036.16, "end": 1036.96, "word": " بنفس", "probability": 0.896728515625}, {"start": 1036.96, "end": 1037.9, "word": " التركيز", "probability": 0.9459228515625}], "temperature": 1.0}, {"id": 44, "seek": 106011, "start": 1039.28, "end": 1060.12, "text": "و جينا عدنا التجربة هلاحظ إذا المحلول الأول لف زي هيك التاني بيلف بالاتجاه المعاكس و أجتا بيدلف هذه بالعكس كأنه لو هذا لف زائد عشرين هذا بيكون لف إيش ناقص عشرين إذا هم بس بيختلفوا ال enantiomers كيف بيلفوا", "tokens": [2407, 10874, 1829, 8315, 6225, 3215, 8315, 16712, 7435, 25513, 3660, 8032, 15040, 5016, 19913, 11933, 15730, 9673, 5016, 1211, 12610, 16247, 12610, 5296, 5172, 30767, 1829, 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0.9853515625}], "temperature": 1.0}, {"id": 108, "seek": 261155, "start": 2603.49, "end": 2611.55, "text": "انانشو مارز تفاعلات الانانشو مارز هذي بده تاخد منه محاضرة مافيش عنده أي مشكلة", "tokens": [7649, 7649, 8592, 2407, 3714, 9640, 11622, 6055, 5172, 995, 30241, 9307, 2423, 7649, 7649, 8592, 2407, 3714, 9640, 11622, 8032, 8848, 1829, 47525, 3224, 6055, 47283, 3215, 9154, 3224, 3714, 5016, 46958, 25720, 19446, 41185, 8592, 43242, 3224, 36632, 37893, 28820, 3660], "avg_logprob": -0.3277698897502639, "compression_ratio": 1.4387755102040816, "no_speech_prob": 6.556510925292969e-07, "words": [{"start": 2603.49, "end": 2604.21, "word": "انانشو", "probability": 0.586944580078125}, {"start": 2604.21, "end": 2604.53, "word": " مارز", "probability": 0.8819986979166666}, {"start": 2604.53, "end": 2606.39, "word": " تفاعلات", "probability": 0.8037109375}, {"start": 2606.39, "end": 2606.93, "word": " الانانشو", "probability": 0.919921875}, {"start": 2606.93, "end": 2607.23, "word": " مارز", "probability": 0.9700520833333334}, {"start": 2607.23, "end": 2607.79, "word": " هذي", "probability": 0.5741780598958334}, {"start": 2607.79, "end": 2608.03, "word": " بده", "probability": 0.442626953125}, {"start": 2608.03, "end": 2608.43, "word": " تاخد", "probability": 0.9871419270833334}, {"start": 2608.43, "end": 2608.87, "word": " منه", "probability": 0.538818359375}, {"start": 2608.87, "end": 2610.27, "word": " محاضرة", "probability": 0.90576171875}, {"start": 2610.27, "end": 2610.61, "word": " مافيش", "probability": 0.6515299479166666}, {"start": 2610.61, "end": 2610.85, "word": " عنده", "probability": 0.844482421875}, {"start": 2610.85, "end": 2610.99, "word": " أي", "probability": 0.43212890625}, {"start": 2610.99, "end": 2611.55, "word": " مشكلة", "probability": 0.9874674479166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2614.98475, "duration_after_vad": 2547.3162499999908}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b429f0872ecc44fa59b1ebcd267721cfeb0d5db7
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/QaZQ1Ndvo1g.srt
@@ -0,0 +1,1766 @@
+1
+00:00:07,360 --> 00:00:13,000
+بسم الله الرحمن الرحيم  تكلّمنا المرة الماضية في
+
+2
+00:00:13,000 --> 00:00:18,800
+موضوع الإيثرات بشكل أساسي تسمية الإيثرات وخواصها
+
+3
+00:00:18,800 --> 00:00:27,600
+اليوم بنستمر في تناول هذا الموضوع، هنتكلم على تحضير
+
+4
+00:00:27,600 --> 00:00:33,340
+الإيثرات وبعض تفاعلاتها، زي التوسع في هذا المجال
+
+5
+00:00:33,950 --> 00:00:40,830
+الآن يوم ما بيجيكم أي إيثر بتكونوا عارفين أن ال
+
+6
+00:00:40,830 --> 00:00:47,070
+إيثر تُقسم إلى نوعين، ممكن الإيثر تكون Symmetric
+
+7
+00:00:47,070 --> 00:00:52,730
+بمعنى مجموعتين الـ R اللي موجودات زي بعض، يعني لما
+
+8
+00:00:52,730 --> 00:00:58,890
+نقول إيثيل إيثيل هذا Symmetric ether مثل مثل فينيل فينيل كل 
+
+9
+00:00:58,890 --> 00:01:03,890
+هذه عبارة عن Symmetrical ethers وممكن الإيثرات
+
+10
+00:01:03,890 --> 00:01:10,770
+تكون Unsymmetrical بمعنى يكون في عندنا مثلا إيثيل مع
+
+11
+00:01:10,770 --> 00:01:17,700
+ميثيل أو إيثيل مع فينيل أو آيزو بروبيل مع إيثيل احتمالات
+
+12
+00:01:17,700 --> 00:01:21,620
+كتير، الآن هنا بيصير عندنا طريقتين للتحضير، يعني لما
+
+13
+00:01:21,620 --> 00:01:26,860
+بيحضر Symmetrical ethers في عنده طريقة، ولما بيحضر
+
+14
+00:01:26,860 --> 00:01:31,950
+Unsymmetrical ethers في عنده طريقة ثانية، الـ
+
+15
+00:01:31,950 --> 00:01:35,270
+Symmetrical ethers طريقة تحضيرهم سهلة وممكن مرت
+
+16
+00:01:35,270 --> 00:01:41,310
+علينا عرضًا أثناء تكلمنا عن الألكينات، إذا أخدنا
+
+17
+00:01:41,310 --> 00:01:46,530
+الكحول وسخناه لحرارة محددة في وجود حامض بيعطينا ال
+
+18
+00:01:46,530 --> 00:01:51,950
+إيثر، يعني مثلًا الـ Diethyl ether إذا احنا أخدنا ال
+
+19
+00:01:51,950 --> 00:01:56,830
+Ethanol مع Sulfuric acid على 140 درجة مئوية
+
+20
+00:01:56,830 --> 00:02:02,470
+بيعطينا الـ Diethyl ether، واضح؟ كذلك الحالة لو بدنا
+
+21
+00:02:02,470 --> 00:02:08,530
+Dipropyl ether مثلًا أو ما إلى ذلك، طريقة سهلة كثير 
+
+22
+00:02:08,530 --> 00:02:15,050
+الآن بتصير عندنا.. بتصير عندنا مشكلة لما بنحضر ال
+
+23
+00:02:15,050 --> 00:02:20,770
+Unsymmetrical ethers، اتخيلوا أنتو لو اجينا بنحضر
+
+24
+00:02:20,770 --> 00:02:25,170
+الـ Unsymmetrical ethers بنفس الطريقة، في هذه الحالة 
+
+25
+00:02:25,170 --> 00:02:30,610
+بدنا نكون مضطرين ناخد كم كحول؟ اثنين، واضح؟ يعني لو 
+
+26
+00:02:30,610 --> 00:02:35,310
+مثلًا بدي إيثر جاي من الـ.. من الـ Methanol و الـ
+
+27
+00:02:35,310 --> 00:02:40,230
+Ethanol بكون بدي Two alcohols يعني بدي الـ Methyl 
+
+28
+00:02:40,230 --> 00:02:48,390
+OH و الـ Ethyl OH، الآن لو هدول الاثنين خلطتهم أنا 
+
+29
+00:02:48,390 --> 00:02:53,790
+مع Sulfuric acid وسخنت، ايش اللي بدي احصل عليه؟ 
+
+30
+00:02:53,790 --> 00:02:58,290
+تخيلوا أن أنا خلطت H plus مع Sulfuric acid وتسخين
+
+31
+00:02:58,600 --> 00:03:03,760
+ماذا تتوقع أن يحدث في هذه الحالة؟
+
+32
+00:03:03,760 --> 00:03:10,660
+طبعًا ضعوا في اعتباركم أن أنا لما أعمل التفاعل لم 
+
+33
+00:03:10,660 --> 00:03:15,640
+أضع جزء واحد من الميثانول وجزء واحد من الإيثانول 
+
+34
+00:03:15,640 --> 00:03:19,520
+أنا وضعت مثلًا One mole of methanol و One mole of
+
+35
+00:03:19,520 --> 00:03:23,900
+ethanol، لحظة ما أبدأ أقول One mole يعني بحكي عن 6 في
+
+36
+00:03:23,900 --> 00:03:24,680
+10 أو 23
+
+37
+00:03:36,250 --> 00:03:42,450
+ممكن يلتقي الميثانول مع جزء ميثانول ثاني وبالتالي
+
+38
+00:03:42,450 --> 00:03:49,450
+يعمل Dimethyl ether يعني يعطي ميثيل وميثيل، وممكن
+
+39
+00:03:49,450 --> 00:03:57,340
+الإيثانول يلتقي مع جزء إيثانول ثاني ويعطي إيثيل أو إيثيل
+
+40
+00:03:57,340 --> 00:04:02,640
+أو إيثيل
+
+41
+00:04:02,640 --> 00:04:05,000
+أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل
+
+42
+00:04:05,000 --> 00:04:05,700
+أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل
+
+43
+00:04:05,700 --> 00:04:07,220
+أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل
+
+44
+00:04:07,220 --> 00:04:07,500
+أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل
+
+45
+00:04:07,500 --> 00:04:13,580
+أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل أو إيثيل، 
+
+46
+00:04:13,880 --> 00:04:17,980
+خليط من ثلاثة نواتج، وهذا دائمًا الكلام الكيميائييين
+
+47
+00:04:17,980 --> 00:04:22,520
+بيجنبوه لأن عملية فصل المركبات عن بعض بالتقطير وغيرها 
+
+48
+00:04:22,520 --> 00:04:28,640
+عملية متعبة ومكلفة وما إلى ذلك، فعملية أن
+
+49
+00:04:28,640 --> 00:04:33,180
+أنا بضحي أحضر Unsymmetrical ether من خلط Two
+
+50
+00:04:33,180 --> 00:04:36,820
+different alcohols ليست طريقة عملية، Is not a
+
+51
+00:04:36,820 --> 00:04:41,440
+practical method، مش مقبولة، يعني لو بدي أقولكوا
+
+52
+00:04:41,440 --> 00:04:44,940
+حضّرولي الـ ميثيل وإيثيل، وطالب بدي أجابني إنه بيخلّط
+
+53
+00:04:44,940 --> 00:04:49,400
+ميثانول وإيثانول وحامض وحرارة، الجواب غلط، هذا
+
+54
+00:04:49,400 --> 00:04:52,700
+الكلام مش مقبول لأن هذا الكلام بيُطلق ثلاثة نواتج
+
+55
+00:04:52,700 --> 00:04:58,260
+عملية فصل الثلاثة نواتج هدول عن بعضهم عملية صعبة و
+
+56
+00:04:58,260 --> 00:05:04,430
+مزعجة، إذن كان لابد من طريقة ثانية لتحضير الـ
+
+57
+00:05:04,430 --> 00:05:08,430
+Unsymmetrical ethers يطلع فيها المركب لوحده، ليس
+
+58
+00:05:08,430 --> 00:05:13,990
+لدي خليط من ثلاثة نواتج، واضحة الفكرة؟ اه.. الآن هذه
+
+59
+00:05:13,990 --> 00:05:18,910
+كيف بيعملوها؟ بيجيبوا Alcohol، واحد من ال Alcohol 
+
+60
+00:05:18,910 --> 00:05:24,250
+بيخلوه ROH، الـ Alcohol نفسه ROH، لو فعلنا مع ال
+
+61
+00:05:24,250 --> 00:05:28,350
+Sodium، كلكوا عارفين أن الـ Sodium بياخد الـ H و
+
+62
+00:05:28,350 --> 00:05:34,590
+بيعملنا RO- minus، فصار عندي RO-NA+، يعني لو كان عندي 
+
+63
+00:05:34,590 --> 00:05:41,030
+مثلًا إيثانول بيصير عندي Sodium Ethoxide، لو كان 
+
+64
+00:05:41,030 --> 00:05:45,470
+عندي هنا إيثانول مع الـ Sodium بيعطينا Sodium
+
+65
+00:05:45,470 --> 00:05:49,770
+Ethoxide، هذا المركب بتطلع هذه معادلة هيك لوحدها
+
+66
+00:05:49,770 --> 00:05:56,130
+الناتج اللي صار عندي هنا باجي بفعله مع RX ثانية
+
+67
+00:05:56,920 --> 00:06:00,300
+واضح؟ يعني أرجو أنه ما تفهموش هذه المعادلة لأن هذا
+
+68
+00:06:00,300 --> 00:06:04,960
+بيطلع الناتجين، لا هذه معادلة لوحدها أنه أنا لو
+
+69
+00:06:04,960 --> 00:06:09,040
+أخدت الـ Ethanol مع الـ Sodium بيطلع له Sodium
+
+70
+00:06:09,040 --> 00:06:13,080
+Ethoxide، صار كل المحلول عبارة عن Sodium Ethoxide 
+
+71
+00:06:13,080 --> 00:06:18,230
+الآن هذا الـ Sodium Ethoxide بنيجي بنضيفه أو بنفعله 
+
+72
+00:06:18,230 --> 00:06:28,170
+مرة ثانية مع R' X، أي R ثانية نفترض مثلًا CH3CL، الـ
+
+73
+00:06:28,170 --> 00:06:32,990
+RO- هذه بتيجي بتعمل عملية إبدال على الـ RX بتهاجم
+
+74
+00:06:32,990 --> 00:06:37,210
+هيك وبتطرد الـ X، وأخدنا أن التفاعل الأساسي
+
+75
+00:06:37,210 --> 00:06:42,090
+للمركبات الـ RX هو الـ Substitution، وأخدنا أنها 
+
+76
+00:06:42,090 --> 00:06:48,750
+ممكن تتم بـ SN1 وممكن تتم بـ SN2 ميكانيزم، واضحة؟
+
+77
+00:06:48,750 --> 00:06:54,030
+فكأنه أنا صار عندي هلأ بالتأكيد R أو ماينوس هاجمت
+
+78
+00:06:54,030 --> 00:06:59,350
+على R' X طلعت الـ X، فبيصير عندي R أو R ناتج واحد
+
+79
+00:06:59,350 --> 00:07:07,470
+فقط، ناتج واحد فقط، هنا يُفضل حتى يكون التفاعل أفضل ما
+
+80
+00:07:07,470 --> 00:07:13,070
+يمكن أنه لما بعمل عملية اختيار أن الـ R' X هذه تكون
+
+81
+00:07:13,070 --> 00:07:19,450
+الـ Primary، يُفضل أن الـ R' X تكون الـ Primary، خلينا
+
+82
+00:07:19,450 --> 00:07:26,930
+ناخد مثال حقيقي بدون R و A، مثلًا لو أخدنا الفينول
+
+83
+00:07:26,930 --> 00:07:32,530
+مع الصوديوم بدي يعطينا Sodium Phenoxide، ممتازة، كل
+
+84
+00:07:32,530 --> 00:07:36,810
+المحلول اللي عندي صار Sodium Phenoxide، الآن هذا
+
+85
+00:07:36,810 --> 00:07:43,970
+المحلول باجي بضيفه على مثلًا Ethyl Chloride أو
+
+86
+00:07:43,970 --> 00:07:48,090
+Ethyl Bromide، لاحظوا إذا أنا هنا بتعامل مع Two
+
+87
+00:07:48,090 --> 00:07:52,910
+flasks، هاي حضرت هنا الـ Ethoxide بعد ما أتحضر 
+
+88
+00:07:52,910 --> 00:07:59,750
+بنضيفه هنا، ايش بتعمل الـ Phenyl O minus بتهاجم هنا
+
+89
+00:07:59,750 --> 00:08:08,110
+وبتطرد الـ X، بيصير عندي Phenyl O CH2 CH3، واضحة
+
+90
+00:08:08,110 --> 00:08:16,890
+الفكرة، لاحظوا هنا لحظة ما أنا بأعمل الاختيار بفضّل 
+
+91
+00:08:16,890 --> 00:08:24,450
+ولا أزم أن يكون الـ RX Primary، يعني مثلًا لو إجينا 
+
+92
+00:08:24,450 --> 00:08:29,750
+بنسألكوا السؤال الآن، كيف ممكن تحضّرو لنا هذا الـ
+
+93
+00:08:29,750 --> 00:08:34,610
+Ether؟ كيف ممكن تحضّروا هذا الـ Ether؟ أنتو لما
+
+94
+00:08:34,610 --> 00:08:39,170
+بتكونوا بتجيبوا على السؤال هذا الـ Ether هذا عبارة
+
+95
+00:08:39,170 --> 00:08:42,350
+عن Symmetrical ولا Unsymmetrical؟ Unsymmetrical..
+
+96
+00:08:42,350 --> 00:08:44,070
+Unsymmetrical.. Unsymmetrical.. Unsymmetrical..
+
+97
+00:08:44,070 --> 00:08:45,530
+Unsymmetrical.. Unsymmetrical.. Unsymmetrical..
+
+98
+00:08:45,530 --> 00:08:47,870
+Unsymmetrical.. Unsymmetrical.. Unsymmetrical..
+
+99
+00:08:47,870 --> 00:08:49,790
+Unsymmetrical.. Unsymmetrical.. Unsymmetrical..
+
+100
+00:08:49,790 --> 00:08:50,590
+Unsymmetrical.. Unsymmetrical.. Unsymmetrical..
+
+101
+00:08:50,590 --> 00:08:51,990
+Unsymmetrical.. Unsymmetrical.. Unsymmetrical..
+
+102
+00:08:51,990 --> 00:08:54,910
+Unsymmetrical.. Unsymmetrical.. Unsymmetrical..
+
+103
+00:08:54,910 --> 00:08:57,670
+Unsymmetrical.. Unsymmetrical.. Unsymmetrical..
+
+104
+00:08:57,670 --> 00:09:01,500
+Unsymmetrical.. Unsـ  Probability Group واحدة
+
+105
+00:09:01,500 --> 00:09:11,800
+منهم بيكون O- والثانية RX، الصعوبة هنا أن أعرف أيّة 
+
+106
+00:09:11,800 --> 00:09:17,140
+اللي بيبقى معها الـ O- وأيّة اللي بيكون الـ RX
+
+107
+00:09:17,140 --> 00:09:22,340
+احنا أخذنا شرط الـ RX لازم تكون الـ Primary، إذا 
+
+108
+00:09:22,340 --> 00:09:26,620
+هذا لما بدي أحلّله لمكوناته، ايش بيكون؟
+
+109
+00:09:31,030 --> 00:09:38,210
+بدي أخد هذا الكحول اللي هو الـ Tertiary-Butanol و
+
+110
+00:09:38,210 --> 00:09:42,930
+التيرشاري بيوتانول هذا لما نفعله مع الصوديوم بدي
+
+111
+00:09:42,930 --> 00:09:46,850
+يعطينا Tertiary But Oxide، هذه المعادلة الأولى
+
+112
+00:09:46,850 --> 00:09:51,030
+اللي عندنا، واضح؟ إذا احنا حضّرنا الـ Tertiary But 
+
+113
+00:09:51,030 --> 00:09:56,190
+Oxide أيون، الأيون السابق، بعد هيك بدنا نفعله مع 
+
+114
+00:09:56,190 --> 00:10:06,380
+ايش؟ مع الـ R هذه اللي هي CH3 CH2 CH2، وهنا بيكون
+
+115
+00:10:06,380 --> 00:10:13,360
+انتهت CL أو BR، واضح؟ في هذه الحالة بيتمّ عملية هجوم
+
+116
+00:10:13,360 --> 00:10:19,880
+من الـ O minus هنا وعملية طرد للـ BR، بنحصل على
+
+117
+00:10:19,880 --> 00:10:20,680
+الناتج المطلوب
+
+118
+00:10:23,830 --> 00:10:28,570
+الآن لو واحدة عملت الجواب هنا بالعكس خلت هذا تصير
+
+119
+00:10:28,570 --> 00:10:34,070
+O minus والـ X تكون هنا Tertiary مش هيصير التفاعل
+
+120
+00:10:34,070 --> 00:10:41,430
+واضح؟ إذا شرط هذا التفاعل أن الـ R X نخليها Primary
+
+121
+00:10:41,430 --> 00:10:45,190
+بصعوبة لو كان Secondary ممكن يمشي بصعوبة كثير، يعني
+
+122
+00:10:45,190 --> 00:10:51,030
+بيكون بطيء، Tertiary مستحيل، فطالما أن أحد مكونات الـ
+
+123
+00:10:51,030 --> 00:10:55,590
+Ether الـ Primary والثاني Secondary أو Tertiary إذا
+
+124
+00:10:55,590 --> 00:10:59,710
+أنا أيّة اللي بدي أخليها RX لبرايماري، لو كان مثلًا
+
+125
+00:10:59,710 --> 00:11:06,530
+Primary مع فينيل لأن
+
+126
+00:11:06,530 --> 00:11:11,570
+الـ Phenol لو أحد عمل عليها X مش لأنها Tertiary لأ أنتو
+
+127
+00:11:11,570 --> 00:11:16,370
+أخدتوا كمان قبل هيك شغلة أنه لا يمكن إبدال X على 
+
+128
+00:11:16,370 --> 00:11:23,180
+حلقة بنزين، متذكرين لما قلنا لكم ARX لا يحدث إبدال
+
+129
+00:11:23,180 --> 00:11:28,440
+بناءً على ذلك لو برضه بدي يجيكم سؤال في الامتحانات
+
+130
+00:11:28,440 --> 00:11:33,760
+واضح، نخلصناه زي
+
+131
+00:11:33,760 --> 00:11:42,270
+هذا المثال تطلعوا عليه من الآخر، حضّرو لنا فينيل O إيثيل 
+
+132
+00:11:42,270 --> 00:11:46,490
+ولا ميثيل ولا Global، واحدة تيجي تقسم هذا تقسيم 
+
+133
+00:11:46,490 --> 00:11:54,890
+خاطئ، يعني تخلي لي هذه فينيل X زائد مثلًا إيثيل O
+
+134
+00:11:54,890 --> 00:11:58,290
+minus وتقول والله هذه إيثيل O minus بتهاجم على فينيل 
+
+135
+00:11:58,290 --> 00:12:04,050
+الـ X بتطردها، إذا السؤال عليه خمس درجات كده بتاخد صفر؟ 
+
+136
+00:12:04,050 --> 00:12:07,490
+ليش؟
+
+137
+00:12:07,490 --> 00:12:12,750
+لأنه لا يتم الإبدال على ال Aromatic compounds السابق
+
+138
+00:12:12,750 --> 00:12:16,670
+أخذناها، واضح؟ لا يتم الإبدال في هذه الحالة، جواب
+
+139
+00:12:16,670 --> 00:12:21,290
+الصح أن تكون هذه فينيل الـ O-؟ وهذه تكون FX
+
+140
+00:12:23,140 --> 00:12:27,240
+هذا اللي هو William Son Synthesis وبالمناسبة
+
+141
+00:12:27,240 --> 00:12:30,420
+طبيعة.. هيك يا ربنا خلق الدنيا سبحانه وتعالى
+
+142
+00:12:30,420 --> 00:12:35,140
+طبيعة الامتحانات لا يمكن أصحّكوا تفكّروا ييجي امتحان
+
+143
+00:12:35,140 --> 00:12:39,660
+وما نجيبش عليه سؤال نختبركوا بهذه المنطقة بتاعة
+
+144
+00:12:39,660 --> 00:12:43,640
+تحضير Unsymmetrical Ether وتعرفولي بالظبط ايش 
+
+145
+00:12:43,640 --> 00:12:47,860
+معنى الـ Primary و Secondary و Tertiary وكيف 
+
+146
+00:12:47,860 --> 00:12:54,540
+تعملوا مكونات هذا الـ Ether ماشي؟ هنا قدام الكاميرا 
+
+147
+00:12:54,540 --> 00:13:00,880
+كشفنا سؤال من الامتحان الآن
+
+148
+00:13:00,880 --> 00:13:07,910
+الـ Cleavage of Ethers، لاحظوا معنى لما بنحكي احنا
+
+149
+00:13:07,910 --> 00:13:13,070
+عن بعض المركبات أو العائلات بنقول Reactions of 
+
+150
+00:13:13,070 --> 00:13:16,570
+مثلًا Alcohols بناخد أربع خمس ست أنواع من ال
+
+151
+00:13:16,570 --> 00:13:20,350
+Reactions، بعد شوية لما نحكي مثلًا عن الـ Aldehydes و
+
+152
+00:13:20,350 --> 00:13:24,090
+الـ Ketones بناخد Reactions of Aldehydes و Ketones
+
+153
+00:13:24,090 --> 00:13:27,910
+ممكن ناخد محاضرتين أو تلاتة، لما حكينا على الـ
+
+154
+00:13:27,910 --> 00:13:32,930
+Alkenes تفاعلات الإضافة والـ Palmer وما إلى ذلك
+
+155
+00:13:32,930 --> 00:13:37,210
+كانت قصة، بظبط ولا لا؟ لكن لما بنحكي على
+
+156
+00:13:37,210 --> 00:13:41,730
+الإيثرات احنا في الأساس قلنا الـ Ethers they are 
+
+157
+00:13:41,730 --> 00:13:46,770
+considered to be inert، يعني تقريبًا ما بتفعلوش، هم 
+
+158
+00:13:46,770 --> 00:13:51,530
+تقريبًا، الملومش غيرها التفاعل اليتيم مع حامض قوي
+
+159
+00:13:51,530 --> 00:13:57,210
+مثل الـ HI، بس حامض قوي مثل الـ HI بكسرهم، إذا 
+
+160
+00:13:57,210 --> 00:14:03,150
+تفاعلهم تفاعل Cleavage ايش يعني Cleavage؟ تكسير، Cleavage
+
+161
+00:14:03,150 --> 00:14:10,190
+Reaction يعني أن أكسر المركب إلى نصفين، طيب كيف مثلًا
+
+162
+00:14:10,190 --> 00:14:15,210
+لو أخدنا هذا الإيثر الفينيل O CH2 CH3 نرجع لنفس
+
+163
+00:14:15,210 --> 00:14:19,450
+الإيثر الآن هذا لما نيجي نفعله مع HI الـ I تعتبر 
+
+164
+00:14:21,030 --> 00:14:25,650
+أو الـ Strong nucleophile نتيجة التهاجم هل يترى 
+
+165
+00:14:25,650 --> 00:14:28,690
+هذا الـ I لما بيتهاجم تهاجم على الـ Primary carbon
+
+166
+00:14:28,690 --> 00:14:32,850
+ولا على الفينيل؟ بتهاجم على الـ Primary carbon أسهل
+
+167
+00:14:32,850 --> 00:14:36,110
+ايش أن تتصل إلى الـ Primary carbon؟ فبتتم هجوم بهذا
+
+168
+00:14:36,110 --> 00:14:43,020
+الشكل؟ وبتكسر هذه، كأنه عملت عكس التفاعل السابق، كأنه
+
+169
+00:14:43,020 --> 00:14:46,280
+عملت عكس التفاعل السابق بتصير أدفين الـ O minus
+
+170
+00:14:46,280 --> 00:
+
+201
+00:17:49,330 --> 00:17:53,050
+كتير حلم حلو أشتري Cherry لأ لكن لو كانت ال
+
+202
+00:17:53,050 --> 00:17:57,030
+primary ممكن كمية إضافية تكون موجودة من اليود 
+
+203
+00:17:57,030 --> 00:18:00,730
+excess اتحال وبالتالي يطلع عندى بس ال iodide بمعنى
+
+204
+00:18:00,730 --> 00:18:04,310
+انه صح اتكون ال alcohol في البداية لكن ال alcohol
+
+205
+00:18:05,890 --> 00:18:10,990
+بخطوة إضافية اتحول ل iodide فكأنه يعني ال two
+
+206
+00:18:10,990 --> 00:18:14,670
+parts of the ether are converted to alkyl halides
+
+207
+00:18:14,670 --> 00:18:20,950
+الجزئين من ال ether اتحولوا ل alkyl halide
+
+208
+00:18:44,950 --> 00:18:51,910
+في عندنا موضوع تاني ال ethers مرات بتكون cyclic
+
+209
+00:18:51,910 --> 00:18:56,850
+ethers واضح يعني بشكل عام ال ethers العادية
+
+210
+00:18:56,850 --> 00:19:03,370
+الفتاحة ROR الآن لو ال O صارت موجودة جوا حلقة
+
+211
+00:19:03,370 --> 00:19:09,690
+بنصير نحكي عن cyclic ether ممكن تكون ال O بحلقة
+
+212
+00:19:09,690 --> 00:19:14,130
+ثلاثية ممكن تكون بحلقة رباعية ممكن تكون بحلقة
+
+213
+00:19:14,130 --> 00:19:18,350
+خماسية سداسية خلينا بس نعود للتذكير بالحلقة
+
+214
+00:19:18,350 --> 00:19:22,650
+الثلاثية وأنا بتهيأ لي مرت علينا الحلقة الثلاثية
+
+215
+00:19:22,650 --> 00:19:28,410
+بتفاعل ال alkyls واضح؟ هذه وين مرت علينا ال
+
+216
+00:19:28,410 --> 00:19:35,270
+ethylene oxide لما كان يكون عندي ethylene CH2 CH2
+
+217
+00:19:35,270 --> 00:19:43,230
+مع الـ peroxyacid كان يعطينا الـ epoxide لاحظوا مع
+
+218
+00:19:43,230 --> 00:19:50,130
+الـ epoxide هو اسم عائلة لكن المركب نفسه بنسميه إما
+
+219
+00:19:50,130 --> 00:19:55,230
+إيثيلين أكسيد أو أوكسيران في الكيمياء الحلقية غير
+
+220
+00:19:55,230 --> 00:20:01,030
+المتجانسة هذا المركب شو بيسموه؟ أوكسيران بنسميه
+
+221
+00:20:01,030 --> 00:20:07,130
+أوكسيران أو لأنه إشتق من الإيثيلين بنقول عنه إيثيلين
+
+222
+00:20:07,130 --> 00:20:13,190
+أكسيد الآن لو حطيت هنا مثيل معنى ذلك الألكين الأصل
+
+223
+00:20:13,190 --> 00:20:18,830
+اللي كان عندي CH3 CH double bond CH2 بروبيلين أو
+
+224
+00:20:18,830 --> 00:20:23,590
+بروبين بناء على ذلك المركب شو حيصير؟ بروبيلين
+
+225
+00:20:23,590 --> 00:20:31,780
+أكسيد طيب، لو كان عنده واحد، اثنين، ثلاثة، أربعة
+
+226
+00:20:31,780 --> 00:20:37,200
+وكانت الـ double bond هنا الـ butane هيكون 1
+
+227
+00:20:37,200 --> 00:20:40,160
+butane oxide، تنسوش الـ butane كان فيه منه 1
+
+228
+00:20:40,160 --> 00:20:44,540
+butane وكان فيه منه 2 butane، الآن هذا على أي
+
+229
+00:20:44,540 --> 00:20:48,180
+double bond إجا؟ على الـ 1، إذا هذا 1 butane
+
+230
+00:20:48,180 --> 00:20:52,780
+oxide طبعًا، ممكن نفس المركبات ينسميها نسبة إلى
+
+231
+00:20:52,780 --> 00:20:57,000
+الـ oxirane هذه الحلقة بدون أي substituent إيش
+
+232
+00:20:57,000 --> 00:21:01,740
+اسمها؟ Oxirane وترقيمها دائمًا يبدأ من ال Oxygen
+
+233
+00:21:01,740 --> 00:21:07,020
+1 2 هنا على موقع 2 شو بتحمل مثيل إذا هذا
+
+234
+00:21:07,020 --> 00:21:16,600
+مثيل أو 2 مثيل Oxirane لو طلعنا على المركب اللي
+
+235
+00:21:16,600 --> 00:21:23,870
+بعده هاي 1,2 مثيل أوكسيران لاحظوا معنا يمكن
+
+236
+00:21:23,870 --> 00:21:29,530
+هنا في الكتابة مش كاتبين احنا الـ 2 ليش مش
+
+237
+00:21:29,530 --> 00:21:34,870
+كاتبينها؟ لأنه ما فيش احتمال ثاني يعني لو اجت المثيل
+
+238
+00:21:34,870 --> 00:21:39,370
+هنا بدها تكون 2 مثيل طب لو حطيناها هنا بنعد هنا
+
+239
+00:21:39,370 --> 00:21:43,070
+2 مثيل يعني لـ 1 مثيل لا يمكن إلا تكون على موقع
+
+240
+00:21:43,070 --> 00:21:46,130
+2 فيه ولـ 1 مثيل لا يمكن إلا تكون على موقع
+
+241
+00:21:46,130 --> 00:21:54,010
+2 لكن لو صار عندي مثلًا زي هذا المركب هاي Carbon
+
+242
+00:21:54,010 --> 00:21:58,430
+1 2 3 4 كان هنا double bond وكان المركب
+
+243
+00:21:58,430 --> 00:22:03,390
+cis-2-butyl فعلنا مع الـ peroxyacid بيعطينا cis-2
+
+244
+00:22:03,390 --> 00:22:07,230
+-butyl oxide في الـ common name لو أجينا بنسميه على
+
+245
+00:22:07,230 --> 00:22:09,730
+تسمية الكيمياء الحلقية
+
+246
+00:22:15,980 --> 00:22:21,160
+على موقع 2 و 3 منها، شوفي عندي، Dimethyl،
+
+247
+00:22:21,160 --> 00:22:26,140
+في هذه الحالة أنا صرت مضطر أن أحط الأرقام، ليش؟
+
+248
+00:22:26,140 --> 00:22:30,400
+لأنه لو عندي مجموعتين مثيل اللي هم أكتر من احتمال،
+
+249
+00:22:30,400 --> 00:22:34,400
+أنا كان .. لأ، 1 مستحيل، لأن ال Oxygen ما
+
+250
+00:22:34,400 --> 00:22:37,460
+بيحملش شيء ثاني، ال Oxygen بس رابطتين، إيش
+
+251
+00:22:37,460 --> 00:22:43,040
+الاحتمال الثاني؟ إيش الاحتمال الثاني لما يكون عندي
+
+252
+00:22:43,040 --> 00:22:45,120
+مجموعتين مثيل على ال Oxygen؟
+
+253
+00:22:50,280 --> 00:22:53,800
+بعيدًا .. هذا عشانه معاها واحدة بنقول cis مش
+
+254
+00:22:53,800 --> 00:23:02,120
+مختلفين أنا بدي على المواقع أيوة من 2 ممكن
+
+255
+00:23:02,120 --> 00:23:08,840
+مجموعتين المثيل يكونوا هنا لو أتيكم هذا المركب سموه
+
+256
+00:23:08,840 --> 00:23:13,640
+في الامتحان شو هتصموه في هذه الحلقة؟ 1 2 3
+
+257
+00:23:13,640 --> 00:23:18,580
+2,2 ثنائي مثيل اوكسيران طب لو سألناك هو هذا
+
+258
+00:23:18,580 --> 00:23:23,740
+cis ولا trans؟ ما فيش دائرة الـ cis والـ trans هنا
+
+259
+00:23:23,740 --> 00:23:27,540
+لأنه احنا سبق قلنا دائرة الـ cis والـ trans سواء
+
+260
+00:23:27,540 --> 00:23:31,560
+حول الـ double bond أو حول الحلقة بتطلب أنه
+
+261
+00:23:31,560 --> 00:23:36,200
+كل كربونة يكون عليها مجموعتين مختلفتين مجموعتين
+
+262
+00:23:36,200 --> 00:23:39,920
+مختلفتين إذا هنا في عند دائرة الـ cis والـ trans فعلًا
+
+263
+00:23:39,920 --> 00:23:44,000
+هي الـ cis 2,3 ثنائي مثيل اوكسيران وهذا لما يكون
+
+264
+00:23:44,000 --> 00:23:50,440
+عكس بعض لـ trans 2,3 ثنائي مثيل اوكسيران واضح؟
+
+265
+00:23:53,560 --> 00:23:58,600
+الآن هذه الـ oxirans لما قلنالكم كيف بتتحضر ذكرنا
+
+266
+00:23:58,600 --> 00:24:02,320
+أنها بشكل أساسي من الـ peroxyacids يعني هاي مثلًا
+
+267
+00:24:02,320 --> 00:24:11,240
+Cyclohexane مع peroxyacid بيعطيني Cyclohexane Oxide
+
+268
+00:24:12,210 --> 00:24:17,490
+أو اثنين سواء مع peroxyacid أو صناعيًا لأنه يلزمنا
+
+269
+00:24:17,490 --> 00:24:20,910
+كتير الـ oxirane بيحضروا مع الـ Oxygen في وجود
+
+270
+00:24:20,910 --> 00:24:26,330
+silver catalyst ودرجة حرارة 250 وضغط برضه بيعطينا
+
+271
+00:24:26,330 --> 00:24:31,290
+الـ oxirane واضح؟ إذن هي العملية في الآخر Oxidation
+
+272
+00:24:31,290 --> 00:24:34,710
+لا الـ الـ مصانع الكبيرة بيستعملوا الـ peroxyacids ال
+
+273
+00:24:34,710 --> 00:24:38,410
+الإيثيلين لأنه صناعة والصناعة هي اللي فيها استعمال
+
+274
+00:24:38,410 --> 00:24:41,730
+درجات حرارة عالية واستعمال ضغط وما إلى ذلك
+
+275
+00:24:41,730 --> 00:24:46,510
+فبياخدوا إيثيلين مع أكسجين silver catalyst حرارة
+
+276
+00:24:46,510 --> 00:24:54,150
+ضغط بيعطينا الأميس إليه هذا الـ oxirane اللي هو أبسط
+
+277
+00:24:54,150 --> 00:24:59,610
+Cyclic Ether لكن هذا Cyclic Ether مهم كتير لأنه له
+
+278
+00:24:59,610 --> 00:25:05,710
+تطبيقات في التحضيرات العضوية وأنا بتهيأ لي؟ أنه
+
+279
+00:25:05,710 --> 00:25:06,670
+احنا أخذنا
+
+280
+00:25:09,100 --> 00:25:14,940
+طبّته احنا أخذنا بعض التطبيقات تبعته لما نيجي
+
+281
+00:25:14,940 --> 00:25:20,400
+نفعله أول شيء لازم نعمل التفاعل بـ acidic medium
+
+282
+00:25:20,400 --> 00:25:23,800
+لازم نعمل التفاعل بـ acidic medium بيعمل
+
+283
+00:25:23,800 --> 00:25:27,340
+protonation هنا الآن بعديك لو فعلنا مع المية المية
+
+284
+00:25:27,340 --> 00:25:28,960
+بتحط any nucleophile
+
+285
+00:25:32,960 --> 00:25:38,440
+واضح؟ إذا كأنه المية أو أي nucleophile أنتم
+
+286
+00:25:38,440 --> 00:25:42,080
+تتخيلوا أن هذا الـ oxirane معاه الـ nucleophile بدّه
+
+287
+00:25:42,080 --> 00:25:46,180
+يهاجم لـ nucleophile بهذا الشكل وهذا الرابط بيتكسر
+
+288
+00:25:46,180 --> 00:25:55,620
+فبيصير عند الـ nucleophile هاي الـ nucleophile CH2 كمان
+
+289
+00:25:55,620 --> 00:25:59,540
+CH2 OH
+
+290
+00:26:00,800 --> 00:26:05,280
+هذا الجزء اللي حاطينه احنا هنا في الدائرة من وين
+
+291
+00:26:05,280 --> 00:26:11,460
+أتي من الـ Ox-Urane وهذا الـ nucleophile اللي بيهجم
+
+292
+00:26:11,460 --> 00:26:17,440
+هذه الكربونة فبيصير عندنا هنا CH2 CH2 OH وهذا
+
+293
+00:26:17,440 --> 00:26:21,860
+الـ nucleophile اللي من برا واضح؟ مثلًا لو كان عندكم
+
+294
+00:26:21,860 --> 00:26:23,500
+الـ nucleophile Methanol
+
+295
+00:26:30,420 --> 00:26:35,440
+الـ O مثيل كأنه nucleophile هنا O مثيل لو كان عندكم
+
+296
+00:26:35,440 --> 00:26:40,420
+مثلًا إيثيلين جلايكول واحدة من هدول الـ OH بتهاجم
+
+297
+00:26:40,420 --> 00:26:48,460
+بتفتح حلقة CH2 CH2 OH لو كان عندكم فينيل MgBr ما
+
+298
+00:26:48,460 --> 00:26:53,340
+عليكم فينيل MgBr يمكن المحاضرة الماضية هذا اللي
+
+299
+00:26:53,340 --> 00:26:58,350
+سمّينه احنا إيش؟ الـ Grignard Reagent والـ
+
+300
+00:26:58,350 --> 00:27:02,370
+Grignard Reagent اتفقنا أن هو يمثل الـ
+
+301
+00:27:02,370 --> 00:27:09,130
+nucleophile بمعنى فينيل مع زوج الإلكترونات، تطلعوا
+
+302
+00:27:09,130 --> 00:27:14,490
+هنا زوج الإلكترونات كأنه تابع لمن؟ للفينيل، بناء على
+
+303
+00:27:14,490 --> 00:27:17,970
+ذلك هذا زوج الإلكترونات اللي على الفينيل هو اللي
+
+304
+00:27:17,970 --> 00:27:21,630
+بيجي يهاجمها لو بتكون طابقوا على هذه المعادلة كأن
+
+305
+00:27:21,630 --> 00:27:26,310
+اللي عندكم هي فينيل زوج الإلكترونات بيهجم هنا
+
+306
+00:27:26,310 --> 00:27:35,310
+بيعمل الـ bond بيصير عندي CH2 CH2 فينيل OH واضح؟
+
+307
+00:27:36,680 --> 00:27:41,280
+إذا لو احنا بنجي .. بنجيبلكم سؤال synthesis كيف
+
+308
+00:27:41,280 --> 00:27:46,940
+ممكن نتحضروا مركب إذا لمحتوا في هذا المركب مجموعة
+
+309
+00:27:46,940 --> 00:27:52,920
+CH2 CH2 OH إذا بإمكانكم تتخيلوا أن هذه المجموعة
+
+310
+00:27:52,920 --> 00:28:01,290
+أصلها كان Oxirane واضح؟ إذا لمحتوا مجموعة الـ CH2
+
+311
+00:28:01,290 --> 00:28:06,830
+CH2 OH بتكونوا تصيروا تفكروا أن هذه المجموعة الأصل
+
+312
+00:28:06,830 --> 00:28:12,910
+تبعها كان Oxirane لأن حلقة Oxirane بتفتح لما تتفاعل
+
+313
+00:28:12,910 --> 00:28:19,590
+مع الـ nucleophiles و بتعطينا مركبات تحتوي على هذه
+
+314
+00:28:19,590 --> 00:28:21,450
+المجموعة CH2 CH2 OH
+
+315
+00:28:27,970 --> 00:28:33,090
+تنسوش تحطوا الـ O هذي اللي منسية في الراسي أول
+
+316
+00:28:33,090 --> 00:28:42,890
+مركب OH طبعًا
+
+317
+00:28:42,890 --> 00:28:49,910
+الـ cyclic ethers مش بس حلقات ثلاثية ممكن يكونوا
+
+318
+00:28:49,910 --> 00:28:55,640
+موجودين على شكل حلقة رباعية ممكن يكون يعني رباعية
+
+319
+00:28:55,640 --> 00:28:59,840
+يعني زي هيك Oxygen وأربع ذرات ممكن يكونوا على شكل
+
+320
+00:28:59,840 --> 00:29:05,440
+حلقات خماسية ممكن سداسية ممكن في حلقات سداسية يكون
+
+321
+00:29:05,440 --> 00:29:08,160
+فيها two oxygens يعني
+
+322
+00:29:13,210 --> 00:29:18,250
+واضح؟ الآن المركب اللي في حلقة رباعية مش كتير
+
+323
+00:29:18,250 --> 00:29:24,250
+مشهور يمكن عشان هيك احنا مش راسمينه بيسموه Oxetane
+
+324
+00:29:24,250 --> 00:29:31,250
+مش كتير مشهور المركب اللي في حلقة خماسية هذا مشهور
+
+325
+00:29:31,250 --> 00:29:36,590
+كتير هذا يستعمل في الكيمياء العضوية كـ solvent اسمه
+
+326
+00:29:39,570 --> 00:29:44,370
+واختصاره THF كتير بتلاحظوا موجود عندكم solvent
+
+327
+00:29:44,370 --> 00:29:49,450
+اسمه THF أو Tetrahydrofuran هذا عبارة عن Cyclic
+
+328
+00:29:49,450 --> 00:29:53,450
+Ether الآن المركب اللي في الحلقة السداسية
+
+329
+00:29:53,450 --> 00:29:56,590
+Tetrahydropyran
+
+330
+00:29:56,590 --> 00:30:04,100
+Tetrahydropyran إذا كان في عندك أكسجنتين في الحلقة
+
+331
+00:30:04,100 --> 00:30:08,440
+السداسية بيصير المركب اللي اسمه دايوكسين هذا
+
+332
+00:30:08,440 --> 00:30:14,740
+الدايوكسين هو عبارة عن مركب سام مسرطن مركب
+
+333
+00:30:14,740 --> 00:30:19,380
+مسرطن سام الدايوكسين يمكن بتذكروا من عدة
+
+334
+00:30:19,380 --> 00:30:26,240
+سنوات يمكن قبل حوالي خمس سنين، ستة الإسبان اكتشفوا
+
+335
+00:30:26,240 --> 00:30:29,600
+الناس أنه في الزيوت اللي بيبيعوها زيت الزيتون فيه
+
+336
+00:30:29,600 --> 00:30:33,920
+دايوكسين سام وبناء على ذلك سحبوا كل شحنات زيت
+
+337
+00:30:33,920 --> 00:30:38,400
+الزيتون تبعتهم من مصر ومن السعودية ومن اليمن ليش كل
+
+338
+00:30:38,400 --> 00:30:43,860
+هذا الكلام صار؟ لأنه لقوا أن هذه مخلوطة بدايوكسين
+
+339
+00:30:45,110 --> 00:30:49,010
+لجوا أنه فيها نسبة دايوكسين هم الحقيقة لما ياخدوا
+
+340
+00:30:49,010 --> 00:30:54,070
+بقايا الزيوت بيعملوا لها استخلاص و extraction بـ
+
+341
+00:30:54,070 --> 00:30:58,690
+solvents زي الـ .. زي الـ hexanes والـ heptanes والـ
+
+342
+00:30:58,690 --> 00:31:04,250
+.. هي الـ .. الـ fuels هذه بيكون جزء منها دايوكسين و
+
+343
+00:31:04,250 --> 00:31:07,690
+ضايل مخلوط مع الزيت فلما بيحللوا الزيت لجوا فيه
+
+344
+00:31:07,690 --> 00:31:14,670
+نسبة دايوكسين فسحبوا الزيوت تبعتهم من الأسواق واضح؟
+
+345
+00:31:15,720 --> 00:31:22,760
+غير هدول المركبات، في عيلة جديدة تدخل الجمال،
+
+346
+00:31:22,760 --> 00:31:25,120
+يعني الواحدة ليها خطر، وغيرها كلها بالفعلات
+
+347
+00:31:25,120 --> 00:31:32,380
+التطريزية اللي هم مجموعة مركبات اكتشفت حديثًا،
+
+348
+00:31:32,380 --> 00:31:35,720
+يعني مش زمان تم اكتشافها، يعني الناس اللي اشتغلوا
+
+349
+00:31:35,720 --> 00:31:40,140
+عليها اشتغلوا تقريبًا في أوائل الثمانينات،
+
+350
+00:31:40,140 --> 00:31:43,520
+وبالنسبة لنا أوائل الثمانينات ما تُعتبرش بعيدة
+
+351
+00:31:43,520 --> 00:31:47,640
+نسبيًا، لأنه احنا بنحكي أحيانًا عن بعض الشغلات قبل
+
+352
+00:31:47,640 --> 00:31:51,920
+مية ومية وخمسين سنة يعني بتذكروا لما حكينا مثلًا عن
+
+353
+00:31:51,920 --> 00:32:00,440
+البنزين .. البنزين اكتشافه كسائل كان 1825 يعني قبل
+
+354
+00:32:00,440 --> 00:32:06,180
+حوالي 200 سنة لما نحكي مثلًا عن Grignard reagent،
+
+355
+00:32:06,180 --> 00:32:12,540
+Grignard أخد جائزة نوبل في الكيمياء سنة 1911 هذا
+
+356
+00:32:12,540 --> 00:32:16,400
+بالضبط قبل مائة سنة، مظبوط ولا لا؟ لكن هدول
+
+357
+00:32:16,400 --> 00:32:19,900
+المركبات الحلوين اللي موجودين هنا بيسموهم الـ crown
+
+358
+00:32:19,900 --> 00:32:24,740
+ethers الـ crown ethers هدول في الـ .. في
+
+359
+00:32:24,740 --> 00:32:28,580
+الثمانينات اكتشفوا والناس اللي اشتغلوا عليهم و
+
+360
+00:32:28,580 --> 00:32:31,780
+طلعوهم أخدوا عليهم جائزة نوبل في الكيمياء بالألف
+
+361
+00:32:31,780 --> 00:32:37,360
+تسعمائة وسبعة وثمانين ألف
+
+362
+00:32:37,360 --> 00:32:41,440
+تسعمائة وسبعة وثمانين سنة ميلادكم ولا برضه قبل؟
+
+363
+00:32:42,950 --> 00:32:48,470
+خلاص خلاص أنتم مولود 2010 فيعتبر
+
+364
+00:32:48,470 --> 00:32:52,630
+نسبيًا نجدال إيش هم هدول الـ crown ethers اللي لهم
+
+365
+00:32:52,630 --> 00:32:58,250
+الأهمية زي ما أنتم بتلاحظوا Cyclic ethers فيهم
+
+366
+00:32:58,250 --> 00:33:03,410
+تكرار لمجموعة CH2 CH2 وبعدين Oxygen CH2 CH2 وبعدين
+
+367
+00:33:03,410 --> 00:33:06,690
+Oxygen CH2 CH2 وبعدين Oxygen CH2 CH2 وبعدين
+
+368
+00:33:06,690 --> 00:33:11,920
+Oxygen وممكن يكونوا على عدة أحجام ممكن يكون
+
+369
+00:33:11,920 --> 00:33:16,540
+على عدة أحجام الآن كيف بيجوا بيسموهم لما يجوا
+
+370
+00:33:16,540 --> 00:33:20,180
+يسموهم خلينا نبدأ نعد من أي نقطة يعني لو بدأنا من
+
+371
+00:33:20,180 --> 00:33:24,640
+هنا واتحركنا نعد كل الذرات 1 2 3 4
+
+372
+00:33:24,640 --> 00:33:28,660
+5 6 7 8 
+
+401
+00:36:06,450 --> 00:36:12,150
+بتيجوا تتطلعوا هنا للفجوة
+
+402
+00:36:12,150 --> 00:36:17,550
+بتعتمد على نوع الـ ether يعني هذا الـ ether الـ 12
+
+403
+00:36:17,550 --> 00:36:23,250
+crown 4 قارن الفجوة تبعته مع الـ 15 crown 5 قارن
+
+404
+00:36:23,250 --> 00:36:29,830
+الفجوة تبعته مع الـ 18 crown 6 بتلاحظوا أن حجم
+
+405
+00:36:29,830 --> 00:36:37,770
+الفجوات مختلف، هذا الكلام بيشدد على أن الأيونات 
+
+406
+00:36:37,770 --> 00:36:43,690
+المعدنية حجمها مختلف، فكأنه كل فجوة بتتناسب مع حجم
+
+407
+00:36:43,690 --> 00:36:50,990
+أيون معين، كل فجوة بتتناسب مع حجم أيون معين، بمعنى
+
+408
+00:36:50,990 --> 00:36:56,700
+لو أنا هنا حطيت أيون كبير بيصعب تبعه الفجوة، لو أنا
+
+409
+00:36:56,700 --> 00:37:01,480
+حطيت هنا أيون صغير كتير، بيطلع من الفجوة، بيعملش 
+
+410
+00:37:01,480 --> 00:37:06,560
+ارتباط، لازم الـ أيون يكون جد و جد الفجوة تقريبا
+
+411
+00:37:06,560 --> 00:37:12,900
+فبناء على ذلك بيستفيدوا من هذه الشغلة في الصناعة
+
+412
+00:37:12,900 --> 00:37:18,540
+وفي الـ biology مثلا لو أنا أجيت أخدت تلات أيونات الـ
+
+413
+00:37:18,540 --> 00:37:23,640
+sodium و الـ potassium و الـ cesium وشوفت قداش الـ
+
+414
+00:37:23,640 --> 00:37:30,080
+diameter تبعهم قداش القطر تبعهم، الـ sodium قطره 1.9
+
+415
+00:37:30,080 --> 00:37:33,080
+angstrom، الـ potassium 2.6
+
+416
+00:37:36,290 --> 00:37:43,250
+3.34، الآن لو جيت جبت هذا المركب وقست قداش الفجوة
+
+417
+00:37:43,250 --> 00:37:48,050
+تبعته، كل العلماء بيشتغلوا بقصة الـ cavity تبعته 2.6 
+
+418
+00:37:48,050 --> 00:37:55,230
+إلى 3.2 cavity تقريبا، الآن لو جيت قلت أحط هذا الـ
+
+419
+00:37:55,230 --> 00:38:00,150
+crown ether في محلول يحتوي على التلات أيونات هدول
+
+420
+00:38:00,150 --> 00:38:02,590
+أن هو اللي بيصبط معه الـ potassium
+
+421
+00:38:05,360 --> 00:38:11,400
+هذا متناسب مع هذه الفجوة، بناء على ذلك لو كان عندي 
+
+422
+00:38:11,400 --> 00:38:16,100
+محلول فيه تلات أيونات وحطيت هذا الـ crown بياخد الـ
+
+423
+00:38:16,100 --> 00:38:19,860
+potassium و يسيب التنين التانيين، اتلاحظين أنتو؟
+
+424
+00:38:19,860 --> 00:38:25,920
+يعني الـ cavity تبعته بس على جد الـ potassium، الـ
+
+425
+00:38:25,920 --> 00:38:33,040
+cavity تبعته بس على جد الـ potassium مش على جد 
+
+426
+00:38:33,040 --> 00:38:39,660
+السيزيام كبير ولا الـ sodium يعتبر صغير، واضح؟ يمكن
+
+427
+00:38:39,660 --> 00:38:45,120
+هذا الكلام له تطبيق، فتفترضوا أكثر، فتفترضوا احنا ناخد 
+
+428
+00:38:45,120 --> 00:38:51,360
+نظرية أن الـ sodium بما إنه صغير عيب كبير دائمًا
+
+429
+00:38:51,360 --> 00:38:54,620
+ارتباط، كفر كفر، يعني من الحكي الكبير بوصل لصغير
+
+430
+00:38:54,620 --> 00:38:58,760
+بعكس اللي .. اه بس لصغير اللي هو بده يعمل ارتباط 
+
+431
+00:38:59,460 --> 00:39:05,020
+بده يعمل ارتباط، واضح؟ بده يعمل ارتباط، هل بيقدر و
+
+432
+00:39:05,020 --> 00:39:09,580
+هو صغير، هاي كل حجم الـmetal في درجة، هالجد و هاي
+
+433
+00:39:09,580 --> 00:39:13,580
+حجم الخضر، هل بيقدر يصل لهدول أزواج الإلكترونية
+
+434
+00:39:13,580 --> 00:39:17,260
+يعمل ارتباط معهم؟ مابقدرش يعمل ارتباط، زي ما هذا
+
+435
+00:39:17,260 --> 00:39:21,700
+رابط من كل الجهة، هذا لما يكون بهذا الشكل القطر تبعه
+
+436
+00:39:21,700 --> 00:39:28,000
+فيمكن يعمل الـ bonding بس لصغير لا مابظبطش هذا 
+
+437
+00:39:28,000 --> 00:39:32,380
+الكلام له حقيقة تطبيقات كتير سواء في الكيميا
+
+438
+00:39:32,380 --> 00:39:38,680
+ككيميا أو في الفروع الطبية المتعلقة بالكيميا مثلا
+
+439
+00:39:38,680 --> 00:39:43,460
+جزء من تطبيقاته أن لو أنا أخدت مركب أيوني زي الـ
+
+440
+00:39:43,460 --> 00:39:50,400
+potassium permanganate الـ KMnO4 هذا الـ kamano أو فور
+
+441
+00:39:50,400 --> 00:39:56,500
+تخيل لو أنا قلت أدوب في البنزين، البنزين مش البنزين
+
+442
+00:39:56,500 --> 00:40:03,090
+solvent، الـ kamano أو فور في البنزين لا يدوب، مابيدوبش
+
+443
+00:40:03,090 --> 00:40:08,970
+ليش مابيدوبش؟ لأن هذا الـ KMnO4 K Plus MnO4 minus
+
+444
+00:40:08,970 --> 00:40:13,090
+Ionic وهذا Non Ionic وانتوا القاعدة العامة اللي
+
+445
+00:40:13,090 --> 00:40:16,570
+عندكم في الذابية Like Dissolve Like، هذا وهذا مش
+
+446
+00:40:16,570 --> 00:40:21,350
+من نفس الأشياء، هذا Ionic وهذا مش Ionic، بناء على
+
+447
+00:40:21,350 --> 00:40:26,730
+ذلك لو أنا لغرض التفاعل بدي أفعل مركب الـ KMnO4 في
+
+448
+00:40:26,730 --> 00:40:33,170
+البنزين ما بيدوبش، طب كيف بيدوبوه؟ بيجوا جوا البنزين
+
+449
+00:40:33,170 --> 00:40:38,210
+جوا البنزين يعني الـ solvent اللي عنده بنزين بيحطوا
+
+450
+00:40:38,210 --> 00:40:45,970
+الـ crown هذا اللي هو الـ 18 crown 6 بيحطوا الـ 18
+
+451
+00:40:45,970 --> 00:40:51,830
+crown 6، هذا الـ 18 crown 6 لما أنا بدي أحط kmn04
+
+452
+00:40:51,830 --> 00:41:00,980
+إيش بيعمل؟ بياخد الـ K في الـ cavity تبعته، صارت دوّب
+
+453
+00:41:00,980 --> 00:41:05,400
+المركب لأن الـ crown بيدوب في البنزين و الـ
+
+454
+00:41:05,400 --> 00:41:10,780
+crown بيدوّب البوتاسيوم في قلبه، بيحط البوتاسيوم في
+
+455
+00:41:10,780 --> 00:41:14,660
+قلب الـ cavity تبعته وبناء على ذلك برمجانات
+
+456
+00:41:14,660 --> 00:41:20,300
+البوتاسيوم مع البنزين لا تدوب مع بنزين مخلوط فيه 
+
+457
+00:41:20,300 --> 00:41:25,420
+شوية crown بيدوب، أنا مش مهم عندي لغرض التفاعل
+
+458
+00:41:25,420 --> 00:41:30,390
+بالمناسبة، لأن الـ crown ولا البوتاسيوم ولا البنزين
+
+459
+00:41:30,390 --> 00:41:34,070
+عارفين أنتو إيش اللي أنا مهم عندي بالتفاعل؟ الـ MnO4
+
+460
+00:41:34,070 --> 00:41:38,190
+minus اللي ضالت حرة بتمشي في البنزين لأنها عامل
+
+461
+00:41:38,190 --> 00:41:42,850
+مؤكسد لما درستوا الأكسدة والعوامل المؤكسدة أنّه
+
+462
+00:41:42,850 --> 00:41:46,450
+اللي كان اسمه عامل مؤكسد ومهم كتير بالنسبة إليه
+
+463
+00:41:46,450 --> 00:41:51,190
+بيرمانجانات البوتاسيوم يعني أنه .. أن واحدة تيجي
+
+464
+00:41:51,190 --> 00:41:54,990
+تقول يا الله البوتاسيوم خسرناه راح جوا الـ crown مع
+
+465
+00:41:54,990 --> 00:41:58,570
+السلامة، ما هو المطلوب؟ أنا المطلوب عندي لغرض 
+
+466
+00:41:58,570 --> 00:42:04,190
+إجراء تفاعل X ده، جزء البوتاسيوم على جزء الـMnO4-
+
+467
+00:42:04,190 --> 00:42:09,890
+فالبوتاسيوم خلّى يدوب في الـ crown والـ MnO4-
+
+468
+00:42:09,890 --> 00:42:13,970
+بتصير تمشي في المحلول، طبعا لاحظوا معي لما تمت 
+
+469
+00:42:13,970 --> 00:42:19,400
+عملية ذابيتها دي، برمجانات البوتاسيوم شو لونها؟ بنفسجي
+
+470
+00:42:19,400 --> 00:42:26,220
+بناء على ذلك البنزين هنا بيصير لونه بنفسجي، البنزين
+
+471
+00:42:26,220 --> 00:42:30,480
+اللي مدوب فيه برمجانات البوتاسيوم بمساعدة الـ
+
+472
+00:42:30,480 --> 00:42:35,240
+18 crown 6 بيسموه pear ball، بنزينماذا يعني
+
+473
+00:42:35,240 --> 00:42:40,540
+بيربو البنزين؟ البنزين البنفسجي وهذا يعتبر 
+
+474
+00:42:40,540 --> 00:42:45,900
+oxidizing agent، عامل مؤكسد ليش عامل مؤكسد؟ بسبب
+
+475
+00:42:45,900 --> 00:42:49,280
+وجود مجموعة البرمانجانات الحرة ومجموعة
+
+476
+00:42:49,280 --> 00:42:54,820
+البرمانجانات من أفضل العوامل المؤكسدة، مظبوط ولا
+
+477
+00:42:54,820 --> 00:43:01,060
+لا؟ هذه تطبيق كيميائي استفدنا فيه من قصة الـ
+
+478
+00:43:01,060 --> 00:43:09,570
+cavity طبعا كتير مرات بيستعملوا .. بيستعملوا كلمات 
+
+479
+00:43:09,570 --> 00:43:16,730
+موازية في اللغة العربية لفكرة الضيف والمضيف، يعني
+
+480
+00:43:16,730 --> 00:43:22,390
+لما هذا يكون هذا في وسعه، إيش بنعتبره؟ مضيف، و
+
+481
+00:43:22,390 --> 00:43:25,830
+الأيون اللي بدأ يدخل فيه؟ ضيف، باللغة الإنجليزية
+
+482
+00:43:25,830 --> 00:43:33,120
+إيش بيقولوها؟ host guest، host guest، هذا الـ host و
+
+483
+00:43:33,120 --> 00:43:36,800
+الـ potassium اللي إجا فيه الـ guest، إذا صار عندي 
+
+484
+00:43:36,800 --> 00:43:40,340
+ضيف ومضيف host guest، لكن في البنزين العكس صار
+
+485
+00:43:40,340 --> 00:43:44,960
+البنزين هو الـ host، لا أبدا أبدا، في البنزين البنزين
+
+486
+00:43:44,960 --> 00:43:50,240
+solvent والـ crown دايب فيه دايب في البنزين، الآن 
+
+487
+00:43:50,240 --> 00:43:55,140
+إيش اللي إجا جوا الـ crown، الـ K اللي إجا في قلبه
+
+488
+00:43:55,140 --> 00:44:03,670
+واضح؟ هي هنا عندكم صورة شبيهة لمضاد حيوي يستعمل
+
+489
+00:44:03,670 --> 00:44:08,710
+شبيه فكرته زي ما بتلاحظوا بإيش؟ بالـ crown ethers
+
+490
+00:44:08,710 --> 00:44:12,770
+وإن كان على أكبر لكن في عندكم هنا oxygens اشملها
+
+491
+00:44:12,770 --> 00:44:18,490
+متكررة، بناء على ذلك هذه الـ oxygens ممكن تحتوي أيون
+
+492
+00:44:18,490 --> 00:44:23,060
+في قلبها ولا لأ؟ زي أيون البوتاسيوم وهذا المضاد
+
+493
+00:44:23,060 --> 00:44:28,620
+الحيوي بياخد تحديدا حسب حجم الـ cavity الفراغة
+
+494
+00:44:28,620 --> 00:44:32,180
+اللي فيها للبوتاسيوم وبيمشي في البوتاسيوم من داخل 
+
+495
+00:44:32,180 --> 00:44:36,620
+جدار الخلية، يعني شوفوا كيف عملية أنه بنتقل كل هذا 
+
+496
+00:44:36,620 --> 00:44:39,680
+بدخل في جدار الخلية وبيدخل حامل معاه إيش؟
+
+497
+00:44:39,680 --> 00:44:44,600
+البوتاسيوم، بيدخل جدار الخلية وبيدخل حامل معاه
+
+498
+00:44:44,600 --> 00:44:50,660
+البوتاسيوم، بهيك تقريبا بنكون انتهينا من هذا الفصل
+
+499
+00:44:50,660 --> 00:44:53,500
+اللي هو الـ ether ومتعلقاته، الحصة اللي جاي إن شاء
+
+500
+00:44:53,500 --> 00:44:55,340
+الله بنبدأ في الـ aldi heights
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3f764b55e10f5cb3cbf25e3d0b33d77d01352194
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/SIxMB7el5Xo_postprocess.srt
@@ -0,0 +1,2000 @@
+1
+00:00:06,440 --> 00:00:12,000
+اليوم ان شاء الله هنبدأ chapter جديد اللي هو ال
+
+2
+00:00:12,000 --> 00:00:16,080
+aromatic compounds الفصل الرابع ال aromatic
+
+3
+00:00:16,080 --> 00:00:23,980
+compounds chapter بسيط و مسهل و ممتعطبعا حتى نعرف
+
+4
+00:00:23,980 --> 00:00:28,340
+إيش موقعهم من الإعراب ال aromatic compounds حتى
+
+5
+00:00:28,340 --> 00:00:34,640
+نعرف إيش موقعهم من الإعراب بنذكر التقسيم العام لل
+
+6
+00:00:34,640 --> 00:00:38,360
+hydrocarbons لحظة ما قلنا إن في عندنا saturated
+
+7
+00:00:38,360 --> 00:00:43,420
+hydrocarbons وفي عندناunsaturated hydrocarbons الـ
+
+8
+00:00:43,420 --> 00:00:47,520
+unsaturated اللي كان فيهم double bonds فمن ال
+
+9
+00:00:47,520 --> 00:00:51,260
+unsaturated ال alkenes كانت عندى ب one double bond
+
+10
+00:00:51,260 --> 00:00:54,920
+و ال alkynes ب two double bonds يعني بال triple
+
+11
+00:00:54,920 --> 00:00:58,780
+bond و كان عندنا الجزء الأخر اللى هو موضوع درسنا
+
+12
+00:00:58,780 --> 00:01:02,660
+اليوم ال aromatic compounds اللى هي المركبات
+
+13
+00:01:02,660 --> 00:01:09,940
+الحلقية اللى فيهاأكثر من رابطة زوجية وبدول الروابط
+
+14
+00:01:09,940 --> 00:01:13,240
+الزوجية بنقول عنهم بيكونوا conjugated يعني بيكونوا
+
+15
+00:01:13,240 --> 00:01:17,840
+على شكل double single double single و لازم كل ال
+
+16
+00:01:17,840 --> 00:01:22,600
+aromatic compounds يكونوا في إيش؟ في حلقة لازم
+
+17
+00:01:22,600 --> 00:01:26,080
+عشان نحكي عن aromatic compounds نحكي عن حلقة يعني
+
+18
+00:01:26,080 --> 00:01:30,180
+لو بدنا نجيبلكم مركب مش حلقة ماحدش عمره يفكر أنه
+
+19
+00:01:30,180 --> 00:01:33,880
+يصنفوا تحت aromatic compounds واضح؟
+
+20
+00:01:36,110 --> 00:01:41,090
+الان اذا برضه بدنا نرجع ل slide نتذكر بعض
+
+21
+00:01:41,090 --> 00:01:44,830
+المعلومات بخصوص ال double bond و ال single bond و
+
+22
+00:01:44,830 --> 00:01:48,730
+ال triple bond اخدنا احنا ال bond length و اخدنا
+
+23
+00:01:48,730 --> 00:01:53,980
+ال bond anglesو ال rotation و ال geometry و ال
+
+24
+00:01:53,980 --> 00:01:58,000
+hybridization يمكن اكتر اشي بيهمنا نركز عليه ال
+
+25
+00:01:58,000 --> 00:02:03,640
+double bond ليش double bond؟ لأنه البنزين موجود
+
+26
+00:02:03,640 --> 00:02:08,600
+فيه double bonds البنزين كحلقة سداسية موجود فيه
+
+27
+00:02:08,600 --> 00:02:13,240
+double bonds واضح؟ يعني لو بدى اشوف انا model
+
+28
+00:02:13,240 --> 00:02:19,360
+للبنزين هي حلقة البنزين بهذا الشكلهذا الشكل في
+
+29
+00:02:19,360 --> 00:02:22,840
+حلقة البنزين زي ما انتوا شايفين فبتلاحظوا ايش اللي
+
+30
+00:02:22,840 --> 00:02:27,420
+موجود عندى double single double single double
+
+31
+00:02:27,420 --> 00:02:29,640
+single هذا اللي هي عملية اللي بنسميها ال
+
+32
+00:02:29,640 --> 00:02:34,260
+conjugation ان ال double bonds are conjugated واضح
+
+33
+00:02:34,260 --> 00:02:40,060
+الان كل carbonكل carbon من ال carbons الستة لو
+
+34
+00:02:40,060 --> 00:02:44,880
+اجيت اطلع عليها حقيقة بلاقينها على طرف double bond
+
+35
+00:02:44,880 --> 00:02:48,620
+يعني هي هذه طرف double bond هذه .. هذه .. هذه ..
+
+36
+00:02:48,620 --> 00:02:52,900
+هذه و بناء على ذلك لو اجينا بدنا نتساءل ايش ال
+
+37
+00:02:52,900 --> 00:02:59,800
+hybridization لكل carbon هلاحظ انه طالع منها اتجاه
+
+38
+00:02:59,800 --> 00:03:02,760
+اتجاهين تلاتة
+
+39
+00:03:06,160 --> 00:03:15,260
+الزاوية 120 المجموع 360 اذا ال carbons اللي
+
+40
+00:03:15,260 --> 00:03:22,720
+موجودين في البنزين جميعهم sb2 hybrid carbons all
+
+41
+00:03:22,720 --> 00:03:28,300
+the carbons in benzene are sb2 hybrid carbons واضح
+
+42
+00:03:28,300 --> 00:03:37,290
+ال bond angle 120الـ bond angle 120 الآن بيجينا
+
+43
+00:03:37,290 --> 00:03:42,910
+شغلة كتير مهمة اللي هي ال bond order و ال bond
+
+44
+00:03:42,910 --> 00:03:50,690
+length ال bond order بنقصد فيه كام عدد الروابط بين
+
+45
+00:03:50,690 --> 00:03:56,900
+ذرتين الكربونكم عدد الروابط من ذرات الكربون الان
+
+46
+00:03:56,900 --> 00:04:01,940
+اذا كنت تتطلع على شكل وحيد من هدولة هتقول والله
+
+47
+00:04:01,940 --> 00:04:06,720
+الروابط في عنده double و single و double و single
+
+48
+00:04:06,720 --> 00:04:10,580
+و double و single هذا الكلام لو انه زي هيك و الشكل
+
+49
+00:04:10,580 --> 00:04:14,720
+ثابت ال single bond أطول من ال double bond اتطلع
+
+50
+00:04:14,720 --> 00:04:21,240
+طول ال single bond بشكل عادل 154 double bond 134
+
+51
+00:04:21,540 --> 00:04:24,820
+فلو هذا الكلام .. لو شكل البنزين زي هيك .. انه فيه
+
+52
+00:04:24,820 --> 00:04:29,040
+double bond و single bond .. كان هذه بده تكون 134
+
+53
+00:04:29,040 --> 00:04:34,140
+و التانية بده تكون 154 .. اذا هل هيكون الطول تبع
+
+54
+00:04:34,140 --> 00:04:40,280
+هدوله متساوي؟ .. هيصير شكل البنزين كيف؟ غير منتظم
+
+55
+00:04:40,280 --> 00:04:47,840
+.. بمعنى مش الست روابط جات بعضالان بالتجربة لاحظوا
+
+56
+00:04:47,840 --> 00:04:52,100
+ان البنزين الست روابط اللى موجودة فيه نفس الطول
+
+57
+00:04:52,100 --> 00:04:59,560
+واضح؟ الست روابط نفس الطول طيب ماشي نفس الطول هل
+
+58
+00:04:59,560 --> 00:05:05,380
+هما يا ترى طولهم من طول ال double bond اللى قصيرة
+
+59
+00:05:05,380 --> 00:05:09,680
+ولا من طول ال single bond اللى طويلة اللى لاحظوا
+
+60
+00:05:09,680 --> 00:05:15,560
+ان طولهم شئ ما betweenthe double bond lengths and
+
+61
+00:05:15,560 --> 00:05:18,960
+the single bond lengths يعني طولهم جاي بين بين
+
+62
+00:05:18,960 --> 00:05:25,140
+واضح طول الرابطة لا هو double bond اكسير ولا هو
+
+63
+00:05:25,140 --> 00:05:30,380
+single bond طويل الآن السؤال كأنه إذا مش double
+
+64
+00:05:30,380 --> 00:05:33,560
+bond إذا مش اتنين أو مش واحد إيش بدي يطلع أنا بدي
+
+65
+00:05:33,560 --> 00:05:38,480
+أطلع واحد و نص اللي هو عدد الروابط بالظبط بطلع
+
+66
+00:05:38,480 --> 00:05:43,890
+واحد و نصفال bond order .. ال bond order في
+
+67
+00:05:43,890 --> 00:05:49,610
+البنزين لو هو واحدولا هو اتنين واحد و نص انتوا لو
+
+68
+00:05:49,610 --> 00:05:52,870
+كنتوا بتشوفوا كيف هذا الكلام بيصير بيصير بسبب ال
+
+69
+00:05:52,870 --> 00:05:57,030
+resonance انه هذه في لحظة من اللحظات double bond
+
+70
+00:05:57,030 --> 00:06:00,210
+وهذه single bond نتيجة ال resonance هذه بتصير
+
+71
+00:06:00,210 --> 00:06:04,150
+double bond وهذه single bond يعني كأنه هالمكانين
+
+72
+00:06:04,150 --> 00:06:07,090
+هدول لو اجيتوا اطلعتوا كام bond اللي موجود فيهم؟
+
+73
+00:06:07,090 --> 00:06:15,470
+واحد اتنين تلاتة لما يصير في resonance1.5 إذا كل
+
+74
+00:06:15,470 --> 00:06:22,730
+رابطة في البنزين 1.5 bond order يعني عندي رابطة و
+
+75
+00:06:22,730 --> 00:06:26,270
+نص bond
+
+76
+00:06:26,270 --> 00:06:33,180
+order in بنزين is 1.5بسبب ال resonance انه في عندى
+
+77
+00:06:33,180 --> 00:06:38,020
+حركة في ال bonds double single double single مرة
+
+78
+00:06:38,020 --> 00:06:40,860
+هدى double هدى single مرة هدى double هدى single
+
+79
+00:06:40,860 --> 00:06:45,200
+المتوسط تبعهم اش بده يطلع بده يطلع عندنا المتوسط
+
+80
+00:06:45,200 --> 00:06:49,260
+تبعهم واحد و نصف و عشان هيك ال bond length للرابطة
+
+81
+00:06:49,260 --> 00:06:52,580
+في البنزين بيكون بين الرابطة القصيرة اللى هى ال
+
+82
+00:06:52,580 --> 00:06:58,490
+double bondالـ 134 و بين الكبيرة 154 بالتجربة نسو
+
+83
+00:06:58,490 --> 00:07:06,730
+139 جاي قيمة بين القيمتين واضح فال bond length هيك
+
+84
+00:07:06,730 --> 00:07:14,100
+بيصير عندى واضح ان هوبين بين و ال bond order واحد
+
+85
+00:07:14,100 --> 00:07:17,280
+و نص بالظبط واحد و نص يعني لما نسألكوا the bond
+
+86
+00:07:17,280 --> 00:07:22,480
+order in بنزين is two and one لأ لو two and one
+
+87
+00:07:22,480 --> 00:07:26,260
+كان بيكون رابطة صيرة و رابطة طويلة و شكل البنزين
+
+88
+00:07:26,260 --> 00:07:30,720
+غير منتظم لكن الحقيقة البنزين شكله منتظم الآن
+
+89
+00:07:30,720 --> 00:07:34,860
+معلومة إضافية عن البنزين لأن كل هدول الزوايا مية و
+
+90
+00:07:34,860 --> 00:07:37,820
+عشرين كجزء كل البنزين شو بيكون
+
+91
+00:07:43,700 --> 00:07:51,280
+البنزين بلانر لأن كل الروابط اللي فيه SB2 hybrid
+
+92
+00:07:51,280 --> 00:07:52,280
+orbitals
+
+93
+00:08:00,190 --> 00:08:03,970
+الآن لو بتكن تتطلعوا على ال hydrogens اللي هم
+
+94
+00:08:03,970 --> 00:08:08,450
+بيكملوا البنزين .. صيغته العامة إيش البنزين؟ C6 ..
+
+95
+00:08:08,450 --> 00:08:13,610
+H6 .. ال hydrogens اللي بيكملوا هذا البنزين .. هل
+
+96
+00:08:13,610 --> 00:08:17,390
+يا ترى بتفرج هدي عن هدي عن هدي عن هدي ولا متكافئات
+
+97
+00:08:17,390 --> 00:08:21,510
+كلهم .. كلهم متكافئات .. بمعنى لو قولنا بدنا نعمل
+
+98
+00:08:21,510 --> 00:08:27,240
+تفاعل .. انشيل واحدة منهم و نحط مكانها chlorineهل
+
+99
+00:08:27,240 --> 00:08:31,240
+بتفرق هذه عن هذه عن هذه عن هذه عن هذه ولا كلهم زي
+
+100
+00:08:31,240 --> 00:08:34,860
+بعض؟ كلهم زي بعض زي تماما لما كنتوا تاخدوا جزء
+
+101
+00:08:34,860 --> 00:08:41,700
+الميثين مثلا CH4 هل كان بيفرق عندى ان اشيل اي
+
+102
+00:08:41,700 --> 00:08:47,580
+هيدروجينة عن التانية؟ مابفرقش، واضح؟ فبناء على ذلك
+
+103
+00:08:47,580 --> 00:08:50,920
+لو انا بدأ اشيل اي هيدروجينة احط بدلها substitute
+
+104
+00:08:50,920 --> 00:08:56,700
+all the six hydrogens are equivalentare
+
+105
+00:08:56,700 --> 00:09:01,900
+equivalent، متكافئات، أي واحدة الإنسان بيقدر إيش؟
+
+106
+00:09:01,900 --> 00:09:07,580
+اشيلها، كل الأماكن زي بعض، كل الأماكن زي بعض، زي
+
+107
+00:09:07,580 --> 00:09:11,680
+اللي بدو يروح يحج، بدو يقف ع جبل عرفة، الرسول عليه
+
+108
+00:09:11,680 --> 00:09:22,010
+الصلاة والسلام إيش قال؟وعرفته كلها موقف وانتبهوا
+
+109
+00:09:22,010 --> 00:09:27,930
+معي لشغل كتير مهمة لو شيلت واحدة من هدولة وحطيت
+
+110
+00:09:27,930 --> 00:09:35,690
+مكانها نفترض ذرة كلور زي هيك صار الجزء اختلف اول
+
+111
+00:09:35,690 --> 00:09:40,170
+واحدة اشيل اي واحدة مفرجش بعد هيك بدي اشيل واحدة
+
+112
+00:09:40,170 --> 00:09:46,900
+تانيةبصير إذا شيلت من هان أو من هان بحط مركب معين
+
+113
+00:09:46,900 --> 00:09:51,540
+لو شيلت من هان حيصير مركب تاني لو شيلت من هان
+
+114
+00:09:51,540 --> 00:09:55,140
+حيصير مركب تاني بصير عنده إش جديد لما يكون عنده
+
+115
+00:09:55,140 --> 00:10:01,560
+two substituents بس the first substituent الست
+
+116
+00:10:01,560 --> 00:10:06,020
+أماكن متكافئة لكن بعد ما غيرت واحدة الآن بنقول
+
+117
+00:10:06,020 --> 00:10:09,980
+بدنا نشيل التانية و نحط ذرة تانية أكيد هدولة تنتين
+
+118
+00:10:10,890 --> 00:10:16,510
+زي بعض بالنسبة لهذه اللي لونها أسود و هدول التنتين
+
+119
+00:10:16,510 --> 00:10:20,230
+زي بعض بالنسبة اللي لونها أسود و هذه اللي جاية
+
+120
+00:10:20,230 --> 00:10:26,090
+مقابل إلها تمثل واحدة طبعا إذا كنت أنا شايل أي
+
+121
+00:10:26,090 --> 00:10:29,330
+carbon أو إجيت أحط على الموقع هذا يمين أو شمال
+
+122
+00:10:29,330 --> 00:10:34,810
+بقول هذا الموقع ortho اللي هو الموقع المجاورلأ
+
+123
+00:10:34,810 --> 00:10:38,310
+الموقع الأول اللي انا حطيته اللي هو موقع two two
+
+124
+00:10:38,310 --> 00:10:43,830
+عن اليمين او two عن الجمال لو اجيت على هذا الموقع
+
+125
+00:10:43,830 --> 00:10:47,570
+اللي هو موقع تلاتة واحد اتنين تلاتة او واحد اتنين
+
+126
+00:10:47,570 --> 00:10:52,090
+تلاتة بسمي ميتا position و لو اجيت على الموقع هذا
+
+127
+00:10:52,090 --> 00:10:55,350
+اللي جاي على اربعة واحد اتنين تلاتة اربعة بسمي
+
+128
+00:10:55,350 --> 00:10:59,030
+البارا position بيصير عندى لما بده احط ال sub city
+
+129
+00:10:59,030 --> 00:11:02,190
+و انت التاني يا بده احط على هذا
+
+130
+00:11:06,350 --> 00:11:11,530
+هذا الكلام هناخده اكثر بالتفصيل لما بدنا نشرح
+
+131
+00:11:11,530 --> 00:11:14,990
+تفاعلات
+
+132
+00:11:14,990 --> 00:11:20,410
+البنزين لحتى الان واضح انكم ال hybridization ال
+
+133
+00:11:20,410 --> 00:11:23,210
+bond angles ال bond lengths البنزين
+
+134
+00:11:25,950 --> 00:11:31,250
+بداياكوا تتذكروا شغلة أنه العلم مابيجيش ببلاش ..
+
+135
+00:11:31,250 --> 00:11:37,510
+العلم مابيجيش ببلاش .. البنزين أول ما اكتشف ..
+
+136
+00:11:37,510 --> 00:11:42,430
+اكتشف سائل كان بيعمل فردق .. العالم فردق إذا
+
+137
+00:11:42,430 --> 00:11:47,250
+بتعرفواتقطير لقطران الفحم الكول تار وما إلى ذلك
+
+138
+00:11:47,250 --> 00:11:52,990
+فصل سائل هذا السائل لجأ أن ال boiling point له 80
+
+139
+00:11:52,990 --> 00:12:01,170
+.81% الآن عمل الصيغة ال molecular formula له لجأ
+
+140
+00:12:01,170 --> 00:12:04,910
+أو قبل ذلك عمل ال empirical formula ال empirical
+
+141
+00:12:04,910 --> 00:12:12,430
+formula متذكرينها أصغر صيغة أصغر نسبة لجها CHالـ
+
+142
+00:12:12,430 --> 00:12:16,550
+CH هلومة C2H2C3H3C4H4
+
+143
+00:12:16,550 --> 00:12:21,330
+في تحاليل معينة عملوا ال molecular formula اللي هي
+
+144
+00:12:21,330 --> 00:12:26,530
+تمثل العدد الحقيقي مش النسبة مش أبسط نسبة ال
+
+145
+00:12:26,530 --> 00:12:33,160
+empirical formulaأبسط نسبة ممكن تكون مضروبة بتنين
+
+146
+00:12:33,160 --> 00:12:34,900
+او تلاتة او اربع او خمس واطفال
+
+147
+00:12:46,610 --> 00:12:54,650
+C6H6 فثبت عنده الآن ان البنزين عبارة عن 6 ذرات
+
+148
+00:12:54,650 --> 00:12:59,470
+كربون و 6 ذرات هيدروجين هذه اللي بنسميها احنا ايش
+
+149
+00:12:59,470 --> 00:13:04,410
+molecular formula دائما و ابدا السؤال الاصعب في
+
+150
+00:13:04,410 --> 00:13:08,290
+الكيميا ان 6 ذرات كربون و 6 ذرات هيدروجين كيف
+
+151
+00:13:08,290 --> 00:13:14,070
+بإمكاننا نحطهم يعملوا شكلفيه قلوم كتير structural
+
+152
+00:13:14,070 --> 00:13:17,030
+formulas .. ال structural formula اللي هي بنسميها
+
+153
+00:13:17,030 --> 00:13:21,310
+الصيغة الاش .. الصيغة التفصيلية أو الصيغة البنائية
+
+154
+00:13:22,220 --> 00:13:27,600
+الصيغة البنائية صعبة جدا إيجادها و بحاجة إلى كثير
+
+155
+00:13:27,600 --> 00:13:32,780
+من التجارب و إلى كثير من العلم الآن إذا تخيلتوا بس
+
+156
+00:13:32,780 --> 00:13:38,120
+أنه اكتشف البنزين ك molecular formula في ال 1824
+
+157
+00:13:38,120 --> 00:13:46,700
+عشان يقولوا بعد هيك أن ال C6H6 موجودين بهذا الشكل
+
+158
+00:13:46,700 --> 00:14:00,170
+كم لازمهم شغلوا بحثكم شهر؟ كم سنة؟ أربعين سنة من
+
+159
+00:14:00,170 --> 00:14:03,570
+الف و تمانمية تقريبا و خمسة و عشرين كان الاكتشاف
+
+160
+00:14:03,570 --> 00:14:08,690
+للألف و تمانمية و خمسة و ستين بس عشان اقول ست ذرات
+
+161
+00:14:08,690 --> 00:14:14,720
+كربون و ست هيدروجين كيف موجودين يصل لهذا الشكلتشوف
+
+162
+00:14:14,720 --> 00:14:20,120
+قدش العلم بياخد وجهته ..الان طالما ان لزمني اربعين
+
+163
+00:14:20,120 --> 00:14:24,620
+سنة و انا اعمل تجارب لحد ما اصل للشكل اللي مازال
+
+164
+00:14:24,620 --> 00:14:29,120
+مقبول و بنقدر نعتبره صحيح في زماننا .. اذا بين بين
+
+165
+00:14:29,120 --> 00:14:35,980
+المفروض نعمله كتير شغل غلطواضح؟ بيوم من الأيام
+
+166
+00:14:35,980 --> 00:14:39,300
+الشغل الغلط اللي عملوه كان موجود في الكتب وكان
+
+167
+00:14:39,300 --> 00:14:44,760
+يتدرس وكانوا يحلفوا عليه يمين عشانك الناس ما تغترش
+
+168
+00:14:44,760 --> 00:14:49,740
+أول ما تجيها فكرة أنها الفكرة اللي هي جاياها أنهي
+
+169
+00:14:49,740 --> 00:14:58,050
+الصح بعد عشر سنين ممكن تكتشف أن الفكرةخطأ، مظبوط
+
+170
+00:14:58,050 --> 00:15:01,890
+ولا لا؟ يعني مناسق مفاوضات Camp David اللي بدهم
+
+171
+00:15:01,890 --> 00:15:05,670
+يحطوه الآن وزير خارجية في مصر، امبارح شو بيقول؟
+
+172
+00:15:05,670 --> 00:15:08,110
+والله انا اكتشفت ان Camp David بالنسبة لنا
+
+173
+00:15:08,110 --> 00:15:11,910
+المصريين كويسة، لكن بالنسبة للفلسطينيين دمرت
+
+174
+00:15:11,910 --> 00:15:17,630
+القضية الفلسطينية، الان وقت ايش اكتشف الكلام؟بعد
+
+175
+00:15:17,630 --> 00:15:21,530
+سنين بعد ما صارت اسرائيل تلعب فينا ومافيش اي حد
+
+176
+00:15:21,530 --> 00:15:25,690
+يدافع عنها بعد ما عزلت القضية عن كل العرب فشيء
+
+177
+00:15:25,690 --> 00:15:30,410
+اليوم انت بتعتقده صح بكرا بيصير غلط من الأشكال
+
+178
+00:15:30,410 --> 00:15:34,790
+اللي كانت موجودة قبل شكل البنزين انا جبتلكوا بعض
+
+179
+00:15:34,790 --> 00:15:38,810
+الأشكال وإذا انتوا بتتطلعوا على هذه الأشكال ويلها
+
+180
+00:15:38,810 --> 00:15:41,390
+أسماء ودُرستة في يوم من الأيام مابتناش ندخل فيها
+
+181
+00:15:41,390 --> 00:15:44,010
+بالتفصيل احنا في النهاية اصفين هذه البنزين set
+
+182
+00:15:44,010 --> 00:15:49,290
+carbonate و set hydrogenateانتهينا منه لكن بس عشان
+
+183
+00:15:49,290 --> 00:15:54,270
+تشوفوا كيف منطق العلم هذا الشكل مثلا الشكل 45
+
+184
+00:15:54,270 --> 00:15:58,990
+بيسموه ديوار بنزين نسبة للعالم ديوار لو بتطلعوا
+
+185
+00:15:58,990 --> 00:16:01,890
+carbon اتنين تلاتة اربعة خمسة ستة ده زي صفحة
+
+186
+00:16:01,890 --> 00:16:06,290
+الكتاب المفتوح او زي ال laptop المفتوح هاي موقع
+
+187
+00:16:06,290 --> 00:16:09,490
+اتنين تلاتة اربعة خمسة ستة حطوها هيدروجين هيدروجين
+
+188
+00:16:09,490 --> 00:16:12,190
+هيدروجين هيدروجين هيدروجين هيدروجين و رابطة في
+
+189
+00:16:12,190 --> 00:16:17,980
+النصزي الكتاب المفتوح هذا كان مقترح للبنزين عمله
+
+190
+00:16:17,980 --> 00:16:23,840
+العالم ديوار العالم مشهورين هدول الأسماء في العلوم
+
+191
+00:16:23,840 --> 00:16:32,700
+هوكل عمل شكل زي هيك واضح؟ عالم تانيلادنبورغ عمل
+
+192
+00:16:32,700 --> 00:16:37,820
+البرزمان زي المنشورة بتعرفوا البرزمان سموه إيش
+
+193
+00:16:37,820 --> 00:16:45,040
+برزمان هذا لادنبورغ ألماني ناس قالوا لأ هو عبارة
+
+194
+00:16:45,040 --> 00:16:50,160
+عن سايكلوبروبين ومربوط برابط أحد يعدوا carbon 2 3
+
+195
+00:16:50,160 --> 00:16:54,760
+4 5 6 و هنا بيجي هيدروجين هيدروجين هيدروجين
+
+196
+00:16:54,760 --> 00:16:59,500
+هيدروجين هيدروجين هيدروجين هاي C6H6واضح؟ شكل تاني
+
+197
+00:16:59,500 --> 00:17:04,820
+كان بالطريقة اللى موجودة هناك 49 Klaus و هدولة
+
+198
+00:17:04,820 --> 00:17:09,700
+كانوا علماء اكبر فى النهاية بس اللى ثبت ان الشكل
+
+199
+00:17:09,700 --> 00:17:15,400
+الصحيح هو الشكل اللى عمله العالم Kekuli الآن
+
+200
+00:17:15,400 --> 00:17:19,800
+لاحظوا هنا انتوا جاعدين بتخلطوا الكيميا بالهندسة
+
+201
+00:17:21,070 --> 00:17:25,930
+الان إنتوا إيش بتخلطوا؟ الكيميا بالهندسة و قد
+
+202
+00:17:25,930 --> 00:17:30,310
+تستغربوا إنه كيكولي .. كيكولي هذا اللي حاطين صورته
+
+203
+00:17:30,310 --> 00:17:36,490
+كان مهندس معماري بعد ما خلص الهندسة المعمارية
+
+204
+00:17:36,490 --> 00:17:40,430
+حولوا درس كيميا زي ما اليوم كتير بيعملوا من
+
+205
+00:17:40,430 --> 00:17:44,150
+المهندسات المعماريات لما بيلاقوا الشغل كلهم بيجوا
+
+206
+00:17:44,150 --> 00:17:47,710
+بيندرسوا من أول و جديد كيميا و فيزيا و تعليم أساسي
+
+207
+00:17:48,240 --> 00:17:53,740
+عدد كبير جدا واضح كيكولي لأنه أحب الكيميا و
+
+208
+00:17:53,740 --> 00:17:58,200
+الكيميا كلها structures و كلها هندسة بناء رباني كل
+
+209
+00:17:58,200 --> 00:18:01,280
+الأشكال اللي بتشوفوها انتوا لاحظوا هي عبارة عن
+
+210
+00:18:01,280 --> 00:18:05,720
+فعلا إيش؟ Geometry مش احنا بندرس Geometry او هندسة
+
+211
+00:18:05,720 --> 00:18:10,800
+فكيكولي كان مهندس معماري حول إلى كيميائي و هو اللي
+
+212
+00:18:10,800 --> 00:18:18,290
+اقترح الشكل هذا تبع البنزينواضح؟ هو ليش اخترح شكل
+
+213
+00:18:18,290 --> 00:18:22,290
+البنزين؟
+
+214
+00:18:22,290 --> 00:18:27,570
+لأ لأ، وش بيعرفوا من التركيبة؟ احنا بنستنتج، احنا
+
+215
+00:18:27,570 --> 00:18:30,910
+لا شايفين ذرات ولا .. ولا ما يحزنون، هذه أشكال
+
+216
+00:18:30,910 --> 00:18:34,070
+استنتاجية على الأقل في المراحل الأولى، الآن بعد ال
+
+217
+00:18:34,070 --> 00:18:38,410
+X-ray صارت أشكال بإمكاننا نشوفها أو نقدرها ..
+
+218
+00:18:38,410 --> 00:18:43,130
+نقدرها باستعمال أشعة X، فذاك الوقت كنا بنستنتج
+
+219
+00:18:43,130 --> 00:18:47,470
+الأشكاليعني الكيميا مثلا ضالت مش قادرة تفهم شكل
+
+220
+00:18:47,470 --> 00:18:52,730
+الميثين اللي هو أبسط شكل للـ 1873 لبعد شكل البنزين
+
+221
+00:18:52,730 --> 00:18:56,950
+لما اكتشفوا شكل الميثين بعد ما اكتشفوا شكل الميثين
+
+222
+00:18:56,950 --> 00:18:59,550
+اللي حكينالكوا هي التتراهيدرال الكيميا اتطورت قبل
+
+223
+00:18:59,550 --> 00:19:04,030
+ايه ماكانوش قادرين يفهموها واضح؟ فالخلاصة بدأ شوية
+
+224
+00:19:04,030 --> 00:19:08,890
+عقول هندسية ربما مرة حكينالكوا في الالوتروبز على
+
+225
+00:19:08,890 --> 00:19:14,200
+الكربون وقلنالكوا في كرة الكربون 60كيف لما يكون
+
+226
+00:19:14,200 --> 00:19:17,780
+عندى ستين ذرة كربون يكونوا فى كرة بعد ما اكتشفوا
+
+227
+00:19:17,780 --> 00:19:21,920
+ان عندي جزء مكون من ستين ذرة كربون اتغلبوا جدا فى
+
+228
+00:19:21,920 --> 00:19:28,540
+موضوعه فى النهاية اللى اتدخله حسب الشكل برضه مهندس
+
+229
+00:19:28,540 --> 00:19:31,700
+معمارى book monster fuller فصاروا يسموا المركبات
+
+230
+00:19:31,700 --> 00:19:35,580
+fullerines fullerines واخدوا عليها جائزة نوبل مش
+
+231
+00:19:35,580 --> 00:19:41,600
+زمان فى 1987 يعني سنة من ولدته جابل؟
+
+232
+00:19:41,600 --> 00:19:42,900
+ماشي
+
+233
+00:19:45,110 --> 00:19:50,970
+الان قدرين تشوفوا انه البنزين resonance structure
+
+234
+00:19:50,970 --> 00:19:54,250
+و لانه resonance structures بشكل عام مرات بيحطوا
+
+235
+00:19:54,250 --> 00:19:59,450
+الحلقة واضحة ال orbitals تبعت البنزين ال orbitals
+
+236
+00:19:59,450 --> 00:20:04,250
+تبعت البنزين طبعا هاي بعض ال orbitals انا حاططلكوا
+
+237
+00:20:04,250 --> 00:20:10,050
+ياها هي عبارة عن بي orbitals عمودية على المستوى
+
+238
+00:20:10,050 --> 00:20:16,550
+الان هذا بيعملبايبوند من الجهتين هذا بتعمل بايبوند
+
+239
+00:20:16,550 --> 00:20:19,350
+من الجهتين والاخرانيات الهان بيعملوا بايبوند من
+
+240
+00:20:19,350 --> 00:20:22,970
+الجهتين بناء على ذلك إيش بيصير فوق البنزين و تحت
+
+241
+00:20:22,970 --> 00:20:28,290
+البنزين electronic cloud حركة إلكترونية واضح و
+
+242
+00:20:28,290 --> 00:20:31,630
+لأنه كلها حركة إلكترونية يعني هل ال بايبوند هل هي
+
+243
+00:20:31,630 --> 00:20:36,210
+هان ولا هانمش بعرف، في حركة إلكترونية و لذلك إحنا
+
+244
+00:20:36,210 --> 00:20:40,630
+إيجي الاقتراح اللي عندنا أنه ال bond order واحد و
+
+245
+00:20:40,630 --> 00:20:46,330
+نص و أنه كل الروابط متساوين و مافيش عنده single و
+
+246
+00:20:46,330 --> 00:20:51,330
+double bonds لكن في عنده resonance structure زي ما
+
+247
+00:20:51,330 --> 00:20:55,830
+أنتوا شايفين هنا إذا ال B orbitals بشكل عام كيف
+
+248
+00:20:55,830 --> 00:21:02,170
+بيكونوا عموديات على مستوى الجزء و هم اللي بيعملوا
+
+249
+00:21:04,320 --> 00:21:08,380
+الـ double bonds هم اللي بيعملوا ال buy bonds على
+
+250
+00:21:08,380 --> 00:21:18,820
+أي الأشكال الآن نيجي لتسمية مراكبات البنزين عبر
+
+251
+00:21:18,820 --> 00:21:22,800
+التاريخ البنزين كتير فيه مراكبات منه من مشتقاته
+
+252
+00:21:22,800 --> 00:21:26,620
+إلى استعمالات و تطبيقات مهمة ولذلك في بعض
+
+253
+00:21:26,620 --> 00:21:32,320
+المراكبات أخدت أسماءشهرة قبل ما نعمل نظام
+
+254
+00:21:32,320 --> 00:21:37,040
+systematic يعني نظام تحليلي من خلاله نقدر نسم
+
+255
+00:21:37,040 --> 00:21:41,960
+المراكبات هذه المراكبات اللي أخدت أسماء شهرة
+
+256
+00:21:41,960 --> 00:21:46,680
+موجودة على اللوح أبسط مراكب زي ما أنتوا شايفين أي
+
+257
+00:21:46,680 --> 00:21:51,740
+واحد فيهم البنزين البنزين بعد البنزين اللي عليه
+
+258
+00:21:51,740 --> 00:21:59,250
+مثل طلوين اللي عليه isopropylاكيومين اكيومين
+
+259
+00:21:59,250 --> 00:22:04,410
+بيذكركوا بإيش؟ بالكمون هذا المكون الأساسي للكمون
+
+260
+00:22:04,410 --> 00:22:10,250
+اكيومين واضح؟ مكون الكمون اللي متصل فيه double
+
+261
+00:22:10,250 --> 00:22:14,610
+bond أخدناه الاستايرين اللي بيعمل ال polymer اللي
+
+262
+00:22:14,610 --> 00:22:18,590
+اسمه ال polystyrene اللي بيعمل ال plastic ال
+
+263
+00:22:18,590 --> 00:22:23,850
+polystyrene اللي عليه OH الفينول أخدناه قولنا
+
+264
+00:22:23,850 --> 00:22:31,370
+بيفضل الشكلEinol في double bond جنبها OH واضح؟
+
+265
+00:22:31,370 --> 00:22:38,470
+اللي فيه O مثل بيسموه Anisole .. Anisole اللي فيه
+
+266
+00:22:38,470 --> 00:22:47,090
+مجموعة Aldehydeبنزالدهيد اللي في هذه المجموعة ال C
+
+267
+00:22:47,090 --> 00:22:51,950
+double bond OCH3 هذه المجموعة بالكيميا بنسميها
+
+268
+00:22:51,950 --> 00:22:57,370
+acetyl احنا هذول مجمعتين كمجموعات لوحدهم ال C
+
+269
+00:22:57,370 --> 00:23:04,710
+double bond OH كمجموعة لوحدها اسمها formalالمجموعة
+
+270
+00:23:04,710 --> 00:23:09,430
+ايش اسمها؟ Formula group وهذه المجموعة C double
+
+271
+00:23:09,430 --> 00:23:18,390
+bond O CH3 اسمها? Acetel و مرات ايش بيختصروها؟ AC
+
+272
+00:23:18,390 --> 00:23:23,510
+فهذا المركب اللي في مجموعة ال formula كله اسمه
+
+273
+00:23:25,040 --> 00:23:31,080
+بنزالديهيد اللي فيه مجموعة الاسيتل أسيتوفينون ..
+
+274
+00:23:31,080 --> 00:23:39,560
+أسيتوفينون اللي فيه حامض COOH .. COOH بنزوك أسيت
+
+275
+00:23:39,910 --> 00:23:46,270
+اللي فيه nh2 أنيلين okay طيب السؤال يا ترى هدولة
+
+276
+00:23:46,270 --> 00:23:51,870
+مطلوب مننا نحفظهم أكيد هدول مركبات أساسية ما
+
+277
+00:23:51,870 --> 00:23:58,290
+بيستغنى عنهم اللي بدرسوا الكيميا الآن بعد ذلك
+
+278
+00:23:58,290 --> 00:24:03,380
+بنستعمل طريقة الاشتقاءIobac method of nomenclature
+
+279
+00:24:03,380 --> 00:24:10,240
+اشتغال مثلا لو عند بروم بنسمي المركب بروم وبنزين
+
+280
+00:24:10,240 --> 00:24:15,240
+لو عندنا نيترو بنزين نيترو بنزين لو عندها دي مثلا
+
+281
+00:24:15,240 --> 00:24:23,380
+CH2 CH3 إتل إتل بنزين لو عندنا بروبل CH2 CH2 CH3
+
+282
+00:24:23,380 --> 00:24:27,120
+بروبل بنزين لو عندنا tertiary butyl اللي عامله زي
+
+283
+00:24:27,120 --> 00:24:27,860
+الصليب
+
+284
+00:24:34,990 --> 00:24:40,530
+Tertiarybutylbenzene، واضح؟ فهم عليك، هذا الإسم
+
+285
+00:24:40,530 --> 00:24:44,790
+سبق، هذا إسم .. إسم شهرة، فكان المركب مفصول وما
+
+286
+00:24:44,790 --> 00:24:48,250
+أخد إسم شهرة قبل ما نحطها الكلام، فما بيسموهش مثل
+
+287
+00:24:48,250 --> 00:24:51,590
+بنزين، يعني لو بدك تتطلع على كل كتب ال organ ال
+
+288
+00:24:51,590 --> 00:24:55,630
+chemistry بيقوله شلة طلوين، كمنطق أنت بدك تقول في
+
+289
+00:24:55,630 --> 00:25:00,060
+الآخر مثل بنزين، مظبوط ولا لا؟صحيح و أنا كان
+
+290
+00:25:00,060 --> 00:25:04,640
+بإمكاني أقول amino benzene لكن أخد اسم ال aniline
+
+291
+00:25:04,640 --> 00:25:10,020
+خلاص هذه أسماء common names و ال common names سبقت
+
+292
+00:25:10,020 --> 00:25:17,200
+النظام اللي هو الاشتقاقي فبتضل .. بتضل عند الناس
+
+293
+00:25:17,200 --> 00:25:22,260
+أسماء إيش ال common names يعني مثلا إحنا في غزة
+
+294
+00:25:22,260 --> 00:25:27,490
+ممكن نقول بدنا نروح على السدرةكل الناس بتعرف
+
+295
+00:25:27,490 --> 00:25:33,030
+السدرة لأن عمرها صار أكم مت ولا ألف سنة، الآن يا
+
+296
+00:25:33,030 --> 00:25:38,210
+تورا الشارعين اللي هناك مالهم مش اسم، إلهم اسم لو
+
+297
+00:25:38,210 --> 00:25:41,290
+بدكوا تروحوا تشوفوا، طب مين بيعرفهم باسم الشوارع
+
+298
+00:25:41,290 --> 00:25:44,890
+بتاعتهم؟
+
+299
+00:25:44,890 --> 00:25:50,050
+إلهم أسماء لكن ماحد بيعرفهم باسمهم ال common name
+
+300
+00:25:50,050 --> 00:25:56,390
+سبقاللي هو الاسم الاشتقاقي واضح؟ الكم و النعم سبق
+
+301
+00:25:56,390 --> 00:25:59,630
+الاسم الاشتقاقي مثلا إحنا عند كل البلد تقولوله
+
+302
+00:25:59,630 --> 00:26:04,050
+بدنا نركب ع شرع المشتل في النصر بركبكوا اجرؤش
+
+303
+00:26:04,050 --> 00:26:09,310
+مكتوب ع الشرع بيتلاقوهش مكتوب شرع المشتل واضح؟
+
+304
+00:26:09,310 --> 00:26:13,230
+فالكم و النعم لما يسبق خلاص بياخد أولوية بتصير
+
+305
+00:26:13,230 --> 00:26:19,290
+تتسمى فيه وإلا كان ممكن سؤالك انسهله أكتر هذا شو
+
+306
+00:26:19,290 --> 00:26:24,400
+أخد اسم؟بنزين .. طب سموليه اشتقاقيا ..
+
+307
+00:26:24,400 --> 00:26:29,580
+Cyclohexatriene
+
+308
+00:26:29,580 --> 00:26:34,920
+.. مش Cyclohexane
+
+309
+00:26:34,920 --> 00:26:40,000
+اكمين .. اتراين .. Cyclohexatriene .. عمركوا
+
+310
+00:26:40,000 --> 00:26:45,040
+سمعتوا حد بيقول عنه .. Cyclohexatriene .. بنزين ..
+
+311
+00:26:45,040 --> 00:26:49,240
+واضح؟ فالاسم الاشتقاقي سبق .. عفوا .. ال common
+
+312
+00:26:49,240 --> 00:26:55,470
+noun سبق خلاصالان لما بصير في عندى .. لما بصير في
+
+313
+00:26:55,470 --> 00:27:01,790
+عندى اكثر من substituent على الجزاء المفروض ان انا
+
+314
+00:27:01,790 --> 00:27:09,110
+بصير بدي استعمل نظامترقيم، نظام ترقيم عشان أسميهم
+
+315
+00:27:09,110 --> 00:27:13,750
+أو نظام حروف أحيانا اللي حكينالكوا ياه قبل شوية
+
+316
+00:27:13,750 --> 00:27:18,910
+قولنالكوا إن إذا اعتبرنا أنه أول موضع أساس أيا كان
+
+317
+00:27:18,910 --> 00:27:23,590
+اللي بيكون بالنسبة له على موضع اتنين وعلى موضع
+
+318
+00:27:23,590 --> 00:27:30,570
+تلاتة وعلى موضع أربعة قارة بس رجاء في ناس يعني من
+
+319
+00:27:30,570 --> 00:27:34,470
+تجربتنا رغم إن الواحد بيحبش يقول هالكلامقدام
+
+320
+00:27:34,470 --> 00:27:40,730
+الكاميرا بس مش مشكلة من تجربتنا في ناس بتخيل انه
+
+321
+00:27:40,730 --> 00:27:45,970
+انا لازم اكون ماسك الجزء زي هيك و هذا ال ortho
+
+322
+00:27:45,970 --> 00:27:50,710
+position لفوق الاصل و ال ortho موجود بهالشكل لأ
+
+323
+00:27:50,710 --> 00:27:54,470
+احنا مابنقولش هذا الكلام احنا بنقول انه اذا في
+
+324
+00:27:54,470 --> 00:28:01,940
+عندى substituent أولى اللي جنبها بتكون orthoواضح؟
+
+325
+00:28:01,940 --> 00:28:06,640
+الآن لو أنا مش ماسك الجزء بهذه الهيئة، ماسكه بهذه
+
+326
+00:28:06,640 --> 00:28:12,460
+الهيئة، هذا الموقع إيش يعتبر؟ برضه Ortho بالنسبة
+
+327
+00:28:12,460 --> 00:28:16,500
+لهذه، إذا ال Ortho هو موقع اتنين، طب لو ماسكه بهذه
+
+328
+00:28:16,500 --> 00:28:21,360
+الهيئة، يعني هذه .. هذه الصفرةبرضه Ortho .. لو
+
+329
+00:28:21,360 --> 00:28:24,260
+ماسكوا هيك .. برضه Ortho .. لو ماسكوا هيك .. برضه
+
+330
+00:28:24,260 --> 00:28:28,540
+Ortho .. فال Ortho هو الموقع المجاور .. في ناس
+
+331
+00:28:28,540 --> 00:28:34,360
+خلاص مصرين انه بدهم يتخيلوا ان هذا المكان هو Ortho
+
+332
+00:28:34,360 --> 00:28:38,760
+.. بالتالي لو انا مسكت الجزء زي هيك .. لو انا مسكت
+
+333
+00:28:38,760 --> 00:28:41,620
+الجزء زي هيك و عندي substituent تحت .. محل ما انا
+
+334
+00:28:41,620 --> 00:28:46,620
+ماسكه .. و قلتلكوا هذا الموقع .. ايش بيكون ..
+
+335
+00:28:46,620 --> 00:28:52,620
+بيكون نيتا بالنسبة لي ..لأن واحد .. تين .. تلاتة
+
+336
+00:28:52,620 --> 00:28:59,660
+واضح؟ فكلمة Ortho و Meta و Para هي شغلة نسبية اللي
+
+337
+00:28:59,660 --> 00:29:03,640
+بيجي على موقع اتنين بسميه Ortho و اللي على موقع
+
+338
+00:29:03,640 --> 00:29:09,100
+تلاتة Meta اللي على موقع أربعة Para واضح؟ الان لو
+
+339
+00:29:09,100 --> 00:29:12,060
+الناس بدهم مش يكتبوا لا Ortho ولا Meta ولا Para
+
+340
+00:29:12,060 --> 00:29:19,480
+بدهم يكتبوا اتنين بيرايحوا حالهم واضح؟ بمعنىلو أنا
+
+341
+00:29:19,480 --> 00:29:25,080
+إجيت واطلعت على هذا المُركّب لاحظوا هذا المُركّب
+
+342
+00:29:25,080 --> 00:29:29,920
+إيش موجود فيه؟ ذرتين الكلور هدولة ذرتين الكلور لما
+
+343
+00:29:29,920 --> 00:29:34,960
+بدي أقول المُركّب dichlorobenzene كيف جايين
+
+344
+00:29:34,960 --> 00:29:39,720
+بالنسبة لبعض؟ Ortho إذا بقدر أنا أقول Ortho
+
+345
+00:29:39,720 --> 00:29:45,060
+dichlorobenzene طب لو بدي أستعمل الأرقام بقدر أقول
+
+346
+00:29:45,060 --> 00:29:52,530
+one twoDichlorobenzene فالأورتوا على موقع 1 و2
+
+347
+00:29:52,530 --> 00:29:57,930
+وانتوا Dichlorobenzene واضح؟ الآن خلّيني أعطيكم
+
+348
+00:29:57,930 --> 00:30:06,130
+مثل تسموه بطريقتين لو كان عندكم هنا CH3 وهنا عندكم
+
+349
+00:30:06,130 --> 00:30:13,670
+CL خلّيني نعتبر أنه الأساس في المركب الطلوين الآن
+
+350
+00:30:13,670 --> 00:30:19,710
+الطلوين على الموقعاتنين اتجاني ايش اكلورو شو بقدر
+
+351
+00:30:19,710 --> 00:30:26,590
+اسمي هذا اورثو اكلورو
+
+352
+00:30:26,590 --> 00:30:27,710
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+353
+00:30:27,710 --> 00:30:31,530
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+354
+00:30:31,530 --> 00:30:32,650
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+355
+00:30:32,650 --> 00:30:34,050
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+356
+00:30:34,050 --> 00:30:34,810
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+357
+00:30:34,810 --> 00:30:36,050
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+358
+00:30:36,050 --> 00:30:43,970
+اكلورو اكلورو اكلورو اكلورو اكلورو اكلورو
+
+359
+00:30:45,660 --> 00:30:50,620
+الان لو حطيت اكتر من Substituent بصير بستعمل بس
+
+360
+00:30:50,620 --> 00:30:55,340
+نظام الأرقام، يعني لو حطيت هنا Chlor و حطيت هنا
+
+361
+00:30:55,340 --> 00:30:59,320
+Brom و
+
+362
+00:30:59,320 --> 00:31:00,620
+بجانس بلد تلوين
+
+363
+00:31:03,520 --> 00:31:09,300
+تو كلوروم تلوين اذا
+
+364
+00:31:09,300 --> 00:31:15,320
+نقطة ابتداء في الترقيم عنده الكاربون اللي حاملة
+
+365
+00:31:15,320 --> 00:31:16,720
+الميثل
+
+366
+00:31:26,710 --> 00:31:32,150
+كان ممكن تسمه المركب orthodimethylbenzene
+
+367
+00:31:32,150 --> 00:31:38,990
+لكن ال dimethylbenzene أخد اسم شهرة Exilin ال
+
+368
+00:31:38,990 --> 00:31:42,130
+dimethylbenzene أخد اسم شهرة .. شو اسم الشهرة لل
+
+369
+00:31:42,130 --> 00:31:46,350
+dimethylbenzene؟ Exilin الآن لو التنتين مثل جنب
+
+370
+00:31:46,350 --> 00:31:51,640
+بعض، شو بنسميه؟Ortho إكزايلين لو إنهم على موقع
+
+371
+00:31:51,640 --> 00:31:57,000
+واحد لتلاتة لبعض ميتا إكزايلين لو على موقع واحد
+
+372
+00:31:57,000 --> 00:32:02,580
+لاربع على بعض بارا إكزايلين إذا الإكزايلين في عند
+
+373
+00:32:02,580 --> 00:32:09,640
+منه Ortho يعني مجمعتين مثل جنب بعض ميتا على موقع
+
+374
+00:32:09,640 --> 00:32:18,450
+واحد تلاتة بارا على موقع واحد وأربع واضح؟ طيبلو
+
+375
+00:32:18,450 --> 00:32:24,720
+كان في عندى الديهايد مثلا مع ال chlorineبدنا نعتبر
+
+376
+00:32:24,720 --> 00:32:29,860
+الأولوية للالدهايد لإن الجزاء ماخد اسم common مع
+
+377
+00:32:29,860 --> 00:32:36,020
+الالدهايد، شو اسمه؟ بنزالدهايد، بنزالدهايد، الان
+
+378
+00:32:36,020 --> 00:32:39,840
+لما تكون هذه number one، one, two, three, four،
+
+379
+00:32:39,840 --> 00:32:44,460
+إيش هتكون؟ Barachlorobenzaldehyde
+
+380
+00:32:44,460 --> 00:32:51,050
+أو 4-chlorobenzaldehydeواضح بارا كلورو بنزلديهيد
+
+381
+00:32:51,050 --> 00:32:58,290
+او four chlorobenzaldehyde الان
+
+382
+00:32:58,290 --> 00:33:07,530
+مرات بيصير الحقيقة عندكم مشكلة لما بيكون عندكم في
+
+383
+00:33:07,530 --> 00:33:14,800
+الجزاءلما بيكون عندكم في الجزاء مجموعتين واحدة
+
+384
+00:33:14,800 --> 00:33:20,580
+منهم بتكون تعتبرها الأصل و تبدأوا الترقيم من عندها
+
+385
+00:33:20,580 --> 00:33:24,640
+و التانية بتكون تقول عنها number two يعني أنيا بدي
+
+386
+00:33:24,640 --> 00:33:28,220
+أقول عنها number one أنيا بدي أقول عنها number two
+
+387
+00:33:28,220 --> 00:33:32,640
+يعني ببساطة لو بتكون تطلعوا مثلا على هذا الجزاء أو
+
+388
+00:33:32,640 --> 00:33:37,460
+على هذا الجزاء هل يا ترى بدي أقول onetwo three
+
+389
+00:33:37,460 --> 00:33:42,660
+four five six ولا بتقول one two three four five
+
+390
+00:33:42,660 --> 00:33:49,050
+six او لو عندي مثلا هنا مثل هذا الجزءهذا من
+
+391
+00:33:49,050 --> 00:33:53,810
+الجزيات اللي بتحير، لو أخدت البنزين مع الميثل، إله
+
+392
+00:33:53,810 --> 00:33:57,830
+اسم شهرة، شو اسم الشهرة تبعه؟ طولوين، طولوين، و لو
+
+393
+00:33:57,830 --> 00:34:01,810
+أخدت البنزين مع ال double bond، إله اسم شهرة؟
+
+394
+00:34:01,810 --> 00:34:04,770
+استيرين، استيرين، شو اسم الشهرة؟ استيرين، استيرين،
+
+395
+00:34:04,770 --> 00:34:05,090
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+396
+00:34:05,090 --> 00:34:05,130
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+397
+00:34:05,130 --> 00:34:06,830
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+398
+00:34:06,830 --> 00:34:09,950
+استيرين، استيرين، استيرين، استيرين، استيرين،
+
+399
+00:34:09,950 --> 00:34:13,260
+استيرين، استيرين، استيرين، استيرين، استيرينوالله
+
+400
+00:34:13,260 --> 00:34:18,920
+Toluene يحمل مجموعة .. إيش اسمها دي؟ CH2 double
+
+401
+00:34:18,920 --> 00:34:25,840
+bond CH أخدتولها اسم في
+
+402
+00:34:25,840 --> 00:34:34,600
+واحدة حكت شوية غلط إيش اسمها دي اللي حكت؟ Vinyl
+
+403
+00:34:34,600 --> 00:34:39,860
+سمعيني .. سمعيني .. بس نسألك شوية .. إيش اسمها؟
+
+404
+00:34:39,860 --> 00:34:49,380
+Vinylفنل مش فنل الان الفنل هي حلقة البنزين الفنل
+
+405
+00:34:49,380 --> 00:34:52,880
+فنل
+
+406
+00:34:52,880 --> 00:35:10,240
+فنل فنل فنل فنل فنل فنل فنل فنل فنل فنل
+
+407
+00:35:11,580 --> 00:35:16,520
+هي حلقة البنزين لأ حلقة البنزين نفسها اسمها phenyl
+
+408
+00:35:16,520 --> 00:35:20,960
+واضح؟
+
+409
+00:35:20,960 --> 00:35:24,580
+حلقة البنزين نفسها اسمها H-Phenyl يعني لو اجت على
+
+410
+00:35:24,580 --> 00:35:28,720
+مركب مثلا معين و كانت هي تعتبر substituent أو
+
+411
+00:35:28,720 --> 00:35:33,060
+group بنسميها H-Phenyl فالخلاصة انه مثل هذه الحالة
+
+412
+00:35:33,060 --> 00:35:36,740
+من الحالات اللي بتحير هل يا تورا المركب اللي عندى
+
+413
+00:35:36,740 --> 00:35:37,940
+بدي أنسبه
+
+414
+00:35:44,770 --> 00:35:49,770
+الحقيقة في عندنا قواعد بتقدروا تعملوها أو تعتبروها
+
+415
+00:35:49,770 --> 00:35:55,190
+كقواعد عامة بتعطي أولويات .. بتعطي أولويات الآن
+
+416
+00:35:55,190 --> 00:36:00,230
+الأولويات بتقول أعلى أولوية بأبدأ الترقيم من عنده
+
+417
+00:36:00,230 --> 00:36:06,050
+و باعتبرها الأساسي ال Easterأقل منها ال acid أقل
+
+418
+00:36:06,050 --> 00:36:10,110
+منها ال aldehyde بمعنى لو عندى acid و عندى
+
+419
+00:36:10,110 --> 00:36:14,810
+aldehyde بيه نمر واحد ال acid الأقل منه ال ketone
+
+420
+00:36:14,810 --> 00:36:21,890
+لو عندى aldehyde و ketone مين اللى له أولوية ال
+
+421
+00:36:21,890 --> 00:36:27,650
+aldehyde واضح؟ الأن اتطلع هذا الشكل هذا الشكل كتير
+
+422
+00:36:27,650 --> 00:36:34,530
+حلو في ال aldehydeوالكيتون و المركب كله مع الديهيد
+
+423
+00:36:34,530 --> 00:36:40,550
+شو اسمه؟ أخدنا Benzaldehyde و المركب تحت مع
+
+424
+00:36:40,550 --> 00:36:44,590
+الكيتون أسيتوفينون
+
+425
+00:36:45,460 --> 00:36:49,300
+قبل شوية أخدناه بالاسم أشور هل يا ترى بدي أنسب
+
+426
+00:36:49,300 --> 00:36:53,620
+المركب لل الديهايد ولا لل كيتون؟ لل الديهايد، إذا
+
+427
+00:36:53,620 --> 00:36:57,660
+بدي أقول هذه الأساس اللي عندى، هذا بنزالديهيد، من
+
+428
+00:36:57,660 --> 00:37:01,500
+وين نمر واحد افترق قيمة؟ من عند ال الديهايد، one,
+
+429
+00:37:01,700 --> 00:37:08,280
+two, three, four، الآن هذه كمجموعة إيش اسمها؟ C
+
+430
+00:37:08,280 --> 00:37:16,420
+double bond O C H3 بتصير مجموعة أسيتلواضح؟ فبصير 4
+
+431
+00:37:16,420 --> 00:37:22,720
+-acetyl أو paraacetyl benzaldehyde شوفتوا كيف؟
+
+432
+00:37:22,720 --> 00:37:26,240
+يعني لما التقى ال aldehyde و ال ketone الأولوية
+
+433
+00:37:26,240 --> 00:37:31,240
+لمين؟ لل aldehyde لو التقى ال ketone و ال alcohol
+
+434
+00:37:31,240 --> 00:37:35,420
+الأولوية لمين؟ ال ketone طبعا أكيد لو التقى ال
+
+435
+00:37:35,420 --> 00:37:40,900
+aldehyde و ال alcohol الأولوية لمين؟ لل aldehyde
+
+436
+00:37:40,900 --> 00:37:43,040
+لاحظوا مثلا هذا المثال
+
+437
+00:37:46,390 --> 00:37:53,630
+مع الالديهايد اسمه
+
+438
+00:37:53,630 --> 00:37:55,330
+benzaldehyde
+
+439
+00:37:58,060 --> 00:38:03,220
+فيلول أنا لإيش بدي أسميه؟ للالديهايد إذا أنا كأنه
+
+440
+00:38:03,220 --> 00:38:07,160
+هي الأساس اللي عندى هذا بنزالديهايد وهي موقع واحد
+
+441
+00:38:07,160 --> 00:38:11,520
+اتنين تلاتة أربعة هذا بنزالديهايد على موقع أربعة
+
+442
+00:38:11,520 --> 00:38:16,200
+إيش حامل؟ مجموعة ال OH مجموعة ال OH إذا ماكانش
+
+443
+00:38:16,200 --> 00:38:19,560
+منسوب إلى المركب شو تسمى؟ هيدروكسي
+
+444
+00:38:21,480 --> 00:38:28,640
+بارا هيدروكسي واضح بارا هيدروكسي واضح إذا كيف اللي
+
+445
+00:38:28,640 --> 00:38:35,750
+هو نظام التسمية ال alcohol أكتر منالأمين اللي هو
+
+446
+00:38:35,750 --> 00:38:40,590
+ال NH2، الأمين أكتر من الألكين اللي فيه double
+
+447
+00:38:40,590 --> 00:38:46,310
+bond، الألكين أكتر من الألكيل، والألكين أكتر من ال
+
+448
+00:38:46,310 --> 00:38:51,230
+halogen، في هيك الأمور، و ال halogens زيها كمان
+
+449
+00:38:51,230 --> 00:38:56,030
+بتيجي ال nitrateيعني منخفضة في الأولوية بناء على
+
+450
+00:38:56,030 --> 00:38:59,810
+ذلك لو بدنا نيجي نشوف كل هدولة طبعا هدولة لما
+
+451
+00:38:59,810 --> 00:39:03,350
+كانوا تنتين halogens بيخلوهم alphabetical اللي
+
+452
+00:39:03,350 --> 00:39:06,430
+بتكون alphabetical في الأول بيحطوه بالنسبة للثانية
+
+453
+00:39:06,430 --> 00:39:12,190
+okay الان هنا لما عندكم الكنو نيترو وين نمر واحد
+
+454
+00:39:12,190 --> 00:39:15,290
+الكنو الكنو الكنو الكنو الكنو الكنو الكنو الكنو
+
+455
+00:39:15,290 --> 00:39:16,890
+الكنو الكنو الكنو الكنو الكنو الكنو الكنو الكنو
+
+456
+00:39:16,890 --> 00:39:25,090
+الكنو الكنو الكنوطلوين إذاً هذه صارت ميتا نيترو
+
+457
+00:39:25,090 --> 00:39:35,010
+طلوين واضح هنا عندكم ألكين و ألكين لمن
+
+458
+00:39:35,010 --> 00:39:40,510
+الأولوية الألكين مركب الألكين شو اسمه استيرين هاي
+
+459
+00:39:40,510 --> 00:39:44,390
+واحد اتنين تلاتة بناخد أقل ترقيم ممكنش واحدة تيجي
+
+460
+00:39:44,390 --> 00:39:49,110
+ترقم واحد اتنين تلاتة اربعة خمسة تروح تكتب five
+
+461
+00:39:49,110 --> 00:39:55,500
+مثللحظة وقت رجعت ان اسمها مجموعة three مثل او ميتا
+
+462
+00:39:55,500 --> 00:40:01,320
+مثل واضح هنا التقى عندكم ال halogen مع ال OH هي ال
+
+463
+00:40:01,320 --> 00:40:07,110
+OH هي ال halogen من الاولويةمُركّب الواتش إيش
+
+464
+00:40:07,110 --> 00:40:13,670
+اسمه؟ فينول إذا بارا كلورو فينول بارا كلورو فينول
+
+465
+00:40:13,670 --> 00:40:18,590
+هذا المُركّب التقى فيه المثل مع تلت مجموعات نايترو
+
+466
+00:40:18,590 --> 00:40:23,210
+مين أعلى؟ الألكين ولا النايترو؟ الألكين مُركّب
+
+467
+00:40:23,210 --> 00:40:26,150
+الألكين لحاله طلوين
+
+468
+00:40:28,350 --> 00:40:35,850
+4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4
+
+469
+00:40:35,850 --> 00:40:41,610
+-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6
+
+470
+00:40:41,610 --> 00:40:45,290
+-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3-4-6-3
+
+471
+00:40:45,290 --> 00:40:52,790
+-6-3-4-6-3-4-6-3-4-6
+
+472
+00:40:52,790 --> 00:40:55,270
+-3-4-
+
+473
+00:40:57,880 --> 00:41:03,680
+هي الـ ketone و الحامض و ال acid ممتاز مين اللي
+
+474
+00:41:03,680 --> 00:41:07,900
+أولوية ال acid و لا ال ketone ال acid إذا ترقيم
+
+475
+00:41:07,900 --> 00:41:12,900
+أنا عند ال acid واحد اتنين تلاتة أربعة مركب ال
+
+476
+00:41:12,900 --> 00:41:19,420
+acid إيش اسمه بنزويك acid إيش بيحمل بنزويك acid
+
+477
+00:41:19,420 --> 00:41:24,460
+على موقع أربعة C double bond OCH3 هذه المجموعة
+
+478
+00:41:24,460 --> 00:41:33,860
+مااسمها AcetylOkay طيب هذا المثال مين تحكيلنا عنه
+
+479
+00:41:33,860 --> 00:41:43,460
+فضلوا ايش انتقام فيه OH OH نيترو مين الهولوية هذا
+
+480
+00:41:43,460 --> 00:41:52,690
+ايه فنولفينول ايش بيحمل؟ عتنين واربعة وستة تراي
+
+481
+00:41:52,690 --> 00:41:57,650
+نايترو فينول هذا المركب مشهور في ال biology ال 246
+
+482
+00:41:57,650 --> 00:42:03,650
+تراي نايترو فينول اللي اسم شهرة بيسموه بكريك أسد
+
+483
+00:42:03,650 --> 00:42:06,830
+حامض لونه أصفر غامق اللي بيشتغل فيكوا القواعي و
+
+484
+00:42:06,830 --> 00:42:13,210
+إيديه بيصيروا أصفر غامق جدا واضح؟ أصفر غامق جدا
+
+485
+00:42:13,210 --> 00:42:14,810
+طيب أخر شيء
+
+486
+00:42:25,730 --> 00:42:29,570
+اخر شي بنعطيكوايا بس بنأكدلكوا ان ال aromatic
+
+487
+00:42:29,570 --> 00:42:33,950
+compounds اللي هم تطبيقات كتيرة في الدنيا .. اللي
+
+488
+00:42:33,950 --> 00:42:39,870
+هم تطبيقات كتيرة في الدنيا مثلا هذا المركب
+
+489
+00:42:39,870 --> 00:42:43,910
+aromatic بنزين acetosilic acid هذا هو الدوة
+
+490
+00:42:43,910 --> 00:42:50,200
+المشهورة اسمه اسبيرينهذا الاسبيرين هو عبارة عن
+
+491
+00:42:50,200 --> 00:42:57,260
+حلقة بنزين هذا المركب الديهايد معه مثل مع OH هذا
+
+492
+00:42:57,260 --> 00:43:04,520
+المركب اللي هو الفانيلا الفانيلا تبعت الكيك هذا
+
+493
+00:43:04,520 --> 00:43:09,260
+المركب برضه في حلقة بنزين مع CH2 و بعدين ايزو
+
+494
+00:43:09,260 --> 00:43:15,060
+بروفين ايزو بيوتلي جروب و CH3 و COH هذا
+
+495
+00:43:15,060 --> 00:43:21,580
+الابوبروفينمار عليكم ال ibuprofen اللي ضد الصداع
+
+496
+00:43:21,580 --> 00:43:26,540
+اللي بيجيب أجل الصداع ال 600 ال algonol 600 اللي
+
+497
+00:43:26,540 --> 00:43:32,300
+بيكون هيك راسهم بده ينفجر واضح فاللي ماعندوش بس
+
+498
+00:43:32,300 --> 00:43:35,540
+بدخل على الكتاب بياخد ibuprofen أسبيرين إيش ما
+
+499
+00:43:35,540 --> 00:43:40,820
+بلزمكم خدوا منهم فهذه مركبات لها أهمية في التطبيق
+
+500
+00:43:40,820 --> 00:43:42,900
+المرة اللي جاي ان شاء الله بنحكي عن التفاعلات
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc.srt
new file mode 100644
index 0000000000000000000000000000000000000000..0747ceed11f88c395fb12d6ebaf0982362925283
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc.srt
@@ -0,0 +1,1408 @@
+1
+00:00:05,990 --> 00:00:12,290
+بنكمل في موضوع تفاعلات الـ alkenes تحديدًا تفاعلات
+
+2
+00:00:12,290 --> 00:00:17,570
+الإضافة تحديدًا تفاعلات الإضافة المرة الماضية
+
+3
+00:00:17,570 --> 00:00:22,150
+كملخص، كملخص على الكلام اللي حكيناه قلنا إنه إحنا
+
+4
+00:00:22,150 --> 00:00:26,390
+لما بندرس تفاعل إضافة الـ alkene بدنا نتطلع على
+
+5
+00:00:26,390 --> 00:00:30,450
+شغلتين بدنا نتطلع على الـ alkene symmetric ولا 
+
+6
+00:00:30,450 --> 00:00:32,750
+unsymmetric بدنا نتطلع على الـ reagent
+
+7
+00:00:40,180 --> 00:00:45,180
+نظريا نتوقع ناتجين نتوقع ناتجين
+
+8
+00:00:48,280 --> 00:00:52,960
+بتحكم التجربة يعني مرات بيطلع عندنا الناتج الأول
+
+9
+00:00:52,960 --> 00:00:55,760
+مرات بيطلع عندنا التاني ومرات بيطلع عندنا حقيقة
+
+10
+00:00:55,760 --> 00:01:02,120
+خليط من الناتج واضح؟ أخدنا بالتفصيل عملية إضافة
+
+11
+00:01:02,120 --> 00:01:07,640
+الميه بثلاث طرق ولاحظنا أن الثلاث طرق بيؤدوا إلى
+
+12
+00:01:07,640 --> 00:01:14,300
+نواتج مرات مختلفة الآن بعد إضافة الميه بناخد إضافة
+
+13
+00:01:14,300 --> 00:01:21,520
+الـHBr إضافة الـHBr مباشرة كلكم هتنتبهوا أن الـHBr
+
+14
+00:01:21,520 --> 00:01:29,740
+عبارة عن Unsymmetrical Reagent واضح؟ بناء على ذلك
+
+15
+00:01:29,740 --> 00:01:33,300
+هذا الـUnsymmetrical Reagent لو بضيف على ألكين
+
+16
+00:01:33,300 --> 00:01:39,640
+بسيط متماثل symmetrical ألكين المتوقع عنده ناتج
+
+17
+00:01:39,640 --> 00:01:44,100
+واحد فلو افترضنا مثلًا أن الـHBr بنضيفه على
+
+18
+00:01:45,370 --> 00:01:49,670
+الإيثالين والإضافة عادة تكون في وجود H+ في 
+
+19
+00:01:49,670 --> 00:01:52,630
+الخطوة الأولى الـ double bond بتتفاعل مع الـ H+
+
+20
+00:01:52,630 --> 00:01:57,670
+بتعمل رابطة هنا هيدي بدل ما هي CH2 صارت CH3 وبتكون
+
+21
+00:01:57,670 --> 00:02:03,330
+عندي كاربوكاتيون الكاربوكاتيون بتفاعل مع الـ Br
+
+22
+00:02:03,330 --> 00:02:11,050
+− بكمل إضافة HBr واضح؟ فعملية الإضافة أو الـ
+
+23
+00:02:11,050 --> 00:02:15,210
+mechanism of addition زيها زي إضافة إيش؟ الميه على
+
+24
+00:02:15,210 --> 00:02:20,330
+خطوتين الخطوة الأولى إضافة الـ H+ على ال
+
+25
+00:02:20,330 --> 00:02:24,570
+double bond تكوين Carbocation الخطوة الثانية اللي
+
+26
+00:02:24,570 --> 00:02:27,850
+هو تفاعل الـ negative ion مع الـ Carbocation
+
+27
+00:02:27,850 --> 00:02:34,230
+واستكمال الإضافة الآن لو كان عندي الالكين un
+
+28
+00:02:34,230 --> 00:02:38,690
+-symmetrical زي البروبين على سبيل المثال لاحظوا
+
+29
+00:02:38,690 --> 00:02:41,870
+هذا الكربون حامل 2 هيدروجين زي هذا الكربون حامل 1
+
+30
+00:02:41,870 --> 00:02:49,050
+هيدروجين وبتيجي H+ تتفاعل لاحظوا أن الناتج
+
+31
+00:02:49,050 --> 00:02:53,010
+اللي عندنا هو عبارة عن ناتج Markovnikov addition
+
+32
+00:02:53,010 --> 00:02:59,510
+إذا إضافة الـHBr في وجود الحامض في وجود الـH+
+
+33
+00:02:59,510 --> 00:03:04,410
+الناتج تبع الإضافة إيش Markovnikov addition بمعنى
+
+34
+00:03:04,410 --> 00:03:08,930
+أن الهيدروجين بتيجي هنا والـ Br بتيجي هنا ملاحظين
+
+35
+00:03:08,930 --> 00:03:14,820
+إنتوا هي الجزئين هي الهيدروجين وهي الـ Br هذه عبارة
+
+36
+00:03:14,820 --> 00:03:20,880
+عن Markovnikov's addition واضح تمامًا لكموا إيش معنى
+
+37
+00:03:20,880 --> 00:03:23,780
+Markovnikov's addition الهيدروجين إجت على اللي حمل
+
+38
+00:03:23,780 --> 00:03:31,560
+الهيدروجين أكثر والـ Br بتكمل التفاعل الآن بالنسبة
+
+39
+00:03:31,560 --> 00:03:36,360
+لـ الـ mechanism of this reaction تمامًا زي الـ
+
+40
+00:03:36,360 --> 00:03:40,940
+mechanism of addition of water Un-symmetrical
+
+41
+00:03:40,940 --> 00:03:45,320
+alkene بمعنى لو أنا تخيلت أنه في عندي هذا الـ Un
+
+42
+00:03:45,320 --> 00:03:48,380
+-symmetrical alkene بندفعله ماقاتش Br في وجود H
+
+43
+00:03:48,380 --> 00:03:52,060
++ اللي بده تتفاعل الاتفاق اللي هي الرابطة
+
+44
+00:03:52,060 --> 00:03:55,180
+الزوجية أو الإلكترونات بتاعتنا الرابطة الزوجية
+
+45
+00:03:55,180 --> 00:03:59,580
+لاحظوا هنا بوضحلكوا الكلام مرة ثانية هي الرابطة
+
+46
+00:03:59,580 --> 00:04:02,420
+الزوجية هي الإلكترونات اللي بندفعله ماقاتش +
+
+47
+00:04:02,420 --> 00:04:08,320
+الآن أما بده تتحرك الرابطة بهذا الشكل بمعنى أن الـ
+
+48
+00:04:08,320 --> 00:04:12,770
+H+ بيجي هنا وهذه الرابطة الزوجية الكاربوكاتيون
+
+49
+00:04:12,770 --> 00:04:15,790
+في هذه الحالة بيتكون هنا شو بيكون هذا الكاربو
+
+50
+00:04:15,790 --> 00:04:21,390
+كاتيون الـ primary ولا الـ secondary أو لو صار
+
+51
+00:04:21,390 --> 00:04:31,150
+التفاعل بطريقة ثانية لو صار
+
+52
+00:04:31,150 --> 00:04:36,030
+التفاعل بطريقة ثانية وين هتيجي الـ Br على هذا
+
+53
+00:04:36,030 --> 00:04:40,330
+الموقع وين هتيجي كوا الـ Br على هذا الموقع ..الآن
+
+54
+00:04:40,330 --> 00:04:45,510
+كاربوكاتيون بصير primary ..أنه المفضل؟ secondary
+
+55
+00:04:45,510 --> 00:04:51,410
+..واضح؟ بناء على ذلك هذا المسار كله ما بيصيرش واللي
+
+56
+00:04:51,410 --> 00:04:55,430
+بيصير عندنا المسار اللي بيكون عبر secondary
+
+57
+00:04:55,430 --> 00:05:00,630
+كاربوكاتيون بيكمل إضافة الـ Br هنا ..واضح؟ إذا لو
+
+58
+00:05:00,630 --> 00:05:02,790
+بنقولكوا إيش الـ mechanism؟
+
+59
+00:05:09,590 --> 00:05:14,410
+الخطوة الأولى هي إضافة الـ H+ وتكوين الـ more
+
+60
+00:05:14,410 --> 00:05:22,080
+stable كاربوكاتيون تحصيل حاصل إضافة الـ Br−
+
+61
+00:05:22,080 --> 00:05:26,080
+طبعًا اللي بيحدد الـ regiochemistry، معنى
+
+62
+00:05:26,080 --> 00:05:29,160
+regiochemistry، regio يعني من region، من منطقة، أن
+
+63
+00:05:29,160 --> 00:05:32,780
+وين التفاعل بيصير، هنا ولا هنا، وإيش الناتج بيكون، هل
+
+64
+00:05:32,780 --> 00:05:37,360
+هو ترى الخطوة الأولى ولا الخطوة الثانية؟ الخطوة
+
+65
+00:05:37,360 --> 00:05:41,620
+الأولى، الخطوة الثانية تابعة لهذه الـ Br هنا ما فيش
+
+66
+00:05:41,620 --> 00:05:44,860
+عنده خيار إلا يجيه، لكن الـ H لاحظوا الـ H كان
+
+67
+00:05:44,860 --> 00:05:50,830
+بالإمكان تيجي زي هيك أو زي هيك واضح الكلام فالتفاعل
+
+68
+00:05:50,830 --> 00:05:55,390
+هنا محكوب بالخطوة الأولى اللي بيؤدي لتكوين الـ more
+
+69
+00:05:55,390 --> 00:06:02,130
+stable carbocation هو الناتج النهائي هذا هو إضافة Markov
+
+70
+00:06:02,130 --> 00:06:07,570
+nikov إضافة حسب قاعدة Markovnikov طبعًا هذا الكلام
+
+71
+00:06:07,570 --> 00:06:14,510
+ليش بيصير بيحاولوا يوضحوا بمنحنى طاقة بنسميها هذا
+
+72
+00:06:14,510 --> 00:06:24,170
+المنحنى بيقول الآتي هاي الـ H+ بدها تضيف على الـ
+
+73
+00:06:24,170 --> 00:06:33,410
+double bond بإمكانها تتسلق قمة قصيرة عشان تكون الـ
+
+74
+00:06:33,410 --> 00:06:38,390
+more stable secondary carbocation أو قمة عالية
+
+75
+00:06:38,390 --> 00:06:44,010
+عشان تكون الـ less stable primary carbocation الآن
+
+76
+00:06:44,010 --> 00:06:47,030
+إنتوا لو تخيلتوا أن إنتوا في قاع واد وبدكوا
+
+77
+00:06:47,030 --> 00:06:49,630
+تطلعوا عندكوا احتمالين عشان تطلعوا من قاع هذا
+
+78
+00:06:49,630 --> 00:06:52,790
+الواد يا إما بدكوا تطلعوا على هضبة صغيرة يا بدكوا
+
+79
+00:06:52,790 --> 00:06:57,150
+تطلعوا على جبل عالي إيش اللي بتفضلوا؟ الهضبة الصغيرة
+
+80
+00:06:57,150 --> 00:07:01,490
+وكذلك الحال هنا أن الطاقة اللازمة بلزم طاقة
+
+81
+00:07:01,490 --> 00:07:05,550
+للتفاعل لازمة الطاقة اللازمة هنا الـ E-activation
+
+82
+00:07:05,550 --> 00:07:10,150
+لتكوين الـ secondary carbocation أقل من الطاقة
+
+83
+00:07:10,150 --> 00:07:14,950
+اللازمة لتكوين الـ primary carbocation ليش؟ لأن الـ
+
+84
+00:07:14,950 --> 00:07:18,590
+secondary carbocation is more stable than the
+
+85
+00:07:18,590 --> 00:07:23,190
+primary carbocation فالتفاعل بأي إتجاه حيصير؟ بهذا
+
+86
+00:07:23,190 --> 00:07:28,760
+الاتجاه واضح؟ التفاعل بيحصل في هذا الاتجاه
+
+87
+00:07:35,760 --> 00:07:41,660
+الـ HBr اللي بيضيف حسب قاعدة Markovnikov في وجود
+
+88
+00:07:41,660 --> 00:07:46,860
+حامض في وجود H+ لاحظوا أنه في وجود Reagent
+
+89
+00:07:46,860 --> 00:07:51,180
+ثاني غير الحامض بيضيف بطريقة ثانية بيضيف Anti
+
+90
+00:07:51,180 --> 00:07:55,140
+Markovnikov Addition إذا مرة ثانية لازم تكونوا
+
+91
+00:07:55,140 --> 00:07:59,760
+منتبهين لازم تكونوا منتبهين لما إحنا بيجي نسألكوا
+
+92
+00:07:59,760 --> 00:08:06,590
+نقولكوا هاي Double Bond HBr على شروط التفاعل إذا
+
+93
+00:08:06,590 --> 00:08:11,030
+كتبنا HBr مع H+، ماهو الناتج اللي بيكون في الطول؟
+
+94
+00:08:11,030 --> 00:08:17,410
+Markovnikov addition إذا كتبنا HBr مع مادة بنسميها
+
+95
+00:08:17,410 --> 00:08:23,020
+البروكسايد، بيضيف عكس قاعدة Markovnikov واضح؟ إذا
+
+96
+00:08:23,020 --> 00:08:27,720
+مرة ثانية عندي إيش؟ الاحتمالين في وجود الحامض حسب
+
+97
+00:08:27,720 --> 00:08:33,540
+قاعدة ماركوفنيكوف في وجود البروكسايد عكس قاعدة
+
+98
+00:08:33,540 --> 00:08:36,760
+ماركوفنيكوف عشان إيه؟ لو أنا بدي أطلع على هذا
+
+99
+00:08:36,760 --> 00:08:42,220
+المثال، هذا المثال هي طرفية double bond في two
+
+100
+00:08:42,220 --> 00:08:47,930
+carbons، أنية اللي عليها الـ hydrogen أكثر، هذه لو
+
+101
+00:08:47,930 --> 00:08:51,770
+هذا التفاعل قلت بدي أكمله HBr في وجود H+ وأين
+
+102
+00:08:51,770 --> 00:08:55,810
+بدي أحط الـ H؟ تحت الـ Br؟ فوق .. فوق .. فوق ..
+
+103
+00:08:55,810 --> 00:08:56,030
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+104
+00:08:56,030 --> 00:08:58,210
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+105
+00:08:58,210 --> 00:08:58,510
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+106
+00:08:58,510 --> 00:09:05,290
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+107
+00:09:05,290 --> 00:09:11,280
+فوق .. فوق الـ Br هذه الإضافة إضافة Markovnikov ولا
+
+108
+00:09:11,280 --> 00:09:14,840
+Anti Markovnikov Anti Markovnikov addition
+
+109
+00:09:14,840 --> 00:09:21,320
+واضح؟ إذا الإضافة في وجود البريكسايد is Anti
+
+110
+00:09:21,320 --> 00:09:28,500
+Markovnikov addition طبعًا ممكن نحاول نعمل تفسير،
+
+111
+00:09:28,500 --> 00:09:32,640
+ممكن نحاول نعمل تفسير، ليش الإضافة في وجود
+
+112
+00:09:32,640 --> 00:09:36,320
+البروكسايد under Markovnikov addition؟ بيروكسيد
+
+113
+00:09:36,320 --> 00:09:40,280
+يعني فوق أكسيد، إيش معناه فوق أكسيد؟ يعني فيه
+
+114
+00:09:40,280 --> 00:09:46,000
+زيادة في الأكسجين، شكل البروكسايد زي هيك ROOR
+
+115
+00:09:46,930 --> 00:09:51,490
+بدل ما يكون عندي ROR اللي هو الـ ether العادي بيكون
+
+116
+00:09:51,490 --> 00:09:57,650
+عندي كم أكسجين ROOR هذه الرابطة اللي بين الـ
+
+117
+00:09:57,650 --> 00:10:02,230
+oxygens اللي بين الـ oxygens في البروكسايد عبارة عن
+
+118
+00:10:02,230 --> 00:10:07,710
+weak bond بمعنى بقليل من الحرارة أو بضوء الشمس أو
+
+119
+00:10:07,710 --> 00:10:12,470
+من الـ UV light بتنكسر هذه الرابطة الرابطة عبارة عن
+
+120
+00:10:12,470 --> 00:10:17,990
+كم إلكترون الآن هدول الإلكترونين لو تخيلناهم زي
+
+121
+00:10:17,990 --> 00:10:25,070
+هيك أي رابطة ممكن تنكسر نوعين من الكسر ممكن تنكسر
+
+122
+00:10:25,070 --> 00:10:30,550
+نوعين من الكسر إما أن يكون الكسر متجانس وإما أن
+
+123
+00:10:30,550 --> 00:10:35,350
+يكون الكسر غير متجانس متجانس بمعنى أن هنا بدو ييجي
+
+124
+00:10:35,350 --> 00:10:39,970
+إلكترون وهنا بدو ييجي إلكترون، إذا هذا الكسر إيش
+
+125
+00:10:39,970 --> 00:10:47,110
+بنسميه؟ homo.. homolytic cleavage إيش يعني
+
+126
+00:10:47,110 --> 00:10:52,220
+homolytic cleavage؟ كسر متجانس هان إلكترون وهان
+
+127
+00:10:52,220 --> 00:10:56,320
+إلكترون ممكن بالتأكيد تنكسر بحيث أنه يكونوا
+
+128
+00:10:56,320 --> 00:11:00,340
+إلكترونين على جهة واحدة أو يطلع عيون سالب وهنا
+
+129
+00:11:00,340 --> 00:11:05,430
+ما فيش ولا إلكترون يطلع عيون موجب بالتأكيد هذا بيصير
+
+130
+00:11:05,430 --> 00:11:12,330
+أكثر heterolytic cleavage أكثر غير متجانس إذا دائمًا
+
+131
+00:11:12,330 --> 00:11:16,130
+الاثنين البساطة من ناحية الـ mathematics يا بتكون
+
+132
+00:11:16,130 --> 00:11:22,920
+واحد زائد واحد يا بتكون اثنين زائد صفر 1 زائد 1
+
+133
+00:11:22,920 --> 00:11:26,620
+يعني لو فيه اثنين شكل بدنا نوزعهم على اثنين كيف
+
+134
+00:11:26,620 --> 00:11:31,060
+بدنا نوزعهم؟ يا هذا بنعطي شكل وهذا شكل هاي توزيع
+
+135
+00:11:31,060 --> 00:11:37,980
+متجانس يا هذا اثنين شكل وهذا صفر وهذا توزيع غير
+
+136
+00:11:37,980 --> 00:11:42,540
+متجانس واضح؟ والنوعين من الكسر بالمناسبة موجودين
+
+137
+00:11:42,540 --> 00:11:49,200
+في الكيمياء لكن أن هو من ناحية الطاقة أسهل الكسر
+
+138
+00:11:49,200 --> 00:11:52,780
+المتجانس ولا غير المتجانس؟
+
+139
+00:11:54,690 --> 00:11:59,790
+طيب الآن إنتوا أي واحدة هي وأختها والاثنين شاكل
+
+140
+00:11:59,790 --> 00:12:03,590
+أن هو أقبل لنفسها أن شاكل هان وشاكل هان ولا
+
+141
+00:12:03,590 --> 00:12:09,290
+اثنين هان وصفر هان ربنا بيحبش الظلم مظبوط ولا لأ؟
+
+142
+00:12:09,290 --> 00:12:14,330
+إذا المتجانس أفضل عارفين ليش غير المتجانس مش مفضل؟
+
+143
+00:12:14,330 --> 00:12:18,730
+لأنه في النهاية هتخلوا اثنين − اللي بيكون حامل
+
+144
+00:12:18,730 --> 00:12:23,830
+إلكترونين بيصير − واللي حامل إلكترون + وبعدين
+
+145
+00:12:23,830 --> 00:12:29,910
+بتيجي تفصله + عن − الـ + عن الـ
+
+146
+00:12:29,910 --> 00:12:33,650
+− في الدنيا بتجاذب ولا بتفصل؟ طيب لما بدي
+
+147
+00:12:33,650 --> 00:12:39,070
+أفصله؟ بالظبط زي المغناطيسين الشمالي والجنوبي
+
+148
+00:12:39,070 --> 00:12:44,930
+الشمالي والجنوبي بتجاذبوا لما بتيجي تفصلوهم بتكون
+
+149
+00:12:44,930 --> 00:12:48,750
+طاقة، مظبوط ولا لا؟ والـ + والـ −، الأصل
+
+150
+00:12:48,750 --> 00:12:53,490
+فيهم التجاذب ولا إنهم يبعدوا عن بعض؟ اه إذا، بناءً
+
+151
+00:12:53,490 --> 00:12:56,830
+على ذلك، لو أنا بدي أعمل كسر غير متجانس في
+
+152
+00:12:56,830 --> 00:13:00,470
+الكيمياء، بدي أخلي إشي − وإشي + وأقعد أبعد
+
+153
+00:13:00,470 --> 00:13:03,750
++ عن −، بدي طاقة، إذا من ناحية طاقة، أنه
+
+154
+00:13:03,750 --> 00:13:08,700
+الأفضل؟ الكسر المتجانس هذا لا يعني أن الكسر غير
+
+155
+00:13:08,700 --> 00:13:12,800
+المتجانس ما بيصيرش بيصير وهناخد ظروف معينة ونتعلم
+
+156
+00:13:12,800 --> 00:13:18,460
+أشياء فيه كسر غير متجانس الشغلتين موجودين واضح؟
+
+157
+00:13:18,460 --> 00:13:23,790
+على أي حال لاحظوا المعنى هنا أنه في هذه الحالة
+
+158
+00:13:23,790 --> 00:13:29,110
+البروكسايد بيعمل homolytic cleavage بيعطينا اثنين
+
+159
+00:13:29,110 --> 00:13:34,450
+RO أي قطعة بتحمل إلكترون واحد شو اتفقنا نسميها
+
+160
+00:13:34,450 --> 00:13:42,080
+free radical جذر حر free radical واضح؟ ودائمًا اللي
+
+161
+00:13:42,080 --> 00:13:46,420
+حامل إلكترون واحد بيصير طماع يحمل كمان إلكترون
+
+162
+00:13:46,420 --> 00:13:50,300
+يعمل رابطة بناء على ذلك هذا الـ R Radical بيجي
+
+163
+00:13:50,300 --> 00:13:55,200
+يتفاعل مع الـ HBr الـ HBr في رابطة كم إلكترون بين الـ
+
+164
+00:13:55,200 --> 00:14:00,500
+H والـ Br؟ اثنين بياخد H مع إلكترونها بيكون لـ ROH
+
+165
+00:14:00,500 --> 00:14:05,100
+كحول زائد Br Radical واضح؟
+
+166
+00:14:06,110 --> 00:14:10,330
+إذاً الـHBr هذه الرابطة عبارة عن كم إلكترون؟
+
+167
+00:14:10,330 --> 00:14:17,290
+اثنين الـROH بياخد الـH مع إلكترونها شو بده يظل
+
+168
+00:14:17,290 --> 00:14:22,810
+عندي؟ الـBr مع إلكترونها بتكون الـBr Radical نقطة
+
+169
+00:14:22,810 --> 00:14:27,450
+البداية هي الـBr Radical يعني كل هذا الكلام تقديم
+
+170
+00:14:27,450 --> 00:14:31,570
+للقاعدية اللي بده يتم فيها التفاعل إيش وظيفة إذا
+
+171
+00:14:31,570 --> 00:14:32,890
+البروكسايد؟
+
+172
+00:14:34,710 --> 00:14:40,050
+أنه بيقصّر وبياخد H من الـHBr بيكون الـBr Radical،
+
+173
+00:14:40,050 --> 00:14:46,010
+كأنه صارت التفاعل اللي عنده مع الـBr Radical الآن
+
+17
+
+201
+00:17:04,600 --> 00:17:11,910
+الـ PR هن بيكوّن أي free radical primary، الـ PR بفضل
+
+202
+00:17:11,910 --> 00:17:16,990
+يتفاعل على أساس أنه يكون secondary free radical
+
+203
+00:17:16,990 --> 00:17:21,010
+لأن الـ stability of free radical زي الـ stability
+
+204
+00:17:21,010 --> 00:17:25,950
+of carbocation، الـ tertiary is more stable than the
+
+205
+00:17:25,950 --> 00:17:31,030
+secondary is more stable than the primary، واضح فالـ
+
+206
+00:17:31,030 --> 00:17:35,930
+PR هنا لما بيكون بده يختار بين نقطتين، بتفاعل بحيث 
+
+207
+00:17:35,930 --> 00:17:43,010
+يكون الـ more stable free radical، شفتوا ليش؟
+
+208
+00:17:43,010 --> 00:17:47,910
+الآن الـ Geometry تبعت التفاعل انحكمت في الخطوة
+
+209
+00:17:47,910 --> 00:17:51,970
+الأولى ولا لأ؟ أكيد، لأنه هنا كان عنده اختيارات، يا 
+
+210
+00:17:51,970 --> 00:17:55,830
+إي جهة، يا إي جهة، أخد مكان معين، الخطوة
+
+211
+00:17:55,830 --> 00:18:02,030
+الثانية، حيجة ده يتفاعل مع الـ HPR، ياخد منها؟ ياخد 
+
+212
+00:18:02,030 --> 00:18:10,650
+منها H، وإذا أخد من الـ HPR H، هي الـ HPR الجزء التاني إذا
+
+213
+00:18:10,650 --> 00:18:14,670
+أخد منها الـ H واتفاعل تهدي الـ H مع إلكترونها 
+
+214
+00:18:14,670 --> 00:18:19,170
+هنا، شو بيطلع له؟ الـ PR Radical، الـ PR Radical 
+
+215
+00:18:19,170 --> 00:18:26,020
+بيبدأ تفاعل من جديد، إذا إحنا هنا أمام سلسلة 
+
+216
+00:18:26,020 --> 00:18:30,940
+وتفاعلات الـ Free Radicals عادة هي عبارة عن سلاسل
+
+217
+00:18:30,940 --> 00:18:36,260
+فلو سألتكم عشان أبدأ الـ slide السابقة أو اللي
+
+218
+00:18:36,260 --> 00:18:40,980
+قلتلكوا الخطوة التحضيرية أكم من ناحية نظرية على
+
+219
+00:18:40,980 --> 00:18:45,740
+الأقل أكم PR Radical بالزمن بمساعدة البروكسايد
+
+220
+00:18:45,740 --> 00:18:53,660
+واحد واحد، لو بس البروكسايد طلع الـ free radical واحد 
+
+221
+00:18:53,660 --> 00:18:59,520
+و الـ free radical اتفاعل هنا، الواحد التاني من وين
+
+222
+00:18:59,520 --> 00:19:04,220
+بيطلع؟ من الـ HBr مرة تانية ومرة تالتة ومرة رابعة
+
+223
+00:19:04,220 --> 00:19:11,500
+إذا بالزمن البروكسيد بكمية كبيرة ولا بكمية بتسميها
+
+224
+00:19:11,500 --> 00:19:17,020
+catalytic amount، بكمية صغيرة، هذا فرق الـ catalyst
+
+225
+00:19:17,020 --> 00:19:20,960
+عن الـ reagent، الـ reagent أو المادة المتفاعل لما
+
+226
+00:19:20,960 --> 00:19:26,800
+يكون فعل شغلتين، بيكون لزمنه، بيكون لازم تكون النسبة
+
+227
+00:19:26,800 --> 00:19:32,340
+واحد لواحد، يعني لو عندي مليون الكين بدي مليون 
+
+228
+00:19:32,340 --> 00:19:40,120
+reagent، لكن الـ catalyst بالزمن منه كمية قليلة جدا 
+
+229
+00:19:40,120 --> 00:19:44,520
+لأنه بيقدمهم وبيعود يعمل generation، بتولد لحاله
+
+230
+00:19:44,520 --> 00:19:51,430
+يعني أول بيئة الـ radical اتولدت بمساعدة البروكسايد
+
+231
+00:19:51,430 --> 00:19:55,210
+.. مظبوط ولا .. بعد هيك الـ PR Radicals الجديدة
+
+232
+00:19:55,210 --> 00:19:59,610
+بتصير تتولد من الـ HPR في الـ second step بدون
+
+233
+00:19:59,610 --> 00:20:04,590
+مساعدة البروكسايد .. واضح؟ هذه فكرة الـ catalyst 
+
+234
+00:20:04,590 --> 00:20:09,110
+بساطة، لو بدي أشبهلكوا إياها زي أنتوا لما بتولعوا
+
+235
+00:20:09,110 --> 00:20:15,310
+الغاز .. الغاز بيضلوا مولع .. إيش بلزمكوا أنتوا 
+
+236
+00:20:15,310 --> 00:20:21,560
+عشان تولعوا الغاز؟ الشرارة، هل بلزمكوا تبقوا ملعين
+
+237
+00:20:21,560 --> 00:20:27,400
+جداحة continue واصلة عشان الغاز يبقى مولع؟ إذا
+
+238
+00:20:27,400 --> 00:20:32,780
+إنتوا بس لازمكوا شرارة واحدة وبعدين تبقوا ماشي
+
+239
+00:20:32,780 --> 00:20:38,280
+تلقائيا لحاله، وإحنا بلزمنا من برا البروكسايد بس
+
+240
+00:20:38,280 --> 00:20:38,940
+يعطينا
+
+241
+00:20:48,760 --> 00:20:55,350
+تفاعل متسلسل متكرر، متسلسل متكرر، واضح؟ زي تفاعلات
+
+242
+00:20:55,350 --> 00:20:58,770
+انشطار النواة، وشو اللي بيخلي الجمبلة الذرية 
+
+243
+00:20:58,770 --> 00:21:03,450
+وغيرها تعمل كل عمل عميلها؟ أن التفاعل تبعها a 
+
+244
+00:21:03,450 --> 00:21:08,070
+chain reaction، بيضلوا يكرر نفسه بشكل سريع لحاله 
+
+245
+00:21:08,070 --> 00:21:11,870
+وهذا عبارة عن a chain reaction، الـ first step 
+
+246
+00:21:11,870 --> 00:21:15,070
+addition of PR radical and formation of the more
+
+247
+00:21:15,070 --> 00:21:20,450
+stable free radical، والـ second step reaction with
+
+248
+00:21:20,450 --> 00:21:28,530
+HPR and formation of a new Br radical which starts
+
+249
+00:21:28,530 --> 00:21:34,710
+the reaction again and again، واضح؟ هذه هي القاعدة 
+
+250
+00:21:34,710 --> 00:21:38,610
+اللي بتتم فيها التفاعل، المحصلة أن إضافة الـ HBr في
+
+251
+00:21:38,610 --> 00:21:46,130
+وجود البروكسايد is Anti Markovnikov's addition
+
+252
+00:21:46,130 --> 00:21:52,610
+واضح؟ لحد هنا بننتهي من هذا الجزء، بنيجي
+
+253
+00:22:04,030 --> 00:22:07,810
+بنكمل، واضح؟ حتى لو عندكوا أشياء تانية بتكون
+
+254
+00:22:07,810 --> 00:22:11,530
+إضافية، مش متأكدة هذا الـ slide عندكوا إياه؟ لأ،
+
+255
+00:22:11,530 --> 00:22:18,890
+هاي موجودة، موجودة، موجودة، امشوا حوالي تلات صفحات
+
+256
+00:22:18,890 --> 00:22:20,270
+لأ، أخدت ..
+
+257
+00:22:29,230 --> 00:22:36,690
+بناخد تفاعل جديد لـ الـ الكينز
+
+258
+00:22:36,690 --> 00:22:44,170
+هذا التفاعل اسمه formation of oxiranes أو ابوكاسايت
+
+259
+00:22:44,170 --> 00:22:50,450
+من الـ الكينز، واضح؟ تكوين مركبات بيسميها الـ oxirans
+
+260
+00:22:50,450 --> 00:22:55,790
+أو الـ Epoxides من الـ alkenes، إذا إحنا أخدنا alkene
+
+261
+00:22:55,790 --> 00:23:03,130
+فعلناه مع peracid، per إيش معناه per؟ لأ per
+
+262
+00:23:03,130 --> 00:23:14,050
+لأ لأ، الـ per مش bear، peracid تعني زيادة
+
+263
+00:23:14,050 --> 00:23:17,950
+اتذكروا لما كنتوا تسموا مثلا perchlorate 
+
+264
+00:23:19,510 --> 00:23:23,810
+يكون في كام أكسجينات؟ أربع أكسجينات، فالـ per هنا
+
+265
+00:23:23,810 --> 00:23:28,270
+تعني الزيادة، peracid معناه حامض فيه أكسجين
+
+266
+00:23:28,270 --> 00:23:32,670
+زيادة، هاي معناه peracid، peracid، الحامض اللي
+
+267
+00:23:32,670 --> 00:23:36,850
+فيه أكسجين زيادة، بشكل عام صيغة الحامض العضوي إيش 
+
+268
+00:23:36,850 --> 00:23:42,990
+هي؟ R C double bond O OH
+
+269
+00:23:44,430 --> 00:23:53,410
+الحامض الفيزيائي بيكون RCOOOH
+
+270
+00:23:53,410 --> 00:24:01,490
+فالحامض مثل الخل مثلا CH3COO
+
+271
+00:24:03,700 --> 00:24:10,640
+حمض العضوي الوظيفة 
+
+272
+00:24:10,640 --> 00:24:11,220
+للحمض
+
+273
+00:24:14,320 --> 00:24:20,440
+بصير زيادة أكسوجينة زي الميه، الميه كانت H2O 
+
+274
+00:24:20,440 --> 00:24:28,120
+واحدة، لما صارت hydrogen peroxide، إيه صارت؟ تنتين
+
+275
+00:24:28,120 --> 00:24:32,720
+أكسوجين، per، مش hydrogen peroxide، فكلمة
+
+276
+00:24:32,720 --> 00:24:37,060
+per إيش بتعني؟ زيادة أكسوجين، فإذا أنا فعلت الـ
+
+277
+00:24:37,060 --> 00:24:41,640
+الكين مع peracid، يعني حامض في أكسجينة زيادة 
+
+278
+00:24:41,640 --> 00:24:46,640
+بييجي بيكوّنلي حلقة ثلاثية متصلة بالأكسجين بهذا
+
+279
+00:24:46,640 --> 00:24:50,520
+الشكل، هذه الحلقة الثلاثية المتصلة بالأكسجين بهذا 
+
+280
+00:24:50,520 --> 00:24:59,000
+الشكل بنسميها حلقة Oxirane، إيش اسمها؟ Oxirane، واضح؟
+
+281
+00:24:59,000 --> 00:25:06,540
+كمجموعة وظيفية، كل الحلقات اللي فيهم حلقة ثلاثية
+
+282
+00:25:06,540 --> 00:25:11,940
+متصلة بالأكسجين بيقولولها epoxide، لاحظوا في عندي 
+
+283
+00:25:11,940 --> 00:25:18,380
+اسم المركب تحديدا، وفي عندي اسم العائلة، زي تماما ما
+
+284
+00:25:18,380 --> 00:25:26,810
+بنقول أن الـ ROH كحول، هذا اسم عائلة، لكن لو جيت قلت 
+
+285
+00:25:26,810 --> 00:25:34,730
+CH3OH ميثانول، هذا اسم إيش الفرد، واضح؟ الآن العائلة
+
+286
+00:25:34,730 --> 00:25:40,530
+الحلقة الثلاثية اللي فيها الـ oxygen اسمها Epoxide
+
+287
+00:25:41,340 --> 00:25:46,200
+العائلة إيش اسمها؟ Epoxides، كل الحلقات الثلاثية
+
+288
+00:25:46,200 --> 00:25:48,620
+اللي في الدنيا اللي فيها أكسوجين طبعا، ممكن هنا
+
+289
+00:25:48,620 --> 00:25:53,920
+يصير R وR وR وR وشغلات كتيرة، كلها كعائلات إيش
+
+290
+00:25:53,920 --> 00:25:59,140
+اسمها؟ Epoxides، الآن الأفراد تبعونها زي ما في عند
+
+291
+00:25:59,140 --> 00:26:04,840
+عائلة الكحول وفي منها إيش؟ أفراد، أبسط فرد فيهم لما
+
+292
+00:26:04,840 --> 00:26:10,280
+هدول الأربعة يكونوا Hydrogens، إيش اسمه؟ Oxirane
+
+293
+00:26:10,280 --> 00:26:15,040
+فالـ Oxirane هو اسم الحلقة المركب اللي فيه كلهم 
+
+294
+00:26:15,040 --> 00:26:20,160
+هيدروجينز برضه، هذا الفرد له اسم تاني، هذا المركب
+
+295
+00:26:20,160 --> 00:26:26,420
+كله لما يكون أربعة هيدروجينز شو اسمه، إيثيلين لما
+
+296
+00:26:26,420 --> 00:26:32,460
+يجي يعمل مع الأكسجين المركب بنسميه إيثيلين أكسيد 
+
+297
+00:26:32,460 --> 00:26:36,940
+أكسيد الإيثيلين لأن هذا اسمه إيثيلين وعمل مع الأكسجين
+
+298
+00:26:36,940 --> 00:26:43,800
+فهذا المركب اللي فيه أربعة هيدروجين اسمه اكسيرين
+
+299
+00:26:43,800 --> 00:26:49,320
+أو أكسيد
+
+300
+00:26:49,320 --> 00:26:55,080
+الإيثيلين، ليش أكسيد الإيثيلين؟ لأنه إجانة من تفاعل
+
+301
+00:26:55,080 --> 00:27:00,180
+الإيثيلين مع الأكسجين، واضح؟ العائلة ككل إيش اسمها؟
+
+302
+00:27:00,180 --> 00:27:05,420
+أكسيد الإيثيلين، لكن المركب نفسه يا بسميه اكسيرين،
+
+303
+00:27:05,420 --> 00:27:11,650
+يا بسميه أكسيد الإيثيلين، الاسمين هما اسمين لا فرق
+
+304
+00:27:11,650 --> 00:27:18,090
+الان بإمكانكوا عادة تصيروا بسهولة تستوعبوا لو يا 
+
+305
+00:27:18,090 --> 00:27:23,250
+ترى الألكين اللي كان عندي ماكانش إيثيلين كان
+
+306
+00:27:23,250 --> 00:27:29,250
+بروبيلين وفعلناه وعملنا double bond بس هذه كانت 
+
+307
+00:27:29,250 --> 00:27:33,970
+CH3 يعني بروبيلين أو بروبين، واجهة المركب الناتج،
+
+308
+00:27:33,970 --> 00:27:40,550
+شو هسميه؟ بروبيلين أكسايد، لو كان هذا بيوتين،
+
+309
+00:27:40,550 --> 00:27:45,030
+بيوتين أكسايد، لو كان بنتين، بنتين أكسايد، شايفين 
+
+310
+00:27:45,030 --> 00:27:48,930
+إنتوا كيف؟
+
+311
+00:27:48,930 --> 00:27:49,590
+واضح؟
+
+312
+00:27:53,120 --> 00:27:57,800
+هنا بنعطي عدة أمثلة، في كل الأحوال بتلاحظوا الـ..
+
+313
+00:27:57,800 --> 00:28:03,480
+الـ peracid، الـ peracid RC ضب الـ bond O O و O H 
+
+314
+00:28:03,480 --> 00:28:07,300
+يعني كله كم O لو كنا بدنا نجمعهم تلاتة تلاتة
+
+315
+00:28:07,300 --> 00:28:10,980
+الحامض العضوي الطبيعي كم O؟ تنتين، تنتين، هذا per
+
+316
+00:28:10,980 --> 00:28:15,740
+acid تلاتة، في كل الأحوال لما بدنا نفعله بده تيجي O
+
+317
+00:28:15,740 --> 00:28:21,020
+وتعمل حلقة ثلاثية هن، أو O تعمل حلقة ثلاثية هن، أو
+
+318
+00:28:21,020 --> 00:28:26,370
+O تعمل حلقة ثلاثية هن، واضح؟ يعني لو قلنا لكوا أكمل
+
+319
+00:28:26,370 --> 00:28:30,050
+المعادلة هن، أو هن، أو هن، كتبنا لكوا صيغة زي هيك 
+
+320
+00:28:30,050 --> 00:28:34,190
+ولا كتبنا لكوا RCO3H ولا كتبنا لكوا peracid، في
+
+321
+00:28:34,190 --> 00:28:38,470
+النهاية بدكوا تكونولنا حلقة ثلاثية، الآن هذه
+
+322
+00:28:38,470 --> 00:28:41,950
+المركبات، لو قلتلكوا هدول المركبات كلهم ما العائلة
+
+323
+00:28:41,950 --> 00:28:47,350
+الجامعة لهم، they are epoxides، واضح؟ كل واحد فيهم
+
+324
+00:28:47,350 --> 00:28:55,070
+إله اسم، كل واحد فيهم إله اسم، اسمه ممكن اشتقه من اسم 
+
+325
+00:28:55,070 --> 00:28:58,110
+المركب الاصلي، يعني مثلا هذا المركب الاصلي اسمه 
+
+326
+00:28:58,110 --> 00:29:05,610
+styrene، هداك إيش بيصير؟ Styrene Oxide، هذا المركب
+
+327
+00:29:05,610 --> 00:29:12,850
+اسمه، إذا بتذكروا اخذناه Isobutene، هذا Isobutene
+
+328
+00:29:12,850 --> 00:29:19,410
+إذا هداك المركب Isobutene Oxide، هذا Cyclohexane أو 
+
+329
+00:29:19,410 --> 00:29:25,880
+Ethyl Cyclohexane، الحلقة نفسها Cyclohexane، مظبوط 
+
+330
+00:29:25,880 --> 00:29:28,820
+ولا لأ؟ إذا المركب اللي هناك إيش بده يصير؟
+
+331
+00:29:28,820 --> 00:29:35,020
+Cyclohexane Oxide، واضح؟ الآن حد بيجي يقولكوا شو
+
+332
+00:29:35,020 --> 00:29:38,980
+هالعائلة؟ شو هالمركبات هدولة؟ they are epoxides، فـ 
+
+333
+00:29:38,980 --> 00:29:43,780
+epoxide اسم عائلة، العائلة في منها إيش؟ أفراد
+
+334
+00:29:43,780 --> 00:29:51,690
+كثيرين، مشاك حال الدنيا ولا لأ؟ طيب إيش فائدات ..
+
+335
+00:29:51,690 --> 00:29:55,510
+إيش فائدات هذه الـ Epoxides؟ هذه الـ Epoxides عبارة
+
+336
+00:29:55,510 --> 00:29:59,890
+عن حلقة ثلاثية، سبق اتفقنا احنا أن الحلقة الثلاثية 
+
+337
+00:29:59,890 --> 00:30:05,510
+حلقة مترايحة من ناحية الـ geometry ولا مضغوطة؟
+
+338
+00:30:05,510 --> 00:30:09,470
+مضغوطة جدا، ليش؟ لأن الزاوية تاعتها المفروض 60 60 
+
+339
+00:30:09,470 --> 00:30:15,560
+60، والزاوية المريحة للكربون كدهش؟ مية وتسعة ونص 
+
+340
+00:30:15,560 --> 00:30:19,200
+مية وتسعة ونص، بناء على ذلك هذه الحلقة بتفتح
+
+341
+00:30:19,200 --> 00:30:25,460
+بسهولة، يعني هذا الـ Epoxide لو أنا اجيت فعلته مع أي 
+
+342
+00:30:25,460 --> 00:30:30,440
+مادة معطية للإلكترونات، فيها إلكترونات بنسميها 
+
+343
+00:30:30,440 --> 00:30:33,340
+Nucleophile، ليش بدي افعله مع مادة فيها إلكترونات
+
+344
+00:30:33,340 --> 00:30:36,460
+السبب بسيط أن الـ oxygen is electronegative، بتكون
+
+345
+00:30:36,460 --> 00:30:39,820
+partially negative، الـ carbon اللي هنا شو بتصير؟
+
+346
+00:30:40,490 --> 00:30:45,270
+partially positive، بناء على ذلك لو أي إش فيه 
+
+347
+00:30:45,270 --> 00:30:48,470
+إلكترونات بيتفعل هنا بيكسر هذه الرابطة بيفتح
+
+348
+00:30:48,470 --> 00:30:54,950
+الحلقة، واضح، مثلا الميه فيها إلكترونات مش فيها
+
+349
+00:30:54,950 --> 00:30:59,190
+أزواج إلكترونات على أكسجين، زوجين من الإلكترونات مش 
+
+350
+00:30:59,190 --> 00:31:04,090
+واحد، احنا بيكفينا واحد، الأن هذه الميه بتيجي 
+
+351
+00:31:04,090 --> 00:31:09,280
+بتتفاعل هن، بتفتح .. بتعمل O .. O minus بتصير OH
+
+352
+00:31:09,280 --> 00:31:13,960
+فلاحظوا أن الأكسجين تبع الابوكسايد بتتحول إلى إيش؟
+
+353
+00:31:13,960 --> 00:31:18,240
+إلى OH وبتضيف الميه، طبعا الميه لما تضيف .. شو
+
+354
+00:31:18,240 --> 00:31:25,380
+بتضيف منها؟ OH، الأن لو إجت فعلت مع H X هنا كأنه
+
+355
+00:31:25,380 --> 00:31:29,180
+عندك X minus، الـ X minus هجمت هنا هذه بتفتح .. 
+
+356
+00:31:29,180 --> 00:31:36,440
+بتصير O وبتاخد الـ H بتصير OH وهنا إيجي عنده الـ
+
+357
+00:31:36,440 --> 00:31:41,620
+X minus، نفس الأشياء، لو أخدت مع R O minus، الـ R O
+
+358
+00:31:41,620 --> 00:31:46,340
+minus بده تفتح هنا، في الآخر لما بتضيف ميطار بتصير 
+
+359
+00:31:46,340 --> 00:31:52,720
+R O H، إذا المفروض يصير واضح عندكم شكل التفاعل أن 
+
+360
+00:31:52,720 --> 00:31:59,580
+الحلقة بتفتح، الـ O تبعها بتصير O H وبيضيف عنده
+
+361
+00:31:59,580 --> 00:32:07,040
+المادة اللي فيها الإلكترونات اللي فعلناها، هذا أي
+
+362
+00:32:07,040 --> 00:32:10,240
+مادة فيها إلكترونات احنا بنسميها نيوكليوفايل
+
+363
+00:32:10,240 --> 00:32:14,480
+لنيوكليوفايل الشيء اللي فيه إلكترونات وبيتفعل من
+
+364
+00:32:14,480 --> 00:32:17,940
+خلال إلكتروناته، هنا الـ O فيها إلكترونات، الـ X فيها
+
+365
+00:32:17,940 --> 00:32:22,200
+إلكترونات، الـ R O minus فيها إلكترونات، إذا كأنه الـ
+
+366
+00:32:22,200 --> 00:32:25,520
+reaction of epoxides هذا with إيش؟ with 
+
+367
+00:32:25,520 --> 00:32:31,24
+
+401
+00:35:20,550 --> 00:35:26,850
+Epoxides بتفتح الحلقة بتكوينها مركبات فيها كحول أو 
+
+402
+00:35:26,850 --> 00:35:34,630
+فيها OH واضح؟ وهذه هي الميكانيزم للتفاعل في هذا ال
+
+403
+00:35:34,630 --> 00:35:38,930
+slide وبننهي 
+
+404
+00:35:38,930 --> 00:35:43,530
+في هذا ال slide زي
+
+405
+00:35:43,530 --> 00:35:49,110
+ما بتلاحظوا هنا بتلاحظوا أن الميّه وين 
+
+406
+00:35:49,110 --> 00:35:54,270
+بتهاجم؟ على الكربون لأن الميّه فيها إلكترونات
+
+407
+00:35:54,270 --> 00:36:01,250
+والكربون موجبة هادة لما بتتحرك زيك بتصير OH plus
+
+408
+00:36:01,250 --> 00:36:04,770
+هي بتكون أخدت ال H من الأول بفتح في النهاية بعدين
+
+409
+00:36:04,770 --> 00:36:11,630
+ال OH إذا الهجوم بيكون من السالب على الموجبة هذا
+
+410
+00:36:11,630 --> 00:36:16,410
+اللي أنا بأبينه، الهجوم من السالب على الموجب، بيصير
+
+411
+00:36:16,410 --> 00:36:20,250
+عنده ring opening، كل هذه عبارة عن أمثلة على
+
+412
+00:36:20,250 --> 00:36:23,770
+الموضوع بنقف عند formation of diols 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..217a4f450b8bb42c9466aa13d8f48e64405cb691
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_postprocess.srt
@@ -0,0 +1,1648 @@
+1
+00:00:05,990 --> 00:00:12,290
+بنكمل في موضوع تفاعلات الـ alkenes تحديدًا تفاعلات
+
+2
+00:00:12,290 --> 00:00:17,570
+الإضافة تحديدًا تفاعلات الإضافة المرة الماضية
+
+3
+00:00:17,570 --> 00:00:22,150
+كملخص، كملخص على الكلام اللي حكيناه قلنا إنه إحنا
+
+4
+00:00:22,150 --> 00:00:26,390
+لما بندرس تفاعل إضافة الـ alkene بدنا نتطلع على
+
+5
+00:00:26,390 --> 00:00:30,450
+شغلتين بدنا نتطلع على الـ alkene symmetric ولا
+
+6
+00:00:30,450 --> 00:00:32,750
+unsymmetric بدنا نتطلع على ال reagent
+
+7
+00:00:40,180 --> 00:00:45,180
+نظريا نتوقع ناتجين نتوقع ناتجين
+
+8
+00:00:48,280 --> 00:00:52,960
+بتحكم التجربة يعني مرات بيطلع عندنا الناتج الأول
+
+9
+00:00:52,960 --> 00:00:55,760
+مرات بيطلع عندنا التاني و مرات بيطلع عندنا حقيقة
+
+10
+00:00:55,760 --> 00:01:02,120
+خليط من الناتج الواضح؟ أخدنا بالتفصيل عملية إضافة
+
+11
+00:01:02,120 --> 00:01:07,640
+الميه بتلت طرق و لاحظنا أن التلت طرق بيؤدوا إلى
+
+12
+00:01:07,640 --> 00:01:14,300
+نواتج مرات مختلفة الآن بعد إضافة الميه بناخد إضافة
+
+13
+00:01:14,300 --> 00:01:21,520
+الـHBrإضافة الـHBr مباشرة كلكم هتنتبهوا أن الـHBr
+
+14
+00:01:21,520 --> 00:01:29,740
+عبارة عن Unsymmetrical Reagent واضح؟ بناء على ذلك
+
+15
+00:01:29,740 --> 00:01:33,300
+هذا الـUnsymmetrical Reagent لو بضيف على ألكين
+
+16
+00:01:33,300 --> 00:01:39,640
+بسيط متماثل symmetrical ألكين المتوقع عنده ناتج
+
+17
+00:01:39,640 --> 00:01:44,100
+واحد فلو افترضنا مثلا أن الـHBr بنضيفه على
+
+18
+00:01:45,370 --> 00:01:49,670
+الإيثالين والإضافة عادة تكون في وجود H بلس في
+
+19
+00:01:49,670 --> 00:01:52,630
+الخطوة الأولى الـ double bond بتتفاعل مع الـ H بلس
+
+20
+00:01:52,630 --> 00:01:57,670
+بتعمل رابطة هنا هيدي بدل ما هي CH2 صارت CH3 وبتكون
+
+21
+00:01:57,670 --> 00:02:03,330
+عندي كاربو كتاين الكاربو كتاين بتفاعلمع الـ Br
+
+22
+00:02:03,330 --> 00:02:11,050
+minus بكمل إضافة HBr واضح؟ فعملية الإضافة أو الـ
+
+23
+00:02:11,050 --> 00:02:15,210
+mechanism of addition زيها زي إضافة إيش؟ المية على
+
+24
+00:02:15,210 --> 00:02:20,330
+خطوتين الخطوة الأولى إضافة الـ H plus على ال
+
+25
+00:02:20,330 --> 00:02:24,570
+double bond تكوين Carbocation الخطوة التانية اللي
+
+26
+00:02:24,570 --> 00:02:27,850
+هو تفاعل الـ negative ion مع ال Carbocation
+
+27
+00:02:27,850 --> 00:02:34,230
+واستكمال الإضافةالان لو كان عندى الالكين un
+
+28
+00:02:34,230 --> 00:02:38,690
+-symmetrical زى البروبين على سبيل المثال لاحظوا
+
+29
+00:02:38,690 --> 00:02:41,870
+هذا الكربون حملة 2 هيدروجين زى هذا الكربون حملة 1
+
+30
+00:02:41,870 --> 00:02:49,050
+هيدروجين وبدأ تيجي H بلس تتفاعللاحظوا ان الناتج
+
+31
+00:02:49,050 --> 00:02:53,010
+اللى عندنا هو عبارة عن ناتج Markov-Nikov addition
+
+32
+00:02:53,010 --> 00:02:59,510
+إذا إضافة الـHBr في وجود الحامض في وجود الـH بلس
+
+33
+00:02:59,510 --> 00:03:04,410
+الناتج تبع الإضافة إيش Markov-Nikov addition بمعنى
+
+34
+00:03:04,410 --> 00:03:08,930
+أن الهيدروجين بتيجي هنا والبر بتيجي هنا ملاحظين
+
+35
+00:03:08,930 --> 00:03:14,820
+انتوا هى الجزئينهي الهيدروجين وهي ال PR هذه عبارة
+
+36
+00:03:14,820 --> 00:03:20,880
+عن Markovnikov's addition واضح تماما لكوا إيش معنى
+
+37
+00:03:20,880 --> 00:03:23,780
+Markovnikov's addition الهيدروجين إجت عن اللي حمل
+
+38
+00:03:23,780 --> 00:03:31,560
+الهيدروجين أكتر و ال PR بتكمل التفاؤل الآن بالنسبة
+
+39
+00:03:31,560 --> 00:03:36,360
+ل ال mechanism of this reaction تماما زي ال
+
+40
+00:03:36,360 --> 00:03:40,940
+mechanism of addition of waterUn-symmetrical
+
+41
+00:03:40,940 --> 00:03:45,320
+alkene بمعنى لو انا اتخيلت انه في عندى هذا الـ Un
+
+42
+00:03:45,320 --> 00:03:48,380
+-symmetrical alkene بندفعله ماقاتش PR في وجود H
+
+43
+00:03:48,380 --> 00:03:52,060
+plus اللى بده تتفاعل الاتفاق اللى هي الرابطة
+
+44
+00:03:52,060 --> 00:03:55,180
+الزوجية او الالكترونات بتاعنا الرابطة الزوجية
+
+45
+00:03:55,180 --> 00:03:59,580
+لاحظوا هنا بوضحلكوا الكلام مرة تانية هى الرابطة
+
+46
+00:03:59,580 --> 00:04:02,420
+الزوجية هى الالكترونات اللى بندفعله ماقاتش plus
+
+47
+00:04:02,420 --> 00:04:08,320
+الان اما بده تتحرك الرابطة بهذا الشكل بمعنى ان ال
+
+48
+00:04:08,320 --> 00:04:12,770
+Hبلاستي جهان و هذه الرابطة الزوجية الكاربو كاتيون
+
+49
+00:04:12,770 --> 00:04:15,790
+في هذه الحالة بيتكون هنا شو بيكون هذا الكاربو
+
+50
+00:04:15,790 --> 00:04:21,390
+كاتيون ال primary ولا ال secondary او لو صار
+
+51
+00:04:21,390 --> 00:04:31,150
+التفاعل بطريقة تانية لو صار
+
+52
+00:04:31,150 --> 00:04:36,030
+التفاعل بطريقة تانية وين هتيجي ال edge على هذا
+
+53
+00:04:36,030 --> 00:04:40,330
+الموقع وين هتيجيكوا ال edgeعلى هذا الموقع ..الان
+
+54
+00:04:40,330 --> 00:04:45,510
+كاربو كاتيون حصير primary ..انه المفضل؟ secondary
+
+55
+00:04:45,510 --> 00:04:51,410
+..واضح؟ بناء على ذلك هذا المسار كله مابيصيرش و
+
+56
+00:04:51,410 --> 00:04:55,430
+اللي بيصير عندنا المسار اللي بيكون عبر secondary
+
+57
+00:04:55,430 --> 00:05:00,630
+كاربو كاتيون بيكمل إضافة ال PR هنا ..واضح؟ إذا لو
+
+58
+00:05:00,630 --> 00:05:02,790
+بنقولكوا إيش ال mechanism؟
+
+59
+00:05:09,590 --> 00:05:14,410
+الخطوة الأولى هي إضافة الـ H بلس وتكوين الـ more
+
+60
+00:05:14,410 --> 00:05:22,080
+stable كاربو كتايونتحصيل حاصل إضافة ال PR minus
+
+61
+00:05:22,080 --> 00:05:26,080
+طبعا اللي بيحدد ال regiochemistry، معنى
+
+62
+00:05:26,080 --> 00:05:29,160
+regiochemistry، regio يعني من region، من منطقة، ان
+
+63
+00:05:29,160 --> 00:05:32,780
+وين التفاعل يصير، هنا ولا هنا، وإيش الاتج يكون، هل
+
+64
+00:05:32,780 --> 00:05:37,360
+هو ترى الخطوة الأولى ولا الخطوة التانية؟ الخطوة
+
+65
+00:05:37,360 --> 00:05:41,620
+الأولى، الخطوة التانية تابعة لهذه ال PR هنا مافيش
+
+66
+00:05:41,620 --> 00:05:44,860
+عنده خيار إلا يجيه، لكن ال H لاحظوا ال H كان
+
+67
+00:05:44,860 --> 00:05:50,830
+بالإمكان تيجي زي هيك أو زي هيكواضح الكلام فالتفاعل
+
+68
+00:05:50,830 --> 00:05:55,390
+هنا محكوب بالخطوة الأولى اللى بيؤدي لتكوين ال more
+
+69
+00:05:55,390 --> 00:06:02,130
+stable carbocation هو نجوسيره هذا هو إضافة Markov
+
+70
+00:06:02,130 --> 00:06:07,570
+Nikov إضافة حسب قاعدة Markov Nikov طبعا هذا الكلام
+
+71
+00:06:07,570 --> 00:06:14,510
+ليش بيصير بيحاولوا يوضحوا بمنحنة طاقة بنسميهاهذا
+
+72
+00:06:14,510 --> 00:06:24,170
+الملحنة بيقول الاتي هاي ال H plus بدها تضيف على ال
+
+73
+00:06:24,170 --> 00:06:33,410
+double bond بإمكانها تتسلق قمة قصيرةعشان تكون ال
+
+74
+00:06:33,410 --> 00:06:38,390
+more stable secondary carbocation او قمة عالية
+
+75
+00:06:38,390 --> 00:06:44,010
+عشان تكون ال less stable primary carbocation الان
+
+76
+00:06:44,010 --> 00:06:47,030
+انتوا لو تخيلتوا ان انتوا في قاعر واد و بدكوا
+
+77
+00:06:47,030 --> 00:06:49,630
+تطلعوا عندكوا احتمالين عشان تطلعوا من قاعر هذا
+
+78
+00:06:49,630 --> 00:06:52,790
+الواد ياما بدكوا تطلعوا على هطبة صغيرة يا بدكوا
+
+79
+00:06:52,790 --> 00:06:57,150
+تطلعوا على جبل عالي ايش اللي بتفضلوا؟العطب الصغيرة
+
+80
+00:06:57,150 --> 00:07:01,490
+و كذلك الحال هنا أن الطاقة اللازمة بلزم طاقة
+
+81
+00:07:01,490 --> 00:07:05,550
+للتفاعل لازمة الطاقة اللازمة هنا ال E-activation
+
+82
+00:07:05,550 --> 00:07:10,150
+لتكوين ال secondary carbocation أقل من الطاقة
+
+83
+00:07:10,150 --> 00:07:14,950
+اللازمة لتكوين ال primary carbocation ليش؟ لأن ال
+
+84
+00:07:14,950 --> 00:07:18,590
+secondary carbocation is more stable than the
+
+85
+00:07:18,590 --> 00:07:23,190
+primary carbocation فالتفاعل بأي اتجاه حيصير؟ بهذا
+
+86
+00:07:23,190 --> 00:07:28,760
+الاتجاهواضح ؟ التفاعل يحصل في هذا الاتجاه
+
+87
+00:07:35,760 --> 00:07:41,660
+الـ HPR اللي بيضيف حسب قاعدة Markov Nikon في وجود
+
+88
+00:07:41,660 --> 00:07:46,860
+حامض في وجود H Plus لاحظوا انه في وجود Reagent
+
+89
+00:07:46,860 --> 00:07:51,180
+تاني غير الحامض بيضيف بطريقة تانية بيضيف Anti
+
+90
+00:07:51,180 --> 00:07:55,140
+Markov Nikon Addition إذا مرة تانية لازم تكونوا
+
+91
+00:07:55,140 --> 00:07:59,760
+منتبهين لازم تكونوا منتبهين لما احنا بيجي نسألكوا
+
+92
+00:07:59,760 --> 00:08:06,590
+نقولكوا هاي Double Bond HPRعلى شروط التفاعل إذا
+
+93
+00:08:06,590 --> 00:08:11,030
+كتبنا HBr مع H بلس، ماهو ناتج اللي بيكون في الطول؟
+
+94
+00:08:11,030 --> 00:08:17,410
+Markovnikov addition إذا كتبنا HBr مع مادة بنسميها
+
+95
+00:08:17,410 --> 00:08:23,020
+البروكسايد، بضيف عكس قاعدة Markovnikovواضح؟ إذا
+
+96
+00:08:23,020 --> 00:08:27,720
+مرة تانية عندي إيش؟ الاحتمالين في وجود الحامض حسب
+
+97
+00:08:27,720 --> 00:08:33,540
+قاعدة ماركوفنيكوف في وجود البروكسايد عكس قاعدة
+
+98
+00:08:33,540 --> 00:08:36,760
+ماركوفنيكوف عشان إيه؟ لو أنا بدي أطلع على هذا
+
+99
+00:08:36,760 --> 00:08:42,220
+المثال، هذا المثال هي طرفية double bond في two
+
+100
+00:08:42,220 --> 00:08:47,930
+carbons، أنية اللي عليها الhydrogen أكتر، هذهلو
+
+101
+00:08:47,930 --> 00:08:51,770
+هذا التفاعل قلت بدي أكمله HBr في وجود H بلاس و أين
+
+102
+00:08:51,770 --> 00:08:55,810
+بدي أحط الـ H؟ تحت الـ PR؟ فوق .. فوق .. فوق ..
+
+103
+00:08:55,810 --> 00:08:56,030
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+104
+00:08:56,030 --> 00:08:58,210
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+105
+00:08:58,210 --> 00:08:58,510
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+106
+00:08:58,510 --> 00:09:05,290
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+107
+00:09:05,290 --> 00:09:11,280
+فوق .. فوقالـ PR هذه الإضافة إضافة Markovnikov و
+
+108
+00:09:11,280 --> 00:09:14,840
+لا Anti Markovnikov Anti Markovnikov addition
+
+109
+00:09:14,840 --> 00:09:21,320
+واضح؟ إذا الإضافة في وجود البريكسايد is Anti
+
+110
+00:09:21,320 --> 00:09:28,500
+Markovnikov addition طبعا ممكن نحاول نعملتفسير،
+
+111
+00:09:28,500 --> 00:09:32,640
+ممكن نحاول نعمل تفسير، ليش الإضافة في وجود
+
+112
+00:09:32,640 --> 00:09:36,320
+البروكسيد under Markovnikov addition؟ بيروكسيد
+
+113
+00:09:36,320 --> 00:09:40,280
+يعني فوق أكسيد، إيش معناه فوق أكسيد؟ يعني فيه
+
+114
+00:09:40,280 --> 00:09:46,000
+زيادة في الأكسوجين، شكل البروكسيد زي هيك R O O R
+
+115
+00:09:46,930 --> 00:09:51,490
+بدل ما يكون عندى ROR اللى هو ال ether العادى بيكون
+
+116
+00:09:51,490 --> 00:09:57,650
+عندى كام أكسوجينة R O O R هذه الرابطة اللى بين ال
+
+117
+00:09:57,650 --> 00:10:02,230
+oxygens اللى بين ال oxygens فى البروكسايد عبارة عن
+
+118
+00:10:02,230 --> 00:10:07,710
+weak bond بمعنى بقليل من الحرارة أو بضوء الشمس أو
+
+119
+00:10:07,710 --> 00:10:12,470
+من ال UV light بتنكسر هذه الرابطة الرابطة عبارة عن
+
+120
+00:10:12,470 --> 00:10:17,990
+كام إلكترونالان هدولة الإلكترونين لو اتخيلناهم زي
+
+121
+00:10:17,990 --> 00:10:25,070
+هيك اي رابطة ممكن تنكسر نوعين من الكسرممكن تنكسر
+
+122
+00:10:25,070 --> 00:10:30,550
+نوعين من الكسر إما أن يكون الكسر متجانس وإما أن
+
+123
+00:10:30,550 --> 00:10:35,350
+يكون الكسر غير متجانس متجانس بمعنى أن هنا بدو ييجي
+
+124
+00:10:35,350 --> 00:10:39,970
+إلكترون وهنا بدو ييجي إلكترون، إذا هذا الكسر إيش
+
+125
+00:10:39,970 --> 00:10:47,110
+بنسميه؟ homo .. homolytic cleavage إيش يعني
+
+126
+00:10:47,110 --> 00:10:52,220
+homolytic cleavage؟كسر متجانس هان إلكترون وهان
+
+127
+00:10:52,220 --> 00:10:56,320
+إلكترون ممكن بالتأكيد تنكسر بحيث أنه يكونوا
+
+128
+00:10:56,320 --> 00:11:00,340
+إلكترونين على جهة واحدة أو يطلع عيون سالب وهنا
+
+129
+00:11:00,340 --> 00:11:05,430
+مافيش ولا إلكترون يطلع عيون موجببالتأكيد هذا بيصير
+
+130
+00:11:05,430 --> 00:11:12,330
+كثر heterolytic cleavage كثر غير متجانس اذا دائما
+
+131
+00:11:12,330 --> 00:11:16,130
+الاتنين البساطة من ناحية ال mathematics يا بتكون
+
+132
+00:11:16,130 --> 00:11:22,920
+واحد زائد واحد يا بتكون اتنين زائد سفر1 زائد 1
+
+133
+00:11:22,920 --> 00:11:26,620
+يعني لو فيه اتنين شكل بدنا نوزعهم على اتنين كيف
+
+134
+00:11:26,620 --> 00:11:31,060
+بدنا نوزعهم؟ يا هذا بنعطي شكل و هذا شكل هاي توزيع
+
+135
+00:11:31,060 --> 00:11:37,980
+متجانس يا هذا اتنين شكل و هذا سفر و هذا توزيع غير
+
+136
+00:11:37,980 --> 00:11:42,540
+متجانس واضح؟ و النوعين من الكثر بالمناسبة موجودين
+
+137
+00:11:42,540 --> 00:11:49,200
+في الكيميا لكن ان هو من ناحية الطاقةأسهل الكثر
+
+138
+00:11:49,200 --> 00:11:52,780
+المتجانس ولا غير المتجانس؟
+
+139
+00:11:54,690 --> 00:11:59,790
+طيب الان انتوا اي واحدة هي و أختها و الاتنين شاكل
+
+140
+00:11:59,790 --> 00:12:03,590
+ان هو اقبل للنفس انه شاكل هان و شاكل هان و لا
+
+141
+00:12:03,590 --> 00:12:09,290
+اتنين هان و سفرهان ربنا بيحبش الظلم مظبوط ولا لأ؟
+
+142
+00:12:09,290 --> 00:12:14,330
+اذا المتجانس افضل عارفين ليش غير المتجانس مش مفضل؟
+
+143
+00:12:14,330 --> 00:12:18,730
+لأنه في النهاية هتخلوا اتنين minusاللي بيكون حامل
+
+144
+00:12:18,730 --> 00:12:23,830
+إلكترونين بيصير minus واللي حامل إلكترون plus و
+
+145
+00:12:23,830 --> 00:12:29,910
+بعدين بتيجي تفصله plus عن minus ال plus عن ال
+
+146
+00:12:29,910 --> 00:12:33,650
+minus في الدنيا بتجاذب ولا بتفصل؟ طيب لما بدي
+
+147
+00:12:33,650 --> 00:12:39,070
+أفصله؟ بالظبط زي المغناطسين الشمالي و الجنوبي
+
+148
+00:12:39,070 --> 00:12:44,930
+الشمالي و الجنوبي بتجاذبوا لما بتكن تفصلوهمبتكون
+
+149
+00:12:44,930 --> 00:12:48,750
+طاقة، مظبوط ولا لا؟ و ال plus و ال minus، الاصل
+
+150
+00:12:48,750 --> 00:12:53,490
+فيهم التجاذب ولا إنهم يبعدوا عن بعض؟ اه إذا، بناءً
+
+151
+00:12:53,490 --> 00:12:56,830
+على ذلك، لو أنا بدي أعمل كسر غير متجانس في
+
+152
+00:12:56,830 --> 00:13:00,470
+الكيميا، بدي أخلي إشي minus و إشي plus و أقعد أبعد
+
+153
+00:13:00,470 --> 00:13:03,750
+plus عن minus، بدي طاقة، إذا من ناحية طاقة، أنه
+
+154
+00:13:03,750 --> 00:13:08,700
+أفضل؟الكسر المتجنس هذا لا يعني ان الكسر غير
+
+155
+00:13:08,700 --> 00:13:12,800
+المتجنس ما بيصيرش بيصير و هناخد ظروف معينة و نتعلم
+
+156
+00:13:12,800 --> 00:13:18,460
+أشياء فيها كسر غير متجنس الشغلتين موجودين واضح؟
+
+157
+00:13:18,460 --> 00:13:23,790
+على أي حاللاحظوا المعنى هنا انه في هذه الحالة
+
+158
+00:13:23,790 --> 00:13:29,110
+البروكسايد بيعمل homolytic cleavage بيعطينا اتنين
+
+159
+00:13:29,110 --> 00:13:34,450
+RO اي قطعة بتحمل إلكترون واحد شو اتفقنا نسميها
+
+160
+00:13:34,450 --> 00:13:42,080
+free radical جذر حرfree radical واضح؟ ودائما اللي
+
+161
+00:13:42,080 --> 00:13:46,420
+حامل إلكترون واحد بيصير طمعان يحمل كمان إلكترون
+
+162
+00:13:46,420 --> 00:13:50,300
+يعمل رابطة بناء على ذلك هذا ال RORadical بيجي
+
+163
+00:13:50,300 --> 00:13:55,200
+يتفعل مع ال HBR ال HBR في رابطة كم إلكترون بين ال
+
+164
+00:13:55,200 --> 00:14:00,500
+H و ال PR؟ اتنين بياخد H مع إلكترونها بيكوّن ل ROH
+
+165
+00:14:00,500 --> 00:14:05,100
+كحول زائد PR radical واضح؟
+
+166
+00:14:06,110 --> 00:14:10,330
+إذاً الـHPR هذه الرابطة عبارة عن كام إلكترون؟
+
+167
+00:14:10,330 --> 00:14:17,290
+إتنين الـROH بياخد الـH مع إلكترونها شو بده يظل
+
+168
+00:14:17,290 --> 00:14:22,810
+عندى؟ الـPR مع إلكترونها بتكون الـPR Radical نقطة
+
+169
+00:14:22,810 --> 00:14:27,450
+البداية هي الـPR Radical يعني كل هذا الكلام تقديم
+
+170
+00:14:27,450 --> 00:14:31,570
+للقالية اللى بده يتم فيها التفاعل إيش وظيفة إذا
+
+171
+00:14:31,570 --> 00:14:32,890
+البروكسايد؟
+
+172
+00:14:34,710 --> 00:14:40,050
+أنه يُقصر ويأخذ H من الـHPR بيكوّن الـPR Radical،
+
+173
+00:14:40,050 --> 00:14:46,010
+كأنه صارت التفاعل اللي عنده مع الـPR Radical الآن
+
+174
+00:14:46,010 --> 00:14:50,510
+في الـslide اللي جاي بدنا نشوف كيف بيتم التفاعل مع
+
+175
+00:14:50,510 --> 00:14:55,110
+الـPR Radical هو الـPR Radical اللي بيتفاعل مع
+
+176
+00:14:55,110 --> 00:14:58,930
+الالكين، هذه كلها خطوات تحضيرية والدليل عيطنى حتى
+
+177
+00:14:58,930 --> 00:15:03,170
+الآن احنا شوفنا الالكينشوفنا الـ Alkene ولا قاعدين
+
+178
+00:15:03,170 --> 00:15:09,050
+من جهز التفاعل من جهز التفاعل صار عندنا PR Radical
+
+179
+00:15:09,050 --> 00:15:15,010
+واضح؟ صار عندنا PR Radical هذا الـ PR Radical هو
+
+180
+00:15:15,010 --> 00:15:20,910
+الآن اللي بدو يتفاعل مع الـ Alkene الـ Alkene
+
+181
+00:15:20,910 --> 00:15:25,550
+عبارة عن Double Bond و Double Bond كام إلكترون
+
+182
+00:15:25,550 --> 00:15:31,760
+فيها؟لأ اتنين ال buy bond انا بقصد ال buy bond ال
+
+183
+00:15:31,760 --> 00:15:34,460
+sigma bond مابيصيرش عليها التفاعل ال buy bond
+
+184
+00:15:34,460 --> 00:15:41,260
+الرابطة التانية إلكترونين وجاي PR مع إلكترونه إيش
+
+185
+00:15:41,260 --> 00:15:47,120
+بده يعمل؟ بده يعمل رابطة هي PR و إلكترون يا بيجي
+
+186
+00:15:47,120 --> 00:15:51,800
+مع هذا الإلكترون بضيف هنا يا بيجي مع هذا الإلكترون
+
+187
+00:15:51,800 --> 00:15:58,160
+بضيف هنا لاحظوا هنا التفاعل يبدأ بإضافة ماذا؟ال PR
+
+188
+00:15:58,160 --> 00:16:03,740
+قبل شوية في تفاعل إضافة ال H PR مع الحامض كانت
+
+189
+00:16:03,740 --> 00:16:09,220
+الخطوة الأولى إضافة إيش ال H والتانية ال PR .. هنا
+
+190
+00:16:09,220 --> 00:16:16,310
+أول خطوةإضافة ال PR التانية ال H يعني لو بدنا نيجي
+
+191
+00:16:16,310 --> 00:16:20,450
+نسألكوا في مسائل الصح و الغلط اللي مرات بتغلبكم
+
+192
+00:16:20,450 --> 00:16:26,650
+نقولكم ال first step in the addition of HPR to
+
+193
+00:16:26,650 --> 00:16:29,170
+alkenes in the presence of peroxide is the
+
+194
+00:16:29,170 --> 00:16:34,310
+formation of a bond to hydrogen لأ is a formation
+
+195
+00:16:34,310 --> 00:16:41,460
+of a bond to bromineالخطوة الأولى تكوين الرابط مع
+
+196
+00:16:41,460 --> 00:16:46,720
+ال PR والتانية مع ال H عكس الكلام اللى حكيناه قبل
+
+197
+00:16:46,720 --> 00:16:51,360
+شوية الآن ال PR لاحظوا عنده خيارات يبدو يتفعل هن
+
+198
+00:16:51,360 --> 00:16:56,980
+لو اتفعل هن بيكوّل free radical ايش نوعه ال PR
+
+199
+00:16:56,980 --> 00:16:59,600
+اتفعل هن شو نوع هذا ال free radical ال primary ال
+
+200
+00:16:59,600 --> 00:17:04,600
+secondary ال tertiary ال secondary طب لو اتفعل ال
+
+201
+00:17:04,600 --> 00:17:11,910
+PR هن بيكوّل اي free radicalprimary ال PR بفضل
+
+202
+00:17:11,910 --> 00:17:16,990
+يتفاعل على أساس أنه يكون secondary free radical
+
+203
+00:17:16,990 --> 00:17:21,010
+لأن ال stability of free radical زي ال stability
+
+204
+00:17:21,010 --> 00:17:25,950
+of carbocation ال tertiary is more stable than the
+
+205
+00:17:25,950 --> 00:17:31,030
+secondary is more stable than the primary واضح فال
+
+206
+00:17:31,030 --> 00:17:35,930
+PR هنا لما بيكون بده يختار بين نقطين بتفاعل بحيث
+
+207
+00:17:35,930 --> 00:17:43,010
+يكونالـ more stable and free radical شفتوا ليش؟
+
+208
+00:17:43,010 --> 00:17:47,910
+الآن الـ Geometry تبعت التفاعل انحكمت في الخطوة
+
+209
+00:17:47,910 --> 00:17:51,970
+الأولى ولا لأ؟ أكيد لأنه هنا كان عنده اختيارات، يا
+
+210
+00:17:51,970 --> 00:17:55,830
+إي جهان، يا إي جهانة، أخد مكان معين الخطوة
+
+211
+00:17:55,830 --> 00:18:02,030
+الثانية، حيجة ده يتفاعل مع الـHPR، ياخد منها؟ ياخد
+
+212
+00:18:02,030 --> 00:18:10,650
+منها H وإذا أخد من الـHPR Hهي HPR الجزء التاني إذا
+
+213
+00:18:10,650 --> 00:18:14,670
+أخد منها الـ H واتفاعل تهدي الـ H مع إلكترونها
+
+214
+00:18:14,670 --> 00:18:19,170
+هنا، شو بيطلع له؟ الـ PR Radical الـ PR Radical
+
+215
+00:18:19,170 --> 00:18:26,020
+بيبدأ تفاعل من جديد، إذا إحنا هنا أمامسلسلة
+
+216
+00:18:26,020 --> 00:18:30,940
+وتفاعلات الـ Free Radicals عادة هي عبارة عن سلاسل
+
+217
+00:18:30,940 --> 00:18:36,260
+فلو سألتكم عشان أبدأ ال slide السابقة أو اللي
+
+218
+00:18:36,260 --> 00:18:40,980
+قلتلكوا الخطوة التحضيرية أكم من ناحية نظرية على
+
+219
+00:18:40,980 --> 00:18:45,740
+الأقل أكم PR Radical بالزمن بمساعدة البروكسايد
+
+220
+00:18:45,740 --> 00:18:53,660
+واحدواحد لو بس البروكسايد طلع ال free radical واحد
+
+221
+00:18:53,660 --> 00:18:59,520
+و ال free radical اتفاعل هناالواحد التاني من وين
+
+222
+00:18:59,520 --> 00:19:04,220
+بيطلع؟ من الـHBr مرة تانية و مرة تالتة و مرة رابعة
+
+223
+00:19:04,220 --> 00:19:11,500
+إذا بالزمن البروكسيد بكمية كبيرة ولا بكمية بتسميها
+
+224
+00:19:11,500 --> 00:19:17,020
+catalytic amount بكمية صغيرة هذا فرق ال catalyst
+
+225
+00:19:17,020 --> 00:19:20,960
+عن ال reagent ال reagent أو المادة المتفاعل لما
+
+226
+00:19:20,960 --> 00:19:26,800
+يكون فعل شغلتين بيكون لزمنهبيكون لازم تكون النسبة
+
+227
+00:19:26,800 --> 00:19:32,340
+واحد لواحد يعني لو عندى مليون الكين بدي مليون
+
+228
+00:19:32,340 --> 00:19:40,120
+reagent لكن ال catalyst بالزمن منه كمية قليلة جدا
+
+229
+00:19:40,120 --> 00:19:44,520
+لأنه بيقدمهم و بيعود يعمل generation بتولد لحاله
+
+230
+00:19:44,520 --> 00:19:51,430
+يعني أول بيئة ال radical اتولدت بمساعدةالبروكسايد
+
+231
+00:19:51,430 --> 00:19:55,210
+.. مظبوط ولا .. بعد هيك ال PR Radicals لجديدة
+
+232
+00:19:55,210 --> 00:19:59,610
+بتصير تتولد من ال HPR في ال second step بدون
+
+233
+00:19:59,610 --> 00:20:04,590
+مساعدة البروكسايد .. واضح؟ هذه فكرة ال catalyst
+
+234
+00:20:04,590 --> 00:20:09,110
+بساطة لو بدي أشبهلكوا إياها زي أنتوا لما بتولعوا
+
+235
+00:20:09,110 --> 00:20:15,310
+الغاز .. الغاز بيضلوا مولع .. إيش بلزمكوا أنتوا
+
+236
+00:20:15,310 --> 00:20:21,560
+عشان تولعوا الغاز؟ الشرارةهل بلزمكوا تبقوا ملعين
+
+237
+00:20:21,560 --> 00:20:27,400
+جداحة continue واصلة عشان الغاز يبقى ملعق؟ إذا
+
+238
+00:20:27,400 --> 00:20:32,780
+إنتوا بس لازمكوا شرارة واحدة وبعدين تبقوا ماشي
+
+239
+00:20:32,780 --> 00:20:38,280
+تلقائيا لحاله وإحنا بلزمنا من برا البروكسايد بس
+
+240
+00:20:38,280 --> 00:20:38,940
+يعطينا
+
+241
+00:20:48,760 --> 00:20:55,350
+تفاعل متسلسل متكرر متسلسل متكررواضح؟ زي تفاعلات
+
+242
+00:20:55,350 --> 00:20:58,770
+لانشطار النووة وشو اللي بيخلي الجمبلة الذرية
+
+243
+00:20:58,770 --> 00:21:03,450
+وغيرها تعمل كل عمل عميلها؟ ان التفاعل تبعها a
+
+244
+00:21:03,450 --> 00:21:08,070
+chain reaction بيضلوا يكرر نفسه بشكل سريع لحاله
+
+245
+00:21:08,070 --> 00:21:11,870
+وهذا عبارة عن a chain reaction ال first step
+
+246
+00:21:11,870 --> 00:21:15,070
+addition of PR radical and formation of the more
+
+247
+00:21:15,070 --> 00:21:20,450
+stable free radical وال second step reaction with
+
+248
+00:21:20,450 --> 00:21:28,530
+HPRand formation of a new Br radical which starts
+
+249
+00:21:28,530 --> 00:21:34,710
+the reaction again and again واضح؟ هذه هي القالية
+
+250
+00:21:34,710 --> 00:21:38,610
+اللي بتتم فيها التفاعل المحصلة ان إضافة الـHBr في
+
+251
+00:21:38,610 --> 00:21:46,130
+وجود البروكسايد is Anti Markovnikov's addition
+
+252
+00:21:46,130 --> 00:21:52,610
+واضح؟ لحد هنا بننتهي من هذا الجزء بنيجي
+
+253
+00:22:04,030 --> 00:22:07,810
+بنكمل واضح؟ حتى لو عندكوا أشياء تانية بتكون
+
+254
+00:22:07,810 --> 00:22:11,530
+إضافية، مش متأكدة هذا ال slide عندكوا إياها؟ لأ،
+
+255
+00:22:11,530 --> 00:22:18,890
+هاي موجودة، موجودة، موجودة امشوا حوالي تلات صفحات
+
+256
+00:22:18,890 --> 00:22:20,270
+لأ، أخدت ..
+
+257
+00:22:29,230 --> 00:22:36,690
+بناخد تفاعل جديد لل ال الكينز
+
+258
+00:22:36,690 --> 00:22:44,170
+هذا التفاعل اسمه formation of oxiranes او ابوكسايت
+
+259
+00:22:44,170 --> 00:22:50,450
+من ال الكينزواضح؟ تكوين مركبات بيسميها ال oxirans
+
+260
+00:22:50,450 --> 00:22:55,790
+أو ال Epoxides من الalkenes إذا إحنا أخدنا alkene
+
+261
+00:22:55,790 --> 00:23:03,130
+فعلناه مع pear acid، pear إيش معناه pear؟ لأ pear
+
+262
+00:23:03,130 --> 00:23:14,050
+لأ لأال bear ber مش bear bear acid تعني زيادة
+
+263
+00:23:14,050 --> 00:23:17,950
+اتذكروا لما كنتوا تسموا مثلا berichlorate
+
+264
+00:23:19,510 --> 00:23:23,810
+يكون في كام أكسجينة؟ أربع أكسجينات فال bear هنا
+
+265
+00:23:23,810 --> 00:23:28,270
+تعني الزيادة bear acid معناه حامض فيه أكسجين
+
+266
+00:23:28,270 --> 00:23:32,670
+زيادة، هاي معناه bear acid، bear acid الحامض اللي
+
+267
+00:23:32,670 --> 00:23:36,850
+فيه أكسجين زيادة، بشكل عام صيغة الحامض العضوي إيش
+
+268
+00:23:36,850 --> 00:23:42,990
+هي؟ R C double bond O OH
+
+269
+00:23:44,430 --> 00:23:53,410
+الحامض الفيزيائي بيكون RCOOOH
+
+270
+00:23:53,410 --> 00:24:01,490
+فالحامض مثل الخل مثلا CH3COO
+
+271
+00:24:03,700 --> 00:24:10,640
+حمض العضوى الوظيفة
+
+272
+00:24:10,640 --> 00:24:11,220
+للحمض
+
+273
+00:24:14,320 --> 00:24:20,440
+بصير زيادة أكسوجينة زي الميه، الميه كانت H2O
+
+274
+00:24:20,440 --> 00:24:28,120
+واحدة، لما صارت hydrogen peroxide، إيه صارت؟ تنتين
+
+275
+00:24:28,120 --> 00:24:32,720
+أكسوجين، pear، مشقولنا hydrogen peroxide، فكلمة
+
+276
+00:24:32,720 --> 00:24:37,060
+pear إيش بتعني؟ زيادة أكسوجينةفإذا أنا فعلت ال
+
+277
+00:24:37,060 --> 00:24:41,640
+الكين مع bare acid يعني حامض في أكسجينة زيادة
+
+278
+00:24:41,640 --> 00:24:46,640
+بييجي بيكوّنلي حلقة ثلاثية متصلة بالأكسجين بهذا
+
+279
+00:24:46,640 --> 00:24:50,520
+الشكل، هذه الحلقة الثلاثية المتصلة بالأكسجين بهذا
+
+280
+00:24:50,520 --> 00:24:59,000
+الشكل بنسميها حلقة Oxarionأيش اسمها؟ Oxirane واضح؟
+
+281
+00:24:59,000 --> 00:25:06,540
+كمجموعة وظيفية كل الحلقات اللي فيهم حلقة ثلاثية
+
+282
+00:25:06,540 --> 00:25:11,940
+متصلة بالأكسجين بيقولولها epoxide لاحظوا في عندي
+
+283
+00:25:11,940 --> 00:25:18,380
+اسم المركب تحديدا وفي عندي اسم العائلة زي تماما ما
+
+284
+00:25:18,380 --> 00:25:26,810
+بنقول ان ال ROHكحول هذا اسم عائلة لكن لو جيت قولت
+
+285
+00:25:26,810 --> 00:25:34,730
+CH3OH ميثانول هذا اسم إيش الفرد واضح؟ الآن العائلة
+
+286
+00:25:34,730 --> 00:25:40,530
+الحلقة الثلاثية اللي فيها ال oxygen اسمها Epoxide
+
+287
+00:25:41,340 --> 00:25:46,200
+العائلة إيش اسمها؟ Epoxides كل الحلقات الثلاثية
+
+288
+00:25:46,200 --> 00:25:48,620
+اللي في الدنيا اللي فيها أكسوجين طبعا ممكن هنا
+
+289
+00:25:48,620 --> 00:25:53,920
+يصير R وR وR وR وشغلات كتيرة كلها كعائلات إيش
+
+290
+00:25:53,920 --> 00:25:59,140
+اسمها؟ Epoxides الآن الأفراد تبعونها زي ما في عند
+
+291
+00:25:59,140 --> 00:26:04,840
+عائلة الكحول وفي منها إيش؟ أفراد أبسط فرد فيهم لما
+
+292
+00:26:04,840 --> 00:26:10,280
+هدول الأربعة يكونوا Hydrogens إيش اسمه؟Oxirane
+
+293
+00:26:10,280 --> 00:26:15,040
+فالـ Oxirane هو اسم الحلقة المُركّب اللي فيه كلهم
+
+294
+00:26:15,040 --> 00:26:20,160
+هيدروجينز برضه هذا الفرد له اسم تاني هذا المُركّب
+
+295
+00:26:20,160 --> 00:26:26,420
+كله لما يكون أربعة هيدروجينز شو اسمه اثيلين لما
+
+296
+00:26:26,420 --> 00:26:32,460
+ييجي يعمل مع الأكسجل المُركّب بنسميه أثيلين أكسيد
+
+297
+00:26:32,460 --> 00:26:36,940
+أكسيد الأثيلين لأن هذا اسمه أثيلين وعمل مع الأكسجل
+
+298
+00:26:36,940 --> 00:26:43,800
+فهذا المُركّباللي فيه أربعة هيدروجين اسمه أكزيرين
+
+299
+00:26:43,800 --> 00:26:49,320
+أو أكسيد
+
+300
+00:26:49,320 --> 00:26:55,080
+الأثيلين ليش أكسيد الأثيلين؟ لأنه إجانة من تفاعل
+
+301
+00:26:55,080 --> 00:27:00,180
+الأثيلين مع الأكسجين، واضح؟ العائلة ككل إيش اسمها؟
+
+302
+00:27:00,180 --> 00:27:05,420
+أكسيد الأثيلين، لكن المركّب نفسه يا بسميه أكزيرين،
+
+303
+00:27:05,420 --> 00:27:11,650
+يا بسميه أكسيد الأثيلينالاسمين هما اسمين لا فرق
+
+304
+00:27:11,650 --> 00:27:18,090
+الان بإمكانكوا عادة تصيروا بسهولة تستوعبوا لو يا
+
+305
+00:27:18,090 --> 00:27:23,250
+ترى الألكين اللى كان عندى ماكنش إثيلين كان
+
+306
+00:27:23,250 --> 00:27:29,250
+بروبيلين وفعلناه وعملنا double bond بس هذه كانت
+
+307
+00:27:29,250 --> 00:27:33,970
+CH3 يعني بروبيلين او بروبينواجهة المُركّب الناتج،
+
+308
+00:27:33,970 --> 00:27:40,550
+شو هسميه؟ إفروبيين أكسايد، لو كان هذا بيوتين،
+
+309
+00:27:40,550 --> 00:27:45,030
+بيوتين أكسايد، لو كان بنتين، بنتين أكسايد، شايفين
+
+310
+00:27:45,030 --> 00:27:48,930
+إنتوا كيف؟
+
+311
+00:27:48,930 --> 00:27:49,590
+واضح؟
+
+312
+00:27:53,120 --> 00:27:57,800
+هنا بنعطي عدة أمثلة في كل الأحوال بتلاحظوا ال ..
+
+313
+00:27:57,800 --> 00:28:03,480
+ال bare acid ال bare acid RC ضب ال bond O O و O H
+
+314
+00:28:03,480 --> 00:28:07,300
+يعني كله أكم O لو كنا بدنا نجمعهم تلاتة تلاتة
+
+315
+00:28:07,300 --> 00:28:10,980
+الحامض العضو الطبيعي كام O؟ تنتين تنتين هذا bare
+
+316
+00:28:10,980 --> 00:28:15,740
+acid تلاتة في كل الأحوال لما بدنا نفعله بده تيجي O
+
+317
+00:28:15,740 --> 00:28:21,020
+و تعمل حلقة ثلاثية هن أو O تعمل حلقة ثلاثية هن أو
+
+318
+00:28:21,020 --> 00:28:26,370
+O تعمل حلقة ثلاثية هنواضح؟ يعني لو قلنا لكوا أكمل
+
+319
+00:28:26,370 --> 00:28:30,050
+المعادلة هان أو هان أو هان كتبنا لكوا صيغة زي هيك
+
+320
+00:28:30,050 --> 00:28:34,190
+ولا كتبنا لكوا RCO3H ولا كتبنا لكوا pear acid في
+
+321
+00:28:34,190 --> 00:28:38,470
+النهاية بدكوا تكونولنا حلقة ثلاثية الآن هذه
+
+322
+00:28:38,470 --> 00:28:41,950
+المركبات لو قلتلكوا هدول المركبات كلهم ما العائلة
+
+323
+00:28:41,950 --> 00:28:47,350
+الجامعة لهم they are epoxides واضح؟ كل واحد فيهم
+
+324
+00:28:47,350 --> 00:28:55,070
+إله اسم كل واحد فيهم إله اسماسمه ممكن اشتقه من اسم
+
+325
+00:28:55,070 --> 00:28:58,110
+المركب الاصلي يعني مثلا هذا المركب الاصلي اسمه
+
+326
+00:28:58,110 --> 00:29:05,610
+styrene هداك ايش بيصير Styrene Oxide هذا المركب
+
+327
+00:29:05,610 --> 00:29:12,850
+اسمه اذا بتذكروا اخدناه Isobutene هذا Isobutene
+
+328
+00:29:12,850 --> 00:29:19,410
+اذا هداك المركب Isobutene Oxide هذا Cyclohexane او
+
+329
+00:29:19,410 --> 00:29:25,880
+Ethyl Cyclohexaneالحلقة نفسها Cyclohexane مظبوط
+
+330
+00:29:25,880 --> 00:29:28,820
+ولا لأ؟ إذا المركب اللي هناك إيش بده يصير؟
+
+331
+00:29:28,820 --> 00:29:35,020
+Cyclohexane Oxide واضح؟ الآن حد بيجي يقولكوا شو
+
+332
+00:29:35,020 --> 00:29:38,980
+هالعائلة؟ شو هالمركبات هدولة؟ they are epoxides ف
+
+333
+00:29:38,980 --> 00:29:43,780
+epoxide اسم عائلة العائلة في منها إيش؟ أفراد
+
+334
+00:29:43,780 --> 00:29:51,690
+كثيرين مشاك حال الدنيا ولا لأ؟طيب ايش فائدات ..
+
+335
+00:29:51,690 --> 00:29:55,510
+ايش فائدات هذه ال Epoxides؟ هذه ال Epoxides عبارة
+
+336
+00:29:55,510 --> 00:29:59,890
+عن حلقة ثلاثية سبق اتفقنا احنا ان الحلقة الثلاثية
+
+337
+00:29:59,890 --> 00:30:05,510
+حلقة مترايحة من ناحية ال geometry ولا مضغوطة؟
+
+338
+00:30:05,510 --> 00:30:09,470
+مضغوطة جدا، ليش؟ لأن الزاوية تاعتها المفروض 60 60
+
+339
+00:30:09,470 --> 00:30:15,560
+60 و الزاوية المريحة لكاربون كدهش؟مية وتسعة و نص
+
+340
+00:30:15,560 --> 00:30:19,200
+مية وتسعة و نص بناء على ذلك هذه الحلقة بتفتح
+
+341
+00:30:19,200 --> 00:30:25,460
+بسهولة يعني هذا ال Epoxide لو انا اجيت فعلته مع اي
+
+342
+00:30:25,460 --> 00:30:30,440
+مادة معطية للإلكترونات فيها إلكترونات بنسميها
+
+343
+00:30:30,440 --> 00:30:33,340
+Nucleophile ليش بدى افعله مع مادة فيها إلكترونات
+
+344
+00:30:33,340 --> 00:30:36,460
+السبب بسيط ان ال oxygen is electronegative بتكون
+
+345
+00:30:36,460 --> 00:30:39,820
+partially negative ال carbon اللي هنا شو بتصير؟
+
+346
+00:30:40,490 --> 00:30:45,270
+partially positive بناء على ذلك لو اي إش فيه
+
+347
+00:30:45,270 --> 00:30:48,470
+إلكترونات بتفاعل هنا بيكسر هذه الرابطة بيفتح
+
+348
+00:30:48,470 --> 00:30:54,950
+الحلقة واضح مثلا الميه فيها إلكترونات مش فيها
+
+349
+00:30:54,950 --> 00:30:59,190
+أزواج إلكترونات على أكسجين زوجين من الإلكترونات مش
+
+350
+00:30:59,190 --> 00:31:04,090
+واحد احنا بيكفينا واحد الأن هذه الميه بتيجي
+
+351
+00:31:04,090 --> 00:31:09,280
+بتتفاعل هنابتفتح .. بتعمل O .. O minus بتصير OH
+
+352
+00:31:09,280 --> 00:31:13,960
+فلاحظوا أن الأكسجين تبع الابوكسايد بتتحول إلى إيش؟
+
+353
+00:31:13,960 --> 00:31:18,240
+إلى OH و بتضيف الميه طبعا الميه لما تضيف .. شو
+
+354
+00:31:18,240 --> 00:31:25,380
+بتضيف منها؟ OH الأن لو إجت فعلت مع H X هنا كأنه
+
+355
+00:31:25,380 --> 00:31:29,180
+عندك X minus ال X minus هجمت هنا هذه بتفتح ..
+
+356
+00:31:29,180 --> 00:31:36,440
+بتصير O و بتاخد ال H بتصيرأو اتش وهنا إيجي عنده ال
+
+357
+00:31:36,440 --> 00:31:41,620
+X minus نفس الأشياء لو أخدت مع R O minus ال R O
+
+358
+00:31:41,620 --> 00:31:46,340
+minus بده تفتح هنا في الآخر لما بتضيف ميطار بتصير
+
+359
+00:31:46,340 --> 00:31:52,720
+R O H إذا المفروض يصار واضح عندكم شكل التفاعل أن
+
+360
+00:31:52,720 --> 00:31:59,580
+الحلقة بتفتح ال O تعتها بتصير O H وبيضيف عنده
+
+361
+00:31:59,580 --> 00:32:07,040
+المادة اللي فيهاالأكترونات اللي فعلناها هذا أي
+
+362
+00:32:07,040 --> 00:32:10,240
+مادة فيها أكترونات احنا بنسميها نيوكليوفايل
+
+363
+00:32:10,240 --> 00:32:14,480
+لنيوكليوفايل الشيء اللي فيه أكترونات وبيتفعل من
+
+364
+00:32:14,480 --> 00:32:17,940
+خلال أكتروناته هنا ال O فيها أكترونات ال X فيها
+
+365
+00:32:17,940 --> 00:32:22,200
+أكترونات ال R O minus فيها أكترونات إذا كأنه ال
+
+366
+00:32:22,200 --> 00:32:25,520
+reaction of epoxides هذا with إيش؟ with
+
+367
+00:32:25,520 --> 00:32:31,240
+نيوكليوفايل كل هدولة بنسميهم احنا إيش؟ نيوكليوفايل
+
+368
+00:32:31,240 --> 00:32:33,780
+إيش معنى نيوكليوفايل؟
+
+369
+00:32:36,730 --> 00:32:43,490
+مش محبلة الإلكترونات، هو فيه إلكترونات، اللي فيه
+
+370
+00:32:43,490 --> 00:32:49,210
+إلكترونات بيكون محبلة إيش؟ للموجب، و أين يوجد
+
+371
+00:32:49,210 --> 00:32:57,230
+الموجب؟ في النوارالنواء إيش بتكون؟ موجبة عشان كلمة
+
+372
+00:32:57,230 --> 00:33:02,010
+file معناها باللاتيني محب الان ال nucleo جاية من
+
+373
+00:33:02,010 --> 00:33:07,750
+وين؟ من ال nucleus من النواء الموجبة إذا هو كأنه
+
+374
+00:33:07,750 --> 00:33:12,370
+معناه nucleophile محب file معناها محب و ال nucleo
+
+375
+00:33:12,370 --> 00:33:17,150
+النواء الموجبة محب للنواء الموجبة اللي محب للموجبة
+
+376
+00:33:17,150 --> 00:33:23,940
+إيش بتكون؟ سالك أو يحمل إلكتروناتطيب لو بدنا نقول
+
+377
+00:33:23,940 --> 00:33:29,580
+في إشي بيكون محبلة السالب إيش بدنا نسميه؟
+
+378
+00:33:29,580 --> 00:33:34,540
+electrophile إيش معناه electrophile؟ محبلة
+
+379
+00:33:34,540 --> 00:33:39,760
+الإلكترونات فال electrophile المحبلة الإلكترونات
+
+380
+00:33:39,760 --> 00:33:40,340
+بيكون
+
+381
+00:33:42,860 --> 00:33:50,040
+والنيوكليوفايل المحب للموجة بيكون سالب أو أزواج من
+
+382
+00:33:50,040 --> 00:33:54,060
+الإلكترونات يعني يمثل كثافة إلكترونية ففهمتوا في
+
+383
+00:33:54,060 --> 00:33:58,140
+ال organic chemistry إيش معناه نيوكليوفايل السالب
+
+384
+00:33:58,140 --> 00:34:01,680
+اللي بيتفعل مع حاجة موجة بقى؟ إيش معناه إلكتروفايل
+
+385
+00:34:01,680 --> 00:34:06,200
+الموجة اللي بيتفعل مع حاجة سالبة؟ الآن هذه
+
+386
+00:34:06,200 --> 00:34:11,260
+الكربونة إيش مالها؟موجبة بناء على ذلك بتكون قاعدة
+
+387
+00:34:11,260 --> 00:34:15,900
+تستنى ييجي عليها غيش، يعني لو حاطيتلكوا بس سؤال زي
+
+388
+00:34:15,900 --> 00:34:20,480
+هيك و قولتلكوا ساهم و انا فراه، هذا الموجب لازم
+
+389
+00:34:20,480 --> 00:34:23,580
+اللي بيجي عليه ايش يكون؟ سالم، لازم اللي بيجي عليه
+
+390
+00:34:23,580 --> 00:34:30,310
+يكون نيوكليوفايلالماء مثال للنيوكليوفايل X- مثل CR
+
+391
+00:34:30,310 --> 00:34:35,830
+- أو PR- مثل النيوكليوفايل الكحول ROH مثل
+
+392
+00:34:35,830 --> 00:34:40,890
+النيوكليوفايل الكحول منزوع الهيدروجين RO- مثل
+
+393
+00:34:40,890 --> 00:34:45,870
+النيوكليوفايل في كل الأحوال الأمر بسيط جدا تفاعل
+
+394
+00:34:45,870 --> 00:34:49,110
+النيوكليوفايل مع الابوكسايد بيجيب النيوكليوفايل
+
+395
+00:34:49,110 --> 00:34:51,650
+على كاربون و بتفتح الحلقة من الجهة التانية بتصير
+
+396
+00:34:51,650 --> 00:34:57,180
+OHصعب ولا سهل؟ إذا لليوكليوفايل بدي ييجي هذا
+
+397
+00:34:57,180 --> 00:35:03,260
+الحركة تفتح تصيب OH هملاحظين نفس ال trend نفس ال
+
+398
+00:35:03,260 --> 00:35:09,320
+trend يعني بنتقدر نقول ان يوكليوفايل open the
+
+399
+00:35:09,320 --> 00:35:16,580
+epoxide ring forming an alcohol or an OH compound
+
+400
+00:35:16,580 --> 00:35:20,550
+مظلوط ولا لأ؟لـ Nucleophiles بتتفاعل مع ال
+
+401
+00:35:20,550 --> 00:35:26,850
+Epoxides بتفتح الحلقة بتكوينها مركبات فيها كحول أو
+
+402
+00:35:26,850 --> 00:35:34,630
+فيها OH واضح؟ وهذه هي الميكانيزم للتفاعل في هذا ال
+
+403
+00:35:34,630 --> 00:35:38,930
+slide وبننهي
+
+404
+00:35:38,930 --> 00:35:43,530
+في هذا ال slide زي
+
+405
+00:35:43,530 --> 00:35:49,110
+ما بتلاحظوا هنا بتلاحظوا ان الميهالميّه وين
+
+406
+00:35:49,110 --> 00:35:54,270
+بتهاجم؟ على الكربون لأن الميّه فيها إلكترونات
+
+407
+00:35:54,270 --> 00:36:01,250
+والكربون موجبة هادة لما بتتحرك زيك بتصير OH plus
+
+408
+00:36:01,250 --> 00:36:04,770
+هي بتكون أخدت ال H من الأول بفتح في النهاية بعدين
+
+409
+00:36:04,770 --> 00:36:11,630
+ال OH إذا الهجوم بيكون من السالب على الموجبةهذا
+
+410
+00:36:11,630 --> 00:36:16,410
+اللي أنا بابنك، الهجوم من السالب على الموجب، بيصير
+
+411
+00:36:16,410 --> 00:36:20,250
+عنده ring opening، كل هذه عبارة عن أمثلة على
+
+412
+00:36:20,250 --> 00:36:23,770
+الموضوع بنقف عند formation of diodes
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b9760ef26a3fe3f24d02c3fabf4beada9278bd1c
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/TfcnzPptjJc_raw.srt
@@ -0,0 +1,1664 @@
+1
+00:00:05,990 --> 00:00:12,290
+بنكمل في موضوع تفاعلات الـ alkenes تحديدًا تفاعلات
+
+2
+00:00:12,290 --> 00:00:17,570
+الإضافة تحديدًا تفاعلات الإضافة المرة الماضية
+
+3
+00:00:17,570 --> 00:00:22,150
+كملخص، كملخص على الكلام اللي حكيناه قلنا إنه إحنا
+
+4
+00:00:22,150 --> 00:00:26,390
+لما بندرس تفاعل إضافة الـ alkene بدنا نتطلع على
+
+5
+00:00:26,390 --> 00:00:30,450
+شغلتين بدنا نتطلع على الـ alkene symmetric ولا
+
+6
+00:00:30,450 --> 00:00:32,750
+unsymmetric بدنا نتطلع على ال reagent
+
+7
+00:00:40,180 --> 00:00:45,180
+نظريا نتوقع ناتجين نتوقع ناتجين
+
+8
+00:00:48,280 --> 00:00:52,960
+بتحكم التجربة يعني مرات بيطلع عندنا الناتج الأول
+
+9
+00:00:52,960 --> 00:00:55,760
+مرات بيطلع عندنا التاني و مرات بيطلع عندنا حقيقة
+
+10
+00:00:55,760 --> 00:01:02,120
+خليط من الناتج الواضح؟ أخدنا بالتفصيل عملية إضافة
+
+11
+00:01:02,120 --> 00:01:07,640
+الميه بتلت طرق و لاحظنا أن التلت طرق بيؤدوا إلى
+
+12
+00:01:07,640 --> 00:01:14,300
+نواتج مرات مختلفة الآن بعد إضافة الميه بناخد إضافة
+
+13
+00:01:14,300 --> 00:01:21,520
+الـHBrإضافة الـHBr مباشرة كلكم هتنتبهوا أن الـHBr
+
+14
+00:01:21,520 --> 00:01:29,740
+عبارة عن Unsymmetrical Reagent واضح؟ بناء على ذلك
+
+15
+00:01:29,740 --> 00:01:33,300
+هذا الـUnsymmetrical Reagent لو بضيف على ألكين
+
+16
+00:01:33,300 --> 00:01:39,640
+بسيط متماثل symmetrical ألكين المتوقع عنده ناتج
+
+17
+00:01:39,640 --> 00:01:44,100
+واحد فلو افترضنا مثلا أن الـHBr بنضيفه على
+
+18
+00:01:45,370 --> 00:01:49,670
+الإيثالين والإضافة عادة تكون في وجود H بلس في
+
+19
+00:01:49,670 --> 00:01:52,630
+الخطوة الأولى الـ double bond بتتفاعل مع الـ H بلس
+
+20
+00:01:52,630 --> 00:01:57,670
+بتعمل رابطة هنا هيدي بدل ما هي CH2 صارت CH3 وبتكون
+
+21
+00:01:57,670 --> 00:02:03,330
+عندي كاربو كتاين الكاربو كتاين بتفاعلمع الـ Br
+
+22
+00:02:03,330 --> 00:02:11,050
+minus بكمل إضافة HBr واضح؟ فعملية الإضافة أو الـ
+
+23
+00:02:11,050 --> 00:02:15,210
+mechanism of addition زيها زي إضافة إيش؟ المية على
+
+24
+00:02:15,210 --> 00:02:20,330
+خطوتين الخطوة الأولى إضافة الـ H plus على ال
+
+25
+00:02:20,330 --> 00:02:24,570
+double bond تكوين Carbocation الخطوة التانية اللي
+
+26
+00:02:24,570 --> 00:02:27,850
+هو تفاعل الـ negative ion مع ال Carbocation
+
+27
+00:02:27,850 --> 00:02:34,230
+واستكمال الإضافةالان لو كان عندى الالكين un
+
+28
+00:02:34,230 --> 00:02:38,690
+-symmetrical زى البروبين على سبيل المثال لاحظوا
+
+29
+00:02:38,690 --> 00:02:41,870
+هذا الكربون حملة 2 هيدروجين زى هذا الكربون حملة 1
+
+30
+00:02:41,870 --> 00:02:49,050
+هيدروجين وبدأ تيجي H بلس تتفاعللاحظوا ان الناتج
+
+31
+00:02:49,050 --> 00:02:53,010
+اللى عندنا هو عبارة عن ناتج Markov-Nikov addition
+
+32
+00:02:53,010 --> 00:02:59,510
+إذا إضافة الـHBr في وجود الحامض في وجود الـH بلس
+
+33
+00:02:59,510 --> 00:03:04,410
+الناتج تبع الإضافة إيش Markov-Nikov addition بمعنى
+
+34
+00:03:04,410 --> 00:03:08,930
+أن الهيدروجين بتيجي هنا والبر بتيجي هنا ملاحظين
+
+35
+00:03:08,930 --> 00:03:14,820
+انتوا هى الجزئينهي الهيدروجين وهي ال PR هذه عبارة
+
+36
+00:03:14,820 --> 00:03:20,880
+عن Markovnikov's addition واضح تماما لكوا إيش معنى
+
+37
+00:03:20,880 --> 00:03:23,780
+Markovnikov's addition الهيدروجين إجت عن اللي حمل
+
+38
+00:03:23,780 --> 00:03:31,560
+الهيدروجين أكتر و ال PR بتكمل التفاؤل الآن بالنسبة
+
+39
+00:03:31,560 --> 00:03:36,360
+ل ال mechanism of this reaction تماما زي ال
+
+40
+00:03:36,360 --> 00:03:40,940
+mechanism of addition of waterUn-symmetrical
+
+41
+00:03:40,940 --> 00:03:45,320
+alkene بمعنى لو انا اتخيلت انه في عندى هذا الـ Un
+
+42
+00:03:45,320 --> 00:03:48,380
+-symmetrical alkene بندفعله ماقاتش PR في وجود H
+
+43
+00:03:48,380 --> 00:03:52,060
+plus اللى بده تتفاعل الاتفاق اللى هي الرابطة
+
+44
+00:03:52,060 --> 00:03:55,180
+الزوجية او الالكترونات بتاعنا الرابطة الزوجية
+
+45
+00:03:55,180 --> 00:03:59,580
+لاحظوا هنا بوضحلكوا الكلام مرة تانية هى الرابطة
+
+46
+00:03:59,580 --> 00:04:02,420
+الزوجية هى الالكترونات اللى بندفعله ماقاتش plus
+
+47
+00:04:02,420 --> 00:04:08,320
+الان اما بده تتحرك الرابطة بهذا الشكل بمعنى ان ال
+
+48
+00:04:08,320 --> 00:04:12,770
+Hبلاستي جهان و هذه الرابطة الزوجية الكاربو كاتيون
+
+49
+00:04:12,770 --> 00:04:15,790
+في هذه الحالة بيتكون هنا شو بيكون هذا الكاربو
+
+50
+00:04:15,790 --> 00:04:21,390
+كاتيون ال primary ولا ال secondary او لو صار
+
+51
+00:04:21,390 --> 00:04:31,150
+التفاعل بطريقة تانية لو صار
+
+52
+00:04:31,150 --> 00:04:36,030
+التفاعل بطريقة تانية وين هتيجي ال edge على هذا
+
+53
+00:04:36,030 --> 00:04:40,330
+الموقع وين هتيجيكوا ال edgeعلى هذا الموقع ..الان
+
+54
+00:04:40,330 --> 00:04:45,510
+كاربو كاتيون حصير primary ..انه المفضل؟ secondary
+
+55
+00:04:45,510 --> 00:04:51,410
+..واضح؟ بناء على ذلك هذا المسار كله مابيصيرش و
+
+56
+00:04:51,410 --> 00:04:55,430
+اللي بيصير عندنا المسار اللي بيكون عبر secondary
+
+57
+00:04:55,430 --> 00:05:00,630
+كاربو كاتيون بيكمل إضافة ال PR هنا ..واضح؟ إذا لو
+
+58
+00:05:00,630 --> 00:05:02,790
+بنقولكوا إيش ال mechanism؟
+
+59
+00:05:09,590 --> 00:05:14,410
+الخطوة الأولى هي إضافة الـ H بلس وتكوين الـ more
+
+60
+00:05:14,410 --> 00:05:22,080
+stable كاربو كتايونتحصيل حاصل إضافة ال PR minus
+
+61
+00:05:22,080 --> 00:05:26,080
+طبعا اللي بيحدد ال regiochemistry، معنى
+
+62
+00:05:26,080 --> 00:05:29,160
+regiochemistry، regio يعني من region، من منطقة، ان
+
+63
+00:05:29,160 --> 00:05:32,780
+وين التفاعل يصير، هنا ولا هنا، وإيش الاتج يكون، هل
+
+64
+00:05:32,780 --> 00:05:37,360
+هو ترى الخطوة الأولى ولا الخطوة التانية؟ الخطوة
+
+65
+00:05:37,360 --> 00:05:41,620
+الأولى، الخطوة التانية تابعة لهذه ال PR هنا مافيش
+
+66
+00:05:41,620 --> 00:05:44,860
+عنده خيار إلا يجيه، لكن ال H لاحظوا ال H كان
+
+67
+00:05:44,860 --> 00:05:50,830
+بالإمكان تيجي زي هيك أو زي هيكواضح الكلام فالتفاعل
+
+68
+00:05:50,830 --> 00:05:55,390
+هنا محكوب بالخطوة الأولى اللى بيؤدي لتكوين ال more
+
+69
+00:05:55,390 --> 00:06:02,130
+stable carbocation هو نجوسيره هذا هو إضافة Markov
+
+70
+00:06:02,130 --> 00:06:07,570
+Nikov إضافة حسب قاعدة Markov Nikov طبعا هذا الكلام
+
+71
+00:06:07,570 --> 00:06:14,510
+ليش بيصير بيحاولوا يوضحوا بمنحنة طاقة بنسميهاهذا
+
+72
+00:06:14,510 --> 00:06:24,170
+الملحنة بيقول الاتي هاي ال H plus بدها تضيف على ال
+
+73
+00:06:24,170 --> 00:06:33,410
+double bond بإمكانها تتسلق قمة قصيرةعشان تكون ال
+
+74
+00:06:33,410 --> 00:06:38,390
+more stable secondary carbocation او قمة عالية
+
+75
+00:06:38,390 --> 00:06:44,010
+عشان تكون ال less stable primary carbocation الان
+
+76
+00:06:44,010 --> 00:06:47,030
+انتوا لو تخيلتوا ان انتوا في قاعر واد و بدكوا
+
+77
+00:06:47,030 --> 00:06:49,630
+تطلعوا عندكوا احتمالين عشان تطلعوا من قاعر هذا
+
+78
+00:06:49,630 --> 00:06:52,790
+الواد ياما بدكوا تطلعوا على هطبة صغيرة يا بدكوا
+
+79
+00:06:52,790 --> 00:06:57,150
+تطلعوا على جبل عالي ايش اللي بتفضلوا؟العطب الصغيرة
+
+80
+00:06:57,150 --> 00:07:01,490
+و كذلك الحال هنا أن الطاقة اللازمة بلزم طاقة
+
+81
+00:07:01,490 --> 00:07:05,550
+للتفاعل لازمة الطاقة اللازمة هنا ال E-activation
+
+82
+00:07:05,550 --> 00:07:10,150
+لتكوين ال secondary carbocation أقل من الطاقة
+
+83
+00:07:10,150 --> 00:07:14,950
+اللازمة لتكوين ال primary carbocation ليش؟ لأن ال
+
+84
+00:07:14,950 --> 00:07:18,590
+secondary carbocation is more stable than the
+
+85
+00:07:18,590 --> 00:07:23,190
+primary carbocation فالتفاعل بأي اتجاه حيصير؟ بهذا
+
+86
+00:07:23,190 --> 00:07:28,760
+الاتجاهواضح ؟ التفاعل يحصل في هذا الاتجاه
+
+87
+00:07:35,760 --> 00:07:41,660
+الـ HPR اللي بيضيف حسب قاعدة Markov Nikon في وجود
+
+88
+00:07:41,660 --> 00:07:46,860
+حامض في وجود H Plus لاحظوا انه في وجود Reagent
+
+89
+00:07:46,860 --> 00:07:51,180
+تاني غير الحامض بيضيف بطريقة تانية بيضيف Anti
+
+90
+00:07:51,180 --> 00:07:55,140
+Markov Nikon Addition إذا مرة تانية لازم تكونوا
+
+91
+00:07:55,140 --> 00:07:59,760
+منتبهين لازم تكونوا منتبهين لما احنا بيجي نسألكوا
+
+92
+00:07:59,760 --> 00:08:06,590
+نقولكوا هاي Double Bond HPRعلى شروط التفاعل إذا
+
+93
+00:08:06,590 --> 00:08:11,030
+كتبنا HBr مع H بلس، ماهو ناتج اللي بيكون في الطول؟
+
+94
+00:08:11,030 --> 00:08:17,410
+Markovnikov addition إذا كتبنا HBr مع مادة بنسميها
+
+95
+00:08:17,410 --> 00:08:23,020
+البروكسايد، بضيف عكس قاعدة Markovnikovواضح؟ إذا
+
+96
+00:08:23,020 --> 00:08:27,720
+مرة تانية عندي إيش؟ الاحتمالين في وجود الحامض حسب
+
+97
+00:08:27,720 --> 00:08:33,540
+قاعدة ماركوفنيكوف في وجود البروكسايد عكس قاعدة
+
+98
+00:08:33,540 --> 00:08:36,760
+ماركوفنيكوف عشان إيه؟ لو أنا بدي أطلع على هذا
+
+99
+00:08:36,760 --> 00:08:42,220
+المثال، هذا المثال هي طرفية double bond في two
+
+100
+00:08:42,220 --> 00:08:47,930
+carbons، أنية اللي عليها الhydrogen أكتر، هذهلو
+
+101
+00:08:47,930 --> 00:08:51,770
+هذا التفاعل قلت بدي أكمله HBr في وجود H بلاس و أين
+
+102
+00:08:51,770 --> 00:08:55,810
+بدي أحط الـ H؟ تحت الـ PR؟ فوق .. فوق .. فوق ..
+
+103
+00:08:55,810 --> 00:08:55,810
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+104
+00:08:55,810 --> 00:08:55,810
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+105
+00:08:55,810 --> 00:08:56,030
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+106
+00:08:56,030 --> 00:08:56,030
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+107
+00:08:56,030 --> 00:08:56,030
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+108
+00:08:56,030 --> 00:08:58,210
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+109
+00:08:58,210 --> 00:08:58,510
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+110
+00:08:58,510 --> 00:09:05,290
+فوق .. فوق .. فوق .. فوق .. فوق .. فوق .. فوق ..
+
+111
+00:09:05,290 --> 00:09:11,280
+فوق .. فوقالـ PR هذه الإضافة إضافة Markovnikov و
+
+112
+00:09:11,280 --> 00:09:14,840
+لا Anti Markovnikov Anti Markovnikov addition
+
+113
+00:09:14,840 --> 00:09:21,320
+واضح؟ إذا الإضافة في وجود البريكسايد is Anti
+
+114
+00:09:21,320 --> 00:09:28,500
+Markovnikov addition طبعا ممكن نحاول نعملتفسير،
+
+115
+00:09:28,500 --> 00:09:32,640
+ممكن نحاول نعمل تفسير، ليش الإضافة في وجود
+
+116
+00:09:32,640 --> 00:09:36,320
+البروكسيد under Markovnikov addition؟ بيروكسيد
+
+117
+00:09:36,320 --> 00:09:40,280
+يعني فوق أكسيد، إيش معناه فوق أكسيد؟ يعني فيه
+
+118
+00:09:40,280 --> 00:09:46,000
+زيادة في الأكسوجين، شكل البروكسيد زي هيك R O O R
+
+119
+00:09:46,930 --> 00:09:51,490
+بدل ما يكون عندى ROR اللى هو ال ether العادى بيكون
+
+120
+00:09:51,490 --> 00:09:57,650
+عندى كام أكسوجينة R O O R هذه الرابطة اللى بين ال
+
+121
+00:09:57,650 --> 00:10:02,230
+oxygens اللى بين ال oxygens فى البروكسايد عبارة عن
+
+122
+00:10:02,230 --> 00:10:07,710
+weak bond بمعنى بقليل من الحرارة أو بضوء الشمس أو
+
+123
+00:10:07,710 --> 00:10:12,470
+من ال UV light بتنكسر هذه الرابطة الرابطة عبارة عن
+
+124
+00:10:12,470 --> 00:10:17,990
+كام إلكترونالان هدولة الإلكترونين لو اتخيلناهم زي
+
+125
+00:10:17,990 --> 00:10:25,070
+هيك اي رابطة ممكن تنكسر نوعين من الكسرممكن تنكسر
+
+126
+00:10:25,070 --> 00:10:30,550
+نوعين من الكسر إما أن يكون الكسر متجانس وإما أن
+
+127
+00:10:30,550 --> 00:10:35,350
+يكون الكسر غير متجانس متجانس بمعنى أن هنا بدو ييجي
+
+128
+00:10:35,350 --> 00:10:39,970
+إلكترون وهنا بدو ييجي إلكترون، إذا هذا الكسر إيش
+
+129
+00:10:39,970 --> 00:10:47,110
+بنسميه؟ homo .. homolytic cleavage إيش يعني
+
+130
+00:10:47,110 --> 00:10:52,220
+homolytic cleavage؟كسر متجانس هان إلكترون وهان
+
+131
+00:10:52,220 --> 00:10:56,320
+إلكترون ممكن بالتأكيد تنكسر بحيث أنه يكونوا
+
+132
+00:10:56,320 --> 00:11:00,340
+إلكترونين على جهة واحدة أو يطلع عيون سالب وهنا
+
+133
+00:11:00,340 --> 00:11:05,430
+مافيش ولا إلكترون يطلع عيون موجببالتأكيد هذا بيصير
+
+134
+00:11:05,430 --> 00:11:12,330
+كثر heterolytic cleavage كثر غير متجانس اذا دائما
+
+135
+00:11:12,330 --> 00:11:16,130
+الاتنين البساطة من ناحية ال mathematics يا بتكون
+
+136
+00:11:16,130 --> 00:11:22,920
+واحد زائد واحد يا بتكون اتنين زائد سفر1 زائد 1
+
+137
+00:11:22,920 --> 00:11:26,620
+يعني لو فيه اتنين شكل بدنا نوزعهم على اتنين كيف
+
+138
+00:11:26,620 --> 00:11:31,060
+بدنا نوزعهم؟ يا هذا بنعطي شكل و هذا شكل هاي توزيع
+
+139
+00:11:31,060 --> 00:11:37,980
+متجانس يا هذا اتنين شكل و هذا سفر و هذا توزيع غير
+
+140
+00:11:37,980 --> 00:11:42,540
+متجانس واضح؟ و النوعين من الكثر بالمناسبة موجودين
+
+141
+00:11:42,540 --> 00:11:49,200
+في الكيميا لكن ان هو من ناحية الطاقةأسهل الكثر
+
+142
+00:11:49,200 --> 00:11:52,780
+المتجانس ولا غير المتجانس؟
+
+143
+00:11:54,690 --> 00:11:59,790
+طيب الان انتوا اي واحدة هي و أختها و الاتنين شاكل
+
+144
+00:11:59,790 --> 00:12:03,590
+ان هو اقبل للنفس انه شاكل هان و شاكل هان و لا
+
+145
+00:12:03,590 --> 00:12:09,290
+اتنين هان و سفرهان ربنا بيحبش الظلم مظبوط ولا لأ؟
+
+146
+00:12:09,290 --> 00:12:14,330
+اذا المتجانس افضل عارفين ليش غير المتجانس مش مفضل؟
+
+147
+00:12:14,330 --> 00:12:18,730
+لأنه في النهاية هتخلوا اتنين minusاللي بيكون حامل
+
+148
+00:12:18,730 --> 00:12:23,830
+إلكترونين بيصير minus واللي حامل إلكترون plus و
+
+149
+00:12:23,830 --> 00:12:29,910
+بعدين بتيجي تفصله plus عن minus ال plus عن ال
+
+150
+00:12:29,910 --> 00:12:33,650
+minus في الدنيا بتجاذب ولا بتفصل؟ طيب لما بدي
+
+151
+00:12:33,650 --> 00:12:39,070
+أفصله؟ بالظبط زي المغناطسين الشمالي و الجنوبي
+
+152
+00:12:39,070 --> 00:12:44,930
+الشمالي و الجنوبي بتجاذبوا لما بتكن تفصلوهمبتكون
+
+153
+00:12:44,930 --> 00:12:48,750
+طاقة، مظبوط ولا لا؟ و ال plus و ال minus، الاصل
+
+154
+00:12:48,750 --> 00:12:53,490
+فيهم التجاذب ولا إنهم يبعدوا عن بعض؟ اه إذا، بناءً
+
+155
+00:12:53,490 --> 00:12:56,830
+على ذلك، لو أنا بدي أعمل كسر غير متجانس في
+
+156
+00:12:56,830 --> 00:13:00,470
+الكيميا، بدي أخلي إشي minus و إشي plus و أقعد أبعد
+
+157
+00:13:00,470 --> 00:13:03,750
+plus عن minus، بدي طاقة، إذا من ناحية طاقة، أنه
+
+158
+00:13:03,750 --> 00:13:08,700
+أفضل؟الكسر المتجنس هذا لا يعني ان الكسر غير
+
+159
+00:13:08,700 --> 00:13:12,800
+المتجنس ما بيصيرش بيصير و هناخد ظروف معينة و نتعلم
+
+160
+00:13:12,800 --> 00:13:18,460
+أشياء فيها كسر غير متجنس الشغلتين موجودين واضح؟
+
+161
+00:13:18,460 --> 00:13:23,790
+على أي حاللاحظوا المعنى هنا انه في هذه الحالة
+
+162
+00:13:23,790 --> 00:13:29,110
+البروكسايد بيعمل homolytic cleavage بيعطينا اتنين
+
+163
+00:13:29,110 --> 00:13:34,450
+RO اي قطعة بتحمل إلكترون واحد شو اتفقنا نسميها
+
+164
+00:13:34,450 --> 00:13:42,080
+free radical جذر حرfree radical واضح؟ ودائما اللي
+
+165
+00:13:42,080 --> 00:13:46,420
+حامل إلكترون واحد بيصير طمعان يحمل كمان إلكترون
+
+166
+00:13:46,420 --> 00:13:50,300
+يعمل رابطة بناء على ذلك هذا ال RORadical بيجي
+
+167
+00:13:50,300 --> 00:13:55,200
+يتفعل مع ال HBR ال HBR في رابطة كم إلكترون بين ال
+
+168
+00:13:55,200 --> 00:14:00,500
+H و ال PR؟ اتنين بياخد H مع إلكترونها بيكوّن ل ROH
+
+169
+00:14:00,500 --> 00:14:05,100
+كحول زائد PR radical واضح؟
+
+170
+00:14:06,110 --> 00:14:10,330
+إذاً الـHPR هذه الرابطة عبارة عن كام إلكترون؟
+
+171
+00:14:10,330 --> 00:14:17,290
+إتنين الـROH بياخد الـH مع إلكترونها شو بده يظل
+
+172
+00:14:17,290 --> 00:14:22,810
+عندى؟ الـPR مع إلكترونها بتكون الـPR Radical نقطة
+
+173
+00:14:22,810 --> 00:14:27,450
+البداية هي الـPR Radical يعني كل هذا الكلام تقديم
+
+174
+00:14:27,450 --> 00:14:31,570
+للقالية اللى بده يتم فيها التفاعل إيش وظيفة إذا
+
+175
+00:14:31,570 --> 00:14:32,890
+البروكسايد؟
+
+176
+00:14:34,710 --> 00:14:40,050
+أنه يُقصر ويأخذ H من الـHPR بيكوّن الـPR Radical،
+
+177
+00:14:40,050 --> 00:14:46,010
+كأنه صارت التفاعل اللي عنده مع الـPR Radical الآن
+
+178
+00:14:46,010 --> 00:14:50,510
+في الـslide اللي جاي بدنا نشوف كيف بيتم التفاعل مع
+
+179
+00:14:50,510 --> 00:14:55,110
+الـPR Radical هو الـPR Radical اللي بيتفاعل مع
+
+180
+00:14:55,110 --> 00:14:58,930
+الالكين، هذه كلها خطوات تحضيرية والدليل عيطنى حتى
+
+181
+00:14:58,930 --> 00:15:03,170
+الآن احنا شوفنا الالكينشوفنا الـ Alkene ولا قاعدين
+
+182
+00:15:03,170 --> 00:15:09,050
+من جهز التفاعل من جهز التفاعل صار عندنا PR Radical
+
+183
+00:15:09,050 --> 00:15:15,010
+واضح؟ صار عندنا PR Radical هذا الـ PR Radical هو
+
+184
+00:15:15,010 --> 00:15:20,910
+الآن اللي بدو يتفاعل مع الـ Alkene الـ Alkene
+
+185
+00:15:20,910 --> 00:15:25,550
+عبارة عن Double Bond و Double Bond كام إلكترون
+
+186
+00:15:25,550 --> 00:15:31,760
+فيها؟لأ اتنين ال buy bond انا بقصد ال buy bond ال
+
+187
+00:15:31,760 --> 00:15:34,460
+sigma bond مابيصيرش عليها التفاعل ال buy bond
+
+188
+00:15:34,460 --> 00:15:41,260
+الرابطة التانية إلكترونين وجاي PR مع إلكترونه إيش
+
+189
+00:15:41,260 --> 00:15:47,120
+بده يعمل؟ بده يعمل رابطة هي PR و إلكترون يا بيجي
+
+190
+00:15:47,120 --> 00:15:51,800
+مع هذا الإلكترون بضيف هنا يا بيجي مع هذا الإلكترون
+
+191
+00:15:51,800 --> 00:15:58,160
+بضيف هنا لاحظوا هنا التفاعل يبدأ بإضافة ماذا؟ال PR
+
+192
+00:15:58,160 --> 00:16:03,740
+قبل شوية في تفاعل إضافة ال H PR مع الحامض كانت
+
+193
+00:16:03,740 --> 00:16:09,220
+الخطوة الأولى إضافة إيش ال H والتانية ال PR .. هنا
+
+194
+00:16:09,220 --> 00:16:16,310
+أول خطوةإضافة ال PR التانية ال H يعني لو بدنا نيجي
+
+195
+00:16:16,310 --> 00:16:20,450
+نسألكوا في مسائل الصح و الغلط اللي مرات بتغلبكم
+
+196
+00:16:20,450 --> 00:16:26,650
+نقولكم ال first step in the addition of HPR to
+
+197
+00:16:26,650 --> 00:16:29,170
+alkenes in the presence of peroxide is the
+
+198
+00:16:29,170 --> 00:16:34,310
+formation of a bond to hydrogen لأ is a formation
+
+199
+00:16:34,310 --> 00:16:41,460
+of a bond to bromineالخطوة الأولى تكوين الرابط مع
+
+200
+00:16:41,460 --> 00:16:46,720
+ال PR والتانية مع ال H عكس الكلام اللى حكيناه قبل
+
+201
+00:16:46,720 --> 00:16:51,360
+شوية الآن ال PR لاحظوا عنده خيارات يبدو يتفعل هن
+
+202
+00:16:51,360 --> 00:16:56,980
+لو اتفعل هن بيكوّل free radical ايش نوعه ال PR
+
+203
+00:16:56,980 --> 00:16:59,600
+اتفعل هن شو نوع هذا ال free radical ال primary ال
+
+204
+00:16:59,600 --> 00:17:04,600
+secondary ال tertiary ال secondary طب لو اتفعل ال
+
+205
+00:17:04,600 --> 00:17:11,910
+PR هن بيكوّل اي free radicalprimary ال PR بفضل
+
+206
+00:17:11,910 --> 00:17:16,990
+يتفاعل على أساس أنه يكون secondary free radical
+
+207
+00:17:16,990 --> 00:17:21,010
+لأن ال stability of free radical زي ال stability
+
+208
+00:17:21,010 --> 00:17:25,950
+of carbocation ال tertiary is more stable than the
+
+209
+00:17:25,950 --> 00:17:31,030
+secondary is more stable than the primary واضح فال
+
+210
+00:17:31,030 --> 00:17:35,930
+PR هنا لما بيكون بده يختار بين نقطين بتفاعل بحيث
+
+211
+00:17:35,930 --> 00:17:43,010
+يكونالـ more stable and free radical شفتوا ليش؟
+
+212
+00:17:43,010 --> 00:17:47,910
+الآن الـ Geometry تبعت التفاعل انحكمت في الخطوة
+
+213
+00:17:47,910 --> 00:17:51,970
+الأولى ولا لأ؟ أكيد لأنه هنا كان عنده اختيارات، يا
+
+214
+00:17:51,970 --> 00:17:55,830
+إي جهان، يا إي جهانة، أخد مكان معين الخطوة
+
+215
+00:17:55,830 --> 00:18:02,030
+الثانية، حيجة ده يتفاعل مع الـHPR، ياخد منها؟ ياخد
+
+216
+00:18:02,030 --> 00:18:10,650
+منها H وإذا أخد من الـHPR Hهي HPR الجزء التاني إذا
+
+217
+00:18:10,650 --> 00:18:14,670
+أخد منها الـ H واتفاعل تهدي الـ H مع إلكترونها
+
+218
+00:18:14,670 --> 00:18:19,170
+هنا، شو بيطلع له؟ الـ PR Radical الـ PR Radical
+
+219
+00:18:19,170 --> 00:18:26,020
+بيبدأ تفاعل من جديد، إذا إحنا هنا أمامسلسلة
+
+220
+00:18:26,020 --> 00:18:30,940
+وتفاعلات الـ Free Radicals عادة هي عبارة عن سلاسل
+
+221
+00:18:30,940 --> 00:18:36,260
+فلو سألتكم عشان أبدأ ال slide السابقة أو اللي
+
+222
+00:18:36,260 --> 00:18:40,980
+قلتلكوا الخطوة التحضيرية أكم من ناحية نظرية على
+
+223
+00:18:40,980 --> 00:18:45,740
+الأقل أكم PR Radical بالزمن بمساعدة البروكسايد
+
+224
+00:18:45,740 --> 00:18:53,660
+واحدواحد لو بس البروكسايد طلع ال free radical واحد
+
+225
+00:18:53,660 --> 00:18:59,520
+و ال free radical اتفاعل هناالواحد التاني من وين
+
+226
+00:18:59,520 --> 00:19:04,220
+بيطلع؟ من الـHBr مرة تانية و مرة تالتة و مرة رابعة
+
+227
+00:19:04,220 --> 00:19:11,500
+إذا بالزمن البروكسيد بكمية كبيرة ولا بكمية بتسميها
+
+228
+00:19:11,500 --> 00:19:17,020
+catalytic amount بكمية صغيرة هذا فرق ال catalyst
+
+229
+00:19:17,020 --> 00:19:20,960
+عن ال reagent ال reagent أو المادة المتفاعل لما
+
+230
+00:19:20,960 --> 00:19:26,800
+يكون فعل شغلتين بيكون لزمنهبيكون لازم تكون النسبة
+
+231
+00:19:26,800 --> 00:19:32,340
+واحد لواحد يعني لو عندى مليون الكين بدي مليون
+
+232
+00:19:32,340 --> 00:19:40,120
+reagent لكن ال catalyst بالزمن منه كمية قليلة جدا
+
+233
+00:19:40,120 --> 00:19:44,520
+لأنه بيقدمهم و بيعود يعمل generation بتولد لحاله
+
+234
+00:19:44,520 --> 00:19:51,430
+يعني أول بيئة ال radical اتولدت بمساعدةالبروكسايد
+
+235
+00:19:51,430 --> 00:19:55,210
+.. مظبوط ولا .. بعد هيك ال PR Radicals لجديدة
+
+236
+00:19:55,210 --> 00:19:59,610
+بتصير تتولد من ال HPR في ال second step بدون
+
+237
+00:19:59,610 --> 00:20:04,590
+مساعدة البروكسايد .. واضح؟ هذه فكرة ال catalyst
+
+238
+00:20:04,590 --> 00:20:09,110
+بساطة لو بدي أشبهلكوا إياها زي أنتوا لما بتولعوا
+
+239
+00:20:09,110 --> 00:20:15,310
+الغاز .. الغاز بيضلوا مولع .. إيش بلزمكوا أنتوا
+
+240
+00:20:15,310 --> 00:20:21,560
+عشان تولعوا الغاز؟ الشرارةهل بلزمكوا تبقوا ملعين
+
+241
+00:20:21,560 --> 00:20:27,400
+جداحة continue واصلة عشان الغاز يبقى ملعق؟ إذا
+
+242
+00:20:27,400 --> 00:20:32,780
+إنتوا بس لازمكوا شرارة واحدة وبعدين تبقوا ماشي
+
+243
+00:20:32,780 --> 00:20:38,280
+تلقائيا لحاله وإحنا بلزمنا من برا البروكسايد بس
+
+244
+00:20:38,280 --> 00:20:38,940
+يعطينا
+
+245
+00:20:48,760 --> 00:20:55,350
+تفاعل متسلسل متكرر متسلسل متكررواضح؟ زي تفاعلات
+
+246
+00:20:55,350 --> 00:20:58,770
+لانشطار النووة وشو اللي بيخلي الجمبلة الذرية
+
+247
+00:20:58,770 --> 00:21:03,450
+وغيرها تعمل كل عمل عميلها؟ ان التفاعل تبعها a
+
+248
+00:21:03,450 --> 00:21:08,070
+chain reaction بيضلوا يكرر نفسه بشكل سريع لحاله
+
+249
+00:21:08,070 --> 00:21:11,870
+وهذا عبارة عن a chain reaction ال first step
+
+250
+00:21:11,870 --> 00:21:15,070
+addition of PR radical and formation of the more
+
+251
+00:21:15,070 --> 00:21:20,450
+stable free radical وال second step reaction with
+
+252
+00:21:20,450 --> 00:21:28,530
+HPRand formation of a new Br radical which starts
+
+253
+00:21:28,530 --> 00:21:34,710
+the reaction again and again واضح؟ هذه هي القالية
+
+254
+00:21:34,710 --> 00:21:38,610
+اللي بتتم فيها التفاعل المحصلة ان إضافة الـHBr في
+
+255
+00:21:38,610 --> 00:21:46,130
+وجود البروكسايد is Anti Markovnikov's addition
+
+256
+00:21:46,130 --> 00:21:52,610
+واضح؟ لحد هنا بننتهي من هذا الجزء بنيجي
+
+257
+00:22:04,030 --> 00:22:07,810
+بنكمل واضح؟ حتى لو عندكوا أشياء تانية بتكون
+
+258
+00:22:07,810 --> 00:22:11,530
+إضافية، مش متأكدة هذا ال slide عندكوا إياها؟ لأ،
+
+259
+00:22:11,530 --> 00:22:18,890
+هاي موجودة، موجودة، موجودة امشوا حوالي تلات صفحات
+
+260
+00:22:18,890 --> 00:22:20,270
+لأ، أخدت ..
+
+261
+00:22:29,230 --> 00:22:36,690
+بناخد تفاعل جديد لل ال الكينز
+
+262
+00:22:36,690 --> 00:22:44,170
+هذا التفاعل اسمه formation of oxiranes او ابوكسايت
+
+263
+00:22:44,170 --> 00:22:50,450
+من ال الكينزواضح؟ تكوين مركبات بيسميها ال oxirans
+
+264
+00:22:50,450 --> 00:22:55,790
+أو ال Epoxides من الalkenes إذا إحنا أخدنا alkene
+
+265
+00:22:55,790 --> 00:23:03,130
+فعلناه مع pear acid، pear إيش معناه pear؟ لأ pear
+
+266
+00:23:03,130 --> 00:23:14,050
+لأ لأال bear ber مش bear bear acid تعني زيادة
+
+267
+00:23:14,050 --> 00:23:17,950
+اتذكروا لما كنتوا تسموا مثلا berichlorate
+
+268
+00:23:19,510 --> 00:23:23,810
+يكون في كام أكسجينة؟ أربع أكسجينات فال bear هنا
+
+269
+00:23:23,810 --> 00:23:28,270
+تعني الزيادة bear acid معناه حامض فيه أكسجين
+
+270
+00:23:28,270 --> 00:23:32,670
+زيادة، هاي معناه bear acid، bear acid الحامض اللي
+
+271
+00:23:32,670 --> 00:23:36,850
+فيه أكسجين زيادة، بشكل عام صيغة الحامض العضوي إيش
+
+272
+00:23:36,850 --> 00:23:42,990
+هي؟ R C double bond O OH
+
+273
+00:23:44,430 --> 00:23:53,410
+الحامض الفيزيائي بيكون RCOOOH
+
+274
+00:23:53,410 --> 00:24:01,490
+فالحامض مثل الخل مثلا CH3COO
+
+275
+00:24:03,700 --> 00:24:10,640
+حمض العضوى الوظيفة
+
+276
+00:24:10,640 --> 00:24:11,220
+للحمض
+
+277
+00:24:14,320 --> 00:24:20,440
+بصير زيادة أكسوجينة زي الميه، الميه كانت H2O
+
+278
+00:24:20,440 --> 00:24:28,120
+واحدة، لما صارت hydrogen peroxide، إيه صارت؟ تنتين
+
+279
+00:24:28,120 --> 00:24:32,720
+أكسوجين، pear، مشقولنا hydrogen peroxide، فكلمة
+
+280
+00:24:32,720 --> 00:24:37,060
+pear إيش بتعني؟ زيادة أكسوجينةفإذا أنا فعلت ال
+
+281
+00:24:37,060 --> 00:24:41,640
+الكين مع bare acid يعني حامض في أكسجينة زيادة
+
+282
+00:24:41,640 --> 00:24:46,640
+بييجي بيكوّنلي حلقة ثلاثية متصلة بالأكسجين بهذا
+
+283
+00:24:46,640 --> 00:24:50,520
+الشكل، هذه الحلقة الثلاثية المتصلة بالأكسجين بهذا
+
+284
+00:24:50,520 --> 00:24:59,000
+الشكل بنسميها حلقة Oxarionأيش اسمها؟ Oxirane واضح؟
+
+285
+00:24:59,000 --> 00:25:06,540
+كمجموعة وظيفية كل الحلقات اللي فيهم حلقة ثلاثية
+
+286
+00:25:06,540 --> 00:25:11,940
+متصلة بالأكسجين بيقولولها epoxide لاحظوا في عندي
+
+287
+00:25:11,940 --> 00:25:18,380
+اسم المركب تحديدا وفي عندي اسم العائلة زي تماما ما
+
+288
+00:25:18,380 --> 00:25:26,810
+بنقول ان ال ROHكحول هذا اسم عائلة لكن لو جيت قولت
+
+289
+00:25:26,810 --> 00:25:34,730
+CH3OH ميثانول هذا اسم إيش الفرد واضح؟ الآن العائلة
+
+290
+00:25:34,730 --> 00:25:40,530
+الحلقة الثلاثية اللي فيها ال oxygen اسمها Epoxide
+
+291
+00:25:41,340 --> 00:25:46,200
+العائلة إيش اسمها؟ Epoxides كل الحلقات الثلاثية
+
+292
+00:25:46,200 --> 00:25:48,620
+اللي في الدنيا اللي فيها أكسوجين طبعا ممكن هنا
+
+293
+00:25:48,620 --> 00:25:53,920
+يصير R وR وR وR وشغلات كتيرة كلها كعائلات إيش
+
+294
+00:25:53,920 --> 00:25:59,140
+اسمها؟ Epoxides الآن الأفراد تبعونها زي ما في عند
+
+295
+00:25:59,140 --> 00:26:04,840
+عائلة الكحول وفي منها إيش؟ أفراد أبسط فرد فيهم لما
+
+296
+00:26:04,840 --> 00:26:10,280
+هدول الأربعة يكونوا Hydrogens إيش اسمه؟Oxirane
+
+297
+00:26:10,280 --> 00:26:15,040
+فالـ Oxirane هو اسم الحلقة المُركّب اللي فيه كلهم
+
+298
+00:26:15,040 --> 00:26:20,160
+هيدروجينز برضه هذا الفرد له اسم تاني هذا المُركّب
+
+299
+00:26:20,160 --> 00:26:26,420
+كله لما يكون أربعة هيدروجينز شو اسمه اثيلين لما
+
+300
+00:26:26,420 --> 00:26:32,460
+ييجي يعمل مع الأكسجل المُركّب بنسميه أثيلين أكسيد
+
+301
+00:26:32,460 --> 00:26:36,940
+أكسيد الأثيلين لأن هذا اسمه أثيلين وعمل مع الأكسجل
+
+302
+00:26:36,940 --> 00:26:43,800
+فهذا المُركّباللي فيه أربعة هيدروجين اسمه أكزيرين
+
+303
+00:26:43,800 --> 00:26:49,320
+أو أكسيد
+
+304
+00:26:49,320 --> 00:26:55,080
+الأثيلين ليش أكسيد الأثيلين؟ لأنه إجانة من تفاعل
+
+305
+00:26:55,080 --> 00:27:00,180
+الأثيلين مع الأكسجين، واضح؟ العائلة ككل إيش اسمها؟
+
+306
+00:27:00,180 --> 00:27:05,420
+أكسيد الأثيلين، لكن المركّب نفسه يا بسميه أكزيرين،
+
+307
+00:27:05,420 --> 00:27:11,650
+يا بسميه أكسيد الأثيلينالاسمين هما اسمين لا فرق
+
+308
+00:27:11,650 --> 00:27:18,090
+الان بإمكانكوا عادة تصيروا بسهولة تستوعبوا لو يا
+
+309
+00:27:18,090 --> 00:27:23,250
+ترى الألكين اللى كان عندى ماكنش إثيلين كان
+
+310
+00:27:23,250 --> 00:27:29,250
+بروبيلين وفعلناه وعملنا double bond بس هذه كانت
+
+311
+00:27:29,250 --> 00:27:33,970
+CH3 يعني بروبيلين او بروبينواجهة المُركّب الناتج،
+
+312
+00:27:33,970 --> 00:27:40,550
+شو هسميه؟ إفروبيين أكسايد، لو كان هذا بيوتين،
+
+313
+00:27:40,550 --> 00:27:45,030
+بيوتين أكسايد، لو كان بنتين، بنتين أكسايد، شايفين
+
+314
+00:27:45,030 --> 00:27:48,930
+إنتوا كيف؟
+
+315
+00:27:48,930 --> 00:27:49,590
+واضح؟
+
+316
+00:27:53,120 --> 00:27:57,800
+هنا بنعطي عدة أمثلة في كل الأحوال بتلاحظوا ال ..
+
+317
+00:27:57,800 --> 00:28:03,480
+ال bare acid ال bare acid RC ضب ال bond O O و O H
+
+318
+00:28:03,480 --> 00:28:07,300
+يعني كله أكم O لو كنا بدنا نجمعهم تلاتة تلاتة
+
+319
+00:28:07,300 --> 00:28:10,980
+الحامض العضو الطبيعي كام O؟ تنتين تنتين هذا bare
+
+320
+00:28:10,980 --> 00:28:15,740
+acid تلاتة في كل الأحوال لما بدنا نفعله بده تيجي O
+
+321
+00:28:15,740 --> 00:28:21,020
+و تعمل حلقة ثلاثية هن أو O تعمل حلقة ثلاثية هن أو
+
+322
+00:28:21,020 --> 00:28:26,370
+O تعمل حلقة ثلاثية هنواضح؟ يعني لو قلنا لكوا أكمل
+
+323
+00:28:26,370 --> 00:28:30,050
+المعادلة هان أو هان أو هان كتبنا لكوا صيغة زي هيك
+
+324
+00:28:30,050 --> 00:28:34,190
+ولا كتبنا لكوا RCO3H ولا كتبنا لكوا pear acid في
+
+325
+00:28:34,190 --> 00:28:38,470
+النهاية بدكوا تكونولنا حلقة ثلاثية الآن هذه
+
+326
+00:28:38,470 --> 00:28:41,950
+المركبات لو قلتلكوا هدول المركبات كلهم ما العائلة
+
+327
+00:28:41,950 --> 00:28:47,350
+الجامعة لهم they are epoxides واضح؟ كل واحد فيهم
+
+328
+00:28:47,350 --> 00:28:55,070
+إله اسم كل واحد فيهم إله اسماسمه ممكن اشتقه من اسم
+
+329
+00:28:55,070 --> 00:28:58,110
+المركب الاصلي يعني مثلا هذا المركب الاصلي اسمه
+
+330
+00:28:58,110 --> 00:29:05,610
+styrene هداك ايش بيصير Styrene Oxide هذا المركب
+
+331
+00:29:05,610 --> 00:29:12,850
+اسمه اذا بتذكروا اخدناه Isobutene هذا Isobutene
+
+332
+00:29:12,850 --> 00:29:19,410
+اذا هداك المركب Isobutene Oxide هذا Cyclohexane او
+
+333
+00:29:19,410 --> 00:29:25,880
+Ethyl Cyclohexaneالحلقة نفسها Cyclohexane مظبوط
+
+334
+00:29:25,880 --> 00:29:28,820
+ولا لأ؟ إذا المركب اللي هناك إيش بده يصير؟
+
+335
+00:29:28,820 --> 00:29:35,020
+Cyclohexane Oxide واضح؟ الآن حد بيجي يقولكوا شو
+
+336
+00:29:35,020 --> 00:29:38,980
+هالعائلة؟ شو هالمركبات هدولة؟ they are epoxides ف
+
+337
+00:29:38,980 --> 00:29:43,780
+epoxide اسم عائلة العائلة في منها إيش؟ أفراد
+
+338
+00:29:43,780 --> 00:29:51,690
+كثيرين مشاك حال الدنيا ولا لأ؟طيب ايش فائدات ..
+
+339
+00:29:51,690 --> 00:29:55,510
+ايش فائدات هذه ال Epoxides؟ هذه ال Epoxides عبارة
+
+340
+00:29:55,510 --> 00:29:59,890
+عن حلقة ثلاثية سبق اتفقنا احنا ان الحلقة الثلاثية
+
+341
+00:29:59,890 --> 00:30:05,510
+حلقة مترايحة من ناحية ال geometry ولا مضغوطة؟
+
+342
+00:30:05,510 --> 00:30:09,470
+مضغوطة جدا، ليش؟ لأن الزاوية تاعتها المفروض 60 60
+
+343
+00:30:09,470 --> 00:30:15,560
+60 و الزاوية المريحة لكاربون كدهش؟مية وتسعة و نص
+
+344
+00:30:15,560 --> 00:30:19,200
+مية وتسعة و نص بناء على ذلك هذه الحلقة بتفتح
+
+345
+00:30:19,200 --> 00:30:25,460
+بسهولة يعني هذا ال Epoxide لو انا اجيت فعلته مع اي
+
+346
+00:30:25,460 --> 00:30:30,440
+مادة معطية للإلكترونات فيها إلكترونات بنسميها
+
+347
+00:30:30,440 --> 00:30:33,340
+Nucleophile ليش بدى افعله مع مادة فيها إلكترونات
+
+348
+00:30:33,340 --> 00:30:36,460
+السبب بسيط ان ال oxygen is electronegative بتكون
+
+349
+00:30:36,460 --> 00:30:39,820
+partially negative ال carbon اللي هنا شو بتصير؟
+
+350
+00:30:40,490 --> 00:30:45,270
+partially positive بناء على ذلك لو اي إش فيه
+
+351
+00:30:45,270 --> 00:30:48,470
+إلكترونات بتفاعل هنا بيكسر هذه الرابطة بيفتح
+
+352
+00:30:48,470 --> 00:30:54,950
+الحلقة واضح مثلا الميه فيها إلكترونات مش فيها
+
+353
+00:30:54,950 --> 00:30:59,190
+أزواج إلكترونات على أكسجين زوجين من الإلكترونات مش
+
+354
+00:30:59,190 --> 00:31:04,090
+واحد احنا بيكفينا واحد الأن هذه الميه بتيجي
+
+355
+00:31:04,090 --> 00:31:09,280
+بتتفاعل هنابتفتح .. بتعمل O .. O minus بتصير OH
+
+356
+00:31:09,280 --> 00:31:13,960
+فلاحظوا أن الأكسجين تبع الابوكسايد بتتحول إلى إيش؟
+
+357
+00:31:13,960 --> 00:31:18,240
+إلى OH و بتضيف الميه طبعا الميه لما تضيف .. شو
+
+358
+00:31:18,240 --> 00:31:25,380
+بتضيف منها؟ OH الأن لو إجت فعلت مع H X هنا كأنه
+
+359
+00:31:25,380 --> 00:31:29,180
+عندك X minus ال X minus هجمت هنا هذه بتفتح ..
+
+360
+00:31:29,180 --> 00:31:36,440
+بتصير O و بتاخد ال H بتصيرأو اتش وهنا إيجي عنده ال
+
+361
+00:31:36,440 --> 00:31:41,620
+X minus نفس الأشياء لو أخدت مع R O minus ال R O
+
+362
+00:31:41,620 --> 00:31:46,340
+minus بده تفتح هنا في الآخر لما بتضيف ميطار بتصير
+
+363
+00:31:46,340 --> 00:31:52,720
+R O H إذا المفروض يصار واضح عندكم شكل التفاعل أن
+
+364
+00:31:52,720 --> 00:31:59,580
+الحلقة بتفتح ال O تعتها بتصير O H وبيضيف عنده
+
+365
+00:31:59,580 --> 00:32:07,040
+المادة اللي فيهاالأكترونات اللي فعلناها هذا أي
+
+366
+00:32:07,040 --> 00:32:10,240
+مادة فيها أكترونات احنا بنسميها نيوكليوفايل
+
+367
+00:32:10,240 --> 00:32:14,480
+لنيوكليوفايل الشيء اللي فيه أكترونات وبيتفعل من
+
+368
+00:32:14,480 --> 00:32:17,940
+خلال أكتروناته هنا ال O فيها أكترونات ال X فيها
+
+369
+00:32:17,940 --> 00:32:22,200
+أكترونات ال R O minus فيها أكترونات إذا كأنه ال
+
+370
+00:32:22,200 --> 00:32:25,520
+reaction of epoxides هذا with إيش؟ with
+
+371
+00:32:25,520 --> 00:32:31,240
+نيوكليوفايل كل هدولة بنسميهم احنا إيش؟ نيوكليوفايل
+
+372
+00:32:31,240 --> 00:32:33,780
+إيش معنى نيوكليوفايل؟
+
+373
+00:32:36,730 --> 00:32:43,490
+مش محبلة الإلكترونات، هو فيه إلكترونات، اللي فيه
+
+374
+00:32:43,490 --> 00:32:49,210
+إلكترونات بيكون محبلة إيش؟ للموجب، و أين يوجد
+
+375
+00:32:49,210 --> 00:32:57,230
+الموجب؟ في النوارالنواء إيش بتكون؟ موجبة عشان كلمة
+
+376
+00:32:57,230 --> 00:33:02,010
+file معناها باللاتيني محب الان ال nucleo جاية من
+
+377
+00:33:02,010 --> 00:33:07,750
+وين؟ من ال nucleus من النواء الموجبة إذا هو كأنه
+
+378
+00:33:07,750 --> 00:33:12,370
+معناه nucleophile محب file معناها محب و ال nucleo
+
+379
+00:33:12,370 --> 00:33:17,150
+النواء الموجبة محب للنواء الموجبة اللي محب للموجبة
+
+380
+00:33:17,150 --> 00:33:23,940
+إيش بتكون؟ سالك أو يحمل إلكتروناتطيب لو بدنا نقول
+
+381
+00:33:23,940 --> 00:33:29,580
+في إشي بيكون محبلة السالب إيش بدنا نسميه؟
+
+382
+00:33:29,580 --> 00:33:34,540
+electrophile إيش معناه electrophile؟ محبلة
+
+383
+00:33:34,540 --> 00:33:39,760
+الإلكترونات فال electrophile المحبلة الإلكترونات
+
+384
+00:33:39,760 --> 00:33:40,340
+بيكون
+
+385
+00:33:42,860 --> 00:33:50,040
+والنيوكليوفايل المحب للموجة بيكون سالب أو أزواج من
+
+386
+00:33:50,040 --> 00:33:54,060
+الإلكترونات يعني يمثل كثافة إلكترونية ففهمتوا في
+
+387
+00:33:54,060 --> 00:33:58,140
+ال organic chemistry إيش معناه نيوكليوفايل السالب
+
+388
+00:33:58,140 --> 00:34:01,680
+اللي بيتفعل مع حاجة موجة بقى؟ إيش معناه إلكتروفايل
+
+389
+00:34:01,680 --> 00:34:06,200
+الموجة اللي بيتفعل مع حاجة سالبة؟ الآن هذه
+
+390
+00:34:06,200 --> 00:34:11,260
+الكربونة إيش مالها؟موجبة بناء على ذلك بتكون قاعدة
+
+391
+00:34:11,260 --> 00:34:15,900
+تستنى ييجي عليها غيش، يعني لو حاطيتلكوا بس سؤال زي
+
+392
+00:34:15,900 --> 00:34:20,480
+هيك و قولتلكوا ساهم و انا فراه، هذا الموجب لازم
+
+393
+00:34:20,480 --> 00:34:23,580
+اللي بيجي عليه ايش يكون؟ سالم، لازم اللي بيجي عليه
+
+394
+00:34:23,580 --> 00:34:30,310
+يكون نيوكليوفايلالماء مثال للنيوكليوفايل X- مثل CR
+
+395
+00:34:30,310 --> 00:34:35,830
+- أو PR- مثل النيوكليوفايل الكحول ROH مثل
+
+396
+00:34:35,830 --> 00:34:40,890
+النيوكليوفايل الكحول منزوع الهيدروجين RO- مثل
+
+397
+00:34:40,890 --> 00:34:45,870
+النيوكليوفايل في كل الأحوال الأمر بسيط جدا تفاعل
+
+398
+00:34:45,870 --> 00:34:49,110
+النيوكليوفايل مع الابوكسايد بيجيب النيوكليوفايل
+
+399
+00:34:49,110 --> 00:34:51,650
+على كاربون و بتفتح الحلقة من الجهة التانية بتصير
+
+400
+00:34:51,650 --> 00:34:57,180
+OHصعب ولا سهل؟ إذا لليوكليوفايل بدي ييجي هذا
+
+401
+00:34:57,180 --> 00:35:03,260
+الحركة تفتح تصيب OH هملاحظين نفس ال trend نفس ال
+
+402
+00:35:03,260 --> 00:35:09,320
+trend يعني بنتقدر نقول ان يوكليوفايل open the
+
+403
+00:35:09,320 --> 00:35:16,580
+epoxide ring forming an alcohol or an OH compound
+
+404
+00:35:16,580 --> 00:35:20,550
+مظلوط ولا لأ؟لـ Nucleophiles بتتفاعل مع ال
+
+405
+00:35:20,550 --> 00:35:26,850
+Epoxides بتفتح الحلقة بتكوينها مركبات فيها كحول أو
+
+406
+00:35:26,850 --> 00:35:34,630
+فيها OH واضح؟ وهذه هي الميكانيزم للتفاعل في هذا ال
+
+407
+00:35:34,630 --> 00:35:38,930
+slide وبننهي
+
+408
+00:35:38,930 --> 00:35:43,530
+في هذا ال slide زي
+
+409
+00:35:43,530 --> 00:35:49,110
+ما بتلاحظوا هنا بتلاحظوا ان الميهالميّه وين
+
+410
+00:35:49,110 --> 00:35:54,270
+بتهاجم؟ على الكربون لأن الميّه فيها إلكترونات
+
+411
+00:35:54,270 --> 00:36:01,250
+والكربون موجبة هادة لما بتتحرك زيك بتصير OH plus
+
+412
+00:36:01,250 --> 00:36:04,770
+هي بتكون أخدت ال H من الأول بفتح في النهاية بعدين
+
+413
+00:36:04,770 --> 00:36:11,630
+ال OH إذا الهجوم بيكون من السالب على الموجبةهذا
+
+414
+00:36:11,630 --> 00:36:16,410
+اللي أنا بابنك، الهجوم من السالب على الموجب، بيصير
+
+415
+00:36:16,410 --> 00:36:20,250
+عنده ring opening، كل هذه عبارة عن أمثلة على
+
+416
+00:36:20,250 --> 00:36:23,770
+الموضوع بنقف عند formation of diodes
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c976362be721fa6eeeef28168571b72b334f50d0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/VV3OIJsKgxM_postprocess.srt
@@ -0,0 +1,2028 @@
+1
+00:00:07,730 --> 00:00:11,930
+اليوم بنكمل ان شاء الله في موضوع الكحولات ال
+
+2
+00:00:11,930 --> 00:00:19,490
+alcohols طبعا كلكوا عارفين انه احنا بدأنا
+
+3
+00:00:19,490 --> 00:00:24,250
+كما يبدأ عادة بدراسة اي عائلة من المراكبات الأضوية
+
+4
+00:00:24,250 --> 00:00:30,350
+بالتعريف فيها بتسميتها بخواصها الفيزيائية بطرق
+
+5
+00:00:30,350 --> 00:00:35,810
+تحضيرها يمكن من طرق التحضير حكينا طريقة واحدة اللي
+
+6
+00:00:35,810 --> 00:00:41,910
+هي تعتبرطريقة تجارية و خاصة بالإيثانول اللي هي
+
+7
+00:00:41,910 --> 00:00:46,310
+طريقة ال fermentation أو التخمير اتكلمنا عنها لكن
+
+8
+00:00:46,310 --> 00:00:53,450
+كطرق مختبر الطريقة المشهورة اكثر في المختبر هي
+
+9
+00:00:53,450 --> 00:01:02,170
+طريقة الإضافة على الalkenes انه احنا نضيف على
+
+10
+00:01:02,170 --> 00:01:03,730
+الalkene ميه
+
+11
+00:01:06,030 --> 00:01:10,090
+بتكون تتذكروا شغلة .. بتكون تتذكروا شغلة أنه احنا
+
+12
+00:01:10,090 --> 00:01:16,070
+هذه الطريقة طريقة الإضافة على الالكين أخدناها و
+
+13
+00:01:16,070 --> 00:01:23,710
+بتمشي بتلت طرق مختلفة اعتمادا على نوع المتفاعل
+
+14
+00:01:23,710 --> 00:01:26,730
+اللي عندنا طبعا لما بنضيف على الكين بالذات لما
+
+15
+00:01:26,730 --> 00:01:31,410
+يكون un symmetric بيصير عندنا possibility ل Markov
+
+16
+00:01:31,410 --> 00:01:36,450
+-Nikov addition و Anti Markov-Nikov additionطبعا
+
+17
+00:01:36,450 --> 00:01:39,950
+حكينا احنا سابقا انه وقتاش بيصير ال markovnikov's
+
+18
+00:01:39,950 --> 00:01:45,550
+addition قولنا ممكن طريقة الإضافة في وجود الميه في
+
+19
+00:01:45,550 --> 00:01:50,610
+وجود الحامض و الطريقة التانية بيقول ما .. اللي هي
+
+20
+00:01:50,610 --> 00:01:56,530
+الإضافة في وجود ال BH3 و بعدين H2O2 و الطريقة
+
+21
+00:01:56,530 --> 00:02:02,650
+التالتة الإضافة في وجود ال mercury plus ميركوريك
+
+22
+00:02:02,650 --> 00:02:07,790
+أسيتيت و كل هذا الكلام واضحوكل طريقة بتعطيني نواة
+
+23
+00:02:07,790 --> 00:02:11,650
+شكل ومواصفات شكل هنا Markov-Nikov addition هنا
+
+24
+00:02:11,650 --> 00:02:14,970
+Anti-Markov-Nikov addition هنا Markov-Nikov
+
+25
+00:02:14,970 --> 00:02:19,110
+addition بتفرق الأولى عن التالتى ان هنا في
+
+26
+00:02:19,110 --> 00:02:23,930
+possibility of rearrangement كل هذا الكلام بتكونوا
+
+27
+00:02:23,930 --> 00:02:31,650
+متذكرينه لأنه شرح بالتفصيل تفاعلات الكحولات الان
+
+28
+00:02:31,650 --> 00:02:38,810
+reactions of alcoholsالتفاعل الأول خلينا نقول نوعا
+
+29
+00:02:38,810 --> 00:02:44,930
+ما معاكس للتفاعل السابق .. معاكس للتفاعل السابق
+
+30
+00:02:44,930 --> 00:02:49,990
+بمعنى أنا في الطريقة السابقة كان يكون عندى ال keen
+
+31
+00:02:49,990 --> 00:02:57,010
+أضيف عليه ما يصير alcohol، الآن بإمكاني ال alcohol
+
+32
+00:02:57,010 --> 00:03:03,730
+أنزع منه ما يصير ال keenواضح؟ يعني العملية يمكن أن
+
+33
+00:03:03,730 --> 00:03:08,210
+تتم بشكل عكسي كيف بتتم هذه العملية اللي هي بيسموها
+
+34
+00:03:08,210 --> 00:03:13,010
+acidic dehydration اش يعني dehydration؟
+
+35
+00:03:13,010 --> 00:03:18,290
+dehydration يعني نزع الماء دائما كلمة dehydration
+
+36
+00:03:18,290 --> 00:03:22,810
+معناها نزع الماء وانتوا طبعا كلكوا ان شاء الله
+
+37
+00:03:22,810 --> 00:03:28,460
+أمهات المستقبل لما يصير عندكم ولاد صغاروتبقوا
+
+38
+00:03:28,460 --> 00:03:31,960
+تروحوا فيهم على المستشفى دائما بتلاقوا الأطباء
+
+39
+00:03:31,960 --> 00:03:35,760
+بيقولوا هذا الولد عنده dehydration إيش يعني ال
+
+40
+00:03:35,760 --> 00:03:39,940
+dehydration؟ انه عنده جفاف .. انه عنده جفاف لإن
+
+41
+00:03:39,940 --> 00:03:44,720
+الميه كلها طلعت منه فبتكون تعطوه إيش؟ محليل تعوضية
+
+42
+00:03:44,720 --> 00:03:51,040
+واضح؟الان ال dehydration هذه العملية دائما بتتم في
+
+43
+00:03:51,040 --> 00:03:56,080
+وجود حامض وبالتسخين العملية بتتم في وجود حامض
+
+44
+00:03:56,080 --> 00:04:00,920
+وبالتسخين طيب لو اجينا قولنا ايش بالظبط وظيفة
+
+45
+00:04:00,920 --> 00:04:05,940
+الحامض ايش بالظبط وظيفة الحامض ليش انا بدي اضيف
+
+46
+00:04:05,940 --> 00:04:12,140
+حامض عشان اتم هذه العملية اذا انتوا بتطلعوا لما
+
+47
+00:04:12,140 --> 00:04:17,810
+بدوا يتم ال dehydration بتطلع OH-أو اتش بلاس في
+
+48
+00:04:17,810 --> 00:04:23,370
+النهاية بيطلع شكل جزء ماء لكن الإشكالية أن الـ OH-
+
+49
+00:04:23,370 --> 00:04:28,950
+لحالها الـ OH- لحالها هذه المجموعة شايفينها هذه
+
+50
+00:04:28,950 --> 00:04:33,210
+المجموعة لو طلعت بده تحمل إلكترونات على الأكسوجين
+
+51
+00:04:33,210 --> 00:04:39,410
+الصغير والأكسوجين مش قدرة أنه يحمل إلكتروناتذرة
+
+52
+00:04:39,410 --> 00:04:43,450
+صغيرة مش كتير بتقدر تحمل إلكترونات إلا يجيها
+
+53
+00:04:43,450 --> 00:04:47,090
+مساعدة خارجية ممكن البعض منكوا يقول طب ما هو في NA
+
+54
+00:04:47,090 --> 00:04:53,610
+OH مثلا عندي NA plus OH minus أه بس ال OH minus
+
+55
+00:04:53,610 --> 00:04:58,560
+هنا جزء منها رايح بالتجاذب مع ال إيشالان A plus
+
+56
+00:04:58,560 --> 00:05:03,600
+لكن انه يطلع عندي OH minus لحالها مشكلة ال O H
+
+57
+00:05:03,600 --> 00:05:07,060
+مابتقدرش تحمل الإلكترونات عشانك احنا متعودين في
+
+58
+00:05:07,060 --> 00:05:12,040
+الكيميا نقول عن مجموعة ال O H انه is a bad leaving
+
+59
+00:05:12,040 --> 00:05:16,640
+group ايش
+
+60
+00:05:16,640 --> 00:05:21,300
+يعني bad leaving group يعني مجموعة مغادرة سيئة مش
+
+61
+00:05:21,300 --> 00:05:27,430
+هي بده تطلعمابتطلعش بسهولة لازم اعمل طرق معينة
+
+62
+00:05:27,430 --> 00:05:34,250
+عشان اخلي هذه المجموعة ال OH- تطلع لانها مابتقدرش
+
+63
+00:05:34,250 --> 00:05:38,450
+تحمل إلكترونات شو هي العملية اللي بنعملها احنا
+
+64
+00:05:38,450 --> 00:05:42,990
+عشان نخلي ال OH- تطلع بنجي للتفاعل في الخطوة
+
+65
+00:05:42,990 --> 00:05:48,800
+الأولى بنضيفحامض H plus الان ال H plus هذا خلوه
+
+66
+00:05:48,800 --> 00:05:52,440
+يجى يتفاعل مع زوج الالكترونات اللى موجود عندنا هنا
+
+67
+00:05:52,440 --> 00:05:59,720
+و يعمل ميه بعد هيك اذا صار مجموعة بدها تطلع ايش
+
+68
+00:05:59,720 --> 00:06:03,620
+هتكون المجموعة اللى بدها تطلع OH minus
+
+69
+00:06:07,180 --> 00:06:13,120
+الـ H2O في هذه الحالة تظهر على شكل جزء متعادل بزام
+
+70
+00:06:13,120 --> 00:06:16,280
+جزء متعادل مش حامل شحنة مش عنده مشكلة المشكلة وين
+
+71
+00:06:16,280 --> 00:06:23,320
+انه تظهر مجموعة صغيرة حاملة شحنة ومش قادرة تحمل مش
+
+72
+00:06:23,320 --> 00:06:28,120
+قادرة تحمل هذه الشحنة ولذلك دائما التفاعلات تبعت
+
+73
+00:06:28,120 --> 00:06:34,050
+ال alcohols أول ما بدي أبدأ فيهابدي أحول ال bad
+
+74
+00:06:34,050 --> 00:06:39,150
+leaving group اللي هي ال OH إلى ال good leaving
+
+75
+00:06:39,150 --> 00:06:42,270
+group ال good leaving group هي الميه كيف بتتم هذا
+
+76
+00:06:42,270 --> 00:06:47,470
+الكلام؟ من خلال إضافة الحامض إذا نعرفنا إيش وظيفة
+
+77
+00:06:47,470 --> 00:06:51,950
+الحامض the function of the acid is to convert the
+
+78
+00:06:51,950 --> 00:06:57,330
+bad leaving group to a good leaving group ليش هذه
+
+79
+00:06:57,330 --> 00:07:01,840
+كانت bad؟ لأنها chargednegative charge، it cannot
+
+80
+00:07:01,840 --> 00:07:04,480
+carry the negative charge، ليش هذه good living
+
+81
+00:07:04,480 --> 00:07:09,100
+group؟ لأنها neutral، لأنها متعادلة، مش حاملة،
+
+82
+00:07:09,100 --> 00:07:11,800
+شحنة، واحد مافيش عنده مصايب ولا واحد فيه عنده
+
+83
+00:07:11,800 --> 00:07:15,560
+مصايب، مين بيكون متريح أكتر؟ المتعادل، اللي مافيش
+
+84
+00:07:15,560 --> 00:07:19,140
+عنده مصايب، الآن هذه خطوة تحضيرية، احنا
+
+85
+00:07:19,140 --> 00:07:23,680
+مابنعتبرهاش خطوة من ال mechanism، ليش؟ لأن ال
+
+86
+00:07:23,680 --> 00:07:30,690
+mechanism هي عملية حذفالميّة في النهاية وتكوين الـ
+
+87
+00:07:30,690 --> 00:07:35,850
+double bond هل تم فيها حد في إشي لحد الآن؟ لأ بس
+
+88
+00:07:35,850 --> 00:07:38,330
+أنا عملت ال bad living group و ال good living
+
+89
+00:07:38,330 --> 00:07:41,250
+group عشانك هذا الخطوة ليست جزء من الميكانيزم طب
+
+90
+00:07:41,250 --> 00:07:45,130
+ها إيش الميكانيزم؟ الميكانيزم الآن لما تيجي تطلع
+
+91
+00:07:45,130 --> 00:07:50,560
+الاتش هذه لحالة بدون زوج الإلكترونات اتش plusواضح؟
+
+92
+00:07:50,560 --> 00:07:54,340
+الـ double bond بتتحرك بهذا الشكل بيفقد جزء الميّه
+
+93
+00:07:54,340 --> 00:07:59,520
+لاحظوا معاه إيش بتكون بهذه الحالة هدولة حركة بتطلع
+
+94
+00:07:59,520 --> 00:08:04,820
+ال H ال double bond بتتحرك الميّه كلها بتفقد بيصير
+
+95
+00:08:04,820 --> 00:08:10,080
+عند ال alkene زاد ال H plus زاد الميّه في النهاية
+
+96
+00:08:10,080 --> 00:08:15,050
+إيش اللي بتلاحظوا؟ أنه تم فقد الماءمظبوط ولا لأ؟ و
+
+97
+00:08:15,050 --> 00:08:19,710
+ال H plus اللي استعملت هنا عوضت طلعت ولا لأ؟ إذا
+
+98
+00:08:19,710 --> 00:08:24,090
+إيش بنقول عن ال H plus هنا اللي دخلت في التفاعل و
+
+99
+00:08:24,090 --> 00:08:28,950
+عوضت طلعت catalyst H plus is a catalyst هم لاحظين
+
+100
+00:08:28,950 --> 00:08:37,400
+هنا catalyst عامل مساعد فقطأيه جت عملت وظيفة معينة
+
+101
+00:08:37,400 --> 00:08:41,180
+ساعدت الـ Bad Living Group أنها تطلع وبعدين عودت
+
+102
+00:08:41,180 --> 00:08:44,600
+رجعت H Plus؟ الآن هذه اللي رجعت ممكن تبدأ تعمل
+
+103
+00:08:44,600 --> 00:08:49,860
+تفاعل جديد ولا لأ؟ أكيد ولذلك لما أنا بدي أضيف على
+
+104
+00:08:49,860 --> 00:08:55,840
+التفاعل H Plus بضيفه بكمية مكافئة ولا بكمية قليلة؟
+
+105
+00:08:55,840 --> 00:09:00,280
+بكمية قليلة لأن انا بتشتغل الشغلة، بتعود ترجع،
+
+106
+00:09:00,280 --> 00:09:04,550
+بتشتغل الشغلة، بتعود ترجع، واضح؟زي على سبيل
+
+107
+00:09:04,550 --> 00:09:08,770
+المثال، لو تتخيلوا مدينتين، فكرة الـ Catalyst، لما
+
+108
+00:09:08,770 --> 00:09:13,510
+يكون عندى خمس سيارات بينقلوا ناس طول النهار، رايح
+
+109
+00:09:13,510 --> 00:09:18,690
+جاي، هم يمثلوا Catalyst، وسيلة بتعمل عملية إيش
+
+110
+00:09:18,690 --> 00:09:22,230
+نقل، بس مش لازم لو بدى أنقل ألف بني آدم يكون عنده
+
+111
+00:09:22,970 --> 00:09:27,310
+الف سيارة خمسة بيقوم المهم رايح جاى رايح جاى وهذا
+
+112
+00:09:27,310 --> 00:09:30,610
+نفس الاشي ال H plus بتطيف بتصير هذا good living
+
+113
+00:09:30,610 --> 00:09:35,190
+group بتطلع و بترجع ال H plus بتطلع من جديد و هكذا
+
+114
+00:09:35,190 --> 00:09:40,970
+واضح هذا اللي هو التفاعل الأول اللي بنسميه acidic
+
+115
+00:09:40,970 --> 00:09:45,970
+dehydration ليش قلنا acidic لأنه بنستعمل ال
+
+116
+00:09:45,970 --> 00:09:52,200
+catalystالـ H plus اللي هو الحامض واضح؟ حتى تتم
+
+117
+00:09:52,200 --> 00:09:58,300
+عملية الـ dehydration والتحول إلى الالكين لازم
+
+118
+00:09:58,300 --> 00:10:07,160
+نستعمل أسلوب هنا بدنا بس تنويه صغير أنه نفس هذا
+
+119
+00:10:07,160 --> 00:10:12,600
+التفاعل مثلا هنا الاثانول بيصير إيثالينهذا التفاعل
+
+120
+00:10:12,600 --> 00:10:18,200
+شويه حساس لدرجة الحرارة بمعنى إذا كانت تسخين ل 180
+
+121
+00:10:18,200 --> 00:10:22,240
+درجة مئوية بتصير عملية ال dehydration بس إذا بنسخن
+
+122
+00:10:22,240 --> 00:10:28,940
+عند 140 درجة مئوية بصير ناتج تاني اللي هو تكوين ال
+
+123
+00:10:28,940 --> 00:10:34,160
+ether ال ether هذه مجموعة ال ether فعند ال 140
+
+124
+00:10:34,160 --> 00:10:37,140
+درجة مئوية هيصير عند ال ether اللي هو ال ether o
+
+125
+00:10:38,720 --> 00:10:42,400
+بناخده بالفصل التامن تكوين الـ Ether لما ناخد
+
+126
+00:10:42,400 --> 00:10:45,940
+تكوين الـ Ether من الـ Ethanol هنقول نفس التفاعل
+
+127
+00:10:45,940 --> 00:10:51,680
+بنسخن وجود H Plus لكن عند 140 درجة موية، الآن هنا
+
+128
+00:10:51,680 --> 00:10:58,560
+عشان التفاعل حساس لدرجة الحرارة لازم تحفظوها،
+
+129
+00:10:58,560 --> 00:11:02,520
+واضح؟ يعني عند 180 درجة موية بيصير عند الـ Alkyl
+
+130
+00:11:02,520 --> 00:11:06,680
+عند 140 درجة موية بيصير عند الـ Ether
+
+131
+00:11:10,370 --> 00:11:16,550
+طبعا هذا ال alcohol اللي احنا كتبناها انه عبارة عن
+
+132
+00:11:16,550 --> 00:11:22,970
+ال primary alcohol ملاحظين CH2OH CH2OH الميكانيزم
+
+133
+00:11:22,970 --> 00:11:27,150
+هذا بخطوة واحدة تطلع ال H هذا تلف هذا تطلع شو
+
+134
+00:11:27,150 --> 00:11:33,230
+سمناها سابقا احنا E2 ميكانيزم اعملنا زيها بالظبط
+
+135
+00:11:33,230 --> 00:11:40,590
+لل elimination لل HXبر لما أخدنا ال mechanisms of
+
+136
+00:11:40,590 --> 00:11:46,110
+elimination في chapter 6 قلنا هما نوعين E2 و E1
+
+137
+00:11:46,110 --> 00:11:50,210
+mechanism الآن هنا ال mechanism اللي هي ال E2 ال
+
+138
+00:11:50,210 --> 00:11:55,690
+one step mechanism و اللي بتصير عادة مع ال primary
+
+139
+00:11:55,690 --> 00:12:01,170
+واضح طيب لو انتقلنا لل tertiary على طول هتلاحظوا
+
+140
+00:12:01,170 --> 00:12:05,170
+ان انتوا متذاكرين ان مع ال tertiary ال mechanism
+
+141
+00:12:05,170 --> 00:12:10,040
+المشهورة اللي هيالـ E1 ميكانيزم والـ E1 ميكانيزم
+
+142
+00:12:10,040 --> 00:12:15,120
+عبارة عن كام step؟ two steps الخطوة الأولى تكوين
+
+143
+00:12:15,120 --> 00:12:21,640
+الكربوكاتيون والخطوة الثانية فقد البروتون وتكوين
+
+144
+00:12:21,640 --> 00:12:27,360
+ال double bond خلينا نشوف كيف تتم هذه العملية أول
+
+145
+00:12:27,360 --> 00:12:32,340
+شيء لابد من الخطوة التحضيرية في كل الأحوال أن هذا
+
+146
+00:12:32,340 --> 00:12:37,560
+الـ OH إيش ما لها؟bad leaving group لازم أعمل
+
+147
+00:12:37,560 --> 00:12:42,940
+اتفاعل في وجود حامض عشان يحول الـ OH إلى H2O الأن
+
+148
+00:12:42,940 --> 00:12:46,320
+صارت الـ bad leaving group و الـ good leaving
+
+149
+00:12:46,320 --> 00:12:49,980
+group هذا لسه مش خطوة في الميكانيزم هذا مش خطوة في
+
+150
+00:12:49,980 --> 00:12:54,220
+الميكانيزم من وين بتبدأ الميكانيزم؟ بتبدأ بفقد
+
+151
+00:12:54,220 --> 00:12:59,560
+الميّه لما تفقد الميّه بتكون عندك كاربو كتايون هذا
+
+152
+00:12:59,560 --> 00:13:05,860
+الكاربو كتايون الأيون الموجب أثبت شيء بيكونمع الـ
+
+153
+00:13:05,860 --> 00:13:09,700
+tertiary وهنا احنا بنشتغل على الـ tertiary ولذلك
+
+154
+00:13:09,700 --> 00:13:13,500
+هذا بيكون stable الكاربو كتايون أثبت شيء مع الـ
+
+155
+00:13:13,500 --> 00:13:18,220
+tertiary هذا الكاربو كتايون الآن بعد ذلك بيفقد H
+
+156
+00:13:18,220 --> 00:13:20,840
+plus في الخطوة التانية وبتيجي ال double bond ده
+
+157
+00:13:20,840 --> 00:13:24,820
+بتتحرك هنا بتكون الalkene زي الـH plus مرة تانية
+
+158
+00:13:24,820 --> 00:13:30,180
+بتلاحظوا ان الـH plus بدأنا فيها وطلعت تاني إذا
+
+159
+00:13:30,180 --> 00:13:37,330
+الـH plus is a catalystلاحظوا التفاعل خطوتين
+
+160
+00:13:37,330 --> 00:13:43,270
+بسيطات الخطوة الأولى فقد الماء وتكوين Carbocation
+
+161
+00:13:43,270 --> 00:13:49,030
+الخطوة التانية فقد البروتون اللي هو في الأساس تم
+
+162
+00:13:49,030 --> 00:13:54,930
+إضافته لعملكتاليسيز للتفاعل وتكوين الألكيد هذه
+
+163
+00:13:54,930 --> 00:13:58,850
+الميكانيزم اللي بـ two steps ال first step و ال
+
+164
+00:13:58,850 --> 00:14:04,210
+second step هي اللي سمناها احنا E1 ميكانيزم اذا لو
+
+165
+00:14:04,210 --> 00:14:08,530
+بدنا نقول كيف بتتم عملية ال elimination من ال
+
+166
+00:14:08,530 --> 00:14:15,030
+primary alcohols ب E2 ميكانيزم من tertiary
+
+167
+00:14:15,030 --> 00:14:15,950
+alcohols
+
+168
+00:14:25,790 --> 00:14:30,950
+في الـ alkenes بتيجينا نفس المشكلة اللي تواجهنا
+
+169
+00:14:30,950 --> 00:14:35,490
+فيها بالـ alkyl halides إذا بتذكروا لما كنا نقول
+
+170
+00:14:35,490 --> 00:14:41,970
+بدنا نعمل عملية حذف من الـ alkyl halides كان في
+
+171
+00:14:41,970 --> 00:14:47,230
+إمكانية أحيانا يتكون عند أكثر من ال keen لما أنا
+
+172
+00:14:47,230 --> 00:14:50,990
+كنت بدأ أحذف ال X ممكن ال H من اليمين و لا ال H من
+
+173
+00:14:50,990 --> 00:14:55,740
+الشمال عشان أكمل H Xالان نفس الفكرة لما بدي أحذف
+
+174
+00:14:55,740 --> 00:15:00,080
+ال OH ال OH اللي بدي أحذفها بدي أحذفها مع إيش؟ هاي
+
+175
+00:15:00,080 --> 00:15:06,100
+ال OH اللي بدي نحذفها مع H مع H هال H هذه ممكن
+
+176
+00:15:06,100 --> 00:15:11,320
+تكون من هنا وبالتالي زيك أحذف الميه وممكن تكون من
+
+177
+00:15:11,320 --> 00:15:14,760
+هنا وبالتالي زيك أحذف الميه الآن إذا حذفت من هنا
+
+178
+00:15:14,760 --> 00:15:20,400
+شو هيتكون؟ هذا ال LK وإذا حذفت من هنا شو هيتكون؟
+
+179
+00:15:21,460 --> 00:15:26,580
+أذا كم ألكين متوقع عنده؟ اتنين و هذه الفكرة بتاعي
+
+180
+00:15:26,580 --> 00:15:31,780
+اللي حكيناها بوضوح لما أخدنا ال elimination of HX
+
+181
+00:15:31,780 --> 00:15:35,780
+قولنا الـ HX X مع H من هنا و لا H من هنا في عندي
+
+182
+00:15:35,780 --> 00:15:40,280
+two possibilities الأهم ايش اللي بيحكم لأي ناتج
+
+183
+00:15:40,280 --> 00:15:47,210
+اللي بيطلع؟ ايش سمينا احنا؟الـ more substituted
+
+184
+00:15:47,210 --> 00:15:51,190
+القين والـ formed القلقين اللي بيكون عليه إبدال
+
+185
+00:15:51,190 --> 00:15:56,350
+أكثر القلقين اللي بيكون عليه إبدال أكثر اللي قال
+
+186
+00:15:56,350 --> 00:16:01,470
+لو جيت سؤالت هذا ال two-butene و ال one-butene قدش
+
+187
+00:16:01,470 --> 00:16:06,650
+الإبدالات اللي على ال two-butene كام substitution؟
+
+188
+00:16:06,650 --> 00:16:08,550
+من تحسب النيارة؟
+
+189
+00:16:11,210 --> 00:16:15,990
+هي في عندى H و H و واحدة قبلت مثل و واحدة قبلت مثل
+
+190
+00:16:15,990 --> 00:16:22,130
+اذا كام substitution انا عندى اتنين هذا المركب هى
+
+191
+00:16:22,130 --> 00:16:28,070
+H و H و H و واحدة اثل اذا كام substitution واحد
+
+192
+00:16:28,070 --> 00:16:33,310
+which is more substituted ال two butene is more
+
+193
+00:16:33,310 --> 00:16:37,490
+substituted than one butene عشان هيك ال major
+
+194
+00:16:37,490 --> 00:16:42,320
+product في هذه الحالة isتو بيوتين و لاحظوا معي لو
+
+195
+00:16:42,320 --> 00:16:48,020
+كانت هذه ال CL و حطينا مع KOH كان برضه هنكتب نفس
+
+196
+00:16:48,020 --> 00:16:54,380
+النتيجة لما أخدنا المثال مع CL و بر هنا و كنا نعمل
+
+197
+00:16:54,380 --> 00:16:58,520
+التفاعل في وجود ال KOH كان يطلع عندنا one butane و
+
+198
+00:16:58,520 --> 00:17:02,810
+two butane و اللي كنا نقول عنهالناتج اللي بتكون
+
+199
+00:17:02,810 --> 00:17:06,510
+بنسبة أعلى ال major product مش ال minor ال major
+
+200
+00:17:06,510 --> 00:17:13,610
+اللي هو ال more substituted ال keen okay هاي كمان
+
+201
+00:17:13,610 --> 00:17:19,790
+مثال لو أخدنا هذا ال cyclopentanol اللي حامل OH
+
+202
+00:17:19,790 --> 00:17:25,690
+وهنا CH3 وهنا فيه H's الآن بالتأكيد ال OH بدأ تطلع
+
+203
+00:17:26,300 --> 00:17:32,140
+هذا مش موضوع نقاش لكن السؤال مع أي هيدروجين مع أي
+
+204
+00:17:32,140 --> 00:17:36,200
+بروتون بدها تطلع في إمكانية تطلع مع الهيدروجين
+
+205
+00:17:36,200 --> 00:17:40,340
+اللي هان وفي إمكانية تطلع مع واحدة من هدولة اللي
+
+206
+00:17:40,340 --> 00:17:45,700
+هان واضح؟ الآن إذا طلعت مع هيدروجين من هدولة هتكون
+
+207
+00:17:45,700 --> 00:17:50,200
+لأي مركب المركب التاني اللي هناك وإذا طلعت ال OH
+
+208
+00:17:50,200 --> 00:17:53,580
+مع هيدروجين من هنا هتكون ال double bond في هذا
+
+209
+00:17:53,580 --> 00:17:58,140
+الموقع لما نيجي نحللwhich is the major product أنه
+
+210
+00:17:58,140 --> 00:18:02,720
+هو الناتج الأساسي ال more substituted اتطلعولي هنا
+
+211
+00:18:02,720 --> 00:18:06,460
+كام substitution عندى و هنا كام substitution عندى
+
+212
+00:18:06,460 --> 00:18:12,680
+هنا في عندى هى ال double bond هى ده متصلة ب carbon
+
+213
+00:18:12,680 --> 00:18:16,240
+و هى ده ب carbon و هى ده ب carbon واحدة منهم بس
+
+214
+00:18:16,240 --> 00:18:22,950
+hydrogen إذا كام substitution عندى هنا تلاتةثلاثة
+
+215
+00:18:22,950 --> 00:18:26,130
+من الهيدروجين راحوا، ضالت واحدة، إذا عندي تلت
+
+216
+00:18:26,130 --> 00:18:31,030
+إبدالات، لإن المركب غير المبدل اللي يحتوي عليه،
+
+217
+00:18:31,030 --> 00:18:35,690
+أربعة هيدروجين، واضح؟ هنا الآن كام substitution؟
+
+218
+00:18:35,690 --> 00:18:39,730
+عندي هذه كام و هذه؟ هنا هيدروجين و هيدروجين مافيش
+
+219
+00:18:39,730 --> 00:18:43,190
+إبدال هنا، اتنين، اتنين، إذا which is the major
+
+220
+00:18:43,190 --> 00:18:47,770
+product؟the first one is the major product واضح؟
+
+221
+00:18:47,770 --> 00:18:51,370
+عشانك لو انا بدي اجيبلكوا اكمل المعادلة هذه او هذه
+
+222
+00:18:51,370 --> 00:18:56,570
+و اكتبلكوا اعطوني ال major product تعملوا ال
+
+223
+00:18:56,570 --> 00:19:01,910
+substitution يعني تعملوا المركب ال major product
+
+224
+00:19:01,910 --> 00:19:07,050
+يكون ال more substituted واضح؟ الناتج الأكثر إبدال
+
+225
+00:19:07,050 --> 00:19:10,730
+هو الناتج الأساسي
+
+226
+00:19:17,840 --> 00:19:22,120
+النوع التاني من التفاعلات، لاحظوا كل التفاعل الأول
+
+227
+00:19:22,120 --> 00:19:26,960
+اللي أخدناه حذف الـ OH مع H لتكوين الكني اللي
+
+228
+00:19:26,960 --> 00:19:33,120
+سمناه عملية dehydration، نزع الماء، الآن التفاعل
+
+229
+00:19:33,120 --> 00:19:41,180
+الثاني هو تفاعل إبدال، إن أبدل الـ OH ب X، ال X
+
+230
+00:19:41,180 --> 00:19:49,670
+يعني CL أو PR أو Uواضح؟ substitution reaction كيف
+
+231
+00:19:49,670 --> 00:19:53,670
+بتتم عملية ال substitution reaction؟ كيف هذا ال OH
+
+232
+00:19:53,670 --> 00:20:00,170
+بدي أخليها تصير X؟ واضح؟ ببساطة، لو كان عندي
+
+233
+00:20:00,170 --> 00:20:04,790
+tertiary alcohol لو كان عندي tertiary alcohol بأجي
+
+234
+00:20:04,790 --> 00:20:10,380
+بفعله ماعدش Clالـ tertiary alcohol بفعله مع الـ
+
+235
+00:20:10,380 --> 00:20:15,580
+HCl بتطلع الـ OH و مع الـ H هذا بتعمل ميه و بيجي
+
+236
+00:20:15,580 --> 00:20:21,400
+عند هنا CL الآن لو جينا قولنا إيش الميكانيزم اللي
+
+237
+00:20:21,400 --> 00:20:27,240
+بدو يتم في هذا التفاعل واحدة
+
+238
+00:20:27,240 --> 00:20:33,920
+تعطينا وصفيا هذا التفاعل كيف بدو يتم على كام خطوة
+
+239
+00:20:41,140 --> 00:20:47,160
+بدي يكون فيه خطوتين أساسيات في الميكانيزم وقولا
+
+240
+00:20:47,160 --> 00:20:55,360
+واحدا خطوة تحضيرية ايش الخطوة التحضيرية تحويل ال O
+
+241
+00:20:55,360 --> 00:21:00,160
+H minus ال bad leaving group إلى good leaving
+
+242
+00:21:00,160 --> 00:21:04,760
+group إذا في الأول هذا لما تكتبوا الميكانيزم له
+
+243
+00:21:05,590 --> 00:21:12,030
+بتقولوا زائد H plus بتصير هذا H2O بعدين الخطوة
+
+244
+00:21:12,030 --> 00:21:18,550
+الأولى الـH2O تفقد بتصير Carbocation
+
+245
+00:21:18,550 --> 00:21:24,970
+بعدين الـCl بتيجي بتتفاعل بيصير عنده اللي هو ال
+
+246
+00:21:24,970 --> 00:21:30,410
+Alkyl chloride واضح؟
+
+247
+00:21:30,410 --> 00:21:37,420
+اذاكام خطوة عندى مرة تانية منى تعيدلى اهم تنتين
+
+248
+00:21:37,420 --> 00:21:41,680
+اساسيات الميكانيزم زاد خطوة تحذيرية في الاول دائما
+
+249
+00:21:41,680 --> 00:21:46,380
+كل التفاعلات الالكحول وانتم غامضين ال OH minus ال
+
+250
+00:21:46,380 --> 00:21:51,140
+OH هذا بدأ تصير H2O بعد ان ال H2O تفقد بتعطيني
+
+251
+00:21:51,140 --> 00:21:54,720
+carbocation هاي ال first step ال carbocation مع ال
+
+252
+00:21:54,720 --> 00:22:00,360
+CL بيعطيني المركب تبعى هذه الميكانيزم اللى احنا
+
+253
+00:22:00,360 --> 00:22:06,240
+سمناها SNone mechanism الآن أنا بتكون تتذكروا شغلة
+
+254
+00:22:06,240 --> 00:22:11,260
+كمان طالما أنه أنا بقول أنه بتكون عندي carbocation
+
+255
+00:22:11,260 --> 00:22:15,140
+طالما أنا بقول بتكون عندي carbocation في الخطوة
+
+256
+00:22:15,140 --> 00:22:20,100
+الأولى، إذا متوقع في النتائج أنه يصير عندي إيش؟
+
+257
+00:22:21,340 --> 00:22:24,420
+rearrangement الكربوكاتيون من مواصفته ال
+
+258
+00:22:24,420 --> 00:22:27,780
+rearrangement يعني لو كان عندي مثلا secondary
+
+259
+00:22:27,780 --> 00:22:31,680
+كربوكاتيون ممكن يعمل rearrangement و يصير tertiary
+
+260
+00:22:31,680 --> 00:22:37,340
+كربوكاتيون more stable و أحيانا primary كربوكاتيون
+
+261
+00:22:37,340 --> 00:22:41,100
+و بيصير tertiary كربوكاتيون أو secondary
+
+262
+00:22:41,100 --> 00:22:45,690
+كربوكاتيون واضح؟كل الكلام اللي أخدته على الـ SN1
+
+263
+00:22:45,690 --> 00:22:49,590
+ميكانيزم برضه بنطبق هنا لكن إنتوا لما درستوا
+
+264
+00:22:49,590 --> 00:22:52,150
+chapter 6 كان عندكوا ال الهيلايت كانت بالخطوة
+
+265
+00:22:52,150 --> 00:22:56,670
+الأولى تفقد ال X و تكون Carbocation الآن هنا بتفقد
+
+266
+00:22:56,670 --> 00:23:02,890
+الميه وبتكون Carbocation والتفاعل بمشي الان
+
+267
+00:23:02,890 --> 00:23:04,930
+بالنسبة ل primary
+
+268
+00:23:07,730 --> 00:23:13,770
+الحقيقة لـ Primary Alcohols لو جينا نفعلهم مع الـ
+
+269
+00:23:13,770 --> 00:23:21,050
+HCl لوحده، ما بيصيرش تفاعل، واضح؟ الـ Primary
+
+270
+00:23:21,050 --> 00:23:28,510
+Alcohols مع HCl لوحده، ما بيصيرش تفاعل من أساسه،
+
+271
+00:23:28,510 --> 00:23:34,410
+تفاعل بطيء جداًالان ايش بيعملوا عشان يصير التفاعل
+
+272
+00:23:34,410 --> 00:23:41,750
+ال primary alcohol بياخدوه مع ال HCL و بيحطوا عليه
+
+273
+00:23:41,750 --> 00:23:48,990
+كمان catalyst زنك كلورايد و كمان حرارة و كل هذا
+
+274
+00:23:48,990 --> 00:23:52,430
+لسه بيعطيني التفاعل مش كتير مقنع يعني بياخد عدة
+
+275
+00:23:52,430 --> 00:23:59,650
+ساعات تسخين لما تم عملية الإبداللأ ال OH بها لوجد
+
+276
+00:23:59,650 --> 00:24:03,610
+و طبعا هنا طالما هذا primary إذا الميكانيزم اللي
+
+277
+00:24:03,610 --> 00:24:08,110
+بتتوقعوها SN2 ميكانيزم الميكانيزم اللي بتتوقعها
+
+278
+00:24:08,110 --> 00:24:12,290
+SN2 ميكانيزم و اليود هنا بتتفاعل أسرع من ال brom
+
+279
+00:24:12,290 --> 00:24:17,670
+أسرع من الchlor واضح لأن اليود بده يهاجم و اليود
+
+280
+00:24:17,670 --> 00:24:21,300
+stronger and nucleophile thanIbromine which is
+
+281
+00:24:21,300 --> 00:24:27,220
+stronger than chlorine وبناء على ذلك هذه يعني أو
+
+282
+00:24:27,220 --> 00:24:32,720
+التفاعل بهذا الشكل رغم أنه ممكن عبر تسخين لعدة
+
+283
+00:24:32,720 --> 00:24:38,360
+ساعات لكنه ليس الطريقة الأمثل لتحويل ال primary
+
+284
+00:24:38,360 --> 00:24:44,470
+alcohols ل ال alkyl halides في طرق أفضل منهواضح؟
+
+285
+00:24:44,470 --> 00:24:47,910
+إذا لو أنا بدي أجي أسألكوا في الامتحان أنه ال
+
+286
+00:24:47,910 --> 00:24:52,710
+primary alcohols react with HCl forming alkyl
+
+287
+00:24:52,710 --> 00:24:58,550
+halides، الجواب لأ، مع ال HCl لحاله لأ، طب مع ال
+
+288
+00:24:58,550 --> 00:25:04,620
+HCl و Zinc chloride و حرارةبصير لكن يعتبر تفاعل
+
+289
+00:25:04,620 --> 00:25:09,320
+بطيء إذا إيش ال best method؟ إيش أفضل طريقة لتحويل
+
+290
+00:25:09,320 --> 00:25:11,880
+ال primary alcohol هي مثلا أنا عندنا واحد اتنين
+
+291
+00:25:11,880 --> 00:25:17,220
+تلاتة بروبانول هذا المركب بروبانول هذا primary
+
+292
+00:25:17,220 --> 00:25:22,720
+alcohol بنيجي بنفعله مع ال BCL3 فوسفوراس تريكلوريد
+
+293
+00:25:22,720 --> 00:25:27,920
+مثلا أو فوسفوراس تريبروميد هذا التفاعل خصوص لل
+
+294
+00:25:27,920 --> 00:25:34,230
+primary alcohol عقول بحب محل ال OACAإذن أنهي أفضل
+
+295
+00:25:34,230 --> 00:25:38,290
+طريقة أنه الـ Primary Alcohol لما بدي أعمل منه
+
+296
+00:25:38,290 --> 00:25:43,630
+Alkyl Halide أفعله مع الـ PCL3 الـ Phosphorus
+
+297
+00:25:43,630 --> 00:25:48,330
+Trichloride لكن نيجي نقول Primary Alcohol مع TCL
+
+298
+00:25:48,330 --> 00:25:54,250
+لحاله ما بتحولها لAlkyl
+
+299
+00:25:54,250 --> 00:25:57,530
+Halide هذه الطريقة اللي هي ال reaction with
+
+300
+00:25:57,530 --> 00:26:02,420
+Phosphorus Chloride في طريقة تانية كمانبنفعله مع
+
+301
+00:26:02,420 --> 00:26:07,840
+مادة بنسميها Theonyl Chloride Theonyl Chloride الـ
+
+302
+00:26:07,840 --> 00:26:13,580
+Theonyl Chloride مادة مشهورة S O C L 2 صيغتها واضح
+
+303
+00:26:13,580 --> 00:26:18,560
+S ضب ال bond O C L C L S O C L 2 Theonyl Chloride
+
+304
+00:26:18,560 --> 00:26:23,360
+برضه هذا التفاعل ممتاز بيحول ال primary alcohols
+
+305
+00:26:23,360 --> 00:26:26,760
+إلى ال الكالهيلايد
+
+306
+00:26:27,940 --> 00:26:32,200
+Alkyl Halides can be prepared from primary
+
+307
+00:26:32,200 --> 00:26:36,820
+alcohols or can be best prepared يعني أفضل إشي by
+
+308
+00:26:36,820 --> 00:26:43,800
+reaction with BCL3 or thionyl chloride واضح؟ إذا
+
+309
+00:26:43,800 --> 00:26:49,300
+أفضل طريقتين يا BCL3 يا thionyl chloride في حالة
+
+310
+00:26:49,300 --> 00:26:53,360
+إن أنا بدي أحول ال primary alcohol إلى
+
+311
+00:26:57,020 --> 00:27:02,360
+الكالهلايد هنا بتجينا شغلة انه احنا اخدنا في عندنا
+
+312
+00:27:02,360 --> 00:27:09,300
+tertiary alcohol OH بHCl بنحولها الى الهلايد ال
+
+313
+00:27:09,300 --> 00:27:16,100
+primary مع ال BCL3 و ال SOCl2 الان بنيجي ل .. لو
+
+314
+00:27:16,100 --> 00:27:22,200
+كان عندى phenolic compound يعني AROH فينل او مشتقة
+
+315
+00:27:22,200 --> 00:27:28,410
+فينلواضح الأوقات شنوية موجودة على بنزينة أو طوابع
+
+316
+00:27:28,410 --> 00:27:33,790
+الـ ARA capital small R بالغلط مكتوبة مش مشكلة AR
+
+317
+00:27:33,790 --> 00:27:43,930
+هيكا الـ AR كمجموعة مش capitalالـ AROH لو فعلناها
+
+318
+00:27:43,930 --> 00:27:50,150
+مع HCl مع HCl و Zinc مع BCl3 مع SOCl2 كله
+
+319
+00:27:50,150 --> 00:27:55,290
+مابتتفعلش ولا بتتحول إلى ال الهيلايد الارلهيلايد
+
+320
+00:27:57,090 --> 00:28:01,110
+إذن لاحظوا معي لو بداجة أسألكوا أنا أقولها الـ
+
+321
+00:28:01,110 --> 00:28:04,890
+Phenols can be converted to aryl halides by
+
+322
+00:28:04,890 --> 00:28:08,830
+heating it with HCl or HCl with zinc chloride or
+
+323
+00:28:08,830 --> 00:28:11,930
+by reacting it with phosphorus trichloride or with
+
+324
+00:28:11,930 --> 00:28:16,150
+thionyl chloride كله لأ ال Phenols أبدا من
+
+325
+00:28:16,150 --> 00:28:25,180
+هالناحية مسكرة واضح؟ ما بتتحول ال Phenols إلىأريل
+
+326
+00:28:25,180 --> 00:28:30,140
+هيلايدز ما بتتحول الفينول إلى اريل هيلايدز طبعا
+
+327
+00:28:30,140 --> 00:28:33,300
+احنا الحمد لله لو احتجنا اريل هيلايدز في اننا طرق
+
+328
+00:28:33,300 --> 00:28:37,600
+تانية لتحضيره يعني لما اكون انا بدي كلور و بنزين
+
+329
+00:28:37,600 --> 00:28:42,000
+بلزم ان اجي احوله من فينول ما تحضير الفينول أساسا
+
+330
+00:28:42,000 --> 00:28:46,080
+صعب انا باخد البنزين كلور و ألمنيوم كلورايدز
+
+331
+00:28:46,080 --> 00:28:47,620
+متذكرين المعادلة؟
+
+332
+00:28:50,330 --> 00:28:53,410
+بقدر أحضره لـ Chlorobenzene لكن بطريقة تانية، بس
+
+333
+00:28:53,410 --> 00:28:57,950
+بالتأكيد مش من خلال الفينول، مش من خلال تحويل الـ
+
+334
+00:28:57,950 --> 00:29:06,330
+OH تاعة الفينول إلى إكلورايد إبنيجيلا
+
+335
+00:29:06,330 --> 00:29:13,230
+تفاعل تالت للـ Alcohol لحد الآن الوضع تحت السيطرة
+
+336
+00:29:13,230 --> 00:29:19,150
+أخدنا تفاعلات الـ dehydration نزع الماء النوع
+
+337
+00:29:19,150 --> 00:29:24,860
+التانيالإبداء لأن الـ OH نحط مكانها X التفاعل
+
+338
+00:29:24,860 --> 00:29:30,620
+التالت الأكسدة Oxidation التفاعل التالت الأكسدة
+
+339
+00:29:30,620 --> 00:29:37,460
+واضح؟ طبعا الأكسدة دائما مرتبطة في ذهنها بإيش؟
+
+340
+00:29:37,460 --> 00:29:42,900
+بالأكسوجين بالأكسوجين يعني جزء من معنى الأكسدة بغض
+
+341
+00:29:42,900 --> 00:29:47,460
+النظر عن المعنى المتعلق بالتأكسد فقد إلكترونات
+
+342
+00:29:47,460 --> 00:29:51,900
+والاختصال اكتساب إلكتروناتفي أساس المفهوم كانت
+
+343
+00:29:51,900 --> 00:29:53,980
+الأكسدة تعني
+
+344
+00:29:56,110 --> 00:30:02,750
+زيادة في الروابط مع إيش؟ مع الأكسجين الأكسدة كانت
+
+345
+00:30:02,750 --> 00:30:07,450
+تعني زيادة في الروابط مع الأكسجين بمعنى كل ما أنا
+
+346
+00:30:07,450 --> 00:30:11,970
+بزيد الروابط مع الأكسجين كأن أنا بعمل إيش؟ أكسدة
+
+347
+00:30:11,970 --> 00:30:17,070
+عشان هيك لو بعيدا عن هذه اتخيلنا المراكبات الآتية
+
+348
+00:30:17,070 --> 00:30:23,130
+لو جيت اتخيلت أنا الاثانول CH3 CH2 OH مع كام
+
+349
+00:30:23,130 --> 00:30:29,380
+أكسجين متحدمع واحدة، مظبوط ولا لا؟ الآن لو شيلت H
+
+350
+00:30:29,380 --> 00:30:36,340
+وH من هنا، سيصبح CH3CWbO OH صار مع كام أكسجين من
+
+351
+00:30:36,340 --> 00:30:40,500
+التحت؟ مع تنتين، إذا أنا صارت عندي عملية
+
+352
+00:30:40,500 --> 00:30:46,770
+oxidation، لو شيلت ال Hبدي يصير عند C double bond
+
+353
+00:30:46,770 --> 00:30:52,630
+O أو H هنا الكربون مع كام أكسجين متحدة؟ تلاتة لو
+
+354
+00:30:52,630 --> 00:30:56,250
+أتيت تعمل التكسير إضافي فيك، أصارت منها وامطلعت C
+
+355
+00:30:56,250 --> 00:30:59,270
+double bond O أو C double bond O ثانو أكسيد
+
+356
+00:30:59,270 --> 00:31:06,250
+الكربون، كم؟ رابط، أربع، إذا أنا عملية تحويل
+
+357
+00:31:06,250 --> 00:31:12,810
+الإيثانوللهذا المركب اللي هو ال Acetaldehyde لهذا
+
+358
+00:31:12,810 --> 00:31:16,590
+المركب اللي هو Acetic Acid لهذا المركب اللي هو
+
+359
+00:31:16,590 --> 00:31:21,650
+ثانو أكسيد الكربون حافظين هم دول المركبات إيثالون
+
+360
+00:31:21,650 --> 00:31:27,710
+و هنا Acetaldehyde
+
+361
+00:31:27,710 --> 00:31:37,370
+و بعدين هذا Acetic Acid و بعدين هذا Carbon Dioxide
+
+362
+00:31:37,370 --> 00:31:43,190
+ثانو أكسيد الكربونقصة كبيرة هذه ولا لأ؟ عارفين وان
+
+363
+00:31:43,190 --> 00:31:53,090
+بتصير هذه القصة الكبيرة؟ مين بتعرف فيكم؟ في جسم
+
+364
+00:31:53,090 --> 00:32:03,690
+البني أدمين أي بني أدمين؟ لأ مش احنا لأ بجسم
+
+365
+00:32:03,690 --> 00:32:09,590
+الكفار مش المسلمينأحنا هنا معظمنا مسلمين، هذي
+
+366
+00:32:09,590 --> 00:32:14,030
+بتصير عند الناس اللي بيشربوا الخمرة، اللي بيشربوا
+
+367
+00:32:14,030 --> 00:32:18,570
+الخمرة بياخدوا على جسمهم إيثانول، مظبوط ولا لأ؟
+
+368
+00:32:19,630 --> 00:32:23,590
+الان هذا الاثانول بيعمل تأثير الإسكار تبعه، كم
+
+369
+00:32:23,590 --> 00:32:27,250
+يأخذ تأثير الإسكار لحد ما يروح، حسب الكمية اللي
+
+370
+00:32:27,250 --> 00:32:31,430
+الناس شربينها، يوم، نص، يوم، ست، سبع، تمان، تسعة،
+
+371
+00:32:31,430 --> 00:32:34,470
+عشر ساعات، إيش بيصير في هال ست، سبع، تمان، تسعة،
+
+372
+00:32:34,470 --> 00:32:39,030
+عشر ساعات اللي بنقول البني آدم فيها drunk، سكران
+
+373
+00:32:39,030 --> 00:32:43,930
+ومش قادر يسيطر على حاله؟ بيصير مختبر كيميا في جسمه
+
+374
+00:32:45,010 --> 00:32:49,570
+بصير في جسمه إيش؟ مختبر كيميا، الإيثانول اللي
+
+375
+00:32:49,570 --> 00:32:53,550
+بياخده من خلال الإنزيمات ومن خلال أشياء معينة في
+
+376
+00:32:53,550 --> 00:32:57,470
+الجسم بيصير acetaldehyde بتأكسد، ال acetaldehyde
+
+377
+00:32:57,470 --> 00:33:05,440
+سام، لحصل الحظ بتأكسد بسرعة إلىأسيتك أسد بتأكسد
+
+378
+00:33:05,440 --> 00:33:09,260
+بسرعة إلى أسيتك أسد والأسيتك أسد بتأكسد لثانو
+
+379
+00:33:09,260 --> 00:33:12,120
+أكسيد الكربون الآن ثانو أكسيد الكربون بنطلع ولا
+
+380
+00:33:12,120 --> 00:33:16,500
+لأ؟ مش احنا كجسم شو بنطلع؟ بنطلع ثانو أكسيد
+
+381
+00:33:16,500 --> 00:33:21,820
+الكربون لاحظوا هذه العملية اللي هو إن الكحول يصير
+
+382
+00:33:21,820 --> 00:33:25,820
+الديهيد يصير أسد يصير ثانو أكسيد الكربون هي عملية
+
+383
+00:33:25,820 --> 00:33:29,810
+كيمية وإحنا في الكيميا بناخد كتاليسيزأحنا في
+
+384
+00:33:29,810 --> 00:33:33,590
+الكيميا بناخد Catalysis، مظبوط ولا لا؟ إيش يعني
+
+385
+00:33:33,590 --> 00:33:38,670
+Catalysis؟ إنه نسرع التفاعلات، الآن السؤال عادي،
+
+386
+00:33:38,670 --> 00:33:45,290
+هل يا تورا في Catalist بيسرع هذا التفاعل؟ إيش معنى
+
+387
+00:33:45,290 --> 00:33:50,370
+الكلام؟ لو هذا ال Catalist موجود، إنه لو شخص معين
+
+388
+00:33:50,370 --> 00:33:56,450
+راح على حفلة وصار شارب إيثانول كتير وبدو يروح
+
+389
+00:33:56,450 --> 00:34:03,100
+بسيارتهممنوع حسب القانون أنه يسوق السيارة لأنه
+
+390
+00:34:03,100 --> 00:34:06,440
+سكران، مش هيسيطر عليها، إيش الحال والله؟ في
+
+391
+00:34:06,440 --> 00:34:10,220
+إمكانية أنه نيجي نعطيه catalyst، حبة حبوب، هال
+
+392
+00:34:10,220 --> 00:34:14,040
+catalyst خلال عشر دقايق، يحول الاثانول لالديهيد،
+
+393
+00:34:14,040 --> 00:34:18,420
+لأسد، لثانوكسيد كربون، خلصنا من الاثانول؟ أبدًا،
+
+394
+00:34:18,420 --> 00:34:23,580
+العلماء مش ناجحين بهالشغلة، لازم ياخد ال .. ال ..
+
+395
+00:34:24,700 --> 00:34:30,200
+الكحول حجه حسب نظام الجسم مافيش عند العلماء لحد
+
+396
+00:34:30,200 --> 00:34:33,840
+اليوم على أقل تقدير إيش بيصير في الدنيا الله بيعلم
+
+397
+00:34:33,840 --> 00:34:41,560
+مافيش طريقة يسرعوا فيها إخراج الكحول من الجسم كتير
+
+398
+00:34:41,560 --> 00:34:45,800
+شغلات أحيانا الملحدين بياخدوا سموم معينة في عندهم
+
+399
+00:34:45,800 --> 00:34:49,540
+toxins مضادات للسموم بيعطوها و بيجدوا على السم
+
+400
+00:34:49,540 --> 00:34:56,280
+بلحظته مظبوط ولا لأ بس الكحول لسه لأيعني بأذكر مرة
+
+401
+00:34:56,280 --> 00:35:03,200
+جريمة قتل التهم فيها شخص بيشرب .. بيشرب كحول و
+
+402
+00:35:03,200 --> 00:35:07,900
+إجوا يحققوا المحققين طبعا برضه في بلد إسلامي بس
+
+403
+00:35:07,900 --> 00:35:13,500
+الشخص بيشرب كحول للأسف إيش عملوا؟ ضالهم يستنوا يوم
+
+404
+00:35:13,500 --> 00:35:17,040
+كامل مع العلم إن كل دقيقة التحقيق بتفيدهم لحد ما
+
+405
+00:35:17,040 --> 00:35:20,810
+البني أدم يصحىاللي بدهم يحققوا معه من الالكو اللي
+
+406
+00:35:20,810 --> 00:35:25,090
+شربينه مافيش عندهم إبرة ولا حب الدواء يعطوياها
+
+407
+00:35:25,090 --> 00:35:30,410
+خلال ربع ساعة تضيع تأثير الكحول من جسمه العلم في
+
+408
+00:35:30,410 --> 00:35:35,230
+هذه المنطقة ما زال بيشتغل على رتم جسم الإنسان رتم
+
+409
+00:35:35,230 --> 00:35:42,410
+جسم الإنسان على البطيء رتم جسم الإنسان على البطيء
+
+410
+00:35:42,410 --> 00:35:49,750
+واضح؟هنا خلّينا فلسفيا نحكي كمان عن شغلة تانية لو
+
+411
+00:35:49,750 --> 00:35:56,870
+إجينا للإيثانول، الإيثانول من وين جاي؟ احنا أخدنا
+
+412
+00:35:56,870 --> 00:36:02,510
+في تحضير الإيثانول، sugar، لو الإيثانول مكوّن
+
+413
+00:36:02,510 --> 00:36:08,690
+المزعج في الخمر، من ال sugar، تمام؟الإيثانول مش
+
+414
+00:36:08,690 --> 00:36:12,990
+بيجي من السكريات وتخميرها، بيخمروا العنب و بيخمروا
+
+415
+00:36:12,990 --> 00:36:16,850
+القصب و بيخمروا العسل و بيخمروا المولاس، مظبوط ولا
+
+416
+00:36:16,850 --> 00:36:22,530
+لأ؟ و الخمور كلها من الانجاص و الفواكه و الطمراللي
+
+417
+00:36:22,530 --> 00:36:26,350
+بيعرف كلها الأشياء، الآن هذه بتحطنا الحقيقة عند
+
+418
+00:36:26,350 --> 00:36:32,090
+شغلة مهمة في الدنيا، أن الأشياء وليست بتاريخها،
+
+419
+00:36:32,090 --> 00:36:36,390
+المهم في الواقع إيش موجود الإنسان اليوم، يعني
+
+420
+00:36:36,390 --> 00:36:40,670
+كإننا بنحكي عن اللي اتعلمتوها إذا اتعلمتوا أنتوا،
+
+421
+00:36:40,670 --> 00:36:44,050
+ماعرفش ممكن ما اتعلمتوش، إيش معنى state function؟
+
+422
+00:36:45,880 --> 00:36:48,200
+دالة الحالة، إيش اللي بنقصده إحنا بال state
+
+423
+00:36:48,200 --> 00:36:52,480
+function أو دالة الحالة؟ دالة الحالة اللي هي الشيء
+
+424
+00:36:52,480 --> 00:36:55,640
+اللي باعتمد على الوضع الآن، ما باعتمدش على
+
+425
+00:36:55,640 --> 00:36:59,340
+التاريخ، ما باعتمدش على ال history، المهم إيش هو
+
+426
+00:36:59,340 --> 00:37:04,320
+الآن؟ تماما زي ما أجي مثلا أنا ألاقي ولد صغير
+
+427
+00:37:04,320 --> 00:37:08,620
+بيلعب في ميا، okay؟ ممكن الولد الصغير اللي بيلعب
+
+428
+00:37:08,620 --> 00:37:11,840
+في المية، هيك ساطل صغير في مية و جاعة بيلعب و بحط
+
+429
+00:37:11,840 --> 00:37:17,940
+على وشه أمه من حد ما تشوفهتغلي بالدنيا أسراخ؟ شوفي
+
+430
+00:37:17,940 --> 00:37:23,950
+شو مالك؟ بتقول والله المي كانت بتغليوالولد عنده
+
+431
+00:37:23,950 --> 00:37:27,550
+انحراج الميّه كانت بتغلي قبل تلت ساعات بس هالجيتها
+
+432
+00:37:27,550 --> 00:37:31,390
+الميّه مابتغليش والميّه هالجيت باردة و الولد ببسوط
+
+433
+00:37:31,390 --> 00:37:35,490
+الان هل أثر التاريخ ان هذي الميّه قبل تلت ساعات
+
+434
+00:37:35,490 --> 00:37:39,490
+كانت تغلي على حالة الميّه الآن؟ عرفت ايش معنى
+
+435
+00:37:39,490 --> 00:37:43,410
+state function؟ ان انا المهم عندي الحالة الآن يعني
+
+436
+00:37:43,410 --> 00:37:46,810
+تجيني طالبة تقولي والله أنا في توجيه الأولى على
+
+437
+00:37:46,810 --> 00:37:50,470
+القطاع ما له مالك و ما له مال القطاع المهم في ال
+
+438
+00:37:50,470 --> 00:37:54,800
+organic جايبة خمسة من تلاتينstate function هل
+
+439
+00:37:54,800 --> 00:37:58,680
+الأولى على القطاع ابتشفعلها أنه كانت الأولى على
+
+440
+00:37:58,680 --> 00:38:02,520
+القطاع اتجوزت و انشغلت و عندها ميد شغلة و بتجلب
+
+441
+00:38:02,520 --> 00:38:05,480
+تطبخ و بعدين بدأت تاخد تلاتين من تلاتين لأنها كانت
+
+442
+00:38:05,480 --> 00:38:08,980
+الأولى على القطاع دي state ايش؟ function المهم
+
+443
+00:38:08,980 --> 00:38:12,720
+عندى الحالة الآن الان انتبهوا معايا كيف بتصير
+
+444
+00:38:12,720 --> 00:38:17,160
+الأمور من ناحية شرعية السكر حلال
+
+445
+00:38:19,360 --> 00:38:24,580
+العناب حلال، الانجاص حلال، التفاح حلال، صار خمرة
+
+446
+00:38:24,580 --> 00:38:29,020
+صار إيثانول حرام، الآن ماحدش ييجي يقول يا أخي
+
+447
+00:38:29,020 --> 00:38:32,580
+انجاص شجرة مباركة، يا أخي طمر، الرسول عليه الصلاة
+
+448
+00:38:32,580 --> 00:38:36,240
+والسلام كان يفطر على الطمر، كان يفطر على الطمر، بس
+
+449
+00:38:36,240 --> 00:38:42,030
+مش لما يصيرمش لما يصير خمرة، واضح؟ كان يفطر على
+
+450
+00:38:42,030 --> 00:38:47,210
+التمر، مش على التمر اللي اتخمر، مظبوط ولا لأ؟ إذا
+
+451
+00:38:47,210 --> 00:38:54,890
+هنا ال sugar حلال، والفواكه حلال، الكحولات، حرام،
+
+452
+00:38:54,890 --> 00:38:58,310
+الالدهايتسام، مرحلة بين هدولة تنتين، بعدين تعالولي
+
+453
+00:38:58,310 --> 00:39:03,050
+على الخل الخل
+
+454
+00:39:03,050 --> 00:39:09,460
+حلال، طب هو من وين جاي؟ من الخمرمظبوط ولا لأ؟
+
+455
+00:39:09,460 --> 00:39:14,020
+الخمر تتحول إلى خل يعني الناس اللي بيعملوا خل
+
+456
+00:39:14,020 --> 00:39:16,400
+التفاح في البيت اللي بيجيبوا التفاح و بيسكروا عليه
+
+457
+00:39:16,400 --> 00:39:19,740
+في الجزازة و شوية بالشمس هو اللي بيصير أن التفاح
+
+458
+00:39:19,740 --> 00:39:23,320
+الحلال بيصير خمرة حرام و الخمرة الحرام بتصير خل
+
+459
+00:39:23,320 --> 00:39:27,960
+حلال و أفضل ما أكلتم الخل لأنه غذاء كامل و في
+
+460
+00:39:27,960 --> 00:39:32,530
+أحاديث نبوية في الخلواضح؟ إذا إحنا جاعدين بنتحول
+
+461
+00:39:32,530 --> 00:39:36,650
+من حلال لحرام لحلال بهمني إيش ال .. إيش اللي أنا
+
+462
+00:39:36,650 --> 00:39:42,130
+الآن قاعد بتعامل معه، هل بهمني تاريخه؟ أه، إذا
+
+463
+00:39:42,130 --> 00:39:50,930
+الخل هنا كيف أصبح حلالا؟ بالشريعة بيستعمله مصطلح،
+
+464
+00:39:50,930 --> 00:39:56,790
+إيش بيقولوا عنه؟ طهرة بالتحول
+
+465
+00:39:58,210 --> 00:40:04,070
+طهورة بإيش؟ بالتحول، هذه عملية التحول من الإثانون
+
+466
+00:40:04,070 --> 00:40:08,850
+للخلق، هذه عملية تطهير لما تاخدوا التطهير في كتاب
+
+467
+00:40:08,850 --> 00:40:12,570
+دراسات في الفقه، بتاخدوا التطهير بالماء، وفي
+
+468
+00:40:12,570 --> 00:40:18,650
+التطهير بإيش؟ بالتحول، إن المادة إذا تحولت من مادة
+
+469
+00:40:18,650 --> 00:40:24,530
+ناجسة إلى مادة طاهرة، خلاص، اتغير تركيبها
+
+470
+00:40:24,530 --> 00:40:30,110
+الكيميائي، بدنا نضل نقول أنا حرام؟ولذلك الخمر
+
+471
+00:40:30,110 --> 00:40:37,170
+الناجس يصبح خلّا طاهرا وعصير الفواكه الطاهر يصبح
+
+472
+00:40:37,170 --> 00:40:42,930
+خمرا ناجسا أنا بتعامل مع اللي موجود عندى
+
+473
+00:40:42,930 --> 00:40:47,670
+وبالمناسبة هنا بتدخل كمان قضية شرعية تانية لأنه
+
+474
+00:40:47,670 --> 00:40:51,470
+لها علاقة .. لها علاقة بالكيميا وكتير الناس اللي
+
+475
+00:40:51,470 --> 00:40:56,200
+بنقشوا هالأمور هذه الناس اللي بعيشوا في أوروباو
+
+476
+00:40:56,200 --> 00:41:00,830
+كويس أن تفهموها لأنها في الأساس قضية علميةإنه
+
+477
+00:41:00,830 --> 00:41:05,170
+بيجيوا على الجيلاتين الجيلاتين بدخل في تحضير كتير
+
+478
+00:41:05,170 --> 00:41:10,730
+من الأطعمة و منها الكيك و أشياء كتيرة الآن من وين
+
+479
+00:41:10,730 --> 00:41:14,750
+بيجيبوا الجيلاتين هنا المشكلة الجيلاتين في أنواع
+
+480
+00:41:14,750 --> 00:41:18,590
+منه بيجيبوها من النباتات من التفاح من غيرها زي
+
+481
+00:41:18,590 --> 00:41:23,950
+البكتين بمعنى هناك جيلاتين بأصل نباتي و هناك
+
+482
+00:41:23,950 --> 00:41:27,850
+جيلاتين بأصل حيواني الجيلاتين اللي بأصل حيواني
+
+483
+00:41:27,850 --> 00:41:31,840
+ممكن يجين من غل العظاميعني لو أخدت عظام بقر أو
+
+484
+00:41:31,840 --> 00:41:35,660
+غيره أو غيراته غالق مع بعض التحولات الكيميائية في
+
+485
+00:41:35,660 --> 00:41:39,560
+نهاية بالتهب جيلاتين الآن الإشكالية أنه في أوروبا
+
+486
+00:41:39,560 --> 00:41:45,080
+العظام اللي مشهورة أكتر هي عظام إيش؟ الخنزير وبناء
+
+487
+00:41:45,080 --> 00:41:49,440
+على ذلك جزء كبير من الجيلاتين اللي موجود عندهم
+
+488
+00:41:49,440 --> 00:41:56,880
+طالع من وين؟ طالع من الخنزير لكن على رأي كثير من
+
+489
+00:41:56,880 --> 00:42:01,790
+العلماءومنهم الدكتور القرضاوي وشيخ حسام الدين
+
+490
+00:42:01,790 --> 00:42:06,790
+عفانى والمقالات كثيرة وموجودة بأنه قد حصل على هذه
+
+491
+00:42:06,790 --> 00:42:10,410
+المواد حتى أخدناها جيلاتين ما خدناهاش زيمية ما
+
+492
+00:42:10,410 --> 00:42:13,610
+خدناهاش عضم اعملنا تفاعلات كيميائية لحد ما حصلنا
+
+493
+00:42:13,610 --> 00:42:17,910
+على الجيلاتين فالجيلاتين بيعتبروا قد طهرة بالتحول
+
+494
+00:42:17,910 --> 00:42:23,330
+حتى لو كان من إيش؟ حتى لو كان من عظام الخنزير وهذا
+
+495
+00:42:23,330 --> 00:42:28,880
+الدارج في الفتوىواضح؟ الجيلاتين حتى لو كان من عظام
+
+496
+00:42:28,880 --> 00:42:34,740
+الخنزير فهو قد طهر بالتحول على رأي كثير جدا،
+
+497
+00:42:34,740 --> 00:42:38,720
+والغالب من العلماء اللي ناقشوا هذا الموضوع والنقاش
+
+498
+00:42:39,360 --> 00:42:44,000
+فقه موجود كثير ومنشور في كتب و بجلات و بفتوى على
+
+499
+00:42:44,000 --> 00:42:47,600
+الانترنت أفهمتوا إيش يعني التطهر بالتحول؟ لأنه
+
+500
+00:42:47,600 --> 00:42:51,940
+المادة تغيرت أنا عملت عليه تفاعلات، غيرته واضح أنا
+
+501
+00:42:51,940 --> 00:42:55,420
+عملت عليه تفاعلات، ماخدتوش زي ما هو زي ما عملت على
+
+502
+00:42:55,420 --> 00:43:00,450
+الكحول تفاعلات خلته في الآخر إيش؟ خلالآن هذه
+
+503
+00:43:00,450 --> 00:43:06,010
+العملية عملية إيش؟ أكسدة المحاضرة الجاية بنعود
+
+504
+00:43:06,010 --> 00:43:09,490
+نحكي عن الأكسدة من ناحية كيميائية يعني هنا إحنا
+
+505
+00:43:09,490 --> 00:43:14,530
+اتكلمنا عن الأكسدة من ناحية ثقافية خليني أقول
+
+506
+00:43:14,530 --> 00:43:19,750
+كثقافة تفهموا إيش يعني الأكسدة؟ الآن كعوامل مؤكسدة
+
+507
+00:43:19,750 --> 00:43:21,970
+وكيمية في المحاضرة الجاية إن شاء الله
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d19c2899c4bb6038256a9e2fc793a6c60eaefa3b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_postprocess.srt
@@ -0,0 +1,2160 @@
+1
+00:00:05,080 --> 00:00:09,300
+اليوم ان شاء الله بنكمل تقريبا الجزء الأخير في هذا
+
+2
+00:00:09,300 --> 00:00:18,060
+الفصل لما قولنا موضوعنا ال alkyl halides ال R X و
+
+3
+00:00:18,060 --> 00:00:23,460
+بشكل أساسي تفاعلاتهم حكينا أنه فيه تفاعلين أساسيين
+
+4
+00:00:23,460 --> 00:00:27,960
+إما أن تتم عملية إبدال لل X substitution و هذه
+
+5
+00:00:27,960 --> 00:00:32,760
+درسناها بالتفصيل و أخدنا different mechanisms SN1
+
+6
+00:00:32,760 --> 00:00:38,680
+و SN2 mechanismsالان الاحتمال التاني ان ال X يتم
+
+7
+00:00:38,680 --> 00:00:43,500
+حذفها مع بروتون الهو elimination of HX في هذه
+
+8
+00:00:43,500 --> 00:00:48,840
+الحالة لما احذف ال X مع بروتون يتكون عندى double
+
+9
+00:00:48,840 --> 00:00:54,340
+bond بمعنى ان ال الكلهيليتز يعطوننا ال keys
+
+10
+00:00:54,340 --> 00:01:01,640
+الكلهيليتز يعطوننا ال keys هل لازم تلاحظوا نقطة ان
+
+11
+00:01:01,640 --> 00:01:08,300
+هدول التفاعلينتفاعلين خلّينا نقول تنافسيين يعني
+
+12
+00:01:08,300 --> 00:01:14,100
+ممكن التنين يحصلوا ولو بنسب متفاوتة في نفس الوقت
+
+13
+00:01:14,100 --> 00:01:19,880
+يعني بيطلع عند ناتج هو عبارة عن خليط من تفاعل
+
+14
+00:01:19,880 --> 00:01:26,500
+إبدال وتفاعلحذف يعني لو مثلا أخدت هذا المُركّب
+
+15
+00:01:26,500 --> 00:01:30,620
+اللي هو two bromopropane أو isopropyl bromide اللي
+
+16
+00:01:30,620 --> 00:01:36,620
+مار علينا و قولت بدي أفعله مع ال N A O H واضح؟
+
+17
+00:01:36,620 --> 00:01:42,350
+ممكن يصير عندى إبدال لل bromبال OH يعطينا ال
+
+18
+00:01:42,350 --> 00:01:46,510
+alcohol ال isopropyl alcohol و ممكن يصير عندى
+
+19
+00:01:46,510 --> 00:01:51,050
+عملية حذف لبروم مع إلكتروناتها لحظوا الحذف ليش
+
+20
+00:01:51,050 --> 00:01:56,490
+بيكون لبروم مع إلكتروناتها زائد واحدة من ال
+
+21
+00:01:56,490 --> 00:02:00,350
+hydrogens بهذا الشكل بدون إلكترونات طبعا لما بدى
+
+22
+00:02:00,350 --> 00:02:04,010
+تحذف هذه ال hydrogen بدون إلكترونات طب زوج
+
+23
+00:02:04,010 --> 00:02:08,230
+الإلكترونات اللى عامل bond معاها شو هيعمل؟هو اللي
+
+24
+00:02:08,230 --> 00:02:14,230
+حيلفه يعمل ال double bond واضح فبصير عملية حدث HPR
+
+25
+00:02:14,230 --> 00:02:20,310
+كأن بظبط بقول H plus PR minus لكن هو بيطلعش ايونيك
+
+26
+00:02:20,310 --> 00:02:23,910
+موليكيول موليكيول بيطلع موليكيولار موليكيول يعني
+
+27
+00:02:23,910 --> 00:02:28,230
+ال HPR مش جزء ايوني مابنقدرش نقول ان صيغته
+
+28
+00:02:28,230 --> 00:02:32,150
+الكيميائية H plus PR minus اللي هو جزء equivalent
+
+29
+00:02:33,090 --> 00:02:38,170
+بند موليكيولار موليكيول واضح الان لما بيحظف ال HPR
+
+30
+00:02:38,170 --> 00:02:42,910
+بيصير عنده elimination طبعا هذا الكلام هيعمل عندكم
+
+31
+00:02:42,910 --> 00:02:48,510
+مشكلة نوعا ما انه لو انا بدي اجي اسألكم ايش النتج
+
+32
+00:02:48,510 --> 00:02:54,360
+اللي بدكوا تحطوه واضح؟غالباً الناتج خليط من هذه
+
+33
+00:02:54,360 --> 00:02:59,880
+المراكبين واضح وإن كان ممكن يزيد في حالات معينة
+
+34
+00:02:59,880 --> 00:03:02,760
+تفاعل ال substitution ويكون تفاعل ال elimination
+
+35
+00:03:02,760 --> 00:03:07,020
+قليل وممكن في حالات تانية تكون نسبة ال elimination
+
+36
+00:03:07,020 --> 00:03:11,780
+عاليةو يكون نسبة ال substitution قليل و في حالات
+
+37
+00:03:11,780 --> 00:03:15,700
+تالتة ممكن تلاقوهم مثلا بنسبة اربعين لستين في
+
+38
+00:03:15,700 --> 00:03:19,380
+المية او خمسين لخمسين في المية يكون الناتجين وبنسب
+
+39
+00:03:19,380 --> 00:03:26,140
+تكاد تكون متساوي هذا الحقيقةبيعتمد على عوامل كثيرة
+
+40
+00:03:26,140 --> 00:03:29,980
+انه يصير الناتج اللي عنده elimination أو
+
+41
+00:03:29,980 --> 00:03:34,660
+substitution بيعتمد على عدة عوامل لحظو انا مثلا
+
+42
+00:03:34,660 --> 00:03:40,280
+ذاكرلكوا اربع انواع من العوامل العامل الأولالـ
+
+43
+00:03:40,280 --> 00:03:46,240
+type of alkyl halide نوع ال alkyl halide بشكل عام
+
+44
+00:03:46,240 --> 00:03:50,800
+بشكل عام لما يكون عنده primary alkyl halide
+
+45
+00:03:50,800 --> 00:03:55,720
+primary primary alkyl halide و بالذات ممكن هنا
+
+46
+00:03:55,720 --> 00:04:01,160
+نضيف زاد strong nucleophile strong nucleophile
+
+47
+00:04:01,160 --> 00:04:07,400
+التفاعل الأساسي إيش بيكونsubstitution غالبا
+
+48
+00:04:07,400 --> 00:04:12,840
+التفاعل بنسبته الكبيرة جدا جدا substitution وهذا
+
+49
+00:04:12,840 --> 00:04:17,660
+ال substitution كمان بيكون in SN2 ميكانيزم واضح
+
+50
+00:04:17,660 --> 00:04:23,040
+طيب واحدة ممكن تقول لو كان عنده ال primary alkyl
+
+51
+00:04:23,040 --> 00:04:27,840
+halide مع weakened nucleophile ال primary alkyl
+
+52
+00:04:27,840 --> 00:04:32,450
+halide مع weakened nucleophile غالبا متفعلشواضح؟
+
+53
+00:04:32,450 --> 00:04:35,370
+الـ Primary Alkyl Halide لو بدأ أضعه على الجهة
+
+54
+00:04:35,370 --> 00:04:40,570
+التانية زي الـ weak nucleophile غالبا ما بيصيرش
+
+55
+00:04:40,570 --> 00:04:46,490
+نتيجة لا حتى تفاعل إبدال بشكل كامل ولا تفاعل
+
+56
+00:04:46,490 --> 00:04:51,490
+elimination واضح؟ الآن لما يكون عنده secondary ال
+
+57
+00:04:51,490 --> 00:04:55,330
+secondary هو دائما اللي فيه الاحتمالين عاليين
+
+58
+00:04:55,330 --> 00:04:59,750
+بيكون عندهSubstitution و Elimination
+
+59
+00:05:27,300 --> 00:05:33,300
+أنا بقدر افعله مع التانين بقدر افعله مع ال strong
+
+60
+00:05:33,300 --> 00:05:39,380
+و بقدر افعله مع weak nucleophile الان انتوا اخدتوا
+
+61
+00:05:39,380 --> 00:05:43,080
+ان ال tertiary alkyl halide مع ال weak nucleophile
+
+62
+00:05:43,080 --> 00:05:48,590
+من اللي بيعمل substitution ب أسهم واحدةهذا الكلام
+
+63
+00:05:48,590 --> 00:05:52,870
+صحيح التيرتشاري الكلهيلايد مع الويك نيكليوفايل
+
+64
+00:05:52,870 --> 00:05:57,410
+بشكل أساس بيعمل substitution أعلى بـSN1 و لما يكون
+
+65
+00:05:57,410 --> 00:06:03,510
+تيرتشاري مع strong نيكليوفايل بيعمل elimination
+
+66
+00:06:03,510 --> 00:06:07,410
+طبعا
+
+67
+00:06:07,410 --> 00:06:11,480
+ال elimination ما أخدناش الميكانزمقلولي حتى الآن
+
+68
+00:06:11,480 --> 00:06:14,520
+هناخدها بعد شوية لما ناخدها بس عشان انا الجدول
+
+69
+00:06:14,520 --> 00:06:17,640
+يكتمل معاكم هتلاحظوا انه بنقوله بيعمل elimination
+
+70
+00:06:17,640 --> 00:06:24,020
+ال A2 ميكانيزمبنتعلم بعد شوية إيش معناه؟ A2
+
+71
+00:06:24,020 --> 00:06:30,500
+Mechanism تقريبا هيك الأمور بتصير سهلة الجزء اللي
+
+72
+00:06:30,500 --> 00:06:35,700
+احنا كنا ماخدينه حتى ما تحسوش ان العلم فيه تناقض
+
+73
+00:06:35,700 --> 00:06:39,840
+احنا كنا ماخدينه ان ال primary alkyl halide مع ال
+
+74
+00:06:39,840 --> 00:06:43,620
+strong nucleophileمين اللي بيعمل substitution و ب
+
+75
+00:06:43,620 --> 00:06:47,920
+SN2 هذا الكلام كنا ماخدينه و كنا ماخدينه ان ال
+
+76
+00:06:47,920 --> 00:06:51,500
+tertiary alkyl halide مع ال weak nucleophile مين
+
+77
+00:06:51,500 --> 00:06:56,940
+اللي بيعمل substitution ب SN1 الآن يمكن نضيفها لأن
+
+78
+00:06:56,940 --> 00:07:01,200
+ال primary مع ال weak nucleophile غالبا مافيش
+
+79
+00:07:01,200 --> 00:07:07,000
+تفاعلوالـ tertiary مع الـ strong الـ nucleophile
+
+80
+00:07:07,000 --> 00:07:14,460
+بيعمل إيقاف بميكانيزم E2 تقريبا يمكن هذا أكثر أو
+
+81
+00:07:14,460 --> 00:07:18,880
+من أكثر العوامل اللي بتأثر على التفاعل أن نشوف الـ
+
+82
+00:07:18,880 --> 00:07:21,580
+Alkyl Halide اللي عندنا primary أو secondary أو
+
+83
+00:07:21,580 --> 00:07:27,640
+tertiary و ال nucleophileweak أو strong و النتائج
+
+84
+00:07:27,640 --> 00:07:32,200
+موجودة عندكم ابتيجي عوامل أخرى تأثيرها أقل من هدول
+
+85
+00:07:32,200 --> 00:07:36,340
+يعني العوامل الأساسية زي لما أخدنا الميكانيزم كنا
+
+86
+00:07:36,340 --> 00:07:42,800
+بشكل أساسي نركز نوع الالكالهلايد نوع النيوكليوفايل
+
+87
+00:07:42,800 --> 00:07:48,480
+واضح نوع الالكالهلايد و نوع النيوكليوفايل
+
+88
+00:07:49,530 --> 00:07:53,750
+واضح؟ زي نفترض اتنين أصدقاء بدوا يكون بينهم علاقة
+
+89
+00:07:53,750 --> 00:07:58,890
+أحمد ومحمد أكتر إشي بيحدد هذه العلاقة أحمد ومحمد
+
+90
+00:07:58,890 --> 00:08:04,050
+هذا ما بيمنعش أنه في ظروف خارجية موجودة ممكن أنها
+
+91
+00:08:04,050 --> 00:08:07,370
+تأثر على هذا الكلام لكن إيش الشيء الأساسي اللي
+
+92
+00:08:07,370 --> 00:08:14,520
+بيأثر؟ اللي هم نفسالأساسية نفس المتفاعلين الان من
+
+93
+00:08:14,520 --> 00:08:18,620
+الأشياء الأساسية الإضافية اللي ممكن تأثر هي ال
+
+94
+00:08:18,620 --> 00:08:22,620
+solvent انا اي تفاعل بعمله ب solvent لاحظوا معي لو
+
+95
+00:08:22,620 --> 00:08:26,760
+كنت مثلا تفاعل عمله ب water بميه الميه بتشجع ال
+
+96
+00:08:26,760 --> 00:08:30,500
+substitution لو كنت عامله ب more polar solvent زي
+
+97
+00:08:30,500 --> 00:08:35,310
+اثانول الاثانول بشجعالـ elimination هاي معلومات
+
+98
+00:08:35,310 --> 00:08:39,190
+بالتجربة إيش نسبها ما إلى ذلك مابنقدرش كل شغلة
+
+99
+00:08:39,190 --> 00:08:44,710
+ندخل فيها درجة الحرارة مثلا الحرارة كل ما كانت
+
+100
+00:08:44,710 --> 00:08:49,690
+مرتفعة في إثناء التفاعل بتشجع ال elimination ال
+
+101
+00:08:49,690 --> 00:08:53,350
+concentration بالذات إذا كان عنده strong
+
+102
+00:08:53,350 --> 00:08:57,630
+nucleophile أو strong base يعني لما أنا بدي أجي
+
+103
+00:08:57,630 --> 00:09:00,790
+أحط هنا strong زي ما أخد ال KOH مثلا
+
+104
+00:09:03,410 --> 00:09:08,770
+هذا قوي و أكون بفعله مع الـ tertiary هيشجع بشكل
+
+105
+00:09:08,770 --> 00:09:14,350
+كبير ال elimination ال concentration of sodium or
+
+106
+00:09:14,350 --> 00:09:19,090
+potassium hydroxide تركيز عالية منه بتشجع ال
+
+107
+00:09:19,090 --> 00:09:24,370
+elimination بشكل أساسي في حالة ما يكون التفاعل مع
+
+108
+00:09:24,370 --> 00:09:28,570
+ال tertiary مع ال primary بيظل تفاعلنا الأساسي إيش
+
+109
+00:09:28,570 --> 00:09:35,270
+ال substitutionعلى أي حال، هنا يعني بتحسوا أنه
+
+110
+00:09:35,270 --> 00:09:41,790
+الكلام كتير و شوية بلخم، قد يظن البعض أنه بده قول
+
+111
+00:09:41,790 --> 00:09:47,030
+فصل، بصراحة لازم تكونوا عارفين أن الدنيا مابتمشيش
+
+112
+00:09:47,030 --> 00:09:57,090
+دائما بقول فصلإنه في أشياء هي هيك مش واضحة يعني في
+
+113
+00:09:57,090 --> 00:10:01,070
+النهاية لازم أعمل تجربة لحد ما أعرف النتيجة بالظبط
+
+114
+00:10:01,070 --> 00:10:06,910
+يعني مش كل إشي بيكون مثالي و بنقدر نحكم عليه بشكل
+
+115
+00:10:06,910 --> 00:10:12,090
+مثالي غير في الآخر إيشالواقع والتجربة هي اللي
+
+116
+00:10:12,090 --> 00:10:15,770
+بتطلع النتيجة النهائية يعني كلكم انا متأكد مليون
+
+117
+00:10:15,770 --> 00:10:19,410
+في المية دخلين على مساق ال organic chemistry بنية
+
+118
+00:10:19,410 --> 00:10:23,610
+صادقة في الدراسة وبنية صادقة بتحصيل علامة 100 من
+
+119
+00:10:23,610 --> 00:10:29,470
+100 الان هذا الوضع المثالي ان انتوا بتحضروا عندكم
+
+120
+00:10:29,470 --> 00:10:33,730
+الكتب بتدرسوا بتسمعوا المحاضرة بدكم تاخدوا 100 من
+
+121
+00:10:33,730 --> 00:10:37,710
+100 الان ايش أرض الواقع؟الله يعيدكوا و أقولكوا بس
+
+122
+00:10:37,710 --> 00:10:43,850
+واضح مش دايما الواقع بيطلع مثالي وبالتالي هلما
+
+123
+00:10:43,850 --> 00:10:47,650
+أقولكوا ممكن هيك ممكن هيك ممكن هيك انتوا في الحياة
+
+124
+00:10:47,650 --> 00:10:51,810
+الاجتماعية لو نقشته أي موضوع مش بتقول والله ممكن
+
+125
+00:10:51,810 --> 00:10:55,810
+هيك ممكن هيك ممكن هيك في إشي دايما هيك واضح و
+
+126
+00:10:55,810 --> 00:11:02,010
+clear cut هيك طبيعة إيش طبيعة الحياةالان لو اتينا
+
+127
+00:11:02,010 --> 00:11:08,170
+بدنا ندرس ال mechanisms of elimination واضح؟لو
+
+128
+00:11:08,170 --> 00:11:14,890
+أخدنا ال a2 ميكانيزم ال a2 ميكانيزم ال a2 ميكانيزم
+
+129
+00:11:14,890 --> 00:11:19,590
+دائما بتتم في حالة ما يكون عنده strong base و أكتر
+
+130
+00:11:19,590 --> 00:11:22,930
+إيش يقولنا لما يكون عنده strong base مع tertiary
+
+131
+00:11:22,930 --> 00:11:27,210
+يعني بدكم تعملوها زي فتوة شرقية أنه ال mechanism
+
+132
+00:11:27,210 --> 00:11:32,890
+إيش ال a2 ميكانيزم ال a2 تقريبا شبيه بال S and 2
+
+133
+00:11:32,890 --> 00:11:42,170
+إذا بتذكروا ال S and 2 كانتone step mechanismمظبوط
+
+134
+00:11:42,170 --> 00:11:48,310
+ولا لأ وبنفس الوقت كانت ال kinetics تبعتها معتمدة
+
+135
+00:11:48,310 --> 00:11:52,970
+على متفاعلين يعني ال rate تبعها بيساوي تركيز ال
+
+136
+00:11:52,970 --> 00:11:57,590
+alkyl halide في تركيز ال nucleophile ال OH minus
+
+137
+00:11:57,590 --> 00:12:02,850
+وفيها نوع من المصارعة بين متفاعلين مش واحد واقف
+
+138
+00:12:02,850 --> 00:12:07,070
+بتفرج و التاني بتفعل هذا الكلام وين شفته في ال SN1
+
+139
+00:12:07,070 --> 00:12:13,720
+الآن ال E2 في هذه الشغلة موازيةللـ SN2 الـ E2
+
+140
+00:12:13,720 --> 00:12:21,040
+موازية للـ SN2 لما بيجي الـ OH- لما بيجي الـ OH- و
+
+141
+00:12:21,040 --> 00:12:26,360
+بده يتفاعل لاحظوا هنا الـ OH- عبارة عن negative
+
+142
+00:12:26,360 --> 00:12:32,240
+charge و negative charge أسرع ما يمكن أسرع ما يمكن
+
+143
+00:12:32,240 --> 00:12:38,560
+بدها إيش؟بيدها positive دائما ال negative أسرع ما
+
+144
+00:12:38,560 --> 00:12:44,000
+يمكن بده positive الآن لو إجينا سألنا أنفسنا و
+
+145
+00:12:44,000 --> 00:12:48,360
+خلينا ناخد التفصيل اللي تحت يترى وين ال positive
+
+146
+00:12:48,360 --> 00:12:54,220
+ممكن تلاقيها ال OH minus ممكن تلاقي ال carbon هادى
+
+147
+00:12:55,760 --> 00:12:59,600
+واضح؟ ممكن تلاقي الـ carbon هذه اللي هنا مشكلة
+
+148
+00:12:59,600 --> 00:13:03,780
+انها partially positive و هذه البرومين partially
+
+149
+00:13:03,780 --> 00:13:08,540
+negative اذا هي positive الان في كمان positive
+
+150
+00:13:08,540 --> 00:13:11,100
+تاني ال proton ال H
+
+151
+00:13:14,170 --> 00:13:18,530
+هذا الـ H لحاله برضه يمثل إيش؟ positive و لو بده
+
+152
+00:13:18,530 --> 00:13:22,550
+يطلع لحاله يظل زوج الإلكترونات positive كامل إذا
+
+153
+00:13:22,550 --> 00:13:27,510
+الـ OH هذه اللي جاية وبتبحث عن positive صار عندها
+
+154
+00:13:27,510 --> 00:13:32,710
+الـ H عبارة عن positive و ال carbon اللي هنا عبارة
+
+155
+00:13:32,710 --> 00:13:38,810
+عن positive واضح؟ إذا هاجمت على ال carbon اللي هنا
+
+156
+00:13:38,810 --> 00:13:45,860
+هيبدأ يصير عندي خمس روابط حتوت ردالـ PR هيصير عند
+
+157
+00:13:45,860 --> 00:13:51,760
+الـ SN2 ميكانيزم هيصير عند ال substitution الإبدال
+
+158
+00:13:51,760 --> 00:13:57,300
+بمعنى لو أنا بدي أجي أقول هي ال OH- هاجمت هنا و
+
+159
+00:13:57,300 --> 00:14:03,580
+طردت ال CL أي تفاعل بدي يصير الإبدال إنه مكان مكان
+
+160
+00:14:03,580 --> 00:14:10,720
+عندي ال CL صار عنده OH طيب لو هذه هاجمت على ال
+
+161
+00:14:10,720 --> 00:14:15,820
+hydrogen هناأخدت بس الـ H لحالها بدون أزواج
+
+162
+00:14:15,820 --> 00:14:20,440
+الإلكترونات شو بده يصير لزوج الإلكترونات هذا؟ بده
+
+163
+00:14:20,440 --> 00:14:23,300
+يكوّن double bond مجرد ما يبدأ يكوّن double bond
+
+164
+00:14:23,300 --> 00:14:28,920
+كام bond بيصير عندي هنا؟ خمسة عشان نتخلص منهم الـ
+
+165
+00:14:28,920 --> 00:14:34,000
+PR بتطلع إذا في خطوة واحدة الميكانيزم ببساطة إنه
+
+166
+00:14:34,000 --> 00:14:40,400
+في خطوة واحدة الـ OH- بتيجي مع الـ H صار هذا زوج
+
+167
+00:14:40,400 --> 00:14:49,190
+إلكتروناتبلوف بهذا الشكل عشان ما يصيبش خمس بتطلع
+
+168
+00:14:49,190 --> 00:14:56,350
+ال PR طبعا هنا لاحظوا انه هيطلع عندى PR minus و ال
+
+169
+00:14:56,350 --> 00:15:01,090
+PR minus معاكش بده يصفق ال PR minus عفوا مع ال
+
+170
+00:15:01,090 --> 00:15:05,550
+sodium ماهي ال OH minus ايش بيكون معها Sodium او
+
+171
+00:15:05,550 --> 00:15:11,060
+كوتاسيوم يعني تخيلوا كانت يا K plusيعني ايه a a
+
+172
+00:15:11,060 --> 00:15:15,040
+plus و a h minus فال بي ار ماينوس هذه مع ال كي بلس
+
+173
+00:15:15,040 --> 00:15:19,660
+ايه بتعمل كي بي ار و ال a h minus مع ال اتش بلس
+
+174
+00:15:19,660 --> 00:15:24,900
+مية اذا نتيجة هذا التفاعل ان ال a h minus اخدت ال
+
+175
+00:15:24,900 --> 00:15:31,830
+اتش بلس عملت المية الان ال كي بلس مع ال بي ارعمل
+
+176
+00:15:31,830 --> 00:15:38,850
+KPR و الـ Alkyl Halide شو صار؟ صار ألكين صار ألكين
+
+177
+00:15:38,850 --> 00:15:42,390
+لأن هنا التفاعل في خطوة واحدة بمعنى هذه بتاخد
+
+178
+00:15:42,390 --> 00:15:46,450
+الأكشن هذه بتلوف هذه بتطلع بنفس اللحظة كام متفاعل
+
+179
+00:15:46,450 --> 00:15:56,610
+بتشوفوا عندكم؟ لأ هاي واحد وهاي واحد عشان هيك هذا
+
+180
+00:15:56,610 --> 00:16:06,220
+التفاعل بنقول عنه احنا one stepوبنقول عنه second
+
+181
+00:16:06,220 --> 00:16:11,580
+order إيش معناه second order؟ إن ال rate تبعته
+
+182
+00:16:11,580 --> 00:16:22,120
+بتسوي K في OH- في RXكل واحدة لأس واحد بالتجارة
+
+183
+00:16:22,120 --> 00:16:26,900
+واضح؟ إذا هذا تفاعل من one step و second order
+
+184
+00:16:26,900 --> 00:16:29,640
+reaction the rate of reaction depends on the
+
+185
+00:16:29,640 --> 00:16:33,620
+concentration of the hydroxide ion كل ما كان ال
+
+186
+00:16:33,620 --> 00:16:39,680
+hydroxide ايون أكتر كل ما كان التفاعل أسرع يمكن
+
+187
+00:16:39,680 --> 00:16:48,620
+هنا يجيني شغلة لما نيجي نقول انهالـ strong base مع
+
+188
+00:16:48,620 --> 00:16:53,520
+ال primary قبل شوية لسه قولنا إيش بيعطي بشكل أساسي
+
+189
+00:16:53,520 --> 00:16:59,580
+إبدال ال strong base مع ال tertiary إيش بيعطي بشكل
+
+190
+00:16:59,580 --> 00:17:06,480
+أساسي elimination ليش بيصير هذا الكلام؟ واضح؟ ليش
+
+191
+00:17:06,480 --> 00:17:12,260
+ال strong base مع ال primary بيعطيإبدال والـ
+
+192
+00:17:12,260 --> 00:17:16,140
+strong base مع الـ tertiary غالبا يعني يصل إلى
+
+193
+00:17:16,140 --> 00:17:22,920
+نسبة 100% بيعطي elimination واضح؟ انتوا اتطلعوا
+
+194
+00:17:22,920 --> 00:17:28,960
+على هذه الـ OH- وافترضوا ان هذه هي الـ strong base
+
+195
+00:17:28,960 --> 00:17:33,900
+لو كان هذه الـ carbon tertiary بمعنى هنا في عندى R
+
+196
+00:17:33,900 --> 00:17:39,850
+الـ R ايش مالها؟ كبيرة وهنا في عندى Rالـ R كبيرة
+
+197
+00:17:39,850 --> 00:17:44,310
+وهي الـ tertiary وهنا فيه positive مخبّى في قلبهم
+
+198
+00:17:44,310 --> 00:17:50,290
+وهنا فيه positive على الطرف أنه أسهل الـ OH minus
+
+199
+00:17:50,290 --> 00:17:55,030
+تيجي على هذا ال positive فيه لو أسع تصل ال
+
+200
+00:17:55,030 --> 00:17:59,610
+positive لل carbon عشانك مابيصيرش إبدال ملاحظين
+
+201
+00:17:59,610 --> 00:18:05,420
+انتوا؟مع الـ tertiary الـ OH- ما عندهاش وسع تصل
+
+202
+00:18:05,420 --> 00:18:10,900
+للكربون هذه الموجة بل الكربون مدفون مدفونة لما
+
+203
+00:18:10,900 --> 00:18:17,540
+تتخيل ان هذا الكربون مثلا CH3 CHHH و هنا CH3 CHHH
+
+204
+00:18:17,540 --> 00:18:25,930
+كله محوط قادرة تصل ال positive المخفي اللي هنالكن
+
+205
+00:18:25,930 --> 00:18:32,130
+بسهولة بتصطدم بـ H بأي H plus لأن الـ H plus طرفية
+
+206
+00:18:32,130 --> 00:18:39,830
+الكربون مخفية الواحد دايما بياخد من الاشي اللي على
+
+207
+00:18:39,830 --> 00:18:46,650
+الطرف و لا من الاشي المخفي الآن زي ما حكينا عندنا
+
+208
+00:18:46,650 --> 00:18:52,740
+الـ OH minus بتبحث عن positive في positiveمخبية
+
+209
+00:18:52,740 --> 00:18:57,180
+صعبة الوصول اليها و في positive طرفية ان هي اللي
+
+210
+00:18:57,180 --> 00:19:00,700
+هتاخدها في حالة ال tertiary الطرفية فطالما انه
+
+211
+00:19:00,700 --> 00:19:04,280
+خبطت في هذا ال positive اللي على الطرف هنا معنى
+
+212
+00:19:04,280 --> 00:19:09,440
+ذلك هتمشي او تستكمل الميكانزم ب E2 elimination
+
+213
+00:19:09,440 --> 00:19:13,500
+هيكون التفاعل بشكل أساسي elimination لكن لو هذه
+
+214
+00:19:13,500 --> 00:19:18,980
+كانت primary H OH في وسع كتير في وسع كتير لل OH
+
+215
+00:19:18,980 --> 00:19:23,600
+minusتيجي و تتفاعل فبتتم عملية ال substitution
+
+216
+00:19:23,600 --> 00:19:30,500
+الان لو سألناكم على .. لو سألناكم على هذا الكلام
+
+217
+00:19:30,500 --> 00:19:37,860
+رغم انه يبدو كلام كيميائي فيه له كمان دليل شرعي؟
+
+218
+00:19:37,860 --> 00:19:46,360
+اه في الشريعة ما هي الكيميا زي الشريعة اه لإن طبعا
+
+219
+00:19:48,300 --> 00:19:52,720
+أيوة، وين بيربطوا المفاهيم العلمية بالإنسانية؟
+
+220
+00:19:52,720 --> 00:20:03,320
+الاشي بياخد اللي على الطرف ولا اللي في النص؟ إنما
+
+221
+00:20:03,320 --> 00:20:08,280
+يأكلوا الذئبه من الغنم القاصية الذئب لما بيجي يعمل
+
+222
+00:20:08,280 --> 00:20:12,120
+abstraction نحنا هنا ناخد حاجة، نتفاعل مع حاجة
+
+223
+00:20:12,120 --> 00:20:15,860
+بيجي الذئب على غنمة في وسط القطيع ولا على اللي شرد
+
+224
+00:20:15,860 --> 00:20:20,900
+على برة؟على اللي شارد لبرا، مظبوط ولا لأ؟ دايما
+
+225
+00:20:20,900 --> 00:20:25,660
+اللي متطرف وشارد لبرا هو اللي بيجي الذئب بيأكله،
+
+226
+00:20:25,660 --> 00:20:28,660
+مظبوط ولا لأ؟ الآن هذه الـH، ما شاء الله عنهاية
+
+227
+00:20:28,660 --> 00:20:33,260
+طرفية، وهذا الـcarbon في حالة الترشري مخفية،
+
+228
+00:20:33,260 --> 00:20:39,950
+مدفونةما هو الأسهل للـ OH-؟ أن تأخذ الأشي الخارجي
+
+229
+00:20:39,950 --> 00:20:45,870
+الطرفي ولذلك هذا التعليل أنه ليش الـ tertiary مع
+
+230
+00:20:45,870 --> 00:20:51,090
+الـ strong nucleophiles undergo mainly elimination
+
+231
+00:20:51,090 --> 00:20:57,030
+reaction with E2 ميكانيزم because it can reach ..
+
+232
+00:20:57,030 --> 00:21:02,840
+طبعا هذا سكندريهذا اللي هنا secondary، تخيلوا لو
+
+233
+00:21:02,840 --> 00:21:07,800
+كان tertiary، بتكون العملية أصعب، it can reach the
+
+234
+00:21:07,800 --> 00:21:16,220
+H plus easier than the carbon plusواضح؟ بتقدر تصل
+
+235
+00:21:16,220 --> 00:21:21,900
+للـ H Plus أسهل ما تصل لـ Carbon واضح؟ ولهذا احنا
+
+236
+00:21:21,900 --> 00:21:25,000
+كتبنا الجملة انه لما يكون عندنا tertiary alkyl
+
+237
+00:21:25,000 --> 00:21:29,940
+halide مع strong base زي الـ KOH التفاعل بشكل أساس
+
+238
+00:21:29,940 --> 00:21:37,180
+ال main reaction is elimination الآن هنا بتجينا
+
+239
+00:21:37,180 --> 00:21:46,810
+شغلة مراتموجودة عندنا بمثل بيقول خيره خيره واضح
+
+240
+00:21:46,810 --> 00:21:50,690
+الكلام نفسه بيجي مرات و بيواجهنا بالكيميا لو
+
+241
+00:21:50,690 --> 00:21:54,930
+افترضت عند هذا المركب .. لو افترضت عند هذا المركب
+
+242
+00:21:54,930 --> 00:22:02,630
+one two three four two promo بيوتينوأنا بدي أعمل
+
+243
+00:22:02,630 --> 00:22:06,550
+تفاعل مع الـ OH- مركز إنه أشوف ناتج ال elimination
+
+244
+00:22:06,550 --> 00:22:11,250
+إحنا قلنا أكيد بزام بنحكي عن elimination بده تطلع
+
+245
+00:22:11,250 --> 00:22:16,950
+ال PR مع إلكتروناتها OH على كربونة مجاورة دائما ال
+
+246
+00:22:16,950 --> 00:22:21,470
+H من وين بتطلع؟ مش من نفس الكربون من الكربونة
+
+247
+00:22:21,470 --> 00:22:24,870
+المجاورة عشان تعمل double bond الآن هنا بنلاحظ
+
+248
+00:22:24,870 --> 00:22:28,590
+عندي احتمال إيه؟ إنه هذه الكربون هذه الكربون اللي
+
+249
+00:22:28,590 --> 00:22:32,960
+هنا في عندها احتمال هناو في عندها احتمال هذا لو
+
+250
+00:22:32,960 --> 00:22:38,360
+اتت ال OH اخدت هذا ال H شو عيصر عندى؟ هاي البونده
+
+251
+00:22:38,360 --> 00:22:42,060
+هاتيجي و تعمل double bond هاتيجي و تعمل double
+
+252
+00:22:42,060 --> 00:22:43,040
+bond هاتيجي و تعمل double bond هاتيجي و تعمل
+
+253
+00:22:43,040 --> 00:22:44,660
+double bond هاتيجي و تعمل double bond هاتيجي و
+
+254
+00:22:44,660 --> 00:22:46,540
+تعمل double bond هاتيجي و تعمل double bond هاتيجي
+
+255
+00:22:46,540 --> 00:22:47,780
+تعمل double bond هاتيجي و تعمل double bond هاتيجي
+
+256
+00:22:47,780 --> 00:22:52,400
+و تعمل double bond
+
+257
+00:22:55,920 --> 00:23:01,360
+هيطلع عنده ألوان بيوتين إذا أنا في عند جنب ال PR
+
+258
+00:23:01,360 --> 00:23:07,300
+من الجهتين أتشز وين بده يكون الإختيار أنه بيطلع
+
+259
+00:23:07,300 --> 00:23:11,740
+بشكل أعلى هنا في عندنا قاعدة بتقول لما يكون عند
+
+260
+00:23:11,740 --> 00:23:17,320
+هذا النمط من الإختيار مش دايما موجود هذا النمط
+
+261
+00:23:17,320 --> 00:23:22,440
+يعني مرات مابيكونش غيرنوع واحد فقط من الهيدروجين
+
+262
+00:23:22,440 --> 00:23:27,580
+وما بيكون إلا احتمال واحد للناتج مرات بيكون عنده
+
+263
+00:23:27,580 --> 00:23:32,420
+احتمالين ومرات بيكون عنده تلاتة يعني لو اتخيلتوا
+
+264
+00:23:32,420 --> 00:23:35,760
+مثلا ان هذا ال carbon اللي حملة PR حملة هنا كمان
+
+265
+00:23:35,760 --> 00:23:40,400
+carbon وعليها etchesيا بده يطلع من هنا، يا من هنا،
+
+266
+00:23:40,400 --> 00:23:44,060
+يا من ال carbon الثالثة، بصير عندي تلت احتمالات طب
+
+267
+00:23:44,060 --> 00:23:46,780
+لما يكون عندي احتمالين او تلت احتمالات، اي
+
+268
+00:23:46,780 --> 00:23:50,840
+الاحتمالات هو المفضل الحدث؟ عندنا قاعدة بسيطة
+
+269
+00:23:50,840 --> 00:23:57,220
+بيسموها the more substituted ال keen will form ال
+
+270
+00:23:57,220 --> 00:24:02,780
+keen اللي فيه substitution اكتر بيتكول، الان بيصير
+
+271
+00:24:02,780 --> 00:24:09,320
+ايش معنى؟more substituted القين واضح؟ عشان نعرف
+
+272
+00:24:09,320 --> 00:24:12,900
+معنى more substituted القين يمكن لازم نكون
+
+273
+00:24:12,900 --> 00:24:18,120
+متذاكرين ال unsubstituted القين القين الغير مبدل
+
+274
+00:24:18,120 --> 00:24:23,080
+إيش هو القين الغير مبدل اللي بنسميه ال parent
+
+275
+00:24:23,080 --> 00:24:28,320
+القين في قلقين إيش بنسميه ال parent القين ال
+
+276
+00:24:28,320 --> 00:24:33,360
+parent يعني القين الأساسي اللي هو ال unsubstituted
+
+277
+00:24:33,360 --> 00:24:34,160
+معنى parent
+
+278
+00:24:36,900 --> 00:24:41,000
+unsubstituted مافيش عليه ولا إبدال أبو ال الكينز
+
+279
+00:24:41,000 --> 00:24:45,760
+كلها هو الاثيلين اللي مافيش عليه ولا إبدال واضح
+
+280
+00:24:45,760 --> 00:24:53,100
+فال parent الكين لما يكون عندى C double bond C H H
+
+281
+00:24:53,100 --> 00:25:00,580
+H H أكم هيدروجينة عندى أربع في أي واحدة منهم إبدلت
+
+282
+00:25:01,580 --> 00:25:06,860
+بزام كله هيدروجينز، إذا هذا هو الـ parent، الأبو،
+
+283
+00:25:06,860 --> 00:25:11,620
+مافيش فيه ولا إبدال، عرفتوا إيش معنى parent؟ طيب
+
+284
+00:25:11,620 --> 00:25:15,080
+لو بدي أجي أقولكم مثلا في ال aromatic compounds،
+
+285
+00:25:15,080 --> 00:25:20,200
+إيش ال parent aromatic compound؟البنزين عليه ستة
+
+286
+00:25:20,200 --> 00:25:25,360
+هيدروجينات ممكن أبدل منهم واحدة بيصير مونو
+
+287
+00:25:25,360 --> 00:25:30,320
+substitute ممكن تنتين تراي substitute ممكن تلاتة
+
+288
+00:25:30,320 --> 00:25:36,700
+ممكن أربعة تترا substitute وها كذا الآن الاثيليل
+
+289
+00:25:36,700 --> 00:25:40,780
+is the parent compound the unsubstituted compound
+
+290
+00:25:40,780 --> 00:25:48,220
+الآن ممكن أبدأ أعمل عمليات إبدال للهيدروجينلو إجيت
+
+291
+00:25:48,220 --> 00:25:53,840
+شيلت هيدروجين و حطيت بدالها R بيصير هذا كام
+
+292
+00:25:53,840 --> 00:25:58,400
+substitution فيه؟ واحد .. one substitution لو من
+
+293
+00:25:58,400 --> 00:26:02,780
+أي مكان شيلت كمان هيدروجين و حطيت كمان R؟ die
+
+294
+00:26:02,780 --> 00:26:07,640
+substituted لو شيلت كمان هيدروجين و حطيت كمان R
+
+295
+00:26:07,640 --> 00:26:12,580
+تالتة try substituted لو شيلت كمان هيدروجين و حطيت
+
+296
+00:26:12,580 --> 00:26:19,280
+كمان R رابعةأنا ممكن أعمل على الاثيلين إبدال
+
+297
+00:26:19,280 --> 00:26:23,720
+لهيدروجين تنتين تلاتة أربعة إذا صار عندى غير
+
+298
+00:26:23,720 --> 00:26:28,480
+المبدل إطلاقا وصار عندى أقصى إبدال على الاثيلين
+
+299
+00:26:28,480 --> 00:26:35,090
+جداش أربعة أني أبدل الأربع هيدروجيناتالآن لما بدنا
+
+300
+00:26:35,090 --> 00:26:39,350
+نشوف أي ناتج بيطلع بنشوف أكم إبدال عندنا لو لاحظنا
+
+301
+00:26:39,350 --> 00:26:44,650
+ناتج تم فيه أربع إبدالات و الناتج التاني فيه
+
+302
+00:26:44,650 --> 00:26:49,370
+إبدالين من المفضل اللي فيه أربعة لو ناتج فيه تلت
+
+303
+00:26:49,370 --> 00:26:55,040
+إبدالات و التاني فيه إبدالين من المفضل التلاتةنجي
+
+304
+00:26:55,040 --> 00:26:59,440
+نطلع على النواتج المكونة هنا و اتخيلوا الـ etches
+
+305
+00:26:59,440 --> 00:27:03,040
+كأنها طالعة من الـ carbons تبعون الـ double bond و
+
+306
+00:27:03,040 --> 00:27:08,960
+نجي نسأل نفسنا في هذا المُركّب الـ one بيوتين كام
+
+307
+00:27:08,960 --> 00:27:15,020
+إبدال عنده؟ لاحظوا معي لو شطبت هذول ال etches
+
+308
+00:27:15,020 --> 00:27:21,120
+موجودين، هاي etch، هاي etch، فيهم إبدال؟ و هاد ال
+
+309
+00:27:21,120 --> 00:27:27,780
+etchموجودة، إذا كام إبدال عندى في هذا؟ واحد فقط
+
+310
+00:27:27,780 --> 00:27:32,820
+هنا في عندى one substitution من الأربعة
+
+311
+00:27:32,820 --> 00:27:38,840
+هيدروجينات، كم ضايل؟ ضايل تلاتة ابدلت واحدة، إذا
+
+312
+00:27:38,840 --> 00:27:43,400
+هنا ال substitution كم؟ واحد لو أجيت هنا حوالي ال
+
+313
+00:27:43,400 --> 00:27:49,880
+double bond، إيش في عندى؟ H وH كم إبدال عندى؟
+
+314
+00:27:49,880 --> 00:27:54,250
+اتنينإذا هذا المركب الـ two butane كام
+
+315
+00:27:54,250 --> 00:27:57,810
+substitution فيه؟ اتنين وال one butane كام
+
+316
+00:27:57,810 --> 00:28:02,750
+substitution فيه؟ واحد أي مركب اللي بتكون بنسبة
+
+317
+00:28:02,750 --> 00:28:07,970
+أعلى اللي هو ال more substituted إذا ال two butane
+
+318
+00:28:07,970 --> 00:28:13,410
+will form more than the one butane because two
+
+319
+00:28:13,410 --> 00:28:16,510
+butane is more substitutedفاهمتوا إيش معناه more
+
+320
+00:28:16,510 --> 00:28:22,270
+substituted؟ فدائما إذا في عندكم احتمالات أنه ممكن
+
+321
+00:28:22,270 --> 00:28:26,950
+هذا الالكين و هذا الالكين بأرسم اتنين بشوف أن هو
+
+322
+00:28:26,950 --> 00:28:31,850
+ال more substituted بالتجربة لاحظوا كثيرا حتى
+
+323
+00:28:31,850 --> 00:28:35,170
+أصبحت قاعدة في النهاية أنه دائما ال more
+
+324
+00:28:35,170 --> 00:28:39,840
+substituted ال keen هو اللي إيش هو اللي بيتكونواضح
+
+325
+00:28:39,840 --> 00:28:44,020
+إذا كيف لما يكون عندى PR من أكثر من جهة Hydrogen
+
+326
+00:28:44,020 --> 00:28:50,140
+بارسم كل النواتج الممكنة و بشوف ال more
+
+327
+00:28:50,140 --> 00:28:53,580
+substituted الان واحدة ممكن تقول ممكن التانية يطلع
+
+328
+00:28:53,580 --> 00:28:56,120
+هذا فيه two substitution و هذا two substitution
+
+329
+00:28:56,120 --> 00:29:01,640
+وقتها بطلع خليط شبه متساوي من مركبين وقتها بطلع
+
+330
+00:29:01,640 --> 00:29:06,200
+خليط شبه متساوي من مركبين
+
+331
+00:29:18,410 --> 00:29:23,430
+بنجي للنوع التاني للنوع التاني من ال elimination و
+
+332
+00:29:23,430 --> 00:29:27,370
+احنا قولنا هذا النوع التاني من ال elimination اكتر
+
+333
+00:29:27,370 --> 00:29:33,810
+اشي ممكن يواجهنا لما يكون في عندنا weak ال
+
+334
+00:29:33,810 --> 00:29:38,730
+nucleophile او weak base طالما weak nucleophile
+
+335
+00:29:38,730 --> 00:29:43,890
+اتفقنا احنا انه ال weak nucleophile بقدرش يعمل ولا
+
+336
+00:29:43,890 --> 00:29:52,710
+شغلة بقعد يتفرج اش بستنىباستثناء ان الـ Cl تفقد مع
+
+337
+00:29:52,710 --> 00:29:59,910
+إلكتروناته ويتكون عنده كاربو كاتيون واضح؟ الآن هذا
+
+338
+00:29:59,910 --> 00:30:03,790
+الكاربو كاتيون هذا الكاربو كاتيون اللي اتكون عنده
+
+339
+00:30:03,790 --> 00:30:09,510
+ممكن يكمل التفاعل ل substitution وممكن يكمل
+
+340
+00:30:09,510 --> 00:30:13,370
+التفاعل ل elimination إذا إجى النيوكليوفايل هنا
+
+341
+00:30:13,370 --> 00:30:20,220
+وهاجم على الكاربونإذا جاء النيوكليوفايل وهاجم على
+
+342
+00:30:20,220 --> 00:30:24,940
+الكاربون، ماذا سيحصل عنده؟ يبدأ النيوكليوفايل
+
+343
+00:30:24,940 --> 00:30:29,880
+بإستخدام الـ SN1 طيب، هذا النيوكليوفايل بتطلع على
+
+344
+00:30:29,880 --> 00:30:34,970
+إيش؟ع الموجب وشاف ال carbon موجبة طيب و هذا ال
+
+345
+00:30:34,970 --> 00:30:38,830
+nucleophile ممكن كما نشوف هنا ال hydrogen كأنها
+
+346
+00:30:38,830 --> 00:30:44,090
+موجبة؟ ممكن اه و بالتالي ال nucleophile هذا لو اجا
+
+347
+00:30:44,090 --> 00:30:47,750
+و اصطدم بال hydrogen و أخد هشال .. هشال ال
+
+348
+00:30:47,750 --> 00:30:53,390
+hydrogen ايش بيترك لهنا؟هيترك لل bond هذه و بتقول
+
+349
+00:30:53,390 --> 00:30:56,870
+له فانا بتعمل double bond بيصير عند ال elimination
+
+350
+00:30:56,870 --> 00:31:05,230
+واضح؟ إذا بنقدر نستنتج أن ال SN1 و ال E1 حقيقة
+
+351
+00:31:05,230 --> 00:31:12,930
+عبارة عن تفاعل بخطوتين الخطوة الأولى منهم مشتركة
+
+352
+00:31:13,780 --> 00:31:21,500
+يعني both SN1 و E1 لديهم نفس الـ first step لو كنا
+
+353
+00:31:21,500 --> 00:31:27,380
+رسمين هدول هيك برسمة واحدة كأننا بيقول ال first
+
+354
+00:31:27,380 --> 00:31:33,780
+step minus CL minus فقدت ال CL هذه ال first step
+
+355
+00:31:33,780 --> 00:31:38,300
+مشتركة للتانتين بعد ما تفقد ال CL بيجي نيوكليو فيل
+
+356
+00:31:38,300 --> 00:31:39,880
+على ال positive بيعطيني
+
+357
+00:31:49,990 --> 00:31:57,450
+الخطوة الصعبة في هذا التفاعل هو
+
+358
+00:31:57,450 --> 00:32:05,460
+أن السالب يلتقى بالموجةأفصل هذا السالب عن الموجة
+
+359
+00:32:05,460 --> 00:32:06,160
+أفصل هذا السالب عن الموجة أفصل هذا السالب عن
+
+360
+00:32:06,160 --> 00:32:06,840
+الموجة أفصل هذا السالب عن الموجة أفصل هذا السالب
+
+361
+00:32:06,840 --> 00:32:08,960
+عن الموجة أفصل هذا السالب عن الموجة أفصل هذا
+
+362
+00:32:08,960 --> 00:32:10,700
+السالب عن الموجة أفصل هذا السالب عن الموجة أفصل
+
+363
+00:32:10,700 --> 00:32:13,040
+هذا السالب عن الموجة أفصل هذا السالب عن الموجة
+
+364
+00:32:13,040 --> 00:32:14,160
+أفصل هذا السالب عن الموجة أفصل هذا السالب عن
+
+365
+00:32:14,160 --> 00:32:14,960
+الموجة أفصل هذا السالب عن الموجة أفصل هذا السالب
+
+366
+00:32:14,960 --> 00:32:16,560
+عن الموجة أفصل هذا السالب عن الموجة أفصل هذا
+
+367
+00:32:16,560 --> 00:32:17,600
+السالب عن الموجة أفصل هذا السالب عن الموجة أفصل
+
+368
+00:32:17,600 --> 00:32:22,100
+هذا السالب عن الموجة أفصل هذا السالب عن الموجة
+
+369
+00:32:22,100 --> 00:32:28,720
+أفصل هذا السالب عن الموجة
+
+370
+00:32:32,740 --> 00:32:41,100
+في بينهم Carbocation و ال rate تبعتهم بتعتمد على
+
+371
+00:32:41,100 --> 00:32:48,860
+ايش لل A X هاي الخطوة كان بيبين ال nucleophile في
+
+372
+00:32:48,860 --> 00:32:55,860
+الخطوة الأولى ليش مش بيبين لأنه ضعيف لأنه ضعيف لأن
+
+373
+00:32:55,860 --> 00:32:59,320
+ال nucleophile ضعيف ضال يستنى لحد ما تطلع ال CL
+
+374
+00:32:59,320 --> 00:33:00,380
+لواحدة
+
+375
+00:33:06,730 --> 00:33:12,350
+اللي بدفع ال CL تطلع عوامل متعلقة بكل التفاعل لإنه
+
+376
+00:33:12,350 --> 00:33:16,050
+في النهاية لما يكتمل التفاعل بيكون من ناحية energy
+
+377
+00:33:16,050 --> 00:33:21,270
+أفضل، واضح؟ يعني خلّيني أقول القاتي، الكلام اللي
+
+378
+00:33:21,270 --> 00:33:25,370
+بتحكي زملتكوا شوية كلام منطقي إنه يا تورا لو ما
+
+379
+00:33:25,370 --> 00:33:30,090
+حطيناش ال nucleophile لو ما حطيناش ال nucleophile
+
+380
+00:33:30,090 --> 00:33:35,970
+هل ال CL بده تطلع و يجف زي هيك و يقعد يطلع؟لأ، هذه
+
+381
+00:33:35,970 --> 00:33:42,170
+عملية متكاملة بمعنى إنه الـ CL لما بتطلع و بتعمل
+
+382
+00:33:42,170 --> 00:33:45,610
+positive بعدك ال nucleophile .. ال nucleophile لما
+
+383
+00:33:45,610 --> 00:33:50,270
+بده يهاجم على ال positive اتذكر عندي عاملين أنا ..
+
+384
+00:33:50,270 --> 00:33:54,050
+هنا عندي bond breaking .. ال bond breaking شو بده؟
+
+385
+00:33:54,050 --> 00:34:01,860
+بده طاقة .. هذه سؤالك طب و هنا bond formationسواء
+
+386
+00:34:01,860 --> 00:34:05,600
+مع الـ positive أو مع الـ H و ال bond formation
+
+387
+00:34:05,600 --> 00:34:10,800
+بيطلع طاقة وبناء على ذلك هذا التفاعل بيصير الآن لو
+
+388
+00:34:10,800 --> 00:34:15,420
+في مكان ما كانت حسابات الطاقة مش سليمة مايمشيش
+
+389
+00:34:15,420 --> 00:34:19,680
+التفاعل يعني ممكن كتير we can eucleophiles تكون
+
+390
+00:34:19,680 --> 00:34:25,300
+بالمجمل من ناحية الطاقة غير إيجابية و نخلطها و
+
+391
+00:34:25,300 --> 00:34:29,140
+مايمشيش التفاعلواضح؟ التفاعل وقته ايش بيمشي؟ لما
+
+392
+00:34:29,140 --> 00:34:34,200
+يكون من ناحية الطاقة، معقول تعرفوا مرة عليكم أن
+
+393
+00:34:34,200 --> 00:34:40,320
+التفاعل بتحكمه شغلتين أساسيتين، شو هما؟ أنه يكون
+
+394
+00:34:40,320 --> 00:34:45,860
+عندي فاقة طاقة، اتقل الطاقة، هذا عامل ال stability
+
+395
+00:34:45,860 --> 00:34:53,880
+و العامل التاني إيش يكون عنده؟ زيادة فوضة increase
+
+396
+00:34:53,880 --> 00:34:59,740
+in the entropyمتذكرين كان عندكم عشان يمشي التفاعل
+
+397
+00:34:59,740 --> 00:35:03,280
+أخدته معادلة من أهم معادلة الكيميا على الإطلاق
+
+398
+00:35:03,280 --> 00:35:11,410
+Delta G بتساوي Delta H minus D Delta Sو لازم delta
+
+399
+00:35:11,410 --> 00:35:16,870
+J تكون negative عشان تكون negative و يمشي التفاعل
+
+400
+00:35:16,870 --> 00:35:20,770
+أفضل شئ بتكون مع delta H تكون minus بمعنى أن
+
+401
+00:35:20,770 --> 00:35:24,710
+التفاعل يطرد حرارة و أن ال delta S تكون positive
+
+402
+00:35:24,710 --> 00:35:31,150
+أن التفاعل يزيد الفوضى أفضل تفاعل على الإطلاق هو
+
+403
+00:35:31,150 --> 00:35:37,950
+الذي يطرد طاقة و يزيدالفوضى بيعطي جزيئات كتير،
+
+404
+00:35:37,950 --> 00:35:43,150
+واضح؟ اعرفته ليش اليهود بدمروا على الناس دورهم و
+
+405
+00:35:43,150 --> 00:35:48,960
+سياراتهم و ما إلى ذلك؟لأن تفاعل انفجار هو أفضل
+
+406
+00:35:48,960 --> 00:35:53,920
+تفاعل على الإطلاق، مجنون، تفاعل مجنون، بيفقد طاقة
+
+407
+00:35:53,920 --> 00:35:59,560
+كتير، و بطلع جزيئات كتير صغيرة و بعمل فوضى، و عشان
+
+408
+00:35:59,560 --> 00:36:02,640
+هيك ممشي بشكل ممتاز، بتشوفوا كيف الدنيا كلها
+
+409
+00:36:02,640 --> 00:36:06,780
+بتطير، و المادة المتفجرة بتصير غازات، هي المادة
+
+410
+00:36:06,780 --> 00:36:10,820
+المتفجرة بتكون عبارة عن جزيئات، خلّيني أتخيلك
+
+411
+00:36:10,820 --> 00:36:13,940
+صغيرة و كلها مربوطة مع بعض، ما بتصدق إنها بدها
+
+412
+00:36:13,940 --> 00:36:19,310
+إيش؟بدأت تتحرر وتفلت وبعد تحرورها وفلتانها كمان
+
+413
+00:36:19,310 --> 00:36:24,530
+بتطلع طاقة كتير وعشان هي هذا التفاعل بتلاقيه أسهل
+
+414
+00:36:24,530 --> 00:36:28,770
+منه هل الواحد بيولع بابور تحت المادة المتفجرة ولا
+
+415
+00:36:28,770 --> 00:36:34,340
+لحالها؟لحالها بتشيل، ليش؟ لأن فيها الشرطين أنه
+
+416
+00:36:34,340 --> 00:36:41,000
+تفقد طاقة وتزيد الفوضى وهذه أهم معادلة بتحكم سير
+
+417
+00:36:41,000 --> 00:36:44,740
+التفاعلات المفروض أنه أخدتوها ولو كثقافة عامة
+
+418
+00:36:44,740 --> 00:36:48,780
+بكيميا B الـ Delta J لازم تكون negative Delta J
+
+419
+00:36:48,780 --> 00:36:54,400
+Delta H minus T Delta S فاللي بيحكم أنه ليش يكتمل
+
+420
+00:36:54,400 --> 00:36:59,040
+التفاعل ويصيروا حسابات متعلقة بأمرين دائما، إيش
+
+421
+00:36:59,040 --> 00:37:05,580
+هما الأمرين؟الطاقة والانترو بيه اللي معبّر عنهم في
+
+422
+00:37:05,580 --> 00:37:12,040
+المعادلة Delta H و Delta S فما تنسوهوش Delta H و
+
+423
+00:37:12,040 --> 00:37:17,500
+Delta S طبعا أكيد ان انتوا لاحظتوا هنا انه نوعا ما
+
+424
+00:37:17,500 --> 00:37:22,920
+في موازاة حتى لما تدرسوا لازم تكون بالكوا ما بين
+
+425
+00:37:22,920 --> 00:37:28,440
+ال SN1 و ال E1 و ال SN2 و ال E2 في بعض ال aspects
+
+426
+00:37:31,190 --> 00:37:37,130
+حتى نختتم هذا الفصل، بس بيظل عندنا slide أو تنتين
+
+427
+00:37:37,130 --> 00:37:41,550
+معلومات ثقافية عامة، أن الـ Alkaliites هدولة اللي
+
+428
+00:37:41,550 --> 00:37:46,390
+احنا درسنا تفاعلاتهم، فيلهم في واقع الحياة العملية
+
+429
+00:37:46,390 --> 00:37:52,790
+كثير من التطبيقات، بنعرض بعض هناحتى تظهروا أن
+
+430
+00:37:52,790 --> 00:37:56,430
+الكيميا هي جزء من الحياة في مراكبات بيسموها
+
+431
+00:37:56,430 --> 00:37:59,710
+polyhalogenated aliphatic compounds يعني
+
+432
+00:37:59,710 --> 00:38:04,810
+الهالوجنات المتصلة بهالوجن و أحيانا بأكثر من
+
+433
+00:38:04,810 --> 00:38:11,130
+هالوجن من المراكبات اللي استعملها كتير في التطبيق
+
+434
+00:38:11,390 --> 00:38:17,910
+الـ CH3Br الميثيلبروميد هذا الميثيلبروميد الناس
+
+435
+00:38:17,910 --> 00:38:22,530
+الذين .. الزراعيين منكم يعني الأخوات اللي في
+
+436
+00:38:22,530 --> 00:38:26,970
+الجرارة و في بيت لاهيا و ما إلى ذلك بيعرفوا شغلة
+
+437
+00:38:26,970 --> 00:38:34,750
+أن الفلاحين لما بيجهزوا الأرض للزراعة إيش بيرشوها؟
+
+438
+00:38:34,750 --> 00:38:39,700
+بيرشوها غازبيجلبوا الأرض و بيرشوها غاز .. هذا
+
+439
+00:38:39,700 --> 00:38:43,620
+الغاز مثل البروميد .. بيقتل كل الحشرات اللي موجودة
+
+440
+00:38:43,620 --> 00:38:47,200
+في التربة .. قبل ما يزرعها .. قبل ما يزرعها ..
+
+441
+00:38:47,200 --> 00:38:52,100
+بيرشها غاز .. وهذا الغاز بالمناسبة مكلفيعني من
+
+442
+00:38:52,100 --> 00:38:56,540
+فترة صغيرة يعني أحد الفلاحين بيقول ان هو عشان رشده
+
+443
+00:38:56,540 --> 00:39:02,400
+المين دفع حاجة غاز سبعتلاف شكل عشان قبل ما يزرع
+
+444
+00:39:02,400 --> 00:39:08,600
+الفراولة انظف من كل إيش من كل الحشرات الآن حتى
+
+445
+00:39:08,600 --> 00:39:13,120
+نزيدكوا تخاف هذا الغاز له أضرار سلبية كتير وبدأ
+
+446
+00:39:13,120 --> 00:39:19,960
+العالم يسعى نحو منعه بدوا يعملوا مؤتمراتلمنعه ومن
+
+447
+00:39:19,960 --> 00:39:24,940
+أكثر المعارضين لمنعه الولايات المتحدة الأمريكية
+
+448
+00:39:24,940 --> 00:39:28,900
+اللي أنا بدها محصول هي من أكثر المعارضين تطالب
+
+449
+00:39:28,900 --> 00:39:33,900
+العالم أن يمنعه وتطالب بمنحها فترة إضافية أكتر حتى
+
+450
+00:39:33,900 --> 00:39:39,040
+هي تمنعهواضح؟ فيه إله كثير أضرار مثل ال bromide
+
+451
+00:39:39,040 --> 00:39:44,180
+اللي هو ال fumigant أو ال بيقتل الحشرات و الأشياء
+
+452
+00:39:44,180 --> 00:39:47,740
+اللي بتكون في إيش .. في التربة و الفلاحين عندنا
+
+453
+00:39:47,740 --> 00:39:52,300
+بشكل standard بستعملوه يعني قبل كل زرعة فراولة
+
+454
+00:39:52,300 --> 00:39:59,270
+لازم يرشوا التربة كلها غاز و هذا مكلفالـ CH2Cl2
+
+455
+00:39:59,270 --> 00:40:02,730
+اللي هو دايكلوروميثين والـ CHCl3 اللي هو
+
+456
+00:40:02,730 --> 00:40:06,950
+الكلوروفورم هدول عبارة عن organic solvents بنجر
+
+457
+00:40:06,950 --> 00:40:13,950
+فيهم التفاعل الـ CF2CF2 to the N هو عبارة عن ال
+
+458
+00:40:13,950 --> 00:40:18,050
+polymer اللي اسمه التفلون مار عليكم التفلون؟
+
+459
+00:40:19,150 --> 00:40:23,730
+Polymer بلاستيكي يمكن اليوم أكتر إشي بيستعملوه
+
+460
+00:40:23,730 --> 00:40:27,310
+دايما بتقولوا بدنا نشتري تفلون لما بيركبوا
+
+461
+00:40:27,310 --> 00:40:32,330
+المواثير ببعض بتشوفوا هذا الأبيض اللفة الصغيرة
+
+462
+00:40:32,330 --> 00:40:35,010
+البيضة اللي بلفوها حوالين المواثير بدل ما كانوا
+
+463
+00:40:35,010 --> 00:40:41,430
+زمان يستعملوهالشعر أو الخطان هذا اسمه إيش؟ تفلون
+
+464
+00:40:41,430 --> 00:40:45,530
+وموجود منه أنواع كتيرة من ال plastic بمواصفات
+
+465
+00:40:45,530 --> 00:40:49,890
+معينة برضه عبارة عن .. من مركبات ال .. ال
+
+466
+00:40:49,890 --> 00:40:53,650
+alcoholites ال chlorofluorocarbons اللي هم
+
+467
+00:40:53,650 --> 00:40:57,690
+المركبات ال .. ال carbons اللي فيهم chlor و fluor
+
+468
+00:40:57,690 --> 00:41:02,430
+هدولة بختصرهم ب CFC و هذه كلمة كتير بسمعوها في
+
+469
+00:41:02,430 --> 00:41:07,620
+البيئة و دايما بحكوا عنهاالـ Chlorofluorocarbons
+
+470
+00:41:07,620 --> 00:41:13,320
+هذه من أمثلتها غاز لـ Freon-12 هذا Freon-12 اللي
+
+471
+00:41:13,320 --> 00:41:16,820
+هو الغاز اللي بيستعملوه في التبريد في داخل
+
+472
+00:41:16,820 --> 00:41:20,840
+التلاجات نفسه كانوا يحطوه في علاب ال spray عشان
+
+473
+00:41:20,840 --> 00:41:24,340
+تعمل ال spraying جيد علاب العطر و ما إلى ذلك و
+
+474
+00:41:24,340 --> 00:41:28,800
+البوية عشان تعمل ال spraying بيحطوها هي بالنسبة
+
+475
+00:41:28,800 --> 00:41:34,540
+لوضع الأرض inert gases لكن وين مشكلتها؟فى السماء
+
+476
+00:41:34,540 --> 00:41:38,940
+مش فى الأرض مشكلتها لما بتطلع على السماء فى
+
+477
+00:41:38,940 --> 00:41:44,020
+الطبقات العليا مع ال UV light بتكسر من خلال
+
+478
+00:41:44,020 --> 00:41:49,300
+تفاعلات معينة طبقة الأوزون ولذلك الآن بيتكلموا عن
+
+479
+00:41:49,300 --> 00:41:54,140
+الثقوب فى طبقة الأوزونبمر عليكم الثقوب في طبقة
+
+480
+00:41:54,140 --> 00:41:58,600
+الأوزون الآن الثقوب في طبقة الأوزون العلماء
+
+481
+00:41:58,600 --> 00:42:00,640
+بيرجحوا أن هو بشكل أساسي جاي من ال
+
+482
+00:42:00,640 --> 00:42:06,000
+chlorofluorocarbons ولذلك اليوم صناعيا التلاجات
+
+483
+00:42:06,000 --> 00:42:11,500
+بيحاولوا يعملوها بنظم غير غاز لفريون ال spraying
+
+484
+00:42:11,500 --> 00:42:18,280
+بيحاولوا يقللوه يعني بأذكر مرة يمكن قبل ما تموت
+
+485
+00:42:18,280 --> 00:42:24,910
+الأميرة دياناالـ Lady Diana جابوها بتجيب إجزازة
+
+486
+00:42:24,910 --> 00:42:28,410
+ريحة و بتكوب على إيدها كاب بدل ما تعمل ال spraying
+
+487
+00:42:28,410 --> 00:42:34,270
+حتى يقولوا للعالم إن ال spraying هذا بيطلع أشياء
+
+488
+00:42:34,270 --> 00:42:38,870
+بتضر بالبيئة أو بتضر بطبقة الأوزون يعني ممكن الناس
+
+489
+00:42:38,870 --> 00:42:42,930
+يستعملوا ريحة عادي هيك يحطوه على إيدهم أفضل من أن
+
+490
+00:42:42,930 --> 00:42:46,890
+كل البشر قاعدين يعملوا spraying و ال spraying هذا
+
+491
+00:42:46,890 --> 00:42:54,120
+إيش بيعمل؟بيعمل تدمير لطبقة الأوزون طبعا انكمل
+
+492
+00:42:54,120 --> 00:42:59,240
+تدمير طبقة الأوزون ايش بيزيد عندنا؟ بيزيد الاحتباس
+
+493
+00:42:59,240 --> 00:43:02,140
+الحراري طب ايش مشكلة الاحتباس الحراري الأساسية
+
+494
+00:43:02,140 --> 00:43:09,140
+علينا؟ ايش بيتبع زيادة درجات الحرارة؟ و ايش بيتبع
+
+495
+00:43:09,140 --> 00:43:12,640
+دوبان الجليد؟
+
+496
+00:43:13,820 --> 00:43:20,060
+غرق كثير من المدن مدن أساسية في العالم اللي راح
+
+497
+00:43:20,060 --> 00:43:24,000
+على أوروبا وما إلى ذلك سيعرف أن دول كاملة ممكن
+
+498
+00:43:24,000 --> 00:43:33,080
+تغرق واضح؟ طبعا ليش بدها تغرق؟ الموضوع بسيط جدا لو
+
+499
+00:43:33,080 --> 00:43:37,000
+أنتوا تخيلتوا أن هنا عندكم جبل من الجليد وهذا في
+
+500
+00:43:37,000 --> 00:43:41,540
+المناطق القطبية وثابت ثابت جبل الجليد مافيش عليه
+
+501
+00:43:41,540 --> 00:43:47,040
+أي مشكلةو أنا عندكم بهذا الشكل نوعا ما سهل و أنا
+
+502
+00:43:47,040 --> 00:43:52,880
+في مدينة زي أمستردام والناس عايشين والجليد هذا
+
+503
+00:43:52,880 --> 00:43:56,820
+معلق على الجبل عمره ما بنزل متجمد الآن لو أنا رفعت
+
+504
+00:43:56,820 --> 00:44:04,040
+الحرارة مجرد ما صار مية مش انهيار مش انهيار ايش
+
+505
+00:44:04,040 --> 00:44:04,740
+الكلمة؟
+
+506
+00:44:07,250 --> 00:44:12,010
+انصهار كثير ناس متعودين يقولوا ذوبان الجليد
+
+507
+00:44:12,010 --> 00:44:16,490
+الذوبان مادة في مادة الجليد دايما استعملوله انصهار
+
+508
+00:44:16,490 --> 00:44:23,190
+واضح انصهار مش ذوبان لما يصير مياه شو هيعمل في متل
+
+509
+00:44:23,190 --> 00:44:27,310
+هذه المدن؟ هيغرقها هذا المشكلة ان الجليد هو صلب
+
+510
+00:44:27,310 --> 00:44:32,270
+يبقى على رأس الجبلبيضلوا على رأس الجبل مافيش عندكم
+
+511
+00:44:32,270 --> 00:44:35,310
+اي مشكلة هذه تجربة روحوا اعملوها في البيت عندكم
+
+512
+00:44:35,310 --> 00:44:39,850
+هاتوا جوالب تلج كبيرة اعملوها و حطوها جانب حوض
+
+513
+00:44:39,850 --> 00:44:44,070
+المغسلة و الحوض ناشف مافيش فيه ولا شغلة طولها من
+
+514
+00:44:44,070 --> 00:44:48,890
+الجامدة بتضلها عاملة زي الجبل و ثابتة مكانها
+
+515
+00:44:48,890 --> 00:44:56,510
+ارتفعت الحرارة شوية صارت ميهإيه بتنزل؟ بتغرق
+
+516
+00:44:56,510 --> 00:45:01,110
+الحوت، مظبوط ولا لأ؟ وهذه اللي هي الإشكالية أنه في
+
+517
+00:45:01,110 --> 00:45:04,870
+دول كاملة منخفضة، هولندا شو بيسموها؟ Netherlands،
+
+518
+00:45:04,870 --> 00:45:11,430
+الأرض المنخفضة، فدول كاملة ممكن تغرق لو هذه الشغلة
+
+519
+00:45:11,430 --> 00:45:17,900
+بتزيد، دول كاملة ممكن تغرق لو هذه الشغلة بتزيدأخر
+
+520
+00:45:17,900 --> 00:45:24,040
+شغلة في عندكم من المركبات اللي فيها halogens يعني
+
+521
+00:45:24,040 --> 00:45:28,100
+كربون و معبروم و chlorofluor أشياء كتيرة بيسموها
+
+522
+00:45:28,100 --> 00:45:33,280
+ال halons ال halons هذه عبارة عن bromine
+
+523
+00:45:33,280 --> 00:45:36,980
+containing chlorofluorocarbons they are called
+
+524
+00:45:36,980 --> 00:45:41,520
+halons and are used to extinguish fire بيستعملهم
+
+525
+00:45:41,520 --> 00:45:45,460
+في الطفايات بتعرفوا طفاية ال halon الطفايات اللي
+
+526
+00:45:45,460 --> 00:45:50,510
+بتكون عليهاالإشارة الخضراء وغالبا هذه طفيات
+
+527
+00:45:50,510 --> 00:45:55,170
+الهالونز لأن هؤلاء غازات خاملة لما يكون عنده مورشة
+
+528
+00:45:55,170 --> 00:45:59,530
+بصلح أجهزة كهربائية ما إلى ذلك لو صار عنده حريقة
+
+529
+00:45:59,530 --> 00:46:04,390
+لا يفضل أنه يجيب مية و يطف يعني لو افترضنا واحد
+
+530
+00:46:04,390 --> 00:46:07,570
+بيصلح تلفزيون كبير و ما إلى ذلك متوقع يصير عنده
+
+531
+00:46:07,570 --> 00:46:12,650
+حريقةبيحط جنبه طفاية ميه لو حط طفاية ميه و كبها
+
+532
+00:46:12,650 --> 00:46:18,110
+الميه على الجهاز مع الكهربا اللي موجودة و حتى لو
+
+533
+00:46:18,110 --> 00:46:21,190
+مافيش كهربا بتخرب كل مكونات الجهاز لكن هو بتجيب
+
+534
+00:46:21,190 --> 00:46:26,790
+طفاية الغاز ال halon بعص بتعمل منع لل أكسوجين عن
+
+535
+00:46:26,790 --> 00:46:32,050
+النار بتطفيها بعد هيك كله بيروحما خربش الجهاز عنده
+
+536
+00:46:32,050 --> 00:46:35,990
+فهذه الطفيات طفيات ال halons ويلها أرقام بيعرفوها
+
+537
+00:46:35,990 --> 00:46:40,130
+تعون الاطفايات لإطفاء الحرائق بالذات المتعلقة
+
+538
+00:46:40,130 --> 00:46:46,790
+بالأجهزة الكهربائية بهيك تقريبا بنأمل أن أعطيناكوا
+
+539
+00:46:46,790 --> 00:46:50,190
+فكرة عن ال alkyl halides وإن شاء الله الحصة
+
+540
+00:46:50,190 --> 00:46:53,650
+القادمة بنبدأ في موضوع جديد
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..79c0045e095e5a91dff5c4ad233214aa20bbc9c5
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_raw.json
@@ -0,0 +1 @@
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56.28, "word": " الكلهيليتز", "probability": 0.8501790364583334}, {"start": 56.28, "end": 57.26, "word": " يعطوننا", "probability": 0.815234375}, {"start": 57.26, "end": 58.02, "word": " ال", "probability": 0.94140625}, {"start": 58.02, "end": 58.5, "word": " keys", "probability": 0.8896484375}, {"start": 58.5, "end": 60.06, "word": " هل", "probability": 0.6748046875}, {"start": 60.06, "end": 60.36, "word": " لازم", "probability": 0.9249674479166666}, {"start": 60.36, "end": 60.82, "word": " تلاحظوا", "probability": 0.96416015625}, {"start": 60.82, "end": 61.36, "word": " نقطة", "probability": 0.9676106770833334}, {"start": 61.36, "end": 61.64, "word": " ان", "probability": 0.77685546875}, {"start": 61.64, "end": 62.12, "word": " هدول", "probability": 0.7919921875}, {"start": 62.12, "end": 63.56, "word": " التفاعلين", "probability": 0.788818359375}], "temperature": 1.0}, {"id": 3, "seek": 8262, "start": 64.22, "end": 82.62, "text": "تفاعلين خلّينا نقول تنافسيين يعني ممكن التنين يحصلوا ولو بنسب متفاوتة في نفس الوقت يعني بيطلع عند ناتج هو عبارة عن خليط من تفاعل إبدال وتفاعل", "tokens": [2655, 5172, 995, 30241, 9957, 16490, 1211, 11703, 9957, 995, 8717, 39648, 6055, 8315, 36178, 1829, 9957, 37495, 22653, 3714, 43020, 16712, 1863, 9957, 7251, 5016, 36520, 14407, 35525, 2407, 44945, 35457, 44650, 5172, 995, 35473, 3660, 8978, 8717, 36178, 2423, 30543, 2655, 37495, 22653, 4724, 1829, 9566, 1211, 3615, 43242, 8717, 9307, 7435, 31439, 6225, 3555, 9640, 3660, 18871, 16490, 20292, 9566, 9154, 6055, 5172, 995, 30241, 11933, 3555, 28259, 1211, 34683, 5172, 995, 30241], "avg_logprob": -0.1532061727016003, "compression_ratio": 1.7133333333333334, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 64.22, "end": 65.3, "word": "تفاعلين", "probability": 0.94482421875}, {"start": 65.3, "end": 65.88, "word": " خلّينا", "probability": 0.61162109375}, {"start": 65.88, "end": 66.18, "word": " نقول", "probability": 0.9892578125}, {"start": 66.18, "end": 67.34, "word": " 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{"start": 75.74, "end": 76.02, "word": " عند", "probability": 0.93603515625}, {"start": 76.02, "end": 76.7, "word": " ناتج", "probability": 0.8636067708333334}, {"start": 76.7, "end": 76.94, "word": " هو", "probability": 0.79638671875}, {"start": 76.94, "end": 77.44, "word": " عبارة", "probability": 0.9957275390625}, {"start": 77.44, "end": 77.72, "word": " عن", "probability": 0.99658203125}, {"start": 77.72, "end": 78.52, "word": " خليط", "probability": 0.90966796875}, {"start": 78.52, "end": 78.94, "word": " من", "probability": 0.990234375}, {"start": 78.94, "end": 79.88, "word": " تفاعل", "probability": 0.9630126953125}, {"start": 79.88, "end": 81.52, "word": " إبدال", "probability": 0.700439453125}, {"start": 81.52, "end": 82.62, "word": " وتفاعل", "probability": 0.87255859375}], "temperature": 1.0}, {"id": 4, "seek": 9922, "start": 83.26, "end": 99.22, "text": "حذف يعني لو مثلا أخدت هذا المُركّب اللي هو two bromopropane أو isopropyl bromide اللي مار علينا و قولت بدي أفعله مع ال N 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"start": 127.81, "end": 152.15, "text": "هو اللي حيلفه يعمل ال double bond واضح فبصير عملية حدث HPR كأن بظبط بقول H plus PR minus لكن هو بيطلعش ايونيك موليكيول موليكيول بيطلع موليكيولار موليكيول يعني ال HPR مش جزء ايوني مابنقدرش نقول ان صيغته الكيميائية H plus PR minus اللي هو جزء equivalent", "tokens": [3224, 2407, 13672, 1829, 11331, 26895, 5172, 3224, 7251, 25957, 1211, 2423, 3834, 6086, 4032, 46958, 5016, 6156, 3555, 9381, 13546, 6225, 42213, 10632, 11331, 3215, 12984, 389, 15958, 9122, 33456, 4724, 19913, 3555, 9566, 4724, 39648, 389, 1804, 11568, 3175, 44381, 31439, 4724, 1829, 9566, 1211, 3615, 8592, 1975, 1829, 11536, 1829, 4117, 3714, 12610, 1829, 4117, 1829, 12610, 3714, 12610, 1829, 4117, 1829, 12610, 4724, 1829, 9566, 1211, 3615, 3714, 12610, 1829, 4117, 1829, 12610, 9640, 3714, 12610, 1829, 4117, 1829, 12610, 37495, 22653, 2423, 389, 15958, 37893, 10874, 11622, 38207, 1975, 1829, 11536, 1829, 3714, 16758, 1863, 28543, 2288, 8592, 8717, 39648, 16472, 20328, 1829, 17082, 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عملية", "probability": 0.9677734375}, {"start": 132.05, "end": 132.49, "word": " حدث", "probability": 0.9459635416666666}, {"start": 132.49, "end": 134.23, "word": " HPR", "probability": 0.41156005859375}, {"start": 134.23, "end": 134.91, "word": " كأن", "probability": 0.878173828125}, {"start": 134.91, "end": 135.39, "word": " بظبط", "probability": 0.7242431640625}, {"start": 135.39, "end": 135.69, "word": " بقول", "probability": 0.92431640625}, {"start": 135.69, "end": 135.99, "word": " H", "probability": 0.849609375}, {"start": 135.99, "end": 136.69, "word": " plus", "probability": 0.325439453125}, {"start": 136.69, "end": 137.77, "word": " PR", "probability": 0.72216796875}, {"start": 137.77, "end": 138.17, "word": " minus", "probability": 0.9267578125}, {"start": 138.17, "end": 138.43, "word": " لكن", "probability": 0.8173828125}, {"start": 138.43, "end": 138.59, "word": " هو", "probability": 0.619140625}, {"start": 138.59, "end": 139.23, "word": " بيطلعش", "probability": 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0.908935546875}, {"start": 146.67, "end": 147.35, "word": " مابنقدرش", "probability": 0.8891194661458334}, {"start": 147.35, "end": 147.61, "word": " نقول", "probability": 0.970458984375}, {"start": 147.61, "end": 147.79, "word": " ان", "probability": 0.7548828125}, {"start": 147.79, "end": 148.23, "word": " صيغته", "probability": 0.8636474609375}, {"start": 148.23, "end": 148.81, "word": " الكيميائية", "probability": 0.84375}, {"start": 148.81, "end": 149.03, "word": " H", "probability": 0.90283203125}, {"start": 149.03, "end": 149.43, "word": " plus", "probability": 0.8125}, {"start": 149.43, "end": 149.73, "word": " PR", "probability": 0.9404296875}, {"start": 149.73, "end": 150.27, "word": " minus", "probability": 0.99072265625}, {"start": 150.27, "end": 150.69, "word": " اللي", "probability": 0.86181640625}, {"start": 150.69, "end": 150.85, "word": " هو", "probability": 0.98583984375}, {"start": 150.85, "end": 151.47, "word": " جزء", "probability": 0.9892578125}, {"start": 151.47, "end": 152.15, "word": " equivalent", "probability": 0.2149658203125}], "temperature": 1.0}, {"id": 7, "seek": 17063, "start": 153.09, "end": 170.63, "text": "بند موليكيولار موليكيول واضح الان لما بيحظف ال HPR بيصير عنده elimination طبعا هذا الكلام هيعمل عندكم مشكلة نوعا ما انه لو انا بدي اجي اسألكم ايش النتج اللي بدكوا تحطوه واضح؟", "tokens": [3555, 41260, 3714, 12610, 1829, 4117, 1829, 12610, 9640, 3714, 12610, 1829, 4117, 1829, 12610, 4032, 46958, 5016, 2423, 7649, 5296, 15042, 4724, 1829, 5016, 19913, 5172, 2423, 12557, 49, 4724, 1829, 9381, 13546, 43242, 3224, 29224, 23032, 3555, 3615, 995, 23758, 2423, 28820, 10943, 39896, 25957, 1211, 43242, 24793, 37893, 28820, 3660, 8717, 45367, 995, 19446, 16472, 3224, 45164, 1975, 8315, 4724, 16254, 1975, 7435, 1829, 24525, 10721, 23275, 2304, 1975, 1829, 8592, 2423, 29399, 7435, 13672, 1829, 47525, 4117, 14407, 6055, 5016, 9566, 2407, 3224, 4032, 46958, 5016, 22807], "avg_logprob": -0.2557744468035905, "compression_ratio": 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{"start": 1054.24, "end": 1054.4, "word": " R", "probability": 0.705078125}, {"start": 1054.4, "end": 1054.64, "word": " ايش", "probability": 0.6888834635416666}, {"start": 1054.64, "end": 1056.26, "word": " مالها؟", "probability": 0.86962890625}, {"start": 1056.26, "end": 1056.82, "word": " كبيرة", "probability": 0.9729817708333334}, {"start": 1056.82, "end": 1057.54, "word": " وهنا", "probability": 0.6290283203125}, {"start": 1057.54, "end": 1057.76, "word": " في", "probability": 0.92724609375}, {"start": 1057.76, "end": 1058.22, "word": " عندى", "probability": 0.83056640625}, {"start": 1058.22, "end": 1058.56, "word": " R", "probability": 0.966796875}], "temperature": 1.0}, {"id": 47, "seek": 108017, "start": 1058.85, "end": 1080.17, "text": "الـ R كبيرة وهي الـ tertiary وهنا فيه positive مخبّى في قلبهم وهنا فيه positive على الطرف أنه أسهل الـ OH minus تيجي على هذا ال positive فيه لو أسع تصل ال positive لل carbon عشانك مابيصيرش إبدال ملاحظين انتوا؟", "tokens": [6027, 39184, 497, 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انتوا؟", "probability": 0.75311279296875}], "temperature": 1.0}, {"id": 48, "seek": 110418, "start": 1080.84, "end": 1104.18, "text": "مع الـ tertiary الـ OH- ما عندهاش وسع تصل للكربون هذه الموجة بل الكربون مدفون مدفونة لما تتخيل ان هذا الكربون مثلا CH3 CHHH و هنا CH3 CHHH كله محوط قادرة تصل ال positive المخفي اللي هنا", "tokens": [2304, 3615, 2423, 39184, 38726, 29104, 2423, 39184, 13931, 12, 19446, 43242, 3224, 33599, 4032, 3794, 3615, 6055, 36520, 5296, 23275, 25513, 11536, 29538, 9673, 29245, 3660, 4724, 1211, 33251, 25513, 11536, 3714, 3215, 5172, 11536, 3714, 3215, 5172, 11536, 3660, 5296, 15042, 6055, 2655, 9778, 26895, 16472, 23758, 33251, 25513, 11536, 50113, 15040, 5995, 18, 5995, 7499, 4032, 34105, 5995, 18, 5995, 7499, 28242, 3224, 3714, 5016, 2407, 9566, 12174, 18513, 25720, 6055, 36520, 2423, 3353, 9673, 9778, 41185, 13672, 1829, 34105], "avg_logprob": -0.3286830254253887, "compression_ratio": 1.6358695652173914, "no_speech_prob": 0.0, "words": [{"start": 1080.84, "end": 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"end": 1086.9, "word": " الموجة", "probability": 0.8473307291666666}, {"start": 1086.9, "end": 1087.0, "word": " بل", "probability": 0.82373046875}, {"start": 1087.0, "end": 1087.52, "word": " الكربون", "probability": 0.8806966145833334}, {"start": 1087.52, "end": 1089.34, "word": " مدفون", "probability": 0.6307373046875}, {"start": 1089.34, "end": 1089.6, "word": " مدفونة", "probability": 0.6438232421875}, {"start": 1089.6, "end": 1090.9, "word": " لما", "probability": 0.8291015625}, {"start": 1090.9, "end": 1091.36, "word": " تتخيل", "probability": 0.986328125}, {"start": 1091.36, "end": 1091.5, "word": " ان", "probability": 0.38427734375}, {"start": 1091.5, "end": 1091.78, "word": " هذا", "probability": 0.7236328125}, {"start": 1091.78, "end": 1092.26, "word": " الكربون", "probability": 0.97021484375}, {"start": 1092.26, "end": 1092.62, "word": " مثلا", "probability": 0.88427734375}, {"start": 1092.62, "end": 1093.26, "word": " CH3", "probability": 0.88818359375}, {"start": 1093.26, 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هذه الكربون هذه الكربون اللي هنا في عندها احتمال هنا", "tokens": [2407, 10721, 8315, 4724, 16254, 5551, 25957, 1211, 6055, 5172, 995, 30241, 20449, 2423, 39184, 13931, 12, 3714, 31747, 11622, 36145, 3224, 5551, 8592, 38688, 8717, 9307, 7435, 2423, 29224, 11933, 5016, 8315, 12174, 1211, 8315, 5551, 4117, 25708, 4724, 11622, 10943, 44945, 5016, 4117, 1829, 18871, 29224, 47525, 3224, 6055, 9566, 1211, 3615, 2423, 11568, 20449, 11933, 23275, 2655, 2288, 11536, 9307, 11296, 13931, 15844, 9122, 25513, 11536, 3660, 3714, 7435, 995, 13063, 3660, 11778, 16373, 15042, 2423, 389, 9154, 4032, 9957, 39894, 9566, 1211, 3615, 22807, 37893, 9154, 8717, 36178, 33251, 25513, 11536, 9154, 33251, 25513, 11536, 3660, 9673, 7435, 995, 13063, 3660, 6225, 8592, 7649, 6055, 25957, 1211, 3834, 6086, 6024, 48506, 34105, 44945, 15040, 5016, 19913, 18871, 16254, 1975, 33753, 2304, 6027, 11933, 1829, 3224, 22807, 36145, 3224, 29538, 33251, 25513, 11536, 29538, 33251, 25513, 11536, 13672, 1829, 34105, 8978, 43242, 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تعمل", "probability": 0.9563802083333334}, {"start": 1343.07, "end": 1343.31, "word": " double", "probability": 0.60205078125}, {"start": 1343.31, "end": 1343.67, "word": " bond", "probability": 0.95751953125}, {"start": 1343.67, "end": 1344.25, "word": " الآن", "probability": 0.72314453125}, {"start": 1344.25, "end": 1344.41, "word": " هنا", "probability": 0.74462890625}, {"start": 1344.41, "end": 1344.87, "word": " بنلاحظ", "probability": 0.83233642578125}, {"start": 1344.87, "end": 1345.13, "word": " عندي", "probability": 0.672607421875}, {"start": 1345.13, "end": 1345.57, "word": " احتمال", "probability": 0.9532470703125}, {"start": 1345.57, "end": 1346.01, "word": " إيه؟", "probability": 0.76861572265625}, {"start": 1346.01, "end": 1346.27, "word": " إنه", "probability": 0.5975341796875}, {"start": 1346.27, "end": 1346.51, "word": " هذه", "probability": 0.525390625}, {"start": 1346.51, "end": 1347.27, "word": " الكربون", "probability": 0.9305013020833334}, {"start": 1347.27, "end": 1347.85, "word": " هذه", "probability": 0.454833984375}, {"start": 1347.85, "end": 1348.43, "word": " الكربون", "probability": 0.9778645833333334}, {"start": 1348.43, "end": 1348.59, "word": " اللي", "probability": 0.946533203125}, {"start": 1348.59, "end": 1348.89, "word": " هنا", "probability": 0.97412109375}, {"start": 1348.89, "end": 1349.31, "word": " في", "probability": 0.58203125}, {"start": 1349.31, "end": 1349.57, "word": " عندها", "probability": 0.77294921875}, {"start": 1349.57, "end": 1349.97, "word": " احتمال", "probability": 0.972412109375}, {"start": 1349.97, "end": 1350.25, "word": " هنا", "probability": 0.6630859375}], "temperature": 1.0}, {"id": 59, "seek": 137240, "start": 1350.94, "end": 1372.4, "text": "و في عندها احتمال هذا لو اتت ال OH اخدت هذا ال H شو عيصر عندى؟ هاي البونده هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond هاتيجي و تعمل double bond", "tokens": [2407, 8978, 43242, 11296, 1975, 33753, 2304, 6027, 23758, 45164, 1975, 2655, 2655, 2423, 13931, 1975, 9778, 3215, 2655, 23758, 2423, 389, 13412, 2407, 6225, 1829, 9381, 2288, 43242, 7578, 22807, 8032, 47302, 29739, 11536, 3215, 3224, 8032, 9307, 1829, 7435, 1829, 4032, 6055, 25957, 1211, 3834, 6086, 8032, 9307, 1829, 7435, 1829, 4032, 6055, 25957, 1211, 3834, 6086, 8032, 9307, 1829, 7435, 1829, 4032, 6055, 25957, 1211, 3834, 6086, 8032, 9307, 1829, 7435, 1829, 4032, 6055, 25957, 1211, 3834, 6086, 8032, 9307, 1829, 7435, 1829, 4032, 6055, 25957, 1211, 3834, 6086, 8032, 9307, 1829, 7435, 1829, 4032, 6055, 25957, 1211, 3834, 6086, 8032, 9307, 1829, 7435, 1829, 4032, 6055, 25957, 1211, 3834, 6086, 8032, 9307, 1829, 7435, 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"end": 1430.38, "word": " قاعدة", "probability": 0.9744873046875}, {"start": 1430.38, "end": 1430.84, "word": " بسيطة", "probability": 0.9923828125}, {"start": 1430.84, "end": 1431.28, "word": " بيسموها", "probability": 0.8541015625}, {"start": 1431.28, "end": 1431.44, "word": " the", "probability": 0.056915283203125}, {"start": 1431.44, "end": 1433.98, "word": " more", "probability": 0.65966796875}, {"start": 1433.98, "end": 1435.08, "word": " substituted", "probability": 0.9189453125}, {"start": 1435.08, "end": 1435.34, "word": " ال", "probability": 0.55029296875}, {"start": 1435.34, "end": 1435.8, "word": " keen", "probability": 0.342041015625}, {"start": 1435.8, "end": 1436.22, "word": " will", "probability": 0.716796875}, {"start": 1436.22, "end": 1436.76, "word": " form", "probability": 0.93896484375}, {"start": 1436.76, "end": 1437.22, "word": " ال", "probability": 0.7353515625}, {"start": 1437.22, "end": 1437.92, "word": " keen", "probability": 0.51513671875}, {"start": 1437.92, "end": 1438.28, "word": " اللي", "probability": 0.900390625}, {"start": 1438.28, "end": 1438.7, "word": " فيه", "probability": 0.800537109375}, {"start": 1438.7, "end": 1439.56, "word": " substitution", "probability": 0.900390625}, {"start": 1439.56, "end": 1440.28, "word": " اكتر", "probability": 0.8790283203125}, {"start": 1440.28, "end": 1441.74, "word": " بيتكول،", "probability": 0.677783203125}, {"start": 1441.74, "end": 1442.16, "word": " الان", "probability": 0.658935546875}, {"start": 1442.16, "end": 1442.78, "word": " بيصير", "probability": 0.9407958984375}, {"start": 1442.78, "end": 1443.54, "word": " ايش", "probability": 0.6476236979166666}, {"start": 1443.54, "end": 1444.22, "word": " معنى؟", "probability": 0.9344482421875}], "temperature": 1.0}, {"id": 63, "seek": 147416, "start": 1444.82, "end": 1474.16, "text": "more substituted القين واضح؟ عشان نعرف معنى more substituted القين يمكن لازم نكون متذاكرين ال unsubstituted القين القين الغير مبدل إيش هو القين الغير مبدل اللي بنسميه ال parent القين في قلقين إيش بنسميه ال parent القين ال parent يعني القين الأساسي اللي هو ال unsubstituted معنى parent", "tokens": [3138, 26441, 4866, 25062, 9957, 4032, 46958, 5016, 22807, 6225, 8592, 7649, 8717, 3615, 28480, 20449, 1863, 7578, 544, 26441, 4866, 25062, 9957, 7251, 43020, 5296, 31377, 2304, 8717, 30544, 44650, 15730, 37983, 9957, 2423, 2693, 836, 372, 270, 4866, 25062, 9957, 25062, 9957, 6024, 118, 13546, 3714, 44510, 1211, 11933, 1829, 8592, 31439, 25062, 9957, 6024, 118, 13546, 3714, 44510, 1211, 13672, 1829, 44945, 38251, 1829, 3224, 2423, 2596, 25062, 9957, 8978, 12174, 1211, 4587, 9957, 11933, 1829, 8592, 44945, 38251, 1829, 3224, 2423, 2596, 25062, 9957, 2423, 2596, 37495, 22653, 25062, 9957, 16247, 3794, 32277, 1829, 13672, 1829, 31439, 2423, 2693, 836, 372, 270, 4866, 20449, 1863, 7578, 2596], "avg_logprob": -0.16294643482459442, "compression_ratio": 2.2731958762886597, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1444.82, "end": 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"probability": 0.93359375}, {"start": 1467.58, "end": 1468.14, "word": " القين", "probability": 0.942138671875}, {"start": 1468.14, "end": 1468.32, "word": " ال", "probability": 0.94873046875}, {"start": 1468.32, "end": 1468.6, "word": " parent", "probability": 0.9453125}, {"start": 1468.6, "end": 1468.94, "word": " يعني", "probability": 0.94873046875}, {"start": 1468.94, "end": 1469.64, "word": " القين", "probability": 0.887451171875}, {"start": 1469.64, "end": 1470.74, "word": " الأساسي", "probability": 0.978271484375}, {"start": 1470.74, "end": 1471.34, "word": " اللي", "probability": 0.96142578125}, {"start": 1471.34, "end": 1471.76, "word": " هو", "probability": 0.98388671875}, {"start": 1471.76, "end": 1472.16, "word": " ال", "probability": 0.814453125}, {"start": 1472.16, "end": 1473.36, "word": " unsubstituted", "probability": 0.9697265625}, {"start": 1473.36, "end": 1473.84, "word": " معنى", "probability": 0.8313802083333334}, {"start": 1473.84, "end": 1474.16, "word": " parent", "probability": 0.9609375}], "temperature": 1.0}, {"id": 64, "seek": 150058, "start": 1476.9, "end": 1500.58, "text": "unsubstituted مافيش عليه ولا إبدال أبو ال الكينز كلها هو الاثيلين اللي مافيش عليه ولا إبدال واضح فال parent الكين لما يكون عندى C double bond C H H H H أكم هيدروجينة عندى أربع في أي واحدة منهم إبدلت", "tokens": [26684, 836, 372, 270, 4866, 19446, 41185, 8592, 47356, 49429, 11933, 44510, 6027, 5551, 3555, 2407, 2423, 2423, 4117, 9957, 11622, 28242, 11296, 31439, 2423, 5718, 104, 26895, 9957, 13672, 1829, 19446, 41185, 8592, 47356, 49429, 11933, 44510, 6027, 4032, 46958, 5016, 6156, 6027, 2596, 2423, 4117, 9957, 5296, 15042, 7251, 30544, 43242, 7578, 383, 3834, 6086, 383, 389, 389, 389, 389, 5551, 24793, 8032, 25708, 2288, 29245, 9957, 3660, 43242, 7578, 5551, 25513, 3615, 8978, 36632, 36764, 24401, 3660, 9154, 16095, 11933, 44510, 1211, 2655], "avg_logprob": -0.32273707924218015, "compression_ratio": 1.6683937823834196, "no_speech_prob": 0.0, "words": [{"start": 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"probability": 0.392578125}, {"start": 1488.82, "end": 1489.14, "word": " double", "probability": 0.4482421875}, {"start": 1489.14, "end": 1489.68, "word": " bond", "probability": 0.90283203125}, {"start": 1489.68, "end": 1490.14, "word": " C", "probability": 0.134033203125}, {"start": 1490.14, "end": 1491.4, "word": " H", "probability": 0.5888671875}, {"start": 1491.4, "end": 1493.1, "word": " H", "probability": 0.87255859375}, {"start": 1493.1, "end": 1494.7, "word": " H", "probability": 0.939453125}, {"start": 1494.7, "end": 1495.62, "word": " H", "probability": 0.64990234375}, {"start": 1495.62, "end": 1496.02, "word": " أكم", "probability": 0.5220947265625}, {"start": 1496.02, "end": 1496.76, "word": " هيدروجينة", "probability": 0.8990885416666666}, {"start": 1496.76, "end": 1497.22, "word": " عندى", "probability": 0.943603515625}, {"start": 1497.22, "end": 1498.22, "word": " أربع", "probability": 0.5916341145833334}, {"start": 1498.22, "end": 1498.62, "word": " في", 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"seek": 154624, "start": 1517.94, "end": 1546.24, "text": "البنزين عليه ستة هيدروجينات ممكن أبدل منهم واحدة بيصير مونو substitute ممكن تنتين تراي substitute ممكن تلاتة ممكن أربعة تترا substitute وها كذا الآن الاثيليل is the parent compound the unsubstituted compound الآن ممكن أبدأ أعمل عمليات إبدال للهيدروجين", "tokens": [6027, 3555, 1863, 11622, 9957, 47356, 8608, 2655, 3660, 8032, 25708, 2288, 29245, 9957, 9307, 3714, 43020, 5551, 44510, 1211, 9154, 16095, 36764, 24401, 3660, 4724, 1829, 9381, 13546, 3714, 11536, 2407, 15802, 3714, 43020, 6055, 29399, 9957, 6055, 23557, 1829, 15802, 3714, 43020, 6055, 1211, 9307, 3660, 3714, 43020, 5551, 25513, 27884, 6055, 2655, 23557, 15802, 4032, 11296, 9122, 15730, 6024, 48506, 2423, 5718, 104, 1829, 20292, 1211, 307, 264, 2596, 14154, 264, 2693, 836, 372, 270, 4866, 14154, 6024, 48506, 3714, 43020, 5551, 44510, 10721, 5551, 25957, 1211, 6225, 2304, 20292, 9307, 11933, 44510, 6027, 24976, 3224, 25708, 2288, 29245, 9957], "avg_logprob": 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إطلاقا وصار عندى أقصى إبدال على الاثيلين جداش أربعة أني أبدل الأربع هيدروجينات", "tokens": [10721, 8315, 3714, 43020, 5551, 25957, 1211, 15844, 2423, 5718, 104, 1829, 20292, 1863, 11933, 44510, 6027, 46740, 25708, 2288, 29245, 9957, 6055, 29399, 9957, 6055, 1211, 9307, 3660, 5551, 25513, 27884, 11933, 15730, 20328, 9640, 43242, 7578, 32771, 13546, 9673, 44510, 1211, 11933, 9566, 15040, 4587, 995, 4032, 9381, 9640, 43242, 7578, 5551, 4587, 9381, 7578, 11933, 44510, 6027, 15844, 2423, 5718, 104, 1829, 20292, 1863, 10874, 3215, 33599, 5551, 25513, 27884, 14739, 1829, 5551, 44510, 1211, 16247, 25513, 3615, 8032, 25708, 2288, 29245, 9957, 9307], "avg_logprob": -0.30007102103395894, "compression_ratio": 1.9933333333333334, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1576.02, "end": 1577.16, "word": "أنا", "probability": 0.29766845703125}, {"start": 1577.16, "end": 1577.56, "word": " ممكن", "probability": 0.6805419921875}, {"start": 1577.56, "end": 1577.96, "word": " أعمل", 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substituted بالتجربة لاحظوا كثيرا حتى أصبحت قاعدة في النهاية أنه دائما ال more substituted ال keen هو اللي إيش هو اللي بيتكون", "tokens": [5172, 995, 16095, 2655, 14407, 11933, 1829, 8592, 20449, 8315, 3224, 544, 26441, 4866, 22807, 6156, 3215, 16373, 15042, 11933, 15730, 8978, 43242, 24793, 1975, 33753, 2304, 6027, 9307, 14739, 3224, 3714, 43020, 23758, 2423, 6027, 4117, 9957, 4032, 23758, 2423, 6027, 4117, 9957, 4724, 10721, 2288, 38251, 1975, 2655, 1863, 9957, 4724, 8592, 38688, 14739, 31439, 2423, 544, 26441, 4866, 20666, 2655, 7435, 25513, 3660, 20193, 5016, 19913, 14407, 9122, 12984, 13546, 995, 11331, 49975, 5551, 9381, 3555, 33753, 12174, 995, 22488, 3660, 8978, 28239, 11296, 10632, 14739, 3224, 11778, 16373, 15042, 2423, 544, 26441, 4866, 2423, 20297, 31439, 13672, 1829, 11933, 1829, 8592, 31439, 13672, 1829, 4724, 36081, 30544], "avg_logprob": -0.19308036020291702, "compression_ratio": 1.8744394618834082, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1695.41, 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"end": 2050.98, "word": " في", "probability": 0.90966796875}, {"start": 2050.98, "end": 2051.44, "word": " مكان", "probability": 0.994873046875}, {"start": 2051.44, "end": 2051.88, "word": " ما", "probability": 0.982421875}, {"start": 2051.88, "end": 2052.92, "word": " كانت", "probability": 0.972900390625}, {"start": 2052.92, "end": 2053.92, "word": " حسابات", "probability": 0.992431640625}, {"start": 2053.92, "end": 2054.34, "word": " الطاقة", "probability": 0.9952799479166666}, {"start": 2054.34, "end": 2054.54, "word": " مش", "probability": 0.99169921875}, {"start": 2054.54, "end": 2054.9, "word": " سليمة", "probability": 0.8792317708333334}, {"start": 2054.9, "end": 2055.42, "word": " مايمشيش", "probability": 0.84521484375}, {"start": 2055.42, "end": 2056.06, "word": " التفاعل", "probability": 0.95654296875}, {"start": 2056.06, "end": 2056.62, "word": " يعني", "probability": 0.83544921875}, {"start": 2056.62, "end": 2056.98, "word": " ممكن", "probability": 0.98828125}, {"start": 2056.98, "end": 2057.38, "word": " كتير", "probability": 0.9568684895833334}, {"start": 2057.38, "end": 2057.64, "word": " we", "probability": 0.352294921875}, {"start": 2057.64, "end": 2057.86, "word": " can", "probability": 0.92822265625}, {"start": 2057.86, "end": 2059.04, "word": " eucleophiles", "probability": 0.6446044921875}, {"start": 2059.04, "end": 2059.68, "word": " تكون", "probability": 0.925048828125}, {"start": 2059.68, "end": 2060.52, "word": " بالمجمل", "probability": 0.9288330078125}, {"start": 2060.52, "end": 2060.86, "word": " من", "probability": 0.9873046875}, {"start": 2060.86, "end": 2061.26, "word": " ناحية", "probability": 0.9903971354166666}, {"start": 2061.26, "end": 2062.54, "word": " الطاقة", "probability": 0.9959309895833334}, {"start": 2062.54, "end": 2063.1, "word": " غير", "probability": 0.989013671875}, {"start": 2063.1, "end": 2063.72, "word": " إيجابية", "probability": 0.98466796875}, {"start": 2063.72, "end": 2063.86, "word": " و", "probability": 0.96826171875}, {"start": 2063.86, "end": 2064.64, "word": " نخلطها", "probability": 0.95361328125}, {"start": 2064.64, "end": 2065.3, "word": " و", "probability": 0.9619140625}, {"start": 2065.3, "end": 2065.86, "word": " مايمشيش", "probability": 0.94931640625}, {"start": 2065.86, "end": 2066.54, "word": " التفاعل", "probability": 0.9656982421875}], "temperature": 1.0}, {"id": 87, "seek": 209478, "start": 2067.14, "end": 2094.78, "text": "واضح؟ التفاعل وقته ايش بيمشي؟ لما يكون من ناحية الطاقة، معقول تعرفوا مرة عليكم أن التفاعل بتحكمه شغلتين أساسيتين، شو هما؟ أنه يكون عندي فاقة طاقة، اتقل الطاقة، هذا عامل ال stability و العامل التاني إيش يكون عنده؟ زيادة فوضة increase in the entropy", "tokens": [2407, 46958, 5016, 22807, 16712, 5172, 995, 30241, 4032, 38149, 3224, 1975, 1829, 8592, 4724, 32640, 8592, 1829, 22807, 5296, 15042, 7251, 30544, 9154, 8717, 39319, 10632, 41950, 995, 28671, 12399, 20449, 39648, 6055, 3615, 28480, 14407, 3714, 25720, 25894, 24793, 14739, 16712, 5172, 995, 30241, 39894, 5016, 24793, 3224, 13412, 17082, 1211, 2655, 9957, 5551, 3794, 32277, 36081, 9957, 12399, 13412, 2407, 8032, 15042, 22807, 14739, 3224, 7251, 30544, 18871, 16254, 6156, 995, 28671, 23032, 995, 28671, 12399, 1975, 2655, 4587, 1211, 41950, 995, 28671, 12399, 23758, 6225, 10943, 1211, 2423, 11826, 4032, 18863, 10943, 1211, 16712, 7649, 1829, 11933, 1829, 8592, 7251, 30544, 43242, 3224, 22807, 30767, 1829, 18513, 3660, 6156, 2407, 11242, 3660, 3488, 294, 264, 30867], "avg_logprob": -0.19847624065462222, "compression_ratio": 1.7366255144032923, "no_speech_prob": 0.0, "words": [{"start": 2067.14, "end": 2067.8, "word": "واضح؟", "probability": 0.77520751953125}, {"start": 2067.8, "end": 2068.3, "word": " التفاعل", "probability": 0.8585205078125}, {"start": 2068.3, "end": 2068.62, "word": " وقته", "probability": 0.5133463541666666}, {"start": 2068.62, "end": 2068.68, "word": " ايش", "probability": 0.6309407552083334}, {"start": 2068.68, "end": 2069.04, "word": " بيمشي؟", 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بتحكمه", "probability": 0.9774169921875}, {"start": 2075.44, "end": 2076.8, "word": " شغلتين", "probability": 0.97216796875}, {"start": 2076.8, "end": 2077.86, "word": " أساسيتين،", "probability": 0.9352213541666666}, {"start": 2077.86, "end": 2078.0, "word": " شو", "probability": 0.822998046875}, {"start": 2078.0, "end": 2079.56, "word": " هما؟", "probability": 0.8466796875}, {"start": 2079.56, "end": 2079.94, "word": " أنه", "probability": 0.724609375}, {"start": 2079.94, "end": 2080.32, "word": " يكون", "probability": 0.99072265625}, {"start": 2080.32, "end": 2080.68, "word": " عندي", "probability": 0.72607421875}, {"start": 2080.68, "end": 2081.08, "word": " فاقة", "probability": 0.8245442708333334}, {"start": 2081.08, "end": 2083.36, "word": " طاقة،", "probability": 0.8692626953125}, {"start": 2083.36, "end": 2083.84, "word": " اتقل", "probability": 0.8909912109375}, {"start": 2083.84, "end": 2084.58, "word": " الطاقة،", "probability": 0.9339599609375}, {"start": 2084.58, "end": 2084.74, "word": " هذا", "probability": 0.8857421875}, {"start": 2084.74, "end": 2085.26, "word": " عامل", "probability": 0.9943033854166666}, {"start": 2085.26, "end": 2085.38, "word": " ال", "probability": 0.56494140625}, {"start": 2085.38, "end": 2085.86, "word": " stability", "probability": 0.7939453125}, {"start": 2085.86, "end": 2086.32, "word": " و", "probability": 0.301025390625}, {"start": 2086.32, "end": 2086.76, "word": " العامل", "probability": 0.9059244791666666}, {"start": 2086.76, "end": 2087.16, "word": " التاني", "probability": 0.97314453125}, {"start": 2087.16, "end": 2087.36, "word": " إيش", "probability": 0.7542317708333334}, {"start": 2087.36, "end": 2087.68, "word": " يكون", "probability": 0.98486328125}, {"start": 2087.68, "end": 2090.58, "word": " عنده؟", "probability": 0.9461263020833334}, {"start": 2090.58, "end": 2091.16, "word": " زيادة", "probability": 0.989013671875}, {"start": 2091.16, "end": 2091.86, "word": " فوضة", "probability": 0.8160400390625}, {"start": 2091.86, "end": 2093.88, "word": " increase", "probability": 0.423095703125}, {"start": 2093.88, "end": 2094.16, "word": " in", "probability": 0.955078125}, {"start": 2094.16, "end": 2094.3, "word": " the", "probability": 0.79052734375}, {"start": 2094.3, "end": 2094.78, "word": " entropy", "probability": 0.9248046875}], "temperature": 1.0}, {"id": 88, "seek": 210916, "start": 2095.5, "end": 2109.16, "text": "متذكرين كان عندكم عشان يمشي التفاعل أخدته معادلة من أهم معادلة الكيميا على الإطلاق Delta G بتساوي Delta H minus D Delta S", "tokens": [2304, 2655, 8848, 37983, 9957, 25961, 43242, 24793, 6225, 8592, 7649, 7251, 2304, 8592, 1829, 16712, 5172, 995, 30241, 5551, 9778, 3215, 47395, 20449, 18513, 37977, 9154, 5551, 16095, 20449, 18513, 37977, 33251, 32640, 25528, 15844, 33688, 9566, 15040, 4587, 18183, 460, 39894, 3794, 995, 45865, 18183, 389, 3175, 413, 18183, 318], "avg_logprob": -0.19295400718473038, "compression_ratio": 1.3333333333333333, "no_speech_prob": 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"word": " الكيميا", "probability": 0.7752278645833334}, {"start": 2102.16, "end": 2102.32, "word": " على", "probability": 0.90185546875}, {"start": 2102.32, "end": 2103.28, "word": " الإطلاق", "probability": 0.877685546875}, {"start": 2103.28, "end": 2103.64, "word": " Delta", "probability": 0.405029296875}, {"start": 2103.64, "end": 2104.08, "word": " G", "probability": 0.4833984375}, {"start": 2104.08, "end": 2104.78, "word": " بتساوي", "probability": 0.71893310546875}, {"start": 2104.78, "end": 2105.64, "word": " Delta", "probability": 0.76025390625}, {"start": 2105.64, "end": 2106.02, "word": " H", "probability": 0.9599609375}, {"start": 2106.02, "end": 2106.54, "word": " minus", "probability": 0.76123046875}, {"start": 2106.54, "end": 2106.98, "word": " D", "probability": 0.4541015625}, {"start": 2106.98, "end": 2107.78, "word": " Delta", "probability": 0.71875}, {"start": 2107.78, "end": 2109.16, "word": " S", "probability": 0.9814453125}], "temperature": 1.0}, {"id": 89, "seek": 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0.888671875}, {"start": 2763.75, "end": 2764.19, "word": " افترضنا", "probability": 0.94560546875}, {"start": 2764.19, "end": 2764.39, "word": " واحد", "probability": 0.957275390625}, {"start": 2764.39, "end": 2764.89, "word": " بيصلح", "probability": 0.7325439453125}, {"start": 2764.89, "end": 2765.61, "word": " تلفزيون", "probability": 0.93466796875}, {"start": 2765.61, "end": 2765.99, "word": " كبير", "probability": 0.9908854166666666}, {"start": 2765.99, "end": 2766.07, "word": " و", "probability": 0.84814453125}, {"start": 2766.07, "end": 2766.17, "word": " ما", "probability": 0.8818359375}, {"start": 2766.17, "end": 2766.31, "word": " إلى", "probability": 0.96484375}, {"start": 2766.31, "end": 2766.55, "word": " ذلك", "probability": 0.994140625}, {"start": 2766.55, "end": 2767.07, "word": " متوقع", "probability": 0.9529622395833334}, {"start": 2767.07, "end": 2767.31, "word": " يصير", "probability": 0.8313802083333334}, {"start": 2767.31, "end": 2767.57, "word": " عنده", "probability": 0.9892578125}, {"start": 2767.57, "end": 2768.05, "word": " حريقة", "probability": 0.9835611979166666}], "temperature": 1.0}, {"id": 117, "seek": 278939, "start": 2769.69, "end": 2789.39, "text": "بيحط جنبه طفاية ميه لو حط طفاية ميه و كبها الميه على الجهاز مع الكهربا اللي موجودة و حتى لو مافيش كهربا بتخرب كل مكونات الجهاز لكن هو بتجيب طفاية الغاز ال halon بعص بتعمل منع لل أكسوجين عن النار بتطفيها بعد هيك كله بيروح", "tokens": [3555, 1829, 5016, 9566, 10874, 1863, 3555, 3224, 23032, 5172, 995, 10632, 3714, 1829, 3224, 45164, 11331, 9566, 23032, 5172, 995, 10632, 3714, 1829, 3224, 4032, 9122, 3555, 11296, 9673, 1829, 3224, 15844, 25724, 3224, 31377, 20449, 33251, 3224, 25513, 995, 13672, 1829, 3714, 29245, 23328, 3660, 4032, 11331, 49975, 45164, 19446, 41185, 8592, 9122, 3224, 25513, 995, 39894, 9778, 25513, 28242, 3714, 4117, 2407, 8315, 2655, 25724, 3224, 31377, 44381, 31439, 39894, 7435, 1829, 3555, 23032, 5172, 995, 10632, 6024, 118, 31377, 2423, 7523, 266, 4724, 3615, 9381, 39894, 25957, 1211, 9154, 3615, 24976, 5551, 4117, 3794, 29245, 9957, 18871, 2423, 8315, 2288, 39894, 9566, 41185, 11296, 39182, 39896, 4117, 28242, 3224, 4724, 13546, 2407, 5016], "avg_logprob": -0.15532309966067137, "compression_ratio": 1.9166666666666667, "no_speech_prob": 8.940696716308594e-07, "words": [{"start": 2769.69, "end": 2770.31, "word": "بيحط", "probability": 0.66949462890625}, {"start": 2770.31, "end": 2770.71, "word": " جنبه", "probability": 0.9429931640625}, {"start": 2770.71, "end": 2771.05, "word": " طفاية", "probability": 0.904296875}, {"start": 2771.05, "end": 2771.23, "word": " ميه", "probability": 0.6549479166666666}, {"start": 2771.23, "end": 2771.35, "word": " لو", "probability": 0.47119140625}, {"start": 2771.35, "end": 2771.59, "word": " حط", "probability": 0.859619140625}, {"start": 2771.59, "end": 2771.91, "word": " طفاية", "probability": 0.965576171875}, {"start": 2771.91, "end": 2772.17, "word": " ميه", "probability": 0.98779296875}, {"start": 2772.17, "end": 2772.31, "word": " و", "probability": 0.96142578125}, {"start": 2772.31, "end": 2772.65, "word": " كبها", "probability": 0.84130859375}, {"start": 2772.65, "end": 2773.27, "word": " الميه", "probability": 0.9694010416666666}, {"start": 2773.27, "end": 2773.89, "word": " على", "probability": 0.77880859375}, {"start": 2773.89, "end": 2774.57, "word": " الجهاز", "probability": 0.9720052083333334}, {"start": 2774.57, "end": 2775.13, "word": " مع", "probability": 0.884765625}, {"start": 2775.13, "end": 2775.81, "word": " الكهربا", "probability": 0.968994140625}, {"start": 2775.81, "end": 2776.03, "word": " اللي", "probability": 0.8115234375}, {"start": 2776.03, "end": 2776.93, "word": " موجودة", "probability": 0.979736328125}, {"start": 2776.93, "end": 2777.57, "word": " و", "probability": 0.69677734375}, {"start": 2777.57, "end": 2777.95, "word": " حتى", "probability": 0.78369140625}, {"start": 2777.95, "end": 2778.11, "word": " لو", "probability": 0.990234375}, {"start": 2778.11, "end": 2778.47, "word": " مافيش", "probability": 0.8759765625}, {"start": 2778.47, "end": 2778.83, "word": " كهربا", "probability": 0.9921875}, {"start": 2778.83, "end": 2779.31, "word": " بتخرب", "probability": 0.7459309895833334}, {"start": 2779.31, "end": 2779.53, "word": " كل", "probability": 0.96484375}, {"start": 2779.53, "end": 2780.09, "word": " مكونات", "probability": 0.9279296875}, {"start": 2780.09, "end": 2780.47, "word": " الجهاز", "probability": 0.9806315104166666}, {"start": 2780.47, "end": 2780.69, "word": " لكن", "probability": 0.7685546875}, {"start": 2780.69, "end": 2780.83, "word": " هو", "probability": 0.94775390625}, {"start": 2780.83, "end": 2781.19, "word": " بتجيب", "probability": 0.9091796875}, {"start": 2781.19, "end": 2781.69, "word": " طفاية", "probability": 0.9833984375}, {"start": 2781.69, "end": 2782.21, "word": " الغاز", "probability": 0.9689127604166666}, {"start": 2782.21, "end": 2782.39, "word": " ال", "probability": 0.95361328125}, {"start": 2782.39, "end": 2782.83, "word": " halon", "probability": 0.5904541015625}, {"start": 2782.83, "end": 2783.87, "word": " بعص", "probability": 0.7220052083333334}, {"start": 2783.87, "end": 2785.13, "word": " بتعمل", "probability": 0.9366861979166666}, {"start": 2785.13, "end": 2785.77, "word": " منع", "probability": 0.880126953125}, {"start": 2785.77, "end": 2785.99, "word": " لل", "probability": 0.8056640625}, {"start": 2785.99, "end": 2786.59, "word": " أكسوجين", "probability": 0.7546142578125}, {"start": 2786.59, "end": 2786.79, "word": " عن", "probability": 0.97900390625}, {"start": 2786.79, "end": 2787.15, "word": " النار", "probability": 0.9405924479166666}, {"start": 2787.15, "end": 2787.99, "word": " بتطفيها", "probability": 0.9024658203125}, {"start": 2787.99, "end": 2788.47, "word": " بعد", "probability": 0.76171875}, {"start": 2788.47, "end": 2788.73, "word": " هيك", "probability": 0.88671875}, {"start": 2788.73, "end": 2788.95, "word": " كله", "probability": 0.970703125}, {"start": 2788.95, "end": 2789.39, "word": " بيروح", "probability": 0.9654541015625}], "temperature": 1.0}, {"id": 118, "seek": 281365, "start": 2789.81, "end": 2813.65, "text": "ما خربش الجهاز عنده فهذه الطفيات طفيات ال halons ويلها أرقام بيعرفوها تعون الاطفايات لإطفاء الحرائق بالذات المتعلقة بالأجهزة الكهربائية بهيك تقريبا بنأمل أن أعطيناكوا فكرة عن ال alkyl halides وإن شاء الله الحصة القادمة بنبدأ في موضوع جديد", "tokens": [15042, 16490, 25513, 8592, 25724, 3224, 31377, 43242, 3224, 6156, 3224, 24192, 41950, 5172, 1829, 9307, 23032, 5172, 1829, 9307, 2423, 7523, 892, 4032, 26895, 11296, 5551, 2288, 4587, 10943, 4724, 40228, 28480, 2407, 11296, 37279, 11536, 2423, 41193, 5172, 47302, 9307, 5296, 28814, 9566, 5172, 16606, 21542, 2288, 16373, 4587, 20666, 8848, 9307, 9673, 2655, 30241, 28671, 20666, 10721, 7435, 3224, 11622, 3660, 33251, 3224, 25513, 16373, 10632, 39627, 1829, 4117, 6055, 4587, 16572, 3555, 995, 44945, 10721, 42213, 14739, 5551, 3615, 9566, 1829, 8315, 4117, 14407, 6156, 4117, 25720, 18871, 2423, 419, 4133, 75, 7523, 1875, 4032, 28814, 1863, 13412, 16606, 21984, 21542, 9381, 3660, 25062, 18513, 46007, 44945, 44510, 10721, 8978, 3714, 2407, 11242, 45367, 10874, 16254, 3215], "avg_logprob": -0.22489754281571653, "compression_ratio": 1.721311475409836, "no_speech_prob": 3.5762786865234375e-07, "words": [{"start": 2789.81, "end": 2789.97, "word": "ما", "probability": 0.31884765625}, {"start": 2789.97, "end": 2790.95, "word": " خربش", "probability": 0.8575846354166666}, {"start": 2790.95, "end": 2791.71, "word": " الجهاز", "probability": 0.9368489583333334}, {"start": 2791.71, "end": 2792.05, "word": " عنده", "probability": 0.9580078125}, {"start": 2792.05, "end": 2793.11, "word": " فهذه", "probability": 0.7421875}, {"start": 2793.11, "end": 2793.61, "word": " الطفيات", "probability": 0.73529052734375}, {"start": 2793.61, "end": 2794.21, "word": " طفيات", "probability": 0.66619873046875}, {"start": 2794.21, "end": 2794.37, "word": " ال", "probability": 0.9609375}, {"start": 2794.37, "end": 2794.81, "word": " halons", "probability": 0.56317138671875}, {"start": 2794.81, "end": 2795.11, "word": " ويلها", "probability": 0.6604817708333334}, {"start": 2795.11, "end": 2795.53, "word": " أرقام", "probability": 0.96044921875}, {"start": 2795.53, "end": 2795.99, "word": " بيعرفوها", "probability": 0.71806640625}, {"start": 2795.99, "end": 2796.27, "word": " تعون", "probability": 0.6253662109375}, {"start": 2796.27, "end": 2796.99, "word": " الاطفايات", "probability": 0.670263671875}, {"start": 2796.99, "end": 2798.07, "word": " لإطفاء", "probability": 0.8982421875}, {"start": 2798.07, "end": 2798.67, "word": " الحرائق", "probability": 0.9014892578125}, {"start": 2798.67, "end": 2799.11, "word": " بالذات", "probability": 0.97216796875}, {"start": 2799.11, "end": 2800.13, "word": " المتعلقة", "probability": 0.981689453125}, {"start": 2800.13, "end": 2801.73, "word": " بالأجهزة", "probability": 0.9468587239583334}, {"start": 2801.73, "end": 2802.99, "word": " الكهربائية", "probability": 0.98173828125}, {"start": 2802.99, "end": 2804.17, "word": " بهيك", "probability": 0.548583984375}, {"start": 2804.17, "end": 2804.81, "word": " تقريبا", "probability": 0.994140625}, {"start": 2804.81, "end": 2805.65, "word": " بنأمل", "probability": 0.892578125}, {"start": 2805.65, "end": 2805.83, "word": " أن", "probability": 0.662109375}, {"start": 2805.83, "end": 2806.79, "word": " أعطيناكوا", "probability": 0.7139718191964286}, {"start": 2806.79, "end": 2807.13, "word": " فكرة", "probability": 0.99267578125}, {"start": 2807.13, "end": 2807.43, "word": " عن", "probability": 0.98681640625}, {"start": 2807.43, "end": 2807.73, "word": " ال", "probability": 0.98193359375}, {"start": 2807.73, "end": 2808.13, "word": " alkyl", "probability": 0.6392415364583334}, {"start": 2808.13, "end": 2808.65, "word": " halides", "probability": 0.868408203125}, {"start": 2808.65, "end": 2808.89, "word": " وإن", "probability": 0.7957356770833334}, {"start": 2808.89, "end": 2809.13, "word": " شاء", "probability": 0.977294921875}, {"start": 2809.13, "end": 2809.29, "word": " الله", "probability": 0.943359375}, {"start": 2809.29, "end": 2810.19, "word": " الحصة", "probability": 0.98046875}, {"start": 2810.19, "end": 2810.73, "word": " القادمة", "probability": 0.9943033854166666}, {"start": 2810.73, "end": 2811.55, "word": " بنبدأ", "probability": 0.9274088541666666}, {"start": 2811.55, "end": 2811.75, "word": " في", "probability": 0.9228515625}, {"start": 2811.75, "end": 2812.31, "word": " موضوع", "probability": 0.996337890625}, {"start": 2812.31, "end": 2813.65, "word": " جديد", "probability": 0.9949544270833334}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2820.66725, "duration_after_vad": 2722.785624999989}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..f6b32dbaaa122ac48dd71819000bc32f1919af04
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/W_tM6CES1Q8_raw.srt
@@ -0,0 +1,2180 @@
+1
+00:00:05,080 --> 00:00:09,300
+اليوم ان شاء الله بنكمل تقريبا الجزء الأخير في هذا
+
+2
+00:00:09,300 --> 00:00:18,060
+الفصل لما قولنا موضوعنا ال alkyl halides ال R X و
+
+3
+00:00:18,060 --> 00:00:23,460
+بشكل أساسي تفاعلاتهم حكينا أنه فيه تفاعلين أساسيين
+
+4
+00:00:23,460 --> 00:00:27,960
+إما أن تتم عملية إبدال لل X substitution و هذه
+
+5
+00:00:27,960 --> 00:00:32,760
+درسناها بالتفصيل و أخدنا different mechanisms SN1
+
+6
+00:00:32,760 --> 00:00:38,680
+و SN2 mechanismsالان الاحتمال التاني ان ال X يتم
+
+7
+00:00:38,680 --> 00:00:43,500
+حذفها مع بروتون الهو elimination of HX في هذه
+
+8
+00:00:43,500 --> 00:00:48,840
+الحالة لما احذف ال X مع بروتون يتكون عندى double
+
+9
+00:00:48,840 --> 00:00:54,340
+bond بمعنى ان ال الكلهيليتز يعطوننا ال keys
+
+10
+00:00:54,340 --> 00:01:01,640
+الكلهيليتز يعطوننا ال keys هل لازم تلاحظوا نقطة ان
+
+11
+00:01:01,640 --> 00:01:08,300
+هدول التفاعلينتفاعلين خلّينا نقول تنافسيين يعني
+
+12
+00:01:08,300 --> 00:01:14,100
+ممكن التنين يحصلوا ولو بنسب متفاوتة في نفس الوقت
+
+13
+00:01:14,100 --> 00:01:19,880
+يعني بيطلع عند ناتج هو عبارة عن خليط من تفاعل
+
+14
+00:01:19,880 --> 00:01:26,500
+إبدال وتفاعلحذف يعني لو مثلا أخدت هذا المُركّب
+
+15
+00:01:26,500 --> 00:01:30,620
+اللي هو two bromopropane أو isopropyl bromide اللي
+
+16
+00:01:30,620 --> 00:01:36,620
+مار علينا و قولت بدي أفعله مع ال N A O H واضح؟
+
+17
+00:01:36,620 --> 00:01:42,350
+ممكن يصير عندى إبدال لل bromبال OH يعطينا ال
+
+18
+00:01:42,350 --> 00:01:46,510
+alcohol ال isopropyl alcohol و ممكن يصير عندى
+
+19
+00:01:46,510 --> 00:01:51,050
+عملية حذف لبروم مع إلكتروناتها لحظوا الحذف ليش
+
+20
+00:01:51,050 --> 00:01:56,490
+بيكون لبروم مع إلكتروناتها زائد واحدة من ال
+
+21
+00:01:56,490 --> 00:02:00,350
+hydrogens بهذا الشكل بدون إلكترونات طبعا لما بدى
+
+22
+00:02:00,350 --> 00:02:04,010
+تحذف هذه ال hydrogen بدون إلكترونات طب زوج
+
+23
+00:02:04,010 --> 00:02:08,230
+الإلكترونات اللى عامل bond معاها شو هيعمل؟هو اللي
+
+24
+00:02:08,230 --> 00:02:14,230
+حيلفه يعمل ال double bond واضح فبصير عملية حدث HPR
+
+25
+00:02:14,230 --> 00:02:20,310
+كأن بظبط بقول H plus PR minus لكن هو بيطلعش ايونيك
+
+26
+00:02:20,310 --> 00:02:23,910
+موليكيول موليكيول بيطلع موليكيولار موليكيول يعني
+
+27
+00:02:23,910 --> 00:02:28,230
+ال HPR مش جزء ايوني مابنقدرش نقول ان صيغته
+
+28
+00:02:28,230 --> 00:02:32,150
+الكيميائية H plus PR minus اللي هو جزء equivalent
+
+29
+00:02:33,090 --> 00:02:38,170
+بند موليكيولار موليكيول واضح الان لما بيحظف ال HPR
+
+30
+00:02:38,170 --> 00:02:42,910
+بيصير عنده elimination طبعا هذا الكلام هيعمل عندكم
+
+31
+00:02:42,910 --> 00:02:48,510
+مشكلة نوعا ما انه لو انا بدي اجي اسألكم ايش النتج
+
+32
+00:02:48,510 --> 00:02:54,360
+اللي بدكوا تحطوه واضح؟غالباً الناتج خليط من هذه
+
+33
+00:02:54,360 --> 00:02:59,880
+المراكبين واضح وإن كان ممكن يزيد في حالات معينة
+
+34
+00:02:59,880 --> 00:03:02,760
+تفاعل ال substitution ويكون تفاعل ال elimination
+
+35
+00:03:02,760 --> 00:03:07,020
+قليل وممكن في حالات تانية تكون نسبة ال elimination
+
+36
+00:03:07,020 --> 00:03:11,780
+عاليةو يكون نسبة ال substitution قليل و في حالات
+
+37
+00:03:11,780 --> 00:03:15,700
+تالتة ممكن تلاقوهم مثلا بنسبة اربعين لستين في
+
+38
+00:03:15,700 --> 00:03:19,380
+المية او خمسين لخمسين في المية يكون الناتجين وبنسب
+
+39
+00:03:19,380 --> 00:03:26,140
+تكاد تكون متساوي هذا الحقيقةبيعتمد على عوامل كثيرة
+
+40
+00:03:26,140 --> 00:03:29,980
+انه يصير الناتج اللي عنده elimination أو
+
+41
+00:03:29,980 --> 00:03:34,660
+substitution بيعتمد على عدة عوامل لحظو انا مثلا
+
+42
+00:03:34,660 --> 00:03:40,280
+ذاكرلكوا اربع انواع من العوامل العامل الأولالـ
+
+43
+00:03:40,280 --> 00:03:46,240
+type of alkyl halide نوع ال alkyl halide بشكل عام
+
+44
+00:03:46,240 --> 00:03:50,800
+بشكل عام لما يكون عنده primary alkyl halide
+
+45
+00:03:50,800 --> 00:03:55,720
+primary primary alkyl halide و بالذات ممكن هنا
+
+46
+00:03:55,720 --> 00:04:01,160
+نضيف زاد strong nucleophile strong nucleophile
+
+47
+00:04:01,160 --> 00:04:07,400
+التفاعل الأساسي إيش بيكونsubstitution غالبا
+
+48
+00:04:07,400 --> 00:04:12,840
+التفاعل بنسبته الكبيرة جدا جدا substitution وهذا
+
+49
+00:04:12,840 --> 00:04:17,660
+ال substitution كمان بيكون in SN2 ميكانيزم واضح
+
+50
+00:04:17,660 --> 00:04:23,040
+طيب واحدة ممكن تقول لو كان عنده ال primary alkyl
+
+51
+00:04:23,040 --> 00:04:27,840
+halide مع weakened nucleophile ال primary alkyl
+
+52
+00:04:27,840 --> 00:04:32,450
+halide مع weakened nucleophile غالبا متفعلشواضح؟
+
+53
+00:04:32,450 --> 00:04:35,370
+الـ Primary Alkyl Halide لو بدأ أضعه على الجهة
+
+54
+00:04:35,370 --> 00:04:40,570
+التانية زي الـ weak nucleophile غالبا ما بيصيرش
+
+55
+00:04:40,570 --> 00:04:46,490
+نتيجة لا حتى تفاعل إبدال بشكل كامل ولا تفاعل
+
+56
+00:04:46,490 --> 00:04:51,490
+elimination واضح؟ الآن لما يكون عنده secondary ال
+
+57
+00:04:51,490 --> 00:04:55,330
+secondary هو دائما اللي فيه الاحتمالين عاليين
+
+58
+00:04:55,330 --> 00:04:59,750
+بيكون عندهSubstitution و Elimination
+
+59
+00:05:27,300 --> 00:05:33,300
+أنا بقدر افعله مع التانين بقدر افعله مع ال strong
+
+60
+00:05:33,300 --> 00:05:39,380
+و بقدر افعله مع weak nucleophile الان انتوا اخدتوا
+
+61
+00:05:39,380 --> 00:05:43,080
+ان ال tertiary alkyl halide مع ال weak nucleophile
+
+62
+00:05:43,080 --> 00:05:48,590
+من اللي بيعمل substitution ب أسهم واحدةهذا الكلام
+
+63
+00:05:48,590 --> 00:05:52,870
+صحيح التيرتشاري الكلهيلايد مع الويك نيكليوفايل
+
+64
+00:05:52,870 --> 00:05:57,410
+بشكل أساس بيعمل substitution أعلى بـSN1 و لما يكون
+
+65
+00:05:57,410 --> 00:06:03,510
+تيرتشاري مع strong نيكليوفايل بيعمل elimination
+
+66
+00:06:03,510 --> 00:06:07,410
+طبعا
+
+67
+00:06:07,410 --> 00:06:11,480
+ال elimination ما أخدناش الميكانزمقلولي حتى الآن
+
+68
+00:06:11,480 --> 00:06:14,520
+هناخدها بعد شوية لما ناخدها بس عشان انا الجدول
+
+69
+00:06:14,520 --> 00:06:17,640
+يكتمل معاكم هتلاحظوا انه بنقوله بيعمل elimination
+
+70
+00:06:17,640 --> 00:06:24,020
+ال A2 ميكانيزمبنتعلم بعد شوية إيش معناه؟ A2
+
+71
+00:06:24,020 --> 00:06:30,500
+Mechanism تقريبا هيك الأمور بتصير سهلة الجزء اللي
+
+72
+00:06:30,500 --> 00:06:35,700
+احنا كنا ماخدينه حتى ما تحسوش ان العلم فيه تناقض
+
+73
+00:06:35,700 --> 00:06:39,840
+احنا كنا ماخدينه ان ال primary alkyl halide مع ال
+
+74
+00:06:39,840 --> 00:06:43,620
+strong nucleophileمين اللي بيعمل substitution و ب
+
+75
+00:06:43,620 --> 00:06:47,920
+SN2 هذا الكلام كنا ماخدينه و كنا ماخدينه ان ال
+
+76
+00:06:47,920 --> 00:06:51,500
+tertiary alkyl halide مع ال weak nucleophile مين
+
+77
+00:06:51,500 --> 00:06:56,940
+اللي بيعمل substitution ب SN1 الآن يمكن نضيفها لأن
+
+78
+00:06:56,940 --> 00:07:01,200
+ال primary مع ال weak nucleophile غالبا مافيش
+
+79
+00:07:01,200 --> 00:07:07,000
+تفاعلوالـ tertiary مع الـ strong الـ nucleophile
+
+80
+00:07:07,000 --> 00:07:14,460
+بيعمل إيقاف بميكانيزم E2 تقريبا يمكن هذا أكثر أو
+
+81
+00:07:14,460 --> 00:07:18,880
+من أكثر العوامل اللي بتأثر على التفاعل أن نشوف الـ
+
+82
+00:07:18,880 --> 00:07:21,580
+Alkyl Halide اللي عندنا primary أو secondary أو
+
+83
+00:07:21,580 --> 00:07:27,640
+tertiary و ال nucleophileweak أو strong و النتائج
+
+84
+00:07:27,640 --> 00:07:32,200
+موجودة عندكم ابتيجي عوامل أخرى تأثيرها أقل من هدول
+
+85
+00:07:32,200 --> 00:07:36,340
+يعني العوامل الأساسية زي لما أخدنا الميكانيزم كنا
+
+86
+00:07:36,340 --> 00:07:42,800
+بشكل أساسي نركز نوع الالكالهلايد نوع النيوكليوفايل
+
+87
+00:07:42,800 --> 00:07:48,480
+واضح نوع الالكالهلايد و نوع النيوكليوفايل
+
+88
+00:07:49,530 --> 00:07:53,750
+واضح؟ زي نفترض اتنين أصدقاء بدوا يكون بينهم علاقة
+
+89
+00:07:53,750 --> 00:07:58,890
+أحمد ومحمد أكتر إشي بيحدد هذه العلاقة أحمد ومحمد
+
+90
+00:07:58,890 --> 00:08:04,050
+هذا ما بيمنعش أنه في ظروف خارجية موجودة ممكن أنها
+
+91
+00:08:04,050 --> 00:08:07,370
+تأثر على هذا الكلام لكن إيش الشيء الأساسي اللي
+
+92
+00:08:07,370 --> 00:08:14,520
+بيأثر؟ اللي هم نفسالأساسية نفس المتفاعلين الان من
+
+93
+00:08:14,520 --> 00:08:18,620
+الأشياء الأساسية الإضافية اللي ممكن تأثر هي ال
+
+94
+00:08:18,620 --> 00:08:22,620
+solvent انا اي تفاعل بعمله ب solvent لاحظوا معي لو
+
+95
+00:08:22,620 --> 00:08:26,760
+كنت مثلا تفاعل عمله ب water بميه الميه بتشجع ال
+
+96
+00:08:26,760 --> 00:08:30,500
+substitution لو كنت عامله ب more polar solvent زي
+
+97
+00:08:30,500 --> 00:08:35,310
+اثانول الاثانول بشجعالـ elimination هاي معلومات
+
+98
+00:08:35,310 --> 00:08:39,190
+بالتجربة إيش نسبها ما إلى ذلك مابنقدرش كل شغلة
+
+99
+00:08:39,190 --> 00:08:44,710
+ندخل فيها درجة الحرارة مثلا الحرارة كل ما كانت
+
+100
+00:08:44,710 --> 00:08:49,690
+مرتفعة في إثناء التفاعل بتشجع ال elimination ال
+
+101
+00:08:49,690 --> 00:08:53,350
+concentration بالذات إذا كان عنده strong
+
+102
+00:08:53,350 --> 00:08:57,630
+nucleophile أو strong base يعني لما أنا بدي أجي
+
+103
+00:08:57,630 --> 00:09:00,790
+أحط هنا strong زي ما أخد ال KOH مثلا
+
+104
+00:09:03,410 --> 00:09:08,770
+هذا قوي و أكون بفعله مع الـ tertiary هيشجع بشكل
+
+105
+00:09:08,770 --> 00:09:14,350
+كبير ال elimination ال concentration of sodium or
+
+106
+00:09:14,350 --> 00:09:19,090
+potassium hydroxide تركيز عالية منه بتشجع ال
+
+107
+00:09:19,090 --> 00:09:24,370
+elimination بشكل أساسي في حالة ما يكون التفاعل مع
+
+108
+00:09:24,370 --> 00:09:28,570
+ال tertiary مع ال primary بيظل تفاعلنا الأساسي إيش
+
+109
+00:09:28,570 --> 00:09:35,270
+ال substitutionعلى أي حال، هنا يعني بتحسوا أنه
+
+110
+00:09:35,270 --> 00:09:41,790
+الكلام كتير و شوية بلخم، قد يظن البعض أنه بده قول
+
+111
+00:09:41,790 --> 00:09:47,030
+فصل، بصراحة لازم تكونوا عارفين أن الدنيا مابتمشيش
+
+112
+00:09:47,030 --> 00:09:57,090
+دائما بقول فصلإنه في أشياء هي هيك مش واضحة يعني في
+
+113
+00:09:57,090 --> 00:10:01,070
+النهاية لازم أعمل تجربة لحد ما أعرف النتيجة بالظبط
+
+114
+00:10:01,070 --> 00:10:06,910
+يعني مش كل إشي بيكون مثالي و بنقدر نحكم عليه بشكل
+
+115
+00:10:06,910 --> 00:10:12,090
+مثالي غير في الآخر إيشالواقع والتجربة هي اللي
+
+116
+00:10:12,090 --> 00:10:15,770
+بتطلع النتيجة النهائية يعني كلكم انا متأكد مليون
+
+117
+00:10:15,770 --> 00:10:19,410
+في المية دخلين على مساق ال organic chemistry بنية
+
+118
+00:10:19,410 --> 00:10:23,610
+صادقة في الدراسة وبنية صادقة بتحصيل علامة 100 من
+
+119
+00:10:23,610 --> 00:10:29,470
+100 الان هذا الوضع المثالي ان انتوا بتحضروا عندكم
+
+120
+00:10:29,470 --> 00:10:33,730
+الكتب بتدرسوا بتسمعوا المحاضرة بدكم تاخدوا 100 من
+
+121
+00:10:33,730 --> 00:10:37,710
+100 الان ايش أرض الواقع؟الله يعيدكوا و أقولكوا بس
+
+122
+00:10:37,710 --> 00:10:43,850
+واضح مش دايما الواقع بيطلع مثالي وبالتالي هلما
+
+123
+00:10:43,850 --> 00:10:47,650
+أقولكوا ممكن هيك ممكن هيك ممكن هيك انتوا في الحياة
+
+124
+00:10:47,650 --> 00:10:51,810
+الاجتماعية لو نقشته أي موضوع مش بتقول والله ممكن
+
+125
+00:10:51,810 --> 00:10:55,810
+هيك ممكن هيك ممكن هيك في إشي دايما هيك واضح و
+
+126
+00:10:55,810 --> 00:11:02,010
+clear cut هيك طبيعة إيش طبيعة الحياةالان لو اتينا
+
+127
+00:11:02,010 --> 00:11:08,170
+بدنا ندرس ال mechanisms of elimination واضح؟لو
+
+128
+00:11:08,170 --> 00:11:14,890
+أخدنا ال a2 ميكانيزم ال a2 ميكانيزم ال a2 ميكانيزم
+
+129
+00:11:14,890 --> 00:11:19,590
+دائما بتتم في حالة ما يكون عنده strong base و أكتر
+
+130
+00:11:19,590 --> 00:11:22,930
+إيش يقولنا لما يكون عنده strong base مع tertiary
+
+131
+00:11:22,930 --> 00:11:27,210
+يعني بدكم تعملوها زي فتوة شرقية أنه ال mechanism
+
+132
+00:11:27,210 --> 00:11:32,890
+إيش ال a2 ميكانيزم ال a2 تقريبا شبيه بال S and 2
+
+133
+00:11:32,890 --> 00:11:42,170
+إذا بتذكروا ال S and 2 كانتone step mechanismمظبوط
+
+134
+00:11:42,170 --> 00:11:48,310
+ولا لأ وبنفس الوقت كانت ال kinetics تبعتها معتمدة
+
+135
+00:11:48,310 --> 00:11:52,970
+على متفاعلين يعني ال rate تبعها بيساوي تركيز ال
+
+136
+00:11:52,970 --> 00:11:57,590
+alkyl halide في تركيز ال nucleophile ال OH minus
+
+137
+00:11:57,590 --> 00:12:02,850
+وفيها نوع من المصارعة بين متفاعلين مش واحد واقف
+
+138
+00:12:02,850 --> 00:12:07,070
+بتفرج و التاني بتفعل هذا الكلام وين شفته في ال SN1
+
+139
+00:12:07,070 --> 00:12:13,720
+الآن ال E2 في هذه الشغلة موازيةللـ SN2 الـ E2
+
+140
+00:12:13,720 --> 00:12:21,040
+موازية للـ SN2 لما بيجي الـ OH- لما بيجي الـ OH- و
+
+141
+00:12:21,040 --> 00:12:26,360
+بده يتفاعل لاحظوا هنا الـ OH- عبارة عن negative
+
+142
+00:12:26,360 --> 00:12:32,240
+charge و negative charge أسرع ما يمكن أسرع ما يمكن
+
+143
+00:12:32,240 --> 00:12:38,560
+بدها إيش؟بيدها positive دائما ال negative أسرع ما
+
+144
+00:12:38,560 --> 00:12:44,000
+يمكن بده positive الآن لو إجينا سألنا أنفسنا و
+
+145
+00:12:44,000 --> 00:12:48,360
+خلينا ناخد التفصيل اللي تحت يترى وين ال positive
+
+146
+00:12:48,360 --> 00:12:54,220
+ممكن تلاقيها ال OH minus ممكن تلاقي ال carbon هادى
+
+147
+00:12:55,760 --> 00:12:59,600
+واضح؟ ممكن تلاقي الـ carbon هذه اللي هنا مشكلة
+
+148
+00:12:59,600 --> 00:13:03,780
+انها partially positive و هذه البرومين partially
+
+149
+00:13:03,780 --> 00:13:08,540
+negative اذا هي positive الان في كمان positive
+
+150
+00:13:08,540 --> 00:13:11,100
+تاني ال proton ال H
+
+151
+00:13:14,170 --> 00:13:18,530
+هذا الـ H لحاله برضه يمثل إيش؟ positive و لو بده
+
+152
+00:13:18,530 --> 00:13:22,550
+يطلع لحاله يظل زوج الإلكترونات positive كامل إذا
+
+153
+00:13:22,550 --> 00:13:27,510
+الـ OH هذه اللي جاية وبتبحث عن positive صار عندها
+
+154
+00:13:27,510 --> 00:13:32,710
+الـ H عبارة عن positive و ال carbon اللي هنا عبارة
+
+155
+00:13:32,710 --> 00:13:38,810
+عن positive واضح؟ إذا هاجمت على ال carbon اللي هنا
+
+156
+00:13:38,810 --> 00:13:45,860
+هيبدأ يصير عندي خمس روابط حتوت ردالـ PR هيصير عند
+
+157
+00:13:45,860 --> 00:13:51,760
+الـ SN2 ميكانيزم هيصير عند ال substitution الإبدال
+
+158
+00:13:51,760 --> 00:13:57,300
+بمعنى لو أنا بدي أجي أقول هي ال OH- هاجمت هنا و
+
+159
+00:13:57,300 --> 00:14:03,580
+طردت ال CL أي تفاعل بدي يصير الإبدال إنه مكان مكان
+
+160
+00:14:03,580 --> 00:14:10,720
+عندي ال CL صار عنده OH طيب لو هذه هاجمت على ال
+
+161
+00:14:10,720 --> 00:14:15,820
+hydrogen هناأخدت بس الـ H لحالها بدون أزواج
+
+162
+00:14:15,820 --> 00:14:20,440
+الإلكترونات شو بده يصير لزوج الإلكترونات هذا؟ بده
+
+163
+00:14:20,440 --> 00:14:23,300
+يكوّن double bond مجرد ما يبدأ يكوّن double bond
+
+164
+00:14:23,300 --> 00:14:28,920
+كام bond بيصير عندي هنا؟ خمسة عشان نتخلص منهم الـ
+
+165
+00:14:28,920 --> 00:14:34,000
+PR بتطلع إذا في خطوة واحدة الميكانيزم ببساطة إنه
+
+166
+00:14:34,000 --> 00:14:40,400
+في خطوة واحدة الـ OH- بتيجي مع الـ H صار هذا زوج
+
+167
+00:14:40,400 --> 00:14:49,190
+إلكتروناتبلوف بهذا الشكل عشان ما يصيبش خمس بتطلع
+
+168
+00:14:49,190 --> 00:14:56,350
+ال PR طبعا هنا لاحظوا انه هيطلع عندى PR minus و ال
+
+169
+00:14:56,350 --> 00:15:01,090
+PR minus معاكش بده يصفق ال PR minus عفوا مع ال
+
+170
+00:15:01,090 --> 00:15:05,550
+sodium ماهي ال OH minus ايش بيكون معها Sodium او
+
+171
+00:15:05,550 --> 00:15:11,060
+كوتاسيوم يعني تخيلوا كانت يا K plusيعني ايه a a
+
+172
+00:15:11,060 --> 00:15:15,040
+plus و a h minus فال بي ار ماينوس هذه مع ال كي بلس
+
+173
+00:15:15,040 --> 00:15:19,660
+ايه بتعمل كي بي ار و ال a h minus مع ال اتش بلس
+
+174
+00:15:19,660 --> 00:15:24,900
+مية اذا نتيجة هذا التفاعل ان ال a h minus اخدت ال
+
+175
+00:15:24,900 --> 00:15:31,830
+اتش بلس عملت المية الان ال كي بلس مع ال بي ارعمل
+
+176
+00:15:31,830 --> 00:15:38,850
+KPR و الـ Alkyl Halide شو صار؟ صار ألكين صار ألكين
+
+177
+00:15:38,850 --> 00:15:42,390
+لأن هنا التفاعل في خطوة واحدة بمعنى هذه بتاخد
+
+178
+00:15:42,390 --> 00:15:46,450
+الأكشن هذه بتلوف هذه بتطلع بنفس اللحظة كام متفاعل
+
+179
+00:15:46,450 --> 00:15:56,610
+بتشوفوا عندكم؟ لأ هاي واحد وهاي واحد عشان هيك هذا
+
+180
+00:15:56,610 --> 00:16:06,220
+التفاعل بنقول عنه احنا one stepوبنقول عنه second
+
+181
+00:16:06,220 --> 00:16:11,580
+order إيش معناه second order؟ إن ال rate تبعته
+
+182
+00:16:11,580 --> 00:16:22,120
+بتسوي K في OH- في RXكل واحدة لأس واحد بالتجارة
+
+183
+00:16:22,120 --> 00:16:26,900
+واضح؟ إذا هذا تفاعل من one step و second order
+
+184
+00:16:26,900 --> 00:16:29,640
+reaction the rate of reaction depends on the
+
+185
+00:16:29,640 --> 00:16:33,620
+concentration of the hydroxide ion كل ما كان ال
+
+186
+00:16:33,620 --> 00:16:39,680
+hydroxide ايون أكتر كل ما كان التفاعل أسرع يمكن
+
+187
+00:16:39,680 --> 00:16:48,620
+هنا يجيني شغلة لما نيجي نقول انهالـ strong base مع
+
+188
+00:16:48,620 --> 00:16:53,520
+ال primary قبل شوية لسه قولنا إيش بيعطي بشكل أساسي
+
+189
+00:16:53,520 --> 00:16:59,580
+إبدال ال strong base مع ال tertiary إيش بيعطي بشكل
+
+190
+00:16:59,580 --> 00:17:06,480
+أساسي elimination ليش بيصير هذا الكلام؟ واضح؟ ليش
+
+191
+00:17:06,480 --> 00:17:12,260
+ال strong base مع ال primary بيعطيإبدال والـ
+
+192
+00:17:12,260 --> 00:17:16,140
+strong base مع الـ tertiary غالبا يعني يصل إلى
+
+193
+00:17:16,140 --> 00:17:22,920
+نسبة 100% بيعطي elimination واضح؟ انتوا اتطلعوا
+
+194
+00:17:22,920 --> 00:17:28,960
+على هذه الـ OH- وافترضوا ان هذه هي الـ strong base
+
+195
+00:17:28,960 --> 00:17:33,900
+لو كان هذه الـ carbon tertiary بمعنى هنا في عندى R
+
+196
+00:17:33,900 --> 00:17:39,850
+الـ R ايش مالها؟ كبيرة وهنا في عندى Rالـ R كبيرة
+
+197
+00:17:39,850 --> 00:17:44,310
+وهي الـ tertiary وهنا فيه positive مخبّى في قلبهم
+
+198
+00:17:44,310 --> 00:17:50,290
+وهنا فيه positive على الطرف أنه أسهل الـ OH minus
+
+199
+00:17:50,290 --> 00:17:55,030
+تيجي على هذا ال positive فيه لو أسع تصل ال
+
+200
+00:17:55,030 --> 00:17:59,610
+positive لل carbon عشانك مابيصيرش إبدال ملاحظين
+
+201
+00:17:59,610 --> 00:18:05,420
+انتوا؟مع الـ tertiary الـ OH- ما عندهاش وسع تصل
+
+202
+00:18:05,420 --> 00:18:10,900
+للكربون هذه الموجة بل الكربون مدفون مدفونة لما
+
+203
+00:18:10,900 --> 00:18:17,540
+تتخيل ان هذا الكربون مثلا CH3 CHHH و هنا CH3 CHHH
+
+204
+00:18:17,540 --> 00:18:25,930
+كله محوط قادرة تصل ال positive المخفي اللي هنالكن
+
+205
+00:18:25,930 --> 00:18:32,130
+بسهولة بتصطدم بـ H بأي H plus لأن الـ H plus طرفية
+
+206
+00:18:32,130 --> 00:18:39,830
+الكربون مخفية الواحد دايما بياخد من الاشي اللي على
+
+207
+00:18:39,830 --> 00:18:46,650
+الطرف و لا من الاشي المخفي الآن زي ما حكينا عندنا
+
+208
+00:18:46,650 --> 00:18:52,740
+الـ OH minus بتبحث عن positive في positiveمخبية
+
+209
+00:18:52,740 --> 00:18:57,180
+صعبة الوصول اليها و في positive طرفية ان هي اللي
+
+210
+00:18:57,180 --> 00:19:00,700
+هتاخدها في حالة ال tertiary الطرفية فطالما انه
+
+211
+00:19:00,700 --> 00:19:04,280
+خبطت في هذا ال positive اللي على الطرف هنا معنى
+
+212
+00:19:04,280 --> 00:19:09,440
+ذلك هتمشي او تستكمل الميكانزم ب E2 elimination
+
+213
+00:19:09,440 --> 00:19:13,500
+هيكون التفاعل بشكل أساسي elimination لكن لو هذه
+
+214
+00:19:13,500 --> 00:19:18,980
+كانت primary H OH في وسع كتير في وسع كتير لل OH
+
+215
+00:19:18,980 --> 00:19:23,600
+minusتيجي و تتفاعل فبتتم عملية ال substitution
+
+216
+00:19:23,600 --> 00:19:30,500
+الان لو سألناكم على .. لو سألناكم على هذا الكلام
+
+217
+00:19:30,500 --> 00:19:37,860
+رغم انه يبدو كلام كيميائي فيه له كمان دليل شرعي؟
+
+218
+00:19:37,860 --> 00:19:46,360
+اه في الشريعة ما هي الكيميا زي الشريعة اه لإن طبعا
+
+219
+00:19:48,300 --> 00:19:52,720
+أيوة، وين بيربطوا المفاهيم العلمية بالإنسانية؟
+
+220
+00:19:52,720 --> 00:20:03,320
+الاشي بياخد اللي على الطرف ولا اللي في النص؟ إنما
+
+221
+00:20:03,320 --> 00:20:08,280
+يأكلوا الذئبه من الغنم القاصية الذئب لما بيجي يعمل
+
+222
+00:20:08,280 --> 00:20:12,120
+abstraction نحنا هنا ناخد حاجة، نتفاعل مع حاجة
+
+223
+00:20:12,120 --> 00:20:15,860
+بيجي الذئب على غنمة في وسط القطيع ولا على اللي شرد
+
+224
+00:20:15,860 --> 00:20:20,900
+على برة؟على اللي شارد لبرا، مظبوط ولا لأ؟ دايما
+
+225
+00:20:20,900 --> 00:20:25,660
+اللي متطرف وشارد لبرا هو اللي بيجي الذئب بيأكله،
+
+226
+00:20:25,660 --> 00:20:28,660
+مظبوط ولا لأ؟ الآن هذه الـH، ما شاء الله عنهاية
+
+227
+00:20:28,660 --> 00:20:33,260
+طرفية، وهذا الـcarbon في حالة الترشري مخفية،
+
+228
+00:20:33,260 --> 00:20:39,950
+مدفونةما هو الأسهل للـ OH-؟ أن تأخذ الأشي الخارجي
+
+229
+00:20:39,950 --> 00:20:45,870
+الطرفي ولذلك هذا التعليل أنه ليش الـ tertiary مع
+
+230
+00:20:45,870 --> 00:20:51,090
+الـ strong nucleophiles undergo mainly elimination
+
+231
+00:20:51,090 --> 00:20:57,030
+reaction with E2 ميكانيزم because it can reach ..
+
+232
+00:20:57,030 --> 00:21:02,840
+طبعا هذا سكندريهذا اللي هنا secondary، تخيلوا لو
+
+233
+00:21:02,840 --> 00:21:07,800
+كان tertiary، بتكون العملية أصعب، it can reach the
+
+234
+00:21:07,800 --> 00:21:16,220
+H plus easier than the carbon plusواضح؟ بتقدر تصل
+
+235
+00:21:16,220 --> 00:21:21,900
+للـ H Plus أسهل ما تصل لـ Carbon واضح؟ ولهذا احنا
+
+236
+00:21:21,900 --> 00:21:25,000
+كتبنا الجملة انه لما يكون عندنا tertiary alkyl
+
+237
+00:21:25,000 --> 00:21:29,940
+halide مع strong base زي الـ KOH التفاعل بشكل أساس
+
+238
+00:21:29,940 --> 00:21:37,180
+ال main reaction is elimination الآن هنا بتجينا
+
+239
+00:21:37,180 --> 00:21:46,810
+شغلة مراتموجودة عندنا بمثل بيقول خيره خيره واضح
+
+240
+00:21:46,810 --> 00:21:50,690
+الكلام نفسه بيجي مرات و بيواجهنا بالكيميا لو
+
+241
+00:21:50,690 --> 00:21:54,930
+افترضت عند هذا المركب .. لو افترضت عند هذا المركب
+
+242
+00:21:54,930 --> 00:22:02,630
+one two three four two promo بيوتينوأنا بدي أعمل
+
+243
+00:22:02,630 --> 00:22:06,550
+تفاعل مع الـ OH- مركز إنه أشوف ناتج ال elimination
+
+244
+00:22:06,550 --> 00:22:11,250
+إحنا قلنا أكيد بزام بنحكي عن elimination بده تطلع
+
+245
+00:22:11,250 --> 00:22:16,950
+ال PR مع إلكتروناتها OH على كربونة مجاورة دائما ال
+
+246
+00:22:16,950 --> 00:22:21,470
+H من وين بتطلع؟ مش من نفس الكربون من الكربونة
+
+247
+00:22:21,470 --> 00:22:24,870
+المجاورة عشان تعمل double bond الآن هنا بنلاحظ
+
+248
+00:22:24,870 --> 00:22:28,590
+عندي احتمال إيه؟ إنه هذه الكربون هذه الكربون اللي
+
+249
+00:22:28,590 --> 00:22:32,960
+هنا في عندها احتمال هناو في عندها احتمال هذا لو
+
+250
+00:22:32,960 --> 00:22:38,360
+اتت ال OH اخدت هذا ال H شو عيصر عندى؟ هاي البونده
+
+251
+00:22:38,360 --> 00:22:42,060
+هاتيجي و تعمل double bond هاتيجي و تعمل double
+
+252
+00:22:42,060 --> 00:22:43,040
+bond هاتيجي و تعمل double bond هاتيجي و تعمل
+
+253
+00:22:43,040 --> 00:22:44,660
+double bond هاتيجي و تعمل double bond هاتيجي و
+
+254
+00:22:44,660 --> 00:22:46,540
+تعمل double bond هاتيجي و تعمل double bond هاتيجي
+
+255
+00:22:46,540 --> 00:22:46,540
+و تعمل double bond هاتيجي و تعمل double bond
+
+256
+00:22:46,540 --> 00:22:46,540
+هاتيجي و تعمل double bond هاتيجي و تعمل double
+
+257
+00:22:46,540 --> 00:22:46,540
+bond هاتيجي و تعمل double bond هاتيجي و تعمل
+
+258
+00:22:46,540 --> 00:22:46,540
+double bond هاتيجي و تعمل double bond هاتيجي و
+
+259
+00:22:46,540 --> 00:22:47,780
+تعمل double bond هاتيجي و تعمل double bond هاتيجي
+
+260
+00:22:47,780 --> 00:22:52,400
+و تعمل double bond
+
+261
+00:22:55,920 --> 00:23:01,360
+هيطلع عنده ألوان بيوتين إذا أنا في عند جنب ال PR
+
+262
+00:23:01,360 --> 00:23:07,300
+من الجهتين أتشز وين بده يكون الإختيار أنه بيطلع
+
+263
+00:23:07,300 --> 00:23:11,740
+بشكل أعلى هنا في عندنا قاعدة بتقول لما يكون عند
+
+264
+00:23:11,740 --> 00:23:17,320
+هذا النمط من الإختيار مش دايما موجود هذا النمط
+
+265
+00:23:17,320 --> 00:23:22,440
+يعني مرات مابيكونش غيرنوع واحد فقط من الهيدروجين
+
+266
+00:23:22,440 --> 00:23:27,580
+وما بيكون إلا احتمال واحد للناتج مرات بيكون عنده
+
+267
+00:23:27,580 --> 00:23:32,420
+احتمالين ومرات بيكون عنده تلاتة يعني لو اتخيلتوا
+
+268
+00:23:32,420 --> 00:23:35,760
+مثلا ان هذا ال carbon اللي حملة PR حملة هنا كمان
+
+269
+00:23:35,760 --> 00:23:40,400
+carbon وعليها etchesيا بده يطلع من هنا، يا من هنا،
+
+270
+00:23:40,400 --> 00:23:44,060
+يا من ال carbon الثالثة، بصير عندي تلت احتمالات طب
+
+271
+00:23:44,060 --> 00:23:46,780
+لما يكون عندي احتمالين او تلت احتمالات، اي
+
+272
+00:23:46,780 --> 00:23:50,840
+الاحتمالات هو المفضل الحدث؟ عندنا قاعدة بسيطة
+
+273
+00:23:50,840 --> 00:23:57,220
+بيسموها the more substituted ال keen will form ال
+
+274
+00:23:57,220 --> 00:24:02,780
+keen اللي فيه substitution اكتر بيتكول، الان بيصير
+
+275
+00:24:02,780 --> 00:24:09,320
+ايش معنى؟more substituted القين واضح؟ عشان نعرف
+
+276
+00:24:09,320 --> 00:24:12,900
+معنى more substituted القين يمكن لازم نكون
+
+277
+00:24:12,900 --> 00:24:18,120
+متذاكرين ال unsubstituted القين القين الغير مبدل
+
+278
+00:24:18,120 --> 00:24:23,080
+إيش هو القين الغير مبدل اللي بنسميه ال parent
+
+279
+00:24:23,080 --> 00:24:28,320
+القين في قلقين إيش بنسميه ال parent القين ال
+
+280
+00:24:28,320 --> 00:24:33,360
+parent يعني القين الأساسي اللي هو ال unsubstituted
+
+281
+00:24:33,360 --> 00:24:34,160
+معنى parent
+
+282
+00:24:36,900 --> 00:24:41,000
+unsubstituted مافيش عليه ولا إبدال أبو ال الكينز
+
+283
+00:24:41,000 --> 00:24:45,760
+كلها هو الاثيلين اللي مافيش عليه ولا إبدال واضح
+
+284
+00:24:45,760 --> 00:24:53,100
+فال parent الكين لما يكون عندى C double bond C H H
+
+285
+00:24:53,100 --> 00:25:00,580
+H H أكم هيدروجينة عندى أربع في أي واحدة منهم إبدلت
+
+286
+00:25:01,580 --> 00:25:06,860
+بزام كله هيدروجينز، إذا هذا هو الـ parent، الأبو،
+
+287
+00:25:06,860 --> 00:25:11,620
+مافيش فيه ولا إبدال، عرفتوا إيش معنى parent؟ طيب
+
+288
+00:25:11,620 --> 00:25:15,080
+لو بدي أجي أقولكم مثلا في ال aromatic compounds،
+
+289
+00:25:15,080 --> 00:25:20,200
+إيش ال parent aromatic compound؟البنزين عليه ستة
+
+290
+00:25:20,200 --> 00:25:25,360
+هيدروجينات ممكن أبدل منهم واحدة بيصير مونو
+
+291
+00:25:25,360 --> 00:25:30,320
+substitute ممكن تنتين تراي substitute ممكن تلاتة
+
+292
+00:25:30,320 --> 00:25:36,700
+ممكن أربعة تترا substitute وها كذا الآن الاثيليل
+
+293
+00:25:36,700 --> 00:25:40,780
+is the parent compound the unsubstituted compound
+
+294
+00:25:40,780 --> 00:25:48,220
+الآن ممكن أبدأ أعمل عمليات إبدال للهيدروجينلو إجيت
+
+295
+00:25:48,220 --> 00:25:53,840
+شيلت هيدروجين و حطيت بدالها R بيصير هذا كام
+
+296
+00:25:53,840 --> 00:25:58,400
+substitution فيه؟ واحد .. one substitution لو من
+
+297
+00:25:58,400 --> 00:26:02,780
+أي مكان شيلت كمان هيدروجين و حطيت كمان R؟ die
+
+298
+00:26:02,780 --> 00:26:07,640
+substituted لو شيلت كمان هيدروجين و حطيت كمان R
+
+299
+00:26:07,640 --> 00:26:12,580
+تالتة try substituted لو شيلت كمان هيدروجين و حطيت
+
+300
+00:26:12,580 --> 00:26:19,280
+كمان R رابعةأنا ممكن أعمل على الاثيلين إبدال
+
+301
+00:26:19,280 --> 00:26:23,720
+لهيدروجين تنتين تلاتة أربعة إذا صار عندى غير
+
+302
+00:26:23,720 --> 00:26:28,480
+المبدل إطلاقا وصار عندى أقصى إبدال على الاثيلين
+
+303
+00:26:28,480 --> 00:26:35,090
+جداش أربعة أني أبدل الأربع هيدروجيناتالآن لما بدنا
+
+304
+00:26:35,090 --> 00:26:39,350
+نشوف أي ناتج بيطلع بنشوف أكم إبدال عندنا لو لاحظنا
+
+305
+00:26:39,350 --> 00:26:44,650
+ناتج تم فيه أربع إبدالات و الناتج التاني فيه
+
+306
+00:26:44,650 --> 00:26:49,370
+إبدالين من المفضل اللي فيه أربعة لو ناتج فيه تلت
+
+307
+00:26:49,370 --> 00:26:55,040
+إبدالات و التاني فيه إبدالين من المفضل التلاتةنجي
+
+308
+00:26:55,040 --> 00:26:59,440
+نطلع على النواتج المكونة هنا و اتخيلوا الـ etches
+
+309
+00:26:59,440 --> 00:27:03,040
+كأنها طالعة من الـ carbons تبعون الـ double bond و
+
+310
+00:27:03,040 --> 00:27:08,960
+نجي نسأل نفسنا في هذا المُركّب الـ one بيوتين كام
+
+311
+00:27:08,960 --> 00:27:15,020
+إبدال عنده؟ لاحظوا معي لو شطبت هذول ال etches
+
+312
+00:27:15,020 --> 00:27:21,120
+موجودين، هاي etch، هاي etch، فيهم إبدال؟ و هاد ال
+
+313
+00:27:21,120 --> 00:27:27,780
+etchموجودة، إذا كام إبدال عندى في هذا؟ واحد فقط
+
+314
+00:27:27,780 --> 00:27:32,820
+هنا في عندى one substitution من الأربعة
+
+315
+00:27:32,820 --> 00:27:38,840
+هيدروجينات، كم ضايل؟ ضايل تلاتة ابدلت واحدة، إذا
+
+316
+00:27:38,840 --> 00:27:43,400
+هنا ال substitution كم؟ واحد لو أجيت هنا حوالي ال
+
+317
+00:27:43,400 --> 00:27:49,880
+double bond، إيش في عندى؟ H وH كم إبدال عندى؟
+
+318
+00:27:49,880 --> 00:27:54,250
+اتنينإذا هذا المركب الـ two butane كام
+
+319
+00:27:54,250 --> 00:27:57,810
+substitution فيه؟ اتنين وال one butane كام
+
+320
+00:27:57,810 --> 00:28:02,750
+substitution فيه؟ واحد أي مركب اللي بتكون بنسبة
+
+321
+00:28:02,750 --> 00:28:07,970
+أعلى اللي هو ال more substituted إذا ال two butane
+
+322
+00:28:07,970 --> 00:28:13,410
+will form more than the one butane because two
+
+323
+00:28:13,410 --> 00:28:16,510
+butane is more substitutedفاهمتوا إيش معناه more
+
+324
+00:28:16,510 --> 00:28:22,270
+substituted؟ فدائما إذا في عندكم احتمالات أنه ممكن
+
+325
+00:28:22,270 --> 00:28:26,950
+هذا الالكين و هذا الالكين بأرسم اتنين بشوف أن هو
+
+326
+00:28:26,950 --> 00:28:31,850
+ال more substituted بالتجربة لاحظوا كثيرا حتى
+
+327
+00:28:31,850 --> 00:28:35,170
+أصبحت قاعدة في النهاية أنه دائما ال more
+
+328
+00:28:35,170 --> 00:28:39,840
+substituted ال keen هو اللي إيش هو اللي بيتكونواضح
+
+329
+00:28:39,840 --> 00:28:44,020
+إذا كيف لما يكون عندى PR من أكثر من جهة Hydrogen
+
+330
+00:28:44,020 --> 00:28:50,140
+بارسم كل النواتج الممكنة و بشوف ال more
+
+331
+00:28:50,140 --> 00:28:53,580
+substituted الان واحدة ممكن تقول ممكن التانية يطلع
+
+332
+00:28:53,580 --> 00:28:56,120
+هذا فيه two substitution و هذا two substitution
+
+333
+00:28:56,120 --> 00:29:01,640
+وقتها بطلع خليط شبه متساوي من مركبين وقتها بطلع
+
+334
+00:29:01,640 --> 00:29:06,200
+خليط شبه متساوي من مركبين
+
+335
+00:29:18,410 --> 00:29:23,430
+بنجي للنوع التاني للنوع التاني من ال elimination و
+
+336
+00:29:23,430 --> 00:29:27,370
+احنا قولنا هذا النوع التاني من ال elimination اكتر
+
+337
+00:29:27,370 --> 00:29:33,810
+اشي ممكن يواجهنا لما يكون في عندنا weak ال
+
+338
+00:29:33,810 --> 00:29:38,730
+nucleophile او weak base طالما weak nucleophile
+
+339
+00:29:38,730 --> 00:29:43,890
+اتفقنا احنا انه ال weak nucleophile بقدرش يعمل ولا
+
+340
+00:29:43,890 --> 00:29:52,710
+شغلة بقعد يتفرج اش بستنىباستثناء ان الـ Cl تفقد مع
+
+341
+00:29:52,710 --> 00:29:59,910
+إلكتروناته ويتكون عنده كاربو كاتيون واضح؟ الآن هذا
+
+342
+00:29:59,910 --> 00:30:03,790
+الكاربو كاتيون هذا الكاربو كاتيون اللي اتكون عنده
+
+343
+00:30:03,790 --> 00:30:09,510
+ممكن يكمل التفاعل ل substitution وممكن يكمل
+
+344
+00:30:09,510 --> 00:30:13,370
+التفاعل ل elimination إذا إجى النيوكليوفايل هنا
+
+345
+00:30:13,370 --> 00:30:20,220
+وهاجم على الكاربونإذا جاء النيوكليوفايل وهاجم على
+
+346
+00:30:20,220 --> 00:30:24,940
+الكاربون، ماذا سيحصل عنده؟ يبدأ النيوكليوفايل
+
+347
+00:30:24,940 --> 00:30:29,880
+بإستخدام الـ SN1 طيب، هذا النيوكليوفايل بتطلع على
+
+348
+00:30:29,880 --> 00:30:34,970
+إيش؟ع الموجب وشاف ال carbon موجبة طيب و هذا ال
+
+349
+00:30:34,970 --> 00:30:38,830
+nucleophile ممكن كما نشوف هنا ال hydrogen كأنها
+
+350
+00:30:38,830 --> 00:30:44,090
+موجبة؟ ممكن اه و بالتالي ال nucleophile هذا لو اجا
+
+351
+00:30:44,090 --> 00:30:47,750
+و اصطدم بال hydrogen و أخد هشال .. هشال ال
+
+352
+00:30:47,750 --> 00:30:53,390
+hydrogen ايش بيترك لهنا؟هيترك لل bond هذه و بتقول
+
+353
+00:30:53,390 --> 00:30:56,870
+له فانا بتعمل double bond بيصير عند ال elimination
+
+354
+00:30:56,870 --> 00:31:05,230
+واضح؟ إذا بنقدر نستنتج أن ال SN1 و ال E1 حقيقة
+
+355
+00:31:05,230 --> 00:31:12,930
+عبارة عن تفاعل بخطوتين الخطوة الأولى منهم مشتركة
+
+356
+00:31:13,780 --> 00:31:21,500
+يعني both SN1 و E1 لديهم نفس الـ first step لو كنا
+
+357
+00:31:21,500 --> 00:31:27,380
+رسمين هدول هيك برسمة واحدة كأننا بيقول ال first
+
+358
+00:31:27,380 --> 00:31:33,780
+step minus CL minus فقدت ال CL هذه ال first step
+
+359
+00:31:33,780 --> 00:31:38,300
+مشتركة للتانتين بعد ما تفقد ال CL بيجي نيوكليو فيل
+
+360
+00:31:38,300 --> 00:31:39,880
+على ال positive بيعطيني
+
+361
+00:31:49,990 --> 00:31:57,450
+الخطوة الصعبة في هذا التفاعل هو
+
+362
+00:31:57,450 --> 00:32:05,460
+أن السالب يلتقى بالموجةأفصل هذا السالب عن الموجة
+
+363
+00:32:05,460 --> 00:32:06,160
+أفصل هذا السالب عن الموجة أفصل هذا السالب عن
+
+364
+00:32:06,160 --> 00:32:06,840
+الموجة أفصل هذا السالب عن الموجة أفصل هذا السالب
+
+365
+00:32:06,840 --> 00:32:08,960
+عن الموجة أفصل هذا السالب عن الموجة أفصل هذا
+
+366
+00:32:08,960 --> 00:32:10,700
+السالب عن الموجة أفصل هذا السالب عن الموجة أفصل
+
+367
+00:32:10,700 --> 00:32:13,040
+هذا السالب عن الموجة أفصل هذا السالب عن الموجة
+
+368
+00:32:13,040 --> 00:32:14,160
+أفصل هذا السالب عن الموجة أفصل هذا السالب عن
+
+369
+00:32:14,160 --> 00:32:14,960
+الموجة أفصل هذا السالب عن الموجة أفصل هذا السالب
+
+370
+00:32:14,960 --> 00:32:16,560
+عن الموجة أفصل هذا السالب عن الموجة أفصل هذا
+
+371
+00:32:16,560 --> 00:32:17,600
+السالب عن الموجة أفصل هذا السالب عن الموجة أفصل
+
+372
+00:32:17,600 --> 00:32:22,100
+هذا السالب عن الموجة أفصل هذا السالب عن الموجة
+
+373
+00:32:22,100 --> 00:32:28,720
+أفصل هذا السالب عن الموجة
+
+374
+00:32:28,720 --> 00:32:28,720
+أفصل هذا
+
+375
+00:32:32,740 --> 00:32:41,100
+في بينهم Carbocation و ال rate تبعتهم بتعتمد على
+
+376
+00:32:41,100 --> 00:32:48,860
+ايش لل A X هاي الخطوة كان بيبين ال nucleophile في
+
+377
+00:32:48,860 --> 00:32:55,860
+الخطوة الأولى ليش مش بيبين لأنه ضعيف لأنه ضعيف لأن
+
+378
+00:32:55,860 --> 00:32:59,320
+ال nucleophile ضعيف ضال يستنى لحد ما تطلع ال CL
+
+379
+00:32:59,320 --> 00:33:00,380
+لواحدة
+
+380
+00:33:06,730 --> 00:33:12,350
+اللي بدفع ال CL تطلع عوامل متعلقة بكل التفاعل لإنه
+
+381
+00:33:12,350 --> 00:33:16,050
+في النهاية لما يكتمل التفاعل بيكون من ناحية energy
+
+382
+00:33:16,050 --> 00:33:21,270
+أفضل، واضح؟ يعني خلّيني أقول القاتي، الكلام اللي
+
+383
+00:33:21,270 --> 00:33:25,370
+بتحكي زملتكوا شوية كلام منطقي إنه يا تورا لو ما
+
+384
+00:33:25,370 --> 00:33:30,090
+حطيناش ال nucleophile لو ما حطيناش ال nucleophile
+
+385
+00:33:30,090 --> 00:33:35,970
+هل ال CL بده تطلع و يجف زي هيك و يقعد يطلع؟لأ، هذه
+
+386
+00:33:35,970 --> 00:33:42,170
+عملية متكاملة بمعنى إنه الـ CL لما بتطلع و بتعمل
+
+387
+00:33:42,170 --> 00:33:45,610
+positive بعدك ال nucleophile .. ال nucleophile لما
+
+388
+00:33:45,610 --> 00:33:50,270
+بده يهاجم على ال positive اتذكر عندي عاملين أنا ..
+
+389
+00:33:50,270 --> 00:33:54,050
+هنا عندي bond breaking .. ال bond breaking شو بده؟
+
+390
+00:33:54,050 --> 00:34:01,860
+بده طاقة .. هذه سؤالك طب و هنا bond formationسواء
+
+391
+00:34:01,860 --> 00:34:05,600
+مع الـ positive أو مع الـ H و ال bond formation
+
+392
+00:34:05,600 --> 00:34:10,800
+بيطلع طاقة وبناء على ذلك هذا التفاعل بيصير الآن لو
+
+393
+00:34:10,800 --> 00:34:15,420
+في مكان ما كانت حسابات الطاقة مش سليمة مايمشيش
+
+394
+00:34:15,420 --> 00:34:19,680
+التفاعل يعني ممكن كتير we can eucleophiles تكون
+
+395
+00:34:19,680 --> 00:34:25,300
+بالمجمل من ناحية الطاقة غير إيجابية و نخلطها و
+
+396
+00:34:25,300 --> 00:34:29,140
+مايمشيش التفاعلواضح؟ التفاعل وقته ايش بيمشي؟ لما
+
+397
+00:34:29,140 --> 00:34:34,200
+يكون من ناحية الطاقة، معقول تعرفوا مرة عليكم أن
+
+398
+00:34:34,200 --> 00:34:40,320
+التفاعل بتحكمه شغلتين أساسيتين، شو هما؟ أنه يكون
+
+399
+00:34:40,320 --> 00:34:45,860
+عندي فاقة طاقة، اتقل الطاقة، هذا عامل ال stability
+
+400
+00:34:45,860 --> 00:34:53,880
+و العامل التاني إيش يكون عنده؟ زيادة فوضة increase
+
+401
+00:34:53,880 --> 00:34:59,740
+in the entropyمتذكرين كان عندكم عشان يمشي التفاعل
+
+402
+00:34:59,740 --> 00:35:03,280
+أخدته معادلة من أهم معادلة الكيميا على الإطلاق
+
+403
+00:35:03,280 --> 00:35:11,410
+Delta G بتساوي Delta H minus D Delta Sو لازم delta
+
+404
+00:35:11,410 --> 00:35:16,870
+J تكون negative عشان تكون negative و يمشي التفاعل
+
+405
+00:35:16,870 --> 00:35:20,770
+أفضل شئ بتكون مع delta H تكون minus بمعنى أن
+
+406
+00:35:20,770 --> 00:35:24,710
+التفاعل يطرد حرارة و أن ال delta S تكون positive
+
+407
+00:35:24,710 --> 00:35:31,150
+أن التفاعل يزيد الفوضى أفضل تفاعل على الإطلاق هو
+
+408
+00:35:31,150 --> 00:35:37,950
+الذي يطرد طاقة و يزيدالفوضى بيعطي جزيئات كتير،
+
+409
+00:35:37,950 --> 00:35:43,150
+واضح؟ اعرفته ليش اليهود بدمروا على الناس دورهم و
+
+410
+00:35:43,150 --> 00:35:48,960
+سياراتهم و ما إلى ذلك؟لأن تفاعل انفجار هو أفضل
+
+411
+00:35:48,960 --> 00:35:53,920
+تفاعل على الإطلاق، مجنون، تفاعل مجنون، بيفقد طاقة
+
+412
+00:35:53,920 --> 00:35:59,560
+كتير، و بطلع جزيئات كتير صغيرة و بعمل فوضى، و عشان
+
+413
+00:35:59,560 --> 00:36:02,640
+هيك ممشي بشكل ممتاز، بتشوفوا كيف الدنيا كلها
+
+414
+00:36:02,640 --> 00:36:06,780
+بتطير، و المادة المتفجرة بتصير غازات، هي المادة
+
+415
+00:36:06,780 --> 00:36:10,820
+المتفجرة بتكون عبارة عن جزيئات، خلّيني أتخيلك
+
+416
+00:36:10,820 --> 00:36:13,940
+صغيرة و كلها مربوطة مع بعض، ما بتصدق إنها بدها
+
+417
+00:36:13,940 --> 00:36:19,310
+إيش؟بدأت تتحرر وتفلت وبعد تحرورها وفلتانها كمان
+
+418
+00:36:19,310 --> 00:36:24,530
+بتطلع طاقة كتير وعشان هي هذا التفاعل بتلاقيه أسهل
+
+419
+00:36:24,530 --> 00:36:28,770
+منه هل الواحد بيولع بابور تحت المادة المتفجرة ولا
+
+420
+00:36:28,770 --> 00:36:34,340
+لحالها؟لحالها بتشيل، ليش؟ لأن فيها الشرطين أنه
+
+421
+00:36:34,340 --> 00:36:41,000
+تفقد طاقة وتزيد الفوضى وهذه أهم معادلة بتحكم سير
+
+422
+00:36:41,000 --> 00:36:44,740
+التفاعلات المفروض أنه أخدتوها ولو كثقافة عامة
+
+423
+00:36:44,740 --> 00:36:48,780
+بكيميا B الـ Delta J لازم تكون negative Delta J
+
+424
+00:36:48,780 --> 00:36:54,400
+Delta H minus T Delta S فاللي بيحكم أنه ليش يكتمل
+
+425
+00:36:54,400 --> 00:36:59,040
+التفاعل ويصيروا حسابات متعلقة بأمرين دائما، إيش
+
+426
+00:36:59,040 --> 00:37:05,580
+هما الأمرين؟الطاقة والانترو بيه اللي معبّر عنهم في
+
+427
+00:37:05,580 --> 00:37:12,040
+المعادلة Delta H و Delta S فما تنسوهوش Delta H و
+
+428
+00:37:12,040 --> 00:37:17,500
+Delta S طبعا أكيد ان انتوا لاحظتوا هنا انه نوعا ما
+
+429
+00:37:17,500 --> 00:37:22,920
+في موازاة حتى لما تدرسوا لازم تكون بالكوا ما بين
+
+430
+00:37:22,920 --> 00:37:28,440
+ال SN1 و ال E1 و ال SN2 و ال E2 في بعض ال aspects
+
+431
+00:37:31,190 --> 00:37:37,130
+حتى نختتم هذا الفصل، بس بيظل عندنا slide أو تنتين
+
+432
+00:37:37,130 --> 00:37:41,550
+معلومات ثقافية عامة، أن الـ Alkaliites هدولة اللي
+
+433
+00:37:41,550 --> 00:37:46,390
+احنا درسنا تفاعلاتهم، فيلهم في واقع الحياة العملية
+
+434
+00:37:46,390 --> 00:37:52,790
+كثير من التطبيقات، بنعرض بعض هناحتى تظهروا أن
+
+435
+00:37:52,790 --> 00:37:56,430
+الكيميا هي جزء من الحياة في مراكبات بيسموها
+
+436
+00:37:56,430 --> 00:37:59,710
+polyhalogenated aliphatic compounds يعني
+
+437
+00:37:59,710 --> 00:38:04,810
+الهالوجنات المتصلة بهالوجن و أحيانا بأكثر من
+
+438
+00:38:04,810 --> 00:38:11,130
+هالوجن من المراكبات اللي استعملها كتير في التطبيق
+
+439
+00:38:11,390 --> 00:38:17,910
+الـ CH3Br الميثيلبروميد هذا الميثيلبروميد الناس
+
+440
+00:38:17,910 --> 00:38:22,530
+الذين .. الزراعيين منكم يعني الأخوات اللي في
+
+441
+00:38:22,530 --> 00:38:26,970
+الجرارة و في بيت لاهيا و ما إلى ذلك بيعرفوا شغلة
+
+442
+00:38:26,970 --> 00:38:34,750
+أن الفلاحين لما بيجهزوا الأرض للزراعة إيش بيرشوها؟
+
+443
+00:38:34,750 --> 00:38:39,700
+بيرشوها غازبيجلبوا الأرض و بيرشوها غاز .. هذا
+
+444
+00:38:39,700 --> 00:38:43,620
+الغاز مثل البروميد .. بيقتل كل الحشرات اللي موجودة
+
+445
+00:38:43,620 --> 00:38:47,200
+في التربة .. قبل ما يزرعها .. قبل ما يزرعها ..
+
+446
+00:38:47,200 --> 00:38:52,100
+بيرشها غاز .. وهذا الغاز بالمناسبة مكلفيعني من
+
+447
+00:38:52,100 --> 00:38:56,540
+فترة صغيرة يعني أحد الفلاحين بيقول ان هو عشان رشده
+
+448
+00:38:56,540 --> 00:39:02,400
+المين دفع حاجة غاز سبعتلاف شكل عشان قبل ما يزرع
+
+449
+00:39:02,400 --> 00:39:08,600
+الفراولة انظف من كل إيش من كل الحشرات الآن حتى
+
+450
+00:39:08,600 --> 00:39:13,120
+نزيدكوا تخاف هذا الغاز له أضرار سلبية كتير وبدأ
+
+451
+00:39:13,120 --> 00:39:19,960
+العالم يسعى نحو منعه بدوا يعملوا مؤتمراتلمنعه ومن
+
+452
+00:39:19,960 --> 00:39:24,940
+أكثر المعارضين لمنعه الولايات المتحدة الأمريكية
+
+453
+00:39:24,940 --> 00:39:28,900
+اللي أنا بدها محصول هي من أكثر المعارضين تطالب
+
+454
+00:39:28,900 --> 00:39:33,900
+العالم أن يمنعه وتطالب بمنحها فترة إضافية أكتر حتى
+
+455
+00:39:33,900 --> 00:39:39,040
+هي تمنعهواضح؟ فيه إله كثير أضرار مثل ال bromide
+
+456
+00:39:39,040 --> 00:39:44,180
+اللي هو ال fumigant أو ال بيقتل الحشرات و الأشياء
+
+457
+00:39:44,180 --> 00:39:47,740
+اللي بتكون في إيش .. في التربة و الفلاحين عندنا
+
+458
+00:39:47,740 --> 00:39:52,300
+بشكل standard بستعملوه يعني قبل كل زرعة فراولة
+
+459
+00:39:52,300 --> 00:39:59,270
+لازم يرشوا التربة كلها غاز و هذا مكلفالـ CH2Cl2
+
+460
+00:39:59,270 --> 00:40:02,730
+اللي هو دايكلوروميثين والـ CHCl3 اللي هو
+
+461
+00:40:02,730 --> 00:40:06,950
+الكلوروفورم هدول عبارة عن organic solvents بنجر
+
+462
+00:40:06,950 --> 00:40:13,950
+فيهم التفاعل الـ CF2CF2 to the N هو عبارة عن ال
+
+463
+00:40:13,950 --> 00:40:18,050
+polymer اللي اسمه التفلون مار عليكم التفلون؟
+
+464
+00:40:19,150 --> 00:40:23,730
+Polymer بلاستيكي يمكن اليوم أكتر إشي بيستعملوه
+
+465
+00:40:23,730 --> 00:40:27,310
+دايما بتقولوا بدنا نشتري تفلون لما بيركبوا
+
+466
+00:40:27,310 --> 00:40:32,330
+المواثير ببعض بتشوفوا هذا الأبيض اللفة الصغيرة
+
+467
+00:40:32,330 --> 00:40:35,010
+البيضة اللي بلفوها حوالين المواثير بدل ما كانوا
+
+468
+00:40:35,010 --> 00:40:41,430
+زمان يستعملوهالشعر أو الخطان هذا اسمه إيش؟ تفلون
+
+469
+00:40:41,430 --> 00:40:45,530
+وموجود منه أنواع كتيرة من ال plastic بمواصفات
+
+470
+00:40:45,530 --> 00:40:49,890
+معينة برضه عبارة عن .. من مركبات ال .. ال
+
+471
+00:40:49,890 --> 00:40:53,650
+alcoholites ال chlorofluorocarbons اللي هم
+
+472
+00:40:53,650 --> 00:40:57,690
+المركبات ال .. ال carbons اللي فيهم chlor و fluor
+
+473
+00:40:57,690 --> 00:41:02,430
+هدولة بختصرهم ب CFC و هذه كلمة كتير بسمعوها في
+
+474
+00:41:02,430 --> 00:41:07,620
+البيئة و دايما بحكوا عنهاالـ Chlorofluorocarbons
+
+475
+00:41:07,620 --> 00:41:13,320
+هذه من أمثلتها غاز لـ Freon-12 هذا Freon-12 اللي
+
+476
+00:41:13,320 --> 00:41:16,820
+هو الغاز اللي بيستعملوه في التبريد في داخل
+
+477
+00:41:16,820 --> 00:41:20,840
+التلاجات نفسه كانوا يحطوه في علاب ال spray عشان
+
+478
+00:41:20,840 --> 00:41:24,340
+تعمل ال spraying جيد علاب العطر و ما إلى ذلك و
+
+479
+00:41:24,340 --> 00:41:28,800
+البوية عشان تعمل ال spraying بيحطوها هي بالنسبة
+
+480
+00:41:28,800 --> 00:41:34,540
+لوضع الأرض inert gases لكن وين مشكلتها؟فى السماء
+
+481
+00:41:34,540 --> 00:41:38,940
+مش فى الأرض مشكلتها لما بتطلع على السماء فى
+
+482
+00:41:38,940 --> 00:41:44,020
+الطبقات العليا مع ال UV light بتكسر من خلال
+
+483
+00:41:44,020 --> 00:41:49,300
+تفاعلات معينة طبقة الأوزون ولذلك الآن بيتكلموا عن
+
+484
+00:41:49,300 --> 00:41:54,140
+الثقوب فى طبقة الأوزونبمر عليكم الثقوب في طبقة
+
+485
+00:41:54,140 --> 00:41:58,600
+الأوزون الآن الثقوب في طبقة الأوزون العلماء
+
+486
+00:41:58,600 --> 00:42:00,640
+بيرجحوا أن هو بشكل أساسي جاي من ال
+
+487
+00:42:00,640 --> 00:42:06,000
+chlorofluorocarbons ولذلك اليوم صناعيا التلاجات
+
+488
+00:42:06,000 --> 00:42:11,500
+بيحاولوا يعملوها بنظم غير غاز لفريون ال spraying
+
+489
+00:42:11,500 --> 00:42:18,280
+بيحاولوا يقللوه يعني بأذكر مرة يمكن قبل ما تموت
+
+490
+00:42:18,280 --> 00:42:24,910
+الأميرة دياناالـ Lady Diana جابوها بتجيب إجزازة
+
+491
+00:42:24,910 --> 00:42:28,410
+ريحة و بتكوب على إيدها كاب بدل ما تعمل ال spraying
+
+492
+00:42:28,410 --> 00:42:34,270
+حتى يقولوا للعالم إن ال spraying هذا بيطلع أشياء
+
+493
+00:42:34,270 --> 00:42:38,870
+بتضر بالبيئة أو بتضر بطبقة الأوزون يعني ممكن الناس
+
+494
+00:42:38,870 --> 00:42:42,930
+يستعملوا ريحة عادي هيك يحطوه على إيدهم أفضل من أن
+
+495
+00:42:42,930 --> 00:42:46,890
+كل البشر قاعدين يعملوا spraying و ال spraying هذا
+
+496
+00:42:46,890 --> 00:42:54,120
+إيش بيعمل؟بيعمل تدمير لطبقة الأوزون طبعا انكمل
+
+497
+00:42:54,120 --> 00:42:59,240
+تدمير طبقة الأوزون ايش بيزيد عندنا؟ بيزيد الاحتباس
+
+498
+00:42:59,240 --> 00:43:02,140
+الحراري طب ايش مشكلة الاحتباس الحراري الأساسية
+
+499
+00:43:02,140 --> 00:43:09,140
+علينا؟ ايش بيتبع زيادة درجات الحرارة؟ و ايش بيتبع
+
+500
+00:43:09,140 --> 00:43:12,640
+دوبان الجليد؟
+
+501
+00:43:13,820 --> 00:43:20,060
+غرق كثير من المدن مدن أساسية في العالم اللي راح
+
+502
+00:43:20,060 --> 00:43:24,000
+على أوروبا وما إلى ذلك سيعرف أن دول كاملة ممكن
+
+503
+00:43:24,000 --> 00:43:33,080
+تغرق واضح؟ طبعا ليش بدها تغرق؟ الموضوع بسيط جدا لو
+
+504
+00:43:33,080 --> 00:43:37,000
+أنتوا تخيلتوا أن هنا عندكم جبل من الجليد وهذا في
+
+505
+00:43:37,000 --> 00:43:41,540
+المناطق القطبية وثابت ثابت جبل الجليد مافيش عليه
+
+506
+00:43:41,540 --> 00:43:47,040
+أي مشكلةو أنا عندكم بهذا الشكل نوعا ما سهل و أنا
+
+507
+00:43:47,040 --> 00:43:52,880
+في مدينة زي أمستردام والناس عايشين والجليد هذا
+
+508
+00:43:52,880 --> 00:43:56,820
+معلق على الجبل عمره ما بنزل متجمد الآن لو أنا رفعت
+
+509
+00:43:56,820 --> 00:44:04,040
+الحرارة مجرد ما صار مية مش انهيار مش انهيار ايش
+
+510
+00:44:04,040 --> 00:44:04,740
+الكلمة؟
+
+511
+00:44:07,250 --> 00:44:12,010
+انصهار كثير ناس متعودين يقولوا ذوبان الجليد
+
+512
+00:44:12,010 --> 00:44:16,490
+الذوبان مادة في مادة الجليد دايما استعملوله انصهار
+
+513
+00:44:16,490 --> 00:44:23,190
+واضح انصهار مش ذوبان لما يصير مياه شو هيعمل في متل
+
+514
+00:44:23,190 --> 00:44:27,310
+هذه المدن؟ هيغرقها هذا المشكلة ان الجليد هو صلب
+
+515
+00:44:27,310 --> 00:44:32,270
+يبقى على رأس الجبلبيضلوا على رأس الجبل مافيش عندكم
+
+516
+00:44:32,270 --> 00:44:35,310
+اي مشكلة هذه تجربة روحوا اعملوها في البيت عندكم
+
+517
+00:44:35,310 --> 00:44:39,850
+هاتوا جوالب تلج كبيرة اعملوها و حطوها جانب حوض
+
+518
+00:44:39,850 --> 00:44:44,070
+المغسلة و الحوض ناشف مافيش فيه ولا شغلة طولها من
+
+519
+00:44:44,070 --> 00:44:48,890
+الجامدة بتضلها عاملة زي الجبل و ثابتة مكانها
+
+520
+00:44:48,890 --> 00:44:56,510
+ارتفعت الحرارة شوية صارت ميهإيه بتنزل؟ بتغرق
+
+521
+00:44:56,510 --> 00:45:01,110
+الحوت، مظبوط ولا لأ؟ وهذه اللي هي الإشكالية أنه في
+
+522
+00:45:01,110 --> 00:45:04,870
+دول كاملة منخفضة، هولندا شو بيسموها؟ Netherlands،
+
+523
+00:45:04,870 --> 00:45:11,430
+الأرض المنخفضة، فدول كاملة ممكن تغرق لو هذه الشغلة
+
+524
+00:45:11,430 --> 00:45:17,900
+بتزيد، دول كاملة ممكن تغرق لو هذه الشغلة بتزيدأخر
+
+525
+00:45:17,900 --> 00:45:24,040
+شغلة في عندكم من المركبات اللي فيها halogens يعني
+
+526
+00:45:24,040 --> 00:45:28,100
+كربون و معبروم و chlorofluor أشياء كتيرة بيسموها
+
+527
+00:45:28,100 --> 00:45:33,280
+ال halons ال halons هذه عبارة عن bromine
+
+528
+00:45:33,280 --> 00:45:36,980
+containing chlorofluorocarbons they are called
+
+529
+00:45:36,980 --> 00:45:41,520
+halons and are used to extinguish fire بيستعملهم
+
+530
+00:45:41,520 --> 00:45:45,460
+في الطفايات بتعرفوا طفاية ال halon الطفايات اللي
+
+531
+00:45:45,460 --> 00:45:50,510
+بتكون عليهاالإشارة الخضراء وغالبا هذه طفيات
+
+532
+00:45:50,510 --> 00:45:55,170
+الهالونز لأن هؤلاء غازات خاملة لما يكون عنده مورشة
+
+533
+00:45:55,170 --> 00:45:59,530
+بصلح أجهزة كهربائية ما إلى ذلك لو صار عنده حريقة
+
+534
+00:45:59,530 --> 00:46:04,390
+لا يفضل أنه يجيب مية و يطف يعني لو افترضنا واحد
+
+535
+00:46:04,390 --> 00:46:07,570
+بيصلح تلفزيون كبير و ما إلى ذلك متوقع يصير عنده
+
+536
+00:46:07,570 --> 00:46:12,650
+حريقةبيحط جنبه طفاية ميه لو حط طفاية ميه و كبها
+
+537
+00:46:12,650 --> 00:46:18,110
+الميه على الجهاز مع الكهربا اللي موجودة و حتى لو
+
+538
+00:46:18,110 --> 00:46:21,190
+مافيش كهربا بتخرب كل مكونات الجهاز لكن هو بتجيب
+
+539
+00:46:21,190 --> 00:46:26,790
+طفاية الغاز ال halon بعص بتعمل منع لل أكسوجين عن
+
+540
+00:46:26,790 --> 00:46:32,050
+النار بتطفيها بعد هيك كله بيروحما خربش الجهاز عنده
+
+541
+00:46:32,050 --> 00:46:35,990
+فهذه الطفيات طفيات ال halons ويلها أرقام بيعرفوها
+
+542
+00:46:35,990 --> 00:46:40,130
+تعون الاطفايات لإطفاء الحرائق بالذات المتعلقة
+
+543
+00:46:40,130 --> 00:46:46,790
+بالأجهزة الكهربائية بهيك تقريبا بنأمل أن أعطيناكوا
+
+544
+00:46:46,790 --> 00:46:50,190
+فكرة عن ال alkyl halides وإن شاء الله الحصة
+
+545
+00:46:50,190 --> 00:46:53,650
+القادمة بنبدأ في موضوع جديد
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik.srt
new file mode 100644
index 0000000000000000000000000000000000000000..58ce7d3764ace82b21de57e15be80cf13330ee76
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik.srt
@@ -0,0 +1,1975 @@
+1
+00:00:05,620 --> 00:00:12,680
+موضوع الalkanes موضوع واسع، واسع كثير ويمكن
+
+2
+00:00:12,680 --> 00:00:18,420
+بتلاحظوا مقارنة في الـ .. في الalkanes لما حكينا
+
+3
+00:00:18,420 --> 00:00:21,380
+عن التفاعل .. التفاعلات بتاعتنا تقولنا الalkanes
+
+4
+00:00:21,380 --> 00:00:27,130
+inner وحكينا تفاعلات بعشر دقائق وربع ساعة وسكرنا 
+
+5
+00:00:27,130 --> 00:00:31,610
+بينما الalkanes they are very reactive يعني هي
+
+6
+00:00:31,610 --> 00:00:37,670
+ثالث محاضرة واحنا بنشرح تفاعلات الalkanes
+
+7
+00:00:37,670 --> 00:00:41,450
+واضح؟ فتفاعلاتها كثيرة الحقيقة they are reactive
+
+8
+00:00:42,470 --> 00:00:48,350
+أخذنا طبعًا على الالكينز تفاعلات الإضافة سواء
+
+9
+00:00:48,350 --> 00:00:52,150
+إضافة أشياء متماثلة أو إضافة أشياء غير متماثلة
+
+10
+00:00:52,150 --> 00:00:57,590
+إضافة الهيدروجين إضافة البروم إضافة الماء إضافة ال
+
+11
+00:00:57,590 --> 00:01:05,680
+HPR تكوين الepoxides تكسير الepoxides واضح؟ هي
+
+12
+00:01:05,680 --> 00:01:09,320
+هذا تقريبًا الكلام اللي أخذناه الآن اليوم موضوعنا 
+
+13
+00:01:09,320 --> 00:01:14,540
+formation of diols تحديدا 1,2-diols معنى all
+
+14
+00:01:14,540 --> 00:01:20,220
+المركب اللي فيه OH الكحول زي ميثانول إيثانول
+
+15
+00:01:20,220 --> 00:01:26,100
+بروبانول فيه OH فالمجموعة الواضحة في الكحول هي
+
+16
+00:01:26,100 --> 00:01:31,140
+مجموعة إيش الall لما يكون عندي diols معنى ذلك
+
+17
+00:01:31,140 --> 00:01:37,750
+مركبات فيها OH مش واحدة OH واضح؟ لما بنقول
+
+18
+00:01:37,750 --> 00:01:43,570
+1,2-diols معناه ذلك مجموعة OH جنب بعض مجموعة 
+
+19
+00:01:43,570 --> 00:01:49,250
+.. مجموعة OH جنب بعض الآن خليكم منتبهين معي مش
+
+20
+00:01:49,250 --> 00:01:54,370
+ضروري أن يكون معنى 1,2-diols أن مجموعة OH
+
+21
+00:01:54,830 --> 00:01:58,750
+واحدة منهم على موقع واحد وواحدة منهم على موقع
+
+22
+00:01:58,750 --> 00:02:02,750
+اثنين لا لا ما فيش علاقة دائمًا لما بنقول 1,2-
+
+23
+00:02:02,750 --> 00:02:06,850
+diols أو مثلًا نقول 1,2-addition معنى ذلك
+
+24
+00:02:06,850 --> 00:02:10,730
+المجموعتين جايات جنب بعض بمعنى ممكن يكونوا اثنين و
+
+25
+00:02:10,730 --> 00:02:14,790
+ثلاثة ولا بعض ممكن يكونوا ثلاثة وأربعة ممكن
+
+26
+00:02:14,790 --> 00:02:18,510
+يكونوا أربعة وخمسة مش إلزام أن كلمة 1,2-
+
+27
+00:02:18,510 --> 00:02:23,400
+diols أن المجموعتين يكونوا إيشو واحد واثنين يعني
+
+28
+00:02:23,400 --> 00:02:26,680
+مثلًا لو حطيت هنا ثلاث ذرات وهي كمان ذرتين وكمان
+
+29
+00:02:26,680 --> 00:02:31,720
+ثلاث ذرات كده المجموعة ثمانية ثلاثة أنكوا حاطين
+
+30
+00:02:31,720 --> 00:02:35,840
+ثلاث كربونات وبعدين أربعة خمسة ستة سبعة ثمانية و
+
+31
+00:02:35,840 --> 00:02:43,420
+جيت وقولتلُكم 4,5-dihydroxy مثلا octane is
+
+32
+00:02:43,420 --> 00:02:49,980
+an example of a 1,2-diol واضح؟ هو مثال على 1,2-
+
+33
+00:02:49,980 --> 00:02:54,380
+diol بمعنى أن المجموعتين موجودات على موقعين
+
+34
+00:02:54,380 --> 00:02:59,460
+متتاليين، هاي معنى كلمة 1,2-diol مش معناها أنه
+
+35
+00:02:59,460 --> 00:03:05,670
+تحديدًا في الجزء على موقع واحد وعلى موقع اثنين بنحصل 
+
+36
+00:03:05,670 --> 00:03:10,730
+عليهم بطريقتين من خلال two different reagents ال
+
+37
+00:03:10,730 --> 00:03:16,010
+reagent الأول الOsmium Oxide Osmium O4 وال
+
+38
+00:03:16,010 --> 00:03:21,350
+Osmium هو معدن من المعادن الثقيلة بالعكس هو تقريبًا
+
+39
+00:03:21,350 --> 00:03:27,590
+أثقل معدن يعني بكثافة تقريباً 21 وكسر
+
+40
+00:03:27,590 --> 00:03:35,570
+تقريبًا جرام لكل سنتيمتر مكعب واضح؟ يعني لو كنتوا
+
+41
+00:03:35,570 --> 00:03:40,210
+بتكونوا .. تحمله لتر منه .. لو كنتوا بتكونوا تحمله
+
+42
+00:03:40,210 --> 00:03:43,750
+لتر منه، معناه ذلك هذا اللتر بدي يكون وزنه
+
+43
+00:03:43,750 --> 00:03:49,350
+واحد وعشرين كيلو جرام، لاحظوا لتر الميه كام
+
+44
+00:03:49,350 --> 00:03:55,050
+وزنه؟ كيلو جرام واحد، مظبوط ولا لا؟ لتر الزئبق،
+
+45
+00:03:55,050 --> 00:03:58,730
+كذاش وزنه؟ كثير مر عليكم 
+
+46
+00:04:01,880 --> 00:04:07,200
+13.6 الكثافة، كثافة الزئبق، يعني لتر
+
+47
+00:04:07,200 --> 00:04:13,260
+الزئبق 13.6 كيلو جرام، لتر الذهب،
+
+48
+00:04:13,260 --> 00:04:20,360
+المفروض تعرفوه، حوالي 20 كيلو جرام واضح؟ عشان
+
+49
+00:04:20,360 --> 00:04:24,520
+هيك لما .. زمان كنتوا بتقرأوا في القصص أنه الصياد
+
+50
+00:04:24,520 --> 00:04:31,820
+مثلًا لقى جرة والجرة فيها ملانة ذهب فحملها فرحًا و
+
+51
+00:04:31,820 --> 00:04:35,320
+حاطط له هيك حامل الجرة ومروح هو لو عنده جرة الذهب
+
+52
+00:04:35,320 --> 00:04:41,040
+فيها 20 كيلو جرام، كده بده يكون وزن الجرة؟
+
+53
+00:04:41,040 --> 00:04:45,520
+20 في 20؟ 400 كيلو جرام، مين بيقدر يحمل
+
+54
+00:04:45,520 --> 00:04:50,290
+400 كيلو جرام هيك بين إيديه ويروح؟ اللي جابنا
+
+55
+00:04:50,290 --> 00:04:54,470
+لها الكلام أن لما تمر عليكم الشغلات مرات تبهدلوا
+
+56
+00:04:54,470 --> 00:04:58,430
+ال Osmium O4 تقريبًا أثقل المعادل لو أخذنا هذا
+
+57
+00:04:58,430 --> 00:05:01,730
+ال Osmium O4 مع Sodium Hydrogen Sulphide في وجود
+
+58
+00:05:01,730 --> 00:05:07,590
+الماء بيعملوا إضافة مجموعتين OH والإضافة بتكون من
+
+59
+00:05:07,590 --> 00:05:11,450
+جهة واحدة syn addition سبق إن حكينا لكم زي من جهة
+
+60
+00:05:11,450 --> 00:05:16,090
+واحدة هذه إيش syn addition من جهتين متعاكستين anti
+
+61
+00:05:16,090 --> 00:05:20,670
+addition في عندي syn addition وفي عندي anti
+
+62
+00:05:20,670 --> 00:05:24,950
+addition اتذكروا لما أخذنا إضافة الهيدروجين قولنا
+
+63
+00:05:24,950 --> 00:05:28,310
+الهيدروجين addition is syn addition لما أخذنا
+
+64
+00:05:28,310 --> 00:05:33,070
+إضافة البرومين البرومين addition is anti addition
+
+65
+00:05:33,070 --> 00:05:38,990
+الآن إضافة مجموعتي الOH من خلال الOsmium O4 في
+
+66
+00:05:38,990 --> 00:05:43,250
+وجود الSodium Hydrogen Sulphide أو من خلال
+
+67
+00:05:43,250 --> 00:05:49,080
+التفاعل مع الPotassium Permanganate  في basic
+
+68
+00:05:49,080 --> 00:05:54,360
+medium في OH− بيعملي syn addition بيضيف
+
+69
+00:05:54,360 --> 00:05:59,840
+المجموعتين ومن جهة واحدة مرات كثير .. مرات كثير
+
+70
+00:05:59,840 --> 00:06:03,340
+أنتم لما بتكونوا تحفظوا وبتكونوا تكملوا معادلات
+
+71
+00:06:03,340 --> 00:06:06,960
+بتاخدوا double bond وبتحفظوا هنا كلمة KMnO4 و
+
+72
+00:06:06,960 --> 00:06:12,460
+بتقولوا بتحط مجموعتين الحقيقة هنا لا بديّاكوا تنتبهوا
+
+73
+00:06:12,460 --> 00:06:18,760
+الKMnO4 بتتفاعل بطريقتين مختلفتين تمامًا في وجود
+
+74
+00:06:18,760 --> 00:06:24,560
+الbasic medium OH− بتعطي مجموعتين OH على جهة
+
+75
+00:06:24,560 --> 00:06:28,320
+واحدة بعد شوية إن شاء الله في المحاضرة هذه هناخد
+
+76
+00:06:28,320 --> 00:06:35,130
+أن في وجود H+ الحامض بتكسر الالكين بطريقة معينة
+
+77
+00:06:35,130 --> 00:06:39,250
+فما بديش أحفظ التفاعل أن تفاعل الالكين مع الPotassium 
+
+78
+00:06:39,250 --> 00:06:47,110
+Permanganate  لا بدي أحفظ أن تفاعل الالكين مع الPotassium Permanganate  in
+
+79
+00:06:47,110 --> 00:06:51,570
+basic medium في وجود الOH− لأن بعد شوية في وجود
+
+80
+00:06:51,570 --> 00:06:57,970
+الH+ هتعطيكوا تفاعل مختلف تمامًا واضح هدول ال
+
+81
+00:06:57,970 --> 00:07:02,110
+two reagents اللي بيكونولي 1,2-diol وزي ما
+
+82
+00:07:02,110 --> 00:07:08,770
+اتفقنا أن الaddition is syn addition بمعنى إضافة
+
+83
+00:07:08,770 --> 00:07:14,090
+من جهة واحدة طبعًا اللي بيخلي الaddition تكون syn
+
+84
+00:07:14,090 --> 00:07:18,990
+addition لو أخذنا كمثال الPotassium Permanganate  في الPotassium Permanganate 
+
+85
+00:07:18,990 --> 00:07:26,050
+المنجنيز متصل بأربع ذرات أكسجين واضح وهيجوا اثنتين
+
+86
+00:07:26,050 --> 00:07:29,730
+منهم يتفاعلوا الآن هل من الممكن يعني لو تخيلتوا 
+
+87
+00:07:29,730 --> 00:07:32,150
+أن هاي مثلًا هنا المنجنيز في الcenter هاي واحد
+
+88
+00:07:32,150 --> 00:07:35,930
+اثنين ثلاثة أربعة نفترض هل من الممكن أن أنا أقدر
+
+89
+00:07:35,930 --> 00:07:40,350
+أضيف زي هيك من جهتين مختلفتين طالما كلهم مربطين
+
+90
+00:07:40,350 --> 00:07:44,790
+بذرة مركزية يعني لما نكون عند MnO4 هاي
+
+91
+00:07:44,790 --> 00:07:48,650
+المنجنيز في النص وهاي الMnO4 وبدي أضيف
+
+92
+00:07:48,650 --> 00:07:53,780
+اثنتين منهم بدهم ييجوا يضيفوا بهذا الشكل هل ممكن أن
+
+93
+00:07:53,780 --> 00:07:57,140
+واحد أضيف من هنا والثانية من وراه فلأن كلهم
+
+94
+00:07:57,140 --> 00:08:02,360
+مرتبطين الأربع ذرات أكسجين بالمنجنيز بيضيفوا 
+
+95
+00:08:02,360 --> 00:08:07,700
+اثنتين منهم من جهة واحدة فبيعطينا الsyn addition
+
+96
+00:08:07,700 --> 00:08:11,500
+عشانك لو كان عندي Cyclohexane ولا Cyclobutane ولا
+
+97
+00:08:11,500 --> 00:08:15,640
+Cyclooctane وبدي أرسم الاتجاه تبعهم لاحظوا ال
+
+98
+00:08:15,640 --> 00:08:19,140
+stereo chemistry الشكل بالفراغ الاثنتين يا بيكونوا
+
+99
+00:08:19,140 --> 00:08:22,960
+لقدام يا بيكونوا لورا في الحالتين هذا يعتبر نفس
+
+100
+00:08:22,960 --> 00:08:26,200
+المركب في هذه الحالة اللي هو syn addition بس
+
+101
+00:08:26,200 --> 00:08:31,820
+ما بيكونش واحدة لقدام واحدة لورا اللي هو anti
+
+102
+00:08:31,820 --> 00:08:37,980
+addition .. اللي هو anti addition لو هنا قلنا لكم
+
+103
+00:08:37,980 --> 00:08:42,760
+أكمل المعادلات موضوع سهل هيضاف الbond مع ال
+
+104
+00:08:42,760 --> 00:08:47,640
+Osmium O4 لاحظوا مجموعتي الOH كيف رسمناهم على
+
+105
+00:08:47,640 --> 00:08:51,920
+جهة واحدة عملنا syn addition Cyclopentane مثلًا
+
+106
+00:08:51,920 --> 00:08:56,220
+بالPotassium Permanganate  in basic medium أنتم لاحظين كلمة ال
+
+107
+00:08:56,220 --> 00:09:00,080
+basic medium برضه إضافة مجموعتي الOH من جهة
+
+108
+00:09:00,080 --> 00:09:08,280
+واحدة هنا بدكم تتذكروا أن هذا ليس أول مرة نأخذ فيها
+
+109
+00:09:08,280 --> 00:09:13,040
+احنا تكوين ال1,2-diol المحاضرة الماضية أخذنا
+
+110
+00:09:13,040 --> 00:09:17,800
+تكوين 1,2-diol من خلال أن احنا من الالكين بداية 
+
+111
+00:09:17,800 --> 00:09:23,080
+عملنا الepoxide بعد هيك الepoxide بإضافة الماء
+
+112
+00:09:23,080 --> 00:09:29,440
+في وجود الحامض كان بيفتحه بهذا الشكل متذكرين؟ الـ
+
+113
+00:09:29,440 --> 00:09:34,800
+لما هذا المكان العلوي كله مسكر .. مسكر بوجود ال
+
+114
+00:09:34,800 --> 00:09:40,960
+oxygen الماء مضطرة تيجي من وين؟ من اتجاه المعاكس،
+
+115
+00:09:40,960 --> 00:09:45,800
+مظبوط ولا لا؟ من عند وين؟ اتجاه المعاكس، من عند
+
+116
+00:09:45,800 --> 00:09:51,450
+فصل القاسم، وبناءً على ذلك ماشي بتعمل؟ اثنتين OH
+
+117
+00:09:51,450 --> 00:09:57,150
+بأي mode of addition anti addition واضح؟ إذا لو
+
+118
+00:09:57,150 --> 00:10:00,890
+أنا إجيت لأني جبتلكوا السؤال وقولتلُكم حضرولي ال
+
+119
+00:10:00,890 --> 00:10:07,410
+1,2-diol ب syn addition في عندكم الطريقة Potassium Permanganate  أو
+
+120
+00:10:07,410 --> 00:10:10,510
+في basic medium أو Osmium tetroxide لو قولتلكوا 
+
+121
+00:10:10,510 --> 00:10:18,350
+بديّاه في الanti addition من نفس الالكين أول إيش
+
+122
+00:10:18,350 --> 00:10:24,400
+من الالكين بدا نكون الepoxide كيف كنا نكونه الكين
+
+123
+00:10:24,400 --> 00:10:29,120
+بير أسيد بيعطينا الepoxide بعدين الepoxide بنعمله
+
+124
+00:10:29,120 --> 00:10:35,180
+ring opening اللي هو فتح الحلقة في وجود H+ H2O
+
+125
+00:10:35,180 --> 00:10:41,680
+بتفتح وبيعطينا الanti-addition الآن هذا التفاعل
+
+126
+00:10:41,680 --> 00:10:47,820
+الثاني للالكين مع الKMnO4 اللي أنا قولتلكم بيعمل
+
+127
+00:10:49,240 --> 00:10:54,880
+تكسير للـDouble Bond هذا التفاعل اللي بالـAcidic
+
+128
+00:10:54,880 --> 00:11:01,920
+Medium Oxidation of Alkenes by Acidic MnO4− لو
+
+129
+00:11:01,920 --> 00:11:05,520
+إحنا إجينا عملنا .. خلّيني أنظر في الأول المعادلة
+
+130
+00:11:05,520 --> 00:11:10,460
+اللي تحت إحنا إجينا عملنا Oxidation لالكين بالـ
+
+131
+00:11:10,460 --> 00:11:15,080
+MnO4 في وجود الحامض بيكسر الـDouble Bond اللي
+
+132
+00:11:15,080 --> 00:11:21,140
+موجود هنا من النص بيكسرها من النص هذه تخليها C
+
+133
+00:11:21,140 --> 00:11:25,460
+Double Bond O وهذه تخليها C Double Bond O يعني
+
+134
+00:11:25,460 --> 00:11:29,060
+عندما أعمل الناتج ببساطة بدي أكسر هذه من النص
+
+135
+00:11:29,060 --> 00:11:34,460
+يصير عندي RCR وهذا C Double Bond O وRCR وC Double
+
+136
+00:11:34,460 --> 00:11:39,160
+Bond O بهذا الشكل الPotassium Permanganate  بيكسر الDouble Bond
+
+137
+00:11:39,160 --> 00:11:46,260
+واضح؟ الآن هذا الكسر هذا الكسر للDouble Bond هو
+
+138
+00:11:46,260 --> 00:11:51,860
+أول خطوة في التفاعل إذا كانت المجموعات هذه R كلها
+
+139
+00:11:51,860 --> 00:11:58,440
+بمعنى مثل إيثيل بروبيل بيوتيل أيًّا كانت يقف التفاعل
+
+140
+00:11:58,440 --> 00:12:03,660
+بهذا الشكل يعني بس بتعملوا الكسر ثم يقف التفاعل
+
+141
+00:12:03,660 --> 00:12:08,160
+واضح طب إيش في احتمال على أيّ كربونة أن يكون غير
+
+142
+00:12:08,160 --> 00:12:15,860
+الـR والـR ممكن يكون عندي H وH أو R وR أو
+
+143
+00:12:15,860 --> 00:12:22,500
+الاحتمال الثالث مين بدها تحكي لنا يا أو R أو H 100%
+
+144
+00:12:22,500 --> 00:12:31,200
+واضح يا بدها يكون عندي H وH أو R وR أو R وH إذا
+
+145
+00:12:31,200 --> 00:12:36,120
+كان عندي المجموعات R وR بتتم كسر لتن تن C Double
+
+146
+00:12:36,120 --> 00:12:43,930
+Bond O ولا يحصل أي تفاعل إضافي إذا كان عندي H وH
+
+147
+00:12:43,930 --> 00:12:48,790
+بيصير عندي C Double Bond O وحملة H وH في الخطوة
+
+148
+00:12:48,790 --> 00:12:52,990
+الأولى الPotassium Permanganate  هذا المركب بيأكسد وإضافة
+
+149
+00:12:52,990 --> 00:12:59,150
+بيطلعوا إيش في الآخر ثاني أكسيد كربون واضح إيش
+
+150
+00:12:59,150 --> 00:13:05,630
+بيطلعوا ثاني أكسيد كربون إذا لو عندي أنا CH2 شو
+
+151
+00:13:05,630 --> 00:13:09,490
+الناتج تبعها اللي بدها تتكون عندي ثاني أكسيد كربون
+
+152
+00:13:09,490 --> 00:13:20,270
+واضح طيب لو عندي RCH بدا تصير R C Double Bond O H
+
+153
+00:13:20,270 --> 00:13:25,150
+في الخطوة الأولى هذا الديهيد بيأكسد الPotassium Permanganate 
+
+154
+00:13:25,150 --> 00:13:33,550
+بخطوة إضافية بيخليه حامض واضح فالCH2 بتصير CO2
+
+155
+00:13:45,300 --> 00:13:52,260
+والـRCR بيبقى زي ما هي R C Double Bond O R واضح
+
+156
+00:13:52,260 --> 00:13:57,860
+إذا أنتم لو أتياكم أيّ مركب وبدنا نعمله تكسير في
+
+157
+00:13:57,860 --> 00:14:01,440
+الKMnO4 صح احنا عارفين أن بالخطوة الأولى بدنا
+
+158
+00:14:01,440 --> 00:14:04,700
+نعمل C Double Bond O وC Double Bond O هذا كلام
+
+159
+00:14:04,700 --> 00:14:09,360
+ما فيش عليه خلاف لكن بيصير عندي further oxidation
+
+160
+00:14:09,360 --> 00:14:14,920
+يعني تأكسد إضافي لأن الKMnO4 عامل مؤكسد قوي إيش
+
+161
+00:14:14,920 --> 00:14:19,980
+تأكسد الإضافة أيّ CH2 النتيجة النهائية بتاعتها إيش
+
+162
+00:14:19,980 --> 00:14:29,800
+بتكون؟ CO2 RCH النتيجة النهائية بتاعتها RCOOH
+
+163
+00:14:29,800 --> 00:14:36,980
+وRCR بظل زي ما هي RCOOR فلو جيبنا لكوا أيّ خلية 
+
+164
+00:14:36,980 --> 00:14:40,540
+من هذه المركبات يعني مثلًا لو هذا المركب اللي
+
+165
+00:14:40,540 --> 00:14:44,980
+رسمناه كنا حاطين هنا R وR وحاططين لكوا من Potassium Permanganate 
+
+166
+00:14:44,980 --> 00:14:45,640
+O4
+
+167
+00:14:50,300 --> 00:14:55,520
+هتكسروا إلى جزئين هذا الجزء الأول شو هيعمل هيظل
+
+168
+00:14:55,520 --> 00:15:09,040
+زي ما هو R C Double Bond O R والجزء الثاني R C
+
+169
+00:15:09,040 --> 00:15:15,800
+Double Bond O OH واضح بهذا الشكل
+
+170
+00:15:28,220 --> 00:15:37,280
+الآن شغلة إضافية الالكينز نفسها ممكن تتكسر تكسير
+
+171
+00:15:37,280 --> 00:15:43,900
+شبيه باستعمال الأوزون بتعرفوا الأوزون اللي بنسميه
+
+172
+00:15:43,900 --> 00:15:48,3
+
+201
+00:18:28,440 --> 00:18:33,680
+بس كسرتها من النصف هاد الـ CH2 شو بتصير CH2C double
+
+202
+00:18:33,680 --> 00:18:40,660
+bond O فكأنه .. كأنه هنا الأوزون عامل مؤكسد أضعف
+
+203
+00:18:40,660 --> 00:18:45,500
+من إيش الـ camon O4 بمعنى بس بيكسر الـ double bond
+
+204
+00:18:45,500 --> 00:18:53,180
+للتنتين C double bond O وبعد هيك وبعد هيك ما بعملش
+
+205
+00:18:53,180 --> 00:18:59,440
+إيش إضافي الـ camon O4 بعمل شغل إضافي، واضح الكلام؟
+
+206
+00:18:59,440 --> 00:19:04,660
+هذا نتيجة التكثُر اللي بنسميه احنا ozonolysis و ash
+
+207
+00:19:04,660 --> 00:19:08,180
+of alkanes طبعًا بيمر عبر intermediate مش كثير
+
+208
+00:19:08,180 --> 00:19:10,460
+احنا مهتمين بتفاصيلها
+
+209
+00:19:14,620 --> 00:19:19,520
+هنا في عندي أمثلة مختلفة .. أمثلة مختلفة ممكن
+
+210
+00:19:19,520 --> 00:19:25,060
+نتطلع عليها بسرعة، المثال الأول هو ozonolysis،
+
+211
+00:19:25,060 --> 00:19:28,520
+ozone و رمرة واحد و رمرة اتنين zinc في وجود
+
+212
+00:19:28,520 --> 00:19:33,020
+الحامض، إيش اللي بدنا نعمله؟ بدنا نأخذ المركب زي ما
+
+213
+00:19:33,020 --> 00:19:40,100
+هو C double bond O و C double bond O المثال التالي
+
+214
+00:19:40,100 --> 00:19:44,300
+نفس الشيء والتالت والرابع بس طبعًا المثال الثالث
+
+215
+00:19:44,300 --> 00:19:47,000
+عشان الـ double bond في داخل حلقة وكذلك الرابع
+
+216
+00:19:47,000 --> 00:19:50,460
+بتفتح الحلقة يعني بيصير عندي C double bond O و C
+
+217
+00:19:50,460 --> 00:19:56,060
+double bond O بيصير عندي ring opening ملاحظين كيف
+
+218
+00:19:56,060 --> 00:20:00,340
+الحلقة فتحت من هنا في نهاية كل double bond بتصير
+
+219
+00:20:02,190 --> 00:20:07,770
+وهل الـ ozone بيعمل further oxidation لأ لما يكون
+
+220
+00:20:07,770 --> 00:20:12,130
+عنده H بيبقى H لو كانت CH2 بيبقى CH2 وما بيعمل الـ
+
+221
+00:20:12,130 --> 00:20:14,210
+ozone further oxidation
+
+222
+00:20:19,320 --> 00:20:25,280
+بنجي لـ مثال إضافي على الـ alkanes لكن هنا إحنا
+
+223
+00:20:25,280 --> 00:20:30,760
+بناخد نوع من الـ alkanes مش double bond واحدة فيه،
+
+224
+00:20:30,760 --> 00:20:35,440
+فيه اثنتين، واضح؟
+
+225
+00:20:35,440 --> 00:20:40,380
+الآن لو قلنا إن إحنا عندنا اثنتين double bonds،
+
+226
+00:20:40,380 --> 00:20:48,850
+بدّه يصير المركب بدل ما هو alkanes بدّه يصير واضح؟
+
+227
+00:20:48,850 --> 00:20:54,070
+إذا إن أنا في عندي in double bond واحدة, die in
+
+228
+00:20:54,070 --> 00:20:57,630
+two double bonds, tri in ..
+
+229
+00:21:07,440 --> 00:21:28,020
+ثلاثة double bonds
+
+230
+00:21:28,020 --> 00:21:32,910
+وهكذا تنفصل بـ double bond يعني يكون عندي double
+
+231
+00:21:32,910 --> 00:21:39,060
+single double إذا ممكن يكون عندي double double أو
+
+232
+00:21:39,060 --> 00:21:43,900
+double single double أو أكون بين الـ two double
+
+233
+00:21:43,900 --> 00:21:49,160
+bonds أكثر من واحدة اثنتين ثلاث أربع كله بيصير
+
+234
+00:21:49,160 --> 00:21:53,420
+نفس الشيء يعني يكون عندي double bond single كمان
+
+235
+00:21:53,420 --> 00:21:57,260
+single واحدة أو اثنتين أو ثلاث أي إن كانوا وبعدين
+
+236
+00:21:57,260 --> 00:22:01,600
+double bond ثانية هذه الأنواع الثلاثة من الـ
+
+237
+00:22:01,600 --> 00:22:08,360
+alkanes لها أسماء النوع الأول بيسمّوه cumulated يعني
+
+238
+00:22:08,360 --> 00:22:15,700
+وراء بعض بالظبط .. cumulated .. cumulated ضايعين
+
+239
+00:22:15,700 --> 00:22:22,080
+واضح؟ النوع الثاني هو اللي عندنا هو محور النقطة
+
+240
+00:22:22,080 --> 00:22:25,340
+اللي بنحكيها الآن conjugated معناها conjugation
+
+241
+00:22:25,340 --> 00:22:30,390
+double single double إذا هذا النوع الثالث اللي هو
+
+242
+00:22:30,390 --> 00:22:36,350
+دارسنا اليوم إيش اسمه conjugated diene وإله تفاعلات
+
+243
+00:22:36,350 --> 00:22:41,670
+خاصة فيه النوع الثالث بعيد عن بعضه منعزل عن بعضه
+
+244
+00:22:41,670 --> 00:22:47,330
+إيش بنسمّيه isolated بتعرف isolation عزل لما نقول
+
+245
+00:22:47,330 --> 00:22:53,390
+إنّه في بني آدم isolated منعزل بنفعل بني آدم يكون
+
+246
+00:22:53,390 --> 00:23:00,690
+منعزل اجتماعيًا آه أبو .. وين بيكون منعزل؟ إذا كان
+
+247
+00:23:00,690 --> 00:23:04,890
+في مجتمع كافر لازم ينعزل، الآية بتقول وأعتزلكم
+
+248
+00:23:04,890 --> 00:23:09,170
+وما تدعونا من دون الله وأدعو ربي عسى الله أكون
+
+249
+00:23:09,170 --> 00:23:16,110
+بدعائه، ربي .. أيّه مش هاطل؟ اجتماعي بالمناسبة في
+
+250
+00:23:16,110 --> 00:23:19,850
+المجتمع المسلم حتى لو فيه مشاكل
+
+251
+00:23:21,420 --> 00:23:26,200
+المسلم الذي يخالط الناس ويصبر على أذاهم خير من
+
+252
+00:23:26,200 --> 00:23:29,660
+الذي لا يخالطهم ولا يصبر على أذاهم، عشانك مش لازم
+
+253
+00:23:29,660 --> 00:23:32,060
+نُعزّز الاجتماع، عشان فين قدّيش بتغلبوا في الـ homework
+
+254
+00:23:32,060 --> 00:23:37,540
+لكن مش عاملين نُعزّز الاجتماع، الآن احنا اللي بدنا
+
+255
+00:23:37,540 --> 00:23:47,820
+نأخذه تحديدا على الـ conjugated ضايعين إضافة HBR لأنّه
+
+256
+00:23:47,820 --> 00:23:54,740
+إلها مواصفة معينة إضافة الـ HPR في وجود حامض بتعرف
+
+257
+00:23:54,740 --> 00:23:58,360
+احنا إنّه في وجود الحامض أول ما بيبدأ التفاعل H
+
+258
+00:23:58,360 --> 00:24:02,280
+Plus بتضيف على أحد الطرفين الآن تخيّلوا معاك،
+
+259
+00:24:02,280 --> 00:24:05,560
+تذكروا الكلام اللي أخذنا إذا ضافت الـ H Plus هنا،
+
+260
+00:24:05,560 --> 00:24:09,800
+شو بيصير؟ secondary carbocation إذا ضافت هنا
+
+261
+00:24:09,800 --> 00:24:16,420
+primary، الأول مفضل، secondary إذن هذا مش خلاف إذا
+
+262
+00:24:16,420 --> 00:24:20,800
+الـ H plus بتضيف هنا بتكون لها الـ secondary
+
+263
+00:24:20,800 --> 00:24:26,120
+carbocation هل الـ secondary carbocation إذا لقى PR
+
+264
+00:24:26,120 --> 00:24:32,990
+minus بتفاعل وبناء على ذلك بيصير عند H و PR الاضافة
+
+265
+00:24:32,990 --> 00:24:37,750
+العادية اللي احنا تعلمناها إضافة HPR على رابطة
+
+266
+00:24:37,750 --> 00:24:44,270
+زوجية الـ allyl لو الـ PR minus تأخر لما يصل
+
+267
+00:24:44,270 --> 00:24:49,450
+للأيون الموجب ملاحظين أنتم ممكن يتأخر في التفاعل
+
+268
+00:24:49,450 --> 00:24:53,670
+لما يصل للأيون الموجب بيصير عندي احتمال ثاني إنّه
+
+269
+00:24:53,670 --> 00:24:57,990
+هنا أنا في عندي هنا أنا في عندي جنب هذا الموجب
+
+270
+00:24:57,990 --> 00:24:59,950
+الموجب قاعد بيستنى بدّه إيش
+
+271
+00:25:02,810 --> 00:25:08,190
+الموجب دائمًا يمثل شحنة مصيبة بدّه يتعادل بدّه سالب
+
+272
+00:25:08,190 --> 00:25:14,450
+فإذا لقى الـ PR minus زي ما بيقولوا بها ونعمة بضيف
+
+273
+00:25:14,450 --> 00:25:19,550
+الـ PR على طول طب إذا ما لاقى الـ PR minus بتيجي الـ
+
+274
+00:25:19,550 --> 00:25:24,250
+double bond بتقول أنا كثافة إلكترونية بتلف بهذا
+
+275
+00:25:24,250 --> 00:25:29,960
+الشكل بتعطي إلكترونات واضح؟ الآن لاحظوا .. لاحظوا
+
+276
+00:25:29,960 --> 00:25:34,040
+معنى لما الـ double bond تلف بهذا الشكل تعطيه
+
+277
+00:25:34,040 --> 00:25:38,300
+إلكترونات محال هنا شو بدّه يصير عندي؟ Ion Moja
+
+278
+00:25:38,300 --> 00:25:45,580
+جديد، إذا هي حلت مشكلة حقيقة ما حلتش مشكلة، بناء
+
+279
+00:25:45,580 --> 00:25:51,100
+على ذلك صارت عندي مشكلة جديدة هذا الـ ايون الموجة
+
+280
+00:25:51,100 --> 00:25:56,720
+الجديد إمّا بيلاقي PR- وبالتالي بتضيف بسرعة هذا
+
+281
+00:25:56,720 --> 00:26:00,880
+إذا ما لاقاش ممكن الـ double bond ترجع وترجع تكون
+
+282
+00:26:00,880 --> 00:26:07,400
+هذا الايون إذا كأنّه هذا الايون اللي احنا بنسمّيه
+
+283
+00:26:07,400 --> 00:26:12,420
+قلل كتايلون مر علينا في double bonds مجموعة القلل
+
+284
+00:26:12,420 --> 00:26:20,100
+القلل double bond CH2 زي هي كانت double bond CH2
+
+285
+00:26:20,100 --> 00:26:24,060
+هذه كانت مجموعة القلل مظبوط الآن لو طلّعت أنا
+
+286
+00:26:24,060 --> 00:26:30,380
+double bond CH2 هذه قليل ولا لأ؟ آه هذه القليل كتايل
+
+287
+00:26:30,380 --> 00:26:36,480
+بنقول عنه بيعمل resonance إيش يعني resonance حركة
+
+288
+00:26:36,480 --> 00:26:40,000
+إلكترونات فقط عمرنا لما نسأل نقول لكم إيش يعني
+
+289
+00:26:40,000 --> 00:26:44,300
+انكتوا اعطوني ترجمة العربية اعطوني المعنى لما أخذنا
+
+290
+00:26:44,300 --> 00:26:50,060
+الـ resonance في أول فصل قلنا لكم الـ resonance حركة
+
+291
+00:26:50,060 --> 00:26:54,840
+إلكترونات الـ resonance حركة إلكترونات وكيف يعبر
+
+292
+00:26:54,840 --> 00:26:59,580
+عنه؟ بالسهم اللي زي هيك اللي اسمه double headed
+
+293
+00:26:59,580 --> 00:27:03,340
+arrows فقط الإلكترونات اللي قاعدة بتتحرك هيك مرة و
+
+294
+00:27:03,340 --> 00:27:07,060
+بتروح هيك مرة فقط حركة إيش؟ إلكترونات الرنين
+
+295
+00:27:07,060 --> 00:27:11,720
+رنين إلكترونات بتكون بتتحرك باتجاهها movement of
+
+296
+00:27:11,720 --> 00:27:16,320
+electrons واضح؟ فاللي بنقوله إحنا إن القليل
+
+297
+00:27:16,320 --> 00:27:20,500
+الكاتيون بيكون في عملية resonance هذا الكلام
+
+298
+00:27:20,500 --> 00:27:24,480
+بيخلّي بعد ما إضافة الـ H على أول موقع الـ PR يا
+
+299
+00:27:24,480 --> 00:27:30,340
+بضيفها موقع اثنين يعني على موقع أربعة إذا أنا في
+
+300
+00:27:30,340 --> 00:27:37,340
+إضافة الـ HBR على الـ conjugated داين بلاحظ إن عنده
+
+301
+00:27:37,340 --> 00:27:44,760
+ناتجين إمّا إنّه يكون عنده one two addition أو one
+
+302
+00:27:44,760 --> 00:27:49,240
+four addition يا الإضافة على موقع وعلى اللي
+
+303
+00:27:49,240 --> 00:27:53,840
+بعده مباشرة يا بتضيف على موقع وعلى نمرة أربعة
+
+304
+00:27:53,840 --> 00:27:57,040
+بالنسبة له شوفتوا إيش تفسير الـ one two و الـ one
+
+305
+00:27:57,040 --> 00:28:00,940
+four addition اللي بنقول لكم فسّروا إنّه على هذا
+
+306
+00:28:00,940 --> 00:28:06,980
+الداين الـ conjugated داين الناتج خليط من مركّبين خليط
+
+307
+00:28:06,980 --> 00:28:10,680
+من الـ one two addition و الـ one four addition ما هو
+
+308
+00:28:10,680 --> 00:28:14,720
+السبب إنّه بتكون عندي قليل كتايلون الـ قليل كتايلون
+
+309
+00:28:14,720 --> 00:28:18,920
+بيعمل resonance مرة لموجبها مرة لموجبها مرة
+
+310
+00:28:18,920 --> 00:28:23,120
+لموجبها مرة لموجبها يا ترى الـ resonance بيقلل
+
+311
+00:28:23,120 --> 00:28:24,620
+الثبات ولا بيزيده؟
+
+312
+00:28:28,020 --> 00:28:32,160
+يعني بيكون more stable ولا less stable لما بيكون
+
+313
+00:28:32,160 --> 00:28:39,020
+في عندي resonance طيّب خلينا نتخيل القاتل إنّه إحنا
+
+314
+00:28:39,020 --> 00:28:46,610
+مروحين من السوق وحاملين عشرة كيلو بدنا نمشي تقريبًا
+
+315
+00:28:46,610 --> 00:28:51,330
+500 متر للدار هل يا ترى إحنا بنضل حاملين العشرة
+
+316
+00:28:51,330 --> 00:28:54,810
+كيلو بإيد واحدة ولا بنكون قاعدين نعمل resonance؟
+
+317
+00:28:54,810 --> 00:28:59,470
+لو صوّرنا أي بني آدم مروح بعشرة كيلو، إيش بيعمل؟
+
+318
+00:28:59,470 --> 00:29:02,190
+بيعمل resonance، مرة بالإيد هذه، مرة بالإيد هذه،
+
+319
+00:29:02,190 --> 00:29:06,010
+مرة بالإيد هذه، مرة بالإيد هذه فالـ resonance حقيقة
+
+320
+00:29:06,010 --> 00:29:13,650
+is a stabilizing effect هو تأثير تثبيتي بيثبت الشحنة
+
+321
+00:29:13,650 --> 00:29:22,670
+بدل ما الشحنة على جهة واحدة بتكون الشحنة على جهتين
+
+322
+00:29:22,670 --> 00:29:28,610
+واضح؟ الآن كل بني آدم .. كل بني آدم بيقدر يفهم
+
+323
+00:29:28,610 --> 00:29:33,990
+الموضوع بطريقته في موضوع الـ resonance واضح؟ كل بني
+
+324
+00:29:33,990 --> 00:29:37,870
+آدم بيقدر في موضوع الـ resonance يفهم الموضوع
+
+325
+00:29:37,870 --> 00:29:44,950
+بطريقته أعطيكم مثال .. مثال من الحياة مثلًا لو
+
+326
+00:29:44,950 --> 00:29:53,650
+افترضنا اثنين أخوة وعندهم أم أو أب كبير بدّه خدمة
+
+327
+00:29:53,650 --> 00:30:00,810
+معيّنة إيش بتلاحظوا بواقع الناس؟ بيحاولوا يعملوا
+
+328
+00:30:00,810 --> 00:30:06,150
+resonance، إنّه والله خلي أسبوع هنا وأسبوع هنا،
+
+329
+00:30:06,150 --> 00:30:11,430
+أسبوع هنا وأسبوع هنا، واضح؟ الآن هذا الـ resonance
+
+330
+00:30:11,430 --> 00:30:16,650
+في وجهة نظرهم في الدنيا، إن هم إيش؟ بيريحوا هم أو
+
+331
+00:30:16,650 --> 00:30:22,110
+نسوانهم، بيريحوا من غلبة الأب أو الأم، مظبوط ولا
+
+332
+00:30:22,110 --> 00:30:26,620
+لا؟ لكن الناس اللي بيفهموا وشو بيعملوا؟ بيكونوا
+
+333
+00:30:26,620 --> 00:30:31,020
+يتقاتلوا مين يخلي الأب أو الأم عنده، في قضية
+
+334
+00:30:31,020 --> 00:30:34,980
+مرفوعة بالمحاكم السعودية بين اثنين أخوة وحاطين
+
+335
+00:30:34,980 --> 00:30:38,740
+أكبر المحامين بيتقاتلوا على أمهم، كل واحد بدّه أمّه
+
+336
+00:30:38,740 --> 00:30:42,720
+تكون عنده يقدّمها في العشر الأواخر زي ما بيقولوا من
+
+337
+00:30:42,720 --> 00:30:46,480
+العمر، وأنتم احسبوها عدّ إيش اللي بتعملوا بحياتكم
+
+338
+00:30:49,210 --> 00:30:52,990
+ما .. ما هو الآن اللي بيكونوا ينقلوا الأم والأبو
+
+339
+00:30:52,990 --> 00:30:57,590
+بيقولوا بدّهم ثبات إيش؟ بدّهم الـ resonance أو الثبات
+
+340
+00:30:57,590 --> 00:31:03,350
+اللي هو تبع الدنيا واللي بدّه يحافظ عليهم طيّب و
+
+341
+00:31:03,350 --> 00:31:11,550
+الآية إيش بتقول؟ وللآخرة خير وأبقى فمن الناس ما
+
+342
+00:31:11,550 --> 00:31:16,510
+يقولوا ربنا آتنا في الدنيا وما له في الآخرة ومنهم
+
+343
+00:31:16,510 --> 00:31:21,570
+من يقول ربنا آتنا في الدنيا حسنة وفي الآخرة حسنة
+
+344
+00:31:21,570 --> 00:31:28,810
+وقنا عذاب النهار والله سريع الحساب هذا الكلام نزل
+
+345
+00:31:28,810 --> 00:31:30,250
+في الآيات اللي هي إيش؟
+
+346
+00:31:33,690 --> 00:31:38,270
+في الآيات لبع الحج مباشرة لأنّ العرب كانوا بعد
+
+347
+00:31:38,270 --> 00:31:42,630
+الحج مجرّد ما يخلصوا الرجم وكل شيء يتجهوا باتجاه
+
+348
+00:31:42,630 --> 00:31:46,590
+جبل عرفات هم في مكة ويصيروا يدعوا ويتفاخرون
+
+349
+00:31:46,590 --> 00:31:50,950
+بالآباء والأجداد ولذلك الآية قالت لهم فإذا قضيتم
+
+350
+00:31:50,950 --> 00:31:56,330
+مناسككم فاذكروا الله كذكركم آباءكم أو أشدّ ذكرى
+
+351
+00:31:56,330 --> 00:32:01,110
+يعني يكون هدفكم الآخرة مش الدنيا هم كانوا يحجوا
+
+352
+00:32:01,110 --> 00:32:06,870
+يخلصوا إيش يقفوا يقولوا في نهاية الحجّة؟ أبويا و
+
+353
+00:32:06,870 --> 00:32:11,910
+أبوك يتفاخرون بالدنيا، الآية قالت لهم فاذكروا الله
+
+354
+00:32:11,910 --> 00:32:16,790
+كذكركم آباءكم أو أشدّ ذكرى فمن الناس من يقولوا ربنا
+
+355
+00:32:16,790 --> 00:32:23,370
+آتنا فاتنا على أي حال، تفاعل إضافي، تعبتم من
+
+356
+00:32:23,370 --> 00:32:27,210
+تفاعلات الـ kids إذا جيبنا لكم على السؤال صح و
+
+357
+00:32:27,210 --> 00:32:30,650
+غلط في الامتحان الـ kids are inert وواحدة بتقول
+
+358
+00:32:30,650 --> 00:32:31,370
+مظبوط
+
+359
+00:32:34,370 --> 00:32:39,170
+الالكينات تفاعلاته كثيرة جدًا هذا التفاعل بنسمّيه
+
+360
+00:32:39,170 --> 00:32:43,630
+deals alder reaction deals alder reaction هو عبارة
+
+361
+00:32:43,630 --> 00:32:50,330
+عن تفاعل بنسمّيه cycle addition reaction إيش يعني
+
+362
+00:32:50,330 --> 00:32:55,110
+cycle addition reaction؟ معنى cycle addition
+
+363
+00:32:55,110 --> 00:33:01,130
+reaction هو تفاعل بأكون أنا فيه رابطتين في نفس
+
+364
+00:33:01,130 --> 00:33:05,990
+الوقت، في نفس اللحظة، يعني لو افترضت أنا عند
+
+365
+00:33:05,990 --> 00:33:11,180
+قطعتين بهذا الشكل وإي جيت جرّبتهم جرّبتهم جرّبتهم على
+
+366
+00:33:11,180 --> 00:33:15,620
+بعض بهذا الشكل لحد ما صار رابطة لأن أنا كم رابطة
+
+367
+00:33:15,620 --> 00:33:20,380
+قاعد بعمل بنفس اللحظة رابطتين هذا التفاعل اللي
+
+368
+00:33:20,380 --> 00:33:24,660
+بضيف قطعتين بنفس اللحظة وبكون two new sigma bonds
+
+369
+00:33:24,660 --> 00:33:30,520
+بسمّيه cycle addition reaction
+
+370
+00:33:30,520 --> 00:33:33,280
+ومن هذه التفاعلات تفاعلات إيش
+
+371
+00:33:48,260 --> 00:33:52,440
+بينما لو أنا كنت بدي أعمل حلقة معيّنة زي هيك بس
+
+372
+00:33:52,440 --> 00:33:59,170
+أسكر طرفينها بعمل رابطة واحدة
+
+373
+0
+
+401
+00:35:59,460 --> 00:36:02,980
+تحطوا الجواب صح أسهل شيء تحركوا رابط هيك و رابط هيك
+
+402
+00:36:02,980 --> 00:36:07,970
+و رابط هيك حتى تكتبوا الجواب بسهولة هي عندي مثال
+
+403
+00:36:07,970 --> 00:36:11,430
+ثاني هي تضيء هذا ال conjugated وهي double bond
+
+404
+00:36:11,430 --> 00:36:15,070
+حتى لو double bond كانت بحلقة مش مشكلة هي واحدة
+
+405
+00:36:15,070 --> 00:36:20,010
+اثنين ثلاثة هذه اللي بده تصير ال new sigma bond
+
+406
+00:36:20,010 --> 00:36:23,390
+هنا هذه اللي بده تصير ال new sigma bond هنا و هذه
+
+407
+00:36:23,390 --> 00:36:28,490
+اللي بده تتحرك هنا طلع عندي برضه cyclohexane ولو
+
+408
+00:36:28,490 --> 00:36:33,640
+متحد مع حلقة ثانية هذا التفاعل شو بنسميه احنا Diels
+
+409
+00:36:33,640 --> 00:36:38,600
+Alder reaction أو Diels Alder cycloaddition
+
+410
+00:36:38,600 --> 00:36:44,540
+reaction فإذا قلنا لكم Diels Alder reaction is a
+
+411
+00:36:44,540 --> 00:36:50,220
+cyclizing reaction أو cyclization reaction خطأ هو
+
+412
+00:36:50,220 --> 00:36:55,900
+cycloaddition a reaction in which two new sigma
+
+413
+00:36:55,900 --> 00:37:03,510
+bonds are formed at the same time إني بكون رابطتين
+
+414
+00:37:03,510 --> 00:37:08,950
+مش رابطة واحدة هم لاحظين هي وهنا اجت رابطة وهنا
+
+415
+00:37:08,950 --> 00:37:14,170
+اجت رابطة we are forming two new sigma bonds
+
+416
+00:37:28,040 --> 00:37:37,740
+من التفاعلات الإضافية المهمة جدا لـ alkenes
+
+417
+00:37:37,740 --> 00:37:42,080
+وتحديدا ممكن ناخذ لأبسط alkenes اللي هو الاثيلين
+
+418
+00:37:42,080 --> 00:37:47,760
+تفاعل عمل Polymer إيش يعني polymer؟ بيكون عندي جزيء
+
+419
+00:37:47,760 --> 00:37:53,060
+واحد بسميه أنا monomer بتحد مع عدد كبير من
+
+420
+00:37:53,060 --> 00:37:57,480
+الجزيقات بيعمله سلسلة polymer يعني لو افترضت هدول
+
+421
+00:37:57,480 --> 00:38:02,400
+الأقلام الأربعة زي بعض وكل واحد فيهم عبارة عن إيش؟
+
+422
+00:38:02,400 --> 00:38:06,940
+إثالين، هاي monomer، monomer، monomer، monomer هذا
+
+423
+00:38:06,940 --> 00:38:10,720
+الإثالين لأنه جزء واحد بالوضع الطبيعي بيكون إيش؟
+
+424
+00:38:10,720 --> 00:38:15,840
+غاز، مظبوط ولا لا؟ مش الإثالين غاز وبيحطوه بالغرف
+
+425
+00:38:15,840 --> 00:38:20,820
+المغلقة على الموز الأخضر عشان يستوي، بتشوفوا الموز
+
+426
+00:38:20,820 --> 00:38:24,550
+لما بيجيبوه استيراد كيف بيكون لونه؟ أخضر على الآخر،
+
+427
+00:38:24,550 --> 00:38:28,250
+هيك .. هيك لازم الموز ي .. ينقل لأنه بيخرب بسرعة،
+
+428
+00:38:28,250 --> 00:38:31,830
+الآن قبل ما ينزلوا على السوق بيحطوا ليلة بغرفة
+
+429
+00:38:31,830 --> 00:38:36,130
+مغلقة بيمرروا عليه غاز الاثيلين، بينضج، بيصير
+
+430
+00:38:36,130 --> 00:38:41,010
+أصفر، الآن هذا الاثيلين لو أجينا وحدنا عدة جزيئات
+
+431
+00:38:41,010 --> 00:38:46,990
+منه، هاي جزيئة اثنين، ثلاثة، أربعة، بدأ يكبر،
+
+432
+00:38:46,990 --> 00:38:50,070
+يكبر، يكبر، صرنا ألفين، ثلاثة آلاف، بيصير
+
+433
+00:38:50,070 --> 00:38:54,710
+polymer، ال polymer هذا plastic ملاحظين؟ يعني أنا
+
+434
+00:38:54,710 --> 00:39:00,490
+ببدأ بغاز، بضغطه، بنتهي ب plastic اللي هو ال
+
+435
+00:39:00,490 --> 00:39:04,390
+plastic الأبيض اللي بيعمله منه كثير من القوانين
+
+436
+00:39:04,390 --> 00:39:08,710
+وغيره وغيرها هذا اللي اسمه polyethylene يعني فيه
+
+437
+00:39:08,710 --> 00:39:11,750
+أكثر من جزء إيثيلين هذه العملية عملية
+
+438
+00:39:11,750 --> 00:39:16,370
+polymerization فال polymerization أنه يكون عنده
+
+439
+00:39:16,370 --> 00:39:22,640
+monomer بظروف معينة من الضغط من درجة الحرارة من
+
+440
+00:39:22,640 --> 00:39:26,100
+إضافة البروكسايد البروكسايد عشان التفاعل free
+
+441
+00:39:26,100 --> 00:39:30,080
+radical reaction المرة الماضية أخذنا البروكسايد
+
+442
+00:39:30,080 --> 00:39:35,200
+بيصير CH2 CH2 to the N و N هذه بتطلع إلى ثلاثة أربع
+
+443
+00:39:35,200 --> 00:39:39,460
+تلاف جزء مع بعض لما يصير ثلاثة أربع تلاف جزء مع بعض
+
+444
+00:39:39,460 --> 00:39:46,600
+الغاز بيصير plastic solid مظبوط ولا لأ؟ هذا زي حال
+
+445
+00:39:46,600 --> 00:39:50,920
+.. زي حال الناس حتى يعني لما يكون بني آدم لوحده
+
+446
+00:39:50,920 --> 00:39:57,720
+المعارض مثلا أيمن نور إيش عمل فيه النظام المصري؟
+
+447
+00:39:57,720 --> 00:40:02,280
+حبسوه لأنه لحاله غاز وحبس وهو كان مرشح رئيس
+
+448
+00:40:02,280 --> 00:40:09,770
+جمهورية لكن لما صار عندي بوليمار من كل الشعب صرت
+
+449
+00:40:09,770 --> 00:40:14,790
+أمام حالة صلبة، هذه الحالة الصلبة انهرت قدامها كل
+
+450
+00:40:14,790 --> 00:40:20,830
+الدنيا، وعشان هي كبيت الشعر، إيش بيقول؟ تقبل
+
+451
+00:40:20,830 --> 00:40:28,550
+رماحه، إذا اجتمعنا نكسره، وإذا افترقنا نكسرت غاز
+
+452
+00:40:28,550 --> 00:40:35,230
+ذاتي، غاز بيكون  انتوا افهموا يعني ال polymers ال
+
+453
+00:40:35,230 --> 00:40:39,050
+polymers مش موضوع بسيط يعني بيقولوا أهم اكتشافات
+
+454
+00:40:39,050 --> 00:40:43,850
+يمكن القرن الماضي مرات بيحكوا تكوين ال polymers
+
+455
+00:40:43,850 --> 00:40:48,110
+يعني تكوين ال nylon وتكوين ال plastic وتكوين ال
+
+456
+00:40:48,110 --> 00:40:52,570
+polystyrene وتكوينها الأقمشة الصناعية كل هذه
+
+457
+00:40:52,570 --> 00:40:56,130
+الأشياء هي اللي اليوم هي اللي رابطة حياتنا يعني
+
+458
+00:40:56,130 --> 00:41:00,370
+هذا الجلم اللي تطلع عليه الآن هذا ال plastic قبل
+
+459
+00:41:00,370 --> 00:41:03,470
+سبعين سنة ما كانش فيه ما كانش فيه غير جلم الرصاص اللي
+
+460
+00:41:03,470 --> 00:41:07,350
+بعمله من الخشب وفي قلبه كربون كان عندي هذه الشغلات
+
+461
+00:41:07,350 --> 00:41:11,210
+ما كانش هذا السبورة ما كانتش هذا الإجماش ما كانش هذا ال
+
+462
+00:41:11,210 --> 00:41:14,690
+plastic ما كانش هذا ال plastic ما كانش هذا ال plastic
+
+463
+00:41:14,690 --> 00:41:17,990
+ما كانش اليوم كل حياتكم صارت مبنية على هذه الفكرة
+
+464
+00:41:17,990 --> 00:41:22,450
+البسيطة يعني مش فكرة صغيرة تتخيلوها أنه أنا قاعد
+
+465
+00:41:22,450 --> 00:41:31,800
+بعص غاز بخليه solid واضح؟ يعني هي من أكبر الأفكار
+
+466
+00:41:31,800 --> 00:41:35,700
+اللي صارت في القرن العشرين فكرة تكوين ال polymers
+
+467
+00:41:35,700 --> 00:41:40,440
+صناعات لبلاستيك والأنابيب زمان كانت الأنابيب كلها
+
+468
+00:41:40,440 --> 00:41:44,800
+يا إما يعملوها أحيانا من ال اسمنت ما أعرفش إذا أنتم
+
+469
+00:41:44,800 --> 00:41:48,660
+وعيين لهذا النوع من الأنابيب أو من الحديد يعني
+
+470
+00:41:48,660 --> 00:41:52,260
+اللي كانوا ينظروا للبيوت القديمة الأنابيب المجارة
+
+471
+00:41:52,260 --> 00:41:56,890
+من إيش كانت تكون؟ من الحديد الظاهر اللي بيكسر،
+
+472
+00:41:56,890 --> 00:42:00,430
+الأنابيب تبعت المي اللي في الشوارع، من إيش كانت
+
+473
+00:42:00,430 --> 00:42:05,850
+تكون؟ إسمنت، إسمنت وأشياء زي هيك اليوم كل الدنيا
+
+474
+00:42:05,850 --> 00:42:10,650
+صارت plastic من ورا مثل هذا التفاعل البسيط فما
+
+475
+00:42:10,650 --> 00:42:14,190
+تفهموش الموضوع أنه بس يعني أنه احنا بنحكي رموز و
+
+476
+00:42:14,190 --> 00:42:20,110
+بس، لا احنا بنحكي واقع، واقع حياة الآن هذا التفاعل
+
+477
+00:42:20,110 --> 00:42:24,210
+كيف بيتم، بزام احنا عندنا البروكسايد، البروكسايد
+
+478
+00:42:24,210 --> 00:42:28,570
+أول ما نشوية حرارة بيعطينا إيش، بنكسر homolytic
+
+479
+00:42:28,570 --> 00:42:32,550
+cleavage، الحصة الماضية أخذناها بيعطينا 2 free
+
+480
+00:42:32,550 --> 00:42:36,650
+radicals هذا ال free radical بيجي على ال double
+
+481
+00:42:36,650 --> 00:42:39,110
+bond اللي لها ال double bond اللي لها كم electron
+
+482
+00:42:39,110 --> 00:42:45,390
+اثنين هياخد التفاعل مع electron واحد صار عند ال RO
+
+483
+00:42:45,390 --> 00:42:51,130
+CH2 CH2 وهذه ال CH2 بترفنية شو طال عليها electron
+
+484
+00:42:51,130 --> 00:42:57,090
+مظبوط الآن خدوا هذا الجزء ال RO CH2 CH2 وعليها
+
+485
+00:42:58,500 --> 00:43:04,220
+free radical فعلوها مع جزء إثالين جديد وخليها
+
+486
+00:43:04,220 --> 00:43:10,280
+تعمل رابطة هنا كبرة اثنين وعلى الطرف free radical
+
+487
+00:43:10,280 --> 00:43:14,580
+كمان مرة كمان مرة كمان مرة لأنه واصل لثلاثة أربع
+
+488
+00:43:14,580 --> 00:43:19,640
+تلاف جزء صار عند بوليمار طبعا عشانه غاز أنا بحاجة
+
+489
+00:43:19,640 --> 00:43:23,760
+إلى حرارة بحاجة إلى البروكسايد اللي بده يبدأ
+
+490
+00:43:23,760 --> 00:43:28,450
+للتفاعل هذا الشرارة تاعت التفاعل تاعت free radical
+
+491
+00:43:28,450 --> 00:43:31,890
+reaction وهذا ال polymerization بالمناسبة شو
+
+492
+00:43:31,890 --> 00:43:37,130
+بيسموها free radical polymerization of ethylene
+
+493
+00:43:37,130 --> 00:43:40,350
+free radical polymerization of ethylene عشان
+
+494
+00:43:40,350 --> 00:43:45,520
+يعطينا ال polyethylene شوفتوا كيف بالتم؟ الآن
+
+495
+00:43:45,520 --> 00:43:51,020
+العلماء طموحهم ما بيقفش يعني أنا بدأت بال إيثيلين
+
+496
+00:43:51,020 --> 00:43:57,700
+وصارت الوحدة المتكررة عندي إيش هي CH2 CH2 CH2 CH2
+
+497
+00:43:57,700 --> 00:44:05,720
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+498
+00:44:05,720 --> 00:44:09,160
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+499
+00:44:09,160 --> 00:44:09,920
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+500
+00:44:09,920 --> 00:44:09,940
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+501
+00:44:09,940 --> 00:44:11,300
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+502
+00:44:11,300 --> 00:44:18,570
+CH2 CH2 CH حطيت مكانها chlorine يعني بمعنى أن الجزء
+
+503
+00:44:18,570 --> 00:44:24,630
+الأول يكون زي هيك بس أنا حطيت chlorine هذا المركب
+
+504
+00:44:24,630 --> 00:44:30,590
+اسمه vinyl chloride أخذتو أنتم مجموعة CH2 double
+
+505
+00:44:30,590 --> 00:44:34,410
+bond CH اسم المجموعة ال vinyl لما يكون معها
+
+506
+00:44:34,410 --> 00:44:38,250
+chlorine Vinyl chloride الآن لو ال vinyl chloride
+
+507
+00:44:38,250 --> 00:44:43,270
+عملوله polymerization بشغل بنفس الطريقة بعملي CH
+
+508
+00:44:43,270 --> 00:44:50,210
+متصلة ب CL CH2 to the N بيصير polyvinyl chloride ال
+
+509
+00:44:50,210 --> 00:44:56,030
+polyvinyl chloride له اسم شهرة مختصر إيش بنختصره
+
+510
+00:44:56,030 --> 00:45:05,900
+PVC مين فيكم ما سمعش في plastic ال PVC لأ لأ أبدا
+
+511
+00:45:05,900 --> 00:45:09,660
+ولا ألياف بصرية ولا إشي شوفتوا الأرضيات اللي مرات
+
+512
+00:45:09,660 --> 00:45:13,040
+بيعملوا منها المستشفيات وغيرها و ال studio هذه
+
+513
+00:45:13,040 --> 00:45:18,260
+كلها PVC شوفتوا هذا ال plastic وهذا التبع الشاشة
+
+514
+00:45:18,260 --> 00:45:23,390
+والشونات تبعتكم ال plastic كل هذا ال PVC نوع ابن
+
+515
+00:45:23,390 --> 00:45:27,590
+عمه للبولي إيثنين واضح؟ ابن عمه للبولي إيثنين ال
+
+516
+00:45:27,590 --> 00:45:32,050
+PVC أشهر شيء بتلاقوا المحلات تابعون ال decor اللي
+
+517
+00:45:32,050 --> 00:45:37,850
+بيبيعوا ستاير بيكونوا كاتبين لبايع ال PVC اللي هو
+
+518
+00:45:37,850 --> 00:45:41,630
+ال plastic اللي بيفردوه على الأرض على ال studio
+
+519
+00:45:41,630 --> 00:45:46,230
+على المطبخ عمركم شفتوه؟ يمكن الآن الناس مع روح
+
+520
+00:45:46,230 --> 00:45:51,500
+السعر لكراميكا بطلوا يهتموا فيه بس قبل حوالي 15 سنة
+
+521
+00:45:51,500 --> 00:45:56,100
+كنتوا معظم المحلات التجارية لما تدخلوها تلاقوها
+
+522
+00:45:56,100 --> 00:46:02,480
+حاطة على الأرض بدل هذا السجاد PVC هو هذا البوليمار
+
+523
+00:46:02,480 --> 00:46:10,460
+ممكن كمان يبدو بستايرين الاستايرين المرة الماضية
+
+524
+00:46:10,460 --> 00:46:15,160
+حكينالكوا عنه اللي هو CH2 ضم ال bond CH وعليه
+
+525
+00:46:15,160 --> 00:46:22,700
+مجموعة بنزين بلاحظين هذا اسمه إيش؟ استايرين ..
+
+526
+00:46:22,700 --> 00:46:27,320
+استايرين ال polymer تبعه زي ال إيثيلين بس بدل H بال
+
+527
+00:46:27,320 --> 00:46:33,280
+hot funnel بيصير polystyrene، plastic برضه، ما
+
+528
+00:46:33,280 --> 00:46:38,310
+تخلطوهوش في ال polyester بتعرفوا البوليستر أول ما
+
+529
+00:46:38,310 --> 00:46:43,970
+بتشتريه جماش، إيش بتقوله؟ قداش قطن وقداش بوليستر
+
+530
+00:46:43,970 --> 00:46:48,890
+وكل ما نسبة القطن صارت أعلى، بتعتبروه أجود، بس
+
+531
+00:46:48,890 --> 00:46:54,890
+اليوم ماحدش برضه بيقبل نسبة قطن مئة في المئة إلا
+
+532
+00:46:54,890 --> 00:46:58,950
+polyester يكون معه يعني يكون أربعين أو خمسين أو
+
+533
+00:46:58,950 --> 00:47:02,670
+ستين في المئة قطن كويس أربعين في المئة polyester
+
+534
+00:47:02,670 --> 00:47:06,490
+بس ما يكونش مئة في المئة polyester مئة في المئة
+
+535
+00:47:06,490 --> 00:47:10,250
+polyester بيكون petrol يعني لو اجت نار بيولع على
+
+536
+00:47:10,250 --> 00:47:16,450
+طول بالحرارة شديد على الجسم مظبوط ولا لأ؟ بيكون
+
+537
+00:47:16,450 --> 00:47:20,850
+خليط من القطن ومن ال polyester الآن ال polyester
+
+538
+00:47:20,850 --> 00:47:26,660
+غير ال polystyrene عشان أنتم ما تخربطوش polystyrene
+
+539
+00:47:26,660 --> 00:47:31,860
+بلاستيك معين البولي إستر بينعمل منه ال fibers
+
+540
+00:47:31,860 --> 00:47:38,060
+الخطان ومنه كل الأقمشة ما فيش فينا حد في لبسه إلا
+
+541
+00:47:38,060 --> 00:47:41,980
+موجود بولي إستر لا يمكن ما فيش حد لابس قطن كتمة ولا
+
+542
+00:47:41,980 --> 00:47:45,200
+بمصنع اليوم كل هذا الجماش اللي أنتم شايفينه
+
+543
+00:47:45,200 --> 00:47:49,140
+الجاكيتات اللي بصاريش غالبا مخلوطة الخطان بتاعتها
+
+544
+00:47:49,140 --> 00:47:52,700
+أربعين خمسين في المئة قطن أربعين خمسين في المئة
+
+545
+00:47:53,460 --> 00:47:58,380
+بولي إستر البولي إستر بيمر علينا بعدين غير البولي
+
+546
+00:47:58,380 --> 00:48:01,740
+ستايرين البولي ستايرين بلاستيك لبراميل وغيرها
+
+547
+00:48:01,740 --> 00:48:07,180
+وغيرها بس اللي بنعمل منه fibers هو البولي إستر
+
+548
+00:48:07,180 --> 00:48:14,040
+أبهيك احنا بنكون خلصنا تفاعلات ال alkynes إن شاء
+
+549
+00:48:14,040 --> 00:48:18,020
+الله المحاضرة الجاية بنبدأ بتفاعلات ال alkynes
+
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..dc1f1bcb263b7bb075f7553a734cb2fbdd3006a7
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/btr865mDwik_postprocess.srt
@@ -0,0 +1,2196 @@
+1
+00:00:05,620 --> 00:00:12,680
+موضوع ال alkanes موضوع واسع، واسع كتير ويمكن
+
+2
+00:00:12,680 --> 00:00:18,420
+بتلاحظوا مقارنة في ال .. في ال alkanes لما حكينا
+
+3
+00:00:18,420 --> 00:00:21,380
+عن التفاعل .. التفاعلات بتاعي تقولنا ال alkanes
+
+4
+00:00:21,380 --> 00:00:27,130
+innerوحكينا تفاعلات بعشر دقائق وربع ساعة و سكرنا
+
+5
+00:00:27,130 --> 00:00:31,610
+بينما ال alkanes they are very reactive يعني هي
+
+6
+00:00:31,610 --> 00:00:37,670
+تالت محاضرة و احنا بنشرح التفاعلات ال alkanes
+
+7
+00:00:37,670 --> 00:00:41,450
+واضح؟ فتفاعلاتها كثيرة الحقيقة they are reactive
+
+8
+00:00:42,470 --> 00:00:48,350
+أخذنا طبعا على ال الكينز تفاعلات الإضافة سواء
+
+9
+00:00:48,350 --> 00:00:52,150
+إضافة أشياء متماثلة أو إضافة أشياء غير متماثلة
+
+10
+00:00:52,150 --> 00:00:57,590
+إضافة الهيدروجين إضافة البروم إضافة الماء إضافة ال
+
+11
+00:00:57,590 --> 00:01:05,680
+HPR تكوين ال epoxides تكسير ال epoxides واضح؟هي
+
+12
+00:01:05,680 --> 00:01:09,320
+هذا تقريبا الكلام اللي أخدناه الان اليوم موضوعنا
+
+13
+00:01:09,320 --> 00:01:14,540
+formation of diols تحديدا one two diols معنى all
+
+14
+00:01:14,540 --> 00:01:20,220
+المركب اللي فيه OH ال alcohol زي ميثانول إيثانول
+
+15
+00:01:20,220 --> 00:01:26,100
+بروبانول فيه OH فالمجموع الواضح في ال alcohol هي
+
+16
+00:01:26,100 --> 00:01:31,140
+مجموعة إيش ال all لما يكون عندى diols معنى ذلك
+
+17
+00:01:31,140 --> 00:01:37,750
+مركبات فيهاتنتيل OH مش واحدة OH واضح؟ لما بنقول
+
+18
+00:01:37,750 --> 00:01:43,570
+one two dials معناه ذلك التنتيل OH جانب بعض التنتو
+
+19
+00:01:43,570 --> 00:01:49,250
+.. التنتيل OH جانب بعض الآن خليكم منتبهين معي مش
+
+20
+00:01:49,250 --> 00:01:54,370
+ضروري انه يكون معنى one two dials انه التنتيل OH
+
+21
+00:01:54,830 --> 00:01:58,750
+واحدة منهم على موقع واحد وواحدة منهم على موقع
+
+22
+00:01:58,750 --> 00:02:02,750
+اتنين لأ لأ مافيش علاقة دايما لما بنقول one two
+
+23
+00:02:02,750 --> 00:02:06,850
+dioles او مثلا نقول one two addition معنى ذلك
+
+24
+00:02:06,850 --> 00:02:10,730
+التنتين جايات جنب بعض بمعنى ممكن يكونوا اتنين و
+
+25
+00:02:10,730 --> 00:02:14,790
+تلاتة و لا بعض ممكن يكونوا تلاتة و اربعة ممكن
+
+26
+00:02:14,790 --> 00:02:18,510
+يكونوا اربعة و خمسة مش الزام انه كلمة one two
+
+27
+00:02:18,510 --> 00:02:23,400
+dioles ان التنتين يكونوا ايشو احد و اتنين يعني
+
+28
+00:02:23,400 --> 00:02:26,680
+مثلا لو حطيت هنا تلت ذرات وهي كمان ذرتين و كمان
+
+29
+00:02:26,680 --> 00:02:31,720
+تلت ذرات كدهش المجموعة تمانية تلاتة انكوا حاطين
+
+30
+00:02:31,720 --> 00:02:35,840
+تلت كربونات و بعدين اربعة خمسة ستة سبعة تمانية و
+
+31
+00:02:35,840 --> 00:02:43,420
+جيت و قولتلكم four five dihydroxy مثلا octane is
+
+32
+00:02:43,420 --> 00:02:49,980
+an example of a one two diolواضح؟ هو مثال على one
+
+33
+00:02:49,980 --> 00:02:54,380
+two diol بمعنى أن المجمعتين موجودات على موقعين
+
+34
+00:02:54,380 --> 00:02:59,460
+متتاليين، هاي معنى كلمة one two diol مش معناها أنه
+
+35
+00:02:59,460 --> 00:03:05,670
+تحديدا في الجزء على موقع واحد وعلى موقع اتنينبنحصل
+
+36
+00:03:05,670 --> 00:03:10,730
+عليهم بطريقتين من خلال two different reagents ال
+
+37
+00:03:10,730 --> 00:03:16,010
+reagent الأول ال Osmium Oxide Osmium O4 و ال
+
+38
+00:03:16,010 --> 00:03:21,350
+Osmium هو معدن من المعادن الثقيلة بالعكس هو تقريبا
+
+39
+00:03:21,350 --> 00:03:27,590
+أثقل معدن يعني بكثافة ابتصل لواحد وعشرين وكسر
+
+40
+00:03:27,590 --> 00:03:35,570
+تقريبا اجرام لكل سنتمتر مكعب واضح؟يعني لو كنتوا
+
+41
+00:03:35,570 --> 00:03:40,210
+بتكون .. تحمله liter منه .. لو كنتوا بتكون تحمله
+
+42
+00:03:40,210 --> 00:03:43,750
+liter منه، معناه ذلك هذا ال liter بدي يكون وزنه
+
+43
+00:03:43,750 --> 00:03:49,350
+واحد و عشرين كيلو جرام، لاحظوا liter الميه كام
+
+44
+00:03:49,350 --> 00:03:55,050
+وزنه؟ كيلو جرام واحد، مظبوط ولا لا؟ liter الزئبق،
+
+45
+00:03:55,050 --> 00:03:58,730
+كداش وزنه؟ كتير مار عليكم
+
+46
+00:04:01,880 --> 00:04:07,200
+تلتاش وستة من عشرة الكثافة، كثافة الزباق، يعني لتر
+
+47
+00:04:07,200 --> 00:04:13,260
+الزباق تلتاش وستة من عشرة كيلو جرام، لتر الدهب،
+
+48
+00:04:13,260 --> 00:04:20,360
+المفروض تعرفوه، حوالي عشرين كيلو جرامواضح؟ عشان
+
+49
+00:04:20,360 --> 00:04:24,520
+هيك لما .. زمان كنتوا تقرأوا في القصص أنه الصياد
+
+50
+00:04:24,520 --> 00:04:31,820
+مثلا لجى جرة و الجرة فيها ملانة دهب فحملها فرحا و
+
+51
+00:04:31,820 --> 00:04:35,320
+حاطيله هيك حامل الجرة و مروح هو لو عنده جر الدهب
+
+52
+00:04:35,320 --> 00:04:41,040
+فيها عشرين كيلو جرام، كدهش بده يكون وزن الجرة؟
+
+53
+00:04:41,040 --> 00:04:45,520
+عشرين في عشرين؟ اربعمية كيلو جرام، مين بيقدر يحمل
+
+54
+00:04:45,520 --> 00:04:50,290
+اربعمية كيلو جرام هيك بين اديه و يروح؟اللي جابنا
+
+55
+00:04:50,290 --> 00:04:54,470
+لها الكلام انه لما تمر عليكم الشغلات مرات تتبهولا
+
+56
+00:04:54,470 --> 00:04:58,430
+الأزوميوم O4 تقريبا أثقل المعادل لو أخدنا هذا
+
+57
+00:04:58,430 --> 00:05:01,730
+الأزوميوم O4 مع السوديوم هيدروجين سولفايد في وجود
+
+58
+00:05:01,730 --> 00:05:07,590
+الميه بيعملوا إضافة مجموعتين OH والإضافة بتكون من
+
+59
+00:05:07,590 --> 00:05:11,450
+جهة واحدة sin addition سبق إن حكينا لكم زي من جهة
+
+60
+00:05:11,450 --> 00:05:16,090
+واحدة هذه إيش sin addition من جهتين متعاكستين anti
+
+61
+00:05:16,090 --> 00:05:20,670
+additionفي عندي sin addition وفي عندي anti
+
+62
+00:05:20,670 --> 00:05:24,950
+addition اتذكروا لما أخدنا إضافة الهيدروجين قولنا
+
+63
+00:05:24,950 --> 00:05:28,310
+الهيدروجين addition is sin addition لما أخدنا
+
+64
+00:05:28,310 --> 00:05:33,070
+إضافة البرومين البرومين addition is anti addition
+
+65
+00:05:33,070 --> 00:05:38,990
+الآن إضافة مجموعتي ال OH من خلال الوزوميوم O4 في
+
+66
+00:05:38,990 --> 00:05:43,250
+وجود ال Sodium Hydrogen Sulphide أو من خلال
+
+67
+00:05:43,250 --> 00:05:49,080
+التفاعل مع الكئمن O4 البوتاسيومبرمجانات في basic
+
+68
+00:05:49,080 --> 00:05:54,360
+medium في OH minus بيعملي sin addition بضيف
+
+69
+00:05:54,360 --> 00:05:59,840
+المجمعتين ومن جهة واحدة مرات كتير .. مرات كتير
+
+70
+00:05:59,840 --> 00:06:03,340
+انتوا لما بتكونوا تحفظوا و بتكونوا تكملوا معادلات
+
+71
+00:06:03,340 --> 00:06:06,960
+بتاخدوا double bond و بتحفظوا هنا كلمة K من O4 و
+
+72
+00:06:06,960 --> 00:06:12,460
+بتقولوا بتحط مجمعتينالحقيقة هنا لأ بدياكوا تنتبهوا
+
+73
+00:06:12,460 --> 00:06:18,760
+الكيمان O4 بتتفاعل بطريقتين مختلفتين تماما في وجود
+
+74
+00:06:18,760 --> 00:06:24,560
+ال basic medium OH minus بتعطي مجموعتين OH على جهة
+
+75
+00:06:24,560 --> 00:06:28,320
+واحدة بعد شوية ان شاء الله في المحاضرة هذه هناخد
+
+76
+00:06:28,320 --> 00:06:35,130
+ان في وجود H plusالحامض بتكسر الالكين بطريقة معينة
+
+77
+00:06:35,130 --> 00:06:39,250
+فمابديش احفظ التفاعل انه تفاعل الالكين مع الكئمن
+
+78
+00:06:39,250 --> 00:06:47,110
+O4 لأ بدي احفظ انه تفاعل الالكين مع الكئمن O4 in
+
+79
+00:06:47,110 --> 00:06:51,570
+basic medium في وجود ال OH- لأن بعد شوية في وجود
+
+80
+00:06:51,570 --> 00:06:57,970
+ال H plusهتعطيكوا تفاعل مختلف تماما واضح هدول ال
+
+81
+00:06:57,970 --> 00:07:02,110
+two reagents اللي بيكونولي one two diol وزي ما
+
+82
+00:07:02,110 --> 00:07:08,770
+اتفقنا ان ال addition is sin addition بمعنى إضافة
+
+83
+00:07:08,770 --> 00:07:14,090
+من جهة واحدة طبعا اللي بيخلي ال addition تكون sin
+
+84
+00:07:14,090 --> 00:07:18,990
+addition لو أخدنا كمثال ال camon O4 في ال camon O4
+
+85
+00:07:18,990 --> 00:07:26,050
+المنغنيز متصل باربع ذراتأكسوجين واضح و هيجوا تنتين
+
+86
+00:07:26,050 --> 00:07:29,730
+منهم يتفاعلوا الآن هل من الممكن يعني لو اتخيلتوا
+
+87
+00:07:29,730 --> 00:07:32,150
+ان هاي مثلا هنا المنجانيز في ال center هاي واحد
+
+88
+00:07:32,150 --> 00:07:35,930
+اتنين تلاتة اربعة نفترض هل من الممكن ان انا اقدر
+
+89
+00:07:35,930 --> 00:07:40,350
+اضيف زي هيك من جهتين مختلفتين طالما كلهم مربطين
+
+90
+00:07:40,350 --> 00:07:44,790
+بذرة مركزية يعني لما نكون عند امن او فور هاي
+
+91
+00:07:44,790 --> 00:07:48,650
+المنجانيز في النص و هاي الامن او فور و بدى اضيف
+
+92
+00:07:48,650 --> 00:07:53,780
+تنتين منهمبدهم ييجيوا يضيفوا بهذا الشكل هل ممكن ان
+
+93
+00:07:53,780 --> 00:07:57,140
+واحد اضيف من هنا و التانية من وراه فلأن كلهم
+
+94
+00:07:57,140 --> 00:08:02,360
+مرتبطين الأربع ذرات أكسجيل بالمانجاليز بيضيفوا
+
+95
+00:08:02,360 --> 00:08:07,700
+تنتين منهم من جهة واحدة فبيعطينا ال sin addition
+
+96
+00:08:07,700 --> 00:08:11,500
+عشانك لو كان عندي Cyclohexane ولا Cyclobutane ولا
+
+97
+00:08:11,500 --> 00:08:15,640
+Cyclooctane وبدو كترسم الاتجاه دبعهم لاحظوا ال
+
+98
+00:08:15,640 --> 00:08:19,140
+stereo chemistry الشكل بالفراغ التنتين يا بيكونوا
+
+99
+00:08:19,140 --> 00:08:22,960
+لقداميا بيكونوا لورا في الحالتين هذا يعتبر نفس
+
+100
+00:08:22,960 --> 00:08:26,200
+المركب في هذه الحالة اللي هو sin addition بس
+
+101
+00:08:26,200 --> 00:08:31,820
+مابيكونش واحدة لقدام واحدة لورا اللي هو anti
+
+102
+00:08:31,820 --> 00:08:37,980
+addition .. اللي هو anti additionلو هنا قلنا لكم
+
+103
+00:08:37,980 --> 00:08:42,760
+اكمل المعادلات موضوع سهل هيضاف ال bond مع ال
+
+104
+00:08:42,760 --> 00:08:47,640
+osmium O4 لاحظوا مجموعتين ال OH كيف رسمناهم على
+
+105
+00:08:47,640 --> 00:08:51,920
+جهة واحدة عملنا sin addition Cyclopentane مثلا
+
+106
+00:08:51,920 --> 00:08:56,220
+بالكامن O4 in basic medium انتوا لاحظين كلمة ال
+
+107
+00:08:56,220 --> 00:09:00,080
+basic medium برضه إضافة مجموعتين ال OH من جهة
+
+108
+00:09:00,080 --> 00:09:08,280
+واحدةهنا بدكم تتذكروا ان هذا ليس أول مرة ناخد فيها
+
+109
+00:09:08,280 --> 00:09:13,040
+احنا تكوين ال 1,2-Diol المحاضرة الماضية أخذنا
+
+110
+00:09:13,040 --> 00:09:17,800
+تكوين 1,2-Diol من خلال ان احنا من الالكين بداية
+
+111
+00:09:17,800 --> 00:09:23,080
+اعملنا الابوكسايد بعد هيك الابوكسايد باضافة الماء
+
+112
+00:09:23,080 --> 00:09:29,440
+في وجود الحامض كان بيفتحبهذا الشكل متذكرين؟ ال a
+
+113
+00:09:29,440 --> 00:09:34,800
+لما هذا المكان العلوي كله مسكر .. مسكر بوجود ال
+
+114
+00:09:34,800 --> 00:09:40,960
+oxygen الميه مضطرة تيجي من وين؟ من اتجاه المعاكس،
+
+115
+00:09:40,960 --> 00:09:45,800
+مظبوط ولا لا؟ من عند وين؟ اتجاه المعاكس، من عند
+
+116
+00:09:45,800 --> 00:09:51,450
+فصل القاسم، وبناء على ذلك ماشي بتعمل؟تنتن أو أتش
+
+117
+00:09:51,450 --> 00:09:57,150
+بأي mood of addition أنتي addition واضح؟ إذا لو
+
+118
+00:09:57,150 --> 00:10:00,890
+أنا إجيت لان جيبتلكوا السؤال و قولتولكوا حضرولي ال
+
+119
+00:10:00,890 --> 00:10:07,410
+1,2 ديول بسن addition في عندكم الطريقة كيامان أو
+
+120
+00:10:07,410 --> 00:10:10,510
+فور باسيك ميديام أو أزوميام أوفور لو قولتلكوا
+
+121
+00:10:10,510 --> 00:10:18,350
+بدياها في ال anti addition من نفس الألكين أول إش
+
+122
+00:10:18,350 --> 00:10:24,400
+من الألكينبدا اكوّن الابوكسايد كيف كنا نكونه الكين
+
+123
+00:10:24,400 --> 00:10:29,120
+بير أسد بيعطينا الابوكسايد بعدين الابوكسايد بنعمله
+
+124
+00:10:29,120 --> 00:10:35,180
+ring opening اللي هو فتح الحلقة في وجود H بلس H2O
+
+125
+00:10:35,180 --> 00:10:41,680
+بتفتح وبيعطينا ال Anti-addition الان هذا التفاعل
+
+126
+00:10:41,680 --> 00:10:47,820
+التاني لل الكين مع ال KMnO4 اللي انا قلتلكم بيعمل
+
+127
+00:10:49,240 --> 00:10:54,880
+تكسير للـ Double Bond هذا التفاعل اللي بالـ Acidic
+
+128
+00:10:54,880 --> 00:11:01,920
+Medium Oxidation of Alkenes by Acidic MnO4- لو
+
+129
+00:11:01,920 --> 00:11:05,520
+إحنا إجينا عملنا .. خلّيني أنظر في الأول المعادلة
+
+130
+00:11:05,520 --> 00:11:10,460
+اللي تحت إحنا إجينا عملنا Oxidation لألكين بالـ
+
+131
+00:11:10,460 --> 00:11:15,080
+MnO4 في وجود الحامض بيكسر الـ Double Bond اللي
+
+132
+00:11:15,080 --> 00:11:21,140
+موجود هنا من النصبتكسرها من النصف هذي تخلوها C
+
+133
+00:11:21,140 --> 00:11:25,460
+double bond O وهذه تخلوها C double bond O يعني
+
+134
+00:11:25,460 --> 00:11:29,060
+عندما أعمل الناتج ببساطة بدي أكسر هذه من النصف
+
+135
+00:11:29,060 --> 00:11:34,460
+يصير عند RCR وهذا C double bond O وRCR وC double
+
+136
+00:11:34,460 --> 00:11:39,160
+bond O بهذا الشكل الكمان أفور بكسر ال double bond
+
+137
+00:11:39,160 --> 00:11:46,260
+واضح؟ الآن هذا الكسر هذا الكسر لل double bondهو
+
+138
+00:11:46,260 --> 00:11:51,860
+أول خطوة في التفاعل إذا كانت المجموعات هذه R كلها
+
+139
+00:11:51,860 --> 00:11:58,440
+بمعنى مثل اثل بروبل بيوتل أي ان كانت يقف التفاعل
+
+140
+00:11:58,440 --> 00:12:03,660
+بهذا الشكل يعني بس بتعملوا الكسر ثم يقف التفاعل
+
+141
+00:12:03,660 --> 00:12:08,160
+واضح طب إيش في احتمال على أي كربونا أنه يكون غير
+
+142
+00:12:08,160 --> 00:12:15,860
+ال R و ال R ممكن يكون عندي H و H أو R و Rأو
+
+143
+00:12:15,860 --> 00:12:22,500
+الاحتمال التالت مين بدى تحكيلنا يا او R أو H 100%
+
+144
+00:12:22,500 --> 00:12:31,200
+واضح يا بدى يكون عندى H و H او R و R او R و H اذا
+
+145
+00:12:31,200 --> 00:12:36,120
+كان عندى المجموعات R و R بتم كسر لتن تن C double
+
+146
+00:12:36,120 --> 00:12:43,930
+bond O ولا يحصل اي تفاعل اضافى اذا كان عندىH وH
+
+147
+00:12:43,930 --> 00:12:48,790
+بيصير عندى C double bond O وحملة H وH فى الخطوة
+
+148
+00:12:48,790 --> 00:12:52,990
+الأولى الكمن و for هذا المركب بيأكسد و إضافة
+
+149
+00:12:52,990 --> 00:12:59,150
+بيطلعوا إيش فى الآخر ثالث أكسيد كربون واضح إيش
+
+150
+00:12:59,150 --> 00:13:05,630
+بيطلعوا ثالث أكسيد كربون إذا لو عندى أنا CHH شو
+
+151
+00:13:05,630 --> 00:13:09,490
+الناتج تبعها اللى بدى يتكون عندى ثالث أكسيد كربون
+
+152
+00:13:09,490 --> 00:13:20,270
+واضحطيب لو عندى RCH بدا تصير R C double bond O H
+
+153
+00:13:20,270 --> 00:13:25,150
+فى الخطوة الأولى هذا الديهيد بيأكسد الكيامان O4
+
+154
+00:13:25,150 --> 00:13:33,550
+بخطوة إضافية بيخليه حامض واضح فال CH2 بتصير CO2
+
+155
+00:13:45,300 --> 00:13:52,260
+والـ RCRبيبقى زي ما هي R C double bond O R واضح
+
+156
+00:13:52,260 --> 00:13:57,860
+اذا انتوا لو اتياكم اي مركب و بدنا نعمله تكسير في
+
+157
+00:13:57,860 --> 00:14:01,440
+ال KMnO4 صح احنا عارفين انه بالخطوة الاولى بدنا
+
+158
+00:14:01,440 --> 00:14:04,700
+نعمل C double bond O و C double bond O هذا كلام
+
+159
+00:14:04,700 --> 00:14:09,360
+مافيش عليه خلاف لكن بيصير عندى further oxidation
+
+160
+00:14:09,360 --> 00:14:14,920
+يعني تاكسد اضافي لان ال KMnO4 عامل مؤكسد قوي ايش
+
+161
+00:14:14,920 --> 00:14:19,980
+تاكسد الاضافة اي CH2النتيجة النهائية بتاعتها ايش
+
+162
+00:14:19,980 --> 00:14:29,800
+بتكون؟ CO2 IRCH النتيجة النهائية بتاعتها RCOOH
+
+163
+00:14:29,800 --> 00:14:36,980
+و IRCR بظلة زي ما هي RCOOR فلو جيبنا لكوا أي خلية
+
+164
+00:14:36,980 --> 00:14:40,540
+من هذه المراكبات يعني مثلا لو هذا المراكب اللي
+
+165
+00:14:40,540 --> 00:14:44,980
+رسمناه كنا حاطين هنا R و R و حاطنا لكوا من كيعمن
+
+166
+00:14:44,980 --> 00:14:45,640
+O4
+
+167
+00:14:50,300 --> 00:14:55,520
+هتكسروا الى جزءين هذا الجزء الاول شو هيعمل هيظله
+
+168
+00:14:55,520 --> 00:15:09,040
+زى ما هو R C double bond O R و الجزء التانى R C
+
+169
+00:15:09,040 --> 00:15:15,800
+double bond O O H واضح بهذا الشكل
+
+170
+00:15:28,220 --> 00:15:37,280
+الان شغلة إضافية ال الكينز نفسها ممكن تتكسر تكسر
+
+171
+00:15:37,280 --> 00:15:43,900
+شبيه باستعمال الأوزون بتعرفوا الأوزون اللي بنسميه
+
+172
+00:15:43,900 --> 00:15:48,380
+الاتروبوف أكسجين يعني الأكسجين في وضعه الطبيعي في
+
+173
+00:15:48,380 --> 00:15:57,810
+الدنيا O2 في صورة تانية له O3هذه الصور للعنصر
+
+174
+00:15:57,810 --> 00:16:01,510
+الواحد بس اللي بتختلف بشكل وجوده في الطبيعة
+
+175
+00:16:01,510 --> 00:16:09,650
+بنسميها الوتروبز أو بالعرب شو بتسموها؟ نظائر لا
+
+176
+00:16:09,650 --> 00:16:15,910
+نظائر ايزوتوبز وموضوعها مختلف اتفاق في عدد
+
+177
+00:16:15,910 --> 00:16:19,430
+البروتونات واختلاف في عدد النيوترونات هذه ايزوتوبز
+
+178
+00:16:19,430 --> 00:16:29,740
+الوتروبز مش ايزوتوبز الوتروبزمر عليكم؟ Allotropes
+
+179
+00:16:29,740 --> 00:16:34,700
+من أمثلتها ال O2 و ال O3 من أمثلتها في الكربون،
+
+180
+00:16:34,700 --> 00:16:40,000
+مين اتذكرنا؟ اه كيف الكربون في الطبيعة؟ ال
+
+181
+00:16:40,000 --> 00:16:46,400
+graphite و ال diamond ال diamond هو ال mass و C60
+
+182
+00:16:46,400 --> 00:16:51,920
+كرة الكربون ستين إذا سمعتوا أنا ماسمعتوش من أوض
+
+183
+00:16:51,920 --> 00:16:57,510
+نحكيلكوا عنهاGraphite و Diamond و C60 من أمثلتها
+
+184
+00:16:57,510 --> 00:17:03,090
+بالفوسفور تبع الحرب ايش الصور اللي بنوجد عليها
+
+185
+00:17:03,090 --> 00:17:10,930
+الفوسفور بالطبيعة؟ الأبيض و الأحمر ايش اللي
+
+186
+00:17:10,930 --> 00:17:18,310
+انخبطوا فيه؟ أه الأبيضوالأحمر طبعا الاختلاف بينهم
+
+187
+00:17:18,310 --> 00:17:22,570
+كيف الذرات بتكون متركبة مع بعض واضح هذه الأشياء
+
+188
+00:17:22,570 --> 00:17:27,630
+بنسميها Allotropes أو صور تهاصل يحصل الان إذا
+
+189
+00:17:27,630 --> 00:17:31,910
+فعلنا ال double bond مع ال allotrope تبع ال oxygen
+
+190
+00:17:31,910 --> 00:17:34,350
+ال O2 اللي هو ال O3 الأوزون
+
+191
+00:17:36,980 --> 00:17:43,720
+وأكمل التفاعل مع الزنك في وجود حامض النتيجة
+
+192
+00:17:43,720 --> 00:17:47,820
+النهائية أسهل من المثال السابق تبع الكمان او فورت
+
+193
+00:17:47,820 --> 00:17:52,780
+ايا كان عندى بدأ تنكسر هذه الرابط و تعمل cw.o وcw
+
+194
+00:17:52,780 --> 00:17:58,540
+.o بدون ما تعمل further oxidation يعني في حالة
+
+195
+00:17:58,540 --> 00:18:02,770
+الكمان او فورت لما كان عندى CH2 كنت اردتأكسد
+
+196
+00:18:02,770 --> 00:18:08,230
+المُركّب درجة إضافية واصلة لـ CO2 أو RCH أكسده لـ
+
+197
+00:18:08,230 --> 00:18:13,110
+R C double bond O H الأن هنا لأ الناتج اللى بيطلع
+
+198
+00:18:13,110 --> 00:18:17,250
+عندى في التكسر بغض النظر عن ال intermediate يعني
+
+199
+00:18:17,250 --> 00:18:22,510
+هذه القطعة لاحظوا فيها H في الأساس ايش الناتج
+
+200
+00:18:22,510 --> 00:18:28,440
+بيطلع فين ال CHC double bond O غيرت فيها اشيزي ميا
+
+201
+00:18:28,440 --> 00:18:33,680
+بس كسرتها من النصف هاد ال CH2 شو بتصير CH2C double
+
+202
+00:18:33,680 --> 00:18:40,660
+bond O فكأنه .. كأنه هنا الأوزون عامل مؤكسب أضعف
+
+203
+00:18:40,660 --> 00:18:45,500
+من إيش ال camon O4 بمعنى بس بيكسر ال double bond
+
+204
+00:18:45,500 --> 00:18:53,180
+لتنتين C double bond O و بعد هيك و بعد هيك مابعملش
+
+205
+00:18:53,180 --> 00:18:59,440
+إيش إضافي ال camon O4بعمل شغل إضافي، واضح الكلام؟
+
+206
+00:18:59,440 --> 00:19:04,660
+هذا نتيجة التكثُر اللي بنسميه احنا ash و zonolysis
+
+207
+00:19:04,660 --> 00:19:08,180
+of alkanes طبعا بيمور عبر intermediate مش كتير
+
+208
+00:19:08,180 --> 00:19:10,460
+احنا مهتمين بتفاصيلها
+
+209
+00:19:14,620 --> 00:19:19,520
+هنا في عندى أمثلة مختلفة .. أمثلة مختلفة ممكن
+
+210
+00:19:19,520 --> 00:19:25,060
+نتطلع عليها بسرعة، المثال الأول هو ozonolysis،
+
+211
+00:19:25,060 --> 00:19:28,520
+ozone و رمرة واحد و رمرة اتنين zinc في وجود
+
+212
+00:19:28,520 --> 00:19:33,020
+الحامض، إيش اللي بدنا نعمله؟بناخد المُركّب زي ما
+
+213
+00:19:33,020 --> 00:19:40,100
+هو C double bond O و C double bond O المثال التالي
+
+214
+00:19:40,100 --> 00:19:44,300
+نفس الاشي و التالت و الرابع بس طبعا المثال التالت
+
+215
+00:19:44,300 --> 00:19:47,000
+عشان ال double bond في داخل حلقة و كذلك الرابع
+
+216
+00:19:47,000 --> 00:19:50,460
+بتفتح الحلقة يعني بيصير عندي C double bond O و C
+
+217
+00:19:50,460 --> 00:19:56,060
+double bond O بيصير عندي ring opening ملاحظين كيف
+
+218
+00:19:56,060 --> 00:20:00,340
+الحلقة الفتحت من هنا في نهاي كل double bond بتصير
+
+219
+00:20:02,190 --> 00:20:07,770
+وهل ال ozone بيعمل further oxidation لأ لما يكون
+
+220
+00:20:07,770 --> 00:20:12,130
+عنده H بيبقى H لو كانت CH2 بيبقى CH2 وما بيعمل ال
+
+221
+00:20:12,130 --> 00:20:14,210
+ozone further oxidation
+
+222
+00:20:19,320 --> 00:20:25,280
+بنجي لأ مثال إضافي على ال alkanes لكن هنا إحنا
+
+223
+00:20:25,280 --> 00:20:30,760
+بناخد نوع من ال alkanes مش double bond واحدة فيه،
+
+224
+00:20:30,760 --> 00:20:35,440
+فيه تنتين، واضح؟
+
+225
+00:20:35,440 --> 00:20:40,380
+الآن لو قولنا إن إحنا عندنا تنتين double bonds،
+
+226
+00:20:40,380 --> 00:20:48,850
+بدو يصير المركب بدل ما هو alkanes بدو يصيرواضح؟
+
+227
+00:20:48,850 --> 00:20:54,070
+اذا ان انا في عندى in double bond واحدة, die in
+
+228
+00:20:54,070 --> 00:20:57,630
+two double bonds, try in ..
+
+229
+00:21:07,440 --> 00:21:28,020
+تلاتة double bonds
+
+230
+00:21:28,020 --> 00:21:32,910
+و هكذاتنفصل بـ double bond يعني يكون عندي double
+
+231
+00:21:32,910 --> 00:21:39,060
+single double إذا ممكن يكون عندي double doubleاو
+
+232
+00:21:39,060 --> 00:21:43,900
+double single double او اكون بين ال two double
+
+233
+00:21:43,900 --> 00:21:49,160
+bonds اكتر من واحدة تنتين تلاتة اربعة كله بيصير
+
+234
+00:21:49,160 --> 00:21:53,420
+نفس الاشي يعني يكون عندى double bond single كمان
+
+235
+00:21:53,420 --> 00:21:57,260
+single واحدة او تنتين او تلاتة اي ان كانوا وبعدين
+
+236
+00:21:57,260 --> 00:22:01,600
+double bond تانية هذه الانواع التلاتة من ال
+
+237
+00:22:01,600 --> 00:22:08,360
+alkanes لها اسماء النوع الاول بيسموه cumulatedيعني
+
+238
+00:22:08,360 --> 00:22:15,700
+ورا بعض بالظبط .. cumulated .. cumulated ضايين
+
+239
+00:22:15,700 --> 00:22:22,080
+واضح؟ النوع التاني هو اللي عندنا هو محور النقطة
+
+240
+00:22:22,080 --> 00:22:25,340
+اللي بنحكيها الآن conjugated معناه conjugation
+
+241
+00:22:25,340 --> 00:22:30,390
+double singledouble إذا هذا النوع التالت اللي هو
+
+242
+00:22:30,390 --> 00:22:36,350
+دارسنا اليوم إيش اسمه conjugated diet وإله تفاعلات
+
+243
+00:22:36,350 --> 00:22:41,670
+خاصة فيه النوع التالت ابعيد عن بعضه منعزل عن بعضه
+
+244
+00:22:41,670 --> 00:22:47,330
+إيش بنسميه isolated بتعرف isolation عزل لما نقول
+
+245
+00:22:47,330 --> 00:22:53,390
+إنه في بني آدم isolated منعزل بنفعل بني آدم يكون
+
+246
+00:22:53,390 --> 00:23:00,690
+منعزل إجتماعيااه أبو .. وين بيكون منعزل؟ إذا كان
+
+247
+00:23:00,690 --> 00:23:04,890
+في مجتمع كافر لازم ينعزل، الآية بتقول و أعتزلكم
+
+248
+00:23:04,890 --> 00:23:09,170
+وما تدعونا من دون الله و أدعو ربي عسى الله أكون
+
+249
+00:23:09,170 --> 00:23:16,110
+بدعاه، ربي .. ايه مش هاطل؟ اجتماعي بالمناسبة في
+
+250
+00:23:16,110 --> 00:23:19,850
+المجتمع المسلم حتى لو فيه مشاكل
+
+251
+00:23:21,420 --> 00:23:26,200
+المسلم الذي يخالط الناس ويصبر على أذاههم خيره من
+
+252
+00:23:26,200 --> 00:23:29,660
+الذي لا يخالطهم ولا يصبر على أذاههم، عشانك مش لازم
+
+253
+00:23:29,660 --> 00:23:32,060
+نعزز الاجتماع، عشان فين قدش بتغلبوا في ال homework
+
+254
+00:23:32,060 --> 00:23:37,540
+لكن مش عاملين نعزز الاجتماع، الآن احنا اللي بدنا
+
+255
+00:23:37,540 --> 00:23:47,820
+ناخده تحديدا على ال conjugated ضايين إضافة HBRلأنه
+
+256
+00:23:47,820 --> 00:23:54,740
+إلها مواصفة معينة إضافة الـ HPR في وجود حامض بتعرف
+
+257
+00:23:54,740 --> 00:23:58,360
+إحنا إنه في وجود الحامض أول ما بيبدأ التفاعل H
+
+258
+00:23:58,360 --> 00:24:02,280
+Plus بتضيف على أحد الطرفين الآن اتخيلوا معاك،
+
+259
+00:24:02,280 --> 00:24:05,560
+تذكروا الكلام اللي أخدنا إذا ضافت الـ H Plus هنا،
+
+260
+00:24:05,560 --> 00:24:09,800
+شو بيصير؟ secondary carbocation إذا ضافت هنا
+
+261
+00:24:09,800 --> 00:24:16,420
+primary، الأول مفضل، secondary إذن هذا مش خلافأذا
+
+262
+00:24:16,420 --> 00:24:20,800
+الـ H plus بتضيف هنا بتكون له الـ secondary
+
+263
+00:24:20,800 --> 00:24:26,120
+carbocation هل ال secondary carbocation إذا لقى PR
+
+264
+00:24:26,120 --> 00:24:32,990
+minus بتفاعل وبناء على ذلك بيصير عند H و PRالاضافة
+
+265
+00:24:32,990 --> 00:24:37,750
+العادية اللى احنا اتعلمناها اضافة HPR على رابطة
+
+266
+00:24:37,750 --> 00:24:44,270
+زوجية الارياتورا لو ال PR minus اتأخر لما يصل
+
+267
+00:24:44,270 --> 00:24:49,450
+للايون الموجب ملاحظين انتوا ممكن يتأخر في التفاعل
+
+268
+00:24:49,450 --> 00:24:53,670
+لما يصل للايون الموجب بيصير عندى احتمال تانى انه
+
+269
+00:24:53,670 --> 00:24:57,990
+هنا انا في عندى هنا انا في عندى جنب هذا الموجب
+
+270
+00:24:57,990 --> 00:24:59,950
+الموجب قاعد بيستنى بده ايش
+
+271
+00:25:02,810 --> 00:25:08,190
+الموجب دائما يمثل شحنة مصيبة بده يتعادل بده سالب
+
+272
+00:25:08,190 --> 00:25:14,450
+فإذا لقى ال PR minus زي ما بيقولوا بها ونعمة بضيف
+
+273
+00:25:14,450 --> 00:25:19,550
+ال PR على طول طب إذا مالقاش ال PR minus بتيجي ال
+
+274
+00:25:19,550 --> 00:25:24,250
+double boot بتقول أنا كثافة إلكترونية بتلوف بهذا
+
+275
+00:25:24,250 --> 00:25:29,960
+الشكل بتعطي إلكتروناتواضح؟ الان لاحظوا .. لاحظوا
+
+276
+00:25:29,960 --> 00:25:34,040
+معنى لما ال double bond تلف بهذا الشكل تعطيه
+
+277
+00:25:34,040 --> 00:25:38,300
+إلكترونات محال هانا شو بده يصير عندى؟ Ion Moja
+
+278
+00:25:38,300 --> 00:25:45,580
+بجديد، إذا هي حلت مشكلة حقيقة ماحلتش مشكلة، بناء
+
+279
+00:25:45,580 --> 00:25:51,100
+على ذلك صارت عندى مشكلة جديدةهذا ال ايون الموجة
+
+280
+00:25:51,100 --> 00:25:56,720
+بالجديد إما بيلاقي PR- وبالتالي بتضيف بسرعة هذا
+
+281
+00:25:56,720 --> 00:26:00,880
+إذا ما لاجعش ممكن ال double bond ترجع و ترجع تكون
+
+282
+00:26:00,880 --> 00:26:07,400
+هذا الايون إذا كأنه هذا الايون اللي احنا بنسميه
+
+283
+00:26:07,400 --> 00:26:12,420
+قلل كتايون مر علينا في double bonds مجموعة القلل
+
+284
+00:26:12,420 --> 00:26:20,100
+القلل double bond CH2 زي هي كانت double bondCH2
+
+285
+00:26:20,100 --> 00:26:24,060
+هدى كانت مجموعة القلل مظبوط الان لو طلعته انا
+
+286
+00:26:24,060 --> 00:26:30,380
+double bond CH2 هدى قلل ولا لأ اه هدى القلل كتايل
+
+287
+00:26:30,380 --> 00:26:36,480
+بنقول عنه بيعمل resonance اش يعني resonance حركة
+
+288
+00:26:36,480 --> 00:26:40,000
+إلكترونات فقط عمرنا لما نسأل نقولكوا اش يعني
+
+289
+00:26:40,000 --> 00:26:44,300
+انكتوا اعطونى ترجمة العرب اعطونى المعنىلما أخدنا
+
+290
+00:26:44,300 --> 00:26:50,060
+ال resonance في أول فصل قلنا لكم ال resonance حركة
+
+291
+00:26:50,060 --> 00:26:54,840
+إلكترونات ال resonance حركة إلكترونات وكيف يعبر
+
+292
+00:26:54,840 --> 00:26:59,580
+عنه؟بالسهم اللي زي هيك اللي اسمه double headed
+
+293
+00:26:59,580 --> 00:27:03,340
+arrows فقط الإلكترونات اللي قاعدة بتتحرك هيك مرة و
+
+294
+00:27:03,340 --> 00:27:07,060
+بترجع هيك مرة فقط حركة إيش؟ إلكترونات الرانين
+
+295
+00:27:07,060 --> 00:27:11,720
+رانين إلكترونات بتكون تتحرك باتجاههم movement of
+
+296
+00:27:11,720 --> 00:27:16,320
+electrons واضح؟ فاللي بنقوله إحنا أن القليل
+
+297
+00:27:16,320 --> 00:27:20,500
+الكاتيون بيكون في عملية resonance هذا الكلام
+
+298
+00:27:20,500 --> 00:27:24,480
+بيخلّي بعد ما ضافة ال H على أول موقع ال PR يا
+
+299
+00:27:24,480 --> 00:27:30,340
+بضيفها موقع اتنينيعني على موقع اربعة اذا انا في
+
+300
+00:27:30,340 --> 00:27:37,340
+اضافة ال HBR ع ال conjugated دايين بلاحظ ان عنده
+
+301
+00:27:37,340 --> 00:27:44,760
+ناتجين اما انه يكون عنده one two additionأو one
+
+302
+00:27:44,760 --> 00:27:49,240
+four addition يا الإضافة بالتم على موقع و على اللي
+
+303
+00:27:49,240 --> 00:27:53,840
+بعده مباشرة يا بتضيف على موقع و على نمرة أربعة
+
+304
+00:27:53,840 --> 00:27:57,040
+بالنسبة له شوفتوا إيش تفسير ال one two و ال one
+
+305
+00:27:57,040 --> 00:28:00,940
+four addition اللي بنقولكوا فسروا انه على هذا
+
+306
+00:28:00,940 --> 00:28:06,980
+الضين ال conjugated ضين الناتجخليط من مركبين خليط
+
+307
+00:28:06,980 --> 00:28:10,680
+من ال one two addition و ال one four addition ماهو
+
+308
+00:28:10,680 --> 00:28:14,720
+السبب انه بتكون عندى قليل كتاين ال قليل كتاين
+
+309
+00:28:14,720 --> 00:28:18,920
+بيعمل resonance مرة لمو جبهال مرة لمو جبهال مرة
+
+310
+00:28:18,920 --> 00:28:23,120
+لمو جبهال مرة لمو جبهال يا ترى ال resonance بيقلل
+
+311
+00:28:23,120 --> 00:28:24,620
+الثبات ولا بيزيده؟
+
+312
+00:28:28,020 --> 00:28:32,160
+يعني بيكون more stable ولا less stable لما بيكون
+
+313
+00:28:32,160 --> 00:28:39,020
+في عندى resonance طيب خلينا نتخيل القاتل انه احنا
+
+314
+00:28:39,020 --> 00:28:46,610
+مروحين من السوق وحملين عشرة كيلوو بدنا نمشي تقريبا
+
+315
+00:28:46,610 --> 00:28:51,330
+500 متر للدار هل يا تورا احنا بنضل حاملين العشرة
+
+316
+00:28:51,330 --> 00:28:54,810
+كيلو بإيد واحدة ولا بنكون قاعدين نعمل resonance؟
+
+317
+00:28:54,810 --> 00:28:59,470
+لو صورنا أي بني أدم مروح بعشرة كيلو، إيش بيعمل؟
+
+318
+00:28:59,470 --> 00:29:02,190
+بيعمل resonance، مرة بالإيد هذه، مرة بالإيد هذه،
+
+319
+00:29:02,190 --> 00:29:06,010
+مرة بالإيد هذه، مرة بالإيد هذه فال resonance حقيقة
+
+320
+00:29:06,010 --> 00:29:13,650
+is a stabilizing effectهو تأثير تثبيتي بثبت الشحنة
+
+321
+00:29:13,650 --> 00:29:22,670
+بدل ما الشحنة على جهة واحدة بتكون الشحنة على جهتين
+
+322
+00:29:22,670 --> 00:29:28,610
+واضح؟ الان كل بني آدم .. كل بني آدم بيقدر يفهم
+
+323
+00:29:28,610 --> 00:29:33,990
+الموضوع بطريقته في موضوع ال resonanceواضح؟ كل بني
+
+324
+00:29:33,990 --> 00:29:37,870
+أدم بيقدر في موضوع ال resonance يفهم الموضوع
+
+325
+00:29:37,870 --> 00:29:44,950
+بطريقته اعطيكم مثال .. مثال من الحياة مثلا لو
+
+326
+00:29:44,950 --> 00:29:53,650
+افترضنا اتنين اخوة و عندهم ام او اب كبير بدوا خدمة
+
+327
+00:29:53,650 --> 00:30:00,810
+معينة ايش بتلاحظوا بواقع الناس؟بحاولوا يعملوا
+
+328
+00:30:00,810 --> 00:30:06,150
+resonance، انه والله خلّي أسبوع هنا و أسبوع هنا،
+
+329
+00:30:06,150 --> 00:30:11,430
+أسبوع هنا و أسبوع هنا، واضح؟ الآن هذا ال resonance
+
+330
+00:30:11,430 --> 00:30:16,650
+في وجهة نظرهم في الدنيا، ان هم ايش؟ بتريحوا هم أو
+
+331
+00:30:16,650 --> 00:30:22,110
+نسوانهم، بتريحوا من غلبة الأب أو الأم، مظبوط ولا
+
+332
+00:30:22,110 --> 00:30:26,620
+لا؟لكن الناس اللي بيفهم و شو بيعملوا؟ بيكونوا
+
+333
+00:30:26,620 --> 00:30:31,020
+يتقاتلوا مين يخلي الأب أو الام عنده، في قضية
+
+334
+00:30:31,020 --> 00:30:34,980
+مرفوعة بالمحاكم السعودية بين اتنين أخوة و حاطين
+
+335
+00:30:34,980 --> 00:30:38,740
+أكبر المحامين بتقاتلوا على أمهم، كل واحد بده أمه
+
+336
+00:30:38,740 --> 00:30:42,720
+تكون عنده يقدمها في العشر الأواخر زي ما بيقولوا من
+
+337
+00:30:42,720 --> 00:30:46,480
+العمر، و انتوا احسبوها عد ايش اللي بتعملوا بحياتكم
+
+338
+00:30:49,210 --> 00:30:52,990
+ما .. ما هو الان اللي بيكونوا ينقلوا الام و الأبو
+
+339
+00:30:52,990 --> 00:30:57,590
+بيقولوا بدهم ثبات إيش؟ بدهم ال resonance أو الثبات
+
+340
+00:30:57,590 --> 00:31:03,350
+اللي هو تبع الدنيا و اللي بده يحافظ عليهم طيب و
+
+341
+00:31:03,350 --> 00:31:11,550
+الآية إيش بتقول؟ و للآخرة خير و أبقى فمن الناس ما
+
+342
+00:31:11,550 --> 00:31:16,510
+يقولوا ربنا آتنا في الدنيا و ما له في الآخرةومنهم
+
+343
+00:31:16,510 --> 00:31:21,570
+من يقول ربنا أتنا في الدنيا حسنة وفي الآخرة حسنة
+
+344
+00:31:21,570 --> 00:31:28,810
+وقنا عذاب النهار والله سريع الحساب هذا الكلام نزل
+
+345
+00:31:28,810 --> 00:31:30,250
+في الآيات اللي هي إيش؟
+
+346
+00:31:33,690 --> 00:31:38,270
+في الآيات لبعد الحج مباشرة لأن العرب كانوا بعد
+
+347
+00:31:38,270 --> 00:31:42,630
+الحج مجرد ما يخلصوا الرجم وكل إشي يتجهوا باتجاه
+
+348
+00:31:42,630 --> 00:31:46,590
+جبل عرفات هم في مينة ويصيروا يدعوا ويتفاخروا
+
+349
+00:31:46,590 --> 00:31:50,950
+بالآباء والأجداد ولذلك الآية قالتلهم فإذا قضيتم
+
+350
+00:31:50,950 --> 00:31:56,330
+مناسككم فاذكروا الله كذكركم آباءكم أو أشد ذكرة
+
+351
+00:31:56,330 --> 00:32:01,110
+يعني يكون هدفكوا الآخرة مش الدنيا هم كانوا يحجوا
+
+352
+00:32:01,110 --> 00:32:06,870
+اخلصواإيش يقفوا يقولوا في نهاية الحجة؟ أبويا و
+
+353
+00:32:06,870 --> 00:32:11,910
+أبوك يتفخروا بالدنيا، الآية جالتلهم فاذكروا الله
+
+354
+00:32:11,910 --> 00:32:16,790
+كذكركم آباءكم أو أشد ذكره فمن الناس من يقولوا ربنا
+
+355
+00:32:16,790 --> 00:32:23,370
+آتنا فاتنا على أي حال، تفاعل إضافي، اتعبتم من
+
+356
+00:32:23,370 --> 00:32:27,210
+تفاعلات ال ال kids إذا جيبنالكم على السؤال صح و
+
+357
+00:32:27,210 --> 00:32:30,650
+غلط في الامتحان ال kids are inert و واحدة بتقول
+
+358
+00:32:30,650 --> 00:32:31,370
+مظبوط
+
+359
+00:32:34,370 --> 00:32:39,170
+الالكينز تفاعلاته مكتيرة جدا هذا التفاعل بنسميه
+
+360
+00:32:39,170 --> 00:32:43,630
+deals elder reaction deals elder reaction هو عبارة
+
+361
+00:32:43,630 --> 00:32:50,330
+عن تفاعل بنسميه cycle addition reaction ايش يعني
+
+362
+00:32:50,330 --> 00:32:55,110
+cycle addition reaction؟معنى cycle addition
+
+363
+00:32:55,110 --> 00:33:01,130
+reaction هو تفاعل بأكون أنا فيه رابطتين في نفس
+
+364
+00:33:01,130 --> 00:33:05,990
+الوقت، في نفس اللحظة، يعني لو افترضت أنا عند
+
+365
+00:33:05,990 --> 00:33:11,180
+قطعتين بهذا الشكلو إي جيت جربتهم جربتهم جربتهم على
+
+366
+00:33:11,180 --> 00:33:15,620
+بعض بهذا الشكل لحد ما صار رابطة لان أنا كام رابطة
+
+367
+00:33:15,620 --> 00:33:20,380
+قاعد بعمل بنفس اللحظة رابطتين هذا التفاعل اللي
+
+368
+00:33:20,380 --> 00:33:24,660
+بضيف قطعتين بنفس اللحظة و بكون two new sigma bonds
+
+369
+00:33:24,660 --> 00:33:30,520
+بسميه cycle addition reaction
+
+370
+00:33:30,520 --> 00:33:33,280
+و من هذه التفاعلات تفاعلات إيش
+
+371
+00:33:48,260 --> 00:33:52,440
+بينما لو انا كنت بدي اعمل حلقة معينة زي هيك بس
+
+372
+00:33:52,440 --> 00:33:59,170
+اسكر طرفينهابعمل رابطة واحدة
+
+373
+00:33:59,170 --> 00:34:02,190
+تفاعل
+
+374
+00:34:02,190 --> 00:34:03,030
+عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل
+
+375
+00:34:03,030 --> 00:34:03,510
+حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة
+
+376
+00:34:03,510 --> 00:34:05,210
+تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل
+
+377
+00:34:05,210 --> 00:34:12,710
+عمل حلقة تفاعل عمل حلقة تفاعل
+
+378
+00:34:12,710 --> 00:34:15,610
+عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل
+
+379
+00:34:15,610 --> 00:34:17,350
+تفاعل عمل حلقة تفاعل عمل حلقة تفاعل عمل حلقة تفاعل
+
+380
+00:34:17,350 --> 00:34:24,570
+عمل حلقة تفاعل عمل حcycloaddition واضح؟ إذا في
+
+381
+00:34:24,570 --> 00:34:28,410
+عندي نوعين لتكوين الحلقات يا إما cyclization من
+
+382
+00:34:28,410 --> 00:34:32,650
+خلال رابط واحدة يا إما cycloaddition من خلال
+
+383
+00:34:32,650 --> 00:34:38,190
+رابطتين ال deals under reaction هو أحد التفاعلات
+
+384
+00:34:38,190 --> 00:34:43,770
+ال cycloaddition المتعلقة بال double bonds ولذلك
+
+385
+00:34:43,770 --> 00:34:47,670
+احنا بندرسه هنا ليش بندرس ال deals under reaction
+
+386
+00:34:47,670 --> 00:34:53,630
+لأن هو تمين تفاعلاتالـ Double bonds من تفاعلات الـ
+
+387
+00:34:53,630 --> 00:34:56,210
+Double bonds طيب نشوف ايش هو ال deals under
+
+388
+00:34:56,210 --> 00:35:03,270
+reaction ال deals under reaction بتتم في تفاعل ال
+
+389
+00:35:03,270 --> 00:35:06,750
+one three دايين او ال conjugated دايين لاحظوا هذا
+
+390
+00:35:06,750 --> 00:35:11,390
+one two three four conjugated دايين مع double bond
+
+391
+00:35:11,390 --> 00:35:15,990
+يعني تنتين double bonds conjugated مع double bond
+
+392
+00:35:15,990 --> 00:35:19,730
+واحدة ايش النتيجة النهائية تكوين رابط اهان و رابط
+
+393
+00:35:19,730 --> 00:35:26,100
+اهانإذا كام رابطة؟ تن تن عشان ما تغلطوش في التعبير
+
+394
+00:35:26,100 --> 00:35:29,480
+عن الناتج بيقولولكوا تخيلوا انكوا حركتوا الرابطة
+
+395
+00:35:29,480 --> 00:35:33,040
+هذي زي هيك هذي زي هيك هذي زي هيك بتطلع عندى حلقة
+
+396
+00:35:33,040 --> 00:35:39,680
+سداسية فيها رابطة زوجية واحدة يعني كإنا بنقول ان
+
+397
+00:35:39,680 --> 00:35:43,420
+ال reaction of the one three ضايين هذا one two
+
+398
+00:35:43,420 --> 00:35:48,400
+threeone three-diene with an alkene with double
+
+399
+00:35:48,400 --> 00:35:53,880
+bond produces cyclohexane
+
+400
+00:35:53,880 --> 00:35:59,460
+..hexane in يعني فيه double bond واحدة لما بتكون
+
+401
+00:35:59,460 --> 00:36:02,980
+تحطوا الجواب صح أسهل إش تحركوا رابط هيك و رابط هيك
+
+402
+00:36:02,980 --> 00:36:07,970
+و رابط هيك حتى تكتبوا الجواب بسهولةهي عندى مثال
+
+403
+00:36:07,970 --> 00:36:11,430
+تانى هى تضيين هذا ال conjugated وهى double bond
+
+404
+00:36:11,430 --> 00:36:15,070
+حتى لو double bond كانت بحلقة مش مشكلة هى واحد
+
+405
+00:36:15,070 --> 00:36:20,010
+اتنين تلاتة هذه اللى بده تصير ال new sigma bond
+
+406
+00:36:20,010 --> 00:36:23,390
+هنا هذه اللى بده تصير ال new sigma bond هنا و هذه
+
+407
+00:36:23,390 --> 00:36:28,490
+اللى بده تتحرك هنا طلع عندى برضه cyclohexane ولو
+
+408
+00:36:28,490 --> 00:36:33,640
+متحد مع حلقة تانية هذا التفاعل شو بنسميه احناdeals
+
+409
+00:36:33,640 --> 00:36:38,600
+elder reaction او deals elder cycloaddition
+
+410
+00:36:38,600 --> 00:36:44,540
+reaction فاذا قلنالكم deals elder reaction is a
+
+411
+00:36:44,540 --> 00:36:50,220
+cyclizing reaction او cyclization reaction خطأ هو
+
+412
+00:36:50,220 --> 00:36:55,900
+cycloaddition a reaction in which two new sigma
+
+413
+00:36:55,900 --> 00:37:03,510
+bondsare formed at the same time اني بكون رابطتين
+
+414
+00:37:03,510 --> 00:37:08,950
+مش رابطة واحدة هم لاحظين هى و هنا اجت رابطة و هنا
+
+415
+00:37:08,950 --> 00:37:14,170
+اجت رابطة we are forming two new sigma bonds
+
+416
+00:37:28,040 --> 00:37:37,740
+من التفاعلات الإضافية المهمة جدا لـAlkenes
+
+417
+00:37:37,740 --> 00:37:42,080
+وتحديدا ممكن ناخد لأبسط Alkenes اللي هو الاثيليين
+
+418
+00:37:42,080 --> 00:37:47,760
+تفاعل عمل Polymerإيش يعني polymer؟ بيكون عندى جزيق
+
+419
+00:37:47,760 --> 00:37:53,060
+واحد بسميه أنا monomer بتحد مع عدد كبير من
+
+420
+00:37:53,060 --> 00:37:57,480
+الجزيقات بيعمله سلسلة polymer يعني لو افترضت هدول
+
+421
+00:37:57,480 --> 00:38:02,400
+الأقلام الأربعة زي بعض وكل واحد فيهم عبارة عن إيش؟
+
+422
+00:38:02,400 --> 00:38:06,940
+إثالين، هاي monomer، monomer، monomer، monomerهذا
+
+423
+00:38:06,940 --> 00:38:10,720
+الإثالين لأنه جزء واحد بالوضع الطبيعي بيكون إيش؟
+
+424
+00:38:10,720 --> 00:38:15,840
+غاز، مظبوط ولا لا؟ مش الإثالين غاز وبيحطوه بالغرف
+
+425
+00:38:15,840 --> 00:38:20,820
+المغلقة على الموز الأخضر عشان يستوي، بتشوفوا الموز
+
+426
+00:38:20,820 --> 00:38:24,550
+لما بيجيبوه استيراد كيف بيكون لونه؟أخضر على الآخر،
+
+427
+00:38:24,550 --> 00:38:28,250
+هيك .. هيك لازم الموز ي .. ينقل لأنه بيخرب بسرعة،
+
+428
+00:38:28,250 --> 00:38:31,830
+الآن قبل ما ينزلوا على السوق بيحطوا ليلة بغرفة
+
+429
+00:38:31,830 --> 00:38:36,130
+مغلقة بيمرروا عليه غاز الاثيلين، بينضج، بيصير
+
+430
+00:38:36,130 --> 00:38:41,010
+أصفر، الآن هذا الاثيلين لو أجينا وحدنا عدة جزيئات
+
+431
+00:38:41,010 --> 00:38:46,990
+منه، هاي جزيئة اتنين، تلاتة، أربعة، بدأ يكبر،
+
+432
+00:38:46,990 --> 00:38:50,070
+يكبر، يكبر، صيرنا ألفين، تلاتة آلاف، بيصير
+
+433
+00:38:50,070 --> 00:38:54,710
+polymer، ال polymer هذا plasticاملاحظين؟ يعني أنا
+
+434
+00:38:54,710 --> 00:39:00,490
+ببدأ بغاز، بضغطه، بنتهي ب plastic اللي هو ال
+
+435
+00:39:00,490 --> 00:39:04,390
+plastic الأبيض اللي بيعمله منه كثير من القوانين
+
+436
+00:39:04,390 --> 00:39:08,710
+وغيره وغيراتها هذا اللي اسمه polyethylene يعني فيه
+
+437
+00:39:08,710 --> 00:39:11,750
+أكتر من جزء إيثيلين هذه العملية عملية
+
+438
+00:39:11,750 --> 00:39:16,370
+polymerization فال polymerization أنه يكون عنده
+
+439
+00:39:16,370 --> 00:39:22,640
+monomerبظروف معينة من الضغط من درجة الحرارة من
+
+440
+00:39:22,640 --> 00:39:26,100
+إضافة البروكسايد البروكسايد عشان التفاعل free
+
+441
+00:39:26,100 --> 00:39:30,080
+radical reaction المرة الماضية أخدنا البروكسايد
+
+442
+00:39:30,080 --> 00:39:35,200
+بيصير CH2 CH2 to the N و N هذه بتطلع إلى تلتة اربع
+
+443
+00:39:35,200 --> 00:39:39,460
+تلاف جزء مع بعض لما يصير تلتة اربع تلاف جزء مع بعض
+
+444
+00:39:39,460 --> 00:39:46,600
+الغاز بيصيرplastic solid مظبوط ولا لأ؟ هذا زي حال
+
+445
+00:39:46,600 --> 00:39:50,920
+.. زي حال الناس حتى يعني لما يكون بني آدم لوحده
+
+446
+00:39:50,920 --> 00:39:57,720
+المعارض مثلا أيمن نور إيش عمل فيه النظام المصري؟
+
+447
+00:39:57,720 --> 00:40:02,280
+زلوا لأنه لحاله غاز و حبس و هو كان مرشح رئيس
+
+448
+00:40:02,280 --> 00:40:09,770
+جمهورية لكن لما صار عندى بوليمار من كل الشعبصرت
+
+449
+00:40:09,770 --> 00:40:14,790
+أمام حالة صلبة، هذه الحالة الصلبة انهرت قدامها كل
+
+450
+00:40:14,790 --> 00:40:20,830
+الدنيا، وعشان هي كبيت الشعر، ايش بيقول؟ تقبل
+
+451
+00:40:20,830 --> 00:40:28,550
+رماحه، إذا اجتمعنا تكسره، وإذا افترقنا تكسرت غاز
+
+452
+00:40:28,550 --> 00:40:35,230
+ذاتي، غاز بيكونانتوا افهموا يعني ال polymers ال
+
+453
+00:40:35,230 --> 00:40:39,050
+polymers مش موضوع بسيط يعني بيقولوا أهم اكتشافات
+
+454
+00:40:39,050 --> 00:40:43,850
+يمكن القرن الماضي مرات بيحكوا تكوين ال polymers
+
+455
+00:40:43,850 --> 00:40:48,110
+يعني تكوين ال nylon و تكوين ال plastic و تكوين ال
+
+456
+00:40:48,110 --> 00:40:52,570
+polystyrene و تكوينها الأقمشة الصناعية كل هذه
+
+457
+00:40:52,570 --> 00:40:56,130
+الأشياء هي اللي اليوم هي اللي رابطة حياتنا يعني
+
+458
+00:40:56,130 --> 00:41:00,370
+هذا الجلم اللي تطلع عليه الآن هذا ال plasticقبل
+
+459
+00:41:00,370 --> 00:41:03,470
+سبعين سنة ماكنش فيه ماكنش فيه غير جلم الارصاص اللي
+
+460
+00:41:03,470 --> 00:41:07,350
+بعمله من الخشب وفي قلبه كربون كان عندى هذه الشغلات
+
+461
+00:41:07,350 --> 00:41:11,210
+ماكنش هذا السبورة ماكنتش هذا الإجماش ماكنش هذا ال
+
+462
+00:41:11,210 --> 00:41:14,690
+plastic ماكنش هذا ال plastic ماكنش هذا ال plastic
+
+463
+00:41:14,690 --> 00:41:17,990
+ماكنش اليوم كل حياتكو صارت مبنية على هذه الفكرة
+
+464
+00:41:17,990 --> 00:41:22,450
+البسيطة يعني مش فكرة صغيرة تتخيلوها أنه أنا قاعد
+
+465
+00:41:22,450 --> 00:41:31,800
+بعص غاز بخليه solid واضح؟يعني هي من أكبر الأفكار
+
+466
+00:41:31,800 --> 00:41:35,700
+اللي صارت في القرن العشرين فكرة تكوين ال polymers
+
+467
+00:41:35,700 --> 00:41:40,440
+صناعات لبلاستيك و الأنابيب زمان كانت الأنابيب كلها
+
+468
+00:41:40,440 --> 00:41:44,800
+يا إما يعملوها أحيانا من ال اسمنت ماعرفش إذا أنتوا
+
+469
+00:41:44,800 --> 00:41:48,660
+وعيين لهذا النوع من الأنابيب أو من الحديد يعني
+
+470
+00:41:48,660 --> 00:41:52,260
+اللي كانوا ينظروا للبيوت القديمة الأنابيب المجارة
+
+471
+00:41:52,260 --> 00:41:56,890
+من إيش كانت تكون؟من الحديد الظاهر اللي بيكسر،
+
+472
+00:41:56,890 --> 00:42:00,430
+الأنابيب تبعت المي اللي في الشوارع، من إيش كانت
+
+473
+00:42:00,430 --> 00:42:05,850
+تكون؟ إسمنت، إسمنت و أشياء زي هيك اليوم كل الدنيا
+
+474
+00:42:05,850 --> 00:42:10,650
+صارت plastic من ورا مثل هذا التفاعل البسيط فما
+
+475
+00:42:10,650 --> 00:42:14,190
+تفهموش الموضوع أنه بس يعني أنه احنا بنحكي رموز و
+
+476
+00:42:14,190 --> 00:42:20,110
+بس، لا احنا بنحكي واقع، واقع حياةالان هذا التفاعل
+
+477
+00:42:20,110 --> 00:42:24,210
+كيف بيتم، بزام احنا عندنا البروكسايد، البروكسايد
+
+478
+00:42:24,210 --> 00:42:28,570
+اول ما شوية حرارة بيعطينا ايش، بنكسر homolytic
+
+479
+00:42:28,570 --> 00:42:32,550
+cleavage، الحصة الماضية أخدناها بيعطينا2 free
+
+480
+00:42:32,550 --> 00:42:36,650
+radicals هذا ال free radical بيجي على ال double
+
+481
+00:42:36,650 --> 00:42:39,110
+bond اللي لها ال double bond اللي لها كام electron
+
+482
+00:42:39,110 --> 00:42:45,390
+اتنين هياخد التفاعل مع electron واحد صار عند ال RO
+
+483
+00:42:45,390 --> 00:42:51,130
+CH2 CH2 و هذه ال CH2 بترفنية شو طال عليها electron
+
+484
+00:42:51,130 --> 00:42:57,090
+مظبوط الآن خدوا هذا الجزء ال RO CH2 CH2 و عليها
+
+485
+00:42:58,500 --> 00:43:04,220
+free radical فعلوها مع جزء إيثالين جديد و خليها
+
+486
+00:43:04,220 --> 00:43:10,280
+تعمل رابطة هنا كبرة اتنين و على الطرف free radical
+
+487
+00:43:10,280 --> 00:43:14,580
+كمان مرة كمان مرة كمان مرة لانه واصل لتالتة اربع
+
+488
+00:43:14,580 --> 00:43:19,640
+تلاف جزء صار عند بوليمار طبعا عشانه غاز انا بحاجة
+
+489
+00:43:19,640 --> 00:43:23,760
+إلى حرارة بحاجة إلى البروكسايد اللي بده يبدأ
+
+490
+00:43:23,760 --> 00:43:28,450
+للتفاعلهذا الشرارة تاعت التفاعل تاعت free radical
+
+491
+00:43:28,450 --> 00:43:31,890
+reaction و هذا ال polymerization بالمناسبة شو
+
+492
+00:43:31,890 --> 00:43:37,130
+بيسموها free radical polymerization of ethylene
+
+493
+00:43:37,130 --> 00:43:40,350
+free radical polymerization of ethylene عشان
+
+494
+00:43:40,350 --> 00:43:45,520
+يعطينا ال polyethylene شوفتوا كيف بالتم؟الان
+
+495
+00:43:45,520 --> 00:43:51,020
+العلماء طموحهم مابيقفش يعني انا بدأت بال إيثيلين
+
+496
+00:43:51,020 --> 00:43:57,700
+وصارت الوحدة المتكررة عندى إيش هي CH2 CH2 CH2 CH2
+
+497
+00:43:57,700 --> 00:44:05,720
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+498
+00:44:05,720 --> 00:44:09,160
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+499
+00:44:09,160 --> 00:44:09,920
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+500
+00:44:09,920 --> 00:44:09,940
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+501
+00:44:09,940 --> 00:44:11,300
+CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2 CH2
+
+502
+00:44:11,300 --> 00:44:18,570
+CH2 CH2 CHحطيت مكانها chlorine يعني بمعنى ان الجزء
+
+503
+00:44:18,570 --> 00:44:24,630
+الاول يكون زي هيك بس انا حطيت chlorine هذا المركب
+
+504
+00:44:24,630 --> 00:44:30,590
+اسمه vinyl chloride اخدتوا انتوا مجموعة CH2 double
+
+505
+00:44:30,590 --> 00:44:34,410
+bond CH اسم المجموعة ال vinyl لما يكون معاها
+
+506
+00:44:34,410 --> 00:44:38,250
+chlorineVinyl chloride الان لو ال vinyl chloride
+
+507
+00:44:38,250 --> 00:44:43,270
+عملوله polymerization بشغل بنفس الطريقة بعملي CH
+
+508
+00:44:43,270 --> 00:44:50,210
+متصلة ب CL CH2 to the N بصير polyvinyl chloride ال
+
+509
+00:44:50,210 --> 00:44:56,030
+polyvinyl chloride له اسم شهره مختصر ايش بنختصره
+
+510
+00:44:56,030 --> 00:45:05,900
+PVC مين فيكم ماسمعش في plastic ال PVCلأ لأ أبدا
+
+511
+00:45:05,900 --> 00:45:09,660
+ولا ألياف بصرية ولا إشي شوفتوا الأرضيات اللي مرات
+
+512
+00:45:09,660 --> 00:45:13,040
+بيعملوا منها المستشفيات وغيرها و ال studio هذه
+
+513
+00:45:13,040 --> 00:45:18,260
+كلها PVC شوفتوا هذا ال plastic و هذا التبع الشاشة
+
+514
+00:45:18,260 --> 00:45:23,390
+و الشونات تبعتكوا ال plastic كل هذا ال PVCنوع ابن
+
+515
+00:45:23,390 --> 00:45:27,590
+عمه للبولي إيثنين واضح؟ ابن عمه للبولي إيثنين ال
+
+516
+00:45:27,590 --> 00:45:32,050
+BVC أشهر إشي بتلاقوا المحلات تابعون ال decor اللي
+
+517
+00:45:32,050 --> 00:45:37,850
+بيبيعوا ستاير بيكونوا كاتبين لبايع ال BVC اللي هو
+
+518
+00:45:37,850 --> 00:45:41,630
+ال plastic اللي بيفردوه على الأرض على ال studio
+
+519
+00:45:41,630 --> 00:45:46,230
+على المطبخ عمركوا شفته؟ يمكن الآن الناس مع روح
+
+520
+00:45:46,230 --> 00:45:51,500
+السعر لكراميكابطلوا يهتموا فيه بس قبل حوالي 15 سنة
+
+521
+00:45:51,500 --> 00:45:56,100
+كنتوا معظم المحلات التجارية لما تدخلوها اتلاقوها
+
+522
+00:45:56,100 --> 00:46:02,480
+حاطة على الأرض بدل هذا السجاد PVC هو هذا البوليمار
+
+523
+00:46:02,480 --> 00:46:10,460
+ممكن كمان يبدو باستايرين الاستايرين المرة الماضية
+
+524
+00:46:10,460 --> 00:46:15,160
+حكينالكوا عنه اللي هو CH2 ضم ال bond CH وعليه
+
+525
+00:46:15,160 --> 00:46:22,700
+مجموعة بنزينبلاحظين هذا اسمه إيش؟ استايرين ..
+
+526
+00:46:22,700 --> 00:46:27,320
+استايرين ال polymer تبعه زي ال إفلين بس بدل H بال
+
+527
+00:46:27,320 --> 00:46:33,280
+hot funnel بصير polystyrene، plastic برضه، ما
+
+528
+00:46:33,280 --> 00:46:38,310
+تخلطوهوش في ال polyesterبتعرفوا البوليستر أول ما
+
+529
+00:46:38,310 --> 00:46:43,970
+بتشتريه جماش، إيش بتقوله؟ قداش قطن و قداش بوليستر
+
+530
+00:46:43,970 --> 00:46:48,890
+و كل ما نسبة القطن صارت أعلى، بتعتبروه أجود، بس
+
+531
+00:46:48,890 --> 00:46:54,890
+اليوم ماحدش برضه بيقبل نسبة قطن مية في الميةالا
+
+532
+00:46:54,890 --> 00:46:58,950
+polyester يكون معه يعني يكون اربعين او خمسين او
+
+533
+00:46:58,950 --> 00:47:02,670
+ستين في المية قطن كويس اربعين في المية polyester
+
+534
+00:47:02,670 --> 00:47:06,490
+بس مايكونش مية في المية polyester مية في المية
+
+535
+00:47:06,490 --> 00:47:10,250
+polyester بيكون petrol يعني لو اجت نار بيولع على
+
+536
+00:47:10,250 --> 00:47:16,450
+طول بالحرارة شديد على الجسم مظبوط ولا لأ؟ بيكون
+
+537
+00:47:16,450 --> 00:47:20,850
+خليط من القطن و من ال polyester الآن ال polyester
+
+538
+00:47:20,850 --> 00:47:26,660
+غير ال polystyreneعشان انتوا ماتخربتوش polystyrene
+
+539
+00:47:26,660 --> 00:47:31,860
+بلاستيك معين البولي إستر بيناعمل منه ال fibers
+
+540
+00:47:31,860 --> 00:47:38,060
+الخطان و منه كل الأقمشة مافيش فينا حد في لبسه إلا
+
+541
+00:47:38,060 --> 00:47:41,980
+موجود بولي إستر لا يمكن مافيش حد لابس قطن كتمة ولا
+
+542
+00:47:41,980 --> 00:47:45,200
+بمصنع اليوم كل هذا الجماش اللي انتوا شايفينه
+
+543
+00:47:45,200 --> 00:47:49,140
+الجاكيتات اللي بصاريش غالبا مخلوطة الخطان بتاعتها
+
+544
+00:47:49,140 --> 00:47:52,700
+اربعين خمسين في المية قطن اربعين خمسين في المية
+
+545
+00:47:53,460 --> 00:47:58,380
+بولي إستر البولي إستر بمر علينا بعدين غير البولي
+
+546
+00:47:58,380 --> 00:48:01,740
+ستايرين البولي ستايرين بلاستيك لبراميل وغيرها
+
+547
+00:48:01,740 --> 00:48:07,180
+وغيرها بس اللي بنعمل منه fibers هو البولي إستر
+
+548
+00:48:07,180 --> 00:48:14,040
+ابهيك احنا بنكون خلصنا تفاعلات الalkynes ان شاء
+
+549
+00:48:14,040 --> 00:48:18,020
+الله المحاضرة الجاية بنبدأ بتفاعلات الalkynes
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6a50ea2927df89df86687433a6fe0e7c57863822
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU.srt
@@ -0,0 +1,1692 @@
+1
+00:00:09,380 --> 00:00:14,160
+بسم الله الرحمن الرحيم، بنكمل اليوم إن شاء الله في
+
+2
+00:00:14,160 --> 00:00:20,520
+موضوع الألكانات وسنتطرق في هذه المحاضرة إلى 
+
+3
+00:00:20,520 --> 00:00:26,300
+الـCyclic alkanes اللي هي المركبات الحلقية التي تحتوي 
+
+4
+00:00:26,300 --> 00:00:32,120
+على روابط أحادية، إن شاء الله هنتعرض إلى الحلقات
+
+5
+00:00:32,120 --> 00:00:37,100
+الثلاثية والرباعية والخماسية والسداسية، المركب اللي 
+
+6
+00:00:37,100 --> 00:00:40,120
+مكوّن من ثلاث كربونات يعني حلقة ثلاثية بنسميه
+
+7
+00:00:40,120 --> 00:00:45,220
+Cyclopropane، اللي مكوّن من أربع كربونات على شكل 
+
+8
+00:00:45,220 --> 00:00:49,540
+حلقة Cyclobutane، المكوّن من خمسة Cyclopentane
+
+9
+00:00:49,540 --> 00:00:53,640
+والمكوّن من ستة Cyclohexane، طبعاً بالتأكيد لو
+
+10
+00:00:53,640 --> 00:00:56,840
+استمرينا يعني السبعة بنسميها Cycloheptane، الثمانية
+
+11
+00:00:56,840 --> 00:00:59,800
+Cyclooctane، التسعة Cyclononane، العشر Cyclo
+
+12
+00:00:59,800 --> 00:01:05,970
+decane وهكذا، الآن لو بدنا نطلع بالتفصيل للمركب
+
+13
+00:01:05,970 --> 00:01:10,750
+الأول اللي هو الـ Cyclopropane، هاي فيه معنى Model
+
+14
+00:01:10,750 --> 00:01:15,930
+أو شكل لـ Cyclopropane، لاحظوا في هذا الشكل الـ
+
+15
+00:01:15,930 --> 00:01:21,270
+Cyclopropane فيه ثلاث ذرات Carbon وعامل روابط اللي 
+
+16
+00:01:21,270 --> 00:01:26,090
+هي عاملة الحلقة الثلاثية، إذا بنلاحظ احنا على كل
+
+17
+00:01:26,090 --> 00:01:32,300
+Carbon حتى يكتمل الأربع روابط ذرتين هيدروجين، واضح؟
+
+18
+00:01:32,300 --> 00:01:35,340
+يعني هذه الـ carbon لما بنيجي نتطلع عليها ونريها 
+
+19
+00:01:35,340 --> 00:01:39,320
+تكون مكتملة، بنلاحظ عليها أربع روابط، رابطتين مع الـ
+
+20
+00:01:39,320 --> 00:01:43,000
+carbons المجاورة ورابطتين مع الهيدروجين.
+
+21
+00:02:01,910 --> 00:02:06,410
+بنستنتج من هنا أن الصيغة العامة للـ Cycloalkanes
+
+22
+00:02:06,410 --> 00:02:13,750
+CnH2n، يعني لما يكون عندي C3 الـ H6، لما يكون عندي 
+
+23
+00:02:13,750 --> 00:02:21,800
+C4 الـ H8، لما يكون عندي C5 الـ H10 وهكذا، واضح؟ هذا
+
+24
+00:02:21,800 --> 00:02:25,340
+بيفرّق عن الألكانات العادية، الألكانات العادية كانت
+
+25
+00:02:25,340 --> 00:02:30,540
+صيغتهم العامة بنذكر CnH2n Plus 2، كانوا يزيدوا
+
+26
+00:02:30,540 --> 00:02:34,060
+ذرتين، طبعاً هدول الذرتين اختفوا لما عملنا اللي 
+
+27
+00:02:34,060 --> 00:02:38,670
+هي الرابطة الحلقية، لما سكرنا على حلقة، الآن هذا الـ
+
+28
+00:02:38,670 --> 00:02:42,490
+Cyclopropane لو اطلعت على ذرات الكربون الثلاث اللي 
+
+29
+00:02:42,490 --> 00:02:46,730
+موجودين فيه بلاحظ أنهم في مستوى واحد، فالـ
+
+30
+00:02:46,730 --> 00:02:50,690
+Cyclopropane is a planar molecule، يعني الثلاث
+
+31
+00:02:50,690 --> 00:02:55,170
+الذرات هي هم عامل أنا ايدي موجودين في مستوى واحد.
+
+32
+00:02:55,800 --> 00:02:59,580
+الآن إذا أنا بتطلع على الـhydrogens اللي محمولين 
+
+33
+00:02:59,580 --> 00:03:02,700
+عليه، ستة هيدروجين، واحد، اثنين، ثلاثة، أربعة،
+
+34
+00:03:02,700 --> 00:03:06,400
+خمسة، ستة، الست ذرات هيدروجين اللي على 
+
+35
+00:03:06,400 --> 00:03:10,880
+الـcyclopropane هدولة متكافئات، يعني لو بدأ أشيل
+
+36
+00:03:10,880 --> 00:03:15,240
+واحدة منهم مثلاً أعمل لها إبدال، substitution، بذرة 
+
+37
+00:03:15,240 --> 00:03:20,690
+نفترض كلور، هاي ذرة كلور، لو شيلت هادي أو هادي أو
+
+38
+00:03:20,690 --> 00:03:24,050
+هادي أو هادي أو هادي أو هادي نفس النتيجة بطلع عندي
+
+39
+00:03:24,050 --> 00:03:29,770
+فقط مركب واحد اللي هو كلوروسيكلوبروبين، ولو
+
+40
+00:03:29,770 --> 00:03:32,810
+رفعت أي واحدة وحطيت مكانها الكلور هيطلع نفس
+
+41
+00:03:32,810 --> 00:03:37,690
+المركب، إذا لو أجينا سألنا كم كلوروسيكلوبروبين
+
+42
+00:03:37,690 --> 00:03:42,910
+أنا فيه عندي واحد، إيش السبب؟ السبب أنّه أصلاً 
+
+43
+00:03:42,910 --> 00:03:48,410
+أنّه أصلاً الهيدروجينات الست، ذرات الهيدروجين الست
+
+44
+00:03:48,410 --> 00:03:51,590
+اللي على الـ cyclopropane they are equivalent، أي
+
+45
+00:03:51,590 --> 00:03:56,250
+واحدة أشيلها زي الثانية، هذي زي هذي، بقلب الجزئية هذي
+
+46
+00:03:56,250 --> 00:04:01,320
+رجعت نفسها، دي بلف ويك، هذي نفسها دي، واضح؟ الآن
+
+47
+00:04:01,320 --> 00:04:06,880
+لاحظوا معنى بيجينا شغلة لو قلنا بدنا نبدل واحدة
+
+48
+00:04:06,880 --> 00:04:11,720
+هيدروجين بكلور، عند احتمال ناتج واحد، طيب الآن لو
+
+49
+00:04:11,720 --> 00:04:16,540
+بدأ أبدل واحدة ثانية بكلور، كم ناتج بده يطلع عند
+
+50
+00:04:16,540 --> 00:04:21,820
+هذا المركب الواحد، لو بدأ اسميه كلوروسيكلوبروبين
+
+51
+00:04:21,820 --> 00:04:25,380
+ولأن كل الأماكن متساوية لازم أقول one 
+
+52
+00:04:25,380 --> 00:04:29,140
+chlorocyclopropane، لأ أبداً كلوروسيكلوبروبين.
+
+53
+00:04:29,140 --> 00:04:34,140
+الآن لو بدي أشيل كمان هيدروجينة جديدة بلاحظ ملاحظة
+
+54
+00:04:34,140 --> 00:04:38,710
+أن هذه الهيدروجينة اللي على الكربون اللي هناتمثل 
+
+55
+00:04:38,710 --> 00:04:43,130
+نوع لأنها على كربون تحمل هيدروجين، وهذول الأربعة 
+
+56
+00:04:43,130 --> 00:04:48,990
+واحد اثنين ثلاثة أربعة متكافئات، إذا بهذه الحالة
+
+57
+00:04:48,990 --> 00:04:57,810
+أنا عندي نوعين من الهيدروجين، لو شلت هذه بعمل مركب
+
+58
+00:04:57,810 --> 00:05:01,870
+جديد، هايّو، إيش بسمي هذا المركب الجديد؟
+
+59
+00:05:03,790 --> 00:05:07,970
+Dichlorocyclopropane، لكن وين موقع ذرتين لكلور على 
+
+60
+00:05:07,970 --> 00:05:12,590
+نفس ذرة الكربون، يعني أنا عند كلور وكلور على نفس 
+
+61
+00:05:12,590 --> 00:05:16,270
+ذرة الكربون، ولذلك هذا المركب بسميه 
+
+62
+00:05:18,840 --> 00:05:23,040
+1,1-Dichlorocyclopropane، هذا إيش بسميه أنا؟ 1,1-
+
+63
+00:05:23,040 --> 00:05:26,860
+Dichlorocyclopropane، طبعاً ممكن أسأل ليش أنا هنا 
+
+64
+00:05:26,860 --> 00:05:31,700
+حطيت الرقم؟ لأنّه من الـDichlorocompound في عند
+
+65
+00:05:31,700 --> 00:05:35,740
+احتمال أنّه يكون عند غير الـ1,1 ولذلك أنا بحدده 
+
+66
+00:05:35,740 --> 00:05:40,420
+بالأرقام، الآن لو قلنا عرفنا أن في عندنا مركب 1,1-
+
+67
+00:05:40,420 --> 00:05:43,980
+Dichlorocyclopropane وإجينا بدنا نشيل واحدة من
+
+68
+00:05:43,980 --> 00:05:47,740
+هدول الـhydrogens اللي حُط مكانها كلوري جديدة، 
+
+69
+00:05:47,740 --> 00:05:51,950
+لاحظوا معنى، لو شيلنا هذه الـ Hydrogen اللي فوق 
+
+70
+00:05:51,950 --> 00:05:58,490
+وحطينا مكانها Clor، بصير المركب 1,2، 3، طبعاً
+
+71
+00:05:58,490 --> 00:06:04,070
+1,2-Dichlorocyclopropane، إن ذرات الكلور واحدة
+
+72
+00:06:04,070 --> 00:06:08,330
+على موقع واحد والثاني على موقع اثنين، إذن هذا 1,2-
+
+73
+00:06:08,330 --> 00:06:13,450
+Dichlorocyclopropane، بنلاحظ كمان ملاحظة إضافية
+
+74
+00:06:13,450 --> 00:06:17,650
+في هذا المركب إن ذرتين الكلور هدول جايين على جهة 
+
+75
+00:06:17,650 --> 00:06:21,870
+واحدة من الجزيء، ولما تكون على جهة واحدة من الجزئ
+
+76
+00:06:21,870 --> 00:06:28,470
+بنستعمل البادئة cis، إذن هذا لما بدي أسميه تسمية 
+
+77
+00:06:28,470 --> 00:06:34,570
+كاملة بدي أسميه cis بمعنى أنّه ذرتين على جهة واحدة،
+
+78
+00:06:34,570 --> 00:06:41,730
+cis-1,2-Dichlorocyclopropane، واضح؟ إذن أنا حددت
+
+79
+00:06:41,730 --> 00:06:46,210
+اتجاه الذرتين من خلال الـBody Assets اللي بتعني
+
+80
+00:06:46,210 --> 00:06:50,330
+أنهم على جهة واحدة أو مع بعض، وحددت مواقعهم إذا 
+
+81
+00:06:50,330 --> 00:06:52,890
+واحدة منهم على موقع واحد، الثانية على موقع اثنين
+
+82
+00:06:52,890 --> 00:06:58,250
+فهذا المركب المجمل cis-1,2-Dichlorocyclopropane.
+
+83
+00:06:58,250 --> 00:07:02,610
+الآن، كان بالإمكان، كان بالإمكان أن نحط الـChlor
+
+84
+00:07:02,610 --> 00:07:06,670
+على نفس الذرة اثنين، لكن نحطها بشكل معاكس.
+
+85
+00:07:09,100 --> 00:07:14,140
+هي الكلور هذه على واحد وهذه على اثنين، إذن هذا 1,2-
+
+86
+00:07:14,140 --> 00:07:18,160
+Dichlorocyclopropane، هي 1,2، 3، 1,2 
+
+87
+00:07:18,160 --> 00:07:23,600
+Dichlorocyclopropane، لكن هنا مجموعات الكلور كيف
+
+88
+00:07:23,600 --> 00:07:28,290
+بنشوفهم احنا؟ عكس بعض، لما يكونوا عكس بعض بنستخدم
+
+89
+00:07:28,290 --> 00:07:32,870
+البادئة أو الـ prefix الـ Trans، فهذا المركب أنا
+
+90
+00:07:32,870 --> 00:07:38,870
+بسميه الـ Trans-1,2-dichlorocyclopropane.
+
+91
+00:07:40,350 --> 00:07:46,090
+كأنّ أنا اللي بلخّصه أنّه لما بدي أحط مرتين كلور كان 
+
+92
+00:07:46,090 --> 00:07:51,410
+عنده احتمال أن أعمل الـ1,1-dichlorocyclopropane والـ
+
+93
+00:07:51,410 --> 00:07:54,670
+1,2-dichlorocyclopropane، الـ 1,2 في منه
+
+94
+00:07:54,670 --> 00:07:58,070
+مركبين، يا بيكونوا ذرتين كلور مع بعض، بس همّ
+
+95
+00:07:58,070 --> 00:08:03,100
+المركب cis، يا بيكونوا ذرتين كلور عكس بعض وبسمّي
+
+96
+00:08:03,100 --> 00:08:07,000
+المركب Trans، تقريباً هذه خلّيني أقول الأشياء
+
+97
+00:08:07,000 --> 00:08:12,200
+المهمة اللي ممكن نحكيها عن الـCyclopropane الآن.
+
+98
+00:08:12,200 --> 00:08:15,960
+إذا انتقلنا للمركب اللي بعده اللي هو
+
+99
+00:08:15,960 --> 00:08:22,380
+الـCyclobutane اللي مكوّن من أربع ذرات، ربما يخطر
+
+100
+00:08:22,380 --> 00:08:28,380
+على بالكوا أن ذرات الكربون الأربع يكونوا في مستوى 
+
+101
+00:08:28,380 --> 00:08:32,340
+واحد، بمعنى أن هذا الجزء يكون planar يعني جاي في 
+
+102
+00:08:32,340 --> 00:08:40,280
+مستوى واحد، لكن حقيقة بالتجربة العملية اللي لوحظ أن 
+
+103
+00:08:40,280 --> 00:08:44,340
+هذا الجزء ليس في مستوى واحد وإنما في حالة انثناء
+
+104
+00:08:44,340 --> 00:08:49,050
+بهذا الشكل، ملاحظين؟ واضحة الصورة كيف منثني تماماً؟
+
+105
+00:08:49,050 --> 00:08:53,950
+بهذا الشكل احنا بنقدر نتخيله، بهذا الشكل بنقدر
+
+106
+00:08:53,950 --> 00:08:58,370
+نتخيله عامل زي هيك، إذا بدنا نعطي اسم هذا اللي عامل 
+
+107
+00:08:58,370 --> 00:09:04,570
+زي هيك بسمّوه زي الـ butterfly زي الفراشة، عمل زي 
+
+108
+00:09:04,570 --> 00:09:08,130
+الفراشة، كيف الفراشة لما بتكون عاملة جناحينها 
+
+109
+00:09:08,130 --> 00:09:14,190
+بزاوية، فالـ Cyclobutane is not a planar molecule، 
+
+110
+00:09:14,190 --> 00:09:19,110
+مش جزء في مستوى واحد، مش عامل زي المربع اللي في 
+
+111
+00:09:19,110 --> 00:09:22,610
+مستوى واحد، لأ جايب three dimensional زي الـ
+
+112
+00:09:22,610 --> 00:09:28,890
+butterfly زي الفراشة، واضح؟ طبعاً أكيد، أكيد بنلاحظ هنا
+
+113
+00:09:28,890 --> 00:09:33,250
+في الـ Cyclobutane أنّه في عندي ثمانية 
+
+114
+00:09:33,250 --> 00:09:37,670
+هيدروجينز، والثمانية هيدروجينز هدولة متكافئات لكن 
+
+115
+00:09:37,670 --> 00:09:41,930
+لو بدي أعمل عمليات إبدال بلاحظ أنّه بإمكاني أبدل 
+
+116
+00:09:41,930 --> 00:09:46,130
+على نفس الـCarbon اثنين أو ثلاثة أو على الـCarbon
+
+117
+00:09:46,130 --> 00:09:49,310
+اللي جنبها أو على الـCarbon اللي جبالها، وممكن يكون
+
+118
+00:09:49,310 --> 00:09:53,010
+عندي أشياء على نفس الاتجاه تعطيني cis وأشياء
+
+119
+00:09:53,010 --> 00:09:57,540
+باتجاهات متعاكسة تعطيني trans، فالخلاصة إنّ لو أنا 
+
+120
+00:09:57,540 --> 00:10:02,620
+بدأ أقول Chlorocyclobutane 
+
+121
+00:10:02,620 --> 00:10:07,200
+عنده منه مركب واحد، بشيل أي هيدروجينة، الثمانية زي
+
+122
+00:10:07,200 --> 00:10:10,680
+بعض، الثمانية زي بعض، وبحط Clor بصير عندي 
+
+123
+00:10:10,680 --> 00:10:15,200
+Chlorocyclobutane، التمن هيدروجينز زي بعض، لكن لو كنت 
+
+124
+00:10:15,200 --> 00:10:20,420
+بدأ أحط الثانية، العدد بيكبر عندي، ليش؟ لأنّ أنا ممكن 
+
+125
+00:10:20,420 --> 00:10:23,940
+أحط الثانية على نفس هذه الكربونة، ممكن أحطها على 
+
+126
+00:10:23,940 --> 00:10:26,580
+هذه الكربونة باتجاه الأولى أو على هذه الكربونة 
+
+127
+00:10:26,580 --> 00:10:29,160
+باتجاه الثانية، ممكن أحطها على الكربونة على موقع
+
+128
+00:10:29,160 --> 00:10:32,680
+ثلاثة، يعني هنا بيصير عندي 1,2 لو حطيتها هنا، 
+
+129
+00:10:32,680 --> 00:10:36,380
+لو حطيتها هنا 1,2، 3، 1,3 باتجاه
+
+130
+00:10:36,380 --> 00:10:39,540
+واحد، 1,3 باتجاه متعاكس، trans،
+
+131
+00:10:39,540 --> 00:10:43,120
+فالخلاصة أنّه بيصير عندي أكثر من isomers، الـ1,1-
+
+132
+00:10:44,290 --> 00:10:49,210
+والـ 1,2-cis والـ 1,2-trans والـ 1,3-cis والـ 
+
+133
+00:10:49,210 --> 00:10:55,930
+1,3-trans كل هدول المركبات ممكن أن نلاحظ وجودهم
+
+134
+00:10:55,930 --> 00:11:01,110
+في الـcyclobutane اللي عامل زي الـ butterfly and 
+
+135
+00:11:01,110 --> 00:11:04,570
+it is not a planar molecule، هي مرة ثانية بنفرّجيكوا
+
+136
+00:11:04,570 --> 00:11:10,230
+إياها كيف هو بكر مطعوج، يعني عامل زي الفراشة، واضح
+
+137
+00:11:10,230 --> 00:11:17,260
+هذا الكلام؟ بعد الـ Cyclopentane بننتقل للمركب 
+
+138
+00:11:17,260 --> 00:11:19,840
+اللي بعده اللي فيه خمس كربونات واللي اسمه 
+
+139
+00:11:19,840 --> 00:11:23,560
+Cyclopentane، إذا بدنا نتطلع على الشكل العام اللي 
+
+140
+00:11:23,560 --> 00:11:28,080
+موجود فيه طبعاً بتلاحظوا وهيّوا أمامكم أنّه فيه خمس
+
+141
+00:11:28,080 --> 00:11:33,560
+ذرات كربون، عشر ذرات هيدروجين، C5H10، ماشي على نفس
+
+142
+00:11:33,560 --> 00:11:40,380
+الصيغة CnH2n فقط، الآن لو قلنا كيف الشكل، البعض ربما
+
+143
+00:11:40,380 --> 00:11:44,690
+يتخيل أنّه Cyclopentane بلانر، يعني يكون في مستوى 
+
+144
+00:11:44,690 --> 00:11:50,510
+واحد، لكن الجواب برضه لأ، بالتجربة الـ Cyclopentane
+
+145
+00:11:50,510 --> 00:11:54,690
+is not a planar، إذا بتطلعوا ماخد هذا الشكل، لو
+
+146
+00:11:54,690 --> 00:11:59,790
+بنطلع على هذا الشكل بنلاحظ إنّه هنا في عند ما يشبه
+
+147
+00:11:59,790 --> 00:12:06,710
+المستوى، وهذا الـ Carbon طالع عن المستوى، في هذه 
+
+148
+00:12:06,710 --> 00:12:11,830
+الحالة، مين يعطينا أقرب تشبيه ممكن يشبه من الحياة 
+
+149
+00:12:11,830 --> 00:12:17,190
+لهذا الشكل؟ لاحظوا هاي أربعة موجودين في مستوى واحد
+
+150
+00:12:17,190 --> 00:12:23,210
+اللي هما تحديداً هايّهم، هنا عندنا واحد، اثنين،
+
+151
+00:12:23,210 --> 00:12:27,270
+ثلاثة، أربعة في مستوى واحد، وهذه طالعة عنهم، هذا
+
+152
+00:12:27,270 --> 00:12:33,800
+الشكل يشبه ماذا؟ يشبه اللي هو مظروف المكتوب المفتوح، 
+
+153
+00:12:33,800 --> 00:12:38,700
+it is like an open envelope، واضح؟ فاحنا اللي 
+
+154
+00:12:38,700 --> 00:12:43,720
+بنقوله أن الـcyclopentane is not a planar molecule،
+
+155
+00:12:43,720 --> 00:12:48,820
+it is like an open envelope، زي المكتوب المفتوح، الآن
+
+156
+00:12:48,820 --> 00:12:52,520
+بتلاحظوا معنى برضه أنّه فيه عشر Hydrogens
+
+157
+00:12:52,520 --> 00:12:56,000
+equivalent، لكن لما بدنا نشيل أكثر من Hydrogens 
+
+158
+00:12:56,000 --> 00:13:00,420
+اثنتين أو ثلاثة بيصير عندي عدد كبير من الـ isomers،
+
+159
+00:13:00,420 --> 00:13:05,900
+يمكن أنّه تجربوها على الورق وتحسبوها بشكل كامل لكن 
+
+160
+00:13:05,900 --> 00:13:11,720
+بشكل عام هذا هو شكل الـ Cyclopentane، it is like an 
+
+161
+00:13:11,720 --> 00:13:15,950
+open envelope، هيكوا شايفين القاعدة وهذا الجزء اللي 
+
+162
+00:13:15,950 --> 00:13:22,330
+هو يمثل المظروف المفتوح، الـ Open Envelope، بننتقل
+
+163
+00:13:22,330 --> 00:13:27,930
+الآن للشكل التالي اللي هو الـ Cyclohexane اللي فيه
+
+164
+00:13:27,930 --> 00:13:31,910
+ست ذرات كربون، طبعاً ربما البعض يعتقد أن الـ 
+
+165
+00:13:31,910 --> 00:13:36,620
+Cyclohexane ماخد الشكل البلانر زي ما بيبدو على
+
+166
+00:13:36,620 --> 00:13:40,800
+الشاشة لكن الحقيقة في التجربة أو في الواقع لأ،
+
+167
+00:13:40,800 --> 00:13:44,780
+الشكل ما بيجيش بلانر، الست ذرات كربون ما بيجيش بلانر،
+
+168
+00:13:44,780 --> 00:13:50,440
+لكن بياخد عدة أشكال من هذه الأشكال اللي ممكن 
+
+169
+00:13:50,440 --> 00:13:54,940
+ياخدها الـ Cyclohexane، إذا بنركز احنا على ذرات
+
+17
+
+201
+00:16:28,690 --> 00:16:33,430
+عندي ما يشبه الرجلين إذا أنا صرت أمام هيئة شبيهة
+
+202
+00:16:33,430 --> 00:16:37,670
+بهيئة الكرسي هذا الكرسي إذا بتلاحظوا اليد الشمال
+
+203
+00:16:37,670 --> 00:16:43,230
+اللي عندي ماسك الظهر تبعه اليد اليمنى ماسك الرجل
+
+204
+00:16:43,230 --> 00:16:50,480
+تبعته، اللي موجود في الوسط هو المكان الجلوس فيه
+
+205
+00:16:50,480 --> 00:16:55,900
+الكرسي هذه الهيئة بيسموها الـ Chair Conformation
+
+206
+00:16:55,900 --> 00:16:59,580
+هذه الهيئة بيسموها الـ Chair Conformation هيئة
+
+207
+00:16:59,580 --> 00:17:04,640
+الكرسي طبعا موجودة عندكم على الشاشة هيئة القارب
+
+208
+00:17:04,640 --> 00:17:07,740
+الـ Boat Conformation موجود عندكم على الشاشة هيئة
+
+209
+00:17:07,740 --> 00:17:13,730
+الكرسي الآن إذا أنا بتطلع على هيئة الكرسي لاحظوا أن
+
+210
+00:17:13,730 --> 00:17:18,630
+الـ 12 هيدروجينة لأن الـ Cyclohexane C6H12 مقسمين
+
+211
+00:17:18,630 --> 00:17:24,660
+إلى نوعين من الهيدروجين، الـ 12 هيدروجينة مقسمين إلى
+
+212
+00:17:24,660 --> 00:17:29,740
+نوعين في هيئة الكرسي في عندي الـ Hydrogens اللي
+
+213
+00:17:29,740 --> 00:17:34,720
+لونهم أخضر باللاحظ أنه موجودين ثلاثة للأعلى و
+
+214
+00:17:34,720 --> 00:17:38,580
+ثلاثة للأسفل طبعا بزام عموديات سواء للأعلى أو
+
+215
+00:17:38,580 --> 00:17:43,660
+للأسفل، بقول عنهم Axial Axial يعني عموديات إذا أنا
+
+216
+00:17:43,660 --> 00:17:52,960
+عندي 6 Axial Hydrogen 3 above the molecule 1 2 3
+
+217
+00:17:52,960 --> 00:17:58,260
+and 3 below the molecule 1 2 3 الباقيين اللي هم
+
+218
+00:17:58,260 --> 00:18:03,190
+ماخدين اللون البرتقالي، هدول بشكل عام جايين باتجاه
+
+219
+00:18:03,190 --> 00:18:08,830
+جانبي الـ 6، 1، 2، 3، 4، 5، 6، نوعًا ما ماخدين
+
+220
+00:18:08,830 --> 00:18:12,750
+الوضع الجانبي لكن لما تتطلعوا بوضوح وين التلاتة
+
+221
+00:18:12,750 --> 00:18:17,490
+اللي هم أكثر عموديات للأعلى، بالذات لما يكون ثابت
+
+222
+00:18:17,490 --> 00:18:20,730
+الشكل ما بيغلبناش، هايهم، شايفين التلاتة الخضر؟
+
+223
+00:18:21,290 --> 00:18:25,510
+واضحين جداً هدولة التلاتة الخضر اللي هما الـ axial
+
+224
+00:18:25,510 --> 00:18:30,370
+ثلاثة فوق و ثلاثة تحت، والباقيين الستة equatorial
+
+225
+00:18:30,370 --> 00:18:36,550
+إذا الـ 12 هيدروجين يقسموا إلى 6 axial hydrogens 3
+
+226
+00:18:36,550 --> 00:18:39,710
+above the molecule and 3 below the molecule and
+
+227
+00:18:39,710 --> 00:18:45,110
+another 6 equatorial hydrogens let's say in the
+
+228
+00:18:45,110 --> 00:18:49,710
+plane of the molecule، الآن هذا الشكل اللي أنا عمال
+
+229
+00:18:49,710 --> 00:18:54,230
+ارسمه و بقول هي الظاهر تبعه موجود بإيد الشمال أنا 
+
+230
+00:18:54,230 --> 00:18:59,890
+ماسكه و القاعدة موجودة باليد اليمنى، يمكن أن أعمله
+
+231
+00:18:59,890 --> 00:19:03,350
+flipping أجيبه زي ما بتجلب الشمسية بتلاعبوا كيف
+
+232
+00:19:03,350 --> 00:19:06,870
+بتجلب الشمسية في الهواء ممكن أجيبه هذا الظاهر
+
+233
+00:19:06,870 --> 00:19:14,230
+أخليه يمثل الرجلين اللي تحت وهذا الرجلين أجيبهُم
+
+234
+00:19:14,230 --> 00:19:18,800
+يمثلوا الظاهر اللي الأعلى لاحظوا هنا أنا جبتهم
+
+235
+00:19:18,800 --> 00:19:23,680
+بهذا الشكل الجميل صار عندي هي اليد اليمنى ماسكة
+
+236
+00:19:23,680 --> 00:19:28,120
+الظهر واليد الشمال ماسكة الرجل اللي تحت هنا
+
+237
+00:19:28,120 --> 00:19:32,480
+بتلاحظوا ملاحظة إن ال hydrogens الخضر اللي كانوا
+
+238
+00:19:32,480 --> 00:19:37,120
+axial صاروا equatorial و ال hydrogens اللي مبينين
+
+239
+00:19:37,120 --> 00:19:40,560
+برتقالي اللي كانوا مبينين على الجنب equatorial
+
+240
+00:19:40,560 --> 00:19:46,370
+صاروا axial ثلاثة فوق، ثلاثة تحت، إذا عملية الـ
+
+241
+00:19:46,370 --> 00:19:50,010
+flipping هنا في هذا الجزء بتغلب الهيدروجينز الـ
+
+242
+00:19:50,010 --> 00:19:53,230
+axial hydrogen will be equatorial and the
+
+243
+00:19:53,230 --> 00:19:57,630
+equatorial hydrogen will be axial، ملاحظين هنا وين
+
+244
+00:19:57,630 --> 00:20:02,010
+الـ axial؟ التلاتة البرتقاليات، وين الـ equatorial
+
+245
+00:20:02,010 --> 00:20:07,210
+صاروا النوع الأخضر، لما بعمله flipping بنعكسه الآن
+
+246
+00:20:07,210 --> 00:20:11,990
+أي الأشكال أثبت لـ Chair Conformation هيئة الكرسي
+
+247
+00:20:11,990 --> 00:20:16,370
+ولا هيئة القارب؟ خلّيني أكد عليه السؤال، هذا سؤال
+
+248
+00:20:16,370 --> 00:20:20,600
+مهم، أي الأشكال أثبت، الـ Chair Conformation اللي
+
+249
+00:20:20,600 --> 00:20:23,340
+احنا عاملين مسكين وهيظهر و هيرجلين، ولا الـ Boat
+
+250
+00:20:23,340 --> 00:20:27,000
+Conformation؟ احنا قلنا الـ Boat Conformation في
+
+251
+00:20:27,000 --> 00:20:31,820
+استدام لذرات الهيدروجين ببعض، إقراب من بعض، ولذلك
+
+252
+00:20:31,820 --> 00:20:37,340
+يعتبر الـ Chair Conformation more stable than الـ
+
+253
+00:20:37,340 --> 00:20:41,220
+Boat Conformation واضح؟ الـ Chair Conformation of
+
+254
+00:20:41,220 --> 00:20:45,750
+Cyclohexane is more stable than the Boat
+
+255
+00:20:45,750 --> 00:20:51,090
+confirmation، الآن لو اتخيلنا إن احنا كل اللي موجود
+
+256
+00:20:51,090 --> 00:20:55,810
+عندنا هيدروجين و بدنا نرفع هيدروجين ونحط بدالها
+
+257
+00:20:55,810 --> 00:21:02,170
+مجموعة مثل جروب هاي مجموعة مثل إن ماسكا CH3 مش هذه
+
+258
+00:21:02,170 --> 00:21:07,850
+مجموعة الميثل، الآن لاحظوا لو شيلت هذه الهيدروجين و
+
+259
+00:21:07,850 --> 00:21:16,140
+حطيت بدالها المجموعة الميثل CH3 وهي ماسك الجزء،
+
+260
+00:21:16,140 --> 00:21:20,100
+لاحظوا هيظهر على اليد اليمنى والرجل في اليد
+
+261
+00:21:20,100 --> 00:21:24,780
+اليسرى، إيش بتلاحظوا هنا في هذا الشكل؟ إن الميثل
+
+262
+00:21:24,780 --> 00:21:32,360
+جروب لو كانت Axial، بتبدأ تصير قريبة من
+
+263
+00:21:32,360 --> 00:21:38,910
+الـ Hydrogens، ولذلك لاحظوا هاي التلاتة axials H وH
+
+264
+00:21:38,910 --> 00:21:43,210
+ومثل، لكن المثل أجمالها صارت قريبة من ال hydrogens
+
+265
+00:21:43,210 --> 00:21:48,910
+طيب لو لفيت الجزيء لو لفيت الجزيء بهذا الشكل
+
+266
+00:21:48,910 --> 00:21:55,370
+هينرجعت الذرات اللي لونهم أخضر يكونوا axial زي ما
+
+267
+00:21:55,370 --> 00:21:59,430
+بتلاحظوا هيهم، التلاتة الخضر إنبينين أقرب شق لكم
+
+268
+00:21:59,430 --> 00:22:03,070
+Axial، وين صارت الـ Methyl group؟ صارت الـ Methyl
+
+269
+00:22:03,070 --> 00:22:06,950
+group equatorial، الآن وين الـ Methyl group عاملة
+
+270
+00:22:06,950 --> 00:22:11,410
+مشاكل أكثر؟ تكون equatorial ولا Axial؟ بالتأكيد
+
+271
+00:22:11,410 --> 00:22:14,690
+لما بتكون equatorial ما فيش إيش تصطدم معه، تتنافر
+
+272
+00:22:14,690 --> 00:22:18,730
+معه، لكن لما كانت Axial شوفنا إنها قريبة من two
+
+273
+00:22:18,730 --> 00:22:24,310
+other hydrogens، ولذلك الـ methylcyclohexane بفضل
+
+274
+00:22:24,310 --> 00:22:28,810
+يكون بالـ Chair formation والـ methyl group تكون
+
+275
+00:22:28,810 --> 00:22:33,690
+في الـ equatorial position، بأكد الـ methyl group
+
+276
+00:22:33,690 --> 00:22:37,750
+وين أفضل تكون؟ في الـ axial ولا في الـ equatorial؟
+
+277
+00:22:38,500 --> 00:22:42,380
+الـ methyl group بتفضل تكون في الـ equatorial
+
+278
+00:22:42,380 --> 00:22:46,080
+position هي شايفين أين جاية؟ على الجانب في ال
+
+279
+00:22:46,080 --> 00:22:49,860
+equatorial position مش في الـ Axial position، ولذلك
+
+280
+00:22:49,860 --> 00:22:55,100
+هدول الشكلين النسبة بينهم حقيقة في الـ Cyclohexane
+
+281
+00:22:55,100 --> 00:22:59,680
+بتكون 95% من الوقت الـ methyl group في الـ
+
+282
+00:22:59,680 --> 00:23:04,280
+equatorial position و فقط 5% من الوقت في الـ axial
+
+283
+00:23:04,280 --> 00:23:07,220
+position لأنه لما بتكون في الـ axial position
+
+284
+00:23:07,220 --> 00:23:12,680
+بتكون عملت نافر مع الـ hydrogen أو الـ two
+
+285
+00:23:12,680 --> 00:23:17,370
+hydrogens اللي موجودين قريب منها طبعا انتبهوا معي
+
+286
+00:23:17,370 --> 00:23:21,190
+في أكبر من الـ methyl group يعني لو أنا بدي أشيل
+
+287
+00:23:21,190 --> 00:23:25,970
+الـ methyl group هذه وأحط بدالها أكبر group في الـ
+
+288
+00:23:25,970 --> 00:23:28,910
+organic chemistry اللي هي tertiary-butyl الأربع
+
+289
+00:23:28,910 --> 00:23:35,270
+كربونات سبق أخدناها كربون متفرع منها مثل و مثل و
+
+290
+00:23:35,270 --> 00:23:39,290
+مثل هذه، إيش بنسميها المجموعة هي موجودة tertiary
+
+291
+00:23:39,290 --> 00:23:44,750
+-butyl أربع كربونات واحد اثنين ثلاثة أربعة هذه
+
+292
+00:23:44,750 --> 00:23:49,530
+المجموعة tert-butyl لما بدأت أحطها اتخيلوا قد إيش
+
+293
+00:23:49,530 --> 00:23:54,390
+أنا بتريح لو حطيت هذه المجموعة في الـ equatorial
+
+294
+00:23:54,390 --> 00:23:58,590
+position بتعملش عندي مشاكل، هاي الشكل اللي عنده
+
+295
+00:23:58,590 --> 00:24:04,410
+واضح تماما، التلت مجموعات الـ axial اللي هي واحدة
+
+296
+00:24:04,410 --> 00:24:08,370
+اثنين ثلاثة، الآن هنا هذه الـ tertiary butyl في أي
+
+297
+00:24:08,370 --> 00:24:12,480
+مستوى في الـ equatorial هي في مستوى الجزيئة مش جاية
+
+298
+00:24:12,480 --> 00:24:18,000
+عمودية، ولذلك هذا الجزيء بيكون بنسبة مئة في المئة
+
+299
+00:24:18,000 --> 00:24:21,440
+tertiary butyl group جاية على الـ equatorial
+
+300
+00:24:21,440 --> 00:24:25,740
+position، اتخيلوا لو كنا بدنا نلفه ونحطها على ال
+
+301
+00:24:25,740 --> 00:24:29,880
+axial position، خليني نعمل يعني هذا بدل ما هو ظهر
+
+302
+00:24:29,880 --> 00:24:33,980
+الكرسي نخليه رجل و هذا بدل ما هو رجل الكرسي اللي
+
+303
+00:24:33,980 --> 00:24:40,070
+لتحت نخليه ظهر هي ده خلينها ظهر و هذه خليناها الـ
+
+304
+00:24:40,070 --> 00:24:44,340
+«ريتشار»، الآن اتخيلوا هذه الـ tertiary-butyl group
+
+305
+00:24:44,340 --> 00:24:50,100
+هي هي إيش عاملة هنا مشاكل؟ وإيش عاملة هنا مشاكل؟
+
+306
+00:24:50,100 --> 00:24:54,320
+بتبدأ تصطدم، بتبدأ تصطدم مع الـhydrogens اللي
+
+307
+00:24:54,320 --> 00:24:59,180
+موجودين هنا وهنا، ولذلك هل يفضل إنه هذه، هي الشكل
+
+308
+00:24:59,180 --> 00:25:03,460
+الكرسي ممتاز جداً بهذا الشكل؟ والـtertiary-butyl
+
+309
+00:25:03,460 --> 00:25:07,040
+على الـaxial؟ هنا على الـaxial نسبتها 0% لإنها
+
+310
+00:25:07,040 --> 00:25:12,640
+بتعمل مشاكل مع الـhydrogens لجراب سمعين؟ هاي مع الـ
+
+311
+00:25:12,640 --> 00:25:18,140
+hydrogen لغريبة بتعمل مشاكل واضح؟ ولذلك بتكون الـ
+
+312
+00:25:18,140 --> 00:25:22,900
+tertiary-butyl بنسبة 0% بهذا الشكل، الأكسي لغريبة
+
+313
+00:25:22,900 --> 00:25:29,120
+هي عمال بتصطدم بالـhydrogens، وبتفضل أن الجزء ألف
+
+314
+00:25:29,120 --> 00:25:35,550
+نفسه بحيث إنه هي تصير في الـ equatorial position، هي
+
+315
+00:25:35,550 --> 00:25:38,430
+الآن لما راحت على الـ equatorial position وهي دهر
+
+316
+00:25:38,430 --> 00:25:42,270
+الكرسي، لاحظوا هنا عاملة مشاكل في الـ equatorial
+
+317
+00:25:42,270 --> 00:25:47,110
+position لأ، وين بتعمل مشاكل لما تكون في الـ axial
+
+318
+00:25:47,110 --> 00:25:49,670
+position، هي الـ equatorial position
+
+319
+00:25:53,290 --> 00:25:56,190
+هي الـ equatorial position الـ tertiary butyl
+
+320
+00:25:56,190 --> 00:26:01,450
+طالعة فيه لبرا مش عاملة عندي مشاكل، ولذلك لما بدأ
+
+321
+00:26:01,450 --> 00:26:04,490
+أقول قد إيش نسبة الـ tertiary butyl في الـ equatorial
+
+322
+00:26:04,490 --> 00:26:10,150
+و الـ axial بقول في الـ equatorial 100% بالـ axial 0%
+
+323
+00:26:10,150 --> 00:26:15,830
+لأنها بتعمل تنافر مع ذرات الهيدروجين التانيات اللي
+
+324
+00:26:15,830 --> 00:26:20,310
+موجودين عندها لو كانت في الـ Axial Position، هذا
+
+325
+00:26:20,310 --> 00:26:25,870
+بشكل عام ملخص عن الـ Cycloalkanes هذا بشكل عام
+
+326
+00:26:25,870 --> 00:26:29,470
+ملخص عن الـ Cycloalkanes أخذنا فيه الـ
+
+327
+00:26:29,470 --> 00:26:34,430
+Cyclopropane الـ Cyclobutane الـ Cyclopentane والـ
+
+328
+00:26:34,430 --> 00:26:35,610
+Cyclohexane
+
+329
+00:26:37,740 --> 00:26:43,920
+طبعا بنختم بشغلة بسيطة إنه بشكل عام الـ alkanes و
+
+330
+00:26:43,920 --> 00:26:50,560
+الـ cycloalkanes هل لهم تفاعلات؟ الجواب إنه بشكل
+
+331
+00:26:50,560 --> 00:26:54,240
+عام يعتبروا الـ alkanes و الـ cycloalkanes inert
+
+332
+00:26:54,240 --> 00:26:58,680
+يعني تفاعلاتهم قليلة جداً ولذلك كثيراً ما تستخدم
+
+333
+00:26:58,680 --> 00:27:03,900
+الـ alkanes و الـ cycloalkanes as solvents، مشهور
+
+334
+00:27:03,900 --> 00:27:09,380
+لهم تفاعلين فقط للـ Alkanes اللي هو تفاعل الـ
+
+335
+00:27:09,380 --> 00:27:14,440
+Combustion إنه احنا الـ Alkanes بنحرقهم بنطلع ثاني
+
+336
+00:27:14,440 --> 00:27:19,060
+أكسيد كربون وميه والناتج الأهم ربما اللي مش مكتوب
+
+337
+00:27:19,060 --> 00:27:24,210
+هنا هو حرارة، بديش أنا أنسى إنه البنزين تبع السيارات
+
+338
+00:27:24,210 --> 00:27:28,110
+الجازولين أو الـ fuel هو عبارة عن خليط من الهيبتين
+
+339
+00:27:28,110 --> 00:27:31,810
+والأيزو أكتين لما أنا بحرقه بموتور السيارة بطلع
+
+340
+00:27:31,810 --> 00:27:36,490
+عندي ثاني أكسيد كربون ومية وحرارة، الناتج المهم إليه
+
+341
+00:27:36,490 --> 00:27:41,860
+في موتور السيارة شو هو؟ الحرارة، الناتج الدار واللي
+
+342
+00:27:41,860 --> 00:27:45,300
+بيعمل الـ greenhouse effect المشكلة البيئية
+
+343
+00:27:45,300 --> 00:27:50,420
+الكبيرة هو ثاني أكسيد الكربون واضح؟ طبعا احنا
+
+344
+00:27:50,420 --> 00:27:55,440
+مضطرين نستعمل الجازولين كوقود للسيارات لأن احنا
+
+345
+00:27:55,440 --> 00:27:59,870
+بدنا الـ energy أو الطاقة هذا بالنسبة لتفاعل ال
+
+346
+00:27:59,870 --> 00:28:04,230
+combustion ومعنى combustion burning in the
+
+347
+00:28:04,230 --> 00:28:09,310
+presence of oxygen الحرق في وجود الـ oxygen يعني في
+
+348
+00:28:09,310 --> 00:28:12,890
+السيارة لما أنا بحرق البنزين بحرق البنزين لحاله
+
+349
+00:28:12,890 --> 00:28:17,310
+ولا فيه Oxygen لأ في Oxygen ولازم تكون النسبة
+
+350
+00:28:17,310 --> 00:28:22,330
+دقيقة جداً ما بين البنزين وما بين الهواء اللي فيه
+
+351
+00:28:22,330 --> 00:28:25,930
+الـ Oxygen و الجزء في السيارة اللي بنظم هذا الكلام
+
+352
+00:28:25,930 --> 00:28:28,650
+أكيد نسبة كبيرة منكم بتعرف اللي بيسموه ال
+
+353
+00:28:28,650 --> 00:28:34,490
+Carburetor ولو صار في خلل ما بين نسبة الوقود والـ
+
+354
+00:28:34,490 --> 00:28:40,330
+Oxygen بيصير مشاكل ممكن يؤدي إلى عدم احتراق كامل
+
+355
+00:28:40,330 --> 00:28:45,270
+للبنزين ويصير يطلع من السيارة دخان أسود دليل على
+
+356
+00:28:45,270 --> 00:28:49,930
+أنه البنزين لم يتم أو الوقود لم يتم حرقه بشكل
+
+357
+00:28:49,930 --> 00:28:53,570
+كامل، واضح؟ فالتفاعل الأول للـ Alkanes هو ال
+
+358
+00:28:53,570 --> 00:28:57,440
+combustion، الحرق في وجود الـ Oxygen الآن التفاعل
+
+359
+00:28:57,440 --> 00:29:01,640
+الثاني الـ halogenation إن أنا أي الكان يعني لو
+
+360
+00:29:01,640 --> 00:29:05,660
+افترضت مثلاً إنه عندي ميثين هذا الميثين اللي أنا
+
+361
+00:29:05,660 --> 00:29:11,820
+ماسكه الآن بإيدي ممكن أعمله إبدال بذرات معينة يعني
+
+362
+00:29:11,820 --> 00:29:16,940
+ممكن أبدله مثلاً بذرة كلورين يعني أشيل هيدروجين
+
+363
+00:29:16,940 --> 00:29:22,120
+وأبدله بكلور صار إيش اسمه كلوروميثين ممكن أشيل
+
+364
+00:29:22,120 --> 00:29:25,650
+الهيدروجين الثاني وأبدله بكمان كلور صار
+
+365
+00:29:25,650 --> 00:29:29,630
+دايكلوروميثين ممكن أشيل الهيدروجين الثالثة وأبدل
+
+366
+00:29:29,630 --> 00:29:33,330
+بكلور صار تريكلوروميثين اللي إله اسم شورا
+
+367
+00:29:33,330 --> 00:29:37,290
+كلوروفورم CHCl3
+
+368
+00:29:37,290 --> 00:29:42,810
+وممكن أشيل الهيدروجين الرابعة وأبدل مثلاً بكلور صار
+
+369
+00:29:42,810 --> 00:29:48,130
+الـ carbon tetrachloride أو الـ tetrachlorocarbon
+
+370
+00:29:48,430 --> 00:29:52,550
+إذا تفاعل ثاني مشهور عن الـ Alkanes اللي هو تفاعل
+
+371
+00:29:52,550 --> 00:29:55,830
+الـ Substitution لما أنا بفعل الـ Alkanes مع الـ
+
+372
+00:29:55,830 --> 00:30:02,790
+Halogens وهذا التفاعل بيلزم وجود حرارة أو ضوء شمس
+
+373
+00:30:02,790 --> 
+
+401
+00:32:27,530 --> 00:32:29,970
+إلكترون يتفاعل مثل الـ Radical
+
+402
+00:32:37,530 --> 00:32:43,170
+Methyl Radical وHCl هذا الـ Methyl Radical بيجي
+
+403
+00:32:43,170 --> 00:32:47,910
+على جزء كلور تاني، هاي جزء كلور تاني، بياخد منه
+
+404
+00:32:47,910 --> 00:32:53,790
+ذرة كلور، بيكوّن كلوروميثين في الخطوة الثانية، 
+
+405
+00:32:53,790 --> 00:32:56,330
+اتكوّن كلوروميثين في الخطوة الثانية، شو ضال
+
+406
+00:32:56,330 --> 00:33:03,010
+عنده؟ Cl Radical، واضح؟ الـ Cl Radical بيتفاعل من 
+
+407
+00:33:03,010 --> 00:33:07,870
+جديد مع جزء ميثين تاني، أنا هين كوّنت؟ لاحظوا
+
+408
+00:33:07,870 --> 00:33:13,210
+الناتج اللي .. هاي خلاصة النواتج الأولى HCl زائد
+
+409
+00:33:13,210 --> 00:33:18,110
+Methylchloride خلصناه وطلع عنده Cl Radical بتفاعل
+
+410
+00:33:18,110 --> 00:33:21,630
+مع جزء Methane تاني بعيد نفس الكلام بيكون في الأول
+
+411
+00:33:21,630 --> 00:33:25,990
+HCl و Methyl Radical بعدين Methylchloride و بيطلع 
+
+412
+00:33:25,990 --> 00:33:32,670
+جزء Free Radical أو Chlorine Atomتانية و بتتفاعل
+
+413
+00:33:32,670 --> 00:33:38,270
+كذا إذا هدول الخطوتين متكررات كل مرة ببدأ بـ Free
+
+414
+00:33:38,270 --> 00:33:44,170
+Radical أو بـ Chlorine atom و بتتفاعل بتعمل HCl مثل
+
+415
+00:33:44,170 --> 00:33:48,510
+Methylchloride و بيطلع Chlorine atom مرة تانية أو Radical
+
+416
+00:33:49,220 --> 00:33:53,060
+بتتفاعل مرة ثانية وهكذا وهكذا هذا التفاعل ممكن
+
+417
+00:33:53,060 --> 00:33:58,240
+يتكرر أربع خمس تلاف مرة قبل ما يوقف بأي طريقة
+
+418
+00:33:58,240 --> 00:34:02,440
+بنسميها termination لاحظوا معي أن هذا التفاعل آلي
+
+419
+00:34:02,440 --> 00:34:06,980
+متكوّن من ثلاث شغلات الشغلة الأولى أنه أنا كان أكون 
+
+420
+00:34:06,980 --> 00:34:12,260
+عندي جزء كلورين إذا بتذكره أو أكسره لـ Two
+
+421
+00:34:12,260 --> 00:34:15,060
+Chlorine atoms هذه الخطوة بسميها أنا إيش؟
+
+422
+00:34:15,570 --> 00:34:20,370
+Initiation خطوة تحضيرية الشيء الثاني خطوتين
+
+423
+00:34:20,370 --> 00:34:26,070
+بتتكرروا اللي بيعملوا الـHCl والـMethylchloride 
+
+424
+00:34:26,070 --> 00:34:29,110
+و بيطلع Radical وبيعيد وبيعيد وبيعيد هذه خطوة
+
+425
+00:34:29,110 --> 00:34:33,690
+متكررة بنسميها Chain propagating step خطوة متوالدة
+
+426
+00:34:33,690 --> 00:34:40,170
+متكاثرة بعد هيك في النهاية ممكن أنه يتم Termination
+
+427
+00:34:40,170 --> 00:34:45,390
+للتفاعل من خلال تفاعل X Radical مع X Radical تاني 
+
+428
+00:34:45,390 --> 00:34:48,950
+يعطيني X2 أو R Radical مثلاً مثل Radical مع مثل
+
+429
+00:34:48,950 --> 00:34:54,770
+Radical تاني يعطيني Ethane أو R Radical مع X
+
+430
+00:34:54,770 --> 00:34:58,790
+Radical تانية من عدة دوائر بيكون موجود عنده طبعاً
+
+431
+00:34:58,790 --> 00:35:03,850
+في التفاعل يعطيني R X واضح؟ وبالتالي هذه الخطوات
+
+432
+00:35:03,850 --> 00:35:08,390
+بتوقف سلسلة تكاثر التفاعل بيسميها Termination إذا
+
+433
+00:35:08,390 --> 00:35:12,670
+الـ Mechanism of reaction متكوّنة من ثلاث شغلات
+
+434
+00:35:13,410 --> 00:35:17,790
+Initiation خطوة تحضيرية تكوين الـ Free Radicals
+
+435
+00:35:17,790 --> 00:35:22,450
+Propagation الخطوة التكاثر والشغلة الثالثة
+
+436
+00:35:22,450 --> 00:35:26,970
+Termination الخطوة إنهاء التفاعل
+
+437
+00:35:29,620 --> 00:35:32,700
+الـ Mechanism of the reaction لاحظوا مع الـ 
+
+438
+00:35:32,700 --> 00:35:36,180
+Mechanism هي خطوات تفصيلية احنا بنشوفهاش يعني
+
+439
+00:35:36,180 --> 00:35:40,460
+المعادلة بتكون عامة لكن جوا المعادلة في خطوات 
+
+440
+00:35:40,460 --> 00:35:44,440
+تفصيلية عادة لا تكتب في المعادلة هي التي تسمى
+
+441
+00:35:44,440 --> 00:35:50,180
+Mechanism فمعنى Mechanism الـ Detailed steps Cannot
+
+442
+00:35:50,180 --> 00:35:53,360
+be seen in the equation يعني لما أنا بدي المعادلة
+
+443
+00:35:53,360 --> 00:35:58,340
+بقول Cl زي ميثين Cl وميثين زي HCl هي المعادلة لكن
+
+444
+00:35:58,340 --> 00:36:01,680
+كيف اتكسر الـ Cl؟ إيش اللي اتكوّن في الأول؟ إيش اللي 
+
+445
+00:36:01,680 --> 00:36:04,740
+اتكوّن في الثاني؟ هذه الخطوات التفصيلية اللي احنا
+
+446
+00:36:04,740 --> 00:36:09,260
+مابنشوفهاش بنسميها Mechanism of the reaction
+
+447
+00:36:11,760 --> 00:36:16,120
+آخر شغل بنحكيها أنه لو أنا كنت بدأ أعمل إبدال على
+
+448
+00:36:16,120 --> 00:36:21,600
+مركب غير الميثين، يعني إيثين، بروبين، وأبدل One
+
+449
+00:36:21,600 --> 00:36:26,580
+Hydrogen by كلورين أو برومين Atom، Two Hydrogens
+
+450
+00:36:26,580 --> 00:36:31,780
+ممكن، للأصل يكون واضح عندكم تماماً إنه إحنا بنتوقع
+
+451
+00:36:31,780 --> 00:36:36,250
+أكثر من ناتج، يعني لو بننظر هنا إلى الشاشة في حالة
+
+452
+00:36:36,250 --> 00:36:40,490
+البروبين Carbon ثلاث تلاتة لو بدي أقول الـ
+
+453
+00:36:40,490 --> 00:36:43,450
+Monochloroproducts يعني لو بس بدي أبدل الهيدروجين
+
+454
+00:36:43,450 --> 00:36:47,170
+بكلور ممكن الكلورة تيجي على الذرة الأولى ويصير
+
+455
+00:36:47,170 --> 00:36:52,830
+عند المركب اللي هو One-Chloropropeneو ممكن الكلور
+
+456
+00:36:52,830 --> 00:36:56,170
+تيجي على الذرة الثانية ويصير عند المركب اللي 
+
+457
+00:36:56,170 --> 00:37:00,970
+اسمه Two-Chloropropene طبعاً كـ Common names هذا اسمه
+
+458
+00:37:00,970 --> 00:37:03,850
+n-propyl chloride لأنه دي مجموعة n-propyl 
+
+459
+00:37:03,850 --> 00:37:09,190
+chloride وهذا اسمه Isopropyl chloride إذا لو بدأ
+
+460
+00:37:09,190 --> 00:37:12,410
+أقول من البروبين الـ Monochloroproducts المتوقع
+
+461
+00:37:12,410 --> 00:37:15,510
+كم ناتج؟ اتنين الـ One-Chloroproduct والـ Two
+
+462
+00:37:15,510 --> 00:37:19,410
+-Chloroproduct الآن لو قلت بدي أبدل ذرتين هيدروجين
+
+463
+00:37:19,410 --> 00:37:24,100
+بكلور كم ناتج ممكن يطلع عنده؟ ممكن ذرتين الكلور
+
+464
+00:37:24,100 --> 00:37:28,760
+يجعل الكربون الأولى، بيطلع One,One-Dichloropropane،
+
+465
+00:37:28,760 --> 00:37:33,680
+ممكن التنتين يجعل الكربون الثانية بيطلع 2,2
+
+466
+00:37:33,680 --> 00:37:37,260
+-Dichloropropane ممكن واحدة تيجي على الـ Carbon
+
+467
+00:37:37,260 --> 00:37:41,580
+الأولى وواحدة على الثانية بيطلع 1,2-Dichloropropane
+
+468
+00:37:41,580 --> 00:37:45,160
+وممكن واحدة تيجي على الـ Carbon الأولى والثانية 
+
+469
+00:37:45,160 --> 00:37:49,760
+على الـ Carbon الثالثة بيطلع 1,3-Dichloropropane إذا 
+
+470
+00:37:49,760 --> 00:37:54,880
+عمال من الـ Dichloropropane أنا شايف أربع مركبات و
+
+471
+00:37:54,880 --> 00:37:59,020
+من الـ 1-Chloropropane شايف مركبين طبعاً واضح أن
+
+472
+00:37:59,020 --> 00:38:03,300
+هدول Isomersوالـ Structural Isomers بيختلفوا في
+
+473
+00:38:03,300 --> 00:38:06,340
+مواقع الروابط هان الكلور على موقع واحد هان الكلور على
+
+474
+00:38:06,340 --> 00:38:09,880
+موقع اثنين أو هان ذرتين كلور على موقع واحد هان ذرتين
+
+475
+00:38:09,880 --> 00:38:12,960
+كلور على موقع اثنين هان ذرة على واحد ذرة على اثنين هان
+
+476
+00:38:12,960 --> 00:38:17,300
+ذرة على واحد ذرة على ثلاثة هاد هي الـ Isomers أو الـ
+
+477
+00:38:17,300 --> 00:38:21,300
+Structural isomers المفروض إنه يصير عندكوا تدريب
+
+478
+00:38:21,300 --> 00:38:25,120
+لو قلنالكوا اعملوا إبدال بذرة واحدة بذرتين على 
+
+479
+00:38:25,120 --> 00:38:29,770
+البيوتين مثلاً ممكن تاخدوه كـ Homeworkكم
+
+480
+00:38:29,770 --> 00:38:34,990
+Monochloroproduct وكم Dichloroproduct ممكن أتوقع
+
+481
+00:38:34,990 --> 00:38:38,290
+من مركب البيوتين شكراً 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..22c7b28a833e31cb368d9defc1b22b1952389ebf
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ceX2ytHDpcU_postprocess.srt
@@ -0,0 +1,1924 @@
+1
+00:00:09,380 --> 00:00:14,160
+بسم الله الرحمن الرحيم بنكمل اليوم ان شاء الله في
+
+2
+00:00:14,160 --> 00:00:20,520
+موضوع ال alkanes وسنتطرق في هذه المحاضرة إلى ال
+
+3
+00:00:20,520 --> 00:00:26,300
+cycle alkanes اللي هي المركبات الحلقية التي تحتوي
+
+4
+00:00:26,300 --> 00:00:32,120
+على روابط أحديةإن شاء الله هنتعرض إلى الحلقات
+
+5
+00:00:32,120 --> 00:00:37,100
+الثلاثية والرباعية والخماسية والسداسية المركب اللي
+
+6
+00:00:37,100 --> 00:00:40,120
+مكوّن من تلت كربونات يعني حلقة ثلاثية بنسميه
+
+7
+00:00:40,120 --> 00:00:45,220
+Cyclopropane اللي مكوّن من أربع كربونات على شكل
+
+8
+00:00:45,220 --> 00:00:49,540
+حلقةCyclobutane المكوّن من خمسة Cycloبنتين
+
+9
+00:00:49,540 --> 00:00:53,640
+والمكوّن من ستة Cyclohexane طبعاً بالتأكيد لو
+
+10
+00:00:53,640 --> 00:00:56,840
+استمرنا يعني السبعة بنسميها Cycloheptane التمانية
+
+11
+00:00:56,840 --> 00:00:59,800
+Cyclo-octane التسعة Cyclo-nonane العشر Cyclo
+
+12
+00:00:59,800 --> 00:01:05,970
+-decane وهكذاالان لو بدنا نطلع بالتفصيل للمركب
+
+13
+00:01:05,970 --> 00:01:10,750
+الأول اللي هو الـ Cyclopropane هاي فيه معنى model
+
+14
+00:01:10,750 --> 00:01:15,930
+أو شكل لـ Cyclopropane لاحظوا في هذا الشكل الـ
+
+15
+00:01:15,930 --> 00:01:21,270
+Cyclopropane فيه تلت ذرات Carbon و عامل روابط اللي
+
+16
+00:01:21,270 --> 00:01:26,090
+هي عاملة الحلقة الثلاثية إذا بنلاحظ احنا على كل
+
+17
+00:01:26,090 --> 00:01:32,300
+Carbon حتى يكتمل الأربع روابط ذرتين هيدروجينواضح
+
+18
+00:01:32,300 --> 00:01:35,340
+يعني هذه الـ carbon لما بنيجي نتطلع عليها و نريها
+
+19
+00:01:35,340 --> 00:01:39,320
+تكون مكتملة بنلاحظ عليها أربع روابط رابطتين مع الـ
+
+20
+00:01:39,320 --> 00:01:43,000
+carbons المجاورة و رابطتين مع الهيدروجين
+
+21
+00:02:01,910 --> 00:02:06,410
+بنستنتج من هنا أن الصيغة العامة للـ Cycloalkanes
+
+22
+00:02:06,410 --> 00:02:13,750
+CNNH2N يعني لما يكون عندى C3 الـ H6 لما يكون عندى
+
+23
+00:02:13,750 --> 00:02:21,800
+C4 الـ H8 لما يكون عندى C5 الـ H10 و هكذاواضح؟ هذا
+
+24
+00:02:21,800 --> 00:02:25,340
+بيفرج عن الألكانز العادية، الألكانز العادية كانت
+
+25
+00:02:25,340 --> 00:02:30,540
+صيغتهم العامة بنذكر CNN H2N Plus 2 كانوا يزيدوا
+
+26
+00:02:30,540 --> 00:02:34,060
+ذارتين، طبعا هدول الذارتين اختفوا لما عملنا اللي
+
+27
+00:02:34,060 --> 00:02:38,670
+هي الرابطة الحلقية، لما سكرنا على حلقةالان هذا الـ
+
+28
+00:02:38,670 --> 00:02:42,490
+Cyclopropane لو اطلعت على ذرات الكربون التلات اللي
+
+29
+00:02:42,490 --> 00:02:46,730
+موجودين فيه بلاحظ انهم في مستوى واحد فالـ
+
+30
+00:02:46,730 --> 00:02:50,690
+Cyclopropane is a planar molecule يعني التلات
+
+31
+00:02:50,690 --> 00:02:55,170
+الذرات هي هم عامل انا ايدي موجودين في مستوى واحد
+
+32
+00:02:55,800 --> 00:02:59,580
+الان اذا انا بتطلع على الـhydrogens اللي محمولين
+
+33
+00:02:59,580 --> 00:03:02,700
+عليه ستة هيدروجين، واحد، اتنين، تلاتة، اربعة،
+
+34
+00:03:02,700 --> 00:03:06,400
+خمسة، ستة، الست ضرات هيدروجين اللي على
+
+35
+00:03:06,400 --> 00:03:10,880
+الـcyclopropane هدولة متكافئات، يعني لو بدأ أشيل
+
+36
+00:03:10,880 --> 00:03:15,240
+واحدة منهم مثلا أعمل لها إبدال، substitution بذرة
+
+37
+00:03:15,240 --> 00:03:20,690
+نفترض كلور، هاي ذرة كلورلو شيلت هادي أو هادي أو
+
+38
+00:03:20,690 --> 00:03:24,050
+هادي أو هادي أو هادي أو هادي نفس النتيجة بطلع عندى
+
+39
+00:03:24,050 --> 00:03:29,770
+فقط مُركّب واحد اللى هو اكلورو سايكلو بروبين ولو
+
+40
+00:03:29,770 --> 00:03:32,810
+رفعت اي واحدة وحطيت مكانها الكلور هيطلع نفس
+
+41
+00:03:32,810 --> 00:03:37,690
+المُركّب إذا لو أجينا سألنا كام اكلورو سايكلو
+
+42
+00:03:37,690 --> 00:03:42,910
+بروبين أنا فيه عندى واحد ايش السبب السبب انه اصلا
+
+43
+00:03:42,910 --> 00:03:48,410
+انه اصلا الهيدروجينات الستة ذرات الهيدروجينالست
+
+44
+00:03:48,410 --> 00:03:51,590
+اللي على ال cyclopropane they are equivalent أي
+
+45
+00:03:51,590 --> 00:03:56,250
+واحدة أشيلها زي التانية هذي زي هذي بقلب الجزية هذي
+
+46
+00:03:56,250 --> 00:04:01,320
+رجعت نفسها دي بلف ويك هذي نفسها دي واضح؟الان
+
+47
+00:04:01,320 --> 00:04:06,880
+لاحظوا معنى بيجينا شغلة لو قلنا بدنا نبدل واحدة
+
+48
+00:04:06,880 --> 00:04:11,720
+هيدروجين بكلور عند احتمال ناتج واحد طيب الان لو
+
+49
+00:04:11,720 --> 00:04:16,540
+بدأ ابدل واحدة تانية بكلور كام ناتج بده يطلع عنده
+
+50
+00:04:16,540 --> 00:04:21,820
+هذا المركب الواحد لو بدأ اسميه اكلورو سايكلو
+
+51
+00:04:21,820 --> 00:04:25,380
+بروبينو لأن كل الأماكن متساوية لازم أقول one
+
+52
+00:04:25,380 --> 00:04:29,140
+chlorocyclopropane لأ أبدا إكلورو سايكلو بروبين
+
+53
+00:04:29,140 --> 00:04:34,140
+الآن لو بدي أشيل كمان هيدروجينة جديدة بلاحظ ملاحظة
+
+54
+00:04:34,140 --> 00:04:38,710
+أن هذه الهيدروجينة اللي على الكربون اللي هناتمثل
+
+55
+00:04:38,710 --> 00:04:43,130
+نوع لأنها على كربون تحمل هيدروجين وهدول الأربعة
+
+56
+00:04:43,130 --> 00:04:48,990
+واحد اتنين تلاتة اربعة متكافئات اذا بهذه الحالة
+
+57
+00:04:48,990 --> 00:04:57,810
+انا عندي نوعين من الهيدروجين لو شلت هذه بعمل مركب
+
+58
+00:04:57,810 --> 00:05:01,870
+جديد هايو ايش بسمي هذا المركب جديد
+
+59
+00:05:03,790 --> 00:05:07,970
+Dichlorocyclopropane لكن وين موقع ذرتين لكلور على
+
+60
+00:05:07,970 --> 00:05:12,590
+نفس ذرة الكربون يعني أنا عند كلور وكلور على نفس
+
+61
+00:05:12,590 --> 00:05:16,270
+ذرة الكربون ولذلك هذا المركب بسميه
+
+62
+00:05:18,840 --> 00:05:23,040
+one dichlorocyclopropane هذا ايش بسمي انا one one
+
+63
+00:05:23,040 --> 00:05:26,860
+dichlorocyclopropane طبعا ممكن اتسأل ليش انا هنا
+
+64
+00:05:26,860 --> 00:05:31,700
+حطيت الرقم لأنه من ال dichlorocompound في عند
+
+65
+00:05:31,700 --> 00:05:35,740
+احتمال انه يكون عند غير ال one one ولذلك انا بحدده
+
+66
+00:05:35,740 --> 00:05:40,420
+بالارقامالان لو قلنا اعرفنا ان في عندنا مُركّب 1,1
+
+67
+00:05:40,420 --> 00:05:43,980
+-dichlorocyclopropane وإجينا بدنا نشيل واحدة من
+
+68
+00:05:43,980 --> 00:05:47,740
+هدول الـhydrogens اللي حُط مكانها إكلوري جديدة،
+
+69
+00:05:47,740 --> 00:05:51,950
+لاحظوا معنالو شيلنا هذه الـ Hydrogen اللي فوق
+
+70
+00:05:51,950 --> 00:05:58,490
+وحطينا مكانها Clor بصير المركب one two three طبعاً
+
+71
+00:05:58,490 --> 00:06:04,070
+one two dichlorocyclopropane إن ذرات الكلور واحدة
+
+72
+00:06:04,070 --> 00:06:08,330
+على موقع واحد والتاني على موقع اتنين إذن هذا one
+
+73
+00:06:08,330 --> 00:06:13,450
+two dichlorocyclopropane بنلاحظ كمان ملاحظة إضافية
+
+74
+00:06:13,450 --> 00:06:17,650
+في هذا المركب إن ذرتين الكلور هدول جايين على جهة
+
+75
+00:06:17,650 --> 00:06:21,870
+واحدة من الجزيءولمّا تكون على جهة واحدة من الجزئ
+
+76
+00:06:21,870 --> 00:06:28,470
+بنستعمل البادئة sis إذن هذا لما بدي أسميه تسمية
+
+77
+00:06:28,470 --> 00:06:34,570
+كاملة بدي أسميه sis بمعنى أنه ذرتين على جهة واحدة
+
+78
+00:06:34,570 --> 00:06:41,730
+sis one two dichlorocyclopropane واضح؟إذن أنا حددت
+
+79
+00:06:41,730 --> 00:06:46,210
+اتجاه الذرتين من خلال الـBody Assets اللي بتعني
+
+80
+00:06:46,210 --> 00:06:50,330
+إنهم على جهة واحدة أو مع بعض وحددت مواقعهم إذا
+
+81
+00:06:50,330 --> 00:06:52,890
+واحدة منهم على موقع واحد، التانية على موقع اتنين
+
+82
+00:06:52,890 --> 00:06:58,250
+فهذا المُركّب المُجمل Sys 1,2-Dichlorocyclopropane
+
+83
+00:06:58,250 --> 00:07:02,610
+الآن، كان بالإمكان، كان بالإمكان إن نحط الـChlor
+
+84
+00:07:02,610 --> 00:07:06,670
+على نفس الذرة اتنين، لكن نحطها بشكل معاكس
+
+85
+00:07:09,100 --> 00:07:14,140
+هي الكلور هذه على واحد وهذه على اتنين اذا هذا one
+
+86
+00:07:14,140 --> 00:07:18,160
+two one two هي one two three one two
+
+87
+00:07:18,160 --> 00:07:23,600
+dichlorocyclopropane لكن هنا مجموعات الكلور كيف
+
+88
+00:07:23,600 --> 00:07:28,290
+بنشوفهم احنا؟عكس بعض لما يكونوا عكس بعض بنستخدم
+
+89
+00:07:28,290 --> 00:07:32,870
+البادئة أو ال prefix ال Trans فهذا المركب أنا
+
+90
+00:07:32,870 --> 00:07:38,870
+بسميه ال Trans 1,2-dichlorocyclopropane
+
+91
+00:07:40,350 --> 00:07:46,090
+كأن أنا اللي بلخصه أنه لما بدي أحط مرتين لكلور كان
+
+92
+00:07:46,090 --> 00:07:51,410
+عنده احتمال أن أعمل الـ 1,1-dichlorocyclopropane و
+
+93
+00:07:51,410 --> 00:07:54,670
+الـ 1,2-dichlorocyclopropane الـ 1,2 في منه
+
+94
+00:07:54,670 --> 00:07:58,070
+مركبين، يا بيكونوا ذرتين لكلور مع بعض، بس هم
+
+95
+00:07:58,070 --> 00:08:03,100
+المركبSES، يا بيكونوا ذرتين لكلور عكس بعض وبسمي
+
+96
+00:08:03,100 --> 00:08:07,000
+المركّب Trans تقريبا هذه خلّيني أقول الأشياء
+
+97
+00:08:07,000 --> 00:08:12,200
+المهمة اللي ممكن نحكيها عن الـCyclopropane الآن
+
+98
+00:08:12,200 --> 00:08:15,960
+إذا انتقلنا للمركّب اللي بعده اللي هو
+
+99
+00:08:15,960 --> 00:08:22,380
+الـCycloputane اللي مكوّن من أربع ذراتربما يخطر
+
+100
+00:08:22,380 --> 00:08:28,380
+على بالكوا إن ذرات الكربون الأربعة يكونوا في مستوى
+
+101
+00:08:28,380 --> 00:08:32,340
+واحد بمعنى إن هذا الجزء يكون planner يعني جاي في
+
+102
+00:08:32,340 --> 00:08:40,280
+مستوى واحد لكن حقيقة بالتجربة العملية اللي لوحظ إن
+
+103
+00:08:40,280 --> 00:08:44,340
+هذا الجزء ليس في مستوى واحد وإنما في حالة انثناء
+
+104
+00:08:44,340 --> 00:08:49,050
+بهذا الشكلاملاحظين واضحة الصورة كيف من ثني تماما
+
+105
+00:08:49,050 --> 00:08:53,950
+بهذا الشكل احنا بنقدر نتخيله بهذا الشكل بنقدر
+
+106
+00:08:53,950 --> 00:08:58,370
+نتخيله عامل زي هيك إذا بدنا نعطي اسم هذا اللي عامل
+
+107
+00:08:58,370 --> 00:09:04,570
+زي هيك بسموه زي ال butterfly زي الفراشةعمل زي
+
+108
+00:09:04,570 --> 00:09:08,130
+الفراشة كيف الفراشة لما بتكون عاملة جناحينها
+
+109
+00:09:08,130 --> 00:09:14,190
+بزاوية فالـ Cyclobutane is not a planar molecule
+
+110
+00:09:14,190 --> 00:09:19,110
+مش جزء في مستوى واحد مش عامل زي المربع اللي في
+
+111
+00:09:19,110 --> 00:09:22,610
+مستوى واحد لأ جايب three dimensional زي ال
+
+112
+00:09:22,610 --> 00:09:28,890
+butterfly زي الفراشة واضح طبعا اكيدأكيد بنلاحظ هنا
+
+113
+00:09:28,890 --> 00:09:33,250
+في الـ «Cycloprop-butane» أنه في عندى تمانية
+
+114
+00:09:33,250 --> 00:09:37,670
+هيدروجينز والتمانية هيدروجينز هدولة متكافئات لكن
+
+115
+00:09:37,670 --> 00:09:41,930
+لو بدى أعمل عمليات إبدال بلاحظ أنه بإمكاني أبدل
+
+116
+00:09:41,930 --> 00:09:46,130
+على نفس الـCarbon تنتين أو تلاتة أو على الـCarbon
+
+117
+00:09:46,130 --> 00:09:49,310
+اللي جنبها أو على الـCarbon اللي جبالها وممكن يكون
+
+118
+00:09:49,310 --> 00:09:53,010
+عندى أشياء على نفس الاتجاه تعطيني «cis» وأشياء
+
+119
+00:09:53,010 --> 00:09:57,540
+باتجاهات متعاكزة تعطيني «trans» فالخلاصةإن لو أنا
+
+120
+00:09:57,540 --> 00:10:02,620
+بدأ أقول Clorocyclobutane
+
+121
+00:10:02,620 --> 00:10:07,200
+عند منه مركب واحد بشيل أي هيدروجينة التمانية زي
+
+122
+00:10:07,200 --> 00:10:10,680
+بعض التمانية زي بعض و بحط Clor بصير عند
+
+123
+00:10:10,680 --> 00:10:15,200
+Clorocyclobutane التمن هيدروجينز زي بعض لكن لو كنت
+
+124
+00:10:15,200 --> 00:10:20,420
+بدأ أحط التانيةالعدد بيكبر عندى، ليش؟ لأن أنا ممكن
+
+125
+00:10:20,420 --> 00:10:23,940
+أحط التاني على نفس هذه الكربونة، ممكن أحطها على
+
+126
+00:10:23,940 --> 00:10:26,580
+هذه الكربونة باتجاه الأولى أو على هذه الكربونة
+
+127
+00:10:26,580 --> 00:10:29,160
+باتجاه التانية، ممكن أحطها على الكربونة على موقع
+
+128
+00:10:29,160 --> 00:10:32,680
+تلاتة، يعني هنا بيصير عندى one two لو حطيتها هنا،
+
+129
+00:10:32,680 --> 00:10:36,380
+لو حطيتها هنا one two three، one three باتجاه
+
+130
+00:10:36,380 --> 00:10:39,540
+واحد، six، one three باتجاه متعاكس، trans،
+
+131
+00:10:39,540 --> 00:10:43,120
+فالخلاصة أنه بيصير عندى أكتر من isomers ال one one
+
+132
+00:10:44,290 --> 00:10:49,210
+و الـ 1,2-cis و الـ 1,2-trans و الـ 1,3-cis و الـ
+
+133
+00:10:49,210 --> 00:10:55,930
+1,3-trans كل هدولة المركبات ممكن أن نلاحظ وجودهم
+
+134
+00:10:55,930 --> 00:11:01,110
+في الـcyclobutane اللي عامل زي الـ butterfly and
+
+135
+00:11:01,110 --> 00:11:04,570
+it is not a planar molecule هي مرة تانية بنفرجيكوا
+
+136
+00:11:04,570 --> 00:11:10,230
+إياها كيف هو بكر مطعوج يعني عامل زي الفراشة واضح
+
+137
+00:11:10,230 --> 00:11:17,260
+هذا الكلام؟بعد الـ Cyclopentane بننتقل للمُركّب
+
+138
+00:11:17,260 --> 00:11:19,840
+اللي بعده اللي فيه خمس كربونات واللي اسمه
+
+139
+00:11:19,840 --> 00:11:23,560
+Cyclopentane إذا بدنا نتطلع على الشكل العام اللي
+
+140
+00:11:23,560 --> 00:11:28,080
+موجود فيه طبعاً بتلاحظ وهيوا أمامكم أنه فيه خمس
+
+141
+00:11:28,080 --> 00:11:33,560
+ذرات كربون عشر ذرات هيدروجين C5H10 ماشي على نفس
+
+142
+00:11:33,560 --> 00:11:40,380
+الصيغة CNH2N فقط الآن لو قلنا كيف الشكل البعض ربما
+
+143
+00:11:40,380 --> 00:11:44,690
+يتخيل أنه Cyclopentane بلانريعني يكون في مستوى
+
+144
+00:11:44,690 --> 00:11:50,510
+واحد لكن الجواب برضه لأ بالتجربة الـ Cyclopentane
+
+145
+00:11:50,510 --> 00:11:54,690
+is not a planar إذا بتطلعوا ماخد هذا الشكل لو
+
+146
+00:11:54,690 --> 00:11:59,790
+بنطلع على هذا الشكل بنلاحظ إنه هنا في عند ما يشبه
+
+147
+00:11:59,790 --> 00:12:06,710
+المستوى وهذا الـ Carbon طالع عن المستوى في هذه
+
+148
+00:12:06,710 --> 00:12:11,830
+الحالة مين يعطينا أقرب تشبيه ممكن يشبه من الحياة
+
+149
+00:12:11,830 --> 00:12:17,190
+لهذا الشكل؟لاحظوا هاي أربعة موجودين في مستوى واحد
+
+150
+00:12:17,190 --> 00:12:23,210
+اللي هما تحديداً هايهم هنا عندنا واحد، اتنين،
+
+151
+00:12:23,210 --> 00:12:27,270
+تلاتة، أربعة في مستوى واحد وهذه طالعة عنهم هذا
+
+152
+00:12:27,270 --> 00:12:33,800
+الشكل يشبه ماذا؟يشبه اللي هو مظروف المكتوب المفتوح
+
+153
+00:12:33,800 --> 00:12:38,700
+it is like an open envelope واضح؟ فاحنا اللي
+
+154
+00:12:38,700 --> 00:12:43,720
+بنقوله ان الـcyclopentane is not a planar molecule
+
+155
+00:12:43,720 --> 00:12:48,820
+it is like an open envelopeزي المكتوب المفتوح الآن
+
+156
+00:12:48,820 --> 00:12:52,520
+بتلاحظوا معنى برضه أنه فيه عشر Hydrogens
+
+157
+00:12:52,520 --> 00:12:56,000
+equivalent لكن لما بدنا نشيل أكتر من Hydrogens
+
+158
+00:12:56,000 --> 00:13:00,420
+دنتين أو تلاتة بيصير عندى عدد كبير من ال isomers
+
+159
+00:13:00,420 --> 00:13:05,900
+يمكن أنه تجربوها ع الورق وتحسبوها بشكل كامل لكن
+
+160
+00:13:05,900 --> 00:13:11,720
+بشكل عام هذا هو شكل ال Cyclopentane it is like an
+
+161
+00:13:11,720 --> 00:13:15,950
+open envelopeهيكوا شايفين القاعدة وهذا الجزء اللي
+
+162
+00:13:15,950 --> 00:13:22,330
+هو يمثل المظروف المفتوح الـ Open Envelope بننتقل
+
+163
+00:13:22,330 --> 00:13:27,930
+الآن للشكل التالي اللي هو الـ Cyclohexane اللي فيه
+
+164
+00:13:27,930 --> 00:13:31,910
+6 ذرات كربون طبعا ربما البعض يعتقد ان الـ
+
+165
+00:13:31,910 --> 00:13:36,620
+Cyclohexaneماخد الشكل البلانر زي ما بيبدو على
+
+166
+00:13:36,620 --> 00:13:40,800
+الشاشة لكن الحقيقة في التجربة أو في الواقع لأ
+
+167
+00:13:40,800 --> 00:13:44,780
+الشكل مابيجيش بلانر الـ 6 ذرات كربون مابيجيش بلانر
+
+168
+00:13:44,780 --> 00:13:50,440
+لكن بياخد عدة أشكال من هذه الأشكال اللي ممكن
+
+169
+00:13:50,440 --> 00:13:54,940
+ياخدها الـ Cyclohexane إذا بنركز احنا على ذرات
+
+170
+00:13:54,940 --> 00:13:59,440
+الكربون اللي بيظهروا عندنا باللون الأسود هنا هاي
+
+171
+00:13:59,440 --> 00:14:04,980
+واحد، اتنين، تلاتةأربعة، خمسة، ستة يعني نتخيل
+
+172
+00:14:04,980 --> 00:14:08,160
+الهيكل الكربوني اللي هو الذرات السود اللي محمولين
+
+173
+00:14:08,160 --> 00:14:13,300
+بالروابط البيضة إذا بنلاحظ هذا الشكل اللي موجود هو
+
+174
+00:14:13,300 --> 00:14:17,560
+شكل بهذا الشكل و بهذا الشكل و بهذا الشكل طالع لفوق
+
+175
+00:14:17,560 --> 00:14:22,380
+هيواضح واحد، اتنين، تلاتة الآن مين يقولنا هذا
+
+176
+00:14:22,380 --> 00:14:26,350
+الشكل يشبه ماذا؟خلّي تركيزنا فقط على الكرات
+
+177
+00:14:26,350 --> 00:14:31,850
+السوداء والروابط البيضاء هذا الشكل حقيقة هو شكل
+
+178
+00:14:31,850 --> 00:14:37,530
+يشبه القارب يشبه القارب تماما بهذا الشكل واضح؟
+
+179
+00:14:37,530 --> 00:14:44,070
+ولذلك الـ Cyclohexane بهذه الهيئة اللي مرسوم فيها
+
+180
+00:14:44,070 --> 00:14:51,340
+بنسميه احناماخد الـ Boat Conformation هيئة القارب
+
+181
+00:14:51,340 --> 00:14:55,160
+ماخد الـ Boat Conformation لاحظوا هذا الـ Boat
+
+182
+00:14:55,160 --> 00:15:00,360
+Conformation اللي ماخده الـ Cyclohexane فيه مشكلة
+
+183
+00:15:00,360 --> 00:15:04,320
+ايش المشكلة اللي فيه؟المشكلة اللي فيه إذا نظرنا
+
+184
+00:15:04,320 --> 00:15:08,380
+للهيدروجين و أنا .. أنا حاطه بألوان مختلفة بلاحظ
+
+185
+00:15:08,380 --> 00:15:12,520
+إنه الهيدروجين اللي على هذا الرأس للقارب و
+
+186
+00:15:12,520 --> 00:15:16,180
+الهيدروجين اللي على هذا الرأس نوعا ما قريب من بعض
+
+187
+00:15:16,180 --> 00:15:23,400
+يعني بنقدر نسمع صوتهم يعني ممكن يخبطوا في بعض هدول
+
+188
+00:15:23,400 --> 00:15:27,300
+الهيدروجين قريب من بعض إيش معنى الهيدروجين قريب من
+
+189
+00:15:27,300 --> 00:15:34,330
+بعض؟إنه بيخلّي شكل الـ Bot Conformation شكل الثبات
+
+190
+00:15:34,330 --> 00:15:38,990
+عنده مش عالي It is not stable confirmation طيب،
+
+191
+00:15:38,990 --> 00:15:44,690
+كيف ممكن أعمل شكل أبعد هدول عن بعض؟ بتعرفوا دائما،
+
+192
+00:15:44,690 --> 00:15:48,910
+المبدأ في الأشكال الهندسية في الكيميا قدر الإمكان
+
+193
+00:15:48,910 --> 00:15:53,930
+إن الذرات تتبعد عن بعض، تتفسحزي ما بتقول الآية
+
+194
+00:15:53,930 --> 00:15:57,230
+أيها الذين آمنوا إذا قيل لكم تفسحوا في المجالس
+
+195
+00:15:57,230 --> 00:16:02,470
+فافسحوا يفسح الله لكم الآن بحركوا بهذا الشكل
+
+196
+00:16:02,470 --> 00:16:07,810
+بحاولوا من هيئة القارب اللي إحنا شايفينها واضحة
+
+197
+00:16:07,810 --> 00:16:12,390
+تماما الهيئة التانية هذه الهيئة التانية إذا بنتطلع
+
+198
+00:16:12,390 --> 00:16:19,950
+عليها بنلاحظ إنها مميزة بالآتي إن أنا في عندهطبعا
+
+199
+00:16:19,950 --> 00:16:23,590
+ال models نوعا ما بتساعد و بأمل أنها بتساعد في
+
+200
+00:16:23,590 --> 00:16:28,690
+عندي ما يشبه القاعدة في عندي ما يشبه الظهر و في
+
+201
+00:16:28,690 --> 00:16:33,430
+عندي ما يشبه الرجلين إذا أنا صرت أمام هيئة شبيهة
+
+202
+00:16:33,430 --> 00:16:37,670
+بهيئة الكرسي هذا الكرسي إذا بتلاحظوا الإيد الشمال
+
+203
+00:16:37,670 --> 00:16:43,230
+اللي عندي ماسك الظهر تبعه الإيد اليمين ماسك الرجل
+
+204
+00:16:43,230 --> 00:16:50,480
+تبعتهاللي موجود في الوسط هو المكان الجلوس في
+
+205
+00:16:50,480 --> 00:16:55,900
+الكرسي هذه الهيئة بيسموها الـ Chair Conformation
+
+206
+00:16:55,900 --> 00:16:59,580
+هذه الهيئة بيسموها الـ Chair Conformation هيئة
+
+207
+00:16:59,580 --> 00:17:04,640
+الكرسي طبعا موجودة عندكم على الشاشة هيئة القارب
+
+208
+00:17:04,640 --> 00:17:07,740
+الـ Boat Conformation موجود عندكم على الشاشة هيئة
+
+209
+00:17:07,740 --> 00:17:13,730
+الكرسي الآن إذا أنا بتطلع على هيئة الكرسيلاحظوا أن
+
+210
+00:17:13,730 --> 00:17:18,630
+الـ 12 هيدروجينة لأن الـ Cyclohexane C6H12 مقسمين
+
+211
+00:17:18,630 --> 00:17:24,660
+إلى نوعين من الهيدروجينالـ 12 هيدروجينة مقسمين إلى
+
+212
+00:17:24,660 --> 00:17:29,740
+نوعين في هيئة الكرسي في عندي الـ Hydrogens اللي
+
+213
+00:17:29,740 --> 00:17:34,720
+لونهم أخضر باللاحظ أنه موجودين تلاتة للأعلى و
+
+214
+00:17:34,720 --> 00:17:38,580
+تلاتة للأسفل طبعا بزام عموديات سواء للأعلى أو
+
+215
+00:17:38,580 --> 00:17:43,660
+للأسفل بقول عنهم Axial Axial يعني عموديات إذا أنا
+
+216
+00:17:43,660 --> 00:17:52,960
+عندي6 Axial Hydrogen 3 above the molecule 1 2 3
+
+217
+00:17:52,960 --> 00:17:58,260
+and 3 below the molecule 1 2 3 الباقيين اللي هم
+
+218
+00:17:58,260 --> 00:18:03,190
+ماخدين اللون البرتقالي هدول بشكل عامجايين باتجاه
+
+219
+00:18:03,190 --> 00:18:08,830
+جانبي الـ 6، 1، 2، 3، 4، 5، 6، نوعًا ما ماخدين
+
+220
+00:18:08,830 --> 00:18:12,750
+الوضع الجانبي لكن لما تتطلعوا بوضوح وين التلاتة
+
+221
+00:18:12,750 --> 00:18:17,490
+اللي هم أكتر عموديات للأعلى، بالذات لما يكون ثابت
+
+222
+00:18:17,490 --> 00:18:20,730
+الشكل ما بيغلبناش، هايهم، شايفين التلاتة الخضر؟
+
+223
+00:18:21,290 --> 00:18:25,510
+واضحين جداً هدولة التلاتة الخضر اللي هما الـ axial
+
+224
+00:18:25,510 --> 00:18:30,370
+تلاتة فوق و تلاتة تحت والباقيين الستة equatorial
+
+225
+00:18:30,370 --> 00:18:36,550
+إذا الـ 12 هيدروجين يقسموا إلى 6 axial hydrogens 3
+
+226
+00:18:36,550 --> 00:18:39,710
+above the molecule and 3 below the molecule and
+
+227
+00:18:39,710 --> 00:18:45,110
+another 6 equatorial hydrogens let's say in the
+
+228
+00:18:45,110 --> 00:18:49,710
+plane of the moleculeالان هذا الشكل اللي انا عمال
+
+229
+00:18:49,710 --> 00:18:54,230
+رسمه و بقول هي الظاهر تبعه موجود بإيد الشمال انا
+
+230
+00:18:54,230 --> 00:18:59,890
+ماسكه و القاعدة موجودة باليد اليمنى يمكن ان اعمله
+
+231
+00:18:59,890 --> 00:19:03,350
+flipping اجلبه زي ما بتجلب الشمسية بتلاعبوا كيف
+
+232
+00:19:03,350 --> 00:19:06,870
+بتجلب الشمسية في الهواء ممكن اجلبه هذا الظاهر
+
+233
+00:19:06,870 --> 00:19:14,230
+اخليه يمثل الرجلين اللي تحت وهذا الرجلين اجلبهم
+
+234
+00:19:14,230 --> 00:19:18,800
+يمثلوا الظاهر اللي الاعلىلاحظوا هنا أنا جلبتهم
+
+235
+00:19:18,800 --> 00:19:23,680
+بهذا الشكل الجميل صار عندى هي اليد اليمين ماسكة
+
+236
+00:19:23,680 --> 00:19:28,120
+الظهر واليد الشمال ماسكة الرجل اللى تحت هنا
+
+237
+00:19:28,120 --> 00:19:32,480
+بتلاحظوا ملاحظة ان ال hydrogens الخضر اللى كانوا
+
+238
+00:19:32,480 --> 00:19:37,120
+axial صاروا equatorial و ال hydrogens اللى مبينين
+
+239
+00:19:37,120 --> 00:19:40,560
+بورتغاني اللى كانوا مبينين على الجنب equatorial
+
+240
+00:19:40,560 --> 00:19:46,370
+صاروا axial تلاتة فوقالتلاتة تحت، إذا عملية الـ
+
+241
+00:19:46,370 --> 00:19:50,010
+flipping هنا في هذا الجزء بتغلب الهيدروجينز الـ
+
+242
+00:19:50,010 --> 00:19:53,230
+axial hydrogen will be equatorial and the
+
+243
+00:19:53,230 --> 00:19:57,630
+equatorial hydrogen will be axial املاحظين هنا وين
+
+244
+00:19:57,630 --> 00:20:02,010
+ال axial؟ التلاتة البوردجانياتوين الـ equatorial
+
+245
+00:20:02,010 --> 00:20:07,210
+صاروا النوع الأخضر لما بعمله flipping بنعكسه الآن
+
+246
+00:20:07,210 --> 00:20:11,990
+أي الأشكال أثبت لـ Chair Conformation هيئة الكرسي
+
+247
+00:20:11,990 --> 00:20:16,370
+و لا هيئة القارب؟ خلّيني أكد عليه السؤال، هذا سؤال
+
+248
+00:20:16,370 --> 00:20:20,600
+مهم أي الأشكال أثبتالـ Chair Conformation اللي
+
+249
+00:20:20,600 --> 00:20:23,340
+احنا عاملا مسكين و هيظهر و هيرجلين ولا الـ Boat
+
+250
+00:20:23,340 --> 00:20:27,000
+Conformation؟ احنا قلنا الـ Boat Conformation في
+
+251
+00:20:27,000 --> 00:20:31,820
+استدام لذرات الهيدروجين ببعض، إقراب من بعض ولذلك
+
+252
+00:20:31,820 --> 00:20:37,340
+يعتبر الـ Chair Conformation more stable than الـ
+
+253
+00:20:37,340 --> 00:20:41,220
+Boat Conformation واضح؟ الـ Chair Conformation of
+
+254
+00:20:41,220 --> 00:20:45,750
+Cyclohexane is more stablethan the bot
+
+255
+00:20:45,750 --> 00:20:51,090
+confirmation الان لو اتخيلنا ان احنا كل اللي موجود
+
+256
+00:20:51,090 --> 00:20:55,810
+عندنا هيدروجين و بدنا نرفع هيدروجين و نحط بدالها
+
+257
+00:20:55,810 --> 00:21:02,170
+مجموعة مثل جروب هاي مجموعة مثل انماسكا CH3 مش هذه
+
+258
+00:21:02,170 --> 00:21:07,850
+مجموعة المثل الان لاحظوا لو شيلت هذه الهيدروجين و
+
+259
+00:21:07,850 --> 00:21:16,140
+حطيت بدالهامجموعة الميثل CH3 وهي ماسك الجزء،
+
+260
+00:21:16,140 --> 00:21:20,100
+لاحظوا هيظهر على الإيد اليمين والرجل في الإيد
+
+261
+00:21:20,100 --> 00:21:24,780
+اليسرى، إيش بتلاحظوا هنا في هذا الشكل؟ إن الميثل
+
+262
+00:21:24,780 --> 00:21:32,360
+جروب لو كانت Axial، بتبدأ تصير قريبة من
+
+263
+00:21:32,360 --> 00:21:38,910
+الـHydrogensولذلك لاحظوا هاي التلاتة axials H وH
+
+264
+00:21:38,910 --> 00:21:43,210
+ومثل لكن المثل أجمالها صارت قريبة من ال hydrogens
+
+265
+00:21:43,210 --> 00:21:48,910
+طيب لو لفيت الجزيق لو لفيت الجزيق بهذا الشكل
+
+266
+00:21:48,910 --> 00:21:55,370
+هينرجعت الذرات اللي لونهم أخضر يكونوا axialزي ما
+
+267
+00:21:55,370 --> 00:21:59,430
+بتلاحظوا هيوم التلاتة الخضر انبينين أقرب شق لكم
+
+268
+00:21:59,430 --> 00:22:03,070
+Axial وين صارت الـ Methyl group؟ صارت الـ Methyl
+
+269
+00:22:03,070 --> 00:22:06,950
+group equatorial الآن وين الـ Methyl group عاملة
+
+270
+00:22:06,950 --> 00:22:11,410
+مشاكل أكتر؟ تكون equatorial ولا Axial؟ بالتأكيد
+
+271
+00:22:11,410 --> 00:22:14,690
+لما بتكون equatorial مافيش إش تصطدم معه، تتنافر
+
+272
+00:22:14,690 --> 00:22:18,730
+معه لكن لما كانت Axial شوفنا إنها جريبة من two
+
+273
+00:22:18,730 --> 00:22:24,310
+other hydrogensولذلك الـ methylcyclohexane بفضل
+
+274
+00:22:24,310 --> 00:22:28,810
+يكون بالـ circle formation والـ methyl group تكون
+
+275
+00:22:28,810 --> 00:22:33,690
+في الـ equatorial position بأكد الـ methyl group
+
+276
+00:22:33,690 --> 00:22:37,750
+وين أفضل تكون؟ في ال axial ولا في ال equatorial؟
+
+277
+00:22:38,500 --> 00:22:42,380
+الـ methyl group بتفضل تكون في الـ equatorial
+
+278
+00:22:42,380 --> 00:22:46,080
+position هي شايفين أين جاية؟ على الجانب في ال
+
+279
+00:22:46,080 --> 00:22:49,860
+equatorial position مش في ال Axial position ولذلك
+
+280
+00:22:49,860 --> 00:22:55,100
+هدول الشكلين النسبة بينهم حقيقةفي الـ Cyclohexane
+
+281
+00:22:55,100 --> 00:22:59,680
+بتكون 95% من الوقت الـ methyl group في الـ
+
+282
+00:22:59,680 --> 00:23:04,280
+equatorial position و فقط 5% من الوقت في الـ axial
+
+283
+00:23:04,280 --> 00:23:07,220
+position لأنه لما بتكون في الـ axial position
+
+284
+00:23:07,220 --> 00:23:12,680
+بتكون عملت نافر مع الـ hydrogen أو الـ two
+
+285
+00:23:12,680 --> 00:23:17,370
+hydrogens اللي موجودين إقراب منهاطبعًا انتبهوا معي
+
+286
+00:23:17,370 --> 00:23:21,190
+في أكبر من الـ methyl group يعني لو أنا بدي أشيل
+
+287
+00:23:21,190 --> 00:23:25,970
+الـ methyl group هذه وأحط بدالها أكبر group في الـ
+
+288
+00:23:25,970 --> 00:23:28,910
+organic chemistry اللي هي tertiary-butyl الأربع
+
+289
+00:23:28,910 --> 00:23:35,270
+كربونات سبق أخدناها كربون متفرع منها مثل و مثل و
+
+290
+00:23:35,270 --> 00:23:39,290
+مثل هذه إيش بنسميها المجموعة هي موجودة tertiary
+
+291
+00:23:39,290 --> 00:23:44,750
+-butyl أربع كربونات واحد اتنين تلاتة أربعةهذه
+
+292
+00:23:44,750 --> 00:23:49,530
+المجموعة ترتشير بيوتل لما بدأت أحطها اتخيلوا قداش
+
+293
+00:23:49,530 --> 00:23:54,390
+انا بتريح لو حطيت هذه المجموعة في ال equatorial
+
+294
+00:23:54,390 --> 00:23:58,590
+position بتعملش عندي مشاكل هاي الشكل اللي عنده
+
+295
+00:23:58,590 --> 00:24:04,410
+واضح تماما التلت مجموعات ال axial اللي هي واحدة
+
+296
+00:24:04,410 --> 00:24:08,370
+تنتين تلاتة الآن هنا هذه ال tertiary butyl في أي
+
+297
+00:24:08,370 --> 00:24:12,480
+مستوىفي الـ equatorial هي في مستوى الجزيئة مش جاية
+
+298
+00:24:12,480 --> 00:24:18,000
+عمودية ولذلك هذا الجزيئ بيكون بنسبة مية في المية
+
+299
+00:24:18,000 --> 00:24:21,440
+tertiary butyl group جاية على ال equatorial
+
+300
+00:24:21,440 --> 00:24:25,740
+position اتخيلوا لو كنا بدنا نلفه و نحطها على ال
+
+301
+00:24:25,740 --> 00:24:29,880
+axial position خليني نعمل يعني هذا بدل ما هو ظهر
+
+302
+00:24:29,880 --> 00:24:33,980
+الكرسي نخليه رجل و هذا بدل ما هو رجل الكرسي اللي
+
+303
+00:24:33,980 --> 00:24:40,070
+لتحت نخليها ظهر هي ده خلينها ظهر و هذهخلناها الـ
+
+304
+00:24:40,070 --> 00:24:44,340
+«ريتشار»الان اتخيلوا هذه الـ tertiary-butyl group
+
+305
+00:24:44,340 --> 00:24:50,100
+هى هى إيش عاملة هنا مشاكل؟ وإيش عاملة هنا مشاكل؟
+
+306
+00:24:50,100 --> 00:24:54,320
+بتبدأ تصطدم .. بتبدأ تصطدم مع الـhydrogens اللى
+
+307
+00:24:54,320 --> 00:24:59,180
+موجودين هنا وهنا ولذلك هل يفضل إنه هذه .. هى الشكل
+
+308
+00:24:59,180 --> 00:25:03,460
+الكرسي ممتاز جدا بهذا الشكل؟ والـtertiary-butyl
+
+309
+00:25:03,460 --> 00:25:07,040
+على الـaxial؟ هنا على الـaxial نسبتها 0% لإنها
+
+310
+00:25:07,040 --> 00:25:12,640
+بتعمل مشاكل مع الـhydrogens لجرابسمعين؟ هاي مع الـ
+
+311
+00:25:12,640 --> 00:25:18,140
+hydrogen لغريبة بتعمل مشاكل واضح؟ ولذلك بتكون الـ
+
+312
+00:25:18,140 --> 00:25:22,900
+tertiary-butyl بنسبة 0% بهذا الشكل الأكسي لغريبة
+
+313
+00:25:22,900 --> 00:25:29,120
+هي عمال بتصطدم بالـhydrogens وبتفضل أن الجزء ألف
+
+314
+00:25:29,120 --> 00:25:35,550
+نفسه بحيث أنه هي تصيرفي الـ equatorial position هي
+
+315
+00:25:35,550 --> 00:25:38,430
+الآن لما راحت على ال equatorial position وهي دهر
+
+316
+00:25:38,430 --> 00:25:42,270
+الكرسي لاحظوا هنا عاملة مشاكل في ال equatorial
+
+317
+00:25:42,270 --> 00:25:47,110
+position لأ وين بتعمل مشاكل لما تكون في ال axial
+
+318
+00:25:47,110 --> 00:25:49,670
+position هي ال equatorial position
+
+319
+00:25:53,290 --> 00:25:56,190
+هي الـ equatorial position الـ tertiary butyl
+
+320
+00:25:56,190 --> 00:26:01,450
+طالعة فيه لبرا مش عاملة عندي مشاكل ولذلك لما بدأ
+
+321
+00:26:01,450 --> 00:26:04,490
+أقول قداش نسبة ال tertiary butyl في ال equatorial
+
+322
+00:26:04,490 --> 00:26:10,150
+و ال axial بقول في ال equatorial 100% بال axial 0%
+
+323
+00:26:10,150 --> 00:26:15,830
+لأنها بتعمل تنافرمع ذرات الهيدروجين التانيات اللي
+
+324
+00:26:15,830 --> 00:26:20,310
+موجودين عنده لو كانت في الـ Axial Position هذا
+
+325
+00:26:20,310 --> 00:26:25,870
+بشكل عام ملخص عن الـ Cycloalkanes هذا بشكل عام
+
+326
+00:26:25,870 --> 00:26:29,470
+ملخص عن الـ Cycloalkanes أخدنا فيه الـ
+
+327
+00:26:29,470 --> 00:26:34,430
+Cyclopropane الـ Cyclobutane الـ Cyclopentane والـ
+
+328
+00:26:34,430 --> 00:26:35,610
+Cyclohexane
+
+329
+00:26:37,740 --> 00:26:43,920
+طبعاً بنختم بشغلة بسيطة أنه بشكل عام الـ alkanes و
+
+330
+00:26:43,920 --> 00:26:50,560
+الـ cycloalkanes هل لهم تفاعلات؟ الجواب أنه بشكل
+
+331
+00:26:50,560 --> 00:26:54,240
+عام يعتبروا الـ alkanes و الـ cycloalkanes inert
+
+332
+00:26:54,240 --> 00:26:58,680
+يعني تفاعلاتهم قليلة جدا و لذلك كثيرا ما تستخدم
+
+333
+00:26:58,680 --> 00:27:03,900
+الـ alkanes و الـ cycloalkanes as solventsمشهور
+
+334
+00:27:03,900 --> 00:27:09,380
+لهم تفاعلين فقط للـ Alkanes اللي هو تفاعل الـ
+
+335
+00:27:09,380 --> 00:27:14,440
+Combustion انه احنا الـ Alkanes بنحرقهم بنطلع ثانو
+
+336
+00:27:14,440 --> 00:27:19,060
+أكسيد كربون وميه و الناتج الأهم ربما اللي مش مكتوب
+
+337
+00:27:19,060 --> 00:27:24,210
+هنا هو حرارةبديش أنا أنسى إنه البنزين تبع السيارات
+
+338
+00:27:24,210 --> 00:27:28,110
+الجازولين أو ال fuel هو عبارة عن خليط من الهيبتين
+
+339
+00:27:28,110 --> 00:27:31,810
+والأيزو أكتين لما أنا بحرقه بموتور السيارة بطلع
+
+340
+00:27:31,810 --> 00:27:36,490
+عندي ثانوكسيد كربون ومية وحرارة الناتج المهم إليه
+
+341
+00:27:36,490 --> 00:27:41,860
+في موتور السيارة شو هو؟الحرارة الناتج الدار واللي
+
+342
+00:27:41,860 --> 00:27:45,300
+بيعمل الـ greenhouse effect المشكلة البيئية
+
+343
+00:27:45,300 --> 00:27:50,420
+الكبيرة هو ثاني أكسيد الكربون واضح؟ طبعا احنا
+
+344
+00:27:50,420 --> 00:27:55,440
+مضطرين نستعمل الجازولين كوقود للسيارات لأن احنا
+
+345
+00:27:55,440 --> 00:27:59,870
+بدنا ال energy أو الطاقةهذا بالنسبة لتفاعل ال
+
+346
+00:27:59,870 --> 00:28:04,230
+combustion ومعنى combustion burning in the
+
+347
+00:28:04,230 --> 00:28:09,310
+presence of oxygen الحرق في وجود ال oxygen يعني في
+
+348
+00:28:09,310 --> 00:28:12,890
+السيارة لما أنا بحرق البنزين بحرق البنزين لحاله
+
+349
+00:28:12,890 --> 00:28:17,310
+ولا فيه oxygenلأ في Oxygen و لازم تكون النسبة
+
+350
+00:28:17,310 --> 00:28:22,330
+دقيقة جدا ما بين البنزين و ما بين الهواء اللي فيه
+
+351
+00:28:22,330 --> 00:28:25,930
+ال Oxygen و الجزء في السيارة اللي بنظم هذا الكلام
+
+352
+00:28:25,930 --> 00:28:28,650
+أكيد نسبة كبيرة منكم بتعرف اللي بيسموه ال
+
+353
+00:28:28,650 --> 00:28:34,490
+Carburetor و لو صار في خلل ما بين نسبة الوقودوالـ
+
+354
+00:28:34,490 --> 00:28:40,330
+Oxygen بيصير مشاكل ممكن يؤدي إلى عدم احتراق كامل
+
+355
+00:28:40,330 --> 00:28:45,270
+للبنزين ويصير يطلع من السيارة دخان أسود دليل على
+
+356
+00:28:45,270 --> 00:28:49,930
+أنه البنزين لم يتم أو الوقود لم يتم حرقه بشكل
+
+357
+00:28:49,930 --> 00:28:53,570
+كامل، واضح؟ فالتفاعل الأول لل Alkanes هو ال
+
+358
+00:28:53,570 --> 00:28:57,440
+combustion، الحرق في وجود ال Oxygenالان التفاعل
+
+359
+00:28:57,440 --> 00:29:01,640
+الثاني الـ halogenation ان انا اي الكان يعني لو
+
+360
+00:29:01,640 --> 00:29:05,660
+افترضت مثلا انه عندى ميثين هذا الميثين اللى انا
+
+361
+00:29:05,660 --> 00:29:11,820
+ماسكه الان بايدى ممكن اعمله ابدال بذرات معينة يعني
+
+362
+00:29:11,820 --> 00:29:16,940
+ممكن ابدله مثلا بذرة كلورين يعني اشيل هيدروجين
+
+363
+00:29:16,940 --> 00:29:22,120
+وابدله بكلور صار ايش اسمه كلور وميثين ممكن اشيل
+
+364
+00:29:22,120 --> 00:29:25,650
+الهيدروجين التانى وابدله بكمان كلورصار
+
+365
+00:29:25,650 --> 00:29:29,630
+دايكلوروميثين ممكن أشيل الهيدروجين التالتة وأبدل
+
+366
+00:29:29,630 --> 00:29:33,330
+بكلور صار تريكلوروميثين اللي إله اسم شورا
+
+367
+00:29:33,330 --> 00:29:37,290
+كلوروفورم CHCl3
+
+368
+00:29:37,290 --> 00:29:42,810
+وممكن أشيل الهيدروجين الرابعة وأبدل مثلا بكلور صار
+
+369
+00:29:42,810 --> 00:29:48,130
+ال carbon tetrachloride أو ال tetrachlorocarbon
+
+370
+00:29:48,430 --> 00:29:52,550
+أذا تفاعل تاني مشهور عن الـ Alkanes اللي هو تفاعل
+
+371
+00:29:52,550 --> 00:29:55,830
+الـ Substitution لما أنا بفعل الـ Alkanes مع الـ
+
+372
+00:29:55,830 --> 00:30:02,790
+Halogens و هذا التفاعل بيلزم وجود حرارة أو ضوء شمس
+
+373
+00:30:02,790 --> 00:30:06,790
+حتى يتم التفاعل إذا الـ Alkanes بتفاعل مع الـ
+
+374
+00:30:06,790 --> 00:30:11,330
+Halogens في وجود الضوء أو الحرارة بيصير عندى إبدال
+
+375
+00:30:11,330 --> 00:30:14,490
+و ممكن أكتر من إبدال يعني ممكن إبدال اتنين تلاتة
+
+376
+00:30:14,490 --> 00:30:20,170
+أربعة و طبعالما يكون الجزء الكبير بيصير عندى عدد
+
+377
+00:30:20,170 --> 00:30:26,280
+كبير من المتشكلات اللى يمكن أن تنتجهذه عملية
+
+378
+00:30:26,280 --> 00:30:31,020
+الـhalogenation طبعاً في إلها آلية في إلها آلية
+
+379
+00:30:31,020 --> 00:30:35,960
+بتتم فيها هذه الآلية بتفترض الآتي إذا إحنا بدنا
+
+380
+00:30:35,960 --> 00:30:42,040
+باختصار نحكي عن الـ mechanism of halogenation يعني
+
+381
+00:30:42,040 --> 00:30:46,680
+كيف بتتم عملية الـhalogenation الـhalogenation
+
+382
+00:30:46,680 --> 00:30:50,160
+خلينا نفترض إن هو إننا الميثين وفي عندنا
+
+383
+00:30:50,160 --> 00:30:58,770
+الـhalogen اللي هو الكلورهذا الكلور موجود كجزء على
+
+384
+00:30:58,770 --> 00:31:05,530
+شكل Cl2 هاي عندي الميثين وهي عندي جزء الكلور إيش
+
+385
+00:31:05,530 --> 00:31:10,910
+اللي بتتم؟ في الخطوة الأولى الحرارة بتكسر جزء
+
+386
+00:31:10,910 --> 00:31:16,270
+الكلور من النص الحرارة إيش بتعمل؟بتكسر جزء الكلور
+
+387
+00:31:16,270 --> 00:31:20,550
+من النص بيطلع إلكترون هنا و إلكترون هنا يعني كأنه
+
+388
+00:31:20,550 --> 00:31:24,910
+بيصير two free radical هذه كلور معقد إلكترون وهذه
+
+389
+00:31:24,910 --> 00:31:29,630
+كلور معقد إلكترون إذا الخطوة الأولى في الميكانزم
+
+390
+00:31:29,630 --> 00:31:35,920
+الحرارة أو الضوء بيكسربيكسر جزء الكلور بيعمله
+
+391
+00:31:35,920 --> 00:31:40,520
+homolysis كسر متجانس الرابطة إلكترونين هن بيجي
+
+392
+00:31:40,520 --> 00:31:44,680
+إلكترون و هن بيجي إلكترون بيطلع عنده two CL
+
+393
+00:31:44,680 --> 00:31:48,640
+radical معنى radical a carbon carrying an odd
+
+394
+00:31:48,640 --> 00:31:52,640
+electron او an atom carrying an odd electron ذرة
+
+395
+00:31:52,640 --> 00:31:56,660
+بتحمل إلكترون مفرد هين كانوا إلكترونين هن أجي واحد
+
+396
+00:31:56,660 --> 00:32:05,790
+و هن أجي واحدهذا الـ radical يتفاعل
+
+397
+00:32:05,790 --> 00:32:11,010
+مع الميثين ويأخذ منه هيدروجين لما يأخذ منه
+
+398
+00:32:11,010 --> 00:32:18,370
+هيدروجين لحظه يكلوره H إيش اتكون عنده جزء HClأول
+
+399
+00:32:18,370 --> 00:32:24,370
+شيء يتكوّن عندي جزء الـ HCl وباقي الجزء سارت
+
+400
+00:32:24,370 --> 00:32:27,530
+كاربون حاملة هيدروجين وهيدروجين وهيدروجين وقد
+
+401
+00:32:27,530 --> 00:32:29,970
+إلكترون يتفاعل مثل الـ Radical
+
+402
+00:32:37,530 --> 00:32:43,170
+Methyl Radical وHCl هذا الـ Methyl Radical بيجي
+
+403
+00:32:43,170 --> 00:32:47,910
+على جزء كلور تاني، هاي جزء كلور تاني، بياخد منه
+
+404
+00:32:47,910 --> 00:32:53,790
+ذرة كلور، بيكوّل لكلور وميثين في الخطوة التانية،
+
+405
+00:32:53,790 --> 00:32:56,330
+اتكوّل لكلور وميثين في الخطوة التانية، شو ضال
+
+406
+00:32:56,330 --> 00:33:03,010
+عنده؟ CL Radical، واضح؟ الـ CL Radical بيتفاعل من
+
+407
+00:33:03,010 --> 00:33:07,870
+أول وجديد مع جزء ميثين تاني، أنا هين كوّنت؟لاحظوا
+
+408
+00:33:07,870 --> 00:33:13,210
+الناتج اللي .. هاي خلاصة النواتج الأولى HCl زائد
+
+409
+00:33:13,210 --> 00:33:18,110
+Methylchloride خلصناه وطلع عنده CR Radical بتفعل
+
+410
+00:33:18,110 --> 00:33:21,630
+مع جزء Methane تاني بعيد نفس الكلام بيكون في الأول
+
+411
+00:33:21,630 --> 00:33:25,990
+HCl و Methyl Radical بعدين Methylchloride و بطلع
+
+412
+00:33:25,990 --> 00:33:32,670
+جزء Free Radical او Chlorine Atomتانية و بتتفاعل
+
+413
+00:33:32,670 --> 00:33:38,270
+كذا إذا هدولا الخطوتين متكررات كل مرة ببدأ ب free
+
+414
+00:33:38,270 --> 00:33:44,170
+radical او ب chlorine atom و بتتفاعل بتعمل HCl مثل
+
+415
+00:33:44,170 --> 00:33:48,510
+chloride و بطلع chlorine atom مرة تانية او radical
+
+416
+00:33:49,220 --> 00:33:53,060
+بتتفاعل مرة تانية و هكذا و هكذا هذا التفاعل ممكن
+
+417
+00:33:53,060 --> 00:33:58,240
+يتكرر أربع خمس تلاف مرة قبل ما يوقف بأي طريقة
+
+418
+00:33:58,240 --> 00:34:02,440
+بنسميها termination لاحظوا معي أن هذا التفاعل آلي
+
+419
+00:34:02,440 --> 00:34:06,980
+تمكون من تلت شغلات الشغلة الأولى أنه أنا كان أكون
+
+420
+00:34:06,980 --> 00:34:12,260
+عندي جزء كلورين إذا بتذكره أو أكسره لـ two
+
+421
+00:34:12,260 --> 00:34:15,060
+chlorine atoms هذه الخطوة بسميها أنا إيش؟
+
+422
+00:34:15,570 --> 00:34:20,370
+Initiation خطوة تحضيرية الشيء الثاني خطوتين
+
+423
+00:34:20,370 --> 00:34:26,070
+يتكرروا اللي بيعملوا الـHCl والـMethylchloride
+
+424
+00:34:26,070 --> 00:34:29,110
+وبيطلع Radical وبيعيد وبيعيد وبيعيد هذه خطوة
+
+425
+00:34:29,110 --> 00:34:33,690
+متكررة بنسميها chain propagating step خطوة متوالدة
+
+426
+00:34:33,690 --> 00:34:40,170
+متكاثرةبعد هيك في النهاية ممكن أنه يتم termination
+
+427
+00:34:40,170 --> 00:34:45,390
+للتفاعل من خلال تفاعل X radical مع X radical تاني
+
+428
+00:34:45,390 --> 00:34:48,950
+يعطيني X2 أو R radical مثلا مثل Radical مع مثل
+
+429
+00:34:48,950 --> 00:34:54,770
+Radical تاني يعطيني Ethaneأو R radical مع X
+
+430
+00:34:54,770 --> 00:34:58,790
+radical تانية من عدة دوائر بيكون موجود عنده طبعاً
+
+431
+00:34:58,790 --> 00:35:03,850
+في التفاعل يعطيني R X واضح؟ وبالتالي هذه الخطوات
+
+432
+00:35:03,850 --> 00:35:08,390
+بتوقف سلسلة تكاتر التفاعل بيسميها termination إذا
+
+433
+00:35:08,390 --> 00:35:12,670
+ال mechanism of reaction امكونة من تلت شغلات
+
+434
+00:35:13,410 --> 00:35:17,790
+Initiation خطوة تحضيرية تكوين الـ Free Radicals
+
+435
+00:35:17,790 --> 00:35:22,450
+Propagation الخطوة التكاثر والشغلة التالتة
+
+436
+00:35:22,450 --> 00:35:26,970
+Termination الخطوة انهاء التفاعل
+
+437
+00:35:29,620 --> 00:35:32,700
+الـ mechanism of the reaction لاحظوا مع الـ
+
+438
+00:35:32,700 --> 00:35:36,180
+mechanism هي خطوات تفصيلية احنا بنشوفهاش يعني
+
+439
+00:35:36,180 --> 00:35:40,460
+المعادلة بتكون عامة لكن جوا المعادلة في خطوات
+
+440
+00:35:40,460 --> 00:35:44,440
+تفصيلية عادة لا تكتب في المعادلة هي التي تسمى
+
+441
+00:35:44,440 --> 00:35:50,180
+mechanism فمعنى mechanism الـ detailed stepsCannot
+
+442
+00:35:50,180 --> 00:35:53,360
+be seen in the equation يعني لما انا بدي المعادلة
+
+443
+00:35:53,360 --> 00:35:58,340
+بقول Cl زي ميثين Cl و ميثين زي HCl هي المعادلة لكن
+
+444
+00:35:58,340 --> 00:36:01,680
+كيف اتكسر ال Cl؟ ايش اللي اتكون في الأول؟ ايش اللي
+
+445
+00:36:01,680 --> 00:36:04,740
+اتكون في التاني؟ هذه الخطوات التفصيلية اللي احنا
+
+446
+00:36:04,740 --> 00:36:09,260
+مابنشوفهاش بنسميها mechanism of the reaction
+
+447
+00:36:11,760 --> 00:36:16,120
+أخر شغل بنحكيها أنه لو أنا كنت بدأ أعمل إبدال على
+
+448
+00:36:16,120 --> 00:36:21,600
+مُركّب غير الميثين، يعني إيثين، بروبين، وأبدل one
+
+449
+00:36:21,600 --> 00:36:26,580
+hydrogen by إكلورين أو إبرومين أتم، two hydrogens
+
+450
+00:36:26,580 --> 00:36:31,780
+ممكن، للأصل يكون واضح عندكم تماماً إنه إحنا بنتوقع
+
+451
+00:36:31,780 --> 00:36:36,250
+أكثر من ناتج، يعني لو بننظر هنا إلى الشاشةفي حالة
+
+452
+00:36:36,250 --> 00:36:40,490
+البروبين كاربون تنتين تلاتة لو بدي أقول الـ
+
+453
+00:36:40,490 --> 00:36:43,450
+Monochloroproducts يعني لو بس بدي أبدل الهيدروجين
+
+454
+00:36:43,450 --> 00:36:47,170
+بكلورة ممكن الكلورة تيجي على الذرة الأولى ويصير
+
+455
+00:36:47,170 --> 00:36:52,830
+عند المركب اللي هو وانكلوروبروبينو ممكن الكلور
+
+456
+00:36:52,830 --> 00:36:56,170
+تيجي على الذرع الثانية و يصير عند المُركّب اللي
+
+457
+00:36:56,170 --> 00:37:00,970
+اسمه two-chloropropen طبعا ك common names هذا اسمه
+
+458
+00:37:00,970 --> 00:37:03,850
+anipropyl لأنه دي مجموعة لبروبيل anipropyl
+
+459
+00:37:03,850 --> 00:37:09,190
+chloride و هذا اسمه isopropyl chloride إذا لو بدأ
+
+460
+00:37:09,190 --> 00:37:12,410
+أقول من البروبين الـ monochloroproducts المتوقع
+
+461
+00:37:12,410 --> 00:37:15,510
+كام ناتج اتنين ال one-chloroproduct و ال two
+
+462
+00:37:15,510 --> 00:37:19,410
+-chloroproduct الآن لو قلت بدي أبدل ذرتين هيدروجين
+
+463
+00:37:19,410 --> 00:37:24,100
+بكلور كام ناتج ممكن يطلع عنده؟ممكن ذرتين الكلور
+
+464
+00:37:24,100 --> 00:37:28,760
+يجعل الكربون الأولى، بطلع one-one-dichloropropane،
+
+465
+00:37:28,760 --> 00:37:33,680
+ممكن التنتين يجعل الكربون الثانيةبطلع 2-2
+
+466
+00:37:33,680 --> 00:37:37,260
+-Dichlorobrobin ممكن واحدة تيجي على الـ Carbon
+
+467
+00:37:37,260 --> 00:37:41,580
+الأولى و واحدة على التانية بطلع 1-2-Dichlorobrobin
+
+468
+00:37:41,580 --> 00:37:45,160
+و ممكن واحدة تيجي على الـ Carbon الأولى و التانية
+
+469
+00:37:45,160 --> 00:37:49,760
+على الـ Carbon التالتة بطلع 1-3-Dichlorobrobin إذا
+
+470
+00:37:49,760 --> 00:37:54,880
+عمال من الـ Dichlorobrobin أنا شايف أربع مركبات و
+
+471
+00:37:54,880 --> 00:37:59,020
+من الـ 1-Chlorobrobin شايف مركبين طبعا واضح أن
+
+472
+00:37:59,020 --> 00:38:03,300
+هدولة Isomersو الـ Structural Isomers بيختلفوا في
+
+473
+00:38:03,300 --> 00:38:06,340
+مواقع الروابط هان الكلور ع موقع واحد هان الكلور ع
+
+474
+00:38:06,340 --> 00:38:09,880
+موقع اتنين او هان ذرتين كلور ع موقع واحد هان ذرتين
+
+475
+00:38:09,880 --> 00:38:12,960
+كلور ع موقع اتنين هان ذرة ع واحد ذرة ع اتنين هان
+
+476
+00:38:12,960 --> 00:38:17,300
+ذرة ع واحد ذرة ع تلاتة هاد هي ال isomers او ال
+
+477
+00:38:17,300 --> 00:38:21,300
+structural isomers المفروض انه يصير عندكوا تدريب
+
+478
+00:38:21,300 --> 00:38:25,120
+لو قلنالكوا اعملوا ابدال بذرة واحدة بذرتين على
+
+479
+00:38:25,120 --> 00:38:29,770
+البيوتين مثلا ممكن تاخدوه ك homeworkكم
+
+480
+00:38:29,770 --> 00:38:34,990
+Monochloroproduct وكم Diachloroproduct ممكن أتوقع
+
+481
+00:38:34,990 --> 00:38:38,290
+من مُركّب البيوتين شكراً
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b0eea5a5878f8aea3d6b5980ca6a4acd4263b869
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw.srt
@@ -0,0 +1,1437 @@
+1
+00:00:11,180 --> 00:00:16,920
+بسم الله الرحمن الرحيم المرة 
+
+2
+00:00:16,920 --> 00:00:21,300
+الماضية أخذنا فكرة عن الأحماض وتسميتهم وعن تحديدا 
+
+3
+00:00:21,300 --> 00:00:28,610
+يمكن كمان الحمضية وتأثرها بعاملين أساسيين اللي هم 
+
+4
+00:00:28,610 --> 00:00:33,070
+ال resonance effect و ال inductive effect واضح؟
+
+5
+00:00:33,510 --> 00:00:39,550
+الآن بسبب الحمضية خلّيني أقول العالية نسبيا لل
+
+6
+00:00:39,550 --> 00:00:44,490
+carboxylic acids بنلاحظ أنهم يتفاعلوا مع ال bases
+
+7
+00:00:44,490 --> 00:00:49,870
+ومع weak bases كمان هذا الكلام مختلف عن الكحولات
+
+8
+00:00:49,870 --> 00:00:55,010
+يعني الكحولات لما كنا نقول الكحول very weak acid
+
+9
+00:00:55,010 --> 00:00:58,590
+لما كنا نيجي نفعله مع sodium hydroxide ما يتفعلش 
+
+10
+00:00:58,590 --> 00:01:02,950
+كنا بدنا very strong base زي ال sodium metal بينما 
+
+11
+00:01:02,950 --> 00:01:08,590
+الأحماض لو بنفعلها مع bases حتى لو كانت من مستوى
+
+12
+00:01:08,590 --> 00:01:13,610
+خلينا نقول ال sodium carbonate يعني الكربونة
+
+13
+00:01:13,610 --> 00:01:20,010
+العادية اللي هي تعتبر weak base بتتفاعل واضح؟ فمن
+
+14
+00:01:20,010 --> 00:01:23,390
+باب أولى بالتأكيد الأحماض هيتفاعلوا مع ال sodium
+
+15
+00:01:23,390 --> 00:01:29,790
+hydroxide التفاعل مشهور هو تفاعل حمض وقاعدة ملح
+
+16
+00:01:29,790 --> 00:01:36,070
+وماء فلو كان عندي أي carboxylic acid مع strong
+
+17
+00:01:36,070 --> 00:01:40,250
+base وحتى مع weak base كمان هلاحظ أنه بتتفاعل
+
+18
+00:01:41,100 --> 00:01:45,440
+بيعطينا ال salt في هذه الحالة ال salt هذا بنسميه
+
+19
+00:01:45,440 --> 00:01:51,800
+sodium carboxylate لحظوا النهاية ate هذه ate
+
+20
+00:01:51,800 --> 00:01:58,300
+مرتبطة بالأيونات السالبة يعني الأيونات السالبة
+
+21
+00:01:58,300 --> 00:02:03,700
+نهايتها ate فاذكروا أنتم مثلا في عندكم أيون ال
+
+22
+00:02:03,700 --> 00:02:11,760
+nitrate والسلفات والأجزالات والأسيتات كل الأيونات
+
+23
+00:02:11,760 --> 00:02:16,400
+السالبة بشكل عام نهايتها إيش بيكون؟ ات .. الأيونات
+
+24
+00:02:16,400 --> 00:02:18,620
+الموجبة شو بيكون نهايتها؟ 
+
+25
+00:02:20,790 --> 00:02:26,690
+أونيوم اونيوم زي امونيوم اوكزونيوم هايدرونيوم واضح
+
+26
+00:02:26,690 --> 00:02:31,870
+فهنا لأنه عندي هذا أيون سالب مثلا نفترض من الاسيتك 
+
+27
+00:02:31,870 --> 00:02:37,360
+اسيد بيكون صوديوم اسيتيت من البنزويك اسيد صوديوم 
+
+28
+00:02:37,360 --> 00:02:42,260
+بنزويت وهكذا على سبيل مثال أي مثال محدد هذا جاي
+
+29
+00:02:42,260 --> 00:02:46,140
+من ال acetic acid هذي ال acetate group بصير صوديوم
+
+30
+00:02:46,140 --> 00:02:50,860
+أسيتاتي المثال الثاني من ال benzoic acid مع ال
+
+31
+00:02:50,860 --> 00:02:57,820
+potassium بصير potassium بنزويت هذا من ال provenic
+
+32
+00:02:57,820 --> 00:03:03,560
+acid فبده يكون مع ال calcium طبعا بنسبة 2 ل 1
+
+33
+00:03:03,560 --> 00:03:10,560
+التفاعل calcium بروبانيت وهكذا فالخلاصة أنه نتيجة
+
+34
+00:03:10,560 --> 00:03:16,420
+للحمضية خلينا نقول المرتفعة نسبية للأحماض 
+
+35
+00:03:16,420 --> 00:03:21,980
+الكربوكسيلية بتفاعلوا مع ال bases وبيقدروا لتكوين
+
+36
+00:03:21,980 --> 00:03:29,840
+الأملاح والماء الآن لو اجينا نقول كيف تحضر ال 
+
+37
+00:03:29,840 --> 00:03:35,000
+carboxylic acids بإمكاننا نعمل الكلام بسبعة slides
+
+38
+00:03:35,000 --> 00:03:41,440
+أو ثمانية وبإمكاننا نختصره ب slide واحدة واضح؟
+
+39
+00:03:41,440 --> 00:03:45,380
+هذه ال slide تقريبا بتحط لنا طريقة اثنتين، ثلاث، 
+
+40
+00:03:45,380 --> 00:03:50,400
+أربعة، خمسة، ستة، سبعة، كل هذه الطرق لتحضير 
+
+41
+00:03:50,400 --> 00:03:54,060
+الأحماض الكربوكسيلية فالطرق زي ما بتعرفوا كثيرة
+
+42
+00:03:54,060 --> 00:04:02,300
+هتلاحظوا أن بعض هذه الطرق درسناها إحنا سابقا، بعض
+
+43
+00:04:02,300 --> 00:04:06,700
+هذه الطرق لتحضير ال carboxylic acids درسناها
+
+44
+00:04:06,700 --> 00:04:13,540
+سابقا، والبعض بيمر علينا لأول مرة خلينا نشوف مثلا 
+
+45
+00:04:13,540 --> 00:04:17,640
+الأشياء اللي درسناها سابقا، الأشياء اللي درسناها
+
+46
+00:04:17,640 --> 00:04:23,320
+سابقا مثلًا هذه الطريقة الثانية لما بكون عندي ال
+
+47
+00:04:23,320 --> 00:04:27,020
+alkyne .. لما بكون عندي ال alkyne وبعمله أنا 
+
+48
+00:04:27,020 --> 00:04:34,340
+ozonolysis followed by oxidation واضح؟ إذا كان هنا
+
+49
+00:04:34,340 --> 00:04:39,950
+في عندي الديهيد بتكون في المرحلة الأولى، هذا ال
+
+50
+00:04:39,950 --> 00:04:45,610
+الديهيد بعد هيك بتأكسد بخطوة إضافية لإيش؟ للحمض،
+
+51
+00:04:45,610 --> 00:04:49,710
+لو كانوا هدول الثلاث R-groups بيظلوا عنده كيتون 
+
+52
+00:04:49,710 --> 00:04:55,270
+وأخذنا في تفاعلات الالكينز أمثلة على هذا النوع و
+
+53
+00:04:55,270 --> 00:04:59,070
+بتذكروا لو كان عندنا two hydrogens كنا مرات نقول 
+
+54
+00:04:59,070 --> 00:05:04,780
+ممكن نصل لثاني أكسيد كربون في الآخر يعني مثل هذا
+
+55
+00:05:04,780 --> 00:05:11,880
+التفاعل اللي هو ال ozoneolysis أخدناه الآن نفس 
+
+56
+00:05:11,880 --> 00:05:15,060
+الفكرة زي ما بيصير ال ozoneolysis في ال double
+
+57
+00:05:15,060 --> 00:05:18,980
+bond برضه بيصير في ال triple bond وبهذه الحالة 
+
+58
+00:05:18,980 --> 00:05:25,050
+بيعطينا حمض من التفاعلات اللي أخذناها أنه ال
+
+59
+00:05:25,050 --> 00:05:30,290
+primary alcohols بس بشرط يكون ال oxidizing agent 
+
+60
+00:05:30,290 --> 00:05:36,830
+strong بتأكسده لحد ما يوصلوا ل ال carboxylic acid
+
+61
+00:05:36,830 --> 00:05:40,590
+إذا بتحاولوا تتذكروا هنا مهم أن نتذكر نوع ال
+
+62
+00:05:40,590 --> 00:05:45,670
+oxidizing agent لأن كان في عندنا oxidizing agent
+
+63
+00:05:46,810 --> 00:05:51,590
+بيوصلني بس لل الديهيد اللي هي مثل البريدينيا
+
+64
+00:05:51,590 --> 00:05:55,750
+ميكلورو كروميت وفي oxidizing agent بيحول ال
+
+65
+00:05:55,750 --> 00:06:04,350
+primary alcohol لأسيد مثل الكيامان O4 و ال K2
+
+66
+00:06:04,350 --> 00:06:10,210
+كروميوم 2 O7 والكروميوم O3 كل هذا الكلام أخذناه 
+
+67
+00:06:10,210 --> 00:06:14,110
+اللي هي ال strong oxidizing agents they convert 
+
+68
+00:06:14,110 --> 00:06:16,230
+primary alcohols
+
+69
+00:06:21,150 --> 00:06:28,570
+الـ PCC كان يحول هذا البرايمري الكحول الى الديهيد
+
+70
+00:06:28,570 --> 00:06:33,210
+الواضح فإذا كنت بدي ال acid وعندي ال primary
+
+71
+00:06:33,210 --> 00:06:35,730
+alcohol لازم أستخدم ال 
+
+72
+00:06:39,640 --> 00:06:45,320
+بالتأكيد لو تكون عندي ال الديهيد هنا نفس الشيء 
+
+73
+00:06:45,320 --> 00:06:48,920
+ممكن نتخيل أن هذا ال الديهيد يتكون من هنا باستعمال 
+
+74
+00:06:48,920 --> 00:06:54,720
+ال PCC البريدينيا كلورو كروميت ال الديهيد نفسه 
+
+75
+00:06:54,720 --> 00:07:02,040
+ممكن أن أكسده مرة ثانية لل acid باستعمال أي واحد من
+
+76
+00:07:02,040 --> 00:07:05,820
+هذه الـ strong oxidizing agent فسواء أنا بدأت ب
+
+77
+00:07:05,820 --> 00:07:09,560
+primary alcohol أو بدأت ب aldehyde إذا كان ال 
+
+78
+00:07:09,560 --> 00:07:14,720
+oxidizing agent اللي عندي من فئة ال camon O4 أو ال 
+
+79
+00:07:14,720 --> 00:07:18,620
+keto chromium 2 O7 أو ال chromium O3 الكروميك أسيد
+
+80
+00:07:18,620 --> 00:07:24,840
+بهذه الحالة بتحول إلى carboxylic acid واضح؟ فزي
+
+81
+00:07:24,840 --> 00:07:30,180
+هيك بنلاحظ إحنا أن هذه الطريقة سبق مرت علينا وهذا
+
+82
+00:07:30,180 --> 00:07:33,740
+الطريقة وممكن نسألكوا ياها بسؤال صح وغلط أنه 
+
+83
+00:07:33,740 --> 00:07:38,280
+primary alcohols are oxidized to carboxylic acids
+
+84
+00:07:38,280 --> 00:07:42,800
+using strong oxidizing agents أو aldehydes are 
+
+85
+00:07:42,800 --> 00:07:47,180
+oxidized to carboxylic acids using strong
+
+86
+00:07:47,180 --> 00:07:53,940
+oxidizing agents إذا بيظل ربما كجديد علينا .. بيظل 
+
+87
+00:07:53,940 --> 00:07:57,720
+كجديد علينا في هذه المنطقة هذه الطريقة وهذه
+
+88
+00:07:57,720 --> 00:08:01,900
+الطريقة وهذه الطريقة ربما ما سبقش مرة علينا ك
+
+89
+00:08:01,900 --> 00:08:05,580
+method for the preparation of carboxylic acids
+
+90
+00:08:05,580 --> 00:08:12,300
+ممكن نبدأ نأخذ آخر method هذه بيسموها oxidation of
+
+91
+00:08:12,300 --> 00:08:17,680
+the aliphatic side chain on an aromatic ring يعني
+
+92
+00:08:18,380 --> 00:08:21,540
+هذه الطريقة بتقول القاتل أنه أنا لما بكون عندي
+
+93
+00:08:21,540 --> 00:08:27,620
+aromatic ring نفترض زي البنزين واضح؟ وبتحمل هنا 
+
+94
+00:08:27,620 --> 00:08:31,400
+aliphatic side chain نفترض هذه الـ side chain 
+
+95
+00:08:31,400 --> 00:08:36,560
+كانت CH3 على سبيل المثال واضح؟ إذا صار في عندي 
+
+96
+00:08:36,560 --> 00:08:42,440
+aromatic ring وال aromatic ring حاملة aliphatic 
+
+97
+00:08:42,440 --> 00:08:48,960
+side chain واضح؟ هذه إيش هذه؟ أليفاتك سايد تشين
+
+98
+00:08:48,960 --> 00:08:55,780
+محمولة على أروماتك رينج لما يكون عندي أليفاتك 
+
+99
+00:08:55,780 --> 00:09:00,420
+سايد تشين محمولة على أروماتك رينج بنعمل لها أكسدة 
+
+100
+00:09:00,420 --> 00:09:05,900
+عادة بالكيامان او فور بالبوتاسيوم
+
+101
+00:09:05,900 --> 00:09:12,120
+بيرمانجانيد بيحول هذه المجموعة الأليفاتك إلى 
+
+102
+00:09:12,120 --> 00:09:19,590
+كربوكسليك أسيد بدل ما هي مثل بتصير c double bond o o
+
+103
+00:09:19,590 --> 00:09:25,860
+h الآن هذا الكلام له شرط هل الكلام باسمع المثل؟ لأ
+
+104
+00:09:25,860 --> 00:09:31,760
+أي aliphatic side chain وإن كبرت بس بشرط أنه ال 
+
+105
+00:09:31,760 --> 00:09:36,100
+carbon المتصلة مباشرة هنا في ال aromatic ring تكون
+
+106
+00:09:36,100 --> 00:09:41,040
+حاملة هيدروجين أقل شيء هيدروجين اثنتين بمشي ثلاث 
+
+107
+00:09:41,040 --> 00:09:46,260
+بمشي بس أقل شيء هيدروجين في هذه الحالة بيعطينا
+
+108
+00:09:46,260 --> 00:09:50,910
+carboxylic acid الآن هذه منطقة خلينا نقول منطقة
+
+109
+00:09:50,910 --> 00:09:56,750
+أحيانًا خطأ عند الطلاب ولذلك خلينا نوضحها يعني لو 
+
+110
+00:09:56,750 --> 00:10:06,330
+افترضنا مثلا عنده بنزين وحامل مثل وبنزين ثاني و
+
+111
+00:10:06,330 --> 00:10:06,910
+حامل
+
+112
+00:10:09,350 --> 00:10:14,130
+Ethyl كبرت الـ aliphatic side chain واضح؟ الآن هذا
+
+113
+00:10:14,130 --> 00:10:19,290
+وهذا بيعطوا نفس الناتج ما أحد يجي يحط ال acid هنا
+
+114
+00:10:19,290 --> 00:10:25,890
+لأ في الحالتين أيًا كانت ال aliphatic side chain
+
+115
+00:10:25,890 --> 00:10:29,830
+وإن كبرت حتى لو كانت عشر كربونات في الآخر بتعطي
+
+116
+00:10:29,830 --> 00:10:34,950
+acid واحد واضحة هذه النقطة الكثير من الطلاب اللي
+
+117
+00:10:34,950 --> 00:10:37,310
+ميكملوا المسألة كانوا بيروحوا بيحطوا أسيد على
+
+118
+00:10:37,310 --> 00:10:41,150
+الكربون الطرفية مثلا لو كان عندي خمس كربونات هنا
+
+119
+00:10:41,150 --> 00:10:46,830
+الخمسة كلهم بدهم ينشالوا ويجي مكانهم مجموعة أسيد
+
+120
+00:10:46,830 --> 00:10:53,250
+واحدة وقت إيش ما بيصيرش التفاعل إذا كانت الكربون
+
+121
+00:10:53,250 --> 00:10:59,170
+هذه الأولى ما فيش عليها هيدروجين لكن مثلًا تكون مثل
+
+122
+00:11:00,620 --> 00:11:04,160
+مثلًا مثلبنزين اللي هو الطلوين أو الاثلبنزين أو
+
+123
+00:11:04,160 --> 00:11:08,480
+البروبلبنزين أو البيوتلبنزين أو الايزوبروبلبنزين
+
+124
+00:11:08,480 --> 00:11:15,640
+كل هدول بيعطوني بنزويك أسيد كلهم بيعطوا نفس الناتج
+
+125
+00:11:15,640 --> 00:11:24,000
+إيش اللي ما بيعطيش زي ال tertiary butyl group مثلًا
+
+126
+00:11:24,000 --> 00:11:26,120
+يعني لو أخذنا هذا المركب
+
+127
+00:11:33,110 --> 00:11:36,930
+هذه مجموعة الـ tertiary-butyl الأربعة المجموعة
+
+128
+00:11:36,930 --> 00:11:40,670
+المزدحمة لأن هذا الكربون اللي هنا مش حاملة هيدروجين
+
+129
+00:11:40,670 --> 00:11:44,370
+هذا لو كنت أعمله oxidation بالكمان O4 ما بيعطينيش
+
+130
+00:11:44,370 --> 00:11:51,890
+acid واضح؟ لكن لو كان المركب H
+
+131
+00:11:51,890 --> 00:11:56,830
+اه
+
+132
+00:11:56,830 --> 00:11:58,950
+واضح؟
+
+133
+00:12:00,070 --> 00:12:03,770
+الآن مثل هذا السؤال عشان نذكركوا شوية في العلم لو
+
+134
+00:12:03,770 --> 00:12:09,810
+كنا بدنا نسألكوا فيه بالصح والغلط شو بنقولكوا؟
+
+135
+00:12:09,810 --> 00:12:17,060
+كيومين تذكروا أن هذا اسمه كيومين، كيومين can be
+
+136
+00:12:17,060 --> 00:12:23,080
+oxidized to benzoic acid، صح الترشيوتيل بنزين 
+
+137
+00:12:23,080 --> 00:12:28,200
+can be oxidized to benzoic acid، غلط طبعا مشكلة لو
+
+138
+00:12:28,200 --> 00:12:33,260
+قلنالكم both كيومين and الترشيوتيل بنزين can be 
+
+139
+00:12:33,260 --> 00:12:36,640
+oxidized to carboxylic acid، لأ مش الاثنين، واحد 
+
+140
+00:12:36,640 --> 00:12:41,920
+منهم اللي بيكون فيه at least one hydrogen واضح هذه
+
+141
+00:12:41,920 --> 00:12:46,160
+الفكرة؟ at least بيكون عندي one hydrogen كل ال
+
+142
+00:12:46,160 --> 00:12:49,160
+side chain بتكون تشيلوها مش تشوفوها كبيرة 
+
+143
+00:12:49,160 --> 00:12:53,660
+تتخلونكوا شوية منها لأ بتكون تجيبوا مساحة تمسحوها
+
+144
+00:12:53,660 --> 00:13:02,120
+وتحطوا مكانها COOH Carboxylic Acid إذا هذا ال
+
+145
+00:13:02,120 --> 00:13:06,800
+method السابع اللي هنا اللي بنسميه oxidation of a
+
+146
+00:13:06,800 --> 00:13:12,660
+side chain on aromatic ring اللي هو أكسدة السلسلة 
+
+147
+00:13:12,660 --> 00:13:16,960
+الأليفاتية ال alphatic side chain attached to
+
+148
+00:13:16,960 --> 00:13:19,000
+aromatic rings
+
+149
+00:13:25,440 --> 00:13:30,320
+بيجينا كمان طريقتين لتحضير ال carboxylic acids
+
+150
+00:13:30,320 --> 00:13:36,880
+الطريقة الأولى بتبدأ من ال RX الطريقة الأولى بتبدأ
+
+151
+00:13:36,880 --> 00:13:43,400
+من ال RX يمكن إذا بدنا نذكركوا أكثر ال RX عادة 
+
+152
+00:13:43,400 --> 00:13:49,440
+ممكن إحنا نحضرها من ال ROH ال alcohol واضح؟ يعني 
+
+153
+00:13:49,440 --> 00:13:56,030
+في الأساس يكون عندك ROH بتعطينا RX لو كانت primary
+
+154
+00:13:56,030 --> 00:14:01,510
+مع ال PBr3 بتعطينا RX ليش أنا رجعت هان خطوة
+
+155
+00:14:01,510 --> 00:14:05,710
+لورا عشان أذكركم بالجملة اللي كنا نقولها 
+
+156
+00:14:08,040 --> 00:14:11,980
+الكيميائي لو كان في الصحراء لو كان في الصحراء و
+
+157
+00:14:11,980 --> 00:14:16,040
+معه alcohol بيحضر منه كل شيء لاحظوا ال alcohol هنا 
+
+158
+00:14:16,040 --> 00:14:20,500
+بإمكاني أحضر منه RX RX بعد شوية بيحضر منه Green 
+
+159
+00:14:20,500 --> 00:14:23,740
+يعني if it's green يعني بيحضر منه ال acid ال acid 
+
+160
+00:14:23,740 --> 00:14:27,400
+هتلاحظوا بيحضر منه كل مشتقات ال acid ال ester وال
+
+161
+00:14:27,400 --> 00:14:29,780
+ال amide و ال acid chloride و ال acid anhydride 
+
+162
+00:14:29,780 --> 00:14:33,960
+اللي بدهم يمروا علينا المشتقات واضح؟ بس مبدئيًا إحنا
+
+163
+00:14:33,960 --> 00:14:39,340
+بنقول أنه لو عندنا الكحول ممكن بسهولة يصير RX ال 
+
+164
+00:14:39,340 --> 00:14:43,620
+RX مع المغنيسيوم أخذنا تفاعل شهير اللي هو ال Grignard
+
+165
+00:14:43,620 --> 00:14:51,380
+reaction بيعطينا RMgX ال RMgX اتفقنا أن هو 
+
+166
+00:14:51,380 --> 00:14:55,980
+يمثل nucleophile ولا electrophile? nucleophile 
+
+167
+00:14:55,980 --> 00:15:05,370
+هو عبارة عن R مع مع زوج الإلكترونات تبعها الآن ثاني 
+
+168
+00:15:05,370 --> 00:15:11,030
+أكسيد الكربون ثاني أكسيد الكربون يمثل very strong
+
+169
+00:15:11,030 --> 00:15:15,230
+electrophile ليش ثاني أكسيد الكربون يمثل 
+
+170
+00:15:15,230 --> 00:15:19,890
+electrophile؟ خلينا نفصلوا هنا تنسوش أن تقولوا 
+
+171
+00:15:19,890 --> 00:15:20,990
+ثاني أكسيد الكربون
+
+172
+00:15:23,630 --> 00:15:28,110
+CO2 وين السالبية أعلى على ال carbon ولا على ال 
+
+173
+00:15:28,110 --> 00:15:31,310
+oxygen على ال oxygen إذا هنا عند partially
+
+174
+00:15:31,310 --> 00:15:37,270
+negative هنا partially positive وهنا partially 
+
+175
+00:15:37,270 --> 00:15:44,570
+negative فال carbon هذه تبع ال carbon dioxide is 
+
+176
+00:15:46,130 --> 00:15:50,530
+electrophile واضح ولهذا السبب ال carbon dioxide
+
+177
+00:15:50,530 --> 00:15:54,650
+إحنا بنعمله على أنه acid anhydride يعني في النهاية 
+
+178
+00:15:54,650 --> 00:16:0
+
+201
+00:18:16,290 --> 00:18:21,370
+أيه؟ لما بنعبّر عن تفاعل على خطوتين بنكتب one و
+
+202
+00:18:21,370 --> 00:18:25,990
+two الآن هذا بيختلف .. هذا بيختلف عن طريقة كتابة ال
+
+203
+00:18:25,990 --> 00:18:28,630
+reaction على السهم ولازم تكونوا منتبهين أنتو 
+
+204
+00:18:28,630 --> 00:18:33,970
+بيختلف كثير أن أكون كاتب .. أن أكون كاتب على السهم
+
+205
+00:18:33,970 --> 00:18:38,110
+بهذا الشكل CO2 
+
+206
+00:18:38,110 --> 00:18:44,380
+فاصلة الـ H plus معناه ذلك هدول الاثنين نضافوا مرة
+
+207
+00:18:44,380 --> 00:18:48,920
+واحدة هنا لما أقول نمرة واحد كذا نمرة اثنين كذا
+
+208
+00:18:48,920 --> 00:18:54,200
+هدول نضافوا بشكل متتالي طبعًا لو هدول بدون ما نحطّوا 
+
+209
+00:18:54,200 --> 00:18:59,460
+مع بعض مش هيطلع نفس الناتج عارفين ليش؟ لأنه احنا
+
+210
+00:18:59,460 --> 00:19:03,920
+اتعلمنا شغل أن الـ H plus بتخرب Greenyard reagent
+
+211
+00:19:03,920 --> 00:19:10,760
+الـ H plus بتتفاعل مع Greenyard وبتعطيني RH مش قولنا
+
+212
+00:19:10,760 --> 00:19:16,380
+المية والـ H plus والـ D2O كلهم لو شافوا green
+
+213
+00:19:16,380 --> 00:19:20,220
+yard reagent يعني الـ green yard reagent بدل ما يتعب
+
+214
+00:19:20,220 --> 00:19:24,180
+حاله لو شاف الـ H plus من أولها و يروح على ال
+
+215
+00:19:24,180 --> 00:19:27,800
+carbon الموجودة بتاعت ثاني أكسيد الكربون بيروح على
+
+216
+00:19:27,800 --> 00:19:33,720
+الـ H plus أسله وأقربله واضح؟ فلذلك عليكم أن
+
+217
+00:19:33,720 --> 00:19:39,140
+تنتبهوا كويس أن هذا التفاعل على مرحلتين أنا مش
+
+218
+00:19:39,140 --> 00:19:44,680
+كثير بهمني أن تكتبوا الناتج الوسيط وبعدين 
+
+219
+00:19:44,680 --> 00:19:48,220
+تطلعوا طالما هدول موجودين بشكل سليم نمرة واحد نمرة
+
+220
+00:19:48,220 --> 00:19:53,560
+اثنين إذا الـ RMGX في الآخر بتعطيني RC double point
+
+221
+00:19:53,560 --> 00:20:00,500
+O OH واضح؟ لكن هذا لعملية التوضيح
+
+222
+00:20:03,250 --> 00:20:13,990
+الآن هنا بفيدكم بصراحة أن تنتبهوا إلى مقارنة ما
+
+223
+00:20:13,990 --> 00:20:18,810
+بين الطرق .. تنتبهوا لمقارنة ما بين الطرق ممكن
+
+224
+00:20:18,810 --> 00:20:24,530
+واحدة تقول طالما أن أنا عندي الـ alcohol وبأكسدته
+
+225
+00:20:24,530 --> 00:20:32,660
+مباشرة للحمض واضح؟ انتبهوا معايا كويس دائمًا الاختصار
+
+226
+00:20:32,660 --> 00:20:38,040
+بيفيد ولا ما بيفيدش أنا قلت لكم الـ RX من وين جاياكم؟
+
+227
+00:20:38,040 --> 00:20:42,140
+من الـ alcohol وأنا عندي alcohol طيب إذا عندي هنا
+
+228
+00:20:42,140 --> 00:20:48,400
+alcohol وبأكسد هذا الـ alcohol مباشرة للحمض ليش
+
+229
+00:20:48,400 --> 00:20:54,860
+أعمل؟ ليش أعمل؟ أنه يكون عندي alcohol alcohol R-O
+
+230
+00:20:54,860 --> 00:21:02,350
+-H نفترض وبعدين الـ alcohol يصير RX والـ RX جرينيارد
+
+231
+00:21:02,350 --> 00:21:08,190
+وجرينيارد بده ظروف صعبة بده very dry solvents يعني
+
+232
+00:21:08,190 --> 00:21:10,930
+يمكن في غزة عندنا ما بظبطش لأن احنا عندنا رطوبة
+
+233
+00:21:10,930 --> 00:21:14,930
+البحر كثير يعني الرطوبة اللي في الجو بتخربه و
+
+234
+00:21:14,930 --> 00:21:19,390
+بعدين مع ثاني أكسيد الكربون كخطوة أولى وبعدين مع
+
+235
+00:21:19,390 --> 00:21:25,310
+المية كخطوة ثانية ملاحظين أنتو؟ طب ليش .. ليش كل
+
+236
+00:21:25,310 --> 00:21:26,250
+هاللفة؟
+
+237
+00:21:30,650 --> 00:21:36,870
+على فرض أنه عندي primary alcohol
+
+238
+00:21:36,870 --> 00:21:41,110
+طلع
+
+239
+00:21:41,110 --> 00:21:43,490
+عليهم كويس بفرجوا هدول عن بعض
+
+240
+00:21:48,010 --> 00:21:53,550
+في هذه الحالة في هذه الحالة هتلاحظ أن أي alcohol
+
+241
+00:21:53,550 --> 00:21:59,130
+موجود عنده أنا بزيد على عدد الكربونات اللي موجودين
+
+242
+00:21:59,130 --> 00:22:05,550
+فيه ذرة كربون جديدة بينما في هذه الحالة أنا بأحتفظ 
+
+243
+00:22:05,550 --> 00:22:11,490
+بنفس عدد الكربونات خلينا ناخد الكلام بمثال لو
+
+244
+00:22:11,490 --> 00:22:15,870
+افترضنا أنّه بدنا نبدأ بالايثانول وننتقل على هذه
+
+245
+00:22:15,870 --> 00:22:22,280
+الجهة هي عندكم الايثانول CH3CH2OH
+
+246
+00:22:22,280 --> 00:22:29,120
+وقلنا بدنا نعمله oxidation مباشر بالـ KMnO4
+
+247
+00:22:29,120 --> 00:22:33,300
+شو هيطلع عندنا
+
+248
+00:22:33,300 --> 00:22:40,080
+الـ primary alcohol oxidation CH3CW
+
+249
+00:22:40,080 --> 00:22:48,190
+bond O هيطلع عندي acid الـ alcohol هنا مكون من كم
+
+250
+00:22:48,190 --> 00:22:54,150
+carbon الـ acid اللي هنا تكون مكون من كم carbon
+
+251
+00:22:54,150 --> 00:23:01,830
+مكون من two carbons طيب لو هذا اجينا حولناه بالـ BX3
+
+252
+00:23:01,830 --> 00:23:13,110
+لـ RX يعني نفترض صار CH3 CH2 خلينا نقول CL وبعد ما
+
+253
+00:23:13,110 --> 00:23:28,330
+حولناه لـ CL بدنا نفعله مع جرينيارد صار CH3CH2MgBr
+
+254
+00:23:28,330 --> 00:23:32,910
+ايثيل ميبروميد
+
+255
+00:23:32,910 --> 00:23:38,330
+الجرينيارد بعدين بدنا نفعله مع ايش؟
+
+256
+00:23:38,330 --> 00:23:47,750
+نمرة واحدة مع الـ CO2 ونمرة 2 H3O بلس في هذه
+
+257
+00:23:47,750 --> 00:23:53,730
+الحالة يوجد انديكاربون 2 موجودين والـ CO2 يمثل
+
+258
+00:23:53,730 --> 00:23:57,630
+الكربون الثالثة فهو يزيد انديكاربون يعني لو
+
+259
+00:23:57,630 --> 00:24:06,940
+استخدمنا الألوان سيصبح CH3 و CH2 موجودين هدول موجودين
+
+260
+00:24:06,940 --> 00:24:10,840
+أصلًا، الآن ثاني أكسيد الكربون بده يجيبلي مجموعة 
+
+261
+00:24:10,840 --> 00:24:20,840
+الـ acid من برا، سيضة بالـ bond OH إذا لو أنا ابتدأت
+
+262
+00:24:20,840 --> 00:24:25,340
+بالـ acidic acid وعملت direct oxidation بأحصل على
+
+263
+00:24:25,340 --> 00:24:30,180
+الحامض المكون من كربون تين عفوًا لو بدأت بالإيثانول
+
+264
+00:24:30,180 --> 00:24:35,440
+بالإيثانول وعملت أكسدة مباشرة بأحصل على الـ acetic
+
+265
+00:24:35,440 --> 00:24:39,680
+acid على الخلق بينما لو مشيت بالـ green yard
+
+266
+00:24:39,680 --> 00:24:44,120
+reagent method طريقة الـ green yard reagent قد ايش كان 
+
+267
+00:24:44,120 --> 00:24:49,020
+عندي carbon هنا في الـ alcohol أو في الـ RX أنا بزيد
+
+268
+00:24:49,020 --> 00:24:52,580
+عليه كربونة من وين اجت الكربونة من ثاني اكسيد
+
+269
+00:24:52,580 --> 00:24:58,980
+الكربون إذا هنا بدأت بـ two carbons انتهيت بتلاتة
+
+270
+00:24:58,980 --> 00:25:04,400
+هنا بدأت بـ two carbons انتهيت بتلاتين هاي الفرق بين
+
+271
+00:25:04,400 --> 00:25:09,840
+الطريقتين صح أنا ببدأ بـ alcohol بس هذا الـ alcohol ال
+
+272
+00:25:09,840 --> 00:25:14,180
+direct oxidation بيزيدش عدد الكربون بمقدار ذرة
+
+273
+00:25:14,180 --> 00:25:18,700
+بينما لما بدي أزيد عدد الكربون بمقدار ذرة من وين
+
+274
+00:25:18,700 --> 00:25:23,380
+بدي أجيب هالذرة هذه؟ في النهاية ميثانوكسيد الكربون
+
+275
+00:25:23,380 --> 00:25:26,980
+عبر اللي هي الـ green yard reagent method
+
+276
+00:25:32,200 --> 00:25:40,300
+بهذا المثال سؤالك منطقي أن أنا لو كنت بدي تلاتة
+
+277
+00:25:40,300 --> 00:25:48,120
+مكان بإمكاني استعمل بروبانول وأعمله oxidation هذا
+
+278
+00:25:48,120 --> 00:25:53,220
+الكلام متعلق بـ simple compounds موجودة ايثانول و
+
+279
+00:25:53,220 --> 00:25:57,880
+بروبانول وما إلى ذلك الآن مش دائمًا في الكيمياء لما
+
+280
+00:25:57,880 --> 00:26:01,740
+بتكبر كل شيء موجود عندك وبتحتاجها في أماكن ثانية
+
+281
+00:26:01,740 --> 00:26:05,700
+لكن في هذه المنطقة لو أنا بدي أجي لطالب أو أدخله
+
+282
+00:26:05,700 --> 00:26:10,580
+على المختبر وأقول حضري لي بروبانويك أسيد مثلًا و
+
+283
+00:26:10,580 --> 00:26:14,940
+لجأت عندها لايثانول ولجأت عندها لبروبانول بإمكانها
+
+284
+00:26:14,940 --> 00:26:18,800
+تستعمل الايثانول بطريقة طويلة وبإمكانها تستعمل
+
+285
+00:26:18,800 --> 00:26:22,320
+البروبانول تبدأ بتلاتة وتطلع الحمض تلاتة هذا 
+
+286
+00:26:22,320 --> 00:26:26,980
+لأنه موجود بس هذا بالفيش أن هذه طريقة كيميائية
+
+287
+00:26:26,980 --> 00:26:31,940
+موجودة في مركبات معينة بظروف معينة بتلزمنا واضح
+
+288
+00:26:31,940 --> 00:26:37,220
+يعني مش دائمًا بيكون الـ starting material موجود والـ
+
+289
+00:26:37,220 --> 00:26:42,540
+starting material متوفر مش دائمًا الـ starting material موجود و
+
+290
+00:26:42,540 --> 00:26:53,040
+متوفر عنده عشان أشتغل عليه واضح
+
+291
+00:26:53,040 --> 00:26:55,280
+الفرق بين هدول الطريقتين؟
+
+292
+00:27:04,100 --> 00:27:08,860
+آخر طريقة نحن نأخذها لتحضير الـ Carboxylic Acids
+
+293
+00:27:08,860 --> 00:27:14,860
+خلينا نقول شبيهة بطريقة Greenyard Reagent شبيهة
+
+294
+00:27:14,860 --> 00:27:19,680
+بطريقة Greenyard Reagent برضه في هذه الطريقة ..
+
+295
+00:27:19,680 --> 00:27:25,780
+برضه في هذه الطريقة ممكن أنا أبدأ بالـ ROH
+
+296
+00:27:26,800 --> 00:27:30,720
+في طريقة Greenyard بدأت بالـ R O H وحولتها لـ R X
+
+297
+00:27:30,720 --> 00:27:37,420
+وهنا ممكن أحولها لـ R X وهنا كاتب R الـ G طبعًا أول
+
+298
+00:27:37,420 --> 00:27:43,300
+ما أنتو بتشوفوا الـ G كستات ايش بيغطر ع بالكم ال
+
+299
+00:27:43,300 --> 00:27:47,020
+washing machine الغسالة الـ L G لكن هنا الـ L G مش
+
+300
+00:27:47,020 --> 00:27:50,000
+غسالة ايش الـ L G؟
+
+301
+00:27:53,730 --> 00:27:59,460
+لو ولا ثلاجة طبعًا لا غسالة ولا ثلاجة الـ LG is a
+
+302
+00:27:59,460 --> 00:28:03,000
+leaving group مجموعة مغادرة يعني مجموعة بتطلع
+
+303
+00:28:03,000 --> 00:28:08,240
+بسهولة وأنسب leaving group الـ X يعني لو نخليها الـ X
+
+304
+00:28:08,240 --> 00:28:13,680
+ر X برضه بتمشي لأن الـ CL أخذنا أنها بتطلع بسهولة
+
+305
+00:28:13,680 --> 00:28:17,480
+والدليل على هيك أخذنا تشابتر كامل اسمه الـ alkyl
+
+306
+00:28:17,480 --> 00:28:20,980
+halides وقلنا الـ alkyl halides بيصير عليهم ال
+
+307
+00:28:20,980 --> 00:28:26,500
+substitution بشكل سهل هنا كأنه أنا مشترك في الخطوة
+
+308
+00:28:26,500 --> 00:28:31,400
+الأولى لو أخذت roh مع الـ bcl3 مثلًا أو الـ bx3 بشكل
+
+309
+00:28:31,400 --> 00:28:36,140
+عام هيعطيني rx ممكن أكمله بطريقتي gradient الآن ال
+
+310
+00:28:36,140 --> 00:28:43,440
+rx نفسه ممكن أجي أفعله مع الـ cyanide CN minus زي
+
+311
+00:28:43,440 --> 00:28:47,940
+sodium cyanide مثلًا أو potassium cyanide الـ CN بدها
+
+312
+00:28:47,940 --> 00:28:53,960
+تيجي تهاجم هذا substitution أسأل 1 وأسأل 2 
+
+313
+00:28:53,960 --> 00:28:57,940
+substitution هذا يجب أن يتهاجم وتطرد الـ X بناء على
+
+314
+00:28:57,940 --> 00:29:05,020
+ذلك سيصبح لدي Rcn لاحظوا هنا أن الـ R موجودة ماذا
+
+315
+00:29:05,020 --> 00:29:09,140
+زاد عليها في هذه الحالة كربونة من أين أتيت
+
+316
+00:29:09,140 --> 00:29:14,680
+الكربونة هذه من الـ Cn الـ Rcn لو أخذته وعملت له
+
+317
+00:29:14,680 --> 00:29:22,200
+هيدروليسيس بمصادر حمضية يعني حطيته بحامض أو كمان
+
+318
+00:29:22,200 --> 00:29:26,420
+ممكن الـ basic media بس نمرة واحد بنحط OH minus
+
+319
+00:29:26,420 --> 00:29:32,260
+ونمرة اثنين H plus هيعطيل الحامض فبنقول احنا أن ال
+
+320
+00:29:32,260 --> 00:29:36,640
+cyanide can be hydrolyzed يعني بتتميئق بالمياه
+
+321
+00:29:36,640 --> 00:29:42,120
+بتتحول إلى حامض إما بإضافة كربوكسيلك أسيد إما
+
+322
+00:29:42,120 --> 00:29:45,380
+بإضافة أسيد زي الـ sulphuric acid مثلًا أو ما إلى
+
+323
+00:29:45,380 --> 00:29:50,880
+ذلك أو بإضافة قاعدة base زي الـ sodium hydroxide
+
+324
+00:29:50,880 --> 00:29:56,400
+وبعدين فعلها مع H plus سواء مشينا زي هيك أو هيك
+
+325
+00:29:56,400 --> 00:30:02,760
+فالـ RCN بتتحول إلى أسيد الآن هذا الـ acid ايش ميزته؟
+
+326
+00:30:04,340 --> 00:30:13,460
+الـ R اللي هو زايد كربونة واحدة عن الـ RX واضح زايد كربونة
+
+327
+00:30:13,460 --> 00:30:17,500
+واحدة عن الـ RX طبعًا لو أنا كنت معطيكم الـ RCN
+
+328
+00:30:17,500 --> 00:30:20,960
+الكربونة خلاص فيها يعني مثلًا لو جيبنالكم في
+
+329
+00:30:20,960 --> 00:30:24,300
+الامتحان المعادلة الكيميائية قولنا لكم complete the
+
+330
+00:30:24,300 --> 00:30:26,920
+following equation وهذه أحيانًا تجربة بيعملوها في
+
+331
+00:30:26,920 --> 00:30:33,100
+المختبر أنتو لسه ما أخذتو المختبر ولا لأ؟ الكثير 
+
+332
+00:30:33,100 --> 00:30:40,340
+بياخذوا بنزو
+
+333
+00:30:40,340 --> 00:30:45,120
+نيتريل أو سيانو بنزين وبعدين بيفعلوا نمرة واحد مع
+
+334
+00:30:45,120 --> 00:30:48,480
+صوديوم هيدروكسيد بتأخذوا في المختبر بتأخذوا كمية
+
+335
+00:30:48,480 --> 00:30:52,560
+منه بتغلو مع صوديوم هيدروكسيد نص ساعة ساعة وبعدين
+
+336
+00:30:52,560 --> 00:30:56,600
+بتضيفوا عليه نقطة حمض شو المحصلة اللي لازم
+
+337
+00:30:56,600 --> 00:30:57,560
+تكتبوها؟
+
+338
+00:31:01,670 --> 00:31:09,950
+النيتريلز بتتحلل إلى أسدين النيتريلز CNN بتتحول
+
+339
+00:31:09,950 --> 00:31:17,650
+إلى أحماض سواء كان هذا التحلل في acidic medium أو كان
+
+340
+00:31:17,650 --> 00:31:22,390
+في basic media يعني الشغلتين موجودين .. الشغلتين
+
+341
+00:31:22,390 --> 00:31:27,110
+موجودين وممكن يتم التفاعل فيهم أهم شيء بديكم
+
+342
+00:31:27,110 --> 00:31:32,070
+تنتبهوا له أن هدول الطريقتين مقارنة بطريقة ال
+
+343
+00:31:32,070 --> 00:31:36,870
+alcohol والـ aldehyde فيهم زيادة carbon لو كنا
+
+344
+00:31:36,870 --> 00:31:44,030
+بنبدأ من الـ RX واضح؟ الـ carbon في الحالة الأولى
+
+345
+00:31:44,030 --> 00:31:47,960
+ايش مصدرها؟ ثاني أكسيد الكربون وفي الحالة
+
+346
+00:31:47,960 --> 00:31:51,800
+الثانية من وين اجت الكربون على الـ R؟ من الـ CN ..
+
+347
+00:31:51,800 --> 00:32:02,300
+الـ C فيها C الحمد لله أنها CN مش CNN ولا cancel من
+
+348
+00:32:02,300 --> 00:32:07,120
+أمام محطة أخضرية كل هذه
+
+349
+00:32:07,120 --> 00:32:13,060
+طرق لتحضير الكربوكسيليك أسيد كم
+
+350
+00:32:13,060 --> 00:32:18,060
+طريقة؟ سبعة ..الآن أنا مرة جبت للطلاب في الامتحان
+
+351
+00:32:18,060 --> 00:32:24,600
+حامض وقلت له حضره بثلاث طرق معقول السؤال؟ احنا 
+
+352
+00:32:24,600 --> 00:32:29,460
+معطيكم سبع طرق تامدوا
+
+353
+00:32:29,460 --> 00:32:35,880
+انتو لازم كله full mark لاحظوا هذه الـ slide كيف
+
+354
+00:32:35,880 --> 00:32:38,900
+الـ green yard reagent .. هذه شرحناها كيف الـ 
+
+355
+00:32:38,900 --> 00:32:41,900
+green yard reagent بتتفاعل مع ثاني أكسيد الكربون
+
+356
+00:32:41,900 --> 00:32:46,500
+بيعطينا الايون السالب والموجب وفي حالة إضافة الـ H
+
+357
+00:32:46,500 --> 00:32:51,300
+بلس بيعطينا الـ acid بتاعت دي فصلناها على الجانب
+
+358
+00:32:51,300 --> 00:32:58,480
+اللي احنا بنحكيه الآن بنجي لموضوع جديد اللي هو ال
+
+359
+00:32:58,480 --> 00:33:03,860
+reactions of carboxylic acids reactions of
+
+360
+00:33:03,860 --> 00:33:09,800
+carboxylic acids طبعًا الـ carboxylic acid لما
+
+361
+00:33:09,800 --> 00:33:14,860
+بتتفاعل بيعطي الـ derivatives of carboxylic acids
+
+362
+00:33:14,860 --> 00:33:19,520
+اللي هي المشتقات لاحظوا هنا هتحسوا أن الـ organic
+
+363
+00:33:19,520 --> 00:33:23,860
+صارت سهلة ليش؟ لأنه احنا في هذا الـ chapter بدنا
+
+364
+00:33:23,860 --> 00:33:31,180
+ندرس الأحماض وبعد هيك مشتقاتها الآن هيجيكم كيف 
+
+365
+00:33:31,180 --> 00:33:37,680
+بنحضر المشتقات تفاعل الحامض هو طريقة تحضير ال
+
+366
+00:33:37,680 --> 00:33:42,060
+derivative يعني لما نقول مثلًا الحامض مع ال
+
+367
+00:33:42,060 --> 00:33:47,900
+thionyl chloride الـ SOCl2 بيعطيني R C O Cl
+
+368
+00:33:47,900 --> 00:33:48,520
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+369
+00:33:48,520 --> 00:33:50,220
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+370
+00:33:50,220 --> 00:33:54,200
+O O
+
+371
+00:33:54,200 --> 00:33:54,380
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+372
+00:3
+
+401
+00:36:40,520 --> 00:36:45,660
+ليش أنا بقول أنا مشتقات للحامض لأن أنا بحضرها من
+
+402
+00:36:45,660 --> 00:36:49,880
+الحامض؟ التفاعل الأخير أن الحامض لو فعلناه مع base
+
+403
+00:36:49,880 --> 00:36:55,330
+بيعطينا الـ salt. هذا أخذناه في أول المحاضرة هذه حمض 
+
+404
+00:36:55,330 --> 00:37:01,590
+وقاعدة بيعطينا هنا نفترض r-c-o-o-  and a plus salt
+
+405
+00:37:01,590 --> 00:37:05,890
+زائد ماء. هذا اللي هو التفاعل اللي ابتدينا فيه 
+
+406
+00:37:05,890 --> 00:37:10,270
+المحاضرة مرة علينا فكأنه التفاعلات الأساسية
+
+407
+00:37:10,270 --> 00:37:17,280
+الأربعة للحامض هي التفاعلات الأربعة اللي بنحضر من 
+
+408
+00:37:17,280 --> 00:37:23,260
+خلالها مشتقات الحامض. يضاف إنهم تفاعل خامس اللي هو
+
+409
+00:37:23,260 --> 00:37:30,600
+أن الحمض زائد قاعدة ملح زائد ماء وبهيك بننهي اليوم
+
+410
+00:37:30,600 --> 00:37:34,460
+المحاضرة وإن شاء الله بنتابع فيه مرات قادمة 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..94f7649767ee9306774cc673701c7fd084fc626b
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2214, "start": 11.18, "end": 22.14, "text": "بسم الله الرحمن الرحيم المرة الماضية أخدنا فكرة عن الأحماض وتسميتهم و عن تحديدا يمكن كمان", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 9673, 25720, 9673, 46958, 10632, 5551, 9778, 3215, 8315, 6156, 4117, 25720, 18871, 16247, 35571, 46958, 34683, 38251, 36081, 16095, 4032, 18871, 6055, 5016, 16254, 28259, 7251, 43020, 9122, 2304, 7649], "avg_logprob": -0.08555640534656804, "compression_ratio": 1.5673076923076923, "no_speech_prob": 0.0, "words": [{"start": 11.18, "end": 12.08, "word": "بسم", "probability": 0.82861328125}, {"start": 12.08, "end": 12.26, "word": " الله", "probability": 0.9765625}, {"start": 12.26, "end": 12.62, "word": " الرحمن", "probability": 0.9786783854166666}, {"start": 12.62, "end": 13.04, "word": " الرحيم", "probability": 0.9933268229166666}, {"start": 13.04, "end": 16.92, "word": " المرة", "probability": 0.936279296875}, {"start": 16.92, "end": 17.42, "word": " الماضية", "probability": 0.9900716145833334}, {"start": 17.42, "end": 17.94, "word": " أخدنا", "probability": 0.93359375}, {"start": 17.94, "end": 18.3, "word": " فكرة", "probability": 0.9951171875}, {"start": 18.3, "end": 18.5, "word": " عن", "probability": 0.98828125}, {"start": 18.5, "end": 19.18, "word": " الأحماض", "probability": 0.9298502604166666}, {"start": 19.18, "end": 20.08, "word": " وتسميتهم", "probability": 0.891357421875}, {"start": 20.08, "end": 20.26, "word": " و", "probability": 0.58837890625}, {"start": 20.26, "end": 20.46, "word": " عن", "probability": 0.8115234375}, {"start": 20.46, "end": 21.3, "word": " تحديدا", "probability": 0.8448486328125}, {"start": 21.3, "end": 21.66, "word": " يمكن", "probability": 0.95068359375}, {"start": 21.66, "end": 22.14, "word": " كمان", "probability": 0.98095703125}], "temperature": 1.0}, {"id": 2, "seek": 3307, "start": 22.75, "end": 33.07, "text": "الحمضية و تأثرها بعاملين أساسيين اللي هم ال resonance effect و ال inductive effect واضح؟", "tokens": [6027, 35571, 11242, 10632, 4032, 6055, 10721, 49115, 11296, 45030, 10943, 1211, 9957, 5551, 3794, 32277, 1829, 9957, 13672, 1829, 8032, 2304, 2423, 30944, 1802, 4032, 2423, 31612, 488, 1802, 4032, 46958, 5016, 22807], "avg_logprob": -0.22098214370863778, "compression_ratio": 1.2110091743119267, "no_speech_prob": 2.4437904357910156e-06, "words": [{"start": 22.75, "end": 23.93, "word": "الحمضية", "probability": 0.85205078125}, {"start": 23.93, "end": 24.73, "word": " و", "probability": 0.2978515625}, {"start": 24.73, "end": 25.47, "word": " تأثرها", "probability": 0.9185791015625}, {"start": 25.47, "end": 26.65, "word": " بعاملين", "probability": 0.80999755859375}, {"start": 26.65, "end": 27.49, "word": " أساسيين", "probability": 0.89921875}, {"start": 27.49, "end": 27.63, "word": " اللي", "probability": 0.885986328125}, {"start": 27.63, "end": 28.61, "word": " هم", "probability": 0.7353515625}, {"start": 28.61, "end": 28.91, "word": " ال", "probability": 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عندى أي carboxylic acid مع strong base وحتى مع weak base كمان هلاحظ انه بتتفاعل", "tokens": [40228, 22653, 33251, 25513, 11536, 3660, 18863, 18513, 10632, 13672, 1829, 39896, 6055, 34268, 26890, 5336, 3096, 39894, 2655, 5172, 995, 30241, 4032, 46958, 5016, 22807, 6156, 27842, 4724, 16758, 5551, 12610, 7578, 20666, 2655, 10721, 4117, 25708, 16247, 35571, 46958, 39896, 2655, 5172, 995, 30241, 14407, 20449, 2423, 20265, 15435, 34454, 16712, 5172, 995, 30241, 37893, 3224, 13063, 31439, 6055, 5172, 995, 30241, 11331, 2304, 11242, 4032, 4587, 995, 22488, 3660, 3714, 1211, 5016, 4032, 2304, 16606, 6156, 1211, 2407, 25961, 43242, 7578, 36632, 1032, 4995, 88, 1050, 8258, 20449, 2068, 3096, 4032, 33753, 7578, 20449, 5336, 3096, 9122, 2304, 7649, 8032, 15040, 5016, 19913, 16472, 3224, 39894, 2655, 5172, 995, 30241], "avg_logprob": -0.14432566364606222, "compression_ratio": 1.6411290322580645, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 72.09, "end": 72.47, "word": "يعني", 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{"start": 97.01, "end": 97.19, "word": " مع", "probability": 0.9853515625}, {"start": 97.19, "end": 97.53, "word": " weak", "probability": 0.9912109375}, {"start": 97.53, "end": 97.87, "word": " base", "probability": 0.87890625}, {"start": 97.87, "end": 98.33, "word": " كمان", "probability": 0.9710286458333334}, {"start": 98.33, "end": 99.27, "word": " هلاحظ", "probability": 0.88623046875}, {"start": 99.27, "end": 99.47, "word": " انه", "probability": 0.772216796875}, {"start": 99.47, "end": 100.25, "word": " بتتفاعل", "probability": 0.8607421875}], "temperature": 1.0}, {"id": 6, "seek": 12472, "start": 101.1, "end": 124.72, "text": "بيعطينا ال salt في هذه الحالة ال salt هذا بنسميه sodium carboxylate لحظوا النهاية ate هذه ate مرتبطة بالأيونات السالبة يعني الأيونات السالبة نهايتها ate فاذكروا أنتم مثلا في عندكم ايون ال nitrate", "tokens": [21292, 3615, 9566, 1829, 8315, 2423, 5139, 8978, 29538, 21542, 6027, 3660, 2423, 5139, 23758, 44945, 38251, 1829, 3224, 20265, 1032, 4995, 5088, 473, 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"word": " البريدينيا", "probability": 0.752197265625}, {"start": 411.92, "end": 412.46, "word": " الكلورو", "probability": 0.74444580078125}, {"start": 412.46, "end": 412.84, "word": " كروميت", "probability": 0.737060546875}, {"start": 412.84, "end": 413.28, "word": " ال", "probability": 0.81982421875}, {"start": 413.28, "end": 413.9, "word": " الديهيد", "probability": 0.965087890625}, {"start": 413.9, "end": 414.72, "word": " نفسه", "probability": 0.9899088541666666}, {"start": 414.72, "end": 415.18, "word": " ممكن", "probability": 0.9873046875}, {"start": 415.18, "end": 415.34, "word": " ان", "probability": 0.58740234375}, {"start": 415.34, "end": 416.02, "word": " اكسته", "probability": 0.8076171875}, {"start": 416.02, "end": 417.4, "word": " مرة", "probability": 0.937744140625}, {"start": 417.4, "end": 417.78, "word": " تانية", "probability": 0.9879557291666666}, {"start": 417.78, "end": 418.06, "word": " لل", "probability": 0.8447265625}, {"start": 418.06, "end": 418.54, "word": " 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424.22, "word": " agent", "probability": 0.89111328125}, {"start": 424.22, "end": 425.08, "word": " فسواء", "probability": 0.8843994140625}, {"start": 425.08, "end": 425.3, "word": " أنا", "probability": 0.81689453125}, {"start": 425.3, "end": 425.7, "word": " بدأت", "probability": 0.8489583333333334}, {"start": 425.7, "end": 425.82, "word": " ب", "probability": 0.8955078125}, {"start": 425.82, "end": 426.34, "word": " primary", "probability": 0.5703125}, {"start": 426.34, "end": 427.02, "word": " alcohol", "probability": 0.81201171875}, {"start": 427.02, "end": 427.64, "word": " أو", "probability": 0.70947265625}, {"start": 427.64, "end": 428.12, "word": " بدأت", "probability": 0.9462890625}, {"start": 428.12, "end": 428.26, "word": " ب", "probability": 0.431396484375}, {"start": 428.26, "end": 428.92, "word": " aldehyde", "probability": 0.75201416015625}, {"start": 428.92, "end": 429.18, "word": " إذا", "probability": 0.83203125}, {"start": 429.18, "end": 429.44, "word": " كان", "probability": 0.9951171875}, {"start": 429.44, "end": 429.56, "word": " ال", "probability": 0.97900390625}, {"start": 429.56, "end": 430.26, "word": " oxidizing", "probability": 0.9482421875}, {"start": 430.26, "end": 430.84, "word": " agent", "probability": 0.89697265625}, {"start": 430.84, "end": 431.32, "word": " اللي", "probability": 0.943359375}, {"start": 431.32, "end": 431.84, "word": " عندي", "probability": 0.684814453125}, {"start": 431.84, "end": 432.42, "word": " من", "probability": 0.986328125}, {"start": 432.42, "end": 432.92, "word": " فئة", "probability": 0.9835611979166666}, {"start": 432.92, "end": 433.26, "word": " ال", "probability": 0.73828125}, {"start": 433.26, "end": 433.66, "word": " camon", "probability": 0.369873046875}, {"start": 433.66, "end": 434.34, "word": " O4", "probability": 0.700439453125}, {"start": 434.34, "end": 434.54, "word": " أو", "probability": 0.794921875}, {"start": 434.54, "end": 434.72, "word": " ال", "probability": 0.5244140625}, {"start": 434.72, "end": 435.0, "word": " keto", "probability": 0.4697265625}, {"start": 435.0, "end": 435.66, "word": " chromium", "probability": 0.806884765625}, {"start": 435.66, "end": 435.92, "word": " 2", "probability": 0.56201171875}, {"start": 435.92, "end": 436.58, "word": " O7", "probability": 0.82373046875}, {"start": 436.58, "end": 436.78, "word": " أو", "probability": 0.85498046875}, {"start": 436.78, "end": 436.92, "word": " ال", "probability": 0.73388671875}, {"start": 436.92, "end": 437.36, "word": " chromium", "probability": 0.946533203125}, {"start": 437.36, "end": 437.74, "word": " O3", "probability": 0.952392578125}, {"start": 437.74, "end": 438.26, "word": " الكروميك", "probability": 0.701171875}, {"start": 438.26, "end": 438.62, "word": " أسد", "probability": 0.7897135416666666}, {"start": 438.62, "end": 439.44, "word": " بهاد", "probability": 0.5801595052083334}, {"start": 439.44, "end": 439.86, "word": " الحالة", "probability": 0.9788411458333334}, {"start": 439.86, "end": 440.42, "word": " بتحول", "probability": 0.8095703125}, {"start": 440.42, "end": 440.88, "word": " إلى", "probability": 0.79931640625}, {"start": 440.88, "end": 442.44, "word": " carboxylic", "probability": 0.7659912109375}, {"start": 442.44, "end": 443.02, "word": " acid", "probability": 0.9462890625}, {"start": 443.02, "end": 444.22, "word": " واضح؟", "probability": 0.808837890625}, {"start": 444.22, "end": 444.84, "word": " فزي", "probability": 0.9290364583333334}, {"start": 444.84, "end": 445.04, "word": " هيك", "probability": 0.734375}, {"start": 445.04, "end": 445.58, "word": " بنلاحظ", "probability": 0.93115234375}, {"start": 445.58, "end": 446.8, "word": " احنا", "probability": 0.8274739583333334}, {"start": 446.8, "end": 447.32, "word": " ان", "probability": 0.60595703125}, {"start": 447.32, "end": 447.64, "word": " هذا", "probability": 0.327392578125}, {"start": 447.64, "end": 448.28, "word": " الطريقة", "probability": 0.9700520833333334}, {"start": 448.28, "end": 448.92, "word": " سبق", "probability": 0.9822591145833334}, {"start": 448.92, "end": 449.34, "word": " مرت", "probability": 0.70263671875}, {"start": 449.34, "end": 449.8, "word": " علينا", "probability": 0.94873046875}, {"start": 449.8, "end": 449.96, "word": " و", "probability": 0.7529296875}, {"start": 449.96, "end": 450.18, "word": " هذا", "probability": 0.66357421875}, {"start": 450.18, "end": 450.82, "word": " الطريقة", "probability": 0.9876302083333334}], "temperature": 1.0}, {"id": 22, "seek": 46866, "start": 451.3, "end": 468.66, "text": "و ممكن نسألكوا ياها بسؤال صح و غلط أنه primary alcohols are oxidized to carboxylic acids using strong oxidizing agents أو الديهيد are oxidized to carboxylic acids using strong oxidizing agents", "tokens": [2407, 3714, 43020, 8717, 3794, 10721, 23275, 14407, 35186, 11296, 4724, 3794, 33604, 6027, 20328, 5016, 4032, 32771, 1211, 9566, 14739, 3224, 6194, 7658, 82, 366, 19924, 1602, 281, 1032, 4995, 88, 1050, 21667, 1228, 2068, 19924, 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preparation of carboxylic acids ممكن نبدأ ناخد آخر method هذه بيسموها oxidation of the aliphatic sided chain on an aromatic ring يعني", "tokens": [28814, 15730, 4724, 1829, 19913, 1211, 12602, 3555, 15042, 9122, 7435, 16254, 3215, 25894, 8315, 4386, 4724, 1829, 19913, 1211, 9122, 7435, 16254, 3215, 25894, 8315, 8978, 29538, 9673, 1863, 9566, 28671, 29538, 41950, 16572, 28671, 4032, 29538, 41950, 16572, 28671, 4032, 29538, 41950, 16572, 28671, 12602, 3555, 15042, 19446, 35457, 4587, 8592, 3714, 25720, 25894, 8315, 9122, 3170, 337, 264, 13081, 295, 1032, 4995, 88, 1050, 21667, 3714, 43020, 8717, 44510, 10721, 8717, 47283, 3215, 19753, 34740, 3170, 29538, 4724, 1829, 38251, 2407, 11296, 36767, 295, 264, 419, 24595, 2399, 41651, 5021, 322, 364, 45831, 4875, 37495, 22653], "avg_logprob": -0.1895312511920929, "compression_ratio": 1.7543859649122806, "no_speech_prob": 0.0, "words": [{"start": 470.02, "end": 470.44, "word": "إذا", "probability": 0.443359375}, {"start": 470.44, "end": 471.16, 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"seek": 56004, "start": 555.47, "end": 560.05, "text": "بدل ما هي مثل بتصير c double bond o o h", "tokens": [3555, 3215, 1211, 19446, 39896, 50113, 1211, 39894, 9381, 13546, 269, 3834, 6086, 277, 277, 276], "avg_logprob": -0.5960477941176471, "compression_ratio": 0.9152542372881356, "no_speech_prob": 0.0, "words": [{"start": 555.47, "end": 555.91, "word": "بدل", "probability": 0.6424153645833334}, {"start": 555.91, "end": 555.99, "word": " ما", "probability": 0.8447265625}, {"start": 555.99, "end": 556.21, "word": " هي", "probability": 0.7939453125}, {"start": 556.21, "end": 556.77, "word": " مثل", "probability": 0.986572265625}, {"start": 556.77, "end": 557.41, "word": " بتصير", "probability": 0.5302734375}, {"start": 557.41, "end": 558.33, "word": " c", "probability": 0.08905029296875}, {"start": 558.33, "end": 558.55, "word": " double", "probability": 0.1439208984375}, {"start": 558.55, "end": 558.97, "word": " bond", "probability": 0.50244140625}, {"start": 558.97, "end": 559.31, 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749.58, "end": 750.28, "word": " كيومين", "probability": 0.9146728515625}, {"start": 750.28, "end": 750.78, "word": " and", "probability": 0.94677734375}, {"start": 750.78, "end": 751.54, "word": " ترث", "probability": 0.84619140625}, {"start": 751.54, "end": 752.12, "word": " شربيوت", "probability": 0.98486328125}, {"start": 752.12, "end": 752.82, "word": " البنزين", "probability": 0.9852294921875}, {"start": 752.82, "end": 753.08, "word": " can", "probability": 0.91162109375}, {"start": 753.08, "end": 753.26, "word": " be", "probability": 0.96630859375}, {"start": 753.26, "end": 753.98, "word": " oxidized", "probability": 0.9658203125}, {"start": 753.98, "end": 754.26, "word": " to", "probability": 0.9765625}, {"start": 754.26, "end": 755.04, "word": " carboxylic", "probability": 0.8997802734375}, {"start": 755.04, "end": 755.42, "word": " acid،", "probability": 0.818603515625}, {"start": 755.42, "end": 755.58, "word": " لأ", "probability": 0.919189453125}, {"start": 755.58, "end": 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hydrogen كل ال side chain بتكون تشيلوها مش تشوفوها كبيرة تتخلونكوا شوية منها لأ بتكون تجيبوا مساحة تمسحوها و تحطوا مكانها COOH Carboxylic Acid اذا هذا ال method السابع اللى هنا اللى بنسميه oxidation of a sided chain", "tokens": [2407, 46958, 5016, 29538, 27188, 4117, 25720, 22807, 412, 1935, 4724, 1829, 30544, 43242, 7578, 472, 12697, 28242, 2423, 1252, 5021, 39894, 30544, 6055, 8592, 26895, 2407, 11296, 37893, 6055, 8592, 38688, 2407, 11296, 9122, 3555, 48923, 6055, 2655, 9778, 1211, 11536, 4117, 14407, 13412, 2407, 10632, 9154, 11296, 5296, 10721, 39894, 30544, 6055, 7435, 1829, 3555, 14407, 47524, 39319, 3660, 46811, 3794, 5016, 2407, 11296, 4032, 6055, 5016, 9566, 14407, 3714, 41361, 11296, 3002, 31187, 2741, 4995, 88, 1050, 5097, 327, 1975, 15730, 23758, 2423, 3170, 21136, 16758, 3615, 13672, 7578, 34105, 13672, 7578, 44945, 38251, 1829, 3224, 36767, 295, 257, 41651, 5021], "avg_logprob": -0.2799107120150611, "compression_ratio": 1.5573122529644268, "no_speech_prob": 0.0, "words": 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"probability": 0.9775390625}, {"start": 783.24, "end": 783.44, "word": " اللى", "probability": 0.7783203125}, {"start": 783.44, "end": 783.74, "word": " هنا", "probability": 0.85009765625}, {"start": 783.74, "end": 784.28, "word": " اللى", "probability": 0.916748046875}, {"start": 784.28, "end": 784.9, "word": " بنسميه", "probability": 0.9444580078125}, {"start": 784.9, "end": 785.52, "word": " oxidation", "probability": 0.81005859375}, {"start": 785.52, "end": 786.46, "word": " of", "probability": 0.97802734375}, {"start": 786.46, "end": 786.8, "word": " a", "probability": 0.9111328125}, {"start": 786.8, "end": 787.46, "word": " sided", "probability": 0.7314453125}, {"start": 787.46, "end": 788.02, "word": " chain", "probability": 0.9140625}], "temperature": 1.0}, {"id": 36, "seek": 79900, "start": 789.24, "end": 799.0, "text": "on aromatic ring اللي هو اكسدت السلسلة الالفاتية ال alphatic sided chain attached to aromatic rings", "tokens": [266, 45831, 4875, 13672, 1829, 31439, 1975, 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832.61, "end": 845.71, "text": "ROH بتعطينا Rx لو كانت برايبر مع ال بي إكس ثري بتعطينا Rx ليش أنا رجعت كهانة خطوة لورا عشان أذكركم بالجملة اللي كنا نقولها", "tokens": [49, 31187, 4724, 2655, 3615, 9566, 1829, 8315, 497, 87, 45164, 25961, 2655, 4724, 23557, 1829, 26890, 20449, 2423, 4724, 1829, 11933, 4117, 3794, 38637, 16572, 4724, 2655, 3615, 9566, 1829, 8315, 497, 87, 32239, 8592, 41850, 12602, 7435, 34268, 9122, 3224, 7649, 3660, 16490, 9566, 2407, 3660, 5296, 13063, 995, 6225, 8592, 7649, 5551, 8848, 37983, 24793, 20666, 7435, 2304, 37977, 13672, 1829, 9122, 8315, 8717, 39648, 11296], "avg_logprob": -0.43348214966910226, "compression_ratio": 1.5434782608695652, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 832.61, "end": 833.59, "word": "ROH", "probability": 0.21905517578125}, {"start": 833.59, "end": 834.47, "word": " بتعطينا", "probability": 0.6352640787760416}, {"start": 834.47, "end": 834.49, "word": " Rx", "probability": 0.191070556640625}, {"start": 834.49, 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"start": 1362.79, "end": 1390.69, "text": "حيطلع عندى acid الار الكحول هنا مكون من كام carbon ال acid اللى هنا تكون مكون من كام carbon مكون من two carbons طيب لو هدا إجينا حولنا بال BX3 ل RX يعني نفترض صار CH3 CH2 خلينا نقول CL", "tokens": [5016, 1829, 9566, 1211, 3615, 43242, 7578, 8258, 2423, 9640, 33251, 5016, 12610, 34105, 3714, 30544, 9154, 9122, 10943, 5954, 2423, 8258, 13672, 7578, 34105, 6055, 30544, 3714, 30544, 9154, 9122, 10943, 5954, 3714, 30544, 9154, 732, 12143, 892, 23032, 1829, 3555, 45164, 8032, 28259, 11933, 7435, 1829, 8315, 11331, 12610, 8315, 20666, 363, 55, 18, 5296, 46197, 37495, 22653, 8717, 5172, 2655, 43042, 20328, 9640, 5995, 18, 5995, 17, 16490, 1211, 9957, 995, 8717, 39648, 12855], "avg_logprob": -0.3239182692307692, "compression_ratio": 1.615819209039548, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 1362.79, "end": 1363.85, "word": "حيطلع", "probability": 0.694287109375}, {"start": 1363.85, "end": 1364.59, "word": " عندى", "probability": 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لو أستخدم الألوان سيصبح CH3 و CH2 موجودين", "tokens": [2304, 3615, 2423, 39184, 3002, 17, 4032, 8717, 2304, 25720, 568, 389, 18, 46, 4724, 1211, 3794, 8978, 29538, 21542, 6027, 3660, 7251, 29245, 3215, 16472, 16254, 4117, 9640, 3555, 11536, 568, 3714, 29245, 23328, 9957, 16070, 39184, 3002, 17, 7251, 2304, 12984, 1211, 33251, 9640, 3555, 11536, 16712, 6027, 2655, 3660, 6156, 3224, 2407, 7251, 11622, 25708, 16472, 16254, 4117, 9640, 3555, 11536, 37495, 22653, 45164, 5551, 14851, 9778, 40448, 16247, 1211, 2407, 7649, 8608, 1829, 9381, 49628, 5995, 18, 4032, 5995, 17, 3714, 29245, 23328, 9957], "avg_logprob": -0.36446630552913367, "compression_ratio": 1.7300613496932515, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1420.45, "end": 1420.81, "word": "مع", "probability": 0.687744140625}, {"start": 1420.81, "end": 1421.03, "word": " الـ", "probability": 0.642578125}, {"start": 1421.03, "end": 1421.83, "word": " CO2", "probability": 0.752197265625}, {"start": 1421.83, "end": 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"end": 1751.86, "word": " ال", "probability": 0.54296875}, {"start": 1751.86, "end": 1752.78, "word": " Rcn", "probability": 0.8369140625}, {"start": 1752.78, "end": 1753.38, "word": " لو", "probability": 0.83056640625}, {"start": 1753.38, "end": 1754.02, "word": " أخدته", "probability": 0.7232421875}, {"start": 1754.02, "end": 1754.14, "word": " و", "probability": 0.88720703125}, {"start": 1754.14, "end": 1754.52, "word": " أعملت", "probability": 0.686614990234375}, {"start": 1754.52, "end": 1754.68, "word": " له", "probability": 0.830078125}, {"start": 1754.68, "end": 1755.84, "word": " هيدروليسيس", "probability": 0.694091796875}, {"start": 1755.84, "end": 1756.24, "word": " بمصادر", "probability": 0.481689453125}, {"start": 1756.24, "end": 1756.86, "word": " أساذيكية", "probability": 0.643341064453125}], "temperature": 1.0}, {"id": 76, "seek": 177286, "start": 1758.8, "end": 1772.86, "text": "يعني حطيته بحامض أو كمان ممكن ال basic media بس نمرة واحد بنحط OH minus ونمرة اتنين H plus هيعطيل الحامض فبنقول احنا ان ال cyanide", "tokens": [40228, 22653, 11331, 9566, 36081, 3224, 4724, 5016, 10943, 11242, 34051, 9122, 2304, 7649, 3714, 43020, 2423, 3875, 3021, 4724, 3794, 8717, 2304, 25720, 36764, 24401, 44945, 5016, 9566, 13931, 3175, 4032, 1863, 2304, 25720, 1975, 2655, 1863, 9957, 389, 1804, 39896, 3615, 9566, 26895, 21542, 10943, 11242, 6156, 3555, 1863, 39648, 1975, 5016, 8315, 16472, 2423, 47463, 482], "avg_logprob": -0.32161458184321723, "compression_ratio": 1.3290322580645162, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1758.8, "end": 1759.12, "word": "يعني", "probability": 0.5186767578125}, {"start": 1759.12, "end": 1759.68, "word": " حطيته", "probability": 0.746337890625}, {"start": 1759.68, "end": 1760.42, "word": " بحامض", "probability": 0.76092529296875}, {"start": 1760.42, "end": 1761.52, "word": " أو", "probability": 0.69384765625}, {"start": 1761.52, "end": 1762.2, "word": " كمان", "probability": 0.8396809895833334}, {"start": 1762.2, 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hydroxide وبعدين الفعلها مع H plus سواء مشينا زي هيك أو هيك فال RCN بتتحول إلى أسد الآن هذا ال acid إيش ميزته؟", "tokens": [7035, 312, 15435, 356, 11312, 37495, 22653, 39894, 39237, 1829, 1829, 4587, 20666, 2304, 10632, 39894, 2655, 5016, 12610, 30731, 11331, 10943, 11242, 11933, 15042, 4724, 28814, 11242, 31845, 3660, 9122, 25513, 2407, 4117, 3794, 26895, 4117, 5551, 3794, 3215, 11933, 15042, 4724, 28814, 11242, 31845, 3660, 5551, 3794, 3215, 30767, 1829, 2423, 39184, 47286, 374, 299, 8258, 50113, 15040, 34051, 19446, 30731, 29910, 23275, 34051, 4724, 28814, 11242, 31845, 3660, 12174, 995, 22488, 3660, 3096, 30767, 1829, 2423, 20265, 15435, 34454, 46599, 22488, 9957, 27188, 30241, 11296, 20449, 389, 1804, 8608, 2407, 16606, 37893, 1829, 8315, 30767, 1829, 39896, 4117, 34051, 39896, 4117, 6156, 6027, 28987, 45, 39894, 2655, 5016, 12610, 30731, 5551, 3794, 3215, 6024, 48506, 23758, 2423, 8258, 11933, 1829, 8592, 3714, 1829, 11622, 47395, 22807], "avg_logprob": -0.2468749994268784, 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"probability": 0.86806640625}, {"start": 1779.62, "end": 1781.6, "word": " كربوكسيلك", "probability": 0.7249755859375}, {"start": 1781.6, "end": 1781.88, "word": " أسد", "probability": 0.8111979166666666}, {"start": 1781.88, "end": 1782.12, "word": " إما", "probability": 0.70703125}, {"start": 1782.12, "end": 1782.74, "word": " بإضافة", "probability": 0.98828125}, {"start": 1782.74, "end": 1783.08, "word": " أسد", "probability": 0.9306640625}, {"start": 1783.08, "end": 1783.28, "word": " زي", "probability": 0.7255859375}, {"start": 1783.28, "end": 1783.46, "word": " الـ", "probability": 0.5103759765625}, {"start": 1783.46, "end": 1784.0, "word": " sulphuric", "probability": 0.7333170572916666}, {"start": 1784.0, "end": 1784.36, "word": " acid", "probability": 0.91357421875}, {"start": 1784.36, "end": 1784.86, "word": " مثلا", "probability": 0.902099609375}, {"start": 1784.86, "end": 1785.06, "word": " أو", "probability": 0.81640625}, {"start": 1785.06, "end": 1785.18, "word": " ما", 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0.8251953125}, {"start": 1792.5, "end": 1793.34, "word": " مع", "probability": 0.56298828125}, {"start": 1793.34, "end": 1793.7, "word": " H", "probability": 0.8232421875}, {"start": 1793.7, "end": 1794.5, "word": " plus", "probability": 0.30517578125}, {"start": 1794.5, "end": 1795.12, "word": " سواء", "probability": 0.9676106770833334}, {"start": 1795.12, "end": 1795.48, "word": " مشينا", "probability": 0.806396484375}, {"start": 1795.48, "end": 1795.7, "word": " زي", "probability": 0.966552734375}, {"start": 1795.7, "end": 1795.84, "word": " هيك", "probability": 0.803955078125}, {"start": 1795.84, "end": 1796.0, "word": " أو", "probability": 0.83984375}, {"start": 1796.0, "end": 1796.4, "word": " هيك", "probability": 0.96923828125}, {"start": 1796.4, "end": 1797.24, "word": " فال", "probability": 0.852294921875}, {"start": 1797.24, "end": 1798.4, "word": " RCN", "probability": 0.612548828125}, {"start": 1798.4, "end": 1799.58, "word": " بتتحول", "probability": 0.9696044921875}, 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{"start": 1854.86, "end": 1855.24, "word": " حمض", "probability": 0.8347981770833334}, {"start": 1855.24, "end": 1855.44, "word": " شو", "probability": 0.75048828125}, {"start": 1855.44, "end": 1856.16, "word": " المحصلة", "probability": 0.8851318359375}, {"start": 1856.16, "end": 1856.26, "word": " اللي", "probability": 0.944091796875}, {"start": 1856.26, "end": 1856.6, "word": " لازم", "probability": 0.9894205729166666}, {"start": 1856.6, "end": 1857.56, "word": " تكتبوها؟", "probability": 0.9393833705357143}], "temperature": 1.0}, {"id": 80, "seek": 187609, "start": 1861.67, "end": 1876.09, "text": "النيترالز هيدروليز لأسدين النيترالز CNN بتتحول لأحمر سواء كان هذا الهيدروليز باسيديك ميديام", "tokens": [6027, 1863, 36081, 2288, 6027, 11622, 8032, 25708, 2288, 12610, 1829, 11622, 5296, 10721, 3794, 3215, 9957, 28239, 36081, 2288, 6027, 11622, 24859, 39894, 2655, 5016, 12610, 5296, 10721, 5016, 29973, 8608, 2407, 16606, 25961, 23758, 2423, 3224, 25708, 2288, 12610, 1829, 11622, 4724, 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acid", "probability": 0.9912109375}, {"start": 2154.49, "end": 2155.29, "word": " anhydride", "probability": 0.85693359375}], "temperature": 1.0}, {"id": 92, "seek": 218048, "start": 2156.15, "end": 2180.49, "text": "الإيستر لو فعلته مع أمونيا أو أي أمين مركب فيه نيتروجين نفس الفكرة برضه هيعمل ال substitution هدف اتهاجم هنا و تطرد ال OH بسرعه DRC double bond O NR2 ممكن تكون NH2, NHR, whatever هذا أو هذا المشتقة شو بنسميها امت", "tokens": [6027, 28814, 1829, 14851, 2288, 45164, 6156, 30241, 47395, 20449, 5551, 2304, 11536, 25528, 34051, 36632, 5551, 2304, 9957, 3714, 31747, 3555, 8978, 3224, 8717, 36081, 2288, 29245, 9957, 8717, 36178, 27188, 4117, 25720, 4724, 43042, 3224, 39896, 25957, 1211, 2423, 35827, 8032, 3215, 5172, 1975, 47395, 26108, 2304, 34105, 4032, 6055, 9566, 2288, 3215, 2423, 13931, 4724, 3794, 2288, 3615, 3224, 12118, 34, 3834, 6086, 422, 426, 49, 17, 3714, 43020, 6055, 30544, 31118, 17, 11, 31118, 49, 11, 2035, 23758, 34051, 23758, 9673, 8592, 2655, 28671, 13412, 2407, 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بقول أنا مشتقات للحامض لأن أنا بحضرها من الحامض التفاعل الأخير أن الحامض لو فعلناه مع base بيعطينا ال salt هذا أخدناه في أول المحاضرة هذه", "tokens": [10721, 2304, 3215, 6156, 27842, 21542, 10943, 11242, 6225, 2304, 6027, 11331, 11242, 43500, 2423, 8258, 35434, 2423, 8258, 18931, 6655, 25502, 2423, 257, 3120, 2423, 10943, 3215, 4032, 8032, 3215, 12610, 3660, 8032, 2304, 16247, 25513, 27884, 33733, 13672, 1829, 47525, 8315, 8717, 3215, 2288, 3794, 16095, 8978, 4724, 995, 4587, 10632, 2423, 7187, 18871, 37893, 2655, 4587, 9307, 16247, 35571, 11242, 6156, 2304, 8592, 2655, 4587, 9307, 21542, 10943, 11242, 37495, 22653, 9154, 9566, 4587, 2423, 28820, 10943, 32239, 8592, 41850, 4724, 39648, 41850, 37893, 2655, 4587, 9307, 24976, 5016, 10943, 11242, 5296, 33456, 41850, 4724, 5016, 11242, 2288, 11296, 9154, 21542, 10943, 11242, 16712, 5172, 995, 30241, 16247, 9778, 13546, 14739, 21542, 10943, 11242, 45164, 6156, 30241, 8315, 3224, 20449, 3096, 4724, 40228, 9566, 1829, 8315, 2423, 5139, 23758, 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2206.38, "end": 2207.28, "word": " التفاعل", "probability": 0.875732421875}, {"start": 2207.28, "end": 2207.86, "word": " الأخير", "probability": 0.82275390625}, {"start": 2207.86, "end": 2208.06, "word": " أن", "probability": 0.46044921875}, {"start": 2208.06, "end": 2208.72, "word": " الحامض", "probability": 0.9309895833333334}, {"start": 2208.72, "end": 2208.96, "word": " لو", "probability": 0.97314453125}, {"start": 2208.96, "end": 2209.48, "word": " فعلناه", "probability": 0.86163330078125}, {"start": 2209.48, "end": 2209.58, "word": " مع", "probability": 0.9833984375}, {"start": 2209.58, "end": 2209.88, "word": " base", "probability": 0.385009765625}, {"start": 2209.88, "end": 2210.4, "word": " بيعطينا", "probability": 0.83125}, {"start": 2210.4, "end": 2210.58, "word": " ال", "probability": 0.6962890625}, {"start": 2210.58, "end": 2210.88, "word": " salt", "probability": 0.412109375}, {"start": 2210.88, "end": 2211.16, "word": " هذا", "probability": 0.72265625}, {"start": 2211.16, "end": 2211.6, "word": " أخدناه", "probability": 0.94736328125}, {"start": 2211.6, "end": 2211.7, "word": " في", "probability": 0.97314453125}, {"start": 2211.7, "end": 2211.92, "word": " أول", "probability": 0.953125}, {"start": 2211.92, "end": 2212.6, "word": " المحاضرة", "probability": 0.976806640625}, {"start": 2212.6, "end": 2212.98, "word": " هذه", "probability": 0.8525390625}], "temperature": 1.0}, {"id": 94, "seek": 223259, "start": 2214.39, "end": 2232.59, "text": "حمض وقاعدة بيعطينا هنا نفترض r-c-o-o and a plus salt زائد ماء هذا اللي هو التفاعل اللي ابتدينا في المحاضرة مرة علينا فكأنه التفاعلات الأساسية الأربعة للحمض", "tokens": [5016, 2304, 11242, 4032, 4587, 995, 22488, 3660, 4724, 1829, 3615, 9566, 1829, 8315, 34105, 8717, 5172, 2655, 43042, 367, 12, 66, 12, 78, 12, 78, 293, 257, 1804, 5139, 30767, 16373, 3215, 3714, 16606, 23758, 13672, 1829, 31439, 16712, 5172, 995, 30241, 13672, 1829, 48127, 2655, 16254, 8315, 8978, 9673, 5016, 46958, 25720, 3714, 25720, 11203, 9957, 995, 6156, 4117, 33456, 3224, 16712, 5172, 995, 30241, 9307, 16247, 3794, 32277, 10632, 16247, 25513, 27884, 24976, 35571, 11242], "avg_logprob": -0.20332278556461575, "compression_ratio": 1.5406976744186047, "no_speech_prob": 9.5367431640625e-06, "words": [{"start": 2214.39, "end": 2215.33, "word": "حمض", "probability": 0.6574503580729166}, {"start": 2215.33, "end": 2216.75, "word": " وقاعدة", "probability": 0.82099609375}, {"start": 2216.75, "end": 2217.45, "word": " بيعطينا", "probability": 0.8270670572916666}, {"start": 2217.45, "end": 2217.79, "word": " هنا", "probability": 0.8017578125}, {"start": 2217.79, "end": 2218.63, "word": " نفترض", "probability": 0.888916015625}, {"start": 2218.63, "end": 2218.89, "word": " r", "probability": 0.1824951171875}, {"start": 2218.89, "end": 2219.07, "word": "-c", "probability": 0.3525390625}, {"start": 2219.07, "end": 2219.25, "word": "-o", "probability": 0.953125}, {"start": 2219.25, "end": 2220.01, "word": "-o", "probability": 0.96142578125}, {"start": 2220.01, "end": 2220.41, "word": " and", "probability": 0.4658203125}, {"start": 2220.41, "end": 2220.61, "word": " a", "probability": 0.869140625}, {"start": 2220.61, "end": 2220.93, "word": " plus", "probability": 0.59130859375}, {"start": 2220.93, "end": 2221.59, "word": " salt", "probability": 0.51904296875}, {"start": 2221.59, "end": 2222.61, "word": " زائد", "probability": 0.8958333333333334}, {"start": 2222.61, "end": 2223.27, "word": " ماء", "probability": 0.85986328125}, {"start": 2223.27, "end": 2223.99, "word": " هذا", "probability": 0.8291015625}, {"start": 2223.99, "end": 2224.13, "word": " اللي", "probability": 0.97705078125}, {"start": 2224.13, "end": 2224.29, "word": " هو", "probability": 0.97705078125}, {"start": 2224.29, "end": 2224.93, "word": " التفاعل", "probability": 0.93359375}, {"start": 2224.93, "end": 2225.09, "word": " اللي", "probability": 0.966552734375}, {"start": 2225.09, "end": 2225.59, "word": " ابتدينا", "probability": 0.866943359375}, {"start": 2225.59, "end": 2225.89, "word": " في", "probability": 0.9404296875}, {"start": 2225.89, "end": 2226.73, "word": " المحاضرة", "probability": 0.990966796875}, {"start": 2226.73, "end": 2226.97, "word": " مرة", "probability": 0.71142578125}, {"start": 2226.97, "end": 2227.71, "word": " علينا", "probability": 0.7849934895833334}, {"start": 2227.71, "end": 2228.51, "word": " فكأنه", "probability": 0.8948974609375}, {"start": 2228.51, "end": 2229.31, "word": " التفاعلات", "probability": 0.95380859375}, {"start": 2229.31, "end": 2230.27, "word": " الأساسية", "probability": 0.9820556640625}, {"start": 2230.27, "end": 2231.13, "word": " الأربعة", "probability": 0.9524739583333334}, {"start": 2231.13, "end": 2232.59, "word": " للحمض", "probability": 0.8782552083333334}], "temperature": 1.0}, {"id": 95, "seek": 225446, "start": 2233.9, "end": 2254.46, "text": "هي التفاعلات الأربعة اللي بنحضر من خلالها مشتقات الحامض يضاف إنهم تفاعل خامس اللي هو إن الحمض زائد قاعدة ملح زائد ماء وبهيك بننهي اليوم المحاضرة وإن شاء الله بنتابع فيه مرات قادمة", "tokens": [3224, 1829, 16712, 5172, 995, 30241, 9307, 16247, 25513, 27884, 13672, 1829, 44945, 5016, 11242, 2288, 9154, 16490, 1211, 6027, 11296, 37893, 2655, 4587, 9307, 21542, 10943, 11242, 7251, 11242, 31845, 36145, 16095, 6055, 5172, 995, 30241, 16490, 10943, 3794, 13672, 1829, 31439, 36145, 21542, 2304, 11242, 30767, 16373, 3215, 12174, 995, 22488, 3660, 3714, 1211, 5016, 30767, 16373, 3215, 3714, 16606, 46599, 3224, 1829, 4117, 44945, 1863, 3224, 1829, 45595, 20498, 9673, 5016, 46958, 25720, 4032, 28814, 1863, 13412, 16606, 21984, 44945, 2655, 16758, 3615, 8978, 3224, 3714, 2288, 9307, 12174, 18513, 46007], "avg_logprob": -0.10814144783898404, "compression_ratio": 1.8418079096045197, "no_speech_prob": 5.364418029785156e-07, "words": [{"start": 2233.9, "end": 2235.06, "word": "هي", "probability": 0.828369140625}, {"start": 2235.06, "end": 2235.94, "word": " التفاعلات", "probability": 0.9611328125}, {"start": 2235.94, "end": 2236.42, "word": " الأربعة", "probability": 0.9386393229166666}, {"start": 2236.42, "end": 2236.58, "word": " اللي", "probability": 0.782958984375}, {"start": 2236.58, "end": 2237.1, "word": " بنحضر", "probability": 0.934814453125}, {"start": 2237.1, "end": 2237.28, "word": " من", "probability": 0.98388671875}, {"start": 2237.28, "end": 2238.44, "word": " خلالها", "probability": 0.988525390625}, {"start": 2238.44, "end": 2239.76, "word": " مشتقات", "probability": 0.9163818359375}, {"start": 2239.76, "end": 2240.36, "word": " الحامض", "probability": 0.9431966145833334}, {"start": 2240.36, "end": 2241.1, "word": " يضاف", "probability": 0.94384765625}, {"start": 2241.1, "end": 2241.38, "word": " إنهم", "probability": 0.647705078125}, {"start": 2241.38, "end": 2241.96, "word": " تفاعل", "probability": 0.909423828125}, {"start": 2241.96, "end": 2242.54, "word": " خامس", "probability": 0.9192708333333334}, {"start": 2242.54, "end": 2242.76, "word": " اللي", "probability": 0.844482421875}, {"start": 2242.76, "end": 2243.26, "word": " هو", "probability": 0.990234375}, {"start": 2243.26, "end": 2243.76, "word": " إن", "probability": 0.61572265625}, {"start": 2243.76, "end": 2244.6, "word": " الحمض", "probability": 0.97021484375}, {"start": 2244.6, "end": 2245.16, "word": " زائد", "probability": 0.8084309895833334}, {"start": 2245.16, "end": 2245.92, "word": " قاعدة", "probability": 0.8333740234375}, {"start": 2245.92, "end": 2247.0, "word": " ملح", "probability": 0.9060872395833334}, {"start": 2247.0, "end": 2248.28, "word": " زائد", "probability": 0.9817708333333334}, {"start": 2248.28, "end": 2249.08, "word": " ماء", "probability": 0.932373046875}, {"start": 2249.08, "end": 2249.94, "word": " وبهيك", "probability": 0.78857421875}, {"start": 2249.94, "end": 2250.34, "word": " بننهي", "probability": 0.948486328125}, {"start": 2250.34, "end": 2250.6, "word": " اليوم", "probability": 0.9609375}, {"start": 2250.6, "end": 2251.22, "word": " المحاضرة", "probability": 0.93115234375}, {"start": 2251.22, "end": 2251.4, "word": " وإن", "probability": 0.7872721354166666}, {"start": 2251.4, "end": 2251.6, "word": " شاء", "probability": 0.935302734375}, {"start": 2251.6, "end": 2251.7, "word": " الله", "probability": 0.95849609375}, {"start": 2251.7, "end": 2252.7, "word": " بنتابع", "probability": 0.9481201171875}, {"start": 2252.7, "end": 2253.42, "word": " فيه", "probability": 0.95703125}, {"start": 2253.42, "end": 2253.94, "word": " مرات", "probability": 0.97216796875}, {"start": 2253.94, "end": 2254.46, "word": " قادمة", "probability": 0.9899088541666666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2254.88975, "duration_after_vad": 2166.0272187499922}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..385ab2c1e92e5ee4445def353f0eb70f7c40df00
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/clI807Oe8Rw_raw.srt
@@ -0,0 +1,1648 @@
+1
+00:00:11,180 --> 00:00:16,920
+بسم الله الرحمن الرحيم المرة
+
+2
+00:00:16,920 --> 00:00:21,300
+الماضية أخدنا فكرة عن الأحماض وتسميتهم و عن تحديدا
+
+3
+00:00:21,300 --> 00:00:28,610
+يمكن كمانالحمضية و تأثرها بعاملين أساسيين اللي هم
+
+4
+00:00:28,610 --> 00:00:33,070
+ال resonance effect و ال inductive effect واضح؟
+
+5
+00:00:33,510 --> 00:00:39,550
+الان بسبب الحامضية خلّيني أقول العالية نسبيا لل
+
+6
+00:00:39,550 --> 00:00:44,490
+carboxylic acids بنلاحظ أنهم يتفاعلوا مع ال bases
+
+7
+00:00:44,490 --> 00:00:49,870
+و مع weak bases كمان هذا الكلام مختلف عن الكحولات
+
+8
+00:00:49,870 --> 00:00:55,010
+يعني الكحولات لما كنا نقول الكحولvery weak acid
+
+9
+00:00:55,010 --> 00:00:58,590
+لما كنا نيجي نفعله مع sodium hydroxide مايتفعلش
+
+10
+00:00:58,590 --> 00:01:02,950
+كنا بدنا very strong base زي ال sodium metal بينما
+
+11
+00:01:02,950 --> 00:01:08,590
+الأحماض لو بنفعلها مع bases حتى لو كانت من مستوى
+
+12
+00:01:08,590 --> 00:01:13,610
+خلينا نقول ال sodium carbonateيعني الكربونة
+
+13
+00:01:13,610 --> 00:01:20,010
+العادية اللي هي تعتبر weak base بتتفاعل واضح؟ فمن
+
+14
+00:01:20,010 --> 00:01:23,390
+باب أولى بالتأكيد الأحماض هيتفاعلوا مع ال sodium
+
+15
+00:01:23,390 --> 00:01:29,790
+hydroxide التفاعل مشهور هو تفاعل حمض وقاعدة ملح
+
+16
+00:01:29,790 --> 00:01:36,070
+وماء فلو كان عندى أي carboxylic acid مع strong
+
+17
+00:01:36,070 --> 00:01:40,250
+base وحتى مع weak base كمان هلاحظ انه بتتفاعل
+
+18
+00:01:41,100 --> 00:01:45,440
+بيعطينا ال salt في هذه الحالة ال salt هذا بنسميه
+
+19
+00:01:45,440 --> 00:01:51,800
+sodium carboxylate لحظوا النهاية ate هذه ate
+
+20
+00:01:51,800 --> 00:01:58,300
+مرتبطة بالأيونات السالبة يعني الأيونات السالبة
+
+21
+00:01:58,300 --> 00:02:03,700
+نهايتها ate فاذكروا أنتم مثلا في عندكم ايون ال
+
+22
+00:02:03,700 --> 00:02:11,760
+nitrateوالسلفات و الأجزالات و الأسيتات كل الأيونات
+
+23
+00:02:11,760 --> 00:02:16,400
+السالبة بشكل عام نهيتها إيش بيكون؟ ات .. الأيونات
+
+24
+00:02:16,400 --> 00:02:18,620
+الموجبة شو بيكون نهيتها؟
+
+25
+00:02:20,790 --> 00:02:26,690
+اونيوم اونيوم زي امونيوم اوكزونيوم هايدرونيوم واضح
+
+26
+00:02:26,690 --> 00:02:31,870
+فهنا لانه عندى هذا ايون سالب مثلا نفترض من الاسيتك
+
+27
+00:02:31,870 --> 00:02:37,360
+اسيد بيكون صوديوم اسيتيت من البنزويك اسيدسوديوم
+
+28
+00:02:37,360 --> 00:02:42,260
+بنزويت و هكذا على سبيل مثال اي مثال محدد هذا جاي
+
+29
+00:02:42,260 --> 00:02:46,140
+من ال acetic acid هذي ال acetate group بصير سوديوم
+
+30
+00:02:46,140 --> 00:02:50,860
+أسيتاتي المثال التاني من ال benzoic acid مع ال
+
+31
+00:02:50,860 --> 00:02:57,820
+potassium بصير potassium بنزويت هذا من ال provenic
+
+32
+00:02:57,820 --> 00:03:03,560
+acidفبدوا يكون مع ال calcium طبعا بنسبة 2 ل 1
+
+33
+00:03:03,560 --> 00:03:10,560
+التفاعل calcium بروبانيت و هكذا فالخلاصة انه نتيجة
+
+34
+00:03:10,560 --> 00:03:16,420
+للحمضية خلينا نقول المرتفعة نسبية للأحماض
+
+35
+00:03:16,420 --> 00:03:21,980
+الكربوكسيلية بتفاعلوا مع ال bases و بيقدروا لتكوين
+
+36
+00:03:21,980 --> 00:03:29,840
+الأملاح و الماءالان لو اجينا نقول كيف تحضر ال
+
+37
+00:03:29,840 --> 00:03:35,000
+carboxylic acidsبإمكاننا نعمل الكلام بسبعة slides
+
+38
+00:03:35,000 --> 00:03:41,440
+أو تمانية و بإمكاننا نختصره ب slide واحدة واضح؟
+
+39
+00:03:41,440 --> 00:03:45,380
+هذه ال slide تقريبا بتحط لنا طريقة تنتين، تلاتة،
+
+40
+00:03:45,380 --> 00:03:50,400
+أربعة، خمسة، ستة، سبعة، كل هذه الطرق لتحضير
+
+41
+00:03:50,400 --> 00:03:54,060
+الأحماض الكربوكسيلية فالطرق زي ما بتعرفوا كثيرا
+
+42
+00:03:54,060 --> 00:04:02,300
+هتلاحظوا أن بعض هذه الطرقدرسناها احنا سابقا، بعض
+
+43
+00:04:02,300 --> 00:04:06,700
+هذه الطرق لتحضير ال carboxylic acids درسناها
+
+44
+00:04:06,700 --> 00:04:13,540
+سابقا، والبعض بيمر علينا لأول مرة خلينا نشوف مثلا
+
+45
+00:04:13,540 --> 00:04:17,640
+الأشياء اللي درسناها سابقا، الأشياء اللي درسناها
+
+46
+00:04:17,640 --> 00:04:23,320
+سابقامثلًا هذه الطريقة التانية لما بكون عندى ال
+
+47
+00:04:23,320 --> 00:04:27,020
+keen .. لما بكون عندى ال keen و بعمله انا
+
+48
+00:04:27,020 --> 00:04:34,340
+ozonolysis followed by oxidation واضح؟ اذا كان هنا
+
+49
+00:04:34,340 --> 00:04:39,950
+في عندىالديهيد اتكون في المرحلة الأولى، هذا ال
+
+50
+00:04:39,950 --> 00:04:45,610
+الديهيد بعد هيك بتأكسد بخطوة إضافية لإيش؟ للحمض،
+
+51
+00:04:45,610 --> 00:04:49,710
+لو كانوا هدولة التلتين R-groups بيظلوا عنده كيتون
+
+52
+00:04:49,710 --> 00:04:55,270
+و أخدنا في تفاعلات الالكينز أمثلة على هذا النوع و
+
+53
+00:04:55,270 --> 00:04:59,070
+بتذكروا لو كان عندنا two hydrogens كنا مرات نقول
+
+54
+00:04:59,070 --> 00:05:04,780
+ممكن نصل لثانو أكسيد كاربون في الآخر يعنيفمثل هذا
+
+55
+00:05:04,780 --> 00:05:11,880
+التفاعل اللي هو ال ozoneolysis أخدناه الآن نفس
+
+56
+00:05:11,880 --> 00:05:15,060
+الفكرة زي ما بيصير ال ozoneolysis في ال double
+
+57
+00:05:15,060 --> 00:05:18,980
+bond برضه بيصير في ال triple bond وبهذا الحالة
+
+58
+00:05:18,980 --> 00:05:25,050
+بيعطينا أحمدمن التفاعلات اللي أخدناها أنه ال
+
+59
+00:05:25,050 --> 00:05:30,290
+primary alcohols بس بشرط يكون ال oxidizing agent
+
+60
+00:05:30,290 --> 00:05:36,830
+strong بتأكسده لحد ما يصلوا ل ال carboxylic acid
+
+61
+00:05:36,830 --> 00:05:40,590
+إذا بتحاولوا تتذكروا هنا مهم أن نتذكر نوع ال
+
+62
+00:05:40,590 --> 00:05:45,670
+oxidizing agent لأن كان في عندنا oxidizing agent
+
+63
+00:05:46,810 --> 00:05:51,590
+بيوصلني بس لل الديهيد اللي هي مثل البريدينيا
+
+64
+00:05:51,590 --> 00:05:55,750
+ميكلورو كروميت وفي اكسيدايزينج ايجانت بيحول ال
+
+65
+00:05:55,750 --> 00:06:04,350
+primary alcohol لاسس مثل الكيامان O4 و ال K2
+
+66
+00:06:04,350 --> 00:06:10,210
+كروميوم 2 O7 و الكروميوم O3 كل هذا الكلام أخدناه
+
+67
+00:06:10,210 --> 00:06:14,110
+اللي هي ال strong oxidizing agents they convert
+
+68
+00:06:14,110 --> 00:06:16,230
+primary alcohols
+
+69
+00:06:21,150 --> 00:06:28,570
+الـ BCC كان يحول هذا البرايمري الكهول الى الديهيد
+
+70
+00:06:28,570 --> 00:06:33,210
+الواضح فإذا كنت بدى ال acid وعندي ال primary
+
+71
+00:06:33,210 --> 00:06:35,730
+alcohol لازم استخدم ال
+
+72
+00:06:39,640 --> 00:06:45,320
+بالتأكيد لو اتكون عندى ال الديهيد هنا نفس الاشي
+
+73
+00:06:45,320 --> 00:06:48,920
+ممكن نتخيل ان هذا ال الديهيد يتكون من هنا باستعمال
+
+74
+00:06:48,920 --> 00:06:54,720
+ال BCC البريدينيا الكلورو كروميت ال الديهيد نفسه
+
+75
+00:06:54,720 --> 00:07:02,040
+ممكن ان اكسته مرة تانية لل acid باستعمال اى واحدمن
+
+76
+00:07:02,040 --> 00:07:05,820
+هذه الـ strong oxidizing agent فسواء أنا بدأت ب
+
+77
+00:07:05,820 --> 00:07:09,560
+primary alcohol أو بدأت ب aldehyde إذا كان ال
+
+78
+00:07:09,560 --> 00:07:14,720
+oxidizing agent اللي عندي من فئة ال camon O4 أو ال
+
+79
+00:07:14,720 --> 00:07:18,620
+keto chromium 2 O7 أو ال chromium O3 الكروميك أسد
+
+80
+00:07:18,620 --> 00:07:24,840
+بهاد الحالة بتحول إلى carboxylic acid واضح؟ فزي
+
+81
+00:07:24,840 --> 00:07:30,180
+هيك بنلاحظ احنا ان هذا الطريقة سبق مرت علينا و هذا
+
+82
+00:07:30,180 --> 00:07:33,740
+الطريقةو ممكن نسألكوا ياها بسؤال صح و غلط أنه
+
+83
+00:07:33,740 --> 00:07:38,280
+primary alcohols are oxidized to carboxylic acids
+
+84
+00:07:38,280 --> 00:07:42,800
+using strong oxidizing agents أو الديهيد are
+
+85
+00:07:42,800 --> 00:07:47,180
+oxidized to carboxylic acids using strong
+
+86
+00:07:47,180 --> 00:07:53,940
+oxidizing agentsإذا بيظل ربما كجديد علينا .. بيظل
+
+87
+00:07:53,940 --> 00:07:57,720
+كجديد علينا في هذه المنطقة هذه الطريقة و هذه
+
+88
+00:07:57,720 --> 00:08:01,900
+الطريقة و هذه الطريقة ربما ماسبقش مرة علينا ك
+
+89
+00:08:01,900 --> 00:08:05,580
+method for the preparation of carboxylic acids
+
+90
+00:08:05,580 --> 00:08:12,300
+ممكن نبدأ ناخد آخر method هذه بيسموها oxidation of
+
+91
+00:08:12,300 --> 00:08:17,680
+the aliphatic sided chain on an aromatic ring يعني
+
+92
+00:08:18,380 --> 00:08:21,540
+هذه الطريقة بتقول القاتل انه انا لما بكون عندى
+
+93
+00:08:21,540 --> 00:08:27,620
+aromatic ring نفترض زى البنزين واضح؟ و بتحمل هنا
+
+94
+00:08:27,620 --> 00:08:31,400
+aliphatic sided chain نفترض هذه الـsided chain
+
+95
+00:08:31,400 --> 00:08:36,560
+كانت CH3 على سبيل المثال واضح؟ اذا صار في عندى
+
+96
+00:08:36,560 --> 00:08:42,440
+aromatic ring و ال aromatic ring حاملة aliphatic
+
+97
+00:08:42,440 --> 00:08:48,960
+sided chain واضح؟ هذى اش هذى؟أليفاتك صيدتشين
+
+98
+00:08:48,960 --> 00:08:55,780
+محمولة على اروماتك رينج لما يكون عندى أليفاتك
+
+99
+00:08:55,780 --> 00:09:00,420
+صيدتشين محمولة على اروماتك رينج بنعمل لها اكسيداشن
+
+100
+00:09:00,420 --> 00:09:05,900
+عادة بالكيامان او فور بالبوتاسيوم
+
+101
+00:09:05,900 --> 00:09:12,120
+بيرمانجانيد بيحول هذه المجموعة الأليفاتك الى
+
+102
+00:09:12,120 --> 00:09:19,590
+كربوكسليك أسدبدل ما هي مثل بتصير c double bond o o
+
+103
+00:09:19,590 --> 00:09:25,860
+hالان هذا الكلام له شرط هل الكلام باسمع المثل؟ لأ
+
+104
+00:09:25,860 --> 00:09:31,760
+اي aliphatic sided chain وان كبرت بس بشرط انه ال
+
+105
+00:09:31,760 --> 00:09:36,100
+carbon المتصلة مباشرة هنا في ال aromatic ring تكون
+
+106
+00:09:36,100 --> 00:09:41,040
+حاملة هيدروجين اقل اشي هيدروجين تنتين بمشي تلاتة
+
+107
+00:09:41,040 --> 00:09:46,260
+بمشي بس اقل اشي هيدروجين في هذه الحالة بيعطينا
+
+108
+00:09:46,260 --> 00:09:50,910
+carboxylic acidالان هذه منطقة خلينا نقول منطقة
+
+109
+00:09:50,910 --> 00:09:56,750
+أحيانا خطأ عند الطلاب و لذلك خلينا نوضحها يعني لو
+
+110
+00:09:56,750 --> 00:10:06,330
+افترضنا مثلا عنده بنزين و حامل مثل و بنزين تاني و
+
+111
+00:10:06,330 --> 00:10:06,910
+حامل
+
+112
+00:10:09,350 --> 00:10:14,130
+Ethyl كبرت الـ aliphatic side chain واضح؟ الآن هذا
+
+113
+00:10:14,130 --> 00:10:19,290
+و هذا بيعطوا نفس الناتج ماحدش يجي يحط ال acid هنا
+
+114
+00:10:19,290 --> 00:10:25,890
+لأ في الحالتين أيا كانت ال aliphatic side chain
+
+115
+00:10:25,890 --> 00:10:29,830
+وإن كبرت حتى لو كانت عشر كربونات في الآخر بتعطي
+
+116
+00:10:29,830 --> 00:10:34,950
+acid واحدواضحة هذه النقطة الكثير من الجمال اللي
+
+117
+00:10:34,950 --> 00:10:37,310
+ميكملوا المسألة كانوا بيروحوا بيحطوا أسد على
+
+118
+00:10:37,310 --> 00:10:41,150
+الكاربون الطرفية مثلا لو كان عندي خمس كاربونات هنا
+
+119
+00:10:41,150 --> 00:10:46,830
+الخمسة كلهم بدهم ينشالوا ويجي مكانهم مجموعة أسد
+
+120
+00:10:46,830 --> 00:10:53,250
+واحدة وقت إيش ما بيصيرش التفاعل إذا كانت الكاربون
+
+121
+00:10:53,250 --> 00:10:59,170
+هذه الأولى مافيش عليها هيدروجين لكن مثلا تكون مثل
+
+122
+00:11:00,620 --> 00:11:04,160
+مثلًا مثلبنزين اللي هو الطلوين أو الاثلبنزين أو
+
+123
+00:11:04,160 --> 00:11:08,480
+البروبلبنزين أو البيوتلبنزين أو الايزوبروبلبنزين
+
+124
+00:11:08,480 --> 00:11:15,640
+كل هدولة بيعطوني بنزويك أسد كلهم بيعطوا نفس الناتج
+
+125
+00:11:15,640 --> 00:11:24,000
+إيش اللي مابيعطيش زي ال tertiary butyl group مثلًا
+
+126
+00:11:24,000 --> 00:11:26,120
+يعني لو أخدنا هذا المركب
+
+127
+00:11:33,110 --> 00:11:36,930
+هذه مجموعة الـ tertiary-butyl الأربعة المجموعة
+
+128
+00:11:36,930 --> 00:11:40,670
+المزدحمة لأن هذا الكربون اللي هنا مش حملة هيدروجين
+
+129
+00:11:40,670 --> 00:11:44,370
+هذا لو كنت اعمله oxidation بالكمان O4 مابيعطينيش
+
+130
+00:11:44,370 --> 00:11:51,890
+acid واضح؟ لكن لو كان المركب H
+
+131
+00:11:51,890 --> 00:11:56,830
+اه
+
+132
+00:11:56,830 --> 00:11:58,950
+واضح؟
+
+133
+00:12:00,070 --> 00:12:03,770
+الان مثل هذا السؤال عشان نذكركوا شوية في العلم لو
+
+134
+00:12:03,770 --> 00:12:09,810
+كنا بدنا نسألكوا فيه بالصح والغلط شو بنقولكوا؟
+
+135
+00:12:09,810 --> 00:12:17,060
+اكيومينتذكروا ان هذا اسمه كيومين، كيومين can be
+
+136
+00:12:17,060 --> 00:12:23,080
+oxidized to benzoic acid، صح الترث شربيوت البنزين
+
+137
+00:12:23,080 --> 00:12:28,200
+can be oxidized to benzoic acid، غلط طبعا مشكلة لو
+
+138
+00:12:28,200 --> 00:12:33,260
+قلنالكم both كيومين and ترث شربيوت البنزين can be
+
+139
+00:12:33,260 --> 00:12:36,640
+oxidized to carboxylic acid، لأ مش التنين، واحد
+
+140
+00:12:36,640 --> 00:12:41,920
+منهم اللي بيكون فيه at least one hydrogenواضح هذه
+
+141
+00:12:41,920 --> 00:12:46,160
+الفكرة؟ at least بيكون عندى one hydrogen كل ال
+
+142
+00:12:46,160 --> 00:12:49,160
+side chain بتكون تشيلوها مش تشوفوها كبيرة
+
+143
+00:12:49,160 --> 00:12:53,660
+تتخلونكوا شوية منها لأ بتكون تجيبوا مساحة تمسحوها
+
+144
+00:12:53,660 --> 00:13:02,120
+و تحطوا مكانها COOH Carboxylic Acid اذا هذا ال
+
+145
+00:13:02,120 --> 00:13:06,800
+method السابع اللى هنا اللى بنسميه oxidation of a
+
+146
+00:13:06,800 --> 00:13:12,660
+sided chainon aromatic ring اللي هو اكسدت السلسلة
+
+147
+00:13:12,660 --> 00:13:16,960
+الالفاتية ال alphatic sided chain attached to
+
+148
+00:13:16,960 --> 00:13:19,000
+aromatic rings
+
+149
+00:13:25,440 --> 00:13:30,320
+بيجينا كمان طريقتين لتحضير ال carboxylic acids
+
+150
+00:13:30,320 --> 00:13:36,880
+الطريقة الأولى بتبدأ من ال RX الطريقة الأولى بتبدأ
+
+151
+00:13:36,880 --> 00:13:43,400
+من ال RX يمكن إذا بدنا نذكركوا أكتر ال RX عادة
+
+152
+00:13:43,400 --> 00:13:49,440
+ممكن إحنا نحضرها من ال ROH ال alcohol واضح؟ يعني
+
+153
+00:13:49,440 --> 00:13:56,030
+في الأساس يكون عندكROH بتعطينا Rx لو كانت برايبر
+
+154
+00:13:56,030 --> 00:14:01,510
+مع ال بي إكس ثري بتعطينا Rx ليش أنا رجعت كهانة
+
+155
+00:14:01,510 --> 00:14:05,710
+خطوة لورا عشان أذكركم بالجملة اللي كنا نقولها
+
+156
+00:14:08,040 --> 00:14:11,980
+الكيميائي لو كان في الصحراء لو كان في الصحراء و
+
+157
+00:14:11,980 --> 00:14:16,040
+معه alcohol بيحضر منه كل إشي لاحظوا ال alcohol هنا
+
+158
+00:14:16,040 --> 00:14:20,500
+بإمكان احضر منه RX RX بعد شوية بيحضر منه Green
+
+159
+00:14:20,500 --> 00:14:23,740
+يعني if it's green يعني بيحضر منه ال acid ال acid
+
+160
+00:14:23,740 --> 00:14:27,400
+هتلاحظوا بيحضر منه كل مشتقات ال acid ال Easter و
+
+161
+00:14:27,400 --> 00:14:29,780
+ال Amid و ال Acid chloride و ال acid anhydride
+
+162
+00:14:29,780 --> 00:14:33,960
+اللي بدهم يمروا علينا المشتقات واضح؟بس مبدئيا احنا
+
+163
+00:14:33,960 --> 00:14:39,340
+بنقول انه لو عندنا الكهول ممكن بسهولة يصير RX ال
+
+164
+00:14:39,340 --> 00:14:43,620
+RX مع المغنيسيوم أخدنا تفاعل شهير اللي هو ال green
+
+165
+00:14:43,620 --> 00:14:51,380
+yard reaction بيعطينا RMGX ال RMGX اتفقنا ان هو
+
+166
+00:14:51,380 --> 00:14:55,980
+يمثل enucleophile ولا electrophile? enucleophile
+
+167
+00:14:55,980 --> 00:15:05,370
+هو عبارة عن R معمع زوج الإلكترونات تبعها الآن ثاني
+
+168
+00:15:05,370 --> 00:15:11,030
+أكسيد الكربون ثاني أكسيد الكربون يمثل very strong
+
+169
+00:15:11,030 --> 00:15:15,230
+electrophile ليش ثاني أكسيد الكربون يمثل
+
+170
+00:15:15,230 --> 00:15:19,890
+electrophile؟ خلّينا نفصلوا هنا تنسوش أن تقولوا
+
+171
+00:15:19,890 --> 00:15:20,990
+ثاني أكسيد الكربون
+
+172
+00:15:23,630 --> 00:15:28,110
+CW.O وين السالبية اعلى على ال carbon ولا على ال
+
+173
+00:15:28,110 --> 00:15:31,310
+oxygen على ال oxygen اذا هنا عند partially
+
+174
+00:15:31,310 --> 00:15:37,270
+negative هنا partially positive و هنا partially
+
+175
+00:15:37,270 --> 00:15:44,570
+negative فال carbon هذه تبعت ال carbon dioxide is
+
+176
+00:15:46,130 --> 00:15:50,530
+Electrophile واضح ولهذا السبب ال carbon dioxide
+
+177
+00:15:50,530 --> 00:15:54,650
+احنا بنعمله على انه acid anhydride يعني في النهاية
+
+178
+00:15:54,650 --> 00:16:00,650
+لو بدنا ندوبه في الميه بيديه يعطينا حامض ثانوكسيد
+
+179
+00:16:00,650 --> 00:16:04,410
+كربون في الميه مش بيعطينا الكربون ال carbonic acid
+
+180
+00:16:04,410 --> 00:16:13,110
+فال R هذه بتيجي بتهاجم على ال positive carbonما
+
+181
+00:16:13,110 --> 00:16:16,970
+طلعناش على فكرة الـ negative بدوا يهاجم على ال
+
+182
+00:16:16,970 --> 00:16:21,270
+positive و بتتحرك زوج الإلكترونات هذا على ال
+
+183
+00:16:21,270 --> 00:16:28,750
+oxygen بيعطينا O minus فبصير عندك كمرحلة أولى R C
+
+184
+00:16:28,750 --> 00:16:34,850
+double bond O O minus لما في خطوة تانية انفعله مع
+
+185
+00:16:34,850 --> 00:16:41,980
+أي حامضبتصير OH فالخلاصة انه تفاعل ل green yard
+
+186
+00:16:41,980 --> 00:16:48,260
+ray agent مع ثاني أكسيد الكربون كخطوة أولى و بعدين
+
+187
+00:16:48,260 --> 00:16:54,280
+مع حامض مخفف كخطوة تانية بيعطيلي الحامض الآن انا
+
+188
+00:16:54,280 --> 00:16:59,500
+بتكون تنتبهوا لطريقة و منطق الكتابة هذا التفاعل لا
+
+189
+00:16:59,500 --> 00:17:04,540
+يجري على مرة واحدةهذا التفاعل يجرى على مرتين المرة
+
+190
+00:17:04,540 --> 00:17:09,180
+الأولى ان انا لجرينيرد رياجينت بده فاعله مع ثانو
+
+191
+00:17:09,180 --> 00:17:17,660
+أكسيد الكربون بعد ما يتفاعل وينتهي التفاعل تحديدا
+
+192
+00:17:17,660 --> 00:17:21,560
+لما بده ينتهي التفاعل هيعطيني هذا الناتج اذا حابين
+
+193
+00:17:21,560 --> 00:17:24,220
+تشوفوه هيعطينا هذا الناتج
+
+194
+00:17:27,190 --> 00:17:34,930
+وهنا بيصير عندكم C double bond O O M G B R بالظبط
+
+195
+00:17:34,930 --> 00:17:41,850
+بيكون O minus M G B R plus ليش؟ لأن ال M G plus
+
+196
+00:17:41,850 --> 00:17:49,780
+two و ال B Rالـ plus 2 و الـ minus 1 كلهم plus one
+
+197
+00:17:49,780 --> 00:17:58,520
+الـ Mg2 plus الـ Br minus one فكل الـ MgBr بتكون
+
+198
+00:17:58,520 --> 00:18:05,460
+plus وهنا O minus الآن هذا بنضيف عليه الـ H plus
+
+199
+00:18:05,460 --> 00:18:11,170
+أو اللي هنا رمزي له H3O plus بيعطينا ال acidفهذا
+
+200
+00:18:11,170 --> 00:18:16,290
+التفاعل على خطوة ولا على خطوتين؟ على خطوتين عشان
+
+201
+00:18:16,290 --> 00:18:21,370
+ايه؟ لما بنعبّل عن تفاعل على خطوتين بنكتب one و
+
+202
+00:18:21,370 --> 00:18:25,990
+two الان هذا بختلف .. هذا بختلف عن طريقة كتابة ال
+
+203
+00:18:25,990 --> 00:18:28,630
+reaction على السهم و لازم تكونوا منتمهين انتوا
+
+204
+00:18:28,630 --> 00:18:33,970
+بختلف كتير ان اكون كاتب .. ان اكون كاتب على السهم
+
+205
+00:18:33,970 --> 00:18:38,110
+بهذا الشكل CO2
+
+206
+00:18:38,110 --> 00:18:44,380
+فاصلةالـ H plus معناه ذلك هدولة التنتين نضافوا مرة
+
+207
+00:18:44,380 --> 00:18:48,920
+واحدة هنا لما أقول نمرة واحد كذا نمرة اتنين كذا
+
+208
+00:18:48,920 --> 00:18:54,200
+هدولة نضافوا بشكل متتالي طبعا لو هدولة بدوني نحطوا
+
+209
+00:18:54,200 --> 00:18:59,460
+مع بعض مش هيطلع نفس الناتج عارفين ليش؟ لأنه احنا
+
+210
+00:18:59,460 --> 00:19:03,920
+اتعلمنا شغل ان الـ H plus بتخرب Greenyard reagent
+
+211
+00:19:03,920 --> 00:19:10,760
+الـ H plus بتتفاعل مع Greenyard وبتعطيني RHمشقولنا
+
+212
+00:19:10,760 --> 00:19:16,380
+الميه و ال H plus و ال D2O كلهم لو شافوا green
+
+213
+00:19:16,380 --> 00:19:20,220
+yard reagent يعني green yard reagent بدل ما يتعب
+
+214
+00:19:20,220 --> 00:19:24,180
+حاله لو شاف ال H plus من أولها و يروح على ال
+
+215
+00:19:24,180 --> 00:19:27,800
+carbon الموجة بتاع ال ثانو أكسيد الكربون بيروح على
+
+216
+00:19:27,800 --> 00:19:33,720
+ال H plus أسله و أقربله واضح؟فلذلك عليكم ان
+
+217
+00:19:33,720 --> 00:19:39,140
+تنتبهوا كويس ان هذا التفاعل على مرحل تاني انا مش
+
+218
+00:19:39,140 --> 00:19:44,680
+كتير بهمني ان تكتبوا الناتج الوسطاني و بعدين
+
+219
+00:19:44,680 --> 00:19:48,220
+تطلعوا طالما هدول موجودين بشكل سليم نمر واحد نمر
+
+220
+00:19:48,220 --> 00:19:53,560
+اتنين اذا ال RMGX في الأخر بتعطيني RC double point
+
+221
+00:19:53,560 --> 00:20:00,500
+O OH واضح؟ لكن هذا لعملية التوضيح
+
+222
+00:20:03,250 --> 00:20:13,990
+الان هنا بفيدكم بصراحة انه تنتبهوا إلى مقارنة ما
+
+223
+00:20:13,990 --> 00:20:18,810
+بين الطرق .. تنتبهوا مقارنة ما بين الطرق ممكن
+
+224
+00:20:18,810 --> 00:20:24,530
+واحدة تقول طالما ان انا عند ال alcohol و باكسده
+
+225
+00:20:24,530 --> 00:20:32,660
+مباشرة للحمضواضح؟ انتبهوا معاك كويس دايما اختصار
+
+226
+00:20:32,660 --> 00:20:38,040
+بفيد ولا مابفيدش انا توقولت ال RX من وين جاياكم؟
+
+227
+00:20:38,040 --> 00:20:42,140
+من ال alcohol و انا عندي alcohol طيب اذا عندي هنا
+
+228
+00:20:42,140 --> 00:20:48,400
+alcohol و بأكسد هذا ال alcohol مباشرة للحمض ليش
+
+229
+00:20:48,400 --> 00:20:54,860
+اعمل؟ ليش اعمل؟ انه يكون عندي alcohol alcohol R-O
+
+230
+00:20:54,860 --> 00:21:02,350
+-H نفترضو بعدين ال alcohol يصير RX و ال RX جرينيرد
+
+231
+00:21:02,350 --> 00:21:08,190
+و جرينيرد بده ظروف صعبة بده very dry solvents يعني
+
+232
+00:21:08,190 --> 00:21:10,930
+يمكن في غزة عندنا مابظبطش لإن احنا عندنا رطوبة
+
+233
+00:21:10,930 --> 00:21:14,930
+البحر كتير يعني الرطوبة اللي في الجو بتخربه و
+
+234
+00:21:14,930 --> 00:21:19,390
+بعدين مع تاني أكسيد كربون كخطوة أولى و بعدين مع
+
+235
+00:21:19,390 --> 00:21:25,310
+الميه كخطوة ثانية ملاحظين انتوا؟ طب ليش .. ليش كل
+
+236
+00:21:25,310 --> 00:21:26,250
+هاللفة؟
+
+237
+00:21:30,650 --> 00:21:36,870
+على فرض انه عندى primary alcohol
+
+238
+00:21:36,870 --> 00:21:41,110
+طلع
+
+239
+00:21:41,110 --> 00:21:43,490
+عليهم كويس بفرجوا هدول عن بعض
+
+240
+00:21:48,010 --> 00:21:53,550
+في هذه الحالة في هذه الحالة هتلاحظ ان اي alcohol
+
+241
+00:21:53,550 --> 00:21:59,130
+موجود عنده انا بزيد على عدد الكربونات اللي موجودين
+
+242
+00:21:59,130 --> 00:22:05,550
+فيه ذرة كربون جديدة بينما في هذه الحالة انا بحتفظ
+
+243
+00:22:05,550 --> 00:22:11,490
+بنفس عدد الكربونات خلينا ناخد الكلام بمثال لو
+
+244
+00:22:11,490 --> 00:22:15,870
+افترضنا انه بدنا نبدأ بالاثانول و ننتقل على هذه
+
+245
+00:22:15,870 --> 00:22:22,280
+الجهةهي عندكم الاثانول CH3CH2OH
+
+246
+00:22:22,280 --> 00:22:29,120
+وقلنا بدنا نعمله oxidation مباشر بال KMnO4
+
+247
+00:22:29,120 --> 00:22:33,300
+شو هيطلع عندنا
+
+248
+00:22:33,300 --> 00:22:40,080
+ال primary alcohol oxidation CH3CW
+
+249
+00:22:40,080 --> 00:22:48,190
+bond Oحيطلع عندى acid الار الكحول هنا مكون من كام
+
+250
+00:22:48,190 --> 00:22:54,150
+carbon ال acid اللى هنا تكون مكون من كام carbon
+
+251
+00:22:54,150 --> 00:23:01,830
+مكون من two carbons طيب لو هدا إجينا حولنا بال BX3
+
+252
+00:23:01,830 --> 00:23:13,110
+ل RX يعني نفترض صار CH3 CH2 خلينا نقول CLو بعد ما
+
+253
+00:23:13,110 --> 00:23:28,330
+حولناه ل CL بدنا نفعله مع جرينيرد صار CH3CH2MgBr
+
+254
+00:23:28,330 --> 00:23:32,910
+إثل ميبروميد
+
+255
+00:23:32,910 --> 00:23:38,330
+الجرينيرد بعدين بدنا نفعله مع إيش؟
+
+256
+00:23:38,330 --> 00:23:47,750
+نمرة واحدةمع الـ CO2 و نمرة 2 H3O بلس في هذه
+
+257
+00:23:47,750 --> 00:23:53,730
+الحالة يوجد انديكاربون 2 موجودين والـ CO2 يمثل
+
+258
+00:23:53,730 --> 00:23:57,630
+الكاربون التالتة فهو يزيد انديكاربون يعني لو
+
+259
+00:23:57,630 --> 00:24:06,940
+أستخدم الألوان سيصبح CH3 و CH2 موجودينهدول موجودين
+
+260
+00:24:06,940 --> 00:24:10,840
+أصلا، الآن ثاني أكسيد الكربون، بده يجيبلي مجموعة
+
+261
+00:24:10,840 --> 00:24:20,840
+ال acid من برا، سيضة بال bond OH إذا لو أنا ابتدأت
+
+262
+00:24:20,840 --> 00:24:25,340
+بال acidic acid وعملت direct oxidation، بحصل على
+
+263
+00:24:25,340 --> 00:24:30,180
+الحامض المكون من كربون تينعفوًا لو بدأت بالإيثانول
+
+264
+00:24:30,180 --> 00:24:35,440
+بالإيثانول وعملت أكسدة مباشرة بحصل على ال acetic
+
+265
+00:24:35,440 --> 00:24:39,680
+acid على الخلق بينما لو مشيت بال green yard
+
+266
+00:24:39,680 --> 00:24:44,120
+reagent method طريقة green yard reagent قداش كان
+
+267
+00:24:44,120 --> 00:24:49,020
+عندي carbon هنا في ال alcohol او في ال RX انا بزيد
+
+268
+00:24:49,020 --> 00:24:52,580
+عليه كربونا من وين اجت الكربونا من ثانوكسيد
+
+269
+00:24:52,580 --> 00:24:58,980
+الكربون اذا هنا بدأت ال two carbons انتهيتبتلاتة
+
+270
+00:24:58,980 --> 00:25:04,400
+هنا بدأت ب two carbons انتهيت بتلتين هاي الفرق بين
+
+271
+00:25:04,400 --> 00:25:09,840
+الطريقتين صح أنا ببدأ ب alcohol بس هذا alcohol ال
+
+272
+00:25:09,840 --> 00:25:14,180
+direct oxidation بيزيدش عدد الكربون بمقدار ذرة
+
+273
+00:25:14,180 --> 00:25:18,700
+بينما لما بدي أزيد عدد الكربون بمقدار ذرة من وين
+
+274
+00:25:18,700 --> 00:25:23,380
+بدي أجيب هالذرة هذه؟في النهاية ميثانوكسيد الكربون
+
+275
+00:25:23,380 --> 00:25:26,980
+عبر اللي هي ال green yard reagent method
+
+276
+00:25:32,200 --> 00:25:40,300
+بهذا المثال سؤالك منطقي ان انا لو كنت بدي تلاتة
+
+277
+00:25:40,300 --> 00:25:48,120
+مكان بإمكاني استعمل بروبانول و اعمله oxidation هذا
+
+278
+00:25:48,120 --> 00:25:53,220
+الكلام متعلق بـ simple compounds موجودة اثانول و
+
+279
+00:25:53,220 --> 00:25:57,880
+بروبانول و ما إلى ذلكالان مش دائما في الكيميا لما
+
+280
+00:25:57,880 --> 00:26:01,740
+تكبر كل اشي موجود عندك و بتحتاجها في اماكن تانية
+
+281
+00:26:01,740 --> 00:26:05,700
+لكن في هذه المنطقة لو انا بدي اجي لطالب او ادخله
+
+282
+00:26:05,700 --> 00:26:10,580
+على المختبر و اقول حضري لي بروبانويك اسد مثلا و
+
+283
+00:26:10,580 --> 00:26:14,940
+لجت عندها ايثانول و لجت عندها بروبانولبإمكانها
+
+284
+00:26:14,940 --> 00:26:18,800
+تستعمل الاثانول بطريقة طويلة و بإمكانها تستعمل
+
+285
+00:26:18,800 --> 00:26:22,320
+البروبانول تبدأ في تلاتة و تطلع الحمض تلاتة هذا
+
+286
+00:26:22,320 --> 00:26:26,980
+لأنه موجود بس هذا بالفيش ان هذه طريقة كيميائية
+
+287
+00:26:26,980 --> 00:26:31,940
+موجودة في مركبات معينة بظروف معينة بتلزمناه واضح
+
+288
+00:26:31,940 --> 00:26:37,220
+يعني مش دائما بيكون ال starting عنده موجود و ال
+
+289
+00:26:37,220 --> 00:26:42,540
+starting عنده متوفر مش دائما ال starting موجود و
+
+290
+00:26:42,540 --> 00:26:53,040
+متوفر عندهعشان اشتغل عليه واضح
+
+291
+00:26:53,040 --> 00:26:55,280
+الفرق بين هدول الطريقتين؟
+
+292
+00:27:04,100 --> 00:27:08,860
+أخر طريقة نحن ناخدها لتحضير الـ Carboxylic Acids
+
+293
+00:27:08,860 --> 00:27:14,860
+خلّينا نقول شبيهة بطريقة Greenyard Reagent شبيهة
+
+294
+00:27:14,860 --> 00:27:19,680
+بطريقة Greenyard Reagent برضه في هذه الطريقة ..
+
+295
+00:27:19,680 --> 00:27:25,780
+برضه في هذه الطريقة ممكن أنا أبدأ بالـ ROH
+
+296
+00:27:26,800 --> 00:27:30,720
+في طريقة Greenyard بدأت بال R O H و حولتها ل R X
+
+297
+00:27:30,720 --> 00:27:37,420
+وهنا ممكن احولها ل R X وهنا كاتب R ال G طبعا اول
+
+298
+00:27:37,420 --> 00:27:43,300
+ما انتوا بتشوفوا ال G كستات ايش بيغطر ع بالكوا ال
+
+299
+00:27:43,300 --> 00:27:47,020
+washing machine الغسالة ال L G لكن هنا ال L G مش
+
+300
+00:27:47,020 --> 00:27:50,000
+غسالة ايش ال L G؟
+
+301
+00:27:53,730 --> 00:27:59,460
+لو ولا تلاجة طبعا لا غسله ولا تلاجةالـ LG is a
+
+302
+00:27:59,460 --> 00:28:03,000
+leaving group مجموعة مغادرة يعني مجموعة بتطلع
+
+303
+00:28:03,000 --> 00:28:08,240
+بسهولة وأنسب leaving group ال X يعني لو نخلها ال X
+
+304
+00:28:08,240 --> 00:28:13,680
+ر X برضه بمشي لأن ال CL أخدنا أنها بتطلع بسهولة
+
+305
+00:28:13,680 --> 00:28:17,480
+والدليل على هيك أخدنا شبتر كامل اسمه ال الكل
+
+306
+00:28:17,480 --> 00:28:20,980
+هيلايتز وقلنا ال الكل هيلايتز بيصير عليهم ال
+
+307
+00:28:20,980 --> 00:28:26,500
+substitution بشكل سهلهنا كأنه أنا مشترك في الخطوة
+
+308
+00:28:26,500 --> 00:28:31,400
+الأولى لو خدت roh مع ال bcl3 مثلا او ال bx3 بشكل
+
+309
+00:28:31,400 --> 00:28:36,140
+عام هيعطيني rx ممكن اكمله بطريقتى gradient الان ال
+
+310
+00:28:36,140 --> 00:28:43,440
+rx نفسه ممكن اجي افعله مع ال cyanide CN minus زى
+
+311
+00:28:43,440 --> 00:28:47,940
+sodium cyanide مثلا او potassium cyanide ال CN بدى
+
+312
+00:28:47,940 --> 00:28:53,960
+تيجي تهاجم هذا substitutionأسأل 1 و أسأل 2
+
+313
+00:28:53,960 --> 00:28:57,940
+substitution هذا يجب أن يتاجم وتطرد ال X بناء على
+
+314
+00:28:57,940 --> 00:29:05,020
+ذلك سيصبح لدي Rcn لاحظوا هنا أن ال R موجودة ماذا
+
+315
+00:29:05,020 --> 00:29:09,140
+زاد عليها في هذه الحالة كربونه من أين أتيت
+
+316
+00:29:09,140 --> 00:29:14,680
+الكربونه هذه من ال Cn ال Rcn لو أخدته و أعملت له
+
+317
+00:29:14,680 --> 00:29:22,200
+هيدروليسيس بمصادر أساذيكيةيعني حطيته بحامض أو كمان
+
+318
+00:29:22,200 --> 00:29:26,420
+ممكن ال basic media بس نمرة واحد بنحط OH minus
+
+319
+00:29:26,420 --> 00:29:32,260
+ونمرة اتنين H plus هيعطيل الحامض فبنقول احنا ان ال
+
+320
+00:29:32,260 --> 00:29:36,640
+cyanidecan be hydrolyzed يعني بتتمييق بالمية
+
+321
+00:29:36,640 --> 00:29:42,120
+بتتحول إلى حامض إما بإضافة كربوكسيلك أسد إما
+
+322
+00:29:42,120 --> 00:29:45,380
+بإضافة أسد زي الـ sulphuric acid مثلا أو ما إلى
+
+323
+00:29:45,380 --> 00:29:50,880
+ذلك أو بإضافة قاعدة base زي ال sodium hydroxide
+
+324
+00:29:50,880 --> 00:29:56,400
+وبعدين الفعلها مع H plus سواء مشينا زي هيك أو هيك
+
+325
+00:29:56,400 --> 00:30:02,760
+فال RCN بتتحول إلى أسد الآن هذا ال acid إيش ميزته؟
+
+326
+00:30:04,340 --> 00:30:13,460
+الو زايد كربونا واحدة عن ال RX واضح زايد كربونا
+
+327
+00:30:13,460 --> 00:30:17,500
+واحدة عن ال RX طبعا لو انا كنت معاطيكم ال RCN
+
+328
+00:30:17,500 --> 00:30:20,960
+الكربونا خلاص فيها يعني مثلا لو جيبنالكم في
+
+329
+00:30:20,960 --> 00:30:24,300
+الامتحان المعادلة القاتية قولناكم complete the
+
+330
+00:30:24,300 --> 00:30:26,920
+following equation وهذه أحيانا تجربة بيعملوها في
+
+331
+00:30:26,920 --> 00:30:33,100
+المختبر انتوا لسه مااخدتوش المختبر ولا لأ؟الكتير
+
+332
+00:30:33,100 --> 00:30:40,340
+بياخدوا بنزو
+
+333
+00:30:40,340 --> 00:30:45,120
+نيترال أو سيانو بنزين وبعدين بيفعلوا نمرة واحد مع
+
+334
+00:30:45,120 --> 00:30:48,480
+سوديوم هيدروكسيد بتاخدوا في المختبر بتاخدوا كمية
+
+335
+00:30:48,480 --> 00:30:52,560
+منه بتغلو مع سوديوم هيدروكسيد نص ساعة ساعة وبعدين
+
+336
+00:30:52,560 --> 00:30:56,600
+بتضيفوا عليه نقطة حمض شو المحصلة اللي لازم
+
+337
+00:30:56,600 --> 00:30:57,560
+تكتبوها؟
+
+338
+00:31:01,670 --> 00:31:09,950
+النيترالز هيدروليز لأسدين النيترالز CNN بتتحول
+
+339
+00:31:09,950 --> 00:31:17,650
+لأحمر سواء كان هذا الهيدروليز باسيديك ميديامأو كان
+
+340
+00:31:17,650 --> 00:31:22,390
+في basic media يعني الشغلتين موجودين .. الشغلتين
+
+341
+00:31:22,390 --> 00:31:27,110
+موجودين و ممكن يتم التفاعل فيهم أهم شيء بديكوا
+
+342
+00:31:27,110 --> 00:31:32,070
+تنتبهوله ان هذول الطريقتين مقارنة بطريقة ال
+
+343
+00:31:32,070 --> 00:31:36,870
+alcohol و ال aldehyde فيهم زيادة carbon لو كنا
+
+344
+00:31:36,870 --> 00:31:44,030
+بنبدأ من ال RX واضح؟ ال carbon في الحالة الأولى
+
+345
+00:31:44,030 --> 00:31:47,960
+إيش مصدرها؟الثانو أكسيد الكربون و في الحالة
+
+346
+00:31:47,960 --> 00:31:51,800
+التانية من وين إجت الكربون على ال R؟ من ال CN ..
+
+347
+00:31:51,800 --> 00:32:02,300
+ال C فيها C الحمد لله أنها CN مش CNN ولا cancel من
+
+348
+00:32:02,300 --> 00:32:07,120
+أمام محطة أخضرية كل هذه
+
+349
+00:32:07,120 --> 00:32:13,060
+طرق لتحضير الكربوكسيليك أسيد كم
+
+350
+00:32:13,060 --> 00:32:18,060
+طريقة؟سبعة ..الان انا مرة جبت للطلاب في الامتحان
+
+351
+00:32:18,060 --> 00:32:24,600
+حامض و قلتله محضروه ب تلات طرق معقول السؤال؟ احنا
+
+352
+00:32:24,600 --> 00:32:29,460
+معطينكوا سبعة طرق تامدوا
+
+353
+00:32:29,460 --> 00:32:35,880
+انتوا لازم كله full markلاحظوا هذه الـ slide كيف
+
+354
+00:32:35,880 --> 00:32:38,900
+الـ green yard reagent .. هذه شرحناها كيف الـ
+
+355
+00:32:38,900 --> 00:32:41,900
+green yard reagent بتفاعل مع تاني أكسيد الكربون
+
+356
+00:32:41,900 --> 00:32:46,500
+بيعطينا الايون السالف والموجب وفي حالة إضافة الـ H
+
+357
+00:32:46,500 --> 00:32:51,300
+بلس بيعطينا ال acid بتاعة دي فصلناها على الجانب
+
+358
+00:32:51,300 --> 00:32:58,480
+اللي احنا بنحكيه الآن بنجي لموضوع جديد اللي هو ال
+
+359
+00:32:58,480 --> 00:33:03,860
+reactions of carboxylic acidsreactions of
+
+360
+00:33:03,860 --> 00:33:09,800
+carboxylic acids طبعا ال carboxylic acid لما
+
+361
+00:33:09,800 --> 00:33:14,860
+بتفاعل بيعطي ال derivatives of carboxylic acids
+
+362
+00:33:14,860 --> 00:33:19,520
+اللي هي المشتقات لاحظوا هنا هتحسوا أن ال organic
+
+363
+00:33:19,520 --> 00:33:23,860
+صارت سهلة ليش؟ لأنه احنا في هذا ال chapter بدنا
+
+364
+00:33:23,860 --> 00:33:31,180
+ندرس الأحماض و بعد هيكمشتقاتها الان هيجيكوا كيف
+
+365
+00:33:31,180 --> 00:33:37,680
+بنحضر المشتقات تفاعل الحامض هو طريقة تحضير ال
+
+366
+00:33:37,680 --> 00:33:42,060
+derivative يعني لما نقول مثلا ال acid مع ال
+
+367
+00:33:42,060 --> 00:33:47,900
+thionyl chloride ال S O C L 2 بيعطيني R C O O O O
+
+368
+00:33:47,900 --> 00:33:48,520
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+369
+00:33:48,520 --> 00:33:50,220
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+370
+00:33:50,220 --> 00:33:54,200
+O O
+
+371
+00:33:54,200 --> 00:33:54,200
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+372
+00:33:54,200 --> 00:33:54,380
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+373
+00:33:54,380 --> 00:33:54,380
+O O O O O O O O O O O O O O O O O O O O O O O O O
+
+374
+00:33:54,380 --> 00:33:54,420
+O O O O O O O O O O O O O O O O O O O O O O
+
+375
+00:33:57,400 --> 00:34:03,400
+derivative الاسدكلوريد كيف بتحضر من الاسد بالتفاعل
+
+376
+00:34:03,400 --> 00:34:11,800
+مع ال SOCl2 ال Easter هو أحد مشتقات الأحماض كيف
+
+377
+00:34:11,800 --> 00:34:19,840
+بنحضره تفاعل شئ لده أن حمض زاد كحول بيعطينا Easter
+
+378
+00:34:19,840 --> 00:34:26,850
+بمعنىهذا الـ ROH يتهاجم هنا وتطرد الـ OH وهنا
+
+379
+00:34:26,850 --> 00:34:32,430
+التفاعل الأساسي هو تفاعل substitution هذا الـ ROH
+
+380
+00:34:32,430 --> 00:34:38,670
+هاجمت هنا وطلعت الـ OH فبصير عندي R سيضع بالبند O
+
+381
+00:34:38,670 --> 00:34:44,710
+ومن الكحول ايش اتجه عندي OR بلس كأن ال Easter
+
+382
+00:34:44,710 --> 00:34:51,780
+انكون من جزئين جزء جاي من الحامض و جزء جاىمن
+
+383
+00:34:51,780 --> 00:34:56,920
+الكحول هذا الجزء اللي هو جاي من إيش؟ من الحمض ال
+
+384
+00:34:56,920 --> 00:35:03,580
+acid part وهذا الجزء ال OR plus من ال alcohol okay
+
+385
+00:35:03,580 --> 00:35:09,520
+إذا تفاعل الأحماض مع الكحولات بيعطينا Easter هيصير
+
+386
+00:35:09,520 --> 00:35:18,020
+عندك طريقة لتحضير؟تفاعل الحامض مع نفسه أو مع حامض
+
+387
+00:35:18,020 --> 00:35:22,760
+آخر ضمن ظروف معينة الحامضين بيفقدوا جزء ميه
+
+388
+00:35:22,760 --> 00:35:26,460
+بيعطونا اللي بنسميه ال acid anhydride
+
+389
+00:35:31,070 --> 00:35:34,830
+مرة تانية ناخدهم بالتفصيل لما ناخد طرق التحضير بس
+
+390
+00:35:34,830 --> 00:35:39,410
+الان عشان يكون عندكم فكرة ان الحامض اذا سخنته مع
+
+391
+00:35:39,410 --> 00:35:42,430
+نفسه و سحبت الميه او سخنته مع حامض تاني و سحبت
+
+392
+00:35:42,430 --> 00:35:49,910
+الميه بيعطيني ال acid anhydride اذا
+
+393
+00:35:49,910 --> 00:35:53,070
+كأن انا من الحامض حضرت ال derivative ال acid
+
+394
+00:35:53,070 --> 00:35:58,110
+chloride ال acid anhydrideالإيستر لو فعلته مع
+
+395
+00:35:58,110 --> 00:36:03,190
+أمونيا أو أي أمين مركب فيه نيتروجين نفس الفكرة
+
+396
+00:36:03,190 --> 00:36:07,730
+برضه هيعمل ال substitution هدف اتهاجم هنا و تطرد
+
+397
+00:36:07,730 --> 00:36:13,930
+ال OH بسرعه DRC double bond O NR2 ممكن تكون NH2,
+
+398
+00:36:14,070 --> 00:36:20,490
+NHR, whatever هذا أو هذا المشتقة شو بنسميها امت
+
+399
+00:36:23,560 --> 00:36:28,200
+أمد فمن الحامض عمال حضرت ال acid chloride ال acid
+
+400
+00:36:28,200 --> 00:36:31,940
+anhydride ال aster الامد و هدولة هم الأربعة
+
+401
+00:36:31,940 --> 00:36:35,280
+derivatives اللي بدنا ندرسهم في باقية ال chapter
+
+402
+00:36:35,280 --> 00:36:40,520
+عن مشتقات الأحمض فمشتقات الحامض يعني منطق الكلام
+
+403
+00:36:40,520 --> 00:36:45,660
+ليش أنا بقول أنا مشتقات للحامض لأن أنا بحضرها من
+
+404
+00:36:45,660 --> 00:36:49,880
+الحامض التفاعل الأخير أن الحامض لو فعلناه مع base
+
+405
+00:36:49,880 --> 00:36:55,330
+بيعطينا ال salt هذا أخدناه في أول المحاضرة هذهحمض
+
+406
+00:36:55,330 --> 00:37:01,590
+وقاعدة بيعطينا هنا نفترض r-c-o-o and a plus salt
+
+407
+00:37:01,590 --> 00:37:05,890
+زائد ماء هذا اللي هو التفاعل اللي ابتدينا في
+
+408
+00:37:05,890 --> 00:37:10,270
+المحاضرة مرة علينا فكأنه التفاعلات الأساسية
+
+409
+00:37:10,270 --> 00:37:17,280
+الأربعة للحمضهي التفاعلات الأربعة اللي بنحضر من
+
+410
+00:37:17,280 --> 00:37:23,260
+خلالها مشتقات الحامض يضاف إنهم تفاعل خامس اللي هو
+
+411
+00:37:23,260 --> 00:37:30,600
+إن الحمض زائد قاعدة ملح زائد ماء وبهيك بننهي اليوم
+
+412
+00:37:30,600 --> 00:37:34,460
+المحاضرة وإن شاء الله بنتابع فيه مرات قادمة
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3633b33c23db02e7b012a9b6c4ddc60cb7d99d97
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/dfKYLYuRvyg_postprocess.srt
@@ -0,0 +1,2352 @@
+1
+00:00:06,990 --> 00:00:13,110
+اليوم ان شاء الله بدنا نبدأ الفصل التالت في مساقن
+
+2
+00:00:13,110 --> 00:00:18,870
+الكيميا الأضوية الفصل التالت بيحكي عن عائلتين من
+
+3
+00:00:18,870 --> 00:00:24,370
+المراكبات الأضوية ال alkenes المراكبات اللي فيهم
+
+4
+00:00:25,430 --> 00:00:29,470
+double bonds و ال alkynes المراكبات اللي فيهم
+
+5
+00:00:29,470 --> 00:00:35,530
+triple bonds واضح؟ هناخدهم من ناحية التسمية من
+
+6
+00:00:35,530 --> 00:00:41,370
+ناحية الخواص و من ناحية التفاعلات واضح؟ هي الأشياء
+
+7
+00:00:41,370 --> 00:00:43,970
+الأساسية اللي بدنا ندرسها في الموضوع التسمية و
+
+8
+00:00:43,970 --> 00:00:49,770
+الخواص و التفاعلات طبعا حتى إن عود نتذكر بوقعهم في
+
+9
+00:00:49,770 --> 00:00:53,430
+ال organ ال chemistryبتذكروا احنا لما اتكلمنا عن
+
+10
+00:00:53,430 --> 00:00:56,870
+ال hydrocarbons قولنا فيه ان hydrocarbons
+
+11
+00:00:56,870 --> 00:01:00,670
+saturated ب single bonds بأقصى ما يمكن من ال
+
+12
+00:01:00,670 --> 00:01:04,470
+hydrogen وفي hydrocarbons unsaturated
+
+13
+00:01:04,470 --> 00:01:08,710
+..unsaturated يعني شيلنا منهم ال hydrogen هم غير
+
+14
+00:01:08,710 --> 00:01:17,140
+مشبعين بال hydrogenومنهم ال alkenes ومنهم
+
+15
+00:01:17,140 --> 00:01:20,400
+ال alkynes اللي فيهم ال triple bond ويلهم الصيغة
+
+16
+00:01:20,400 --> 00:01:27,360
+العامة cn h2n-2 طبعا هذه الصيغة لما يكون عنده
+
+17
+00:01:27,360 --> 00:01:33,300
+رابطة زوجية واحدةأو رابطة ثلاثية واحدة بمعنى لو
+
+18
+00:01:33,300 --> 00:01:38,100
+عندك ال keen في رابطتين زوجيتين هتلاحظوا تلقائيا
+
+19
+00:01:38,100 --> 00:01:43,080
+ان صيغة العامة تبعته هتصبح cn h2n-2 يعني مقابل كل
+
+20
+00:01:43,080 --> 00:01:48,320
+رابطة إضافية انا بخصم ذرتين هيدروجين مقابل كل
+
+21
+00:01:48,320 --> 00:01:51,660
+رابطة إضافية انا بخصم ذرتين هيدروجين وسبق انا
+
+22
+00:01:51,660 --> 00:01:55,280
+قلنالكوا كمان في ال cycle ال keen ان احنا مقابل
+
+23
+00:01:55,280 --> 00:02:00,870
+تكوين كل حلقةأحنا بنخصن برضه ذرتين هيدروجين من
+
+24
+00:02:00,870 --> 00:02:07,190
+الصيغة المشفعة الآن إذا بدنا بعض المعلومات و اللي
+
+25
+00:02:07,190 --> 00:02:11,610
+بتحتوي مقارنات عن ال single bonds و ال double
+
+26
+00:02:11,610 --> 00:02:17,030
+bonds و ال triple bonds هنلاحظ القاتي بالنسبة لل
+
+27
+00:02:17,030 --> 00:02:21,910
+single bonds الجيومتر الأولين الكاربون أتون
+
+28
+00:02:22,320 --> 00:02:25,540
+الجيومتري حوالين ال carbon atom في ال single bond
+
+29
+00:02:25,540 --> 00:02:30,440
+ما زلتوا بتذكروها بهذا الشكل أربع روابط أزاوية
+
+30
+00:02:30,440 --> 00:02:36,920
+كده؟ 109.5 و الشكل حوالين ال carbon تتراهيدرال وال
+
+31
+00:02:36,920 --> 00:02:39,700
+hybridization لهذا ال carbon
+
+32
+00:02:47,500 --> 00:02:53,880
+الزاوية تبعتها حوالين الكربون 109.5 الهيبردايزيشن
+
+33
+00:02:53,880 --> 00:03:00,080
+للكربون SB3 واضح؟ والشكل تتراهي تتراهي لو بنتطلع
+
+34
+00:03:00,080 --> 00:03:04,220
+على مركب فيه double bond لو بنتطلع على مركب فيه
+
+35
+00:03:04,220 --> 00:03:08,040
+double bond هلاحظ ان حوالين الكربون المكونة من ال
+
+36
+00:03:08,040 --> 00:03:10,000
+double bond ال hybridization كان
+
+37
+00:03:17,150 --> 00:03:22,130
+الان ال double bond التفاقنة اللي مكونة من رابطتين
+
+38
+00:03:22,130 --> 00:03:27,530
+اللي هي ال sigma bond الرابطة ال head to head اللي
+
+39
+00:03:27,530 --> 00:03:32,870
+جاي بين الرأس و ال double bond اللي هي ال bi bond
+
+40
+00:03:32,870 --> 00:03:35,850
+ال second bond ال bi bond اللي بتكون above and
+
+41
+00:03:35,850 --> 00:03:42,510
+below ال sigma bond هذي بتكون عبارة عن باي bondإذا
+
+42
+00:03:42,510 --> 00:03:45,990
+الـ Double bond عبارة عن نوعين من ال bonds Sigma
+
+43
+00:03:45,990 --> 00:03:51,930
+bond أساسية و ال bi bond فوق و تحت مستوى الجزية
+
+44
+00:03:51,930 --> 00:03:58,030
+العاملة اللي هي ال electronic cloud و ال 720 لو
+
+45
+00:03:58,030 --> 00:04:05,630
+بنطلع احنا على ال alkynes ال alkynes بنلاحظ ان
+
+46
+00:04:05,630 --> 00:04:08,750
+الكاربونات اللي بيكونوا ال triple bond هنا في
+
+47
+00:04:08,750 --> 00:04:15,970
+الكاربون و هنافي carbon ال hybridization لهم Sb ال
+
+48
+00:04:15,970 --> 00:04:19,750
+hybridization للكربونز اللي بتكون ل triple bond Sb
+
+49
+00:04:19,750 --> 00:04:25,870
+طبعا بيكون عندى one sigma bond و ايه كم by bond؟
+
+50
+00:04:25,870 --> 00:04:30,070
+two by bonds فال triple bond مكونا من one sigma
+
+51
+00:04:30,070 --> 00:04:34,190
+bond و two by bonds ال by bonds وين بيكونوا
+
+52
+00:04:34,190 --> 00:04:42,670
+كالكترونات فوق و تحتفلما انتوا تتخيلوا ان انا عندى
+
+53
+00:04:42,670 --> 00:04:47,850
+four وتحت وامام وخالف صار عندى اللى بنسميه
+
+54
+00:04:47,850 --> 00:04:52,710
+cylindrical electronic cloud يعني سحابة إلكترونية
+
+55
+00:04:52,710 --> 00:04:59,130
+إستوانية زى الإستوانة واضح؟ الإلكترونات زى
+
+56
+00:04:59,130 --> 00:05:03,650
+الإستوانة بتكون محاوطة الجزء إذا هذه ال electronic
+
+57
+00:05:03,650 --> 00:05:07,470
+cloud ولو احنا رسمينا بهذا الشكل على السطورة لكن
+
+58
+00:05:07,470 --> 00:05:13,260
+هي حقيقةفوق و تحت و أمام و خلف فبنحكي عن
+
+59
+00:05:13,260 --> 00:05:19,260
+cylindrical electronic
+
+60
+00:05:19,260 --> 00:05:26,640
+cloud يعني سحابة إلكترونية إستروانية محوطة جزء من
+
+61
+00:05:26,640 --> 00:05:34,310
+كل الجهات واضح؟ الزاوية طبعا في الجزاءمية و تمانين
+
+62
+00:05:34,310 --> 00:05:38,630
+وبهذا .. وبهذا الشكل الجزء اللي فيه triple bond زي
+
+63
+00:05:38,630 --> 00:05:43,810
+ما احنا شايفينه هنا بيكون linear الجزء اللي فيه
+
+64
+00:05:43,810 --> 00:05:48,630
+triple bond بيكون linear و الجزء اللي فيه double
+
+65
+00:05:48,630 --> 00:05:53,350
+bonds بده يكون planar و حوالين كل carbon اترايجونا
+
+66
+00:05:53,350 --> 00:05:57,590
+لplanarالجزء كله في مستوى واحد لحظه لما بنحطه في
+
+67
+00:05:57,590 --> 00:06:02,330
+إيدنا الجزء في مستوى واحد بينما الجزء التتراهيدرال
+
+68
+00:06:02,330 --> 00:06:07,630
+three-dimensional كان مش في مستوى واحد واضح؟ هذا
+
+69
+00:06:07,630 --> 00:06:11,350
+الجزء three-dimensional لكن هذا بيكون في مستوى
+
+70
+00:06:11,350 --> 00:06:16,210
+واحد و اللي بعده بيكون linear هذا بالنسبة للشكل لل
+
+71
+00:06:16,210 --> 00:06:20,210
+single bond لل double bond لل triple bond الآن
+
+72
+00:06:20,210 --> 00:06:27,060
+بيجينا شغلتين قوة الرابطةوطول الرابطة، قوة الرابطة
+
+73
+00:06:27,060 --> 00:06:33,260
+وطول الرابطة ال single bond عادة هي أضعف واحدة
+
+74
+00:06:33,260 --> 00:06:37,980
+فيهمالـ single point أقف واحدة، ليش؟ لأن أنا عندي
+
+75
+00:06:37,980 --> 00:06:43,360
+سيجما، هنا الرابط أقوى، سيجما زاد عليها باي، هنا
+
+76
+00:06:43,360 --> 00:06:47,280
+الرابط أقوى و أقوى، سيجما و زاد عليها اتنين باي،
+
+77
+00:06:47,280 --> 00:06:54,260
+واضح؟ دائما الرابط القوية بتكون أقصر، واضح؟ عشان
+
+78
+00:06:54,260 --> 00:06:57,160
+هيك لما نقدر نتطلع على طول الروابط في الـ
+
+79
+00:06:57,160 --> 00:06:57,900
+picometer
+
+80
+00:07:02,680 --> 00:07:06,600
+طلع طول الموابط بالبيكوميتر بالمتوسط ال single
+
+81
+00:07:06,600 --> 00:07:12,540
+bond بتكون 154 بيكوميتر ال double bond بتكون 134
+
+82
+00:07:12,540 --> 00:07:19,780
+بيكوميتر ال triple bond بتكون 121 بيكوميتر إذن
+
+83
+00:07:19,780 --> 00:07:25,920
+أنية الأقصر ال triple bond واضح؟ أنية الأطول ال
+
+84
+00:07:25,920 --> 00:07:30,820
+single bond إذن بنقدر إحنا نقول إن ال triple bond
+
+85
+00:07:30,820 --> 00:07:40,790
+هيshortest and strongest وبنفس الوقت strongest هي
+
+86
+00:07:40,790 --> 00:07:46,390
+الأقصر والأقوى هي الأقصر والأقوى الآن لما بدنا نجي
+
+87
+00:07:46,390 --> 00:07:50,670
+بالعكس على ال single point إيش هنقول طولة longest
+
+88
+00:07:50,670 --> 00:07:57,810
+and weakest واضح؟ هذه الأطول والاطا فديك الأقصر
+
+89
+00:07:57,810 --> 00:08:04,040
+والأقوى واضح؟هذا الكلام بيتبعوا شغلة بيتبعوا شغلة
+
+90
+00:08:04,040 --> 00:08:08,320
+أنه أنا لو كان عندي جزء في single bond لو كان عندي
+
+91
+00:08:08,320 --> 00:08:12,720
+جزء و هذا الجزء في single bond و أخدناه في ال
+
+92
+00:08:12,720 --> 00:08:16,940
+conformations في إمكانية rotation و دوران حوالي ال
+
+93
+00:08:16,940 --> 00:08:22,260
+single bond ملاحظين؟ في عندي إمكانية للدوران حوالي
+
+94
+00:08:22,260 --> 00:08:28,090
+ال single bond لأنها رابطة ضعيفةالان لو صار عندى
+
+95
+00:08:28,090 --> 00:08:32,450
+ال triple bond ال rotation بصير restricted ممنوع
+
+96
+00:08:32,450 --> 00:08:39,330
+لو جربنا نمسك جزء زى هذا بدنا نلفهمستحيل، واضح؟
+
+97
+00:08:39,330 --> 00:08:42,590
+الرابط أصبحت أقوى، لو بدأتش أحكي rotation حوالين
+
+98
+00:08:42,590 --> 00:08:47,450
+ال triple bond، برضه مستحيل، إذا ال rotation أو
+
+99
+00:08:47,450 --> 00:08:52,630
+الدوران يكون حول الرابط الوحدية possible،
+
+100
+00:08:52,630 --> 00:08:58,370
+restricted around or about double bond و triple
+
+101
+00:08:58,370 --> 00:09:02,260
+bond، واضح؟الشكل زي ما قولنا هنا تتراهيدرال
+
+102
+00:09:02,260 --> 00:09:06,060
+تراهيدرال البلانر ومعناه Linear ال hybridization
+
+103
+00:09:06,060 --> 00:09:11,560
+حكينا عندنا هنا SB3 وحكينا عندنا SB2 وحكينا عندنا
+
+104
+00:09:11,560 --> 00:09:17,780
+SB تقريبا هذه كلها معلومات تلخيصية مقارنة بدكم
+
+105
+00:09:17,780 --> 00:09:21,880
+تهتموا فيها يعني لو طالب منكم بده تعمل quiz بأسئلة
+
+106
+00:09:21,880 --> 00:09:22,600
+صح و غلط
+
+107
+00:09:27,010 --> 00:09:30,430
+مقارنات أنه أقول أنه أصغر، إيش نوع الـ Geometry،
+
+108
+00:09:30,430 --> 00:09:32,630
+إيش نوع ال hybridization، واضح؟
+
+109
+00:09:56,120 --> 00:10:03,310
+الان السؤال كيف بنسمي الالكينز والالكاينز؟تقريباً
+
+110
+00:10:03,310 --> 00:10:08,010
+المبدأ العام في التسمية شبيه لتسمية ال الكنز لكن
+
+111
+00:10:08,010 --> 00:10:13,830
+في حالة ال الكنز كان الجزء بينتهي بالنهاية A and E
+
+112
+00:10:13,830 --> 00:10:19,310
+الكنب، أوبين، بيوتين، هكسير، الاتدر .. في ال
+
+113
+00:10:19,310 --> 00:10:23,710
+double bond بيصير الجزء ينتهي بالنهاية T فالنهاية
+
+114
+00:10:23,710 --> 00:10:29,670
+E النهاتي معناها جزء في double bond بعد شوية حين
+
+115
+00:10:29,670 --> 00:10:36,550
+اتعلم لو كان فيه تنتين double bondبدو يصير دايين و
+
+116
+00:10:36,550 --> 00:10:40,690
+لو في تلاتة double bolts تترايين فالإن معناها
+
+117
+00:10:40,690 --> 00:10:46,730
+double bolt إذا كانوا تنتين، دايين، تلاتة، تتراين،
+
+118
+00:10:46,730 --> 00:10:53,810
+أربعة، تتراين و هكذا و إذا كان عند ال kind يعني في
+
+119
+00:10:53,810 --> 00:10:57,010
+triple bolt بحط النهاية I
+
+120
+00:10:59,830 --> 00:11:03,810
+النهاية I بتعبر عن جزئة triple bond إذا انتوا ممكن
+
+121
+00:11:03,810 --> 00:11:12,490
+تشوفوا هكسين وهكسين وهكساي الهكسين single bonds
+
+122
+00:11:12,490 --> 00:11:19,510
+الهكسين double bond الهكساي triple bond لما بنجي
+
+123
+00:11:19,510 --> 00:11:23,530
+بنسمي بنبحث مرة تانية عن أطول سلسلة
+
+124
+00:11:29,040 --> 00:11:33,580
+هذه السلسلة يجب أن تحتوي .. مرة تانية .. يجب أن
+
+125
+00:11:33,580 --> 00:11:39,920
+تحتوي على اللي هو ال double bond او ال triple bond
+
+126
+00:11:39,920 --> 00:11:45,560
+يعني لو بدكم تتطلعوا مثلا على هذا الجزء ممكن
+
+127
+00:11:45,560 --> 00:11:49,800
+تشوفوا ان هاي سلسلة واحد اتنين تلاتة اربعة خمسة
+
+128
+00:11:49,800 --> 00:11:53,840
+ستة و ال double bond جزء منها ال double bond مش
+
+129
+00:11:53,840 --> 00:11:55,040
+بطرف واحد
+
+130
+00:11:58,570 --> 00:12:02,630
+لكن لو أخدت السلسلة منها ان واحد اتنين تلاتة اربع
+
+131
+00:12:02,630 --> 00:12:07,530
+خمسة ستة سابعة تمانية اتنين اتنين اتنين اتنين
+
+132
+00:12:07,530 --> 00:12:07,770
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+133
+00:12:07,770 --> 00:12:08,910
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+134
+00:12:08,910 --> 00:12:08,970
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+135
+00:12:08,970 --> 00:12:12,690
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+136
+00:12:12,690 --> 00:12:15,570
+اتنين اتنين اتنين اتنين اتنين اتنين اتنين اتنين
+
+137
+00:12:15,570 --> 00:12:27,690
+اتنين اتنين
+
+138
+00:12:30,410 --> 00:12:34,810
+لما بعمل الترقيم، الترقيم لازم يمول أسرع ما يمكن
+
+139
+00:12:34,810 --> 00:12:40,810
+بال double point أو بال triple point بالظبط أقرب
+
+140
+00:12:40,810 --> 00:12:45,010
+ما يمكن في الترقيم طيب، لما بدي أحدد موقعها، هل
+
+141
+00:12:45,010 --> 00:12:52,450
+بنحدد موقعها بإعطاء رقم 1 ولا 2؟ بنعطي بس رقم
+
+142
+00:12:52,450 --> 00:12:57,680
+البداية تبعهايعني هذه الرابطة جاية بين ذرة واحد و
+
+143
+00:12:57,680 --> 00:13:02,200
+اتنين لكن انا لما بدأش اسمي بس بقول one عشان هي
+
+144
+00:13:02,200 --> 00:13:05,900
+كان الاسم بدون ما ناخد هذه نعتبرها substituent من
+
+145
+00:13:05,900 --> 00:13:09,480
+ذرة تلتين تلاتة ال substituent اللي من تلت ذرات شو
+
+146
+00:13:09,480 --> 00:13:16,530
+اسمها? proble كمجموعة فهذا two probleلاحظوا one
+
+147
+00:13:16,530 --> 00:13:21,630
+hexyl إيش معناه one hexyl؟ إنه رابطة الزوجية تبتدأ
+
+148
+00:13:21,630 --> 00:13:26,030
+من نقطة واحد بحطش نقطة البداية و النهاية تعتها بس
+
+149
+00:13:26,030 --> 00:13:30,250
+بحدد نقطة البداية أكيد بتكون هي من واحد رايحة
+
+150
+00:13:30,250 --> 00:13:35,050
+لإتنين لو كنت مثلا بد المركب two hexyl وين هتكون
+
+151
+00:13:35,050 --> 00:13:36,370
+الرابطة الزوجية؟
+
+152
+00:13:40,710 --> 00:13:49,610
+تماما لو جت ال رابط الزوجية هتتغير السلسلة كذلك
+
+153
+00:13:49,610 --> 00:13:54,070
+لو بدنا نشوف مثلا هذا المركب نحاول نسميه مع بعض
+
+154
+00:13:54,070 --> 00:13:58,710
+هتلاحظوا فيه عندنا هاي سلسلة واحد اتنين تلاتة
+
+155
+00:13:58,710 --> 00:14:02,490
+اربعة خمسة واحد اتنين تلاتة اربعة خمسة
+
+156
+00:14:06,580 --> 00:14:11,080
+وحاولات أطول سلسلة تحتوي على ال double bond واحد
+
+157
+00:14:11,080 --> 00:14:15,120
+اتنين تلاتة اربعة خمسة لاحظوا بدنا الترقيم من هذه
+
+158
+00:14:15,120 --> 00:14:20,300
+الجهة لأن بداية ال double bond هنا بتكون على رقم
+
+159
+00:14:20,300 --> 00:14:25,900
+اتنين لو بدت الترقيم من هنا تكون على رقم تلاتة
+
+160
+00:14:25,900 --> 00:14:29,300
+اتنين تلاتة بتكون على رقم تلاتة ان هو الأنسب اتنين
+
+161
+00:14:29,300 --> 00:14:34,690
+بتكون على رقم اتنين عشان هذا المركب two بانتينهذا
+
+162
+00:14:34,690 --> 00:14:38,370
+الأساس فيه two بنتين بعدين ال substituents بنذكرهم
+
+163
+00:14:38,370 --> 00:14:41,930
+بالطريقة اللي اتعلمناها السابقة عندنا pro و عندنا
+
+164
+00:14:41,930 --> 00:14:46,610
+مثل مين alphabetical في الأول ال pro كده هذا
+
+165
+00:14:46,610 --> 00:14:54,250
+المركب four promo two مثل two بنتين four promo two
+
+166
+00:14:54,250 --> 00:15:00,310
+مثل two بنتين الكلام نفسه بتم لو كان في عندنا ال
+
+167
+00:15:00,310 --> 00:15:05,960
+kinds بس بتصير النهايةيعني لو هذا المركب بدي أحط
+
+168
+00:15:05,960 --> 00:15:11,020
+هنا كمان point، بدي يكون بنفس الاسم، بنفس الاسم،
+
+169
+00:15:11,020 --> 00:15:15,420
+ما عدا نمتين، one head side، بحبتش فيه substitute
+
+170
+00:15:15,420 --> 00:15:22,040
+once و بتصير I أو .. و بنشوف ال cuisineالآن في
+
+171
+00:15:22,040 --> 00:15:26,580
+الـAlkenes تحديدًا بتيجينا ظاهرة جديدة، ظاهرة
+
+172
+00:15:26,580 --> 00:15:32,800
+متشكلات فراغية، ظاهرة متشكلات فراغية، وبيجيني كمان
+
+173
+00:15:32,800 --> 00:15:36,580
+للـAlkenes مجموعات، بتعرفوا أنتوا لما أخدنا
+
+174
+00:15:36,580 --> 00:15:40,800
+الـAlkenes، قلنا ميثين، منه مجموعة؟ الـMethane
+
+175
+00:15:40,800 --> 00:15:43,360
+الـMethane، الـEthane منه مجموعة؟ الـEthane
+
+176
+00:15:43,360 --> 00:15:46,500
+الـEthane، البروبين منه مجموعة؟ البروبين البروبين،
+
+177
+00:15:46,500 --> 00:15:50,580
+طيب، يا ترى الـAlkenes مافيش منها مجموعات؟في منها
+
+178
+00:15:50,580 --> 00:15:55,660
+مجموعات لو أخدت الـ Ethane وإله ال common name
+
+179
+00:15:55,660 --> 00:16:00,760
+إيثيلين واضح؟ هو إيثين و ال common name إله
+
+180
+00:16:00,760 --> 00:16:06,580
+إيثيلين وشلت منه هيدروجين واحدة ذرة هيدروجين واحدة
+
+181
+00:16:06,580 --> 00:16:10,020
+صار هذا الجزء اللي ضاير كله عبارة عن مجموعة
+
+182
+00:16:10,020 --> 00:16:14,940
+المجموعة دائما هي الجزء ماقص الـ hydrogen هذه
+
+183
+00:16:14,940 --> 00:16:19,580
+المجموعة شو بيسموها؟ بيسموها مجموعة الـ VinylVinyl
+
+184
+00:16:19,580 --> 00:16:25,420
+بال V مش بال F ما تقولوش Vinyl لأن Vinyl مجموعة
+
+185
+00:16:25,420 --> 00:16:30,500
+تانية هي عبارة عن حلقة البنزين هذه لما تكون موجودة
+
+186
+00:16:30,500 --> 00:16:36,660
+كمجموعة بنسميها ال Vinyl فباللفظ بدي أسمح حرف ال V
+
+187
+00:16:36,660 --> 00:16:43,780
+Vinyl مش Vinyl Vinyl هذه مجموعة ال Vinyl واضح؟ فلو
+
+188
+00:16:43,780 --> 00:16:48,180
+حطيت أنا هنا Chlor إيش بيصير اسم الجزية بركوبه
+
+189
+00:16:48,180 --> 00:16:53,140
+name؟فنل اكلورايد الان لو كنت بتسميه بال IUPAC
+
+190
+00:16:53,140 --> 00:16:59,880
+Nomenclature اكلورو
+
+191
+00:16:59,880 --> 00:17:06,120
+ايثين اكلورو ايثين بالظبط بنحطله رقم لموقع الكلورو
+
+192
+00:17:06,120 --> 00:17:09,480
+ولا لموقع ال double bond؟ لأ لإن مافيش الاحتمال
+
+193
+00:17:09,480 --> 00:17:13,580
+واحد، مافيش الاحتمال واحد، واضح؟ اذا هذا بال
+
+194
+00:17:13,580 --> 00:17:17,780
+common name فنل اكلورايد بال IUPAC name اكلورو
+
+195
+00:17:17,780 --> 00:17:23,820
+ايثينالآن لو أخدت جزء لبروبيلين واللي إلكم و النام
+
+196
+00:17:23,820 --> 00:17:30,620
+بروبيلين وخصمت هيدروجين من هذا الـCH3 اللي هنا
+
+197
+00:17:30,620 --> 00:17:36,780
+بيعطيني مجموعة بهذا الشكل هاي الجزء ناقص one
+
+198
+00:17:36,780 --> 00:17:41,560
+hydrogen atom بيعطيني مجموعة ممكن هذه تتصل مع كلور
+
+199
+00:17:41,560 --> 00:17:45,920
+مع بنزين مع أي شيء يعني كل هذه تعامل كمجموعة CH2
+
+200
+00:17:46,940 --> 00:17:49,920
+الـ 0.CH2 وهذه مجموعة في الـ organic chemistry لها
+
+201
+00:17:49,920 --> 00:17:58,720
+اسم، شو بنسميها؟ ألل، ألل، واضح؟ بنسميها ألل، و لو
+
+202
+00:17:58,720 --> 00:18:02,200
+كانت متصلة بالكلور، شو بتصير؟ ألل الكلورايد، ألل
+
+203
+00:18:02,200 --> 00:18:06,420
+الكلورايد، لو متصلة بالـ OH مثلا، الـ OH المجموعة
+
+204
+00:18:06,420 --> 00:18:09,520
+اللي واقف فيها للكحول، بيصير ألل الكحول
+
+205
+00:18:15,200 --> 00:18:20,460
+ال CR بتصير OH، لو هذه OH بيصير عندك قلل الكهول،
+
+206
+00:18:20,460 --> 00:18:25,760
+واضح؟ القلل هذه كتسمية من الناحية خلينا نقول
+
+207
+00:18:25,760 --> 00:18:29,580
+التاريخية جاية من عائلة نباتية بيسموها عائلة
+
+208
+00:18:29,580 --> 00:18:36,220
+الاليوم، والاليوم هي العائلة تبعت الطومةالـ Garlic
+
+209
+00:18:36,220 --> 00:18:41,880
+ليش؟ لأن الطومة من مكوناتها بتكون مجموعة الألل هذه
+
+210
+00:18:41,880 --> 00:18:47,140
+مع ذرّة كابريت وذرّة كابريت وألل تانية داي ألل داي
+
+211
+00:18:47,140 --> 00:18:50,500
+سالفايت هذا مُركّب أساسي في الطومة، لكن وجود
+
+212
+00:18:50,500 --> 00:18:53,660
+الكابريت في الطومة هو اللي بيطلّع الرائحة السيئة
+
+213
+00:18:53,660 --> 00:18:58,320
+إلها، تعرفوا الكابريت دائما مرتبط بإيش؟ بالرائحة
+
+214
+00:18:58,320 --> 00:19:01,480
+السيئة، السيئة، فلأن العائلة النباتية كلها تحت
+
+215
+00:19:01,480 --> 00:19:07,710
+الطومة الاليوم منها إجتكلمة القليل جروب كتسمية طيب
+
+216
+00:19:07,710 --> 00:19:10,870
+هذا القليل الكلورايد لو بدنا واحدة بنكون سامينا
+
+217
+00:19:10,870 --> 00:19:19,610
+إياه بال Iopac Nomenclature أمين
+
+218
+00:19:19,610 --> 00:19:27,630
+اجتهد فضلي لأ
+
+219
+00:19:27,630 --> 00:19:34,800
+ليش؟لأن أولوية الترقيم البداية بتاعتها عند ال
+
+220
+00:19:34,800 --> 00:19:40,360
+double bot انا هنا بقدر اخل ال double bot تمثل
+
+221
+00:19:40,360 --> 00:19:45,420
+نقطة واحد بدايتها و لو بترقمها ابتدت تكون اتنين
+
+222
+00:19:45,420 --> 00:19:50,900
+فالاصل الترقيم اللى عندى يكون واحد اتنين تلاتة
+
+223
+00:19:50,900 --> 00:19:58,000
+فهذا لما انا بدى اسميه الآن three chloro
+
+224
+00:20:00,490 --> 00:20:05,670
+one ibropine دايما احنا بقولنا الاولوية في إعطاء
+
+225
+00:20:05,670 --> 00:20:09,910
+الأرقام لإيش الاولوية في إعطاء الأرقام للطابق
+
+226
+00:20:09,910 --> 00:20:13,350
+الجدران مش لل substitute in another three chloro
+
+227
+00:20:13,350 --> 00:20:15,210
+one ibropine
+
+228
+00:20:25,140 --> 00:20:30,420
+طبعا بعد البروبين لو بدي أجي لجزء اللي بعد اللي
+
+229
+00:20:30,420 --> 00:20:35,920
+بقى أربع ذرات كربون هلاحظ أنه هيصير أمامي ظاهرة
+
+230
+00:20:35,920 --> 00:20:40,780
+جديدة أنه أنا لما يصير عندي أربع ذرات كربون ال
+
+231
+00:20:40,780 --> 00:20:45,060
+double bond ممكن أحطها بين واحد واتنين وممكن أحطها
+
+232
+00:20:45,060 --> 00:20:49,690
+بين اتنين وتلاتةواضح؟ لو حطيت ال double bolt بين
+
+233
+00:20:49,690 --> 00:20:53,290
+الذرة واحد و اتنين بيصير الجزء اسم واحد اتنين
+
+234
+00:20:53,290 --> 00:20:59,550
+تلاتة اربعة و هي نقطة البداية what a beauty طب
+
+235
+00:20:59,550 --> 00:21:03,210
+ممكن احط ال double bolt هنا بين الذرة اتنين و
+
+236
+00:21:03,210 --> 00:21:09,230
+تلاتة ممكن احط ال clone بين الذرة اتنين و تلاتة
+
+237
+00:21:09,230 --> 00:21:16,860
+لما اجي حقيقة اطبق هذا الكلاملما نطبق هذا الكلام و
+
+238
+00:21:16,860 --> 00:21:20,220
+نتخيل أنه عندنا البيوتين، معناه البيوتين أنه عندي
+
+239
+00:21:20,220 --> 00:21:24,200
+كام ذرّة carbon؟ أربعة أو هيني بتحط بين اتنين و
+
+240
+00:21:24,200 --> 00:21:29,590
+تلاتة، هذه الذرات السمرة، ذرات ال carbonهي واحد،
+
+241
+00:21:29,590 --> 00:21:34,370
+اتنين، تلاتة، اربعة، وهي الـ Double bond هدولة
+
+242
+00:21:34,370 --> 00:21:39,030
+عبارة عن مجموعتين CH3 حاملين Hydrogens، مظبوط ولا
+
+243
+00:21:39,030 --> 00:21:44,430
+لا؟ okay الأن بلاحظ و أنا بعمل الجزء أنه بإمكاني
+
+244
+00:21:44,430 --> 00:21:50,510
+أخلي مجموعتين الـCH3 على جهة واحدة اه و ممكن أخلي
+
+245
+00:21:50,510 --> 00:21:57,140
+مجموعتين الـCH3 على جهتين متعاكستينبلاحظين كيف
+
+246
+00:21:57,140 --> 00:22:02,300
+الجزير مجموعتين الـCH3 ممكن يكونوا على جهة واحدة
+
+247
+00:22:02,300 --> 00:22:08,140
+وممكن يكونوا على جهتين متعاكستين إذا الـ2 بيوتين
+
+248
+00:22:08,140 --> 00:22:12,860
+مش مُركّب واحد عبارة عن مُركّبين، عبارة عن
+
+249
+00:22:12,860 --> 00:22:16,560
+مُركّبين يا بيكون الـmythic groups at the same
+
+250
+00:22:16,560 --> 00:22:21,500
+side وبالتالي بيقول إن مُركّب الـNDCS 2 بيوتين يا
+
+251
+00:22:21,500 --> 00:22:25,260
+بيكونوا على جهتين متعاكستين
+
+252
+00:22:29,210 --> 00:22:34,430
+إذا من الأربع ذرات كربون اللى ورا بعض لتشيل كان
+
+253
+00:22:34,430 --> 00:22:40,050
+بإمكانه يكون عندى one butane أو cis to butane أو
+
+254
+00:22:40,050 --> 00:22:43,630
+trans to butane طب واحدة بتقول هو ال cis مابصيرش
+
+255
+00:22:43,630 --> 00:22:48,890
+ال transالجواب لأ، ليش مابصيرش Trans؟ لإن الدوران
+
+256
+00:22:48,890 --> 00:22:53,230
+ممنوح حول الرابطة الزوجية، عشانك لما بتحول السسلة
+
+257
+00:22:53,230 --> 00:22:59,170
+ل Trans، هل يا ترد بال rotation بمشي؟ تطلع علي، هي
+
+258
+00:22:59,170 --> 00:23:02,510
+اللي بحول بال rotation، ظابط؟ لأ، طب كيف السس
+
+259
+00:23:02,510 --> 00:23:05,950
+بيصير Trans؟ لازم أكسر هذه الرابطة، أكسر هذه
+
+260
+00:23:05,950 --> 00:23:10,560
+الرابطة، و أكوّن روابط من أول و جديدإذا هذا مُركّب
+
+261
+00:23:10,560 --> 00:23:14,920
+و هذا مُركّب بخلاص فيزيائية مختلفة ولذلك لو واحدة
+
+262
+00:23:14,920 --> 00:23:19,360
+منكم بدأت تشتري مُركّب اسمه two-butane و بتروح على
+
+263
+00:23:19,360 --> 00:23:21,940
+مخزن الكيميائيات وبتقولوا بدي two-butane بقولها
+
+264
+00:23:21,940 --> 00:23:26,060
+مافيش مُركّب في الدنيا اسمه two-butane فيه cis two
+
+265
+00:23:26,060 --> 00:23:32,080
+-butane أو trans two-butane واضح؟ فيه cis two
+
+266
+00:23:32,080 --> 00:23:38,130
+-butane أو trans two-butane لكن مافيش ..مركب اسمه
+
+267
+00:23:38,130 --> 00:23:41,890
+two butane زي ما واحدة بيجيها ولد، بيقوله اجهبني
+
+268
+00:23:41,890 --> 00:23:45,730
+ادم، بينفعش اجهبني ادم، يا ولد، يا بنت، يا بنت، يا
+
+269
+00:23:45,730 --> 00:23:49,050
+بنت،
+
+270
+00:23:49,050 --> 00:23:49,590
+بنت، يا بنت، يا بنت، يا بنت، يا بنت، يا بنت، يا
+
+271
+00:23:49,590 --> 00:23:49,610
+بنت، يا بنت، يا بنت، يا بنت، يا بنت، يا بنت، يا
+
+272
+00:23:49,610 --> 00:23:56,070
+بنت، يا بنت، يا بنت، يا بنت،
+
+273
+00:24:06,030 --> 00:24:11,650
+أربع ذرّات كربون و تكون إيش مالها؟ تكون متفرعة
+
+274
+00:24:11,650 --> 00:24:16,790
+براشد، بهاد الحالة لو كنت بدأ أعمل double bond على
+
+275
+00:24:16,790 --> 00:24:22,570
+جهة ما منها، هحصل على مركب رابع من أربع ذرّات
+
+276
+00:24:22,570 --> 00:24:28,930
+كربون، بيكون اسمه isobutene بال common nucleation
+
+277
+00:24:28,930 --> 00:24:34,650
+لأنه و هو كله single bonds، شو سمناه المركب؟
+
+278
+00:24:37,650 --> 00:24:43,490
+Isobutane لما كان كله single bonds لما بنعمل
+
+279
+00:24:43,490 --> 00:24:46,630
+double bond طبعا نعملها على هذا الموقع زي هذا زي
+
+280
+00:24:46,630 --> 00:24:52,010
+هذا بدي يصير Isobutane طب لو كنا بدنا نسميه في ال
+
+281
+00:24:52,010 --> 00:24:55,630
+-iobaconomenclature بده أشوف أين أطول سلسلة تحتوي
+
+282
+00:24:55,630 --> 00:25:00,720
+على1,2,3 إذا one of propane و هذا ال one of
+
+283
+00:25:00,720 --> 00:25:05,700
+propane على موقع اتنين إيش حامل مثل إذا لو بدنا
+
+284
+00:25:05,700 --> 00:25:10,740
+نجيبلكوا سؤال صح و غلط هنقولكوا isobutene is also
+
+285
+00:25:10,740 --> 00:25:16,340
+called two methyl one of propane مظلوم ال
+
+286
+00:25:16,340 --> 00:25:22,660
+isobutene is two methyl one of propane واضح؟ الآن
+
+287
+00:25:22,660 --> 00:25:27,970
+ممكن واحدة تيجي تسأل سؤالتقول يا تورا، ليش أنا صار
+
+288
+00:25:27,970 --> 00:25:31,890
+عند ظاهرة cis و trans في الـ2 بيوتين، حوالين
+
+289
+00:25:31,890 --> 00:25:36,130
+الـdouble bond؟ طب هي أنا في الـ1 بيوتين، عند
+
+290
+00:25:36,130 --> 00:25:41,710
+double bond، هل هذا منه cis و trans؟ في الـisو
+
+291
+00:25:41,710 --> 00:25:47,570
+بيوتين، عند double bond، هل منه cis و trans؟ واضح؟
+
+292
+00:25:47,570 --> 00:25:50,890
+إذا السؤال كأنه بالظبط ورتيش بيكون
+
+293
+00:25:55,200 --> 00:25:59,500
+وبقتاش بيكون من المُركّب اتنين ووبقتاش لأ مابيكونش
+
+294
+00:25:59,500 --> 00:26:03,660
+من المُركّب اتنين ضالة الـ Sexual Trans ابتدوا
+
+295
+00:26:03,660 --> 00:26:08,620
+يوجد إذا كان حوالين الطرفين تعون الـ double bond
+
+296
+00:26:08,620 --> 00:26:12,940
+كل double bond عبارة عن كام طرف طرفين high carbon
+
+297
+00:26:12,940 --> 00:26:17,300
+وhigh carbon هنا high carbon وhigh carbon هنا high
+
+298
+00:26:17,300 --> 00:26:20,300
+carbon high carbon high carbon high carbon لازم
+
+299
+00:26:20,300 --> 00:26:24,280
+حوالين كل طرف من ال double bond يكون عنده مجموعتين
+
+300
+00:26:24,280 --> 00:26:30,810
+مختلفةلاحظوا هنا هذا الطرف شو عليه؟ هيدروجين
+
+301
+00:26:30,810 --> 00:26:35,550
+وهيدروجين طالما هدولا المجموعتين زي بعض إذا مافيش
+
+302
+00:26:35,550 --> 00:26:40,090
+عندى طارد السيسوناترانس مافيش من المركب إلا واحد،
+
+303
+00:26:40,090 --> 00:26:43,990
+هنا مظبوط في عندى هيدروجين ومجموعة تانية، هذه
+
+304
+00:26:43,990 --> 00:26:48,250
+الكربون حولها مجموعتين مختلفتين، بس هذه الكربون
+
+305
+00:26:48,250 --> 00:26:50,250
+حولها نفس
+
+306
+00:26:58,830 --> 00:27:03,010
+أتشو مثل، إذا المجمعتين مختلفتين، هي الكلام، هذا
+
+307
+00:27:03,010 --> 00:27:07,890
+ال carbon، شو حولها؟ أتشو مثل، إذا هذا الجزء فيه
+
+308
+00:27:07,890 --> 00:27:12,490
+نضمنه مُركّب تاني، كيف برسم المُركّب التاني؟ بثبت
+
+309
+00:27:12,490 --> 00:27:16,670
+كل الجزء، كإن في الناسخ و اللاصق، بنسخ و بحطه هنا،
+
+310
+00:27:16,670 --> 00:27:21,870
+بخلي الجهة ثابتة و بعكس الجهة التانيةيعني لما أكون
+
+311
+00:27:21,870 --> 00:27:25,370
+راسم هذا الجزء أقولكوا ارسمولي ال ISO مرة تانية
+
+312
+00:27:25,370 --> 00:27:30,770
+ابتخدوا انتوا زي نسخ بتحطوها هنا هذا بتثبت جهة
+
+313
+00:27:30,770 --> 00:27:35,690
+بتعكس الجهة التانية بصير عندكوا ال ISO مرة تانية
+
+314
+00:27:35,690 --> 00:27:41,850
+لاحظوا هنا هذا في منه مركب ولا اتنين ال ISO butane
+
+315
+00:27:41,850 --> 00:27:47,590
+هذا ال carbon شو حواليها أكترات زي بعض و هذا ال
+
+316
+00:27:47,590 --> 00:27:53,290
+carbon مثل و مثل برضه زي بعضوالـ Trans كظاهرة
+
+317
+00:27:53,290 --> 00:27:58,850
+وحوالين كل Carbon مجموعتين مختلفة واضح؟ فهذه
+
+318
+00:27:58,850 --> 00:28:06,130
+الحالة بيكون من المركب اتنين واحد Ses واحد Trans
+
+319
+00:28:06,130 --> 00:28:09,170
+واضح؟
+
+320
+00:28:09,170 --> 00:28:20,730
+طيب بيجينا سؤال جديد بيجينا
+
+321
+00:28:20,730 --> 00:28:27,280
+سؤال جديدلو يا تورا اذا مركب من المركبات كان عندى
+
+322
+00:28:27,280 --> 00:28:32,680
+double bond و triple bond مركب ايش بيحتوي على
+
+323
+00:28:32,680 --> 00:28:37,860
+double bond و triple bond كيف بدى اسمى هذا المركب
+
+324
+00:28:37,860 --> 00:28:40,580
+اللى فيه double bond و triple bond يعني two
+
+325
+00:28:40,580 --> 00:28:45,580
+functional groups هل يا تورا بدى اعتبره
+
+326
+00:28:54,450 --> 00:29:00,810
+الجواب بالشكل القاتل لو عندى double bond و triple
+
+327
+00:29:00,810 --> 00:29:09,250
+bond بنبدأ الترقيم من الجهة اللى بتكون اقربلأ
+
+328
+00:29:09,250 --> 00:29:13,110
+الرابطة، بغض النظر كانت ثلاثية أو ثنائية، يعني
+
+329
+00:29:13,110 --> 00:29:17,550
+بجرب أرقم عن اليمين، بجرب أرقم عن الشمال، وين
+
+330
+00:29:17,550 --> 00:29:23,190
+الترقيم بيجي أسرع ما يمكن على double bond أو
+
+331
+00:29:23,190 --> 00:29:26,070
+triple bond بتكون الأولوية الترقيم بهذا الاتجاه،
+
+332
+00:29:26,070 --> 00:29:31,660
+يعني لو طلعنا هنا على هذاالجزاء اللى موجود فوق ..
+
+333
+00:29:31,660 --> 00:29:35,160
+الجزاء اللى موجود فوق و انا متحير هى فى double
+
+334
+00:29:35,160 --> 00:29:40,040
+bond او triple bond مظبوط ولا لأ من وين بدى ابدأ
+
+335
+00:29:40,040 --> 00:29:45,840
+ارقم .. من وين بدأ ابدأ ارقم بجرب هنا واحدفلحظة
+
+336
+00:29:45,840 --> 00:29:50,260
+اتنين مريت على multiple bond بغض النظر شو هي الان
+
+337
+00:29:50,260 --> 00:29:53,700
+لو رقمت منها واحد اتنين تلاتة تلاتة تلاتة تلاتة
+
+338
+00:29:53,700 --> 00:29:56,040
+تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة
+
+339
+00:29:56,040 --> 00:29:56,240
+تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة
+
+340
+00:29:56,240 --> 00:29:58,780
+تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة تلاتة
+
+341
+00:29:58,780 --> 00:30:07,900
+تلاتة
+
+342
+00:30:07,900 --> 00:30:14,780
+تلاتة
+
+343
+00:30:14,780 --> 00:30:22,420
+تالان بعد ما حطيت الترقيم دائما باذكر .. دائما
+
+344
+00:30:22,420 --> 00:30:30,130
+باذكر من ناحية كتابية ال E قبل ال Iفى كل الحالات
+
+345
+00:30:30,130 --> 00:30:35,770
+دائما ال اين بتذكر قبل الاين فالمشكلة عندى حقيقة
+
+346
+00:30:35,770 --> 00:30:39,550
+مش مين اذكره فى الأول ومين فى التانى لأ دائما قولا
+
+347
+00:30:39,550 --> 00:30:44,390
+واحدا بذكر انا الاين قبل الاين لكن من وين ابدأ
+
+348
+00:30:44,390 --> 00:30:48,610
+الترقيم هنا المشكلة واضح؟ عشان هيك هذا المركب
+
+349
+00:30:57,690 --> 00:31:02,350
+لازم نحدد اين موقع ال double bond من خلال نقطة
+
+350
+00:31:02,350 --> 00:31:06,050
+بدايتها و اين موقع ال triple bond من خلال نقطة
+
+351
+00:31:06,050 --> 00:31:12,610
+بدايتها نقطة بداية ال double bond موقع 4
+
+352
+00:31:13,790 --> 00:31:17,610
+واضح؟ الآن المركب هذا بزن فيه double bond و triple
+
+353
+00:31:17,610 --> 00:31:22,690
+bond إذا هو in-line اتكون من مقطعين زي ما بيكون
+
+354
+00:31:22,690 --> 00:31:25,790
+عندكم course من الفيزيا و الكيميا، شو بنسميه؟
+
+355
+00:31:27,530 --> 00:31:30,870
+physical chemistry هذا في double bond و triple
+
+356
+00:31:30,870 --> 00:31:36,690
+bond إيش بدى أسميه in, in, in, in, in, in, in, in,
+
+357
+00:31:36,690 --> 00:31:37,690
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+358
+00:31:37,690 --> 00:31:37,710
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+359
+00:31:37,730 --> 00:31:37,810
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+360
+00:31:37,810 --> 00:31:38,110
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+361
+00:31:38,110 --> 00:31:40,530
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+362
+00:31:40,530 --> 00:31:40,570
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+363
+00:31:40,570 --> 00:31:42,210
+in, in, in, in, in, in, in, in, in, in, in, in,
+
+364
+00:31:42,210 --> 00:31:42,650
+in, in, in, in, in, in, in, in, in,
+
+365
+00:31:45,330 --> 00:31:53,250
+in, in
+
+366
+00:31:54,030 --> 00:32:00,230
+من الموقع اتنين و بعد هيك four i و ال i اللي هي لل
+
+367
+00:32:00,230 --> 00:32:04,870
+triple point تبدأ من موقع اربع اذا انا قطعت الاسم
+
+368
+00:32:04,870 --> 00:32:11,370
+عشان اقدر اوضح بالظبط وين موقع كل مجموعة واضح؟
+
+369
+00:32:11,370 --> 00:32:17,360
+الان لو اطلعتوا على الجزء شوية صغير انعكسلاحظوا
+
+370
+00:32:17,360 --> 00:32:20,920
+مرة تانية لما بدأ أبدأ الترقيم واحد اتنين هى نقطة
+
+371
+00:32:20,920 --> 00:32:24,500
+البداية واحد اتنين تلاتة اذا الترقيم من وين لازم
+
+372
+00:32:24,500 --> 00:32:28,300
+يبدأ من هنا واحد اتنين تلاتة اربعة خمسة ستة سبعة
+
+373
+00:32:28,300 --> 00:32:33,940
+الجزء بيبقى برضه in I لكن بهذه الحالة ال in وين
+
+374
+00:32:33,940 --> 00:32:44,360
+صارت four hepten two I واضح four hepten two Iواضح
+
+375
+00:32:44,360 --> 00:32:49,180
+هذه النقطة؟ إذا إحنا الترقيم تبعنا بنعمله بحيث
+
+376
+00:32:49,180 --> 00:32:53,620
+اللي بنمر عليها أسرع ما يمكن بيكون من عدة ترقيم
+
+377
+00:32:53,620 --> 00:32:57,800
+سواء كان ال double bond أو ال triple bond هنا
+
+378
+00:32:57,800 --> 00:33:00,860
+بيجينا التساؤل طب لو كان ال double bond و ال
+
+379
+00:33:00,860 --> 00:33:03,940
+triple bond متساويات يعني هذا ع موقع اثنين من هنا
+
+380
+00:33:03,940 --> 00:33:09,900
+و هذا ع موقع اثنين من هنا equidistant واضح؟ زي هذا
+
+381
+00:33:09,900 --> 00:33:16,050
+المثال لما اجت هنا واحد اتنينلما إجيت هنا واحد،
+
+382
+00:33:16,050 --> 00:33:20,290
+تنين، من وين بدي أبدأ الترقيم؟ الآن إذا كانوا
+
+383
+00:33:20,290 --> 00:33:24,650
+متساويات، بأبدأ الترقيم من الجهة الأقرب للإين، مش
+
+384
+00:33:24,650 --> 00:33:30,910
+للأين إذا متساويات، واضح؟ إذا على موقع اتنين هنا
+
+385
+00:33:30,910 --> 00:33:34,850
+إين، ع موقع اتنين هنا أين، الترقيم بدي يبدأ من
+
+386
+00:33:34,850 --> 00:33:39,370
+الإين الأولوية للإين في هذه الحالة ولذلك هذا الجزء
+
+387
+00:33:39,370 --> 00:33:43,880
+بعد ما أرقم بهذا الشكل، يعني بدأت من الإينبصير
+
+388
+00:33:43,880 --> 00:33:51,660
+اسمه توهبتين فايف اين مش العكس واضح؟ توهبتين فايف
+
+389
+00:33:51,660 --> 00:33:56,800
+اين الآن لو الجزء كبر زي الأمثلة اللي هنا موجودة
+
+390
+00:33:56,800 --> 00:34:01,560
+ممكن نطلع على واحد او اتنين منها بنستمر بنفس
+
+391
+00:34:01,560 --> 00:34:05,480
+المنطق يعني هذه عبارة عن أمثلة إثرائية يعني هذا
+
+392
+00:34:05,480 --> 00:34:11,380
+المثال carbon اتنين تلاتة أربعة ايش هيكون؟
+
+393
+00:34:13,330 --> 00:34:19,310
+أو بيوت one iron فيه بيحطوا one بيوتين او بيوت one
+
+394
+00:34:19,310 --> 00:34:23,530
+iron نفس الاشي المهم انه حددنا بداية ال triple
+
+395
+00:34:23,530 --> 00:34:29,870
+bond على موقع واحد شو ضال عندى؟ على موقع أربعة و
+
+396
+00:34:29,870 --> 00:34:34,760
+أربعة dive loro و على موقع تلاتةمثل .. اذا هذا
+
+397
+00:34:34,760 --> 00:34:39,280
+four for daifloro .. three مثل .. one بيوتين او
+
+398
+00:34:39,280 --> 00:34:41,700
+بيوت one اين .. يعني هتشوفوا الطريقتين .. يعني
+
+399
+00:34:41,700 --> 00:34:45,240
+هتشوفوا مكتوب بيوت one اين و هتشوفوا مكتوب one
+
+400
+00:34:45,240 --> 00:34:53,210
+بيوتين .. لما يكون عندكمبند واحدة واضح انا بفضل
+
+401
+00:34:53,210 --> 00:34:57,290
+تكتبه بصيغة one بيوتاين يعني ما تضطروش انكوا
+
+402
+00:34:57,290 --> 00:35:00,990
+تقطعوا الاسم و تحطوا الرقم في وسطه الا في الحالات
+
+403
+00:35:00,990 --> 00:35:05,530
+اللي زي هذه اللي بكون عندى مجموعتين فبكون حطيت
+
+404
+00:35:05,530 --> 00:35:11,850
+لواحدة الرقم جبل و لواحدة الرقم في نص الاسم واضح
+
+405
+00:35:11,850 --> 00:35:17,650
+هذا المركب هذا المركب إذا بتطلع عليه فيه ال triple
+
+406
+00:35:17,650 --> 00:35:23,290
+bondو double bond، في triple bond و في double
+
+407
+00:35:23,290 --> 00:35:28,710
+bond، الآن من وين بدى أبدأ؟ بدى أقول من اللى بتكون
+
+408
+00:35:28,710 --> 00:35:32,430
+أقرب للترقيم، هنا ال triple bond بنمره واحد بتبدأ،
+
+409
+00:35:32,430 --> 00:35:35,610
+هنا ال double bond اتنين، اذا انا مضطر أبدأ من
+
+410
+00:35:35,610 --> 00:35:38,610
+هنا، one, two, three, four, five، الآن إيش اللى
+
+411
+00:35:38,610 --> 00:35:43,310
+بيذكر قبل؟ een ولا ein؟alphabetically ال E قبل ال
+
+412
+00:35:43,310 --> 00:35:48,750
+Y عشانيك هذا لما بدوا يسموه بيسموه بنت بنت three
+
+413
+00:35:48,750 --> 00:35:52,490
+in one ein يعني كأن هو بيقول إن ال in بتبدأ في
+
+414
+00:35:52,490 --> 00:35:56,350
+موقع تلاتة و ال ein بتبدأ في موقع واحد هذا كان
+
+415
+00:35:56,350 --> 00:36:00,250
+ممكن يسميه بطريقة شبه من اللي هنا تقول three بنتين
+
+416
+00:36:00,250 --> 00:36:06,750
+one ein برضه بيمشي و هذا أنا بفضلها three بنتين
+
+417
+00:36:06,750 --> 00:36:09,790
+one
+
+418
+00:36:11,620 --> 00:36:18,480
+يمكن تبين ألطف من انه نقطعه مرتين ال مثال اللي
+
+419
+00:36:18,480 --> 00:36:23,020
+بعده بتلاحظوا ان ال triple bond و double bond على
+
+420
+00:36:23,020 --> 00:36:30,700
+مسافتين متساويات وجدتها نقطة البداية في الترقيم
+
+421
+00:36:30,700 --> 00:36:36,320
+بتكون حوالين ال double bond مش ال triple bond ال E
+
+422
+00:36:36,320 --> 00:36:37,960
+مش ال I
+
+423
+00:36:54,940 --> 00:36:59,260
+هنا في عندنا أمثلة إضافية بتوضح لنا لو كان عندنا
+
+424
+00:36:59,260 --> 00:37:04,360
+أكتر من double bond أو أكتر من triple bond يعني
+
+425
+00:37:04,360 --> 00:37:09,330
+هذا الجزء مثلا كام double bond فيه؟تن تن هيكون
+
+426
+00:37:09,330 --> 00:37:14,530
+ضايقين و بنحدد مواقعهم وين موقعهم لما نحط هاي نقطة
+
+427
+00:37:14,530 --> 00:37:20,650
+بداية و نقطة بداية one three بيوته ضايقين one
+
+428
+00:37:20,650 --> 00:37:24,370
+three بيوته ضايقين بيوته لإنه أربعة فدون الأربعة
+
+429
+00:37:24,370 --> 00:37:28,270
+وين نقطة بداية ال double bonds على واحد و التلاتة
+
+430
+00:37:28,270 --> 00:37:31,630
+إذا في substitute one زي هذه بنقول two مثل one
+
+431
+00:37:31,630 --> 00:37:37,070
+three بيوته ضايقين لو المركب اللي عندي cyclic حلقي
+
+432
+00:37:37,870 --> 00:37:45,290
+بدل ما كنت بسميه cycle بنتين بصير أقول cycle بنتين
+
+433
+00:37:45,290 --> 00:37:51,110
+.. in .. واضح؟ cycle بنتين لما بأبدأ الترقيم ..
+
+434
+00:37:51,110 --> 00:37:55,230
+لما بأبدأ الترقيم بلاحظ أنه بإمكان أقول one two أو
+
+435
+00:37:55,230 --> 00:37:59,730
+one two .. واضح؟ لكن هذه ال one two بتمرنني على
+
+436
+00:37:59,730 --> 00:38:04,100
+المثلبتصير نمرة تلاتة، لو قلت منها انا one, two,
+
+437
+00:38:04,300 --> 00:38:08,380
+three, four, five، انه احسن، اقول لكوا دائما في
+
+438
+00:38:08,380 --> 00:38:12,320
+التسمية بنسعى نحو ال lower number اذا هذا three
+
+439
+00:38:12,320 --> 00:38:18,540
+مثل Cyclopentane طبعا
+
+440
+00:38:18,540 --> 00:38:21,060
+اللي بيقول حدد موقع هدولة انه حاطينها دي three
+
+441
+00:38:21,060 --> 00:38:26,860
+لاحظوا انا Cyclohexane، لكن كام double bond فيه؟
+
+442
+00:38:26,860 --> 00:38:29,900
+اذا حيصير Cyclohexa
+
+443
+00:38:32,140 --> 00:38:35,080
+cyclohexadiene هنا لما بكون عندى تنتين double
+
+444
+00:38:35,080 --> 00:38:39,060
+bonds بدوا يكون واضح عندكم انه لازم امر فى تنتين
+
+445
+00:38:39,060 --> 00:38:43,620
+double bonds كأولوية يعني كان بالإمكان واحدة تفكر
+
+446
+00:38:43,620 --> 00:38:46,680
+و تقول بدي امشي من هنا واحد اتنين و اخلى لك روم
+
+447
+00:38:46,680 --> 00:38:50,380
+تلاتة و بعدين طيب كويس لو ماشي من هنا هاي ال
+
+448
+00:38:50,380 --> 00:38:53,860
+double bond عن امرا واحد اتنين تلاتة اربعة خمسة
+
+449
+00:38:53,860 --> 00:38:58,280
+هذه وين بدأ تجينى على خمسة طب فى عندى احتمال تانى
+
+450
+00:38:58,280 --> 00:39:02,820
+ان اقول واحدأتنين تلاتة .. لاحظوا هنا نقاط البداية
+
+451
+00:39:02,820 --> 00:39:05,480
+لل double bond .. ستين تان .. لازم أمر عنهم ..
+
+452
+00:39:05,480 --> 00:39:10,800
+اتنين تان .. واحد و تلاتة .. و لبرومي بتجينا على
+
+453
+00:39:10,800 --> 00:39:14,900
+خمسة .. واحدة كان ممكن تفكر تقول واحد اتنين تلاتة
+
+454
+00:39:14,900 --> 00:39:18,790
+..السنة متحيرين هاي واحد اتنين تلت او هاي واحد
+
+455
+00:39:18,790 --> 00:39:22,990
+اتنين تلت يعني هيك one three و هيك one three بس ال
+
+456
+00:39:22,990 --> 00:39:26,850
+one three اللي هنا بيجيب ليله بوم على five ال one
+
+457
+00:39:26,850 --> 00:39:31,250
+three اللي هنا one two three four five sixشوفتوا
+
+458
+00:39:31,250 --> 00:39:35,670
+كيف؟ فأولويتي أن أمر على ال double points أسرع ما
+
+459
+00:39:35,670 --> 00:39:40,510
+يمكن بعدها إذا اتساوى الاحتمالين بتطلع على ..
+
+460
+00:39:40,510 --> 00:39:44,470
+بتطلع على ال substitute الإضافية إذا هذا بدي يصف
+
+461
+00:39:44,470 --> 00:39:51,050
+.. بدي يصف five probe one three cyclohexa دينفس
+
+462
+00:39:51,050 --> 00:39:55,670
+الاشي هنا تلاتة bonds هتشوفوا النهاية اترايين و
+
+463
+00:39:55,670 --> 00:39:59,770
+بتحددوا مواقعهم هنا cyclic تلاتة double bonds
+
+464
+00:39:59,770 --> 00:40:05,870
+هيكون cyclo-octa اترايين و بنحدد مواقعهم و لاحظوا
+
+465
+00:40:05,870 --> 00:40:09,550
+مرت على كل ال double bonds one two three four five
+
+466
+00:40:09,550 --> 00:40:15,610
+على واحد بداية ع تلاتة ع خمسة one three five cyclo
+
+467
+00:40:15,610 --> 00:40:24,830
+-octa اترايين لأنهم تمانتمان كاربونات واضح؟ الان
+
+468
+00:40:24,830 --> 00:40:30,450
+نرجع اكتر .. نرجع اكتر شوية و توسع صغير لظاهرة ال
+
+469
+00:40:30,450 --> 00:40:35,010
+cesueletrons اللي حكينا عنها زي ما حكينا احنا زي
+
+470
+00:40:35,010 --> 00:40:37,950
+ما ال بيوتين ال two-butene تحديدا فيه منه
+
+471
+00:40:37,950 --> 00:40:41,170
+cesueletrons يعني مجموعتين الميثل ممكن يكونوا على
+
+472
+00:40:41,170 --> 00:40:46,050
+جهة واحدة او على جهات متعاكسة الكلام ممكن يكون مع
+
+473
+00:40:46,050 --> 00:40:50,840
+غير مجموعات الميثل يعني ممكن يكون مع كلورينيعني لو
+
+474
+00:40:50,840 --> 00:40:55,260
+بدأ أحط الchlor على موقعين في جزء الethane نفسه
+
+475
+00:40:55,260 --> 00:41:00,600
+ممكن أحط الchlor هنا و هنا و ممكن أحطه هنا و هنا
+
+476
+00:41:00,600 --> 00:41:06,840
+واضح؟ طبعا ممكن أحط الchlor على ذرة واحدة يعني لو
+
+477
+00:41:06,840 --> 00:41:10,840
+كان عندي في الأساس جزء ethane بأربعة hydrogens لو
+
+478
+00:41:10,840 --> 00:41:14,220
+حاطيت ذرتين الchlor هنا، بيكون عندي من المركب واحد
+
+479
+00:41:14,220 --> 00:41:16,820
+ولا اتنين؟ واحد، واحد، واحد، واحد، واحد، واحد،
+
+480
+00:41:16,820 --> 00:41:17,660
+واحد، واحد، واحد، واحد، واحد، واحد، واحد، واحد،
+
+481
+00:41:17,660 --> 00:41:17,740
+واحد، واحد، واحد، واحد، واحد، واحد، واحد، واحد،
+
+482
+00:41:17,740 --> 00:41:19,780
+واحد، واحد، واحد، واحد، واحداللي هو هذا المُركّب
+
+483
+00:41:19,780 --> 00:41:28,280
+تحديدًا أكلور أكلور أتش أتش هذا one-one
+
+484
+00:41:28,280 --> 00:41:34,400
+-dichloroethane وفيش منه غير مُركّب واحد ليش؟ لأن
+
+485
+00:41:34,400 --> 00:41:37,740
+هنا الذرتين زي بعض و هنا الذرتين زي بعض لكن لما
+
+486
+00:41:37,740 --> 00:41:42,140
+باجي بعمل ال one-two-dichloroethane بلاحظ منه ses
+
+487
+00:41:42,980 --> 00:41:48,120
+ومنه ال trans .. منه ال cis ومنه ال trans .. واضح؟
+
+488
+00:41:48,120 --> 00:41:52,640
+فهذه ظاهرة ال cis و ال trans عبارة عن ظاهرة عامة
+
+489
+00:41:52,640 --> 00:41:59,320
+.. الآن في هذا المجال زي ما بتلاحظوا ان هدولة
+
+490
+00:41:59,320 --> 00:42:04,280
+تنتين زي بعض قولنا cis .. هدولة تنتين زي بعض قولنا
+
+491
+00:42:04,280 --> 00:42:10,560
+trans .. الأمور ممكن تصعب شوية معنىممكن تصعب شويه
+
+492
+00:42:10,560 --> 00:42:15,760
+معناه زى المثال اللى موجود عندى هنا اتطلعوا معاه
+
+493
+00:42:15,760 --> 00:42:20,620
+لو جت اتطلعت على هذا الجزء هنا في عندي carbon
+
+494
+00:42:20,620 --> 00:42:25,840
+اليود و الchlor زى بعض لأ مجموعتين مختلفتين و هنا
+
+495
+00:42:25,840 --> 00:42:32,700
+عندى ال brom و الميثل زى بعض مجموعتين مختلفتين إذا
+
+496
+00:42:32,700 --> 00:42:39,370
+هذا الجزء منهمنه مركبين .. منه مركبين .. كويس؟ لما
+
+497
+00:42:39,370 --> 00:42:42,790
+بدي أرسم المركب التاني باخد هذا بانسخه زي ما هو و
+
+498
+00:42:42,790 --> 00:42:48,330
+بعكس هدول الاتنين .. الآن ازمنتكوا حكت هيك ع
+
+499
+00:42:48,330 --> 00:42:52,910
+السريع جالت كلمة cis و trans لكن لو أنا بدي
+
+500
+00:42:52,910 --> 00:42:56,250
+أسألكوا كيف بدي أعرف إنه cis و trans؟ لما كان يكون
+
+501
+00:42:56,250 --> 00:42:58,690
+عندى chlorine و chlorine أقول هدول زي بعض و
+
+502
+00:42:58,690 --> 00:43:02,190
+الموضوع سهل .. هذا المركب لما بدي أطلع عليه فيه
+
+503
+00:43:02,190 --> 00:43:07,060
+youth و probe و chlorine و methylولا واحدة بتشبه
+
+504
+00:43:07,060 --> 00:43:10,060
+التاني عشان اقدر اقول ان هدولا زي بعض و لا مش زي
+
+505
+00:43:10,060 --> 00:43:16,660
+بعض فبصير صعب شوية عليا ان بسهولة اجاوب على السؤال
+
+506
+00:43:16,660 --> 00:43:19,940
+شو هو هذا المركب ال archive بيجيبوا عليه بيجوا
+
+507
+00:43:19,940 --> 00:43:22,580
+بتطلعوا على ال carbon الأولى بيقولوا تطلعوا على
+
+508
+00:43:22,580 --> 00:43:26,560
+أول ذرة متصلة فيها إيش إلها ال atomic number العدد
+
+509
+00:43:26,560 --> 00:43:30,800
+الذرع وعلى أول ذرة هنا وشوفوا مين أعلى الآن كلكم
+
+510
+00:43:30,800 --> 00:43:35,800
+تذكرين الجدول الدوري اللي هو floorالكلور .. البروم
+
+511
+00:43:35,800 --> 00:43:39,280
+.. اليود .. ايه هو اعلى واحد فيهم؟ اليود .. اليود
+
+512
+00:43:39,280 --> 00:43:42,840
+.. اذا لما بدي اقارن اليود مع الكلور .. مين اعلى
+
+513
+00:43:42,840 --> 00:43:45,400
+في ال atomic number؟ اليود .. اليود .. بقول هي
+
+514
+00:43:45,400 --> 00:43:49,400
+الاعلى ..الان بعد هيك بدي اجعل طلع .. في عند بروم
+
+515
+00:43:49,400 --> 00:43:53,040
+و المتصلة مباشرة carbon .. ايه هو اعلى في ال
+
+516
+00:43:53,040 --> 00:43:57,120
+atomic number؟ البروم ولا ال carbon؟ كلهم حافظين
+
+517
+00:43:57,120 --> 00:44:00,600
+الشكل العام تبع الجدول الدوري .. البروم اعلى ..
+
+518
+00:44:00,600 --> 00:44:05,270
+اذا كأنه انا قدرت اقول ان هذه اعلى و هذه اعلىالان
+
+519
+00:44:05,270 --> 00:44:08,590
+المجموعتين الأعلى في ال atomic number اللي لهم
+
+520
+00:44:08,590 --> 00:44:12,510
+priority او أولوية يجوا على جهة واحدة في هذه
+
+521
+00:44:12,510 --> 00:44:17,570
+الحالة كأنه المركب sis لاحظوا في الحالة التانية لو
+
+522
+00:44:17,570 --> 00:44:22,550
+قلت chlorine و iod من الأعلى بروم و carbon من
+
+523
+00:44:22,550 --> 00:44:29,030
+الأعلى لبروم الأعلى يجواعكس بعض كأنه المركب trans
+
+524
+00:44:29,030 --> 00:44:32,770
+لكن في هذه الحالة اللي المجموعات مش زي بعض
+
+525
+00:44:32,770 --> 00:44:37,950
+بيستخدموش كلمة cis و trans بيستعملوا حروف جاية من
+
+526
+00:44:37,950 --> 00:44:42,270
+اللغة الألمانية حروف من وين جاية؟ من اللغة
+
+527
+00:44:42,270 --> 00:44:46,270
+الألمانية اللغة الألمانية فيها كلمة it's zusammen
+
+528
+00:44:46,270 --> 00:44:51,530
+it's zusammen يعني مع بعضجايين مع بعض فالأشياء
+
+529
+00:44:51,530 --> 00:44:56,470
+اللي جايين مع بعض بيستخدمولهم بدل كلمة sis حرف
+
+530
+00:44:56,470 --> 00:45:01,230
+الزد كأنه الزد الآن بنقدر نقول ان هو من ناحية
+
+531
+00:45:01,230 --> 00:45:06,550
+المبدأ موازي لل sis لكن ال sis حالة خاصة لما تكون
+
+532
+00:45:06,550 --> 00:45:10,430
+المجموعات زي بعض بنستعمل ال sis لما الحالة تصعب
+
+533
+00:45:10,430 --> 00:45:14,490
+شويةالزد، لكن لو أنا بدأ أترجم ال sis معناها أنه
+
+534
+00:45:14,490 --> 00:45:18,230
+مع بعض أو من جهة واحدة و ال zed معناها من جهة
+
+535
+00:45:18,230 --> 00:45:23,250
+واحدة، لكن أنيا الحالة الأعامالـ Z لأن الـ Z بتجيب
+
+536
+00:45:23,250 --> 00:45:27,410
+لمجموعات مختلفة فبدي أعمل شوية تحليل و أسأل نفسي
+
+537
+00:45:27,410 --> 00:45:31,610
+عن ال atomic numbers قبل ما أقدر أحط الجواب واضح؟
+
+538
+00:45:31,610 --> 00:45:36,930
+ولذلك أنا بظنوا زي بعض واستعملوا Z ولا التعاكس في
+
+539
+00:45:36,930 --> 00:45:42,560
+عندهم كلمة entgagen .. entgagen ضد بعضانت جاجل
+
+540
+00:45:42,560 --> 00:45:47,480
+فبيستعملوا البادئة E الان كإنها البادئة E من ناحية
+
+541
+00:45:47,480 --> 00:45:53,200
+المبدأ موازية لل Trans لكن احنا كاستعمال احنا
+
+542
+00:45:53,200 --> 00:45:58,880
+كاستعمال بدنا نستعملالمجموعات اللي كلها مختلفة
+
+543
+00:45:58,880 --> 00:46:04,640
+نظام Z و E لما يكون الجزء بسيط زي ال بيوتين مثل و
+
+544
+00:46:04,640 --> 00:46:09,240
+مثل زي دايكلور و كلور و كلور مبينين بسهولة نستعمل
+
+545
+00:46:09,240 --> 00:46:12,740
+S و Trans ف ال Z و ال E هي الأعام و ال S و ال
+
+546
+00:46:12,740 --> 00:46:19,440
+Trans بنبدأ نعتبرها حالة خاصة ال Z موازية لل S و
+
+547
+00:46:19,440 --> 00:46:26,340
+ال E موازية لل Trans حتى لو الجزء كبربضلني على نفس
+
+548
+00:46:26,340 --> 00:46:29,880
+الشيء يعني هنا مثلا هاي double bond هذه متصلة ب
+
+549
+00:46:29,880 --> 00:46:34,400
+CH3 و هذه متصلة ب CH2 CH3 أنهي أكبر في الآخر في ال
+
+550
+00:46:34,400 --> 00:46:39,660
+atomic number هذه لأن هنا H و H و H هنا H و H و
+
+551
+00:46:39,660 --> 00:46:44,400
+Carbon اللي بعد يعني أول atom carbon carbon على
+
+552
+00:46:44,400 --> 00:46:47,160
+العين والرأس بس اللي بعد هنا في carbon فكل هذه
+
+553
+00:46:47,160 --> 00:46:50,800
+المجموعة كأيه اللي بتصير الأعلى الآن لو أتيت طلعت
+
+554
+00:46:50,800 --> 00:46:57,910
+هذه carbon متصلة بإيش؟ب H و CH3 و O واحدة هذه
+
+555
+00:46:57,910 --> 00:47:05,470
+carbon متصلة ب إيش؟ هذه اللي هنا ب C و O و O ال
+
+556
+00:47:05,470 --> 00:47:10,490
+double bond عملوها إيش؟ O مرتل فالان carbon متصلة
+
+557
+00:47:10,490 --> 00:47:15,830
+ب C و H و O ولا carbon متصلة ب C و O و O أنية
+
+558
+00:47:15,830 --> 00:47:22,510
+أعلى؟ هذه ولذلك هذه المجموعة أعلى من هذهواضح؟ باجي
+
+559
+00:47:22,510 --> 00:47:29,310
+بتطلع على هذه الذرع، إيش متصلة؟ بـC O O، هنا بـC H
+
+560
+00:47:29,310 --> 00:47:33,110
+O، أنهى اللى أعلى؟ أكيد هذه، واضح؟ الآن هدول
+
+561
+00:47:33,110 --> 00:47:37,910
+المجمعتين زى بعض، إذا هذا المركب إيش بدو يكون؟ Z
+
+562
+00:47:37,910 --> 00:47:44,470
+كذلك الحال هنا، لو إجيت طلعت U DuClorأنه الأعلى؟
+
+563
+00:47:44,470 --> 00:47:48,530
+اليود واضح طب هنا لما أجهز طلع على مثل حلقة بنزين
+
+564
+00:47:48,530 --> 00:47:52,290
+مرة تانية يعتبروا هذه carbon عادية و هذه carbon
+
+565
+00:47:52,290 --> 00:47:56,650
+الآن هنا carbon و carbon زي بعض بنطلع لمبعد هذه ال
+
+566
+00:47:56,650 --> 00:48:02,750
+carbon متصلة بإيش؟ ب carbon و carbon و H هذه ال
+
+567
+00:48:02,750 --> 00:48:08,510
+carbon متصلة بإيش؟ ب carbon و carbon و carbon إذا
+
+568
+00:48:08,510 --> 00:48:15,450
+أن هي أعلىأنا لاحظوا معي ماباخدش الوزن الكلي للقطع
+
+569
+00:48:15,450 --> 00:48:19,710
+المتصل هنا لأ بمشي بالتدرج اللي بوضحلكوا إياه هذه
+
+570
+00:48:19,710 --> 00:48:26,170
+متصلة ب carbon و carbon واضح؟ مش واحدة تيجي تجمع
+
+571
+00:48:26,170 --> 00:48:31,170
+المجموعة جمع حسابي و أجتها بترتكب خطأ كبير يعني
+
+572
+00:48:31,170 --> 00:48:34,870
+بدي أعطيكم مثل لو كان عندكم double bonds مثلا و
+
+573
+00:48:34,870 --> 00:48:38,810
+هنا في عندكم floor و هنا في عندكم carbon و ال
+
+574
+00:48:38,810 --> 00:48:43,860
+carbon هذه حاملة يوتأيود .. أيود .. وعارفين اليود
+
+575
+00:48:43,860 --> 00:48:47,780
+قد إيش الدنيا .. أنية المجموعة اللي إلها أولوية ..
+
+576
+00:48:47,780 --> 00:48:54,740
+الأعلى .. بديش أطلع على أي إشي بعد إلا لما أخلص من
+
+577
+00:48:54,740 --> 00:48:57,140
+الأولى .. إذا الأولى حلتني المشكلة بطلع إشي اللي
+
+578
+00:48:57,140 --> 00:49:01,740
+بعدها .. هنا الاتصال المباشر مع إيش .. هنا الاتصال
+
+579
+00:49:01,740 --> 00:49:05,340
+المباشر مع إيش .. طب .. أنية أعلى .. ال floor ولا
+
+580
+00:49:05,340 --> 00:49:10,980
+ال carbon .. ال floor .. هي الأعلى ..بجيش اخد نمرة
+
+581
+00:49:10,980 --> 00:49:14,300
+اتنين والتلاتة الا اذا نمرة واحد ماحلتش المشكلة
+
+582
+00:49:14,300 --> 00:49:18,500
+عندى .. واضح .. بجيش اخد نمرة اتنين والتلاتة الا
+
+583
+00:49:18,500 --> 00:49:22,320
+اذا نمرة واحد ماحلتش المشكلة عندى .. بهك تقريبا
+
+584
+00:49:22,320 --> 00:49:28,040
+بنقدر نشوف كيف احنا بنحدد ال Z وال E ايزو مارز وفي
+
+585
+00:49:28,040 --> 00:49:36,230
+عندنا مجموعة قواعد حقيقة موجودين هنا بشكل عامبهذا
+
+586
+00:49:36,230 --> 00:49:41,290
+الشكل بيكون واضح مجموعات متشابهة باستعمل SESTRANS
+
+587
+00:49:41,290 --> 00:49:45,290
+مجموعات مختلفة باستعمل Z و E المرة الجاية ان شاء
+
+588
+00:49:45,290 --> 00:49:49,210
+الله بنبدأ فيه تفاعلات ال ال keys
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b2db1d2fac08bb7327fcdb4e99a95453b2f45251
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo_postprocess.srt
@@ -0,0 +1,1960 @@
+1
+00:00:08,680 --> 00:00:13,720
+المرة الماضية اتكلمنا عن بداية تفاعلات ال E-stars
+
+2
+00:00:13,720 --> 00:00:18,040
+وقولنا ال E-stars ومشتقات الأحمض بشكل عام تفاعلها
+
+3
+00:00:18,040 --> 00:00:22,440
+الأساسي هو تفاعل إيش؟الـ Substitution الـ
+
+4
+00:00:22,440 --> 00:00:26,920
+Nucleophilic Substitution بمعنى مجموعة الـ OR
+
+5
+00:00:26,920 --> 00:00:33,080
+بتطلع و بيدخل عندنا مجموعة للنوكليوفايل أي ان كانت
+
+6
+00:00:33,080 --> 00:00:37,960
+الان المرة هذه بناخد تفاعل ال E Stars مع متفاعل
+
+7
+00:00:37,960 --> 00:00:43,080
+Greenyard وبشكل عام بيحطوا متفاعل Greenyard بزيادة
+
+8
+00:00:43,080 --> 00:00:48,850
+طبعا بتكونوا متذكرين ان Greenyard Reagentسابق ان
+
+9
+00:00:48,850 --> 00:00:55,090
+اتكلمنا عنه ان هو عبارة عن R مع أزواج Electronata
+
+10
+00:00:55,090 --> 00:00:59,150
+بمعنى الـ Green Yardley Agent هو عبارة عن الـ
+
+11
+00:00:59,150 --> 00:01:02,970
+Nucleophile واضح؟ بناء على ذلك طالما الـ Green
+
+12
+00:01:02,970 --> 00:01:07,130
+Yardley Agent بالنسبة لي بيمثل هذه الشغلة، ما عدا
+
+13
+00:01:07,130 --> 00:01:11,530
+ذلك مش مهم R مع أزواج Electronata الـ Nucleophile
+
+14
+00:01:11,530 --> 00:01:14,770
+إذا إيش تفاعل الأساسي مع الـ E star؟
+
+15
+00:01:23,040 --> 00:01:28,620
+هذا الـ R تبعت لجرينيار ده انا حاطط لها R'' على
+
+16
+00:01:28,620 --> 00:01:32,640
+اساس انه يميزها عن الارز اللي موجودين يعني ايا
+
+17
+00:01:32,640 --> 00:01:37,820
+كانت مثل اثل فنل الخلاصة المجموعة ال الكل او ال R
+
+18
+00:01:37,820 --> 00:01:43,870
+اللي مع جرينيار بتيجي محلالـ OR فبصير عندك كيتون
+
+19
+00:01:43,870 --> 00:01:48,350
+هذا كيف يتم التفاعل بالنصف مش كتير موضوع لكن
+
+20
+00:01:48,350 --> 00:01:54,150
+الإبتدال سهل انه ال green yard الكليكروبي بتيجي
+
+21
+00:01:54,150 --> 00:01:58,350
+محل ال OR الآن لاحظوا هنا في الخطوة الأولى صار
+
+22
+00:01:58,350 --> 00:02:04,280
+عندك كيتون إذا رجعتوا لتفاعلات ال ketonesمع
+
+23
+00:02:04,280 --> 00:02:07,740
+Greenyard هتلاحظوا ان الكيتون بتفاعل مع Greenyard
+
+24
+00:02:07,740 --> 00:02:11,760
+بناء على ذلك لو كان عندى كمان كمية إضافية من
+
+25
+00:02:11,760 --> 00:02:18,580
+Greenyard بمعنى عندى كمان كمية إضافية من ال R تبع
+
+26
+00:02:18,580 --> 00:02:22,360
+ال Greenyard في هذه الحالة الكمية الإضافية هتتفاعل
+
+27
+00:02:22,360 --> 00:02:26,680
+مع ايش؟ مع الكيتون الكيتون تفاعله
+
+28
+00:02:29,720 --> 00:02:35,060
+addition إضافة واضح إذا بيصير عند التفاعلين هاي
+
+29
+00:02:35,060 --> 00:02:39,060
+النتج النهائي مرة تانية أنه دخلت R group تانية و
+
+30
+00:02:39,060 --> 00:02:44,580
+ال O صارت OH إذا بتذكروا كنا بهذا الشكل نعمل
+
+31
+00:02:44,580 --> 00:02:49,360
+التفاعل متذكرين؟ إذا ال green yard بنقدر نقول أنه
+
+32
+00:02:49,360 --> 00:02:54,160
+بيتفاعل على مرحلتين مع ال eastern لما يكون بكمية
+
+33
+00:02:54,160 --> 00:03:00,790
+مضاعفة بمكافئ مضاعف التفاعل الأولsubstitution
+
+34
+00:03:00,790 --> 00:03:07,190
+إبتدال بيؤدي إلى تكوين الكيتون ثم يتفاعل مباشرة
+
+35
+00:03:07,190 --> 00:03:11,810
+بتفاعل إضافة يؤدي إلى تكوين هذا الالكول هذا
+
+36
+00:03:11,810 --> 00:03:16,090
+الالكول إذا بتبتطلع عليه تيرت شري الالكول عشانك
+
+37
+00:03:16,090 --> 00:03:21,750
+متعودين احنا نقول الآن انه تفاعل ال Easter مع كمية
+
+38
+00:03:21,750 --> 00:03:27,050
+مضاعفة من ال green yard في المحصلة بيعطينيTertiary
+
+39
+00:03:27,050 --> 00:03:30,970
+Alcohol هذا الـ tertiary alcohol المتكوّن بيكون
+
+40
+00:03:30,970 --> 00:03:36,230
+فيه مجموعتين زي بعض ليش المجموعتين زي بعض؟ لأنهم
+
+41
+00:03:36,230 --> 00:03:41,930
+إجوا من الـ green yard على مرتين إجوا من ال green
+
+42
+00:03:41,930 --> 00:03:45,650
+yard reaction ع مرتين المرة الأولى إجت R double
+
+43
+00:03:45,650 --> 00:03:50,150
+prime وطردت ال OR و المرة الثانية أضيفة ال R
+
+44
+00:03:50,150 --> 00:03:54,850
+double prime و C double point O صارت OH فكمحصلة
+
+45
+00:03:57,060 --> 00:04:00,840
+التجارب الأساسية لتجارب الـ Greenyard Reagent هي
+
+46
+00:04:00,840 --> 00:04:02,240
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+47
+00:04:02,240 --> 00:04:02,660
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+48
+00:04:02,660 --> 00:04:07,960
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+49
+00:04:07,960 --> 00:04:09,180
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+50
+00:04:09,180 --> 00:04:11,240
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+51
+00:04:11,240 --> 00:04:12,320
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+52
+00:04:12,320 --> 00:04:16,560
+تجارب التجارب الأساسية تجارب التجارب الأساسية
+
+53
+00:04:16,560 --> 00:04:21,030
+تجارب التجارب الأسكيف ممكن تحضروا ال tertiary
+
+54
+00:04:21,030 --> 00:04:24,790
+alcohol؟ بأي طريقة أنتوا عارفينها تريدون أن تبدو
+
+55
+00:04:24,790 --> 00:04:28,910
+بال Easter و تفعلوا مع Green Yard مرتين ممكن
+
+56
+00:04:28,910 --> 00:04:31,710
+مايكونش معطيكوا تبدو من ال Easter ممكن تبدو من ال
+
+57
+00:04:31,710 --> 00:04:36,450
+acid فهذه الحالة ال acid بتحوله ل Easter و ال
+
+58
+00:04:36,450 --> 00:04:44,410
+Easter بتفعل مع Green Yard مرتين واضح؟ لكن طالما
+
+59
+00:04:44,410 --> 00:04:50,070
+أنه معطيكوا أنا هنا ل Green Yardبنسبة مضاعفة أو
+
+60
+00:04:50,070 --> 00:04:55,230
+كاتب excess المفروض لو بدى اجيب اكمال معادلة شغلة
+
+61
+00:04:55,230 --> 00:04:59,590
+زي هيك بس يكون عندى هذا الجواب اللى هنا انه green
+
+62
+00:04:59,590 --> 00:05:05,090
+yard اتفعل مرتين كل هذه الأشياء بهمنيش اشوفها واضح
+
+63
+00:05:05,090 --> 00:05:08,650
+كل هذه الأشياء بهمنيش اشوفها لما اقولكم complete
+
+64
+00:05:08,650 --> 00:05:12,170
+the following equation حطلكوا فراغ green yard مع
+
+65
+00:05:12,170 --> 00:05:16,670
+easter green yard excess مع easterترتشر ألكول
+
+66
+00:05:16,670 --> 00:05:22,130
+بمجموعتين الـR اللي جايين من الـgreen yard reagent
+
+67
+00:05:34,010 --> 00:05:38,590
+من تفاعلات ال E stars اللي هي ايضا تفاعلات ابدال
+
+68
+00:05:38,590 --> 00:05:42,310
+اللي بنسميها ال ammonolysis التفاعل مع ال ammonia
+
+69
+00:05:42,310 --> 00:05:46,190
+لو اتطلعنا ال ammonia نيوكليوفايد بنفس المبدأ
+
+70
+00:05:46,190 --> 00:05:50,730
+بتتفاعل و تبرد ال OR حيث ان عندي RC ضو ال bond O
+
+71
+00:05:50,730 --> 00:05:55,290
+and H2 من ال ammonia بناء على ذلك ال E star مع ال
+
+72
+00:05:55,290 --> 00:06:02,030
+ammonia بيعطينيالامد واضح أيا كان هاي مثال إضافي
+
+73
+00:06:02,030 --> 00:06:08,610
+هاي E star مع ammonia بيعطينا الامد وهذا تفاعل زي
+
+74
+00:06:08,610 --> 00:06:14,770
+ما بتلاحظ انه تكراري يعني بنكرر احنا تقريبا نفس
+
+75
+00:06:14,770 --> 00:06:21,030
+الكلام ال uq file بحل محل ال OR من
+
+76
+00:06:21,030 --> 00:06:26,630
+تفاعلاتالـ E stars من تفاعلات الـ E stars اللي هو
+
+77
+00:06:26,630 --> 00:06:34,670
+تفاعل ال reduction of E stars حقيقة
+
+78
+00:06:34,670 --> 00:06:39,910
+تفاعل ال reduction of E stars مع ال lithium
+
+79
+00:06:39,910 --> 00:06:44,430
+aluminum hydride مع ال lithium aluminum hydride
+
+80
+00:06:44,430 --> 00:06:48,330
+هذا ال hydride احنا اتفقنا ك reducing agent هو
+
+81
+00:06:48,330 --> 00:06:49,550
+مصدر لإيش؟
+
+82
+00:06:52,520 --> 00:06:55,960
+الـ H مع أزواج الإلكترونات
+
+83
+00:07:04,840 --> 00:07:09,480
+Hydride anion الليثيوم الومنوم هيدرايد هذا مصدر
+
+84
+00:07:09,480 --> 00:07:13,360
+الهيدرايد انايون ايش اللي بيعملوا في ال reduction؟
+
+85
+00:07:13,360 --> 00:07:18,500
+اذا بتقدروا تطلعوا عمل شبيه جدا بمتفاعل جرينيار
+
+86
+00:07:18,500 --> 00:07:24,900
+اتذكروا في ايه؟ الجرينيار اتفاعل ال a star اتفاعل
+
+87
+00:07:24,900 --> 00:07:33,260
+ال a star مع ال R minus مرتين وال O صارتهنا نفس
+
+88
+00:07:33,260 --> 00:07:39,160
+الشيء كأن الـ H- تهاجم في الخطوة الأولى تطرد الـ
+
+89
+00:07:39,160 --> 00:07:44,600
+OR و الـ H- تهاجم في الخطوة التانية تحول هذه إلى
+
+90
+00:07:44,600 --> 00:07:50,440
+OH فبالمحص لهذا التفاعل موازي موازلة تفاعل
+
+91
+00:07:50,440 --> 00:07:55,380
+اجرنيارد ان انا فعلت مع الـ UQ file مرتين يعني لما
+
+92
+00:07:55,380 --> 00:08:01,000
+اجي في الخطوة الأولى اقول زي هيك حسر عندك R
+
+93
+00:08:19,040 --> 00:08:24,520
+بنان على ذلك مرة تانية كان محصلة ال reduction of E
+
+94
+00:08:24,520 --> 00:08:31,080
+stars with hydrides produces primary alcohols تبقى
+
+95
+00:08:31,080 --> 00:08:37,270
+صحبمعنى ان هذه الـ c double bond o مكانها بجي
+
+96
+00:08:37,270 --> 00:08:46,010
+بتطلع في عندى c double bond o لأ مش OH CH2 OH ناس
+
+97
+00:08:46,010 --> 00:08:48,690
+كتير لما يحطولي الجواب مهمش ليش الغلطة هذه و
+
+98
+00:08:48,690 --> 00:08:54,310
+بعتبرها خطأ بيروح و بيحطلي R OH هي خلطة وين راحت
+
+99
+00:08:54,310 --> 00:09:00,390
+ال C؟يعني بيكونوا طرسوا نوعا ما ويعرفوا انه ال a
+
+100
+00:09:00,390 --> 00:09:03,070
+star بالليثيام ألومنوم هيدرايت بيصير له reduction
+
+101
+00:09:03,070 --> 00:09:07,630
+و بيصير alcohol لكن لما ييجي ينفذ الجواب بكتبش
+
+102
+00:09:07,630 --> 00:09:15,890
+RCH2OH بيروح بكتب R OH طب هون رحت ال C إذا الجواب
+
+103
+00:09:15,890 --> 00:09:22,510
+الصح R و ال C نفسها بتصير CH2 لإن ال C موجودة و
+
+104
+00:09:22,510 --> 00:09:26,270
+أضيف عليها ال H mark دين فبتصير
+
+105
+00:09:28,630 --> 00:09:34,170
+CH2OH R CH2OH إذا بنقدر نقول ببساطة إنه reduction
+
+106
+00:09:34,170 --> 00:09:40,770
+of esters produces primary alcohols الان هذا
+
+107
+00:09:40,770 --> 00:09:44,890
+الكلام للي بيحبوا الأسئلة بنقدر نسأل عنه بسؤال صح
+
+108
+00:09:44,890 --> 00:09:48,010
+و غلط نقول reduction of esters produces aldehydes
+
+109
+00:09:48,010 --> 00:09:58,400
+أوكيتون أو كربوكسيليك أسد برايمر ألكول برايمر
+
+110
+00:09:58,400 --> 00:10:06,240
+ألكول برايمر ألكول برايمر ألكول برايمر
+
+111
+00:10:06,240 --> 00:10:07,180
+ألكول برايمر ألكول برايمر ألكول برايمر ألكول
+
+112
+00:10:07,180 --> 00:10:07,280
+برايمر ألكول برايمر ألكول برايمر ألكول برايمر
+
+113
+00:10:07,280 --> 00:10:07,540
+ألكول برايمر ألكول برايمر ألكول برايمر ألكول
+
+114
+00:10:07,540 --> 00:10:10,900
+برايمر ألكول برايمر ألكول برايمر ألكول برايمر
+
+115
+00:10:10,900 --> 00:10:15,620
+ألكول
+
+116
+00:10:15,620 --> 00:10:22,360
+بالليثيام ألومنوم هايدرايد بس بيشتغل على ال double
+
+117
+00:10:22,360 --> 00:10:28,260
+bonds بيسيبه من ال double bonds بناء على ذلك ال c
+
+118
+00:10:28,260 --> 00:10:34,860
+double bond o شو هتصير؟ شوفين
+
+119
+00:10:34,860 --> 00:10:39,080
+الناس اللي بتتغلبوا لما يكتبوا النواتج كل إشي
+
+120
+00:10:39,080 --> 00:10:42,500
+بتيجي زي ما هو في النهاية ال production of easter
+
+121
+00:10:42,500 --> 00:10:53,960
+بيحول لل c double bond oبحول الـ CH2OH إلى CH2OH
+
+122
+00:11:03,740 --> 00:11:10,800
+في تفاعل ل ال E stars موازي بشكل كبير جدا للتفاعل
+
+123
+00:11:10,800 --> 00:11:14,660
+اللي أخدناه اللي قلنا عنه الالدول reaction في
+
+124
+00:11:14,660 --> 00:11:19,620
+الالدول reaction كنت أخد جزيئين الديهيد وأفعلهم مع
+
+125
+00:11:19,620 --> 00:11:23,840
+baseواحد يصير الـ nucleophile و بعدين يعمل
+
+126
+00:11:23,840 --> 00:11:29,080
+addition على الجزاء التاني إذا رجعته بويس الان في
+
+127
+00:11:29,080 --> 00:11:33,860
+ال E stars بعمل نفس الشيء باخد جزايين من ال E
+
+128
+00:11:33,860 --> 00:11:38,760
+stars بفعلهم مع واحد من ال base ال base هتيجي على
+
+129
+00:11:38,760 --> 00:11:42,800
+مكان ال alpha hydrogen اللي هي ال hydrogen اللي
+
+130
+00:11:42,800 --> 00:11:47,880
+جام ال C double bond O هتشيل ال hydrogen هتصير هذه
+
+131
+00:11:47,880 --> 00:11:55,670
+ال CH2 شمالهامينوس ايون سالب صارت نيوكليوفايل الان
+
+132
+00:11:55,670 --> 00:12:01,370
+صارت تفاعل ببساطة نيوكليوفايل بتفاعل مع easter شو
+
+133
+00:12:01,370 --> 00:12:06,450
+تفاعل نيوكليوفايل مع ال easter Substitution
+
+134
+00:12:06,450 --> 00:12:14,510
+عقول بمعنى هذا بيجي يهاجم زي هيك و هذا تطلع واضح؟
+
+135
+00:12:16,290 --> 00:12:21,690
+بناء على ذلك الناتج اللي عندي هيكون CH3CWbO هذي
+
+136
+00:12:21,690 --> 00:12:26,510
+اللي في المربع الأزرق هذي جاية من ال Easter الأول
+
+137
+00:12:26,510 --> 00:12:31,810
+ومن ال Easter التاني CH2CWbO O CH2 CH3 بحطها زي ما
+
+138
+00:12:31,810 --> 00:12:38,370
+هي لاحظوا هذا التفاعل موازي لتفاعل الدل تفاعل الدل
+
+139
+00:12:38,370 --> 00:12:43,770
+كنت أخد جزيئين الديهايد واحد أخليه ايون لما يتفاعل
+
+140
+00:12:43,770 --> 00:12:48,360
+مع التاني شو التفاعل اللي كان يعمله؟أضافة
+
+141
+00:12:48,360 --> 00:12:52,580
+اليوكليوفايل مع الديهيدوكيتون اضافة اليوكليوفايل
+
+142
+00:12:52,580 --> 00:12:53,540
+مع ال E-star
+
+143
+00:13:01,720 --> 00:13:07,960
+substitution إبدال بينما الالدول reaction is an
+
+144
+00:13:07,960 --> 00:13:12,180
+addition reaction واضح هذا السؤال صح و غلط الالدول
+
+145
+00:13:12,180 --> 00:13:20,400
+reaction is an addition reaction because الالدول
+
+146
+00:13:20,400 --> 00:13:26,520
+بتعامل مع ال الديهيدز الالدول بتعامل مع ال
+
+147
+00:13:26,520 --> 00:13:31,970
+الديهيدزوالـ Antihites تفعيلها الأساسي الـ Claisen
+
+148
+00:13:31,970 --> 00:13:36,970
+reaction بتعمل مع ال A stars وال A stars تفعيلها
+
+149
+00:13:36,970 --> 00:13:38,890
+الأساسي substitution
+
+150
+00:13:40,780 --> 00:13:45,300
+هي مثلا مثال تاني هذا الجزء لو بده يعمل إكليزين
+
+151
+00:13:45,300 --> 00:13:49,280
+كوندنسيشن الان احنا اتفقنا سابقا ايش افضل طريقة
+
+152
+00:13:49,280 --> 00:13:54,180
+لكتابة ناتج إكليزين او ألدول ان احط جزايين جان بعض
+
+153
+00:13:54,180 --> 00:13:57,320
+بالظبط زي ما حكت زملتكم بناء على ذلك هان انا
+
+154
+00:13:57,320 --> 00:14:03,220
+بتتخيل ان عندي صيبة بال bond O O CH2 CH3 و هن احط
+
+155
+00:14:03,220 --> 00:14:10,180
+CH2 و هن احط CH3 هى جزء و جزء واحد منهم بده يصير
+
+156
+00:14:11,800 --> 00:14:16,300
+ايون ويهاجم ع التاني الان من وين بيصير ايون وبيحذف
+
+157
+00:14:16,300 --> 00:14:20,420
+بروتون؟ من الجانب الـ C double bond او من الالف
+
+158
+00:14:20,420 --> 00:14:25,260
+هيدروجين، اذا هنا حيصير عنده نيجاتيف، هاي الايون
+
+159
+00:14:25,260 --> 00:14:31,900
+هذا اللي صار نيوكليوفايد بيهاجم على الجزء هذا
+
+160
+00:14:31,900 --> 00:14:33,120
+وبيطرد
+
+161
+00:14:37,260 --> 00:14:42,280
+بناء على ذلك بيصير عندكم هذا الجزء اللي هو مبين
+
+162
+00:14:42,280 --> 00:14:50,920
+باللون الأصمر CH3CH2C double bond O و هذا من وين
+
+163
+00:14:50,920 --> 00:14:58,240
+بيكون التصل من ال CH اللي هنا اذا هنا المجموعة
+
+164
+00:14:58,240 --> 00:15:03,310
+المثل هتكونلا تحت أو لا فوق مش مشكلة المهم هو بتصل
+
+165
+00:15:03,310 --> 00:15:06,810
+من الـ C اللي جنب الكربون هذه المسألة في معظم
+
+166
+00:15:06,810 --> 00:15:10,430
+المرات لما بيصير خطأ فيها بيجي الطالب بيروح بيعمل
+
+167
+00:15:10,430 --> 00:15:15,590
+ال minus هنا و بيحط هدولة بشكل مستقيم هنا محور
+
+168
+00:15:15,590 --> 00:15:21,350
+الخطأ في هذا السؤال فال minus دائما وين بيكون؟ على
+
+169
+00:15:21,350 --> 00:15:27,090
+ال alpha-hydrogen البركب اللي انت لازم تفعله انت
+
+170
+00:15:27,090 --> 00:15:32,080
+خدت الكربون اللي بتفرق بالارلأ اللي جنب الـ O هي
+
+171
+00:15:32,080 --> 00:15:41,560
+الـ C double bond O من جنبها شيلنا بروتل الهجوم
+
+172
+00:15:41,560 --> 00:15:44,160
+على الكربونة المتصلة بالـ O في كل ال E stars
+
+173
+00:15:47,770 --> 00:15:52,110
+هذا من أساس أساس كيمية ال Easter هذا أساس الإبدال
+
+174
+00:15:52,110 --> 00:15:57,670
+في ال Easter أن المجموعة اللي بتفقد هي ال OR هذا
+
+175
+00:15:57,670 --> 00:16:01,830
+أساس أساس كيمية ال Easter و الإبدال فيه أن ال OR
+
+176
+00:16:01,830 --> 00:16:06,850
+هي المجموعة اللي بيصير إلها إبدال واضح فلو
+
+177
+00:16:06,850 --> 00:16:10,570
+جيبنالكم مسألة مكتوب فيها اتنين من هذا مع واحد
+
+178
+00:16:10,570 --> 00:16:16,500
+base و اكتبونا الناتجأو اتنين من هذا مع واحد base
+
+179
+00:16:16,500 --> 00:16:23,800
+اكتبوا الناتج بنفس المنطق يعني لازم نكتب المتفاعل
+
+180
+00:16:23,800 --> 00:16:28,500
+اللي موجود مرتين نكتبه مرتين جانب بعضه بنعمل ال
+
+181
+00:16:28,500 --> 00:16:32,560
+minus على alpha hydrogen بنحركه بحيث يعمل
+
+182
+00:16:32,560 --> 00:16:37,120
+substitution هذا هو التفاعل اللي اسمه Clayson
+
+183
+00:16:37,120 --> 00:16:43,330
+Condensation هو شبيه بالدول Condensation معادةإن
+
+184
+00:16:43,330 --> 00:16:47,430
+هذا التفاعل إيستارد والإيستارد تفاعل الأساسي
+
+185
+00:16:47,430 --> 00:16:55,010
+السبستوتيوشن والالديهيدس والكيتون نجلة
+
+186
+00:16:55,010 --> 00:17:00,650
+derivative تاني من أنواع مشتقات الأحماض اللي هي ال
+
+187
+00:17:00,650 --> 00:17:03,310
+acid halides
+
+188
+00:17:04,780 --> 00:17:12,960
+الـ Acid Hylides صغيرها العامة RCW.OX X ممكن تكون
+
+189
+00:17:12,960 --> 00:17:20,670
+كلور أو كرومحسب واضح بشكل عام ال acid halides تحضر
+
+190
+00:17:20,670 --> 00:17:26,250
+من تفاعل الحامض تفاعل الحامض مع بي CL3 لو كنت بدي
+
+191
+00:17:26,250 --> 00:17:31,670
+الchlor أو مع بي PR3 يعني Phosphorus Trichloride
+
+192
+00:17:31,670 --> 00:17:35,950
+أو Phosphorus Tribromide بشيل ال OH لاحظوا أنا
+
+193
+00:17:35,950 --> 00:17:39,170
+برضه مازلت بحكي عن حامض والحامض تفاعل الأساسي ال
+
+194
+00:17:39,170 --> 00:17:45,010
+substitution يعني كأن أنا بجيب CL و بطردالقواتش و
+
+195
+00:17:45,010 --> 00:17:47,830
+احنا قولنا كل chapter عشرة هذا هنظل نكرر فيه
+
+196
+00:17:47,830 --> 00:17:54,110
+substitution فإذا كان هذا اسمه acidic acid ال
+
+197
+00:17:54,110 --> 00:18:00,790
+chloride المتكون منه شو بيصير اسمه؟ Acetylchloride
+
+198
+00:18:00,790 --> 00:18:07,270
+هذي
+
+199
+00:18:07,270 --> 00:18:12,890
+المجموعة اللي هي CH3 سبق اتعرفنا عليها اسمها
+
+200
+00:18:12,890 --> 00:18:18,920
+مجموعةالاسيتل فمن الاسيتك أسد بتطلع استلكلوريد لو
+
+201
+00:18:18,920 --> 00:18:22,900
+كنت أكون ماشي على أي بكنوم name إيثانويك أسد
+
+202
+00:18:22,900 --> 00:18:29,780
+إيثانويل إكلوريد بس طبعا الشهرة أنه عندي أسيتك أسد
+
+203
+00:18:29,780 --> 00:18:34,920
+و أستلكلوريد طب لو قلتلكوا بده مركب بنزويل إكلوريد
+
+204
+00:18:37,610 --> 00:18:49,270
+بنزويك أسل مع Cl يعني أرسمولي شكل بنزويل Cl هاي
+
+205
+00:18:49,270 --> 00:18:57,710
+الـCOO جاية من بنزويك أسل مع Cl إذا وين مجموعة
+
+206
+00:18:57,710 --> 00:18:58,810
+البنزويل؟
+
+207
+00:19:01,040 --> 00:19:05,660
+هذه المجموعة ايش اسمها؟ Benzoy طب لو قلنالكوا بدنا
+
+208
+00:19:05,660 --> 00:19:10,600
+بنزل اكلوراي بنزل
+
+209
+00:19:10,600 --> 00:19:18,160
+اكلوراي مجموعة البنزل هي عبارة عن الفنل
+
+210
+00:19:28,890 --> 00:19:38,950
+بنزل وبنزويل بنزل بنزل بنزل بنزلفال بنزيل
+
+211
+00:19:38,950 --> 00:19:42,410
+الكلورايد غير البنزيل الكلورايد يعني لو في
+
+212
+00:19:42,410 --> 00:19:46,110
+المستقبل اشتغلتوا و عندكوا في مكان العمل تجربة هات
+
+213
+00:19:46,110 --> 00:19:49,290
+اتنين جرام بنزيل الكلورايد اتروح الواحدة على
+
+214
+00:19:49,290 --> 00:19:52,850
+المختبر بدون انتباه اجيب بنزيل الكلورايد هذا مركب
+
+215
+00:19:52,850 --> 00:19:57,810
+و هذا مركب هذا كيميا و هذا كيميا مختلفة تماما
+
+216
+00:19:57,810 --> 00:20:03,750
+بنزيل الكلورايد اشهر و بنزيل الكلورايد اشهر تاني
+
+217
+00:20:03,750 --> 00:20:09,200
+تماما واضح فاختبرالتوضيح
+
+218
+00:20:15,000 --> 00:20:21,900
+أهم شغلة في ال benzoyl chlorides كخواص أو ال acid
+
+219
+00:20:21,900 --> 00:20:27,720
+chlorides بشكل عام اللي هي نوكشيا يعني بتحرك و
+
+220
+00:20:27,720 --> 00:20:33,760
+عشان الجزء الكبير مانا يستخدم ك tear gases كغازات
+
+221
+00:20:33,760 --> 00:20:40,960
+مصيلة للدموع يعني ال benzoyl chloride نفسه اللي تو
+
+222
+00:20:40,960 --> 00:20:44,660
+كتبناها ده بيستخدم كغاز مصيل
+
+223
+00:20:50,930 --> 00:20:56,130
+الان كيف بيشتغل هذا يعني القالية اللي بيشتغل فيها
+
+224
+00:20:56,130 --> 00:21:01,510
+كغاز مثيل للدموع؟ بيجي على المناطق في الجسم اللي
+
+225
+00:21:01,510 --> 00:21:06,980
+فيها ميةبناء على ذلك لو حد كنا مساكرين راسه و إجا
+
+226
+00:21:06,980 --> 00:21:10,360
+غاز المسيل الدموع على رجله ولا على إيده بدون ميه
+
+227
+00:21:10,360 --> 00:21:16,520
+مافيش عنده مشكلة وين تأثيره؟ على العينان و المنخار
+
+228
+00:21:16,520 --> 00:21:24,140
+و الزواج إذا هو بتفاعل مع الميه طب بتفاعل مع الميه
+
+229
+00:21:24,140 --> 00:21:28,180
+شو بده يعمل؟ مرتين بده يعمل substitution أن الميه
+
+230
+00:21:28,180 --> 00:21:34,550
+تهاجم هنا و تطردالـ Cl بناء على ذلك اللي حيصير
+
+231
+00:21:34,550 --> 00:21:41,750
+عندي هذا سيرجع إلى C double bond O OH للحمض دل من
+
+232
+00:21:41,750 --> 00:21:50,470
+هنا عندي H ومن هنا Cl زائد HCl هذا
+
+233
+00:21:50,470 --> 00:21:54,090
+الـ HCl اللي بيطلع من تفاعل البنزويل الكلورايد مع
+
+234
+00:21:54,090 --> 00:21:56,710
+الميه هو اللي بيسبب الحرجان هو الحمض المعروف
+
+235
+00:21:56,710 --> 00:22:02,270
+بالنسبة لكمبملاحظين؟ إذا هم بدل ما يرشوا البني آدم
+
+236
+00:22:02,270 --> 00:22:07,410
+بـHCL بيروحوا برشوه بنزوي الكلورايت، بتفعل مع ميط
+
+237
+00:22:07,410 --> 00:22:11,930
+العين أو الزور، بيعطي بنزويك أسد، هذا حامض ضعيف،
+
+238
+00:22:11,930 --> 00:22:15,650
+خليني أقول بنزويك أسد، لكن بيعطي كمان HCL هو اللي
+
+239
+00:22:15,650 --> 00:22:20,190
+بيسبب المشاكل، واضح؟ عشان هيك، لو كنتي تسألوا
+
+240
+00:22:20,190 --> 00:22:23,290
+الناس اللي أكتر منكوا عايشوا الغازات المثيلة
+
+241
+00:22:23,290 --> 00:22:29,150
+للدموع، كانت الإشكالية فيها وين؟إن البني أدم يتعرض
+
+242
+00:22:29,150 --> 00:22:33,670
+للغاز، خلّص، خلّصنا من العينان و إشي، لابس نص كم و
+
+243
+00:22:33,670 --> 00:22:37,390
+وجهه، كله بيكون ملزج عليه الـ Benzoyl chloride،
+
+244
+00:22:37,390 --> 00:22:41,530
+لكن مش متأثر، بس إذا راح يتوضى و لا غسل شوية صغيرة
+
+245
+00:22:41,530 --> 00:22:45,490
+بمية و لا نزل عليه عراج، بيصير التفاعل و بيصير
+
+246
+00:22:45,490 --> 00:22:51,970
+جلده يحرقه، فكانت المشكلة إن الواحد يتوضى بعد
+
+247
+00:22:51,970 --> 00:22:58,590
+مظاهرةلازم إيش يعمل البني آدم؟ يغسل نفسه بصابونة و
+
+248
+00:22:58,590 --> 00:23:03,190
+بمية كبيرة وبشكير هيك مع صابونة ومية كبيرة بحيث
+
+249
+00:23:03,190 --> 00:23:07,190
+يخلص كل هذا أما وضوء عادي بمية خفيفة ولا العراج
+
+250
+00:23:07,190 --> 00:23:12,750
+ينزل على الجسم اللي عليه بنزوليكلورايد وجد البني
+
+251
+00:23:12,750 --> 00:23:21,870
+آدم بيصير في إيش؟ في المحضوروالله يفيكوا الشرط إذا
+
+252
+00:23:21,870 --> 00:23:25,850
+بتلاحظوا هنا ان ال acid chlorides they react
+
+253
+00:23:25,850 --> 00:23:29,630
+violently with water يعني بيتفاعلوا مع الميه بشكل
+
+254
+00:23:29,630 --> 00:23:37,390
+كبير جدا لما يتفاعلوا مع الميه شو بيعطوه الحمض
+
+255
+00:23:37,390 --> 00:23:47,810
+الكربوكسيلي زائد HCl وHCl هو سبب المشاكلبالمجمل ال
+
+256
+00:23:47,810 --> 00:23:51,570
+acid chloride هي من مشتقات الأحمض عشان يتفاعلها مع
+
+257
+00:23:51,570 --> 00:23:56,150
+أي نيوكليوفايل هو إبتال يعني هنا تلخيص للكلام اللي
+
+258
+00:23:56,150 --> 00:24:01,310
+حاكيناه لو بدى يتفاعل مع الميه بدا تهاجم و تطرد ال
+
+259
+00:24:01,310 --> 00:24:06,130
+CL لو بدى يتفاعل مع ال إيثانول بدا يهاجم و يطرد ال
+
+260
+00:24:06,130 --> 00:24:10,310
+CL لو بدا تتفاعل مع الأمونيب بدا تهاجم و تطرد ال
+
+261
+00:24:10,310 --> 00:24:13,450
+CL بناء على ذلك ال acid chloride مع الميه شو
+
+262
+00:24:13,450 --> 00:24:19,780
+بيعطيني؟الاسد اللي احنا حكيناه الاسد كلورايد مع
+
+263
+00:24:19,780 --> 00:24:26,540
+الاثانول هيحط بدل ال CL OR او O Ethan بهاد الحالة
+
+264
+00:24:26,540 --> 00:24:32,440
+اذا كنا محددينها بيعطينا ال T star والتفاعل مع
+
+265
+00:24:32,440 --> 00:24:38,000
+الأمونيا الامد اذا الاسد كلورايد مع الميه بيعطينا
+
+266
+00:24:38,000 --> 00:24:42,140
+اسد الاسد كلورايد مع ال alcohol T star الاسد
+
+267
+00:24:42,140 --> 00:24:46,720
+كلورايد مع الأمونياحمد، لاحظوا إنه إحنا كإينا
+
+268
+00:24:46,720 --> 00:24:51,770
+بندور بسلسلة مفرقةواضح؟ يعني لو رجعت أخدت ال E
+
+269
+00:24:51,770 --> 00:24:58,610
+star نفترض مع BCL3 هيرض يعطينا أيش؟ أسد كلورايد أو
+
+270
+00:24:58,610 --> 00:25:03,870
+أخدت ال acid مثلا مع ال .. زي ما شوفنا قبل شوية مع
+
+271
+00:25:03,870 --> 00:25:10,090
+ال BCL3 هيرض يعطينا أيش؟ أسد كلورايد فكأنه يعني في
+
+272
+00:25:10,090 --> 00:25:13,430
+كل هذا ال chapter عمال بنلوف حوالين فكرة واحد هي
+
+273
+00:25:13,430 --> 00:25:23,630
+فكرة أيش؟ كلمة واحدةSubstitution هي فكرة الـ
+
+274
+00:25:23,630 --> 00:25:32,250
+Substitution طيب
+
+275
+00:25:32,250 --> 00:25:37,430
+لو قلنا بدنا ال acid chloride تفاعل مع Green Yard
+
+276
+00:25:37,430 --> 00:25:38,230
+reagent
+
+277
+00:25:43,960 --> 00:25:48,580
+زي ال E star بالظبط موجودة في ال slide عندكم زي ال
+
+278
+00:25:48,580 --> 00:25:54,160
+E star بالظبط ان ال green yard بده يتفاعل عنده على
+
+279
+00:25:54,160 --> 00:26:00,700
+مرتين ال green yard مصدر لل R مع إلكتروناته بناء
+
+280
+00:26:00,700 --> 00:26:04,800
+على ذلك ال R بده تهاجم و ال CL بده تطلع في مرحلته
+
+281
+00:26:04,800 --> 00:26:12,420
+الأولى شو بيعطيني؟ كيتونبعد ذلك الـ R تهاجم مرة
+
+282
+00:26:12,420 --> 00:26:18,540
+تانية على الكيتون وتعمل إضافة في مرحلته التالية
+
+283
+00:26:18,540 --> 00:26:21,360
+بيعطي الـ tertiary alcohol سيبكم الأشياء اللي في
+
+284
+00:26:21,360 --> 00:26:26,540
+النص التوضيحية إذا زي ما ال Easter بتفاعل مع
+
+285
+00:26:26,540 --> 00:26:30,080
+Greenyard ع مرتين بيعطي في الأول كيتون وبعدين
+
+286
+00:26:30,080 --> 00:26:33,960
+tertiary alcohol ال acid chloride بتفاعل بنفس
+
+287
+00:26:33,960 --> 00:26:40,700
+الطريقة على مرتين بيعطي في الأول كيتون وبعدينالفرق
+
+288
+00:26:40,700 --> 00:26:43,660
+بين ال Easter و ال Acid Chloride انه في حالة ال
+
+289
+00:26:43,660 --> 00:26:46,840
+Easter كانت تفقد OR في حالة ال Acid Chloride تفقد
+
+290
+00:26:46,840 --> 00:26:54,880
+CL مع ذلك نفس النتيجة اذا احنا بنقدر نقول تفاعل ال
+
+291
+00:26:54,880 --> 00:26:59,360
+Acid Chloride مع excess green yard reagent
+
+292
+00:26:59,360 --> 00:27:04,800
+produces finallyTertiary Alcohol و ال reaction
+
+293
+00:27:04,800 --> 00:27:09,320
+بيمر عبر تكوين الكيتون تكوين الكيتون هو تفاعل
+
+294
+00:27:09,320 --> 00:27:13,220
+إبدال تكوين ال alcohol من الكيتون هو تفاعل
+
+295
+00:27:13,220 --> 00:27:19,180
+addition أو إضافة إذا هذا التفاعل موازي تماما
+
+296
+00:27:19,180 --> 00:27:22,420
+لتفاعل ال Easter eggs
+
+297
+00:27:31,100 --> 00:27:38,970
+مشتقة جديدة من مشتقات الأحماض الاسدUnhydrates
+
+298
+00:27:38,970 --> 00:27:44,150
+الاسد Unhydrates الاسد Unhydrates بنحصل عليها من
+
+299
+00:27:44,150 --> 00:27:49,970
+خلال أن نفعل جزيئين من الحامض جزيئين من الحامض مع
+
+300
+00:27:49,970 --> 00:27:54,870
+بعضهم البعض واضح؟ واحد منهم بيعمل كمستقبل و واحد
+
+301
+00:27:54,870 --> 00:27:59,190
+منهم بيعمل كأنه اليوكليوفايل بناء على ذلك هذا اللي
+
+302
+00:27:59,190 --> 00:28:03,490
+انتوا شايفينه مثلا جزيئ واحد من الحامض اتخيلوا انه
+
+303
+00:28:03,490 --> 00:28:11,570
+بيدفعل مع نفسهواضح؟ إذا أنا بفعل جزيئين من الحامض
+
+304
+00:28:11,570 --> 00:28:16,050
+مع بعض بسخن الحامض طبعا أنا بجيب الجزية بجيب كمية
+
+305
+00:28:16,050 --> 00:28:22,210
+حامض بسخنها في وجود H plus إضافة من الخارج شوية
+
+306
+00:28:22,210 --> 00:28:26,450
+الآن التفاعل اللي بده يتم هو تفاعل مرة تانية إبدال
+
+307
+00:28:26,450 --> 00:28:34,750
+إن واحد من الحامض بيجي بهاجم هنا وبيطرد الـ OHيعني
+
+308
+00:28:34,750 --> 00:28:39,190
+كإن واحد بيعمل كـ Nucleophile والثاني بيعمل كـ
+
+309
+00:28:39,190 --> 00:28:43,290
+Electrophile أو مستقبل لما يطرد الـ OH حيصير عند
+
+310
+00:28:43,290 --> 00:28:50,020
+هذا الجزء الأولاني CH3CW.Oومن الحمض التالي بيجيني
+
+311
+00:28:50,020 --> 00:28:56,580
+OCH3 هذا الشكل أو هذه المجموعة هي مجموعة ال
+
+312
+00:28:56,580 --> 00:29:00,960
+unhydrate ليش احنا بنقول unhydrate لأنه لما طردت
+
+313
+00:29:00,960 --> 00:29:07,940
+هذه ال OH مع ال H اللي من هنا، شو اعطوني؟مية فكأنه
+
+314
+00:29:07,940 --> 00:29:13,120
+أنا في تفاعل ال unhydrate خلطت جزيئين حامض مع بعض
+
+315
+00:29:13,120 --> 00:29:19,160
+شبكته في بعض و طلعت برا مية فمعنى unhydrate أن هذا
+
+316
+00:29:19,160 --> 00:29:25,110
+مخصوم منهمية مخصوم منه مية الصيغة العامة في شكل
+
+317
+00:29:25,110 --> 00:29:31,030
+عام لل unhydrate لل unhydrate C double bond O أو C
+
+318
+00:29:31,030 --> 00:29:35,450
+double bond O يعني لما بدي أطلع كمجموعة وظيفية
+
+319
+00:29:35,450 --> 00:29:39,930
+أجيبلكم مركب في C double bond O أو C double bond O
+
+320
+00:29:39,930 --> 00:29:45,790
+أقولكوا ما عائلة هذا المركب unhydrateواضح
+
+321
+00:29:45,790 --> 00:29:50,510
+فالمجموعة الوظيفية تبعت الانهيدريد C double bond O
+
+322
+00:29:50,510 --> 00:29:57,390
+O C double bond O الان بيظل على الأطراف ال R اللي
+
+323
+00:29:57,390 --> 00:30:03,330
+جاية من الحامض في هذه الحالة هتلاحظوا ان
+
+324
+00:30:03,330 --> 00:30:09,270
+الكيميائين عندهم طرق فنية ممكن يخلوا الحامض يتفاعل
+
+325
+00:30:09,270 --> 00:30:13,690
+مع نفسه إذا الحامض اتفاعل مع نفسه هتكون مجموعتي ال
+
+326
+00:30:13,690 --> 00:30:19,320
+R هدولةزي بعض نفسهم بيصير عندي symmetrical
+
+327
+00:30:19,320 --> 00:30:23,980
+anhydride يعني anhydride إيش ماله متمثل فإذا كان
+
+328
+00:30:23,980 --> 00:30:28,760
+هذا اسم الحامض acetic acid ال anhydride اللي منه
+
+329
+00:30:28,760 --> 00:30:37,780
+شو بيكون اسمه acetic anhydride طبعا هو كاتبه بصيغة
+
+330
+00:30:37,780 --> 00:30:41,900
+ethanoic acid ethanoic anhydride نفس الفكرة بس
+
+331
+00:30:41,900 --> 00:30:49,970
+الأشهر أن هذا الحامضحمد الخد ايش اسمه؟ Acetic Acid
+
+332
+00:30:49,970 --> 00:30:55,530
+و الانهيدريد اللي بنشأ منه Acetic Anhydride الان
+
+333
+00:30:55,530 --> 00:31:00,310
+ال Acetic Anhydride is a symmetrical anhydride ايش
+
+334
+00:31:00,310 --> 00:31:04,550
+يعني symmetrical anhydride؟ متمثل يعني مجموعتي ال
+
+335
+00:31:04,550 --> 00:31:12,530
+R اللي موجودة عليه نفس الشيءمجموعتي ال R اللي
+
+336
+00:31:12,530 --> 00:31:16,650
+موجودة عليه نفس الاشي فتسميته سهلة بناخد اسم
+
+337
+00:31:16,650 --> 00:31:23,370
+الحامض acidic بس بدل كلمة acid تستبدل كلمة acid
+
+338
+00:31:23,370 --> 00:31:29,070
+بكلمة unhydrate هذا في حالة ما احكي عن unhydrate
+
+339
+00:31:29,070 --> 00:31:37,630
+متمثل بشيل كلمة acid و بحط مكانها unhydrate
+
+340
+00:31:50,350 --> 00:31:55,330
+لاحظوا أنه في التفاعل السابق كان عندي جزيين حامض
+
+341
+00:31:55,330 --> 00:31:58,510
+مفصلات عن بعض، عشان ذلك التفاعل بسميه
+
+342
+00:31:58,510 --> 00:32:02,750
+Intermolecular ولا Intramolecular؟ Intermolecular،
+
+343
+00:32:02,750 --> 00:32:05,930
+بين جزيين مختلفين، يعني هذه حامض وهذه حامض،
+
+344
+00:32:05,930 --> 00:32:13,250
+واتفاعلوا مع بعض وفقدواالان ممكن يكون عندى حامض او
+
+345
+00:32:13,250 --> 00:32:18,430
+مركب فيه جزيين الحامض مع بعض ومر عليا امثلة مثلا
+
+346
+00:32:18,430 --> 00:32:22,070
+هذا المركب اللى فيه ضب البود لبيوتين واحد اتنين
+
+347
+00:32:22,070 --> 00:32:28,210
+تلاتة اربعة مر عليا الحامض ايش اسمه مليك اسد بناء
+
+348
+00:32:28,210 --> 00:32:32,970
+على ذلك هذا المليك اسد لو سخنته 135 درجه موية هذه
+
+349
+00:32:32,970 --> 00:32:37,730
+بتتفعل هنا و بتتردالـ OH طبعا الـ OH مع ال H اللي
+
+350
+00:32:37,730 --> 00:32:42,350
+هانا هيكونوله مية بتكون هذا المركب ايش اسم هذا
+
+351
+00:32:42,350 --> 00:32:48,670
+المركب ماليك أنهيدريد إذا الماليك أسد اللي هو
+
+352
+00:32:48,670 --> 00:32:53,510
+عبارة عن داي أسد اتفاعل ماتعطيني ماليك أنهيدريد
+
+353
+00:32:53,510 --> 00:32:56,710
+هذا ال reaction الآن Intermolecular ولا
+
+354
+00:32:58,580 --> 00:33:02,440
+Intramolecular يعني جوا الجزئ الشغلتين المتفاعلات
+
+355
+00:33:02,440 --> 00:33:08,200
+Intramolecular reaction واضح؟ وشبيه تماما في ..
+
+356
+00:33:08,200 --> 00:33:11,660
+شبيه تماما في هذا الحامض اللي هو البنزين اللي عليه
+
+357
+00:33:11,660 --> 00:33:15,760
+مجموعتين حمض جانب بعض أخدنا اسمه .. مين متذكرة
+
+358
+00:33:15,760 --> 00:33:19,740
+اسمه؟
+
+359
+00:33:19,740 --> 00:33:24,680
+مين متذكرة؟ Phthalic Anhydrate
+
+360
+00:33:27,800 --> 00:33:32,080
+الان ارجعوا على ال بنزير افتاليك اسد ارجعوا على
+
+361
+00:33:32,080 --> 00:33:35,140
+البنزير بتلاقيوا اخدنا الحامض اذا المجموع تحت جانب
+
+362
+00:33:35,140 --> 00:33:40,380
+بعض اسمه افتاليك اسد و اذا بيفرجوا على الميتا
+
+363
+00:33:40,380 --> 00:33:44,900
+ايزوفتاليك اسد و اذا على البارا تيرفتاليك اسد احنا
+
+364
+00:33:44,900 --> 00:33:49,640
+قولنا اقل تقدير لازم تحفظوا شكل الافتاليك اسد الان
+
+365
+00:33:49,640 --> 00:33:53,060
+لو قولنالكم في الامتحان و رسمونا افتاليك انهيدرايد
+
+366
+00:33:53,060 --> 00:34:00,150
+كيف هترسموه؟أجاكوا سؤال ارسم أفثاليك أنهيجرايت
+
+367
+00:34:00,150 --> 00:34:06,250
+واحدة من هدولة بدها تاجم على ال CW Bond O و تترد
+
+368
+00:34:06,250 --> 00:34:14,450
+ال OH بناء على ذلك هيكون شبيه جدا
+
+369
+00:34:14,450 --> 00:34:16,890
+في المركب اللي فوق CW Bond O
+
+370
+00:34:19,460 --> 00:34:24,460
+هو high-lithalic anhydride، إذن، Lithalic acid
+
+371
+00:34:24,460 --> 00:34:27,440
+بيعطي Lithalic anhydride، برضه هذا التفاعل
+
+372
+00:34:27,440 --> 00:34:32,460
+Intermolecular ولا Intramolecular؟ Intramolecular،
+
+373
+00:34:32,460 --> 00:34:36,380
+مجموعتين حامض، في داخل الجزء، بكثفهم دول
+
+374
+00:34:36,380 --> 00:34:42,200
+المجموعتين مع بعضهم البعض، واضح؟ سواء بال-malic
+
+375
+00:34:42,200 --> 00:34:45,840
+acid ولا بال-lithalic acid
+
+376
+00:34:50,440 --> 00:34:53,700
+طبعا لو أخدت حامض تاني زي الاسيتك أسد ايش ما كان
+
+377
+00:34:53,700 --> 00:34:59,500
+يكون و سخنته بتفعل مع بعضه لكن انتر موليكولار
+
+378
+00:34:59,500 --> 00:35:04,680
+جزيين مختلفة طيب بيجيلي السؤال عاد لو بدي
+
+379
+00:35:04,680 --> 00:35:07,900
+unhydrate انسمتريكل
+
+380
+00:35:09,640 --> 00:35:14,140
+يعني بدي أجي على هذه المجموعة الوظيفية تبع
+
+381
+00:35:14,140 --> 00:35:19,160
+ترانهيدريد هذي مش موضع خلاف بس بديش أحط ال R اللي
+
+382
+00:35:19,160 --> 00:35:25,020
+هان و اللي هان زي بعض مثلا
+
+383
+00:35:25,020 --> 00:35:34,460
+بدي هنا مجموعة مثل وهنا مجموعة propyl هملاحظين مثل
+
+384
+00:35:34,460 --> 00:35:41,570
+و propylكيف تحضره؟ تتذكره مثلًا لما أخذنا الأمثلة
+
+385
+00:35:41,570 --> 00:35:47,670
+على تحضير الـ Unsymmetrical Ether لما أخذنا الـ
+
+386
+00:35:47,670 --> 00:35:51,270
+Unsymmetrical Ether لو أخذتوا two alcohol و سخنتوه
+
+387
+00:35:51,270 --> 00:35:55,680
+مع بعض، يظهر عندكم كام ناتج؟تلاتة لأ في ال
+
+388
+00:35:55,680 --> 00:35:58,420
+aldehyde بيطلع أربعة في ال aldehydes لو كنتوا
+
+389
+00:35:58,420 --> 00:36:01,980
+بتكونوا تعملوا aldol reaction الآن هنا لو أخدت
+
+390
+00:36:01,980 --> 00:36:06,620
+الحامض تبع ال butane واحد اتنين تلاتة أربعة و
+
+391
+00:36:06,620 --> 00:36:10,440
+الحامض تبع ال acetic و سخنته مع بعض كام ناتج بتوقع
+
+392
+00:36:10,440 --> 00:36:15,130
+يطلع عنده؟تلاتة أن الـ butanoic acid يتفاعل مع
+
+393
+00:36:15,130 --> 00:36:18,890
+نفسه يعطينا butanoic anhydride و ال acetic acid
+
+394
+00:36:18,890 --> 00:36:21,790
+يتفاعل مع نفسه يعطينا acetic anhydride أو واحد من
+
+395
+00:36:21,790 --> 00:36:24,970
+هدول يتفاعل مع التاني يعطينا ال mix طبعا هذا كلام
+
+396
+00:36:24,970 --> 00:36:30,500
+عمليهذا كلام غير عملي إطلاقاً طب هى إيش بيعملوا
+
+397
+00:36:30,500 --> 00:36:35,960
+بيجيبوا شق من هدول الاتنين شكل acid chloride وشق
+
+398
+00:36:35,960 --> 00:36:40,820
+على شكل ملح الحامض يعني واحد فيه O minus و واحد
+
+399
+00:36:40,820 --> 00:36:45,980
+فيه chloride أو ممكن E start الآن لما نفعل ال acid
+
+400
+00:36:45,980 --> 00:36:50,720
+chloride مع السلطة هذه ال O minus إلا بس احتمال
+
+401
+00:36:50,720 --> 00:36:58,290
+وحيد إنها تاجم هنا و تطلط ال CLتحضير الـ Mixed
+
+402
+00:36:58,290 --> 00:37:02,750
+Anhydride من خلال تفاعل الـ Acidic Chloride مع
+
+403
+00:37:02,750 --> 00:37:08,350
+الكربوكسيلات أنيون هذا ليس اسمه كربوكسيلات أنيون
+
+404
+00:37:08,350 --> 00:37:13,390
+يعني هذا الصوديوم ايش بنسميها؟ اسيتات خلّات
+
+405
+00:37:13,390 --> 00:37:17,390
+الصوديوم صوديوم أسيتات من أين جايبنا من الاسيتك
+
+406
+00:37:17,390 --> 00:37:20,490
+أسد مع الصوديوم هيدروكسيد يعطينا صوديوم أسيتات
+
+407
+00:37:20,490 --> 00:37:27,150
+تحضير الـ Mixed Anhydride من خلال تفاعلأسد كلورايت
+
+408
+00:37:27,150 --> 00:37:34,950
+بنفعل E star بنفعل E star لأن أنا سواء طردت CL ولا
+
+409
+00:37:34,950 --> 00:37:43,470
+طردت OR مفرد 100 انتي مع الكاربوكسيلات انايون اللي
+
+410
+00:37:43,470 --> 00:37:49,630
+هو الايون السالب الايون السالب للحمد في هذه الحالة
+
+411
+00:37:49,630 --> 00:37:50,710
+بنقول بنفعل
+
+412
+00:37:53,630 --> 00:37:57,470
+اللي هو الـ butanoic acid اللي هو الـ butanoic
+
+413
+00:37:57,470 --> 00:38:03,550
+أكلورا .. ال butanoil أكلورايد مع مثلا ال sodium
+
+414
+00:38:03,550 --> 00:38:07,810
+acetate هذا بيعمل ال nucleophile وهذا بيعمل ال
+
+415
+00:38:07,810 --> 00:38:13,210
+substitution بيطلع عنده ال unsymmetrical anhydride
+
+416
+00:38:13,210 --> 00:38:18,950
+أو مجرد بيسموه إيش mixed anhydride يعني مش جاي من
+
+417
+00:38:18,950 --> 00:38:23,920
+نفس النوع، هاي هذا أزرق و أزرق، هذاSymmetrical لكن
+
+418
+00:38:23,920 --> 00:38:29,660
+لما نعمل زي هيك mixed unhydrate واضح فالمixed
+
+419
+00:38:29,660 --> 00:38:35,700
+unhydrate ماقدرش أحضره أنه أخد الحمضين و أسخنهم في
+
+420
+00:38:35,700 --> 00:38:42,420
+وجود H plus و إلا بيطلع عندى كام ناتجزي الـ
+
+421
+00:38:42,420 --> 00:38:45,840
+unsymmetrical ether، لو أخدتي الكحولين و سخلتهم مع
+
+422
+00:38:45,840 --> 00:38:49,880
+بعض، كام نتيجة كانت بتطلع عندك؟ تلاتة، بتلاحظوا أن
+
+423
+00:38:49,880 --> 00:38:53,300
+الأفكار في الأوريجان ال chemistry نوعا ما بتصير،
+
+424
+00:38:53,300 --> 00:38:57,920
+اتكرر بعض، بس المهمين يتذكرها
+
+425
+00:39:08,420 --> 00:39:13,040
+طبعا لو كنا بدنا نسمي .. لو كنا بدنا نسمي ال mixed
+
+426
+00:39:13,040 --> 00:39:19,140
+anhydride احنا سمينا ال symmetrical مثلا هذا جاي
+
+427
+00:39:19,140 --> 00:39:22,960
+من ال benzoic acid هاي ال anhydride group جاي من
+
+428
+00:39:22,960 --> 00:39:27,940
+benzoic acid شو بنسميه؟ Benzoic anhydride هذا جاي
+
+429
+00:39:28,810 --> 00:39:35,530
+كربونة تنتين تلاتة من البروبانويك أسد بروبانويك
+
+430
+00:39:35,530 --> 00:39:38,290
+أنهيدريد هذا الـ symmetrical أخدنا طب لما يكون
+
+431
+00:39:38,290 --> 00:39:47,170
+unsymmetrical بصير عندي غير الانهيدريد مجموعتين
+
+432
+00:39:48,640 --> 00:39:52,740
+بهذه الحالة بدي أذكر المجموعتين أو الحامضين اللي
+
+433
+00:39:52,740 --> 00:39:59,160
+اتكوّن منهم هذا الحامض شو أصله؟ CH3C أسيتيك وهذا
+
+434
+00:39:59,160 --> 00:40:04,520
+الحامض C double bond O بنزويك فكله بنقول أسيتيك
+
+435
+00:40:04,520 --> 00:40:09,480
+بنزويك أنهيدريد أنه هو الانهيدريد اللي جاي من
+
+436
+00:40:09,480 --> 00:40:14,660
+الاسيتيك أسد و البنزويك أسد و بنذكرهم alphabetical
+
+437
+00:40:14,660 --> 00:40:21,730
+يعني A قبل ال Bacetic benzoic anhydride إذا بنذكر
+
+438
+00:40:21,730 --> 00:40:25,910
+في حالة ما يكون متماثل اسم الحمض مرة واحدة طب غير
+
+439
+00:40:25,910 --> 00:40:32,150
+متماثل بنذكر الحامضين alphabetical فإذا كان مكوّن
+
+440
+00:40:32,150 --> 00:40:36,370
+من الacetic acid مع الbenzoic acid بيكون acetic
+
+441
+00:40:36,370 --> 00:40:39,950
+benzoic anhydride الآن لو قلتلكوا هذا كيف نحطه
+
+442
+00:40:39,950 --> 00:40:43,930
+يعني جيبناه في الامتحان وقلنالكوا how can you
+
+443
+00:40:43,930 --> 00:40:47,030
+prepare this compound شو هتعمله؟
+
+444
+00:40:49,660 --> 00:40:58,580
+واحد منهم هتاخده على شكل اكلورايد والتاني على شكل
+
+445
+00:40:58,580 --> 00:41:07,100
+ايون سالب مشقولنا اكلورايد مع ايون سالب واعدي
+
+446
+00:41:07,100 --> 00:41:11,580
+كلورايد والتاني ايون سالب هذه بتهاجم هنا وبتطرد
+
+447
+00:41:14,410 --> 00:41:18,870
+اكلورايد زائد انايون اكلورايد زائد انايون بيعطينا
+
+448
+00:41:18,870 --> 00:41:28,290
+ال mix unhydrate عشان
+
+449
+00:41:28,290 --> 00:41:32,010
+بس نقف عند ال amides المرعن هادر هي تفاعل ال
+
+450
+00:41:32,010 --> 00:41:40,430
+unhydrate هتلاحظوا شغل ان تفاعل ال unhydrate موازي
+
+451
+00:41:41,910 --> 00:41:45,490
+للتفاعلات السابقة، تفاعل الـ anhydride موازي
+
+452
+00:41:45,490 --> 00:41:50,030
+للتفاعلات السابقة، يعني ممكن أفعل مع الميه، مع
+
+453
+00:41:50,030 --> 00:41:53,110
+الالكول، مع الأمونيا، في كل الأحوال، شو التفاعل
+
+454
+00:41:53,110 --> 00:41:56,710
+اللي بيعمل إياه؟ Substitution، يعني كأني بجيب هذه،
+
+455
+00:41:56,710 --> 00:42:01,470
+اتهاجم هنا، و باترد هذهأو بجيب ال R هذى تاجم هنا
+
+456
+00:42:01,470 --> 00:42:05,410
+وبطرد هذى أو بجيب ال ammonia تاجم هنا وبطرد كل
+
+457
+00:42:05,410 --> 00:42:12,590
+المجموعة اللى هى OCH3 بناء عدلك ال unhydrate مع
+
+458
+00:42:12,590 --> 00:42:17,010
+الميه برجع acid مع ال alcohol بصير yeast مع ال
+
+459
+00:42:17,010 --> 00:42:22,850
+ammonia بصير amide لاعظم التفاعلات بشكل كبير
+
+460
+00:42:22,850 --> 00:42:31,740
+متوازية أخر تفاعل اللى بنحكيهاللي هو تفاعل تحضير
+
+461
+00:42:31,740 --> 00:42:36,840
+الاسبيرين وربما مر معاكوا في المعمل انتوا باخدتوش
+
+462
+00:42:36,840 --> 00:42:41,320
+معمل الاسبيرين بيحضروه من خلال تفاعل الاسيتك
+
+463
+00:42:41,320 --> 00:42:45,580
+أنهيدريد مع هذا الحامض اللي اسمه salicylic acid
+
+464
+00:42:45,580 --> 00:42:50,000
+بالمحصلة هذا الحامض يمثل ال nucleophile هذا ال
+
+465
+00:42:50,000 --> 00:42:56,190
+nucleophile ييجي يهاجم هنا ويطردهذه المجموعة فبصير
+
+466
+00:42:56,190 --> 00:43:02,250
+عند ال salicylic acid C double bond O CH3 فبنسمي
+
+467
+00:43:02,250 --> 00:43:09,790
+الأسبيرين أسيتو أسيتو سالي سيليك أسيتو أسيتو سالي
+
+468
+00:43:09,790 --> 00:43:14,730
+سيليك أسيتو أسيتو
+
+469
+00:43:14,730 --> 00:43:18,510
+سالي سيليك أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو
+
+470
+00:43:18,510 --> 00:43:18,670
+أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو
+
+471
+00:43:18,670 --> 00:43:18,730
+أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو
+
+472
+00:43:18,730 --> 00:43:19,840
+أسيتو أسيتو أسيتو أسيتو أسيتو أسيتو أسيتشبيهة
+
+473
+00:43:19,840 --> 00:43:25,220
+بكلمة الصفصاف هذا ال salicylic acid بيطلو من شجر
+
+474
+00:43:25,220 --> 00:43:30,600
+الصفصاف وهو اللي بيستعمل كدوة ضد الصداع لكن بيكون
+
+475
+00:43:30,600 --> 00:43:35,860
+بيشعط المعدة أو بيحرق المعدة فعشان يحسنوا خواصه
+
+476
+00:43:35,860 --> 00:43:39,280
+بفعلوه مع ال acidic anhydride بدل ما ياخدوا
+
+477
+00:43:39,280 --> 00:43:45,520
+salicylic acid مباشرة بياخدوه على شكلأسيتو
+
+478
+00:43:45,520 --> 00:43:48,940
+ساليسيليك أسد يدخل على الأمعاء و يبقى أسيتو
+
+479
+00:43:48,940 --> 00:43:52,440
+ساليسيليك أسد أو على المعدة أول من ينزل على
+
+480
+00:43:52,440 --> 00:43:56,780
+الأمعاء في وسط قلوة بيرد بيرجع لساليسيليك أسد و
+
+481
+00:43:56,780 --> 00:44:01,300
+الساليسيليك أسد هو اللي بعالج الصداع واضح؟ إذا أنا
+
+482
+00:44:01,300 --> 00:44:06,580
+كأني حولت الساليسيليك أسد ل أسبيرين ليش؟ لأن
+
+483
+00:44:06,580 --> 00:44:10,500
+الساليسيليك أسد بحرج المعدة بناء على ذلك بحاوله
+
+484
+00:44:10,500 --> 00:44:15,520
+لإيش؟لأسبيرين أخدت الأسبيرين بنزل على المعدة بيضله
+
+485
+00:44:15,520 --> 00:44:20,980
+أسبيرين بيروح على المعاق بيرجع ساليسيليك أسد و
+
+486
+00:44:20,980 --> 00:44:26,620
+الساليسيليك أسد اللي بعالج الصداع واضح فلاحظوا بس
+
+487
+00:44:26,620 --> 00:44:30,820
+لأن المرور في المعدة حساس بنشعه يحرج المعدة بنحول
+
+488
+00:44:30,820 --> 00:44:34,720
+الساليسيليك أسد إلى أسبيرين أو أسيتوساليسيليك أسد
+
+489
+00:44:34,720 --> 00:44:40,680
+في الأمعاق بيرجع بيصيربرجع بصير salicylic acid
+
+490
+00:44:40,680 --> 00:44:46,420
+ابهيك بنقف احنا عند ال amides ماشي؟
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..7c4c309284034f8d82c787100f652908c9d6dbd8
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/eNQz8ZvnaMo_raw.json
@@ -0,0 +1 @@
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12, "seek": 31489, "start": 288.35, "end": 314.89, "text": "بنسبة مضاعفة أو كاتب excess المفروض لو بدى اجيب اكمال معادلة شغلة زي هيك بس يكون عندى هذا الجواب اللى هنا انه green yard اتفعل مرتين كل هذه الأشياء بهمنيش اشوفها واضح كل هذه الأشياء بهمنيش اشوفها لما اقولكم complete the following equation حطلكوا فراغ green yard مع easter green yard excess مع easter", "tokens": [3555, 1863, 35457, 3660, 3714, 11242, 45761, 5172, 3660, 34051, 9122, 9307, 3555, 9310, 9673, 5172, 32887, 11242, 45164, 47525, 7578, 1975, 7435, 1829, 3555, 1975, 24793, 6027, 20449, 18513, 37977, 13412, 17082, 37977, 30767, 1829, 39896, 4117, 4724, 3794, 7251, 30544, 43242, 7578, 23758, 25724, 14407, 3555, 13672, 7578, 34105, 16472, 3224, 3092, 11682, 1975, 2655, 5172, 30241, 3714, 43500, 9957, 28242, 29538, 16247, 8592, 1829, 16606, 4724, 16095, 22653, 8592, 1975, 8592, 38688, 11296, 4032, 46958, 5016, 28242, 29538, 16247, 8592, 1829, 16606, 4724, 16095, 22653, 8592, 1975, 8592, 38688, 11296, 5296, 15042, 1975, 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306.57, "end": 306.77, "word": " هذه", "probability": 0.9638671875}, {"start": 306.77, "end": 307.09, "word": " الأشياء", "probability": 0.991943359375}, {"start": 307.09, "end": 307.45, "word": " بهمنيش", "probability": 0.96728515625}, {"start": 307.45, "end": 307.67, "word": " اشوفها", "probability": 0.9456787109375}, {"start": 307.67, "end": 307.85, "word": " لما", "probability": 0.7344970703125}, {"start": 307.85, "end": 308.23, "word": " اقولكم", "probability": 0.7254231770833334}, {"start": 308.23, "end": 308.65, "word": " complete", "probability": 0.83349609375}, {"start": 308.65, "end": 308.87, "word": " the", "probability": 0.8701171875}, {"start": 308.87, "end": 309.13, "word": " following", "probability": 0.80615234375}, {"start": 309.13, "end": 309.69, "word": " equation", "probability": 0.958984375}, {"start": 309.69, "end": 310.27, "word": " حطلكوا", "probability": 0.491943359375}, {"start": 310.27, "end": 310.81, "word": " فراغ", "probability": 0.846923828125}, {"start": 310.81, "end": 311.49, "word": " green", "probability": 0.282470703125}, {"start": 311.49, "end": 311.91, "word": " yard", "probability": 0.8896484375}, {"start": 311.91, "end": 312.17, "word": " مع", "probability": 0.85595703125}, {"start": 312.17, "end": 312.83, "word": " easter", "probability": 0.61370849609375}, {"start": 312.83, "end": 313.37, "word": " green", "probability": 0.59619140625}, {"start": 313.37, "end": 313.67, "word": " yard", "probability": 0.94580078125}, {"start": 313.67, "end": 314.07, "word": " excess", "probability": 0.8056640625}, {"start": 314.07, "end": 314.37, "word": " مع", "probability": 0.98974609375}, {"start": 314.37, "end": 314.89, "word": " easter", "probability": 0.86083984375}], "temperature": 1.0}, {"id": 13, "seek": 32213, "start": 315.65, "end": 322.13, "text": "ترتشر ألكول بمجموعتين الـR اللي جايين من الـgreen yard reagent", "tokens": [2655, 2288, 2655, 8592, 2288, 5551, 23275, 12610, 4724, 2304, 7435, 2304, 2407, 34268, 9957, 2423, 39184, 49, 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"probability": 0.6141357421875}], "temperature": 1.0}, {"id": 14, "seek": 35697, "start": 334.01, "end": 356.97, "text": "من تفاعلات ال E stars اللي هي ايضا تفاعلات ابدال اللي بنسميها ال ammonolysis التفاعل مع ال ammonia لو اتطلعنا ال ammonia نيوكليوفايد بنفس المبدأ بتتفاعل و تبرد ال OR حيث ان عندي RC ضو ال bond O and H2 من ال ammonia بناء على ذلك ال E star مع ال ammonia بيعطيني", "tokens": [27842, 6055, 5172, 995, 30241, 9307, 2423, 462, 6105, 13672, 1829, 39896, 1975, 1829, 11242, 995, 6055, 5172, 995, 30241, 9307, 1975, 44510, 6027, 13672, 1829, 44945, 38251, 1829, 11296, 2423, 36431, 401, 4642, 16712, 5172, 995, 30241, 20449, 2423, 46833, 45164, 1975, 2655, 9566, 1211, 3615, 8315, 2423, 46833, 8717, 1829, 2407, 4117, 20292, 38688, 995, 25708, 44945, 36178, 9673, 44510, 10721, 39894, 2655, 5172, 995, 30241, 4032, 6055, 26890, 3215, 2423, 19654, 11331, 1829, 12984, 16472, 18871, 16254, 28987, 48812, 2407, 2423, 6086, 422, 293, 389, 17, 9154, 2423, 46833, 44945, 16606, 15844, 29910, 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{"start": 338.59, "end": 339.09, "word": " اللي", "probability": 0.9228515625}, {"start": 339.09, "end": 339.63, "word": " بنسميها", "probability": 0.808837890625}, {"start": 339.63, "end": 339.71, "word": " ال", "probability": 0.70068359375}, {"start": 339.71, "end": 340.59, "word": " ammonolysis", "probability": 0.3262125651041667}, {"start": 340.59, "end": 341.27, "word": " التفاعل", "probability": 0.91796875}, {"start": 341.27, "end": 341.49, "word": " مع", "probability": 0.9921875}, {"start": 341.49, "end": 341.71, "word": " ال", "probability": 0.57568359375}, {"start": 341.71, "end": 342.31, "word": " ammonia", "probability": 0.66357421875}, {"start": 342.31, "end": 343.17, "word": " لو", "probability": 0.7939453125}, {"start": 343.17, "end": 344.05, "word": " اتطلعنا", "probability": 0.7286783854166666}, {"start": 344.05, "end": 344.17, "word": " ال", "probability": 0.896484375}, {"start": 344.17, "end": 344.53, "word": " ammonia", "probability": 0.9697265625}, {"start": 344.53, "end": 345.39, "word": " نيوكليوفايد", "probability": 0.704833984375}, {"start": 345.39, "end": 345.77, "word": " بنفس", "probability": 0.970947265625}, {"start": 345.77, "end": 346.19, "word": " المبدأ", "probability": 0.96728515625}, {"start": 346.19, "end": 346.99, "word": " بتتفاعل", "probability": 0.82421875}, {"start": 346.99, "end": 347.11, "word": " و", "probability": 0.8310546875}, {"start": 347.11, "end": 347.57, "word": " تبرد", "probability": 0.7596028645833334}, {"start": 347.57, "end": 347.83, "word": " ال", "probability": 0.55322265625}, {"start": 347.83, "end": 348.31, "word": " OR", "probability": 0.59912109375}, {"start": 348.31, "end": 348.95, "word": " حيث", "probability": 0.83154296875}, {"start": 348.95, "end": 349.07, "word": " ان", "probability": 0.494873046875}, {"start": 349.07, "end": 349.29, "word": " عندي", "probability": 0.67626953125}, {"start": 349.29, "end": 349.69, "word": " RC", "probability": 0.436279296875}, {"start": 349.69, "end": 349.95, "word": " ضو", "probability": 0.25750732421875}, {"start": 349.95, "end": 350.07, "word": " ال", "probability": 0.17822265625}, {"start": 350.07, "end": 350.29, "word": " bond", "probability": 0.428466796875}, {"start": 350.29, "end": 350.73, "word": " O", "probability": 0.90771484375}, {"start": 350.73, "end": 351.65, "word": " and", "probability": 0.42529296875}, {"start": 351.65, "end": 352.15, "word": " H2", "probability": 0.912353515625}, {"start": 352.15, "end": 352.39, "word": " من", "probability": 0.98486328125}, {"start": 352.39, "end": 352.55, "word": " ال", "probability": 0.89208984375}, {"start": 352.55, "end": 352.93, "word": " ammonia", "probability": 0.98193359375}, {"start": 352.93, "end": 353.31, "word": " بناء", "probability": 0.741455078125}, {"start": 353.31, "end": 353.53, "word": " على", "probability": 0.60693359375}, {"start": 353.53, "end": 353.97, "word": " ذلك", "probability": 0.993896484375}, {"start": 353.97, "end": 354.19, "word": " ال", "probability": 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H مع أزواج الإلكترونات", "tokens": [6027, 39184, 389, 20449, 5551, 11622, 2407, 26108, 33688, 23275, 2655, 2288, 11536, 9307], "avg_logprob": -0.34895833730697634, "compression_ratio": 0.8545454545454545, "no_speech_prob": 0.0, "words": [{"start": 412.52, "end": 412.86, "word": "الـ", "probability": 0.63330078125}, {"start": 412.86, "end": 413.08, "word": " H", "probability": 0.84716796875}, {"start": 413.08, "end": 413.5, "word": " مع", "probability": 0.344482421875}, {"start": 413.5, "end": 415.16, "word": " أزواج", "probability": 0.85986328125}, {"start": 415.16, "end": 415.96, "word": " الإلكترونات", "probability": 0.8333333333333334}], "temperature": 1.0}, {"id": 18, "seek": 45042, "start": 424.84, "end": 450.42, "text": "Hydride anion الليثيوم الومنوم هيدرايد هذا مصدر الهيدرايد انايون ايش اللي بيعملوا في ال reduction؟ اذا بتقدروا تطلعوا عمل شبيه جدا بمتفاعل جرينيار اتذكروا في ايه؟ الجرينيار اتفاعل ال a star اتفاعل ال a star مع ال R minus مرتين وال O صارت", "tokens": [39, 6655, 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0.8548583984375}, {"start": 440.46, "end": 441.36, "word": " الجرينيار", "probability": 0.861328125}, {"start": 441.36, "end": 442.44, "word": " اتفاعل", "probability": 0.94833984375}, {"start": 442.44, "end": 442.78, "word": " ال", "probability": 0.8935546875}, {"start": 442.78, "end": 443.12, "word": " a", "probability": 0.1488037109375}, {"start": 443.12, "end": 443.48, "word": " star", "probability": 0.0205078125}, {"start": 443.48, "end": 444.9, "word": " اتفاعل", "probability": 0.77587890625}, {"start": 444.9, "end": 445.1, "word": " ال", "probability": 0.900390625}, {"start": 445.1, "end": 445.36, "word": " a", "probability": 0.93896484375}, {"start": 445.36, "end": 445.7, "word": " star", "probability": 0.87353515625}, {"start": 445.7, "end": 446.16, "word": " مع", "probability": 0.947265625}, {"start": 446.16, "end": 446.38, "word": " ال", "probability": 0.84521484375}, {"start": 446.38, "end": 446.62, "word": " R", "probability": 0.490478515625}, {"start": 446.62, "end": 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{"start": 474.98, "end": 475.12, "word": " يعني", "probability": 0.860107421875}, {"start": 475.12, "end": 475.38, "word": " لما", "probability": 0.8759765625}, {"start": 475.38, "end": 475.74, "word": " اجي", "probability": 0.7750651041666666}, {"start": 475.74, "end": 475.88, "word": " في", "probability": 0.9052734375}, {"start": 475.88, "end": 476.26, "word": " الخطوة", "probability": 0.984619140625}, {"start": 476.26, "end": 476.6, "word": " الأولى", "probability": 0.9793294270833334}, {"start": 476.6, "end": 476.92, "word": " اقول", "probability": 0.795166015625}, {"start": 476.92, "end": 477.22, "word": " زي", "probability": 0.851806640625}, {"start": 477.22, "end": 478.26, "word": " هيك", "probability": 0.946044921875}, {"start": 478.26, "end": 479.08, "word": " حسر", "probability": 0.6368815104166666}, {"start": 479.08, "end": 479.78, "word": " عندك", "probability": 0.699951171875}, {"start": 479.78, "end": 481.0, "word": " R", "probability": 0.50830078125}], "temperature": 1.0}, {"id": 20, "seek": 51136, "start": 499.04, "end": 511.36, "text": "بنان على ذلك مرة تانية كان محصلة ال reduction of E stars with hydrides produces primary alcohols تبقى صح", "tokens": [3555, 1863, 7649, 15844, 29910, 23275, 3714, 25720, 6055, 7649, 10632, 25961, 3714, 5016, 36520, 3660, 2423, 11004, 295, 462, 6105, 365, 5796, 81, 1875, 14725, 6194, 7658, 82, 6055, 3555, 4587, 7578, 20328, 5016], "avg_logprob": -0.4578992972771327, "compression_ratio": 1.1129032258064515, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 499.04, "end": 500.12, "word": "بنان", "probability": 0.2005615234375}, {"start": 500.12, "end": 500.34, "word": " على", "probability": 0.669921875}, {"start": 500.34, "end": 500.82, "word": " ذلك", "probability": 0.9814453125}, {"start": 500.82, "end": 501.4, "word": " مرة", "probability": 0.91357421875}, {"start": 501.4, "end": 501.7, "word": " تانية", "probability": 0.9772135416666666}, {"start": 501.7, "end": 501.94, "word": " كان", "probability": 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761.75, "word": " أخليه", "probability": 0.803466796875}, {"start": 761.75, "end": 762.21, "word": " ايون", "probability": 0.769775390625}, {"start": 762.21, "end": 763.29, "word": " لما", "probability": 0.880126953125}, {"start": 763.29, "end": 763.77, "word": " يتفاعل", "probability": 0.97353515625}, {"start": 763.77, "end": 763.93, "word": " مع", "probability": 0.98974609375}, {"start": 763.93, "end": 764.37, "word": " التاني", "probability": 0.919921875}, {"start": 764.37, "end": 764.49, "word": " شو", "probability": 0.867431640625}, {"start": 764.49, "end": 764.97, "word": " التفاعل", "probability": 0.9027099609375}, {"start": 764.97, "end": 765.11, "word": " اللي", "probability": 0.9814453125}, {"start": 765.11, "end": 765.33, "word": " كان", "probability": 0.9873046875}, {"start": 765.33, "end": 765.97, "word": " يعمله؟", "probability": 0.841552734375}], "temperature": 1.0}, {"id": 31, "seek": 77354, "start": 767.46, "end": 773.54, "text": "أضافة اليوكليوفايل مع الديهيدوكيتون اضافة اليوكليوفايل مع ال E-star", "tokens": [10721, 11242, 31845, 3660, 45595, 2407, 4117, 20292, 38688, 995, 26895, 20449, 2423, 16254, 3224, 25708, 2407, 4117, 36081, 11536, 1975, 11242, 31845, 3660, 45595, 2407, 4117, 20292, 38688, 995, 26895, 20449, 2423, 462, 12, 9710], "avg_logprob": -0.5194256950069118, "compression_ratio": 1.6666666666666667, "no_speech_prob": 5.364418029785156e-07, "words": [{"start": 767.46, "end": 768.36, "word": "أضافة", "probability": 0.702545166015625}, {"start": 768.36, "end": 769.46, "word": " اليوكليوفايل", "probability": 0.6586390904017857}, {"start": 769.46, "end": 769.68, "word": " مع", "probability": 0.623046875}, {"start": 769.68, "end": 770.82, "word": " الديهيدوكيتون", "probability": 0.765625}, {"start": 770.82, "end": 771.48, "word": " اضافة", "probability": 0.7099456787109375}, {"start": 771.48, "end": 772.58, "word": " اليوكليوفايل", "probability": 0.9577287946428571}, {"start": 772.58, "end": 772.76, "word": " مع", "probability": 0.96533203125}, {"start": 772.76, "end": 772.9, "word": " ال", "probability": 0.89990234375}, {"start": 772.9, "end": 773.06, "word": " E", "probability": 0.291015625}, {"start": 773.06, "end": 773.54, "word": "-star", "probability": 0.26509857177734375}], "temperature": 1.0}, {"id": 32, "seek": 80744, "start": 781.72, "end": 807.44, "text": "substitution إبدال بينما الالدول reaction is an addition reaction واضح هذا السؤال صح و غلط الالدول reaction is an addition reaction because الالدول بتعامل مع ال الديهيدز الالدول بتعامل مع ال الديهيدز", "tokens": [30131, 372, 6518, 11933, 44510, 6027, 49374, 15042, 2423, 6027, 3215, 12610, 5480, 307, 364, 4500, 5480, 4032, 46958, 5016, 23758, 21136, 33604, 6027, 20328, 5016, 4032, 32771, 1211, 9566, 2423, 6027, 3215, 12610, 5480, 307, 364, 4500, 5480, 570, 2423, 6027, 3215, 12610, 39894, 3615, 10943, 1211, 20449, 2423, 2423, 16254, 3224, 25708, 11622, 2423, 6027, 3215, 12610, 39894, 3615, 10943, 1211, 20449, 2423, 2423, 16254, 3224, 25708, 11622], "avg_logprob": -0.27816900484998464, "compression_ratio": 2.0709219858156027, "no_speech_prob": 0.0, "words": [{"start": 781.72, "end": 782.7, "word": "substitution", "probability": 0.6882731119791666}, {"start": 782.7, "end": 783.42, "word": " إبدال", "probability": 0.59326171875}, {"start": 783.42, "end": 784.78, "word": " بينما", "probability": 0.879150390625}, {"start": 784.78, "end": 785.78, "word": " الالدول", "probability": 0.7843017578125}, {"start": 785.78, "end": 786.66, "word": " reaction", "probability": 0.68212890625}, {"start": 786.66, "end": 787.72, "word": " is", "probability": 0.7890625}, {"start": 787.72, "end": 787.96, "word": " an", "probability": 0.69091796875}, {"start": 787.96, "end": 788.38, "word": " addition", "probability": 0.7685546875}, {"start": 788.38, "end": 789.18, "word": " reaction", "probability": 0.87353515625}, {"start": 789.18, "end": 789.78, "word": " واضح", "probability": 0.7706705729166666}, {"start": 789.78, "end": 790.58, "word": " هذا", "probability": 0.384521484375}, {"start": 790.58, "end": 790.88, "word": " السؤال", "probability": 0.8790690104166666}, {"start": 790.88, "end": 791.14, "word": " صح", "probability": 0.99169921875}, {"start": 791.14, "end": 791.26, "word": " و", "probability": 0.93408203125}, {"start": 791.26, "end": 791.6, "word": " غلط", "probability": 0.861328125}, {"start": 791.6, "end": 792.18, "word": " الالدول", "probability": 0.876708984375}, {"start": 792.18, "end": 792.76, "word": " reaction", "probability": 0.90966796875}, {"start": 792.76, "end": 793.46, "word": " is", "probability": 0.85888671875}, {"start": 793.46, "end": 794.42, "word": " an", "probability": 0.63134765625}, {"start": 794.42, "end": 795.04, "word": " addition", "probability": 0.92041015625}, {"start": 795.04, "end": 795.82, "word": " reaction", "probability": 0.90087890625}, {"start": 795.82, "end": 796.24, "word": " because", "probability": 0.04925537109375}, {"start": 796.24, "end": 800.4, "word": " الالدول", "probability": 0.8743896484375}, {"start": 800.4, "end": 801.06, "word": " بتعامل", "probability": 0.84130859375}, {"start": 801.06, "end": 801.26, "word": " مع", "probability": 0.97265625}, {"start": 801.26, "end": 803.28, "word": " ال", "probability": 0.78759765625}, {"start": 803.28, "end": 804.3, "word": " الديهيدز", "probability": 0.58388671875}, {"start": 804.3, "end": 805.08, "word": " الالدول", "probability": 0.9228515625}, {"start": 805.08, "end": 805.96, "word": " بتعامل", "probability": 0.94677734375}, {"start": 805.96, "end": 806.38, "word": " مع", "probability": 0.9814453125}, {"start": 806.38, "end": 806.52, "word": " ال", "probability": 0.99267578125}, {"start": 806.52, "end": 807.44, "word": " الديهيدز", "probability": 0.97119140625}], "temperature": 1.0}, {"id": 33, "seek": 81889, "start": 808.13, "end": 818.89, "text": "والـ Antihites تفعيلها الأساسي الـ Claisen reaction بتعمل مع ال A stars وال A stars تفعيلها الأساسي substitution", "tokens": [2407, 6027, 39184, 5130, 4247, 3324, 6055, 5172, 3615, 26895, 11296, 16247, 3794, 32277, 1829, 2423, 39184, 12947, 11106, 5480, 39894, 25957, 1211, 20449, 2423, 316, 6105, 16070, 316, 6105, 6055, 5172, 3615, 26895, 11296, 16247, 3794, 32277, 1829, 35827], "avg_logprob": -0.3387957375224044, "compression_ratio": 1.382608695652174, "no_speech_prob": 0.0, "words": [{"start": 808.13, "end": 808.49, "word": "والـ", "probability": 0.5673828125}, {"start": 808.49, "end": 808.91, "word": " Antihites", "probability": 0.572021484375}, {"start": 808.91, "end": 809.39, "word": " تفعيلها", "probability": 0.8353515625}, {"start": 809.39, "end": 810.15, "word": " الأساسي", "probability": 0.9188232421875}, {"start": 810.15, "end": 811.27, "word": " الـ", "probability": 0.7216796875}, {"start": 811.27, "end": 811.97, "word": " Claisen", "probability": 0.5242919921875}, {"start": 811.97, "end": 812.59, "word": " reaction", "probability": 0.80908203125}, {"start": 812.59, "end": 813.21, "word": " بتعمل", "probability": 0.87109375}, {"start": 813.21, "end": 813.53, "word": " مع", "probability": 0.9599609375}, {"start": 813.53, "end": 814.53, "word": " ال", "probability": 0.93212890625}, {"start": 814.53, "end": 814.71, "word": " A", "probability": 0.389892578125}, {"start": 814.71, "end": 815.25, "word": " stars", "probability": 0.161376953125}, {"start": 815.25, "end": 815.83, "word": " وال", "probability": 0.361083984375}, {"start": 815.83, "end": 816.07, "word": " A", "probability": 0.564453125}, {"start": 816.07, "end": 816.37, "word": " stars", "probability": 0.8583984375}, {"start": 816.37, "end": 816.97, "word": " تفعيلها", "probability": 0.9361328125}, {"start": 816.97, "end": 817.75, "word": " الأساسي", "probability": 0.9698486328125}, {"start": 817.75, "end": 818.89, "word": " substitution", "probability": 0.50439453125}], "temperature": 1.0}, {"id": 34, "seek": 85018, "start": 820.78, "end": 850.18, "text": "هي مثلا مثال تاني هذا الجزء لو بده يعمل إكليزين كوندنسيشن الان احنا اتفقنا سابقا ايش افضل طريقة لكتابة ناتج إكليزين او ألدول ان احط جزايين جان بعض بالظبط زي ما حكت زملتكم بناء على ذلك هان انا بتتخيل ان عندي صيبة بال bond O O CH2 CH3 و هن احط CH2 و هن احط CH3 هى جزء و جزء واحد منهم بده يصير", "tokens": [3224, 1829, 50113, 15040, 50113, 6027, 6055, 7649, 1829, 23758, 25724, 11622, 38207, 45164, 47525, 3224, 7251, 25957, 1211, 11933, 4117, 20292, 11622, 9957, 9122, 11536, 3215, 1863, 3794, 1829, 8592, 1863, 2423, 7649, 1975, 5016, 8315, 1975, 2655, 5172, 4587, 8315, 8608, 16758, 4587, 995, 1975, 1829, 8592, 1975, 5172, 11242, 1211, 23032, 16572, 28671, 5296, 4117, 2655, 16758, 3660, 8717, 9307, 7435, 11933, 4117, 20292, 11622, 9957, 1975, 2407, 5551, 1211, 3215, 12610, 16472, 1975, 5016, 9566, 10874, 11622, 47302, 9957, 10874, 7649, 45030, 11242, 20666, 19913, 3555, 9566, 30767, 1829, 19446, 11331, 4117, 2655, 30767, 42213, 2655, 24793, 44945, 16606, 15844, 29910, 23275, 8032, 7649, 1975, 8315, 39894, 2655, 9778, 26895, 16472, 18871, 16254, 20328, 1829, 49401, 20666, 6086, 422, 422, 5995, 17, 5995, 18, 4032, 8032, 1863, 1975, 5016, 9566, 5995, 17, 4032, 8032, 1863, 1975, 5016, 9566, 5995, 18, 8032, 7578, 10874, 11622, 38207, 4032, 10874, 11622, 38207, 36764, 24401, 9154, 16095, 47525, 3224, 7251, 9381, 13546], "avg_logprob": -0.2699386375082051, "compression_ratio": 1.848148148148148, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 820.78, "end": 821.12, "word": "هي", "probability": 0.459228515625}, {"start": 821.12, "end": 821.58, "word": " مثلا", "probability": 0.772705078125}, {"start": 821.58, "end": 822.22, "word": " مثال", "probability": 0.92626953125}, {"start": 822.22, "end": 822.72, "word": " تاني", "probability": 0.8974609375}, {"start": 822.72, "end": 823.2, "word": " هذا", "probability": 0.537109375}, {"start": 823.2, "end": 823.74, "word": " الجزء", "probability": 0.7682291666666666}, {"start": 823.74, "end": 823.86, "word": " لو", "probability": 0.919921875}, {"start": 823.86, "end": 824.12, "word": " بده", "probability": 0.646728515625}, {"start": 824.12, "end": 824.58, "word": " يعمل", "probability": 0.982421875}, {"start": 824.58, "end": 825.3, "word": " إكليزين", "probability": 0.730712890625}, {"start": 825.3, "end": 826.22, "word": " كوندنسيشن", "probability": 0.7646026611328125}, {"start": 826.22, "end": 826.86, "word": " الان", "probability": 0.50726318359375}, {"start": 826.86, "end": 827.06, "word": " احنا", "probability": 0.7093912760416666}, {"start": 827.06, "end": 827.64, "word": " اتفقنا", "probability": 0.947265625}, {"start": 827.64, "end": 828.2, "word": " سابقا", "probability": 0.975830078125}, {"start": 828.2, "end": 828.5, "word": " ايش", "probability": 0.737548828125}, {"start": 828.5, "end": 828.88, "word": " افضل", "probability": 0.8795166015625}, {"start": 828.88, "end": 829.28, "word": " طريقة", "probability": 0.9933268229166666}, {"start": 829.28, "end": 829.88, "word": " لكتابة", "probability": 0.94912109375}, {"start": 829.88, "end": 830.24, "word": " ناتج", "probability": 0.9807942708333334}, {"start": 830.24, "end": 830.98, "word": " إكليزين", "probability": 0.94072265625}, {"start": 830.98, "end": 831.26, "word": " او", "probability": 0.760498046875}, {"start": 831.26, "end": 831.82, "word": " ألدول", "probability": 0.66705322265625}, {"start": 831.82, "end": 832.74, "word": " ان", "probability": 0.50048828125}, {"start": 832.74, "end": 833.08, "word": " احط", "probability": 0.737060546875}, {"start": 833.08, "end": 833.64, "word": " جزايين", "probability": 0.78070068359375}, {"start": 833.64, "end": 833.86, "word": " جان", "probability": 0.830078125}, {"start": 833.86, "end": 834.18, "word": " بعض", "probability": 0.869384765625}, {"start": 834.18, "end": 834.62, "word": " بالظبط", "probability": 0.922607421875}, {"start": 834.62, "end": 834.8, "word": " زي", "probability": 0.89208984375}, {"start": 834.8, "end": 834.88, "word": " ما", "probability": 0.98095703125}, {"start": 834.88, "end": 835.2, "word": " حكت", "probability": 0.9586588541666666}, {"start": 835.2, "end": 835.86, "word": " زملتكم", "probability": 0.661865234375}, {"start": 835.86, "end": 836.46, "word": " بناء", "probability": 0.83447265625}, {"start": 836.46, "end": 836.68, "word": " على", "probability": 0.82763671875}, {"start": 836.68, "end": 837.04, "word": " ذلك", "probability": 0.990966796875}, {"start": 837.04, "end": 837.26, "word": " هان", "probability": 0.3472900390625}, {"start": 837.26, "end": 837.32, "word": " انا", "probability": 0.60498046875}, {"start": 837.32, "end": 837.8, "word": " بتتخيل", "probability": 0.837646484375}, {"start": 837.8, "end": 837.92, "word": " ان", "probability": 0.73583984375}, {"start": 837.92, "end": 838.22, "word": " عندي", "probability": 0.787353515625}, {"start": 838.22, "end": 838.52, "word": " صيبة", "probability": 0.578369140625}, {"start": 838.52, "end": 838.7, "word": " بال", "probability": 0.79296875}, {"start": 838.7, "end": 838.94, "word": " bond", "probability": 0.382568359375}, {"start": 838.94, "end": 839.28, "word": " O", "probability": 0.70849609375}, {"start": 839.28, "end": 839.8, "word": " O", "probability": 0.494140625}, {"start": 839.8, "end": 841.14, "word": " CH2", "probability": 0.846923828125}, {"start": 841.14, "end": 842.1, "word": " CH3", "probability": 0.916015625}, {"start": 842.1, "end": 842.54, "word": " و", "probability": 0.5966796875}, {"start": 842.54, "end": 842.76, "word": " هن", "probability": 0.4981689453125}, {"start": 842.76, "end": 843.22, "word": " احط", "probability": 0.83154296875}, {"start": 843.22, "end": 844.72, "word": " CH2", "probability": 0.9775390625}, {"start": 844.72, "end": 844.94, "word": " و", "probability": 0.86962890625}, {"start": 844.94, "end": 845.14, "word": " هن", "probability": 0.898193359375}, {"start": 845.14, "end": 845.6, "word": " احط", "probability": 0.8502604166666666}, {"start": 845.6, "end": 846.54, "word": " CH3", "probability": 0.988037109375}, {"start": 846.54, "end": 846.96, "word": " هى", "probability": 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"text": "الان كيف بيشتغل هذا يعني القالية اللي بيشتغل فيها كغاز مثيل للدموع؟ بيجي على المناطق في الجسم اللي فيها مية", "tokens": [6027, 7649, 9122, 33911, 4724, 1829, 8592, 2655, 17082, 1211, 23758, 37495, 22653, 25062, 6027, 10632, 13672, 1829, 4724, 1829, 8592, 2655, 17082, 1211, 8978, 11296, 9122, 17082, 31377, 50113, 26895, 24976, 40448, 45367, 22807, 4724, 1829, 7435, 1829, 15844, 9673, 1863, 41193, 4587, 8978, 25724, 38251, 13672, 1829, 8978, 11296, 3714, 10632], "avg_logprob": -0.2345196756499785, "compression_ratio": 1.5853658536585367, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 1250.93, "end": 1251.99, "word": "الان", "probability": 0.470458984375}, {"start": 1251.99, "end": 1252.55, "word": " كيف", "probability": 0.906494140625}, {"start": 1252.55, "end": 1253.21, "word": " بيشتغل", "probability": 0.80126953125}, {"start": 1253.21, "end": 1253.65, "word": " هذا", "probability": 0.5205078125}, {"start": 1253.65, "end": 1254.31, "word": " يعني", "probability": 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"probability": 0.9765625}, {"start": 1704.59, "end": 1705.25, "word": " تفاعل", "probability": 0.9053955078125}, {"start": 1705.25, "end": 1705.57, "word": " مرة", "probability": 0.90869140625}, {"start": 1705.57, "end": 1705.93, "word": " تانية", "probability": 0.9640299479166666}, {"start": 1705.93, "end": 1706.45, "word": " إبدال", "probability": 0.8650716145833334}, {"start": 1706.45, "end": 1706.89, "word": " إن", "probability": 0.4072265625}, {"start": 1706.89, "end": 1707.35, "word": " واحد", "probability": 0.991455078125}, {"start": 1707.35, "end": 1707.59, "word": " من", "probability": 0.99658203125}, {"start": 1707.59, "end": 1708.15, "word": " الحامض", "probability": 0.9928385416666666}, {"start": 1708.15, "end": 1708.55, "word": " بيجي", "probability": 0.9356689453125}, {"start": 1708.55, "end": 1709.15, "word": " بهاجم", "probability": 0.8077392578125}, {"start": 1709.15, "end": 1709.53, "word": " هنا", "probability": 0.916015625}, {"start": 1709.53, "end": 1711.17, "word": " وبيطرد", "probability": 0.85556640625}, {"start": 1711.17, "end": 1712.41, "word": " الـ", "probability": 0.7216796875}, {"start": 1712.41, "end": 1712.75, "word": " OH", "probability": 0.390380859375}], "temperature": 1.0}, {"id": 71, "seek": 172775, "start": 1714.41, "end": 1727.75, "text": "يعني كإن واحد بيعمل كـ Nucleophile والثاني بيعمل كـ Electrophile أو مستقبل لما يطرد الـ OH حيصير عند هذا الجزء الأولاني CH3CW.O", "tokens": [40228, 22653, 9122, 28814, 1863, 36764, 24401, 4724, 1829, 25957, 1211, 9122, 39184, 13612, 2160, 49242, 16070, 12984, 7649, 1829, 4724, 1829, 25957, 1211, 9122, 39184, 12575, 11741, 794, 34051, 3714, 14851, 4587, 36150, 5296, 15042, 7251, 9566, 2288, 3215, 2423, 39184, 13931, 11331, 1829, 9381, 13546, 43242, 23758, 25724, 11622, 38207, 16247, 12610, 7649, 1829, 5995, 18, 34, 54, 13, 46], "avg_logprob": -0.2973710194466606, "compression_ratio": 1.2967741935483872, "no_speech_prob": 0.0, "words": [{"start": 1714.41, "end": 1714.75, "word": "يعني", 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"probability": 0.91650390625}, {"start": 2668.02, "end": 2668.6, "word": " حساس", "probability": 0.9913736979166666}, {"start": 2668.6, "end": 2669.06, "word": " بنشعه", "probability": 0.60675048828125}, {"start": 2669.06, "end": 2669.48, "word": " يحرج", "probability": 0.82275390625}, {"start": 2669.48, "end": 2669.96, "word": " المعدة", "probability": 0.904296875}, {"start": 2669.96, "end": 2670.82, "word": " بنحول", "probability": 0.921875}, {"start": 2670.82, "end": 2671.56, "word": " الساليسيليك", "probability": 0.9409877232142857}, {"start": 2671.56, "end": 2671.98, "word": " أسد", "probability": 0.97802734375}, {"start": 2671.98, "end": 2672.52, "word": " إلى", "probability": 0.87451171875}, {"start": 2672.52, "end": 2673.18, "word": " أسبيرين", "probability": 0.9833984375}, {"start": 2673.18, "end": 2673.36, "word": " أو", "probability": 0.83447265625}, {"start": 2673.36, "end": 2674.28, "word": " أسيتوساليسيليك", "probability": 0.884716796875}, {"start": 2674.28, "end": 2674.72, "word": " أسد", "probability": 0.9881184895833334}, {"start": 2674.72, "end": 2675.06, "word": " في", "probability": 0.61669921875}, {"start": 2675.06, "end": 2675.64, "word": " الأمعاق", "probability": 0.9283203125}, {"start": 2675.64, "end": 2676.06, "word": " بيرجع", "probability": 0.9283447265625}, {"start": 2676.06, "end": 2676.58, "word": " بيصير", "probability": 0.90771484375}], "temperature": 1.0}, {"id": 110, "seek": 268642, "start": 2678.16, "end": 2686.42, "text": "برجع بصير salicylic acid ابهيك بنقف احنا عند ال amides ماشي؟", "tokens": [26890, 7435, 3615, 4724, 9381, 13546, 1845, 2632, 1050, 8258, 48127, 3224, 1829, 4117, 44945, 4587, 5172, 1975, 5016, 8315, 43242, 2423, 669, 1875, 3714, 33599, 1829, 22807], "avg_logprob": -0.27545797002726585, "compression_ratio": 0.9891304347826086, "no_speech_prob": 0.0, "words": [{"start": 2678.16, "end": 2678.58, "word": "برجع", "probability": 0.7942708333333334}, {"start": 2678.58, "end": 2679.14, "word": " بصير", "probability": 0.8688151041666666}, {"start": 2679.14, "end": 2680.26, "word": " salicylic", "probability": 0.8587239583333334}, {"start": 2680.26, "end": 2680.68, "word": " acid", "probability": 0.96923828125}, {"start": 2680.68, "end": 2681.66, "word": " ابهيك", "probability": 0.650177001953125}, {"start": 2681.66, "end": 2682.12, "word": " بنقف", "probability": 0.9371744791666666}, {"start": 2682.12, "end": 2682.48, "word": " احنا", "probability": 0.9114583333333334}, {"start": 2682.48, "end": 2682.9, "word": " عند", "probability": 0.98486328125}, {"start": 2682.9, "end": 2684.4, "word": " ال", "probability": 0.9365234375}, {"start": 2684.4, "end": 2684.9, "word": " amides", "probability": 0.5147705078125}, {"start": 2684.9, "end": 2686.42, "word": " ماشي؟", "probability": 0.8194580078125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2689.753, "duration_after_vad": 2541.153468749989}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4.srt
new file mode 100644
index 0000000000000000000000000000000000000000..3e794bd1c6d7e64795ebde422bbf114b1e0ede13
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4.srt
@@ -0,0 +1,1814 @@
+1
+00:00:09,000 --> 00:00:12,660
+بنبدأ اليوم بالفصل التاسع، العنوان هو الـ
+
+2
+00:00:12,660 --> 00:00:17,420
+aldehydes والكيتونات الآن الفصل التاسع والفصل
+
+3
+00:00:17,420 --> 00:00:24,320
+العاشر بيتكلم عن المركبات اللي فيها رابطة C double
+
+4
+00:00:24,320 --> 00:00:31,060
+bond O هذه المجموعة الـ C double bond O في أي مكان
+
+5
+00:00:31,060 --> 00:00:36,530
+كانتسموها الـ carbonyl group يعني المجموعة نفسها
+
+6
+00:00:36,530 --> 00:00:40,410
+الـ C double bond O لحالها بيقولوا عنها ال
+
+7
+00:00:40,410 --> 00:00:45,170
+carbonyl group الآن المركبات اللي فيهم C double
+
+8
+00:00:45,170 --> 00:00:50,570
+bond O بنقول عنهم Carbonyl compounds واضح؟ إذا في
+
+9
+00:00:50,570 --> 00:00:54,290
+عندي Carbonyl group و Carbonyl compounds ال
+
+10
+00:00:54,290 --> 00:00:58,130
+Carbonyl compounds أنواع كتيرة يعني موجود في كثير
+
+11
+00:00:58,130 --> 00:01:02,890
+موجود في كثير C double bond O يعني مثلًا في ال
+
+12
+00:01:02,890 --> 00:01:07,960
+aldehydes ال C double bond O جنب hydrogen في الـ
+
+13
+00:01:07,960 --> 00:01:11,560
+ketones الـ C double bond O جنب أو بين two R
+
+14
+00:01:11,560 --> 00:01:16,580
+groups في الأحماض الـ carboxylic acids بيكون عندي
+
+15
+00:01:16,580 --> 00:01:20,340
+C double bond O OH في ال E stars بيكون عندي C
+
+16
+00:01:20,340 --> 00:01:25,060
+double bond O OR في الأبد C double bond O NH2 في
+
+17
+00:01:25,060 --> 00:01:29,300
+ال acid chlorides C double bond O Cl بيجي كمان
+
+18
+00:01:29,300 --> 00:01:33,440
+عائلة ال acid anhydrides بتمر علينا في الفصل
+
+19
+00:01:33,440 --> 00:01:37,800
+العاشر مع هدول المجموعات الآن هذه ال carbonyl
+
+20
+00:01:37,800 --> 00:01:43,640
+compounds كلها بجسمها نوعين وبناء على ذلك كمان
+
+21
+00:01:43,640 --> 00:01:48,600
+بتبين في تقسيم الفصول في الكتاب يعني ال aldehydes
+
+22
+00:01:48,600 --> 00:01:54,460
+و ال ketones يعتبروا نوع و ال acid و بيقولوا عن هذه
+
+23
+00:01:54,460 --> 00:01:58,880
+الأشياء كلها مشتقات ال acid طالعة من الحامض بتيجي
+
+24
+00:01:58,880 --> 00:02:04,540
+نوع تاني، الآن ليش هذا التصنيف؟ ليش ال aldehydes و
+
+25
+00:02:04,540 --> 00:02:08,800
+ال ketones؟ نوع و بنفصلها عادة في جميع كتب ال
+
+26
+00:02:08,800 --> 00:02:13,730
+organic تقريبًا فصلوا في فصل مستقل لحاله والأحماض
+
+27
+00:02:13,730 --> 00:02:18,230
+ومشتقاتها بتلاقوها بفصل تاني لحالها لأن هدول
+
+28
+00:02:18,230 --> 00:02:24,360
+باختلفوا اختلاف كبير في طريقة التفاعل في المحصلة
+
+29
+00:02:24,360 --> 00:02:29,280
+هتتعلموا كلمتين اللي بيفهم هدول الكلمتين عن فهم
+
+30
+00:02:29,280 --> 00:02:34,320
+بيكون استوعب المادة كلها اللي هي الفصل التاسع
+
+31
+00:02:34,320 --> 00:02:39,720
+والفصل العاشر أن ال الديهايدات والكيتونات التفاعل
+
+32
+00:02:39,720 --> 00:02:46,650
+الأساسي تبعهم هو تفاعل إضافة addition والأحماض
+
+33
+00:02:46,650 --> 00:02:51,430
+ومشتقاتها التفاعل الأساسي تبعهم تفاعل إبدال
+
+34
+00:02:51,430 --> 00:02:55,950
+substitution واضح؟ يعني لو أنتم ما شاء الله عنكم
+
+35
+00:02:55,950 --> 00:03:01,800
+اتخرجتوا وبتكونوا دخلوا مسابقة توظيف مش معقول
+
+36
+00:03:01,800 --> 00:03:04,600
+نجيب لكم ورقة وجلم وأنتم تدخلوا امتحان شفهي و
+
+37
+00:03:04,600 --> 00:03:08,320
+نقعد نقول لكم عيدوا وزيدوا نسألكم سؤالين ثلاثة
+
+38
+00:03:08,320 --> 00:03:12,300
+عامين جدًا بنعرفكم بتفهموا كيمياء عضوية ولا لأ لو
+
+39
+00:03:12,300 --> 00:03:15,700
+أجينا قولنا لكم مثلًا ايش التفاعل الأساسي على
+
+40
+00:03:15,700 --> 00:03:21,180
+الalkenes لازم أسمع addition و electrophilic
+
+41
+00:03:21,180 --> 00:03:26,140
+addition على الalkalitesلازم أسمع substitution و
+
+42
+00:03:26,140 --> 00:03:30,200
+nucleophilic على الـ aromatic compounds مثلًا
+
+43
+00:03:30,200 --> 00:03:36,320
+Electrophilic substitution على الألديهيدات
+
+44
+00:03:36,320 --> 00:03:41,640
+والكيتونات تفاعلنا addition على الأحماض ومشتقاتها
+
+45
+00:03:41,640 --> 00:03:46,240
+تفاعلنا substitution هذا هنشوفه بالأمثلة بس هذا حتى
+
+46
+00:03:46,240 --> 00:03:50,720
+يكون عندكم استيعاب ليش هدول المركبين يمثلوا بحد
+
+47
+00:03:50,720 --> 00:03:56,640
+ذاتهما عائلة وباقي المركبات هذه تمثل عائلة ثانية
+
+48
+00:03:56,640 --> 00:04:00,740
+لأنه في اختلاف جوهري في التفاعل الأساسي لهدول
+
+49
+00:04:00,740 --> 00:04:03,480
+العائلتين واحدة بتفعل بالإضافة والثانية بتفعل
+
+50
+00:04:03,480 --> 00:04:04,420
+بالإبدال
+
+51
+00:04:07,820 --> 00:04:11,840
+بالنسبة لبعض الخواص لـ aldehydes و الـ ketones
+
+52
+00:04:11,840 --> 00:04:17,300
+طبعًا واضح أن الرابطة الـ C double bond O نسبياً polar
+
+53
+00:04:17,300 --> 00:04:21,360
+بس مافيش فيه hydrogen bonding يعني لما أطلع أنا
+
+54
+00:04:21,360 --> 00:04:24,700
+على ال oxygen و ال carbon ال oxygen is more
+
+55
+00:04:24,700 --> 00:04:29,800
+electronegative than carbon و عشان هيك هتلاحظوا
+
+56
+00:04:29,800 --> 00:04:36,040
+دائمًا أن في عندي طرف سالب عند ال oxygen و طرف موجب
+
+57
+00:04:36,040 --> 00:04:43,620
+عند الكربون هذا الطرف الموجب عند الكربون هو أساس
+
+58
+00:04:43,620 --> 00:04:48,710
+الكيمياء تبع الكربونيل compounds كلها يعني دائمًا
+
+59
+00:04:48,710 --> 00:04:52,230
+لما أبدأ أفكر في carbonyl compound أبدأ أفكر أنه
+
+60
+00:04:52,230 --> 00:04:57,170
+الرابطة مستقطبة فيها طرف سالب اللي هو ال oxygen
+
+61
+00:04:57,170 --> 00:05:02,110
+وطرف موجب اللي هو ال carbon الآن التفاعل الأساسي
+
+62
+00:05:02,110 --> 00:05:07,310
+هتلاحظوا مركز على هذا الكربون اللي موجود في ال
+
+63
+00:05:07,310 --> 00:05:13,990
+carbonyl compounds طالما هذا الطرف موجب معناه ذلك
+
+64
+00:05:13,990 --> 00:05:16,490
+شو اللي بنتوقع بده يهاجم عليه بعد شو اللي مصير
+
+65
+00:05:16,490 --> 00:05:21,010
+التفاعلات؟ إيش يعني سالب؟ Enucleophile عشانك
+
+66
+00:05:21,010 --> 00:05:24,630
+هتلاقوا على ال الديهايدات والكيتونات Enucleophilic
+
+67
+00:05:24,630 --> 00:05:27,050
+addition و هتلاقوا على العائلة الثانية
+
+68
+00:05:27,050 --> 00:05:30,850
+Enucleophilic substitution في كل الأحوال طالما هذا
+
+69
+00:05:30,850 --> 00:05:35,810
+موجب اللي بده يهاجم عليه لازم يكون سالب واضح؟
+
+70
+00:05:35,810 --> 00:05:40,150
+بالنسبة لل boiling points طبعًا بتلاحظوا أن ال
+
+71
+00:05:40,150 --> 00:05:44,030
+الديهايدات والكيتونات مافيهما hydrogen bonding لأن شرط
+
+72
+00:05:44,030 --> 00:05:49,630
+ال hydrogen bonding أن يكون عنده هيدروجين مرتبطة
+
+73
+00:05:49,630 --> 00:05:55,030
+بأكسجين أو نيتروجين أو فلور واحدة من الثلاث ذرات
+
+74
+00:05:55,030 --> 00:05:59,790
+الآن هنا مافيش شيء مرتبط بالأكسجين ولذلك نقطة
+
+75
+00:05:59,790 --> 00:06:05,470
+غليانهم أقل من الكحولات واضح؟ يعني مثلًا الأسيتون
+
+76
+00:06:05,470 --> 00:06:08,810
+اللي هو عبارة عن ثلاث ذرات كربون وذرة أكسجين
+
+77
+00:06:08,810 --> 00:06:15,240
+بيغلي عند 56 لو بدي أقارنه بالبروبانول ممكن بيغلي
+
+78
+00:06:15,240 --> 00:06:20,840
+بالتسعينات أو جري بالمئة، واضح؟ ليش هدول ال
+
+79
+00:06:20,840 --> 00:06:26,180
+aldehydes و ال ketones لهم نقاط غليان أقل من ال
+
+80
+00:06:26,180 --> 00:06:31,080
+alcohols because they don't have hydrogen bonds
+
+81
+00:06:31,080 --> 00:06:37,460
+الذوبانية بشكل عام ضعيفة جدًا في الماء، يعني
+
+82
+00:06:37,460 --> 00:06:40,900
+مافيش غير اللي بنسميهم ال lower aldehydes and
+
+83
+00:06:40,900 --> 00:06:47,260
+ketones تعرف إيش يعني ال lower؟ الـ Lower Aldehydes
+
+84
+00:06:47,260 --> 00:06:52,780
+and Ketones اللي هم فيهم عدد كربونات قليل يعني أول
+
+85
+00:06:52,780 --> 00:06:56,380
+Aldehydes و Ketones في السلسلة هدول اللي بيدوبوا
+
+86
+00:06:56,380 --> 00:07:00,380
+في الماء يعني مثلًا ال Acetaldehyde بيدوب في الماء
+
+87
+00:07:00,380 --> 00:07:04,620
+ال Formaldehyde بيدوب في الماء ال Acetone كأبسط
+
+88
+00:07:04,620 --> 00:07:07,560
+Ketone بيدوب في الماء بعد هيك ال R group بتصير
+
+89
+00:07:07,560 --> 00:07:11,200
+كبيرة المركبات ما بتدوبش في الماء يعني اللي بدنا
+
+90
+00:07:11,200 --> 00:07:15,700
+نقول مثلًا three-hexanone ولا three-cyclopentanone
+
+91
+00:07:15,700 --> 00:07:19,780
+هذه الكيتونات إذا كبرت خلاص ما بتدوب في الماء فبس
+
+92
+00:07:19,780 --> 00:07:23,320
+اللي هم ال low molecular weight species يعني
+
+93
+00:07:23,320 --> 00:07:27,140
+الأشياء اللي ال molecular weight تبعها صغير اللي
+
+94
+00:07:27,140 --> 00:07:31,380
+هم أوائل الألدهيدات والكيتونات فقط اللي بيدوبوا في
+
+95
+00:07:31,380 --> 00:07:38,500
+الماء بعد ذلك مافيش شيء ذوبان في الماء لأنه مافيش
+
+96
+00:07:38,500 --> 00:07:44,140
+عنده hydrogen bonding كمان تساعد على الذوبان الآن
+
+97
+00:07:44,140 --> 00:07:48,940
+بالنسبة لتسمية هذه المركبات بالنسبة لتسمية هذه
+
+98
+00:07:48,940 --> 00:07:55,060
+المركبات احنا في ال IUPAC Nomenclature اتفقنا أن
+
+99
+00:07:55,060 --> 00:08:02,520
+بناخد اسم ال الكان و بنزيد عليه نهاية يعني مثلًا لو
+
+100
+00:08:02,520 --> 00:08:07,860
+فكرنا بذرتين carbon لو فكرنا بذرتين carbon الأصل
+
+101
+00:08:07,860 --> 00:08:12,360
+لما يكون عندي ذرتين carbon ايش المركب إيثان إيثان
+
+102
+00:08:12,360 --> 00:08:17,020
+okay الآن لو صار المركب فيه double bond ايش بيصير
+
+103
+00:08:17,020 --> 00:08:22,340
+إيثين إيثين لو صار فيه triple bond إيثان إيثان لو صار
+
+104
+00:08:22,340 --> 00:08:28,890
+فيه OH إيثانول واضح فالتغيير في الآخر طيب الأن لو
+
+105
+00:08:28,890 --> 00:08:33,270
+صار في الديهايد ولو صار في المركب بعد هيك كيتون
+
+106
+00:08:33,270 --> 00:08:40,250
+إذا صار في الديهايد بنضيف له النهاية ال فهذا بيصير
+
+107
+00:08:40,250 --> 00:08:46,770
+methanol يبدو للأسف ناقصة كتابة ال a هنا قبل ال L
+
+108
+00:08:49,330 --> 00:08:54,070
+ليش؟ لأنه كم كربونة عندي هنا؟ واحدة كربونة واحدة
+
+109
+00:08:54,070 --> 00:09:00,190
+يعني ميثان الآن لما بيصير الديهايد ميثانال كربونة
+
+110
+00:09:00,190 --> 00:09:08,830
+واحدة كربونتين إيثان إيثانال ثلاث بروبانال أربعة
+
+111
+00:09:08,830 --> 00:09:15,520
+بيوتانال فال الديهايد بشكل عام بتاخد النهاية AL ال
+
+112
+00:09:15,520 --> 00:09:20,540
+-AL واضح؟ طبعًا هذا ما بيمنعش أن المركبات الصغيرة
+
+113
+00:09:20,540 --> 00:09:25,020
+فيها أسماء شهرة والناس كثير برا بتتعامل مع أسماء
+
+114
+00:09:25,020 --> 00:09:29,920
+شهرة بتاعتها يعني الميثانال اسمه formaldehyde
+
+115
+00:09:29,920 --> 00:09:37,000
+الإيثانال هو الacetaldehyde البروبانال بيسموه مرات
+
+116
+00:09:37,000 --> 00:09:38,740
+البروبيونالديهيد
+
+117
+00:09:45,930 --> 00:09:49,590
+البيوتانال بيسموه butyraldehyde
+
+118
+00:09:51,670 --> 00:09:57,070
+و مع الممارسة هتحسوا أن الشغلة مش .. مش هتكون صعبة
+
+119
+00:09:57,070 --> 00:10:02,950
+كثير عليكم الآن لو صار على المركب substituents
+
+120
+00:10:02,950 --> 00:10:08,610
+كثيرة أنتم هتلاقوا حالكم ملزمين تلقائيًا أنكم
+
+121
+00:10:08,610 --> 00:10:13,230
+تستعملوا الـ .. واضح؟
+
+122
+00:10:13,230 --> 00:10:20,330
+يعني لو بنسأل عن مركب وفيه substituents تلقائيًا
+
+123
+00:10:20,330 --> 00:10:27,050
+تستعملوا أي نومنكليتشر أيوباك نومنكليتشر أيوباك
+
+124
+00:10:27,050 --> 00:10:27,770
+نومنكليتشر أيوباك نومنكليتشر أيوباك نومنكليتشر أيوباك
+
+125
+00:10:27,770 --> 00:10:28,010
+نومنكليتشر أيوباك نومنكليتشر أيوباك نومنكليتشر أيوباك
+
+126
+00:10:28,010 --> 00:10:30,450
+نومنكليتشر أيوباك نومنكليتشر أيوباك نومنكليتشر أيوباك
+
+127
+00:10:30,450 --> 00:10:32,690
+نومنكليتشر أيوباك نومنكليتشر أيوباك نومنكليتشر أيوباك
+
+128
+00:10:32,690 --> 00:10:39,530
+نومنكليتشر أيوباك نومنكليتشر أيوباك نومنكليتشر أيوباك
+
+129
+00:10:39,530 --> 00:10:45,770
+نومنكليتشر أيوباك نومنكليتشر أيوباك نشو بدكم تسموه
+
+130
+00:10:45,770 --> 00:10:50,290
+butyraldehyde؟ وقتها لازم تيجي تسموا هذا المركب
+
+131
+00:10:50,290 --> 00:10:57,180
+كمشتقة بيوتانال واضح هنا بتكون تتذكروا القواعد اللي
+
+132
+00:10:57,180 --> 00:11:02,420
+أعطيناكم إياها حال التقاء أكثر من مجموعة وظيفية
+
+133
+00:11:02,420 --> 00:11:07,000
+من إله أولوية يعني هذا المركب مثلًا في مجموعة ال
+
+134
+00:11:07,000 --> 00:11:12,220
+الديهايد وفي مجموعة ال alcohol ال الديهايد أولويته
+
+135
+00:11:12,220 --> 00:11:15,800
+أعلى من ال alcohol عشانكم لما تترقبو تقولوا واحد اثنين
+
+136
+00:11:15,800 --> 00:11:21,700
+ثلاث أربع one two three four إذا كم substitute
+
+137
+00:11:21,700 --> 00:11:28,200
+عندي هنا اثنتان واضح لما بدي اسمي هذا المركب تسمية
+
+138
+00:11:28,200 --> 00:11:34,600
+كاملة شو بدي يصير اسمه two chloro three hydroxy
+
+139
+00:11:34,600 --> 00:11:45,420
+butanate اه two chloro three hydroxy butanate الآن
+
+140
+00:11:45,420 --> 00:11:51,780
+السؤال يلزم أن أقول one butanane لأن الالدهايد لا
+
+141
+00:11:51,780 --> 00:11:57,530
+تكون إلا طرفية على الموضوع واحد واضح؟ يعني دائمًا في
+
+142
+00:11:57,530 --> 00:12:00,710
+ال الديهايد يلزم .. أنا قلت هذا المركب الديهايد
+
+143
+00:12:00,710 --> 00:12:05,150
+إذا الـ C double bond O تبعته بتكون طرفية فإذا
+
+144
+00:12:05,150 --> 00:12:09,210
+المركب منسوب لل الديهايد ما يلزمش أني أجي أحط one
+
+145
+00:12:09,210 --> 00:12:14,510
+butanol بعد شوية لما نأخذ كيتون مثلًا 6 كربونات و
+
+146
+00:12:14,510 --> 00:12:17,190
+فيه C double bond O ممكن تكون والله على موقع اثنين
+
+147
+00:12:17,300 --> 00:12:21,700
+ممكن تكون على موقع ثلاثة بيصير ملزم أن أحدد وين
+
+148
+00:12:21,700 --> 00:12:25,620
+موقع الـ C double bond O في الكيتون لأن لو عندي
+
+149
+00:12:25,620 --> 00:12:29,220
+سلسلة طويلة في ال الديهايد دائمًا بتكون على نمرة
+
+150
+00:12:29,220 --> 00:12:32,420
+واحدة ده ميزة ال الديهايد أن ال C double bond O
+
+151
+00:12:32,420 --> 00:12:36,440
+على نمرة واحدة بس لو صار عندك كيتون بعشر ذرات
+
+152
+00:12:36,440 --> 00:12:39,700
+كربون هل ال C double bond O على موقع اثنين ثلاثة
+
+153
+00:12:39,700 --> 00:12:46,250
+أربعة خمسة احنا مش عارفين ولذلك يجب أن نضع أرقام في
+
+154
+00:12:46,250 --> 00:12:50,070
+حالة الـ ketone إذا كان لدينا لبس في موقع المجموعة
+
+155
+00:12:50,070 --> 00:12:54,110
+بس في ال الديهايد عمره ما أحد يحط وان بيوتانال خلاص
+
+156
+00:12:54,110 --> 00:12:57,910
+بيوتانال هي لا تكون إلا على موقع واحد واضح هذه
+
+157
+00:12:57,910 --> 00:13:02,470
+الفكرة؟ سنشوف أمثلة إضافية الآن جزء من الاروماتيك
+
+158
+00:13:02,470 --> 00:13:09,950
+كومباونز مر علينا هذا المركب ال benzaldehyde مر
+
+159
+00:13:09,950 --> 00:13:12,610
+علينا و بتعرفوا لو كان في substitution تاني
+
+160
+00:13:12,610 --> 00:13:17,910
+علمناكم كيف نسميه هذا المركب مثلًا هي في aldehyde
+
+161
+00:13:17,910 --> 00:13:23,610
+و OH لمن أولويته في التسمية لل aldehyde إذا أنا
+
+162
+00:13:23,610 --> 00:13:29,390
+هرقم منها وهمر أسرع ما يمكن على ال OH فبدي يكون
+
+163
+00:13:29,390 --> 00:13:33,990
+المركب 2-hydroxybenzaldehyde
+
+164
+00:13:33,990 --> 00:13:39,350
+يعني لو كتبتوا 2-hydroxybenzaldehyde it's okay الآن
+
+165
+00:13:39,350 --> 00:13:43,650
+مرات بيقولوا له بنزين carbaldehyde لكن الأشهر بنز
+
+166
+00:13:43,650 --> 00:13:46,830
+aldehyde زي ماذا بيسميه بنز aldehyde هذا two
+
+167
+00:13:46,830 --> 00:13:55,230
+hydroxy benz aldehyde هذا
+
+168
+00:13:55,230 --> 00:14:00,290
+المركب حاطينه مش عشان تحفظوا شكله بس على أساس
+
+169
+00:14:00,290 --> 00:14:06,190
+تشوفوا أن أنا عندي aldehyde و alcohol و مثلًا بنزين
+
+170
+00:14:06,190 --> 00:14:12,010
+تقولوا ايش الكيمياء هذه في النهاية هذا المركب هو ال
+
+171
+00:14:12,010 --> 00:14:15,850
+vanilla اللي بيعملوا فيها ال cake ال vanilla اللي
+
+172
+00:14:15,850 --> 00:14:19,690
+بيعملوا فيها ال cake الآن لو مجموعة ال aldehyde ..
+
+173
+00:14:19,690 --> 00:14:23,670
+لو مجموعة ال aldehyde اجت على حلقة وبدي اسميها
+
+174
+00:14:23,670 --> 00:14:30,800
+كمجموعة يعني هذه كلها Cyclopentane مظبوط ولا لأ؟ لو
+
+175
+00:14:30,800 --> 00:14:33,960
+كان ديهايد وبعد شوية لما يجيني أسد بنقول
+
+176
+00:14:33
+
+201
+00:16:53,240 --> 00:16:59,500
+إذا صار عنده أكثر من احتمال دائماً الأرقام بتلحط
+
+202
+00:16:59,500 --> 00:17:02,580
+إذا في عنده أكثر من احتمال عشان هي اللي بيكون 
+
+203
+00:17:02,580 --> 00:17:06,300
+لحاله ومافيش احتمالات كثيرة مابياخدش أرقام يعني
+
+204
+00:17:06,300 --> 00:17:12,420
+أعطيكم مثال في الأردن مثلاً الملك عبدالله بيكون
+
+205
+00:17:12,420 --> 00:17:19,710
+أبوه ولا سيده للملك حسين؟ لأ طبعاً سيده، الملك عبد
+
+206
+00:17:19,710 --> 00:17:23,650
+الله سيده للملك حسين، الملك حسين ابنه طلال، بس
+
+207
+00:17:23,650 --> 00:17:28,810
+أبوه طلال ماخلهوش ياخد الحكم غير حوالي كام من شهر
+
+208
+00:17:28,810 --> 00:17:32,510
+وبعدين شلوه وحطوا الملك حسين بداله، كان اسمه بس
+
+209
+00:17:32,510 --> 00:17:37,290
+الملك عبدالله، ليش؟ لأنه مافيش منافس ثاني، الآن
+
+210
+00:17:37,290 --> 00:17:42,130
+لما إجه حفيده، بعد ذلك سنقول عبدالله الثاني، وقت أنا 
+
+211
+00:17:42,130 --> 00:17:46,890
+بدأت أستعمل الأرقام إذا صار في عندي احتمال اللبس
+
+212
+00:17:46,890 --> 00:17:50,110
+واضح؟ الآن هنا مافيش غير موقع واحد تيجي فيه الـ C
+
+213
+00:17:50,110 --> 00:17:53,770
+double bond وعشان يبين كيتون، ولذلك مش كتير مهم 
+
+214
+00:17:53,770 --> 00:17:59,610
+أكتب to Propanone، لكن مثلاً هذا المركب اللي هنا لو
+
+215
+00:17:59,610 --> 00:18:05,750
+بتطلعي 1,2,3,4,5 كم احتمال ممكن يكون فيه كيتون في 
+
+216
+00:18:05,750 --> 00:18:11,970
+هذا المركب؟ لابس احتمالين، لاحظوا الـ C double
+
+217
+00:18:11,970 --> 00:18:17,330
+bond إذا إجت على أول موقع فمركبه 2-pentanone، إذا إجت
+
+218
+00:18:17,330 --> 00:18:23,870
+على الموقع الثاني 3-pentanol، إذا إجت على الموقع 
+
+219
+00:18:23,870 --> 00:18:28,760
+الثالث 3-pentanone، إذا أتيت عن موقع هذا اللي هنا
+
+220
+00:18:28,760 --> 00:18:32,980
+بتصير 2-pentanone من الجهة الثانية لأنه دائماً لازم
+
+221
+00:18:32,980 --> 00:18:36,960
+ناخد أقل ترقيم، مابتتصلش 4-pentanone لأنه لو
+
+222
+00:18:36,960 --> 00:18:40,680
+عديت واحدة منها واحد اثنين بترجع يشتوق 3-pentanone
+
+223
+00:18:40,680 --> 00:18:46,120
+في هذه الحالة أنا ملزم أن أحط أرقام لأن في عندي
+
+224
+00:18:46,120 --> 00:18:50,560
+خوف، في هذه الحالة مثلاً في الأربع ذرات كربون هل أنا
+
+225
+00:18:50,560 --> 00:18:57,090
+كثير ملزم أن أحط أرقام، لما أقول butanol، أساساً
+
+226
+00:18:57,090 --> 00:18:59,510
+مافيش شيء، لو هنا اثنين وهنا اثنين، يعني هذا
+
+227
+00:18:59,510 --> 00:19:04,550
+محطوطة في النهاية زيادة، واضح؟ احنا مش كثير بنحاسب 
+
+228
+00:19:04,550 --> 00:19:08,570
+لما طالبة تحطها بزيادة، لكن الخلاصة أن الشيء 
+
+229
+00:19:08,570 --> 00:19:14,460
+الواضح، اللي مافيش فيه منافسة، يمكن أن يُترك، الآن
+
+230
+00:19:14,460 --> 00:19:18,660
+مرات هذه الـ Ketones بيسموها common names، كيف 
+
+231
+00:19:18,660 --> 00:19:22,500
+بيسموها common names؟ بيجوا جنب الـ CWO وبياخدوا
+
+232
+00:19:22,500 --> 00:19:26,220
+المجموعات اللي محوطين، هذه مجموعة وهذه مجموعة هذه
+
+233
+00:19:26,220 --> 00:19:28,840
+المجموعة اللي هنا على اليمين أو على الشمال، شو
+
+234
+00:19:28,840 --> 00:19:35,520
+اسمها؟ Methyl ethyl Ketone، هذه مثل، فالمركبات بنسميه 
+
+235
+00:19:35,520 --> 00:19:41,990
+Ethyl Methyl Ketone، واضح، إيثل ميثيل كيتون، لو هذا بدنا
+
+236
+00:19:41,990 --> 00:19:47,970
+نتطلع مثلاً هذه المجموعة إيثل وهذه المجموعة إيثل فهذا 
+
+237
+00:19:47,970 --> 00:19:53,510
+بيسموه داى إيثل كيتون، داى إيثل كيتون، هذا نوع من ال
+
+238
+00:19:53,510 --> 00:19:56,750
+common nomenclature، نوع من ال common nomenclature
+
+239
+00:19:56,750 --> 00:19:58,970
+اللي هي التسمية الشعبية
+
+240
+00:20:01,360 --> 00:20:08,020
+الأساس في تسمية ال الديهيدز حرفين، والأساس في تسمية
+
+241
+00:20:08,020 --> 00:20:13,960
+ال ketones تلت حروف، ال الديهيدز لما بنسميه بنضيف
+
+242
+00:20:13,960 --> 00:20:17,840
+نهاية al لل ketones one 
+
+243
+00:20:20,550 --> 00:20:25,690
+one واضح؟ إذا كل مركب حتشوفه نهايته al إذا هو 
+
+244
+00:20:25,690 --> 00:20:31,990
+الديهايد ونهايته one إذا هو كيتون، هنا مثلاً هذا
+
+245
+00:20:31,990 --> 00:20:39,210
+المركب Cyclohexane بيصير Cyclohexanone، بيلزم نيجي
+
+246
+00:20:39,210 --> 00:20:45,630
+نقول one Cyclohexanone؟ مابيلزم لأن كل المواقع في
+
+247
+00:20:45,630 --> 00:20:51,560
+Cyclohexane تعتبر مواقع متساوية، هذا الـ Ketone
+
+248
+00:20:51,560 --> 00:20:56,200
+أخدتوله اسم، أنتو لما تكون مجموعة الأسيتا على
+
+249
+00:20:56,200 --> 00:21:02,520
+البنزين سمناه أسيتوفينون وممكن نسميه برضه على أساس
+
+250
+00:21:02,520 --> 00:21:06,040
+أن هذا كيتون، هاى مجموعة أو هاى مجموعة ماذا يسمى
+
+251
+00:21:06,040 --> 00:21:12,420
+هذه المجموعة؟ فنل فبيصير مثل فنل كيتون، أو لأن كل 
+
+252
+00:21:12,420 --> 00:21:17,540
+هذه المجموعة أسيتل بيصير أسيتوفينون، أخدناها في
+
+253
+00:21:17,540 --> 00:21:22,920
+الأروماتيك كومباونز أسيتوفينون، المركب هذا الداى
+
+254
+00:21:22,920 --> 00:21:24,060
+فنل كيتون
+
+255
+00:21:28,880 --> 00:21:33,840
+Diphenylketone برضه بياخد اسم شهرة بنزوفينون هو
+
+256
+00:21:33,840 --> 00:21:37,200
+يعامل ك أيوبك حتى بنزوفينون، خلاص يعني بيصيروا
+
+257
+00:21:37,200 --> 00:21:43,160
+عارفينه إيش اسمه بنزوفينون، إذا بنزوفينون
+
+258
+00:21:43,160 --> 00:21:47,180
+أسيتوفينون، كل المركبات هذه عبارة عن يعني خليني
+
+259
+00:21:47,180 --> 00:21:53,120
+أقول Simple Compounds مافيش فيها Substituent
+
+260
+00:21:55,560 --> 00:21:58,680
+يعني تغلب في التسمية مافيش فيها Substituency، تغلب
+
+261
+00:21:58,680 --> 00:22:04,700
+في التسمية لكن احنا بالتأكيد بإمكاننا الآن نعطي 
+
+262
+00:22:04,700 --> 00:22:08,920
+مركبات أعقد بتحتوي على أكثر من مجموعة وظيفية 
+
+263
+00:22:08,920 --> 00:22:12,680
+ونقولكم كيف بنسميها ومن أمثال هذه المركبات احنا 
+
+264
+00:22:12,680 --> 00:22:16,320
+لو كنا بدنا نسأل في الامتحان يعني هذه كلها تعتبر 
+
+265
+00:22:16,320 --> 00:22:21,660
+مقدمة، الخلاصة عشان نذكركم، قولنا النهاية قال
+
+266
+00:22:26,730 --> 00:22:30,930
+الأولويات إذا التقت في الجزء أكثر من مجموعة
+
+267
+00:22:30,930 --> 00:22:36,970
+الألكين أقل من الألكين أقل من الكحول أقل من
+
+268
+00:22:36,970 --> 00:22:41,280
+الكيتون أقل من ال الديهايد، أقل من الاسيد، أقل من ال
+
+269
+00:22:41,280 --> 00:22:46,760
+ايستر، يعني الجزء لو التقف فيه كيتون مع الديهايد
+
+270
+00:22:46,760 --> 00:22:51,020
+الأولوية لمن؟ لل الديهايد، بداية الترقيم من أين؟ 
+
+271
+00:22:51,020 --> 00:22:59,300
+نهاية الاسم الـ al، لما المركب يكون في الـ al و one،
+
+272
+00:22:59,300 --> 00:23:07,070
+نهايته الـ al والـ ol، قال يعني الديهايد والـ ol 
+
+273
+00:23:07,070 --> 00:23:12,230
+الكحول، قال والـ ol، يعني زي هذا المركب لو حطيناها
+
+274
+00:23:12,230 --> 00:23:16,230
+نقاش طبعاً لاحظوا أكيد كلكم مش لازم تقلطوا على
+
+275
+00:23:16,230 --> 00:23:18,930
+الغلطة لما هذا أنا أكون سايبها مش كاتب فيها شيء
+
+276
+00:23:18,930 --> 00:23:24,630
+إيش معناها CH3 في ناس كثير للأسف بيقلطوا يعني في
+
+277
+00:23:24,630 --> 00:23:28,710
+الامتحان اللي عملوا بصلحوا عندكم مركب بنتين يمكن 
+
+278
+00:23:28,710 --> 00:23:32,030
+تلت بنات كاتبين بنتين رغم إن كلكم بنات كلكم
+
+279
+00:23:32,030 --> 00:23:37,780
+عاملينه بيوتين، طيب مبين فيه خمس كربونات واضح يعني
+
+280
+00:23:37,780 --> 00:23:41,880
+هذا لما بتعده هذه كربونة، طالما أنا أتركها مش كاتب
+
+281
+00:23:41,880 --> 00:23:45,860
+جنبها H بتظهر كربونة لكن في مثل هذه الحالة بتصير 
+
+282
+00:23:45,860 --> 00:23:51,880
+إيش، الآن لو بدنا نسمي هذا المركب إيش اللي موجود 
+
+283
+00:23:51,880 --> 00:23:57,300
+عندي هنا الديهايد وكلوروميثيل بيظهر للاصل
+
+284
+00:23:57,300 --> 00:24:04,450
+الديهايد واحد اثنين ثلاثة أربعة إذا هذا بيوتانال 
+
+285
+00:24:04,450 --> 00:24:05,770
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+286
+00:24:05,770 --> 00:24:09,670
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+287
+00:24:09,670 --> 00:24:14,690
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+288
+00:24:14,690 --> 00:24:15,130
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+289
+00:24:15,130 --> 00:24:15,170
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+290
+00:24:15,170 --> 00:24:15,190
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+291
+00:24:15,190 --> 00:24:22,210
+بيوتانال بيوتانال بيوتانال بيوتان
+
+292
+00:24:24,200 --> 00:24:29,380
+طبعاً بدنا نشوف أقل ترقيم يعني إذا عدينا 1,2,3,4,1
+
+293
+00:24:29,380 --> 00:24:34,020
+,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2
+
+294
+00:24:34,020 --> 00:24:35,460
+,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3
+
+295
+00:24:35,460 --> 00:24:40,120
+,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,لما كان
+
+296
+00:24:40,120 --> 00:24:45,440
+عندي هنا الـ al ماحطتش رقم هي دائماً وأبداً واحد لكن
+
+297
+00:24:45,440 --> 00:24:51,200
+لما كان عندي one حددت الـ one إيش هي الـ one وين موقعها
+
+298
+00:24:51,200 --> 00:24:56,340
+جاى على موقع ثلاثة وعلى اثنين وأربعة إيش عندكم
+
+299
+00:24:56,340 --> 00:25:01,320
+دايمثل، إذا هذا المركب 2,4-dimethyl-3-
+
+300
+00:25:01,320 --> 00:25:07,840
+hexanol، واضح، الآن هذا المركب إيش اللي بيلتقى فيه
+
+301
+00:25:08,300 --> 00:25:13,780
+acid و .. وين الـ acid احنا أخدنا الـ acid جبنا
+
+302
+00:25:13,780 --> 00:25:20,120
+سيرة الـ acid، الـ acid لما يكون من نفس الكربونة طالع
+
+303
+00:25:20,120 --> 00:25:25,820
+مستوي بالـ bond O والـ OH وهذا موضوع chapter 10
+
+304
+00:25:25,820 --> 00:25:30,180
+احنا ولا جبنا سيرته، مستوي بالـ bond O والـ OH لما 
+
+305
+00:25:30,180 --> 00:25:34,800
+يكونوا طالعين من نفس الكربونة، بنحكي عن acid الآن
+
+306
+00:25:34,800 --> 00:25:39,750
+هذولا من الكربونات مختلفة هذا مش asset إطلاقاً هذا
+
+307
+00:25:39,750 --> 00:25:46,770
+مركب فيه one و one، الأولوية له الـ one إذا نهاية
+
+308
+00:25:46,770 --> 00:25:51,150
+المركب one والترقيم بيمشي أسرع ما يمكن على الـ seed
+
+309
+00:25:51,150 --> 00:25:54,350
+of الـ bond أو الـ ketone، كتابة الـ ketone one two
+
+310
+00:25:54,350 --> 00:26:00,890
+three four five إذا هذا عبارة عن two بالـ one ال
+
+311
+00:26:00,890 --> 00:26:08,720
+two بتحدد موقع الـ one موقع الكيتون، وإيش جاي فيه على 
+
+312
+00:26:08,720 --> 00:26:17,760
+موقع أربعة 4-hydroxy-2-pentanone 4-hydroxy-2
+
+313
+00:26:17,760 --> 00:26:22,620
+-pentanone لأن التقاء الكحول مع الكيتون الأولوية
+
+314
+00:26:22,620 --> 00:26:29,360
+فيه بالترقيم التسمية للكيتون، المثال اللي بعيد 
+
+315
+00:26:29,360 --> 00:26:37,230
+عبارة عن التقاء الديهايد وكيتون، خليني بس أنوح هنا
+
+316
+00:26:37,230 --> 00:26:46,170
+لنقطة الـ OH، الـ OH لما تكون مجموعة مركب يعني المركب
+
+317
+00:26:46,170 --> 00:26:50,870
+كله منسوب إليها هي شو بيصير؟ بيقول عنها هيدروكسي
+
+318
+00:26:50,870 --> 00:26:57,520
+إذا أنا الـ OH بتعامل معها بمسمى Hydroxy إذا أصبحت 
+
+319
+00:26:57,520 --> 00:27:02,940
+مجموعة لكن إذا المركب منسوب إلها بيكون كل المركب
+
+320
+00:27:02,940 --> 00:27:13,140
+نهايته O الـ al هيجيبنا الكلام نفسه مع الـ C double
+
+321
+00:27:13,140 --> 00:27:19,820
+bond O، الـ C double bond O لو كانت الديهايد بتكون
+
+322
+00:27:21,010 --> 00:27:27,510
+أقل، لو كانت كيتون al، الآن، لو في أعلى منها،
+
+323
+00:27:27,510 --> 00:27:31,790
+هترجع مجموعة،
+
+324
+00:27:31,790 --> 00:27:35,970
+واضح؟ يعني لو إنه كان مع acid، وعنكم C double bond
+
+325
+00:27:35,970 --> 00:27:40,610
+O كيتونية و C double bond O كمان، تبعت aldehyde،
+
+326
+00:27:40,610 --> 00:27:45,970
+بس أنا اللي عنديا acid، هيرجعوا لاسمهم الأصلي، شو
+
+327
+00:27:45,970 --> 00:27:54,410
+اسمهم الأصلي؟ Oxo، أكزو من الـ Oxygen واضح؟ بناء على
+
+328
+00:27:54,410 --> 00:27:57,790
+ذلك، لما طلع هذا المركب هاى الالديهيد وهي الكيتون
+
+329
+00:27:57,790 --> 00:28:02,970
+الالديهيد كان جنبه H، مركبي بأنسبه لإيش؟
+
+330
+00:28:02,970 --> 00:28:07,850
+للالديهيد، الالديهيد أقوى من الكيتون، مركبي بأنسبه
+
+331
+00:28:07,850 --> 00:28:14,190
+للالديهيد، إذا نهاية مركبي الـ al، واضح؟ إذا هنا
+
+332
+00:28:14,190 --> 00:28:19,770
+بعد واحد اثنين ثلاثة أربعة هذا المركب بيوتانال
+
+333
+00:28:19,770 --> 00:28:23,830
+هذا
+
+334
+00:28:23,830 --> 00:28:29,370
+الـ butanol على موقع ثلاثة بيحمل الـ C double bond
+
+335
+00:28:29,370 --> 00:28:34,330
+O، هنا بطلت كيتون لأنه خلاص هو المركب بيُنسب
+
+336
+00:28:34,330 --> 00:28:38,550
+لمجموعة وظيفية واحدة نصف ال الديهايد، خلصت إذن هنا
+
+337
+00:28:38,550 --> 00:28:42,630
+الـ C double bond O رجعت لأصل اسمها إيش أصل اسمها
+
+338
+00:28:42,630 --> 00:28:50,490
+أوكزو أوكزو، واضح؟ أصلها أوكزو فبيصير هذا 3-
+
+339
+00:28:50,490 --> 00:28:58,070
+-oxobutanal واضح؟
+
+340
+00:28:58,070 --> 00:29:01,170
+كذلك الحال لو بعد شوية مثلاً باخد acid ومعه
+
+341
+00:29:01,170 --> 00:29:05,450
+aldehyde مركب يحب يقول عنه acid، الـ aldehyde شو
+
+342
+00:29:05,450 --> 00:29:12,200
+هتصير اسمها؟ أوكزو، هنبطل نقول عنها aldehyde إذا أصبحت 
+
+343
+00:29:12,200 --> 00:29:16,200
+الـ C double bond O عبارة عن مجموعة عادية المركب 
+
+344
+00:29:16,200 --> 00:29:21,180
+مش منسوب إلها بنعبر عنها F-oxo، والـ OH إذا كان
+
+345
+00:29:21,180 --> 00:29:27,460
+المركب مش منسوب إلها بنسميها Hydroxy واضح؟ المركب
+
+346
+00:29:27,460 --> 00:29:32,040
+اللي بعده مين تحكيلنا عنه؟ تتأملوا فيه هيك شوية إيش
+
+347
+00:29:32,040 --> 00:29:38,220
+اللي موجود في هذا آخر مركب؟ كيتون وإيش؟ مؤلقين
+
+348
+00:29:40,460 --> 00:29:44,360
+كيتون وألكين، الكيتون أقوى من الألكين إذا هو
+
+349
+00:29:44,360 --> 00:29:51,360
+كعائلة آخر شيء بده يظهر في اسمه الـ one والترقيم
+
+350
+00:29:51,360 --> 00:29:57,940
+بده يمر أسرع ما يمكن برضه على الـ one عن كيتون، لما 
+
+351
+00:29:57,940 --> 00:30:04,060
+نيجي نقول one two three four five six هذا عبارة عن
+
+352
+00:30:04,060 --> 00:30:13,080
+هكسانون، الآن هذا الهكسانون واحد منه صارف بيصير هي
+
+353
+00:30:13,080 --> 00:30:17,920
+موقعها بالرقم، والـ double bond كان ممكن تكون هنا
+
+354
+00:30:17,920 --> 00:30:22,740
+أو هنا أو هنا، إذا يجب تحديد نقطة بدايتها كمان
+
+355
+00:30:22,740 --> 00:30:27,740
+بالرقم، إيش نقطة بدايتها هاد الـ double bond ثلاثة
+
+356
+00:30:27,740 --> 00:30:34,560
+إذا هنا يجب نقطة أو نقطة نقطة نقطة نقطة نقطة نقطة
+
+357
+00:30:34,560 --> 00:30:40,600
+نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة
+
+358
+00:30:40,600 --> 00:30:42,050
+نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة ثالث
+
+359
+00:30:42,050 --> 00:30:47,790
+ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث
+
+360
+00:30:47,790 --> 00:30:54,010
+ثلاث ثلاث ثلاث ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+361
+00:30:54,010 --> 00:30:56,550
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+362
+00:30:56,550 --> 00:30:56,830
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة
+
+363
+00:30:56,830 --> 00:31:04,690
+ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة ثلاثة هنقولكم ارسمولنا
+
+364
+00:31:04,690 --> 00:31:09,970
+هذا المركب، بتحطوا 6 carbonate، بعدين هتيجوا على
+
+365
+00:31:09,970 --> 00:31:21,090
+موقع 2، تحطوا one، وعلى موقع 3، تحطوا double
+
+366
+00:31:21,090 --> 00:31:23,490
+bond، واضح؟
+
+367
+00:31:36,
+
+401
+00:34:29,770 --> 00:34:34,330
+اعطوا حروف من بعدها لاتينية Alpha, Beta, Gamma,
+
+402
+00:34:34,390 --> 00:34:38,450
+Delta واضح بعد الـ C double bond O الآن إذا
+
+403
+00:34:38,450 --> 00:34:42,270
+اعطيتها أنا Alpha و أنا Beta وين جاية الـ OH على
+
+404
+00:34:42,270 --> 00:34:47,270
+موقع Beta فكانوا يقولوا Beta Hydroxybutyraldehyde
+
+405
+00:34:49,380 --> 00:34:52,800
+common name هذا common name  الايوبك بيظله three
+
+406
+00:34:52,800 --> 00:34:56,900
+-hydroxybutanol لكن أنتم لو قرأته Beta
+
+407
+00:34:56,900 --> 00:35:01,300
+-hydroxybutyraldehyde بتكون تسيبوا مجموعة الـ C
+
+408
+00:35:01,300 --> 00:35:05,960
+double bond O و تبدأوا تحطوا من بعدها Alpha Beta
+
+409
+00:35:05,960 --> 00:35:11,720
+Delta Gamma بصير كل الكلام Alpha Beta Gamma Delta
+
+410
+00:35:11,720 --> 00:35:15,540
+Gamma لو اجت هنا نفس الشيء لو اجت هنا واضح
+
+411
+00:35:19,360 --> 00:35:26,940
+هذا المركب ما شاء الله عنه صدقوني
+
+412
+00:35:26,940 --> 00:35:31,860
+مش صعب يعني لو جيبناه في الامتحان و قلنا لوحده
+
+413
+00:35:31,860 --> 00:35:36,180
+فيكم تحلله ولا شيء تقول هذه المجموعة إيش اسمها؟
+
+414
+00:35:36,180 --> 00:35:41,820
+فينل و هذه المجموعة؟ كلور و هذا C double bond O
+
+415
+00:35:41,820 --> 00:35:47,380
+aldehyde كم ذرة عندكم؟ اثنتين، ثلاث إذا المركب
+
+416
+00:35:47,380 --> 00:35:47,780
+إيه؟
+
+417
+00:35:50,640 --> 00:35:57,120
+بس لأنه في double bond بتبدأ من موقع اثنين إبروبين
+
+418
+00:35:57,120 --> 00:36:02,360
+ال إذا هنا لما أنا أقول ال two إبروبين ال ال two
+
+419
+00:36:02,360 --> 00:36:07,980
+تعبر عن إيش؟ عن موقع ال double bond أن هذا المركب
+
+420
+00:36:07,980 --> 00:36:11,980
+إبروبين ال في double bond و في ال ال ما نسمها
+
+421
+00:36:11,980 --> 00:36:17,640
+ترقيم دائما و أبدا يا مخدر رقم واحد إذا هذه ال two
+
+422
+00:36:17,640 --> 00:36:23,140
+بتحدد لموقع إيش؟ لموقع الرابطة الثنائية نهجية على E
+
+423
+00:36:23,140 --> 00:36:28,680
+الآن بعد ذلك أتيت عندكم ثلاثة كلورو ثلاثة فينيل
+
+424
+00:36:28,680 --> 00:36:33,120
+ثلاثة كلورو ثلاثة فينيل ثلاثة كلورو ثلاثة كلورو
+
+425
+00:36:33,120 --> 00:36:42,680
+ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو
+
+426
+00:36:50,250 --> 00:36:57,510
+كمجموعة مش مانا متصل C هنا carbon متصل CL متصل
+
+427
+00:36:57,510 --> 00:37:02,070
+carbon إذا المجموعة تلك بار على جهة واحدة فهذا
+
+428
+00:37:02,070 --> 00:37:10,630
+المركب إيش بيصير Z ثلاثة كلوروز ثلاثة كلوروز ثلاثة
+
+429
+00:37:10,630 --> 00:37:12,270
+كلوروز ثلاثة كلوروز ثلاثة كلوروز ثلاثة كلوروز
+
+430
+00:37:12,270 --> 00:37:12,330
+ثلاثة كلوروز ثلاثة كلوروز ثلاثة كلوروز
+
+431
+00:37:16,880 --> 00:37:23,340
+هذا سبوب الأحمر بنزالديهيد على موقع بارا إيش عليه
+
+432
+00:37:23,340 --> 00:37:28,660
+بارا نايترو بنزالديهيد ما تستغربوا إذا جئتم في
+
+433
+00:37:28,660 --> 00:37:33,140
+كتاب قديم كاتبه بارا نايترو بنزيل كاربالديهيد
+
+434
+00:37:33,140 --> 00:37:36,700
+بتاية اللي قبل شوية حكيت لكم عنها لكن الأسهل
+
+435
+00:37:36,700 --> 00:37:45,620
+بنزالديهيد هذا سايكلوبنتين كاربالديهيد
+
+436
+00:37:47,090 --> 00:37:50,570
+مشغولنا لما بيحمل مجموعة الـ C double bond OH
+
+437
+00:37:50,570 --> 00:37:55,510
+بنقول عنها carb-aldehyde هذه المجموعة إذا هي carb
+
+438
+00:37:55,510 --> 00:38:01,050
+-aldehyde و هذا عبارة عن Cyclopentane
+
+439
+00:38:01,050 --> 00:38:04,730
+-carb-aldehyde حامل على موقع اثنين، لاحظوا ترقيمي
+
+440
+00:38:04,730 --> 00:38:07,230
+بدأته من وين؟ من ال الديهايد، إيش حامل على موقع
+
+441
+00:38:07,230 --> 00:38:11,730
+اثنين؟ two ethyl و عمل لكم الأسهم باتجاهكم، إذا
+
+442
+00:38:11,730 --> 00:38:18,380
+الاثنتين على جهة واحدة من حلقة، إذا مركب سسواضح؟
+
+443
+00:38:18,380 --> 00:38:22,560
+زي السؤال اللي اجاكم في الامتحان سيس ولا واحدة
+
+444
+00:38:22,560 --> 00:38:27,720
+جايبها غلط كله جبته صح طبعا هنا
+
+445
+00:38:27,720 --> 00:38:33,620
+الديهايد و الديهايد على الطرفين ذرة اثنتين، ثلاث،
+
+446
+00:38:33,620 --> 00:38:39,880
+أربع، خمس، بنسميه بنتين دايالمش لو كان OH OH
+
+447
+00:38:39,880 --> 00:38:45,620
+بدنا نقول diol اه هنا الديهايد و الديهايد الديهايد
+
+448
+00:38:45,620 --> 00:38:49,920
+اسمه الشهرة glutaraldehyde معناه و معناه هدول
+
+449
+00:38:49,920 --> 00:38:54,400
+كلهم من عيلة ال الديهايد أمثلة اثرائية زي ما قلنا
+
+450
+00:38:54,400 --> 00:38:59,000
+هنا الأسيتون أو الروبانون اخذناه الأسيتوفينون
+
+451
+00:38:59,000 --> 00:39:06,070
+اخذناه مشتقة Cyclohexanone انتم المهم تحددوا الأصل
+
+452
+00:39:06,070 --> 00:39:11,210
+تبعه هذا كله مشتقة Cyclohexanone و حطوا واحد اثنين
+
+453
+00:39:11,210 --> 00:39:14,930
+ثلاث أربع و بعدين اعطوا أرقام هذا Cyclohexanone
+
+454
+00:39:14,930 --> 00:39:21,450
+على ال two في برومو و على ال four دايمثل إذا two
+
+455
+00:39:21,450 --> 00:39:28,270
+برومو four four دايمثل Cyclohexanone هذا المركب
+
+456
+00:39:28,270 --> 00:39:32,770
+اللي شايفينه مين تقولي كيف بده يسميه؟ بنزان بنزين
+
+457
+00:39:32,770 --> 00:39:37,010
+حامل أشياء كثيرة انسوها كبنزين عملوها على أنها
+
+458
+00:39:37,010 --> 00:39:45,310
+مجموعة فينل و اعتبروا أن هذا المركب تبعي كم كربونا؟
+
+459
+00:39:45,310 --> 00:39:53,930
+لا بيجي كمان واحدة هنا عشان تصير أطول سلسلة ثلاث
+
+460
+00:39:53,930 --> 00:39:58,990
+كربونات و هذه جاية بين مجموعتين الكل يعتبر اللي
+
+461
+00:39:58,990 --> 00:40:05,910
+عندك كيتون يعتبر اللي عندك كيتون بروبانون الآن هنا
+
+462
+00:40:05,910 --> 00:40:10,390
+بدنا نقول one two three على ال one في عندنا phenyl
+
+463
+00:40:10,390 --> 00:40:17,330
+و على ال two مثل و مثل إذا two two دايمثل one
+
+464
+00:40:17,330 --> 00:40:22,770
+phenyl بروبانون تو تو دايمثل وان فيل البروبانون أو
+
+465
+00:40:22,770 --> 00:40:30,870
+كان ممكن تقول وان بروبانون مش مشكلة كبيرة هذا
+
+466
+00:40:30,870 --> 00:40:36,330
+المركب one two three four five سايكلو بنتين سايكلو
+
+467
+00:40:36,330 --> 00:40:44,140
+بنتان on on ولا on ondie on إذا هذا بيصير one
+
+468
+00:40:44,140 --> 00:40:48,080
+three ليش؟ لأن ال die on هدول اثنتين ال on وين
+
+469
+00:40:48,080 --> 00:40:52,100
+موجودين؟ على واحد و ثلاث إذا هذا one three
+
+470
+00:40:52,100 --> 00:40:58,300
+cyclobentain die on إيش
+
+471
+00:40:58,300 --> 00:41:07,000
+عليه غير ال die on؟ two two die مثل عليه two two
+
+472
+00:41:07,000 --> 00:41:16,370
+die مثل نشوف آخر مركب هذه الحلقة عملوها Substitute
+
+473
+00:41:16,370 --> 00:41:21,410
+Cyclobutane هي عندك ذرة اثنتين ثلاث هذا المجموعات
+
+474
+00:41:21,410 --> 00:41:27,850
+الوظيفية عليها ثلاث كربونات شو هم الديهايد
+
+475
+00:41:27,850 --> 00:41:35,550
+و كيتون مركب لإيش بنسبة الديهايد إذا هذا عبارة عن
+
+476
+00:41:35,550 --> 00:41:44,130
+مشتقة Probanal Probanal على موقع ثلاث السبب اللي
+
+477
+00:41:44,130 --> 00:41:48,510
+بتقولها لما ترجع لأصلها شو اسمها اقزو إذا three
+
+478
+00:41:48,510 --> 00:41:55,770
+oxo-probanal و على three أيضا cyclobutyl إذا three
+
+479
+00:41:55,770 --> 00:42:04,150
+oxo-cyclobutyl-probanal three oxo-cyclobutyl
+
+480
+00:42:04,150 --> 00:42:11,880
+-probanal واضح بتيألي هيكل ما بديش أشرح غير التسمية
+
+481
+00:42:11,880 --> 00:42:14,640
+اليوم يعني إذا بدكم و لابد بعطيكم مركب انتم
+
+482
+00:42:14,640 --> 00:42:22,620
+تسموه لكن أكثر من هيك المرة الجاية هذه ال slide
+
+483
+00:42:22,620 --> 00:42:26,820
+تاب على التسمية هذه ال slide تاب على التسمية لازم
+
+484
+00:42:26,820 --> 00:42:31,660
+نمر عليها بدقيقة انتبهوا معي تعلمناهم مثل
+
+485
+00:42:31,660 --> 00:42:35,600
+اثيل بروبيل ايزوبروبل ترت بيوت الواطفار لما اخذنا
+
+486
+00:42:35,600 --> 00:42:43,140
+الالكينز قلنا في عندنا بعض المجموعات الشهيرة الفينل
+
+487
+00:42:43,140 --> 00:42:51,560
+و الأليل الآن في ال .. مجموعات
+
+488
+00:42:51,560 --> 00:42:58,440
+يعني السبب اللي قلت OH كمجموعة
+
+489
+00:42:58,440 --> 00:43:05,310
+بيكون اسمها formal و الـ C double bond O CH3 بيكون
+
+490
+00:43:05,310 --> 00:43:10,870
+اسمها Acetyl و الـ C double bond O Phenyl بيكون
+
+491
+00:43:10,870 --> 00:43:17,570
+اسمها Benzyl لا مش Benzyl انتبهوا معي، هذه
+
+492
+00:43:17,570 --> 00:43:22,410
+Benzyl ليش احنا بنركز أنها مش Benzyl لأن حقيقة في
+
+493
+00:43:22,410 --> 00:43:26,050
+مجموعة ثانية في ال organ ال chemistry اسمها Benzyl
+
+494
+00:43:26,830 --> 00:43:32,550
+واضح؟ المجموعة ال بنزل بنطعم هذه المجموعة اللي هي
+
+495
+00:43:32,550 --> 00:43:39,330
+زي هيك و CH2 هذه المجموعة اسمها بنزل فماحدش يخربط
+
+496
+00:43:39,330 --> 00:43:52,630
+كلمة بنزل بنزل و بنزايل و حطيت هنا CH2CL و قلت لكم
+
+497
+00:43:52,630 --> 00:43:57,980
+سمولي هذا المركب بالـ common nomenclature بنزل
+
+498
+00:43:57,980 --> 00:44:07,540
+كلوريد لأن هذه المجموعة كلها اسم Benzyl بنزل تبني
+
+499
+00:44:07,540 --> 00:44:15,460
+في المركز المركب صوفي برمضان و بارك يعني تبني في
+
+500
+00:44:15,460 --> 00:44:22,260
+المركب المركب الصوفي برمضان و بارك
+
+501
+00:44:24,810 --> 00:44:30,650
+بنزيل بنزيل كلوريد
+
+502
+00:44:30,650 --> 00:44:37,690
+بالايوباك هلأ
+
+503
+00:44:37,690 --> 00:44:46,070
+مشتقة إيش؟ مثيل، بس كرمولة واحدة، شو بيحمل
+
+504
+00:44:46,070 --> 00:44:55,520
+المثيل؟ كلور ثانل مثيل كأنه أصله CH4 شيلنا H
+
+505
+00:44:55,520 --> 00:45:00,800
+و عطينا Cl و شيلنا H و عطينا Ph إذا هو مشتقة مثيل
+
+506
+00:45:04,270 --> 00:45:10,050
+مثل بنزل كلوريد فلما نقول بنزل كلوريد مركب و
+
+507
+00:45:10,050 --> 00:45:16,890
+لما نقول بنزايل كلوريد مركب ثاني مختلف رجال ما
+
+508
+00:45:16,890 --> 00:45:25,270
+تخلطوا بينهم بنزايل و بنزل مركبين مختلفين H
+
+509
+00:45:25,270 --> 00:45:29,770
+-formyl سيضاو المندقو مثل أسيتل و سيضاو بالمندقو
+
+510
+00:45:29,770 --> 00:45:32,390
+فينل بنزايد
+
+511
+00:45:35,400 --> 00:45:39,960
+بهيك بننتهي اليوم في موضوع التسمية
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..10dbd16a4fd546f372c1b3f6b3fa4df46c33e056
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ed3N8wlqqQ4_postprocess.srt
@@ -0,0 +1,2044 @@
+1
+00:00:09,000 --> 00:00:12,660
+بنبدأ اليوم بالفصل التاسع، العنوان هو الـ
+
+2
+00:00:12,660 --> 00:00:17,420
+aldehydes والكيتوز الان الفصل التاسع و الفصل
+
+3
+00:00:17,420 --> 00:00:24,320
+العاشر بيتكلم عن المركبات اللي فيها رابطة C double
+
+4
+00:00:24,320 --> 00:00:31,060
+bond O هذه المجموعة الـ C double bond O في أي مكان
+
+5
+00:00:31,060 --> 00:00:36,530
+كانتبسموها الـ carbonyl group يعني المجموعة نفسها
+
+6
+00:00:36,530 --> 00:00:40,410
+الـ C double bond O لحالها بيقولوا عنها ال
+
+7
+00:00:40,410 --> 00:00:45,170
+carbonyl group الآن المركبات اللي فيهمC double
+
+8
+00:00:45,170 --> 00:00:50,570
+bond O بنقول عنهم Carbonyl compounds واضح؟ إذا في
+
+9
+00:00:50,570 --> 00:00:54,290
+عندي Carbonyl group و Carbonyl compounds ال
+
+10
+00:00:54,290 --> 00:00:58,130
+Carbonyl compounds أنواع كتيرة يعني موجود في كتير
+
+11
+00:00:58,130 --> 00:01:02,890
+موجود في كتير C double bond O يعني مثلا في ال
+
+12
+00:01:02,890 --> 00:01:07,960
+aldehydes ال C double bond O جنب hydrogenفي الـ
+
+13
+00:01:07,960 --> 00:01:11,560
+ketones الـ C double bond O جنب أو بين two R
+
+14
+00:01:11,560 --> 00:01:16,580
+groups في الأحماض الـ carboxylic acids بيكون عندي
+
+15
+00:01:16,580 --> 00:01:20,340
+C double bond O OH في ال E stars بيكون عندي C
+
+16
+00:01:20,340 --> 00:01:25,060
+double bond O OR في الأبد C double bond O NH2 في
+
+17
+00:01:25,060 --> 00:01:29,300
+ال acid chlorides C double bond O Cl بيجي كمان
+
+18
+00:01:29,300 --> 00:01:33,440
+عائلة ال acid anhydrides بتمر علينا في الفصل
+
+19
+00:01:33,440 --> 00:01:37,800
+العاشر مع هدول المجموعةالان هذه ال carbonyl
+
+20
+00:01:37,800 --> 00:01:43,640
+compounds كلها بجسمها نوعين وبناء على ذلك كمان
+
+21
+00:01:43,640 --> 00:01:48,600
+بتبين في تقسيم الفصول في الكتاب يعني ال aldehydes
+
+22
+00:01:48,600 --> 00:01:54,460
+و ال ketones يعتبروا نوعو ال acid و بيقولوا عن هذه
+
+23
+00:01:54,460 --> 00:01:58,880
+الأشياء كلها مشتقات ال acid طالعة من الحامض بتيجي
+
+24
+00:01:58,880 --> 00:02:04,540
+نوع تاني، الآن ليش هذا التصنيف؟ ليش ال aldehydes و
+
+25
+00:02:04,540 --> 00:02:08,800
+ال ketones؟ نوع و بنفسله عادة في جميع كتب ال
+
+26
+00:02:08,800 --> 00:02:13,730
+organic تقريبابفصلوه في فصل مستقل لحاله والأحماض
+
+27
+00:02:13,730 --> 00:02:18,230
+ومشتقاتها بتلاقوها بفصل تاني لحالها لأن هدولة
+
+28
+00:02:18,230 --> 00:02:24,360
+باختلفوا اختلاف كبير في طريقة التفاعلفي المحصلة
+
+29
+00:02:24,360 --> 00:02:29,280
+هتتعلموا كلمتين اللي بيدقن هدولا الكلمتين عن فهم
+
+30
+00:02:29,280 --> 00:02:34,320
+بيكون استوعب المادة كلها اللي هي الفصل التاسع
+
+31
+00:02:34,320 --> 00:02:39,720
+والفصل العاشر ان ال الديهايتس والكيتونز التفاعل
+
+32
+00:02:39,720 --> 00:02:46,650
+الأساسي تبعهم هو تفاعل إضافة additionوالأحماض
+
+33
+00:02:46,650 --> 00:02:51,430
+ومشتقاتها التفاعل الأساسي تبعهم تفاعل إبدال
+
+34
+00:02:51,430 --> 00:02:55,950
+substitution واضح؟ يعني لو أنتوا ما شاء الله عنكوا
+
+35
+00:02:55,950 --> 00:03:01,800
+اتخرجتوا و بتكونوا دخلوا مسابقة توظيفمش معقول
+
+36
+00:03:01,800 --> 00:03:04,600
+نجيبلكوا ورقة و جلم و أنتوا تدخلين امتحان شفه و
+
+37
+00:03:04,600 --> 00:03:08,320
+نقعد نقولكوا عيدوا و زيدوا نسألكوا سؤالين تلاتة
+
+38
+00:03:08,320 --> 00:03:12,300
+عامين جدا بنعرفكوا بتفهموا كيميا عضوية ولا لأ لو
+
+39
+00:03:12,300 --> 00:03:15,700
+أجينا قولنالكوا مثلا ايش التفاعل الأساسي على
+
+40
+00:03:15,700 --> 00:03:21,180
+الalkenes لازم أسمع addition و electrophilic
+
+41
+00:03:21,180 --> 00:03:26,140
+addition على الalkalitesلازم أسمع substitution و
+
+42
+00:03:26,140 --> 00:03:30,200
+nucleophilic على الـ aromatic compounds مثلًا
+
+43
+00:03:30,200 --> 00:03:36,320
+Electrophilic substitution على الألديهيدس
+
+44
+00:03:36,320 --> 00:03:41,640
+والكيتونز تفاعلنا addition على الأحماض ومشتقاتها
+
+45
+00:03:41,640 --> 00:03:46,240
+تفاعلنا substitution هذا هنشوفه بالأمثلةبس هذا حتى
+
+46
+00:03:46,240 --> 00:03:50,720
+يكون عندكم استيعاب ليش هدول المركبين يمثلوا بحد
+
+47
+00:03:50,720 --> 00:03:56,640
+ذاتهم عائلة وباقي المركبات هذه تمثل عائلة تانية
+
+48
+00:03:56,640 --> 00:04:00,740
+لأنه في اختلاف جوهري في التفاعل الأساسي لهدول
+
+49
+00:04:00,740 --> 00:04:03,480
+العائلتين واحد بتفعل بالإضافة والثاني بتفعل
+
+50
+00:04:03,480 --> 00:04:04,420
+بالإبدال
+
+51
+00:04:07,820 --> 00:04:11,840
+بالنسبة لبعض الخواص لـ aldehydes و الـ ketones
+
+52
+00:04:11,840 --> 00:04:17,300
+طبعا واضح ان الرابط السيطب الـ bond O نسبيا polar
+
+53
+00:04:17,300 --> 00:04:21,360
+بس مافيش فيه hydrogen bonding يعني لما أطلع انا
+
+54
+00:04:21,360 --> 00:04:24,700
+على ال oxygen و ال carbon ال oxygen is more
+
+55
+00:04:24,700 --> 00:04:29,800
+electronegative than carbon و عشان هيك هتلاحظوا
+
+56
+00:04:29,800 --> 00:04:36,040
+دائما ان في عندى طرف سالب عند ال oxygen و طرفموجب
+
+57
+00:04:36,040 --> 00:04:43,620
+عند الكربون هذا الطرف الموجب عند الكربون هو أساس
+
+58
+00:04:43,620 --> 00:04:48,710
+الكيميا تبع الكربوني ال compounds كلهايعني دائما
+
+59
+00:04:48,710 --> 00:04:52,230
+لما بدأ أفكر في carbonyl compound بدأ أفكر أنه
+
+60
+00:04:52,230 --> 00:04:57,170
+الرابطة مستقطبة فيها طرف سالب اللي هو ال oxygen
+
+61
+00:04:57,170 --> 00:05:02,110
+وطرف موجب اللي هو ال carbon الآن التفاعل الأساسي
+
+62
+00:05:02,110 --> 00:05:07,310
+هتلاحظوا مركز على هذا الكربون اللي موجود في ال
+
+63
+00:05:07,310 --> 00:05:13,990
+carbonyl compounds طالما هذا الطرف موجب معناه ذلك
+
+64
+00:05:13,990 --> 00:05:16,490
+شو اللي بنتوقع بده يهاجم عليه بعد شو اللي مصير
+
+65
+00:05:16,490 --> 00:05:21,010
+التفاعلات؟إيش يعني سالب؟ Enucleophile عشانك
+
+66
+00:05:21,010 --> 00:05:24,630
+هتلاقوا على ال الديهيدس والكيتونز Enucleophilic
+
+67
+00:05:24,630 --> 00:05:27,050
+addition و هتلاقوا على العائلة التانية
+
+68
+00:05:27,050 --> 00:05:30,850
+Enucleophilic substitution في كل الأحوال طالما هذا
+
+69
+00:05:30,850 --> 00:05:35,810
+موجب اللي بده يهاجم عليه لازم يكون سالب واضح؟
+
+70
+00:05:35,810 --> 00:05:40,150
+بالنسبة لل boiling points طبعا بتلاحظوا أن ال
+
+71
+00:05:40,150 --> 00:05:44,030
+الديهيدس والكيتونز مافيهم hydrogen bonding لأن شرط
+
+72
+00:05:44,030 --> 00:05:49,630
+ال hydrogen bonding أن يكون عندههيدروجين مرتبطة
+
+73
+00:05:49,630 --> 00:05:55,030
+باكسوجين او نيتروجين او فلور واحدة من التلات ذرات
+
+74
+00:05:55,030 --> 00:05:59,790
+الان هنا مافي اشي مرتبط بالاكسوجين ولذلك نقطة
+
+75
+00:05:59,790 --> 00:06:05,470
+غليانهم اقل من الكحولات واضح؟ يعني مثلا الاسيتون
+
+76
+00:06:05,470 --> 00:06:08,810
+اللى هو عبارة عن تلات ذرات كربون وذرة اكسوجين
+
+77
+00:06:08,810 --> 00:06:15,240
+بيغلي عند 56 لو بدى اقارنه بالبروبانولممكن بيغلي
+
+78
+00:06:15,240 --> 00:06:20,840
+بالتسعينات أو جري بالمية، واضح؟ فليش هدول ال
+
+79
+00:06:20,840 --> 00:06:26,180
+aldehydes و ال ketones لهم نقاط غليان أقل من ال
+
+80
+00:06:26,180 --> 00:06:31,080
+alcohols because they don't have hydrogen bonds
+
+81
+00:06:31,080 --> 00:06:37,460
+السليوبيلية بشكل عام ضعيفة جدا في الميه، يعني
+
+82
+00:06:37,460 --> 00:06:40,900
+مافيش غير اللي بنسميهم ال lower aldehydes and
+
+83
+00:06:40,900 --> 00:06:47,260
+ketones تعرف إيش يعني ال lower؟الـ Lower Aldehydes
+
+84
+00:06:47,260 --> 00:06:52,780
+and Ketones اللي هم فيهم عدد كربونات جليل يعني أول
+
+85
+00:06:52,780 --> 00:06:56,380
+Aldehydes و Ketones في السلسلة هدولة اللي بيدوبوا
+
+86
+00:06:56,380 --> 00:07:00,380
+في الميه يعني مثلا ال Acetaldehyde بيدوب في الميه
+
+87
+00:07:00,380 --> 00:07:04,620
+ال Formaldehyde بيدوب في الميه ال Acetone كأبسط
+
+88
+00:07:04,620 --> 00:07:07,560
+Ketone بيدوب في الميه بعد هيك ال R group بتصير
+
+89
+00:07:07,560 --> 00:07:11,200
+كبيرة المركبات مابيدوبوش في الميهيعني اللي بدنا
+
+90
+00:07:11,200 --> 00:07:15,700
+نقول مثلا three-hexanone ولا three-cyclopentanone
+
+91
+00:07:15,700 --> 00:07:19,780
+هذه الكيتونات إذا كبرت خلاص مابتدوب في الميه فبس
+
+92
+00:07:19,780 --> 00:07:23,320
+اللي هم ال low molecular weight species يعني
+
+93
+00:07:23,320 --> 00:07:27,140
+الأشياء اللي ال molecular weight تبعها صغير اللي
+
+94
+00:07:27,140 --> 00:07:31,380
+هم أوائل الألدهيات والكيتون فقط اللي بيدوبوا في
+
+95
+00:07:31,380 --> 00:07:38,500
+الميه بعد ذلك مافيش شيء ذوبانفي الميه لأنه مافيش
+
+96
+00:07:38,500 --> 00:07:44,140
+عنده hydrogen bonding كمان تساعد على الضوابان الان
+
+97
+00:07:44,140 --> 00:07:48,940
+بالنسبة لتسمية هذه المركبات بالنسبة لتسمية هذه
+
+98
+00:07:48,940 --> 00:07:55,060
+المركبات احنا في ال IUPAC Nomenclature اتفقنا ان
+
+99
+00:07:55,060 --> 00:08:02,520
+بناخد اسم ال الكان و بنزيد عليه نهايةيعني مثلا لو
+
+100
+00:08:02,520 --> 00:08:07,860
+فكرنا بذرتين carbon لو فكرنا بذرتين carbon الاصل
+
+101
+00:08:07,860 --> 00:08:12,360
+لما يكون عندى ذرتين carbon ايش المركب اثان اثان
+
+102
+00:08:12,360 --> 00:08:17,020
+okay الان لو صار المركب فيه double bond ايش بيصير
+
+103
+00:08:17,020 --> 00:08:22,340
+اثين اثين لو صار فيه triple bond اثان اثان لو صار
+
+104
+00:08:22,340 --> 00:08:28,890
+فيه OH اثانولواضح فالتغيير في الآخر طيب الأن لو
+
+105
+00:08:28,890 --> 00:08:33,270
+صار في الديهايد و لو صار في المركب بعد هيك كيتون
+
+106
+00:08:33,270 --> 00:08:40,250
+إذا صار في الديهايد بنضيف له النهاية ال فهذا بيصير
+
+107
+00:08:40,250 --> 00:08:46,770
+methanol يبدو للأسف ناقصة كتابة ال a هنا قبل ال L
+
+108
+00:08:49,330 --> 00:08:54,070
+ليش؟ لأنه كم كربونا عندي هنا؟ واحدة كربونا واحدة
+
+109
+00:08:54,070 --> 00:09:00,190
+يعني ميثين الآن لما بيصير الديهايد ميثانال كربونا
+
+110
+00:09:00,190 --> 00:09:08,830
+واحد كربونتين اتين ايثانال تلاتة بروبانال اربعة
+
+111
+00:09:08,830 --> 00:09:15,520
+بيوتانال فال الديهايد بشكل عام تاخد النهاية ALالـ
+
+112
+00:09:15,520 --> 00:09:20,540
+ANL واضح؟ طبعا هذا ما بيمنعش ان المراكبات الصغيرة
+
+113
+00:09:20,540 --> 00:09:25,020
+فيها أسماء شهرة و الناس كتير برات بتتعامل مع أسماء
+
+114
+00:09:25,020 --> 00:09:29,920
+شهرة بتاعتهم يعني الميثانال اسمه formaldehyde
+
+115
+00:09:29,920 --> 00:09:37,000
+الإيثانال هو الacetaldehyde البروبانال بيسموه مرات
+
+116
+00:09:37,000 --> 00:09:38,740
+البروبيونالديهيد
+
+117
+00:09:45,930 --> 00:09:49,590
+البيوتنال بيسموه butyraldehyde
+
+118
+00:09:51,670 --> 00:09:57,070
+و مع الممارسة هتحسوا ان الشغلة مش .. مش هتكون صعبة
+
+119
+00:09:57,070 --> 00:10:02,950
+كتير عليكم الان لو صار على المركب substituents
+
+120
+00:10:02,950 --> 00:10:08,610
+كتيرة انتوا هتلاقوا حالكم ملزمين تلقائيا انكوا
+
+121
+00:10:08,610 --> 00:10:13,230
+تستعملوا ال .. واضح؟
+
+122
+00:10:13,230 --> 00:10:20,330
+يعني لو بنسأل عن مركب وفيه substituentsتلقائيًا
+
+123
+00:10:20,330 --> 00:10:27,050
+تستعمل أي نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+124
+00:10:27,050 --> 00:10:27,770
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+125
+00:10:27,770 --> 00:10:28,010
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+126
+00:10:28,010 --> 00:10:30,450
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+127
+00:10:30,450 --> 00:10:32,690
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+128
+00:10:32,690 --> 00:10:39,530
+نومنكليتشر أيوبك نومنكليتشر أيوبك نومنكليتشر أيوبك
+
+129
+00:10:39,530 --> 00:10:45,770
+نومنكليتشر أيوبك نومنكليتشر أيوبك نشو بدكم تسموه
+
+130
+00:10:45,770 --> 00:10:50,290
+butyraldehyde؟ وقتها لازم تيجي تسمو هذا المركب
+
+131
+00:10:50,290 --> 00:10:57,180
+كمشتقةبيوتنال واضح هنا بتكون تتذكروا القواعد اللي
+
+132
+00:10:57,180 --> 00:11:02,420
+أعطيناكوا إياها حال التقاء أكثر من مجموعة وظيفية
+
+133
+00:11:02,420 --> 00:11:07,000
+من إله أولوية يعني هذا المركب مثلا في مجموعة ال
+
+134
+00:11:07,000 --> 00:11:12,220
+الديهايد وفي مجموعة ال alcohol ال الديهايد أولويته
+
+135
+00:11:12,220 --> 00:11:15,800
+أعلى من ال alcohol عشانك لما تترقب تقول واحد اتنين
+
+136
+00:11:15,800 --> 00:11:21,700
+تلاتةاربع one two three four اذا كام substitute
+
+137
+00:11:21,700 --> 00:11:28,200
+عندى هنا تلتان واضح لما بدى اسم هذا المركب تسمية
+
+138
+00:11:28,200 --> 00:11:34,600
+كاملة شو بدى يصير اسمه two chloro three hydroxy
+
+139
+00:11:34,600 --> 00:11:45,420
+butanate اه two chloro three hydroxy butanate الآن
+
+140
+00:11:45,420 --> 00:11:51,780
+السؤالبيلزم أن أقول one butanane لأن الالدهايد لا
+
+141
+00:11:51,780 --> 00:11:57,530
+تكون إلا طرفية على الموضوع واحدواضح؟ يعني دائما في
+
+142
+00:11:57,530 --> 00:12:00,710
+ال الديهايد بلزم .. أنا قلت هذا المركب الديهايد
+
+143
+00:12:00,710 --> 00:12:05,150
+إذا الـ C double bond O تبعته بتكون طرفية فإذا
+
+144
+00:12:05,150 --> 00:12:09,210
+المركب منسوب لل الديهايد مابلزمش أني أجي أحط one
+
+145
+00:12:09,210 --> 00:12:14,510
+butanol بعد شوية لما ناخد كيتون مثلا 6 كربونات و
+
+146
+00:12:14,510 --> 00:12:17,190
+فيه C double bond O ممكن تكون والله على موقع اتنين
+
+147
+00:12:17,300 --> 00:12:21,700
+ممكن تكون على موقع تلاتة بيصير ملزم ان احدد وين
+
+148
+00:12:21,700 --> 00:12:25,620
+موقع الـ C double bond O في الكيتون لان لو عندي
+
+149
+00:12:25,620 --> 00:12:29,220
+سلسلة طويلة في ال الديهايد دائما بتكون على نمرة
+
+150
+00:12:29,220 --> 00:12:32,420
+واحدة ده ميزة ال الديهايد ان ال C double bond O
+
+151
+00:12:32,420 --> 00:12:36,440
+على نمرة واحدة بس لو صار عندك كيتون بعشر ذرات
+
+152
+00:12:36,440 --> 00:12:39,700
+كربون هل ال C double bond O على موقع اتنين تلاتة
+
+153
+00:12:39,700 --> 00:12:46,250
+اربعة خمسة احنا مش عارفين ولذلكيجب أن نضع أرقام في
+
+154
+00:12:46,250 --> 00:12:50,070
+حالة الـ ketone إذا كان لدينا لبس في موقع المجموعة
+
+155
+00:12:50,070 --> 00:12:54,110
+بس في ال الديهايد عمره لا أحد يحط وان بيوتنال خلاص
+
+156
+00:12:54,110 --> 00:12:57,910
+بيوتنال هي لا تكون إلا على موقع واحد واضح هذه
+
+157
+00:12:57,910 --> 00:13:02,470
+الفكرة؟ سنشوف أمثل إضافية الآن جزء من الاروماتيك
+
+158
+00:13:02,470 --> 00:13:09,950
+كومباونز مر علينا هذا المركب ال pins الديهايدمر
+
+159
+00:13:09,950 --> 00:13:12,610
+علينا و بتعرفوا لو كان في substitution تاني
+
+160
+00:13:12,610 --> 00:13:17,910
+علمناكوا كيف نسميه هذا المركب مثلا هي في aldehyde
+
+161
+00:13:17,910 --> 00:13:23,610
+و OH لمن أولويته في التسمية لل aldehyde اذا انا
+
+162
+00:13:23,610 --> 00:13:29,390
+هرقم منها و همر أسرع ما يمكن على ال OH فبدي يكون
+
+163
+00:13:29,390 --> 00:13:33,990
+المركب 2-hydroxybenzaldehyde
+
+164
+00:13:33,990 --> 00:13:39,350
+يعني لو كتبتوا 2-hydroxybenzaldehyde it's okayالان
+
+165
+00:13:39,350 --> 00:13:43,650
+مرات بيقولوله بنزين carbaldehyde لكن الأشهر بنز
+
+166
+00:13:43,650 --> 00:13:46,830
+aldehyde زي ماذا بيسميه بنز aldehyde هذا two
+
+167
+00:13:46,830 --> 00:13:55,230
+hydroxy benz aldehyde هذا
+
+168
+00:13:55,230 --> 00:14:00,290
+المرتب حاطيله مش عشان تحفظوا شكله بس على أساس
+
+169
+00:14:00,290 --> 00:14:06,190
+تشوفوا ان انا عندى aldehyde و alcohol و مثلو بنزين
+
+170
+00:14:06,190 --> 00:14:12,010
+تقولوا إيش الكيميا هذه في النهاية هذا المركب هو ال
+
+171
+00:14:12,010 --> 00:14:15,850
+vanilla اللي بيعملوا فيها ال cake ال vanilla اللي
+
+172
+00:14:15,850 --> 00:14:19,690
+بيعملوا فيها ال cake الأن لو مجموعة ال aldehyde ..
+
+173
+00:14:19,690 --> 00:14:23,670
+لو مجموعة ال aldehyde إجت على حلقة و بدي أسميها
+
+174
+00:14:23,670 --> 00:14:30,800
+كمجموعة يعني هذه كلها Cyclopentaneمظبوط ولا لأ؟ لو
+
+175
+00:14:30,800 --> 00:14:33,960
+كان ديهايد و بعد شوية لما يجيني أسد بنقول
+
+176
+00:14:33,960 --> 00:14:37,840
+Cyclopentane و بالصيغة بالبندق OH لما بتيجي كلها
+
+177
+00:14:37,840 --> 00:14:42,020
+كمجموعة ملتصقة بالحلقات خمسية سدسية واطفات بنقول
+
+178
+00:14:42,020 --> 00:14:47,240
+عنها carbaldehyde يعني هذه الأن أصبحت كأنها مجموعة
+
+179
+00:14:47,240 --> 00:14:54,140
+ملتصقة بcyclopentane فهذا المركب اللي همنن نسميه
+
+180
+00:14:54,140 --> 00:15:01,120
+بنقول Cyclopentaneوهذه المجموعة
+
+181
+00:15:01,120 --> 00:15:11,060
+كرب أنديهيد بيصير كله Cyclopentane Carbohydrate من
+
+182
+00:15:11,060 --> 00:15:19,680
+وين ال Clor؟ لو حطيت هنا Clor، هاي واحد، اتنين،
+
+183
+00:15:19,680 --> 00:15:25,880
+تلاتة الأولوية لل Carbohydrateثلاثة كلورو
+
+184
+00:15:25,880 --> 00:15:32,440
+سايكلوبنتين كربالديهيد وين ال double bond؟ بتصير
+
+185
+00:15:32,440 --> 00:15:40,800
+سايكلوبنتين و بنحدد موقع ال double bond ببدأ
+
+186
+00:15:40,800 --> 00:15:43,920
+من عند ال aldehyde ببدأ من عند ال aldehyde one
+
+187
+00:15:43,920 --> 00:15:46,860
+واضح؟ ببدأ ال one من عند ال aldehyde يعني لو
+
+188
+00:15:46,860 --> 00:15:50,460
+double bond هنا بقول one, two, three و بمشي بهذا
+
+189
+00:15:50,460 --> 00:15:55,500
+الشكل واضح؟ بنبدأ من عند ال aldehydeبيصير
+
+190
+00:15:55,500 --> 00:16:01,820
+Cyclopentene Carb Antihydrate و بنحدد موقع double
+
+191
+00:16:01,820 --> 00:16:07,220
+bond بنحدد موقع double bond الان
+
+192
+00:16:07,220 --> 00:16:14,940
+بالنسبة لكيتون افضل كيتون من تلت ذرات كربون اللي
+
+193
+00:16:14,940 --> 00:16:23,120
+هو Evropanol بنحط النهاية ايش للكيتون onكل مراكبات
+
+194
+00:16:23,120 --> 00:16:26,200
+الكيتون لما بتعبر عنها بال أيو بكنوميكليتشار هذا
+
+195
+00:16:26,200 --> 00:16:30,820
+السطر اللي فوق في كل المراكبات هو تعبير عن ال أيو
+
+196
+00:16:30,820 --> 00:16:35,640
+بكنوميكليتشار بنحط نهاية on طبعا هذا البروبانون
+
+197
+00:16:35,640 --> 00:16:39,220
+اسمه أسيتون ممكن بعض يقول ليش ما سمناه two
+
+198
+00:16:39,220 --> 00:16:43,000
+-probanon على أساس ان ال on ع موقع اتنين هو طالما
+
+199
+00:16:43,000 --> 00:16:48,420
+كيتون طالما كيتون مافيش إله الاحتمال واحد دائما
+
+200
+00:16:48,420 --> 00:16:51,260
+الأرقام وانتش احنا بنحطها
+
+201
+00:16:53,240 --> 00:16:59,500
+إذا صار عنده أكثر من احتمال دائما الأرقام بتلحط
+
+202
+00:16:59,500 --> 00:17:02,580
+إذا في عنده أكثر من احتمال عشان هي اللي بيكون
+
+203
+00:17:02,580 --> 00:17:06,300
+لحاله ومافيش احتمالات كتيرة مابياخدش أرقام يعني
+
+204
+00:17:06,300 --> 00:17:12,420
+أعطيكوا مثال في القردن مثلا الملك عبدالله بيكون
+
+205
+00:17:12,420 --> 00:17:19,710
+أبوه ولا سيده للملك حسين؟ لأ طبعا سيدهلأ الملك عبد
+
+206
+00:17:19,710 --> 00:17:23,650
+الله سيده للملك إحسين، الملك الحسين ابنه طلال، بس
+
+207
+00:17:23,650 --> 00:17:28,810
+أبوه طلال ماخلهوش ياخد الحكم غير حوالي كام من شهر
+
+208
+00:17:28,810 --> 00:17:32,510
+و بعدين شلوه و حطوا للملك إحسين بداله، كان اسمه بس
+
+209
+00:17:32,510 --> 00:17:37,290
+الملك عبد الله، ليش؟ لأنه مافيش منافس تاني، الآن
+
+210
+00:17:37,290 --> 00:17:42,130
+لما إجه حفيدهبعد ذلك سنقول عبدالله الثاني وقت انا
+
+211
+00:17:42,130 --> 00:17:46,890
+بدأت استعمل الأرقام إذا صار في عندى احتمال اللبس
+
+212
+00:17:46,890 --> 00:17:50,110
+واضح؟ الان هنا مافيش غير موقع واحد تيجي فيه الـ C
+
+213
+00:17:50,110 --> 00:17:53,770
+double bond وعشان يبين كيتون ولذلك مش كتير مهم
+
+214
+00:17:53,770 --> 00:17:59,610
+اكتب to Probanon لكن مثلا هذا المركب اللى هنا لو
+
+215
+00:17:59,610 --> 00:18:05,750
+بتطلعى 1,2,3,4,5 كم احتمال ممكن يكون فيه كيتون في
+
+216
+00:18:05,750 --> 00:18:11,970
+هذا المركب؟ لابس احتمالين، لاحظوا الـ c double
+
+217
+00:18:11,970 --> 00:18:17,330
+bond إذا إجت على أول موقع فمركبه الدماغ، إذا إجت
+
+218
+00:18:17,330 --> 00:18:23,870
+على الموقع التاني two pentanol، إذا إجت على الموقع
+
+219
+00:18:23,870 --> 00:18:28,760
+الثالث3 pentanone إذا أتيت عن موقع هذا اللي هنا
+
+220
+00:18:28,760 --> 00:18:32,980
+بتصير 2 pentanone من الجهة التانية لأنه دائما لازم
+
+221
+00:18:32,980 --> 00:18:36,960
+ناخد أقل ترقيم مابتتصلش أربعة pentanone لأنه لو
+
+222
+00:18:36,960 --> 00:18:40,680
+عديت واحدة منها واحد اتنين بترجع يشتوق pentanone
+
+223
+00:18:40,680 --> 00:18:46,120
+في هذه الحالة أنا ملزم أن أحط أرقام لأن في عندي
+
+224
+00:18:46,120 --> 00:18:50,560
+خوف في هذه الحالة مثلا في الأربع ذرات كربون هل أنا
+
+225
+00:18:50,560 --> 00:18:57,090
+كتير ملزم أن أحط أرقاملما أقول butanol، أساسا
+
+226
+00:18:57,090 --> 00:18:59,510
+مافيش شيء، لو هنا اتنين وهنا اتنين، يعني هذا
+
+227
+00:18:59,510 --> 00:19:04,550
+محطوطة في النهاية زيادة، واضح؟ احنا مش كتير بنحاسب
+
+228
+00:19:04,550 --> 00:19:08,570
+لما طالبة تحطها بزيادة، لكن الخلاصة أن الشيء
+
+229
+00:19:08,570 --> 00:19:14,460
+الواضح، اللي مافيش فيه منافسة، يمكن أن يُتركالان
+
+230
+00:19:14,460 --> 00:19:18,660
+مرات هذه الـ Ketones بيسموها common names كيف
+
+231
+00:19:18,660 --> 00:19:22,500
+بيسموها common names؟ بيجوا جنب الـ CWO و بياخدوا
+
+232
+00:19:22,500 --> 00:19:26,220
+المجموعات اللي محوطين، هذه مجموعة و هذه مجموعة هذه
+
+233
+00:19:26,220 --> 00:19:28,840
+المجموعة اللي هنا على اليمين أو على الشمال، شو
+
+234
+00:19:28,840 --> 00:19:35,520
+اسمها؟ carbon-10-ethyl، هذه مثل، فالمراكب بنسميه
+
+235
+00:19:35,520 --> 00:19:41,990
+Ethyl Methyl Ketoneواضح اثل مثل كيتون لو هذا بدنا
+
+236
+00:19:41,990 --> 00:19:47,970
+نتطلع مثلا هذه المجموعة اثل وهذه المجموعة اثل فهذا
+
+237
+00:19:47,970 --> 00:19:53,510
+بيسموه داي اثل كيتون داي اثل كيتون هذا نوع من ال
+
+238
+00:19:53,510 --> 00:19:56,750
+common nomenclature نوع من ال common nomenclature
+
+239
+00:19:56,750 --> 00:19:58,970
+اللي هي التسمية الشعبية
+
+240
+00:20:01,360 --> 00:20:08,020
+الأساس في تسمية ال الديهيدز حرفين والأساس في تسمية
+
+241
+00:20:08,020 --> 00:20:13,960
+ال ketones تلت حروف ال الديهيدز لما بنسميه بنضيف
+
+242
+00:20:13,960 --> 00:20:17,840
+نهاية A لل ketones on
+
+243
+00:20:20,550 --> 00:20:25,690
+on واضح؟ إذا كل مركب حتشوفه نهايته ال إذا هو
+
+244
+00:20:25,690 --> 00:20:31,990
+الديهايد والنهايته on إذا هو كيتون هنا مثلا هذا
+
+245
+00:20:31,990 --> 00:20:39,210
+المركب Cyclohexane بيصير Cyclohexanone بيلزم نيجي
+
+246
+00:20:39,210 --> 00:20:45,630
+نقول one Cyclohexanone؟ مابيلزم لأن كل المواقع في
+
+247
+00:20:45,630 --> 00:20:51,560
+Cyclohexane تعتبر مواقع متساويةهذا الـ Ketone
+
+248
+00:20:51,560 --> 00:20:56,200
+أخدتوله اسم انتوا لما تكون مجموعة الاسيتا على
+
+249
+00:20:56,200 --> 00:21:02,520
+البنزين سمناه اسيتوفينون وممكن نسميه برضه على أساس
+
+250
+00:21:02,520 --> 00:21:06,040
+أن هذا كيتون، هاي مجموعة أو هاي مجموعةماذا يسمى
+
+251
+00:21:06,040 --> 00:21:12,420
+هذه المجموعة؟ فنل فبصير مثل فنل كيتون أو لأن كل
+
+252
+00:21:12,420 --> 00:21:17,540
+هذه المجموعة أسيتل بيصير أسيتوفيلون أخدناها في
+
+253
+00:21:17,540 --> 00:21:22,920
+الاروماتيك كومباونز أسيتوفيلون المركب هذا الداي
+
+254
+00:21:22,920 --> 00:21:24,060
+فنل كيتون
+
+255
+00:21:28,880 --> 00:21:33,840
+Diphenylketone برضه بياخد اسم شهرة بنزوفينون هو
+
+256
+00:21:33,840 --> 00:21:37,200
+يعامل ك أيوبك حتى بنزوفينون خلاص يعني بيصيروا
+
+257
+00:21:37,200 --> 00:21:43,160
+عارفينه إيش اسمه بنزوفينون إذا بنزوفينون
+
+258
+00:21:43,160 --> 00:21:47,180
+أسيتوفينون كل المركبات هذه عبارة عن يعني خليني
+
+259
+00:21:47,180 --> 00:21:53,120
+أقول simple compounds مافيش فيها substitute
+
+260
+00:21:55,560 --> 00:21:58,680
+يعني تغلب في التسميه مافيش فيها substituency تغلب
+
+261
+00:21:58,680 --> 00:22:04,700
+في التسميه لكن احنا بالتأكيد بإمكاننا الآن نعطي
+
+262
+00:22:04,700 --> 00:22:08,920
+مركبات أعقد بتحتوي على أكثر من مجموعة وظيفية
+
+263
+00:22:08,920 --> 00:22:12,680
+ونقولكوا كيف بنسميها ومن أمثال هذه المركبات احنا
+
+264
+00:22:12,680 --> 00:22:16,320
+لو كنا بدنا نسأل في الامتحان يعني هذه كلها تعتبر
+
+265
+00:22:16,320 --> 00:22:21,660
+مقدمة الخلاصة عشان نذكركم قولنا النهاية قال
+
+266
+00:22:26,730 --> 00:22:30,930
+الأولويات إذا التقت في الجزء أكتر من مجموعة
+
+267
+00:22:30,930 --> 00:22:36,970
+الألكيين أقل من الألكيين أقل من الالكول أقل من
+
+268
+00:22:36,970 --> 00:22:41,280
+الكيتونأقل من ال الديهايد، أقل من الاسد، أقل من ال
+
+269
+00:22:41,280 --> 00:22:46,760
+إيستر يعني الجزء لو التقف فيه كيتون مع الديهايد
+
+270
+00:22:46,760 --> 00:22:51,020
+الأولوية لمن؟ لل الديهايد، بداية الترقيم من أين؟
+
+271
+00:22:51,020 --> 00:22:59,300
+نهاية الإسم ال مش on، لما المركب يكون في ال و on،
+
+272
+00:22:59,300 --> 00:23:07,070
+نهايته ال ال و all القال يعني الديهايد و all
+
+273
+00:23:07,070 --> 00:23:12,230
+الكهول قال و all يعني زي هذا المركب لو حطيناها
+
+274
+00:23:12,230 --> 00:23:16,230
+نقاش طبعا لاحظوا أكيد كلكم مش لازم تقلطوا على
+
+275
+00:23:16,230 --> 00:23:18,930
+الغلطة لما هذا أنا أكون سايبها مش كاتب فيها إشي
+
+276
+00:23:18,930 --> 00:23:24,630
+إيش معناها CH3 في ناس كتير للأسف بيقلطوا يعني في
+
+277
+00:23:24,630 --> 00:23:28,710
+الامتحان اللي عملوا بصلحوا عندكم مركب بنتين يمكن
+
+278
+00:23:28,710 --> 00:23:32,030
+تلت بنات كاتبين بنتين رغم إن كلكم بنات كلكم
+
+279
+00:23:32,030 --> 00:23:37,780
+عاملينه بيوتينطب مبين فيه خمس كربونات واضح يعني
+
+280
+00:23:37,780 --> 00:23:41,880
+هذا لما بتعده هذي كربونا طالما انا اتركها مش كاتب
+
+281
+00:23:41,880 --> 00:23:45,860
+جنبها H بتظهر كربونا لكن في مثل هذه الحالة بتصير
+
+282
+00:23:45,860 --> 00:23:51,880
+ايش الان لو بدنا نسمي هذا المركب ايش اللي موجود
+
+283
+00:23:51,880 --> 00:23:57,300
+عندى هنا الديهايد و كلوروميثيل بيظهر للاصل
+
+284
+00:23:57,300 --> 00:24:04,450
+الديهايد واحد اتنين تلاتة اربع اذا هذابيوتانال
+
+285
+00:24:04,450 --> 00:24:05,770
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+286
+00:24:05,770 --> 00:24:09,670
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+287
+00:24:09,670 --> 00:24:14,690
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+288
+00:24:14,690 --> 00:24:15,130
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+289
+00:24:15,130 --> 00:24:15,170
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+290
+00:24:15,170 --> 00:24:15,190
+بيوتانال بيوتانال بيوتانال بيوتانال بيوتانال
+
+291
+00:24:15,190 --> 00:24:22,210
+بيوتانال بيوتانال بيوتانال بيوتان
+
+292
+00:24:24,200 --> 00:24:29,380
+طبعاً بدنا نشوف أقل ترقيم يعني إذا قدنا 1,2,3,4,1
+
+293
+00:24:29,380 --> 00:24:34,020
+,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2
+
+294
+00:24:34,020 --> 00:24:35,460
+,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3
+
+295
+00:24:35,460 --> 00:24:40,120
+,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,1,2,3,4,لما كان
+
+296
+00:24:40,120 --> 00:24:45,440
+عندى هنا ال ماحطتش رقم هي دائما و أبدا واحد لكن
+
+297
+00:24:45,440 --> 00:24:51,200
+لما كان عندى on حددت ال on ايش هي ال on وين موقعها
+
+298
+00:24:51,200 --> 00:24:56,340
+جاى على موقع تلاتة وعلى اتنين و أربعة ايش عندكم
+
+299
+00:24:56,340 --> 00:25:01,320
+دايمثل اذا هذا المركب two four dimethyl three
+
+300
+00:25:01,320 --> 00:25:07,840
+hexanol واضح الان هذا المركب ايش اللى بيلتقى فيه
+
+301
+00:25:08,300 --> 00:25:13,780
+acid و .. وين ال acid احنا أخدنا ال acid جيبنا
+
+302
+00:25:13,780 --> 00:25:20,120
+سيرة ال acid ال acid لما يكون من نفس الكربونة طالع
+
+303
+00:25:20,120 --> 00:25:25,820
+استيظة بال bond O و ال OH و هذا موضوع chapter 10
+
+304
+00:25:25,820 --> 00:25:30,180
+احنا ولا جيبنا سيرته استيظة بال bond O و ال OH لما
+
+305
+00:25:30,180 --> 00:25:34,800
+يكونوا طالعين من نفس الكربونة بنحكي عن acid الان
+
+306
+00:25:34,800 --> 00:25:39,750
+هذولا من الكربوناتمختلفة هذا مش asset إطلاقا هذا
+
+307
+00:25:39,750 --> 00:25:46,770
+مركب فيه own و own الأولوية له ال own إذا نهاية
+
+308
+00:25:46,770 --> 00:25:51,150
+المركب own والترقيم بيمور أسرع ما يمكن على ال seed
+
+309
+00:25:51,150 --> 00:25:54,350
+of ال bond أو ال ketone كتابة ال ketone one two
+
+310
+00:25:54,350 --> 00:26:00,890
+three four five إذا هذا عبارة عن two بالتنون ال
+
+311
+00:26:00,890 --> 00:26:08,720
+two بتحدد موقع ال ownموقع الكيتون وإيش جاي فيه على
+
+312
+00:26:08,720 --> 00:26:17,760
+موقع أربعة for hydroxy-2-bentanone for hydroxy-2
+
+313
+00:26:17,760 --> 00:26:22,620
+-bentanone لان التقاء الكحول مع الكيتون الأولوية
+
+314
+00:26:22,620 --> 00:26:29,360
+فيه بالترقيم التسمية للكيتون المثال اللي بعيد
+
+315
+00:26:29,360 --> 00:26:37,230
+عبارة عن التقاءالدهايدو كيتون خليني بس أنوح هنا
+
+316
+00:26:37,230 --> 00:26:46,170
+لنقطة ال OH ال OH لما تكون مجموع مركب يعني المركب
+
+317
+00:26:46,170 --> 00:26:50,870
+كله منسوب إليها هي شو بيصير؟ بيقول عنها هيدروكسي
+
+318
+00:26:50,870 --> 00:26:57,520
+إذا أناالـ OH بتعامل معها بمسمى Hydroxy إذا أصبحت
+
+319
+00:26:57,520 --> 00:27:02,940
+مجموعة لكن إذا المركب منسوب إلها بيكون كل المركب
+
+320
+00:27:02,940 --> 00:27:13,140
+نهايته O الـ A هيجيبنا الكلام نفسه مع الـ C double
+
+321
+00:27:13,140 --> 00:27:19,820
+bond O الـ C double bond O لو كانت الديهيد بتكون
+
+322
+00:27:21,010 --> 00:27:27,510
+أقل، لو كانت كيتون All، الآن، لو في أعلى منها،
+
+323
+00:27:27,510 --> 00:27:31,790
+هترجع مجموعة،
+
+324
+00:27:31,790 --> 00:27:35,970
+واضح؟ يعني لو إنه كان مع acid، وعنكم C double bond
+
+325
+00:27:35,970 --> 00:27:40,610
+O كيتونية و C double bond O كمان، تبعت aldehyde،
+
+326
+00:27:40,610 --> 00:27:45,970
+بس أنا اللي عنديا acid، هيرجعوا لاسمهم الأصلي، شو
+
+327
+00:27:45,970 --> 00:27:54,410
+اسمهم الأصلي؟ Oxoأكزو من الـ Oxygen واضح؟ بناء على
+
+328
+00:27:54,410 --> 00:27:57,790
+ذلك لما طلع هذا المُركّب هاي الالديهيد وهي الكيتون
+
+329
+00:27:57,790 --> 00:28:02,970
+الالديهيد كان جنبه H مُركّبي بأنسبه لإيش؟
+
+330
+00:28:02,970 --> 00:28:07,850
+للالديهيد الالديهيد أقوى من الكيتون مُركّبي بأنسبه
+
+331
+00:28:07,850 --> 00:28:14,190
+للالديهيد إذا نهاية مُركّبي ال .. واضح؟ إذا هنا
+
+332
+00:28:14,190 --> 00:28:19,770
+بعد واحد اتنين تلاتة أربعة هذا المُركّب بيوتهالان
+
+333
+00:28:19,770 --> 00:28:23,830
+هذا
+
+334
+00:28:23,830 --> 00:28:29,370
+الـ butanol على موقع تلاتة بيحمل الـ C double bond
+
+335
+00:28:29,370 --> 00:28:34,330
+O هنا بطلت كيتون لأنه خلاص هو المُركّب بيُنسب
+
+336
+00:28:34,330 --> 00:28:38,550
+لمجموعة وظيفية واحدة نصف ال الديهايد خلصت إذن هنا
+
+337
+00:28:38,550 --> 00:28:42,630
+ال C double bond O رجعت لأصل اسمها ايش أصل اسمها
+
+338
+00:28:42,630 --> 00:28:50,490
+اقزو اقزوواضح؟ أصلها أوكزو فبصير هذا three
+
+339
+00:28:50,490 --> 00:28:58,070
+-oxobutanol واضح؟
+
+340
+00:28:58,070 --> 00:29:01,170
+كذلك الحال لو بعد شوية مثلا باخد acid ومعه
+
+341
+00:29:01,170 --> 00:29:05,450
+aldehyde مركب يحب يقول عنه acid ال aldehyde شو
+
+342
+00:29:05,450 --> 00:29:12,200
+هتصير اسمها؟ أوكزو، هنبطل نقول عنها الفإذا أصبحت
+
+343
+00:29:12,200 --> 00:29:16,200
+الـ C double bond O عبارة عن مجموعة عادية المركب
+
+344
+00:29:16,200 --> 00:29:21,180
+مش منسوب إلها بنعبر عنها F-oxo و الـ OH إذا كان
+
+345
+00:29:21,180 --> 00:29:27,460
+المركب مش منسوب إلها بنسميها Hydroxy واضح؟ المركب
+
+346
+00:29:27,460 --> 00:29:32,040
+اللي بعد مين تحكيلنا عنه؟ تتأملوا فيه هيك شوية إيش
+
+347
+00:29:32,040 --> 00:29:38,220
+اللي موجود في هذا آخر مركب؟ كيتون و إيش؟ مؤلقين
+
+348
+00:29:40,460 --> 00:29:44,360
+كيتون و ألكين الكيتون أقوى من الألكين إذا هو
+
+349
+00:29:44,360 --> 00:29:51,360
+كعائلة آخر إشي بده يظهر في اسمه الـ on والترقيم
+
+350
+00:29:51,360 --> 00:29:57,940
+بده يمر أسرع ما يمكن برضه على ال on عن كيتون لما
+
+351
+00:29:57,940 --> 00:30:04,060
+نيجي نقول one two three four five six هذا عبارة عن
+
+352
+00:30:04,060 --> 00:30:13,080
+هكسانون الآن هذا الهكسانون واحد منه صارفبصير هي
+
+353
+00:30:13,080 --> 00:30:17,920
+موقعها بالرقم و ال double point كان ممكن تكون هان
+
+354
+00:30:17,920 --> 00:30:22,740
+او هان او هان اذا يجب تحديد نقطة بدايتها كمان
+
+355
+00:30:22,740 --> 00:30:27,740
+بالرقم ايش نقطة بدايتها هاد ال double point تلاتة
+
+356
+00:30:27,740 --> 00:30:34,560
+اذا هنا يجب نقطة او نقطة نقطة نقطة نقطة نقطة نقطة
+
+357
+00:30:34,560 --> 00:30:40,600
+نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة
+
+358
+00:30:40,600 --> 00:30:42,050
+نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطة نقطةثالث
+
+359
+00:30:42,050 --> 00:30:47,790
+ثالث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث ثلاث
+
+360
+00:30:47,790 --> 00:30:54,010
+ثلاث ثلاث ثلاث تلات تلات تلات تلات تلات تلات تلات
+
+361
+00:30:54,010 --> 00:30:56,550
+تلات تلات تلات تلات تلات تلات تلات تلات تلات تلات
+
+362
+00:30:56,550 --> 00:30:56,830
+تلات تلات تلات تلات تلات تلات تلات تلات تلات تلات
+
+363
+00:30:56,830 --> 00:31:04,690
+تلات تلات تلات تلات تلات تلات توانقولكوا ارسمولنا
+
+364
+00:31:04,690 --> 00:31:09,970
+هذا المُركّب، بتحطوا 6 carbonate، بعدين هتيجوا على
+
+365
+00:31:09,970 --> 00:31:21,090
+موقع 2، تحطوا on، وعلى موقع 3، تحطوا double
+
+366
+00:31:21,090 --> 00:31:23,490
+bond، واضح؟
+
+367
+00:31:36,430 --> 00:31:41,810
+في هذا الـ slide عندكم مجموعة برضه إضافية من
+
+368
+00:31:41,810 --> 00:31:47,250
+الأمثلة خلّينا نقول أمثلة إثرائية حتى يعني تتقنوا
+
+369
+00:31:47,250 --> 00:31:52,370
+موضوع التسمية بشكل كبير لأنه أول ما بتكونوا
+
+370
+00:31:52,370 --> 00:31:55,450
+تتعاملوا مع عائلة إذا بتعرفوش يتسموها كيف بتكونوا
+
+371
+00:31:55,450 --> 00:32:00,130
+تتعاملوا معها؟ مظبوط ولا لا؟ لازم نكون نتقن موضوع
+
+372
+00:32:00,130 --> 00:32:05,710
+التسمية إذا مرّينا عليهم بسرعة المركب الأول
+
+373
+00:32:06,820 --> 00:32:12,380
+بيوتانال مر علينا او butyraldehyd مظبوط ولا لا
+
+374
+00:32:12,380 --> 00:32:18,240
+المركب الثاني لاحظوا فيه الديهيدر كو أتش تري
+
+375
+00:32:18,240 --> 00:32:27,360
+هيدروكسي بيوتانال الان في تسمية قديمة مرات بتمر
+
+376
+00:32:27,360 --> 00:32:34,780
+معاكم من باب التاريخ لأن المشكلة انه مرات لازم
+
+377
+00:32:34,780 --> 00:32:42,690
+تعرفوايعني الأسماء زي ما كانت يعني تذكر ملزمين
+
+378
+00:32:42,690 --> 00:32:46,990
+أنتوا تعرفوها، يعني مثلا لما ييجوا يقولوا شيخ
+
+379
+00:32:46,990 --> 00:32:49,930
+الإسلام، يعني أنتوا بتقراوا كان اتلاقوا واحد قال
+
+380
+00:32:49,930 --> 00:32:54,630
+وقال شيخ الإسلام في هذه المسألةإذا كنتوا ما
+
+381
+00:32:54,630 --> 00:32:59,910
+بتعرفوش إنه ابن تيمية هتتغلبوا، مظبوط ولا لأ؟ إذا
+
+382
+00:32:59,910 --> 00:33:04,890
+ما بتعرفوش إنه ابن تيمية هتتغلبوا أو واحد شاعر
+
+383
+00:33:04,890 --> 00:33:10,390
+شعبي مثلا كتير وفي الشعر الشعبي تبعه وقال الختيار
+
+384
+00:33:10,390 --> 00:33:15,790
+وقال .. شو يعني الختيار؟ إذا ما بتعرفوش هذه
+
+385
+00:33:15,790 --> 00:33:20,470
+الأشياء مش هتمشي الدنيا معكم إذا لو شغلة سمت بميت
+
+386
+00:33:20,470 --> 00:33:26,390
+تسميةانتم مضطرين تعرفوا الميتة اسمها يعني لو واحد
+
+387
+00:33:26,390 --> 00:33:31,370
+ايجيه جالي الختيار، شو بتقوله؟ وده جالي الياسر وده
+
+388
+00:33:31,370 --> 00:33:36,320
+جالي الكاسرمش بيقولوا الياسر، الكاسر، أبو عمار،
+
+389
+00:33:36,320 --> 00:33:41,200
+الختيار، عرفات كل هذه الأسماء المفروض تكون عندكم
+
+390
+00:33:41,200 --> 00:33:45,080
+في ذهنكم أن هي تعبير عن نفس الشخص الآن قولوا ليش
+
+391
+00:33:45,080 --> 00:33:50,100
+بتسمى الأشي بأكثر من اسم هذا حال الدنيا يعني هذا
+
+392
+00:33:50,100 --> 00:33:54,060
+نوع من خلينا أقول التاريخ بس المفروض الواحد يعرفه
+
+393
+00:33:54,060 --> 00:33:59,560
+الآن زمان كانوا يسموا .. يحددوا مواقع المجموعات
+
+394
+00:33:59,560 --> 00:34:05,030
+الإضافية مش بأرقاممش بأرقام يعني هنا أنا لما بتعمل
+
+395
+00:34:05,030 --> 00:34:08,490
+نظام الترقيم ولا أسهل منه في ال IOPAC هذا الكلام
+
+396
+00:34:08,490 --> 00:34:12,570
+صحيح هاي واحد اتنين تلاتة أربعة و ال OH هذه اللي
+
+397
+00:34:12,570 --> 00:34:16,690
+عاملها لمشكلة وين جاية؟ ع موقع تلاتة قولت three
+
+398
+00:34:16,690 --> 00:34:21,370
+hydroxybutanol في نظام تاني كان يستعمل كان يقولوا
+
+399
+00:34:21,370 --> 00:34:25,990
+سيبوا المجموعة الأصلية اللي هيالـ C double bond O
+
+400
+00:34:25,990 --> 00:34:29,770
+سيبوا المجموعة الأصلية الـ C double bond O و ابدوا
+
+401
+00:34:29,770 --> 00:34:34,330
+اعطوا حروف من بعدها لاتينية Alpha, Beta, Gamma,
+
+402
+00:34:34,390 --> 00:34:38,450
+Delta واضح بعد الـ C double bond O الان اذا
+
+403
+00:34:38,450 --> 00:34:42,270
+اعطيتها انا Alpha وانا Beta وين جاية الـ OH على
+
+404
+00:34:42,270 --> 00:34:47,270
+موقع Beta فكانوا يقولوا Beta Hydroxybutyraldehyde
+
+405
+00:34:49,380 --> 00:34:52,800
+common name هذا common name الايوبك بيظله three
+
+406
+00:34:52,800 --> 00:34:56,900
+-hydroxybutanol لكن انتوا لو قرأته beta
+
+407
+00:34:56,900 --> 00:35:01,300
+-hydroxybutyraldehyde بتكون تسيبوا مجموعة الـ C
+
+408
+00:35:01,300 --> 00:35:05,960
+double bond O و تبدأوا تحطوا من بعدها Alpha Beta
+
+409
+00:35:05,960 --> 00:35:11,720
+Delta Gamma بصريش كل الكلام Alpha Beta Gamma Delta
+
+410
+00:35:11,720 --> 00:35:15,540
+Gamma لو اجت هنا نفس الاشي لو اجت هنا واضح
+
+411
+00:35:19,360 --> 00:35:26,940
+هذا المركب ما شاء الله عنه صدقوني
+
+412
+00:35:26,940 --> 00:35:31,860
+مش صعب يعني لو جيبناه في الامتحان و قولنا لوحده
+
+413
+00:35:31,860 --> 00:35:36,180
+فيكوا تحلله ولا إشي تقول هذه المجموعة إيش اسمها؟
+
+414
+00:35:36,180 --> 00:35:41,820
+فنل و هذه المجموعة؟ أكلور و هذا C double bond O
+
+415
+00:35:41,820 --> 00:35:47,380
+aldehyde كام ذرع عندكم؟ اتنين، تلاتة إذا المركب
+
+416
+00:35:47,380 --> 00:35:47,780
+إيه؟
+
+417
+00:35:50,640 --> 00:35:57,120
+بس لإنه في double bond بتبدأ من موقع اتنين إبروبين
+
+418
+00:35:57,120 --> 00:36:02,360
+ال إذا هنا لما أنا أقول ال two إبروبين ال ال two
+
+419
+00:36:02,360 --> 00:36:07,980
+تعبر عن إيش؟ عن موقع ال double bond إن هذا المركب
+
+420
+00:36:07,980 --> 00:36:11,980
+إبروبين ال في double bond و في ال ال مابنسمها
+
+421
+00:36:11,980 --> 00:36:17,640
+ترقيم دائما و أبدا يا مخدر رقم واحد إذا هذه ال two
+
+422
+00:36:17,640 --> 00:36:23,140
+بتحدد لموقع إيش؟بوقع الرابطة الثنائية نهجية على E
+
+423
+00:36:23,140 --> 00:36:28,680
+الان بعد ذلك اتيت عندكم ثلاثة كلورو ثلاثة فينيل
+
+424
+00:36:28,680 --> 00:36:33,120
+ثلاثة كلورو ثلاثة فينيل ثلاثة كلورو ثلاثة كلورو
+
+425
+00:36:33,120 --> 00:36:42,680
+ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو ثلاثة كلورو
+
+426
+00:36:50,250 --> 00:36:57,510
+كمجموعة مش مانا متصل C هنا carbon متصل CL متصل
+
+427
+00:36:57,510 --> 00:37:02,070
+carbon إذا المجموعة تلك بار على جهة واحدة فهذا
+
+428
+00:37:02,070 --> 00:37:10,630
+المركب إيش بيصير Z ثلاثة كلوروز ثلاثة كلوروز ثلاثة
+
+429
+00:37:10,630 --> 00:37:12,270
+كلوروز ثلاثة كلوروز ثلاثة كلوروز ثلاثة كلوروز
+
+430
+00:37:12,270 --> 00:37:12,330
+ثلاثة كلوروز ثلاثة كلوروز ثلاثة كلوروز
+
+431
+00:37:16,880 --> 00:37:23,340
+هذا سبوب الأحمر بنزالديهيد على موقع بارا إيش عليه
+
+432
+00:37:23,340 --> 00:37:28,660
+بارا نايترو بنزالديهيد ما تستغربوش إذا لجيتوا في
+
+433
+00:37:28,660 --> 00:37:33,140
+كتاب قديم كاتبه بارا نايترو بنزيل كاربالديهيد
+
+434
+00:37:33,140 --> 00:37:36,700
+بتاية اللي قبل شوية حكيتلكوا عنها لكن الأسهل
+
+435
+00:37:36,700 --> 00:37:45,620
+بنزالديهيد هذا سايكلوبنتين كاربالديهيد
+
+436
+00:37:47,090 --> 00:37:50,570
+مشغولنا لما بيحمل مجموعة الـ C double bond OH
+
+437
+00:37:50,570 --> 00:37:55,510
+بنقول عنها carb-aldehyde هذه المجموعة إذا هي carb
+
+438
+00:37:55,510 --> 00:38:01,050
+-aldehyde وهذا عبارة عن Cyclopentane
+
+439
+00:38:01,050 --> 00:38:04,730
+-carb-aldehyde حامل على موقع اتنين، لاحظوا ترقيمي
+
+440
+00:38:04,730 --> 00:38:07,230
+بدأته من وين؟ من ال الديهايد، إيش حامل على موقع
+
+441
+00:38:07,230 --> 00:38:11,730
+اتنين؟ two ethyl وعمللكوا الأسهم باتجاهكم، إذا
+
+442
+00:38:11,730 --> 00:38:18,380
+التنتين على جهة واحدة من حلقة، إذا مركبة سسواضح؟
+
+443
+00:38:18,380 --> 00:38:22,560
+زي السؤال اللي إجاكمه في الامتحان سيس ولا واحدة
+
+444
+00:38:22,560 --> 00:38:27,720
+جايبها غلط كله جبته صح طبعا هنا
+
+445
+00:38:27,720 --> 00:38:33,620
+الديهايد و الديهايد على الطرفين ضرة تنتين، تلاتة،
+
+446
+00:38:33,620 --> 00:38:39,880
+أربعة، خمسة، بنسميه بنتين دايالمش لو كان OH OH
+
+447
+00:38:39,880 --> 00:38:45,620
+بدنا نقول diol اه هنا الديهايد و الديهايد الديهايد
+
+448
+00:38:45,620 --> 00:38:49,920
+اسمه الشهرة glutaraldehyde ماعناه و ماعناه هدولة
+
+449
+00:38:49,920 --> 00:38:54,400
+كلهم من عيلة ال الديهايد امثلة اثرائية زي ما قولنا
+
+450
+00:38:54,400 --> 00:38:59,000
+هنا الاسيتون او الروبانون اخدناه الاسيتوفينون
+
+451
+00:38:59,000 --> 00:39:06,070
+اخدناهمشتقة Cyclohexanone انتوا المهم تحددوا الاصل
+
+452
+00:39:06,070 --> 00:39:11,210
+تبعه هذا كله مشتقة Cyclohexanone وحطوا واحد اتنين
+
+453
+00:39:11,210 --> 00:39:14,930
+تلاتة اربعة و بعدين اعطوا ارقام هذا Cyclohexanone
+
+454
+00:39:14,930 --> 00:39:21,450
+على ال two في برومو وعلى ال four ديمثل اذا two
+
+455
+00:39:21,450 --> 00:39:28,270
+برومو four four دايمثل Cyclohexanone هذا المركب
+
+456
+00:39:28,270 --> 00:39:32,770
+اللي شايفينه مين تقولي كيف بده تسميه؟بزان بنزين
+
+457
+00:39:32,770 --> 00:39:37,010
+حملة أشياء كتيرة انسوها كبنزين عملوها على أنها
+
+458
+00:39:37,010 --> 00:39:45,310
+مجموعة فنل واعتبروا أن هذا المركب تبعي كام كربونا؟
+
+459
+00:39:45,310 --> 00:39:53,930
+لأ بيجي كمان واحدة هنا عشان تصير أطول سلسلةثلاث
+
+460
+00:39:53,930 --> 00:39:58,990
+كربونات وهذه جاية بين مجموعتين الكل يعتبر اللي
+
+461
+00:39:58,990 --> 00:40:05,910
+عندك كيتون يعتبر اللي عندك كيتون بروبانون الان هنا
+
+462
+00:40:05,910 --> 00:40:10,390
+بينا نقول one two three على ال one في عندنا phenyl
+
+463
+00:40:10,390 --> 00:40:17,330
+وعلى ال two مثل و مثل اذا two two die مثل one
+
+464
+00:40:17,330 --> 00:40:22,770
+phenyl بروبانونتو تو داي مثل وان فيل البروبانون او
+
+465
+00:40:22,770 --> 00:40:30,870
+كان ممكن تقول وان بروبانون مش مشكلة كبيرة هذا
+
+466
+00:40:30,870 --> 00:40:36,330
+المركب one two three four five سايكلو بنتين سايكلو
+
+467
+00:40:36,330 --> 00:40:44,140
+بنتان on on ولا on ondie on اذا هذا بيصير one
+
+468
+00:40:44,140 --> 00:40:48,080
+three ليش؟ لأن ال die on هدولة تنتين ال on وين
+
+469
+00:40:48,080 --> 00:40:52,100
+موجودين؟ ع واحد و تلت اذا هذا one three
+
+470
+00:40:52,100 --> 00:40:58,300
+cyclobentain die on اش
+
+471
+00:40:58,300 --> 00:41:07,000
+عليه غير ال die on؟ two two die مثل عليه two two
+
+472
+00:41:07,000 --> 00:41:16,370
+die مثل نشوف اخر مركبهذه الحلقة عملوها Substitute
+
+473
+00:41:16,370 --> 00:41:21,410
+Cyclobutane هي عندك ذرة تنتين تلاتة هذا المجموعات
+
+474
+00:41:21,410 --> 00:41:27,850
+الوظيفية عليها تلت كربونات شو هما الديهايد
+
+475
+00:41:27,850 --> 00:41:35,550
+وكيتون مركب لإيش بنسبه الديهايد إذا هذا عبارة عن
+
+476
+00:41:35,550 --> 00:41:44,130
+مشتقة Probanal Probanal على موقع تلاتةالسبب اللي
+
+477
+00:41:44,130 --> 00:41:48,510
+بتقولها لما ترجع لأصلها شو اسمها اقزو اذا three
+
+478
+00:41:48,510 --> 00:41:55,770
+oxo-probanal وعلى three أيضا cyclobutyl اذا three
+
+479
+00:41:55,770 --> 00:42:04,150
+oxo-cyclobutyl-probanal three oxo-cyclobutyl
+
+480
+00:42:04,150 --> 00:42:11,880
+-probanal واضح بتيألي هيكلأ بديش أشرح غير التسمية
+
+481
+00:42:11,880 --> 00:42:14,640
+اليوم يعني إذا بدكوا و لابد بعطيكوا مركب أنتوا
+
+482
+00:42:14,640 --> 00:42:22,620
+تسموه لكن أكتر من هيك المرة الجاية هذه ال slide
+
+483
+00:42:22,620 --> 00:42:26,820
+تاب على التسمية هذه ال slide تاب على التسمية لازم
+
+484
+00:42:26,820 --> 00:42:31,660
+نمر عليها بدقيقة انتبهوا معايا اتعلمناهم مثل
+
+485
+00:42:31,660 --> 00:42:35,600
+اثلبروبل ايزوبروبل ترتشر بيوت الواطفار لما أخدنا
+
+486
+00:42:35,600 --> 00:42:43,140
+الالكينزقلنا في عندنا بعض المجموعات الشهيرة الفينل
+
+487
+00:42:43,140 --> 00:42:51,560
+والألل الان في ال .. مجموعات
+
+488
+00:42:51,560 --> 00:42:58,440
+يعني السبب اللي قلت OH كمجموعة
+
+489
+00:42:58,440 --> 00:43:05,310
+بيكون اسمها formalو الـ C double bond O CH3 بيكون
+
+490
+00:43:05,310 --> 00:43:10,870
+اسمها Acetyl و الـ C double bond O Phenyl بيكون
+
+491
+00:43:10,870 --> 00:43:17,570
+اسمها Benzyl لأ مش Benzyl انتبهوا معايا، هذه
+
+492
+00:43:17,570 --> 00:43:22,410
+Benzyl ليش احنا بنركز انها مش Benzyl لأن حقيقة في
+
+493
+00:43:22,410 --> 00:43:26,050
+مجموعة تانية في ال organ ال chemistry اسمها Benzyl
+
+494
+00:43:26,830 --> 00:43:32,550
+واضح؟ المجموعة ال بنزل بنطعم هذه المجموعة اللي هي
+
+495
+00:43:32,550 --> 00:43:39,330
+زي هيك و CH2 هذه المجموعة اسمها بنزل فماحدش خربت
+
+496
+00:43:39,330 --> 00:43:52,630
+كلمة بنزل بنزل وبنزايل وحطيت هنا CH2CL وقلتلكوا
+
+497
+00:43:52,630 --> 00:43:57,980
+سمولي هذا المركببال common nomenclature بنزل
+
+498
+00:43:57,980 --> 00:44:07,540
+إكلورايد لأن هذه المجموعة كلها إسم بنزل بنزل تبني
+
+499
+00:44:07,540 --> 00:44:15,460
+في المركز المركب صوفي برمضان و بارك يعني تبني في
+
+500
+00:44:15,460 --> 00:44:22,260
+المركب المركب الصوفي برمضان و بارك
+
+501
+00:44:24,810 --> 00:44:30,650
+بنزيل بنزيل اكلوراي
+
+502
+00:44:30,650 --> 00:44:37,690
+بالايوباد هلأ
+
+503
+00:44:37,690 --> 00:44:46,070
+مصطلقة إيش؟ مثيل، بس كرمولة واحدة، شو بيحمل
+
+504
+00:44:46,070 --> 00:44:55,520
+المثيل؟ اكلورا ثانل مثيلكأنه أصله CH4 شيلنا H
+
+505
+00:44:55,520 --> 00:45:00,800
+وعطينا Cl وشيلنا H وعطينا Ph إذا هو مشتقة مثيل
+
+506
+00:45:04,270 --> 00:45:10,050
+مثل بنزل إكلورايد فلما نقول بنزل إكلورايد مُركّب و
+
+507
+00:45:10,050 --> 00:45:16,890
+لما نقول بنزايل إكلورايد مُركّب تاني مختلف رجال ما
+
+508
+00:45:16,890 --> 00:45:25,270
+تخلطوش بينهم بنزايل و بنزل مُركّبين مختلفين H
+
+509
+00:45:25,270 --> 00:45:29,770
+-formyl سيضاو المندقو مثل أسيتل و سيضاو بالمندقو
+
+510
+00:45:29,770 --> 00:45:32,390
+فينل بنزايد
+
+511
+00:45:35,400 --> 00:45:39,960
+بهيك بننتهي اليوم في موضوع التسمية
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI.srt
new file mode 100644
index 0000000000000000000000000000000000000000..d5528a214b087684ba0525292c722d217ab9f5d8
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI.srt
@@ -0,0 +1,1649 @@
+1
+00:00:07,830 --> 00:00:13,090
+بسم الله الرحمن الرحيم زي ما بتعرفوا احنا بدأنا في
+
+2
+00:00:13,090 --> 00:00:19,470
+الفصل السادس اللي هو كان عن الكايل هالايدز بشكل أساسي
+
+3
+00:00:19,470 --> 00:00:24,950
+بنحكي عن نوعين من التفاعلات، تفاعلات الإبدال
+
+4
+00:00:24,950 --> 00:00:30,430
+وتفاعلات الحذف، إذا بدي أمر بسرعة معكم مرات
+
+5
+00:00:30,430 --> 00:00:35,070
+الواحد بحب أنه يذكركم بالأشياء اللي حكيناها، ليش؟
+
+6
+00:00:36,210 --> 00:00:41,870
+بنذكر الطلاب بما شرح في محاضرة ربما بدقيقة أو 
+
+7
+00:00:41,870 --> 00:00:46,750
+دقيقتين بيحسوا كأنه الموضوع مش صعب لما يُؤخذ
+
+8
+00:00:47,480 --> 00:00:52,980
+كصورة كلية احنا اللي حكيناه أننا تعرّفنا ببساطة على 
+
+9
+00:00:52,980 --> 00:00:57,020
+أنواع الكايل هالايدز ال primary و ال secondary و
+
+10
+00:00:57,020 --> 00:01:02,020
+ال tertiary بعد هيك تعرّفنا على قوة الروابط مع ال
+
+11
+00:01:02,020 --> 00:01:06,420
+كايل هالايدز قلنا أنه أضعف الروابط مع اليود و بعدها
+
+12
+00:01:06,420 --> 00:01:11,200
+مع البروم وبالتالي أكثر رابطة معرضة للكسر و
+
+13
+00:01:11,200 --> 00:01:15,280
+للإبدال بسهولة اللي هي مع اليود و بعدها مع البروم
+
+14
+00:01:15,280 --> 00:01:19,790
+أصعب الروابط مع ال فلور و لذلك احنا ما بندرسش فلور
+
+15
+00:01:19,790 --> 00:01:28,430
+يعني هذه شغلة صعبة بعد هيك قلنا أنّه عشان يتم الإبدال 
+
+16
+00:01:29,250 --> 00:01:33,990
+لازم يكون في عندنا نيوكليوفايل لأن الكربون مع ال X
+
+17
+00:01:33,990 --> 00:01:36,890
+أو الكربون مع ال CL اللي بيقارعي ايش الكربون
+
+18
+00:01:36,890 --> 00:01:40,430
+نوعًا ما positive ايش اللي بيهاجم على ال positive و
+
+19
+00:01:40,430 --> 00:01:45,170
+يطرد ال X بإلكتروناتها بيكون إما negative أو بيحمي
+
+20
+00:01:45,170 --> 00:01:49,910
+الإلكترونات اللي بنسميه نيوكليوفايل، النيوكليوفايل 
+
+21
+00:01:49,910 --> 00:01:54,870
+أخذتوا عنها أنّه ممكن تكون neutral وممكن تكون 
+
+22
+00:01:54,870 --> 00:01:59,810
+charged، لتشارج نيوكليوفايل شحنة سالبة بيجي سالب
+
+23
+00:01:59,810 --> 00:02:05,530
+يدخل على التفاعل و بيطرد X سالب واضح يعني بدخل
+
+24
+00:02:05,530 --> 00:02:11,470
+نيوكليوفايل سالب و بتطلع X سالبة، الأمر بسيط الآن
+
+25
+00:02:11,470 --> 00:02:15,230
+لنيوترال نيوكليوفايل بيجي نيوكليوفايل بيتفاعل و
+
+26
+00:02:15,230 --> 00:02:20,710
+بعد ذلك بيفقد H plus فدائمًا اللي بيكون عندي كنتج
+
+27
+00:02:20,710 --> 00:02:25,090
+هو النيوكليوفايل minus H plus يعني لو كان
+
+28
+00:02:25,090 --> 00:02:29,450
+النيوكليوفايل ماء H2O شو المجموعة اللي بده يحطها؟ OH
+
+29
+00:02:29,450 --> 00:02:33,430
+لو كان النيوكليوفايل إيثانول إيثل OH شو المجموعة اللي 
+
+30
+00:02:33,430 --> 00:02:39,090
+بده يحطها؟ إيثل O إيثوكسايد لو كان النيوكليوفايل
+
+31
+00:02:39,090 --> 00:02:45,510
+أمونيا NH3 شو النيوكليوفايل اللي بتحطها NH2 هي
+
+32
+00:02:45,510 --> 00:02:50,610
+بتتفاعل في مرحلتها الأولى على شكل NH3 ثم مباشرة
+
+33
+00:02:50,610 --> 00:02:56,730
+بتفقد H بلس برضه تعرّفنا أنّ شيء أساسي عشان نفهم
+
+34
+00:02:56,730 --> 00:03:01,450
+التفاعلات أن نعرف قوة النيوكليوفايل بتكون إما strong
+
+35
+00:03:01,450 --> 00:03:04,830
+وإما weak، قلنا دائمًا ال charge 
+
+36
+00:03:04,830 --> 00:03:08,520
+النيوكليوفايل they are stronger thanالـ neutral
+
+37
+00:03:08,520 --> 00:03:14,340
+ones، وقلنا أنّه كل ما اتحركنا في الدورة إلى اليسار 
+
+38
+00:03:14,340 --> 00:03:18,040
+أو في المجموعة إلى أسفل الـ nucleophilic power 
+
+39
+00:03:18,040 --> 00:03:22,500
+بتزيد دائمًا لما أعمل مقارنة بقارن charged
+
+40
+00:03:22,500 --> 00:03:26,380
+nucleophile مع charged nucleophile أو neutral مع 
+
+41
+00:03:26,380 --> 00:03:31,920
+neutral، أخذنا أمثلة على أنواع ال nucleophile بمعنى 
+
+42
+00:03:31,920 --> 00:03:35,420
+أنّ ال nucleophile ممكن الذرة المهاجمة اللي عليها 
+
+43
+00:03:35,420 --> 00:03:41,130
+زوج من الإلكترونات تكون أكسجين ممكن تكون نيتروجين
+
+44
+00:03:41,130 --> 00:03:45,970
+ممكن تكون كربون ممكن تكون سالفر ممكن تكون هالوجين
+
+45
+00:03:45,970 --> 00:03:53,990
+كلهم القاسم المشترك بينهم ايش؟ وجود زوج الإلكترونات
+
+46
+00:03:53,990 --> 00:03:58,410
+واضح؟ ولذلك في النهاية الكيمياء مرات كتيرة لما 
+
+47
+00:03:58,410 --> 00:04:03,290
+الواحد بده يفهمها بلاحظ أنّ كلما تعمق الإنسان في
+
+48
+00:04:03,290 --> 00:04:09,360
+فهم الكيمياء بيرجع لإيش؟ للإلكترونات لأن الإلكترونات
+
+49
+00:04:09,360 --> 00:04:13,580
+هي اللي بتعمل التفاعلات والأشياء ولذلك لو يعني 
+
+50
+00:04:13,580 --> 00:04:17,640
+شوية صغيرة بدنا نخرج عن الموضوع لو كنت تستعرض 
+
+51
+00:04:17,640 --> 00:04:23,240
+تعريف مثلًا الأحماض والقواعد أول ما بدءوا يعرفوا 
+
+52
+00:04:23,240 --> 00:04:27,020
+الحمض والقاعدة Arrhenius قال الحمض اللي بيعطي H
+
+53
+00:04:27,020 --> 00:04:32,100
+plus والقاعدة اللي بتعطي OH minus، إجا بعد هيك
+
+54
+00:04:32,100 --> 00:04:35,060
+Laurie Bronsted قال الحمض اللي بيعطي H plus
+
+55
+00:04:35,060 --> 00:04:39,340
+والقاعدة اللي بتكتسب H plus، خلاصني من مشكلة OH 
+
+56
+00:04:39,340 --> 00:04:44,780
+minus، إجا بعدين Lewis لما اتعمق أكثر ايش قال؟ الحمض
+
+57
+00:04:44,780 --> 00:04:47,680
+اللي بيكتسب إلكترونات والقاعدة اللي بتعطي
+
+58
+00:04:47,680 --> 00:04:51,060
+إلكترونات، فالعلم في قمة التطور وصل لوين؟ 
+
+59
+00:04:51,060 --> 00:04:55,360
+للإلكترونات، فاللي بيفهم هذا القاسم المشترك بيصير
+
+60
+00:04:55,360 --> 00:04:59,240
+الموضوع سهل عليه، يعني ممكن واحدة تنظر لجدول زي هذا
+
+61
+00:04:59,240 --> 00:05:04,730
+تقول شو هالمصيبة ويقطع الكيمياء، وحدة ثانية بتقول كل
+
+62
+00:05:04,730 --> 00:05:09,090
+اللي موجود بالجدول هذا هو فكرة واحدة أن أي ذرة 
+
+63
+00:05:09,090 --> 00:05:15,210
+عليها زوج من الإلكترونات بسمها نيوكليوفايل بيجي
+
+64
+00:05:15,210 --> 00:05:18,490
+هذا زوج الإلكترونات بيهجم على الكربون و بطرد ال X
+
+65
+00:05:18,490 --> 00:05:22,930
+مع زوج إلكتروناتها، إذا هنا أنا صار عندي المعادلة
+
+66
+00:05:22,930 --> 00:05:31,390
+العامة اللي هي نيوكليوفايل، مرات بيقولوا Z زوج
+
+67
+00:05:31,390 --> 00:05:35,530
+الإلكترونات كل الفكرة فيه زوج الإلكترونات زائد ال
+
+68
+00:05:35,530 --> 00:05:43,110
+RX، ال X سالب ال R موجبة، وين بدو ييجي السالب هذا
+
+69
+00:05:43,110 --> 00:05:50,270
+بدو ييجي هنا يهاجم ويطرد ال X مع الإلكترونات، خلصنا
+
+70
+00:05:50,270 --> 00:05:55,260
+كل المعادلات اللي موجودة بتلخصوا بهذه المعادلة
+
+71
+00:05:55,260 --> 00:05:58,640
+العامة، كل المعادلات اللي موجودة بيصير عندكم في
+
+72
+00:05:58,640 --> 00:06:06,040
+النهاية RZ زائد X minus، واضح؟ فشوفوا كيف لما يصير
+
+73
+00:06:06,040 --> 00:06:08,580
+عندكم قاعدة كلية بيبطل الواحد يخاف أن
+
+74
+00:06:08,580 --> 00:06:12,920
+النيوكليوفايل Oxygen نيتروجين وبطّار مش مش المشكلة
+
+75
+00:06:12,920 --> 00:06:19,660
+واضح؟ المهم في النيوكليوفايل وجود زوج الإلكترونات
+
+76
+00:06:20,450 --> 00:06:25,590
+هذه ال slide أخذناها برضه إذا بتذكروا وبيكون
+
+77
+00:06:25,590 --> 00:06:29,590
+رجعنا كويس كل اللي اخذتوّه في المحاضرة الماضية أنّ
+
+78
+00:06:29,590 --> 00:06:33,270
+لما كان عندي ال nucleophile يكون مشحون زي OH-, 
+
+79
+00:06:33,270 --> 00:06:41,160
+التفاعل ببساطة بتدخل OH-, تطلع Br-, خلصنا، لما يكون
+
+80
+00:06:41,160 --> 00:06:46,320
+الـ nucleophile متعادل بتدخل الميّة و تصبح Br- بعد
+
+81
+00:06:46,320 --> 00:06:50,520
+ذلك هذه الميّة اللي دخلت هنا ماذا ستفقد؟ هيدروجين
+
+82
+00:06:50,520 --> 00:06:55,400
+هيدروجين عشان تصفؤه H واضح؟ عشان تصفؤه H
+
+83
+00:06:55,400 --> 00:06:59,600
+هذا الهيدروجين هذا اللي طلعت في الآخر مع ال Br- بتطلع
+
+84
+00:06:59,600 --> 00:07:05,120
+على شكل HBr، الآن لما اجينا نشرح ال mechanisms أو
+
+85
+00:07:05,120 --> 00:07:12,780
+آليات التفاعل قلنا إنّه في عندنا إما ممكن نصنف SN1
+
+86
+00:07:12,780 --> 00:07:19,620
+ميكانيزم أو SN2 ميكانيزم، ال SN1 حطينا لها شروط و
+
+87
+00:07:19,620 --> 00:07:26,260
+SN2 حطينا لها شروط، شروط ال SN2 كانت عبارة عن strong
+
+88
+00:07:26,260 --> 00:07:31,040
+nucleophile و primary alkyl halide، يعني لما يكون
+
+89
+00:07:31,040 --> 00:07:34,360
+عندي strong nucleophile ال primary alkyl halide
+
+90
+00:07:34,360 --> 00:07:40,920
+غالباً بيصير ميكانيزم مكونة من جزئين يعني ال 
+
+91
+00:07:40,920 --> 00:07:45,560
+nucleophile بيهاجم و بيبدأ يعمل رابطة ال Br بتبدأ 
+
+92
+00:07:45,560 --> 00:07:48,880
+تنكسر بيصير عندي هذا ال transition state اللي
+
+93
+00:07:48,880 --> 00:07:54,880
+سميناه بـ pentavalent خمسية الارتباط، بعد ذلك يكتمل
+
+94
+00:07:54,880 --> 00:07:58,840
+تكوين هذه الرابطة أو يكتمل كسر ال Br minus طبعًا
+
+95
+00:07:58,840 --> 00:08:02,880
+بتلاحظوا أنه بسرعة ال inversion ولا لأ؟ ال Br كانت
+
+96
+00:08:02,880 --> 00:08:07,700
+باتجاه الـ nucleophile، جاء بالاتجاه المعاكس، ايش
+
+97
+00:08:07,700 --> 00:08:12,380
+اللي بيسمح لل nucleophile أنّه يهاجم بسهولة؟
+
+98
+00:08:12,880 --> 00:08:17,200
+وجود وسع أن هذه الكربون تكون primary، لو كان ال
+
+99
+00:08:17,200 --> 00:08:22,580
+tertiary الوسع مغلق ما فيش مكان يدخل ال nucleophile
+
+100
+00:08:22,580 --> 00:08:27,360
+من خلاله، فأفضل شيء لهذه ال mechanism أنّه يكون هذا
+
+101
+00:08:27,360 --> 00:08:31,400
+ال nucleophile strong ويلاقي وسع يلاقي primary
+
+102
+00:08:31,400 --> 00:08:33,020
+carbon
+
+103
+00:08:34,870 --> 00:08:39,270
+عملنا ملحوظة طاقة للتفاعل، هذه المتفاعلات لـ 
+
+104
+00:08:39,270 --> 00:08:42,270
+Transition State pentavalent دائمًا لـ Transition
+
+105
+00:08:42,270 --> 00:08:49,010
+State الطاقة تبعتها أعلى من ال reactants و ال 
+
+106
+00:08:49,010 --> 00:08:53,190
+products بعد ذلك لما تفقد ال Br بيكتمل هنا تكوين
+
+107
+00:08:53,190 --> 00:08:58,310
+الرابطة، تكوين الرابطة بيفقد من خلاله طاقة فبينزل 
+
+108
+00:08:58,310 --> 00:09:02,030
+التفاعل سواء كان exothermic أو endothermic مش مشكلة
+
+109
+00:09:02,030 --> 00:09:07,610
+كل هذا الكلام تقريبًا شرحناه، هذه ال slide اللي
+
+110
+00:09:07,610 --> 00:09:11,930
+موجودة عندنا ربما أضفناها ما فيش فيها أي شيء غير
+
+111
+00:09:11,930 --> 00:09:17,680
+التأكيد على فكرة أنّه لما يكون عنده primary
+
+112
+00:09:17,680 --> 00:09:23,220
+الكايل هالايد هجوم للنيوكليوفايل اللي هنا بين Z مرسوم
+
+113
+00:09:23,220 --> 00:09:27,900
+بالأزرق بيكون أسهل يعني أبسط مثال لو كان عندي مثل
+
+114
+00:09:27,900 --> 00:09:32,080
+برومايد مثلًا، حيكون عندي H و H و H، لاحظوا ال 
+
+115
+00:09:32,080 --> 00:09:37,280
+hydrogens ايش حجمهم صغير ففي وسع لل Z تيجي من هنا
+
+116
+00:09:37,280 --> 00:09:41,200
+وهذه تبدأ تطلع فصار في احتمال أن يكون هنا عندي خمس
+
+117
+00:09:41,200 --> 00:09:47,700
+روابط بسهولة في ال transition state طبعًا لو صار
+
+118
+00:09:47,700 --> 00:09:52,600
+عندي primary بدي يكون عندي ارتباط مع كربون واحدة
+
+119
+00:09:52,600 --> 00:09:56,720
+برضه ما زال عندي two hydrogens و ال two hydrogens
+
+120
+00:09:56,720 --> 00:10:00,880
+ايش بيكونوا صغار، الآن لو صار secondary هي
+
+121
+00:10:00,880 --> 00:10:05,080
+secondary هي مرتبطة ب two carbons، بدأ يكبر الحجم
+
+122
+00:10:05,080 --> 00:10:09,300
+اللي هنا بتبدأ ال Z يصير حواليها ايش نوع من 
+
+123
+00:10:09,300 --> 00:10:14,250
+الصعوبة، لو صار tertiary هذه الكربون بيصير حواليها
+
+124
+00:10:14,250 --> 00:10:18,050
+مثل ومثل ومثل، طبعًا أنتوّا تخيلوا هدول ثلاث طبقات 
+
+125
+00:10:18,050 --> 00:10:23,590
+كبار وكل مثل طالع منها H و H و H و H و 
+
+126
+00:10:23,590 --> 00:10:27,510
+H و H، يعني لو بدكم تتخيلوها أن هذه كربون 
+
+127
+00:10:27,510 --> 00:10:29,990
+حيطلع H وكمان H وكمان H وكمان H وكمان H
+
+128
+00:10:29,990 --> 00:10:30,610
+وكمان H وكمان H وكمان H وكمان H وكمان H
+
+129
+00:10:30,610 --> 00:10:34,110
+وكمان H وكمان H وكمان H وكمان H وكمان H
+
+130
+00:10:34,110 --> 00:10:35,470
+وكمان H وكمان H وكمان H وكمان H وكمان H
+
+131
+00:10:35,470 --> 00:10:38,900
+وكمان H وكمان، فعشان هيك ال SN2 reactions
+
+132
+00:10:38,900 --> 00:10:44,600
+ما بتصيرش مع ال tertiary، السبب هنا بنسميه steric
+
+133
+00:10:44,600 --> 00:10:50,360
+factor، steric يعني متعلق بعمل ايش؟ بالازدحام، أنّه
+
+134
+00:10:50,360 --> 00:10:57,050
+ما فيش وسع، steric factor ماشي عن hysteric factor 
+
+135
+00:10:57,050 --> 00:11:03,050
+سبب متعلق بعمل الازدحام أنّ ما فيش أو مرات بيسموه 
+
+136
+00:11:03,050 --> 00:11:08,410
+hysteric hindrance ايش يعني hindrance ممانعة أنّه
+
+137
+00:11:08,410 --> 00:11:13,250
+ما فيش وسع أنّه يجي يتفاعل واضح؟ فلما نقول ليش أفضل
+
+138
+00:11:13,250 --> 00:11:19,690
+شيء ال SN2 reaction مع ال primary الجواب بنقول
+
+139
+00:11:19,690 --> 00:11:22,750
+due to steric factor
+
+140
+00:11:25,410 --> 00:11:29,770
+يعني لو بدي أجيبلكم سؤال صح و غلط في الامتحان
+
+141
+00:11:29,770 --> 00:11:35,730
+أقول لكم ال SN2 reactions occurs with the
+
+142
+00:11:35,730 --> 00:11:40,110
+primary alkyl halides due to electronic factors 
+
+143
+00:11:40,110 --> 00:11:45,450
+أسباب تتعلق بالإلكترونات وش .. لأ due to steric
+
+144
+00:11:45,450 --> 00:11:50,290
+factor أسباب تتعلق بالفراغ بالوسع واضحة النقطة
+
+145
+00:11:50,290 --> 00:11:51,310
+هذه؟ اه
+
+146
+00:11:55,600 --> 00:12:00,380
+الآن بنبدأ في الدرس الجديد اللي بنكمل فيه اليوم
+
+147
+00:12:00,380 --> 00:12:05,860
+اللي هو لو كان عندي tertiary alkyl halides هنا بصير
+
+148
+00:12:05,860 --> 00:12:13,000
+بحكي عن ميكانيزم جديدة اللي بنسميها ايش؟ SN-1 
+
+149
+00:12:13,000 --> 00:12:17,520
+والآن بنشوف ليش بنسميها SN-1 في ال tertiary 
+
+150
+00:12:17,520 --> 00:12:22,860
+alkyl halides، آخر شغلة قبل شوية حكيناها احنا أن ال 
+
+151
+00:12:22,860 --> 00:12:29,800
+tertiary صعب يصير مع الـ SN2 لأنّه ما فيش شيء وسع
+
+152
+00:12:29,800 --> 00:12:34,820
+لأنّه في steric factor، بناءً على ذلك لما بيكون عندي
+
+153
+00:12:34,820 --> 00:12:38,660
+tertiary alkyl halide زي هذا المركب اللي هو 
+
+154
+00:12:38,660 --> 00:12:44,500
+tertiary butyl bromide شايفينه؟ ويكون بالذات كمان 
+
+155
+00:12:44,500 --> 00:12:48,860
+ال nucleophile ضعيف يعني مش قادر يهاجم ولا له
+
+156
+00:12:48,860 --> 00:12:54,300
+وسع يهاجم ماذا سيحصل؟ الـ nucleophile سيفعل الحياد
+
+157
+00:12:54,300 --> 00:13:00,920
+يستنى لحد ما تطلع ال Br مع إلكتروناتها يعني اللي 
+
+158
+00:13:00,920 --> 00:13:03,760
+بيصير أنّه بدأت تطلع ال Br مع إلكتروناتها، طيب لما
+
+159
+00:13:03,760 --> 00:13:09,240
+تطلع ال Br مع إلكتروناتها بيصير وسع بالتأكيد،
+
+160
+00:13:09,240 --> 00:13:12,700
+بالتأكيد بيصير واسع لإن أنا هنا كان عندي حوالين ال
+
+161
+00:13:12,700 --> 00:13:18,200
+carbon أربع مجموعات بيصير حوالين الكربون ثلاث
+
+162
+00:13:18,200 --> 00:13:22,560
+مجموعات، إذا صار في عندي وسع يعني لو تخيلنا مثلًا
+
+163
+00:13:22,560 --> 00:13:30,680
+أن هذه هي الكربون المعنية هذه ثلاث ذرات كربون،
+
+164
+00:13:30,680 --> 00:13:34,560
+شايفينهم؟ نعمل كل الروابط باللون الأصفر 
+
+165
+00:13:38,620 --> 00:13:42,240
+هذا هو الكاربوكاتيون اللي بيطلع عندي، طلعوا
+
+166
+00:13:42,240 --> 00:13:46,580
+معايا، هدول صاروا في مستوى واحد، صار عندي فراغ من 
+
+167
+00:13:46,580 --> 00:13:50,420
+هنا ومن هنا، لأي مجموعة من الخارج بدأت تيجي تهاجم 
+
+168
+00:13:51,090 --> 00:13:57,110
+أنها تيجي تتفاعل، واضح؟ إذا هنا كخطوة أولى لإنّ 
+
+169
+00:13:57,110 --> 00:14:03,010
+عندي ثلاث مجموعات مثل أكبر اللي بيصير أنّ بتطلع ال 
+
+170
+00:14:03,010 --> 00:14:06,130
+halogen atom، لما تطلع ال halogen atom مع 
+
+171
+00:14:06,130 --> 00:14:10,750
+
+201
+00:16:43,900 --> 00:16:47,520
+معناه أنه يتم التفاعل من الجهتين with more 
+
+202
+00:16:47,520 --> 00:16:52,980
+inversion يعني نفترض 70% inversion 30% من نفس
+
+203
+00:16:52,980 --> 00:16:56,820
+الاتجاه واضح فالـ stereo chemistry هنا إيش بنقول
+
+204
+00:16:56,820 --> 00:17:02,280
+عنها racimization لكن هل يا ترى هو complete
+
+205
+00:17:02,280 --> 00:17:06,700
+racimization؟ complete racimization يعني خمسين في
+
+206
+00:17:06,700 --> 00:17:12,960
+المية خمسين في المية الواقع لأ racimization with
+
+207
+00:17:12,960 --> 00:17:22,300
+أكثر more inversion ليش أكثر more inversion؟ because
+
+208
+00:17:22,300 --> 00:17:25,880
+of the presence of the leaving group
+
+209
+00:17:32,840 --> 00:17:37,920
+السبب هو وجود المجموعة المغادرة، ولو بعددها عشرين
+
+210
+00:17:37,920 --> 00:17:43,020
+كيلو، ولو بعدت إلى عشرين كيلو، لكن بيظل أنه ممكن
+
+211
+00:17:43,020 --> 00:17:46,780
+تيجي منها وممكن منها، لكن من وين الأسهل؟ من الجهة
+
+212
+00:17:46,780 --> 00:17:51,060
+اللي فاضية مية في المية، بتشوفوا الآن المعارك على
+
+213
+00:17:51,060 --> 00:17:55,380
+التلفزيون ولا لأ؟ الجيش اللي طالع، الناس بفضله
+
+214
+00:17:55,380 --> 00:17:59,920
+ييجوا من منطقته ولا بييجوا بالعكس تماما، ولو هو
+
+215
+00:17:59,920 --> 00:18:06,020
+بعيد، لكن ما زالت آثاره موجودة، واضح؟ إذا بيصير
+
+216
+00:18:06,020 --> 00:18:10,740
+عندك  Racimization with more inversion والسبب due
+
+217
+00:18:10,740 --> 00:18:14,620
+to the presence of the leaving group in the nearby
+
+218
+00:18:14,620 --> 00:18:20,700
+space في الفراغ القريب ما زالت الـ leaving group
+
+219
+00:18:20,700 --> 00:18:26,940
+موجودة واضح هذا الكلام؟ الآن لو بدنا نتعمق بهذه الـ
+
+220
+00:18:26,940 --> 00:18:34,540
+mechanism هلاحظ أن هذه الـ mechanism كام خطوة، خطوتين
+
+221
+00:18:34,540 --> 00:18:41,440
+هذه الخطوة الأولى وهذه الخطوة الثانية الخطوة
+
+222
+00:18:41,440 --> 00:18:47,340
+الأولى كسر الـ halogen bond لتكوين planar carbo cation
+
+223
+00:18:47,340 --> 00:18:53,760
+موجب والخطوة الثانية تتكون وخلص بيجي الـ
+
+224
+00:18:53,760 --> 00:19:01,300
+nucleophile يتفاعل ويعطيني الـ alkyl halide أيّهما
+
+225
+00:19:01,300 --> 00:19:06,200
+أصعب؟ الخطوة الأولى ولا الخطوة الثانية؟ الخطوة
+
+226
+00:19:06,200 --> 00:19:11,240
+الأولى .. مش دائما .. الخطوة الأولى هنا على أقل
+
+227
+00:19:11,240 --> 00:19:19,550
+تقدير أصعب .. ليش؟ لأنه أنا .. انتبهوا معي بلغة
+
+228
+00:19:19,550 --> 00:19:25,750
+الشحنات في الخطوة الأولى .. في الخطوة الأولى قاعد
+
+229
+00:19:25,750 --> 00:19:31,390
+بأفصل موجب عن سالب، امسكوا موجب وسالب وافصلوهم عن 
+
+230
+00:19:31,390 --> 00:19:37,110
+بعض إيش بدكم؟ energy في الخطوة الثانية قاعد بجيب
+
+231
+00:19:37,110 --> 00:19:43,620
+سالب على موجبداعمًا الـ repulsion هذا والـ
+
+232
+00:19:43,620 --> 00:19:47,900
+separation of positive and negative charges، it
+
+233
+00:19:47,900 --> 00:19:51,840
+needs energy، اللي بيفصل مغناطيسين ولا شحنتين
+
+234
+00:19:51,840 --> 00:19:57,400
+متجاذبتين، بده طاقة، واللي بيمسك مغناطيسين شمالي
+
+235
+00:19:57,400 --> 00:20:01,000
+وجنوبي وبيجربهم مع بعض، هم بتجربوا قبل ما إيده
+
+236
+00:20:01,000 --> 00:20:05,320
+تيجي، هم بصحبوله إيده، مظبوط ولا لأ؟ صح ولا لأ؟
+
+237
+00:20:05,320 --> 00:20:08,900
+عشان هيك لما بيكون عندنا يعني عفوا في المشاكل
+
+238
+00:20:08,900 --> 00:20:13,680
+العائلية لما يصير وبدهم يفصلوا الولد عن أمه
+
+239
+00:20:13,680 --> 00:20:19,320
+بتحسوا كيف بيجيبوا المنظر وهم قاعدين بيفصلوه وما
+
+240
+00:20:19,320 --> 00:20:24,540
+إلى ذلك وبصعوبة وفي آخر الفيلم لما يجيبولكم أن
+
+241
+00:20:24,540 --> 00:20:30,940
+الولد رجع لأمه بيدي جراي ملاحظين أنتو كيف؟ هنا
+
+242
+00:20:30,940 --> 00:20:36,140
+نفس الشيء أنا بأفصل موجب عن سالب واضح وبالتالي بحتاج
+
+243
+00:20:36,140 --> 00:20:41,000
+طاقة ولذلك هذه الخطوة هي الخطوة الصعبة هي الخطوة
+
+244
+00:20:41,000 --> 00:20:46,060
+الصعبة خطوة خروج الـ Br minus ونفس الشيء كان عندنا
+
+245
+00:20:46,060 --> 00:20:49,740
+نبقى نحكي على الواقع تباعنا لما اليهود طلعوا من
+
+246
+00:20:49,740 --> 00:20:54,760
+غزة كان طلوعهم من المستوطنات الخطوة الصعبة هذا
+
+247
+00:20:54,760 --> 00:21:04,190
+الطلوع أخد من سنة 67 لـ 2005 اه 38 سنة طيب بعد ما
+
+248
+00:21:04,190 --> 00:21:10,910
+طلعوا قداش لزم للناس عشان يدخلوا المستوطنات؟ عشر
+
+249
+00:21:10,910 --> 00:21:14,530
+ثواني يعني هم كانوا ما عادهم يطلعوا على الـ 12 في الليل
+
+250
+00:21:14,530 --> 00:21:17,770
+واحد زميل بيكلمنا 12 و 5 بيقول أنا في المستوطنة
+
+251
+00:21:18,600 --> 00:21:22,740
+الملاحظين أنتو الخطوة الصعبة والسهلة هذا جزء من
+
+252
+00:21:22,740 --> 00:21:28,480
+الكيميا أن إحنا بنقول هذه slow step وهذه fast
+
+253
+00:21:28,480 --> 00:21:33,320
+step إذا أنا أمام two steps واحدة منهم slow واحدة
+
+254
+00:21:33,320 --> 00:21:39,200
+منهم fast، لما أنا أسألكم الـ first step in SN1
+
+255
+00:21:39,200 --> 00:21:44,580
+reactions is a fast step it is the slow step والـ
+
+256
+00:21:44,580 --> 00:21:48,620
+second step fast step الآن الـ slow step بيعطوها
+
+257
+00:21:48,620 --> 00:21:52,680
+اسم بيقولوا عنها الـ rate determining step هي
+
+258
+00:21:52,680 --> 00:21:58,820
+الخطوة المحددة لسرعة التفاعل كل الموضوع بيعتمد
+
+259
+00:21:58,820 --> 00:22:05,240
+عليها الخطوة التانية إيش بنسميها تحصيل حاصل، واضح؟
+
+260
+00:22:05,240 --> 00:22:10,580
+إذا هذه الـ slow step هي إيش بنسميها إحنا كمان rate
+
+261
+00:22:10,580 --> 00:22:18,500
+determining step يعني هي الخطوة المحددة لسرعة
+
+262
+00:22:18,500 --> 00:22:25,080
+التفاعل واضح؟ أنتو ممكن شوية ماوعتوش الحواجز اللي
+
+263
+00:22:25,080 --> 00:22:28,660
+كانت على طريق غزة خانيونس واللي ما زالت موجودة في
+
+264
+00:22:28,660 --> 00:22:32,700
+الضفة لما واحد الآن بدو يطلع ما بين مدينتين في
+
+265
+00:22:32,700 --> 00:22:38,260
+عندهم حاجز بيكلم جماعة وأنا جاي إن شاء الله ..
+
+266
+00:22:38,260 --> 00:22:43,830
+واضح؟ ليش؟ وين عنده الخطوة الصعبة؟ لحد ما يقطع
+
+267
+00:22:43,830 --> 00:22:47,670
+الحاجز، بعد ما يقطع الحاجز، لو بده يكلم البيت،
+
+268
+00:22:47,670 --> 00:22:52,450
+بيكلمهم، بيقولهم جهزوا الأكل، أنا وصلت خلاص ضمن ..
+
+269
+00:22:52,450 --> 00:22:58,030
+قطع الحاجز هو الخطوة إيش؟ الصعبة، بعد هيك الخطوة
+
+270
+00:22:58,030 --> 00:23:02,930
+التانية هي خطوة إيش مالها؟ سهلة، واضح؟ الآن لاحظوا
+
+271
+00:23:02,930 --> 00:23:06,970
+مع الخطوة الصعبة هذه اعتمدت على متفاعل ولا
+
+272
+00:23:06,970 --> 00:23:11,830
+متفاعلين؟ متفاعل، إيش شايفين فيها أنتو بس؟
+
+273
+00:23:11,830 --> 00:23:17,230
+الـ alkyl halide، الـ nucleophile إيش ماله؟ ضعيف، قاعد
+
+274
+00:23:17,230 --> 00:23:21,250
+بستنى، زي أحوالنا، الـ nucleophile ضعيف، ولذلك
+
+275
+00:23:21,250 --> 00:23:26,870
+هنا سرعة التفاعل كلها بتعتمد على إيش؟ على متفاعل
+
+276
+00:23:26,870 --> 00:23:32,170
+واحد مش على متفاعلين ولذلك هذي الميكانيزم بيسموها
+
+277
+00:23:32,170 --> 00:23:37,790
+substitution nucleophilic unimolecular يعني
+
+278
+00:23:37,790 --> 00:23:42,790
+بتعتمد على متفاعل واحد اللي هو الـ RX مش على
+
+279
+00:23:42,790 --> 00:23:47,810
+متفاعلين واضح؟ فلو أنا بدي أحط الـ rate of this
+
+280
+00:23:47,810 --> 00:23:56,960
+reaction شو بتساوي الـ rate؟ K في تركيز الـ RX هل
+
+281
+00:23:56,960 --> 00:24:01,600
+بيظهر عند الـ nucleophile؟ لأ قبل شوية لما كنا نحكي
+
+282
+00:24:01,600 --> 00:24:06,840
+SN2 إيش كنا نقول الـ rate؟ rate بتساوي كيف؟ RX في
+
+283
+00:24:06,840 --> 00:24:11,100
+nucleophile كانوا التنين بيتصارعوا هنا بس التفاعل
+
+284
+00:24:11,100 --> 00:24:17,240
+معتمد على الـ RX ولذلك اسمها substitution in
+
+285
+00:24:17,240 --> 00:24:21,830
+nucleophilic unimolecular إذن لو أنا بدأت أسألكم
+
+286
+00:24:21,830 --> 00:24:24,310
+the rate of SN1 reactions depends on the
+
+287
+00:24:24,310 --> 00:24:29,050
+concentration of nucleophile and RX لأ it depends
+
+288
+00:24:29,050 --> 00:24:32,990
+on the concentration of RX ماشي لو بدنا نسألها
+
+289
+00:24:32,990 --> 00:24:37,530
+بطريقة تانية SN1 reactions are first order
+
+290
+00:24:37,530 --> 00:24:42,810
+reactions first order معتمدين على الـ RX والـ RX الـ
+
+291
+00:24:42,810 --> 00:24:49,270
+factor تبعها واحد بينما الـ SN2 they are second
+
+292
+00:24:49,270 --> 00:24:54,490
+order reactions أو لو بدنا نسألهم، بيعتمدوا على
+
+293
+00:24:54,490 --> 00:25:01,490
+تركيز إيش؟ المتفاعلين الـ RX والـ nucleophile واضح؟
+
+294
+00:25:01,490 --> 00:25:08,290
+طبعا إحنا دائما بنهتم بالخطوة إيش اللي هي البطيئة
+
+295
+00:25:08,290 --> 00:25:12,670
+الـ slow step الخطوة التانية تحصيل حاصل الآن لاحظوا
+
+296
+00:25:12,670 --> 00:25:17,710
+معي أن أنتو هنا أخدتوا معلومات كتيرة متعلقة بالـ
+
+297
+00:25:17,710 --> 00:25:22,790
+SN1 reactions بتذكروا المرة الماضية أعطيناكم الـ
+
+298
+00:25:22,790 --> 00:25:29,250
+SN2 reactions  وأعطيناكم عليها شوية أشياء الآن لما
+
+299
+00:25:29,250 --> 00:25:34,550
+بدي أجي SN1 reactions وأبدأ أذكركم أفضل شيء بتمشي
+
+300
+00:25:34,550 --> 00:25:34,950
+معه
+
+301
+00:25:37,940 --> 00:25:43,560
+SN1 reactions الـ tertiary أفضل من الـ secondary
+
+302
+00:25:43,560 --> 00:25:46,820
+أفضل من الـ primary حتى الـ primary ما بيصيرش نمرة
+
+303
+00:25:46,820 --> 00:25:53,300
+تانية بتفضل الـ weak الـ nucleophile نمرة تلاتة one
+
+304
+00:25:53,300 --> 00:25:58,380
+or two steps two steps وبتكون تعرفوا أيّهما السريعة
+
+305
+00:25:58,380 --> 00:26:06,300
+فيهم التانية البطيئة الأولى نمرة أربع بتكون فيها
+
+306
+00:26:08,880 --> 00:26:12,020
+الـ carbocation هنا بنسمي الـ carbocation
+
+307
+00:26:12,020 --> 00:26:17,080
+intermediate مش transition state  لـ transition state
+
+308
+00:26:17,080 --> 00:26:20,160
+أثناء تكون الـ intermediate يعني بين هذا وهذا في
+
+309
+00:26:20,160 --> 00:26:23,540
+transition state وبين هذه وهذه في transition
+
+310
+00:26:23,540 --> 00:26:29,240
+state واضح؟ بس هذا الـ carbocation شو بنسميه إحنا؟
+
+311
+00:26:29,240 --> 00:26:34,660
+intermediate الكائن
+
+312
+00:26:36,860 --> 00:26:40,840
+أولية أو ثانوية؟ أولية أو ثانوية؟ أولية أو ثانوية؟
+
+313
+00:26:40,840 --> 00:26:41,080
+أولية أو ثانوية؟ أولية أو ثانوية؟ أولية أو ثانوية؟
+
+314
+00:26:41,080 --> 00:26:41,120
+أولية أو ثانوية؟ أولية أو ثانوية؟ أولية أو ثانوية؟
+
+315
+00:26:41,120 --> 00:26:41,320
+أولية أو ثانوية؟ أولية أو ثانوية؟ أولية أو ثانوية؟
+
+316
+00:26:41,320 --> 00:26:41,560
+أولية أو ثانوية؟ أولية أو ثانوية؟ أولية أو ثانوية؟
+
+317
+00:26:41,560 --> 00:26:51,280
+أولية أو ثانوية؟ أولية أو ثانوية؟ أولية أو ثانوية؟
+
+318
+00:26:51,280 --> 00:27:02,860
+أولية أو
+
+319
+00:27:02,860 --> 00:27:10,630
+ثانوية بـ SN1 طبعا ممكن هنا يجيني سؤال طب لو
+
+320
+00:27:10,630 --> 00:27:18,430
+عندي secondary الـ secondary بين بين الـ secondary
+
+321
+00:27:18,430 --> 00:27:24,710
+مع الـ strong الـ nucleophile شو هيمشي؟ SN2 والـ
+
+322
+00:27:24,710 --> 00:27:29,570
+secondary مع الـ weak بيمشي بـ SN1 واضح؟
+
+323
+00:27:32,690 --> 00:27:38,230
+هذا منحنى هذا منحنى للتفاعل الآن دائما اهتموا
+
+324
+00:27:38,230 --> 00:27:43,990
+بالمقارنات يعني لما بتدرسوا إحنا قبل شوية رسمنا لكم
+
+325
+00:27:43,990 --> 00:27:49,950
+منحنى للـ SN2 reaction إيش كانت ميزة منحنى الـ SN2
+
+326
+00:27:49,950 --> 00:27:55,910
+دائما منحنى الطاقة لتفاعل معين منحنى الطاقة لأي
+
+327
+00:27:55,910 --> 00:27:59,930
+تفاعل في عندي reactants الـ transition state بتعلق
+
+328
+00:27:59,930 --> 00:28:07,200
+product فكلبيك زي هذه بلغة المنحنيات تمثل إيش step
+
+329
+00:28:07,200 --> 00:28:12,300
+أو خطوة بناء على ذلك لما أنا هنا باجي بقى أطلع على
+
+330
+00:28:12,300 --> 00:28:17,960
+هذا التفاعل كم step؟ one step reactants؟ الـ
+
+331
+00:28:17,960 --> 00:28:21,840
+transition state of products الآن لما بدي أجي أرسم
+
+332
+00:28:21,840 --> 00:28:28,040
+منحنى لأسئلة SN1 reaction شو بتكون تتوقعوا يكون
+
+333
+00:28:28,040 --> 00:28:32,560
+عنده؟ بدي يصير عندي two steps مش one step يعني
+
+334
+00:28:32,560 --> 00:28:38,000
+المنحنى مرتين قمتين لكن لو بدنا نيجي نسأل أي قمة
+
+335
+00:28:38,000 --> 00:28:42,200
+يا ترى اللي بده تكون الأعلى والأصعب أي قمة
+
+336
+00:28:42,200 --> 00:28:46,920
+الأعلى والأصعب الأولى عشان هيك أنتو تطلعوا معنا
+
+337
+00:28:46,920 --> 00:28:51,360
+لما تشوفوا هي عندكم reactants وهي الـ transition
+
+338
+00:28:51,360 --> 00:28:56,520
+state اللي هو الـ carbocation هنا لو بتشوفوا الـ
+
+339
+00:28:56,520 --> 00:29:03,330
+transition state الأولى كده كبيرة جدا يعني بدو يقفز
+
+340
+00:29:03,330 --> 00:29:06,970
+قفزة كبيرة جدا الآن هذا الـ carbocation بعد هيك لما
+
+341
+00:29:06,970 --> 00:29:11,550
+بدو يتفاعل ويعطينا الـ product النهائي هنا ماخد
+
+342
+00:29:11,550 --> 00:29:17,650
+تفاعل الماء مع الـ .. هو الـ tertiary-butyl bromide
+
+343
+00:29:17,650 --> 00:29:21,370
+الـ reactant هو tertiary-butyl bromide هنا بيعطينا
+
+344
+00:29:21,370 --> 00:29:24,490
+الـ carbocation لحاله نفس المعادلة اللي أنتو
+
+345
+00:29:24,490 --> 00:29:29,270
+شوفتوها بعدين بيجي الـ Br .. زاد الـ Br minus بتيجي
+
+346
+00:29:29,270 --> 00:29:35,190
+الماء تتفاعل بضيف OH2 plus وبعدين بتفقد الـ H plus
+
+347
+00:29:35,190 --> 00:29:39,670
+الآن فقد الـ H plus موضوع بسيط مش موضوعنا لكن هنا
+
+348
+00:29:39,670 --> 00:29:44,060
+لما أبدأ أطلع كم خطوة هذا التفاعل خطوة تانية هي
+
+349
+00:29:44,060 --> 00:29:48,700
+الخطوة الأولى طلع معي reactant transition state لـ
+
+350
+00:29:48,700 --> 00:29:50,960
+product الـ carbocation الخطوة التانية الـ
+
+351
+00:29:50,960 --> 00:29:57,230
+carbocation مع الماء هذه الخطوة التانية البعض يشوف
+
+352
+00:29:57,230 --> 00:29:59,610
+الخطوة التالتة الخطوة التالتة ليست أساسية في
+
+353
+00:29:59,610 --> 00:30:03,330
+الميكانيزم الخطوة التالتة أن المياه تدخل مع
+
+354
+00:30:03,330 --> 00:30:08,230
+البروتون ويفقد البروتون منها تدخل OH2 ويفقد الـ OH
+
+355
+00:30:08,230 --> 00:30:14,210
+لكن كميكانيزم أساسي كم خطوة التفاعل؟ خطوتين واضح؟
+
+356
+00:30:14,210 --> 00:30:18,390
+دائما نقول الـ reaction is a two step
+
+357
+00:30:25,980 --> 00:30:33,100
+أيّهما أصعب؟ هذه القفزة أو هذه القفزة؟ هذه الصعوبة
+
+358
+00:30:33,100 --> 00:30:39,840
+التي هي الـ activation energy الفرق ما بين الـ
+
+359
+00:30:39,840 --> 00:30:43,080
+transition state والـ reactant أي activation هنا
+
+360
+00:30:43,080 --> 00:30:47,520
+عالي أي activation هنا قليل جدا ولذلك الـ first
+
+361
+00:30:47,520 --> 00:30:52,180
+step is the difficult step لازم يكون عندكم فهم
+
+362
+00:30:52,180 --> 00:30:57,280
+لطريقة رسم المنحنيات يعني هذا المنحنى مجرد ما
+
+363
+00:30:57,280 --> 00:31:01,780
+تشوفوه يقول لـ طالبة منكم اتفضلي اشرحي لنا ماذا يعني
+
+364
+00:31:01,780 --> 00:31:06,820
+هذا المنحنى لو رسلنا لحدين هتقول هذا منحنى تفاعل
+
+365
+00:31:06,820 --> 00:31:13,370
+من خطوتين هي خطوة؟ هي خطوة الخطوة الأولى صعبة
+
+366
+00:31:13,370 --> 00:31:18,470
+والخطوة الثانية سهلة والتفاعل بمجمله إذا شوفت هي
+
+367
+00:31:18,470 --> 00:31:21,710
+الـ reactants وهي الـ final products اكزوثرميك ولا
+
+368
+00:31:21,710 --> 00:31:32,670
+اندوثرميك هي الـ reactant الأصلي فقط
+
+369
+00:31:32,670 --> 00:31:39,540
+طاقة طاقة النواتج أقل إذا فقدت طاقة هذا Exothermic
+
+370
+00:31:39,540 --> 00:31:46,990
+بامتياز دائما التفاعل لما بيكونوا الـ products أقل
+
+371
+00:31:46,990 --> 00:31:51,190
+من الـ reactants في الطاقة، شو بيكون؟ Exothermic،
+
+372
+00:31:51,190 --> 00:31:55,350
+نرجع للتفاعل تبع قبل شوية، المنحنى الواحد، هذا
+
+373
+00:31:55,350 --> 00:3
+
+401
+00:34:35,620 --> 00:34:41,800
+شايفين الآن بدكم تكونوا متذكرين على السريع
+
+402
+00:34:41,800 --> 00:34:45,880
+شغلتين، لما بتكون Carbocation أخذنا احنا إذا 
+
+403
+00:34:45,880 --> 00:34:49,300
+بتدخلوا the stability of carbocation، بقولنا أنه
+
+404
+00:34:49,300 --> 00:34:56,740
+أكثر carbocation stable، ال tertiary، شو السبب؟ أنه
+
+405
+00:34:56,740 --> 00:35:01,600
+في حواليه electron donating groups، يعني في ال
+
+406
+00:35:01,600 --> 00:35:06,600
+tertiary، هذا موجبة، حواليه ثلاث مجموعات بيعطوا
+
+407
+00:35:06,600 --> 00:35:11,280
+إلكترونات، فتقل الشحنة الموجبة بقى، في ال secondary،
+
+408
+00:35:11,280 --> 00:35:15,600
+مجموعتين، هذا ال slide أخذناها احنا لما أخذنا ال
+
+409
+00:35:15,600 --> 00:35:21,820
+stability of carbocation سابقا، أخذنا شيء زيها هنا
+
+410
+00:35:21,820 --> 00:35:27,980
+في ال primary مجموعة واحدة بس، إذا وين أكثر إنقاص
+
+411
+00:35:27,980 --> 00:35:34,160
+لشحنة الموجبة وكل ما نقصت الشحنة زادت الثبات، إذا
+
+412
+00:35:34,160 --> 00:35:40,340
+أكثر شيء ثابت اللي هو ال tertiary carbocation
+
+413
+00:35:40,340 --> 00:35:45,060
+فأسهل شيء بتكون ال reaction الثابت هو اللي بتكون
+
+414
+00:35:45,060 --> 00:35:48,880
+بسهولة، وعشان هيك احنا بنقول أنه في ال questions و ال
+
+415
+00:35:48,880 --> 00:35:53,260
+reactions ال reaction أفضل من ال secondary أفضل من
+
+416
+00:35:53,260 --> 00:35:57,900
+ال primary، متذكرين هذا الكلام؟ ال reaction أفضل من
+
+417
+00:35:57,900 --> 00:36:02,780
+ال secondary أفضل من ال primary برضه لما أخذتو ال
+
+418
+00:36:02,780 --> 00:36:06,960
+carbon-cation نتذكر شغلة أخذناها قولنا لو اتكون
+
+419
+00:36:06,960 --> 00:36:10,800
+carbon-cation ونفترض كان secondary وفيه إمكانية
+
+420
+00:36:10,800 --> 00:36:15,600
+يعمل rearrangement تصير tertiary بتصير ولا لأ؟
+
+421
+00:36:15,600 --> 00:36:19,460
+بتصير بيعمل rearrangement  مشكلة بني آدم بيحس أنه وضعه
+
+422
+00:36:19,460 --> 00:36:26,690
+عشان هيك لو أنا مثلا بدي أجي أخد هذا المركب هنا فيه
+
+423
+00:36:26,690 --> 00:36:31,810
+primary X لو بدها تمشي بتفاعل SN2 تخيلوا ايش اللي
+
+424
+00:36:31,810 --> 00:36:35,850
+بيصير بيصير positive هنا هذا الكربو كاتيون ايش
+
+425
+00:36:35,850 --> 00:36:42,430
+ماله ال primary بِينتقل ال H من هنا بيصير secondary
+
+426
+00:36:42,430 --> 00:36:46,270
+ف ال Z اللي هي nucleophile بدل ما تيجي محل ال X وين بتجي
+
+427
+00:36:46,270 --> 00:36:52,060
+محل ال secondary ملاحظين معي الكاربو كاتيون أول ما 
+
+428
+00:36:52,060 --> 00:36:55,660
+يتكون بتكون هنا على ال primary صار متكون على ال
+
+429
+00:36:55,660 --> 00:37:00,700
+primary ايش بيصير ناقل هيدروجين شفت بيصير الكاربو 
+
+430
+00:37:00,700 --> 00:37:05,080
+كاتيون secondary ال Z بتيجي هنا أو لو هذا المركب
+
+431
+00:37:05,080 --> 00:37:09,680
+هاي X فقدت ايش صار هنا الكاربو كاتيون عنده لما
+
+432
+00:37:09,680 --> 00:37:17,070
+فقدت هذه ال X ال primary شو بيصير تنتقل هيدريد
+
+433
+00:37:17,070 --> 00:37:22,430
+تصبح CH3 وهنا الفراغ أين تأتي الـ Z كأن ال
+
+434
+00:37:22,430 --> 00:37:28,130
+primary في خطوته الأولى صار tertiary و ال Z جاءت
+
+435
+00:37:28,130 --> 00:37:30,710
+على ال tertiary لاحظوا هنا ال range من ال
+
+436
+00:37:30,710 --> 00:37:34,310
+primary إلى secondary هنا من ال primary إلى
+
+437
+00:37:34,310 --> 00:37:40,630
+tertiary لو افترضنا هنا راحت ال X صار كربوكاتيون
+
+438
+00:37:40,630 --> 00:37:45,500
+على العين والرأس بعد ذلك ماذا يحصل؟ النوكليوفايل تنتقل و
+
+439
+00:37:45,500 --> 00:37:49,340
+يصبح carbocation هنا، شو نوعه؟ ترشياري، ال Z بتيجي
+
+440
+00:37:49,340 --> 00:37:53,240
+عليه، هل ملاحظين؟ هذه هي ال rearrangement اللي سبق
+
+441
+00:37:53,240 --> 00:37:57,240
+أن أعطينا أمثلة زيها، يعني مش كثير هنركز بهذا
+
+442
+00:37:57,240 --> 00:38:00,300
+المسافة عليها، بس حتى لما تسمعوا كلمة
+
+443
+00:38:00,300 --> 00:38:03,520
+rearrangement يكون واضح عندكم، أنه لو كان عندي
+
+444
+00:38:03,520 --> 00:38:07,860
+primary carbocation بيمكنه يصير secondary؟ بيصير،
+
+445
+00:38:07,860 --> 00:38:12,020
+لو كان secondary بإمكانه يصير tertiary، بيصير، يعني
+
+446
+00:38:12,020 --> 00:38:15,820
+اللي معدله سبعين بده يخليه ثمانين، واللي معدله
+
+447
+00:38:15,820 --> 00:38:19,560
+ثمانين بده يخليه تسعين، ولو معدله سبعين وبيخليه
+
+448
+00:38:19,560 --> 00:38:27,290
+تسعين، نور على نور، نور على نور هذه ال slide
+
+449
+00:38:27,290 --> 00:38:31,650
+أخذناها قولنا أنه لو عندي secondary التفاعل بشكل
+
+450
+00:38:31,650 --> 00:38:35,790
+كبير بيعتمد على قوة ال nucleophile فلما يكون ال
+
+451
+00:38:35,790 --> 00:38:42,610
+nucleophile strong بيشجع SN2 لما يكون weak بيشجع
+
+452
+00:38:42,610 --> 00:38:47,370
+SN1 ال solvent له تأثير لكن خارج مستوى دراستنا هذه
+
+453
+00:38:47,370 --> 00:38:51,010
+ال slide بنختم المحاضرة اليوم فيها بإمكانكم
+
+454
+00:38:51,010 --> 00:38:56,610
+تقرؤوها بهدوء هي مقارنة احنا كتبناها على الجانب 
+
+455
+00:38:56,610 --> 00:39:02,170
+مرتين وبسيبها مكتوبة الآن و بنخلص المحاضرة هي
+
+456
+00:39:02,170 --> 00:39:08,270
+مقارنة ما بين ال SN2 و SN1 ال SN2 second order
+
+457
+00:39:08,270 --> 00:39:12,430
+أخذناها فيها complete inversion مش فيها
+
+458
+00:39:12,430 --> 00:39:15,390
+rearrangement ال reactivity بتراعي ما له أكثر من 
+
+459
+00:39:15,390 --> 00:39:21,340
+secondary أكثر من tertiary الآن ال SN1 first order
+
+460
+00:39:21,340 --> 00:39:25,800
+فيها racemization و في ال inversion زيادة فيها
+
+461
+00:39:25,800 --> 00:39:29,780
+rearrangement و ال tertiary أفضل من ال secondary
+
+462
+00:39:29,780 --> 00:39:34,320
+أفضل من ال primary و زدوا هنا أن هذه one step و
+
+463
+00:39:34,320 --> 00:39:40,680
+هذه two step و ال two steps اللي هنا الأولى slow
+
+464
+00:39:40,680 --> 00:39:45,680
+الثانية fast الآن مثل هذه المقارنة بنقدر نجيب
+
+465
+00:39:45,680 --> 00:39:50,630
+عليها كم سؤال صح و غلط عشرين سؤال صح و غلط و
+
+466
+00:39:50,630 --> 00:39:57,350
+بتلخص لنا كل المحاضرتين اللي فاتوا مثل هذه المقارنة 
+
+467
+00:39:57,350 --> 00:40:00,390
+بتلخص المحاضرتين اللي فاتوا وأنا بأتهيأ له أنه
+
+468
+00:40:00,390 --> 00:40:05,990
+أخذنا احنا يعني أخذناهم يعني بشكل بعتقد أنه كافي
+
+469
+00:40:05,990 --> 00:40:06,710
+شكرا
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_raw.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5554c13335c5914773c5d2d683ee7ae4456a4759
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/gWVEViU4QgI_raw.srt
@@ -0,0 +1,1884 @@
+1
+00:00:07,830 --> 00:00:13,090
+بسم الله الرحمن الرحيم زي ما بتعرفوا احنا بدأنا في
+
+2
+00:00:13,090 --> 00:00:19,470
+الفصل السادس اللي هو كان الكلهيلايتس بشكل أساسي
+
+3
+00:00:19,470 --> 00:00:24,950
+بنحكي عن نوعين من التفاعلات، تفاعلات الإبدال
+
+4
+00:00:24,950 --> 00:00:30,430
+وتفاعلات الحذف، إذا بدي أمر عالسريع معكم مرات
+
+5
+00:00:30,430 --> 00:00:35,070
+الواحد بحب أنه يذكركم بالأشياء اللي حكيناها، ليش؟
+
+6
+00:00:36,210 --> 00:00:41,870
+بنذكر الطلاب بما شرح في محاضرة ربما بدقيقة أو
+
+7
+00:00:41,870 --> 00:00:46,750
+دقيقتين بيحسوا كدهش أنه الموضوع مش صعب لما يُأخذ
+
+8
+00:00:47,480 --> 00:00:52,980
+كصورة كلية احنا اللي حكيناه ان اتعرفنا ببساطة على
+
+9
+00:00:52,980 --> 00:00:57,020
+انواع ال الكلهيلهيتز ال primary و ال secondary و
+
+10
+00:00:57,020 --> 00:01:02,020
+ال tertiary بعد هيك اتعرفنا على قوة الروابط مع ال
+
+11
+00:01:02,020 --> 00:01:06,420
+الكلهيلهيتز قلنا انه اضعف الروابط مع اليود و بعدها
+
+12
+00:01:06,420 --> 00:01:11,200
+مع البروم وبالتالي اكثر رابطة معرضة للكسر و
+
+13
+00:01:11,200 --> 00:01:15,280
+للابدال بسهولة اللي هي مع اليود و بعدها مع البروم
+
+14
+00:01:15,280 --> 00:01:19,790
+اصعب الروابطمع ال floor و لذلك احنا مابندرسش floor
+
+15
+00:01:19,790 --> 00:01:28,430
+يعني هذه شغلة صعبة بعد هيك قلنا انه عشان تم إبدال
+
+16
+00:01:29,250 --> 00:01:33,990
+لازم يكون في عند نيوكليوفايل لأن الكربون مع ال X
+
+17
+00:01:33,990 --> 00:01:36,890
+أو ال carbon مع ال CL اللي بيقارعي ايش الكربون
+
+18
+00:01:36,890 --> 00:01:40,430
+نوعا ما positive ايش اللي بيهاجم على ال positive و
+
+19
+00:01:40,430 --> 00:01:45,170
+يطرد ال X بإلكتروناتها بيكون إما negative أو بيحمي
+
+20
+00:01:45,170 --> 00:01:49,910
+الإلكترونات اللي بنسميه نيوكليوفايل النيوكليوفايل
+
+21
+00:01:49,910 --> 00:01:54,870
+أخدتوا عنها أنه ممكن تكون neutralو ممكن تكون
+
+22
+00:01:54,870 --> 00:01:59,810
+charged لتشارج نيوكليوفايل شحنه سالبة بيجي سالب
+
+23
+00:01:59,810 --> 00:02:05,530
+يدخل على التفاعل و بيطرد X سالب واضح يعني بدخل
+
+24
+00:02:05,530 --> 00:02:11,470
+نيوكليوفايل سالب و بتطلع X سالبة الأمر بسيط الان
+
+25
+00:02:11,470 --> 00:02:15,230
+لنيوترا لنيوكليوفايل بيجي لنيوكليوفايل بيتفاعل و
+
+26
+00:02:15,230 --> 00:02:20,710
+بعد ذلك بيفقد H plus فدائما اللي بيكون عندى كنتج
+
+27
+00:02:20,710 --> 00:02:25,090
+هو لنيوكليوفايل minusH plus يعني لو كان
+
+28
+00:02:25,090 --> 00:02:29,450
+النيكليوفييل مية H2O شو المجبع اللي بده تحطها؟ OH
+
+29
+00:02:29,450 --> 00:02:33,430
+لو كان النيكليوفييل إيثانول إيثل OH شو المجبع اللي
+
+30
+00:02:33,430 --> 00:02:39,090
+بده تحطها؟ إيثل O إيثوكسايد لو كان النيكليوفييل
+
+31
+00:02:39,090 --> 00:02:45,510
+أمونيا and H3شو النيوكليوفايل اللي بتحطها NH2 هي
+
+32
+00:02:45,510 --> 00:02:50,610
+بتتفاعل في مرحلتها الأولى على شكل NH3 ثم مباشرة
+
+33
+00:02:50,610 --> 00:02:56,730
+بتفقد H بلس برضه اتعرفنا انه شيء أساسي عشان نفهم
+
+34
+00:02:56,730 --> 00:03:01,450
+التفاعلات ان نعرف قوة النيوكليوفايل بتكون واجتش
+
+35
+00:03:01,450 --> 00:03:04,830
+strong وواجتش weak قولنا دائما ال charge
+
+36
+00:03:04,830 --> 00:03:08,520
+النيوكليوفايل they are stronger thanالـ neutral
+
+37
+00:03:08,520 --> 00:03:14,340
+ones وقلنا إنه كل ما اتحركنا في الدورة إلى اليسار
+
+38
+00:03:14,340 --> 00:03:18,040
+أو في المجموعة إلى أسفل الـ nucleophilic power
+
+39
+00:03:18,040 --> 00:03:22,500
+بتزيد دائما لما أعمل مقارنة بقارن charged
+
+40
+00:03:22,500 --> 00:03:26,380
+nucleophile مع charged nucleophile أو neutral مع
+
+41
+00:03:26,380 --> 00:03:31,920
+neutral أخدنا أمثلة على أنواع ال nucleophile بمعنى
+
+42
+00:03:31,920 --> 00:03:35,420
+إن ال nucleophile ممكن الذر المهاجمة اللي عليها
+
+43
+00:03:35,420 --> 00:03:41,130
+زوجمن الإلكترونات تكون أكسوجين ممكن تكون نيتروجين
+
+44
+00:03:41,130 --> 00:03:45,970
+ممكن تكون كاربون ممكن تكون سالفر ممكن تكون هالوجين
+
+45
+00:03:45,970 --> 00:03:53,990
+كلهم القاسم المشترك بينهم إيش وجود زوج الإلكترونات
+
+46
+00:03:53,990 --> 00:03:58,410
+واضح؟ ولذلك في النهاية الكيميا مرات كتيرة لما
+
+47
+00:03:58,410 --> 00:04:03,290
+الواحد بده يفهمها بلاحظ إنه كلما تعمق الإنسان في
+
+48
+00:04:03,290 --> 00:04:09,360
+فهم الكيميا بيرجع لإيش؟للإلكترونات لأن الإلكترونات
+
+49
+00:04:09,360 --> 00:04:13,580
+هي اللي بتعمل التفاعلات و الأشياء ولذلك لو يعني
+
+50
+00:04:13,580 --> 00:04:17,640
+شوية صغيرة بدنا نخرج على الموضوع لو كنت تستعرضه
+
+51
+00:04:17,640 --> 00:04:23,240
+تعريف مثلا الأحماض والقواعدأول ما بدوا يعرفوا
+
+52
+00:04:23,240 --> 00:04:27,020
+الحمض والقاعدة Arrhenius قال الحمض اللي بيعطي H
+
+53
+00:04:27,020 --> 00:04:32,100
+plus والقاعدة اللي بتعطي OH minus إجا بعد هيك
+
+54
+00:04:32,100 --> 00:04:35,060
+Laurie Bronsted قال الحمض اللي بيعطي H plus
+
+55
+00:04:35,060 --> 00:04:39,340
+والقاعدة اللي بتكتسب H plus خلاصني من مشكلة OH
+
+56
+00:04:39,340 --> 00:04:44,780
+minus إجا بعدين Lewis لما اتعمق أكتر إيش قال؟الحمض
+
+57
+00:04:44,780 --> 00:04:47,680
+اللي بيكتسب إلكترونات والقاعدة اللي بتعطي
+
+58
+00:04:47,680 --> 00:04:51,060
+إلكترونات فالعلم في قمة التطور وصل لوين؟
+
+59
+00:04:51,060 --> 00:04:55,360
+للإلكترونات فاللي بيفهم هذا القاسم المشترك بيصير
+
+60
+00:04:55,360 --> 00:04:59,240
+الموضوع سهل عليه يعني ممكن واحدة تنظر لجدول زي هذا
+
+61
+00:04:59,240 --> 00:05:04,730
+تقول شو هالمصيبة ويقطع الكيمياوحدة تانية بتقول كل
+
+62
+00:05:04,730 --> 00:05:09,090
+اللي موجود بالجدول هذا هو فكرة واحدة أن أي ذرة
+
+63
+00:05:09,090 --> 00:05:15,210
+عليها زوج من الإلكترونات بسمها نيوكليوفايل بييجي
+
+64
+00:05:15,210 --> 00:05:18,490
+هذا زوج الإلكترونات بيهجم على الكربون و بطرد ال X
+
+65
+00:05:18,490 --> 00:05:22,930
+مع زوج إلكتروناتها إذا هنا أنا صار عند المعادلة
+
+66
+00:05:22,930 --> 00:05:31,390
+العامة اللي هي لنيوكليوفايلمرات بيقولوا Z زوج
+
+67
+00:05:31,390 --> 00:05:35,530
+الإلكترونات كل الفكرة فيه زوج الإلكترونات زائد ال
+
+68
+00:05:35,530 --> 00:05:43,110
+R X ال X سالب ال R موجة وين بدو ييجي السالب هذا
+
+69
+00:05:43,110 --> 00:05:50,270
+بده ييجي هنا يهاجم ويطرد ال X مع الإلكترونات خلصنا
+
+70
+00:05:50,270 --> 00:05:55,260
+كل المعادلات اللي موجودةبتلخصوا بهذه المعادلة
+
+71
+00:05:55,260 --> 00:05:58,640
+العامة كل المعادلات اللي موجودة بيصير عندكم في
+
+72
+00:05:58,640 --> 00:06:06,040
+النهاية RZ زائد X minus واضح فشوفوا كيف لما يصير
+
+73
+00:06:06,040 --> 00:06:08,580
+عندكم قاعدة كلية بيبطل الواحد يخاف ان
+
+74
+00:06:08,580 --> 00:06:12,920
+النيكوليوفايل Oxygen نيتروجين واطبار مش مش المشكلة
+
+75
+00:06:12,920 --> 00:06:19,660
+واضح المهم في النيكوليوفايل وجود زوج الالكترونات
+
+76
+00:06:20,450 --> 00:06:25,590
+هذه ال slide أخدناها برضه إذا بتذكروا و بيكون
+
+77
+00:06:25,590 --> 00:06:29,590
+رجعنا كويس كل اللي أخدتهوا في المحاضرة الماضية أنه
+
+78
+00:06:29,590 --> 00:06:33,270
+لما كان عند ال enucleophile يكون مشحون زي OH-,
+
+79
+00:06:33,270 --> 00:06:41,160
+التفاعل ببساطة بتدخل OH-, تطلع PR-, خلصنالما يكون
+
+80
+00:06:41,160 --> 00:06:46,320
+الـ nucleophile متعدد تدخل الميّه و تصبح PR- بعد
+
+81
+00:06:46,320 --> 00:06:50,520
+ذلك هذا الميّه اللي دخلت هنا ماذا ستفقد؟ هيدروجين
+
+82
+00:06:50,520 --> 00:06:55,400
+هيدروجين عشان تصفؤه H واضح؟ عشان تصفؤه H
+
+83
+00:06:55,400 --> 00:06:59,600
+هالهيدروجين هذا اللي طلعت في الآخر مع ال PR- بتطلع
+
+84
+00:06:59,600 --> 00:07:05,120
+على شكل HBR الان لما أجينا نشرح ال mechanisms أو
+
+85
+00:07:05,120 --> 00:07:12,780
+قليات التفاعلقلنا إنه في عندنا إما ممكن نصنف SN1
+
+86
+00:07:12,780 --> 00:07:19,620
+ميكانيزم أو SN2 ميكانيزم ال SN1 حطنا لها شروط و
+
+87
+00:07:19,620 --> 00:07:26,260
+SN2 حطنا لها شروط شروط ال SN2 كانت عبارة عنstrong
+
+88
+00:07:26,260 --> 00:07:31,040
+nucleophile و primary alkyl halide يعني لما يكون
+
+89
+00:07:31,040 --> 00:07:34,360
+عندي strong nucleophile ال primary alkyl halide
+
+90
+00:07:34,360 --> 00:07:40,920
+غالبا بيصير ميكانيزم مكونة من جزئين يعني ال
+
+91
+00:07:40,920 --> 00:07:45,560
+nucleophile بيهاجم و بيبدأ يعمل رابطة ال PR بتبدأ
+
+92
+00:07:45,560 --> 00:07:48,880
+تنكسر بيصير عندى هذا ال transition state اللي
+
+93
+00:07:48,880 --> 00:07:54,880
+سمناهابـ Intervalent خمسية الإرتباط بعد ذلك يكتمل
+
+94
+00:07:54,880 --> 00:07:58,840
+تكوين هذا الرابط أو يكتمل كسر الـ PR minus طبعاً
+
+95
+00:07:58,840 --> 00:08:02,880
+بتلاحظوا أنه بسرعة ال inversion ولا لأ ال PR كانت
+
+96
+00:08:02,880 --> 00:08:07,700
+باتجاه الـ nucleophile جاء بالاتجاه المعاكس إيش
+
+97
+00:08:07,700 --> 00:08:12,380
+اللي بيسمح لل nucleophile أنه يهاجم Hannah بسهولة؟
+
+98
+00:08:12,880 --> 00:08:17,200
+ووجود وسع انه هذه ال carbon تكون primary لو كان ال
+
+99
+00:08:17,200 --> 00:08:22,580
+tertiary الوسع مغلق مافيش مكان يدخل ال nucleophile
+
+100
+00:08:22,580 --> 00:08:27,360
+من خلاله فأفضل شئ لهذه ال mechanism انه يكون هذا
+
+101
+00:08:27,360 --> 00:08:31,400
+ال nucleophile strong ويلاجى وسع يلاجى primary
+
+102
+00:08:31,400 --> 00:08:33,020
+carbon
+
+103
+00:08:34,870 --> 00:08:39,270
+أعملنا ملحنة طاقة للتفاعل هذه المتفاعلات لـ
+
+104
+00:08:39,270 --> 00:08:42,270
+Transition State Intervalent دائما لـ Transition
+
+105
+00:08:42,270 --> 00:08:49,010
+State الطاقة تبعتها أعلى من ال reactants و ال
+
+106
+00:08:49,010 --> 00:08:53,190
+products بعد ذلك لما تفقد ال PR بيكتمل هنا تكوين
+
+107
+00:08:53,190 --> 00:08:58,310
+الرابطة تكوين الرابطة بيفقد من خلاله طاقة فبينزل
+
+108
+00:08:58,310 --> 00:09:02,030
+التفاعلسواء كان exothermic أو endothermic مش مشكلة
+
+109
+00:09:02,030 --> 00:09:07,610
+كل هذا الكلام تقريبا شرحناه هذه ال slide اللي
+
+110
+00:09:07,610 --> 00:09:11,930
+موجودة عندنا ربما أضفناها مافيش فيها أي إشي غير
+
+111
+00:09:11,930 --> 00:09:17,680
+التأكيد على فكرة أنه لما يكون عندهprimary
+
+112
+00:09:17,680 --> 00:09:23,220
+الكلهيلايد هجوم لليوكليوفايل اللي هنا بين Z مرسوم
+
+113
+00:09:23,220 --> 00:09:27,900
+بالأزرق بيكون أسهل يعني أبسط مثال لو كان عندى مثل
+
+114
+00:09:27,900 --> 00:09:32,080
+برمايد مثلا حيكون عندى اتش و اتش و اتش لاحظوا ال
+
+115
+00:09:32,080 --> 00:09:37,280
+hydrogens ايش حجمهم صغير ففي وسع لل Z تيجي من هنا
+
+116
+00:09:37,280 --> 00:09:41,200
+وهذه تبدأ تطلع فصار في احتمال ان يكون هنا عندى خمس
+
+117
+00:09:41,200 --> 00:09:47,700
+روابطبسهولة في ال transition state طبعا لو صار
+
+118
+00:09:47,700 --> 00:09:52,600
+عندى primary بدى يكون عندى ارتباط مع carbon واحدة
+
+119
+00:09:52,600 --> 00:09:56,720
+برضه ما زال عندى two hydrogens و ال two hydrogens
+
+120
+00:09:56,720 --> 00:10:00,880
+ايش بيكونوا صغار الان لو صار secondary هي
+
+121
+00:10:00,880 --> 00:10:05,080
+secondary هي مرتبطة ب two carbons بدأ يكبر الحجم
+
+122
+00:10:05,080 --> 00:10:09,300
+اللى هنا بتبدأ الزد يصير حواليها ايش نوع من
+
+123
+00:10:09,300 --> 00:10:14,250
+الصعوبة لو صار tertiaryهذه ال carbon بيصير حواليها
+
+124
+00:10:14,250 --> 00:10:18,050
+مثل و مثل و مثل طبعا انتوا تخيلوا هدولة تلت طبب
+
+125
+00:10:18,050 --> 00:10:23,590
+لكبار و كل مثل طالع منها اتش و اتش و اتش و اتش و
+
+126
+00:10:23,590 --> 00:10:27,510
+اتش و اتش يعني لو بدكم تتخيلوها ان هذي carbon
+
+127
+00:10:27,510 --> 00:10:29,990
+هيطلع اتش وكمان اتش وكمان اتش وكمان اتش وكمان اتش
+
+128
+00:10:29,990 --> 00:10:30,610
+وكمان اتش وكمان اتش وكمان اتش وكمان اتش وكمان اتش
+
+129
+00:10:30,610 --> 00:10:34,110
+وكمان اتش وكمان اتش وكمان اتش وكمان اتش وكمان اتش
+
+130
+00:10:34,110 --> 00:10:35,470
+وكمان اتش وكمان اتش وكمان اتش وكمان اتش وكمان اتش
+
+131
+00:10:35,470 --> 00:10:38,900
+وكمان اتش وكمانفعشان هيك ال S and two reactions
+
+132
+00:10:38,900 --> 00:10:44,600
+مابتصيرش مع ال tertiary السبب هنا بنسميه steric
+
+133
+00:10:44,600 --> 00:10:50,360
+factor، steric يعني متعلق بعمل إيش لاستحام، إنه
+
+134
+00:10:50,360 --> 00:10:57,050
+مافيش وسع، steric factorماشي عن hysteric factor
+
+135
+00:10:57,050 --> 00:11:03,050
+سبب متعلق بعمل الازدحام انه مفيش او مرات بيسموه
+
+136
+00:11:03,050 --> 00:11:08,410
+hysteric hindrance اش يعني hindrance ممانعة انه
+
+137
+00:11:08,410 --> 00:11:13,250
+مافيش وسع انه يجي يتفاعل واضح فلما نقول ليش افضل
+
+138
+00:11:13,250 --> 00:11:19,690
+اشي الاسئن to reaction مع ال primary الجواب بنقول
+
+139
+00:11:19,690 --> 00:11:22,750
+due to hysteric factor
+
+140
+00:11:25,410 --> 00:11:29,770
+يعني لو بدى أجيبلكوا سؤال صح و غلط في الامتحان
+
+141
+00:11:29,770 --> 00:11:35,730
+أقولكم الله أسئلتو reactions occurs with the
+
+142
+00:11:35,730 --> 00:11:40,110
+primary alkyl halides due to electronic factors
+
+143
+00:11:40,110 --> 00:11:45,450
+أسباب تتعلق بالإلكترونات وش .. لأ due to steric
+
+144
+00:11:45,450 --> 00:11:50,290
+factor أسباب تتعلق بالفراغ بالوسع واضحة النقطة
+
+145
+00:11:50,290 --> 00:11:51,310
+هذه؟ أه
+
+146
+00:11:55,600 --> 00:12:00,380
+الان بنبدأ في الدارس الجديد اللى بنكمل فيه اليوم
+
+147
+00:12:00,380 --> 00:12:05,860
+اللى هو لو كان عندى tertiary alkalites هانا بصير
+
+148
+00:12:05,860 --> 00:12:13,000
+بحكي عن ميكانيزم جديدة اللى بنسميها ايش S-N-1
+
+149
+00:12:13,000 --> 00:12:17,520
+والان بنشوف ليش بنسميها S-N-1 في ال tertiary
+
+150
+00:12:17,520 --> 00:12:22,860
+alkalites اخر شغلة قبل شوية حكيناها احنا ان ال
+
+151
+00:12:22,860 --> 00:12:29,800
+tertiary صعب يصيرمع الـ SN2 لأنه مافيش شيء وسع
+
+152
+00:12:29,800 --> 00:12:34,820
+لأنه في اندستيرك فاكتر بناء على ذلك لما بيكون عنده
+
+153
+00:12:34,820 --> 00:12:38,660
+tertiary alkyl halide زي هذا المركب اللي هو
+
+154
+00:12:38,660 --> 00:12:44,500
+tertiary butyl bromide شايفينه؟ ويكون بالذات كمان
+
+155
+00:12:44,500 --> 00:12:48,860
+ال nucleophile اضعيف يعني مش قادر يهاجم ولا له
+
+156
+00:12:48,860 --> 00:12:54,300
+وسعي يهاجمماذا سيحصل؟ الـ Nucleophile سيفعل الحياد
+
+157
+00:12:54,300 --> 00:13:00,920
+يستنى لحد ما تطلع ال PR مع إلكتروناتها يعني اللي
+
+158
+00:13:00,920 --> 00:13:03,760
+بيصير أنه بدأ تطلع ال PR مع إلكتروناتها طيب لما
+
+159
+00:13:03,760 --> 00:13:09,240
+تطلع ال PR مع إلكتروناتها بيصير وسعبالتأكيد،
+
+160
+00:13:09,240 --> 00:13:12,700
+بالتأكيد بيصير واسع لإن أنا هنا كان عندي حوالين ال
+
+161
+00:13:12,700 --> 00:13:18,200
+carbon أربع مجموعات بيصير حوالين ال carbon تلت
+
+162
+00:13:18,200 --> 00:13:22,560
+مجموعات، إذا صار في عندي وسع يعني لو تخيلنا مثلا
+
+163
+00:13:22,560 --> 00:13:30,680
+إن هذه هي ال carbon المعنية هذه تلت ذرات carbon،
+
+164
+00:13:30,680 --> 00:13:34,560
+شايفينهم؟ نعمل كل الروابط باللون الأصفر
+
+165
+00:13:38,620 --> 00:13:42,240
+هذا هو الكاربو كاتيون اللي بيطلع عندى، طلعوا
+
+166
+00:13:42,240 --> 00:13:46,580
+معايا، هدولة صاروا في مستوى واحد، صار عندى فراغ من
+
+167
+00:13:46,580 --> 00:13:50,420
+هنا و من هنا لأي مجموعة من الخارج بدأ تيجي تهاجم
+
+168
+00:13:51,090 --> 00:13:57,110
+إنها تيجي تتفاعل، واضح؟ إذا هانا كخطوة أولى لإنه
+
+169
+00:13:57,110 --> 00:14:03,010
+عندي تلت مجموعات مثل اكبار اللي بيصير انه بتطلع ال
+
+170
+00:14:03,010 --> 00:14:06,130
+halogen atom لما تطلع ال halogen atom مع
+
+171
+00:14:06,130 --> 00:14:10,750
+إلكتروناتها، شو بده تترك مكانها؟الـ positive هذا
+
+172
+00:14:10,750 --> 00:14:17,030
+على الكربون شو بنسميه كربو كتاين ايون كربون موجر
+
+173
+00:14:17,030 --> 00:14:23,410
+هذا الكربو كتاين هذا الكربو كتاين كيف شكله بلانر
+
+174
+00:14:23,410 --> 00:14:29,470
+بلانر ملاحظين انتوا و بناء على ان هذا الكربو كتاين
+
+175
+00:14:29,470 --> 00:14:34,370
+اللي عند انا بلانر لما بدى تيجي النيوكليوفايل او
+
+176
+00:14:34,370 --> 00:14:39,630
+يجي النيوكليوفايل يهاجم عليهبيقدر يهاجم منها أنا
+
+177
+00:14:39,630 --> 00:14:43,870
+وبيقدر يهاجم منها أنا، إذا الهجوم يتم من جهة ولا
+
+178
+00:14:43,870 --> 00:14:49,490
+من جهتين؟ من جهتين طبعا بيكون في اعتباركوا أنه
+
+179
+00:14:49,490 --> 00:14:55,410
+مابيطلعوش هدول الجهتين متساويتين الهجوم عليهم، ليش
+
+180
+00:14:55,410 --> 00:15:00,760
+مابيطلعوش متساويتين؟لأنه انا لو افترضت ان عندي هذه
+
+181
+00:15:00,760 --> 00:15:05,980
+ذرة و قاعدة بتنكسر و انكسرت و صار عندي زي هذا و
+
+182
+00:15:05,980 --> 00:15:10,440
+لسه قاعدة بتبعد، شايفين المنظر؟ يعني لما كانوا
+
+183
+00:15:10,440 --> 00:15:15,100
+أربعة كانوا بهذا الشكل، الآن هذه انكسرت و قاعدة
+
+184
+00:15:15,100 --> 00:15:20,820
+بتبعد و هذا صار بلا نار، لكن مازالت موجودة إجريب
+
+185
+00:15:21,710 --> 00:15:26,170
+وين الاحتمال اسهل؟ رغم ان هذا الاحتمال انفتح و هذا
+
+186
+00:15:26,170 --> 00:15:31,650
+الاحتمال انفتح لكن هذه ما زالت نوعا ما جريبة فبناء
+
+187
+00:15:31,650 --> 00:15:37,190
+على ذلك لو كان في احتمال نفترض 60% او 70% ييجي من
+
+188
+00:15:37,190 --> 00:15:43,130
+العكس بكل احتمال 30% او 40% انه ييجي من مكان خروج
+
+189
+00:15:43,130 --> 00:15:48,520
+هذهإيش السبب؟ إن هذه ما زالت موجودة، يعني أنا
+
+190
+00:15:48,520 --> 00:15:52,380
+أتخيلها هنا، لو ذرة جاية من هنا، ممكن تخبط فيها؟
+
+191
+00:15:52,380 --> 00:15:58,580
+ممكن، من هنا، اتجوزتها، ولذلك صح بيصير التفاعل من
+
+192
+00:15:58,580 --> 00:16:04,260
+الجهتين، لكن من أي جهة بيصير أكتر؟ من الجهة
+
+193
+00:16:04,260 --> 00:16:09,620
+المعاكسة أكتر، السبب إن هذه ما زالت لسه قريبة،
+
+194
+00:16:09,620 --> 00:16:16,110
+يعني ماصارش الوضع بهذا الشكل تماماًطلعوا كيف؟ هذه
+
+195
+00:16:16,110 --> 00:16:21,030
+طلعت و ما زالت قريبة، الآن من وين؟ الأفضل أنه يتم
+
+196
+00:16:21,030 --> 00:16:24,270
+التفاعل من الجهة المفتوحة، لكن هذه الجهة برضه إيش
+
+197
+00:16:24,270 --> 00:16:28,330
+مالها؟ مفتوحة، ولذلك احنا بنقول أن التفاعل بيتم صح
+
+198
+00:16:28,330 --> 00:16:34,700
+من الجهتين، لكنwith more inversion عشان هيك لما
+
+199
+00:16:34,700 --> 00:16:39,020
+بيجوا بيحكوا عن هذا التفاعل كيف النيوكليوفال بده
+
+200
+00:16:39,020 --> 00:16:43,900
+ييجي بيقولوا بيصير عند راسيمايزيشن راسيمايزيشن
+
+201
+00:16:43,900 --> 00:16:47,520
+معناه أنه يتم التفاعل من الجهتين with more
+
+202
+00:16:47,520 --> 00:16:52,980
+inversion يعني نفترض 70% inversion 30% من نفس
+
+203
+00:16:52,980 --> 00:16:56,820
+الاتجاه واضح فال stereo chemistry هانا إيش بنقول
+
+204
+00:16:56,820 --> 00:17:02,280
+عنهاracimization لكن هل يا تورا هو complete
+
+205
+00:17:02,280 --> 00:17:06,700
+racimization؟ complete racimization يعني خمسين في
+
+206
+00:17:06,700 --> 00:17:12,960
+المية خمسين في المية الواقع لأ racimization with
+
+207
+00:17:12,960 --> 00:17:22,300
+اش more inversion ليش more inversion؟ because
+
+208
+00:17:22,300 --> 00:17:25,880
+of the presence of the living group
+
+209
+00:17:32,840 --> 00:17:37,920
+السبب هو وجود المجموعة المغادرة، و لو بعددها عشرين
+
+210
+00:17:37,920 --> 00:17:43,020
+كيلوولو بعدت الى عشرين كيلو، لكن بيظل انه ممكن
+
+211
+00:17:43,020 --> 00:17:46,780
+تيجي منها وممكن منها، لكن من وين الأسهل؟ من الجهة
+
+212
+00:17:46,780 --> 00:17:51,060
+اللي فاضية مية في المية، بتشوفوا الآن المعارك على
+
+213
+00:17:51,060 --> 00:17:55,380
+التلفزيون ولا لأ؟ الجيش اللي طالع، الناس بفضله
+
+214
+00:17:55,380 --> 00:17:59,920
+ييجوا من منطقته ولا بييجوا بالعكس تماما، ولو هو
+
+215
+00:17:59,920 --> 00:18:06,020
+بعيد، لكن ما زالت آثارهموجودة، واضح؟ إذا بيصير
+
+216
+00:18:06,020 --> 00:18:10,740
+عندك Rassimization with more inversion والسبب due
+
+217
+00:18:10,740 --> 00:18:14,620
+to the presence of the leaving group in the nearby
+
+218
+00:18:14,620 --> 00:18:20,700
+space في الفراغ القريب ما زالت ال leaving group
+
+219
+00:18:20,700 --> 00:18:26,940
+موجودة واضح هذا الكلام؟ الآن لو بدنا نتعمق بهذه ال
+
+220
+00:18:26,940 --> 00:18:34,540
+mechanism هلاحظ أن هذه ال mechanism كام خطوةخطوتين
+
+221
+00:18:34,540 --> 00:18:41,440
+هذه الخطوة الأولى وهذه الخطوة الثانية الخطوة
+
+222
+00:18:41,440 --> 00:18:47,340
+الأولى كسر الهالوجين بوند لتكوين بلانر كاربو كتاين
+
+223
+00:18:47,340 --> 00:18:53,760
+موجب والخطوة الثانية اتكون و خلص بيجي ال
+
+224
+00:18:53,760 --> 00:19:01,300
+نيوكليوفايل يتفاعل ويعطيني ال الكلهيلايتأيهما
+
+225
+00:19:01,300 --> 00:19:06,200
+أصعب؟ الخطوة الأولى ولا الخطوة الثانية؟ الخطوة
+
+226
+00:19:06,200 --> 00:19:11,240
+الأولى .. مش دايما .. الخطوة الأولى هنا على أقل
+
+227
+00:19:11,240 --> 00:19:19,550
+تقدير أصعب .. ليش؟لأنه انا .. انتبهوا معي بلغة
+
+228
+00:19:19,550 --> 00:19:25,750
+الشحنات في الخطوة الأولى .. في الخطوة الأولى قاعد
+
+229
+00:19:25,750 --> 00:19:31,390
+بافصل موجب عن سالب امسكوا موجب و سالب و افصلوهم عن
+
+230
+00:19:31,390 --> 00:19:37,110
+بعض ايش بدكم؟ energy في الخطوة الثانية قاعد بجيب
+
+231
+00:19:37,110 --> 00:19:43,620
+سالب على موجبداعمًا الـ revulsion هذا والـ
+
+232
+00:19:43,620 --> 00:19:47,900
+separation of positive and negative charges، it
+
+233
+00:19:47,900 --> 00:19:51,840
+needs energy، اللي بيفصل مغناطسين و لا شحنتين
+
+234
+00:19:51,840 --> 00:19:57,400
+متجاذبتين، بده طاقة، و اللي بيمسك مغناطسين شمالي
+
+235
+00:19:57,400 --> 00:20:01,000
+وجنوبي و بجربهم مع بعض، هم بتجربوا قبل ما إيده
+
+236
+00:20:01,000 --> 00:20:05,320
+تيجي، هم بصحبوله إيده، مظبوط ولا لأ؟صح ولا لأ؟
+
+237
+00:20:05,320 --> 00:20:08,900
+عشان هيك لما بيكون عندنا يعني عفوا في المشاكل
+
+238
+00:20:08,900 --> 00:20:13,680
+العائلية لما يصير و بدهم يفصلوا الولد عن أمه
+
+239
+00:20:13,680 --> 00:20:19,320
+بتحسوا كيف بيجيبوا المنظر و هم قاعدين بيفصلوه و ما
+
+240
+00:20:19,320 --> 00:20:24,540
+إلى ذلك وبصعوبة و في آخر الفيلم لما يجيبولكم أن
+
+241
+00:20:24,540 --> 00:20:30,940
+الولد رجع لأمه بيدي جراي ملاحظين أنتوا كيف؟ هنا
+
+242
+00:20:30,940 --> 00:20:36,140
+نفس الاشي أنا بفصل موجب عن سالبواضح وبالتالي بحتاج
+
+243
+00:20:36,140 --> 00:20:41,000
+طاقة ولذلك هذه الخطوة هي الخطوة الصعبة هي الخطوة
+
+244
+00:20:41,000 --> 00:20:46,060
+الصعبة خطوة خروج ال PR minus ونفس الاشي كان عندنا
+
+245
+00:20:46,060 --> 00:20:49,740
+نبقى نحكي على الواقع تباعنا لما اليهود طلعوا من
+
+246
+00:20:49,740 --> 00:20:54,760
+غزة كان طلوعهم من المستوطنات الخطوة الصعبة هذا
+
+247
+00:20:54,760 --> 00:21:04,190
+الطلوع أخد من سنة 67 ل 2005 اه 38 سنةطيب بعد ما
+
+248
+00:21:04,190 --> 00:21:10,910
+طلعوا قداش لزم للناس عشان يدخلوا المستوطنات؟ عشر
+
+249
+00:21:10,910 --> 00:21:14,530
+ثواني يعني هم كانوا ماعدهم يطلعوا ع ال 12 في الليل
+
+250
+00:21:14,530 --> 00:21:17,770
+واحد زميل بيكلمنا 12 و 5 بيقول أنا في المستوطنة
+
+251
+00:21:18,600 --> 00:21:22,740
+الملاحظين انتوا الخطوة الصعبة و السهلة هذا جزء من
+
+252
+00:21:22,740 --> 00:21:28,480
+الكيميا ان احنا بنقول هذه slow step و هذه fast
+
+253
+00:21:28,480 --> 00:21:33,320
+step اذا انا امام two steps واحدة منهم slow واحدة
+
+254
+00:21:33,320 --> 00:21:39,200
+منهم fastfast لما انا اسألكوا ال first step in SN1
+
+255
+00:21:39,200 --> 00:21:44,580
+reactions is a fast step it is the slow step و ال
+
+256
+00:21:44,580 --> 00:21:48,620
+second step fast step الان ال slow step بيعطوها
+
+257
+00:21:48,620 --> 00:21:52,680
+اسم بيقولوا عنها ال rate determining step هي
+
+258
+00:21:52,680 --> 00:21:58,820
+الخطوة المحددة لسرعة التفاعلكل الموضوع بيعتمد
+
+259
+00:21:58,820 --> 00:22:05,240
+عليها الخطوة التانية إيش بنسميها تحصيل حاصل، واضح؟
+
+260
+00:22:05,240 --> 00:22:10,580
+إذا هذه ال slow step هي إيش بنسميها إحنا كمان rate
+
+261
+00:22:10,580 --> 00:22:18,500
+determining step يعني هي الخطوة المحددة لسرعة
+
+262
+00:22:18,500 --> 00:22:25,080
+التفاعلواضح؟ انتوا ممكن شوية ماوعتوش الحواجز اللي
+
+263
+00:22:25,080 --> 00:22:28,660
+كانت ع طريق غزة خانيونس و اللي مازالت موجودة في
+
+264
+00:22:28,660 --> 00:22:32,700
+الضفة لما واحد الان بدو يطلع ما بين مدينتين في
+
+265
+00:22:32,700 --> 00:22:38,260
+عندهم حاجز بيكلم جماعة و أنا جاي ان شاء الله ..
+
+266
+00:22:38,260 --> 00:22:43,830
+واضح؟ليش؟ وين عنده الخطوة الصعبة؟ لحد ما يقطع
+
+267
+00:22:43,830 --> 00:22:47,670
+الحاجز، بعد ما يقطع الحاجز، لو بده يكلم البيت،
+
+268
+00:22:47,670 --> 00:22:52,450
+بيكلمهم، بيقولهم جهزوا الأكل، أنا وصلت خلاص ضمن ..
+
+269
+00:22:52,450 --> 00:22:58,030
+قطع الحاجز هو الخطوة إيش؟ الصعبة، بعد هيك الخطوة
+
+270
+00:22:58,030 --> 00:23:02,930
+التانية هي خطوة إيش مالها سهلة، واضح؟ الآن لاحظوا
+
+271
+00:23:02,930 --> 00:23:06,970
+مع الخطوة الصعبة هذه اعتمدت على متفاعل ولا
+
+272
+00:23:06,970 --> 00:23:11,830
+متفاعلين؟متفاعل، إيش شايفين فيها انتوا بس؟
+
+273
+00:23:11,830 --> 00:23:17,230
+الكلهيلايت، ال nucleophile إيش ماله؟ أضعيف، قاعد
+
+274
+00:23:17,230 --> 00:23:21,250
+باستنى، زي أحوالنا، ال nucleophile أضعيف، ولذلك
+
+275
+00:23:21,250 --> 00:23:26,870
+هنا سرقة التفاعل كلها بتعتمد على إيش؟على متفاعل
+
+276
+00:23:26,870 --> 00:23:32,170
+واحد مش على متفاعلين ولذلك هذي الميكانيزم بيسموها
+
+277
+00:23:32,170 --> 00:23:37,790
+substitution in nucleophilic unimolecular يعني
+
+278
+00:23:37,790 --> 00:23:42,790
+بتعتمد على متفاعل واحد اللي هو ال R X مش على
+
+279
+00:23:42,790 --> 00:23:47,810
+متفاعلين واضح؟ فلو أنا بدي أحط ال rate of this
+
+280
+00:23:47,810 --> 00:23:56,960
+reaction شو بتساوي ال rate؟ K في التركيزالـ RX هل
+
+281
+00:23:56,960 --> 00:24:01,600
+بيظهر عند النيكليوفايل؟ لأ قبل شوية لما كنا نحكي
+
+282
+00:24:01,600 --> 00:24:06,840
+SN2 إيش كنا نقول ال rate؟ rate بتساوي كيف؟ RX في
+
+283
+00:24:06,840 --> 00:24:11,100
+نيكليوفايل كانوا التنين بيتصارعوا هنا بس التفاعل
+
+284
+00:24:11,100 --> 00:24:17,240
+معتمد على ال RX ولذلك اسمها substitution in
+
+285
+00:24:17,240 --> 00:24:21,830
+nucleophilic unimolecularإذن لو أنا بدأتش أسألكوا
+
+286
+00:24:21,830 --> 00:24:24,310
+the rate of S and 1 reactions depends on the
+
+287
+00:24:24,310 --> 00:24:29,050
+concentration of nucleophile and RX لأ it depends
+
+288
+00:24:29,050 --> 00:24:32,990
+on the concentration of RX ماشي لو بدنا نسألها
+
+289
+00:24:32,990 --> 00:24:37,530
+بطريقة تانية S and 1 reactions are first order
+
+290
+00:24:37,530 --> 00:24:42,810
+reactions first order معتمدين على ال RX و ال RX ال
+
+291
+00:24:42,810 --> 00:24:49,270
+factor تبعها واحد بينما ال S and 2 they areSecond
+
+292
+00:24:49,270 --> 00:24:54,490
+order reactions أو لو بدنا نسألهم، بيعتمدوا على
+
+293
+00:24:54,490 --> 00:25:01,490
+تركيز أيش؟ المتفاعلين الـ RX و النيوكليوفايل واضح؟
+
+294
+00:25:01,490 --> 00:25:08,290
+طبعا احنا دائما بنهتم بالخطوة الاشاللي هي البطيئة
+
+295
+00:25:08,290 --> 00:25:12,670
+ال slow step الخطوة التانية تحصيل حاصل الان لاحظوا
+
+296
+00:25:12,670 --> 00:25:17,710
+معي ان انتوا هنا أخدتوا معلومات كتيرة متعلقة بال
+
+297
+00:25:17,710 --> 00:25:22,790
+SN1 reactions بتذكروا المرة الماضية أعطيناكم ال
+
+298
+00:25:22,790 --> 00:25:29,250
+SN2 reactions و أعطيناكم عليها شوية أشياء الان لما
+
+299
+00:25:29,250 --> 00:25:34,550
+بدي أجي SN1 reactions و أبدأ أذكركم أفضل إشي بتمشي
+
+300
+00:25:34,550 --> 00:25:34,950
+معه
+
+301
+00:25:37,940 --> 00:25:43,560
+أسانوان reactions ال tertiary أفضل من ال secondary
+
+302
+00:25:43,560 --> 00:25:46,820
+أفضل من ال primary حتى ال primary ما بيصيرش نمرة
+
+303
+00:25:46,820 --> 00:25:53,300
+تانية بتفضل ال weak ال nucleophile نمرة تلاتة one
+
+304
+00:25:53,300 --> 00:25:58,380
+or two steps two steps و بتكون تعرفوا أنية السريعة
+
+305
+00:25:58,380 --> 00:26:06,300
+فيهم التانية البطيقة الأولى نمرة أربع بتكون فيها
+
+306
+00:26:08,880 --> 00:26:12,020
+الكاربو كاتيون هنا بنسمي الكاربو كاتيون
+
+307
+00:26:12,020 --> 00:26:17,080
+intermediate مش transition state لترانزيشن state
+
+308
+00:26:17,080 --> 00:26:20,160
+أثناء تكون intermediate يعني بين هذا و هذا في
+
+309
+00:26:20,160 --> 00:26:23,540
+transition state و بين هذه و هذه في transition
+
+310
+00:26:23,540 --> 00:26:29,240
+state واضح؟ بس هذا الكاربو كاتيون شو بنسميه احنا؟
+
+311
+00:26:29,240 --> 00:26:34,660
+intermediate الكائنة
+
+312
+00:26:36,860 --> 00:26:40,840
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+313
+00:26:40,840 --> 00:26:41,080
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+314
+00:26:41,080 --> 00:26:41,080
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+315
+00:26:41,080 --> 00:26:41,120
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+316
+00:26:41,120 --> 00:26:41,120
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+317
+00:26:41,120 --> 00:26:41,320
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+318
+00:26:41,320 --> 00:26:41,560
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+319
+00:26:41,560 --> 00:26:51,280
+أولا أو ثانوية؟ أولا أو ثانوية؟ أولا أو ثانوية؟
+
+320
+00:26:51,280 --> 00:27:02,860
+أولا أو
+
+321
+00:27:02,860 --> 00:27:10,630
+ثانويةب S and 1 طبعا ممكن هنا يجيني سؤال طب لو
+
+322
+00:27:10,630 --> 00:27:18,430
+عندي secondary ال secondary بين بين ال secondary
+
+323
+00:27:18,430 --> 00:27:24,710
+مع ال strong ال nucleophile شو هيمشي؟ S and 2 و ال
+
+324
+00:27:24,710 --> 00:27:29,570
+secondary مع ال weak بيمشي ب S and 1 واضح؟
+
+325
+00:27:32,690 --> 00:27:38,230
+هذا منحنى هذا منحنى للتفاعل الآن دائما اهتموا
+
+326
+00:27:38,230 --> 00:27:43,990
+بالمقارنات يعني لما بتدرسوا احنا قبل شوية رسمنالكم
+
+327
+00:27:43,990 --> 00:27:49,950
+منحنى لل SN2 reaction ايش كانت ميزة منحنى ال SN2
+
+328
+00:27:49,950 --> 00:27:55,910
+دائما منحنى الطاقة لتفاعل معين منحنى الطاقة لأي
+
+329
+00:27:55,910 --> 00:27:59,930
+تفاعل في عندي reactants ال transition state بتعلق
+
+330
+00:27:59,930 --> 00:28:07,200
+product فكلبيك زي هذه بلغة المنحنيات تمثل إيش step
+
+331
+00:28:07,200 --> 00:28:12,300
+أو خطوة بناء على ذلك لما أنا هنا باجي بقى أطلع على
+
+332
+00:28:12,300 --> 00:28:17,960
+هذا التفاعل أكم step؟ one step reactants؟ ال
+
+333
+00:28:17,960 --> 00:28:21,840
+transition state of products الآن لما بدي أجي أرسم
+
+334
+00:28:21,840 --> 00:28:28,040
+منحنى لأسئلة one reaction شو بتكون تتوقعوا يكون
+
+335
+00:28:28,040 --> 00:28:32,560
+عنده؟بدي أصير عندي two steps مش one step يعني
+
+336
+00:28:32,560 --> 00:28:38,000
+الملحنة مرتين قمتين لكن لو بدنا نيجي نسأل أي قمة
+
+337
+00:28:38,000 --> 00:28:42,200
+يا تورا اللي بده تكون الأعلى و الأصعب أي قمة
+
+338
+00:28:42,200 --> 00:28:46,920
+الأعلى و الأصعب الأولى عشان هيك انتوا تطلعوا معنا
+
+339
+00:28:46,920 --> 00:28:51,360
+لما تشوفوا هي عندكم reactants وهي ال transition
+
+340
+00:28:51,360 --> 00:28:56,520
+state اللي هو ال carbocation هنا لو بتشوفوا ال
+
+341
+00:28:56,520 --> 00:29:03,330
+transition state الأولى كدهكبيرة جدا يعني بدو يقفز
+
+342
+00:29:03,330 --> 00:29:06,970
+قفزة كبيرة جدا الان هذا الكربوكاتين بعد هيك لما
+
+343
+00:29:06,970 --> 00:29:11,550
+بدو يتفاعل ويعطينا ال product النهائي هنا ماخد
+
+344
+00:29:11,550 --> 00:29:17,650
+تفاعل الماءمع الـ .. هو الـ tertiary-butyl bromide
+
+345
+00:29:17,650 --> 00:29:21,370
+الـ reactant هو tertiary-butyl bromide هنا بيعطينا
+
+346
+00:29:21,370 --> 00:29:24,490
+الـ carbocation لحاله نفس المعادلة اللي انتوا
+
+347
+00:29:24,490 --> 00:29:29,270
+شوفتوها بعدين بيجي ال PR .. زاد ال PR minus بتيجي
+
+348
+00:29:29,270 --> 00:29:35,190
+الميه تتفاعل بضيف OH2 plus وبعدين بتفقد ال H plus
+
+349
+00:29:35,190 --> 00:29:39,670
+الان فقد ال H plus موضوع بسيط مش موضوعنا لكن هنا
+
+350
+00:29:39,670 --> 00:29:44,060
+لما ابدا اطلع كام خطوة هذا التفاعلخطوة تانية هي
+
+351
+00:29:44,060 --> 00:29:48,700
+الخطوة الأولى طلع معي reactant transition state ل
+
+352
+00:29:48,700 --> 00:29:50,960
+product ال carbocation الخطوة التانية ال
+
+353
+00:29:50,960 --> 00:29:57,230
+carbocation مع الميههذه الخطوة التانية البعض يشوف
+
+354
+00:29:57,230 --> 00:29:59,610
+الخطوة التالتة الخطوة التالتة ليست أساسية في
+
+355
+00:29:59,610 --> 00:30:03,330
+الميكانيزم الخطوة التالتة ان المياه تدخل مع
+
+356
+00:30:03,330 --> 00:30:08,230
+البروتن ويفقد البروتن منها تدخل OH2 ويفقد ال OH
+
+357
+00:30:08,230 --> 00:30:14,210
+لكن كميكانيزم أساسي كم خطوة التفاعل؟ خطوتين واضح؟
+
+358
+00:30:14,210 --> 00:30:18,390
+دائما نقول ال reaction is a two step
+
+359
+00:30:25,980 --> 00:30:33,100
+أيهم أصعب؟ هذه القفزة أو هذه القفزة؟ هذه الصعوبة
+
+360
+00:30:33,100 --> 00:30:39,840
+التي هي ال activation energyالفرق ما بين ال
+
+361
+00:30:39,840 --> 00:30:43,080
+transition state و ال reactant اي activation هنا
+
+362
+00:30:43,080 --> 00:30:47,520
+عالي اي activation هنا قليل جدا و لذلك ال first
+
+363
+00:30:47,520 --> 00:30:52,180
+step is the difficult step لازم يكون عندكم فهم
+
+364
+00:30:52,180 --> 00:30:57,280
+لطريقة رسم المنحنيات يعني هذا المنحنى مجرد ما
+
+365
+00:30:57,280 --> 00:31:01,780
+تشوفوه يقول لطالبة منكوا اتفضلي اشرحيلنا ماذا يعني
+
+366
+00:31:01,780 --> 00:31:06,820
+هذا المنحنى لو رسلنا لحدين هتقول هذا منحنى تفاعل
+
+367
+00:31:06,820 --> 00:31:13,370
+من خطوتينهي خطوة؟ هى خطوة الخطوة الأولى صعبة
+
+368
+00:31:13,370 --> 00:31:18,470
+والخطوة الثانية سهلة والتفاعل بمجمله اذا شوفت هى
+
+369
+00:31:18,470 --> 00:31:21,710
+ال reactants وهى ال final products اكزو ثرميك ولا
+
+370
+00:31:21,710 --> 00:31:32,670
+اندو ثرميك هى ال reactant الأصلى فقط
+
+371
+00:31:32,670 --> 00:31:39,540
+طاقة طاقة النواتج اقل اذا فقدت طاقةهذا Exothermic
+
+372
+00:31:39,540 --> 00:31:46,990
+بامتيازدائما التفاعل لما بيكونوا ال products أقل
+
+373
+00:31:46,990 --> 00:31:51,190
+من ال reactants في الطاقة، شو بيكون؟ Exothermic،
+
+374
+00:31:51,190 --> 00:31:55,350
+نرجع للتفاعل تبع قبل شوية، المنحنة الواحد، هذا
+
+375
+00:31:55,350 --> 00:31:59,250
+المنحنة Exo ولا Endothermic؟ Exothermic،
+
+376
+00:31:59,250 --> 00:32:03,750
+Exothermic، كانت نفترض طاقة ال reactants خلينا
+
+377
+00:32:03,750 --> 00:32:09,310
+تجاوزا، نقول رقم عشرة، عشرة مثلا، تجاوزا، مع العلم
+
+378
+00:32:09,310 --> 00:32:16,120
+الطاقة لا تحددصارت ستة تجاوزا اذا هنا ايش صار عندى
+
+379
+00:32:16,120 --> 00:32:20,800
+نقص في الطاقة اذا فقدت الطاقة فهذا التفاعل ايش
+
+380
+00:32:20,800 --> 00:32:24,320
+اكسو ثيرميك لو بدى يكون اندو ثيرميك كيف بده ينتهي؟
+
+381
+00:32:24,320 --> 00:32:29,540
+بدي يكون زي هي يعني لو اصف التفاعل بهذا الشكل
+
+382
+00:32:29,540 --> 00:32:34,160
+بنقول هذا اندو ثيرميك لكن بزامو هاي مستوى ال
+
+383
+00:32:34,160 --> 00:32:39,950
+reactants زي هيexothermic هذا exothermic هذا
+
+384
+00:32:39,950 --> 00:32:43,870
+endothermic هنا طاقة النواتج أعلى من طاقة
+
+385
+00:32:43,870 --> 00:32:48,990
+المتفاعلات إذا هو اكتسب طاقة و بقيت هذه الطاقة
+
+386
+00:32:48,990 --> 00:32:53,530
+المكتسبة في النواتج هذا المفروض يعني تكون اتعلمتها
+
+387
+00:32:53,530 --> 00:33:00,890
+منحنيات التفاعل لو مثلا بدي أجي أقولكم إذا بتسمحوا
+
+388
+00:33:00,890 --> 00:33:05,830
+أرسمولي منحنة لتفاعل من خطوتين
+
+389
+00:33:15,210 --> 00:33:18,590
+والتفاعل كله اندو ثيرميك
+
+390
+00:33:21,290 --> 00:33:24,910
+ممكن أجيبلكم سؤال في الامتحان بس زي هيك ارسمولي
+
+391
+00:33:24,910 --> 00:33:31,470
+منحنى لتفاعل من خطواتين الخطوة الأولى سهلة و
+
+392
+00:33:31,470 --> 00:33:36,770
+الخطوة الثانية صعبة و التفاعل بمجمله into thermic
+
+393
+00:33:36,770 --> 00:33:40,610
+لما تريدون أن تأتيوا ترسموا بتعملوا زي هيك و زي
+
+394
+00:33:40,610 --> 00:33:47,650
+هيك هاي منحنى حطوا هذه reactantsإيش أنا قاعد بقول؟
+
+395
+00:33:47,650 --> 00:33:52,690
+الخطوة الأولى سهلة بعمل ال activation energy بسيط
+
+396
+00:33:52,690 --> 00:34:02,750
+و الخطوة الثانية صعبة إيش بعمللها؟ و التفاعل
+
+397
+00:34:02,750 --> 00:34:08,130
+endothermic هاي خط ال reactance هذا الملحانة بيمثل
+
+398
+00:34:08,130 --> 00:34:15,940
+هذه المواصفات هاي تفاعل من خطوتين هاي خطوةالخطوة
+
+399
+00:34:15,940 --> 00:34:20,860
+الأولى، الخطوة الثانية صعبة التفاعل بمجمله
+
+400
+00:34:20,860 --> 00:34:25,180
+endothermic لو كنت جاي التفاعل بمجمله exothermic،
+
+401
+00:34:25,180 --> 00:34:30,440
+شو هيحصل في المنحنة؟ هينزلها تحت، واضح؟ فاحنا
+
+402
+00:34:30,440 --> 00:34:35,620
+الخطوات بنقدر نعبر عنها بمنحنيات طاقة زي ما انتوا
+
+403
+00:34:35,620 --> 00:34:41,800
+شايفينالان بديكوا تكونوا متذكرين على السريع
+
+404
+00:34:41,800 --> 00:34:45,880
+شغلتين، لما بتكون Carbocation أخدنا إحنا إذا
+
+405
+00:34:45,880 --> 00:34:49,300
+بتدخلوا ال stability of carbocation، بقولنا أنه
+
+406
+00:34:49,300 --> 00:34:56,740
+أكتر carbocation stable، ال tertiary، شو السبب؟إنه
+
+407
+00:34:56,740 --> 00:35:01,600
+في حواليه electron donating groups، يعني في ال
+
+408
+00:35:01,600 --> 00:35:06,600
+tertiary، هذا موجة، حواليه تلت مجموعات بيعطوا
+
+409
+00:35:06,600 --> 00:35:11,280
+إلكترونات، فتقل الشحن الموجة بقى، في ال secondary،
+
+410
+00:35:11,280 --> 00:35:15,600
+مجموعتين، هذا ال slide أخدناها إحنا لما أخدنا ال
+
+411
+00:35:15,600 --> 00:35:21,820
+stability of carbocation سابقا، أخدنا إش زيهاهنا
+
+412
+00:35:21,820 --> 00:35:27,980
+في ال primary مجموعة واحدة بس، اذا وين اكتر انقاص
+
+413
+00:35:27,980 --> 00:35:34,160
+لشحنة الموجبة وكل ما نقصت الشحنة زادة، الثبات، اذا
+
+414
+00:35:34,160 --> 00:35:40,340
+اكتر اشي ثابت اللي هو ال tertiary carbohydrate
+
+415
+00:35:40,340 --> 00:35:45,060
+فاسهل اشي بتكونال torture الثابت هو اللي بتكون
+
+416
+00:35:45,060 --> 00:35:48,880
+بسهولة، وعشانك احنا بنقول انه في ال questions و ال
+
+417
+00:35:48,880 --> 00:35:53,260
+reactions ال torture أفضل من ال secondary أفضل من
+
+418
+00:35:53,260 --> 00:35:57,900
+ال primary، متذكرين هذا الكلام؟ ال torture أفضل من
+
+419
+00:35:57,900 --> 00:36:02,780
+ال secondary أفضل من ال primaryبرضه لما أخدتوا ال
+
+420
+00:36:02,780 --> 00:36:06,960
+carbon-cation نتذكروا شغلة أخدناها قولنا لو اتكون
+
+421
+00:36:06,960 --> 00:36:10,800
+carbon-cation ونفترض كان secondary وفيه إمكانية
+
+422
+00:36:10,800 --> 00:36:15,600
+يعمل rearrangement تصير tertiary بتصير ولا لأ؟
+
+423
+00:36:15,600 --> 00:36:19,460
+بتصير بيعمل rearrangement مشكول بني آدم بيحس نوضعه
+
+424
+00:36:19,460 --> 00:36:26,690
+عشان هيك لو أنا مثلا بدي أجي أخدهذا المركب هنا فيه
+
+425
+00:36:26,690 --> 00:36:31,810
+primary X لو بدها تمشي بتفاعل SN2 اتخيلوا ايش اللي
+
+426
+00:36:31,810 --> 00:36:35,850
+بيصير بيصير positive هنا هذا الكربو كاتيون ايش
+
+427
+00:36:35,850 --> 00:36:42,430
+ماله ال primary ابتنق ال H من هنا بيصير secondary
+
+428
+00:36:42,430 --> 00:36:46,270
+ف ال Z ل نيوكليوفايد بدل ميجي محل ال X وين بيجي
+
+429
+00:36:46,270 --> 00:36:52,060
+محل ال secondaryملاحظين معي الكاربو كاتيون اول ما
+
+430
+00:36:52,060 --> 00:36:55,660
+يتكون بتكون هنا على ال primary صار متكون على ال
+
+431
+00:36:55,660 --> 00:37:00,700
+primary ايش بيصير ناقل هيدرايت شفت بيصير الكاربو
+
+432
+00:37:00,700 --> 00:37:05,080
+كاتيون secondary ال Z بتيجي هنا او لو هذا المركب
+
+433
+00:37:05,080 --> 00:37:09,680
+هاي X فقدت ايش صار هنا الكاربو كاتيون عنده لما
+
+434
+00:37:09,680 --> 00:37:17,070
+فقدت هذه ال X ال primary شو بيصيرتنتقل high drive
+
+435
+00:37:17,070 --> 00:37:22,430
+تصبح DCH3 و هنا الفراغ اين تأتي الـ Z كأن ال
+
+436
+00:37:22,430 --> 00:37:28,130
+primary في خطوته المولى صار tertiary و ال Z جاءت
+
+437
+00:37:28,130 --> 00:37:30,710
+على ال tertiary لاحظوا هنا ال range مت من ال
+
+438
+00:37:30,710 --> 00:37:34,310
+primary إلى secondary هنا من ال primary إلى
+
+439
+00:37:34,310 --> 00:37:40,630
+tertiary لو فترضت هنا راحت ال X صار كربوكاتا يلمج
+
+440
+00:37:40,630 --> 00:37:45,500
+على العين والرأس بعد ذلك ماذا يحصل؟الأكشف تنتقل و
+
+441
+00:37:45,500 --> 00:37:49,340
+يصبح كاربو كاتيون هنا، شو نوعه؟ ترشر، الزد بتيجي
+
+442
+00:37:49,340 --> 00:37:53,240
+عليه، هل ملاحظين؟ هذه هي ال rearrangement اللي سبق
+
+443
+00:37:53,240 --> 00:37:57,240
+أنه أعطينا أمثلة زيها، يعني مش كتير هنركز بهذا
+
+444
+00:37:57,240 --> 00:38:00,300
+المسافة عليها، بس حتى لما تسمعوا كلمة
+
+445
+00:38:00,300 --> 00:38:03,520
+rearrangement يكون واضح عندكم، أنه لو كان عندى
+
+446
+00:38:03,520 --> 00:38:07,860
+primary كاربو كاتيون بيمكنه يصير secondary؟بصير،
+
+447
+00:38:07,860 --> 00:38:12,020
+لو كان secondary بإمكانه يصير tertiary، بصير، يعني
+
+448
+00:38:12,020 --> 00:38:15,820
+اللي معدله سبعين بده تخليه تمانين، و اللي معدله
+
+449
+00:38:15,820 --> 00:38:19,560
+تمانين بده تخليه تسعين، و لو معدله سبعين و بتخليه
+
+450
+00:38:19,560 --> 00:38:27,290
+تسعين، نور على نور، نور على نورهذه الـ slide
+
+451
+00:38:27,290 --> 00:38:31,650
+أخدناها قولنا إنه لو عندي سكاندري التفاعل بشكل
+
+452
+00:38:31,650 --> 00:38:35,790
+كبير بيعتمد على قوة الـ nucleophile فلما يكون ال
+
+453
+00:38:35,790 --> 00:38:42,610
+nucleophile strong بيشجع SN2 لما يكون weak بيشجع
+
+454
+00:38:42,610 --> 00:38:47,370
+SN1 ال solvent له تأثير لكن خارج مستوى دراستنا هذه
+
+455
+00:38:47,370 --> 00:38:51,010
+ال slide بنختم المحاضرة اليوم فيها بإمكانكوا
+
+456
+00:38:51,010 --> 00:38:56,610
+تقرؤوها بهدوء هي مقارنةأحنا كتبناها على الجانب
+
+457
+00:38:56,610 --> 00:39:02,170
+مرتين وبسيبها مكتوبة الآن و بنخلص المحاضرة هي
+
+458
+00:39:02,170 --> 00:39:08,270
+مقارنة ما بين ال SN2 و SN1 ال SN2 second order
+
+459
+00:39:08,270 --> 00:39:12,430
+أخدناها فيها complete inversion مش فيها
+
+460
+00:39:12,430 --> 00:39:15,390
+rearrangement ال reactivity براعي ما ليه أكتر من
+
+461
+00:39:15,390 --> 00:39:21,340
+secondary أكتر من tertiary الآن ال SN1first order
+
+462
+00:39:21,340 --> 00:39:25,800
+فيها رسميزيشن و في ال inversion زيادة فيها
+
+463
+00:39:25,800 --> 00:39:29,780
+rearrangement و ال tertiary افضل من ال secondary
+
+464
+00:39:29,780 --> 00:39:34,320
+افضل من ال primary و زيدوا هنا ان هذه one step و
+
+465
+00:39:34,320 --> 00:39:40,680
+هذه two step و ال two steps اللي هنا الاولة slow
+
+466
+00:39:40,680 --> 00:39:45,680
+التانية fast الان مثل هذه المقارنة بنقدر نجيب
+
+467
+00:39:45,680 --> 00:39:50,630
+عليها كام سؤال صح و غلطعشرين سؤال صح و غلط و
+
+468
+00:39:50,630 --> 00:39:57,350
+بتلخصنا كل المحاضرتين اللي فاتوا مثل هذه المقارنة
+
+469
+00:39:57,350 --> 00:40:00,390
+بتلخص المحاضرتين اللي فاتوا و أنا بتهيأ ليه أنه
+
+470
+00:40:00,390 --> 00:40:05,990
+أخدنا احنا يعني أخدناهم يعني بشكل بعتقد أنه كافي
+
+471
+00:40:05,990 --> 00:40:06,710
+شكرا
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..66e9a6f2b9c1247de28aa44b943a6cfb60f7387e
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/j9kpnbGKbz8_postprocess.srt
@@ -0,0 +1,1692 @@
+1
+00:00:05,200 --> 00:00:09,580
+اليوم نحن في تفاعل الـ aldehydes و الـ ketones
+
+2
+00:00:09,580 --> 00:00:15,280
+المرة الماضية حكينا شغل أساسية قلنا إنه في عندنا
+
+3
+00:00:15,280 --> 00:00:20,920
+تفاعل عام للـ aldehydes و الـ ketones بيعتمد على
+
+4
+00:00:20,920 --> 00:00:26,940
+إنه الـ carbon تبعت الـ carbonyl group is an
+
+5
+00:00:26,940 --> 00:00:30,820
+electrophile يعني positive، واضح؟ سواء كانت
+
+6
+00:00:31,150 --> 00:00:35,190
+Positive كامل أو كانت positive جزء في النهاية
+
+7
+00:00:35,190 --> 00:00:38,870
+بيصير عليها تفاعل الـ Eucleophile التفاعل في شكل
+
+8
+00:00:38,870 --> 00:00:42,070
+عام للـ Eucleophile لما بيتهاجم على الكربون الـ O
+
+9
+00:00:42,070 --> 00:00:47,930
+في نهاية بيصير OH، واضح؟ إذا التفاعل الأساسي
+
+10
+00:00:47,930 --> 00:00:54,500
+للالدهايتز والكيتون هو مهاجمة الـ Eucleophileوزي
+
+11
+00:00:54,500 --> 00:00:58,900
+ما اتفقنا الـ O إيش بتصير؟ OH هذا الكلام أخدنا
+
+12
+00:00:58,900 --> 00:01:03,360
+مثال عليه هذا الكلام أخدنا مثال عليه في تفاعل
+
+13
+00:01:03,360 --> 00:01:07,920
+الميه وإن كان تفاعل الميه محدود يعني مش مع مراكبات
+
+14
+00:01:07,920 --> 00:01:11,900
+كثير بيصير اللي هي عملية إضافة الميه بنسميها
+
+15
+00:01:11,900 --> 00:01:16,360
+hydration فلما نضيف الميه هذه الـ OH اللي شايفينها
+
+16
+00:01:16,360 --> 00:01:22,040
+باللون الأحمر هي بتضيف وهذه ال Oxygen بتصير OH هذا
+
+17
+00:01:22,040 --> 00:01:26,920
+المراكب اللي على نفسهاللي على نفس ال carbon فيه
+
+18
+00:01:26,920 --> 00:01:33,800
+مجموعتين OH بنسميه hydrate واضح مع ال formaldehyde
+
+19
+00:01:33,800 --> 00:01:38,600
+بيتكون و بيقولنا كمان بتكون مع ال chloral واضح
+
+20
+00:01:38,600 --> 00:01:42,160
+بيكون اسم هذا formaldehyde hydrate لو ال aldehyde
+
+21
+00:01:42,160 --> 00:01:47,380
+اللي عندي كان chloral بيكون chloral hydrate الآن
+
+22
+00:01:47,380 --> 00:01:54,290
+بدنا ناخد أمثلة تانية بس نغير فيهاللـ nucleophile
+
+23
+00:01:54,290 --> 00:01:59,610
+اللي بيهاجمها لكن نفس الشكل للتفاعل هنلاحظ أنه
+
+24
+00:01:59,610 --> 00:02:06,070
+بيستمر مثلا عملية إضافة ال alcohols ال alcohols R
+
+25
+00:02:06,070 --> 00:02:13,170
+O H واضح؟ لما بنضيف ال alcohol اللي هضيف can
+
+26
+00:02:13,170 --> 00:02:20,890
+nucleophile ال R Oو الـ CW.O بدأ تصير OH الان هنا
+
+27
+00:02:20,890 --> 00:02:25,810
+بتلاحظوا ان انتوا على carbon واحدة عندكم مجموعتين
+
+28
+00:02:25,810 --> 00:02:34,410
+وظيفيتين عندكم alcohol و عندكم ether هذه ال R C O
+
+29
+00:02:34,410 --> 00:02:38,210
+R او ال C O R هذا ether واضح؟
+
+30
+00:02:40,670 --> 00:02:44,450
+الالكهول الان هدولة المجمعتين الوظيفيتين موجودين
+
+31
+00:02:44,450 --> 00:02:48,350
+على كاربون واحدة ال ether والالكهول هذه التوليفة
+
+32
+00:02:48,350 --> 00:02:54,110
+او هذا الشكل بنقول عن المركب hemiacetal فال
+
+33
+00:02:54,110 --> 00:02:57,770
+hemiacetal هو المركب اللي على الكاربون الواحدة
+
+34
+00:02:57,770 --> 00:03:04,410
+موجود عند كحول وموجود ether بمعنى على الكاربون OR
+
+35
+00:03:04,410 --> 00:03:11,590
+وOH واضح؟بناء على ذلك، لو افترضت مثلا انه انا كنت
+
+36
+00:03:11,590 --> 00:03:17,350
+بادي هنا بمجموعة مثل CH3 في هذه الحالة، شو هيكون
+
+37
+00:03:17,350 --> 00:03:21,010
+اسم ال الديهيد؟
+
+38
+00:03:21,010 --> 00:03:28,290
+أسيتالديهيد، بعد هيك لو ضفت عليه إيثانون، هيصير
+
+39
+00:03:28,290 --> 00:03:32,890
+أسيتالديهيد هيمي أسيتال of إيثانول، أنا بتحدد كمان
+
+40
+00:03:34,800 --> 00:03:40,720
+واضح فبصير acetaldehyde hemiacetal خلّيني أقول ال
+
+41
+00:03:40,720 --> 00:03:45,940
+hemiacetal في نهاية هو اسم عائلة زي ما الكحول اسم
+
+42
+00:03:45,940 --> 00:03:50,080
+عائلة و ال ether اسم عائلة و ال ketone اسم عائلة
+
+43
+00:03:50,080 --> 00:03:54,780
+فال hemiacetal بيظل اسم عائلة، العائلة فيها على
+
+44
+00:03:54,780 --> 00:04:02,580
+الكربون الواحدة OH و ORهذا التفاعل واضح تماما انه
+
+45
+00:04:02,580 --> 00:04:06,560
+تفاعل addition ليش تفاعل addition لأنه انا على ال
+
+46
+00:04:06,560 --> 00:04:09,720
+double bond لما تيجي و انت تتطلع هذه كانت double
+
+47
+00:04:09,720 --> 00:04:15,820
+bond ضفت OR وضفت H و حولت ال double إلى single
+
+48
+00:04:15,820 --> 00:04:20,180
+bond وبناء على ذلك هذا التفاعل هو تفاعل addition
+
+49
+00:04:20,840 --> 00:04:27,580
+الان اذا كان عندى الكحول موجود بنسبة كبيرة .. اذا
+
+50
+00:04:27,580 --> 00:04:31,960
+الكحول عندى موجود بنسبة كبيرة بيصير تفاعل تاني
+
+51
+00:04:31,960 --> 00:04:36,640
+إضافي بعد ما نخلص تفاعل ال addition بتيجي الكمية
+
+52
+00:04:36,640 --> 00:04:43,430
+الإضافية من الكحول بتهاجم هنا و بتطرد ال OHلاحظوا
+
+53
+00:04:43,430 --> 00:04:47,570
+هنا مجموعة إجت و مجموعة طلعت إذا إيش هذا التفاعل
+
+54
+00:04:47,570 --> 00:04:53,570
+إبتال مجموعة بتحل محال مجموعة substitution فبصير
+
+55
+00:04:53,570 --> 00:04:59,770
+عند مدل ال OH و OR في هذه الحالة صار عند مركب على
+
+56
+00:04:59,770 --> 00:05:05,050
+نفس ال carbon مجمعتين ether يعني على ال carbon OR
+
+57
+00:05:05,050 --> 00:05:12,430
+و OR هذه العائلة بنسميها acetalإذا أنا في عندى
+
+58
+00:05:12,430 --> 00:05:17,390
+hemacetal يعني نص أسيتال لإنه OR واحدة والتانية OH
+
+59
+00:05:17,390 --> 00:05:24,230
+وفي عندى أسيتال كامل الأسيتال الكامل OR و OR واضح
+
+60
+00:05:24,230 --> 00:05:29,430
+بنصير كام مرة اتفاعل الكحول مرتين الآن هنا بدكوا
+
+61
+00:05:29,430 --> 00:05:37,720
+تنتبهواجيدا لتوصيف التفاعل الخطوة
+
+62
+00:05:37,720 --> 00:05:41,280
+الأولى لما بدنا نتكلم عنها ال formation of
+
+63
+00:05:41,280 --> 00:05:47,580
+hemeacetal is in eucleophilic addition reaction
+
+64
+00:05:48,700 --> 00:05:53,880
+واضح؟ لما أنا بدأت أسألكم تكوين الـ hemeacetal هل
+
+65
+00:05:53,880 --> 00:05:57,460
+هو a nucleophilic addition reaction ولا
+
+66
+00:05:57,460 --> 00:06:01,380
+substitution reaction؟ a nucleophilic addition
+
+67
+00:06:01,380 --> 00:06:06,720
+reaction لكن ال formation of acetal from
+
+68
+00:06:06,720 --> 00:06:14,420
+hemeacetal acetal from hemeacetal is a
+
+69
+00:06:14,420 --> 00:06:16,400
+substitution reaction
+
+70
+00:06:18,100 --> 00:06:21,900
+واضح؟ اذا انا لما بحول الهيمي أسيتال لأسيتال بعمل
+
+71
+00:06:21,900 --> 00:06:26,100
+إبدال لما بحول ال الديهايد او الكيتون لهيمي أسيتال
+
+72
+00:06:26,100 --> 00:06:30,700
+بعمل إضافة الان لو انا كنت بدأ اتفلسف اكثر عليكم و
+
+73
+00:06:30,700 --> 00:06:37,260
+اجي اسألكم اقولكم تكوين الاسيتال من ال الديهايد او
+
+74
+00:06:37,260 --> 00:06:44,680
+الكيتون هو عبارة عن عمليتين متتابعتين الاولى
+
+75
+00:06:45,710 --> 00:06:50,630
+addition والتانية substitution واضح فبتكونوا
+
+76
+00:06:50,630 --> 00:06:54,250
+دقيقين في توصيف هذه العملية أول إشي بيصير عندى
+
+77
+00:06:54,250 --> 00:06:58,650
+addition to form the hemiacetal then substitution
+
+78
+00:06:58,650 --> 00:07:03,860
+of the OH to form the acetalواضحة هذه الفكرة، هذا
+
+79
+00:07:03,860 --> 00:07:08,400
+الكلام بيعتمد على قداش أنا عندى كمية كحول، بمعنى
+
+80
+00:07:08,400 --> 00:07:12,540
+لو حطيت الكحول بنسبة واحد الى واحد فقط هيتكون عندى
+
+81
+00:07:12,540 --> 00:07:17,120
+ال hemacetal لو حطيت بنسبة اتنين الى واحد او اكثر
+
+82
+00:07:17,120 --> 00:07:20,880
+هيتكون عندى في النهاية الacetal
+
+83
+00:07:31,600 --> 00:07:38,260
+ممكن الكحول والالديهيد يكونوا موجودين في داخل جزء
+
+84
+00:07:38,260 --> 00:07:43,360
+واحد يعني لاحظوا في المثال السابق الكحول عبارة عن
+
+85
+00:07:43,360 --> 00:07:48,340
+جزء والالديهيد جزء منفصلين وبيجوا يتفاعلوا مع بعض
+
+86
+00:07:48,340 --> 00:07:54,420
+الان لو كان عندى مثل هذا المركب مثلاواضح؟ اللي هو
+
+87
+00:07:54,420 --> 00:07:58,780
+الـ 5-hydroxybenthanol نعرف كيف نسميه، هاي واحد،
+
+88
+00:07:58,780 --> 00:08:01,640
+اتنين، تلاتة، أربعة، خمسة، هذا penthanol على
+
+89
+00:08:01,640 --> 00:08:06,020
+مجموعة خمسة إيش عندكم؟ OH إذاً هذا 5
+
+90
+00:08:06,020 --> 00:08:10,180
+-hydroxybenthanol الآن لاحظوا هنا، في عند ال
+
+91
+00:08:10,180 --> 00:08:14,080
+الديهايد وفي عند ال OH تبع الكحول اللي بدأت تتفاعل
+
+92
+00:08:14,080 --> 00:08:18,620
+وعشان كذا لما بنعمله بـH plus يعني في وجود حامض
+
+93
+00:08:19,160 --> 00:08:23,020
+ممكن التفاعل يحدث في داخل الجزء، بنسميه
+
+94
+00:08:23,020 --> 00:08:29,120
+Intramolecular Intramolecular إن المتفاعلين يكونوا
+
+95
+00:08:29,120 --> 00:08:36,260
+داخل الجزء، مش يجي الألديهيد قطعة والألكوهول قطعة
+
+96
+00:08:36,260 --> 00:08:40,900
+تانية، لأ هنا التلتين موجودات في داخل الجزء فبتم
+
+97
+00:08:40,900 --> 00:08:46,420
+تفاعل وهذا بتصير OH
+
+98
+00:08:48,710 --> 00:08:53,310
+اللي هو تكوين الـ Hemacetal هذا التفاعل اللي بيكون
+
+99
+00:08:53,310 --> 00:08:57,050
+المتفاعلين تبعله في داخل الجزء شو بنسميه؟
+
+100
+00:08:57,050 --> 00:09:01,970
+Intramolecular within the molecule لكن لما أنا
+
+101
+00:09:01,970 --> 00:09:05,970
+بجيب جزيئين منفصلين يتفاعلوا مع بعض شو بوصف
+
+102
+00:09:05,970 --> 00:09:12,550
+التفاعل؟ Intermolecular فبيتميزوا ما بين تفاعل زي
+
+103
+00:09:12,550 --> 00:09:16,290
+هذا Intramolecular
+
+104
+00:09:17,300 --> 00:09:22,980
+إن الرأسين المتفاعلين في تاخر الجزيئة وعندما أحضر
+
+105
+00:09:22,980 --> 00:09:27,440
+جزيئين X وY ويتفاعلوا مع بعض هما مفصلين هذا
+
+106
+00:09:27,440 --> 00:09:32,800
+التفاعل شو بنسميه Intermolecular وهذا مصطلح دائما
+
+107
+00:09:32,800 --> 00:09:33,900
+نستعمله
+
+108
+00:09:35,940 --> 00:09:40,020
+التفاعل فيه عند Intramolecular و Intermolecular
+
+109
+00:09:40,020 --> 00:09:44,700
+ففي هذا المثال لما بنوجد الـ OH و الـ Aldehyde
+
+110
+00:09:44,700 --> 00:09:48,360
+بتفاعلوا مع بعض ولو انهم الاتنين موجودين في جزء
+
+111
+00:09:48,360 --> 00:09:51,820
+واحد هيعطيين اللي هو الـ Ether مع الـ OH
+
+112
+00:09:51,820 --> 00:09:56,460
+-Hemiacetal واضح؟ فبتكون عندنا اللي هو
+
+113
+00:09:56,460 --> 00:10:01,680
+الـHemiacetal-O5-Hydroxybintanate هذا الحقيقة
+
+114
+00:10:01,680 --> 00:10:06,380
+التفاعل بالذات هذا يعتبر مهم كتيريعتبر مهم كتير
+
+115
+00:10:06,380 --> 00:10:11,040
+ليش مهم؟ لأنه لما تدرسوا انتوا في ال biochemistry
+
+116
+00:10:11,040 --> 00:10:19,660
+هتاخدوا تركيب الجولوكوز الجولوكوز عبارة عن 6 ذرات
+
+117
+00:10:19,660 --> 00:10:26,000
+كربون موجود فيهم موجود فيهم الديهيد وموجود و H
+
+118
+00:10:26,000 --> 00:10:33,540
+زكتار وبيكون مرات بشكل a cyclic يعني فاتح ومرات
+
+119
+00:10:33,540 --> 00:10:41,510
+بشكلcyclic ايه cyclic يعني؟ مش حلقي non-cyclic ايه
+
+120
+00:10:41,510 --> 00:10:47,590
+تبعت؟ ايش هذه؟ النفة مش ال a بتيجي حرف نفة a
+
+121
+00:10:47,590 --> 00:10:52,530
+-cyclic أسيمتريك يعني غير متماثل غير حلقي فبيكون
+
+122
+00:10:52,530 --> 00:10:57,370
+مرات بالشكل الفاتح و بيكون مرات بالشكل المسكر وهذا
+
+123
+00:10:57,370 --> 00:11:04,240
+اتزال موجودفي السكريات وموجود في الجولوكوز فبهذا
+
+124
+00:11:04,240 --> 00:11:08,960
+الشكل بيصير هذا التفاعل بالنسبة لنا تفاعل مهم واضح
+
+125
+00:11:08,960 --> 00:11:12,960
+لإن أحد التفاعلات اللي بتاخدوها بالتفصيل في
+
+126
+00:11:12,960 --> 00:11:16,260
+الكيميا الحيوية بيصير عند هذا الجولوكوز طبعا
+
+127
+00:11:16,260 --> 00:11:20,440
+هتتعلموا كيف تسمو إيش معنا بيتا وإيش معنا دي إيش
+
+128
+00:11:20,440 --> 00:11:25,230
+لوكو بيرانوس كل هذا الكلام وين ماكانهفي course
+
+129
+00:11:25,230 --> 00:11:29,330
+Biochemistry على الـ Carbohydrate لكن أهم شيء
+
+130
+00:11:29,330 --> 00:11:33,510
+عندنا الآن أنه مثل هذا التفاعل بالظبط هو اللي
+
+131
+00:11:33,510 --> 00:11:38,110
+بيصير لما بتتم عملية الإغلاق للجولوكوز هو تفاعل
+
+132
+00:11:38,110 --> 00:11:43,970
+Hemacetal Formation تفاعل تكوين Hemacetal
+
+133
+00:11:43,970 --> 00:11:47,270
+Intramolecular Hemacetal Formation
+
+134
+00:11:54,130 --> 00:12:00,390
+ممكن واجهنا الموضوع بصورة تانية احنا قلنا لو بدنا
+
+135
+00:12:00,390 --> 00:12:06,450
+نضيف كحول واحد بيصير عندنا hemacetal لما نكمل كمان
+
+136
+00:12:06,450 --> 00:12:11,690
+كحول بيصير acetal الان لاحظوا في مثل هذا التفاعل
+
+137
+00:12:11,690 --> 00:12:16,770
+يعني لو فعلنا ال acetone مع الethylene glycol هذا
+
+138
+00:12:16,770 --> 00:12:25,090
+كيتون الethylene glycolهو حقيقة die all يعني في
+
+139
+00:12:25,090 --> 00:12:30,670
+مجموعتين alcohol ألاحظون؟ في مجموعتين OAC يعني
+
+140
+00:12:30,670 --> 00:12:36,410
+كأنه بيمثل die alcohol بناء على ذلك هذا الـ
+
+141
+00:12:36,410 --> 00:12:40,290
+ethylene glycol لو إجا بده يتفاعل بيتفاعل على
+
+142
+00:12:40,290 --> 00:12:44,810
+مرتين بيكوّن في المرة الأولى يعني بإمكاننا نتطلع
+
+143
+00:12:44,810 --> 00:12:48,110
+إحنا أنه في المرة الأولى هذه تيجي تتفاعل وهذا تصير
+
+144
+00:12:48,980 --> 00:12:59,640
+هذه الحالة ستعطيك حالة وثيقة OH وهنا OH ثم
+
+145
+00:12:59,640 --> 00:13:05,780
+التفاعل الأول اللي هو كحول مع الكيتون أعطانا
+
+146
+00:13:05,780 --> 00:13:12,400
+hemiacetal الأن لأن الـ OH التانية موجودة تكمل
+
+147
+00:13:12,400 --> 00:13:19,310
+التفاعلsubstitution بتكون الacetal فهنا مجمعتين ال
+
+148
+00:13:19,310 --> 00:13:24,150
+OH موجودين في جزء واحد قبل شوية لما أخدنا الفكرة
+
+149
+00:13:24,150 --> 00:13:28,270
+العامة كنا نقول انه two alcohol molecules react
+
+150
+00:13:28,270 --> 00:13:32,730
+the first one and then the second one الان اللي
+
+151
+00:13:32,730 --> 00:13:39,260
+قاعد بيصير ان هذا الجزء نفسهموجود فيه مجموعتين
+
+152
+00:13:39,260 --> 00:13:43,240
+ألكوهول فبتفاعلوا بشكل متتالي أول تفاعل بتفاعل
+
+153
+00:13:43,240 --> 00:13:49,020
+واحدة منهم و بتعمل addition هذه العملية بهذا الشكل
+
+154
+00:13:49,020 --> 00:13:54,380
+هي عملية ايش addition وبعد هيك لما بدأت العملية
+
+155
+00:13:54,380 --> 00:14:02,740
+التانية substitution إبدال فبتكون عندنا ال acetone
+
+156
+00:14:02,740 --> 00:14:08,410
+ليش acetone لأن هذا أصلاجاي من الاسيتون اثيلين
+
+157
+00:14:08,410 --> 00:14:13,990
+غلايكول أسيتال لما بنيجي نسميه على الشقين تبعونه
+
+158
+00:14:13,990 --> 00:14:20,170
+هذا الجزء كان اسيتون هذا الجزء كان اثيلين غلايكول
+
+159
+00:14:20,170 --> 00:14:27,030
+فصار عند اسيتون اثيلين غلايكولأسيتال ليش أسيتال؟
+
+160
+00:14:27,030 --> 00:14:32,830
+لأنه متصل ب OR و ب OR لكن مثل هذا المركب لو كنتوا
+
+161
+00:14:32,830 --> 00:14:37,690
+بتكونوا تسموه، شو هتسموه؟ هتقولوا أسيتون، هاي جزء
+
+162
+00:14:37,690 --> 00:14:44,750
+الأسيتون، إثالين غلايكول، هيمي أسيتال لأن هذا متصل
+
+163
+00:14:44,750 --> 00:14:51,300
+في الكاربون OHو OR هذا hemacetal فهي ال acetone
+
+164
+00:14:51,300 --> 00:14:55,780
+إيثيلين جلايكل hemacetal هداك acetone إيثيلين
+
+165
+00:14:55,780 --> 00:15:03,820
+جلايكل acetal كامل لأ
+
+166
+00:15:03,820 --> 00:15:08,840
+لأ لأ نسبة لأبوه
+
+167
+00:15:12,530 --> 00:15:17,890
+نسبة لأبوه خلينا نوضح السؤال اللي بتسأله زملتكم ..
+
+168
+00:15:17,890 --> 00:15:23,870
+السؤال اللي بتسأله زملتكم كتير أشياء .. كتير أشياء
+
+169
+00:15:23,870 --> 00:15:31,030
+بتتسمى .. بتتسمى في الدنيا نسبة للأصل و كتير أشياء
+
+170
+00:15:31,030 --> 00:15:38,150
+في الدنيا بتتسمى نسبة للفرعواضح؟ يعني الأشياء ممكن
+
+171
+00:15:38,150 --> 00:15:44,390
+تتسمى نسبة للأصل والأشياء يمكن أن تسمى أيضا نسبة
+
+172
+00:15:44,390 --> 00:15:51,050
+لإيش؟ للفرعحسب ما بده الإنسان .. حسب ما بده
+
+173
+00:15:51,050 --> 00:15:56,190
+الإنسان يوضح شيء معين، يعني هذا .. هذا المفهوم
+
+174
+00:15:56,190 --> 00:16:02,130
+بالحياة شوية بنطلع عن الكيميا، يعني مثلا عائلة ..
+
+175
+00:16:02,130 --> 00:16:06,910
+عائلة محترمة، خلينا هيك نحكي، عائلة محترمة، إلها
+
+176
+00:16:06,910 --> 00:16:13,490
+إبن .. إلها إبن بيروح اللي هو بده يشتغل في مهنةغير
+
+177
+00:16:13,490 --> 00:16:18,050
+جائزة شرعان، مهنة محرمة، بدّو يشتغلوا في مصنع خمرة
+
+178
+00:16:18,050 --> 00:16:23,710
+بيسألوا أبوه إيش بتشتغل؟ أبوه راجل اتقل، محترم،
+
+179
+00:16:23,710 --> 00:16:29,190
+بيسألوا إيش بتشتغل؟ بيقولوا أنا بعصر عنب بعصر عنب،
+
+180
+00:16:29,190 --> 00:16:33,790
+الكلامتين حلال، العصر حلال والعنب حلال كان أبوه
+
+181
+00:16:33,790 --> 00:16:38,250
+بسرعة بيقولوا أنت بتعصر خمر هو بعصر خمر ولا بعصر
+
+182
+00:16:38,250 --> 00:16:43,910
+عنب؟لكن العناب يؤدي إلى ماذا؟ إلى الخمر فالأب
+
+183
+00:16:43,910 --> 00:16:48,510
+الفهمان بيقول و الله شغلتك ما هي صابطة ماتزينهاش و
+
+184
+00:16:48,510 --> 00:16:54,390
+لذلك إني أراني أعصره خمرا ملاحظين الآية إيش حكت؟
+
+185
+00:16:54,390 --> 00:16:58,270
+حكت هو الواحد بيوصل الخمر ولا بيوصل العناب هانا
+
+186
+00:16:58,270 --> 00:17:02,630
+سامة علىالفرع مش على الأصل الان اللي بتسألوا
+
+187
+00:17:02,630 --> 00:17:07,530
+زملتكم انه هذا ليش سميناه إيثالين glycol طب هو
+
+188
+00:17:07,530 --> 00:17:11,530
+مرمعنا تلت أربع مرات زي هيك مرمعنا تلت أربع مرات
+
+189
+00:17:11,530 --> 00:17:16,370
+زي هيك هاي ال إيثالين أفندي هاي الإيثالين هذا
+
+190
+00:17:16,370 --> 00:17:20,370
+اعملنا منه أكتر من شغله في كل الأحوال فقط خواصه
+
+191
+00:17:20,370 --> 00:17:24,630
+كإيثالين بس لما سميناه سميناه على أساسه إيش المثال
+
+192
+00:17:24,630 --> 00:17:30,010
+الأول اللي أخدناه؟لما كنا نعمله oxidation كان صير
+
+193
+00:17:30,010 --> 00:17:38,890
+زي هيك، ضال إيثالين ولا .. هانا الأصل، بس هذا إيش
+
+194
+00:17:38,890 --> 00:17:46,710
+سميته؟ إيثالين Oxide سميته على إيش؟ سميته على
+
+195
+00:17:46,710 --> 00:17:51,050
+الأصل تبعه، نفس الإيثالين هذا، لو أخدته مع الكئمن
+
+196
+00:17:51,050 --> 00:17:51,870
+O4
+
+197
+00:17:55,360 --> 00:18:02,240
+و OH في basic medium مثلا إيش صار؟ بطل إيثالين لكن
+
+198
+00:18:02,240 --> 00:18:08,140
+أنا لما بسمي إيثالين إيجليكول نسبة إلى إيش؟ نسبة
+
+199
+00:18:08,140 --> 00:18:15,520
+للأصل بس هو هنا مش إيثالين إيثالين إيجليكول بعد
+
+200
+00:18:15,520 --> 00:18:20,360
+هيك ممكن كمان تيجي تتذكر كمان شغلة إنه هذا
+
+201
+00:18:20,360 --> 00:18:25,910
+الإيثالين لما عملنا منه polymerفي وجود ال ROR
+
+202
+00:18:25,910 --> 00:18:30,330
+البروكسايد ال free radical polymerization شو صار
+
+203
+00:18:30,330 --> 00:18:41,140
+عندى صار عندى CH2 CH2 to the Nضال إثيلين في الـ
+
+204
+00:18:41,140 --> 00:18:44,660
+polymer ولا راحت ال double bond؟ راحت طب إيش
+
+205
+00:18:44,660 --> 00:18:49,700
+سمناها؟ poly .. polyethylene ولا polyethylene؟
+
+206
+00:18:49,700 --> 00:18:54,040
+polyethylene على الأصل فكل هذه المراكبات مسمية على
+
+207
+00:18:54,040 --> 00:18:54,940
+الأصل
+
+208
+00:18:59,340 --> 00:19:04,780
+فاحنا كتير بنسمي شغلات على الأصل اللي إجت منه،
+
+209
+00:19:04,780 --> 00:19:09,280
+كتير بنسمي شغلات على الأصل اللي إجت منه، نفس الأشي
+
+210
+00:19:09,280 --> 00:19:12,660
+هنا لو بدكتيجي تقولي ليش هذا سميته، هو هذا ضاي
+
+211
+00:19:12,660 --> 00:19:13,500
+الأسيتون
+
+212
+00:19:16,340 --> 00:19:20,640
+هذا ضايل أسيتون وهذا ضايل إثيلين غلايكون بهذا
+
+213
+00:19:20,640 --> 00:19:24,520
+الشكل هذه أسيتون وهذه إثيلين غلايكون بس هذه القطعة
+
+214
+00:19:24,520 --> 00:19:27,780
+جاية من أسيتون وهذه القطعة جاية من إثيلين غلايكون
+
+215
+00:19:27,780 --> 00:19:33,820
+فسمينا كله أسيتون نسبة للأصل إثيلين غلايكون نسبة
+
+216
+00:19:33,820 --> 00:19:43,240
+للأصل أو أسيتون واضح؟ فكثير احنا بنسمي نسبة
+
+217
+00:19:44,100 --> 00:19:51,180
+للاصل و مرات بنسمي نسبة للفرع و الأمثلة في ذلك في
+
+218
+00:19:51,180 --> 00:19:52,400
+العلوم الإنسانية
+
+219
+00:19:59,860 --> 00:20:04,980
+هنا عندكم مجموعة إثرائية من الأمثلة مجموعة إثرائية
+
+220
+00:20:04,980 --> 00:20:10,400
+من الأمثلة لاحظوا مثلا في المثال الأول مش كله يعني
+
+221
+00:20:10,400 --> 00:20:14,980
+ضروري احنا نتطلع عليها لأنه المفروض أنه تتدربوا في
+
+222
+00:20:14,980 --> 00:20:19,020
+البيت تكتبوا الشغل ولاحظوا يعني دائما في ال organ
+
+223
+00:20:19,020 --> 00:20:23,420
+ال chemistry مشكلة .. مشكلة عند الطلاب لما يدرسوا
+
+224
+00:20:23,420 --> 00:20:29,310
+الكيميا من slides و بس بيقرأها في الليل واضحةبييجي
+
+225
+00:20:29,310 --> 00:20:32,110
+في الامتحان بيده يعيد كتابة شغلة بيلاقي حاله
+
+226
+00:20:32,110 --> 00:20:35,410
+مابيعرفش يكتب انا كتير كان عندى احساس و انا بصلح
+
+227
+00:20:35,410 --> 00:20:39,150
+الامتحان لكوا و لا غيركوا ان انتوا فاهمين تماما
+
+228
+00:20:39,150 --> 00:20:45,610
+لكن ولا مرة اجيتوا و طبقتوا بالورقة و الجلم و
+
+229
+00:20:45,610 --> 00:20:48,590
+عدتوا الشغلة تلت مرات لحد ما أتقنتوا انكوا بتقدروا
+
+230
+00:20:48,590 --> 00:20:51,410
+ترسموها عشان هيك الشغلة اللي فاهمينها ماجدرتوش
+
+231
+00:20:51,410 --> 00:20:57,130
+يتعبرواماقدرتوش يتعبروا عنها و دائما أنا يعني بذكر
+
+232
+00:20:57,130 --> 00:21:01,390
+مقولة أستاذي و يمكن حكيتهلكوا إياها الدكتور عادي
+
+233
+00:21:01,390 --> 00:21:04,230
+الجرار علمناه في الجامعة الأردنية كان يقولنا
+
+234
+00:21:04,230 --> 00:21:08,430
+الكيميائي الشاطر هو الكيميائي اللي عن يمينه ورق
+
+235
+00:21:08,430 --> 00:21:14,810
+خرطوش و عن شماله سلة محملات و كل شغلة بيكتب و
+
+236
+00:21:14,810 --> 00:21:20,610
+بيرمى بيكتب و بيرمى بتصير الإيد تبعته متعودة إنها
+
+237
+00:21:20,610 --> 00:21:28,080
+اتنفذماعد ذلك خلاص هو بده يحتفظ بالورق بستعمل
+
+238
+00:21:28,080 --> 00:21:33,740
+الخبز ولا إيش ماكان واضح؟ الآن لاحظوا هذا المثال
+
+239
+00:21:33,740 --> 00:21:37,760
+أي مثال من هدول كان ممكن نجيب الكياب سهولة في
+
+240
+00:21:37,760 --> 00:21:41,860
+امتحان بس المهم أنه لازم تكتبوا بيدكوا عشان تتقنوا
+
+241
+00:21:41,860 --> 00:21:45,840
+ال organ chemistry هنا عندي الديهيد مع two
+
+242
+00:21:45,840 --> 00:21:50,910
+alcoholsشو اللي بدى يتكون عندى في هذه الحالة ال
+
+243
+00:21:50,910 --> 00:21:56,330
+final product أسيتال بمعنى هتصير OR و ال OH
+
+244
+00:21:56,330 --> 00:22:00,650
+التانية برضه هتصير OR Oethyl و Oethyl هى شكل
+
+245
+00:22:00,650 --> 00:22:07,450
+الأسيتال هى شكل الأسيتال هنا عندى مثال شبيه في
+
+246
+00:22:07,450 --> 00:22:11,910
+اللى حكيناه قبل شوية Cyclohexanone كيتون وهذا
+
+247
+00:22:13,750 --> 00:22:19,790
+ethylene glycol هيتفاعل مرتين إذا هانا هيعمل O O
+
+248
+00:22:19,790 --> 00:22:24,010
+بهذا الشكل الآن صدقوني هذه إذا في المثال السابق
+
+249
+00:22:24,010 --> 00:22:28,170
+وفي هذا المثال ما دربتوش إيدكوا عليها بسهولة لو
+
+250
+00:22:28,170 --> 00:22:32,250
+أجتكوا في الامتحان مش هتعرفوا ترسموها رغم أنه واضح
+
+251
+00:22:32,250 --> 00:22:40,130
+أن تنتيل O H's يتفاعلوا ورا بعض واضح؟ هانا إيش
+
+252
+00:22:40,130 --> 00:22:41,850
+المثال إذا بتلاحظوا
+
+253
+00:22:46,590 --> 00:22:53,810
+هذا مثال مزدوج .. هذا مثال مزدوج فى عندى ketone و
+
+254
+00:22:53,810 --> 00:23:00,130
+فى عندى OH ايش بتعمل ال OH هذه؟ بدى تعمل
+
+255
+00:23:00,130 --> 00:23:05,150
+intramolecular reaction طبعا تحاولوا تسكر المركب
+
+256
+00:23:05,150 --> 00:23:11,710
+حيصير هذا O و هذا ال O تتحول إلى OH بعد هي تلاحظوا
+
+257
+00:23:11,710 --> 00:23:17,430
+ايش ضاف؟ضاف كمان كحول خارج يعني كأنه في هذه
+
+258
+00:23:17,430 --> 00:23:21,490
+المسألة عمل كحول داخل اللي هو أول تفاعل ال
+
+259
+00:23:21,490 --> 00:23:27,210
+formation of hemiacetal من ال OH الداخلية اتفاعلت
+
+260
+00:23:27,210 --> 00:23:31,310
+بعد هيك راح جاب كحول من الخارج methanol الميثانول
+
+261
+00:23:31,310 --> 00:23:38,250
+حل محل ال OH فأعطانا هذا المركب بعرفش إذا واضح ولا
+
+262
+00:23:38,250 --> 00:23:45,300
+بيلزم نعمله تفصيل إضافة واضح هذا المثال؟تطلعوا
+
+263
+00:23:45,300 --> 00:23:49,660
+مرات وين بتصير المشكلة .. مرات وين بتصير المشكلة
+
+264
+00:23:49,660 --> 00:23:54,860
+أنه كيف أرتب الأشياء بحيث تكون المتفاعلات جاية
+
+265
+00:23:54,860 --> 00:23:59,760
+بشكل قريب على بعضها البعض، يعني نفس هذا .. نفس هذا
+
+266
+00:23:59,760 --> 00:24:05,040
+اللي موجود هنا، لو أنا كتبته بهذه الصيغة CH3 C
+
+267
+00:24:05,040 --> 00:24:07,180
+double bond O و بعدين اعملت
+
+268
+00:24:14,200 --> 00:24:18,520
+هذا نفس هذا كاربون اتنين تلاتة اربعة خمسة كاربون
+
+269
+00:24:18,520 --> 00:24:22,000
+اتنين تلاتة اربعة خمسة و حملة أو أتش و هذا ممكن
+
+270
+00:24:22,000 --> 00:24:27,520
+نخليه هكذا بشكل انا انا صار واضح عندى ان هاي
+
+271
+00:24:27,520 --> 00:24:33,400
+الكهول و هاي كيتل بناء على ذلك شو التفاعل اللى
+
+272
+00:24:33,400 --> 00:24:39,040
+احنا بنتوقعه في هذه الحالة ان هذه بتهاجم هنا و هذه
+
+273
+00:24:40,430 --> 00:24:44,770
+بنتيجة هنا تصير OH فالنتج اللي بده يتكون بهذه
+
+274
+00:24:44,770 --> 00:24:52,910
+الحالة كنتج مرحلة في نص الطريق هذه
+
+275
+00:24:52,910 --> 00:25:04,480
+CH3 وهذه OH إذا هذا التفاعل عمل لكهيمي أسيتال هذا
+
+276
+00:25:04,480 --> 00:25:09,520
+التفاعل عمل هيمي أسيتال الآن راحوا لحقوا هذا
+
+277
+00:25:09,520 --> 00:25:13,960
+التفاعل بتفاعل تاني فعلوه كمان مرة مع الميثانون
+
+278
+00:25:15,000 --> 00:25:19,980
+ماذا تفعل الميثانول؟ تحل محل الـ OH وتطرد الـ OH و
+
+279
+00:25:19,980 --> 00:25:23,860
+تحل المحلة و تظهر النتج اللي عندكم إذا النتج اللي
+
+280
+00:25:23,860 --> 00:25:28,900
+عندكم هو نتاج خطوتين حقيقة التفاعل الأول اللي هو
+
+281
+00:25:28,900 --> 00:25:33,760
+الـ intramolecular reaction to form the hemiacetal
+
+282
+00:25:33,760 --> 00:25:38,540
+و بعد هيك ال substitution reaction to form the
+
+283
+00:25:38,540 --> 00:25:44,060
+acetalأول تفاعل Intramolecular هي الـ OH والـ C
+
+284
+00:25:44,060 --> 00:25:48,160
+double bond O في نفس الجزيء Intramolecular هذا
+
+285
+00:25:48,160 --> 00:25:51,720
+بنوصفه مظبوط ولا لا؟ بعد ذلك التفاعل التالي لما
+
+286
+00:25:51,720 --> 00:25:56,720
+أجيب هذا كله جزيء والميطانول جزيء This is
+
+287
+00:25:56,720 --> 00:26:01,500
+intramolecular reaction
+
+288
+00:26:01,500 --> 00:26:05,360
+واضح المثال هذا؟
+
+289
+00:26:08,510 --> 00:26:15,310
+بس بالتأكيد بيلزم تتدربوا عليه الآن المثال اللي
+
+290
+00:26:15,310 --> 00:26:24,930
+بعده شوية بدون ورقة وقلم انا بأكدلكوا انه صعب
+
+291
+00:26:24,930 --> 00:26:29,550
+انكوا تصلوله يعني لاحظوا كيف مرات الأمثلة بتكون
+
+292
+00:26:29,550 --> 00:26:36,050
+موجودة ومرسومة وإيش الناتج كيف هذا الناتج طلع من
+
+293
+00:26:36,050 --> 00:26:42,690
+هذا المثالأنا حقيقة بهذا المثال وببساطة عندي C
+
+294
+00:26:42,690 --> 00:26:51,330
+double bond O وعندي تنتين OH OH إذا هيتم تفاعل على
+
+295
+00:26:51,330 --> 00:26:57,770
+مرتين مرة مع ال OH الأولى ويعمل ليهمي أسيتال ومرة
+
+296
+00:26:57,770 --> 00:27:03,230
+مع ال OH التانية ويعمل أسيتال فقط اللي بيلزم فقط
+
+297
+00:27:03,230 --> 00:27:07,670
+اللي بيلزم عاد كيف نكون مرتبين الجزء بحيث نعمله
+
+298
+00:27:08,400 --> 00:27:12,480
+بالشكل الناتج اللي هو أنا الحلقة تانية يعني لو
+
+299
+00:27:12,480 --> 00:27:16,880
+أخدنا هذه ال carbon لو أخدنا هذه ال carbon اللي هي
+
+300
+00:27:16,880 --> 00:27:23,240
+السيضة بال bond السيضة بال bond O بهذا الشكل بعد
+
+301
+00:27:23,240 --> 00:27:27,080
+ذلك بدنا نتحرك بشكل متعاكس عشان نحط باقي ال carbon
+
+302
+00:27:27,080 --> 00:27:31,620
+كام carbon عندي غيرها؟ واحد اتنين تلاتة اربعة و ال
+
+303
+00:27:31,620 --> 00:27:43,850
+O هاي واحد اتنين تلاتة اربعةوهنا ال O هى O H هى ده
+
+304
+00:27:43,850 --> 00:27:50,630
+الجزء الآن على الجهة التانية على
+
+305
+00:27:50,630 --> 00:27:54,710
+الجهة التانية كام carbon عندى برضه اربعة واحد
+
+306
+00:27:54,710 --> 00:28:02,010
+اتنين تلاتة اربعة و
+
+307
+00:28:02,010 --> 00:28:02,830
+ال O هذه
+
+308
+00:28:08,700 --> 00:28:15,980
+أو أتش هذا نفس هذا بس غيرنا طريقة الرسم الآن لو
+
+309
+00:28:15,980 --> 00:28:19,220
+كنتوا تقولوا كيف تم التفاعل وممكن هذه عشان كمان
+
+310
+00:28:19,220 --> 00:28:24,580
+المنظر اللي خليكي بشكل مستقيم هاي أو أتش كيف بتم
+
+311
+00:28:24,580 --> 00:28:31,160
+التفاعل أول تفاعل هذه ال أو أتش بتهاجم هنا وهذه
+
+312
+00:28:31,160 --> 00:28:36,660
+بتصير أو أتش تاني تفاعلنعمله باللون الأزرق، هاي
+
+313
+00:28:36,660 --> 00:28:42,020
+أول تفاعل صار واضح، تاني تفاعل هذه الـ OH بتهاجم
+
+314
+00:28:42,020 --> 00:28:49,620
+هنا وبتطرد كل الـ OH اللي اتكونت هنا، صار النتيجة
+
+315
+00:28:52,470 --> 00:28:57,590
+هذا هو نفس هذا فقط طريقة الرسم اختلفت عندكم OH
+
+316
+00:28:57,590 --> 00:29:02,510
+بدأت تتفاعل لأول مرة و OH بدأت تتفاعل لتانى مرة
+
+317
+00:29:02,510 --> 00:29:07,150
+التفاعل على ايش؟ على مرتين هذه ال OH لما تتفاعل
+
+318
+00:29:07,150 --> 00:29:11,250
+بيصير عنده hemacetal التفاعل اللى ماشرله بالأحمر
+
+319
+00:29:11,250 --> 00:29:16,150
+بتيجى ال OH التانية بتطرد ال OH الأولى بتكون عند
+
+320
+00:29:16,150 --> 00:29:18,870
+ال acetal بيصير عند هذا المركب
+
+321
+00:29:22,460 --> 00:29:30,940
+أخر تفاعل سهل و بسيط بدل ما كان عندى ethylene
+
+322
+00:29:30,940 --> 00:29:38,880
+glycol OH OH ممكن استعمل التيو كومباوند الهو بدل
+
+323
+00:29:38,880 --> 00:29:46,120
+ال OH SH SH ما هي ال SH و ال OH بتفاعلوا زي بعض
+
+324
+00:29:46,120 --> 00:29:51,600
+الان كيف هذا التفاعل هنا تنتهي ال OHSأعطانا هذا
+
+325
+00:29:51,600 --> 00:29:55,100
+النتج تفاعله على مرتين نفس الشيء الـSH هاتيجي
+
+326
+00:29:55,100 --> 00:30:01,820
+تتفاعل هنا SS ولمّا يكون عنده جزايين هيتفاعلوها
+
+327
+00:30:01,820 --> 00:30:10,460
+هيتفاعلوها ملاحظين هاي هذا الجزء زي هذا الجزء
+
+328
+00:30:10,460 --> 00:30:16,480
+تماما فقط ال oxygen بدل ما هي oxygen صارت sulfur
+
+329
+00:30:16,480 --> 00:30:21,520
+الآن عندنا C double bond O تاني على الجهة هذهبنكرر
+
+330
+00:30:21,520 --> 00:30:28,860
+التفاعل على الجهة التانية، واضح؟ شوية هذه أمثلة
+
+331
+00:30:28,860 --> 00:30:35,770
+متطورة، هي الفكرة في الأورجان الكيميستريان انتوا
+
+332
+00:30:35,770 --> 00:30:39,770
+بتتعلموا التفاعل البسيط ان انتوا بتتعلموا التفاعل
+
+333
+00:30:39,770 --> 00:30:44,310
+البسيط اذا أتقنتوا بعدك لو حطناها في مكان كبير
+
+334
+00:30:44,310 --> 00:30:49,230
+وواسع مع جزائي كبير زي هيك بتغير التفاعل البسيط؟
+
+335
+00:30:49,230 --> 00:30:54,290
+مابتغيرش يعني هذا التفاعل هو نفس التفاعل كل هذه
+
+336
+00:30:54,290 --> 00:30:57,170
+نفس التفاعلات البسيطة اللي أخدناها بس هنا الجزيات
+
+337
+00:30:57,170 --> 00:31:02,690
+إيش مالها؟كبرت، زي أي إنسان أو إنسانة مثلا بتعلم
+
+338
+00:31:02,690 --> 00:31:07,050
+سواج السيارات، هو بتعلمهم بشوارع صغار في منطقة
+
+339
+00:31:07,050 --> 00:31:10,470
+هادئة، الآن هيدلوا طول عمره بشوارع صغار في منطقة
+
+340
+00:31:10,470 --> 00:31:13,910
+هادئة؟ ولا لو بعتناه بعد ذلك على الـNew York، بده
+
+341
+00:31:13,910 --> 00:31:19,570
+يعرف يسوج السيارة فيها؟هي نفس المبادئ، مظبوط؟
+
+342
+00:31:19,570 --> 00:31:23,630
+فانتوا في الأول بتتعلموا المبادئ وهنا بيصير انه
+
+343
+00:31:23,630 --> 00:31:27,310
+يعني كيف الكيميا هي علم بيكبر و علم أبحاث انه
+
+344
+00:31:27,310 --> 00:31:30,850
+انتوا اللي زيكوا بياخد المبادئ طب طالب الماجستير
+
+345
+00:31:30,850 --> 00:31:36,630
+شو بيعمل؟ بيروح على جزايين اكبار كتير و بفاعل OH
+
+346
+00:31:36,630 --> 00:31:40,130
+مع C double bond O و بيعمل hemacetal بس المشكلة ان
+
+347
+00:31:40,130 --> 00:31:45,360
+الجزايين اللي بيشتغل فيهم اكبار، لكن التفاعلهو
+
+348
+00:31:45,360 --> 00:31:50,760
+اللي درسوا بسنة أولى عشان هيك يعني بيكفى بيكفى
+
+349
+00:31:50,760 --> 00:31:55,200
+لطلاب مثلا التربية أو اللي هم التحاليل الطبية أنه
+
+350
+00:31:55,200 --> 00:31:58,780
+احنا نعطيهم مساق واحد مبادئ زي بني أدم علمناه يسوق
+
+351
+00:31:58,780 --> 00:32:04,900
+سيارة بعد هيك لو حضرتوا مؤتمر كيميا هتلاقوا أنه
+
+352
+00:32:04,900 --> 00:32:09,060
+الإنسان اللي بيشرح مثلا ممكن يمر عليه كيف تعملوا
+
+353
+00:32:09,060 --> 00:32:13,140
+hemacetal لكن بيكون الجزيئات اللي بتعامل معها
+
+354
+00:32:13,990 --> 00:32:19,970
+جزيئات كبيرة جزيئات كبيرة ولا البنا اللي بيبني
+
+355
+00:32:19,970 --> 00:32:24,750
+البرج مش هو نفسه اللي بتترب على بنا حيطة مظبوط ولا
+
+356
+00:32:24,750 --> 00:32:29,270
+لأ؟ وهذا هو اللي بيصير هنا انه جد ما تكبر الجزيئات
+
+357
+00:32:29,270 --> 00:32:34,070
+لكن المبدأ هذا اللي احنا قاعدين بنقشر عليه اتغير
+
+358
+00:32:34,070 --> 00:32:42,170
+hemacetal بعدين acetal addition بعدين substitution
+
+359
+00:32:42,170 --> 00:32:43,610
+ولو الجزيئة
+
+360
+00:32:58,740 --> 00:33:03,340
+الان على نفس المبدأ بناخد الـ nucleophile تاني
+
+361
+00:33:03,340 --> 00:33:10,140
+يعني مش معقول الحصة كلها بس نضيع على الكحول يعني
+
+362
+00:33:10,140 --> 00:33:13,260
+لو أتينا بعد كل هالتعب بدنا نقول إيش اللي أخدته
+
+363
+00:33:14,520 --> 00:33:20,380
+بسطر واحد الكحول بيعمل addition و يتبع في
+
+364
+00:33:20,380 --> 00:33:24,680
+substitution خلصنا مافيش اكتر من هيك الان ال
+
+365
+00:33:24,680 --> 00:33:28,120
+addition of hydrogen cyanide ال hydrogen cyanide
+
+366
+00:33:28,120 --> 00:33:32,060
+النيوكليوفايل اللي فيه اللي بتفعل في النهاية هو ال
+
+367
+00:33:32,060 --> 00:33:37,180
+CN و بتفعل من خلال الكربون الان نفس التفاعل تماما
+
+368
+00:33:37,180 --> 00:33:44,750
+ال CN بده تهاجم و ال O بده تصير OHالـCN بدأ تهاجم
+
+369
+00:33:44,750 --> 00:33:50,130
+والـO بدأ تصير OH الان لو اتينا واطلعنا مثلا هنا
+
+370
+00:33:50,130 --> 00:33:54,270
+هذا أسيتون هذا أسيتالديهيد لاحظوا التفاعل بتكرر
+
+371
+00:33:54,270 --> 00:33:59,950
+ولو الجزيئات اشمالها بتكبر هاي الـCN بتهاجم والـO
+
+372
+00:33:59,950 --> 00:34:05,110
+بتصير OH أو التفاعل أسيتالديهيد اللي بعده أسيتون
+
+373
+00:34:05,110 --> 00:34:11,210
+طب هذا Cyclohexanone نفس الفكرة تماما الـCN بتهاجم
+
+374
+00:34:12,020 --> 00:34:17,220
+و ال O بتصير OH الان لازم تكونوا متأكدين 100% انه
+
+375
+00:34:17,220 --> 00:34:20,920
+انا لو بدأ اسألكوا في الامتحان لأ هجيب
+
+376
+00:34:20,920 --> 00:34:26,900
+Acetaldehyde ولا Acetone ولا Cyclohexanone لإن
+
+377
+00:34:26,900 --> 00:34:31,520
+انا علمتكوا مبدأ مش علمتكوا جزاء لإن انا علمتكوا
+
+378
+00:34:31,520 --> 00:34:36,480
+مبدأ الان لو اجيت جبتلكوا مثل زي C double bond OH
+
+379
+00:34:36,480 --> 00:34:44,080
+CH2 و حطيت هنا بنزينةو حطيت هنا cl و حطيت هنا ch3
+
+380
+00:34:44,080 --> 00:34:53,300
+و بعدين قلتلكم مع ال hcn و
+
+381
+00:34:53,300 --> 00:35:00,540
+لو الجزء كبر لكن التفاعل المبدأ نفسه ان هذي بتهاجم
+
+382
+00:35:01,530 --> 00:35:04,890
+وهذا يحصل في بعض الأحيان، ونضع النتجة المشكلة
+
+383
+00:35:04,890 --> 00:35:09,990
+الكتير عندكم مرات ان انتوا ماانتبهتوش للرؤوس
+
+384
+00:35:09,990 --> 00:35:16,490
+المتفاعلة دائما في الكيميا، ما تخافوش من الجزء
+
+385
+00:35:16,490 --> 00:35:21,320
+الكبيرأهم شيء في الجزية الكبيرة أن تفهموا أين
+
+386
+00:35:21,320 --> 00:35:24,180
+الرأس اللي بدي يتفاعل فيه انتوا عندكوا هنا CL
+
+387
+00:35:24,180 --> 00:35:28,480
+وعندكوا هنا C double bond O بس هدولة الرأسين اللي
+
+388
+00:35:28,480 --> 00:35:33,060
+بتفاعلوا زي ما نيجي نقول و الله عملية المصافحة إيش
+
+389
+00:35:33,060 --> 00:35:37,800
+عملية المصافحة التقاء التان تان تان الان ممكن
+
+390
+00:35:37,800 --> 00:35:42,490
+المصافحة تكون بين طفلينممكن تكون بين طفل وإنسان
+
+391
+00:35:42,490 --> 00:35:46,910
+كبير، ممكن تكون بين زعيمين بيوضعوا بعض قبل ما
+
+392
+00:35:46,910 --> 00:35:53,010
+يفقدوا العرش، كله ممكن، واضح؟ الان لاحظوا حتى في
+
+393
+00:35:53,010 --> 00:35:57,930
+التسمية، الان هذا Acetaldehyde بيعطيني Cl و OH،
+
+394
+00:35:57,930 --> 00:36:01,930
+هذه المجموعة اللي فيها المركبات اللي حاملة على
+
+395
+00:36:01,930 --> 00:36:07,810
+الكربون الواحدة Cl و OH بيسموها cyanohydrins
+
+396
+00:36:08,620 --> 00:36:13,060
+فالمُركّب إذا كان أصله Acetaldehyde هانا تسميه على
+
+397
+00:36:13,060 --> 00:36:17,520
+إيش؟ على الأصل إذا أصله Acetaldehyde بنسميه
+
+398
+00:36:17,520 --> 00:36:26,580
+Acetaldehyde و بنضيف عليه Cyanohedrin
+
+399
+00:36:26,580 --> 00:36:30,060
+Acetaldehyde
+
+400
+00:36:30,060 --> 00:36:35,840
+Cyanohedrin إيش يعني Cyanohedrin؟ إنه على الكربون
+
+401
+00:36:35,840 --> 00:36:42,750
+موجود عندي CNو OH فالأصل Acetaldehyde لما اتفعل مع
+
+402
+00:36:42,750 --> 00:36:46,610
+ال HCN أعطاني Acetaldehyde-Cyanohydride الأن
+
+403
+00:36:46,610 --> 00:36:53,510
+المركب التالي كلكوا هيتسموه بسهولة شو هيكون اسمه؟
+
+404
+00:36:53,510 --> 00:37:03,190
+أسيتون سيانوهيدرين المركب التالت هذا
+
+405
+00:37:05,160 --> 00:37:10,420
+Cyclohexanone بنقولش Cyclohexane ممكن واحدة لما
+
+406
+00:37:10,420 --> 00:37:13,720
+تيجي تسميه هنا تشوف هذا Cyclohexane وين
+
+407
+00:37:13,720 --> 00:37:17,260
+Cyclohexanone هذا Cyclohexanone تروح تسميه
+
+408
+00:37:17,260 --> 00:37:20,720
+Cyclohexane-Cyanohydrin لأ احنا بنسميه
+
+409
+00:37:20,720 --> 00:37:26,660
+Cyclohexanone طب فيه هنا Cyclohexanone نسبة للأصل
+
+410
+00:37:26,660 --> 00:37:32,240
+Cyclohexanone-Cyanohydrin هذا أخر مركب اللي موجود
+
+411
+00:37:32,240 --> 00:37:32,580
+هنا
+
+412
+00:37:36,320 --> 00:37:47,700
+شو اسم هذا المُركّب؟ بنزين بقالدهايد بنزالدهايد
+
+413
+00:37:47,700 --> 00:37:52,660
+بنزالدهايد
+
+414
+00:37:52,660 --> 00:37:55,840
+سيانوهيدرين بنزالدهايد بنزالدهايد سيانوهيدرين و لو
+
+415
+00:37:55,840 --> 00:38:00,880
+هذه صارت CH3 لو
+
+416
+00:38:00,880 --> 00:38:05,740
+هذه صارت CH3 هيصير أسيتوفينون
+
+417
+00:38:07,050 --> 00:38:11,550
+Cyanohydrin إذا أنا زي ما بتلاحظوا بتعلم قواعد
+
+418
+00:38:11,550 --> 00:38:16,690
+عامة سواء في التفاعل أو حتى في نظام التسمية
+
+419
+00:38:16,690 --> 00:38:21,910
+والقواعد العامة جاعدة بتتكرر ولا لأ نفس المنطق
+
+420
+00:38:21,910 --> 00:38:26,670
+يعني أنا أنا بعيد نفس المنطق في كل الأحوال هذه حتى
+
+421
+00:38:26,670 --> 00:38:31,450
+طريقة التسمية أنه أنا بسمل الديهايد أو ال ketone و
+
+422
+00:38:31,450 --> 00:38:35,090
+باتبعه بكلمات cyanohydrin
+
+423
+00:38:43,950 --> 00:38:46,450
+خلاص اليوم صيف الله يعطيكوا العافية
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs.srt
new file mode 100644
index 0000000000000000000000000000000000000000..5a77a20092083fe9cac93d4efb23e0f0f89643a0
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs.srt
@@ -0,0 +1,1838 @@
+1
+00:00:10,440 --> 00:00:15,720
+اليوم إن شاء الله بدنا نستمر في الفصل السادس الذي 
+
+2
+00:00:15,720 --> 00:00:19,280
+كان عنوانه،  و أعطينا فيه مقدمة صغيرة إذا بتذكروا
+
+3
+00:00:19,280 --> 00:00:23,640
+Alkyl Halides طبعًا بتذكروا قلنا الـ Alkyl Halides
+
+4
+00:00:23,640 --> 00:00:28,820
+المركبات التي هي R X والـ X عبارة عن Halogen،
+
+5
+00:00:28,960 --> 00:00:35,880
+Chlor, Brom, Iodine, Fluor هذه المركبات هناخد إليها 
+
+6
+00:00:36,530 --> 00:00:40,930
+نوعين أساسيين من التفاعلات إما تفاعلات الإبدال
+
+7
+00:00:40,930 --> 00:00:45,330
+substitution يعني نشيل الـ X ونحط بدالها حاجة
+
+8
+00:00:45,330 --> 00:00:50,790
+ثانية أو تفاعلات ثانية بنسميها elimination تفاعلات
+
+9
+00:00:50,790 --> 00:00:55,470
+الحذف،  الذي يخصه بتفاعلات الحذف أنه بنشيل الـ X مع
+
+10
+00:00:55,470 --> 00:01:00,150
+Hydrogen، ونكون Double bond يعني بيصير عنده الـ
+
+11
+00:01:00,150 --> 00:01:06,790
+Alkene واضح؟ فتفاعلات الحذف بيصير إننا إيش الـ Alkyl
+
+12
+00:01:06,790 --> 00:01:11,970
+الـ مرة الماضية تعرّفنا على أنواع الـ Alkyl Halides
+
+13
+00:01:11,970 --> 00:01:16,250
+قلنا الـ Alkyl Halides ممكن نصنفهم إلى Primary أو
+
+14
+00:01:16,250 --> 00:01:22,310
+Secondary أو Tertiary تعرّفنا على إنّ الـ Carbon
+
+15
+00:01:22,310 --> 00:01:27,030
+Halogen bond is generally a polar bond  أنه أقوى 
+
+16
+00:01:27,030 --> 00:01:32,520
+رابطة هي الرابطة التي مع الـ Fluor، وأن أضعف رابطة 
+
+17
+00:01:32,520 --> 00:01:37,300
+هي الرابطة التي مع اليود وبناءً على ذلك وصلنا إلى
+
+18
+00:01:37,300 --> 00:01:43,080
+أنّ التفاعل أسرع ما يمكن بتتم مع اليود لأنه ممكن 
+
+19
+00:01:43,080 --> 00:01:48,460
+ينكسر بسهولة، وبعده الـ Brom، وبعده الـ Chlor،  واضح؟ لأنّ
+
+20
+00:01:48,460 --> 00:01:53,620
+في الحالتين سواء أنا كنت بدأ أعمل تفاعل إبدال لازم
+
+21
+00:01:53,620 --> 00:01:59,320
+أشيل الـ X واضح؟ ولو بدأت أعمل تفاعل حذف، بده يشيل
+
+22
+00:01:59,320 --> 00:02:04,100
+الـ X مع هيدروجين، فبالحالتين لازم إنّ هذه الـ X يصير 
+
+23
+00:02:04,100 --> 00:02:09,180
+لها Bond breaking، تنكسر الرابطة بتاعتها، واضح؟
+
+24
+00:02:09,180 --> 00:02:13,040
+فإيش الذي ينكسر دائمًا؟ الرابطة القوية ولا الرابطة
+
+25
+00:02:13,040 --> 00:02:16,800
+الضعيفة؟ الضعيفة، وهذا كلام منطقي، يعني ما بتحسوش 
+
+26
+00:02:16,800 --> 00:02:24,760
+إنّ في مشاكل، الآن هنبدأ درسنا الجديد الذي بنسميه
+
+27
+00:02:24,760 --> 00:02:29,040
+نحن الـ Nucleophilic substitution in general أنّ
+
+28
+00:02:29,040 --> 00:02:36,410
+الذي بده يهاجم على الـ RX لازم يكون Nucleophile سبق
+
+29
+00:02:36,410 --> 00:02:39,810
+إنّه ربما عرفنا شيء الذي نقصده نحن بالـ New 
+
+30
+00:02:39,810 --> 00:02:44,790
+Cleophile الذي هو عبارة عن Species أو أشياء أما
+
+31
+00:02:44,790 --> 00:02:50,450
+بيحمل شحنة سالبة أو إلكترونات في كل الأحوال لازم 
+
+32
+00:02:50,450 --> 00:02:56,070
+يكون عليه أزواج من الإلكترونات،  يعني هو يمثل كثافة
+
+33
+00:02:56,070 --> 00:03:02,270
+إلكترونية، يمكن هذا الـ Nucleophile أن يكون مشحونًا 
+
+34
+00:03:02,270 --> 00:03:07,950
+يعني تظهر عليه الشحنة السالبة، ويمكن أن يكون متعادلًا
+
+35
+00:03:07,950 --> 00:03:13,310
+لو بدنا نأخذ أمثلة مثلًا الـ OH- هذا الشكل تبعها الـ
+
+36
+00:03:13,310 --> 00:03:19,560
+Structure للـ OH- فبتلاحظوا هنا إيش بتكون مشحونة
+
+37
+00:03:19,560 --> 00:03:25,340
+تظهر عليها شحنة سالبة، ويوجد على الأكسجين عدة أزواج 
+
+38
+00:03:25,340 --> 00:03:29,540
+من الإلكترونات، لما بتتم التفاعل بتتم التفاعل من خلال
+
+39
+00:03:29,540 --> 00:03:35,200
+الهجوم من أزواج الإلكترونات، كذلك الحالة لو بتطلع 
+
+40
+00:03:35,200 --> 00:03:42,360
+على الـ CN- برضه بتكون مشحونة وهيعد أزواج إلكترونات 
+
+41
+00:03:42,360 --> 00:03:46,500
+على الكربون، ويتم التفاعل على إيش؟ الكربون، بمعنى
+
+42
+00:03:46,500 --> 00:03:51,720
+هنا الذرة المهاجمة أي ذرة؟ الأكسجين، هنا الذرة 
+
+43
+00:03:51,720 --> 00:03:56,340
+المهاجمة أي ذرة؟ الكربون طبعًا ما في شيء في الدنيا
+
+44
+00:03:56,340 --> 00:04:03,310
+نباع ونشره بصيغة سالبة، هذه عبارة عن مركبات
+
+45
+00:04:03,310 --> 00:04:08,730
+أيونيّة بشكل عام متعادلة لكن عندما ندوّبها تفصل إلى
+
+46
+00:04:08,730 --> 00:04:13,210
+أيونين مثلًا OH- ممكن يأتي من الـ Sodium Hydroxide
+
+47
+00:04:13,210 --> 00:04:19,070
+بيكون عندنا NA+, OH-, الخلاصة إنّه يوفر للـ Sodium 
+
+48
+00:04:19,070 --> 00:04:25,750
+Hydroxide OH-, CN-, ممكن يأتي من مركب Sodium
+
+49
+00:04:25,750 --> 00:04:28,250
+Cyanide NA+, 
+
+50
+00:04:34,350 --> 00:04:44,430
+الشحنة السالبة بيحمل شحنة نيوكليوفيل سالبة، يمكن
+
+51
+00:04:44,430 --> 00:04:50,710
+إنّ الشحنة يكون متعادل،  ما يحملش شحنة، لكن
+
+52
+00:04:50,710 --> 00:04:55,310
+يوجد عليه أزواج إلكترونات، يتفاعل من خلالها من
+
+53
+00:04:55,310 --> 00:05:02,040
+أمثلة الـ Neutral Nucleophiles المشهورة الماء الـ
+
+54
+00:05:02,040 --> 00:05:07,300
+H2O إذا بتطلع هي O H H وكلّكم عارفين أنّ الماء
+
+55
+00:05:07,300 --> 00:05:11,220
+فيها كم زوج من الإلكترونات؟ زوجين من الإلكترونات
+
+56
+00:05:11,220 --> 00:05:14,260
+لو بتطلع على الـ Polarity من الـ Electronegative 
+
+57
+00:05:14,260 --> 00:05:17,900
+يتقع على الأكسجين ولا الهيدروجين؟ إذا كأنّه صار عند
+
+58
+00:05:17,900 --> 00:05:23,280
+الرأس Partially negative،  برضه هنا التفاعل من خلال
+
+59
+00:05:24,590 --> 00:05:28,550
+زوج الإلكترونات الموجودة على الأكسجين، لو بدنا نطلع
+
+60
+00:05:28,550 --> 00:05:32,950
+على الأمونيا مثلًا NH3 كلّكم تتذكروا أنّ 
+
+61
+00:05:32,950 --> 00:05:38,050
+الأمونيا بإيش كانت تمتاز؟ بزوج الإلكترونات الذي
+
+62
+00:05:38,050 --> 00:05:43,570
+موجودة على النيتروجين، وبناءً على ذلك النيتروجين هي
+
+63
+00:05:43,570 --> 00:05:46,750
+التي بتكون Partially negative،  فالأمونيا بتتفاعل من
+
+64
+00:05:46,750 --> 00:05:51,330
+خلال زوج الإلكترونات،  لاحظوا وين في عندي زوج
+
+65
+00:05:51,330 --> 00:05:54,690
+الإلكترونات هتيجي الرابطة الجديد لما يتم التفاعل
+
+66
+00:05:54,690 --> 00:05:59,570
+يعني هنا الرابطة هتكون مع الـ Oxygen،  هنا مع الـ
+
+67
+00:05:59,570 --> 00:06:04,810
+Carbon،  هنا مع الـ Oxygen، هنا مع الـ Nitrogen، هدول هم
+
+68
+00:06:04,810 --> 00:06:08,930
+النوعين خلينا نقول من الـ Nucleophiles التي بيمروا
+
+69
+00:06:08,930 --> 00:06:14,070
+علينا الذي هم الـ Charged Nucleophiles والـ Neutral
+
+70
+00:06:14,070 --> 00:06:22,470
+Nucleophiles، الآن عندما ندرس التفاعلات سواء تفاعلات
+
+71
+00:06:22,470 --> 00:06:31,690
+الحذف أو الإبدال، ستلاحظون أنّ هناك شيئين في معادلة 
+
+72
+00:06:31,690 --> 00:06:39,110
+التفاعل،  هناك الـ Nucleophile وهناك الـ RX وبناءً 
+
+73
+00:06:39,110 --> 00:06:43,790
+على ذلك نتيجة التفاعل مرتبطة بخواص هذولة الـ RX 
+
+74
+00:06:43,790 --> 00:06:48,570
+ربما تتذكرون أنّ قلنا عنهم ممكن يكون Primary أو 
+
+75
+00:06:48,570 --> 00:06:52,310
+Secondary أو Tertiary،  هذه المعلومة هتلزمنا لما 
+
+76
+00:06:52,310 --> 00:06:57,590
+نفهم التفاعل بشكل أعمق،  الآن الـ Nucleophiles تصنف
+
+77
+00:06:57,590 --> 00:07:03,690
+إلى نوعين،  وحسب نوع الـ Nucleophile برضه بيصير إيش 
+
+78
+00:07:03,690 --> 00:07:09,090
+التفاعل،  هتلاحظوا إنّه نحن بنقول الـ Nucleophiles يا
+
+79
+00:07:09,090 --> 00:07:15,240
+إما بيكونوا Strong أقوياء يا إما بيكونوا Weak،  إذا
+
+80
+00:07:15,240 --> 00:07:19,280
+تصنيف الـ Nucleophile هتلاقونا دائمًا بنحكيلكم This
+
+81
+00:07:19,280 --> 00:07:23,260
+is a Strong Nucleophile، This is a Weak Nucleophile 
+
+82
+00:07:23,260 --> 00:07:29,560
+إذا المفروض فينا كمرحلة أولى نعرف في شوية تغيير في
+
+83
+00:07:29,560 --> 00:07:32,560
+الـ Slides كلها موجودة بعد Slideين تلاتة،  هنا معظم
+
+84
+00:07:32,560 --> 00:07:37,100
+الـ Slides أنا غيرتها بس بلزمكم مش تنسخوا من أول وجديد يعني إذا بتجلبوا بتلاقوا Strength of 
+
+85
+00:07:37,100 --> 00:07:39,840
+Nucleophiles وما إلى ذلك، واضح؟ شوية بس عشان يعني
+
+86
+00:07:39,840 --> 00:07:45,880
+سهولة أو تتابع الشرح هتلاقي إنّه في Slide أو جزء من
+
+87
+00:07:45,880 --> 00:07:50,260
+الـ Slide يجي قبل الثاني واضح؟ اه فبيهمّني أنا إنّ
+
+88
+00:07:50,260 --> 00:07:56,180
+أكون بسهولة أعرف الـ Nucleophile هل هو Strong أو
+
+89
+00:07:56,180 --> 00:08:01,100
+Weak ولو كان عندي Two Nucleophiles إنّ هو فيهم
+
+90
+00:08:01,100 --> 00:08:05,620
+أقوى من الثاني، واضح؟ الآن بشكل عام نحن بنقول إنّ
+
+91
+00:08:13,220 --> 00:08:17,360
+الـ Charged Nucleophiles التي عليها شحنة سالبة 
+
+92
+00:08:17,360 --> 00:08:22,550
+كاملة They are stronger than Neutral ones يعني لما
+
+93
+00:08:22,550 --> 00:08:26,970
+يكون عند Nucleophile ليش نحن سالبة هو دائمًا،  و
+
+94
+00:08:26,970 --> 00:08:33,970
+أبدأ أقوى من الـ Nucleophile المتعادل مثلًا الـ OH- والـ
+
+95
+00:08:33,970 --> 00:08:38,150
+H2O هدول اثنين لما يصير تفاعل إبدال بيحطوا 
+
+96
+00:08:38,150 --> 00:08:43,670
+مجموعة الـ OH إنّه هو أقوى فيهم كـ Nucleophile بالـ OH-
+
+97
+00:08:43,670 --> 00:08:50,470
+أقوى من الـ H2O كذلك الحالة الـ Ethyl O- بنسميه
+
+98
+00:08:50,470 --> 00:08:58,450
+إثوكسايد،  هذا الـ OH- إيش اسمه؟ الـ OH- هيدروكسايد 
+
+99
+00:08:58,450 --> 00:09:03,860
+هنا لما يصير إثل شو بيصير اسمه؟ إثوكسايد،  إذا كان
+
+100
+00:09:03,860 --> 00:09:05,900
+مثل الـ O-, إذا كان مثل الـ O-, إذا كان مثل الـ
+
+101
+00:09:05,900 --> 00:09:06,920
+O-, إذا كان مثل الـ O-, إذا كان مثل الـ O-, إذا
+
+102
+00:09:06,920 --> 00:09:06,940
+كان مثل الـ O-, إذا كان مثل الـ O-, إذا كان مثل
+
+103
+00:09:06,940 --> 00:09:11,240
+الـ O-, إذا كان مثل الـ O-, إذا كان مثل الـ O-,
+
+104
+00:09:11,240 --> 00:09:12,880
+إذا كان مثل الـ O-, إذا كان مثل الـ O-, إذا كان
+
+105
+00:09:12,880 --> 00:09:13,220
+مثل الـ O-, إذا كان مثل الـ O-, إذا كان مثل الـ
+
+106
+00:09:13,220 --> 00:09:13,260
+O-, إذا كان مثل الـ O-, إذا كان مثل الـ O-, إذا
+
+107
+00:09:13,260 --> 00:09:14,340
+كان مثل الـ O-, إذا كان مثل الـ O-, إذا كان مثل
+
+108
+00:09:14,340 --> 00:09:18,740
+الـ O-, إذا كان مثل الـ O-, إذا كان مثل الـ O-,
+
+109
+00:09:18,740 --> 00:09:21,880
+إذا
+
+110
+00:09:21,880 --> 00:09:28,280
+كان مثل الـ O-, إذا كان مثل الـ O-, أو لو كانت مع
+
+111
+00:09:28,280 --> 00:09:33,100
+صوديوم بيكون اسم المركب Sodamate، بتكون أقوى من
+
+112
+00:09:33,100 --> 00:09:36,980
+الأمونيا، إذا هل القاعدة الأولى في قوة
+
+113
+00:09:36,980 --> 00:09:41,220
+الـ Nucleophile؟ إنّه لو عند Nucleophile بشكل عام نفس
+
+114
+00:09:41,220 --> 00:09:48,020
+الذرات، بدو يكون الـ Charged أقوى من الـ Neutral،
+
+115
+00:09:48,020 --> 00:09:51,940
+واضح؟ الـ Charged Nucleophile are stronger than
+
+116
+00:09:51,940 --> 00:09:58,210
+Neutral Nucleophiles، النقطة الأولى لو إجينا بدنا 
+
+117
+00:09:58,210 --> 00:10:03,410
+نشوف قوة الـ Nucleophile حسب تحركنا في الجدول 
+
+118
+00:10:03,410 --> 00:10:07,850
+الدوري، إذا بتذكروا، واضح دائمًا نحن كنا نعمل
+
+119
+00:10:07,850 --> 00:10:13,750
+المقارنات، ونتخيل أنّ الجدول الدوري بهذا الشكل، الآن
+
+120
+00:10:13,750 --> 00:10:19,730
+كيف بتزيد قوة الـ Nucleophile لما بتعمل مقارنة دائمًا
+
+121
+00:10:19,730 --> 00:10:24,530
+أو ابدأ انتبهوا إذا بتقارنوا Charged Nucleophile
+
+122
+00:10:24,530 --> 00:10:29,690
+مع Charged Nucleophile أو Neutral Nucleophile مع
+
+123
+00:10:29,690 --> 00:10:32,610
+Neutral Nucleophile، سواء بتكون تتحركوا عبر
+
+124
+00:10:32,610 --> 00:10:39,130
+المجموعة أو عبر الدورة، الـ Nucleophilicity بتزيد بهذا 
+
+125
+00:10:39,130 --> 00:10:44,770
+الشكل كلما اتجهنا إلى اليسار، وبتزيد بهذا الشكل
+
+126
+00:10:44,770 --> 00:10:50,110
+كلما اتجهنا إلى أسفل، واضح؟ بهذا الشكل بتزيد
+
+127
+00:10:50,110 --> 00:10:55,570
+الـ Nucleophilicity، الآن لو بدكم تحاولوا تتذكروا الذرات
+
+128
+00:10:55,570 --> 00:10:59,310
+الأساسية في الجدول الدوري، كلّكم تتذكرون أنّ في
+
+129
+00:10:59,310 --> 00:11:03,910
+الجدول الدوري كان عندي Carbon، Nitrogen، Oxygen 
+
+130
+00:11:03,910 --> 00:11:04,710
+Fluor
+
+131
+00:11:14,390 --> 00:11:19,390
+الأساسية جدًا في الجدول الدوري، الآن لو إجيت أقارن 
+
+132
+00:11:19,390 --> 00:11:25,900
+الـ Nitrogen والـ Nucleophile في Oxygen، هو أقارن الـ
+
+133
+00:11:25,900 --> 00:11:29,440
+Ammonia مع الماء، لاحظوا هنا في المقارنة كيف الـ
+
+134
+00:11:29,440 --> 00:11:34,580
+Ammonia متعادلة، والماء متعادلة، لكن أيّهم أقوى كان 
+
+135
+00:11:34,580 --> 00:11:40,120
+Nucleophile؟ الـ Nitrogen،  التي هي الـ Ammonia أقوى
+
+136
+00:11:40,120 --> 00:11:47,120
+من الماء، الآن لو إجيت بدي أقارن Nitrogen و Oxygen 
+
+137
+00:11:47,120 --> 00:11:53,660
+مرة ثانية، لكن بدي أقارن الأيونات السالبة بتاعتها، إن
+
+138
+00:11:53,660 --> 00:11:59,040
+أيه همّا أقوى الـ NH2 minus ولا الـ OH minus
+
+139
+00:11:59,040 --> 00:12:08,080
+انتبهوا معي، قارن متعادل متعادل أو مشحون ومشحون، طيب
+
+140
+00:12:08,080 --> 00:12:12,140
+لو بدي أنزل في المجموعة،  خليني أفرض الماء إيش
+
+141
+00:12:12,140 --> 00:12:19,160
+بتعمل؟ H2O المتعادل تبعها الكبريت H2S، أيّهما أقوى 
+
+142
+00:12:19,160 --> 00:12:24,520
+كـ Nucleophile؟ H2S is stronger than H2O،  أنا بقول كل ما
+
+143
+00:12:24,520 --> 00:12:28,840
+بنزل لتحت الـ Strength of a Nucleophile increases
+
+144
+00:12:28,840 --> 00:12:34,790
+طيب لو بدي أقارن الـ OH- مع إيش بدي أقارنها؟ مع الـ SH
+
+145
+00:12:34,790 --> 00:12:41,430
+minus،  أيّهما أقوى؟ الـ SH minus is stronger than OH
+
+146
+00:12:41,430 --> 00:12:48,470
+minus،  SH minus is stronger than OH minus،  واضح هذا 
+
+147
+00:12:48,470 --> 00:12:53,750
+فاهم، الـ Strength of Nucleophiles بيفيدنا أثناء
+
+148
+00:12:53,750 --> 00:12:56,530
+دراسة التفاعلات،  فمن الأول والطالع إذا بنقول This
+
+149
+00:12:56,530 --> 00:12:59,630
+is a Strong Nucleophile،  or Weak Nucleophile، or
+
+150
+00:12:59,630 --> 00:13:03,290
+This is stronger than the other one،  المفروض تكونوا 
+
+151
+00:13:04,040 --> 00:13:12,300
+فاهمين،  همّ وإحنا؟ بنحكي الآن التفاعل الأساسي، يمكن 
+
+152
+00:13:12,300 --> 00:13:15,160
+الـ Slide عندكم على الورق تكون واضحة، وموجودة في 
+
+153
+00:13:15,160 --> 00:13:21,220
+الكتاب، التفاعل 
+
+154
+00:13:21,220 --> 00:13:28,080
+الأساسي في الـ Alkyl Halides هو تفاعل الـ
+
+155
+00:13:28,080 --> 00:13:31,900
+Substitution الذي هو ببساطة إنّ أنا عند الـ
+
+156
+00:13:31,900 --> 00:13:33,060
+Nucleophile
+
+157
+00:13:45,090 --> 00:13:48,690
+هذه المعادلة الأساسية 
+
+158
+00:13:57,050 --> 00:14:01,030
+بدأ تصير الـ R بدل ما هي متصلة بـ X متصلة بإيش؟
+
+159
+00:14:01,030 --> 00:14:04,370
+بالـ Nucleophile، الـ .. شفته قبل شوية الـ OH
+
+160
+00:14:04,370 --> 00:14:10,330
+والماء؟ اه ممكن يكون Nitrogen ممكن يكون Carbon 
+
+161
+00:14:10,330 --> 00:14:16,970
+ممكن يكون Sulfur ممكن يكون Halogen كلّ هذه عبارة عن
+
+162
+00:14:16,970 --> 00:14:23,550
+احتمالات أكثر من الـ Nucleophile، كلّ هذه عبارة عن
+
+163
+00:14:23,550 --> 00:14:29,980
+احتمالات أكثر من الـ Nucleophile، فإذا مثلًا أنا بدي
+
+164
+00:14:29,980 --> 00:14:36,060
+أشوف أنواع الـ Oxygen in Nucleophiles،  مرّ علينا قبل
+
+165
+00:14:36,060 --> 00:14:43,950
+شوية الـ OH- الـ Hydroxide Anion اه ومرّ علينا الـ OR
+
+166
+00:14:43,950 --> 00:14:55,190
+minus زي إثل O minus فالـ RO minus is Alkoxide،  مرّ
+
+167
+00:14:55,190 --> 00:15:03,470
+علينا الماء H2O هذه Neutral، مرّ علينا الكحول ROH 
+
+168
+00:15:03,470 --> 00:15:09,290
+هذه برضه Neutral،  Neutral
+
+169
+00:15:11,850 --> 00:15:20,650
+ممكن يكون عندك كربوكسيلات أنيون زي أيون الأسيتات
+
+170
+00:15:20,650 --> 00:15:25,290
+إذا ماذا ذاكرين، ومرّ عليكم في الأسيتك أسيد،  وصوديوم 
+
+171
+00:15:25,290 --> 00
+
+201
+00:18:10,990 --> 00:18:16,330
+محل الـ CL الـ iodide ممكن يكون عنده carbon
+
+202
+00:18:16,330 --> 00:18:21,610
+nucleophiles يعني الرأس تبع التفاعل هو إيش carbon
+
+203
+00:18:21,610 --> 00:18:28,070
+تومر عليا الـ CN minus رسمنا شكله الـ cyanide الـ
+
+204
+00:18:28,070 --> 00:18:35,210
+cyanide بيطرد الـ halogen و بحل محلها و ممكن يمر 
+
+205
+00:18:35,210 --> 00:18:41,270
+علي كمان الـ nucleophile تاني اللي اسمه الـ
+
+206
+00:18:41,270 --> 00:18:46,590
+acetylide الـ acetylide بتذكروا هذا الـ acetylide مر
+
+207
+00:18:46,590 --> 00:18:52,720
+عليكم ولا لا؟ لما كنا ناخد الـ terminal الـ kinds
+
+208
+00:18:52,720 --> 00:18:57,300
+متذاكرين الـ terminal الـ kinds اللي زي هيك الـ a c
+
+209
+00:18:57,300 --> 00:19:03,840
+triple bond c h كنا نقول هدولة مع base إيش
+
+210
+00:19:03,840 --> 00:19:12,000
+بيعملوا؟ بيفقدوا H plus يعملوا كإنهم assets مش 
+
+211
+00:19:12,000 --> 00:19:16,140
+strong acids لأ مش strong لكن كـ acids فبدي يصير 
+
+212
+00:19:16,140 --> 00:19:21,600
+عندكم R C triple bond C وهنا زوج إلكترونات شو صفيت
+
+213
+00:19:21,600 --> 00:19:26,200
+هذه الكربونات ثانفة ثانفة إذا هذا الـ acetylide
+
+214
+00:19:26,200 --> 00:19:31,040
+عبارة عن nucleophile هذا الـ acetylide عبارة عن 
+
+215
+00:19:31,040 --> 00:19:35,060
+نيوكليوفايل الآن لو هذا الـ nucleophile بدي افعله
+
+216
+00:19:35,060 --> 00:19:42,640
+مثلا مع CH3PR شو التفاعل اللي بدي يحصل عنده بدي
+
+217
+00:19:42,640 --> 00:19:48,280
+ييجي هذا يهاجم هنا و يطرد الـ PR
+
+218
+00:19:51,090 --> 00:19:55,010
+بنلاحظ إيش كيف التفاعل هي الـ substitution إشي بيحقق
+
+219
+00:19:55,010 --> 00:20:00,170
+المحل إشي بناء على ذلك النتج هنا إيش متوقع يصير R
+
+220
+00:20:00,170 --> 00:20:08,630
+C triple bond C وهنا CH3
+
+221
+00:20:08,630 --> 00:20:14,530
+شوفتوا كيف عملية الـ substitution هي هذا الـ
+
+222
+00:20:14,530 --> 00:20:20,510
+Nucleophile عمل substitution للـ PR حال ما حلها صار
+
+223
+00:20:20,510 --> 00:20:24,990
+عنده مركب جديد
+
+224
+00:20:24,990 --> 00:20:30,570
+واضحة الفكرة هنا؟ هي نفس اللي مكتوبة عندكم أن هذا 
+
+225
+00:20:30,570 --> 00:20:35,930
+مع RX بيعطينا RC triple bond CR تانية
+
+226
+00:20:37,700 --> 00:20:41,440
+فلأي واحد من هدول الـ nucleophiles لو قولنالكوا
+
+227
+00:20:41,440 --> 00:20:45,420
+أكملوا المعادلة تقريبا بشكل شبيه في اللي احنا
+
+228
+00:20:45,420 --> 00:20:54,960
+بنعمله أن الـ nucleophile بها ..
+
+229
+00:20:54,960 --> 00:21:02,660
+الآن بدياكوا تنتبهوا لشغلة احنا عاملين مرات بنعطيكم
+
+230
+00:21:02,660 --> 00:21:09,580
+الـ nucleophile أقوى شغلة مراتب اللي أعطيكم 
+
+231
+00:21:09,580 --> 00:21:17,380
+بيها بكل بيش الـ neutral كيف 
+
+232
+00:21:17,380 --> 00:21:27,660
+أكتب نتيجة التفاعل، كيف أكتب المعادلة،
+
+233
+00:21:27,660 --> 00:21:34,190
+إذا كان nucleophile، it's chargedوإذا كان الـ
+
+234
+00:21:34,190 --> 00:21:39,830
+nucleophile الـ neutral كيف بتم التفاعد؟ خلّينا في 
+
+235
+00:21:39,830 --> 00:21:46,150
+الأول ناخد الـ charged nucleophile لو أخدنا كان
+
+236
+00:21:46,150 --> 00:21:53,070
+الـ nucleophile الـ OH minus هذه عبارة عن نيجاتيف
+
+237
+00:21:53,070 --> 00:21:59,270
+أنيون ولا لأ؟ أيون سالب هذا الـ OH minus بدو يحل
+
+238
+00:21:59,270 --> 00:22:06,780
+محل الـ PR minus مع إلكتروناتها هنا التفاعل و
+
+239
+00:22:06,780 --> 00:22:12,160
+كتابته بسيط ما فيش فيه أي مشكلة سالب بده يحل محل 
+
+240
+00:22:12,160 --> 00:22:18,060
+سالب OH minus بده تيجي تحل محل الـ PR مع أزواج
+
+241
+00:22:18,060 --> 00:22:23,920
+الإلكترونات تبعها واضح؟ يعني مجمل التفاعل كان هذا
+
+242
+00:22:23,920 --> 00:22:29,780
+الجزء المتعادل مع الـ أيون السالب لما تم هذا الهجوم
+
+243
+00:22:29,780 --> 00:22:37,320
+هنا و طردت الـ PR شو طلع عندي OH محل الـ PR زائد PR
+
+244
+00:22:37,320 --> 00:22:41,960
+minus لاحظوا هنا المعادلة من ناحية شحنات معادلة
+
+245
+00:22:41,960 --> 00:22:46,280
+موزونة بمعنى أنا اللى بدأت فيه كان عبارة عن متعادل
+
+246
+00:22:46,280 --> 00:22:52,920
+زائد سالب اللي طلع عندي متعادل زائد سالب فما فيش 
+
+247
+00:22:52,920 --> 00:22:57,520
+عندي أي مشكلة واضح يعني لما بيكون عندي charged
+
+248
+00:22:57,520 --> 00:23:01,080
+nucleophile سالب كل اللي بلزم ننقّي بدل الـ
+
+249
+00:23:01,080 --> 00:23:05,960
+nucleophile احطه على الـ carbon اللي حامله الـ X و
+
+250
+00:23:05,960 --> 00:23:08,620
+أطرد الـ X مع 
+
+251
+00:23:14,720 --> 00:23:22,160
+الكتابة المعادلة هنا هي كتابة بسيطة و مباشرة ما فيش
+
+252
+00:23:22,160 --> 00:23:29,840
+فيها أي مشكلة minus بيحل محل ما فيش أي مشكلة الآن
+
+253
+00:23:29,840 --> 00:23:36,120
+لو أتينا بدنا نعمل التفاعل نفسه مع neutral
+
+254
+00:23:36,120 --> 00:23:42,830
+nucleophile متبهين معاه؟ مع المية الـ OH minus 
+
+255
+00:23:42,830 --> 00:23:46,050
+والمية في النهاية بيكونولي نفس المركب بيدخلولي
+
+256
+00:23:46,050 --> 00:23:51,190
+مجموعة OH بس كيف طريقة كتابة التفاعل هنا المشكلة 
+
+257
+00:23:51,190 --> 00:23:57,450
+المية ما فيش فيها شحنة فيها أزواج إلكترونات هذه
+
+258
+00:23:57,450 --> 00:24:05,760
+المية متعادلة مظبوط ولا لأ؟ وهذا الجزء الـ RX برضه 
+
+259
+00:24:05,760 --> 00:24:11,020
+متعادل مظبوط ولا لأ الآن لما تيجي المية هتهاجم هنا
+
+260
+00:24:11,020 --> 00:24:19,020
+و تطرد الـ PR مع إلكتروناتك كيف هتطلع الـ PR minus
+
+261
+00:24:19,020 --> 00:24:24,800
+انتبهوا معي هين أنا هنا بدي أكتبها الـ RX إيش مالها
+
+262
+00:24:24,800 --> 00:24:30,170
+متعادلة و المية متعادلة متعادلة neutral مع neutral
+
+263
+00:24:30,170 --> 00:24:35,410
+المفروض برضه حسب وزن المعادلات إذا أنا كل اللي
+
+264
+00:24:35,410 --> 00:24:39,770
+بادي فيه متعادل كل النتيجة اللي لازم تطلع عندي إيش
+
+265
+00:24:39,770 --> 00:24:45,550
+لازم تكون متعادلة طب نشوف لما هذه المية بتهاجم هنا 
+
+266
+00:24:45,550 --> 00:24:52,710
+اطلعوا معاه الـ oxygen صار عليها كام رابطة تلات
+
+267
+00:24:52,710 --> 00:24:56,970
+روابط مش تنتهي القزوج من الإلكترونات لو حسبنا الـ
+
+268
+00:24:56,970 --> 00:25:00,430
+formal charge إلها هي في الأساس الـ oxygen في
+
+269
+00:25:00,430 --> 00:25:06,270
+المجموعة السادسة هقول ستة ناقص تلاتة ناقص اتنين
+
+270
+00:25:06,270 --> 00:25:12,290
+plus one إذا هنا هتدخل الماء كاملا وصار عند جزء
+
+271
+00:25:12,290 --> 00:25:18,590
+plus وطلع الـ PR minus لما أجهزة أطلع على هذا الجزء 
+
+272
+00:25:18,590 --> 00:25:25,540
+كله اللي طلع عنده هتلاحظون عليه أنه متعادل، minus و
+
+273
+00:25:25,540 --> 00:25:32,980
+plus، واضح؟ إذن لما كانت كل reactants متعادلة، كل
+
+274
+00:25:32,980 --> 00:25:35,220
+product طلعت برضه 
+
+275
+00:25:39,020 --> 00:25:45,280
+و هذا كلام منطقي جدا، لكن يا تورا هل هيظل هذا
+
+276
+00:25:45,280 --> 00:25:54,720
+الجزء اللي هو الـ CH3 CH2 حامل أكسجين موجبة و بتحمل 
+
+277
+00:25:54,720 --> 00:26:00,780
+ترتين هيدروجين؟ عادة الأكسجين كام رابطة بتتكون؟
+
+278
+00:26:00,780 --> 00:26:06,350
+اتعلمناها أول ما خدنا الـ organic الأكسجين وضعها
+
+279
+00:26:06,350 --> 00:26:11,190
+الطبيعي رابطتين وزوجين إلكترونات إذا هنا الأكسجين 
+
+280
+00:26:11,190 --> 00:26:15,410
+بوضع طبيعي تلت روابط وزوج واحد من الإلكترونات هل 
+
+281
+00:26:15,410 --> 00:26:19,550
+الأكسجين هنا بوضع طبيعي؟ لأ طب كيف بدت ترجع للوضع 
+
+282
+00:26:19,550 --> 00:26:26,750
+الطبيعي الأكسجين؟ بدت تفقد ذرة هيدروجين واحدة بدون 
+
+283
+00:26:26,750 --> 00:26:32,010
+إلكتروناتها بمعنى بدت تفقد الـ proton الـ proton هذا 
+
+284
+00:26:32,010 --> 00:26:38,970
+الـ proton ملاحظين كيف أنا قاعد بفقده بدون .. بدون
+
+285
+00:26:38,970 --> 00:26:42,030
+زوج الإلكترونات .. زوج الإلكترونات بيضلوا يتحملوا
+
+286
+00:26:42,030 --> 00:26:50,950
+الـ oxygen ممكن تاخدوا المية تعمل H3O plus جزء
+
+287
+00:26:50,950 --> 00:26:56,890
+مية ياخد الـ H هذه مش المية بتاخد H plus الآن لما 
+
+288
+00:26:56,890 --> 00:26:59,970
+يصير هذا الكلام صار عندي على الـ oxygen كام رابطة
+
+289
+00:27:01,080 --> 00:27:05,640
+رابطتين كام زوج من الإلكترونات هاي واحد والرابط
+
+290
+00:27:05,640 --> 00:27:09,840
+هاد عبارة عن زوج تاني إذا حصلت على مركب الـ OH
+
+291
+00:27:09,840 --> 00:27:19,360
+المتعادل ولا لأ حصلت عليه زائد الـ H3O plus اللي هو
+
+292
+00:27:19,360 --> 00:27:23,440
+الهيدرونيوم طبعا اللي هيصير عندكم في النهاية أن الـ
+
+293
+00:27:23,440 --> 00:27:31,960
+H3O plus هذا هييجي الـ PR minus ياخد منه الـ H plus
+
+294
+00:27:31,960 --> 00:27:38,040
+بيعمل الـ HPR يعني هذه المية بس هيك دخلت للمساعدة
+
+295
+00:27:38,040 --> 00:27:44,020
+على نزع الـ H من هنا هذه المية طلعت مية الـ H plus
+
+296
+00:27:44,020 --> 00:27:49,860
+مع الـ PR HPR خلصنا واضح؟
+
+297
+00:27:49,860 --> 00:27:54,980
+الآن انتبهوا معايا بس انتبهوا معايا في النهاية
+
+298
+00:27:54,980 --> 00:28:02,840
+المية والـ OH minus شو المجموعة اللي بيدخلوها؟ كنتج
+
+299
+00:28:02,840 --> 00:28:08,620
+النتج ما يختلفش بمعنى لما أفعل أنا الـ RX مع OH
+
+300
+00:28:08,620 --> 00:28:15,540
+minus ولا الـ RX مع H2O الناتج هو ادخال مجموعة الـ
+
+301
+00:28:15,540 --> 00:28:15,760
+OH
+
+302
+00:28:20,410 --> 00:28:25,790
+لكن الـ OH لو كان عندي OH minus بتكون عملية دخولها
+
+303
+00:28:25,790 --> 00:28:32,050
+مباشرة أن دخل minus وطلع minus لما بيكون عندي مية 
+
+304
+00:28:32,050 --> 00:28:38,650
+بتدخل المية و بتعمل أي الموجة بعدك بتفقد المية الـ
+
+305
+00:28:38,650 --> 00:28:43,190
+proton هذا الـ proton وأن بيروح في النهاية مع الـ PR
+
+306
+00:28:43,190 --> 00:28:49,740
+بيعمل HPR واضح؟ هذا الـ proton في النهاية بيروح مع الـ
+
+307
+00:28:49,740 --> 00:28:57,760
+PR و بيعمل HPR إذا معادلة .. هذا تفصيل كيف بيصير
+
+308
+00:28:57,760 --> 00:29:01,240
+الكلام بمعنى أنا بحكي مرة واحدة بس ما بديش ياكم 
+
+309
+00:29:01,240 --> 00:29:06,620
+اتضالكم أنتو لخمين نفسكم فيه أنا في النهاية لما 
+
+310
+00:29:06,620 --> 00:29:17,670
+بدي أقولكوا أكمل معادلة RX زائد HPR كيف بدكم تعملوها
+
+311
+00:29:17,670 --> 00:29:27,090
+الـ H2O مصدر لإيش لـ OH اللي هو الجواب اللي هذه 
+
+312
+00:29:27,090 --> 00:29:38,050
+هتقولوا A OH زائد HX هاي اللي بيصير واضح؟
+
+313
+00:29:40,280 --> 00:29:44,120
+لكن هنا أنا بعطيكم التفاصيل بس تفاصيل كيف تم هذا
+
+314
+00:29:44,120 --> 00:29:50,220
+الكلام ولو كنت الآن أنا أعملكم الـ Rx تتفاعل مع الـ
+
+315
+00:29:50,220 --> 00:29:54,940
+OH- برضه 
+
+316
+00:29:54,940 --> 00:30:04,760
+هيعطيني ROH زائد هذه الـ Rx بإمكانها تتفاعل مع الـ
+
+317
+00:30:04,760 --> 00:30:10,120
+OH- بدأ تعطيني ROH و بإمكانها تتفاعل مع المية 
+
+318
+00:30:10,120 --> 00:30:15,180
+برضه بدأ تعطيني ROH في حالة ما بتتفاعل مع المية
+
+319
+00:30:15,180 --> 00:30:19,160
+شو ناتج الإضاف اللي بيطلع HX في حالة ما بتتفاعل مع
+
+320
+00:30:19,160 --> 00:30:22,840
+المية بيطلع X-
+
+321
+00:30:24,890 --> 00:30:28,330
+طبعا البعض منكم بيقول هي بيطلع في التفاعل minus
+
+322
+00:30:28,330 --> 00:30:33,770
+هيك بيبقى X minus لأ ما هو منطقي أن الـ O H minus
+
+323
+00:30:33,770 --> 00:30:41,650
+أساسا إيش كانت كانت مثلا N A O H N A plus O H فالـ
+
+324
+00:30:41,650 --> 00:30:45,970
+N A plus O H كانت مع بعض لأن O H اتفاعلت إيش بدي
+
+325
+00:30:45,970 --> 00:30:50,690
+يطلع عندك يا جميل؟ N A X مثلا Sodium chloride أو 
+
+326
+00:30:50,690 --> 00:30:57,000
+Sodium bromide فالآن a plus موجودة سواء كانت قبل
+
+327
+00:30:57,000 --> 00:31:02,220
+التفاعل counter ion للـ O H minus بعد التفاعل بتصير
+
+328
+00:31:02,220 --> 00:31:10,060
+counter ion للـ X minus واضح؟ مش عندكوا مشكلة الآن 
+
+329
+00:31:10,060 --> 00:31:15,500
+دائما وأبدا لما بتكون تيجوا اتكملوا نتيجة التفاعل
+
+330
+00:31:16,140 --> 00:31:20,200
+و يكون عندكم الـ nucleophile نيوترال وبتكون 
+
+331
+00:31:20,200 --> 00:31:23,400
+تكتبوا الـ product ما بتكونش تلفوا كل هالكلام الفاضي 
+
+332
+00:31:23,400 --> 00:31:27,420
+لازم الـ product يكون الـ neutral الـ nucleophile
+
+333
+00:31:27,420 --> 00:31:36,280
+مخصوم منه إيش H مخصوم منه H مظبوط ولا لا هنا لما
+
+334
+00:31:36,280 --> 00:31:43,040
+قلت H2O إيش اللي حطته OH الخصم H خليني أؤكد على
+
+335
+00:31:43,040 --> 00:31:51,550
+هذه النقطة خليني أؤكد على هذه النقطة ناخد 
+
+336
+00:31:51,550 --> 00:32:04,570
+Rx ونجي نفعلها مع تلت شغلات مع الـ H2O مع الـ NH3 مع 
+
+337
+00:32:04,570 --> 00:32:14,480
+الـ CH3 نفترض OH ونقول إيش النتيجة في كل حالة أعطوني
+
+338
+00:32:14,480 --> 00:32:17,860
+الناتج .. أعطوني الناتج الـ organic product الأساسي
+
+339
+00:32:17,860 --> 00:32:28,000
+هنا R O H خلاص الـ H بتروح مع الـ X بعدين و هنا R
+
+340
+00:32:28,000 --> 00:32:40,680
+and H two راحت H و هنا R O CH3 اللي بتحطلي CH3O
+
+341
+00:32:40,680 --> 00:32:46,650
+بتحطلها غلط لأن إيش اللي بيشبك بالـ carbon؟ الـ oxygen 
+
+342
+00:32:46,650 --> 00:32:51,770
+ولا اللي بيشبك في الـ R محل الـ X؟ الـ O أخذناها قبل 
+
+343
+00:32:51,770 --> 00:32:56,750
+شوية لما درسنا الـ nucleophile وين موجودة أزواج 
+
+344
+00:32:56,750 --> 00:33:00,990
+الإلكترونات اللي هنا و بتهاجم على الـ oxygen عشان 
+
+345
+00:33:00,990 --> 00:33:05,890
+هيك الناتج R OCH3 واضح؟
+
+346
+00:33:07,540 --> 00:33:12,040
+إذا لما إحنا بنكمل مع الـ neutral الـ nucleophile
+
+347
+00:33:12,040 --> 00:33:18,800
+مجرد إنه الناتج بده ينخسم منه hydrogena proton أول 
+
+348
+00:33:18,800 --> 00:33:25,180
+إيش بتفاعل و بيكون الناتج فيه الـ proton زي كده وبعدين 
+
+349
+00:33:25,180 --> 00:33:28,240
+يفقد إيش الـ proton على طول
+
+350
+00:33:37,960 --> 00:33:43,480
+الآن كل هذا الكلام اللي حكيناه احنا هو كيف أكتب 
+
+351
+00:33:43,480 --> 00:33:49,540
+الناتج، كيف أنا أكتب الناتج، لكن الدارس كل اليوم
+
+352
+00:33:49,540 --> 00:33:55,360
+مش على كيف نكتب الناتج، كيف القالية اللي بتتم فيها 
+
+353
+00:33:55,360 --> 00:34:02,220
+عملية الإبدال واضح كيف القالية اللي بتتم فيها عملية
+
+354
+00:34:02,220 --> 00:34:06,200
+الإبدال كل الكلام هذا اللي موجود هنا reaction with
+
+355
+00:34:06,200 --> 00:34:13,310
+water وما إلى ذلك هو كيف نكتب ناتج الإبدال لكن إيش
+
+356
+00:34:13,310 --> 00:34:19,450
+القالية اللي بتتم فيها عملية الإبدال العلماء هذا
+
+357
+00:34:19,450 --> 00:34:23,730
+الموضوع درسوه و أخذ منهم فترة طويلة يعني مش أقل
+
+358
+00:34:23,730 --> 00:34:28,810
+خلّنا نقول من ستين سبعين سنة و الموضوع بيتطور و
+
+359
+00:34:28,810 --> 00:34:35,710
+بيدرس ما تفكروش العلم اللي بيصلكم مهضوم أن هو شغل
+
+360
+00:34:37,040 --> 00:34:42,200
+يوم ويومين من الثلاثينات ومن العشرينات تقريبا و
+
+361
+00:34:42,200 --> 00:34:46,760
+الناس بيشتغلوا على هذا الموضوع عشان يفهموا إيش 
+
+362
+00:34:46,760 --> 00:34:52,280
+القالية اللي بتتم فيها التفاعل طبعا البعض فيكم 
+
+363
+00:34:52,280 --> 00:34:58,060
+ما بيعرفش إيش معنى أساسا قالية أنتو متعودين تعرفوا 
+
+364
+00:34:58,060 --> 00:35:04,640
+إيش نواتج مش متعودين تعرفوا قالية إيش اللي بنقصده
+
+365
+00:35:04,640 --> 00:35:09,780
+احنا لما بنقول قالية التفاعل قالية التفاعل هي
+
+366
+00:35:09,780 --> 00:35:19,120
+الخطوات التفصيلية التي لا تظهر في المعادلة واضح؟
+
+367
+00:35:19,120 --> 00:35:25,280
+قالية التفاعل هي الخطوات التفصيلية التي لا تظهر في
+
+368
+00:35:25,280 --> 00:35:31,200
+المعادلة مثلا لو افترضنا القاتل أننا نعمل في
+
+369
+00:35:31,200 --> 00:35:36,340
+الدنيا substitution إبدال
+
+401
+00:38:22,950 --> 00:38:28,930
+هذا اللي هو تقريباً موضوعنا الآن العلماء بدراستهم
+
+402
+00:38:28,930 --> 00:38:32,810
+لهذا الموضوع لاحظوا ببساطة
+
+403
+00:38:35,130 --> 00:38:43,450
+إن الكيمياء لا تخرج عن النسق الإنساني  توي
+
+404
+00:38:43,450 --> 00:38:47,790
+لما أخذنا الإبدال في النسق الإنساني إيش قلنا احنا؟
+
+405
+00:38:47,790 --> 00:38:54,390
+قلنا شغلتين أساسيات إذا واحد قوي بيجاتل وبيهاجم
+
+406
+00:38:54,390 --> 00:39:02,410
+لحد ما إيش؟ يحل محل الثاني وإذا واحد ضعيف بيستنى
+
+407
+00:39:02,410 --> 00:39:09,250
+لحد ما هذاك يخلّي مكانه بيجي إيش؟ مكانه تقريباً نفس
+
+408
+00:39:09,250 --> 00:39:14,390
+هذا المنطق بالظبط بيصير في الكيمياء وهنا بيبدأ
+
+409
+00:39:14,390 --> 00:39:21,010
+يلزمنا إيش؟ أن لما بدنا ندرس تفاعل كشيء أساسي بدأ
+
+410
+00:39:21,010 --> 00:39:26,490
+تتذكرون كلمة strong و weak متذكرين أول محاضرة إيش
+
+411
+00:39:26,490 --> 00:39:34,640
+قلنا لكم؟ ال nucleophile يا strong يا weak يا قوي يا 
+
+412
+00:39:34,640 --> 00:39:39,700
+ضعيف، إذا القوي هيتعامل بطريقة، خلينا نقول بطريقة 
+
+413
+00:39:39,700 --> 00:39:45,440
+الشجار والهجوم، والضعيف بده يتعامل بطريقة إيش؟
+
+414
+00:39:45,440 --> 00:39:50,340
+الانتظار، واضح؟ نفس المنطق اللي في الدنيا هو 
+
+415
+00:39:50,340 --> 00:39:54,740
+المنطق اللي موجود وين؟ في الكيمياء، بناء على ذلك
+
+416
+00:39:55,730 --> 00:40:00,390
+النوع الأول من الإبدال بيسموه SN2 reaction 
+
+417
+00:40:00,390 --> 00:40:06,490
+لاحظوا two هذي جايه من إنه في شغلتين بتجاتله،
+
+418
+00:40:06,490 --> 00:40:11,670
+بتفاعله بتعرفوا باللغة العربية في أفعال بيقولوا 
+
+419
+00:40:11,670 --> 00:40:16,710
+عنها ما بتيجي إلا من إيش؟ إلا من شغلتين اللي هي
+
+420
+00:40:16,710 --> 00:40:24,940
+أفعال تفاعلية يعني تفاعل بين مادتين تشاجر بين 
+
+421
+00:40:24,940 --> 00:40:30,660
+اثنين تحاور بين اثنين هذه أفعال تشاركية اللي 
+
+422
+00:40:30,660 --> 00:40:36,580
+بيشترك فيها إيش اثنين في أفعال بتيجي من واحد أكله
+
+423
+00:40:36,580 --> 00:40:42,980
+وشربه ونامة هذه أفعال من واحد واضح؟ الآن أنا
+
+424
+00:40:42,980 --> 00:40:47,880
+النوع الأول من التفاعلات بسميه SN2 reactions
+
+425
+00:40:47,880 --> 00:40:53,870
+S يعني substitution إبدال أو N يعني nucleophilic 
+
+426
+00:40:53,870 --> 00:40:58,210
+يعني المهاجم عبارة عن nucleophilic بكل هذول
+
+427
+00:40:58,210 --> 00:41:02,490
+المهاجم عبارة عن nucleophilic طب إيش ال two؟ ال
+
+428
+00:41:02,490 --> 00:41:08,250
+two معناها إنه باي موليكيولار يعني الشغلتين بيكونوا
+
+429
+00:41:08,250 --> 00:41:13,380
+موجودين في التفاعل يعني كأنه التفاعل فيه إيش؟ شجار
+
+430
+00:41:13,380 --> 00:41:19,180
+أو معتمد على شغلتين في الخطوة الأساسية واضح؟ باي 
+
+431
+00:41:19,180 --> 00:41:23,400
+موليكيولار إيش؟ أمال باي موليكيولار؟ هذه الميكانيزم
+
+432
+00:41:23,400 --> 00:41:26,500
+السهلة بيمثّلوها بالشكل هذا عشان نفهمها كويس
+
+433
+00:41:26,500 --> 00:41:30,720
+بيقولوا لما يكون عندك nucleophile strong ومعنى 
+
+434
+00:41:30,720 --> 00:41:35,550
+strong خلينا نقول مشحون مثلاً charged .. اتفقنا أن
+
+435
+00:41:35,550 --> 00:41:41,030
+الـ charged nucleophiles are strong .. بتيجي بسرعة
+
+436
+00:41:41,030 --> 00:41:45,570
+بتهجم على الكربون .. ليش بده تهجم على الكربون؟ لأن
+
+437
+00:41:45,570 --> 00:41:50,370
+الكربون هي ال partially positive .. هذا السالب بده 
+
+438
+00:41:50,370 --> 00:41:57,450
+يهجم على الموجب لاحظوا هنا عشان تتم عملية الهجوم ما 
+
+439
+00:41:57,450 --> 00:42:02,730
+هو أفضل وضع لكي يحصل هذا التفاعل بالطريقة هذه
+
+440
+00:42:02,730 --> 00:42:08,490
+شغلتين أول شيء هذا ال nucleophile بدّه يكون إيش 
+
+441
+00:42:08,490 --> 00:42:16,790
+strong عشان يقدر يهاجم ونمرة اثنين هذا ال carbon 
+
+442
+00:42:16,790 --> 00:42:25,860
+بزن بده ييجي هجوم عليها يصليها يعني لمركزها، إيش 
+
+443
+00:42:25,860 --> 00:42:30,780
+لازم يكون فيها؟ لازم يكون فيها وسع، عشان المهاجم 
+
+444
+00:42:30,780 --> 00:42:36,480
+يقدر يصل، واضح؟ تكون أقل شيء في الازدحام هذا وين
+
+445
+00:42:36,480 --> 00:42:39,960
+بيصير؟ مع ال primary ولا مع ال secondary ولا مع ال
+
+446
+00:42:39,960 --> 00:42:42,600
+tertiary؟ مع ال primary 
+
+447
+00:42:47,510 --> 00:42:52,430
+لاحظوا هنا الكربون متصلة بكم كربون؟ متصلة بكربون
+
+448
+00:42:52,430 --> 00:42:56,990
+واحدة primary والذرات التالية هيدروجينات صغار فال
+
+449
+00:42:56,990 --> 00:43:01,690
+nucleophile بلاقي ثغرة يهجم من خلالها ال
+
+450
+00:43:01,690 --> 00:43:07,730
+nucleophile قوي بلاقي ثغرة بيهجم من هنا تبدأ هذه 
+
+451
+00:43:07,730 --> 00:43:13,110
+تتكون هل معقول الكربون يصير حواليها خمس روابط؟ آه
+
+452
+00:43:13,110 --> 00:43:16,810
+إذا مجرد بتبقى الرابطة اللي ال .. ال .. ال
+
+453
+00:43:16,810 --> 00:43:23,270
+nucleophile مع ال carbon تتكون، إيش بيصير؟ للرابطة 
+
+454
+00:43:23,270 --> 00:43:29,630
+ال brom مع ال carbon، بتبدأ تنكسر، إذا أنا كأنه في 
+
+455
+00:43:29,630 --> 00:43:32,970
+نفس اللحظة حاجة بتيجي محل حاجة، شوفتوا منطق 
+
+456
+00:43:32,970 --> 00:43:37,710
+الصراع؟ إنه هذا قاعد بيدخل وهذا قاعد بيطلع، إذا
+
+457
+00:43:37,710 --> 00:43:43,630
+هنا في عنده هجوم وهنا في عنده حرب bond formation
+
+458
+00:43:43,630 --> 00:43:49,890
+و bond breaking لو واحد بيطلع بيلاقي هذا هاجم و
+
+459
+00:43:49,890 --> 00:43:56,850
+هذا هارب شوفتم بارح المظاهرات في سوريا واحد هاجم و 
+
+460
+00:43:56,850 --> 00:44:04,240
+واحد هارب هذا تشاجر وتظاهر مكون من إيش؟ من جزئين، 
+
+461
+00:44:04,240 --> 00:44:07,720
+إذا لو أنا بدي أشوف ال transition state، إيش
+
+462
+00:44:07,720 --> 00:44:13,740
+الميزة تبعت ال transition state هنا؟ أنها خماسية
+
+463
+00:44:13,740 --> 00:44:20,440
+الارتباط واضح؟ خماسية الارتباط .. كم رابطة مبينة عندكم 
+
+464
+00:44:20,440 --> 00:44:25,400
+هنا .. تطلعوا عندي .. pentavalent .. بس ثلاثة كاملين 
+
+465
+00:44:25,400 --> 00:44:28,840
+وبعدين الاثنين التانين .. pentavalent يعني خماسية
+
+466
+00:44:28,840 --> 00:44:32,520
+الارتباط .. ثلاثة أصلية وواحدة بتتكون وواحدة
+
+467
+00:44:32,520 --> 00:44:37,160
+بتنكسر .. الآن لما يكتمل التفاعل .. هذه يكتمل
+
+468
+00:44:37,160 --> 00:44:41,940
+تكوينها .. وهذه يكتمل خروجها .. صارت عندي عملية
+
+469
+00:44:41,940 --> 00:44:49,010
+الإبدال ..واضح؟ هذا التفاعل يتم في كم خطوة؟ هذه 
+
+470
+00:44:49,010 --> 00:44:53,010
+خطوة واحدة، كل خطوة في الدنيا دائماً وأبداً الها 
+
+471
+00:44:53,010 --> 00:44:57,050
+transition state مرّ عليكم يمكن في ال general
+
+472
+00:44:57,050 --> 00:45:02,130
+chemistry اللي هي مرحلة في أثناء الخطوة، واضح؟ لكن
+
+473
+00:45:02,130 --> 00:45:08,300
+هنا التفاعل كم step؟ one step هذا التفاعل الآن 
+
+474
+00:45:08,300 --> 00:45:13,180
+بيسمّوه substitution nucleophilic bimolecular
+
+475
+00:45:13,180 --> 00:45:22,380
+قولولي ليش bimolecular؟ لأنه هنا كم جزء بتشاجروا و
+
+476
+00:45:22,380 --> 00:45:28,160
+بتفاعلوا قاعدين؟ اثنين اثنين
+
+477
+00:45:28,160 --> 00:45:33,640
+بتفاعلوا وبناء على ذلك لو أنا كنت بدي أجي أسأل إيش 
+
+478
+00:45:33,640 --> 00:45:41,110
+كائنتيك بهذا التفاعل؟ first order ولا second order
+
+479
+00:45:41,110 --> 00:45:47,990
+second order ال rate هنا بتساوي تعتمد أخذتو
+
+480
+00:45:47,990 --> 00:45:55,970
+قوانين ال rate K في تركيز ال nucleophile في تركيز
+
+481
+00:45:55,970 --> 00:46:03,600
+ال RX الثانيين داخلين في التفاعل واضح؟ إذا هذا
+
+482
+00:46:03,600 --> 00:46:08,060
+التفاعل first order ولا second order؟ second order
+
+483
+00:46:08,060 --> 00:46:14,180
+واضح؟ طيب لو طلعتوا كمان نظرة ال PR لوين كان 
+
+484
+00:46:14,180 --> 00:46:21,900
+اتجاهها؟ بهذا الشكل لل nucleophile إيجاء من وين؟ من
+
+485
+00:46:21,900 --> 00:46:25,820
+الخلف وبناء على ذلك في الناتج إيش صار عندي في ال
+
+486
+00:46:25,820 --> 00:46:31,820
+stereo chemistry inversion كانت ال PR باتجاه صارت
+
+487
+00:46:31,820 --> 00:46:37,400
+ال nucleophile بالاتجاه الثاني واضح كل هذا الكلام
+
+488
+00:46:37,400 --> 00:46:43,920
+اللي احنا بنحكيه عبارة عن مواصفات لهذه القاعدة وقت 
+
+489
+00:46:43,920 --> 00:46:46,960
+إيش؟ بتمدد القاعدة وقت إيش أنا بقول إن التفاعل مش
+
+490
+00:46:46,960 --> 00:46:52,980
+بادئ القاعدة إذا كان عنده strong nucleophile و
+
+491
+00:46:52,980 --> 00:46:59,260
+primary alkyl halide إذا عنده strong nucleophile و
+
+492
+00:46:59,260 --> 00:47:04,020
+primary alkyl halide هذه الميكانيزم الأولى، الآن 
+
+493
+00:47:04,020 --> 00:47:09,080
+لو مرة ثانية بدي ألخص مواصفاتها اللي سميناها إيش
+
+494
+00:47:09,080 --> 00:47:14,610
+احنا؟ أسئلتوا إيش أخذتو معلومات عن الـ SN2 لو كنا 
+
+495
+00:47:14,610 --> 00:47:19,150
+بنجيبلكوا سؤال صح و غلط عنها بتمشي نمرا واحد مع
+
+496
+00:47:19,150 --> 00:47:25,730
+الـ strong الـ nucleophile أفضل إيش الها نمرا 
+
+497
+00:47:25,730 --> 00:47:30,110
+اثنين ال primary أفضل من ال secondary ما بتصيرش مع 
+
+498
+00:47:30,110 --> 00:47:34,490
+الترشيح ممكن مع ال secondary تمشي بس أنه أسرع ال
+
+499
+00:47:34,490 --> 00:47:39,740
+primary أفضل من ال secondary نمرا ثلاثة الكايناتيك
+
+500
+00:47:39,740 --> 00:47:49,140
+ال rate بتاعتها K في ال RX في ال nucleophile إذا ال 
+
+501
+00:47:49,140 --> 00:47:56,940
+rate هنا second order نمرا أربعة ل transition
+
+502
+00:47:56,940 --> 00:48:00,240
+state إيش مواصفاتها؟ 
+
+503
+00:48:04,900 --> 00:48:09,140
+الارتباط pentavalent خماسية الارتباط نمرا خمسة
+
+504
+00:48:09,140 --> 00:48:20,920
+لستيريو كيمستري retention ولا inversion نمرا
+
+505
+00:48:20,920 --> 00:48:24,760
+ستة ولا نمرا واحد يمكن كان بدأ تكون one step ولا
+
+506
+00:48:24,760 --> 00:48:33,140
+two step one step هذا جاي وهذا طالع كل هذول مواصفات 
+
+507
+00:48:33,140 --> 00:48:38,360
+الـ SN2 reaction اللي بتتم لما يكون عنده strong
+
+508
+00:48:38,360 --> 00:48:42,240
+nucleophile مع primary وأحياناً مع secondary alkyl 
+
+509
+00:48:42,240 --> 00:48:46,580
+halides بتتم التفاعل ب one step بالتفاعل داخل في
+
+510
+00:48:46,580 --> 00:48:50,320
+الكائنات X تبعه المتفاعلين لل nucleophile و ال RX
+
+511
+00:48:50,320 --> 00:48:53,820
+ل Transition Statement pentavalent ل Stereochemistry
+
+512
+00:48:53,820 --> 00:48:58,650
+inversion الآن لاحظوا هذول الست مواصفات المحاضرة
+
+513
+00:48:58,650 --> 00:49:01,170
+اللي جايه إن شاء الله لما نحكي على نوع ثاني من
+
+514
+00:49:01,170 --> 00:49:05,510
+التفاعلات هنعود نتطلع عليهم كيف بيختلفوا يعني
+
+515
+00:49:05,510 --> 00:49:10,450
+حيصير كأنه عندي جدول مقارنة إن هاي الميكانيزم
+
+516
+00:49:10,450 --> 00:49:14,470
+الأولى، هاي مواصفاتها طب الميكانيزم الثانية، إيش
+
+517
+00:49:14,470 --> 00:49:19,790
+مواصفاتها بالنسبة للـ nucleophile، للـ RX؟ لل .. ال
+
+518
+00:49:19,790 --> 00:49:23,870
+rate، لل inversion، لل stereo chemistry، لعدد
+
+519
+00:49:23,870 --> 00:49:29,490
+الخطوات، هذا الكلام كله بندرسه المحاضرة الجاية إن 
+
+520
+00:49:29,490 --> 00:49:29,790
+شاء الله
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8bb53d59e95b7a66c5902b9df85d16e18995f0dd
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/np7Zu_Pnvhs_postprocess.srt
@@ -0,0 +1,2080 @@
+1
+00:00:10,440 --> 00:00:15,720
+اليوم ان شاء الله بدنا نستمر في الفصل السادس اللى
+
+2
+00:00:15,720 --> 00:00:19,280
+كان عنوانه و أعطينا فيه مقدمة صغيرة إذا بتذكروا
+
+3
+00:00:19,280 --> 00:00:23,640
+Alkyl Halides طبعا بتذكروا نقولنا ال Alkyl Halides
+
+4
+00:00:23,640 --> 00:00:28,820
+المركبات اللى هم R X وال X عبارة عن Halogen,
+
+5
+00:00:28,960 --> 00:00:35,880
+Chlor, Brom, Mute, Fluor هذه المركبات هناخد إليها
+
+6
+00:00:36,530 --> 00:00:40,930
+نوعين أساسيين من التفاعلات إما تفاعلات الإبدال
+
+7
+00:00:40,930 --> 00:00:45,330
+substitution يعني نشيل ال X و نحط بدالها حاجة
+
+8
+00:00:45,330 --> 00:00:50,790
+تانية أو تفاعلات تانية بنسميها elimination تفاعلات
+
+9
+00:00:50,790 --> 00:00:55,470
+الحذف اللي بنخصه بتفاعلات الحذف أنه بنشيل ال X مع
+
+10
+00:00:55,470 --> 00:01:00,150
+hydrogen و بنكون double bond يعني بيصير عنده ال
+
+11
+00:01:00,150 --> 00:01:06,790
+keen واضح؟فبتفاعلات الحذف بيصير اننا ايش الكيل
+
+12
+00:01:06,790 --> 00:01:11,970
+المرة الماضية اتعرفنا على انواع ال الكلهيلايتز
+
+13
+00:01:11,970 --> 00:01:16,250
+قلنا ال الكلهيلايتز ممكن نصنفهم الى primary او
+
+14
+00:01:16,250 --> 00:01:22,310
+secondary او tertiary اتعرفنا على ان ال carbon
+
+15
+00:01:22,310 --> 00:01:27,030
+halogen bond is generally a polar bond انه اقوى
+
+16
+00:01:27,030 --> 00:01:32,520
+رابطةهي الرابطة اللي مع ال flora و أن أضعف رابطة
+
+17
+00:01:32,520 --> 00:01:37,300
+هي الرابطة اللي مع اليود وبناء على ذلك وصلنا إلى
+
+18
+00:01:37,300 --> 00:01:43,080
+أن التفاعل أسرع ما يمكن بتتم مع اليود لأنه ممكن
+
+19
+00:01:43,080 --> 00:01:48,460
+ينكسر بسهولة وبعده ال brom وبعده الchlor واضح؟ لأن
+
+20
+00:01:48,460 --> 00:01:53,620
+في الحالتين سواء أنا كنت بدأ أعمل تفاعل إبدال لازم
+
+21
+00:01:53,620 --> 00:01:59,320
+أشيل ال Xواضح؟ و لو بدت أعمل تفاعل حذف، بده أشيل
+
+22
+00:01:59,320 --> 00:02:04,100
+ال X مع هيدروجين، فبالحالتين لازم أن هذي ال X يصير
+
+23
+00:02:04,100 --> 00:02:09,180
+لها bond breaking، تنكسر الرابطة بتاعتها، واضح؟
+
+24
+00:02:09,180 --> 00:02:13,040
+فإيش اللي بينكسر دائما؟ الرابطة القوية ولا الرابطة
+
+25
+00:02:13,040 --> 00:02:16,800
+الضعيفة؟ الضعيفة، و هذا كلام منطقي، يعني ما بتحسوش
+
+26
+00:02:16,800 --> 00:02:24,760
+أنه في مشاكلالان هنبدأ درسنا الجديد اللى بنسميه
+
+27
+00:02:24,760 --> 00:02:29,040
+احنا ال nucleophilic substitution in general ان
+
+28
+00:02:29,040 --> 00:02:36,410
+اللى بده يهاجم على ال RX لازم يكون nucleophileسبق
+
+29
+00:02:36,410 --> 00:02:39,810
+انه ربما عرفنا اشي اللي بنقصده احنا بال New
+
+30
+00:02:39,810 --> 00:02:44,790
+Cleophile اللي هو عبارة عن Species او اشهر اما
+
+31
+00:02:44,790 --> 00:02:50,450
+بيحمل شحنة سالبة او إلكترونات في كل الأحوال لازم
+
+32
+00:02:50,450 --> 00:02:56,070
+يكون عليه أزواج من الإلكترونات يعني هو يمثلكثافة
+
+33
+00:02:56,070 --> 00:03:02,270
+إلكترونية يمكن هذا الـ nucleophile أن يكون مشحون
+
+34
+00:03:02,270 --> 00:03:07,950
+يعني تظهر عليه الشحنة السالبة ويمكن أن يكون متعادل
+
+35
+00:03:07,950 --> 00:03:13,310
+لو بدنا ناخد أمثلة مثلا ال OH- هذا الشكل تبعها ال
+
+36
+00:03:13,310 --> 00:03:19,560
+structure لل OH- فبتلاحظوا هنا إيش بتكونمشحونة
+
+37
+00:03:19,560 --> 00:03:25,340
+تظهر عليها شحنة سالبة ويوجد على الأكسجين عدة أزواج
+
+38
+00:03:25,340 --> 00:03:29,540
+من الإلكترونات لما بتم التفاعل بتم التفاعل من خلال
+
+39
+00:03:29,540 --> 00:03:35,200
+الهجوم من أزواج الإلكترونات كذلك الحالة لو بتقطل
+
+40
+00:03:35,200 --> 00:03:42,360
+على ال CN- برضه بتكونمشحونة وهيعد أزواج إلكترونات
+
+41
+00:03:42,360 --> 00:03:46,500
+على الكربون ويتم التفاعل على إيش؟ الكربون، بمعنى
+
+42
+00:03:46,500 --> 00:03:51,720
+هنا الذرّة المهاجمة أي ذرّة؟ الأكسجين، هنا الذرّة
+
+43
+00:03:51,720 --> 00:03:56,340
+المهاجمة أي ذرّة؟ الكربون طبعا مافيش إشي في الدنيا
+
+44
+00:03:56,340 --> 00:04:03,310
+بنباع وبينشره بصيغة سالبهذه عبارة عن مراكبات
+
+45
+00:04:03,310 --> 00:04:08,730
+ايونية بشكل عام متعادلة لكن عندما ندوّبها تفصل إلى
+
+46
+00:04:08,730 --> 00:04:13,210
+ايونين مثلا OH- ممكن يأتي من الـ Sodium Hydroxide
+
+47
+00:04:13,210 --> 00:04:19,070
+بيكون عند NA+, OH-, الخلاصة أنه يوفر لل Sodium
+
+48
+00:04:19,070 --> 00:04:25,750
+Hydroxide OH-, CN-, ممكن يأتي من مراكب Sodium
+
+49
+00:04:25,750 --> 00:04:28,250
+Cyanide NA+,
+
+50
+00:04:34,350 --> 00:04:44,430
+الشحنة السالبة بيحمل شحنة نيوكليوفايل سالبة يمكن
+
+51
+00:04:44,430 --> 00:04:50,710
+ان الشحنة يكون نيوترالمتعادل، مايحملش شحنة، لكن
+
+52
+00:04:50,710 --> 00:04:55,310
+يوجد عليه أزواج إلكترونات يتفاعل من خلالها من
+
+53
+00:04:55,310 --> 00:05:02,040
+أمثلة الـ neutral nucleophiles المشهورة الميةالـ
+
+54
+00:05:02,040 --> 00:05:07,300
+H2O إذا بتطلع هي O H H وكلكوا عارفين أنه المياه
+
+55
+00:05:07,300 --> 00:05:11,220
+فيها كام زوج من الإلكترونات زوجين من الإلكترونات
+
+56
+00:05:11,220 --> 00:05:14,260
+لو بتطلع على الـ polarity من الـ electronegative
+
+57
+00:05:14,260 --> 00:05:17,900
+يتقع على الأكسجون ولا الهيدروجين إذا كأنه صار عند
+
+58
+00:05:17,900 --> 00:05:23,280
+الرأس partially negative برضه هنا التفاعل من خلال
+
+59
+00:05:24,590 --> 00:05:28,550
+زوج الإلكترونات الموجودة على الأكسجيل لو بدنا نطلع
+
+60
+00:05:28,550 --> 00:05:32,950
+على الأمونيا مثلا ان أتش ثري كلكم تتذكروا أن
+
+61
+00:05:32,950 --> 00:05:38,050
+الأمونيا بإيش كانت تمتازة بزوج الإلكترونات اللي
+
+62
+00:05:38,050 --> 00:05:43,570
+موجودة على النيتروجين وبناء على ذلك النيتروجين هي
+
+63
+00:05:43,570 --> 00:05:46,750
+اللي بتكون partially negative فالأمونيا بتتفاعل من
+
+64
+00:05:46,750 --> 00:05:51,330
+خلالزوج الألكترونات لاحظوا وين في عندي زوج
+
+65
+00:05:51,330 --> 00:05:54,690
+الألكترونات هتيجي الرابط الجديد لما يتم التفاعل
+
+66
+00:05:54,690 --> 00:05:59,570
+يعني هنا الرابط هتكون مع ال oxygen هنا مع ال
+
+67
+00:05:59,570 --> 00:06:04,810
+carbon هنا مع ال oxygen هنا مع ال nitrogen هدول هم
+
+68
+00:06:04,810 --> 00:06:08,930
+النوعين خلينا نقول من ال nucleophiles اللي بيمروا
+
+69
+00:06:08,930 --> 00:06:14,070
+علينا اللي هم ال charged nucleophiles و ال neutral
+
+70
+00:06:14,070 --> 00:06:22,470
+nucleophilesالان عندما ندرس التفاعلات سواء تفاعلات
+
+71
+00:06:22,470 --> 00:06:31,690
+الحذف أو الإبداع ستلاحظ ان هناك شغلتين في معادلة
+
+72
+00:06:31,690 --> 00:06:39,110
+التفاعل هناك الـ Nucleophile و هناك الـ RX وبناء
+
+73
+00:06:39,110 --> 00:06:43,790
+على ذلك نتيجة التفاعل مرتبطة بخواص هذولة الـ RX
+
+74
+00:06:43,790 --> 00:06:48,570
+ربما تذكر ان قلنا عنهممكن يكون primary او
+
+75
+00:06:48,570 --> 00:06:52,310
+secondary او tertiary هذه المعلومة هتلزمنا لما
+
+76
+00:06:52,310 --> 00:06:57,590
+نفهم التفاعل بشكل اعمق الان ال nucleophiles تصنف
+
+77
+00:06:57,590 --> 00:07:03,690
+الى نوعين وحسب نوع ال nucleophile برضه بيصير ايش
+
+78
+00:07:03,690 --> 00:07:09,090
+التفاعل هتلاحظوا انه احنا بنقول ال nucleophiles يا
+
+79
+00:07:09,090 --> 00:07:15,240
+اما بيكونوا strong قويين يا اما بيكونوا weakإذا
+
+80
+00:07:15,240 --> 00:07:19,280
+تصنيف النيوكليوفايل هتلاقونا دايما بنحكيلكم this
+
+81
+00:07:19,280 --> 00:07:23,260
+is a strong nucleophile this is a weak nucleophile
+
+82
+00:07:23,260 --> 00:07:29,560
+إذا المفروض فينا كمرحلة أولى نعرف في شوية تغيير في
+
+83
+00:07:29,560 --> 00:07:32,560
+ال slides كلها موجودة بعد slideين تلاتة هنا معظم
+
+84
+00:07:32,560 --> 00:07:37,100
+ال slides أنا غيرتها بس بلزمكم مش تنسخوا من أول و
+
+85
+00:07:37,100 --> 00:07:39,840
+جديد يعني إذا بتجلبوا بتلاقيوا strength of
+
+86
+00:07:39,840 --> 00:07:45,880
+nucleophiles و ما إلى ذلك واضح؟شوية بس عشان يعني
+
+87
+00:07:45,880 --> 00:07:50,260
+سهولة او تتابع الشرح هتلاقي انه في slide او جزء من
+
+88
+00:07:50,260 --> 00:07:56,180
+ال slide ايجي قبل التاني واضح؟ اه فبهمني انا ان
+
+89
+00:07:56,180 --> 00:08:01,100
+اكون بسهولة اعرف ال nucleophile هل هو strong او
+
+90
+00:08:01,100 --> 00:08:05,620
+weak و لو كان عندى two nucleophiles ان هو فيهم
+
+91
+00:08:05,620 --> 00:08:13,220
+اقوى من التاني واضح؟الان بشكل عام احنا بنقول ان
+
+92
+00:08:13,220 --> 00:08:17,360
+الـcharged nucleo files اللي عليها شحنة سالبة
+
+93
+00:08:17,360 --> 00:08:22,550
+كاملة they are stronger than neutral onesيعني لما
+
+94
+00:08:22,550 --> 00:08:26,970
+يكون عند نيوكليوفايل علاش أحنا سالبة هو دائما و
+
+95
+00:08:26,970 --> 00:08:33,970
+أبدا أقوى من النيوكليوفايل المتعادل مثلا الـ OH- و
+
+96
+00:08:33,970 --> 00:08:38,150
+الـ H2O هدولة اتنين لما يصير تفاعل إبداع بيحطوا
+
+97
+00:08:38,150 --> 00:08:43,670
+مجموعة الـ OHأن هو أقوى فيهم كنيوكليوفايل بالـ OH-
+
+98
+00:08:43,670 --> 00:08:50,470
+أقوى من الـ H2O كذلك الحالة الـ Ethyl O- بنسميه
+
+99
+00:08:50,470 --> 00:08:58,450
+إثوكسايد هذا الـ OH- إيش اسمه؟ الـ OH- هيدروكسايد
+
+100
+00:08:58,450 --> 00:09:03,860
+هنا لما يصير إثل شو بيصير اسمه؟إثوكسايد إذا كان
+
+101
+00:09:03,860 --> 00:09:05,900
+مثل الـ O-, إذا كان مثل الـ O-, إذا كان مثل الـ
+
+102
+00:09:05,900 --> 00:09:06,920
+O-, إذا كان مثل الـ O-, إذا كان مثل الـ O-, إذا
+
+103
+00:09:06,920 --> 00:09:06,940
+كان مثل الـ O-, إذا كان مثل الـ O-, إذا كان مثل
+
+104
+00:09:06,940 --> 00:09:11,240
+الـ O-, إذا كان مثل الـ O-, إذا كان مثل الـ O-,
+
+105
+00:09:11,240 --> 00:09:12,880
+إذا كان مثل الـ O-, إذا كان مثل الـ O-, إذا كان
+
+106
+00:09:12,880 --> 00:09:13,220
+مثل الـ O-, إذا كان مثل الـ O-, إذا كان مثل الـ
+
+107
+00:09:13,220 --> 00:09:13,260
+O-, إذا كان مثل الـ O-, إذا كان مثل الـ O-, إذا
+
+108
+00:09:13,260 --> 00:09:14,340
+كان مثل الـ O-, إذا كان مثل الـ O-, إذا كان مثل
+
+109
+00:09:14,340 --> 00:09:18,740
+الـ O-, إذا كان مثل الـ O-, إذا كان مثل الـ O-,
+
+110
+00:09:18,740 --> 00:09:21,880
+إذا
+
+111
+00:09:21,880 --> 00:09:28,280
+كان مثل الـ O-, إذا كان مثل الـ O-, إو لو كانت مع
+
+112
+00:09:28,280 --> 00:09:33,100
+صوديوم بيكون اسم المركب Sodamate بتكون أقوى من
+
+113
+00:09:33,100 --> 00:09:36,980
+الأمونيا، إذا هل القاعدة الأولى في قوة
+
+114
+00:09:36,980 --> 00:09:41,220
+النيوكليوفايل؟ إنه لو عند نيوكليوفايل بشكل عام نفس
+
+115
+00:09:41,220 --> 00:09:48,020
+الظرات، بدوا يكون الـcharged أقوى من ال neutral،
+
+116
+00:09:48,020 --> 00:09:51,940
+واضح؟ الcharged نيوكليوفايل are stronger than
+
+117
+00:09:51,940 --> 00:09:58,210
+neutral enucleophilesالنقطة الأولى لو إجينا بدنا
+
+118
+00:09:58,210 --> 00:10:03,410
+نشوف قوة الـ nucleophile حسب تحركنا في الجدول
+
+119
+00:10:03,410 --> 00:10:07,850
+الدوري إذا بتذكروا واضح دائما احنا كنا نعمل
+
+120
+00:10:07,850 --> 00:10:13,750
+المقارنات و نتخيل أن الجدول الدوري بهذا الشكلالان
+
+121
+00:10:13,750 --> 00:10:19,730
+كيف بتزيد قوة النيوكليوفايل لما بتعمل مقارنة دائما
+
+122
+00:10:19,730 --> 00:10:24,530
+او ابدا انتبهوا اذا بتقارنوا اتشارجد نيوكليوفايل
+
+123
+00:10:24,530 --> 00:10:29,690
+مع اتشارجد نيوكليوفايل او نيوترال نيوكليوفايل مع
+
+124
+00:10:29,690 --> 00:10:32,610
+نيوترال نيوكليوفايل سواء بتكون تتحركوا عبر
+
+125
+00:10:32,610 --> 00:10:39,130
+المجموعة او عبر الدورة النيوكليوفاليستي بتزيد بهذا
+
+126
+00:10:39,130 --> 00:10:44,770
+الشكلكلما اتجهنا الى اليسار و بتزيد بهذا الشكل
+
+127
+00:10:44,770 --> 00:10:50,110
+كلما اتجهنا الى أسفل واضح؟ بهذا الشكل بتزيد
+
+128
+00:10:50,110 --> 00:10:55,570
+النيوكليوفلستي الان لو بدكم تحاولوا تتذكروا الذرات
+
+129
+00:10:55,570 --> 00:10:59,310
+الأساسية في الجدول الدوري كلكم اتذكرين ان في
+
+130
+00:10:59,310 --> 00:11:03,910
+الجدول الدوري كان عندى carbon نيتروجين اكسوجين
+
+131
+00:11:03,910 --> 00:11:04,710
+افدور
+
+132
+00:11:14,390 --> 00:11:19,390
+الأساسيه جدا في الجدول الدوري الان لو اجيت اقارن
+
+133
+00:11:19,390 --> 00:11:25,900
+النيتروجين واليوكليوفايل في اكسوجينهو اقارن ال
+
+134
+00:11:25,900 --> 00:11:29,440
+ammonia مع الميّه، لاحظوا هنا في المقارنة كيف ال
+
+135
+00:11:29,440 --> 00:11:34,580
+ammonia متعادلة والميّه متعادلة، لكن ايهم اقوى كان
+
+136
+00:11:34,580 --> 00:11:40,120
+nucleophile؟ ال nitrogen، اللي هي ال ammonia اقوى
+
+137
+00:11:40,120 --> 00:11:47,120
+من الميّهالان لو اجيت بدي اقارن نيتروجين و اكسوجين
+
+138
+00:11:47,120 --> 00:11:53,660
+مرة تانية لكن بدي اقارن الايونات السالي بتاعتهم ان
+
+139
+00:11:53,660 --> 00:11:59,040
+ايه هما اقوى ال N H2 minus ولا ال O H minus
+
+140
+00:11:59,040 --> 00:12:08,080
+انتبهوا معي قارن متعدل متعدل او مشحون و مشحونطيب
+
+141
+00:12:08,080 --> 00:12:12,140
+لو بدى أنزل في المجموعة خليني افترض الميه ايش
+
+142
+00:12:12,140 --> 00:12:19,160
+بتعمل H2O المتعدل تبعها الكبريت H2S ايهما اقوى
+
+143
+00:12:19,160 --> 00:12:24,520
+كنيكليوفيل H2S is stronger than H2O انا بقول كل ما
+
+144
+00:12:24,520 --> 00:12:28,840
+بنزل لتحت ال strength of a nucleophile increases
+
+145
+00:12:28,840 --> 00:12:34,790
+طيب لو بدى اقارن ال OH- مع ايش بدى اقارنهامع ال sh
+
+146
+00:12:34,790 --> 00:12:41,430
+minus أيه ما أقوى ال sh minus is stronger than oh
+
+147
+00:12:41,430 --> 00:12:48,470
+minus sh minus is stronger than oh minus واضح هذا
+
+148
+00:12:48,470 --> 00:12:53,750
+فاهم ال strength of nucleophiles بيفيدنا أثناء
+
+149
+00:12:53,750 --> 00:12:56,530
+دراسة التفاعلات فمن الأول و الطالع إذا بنقول this
+
+150
+00:12:56,530 --> 00:12:59,630
+is a strong nucleophile or weak nucleophile or
+
+151
+00:12:59,630 --> 00:13:03,290
+this is stronger than the other one المفروض تكونوا
+
+152
+00:13:04,040 --> 00:13:12,300
+فاهمين هم و احنا؟ ابنحكي الآن التفاعل الأساسي يمكن
+
+153
+00:13:12,300 --> 00:13:15,160
+ال slide عندكوا على الورق تكون واضحة وموجودة في
+
+154
+00:13:15,160 --> 00:13:21,220
+الكتاب التفاعل
+
+155
+00:13:21,220 --> 00:13:28,080
+الأساسي في الalkyl halides هو تفاعل ال
+
+156
+00:13:28,080 --> 00:13:31,900
+substitution اللي هو ببساطة انه انا عند ال
+
+157
+00:13:31,900 --> 00:13:33,060
+nucleophile
+
+158
+00:13:45,090 --> 00:13:48,690
+هذه المعادلة الأساسية
+
+159
+00:13:57,050 --> 00:14:01,030
+بدا تصير ال R بدل ما هي متصلة ب X متصلة بإيش؟
+
+160
+00:14:01,030 --> 00:14:04,370
+بالنيوكليوفايل ال ال .. شوفته قبل شوية ال OH
+
+161
+00:14:04,370 --> 00:14:10,330
+والميه؟ اه ممكن يكون نيتروجين ممكن يكون كاربون
+
+162
+00:14:10,330 --> 00:14:16,970
+ممكن يكون سالفر ممكن يكون هالوجين كل هذه عبارة عن
+
+163
+00:14:16,970 --> 00:14:23,550
+احتمالات اكتران من النيوكليوفايل كل هذه عبارة عن
+
+164
+00:14:23,550 --> 00:14:29,980
+احتمالات اكتران من النيوكليوفايلفإذا مثلًا أنا بدي
+
+165
+00:14:29,980 --> 00:14:36,060
+أشوف أنواع الـ Oxygen in nucleophiles مر علينا قبل
+
+166
+00:14:36,060 --> 00:14:43,950
+شوية الـ OH- الـ hydroxide أنيونأه ومر علينا ال OR
+
+167
+00:14:43,950 --> 00:14:55,190
+minus زي إثل O minus فال RO minus is Alkoxide مر
+
+168
+00:14:55,190 --> 00:15:03,470
+علينا الميه H2O هذه نيوترال مر علينا الألكوهول ROH
+
+169
+00:15:03,470 --> 00:15:09,290
+هذه برضه نيوترال انيوترال
+
+170
+00:15:11,850 --> 00:15:20,650
+ممكن يكون عندك كربوكسيلات انايون زي ايون الاسيتات
+
+171
+00:15:20,650 --> 00:15:25,290
+اذا ماذا ذاكرين ومر عليكم في الاسيتك اسيد و سوديوم
+
+172
+00:15:25,290 --> 00:15:32,040
+اسيتات CH3C double bondو او ماينوس اذا مش واضح
+
+173
+00:15:32,040 --> 00:15:39,620
+برضه بنواضحه اليكم وين
+
+174
+00:15:39,620 --> 00:15:44,820
+ال ايون هنا اللي الرأس اللي بتم من خلال التفاعل ال
+
+175
+00:15:44,820 --> 00:15:50,480
+او ماينوس هذا ايش اسمهالـ Carboxylate بشكل عام لو
+
+176
+00:15:50,480 --> 00:15:55,440
+كانت مثل Acetate و هكذا الـ Carboxylate أنا .. كل
+
+177
+00:15:55,440 --> 00:15:58,620
+هذه الأنواع الأولى عبارة عن أي نوع من الـ
+
+178
+00:15:58,620 --> 00:16:03,540
+Nucleophiles؟ Oxygen Enucleophiles يعني بتتفاعل من
+
+179
+00:16:03,540 --> 00:16:11,120
+خلال الـ Oxygen بتهاجم الكربون و بتحل محل اللي هي
+
+180
+00:16:11,120 --> 00:16:17,430
+الـ Halogenالنوع التاني nitrogen nucleophiles ممكن
+
+181
+00:16:17,430 --> 00:16:24,650
+يكون عند ال ammonia NH3 ممكن يكون عندنا ال amide
+
+182
+00:16:24,650 --> 00:16:33,850
+RNH2 ممكن يكون عندنا ال amine RNH2
+
+183
+00:16:33,850 --> 00:16:38,510
+أو NH متصلة بمجموعتين R أو N متصلة ب3 مجموعات R
+
+184
+00:16:38,510 --> 00:16:40,630
+الخلاصة كل هذول عبارة عن
+
+185
+00:16:45,360 --> 00:16:50,920
+النوع التاني ممكن يكون عندكم سلفر اليوكليوفايل زي
+
+186
+00:16:50,920 --> 00:16:56,140
+sh- زي h2s زي rs- زي r2s
+
+187
+00:16:58,340 --> 00:17:03,700
+واضح؟ هذا الحقيقة تصنيف سهل شوية مش واضح إلكوا بس
+
+188
+00:17:03,700 --> 00:17:07,840
+بسيط جدا يعنى اللى ال nucleophile يا بيكون oxygen
+
+189
+00:17:07,840 --> 00:17:12,580
+الرأس تبعه يا nitrogen يا sulfur مافيش فيهم ال
+
+190
+00:17:12,580 --> 00:17:16,440
+slide هذه أكتر من هيك ممكن يكون ال nucleophile
+
+191
+00:17:16,440 --> 00:17:21,260
+halogen طب إنتوا بتقولوا اللى عندى أنا عبارة عن
+
+192
+00:17:21,260 --> 00:17:27,950
+إيش halogen هو halogen بده يحل محل halogenالجواب
+
+193
+00:17:27,950 --> 00:17:32,250
+أه طب أنه اللي بيحل محل التاني لما تتطلعوا انتوا
+
+194
+00:17:32,250 --> 00:17:36,790
+على ال halogens ال floor ال chlorine ال brom ال
+
+195
+00:17:36,790 --> 00:17:42,230
+iod اللي تحت بيحل محل اللي فوق يعني لو كان عندي
+
+196
+00:17:42,230 --> 00:17:49,610
+RCL فعلتها مع I minus ال iod بيحل محل إيش محل ال
+
+197
+00:17:49,610 --> 00:17:55,550
+CL و بيحل محل ال PR واضح ال PR بيحل محلالـ CL
+
+198
+00:17:55,550 --> 00:17:59,270
+غالبا انسوا موضوع ال floor لأنه ال floor رابطته
+
+199
+00:17:59,270 --> 00:18:04,930
+قوية لكن بشكل عام بإمكانكوا تتخيلوا ان اليوت يمكن
+
+200
+00:18:04,930 --> 00:18:10,990
+ان يحل محل ال PR او محل ال CL و ال PR يمكن ان يحل
+
+201
+00:18:10,990 --> 00:18:16,330
+محل ال CL ال iodide ممكن يكون عنده carbon
+
+202
+00:18:16,330 --> 00:18:21,610
+nucleophiles يعني الرأس تبع التفاعل هو ايش carbon
+
+203
+00:18:21,610 --> 00:18:28,070
+تومر عليا ال CN minusرسمنا شكله ال cyanide ال
+
+204
+00:18:28,070 --> 00:18:35,210
+cyanide بيطرد ال halogen و بحل محلها و ممكن يمر
+
+205
+00:18:35,210 --> 00:18:41,270
+علي كمان ال nucleophile تاني اللي اسمه ال
+
+206
+00:18:41,270 --> 00:18:46,590
+acetylide ال acetylide بتذكروا هذا ال acetylide مر
+
+207
+00:18:46,590 --> 00:18:52,720
+عليكم ولا لا؟لما كنا ناخد ال terminal ال kinds
+
+208
+00:18:52,720 --> 00:18:57,300
+متذاكرين ال terminal ال kinds اللي زي هيك ال a c
+
+209
+00:18:57,300 --> 00:19:03,840
+triple bond c h كنا نقول هدولة مع base إيش
+
+210
+00:19:03,840 --> 00:19:12,000
+بيعملوا؟بيفقدوا H بلس يعملوا كإنهم assets مش
+
+211
+00:19:12,000 --> 00:19:16,140
+strong assets لأ مش strong لكن ك assets فبدي يصير
+
+212
+00:19:16,140 --> 00:19:21,600
+عندكم R C triple bond C وهنا زوج إلكترونات شو صفيت
+
+213
+00:19:21,600 --> 00:19:26,200
+هذه الكربونات ثانفة ثانفة إذا هذا الacetylide
+
+214
+00:19:26,200 --> 00:19:31,040
+عبارة عن enucleophileهذا ال city line عبارة عن
+
+215
+00:19:31,040 --> 00:19:35,060
+نيوكليوفايل الان لو هذا ال نيوكليوفايل بدي افعله
+
+216
+00:19:35,060 --> 00:19:42,640
+مثلا مع CH3PR شو التفاعل اللي بدي يحصل عنده بدي
+
+217
+00:19:42,640 --> 00:19:48,280
+ييجي هذا يهاجم هنا و يطرد ال PR
+
+218
+00:19:51,090 --> 00:19:55,010
+بنلاحظين كيف التفاعل هي ال substitution إشي بيحقق
+
+219
+00:19:55,010 --> 00:20:00,170
+المحل إشي بناء على ذلك النتج هنا إيش متوقع يصير R
+
+220
+00:20:00,170 --> 00:20:08,630
+C triple bond C وهنا CH3
+
+221
+00:20:08,630 --> 00:20:14,530
+شوفتوا كيف عملية ال substitutionهي هذا الـ
+
+222
+00:20:14,530 --> 00:20:20,510
+Nucleophile عمل substitution لل PR حال ما حلها صار
+
+223
+00:20:20,510 --> 00:20:24,990
+عنده مركب جديد
+
+224
+00:20:24,990 --> 00:20:30,570
+واضحة الفكرة هنا؟ هي نفس اللي مكتوبة عندكم ان هذا
+
+225
+00:20:30,570 --> 00:20:35,930
+مع RX بيعطينا RC triple bond CR تانية
+
+226
+00:20:37,700 --> 00:20:41,440
+فلأي واحد من هدول ال nuclear files لو قولنالكوا
+
+227
+00:20:41,440 --> 00:20:45,420
+اكملوا المعادلة تقريبا بشكل شبيه في اللي احنا
+
+228
+00:20:45,420 --> 00:20:54,960
+بنعملهان انه ال nuclear file بها ..
+
+229
+00:20:54,960 --> 00:21:02,660
+الان بدياكوا تنتبهوا لشغلة احنا عامال مرات بنعطيكم
+
+230
+00:21:02,660 --> 00:21:09,580
+ال nuclear file اقوى الشارعالمراتب اللي أعطيكم
+
+231
+00:21:09,580 --> 00:21:17,380
+بيها بكل بيش ال neutral كيف
+
+232
+00:21:17,380 --> 00:21:27,660
+أكتب نتيجة التفاعل، كيف أكتب المعادلة،
+
+233
+00:21:27,660 --> 00:21:34,190
+إذا كان نيكليوفاعل، it's chargedوإذا كان الـ
+
+234
+00:21:34,190 --> 00:21:39,830
+nucleophile الـ neutral كيف بتم التفاعد؟ خلّينا في
+
+235
+00:21:39,830 --> 00:21:46,150
+الأول ناخد الـ charged nucleophile لو أخدنا كان
+
+236
+00:21:46,150 --> 00:21:53,070
+الـ nucleophile الـ OH minus هذه عبارة عن نيجاتيف
+
+237
+00:21:53,070 --> 00:21:59,270
+أنيون ولا لأ؟ ايون سالف هذا الـ OH minus بدو يحل
+
+238
+00:21:59,270 --> 00:22:06,780
+محلالـ PR minus مع إلكتروناتها هنا التفاعل و
+
+239
+00:22:06,780 --> 00:22:12,160
+كتابته بسيط مافيش فيه أي مشكلة سالب بده يحل محل
+
+240
+00:22:12,160 --> 00:22:18,060
+سالب OH minus بده تيجي تحل محل ال PR مع أزواج
+
+241
+00:22:18,060 --> 00:22:23,920
+الإلكترونات تبعها واضح؟ يعني مجمل التفاعل كان هذا
+
+242
+00:22:23,920 --> 00:22:29,780
+الجزء المتعادل معالايون السالم لما تم هذا الهجوم
+
+243
+00:22:29,780 --> 00:22:37,320
+هنا و طردت ال PR شو طلع عندى OH محل ال PR زائد PR
+
+244
+00:22:37,320 --> 00:22:41,960
+minus لاحظوا هنا المعادلة من ناحية شحنات معادلة
+
+245
+00:22:41,960 --> 00:22:46,280
+موزونة بمعنى انا اللى بدأت فيه كان عبارة عن متعادل
+
+246
+00:22:46,280 --> 00:22:52,920
+زائدسالب اللي طلع عندى متعادل زائد سالب فمافيش
+
+247
+00:22:52,920 --> 00:22:57,520
+عندى اي مشكلة واضح يعني لما بيكون عندى charged
+
+248
+00:22:57,520 --> 00:23:01,080
+nucleophile سالب كل اللي بلزم ننقجي بدل ال
+
+249
+00:23:01,080 --> 00:23:05,960
+nucleophile احطه على ال carbon اللي حامله ال X و
+
+250
+00:23:05,960 --> 00:23:08,620
+اطرد ال X مع
+
+251
+00:23:14,720 --> 00:23:22,160
+الكتابة المعادلة هنا هي كتابة بسيطة و مباشرة مافيش
+
+252
+00:23:22,160 --> 00:23:29,840
+فيها اي مشكلة minus بيحل محل مافيش اي مشكلة الان
+
+253
+00:23:29,840 --> 00:23:36,120
+لو اتينا بدنا نعمل التفاعل نفسه مع neutral
+
+254
+00:23:36,120 --> 00:23:42,830
+nucleophileمتبهين معاه؟ مع الميّه الـ OH minus
+
+255
+00:23:42,830 --> 00:23:46,050
+والميّه في النهاية بيكونولي نفس المُركّب بيدخلولي
+
+256
+00:23:46,050 --> 00:23:51,190
+مجموعة OH بس كيف طريقة كتابة التفاعل هنا المشكلة
+
+257
+00:23:51,190 --> 00:23:57,450
+الميّه مافيش فيها شحنة فيها أزواج إلكترونات هذه
+
+258
+00:23:57,450 --> 00:24:05,760
+الميّه متعادلة مظبوط ولا لأ؟ وهذا الجزء الـ RXبرضه
+
+259
+00:24:05,760 --> 00:24:11,020
+متعادل مظبوط ولا لأ الان لما تيجي الميه هتهاجم هنا
+
+260
+00:24:11,020 --> 00:24:19,020
+و تطرد ال PR مع إلكتروناتك كيف هتطلع ال PR minus
+
+261
+00:24:19,020 --> 00:24:24,800
+انتبهوا معي هين أنا هنا بده أكتبها ال RX إيش مالها
+
+262
+00:24:24,800 --> 00:24:30,170
+متعادلة و الميه متعادلةمتعادلة neutral مع neutral
+
+263
+00:24:30,170 --> 00:24:35,410
+المفروض برضه حسب وزن المعادلات اذا انا كل اللي
+
+264
+00:24:35,410 --> 00:24:39,770
+بادي فيه متعادل كل النتيجة اللي لازم تطلع عندى اش
+
+265
+00:24:39,770 --> 00:24:45,550
+لازم تكون متعادلة طب نشوف لما هذه المية بتهاجم هنا
+
+266
+00:24:45,550 --> 00:24:52,710
+اتطلعوا معاه ال oxygen صار عليها كام رابطةتلات
+
+267
+00:24:52,710 --> 00:24:56,970
+روابط مش تنتهي القزوج من الإلكترونات لو حسبنا ال
+
+268
+00:24:56,970 --> 00:25:00,430
+formal charge إلها هي في الأساس ال oxygen في
+
+269
+00:25:00,430 --> 00:25:06,270
+المجموعة السادسة هقول ستة ناقص تلاتة ناقص اتنين
+
+270
+00:25:06,270 --> 00:25:12,290
+plus one إذا هنا هتدخل الماء كاملا وصار عند جزء
+
+271
+00:25:12,290 --> 00:25:18,590
+plus وطلع ال PR minus لما أجهزة أطلع على هذا الجزء
+
+272
+00:25:18,590 --> 00:25:25,540
+كله اللي طلع عندهتلاحظون عليه أنه متعادل، minus و
+
+273
+00:25:25,540 --> 00:25:32,980
+plus، واضح؟ إذن لما كانت كل reactants متعادلة، كل
+
+274
+00:25:32,980 --> 00:25:35,220
+product طلعت برضه
+
+275
+00:25:39,020 --> 00:25:45,280
+و هذا كلام منطقي جدا، لكن يا تورا هل هيظل هذا
+
+276
+00:25:45,280 --> 00:25:54,720
+الجزء اللي هو ال CH3 CH2 حامل أكسجين موجبة و بتحمل
+
+277
+00:25:54,720 --> 00:26:00,780
+ترتين هيدروجين؟ عادة الأكسجين كام رابطة بتتكون؟
+
+278
+00:26:00,780 --> 00:26:06,350
+اتعلمناها أول ما خدنا ال organicالأكسجين وضعها
+
+279
+00:26:06,350 --> 00:26:11,190
+الطبيعي رابطتين وزوجين إلكترونات إذا هنا الأكسجين
+
+280
+00:26:11,190 --> 00:26:15,410
+بوضع طبيعي تلت روابط وزوج واحد من الإلكترونات هل
+
+281
+00:26:15,410 --> 00:26:19,550
+الأكسجين هنا بوضع طبيعي؟ لأ طب كيف بدت ترجع للوضع
+
+282
+00:26:19,550 --> 00:26:26,750
+الطبيعي الأكسجين؟ بدت تفقد ذرة هيدروجين واحدة بدون
+
+283
+00:26:26,750 --> 00:26:32,010
+إلكتروناتها بمعنى بدت تفقد البروتون البروتون هذا
+
+284
+00:26:32,010 --> 00:26:38,970
+البروتوناملاحظين كيف أنا قاعد بفقده بدون .. بدون
+
+285
+00:26:38,970 --> 00:26:42,030
+زوج الالكترونات .. زوج الالكترونات بيضلوا يتحملوا
+
+286
+00:26:42,030 --> 00:26:50,950
+ال oxygen ممكن تاخدوا الميه تعمل H3O plus جزء
+
+287
+00:26:50,950 --> 00:26:56,890
+ميه ياخد ال H هذه مش الميه بتاخد H plus الان لما
+
+288
+00:26:56,890 --> 00:26:59,970
+يصير هذا الكلام صار عندي على ال oxygen كام رابطة
+
+289
+00:27:01,080 --> 00:27:05,640
+رابطتين كام زوج من الالكترونات هاي واحد والرابط
+
+290
+00:27:05,640 --> 00:27:09,840
+هاد عبارة عن زوج تاني اذا حصلت على مركب ال OH
+
+291
+00:27:09,840 --> 00:27:19,360
+المتعادل ولا لأ حصلت عليه زائد ال H3O plus اللي هو
+
+292
+00:27:19,360 --> 00:27:23,440
+الهيدرونيوم طبعا اللي هيصير عندكم في النهاية ان ال
+
+293
+00:27:23,440 --> 00:27:31,960
+H3O plus هذا هييجي ال PR minus ياخد منهالـ H plus
+
+294
+00:27:31,960 --> 00:27:38,040
+بيعمل الـ HPR يعني هذه الميه بس هيك دخلت للمساعدة
+
+295
+00:27:38,040 --> 00:27:44,020
+على نزع الـ H من هنا هذه الميه طلعت ميه الـ H plus
+
+296
+00:27:44,020 --> 00:27:49,860
+مع الـ PR HPR خلصنا واضح؟
+
+297
+00:27:49,860 --> 00:27:54,980
+الآن انتبهوا معايا بس انتبهوا معايا في النهاية
+
+298
+00:27:54,980 --> 00:28:02,840
+الميه والـ OH minus شو المجموعة اللي بيدخلوها؟كنتج
+
+299
+00:28:02,840 --> 00:28:08,620
+الناتج مابختلفش بمعنى لما افعل انا ال RX مع OH
+
+300
+00:28:08,620 --> 00:28:15,540
+minus ولا ال RX مع H2O الناتج هو ادخال مجموعة ال
+
+301
+00:28:15,540 --> 00:28:15,760
+OH
+
+302
+00:28:20,410 --> 00:28:25,790
+لكن ال OH لو كان عندى OH minus بتكون عملية دخولها
+
+303
+00:28:25,790 --> 00:28:32,050
+مباشرة انه دخل minus وطلع minus لما بيكون عندى ميه
+
+304
+00:28:32,050 --> 00:28:38,650
+ابتدخل الميه و بتعمل أي الموجة بعدك بتفقد الميه ال
+
+305
+00:28:38,650 --> 00:28:43,190
+proton هذا ال proton وان بيروح في النهاية مع ال PR
+
+306
+00:28:43,190 --> 00:28:49,740
+بيعمل HPRواضح؟ هذا البروتون في النهاية بيروح مع ال
+
+307
+00:28:49,740 --> 00:28:57,760
+PR و بيعمل HPR اذا معادلة .. هذا تفصيل كيف بيصير
+
+308
+00:28:57,760 --> 00:29:01,240
+الكلام بمعنى انا بحكي مرة واحدة بس مابديش ياكم
+
+309
+00:29:01,240 --> 00:29:06,620
+اتضالكم انتوا لخمين نفسكم فيه انا في النهاية لما
+
+310
+00:29:06,620 --> 00:29:17,670
+بدي اقولكوا اكمل معادلة RX زاد HPRكيف بدكم تعملوها
+
+311
+00:29:17,670 --> 00:29:27,090
+ال H2O مصدر لإيش ل OH اللي هو الجواب اللي هذه
+
+312
+00:29:27,090 --> 00:29:38,050
+هتقولوا A OH زائد HX هاي اللي بيصير واضح؟
+
+313
+00:29:40,280 --> 00:29:44,120
+لكن هنا انا بعطيكم التفاصيل بس تفاصيل كيف تم هذا
+
+314
+00:29:44,120 --> 00:29:50,220
+الكلام و لو كنت الان انا اعملكم ال Rx تتفاعل مع ال
+
+315
+00:29:50,220 --> 00:29:54,940
+OH- برضه
+
+316
+00:29:54,940 --> 00:30:04,760
+هيعطيني ROH زائدهذه الـ Rx بإمكانها تتفاعل مع الـ
+
+317
+00:30:04,760 --> 00:30:10,120
+OH- بدأ تعطيني ROH و بإمكانها تتفاعل مع الميّه
+
+318
+00:30:10,120 --> 00:30:15,180
+برضه بدأ تعطيني ROH في حالة ما بتتفاعل مع الميّه
+
+319
+00:30:15,180 --> 00:30:19,160
+شو ناتج الإضاف اللي بيطلع HX في حالة ما بتتفاعل مع
+
+320
+00:30:19,160 --> 00:30:22,840
+الميّه بيطلع X-
+
+321
+00:30:24,890 --> 00:30:28,330
+طبعا البعض منكم بيقول هي بيطلع في التفاعل minus
+
+322
+00:30:28,330 --> 00:30:33,770
+هيك بيبقى X minus لأ ما هو منطقي ان ال O H minus
+
+323
+00:30:33,770 --> 00:30:41,650
+أساسا ايش كانت كانت مثلا N A O H N A plus O H فال
+
+324
+00:30:41,650 --> 00:30:45,970
+N A plus O H كانت مع بعض لأن O H اتفاعلت ايش بدي
+
+325
+00:30:45,970 --> 00:30:50,690
+يطلع عندك يا جميل؟ N A X مثلا Sodium chloride او
+
+326
+00:30:50,690 --> 00:30:57,000
+Sodium bromideفالان a plus موجودة سواء كانت قبل
+
+327
+00:30:57,000 --> 00:31:02,220
+التفاعل counter أيه لل O H minus بعد التفاعل بتصير
+
+328
+00:31:02,220 --> 00:31:10,060
+counter أيه لل X minus واضح؟ مش عندكوا مشكلة الان
+
+329
+00:31:10,060 --> 00:31:15,500
+دائما و أبدا لما بتكون تيجوا اتكملوا نتيجة التفاعل
+
+330
+00:31:16,140 --> 00:31:20,200
+و يكون عندكم الـ nucleophile نيوترال و بتكون
+
+331
+00:31:20,200 --> 00:31:23,400
+تكتبوا ال product مابتكونش تلفوا كل هالكلام الفاضي
+
+332
+00:31:23,400 --> 00:31:27,420
+لازم ال product يكون ال neutral ال nucleophile
+
+333
+00:31:27,420 --> 00:31:36,280
+مخصوم منه إيش H مخصوم منه H مظبوط ولا لا هنا لما
+
+334
+00:31:36,280 --> 00:31:43,040
+قولت H2O إيش اللي حطته OH الخصم H خليني أؤكد على
+
+335
+00:31:43,040 --> 00:31:51,550
+هذه النقطة خليني أؤكد علىهذه النقطة ناخد
+
+336
+00:31:51,550 --> 00:32:04,570
+Rx ونجي نفعلها مع تلت شغلات مع ال H2O مع ال NH3 مع
+
+337
+00:32:04,570 --> 00:32:14,480
+ال CH3 نفترض OH ونقول إيش النتيجة في كل حالةأعطوني
+
+338
+00:32:14,480 --> 00:32:17,860
+الناتج .. اعطوني الناتج ال organic product الأساسي
+
+339
+00:32:17,860 --> 00:32:28,000
+هنا R O H خلاص ال H بتروح مع ال X بعدين و هنا R
+
+340
+00:32:28,000 --> 00:32:40,680
+and H two راحت H و هنا R O CH3 اللي بتحطلي CH3O
+
+341
+00:32:40,680 --> 00:32:46,650
+بتحطلها غلطلأن إيش اللي بيشبك بالcarbon؟ ال oxygen
+
+342
+00:32:46,650 --> 00:32:51,770
+ولا اللي بيشبك في ال R محل ال X؟ ال O أخدناها قبل
+
+343
+00:32:51,770 --> 00:32:56,750
+شوية لما درسنا ال nucleophile وين موجودة أزواج
+
+344
+00:32:56,750 --> 00:33:00,990
+الإلكترونات اللي هانا و بتهاجم على ال oxygen عشان
+
+345
+00:33:00,990 --> 00:33:05,890
+هيك الناتج R OCH3 واضح؟
+
+346
+00:33:07,540 --> 00:33:12,040
+إذا لما إحنا بنكمل مع ال neutral ال nucleophile
+
+347
+00:33:12,040 --> 00:33:18,800
+مجرد إنه الناتج بده ينخسم منه hydrogena proton أول
+
+348
+00:33:18,800 --> 00:33:25,180
+إش بتفاعل و بيكون الناتج فيه ال proton زيك و بعدين
+
+349
+00:33:25,180 --> 00:33:28,240
+يفقد إيش ال proton على طول
+
+350
+00:33:37,960 --> 00:33:43,480
+الان كل هذا الكلام اللي حكيناه احنا هو كيف اكتب
+
+351
+00:33:43,480 --> 00:33:49,540
+الناتج، كيف انا اكتب الناتج، لكن الدارس كل اليوم
+
+352
+00:33:49,540 --> 00:33:55,360
+مش على كيف نكتب الناتج، كيف القالية اللي بتتم فيها
+
+353
+00:33:55,360 --> 00:34:02,220
+عملية الإبدالواضح كيف القالية اللى بتتم فيها عملية
+
+354
+00:34:02,220 --> 00:34:06,200
+الإبدال كل الكلام هذا اللى موجود هنا reaction with
+
+355
+00:34:06,200 --> 00:34:13,310
+water وما إلى ذلك هو كيف نكتبنتج الإبدال لكن إيش
+
+356
+00:34:13,310 --> 00:34:19,450
+القالية اللى بتتم فيها عملية الإبدال العلماء هذا
+
+357
+00:34:19,450 --> 00:34:23,730
+الموضوع درسوه و أخذ منهم فترة طويلة يعني مش أقل
+
+358
+00:34:23,730 --> 00:34:28,810
+خلنا نقول من ستين سبعين سنة و الموضوع بيتطور و
+
+359
+00:34:28,810 --> 00:34:35,710
+بيدرس ماتفكروش العلم اللى بيصلكم مهضوم أن هو شغل
+
+360
+00:34:37,040 --> 00:34:42,200
+يوم و يومين من التلاتينات و من العشرينات تقريبا و
+
+361
+00:34:42,200 --> 00:34:46,760
+الناس بيشتغلوا على هذا الموضوع عشان يفهموا ايش
+
+362
+00:34:46,760 --> 00:34:52,280
+القالية اللي بتم فيها التفاعل طبعا البعض فيكم
+
+363
+00:34:52,280 --> 00:34:58,060
+مابيعرفش ايش معنى أساسا قالية انتوا متعودين تعرفوا
+
+364
+00:34:58,060 --> 00:35:04,640
+ايش نواتج مش متعودين تعرفوا قالية ايش اللي بنقصده
+
+365
+00:35:04,640 --> 00:35:09,780
+احنا لما بنقول قالية التفاعلقالية التفاعل هي
+
+366
+00:35:09,780 --> 00:35:19,120
+الخطوات التفصيلية التي لا تظهر في المعادلة واضح ؟
+
+367
+00:35:19,120 --> 00:35:25,280
+قالية التفاعل هي الخطوات التفصيلية التي لا تظهر في
+
+368
+00:35:25,280 --> 00:35:31,200
+المعادلة مثلا لو افترضنا القاتل اننا نعمل في
+
+369
+00:35:31,200 --> 00:35:36,340
+الدنيا substitution إبدال يعني واحد ساكن في بيت
+
+370
+00:35:37,440 --> 00:35:44,540
+بدنا نطلعه و نجيب فلان مكانه واضح؟ الان كتفاعل او
+
+371
+00:35:44,540 --> 00:35:51,580
+كنتيجة بنقول والله فلان ساكن في هذا البيت طلع و
+
+372
+00:35:51,580 --> 00:35:55,640
+اجى فلان مكانه هاي نعملنا عملية ايش؟ ابدال هذا هو
+
+373
+00:35:55,640 --> 00:36:00,820
+التفاعل لكن يا ترى لو اجينا نسأل عن القالية كيف
+
+374
+00:36:00,820 --> 00:36:08,010
+طلعت؟ والله ممكن طلع بالضرببتصير الناس مابيعملوش
+
+375
+00:36:08,010 --> 00:36:12,530
+مشاكل لحد ما واحد يطلع التاني وعشان يتم الضرب لازم
+
+376
+00:36:12,530 --> 00:36:21,490
+اللي بيطلعه يكون إيش؟ جوي طيب وإذا كان ضعيف بيقدر
+
+377
+00:36:21,490 --> 00:36:27,330
+يطلعه؟ ها إيش بيعمل؟ بقعد يستنى لحد ما هو يطلع من
+
+378
+00:36:27,330 --> 00:36:33,150
+مزاجه يجرف منه وبعدين هو بيجيبحي المحله بصير ولا
+
+379
+00:36:33,150 --> 00:36:39,990
+لأ؟ طيب خلّينا نذكركم اتذكروا الانسحاب الإسرائيلي
+
+380
+00:36:39,990 --> 00:36:45,590
+اللي صار من عندنا بال 2005 تمام؟ احنا اليهود دخلوا
+
+381
+00:36:45,590 --> 00:36:50,010
+عندنا وكانوا جويين وماخدين هالمستوطنات واحنا ضعاف
+
+382
+00:36:50,010 --> 00:36:55,170
+ايش عملنا؟ ضلينا نطلع فيهم .. نطلع فيهم .. نطلع
+
+383
+00:36:55,170 --> 00:37:02,740
+فيهم لحد ما ايجي على بالهم يرحلوالحد لحظة الرحيل و
+
+384
+00:37:02,740 --> 00:37:08,640
+احنا واقفين بعيد خمسة كيلو، لحد ما طلعوا في اخر
+
+385
+00:37:08,640 --> 00:37:13,880
+يوم في الانسحاب الساعة اتناشر في الليل، بعد ما
+
+386
+00:37:13,880 --> 00:37:18,680
+طلعوا باكمة جيجا كانوا الناس مليانا المستوطنات،
+
+387
+00:37:18,680 --> 00:37:23,620
+بثوانيبس لاحظوا هنا كيف المنطق لأنه إحنا ضعاف ما
+
+388
+00:37:23,620 --> 00:37:28,240
+إجيناش نجاتل فيهم، ضلينا واقفين نستنى لحد ما هم
+
+389
+00:37:28,240 --> 00:37:34,260
+شغلوا الدبابات و المدرعات العسكرية و طلعوا و بعدين
+
+390
+00:37:34,260 --> 00:37:38,480
+إحنا عملنا إيش؟ إبدال، في مكان تاني ممكن الإبدال
+
+391
+00:37:38,480 --> 00:37:41,900
+يكون بطوشة، في مكان تالت ممكن الإبدال يكون
+
+392
+00:37:41,900 --> 00:37:48,390
+بالإغراء المادي، بندفعلك إيش؟ إخلقوابتعرفوا مش هذا
+
+393
+00:37:48,390 --> 00:37:51,690
+في منطق الناس أنه بيجي و بيغروا الواحد خدلك ألفين
+
+394
+00:37:51,690 --> 00:37:56,850
+دينار و اطلع؟ الآن هذه كلها عبارة عن آليات إبدال
+
+395
+00:37:56,850 --> 00:38:02,950
+لكن الناس لما بيحكوا عن التفاعل بيقولوا النتيجة أن
+
+396
+00:38:02,950 --> 00:38:06,090
+فلان طلع و إجا فلان ما كانوا على هذه الشجرة خلصنا
+
+397
+00:38:06,090 --> 00:38:11,450
+لكن بأي آلية تمت هذه العملية؟هذا اللي احنا بدنا
+
+398
+00:38:11,450 --> 00:38:16,170
+ندرسه، واضح؟ إذا بدنا نميز بين التفاعلات اللي احنا
+
+399
+00:38:16,170 --> 00:38:19,310
+أخدناها، انه كذا بيحل محل كذا، كذا بيحل على العين
+
+400
+00:38:19,310 --> 00:38:22,950
+و الراس طب ما هي القالية التي يتم فيها التفاعل؟
+
+401
+00:38:22,950 --> 00:38:28,930
+هذا اللي هو تقريبا موضوعنا الآن العلماء بدراستهم
+
+402
+00:38:28,930 --> 00:38:32,810
+لهذا الموضوع لاحظوا ببساطة
+
+403
+00:38:35,130 --> 00:38:43,450
+إن الكيميا لا تخرج عن النسق الإنساني توي
+
+404
+00:38:43,450 --> 00:38:47,790
+لما أخدنا الإبدال في النسق الإنساني إيش قلنا إحنا؟
+
+405
+00:38:47,790 --> 00:38:54,390
+قلنا شغلتين أساسيات إذا واحد قوي بيجاتل و بيهاجم
+
+406
+00:38:54,390 --> 00:39:02,410
+لحد ما إيش؟ احل محل التاني و إذا واحد ضعيف بيستنى
+
+407
+00:39:02,410 --> 00:39:09,250
+لحد ما هداك يخل المكانو بيجي ايش؟ مكانه تقريبا نفس
+
+408
+00:39:09,250 --> 00:39:14,390
+هذا المنطق بالظبط بيصير في الكيميا وهنا بيبدأ
+
+409
+00:39:14,390 --> 00:39:21,010
+يلزمنا ايش؟ ان لما بدنا ندرس تفاعل كشيء أساسي بدأ
+
+410
+00:39:21,010 --> 00:39:26,490
+أتذكر كلمة strong و weak متذكرين أول محاضرة ايش
+
+411
+00:39:26,490 --> 00:39:34,640
+قلنالكم؟ ال nucleophile يا strongيا weak يا قوى يا
+
+412
+00:39:34,640 --> 00:39:39,700
+ضعيف، إذا القوى هيتعامل بطريقة، خلّينا نقول بطريقة
+
+413
+00:39:39,700 --> 00:39:45,440
+الشجار والهجوم، والضعيف بده يتعامل بطريقة إيش؟
+
+414
+00:39:45,440 --> 00:39:50,340
+الانتظار، واضح؟ نفس المنطق اللي في الدنيا هو
+
+415
+00:39:50,340 --> 00:39:54,740
+المنطق اللي موجود وين في الكيميا، بناء على ذلك
+
+416
+00:39:55,730 --> 00:40:00,390
+النوع الأول من الإبدال بيسموه as and to reaction
+
+417
+00:40:00,390 --> 00:40:06,490
+لاحظوا two هذي جاية من إنه في شغلتين بتجاتله،
+
+418
+00:40:06,490 --> 00:40:11,670
+بتفاعله بتعرفوا باللغة العربية في أفعال بيقولوا
+
+419
+00:40:11,670 --> 00:40:16,710
+عنها مابتيجيش إلا من إيش؟ إلا من شغلتين اللي هي
+
+420
+00:40:16,710 --> 00:40:24,940
+أفعال تفاعلة يعني تفاعلة بين مادتين تشاجرةبين
+
+421
+00:40:24,940 --> 00:40:30,660
+اتنين تحاورة بين اتنين هذه أفعال تشاركية اللي
+
+422
+00:40:30,660 --> 00:40:36,580
+بيشترك فيها ايش اتنين في أفعال بتيجي من واحد أكله
+
+423
+00:40:36,580 --> 00:40:42,980
+و شربه و نامه هذه أفعال من واحد واضح؟ الآن أنا
+
+424
+00:40:42,980 --> 00:40:47,880
+النوع الأول من التفاعلات بسميه S and two reactions
+
+425
+00:40:47,880 --> 00:40:53,870
+S يعني substitution إبدالأو أن يعني نيوكليوفيليك
+
+426
+00:40:53,870 --> 00:40:58,210
+يعني المهاجم عبارة عن نيوكليوفيليك بكل هدول
+
+427
+00:40:58,210 --> 00:41:02,490
+المهاجم عبارة عن نيوكليوفيليك طب ايش ال two؟ ال
+
+428
+00:41:02,490 --> 00:41:08,250
+two معناها انه باي موليكيولار ان الشغلتين بيكونوا
+
+429
+00:41:08,250 --> 00:41:13,380
+موجودين في التفاعل يعني كأنه التفاعل فيه ايش؟شجار
+
+430
+00:41:13,380 --> 00:41:19,180
+أو معتمد على شغلتين في الخطوة الأساسية واضح؟ باي
+
+431
+00:41:19,180 --> 00:41:23,400
+موليكيولار ايش أمال باي موليكيولار؟ هذه الميكانيزم
+
+432
+00:41:23,400 --> 00:41:26,500
+البساطة بيمثلوها بالشكل القاتل عشان نفهمها كويس
+
+433
+00:41:26,500 --> 00:41:30,720
+بيقولوا لما يكون عند اليوكليوفايل strong ومعنى
+
+434
+00:41:30,720 --> 00:41:35,550
+strong خلينا نقول مشحون مثلااتشارجد .. اتفقنا ان
+
+435
+00:41:35,550 --> 00:41:41,030
+الـ charged nucleophiles are strong .. بتيجي بسرعة
+
+436
+00:41:41,030 --> 00:41:45,570
+بتهجم على الكربون .. ليش بده تهجم على الكربون؟ لأن
+
+437
+00:41:45,570 --> 00:41:50,370
+الكربون هي ال partially positive .. هذا السالب بده
+
+438
+00:41:50,370 --> 00:41:57,450
+يهجم على الموجبلاحظوا هنا عشان تتم عملية الهجوم ما
+
+439
+00:41:57,450 --> 00:42:02,730
+هو أفضل وضع لكي يحصل هذا التفاعل بالطريقة هذه
+
+440
+00:42:02,730 --> 00:42:08,490
+شغلتين اول اشي هذا ال nucleophile بديه يكون ايش
+
+441
+00:42:08,490 --> 00:42:16,790
+strong عشان يقدر يهاجم ونمره اتنين هذا ال carbon
+
+442
+00:42:16,790 --> 00:42:25,860
+بزن بده ييجي هجوم عليها يصلىلا يعني لمركزها، إيش
+
+443
+00:42:25,860 --> 00:42:30,780
+لازم يكون فيها؟ لازم يكون فيها وسع، عشان المهاجم
+
+444
+00:42:30,780 --> 00:42:36,480
+يقدر يصل، واضح؟ تكون أقل إشي في الازدحام هذا وين
+
+445
+00:42:36,480 --> 00:42:39,960
+بيصير؟ مع ال primary ولا مع ال secondary ولا مع ال
+
+446
+00:42:39,960 --> 00:42:42,600
+tertiary؟ مع ال primary
+
+447
+00:42:47,510 --> 00:42:52,430
+لاحظوا هنا الكربون متصلة بكم كربون؟ متصلة بكربون
+
+448
+00:42:52,430 --> 00:42:56,990
+واحدة primary والذرات التالية هيدروجينات صغار فال
+
+449
+00:42:56,990 --> 00:43:01,690
+nucleophile بلاقي ثغرة يهجم من خلالها ال
+
+450
+00:43:01,690 --> 00:43:07,730
+nucleophile قوي بلاقي ثغرة بيهجم من هنا تبدأ هذه
+
+451
+00:43:07,730 --> 00:43:13,110
+تتكون هل معقول الكربون يصير حواليه خمس روابط؟أه
+
+452
+00:43:13,110 --> 00:43:16,810
+إذا مجرد بتبقى الرابط اللي ال .. ال .. ال
+
+453
+00:43:16,810 --> 00:43:23,270
+nucleophile مع ال carbon تتكون، إيش بيصير؟ لرابطة
+
+454
+00:43:23,270 --> 00:43:29,630
+ال brom مع ال carbon، بتبدأ تنكسر، إذا أنا كأنه في
+
+455
+00:43:29,630 --> 00:43:32,970
+نفس اللحظة حاجة بتيجي محال حاجة، شوفتوا منطق
+
+456
+00:43:32,970 --> 00:43:37,710
+الصراع؟ إنه هذا قاعد بيدخل و هذا قاعد بيطلع، إذا
+
+457
+00:43:37,710 --> 00:43:43,630
+هنا في عنده هجوم و هنا في عنده حروبbond formation
+
+458
+00:43:43,630 --> 00:43:49,890
+و bond breaking لو واحد بيطلع بيلاقي هذا هاجم و
+
+459
+00:43:49,890 --> 00:43:56,850
+هذا هارب شوفتم بارح المظاهرات في سوريا واحد هاجم و
+
+460
+00:43:56,850 --> 00:44:04,240
+واحد هارب هذا تشاجر و تظاهر مكون من إيش؟من جزئين،
+
+461
+00:44:04,240 --> 00:44:07,720
+إذا لو أنا بدي أشوف ال transition state، إيش
+
+462
+00:44:07,720 --> 00:44:13,740
+الميزة تبعت ال transition state هنا؟ أنها خماسية
+
+463
+00:44:13,740 --> 00:44:20,440
+الإرتباطواضح؟ خمسية الإرتباط .. كم رابط مبين عندكم
+
+464
+00:44:20,440 --> 00:44:25,400
+هنا .. تطلعوا عندى .. بنتا فيلت .. بس تلاتة كاملين
+
+465
+00:44:25,400 --> 00:44:28,840
+و بعدين التنتين التانين .. بنتا فيلت يعني خمسية
+
+466
+00:44:28,840 --> 00:44:32,520
+الإرتباط .. تلاتة أصليات و واحدة بتتكون واحدة
+
+467
+00:44:32,520 --> 00:44:37,160
+ابتنكسل .. الآن لما يكتمل التفاعل .. هذه يكتمل
+
+468
+00:44:37,160 --> 00:44:41,940
+تكوينها .. و هذه يكتمل خروجها .. صارت عندى عملية
+
+469
+00:44:41,940 --> 00:44:49,010
+الإبدال ..واضح؟ هذا التفاعل يتم في كام خطوة؟ هذه
+
+470
+00:44:49,010 --> 00:44:53,010
+خطوة واحدة، كل خطوة في الدنيا دائما و أبدا إلها
+
+471
+00:44:53,010 --> 00:44:57,050
+transition state مر عليكم يمكن في ال general
+
+472
+00:44:57,050 --> 00:45:02,130
+chemistry اللي هي مرحلة في أثناء الخطوة، واضح؟ لكن
+
+473
+00:45:02,130 --> 00:45:08,300
+هنا التفاعل كام step؟ one stepهذا التفاعل الآن
+
+474
+00:45:08,300 --> 00:45:13,180
+بيسموه substitution in nucleophilic bimolecular
+
+475
+00:45:13,180 --> 00:45:22,380
+قولولي ليش bimolecular؟ لأنه هنا كم جزء بتشجروا و
+
+476
+00:45:22,380 --> 00:45:28,160
+بتفاعلوا قاعدين؟ اتنين اتنين
+
+477
+00:45:28,160 --> 00:45:33,640
+بتفاعلوا وبناء على ذلك لو انا كنت بدي اجي اسأل ايش
+
+478
+00:45:33,640 --> 00:45:41,110
+كائنتك بهذا التفاعل؟first order و لا second order
+
+479
+00:45:41,110 --> 00:45:47,990
+second order ال rate هنا بتساوت تعتمد أخدتوا
+
+480
+00:45:47,990 --> 00:45:55,970
+قوانين ال rate K في تركيز ال nucleophile في تركيز
+
+481
+00:45:55,970 --> 00:46:03,600
+ال RX التانيين دخلين في التفاعلواضح؟ إذا هذا
+
+482
+00:46:03,600 --> 00:46:08,060
+التفاعل first order ولا second order؟ second order
+
+483
+00:46:08,060 --> 00:46:14,180
+واضح؟ طيب لو اطلعتوا كمان نظرة ال PR لوين كان
+
+484
+00:46:14,180 --> 00:46:21,900
+اتجاهها؟ بهذا الشكل لل nucleophile إيجا من وين؟من
+
+485
+00:46:21,900 --> 00:46:25,820
+الخلف وبناء على ذلك في الناتج إيش صار عندى في ال
+
+486
+00:46:25,820 --> 00:46:31,820
+stereo chemistry inversion كانت ال PR باتجاه صارت
+
+487
+00:46:31,820 --> 00:46:37,400
+ال nucleophile بالاتجاه التانى واضح كل هذا الكلام
+
+488
+00:46:37,400 --> 00:46:43,920
+اللى إحنا بنحكيه عبارة عن مواصفات لهذه القالية وقت
+
+489
+00:46:43,920 --> 00:46:46,960
+إيش باتماد القالية وقت إيش أنا بقول إن التفاعل مش
+
+490
+00:46:46,960 --> 00:46:52,980
+بادى القاليةإذا كان عنده strong nucleophile و
+
+491
+00:46:52,980 --> 00:46:59,260
+primary alkyl halide إذا عنده strong nucleophile و
+
+492
+00:46:59,260 --> 00:47:04,020
+primary alkyl halide هذه الميكانيزم الأولى، الآن
+
+493
+00:47:04,020 --> 00:47:09,080
+لو مرة تانية بدي ألخص مواصفاتها اللي سمناها إيش
+
+494
+00:47:09,080 --> 00:47:14,610
+احنا؟أسئلتوا إيش أخدتوا معلومات عن الـ SN2 لو كنا
+
+495
+00:47:14,610 --> 00:47:19,150
+بنجيبلكوا سؤال صح و غلط عنها بتمشي نمرا واحد مع
+
+496
+00:47:19,150 --> 00:47:25,730
+الـ strong الـ nucleophile أفضل إيش إلها نمرا
+
+497
+00:47:25,730 --> 00:47:30,110
+اتنين ال primary أفضل من ال secondary ما بتصيرش مع
+
+498
+00:47:30,110 --> 00:47:34,490
+الترشد ممكن مع ال secondary تمشي بس أنه أسرع ال
+
+499
+00:47:34,490 --> 00:47:39,740
+primary أفضل من ال secondary نمرا تلاتةالكاينة تك
+
+500
+00:47:39,740 --> 00:47:49,140
+ال rate بتاعتها كي في ال RX في ال nucleify إذا ال
+
+501
+00:47:49,140 --> 00:47:56,940
+rate هنا second order نمرا أربعة ل transition
+
+502
+00:47:56,940 --> 00:48:00,240
+state إيش مواصفاتها؟
+
+503
+00:48:04,900 --> 00:48:09,140
+الارتباط بانتفالنت خمسية الارتباط نمرا خمسة
+
+504
+00:48:09,140 --> 00:48:20,920
+لستيريو كيميستري retention ولا inversion نمرا
+
+505
+00:48:20,920 --> 00:48:24,760
+ستة ولا نمرا واحد يمكن كان بدأ تكون one step ولا
+
+506
+00:48:24,760 --> 00:48:33,140
+two step one step هذا جاي وهذا طالع كل هذهمواصفات
+
+507
+00:48:33,140 --> 00:48:38,360
+الـ SN2 reaction اللي بتتم لما يكون عنده strong
+
+508
+00:48:38,360 --> 00:48:42,240
+nucleophile مع primary و أحيانا مع secondary alkyl
+
+509
+00:48:42,240 --> 00:48:46,580
+halides بتتم التفاعل ب one step بالتفاعل داخل في
+
+510
+00:48:46,580 --> 00:48:50,320
+الكائنات X تبعه المتفاعلين لل nucleophile و ال RX
+
+511
+00:48:50,320 --> 00:48:53,820
+ل Transition Statement Avalant ل Stereochemistry
+
+512
+00:48:53,820 --> 00:48:58,650
+Invergentالان لاحظوا هدول الست مواصفات المحاضرة
+
+513
+00:48:58,650 --> 00:49:01,170
+اللى جاية ان شاء الله لما نحكي على نوع تاني من
+
+514
+00:49:01,170 --> 00:49:05,510
+التفاعلات هنعود نتطلع عليهم كيف بيختلفوا يعني
+
+515
+00:49:05,510 --> 00:49:10,450
+حيصير كإنه عندي جدول مقارنة إن هاي الميكانيزم
+
+516
+00:49:10,450 --> 00:49:14,470
+الأولى، هاي مواصفاتها طب الميكانيزم التانى، إيش
+
+517
+00:49:14,470 --> 00:49:19,790
+مواصفاتها بالنسبة للـ nucleophile، للـ RX؟لل .. ال
+
+518
+00:49:19,790 --> 00:49:23,870
+rate، لل inversion، لل stereo chemistry، لعدد
+
+519
+00:49:23,870 --> 00:49:29,490
+الخطوات، هذا الكلام كله بندرسه المحاضرة الجاية ان
+
+520
+00:49:29,490 --> 00:49:29,790
+شاء الله
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8.srt
new file mode 100644
index 0000000000000000000000000000000000000000..c46e57800a7996666f807d30ed64259e5b8e5b38
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8.srt
@@ -0,0 +1,1449 @@
+1
+00:00:08,560 --> 00:00:15,180
+بسم الله الرحمن الرحيم اليوم إن شاء الله بتكون
+
+2
+00:00:15,180 --> 00:00:20,020
+المحاضرة الأخيرة في هذا المساق وهي محاضرة سهلة
+
+3
+00:00:20,020 --> 00:00:28,550
+وبسيطة عن بعض تفاعلات الأمينات طبعا سبق أن تكلمنا 
+
+4
+00:00:28,550 --> 00:00:35,230
+أن يعني سرّ الأمينات الجبار خلينا نقول اللي في ال
+
+5
+00:00:35,230 --> 00:00:42,110
+amines هي إيش؟ زوج الإلكترونات يعني سرّ ال amines
+
+6
+00:00:42,110 --> 00:00:47,350
+زوج الإلكترونات طالما الأمينات زي ما بتلاحظوا
+
+7
+00:00:47,350 --> 00:00:51,390
+فيها هذا الزوج من الإلكترونات إذا هم ممكن
+
+8
+00:00:51,390 --> 00:00:56,660
+يتفاعلوا  Can they act as nucleophiles أي تفاعل أخذناه
+
+9
+00:00:56,660 --> 00:01:00,900
+بيلزمه الـ nucleophile الأمين ممكن يتفاعل على
+
+10
+00:01:00,900 --> 00:01:05,200
+سبيل المثال مثلا مع ال acid halides ممكن الأمين
+
+11
+00:01:05,200 --> 00:01:08,380
+ييجي يتفاعل اللي هو تفاعل ال substitution الشهير
+
+12
+00:01:08,380 --> 00:01:15,460
+لأنه هذا acid halide يهاجم بهذا الشكل ويطرد 
+
+13
+00:01:16,310 --> 00:01:21,690
+الـ Cl يعطينا الأمايد الآن طالما الكلام مع الـ Acid
+
+14
+00:01:21,690 --> 00:01:28,770
+Chloride بيمشي إذا بالتأكيد موازقله تماماً لو كان
+
+15
+00:01:28,770 --> 00:01:32,770
+عنده مشتقة زي الـ Acid Chloride وتحديداً الـ Ester
+
+16
+00:01:32,770 --> 00:01:37,210
+أو الـ Anhydride يعني في كل الأحوال لو كانت
+
+17
+00:01:37,210 --> 00:01:41,530
+هذه RC double bond O O-ethyl هيعمل نفس التفاعل
+
+18
+00:01:41,530 --> 00:01:45,870
+ويطرد الـ O-ethyl لو كانت RC double bond OOC
+
+19
+00:01:45,870 --> 00:01:50,270
+double bond OR مثلاً anhydride هيتفعل بنفس الطريقة
+
+20
+00:01:50,270 --> 00:01:55,070
+وهذا الكلام يعني لما بندرسه احنا بندرسه كتكرار
+
+21
+00:01:55,070 --> 00:01:58,210
+لأنه حقيقة لما خدنا تفاعل ال acid chlorides و
+
+22
+00:01:58,210 --> 00:02:02,990
+ال esters و ال anhydrides كنا ناخد تفاعلهم مع ال
+
+23
+00:02:02,990 --> 00:02:07,730
+amines تقريبا كل الأمثلة اللي هنا أمثلة متوازية
+
+24
+00:02:07,730 --> 00:02:12,400
+تماماً أنه في عندي هجوم و substitution أنه في عندي
+
+25
+00:02:12,400 --> 00:02:16,300
+هجوم و substitution لحظة اللي بيتقن المبدأ بغض النظر
+
+26
+00:02:16,300 --> 00:02:20,580
+عن كبر الجزئية أنا بتعامل مع مبدأ زوج إلكترونات
+
+27
+00:02:20,580 --> 00:02:26,560
+بيهاجم على ال positive carbon بيطرد إيش؟ ال Cl طبعا
+
+28
+00:02:26,560 --> 00:02:31,000
+بالتأكيد بدكم تكونوا متذاكرين أن هذه الأمينات لو
+
+29
+00:02:31,000 --> 00:02:35,680
+كانت بتهاجم على الديهيد أو كيتون هتعمل إبدال
+
+30
+00:02:38,930 --> 00:02:42,570
+إيش هتعمل؟ addition هتعمل addition وتحولها إلى
+
+31
+00:02:42,570 --> 00:02:46,370
+imine وال addition ممكن يتبع ب elimination هاي
+
+32
+00:02:46,370 --> 00:02:51,150
+هنا في مثال مثلا تفاعل أمين مع anhydride بالتأكيد
+
+33
+00:02:51,150 --> 00:02:55,410
+برضه مرة ثانية الأمين بده يهاجم على ال C double bond O و
+
+34
+00:02:55,410 --> 00:03:01,030
+بده يطرد المجموعة هذه كلها فجميع هذه التفاعلات
+
+35
+00:03:01,030 --> 00:03:06,550
+الحقيقة هي تفاعلات متوازية تفاعلات substitution
+
+36
+00:03:06,550 --> 00:03:12,910
+بهذه التفاعلات the amines act as nucleophiles
+
+37
+00:03:24,260 --> 00:03:28,380
+السؤال ممكن يصير، لو كان هذا unsymmetrical يعني
+
+38
+00:03:28,380 --> 00:03:32,020
+نفترض أن هذه كانت مثل وهذه فنل بده يروح هنا أو
+
+39
+00:03:32,020 --> 00:03:36,020
+هنا غالباً هيروح على الجهتين وهيعطي ناتجين بأي
+
+40
+00:03:36,020 --> 00:03:41,080
+نسب بيعتمد على تجربة؟ بس لو كان هذا غير متماثل
+
+41
+00:03:41,080 --> 00:03:43,980
+يعني السيد أبو البون تقول هنا نفترض مثل الـphenol
+
+42
+00:03:43,980 --> 00:03:48,760
+ممكن جزء يتفاعل على هذه وجزء على هذه وبيطلع نواتج
+
+43
+00:03:48,760 --> 00:03:53,480
+بِنَسب مختلفة لا تُحدّد إلا بإيش؟ إلا بالتجربة
+
+44
+00:03:53,480 --> 00:03:56,200
+لأنه في النهاية الكيمياء بتضال زي ما حكينا كثير
+
+45
+00:03:56,200 --> 00:04:04,880
+علم تجريبي علم تجريبي واضح؟ الآن آخر تفاعل لـ 
+
+46
+00:04:04,880 --> 00:04:10,720
+aromatic amines عادة بيكون فعال هو تفاعل مهم جدا
+
+47
+00:04:10,720 --> 00:04:15,360
+أن ال aromatic amines اللي هو ال aniline مشتقاته
+
+48
+00:04:15,360 --> 00:04:22,420
+ال aniline مشتقاته بيتفاعلوا مع ال nitrous acid ال
+
+49
+00:04:22,420 --> 00:04:27,560
+nitrous acid إذا بتذكروا HNO2 ليش؟ اتذكروا ال
+
+50
+00:04:27,560 --> 00:04:36,040
+nitric acid إيش كان؟ HNO3 Nitric Acid HNO2 Nitrous
+
+51
+00:04:36,040 --> 00:04:40,660
+اللي بيكون أعلى في ال oxygen Nitric اللي بيكون أقل
+
+52
+00:04:40,660 --> 00:04:46,880
+Nitrous هذا الكلام سبق مرة عليكم الخلاصة ال
+
+53
+00:04:46,880 --> 00:04:50,400
+aromatic amines زي ال Aniline بتفعل مع ال Nitrous
+
+54
+00:04:50,400 --> 00:04:57,830
+Acid في وجود HCl بيعطونا أملاح بيكون سرعة البنزين
+
+55
+00:04:57,830 --> 00:05:02,470
+N2 plus Cl minus هذه عبارة عن أيونين يعني هذا
+
+56
+00:05:02,470 --> 00:05:09,570
+لحاله هيك بيكون plus وجنبه Cl minus زي Na Cl
+
+57
+00:05:09,570 --> 00:05:16,300
+تذكروا Na إيش بيكون plus Cl minus نفس الفكرة إذا
+
+58
+00:05:16,300 --> 00:05:22,560
+NaCl is a salt وهذا salt موازي له تماماً plus
+
+59
+00:05:22,560 --> 00:05:27,040
+minus plus minus إذا أنا بحكي عن salt الآن هذا ال
+
+60
+00:05:27,040 --> 00:05:32,280
+salt في كم نيتروجينة؟ نتين إيش اسم غاز
+
+61
+00:05:32,280 --> 00:05:37,840
+النيتروجين غير النيتروجين؟ لا غير النيتروجين
+
+62
+00:05:37,840 --> 00:05:39,720
+الأزوت
+
+63
+00:05:40,940 --> 00:05:44,640
+وعشان يقطعون البيئة مرات لما بيقولوا أن في أكاسيد
+
+64
+00:05:44,640 --> 00:05:49,800
+نيتروجين بتلوث الجو بيقولوا أكاسيد الأزوت وبناءً
+
+65
+00:05:49,800 --> 00:05:53,320
+على ذلك في كثير في التسميات لما بدنا نختصر التعبير
+
+66
+00:05:53,320 --> 00:05:57,680
+عن ال nitrogen في الكيمياء العضوية بنستعمل بدل كلمة
+
+67
+00:05:57,680 --> 00:06:02,220
+nitrogen أزا أزا يعني نيتروجين di-aza يعني
+
+68
+00:06:02,220 --> 00:06:06,140
+نيتروجين ثاني tri-aza يعني ثلاث نيتروجينات يعني
+
+69
+00:06:06,140 --> 00:06:09,240
+مثلاً لما بدنا نسمي مركب فيه ثلاث نيتروجينات وحلقة
+
+70
+00:06:09,240 --> 00:06:15,140
+خماسية بنقول try aza cyclo معناه حلقة خماسية فيها ثلاث
+
+71
+00:06:15,140 --> 00:06:21,340
+نيتروجينات فكلمة aza مرتبطة بإيش؟ من نيتروجين is
+
+72
+00:06:21,340 --> 00:06:27,500
+it؟ الآن هذا بيسموه diaza لأنه فيه نتين ولأنه
+
+73
+00:06:27,500 --> 00:06:35,990
+موجب الأيون الموجب إيش نهايته؟ -onium والسالب -ite ..
+
+74
+00:06:35,990 --> 00:06:41,710
+-ite وولد عمها -ite
+
+75
+00:06:41,710 --> 00:06:46,770
+وولد عمها إيش ولد عم الـ -ite؟ لا الـ -ate دي
+
+76
+00:06:46,770 --> 00:06:50,550
+كانت تبعت ال Ester لا الـ -ite نفسها مش هي لل أيون
+
+77
+00:06:50,550 --> 00:06:56,730
+السالب وإيش كمان بيجي لل أيون السالب؟ -ite ..
+
+78
+00:06:56,730 --> 00:07:03,970
+انتوا اتذكروا الـ .. لما يكون عندكم كلوريت مش فيه
+
+79
+00:07:03,970 --> 00:07:11,190
+chloride؟ برضه الـ -ite أيون سالب نيتريت سالب نيتريت
+
+80
+00:07:11,190 --> 00:07:16,930
+سالب في الـ chloride وال chloride إيش كمان عندكم؟
+
+81
+00:07:16,930 --> 00:07:24,310
+per chlorite و hypo chlorite كل هدول السالبين يعني
+
+82
+00:07:24,310 --> 00:07:28,430
+ال per chlorite و الـ .. وال chloride وال
+
+83
+00:07:28,430 --> 00:07:33,150
+hypochlorite كلها أيونات سالبة لكن بشكل عام لما
+
+84
+00:07:33,150 --> 00:07:37,670
+يكون عندي بس أيون واحد يعني زي ال acetate ما فيش
+
+85
+00:07:37,670 --> 00:07:41,910
+غير شكل واحد في ال oxygen اللي مستعمل أكثر اللي هو
+
+86
+00:07:41,910 --> 00:07:46,570
+الـ -ate لكن لما بصير عندي زيادة ونقص في عدد ال
+
+87
+00:07:46,570 --> 00:07:51,630
+oxygen ممكن نستعمل per -ate ,-ate,-ite, -ite,-ite 
+
+88
+00:07:54,800 --> 00:07:58,180
+فشوية احنا بنضل نطلع عن الموضوع بس بنذكركم في
+
+89
+00:07:58,180 --> 00:08:00,960
+أشياء في الكيمياء العامة فعشان هيك هذا المركب
+
+90
+00:08:00,960 --> 00:08:06,020
+بيسموه بنزين هي بنزين diaza يعني في نيتروجنتين
+
+91
+00:08:06,020 --> 00:08:11,640
+-onium يعني أيون موجب salt chloride فبصير
+
+92
+00:08:11,640 --> 00:08:14,480
+كل هذا اسمه بنزين diazonium 
+
+93
+00:08:18,580 --> 00:08:23,040
+العائلة هذه كلها من المركبات بيسموها Diazonium
+
+94
+00:08:23,040 --> 00:08:27,520
+salts أو Diazonium compounds أو أملاح ال Diazonium
+
+95
+00:08:27,520 --> 00:08:35,750
+الآن يا ترى هل أملاح ال Diazonium هذه مفيدة؟ بحد
+
+96
+00:08:35,750 --> 00:08:42,310
+ذاتها مش مفيدة وبتتكون ما بين 0 إلى 5 درجات مئوية
+
+97
+00:08:42,310 --> 00:08:45,510
+زي ما أنتم شايفين ولو الحرارة ارتفعت عن هيك
+
+98
+00:08:45,510 --> 00:08:50,770
+بتخرب بتتكسر طيب إيش الفائدة بتاعتها؟ الفائدة
+
+99
+00:08:50,770 --> 00:08:55,390
+بتاعتها مش بذاتها الفائدة تبع ال diazonium salts
+
+100
+00:08:55,390 --> 00:09:01,090
+هذه إنها بتتحول إلى مركبات ثانية يعني هي bridge
+
+101
+00:09:01,090 --> 00:09:07,480
+للتحول أو جسر للتحول حلقة وصل اسمها زي ما بدكم
+
+102
+00:09:07,480 --> 00:09:13,580
+للتحول إلى مجموعة من المركبات الثانية تحضر من
+
+103
+00:09:13,580 --> 00:09:18,400
+خلالها يعني هي نقطة انطلاق لإيش جديد بس هي بحد
+
+104
+00:09:18,400 --> 00:09:23,180
+ذاتها مش كتير مهمة لأنها مش ثابتة تتكون أثناء
+
+105
+00:09:23,180 --> 00:09:28,300
+التفاعل لو الحرارة ارتفعت بتخرب لكن هي نقطة إيش
+
+106
+00:09:29,260 --> 00:09:33,240
+انطلاق الآن عشان تشوفوا نقطة الانطلاق اطلعوا على
+
+107
+00:09:33,240 --> 00:09:37,560
+هذا ال slide هاي نحط لكم diazonium salt ومحضرين
+
+108
+00:09:37,560 --> 00:09:42,280
+منها كم مركب واحد اثنين ثلاثة أربعة خمسة ستة سبعة
+
+109
+00:09:42,280 --> 00:09:46,760
+كل هدول بنحضرهم من وين؟ من ال diazonium salt وهي
+
+110
+00:09:46,760 --> 00:09:52,500
+معناه أن هي تعتبر نقطة انطلاق واضح؟ فعلى سبيل
+
+111
+00:09:52,500 --> 00:10:00,000
+المثال ممكن ال diazonium salt الفاعل مع HCl وكبر
+
+112
+00:10:00,000 --> 00:10:05,940
+كلور يبدل محل ال diazonium chloride واضح؟ هذا
+
+113
+00:10:05,940 --> 00:10:09,120
+التفاعل بالمناسبة يسموه Sandmeyer reaction
+
+114
+00:10:11,940 --> 00:10:18,400
+Sandmeyer أكيد أن اللي بدل محله إنتوا إيش؟ Cl طبعاً
+
+115
+00:10:18,400 --> 00:10:21,700
+البعض هيقول أن ما إحنا بنقدر نحضر ال Cl من
+
+116
+00:10:21,700 --> 00:10:26,880
+البنزين بألومنيوم كلوريد و .. وكلورين بالعكس
+
+117
+00:10:26,880 --> 00:10:32,480
+هذا التحضير أسهل لسبب بسيط أن مرات أنتم بتاخدوا
+
+118
+00:10:32,480 --> 00:10:40,170
+التفاعل بدون ما تحسوا خليني أقول بإيش بِغلَبتَه يعني
+
+119
+00:10:40,170 --> 00:10:45,570
+لما نيجي نقول Cl2 ألومنيوم كلوريد زي اللي بيحكي
+
+120
+00:10:45,570 --> 00:10:50,530
+جملة مثلاً امبارح يمكن كان ذكر النكبة كل ناس بيجي
+
+121
+00:10:50,530 --> 00:10:55,730
+ويقولوا سانو حرروا فلسطين وتحروا فلسطين لعبة ولا
+
+122
+00:10:55,730 --> 00:10:59,510
+الكلمة لها مواقفها لحظة أنا مثلاً لما تقولوا احنا
+
+123
+00:10:59,510 --> 00:11:06,490
+بنفعل مع Cl2 ألومنيوم كلوريد ال Cl2 غاز وغاز سام
+
+124
+00:11:07,590 --> 00:11:14,050
+معنى ذلك لو أنا بدي استعمله بدي حذر لما بشتريه
+
+125
+00:11:14,050 --> 00:11:21,350
+في استوانات غاز مؤكسد لما بدي أحط له منظم للأنبوبة
+
+126
+00:11:21,350 --> 00:11:25,790
+الغاز ما بحط له منظم عادي بياكله خلال يوم منظم
+
+127
+00:11:25,790 --> 00:11:30,510
+نحاس له منظم بشتريه خصوصي بمبالغ غالية جداً ..
+
+128
+00:11:30,510 --> 00:11:35,710
+واضح؟ لما بدي أمشي بمشي بمواسير معدنية خاصة مش في
+
+129
+00:11:35,710 --> 00:11:40,710
+plastic وبعد يومين قبل اللي هو .. واضح؟ ونفس
+
+130
+00:11:40,710 --> 00:11:44,050
+الوقت لما بدي أشتغل بدي شفاط جو يشفط كل الغاز اللي
+
+131
+00:11:44,050 --> 00:11:49,830
+بيزيد لإن أنا بتعامل مع غاز .. سام مضبوط ولا لا؟
+
+132
+00:11:49,830 --> 00:11:55,290
+مرة صار في الزرقاء هيك تسرب غاز .. غاز كلورين كل
+
+133
+00:11:55,290 --> 00:11:59,770
+مدينة الزرقاء شردت ونزل أيامها الملك حسين في الليل
+
+134
+00:12:00,040 --> 00:12:07,220
+تابع الحادث فهنا أنا بأتعامل مع غاز وبأتعامل مع
+
+135
+00:12:07,220 --> 00:12:13,460
+غاز سام فما تتوقعوش أن الموضوع التعامل معاه بسهولة
+
+136
+00:12:13,460 --> 00:12:16,860
+اللي أنتم بتخيلوها ال aluminum chloride ال
+
+137
+00:12:16,860 --> 00:12:21,720
+aluminum chloride Lewis acid تمام؟ بناء على ذلك هو
+
+138
+00:12:21,720 --> 00:12:26,660
+شره جداً للمية وأنا بوزنه .. وأنا بوزنه وبنجله
+
+139
+00:12:26,660 --> 00:12:30,560
+من مكان لمكان بياخد من مية الجو وبيتفاعل معها
+
+140
+00:12:30,560 --> 00:12:36,020
+تخيل لحد وين؟ وبالتالي ممكن يخرب يعني بده شروط
+
+141
+00:12:36,020 --> 00:12:39,660
+شديدة من الجفاف أثناء ما بكون بشتغل في المختبر
+
+142
+00:12:39,660 --> 00:12:45,220
+فعلياً لا هذا مريح في التعامل ولا هذا مريح في
+
+143
+00:12:45,220 --> 00:12:50,360
+التعامل يعني بده احتياطات مخبرية مش بس .. مش
+
+144
+00:12:50,360 --> 00:12:56,400
+بسهولة الكتيرة يعني تتخيلوا التعامل معاه طبعاً مرات
+
+145
+00:12:56,400 --> 00:12:59,160
+كثير لما احنا بنشرح لكم نكتب لكم المعادلة وما
+
+146
+00:12:59,160 --> 00:13:03,100
+بنجيب لكم مش هذه الأشياء لسبب بسيط أن أنتم بتظلوا
+
+147
+00:13:04,620 --> 00:13:07,940
+في general organic course لكن لو نزلتوا على المعمل
+
+148
+00:13:07,940 --> 00:13:11,100
+الكلام اللي بتفكروا بنعمله بثانية حتى تكتشفوا أنه
+
+149
+00:13:11,100 --> 00:13:14,440
+بدكم أسبوع تجهزوا لتشتريوا الأنبوبة والغاز و
+
+150
+00:13:14,440 --> 00:13:20,000
+تظبطوا الشفاطات وتشتريوا المنظم ليست عملية سهلة و
+
+151
+00:13:20,000 --> 00:13:23,620
+بدقة فهذه العملية اللي لسه بنستعمل فيها على
+
+152
+00:13:23,620 --> 00:13:28,500
+HCl وCuCl تعتبر أسهل إليه من أن استعمل
+
+153
+00:13:28,500 --> 00:13:32,340
+غاز سام واضح؟
+
+154
+00:13:32,340 --> 00:13:39,590
+هذه إحدى التفاعلات نشوف تفاعل ثاني موازي التفاعل
+
+155
+00:13:39,590 --> 00:13:44,770
+الثاني الموازي تقريباً أن نضع HBr هذه موازية تماماً و
+
+156
+00:13:44,770 --> 00:13:52,370
+بنفس الاسم الفاعل HBr مع CuBr بحط لنا إيش؟ ال
+
+157
+00:13:52,370 --> 00:13:58,970
+Br تفاعل ثالث أن نضع ال CN برضه مع CuCN
+
+158
+00:13:58,970 --> 00:14:06,940
+بنشيل ال N2 وبنضع ال CN ونحط إيش مكانها؟ ال CN
+
+159
+00:14:06,940 --> 00:14:13,980
+برضه هي التفاعل الثالث تفاعل رابع إننا نحط ال I
+
+160
+00:14:13,980 --> 00:14:21,020
+يعني هيحط لنا كل ال halogens إننا
+
+161
+00:14:21,020 --> 00:14:27,120
+نحط ال I باستعمال KI تفاعل خامس بحط ال F
+
+162
+00:14:27,120 --> 00:14:32,500
+باستعمال HPF4 مع حرارة لاحظوا ال halogen ال F
+
+163
+00:14:34,410 --> 00:14:41,090
+Cl, Br, I كلهم ممكن أحطهم محل إيش؟ محل
+
+164
+00:14:41,090 --> 00:14:44,130
+ال diazonium salt وسيقان إيش قعدت بيجي سؤالك؟
+
+165
+00:14:44,130 --> 00:14:47,590
+السيقان سبب ال انتمو جا أكيد طب إحنا ممكن نبدلها
+
+166
+00:14:47,590 --> 00:14:50,430
+بالـ -cyanide السالب ممكنش ال انتمو جا في محل ال موجب
+
+167
+00:14:50,430 --> 00:14:54,990
+السالب في محل ال سالب؟ يعني ما قلناش نبدلها بالـ -cyanide
+
+168
+00:14:54,990 --> 00:14:57,750
+السالب ولا حكينا عن الميكانيزم اللي بتتم فيها
+
+169
+00:14:57,750 --> 00:15:02,880
+الإبدال أنت حكيت من عندك مش أنا أنت قلت إنك بدك
+
+170
+00:15:02,880 --> 00:15:08,960
+تبدل ..الآن هذا كله HCl مع CuCl أو KCl مع
+
+171
+00:15:08,960 --> 00:15:12,540
+CuCl هذا كله بيجيب Cl positive زي ما كنت
+
+172
+00:15:12,540 --> 00:15:15,760
+أنا مع الكلورين والالومنيوم كلوريد شو اللي كنت
+
+173
+00:15:15,760 --> 00:15:24,400
+أتعامل معاه؟ اه okay الآن في تفاعل كثير مهم تفاعل
+
+174
+00:15:24,400
+
+201
+00:17:58,140 --> 00:18:04,620
+تبعتكم بدأ تكون الـ CL واضح؟ الآن بحاول أعطيكم
+
+202
+00:18:04,620 --> 00:18:08,760
+مثال أو اثنين تأكيديات على الاستفادة من هذه
+
+203
+00:18:08,760 --> 00:18:11,840
+الطريقة في ال organic synthesis لأن هذا موضوع
+
+204
+00:18:11,840 --> 00:18:18,460
+دائماً نسأل عنه لكن خلّينا ناخد آخر slide موجودة
+
+205
+00:18:18,460 --> 00:18:24,040
+معنا آخر slide أن الـ diazonium salts نفسها ممكن
+
+206
+00:18:24,040 --> 00:18:28,480
+تتفاعل مع الفينول، هنا بتكون تلاحظوا أن ال
+
+207
+00:18:28,480 --> 00:18:33,280
+diazonium salt موجبة، الفينول وين بيودّي؟ على موقع
+
+208
+00:18:33,280 --> 00:18:39,740
+Ortho و موقع بارا يعني لو جيبت فينول جاهز ال OH
+
+209
+00:18:39,740 --> 00:18:44,680
+كـ substituent سبقنا حكينا أنا activating group و
+
+210
+00:18:44,680 --> 00:18:48,700
+ortho-para directing group فلما نيجي نفعلها مع مادة
+
+211
+00:18:48,700 --> 00:18:52,220
+بهذه المادة وين بنتوقع ييجي يهاجم على ال بارا و
+
+212
+00:18:52,220 --> 00:18:56,800
+على ال ortho-para لو أخدنا ناتج البارا لو أخدنا ناتج
+
+213
+00:18:56,800 --> 00:18:59,880
+تبع البارا بيصير عندنا هذا المركب اللي هو ال
+
+214
+00:18:59,880 --> 00:19:06,200
+phenol, phenol, phenol هذه عبارة عن مركبات صبغات
+
+215
+00:19:06,200 --> 00:19:08,900
+هي الصبغات الملونة اللي أنتم بتشوفوها الصفراء
+
+216
+00:19:08,900 --> 00:19:17,140
+والبراندجانية بنسميها diazo dyes صبغات النيتروجين
+
+217
+00:19:17,140 --> 00:19:22,420
+اللي هو الثنائي داي ازو إيش يعني داي ازو يعني وجود
+
+218
+00:19:22,420 --> 00:19:29,220
+نيتروجين ثاني داي صبغة فالصبغات اللي فيها نيتروجين
+
+219
+00:19:29,220 --> 00:19:33,360
+ثاني طبعاً في صبغات من مركبات ثانية مختلفة تماماً في
+
+220
+00:19:33,360 --> 00:19:37,040
+الشكل ومشكلة بصراحة
+
+221
+00:19:38,970 --> 00:19:47,960
+مشكلة الصبغات حقيقة أنه للأسف الشديد طبعاً بدها نوع
+
+222
+00:19:47,960 --> 00:19:53,900
+من الحذر يعني بيشتغلوا صبغة بنزلوها على السوق
+
+223
+00:19:53,900 --> 00:20:00,680
+باستعملوها الناس وبعد هيك بيثبت أنه لها كثير
+
+224
+00:20:00,680 --> 00:20:05,360
+تأثيرات ضارة على الشعر وما إلى ذلك خصوصاً يعني
+
+225
+00:20:05,360 --> 00:20:08,380
+الأبحاث الكثيرة اللي هي الشغل اللي بيشتغلون النساء
+
+226
+00:20:08,380 --> 00:20:13,380
+اللي بيكثروا من الصبغة كثير معرضين بشكل كبير
+
+227
+00:20:13,380 --> 00:20:18,540
+جداً للـ cancer وما إلى ذلك يعني اليوم الجيل القديم
+
+228
+00:20:18,540 --> 00:20:23,200
+من الصبغات مثلاً كان من مركبات pyrazoles في الغالب
+
+229
+00:20:23,200 --> 00:20:29,840
+معظمها pyrazoles دراسات هائلة .. دراسات هائلة طلعت
+
+230
+00:20:29,840 --> 00:20:34,340
+أنه هذه المركبات carcinogenic طبعاً الشركات بتبدأ
+
+231
+00:20:34,340 --> 00:20:37,920
+تعرف قبل الناس يعني نفس الشركات اللي بتعمل الصبغات
+
+232
+00:20:37,920 --> 00:20:42,820
+بتبدأ تعرف فينها لما تعرف شو بدها تسوي بتروح بتحضر
+
+233
+00:20:42,820 --> 00:20:46,320
+أجيال جديدة، طب والمحضر عندها والمصانع اللي
+
+234
+00:20:46,320 --> 00:20:50,860
+شغالة وما إلى ذلك وبنزل القديم عرض خدوا في
+
+235
+00:20:50,860 --> 00:20:54,540
+العالم الثالث والرابع والخامس بيروحوا ببيعوهم كل
+
+236
+00:20:54,540 --> 00:20:59,810
+القديم وبيعملوا أشياء جديدة، يعني الـ Pyrazoles من
+
+237
+00:20:59,810 --> 00:21:05,310
+حوالي 15 سنة أو أقل بدوا يستعملوها بالـ Triazines،
+
+238
+00:21:05,310 --> 00:21:08,210
+يعني بدل ما هي حلقات خمسية بنيتروجينتين صار حلقات
+
+239
+00:21:08,210 --> 00:21:13,970
+ستة بتلات نيتروجينات، لكن مين اللي عنده تفاصيل
+
+240
+00:21:13,970 --> 00:21:20,370
+العمل هذا اللي قاعد بنشغل؟ الشركات، الشركات، ولذلك
+
+241
+00:21:20,370 --> 00:21:25,120
+هذه المناطق كلها تعتبر مناطق أقل ما يُقال فيها أنه
+
+242
+00:21:25,120 --> 00:21:29,140
+تحت التجربة، لكن ثابت بحالات كثيرة أنه في شغلات
+
+243
+00:21:29,140 --> 00:21:33,960
+منها فعلًا كانت بمعنى الكلمة carcinogenic وسُحبت
+
+244
+00:21:33,960 --> 00:21:37,980
+من الأسواق، عدمين اللي اتبع، على أي حال، هذا نوع
+
+245
+00:21:37,980 --> 00:21:41,340
+من الصبغات اللي بنحضره احنا اللي هو الـ diazodide
+
+246
+00:21:41,340 --> 00:21:46,450
+اللي هي الصبغات اللي فيها two nitrogels هذه yellow
+
+247
+00:21:46,450 --> 00:21:52,370
+leaflets اللي أول ما بتتكون بتتكون يعني بشكل أصفر
+
+248
+00:21:52,370 --> 00:21:56,470
+high melting point اللي هو بندوّب شوية بـ ethanol أو
+
+249
+00:21:56,470 --> 00:22:06,050
+إيش هو بنحصل على هذه الألوان ويا ما أحلاها لكن على
+
+250
+00:22:06,050 --> 00:22:12,290
+أي حال خلّينا يمكن نظل محافظين على الإضاءة إذا
+
+251
+00:22:12,290 --> 00:22:13,450
+بنعمل زي هيك
+
+252
+00:22:18,620 --> 00:22:24,100
+بإمكاننا الفكرة الأخيرة نعطيكوا عليها .. نعطيكم
+
+253
+00:22:24,100 --> 00:22:29,700
+عليها بعض الأمثلة مثلاً لو جيبنالكم أنه بدنا
+
+254
+00:22:29,700 --> 00:22:34,300
+نتحضرولنا هذا
+
+255
+00:22:34,300 --> 00:22:35,480
+المركب
+
+256
+00:22:47,410 --> 00:22:54,010
+ليش طفل هذا؟ لو بدنا نحضر هذا ونبتدأ من البنزين
+
+257
+00:22:54,010 --> 00:23:00,730
+نحضر هذا ونبتدأ من إيش؟ من البنزين لاحظوا أن
+
+258
+00:23:00,730 --> 00:23:05,410
+أنتم تعلمتوا .. تعلمتوا تحضير مجموعة الميثيل
+
+259
+00:23:05,410 --> 00:23:14,740
+بنقدر نحط الـ .. بنقدر نحط الميثيل من خلال CH3Cl لكن 
+
+260
+00:23:14,740 --> 00:23:18,900
+لو قلنا مجموعة الحامض أخذتم الطريقة نحط الحامض أه
+
+261
+00:23:18,900 --> 00:23:25,060
+إذا المفروض وأنتم بتفكروا تقولوا احنا بنرجع
+
+262
+00:23:25,060 --> 00:23:29,100
+بالجوه برأس معادة السهم بهذه الطريقة شايفين هذا
+
+263
+00:23:29,100 --> 00:23:33,900
+السهم هذا السهم اللي بنقول عنه احنا سهم ال retro
+
+264
+00:23:33,900 --> 00:23:40,620
+synthesis يعني أنا لو كنت retro synthesis يعني لو
+
+265
+00:23:40,620 --> 00:23:45,680
+كنت برجع برجوع المفروض أن أقول أن ال COOH من وين
+
+266
+00:23:45,680 --> 00:23:58,000
+جاية من ال CNI كأنه صار عندك CH3 و CN ماشي بدّاجة
+
+267
+00:23:58,000 --> 00:24:04,760
+أقول ال CN من وين جايه واضح؟
+
+268
+00:24:06,910 --> 00:24:17,610
+طيب لسه أخدنا ال CN من وين جايه؟ من النيتروزو ال 2
+
+269
+00:24:17,610 --> 00:24:32,890
+plus، مظبوط؟ النيتروزو من وين جايه؟ من ال N H 2 ممكن
+
+270
+00:24:32,890 --> 00:24:38,950
+في الأصل ال نيترو بقدر أنا أكون بدي بالميثيل و
+
+271
+00:24:38,950 --> 00:24:43,250
+أحط ال N-H2 ما هي ال N-H2 من وين بتيجي؟ من ال
+
+272
+00:24:43,250 --> 00:24:54,170
+Nitro يعني كأنه هذا بدي يكون CH3 و NO2 CH3 و NO2
+
+273
+00:24:54,170 --> 00:24:58,770
+طيب هي لسه ما زال عندي مجموعة ثاني CH3 و NO2 مين اللي
+
+274
+00:24:58,770 --> 00:25:04,530
+بدي أحطها بالأول؟ لو بديك بالميثيل وين هتودّي؟
+
+275
+00:25:05,280 --> 00:25:10,720
+ortho-para لو بدأت بالنيترو ميدا، إذا أنا المفروض لو
+
+276
+00:25:10,720 --> 00:25:20,880
+بدي أبدأ أكون بدء من النيترو on
+
+277
+00:25:20,880 --> 00:25:24,420
+O2 وبعدين النيترو من وين بجيبه؟
+
+278
+00:25:26,910 --> 00:25:33,670
+من البنزين الآن كل هذا ارجع بالتفكير عشان ذلك احنا
+
+279
+00:25:33,670 --> 00:25:38,790
+إيش بنسميه retro synthesis لو كنت عاد بدي أبدأ
+
+280
+00:25:38,790 --> 00:25:42,750
+أعمل المسألة من أول وجديد بقول بنزين إيش اللي بدي
+
+281
+00:25:42,750 --> 00:25:48,370
+يخليه نيترو بصير أحط الاسم زي هيك ما بديش أُعيد كتابة
+
+282
+00:25:48,370 --> 00:25:52,590
+كل إشي بس أنتم المفروض تعدّوا بدي أحط له HNO3
+
+283
+00:26:00,060 --> 00:26:08,860
+النيترو لما بدي أحوله النيترو
+
+284
+00:26:08,860 --> 00:26:13,840
+لما بدي أحوله النيترو لما بدي أحوله النيترو لما
+
+285
+00:26:13,840 --> 00:26:15,600
+بدي أحوله النيترو لما بدي أحوله النيترو لما بدي
+
+286
+00:26:15,600 --> 00:26:16,780
+أحوله النيترو لما بدي أحوله النيترو لما بدي أحوله
+
+287
+00:26:16,780 --> 00:26:17,560
+النيترو لما بدي أحوله النيترو لما بدي أحوله
+
+288
+00:26:17,560 --> 00:26:20,580
+النيترو لما بدي أحوله النيترو لما بدي أحوله
+
+289
+00:26:20,580 --> 00:26:23,200
+النيترو لما بدي أحوله النيترو لما بدي أحوله
+
+290
+00:26:23,200 --> 00:26:23,360
+النيترو لما بدي أحوله النيترو لما بدي أحوله
+
+291
+00:26:23,360 --> 00:26:23,380
+النيترو لما بدي أحوله النيترو لما بدي أحوله
+
+292
+00:26:23,380 --> 00:26:28,960
+النيترو لما بدي Diazonium HNO2
+
+293
+00:26:28,960 --> 00:26:35,580
+مرات من اللي بيستعملوا ال HNO2 بيستعملوا ال sodium
+
+294
+00:26:35,580 --> 00:26:38,720
+nitrite مع حمض ال sodium nitrite مع حمض بتفعل و
+
+295
+00:26:38,720 --> 00:26:45,200
+بتطلع HNO2 يعني لو قلنا HNO2 ولا قلنا NA NO2
+
+296
+00:26:45,200 --> 00:26:51,150
+زائد H plus هدول معناهُم برضه HNO2 لأن ال sodium
+
+297
+00:26:51,150 --> 00:26:55,730
+nitrate بتفعل مع الحمض بتطلع HNO2 مش المشكلة okay
+
+298
+00:26:55,730 --> 00:27:06,990
+ال L2 plus كيف بدأ تصير CNO KCN كبرتوا ال CN إيش
+
+299
+00:27:06,990 --> 00:27:13,470
+اللي بيبقى يخليها COH ملاحظين؟
+
+300
+00:27:19,510 --> 00:27:25,330
+فهذا اللي هو يعني مثال على ال retro synthesis كيف
+
+301
+00:27:25,330 --> 00:27:30,910
+الأمور اللي واحد بتعامل معها بتعامل معها بهدوء
+
+302
+00:27:30,910 --> 00:27:34,550
+ممكن نشرح كمان مثال واحد أخير
+
+303
+00:27:44,680 --> 00:27:49,080
+طبعاً في كثير أشياء أسهل من هيك وهذا مش صعب بس
+
+304
+00:27:49,080 --> 00:27:56,520
+متدرّج لأ متدرّج مش صعب مش في ولا خطوة صعبة بس متدرّج
+
+305
+00:27:56,520 --> 00:28:01,320
+ناخد
+
+306
+00:28:01,320 --> 00:28:07,460
+كمان مثال ناخد كمان مثال لو جيبناكم هذا المركب
+
+307
+00:28:07,460 --> 00:28:11,100
+اللي
+
+308
+00:28:11,100 --> 00:28:18,070
+موجود فيه PRPR PR
+
+309
+00:28:18,070 --> 00:28:25,270
+وقلنا لكم كيف بتكون تحضروه انطلاقاً من البنزين how
+
+310
+00:28:25,270 --> 00:28:29,310
+can you prepare this compound this compound
+
+311
+00:28:29,310 --> 00:28:36,770
+starting from بنزين لاحظوا
+
+312
+00:28:36,770 --> 00:28:43,750
+معي لو أنا كنت بدي أبدأ تحضير عادي يعني البنزين و
+
+313
+00:28:43,750 --> 00:28:51,250
+بعدين أقول PR2 مثلاً و Aluminium Bromide أو FeBr3
+
+314
+00:28:51,250 --> 00:28:56,490
+مثلاً بيمشي
+
+315
+00:28:56,490 --> 00:29:03,130
+المفروض
+
+316
+00:29:03,130 --> 00:29:06,330
+لو بدنا نعمل هذا ال synthesis أول شيء بده تيجي إيش
+
+317
+00:29:06,330 --> 00:29:13,320
+أول PR بكويس لو افترضنا اجت أول PR بعد ذلك يجب أن
+
+318
+00:29:13,320 --> 00:29:17,740
+تتفعل مرة أخرى بعد ذلك يجب أن تتفعل مرة أخرى بعد
+
+319
+00:29:17,740 --> 00:29:18,900
+ذلك يجب أن تتفعل مرة أخرى بعد ذلك يجب أن تتفعل مرة
+
+320
+00:29:18,900 --> 00:29:18,960
+أخرى بعد ذلك يجب أن تتفعل مرة أخرى بعد ذلك يجب أن
+
+321
+00:29:18,960 --> 00:29:19,540
+تتفعل مرة أخرى بعد ذلك يجب أن تتفعل مرة أخرى بعد
+
+322
+00:29:19,540 --> 00:29:20,320
+ذلك يجب أن تتفعل مرة أخرى بعد ذلك يجب أن تتفعل مرة
+
+323
+00:29:20,320 --> 00:29:20,380
+أخرى بعد ذلك يجب أن تتفعل مرة أخرى بعد ذلك يجب أن
+
+324
+00:29:20,380 --> 00:29:26,980
+تتفعل مرة أخرى بعد ذلك يجب أن تتفعل مرة
+
+325
+00:29:26,980 --> 00:29:39,080
+أخرى بعد ذلك يجب أن تتفعل مرة أخرى بعد ذ
+
+326
+00:29:39,210 --> 00:29:42,950
+الـ bar .. الـ bar هل بيعطيني هذا الشكل اللي موجود
+
+327
+00:29:42,950 --> 00:29:47,510
+هنا؟ إذا ال multi substitution يعني أنه يصير إبدال
+
+328
+00:29:47,510 --> 00:29:51,170
+وبعده كمان إبدال وبعده كمان إبدال مش هيعطيني هذا
+
+329
+00:29:51,170 --> 00:29:56,310
+.. مش هيعطيني هذا بناءً على ذلك أنا بحاجة .. أنا
+
+330
+00:29:56,310 --> 00:30:02,510
+بحاجة إلى استراتيجية جديدة أنا بحاجة إلى
+
+331
+00:30:02,510 --> 00:30:05,890
+استراتيجية جديدة أشغل عليها
+
+332
+00:30:08,930 --> 00:30:13,190
+هذه الاستراتيجية الجديدة اللي عملوها بالشكل القادر
+
+333
+00:30:13,190 --> 00:30:19,530
+ال بنزين مش صعب عليهم يحولوه إلى نيترو بنزين هذه
+
+334
+00:30:19,530 --> 00:30:26,710
+صعبة ولا لا بستعملوا HNO3 H2SO4
+
+335
+00:30:26,710 --> 00:30:34,750
+النيترو بنزين برضه مش صعب عليهم يخلوه أنيلين يعني
+
+336
+00:30:34,750 --> 00:30:35,750
+NH2
+
+337
+00:30:39,370 --> 00:30:44,670
+نيكل ممتازة الآن الأنيلين is an activating group الـ
+
+338
+00:30:44,670 --> 00:30:49,230
+amino group اللي على الأنيلين is an activating
+
+339
+00:30:49,230 --> 00:30:56,230
+group و ortho-para directing والآن أناشطة هذه لو
+
+340
+00:30:56,230 --> 00:31:04,370
+فعلناها مع الـ PR2 بكمية كبيرة بتحط PR هنا وهنا و
+
+341
+00:31:04,370 --> 00:31:11,000
+هنا على التلات أماكن بتحط وين؟ على التلات أماكن يعني
+
+342
+00:31:11,000 --> 00:31:22,780
+بتحط لي nh2 و pr و pr و pr طيب الآن وصلنا لها
+
+343
+00:31:22,780 --> 00:31:28,480
+المرحلة المركب موجود بس فيه مشكلة إيش هي المشكلة
+
+344
+00:31:28,480 --> 00:31:36,380
+اللي فيه nh2 بدنا نتخلص منها بنقدر نتخلص منها كيف
+
+345
+00:31:36,380 --> 00:31:38,780
+نلغيها
+
+346
+00:31:40,390 --> 00:31:45,390
+عند الروضة بيلغيها بالمساحة مش فيه جلم لرصاص وإنه
+
+347
+00:31:45,390 --> 00:31:53,950
+مساحة بيمسحوها بدي أحولها لـ H كيف؟
+
+348
+00:31:53,950 --> 00:31:59,010
+طيب لسه أنا أخذت أن H2 بتصير دايزونيا يعني لما
+
+349
+00:31:59,010 --> 00:32:02,690
+نقول HNO2
+
+350
+00:32:02,690 --> 00:32:06,150
+بيصير
+
+351
+00:32:06,150 --> 00:32:16,340
+هنا N2 plus وهنا PR و PR و PR الـ N2 plus بإيش أخذنا
+
+352
+00:32:16,340 --> 00:32:29,540
+ال HbO3 H3bO2 الـ acid هذا بتصير H واضح؟
+
+353
+00:32:29,540 --> 00:32:39,520
+لأن أنا عند PR PR PR واضح
+
+354
+00:32:39,520 --> 00:32:46,280
+ولا لأ؟ هذه المسائل الأخيرة اللي احنا عمال بناخدها،
+
+355
+00:32:46,280 --> 00:32:54,520
+هذه قمة الكيمياء ولا لأ؟ لازم لما تكون آخر محاضرة،
+
+356
+00:32:54,520 --> 00:33:00,080
+تصلوا لإيش؟ لقمة الكيمياء، بس عارفين لما تصلوا لقمة
+
+357
+00:33:00,080 --> 00:33:07,060
+الكيمياء، بتكتشفوا أنه وصلتوا لإيش؟ ما هي العلوم في
+
+358
+00:33:07,060 --> 00:33:11,460
+الآخر انتبهوا معي العلوم في الآخر بتلاقوها بترجع
+
+359
+00:33:11,460 --> 00:33:18,040
+بتصب في مصب واحد بتكتشفوا إنكم وصلتوا لقمة المنطق
+
+360
+00:33:18,040 --> 00:33:23,700
+الإنساني والعلوم الإنسانية هذه الفكرة هذه الفكرة
+
+361
+00:33:23,700 --> 00:33:30,860
+قبل ما تكون فكرة كيميائية هي فكرة إنسانية بحتة بكل
+
+362
+00:33:30,860 --> 00:33:36,150
+معنى الكلمة موجودة في حياتنا الطبيعية ولما تفهموها
+
+363
+00:33:36,150 --> 00:33:39,750
+بالشكل بتحسوا قد إيش أنه الدنيا بتكبر .. بتكبر ..
+
+364
+00:33:39,750 --> 00:33:44,050
+بتكبر وبتعود إيش؟ تصغر احنا إيش اللي عملنا بهذه
+
+365
+00:33:44,050 --> 00:33:52,310
+الفكرة؟ احنا جبنا مجموعة الأمينو .. مجموعة الأمينو
+
+366
+00:33:52,310 --> 00:33:59,090
+اللي جبناها هنا استفدنا منها أي مستفادة ولا لأ؟ صح
+
+367
+00:33:59,090 --> 00:34:06,280
+ولا لأ؟ فادتنا بشغلتين فادتنا بشغل ثاني الشغلة الأولى
+
+368
+00:34:06,280 --> 00:34:09,760
+أنها activating يعني بتخلي البروم يتفعل تلات مرات
+
+369
+00:34:09,760 --> 00:34:14,740
+بسرعة والشغلة الثانية أنَّها ortho-paradirectal group
+
+370
+00:34:14,740 --> 00:34:19,640
+إذا أنا أنا نمرة واحد بقول ال NH2 اكتفت
+
+371
+00:34:19,640 --> 00:34:24,140
+اكتفت
+
+372
+00:34:24,140 --> 00:34:25,340
+اكتفت اكتفت اكتفت اكتفت اكتفت اكتفت اكتفت
+
+373
+00:34:25,340 --> 00:34:27,320
+اكتفت اكتفت اكتفت اكتفت اكتفت اكتفت اكتفت
+
+374
+00:34:27,320 --> 00:34:
+
+401
+00:37:08,500 --> 00:37:12,880
+واحد يبنيه قصر يعني ما حدش قاله قصر ازاي فكان هذا
+
+402
+00:37:12,880 --> 00:37:17,220
+المهندس أو البناء اسمه سليمار ثم بنى القصر هذا
+
+403
+00:37:17,220 --> 00:37:21,960
+كان عجيب غريب فالملك خاف أنه أي حد ييجي سليمار
+
+404
+00:37:21,960 --> 00:37:25,360
+يبني مثل هذا القصر فاشتبه حرماه من باب مصر ألا
+
+405
+00:37:25,360 --> 00:37:30,640
+يُبني لأحد مثل هذا يعني بعد ما بناله القصر قتله حتى
+
+406
+00:37:30,640 --> 00:37:36,960
+لا يبني مثله للآخرين ودرجة مثلا هذا جزاءه cinema
+
+407
+00:37:36,960 --> 00:37:42,300
+بيعمل معروف زي ال Amino group في الآخر بنرد نخليها 
+
+408
+00:37:42,300 --> 00:37:48,180
+hydrogen حال الدنيا هذا على أي حال يعني احنا بنأمل
+
+409
+00:37:48,180 --> 00:37:51,400
+بنأمل أنكم تكونوا استمتعتوا بمساق الكيمياء العضوية
+
+410
+00:37:51,400 --> 00:37:56,420
+بنعتذر شوية أن المساق كان رسمي لأنه كان فيه تصوير
+
+411
+00:37:57,870 --> 00:38:03,330
+لأ لأ لأ المساقات التانية صغيرة مش هذا كبير في
+
+412
+00:38:03,330 --> 00:38:06,790
+الجامعة هيك لازم يكون المساق إنما إذا في مساقات
+
+413
+00:38:06,790 --> 00:38:10,830
+بتاخدوها عشرين صفعة ده موضوع تاني إن شاء الله ربنا
+
+414
+00:38:10,830 --> 00:38:15,710
+يوفقكم بالامتحان، الامتحان يوم الثلاثاء القادم وأن 
+
+415
+00:38:15,710 --> 00:38:19,510
+يُحشر الناس وضاحا، ما أطيب أمنيات التوفيق
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..e52db0046840e4f67e664b9354771b5a20829aa7
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/ptga-V-eGF8_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2488, "start": 8.56, "end": 24.88, "text": "بسم الله الرحمن الرحيم اليوم إن شاء الله بتكون المحاضرة الأخيرة في هذا المساق وهي محاضرة سهلة وبسيطة عن بعض تفاعلات ال Amiens", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 45595, 20498, 36145, 13412, 16606, 21984, 39894, 30544, 9673, 5016, 46958, 25720, 16247, 9778, 48923, 8978, 23758, 9673, 3794, 995, 4587, 37037, 1829, 3714, 5016, 46958, 25720, 8608, 3224, 37977, 4032, 3555, 3794, 1829, 9566, 3660, 18871, 45030, 11242, 6055, 5172, 995, 30241, 9307, 2423, 2012, 24594], "avg_logprob": -0.12260142439290096, "compression_ratio": 1.5524475524475525, "no_speech_prob": 4.76837158203125e-07, "words": [{"start": 8.56, "end": 9.88, "word": "بسم", "probability": 0.8173828125}, {"start": 9.88, "end": 10.06, "word": " الله", "probability": 0.97314453125}, {"start": 10.06, "end": 10.42, "word": " الرحمن", "probability": 0.9720052083333334}, {"start": 10.42, "end": 10.96, "word": " الرحيم", "probability": 0.9934895833333334}, {"start": 10.96, "end": 12.72, "word": " اليوم", "probability": 0.89599609375}, {"start": 12.72, "end": 12.88, "word": " إن", "probability": 0.472412109375}, {"start": 12.88, "end": 13.1, "word": " شاء", "probability": 0.977783203125}, {"start": 13.1, "end": 13.32, "word": " الله", "probability": 0.96826171875}, {"start": 13.32, "end": 15.18, "word": " بتكون", "probability": 0.953369140625}, {"start": 15.18, "end": 15.86, "word": " المحاضرة", "probability": 0.990966796875}, {"start": 15.86, "end": 16.52, "word": " الأخيرة", "probability": 0.9853515625}, {"start": 16.52, "end": 16.74, "word": " في", "probability": 0.94873046875}, {"start": 16.74, "end": 17.02, "word": " هذا", "probability": 0.94775390625}, {"start": 17.02, "end": 17.7, "word": " المساق", "probability": 0.8990478515625}, {"start": 17.7, "end": 18.06, "word": " وهي", "probability": 0.83251953125}, {"start": 18.06, "end": 18.82, "word": " محاضرة", "probability": 0.9957275390625}, {"start": 18.82, "end": 20.02, "word": " سهلة", "probability": 0.98779296875}, {"start": 20.02, "end": 21.2, "word": " وبسيطة", "probability": 0.8929850260416666}, {"start": 21.2, "end": 22.16, "word": " عن", "probability": 0.98876953125}, {"start": 22.16, "end": 23.04, "word": " بعض", "probability": 0.986572265625}, {"start": 23.04, "end": 23.96, "word": " تفاعلات", "probability": 0.89638671875}, {"start": 23.96, "end": 24.3, "word": " ال", "probability": 0.88525390625}, {"start": 24.3, "end": 24.88, "word": " Amiens", "probability": 0.29705810546875}], "temperature": 1.0}, {"id": 2, "seek": 5419, "start": 25.95, "end": 54.19, "text": "طبعا سبق ان اتكلمنا انه يعني شعرة شمشوم الجبار خلينا نقول اللي في ال amines هي إيش زوج الإلكترونات يعني سر ال amines زوج الإلكترونات طالما ال amines زي ما بتلاحظوا مانا فيهم هذا الزوج من الإلكترونات إذا هم ممكن يتفاعلوا can you kill your files", "tokens": [9566, 3555, 3615, 995, 8608, 3555, 4587, 16472, 1975, 2655, 4117, 19528, 8315, 16472, 3224, 37495, 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بيتقن مبدأ بغض النظر عن كبر الجزية انا بتعامل مع مبدأ زوج إلكترونات بيهاجم على ال positive carbon بيطرد ايش ال CL طبعا بالتأكيد بدكوا تكونوا متذاكرين ان هذه ال amines لو كانت بتهاجم على الديهيد او كيتون هتعمل ابدال", "tokens": [7649, 3224, 8978, 43242, 7578, 8032, 7435, 20498, 4032, 35827, 16472, 3224, 8978, 43242, 7578, 8032, 7435, 20498, 4032, 35827, 5296, 5016, 19913, 3660, 13672, 7578, 4724, 36081, 4587, 1863, 3714, 44510, 10721, 4724, 17082, 11242, 28239, 19913, 2288, 18871, 9122, 26890, 25724, 11622, 10632, 1975, 8315, 39894, 3615, 10943, 1211, 20449, 3714, 44510, 10721, 30767, 29245, 11933, 23275, 2655, 2288, 11536, 9307, 4724, 1829, 3224, 26108, 2304, 15844, 2423, 3353, 5954, 4724, 1829, 9566, 2288, 3215, 1975, 1829, 8592, 2423, 12855, 23032, 3555, 3615, 995, 20666, 2655, 10721, 4117, 25708, 47525, 4117, 14407, 6055, 30544, 14407, 44650, 15730, 37983, 9957, 16472, 29538, 2423, 669, 1652, 45164, 25961, 2655, 39894, 3224, 26108, 2304, 15844, 2423, 16254, 3224, 25708, 1975, 2407, 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إلا بإيش؟ إلا بالتجربة، لأنه في النهاية الكيمياء بتضال زي ما حكينا كتير علم تجريبي، علم تجريبي، واضح؟", "tokens": [3555, 3794, 45164, 25961, 23758, 32771, 13546, 44650, 2304, 5718, 104, 1211, 12399, 37495, 22653, 21136, 25708, 5551, 3555, 2407, 29739, 11536, 6055, 39648, 34105, 8717, 5172, 2655, 43042, 50113, 1211, 2423, 3224, 7649, 31845, 9957, 1211, 3714, 43020, 10874, 11622, 38207, 7251, 2655, 5172, 995, 30241, 15844, 29538, 49610, 11622, 38207, 15844, 29538, 4032, 21292, 9566, 1211, 3615, 8717, 2407, 9307, 7251, 7435, 1829, 3555, 8717, 35457, 3714, 46456, 46538, 3660, 20193, 6055, 24401, 3215, 11933, 15040, 4724, 28814, 1829, 8592, 22807, 11933, 15040, 20666, 2655, 7435, 25513, 3660, 12399, 5296, 33456, 3224, 8978, 28239, 11296, 10632, 33251, 32640, 1829, 16606, 39894, 11242, 6027, 30767, 1829, 19446, 11331, 4117, 1829, 8315, 9122, 2655, 13546, 11203, 2304, 6055, 7435, 16572, 21292, 12399, 11203, 2304, 6055, 7435, 16572, 21292, 12399, 4032, 46958, 5016, 22807], "avg_logprob": 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41, "seek": 99227, "start": 970.67, "end": 992.27, "text": "من ال nitro benzene و ال nitro benzene من ال benzene فكأنه صار عنده يعني سلسلة benzene, nitro benzene بال reduction بصير aniline، ال aniline بال sodium nitrite أو ال nitrous acid بصير diazonium salt، ال diazonium salt مع H plus, H2O بصير phylon", "tokens": [27842, 2423, 10900, 340, 44335, 1450, 4032, 2423, 10900, 340, 44335, 1450, 9154, 2423, 44335, 1450, 6156, 4117, 33456, 3224, 20328, 9640, 43242, 3224, 37495, 22653, 8608, 1211, 3794, 37977, 44335, 1450, 11, 10900, 340, 44335, 1450, 20666, 11004, 4724, 9381, 13546, 364, 388, 533, 12399, 2423, 364, 388, 533, 20666, 20265, 10900, 35002, 34051, 2423, 10900, 21189, 8258, 4724, 9381, 13546, 6801, 35296, 2197, 5139, 12399, 2423, 6801, 35296, 2197, 5139, 20449, 389, 1804, 11, 389, 17, 46, 4724, 9381, 13546, 903, 34926], "avg_logprob": -0.26158087113324335, "compression_ratio": 1.7, "no_speech_prob": 1.1324882507324219e-06, "words": [{"start": 970.67, "end": 970.97, "word": "من", 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ممكن في الأصل ال 9", "tokens": [9566, 45865, 5296, 3794, 3224, 5551, 9778, 3215, 8315, 2423, 14589, 9154, 4032, 9957, 10874, 995, 10632, 22807, 9154, 2423, 22653, 31377, 2407, 2423, 568, 1804, 12399, 3714, 19913, 3555, 2407, 9566, 22807, 2423, 22653, 31377, 2407, 9154, 4032, 9957, 10874, 995, 10632, 22807, 9154, 2423, 426, 389, 568, 3714, 43020, 8978, 16247, 36520, 2423, 1722], "avg_logprob": -0.3538925480424312, "compression_ratio": 1.492063492063492, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 1446.91, "end": 1447.29, "word": "طوي", "probability": 0.3824462890625}, {"start": 1447.29, "end": 1447.55, "word": " لسه", "probability": 0.9417317708333334}, {"start": 1447.55, "end": 1448.01, "word": " أخدنا", "probability": 0.9183349609375}, {"start": 1448.01, "end": 1448.11, "word": " ال", "probability": 0.87060546875}, {"start": 1448.11, "end": 1448.27, "word": " CN", "probability": 0.1827392578125}, {"start": 1448.27, "end": 1448.51, "word": " من", "probability": 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"text": "لأ لأ لأ المساقات التانية صغيرة مش هذا كبير في الجامعة هيك لازم يكون المساق إنما إذا في مساقات بتاخدوها عشرين صفعة ده موضوع تاني ان شاء الله ربنا يوفقكوا بالامتحان، الامتحان يوم التلاتة القادم وأن يحشر الناس وضحا، ما أطيب أمنيات التوفير", "tokens": [1211, 10721, 5296, 10721, 5296, 10721, 9673, 3794, 995, 4587, 9307, 16712, 7649, 10632, 20328, 17082, 48923, 37893, 23758, 9122, 3555, 13546, 8978, 25724, 10943, 27884, 39896, 4117, 5296, 31377, 2304, 7251, 30544, 9673, 3794, 995, 4587, 36145, 15042, 11933, 15730, 8978, 47524, 995, 4587, 9307, 39894, 47283, 3215, 2407, 11296, 6225, 46309, 9957, 20328, 5172, 27884, 11778, 3224, 3714, 2407, 11242, 45367, 6055, 7649, 1829, 16472, 13412, 16606, 21984, 12602, 3555, 8315, 7251, 38688, 4587, 4117, 14407, 20666, 10943, 2655, 5016, 7649, 12399, 2423, 10943, 2655, 5016, 7649, 7251, 20498, 16712, 1211, 9307, 3660, 25062, 18513, 2304, 4032, 33456, 7251, 5016, 46309, 2423, 8315, 3794, 4032, 11242, 5016, 995, 12399, 19446, 5551, 9566, 1829, 3555, 5551, 2304, 22653, 9307, 16712, 38688, 13546], "avg_logprob": -0.1446572531375193, "compression_ratio": 1.9196428571428572, "no_speech_prob": 6.556510925292969e-07, "words": [{"start": 2277.87, "end": 2278.25, "word": "لأ", "probability": 0.7152099609375}, {"start": 2278.25, "end": 2278.43, "word": " لأ", "probability": 0.93017578125}, {"start": 2278.43, "end": 2278.79, "word": " لأ", "probability": 0.862060546875}, {"start": 2278.79, "end": 2280.41, "word": " المساقات", "probability": 0.8861328125}, {"start": 2280.41, "end": 2280.89, "word": " التانية", "probability": 0.9715169270833334}, {"start": 2280.89, "end": 2281.35, "word": " صغيرة", "probability": 0.9910481770833334}, {"start": 2281.35, "end": 2281.57, "word": " مش", "probability": 0.84033203125}, {"start": 2281.57, "end": 2281.85, "word": " هذا", "probability": 0.303466796875}, {"start": 2281.85, "end": 2282.37, "word": " كبير", "probability": 0.9957682291666666}, {"start": 2282.37, "end": 2283.33, "word": " في", "probability": 0.71337890625}, {"start": 2283.33, "end": 2283.95, "word": " الجامعة", "probability": 0.9650065104166666}, {"start": 2283.95, "end": 2284.23, "word": " هيك", "probability": 0.9658203125}, {"start": 2284.23, "end": 2284.61, "word": " لازم", "probability": 0.9931640625}, {"start": 2284.61, "end": 2284.87, "word": " يكون", "probability": 0.9912109375}, {"start": 2284.87, "end": 2285.39, "word": " المساق", "probability": 0.98388671875}, {"start": 2285.39, "end": 2285.73, "word": " إنما", "probability": 0.64208984375}, {"start": 2285.73, "end": 2285.95, "word": " إذا", "probability": 0.941162109375}, {"start": 2285.95, "end": 2286.15, "word": " في", "probability": 0.8642578125}, {"start": 2286.15, "end": 2286.79, "word": " مساقات", "probability": 0.9326171875}, {"start": 2286.79, "end": 2287.31, "word": " بتاخدوها", "probability": 0.94208984375}, {"start": 2287.31, "end": 2287.73, "word": " عشرين", "probability": 0.9607747395833334}, {"start": 2287.73, "end": 2288.07, "word": " صفعة", "probability": 0.8094889322916666}, {"start": 2288.07, "end": 2288.23, "word": " ده", "probability": 0.926513671875}, {"start": 2288.23, "end": 2288.61, "word": " موضوع", "probability": 0.9974365234375}, {"start": 2288.61, "end": 2289.11, "word": " تاني", "probability": 0.9763997395833334}, {"start": 2289.11, "end": 2290.17, "word": " ان", "probability": 0.5}, {"start": 2290.17, "end": 2290.41, "word": " شاء", "probability": 0.945556640625}, {"start": 2290.41, "end": 2290.51, "word": " الله", "probability": 0.95654296875}, {"start": 2290.51, "end": 2290.83, "word": " ربنا", "probability": 0.96923828125}, {"start": 2290.83, "end": 2291.37, "word": " يوفقكوا", "probability": 0.8623046875}, {"start": 2291.37, "end": 2292.13, "word": " بالامتحان،", "probability": 0.8758951822916666}, {"start": 2292.13, "end": 2292.61, "word": " الامتحان", "probability": 0.9654296875}, {"start": 2292.61, "end": 2292.95, "word": " يوم", "probability": 0.99365234375}, {"start": 2292.95, "end": 2293.93, "word": " التلاتة", "probability": 0.9671630859375}, {"start": 2293.93, "end": 2295.41, "word": " القادم", "probability": 0.9923502604166666}, {"start": 2295.41, "end": 2295.71, "word": " وأن", "probability": 0.524658203125}, {"start": 2295.71, "end": 2296.15, "word": " يحشر", "probability": 0.9596354166666666}, {"start": 2296.15, "end": 2296.67, "word": " الناس", "probability": 0.9768880208333334}, {"start": 2296.67, "end": 2297.87, "word": " وضحا،", "probability": 0.61328125}, {"start": 2297.87, "end": 2297.99, "word": " ما", "probability": 0.5244140625}, {"start": 2297.99, "end": 2298.35, "word": " أطيب", "probability": 0.80511474609375}, {"start": 2298.35, "end": 2298.85, "word": " أمنيات", "probability": 0.90771484375}, {"start": 2298.85, "end": 2299.51, "word": " التوفير", "probability": 0.9267578125}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2302.1655, "duration_after_vad": 2205.666593749994}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U.srt
new file mode 100644
index 0000000000000000000000000000000000000000..eeef723bea716b8b4417cac65150158129321d5a
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U.srt
@@ -0,0 +1,1858 @@
+1
+00:00:15,180 --> 00:00:19,600
+بسم الله الرحمن الرحيم، بنكمل اليوم إن شاء الله في
+
+2
+00:00:19,600 --> 00:00:25,620
+موضوع الamines. المحاضرة الماضية أخذنا تسمية ال
+
+3
+00:00:25,620 --> 00:00:30,580
+amines و أخذنا بشكل عام طريقتين، اللي هما ال IUPAC 
+
+4
+00:00:30,580 --> 00:00:36,840
+method وال common method. لو مثلاً بدنا نؤكد على
+
+5
+00:00:36,840 --> 00:00:41,400
+هالكلام ونضيف أنه في طريقة ثالثة أحياناً موجودة
+
+6
+00:00:41,400 --> 00:00:46,140
+أيضاً في الاستعمال، حتى إذا يعني قرأت اسمها  باستعمالها
+
+7
+00:00:46,140 --> 00:00:50,660
+ما يكونش غريب عليكم. لو أخذنا مثلاً أربع ذرات كربون
+
+8
+00:00:50,660 --> 00:00:54,740
+عليهم amino group و بدنا نسمي بال IUPAC 
+
+9
+00:00:54,740 --> 00:00:58,200
+Nomenclature، بنقول one amino بيوتان. احنا اتفقنا أن
+
+10
+00:00:58,200 --> 00:01:03,660
+ال amino تعمل كمجموعة كـ substitute. لو بدنا نسمي
+
+11
+00:01:03,660 --> 00:01:07,420
+بال common name، بناخد هذه المجموعة بيوتل و بنقول
+
+12
+00:01:07,420 --> 00:01:13,320
+بيوتيل أمين. هذا ال IUPAC name، هذا ال common name. في 
+
+13
+00:01:13,320 --> 00:01:19,340
+طريقة ثالثة للتسمية، بيسموها chemical abstract name 
+
+14
+00:01:19,340 --> 00:01:26,340
+الـ CA. هذه اختصار لإيش؟ لـ chemical abstract.
+
+15
+00:01:30,350 --> 00:01:35,090
+الـ chemical abstracts هي الفهارس اللي بتلخص الجديد
+
+16
+00:01:35,090 --> 00:01:38,110
+في علم الكيمياء، و بتصدرها الجامعية الكيميائية 
+
+17
+00:01:38,110 --> 00:01:42,290
+الأمريكية. واضح؟ فهدول لما بيعملوا ملخصات وما إلى
+
+18
+00:01:42,290 --> 00:01:47,250
+ذلك، بيسموا ال amines بطريقة غير ال IUPAC و
+
+19
+00:01:47,250 --> 00:01:50,880
+غير ال common name، بيسموها ال chemical abstract
+
+20
+00:01:50,880 --> 00:01:56,740
+name. بهاد الطريقة بيحاولوا يخلوا مجموعة الأمين زي
+
+21
+00:01:56,740 --> 00:02:00,660
+تماماً ما كانت مجموعة ال alcohol. يعني لما كانت
+
+22
+00:02:00,660 --> 00:02:03,660
+مجموعة ال alcohol كانت تعتبر functional group 
+
+23
+00:02:03,660 --> 00:02:08,780
+وبتعطي النهاية -ol. فلو كان أنا عندي أربع ذرات كربون، شو
+
+24
+00:02:08,780 --> 00:02:14,480
+كنت اسمي المركب؟ بيوتان-ol. هم بيقولوا كمان ال amine
+
+25
+00:02:14,480 --> 00:02:19,860
+مش أقل يعني قيمة من ال alcohol، فسموا المركب بيوتان
+
+26
+00:02:19,860 --> 00:02:25,980
+amine. واضح؟ فكأنه بيعملوا الأمين كإنها functional 
+
+27
+00:02:25,980 --> 00:02:30,500
+group اسمها amine. لاحظوا، بتختلف عن ال common name، ال
+
+28
+00:02:30,500 --> 00:02:35,740
+common name احنا بنحط اسم المجموعة، أنا بيوتيل أمين.
+
+29
+00:02:35,740 --> 00:02:42,640
+هنا بيحط اسم الألكان، بيوتان أمين، تماماً زي ما كنا 
+
+30
+00:02:42,640 --> 00:02:49,180
+نقول للألكول بيوتان-ol ولا  الـ aldehyde بيوتان-al 
+
+31
+00:02:49,180 --> 00:02:54,600
+ولا الأمين بيقول يكون بيوتان أمين، فكأنه الألكول 
+
+32
+00:02:54,600 --> 00:02:58,620
+بهذه الحالة... الأمين عفواً، بهذه الحالة بيمثل
+
+33
+00:02:58,620 --> 00:03:03,050
+functional group بنسميها إيش؟ أمين. ما بدناش ناخد كل
+
+34
+00:03:03,050 --> 00:03:07,350
+الأمثلة، ممكن ناخد مثال أو اثنين تأكيديين، مثلاً هنا 
+
+35
+00:03:07,350 --> 00:03:11,650
+لو بدي هذا المركب، واحد اثنين ثلاثة، إذا هذا بروبان
+
+36
+00:03:11,650 --> 00:03:17,450
+في أي IUPAC nomenclature، على موقع اثنين عند amino وعند 
+
+37
+00:03:17,450 --> 00:03:24,410
+مثيل، فبيصير two amino two مثيل بروبان. لو بدي ال
+
+38
+00:03:24,410 --> 00:03:27,430
+common name، باخد هذه كلها كمجموعة، أربع ذرات
+
+39
+00:03:27,430 --> 00:03:32,600
+الكربون اللي فيهم، تشبه في جعبات الـ tertiary بيوت 
+
+40
+00:03:32,600 --> 00:03:37,120
+الأمين الآن. لو كنت بدي أسميه على ال chemical
+
+41
+00:03:37,120 --> 00:03:42,840
+abstract nomenclature، هذا بدي يكون two بروبان أمين
+
+42
+00:03:42,840 --> 00:03:47,660
+و بنحط عليه وجود مجموعة المثيل، يعني أي واحد
+
+43
+00:03:47,660 --> 00:03:54,340
+اثنين ثلاثة، لو كان OH قولنا two بروبان-ol، هنا أمين
+
+44
+00:03:54,340 --> 00:04:02,180
+two بروبان أمين two مثيل two بروبان أمين وهكذا
+
+45
+00:04:02,180 --> 00:04:08,400
+بإمكانكم تشوفوا التسميات، الأشكال اللي تحت هذه هي
+
+46
+00:04:08,400 --> 00:04:12,500
+بعض المركبات اللي موجودة في التطبيق، و ما عدا
+
+47
+00:04:12,500 --> 00:04:17,900
+المركب الأول، كله بنسميها احنا مركبات حلقية غير
+
+48
+00:04:17,900 --> 00:04:22,300
+متجانسة. إيش يعني غير متجانسة؟ يعني الحلقة مش كلها
+
+49
+00:04:22,300 --> 00:04:26,760
+كربون، الحلقة فيها كربون و ذرات غير الكربون. من هنا
+
+50
+00:04:26,760 --> 00:04:33,820
+جاء عدم التجانس. واضح؟ وهذه لها الحقيقة استعمالات 
+
+51
+00:04:33,820 --> 00:04:37,380
+كثيرة في التطبيق، لكن احنا في الكيمياء بندرسها بمساق
+
+52
+00:04:37,380 --> 00:04:42,400
+كامل بسنة رابعة، بنسميه heterocyclic chemistry. فإذا
+
+53
+00:04:42,400 --> 00:04:46,480
+سمعتوا مركبات من هالنوع: اندول، بيريدين، بيريديل
+
+54
+00:04:46,480 --> 00:04:50,840
+بيريميدين، بايروليدين، بايرول، إيميدازول،  وإلخ... كل هذه 
+
+55
+00:04:50,840 --> 00:04:56,840
+برضه مركبات تحتوي على اللي هي ال nitrogen موجودة
+
+56
+00:04:56,840 --> 00:05:01,580
+لكن مش هنا مجال دراستها. البنزين اللي عليه أنيلين، 
+
+57
+00:05:01,580 --> 00:05:10,540
+علمناها ده: أنيلين ومشتقاته. الآن لو إجينا لـ ال 
+
+58
+00:05:10,540 --> 00:05:15,780
+physical properties of amines. طبعاً إذا بنركز على
+
+59
+00:05:16,740 --> 00:05:20,720
+الـ boiling point، إذا بنركز على ال boiling point
+
+60
+00:05:20,720 --> 00:05:28,100
+بنلاحظ إنه ال amines بشكل عام ممكن تعمل مع نفسها
+
+61
+00:05:28,100 --> 00:05:33,820
+نوع من ال hydrogen bonding. يعني H من أمين بتعمل
+
+62
+00:05:33,820 --> 00:05:40,100
+hydrogen bonding مع أمين ثاني. ولذلك إذا يعني بنطلع
+
+63
+00:05:40,100 --> 00:05:45,520
+أحياناً بنلاحظ أنه نسبياً ممكن تكون عالية، بعض ال
+
+64
+00:05:45,520 --> 00:05:49,100
+amines ال boiling point، لكن مش كثير، مش زي ال
+
+65
+00:05:49,100 --> 00:05:53,940
+alcohol، يعني مش بقوة ال hydrogen bonding تبعت ال 
+
+66
+00:05:53,940 --> 00:05:59,570
+alcohol. لو... يعني بتكون تنظروا مثلاً إلى ثلاثة 
+
+67
+00:05:59,570 --> 00:06:03,950
+مراكبات، تقريباً التلاتة مراكبات ماخذين نفس ال
+
+68
+00:06:03,950 --> 00:06:06,970
+molecular weight، يعني ال molecular weight ثلاثة و
+
+69
+00:06:06,970 --> 00:06:10,910
+واحد، وثلاثة اثنين، وثلاثة. لاحظوا ال Ethane بـ
+
+70
+00:06:10,910 --> 00:06:14,790
+molecular weight ثلاثة، ال boiling point تبعته ناقص 
+
+71
+00:06:14,790 --> 00:06:22,020
+ثمانية وثمانين. واضح؟ الآن الـ Methyl الـ molecular 
+
+72
+00:06:22,020 --> 00:06:27,200
+weight 32، قريب منه ال boiling point plus 65. الآن
+
+73
+00:06:27,200 --> 00:06:30,080
+إيش اللي رفعه؟ يعني نفترض أن التلاتة دول ال
+
+74
+00:06:30,080 --> 00:06:33,800
+molecular weight متساوي، شو اللي رفعه؟ 88 درجة و 
+
+75
+00:06:33,800 --> 00:06:40,060
+65، يعني بحكي أنا عن حوالي 140، 150 درجة ارتفاع 
+
+76
+00:06:40,780 --> 00:06:44,960
+الهيدروجين bond اللي بتعملها الـ alcohol، واضح؟
+
+77
+00:06:44,960 --> 00:06:49,160
+الآن لو إجينا واطلعنا على الميثيل أمين، باللاحظ
+
+78
+00:06:49,160 --> 00:06:55,020
+الميثيل أمين minus 6.3، برضه نسبياً مرتفع فوق ال 80
+
+79
+00:06:55,020 --> 00:07:00,260
+درجة عن الإيثان. إيش السبب؟ برضه الـ hydrogen 
+
+80
+00:07:00,260 --> 00:07:03,000
+bonding، لكن إحنا اللي بنقوله إنه الـ hydrogen 
+
+81
+00:07:03,000 --> 00:07:08,020
+bonding في الألكوهولز أعلى منه في الأمينز، بس
+
+82
+00:07:08,020 --> 00:07:12,060
+بالتأكيد في بالأمينز hydrogen bonding عمال رفعتها 
+
+83
+00:07:12,060 --> 00:07:16,240
+عن مركب موازي مع دوم الـ hydrogen bonding، هنا في
+
+84
+00:07:16,240 --> 00:07:21,360
+الـ إيثين 80 درجة، واضح؟ فدول الـ 80 درجة من وين
+
+85
+00:07:21,360 --> 00:07:28,900
+إجوا؟ هيدروجين bond، هيدروجين 
+
+86
+00:07:28,900 --> 00:07:29,500
+bond، هيدروجين bond، هيدروجين bond، هيدروجين
+
+87
+00:07:29,500 --> 00:07:31,920
+bond، هيدروجين bond، هيدروجين bond، هيدروجين
+
+88
+00:07:31,920 --> 00:07:34,160
+bond، هيدروجين bond، هيدروجين bond، هيدروجين
+
+89
+00:07:34,160 --> 00:07:38,140
+bond، هيدروجين bond، هيدروجين bond، هيدروجين
+
+90
+00:07:38,140 --> 00:07:42,820
+bond، هيدروجين bond، هيدروجين bond، هيدروجين
+
+91
+00:07:42,820 --> 00:07:50,160
+bond، هيدروجين bond، هيدروجين 
+
+92
+00:07:50,160 --> 00:07:54,400
+bond. يعني مثلاً لو بدنا ناخد مقارنة... لو بدنا
+
+93
+00:07:54,400 --> 00:07:57,680
+ناخد مقارنة بين هذا المركب اللي هو الـ 
+
+94
+00:07:57,680 --> 00:08:01,620
+dimethylamine و هذا المركب اللي هو ال
+
+95
+00:08:01,620 --> 00:08:05,340
+trimethylamine، رغم أن هذا عمال بيزيد في ال
+
+96
+00:08:05,340 --> 00:08:09,480
+molecular weight لكن الـ dimethylamine ما زال فيه 
+
+97
+00:08:09,480 --> 00:08:13,380
+hydrogen، الـ trimethylamine ما فيش فيه hydrogen،
+
+98
+00:08:13,380 --> 00:08:17,170
+رغم أن هذا أصغر في الوزن في ال molecular weight 
+
+99
+00:08:17,170 --> 00:08:21,570
+أصغر بسبعة مثلاً، لكن لاحظوا ال boiling point تبعته
+
+100
+00:08:21,570 --> 00:08:25,550
+سبع درجات تقريباً، بينما ال boiling point هنا ثلاثة
+
+101
+00:08:25,550 --> 00:08:30,990
+درجات. ليش الـ trimethylamine كان أقل من ال
+
+102
+00:08:30,990 --> 00:08:34,650
+dimethylamine؟ 
+
+103
+00:08:34,650 --> 00:08:40,350
+لأن الـ trimethylamine ما فيش فيه hydrogen bonding
+
+104
+00:08:40,350 --> 00:08:47,110
+واضح؟ لأنه ما فيش فيه hydrogen bonding. طبعاً الميثيل
+
+105
+00:08:47,110 --> 00:08:51,050
+أمين بيعمل hydrogen bonding لكن في شكل عام هو 
+
+106
+00:08:51,050 --> 00:08:57,030
+بيكون غاز. يلاحظوا minus 6.3، والغازات بتقدروا 
+
+107
+00:08:57,030 --> 00:09:01,550
+تتذكروا العلاقة الأساسية بينها أنه تعامل كأنها 
+
+108
+00:09:01,550 --> 00:09:06,770
+جزيئات منفصلة لأنه خفيف كثير، وبيحكمها ال kinetic
+
+109
+00:09:06,770 --> 00:09:11,890
+theory. جزيئات بتتحرك و بتتصادم في جدار الإناء، لكن
+
+110
+00:09:11,890 --> 00:09:16,240
+المقارنة هنا واضحة بين الداي ميثيل أمين والـ Tri
+
+111
+00:09:16,240 --> 00:09:21,480
+-methylamine، أعلى في الـ boiling point بسبب أنه 
+
+112
+00:09:21,480 --> 00:09:24,500
+عنده إمكانية hydrogen bonding وهذه الإمكانية غير
+
+113
+00:09:24,500 --> 00:09:31,640
+موجودة في الـ Tri-methylamine. الآن كيف تحضر ال 
+
+114
+00:09:31,640 --> 00:09:37,040
+amines؟ هتلاحظوا إنه في مجموعة من الطرق، احنا مرت
+
+115
+00:09:37,040 --> 00:09:41,760
+علينا مثلاً الطريقة الأولى، إنه احنا بنحضر ال amine
+
+116
+00:09:41,760 --> 00:09:45,760
+من خلال reduction of amides، بليثيوم ألومنيوم
+
+117
+00:09:45,760 --> 00:09:50,280
+هيدريد. هذه
+
+118
+00:09:50,280 --> 00:09:54,480
+الطريقة مرت علينا لما درسنا ال amides، قلنا بنحول 
+
+119
+00:09:54,480 --> 00:10:03,390
+الـ carbonyl bond O إلى CH2، يعني بيتم إضافة H- على
+
+120
+00:10:03,390 --> 00:10:09,430
+مرتين. وهذه دوري ست في ال chemistry of amides، أنه 
+
+121
+00:10:09,430 --> 00:10:17,000
+amides are reduced to amines. الطريقة الثانية، لو 
+
+122
+00:10:17,000 --> 00:10:20,720
+بدنا نتطلع على الـ Nitro Compounds، لو بدنا نتطلع
+
+123
+00:10:20,720 --> 00:10:23,640
+على الـ Nitro Compounds وخلّيني أذكركم أن الـ
+
+124
+00:10:23,640 --> 00:10:27,740
+Nitro Compounds كنا بنجيبهم احنا من البنزين، يعني
+
+125
+00:10:27,740 --> 00:10:30,820
+لو بدنا نيترو بنزين، الـ Nitro aromatic Compounds
+
+126
+00:10:30,820 --> 00:10:39,420
+كنت أستعمل البنزين، أستعمل Nitric Acid و H2SO4 
+
+127
+00:10:39,420 --> 00:10:45,850
+فبناء على ذلك، البنزين ممكن نعمله نيتراشن. الآن ال 
+
+128
+00:10:45,850 --> 00:10:49,450
+Nitro برضه بنعمل لها reduction، وعادة ال reduction
+
+129
+00:10:49,450 --> 00:10:55,530
+هنا بـ hydrogen زائد مثل مثل زي nickel أو platinum
+
+130
+00:10:55,530 --> 00:11:02,430
+هذا ال reduction بيحول ال NO2 إلى NH2. لاحظوا معنى
+
+131
+00:11:02,430 --> 00:11:07,050
+شغلة مهمة جداً، وخطأ كثير بيقعوا فيه الطلاب، إنه لما 
+
+132
+00:11:07,050 --> 00:11:12,290
+نيجي نقولهم كيف يحضر ال aniline كثير كثير بيعملوا 
+
+133
+00:11:12,290 --> 00:11:16,030
+غلطة. هم بيوصوا إن الواحد ما يكتبش الشيء الغلط، بلاش 
+
+134
+00:11:16,030 --> 00:11:20,110
+تروح تترسخ في ذهن الناس، بس هذا إذا صرتم علمّات
+
+135
+00:11:20,110 --> 00:11:26,620
+للمرحلة الابتدائية. ممنوع تكتبوا الغلط، واضح؟ للمراحل
+
+136
+00:11:26,620 --> 00:11:29,260
+الابتدائية والإعدادية بيقولوا ما تكتبش الغلط، ما
+
+137
+00:11:29,260 --> 00:11:35,080
+تكتبش قدامه إلا الصح. في مرحلة جامعية، ممكن الواحد
+
+138
+00:11:35,080 --> 00:11:38,320
+يكتب الغلط. الغلط اللي دائماً بينعمل، إنه لما نقول
+
+139
+00:11:38,320 --> 00:11:44,760
+كيف تحضر الأنيليين، بيجوا ناس بيقولوا لنا بنزين مع NH3
+
+140
+00:11:44,760 --> 00:11:48,480
+و بيحطوا H اللي بيجي على بالهم، و بيعطي أنيلين. هذا
+
+141
+00:11:48,480 --> 00:11:54,870
+إيش؟ قبل ما تشوفوا الكاميرا... هذا أخطاء مش خطأ واحد، 
+
+142
+00:11:54,870 --> 00:11:58,650
+بنعتبره. الأنيليين بتحضرش من البنزين مع الأمونيا. 
+
+143
+00:11:58,650 --> 00:12:02,890
+طبعاً لو بدنا نقول ليش طيب؟ هذا يعني مستحيل، وبنخوف 
+
+144
+00:12:02,890 --> 00:12:09,430
+ونشرح له أربع أخطاء، لأنه اتفقنا احنا أن التفاعل
+
+145
+00:12:09,430 --> 00:12:15,390
+الأساسي تبع البنزين هو أن نضيف عليه شيء موجب، وال
+
+146
+00:12:15,390 --> 00:12:24,090
+ammonia هذه، ال NH3 بتحمل زوج من الإلكترونات، وهنا
+
+147
+00:12:24,090 --> 00:12:28,690
+في عندي أزواج من الإلكترونات. هل يا ترى بقدر أجيب 
+
+148
+00:12:28,690 --> 00:12:34,690
+أنا إلكترونات على إلكترونات؟ لأ، لذلك دائماً اللي بده
+
+149
+00:12:34,690 --> 00:12:38,250
+يجي يهاجم على البنزين اللي بده يكون بشكل عام موجب
+
+150
+00:12:38,250 --> 00:12:41,810
+عشانك لما درسنا ال Nitration قلنا إن هدول
+
+151
+00:12:41,810 --> 00:12:47,770
+الحامضين مع بعض بيعطونا NO2 plus هي اللي بتهاجم
+
+152
+00:12:47,770 --> 00:12:52,750
+على ال minus. ولذلك هذا التحضير، إن أنا بتحضر
+
+153
+00:12:52,750 --> 00:12:57,370
+الأنيليين مباشرة بأمونيا مع بنزين، هذا كلام لا يجوز
+
+154
+00:12:57,370 --> 00:13:01,990
+والسبب إن أنا ما بقدرش أضيف سالب على سالب. أنا اللي
+
+155
+00:13:01,990 --> 00:13:06,210
+بدي أضيف، بدي أضيف موجب على سالب. ولذلك إذا بدنا 
+
+156
+00:13:06,210 --> 00:13:10,630
+نسألكم كيف بتحضروا الأنيليين، أو ممكن نكون مصعبين
+
+157
+00:13:10,630 --> 00:13:17,830
+السؤال، مثل: أنيلين مثلاً، كيف بدكم تمشوها؟ بدنا
+
+158
+00:13:20,160 --> 00:13:25,360
+نبدأ من البنزين ونستعمل عملية ال Nitration طبعاً
+
+159
+00:13:25,360 --> 00:13:29,940
+كأنيليين بنحولها لنيترو، بعدين هالـ نيترو بالـ
+
+160
+00:13:29,940 --> 00:13:34,260
+reduction. الآن لو كان في عندك أكثر من Substituent 
+
+161
+00:13:34,260 --> 00:13:41,400
+في هذه الحالة لازم أنتبه لعملية الترتيب، أي واحدة
+
+162
+00:13:41,400 --> 00:13:46,540
+نحطها في الأول. يعني مثلاً لو كان السؤال عندكم إن
+
+163
+00:13:46,540 --> 00:13:53,260
+كيف بدي أحضر ال NH2CH3
+
+164
+00:13:53,260 --> 00:13:58,540
+واضح؟
+
+165
+00:13:58,540 --> 00:14:03,920
+قدر
+
+166
+00:14:03,920 --> 00:14:09,140
+الإمكانية، نعتبر إن الـ NH2 أصلها إيش؟ يعني هذه جاية
+
+167
+00:14:09,140 --> 00:14:19,420
+من إيش؟ أصلها نيترو، هذه أصلها. بناء على ذلك، لو كنت
+
+168
+00:14:19,420 --> 00:14:23,760
+بتبدأ بالمثيل، المثيل بتوجه بارا، لو كنت بتبدأ
+
+169
+00:14:23,760 --> 00:14:31,500
+بالنيترو، النيترو بتوجه ميتا، النيترو is a 
+
+170
+00:14:31,500 --> 00:14:35,580
+meta-directing group، الـ amino para-directing
+
+171
+00:14:35,580 --> 00:14:38,920
+group، بس النيترو ميتا، انتبهوا معايا، هذي
+
+172
+00:14:38,920 --> 00:14:
+
+201
+00:16:58,900 --> 00:17:03,620
+أقول بنزين مع OH- اللي هو ما عطيني الفينول هنتعلم
+
+202
+00:17:03,620 --> 00:17:08,920
+طريقة إن شاء الله كيف نحضر الفينول بطريق غير مباشر
+
+203
+00:17:08,920 --> 00:17:13,220
+بس ما نقدرش نحضره بمباشر فإذا سئلته عن الأنيلين أو
+
+204
+00:17:13,220 --> 00:17:20,100
+الـفينول الطريقة غير مباشرة الطريقة غير مباشرة
+
+205
+00:17:20,100 --> 00:17:22,660
+لعملية التحضير
+
+206
+00:17:34,790 --> 00:17:41,210
+الآن في كمان طريقة ممكن من خلالها أن نحضر
+
+207
+00:17:42,430 --> 00:17:47,790
+الأمين يعني إن نعمل reduction للـ nitriles طبعا
+
+208
+00:17:47,790 --> 00:17:53,410
+انتبهوا معي إنه الـ nitrile اللي هي ال RCN من وين
+
+209
+00:17:53,410 --> 00:17:59,870
+أنا ممكن أجيبها بشكل عام من ال RCl يعني لو كان
+
+210
+00:17:59,870 --> 00:18:04,390
+عندي مثل أن أنا مثل nitrile بدي أحضرها المفروض
+
+211
+00:18:04,390 --> 00:18:09,690
+بحضرها من CH3Cl مع CN-
+
+212
+00:18:11,570 --> 00:18:17,450
+واضح؟ CH3Cl مع Cl- لو بدنا نقول أكثر الـ CH3Cl من 
+
+213
+00:18:17,450 --> 00:18:28,870
+وين بنحضرها؟ من ال alcohol CH3OH مثلا مع BCl3 و
+
+214
+00:18:28,870 --> 00:18:32,010
+هذا الكلام اللي كنا دائما بنحكيه أن ال alcohol
+
+215
+00:18:32,010 --> 00:18:36,030
+يمثل نقطة إيش؟ انطلاق في ال organic synthesis
+
+216
+00:18:37,380 --> 00:18:40,400
+فالخلاصة لو عندي alcohol ممكن أحوله لـ chloride
+
+217
+00:18:40,400 --> 00:18:45,860
+لـ chloride لـ nitrile بعمله hydrogenation reduction
+
+218
+00:18:45,860 --> 00:18:49,760
+سواء هذا ال reduction بليثيوم ألومنيوم هيدريد ممكن
+
+219
+00:18:49,760 --> 00:18:55,040
+أو بهيدروجينوميتال طبعا
+
+220
+00:18:55,040 --> 00:18:57,960
+المقصود بال reduction أنه على الكربون والنيتروجين
+
+221
+00:18:57,960 --> 00:19:07,970
+هذه بضيف H وH وكمان H وH هي صار CH3CH2NH2
+
+222
+00:19:07,970 --> 00:19:15,970
+لاحظوا هذه الطريقة فيها ميزة أنه أنا في المركب
+
+223
+00:19:15,970 --> 00:19:21,310
+الأول سواء كان alcohol أو كان chloride عدد ذرات
+
+224
+00:19:21,310 --> 00:19:26,350
+الكربون اللي عنده بتكون أقل بواحد من الأمين الناتج
+
+225
+00:19:26,350 --> 00:19:29,210
+يعني هنا لما يكون عندي مثل chloride كم كربون
+
+226
+00:19:29,210 --> 00:19:33,810
+عنده؟ واحد لو كنت بدأت أقول لكم حضروا لي ethyl amine
+
+227
+00:19:33,810 --> 00:19:38,850
+الآن هنا زادت كربونة يعني هي المثل هذه هي المثل هذه
+
+228
+00:19:38,850 --> 00:19:43,090
+طب من وين اجت الكربونة لزيادة من ال cyan .. ال
+
+229
+00:19:43,090 --> 00:19:49,090
+cyanide واضح فهذه الطريقة بتحتمل زيادة كربونة على
+
+230
+00:19:49,090 --> 00:19:52,030
+عدد الكربونات الأصلية أنا كان عندي كربونة واحدة
+
+231
+00:19:52,030 --> 00:19:58,000
+هناك بيصير عنده two carbon atoms واضحوالـ Carbon
+
+232
+00:19:58,000 --> 00:20:03,280
+الجديدة مصدرها من مجموعة الـ CNI زي ما حكينا إن
+
+233
+00:20:03,280 --> 00:20:06,560
+إضافة الهيدروجين أو الـ reduction يابليثيوم
+
+234
+00:20:06,560 --> 00:20:10,500
+ألومنيوم هيدريد أو بإضافة غاز الهيدروجين في وجود
+
+235
+00:20:10,500 --> 00:20:26,020
+متل بيعطينا الأمين الطريقة
+
+236
+00:20:26,790 --> 00:20:31,570
+الثالثة أو الرابعة لتحضير ال amines الطريقة
+
+237
+00:20:31,570 --> 00:20:37,110
+الرابعة لتحضير ال amines عمليا أو تطبيقيا هذه
+
+238
+00:20:37,110 --> 00:20:43,090
+الطريقة لها تفاصيل كثيرة لكن على أرض الواقع ممكن
+
+239
+00:20:43,090 --> 00:20:47,470
+تفهموها بسهولة إذا أنا أخذت ال alkyl halide
+
+240
+00:20:50,810 --> 00:20:58,170
+وفعلته مع الأمونيا أو أي أمين ثاني بس حطيت عند شرط
+
+241
+00:20:58,170 --> 00:21:05,670
+ضروري جدا أن هذه الأمونيا تكون excess واضح؟
+
+242
+00:21:05,670 --> 00:21:13,210
+يعني RX زائد أمونيا excess بيعطينا الأمين زائد
+
+243
+00:21:13,210 --> 00:21:19,450
+طبعا أمونيوم بروميد ليش فكرة ال excess هذه بنحطها
+
+244
+00:21:19,450 --> 00:21:25,470
+احنا؟ ليش بنحط ال .. ال ammonia تكون زيادة؟ على
+
+245
+00:21:25,470 --> 00:21:29,750
+أساس أنه اللي ممكن يصير عندي .. اللي ممكن يصير
+
+246
+00:21:29,750 --> 00:21:34,730
+عندي أنه لو ما حطيتش أنا ال ammonia هذه excess ممكن
+
+247
+00:21:34,730 --> 00:21:39,290
+بعد ما نحول إلى ال amine الأول هيصير عندي amine
+
+248
+00:21:39,290 --> 00:21:44,540
+تمام؟ يجي ال amine هذا الأول اللي هو يتفاعل مع
+
+249
+00:21:44,540 --> 00:21:48,500
+جزيئات ثانية من البروم يعمل secondary compound
+
+250
+00:21:48,500 --> 00:21:52,280
+وممكن هذا المركب بعد ما ينتج يتفاعل كمان مرة
+
+251
+00:21:52,280 --> 00:21:57,660
+يعطينا tertiary الخلاصة كل الغلبة والمعادلات أنا 
+
+252
+00:21:57,660 --> 00:22:01,820
+هذه ما بديش أغوص معكم فيها أنا اللي بدي إياه منكم
+
+253
+00:22:01,820 --> 00:22:06,840
+في هذه اللحظة أن alkyl halides مع ال ammonia
+
+254
+00:22:06,840 --> 00:22:12,470
+excess بيعطينا أمين بدون مشاكل يعني زي هيك المعادلة
+
+255
+00:22:12,470 --> 00:22:20,610
+بتكون إيش بدون مشاكل واضح؟ وهذه بيكون تكملتها زائد
+
+256
+00:22:20,610 --> 00:22:28,190
+طبعا HBr إذا ما حطيناش هذا excess بيصير مشاكل كثيرة
+
+257
+00:22:28,190 --> 00:22:31,930
+كل المعادلات اللي قدامكم أن التفاعل بتمر بتنين وثلاثة وبيصير فيه غلبة واضح؟ خلينا احنا على
+
+258
+00:22:31,930 --> 00:22:35,650
+المعادلة اللي بدون مشاكل أنه alkyl halide مع ال
+
+259
+00:22:35,650 --> 00:22:40,470
+ammonia excess بيعطينا ال amine زي ال HBr اللي هي
+
+260
+00:22:40,470 --> 00:22:44,230
+المعادلة البسيطة اللي ما فيش فيها مشاكل وين بتصير
+
+261
+00:22:44,230 --> 00:22:47,990
+المشاكل؟ إذا هذا كان مش excess بيصير عندكم صفحتين
+
+262
+00:22:47,990 --> 00:22:53,440
+معادلات بهذه المرحلة أنا أعتقد أنه أنا في غنى عنهم
+
+263
+00:22:53,440 --> 00:22:57,960
+واضح؟ وفي غنى عن الصفحة هذه الأخيرة اللي فيها text
+
+264
+00:22:57,960 --> 00:23:02,620
+بيشرح ليش بتصير المشاكل واضح؟ فكل اللي بيلزمنا
+
+265
+00:23:02,620 --> 00:23:09,100
+نكون عارفينه أنه تفاعل ال alkyl halide مع ال
+
+266
+00:23:09,100 --> 00:23:12,620
+ammonia excess مباشرة بيعطيني الأمين بدون مشاكل
+
+267
+00:23:12,620 --> 00:23:17,040
+اللي بدهوا مشاكل يستعمل مش excess
+
+268
+00:23:34,410 --> 00:23:38,790
+تقريبا هذا مثال تطبيقه على نفس الفكرة .. هذا مثال
+
+269
+00:23:38,790 --> 00:23:43,330
+تطبيقه على نفس الفكرة لو أخدت أنا الـ allyline مثلا مع
+
+270
+00:23:43,330 --> 00:23:46,770
+الـ methyl iodide بيصير عندي تفاعل إحلال، هاي
+
+271
+00:23:46,770 --> 00:23:51,570
+الـ allylene بيهاجم هنا و بيطرد اليود بيعطيني methyl
+
+272
+00:23:51,570 --> 00:23:56,010
+-allylene لو ال methyl-allylene بدفعله كمان مرة
+
+273
+00:23:56,010 --> 00:23:59,030
+أنا مع ال methyl-iodide، هاي زوج الإلكترونات،
+
+274
+00:23:59,030 --> 00:24:02,450
+بأفعله يهاجم ويطرد اليود، بيصير عندي
+
+275
+00:24:06,360 --> 00:24:15,800
+المثال الأخير في هذا المجال أن نيتروجين بتحل محل
+
+276
+00:24:16,880 --> 00:24:21,060
+البروم بس احنا كنا نجيب ال nitrogen بجزيء والبروم
+
+277
+00:24:21,060 --> 00:24:25,700
+بجزيء ثاني هل ممكن يكون ال nitrogen و البروم بنفس
+
+278
+00:24:25,700 --> 00:24:30,500
+الجزيء بمعنى التفاعل يكون intra-molecular؟ الجواب
+
+279
+00:24:30,500 --> 00:24:34,200
+أه في هذا المثال اللي عندي اللي في حلقة بيريدين
+
+280
+00:24:34,200 --> 00:24:41,310
+هنا NH2 مثل مع Br بيهاجم ال nitrogen و بيطرد ال br
+
+281
+00:24:41,310 --> 00:24:46,370
+هو SN2 substitution غالبا فتعطينا هذا المركب
+
+282
+00:24:46,370 --> 00:24:49,510
+اللي فيه حلقة خمسية فيها نيتروجين وحلقة سداسية
+
+283
+00:24:49,510 --> 00:24:56,570
+فيها نيتروجين وحلقة البيريدين وحلقة بيروليدين
+
+284
+00:24:56,570 --> 00:25:03,060
+المركب كله هو نيكوتين السيجارة واضح؟ المركب كله
+
+285
+00:25:03,060 --> 00:25:06,600
+وأنا كنت أنسى كده الفكرة ليش احنا جبنا هذا المثال
+
+286
+00:25:06,600 --> 00:25:13,300
+هنا حتى نفرجيكم إنه ال nitrogen بتحل محل لبروم
+
+287
+00:25:13,300 --> 00:25:17,840
+اللي هو موضوعنا تحضير ال amines من خلال أن ال
+
+288
+00:25:17,840 --> 00:25:20,860
+nitrogen بتحل محل لبروم
+
+289
+00:25:34,040 --> 00:25:39,800
+الآن ال Amines زي ما احنا اتفقنا وكل مركبات ال
+
+290
+00:25:39,800 --> 00:25:44,830
+nitrogen عادة بيكون عليهم زوج من الإلكترونات ولذلك
+
+291
+00:25:44,830 --> 00:25:49,550
+يعاملوا على إنهم bases وفي المركبات الـnatural
+
+292
+00:25:49,550 --> 00:25:53,530
+اللي فيها الـNitrogen هذه بالذات على حلقات بيسموها
+
+293
+00:25:53,530 --> 00:25:58,290
+الـAlkaloids ومن هذه الـAlkaloids بالمناسبة زي هذا
+
+294
+00:25:58,290 --> 00:26:01,490
+المركب النيكوتين بسبب وجود الـNitrogen هنا اللي
+
+295
+00:26:01,490 --> 00:26:04,710
+لها زوج إلكترونات والـNitrogen هنا اللي لها زوج
+
+296
+00:26:04,710 --> 00:26:11,260
+إلكترونات بيقولوا هذا مركب قاعدي بياخد الاسم
+
+297
+00:26:11,260 --> 00:26:14,320
+العائلة العام في المركبات أو المنتجات الطبيعية
+
+298
+00:26:14,320 --> 00:26:19,560
+بنسمي احنا إيش ال Alkaloid فالمهم في ال Amines
+
+299
+00:26:19,560 --> 00:26:26,000
+حقيقة هو زوج الإلكترونات هذا زوج الإلكترونات بيخلي
+
+300
+00:26:26,000 --> 00:26:31,140
+ال Amines بشكل عام مش دائما بالمطلق بشكل عام
+
+301
+00:26:31,140 --> 00:26:41,480
+يتفاعلوا as bases وقتاش ممكن يتفاعلوا مش كـ base إذا
+
+302
+00:26:41,480 --> 00:26:46,100
+بنجيب base أقوى منهم واضح؟ ليش؟ زي ما بتقول أهو
+
+303
+00:26:46,100 --> 00:26:51,260
+فوق كل ذي علم عليم يعني أي حامض ممكن أحوله ل base
+
+304
+00:26:51,260 --> 00:26:56,300
+بـ بإيش؟ بتجيب حامض أقوى منه و ال base ممكن
+
+305
+00:26:56,300 --> 00:26:59,680
+أخليها تبين كإنها acid بتجيب قاعدة أقوى منها
+
+306
+00:26:59,680 --> 00:27:04,800
+بتصير هي كإنها acid والقاعدة الأقوى .. أه لكن بشكل
+
+307
+00:27:04,800 --> 00:27:10,020
+عام ال amines و ال ammonia they are considered as
+
+308
+00:27:10,600 --> 00:27:17,400
+bases بشكل عام bases عشان لو مثلا احنا بناخد ال
+
+309
+00:27:17,400 --> 00:27:23,740
+ammonia على سبيل المثال مع H+ خلينا نفترضها
+
+310
+00:27:23,740 --> 00:27:30,900
+أنها كانت H3O+ يعني حامض مدوب في مية واضح فال
+
+311
+00:27:30,900 --> 00:27:32,660
+ammonia منها أنا هتاخد
+
+312
+00:27:39,080 --> 00:27:43,440
+الحامض اللي مدوب في مياه أسيد بيعطينا الأمونيوم أيون
+
+313
+00:27:43,440 --> 00:27:48,080
+الآن NH4+ زائد الميه أهم في الموضوع أن
+
+314
+00:27:48,080 --> 00:27:53,850
+الأمونيا هنا تعاملت كإنها إيش base ونفس الشيء لو أنا
+
+315
+00:27:53,850 --> 00:27:59,430
+بأخذ حتى بالحالة الغازية مش بالحالة السائلة ويمكن
+
+316
+00:27:59,430 --> 00:28:04,790
+كان عندكم أو مرات بيكون في تجربة أو في مساق
+
+317
+00:28:04,790 --> 00:28:12,130
+الكيمياء العامة تجربة بتوضح كده بيمشوا الجزيئات
+
+318
+00:28:12,130 --> 00:28:21,360
+بيجيبوا أُرْبُوبَة بهذا الشكل وبحط هنا نقطة من الأمونيا
+
+319
+00:28:21,830 --> 00:28:26,150
+solution وبيحطوه هنا نقطة من ال HCl بيحطوه بعيد
+
+320
+00:28:26,150 --> 00:28:30,710
+طبعا هنا هتتبخر أمونيا وهنا هتتبخر HCl هيبدا
+
+321
+00:28:30,710 --> 00:28:35,230
+يجربوا مع بعض لحظة ما بتتفاعل الأمونيا بشكلها
+
+322
+00:28:35,230 --> 00:28:40,450
+الغازي مع ال HCl بشكله الغازي بيعطينا ال NH4Cl
+
+323
+00:28:40,450 --> 00:28:44,990
+الأمونيوم كلوريد والأمونيوم كلوريد دائما
+
+324
+00:28:44,990 --> 00:28:50,630
+بتذكروا في المدارس إيش كنتوا تسموه كلوريد
+
+325
+00:28:50,630 --> 00:28:51,450
+الأمونيوم
+
+326
+00:28:55,250 --> 00:28:59,770
+اليوم مشي كثير الدنيا شتاء بيقولوا عنه صُحُب بيضاء
+
+327
+00:28:59,770 --> 00:29:03,910
+من كلوريد الأمونيوم يعني أول ما بتتحدوا مع بعض
+
+328
+00:29:03,910 --> 00:29:08,810
+بيعملوا لون أبيض زي السحابة البيضاء فإذا التقى غاز
+
+329
+00:29:08,810 --> 00:29:15,950
+الأمونيا مع غاز ال HCl مش مع المحلول بيعطينا white
+
+330
+00:29:15,950 --> 00:29:19,110
+clouds أو صحوب بيضاء من الأمونيوم كلوريد طبعا
+
+331
+00:29:19,110 --> 00:29:23,560
+هذه بتيجي في منطقة معينة هنا اللي هي ال ammonia و
+
+332
+00:29:23,560 --> 00:29:28,440
+ال chloride وقعدت أحسبه قد ايش بيمشي كل جزيء نسبة
+
+333
+00:29:28,440 --> 00:29:33,540
+لوزنه مين اللي بده يمشي أسرع الجزيء الخفيف بناء
+
+334
+00:29:33,540 --> 00:29:37,780
+على ذلك هنكون احنا بعاد عن الجزيء الخفيف و grab
+
+335
+00:29:37,780 --> 00:29:46,120
+للجزيء الثقيل واضحة ولا نوضحها أكثر بلاش نوضحها
+
+336
+00:29:46,120 --> 00:29:53,060
+أكثر هالجيتا لو حطينا لو حطينا ولد صغير مع ال M
+
+337
+00:29:53,060 --> 00:29:57,920
+مثلا وبينهم عشرين متر وتركناهم ال M كم خطوة
+
+338
+00:29:57,920 --> 00:30:02,140
+بتمشي؟ هذا إذا مشيت ثلاث خطوات والولد لما بيجي
+
+339
+00:30:02,140 --> 00:30:06,340
+يجري كم خطوة بيمشي؟ يمكن خمسة عشر خطوة هل بيمشوا
+
+340
+00:30:06,340 --> 00:30:10,460
+بنفس الشيء الخفيف مع الثقيل؟ نفس الشيء فلو
+
+341
+00:30:10,460 --> 00:30:13,920
+بتخيلوا أنه زي هيك هنا بدو يكون عندي مثلا ال HCl
+
+342
+00:30:13,920 --> 00:30:19,400
+هنا بدو يكون عندي ال ammonia ليش؟ لأن ال HCl بنحكي
+
+343
+00:30:19,400 --> 00:30:22,180
+احنا عن خمسة وثلاثين ونصف، ستة وثلاثين ونصف
+
+344
+00:30:22,180 --> 00:30:26,180
+الوزن، هنا بنحكي عن سبعة عشر، أربعة عشر ثلاثة، إذا
+
+345
+00:30:26,180 --> 00:30:29,860
+من الأدق واللي بيمشي أقل، إله علاقة عكسية مع
+
+346
+00:30:29,860 --> 00:30:33,820
+المسافة وبيعملوها تجربة وبيجيسوا كده المسافة
+
+347
+00:30:33,820 --> 00:30:37,680
+هنا والمسافة هنا وبيحققوا هذه العلاقة، واضح؟
+
+348
+00:30:41,600 --> 00:30:48,040
+الخلاصة أن تفاعل الـ Ammonia gas مع الـ HCl gas هو
+
+349
+00:30:48,040 --> 00:30:54,540
+حقيقة تفاعل acid-base أن زوج الإلكترونات بتاع الـ
+
+350
+00:30:54,540 --> 00:30:59,660
+Ammonia هو اللي بده يتفاعل مع الـ H+ بيكون
+
+351
+00:30:59,660 --> 00:31:03,840
+للايون الموجب الأمونيوم طبعا عندي كلور بده يكون
+
+352
+00:31:03,840 --> 00:31:04,500
+أمونيوم
+
+353
+00:31:09,870 --> 00:31:16,990
+الآن لو أتينا نتطلع على ال basicity of amines زي
+
+354
+00:31:16,990 --> 00:31:21,610
+ما اتفقنا احنا أن ال a means are bases ال a means
+
+355
+00:31:21,610 --> 00:31:26,670
+are bases وسبب
+
+356
+00:31:26,670 --> 00:31:34,750
+ال basicity زوج ال electronic لاحظوا هنا حاطط عدة
+
+357
+00:31:34,750 --> 00:31:39,770
+أشياء من خلالها ممكن احنا نعمل مقارنة وقت إيش
+
+358
+00:31:39,770 --> 00:31:45,350
+بتزيد ال basicity وقت إيش بتقل الجواب بسيط كل ما
+
+359
+00:31:45,350 --> 00:31:49,990
+زادت الكثافة الإلكترونية كل ما زادت الكثافة
+
+360
+00:31:49,990 --> 00:31:56,550
+الإلكترونية بيكون المركب basic أكثر ولا أقل وكل ما
+
+361
+00:31:56,550 --> 00:32:02,870
+سحبنا منه إلكترونات بيكون less basic بناء على ذلك لو
+
+362
+00:32:02,870 --> 00:32:07,990
+احنا بناجي بنطلع هو أنا للأسف مش كاتب لكم ال pKb
+
+363
+00:32:08,810 --> 00:32:14,490
+كاتب ال pKa للحمض المرافق يعني الأمونيا الحامض
+
+364
+00:32:14,490 --> 00:32:20,110
+المرافق تبعها ال NH4+ هو كاتب ال pKa
+
+365
+00:32:20,110 --> 00:32:24,610
+للأمونيوم أيون اللي أسهل إله في المقارنة كان ممكن
+
+366
+00:32:24,610 --> 00:32:30,010
+أكتب ال pKb لنفس الأمونيا الآن مش مشكلة كبيرة لما
+
+367
+00:32:30,010 --> 00:32:34,090
+بدي أحسبها بدي أقول 14 ناقص هذه يعني لو بدي أحكي
+
+368
+00:32:34,090 --> 00:32:36,590
+هنا بدي أحكي عن 4.7
+
+369
+00:32:39,290 --> 00:32:45,330
+على سبيل المثال ولو بدي أحكي هنا في حالة
+
+370
+00:32:45,330 --> 00:32:53,900
+الأنيلين بدي أحكي عنه 9.3 تقريبا وهكذا يعني مش صعب
+
+371
+00:32:53,900 --> 00:32:59,900
+أن نحسب مش صعب أن نحسب ال pKb مش صعب أن نحسب ال
+
+372
+00:32:59,900 --> 00:33:04,260
+pKb طبعا بتكونوا أنتم متذاكرين ش
+
+401
+00:35:34,210 --> 00:35:39,890
+بتشكل جوا الحلقة، واضح؟ ولذلك الـ aliphatic amines
+
+402
+00:35:39,890 --> 00:35:44,010
+بشكل عام they are more basic than aromatic amines
+
+403
+00:35:44,010 --> 00:35:47,910
+لأن الـ aromatic amines بتعمل resonance فبدل ما زوج
+
+404
+00:35:47,910 --> 00:35:50,870
+الإلكترونات يكون على نيتروجين في أحد الـ resonance
+
+405
+00:35:50,870 --> 00:35:54,750
+structure شو صارت الـ nitrogen؟ positive، بطل عليها
+
+406
+00:35:54,750 --> 00:36:00,650
+زوج الإلكترونات، واضح؟ فلو بدنا نيجي نسأل كقاعدة
+
+407
+00:36:00,650 --> 00:36:06,910
+عامة وهي أكثر أساسية ألفاتيك أمين أو أروماتيك أمين
+
+408
+00:36:06,910 --> 00:36:13,410
+الجواب ألفاتيك أمين بسبب ريزونانس الأروماتيك أمين
+
+409
+00:36:13,410 --> 00:36:18,430
+هم أعلى والسبب أن الأروماتيك أمين بيعملوا ريزونانس
+
+410
+00:36:18,430 --> 00:36:23,890
+الألفاتيك أمين بيعملوش ريزونانس هذه النقطة الأولى
+
+411
+00:36:23,890 --> 00:36:31,530
+الآن لو رجعنا شوية صغيرة للجدول وعملنا كمان مقارنة
+
+412
+00:36:32,150 --> 00:36:38,970
+يا ترى مين بيكون more basic؟ الأمين اللي عليه
+
+413
+00:36:38,970 --> 00:36:44,890
+مثلاً R1 أو R2 أو R3 لحظة، أنا عندي مثل أمين، المثل
+
+414
+00:36:44,890 --> 00:36:51,030
+بتعطي إلكترونات، هنا دايمثل أمين، مجموعة المثل،
+
+415
+00:36:51,030 --> 00:37:00,110
+هنا تراي مثل أمين، واضح؟ قاعدية أعلى واحدة فيهم الـ
+
+416
+00:37:00,110 --> 00:37:05,790
+trimethylamine is more basic than الـ
+
+417
+00:37:05,790 --> 00:37:11,170
+dimethylamine بمعنى أنه أنا كل ما بيكون عندي... كل 
+
+418
+00:37:11,170 --> 00:37:15,700
+ما بيكون عندي electron donating groups المفروض الـ
+
+419
+00:37:15,700 --> 00:37:21,120
+basicity ايش يصير لها؟ تزيد هذا الكلام نفسه ممكن
+
+420
+00:37:21,120 --> 00:37:28,300
+تلاحظوه لو بدكوا تعمله مقارنة مثلاً المثال اللي تحت
+
+421
+00:37:28,300 --> 00:37:34,140
+aromatic احنا قولنا الـ aromatic بشكل عام ليس basic
+
+422
+00:37:34,140 --> 00:37:40,640
+لكن خليني أقارن aromatic مع aromatic مع aromatic
+
+423
+00:37:41,600 --> 00:37:47,820
+واضح؟ كله ضعيف، لكن مين فيهم؟ الأضعف، الآن لو حطيت
+
+424
+00:37:47,820 --> 00:37:52,440
+هنا مجموعة مثل، مجموعة المثل، بتعطي إلكترونات،
+
+425
+00:37:52,440 --> 00:37:56,800
+خليني أعتبر الـ H حلق وسط، وهنا مجموعة نيترو بتسحب
+
+426
+00:37:56,800 --> 00:38:03,100
+الإلكترونات، أنه بنتوقع يكون more basic اللي فيه
+
+427
+00:38:03,100 --> 00:38:06,860
+زيادة الإلكترونات لأن الـ basicity هي قصة
+
+428
+00:38:06,860 --> 00:38:09,980
+الإلكترونات، ايش اللي بيزيدها؟ واضح؟ اللي فيه
+
+429
+00:38:09,980 --> 00:38:13,740
+زيادة الإلكترونات، واضح؟ نفس الأشياء لو كنتوا
+
+430
+00:38:13,740 --> 00:38:16,980
+تاخدوها مثلاً، لو أخدتوا الـ etheramine، هاي زوج
+
+431
+00:38:16,980 --> 00:38:22,800
+إلكترونات، شايفينه؟ طيب، لو عملت chloroethelamine
+
+432
+00:38:24,060 --> 00:38:27,660
+هذا نفس زوج الإلكترونات لكن الكلور ماذا يعمل؟
+
+433
+00:38:27,660 --> 00:38:32,740
+بيسحب شوية من الإلكترونات إذا وين الإلكترونات أكتر
+
+434
+00:38:32,740 --> 00:38:37,600
+هتكون؟ في الـ إيثالأمين ولا في الكلورو؟ إيثالأمين
+
+435
+00:38:37,600 --> 00:38:41,300
+في الإيثالأمين إذا هذا الإيثالأمين is more basic
+
+436
+00:38:41,300 --> 00:38:46,060
+فكأنه أنا قاعد بقول كلمة إن الـ electron donating
+
+437
+00:38:46,060 --> 00:38:52,230
+groups المجموعات المعطية increase basicity و الـ
+
+438
+00:38:52,230 --> 00:38:56,850
+electron withdrawing groups decrease basicity و
+
+439
+00:38:56,850 --> 00:39:01,430
+هذا كلام بسيط إن أنا عندي زوج electronic إذا حطيت
+
+440
+00:39:01,430 --> 00:39:04,990
+electron donating بزيد الكثافة الإلكترونية بصير
+
+441
+00:39:04,990 --> 00:39:10,070
+more basic إذا حطيت electron withdrawing groups
+
+442
+00:39:10,070 --> 00:39:15,940
+بقلل الكثافة الإلكترونية بصير less basic فوصفياً
+
+443
+00:39:15,940 --> 00:39:20,000
+العملية سهلة طبعاً مش مطلوب مني أن أنا أقعد أحفظ
+
+444
+00:39:20,000 --> 00:39:24,980
+الجداول والأرقام لكن مطلوب مني في الـ basicity أن
+
+445
+00:39:24,980 --> 00:39:30,160
+أكون عارف أشياء كمبادئ عامة أن الـ aliphatic amines
+
+446
+00:39:30,160 --> 00:39:35,480
+they are more basic than aromatic amines الآن سواء
+
+447
+00:39:35,480 --> 00:39:38,620
+على aliphatic amines أو على aromatic amines إذا
+
+448
+00:39:38,620 --> 00:39:43,800
+حطيت مجموعات معطية بتزيد القاعدية، وإذا حطيت
+
+449
+00:39:43,800 --> 00:39:48,360
+مجموعات ساحبة، بتقل القاعدية، واضح؟ هاي التلات
+
+450
+00:39:48,360 --> 00:39:51,860
+حاجات اللي بدي أقولها ألفاتك أمينs are more basic
+
+451
+00:39:51,860 --> 00:39:55,140
+than aromatic amines، electron donating groups
+
+452
+00:39:55,140 --> 00:40:00,720
+increase basicity، and electron withdrawing groups
+
+453
+00:40:00,720 --> 00:40:03,760
+decrease basicity، واضح؟
+
+454
+00:40:08,850 --> 00:40:12,430
+لأ ما هذا الـ slide برضه على الـ basicity و الـ
+
+455
+00:40:12,430 --> 00:40:21,850
+acidity هذا
+
+456
+00:40:21,850 --> 00:40:28,430
+الـ slide بتجيبلنا... بتجيبلنا مثال عادة بيعملوا
+
+457
+00:40:28,430 --> 00:40:32,050
+تجربة في المختبر بعرفش ايه ممكن تعملوه برضه إنتوا 
+
+458
+00:40:32,050 --> 00:40:38,260
+إذا أخدتوا المختبر أو لأ إنهم بياخدوا الـ para مثل
+
+459
+00:40:38,260 --> 00:40:43,980
+أنيلين اللي هو الـ para توليدين هذا والـ para نيترو
+
+460
+00:40:43,980 --> 00:40:51,360
+تولوين لاحظوا أنا عند مثل ومثل مجموعة أمينو
+
+461
+00:40:51,360 --> 00:40:58,700
+ومجموعة نيترو ممكن أن البعض يفكر أن النيترو جروب
+
+462
+00:40:58,700 --> 00:41:04,660
+basic من أي منطلق؟ من منطلق أن تشوفه النيتروجين لكن
+
+463
+00:41:04,660 --> 00:41:10,500
+انتبهوا معي أن النيتروجين هذه تبعت مجموعة النيترو
+
+464
+00:41:10,500 --> 00:41:16,360
+ماعليهاش أزواج إلكترونات هي نيتروجين موجبة بمعنى
+
+465
+00:41:16,360 --> 00:41:19,420
+هذه النيتروجين تعطي الـ aniline على العين والرأس
+
+466
+00:41:19,420 --> 00:41:23,180
+عليها زوج من الإلكترونات بس هذه لما بدنا نرسمها
+
+467
+00:41:23,180 --> 00:41:26,160
+حقيقة بترسم بهذا الشكل
+
+468
+00:41:32,930 --> 00:41:37,630
+وهنا O بتكون minus وهنا plus فالنيتروجينها دي
+
+469
+00:41:37,630 --> 00:41:41,670
+ماعليهاش إلكترونات النيترو كمجموعة بنرسمها بالشكل
+
+470
+00:41:41,670 --> 00:41:44,990
+اللي موجود عندكم بناء على ذلك لو بدأ أقول هذا
+
+471
+00:41:44,990 --> 00:41:48,750
+المركب اللي فيه الـ amino ولا فيه الـ nitro which is
+
+472
+00:41:48,750 --> 00:41:55,250
+more basic أكيد هذا اللي هو الـ para طول يديك طيب لو
+
+473
+00:41:55,250 --> 00:41:59,170
+كان عندي خليط من المركبين مخلوطين مع بعض وبدي
+
+474
+00:41:59,170 --> 00:42:04,970
+طريقة كيميائية في المعمل أني أفصلهم عن بعض واضح
+
+475
+00:42:04,970 --> 00:42:09,810
+ايش التجربة؟ أنه أنا عندي اللي هو الـ nitro مع الـ
+
+476
+00:42:09,810 --> 00:42:14,290
+amino وبدي أفصلهم طبعاً ممكن ناس ممكن ناس منكم
+
+477
+00:42:14,290 --> 00:42:20,250
+يقولوا ما هو احنا ليش في الأساس نخلطهم؟ عشان في
+
+478
+00:42:20,250 --> 00:42:25,890
+الآخر نتغلب بفصلهم يعني لو من الأصل ما خلطناهم مش
+
+479
+00:42:25,890 --> 00:42:31,050
+بلزمناش تجربة أننا نفصلهم اه بس اتذكروا نقطة
+
+480
+00:42:31,050 --> 00:42:35,930
+اتذكروا نقطة أن أنا هذا المركب اللي فيه الـ amino
+
+481
+00:42:35,930 --> 00:42:40,920
+حضرته من هذا مظبوط ولا لأ؟ قبل شوية احنا كنا
+
+482
+00:42:40,920 --> 00:42:44,880
+نقول لكم أن مركب الـ Nitro هذا بالـ hydrogenation
+
+483
+00:42:44,880 --> 00:42:48,620
+مع الـ metal بيعطينا الـ Amino الآن فالاتنين
+
+484
+00:42:48,620 --> 00:42:53,040
+موجودين مع بعض ممكن التفاعل لا يصل إلى النهاية
+
+485
+00:42:53,040 --> 00:42:58,300
+وبالتالي صار عنده متكون الـ Amino compound وصار
+
+486
+00:42:58,300 --> 00:43:03,720
+عنده الـ Nitro والاتنين صاروا مخلوطين مع بعض كيف
+
+487
+00:43:03,720 --> 00:43:09,720
+ممكن أفصل المركبين؟ بيقول لك لو اجينا... ضفنا له
+
+488
+00:43:09,720 --> 00:43:17,420
+محمض HCl الـ HCl هيتفاعل مع مين؟ بس مع الـ basic مع
+
+489
+00:43:17,420 --> 00:43:21,580
+هذا مش هيتفاعل مع هذا بناء على ذلك هذا المركب اللي
+
+490
+00:43:21,580 --> 00:43:25,990
+هو الـ Nitro Toluene هيظل زي ما هو مش هيتفاعل مع الـ
+
+491
+00:43:25,990 --> 00:43:31,550
+HCl بينما الـ para توليدين هيتفاعل مع الـ HCl هتصير
+
+492
+00:43:31,550 --> 00:43:40,350
+هذه N-H3+، النيتروجين هتاخد H+، N-H3+، و Cl-، اللي
+
+493
+00:43:40,350 --> 00:43:45,770
+هو الـ chloride لاحظوا معنى أن هذا المركب صار plus
+
+494
+00:43:45,770 --> 00:43:51,730
+minus ايش يعني plus minus؟ Salt ملح مش الأملح plus
+
+495
+00:43:51,730 --> 00:43:54,250
+minus و الـ salt بيكون بيدوب
+
+496
+00:44:04,640 --> 00:44:10,740
+بناء على ذلك بنقدر نعمل عملية extraction نضيف
+
+497
+00:44:10,740 --> 00:44:15,820
+organic solvent ومية هذا المركب وين بده يروح؟
+
+498
+00:44:15,820 --> 00:44:18,900
+على المية هذا بده يروح على الـ organic solvent لو
+
+499
+00:44:18,900 --> 00:44:23,020
+افترضنا الـ organic solvent إيثر بعدين إذا بخرنا الـ
+
+500
+00:44:23,020 --> 00:44:27,470
+ether بيظل هذا المركب نقي طب هذا اللي ضال دايب في
+
+501
+00:44:27,470 --> 00:44:32,590
+المية... بيضيف
+
+502
+00:44:32,590 --> 00:44:37,350
+نقاط NaOH لاحظوا الـ NaOH strong base بتروح بتسحب
+
+503
+00:44:37,350 --> 00:44:42,330
+الـ HCl اللي اتفاعل هنا بتتفاعل معه بتعطينا NaCl
+
+504
+00:44:42,330 --> 00:44:47,150
+زائد H2O وبرجع هذا لـ organic بزامه رجع لـ organic في
+
+505
+00:44:47,150 --> 00:44:52,770
+المية شو بيعمل؟ بترسبه بيدوب في المية لما يكون
+
+506
+00:44:52,770 --> 00:45:01,210
+Salt فإذا أنا نقطت نقاط NaOH على المية هتسحب منه الـ
+
+507
+00:45:01,210 --> 00:45:05,330
+HCl هيرجع Organic وإذا ما رجع Organic بترسب كمادة
+
+508
+00:45:05,330 --> 00:45:11,530
+صلبة وبنعمل له filtration واضح فالفكرة في فصل هدول
+
+509
+00:45:11,530 --> 00:45:15,990
+المركبين اللي هي الفكرة الأساسية أن هذا بيتفعل as a
+
+510
+00:45:15,990 --> 00:45:18,950
+base هذا ما بيتفعلش هذا ما بيتفعل as a base بيعمل
+
+511
+00:45:18,950 --> 00:45:23,370
+عندك Salt هذا بيطلق organic، organic بنفصله
+
+512
+00:45:23,370 --> 00:45:27,270
+وبنبخره، طب هذا الـ salt كيف بدنا نسترده؟ بنضيف
+
+513
+00:45:27,270 --> 00:45:32,050
+عليه Sodium Hydroxide بيرودي يتحول إلى الـ aniline
+
+514
+00:45:32,050 --> 00:45:37,110
+و بنعمل له filtration و بنفصله على أي حال إذا هذه
+
+515
+00:45:37,110 --> 00:45:44,430
+مرت عليكوا تجربة في الجزء العملي بإمكانكم تشوفوا
+
+516
+00:45:44,430 --> 00:45:50,390
+بالمناسبة الـ organic العملي نازل بالصيف نازل بالصيف
+
+517
+00:45:50,390 --> 00:45:53,630
+يعني الناس اللي عندهم فضاوة أنا شخصياً بنصحهم
+
+518
+00:45:53,630 --> 00:45:58,170
+ياخدوها بالصيف لإنه بالفصل الأول أعداد كبيرة و
+
+519
+00:45:58,170 --> 00:46:02,230
+برضه أنتو عندكم شغلكم بالفصل الأول فالـ organic
+
+520
+00:46:02,230 --> 00:46:11,030
+العملي نازل بالصيف وممكنكم تاخدوها على أي حال ابنه
+
+521
+00:46:11,030 --> 00:46:13,110
+وجفهان العملي 
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..6d49a3fe9be120efc0ab4569b642f77acb98256f
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_postprocess.srt
@@ -0,0 +1,2084 @@
+1
+00:00:15,180 --> 00:00:19,600
+بسم الله الرحمن الرحيم بنكمل اليوم ان شاء الله في
+
+2
+00:00:19,600 --> 00:00:25,620
+موضوع ال amends المحاضرة الماضية أخدنا تسمية ال
+
+3
+00:00:25,620 --> 00:00:30,580
+amends و أخدنا بشكل عام طريقتيناللي هم ال iobac
+
+4
+00:00:30,580 --> 00:00:36,840
+method وال common method لو مثلا بدنا نأكد على
+
+5
+00:00:36,840 --> 00:00:41,400
+هالكلام ونضيف أنه في طريقة ثالثة أحيانا موجودة
+
+6
+00:00:41,400 --> 00:00:46,140
+أيضا في الاستعمال حتى إذا يعني قرأت اسمباستعمالها
+
+7
+00:00:46,140 --> 00:00:50,660
+ما يكونش غريب عليكم لو أخدنا مثلا أربع ذرات كربون
+
+8
+00:00:50,660 --> 00:00:54,740
+عليهم amino group و بدنا نسمي بال Iopac
+
+9
+00:00:54,740 --> 00:00:58,200
+Nomenclature بنقول one amino بيوتين احنا اتفقنا ان
+
+10
+00:00:58,200 --> 00:01:03,660
+ال amino تعمل كمجموعة ك substitute لو بدنا نسمي
+
+11
+00:01:03,660 --> 00:01:07,420
+بال common نامي بناخد هذه المجموعة بيوتل و بنقول
+
+12
+00:01:07,420 --> 00:01:13,320
+بيوتلأمين هذا ال iopic name هذا ال common name في
+
+13
+00:01:13,320 --> 00:01:19,340
+طريقة تالتة للتسمية بيسموها chemical abstract name
+
+14
+00:01:19,340 --> 00:01:26,340
+ال CA هذه اختصار لإيش؟ ل chemical abstract
+
+15
+00:01:30,350 --> 00:01:35,090
+ال chemical abstracts هي الفهارس اللي بتلخص الجديد
+
+16
+00:01:35,090 --> 00:01:38,110
+في علم الكيميا و بتصدرها الجامعية الكيميائية
+
+17
+00:01:38,110 --> 00:01:42,290
+الأمريكية واضح فهدول لما بيعملوا ملخصات و ما إلى
+
+18
+00:01:42,290 --> 00:01:47,250
+ذلك بيسموا ال a means بطريقة غير ال I opinion و
+
+19
+00:01:47,250 --> 00:01:50,880
+غير ال common nameبيسموها ال chemical abstract
+
+20
+00:01:50,880 --> 00:01:56,740
+name بهاد الطريقة بيحاولوا يخلوا مجموعة الأمين زي
+
+21
+00:01:56,740 --> 00:02:00,660
+تماما ما كانت مجموعة ال alcohol يعني لما كانت
+
+22
+00:02:00,660 --> 00:02:03,660
+مجموعة ال alcohol كانت تعتبر functional group
+
+23
+00:02:03,660 --> 00:02:08,780
+وبتعطي النهايةall فلو كان انا عندى اربع معقوقات شو
+
+24
+00:02:08,780 --> 00:02:14,480
+كنت اسم المركب بيوتان all هم بيقولوا كمان ال amine
+
+25
+00:02:14,480 --> 00:02:19,860
+مش اقل يعنى قيمة من ال alcohol فسموا المركب بيوتان
+
+26
+00:02:19,860 --> 00:02:25,980
+amineواضح؟ فكأنه بيعملوا الامين كإنها functional
+
+27
+00:02:25,980 --> 00:02:30,500
+group اسمها امين لاحظوا بتخنف عن ال common name ال
+
+28
+00:02:30,500 --> 00:02:35,740
+common name احنا بنحط اسم المجموعة انا بيوت الامين
+
+29
+00:02:35,740 --> 00:02:42,640
+هنا بيحط اسم الألكان بيوتانأمين تماما زى ما كنا
+
+30
+00:02:42,640 --> 00:02:49,180
+نقول للألكول بيوتان all ولا ال الديهايد بيوتان ال
+
+31
+00:02:49,180 --> 00:02:54,600
+ولا الأمين بيقول يكون بيوتان أمين فكأنه الألكول
+
+32
+00:02:54,600 --> 00:02:58,620
+بهذه الحالة .. الأمين عفوا بهذه الحالة بيمثل
+
+33
+00:02:58,620 --> 00:03:03,050
+functional group بنسميها إيش أمينمابدناش ناخد كل
+
+34
+00:03:03,050 --> 00:03:07,350
+الأمثلة ممكن ناخد مثال او اتنين تأكيديين مثلا هنا
+
+35
+00:03:07,350 --> 00:03:11,650
+لو بدي هذا المركب واحد اتنين تلاتة اذا هذا إبروبان
+
+36
+00:03:11,650 --> 00:03:17,450
+في أي بكنومينكليتشر على موقع اتنين عند امينو وعند
+
+37
+00:03:17,450 --> 00:03:24,410
+مثل فبصير two amino two مثل إبروبان لو بدي ال
+
+38
+00:03:24,410 --> 00:03:27,430
+common name باخد هذه كلها كمجموعة اربع ذرات
+
+39
+00:03:27,430 --> 00:03:32,600
+الكربون اللي فيهم تشبهفي جعبات الـ tertiary بيوت
+
+40
+00:03:32,600 --> 00:03:37,120
+الأمين الان لو كنت بدى أسميه على ال chemical
+
+41
+00:03:37,120 --> 00:03:42,840
+abstract nomenclature هذا بدى يكون to بروبان أمين
+
+42
+00:03:42,840 --> 00:03:47,660
+و بنحط عليه وجود مجموعة الاش المثل يعنى اي واحد
+
+43
+00:03:47,660 --> 00:03:54,340
+اتنين تلاتة لو كان OH قولنا to بروبان all هنا أمين
+
+44
+00:03:54,340 --> 00:04:02,180
+to بروبان أمين to مثل to بروبانأمين و هكذا
+
+45
+00:04:02,180 --> 00:04:08,400
+بإمكانكوا تشوفوا التسميات الأشكال اللي تحت هذه هي
+
+46
+00:04:08,400 --> 00:04:12,500
+بعض المركبات اللي موجودة في التطبيق و ما عدا
+
+47
+00:04:12,500 --> 00:04:17,900
+المركب الأول كله بنسميها احنا مركبات حلقية غير
+
+48
+00:04:17,900 --> 00:04:22,300
+متجانسة ايش يعني غير متجانسة يعني الحلقة مش كلها
+
+49
+00:04:22,300 --> 00:04:26,760
+كربون الحلقة فيها كربون و ذرات غير الكربون من هنا
+
+50
+00:04:26,760 --> 00:04:33,820
+جاء عدمالتجانس واضح وهذه لها الحقيقة استعمالات
+
+51
+00:04:33,820 --> 00:04:37,380
+كثيرة في التطبيق لكن احنا في الكيميا بندرسها بمساق
+
+52
+00:04:37,380 --> 00:04:42,400
+كامل بسنة رابعة بنسميه heterocyclic chemistry فإذا
+
+53
+00:04:42,400 --> 00:04:46,480
+سمعتوا مركبات من هالصلف اندول بيريديل بيريديل
+
+54
+00:04:46,480 --> 00:04:50,840
+بيريميديل بايروليديل بايرول اميدازول واطفة كل هذه
+
+55
+00:04:50,840 --> 00:04:56,840
+برضه مركبات تحتوي علىاللي هي ال nitrogen موجودة
+
+56
+00:04:56,840 --> 00:05:01,580
+لكن مش هنا مجال دراستها البنزين اللي عليه أن أجتوت
+
+57
+00:05:01,580 --> 00:05:10,540
+علمناها ده أنالين ومشتقاته الآن لو إجينا ل ال
+
+58
+00:05:10,540 --> 00:05:15,780
+physical properties of a means طبعا إذا بنركز على
+
+59
+00:05:16,740 --> 00:05:20,720
+الـ boiling point إذا بنركز على ال boiling point
+
+60
+00:05:20,720 --> 00:05:28,100
+بنلاحظ إنه ال amines بشكل عام ممكن تعمل مع نفسها
+
+61
+00:05:28,100 --> 00:05:33,820
+نوع من ال hydrogen bondingيعني أتش من أمين بتعمل
+
+62
+00:05:33,820 --> 00:05:40,100
+hydrogen bonding مع أمين تاني ولذلك إذا يعني بنطلع
+
+63
+00:05:40,100 --> 00:05:45,520
+أحيانا بنلاحظ أنه نسبيا ممكن تكون عالية بعض ال
+
+64
+00:05:45,520 --> 00:05:49,100
+amines ال boiling point لكن مش كثير مش زي ال
+
+65
+00:05:49,100 --> 00:05:53,940
+alcohol يعني مش بقوة ال hydrogen bonding تبعت ال
+
+66
+00:05:53,940 --> 00:05:59,570
+alcoholلو .. يعني بتكون تنظروا مثلا إلى تلت
+
+67
+00:05:59,570 --> 00:06:03,950
+مراكبات تقريبا التلت مراكبات ماخدين نفس ال
+
+68
+00:06:03,950 --> 00:06:06,970
+molecular weight يعني ال molecular weight تلتين و
+
+69
+00:06:06,970 --> 00:06:10,910
+واحد و تلتين اتنين و تلتين لاحظوا ال Ethan ب
+
+70
+00:06:10,910 --> 00:06:14,790
+molecular weight تلتين ال boiling point تبعته ناقص
+
+71
+00:06:14,790 --> 00:06:22,020
+تمانية و تمانينواضح؟ الان ال مثلول ال molecular
+
+72
+00:06:22,020 --> 00:06:27,200
+weight 32 قريب منه ال boiling point plus 65 الان
+
+73
+00:06:27,200 --> 00:06:30,080
+ايش اللي رفعوا؟ يعني نفترض ان التلاتة دول ال
+
+74
+00:06:30,080 --> 00:06:33,800
+molecular weight متساوي، شو اللي رفعوا؟ 88 درجة و
+
+75
+00:06:33,800 --> 00:06:40,060
+65 يعني بحكي انا عن حوالي 140، 150 درجة ارتفاع
+
+76
+00:06:40,780 --> 00:06:44,960
+الهيدروجين البوندغ اللى بتعملها الالكوهول واضح؟
+
+77
+00:06:44,960 --> 00:06:49,160
+الان لو اجينا واطلعنا على الميثل أمين باللاحظ
+
+78
+00:06:49,160 --> 00:06:55,020
+الميثل أمين minus 6.3 برضه نسبيا مرتفع فوق ال 80
+
+79
+00:06:55,020 --> 00:07:00,260
+درجة عن الاثانإيش السبب؟ برضه الـ hydrogen
+
+80
+00:07:00,260 --> 00:07:03,000
+bonding، لكن إحنا اللي بنقوله إنه الـ hydrogen
+
+81
+00:07:03,000 --> 00:07:08,020
+bonding في الألكوهولز أعلى منه في الأمينز، بس
+
+82
+00:07:08,020 --> 00:07:12,060
+بالتأكيد في بالأمينز hydrogen bonding عمال رفعتها
+
+83
+00:07:12,060 --> 00:07:16,240
+عن مُركّب موازي مع دوم الـ hydrogen bonding هنا في
+
+84
+00:07:16,240 --> 00:07:21,360
+الـ إيثين 80 درجة، واضح؟ فدول الـ 80 درجة من وين
+
+85
+00:07:21,360 --> 00:07:28,900
+إجوا؟هيدروجين بوندنج هيدروجين
+
+86
+00:07:28,900 --> 00:07:29,500
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+87
+00:07:29,500 --> 00:07:31,920
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+88
+00:07:31,920 --> 00:07:34,160
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+89
+00:07:34,160 --> 00:07:38,140
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+90
+00:07:38,140 --> 00:07:42,820
+بوندنج هيدروجين بوندنج هيدروجين بوندنج هيدروجين
+
+91
+00:07:42,820 --> 00:07:50,160
+بوندنج هيدروجين بوندنج هيدروجين
+
+92
+00:07:50,160 --> 00:07:54,400
+بوندنجيعني مثلا لو بدنا ناخد مقارنة .. لو بدنا
+
+93
+00:07:54,400 --> 00:07:57,680
+ناخد مقارنة بين هذا المركب اللي هو الـ
+
+94
+00:07:57,680 --> 00:08:01,620
+dimethylamine و هذا المركب اللي هو ال
+
+95
+00:08:01,620 --> 00:08:05,340
+trimethylamine رغم أن هذا عمال بيزيد في ال
+
+96
+00:08:05,340 --> 00:08:09,480
+molecular weight لكن الdimethylamine ما زال فيه
+
+97
+00:08:09,480 --> 00:08:13,380
+hydrogen، ال trimethylamine مافيش فيه hydrogen،
+
+98
+00:08:13,380 --> 00:08:17,170
+رغم أن هذا أصغرفي الوزن في ال molecular weight
+
+99
+00:08:17,170 --> 00:08:21,570
+أصغر بجمعة مثل لكن لاحظوا ال boiling point تبعته
+
+100
+00:08:21,570 --> 00:08:25,550
+سبع درجات تقريبا بينما ال boiling point هنا تلت
+
+101
+00:08:25,550 --> 00:08:30,990
+درجات ليش ال trimethylamine كان أقل من ال
+
+102
+00:08:30,990 --> 00:08:34,650
+diamethylamine
+
+103
+00:08:34,650 --> 00:08:40,350
+لأن ال trimethylamine مافيش فيه hydrogen bonding
+
+104
+00:08:40,350 --> 00:08:47,110
+واضح لأنه مافيش فيه hydrogen bondingطبعاً الميثل
+
+105
+00:08:47,110 --> 00:08:51,050
+أمين بيعمل hydrogen bonding لكن في شكل عام هو
+
+106
+00:08:51,050 --> 00:08:57,030
+بيكون غاز يلاحظوا minus 6.3 و الغازات بتقدروا
+
+107
+00:08:57,030 --> 00:09:01,550
+تتذكروا العلاقة الأساسية بينها أنه تعامل كأنها
+
+108
+00:09:01,550 --> 00:09:06,770
+جزيئات منفصلة لأنه خفيف كتير و بحكومها ال kinetic
+
+109
+00:09:06,770 --> 00:09:11,890
+theory جزيئات بتتحرك و بتتصادم في جدار الإناء لكن
+
+110
+00:09:11,890 --> 00:09:16,240
+المقارنة هنا واضحة بين الداي ميثل أمينوالـ Tri
+
+111
+00:09:16,240 --> 00:09:21,480
+-methylamine أعلى في الـ boiling point بسبب انه
+
+112
+00:09:21,480 --> 00:09:24,500
+عنده إمكانية hydrogen bonding وهذه الإمكانية غير
+
+113
+00:09:24,500 --> 00:09:31,640
+موجودة في الـ Tri-methylamineالان كيف تحضر ال
+
+114
+00:09:31,640 --> 00:09:37,040
+amines هتلاحظوا انه في مجموعة من الطرق احنا مرت
+
+115
+00:09:37,040 --> 00:09:41,760
+علينا مثلا الطريقة الأولى انه احنا بنحطر ال amine
+
+116
+00:09:41,760 --> 00:09:45,760
+من خلال reduction of amides بليثيوم ألومينوم
+
+117
+00:09:45,760 --> 00:09:50,280
+هيدرايد هذه
+
+118
+00:09:50,280 --> 00:09:54,480
+الطريقة مرت علينا لما درسنا ال amides قلنا بنحول
+
+119
+00:09:54,480 --> 00:10:03,390
+السيطة بال bond O إلىCH2 يعني بيتم إضافة H- على
+
+120
+00:10:03,390 --> 00:10:09,430
+مرتين وهذه دوري ست في ال chemistry of amides أنه
+
+121
+00:10:09,430 --> 00:10:17,000
+amides are reduced to aminesالطريقة التانية لو
+
+122
+00:10:17,000 --> 00:10:20,720
+بدنا نتطلع على الـ Nitro Compounds لو بدنا نتطلع
+
+123
+00:10:20,720 --> 00:10:23,640
+على الـ Nitro Compounds و خلّيني أذكركوا أن الـ
+
+124
+00:10:23,640 --> 00:10:27,740
+Nitro Compounds كنا بنجيبهم احنا من البنزين يعني
+
+125
+00:10:27,740 --> 00:10:30,820
+لو بدنا نيترو بنزين الـ Nitro aromatic Compounds
+
+126
+00:10:30,820 --> 00:10:39,420
+كنت استعمل البنزين استعمل Nitric Acid و H2SO4
+
+127
+00:10:39,420 --> 00:10:45,850
+فبناء على ذلك البنزينممكن نعمله نيتراشن الان ال
+
+128
+00:10:45,850 --> 00:10:49,450
+Nitro برضه بنعمل لها reduction و عادة ال reduction
+
+129
+00:10:49,450 --> 00:10:55,530
+هنا ب hydrogenزائد مثل مثل زي nickel او platinum
+
+130
+00:10:55,530 --> 00:11:02,430
+هذا ال reduction بيحول ال NO2 الى NH2 لاحظوا معنى
+
+131
+00:11:02,430 --> 00:11:07,050
+شغلة مهمة جدا و خطأ كتير بيجعوا فيه الطلاب انه لما
+
+132
+00:11:07,050 --> 00:11:12,290
+نيجي نقولهم كيف يحضر ال aniline كتير كتير بيعملوا
+
+133
+00:11:12,290 --> 00:11:16,030
+غلطة هم بيوصوا ان الواحد مايكتبش الاشي الغلط بلاش
+
+134
+00:11:16,030 --> 00:11:20,110
+تروح يرسخ في ذهن الناس بس هذا إذا صرتم علمات
+
+135
+00:11:20,110 --> 00:11:26,620
+للمرحلة الابتدائيةممنوع تكتبوا الغلط واضح؟ للمراحل
+
+136
+00:11:26,620 --> 00:11:29,260
+الابتدائية و الاعدادية بيقولوا ما تكتبش الغلط ما
+
+137
+00:11:29,260 --> 00:11:35,080
+تكتبش قدامه الا الصح في مرحلة جامعية ممكن الواحد
+
+138
+00:11:35,080 --> 00:11:38,320
+يكتب الغلط الغلط اللي دايما بيناعمل انه لما نقول
+
+139
+00:11:38,320 --> 00:11:44,760
+كيف تحضر الانيلين بيجيوا ناس بيقولنا بنزين مع NH3
+
+140
+00:11:44,760 --> 00:11:48,480
+و بيحطوا اش اللي بيجي على بالهم و بيعطي انيلين هذا
+
+141
+00:11:48,480 --> 00:11:54,870
+ايش؟ قبل ما تشوفوا الكاميراهذا أخطاء مش خطأ واحد
+
+142
+00:11:54,870 --> 00:11:58,650
+بنعتبره الانيلين بتحضرش من البنزين مع الأمونيا
+
+143
+00:11:58,650 --> 00:12:02,890
+طبعا لو بدنا نقول ليش طيب هذا يعني مستحيل و بنخوف
+
+144
+00:12:02,890 --> 00:12:09,430
+و بنشطله أربع أخطاء لأنهإتفقنا إحنا أن التفاعل
+
+145
+00:12:09,430 --> 00:12:15,390
+الأساسي تبع البنزين هو أن نضيف عليه إشي موجب و ال
+
+146
+00:12:15,390 --> 00:12:24,090
+ammonia هذه ال N-H3 بتحمل زوج من الإلكترونات وهنا
+
+147
+00:12:24,090 --> 00:12:28,690
+في عندي أزواج من الإلكترونات هل يا تورا بقدر أجيب
+
+148
+00:12:28,690 --> 00:12:34,690
+أنا إلكترونات على إلكترونات؟لأ لذلك دائما اللي بده
+
+149
+00:12:34,690 --> 00:12:38,250
+ييجي يهاجم على البنسي اللي بده يكون بشكل عام موجة
+
+150
+00:12:38,250 --> 00:12:41,810
+عشانك لما درسنا ال nutrition قولنا ان هدولا
+
+151
+00:12:41,810 --> 00:12:47,770
+الحامضين مع بعض بيعطونا NO2 plus هي اللي بتهاجم
+
+152
+00:12:47,770 --> 00:12:52,750
+على ال minusولذلك هذا التحضير ان انا بتحضر
+
+153
+00:12:52,750 --> 00:12:57,370
+الانيلين مباشرة بأمونيا مع بنزين هذا كلام لا يجوز
+
+154
+00:12:57,370 --> 00:13:01,990
+والسبب ان انا مابقدرش اضيف سالب على سالب انا اللي
+
+155
+00:13:01,990 --> 00:13:06,210
+بدي اضيف بدي اضيف موجب على سالب ولذلك اذا بدنا
+
+156
+00:13:06,210 --> 00:13:10,630
+نسألكوا كيف بتحضروا الانيلين او ممكن نكون مصعبين
+
+157
+00:13:10,630 --> 00:13:17,830
+السؤال المثل انيلين مثلا كيف بدكوا تمشيه بدنا
+
+158
+00:13:20,160 --> 00:13:25,360
+بنبقى من البنزين ونستعمل عملية الـ Nitration طبعا
+
+159
+00:13:25,360 --> 00:13:29,940
+كأنيلين بنحوّل لنيترو بعدين هالانيلين بال
+
+160
+00:13:29,940 --> 00:13:34,260
+reduction الآن لو كان في عندك أكتر من Substituent
+
+161
+00:13:34,260 --> 00:13:41,400
+في هذه الحالة لازم أنتبه لعملية الترتيب أي واحدة
+
+162
+00:13:41,400 --> 00:13:46,540
+نحطها في الأول يعني مثلا لو كان السؤال عندكم ان
+
+163
+00:13:46,540 --> 00:13:53,260
+كيف بدي أحضرالـ NH2CH3
+
+164
+00:13:53,260 --> 00:13:58,540
+واضح؟
+
+165
+00:13:58,540 --> 00:14:03,920
+قدر
+
+166
+00:14:03,920 --> 00:14:09,140
+الإمكان تعتبر أن الـ NH2 أصلها إيش؟ يعني هذه جاية
+
+167
+00:14:09,140 --> 00:14:19,420
+من إيش؟ أصلها نيترو هذه أصلهابناء على ذلك، لو كنت
+
+168
+00:14:19,420 --> 00:14:23,760
+بتبدأ بالمثل، المثل بتوجه بارا، لو كنت بتبدأ
+
+169
+00:14:23,760 --> 00:14:31,500
+بالنيترو، النيترو بتوجه ميتا، النيترو is a
+
+170
+00:14:31,500 --> 00:14:35,580
+metadirecting group، الاماينو بارا directing
+
+171
+00:14:35,580 --> 00:14:38,920
+group، بس النيترو ميتا، انتبهوا معايا، هذي
+
+172
+00:14:38,920 --> 00:14:42,280
+activating و بارا directing group، هذي
+
+173
+00:14:42,280 --> 00:14:47,380
+deactivating وميتا directing groupواضح فبناء على
+
+174
+00:14:47,380 --> 00:14:51,480
+ذلك لو بدأ ابدأ بالبنزين ممكن اعمل اول اشي مثيلاشن
+
+175
+00:14:51,480 --> 00:14:58,880
+احط المثل و بعدين نيتراشن اذا البنزين اول اشي بنحط
+
+176
+00:14:58,880 --> 00:15:02,640
+المثل مثل كلورايد مثلا مع الومنيوم كلورايد و
+
+177
+00:15:02,640 --> 00:15:08,740
+الخطوة التانية نيتراشن بصير عند بارا نيترو طولوين
+
+178
+00:15:08,740 --> 00:15:15,840
+و بعدين بنعملهreduction واضح النيترو لما يصير امين
+
+179
+00:15:15,840 --> 00:15:19,300
+بده ينعمل reduction اذا هذا لو كان بده الخطوات
+
+180
+00:15:19,300 --> 00:15:26,960
+كاملة ابتداء من البنزين كيف بده اعمل بنزين CH3
+
+181
+00:15:26,960 --> 00:15:30,560
+CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3 CH3
+
+182
+00:15:30,560 --> 00:15:34,840
+CH3 CH3
+
+183
+00:15:34,840 --> 00:15:39,040
+CH3 CH3
+
+184
+00:15:40,460 --> 00:15:47,660
+بعدين reduction طبعا هنا نيتريشن HRO3H2SO4
+
+185
+00:15:47,660 --> 00:15:52,500
+هنا reduction HRO3H2SO4
+
+186
+00:15:52,500 --> 00:15:56,880
+HRO3H2SO4
+
+187
+00:15:56,880 --> 00:15:57,280
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+188
+00:15:57,280 --> 00:15:57,800
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+189
+00:15:57,800 --> 00:15:58,140
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+190
+00:15:58,140 --> 00:15:58,540
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+191
+00:15:58,540 --> 00:16:01,760
+HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4
+
+192
+00:16:01,760 --> 00:16:10,610
+HRO3H2SO4 HRO3H2فالخلاصة انه مابتنحطش ال amino
+
+193
+00:16:10,610 --> 00:16:16,810
+group مباشرة لازم تيجي من وين؟ من ال nitro في مركب
+
+194
+00:16:16,810 --> 00:16:21,130
+الحقيقة شبيه ايضا .. شبيه ايضا ومابديش ياكوا
+
+195
+00:16:21,130 --> 00:16:26,630
+تغلطوا، هنعود نركز عليه شبيه ايضا بال .. بالانيلين
+
+196
+00:16:26,630 --> 00:16:32,650
+لا يحضر مباشرة اللي هو مركب الفينول واضح؟ لما
+
+197
+00:16:32,650 --> 00:16:35,810
+بيكون عندكم فينول هنا OH
+
+198
+00:16:38,750 --> 00:16:45,090
+مش معقول ان واحدة تيجي تعمللنا بنزين مع OH minus
+
+199
+00:16:45,090 --> 00:16:52,310
+ليش لان هتحط minus على minus هذا الكلام لا يجوز
+
+200
+00:16:52,310 --> 00:16:58,900
+الفينول لا يحضر مباشرة من البنزينالفينول بقدرش
+
+201
+00:16:58,900 --> 00:17:03,620
+أقول بنزين مع OH- اللي هو ماعطيني الفينول هنتعلم
+
+202
+00:17:03,620 --> 00:17:08,920
+طريقة ان شاء الله كيف نحضر الفينول بطريق غير مباشر
+
+203
+00:17:08,920 --> 00:17:13,220
+بس مانقدرش نحضره بمباشر فإذا سئلته عن الانيلين أو
+
+204
+00:17:13,220 --> 00:17:20,100
+الفينول الطريقة غير مباشرة الطريقة غير مباشرة
+
+205
+00:17:20,100 --> 00:17:22,660
+لعملية التحضير
+
+206
+00:17:34,790 --> 00:17:41,210
+الان في كمان طريقة ممكن من خلالها انحضر
+
+207
+00:17:42,430 --> 00:17:47,790
+الأ means إن نعمل reduction للـ neutrals طبعا
+
+208
+00:17:47,790 --> 00:17:53,410
+انتبهوا معي إنه الـ neutral اللي هي ال Rcn من وين
+
+209
+00:17:53,410 --> 00:17:59,870
+أنا ممكن أجيبها بشكل عام من ال Rcl يعني لو كان
+
+210
+00:17:59,870 --> 00:18:04,390
+عندي مثل أن أنا مثل neutral بدي أحضرها المفروض
+
+211
+00:18:04,390 --> 00:18:09,690
+بحضرها من CH3 CL مع CN minus
+
+212
+00:18:11,570 --> 00:18:17,450
+واضح؟ CH3Cl مع Cl- لو بدنا نقول أكتر ال CH3Cl من
+
+213
+00:18:17,450 --> 00:18:28,870
+وين بنحضرها؟ من ال alcohol CH3OH مثلا مع BCl3 و
+
+214
+00:18:28,870 --> 00:18:32,010
+هذا الكلام اللي كنا دايما بنحكيه أن ال alcohol
+
+215
+00:18:32,010 --> 00:18:36,030
+يمثل نقطة إيش؟ انطلاق في ال organic synthesis
+
+216
+00:18:37,380 --> 00:18:40,400
+فالخلاص لو عندى alcohol ممكن احوله لchloride
+
+217
+00:18:40,400 --> 00:18:45,860
+لchloride ل نيترال بعمله hydrogenation reduction
+
+218
+00:18:45,860 --> 00:18:49,760
+سواء هذا ال reduction بليثيوم ألومنوم هيدرايد ممكن
+
+219
+00:18:49,760 --> 00:18:55,040
+أو بهيدروجينوميتال طبعا
+
+220
+00:18:55,040 --> 00:18:57,960
+المقصود بال reduction انه على الكابون و النيتروجين
+
+221
+00:18:57,960 --> 00:19:07,970
+هذه بضيف H وH وكمان H وH هى صار CH3 CH2un-atched
+
+222
+00:19:07,970 --> 00:19:15,970
+لاحظوا هذه الطريقة فيها ميزة انه انا في المركب
+
+223
+00:19:15,970 --> 00:19:21,310
+الأول سواء كان alcohol او كان chloride عدد ذرات
+
+224
+00:19:21,310 --> 00:19:26,350
+الكربون اللي عنده بتكون اقل بواحد من الأمين الناتج
+
+225
+00:19:26,350 --> 00:19:29,210
+يعني هنا لما يكون عندى مثل chloride كام كربون
+
+226
+00:19:29,210 --> 00:19:33,810
+عنده؟ واحد لو كنت بدأ أقولكوا حضرولي اث الأمين
+
+227
+00:19:33,810 --> 00:19:38,850
+الآن هنا زادتكربونة يعني هي المثل هذه هي المثل هذه
+
+228
+00:19:38,850 --> 00:19:43,090
+طب من وين إجت الكربونة لزيادة من ال cyan .. ال
+
+229
+00:19:43,090 --> 00:19:49,090
+cyanide واضح فهذه الطريقة بتحتمل زيادة كربونة على
+
+230
+00:19:49,090 --> 00:19:52,030
+عدد الكربونات الأصلية أنا كان عندي كربونة واحدة
+
+231
+00:19:52,030 --> 00:19:58,000
+هناك بيصير عنده two carbon atoms واضحوالـ Carbon
+
+232
+00:19:58,000 --> 00:20:03,280
+الجديدة مصدرها من مجموعة الـ CNI زي ما حكينا إن
+
+233
+00:20:03,280 --> 00:20:06,560
+إضافة الهيدروجين أو الـ reduction يابليثيوم
+
+234
+00:20:06,560 --> 00:20:10,500
+ألومنوم هيدرايديا بإضافة غاز الهيدروجين في وجود
+
+235
+00:20:10,500 --> 00:20:26,020
+متل بيعطينا الأمين الطريقة
+
+236
+00:20:26,790 --> 00:20:31,570
+التالتة او الرابعة لتحضير ال amines الطريقة
+
+237
+00:20:31,570 --> 00:20:37,110
+الرابعة لتحضير ال amines عمليا او تطبيقيا هذه
+
+238
+00:20:37,110 --> 00:20:43,090
+الطريقة لها تفاصيل كتيرة لكن على أرض الواقع ممكن
+
+239
+00:20:43,090 --> 00:20:47,470
+تفهموها بسهولة اذا انا أخدت الalkyl halide
+
+240
+00:20:50,810 --> 00:20:58,170
+وفعلته مع الأمونيا أو أي أمين تاني بس حطيت عند شرط
+
+241
+00:20:58,170 --> 00:21:05,670
+ضروري جدا ان هذه الأمونيا تكون excess واضح؟
+
+242
+00:21:05,670 --> 00:21:13,210
+يعني RX زائد أمونيا excess بيعطينا الأمين زائد
+
+243
+00:21:13,210 --> 00:21:19,450
+طبعا أمونيومبروميد ليش فكرة ال excess هذه بنحطها
+
+244
+00:21:19,450 --> 00:21:25,470
+احنا؟ليش بنحط ال .. ال ammonia تكون زيادة؟ على
+
+245
+00:21:25,470 --> 00:21:29,750
+أساس انه اللي ممكن يصير عندى .. اللي ممكن يصير
+
+246
+00:21:29,750 --> 00:21:34,730
+عندى انه لو ماحطيتش انا ال ammonia هذه excess ممكن
+
+247
+00:21:34,730 --> 00:21:39,290
+بعد ما نحول الى ال amine الأول هيصار عندى amine
+
+248
+00:21:39,290 --> 00:21:44,540
+تمام؟ يجي ال amine هذا الأول اللي ..هو يتفاعل مع
+
+249
+00:21:44,540 --> 00:21:48,500
+جزيئات تانية من البروم يعمل secondary compound
+
+250
+00:21:48,500 --> 00:21:52,280
+وممكن هذا المركب بعد ما ينتج يتفاعل كمان مرة
+
+251
+00:21:52,280 --> 00:21:57,660
+يعطينا tertiary الخلاصة كل الغلبة والمعادلات انا
+
+252
+00:21:57,660 --> 00:22:01,820
+هذه مابديش اغص معاكم فيها انا اللي بدي اياه منكم
+
+253
+00:22:01,820 --> 00:22:06,840
+في هذه اللحظة ان الalkyl halides مع ال ammonia
+
+254
+00:22:06,840 --> 00:22:12,470
+excess بيعطيناأمين بدون مشاكل يعني زي هيك المعادلة
+
+255
+00:22:12,470 --> 00:22:20,610
+بتكون ايش بدون مشاكل واضح؟ وهذه بيكون تكملتها زائد
+
+256
+00:22:20,610 --> 00:22:28,190
+طبعا HPRإذا ما حطيناش هذا excess بصير مشاكل كتير
+
+257
+00:22:28,190 --> 00:22:31,930
+كل المعادلات اللي قدامكوا ان التفاعل بتمر تين و
+
+258
+00:22:31,930 --> 00:22:35,650
+تلاتة و بيصير فيه غلبة واضح؟ خلينا احنا على
+
+259
+00:22:35,650 --> 00:22:40,470
+المعادلة اللي بدون مشاكل انه الalkyl heli مع ال
+
+260
+00:22:40,470 --> 00:22:44,230
+ammonia excess بيعطينا ال amine زي ال HBr اللي هي
+
+261
+00:22:44,230 --> 00:22:47,990
+المعادلة البسيطة اللي مافيش فيها مشاكل وين بتصير
+
+262
+00:22:47,990 --> 00:22:53,440
+المشاكل؟إذا هذا كان مش excess بيصير عندكوا صفحتين
+
+263
+00:22:53,440 --> 00:22:57,960
+معادلات بهذه المرحلة أنا بعتقد أنه أنا في غنى عنهم
+
+264
+00:22:57,960 --> 00:23:02,620
+واضح؟ وفي غنى عن الصفحة هذه الأخيرة اللي فيها text
+
+265
+00:23:02,620 --> 00:23:09,100
+بيشرح ليش بتصير المشاكل واضح؟ فكل اللي بيلزمنا
+
+266
+00:23:09,100 --> 00:23:12,620
+نكون عارفينه أنه تفاعل ال alkyl halide مع ال
+
+267
+00:23:12,620 --> 00:23:17,040
+ammonia excess مباشرة بيعطيني الأمين بدون مشاكل
+
+268
+00:23:17,040 --> 00:23:23,310
+اللي بدهوا مشاكليستعمل مش إكسس
+
+269
+00:23:34,410 --> 00:23:38,790
+تقريبا هذا مثال تطبيقه على نفس الفكرة .. هذا مثال
+
+270
+00:23:38,790 --> 00:23:43,330
+تطبيقه على نفس الفكرة لو أخدت أنا الأليلين مثلا مع
+
+271
+00:23:43,330 --> 00:23:46,770
+ال methyl iodide بصير عندي تفاعل إفدال، هاي
+
+272
+00:23:46,770 --> 00:23:51,570
+الأليلين بيهاجم هنا و بيطرد اليود بيعطيني methyl
+
+273
+00:23:51,570 --> 00:23:56,010
+-allylene لو ال methyl-allylene بيدفعله كمان مرة
+
+274
+00:23:56,010 --> 00:23:59,030
+أنا مع ال methyl-iodide، هاي زوج الألكترونات،
+
+275
+00:23:59,030 --> 00:24:02,450
+أفعله يهاجم و يطرد اليود، بيصير عندي
+
+276
+00:24:06,360 --> 00:24:15,800
+المثال الأخير في هذا المجال أن نيتروجين بتحل محل
+
+277
+00:24:16,880 --> 00:24:21,060
+البروم بس احنا كنا نجيب ال nitrogen بجزيق و البروم
+
+278
+00:24:21,060 --> 00:24:25,700
+بجزيق تاني هل ممكن يكون ال nitrogen و البروم بنفس
+
+279
+00:24:25,700 --> 00:24:30,500
+الجزيق بمعنى التفاعل يكون intra-molecular؟ الجواب
+
+280
+00:24:30,500 --> 00:24:34,200
+اه في هذا المثال اللي عندى اللي في حلقة بيريدين
+
+281
+00:24:34,200 --> 00:24:41,310
+هنا H1H مثل مع PR بتهاجم ال nitrogen و بتطردالبر
+
+282
+00:24:41,310 --> 00:24:46,370
+هو SM2 substitution غالبا فتعطينا هذا المُركّب
+
+283
+00:24:46,370 --> 00:24:49,510
+اللي فيه حلقة خمسية فيها نيتروجين وحلقة سوداسية
+
+284
+00:24:49,510 --> 00:24:56,570
+فيها نيتروجين وحلقة البريدين وحلقة بيروليدين
+
+285
+00:24:56,570 --> 00:25:03,060
+المُركّب كله هو نيكوتين السجائرواضح؟ المراكب كله
+
+286
+00:25:03,060 --> 00:25:06,600
+وانا كنت انسى كده الفكرة ليش احنا جيبنا هذا المثال
+
+287
+00:25:06,600 --> 00:25:13,300
+هنا حتى نفرجيكوا انه ال nitrogen بتحل محل لبروم
+
+288
+00:25:13,300 --> 00:25:17,840
+اللي هو موضوعنا تحضير ال amines من خلال ان ال
+
+289
+00:25:17,840 --> 00:25:20,860
+nitrogen تحل محل لبروم
+
+290
+00:25:34,040 --> 00:25:39,800
+الآن الـ Amines زي ما احنا اتفقنا وكل مركبات الـ
+
+291
+00:25:39,800 --> 00:25:44,830
+nitrogen عادة بيكون عليهم زوج منالإلكترونات ولذلك
+
+292
+00:25:44,830 --> 00:25:49,550
+يُعاملوا على إنهم bases وفي المُركّبات الـnatural
+
+293
+00:25:49,550 --> 00:25:53,530
+اللي فيها الـNitrogen هذه بالذات على حلقات بيسموها
+
+294
+00:25:53,530 --> 00:25:58,290
+الـAlkaloids ومن هذه الـAlkaloids بالمناسبة زي هذا
+
+295
+00:25:58,290 --> 00:26:01,490
+المُركّب النيكوتين بسبب وجود الـNitrogen هنا اللي
+
+296
+00:26:01,490 --> 00:26:04,710
+لها زوج إلكترونات والـNitrogen هنا اللي لها زوج
+
+297
+00:26:04,710 --> 00:26:11,260
+إلكترونات بيقولوا هذا مُركّب قاعدي بياخدالاسم
+
+298
+00:26:11,260 --> 00:26:14,320
+العائلة العام في المراكبات أو المنتجات الطبيعية
+
+299
+00:26:14,320 --> 00:26:19,560
+بنسمي احنا ايش ال Calorie فالمهم في ال Amines
+
+300
+00:26:19,560 --> 00:26:26,000
+حقيقة هو زوج الإلكترونات هذا زوج الإلكترونات بيخلي
+
+301
+00:26:26,000 --> 00:26:31,140
+ال Amines بشكل عام مش دائما بالمطلق بشكل عام
+
+302
+00:26:31,140 --> 00:26:41,480
+يتفاعلوا as bases وقتاش ممكن يتفاعلوامش كباسإذا
+
+303
+00:26:41,480 --> 00:26:46,100
+بنجيب base أقوى منهم واضح؟ ليش؟ زي ما بتقول أهو
+
+304
+00:26:46,100 --> 00:26:51,260
+فوق كل ذي علم عليم يعني أي حامض ممكن أحاوله ل base
+
+305
+00:26:51,260 --> 00:26:56,300
+ب .. بإيش؟ بتجيب حامض أقوى منه و ال base ممكن
+
+306
+00:26:56,300 --> 00:26:59,680
+أخليها تبين كإنها acid بتجيب قاعدة أقوى منها
+
+307
+00:26:59,680 --> 00:27:04,800
+بتصيريا كإنها acid و القاعدة الأقوى .. أه لكن بشكل
+
+308
+00:27:04,800 --> 00:27:10,020
+عام ال amines و ال ammonia they are considered as
+
+309
+00:27:10,600 --> 00:27:17,400
+basis بشكل عام basis عشان ات لو مثلا احنا بناخد ال
+
+310
+00:27:17,400 --> 00:27:23,740
+ammonia على سبيل المثال مع H plus خلينا نفترضها
+
+311
+00:27:23,740 --> 00:27:30,900
+انها كانت H3O plus يعني حامض مدوب في ميه واضح فال
+
+312
+00:27:30,900 --> 00:27:32,660
+ammonia منها انا هتاخد
+
+313
+00:27:39,080 --> 00:27:43,440
+الحامض اللي مدوب في مياه أسد بيعطينا الامونيوم ايو
+
+314
+00:27:43,440 --> 00:27:48,080
+الان اتش فور بلس زائد الميه اهم في الموضوع ان
+
+315
+00:27:48,080 --> 00:27:53,850
+الامونيا هنا تعاملت كإنها ايشبس و نفس الاشي لو انا
+
+316
+00:27:53,850 --> 00:27:59,430
+باخد حتى بالحالة الغازية مش بالحالة السائلة و يمكن
+
+317
+00:27:59,430 --> 00:28:04,790
+كان عندكم او مرات بيكون في تجربة او في مساق
+
+318
+00:28:04,790 --> 00:28:12,130
+الكيميا العامة تجربة بتوضح كده يمشوا الجزيئات
+
+319
+00:28:12,130 --> 00:28:21,360
+بيجيبواأربوبة بهذا الشكل وبحط هنا نقطة من الأمونيا
+
+320
+00:28:21,830 --> 00:28:26,150
+سوليوشن و بيحطوه هنا نقطة من ال HCl بيحطوه مبعد
+
+321
+00:28:26,150 --> 00:28:30,710
+طبعا هنا هتتبخر أمونيا وهنا هتتبخر HCl هيبدو
+
+322
+00:28:30,710 --> 00:28:35,230
+يجربوا مع بعض لحظة ما بتتفاعل الأمونيا بشكلها
+
+323
+00:28:35,230 --> 00:28:40,450
+الغازي مع ال HCl بشكله الغازي بيعطينا ال H4Cl
+
+324
+00:28:40,450 --> 00:28:44,990
+الأمونيوم الكلورايد والأمونيوم الكلورايد دائما
+
+325
+00:28:44,990 --> 00:28:50,630
+بتذكروا في المدارس إيش كنتوا تسموه كلوريد
+
+326
+00:28:50,630 --> 00:28:51,450
+الأمونيوم
+
+327
+00:28:55,250 --> 00:28:59,770
+اليوم مشي كتير الدنيا شتاء بيقولوا عنه صحوب بيضاء
+
+328
+00:28:59,770 --> 00:29:03,910
+من كلوريد الأمونيوم يعني أول ما بتحدوا مع بعض
+
+329
+00:29:03,910 --> 00:29:08,810
+بيعملوا لون أبيض زي السحابة البيضاء فإذا التقى غاز
+
+330
+00:29:08,810 --> 00:29:15,950
+الأمونيا مع غاز ال HCl مش مع المحليل بيعطينا white
+
+331
+00:29:15,950 --> 00:29:19,110
+clouds أو صحوب بيضاء من الأمونيوم الكلوريد طبعا
+
+332
+00:29:19,110 --> 00:29:23,560
+هذه بتيجي في منطقة معينة هنااللي هي ال ammonia و
+
+333
+00:29:23,560 --> 00:29:28,440
+ال chloride و قعدت بحسبه قداشه بيمشي كل جزيق نسبة
+
+334
+00:29:28,440 --> 00:29:33,540
+لوزنه مين اللي بده يمشي أسرع الجزيق الخفيف بناء
+
+335
+00:29:33,540 --> 00:29:37,780
+على ذلك هنكون احنا بعاد عن الجزيق الخفيف و grab
+
+336
+00:29:37,780 --> 00:29:46,120
+للجزيق التجيل واضحة ولا نوضحها أكتر بلاش نوضحها
+
+337
+00:29:46,120 --> 00:29:53,060
+أكتر هالجيتا لو حطينا .. لو حطينا ولد صغيرمع ال M
+
+338
+00:29:53,060 --> 00:29:57,920
+مثلا و بينهم عشرين متر و تركناهم ال M أكم خطوة
+
+339
+00:29:57,920 --> 00:30:02,140
+بتمشي؟ هذا إذا مشيت تلت خطوات و الولد لما بيجي
+
+340
+00:30:02,140 --> 00:30:06,340
+جراي أكم خطوة بمشي؟ يمكن خمستاشر خطوة هل بيمشوا
+
+341
+00:30:06,340 --> 00:30:10,460
+بنفس الإشي الخفيف مع اللي تجيل؟ نفس الإشي فلو
+
+342
+00:30:10,460 --> 00:30:13,920
+بتخيلوا أنه زي هيك هنا بدو يكون عندي مثلا ال HCl
+
+343
+00:30:13,920 --> 00:30:19,400
+هنا بدو يكون عندي ال ammonia ليش؟ لأن ال HClبنحكي
+
+344
+00:30:19,400 --> 00:30:22,180
+احنا عن خمسة و تلاتين و نص، ستة و تلاتين و نص
+
+345
+00:30:22,180 --> 00:30:26,180
+الوزن، هنا بنحكي عن سبعتاشر، اربعتاشر تلاتة، إذا
+
+346
+00:30:26,180 --> 00:30:29,860
+من الأدقال و اللي بيمشي أقل، إله علاقة عكسية مع
+
+347
+00:30:29,860 --> 00:30:33,820
+المسافة و بيعملوها تجربة و بيجيسوا كدهش المسافة
+
+348
+00:30:33,820 --> 00:30:37,680
+هنا و المسافة هنا و بيحققوا هذه العلاقة، واضح؟
+
+349
+00:30:41,600 --> 00:30:48,040
+الخلاصة أن تفاعل الـ Ammonia gas مع الـ HCl gas هو
+
+350
+00:30:48,040 --> 00:30:54,540
+حقيقة تفاعل acid-base أن زوج الإلكترونات بتاع الـ
+
+351
+00:30:54,540 --> 00:30:59,660
+Ammonia هو اللي بده يتفاعل مع الـ H plus بيكوّن
+
+352
+00:30:59,660 --> 00:31:03,840
+للأيون الموجة بأمونيوم طبعا عندي كلور بده يكون
+
+353
+00:31:03,840 --> 00:31:04,500
+أمونيوم
+
+354
+00:31:09,870 --> 00:31:16,990
+الان لو اتينا نتطلع على ال basicity of a means زي
+
+355
+00:31:16,990 --> 00:31:21,610
+ما اتفقنا احنا ان ال a means are basis ال a means
+
+356
+00:31:21,610 --> 00:31:26,670
+are basis وسبب
+
+357
+00:31:26,670 --> 00:31:34,750
+ال basicity زوج ال electronic لاحظوا هنا حاططعدة
+
+358
+00:31:34,750 --> 00:31:39,770
+أشياء من خلالها ممكن احنا نعمل مقارنة وقت إيش
+
+359
+00:31:39,770 --> 00:31:45,350
+بتزيد ال basicity وقت إيش بتقل الجواب بسيط كل ما
+
+360
+00:31:45,350 --> 00:31:49,990
+زادت الكثافة الإلكترونية كل ما زادت الكثافة
+
+361
+00:31:49,990 --> 00:31:56,550
+الإلكترونية بيكون المركب basic أكتر ولا أقل وكل ما
+
+362
+00:31:56,550 --> 00:32:02,870
+سحبنا منه إلكتروناتبكون less basic بناء على ذلك لو
+
+363
+00:32:02,870 --> 00:32:07,990
+احنا بناجي بنطلع هو أنا للأسف مش كاتبلكوا ال BKB
+
+364
+00:32:08,810 --> 00:32:14,490
+كاتب ال BKA للحمض المرافق يعني الأمونيا الحامض
+
+365
+00:32:14,490 --> 00:32:20,110
+المرافق تبعها الاناتش فور بلس هو كاتب ال BKA
+
+366
+00:32:20,110 --> 00:32:24,610
+للأمونيوم أيون اللي أسهل إلي في المقارنة كان ممكن
+
+367
+00:32:24,610 --> 00:32:30,010
+أكتب ال BKB لنفس الأمونيا الآن مش مشكلة كبيرة لما
+
+368
+00:32:30,010 --> 00:32:34,090
+بدي أحسبها بدي أقول 14 ناقص هذي يعني لو بدي أحكي
+
+369
+00:32:34,090 --> 00:32:36,590
+هنا بدي أحكي عن four point
+
+370
+00:32:39,290 --> 00:32:45,330
+seven على سبيل المثال و لو بدي أحكي هنا في حالة
+
+371
+00:32:45,330 --> 00:32:53,900
+الانالين بدي أحكي عنه9.3 تقريبا و هكذا يعني مش صعب
+
+372
+00:32:53,900 --> 00:32:59,900
+ان نحسب .. مش صعب ان نحسب ال BKB مش صعب ان نحسب ال
+
+373
+00:32:59,900 --> 00:33:04,260
+BKB طبعا بتكونوا انتوا متذاكرين شغلة انه كل ما ال
+
+374
+00:33:04,260 --> 00:33:10,120
+BKB بتقل معنى ذلك ال basicity بده تكون اعلى بناء
+
+375
+00:33:10,120 --> 00:33:14,360
+على ذلك لو بده في الأول المقارنة الأولى بين ألفاتك
+
+376
+00:33:14,360 --> 00:33:19,920
+أمين زي ال بيث الأمين أو ال دايمة الأمين مطفاتأي
+
+377
+00:33:19,920 --> 00:33:22,900
+اروماتيك كومباون من الأعلى الالفاتك ولا
+
+378
+00:33:22,900 --> 00:33:28,260
+الاروماتيك؟ الالفاتك
+
+379
+00:33:30,660 --> 00:33:34,740
+هذا من ناحية القيمة واضح أن الـ aliphatic الـ
+
+380
+00:33:34,740 --> 00:33:40,300
+basicity لهم أعلى السؤال لماذا؟ لسبب بسيط أن زوج
+
+381
+00:33:40,300 --> 00:33:44,340
+الألكترونات في الـ aliphatic compounds جاهز إنه
+
+382
+00:33:44,340 --> 00:33:47,620
+يتفاعل جاهز إنه يكون كأنه base بينما في ال
+
+383
+00:33:47,620 --> 00:33:51,960
+aromatic compounds بيعمل resonanceوبالتالي هو غير
+
+384
+00:33:51,960 --> 00:33:57,080
+جاهز للتفاعل الخارجي واضح في السبب حقيقة هو ال
+
+385
+00:33:57,080 --> 00:34:01,220
+resonance نفس الأشياء هنا لو أنا مثلا بدي أجي أطلع
+
+386
+00:34:01,220 --> 00:34:06,560
+على ال aniline و ال cyclohexane hexamine اللي
+
+387
+00:34:06,560 --> 00:34:11,370
+بيكون أعلى ك baseالـCyclohexyl، هذا الـaliphatic،
+
+388
+00:34:11,370 --> 00:34:16,030
+هذا الـaromatic، ما هو السبب؟ السبب هنا إن هذا زوج
+
+389
+00:34:16,030 --> 00:34:22,770
+الإلكترونات عشان يكون base لزمنه وين يتفاعل؟ برا،
+
+390
+00:34:22,770 --> 00:34:27,710
+اللي بده يثبت قوته، وين بده يثبت قوته؟ برا ولا
+
+391
+00:34:27,710 --> 00:34:33,610
+جوا؟ برا، واضح؟ عشان هيك الرجال اللي عن جد هو مين؟
+
+392
+00:34:34,700 --> 00:34:37,940
+اللي بيثبت قوته برا مش علي ولادنا صغار في الدار و
+
+393
+00:34:37,940 --> 00:34:44,140
+بيعمل مشاكل و .. واضح؟ اه ف .. عشان يكون بياس معنى
+
+394
+00:34:44,140 --> 00:34:47,680
+ذلك هو جاهز للتفاعل برا مش جاهز انه يضل يتفاعل مع
+
+395
+00:34:47,680 --> 00:34:52,220
+نفسه و يضحن نفسه الآن هنا في حالة الـ aromatic
+
+396
+00:34:52,220 --> 00:34:56,520
+amine هذا زوج الإلكترونات في resonance effect ممكن
+
+397
+00:34:56,520 --> 00:35:00,260
+يتحرك زي هيك تيجي هذه ال minus تصير محمولة هنا
+
+398
+00:35:00,260 --> 00:35:04,920
+كمان حركة تصير هنا كمان حركة تصير هنا الخلاصةهل
+
+399
+00:35:04,920 --> 00:35:25,060
+هذا زوج الالكترونات جاهز للتفاعل مع الخارج؟ هل
+
+400
+00:35:25,060 --> 00:35:30,800
+هذا زوج الالكترونات جاهز للتفاعل مع الخارج؟
+
+401
+00:35:34,210 --> 00:35:39,890
+بتشكل جوا الحلقة، واضح؟ ولذلك الـ aliphatic amines
+
+402
+00:35:39,890 --> 00:35:44,010
+بشكل عام they are more basic than aromatic amines
+
+403
+00:35:44,010 --> 00:35:47,910
+لأن ال aromatic amines بتعمل resonance فبدل ما زوج
+
+404
+00:35:47,910 --> 00:35:50,870
+الإلكترونات هيوا عن نيتروجين في أحد ال resonance
+
+405
+00:35:50,870 --> 00:35:54,750
+structure شو صارت ال nitrogen؟ positive، بطل عليها
+
+406
+00:35:54,750 --> 00:36:00,650
+زوج الإلكترونات، واضح؟ فلو بدنا نيجي نسأل كقاعدة
+
+407
+00:36:00,650 --> 00:36:06,910
+عامةوهي أكثر أساسية ألفاتيك أو أروماتيك أمين
+
+408
+00:36:06,910 --> 00:36:13,410
+الجواب ألفاتيك أمين بسبب ريزونانس الألفاتيك أمين
+
+409
+00:36:13,410 --> 00:36:18,430
+هم أعلى والسبب أن الأروماتيك أمين بيعملوا ريزونانس
+
+410
+00:36:18,430 --> 00:36:23,890
+الألفاتيك أمين بيعملوش ريزونانس هذه النقطة الأولى
+
+411
+00:36:23,890 --> 00:36:31,530
+الآن لو رجعنا شوية صغيرة للجدول وعملنا كمان مقارنة
+
+412
+00:36:32,150 --> 00:36:38,970
+يا تورا، مين بيكون more basic؟ الأمين اللي عليه
+
+413
+00:36:38,970 --> 00:36:44,890
+مثلا R1 أو R2 أو R3 لحظة، أنا عندي مثل أمين، المثل
+
+414
+00:36:44,890 --> 00:36:51,030
+بتعطي إلكترونات، هنا die مثل أمين، مجموعة المثل،
+
+415
+00:36:51,030 --> 00:37:00,110
+هنا try مثل أمينواضح؟ قلية أعلى واحدة فيهم الـ
+
+416
+00:37:00,110 --> 00:37:05,790
+trimethylamine is more basic than الـ
+
+417
+00:37:05,790 --> 00:37:11,170
+dimethylamine بمعنى أنه أنا كل ما بيكون عندي .. كل
+
+418
+00:37:11,170 --> 00:37:15,700
+ما بيكون عندي electrondonating groups المفروض ال
+
+419
+00:37:15,700 --> 00:37:21,120
+basicity ايش يصير لها اتزيد هذا الكلام نفسه ممكن
+
+420
+00:37:21,120 --> 00:37:28,300
+تلاحظوه لو بدكوا تعمله مقارنة مثلا المثال اللي تحت
+
+421
+00:37:28,300 --> 00:37:34,140
+aromatic احنا قولنا ال aromatic بشكل عام ليس basic
+
+422
+00:37:34,140 --> 00:37:40,640
+لكن خليني اقارن aromatic مع aromatic مع aromatic
+
+423
+00:37:41,600 --> 00:37:47,820
+واضح؟ كله ضعيف، لكن مين فيهم؟ الأضعف، الأن لو حطيت
+
+424
+00:37:47,820 --> 00:37:52,440
+هنا مجموعة مثل، مجموعة المثل، بتعطي إلكترونات،
+
+425
+00:37:52,440 --> 00:37:56,800
+خليني اعتبر الـ H حلق وسط، وهنا مجموعة نيترو بتسحب
+
+426
+00:37:56,800 --> 00:38:03,100
+الإلكترونات، أنه بنتوقع يكون more basicاللي فيه
+
+427
+00:38:03,100 --> 00:38:06,860
+زيادة الإلكترونات لأن ال basicity هي قصة
+
+428
+00:38:06,860 --> 00:38:09,980
+الإلكترونات، إيش اللي بيزيدها، واضح؟ اللي فيه
+
+429
+00:38:09,980 --> 00:38:13,740
+زيادة الإلكترونات، واضح؟ نفس الأشياء لو كنتوا
+
+430
+00:38:13,740 --> 00:38:16,980
+تاخدوها مثلا، لو أخدتوا ال etheramine، هاي زوج
+
+431
+00:38:16,980 --> 00:38:22,800
+إلكترونات، شايفينه؟ طيب، لو عملت chloroethelamine
+
+432
+00:38:24,060 --> 00:38:27,660
+هذا نفس زوج الإلكترونات لكن الكلور ماذا يعمل؟
+
+433
+00:38:27,660 --> 00:38:32,740
+بيسحب شوية من الإلكترونات إذا وين الإلكترونات أكتر
+
+434
+00:38:32,740 --> 00:38:37,600
+هتكون؟ في ال إيثالأمين ولا في الكلورو؟ إيثالأمين
+
+435
+00:38:37,600 --> 00:38:41,300
+في الإيثالأمين إذا هذا الإيثالأمين is more basic
+
+436
+00:38:41,300 --> 00:38:46,060
+فكأنه أنا قاعد بقول كلمة إن ال electron donating
+
+437
+00:38:46,060 --> 00:38:52,230
+groups المجموعات المعطية increaseبسيسيتي و ال
+
+438
+00:38:52,230 --> 00:38:56,850
+electron with drawing groups decrease basicity و
+
+439
+00:38:56,850 --> 00:39:01,430
+هذا كلام بسيط إن أنا عندي زوج electronic إذا حطيت
+
+440
+00:39:01,430 --> 00:39:04,990
+electron donating بزيد الكثافة الإلكترونية بصير
+
+441
+00:39:04,990 --> 00:39:10,070
+more basic إذا حطيت electron with drawing groups
+
+442
+00:39:10,070 --> 00:39:15,940
+بجلل الكثافة الإلكترونية بصيرless basic فوصفيا
+
+443
+00:39:15,940 --> 00:39:20,000
+العملية سهلة طبعا مش مطلوب مني ان انا اقعد احفظ
+
+444
+00:39:20,000 --> 00:39:24,980
+الجداول و الأرقام لكن مطلوب مني في ال basicity ان
+
+445
+00:39:24,980 --> 00:39:30,160
+اكون عارف أشياء كمبادئ عامة ان ال aliphatic amines
+
+446
+00:39:30,160 --> 00:39:35,480
+they are more basic than aromatic amines الآن سواء
+
+447
+00:39:35,480 --> 00:39:38,620
+على aliphatic amines او على aromatic amines اذا
+
+448
+00:39:38,620 --> 00:39:43,800
+حطيت مجموعات معطيةبتزيد القاعدية، وإذا حطيت
+
+449
+00:39:43,800 --> 00:39:48,360
+مجموعات ساحبة، بتقل القاعدية، واضح؟ هاي التلات
+
+450
+00:39:48,360 --> 00:39:51,860
+حاجات اللي بدي أقولها ألفاتك أمينs are more basic
+
+451
+00:39:51,860 --> 00:39:55,140
+than aromatic amines، electron donating groups
+
+452
+00:39:55,140 --> 00:40:00,720
+increase basicity، and electron withdrawing groups
+
+453
+00:40:00,720 --> 00:40:03,760
+decrease basicity، واضح؟
+
+454
+00:40:08,850 --> 00:40:12,430
+لأ ما هاد ال slide برضه على ال basicity و ال
+
+455
+00:40:12,430 --> 00:40:21,850
+acidity هاد
+
+456
+00:40:21,850 --> 00:40:28,430
+ال slide بتجيبلنا .. بتجيبلنا مثال عادة بيعملوا
+
+457
+00:40:28,430 --> 00:40:32,050
+تجربة في المختبر بعرفش إيه ممكن تعملوه برضه إنتوا
+
+458
+00:40:32,050 --> 00:40:38,260
+إذا أخدتوا المختبر أو لأ إنهم بياخدواالبارا مثل
+
+459
+00:40:38,260 --> 00:40:43,980
+أنيلين اللي هو البارا تولدين هذا والبارا نيترو
+
+460
+00:40:43,980 --> 00:40:51,360
+طولوين لاحظوا أنا عند مثل و مثل مجموعةأمينو
+
+461
+00:40:51,360 --> 00:40:58,700
+ومجموعة نيترو ممكن ان البعض يفكر ان النيترو جروب
+
+462
+00:40:58,700 --> 00:41:04,660
+basic من اي منطلق من منطلق ان تشوفه النيتروجين لكن
+
+463
+00:41:04,660 --> 00:41:10,500
+انتبهوا معي ان النيتروجين هذه تبعت مجموعة النيترو
+
+464
+00:41:10,500 --> 00:41:16,360
+ماعليهاش أزواج إلكترونات هي نيتروجين موجبةبمعنى
+
+465
+00:41:16,360 --> 00:41:19,420
+هذه النيتروجين تعطي الانيلين على العين والرأس
+
+466
+00:41:19,420 --> 00:41:23,180
+عليها زوج من الإلكترونات بس هذه لما بدنا نرسمها
+
+467
+00:41:23,180 --> 00:41:26,160
+حقيقة بترسم بهذا الشكل
+
+468
+00:41:32,930 --> 00:41:37,630
+وهنا O بتكون minus وهنا plus فالنيترو جينها دي
+
+469
+00:41:37,630 --> 00:41:41,670
+ماعليهاش إلكترونات النيترو كمجموعة بنرسمها بالشكل
+
+470
+00:41:41,670 --> 00:41:44,990
+اللي موجود عندكم بناء على ذلك لو بدأ أقول هذا
+
+471
+00:41:44,990 --> 00:41:48,750
+المركب اللي فيه ال amino ولا فيه ال nitro which is
+
+472
+00:41:48,750 --> 00:41:55,250
+more basicأكيد هذا اللي هو البارا طول يديك طيب لو
+
+473
+00:41:55,250 --> 00:41:59,170
+كان عندي خليط من المركبين مخلوطين مع بعض و بدي
+
+474
+00:41:59,170 --> 00:42:04,970
+طريقة كيميائية في المعمل اني افصلهم عن بعض واضح
+
+475
+00:42:04,970 --> 00:42:09,810
+ايش التجربة انه انا عندي اللي هو ال nitro مع ال
+
+476
+00:42:09,810 --> 00:42:14,290
+amino و بدي افصلهم طبعا ممكن ناس ممكن ناس منكوا
+
+477
+00:42:14,290 --> 00:42:20,250
+يقولوا ما هو احنا ليش في الأساس نخلطهمعشان في
+
+478
+00:42:20,250 --> 00:42:25,890
+الآخر نتغلب بفصلهم يعني لو من الاصل ما خلطناهم مش
+
+479
+00:42:25,890 --> 00:42:31,050
+بلزمناش تجربة اننا نفصلهم اه بس اتذكروا نقطة
+
+480
+00:42:31,050 --> 00:42:35,930
+اتذكروا نقطة انه انا هذا المركب اللي فيه ال amino
+
+481
+00:42:35,930 --> 00:42:40,920
+حضرته من هذامظبوط ولا لأ؟ قبل شوية احنا كنا
+
+482
+00:42:40,920 --> 00:42:44,880
+نقولكوا انه مركب الـ Nitro هذا بالـ hydrogenation
+
+483
+00:42:44,880 --> 00:42:48,620
+مع الـmetal بيعطينا الـ Amino الان فالاتنين
+
+484
+00:42:48,620 --> 00:42:53,040
+موجودين مع بعض ممكن التفاعل لا يصل الى النهاية
+
+485
+00:42:53,040 --> 00:42:58,300
+وبالتالي صار عنده متكون الـ Amino compound وصار
+
+486
+00:42:58,300 --> 00:43:03,720
+عنده الـ Nitroوالاتنين صاروا مخلوطين مع بعض كيف
+
+487
+00:43:03,720 --> 00:43:09,720
+ممكن افصل المركبين؟ بيقول الات لو اجينا .. ضفنا له
+
+488
+00:43:09,720 --> 00:43:17,420
+محمض HCl ال HCl هيتفاعل مع مين؟ بس مع ال basic مع
+
+489
+00:43:17,420 --> 00:43:21,580
+هذا مش هيتفاعل مع هذا بناء على ذلك هذا المركب اللي
+
+490
+00:43:21,580 --> 00:43:25,990
+هو ال Nitro Toluene هيظل زي ما هومش هيتفاعل مع ال
+
+491
+00:43:25,990 --> 00:43:31,550
+HCl بينما ال باراتوليدين هيتفاعل مع ال HCl هتصير
+
+492
+00:43:31,550 --> 00:43:40,350
+هذي N-H3+, النيتروجين هتاخد H+, N-H3+, و Cl-, اللي
+
+493
+00:43:40,350 --> 00:43:45,770
+هو ال chloride لاحظوا معنى ان هذا المركب صار plus
+
+494
+00:43:45,770 --> 00:43:51,730
+minus ايش يعني plus minus Salt ملح مش الأملح plus
+
+495
+00:43:51,730 --> 00:43:54,250
+minus و ال salt بيكون بيدوب
+
+496
+00:44:04,640 --> 00:44:10,740
+بناء على ذلك بنقدر نعمل عملية extraction نضيف
+
+497
+00:44:10,740 --> 00:44:15,820
+organic solvent وميّه هذا المُركّب وين بده يروح؟
+
+498
+00:44:15,820 --> 00:44:18,900
+على الميّه هذا بده يروح على ال organic solvent لو
+
+499
+00:44:18,900 --> 00:44:23,020
+افترضنا ال organic solvent إيثر بعدين إذا بخرنا ال
+
+500
+00:44:23,020 --> 00:44:27,470
+etherبيظل هذا المُركّب نقي طب هذا اللي ضال دايب في
+
+501
+00:44:27,470 --> 00:44:32,590
+الميّه .. بيضيف
+
+502
+00:44:32,590 --> 00:44:37,350
+نقاط NaOH لاحظوا الـ NaOH strong base بتروح بتسحب
+
+503
+00:44:37,350 --> 00:44:42,330
+الـ HCl اللي اتفاعل هنا بتتفاعل معه بتعطينا NaCl
+
+504
+00:44:42,330 --> 00:44:47,150
+زاد H2O وبرجع هذا ل organic بزامه رجع ل organic في
+
+505
+00:44:47,150 --> 00:44:52,770
+الميّه شو بيعمل؟ بترسبهو بيدوب في الميه لما يكون
+
+506
+00:44:52,770 --> 00:45:01,210
+Salt فإذا أنا نقطت نقط NaOH على الميه هتسحب منه ال
+
+507
+00:45:01,210 --> 00:45:05,330
+HCl هيرجع Organic وإذا ما رجع Organic بترسب كمادة
+
+508
+00:45:05,330 --> 00:45:11,530
+صلبة وبنعمله filtration واضح فالفكرة في فصل هدول
+
+509
+00:45:11,530 --> 00:45:15,990
+المركبين اللي هي الفكرة الأساسية أن هذا بتفعل as a
+
+510
+00:45:15,990 --> 00:45:18,950
+base هذا ما بتفعلش هذا ما بتفعل as a base بيعمل
+
+511
+00:45:18,950 --> 00:45:23,370
+عندكSalt هذا بيطلق organic، organic بنفصله
+
+512
+00:45:23,370 --> 00:45:27,270
+وبنبخره، طب هذا ال salt كيف بدنا نسترده؟ بنضيف
+
+513
+00:45:27,270 --> 00:45:32,050
+عليه Sodium Hydroxide بيرودي يتحول إلى ال aniline
+
+514
+00:45:32,050 --> 00:45:37,110
+و بنعمله filtration و بنفصله على أي حال إذا هذه
+
+515
+00:45:37,110 --> 00:45:44,430
+مرت عليكوا تجربة في الجزء العملي بإمكانكوا تشوفوا
+
+516
+00:45:44,430 --> 00:45:50,390
+بالمناسبة ال organic العملي نازل بالصيفنازل بالصيف
+
+517
+00:45:50,390 --> 00:45:53,630
+يعني الناس اللي عندهم فضاوة أنا شخصيا بنصحهم
+
+518
+00:45:53,630 --> 00:45:58,170
+ياخدوه بالصيف لإنه بالفصل الأول أعدادي كبيرة و
+
+519
+00:45:58,170 --> 00:46:02,230
+برضه انتوا عندكوا شغلكوا بالفصل الأول فال organic
+
+520
+00:46:02,230 --> 00:46:11,030
+العملي نازل بالصيف و ممكنكم تاخدوه على أي حال ابنه
+
+521
+00:46:11,030 --> 00:46:13,110
+و جفهان العملي
+
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..80e1c23ed8c060ea576f233af62177e3eb9e4c87
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/r6qdaE5Oo4U_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2846, "start": 15.18, "end": 28.46, "text": "بسم الله الرحمن الرحيم بنكمل اليوم ان شاء الله في موضوع ال amends المحاضرة الماضية أخدنا تسمية ال amends و أخدنا بشكل عام طريقتين", "tokens": [3555, 38251, 21984, 34892, 5016, 27842, 34892, 5016, 32640, 44945, 24793, 1211, 45595, 20498, 16472, 13412, 16606, 21984, 8978, 3714, 2407, 11242, 45367, 2423, 669, 2581, 9673, 5016, 46958, 25720, 9673, 46958, 10632, 5551, 9778, 3215, 8315, 6055, 38251, 10632, 2423, 669, 2581, 4032, 5551, 9778, 3215, 8315, 4724, 8592, 28820, 6225, 10943, 23032, 16572, 38149, 9957], "avg_logprob": -0.0888335108757019, "compression_ratio": 1.60431654676259, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 15.180000000000003, "end": 15.96, "word": "بسم", "probability": 0.871826171875}, {"start": 15.96, "end": 16.14, "word": " الله", "probability": 0.974609375}, {"start": 16.14, "end": 16.46, "word": " الرحمن", "probability": 0.9567057291666666}, {"start": 16.46, "end": 16.82, "word": " الرحيم", "probability": 0.990234375}, {"start": 16.82, "end": 18.52, "word": " بنكمل", "probability": 0.861328125}, {"start": 18.52, "end": 18.84, "word": " اليوم", "probability": 0.922607421875}, {"start": 18.84, "end": 19.02, "word": " ان", "probability": 0.6533203125}, {"start": 19.02, "end": 19.22, "word": " شاء", "probability": 0.98046875}, {"start": 19.22, "end": 19.28, "word": " الله", "probability": 0.96630859375}, {"start": 19.28, "end": 19.6, "word": " في", "probability": 0.90966796875}, {"start": 19.6, "end": 20.28, "word": " موضوع", "probability": 0.9969482421875}, {"start": 20.28, "end": 20.46, "word": " ال", "probability": 0.98486328125}, {"start": 20.46, "end": 21.06, "word": " amends", "probability": 0.388427734375}, {"start": 21.06, "end": 23.14, "word": " المحاضرة", "probability": 0.956787109375}, {"start": 23.14, "end": 23.82, "word": " الماضية", "probability": 0.9933268229166666}, {"start": 23.82, "end": 24.58, "word": " أخدنا", "probability": 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"word": " ال", "probability": 0.912109375}, {"start": 500.41, "end": 500.71, "word": " boiling", "probability": 0.908203125}, {"start": 500.71, "end": 501.09, "word": " point", "probability": 0.98046875}, {"start": 501.09, "end": 501.57, "word": " تبعته", "probability": 0.76019287109375}, {"start": 501.57, "end": 501.99, "word": " سبع", "probability": 0.78759765625}, {"start": 501.99, "end": 502.57, "word": " درجات", "probability": 0.97021484375}, {"start": 502.57, "end": 503.07, "word": " تقريبا", "probability": 0.98212890625}, {"start": 503.07, "end": 503.45, "word": " بينما", "probability": 0.90087890625}, {"start": 503.45, "end": 503.59, "word": " ال", "probability": 0.91259765625}, {"start": 503.59, "end": 503.87, "word": " boiling", "probability": 0.9443359375}, {"start": 503.87, "end": 504.27, "word": " point", "probability": 0.98291015625}, {"start": 504.27, "end": 504.61, "word": " هنا", "probability": 0.89599609375}, {"start": 504.61, "end": 505.55, "word": " تلت", "probability": 0.9456380208333334}, {"start": 505.55, "end": 506.21, "word": " درجات", "probability": 0.9949544270833334}, {"start": 506.21, "end": 506.79, "word": " ليش", "probability": 0.74462890625}, {"start": 506.79, "end": 506.95, "word": " ال", "probability": 0.84033203125}, {"start": 506.95, "end": 508.23, "word": " trimethylamine", "probability": 0.756201171875}, {"start": 508.23, "end": 508.75, "word": " كان", "probability": 0.97021484375}, {"start": 508.75, "end": 509.39, "word": " أقل", "probability": 0.95703125}, {"start": 509.39, "end": 509.79, "word": " من", "probability": 0.9873046875}, {"start": 509.79, "end": 510.99, "word": " ال", "probability": 0.8515625}, {"start": 510.99, "end": 514.65, "word": " diamethylamine", "probability": 0.6815673828125}, {"start": 514.65, "end": 515.69, "word": " لأن", "probability": 0.787109375}, {"start": 515.69, "end": 515.95, "word": " ال", "probability": 0.11224365234375}, {"start": 515.95, "end": 517.09, "word": " trimethylamine", 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عام هو بيكون غاز يلاحظوا minus 6.3 و الغازات بتقدروا تتذكروا العلاقة الأساسية بينها أنه تعامل كأنها جزيئات منفصلة لأنه خفيف كتير و بحكومها ال kinetic theory جزيئات بتتحرك و بتتصادم في جدار الإناء لكن المقارنة هنا واضحة بين الداي ميثل أمين", "tokens": [9566, 3555, 3615, 995, 14111, 9673, 1829, 12984, 1211, 5551, 2304, 9957, 4724, 1829, 25957, 1211, 12697, 28824, 44381, 8978, 13412, 28820, 6225, 10943, 31439, 4724, 1829, 30544, 32771, 31377, 7251, 15040, 5016, 19913, 14407, 3175, 1386, 13, 18, 4032, 6024, 118, 31377, 9307, 39894, 28543, 2288, 14407, 6055, 2655, 8848, 37983, 14407, 18863, 15040, 28671, 16247, 3794, 32277, 10632, 49374, 11296, 14739, 3224, 37279, 10943, 1211, 9122, 33456, 11296, 10874, 11622, 1829, 19986, 9307, 9154, 5172, 36520, 3660, 5296, 33456, 3224, 16490, 5172, 33911, 9122, 2655, 13546, 4032, 4724, 5016, 4117, 20498, 11296, 2423, 27135, 5261, 10874, 11622, 1829, 19986, 9307, 39894, 2655, 5016, 31747, 4032, 39894, 2655, 9381, 18513, 2304, 8978, 10874, 3215, 9640, 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{"start": 551.89, "end": 552.69, "word": " المقارنة", "probability": 0.9884765625}, {"start": 552.69, "end": 552.89, "word": " هنا", "probability": 0.124267578125}, {"start": 552.89, "end": 553.39, "word": " واضحة", "probability": 0.9766845703125}, {"start": 553.39, "end": 553.63, "word": " بين", "probability": 0.93505859375}, {"start": 553.63, "end": 553.99, "word": " الداي", "probability": 0.563232421875}, {"start": 553.99, "end": 554.35, "word": " ميثل", "probability": 0.8614501953125}, {"start": 554.35, "end": 554.81, "word": " أمين", "probability": 0.96630859375}], "temperature": 1.0}, {"id": 25, "seek": 56816, "start": 555.62, "end": 568.16, "text": "والـ Tri-methylamine أعلى في الـ boiling point بسبب انه عنده إمكانية hydrogen bonding وهذه الإمكانية غير موجودة في الـ Tri-methylamine", "tokens": [2407, 6027, 39184, 10931, 12, 76, 3293, 88, 4326, 533, 5551, 3615, 23942, 8978, 2423, 39184, 16208, 935, 4724, 35457, 3555, 16472, 3224, 43242, 3224, 11933, 2304, 41361, 10632, 12697, 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HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2SO4 HRO3H2", "tokens": [3555, 22488, 9957, 11004, 23032, 3555, 3615, 995, 34105, 8717, 36081, 16572, 8592, 1863, 19460, 46, 18, 39, 17, 17188, 19, 34105, 11004, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 39, 17, 17188, 19, 19460, 46, 18, 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تعمللنا بنزين مع OH minus ليش لان هتحط minus على minus هذا الكلام لا يجوز الفينول لا يحضر مباشرة من البنزين", "tokens": [2304, 8592, 20449, 39648, 16472, 36764, 24401, 3660, 6055, 1829, 7435, 1829, 6055, 25957, 1211, 1211, 8315, 44945, 11622, 9957, 20449, 13931, 3175, 32239, 8592, 5296, 7649, 8032, 2655, 5016, 9566, 3175, 15844, 3175, 23758, 2423, 28820, 10943, 20193, 7251, 7435, 2407, 11622, 27188, 9957, 12610, 20193, 7251, 5016, 11242, 2288, 3714, 3555, 33599, 25720, 9154, 29739, 1863, 11622, 9957], "avg_logprob": -0.17763832064925647, "compression_ratio": 1.5138888888888888, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 998.75, "end": 999.07, "word": "مش", "probability": 0.84619140625}, {"start": 999.07, "end": 999.55, "word": " معقول", "probability": 0.9892578125}, {"start": 999.55, "end": 999.73, "word": " ان", "probability": 0.409912109375}, {"start": 999.73, "end": 1000.15, "word": " واحدة", "probability": 0.9324544270833334}, {"start": 1000.15, "end": 1000.45, 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مشاكل واضح؟ وهذه بيكون تكملتها زائد طبعا HPR", "tokens": [10721, 2304, 9957, 47525, 11536, 37893, 995, 28820, 37495, 22653, 30767, 1829, 39896, 4117, 9673, 3615, 18513, 37977, 39894, 30544, 1975, 1829, 8592, 47525, 11536, 37893, 995, 28820, 4032, 46958, 5016, 22807, 37037, 24192, 4724, 1829, 30544, 6055, 24793, 1211, 2655, 11296, 30767, 16373, 3215, 23032, 3555, 3615, 995, 12557, 49], "avg_logprob": -0.2743389360033549, "compression_ratio": 1.4453781512605042, "no_speech_prob": 9.5367431640625e-07, "words": [{"start": 1329.27, "end": 1329.89, "word": "أمين", "probability": 0.6947428385416666}, {"start": 1329.89, "end": 1330.29, "word": " بدون", "probability": 0.899658203125}, {"start": 1330.29, "end": 1330.89, "word": " مشاكل", "probability": 0.9806315104166666}, {"start": 1330.89, "end": 1331.13, "word": " يعني", "probability": 0.5870361328125}, {"start": 1331.13, "end": 1331.41, "word": " زي", "probability": 0.68603515625}, {"start": 1331.41, "end": 1331.67, "word": " هيك", 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بياخد", "tokens": [6027, 28814, 23275, 2655, 2288, 11536, 9307, 35525, 8848, 23275, 7251, 10859, 3615, 10943, 1211, 14407, 15844, 36145, 16095, 17949, 4032, 41185, 9673, 10859, 31747, 11703, 3555, 9307, 2423, 39184, 16296, 13672, 1829, 8978, 11296, 2423, 39184, 45, 270, 7747, 29538, 20666, 8848, 9307, 15844, 11331, 1211, 4587, 9307, 4724, 1829, 38251, 2407, 11296, 2423, 39184, 9171, 74, 10334, 3742, 4032, 27842, 29538, 2423, 39184, 9171, 74, 10334, 3742, 20666, 2304, 8315, 35457, 3660, 30767, 1829, 23758, 9673, 10859, 31747, 11703, 3555, 28239, 1829, 4117, 35473, 9957, 4724, 35457, 3555, 49610, 23328, 2423, 39184, 45, 270, 7747, 34105, 13672, 1829, 5296, 11296, 30767, 29245, 11933, 23275, 2655, 2288, 11536, 9307, 4032, 6027, 39184, 45, 270, 7747, 34105, 13672, 1829, 5296, 11296, 30767, 29245, 11933, 23275, 2655, 2288, 11536, 9307, 4724, 1829, 39648, 14407, 23758, 3714, 10859, 31747, 11703, 3555, 12174, 995, 22488, 1829, 4724, 1829, 47283, 3215], "avg_logprob": -0.1581503413617611, 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{"start": 1562.75, "end": 1563.73, "word": " والـNitrogen", "probability": 0.7506510416666666}, {"start": 1563.73, "end": 1564.01, "word": " هنا", "probability": 0.95947265625}, {"start": 1564.01, "end": 1564.19, "word": " اللي", "probability": 0.989990234375}, {"start": 1564.19, "end": 1564.43, "word": " لها", "probability": 0.97119140625}, {"start": 1564.43, "end": 1564.71, "word": " زوج", "probability": 0.98193359375}, {"start": 1564.71, "end": 1566.47, "word": " إلكترونات", "probability": 0.91162109375}, {"start": 1566.47, "end": 1567.03, "word": " بيقولوا", "probability": 0.900146484375}, {"start": 1567.03, "end": 1567.19, "word": " هذا", "probability": 0.904296875}, {"start": 1567.19, "end": 1567.73, "word": " مُركّب", "probability": 0.96455078125}, {"start": 1567.73, "end": 1568.35, "word": " قاعدي", "probability": 0.8817138671875}, {"start": 1568.35, "end": 1569.09, "word": " بياخد", "probability": 0.9390869140625}], "temperature": 1.0}, {"id": 67, "seek": 159686, "start": 1569.56, "end": 1596.86, "text": "الاسم العائلة العام في المراكبات أو المنتجات الطبيعية بنسمي احنا ايش ال Calorie فالمهم في ال Amines حقيقة هو زوج الإلكترونات هذا زوج الإلكترونات بيخلي ال Amines بشكل عام مش دائما بالمطلق بشكل عام يتفاعلوا as bases وقتاش ممكن يتفاعلوا", "tokens": [6027, 32277, 2304, 18863, 16373, 37977, 18863, 10943, 8978, 9673, 23557, 4117, 3555, 9307, 34051, 9673, 29399, 7435, 9307, 41950, 21292, 3615, 10632, 44945, 38251, 1829, 1975, 5016, 8315, 1975, 1829, 8592, 2423, 3511, 17473, 6156, 45340, 16095, 8978, 2423, 2012, 1652, 11331, 38436, 28671, 31439, 30767, 29245, 33688, 23275, 2655, 2288, 11536, 9307, 23758, 30767, 29245, 33688, 23275, 2655, 2288, 11536, 9307, 4724, 1829, 9778, 20292, 2423, 2012, 1652, 4724, 8592, 28820, 6225, 10943, 37893, 11778, 16373, 15042, 20666, 2304, 9566, 1211, 4587, 4724, 8592, 28820, 6225, 10943, 7251, 2655, 5172, 995, 30241, 14407, 382, 17949, 4032, 38149, 33599, 3714, 43020, 7251, 2655, 5172, 995, 30241, 14407], "avg_logprob": 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ايش", "probability": 0.8458658854166666}, {"start": 1575.68, "end": 1576.48, "word": " ال", "probability": 0.63037109375}, {"start": 1576.48, "end": 1577.0, "word": " Calorie", "probability": 0.469329833984375}, {"start": 1577.0, "end": 1578.48, "word": " فالمهم", "probability": 0.9293619791666666}, {"start": 1578.48, "end": 1578.82, "word": " في", "probability": 0.958984375}, {"start": 1578.82, "end": 1579.08, "word": " ال", "probability": 0.93408203125}, {"start": 1579.08, "end": 1579.56, "word": " Amines", "probability": 0.66552734375}, {"start": 1579.56, "end": 1580.3, "word": " حقيقة", "probability": 0.8678385416666666}, {"start": 1580.3, "end": 1581.2, "word": " هو", "probability": 0.96240234375}, {"start": 1581.2, "end": 1582.6, "word": " زوج", "probability": 0.950439453125}, {"start": 1582.6, "end": 1583.72, "word": " الإلكترونات", "probability": 0.87109375}, {"start": 1583.72, "end": 1583.96, "word": " هذا", "probability": 0.5234375}, {"start": 1583.96, "end": 1584.28, "word": 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"text": "إذا بنجيب base أقوى منهم واضح؟ ليش؟ زي ما بتقول أهو فوق كل ذي علم عليم يعني أي حامض ممكن أحاوله ل base ب .. بإيش؟ بتجيب حامض أقوى منه و ال base ممكن أخليها تبين كإنها acid بتجيب قاعدة أقوى منها بتصيريا كإنها acid و القاعدة الأقوى .. أه لكن بشكل عام ال amines و ال ammonia they are considered as", "tokens": [28814, 15730, 44945, 7435, 1829, 3555, 3096, 5551, 4587, 2407, 7578, 9154, 16095, 4032, 46958, 5016, 22807, 32239, 8592, 22807, 30767, 1829, 19446, 39894, 39648, 5551, 3224, 2407, 6156, 30543, 28242, 29910, 1829, 11203, 2304, 11203, 32640, 37495, 22653, 36632, 11331, 10943, 11242, 3714, 43020, 5551, 5016, 995, 12610, 3224, 5296, 3096, 4724, 4386, 4724, 28814, 1829, 8592, 22807, 39894, 7435, 1829, 3555, 11331, 10943, 11242, 5551, 4587, 2407, 7578, 9154, 3224, 4032, 2423, 3096, 3714, 43020, 5551, 9778, 20292, 11296, 6055, 3555, 9957, 9122, 28814, 1863, 11296, 8258, 39894, 7435, 1829, 3555, 12174, 995, 22488, 3660, 5551, 4587, 2407, 7578, 9154, 11296, 39894, 9381, 13546, 25528, 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{"start": 2150.59, "end": 2150.87, "word": " resonance", "probability": 0.81884765625}, {"start": 2150.87, "end": 2151.47, "word": " structure", "probability": 0.8134765625}, {"start": 2151.47, "end": 2151.73, "word": " شو", "probability": 0.759033203125}, {"start": 2151.73, "end": 2152.03, "word": " صارت", "probability": 0.8697916666666666}, {"start": 2152.03, "end": 2152.15, "word": " ال", "probability": 0.61865234375}, {"start": 2152.15, "end": 2153.51, "word": " nitrogen؟", "probability": 0.641357421875}, {"start": 2153.51, "end": 2154.07, "word": " positive،", "probability": 0.64599609375}, {"start": 2154.07, "end": 2154.43, "word": " بطل", "probability": 0.9521484375}, {"start": 2154.43, "end": 2154.75, "word": " عليها", "probability": 0.988037109375}, {"start": 2154.75, "end": 2155.01, "word": " زوج", "probability": 0.989990234375}, {"start": 2155.01, "end": 2156.95, "word": " الإلكترونات،", "probability": 0.9190150669642857}, {"start": 2156.95, "end": 2158.07, "word": " واضح؟", "probability": 0.9713134765625}, {"start": 2158.07, "end": 2158.95, "word": " فلو", "probability": 0.9638671875}, {"start": 2158.95, "end": 2159.23, "word": " بدنا", "probability": 0.824951171875}, {"start": 2159.23, "end": 2159.47, "word": " نيجي", "probability": 0.968017578125}, {"start": 2159.47, "end": 2159.91, "word": " نسأل", "probability": 0.9825439453125}, {"start": 2159.91, "end": 2160.65, "word": " كقاعدة", "probability": 0.97451171875}, {"start": 2160.65, "end": 2161.11, "word": " عامة", "probability": 0.99853515625}], "temperature": 1.0}, {"id": 93, "seek": 219153, "start": 2162.41, "end": 2191.53, "text": "وهي أكثر أساسية ألفاتيك أو أروماتيك أمين الجواب ألفاتيك أمين بسبب ريزونانس الألفاتيك أمين هم أعلى والسبب أن الأروماتيك أمين بيعملوا ريزونانس الألفاتيك أمين بيعملوش ريزونانس هذه النقطة الأولى الآن لو رجعنا شوية صغيرة للجدول وعملنا كمان مقارنة", "tokens": [2407, 3224, 1829, 5551, 4117, 49115, 5551, 3794, 32277, 10632, 5551, 46538, 9307, 1829, 4117, 34051, 5551, 2288, 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احفظ الجداول و الأرقام لكن مطلوب مني في ال basicity ان اكون عارف أشياء كمبادئ عامة ان ال aliphatic amines they are more basic than aromatic amines الآن سواء على aliphatic amines او على aromatic amines اذا حطيت مجموعات معطية", "tokens": [1832, 3875, 6156, 2407, 9381, 5172, 25528, 18863, 42213, 10632, 8608, 3224, 37977, 23032, 3555, 3615, 995, 37893, 3714, 9566, 1211, 37746, 9154, 1829, 16472, 1975, 8315, 1975, 4587, 22488, 1975, 5016, 5172, 19913, 25724, 28259, 12610, 4032, 16247, 2288, 4587, 10943, 44381, 3714, 9566, 1211, 37746, 9154, 1829, 8978, 2423, 3875, 507, 16472, 1975, 30544, 6225, 9640, 5172, 5551, 8592, 1829, 16606, 9122, 2304, 3555, 18513, 19986, 6225, 10943, 3660, 16472, 2423, 419, 24595, 2399, 669, 1652, 436, 366, 544, 3875, 813, 45831, 669, 1652, 6024, 48506, 8608, 2407, 16606, 15844, 419, 24595, 2399, 669, 1652, 1975, 2407, 15844, 45831, 669, 1652, 1975, 15730, 11331, 9566, 36081, 3714, 7435, 2304, 45367, 9307, 20449, 9566, 10632], "avg_logprob": -0.16212606531941992, 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ممكن افصل المركبين؟ بيقول الات لو اجينا .. ضفنا له محمض HCl ال HCl هيتفاعل مع مين؟ بس مع ال basic مع هذا مش هيتفاعل مع هذا بناء على ذلك هذا المركب اللي هو ال Nitro Toluene هيظل زي ما هو", "tokens": [2407, 6027, 9307, 1863, 9957, 20328, 9640, 14407, 3714, 9778, 1211, 2407, 9566, 9957, 20449, 45030, 11242, 9122, 33911, 3714, 43020, 1975, 5172, 36520, 9673, 31747, 3555, 9957, 22807, 4724, 1829, 39648, 2423, 9307, 45164, 1975, 7435, 1829, 8315, 4386, 48812, 5172, 8315, 46740, 3714, 35571, 11242, 389, 9966, 2423, 389, 9966, 39896, 2655, 5172, 995, 30241, 20449, 3714, 9957, 22807, 4724, 3794, 20449, 2423, 3875, 20449, 23758, 37893, 39896, 2655, 5172, 995, 30241, 20449, 23758, 44945, 16606, 15844, 29910, 23275, 23758, 9673, 31747, 3555, 13672, 1829, 31439, 2423, 37942, 340, 21402, 84, 1450, 39896, 19913, 1211, 30767, 1829, 19446, 31439], "avg_logprob": -0.2959558937479468, "compression_ratio": 1.6757990867579908, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 2580.88, "end": 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new file mode 100644
index 0000000000000000000000000000000000000000..077020e59cdecbce4f6450aa076d970bdb26ac63
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/sCPLeVK9zQ0_raw.json
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"text": "ممكن انا اضيف مثلا الهيدروجين الهيدروجين جزء H single bond H اتطلع عليه بنفس المنطق هل يا ترى هذا الهيدروجين متماثل ولا غير متماثل اذا الهيدروجين متماثل ممكن اضيف انا جزء كلورين Cl2 Cl single bond", "tokens": [2304, 43020, 1975, 8315, 1975, 11242, 33911, 50113, 15040, 2423, 3224, 25708, 2288, 29245, 9957, 2423, 3224, 25708, 2288, 29245, 9957, 10874, 11622, 38207, 389, 2167, 6086, 389, 1975, 2655, 9566, 1211, 3615, 47356, 44945, 36178, 9673, 1863, 9566, 4587, 8032, 1211, 35186, 6055, 2288, 7578, 23758, 2423, 3224, 25708, 2288, 29245, 9957, 44650, 2304, 5718, 104, 1211, 49429, 32771, 13546, 44650, 2304, 5718, 104, 1211, 1975, 15730, 2423, 3224, 25708, 2288, 29245, 9957, 44650, 2304, 5718, 104, 1211, 3714, 43020, 1975, 11242, 33911, 1975, 8315, 10874, 11622, 38207, 9122, 1211, 13063, 9957, 2033, 17, 2033, 2167, 6086], "avg_logprob": -0.16256313492553404, "compression_ratio": 1.907514450867052, "no_speech_prob": 6.9141387939453125e-06, "words": [{"start": 290.94, "end": 291.52, "word": "ممكن", "probability": 0.86962890625}, {"start": 291.52, "end": 291.84, "word": " انا", "probability": 0.47845458984375}, {"start": 291.84, "end": 292.38, "word": " اضيف", "probability": 0.9671223958333334}, {"start": 292.38, "end": 292.86, "word": " مثلا", "probability": 0.883544921875}, {"start": 292.86, "end": 293.88, "word": " الهيدروجين", "probability": 0.8669026692708334}, {"start": 293.88, "end": 295.02, "word": " الهيدروجين", "probability": 0.9072265625}, {"start": 295.02, "end": 295.56, "word": " جزء", "probability": 0.85693359375}, {"start": 295.56, "end": 296.48, "word": " H", "probability": 0.71435546875}, {"start": 296.48, "end": 297.16, "word": " single", "probability": 0.43115234375}, {"start": 297.16, "end": 297.64, "word": " bond", "probability": 0.896484375}, {"start": 297.64, "end": 298.18, "word": " H", "probability": 0.939453125}, {"start": 298.18, "end": 299.9, "word": " اتطلع", "probability": 0.7734375}, {"start": 299.9, "end": 300.1, "word": " عليه", 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{"start": 306.86, "end": 307.92, "word": " الهيدروجين", "probability": 0.9607747395833334}, {"start": 307.92, "end": 309.68, "word": " متماثل", "probability": 0.92685546875}, {"start": 309.68, "end": 310.24, "word": " ممكن", "probability": 0.9736328125}, {"start": 310.24, "end": 310.8, "word": " اضيف", "probability": 0.9641927083333334}, {"start": 310.8, "end": 311.3, "word": " انا", "probability": 0.76416015625}, {"start": 311.3, "end": 311.8, "word": " جزء", "probability": 0.9765625}, {"start": 311.8, "end": 312.5, "word": " كلورين", "probability": 0.834228515625}, {"start": 312.5, "end": 314.14, "word": " Cl2", "probability": 0.61376953125}, {"start": 314.14, "end": 315.04, "word": " Cl", "probability": 0.73046875}, {"start": 315.04, "end": 316.26, "word": " single", "probability": 0.76513671875}, {"start": 316.26, "end": 316.76, "word": " bond", "probability": 0.94677734375}], "temperature": 1.0}, {"id": 13, "seek": 33899, "start": 317.15, "end": 338.99, "text": "الـ HCL ممكن اضيف الـ HCL ممكن اضيف الـ HCL ممكن اضيف الـ HCL", "tokens": [6027, 39184, 389, 22458, 3714, 43020, 1975, 11242, 33911, 2423, 39184, 389, 22458, 3714, 43020, 1975, 11242, 33911, 2423, 39184, 389, 22458, 3714, 43020, 1975, 11242, 33911, 2423, 39184, 389, 22458], "avg_logprob": -0.5048828218132257, "compression_ratio": 2.425, "no_speech_prob": 1.8477439880371094e-06, "words": [{"start": 317.15, "end": 318.45, "word": "الـ", "probability": 0.533203125}, {"start": 318.45, "end": 318.71, "word": " HCL", "probability": 0.265472412109375}, {"start": 318.71, "end": 323.21, "word": " ممكن", "probability": 0.5111083984375}, {"start": 323.21, "end": 325.87, "word": " اضيف", "probability": 0.8125}, {"start": 325.87, "end": 326.07, "word": " الـ", "probability": 0.5989990234375}, {"start": 326.07, "end": 329.75, "word": " HCL", "probability": 0.712646484375}, {"start": 329.75, "end": 335.19, "word": " ممكن", "probability": 0.51611328125}, {"start": 335.19, "end": 335.19, "word": " اضيف", "probability": 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"compression_ratio": 1.4782608695652173, "no_speech_prob": 5.364418029785156e-07, "words": [{"start": 345.8, "end": 346.88, "word": "ممكن", "probability": 0.51763916015625}, {"start": 346.88, "end": 347.52, "word": " اضيف", "probability": 0.6580403645833334}, {"start": 347.52, "end": 348.76, "word": " الميه", "probability": 0.66015625}, {"start": 348.76, "end": 349.26, "word": " الميه", "probability": 0.66534423828125}, {"start": 349.26, "end": 349.42, "word": " لما", "probability": 0.51171875}, {"start": 349.42, "end": 349.84, "word": " بتضيف", "probability": 0.763427734375}, {"start": 349.84, "end": 350.22, "word": " بتضيف", "probability": 0.8199869791666666}, {"start": 350.22, "end": 350.74, "word": " كجزء", "probability": 0.751220703125}, {"start": 350.74, "end": 351.0, "word": " اين", "probability": 0.562744140625}, {"start": 351.0, "end": 351.7, "word": " H", "probability": 0.35888671875}, {"start": 351.7, "end": 353.18, "word": " جزء", "probability": 0.9070638020833334}, 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"word": " ال", "probability": 0.701171875}, {"start": 386.06, "end": 386.76, "word": " reagent", "probability": 0.975830078125}, {"start": 386.76, "end": 387.4, "word": " can", "probability": 0.95703125}, {"start": 387.4, "end": 387.74, "word": " be", "probability": 0.96923828125}], "temperature": 1.0}, {"id": 16, "seek": 39893, "start": 390.17, "end": 398.93, "text": "الان ممكن اضيف simetrical reagent على simetrical alkene زي هيك", "tokens": [6027, 7649, 3714, 43020, 1975, 11242, 33911, 1034, 32283, 26949, 317, 15844, 1034, 32283, 37688, 1450, 30767, 1829, 39896, 4117], "avg_logprob": -0.5543154761904762, "compression_ratio": 1.0379746835443038, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 390.1700000000001, "end": 391.57000000000005, "word": "الان", "probability": 0.49951171875}, {"start": 391.57000000000005, "end": 392.97, "word": " ممكن", "probability": 0.7220458984375}, {"start": 392.97, "end": 394.33, "word": " اضيف", "probability": 0.888671875}, {"start": 394.33, 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لكم", "probability": 0.61181640625}, {"start": 421.44, "end": 422.64, "word": " product", "probability": 0.431884765625}, {"start": 422.64, "end": 423.98, "word": " كم", "probability": 0.724365234375}, {"start": 423.98, "end": 424.84, "word": " جزيء", "probability": 0.8514404296875}], "temperature": 1.0}, {"id": 18, "seek": 45433, "start": 425.47, "end": 454.33, "text": "واحد واضح اذا لو احنا بدنا نحاول يعني نعمل ملخص صغير نضيع هذا شوية نعمل ملخص صغير يعني بدنا نتخيل ان احنا عندنا ال keen و في عندنا reagent لما ال keen يكون symmetric و ال reagent يكون symmetric هكا product فيطلع عندنا", "tokens": [14407, 24401, 4032, 46958, 5016, 1975, 15730, 45164, 1975, 5016, 8315, 47525, 8315, 8717, 5016, 995, 12610, 37495, 22653, 8717, 25957, 1211, 3714, 1211, 9778, 9381, 20328, 17082, 13546, 8717, 11242, 40228, 23758, 13412, 2407, 10632, 8717, 25957, 1211, 3714, 1211, 9778, 9381, 20328, 17082, 13546, 37495, 22653, 47525, 8315, 8717, 2655, 9778, 26895, 16472, 1975, 5016, 8315, 43242, 8315, 2423, 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product او احتمال واحد طيب لو اخدت هذا ال reactant السيمتريك و قلت بدي افعله على البروبين", "tokens": [1211, 15042, 7251, 30544, 2423, 2423, 4117, 9957, 8608, 32640, 2655, 16572, 4117, 4032, 2423, 4515, 394, 8608, 32640, 2655, 16572, 4117, 43242, 3224, 1674, 1975, 2407, 1975, 33753, 2304, 6027, 36764, 24401, 23032, 1829, 3555, 45164, 1975, 9778, 3215, 2655, 23758, 2423, 4515, 394, 21136, 32640, 2655, 16572, 4117, 4032, 12174, 1211, 2655, 4724, 16254, 1975, 5172, 30241, 3224, 15844, 2423, 26890, 37746, 9957], "avg_logprob": -0.355587127533826, "compression_ratio": 1.6433566433566433, "no_speech_prob": 1.7285346984863281e-06, "words": [{"start": 458.53999999999996, "end": 459.46, "word": "لما", "probability": 0.12432861328125}, {"start": 459.46, "end": 459.74, "word": " يكون", "probability": 0.873046875}, {"start": 459.74, "end": 459.9, "word": " ال", "probability": 0.88330078125}, {"start": 459.9, "end": 460.54, "word": " الكين", "probability": 0.5270182291666666}, {"start": 460.54, 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تورا لما بدي اضيف الهيدروجين بهذا الشكل تيجي اتشان و اتشان، هيفرق انه هيك اضيفه ولا هيك ولا حد؟ اذا برضه هيطلع ناتج واحد فإضافة ال symmetrical reagent على ال unsymmetrical alkene برضه بيطلعلي إيش؟ one product", "tokens": [2407, 1975, 5016, 8315, 1975, 2655, 5172, 4587, 8315, 16472, 2423, 26890, 2407, 21292, 1863, 307, 2693, 32497, 17475, 8032, 1211, 35186, 6055, 13063, 995, 5296, 15042, 4724, 16254, 1975, 11242, 33911, 2423, 3224, 25708, 2288, 29245, 9957, 39627, 15730, 25124, 28820, 6055, 1829, 7435, 1829, 1975, 2655, 8592, 7649, 4032, 1975, 2655, 8592, 7649, 12399, 39896, 5172, 2288, 4587, 16472, 3224, 39896, 4117, 1975, 11242, 33911, 3224, 49429, 39896, 4117, 49429, 11331, 3215, 22807, 1975, 15730, 4724, 43042, 3224, 39896, 9566, 1211, 3615, 8717, 9307, 7435, 36764, 24401, 6156, 28814, 11242, 31845, 3660, 2423, 40360, 26949, 317, 15844, 2423, 2693, 32497, 32283, 37688, 1450, 4724, 43042, 3224, 4724, 1829, 9566, 1211, 3615, 20292, 11933, 1829, 8592, 22807, 472, 1674], "avg_logprob": 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"end": 518.31, "text": "طب ممكن نفكر نضيف unsymmetrical reagent زي ال HCl على symmetrical alkene بده احط HCl احط هنا H وهنا Cl ولا هنا H وهنا Cl؟", "tokens": [9566, 3555, 3714, 43020, 8717, 5172, 37983, 8717, 11242, 33911, 2693, 32497, 32283, 26949, 317, 30767, 1829, 2423, 389, 9966, 15844, 40360, 37688, 1450, 47525, 3224, 1975, 5016, 9566, 389, 9966, 1975, 5016, 9566, 34105, 389, 37037, 8315, 2033, 49429, 34105, 389, 37037, 8315, 2033, 22807], "avg_logprob": -0.33643617021276595, "compression_ratio": 1.3203125, "no_speech_prob": 1.7881393432617188e-07, "words": [{"start": 502.69, "end": 502.97, "word": "طب", "probability": 0.44140625}, {"start": 502.97, "end": 503.27, "word": " ممكن", "probability": 0.981201171875}, {"start": 503.27, "end": 503.81, "word": " نفكر", "probability": 0.9446614583333334}, {"start": 503.81, "end": 504.47, "word": " نضيف", "probability": 0.88330078125}, {"start": 504.47, "end": 507.09, "word": " unsymmetrical", "probability": 0.6952311197916666}, {"start": 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"word": " عندكوا", "probability": 0.8347981770833334}, {"start": 523.49, "end": 523.55, "word": " ع", "probability": 0.255126953125}, {"start": 523.55, "end": 523.89, "word": " الجهة", "probability": 0.822265625}, {"start": 523.89, "end": 524.83, "word": " CH3", "probability": 0.843017578125}, {"start": 524.83, "end": 525.75, "word": " وعالتانية", "probability": 0.7495524088541666}, {"start": 525.75, "end": 526.75, "word": " CH2CL", "probability": 0.8736979166666666}, {"start": 526.75, "end": 527.29, "word": " لو", "probability": 0.69287109375}, {"start": 527.29, "end": 527.67, "word": " عملنا", "probability": 0.974609375}, {"start": 527.67, "end": 527.91, "word": " هيك", "probability": 0.6768798828125}, {"start": 527.91, "end": 528.49, "word": " CH3", "probability": 0.960693359375}, {"start": 528.49, "end": 529.43, "word": " وCH2CL", "probability": 0.8326416015625}, {"start": 529.43, "end": 529.75, "word": " و", "probability": 0.6025390625}, {"start": 529.75, "end": 529.87, "word": " 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"end": 551.15, "word": " شغلة", "probability": 0.7245279947916666}, {"start": 551.15, "end": 551.63, "word": " اخيرة", "probability": 0.7097981770833334}, {"start": 551.63, "end": 552.85, "word": " ان", "probability": 0.92236328125}, {"start": 552.85, "end": 553.31, "word": " انا", "probability": 0.93798828125}, {"start": 553.31, "end": 553.73, "word": " اجي", "probability": 0.6429036458333334}, {"start": 553.73, "end": 554.21, "word": " اضيف", "probability": 0.9754231770833334}, {"start": 554.21, "end": 555.77, "word": " unsymmetrical", "probability": 0.6924641927083334}, {"start": 555.77, "end": 556.65, "word": " reagent", "probability": 0.891845703125}, {"start": 556.65, "end": 556.91, "word": " على", "probability": 0.65185546875}, {"start": 556.91, "end": 557.89, "word": " unsymmetrical", "probability": 0.9609375}, {"start": 557.89, "end": 558.53, "word": " alkene", "probability": 0.6217041015625}, {"start": 558.53, "end": 559.53, "word": " ال", "probability": 0.87744140625}, {"start": 559.53, "end": 560.05, "word": " reagent", "probability": 0.966796875}, {"start": 560.05, "end": 560.31, "word": " غير", "probability": 0.994140625}, {"start": 560.31, "end": 561.11, "word": " متماثل", "probability": 0.86259765625}, {"start": 561.11, "end": 562.55, "word": " والalkene", "probability": 0.71923828125}, {"start": 562.55, "end": 562.83, "word": " غير", "probability": 0.994140625}, {"start": 562.83, "end": 563.65, "word": " متماثل", "probability": 0.89638671875}, {"start": 563.65, "end": 564.23, "word": " الان", "probability": 0.6650390625}, {"start": 564.23, "end": 564.63, "word": " اتطلع", "probability": 0.78681640625}, {"start": 564.63, "end": 564.79, "word": " لو", "probability": 0.94677734375}, {"start": 564.79, "end": 565.03, "word": " بدى", "probability": 0.55859375}, {"start": 565.03, "end": 565.35, "word": " اضيف", "probability": 0.9685872395833334}, {"start": 565.35, "end": 565.77, "word": " بهذا", "probability": 0.916015625}, {"start": 565.77, "end": 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"end": 1421.54, "word": " نوع", "probability": 0.98779296875}, {"start": 1421.54, "end": 1421.72, "word": " من", "probability": 0.9716796875}, {"start": 1421.72, "end": 1422.48, "word": " الاستقطاب", "probability": 0.8878173828125}, {"start": 1422.48, "end": 1422.7, "word": " يعني", "probability": 0.9052734375}, {"start": 1422.7, "end": 1423.1, "word": " كأنه", "probability": 0.9083658854166666}, {"start": 1423.1, "end": 1423.26, "word": " أنا", "probability": 0.81494140625}, {"start": 1423.26, "end": 1423.8, "word": " جسمت", "probability": 0.9235026041666666}, {"start": 1423.8, "end": 1424.58, "word": " الجزئة", "probability": 0.81170654296875}, {"start": 1424.58, "end": 1425.82, "word": " موجب", "probability": 0.95751953125}, {"start": 1425.82, "end": 1426.66, "word": " و", "probability": 0.630859375}, {"start": 1426.66, "end": 1427.1, "word": " سالب", "probability": 0.7835286458333334}, {"start": 1427.1, "end": 1427.76, "word": " بضيف", "probability": 0.8359375}, {"start": 1427.76, "end": 1428.52, "word": " الموجب", "probability": 0.9521484375}, {"start": 1428.52, "end": 1429.32, "word": " بيعمل", "probability": 0.969970703125}, {"start": 1429.32, "end": 1429.74, "word": " ايون", "probability": 0.8583984375}, {"start": 1429.74, "end": 1430.18, "word": " بروم", "probability": 0.8779296875}, {"start": 1430.18, "end": 1430.82, "word": " موجب", "probability": 0.9934895833333334}, {"start": 1430.82, "end": 1431.0, "word": " و", "probability": 0.880859375}, {"start": 1431.0, "end": 1431.28, "word": " دايما", "probability": 0.7307942708333334}, {"start": 1431.28, "end": 1431.92, "word": " الايونات", "probability": 0.8443359375}, {"start": 1431.92, "end": 1432.64, "word": " الموجبة", "probability": 0.9811197916666666}, {"start": 1432.64, "end": 1433.78, "word": " بنسميها", "probability": 0.891845703125}, {"start": 1433.78, "end": 1434.36, "word": " onion", "probability": 0.2271728515625}, {"start": 1434.36, "end": 1435.22, "word": " ions", "probability": 0.69189453125}, {"start": 1435.22, "end": 1435.78, "word": " ايش", "probability": 0.7506510416666666}, {"start": 1435.78, "end": 1436.04, "word": " يعني", "probability": 0.97119140625}, {"start": 1436.04, "end": 1436.8, "word": " onion؟", "probability": 0.801025390625}], "temperature": 1.0}, {"id": 59, "seek": 146084, "start": 1438.36, "end": 1460.84, "text": "Ion موجب بتذكروا مثلا كانوا يمروا عليكم كلمة ammonium امونيوم ايون موجب لو مع ال oxygen ايون موجب شو بتسميه اكزونيوم لو مع ال chlorine اكلورونيوم لو مع البروم ابرومونيوم واضح؟", "tokens": [40, 266, 3714, 29245, 3555, 39894, 8848, 37983, 14407, 50113, 15040, 25961, 14407, 7251, 29973, 14407, 25894, 24793, 9122, 19528, 3660, 36431, 2197, 1975, 2304, 11536, 1829, 20498, 1975, 1829, 11536, 3714, 29245, 3555, 45164, 20449, 2423, 9169, 1975, 1829, 11536, 3714, 29245, 3555, 13412, 2407, 39894, 38251, 1829, 3224, 1975, 4117, 11622, 11536, 1829, 20498, 45164, 20449, 2423, 39888, 1975, 4117, 1211, 13063, 11536, 1829, 20498, 45164, 20449, 2423, 26890, 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يكتمل التفاعل من الجهة المعاكسة", "tokens": [5172, 3215, 16373, 15042, 28239, 11296, 10632, 322, 2197, 39894, 3615, 22653, 1975, 1829, 11536, 3714, 29245, 3555, 6156, 3615, 8592, 7649, 7251, 2655, 5016, 12610, 30731, 10874, 11622, 38207, 3714, 29245, 3555, 7251, 11242, 33911, 8978, 29739, 28259, 10632, 4724, 1829, 25957, 1211, 2423, 26890, 20498, 11536, 1829, 20498, 1975, 1829, 11536, 39627, 15730, 25124, 28820, 38637, 2304, 7251, 4117, 39237, 1211, 16712, 5172, 995, 30241, 9154, 25724, 3224, 3660, 9673, 3615, 995, 4117, 3794, 3660], "avg_logprob": -0.3006811034985078, "compression_ratio": 1.6335403726708075, "no_speech_prob": 2.2649765014648438e-06, "words": [{"start": 1461.64, "end": 1462.4, "word": "فدائما", "probability": 0.605010986328125}, {"start": 1462.4, "end": 1462.98, "word": " النهاية", "probability": 0.7584635416666666}, {"start": 1462.98, "end": 1463.44, "word": " onium", "probability": 0.32220458984375}, {"start": 1463.44, "end": 1463.96, "word": " بتعني", "probability": 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الرابط على البروم و بيكون لي رابط احدية بحصل على جزء متعدل بهيك إيش بتلاحظه ان البروم أو البرومين addition is Anti addition Anti يعني يتم من جهتين", "tokens": [3555, 28814, 11242, 31845, 3660, 25724, 11622, 38207, 21136, 6027, 3555, 23032, 3555, 3615, 995, 3714, 14851, 5016, 26895, 36145, 3224, 7251, 3555, 4587, 7578, 10874, 3224, 3660, 6055, 16572, 5172, 9154, 34105, 4032, 10874, 3224, 3660, 5551, 8592, 2304, 6027, 11296, 3714, 36150, 2407, 17082, 3714, 7435, 2288, 3215, 19446, 7251, 7435, 1829, 21136, 6027, 3555, 23758, 34105, 39894, 47341, 3615, 34892, 16758, 9566, 15844, 2423, 26890, 20498, 4032, 4724, 1829, 30544, 32239, 12602, 16758, 9566, 1975, 24401, 10632, 4724, 5016, 36520, 15844, 10874, 11622, 38207, 44650, 22488, 1211, 4724, 3224, 1829, 4117, 11933, 1829, 8592, 39894, 15040, 5016, 19913, 3224, 16472, 2423, 26890, 20498, 34051, 2423, 26890, 20498, 9957, 4500, 307, 27757, 4500, 27757, 37495, 22653, 7251, 39237, 9154, 10874, 3224, 2655, 9957], "avg_logprob": 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مصارين", "probability": 0.61846923828125}, {"start": 2275.99, "end": 2276.21, "word": " و", "probability": 0.5283203125}, {"start": 2276.21, "end": 2276.51, "word": " هنا", "probability": 0.487548828125}, {"start": 2276.51, "end": 2276.87, "word": " نفس", "probability": 0.9951171875}, {"start": 2276.87, "end": 2277.33, "word": " الفكرة", "probability": 0.9944661458333334}, {"start": 2277.33, "end": 2277.81, "word": " تماما", "probability": 0.9869791666666666}, {"start": 2277.81, "end": 2277.99, "word": " انا", "probability": 0.6173095703125}, {"start": 2277.99, "end": 2278.11, "word": " في", "probability": 0.9580078125}, {"start": 2278.11, "end": 2278.33, "word": " اندي", "probability": 0.4014892578125}, {"start": 2278.33, "end": 2278.93, "word": " احتمالين", "probability": 0.97314453125}, {"start": 2278.93, "end": 2279.65, "word": " صيروا", "probability": 0.8751627604166666}, {"start": 2279.65, "end": 2280.33, "word": " هذا", "probability": 0.364013671875}, {"start": 2280.33, "end": 2281.01, "word": " أحدهم", "probability": 0.8883463541666666}, {"start": 2281.01, "end": 2281.65, "word": " وفي", "probability": 0.8232421875}, {"start": 2281.65, "end": 2282.17, "word": " الاحتمال", "probability": 0.8629150390625}, {"start": 2282.17, "end": 2282.67, "word": " التاني", "probability": 0.93359375}, {"start": 2282.67, "end": 2283.15, "word": " الآن", "probability": 0.6142578125}, {"start": 2283.15, "end": 2283.65, "word": " التفاعل", "probability": 0.94287109375}, {"start": 2283.65, "end": 2283.99, "word": " اختار", "probability": 0.9363606770833334}, {"start": 2283.99, "end": 2284.53, "word": " احتمال", "probability": 0.9879150390625}, {"start": 2284.53, "end": 2284.83, "word": " من", "probability": 0.9931640625}, {"start": 2284.83, "end": 2285.93, "word": " التانين", "probability": 0.7571614583333334}, {"start": 2285.93, "end": 2286.57, "word": " بيصير", "probability": 0.9130859375}, {"start": 2286.57, "end": 2287.19, "word": " السؤال", "probability": 0.99755859375}, 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30544, 15844, 2423, 41779, 9566, 37893, 42963, 33753, 2304, 6027, 16712, 7649, 1829, 4032, 33251, 9640, 3555, 2407, 9122, 2655, 995, 9957, 7251, 30544, 15844, 41950, 28480, 4032, 46958, 5016, 27188, 4117, 25720, 22807, 16490, 1211, 9381, 47395, 22807, 16490, 1211, 14407, 23758, 21136, 33604, 6027, 4386, 16490, 1211, 14407, 23758, 21136, 33604, 6027, 5296, 19528, 25720, 25724, 995, 10632, 4386, 16490, 1211, 14407, 23758, 21136, 33604, 6027, 5296, 19528, 25720, 25724, 995, 10632, 4386, 4724, 3794, 8032, 1863, 44510, 10721, 9154, 43242, 3224, 5296, 33456, 3224, 4724, 5016, 26108, 3660, 30731, 6055, 5172, 9381, 26895], "avg_logprob": -0.14750573230445932, "compression_ratio": 2.28, "no_speech_prob": 5.4836273193359375e-06, "words": [{"start": 2295.39, "end": 2295.73, "word": "وإن", "probability": 0.743408203125}, {"start": 2295.73, "end": 2296.31, "word": " الكاربو", "probability": 0.72802734375}, {"start": 2296.31, "end": 2296.65, "word": " كتاين", "probability": 0.6986083984375}, {"start": 2296.65, "end": 2296.99, "word": " يكون", "probability": 0.962646484375}, {"start": 2296.99, "end": 2297.25, "word": " على", "probability": 0.89990234375}, {"start": 2297.25, "end": 2297.95, "word": " الوسط", "probability": 0.986328125}, {"start": 2297.95, "end": 2298.71, "word": " مش", "probability": 0.58251953125}, {"start": 2298.71, "end": 2299.35, "word": " الاحتمال", "probability": 0.89208984375}, {"start": 2299.35, "end": 2299.71, "word": " التاني", "probability": 0.91064453125}, {"start": 2299.71, "end": 2299.77, "word": " و", "probability": 0.6875}, {"start": 2299.77, "end": 2300.25, "word": " الكاربو", "probability": 0.81011962890625}, {"start": 2300.25, "end": 2300.75, "word": " كتاين", "probability": 0.9730224609375}, {"start": 2300.75, "end": 2301.57, "word": " يكون", "probability": 0.95458984375}, {"start": 2301.57, "end": 2301.91, "word": " على", "probability": 0.95166015625}, {"start": 2301.91, "end": 2303.25, "word": " الطرف", "probability": 0.9658203125}, {"start": 2303.25, "end": 2303.79, "word": " واضح", "probability": 0.9166666666666666}, {"start": 2303.79, "end": 2307.37, "word": " الفكرة؟", "probability": 0.79644775390625}, {"start": 2307.37, "end": 2311.43, "word": " خلصته؟", "probability": 0.78818359375}, {"start": 2311.43, "end": 2311.83, "word": " خلوا", "probability": 0.8738606770833334}, {"start": 2311.83, "end": 2312.01, "word": " هذا", "probability": 0.96533203125}, {"start": 2312.01, "end": 2312.67, "word": " السؤال", "probability": 0.9954427083333334}, {"start": 2312.67, "end": 2312.77, "word": " ..", "probability": 0.6201171875}, {"start": 2312.77, "end": 2313.57, "word": " خلوا", "probability": 0.9127604166666666}, {"start": 2313.57, "end": 2313.77, "word": " هذا", "probability": 0.99365234375}, {"start": 2313.77, "end": 2314.13, "word": " السؤال", "probability": 0.9959309895833334}, {"start": 2314.13, "end": 2314.59, "word": " للمرة", "probability": 0.9716796875}, {"start": 2314.59, "end": 2315.09, "word": " الجاية", "probability": 0.8502604166666666}, {"start": 2315.09, "end": 2316.05, "word": " ..", "probability": 0.62353515625}, {"start": 2316.05, "end": 2316.31, "word": " خلوا", "probability": 0.9065755208333334}, {"start": 2316.31, "end": 2316.51, "word": " هذا", "probability": 0.99462890625}, {"start": 2316.51, "end": 2316.83, "word": " السؤال", "probability": 0.9967447916666666}, {"start": 2316.83, "end": 2317.21, "word": " للمرة", "probability": 0.98583984375}, {"start": 2317.21, "end": 2317.49, "word": " الجاية", "probability": 0.9881184895833334}, {"start": 2317.49, "end": 2317.57, "word": " ..", "probability": 0.54345703125}, {"start": 2317.57, "end": 2317.73, "word": " بس", "probability": 0.946533203125}, {"start": 2317.73, "end": 2318.27, "word": " هنبدأ", "probability": 0.931884765625}, {"start": 2318.27, "end": 2318.45, "word": " من", "probability": 0.99462890625}, {"start": 2318.45, "end": 2318.95, "word": " عنده", "probability": 0.974853515625}, {"start": 2318.95, "end": 2319.89, "word": " لأنه", "probability": 0.7486979166666666}, {"start": 2319.89, "end": 2320.35, "word": " بحاجة", "probability": 0.994873046875}, {"start": 2320.35, "end": 2320.71, "word": " إلى", "probability": 0.91455078125}, {"start": 2320.71, "end": 2321.63, "word": " تفصيل", "probability": 0.9381103515625}], "temperature": 1.0}, {"id": 93, "seek": 232983, "start": 2322.89, "end": 2329.83, "text": "فكروا فيه كويس انه في احتمالين اختار واحد و المرة الجاية ان شاء الله بنبدأ الشغل", "tokens": [5172, 37983, 14407, 8978, 3224, 9122, 45865, 3794, 16472, 3224, 8978, 1975, 33753, 2304, 6027, 9957, 1975, 46456, 9640, 36764, 24401, 4032, 9673, 25720, 25724, 995, 10632, 16472, 13412, 16606, 21984, 44945, 44510, 10721, 25124, 17082, 1211], "avg_logprob": -0.20240543076866552, "compression_ratio": 1.4215686274509804, "no_speech_prob": 0.0008945465087890625, "words": [{"start": 2322.89, "end": 2323.41, "word": "فكروا", "probability": 0.9220377604166666}, {"start": 2323.41, "end": 2323.69, "word": " فيه", "probability": 0.972412109375}, {"start": 2323.69, "end": 2324.33, "word": " كويس", "probability": 0.9934895833333334}, {"start": 2324.33, "end": 2324.85, "word": " انه", "probability": 0.5196533203125}, {"start": 2324.85, "end": 2324.93, "word": " في", "probability": 0.86767578125}, {"start": 2324.93, "end": 2325.45, "word": " احتمالين", "probability": 0.89765625}, {"start": 2325.45, "end": 2325.85, "word": " اختار", "probability": 0.9723307291666666}, {"start": 2325.85, "end": 2326.33, "word": " واحد", "probability": 0.96484375}, {"start": 2326.33, "end": 2327.09, "word": " و", "probability": 0.383056640625}, {"start": 2327.09, "end": 2327.39, "word": " المرة", "probability": 0.798583984375}, {"start": 2327.39, "end": 2327.71, "word": " الجاية", "probability": 0.644775390625}, {"start": 2327.71, "end": 2327.85, "word": " ان", "probability": 0.87353515625}, {"start": 2327.85, "end": 2328.01, "word": " شاء", "probability": 0.96533203125}, {"start": 2328.01, "end": 2328.19, "word": " الله", "probability": 0.9580078125}, {"start": 2328.19, "end": 2329.53, "word": " بنبدأ", "probability": 0.7820638020833334}, {"start": 2329.53, "end": 2329.83, "word": " الشغل", "probability": 0.8722330729166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2342.104, "duration_after_vad": 2256.9968749999925}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI.srt
new file mode 100644
index 0000000000000000000000000000000000000000..eb8eda39daa1cf532b9e639f316449e4b1b38004
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI.srt
@@ -0,0 +1,1790 @@
+1
+00:00:09,630 --> 00:00:17,330
+اليوم موضوعنا فصل جديد وممتع هو الفصل المعنوان 
+
+2
+00:00:17,330 --> 00:00:25,020
+stereochemistry معنى stereochemistry دراسة شكل
+
+3
+00:00:25,020 --> 00:00:31,560
+الجزء في الفراغ في ثلاثة أبعاد واضح؟ يعني دائماً كلمة 
+
+4
+00:00:31,560 --> 00:00:35,880
+stereo بتعني شيء بيطلع في ثلاثة أبعاد حتى اللي
+
+5
+00:00:35,880 --> 00:00:41,300
+بتسموه الـ stereo تبع الصوت بيطلع الصوت في ثلاثة
+
+6
+00:00:41,300 --> 00:00:45,000
+أبعاد أو في كل الاتجاهات واضح؟ three-dimensional
+
+7
+00:00:45,000 --> 00:00:51,460
+هذا الحقيقة chapter ممتع 
+
+8
+00:00:51,460 --> 00:00:59,400
+جداً.. كمقدمة له بدنا نذكر اللوحة اللي
+
+9
+00:00:59,400 --> 00:01:03,420
+مرت علينا وقلنا هتظل تتكرر علينا كثير اللي هي 
+
+10
+00:01:03,420 --> 00:01:08,860
+فيها تصنيف للـ isomers اللي فيها تصنيف للـ isomers
+
+11
+00:01:08,860 --> 00:01:15,170
+يمكن أنا شوية صغيرة كبرتها أو قسمتها إلى جزئين
+
+12
+00:01:15,170 --> 00:01:24,630
+الجزء الفوق هذا طبعاً معنى isomers هي مركبات تختلف
+
+13
+00:01:24,630 --> 00:01:31,350
+في الشكل البنائي لكن لها نفس الـ molecular formula
+
+14
+00:01:31,350 --> 00:01:35,350
+الصيغة الجزئية طبعاً طالما لها نفس الصيغة الجزئية
+
+15
+00:01:35,350 --> 00:01:38,510
+من باب أو لا لها نفس الـ empirical formula طبعاً 
+
+16
+00:01:38,510 --> 00:01:41,230
+تكونوا متذكرين أنتم أنه لما أخذتم الصيغة
+
+17
+00:01:41,230 --> 00:01:47,010
+الكيميائية أخذتم ثلاثة صياغ empirical formula اللي هي
+
+18
+00:01:47,010 --> 00:01:52,450
+أبسط نسبة، الـ molecular formula اللي هي الأعداد 
+
+19
+00:01:52,450 --> 00:01:57,890
+الحقيقية للجزء، و الـ structural formula كيف بيشبكوا 
+
+20
+00:01:57,890 --> 00:02:04,310
+واضح يعني مثلاً أنا ممكن أقول الـ chemical formula
+
+21
+00:02:04,310 --> 00:02:07,230
+العادية هدول ثلاثة أقلام لكن لما بدي structural
+
+22
+00:02:07,230 --> 00:02:11,470
+formula وبدي أعمل منهم شكل ممكن أعمله بأكثر من
+
+23
+00:02:11,470 --> 00:02:16,350
+طريقة هنا بصير في عند إيش؟ Structural formula فال
+
+24
+00:02:16,350 --> 00:02:19,730
+isomers they are as you can see different 
+
+25
+00:02:19,730 --> 00:02:24,170
+compounds that have the same molecular formula،
+
+26
+00:02:24,170 --> 00:02:27,610
+اللي هو نفس الـ molecular formula، but different
+
+27
+00:02:27,610 --> 00:02:32,500
+structuresthey differ in the structural formula
+
+28
+00:02:32,500 --> 00:02:40,520
+الآن بيقسموا الـ isomers لنوعين أساسيين النوع الأول
+
+29
+00:02:40,520 --> 00:02:46,880
+بنسميه constitutional isomers يعني isomers مختلفة
+
+30
+00:02:46,880 --> 00:02:51,800
+في البناء أو في التكوين وعشان إيه كمان بتاخد اسم
+
+31
+00:02:51,800 --> 00:02:56,320
+ثاني الـ constitutional isomers نفسه بيسموها 
+
+32
+00:02:56,320 --> 00:03:01,950
+structural isomers واضح فإذا قلنا constitutional
+
+33
+00:03:01,950 --> 00:03:10,150
+isomers أو قلنا structural isomers نفس المعنى they
+
+34
+00:03:10,150 --> 00:03:14,870
+differ in the bonding in the structure الآن لو
+
+35
+00:03:14,870 --> 00:03:18,390
+بتيجي تلاحظوا هدول الـ constitutional isomers أو الـ
+
+36
+00:03:18,390 --> 00:03:24,970
+structural isomers إيش تعريفهم بتلاقوا  atoms
+
+37
+00:03:24,970 --> 00:03:28,390
+are attached to one another in different ways
+
+38
+00:03:28,390 --> 00:03:33,610
+الذرات مرتبطة مع بعض البعض بطرق مختلفة يعني 
+
+39
+00:03:33,610 --> 00:03:39,810
+بيختلفوا في الـ bonding في الروابط واضح تماماً زي ما
+
+40
+00:03:39,810 --> 00:03:43,470
+أنا بدي أمسك هدول الأقلام أقول في عندي أحمر أزرق
+
+41
+00:03:43,470 --> 00:03:48,010
+أسود هاني عملت إيش structure الآن الـ bonding كيف
+
+42
+00:03:48,010 --> 00:03:51,530
+عندي هنا أحمر أزرق أسود أزرق أزرق أزرق أزرق أزرق 
+
+43
+00:03:51,530 --> 00:04:05,290
+أزرق أزرق أزرق أزرق أزرق أزرق أزرق أزرق أزرق أزرق 
+
+44
+00:04:05,800 --> 00:04:11,580
+وعاد التكوين بشكل جديد واضح من الأمثلة عليها لو
+
+45
+00:04:11,580 --> 00:04:15,820
+بتتطلع على المثال اللي موجود عندكم مثلاً الـ ethanol 
+
+46
+00:04:15,820 --> 00:04:21,760
+و الـ di-methyl ether كل جزء صيغته الـ chemical
+
+47
+00:04:21,760 --> 00:04:26,260
+formula تبعته C2H6O 
+
+48
+00:04:26,260 --> 00:04:32,260
+إذا هذول مشتركون في الصيغة وين الاختلاف تبعهم؟ في
+
+49
+00:04:32,260 --> 00:04:36,520
+الارتباط يعني بعيداً عن الهيدروجين الجزء الأول 
+
+50
+00:04:36,520 --> 00:04:41,980
+بتلاقي تركيبه carbon carbon oxygen الجزء الثاني
+
+51
+00:04:41,980 --> 00:04:47,500
+بتلاقي تركيبه carbon oxygen carbon إذا هدول they 
+
+52
+00:04:47,500 --> 00:04:50,220
+differ in bonding
+
+53
+00:04:51,670 --> 00:04:54,950
+أو زي ما بتلاحظوا التعريف atoms are attached to
+
+54
+00:04:54,950 --> 00:04:58,290
+one another in different ways الذرات مرتبطة في بعض 
+
+55
+00:04:58,290 --> 00:05:06,210
+البعض بطرق مختلفة هذا أنه حقيقة هو أسهل أنواع الـ 
+
+56
+00:05:06,210 --> 00:05:10,440
+isomers هذا النوع الـ structural isomers اللي 
+
+57
+00:05:10,440 --> 00:05:16,020
+بيختلفه في مواقع الارتباط هو أسهل أشكال الـ isomers
+
+58
+00:05:16,020 --> 00:05:22,740
+يعني بنظرة بثانية بتقدروا تكتشفوا أن هذا مش زي هذا 
+
+59
+00:05:23,370 --> 00:05:28,190
+واضح؟ سهل جداً أن نكتشف الـ structural isomers يعني
+
+60
+00:05:28,190 --> 00:05:31,370
+مجرد ما بتطلعوا بتقولوا أن هدول structural
+
+61
+00:05:31,370 --> 00:05:37,150
+isomers خليني أعطيكم مثال ثاني تقولولي عنه أنه
+
+62
+00:05:37,150 --> 00:05:40,630
+فعلاً structural isomers ولا لا؟ لو تخيلتوا أن 
+
+63
+00:05:40,630 --> 00:05:45,770
+عندكم بنزين وحطينا زي هيك كلور وكلور وبنزين ثاني
+
+64
+00:05:45,770 --> 00:05:51,890
+وحطينا كلور وكلور هدول الجزيئين
+
+65
+00:05:55,640 --> 00:06:00,340
+Are they structural isomers؟ أكيد لأن هنا إذا
+
+66
+00:06:00,340 --> 00:06:03,300
+بتبتطلع الارتباط، عندي chlorine، carbon، carbon،
+
+67
+00:06:03,300 --> 00:06:10,820
+chlorine، carbon، carbon، carbon، chlorine،
+
+68
+00:06:10,820 --> 00:06:12,600
+carbon، carbon، carbon، chlorine،
+
+69
+00:06:12,600 --> 00:06:12,800
+carbon، carbon، carbon، carbon،
+
+70
+00:06:12,800 --> 00:06:16,060
+carbon، carbon، carbon، carbon،
+
+71
+00:06:16,060 --> 00:06:16,840
+carbon، carbon، carbon، carbon،
+
+72
+00:06:16,840 --> 00:06:16,860
+carbon، carbon، carbon، carbon،
+
+73
+00:06:16,860 --> 00:06:16,880
+carbon، carbon، carbon، carbon،
+
+74
+00:06:16,880 --> 00:06:19,960
+carbon، carbon، carbon، carbon،
+
+75
+00:06:19,960 --> 00:06:20,440
+carbon، carbon، carbon، carbon،
+
+76
+00:06:20,440 --> 00:06:20,460
+carbon، carbon، carbon، carbon،
+
+77
+00:06:24,290 --> 00:06:30,030
+ميثانول المركب الثاني دايمثل إيثر إذا ال
+
+78
+00:06:30,030 --> 00:06:37,610
+structural isomers they have different names ليش؟ 
+
+79
+00:06:37,610 --> 00:06:41,790
+لأن الـ name أو الاسم للمركب بيعبر عن.. عن 
+
+80
+00:06:41,790 --> 00:06:44,530
+structure عن ذرات طالما الـ structure اختلف إذا 
+
+81
+00:06:44,530 --> 00:06:50,580
+الاسم اختلف نفس الشيء هنالك كنتوا بتكونوا تسموا
+
+82
+00:06:50,580 --> 00:06:56,820
+هدول المركبين هتقولوا ortho-dichlorobenzene أو
+
+83
+00:06:56,820 --> 00:07:03,240
+one two dichlorobenzene هنا tara-dichlorobenzene 
+
+84
+00:07:03,240 --> 00:07:07,700
+أو one four dichlorobenzene ملاحظين أنتم أن مواقع 
+
+85
+00:07:07,700 --> 00:07:11,920
+الارتباط كلها اختلفت الـ bonding اختلف هذا أبسط نوع من 
+
+86
+00:07:11,920 --> 00:07:15,680
+الـ isomers اللي مر علينا كثير أمثلة زيه اللي 
+
+87
+00:07:15,680 --> 00:07:20,730
+بنسميها إيش؟ Structural isomers مش هذا موضوعنا اليوم 
+
+88
+00:07:20,730 --> 00:07:25,190
+مش هذا موضوعنا اليوم إيش موضوعنا احنا اليوم النوع 
+
+89
+00:07:25,190 --> 00:07:30,350
+الثاني من الـ isomers اللي اسمه الـ stereo isomers
+
+90
+00:07:30,350 --> 00:07:37,830
+الـ stereo isomers شوية بغلبه بدهم عين أو يمكن في
+
+91
+00:07:37,830 --> 00:07:41,530
+أول الأشياء ما تصدقوش أن هدول الأشياء مختلفين عن
+
+92
+00:07:41,530 --> 00:07:46,230
+بعضهم البعض مكتوب فيهم atoms have the same 
+
+93
+00:07:46,230 --> 00:07:50,750
+substitution or constitution عفواً the same bonding 
+
+94
+00:07:50,750 --> 00:07:54,970
+لهم نفس مواقع الارتباط but different arrangement 
+
+95
+00:07:54,970 --> 00:08:00,290
+in space لكن كيف شكلهم بالفراغ بيختلف بس مواقع 
+
+96
+00:08:00,290 --> 00:08:06,480
+ارتباطهم لا تختلف، فقط بيختلفوا بإيش؟ بالشكل اللي 
+
+97
+00:08:06,480 --> 00:08:12,300
+موجود في الفراغ، كيف بالفراغ بيكون شكلهم، فللوحة
+
+98
+00:08:12,300 --> 00:08:17,620
+الأولى الناس ممكن يخربطوا بينهم، الآن جرت العادة
+
+99
+00:08:17,620 --> 00:08:21,560
+أن الواحد قبل ما يشرح هذه الظاهرة كيميائياً، هذه
+
+100
+00:08:21,560 --> 00:08:27,040
+ظاهرة حياتية يعني موجودة في الحياة كثير قد تكونوا
+
+101
+00:08:27,040 --> 00:08:30,620
+أنتبهتوا إليها وقد لا تكونوا انتبهتوا إليها بس عليها
+
+102
+00:08:30,620 --> 00:08:35,060
+الأمثلة في الحياة كثيرة لا تعد ولا تحصى أنه أشياء 
+
+103
+00:08:35,060 --> 00:08:41,560
+مبينة زي بعض لكن هي حقيقة مختلفة دائماً أبداً المثال
+
+104
+00:08:41,560 --> 00:08:45,320
+اللي بيبدأوا فيه وبينطلقوا منه هو الـ Eden تعون 
+
+105
+00:08:45,320 --> 00:08:51,840
+البني آدم هدول الأيدي الآن السؤال هدول الأيدي زي 
+
+106
+00:08:51,840 --> 00:08:59,900
+بعض ولا لا؟ ملاحظين أنتم؟ معنى زي بعض أنه أنا 
+
+107
+00:08:59,900 --> 00:09:05,820
+بقدر أحط واحدة محل الثانية يعني
+
+108
+00:09:05,820 --> 00:09:09,500
+لو بقدرة قادر بنفك هدول التنتين بنقدر نحط هذه محل
+
+109
+00:09:09,500 --> 00:09:12,240
+هذه وهذه محل هذه إيش رأيكم؟ 
+
+110
+00:09:15,510 --> 00:09:18,950
+طبعاً أنتم صعب عليكم تتخيلوا أن تعون البني آدم 
+
+111
+00:09:18,950 --> 00:09:22,730
+بنفكوا لكن معظمكم في الطفولة إذا ما كانش في الكبر 
+
+112
+00:09:22,730 --> 00:09:27,130
+كمان في عندهم العرايس لصغار لما تيجوا تركبوا
+
+113
+00:09:27,130 --> 00:09:31,490
+العروسة العروسة أيدين ورجلين لما تيجوا تركبوها 
+
+114
+00:09:31,490 --> 00:09:35,670
+بتحسوا أنه لازم أحط اليد اليمنى محلّها واليد
+
+115
+00:09:35,670 --> 00:09:40,770
+اليسرى محلّها لو حطيتها بالعكس بدل ما تكون اليد الـ.. 
+
+116
+00:09:42,080 --> 00:09:46,180
+الـ calf تبعها بيأشر لجوه جهة الجسم لو حطيتها
+
+117
+00:09:46,180 --> 00:09:51,720
+بالعكس بيطلع لبرة واضح؟ نفس الأشياء دول الأيدين إذا 
+
+118
+00:09:51,720 --> 00:09:56,060
+بتطلع عليهم شبههم كبير جداً يعني لو أنا اتخيلت أنه
+
+119
+00:09:56,060 --> 00:10:00,960
+عندي مرايا هذه اليد هي صورة هذه اليد في المرأة
+
+120
+00:10:02,180 --> 00:10:06,020
+واضح؟ صورة بعض في المرأة لكن السؤال هل يا ترى
+
+121
+00:10:06,020 --> 00:10:08,800
+هدول الأشياء اللي صورة بعض في المرأة بينطبقوا ولا
+
+122
+00:10:08,800 --> 00:10:13,380
+لا؟ بشكل عام لما بيكون عندي شغلتين صورة بعض في
+
+123
+00:10:13,380 --> 00:10:18,540
+المرأة ممكن ينطبقوا على بعض وممكن لا ينطبقوا على
+
+124
+00:10:18,540 --> 00:10:23,980
+بعض حسب كيف شكلهم بالفرق يعني مثلاً لو مسكت هدول 
+
+125
+00:10:23,980 --> 00:10:30,720
+الكرتونين الخضر مثلاً كبر بس مش فيهم أي شيء هذه صورة
+
+126
+00:10:30,720 --> 00:10:34,780
+هذه في المرأة الآن هدول كل شيء فيهم symmetric 
+
+127
+00:10:34,780 --> 00:10:39,180
+بشكل كبير متماثلات بينطبقوا على بعض بمعنى لو كان
+
+128
+00:10:39,180 --> 00:10:42,680
+في جالب محطوطة هذه فيه وفيه فراغات عشان تقعد فيه 
+
+129
+00:10:42,680 --> 00:10:48,380
+بالراحة هذه بتقعد زيها ولا لا؟ بينطبقوا على بعض
+
+130
+00:10:48,380 --> 00:10:55,870
+واضح؟ بينطبقوا على بعض بسهولة جداً واضح؟ الآن في 
+
+131
+00:10:55,870 --> 00:11:00,350
+شغلات لأ ما بتنطبقش على بعض، يعني لو تخيلتوا مثلاً
+
+132
+00:11:00,350 --> 00:11:05,010
+هدول الإثنين، لو أنا كنت بدي أشيل هذه اليد وأجي
+
+133
+00:11:05,010 --> 00:11:10,410
+أحط هذه مكانها، لاحظوا الكف وين اتجاهه هنا؟ على جهة
+
+134
+00:11:10,410 --> 00:11:15,150
+البني آدم، لو كنت بدي أحط هذه، بدي أحطها زي هيك، 
+
+135
+00:11:15,150 --> 00:11:20,730
+إيش صار في هذا الإصبع؟ رايح باتجاه هذا الإصبع رايح 
+
+136
+00:11:20,730 --> 00:11:24,470
+باتجاه ثاني، إذا هذه اليد وهذه اليد بنقدر نقول 
+
+137
+00:11:24,470 --> 00:11:32,970
+عنهم صورة بعض في المرأة لكنها غير متطابقة صورة بعض
+
+138
+00:11:32,970 --> 00:11:39,450
+في المرأة لكنها غير متطابقة معنى صورة بعض في 
+
+139
+00:11:39,450 --> 00:11:45,940
+المرأة mirror images معنى غير متطابقة non-super
+
+140
+00:11:45,940 --> 00:11:51,720
+-imposable متطابق non-super-imposable غير متطابق
+
+141
+00:11:51,720 --> 00:11:56,880
+إذن احنا بنقدر الآن نقول أن هدول الـ two hands
+
+142
+00:11:56,880 --> 00:12:04,580
+الـ hands الأيدين non
+
+143
+00:12:04,580 --> 00:12:07,620
+-super
+
+144
+00:12:07,620 --> 00:12:08,800
+-imposable
+
+145
+00:12:13,170 --> 00:12:19,950
+mirror images يعني 
+
+146
+00:12:19,950 --> 00:12:26,110
+صورة بعض في المرأة ولكنها غير متطابقة واضح؟ الآن 
+
+147
+00:12:26,110 --> 00:12:32,590
+هذا الاختلاف بالمناسبة هو اختلاف بس بالشكل الفراغي
+
+148
+00:12:32,590 --> 00:12:36,870
+بمعنى لو كنا بدنا نيجي مثلاً على خاصية زي الكتلة و
+
+149
+00:12:36,870 --> 00:12:40,610
+أخذنا اليد هادي واليد هادي هلاحظ إنهم نفس
+
+150
+00:12:40,610 --> 00:12:44,230
+الكتلة كإن أنا بدأت أجرب من الكيمياء يعني لما بقول 
+
+151
+00:12:44,230 --> 00:12:48,690
+the same molecular formula نفس الصيغة الجزئية
+
+152
+00:12:48,690 --> 00:12:51,330
+معناه the same molecular formula the same
+
+153
+00:12:51,330 --> 00:12:54,800
+molecular weight نفس الوزن، بس الاختلاف وين بده
+
+154
+00:12:54,800 --> 00:12:59,260
+يكون؟ بالشكل الفراغي الآن هذه الظاهرة، ظاهرة 
+
+155
+00:12:59,260 --> 00:13:03,120
+الأيدين اللي بيكونوا صورة بعض في المرأة ولكنها 
+
+156
+00:13:03,120 --> 00:13:07,920
+غير متطابقة بيسموها ظاهرة الـ handedness اللي هي
+
+157
+00:13:07,920 --> 00:13:11,700
+ظاهرة يعني مثل الأيدين handedness
+
+158
+00:13:17,380 --> 00:13:20,520
+إذا لو قلنا ظاهرة الـ handedness أي شيء صورة بعض
+
+159
+00:13:20,520 --> 00:13:25,640
+في المرأة غير متطابقة بتكون زي هيك الآن لو اجيتم
+
+160
+00:13:25,640 --> 00:13:29,280
+تعطوا أمثلة.. لو اجيتم تعطوا أمثلة على هذا
+
+161
+00:13:29,280 --> 00:13:35,000
+الموضوع من الحياة أمثلة كثير مين تعطينا مثل غير
+
+162
+00:13:35,000 --> 00:13:42,540
+الأيدين؟ خلصنا من الأيدين بنفع
+
+163
+00:13:42,540 --> 00:13:50,600
+رجلين؟ بنفع رجلين بنفع ما يوضع في الرجلين؟ الأحذية 
+
+164
+00:13:50,600 --> 00:13:57,640
+الحذاء شوية كبير يعني معظمكم بيميزه بس لاحظوا
+
+165
+00:13:57,640 --> 00:14:04,340
+دائماً عندكم مشكلة مع الطفل الصغير بن سنة وسنتين
+
+166
+00:14:04,340 --> 00:14:09,580
+أكم مرة بتكونوا تقولوا له اليمين لشمال بدلهم بياخدوا
+
+167
+00:14:09,580 --> 00:14:15,290
+الطفل لـ 4 و 5 سنين وهو مش قادر يحس الفرق بين اللي 
+
+168
+00:14:15,290 --> 00:14:19,710
+هو فردتي الحذاء ليش؟ لأنه بنطبق عليهم نفس الفكرة
+
+169
+00:14:19,710 --> 00:14:25,550
+هم صورة بعض في المرأة غير متطابقة فعشان يفهمها
+
+170
+00:14:25,550 --> 00:14:29,850
+الطفل قداش بده هذه الظاهرة؟ بده أربع أو خمس سنين 
+
+171
+00:14:29,850 --> 00:14:37,030
+الأصعب منها الجرابين ثلاثة أرباع الناس بخرف طينهم بس
+
+172
+00:14:37,030 --> 00:14:41,150
+لو بدكم تيجوا للحقيقة برضه فيهم شمال ويمين 
+
+173
+00:14:41,150 --> 00:14:48,920
+الـ Quantat تعون الأيد فيهم شمال ويمين الودنتين
+
+174
+00:14:48,920 --> 00:14:54,460
+اتخيلوا لو واحد هيك وودنتين ووجعه يعني اتجمده في 
+
+175
+00:14:54,460 --> 00:14:58,360
+بارد شديد في روسيا ووجعه الجراح بده يربط له إياهم 
+
+176
+00:14:58,360 --> 00:15:04,420
+لازم يكون عنده فكرة أن هدول فيهم شمال ويمين واضح؟
+
+177
+00:15:04,420 --> 00:15:08,780
+الكلام وين بتكرر؟ عند الناس العاديين وبيفهموا هذه
+
+178
+00:15:08,780 --> 00:15:14,270
+الظاهرة كويس لو الباب تبع السيارة خربان بيروح الواحد
+
+179
+00:15:
+
+201
+00:17:05,210 --> 00:17:12,450
+okay ونحط عليه أربع ذرات خلينا نقول بدنا نحط عليه 
+
+202
+00:17:12,450 --> 00:17:19,030
+يود اليود إيش لونه أزرق هيحطين هذه الزرقة تعبيرا
+
+203
+00:17:19,030 --> 00:17:26,790
+عن اليود وبدنا نحط عليه بروم البروم إيش لونه لا
+
+204
+00:17:26,790 --> 00:17:32,720
+بردجان البروم البروم أحمر على برتقالي برتقالي
+
+205
+00:17:32,720 --> 00:17:36,900
+البروم برتقالي محلول البرومين لما بتعملوا تجربة
+
+206
+00:17:36,900 --> 00:17:40,560
+double bond وبيختفي لونه بيختفي من البرتقالي إلى
+
+207
+00:17:40,560 --> 00:17:45,720
+عديم اللون البروم برتقالي مظبوط ولا لأ الchlor
+
+208
+00:17:45,720 --> 00:17:51,280
+أخضر أخضر على أصفر إذا احفظوا اليوم الألوان هذا
+
+209
+00:17:51,280 --> 00:17:56,420
+الأزرق تعبير عن إيش يود والبرتقالي البروم والأخضر
+
+210
+00:17:56,420 --> 00:18:02,690
+الchlor هذه السكنية نعتبرها هيدروجين Okay؟ الآن يا
+
+211
+00:18:02,690 --> 00:18:09,990
+تورا لو أنا اجيت عملت لو أنا اجيت عملت صورة لهذا
+
+212
+00:18:09,990 --> 00:18:16,470
+الجزء في المرأة حطيت هنا hydrogen, brom, iod, 
+
+213
+00:18:17,050 --> 00:18:21,530
+chlorine هاي هدول التنين صورة بعض في المرأة ولا
+
+214
+00:18:21,530 --> 00:18:26,790
+لأ؟ الآن يا تورا هدول التنين بنطبقوا على بعض ولا
+
+215
+00:18:26,790 --> 00:18:33,060
+لأ؟ واضح؟ انجرب معناه بنطبقوا على بعض كل ذرة بده
+
+216
+00:18:33,060 --> 00:18:37,840
+تيجي مكان التاني لو إجينا نجرب هنا حطينا البردجاني
+
+217
+00:18:37,840 --> 00:18:43,820
+على البردجاني البنة على البنة إيش بتلاحظوا؟ الأخضر
+
+218
+00:18:43,820 --> 00:18:48,660
+والأزرق مايجيوش على بعض لو بدنا نجرب نقول طب بنظبط
+
+219
+00:18:48,660 --> 00:18:54,340
+الأخضر والأزرق مش مشكلة نحاول نخلي الأزرق والأخضر
+
+220
+00:18:54,340 --> 00:18:58,060
+ييجوا على بعض هاي هاي حلينا المشكلة أزرق و أزرق
+
+221
+00:18:59,060 --> 00:19:07,740
+أخضر و أخضر صار البرتقالي إذا هدولة التنين حقيقة
+
+222
+00:19:07,740 --> 00:19:12,140
+غير مطابقين على بعضهم البعض رغم شدة التشابه اللي
+
+223
+00:19:12,140 --> 00:19:16,080
+بينهم و رغم إنهم صورة بعض في المرأة إذا هنا تتكرر
+
+224
+00:19:16,080 --> 00:19:22,060
+ظاهرة إيش ال handedness إن هدولة زي ال hands واضح؟
+
+225
+00:19:22,450 --> 00:19:26,890
+بالمناسبة كل الأشياء اللي فيها هذه الظاهرة بتكون
+
+226
+00:19:26,890 --> 00:19:30,510
+stereo isomers بمعنى نفس الذرات نفس ال molecular
+
+227
+00:19:30,510 --> 00:19:35,130
+weight كله نفس الاشياء لكن الاختلاف هنا وين بشكل
+
+228
+00:19:35,130 --> 00:19:40,060
+الفراغة بنسميهم enantiomers واضح؟ عشان هيك ال
+
+229
+00:19:40,060 --> 00:19:43,940
+stereo isomers بيقسموا إلى نوعين النوع اللي بنبدأ
+
+230
+00:19:43,940 --> 00:19:47,340
+في هذه المحاضرة و جزء من البعدة اسمه enantiomers و
+
+231
+00:19:47,340 --> 00:19:51,960
+النوع الثاني بعدين بنتعرف عليه اسمه the stereomers
+
+232
+00:19:51,960 --> 00:19:56,700
+اليوم احنا بالإيش؟ بال enantiomers ال enantiomers
+
+233
+00:19:56,700 --> 00:20:00,880
+they are non super imposible mirror image
+
+234
+00:20:00,880 --> 00:20:07,850
+stereoisomers زي شغل الإيدين هما Stereoisomers صورة
+
+235
+00:20:07,850 --> 00:20:12,530
+بعض في المرأة غير متطابقة باللغة الإنجليزية ببساطة
+
+236
+00:20:12,530 --> 00:20:16,650
+إيش بنقول ال Enosomers؟ none, super, imposible
+
+237
+00:20:16,650 --> 00:20:20,410
+يعني غير متطابقة mirror image stereoisomers صورة
+
+238
+00:20:20,410 --> 00:20:29,290
+بعض في المرأة ولكنها غير متطابقة مظبوط ولا لأ؟ مين
+
+239
+00:20:29,290 --> 00:20:35,000
+تعرفيلنا إياهم؟ إيش هما ال Enosomers؟ تفضلي ..
+
+240
+00:20:35,000 --> 00:20:40,640
+تفضلي .. اه حاضر .. اه تفضلي .. non super .. non
+
+241
+00:20:40,640 --> 00:20:46,240
+super .. imposible .. non super imposible .. non
+
+242
+00:20:46,240 --> 00:20:47,940
+super imposible mirror image .. non super
+
+243
+00:20:47,940 --> 00:20:49,760
+imposible mirror image .. non super imposible
+
+244
+00:20:49,760 --> 00:20:50,040
+mirror image .. non super imposible mirror image
+
+245
+00:20:50,040 --> 00:20:50,140
+imposible mirror image .. non super imposible
+
+246
+00:20:50,140 --> 00:20:50,560
+mirror image .. non super imposible mirror image
+
+247
+00:20:50,560 --> 00:20:50,680
+.. non super imposible mirror image .. non super
+
+248
+00:20:50,680 --> 00:20:50,780
+imposible mirror image .. non super imposible
+
+249
+00:20:50,780 --> 00:20:51,140
+imposible mirror image .. non super imposible
+
+250
+00:20:51,140 --> 00:20:51,680
+mirror image .. non super imposible mirror image
+
+251
+00:20:51,680 --> 00:20:52,960
+imposible mirror image .. non super imposible
+
+252
+00:20:52,960 --> 00:20:55,620
+mirror image .. non super imposible mirror image
+
+253
+00:20:55,620 --> 00:20:58,040
+.. non super imposible mirror image .. non super
+
+254
+00:20:58,040 --> 00:21:02,780
+imposible mirror image .. non super imposible
+
+255
+00:21:02,780 --> 00:21:03,960
+mirror
+
+256
+00:21:07,430 --> 00:21:12,350
+آخر الحصة بدنا نعطيها إياه، ماشي الحال ولا لأ؟ ها
+
+257
+00:21:12,350 --> 00:21:16,910
+احنا أقولها لك، بدنا نعطيك إياه، الآن لو أجيت
+
+258
+00:21:16,910 --> 00:21:23,730
+سألتكم، في شرط عشان نعطيها إياه، عارفين شو هو
+
+259
+00:21:23,730 --> 00:21:27,290
+الشرط؟ إنها تحلف ليمين أي واحد اللي قلت لها بده
+
+260
+00:21:27,290 --> 00:21:27,850
+أعطيك إياه
+
+261
+00:21:32,320 --> 00:21:37,820
+لأ، يمين رسمي، مش تخميني أنه واحد فيهم اللي أنا
+
+262
+00:21:37,820 --> 00:21:43,180
+قلت لها بتعطيك إياه بثقة مائة في المائة هل تستطيع
+
+263
+00:21:43,180 --> 00:21:51,200
+أن تجيب؟ خلاص، راحت عليها الجائزة، مشكلة إذا أنا
+
+264
+00:21:51,200 --> 00:21:55,340
+بعد ما شفت هدول اللي فيهم تشابه كبير صرت عندي
+
+265
+00:21:55,340 --> 00:22:00,260
+مشكلة جديدة إن كيف بدي أميزهم عن بعض؟ عشان بعد شوية
+
+266
+00:22:00,260 --> 00:22:03,540
+لما تقول أبنان أعطيك إياها تتطلع، تقول خلاص، أعرف
+
+267
+00:22:03,540 --> 00:22:09,400
+أنا اللي بدي أاخده، واضح؟ إذا بيصير السؤال كيف بدي
+
+268
+00:22:09,400 --> 00:22:12,520
+أميز هذا عن هذا؟ أنا هلجأت هذا ماسكه بالإيدي
+
+269
+00:22:12,520 --> 00:22:15,360
+اليمين و هذا بالإيشمال؟ لو إن لفتك شوية ورجعت
+
+270
+00:22:15,360 --> 00:22:20,470
+ماسكهم، شو بدي أعرفكم؟ كيف بدي اميزهم عن بعض؟ بس زي
+
+271
+00:22:20,470 --> 00:22:24,250
+ما أنا بقول إنه في بينهم نوع من الاختلاف ماانطبقوش
+
+272
+00:22:24,250 --> 00:22:27,990
+على بعض، إذا لازم يكون عنده القدرة على إني اميزهم
+
+273
+00:22:27,990 --> 00:22:33,550
+عن بعض، الآن التمييز تبعهم عن بعض سهل، اتخيلوا
+
+274
+00:22:33,550 --> 00:22:38,200
+انهم سيكتوا اي واحد بدي اياكوا اترطبوا الذرات
+
+275
+00:22:38,200 --> 00:22:41,760
+تبعونه أولويات من الأعلى في الـ atomic weight
+
+276
+00:22:41,760 --> 00:22:48,060
+للأقل للأقل للأقل زي ما عملنا لما كنا ناخد الـ CIS
+
+277
+00:22:48,060 --> 00:22:52,360
+والـ Trans والـ Z والـEI زمارز متذاكرين هم ولا لأ؟
+
+278
+00:22:52,360 --> 00:22:56,900
+الآن احنا الأربع ذرات اللي عندنا لو تتذكروا الجدول
+
+279
+00:22:56,900 --> 00:23:04,150
+الدوري كل شيء كله كان عندي floor floor floor يهود
+
+280
+00:23:04,150 --> 00:23:10,350
+والهيدروجين الأقل واحد إذا أي مجموعة فيهم الأقل
+
+281
+00:23:10,350 --> 00:23:15,690
+الهيدروجين بعد هيك لو بدى أتحرك من الأكبر إلى
+
+282
+00:23:15,690 --> 00:23:23,090
+الأصغر أنه أعلى واحد بعده لبروم بعده لكلور الآن
+
+283
+00:23:23,090 --> 00:23:27,890
+عشان أميزهم بمسك الجزيء بمسك الجزيء بخل المجموعة
+
+284
+00:23:27,890 --> 00:23:34,210
+الأقل الخلفهيتفقنا الهيدروجين للخلف، الآن بقاجي
+
+285
+00:23:34,210 --> 00:23:41,350
+أتحرك من الأعلى للأقل للأقل، وين الأعلى؟ اليود،
+
+286
+00:23:41,350 --> 00:23:46,910
+الأقل منه؟ البروم، الأقل منه؟ الكلور، الأقل منه؟
+
+287
+00:23:46,910 --> 00:23:47,050
+الكلور، الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+288
+00:23:47,050 --> 00:23:55,590
+الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+289
+00:23:55,590 --> 00:23:56,990
+الأقل منه؟ الكلور، الأقل منه؟ الكلور، الأقل منه؟
+
+290
+00:23:56,990 --> 00:23:57,510
+الكلور، الأقل منه؟ الكلور، الأقل منه؟ الكلور،
+
+291
+00:23:57,510 --> 00:24:03,150
+الأقل منه؟ اليطلع زيه، خلّينا نمسك التاني، خلّينا
+
+292
+00:24:03,150 --> 00:24:08,610
+أقل مجموعة الهيدروجين للخلف، وبدأ اتحرك من الأعلى
+
+293
+00:24:08,610 --> 00:24:16,990
+للأقل اليود لبروم لكلور، مع قارب الساعة، إذا أنا
+
+294
+00:24:16,990 --> 00:24:21,880
+اقدرت أحصل الاختلاف اللي بينهم كتير تحصل الاختلاف
+
+295
+00:24:21,880 --> 00:24:25,420
+اللي بينهم إنه أنا لما بحطه مبادية معينة بحس إنه
+
+296
+00:24:25,420 --> 00:24:29,460
+أقل مجموعة للخلف وبعدين بنتقل من الأعلى للأقل
+
+297
+00:24:29,460 --> 00:24:37,540
+للأقل اما أن أتحرك مع عقارب الساعة أو أتحرك عكس
+
+298
+00:24:37,540 --> 00:24:44,160
+عقارب الساعة الآن إذا تحركت مع عقارب الساعة باعطي
+
+299
+00:24:44,160 --> 00:24:49,980
+للجزء الرمز R R جاية من إيش؟ من اليمين باللاتيني
+
+300
+00:24:50,990 --> 00:24:57,650
+بعطي إيش الرمز؟ R إذا تحركت مع عقارب الساعة بعطي R
+
+301
+00:24:57,650 --> 00:25:04,570
+إذا تحركت عكس عقارب الساعة بعطي S هذه ال S بس
+
+302
+00:25:04,570 --> 00:25:08,750
+مقدمة لكن لو إجيت الآن قولت أنا بدي أسمي هذا
+
+303
+00:25:08,750 --> 00:25:14,110
+المركب كاملاً هذا عبارة عن Carbon واحدة إذا هو
+
+304
+00:25:14,110 --> 00:25:20,570
+مشتقة Methane الكربل الواحدة مشتقة مثين عليها تلت
+
+305
+00:25:20,570 --> 00:25:26,370
+مجموعات إبروم وكلور وايود حسب الترتيب ال
+
+306
+00:25:26,370 --> 00:25:33,830
+alphabetical هذا المركب اسمه إبرومو إكلورو أيودو
+
+307
+00:25:33,830 --> 00:25:40,660
+مثين في خلاف عليها؟ لا ابدا ابرومو اكلورو ايودو
+
+308
+00:25:40,660 --> 00:25:45,260
+ميثين هاي من ناحية الذرات الآن لو اجيت للمركب
+
+309
+00:25:45,260 --> 00:25:50,360
+الثاني إيش اسمه؟ نفس الشي لاحظ هنا لأنهم متحدين
+
+310
+00:25:50,360 --> 00:25:55,260
+في الارتباط وفي عدد الذرات abromo-chloro
+
+311
+00:25:55,260 --> 00:26:00,040
+-iodomethane إذا الاسم اللي بيحدد الأنواع الذرات
+
+312
+00:26:00,040 --> 00:26:04,320
+ومواقعها مختلفش بين هذا وهذا هذا abromo-chloro
+
+313
+00:26:04,320 --> 00:26:10,240
+-iodomethane وهذا abromo-chloro-iodomethane ما فيش
+
+314
+00:26:10,240 --> 00:26:15,140
+بينهم اختلاف هوين الاختلاف بدي أبينه أن أحط بادئة
+
+315
+00:26:15,140 --> 00:26:19,160
+اتميز ليهم زي تماما حوالين ال double bond كنا نحط
+
+316
+00:26:19,160 --> 00:26:27,140
+البادئة Cis و Trans أو انعبر عنهم ب Z و E الآن هذا
+
+317
+00:26:27,140 --> 00:26:31,360
+اتطلع عليه مرة ثانية اتذكر واحد اثنين ثلاثة هذا
+
+318
+00:26:31,360 --> 00:26:36,540
+بنحط قدامه حرف ال S capital S بين قوسين بيصير S
+
+319
+00:26:36,540 --> 00:26:39,680
+-bromochloroiodomethane
+
+320
+00:26:39,680 --> 00:26:46,280
+وهذا بيصير R-bromochloroiodomethane
+
+321
+00:26:47,190 --> 00:26:51,190
+زي تماما ما كنتوا تقولوا اسم two بيوتين مشترك two
+
+322
+00:26:51,190 --> 00:26:56,090
+بيوتين و two بيوتين بإيش بنفرجهم عن بعض هذا بنحطله
+
+323
+00:26:56,090 --> 00:27:00,530
+بادئة cis هذا بنحطله بادئة trans الآن في حالة هدول
+
+324
+00:27:00,530 --> 00:27:05,210
+المركبات اللي احنا بنسميهم enantiomers بنحط إيش
+
+325
+00:27:05,210 --> 00:27:10,790
+البادئة؟ R و S اللي مع عقارب الساعة R اللي ضد
+
+326
+00:27:10,790 --> 00:27:16,550
+عقارب الساعة S واضح؟ الآن هذا الكلام أنا بتابعني
+
+327
+00:27:16,550 --> 00:27:21,290
+صرته أنتوا أتقنتوه من خلال إنه احنا مسكين الجزائر
+
+328
+00:27:21,290 --> 00:27:26,130
+لكن الإشكالية إنه احنا لو بدنا نيجي نسألكوا حقيقة
+
+329
+00:27:26,130 --> 00:27:32,250
+في الامتحان ما بنخليكوا مش تمسكوا الجزائر بنرسملكم
+
+330
+00:27:33,930 --> 00:27:37,550
+نرسملكم على اللوح أو على الورقة وبنقولكوا حددونا
+
+331
+00:27:37,550 --> 00:27:42,890
+هذا المركب R ولا S إذا بيصير سؤالي كيف بدي أحدد هذا
+
+332
+00:27:42,890 --> 00:27:47,790
+R ولا S لما أكون أنا راسمه خليني آخد واحد منهم
+
+333
+00:27:47,790 --> 00:27:52,870
+واتأكد منه في الأول بالشكل العام هل هو R ولا S هذا
+
+334
+00:27:52,870 --> 00:28:00,750
+اللي أنا ماسكه، شو هو؟ يود؟ إبروم؟ إكلور؟ هذا R
+
+335
+00:28:00,750 --> 00:28:06,800
+خلاص ال S خلصت منه بديش أشوفه إذا أنا اللي ماسكه
+
+336
+00:28:06,800 --> 00:28:11,260
+يعني قادر أشوفه بالظبط إنه R ولا لأ؟ قادر أشوفه
+
+337
+00:28:11,260 --> 00:28:16,880
+أنه R بدي أرجع أرسمه على اللوح الآن أنا بإمكاني
+
+338
+00:28:16,880 --> 00:28:20,000
+أرسمه طرق مختلفة طبعاً تكونوا أنتوا متذكري إن احنا
+
+339
+00:28:20,000 --> 00:28:24,460
+اتفقنا الجزء حوالين ال carbon نقول رابطتين زي هيك
+
+340
+00:28:24,460 --> 00:28:30,460
+للأمام ورابطتين للخلف بنرسمه على شكل cross بس
+
+341
+00:28:30,460 --> 00:28:35,030
+المفهوم أن الويجيه أفقيات للأمام هيك رايحين واللي
+
+342
+00:28:35,030 --> 00:28:40,870
+بيجوا رأسيات رايحين لوين؟ للخلف الآن يا تورا لو
+
+343
+00:28:40,870 --> 00:28:50,610
+هذا الجزء اجينا مسكناه زي هيك ممكن نرسمه زي هيك؟
+
+344
+00:28:50,610 --> 00:29:00,470
+إيش بدنا نحط هنا؟ claw هنا إبروم هنا هنا
+
+345
+00:29:02,270 --> 00:29:06,090
+ممكن نجرب نمسكه بطريقة ثانية، حد مش ممنعنا كيف
+
+346
+00:29:06,090 --> 00:29:11,770
+نمسكه، أنا بمسكه بمليون طريقة، كويس؟ لكن لحظة أنا
+
+347
+00:29:11,770 --> 00:29:16,290
+ماسك جزيقه برسم يعني، المفروض إنه مايتغيرش، إيش
+
+348
+00:29:16,290 --> 00:29:21,270
+أنا بضحك؟ هاي الدرجان، كلاو، كلاو، كلاو، كلاو،
+
+349
+00:29:21,270 --> 00:29:23,090
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+350
+00:29:23,090 --> 00:29:25,170
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+351
+00:29:25,170 --> 00:29:25,770
+كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو، كلاو،
+
+352
+00:29:25,770 --> 00:29:31,290
+كلاو، كلاو،
+
+353
+00:29:39,820 --> 00:29:55,240
+ممكن أمسكه بطريقة رابعة هذا
+
+354
+00:29:55,240 --> 00:29:59,080
+كله أرسم لنفس الجذيل يعني الجذيل اللي أنا مازكه R
+
+355
+00:29:59,080 --> 00:30:05,280
+ولا S إذا أتوا مش متأكدين لسه أتأكدوا R U دي بروم
+
+356
+00:30:05,280 --> 00:30:09,300
+نيجي
+
+357
+00:30:09,300 --> 00:30:14,080
+على اللوح احنا رسمنا ال R بطرق مختلفة انحدد اقل
+
+358
+00:30:14,080 --> 00:30:24,060
+مجموعة اقل مجموعة و
+
+359
+00:30:24,060 --> 00:30:28,700
+بعدين نيجي نتحرك من الأعلى للأقل للأقل ونشوف إيش
+
+360
+00:30:28,700 --> 00:30:35,230
+اللي بيطلع عندنا إذا اتحركنا نقع لوحدة يود بروم
+
+361
+00:30:35,230 --> 00:30:38,630
+بكلور
+
+362
+00:30:38,630 --> 00:30:43,410
+هينا ماشي هيك كيف أنا متحرك مع قرب الساعة إذا هذا
+
+363
+00:30:43,410 --> 00:30:48,970
+المركب R في عندي مشكلة زي ما بقينا على رأسنا قصة
+
+364
+00:30:48,970 --> 00:30:54,950
+سهلة جداً نيجي هنا نتطلع كمان مرة والأعلى واحدة
+
+365
+00:30:54,950 --> 00:31:01,030
+بعدها بعدها كيف
+
+366
+00:31:01,030 --> 00:31:06,960
+أنا متحرك مع القرن الساعة، إذا هذا R نيجي على
+
+367
+00:31:06,960 --> 00:31:12,480
+المركب اللي بعده يود،
+
+368
+00:31:12,480 --> 00:31:20,020
+إبروم، حينيكا، إفلون، كيف صارت أتحرك؟ صار عندي
+
+369
+00:31:20,020 --> 00:31:23,840
+مشكلة، طب أنا اللي ماسكه راسمه R، الاسم، حطناه
+
+370
+00:31:23,840 --> 00:31:27,320
+بعيد عنه لحظة وأنا صار عندي مشكلة، تشوفها بتتكرر
+
+371
+00:31:27,320 --> 00:31:36,220
+ولا لأ؟ اه، لو يقولنا أشهر على
+
+401
+00:34:15,820 --> 00:34:20,140
+وأنتم من نفس الجهة بيصير عندكم مشكلة طب كيف بتحل
+
+402
+00:34:20,140 --> 00:34:23,380
+هذه المعضلة؟
+
+403
+00:34:23,380 --> 00:34:28,840
+بتعرفوا المثل اللي بيقول صدمة بتضيع صدمة؟ ولا 
+
+404
+00:34:28,840 --> 00:34:34,160
+minus ضرب minus بيساوي زائد؟ الآن أنا هنا في عندي
+
+405
+00:34:34,160 --> 00:34:39,260
+خطأ إن المجموعة اللي أصل تكون للخلف مرسومة للأمام
+
+406
+00:34:39,260 --> 00:34:43,140
+طالما أنه على أحد الجانبين فهي للأمام بقول غلطة
+
+407
+00:34:43,140 --> 00:34:48,920
+بتضيع غلطة باجي لما أحدد ال configuration بقرا إيش 
+
+408
+00:34:48,920 --> 00:34:53,640
+طلع عندي ال configuration و بكتب عكسه كأن عملت عكس
+
+409
+00:34:53,640 --> 00:34:55,660
+في عكس بتطلع الجواب عندكم صح
+
+410
+00:34:58,290 --> 00:35:01,850
+بتكتشفوا و تفهموها بشكل قاتل، إذا أقل مجموعة عندكم 
+
+411
+00:35:01,850 --> 00:35:05,650
+موجودة لِفوق أو لتحت، امشوا من الأعلى للأقل و حطوا 
+
+412
+00:35:05,650 --> 00:35:10,050
+الجواب مباشرة، بتكونوا اشتغلتوا صح. الآن، إذا أقل
+
+413
+00:35:10,050 --> 00:35:17,450
+مجموعة موجودة على أحد الجانبين،
+
+414
+00:35:17,450 --> 00:35:22,550
+امشوا من الأعلى للأقل و اكتبوا عكس الجواب، تتعبوش
+
+415
+00:35:22,550 --> 00:35:27,830
+أعصابكم؟ امشوا زي ما احنا متفقين بس طالما أقل 
+
+416
+00:35:27,830 --> 00:35:31,810
+مجموعة محطوطة على الجانب وكتبوا عكس الجواب بتكونوا
+
+417
+00:35:31,810 --> 00:35:36,890
+عملتوها الصح ليش؟ لأن هذه المجموعة للأمام معكوسة
+
+418
+00:35:36,890 --> 00:35:42,250
+فأنتم الجواب اللي بتطلعوه بتعكسه واضح؟ وعشان كذا لما 
+
+419
+00:35:42,250 --> 00:35:46,030
+أنا هنا بمشي يود ال brom و الchloro وهذه أقل
+
+420
+00:35:46,030 --> 00:35:52,330
+مجموعة على الجانب بتبقى I ببينها S بتقول S بصوت
+
+421
+00:35:53,740 --> 00:35:58,680
+بصوت واطي و بحد يسمعه، بس لازم ينسمع الاسم، لأنه
+
+422
+00:35:58,680 --> 00:36:08,140
+إيش؟ لأنه من الحروف الصفير والهمس، مهموس و أفحته 
+
+423
+00:36:08,140 --> 00:36:12,660
+شخص سكت، مظبوط ولا لأ؟ أه من الحروف الصفير والهمس،
+
+424
+00:36:12,660 --> 00:36:19,600
+بتسمعه، بتقول هي بصوت واطي، و بتكتبوه آه، بتكون
+
+425
+00:36:19,600 --> 00:36:25,160
+حطيته الجواب الصحيح كأنكم اكتشفتم إن في عندكم غلطة
+
+426
+00:36:25,160 --> 00:36:29,840
+في المجموعة أنها مش مرسومة للخلف مرسومة للأمام و
+
+427
+00:36:29,840 --> 00:36:34,080
+الشرط تكون مرسومة للخلف بتحط بناها هذا المركب نفس
+
+428
+00:36:34,080 --> 00:36:45,200
+الشيء باجي بقول you'd بقول كتابة
+
+429
+00:36:45,200 --> 00:36:52,660
+الصحيح باضح؟ وبهيك بنقدر احنا نحدد ال configuration
+
+430
+00:36:52,660 --> 00:36:58,980
+لأي جزء .. بهيك بنقدر احنا نحدد ال configuration
+
+431
+00:36:58,980 --> 00:37:08,100
+لأي جزء .. الآن كتير كلام شرحناه لكم و احنا
+
+432
+00:37:08,100 --> 00:37:12,980
+واقفينه وجلبنا صفحات كتيرة خلينا نمشي عليها بسرعة 
+
+433
+00:37:12,980 --> 00:37:16,260
+في ال computer و تشوف إنه فعلا أخذنا هذه الأشياء 
+
+434
+00:37:16,260 --> 00:37:21,480
+ولا لأ، باقي صفحة ال isomers هنعود نرجع لها في هدوء
+
+435
+00:37:21,480 --> 00:37:29,480
+الآن عرفنا إيش معنى pair of enantiomers واضح؟ لما
+
+436
+00:37:29,480 --> 00:37:34,020
+يكون عندي carbon بتحمل أربع مجموعات مختلفة الآن
+
+437
+00:37:34,020 --> 00:37:37,040
+هذه ال carbon اللي بتحمل أربع مجموعات مختلفة
+
+438
+00:37:37,040 --> 00:37:42,440
+بنسميها كايرال كاربون إيش معنى كايرال كاربون؟ 
+
+439
+00:37:42,440 --> 00:37:47,190
+بتحمل أربع مجموعات مختلفة، إذا حصل هذا الكلام زي 
+
+440
+00:37:47,190 --> 00:37:53,850
+الحالة اللي عندنا فالجزء و صورته في المرأة بيكونوا
+
+441
+00:37:53,850 --> 00:37:58,430
+غير متطابقين و بيطلع عندنا تعريف الانان شمارز 
+
+442
+00:37:58,430 --> 00:38:05,110
+والانان شمارز دائما هي عبارة عن زوج واضح؟ زوج هذا 
+
+443
+00:38:05,110 --> 00:38:11,350
+و هذا فردتين انان شمارز الآن شرط وجود الانان شمارز
+
+444
+00:38:11,350 --> 00:38:17,050
+زي ما قلنا أنه يكون يكون أربع روابط مختلفة على
+
+445
+00:38:17,050 --> 00:38:21,530
+كربونة واحدة عشان هيك دائما احنا بنعلم الكربونة 
+
+446
+00:38:21,530 --> 00:38:26,490
+اللي عليها أربع مجموعات مختلفة بنجمة وبنقول هنا في
+
+447
+00:38:26,490 --> 00:38:30,190
+عندي stereogenic center يعني مركز لل
+
+448
+00:38:30,190 --> 00:38:35,090
+stereochemistry أو chiral center أو chiral carbon
+
+449
+00:38:35,090 --> 00:38:38,950
+كله نفس الأشياء ال carbon اللي حامل أربع مجموعات
+
+450
+00:38:38,950 --> 00:38:42,690
+مختلفة شو بسميها؟ chiral carbon, chiral center,
+
+451
+00:38:42,910 --> 00:38:46,740
+stereogenic center الآن احنا حاطين لكم هنا بعض
+
+452
+00:38:46,740 --> 00:38:49,960
+الرسومات تشوفوا أي carbon عليها أربع مجموعات
+
+453
+00:38:49,960 --> 00:38:53,840
+مختلفة اللي عليها أربع مجموعات مختلفة اللي حاطين
+
+454
+00:38:53,840 --> 00:38:59,600
+عليها نجمة يعني الجزء الأول بس carbon واحدة حاملة 
+
+455
+00:38:59,600 --> 00:39:02,560
+أربع مجموعات مختلفة طبعا المبينين ثلاثة الرابعة هي
+
+456
+00:39:02,560 --> 00:39:08,360
+إيش؟ ال H و الجزء الثاني نفس الشيء عليه كلور و عليه
+
+457
+00:39:08,360 --> 00:39:13,880
+مثل و عليه المجموعة الكبيرة الأخيرة و عليه هذه فقط 
+
+458
+00:39:13,880 --> 00:39:18,520
+الكاربون الكايرال كاربون اللي عليها كم مجموعة
+
+459
+00:39:18,520 --> 00:39:25,280
+مختلفة أربع مجموعات مختلفة نأجل هذا ال slide الآن
+
+460
+00:39:25,280 --> 00:39:31,270
+كيف نحدد ال configuration الـ R و ال S أخذنا قولنا
+
+461
+00:39:31,270 --> 00:39:37,770
+أقل مجموعة بنخليها لِورى و بعدين بنبدأ من الأعلى
+
+462
+00:39:37,770 --> 00:39:45,560
+للأقل للأقل و بنمشي على إذا كان عندنا مع عقارب
+
+463
+00:39:45,560 --> 00:39:50,220
+الساعة بيكون عندي R باللاتيني rectus يعني إحنا 
+
+464
+00:39:50,220 --> 00:39:54,740
+ماشيين مع عقارب الساعة أو right وإذا عندي عكس
+
+465
+00:39:54,740 --> 00:39:59,820
+عقارب الساعة بيكون عندي S sinister أو left ماشيين
+
+466
+00:39:59,820 --> 00:40:04,360
+عكس عقارب الساعة القواعد اللي بناخدها لِإن نقول هذه
+
+467
+00:40:04,360 --> 00:40:08,600
+الأعلى و الأقل و الأقل أخذناها لما حددنا ال sexual
+
+468
+00:40:08,600 --> 00:40:14,370
+trans بتعتمد على ال atomic number وإذا أول مجموعة
+
+469
+00:40:14,370 --> 00:40:18,630
+ما حلتليش بروح على اللي بعده أخدنا تفصيل كتير
+
+470
+00:40:18,630 --> 00:40:24,630
+فيها الآن هي عندكم مجموعة من الأمثلة حاطين احنا
+
+471
+00:40:24,630 --> 00:40:31,290
+لها كمساعدة لكم ال configuration ممكن نختم اليوم
+
+472
+00:40:31,290 --> 00:40:37,310
+أن نتطلع على بعض هذه الأمثلة تطلعوا معه إيش
+
+473
+00:40:37,310 --> 00:40:44,690
+بتلاحظوا؟ إنه أنا أقل مجموعة في المثال الأول اللي
+
+474
+00:40:44,690 --> 00:40:48,650
+هي ال H حاططها وين فوق أو تحت، إذا ال
+
+475
+00:40:48,650 --> 00:40:54,190
+configuration هيطلع مباشرة، ما عكسش، فلو بتتطلع على
+
+476
+00:40:54,190 --> 00:40:57,290
+المثال اللي فوق، أعلى مجموعة ال U بعدين ال brom،
+
+477
+00:40:57,290 --> 00:41:03,170
+بعدين ال chlorine، كيف ماشيين؟ R، الآن تطلع على
+
+478
+00:41:03,170 --> 00:41:09,190
+المثال اللي تحته الـ H على الجانب إذا الجواب 
+
+479
+00:41:09,190 --> 00:41:13,370
+اللي بيطلع عندي لازم أعكسه امشي و يدبرو مكلور
+
+480
+00:41:13,370 --> 00:41:22,190
+انبعينه R بكتب S خدوا المثال اللي بعد هذا المثال
+
+481
+00:41:22,190 --> 00:41:31,770
+إيش المجموعات اللي عندي عندي مثل إثل إبروم و H أقل 
+
+482
+00:41:31,770 --> 00:41:37,020
+مجموعة الهيدروجين محطوطة على الجانب إذا في نهاية
+
+483
+00:41:37,020 --> 00:41:40,900
+الجواب اللي عندي هينكس أنهي أعلى البروم ولا ال مثل 
+
+484
+00:41:40,900 --> 00:41:45,060
+والإثل البروم لأن البروم هالوجي للمثل والإثل
+
+485
+00:41:45,060 --> 00:41:50,760
+كاربون في النهاية فالبروم أعلى واحدة بعد البروم
+
+486
+00:41:50,760 --> 00:41:55,040
+مين بيجي أعلى ال إثل ولا المثل ال إثل أعلى كاربون
+
+487
+00:41:55,040 --> 00:42:01,800
+و بعدها كاربون فبناء على ذلك بتكون عندي بروم إثل
+
+488
+00:42:01,800 --> 00:42:11,380
+انبعينا S بكتب R ليش؟ لأنه هذا على الجانب واضح؟ لو 
+
+489
+00:42:11,380 --> 00:42:16,800
+تتطلع على .. بديش أخد أنا كل الأمثلة لكن خلينا 
+
+490
+00:42:16,800 --> 00:42:22,980
+نقول ننتهي بهذا المثال أقل
+
+491
+00:42:22,980 --> 00:42:28,060
+مجموعة الـ H الآن بعد ذلك إيش متصل عندي في ال
+
+492
+00:42:28,060 --> 00:42:35,630
+carbon؟ O و Carbon و carbon إن هو أعلى ال O بعدك
+
+493
+00:42:35,630 --> 00:42:38,910
+هذه ال carbon متصلة بتلاتة edges هذه ال carbon
+
+494
+00:42:38,910 --> 00:42:45,870
+متصلة ب O و ب O و ب CH3 هان .. هان ال carbon اللي
+
+495
+00:42:45,870 --> 00:42:52,210
+متصلة بال O اللي حملة A إذا إن هي أعلى A بناء على
+
+496
+00:42:52,210 --> 00:42:59,340
+ذلك الترتيب اللي عندي هاي واحد اثنين ثلاثة مبينأس
+
+497
+00:42:59,340 --> 00:43:04,340
+بكتب أ كل الأمثلة هذه بإمكانكم بهدوء تعملوها في
+
+498
+00:43:04,340 --> 00:43:10,560
+البيت و بإمكانكم تتحققوا من الإجابة شكرا لكم
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..84c9bd3a7218b01a5f667e982e6de6f63ff2dc20
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/uUrLhVX-LwI_raw.json
@@ -0,0 +1 @@
+{"segments": [{"id": 1, "seek": 2257, "start": 9.63, "end": 22.57, "text": "اليوم موضوعنا فصل جديد و ممتع هو الفصل المعنوان stereochemistry معنى stereochemistry", "tokens": [6027, 1829, 20498, 3714, 2407, 11242, 45367, 8315, 6156, 36520, 10874, 16254, 3215, 4032, 3714, 2304, 2655, 3615, 31439, 27188, 36520, 9673, 3615, 1863, 2407, 7649, 12730, 8997, 443, 5980, 20449, 1863, 7578, 12730, 8997, 443, 5980], "avg_logprob": -0.11615954006188794, "compression_ratio": 1.2959183673469388, "no_speech_prob": 4.172325134277344e-07, "words": [{"start": 9.63, "end": 10.39, "word": "اليوم", "probability": 0.9601236979166666}, {"start": 10.39, "end": 11.31, "word": " موضوعنا", "probability": 0.99638671875}, {"start": 11.31, "end": 12.71, "word": " فصل", "probability": 0.9228515625}, {"start": 12.71, "end": 13.49, "word": " جديد", "probability": 0.99609375}, {"start": 13.49, "end": 13.95, "word": " و", "probability": 0.99267578125}, {"start": 13.95, "end": 15.17, "word": " ممتع", "probability": 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{"start": 138.81, "end": 138.97, "word": " can", "probability": 0.96533203125}, {"start": 138.97, "end": 139.23, "word": " see", "probability": 0.93701171875}, {"start": 139.23, "end": 139.73, "word": " different", "probability": 0.89111328125}, {"start": 139.73, "end": 140.65, "word": " compounds", "probability": 0.935546875}, {"start": 140.65, "end": 141.37, "word": " that", "probability": 0.943359375}, {"start": 141.37, "end": 141.73, "word": " have", "probability": 0.96728515625}, {"start": 141.73, "end": 141.95, "word": " the", "probability": 0.93359375}, {"start": 141.95, "end": 142.31, "word": " same", "probability": 0.9150390625}, {"start": 142.31, "end": 142.83, "word": " molecular", "probability": 0.7734375}, {"start": 142.83, "end": 144.17, "word": " formula،", "probability": 0.73193359375}, {"start": 144.17, "end": 144.31, "word": " اللي", "probability": 0.6949462890625}, {"start": 144.31, "end": 144.39, "word": " هو", "probability": 0.48779296875}, {"start": 144.39, "end": 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تلاحظوا هدول ال constitutional isomers أو ال structural isomers إيش تعريفهم بتلاقوا القاتل", "tokens": [2407, 46958, 5016, 6156, 28814, 15730, 12174, 1211, 8315, 20176, 307, 298, 433, 34051, 12174, 1211, 8315, 15067, 307, 298, 433, 8717, 36178, 9673, 3615, 1863, 7578, 436, 743, 294, 264, 28824, 294, 264, 3877, 2423, 7649, 45164, 39894, 19452, 6055, 15040, 5016, 19913, 14407, 8032, 3215, 12610, 2423, 20176, 307, 298, 433, 34051, 2423, 15067, 307, 298, 433, 11933, 1829, 8592, 37279, 16572, 5172, 16095, 39894, 15040, 4587, 14407, 25062, 9307, 1211], "avg_logprob": -0.1691300691785039, "compression_ratio": 1.6304347826086956, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 178.91, "end": 179.41, "word": "واضح", "probability": 0.978515625}, {"start": 179.41, "end": 180.29, "word": " فإذا", "probability": 0.71728515625}, {"start": 180.29, "end": 180.73, "word": " قلنا", "probability": 0.92822265625}, {"start": 180.73, "end": 181.95, "word": " constitutional", "probability": 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"start": 384.29, "end": 407.71, "text": "ميثانول المركب التاني داي مثل إيثر إذا ال structural isomers they have different names ليش؟ لأن ال name أو الاسم للمركب بيعبر عن .. عن structure عن ذرات طالما ال structure اختلف إذا الاسم اختلف نفس الاشي هنا", "tokens": [2304, 1829, 12984, 7649, 12610, 9673, 31747, 3555, 16712, 7649, 1829, 11778, 47302, 50113, 1211, 11933, 1829, 49115, 11933, 15730, 2423, 15067, 307, 298, 433, 436, 362, 819, 5288, 32239, 8592, 22807, 5296, 33456, 2423, 1315, 34051, 2423, 32277, 2304, 5296, 19528, 31747, 3555, 4724, 1829, 3615, 3555, 2288, 18871, 4386, 18871, 3877, 18871, 29910, 2288, 9307, 23032, 6027, 15042, 2423, 3877, 1975, 46456, 46538, 11933, 15730, 2423, 32277, 2304, 1975, 46456, 46538, 8717, 36178, 2423, 33599, 1829, 34105], "avg_logprob": -0.2820312425494194, "compression_ratio": 1.6269430051813472, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 384.29, "end": 385.01, "word": "ميثانول", "probability": 0.7642578125}, {"start": 385.01, "end": 385.91, "word": " المركب", "probability": 0.74609375}, {"start": 385.91, "end": 386.55, "word": " التاني", "probability": 0.9182942708333334}, {"start": 386.55, "end": 387.93, "word": " داي", "probability": 0.295562744140625}, {"start": 387.93, "end": 388.63, "word": " مثل", "probability": 0.977294921875}, {"start": 388.63, "end": 389.21, "word": " إيثر", "probability": 0.6629231770833334}, {"start": 389.21, "end": 389.85, "word": " إذا", "probability": 0.669921875}, {"start": 389.85, "end": 390.03, "word": " ال", "probability": 0.77197265625}, {"start": 390.03, "end": 390.85, "word": " structural", "probability": 0.366943359375}, {"start": 390.85, "end": 391.95, "word": " isomers", "probability": 0.9637044270833334}, {"start": 391.95, "end": 392.27, "word": " they", "probability": 0.4775390625}, {"start": 392.27, "end": 392.93, "word": " have", "probability": 0.97021484375}, {"start": 392.93, "end": 394.75, "word": " different", "probability": 0.92626953125}, {"start": 394.75, "end": 395.37, "word": " names", "probability": 0.908203125}, {"start": 395.37, "end": 397.61, "word": " ليش؟", "probability": 0.6039225260416666}, {"start": 397.61, "end": 397.83, "word": " لأن", "probability": 0.86572265625}, {"start": 397.83, "end": 398.09, "word": " ال", "probability": 0.87451171875}, {"start": 398.09, "end": 398.59, "word": " name", "probability": 0.9296875}, {"start": 398.59, "end": 398.83, "word": " أو", "probability": 0.91943359375}, {"start": 398.83, "end": 399.31, "word": " الاسم", "probability": 0.7686360677083334}, {"start": 399.31, "end": 399.99, "word": " للمركب", "probability": 0.8712158203125}, {"start": 399.99, "end": 400.55, "word": " بيعبر", "probability": 0.6111328125}, {"start": 400.55, "end": 400.91, "word": " عن", "probability": 0.98193359375}, {"start": 400.91, "end": 401.11, "word": " ..", "probability": 0.33935546875}, {"start": 401.11, "end": 401.79, "word": " عن", "probability": 0.86328125}, {"start": 401.79, "end": 402.33, "word": " structure", "probability": 0.6943359375}, {"start": 402.33, "end": 402.55, "word": " عن", "probability": 0.68994140625}, {"start": 402.55, "end": 402.97, "word": " ذرات", "probability": 0.9363606770833334}, {"start": 402.97, "end": 403.29, "word": " طالما", "probability": 0.9493815104166666}, {"start": 403.29, "end": 403.43, "word": " ال", "probability": 0.94677734375}, {"start": 403.43, "end": 403.81, "word": " structure", "probability": 0.89404296875}, {"start": 403.81, "end": 404.27, "word": " اختلف", "probability": 0.8494466145833334}, {"start": 404.27, "end": 404.53, "word": " إذا", "probability": 0.861572265625}, {"start": 404.53, "end": 405.15, "word": " الاسم", "probability": 0.8631184895833334}, {"start": 405.15, "end": 406.29, "word": " اختلف", "probability": 0.95458984375}, {"start": 406.29, "end": 406.89, "word": " نفس", "probability": 0.969970703125}, {"start": 406.89, "end": 407.39, "word": " الاشي", "probability": 0.7974446614583334}, {"start": 407.39, "end": 407.71, "word": " هنا", "probability": 0.92822265625}], "temperature": 1.0}, {"id": 18, "seek": 43644, "start": 408.88, "end": 436.44, "text": "لو كنتوا بتكونوا تسموا هدولة المركبين هتقولوا ortho-dichlorobenzene او one two dichlorobenzene هنا tara-dichlorobenzene او one four dichlorobenzene ملاحظين انتوا ان مواقع الارتباط كلها اختلفت البندج اختلف هذا أبسط نوع من ال isomers اللي مر علينا كتير أمثلة زيه اللي بنسميها ايش", "tokens": [1211, 2407, 9122, 29399, 14407, 39894, 30544, 14407, 6055, 38251, 14407, 8032, 3215, 12610, 3660, 9673, 31747, 3555, 9957, 8032, 2655, 39648, 14407, 19052, 78, 12, 67, 480, 6746, 996, 11368, 1450, 1975, 2407, 472, 732, 10390, 6746, 996, 11368, 1450, 34105, 23837, 12, 67, 480, 6746, 996, 11368, 1450, 1975, 2407, 472, 1451, 10390, 6746, 996, 11368, 1450, 3714, 15040, 5016, 19913, 9957, 16472, 2655, 14407, 16472, 3714, 14407, 4587, 3615, 2423, 9640, 2655, 3555, 41193, 28242, 11296, 1975, 46456, 46538, 2655, 29739, 41260, 7435, 1975, 46456, 46538, 23758, 5551, 3555, 3794, 9566, 8717, 45367, 9154, 2423, 307, 298, 433, 13672, 1829, 3714, 2288, 25894, 8315, 9122, 2655, 13546, 5551, 2304, 12984, 37977, 30767, 1829, 3224, 13672, 1829, 44945, 38251, 1829, 11296, 1975, 1829, 8592], "avg_logprob": -0.20127952849771094, "compression_ratio": 1.7656903765690377, "no_speech_prob": 0.0, "words": [{"start": 408.88, "end": 409.18, "word": "لو", "probability": 0.785400390625}, {"start": 409.18, "end": 409.76, "word": " كنتوا", "probability": 0.9007161458333334}, {"start": 409.76, "end": 410.24, "word": " بتكونوا", "probability": 0.6321614583333334}, {"start": 410.24, "end": 410.58, "word": " تسموا", "probability": 0.90087890625}, {"start": 410.58, "end": 411.0, "word": " هدولة", "probability": 0.761962890625}, {"start": 411.0, "end": 411.9, "word": " المركبين", "probability": 0.8626708984375}, {"start": 411.9, "end": 413.26, "word": " هتقولوا", "probability": 0.8719482421875}, {"start": 413.26, "end": 414.82, "word": " ortho", "probability": 0.4481201171875}, {"start": 414.82, "end": 416.52, "word": "-dichlorobenzene", "probability": 0.813720703125}, {"start": 416.52, "end": 416.82, "word": " او", "probability": 0.801025390625}, {"start": 416.82, "end": 417.02, "word": " one", "probability": 0.646484375}, {"start": 417.02, "end": 417.26, "word": " two", "probability": 0.6396484375}, {"start": 417.26, "end": 418.64, "word": " dichlorobenzene", "probability": 0.869921875}, {"start": 418.64, "end": 419.4, "word": " هنا", "probability": 0.8115234375}, {"start": 419.4, "end": 421.1, "word": " tara", "probability": 0.125}, {"start": 421.1, "end": 423.24, "word": "-dichlorobenzene", "probability": 0.9091099330357143}, {"start": 423.24, "end": 423.8, "word": " او", "probability": 0.970947265625}, {"start": 423.8, "end": 424.62, "word": " one", "probability": 0.9541015625}, {"start": 424.62, "end": 425.1, "word": " four", "probability": 0.93994140625}, {"start": 425.1, "end": 426.26, "word": " dichlorobenzene", "probability": 0.96455078125}, {"start": 426.26, "end": 426.78, "word": " ملاحظين", "probability": 0.8548828125}, {"start": 426.78, "end": 427.06, "word": " انتوا", "probability": 0.7129720052083334}, {"start": 427.06, "end": 427.16, "word": " ان", "probability": 0.578125}, {"start": 427.16, "end": 427.7, "word": " مواقع", "probability": 0.980224609375}, {"start": 427.7, "end": 428.42, "word": " الارتباط", "probability": 0.9041015625}, {"start": 428.42, "end": 428.7, "word": " كلها", "probability": 0.958984375}, {"start": 428.7, "end": 429.3, "word": " اختلفت", "probability": 0.958740234375}, {"start": 429.3, "end": 429.78, "word": " البندج", "probability": 0.6617838541666666}, {"start": 429.78, "end": 430.2, "word": " اختلف", "probability": 0.9798177083333334}, {"start": 430.2, "end": 430.76, "word": " هذا", "probability": 0.8564453125}, {"start": 430.76, "end": 431.26, "word": " أبسط", "probability": 0.8450927734375}, {"start": 431.26, "end": 431.58, "word": " نوع", "probability": 0.9873046875}, {"start": 431.58, "end": 431.92, "word": " من", "probability": 0.99609375}, {"start": 431.92, "end": 432.2, "word": " ال", "probability": 0.95556640625}, {"start": 432.2, "end": 433.06, "word": " isomers", "probability": 0.8688151041666666}, {"start": 433.06, "end": 433.64, "word": " اللي", "probability": 0.783935546875}, {"start": 433.64, "end": 433.86, "word": " مر", "probability": 0.754150390625}, {"start": 433.86, "end": 434.22, "word": " علينا", "probability": 0.941650390625}, {"start": 434.22, "end": 434.54, "word": " كتير", "probability": 0.9558919270833334}, {"start": 434.54, "end": 435.0, "word": " أمثلة", "probability": 0.8902587890625}, {"start": 435.0, "end": 435.4, "word": " زيه", "probability": 0.98291015625}, {"start": 435.4, "end": 435.68, "word": " اللي", "probability": 0.9482421875}, {"start": 435.68, "end": 436.14, "word": " بنسميها", "probability": 0.94140625}, {"start": 436.14, "end": 436.44, "word": " ايش", "probability": 0.751220703125}], "temperature": 1.0}, {"id": 19, "seek": 45553, "start": 436.67, "end": 455.53, "text": "Structural isomers مش هذا موضوعنا اليوم مش هذا موضوعنا اليوم ايش موضوعنا احنا اليوم النوع التاني من ال isomers اللي اسمه ال stereo isomers ال stereo isomers شوية بغلبه بدهم عين", "tokens": [4520, 1757, 1807, 307, 298, 433, 37893, 23758, 3714, 2407, 11242, 45367, 8315, 45595, 20498, 37893, 23758, 3714, 2407, 11242, 45367, 8315, 45595, 20498, 1975, 1829, 8592, 3714, 2407, 11242, 45367, 8315, 1975, 5016, 8315, 45595, 20498, 28239, 45367, 16712, 7649, 1829, 9154, 2423, 307, 298, 433, 13672, 1829, 24525, 2304, 3224, 2423, 29029, 307, 298, 433, 2423, 29029, 307, 298, 433, 13412, 2407, 10632, 4724, 17082, 46152, 3224, 47525, 16095, 6225, 9957], "avg_logprob": -0.17704814269736008, "compression_ratio": 1.8758620689655172, "no_speech_prob": 6.496906280517578e-06, "words": [{"start": 436.67, "end": 437.59, "word": "Structural", "probability": 0.7578125}, {"start": 437.59, "end": 438.23, "word": " isomers", "probability": 0.8435872395833334}, {"start": 438.23, "end": 439.03, "word": " مش", "probability": 0.1287841796875}, {"start": 439.03, "end": 439.37, "word": " هذا", "probability": 0.7626953125}, {"start": 439.37, "end": 439.99, "word": " موضوعنا", "probability": 0.92431640625}, {"start": 439.99, "end": 440.73, "word": " اليوم", "probability": 0.956787109375}, {"start": 440.73, "end": 441.13, "word": " مش", "probability": 0.10089111328125}, {"start": 441.13, "end": 441.37, "word": " هذا", "probability": 0.904296875}, {"start": 441.37, "end": 441.87, "word": " موضوعنا", "probability": 0.972265625}, {"start": 441.87, "end": 442.21, "word": " اليوم", "probability": 0.978759765625}, {"start": 442.21, "end": 442.85, "word": " ايش", "probability": 0.7740885416666666}, {"start": 442.85, "end": 443.33, "word": " موضوعنا", "probability": 0.93798828125}, {"start": 443.33, "end": 443.57, "word": " احنا", "probability": 0.9694010416666666}, {"start": 443.57, "end": 443.99, "word": " اليوم", "probability": 0.958740234375}, {"start": 443.99, "end": 445.19, "word": " النوع", "probability": 0.935791015625}, {"start": 445.19, "end": 445.99, "word": " التاني", "probability": 0.96484375}, {"start": 445.99, "end": 446.21, "word": " من", "probability": 0.9931640625}, {"start": 446.21, "end": 446.39, "word": " ال", "probability": 0.892578125}, {"start": 446.39, "end": 447.21, "word": " isomers", "probability": 0.89794921875}, {"start": 447.21, "end": 447.83, "word": " اللي", "probability": 0.757568359375}, {"start": 447.83, "end": 448.47, "word": " اسمه", "probability": 0.9519856770833334}, {"start": 448.47, "end": 448.67, "word": " ال", "probability": 0.83935546875}, {"start": 448.67, "end": 449.17, "word": " stereo", "probability": 0.489013671875}, {"start": 449.17, "end": 450.35, "word": " isomers", "probability": 0.9485677083333334}, {"start": 450.35, "end": 451.03, "word": " ال", "probability": 0.8271484375}, {"start": 451.03, "end": 451.47, "word": " stereo", "probability": 0.80810546875}, {"start": 451.47, "end": 452.43, "word": " isomers", "probability": 0.98193359375}, {"start": 452.43, "end": 453.05, "word": " شوية", "probability": 0.91015625}, {"start": 453.05, "end": 453.89, "word": " بغلبه", "probability": 0.956298828125}, {"start": 453.89, "end": 455.01, "word": " بدهم", "probability": 0.78125}, {"start": 455.01, "end": 455.53, "word": " عين", "probability": 0.986572265625}], "temperature": 1.0}, {"id": 20, "seek": 48129, "start": 456.65, "end": 481.29, "text": "أو يمكن في أول الأشياء ما تصدقوش ان هدول الأشياء مختلفين عن بعضهم البعض مكتوب فيهم atoms have the same substitution or constitution عفوا the same bonding لهم نفس مواقع الارتباط but different arrangement in space لكن كيف شكلهم بالفراغ بختلف بس مواقع ارتباطهم", "tokens": [10721, 2407, 7251, 43020, 8978, 5551, 12610, 16247, 8592, 1829, 16606, 19446, 6055, 9381, 3215, 4587, 2407, 8592, 16472, 8032, 3215, 12610, 16247, 8592, 1829, 16606, 3714, 46456, 46538, 9957, 18871, 45030, 11242, 16095, 29739, 3615, 11242, 3714, 4117, 2655, 37746, 8978, 16095, 16871, 362, 264, 912, 35827, 420, 11937, 6225, 5172, 14407, 264, 912, 28824, 5296, 16095, 8717, 36178, 3714, 14407, 4587, 3615, 2423, 9640, 2655, 3555, 41193, 457, 819, 17620, 294, 1901, 44381, 9122, 33911, 13412, 28820, 16095, 20666, 5172, 2288, 5718, 118, 4724, 46456, 46538, 4724, 3794, 3714, 14407, 4587, 3615, 1975, 43500, 3555, 41193, 16095], "avg_logprob": -0.20687499940395354, "compression_ratio": 1.6523605150214593, "no_speech_prob": 2.384185791015625e-07, "words": [{"start": 456.65, "end": 457.39, "word": "أو", "probability": 0.38623046875}, {"start": 457.39, "end": 457.69, "word": " يمكن", "probability": 0.5548095703125}, {"start": 457.69, "end": 457.83, "word": " في", "probability": 0.7265625}, {"start": 457.83, "end": 458.17, "word": " أول", "probability": 0.9521484375}, {"start": 458.17, "end": 458.91, "word": " الأشياء", "probability": 0.961669921875}, {"start": 458.91, "end": 459.03, "word": " ما", "probability": 0.279296875}, {"start": 459.03, "end": 459.57, "word": " تصدقوش", "probability": 0.9683430989583334}, {"start": 459.57, "end": 459.69, "word": " ان", "probability": 0.423828125}, {"start": 459.69, "end": 460.01, "word": " هدول", "probability": 0.6814778645833334}, {"start": 460.01, "end": 460.47, "word": " الأشياء", "probability": 0.885498046875}, {"start": 460.47, "end": 461.31, "word": " مختلفين", "probability": 0.9864501953125}, {"start": 461.31, "end": 461.53, "word": " عن", "probability": 0.96240234375}, {"start": 461.53, "end": 462.11, "word": " بعضهم", "probability": 0.92333984375}, {"start": 462.11, "end": 462.61, "word": " البعض", "probability": 0.994140625}, {"start": 462.61, "end": 463.63, "word": " مكتوب", "probability": 0.9544677734375}, {"start": 463.63, "end": 464.11, "word": " فيهم", "probability": 0.95458984375}, {"start": 464.11, "end": 465.17, "word": " atoms", "probability": 0.2193603515625}, {"start": 465.17, "end": 465.73, "word": " have", "probability": 0.916015625}, {"start": 465.73, "end": 465.97, "word": " the", 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0.95654296875}, {"start": 1152.92, "end": 1153.18, "word": " إنهم", "probability": 0.6688232421875}, {"start": 1153.18, "end": 1153.6, "word": " صورة", "probability": 0.9568684895833334}, {"start": 1153.6, "end": 1153.94, "word": " بعض", "probability": 0.9541015625}, {"start": 1153.94, "end": 1154.1, "word": " في", "probability": 0.95654296875}, {"start": 1154.1, "end": 1154.62, "word": " المرأة", "probability": 0.790771484375}, {"start": 1154.62, "end": 1155.12, "word": " إذا", "probability": 0.848388671875}, {"start": 1155.12, "end": 1155.38, "word": " هنا", "probability": 0.93994140625}, {"start": 1155.38, "end": 1156.08, "word": " تتكرر", "probability": 0.9935302734375}, {"start": 1156.08, "end": 1156.58, "word": " ظاهرة", "probability": 0.95947265625}, {"start": 1156.58, "end": 1157.1, "word": " إيش", "probability": 0.91552734375}, {"start": 1157.1, "end": 1157.94, "word": " ال", "probability": 0.71923828125}, {"start": 1157.94, "end": 1158.58, "word": " handedness", "probability": 0.6505126953125}, {"start": 1158.58, "end": 1158.74, "word": " إن", "probability": 0.5107421875}, {"start": 1158.74, "end": 1159.18, "word": " هدولة", "probability": 0.9654541015625}, {"start": 1159.18, "end": 1159.56, "word": " زي", "probability": 0.974365234375}, {"start": 1159.56, "end": 1159.88, "word": " ال", "probability": 0.97509765625}, {"start": 1159.88, "end": 1160.38, "word": " hands", "probability": 0.86279296875}, {"start": 1160.38, "end": 1162.06, "word": " واضح؟", "probability": 0.888427734375}], "temperature": 1.0}, {"id": 47, "seek": 117777, "start": 1162.45, "end": 1177.77, "text": "بالمناسبة كل الأشياء اللي فيها هذه الظاهرة بتكون stereo isomers بمعنى نفس الذرات نفس ال molecular weight كله نفس الاشياء لكن الإختلاف هنا وين بشكل الفراغة بنسميهم enantiomers", "tokens": [3555, 45340, 8315, 35457, 3660, 28242, 16247, 8592, 1829, 16606, 13672, 1829, 8978, 11296, 29538, 6024, 116, 40294, 25720, 39894, 30544, 29029, 307, 298, 433, 4724, 2304, 3615, 1863, 7578, 8717, 36178, 32545, 2288, 9307, 8717, 36178, 2423, 19046, 3364, 28242, 3224, 8717, 36178, 2423, 33599, 1829, 16606, 44381, 33688, 46456, 15040, 5172, 34105, 4032, 9957, 4724, 8592, 28820, 27188, 2288, 5718, 118, 3660, 44945, 38251, 1829, 16095, 465, 11520, 298, 433], "avg_logprob": -0.16834331538579236, "compression_ratio": 1.5326086956521738, "no_speech_prob": 1.1920928955078125e-07, "words": [{"start": 1162.45, "end": 1163.45, "word": "بالمناسبة", "probability": 0.9373046875}, {"start": 1163.45, "end": 1163.95, "word": " كل", "probability": 0.6025390625}, {"start": 1163.95, "end": 1164.57, "word": " الأشياء", "probability": 0.991455078125}, {"start": 1164.57, "end": 1164.79, "word": " اللي", "probability": 0.854248046875}, {"start": 1164.79, "end": 1165.05, "word": " فيها", "probability": 0.96337890625}, {"start": 1165.05, "end": 1165.29, "word": " هذه", "probability": 0.9140625}, {"start": 1165.29, "end": 1165.93, "word": " الظاهرة", "probability": 0.969970703125}, {"start": 1165.93, "end": 1166.89, "word": " بتكون", "probability": 0.86474609375}, {"start": 1166.89, "end": 1167.31, "word": " stereo", "probability": 0.3798828125}, {"start": 1167.31, "end": 1168.03, "word": " isomers", "probability": 0.9298502604166666}, {"start": 1168.03, "end": 1168.75, "word": " بمعنى", "probability": 0.93935546875}, {"start": 1168.75, "end": 1169.01, "word": " نفس", "probability": 0.9873046875}, {"start": 1169.01, "end": 1169.79, "word": " الذرات", "probability": 0.8365885416666666}, {"start": 1169.79, "end": 1170.07, "word": " نفس", "probability": 0.825439453125}, {"start": 1170.07, "end": 1170.17, "word": " ال", "probability": 0.85546875}, {"start": 1170.17, "end": 1170.51, "word": " molecular", "probability": 0.689453125}, {"start": 1170.51, "end": 1170.77, "word": " weight", "probability": 0.873046875}, {"start": 1170.77, "end": 1171.05, "word": " كله", "probability": 0.806640625}, {"start": 1171.05, "end": 1171.29, "word": " نفس", "probability": 0.99560546875}, {"start": 1171.29, "end": 1171.95, "word": " الاشياء", "probability": 0.8546142578125}, {"start": 1171.95, "end": 1172.43, "word": " لكن", "probability": 0.86572265625}, {"start": 1172.43, "end": 1173.17, "word": " الإختلاف", "probability": 0.8721923828125}, {"start": 1173.17, "end": 1173.37, "word": " هنا", "probability": 0.201904296875}, {"start": 1173.37, "end": 1173.75, "word": " وين", "probability": 0.8623046875}, {"start": 1173.75, "end": 1175.13, "word": " بشكل", "probability": 0.8806966145833334}, {"start": 1175.13, "end": 1175.65, "word": " الفراغة", "probability": 0.841162109375}, {"start": 1175.65, "end": 1176.41, "word": " بنسميهم", "probability": 0.85247802734375}, {"start": 1176.41, "end": 1177.77, "word": " enantiomers", "probability": 0.79022216796875}], "temperature": 1.0}, {"id": 48, "seek": 120211, "start": 1178.24, "end": 1202.12, "text": "واضح؟ عشان هيك ال stereo isomers بيقسموا إلى نوعين النوع اللي بنبدأ في هذه المحاضرة و جزء من البعدة اسمه enantiomers و النوع التاني بعدين بنتعرف عليه اسمه the stereomers اليوم احنا بالإيش؟ بال enantiomers ال enantiomers they are non sober invisible mirror image stereoisomers", "tokens": [2407, 46958, 5016, 22807, 6225, 8592, 7649, 39896, 4117, 2423, 29029, 307, 298, 433, 4724, 1829, 4587, 38251, 14407, 30731, 8717, 45367, 9957, 28239, 45367, 13672, 1829, 44945, 44510, 10721, 8978, 29538, 9673, 5016, 46958, 25720, 4032, 10874, 11622, 38207, 9154, 29739, 22488, 3660, 24525, 2304, 3224, 465, 11520, 298, 433, 4032, 28239, 45367, 16712, 7649, 1829, 39182, 9957, 44945, 2655, 3615, 28480, 47356, 24525, 2304, 3224, 264, 12730, 298, 433, 45595, 20498, 1975, 5016, 8315, 20666, 28814, 1829, 8592, 22807, 20666, 465, 11520, 298, 433, 2423, 465, 11520, 298, 433, 436, 366, 2107, 26212, 14603, 8013, 3256, 12730, 7376, 298, 433], "avg_logprob": -0.18431432646455118, "compression_ratio": 1.705128205128205, "no_speech_prob": 3.159046173095703e-06, "words": [{"start": 1178.24, "end": 1178.94, "word": "واضح؟", "probability": 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"probability": 0.97314453125}, {"start": 1184.08, "end": 1184.26, "word": " هذه", "probability": 0.46044921875}, {"start": 1184.26, "end": 1184.9, "word": " المحاضرة", "probability": 0.989990234375}, {"start": 1184.9, "end": 1185.04, "word": " و", "probability": 0.457763671875}, {"start": 1185.04, "end": 1185.3, "word": " جزء", "probability": 0.8924153645833334}, {"start": 1185.3, "end": 1185.48, "word": " من", "probability": 0.994140625}, {"start": 1185.48, "end": 1186.06, "word": " البعدة", "probability": 0.7293294270833334}, {"start": 1186.06, "end": 1186.4, "word": " اسمه", "probability": 0.9676106770833334}, {"start": 1186.4, "end": 1187.12, "word": " enantiomers", "probability": 0.70257568359375}, {"start": 1187.12, "end": 1187.34, "word": " و", "probability": 0.76513671875}, {"start": 1187.34, "end": 1187.58, "word": " النوع", "probability": 0.947021484375}, {"start": 1187.58, "end": 1188.58, "word": " التاني", "probability": 0.9778645833333334}, {"start": 1188.58, "end": 1189.04, "word": " بعدين", "probability": 0.760009765625}, {"start": 1189.04, "end": 1189.66, "word": " بنتعرف", "probability": 0.9102783203125}, {"start": 1189.66, "end": 1189.94, "word": " عليه", "probability": 0.9873046875}, {"start": 1189.94, "end": 1190.54, "word": " اسمه", "probability": 0.97607421875}, {"start": 1190.54, "end": 1191.26, "word": " the", "probability": 0.6435546875}, {"start": 1191.26, "end": 1191.96, "word": " stereomers", "probability": 0.8805338541666666}, {"start": 1191.96, "end": 1192.58, "word": " اليوم", "probability": 0.901123046875}, {"start": 1192.58, "end": 1192.92, "word": " احنا", "probability": 0.9103190104166666}, {"start": 1192.92, "end": 1194.4, "word": " بالإيش؟", "probability": 0.6802978515625}, {"start": 1194.4, "end": 1194.56, "word": " بال", "probability": 0.88916015625}, {"start": 1194.56, "end": 1195.32, "word": " enantiomers", "probability": 0.89501953125}, {"start": 1195.32, "end": 1195.78, "word": " ال", "probability": 0.869140625}, {"start": 1195.78, "end": 1196.7, "word": " enantiomers", "probability": 0.9056396484375}, {"start": 1196.7, "end": 1197.1, "word": " they", "probability": 0.7099609375}, {"start": 1197.1, "end": 1197.82, "word": " are", "probability": 0.953125}, {"start": 1197.82, "end": 1198.56, "word": " non", "probability": 0.89453125}, {"start": 1198.56, "end": 1199.42, "word": " sober", "probability": 0.360595703125}, {"start": 1199.42, "end": 1200.0, "word": " invisible", "probability": 0.6064453125}, {"start": 1200.0, "end": 1200.44, "word": " mirror", "probability": 0.87744140625}, {"start": 1200.44, "end": 1200.88, "word": " image", "probability": 0.8603515625}, {"start": 1200.88, "end": 1202.12, "word": " stereoisomers", "probability": 0.892333984375}], "temperature": 1.0}, {"id": 49, "seek": 123225, "start": 1203.07, "end": 1232.25, "text": "زي شغل الإيدين هما Stereoisomers صورة بعض في المرأة غير متطابقة باللغة الإنجليزية ببساطة إيش بنقول ال Enosomers؟ none, super, imposible يعني غير متطابقة mirror image stereoisomers صورة بعض في المرأة ولكنها غير متطابقة مظبوط ولا لأ؟ مين تعرفيلنا إياهم؟ إيش هما ال Enosomers؟", "tokens": [11622, 1829, 13412, 17082, 1211, 33688, 25708, 9957, 8032, 15042, 745, 323, 7376, 298, 433, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 10721, 3660, 32771, 13546, 44650, 9566, 16758, 28671, 20666, 1211, 17082, 3660, 33688, 1863, 7435, 20292, 11622, 10632, 4724, 3555, 3794, 41193, 3660, 11933, 1829, 8592, 44945, 39648, 2423, 2193, 329, 298, 433, 22807, 6022, 11, 1687, 11, 38396, 964, 37495, 22653, 32771, 13546, 44650, 9566, 16758, 28671, 8013, 3256, 12730, 7376, 298, 433, 20328, 13063, 3660, 45030, 11242, 8978, 9673, 2288, 10721, 3660, 35525, 19452, 11296, 32771, 13546, 44650, 9566, 16758, 28671, 3714, 19913, 3555, 2407, 9566, 49429, 5296, 10721, 22807, 3714, 9957, 37279, 28480, 26895, 8315, 11933, 25528, 16095, 22807, 11933, 1829, 8592, 8032, 15042, 2423, 2193, 329, 298, 433, 22807], "avg_logprob": -0.20706200153808893, "compression_ratio": 1.8059071729957805, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1203.07, "end": 1203.51, "word": "زي", "probability": 0.94384765625}, {"start": 1203.51, "end": 1204.35, "word": " شغل", "probability": 0.9280598958333334}, {"start": 1204.35, "end": 1204.85, "word": " الإيدين", "probability": 0.8219401041666666}, {"start": 1204.85, "end": 1205.45, "word": " هما", "probability": 0.684326171875}, {"start": 1205.45, "end": 1206.87, "word": " Stereoisomers", "probability": 0.7914306640625}, {"start": 1206.87, "end": 1207.85, "word": " صورة", "probability": 0.9132486979166666}, {"start": 1207.85, "end": 1208.21, "word": " بعض", "probability": 0.967529296875}, {"start": 1208.21, "end": 1208.39, "word": " في", "probability": 0.96533203125}, {"start": 1208.39, "end": 1209.17, "word": " المرأة", "probability": 0.8912353515625}, {"start": 1209.17, "end": 1210.11, "word": " غير", "probability": 0.979248046875}, {"start": 1210.11, "end": 1210.75, "word": " متطابقة", "probability": 0.984130859375}, {"start": 1210.75, "end": 1211.19, "word": " باللغة", "probability": 0.888671875}, {"start": 1211.19, "end": 1211.75, "word": " الإنجليزية", "probability": 0.9107259114583334}, {"start": 1211.75, "end": 1212.53, "word": " ببساطة", "probability": 0.9923828125}, {"start": 1212.53, "end": 1212.81, "word": " إيش", "probability": 0.8333333333333334}, {"start": 1212.81, "end": 1213.13, "word": " بنقول", "probability": 0.8984375}, {"start": 1213.13, "end": 1213.31, "word": " ال", "probability": 0.939453125}, {"start": 1213.31, "end": 1214.39, "word": " Enosomers؟", "probability": 0.5732177734375}, {"start": 1214.39, "end": 1214.87, "word": " none,", "probability": 0.24365234375}, {"start": 1215.17, "end": 1215.67, "word": " super,", "probability": 0.849609375}, {"start": 1215.83, "end": 1216.65, "word": " imposible", "probability": 0.4625244140625}, {"start": 1216.65, "end": 1216.95, "word": " يعني", "probability": 0.750732421875}, {"start": 1216.95, "end": 1217.19, "word": " غير", "probability": 0.992431640625}, {"start": 1217.19, "end": 1217.89, "word": " متطابقة", "probability": 0.992431640625}, {"start": 1217.89, "end": 1218.19, "word": " mirror", "probability": 0.373291015625}, {"start": 1218.19, "end": 1218.61, "word": " image", "probability": 0.87841796875}, {"start": 1218.61, "end": 1219.73, "word": " stereoisomers", "probability": 0.85491943359375}, {"start": 1219.73, "end": 1220.41, "word": " صورة", "probability": 0.9850260416666666}, {"start": 1220.41, "end": 1220.71, "word": " بعض", "probability": 0.9560546875}, {"start": 1220.71, "end": 1220.87, "word": " في", "probability": 0.99072265625}, {"start": 1220.87, "end": 1221.59, "word": " المرأة", "probability": 0.9632568359375}, {"start": 1221.59, "end": 1223.11, "word": " ولكنها", "probability": 0.8736979166666666}, {"start": 1223.11, "end": 1224.39, "word": " غير", "probability": 0.990234375}, {"start": 1224.39, "end": 1225.69, "word": " متطابقة", "probability": 0.9945068359375}, {"start": 1225.69, "end": 1227.73, "word": " مظبوط", "probability": 0.86669921875}, {"start": 1227.73, "end": 1227.89, "word": " ولا", "probability": 0.92578125}, {"start": 1227.89, "end": 1228.59, "word": " لأ؟", "probability": 0.8865559895833334}, {"start": 1228.59, "end": 1229.29, "word": " مين", "probability": 0.799560546875}, {"start": 1229.29, "end": 1229.87, "word": " تعرفيلنا", "probability": 0.631103515625}, {"start": 1229.87, "end": 1230.97, "word": " إياهم؟", "probability": 0.7464599609375}, {"start": 1230.97, "end": 1231.11, "word": " إيش", "probability": 0.9622395833333334}, {"start": 1231.11, "end": 1231.23, "word": " هما", "probability": 0.7841796875}, {"start": 1231.23, "end": 1231.37, "word": " ال", "probability": 0.97412109375}, {"start": 1231.37, "end": 1232.25, "word": " Enosomers؟", "probability": 0.935546875}], "temperature": 1.0}, {"id": 50, "seek": 126396, "start": 1234.32, "end": 1263.96, "text": "تفضلي .. تفضلي .. اه حاضر .. اه تفضلي .. non 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"probability": 0.32080078125}, {"start": 1513.35, "end": 1513.77, "word": " واحدة", "probability": 0.9169921875}, {"start": 1513.77, "end": 1513.91, "word": " إذا", "probability": 0.723876953125}, {"start": 1513.91, "end": 1514.11, "word": " هو", "probability": 0.97509765625}, {"start": 1514.11, "end": 1514.71, "word": " مشتقة", "probability": 0.8089192708333334}, {"start": 1514.71, "end": 1516.97, "word": " Methane", "probability": 0.765869140625}], "temperature": 1.0}, {"id": 61, "seek": 153467, "start": 1517.67, "end": 1534.67, "text": "الكربل الواحدة مشتقة مثين عليها تلت مجموعات إبروم و كلور و أيود حسب الترتيب ال alphabetical هذا المركب اسمه إبرومو إكلورو أيودو مثين", "tokens": [6027, 4117, 25513, 1211, 2423, 14407, 24401, 3660, 37893, 2655, 28671, 50113, 9957, 25894, 11296, 6055, 1211, 2655, 3714, 7435, 2304, 45367, 9307, 11933, 26890, 20498, 4032, 28242, 13063, 4032, 36632, 23328, 11331, 35457, 16712, 2288, 31371, 3555, 2423, 23339, 804, 23758, 9673, 31747, 3555, 24525, 2304, 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"seek": 230271, "start": 2293.85, "end": 2302.71, "text": "يكون اربع روابط مختلفة على كربونا واحدة عشان هيك دائما احنا بنعلم الكربونا اللي عليها", "tokens": [1829, 30544, 1975, 25513, 3615, 12602, 14407, 3555, 9566, 3714, 46456, 46538, 3660, 15844, 9122, 25513, 2407, 8315, 36764, 24401, 3660, 6225, 8592, 7649, 39896, 4117, 11778, 16373, 15042, 1975, 5016, 8315, 44945, 3615, 19528, 33251, 25513, 2407, 8315, 13672, 1829, 25894, 11296], "avg_logprob": -0.14985795319080353, "compression_ratio": 1.5, "no_speech_prob": 8.821487426757812e-06, "words": [{"start": 2293.85, "end": 2294.31, "word": "يكون", "probability": 0.6182861328125}, {"start": 2294.31, "end": 2294.75, "word": " اربع", "probability": 0.8009440104166666}, {"start": 2294.75, "end": 2295.61, "word": " روابط", "probability": 0.9749755859375}, {"start": 2295.61, "end": 2296.87, "word": " مختلفة", "probability": 0.98291015625}, {"start": 2296.87, "end": 2297.05, "word": " على", "probability": 0.66259765625}, {"start": 2297.05, 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مركز لل stereochemistry أو chiral center أو chiral carbon كله نفس الأشياء ال carbon اللي حامل أربع مجموعات مختلفة شو بسميها؟ chiral carbon, chiral center, stereogenic center", "tokens": [10721, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660, 44945, 7435, 46007, 46599, 1863, 39648, 34105, 8978, 43242, 1829, 12730, 25473, 3056, 37495, 22653, 3714, 31747, 11622, 24976, 29029, 48353, 34051, 23782, 304, 3056, 34051, 23782, 304, 5954, 28242, 3224, 8717, 36178, 16247, 8592, 1829, 16606, 2423, 5954, 13672, 1829, 11331, 10943, 1211, 5551, 25513, 3615, 3714, 7435, 2304, 45367, 9307, 3714, 46456, 46538, 3660, 13412, 2407, 4724, 38251, 1829, 11296, 22807, 23782, 304, 5954, 11, 23782, 304, 3056, 11, 12730, 25473, 3056], "avg_logprob": -0.20330459153515168, "compression_ratio": 1.78125, "no_speech_prob": 1.5497207641601562e-06, "words": [{"start": 2303.47, "end": 2303.99, "word": "أربع", "probability": 0.82958984375}, {"start": 2303.99, "end": 2304.59, "word": " مجموعات", 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diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_raw.json b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..e1427f2f3f4f83503c5a169209ddcb834236ac52
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/voCtxvzP8YI_raw.json
@@ -0,0 +1 @@
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بتقول ليش يعني هالغلبة مغلبيننا ومناشفين ريجنا في ال الديهيدس والكيتونز دائما و أبدا بتبقى دالكوا متذكرين شكلها أن الكيميا وطبعا بالتأكيد الرياضيات يعني مش رموز مش رموز لكنها", "tokens": [5172, 28820, 29538, 6055, 34268, 26890, 23032, 2288, 4587, 5296, 2655, 5016, 11242, 13546, 2423, 2423, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 11622, 23032, 3555, 3615, 995, 11933, 15730, 36764, 24401, 3660, 9154, 24793, 39894, 39648, 32239, 8592, 37495, 22653, 8032, 6027, 17082, 46152, 3660, 3714, 17082, 46152, 9957, 8315, 4032, 2304, 1863, 33599, 5172, 9957, 12602, 1829, 7435, 8315, 8978, 2423, 2423, 16254, 3224, 25708, 3794, 16070, 4117, 36081, 11536, 11622, 11778, 16373, 15042, 4032, 5551, 3555, 28259, 39894, 3555, 4587, 7578, 11778, 6027, 4117, 14407, 44650, 8848, 37983, 9957, 13412, 28820, 11296, 14739, 33251, 32640, 25528, 4032, 9566, 3555, 3615, 995, 20666, 2655, 10721, 4117, 25708, 2423, 16572, 46958, 1829, 9307, 37495, 22653, 37893, 12602, 2304, 2407, 11622, 37893, 12602, 2304, 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OH زي هي قطعة واحدة لو كانت مركبة ايون الميه .. لو كانت مركبة ايون هيكون زي هيك", "tokens": [3555, 2304, 3615, 1863, 7578, 9673, 1829, 3224, 19046, 49429, 17437, 299, 14154, 22807, 19046, 14154, 389, 31187, 10874, 11622, 38207, 36764, 24401, 37495, 22653, 45164, 6055, 9778, 26895, 2655, 14407, 8032, 47302, 12174, 9566, 34268, 9957, 8032, 3215, 12610, 3660, 4724, 2304, 12984, 43761, 2423, 13931, 4386, 13931, 30767, 1829, 39896, 12174, 9566, 27884, 36764, 24401, 3660, 45164, 25961, 2655, 3714, 31747, 49401, 1975, 1829, 11536, 9673, 1829, 3224, 4386, 45164, 25961, 2655, 3714, 31747, 49401, 1975, 1829, 11536, 39896, 30544, 30767, 1829, 39896, 4117], "avg_logprob": -0.1980962667657041, "compression_ratio": 1.679144385026738, "no_speech_prob": 5.960464477539063e-08, "words": [{"start": 1376.02, "end": 1376.72, "word": "بمعنى", "probability": 0.9552734375}, {"start": 1376.72, "end": 1377.5, "word": " الميه", "probability": 0.6438802083333334}, {"start": 1377.5, "end": 1378.36, "word": " 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{"start": 1873.87, "end": 1874.29, "word": " كانت", "probability": 0.94775390625}, {"start": 1874.29, "end": 1874.73, "word": " اصلا", "probability": 0.81396484375}, {"start": 1874.73, "end": 1875.57, "word": " C", "probability": 0.479248046875}, {"start": 1875.57, "end": 1875.79, "word": " double", "probability": 0.51123046875}, {"start": 1875.79, "end": 1876.19, "word": " bond", "probability": 0.94482421875}, {"start": 1876.19, "end": 1876.51, "word": " O", "probability": 0.93212890625}], "temperature": 1.0}, {"id": 78, "seek": 190692, "start": 1877.8, "end": 1906.92, "text": "واضح؟ لكن لو بدنا نقول مثلا مع ال .. propranaldehyde مع ال .. pentaldehyde whatever بشكل عام التفاعل هذا عبارة عن اتزان بيظله على هذا الشكل المنفصل يعني الاتزان بيكون أكثر لليسار لل reactants منه لل products واضح؟ وين بيكونوا ال products أكتر؟ في ال formaldehyde", "tokens": [2407, 46958, 5016, 22807, 44381, 45164, 47525, 8315, 8717, 39648, 50113, 15040, 20449, 2423, 4386, 447, 1424, 282, 304, 1479, 3495, 1479, 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"probability": 0.6380615234375}, {"start": 2003.56, "end": 2003.96, "word": " نعطيكوا", "probability": 0.9718424479166666}, {"start": 2003.96, "end": 2004.18, "word": " براق", "probability": 0.6942545572916666}, {"start": 2004.18, "end": 2004.9, "word": " الامتحانات", "probability": 0.9171549479166666}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2005.786125, "duration_after_vad": 1946.2631249999954}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_postprocess.srt b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8440cf6186ce43e01a9a844cc3dcf77862cfbcf3
--- /dev/null
+++ b/PL9fwy3NUQKwaZxgC_hXbLNCo6xPA4DJV_/yjrGokFtNpo_postprocess.srt
@@ -0,0 +1,2048 @@
+1
+00:00:05,650 --> 00:00:10,570
+المرة الماضية اتكلمنا على مقدمة لل aromatic
+
+2
+00:00:10,570 --> 00:00:16,570
+compounds وتسميتها واضح اليوم ان شاء الله بدنا
+
+3
+00:00:16,570 --> 00:00:22,170
+ندرس تفاعلات ال aromatic compounds تفاعلات البنزين
+
+4
+00:00:22,170 --> 00:00:29,310
+دائما و ابدا دائما و ابداصورة كلية لأي موضوع
+
+5
+00:00:29,310 --> 00:00:35,010
+بيتريح واضح؟ و الصورة الكلية دائما انك تكون فاهم
+
+6
+00:00:35,010 --> 00:00:38,990
+ايش التفاعل العام يعني احنا الالف chapter اربعة
+
+7
+00:00:38,990 --> 00:00:44,270
+اربعة من اتناشر chapter يعني تلت المنهج اذا اجيت
+
+8
+00:00:44,270 --> 00:00:49,500
+سألتكم ايش اللي درسناه؟ الالكينزلما نقول الـ
+
+9
+00:00:49,500 --> 00:00:54,120
+Alkenes، شو تفاعلاتهم؟ بكلمة واحدة، بدو يكون
+
+10
+00:00:54,120 --> 00:00:58,660
+الكلام بشكل أساسي Substitution Free Radical
+
+11
+00:00:58,660 --> 00:01:02,520
+Substitution، مظبوط ولا لا؟ رغم أنه بشكل عام inert
+
+12
+00:01:02,520 --> 00:01:06,920
+لكن لما بيعملوا Free Radical Substitution أو الـ
+
+13
+00:01:06,920 --> 00:01:13,060
+Thermolysis والتكسر بالحرارة الآن، لو جينا على الـ
+
+14
+00:01:13,060 --> 00:01:21,250
+Alkenes تفاعلهم الـ Additionالان لو سألنا ايش نوع
+
+15
+00:01:21,250 --> 00:01:26,350
+ال addition اللى بتتم على ال الكينز ايش اللى كنا
+
+16
+00:01:26,350 --> 00:01:30,170
+نبدأ فيه التفاعل موجب ولا سالب اللى بيجي وبيهاجم
+
+17
+00:01:30,170 --> 00:01:35,350
+ال الكينز موجب اتش بلس اذا نوع ال addition اللى
+
+18
+00:01:35,350 --> 00:01:40,090
+على ال الكينز electrophilic additionElectrophilic
+
+19
+00:01:40,090 --> 00:01:44,710
+لإنه بيجي Electrophile بيجي موجب ..لأن ليش بيجي
+
+20
+00:01:44,710 --> 00:01:49,570
+الموجب؟ لأن هذا ال keen double bond .. هاي زيك
+
+21
+00:01:49,570 --> 00:01:52,770
+double bond .. double bond يعني إلكترونات .. لأن
+
+22
+00:01:52,770 --> 00:01:57,520
+الإلكترونات شو اللي بيجي يهاجم عليها؟positive ولا
+
+23
+00:01:57,520 --> 00:02:02,360
+negative؟ positive إذا ال addition اللي بيصير على
+
+24
+00:02:02,360 --> 00:02:07,680
+ال alkenes ومتلها ال alkynes is electrophilic
+
+25
+00:02:07,680 --> 00:02:12,040
+addition يعني لو بدنا نيجي نجيبلكوا سؤال نقول
+
+26
+00:02:12,040 --> 00:02:16,280
+والله ال alkenes undergo a eucleophilic addition
+
+27
+00:02:16,280 --> 00:02:22,180
+in generalالجواب غلط التفاعل الأساسي Electrophilic
+
+28
+00:02:22,180 --> 00:02:27,520
+addition هي إلكترونيات بجهة Electrophile موجة،
+
+29
+00:02:27,520 --> 00:02:32,600
+واضح؟ الآن الـ aromatic compounds، إيه التفاعل
+
+30
+00:02:32,600 --> 00:02:37,960
+الأساسي؟ والله إذا الـalkenes فيهم double bond
+
+31
+00:02:37,960 --> 00:02:45,620
+واحدةالبنزين فيه تلاتة اللي عاملين resonance يعني
+
+32
+00:02:45,620 --> 00:02:49,660
+اللي بدو ييجي يهاجم على البنزين كأنه بيهاجم على
+
+33
+00:02:49,660 --> 00:02:56,280
+حقل من الإلكترونات كأنه بيهاجم على سحابة إلكترونية
+
+34
+00:02:56,280 --> 00:02:59,240
+الآن اللي بدو ييجي يهاجم على سحابة إلكترونية إيش
+
+35
+00:02:59,240 --> 00:03:04,020
+شرطه؟ إنه بدو يكون .. هذه البنزين .. بدو يكون موجة
+
+36
+00:03:05,250 --> 00:03:10,930
+واضح بيكون موجب اللي بيهاجم على البنزين على سحابة
+
+37
+00:03:10,930 --> 00:03:14,450
+إلكترونية كبيرة بيكون موجب وعشان هيك المسمى
+
+38
+00:03:14,450 --> 00:03:20,760
+التفاعل electrophilic aromaticsubstitution هنا
+
+39
+00:03:20,760 --> 00:03:27,240
+بيجينا اختلاف أساسي وجوهري كبير كبير ما بين ال
+
+40
+00:03:27,240 --> 00:03:31,840
+alkenes وما بين ال aromatic compounds ال alkenes
+
+41
+00:03:31,840 --> 00:03:34,360
+كانوا عبارة عن double bond وال double bond إيش
+
+42
+00:03:34,360 --> 00:03:42,800
+نقول عنها؟ بتكسروبتعمل إضافة إضافة دارتين الآن
+
+43
+00:03:42,800 --> 00:03:46,800
+ربما يخطر على بال الناس للوهلة الأولى إنه إذا الـ
+
+44
+00:03:46,800 --> 00:03:50,500
+double bond بتعمل addition لما يكونوا تلاتة ممكن
+
+45
+00:03:50,500 --> 00:03:54,820
+نتخيلهم بهذا الشكل أو بالشكل ما شاء الله كام
+
+46
+00:03:54,820 --> 00:03:58,760
+double bond عندى تلاتة إنه نتخيل إنه بدو ييجي
+
+47
+00:03:58,760 --> 00:04:02,380
+electrophile متفقين عليها بدو يجيهم موجب لكن يعمل
+
+48
+00:04:02,380 --> 00:04:06,620
+addition الواقع إنه بالتجربة لاجو مابصيرش على
+
+49
+00:04:06,620 --> 00:04:12,680
+البنزين additionما بيصير عليه addition رغم وجود
+
+50
+00:04:12,680 --> 00:04:17,060
+ايشتلاتة double bonds، عشانك بيقولوا ان ال double
+
+51
+00:04:17,060 --> 00:04:26,180
+bonds هدولة تبعون البنزين لا يوجد فيهم مواصفات ال
+
+52
+00:04:26,180 --> 00:04:29,840
+double bond الواحدة، they don't have or they don't
+
+53
+00:04:29,840 --> 00:04:34,680
+show double bond character لأن أهم ميزة لل double
+
+54
+00:04:34,680 --> 00:04:39,480
+bond انها بتعمل ايش؟ addition هدولة مابرضوش يعملوا
+
+55
+00:04:39,480 --> 00:04:44,560
+additionواضح؟ هدولة ما بيرضوش يعملوا addition ليش
+
+56
+00:04:44,560 --> 00:04:47,460
+هدولة مش راضيين يعملوا addition هان، برا، و هان،
+
+57
+00:04:47,460 --> 00:04:51,220
+برا، و هان، برا؟ لأن هم مع بعضهم عاملين resonance
+
+58
+00:04:51,220 --> 00:04:56,060
+egg عاملين دائرة مغلقة في بعض ومثبتين نفسهم
+
+59
+00:04:56,060 --> 00:05:01,520
+بنفسهم، مابيحبوش يتفاعلوا برا فرغم وجود تلاتة
+
+60
+00:05:01,520 --> 00:05:05,400
+double bonds في البنزين لكن مابيعملش تفاعل الـ
+
+61
+00:05:05,400 --> 00:05:10,760
+double bond إذا هذا الكلام شوية هيسهل علينايعني
+
+62
+00:05:10,760 --> 00:05:14,360
+لما كنا ناخد ال double bonds و نبدأ نقول إضافة
+
+63
+00:05:14,360 --> 00:05:21,320
+نقول إضافة ال hydrogen ال halogen ال hbr ال hcl ال
+
+64
+00:05:21,320 --> 00:05:27,220
+h2o و كل إيش إضافات إضافات إضافات هنا ولا تفاعل
+
+65
+00:05:27,220 --> 00:05:31,420
+منهم باللغة ولا إشي بصير ولا كأنه عندى
+
+66
+00:05:37,800 --> 00:05:41,800
+البنزين صح بحتوى ع تلاتة double bonds لكنه لايتفعل
+
+67
+00:05:41,800 --> 00:05:48,220
+دفعولات double bondsبيعمل substitution إيش اللي
+
+68
+00:05:48,220 --> 00:05:53,440
+بده يبدل اللي بده يبدل ببساطة ال H اللي موجودة هنا
+
+69
+00:05:53,440 --> 00:06:00,020
+بدأ تنشال و يجي بدالها إش جديد شيلت H حطيت X أيا
+
+70
+00:06:00,020 --> 00:06:04,460
+كانت هال X هذا التفاعل إيش يعتبر substitution إذا
+
+71
+00:06:04,460 --> 00:06:09,560
+التفاعل الأساسي لل aromatic compounds the main
+
+72
+00:06:09,560 --> 00:06:16,010
+reaction of aromatic compounds isلأ Electrophilic
+
+73
+00:06:16,010 --> 00:06:19,850
+Substitution بديكوا تتعودوا تحطوا الكلام بالظبط
+
+74
+00:06:19,850 --> 00:06:23,790
+لأنه أنا برضه لما بدي أسالكوا عنه بدي أسالكوا
+
+75
+00:06:23,790 --> 00:06:30,490
+بالظبط في الألكينزكننا نقول free radical
+
+76
+00:06:30,490 --> 00:06:34,610
+substitution متذكرين؟ لما كنا نعمل الهالوجينيشن
+
+77
+00:06:34,610 --> 00:06:38,370
+كان إبدال من خلال ال free radical اللي كان يهاجم
+
+78
+00:06:38,370 --> 00:06:42,730
+CR radical هنا اللي بده يهاجم موجب إذا في عنده
+
+79
+00:06:42,730 --> 00:06:47,170
+free radical substitution في عنده electrophilic
+
+80
+00:06:47,170 --> 00:06:50,670
+substitution بعد ذلك بشبتر ستة في substitution
+
+81
+00:06:50,670 --> 00:06:53,850
+تاني على الalkyl halide اللي بيهاجم ال nucleophile
+
+82
+00:06:53,850 --> 00:06:59,260
+في nucleophilic substitutionإذا أنا عندي أكتر من
+
+83
+00:06:59,260 --> 00:07:03,380
+شغلة وكل حاجة بدنا نحفظها بالظبط ماببتيش أنا أجي
+
+84
+00:07:03,380 --> 00:07:07,200
+أقول ال alkanes و ال aromatic compounds و بعد شوية
+
+85
+00:07:07,200 --> 00:07:09,680
+و شنطر ستة ال alkyl halides they undergo
+
+86
+00:07:09,680 --> 00:07:14,900
+substitution صح إبدال لكن في التلت حالات مختلفين
+
+87
+00:07:14,900 --> 00:07:18,140
+صرنا ماخدين إحنا ال alkanes free radical
+
+88
+00:07:18,140 --> 00:07:20,620
+substitution الآن ال aromatic compounds
+
+89
+00:07:20,620 --> 00:07:24,520
+electrophilic substitution بعد شوية ال alkyl
+
+90
+00:07:24,520 --> 00:07:28,790
+halidesالـ Eucleophilic Substitution الطلاب اللي
+
+91
+00:07:28,790 --> 00:07:34,670
+أحيانا بيغلطوا بيكونوا مش مميزين هذه الشغلات فخلاص
+
+92
+00:07:34,670 --> 00:07:38,370
+كله عندهم substitution بتجيب سؤال صح و غلط ولا
+
+93
+00:07:38,370 --> 00:07:43,680
+سؤالين على هذهتخربته فيهم، واضح؟ إذا هذا التفاعل
+
+94
+00:07:43,680 --> 00:07:47,980
+Electrophilic Substitution إنه حيصير إبدال
+
+95
+00:07:47,980 --> 00:07:52,940
+والمهاجم Electrophile، الآن يمكن أن يتم أنواع
+
+96
+00:07:52,940 --> 00:07:57,520
+كثيرة من الإبدال، ممكن إنه يصير إبدال ب X، بحيث إن
+
+97
+00:07:57,520 --> 00:08:04,970
+X هالوجينيعني CL VR U واضح هذه العملية بنسميها
+
+98
+00:08:04,970 --> 00:08:09,130
+الهالوجينيشن الهالوجينيشن اللي بده يضيف إيش لازم
+
+99
+00:08:09,130 --> 00:08:13,230
+يكون موجبة اللي بده يضيف عشان يعمل الإبدال يعني
+
+100
+00:08:13,230 --> 00:08:17,390
+اللي بده يستم في الإبدال ممكن تتم إضافة أو إبدال
+
+101
+00:08:17,390 --> 00:08:22,970
+نيترو جروب و النيترو إيش بتلاحظوها هنا موجبة
+
+102
+00:08:22,970 --> 00:08:28,660
+العمليةنيتراشن بدل الأكشن نيترو نيتراشن بكس
+
+103
+00:08:28,660 --> 00:08:35,200
+هالوجيناشن ممكن تم ب HSO3 plus سالفونك أسد
+
+104
+00:08:35,200 --> 00:08:44,180
+سالفوناشن ممكن تم ب R plusالكليجروب الـ chelation
+
+105
+00:08:44,180 --> 00:08:49,320
+ممكن يتم بـ R C double bond O positive في النهاية
+
+106
+00:08:49,320 --> 00:08:52,940
+R C double bond O positive هذه اسمها مجموعة
+
+107
+00:08:52,940 --> 00:08:57,600
+الاسيليجروب اسيليشن الآن احنا هناخد هدولة بالتفصيل
+
+108
+00:08:58,500 --> 00:09:01,340
+يعني هذا الـ scheme العام أو الصورة الكلية
+
+109
+00:09:01,340 --> 00:09:04,140
+للتفاعلات بناخد الـ halogenation، بعدين الـ
+
+110
+00:09:04,140 --> 00:09:07,920
+nitration، sulfonation، alkylation، acylation،
+
+111
+00:09:07,920 --> 00:09:12,720
+يعني إيه؟ بناخدهم بالتفصيل وكيف الـ mechanism اللي
+
+112
+00:09:12,720 --> 00:09:16,460
+بتيم فيها التفاعل، كيف القالية اللي بتيم فيها
+
+113
+00:09:16,460 --> 00:09:24,560
+التفاعل خلينا نبدأ في ال halogenation مثلا، لو
+
+114
+00:09:24,560 --> 00:09:26,880
+إجينا نعمل تفاعل مع البرومين
+
+115
+00:09:29,240 --> 00:09:33,740
+بتكن تنتبه دائما و أبدا لل reagents كاملة يعني ما
+
+116
+00:09:33,740 --> 00:09:38,020
+تحفظوش بس الأشياء من طرفها يعني لما كنا زمان نفعل
+
+117
+00:09:38,020 --> 00:09:43,860
+ال cane مع ال bromine كنا نقول ال cane مع ال
+
+118
+00:09:43,860 --> 00:09:48,220
+bromine نكتب ع ساموش و بعدين نحط تحت عشان يمشي
+
+119
+00:09:48,220 --> 00:09:55,520
+التفاعل heat or light ضوء أو حرارة واضح؟ الآن هنا
+
+120
+00:09:55,520 --> 00:10:01,380
+مع البنزين لو عملنا bromineوكتبنا heat or light ما
+
+121
+00:10:01,380 --> 00:10:10,520
+بصيرش تفاعل لازم البرومين يكون معه مركب FeBr3 او
+
+122
+00:10:10,520 --> 00:10:14,760
+ممكن يكون aluminum Br3 او aluminum Cr3 بمشي خلاني
+
+123
+00:10:14,760 --> 00:10:21,180
+اقول انسب اشهر ال FeBr3واضح؟ هدولا الماديتين إشي
+
+124
+00:10:21,180 --> 00:10:26,900
+بيعملوا مع بعض، بتيجوا تتطلعوا تتذكرولي البرومين
+
+125
+00:10:26,900 --> 00:10:32,420
+نفسه جزء من ذاتين بروم زي بعض، هاي و ها نتخيل، هاي
+
+126
+00:10:32,420 --> 00:10:37,240
+بروم و هاي بروم، يتورى البرومين نفسه كجزء، بيكون
+
+127
+00:10:37,240 --> 00:10:42,370
+قطبي ولا غير قطبي؟بيكون غير قطب لإن هذي بروم و هذي
+
+128
+00:10:42,370 --> 00:10:46,290
+بروم و ال electronegativity متساوية مش زي ال HCL
+
+129
+00:10:46,290 --> 00:10:50,670
+انطارت ممكن يكون في فاندرفالز forces أو لندن
+
+130
+00:10:50,670 --> 00:10:53,930
+forces اللي هي حركة الإلكترونات يعني شوية تتركز
+
+131
+00:10:53,930 --> 00:10:58,650
+لكن بشكل عام هو nonpolar لإن الدارتين أشمالهم زي
+
+132
+00:10:58,650 --> 00:11:04,290
+بعض طب هذا الجزء ال nonpolar كيف أنا بدي أخليه
+
+133
+00:11:04,290 --> 00:11:11,220
+polar بحيث أنه أنا بدي أخد منه PR plusلأنه المطلوب
+
+134
+00:11:11,220 --> 00:11:19,200
+لكي يتم التفاعل بـ R Plusواضح؟ كيف بدي أكسر الجزء
+
+135
+00:11:19,200 --> 00:11:26,860
+اللي هو عبارة عن PR2 أخليه عبارة عن PR- و PR+, و
+
+136
+00:11:26,860 --> 00:11:32,460
+أاخد للتفاعل الـ PR+. واضح الفكرة؟ إذا أنا بدي
+
+137
+00:11:32,460 --> 00:11:38,460
+أكسر التماثل تبعه، بنجيب هذا المركب الـ FeBr3 الـ
+
+138
+00:11:38,460 --> 00:11:46,070
+FeBr3 لو لاحظناه لوحده هنازي هيك عبارة عن حديد
+
+139
+00:11:46,070 --> 00:11:52,470
+متصل بكم بروم؟ تلاتة بزامه متصل ب تلاتة برومين، كم
+
+140
+00:11:52,470 --> 00:11:58,250
+إلكترون حواليه؟ ستة الوضع الطبيعي للإلكترونات،
+
+141
+00:11:58,250 --> 00:12:02,230
+كداش يكونوا؟ تمانية، هذا في ناقص إلكترونات،
+
+142
+00:12:02,230 --> 00:12:08,180
+electron deficient أو electron poorإيش يعني
+
+143
+00:12:08,180 --> 00:12:13,160
+electron deficient أو poor؟ عنده نقص أو فقر أو عوز
+
+144
+00:12:13,160 --> 00:12:16,560
+في الإلكترونات الأشياء اللي عندها نقص في
+
+145
+00:12:16,560 --> 00:12:21,300
+الإلكترونات حسب تعريف Lewis للأحمض والقواعد عبارة
+
+146
+00:12:21,300 --> 00:12:26,960
+عن Lewis acid ولا Lewis base Lewis acid acid is
+
+147
+00:12:26,960 --> 00:12:31,700
+electron acceptor بده إلكترونات وال base is
+
+148
+00:12:31,700 --> 00:12:36,900
+electron donor بتاعة الإلكترونات إذا هذا عبارة عن
+
+149
+00:12:38,090 --> 00:12:47,270
+Lewis أسد أسد أسد
+
+150
+00:12:47,270 --> 00:12:49,290
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+151
+00:12:49,290 --> 00:12:50,910
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+152
+00:12:50,910 --> 00:12:52,970
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+153
+00:12:52,970 --> 00:12:55,830
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد
+
+154
+00:12:55,830 --> 00:13:04,850
+أسد أسد أسد أسد أسد أسد أسد أسد أسد أسد أس
+
+155
+00:13:05,550 --> 00:13:10,430
+واضح؟ إذا وجود هذا الـ Lewis acid اللي بحاجة إلى
+
+156
+00:13:10,430 --> 00:13:15,830
+PR رابعة هو اللي بيخدمني في التفاعل لأنه بيعمل
+
+157
+00:13:15,830 --> 00:13:22,270
+polarization أو استخطاف بيسحب من الـ PR2 PR خلّيني
+
+158
+00:13:22,270 --> 00:13:26,550
+أقول مع with its pair of electrons and it leaves a
+
+159
+00:13:26,550 --> 00:13:32,070
+positive bromine بيسيبلي bromine موجة هذا ال
+
+160
+00:13:32,070 --> 00:13:35,680
+bromine الموجة بالأن هو اللي بتفاعليعني في الـ
+
+161
+00:13:35,680 --> 00:13:39,000
+slide الجاية هتلاحظوا أنه بدأنا ببرومين مجبرة في
+
+162
+00:13:39,000 --> 00:13:43,640
+حد بدى عودي يسألنا من وين إجا؟ شوفنا من وين إجا،
+
+163
+00:13:43,640 --> 00:13:53,020
+بمساعدة الـ Lewis acid الـ FABR3 الآن
+
+164
+00:13:53,020 --> 00:13:57,520
+هذا الـ PR positive أول ما بيجي عندى خلينا نتخيل
+
+165
+00:13:57,520 --> 00:14:02,760
+أنه هنا كانت فيه double bond واضح؟ وفيه هيدروجين
+
+166
+00:14:03,560 --> 00:14:06,720
+هذه الـ double bonds إلكترونة و جايها موجة .. إيش
+
+167
+00:14:06,720 --> 00:14:13,480
+بتعمل؟ بتعمل رابطة معه، هيها إذا اتحركت واحدة من
+
+168
+00:14:13,480 --> 00:14:17,720
+الـ double bonds إزاي كنت بتكون تتخيل؟ اتحركت
+
+169
+00:14:17,720 --> 00:14:23,280
+واحدة من الـ double bonds و عملت رابطة مع البرومين
+
+170
+00:14:23,280 --> 00:14:30,620
+لما اتحركت هذه الـ double bonds شو سابت مكانها؟هذا
+
+171
+00:14:30,620 --> 00:14:34,900
+الـ carbocation مش ضروري يظل ثابت مكانه، ممكن يعمل
+
+172
+00:14:34,900 --> 00:14:38,760
+resonance، بمعنى لو هات اتحركت زي هيك، وين هيصير
+
+173
+00:14:38,760 --> 00:14:42,740
+الموجة؟ على هذا الموقع، لو هات اتحركت زي هيك، وين
+
+174
+00:14:42,740 --> 00:14:47,580
+هصير الموجة؟ على هذا الموقع، اذا انا عمالة في عنده
+
+175
+00:14:49,060 --> 00:14:53,860
+positive charge in resonance متنقلة بين أكتر من
+
+176
+00:14:53,860 --> 00:14:56,840
+مكان، معناه ذلك هذي positive charge stable ولا
+
+177
+00:14:56,840 --> 00:15:01,020
+unstable؟ بنتحر
+
+178
+00:15:01,020 --> 00:15:06,520
+بعدين ال resonance أساسي stability، مظبوط ولا لأ؟
+
+179
+00:15:06,520 --> 00:15:10,120
+الاشي لما بيكون متنقل بين أكتر من شغل الحمل إذا
+
+180
+00:15:10,120 --> 00:15:18,010
+توزعماذا نقول؟ الحمل إذا توزع ان شال و هذا حمل
+
+181
+00:15:18,010 --> 00:15:23,290
+موزع على تلت أماكن إذا ليست شحنة مركزة شحنة موزعة
+
+182
+00:15:23,290 --> 00:15:29,130
+بال resonance إذا هذا stable واضح؟ الآن عشان يكتمل
+
+183
+00:15:29,130 --> 00:15:33,570
+التفاعل .. عشان يكتمل التفاعل كل اللي بدو يصير أنه
+
+184
+00:15:33,570 --> 00:15:39,390
+تفقد هذه الـ H plus لحالها وهذه ترد تتحرك هنا
+
+185
+00:15:42,760 --> 00:15:47,420
+واضح؟ طبعا إنتوا هتيجيوا تسأله فقدت ال H plus على
+
+186
+00:15:47,420 --> 00:15:51,420
+العين و الرأس وين بدها تروح ال H plus؟ هتظل هكذا و
+
+187
+00:15:51,420 --> 00:15:58,760
+إحنا موجبة؟ لأ بتروح في PR minus لزقة حلوين في ال
+
+188
+00:15:58,760 --> 00:16:08,820
+FEPR 3 صارت FEPR 4 بتردده لما تيجي ال H plus بتقول
+
+189
+00:16:08,820 --> 00:16:09,760
+أنا بد ال PR
+
+190
+00:16:28,370 --> 00:16:29,810
+هيرجع مرة تانية
+
+191
+00:16:33,100 --> 00:16:37,120
+هنرجع للـ slide هيرجع مرة تانية مع جزء البرومين
+
+192
+00:16:37,120 --> 00:16:42,680
+ويعمل نفس الكلام ياخد منه PR- ويسيب لبر بوزيتف إذا
+
+193
+00:16:42,680 --> 00:16:48,960
+كأنه أنا البرومين يطلع الموجبة و بعدين السالب في
+
+194
+00:16:48,960 --> 00:16:53,120
+نهاية التفاعل بيرود ياخد هال إيش الـ H plus ويرجع
+
+195
+00:16:53,120 --> 00:16:56,420
+هذا في EPR3 و بعيد الكرة و بعيد الكرة و بعيد الكرة
+
+196
+00:16:56,420 --> 00:17:00,580
+و بعيد الكرة هذا هو اللي عملتش
+
+197
+00:17:02,440 --> 00:17:09,420
+الـ Catalyst هذا هو عمل الـ Catalyst إنه بكمية
+
+198
+00:17:09,420 --> 00:17:15,760
+قليلة بيكون موجود و بيبقى .. يعيد التفاعل يعيد
+
+199
+00:17:15,760 --> 00:17:21,820
+التفاعل يعيد التفاعل إذا حقيقة محصلة التفاعل لو
+
+200
+00:17:21,820 --> 00:17:25,700
+أنا في نهاية التفاعل بدي أشوف إيش المحصلة الـ
+
+201
+00:17:25,700 --> 00:17:33,240
+FeBr3 بطلع زي ما هو إذا صار عندى بدل الفنزينبرومو
+
+202
+00:17:33,240 --> 00:17:40,800
+بنزين زائد HBR يعني كأنا بنقول بنزين زائد PR2 في
+
+203
+00:17:40,800 --> 00:17:46,860
+وجود الـFeBr3 برومو بنزين زائد HBR، واضح؟ بس إحنا
+
+204
+00:17:46,860 --> 00:17:50,920
+قعدت شوفنا التفاصيل كيف بيتم التفاعل، الـmechanism
+
+205
+00:17:50,920 --> 00:17:55,620
+of the reaction وشوفنا إن ال reaction هنا بيمشي
+
+206
+00:17:55,620 --> 00:17:57,440
+بـelectrophilic aromatic
+
+207
+00:18:04,180 --> 00:18:09,000
+الان اللى فهم هذا الكلام هيلاحظ انه بعد هيك باقى
+
+208
+00:18:09,000 --> 00:18:16,560
+التفاعلات بتصير تقريبا شبيهة جدا، يعني بنقدر نمشي
+
+209
+00:18:16,560 --> 00:18:20,420
+أسرع، واضح؟ بنقدر نمشي في الشارع أسرع
+
+210
+00:18:23,210 --> 00:18:28,810
+مثلًا لو بدنا نيجي نقول الـ Cl2 برضه بنستعمله Cl2
+
+211
+00:18:28,810 --> 00:18:33,430
+مع FeCl3 بطلع Cl positive و double bond و هد بتعمل
+
+212
+00:18:33,430 --> 00:18:38,490
+resonance و نفس الكلام لو قولنا ال I2 بنستعمله
+
+213
+00:18:38,490 --> 00:18:44,050
+cover إكلورايد في نهاية هدولة بتطلعوله I positive
+
+214
+00:18:44,050 --> 00:18:47,650
+و بتضيف ال I positive و بيعمل resonance تفقد ال H
+
+215
+00:18:47,650 --> 00:18:55,170
+plus واضح؟ سهل عملية سهلةالان لو اجينا ل ال
+
+216
+00:18:55,170 --> 00:19:00,670
+nitration لو اجينا ل ال nitration لو ضفنا على
+
+217
+00:19:00,670 --> 00:19:08,290
+البنزين nitric acid لحاله مابصيرش تفاعل يعني لو
+
+218
+00:19:08,290 --> 00:19:14,290
+جيبت بنزين و حطيت فوق السهم بس nitric acid هاي
+
+219
+00:19:14,290 --> 00:19:21,780
+بنزين و بتحط فوق السهم ايش؟HNO3 نيتريك أسد لحاله
+
+220
+00:19:21,780 --> 00:19:26,920
+ما بيصيرش تفاعل عشان أعمل نيتريشن لازم أضيف نيتريك
+
+221
+00:19:26,920 --> 00:19:34,060
+أسد مع سالفاريك أسد H2SO4 لازم أضيف هدولة التنتين
+
+222
+00:19:34,060 --> 00:19:38,720
+مع بعضاللي بدأت تكمل معادلة جيوب سؤال امتحان لازم
+
+223
+00:19:38,720 --> 00:19:46,760
+تكتب ليه لـNitration HNO3 مع H2SO4 الآن في الخطوة
+
+224
+00:19:46,760 --> 00:19:51,400
+التحضيرية في الخطوة التحضيرية للتفاعل الـH2SO4 و
+
+225
+00:19:51,400 --> 00:19:55,180
+الـHNO3 هم اللي بتفاعلوا بينهم وبين بعض بيعطوني
+
+226
+00:19:55,180 --> 00:20:00,840
+H2O زي HNO2 plus أنا اللي بهمني الـHNO2 plus اللي
+
+227
+00:20:00,840 --> 00:20:03,900
+هو الـelectrophile الآن إذا صار موجود
+
+228
+00:20:03,900 --> 00:20:10,150
+الـelectrophileخلاص انحلت المشكلة واضح؟ بنفس
+
+229
+00:20:10,150 --> 00:20:14,930
+المنطق السابق إذا خلطة الـ H2SO4 و الـ HNO3 هي
+
+230
+00:20:14,930 --> 00:20:20,330
+اللي بتطلع له الـ Electrophile الـ NO2 Plus هذا
+
+231
+00:20:20,330 --> 00:20:23,590
+الـ NO2 Plus لما اتفعل تتحرك Double Bond بيعمل
+
+232
+00:20:23,590 --> 00:20:27,770
+Carbocation ب Resonance و بعدين بيفقد H Plus
+
+233
+00:20:27,770 --> 00:20:31,410
+بيعطينا Nitro مش فيها المشكلة
+
+234
+00:20:34,510 --> 00:20:40,670
+طيب، لو إجينا لـ Sulphonation، كيف بنضيف الـ
+
+235
+00:20:40,670 --> 00:20:48,610
+Sulphonic Acid؟ اللي بنحطه حقيقة على السهم H2SO4،
+
+236
+00:20:48,610 --> 00:20:53,810
+الـ sulphuric acid، بس بيقولوا عنه effumingfuming
+
+237
+00:20:53,810 --> 00:20:57,370
+sulphuric acid إيش يعني fuming sulphuric acid؟
+
+238
+00:20:57,370 --> 00:21:01,890
+fumes يعني أبخرة وfume hood اللي هو خزانة الأبخرة
+
+239
+00:21:01,890 --> 00:21:04,670
+اللي في المختبر اللي بتشفط البخار ال fuming هو
+
+240
+00:21:04,670 --> 00:21:10,030
+عبارة عن sulphuric acid وفيه كمية إضافية من غاز ال
+
+241
+00:21:10,030 --> 00:21:15,150
+S O 3 اللي هو أساسا اللي لما بندوبهبالميه بيعمل
+
+242
+00:21:15,150 --> 00:21:18,450
+sulfuric acid بتذكرين انتوا كيف بنحضر ال sulfuric
+
+243
+00:21:18,450 --> 00:21:24,870
+acid؟ بندوب S O 3 in water و لما بدنا نعمل ال
+
+244
+00:21:24,870 --> 00:21:34,170
+sulfurous acid ال H 2 S O 3 نراجع
+
+245
+00:21:34,170 --> 00:21:45,930
+شوية كيميا S O 3 زائد H 2 O و S O 2 زائدH2O الـ
+
+246
+00:21:45,930 --> 00:21:52,590
+SO3 مع الـ H2O شو بيعطينا؟ الحمض الكابريتيك H2SO4
+
+247
+00:21:52,590 --> 00:21:56,850
+إذا من ثالث أكسيد الكابريت مع الميه بطلع الـ H2SO4
+
+248
+00:21:56,850 --> 00:21:59,890
+H2SO3
+
+249
+00:21:59,890 --> 00:22:05,530
+الـ Sulphurous و Sulphuric Sulphuric Acid و
+
+250
+00:22:05,530 --> 00:22:09,190
+Sulphurous Acid فالخلاصة إن إحنا هنا لما بنستعمل
+
+251
+00:22:09,190 --> 00:22:15,330
+نستعمل H2SO4 مع غازاس او ثري يعني بيكون ال
+
+252
+00:22:15,330 --> 00:22:20,850
+sulfuric acid لما نفتح البوتل تبعه بيدخل محطوط فيه
+
+253
+00:22:20,850 --> 00:22:26,790
+كمية ايش زائدة من الاس او ثري طيب خلينا قبل ما
+
+254
+00:22:26,790 --> 00:22:30,270
+نمحي هذه نقولكوا هذا المعادلة بإيش بتذكركوا
+
+255
+00:22:30,270 --> 00:22:34,770
+التانية بلاش يقولوا
+
+256
+00:22:34,770 --> 00:22:44,120
+ايوة بإيش بالظبط ال acid rainالأمطار الحامضية لأن
+
+257
+00:22:44,120 --> 00:22:49,060
+المصانع .. المصانع بتطلع أبخرة SO2 .. أبخرة الـ
+
+258
+00:22:49,060 --> 00:22:54,280
+SO2 مع الميال في الجو والسحاب بتعمل H2SO3 هذا اللي
+
+259
+00:22:54,280 --> 00:22:57,520
+بنزل على الشجر و بيموته اللي بنسميه الـ acid rain
+
+260
+00:22:57,520 --> 00:23:02,520
+ال acid rain أو المطر الحامضي أو على المباني على
+
+261
+00:23:02,520 --> 00:23:06,980
+الحجر الجيري و المباني و ال .. الظواهر اللي بتصير
+
+262
+00:23:06,980 --> 00:23:10,520
+.. اكيد بتاعة ال .. ال acid rain
+
+263
+00:23:14,560 --> 00:23:21,140
+إذا خلطة ال H2SO4 و ال S O3 هي اللي بتطلع ليه؟ ال
+
+264
+00:23:21,140 --> 00:23:29,760
+S O3 H كلها كلها S O3 H بتكون positive و لا عن S
+
+265
+00:23:29,760 --> 00:23:34,780
+double bond O double bond O OH و من هنا بتتفاعل
+
+266
+00:23:34,780 --> 00:23:38,060
+واضح؟
+
+267
+00:23:38,060 --> 00:23:41,560
+أنتم بتذكرين كيف شكل ال sulfuric acid في الكيميا
+
+268
+00:23:41,560 --> 00:24:04,650
+ولا لأ؟التفصيل اللي هو الـ Sulphuric acid الواضح؟
+
+269
+00:24:04,650 --> 00:24:07,930
+هذا اللي هو اللي بيكون الـ Sulphur هنا ال positive
+
+270
+00:24:07,930 --> 00:24:12,610
+وهو اللي بيجي يتفاعلهو اللي بدو يجي يتفاعل
+
+271
+00:24:12,610 --> 00:24:19,910
+الإلكترونات بتتحرك عليه وبنفس المنطق بتتم استكمال
+
+272
+00:24:19,910 --> 00:24:26,010
+التفاعل بنفس المنطق بتتم عملية استكمال التفاعل
+
+273
+00:24:26,010 --> 00:24:30,390
+بنحصل على الـ Sulphonic acid هذا المركب اللي فيه
+
+274
+00:24:30,390 --> 00:24:38,450
+SO3H بيسموه إيش Sulphonic acid Sulphonic acid
+
+275
+00:24:40,460 --> 00:24:44,120
+أو مرات بكتبوا بنزين salphonic acid حر ينام مش
+
+276
+00:24:44,120 --> 00:24:55,720
+مشكلة بنجي
+
+277
+00:24:55,720 --> 00:25:03,140
+لتفاعل إضافي كيف نحط R group طبعا بدي ال R تكون
+
+278
+00:25:04,620 --> 00:25:09,200
+بوزيتف انا اتفقت هذه positive is a must لابد منها
+
+279
+00:25:09,200 --> 00:25:17,180
+لو جيبنا مثلا CH3Cl اللي هي عبارة عن RCl مع
+
+280
+00:25:17,180 --> 00:25:20,860
+ألومينيوميكلورايد الألومينيوميكلورايد لاحظوا برضه
+
+281
+00:25:20,860 --> 00:25:26,690
+لويسالوث أسد لأنه كام كلور متصل فيه؟ تلاتة، إذا
+
+282
+00:25:26,690 --> 00:25:30,030
+الألمنيوم عادسة إلكترونات بده إلكترونات،
+
+283
+00:25:30,030 --> 00:25:35,690
+فالألمنيوم الكلورايد بيسحب الكلورين مع إلكترونات
+
+284
+00:25:35,690 --> 00:25:39,810
+الرابطة على جهته، كل هذا الكلام بناشيه، أنا إيش
+
+285
+00:25:39,810 --> 00:25:45,030
+اللي بديه؟ إنه عمل polarization للجزء، خلال الـCH3
+
+286
+00:25:45,030 --> 00:25:49,150
+positive، خلال الـCH3 positive، هذا الـCH3
+
+287
+00:25:49,150 --> 00:25:54,150
+positive، هذا كله أنا؟ اتفقت؟إنه مش مهم عندي المهم
+
+288
+00:25:54,150 --> 00:25:58,750
+إنه بقدر أخد ال CH3 positive عطول إذا أخدناها
+
+289
+00:25:58,750 --> 00:26:06,890
+التفاعل بيصير straightforward، تلقائي، واضح؟ إذا
+
+290
+00:26:06,890 --> 00:26:12,670
+إيش الشرط لإضافة ال L-Kilogram لما أنا بفعل RCL
+
+291
+00:26:12,670 --> 00:26:20,250
+ولا RX؟وجود aluminium X3 عشان يسحب الـ X مع
+
+292
+00:26:20,250 --> 00:26:26,130
+إلكتروناتها ويسيب له الـ positive R واللي بدها
+
+293
+00:26:26,130 --> 00:26:31,510
+تتفاعل هي الـ positive R ممكن تكون CH3 ممكن تكون
+
+294
+00:26:31,510 --> 00:26:37,690
+إثل ممكن تكون بروبل المعادلة عامة يعني مش الزام بس
+
+295
+00:26:37,690 --> 00:26:43,390
+بالـCH3 لأ هي المعادلة بنقدر نعتبرها مع Rالمعادلة
+
+296
+00:26:43,390 --> 00:26:50,550
+نقدر نعتبرها معارض وبهيك بتتم عملية الـ alkylation
+
+297
+00:26:50,550 --> 00:26:58,470
+الـ alkylation اللي هو التفاعل مع الكل جروب يعني
+
+298
+00:26:58,470 --> 00:27:01,970
+ألمنيوم بي آر ثري أو إش .. لأ هو المناسب و سعره
+
+299
+00:27:01,970 --> 00:27:05,970
+معقول يستعمل بهذا التفاعل ألمنيوم كلورايد ألمنيوم
+
+300
+00:27:05,970 --> 00:27:06,570
+كلورايد
+
+301
+00:27:13,620 --> 00:27:19,200
+الآن هنا احنا حاطينلكم بعض ال limitations اللي هو
+
+302
+00:27:19,200 --> 00:27:24,280
+محددات لـ Frédéric Raft's alkylation طبعا بيسموه
+
+303
+00:27:24,280 --> 00:27:28,060
+نسبة للعالم أو للعلماء Frédéric Raft هذي ال
+
+304
+00:27:28,060 --> 00:27:32,520
+alkylation شو بيسموها؟ Frédéric Raft's alkylation
+
+305
+00:27:32,520 --> 00:27:36,820
+على حسب الناس اللي اشتغلوا الشغل الآن في عندى بعض
+
+306
+00:27:36,820 --> 00:27:43,510
+المشاكل اللي ممكن بدنا نواجههاوهي أن التفاعل بتتم
+
+307
+00:27:43,510 --> 00:27:51,310
+مع الـ RCl بس ما بتتمش مع الـ ArCl ولا مع الـ
+
+308
+00:27:51,310 --> 00:27:56,790
+Vinyl Cl الـ Ar بمعنى أنه لو كان عندى حلقة بنزين
+
+309
+00:27:56,790 --> 00:28:00,870
+تانية فيها Cl هل يا تورا ال .. ال aluminium
+
+310
+00:28:00,870 --> 00:28:03,930
+chloride بياخد من البنزين التانية لكلورة و
+
+311
+00:28:03,930 --> 00:28:08,790
+بيسيبليها موجبة؟لأ، لو كان عندى برضه vinyl
+
+312
+00:28:08,790 --> 00:28:14,070
+اكلورايد الـ vinyl متذاكرينه؟ اه، يعني هنا الـ RCl
+
+313
+00:28:14,070 --> 00:28:22,170
+هي معروفة من R مثل، إثل، بروبل، إش ما كان الـ ArCl
+
+314
+00:28:22,170 --> 00:28:28,050
+اللى هو aromatic يعني بنزين أو من جماعة البنزين
+
+315
+00:28:28,050 --> 00:28:34,370
+مشتقاته هنا ممكن أنه تفقد الـCl ويبقى عندى R
+
+316
+00:28:35,140 --> 00:28:39,300
+positive مافيش عندى اي مشكلة هنا لأ مابصيرش
+
+317
+00:28:39,300 --> 00:28:45,960
+التفاعل واضح؟ و هنا CL هل يا تورا يمكن أن تفقد من
+
+318
+00:28:45,960 --> 00:28:51,040
+هنا ال CL و يظل هذا positive لأ لأ مابصيرش اذا
+
+319
+00:28:51,040 --> 00:28:56,080
+التفاعل بس بيصير مع القلك ال highlights مابصيرش مع
+
+320
+00:28:56,080 --> 00:29:03,180
+القرق ال highlights و لا بيصير مع الدفين الهيمان
+
+321
+00:29:04,520 --> 00:29:12,700
+واضحة هذه النقطة هذه نقطة مهمة ال Rpg limitation
+
+322
+00:29:12,700 --> 00:29:19,060
+أو محدد تاني لهذا التفاعل بيعمل مشكلة ان حلقة
+
+323
+00:29:19,060 --> 00:29:25,280
+البنزين لو كان عليها بعض المجموعات المثبتة بنسميها
+
+324
+00:29:25,280 --> 00:29:31,520
+أو الساحبة للإلكترونات بيصير التفاعل بطيء تقريبا
+
+325
+00:29:31,520 --> 00:29:37,020
+ما بيمشيشوالمجموعات يعني لو كان عليها مجموعة أصلاً
+
+326
+00:29:37,020 --> 00:29:43,170
+وبيضيف كمان الكلواضح؟ لو كان عليها أصلاً مجموعة
+
+327
+00:29:43,170 --> 00:29:46,590
+وغير المجموعة بتضيف كمان الكلوة اللي هنعود نتوسع
+
+328
+00:29:46,590 --> 00:29:50,030
+فيه هذه المجموعات اللي .. اللي لو كانت موجودة
+
+329
+00:29:50,030 --> 00:29:53,990
+أصلاً على البنزين وبثبت التفاعل الـ Nitro،
+
+330
+00:29:53,990 --> 00:29:58,650
+السيانو، الـSO3H، الـCHO، الـCOR، الـCOH، الـC
+
+331
+00:29:58,650 --> 00:30:04,150
+double bond OR والـNR3 هذا النقطة بالذات هنرجعلها
+
+332
+00:30:04,150 --> 00:30:09,540
+مرة ثانيةإنه في مجموعات لو كانت أصلاً موجودة على
+
+333
+00:30:09,540 --> 00:30:14,060
+الحلقة بتعمل deactivation، deactivation يعني بتثبت
+
+334
+00:30:14,060 --> 00:30:20,180
+الحلقة وتبطل الحلقة تتفاعل، واضح؟ الشيء التاني أنه
+
+335
+00:30:20,180 --> 00:30:25,180
+لو ماكنش، بس كانت الكل جروب وإجي اتفاعلت مع مثل
+
+336
+00:30:25,180 --> 00:30:29,640
+الكلوريد، ممكن التفاعل مش بس يحط مثل واحدة، ممكن
+
+337
+00:30:29,640 --> 00:30:34,590
+يحط إتين أو تلاتةيعني يعمل multiple substitution
+
+338
+00:30:34,590 --> 00:30:39,550
+يعني يضيف أكثر من مجموعة في هذه الحالة كأنه بعد ما
+
+339
+00:30:39,550 --> 00:30:46,190
+يضيف أول مثل الحلقة إيش بتصير؟ Activatedمنشطة بحيث
+
+340
+00:30:46,190 --> 00:30:50,490
+أنها تضيف المجموعة التانية والتالتة إذن كأنه هناخد
+
+341
+00:30:50,490 --> 00:30:55,270
+بعد شوية أنه في ظاهرة اسمها activation حلقة منشطة
+
+342
+00:30:55,270 --> 00:31:00,290
+بدأت تتفاعل أكتر وفي deactivation في مجموعات بتعمل
+
+343
+00:31:00,290 --> 00:31:04,070
+activation بتشجع على المزيد من التفاعلات وفي
+
+344
+00:31:04,070 --> 00:31:09,170
+مجموعات بتعمل deactivation بتوقف التفاعلات واضح
+
+345
+00:31:09,170 --> 00:31:10,170
+هذا ال point؟
+
+346
+00:31:15,990 --> 00:31:21,450
+في عندنا كمان تفاعل اللي هو التفاعل مع الacetyl
+
+347
+00:31:21,450 --> 00:31:27,510
+groups انتوا مارة عليكم يمكن مجموعة إيش؟ الacetyl
+
+348
+00:31:27,510 --> 00:31:34,170
+اه متذكرين شو هي الacetyl؟ ال CH3C double bond اه
+
+349
+00:31:34,170 --> 00:31:42,270
+شو اسمها؟ Acetyl انتبهوا معايا في اسم عائلة وفي
+
+350
+00:31:42,270 --> 00:31:48,710
+اسم فرددايماً أسماء العائلات بنكون محددين شو
+
+351
+00:31:48,710 --> 00:31:54,080
+المجموعة اللي بنستخدم Rبنستخدم R يعني لو كنا
+
+352
+00:31:54,080 --> 00:32:00,820
+كاتبين احنا R C double bond O CL هذه ال R C double
+
+353
+00:32:00,820 --> 00:32:05,740
+bond O اسمها Ethyl group يمكن ال R فيها تكون مثل
+
+354
+00:32:05,740 --> 00:32:12,560
+ممكن إثل ممكن بروبل ممكن بيوتل أيه ان كانت واضح؟
+
+355
+00:32:12,560 --> 00:32:16,960
+اذا هذه المجموعة العامة ال general group شو اسمها؟
+
+356
+00:32:17,540 --> 00:32:24,960
+acetyl group الـ A لو كانت حالة خاصة الـ R مثل ..
+
+357
+00:32:24,960 --> 00:32:33,860
+شو بيصير اسم المجموعة؟ Acetyl واضح الفكرة؟ فالـ
+
+358
+00:32:33,860 --> 00:32:39,920
+Acetyl هي مجموعة خاصة حُددت فيها الـ R بإنها
+
+359
+00:32:42,590 --> 00:32:48,730
+واضح؟ فهذه أسل وهذه أستل الأسل المجموعة العامة
+
+360
+00:32:48,730 --> 00:32:53,330
+الآن إحنا لما بندرس التفاعل بندرسه بشكل عام مع كل
+
+361
+00:32:53,330 --> 00:32:58,910
+أنواع ال R ولذلك بنسمي التفاعل افريدي ل crafts
+
+362
+00:33:00,610 --> 00:33:05,170
+acetylation لو كنت بأقصد أني أخلي ال R مثل ممكن
+
+363
+00:33:05,170 --> 00:33:10,550
+أقول وجهتها Acetylation واضح؟ إذا ال Acetyl هي ال
+
+364
+00:33:10,550 --> 00:33:14,950
+general group اللي بنكتب فيها R ال Acetyl هي ال
+
+365
+00:33:14,950 --> 00:33:20,890
+specific group و ال R is CH3على أي حال، هذا
+
+366
+00:33:20,890 --> 00:33:25,430
+التفاعل أيضًا بالزمن فيه positive كيف بجيب ال
+
+367
+00:33:25,430 --> 00:33:29,670
+positive؟ بجيب افاعل مثلًا كمثال الـ Acetachloride
+
+368
+00:33:29,670 --> 00:33:33,170
+مع الـ Aluminium Chloride الآن الـ Aluminium
+
+369
+00:33:33,170 --> 00:33:40,670
+Chloride بدي أخد Cl مع إلكتروناتها، شو هيخليلها
+
+370
+00:33:40,670 --> 00:33:45,050
+على الكربون اللي هي موجب؟ هذا الموجب طبعًا ممكن
+
+371
+00:33:45,050 --> 00:33:49,490
+ينتقل بين الكربون والأكسجنيعني لو اتحرك زوج
+
+372
+00:33:49,490 --> 00:33:52,970
+إلكترونات من هنا يعني من الرابط التلاثية بيصير
+
+373
+00:33:52,970 --> 00:33:56,250
+الموجب على الـ Oxygen لو ضالت زي ما فقدت، بيكون
+
+374
+00:33:56,250 --> 00:33:59,250
+على الـ Carbon هو هنرسم أحد الـ Resonance
+
+375
+00:33:59,250 --> 00:34:03,210
+Structures له بشكل عام تعتبره في الأساس وين الـ
+
+376
+00:34:03,210 --> 00:34:07,610
+Positive موجود؟ على الـ Carbon يعني بمثل هذا الشكل
+
+377
+00:34:07,610 --> 00:34:11,250
+وفقدت الـCl، ضالت الـ Carbon positive الآن هذا الـ
+
+378
+00:34:11,250 --> 00:34:14,190
+Carbon الـ Positive هذا الـ Carbon الـ Positive
+
+379
+00:34:14,190 --> 00:34:22,270
+اللي هناوهي هتجي تتفاعل مع الحلقة بنفس المنطقة الـ
+
+380
+00:34:22,270 --> 00:34:26,630
+bond من الحلقة اتحركت عليها على الكربون الـ
+
+381
+00:34:26,630 --> 00:34:31,430
+positive و بعدين تفقد الهيدروجين إذا التفاعل بتم
+
+382
+00:34:31,430 --> 00:34:35,570
+بنفس الطريقة لاحظوا في جميع التفاعلات أنا عمال
+
+383
+00:34:35,570 --> 00:34:40,410
+الهدف الأساسي اللي بيضمنني أن التفاعل مشهي هو
+
+384
+00:34:40,410 --> 00:34:45,480
+تكوين الـ Electrophileوبشكل عام، في معظم الحالات
+
+385
+00:34:45,480 --> 00:34:49,640
+عامال عشان نكون الـ Electrophile شو كنا نضيف؟
+
+386
+00:34:49,640 --> 00:34:56,920
+Lewis acid مع الـ halogens ومع الـ الـ الـ RCL ومع
+
+387
+00:34:56,920 --> 00:35:02,980
+الـ Acyl halides في كل الأحوال، قاعدين نضيف احنا
+
+388
+00:35:02,980 --> 00:35:07,300
+Lewis acid عشان يكونلي الـ Electrophile اللي بدي
+
+389
+00:35:07,300 --> 00:35:12,860
+يعمل التفاعلبيكوّل ال electrified بيكوّل ال
+
+390
+00:35:12,860 --> 00:35:13,660
+electrified بيكوّل ال electrified بيكوّل ال
+
+391
+00:35:13,660 --> 00:35:14,240
+electrified بيكوّع ال electrified بيكوّع ال
+
+392
+00:35:14,240 --> 00:35:14,300
+electrified بيكوّع ال electrified بيكوّع ال
+
+393
+00:35:14,300 --> 00:35:14,380
+electrified بيكوّع ال electrified بيكوّع ال
+
+394
+00:35:14,380 --> 00:35:14,440
+electrified بيكوّع ال electrified بيكوّع ال
+
+395
+00:35:14,440 --> 00:35:15,300
+electrified بيكوّع ال electrified بيكوّع ال
+
+396
+00:35:15,300 --> 00:35:18,360
+electrified بيكوّع ال electrified بيكوّع ال
+
+397
+00:35:18,360 --> 00:35:24,100
+electrified بيكوّع ال electrified بيكوّع
+
+398
+00:35:24,100 --> 00:35:30,540
+ال electrified
+
+399
+00:35:30,540 --> 00:35:34,560
+بيكوّع
+
+400
+00:35:34,560 --> 00:35:36,880
+ال electr
+
+401
+00:35:38,580 --> 00:35:42,000
+لأ الهيدروجين هذا فقط القائمة هو وين بده يروح
+
+402
+00:35:42,000 --> 00:35:46,560
+الهيدروجين هذا اللي بده يفقد تنسيش أنه الهيدروجين
+
+403
+00:35:46,560 --> 00:35:51,700
+هذا لما بده يطلع بده يكون عنده aluminium Cl3 مع Cl
+
+404
+00:35:51,700 --> 00:35:56,560
+إضافية minus ال H plus اللي بتطلع من هنا بدي أخد
+
+405
+00:35:56,560 --> 00:36:02,710
+ال Cl minus لأقنعة Clواضح؟ يعني الـ H بلس اللي
+
+406
+00:36:02,710 --> 00:36:07,670
+بشجعه على الفقد موجود الـ Cl ماينوس اللي ملتصقة
+
+407
+00:36:07,670 --> 00:36:11,250
+لحظيا في الالمنيوم الكلورايد فالـ Cl ماينوس بتاخد
+
+408
+00:36:11,250 --> 00:36:15,930
+الـ H بلس قبل الـ HCl شو رجع عنده؟ الومنيوم
+
+409
+00:36:15,930 --> 00:36:20,410
+الكلورايد، بعيد الدائرة، برجع عند الومنيوم
+
+410
+00:36:20,410 --> 00:36:29,070
+الكلورايد و بعيد الدائرةطيب الآن لو قلنا بدنا ننظر
+
+411
+00:36:29,070 --> 00:36:39,650
+لهذه الأمثلة ونقولكوا أكمل المعادلة لاحظوا
+
+412
+00:36:39,650 --> 00:36:46,370
+هذا التفاعل شو نوعه؟ Acetylation أو Acetylation
+
+413
+00:36:46,370 --> 00:36:51,610
+الألومنيوميكلورايد بدي ياخد الـCl يصير عند ال
+
+414
+00:36:51,610 --> 00:36:57,310
+Electrophile شو النتيجة؟تكوين الـ acetyl group،
+
+415
+00:36:57,310 --> 00:37:00,230
+لاحظوا بتكون مع عدد CL، بس احنا دايما في ال
+
+416
+00:37:00,230 --> 00:37:04,290
+organic بنركز على ال organic product، يعني مراتي
+
+417
+00:37:04,290 --> 00:37:07,330
+بنكتبش النواتج التانية، أنا بهمن ال organic
+
+418
+00:37:07,330 --> 00:37:12,710
+product اسم
+
+419
+00:37:12,710 --> 00:37:16,360
+الشهرة أسيتوفينون أخدناه المرة الماضيةيعني كان
+
+420
+00:37:16,360 --> 00:37:23,760
+ممكن تسميه أسيت البنزين عادي بس طالما إله اسم شمرة
+
+421
+00:37:23,760 --> 00:37:27,620
+أشهر بدك تسميه أسيتوفينون بدك تسميه أسيتوفينون
+
+422
+00:37:27,620 --> 00:37:31,460
+واضح؟ بدك تسميه أسيتوفينون الأن لاحظوا في المرة
+
+423
+00:37:31,460 --> 00:37:36,060
+التانية HNO3 وH2SO4 شوف كيف كتبت ال agents بدقة
+
+424
+00:37:36,060 --> 00:37:40,760
+نيتريشن نيتريشن NO2 في المرة التالتة
+
+425
+00:37:44,140 --> 00:37:47,300
+هالوجيناشن؟ بده يروح الالمنيوم الكلورايد، هذا
+
+426
+00:37:47,300 --> 00:37:51,880
+الكيلاشن، هذا مش هالوجيناشن، this reaction is
+
+427
+00:37:51,880 --> 00:37:56,020
+الكيلاشن، هذا ايزوبروبليكلورايد، لما ييجي
+
+428
+00:37:56,020 --> 00:38:00,000
+الالمنيوم الكلورايد وياخد هذه الكلورين، وين هيسيب
+
+429
+00:38:00,000 --> 00:38:04,860
+له ال positive؟ على الكاربون الوسطانية، محل ما
+
+430
+00:38:04,860 --> 00:38:07,040
+انشلت الـCl، محل ما بيتفاعل
+
+431
+00:38:09,680 --> 00:38:16,300
+محل ما انشالت ال CL محل ما بيتفعل بالظبط واضح؟ طيب
+
+432
+00:38:16,300 --> 00:38:20,480
+خلّينا ناخد أخر معادلة نكتبها بالقلم وننهي
+
+433
+00:38:20,480 --> 00:38:24,760
+المحاضرة اليوم لو يا تورا إجينا فعلنا مش مع هذا
+
+434
+00:38:24,760 --> 00:38:29,220
+المُركّب لو إجينا عملنا كمان سهم وحطينا هذا
+
+435
+00:38:29,220 --> 00:38:35,400
+المُركّب في وجود H plus بروبين
+
+436
+00:38:45,690 --> 00:38:52,290
+شو بده يعمل هنا؟لاحظوا هنا لما فقد من هذا المثال
+
+437
+00:38:52,290 --> 00:39:00,370
+الـCL، إيش صار عندى؟ CH2، CH موجبة، CH3 طيب، لما
+
+438
+00:39:00,370 --> 00:39:05,570
+أنا بحط و أخدناه في تفاعلات الإضافة للالكينز الكين
+
+439
+00:39:05,570 --> 00:39:11,390
+مع H Plus، إيش دائما و أبدا الخطوة الأولى؟ إضافة
+
+440
+00:39:11,390 --> 00:39:14,210
+الـH Plus على الـDouble bond وكسرها و تكوين
+
+441
+00:39:14,210 --> 00:39:21,180
+Carbocation إذا، هدول الاتنين شو بيعملوا مع بعض؟هي
+
+442
+00:39:21,180 --> 00:39:26,740
+الـ H ضافة هنا دي صارت CH3 وضافة على الـ Bromine
+
+443
+00:39:26,740 --> 00:39:30,100
+والكربوكاتين اتكون هنا نفس الكربوكاتين اللي هنا
+
+444
+00:39:30,100 --> 00:39:37,660
+ولا لأ؟ نفسه نفس الاتكون هنا ممكن نكونه من خلال
+
+445
+00:39:37,660 --> 00:39:41,980
+تفاعل البروبين مع الـ H Plus صار نفس الكربوكاتين
+
+446
+00:39:41,980 --> 00:39:47,400
+بكم اللي بيعطيني نفس النتيجةإذاً، هذا المُركّب
+
+447
+00:39:47,400 --> 00:39:52,240
+اللي أنتوا شايفينه الآن بقدر أحضره بأكتر من طريقة
+
+448
+00:39:52,240 --> 00:39:56,980
+ممكن أخد Iso-Propyl chloride مع Aluminium chloride
+
+449
+00:39:56,980 --> 00:40:02,660
+بيعطوني Iso-Propyl-Cation وممكن أخد بروبين مع H
+
+450
+00:40:02,660 --> 00:40:06,760
+Plus بيعطوني برضه Iso-Propyl-Cation، نفس الـCation
+
+451
+00:40:06,760 --> 00:40:10,740
+إذاً التفاعل هيكمل لنفس الناتج
+
+452
+00:40:12,310 --> 00:40:16,830
+التفاعل هيكمل لنفس الناتج، لو أخدت reaction of
+
+453
+00:40:16,830 --> 00:40:21,210
+benzene with isopropyl chloride in presence of
+
+454
+00:40:21,210 --> 00:40:24,930
+aluminium chloride or reaction of benzene with
+
+455
+00:40:24,930 --> 00:40:29,370
+propene in presence of H plus produces سميليا، شو
+
+456
+00:40:29,370 --> 00:40:35,150
+اسم المركب؟ انت رافعيدك، كنت بدك تجاوبي، شو اسمه
+
+457
+00:40:35,150 --> 00:40:37,610
+بس، احنا خلينا في اسمه؟
+
+458
+00:40:41,960 --> 00:40:47,620
+وأنا حد فيكوا أفطر حمص عليه كمون؟ اكيومين ال
+
+459
+00:40:47,620 --> 00:40:56,940
+isopropyl بنزين له اسم شهرة أخدناه اكيومين اكيومين
+
+460
+00:40:56,940 --> 00:41:00,120
+اسم الشهرة تبع ال isopropyl بنزين اتفضل أسألك
+
+461
+00:41:00,120 --> 00:41:08,940
+عشانك
+
+462
+00:41:08,940 --> 00:41:13,700
+غيبتي جابلها بحصةما غيبتيش؟ إذا نتذكر معاه .. إذا
+
+463
+00:41:13,700 --> 00:41:17,160
+نتذكر معاه لما باطيفه على الطرف شو نوع ال
+
+464
+00:41:17,160 --> 00:41:23,280
+carbocation اللي بتكونه؟ secondary carbocation ..
+
+465
+00:41:23,280 --> 00:41:27,140
+مظبوط ولا لأ؟ و لو تفتح هنا شو نوع ال carbocation
+
+466
+00:41:27,140 --> 00:41:39,450
+اللي بتكونه؟بريماري كاربو كاتاينو نختبر
+
+467
+00:41:39,450 --> 00:41:44,170
+ذكائكم ونعطيكم سؤال هوميرك للحصة القادمة
+
+468
+00:41:47,150 --> 00:41:52,230
+انتبهوا هذا الكلام انا متأكد ان الطالبات الممتازات
+
+469
+00:41:52,230 --> 00:41:55,370
+بالبسطه على هيك اسئلة انا متأكد ان الطالبات
+
+470
+00:41:55,370 --> 00:41:59,850
+الممتازات بالبسطه على هيك اسئلة الان لو جبنالكوا
+
+471
+00:41:59,850 --> 00:42:05,690
+في أكمل المعادلة هذا المركب CH2 double bond CH
+
+472
+00:42:05,690 --> 00:42:16,400
+حطينا هنا C وحطينا H وCH3 وCH3 وقلنا في وجودأتش
+
+473
+00:42:16,400 --> 00:42:24,020
+بلاس وهدولة موجودين في أتش بلاس مع البنزين إيش بده
+
+474
+00:42:24,020 --> 00:42:29,160
+يكون النتيجة؟
+
+475
+00:42:29,160 --> 00:42:34,840
+عشان
+
+476
+00:42:34,840 --> 00:42:38,260
+انتوا بس تكتبوا صحيح، بناعطيكوا الفكرة الفكرة كلمة
+
+477
+00:42:38,260 --> 00:42:41,100
+واللي بتقولي الكلمة هعطيها علامة على طول هالجيتها
+
+478
+00:42:41,100 --> 00:42:43,680
+هتنزلها على كشف الدرجات إيش الفكرة اللي في هذا
+
+479
+00:42:43,680 --> 00:42:48,070
+السؤال؟فى الرابط اللى .. ماجيبتوش الفكرة اللى
+
+480
+00:42:48,070 --> 00:42:52,730
+بتاخدوا عليها علامة علامة هذى مش ببلاش ايش الفكرة
+
+481
+00:42:52,730 --> 00:42:57,210
+اللى بهدى السؤال ان الحديث في الرابط اللى مش هايل
+
+482
+00:42:57,210 --> 00:43:10,230
+نلعب فى البنزينة فكرة
+
+483
+00:43:10,230 --> 00:43:11,090
+أخدناها
+
+484
+00:43:14,650 --> 00:43:22,890
+لأ لأ لأ لاتش بلس حطي فارقة خلصنا من هالموضوع انا
+
+485
+00:43:22,890 --> 00:43:26,750
+مش راضي اجاوبها احذروا ليش مش راضي اجاوبها لأنه
+
+486
+00:43:26,750 --> 00:43:29,410
+اذا جوابت أكلكوا هتزعلوا انكوا ضيعتوا أحاركوا
+
+487
+00:43:29,410 --> 00:43:35,090
+علامة هتزعلوا
+
+488
+00:43:36,060 --> 00:43:40,100
+مش مشكلة لأنه بعد هيك هيصير rearrangement أول ما
+
+489
+00:43:40,100 --> 00:43:44,420
+أضيف ال H plus هنا الكاربو كاتيون هنا secondary
+
+490
+00:43:44,420 --> 00:43:49,020
+مباشرة هيصير hydride shift هيصير الكاربو كاتيون
+
+491
+00:43:49,020 --> 00:43:57,570
+هنا وهذه هتشبك من هنا مش من هناواضح الفكرة؟ بيصير
+
+492
+00:43:57,570 --> 00:44:00,850
+rearrangement الكلمة اللى كنت بدى أسمعها منكوا
+
+493
+00:44:00,850 --> 00:44:04,850
+كلمة rearrangement أنه أنا ضفت ال H plus هنا وين
+
+494
+00:44:04,850 --> 00:44:10,370
+صار ال carbocation؟ secondary فى إمكانية تتحرك ال
+
+495
+00:44:10,370 --> 00:44:15,970
+H هذه ويصير ال carbocation tertiary ومحل ما صار ال
+
+496
+00:44:15,970 --> 00:44:21,940
+carbocation tertiary بيكون عندى إيش؟محل ما صار
+
+497
+00:44:21,940 --> 00:44:25,920
+الكربوكاتيون الـ tertiary بصير التفاعل، إذا هنا
+
+498
+00:44:25,920 --> 00:44:32,160
+صارت فكرة الـ rearrangementفي حالة الـ Alkyl
+
+499
+00:44:32,160 --> 00:44:35,740
+Halides بالمناسبة عاد الـ rearrangements هذه اللي
+
+500
+00:44:35,740 --> 00:44:38,980
+برضه هنا لو كنتوا بتفقدوا كلور مش ضروري من خلال
+
+501
+00:44:38,980 --> 00:44:43,880
+الالكين وعملة secondary و بإمكانه يتحول إلى
+
+502
+00:44:43,880 --> 00:44:48,760
+tertiary برضه بيصير rearrangement بمعنى لو كان هذا
+
+503
+00:44:48,760 --> 00:44:56,460
+المركب زيك CH2 CH3 خليني أقول و هذه CHCL و هنا COH
+
+504
+00:44:56,460 --> 00:45:05,400
+و CH3 و CH3وحطينا هنا الومنيوم كلورايت الومنيوم
+
+505
+00:45:05,400 --> 00:45:09,480
+كلورايت شو بدي اعمل؟ هيسحب السيارة ليكوّل السكاندر
+
+506
+00:45:09,480 --> 00:45:15,160
+كاربو كاتايل هذا بيعمل ال arrangement والنتيجة ان
+
+507
+00:45:15,160 --> 00:45:20,540
+التفاعل لا يتم مكان الكلور انما يتم هنا هذه الجملة
+
+508
+00:45:20,540 --> 00:45:23,840
+اللي قبل شوية انا امشيت عليها بسرعة اذا بتتذكروا
+
+509
+00:45:23,840 --> 00:45:27,740
+هنا اخر كلمة ايش كان مكتوب عندكم
+
+510
+00:45:32,500 --> 00:45:38,820
+إنه في ال alkylation لما بتكون carbocation و بده
+
+511
+00:45:38,820 --> 00:45:44,960
+يتفاعل لو صاحله احسن وضعه بيحسن ولا لأ؟ لو صاحله
+
+512
+00:45:44,960 --> 00:45:48,900
+يعمل rearrangement بيعمل ولا لأ؟ شكرا
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/2zptYWX_3Yw_postprocess.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/2zptYWX_3Yw_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..ad7a76cdc96bcd43d12677af4290ad3318cbefb8
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/2zptYWX_3Yw_postprocess.srt
@@ -0,0 +1,1652 @@
+1
+00:00:19,980 --> 00:00:25,200
+بسم الله الرحمن الرحيمالحمد لله والصلاة والسلام
+
+2
+00:00:25,200 --> 00:00:30,300
+على رسول الله وعلى آله وصحبه وسلم تسليما كثيرا
+
+3
+00:00:30,300 --> 00:00:38,160
+وبعد لا يزال الحديث حول موضوع زواج المسيار كنا في
+
+4
+00:00:38,160 --> 00:00:43,860
+ما سبق تحدثنا عن التعريف لزواج المسيار عن النشأة
+
+5
+00:00:43,860 --> 00:00:48,500
+لهذا الزواج النشأة المكانية وكيف أنها بعد ذلك
+
+6
+00:00:48,500 --> 00:00:57,190
+انتشرت في كثير من البلدانثم تحدثنا أيضًا عن وجوه
+
+7
+00:00:57,190 --> 00:01:03,270
+المقارنة بين زواج المسيار وبعض الأنواع العقد
+
+8
+00:01:03,270 --> 00:01:09,330
+الأخرى بدءًا بالفرق بين زواج المسيار وعقد الزواج
+
+9
+00:01:09,330 --> 00:01:15,540
+الشرعي الصحيح وقلنا بأنها التفيقانأي هدان العقدان
+
+10
+00:01:15,540 --> 00:01:19,620
+الزواج المسيار والزواج العادى الشرعى في كونهما
+
+11
+00:01:19,620 --> 00:01:23,720
+مستقملان للأركان والشروط ويختلفان في كون زواج
+
+12
+00:01:23,720 --> 00:01:31,420
+المسيار فيه تنازل من المرأة عن بعض حقوقها المستحقة
+
+13
+00:01:31,420 --> 00:01:38,480
+لهذا العقدثم قررنا كذلك بين عقد زواج المسيار
+
+14
+00:01:38,480 --> 00:01:43,380
+والزواج العرفي أو النكاح السر وقلنا بأن نكاح السر
+
+15
+00:01:43,380 --> 00:01:49,060
+أو الزواج العرفي له صور متعددة بعضها مقبولة شرعا
+
+16
+00:01:49,060 --> 00:01:56,260
+وبعضها غير مقبولة وبعضها مختلفة فيها لكن القاسم
+
+17
+00:01:56,260 --> 00:02:00,880
+المشترك بين صور زواج السر أو الزواج العرفي جميعا
+
+18
+00:02:00,880 --> 00:02:07,180
+هو كونها غير موثقةتوثيقا رسميا في الدوائر الحكومية
+
+19
+00:02:07,180 --> 00:02:13,120
+أو في المحاكم الشرعية لكن بعض صورها وإن كانت غير
+
+20
+00:02:13,120 --> 00:02:18,300
+مواثقة مستقملة لأركانها وشروطها من حيث الولي
+
+21
+00:02:18,300 --> 00:02:24,100
+والشهود والإيجاب والقمول وكل ذلك وهذه تكاد تكون
+
+22
+00:02:24,100 --> 00:02:28,620
+محل اتفاق لو لا مخالفات البعض باعتبار من باب
+
+23
+00:02:28,620 --> 00:02:33,200
+الحيطة بسبب عدم التوثيق والبعض
+
+24
+00:02:35,650 --> 00:02:40,890
+والصورة الأخرى و الصورة الأخرى عندما لا يكون هناك
+
+25
+00:02:40,890 --> 00:02:46,150
+توثيق بالإضافة إلى عدم وجود لا ولي ولا شهود فهذه
+
+26
+00:02:46,150 --> 00:02:53,050
+محل اتفاق على بطلانها وحرمتها أما إذا كان هناك
+
+27
+00:02:53,050 --> 00:02:58,590
+شهود و بلا ولي و بلا توثيق فالأمر محل خلافة القاسم
+
+28
+00:02:58,590 --> 00:03:04,150
+أو الوجه وجه الشبح إن صح التعبير بين زواج المسيار
+
+29
+00:03:04,930 --> 00:03:11,390
+والزواج العرفي بصوره المختلفة يعني يختلف باختلاف
+
+30
+00:03:11,390 --> 00:03:17,030
+كل صورة، كل صورة، يعني الزواج الرسيار والزواج
+
+31
+00:03:17,030 --> 00:03:23,190
+العرفي المكتمل للأركان والشروط متفقان من حيث
+
+32
+00:03:23,190 --> 00:03:26,990
+اجتماع كل منهم للأركان والشروط ومختلفا من حيث
+
+33
+00:03:26,990 --> 00:03:33,620
+التوثيق وعدمهومسألة التوثيق هذه حقيقة هي فارق
+
+34
+00:03:33,620 --> 00:03:39,280
+أساسي بين زواج المسيار وكل صور الزواج العرفي كل
+
+35
+00:03:39,280 --> 00:03:43,140
+صور الزواج العرفي غير موثق أما زواج المسيار فالأصل
+
+36
+00:03:43,140 --> 00:03:48,840
+فيه أنه موثق حتى وإن تنازلت المرأة عن بعض حقوقها
+
+37
+00:03:48,840 --> 00:03:54,140
+لكن المشكلة عندما يكون هناك زواج ممسيار وأيضا هو
+
+38
+00:03:54,140 --> 00:03:59,860
+غير موثق أويعني بلا ولي أو بلا شهود هنا تزداد
+
+39
+00:03:59,860 --> 00:04:07,060
+المشكلة وربما يصل إلى درجة المنع بالاتفاق أو إلى
+
+40
+00:04:07,060 --> 00:04:14,450
+زيادة هوة الخلافبينهما وقوته ذلك أن الخلافة اللي
+
+41
+00:04:14,450 --> 00:04:19,950
+نجده اليوم بزواج المسيار رغم اكتمال شروطه وأركانه
+
+42
+00:04:19,950 --> 00:04:25,930
+فقط لأن هناك تنازلات من قبل المرأة عن بعض حقوقها
+
+43
+00:04:25,930 --> 00:04:31,330
+هناكخلاف لكن الخلاف دعني أقول ربما يكون ضعيفا
+
+44
+00:04:31,330 --> 00:04:36,890
+بمعنى أننا سنجد أن الراجح هو القول بجواز زواج
+
+45
+00:04:36,890 --> 00:04:41,810
+المسيار لكن عندما يكون زواج المسيار فيه بعض الصفات
+
+46
+00:04:41,810 --> 00:04:47,090
+الموجودة إضافة في زواج العرفي من عدم التوثيق أو
+
+47
+00:04:47,090 --> 00:04:51,590
+عدم الإشهاد أو عدم الولاية فهنا يتزداد إشكالية
+
+48
+00:04:51,590 --> 00:04:58,870
+زواج المسيار في هذه الحالة ويتزدادويزداد يعني
+
+49
+00:04:58,870 --> 00:05:05,030
+ترجيح القول ويكون رجحان القول ببطلانه ربما هو
+
+50
+00:05:05,030 --> 00:05:08,210
+الأولى في هذه الحالة على كل الأحوال إذن هذا
+
+51
+00:05:08,210 --> 00:05:12,690
+بالنسبة لزواجهالمسيار وزواج العُرفى أما زواج
+
+52
+00:05:12,690 --> 00:05:20,570
+المسيار وزواج المتعة فربما يعني يتفقان من حيث ان
+
+53
+00:05:20,570 --> 00:05:27,190
+ان كل منهما لا يترتب عليه أو تسقط المرأة فيه في
+
+54
+00:05:27,190 --> 00:05:31,310
+الغالب حقوقها أو كثير من حقوقها فإذا كان زواج
+
+55
+00:05:31,310 --> 00:05:35,450
+المسيار وهو المكتمل للأركان والشروط تسقط المرأة في
+
+56
+00:05:35,450 --> 00:05:42,970
+حقوقها فزواج المتعة كذلكهو يعني مجرد زواج لمدة
+
+57
+00:05:42,970 --> 00:05:48,550
+محددة ولا يترتب عليه أو لا يلتزم به الرجل بأي حقوق
+
+58
+00:05:48,550 --> 00:05:54,470
+نحو المرأة فربما يتشبهن هذه الزاوية لكن الإختلاف
+
+59
+00:05:54,470 --> 00:06:00,630
+واضح وكبير بينهما من حيث إن زواجة ألم السيارة
+
+60
+00:06:00,630 --> 00:06:05,430
+مكتمل مرة أخرى أقول الأركان والشروط وهو على سبيل
+
+61
+00:06:05,430 --> 00:06:10,430
+التأبيدكما هو الأصل في الزواج الشريعي الصحيح بينما
+
+62
+00:06:10,430 --> 00:06:16,190
+زواج المتعة على سبيل التوقيت وهذا مخالف لمقصد
+
+63
+00:06:16,190 --> 00:06:23,560
+الشريعة في الزواجهذا كله تحدثنا في المرة الماضية
+
+64
+00:06:23,560 --> 00:06:28,580
+ربما لنصل إلى الحديث في باقية المقدمات قبل أن نصل
+
+65
+00:06:28,580 --> 00:06:36,740
+إلى الحكم لنحديث عن أسباب ظهور أو وجود وانتشار
+
+66
+00:06:36,740 --> 00:06:42,300
+زواج المسيح يعني هذه الأسباب لم نتحدث عنها المرة
+
+67
+00:06:42,300 --> 00:06:47,530
+الماضية ولا تحدثنا عنهايعني هي استكمال للحديث عن
+
+68
+00:06:47,530 --> 00:06:52,310
+النشأة احنا تحدثت عن النشأة المكانية وأنها أول ما
+
+69
+00:06:52,310 --> 00:06:56,890
+ظهرت هذه الظاهرة في السعودية في بلدة القصيم أو
+
+70
+00:06:56,890 --> 00:07:00,470
+مدينة القصيم ثم انتشرت في دول الخليج لكن ما هي
+
+71
+00:07:00,470 --> 00:07:07,200
+وربما يعني احنا تعرفنا بالاجمالعلى الأسباب عموما
+
+72
+00:07:07,200 --> 00:07:14,960
+لكن بالتفصيل أسباب ظهور زواج المسيار حقيقة يعني لا
+
+73
+00:07:14,960 --> 00:07:20,700
+تعود فقط إلى المرأة كما قد يظن أو ليست سببها فقط
+
+74
+00:07:20,700 --> 00:07:28,860
+يعني مشكلة المرأة من عنوس أو طلاق أو كونها أرمل أو
+
+75
+00:07:28,860 --> 00:07:33,010
+إلى غير ذلك بل ربما تقود إلى المرأةفي السبب
+
+76
+00:07:33,010 --> 00:07:36,390
+الرئيسي وربما تعودوا إلى الراجل وربما المجتمع
+
+77
+00:07:36,390 --> 00:07:46,510
+أيضًا إذا هناك ثلاث جهات كل جهة هي تكون سابقًا أو
+
+78
+00:07:46,510 --> 00:07:53,470
+تساهم بمجموعة من الأسباب أو ساهمت بالفعل حتى وجدنا
+
+79
+00:07:53,470 --> 00:08:00,370
+هذا النوع من أنواع الزواج بات ظاهرة أو انتشرة في
+
+80
+00:08:00,370 --> 00:08:05,450
+كثير من البلدانأما بالنسبة للأسباب التي تعودوا
+
+81
+00:08:05,450 --> 00:08:10,190
+للمرأة أو للنساء فقد تطرقنا إليها يعني ما هي ظاهرة
+
+82
+00:08:10,190 --> 00:08:14,970
+وجود مشكلة العنوثة أو كثرة الأرامل بسبب وجود حروب
+
+83
+00:08:14,970 --> 00:08:17,890
+معينة أو كثرة المطلقات بسبب وجود المشاكل
+
+84
+00:08:17,890 --> 00:08:24,370
+الاجتماعية هذه الظاهرة أو هذا السبب يجعل علماء
+
+85
+00:08:24,370 --> 00:08:32,160
+الاجتماعوالحريصين على استقرار المجتمع الذي يعيشون
+
+86
+00:08:32,160 --> 00:08:35,860
+فيه على البحث عن حلول وهذا ما فعله فهد الغنيم
+
+87
+00:08:35,860 --> 00:08:40,640
+عندما وجد أن هذه المشكلة مشكلة العنوان تتفاقم في
+
+88
+00:08:40,640 --> 00:08:46,940
+بلدهفأخد يروجه أو فوجد هذا الحل و أخد يروجه له و
+
+89
+00:08:46,940 --> 00:08:53,680
+بدأ التفاعل معاه و بدأ يعني ينتشر و بعد ذلك بدأ
+
+90
+00:08:53,680 --> 00:09:03,410
+العلماء يتحدثون و يبينون حكمةإذن هذا سبب وسبب آخر
+
+91
+00:09:03,410 --> 00:09:09,370
+من أسباب وجود هذه الظاهرة وتتعلق بالنساء أنفسهم
+
+92
+00:09:09,370 --> 00:09:18,610
+أيضا وهو رفض النساء لظاهرة التعدد أو لزواج التعدد
+
+93
+00:09:21,090 --> 00:09:31,250
+الأصل أنه يعني الإنسان إذا لم يوفق في زواج معين
+
+94
+00:09:31,250 --> 00:09:36,450
+ولا يريد الطلاق لسبب أو لآخر له شرع الله عز وجل
+
+95
+00:09:36,450 --> 00:09:40,610
+للزوج عن الزوج من ثانية وثالثة خاصة عندما يكون
+
+96
+00:09:40,610 --> 00:09:47,290
+هناك سبب معين وإن وراء ذلك تنكحوا ما طاب لكم من
+
+97
+00:09:47,290 --> 00:09:52,450
+الإنسان ماتنة وثلاثة وربع ولكنخاصة في العصور
+
+98
+00:09:52,450 --> 00:10:01,110
+الحاضرة التي نعيش لم يعد تعدد في الزواج ظاهرة
+
+99
+00:10:01,110 --> 00:10:06,770
+مقبولة لدى النساء أنفسهم أقول لا لدى المرأة التي
+
+100
+00:10:06,770 --> 00:10:11,230
+يريد زوجها أن يعدد عليها أو يتزوج عليها ولا لدى
+
+101
+00:10:11,230 --> 00:10:14,970
+المرأة التي يريد أن يتزوجها لا هذه تقبل في العام
+
+102
+00:10:14,970 --> 00:10:18,850
+الأغلبلكن احنا احيانا نجد طبعا النادر لا حكم له
+
+103
+00:10:18,850 --> 00:10:22,790
+لكن في العام الأغلب المرأة لا تقبل الا بأن تكون
+
+104
+00:10:22,790 --> 00:10:28,020
+متفردة او الزوجة الأولى والاخيرةوكذلك يعني إذا
+
+105
+00:10:28,020 --> 00:10:34,140
+كانت .. فلذلك لو أراد الرجل أن يتزوج من امرأة أخرى
+
+106
+00:10:34,140 --> 00:10:41,000
+أو يريد أن يعدد فإنه لا يلقى قبولا من قبل النساء
+
+107
+00:10:41,000 --> 00:10:47,480
+أو أهليهم اللواتي يريد أن يتزوج منهن أو يتقدم
+
+108
+00:10:47,480 --> 00:10:49,900
+اليهن نظرا
+
+109
+00:10:51,350 --> 00:10:57,050
+للثقافة المنتشرة في هذا المجتمع أو بغض النظر أو
+
+110
+00:10:57,050 --> 00:11:01,390
+لأن المرأة بطبيعتها كأي إنسان كأي إنسان يا أخوتي
+
+111
+00:11:01,390 --> 00:11:06,810
+هي مش يعني التعدد يعني في شيء من المقاسمة في مصلحة
+
+112
+00:11:06,810 --> 00:11:12,020
+معينةوهذا فيه ضرر والإسلام يعترف به بالمناسبة لكن
+
+113
+00:11:12,020 --> 00:11:17,880
+مشروعية الإسلام أو شرعانة الإسلام للزواج من ثانية
+
+114
+00:11:17,880 --> 00:11:22,840
+رغم ما فيه من ضرر أقول بكل وضوح رغم ما فيه من ضرر
+
+115
+00:11:22,840 --> 00:11:28,980
+قد يقع على الزوجة أو على الأسرة لكنه إنما شرع لضرر
+
+116
+00:11:28,980 --> 00:11:36,570
+أكبر لدفع ضرر أكبرمتمثل في يعني وقوع الرجل أحيانا
+
+117
+00:11:36,570 --> 00:11:42,870
+او احتمالية وقوعه في الفاحشة او لأنه يرغب في الولد
+
+118
+00:11:42,870 --> 00:11:47,750
+اذا كان ممكن او لأسباب متعددة تكون اكبر من انه من
+
+119
+00:11:47,750 --> 00:11:57,200
+مسائل مادية او ضرر يقع علىهذه المرأة أو تلك فطبيعة
+
+120
+00:11:57,200 --> 00:12:01,860
+الإنسان طبعا يعني يريد أن يدفع الضرر عن نفسه هذا
+
+121
+00:12:01,860 --> 00:12:10,720
+لكن الشرع ينظره بنظرة واسعة و عامة و متكاملة و كما
+
+122
+00:12:10,720 --> 00:12:15,180
+قلت يعني رغم أنه ممكن يعني يترتب على هذا الحكم بعض
+
+123
+00:12:15,180 --> 00:12:20,960
+الأضرار التي تلحق ببعض الأفرادلكن عليه هذا الفرد
+
+124
+00:12:20,960 --> 00:12:26,700
+أن يفهم أن ثمة مصطحة أعظم تتحقق وعليه أن يرضى وأن
+
+125
+00:12:26,700 --> 00:12:34,480
+يقبل بذلك لكن أن له أن يقبل في ظل ظروف يعني فرضت
+
+126
+00:12:34,480 --> 00:12:38,680
+على المجتمع أو جعلت من الزواج من ثانية جريمة
+
+127
+00:12:38,680 --> 00:12:45,420
+وخيانة وإلى ما سوى ذلك ولم تجعل النساء يقبلن هذا
+
+128
+00:12:45,420 --> 00:12:53,410
+بحال من الأحوالأفلام وتمثليات بعض الدول العربية
+
+129
+00:12:53,410 --> 00:12:57,610
+المحيطة بنا والتي انتشرت على مدار عقود من الزمان
+
+130
+00:12:57,610 --> 00:13:05,690
+يعني أفسدت عقول الرجال والنساء وجرّمت هذا العمل أو
+
+131
+00:13:05,690 --> 00:13:11,010
+هذا الحكم الشرعي الطاهر الذي يريد أن ينشر الطهارة
+
+132
+00:13:11,010 --> 00:13:16,730
+والنظافة والاستقرار في المجتمع حقيقةعلى كل الأحوال
+
+133
+00:13:16,730 --> 00:13:21,610
+المهم ان احنا في النتيجة ان النساء بغض النظر عن
+
+134
+00:13:21,610 --> 00:13:26,730
+السبب ورا هذه الفكرة والسبب ورا هذا الرفض المهم ان
+
+135
+00:13:26,730 --> 00:13:32,930
+السبب ان النساء لم تتقبل فكرة التعدد مما دفع
+
+136
+00:13:32,930 --> 00:13:38,670
+الرجال الذين يريدون ان يتزوجوا من ثانية ان يتجهوا
+
+137
+00:13:38,670 --> 00:13:45,810
+الى زواج المسيار دفعا لضرر ايضاخوفا لأن المرأة في
+
+138
+00:13:45,810 --> 00:13:53,150
+ظل رغبة الرجل بالتعدد ربما يعني تقلب البيت و بماذا
+
+139
+00:13:53,150 --> 00:14:00,110
+اخر تسبب مشكلة كبيرة فلذلك دفع لهذه المشكلة فهو
+
+140
+00:14:00,110 --> 00:14:05,580
+يذهب الى زواج المسيار اللي هو فيه لغالمبكون فيه
+
+141
+00:14:05,580 --> 00:14:09,200
+يعني عدم إعلام المرأة الأولى فيه هو جانب الإشهار
+
+142
+00:14:09,200 --> 00:14:12,140
+هناك والإعلام عشان ما نكون مش .. ما .. ليس زواج
+
+143
+00:14:12,140 --> 00:14:16,520
+سره هو زواج معلن لكن معلن لدى أهل الزوجة والبيئة
+
+144
+00:14:16,520 --> 00:14:20,620
+اللي هو تزامن لكن في الغالب أن المرأة زوجته لا
+
+145
+00:14:20,620 --> 00:14:26,120
+تعلم بذلك خاصة أنه يعني أن المدة التي يقضيها معها
+
+146
+00:14:26,120 --> 00:14:34,300
+لا تشككه في كونه متزوج المدةيكون خصيرة كما قلنا
+
+147
+00:14:34,300 --> 00:14:38,300
+يوم في الأسبوع شهر في السنة أسبوعين في كل .. وكذا
+
+148
+00:14:38,300 --> 00:14:43,140
+مدة قليلة لا تؤثر وربما لا تشعر أقول وحتى لو علمة
+
+149
+00:14:43,140 --> 00:14:52,380
+المرأة لا يعني لا يترتب على ذلك كما يترتب فيما لو
+
+150
+00:14:52,380 --> 00:14:58,200
+فيما لو كان متزوجا زواجا عاديا من ثانية يعني هي
+
+151
+00:14:58,200 --> 00:15:04,250
+ممكن تعمل حالها مش عارفةخالص أو حتى لو يعني علمت
+
+152
+00:15:04,250 --> 00:15:10,110
+بذلك فإن الضرر في ما تراه هي يعني خفيف هي أساسا
+
+153
+00:15:10,110 --> 00:15:16,200
+رافضة التعدد للبرر واحد يجسمها نص بالنصفي مصلحة
+
+154
+00:15:16,200 --> 00:15:20,340
+معينة لكن الآن في هذا الزواج مافيش مقاسمة مافيش
+
+155
+00:15:20,340 --> 00:15:24,300
+مقاسمة تقريبا يعني هو طبيعي أن الراجل ممكن يغيب
+
+156
+00:15:24,300 --> 00:15:31,060
+غيبات كل فترة معينة لعمل لتجارة لتعليم لكذا لكذا
+
+157
+00:15:31,060 --> 00:15:35,740
+فهي لا تشعر بهذه المقاسمة على الأرض خاصة وإضافة
+
+158
+00:15:35,740 --> 00:15:39,840
+إلى ذلك أنه لا نفقة الراتب زي ما هو مش مانجوز كله
+
+159
+00:15:39,840 --> 00:15:45,380
+في إيدهاما مشكلة يعني ما .. ما .. مافيش من المخزون
+
+160
+00:15:45,380 --> 00:15:48,800
+أنه يشتري بيت للبيت لل .. لل .. للثاني لأنه هي
+
+161
+00:15:48,800 --> 00:15:52,980
+موفرة البيت وموفرة كل إشي فمافيش ضرر فلذلك قد تقبل
+
+162
+00:15:52,980 --> 00:15:58,670
+بذلك أو يعني .. او يعني حد وين عالي مايتقدرتتجاهل
+
+163
+00:15:58,670 --> 00:16:06,570
+الأمر إذا يعني نرجع لعدم قبول تعدد الزواج هو سبب
+
+164
+00:16:06,570 --> 00:16:11,750
+آخر ثم سبب ثالث يعود إلى المرأة كل هذه تعود إلى
+
+165
+00:16:11,750 --> 00:16:19,130
+المرأة الأسباب أن أحيانا المرأة نفسها محتاجة حقيقة
+
+166
+00:16:19,130 --> 00:16:27,070
+إلى أن تتزوج وتبقى في بيت أهلهاوتبقى في بيت أهلها
+
+167
+00:16:27,070 --> 00:16:32,170
+لماذا؟ لمرضهم، لحاجتهم، لأي سبب، لا .. لا .. لا ..
+
+168
+00:16:32,170 --> 00:16:33,410
+لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا
+
+169
+00:16:33,410 --> 00:16:34,030
+.. لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا ..
+
+170
+00:16:34,030 --> 00:16:34,550
+لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا
+
+171
+00:16:34,550 --> 00:16:35,850
+.. لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا ..
+
+172
+00:16:35,850 --> 00:16:36,670
+لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا
+
+173
+00:16:36,670 --> 00:16:37,950
+لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا
+
+174
+00:16:37,950 --> 00:16:38,590
+.. لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا ..
+
+175
+00:16:38,590 --> 00:16:39,010
+لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا .. لا
+
+176
+00:16:39,010 --> 00:16:42,250
+لا .. لا .. لا .. لا .. لا .. لا ..
+
+177
+00:16:42,250 --> 00:16:46,490
+لا .. لا
+
+178
+00:16:48,330 --> 00:16:54,690
+و في الوضع الطبيعي هي تصر على أن تنتقل و تقوم بيتا
+
+179
+00:16:54,690 --> 00:16:59,430
+و شقة و إلى غير ذلك لكن المرة العكس المرة بتقول لأ
+
+180
+00:16:59,430 --> 00:17:05,800
+اللي بده يعنيأنا متنازل عن السكن وهي السكن جاهز
+
+181
+00:17:05,800 --> 00:17:12,520
+هنا موجود ويا سيدي بلاش إذا كان عنده زوجة أخرى أو
+
+182
+00:17:12,520 --> 00:17:15,960
+حتى لو لم يكن متزوج بالمناسبة زواج المسيار ليس
+
+183
+00:17:15,960 --> 00:17:19,880
+مرتبط بالمتزوجين فقط ممكن يكون زواج المسيار للعزاب
+
+184
+00:17:19,880 --> 00:17:24,430
+يعني أيضا وكل مرة دكتور تتنازل عن السكن؟كل انتوات
+
+185
+00:17:24,430 --> 00:17:27,150
+من السيارة .. لا مش بالضرورة .. مش بالضرورة .. هذا
+
+186
+00:17:27,150 --> 00:17:31,010
+احد الحقوق منهما من يتنزل عن السكن منهما من يتنزل
+
+187
+00:17:31,010 --> 00:17:34,710
+عن النفقة منهما من يتنزل عن المبيت او عن القسم و
+
+188
+00:17:34,710 --> 00:17:41,570
+منهما من يتنزل عن حقين او ثلاثةمش شرق لأ، أي تنازل
+
+189
+00:17:41,570 --> 00:17:46,690
+عن أي حق هو يعطي صورة من صور زواج المسيحان، اه
+
+190
+00:17:46,690 --> 00:17:52,670
+النفقة لحالها ما هي هذه المشوار أو حق مستمر،
+
+191
+00:17:52,670 --> 00:17:58,840
+المبيت برضه حق مستمر أو القسم فيهالمهر لأ، ليش؟
+
+192
+00:17:58,840 --> 00:18:03,200
+لأن المهر واجب، لكن ممكن تنزل فيه كيف تصير، أيوة
+
+193
+00:18:03,200 --> 00:18:08,400
+يعني بشيء رمزي أو ممكن نقول له خد يا سيدي ها أدفع،
+
+194
+00:18:08,400 --> 00:18:16,770
+يد ما بده أبويا، ها؟ ها ممكنمن جبتها يعني على أساس
+
+195
+00:18:16,770 --> 00:18:21,670
+أنه يجب المهر يعني حتى أن البعض اعتبر المهر ركنا
+
+196
+00:18:21,670 --> 00:18:26,070
+كالمالكية ركنا في صحة الزواج لكن حقيقة جمهور
+
+197
+00:18:26,070 --> 00:18:29,830
+العلماء أن المهر حتى لو لم تدفعه لا يؤثر على صحة
+
+198
+00:18:29,830 --> 00:18:33,950
+الزواج ولكن يبقى دايما في ذمتك ولذلك وجب مهر مثل
+
+199
+00:18:33,950 --> 00:18:39,150
+حتى عند عدم التسمية حتى عند عدم التسمية أمر ثابت
+
+200
+00:18:39,150 --> 00:18:44,770
+لكن ممكن احنا قلناالتمس ولو ختمت من الحديد يعني مش
+
+201
+00:18:44,770 --> 00:18:47,810
+إيش كان المهرف إيش فيه مشكلة يعني أي حاجة بتمشي
+
+202
+00:18:47,810 --> 00:18:52,910
+زوجتكها بما بتعلم أو بتعليمها القرآن
+
+203
+00:18:56,040 --> 00:19:00,100
+بما معك من القرآن يعني أن تعلمها بما معك من القرآن
+
+204
+00:19:00,100 --> 00:19:07,140
+ف .. هذا .. إذا هذه بعض أسباب تتعلق بالمرأة لكن زي
+
+205
+00:19:07,140 --> 00:19:12,380
+ما قلنا ليست كل الأسباب لظهور وانتشار زواج المسيار
+
+206
+00:19:12,380 --> 00:19:15,720
+متعلقة بالمرأة فهناك دوافع من قبل الرجل أيضا أو
+
+207
+00:19:15,720 --> 00:19:22,400
+أسباب تعود للرجل نفسه يعني تماما تشبه الأسباب التي
+
+208
+00:19:22,400 --> 00:19:27,670
+تعود في رغبته في التعددرغبته في التعدد لكن هو مش
+
+209
+00:19:27,670 --> 00:19:32,850
+قادر زي ما قلنا على التعدد و لكنه يريد أن يتزوج و
+
+210
+00:19:32,850 --> 00:19:38,270
+ربما بعض الرجال لاتكفيهم امرأة واحدة فولكن في نفس
+
+211
+00:19:38,270 --> 00:19:44,850
+الوقت عندما يريد ان يعدد يجد مشكلة يجد ضررا فيدفعه
+
+212
+00:19:44,850 --> 00:19:54,550
+ذلك الى ان يستعيض بزواج المسيح فيقضي حاجته و رغبته
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+213
+00:19:55,940 --> 00:20:05,360
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+
+214
+00:20:05,360 --> 00:20:08,540
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+215
+00:20:08,540 --> 00:20:13,020
+زواج و متزوج نسيار هو تحت مظلة التعدد لكن صورته
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+216
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+مختلفة فقط يعني عن التعدد العادي لأن التعدد العادي
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+217
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+218
+00:20:23,280 --> 00:20:30,580
+عدل في القسم وكل شيء هذا في تنازل عن بعض الحكومة
+
+219
+00:20:31,910 --> 00:20:36,250
+طبعاً قد يكون الدافع مادي يعني هناك الدافع هو
+
+220
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+الرغبة الفطرية عند الرجل وعدم الكفاية اكتفائه
+
+221
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+بواحدة أو حتى لو لم يكن كما قلت متزوج هو ماعندوش
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+222
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+أساسا ماعندوش يعني شاب وأعزب وبلغ ثلاثين ربما وليس
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+223
+00:20:53,630 --> 00:21:03,320
+فقيرففي امرأة يعني متسعدة تتنازل عنه عن يعني
+
+224
+00:21:03,320 --> 00:21:08,180
+النفقة وعن كذا وعن كذا لكن عمرها اربعين سنة مثلا
+
+225
+00:21:08,180 --> 00:21:14,920
+يعني او خمس واربعين قد يعنييجدوا .. فهو دافع ..
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+226
+00:21:14,920 --> 00:21:20,000
+الدافع المادي عنده وعدم الرغبة في التحمل التكاليف
+
+227
+00:21:20,000 --> 00:21:23,480
+وممكن يكون هذا يعني صورة أخرى ممكن يكون غني لكن
+
+228
+00:21:23,480 --> 00:21:28,300
+بخيل ومبدوش يدفع فلجاها ممكن يكون هذا الدافع أيضا
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+229
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+اهأه بده يعني يتزوج بدون ما يتحمل أي يعني قد يكون
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+230
+00:21:35,610 --> 00:21:40,110
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+231
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+232
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+233
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+بالمبيت و القسم
+
+234
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+وكمان قد يكون السبب هو أن هذا الزواج أنه يندفع إلى
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+235
+00:22:04,300 --> 00:22:07,880
+هذا الزواج كما قلنا هي على فكرة أسباب متداخلة يعني
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+236
+00:22:07,880 --> 00:22:13,500
+يحافظ على شيء من الاستقرار في بيته يعني أما إذا
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+237
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+تزوج كما قلنا زواجكثاني وعادي قد يسبب اضطرابك فهو
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+238
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+239
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+240
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+يندفع إلى بهذا الزواج أخيرا الأسباب التي تتعلق
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+241
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+242
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+243
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+244
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+وكله بده تكاليف ونفقات وإلى غير ذلكفهذا الارتفاع
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+245
+00:22:58,970 --> 00:23:03,270
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+246
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+247
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+248
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+249
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+عمره ثلاثين وخمس وثلاثين ثاني وربما اربعين وهو مش
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+250
+00:23:26,610 --> 00:23:34,180
+متزوج لأن الزواجتكاليف باهظة و هو موظف حتة موظف
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+251
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+252
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+253
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+254
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+لغيراته فإذن فعندما يجد زواجا كهذا الزواجحقيقة
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+255
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+يعني بكيف على .. بفرصة بكيف
+
+256
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+على .. بفرصة بكيف
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+257
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+على .. بفرصة بكيف على .. بفرصة بكيف على .. بفرصة
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+258
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+بكيف على .. بفرصة بكيف على .. بفرصة بكيف على ..
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+259
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+بفرصة بكيف على .. بفرصة بكيف على .. بفرصة بكيف على
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+260
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+261
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+بكيف على بفرصة بكيف على بفرصة بكيف على بفرصة بكيف
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+262
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+263
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+264
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+265
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+أهله مثلاأه بترضى؟ حسب .. اه يعني يمكن احنا في
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+266
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+المدة الأخيرة هذه في السنتين ثلاث أيام الحصار صار
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+267
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+في .. أما فترة سابقة حقيقة كان خط أحمر لازم نكون
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+268
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+شيء مستقلي لكن يمكن في فترة السنوات الأخيرة مع ضغط
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+269
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+الواقع اللي احنا بنعيش فيه صار الأهل والبنات
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+270
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+271
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+بناء ولا إمكانية مال ولا إله إرادة نسأل اللهيعني
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+272
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+أن .. أن يفرج عن هذا الحال وسبب آخر ومهم أيضا
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+273
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+يتعلق بالمجتمع النظر العامة للمجتمع التي تنفر
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+274
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+وتزدري وتحتقر الذي يتزوج من زوجة ثانيةوهذا ناتج
+
+275
+00:25:34,010 --> 00:25:37,370
+أيضًا عن الإعلام
+
+276
+00:25:41,150 --> 00:25:46,790
+الإعلام الغربي والشرقي اللذي سار فيه والذي يسلط
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+277
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+على أبناء المسلمين يدفرهم كما قلت ويصوروا لهم أن
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+278
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+الزواج بالذات هو خيانة وهو جريمة وإلى غير ذلك لحيث
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+279
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+أصبح هناك ثقافة عند المجتمع في المجتمع أن اللي
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+280
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+بتزوج واحدة تانية عليه علامة استفهام يعني ارتكب
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+281
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+جريم يا أولادطب ليش ارتكب جريم؟ أليس هذا شرع الله؟
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+282
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+283
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+أو هيك قال أو هيك أفاد
+
+284
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+285
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+286
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+287
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+يا أخوات أنا أقول شيء حقيقة المرأة بطبيعتها أقول
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+288
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+289
+00:26:55,330 --> 00:27:00,310
+عادية وظروف طبيعية بعيدا عن ضغط الإعلام وضغط
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+290
+00:27:00,310 --> 00:27:07,270
+الواقع وظروف العادية لكن .. لكن في ظل يعني هذه
+
+291
+00:27:07,270 --> 00:27:12,470
+الثقافة المستوردة من هنا ومن هناك تتغير المفاهيم
+
+292
+00:27:12,470 --> 00:27:18,510
+في هذه الحالة تتغير المفاهيم وبتصير المرأة بين ..
+
+293
+00:27:18,510 --> 00:27:24,100
+يعني في حيرة من أمرهافي حيرة من أمرها حتى تخرج من
+
+294
+00:27:24,100 --> 00:27:29,480
+البيت تكال
+
+295
+00:27:29,480 --> 00:27:36,460
+لها التساؤلات وتشعر بالحرج من من حولها من النساء
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+296
+00:27:36,460 --> 00:27:40,220
+انت مالك انت ايش ناقصك ايش اللي عمله ايش المصيب
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+297
+00:27:40,220 --> 00:27:45,150
+اللي عملها جوزك إلى غير ذلكفترجع إذا كانت تقبلت في
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+298
+00:27:45,150 --> 00:27:50,850
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+299
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+
+300
+00:27:55,850 --> 00:28:02,670
+عن ضغط هذا الإعلان الغربي أو المعادي والمخالف يعني
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+301
+00:28:02,670 --> 00:28:07,630
+هذا أمر طبيعي أمر طبيعي طبيعي مش بالمرة يعني هو كل
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+302
+00:28:07,630 --> 00:28:14,290
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+303
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+304
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+تتقبل ذلك تتقبل ذلك خاصة إنه في بعض الدول من أراد
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+305
+00:28:26,050 --> 00:28:31,730
+أن يتزوج من زوجة جديدة الزوجة الأولى يقدم لها من
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+306
+00:28:31,730 --> 00:28:35,330
+يعني الأعطيات
+
+307
+00:28:36,360 --> 00:28:40,960
+والهدايا و المنح بتقولك يتجاوز بس هات مش مشكلة هات
+
+308
+00:28:40,960 --> 00:28:46,080
+غير للتقم الجديد و جيبلي ذهب و إلى غير ذلك في بعض
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+309
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+الدول زي هيك زائد ان بعض المجتمعات تحرصوا يعني على
+
+310
+00:28:52,500 --> 00:28:58,290
+قصرة الأولادوالعزوة يعني كما يقال ف .. و المرأة
+
+311
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+تحرصوا كذلك على أن يكون لزوجها يعني هذه ال .. هذه
+
+312
+00:29:04,450 --> 00:29:08,910
+الصفة .. هذه الصفة منها ولا من غيرها لأنه تتباهى
+
+313
+00:29:08,910 --> 00:29:15,100
+يعني أنا حدثتفي هذا الأمر يعني من أقارب ليه عايشون
+
+314
+00:29:15,100 --> 00:29:18,440
+في السعودية تعرفوا الفلسطينيين موجودين في كل مكان
+
+315
+00:29:18,440 --> 00:29:21,760
+و الفلسطينيين عادة مافيش واحد مافيش غيرها يعني
+
+316
+00:29:21,760 --> 00:29:26,800
+فولادهم .. ولادهم لما بروحوا على المدارس بصيروا
+
+317
+00:29:26,800 --> 00:29:30,860
+يتساءلوا أنت كام أخوا إليك؟ أنت كام أخ؟ أطل فلسطين
+
+318
+00:29:30,860 --> 00:29:34,320
+يقولوا أنا إلي أختين وأخوين مثلا يعني على أربعة
+
+319
+00:29:34,320 --> 00:29:38,900
+انفارة كالعادة أو خمس انفارةفهو يسأل أولاد
+
+320
+00:29:38,900 --> 00:29:42,080
+السعوديين مثلا أو أولاد يقولوا إيه ليه عشرين خمس
+
+321
+00:29:42,080 --> 00:29:47,820
+وعشرين تلاتين أخوا فهو يشعر حتى فهو يريد هو يطالب
+
+322
+00:29:47,820 --> 00:29:55,320
+أباهه بأن يتزوج حتى يباهي غيرهم فالأمر يعني أقصد
+
+323
+00:29:55,320 --> 00:30:02,540
+ثقافة المجتمع لها دخلكبير في رضا وتقبل واقتناع
+
+324
+00:30:02,540 --> 00:30:11,340
+المرأة واتباره أمر طبيعي في ذلك على كل الأحوال هذه
+
+325
+00:30:11,340 --> 00:30:18,020
+بعض الأسباب التي كانت ورا انتشار زواج المسيار
+
+326
+00:30:18,020 --> 00:30:24,740
+وظهوره لنعود الآن الى بيت القصيد وهو الحكم نعمهلا
+
+327
+00:30:24,740 --> 00:30:29,640
+بعدي تدري دكتور سوقان هل التعادل من أربع ثوجات هل
+
+328
+00:30:29,640 --> 00:30:36,040
+هو السنة؟ مين قالك سنة؟ مش مضرر هو على الإباحة على
+
+329
+00:30:36,040 --> 00:30:42,620
+الإباحة على الإباحة وقد يكونوا سنة يعني هو الزواج
+
+330
+00:30:42,620 --> 00:30:48,460
+ابتدائي له أحكام متعددة يختلف يعني قد يكون واجبا
+
+331
+00:30:48,460 --> 00:30:53,380
+وقد يكون مستحبا وقد يكون مكروها وقد يكون حرامافمن
+
+332
+00:30:53,380 --> 00:30:59,020
+باب أولى أيضا التعدد أن يصل أن تكون له هذه الأحكام
+
+333
+00:30:59,020 --> 00:31:03,820
+المختلفة في الأصل على الإباحة الزواج العادي أندى
+
+334
+00:31:03,820 --> 00:31:06,620
+البعض على الإباحة أندى الشفائية على الإباحة
+
+335
+00:31:09,930 --> 00:31:14,370
+لكن .. احنا .. في مشكلة انه هل التعدد أصل ولا مش
+
+336
+00:31:14,370 --> 00:31:19,730
+أصل ولا الأصل الواحدة ولا التعدد مش إشكال يعني من
+
+337
+00:31:19,730 --> 00:31:23,950
+غير النظر احنا كل .. يعني أحيانا فعلا يا أخوات
+
+338
+00:31:23,950 --> 00:31:29,330
+التعدد قد يكون حراما إذا كان هذا التعدد سيؤدي إلى
+
+339
+00:31:29,330 --> 00:31:33,390
+مفاسد ومصائب في البيت إذا كان هذا الذي يريد أن
+
+340
+00:31:33,390 --> 00:31:39,640
+يتزوجسيترتب على زواجه يعني .. يعني .. او هو لا
+
+341
+00:31:39,640 --> 00:31:44,700
+يستطيع ان يقوم بالحقوق التي امر الله بها او رتبها
+
+342
+00:31:44,700 --> 00:31:49,020
+على .. في إشكالات يعني حقيقة لكن .. و نحن نقول هذا
+
+343
+00:31:49,020 --> 00:31:56,920
+الكلام أيضا لابد أن نقولأن يعني التعدد إذا توفرت
+
+344
+00:31:56,920 --> 00:32:03,040
+يعني حروفه وإمكانياته ولم يترتب عليه أدرار يعني
+
+345
+00:32:03,040 --> 00:32:09,680
+مستفحلة يعني لا نستطيع أن نقول بمنعه أبدا خاصة
+
+346
+00:32:09,680 --> 00:32:13,960
+وأنه مقرر يعني في الشريعة في كتاب ربنا وفي سنة
+
+347
+00:32:13,960 --> 00:32:19,770
+النبي لكن أنا .. أنا كأبو بنتمثلا أبو لابنتي و أجى
+
+348
+00:32:19,770 --> 00:32:24,130
+جوزك قاللي يا عمي يا حماية بتتجوز على بنتك أنا
+
+349
+00:32:24,130 --> 00:32:33,530
+مابقبلش بقبلش لكن باعتبار مصلحة الخاصة لكن .. لكن
+
+350
+00:32:33,530 --> 00:32:37,970
+والله إذا ظروفه يعني هو في الآخر هذا حق و أنا
+
+351
+00:32:37,970 --> 00:32:43,890
+مابقبلش لكن مابقدرش أفرضأفرد عليه هو يقدر إذا كان
+
+352
+00:32:43,890 --> 00:32:50,450
+لديه يعني عنده التزام بالحكم الشرعي وبالدين وكذا
+
+353
+00:32:50,450 --> 00:32:57,670
+هو يعرف هو الآن يعني ظرفه يعني وظروفه تقتضي أن
+
+354
+00:32:57,670 --> 00:33:03,190
+يتزوج إن لم يتزوج سيقع فيه مفسدة أكبر وهكذا يعني
+
+355
+00:33:03,190 --> 00:33:08,470
+هو يقدر في ذلك وليس ليه بعد ذلك أنان امنعه فعليا
+
+356
+00:33:08,470 --> 00:33:13,350
+انا باعترض لكن مقدرش امنع في فرق بين ان اعترض
+
+357
+00:33:13,350 --> 00:33:17,250
+الرسول صلى الله عليه و سلم اعترض على عليه من زواجه
+
+358
+00:33:17,250 --> 00:33:23,070
+من رغبته في الزواج على فاطمة رضي الله عنها كاب و
+
+359
+00:33:23,070 --> 00:33:28,730
+ليس كمشرع لكن التشريع غير ففي
+
+360
+00:33:28,730 --> 00:33:34,930
+فرق بين هذه الصورة و تلك الآن نعود إلى حكم الزواج
+
+361
+00:33:35,840 --> 00:33:42,320
+زواج المسيار لكن السؤال يا أخوات قبل أن نبيّن
+
+362
+00:33:42,320 --> 00:33:48,900
+الحكم إذا كان هذا الزواج كما وصفناه وعرفناه بأنه
+
+363
+00:33:48,900 --> 00:33:56,560
+زواج مستقل للأركان والشروق فلم يكون فيه الخلاف
+
+364
+00:33:56,560 --> 00:34:04,810
+أليستالأركان والشروط ووجودها هي معيار الصحة وعدمه
+
+365
+00:34:04,810 --> 00:34:09,050
+فكل ما اكتمل أي عقد من العقود حتى عقد الزواج أو أي
+
+366
+00:34:09,050 --> 00:34:13,430
+عقد من العقود كل ما استكمل أليس معيار الصحة النظرة
+
+367
+00:34:13,430 --> 00:34:17,530
+في العقد فيما أركانه وشروته فإذا استكمل العقد و
+
+368
+00:34:17,530 --> 00:34:22,890
+أركانه وشروته صحناه فإذا تخلف أحد الأركان أو بعض
+
+369
+00:34:22,890 --> 00:34:29,680
+الشروط اللي لم نصحه أو أفسدناه أو بطلناهإذا لماذا
+
+370
+00:34:29,680 --> 00:34:36,320
+.. لماذا ال .. لكن الذين راهوا وقد وجدتم أن ثم
+
+371
+00:34:36,320 --> 00:34:41,180
+تخلاف اللي نجده .. اللي وجدناه على الأرض وفي
+
+372
+00:34:41,180 --> 00:34:46,860
+الواقع أن ثم تخلاف بين العلماء في زواج المسيار بين
+
+373
+00:34:46,860 --> 00:34:51,700
+قائل بالإباحة مع الكراه طبعا و بين قائل بالتحريم
+
+374
+00:34:51,700 --> 00:34:57,280
+أو المنع و بين متوقفوبينها متوقف فما هو السر في
+
+375
+00:34:57,280 --> 00:35:04,560
+ذلك يا ترى ربما ترتب المفاسد بعد عقد زواج المفسيرة
+
+376
+00:35:04,560 --> 00:35:09,460
+فربما المفاسد الذات ستترتب على هذا العقد بعد حدوثي
+
+377
+00:35:09,460 --> 00:35:14,040
+واستكمالي أدكاني وشروطي كبيرة و القواعد الشرعية
+
+378
+00:35:14,040 --> 00:35:19,390
+قائمة على ذات المفاسدهذا جميل هذا جميل هذا جميل
+
+379
+00:35:19,390 --> 00:35:24,390
+لكن لعله ليس السبب الرئيسي في الخلاف على أعتبار أن
+
+380
+00:35:24,390 --> 00:35:28,350
+حتى الزواج العادي ممكن تترتب عليه مشاكل كما
+
+381
+00:35:28,350 --> 00:35:32,130
+المشاكل التي تحدث في .. قد يتزوج الإنسان زواجا
+
+382
+00:35:32,130 --> 00:35:38,650
+عاديا ويتخلى عن مسئولياته في النفقة في الأولاد
+
+383
+00:35:38,650 --> 00:35:42,570
+ويحدث كما يحدث في زواج المسيان لكن لعله هناك سبب
+
+384
+00:35:42,570 --> 00:35:48,650
+آخر او سبب .. نعم أصل في النفقة هي تكون الزواجعلى
+
+385
+00:35:48,650 --> 00:35:51,590
+الزوج قصدي .. على الزوج .. نعم .. انا نفق على
+
+386
+00:35:51,590 --> 00:35:54,990
+زوجتك أما في زوجة بالسيارة لو انتقلت للزوج على
+
+387
+00:35:54,990 --> 00:35:58,590
+زوجتك اللي نفقها تبقى ممكن هذا محل الفرق هو نفس
+
+388
+00:35:58,590 --> 00:36:01,750
+الكلام اللي حكته يالا يختلف يعني و الرد عليه هو هو
+
+389
+00:36:01,750 --> 00:36:07,430
+هل من شيء آخر يعني أنا في ظن يا أخوات أن المسألة
+
+390
+00:36:07,430 --> 00:36:14,240
+أبعد من ذلكيعني هذه التي تقولونها من الأدلة التي
+
+391
+00:36:14,240 --> 00:36:20,120
+استدل بها هؤلاء أو أولئك الإضافية لكن سبب الخلاف
+
+392
+00:36:20,120 --> 00:36:24,500
+الرئيسي والذي ربما لم يذكر هنا أو ذكر في ثنايا
+
+393
+00:36:24,500 --> 00:36:32,560
+الكلام هو أن العلماء اختلفوا ابتداء في أن هل الشرط
+
+394
+00:36:33,170 --> 00:36:38,690
+المخالف لمقتضل العقد الفاسد يعني هل يبطل العقد او
+
+395
+00:36:38,690 --> 00:36:48,980
+لا هذا عقد هذا عقد اقترنه بشروط هي مخالفةلما ينبغي
+
+396
+00:36:48,980 --> 00:36:54,900
+أن يترتب عليه العقد عقد الزواج إذا عقد تترتب عليه
+
+397
+00:36:54,900 --> 00:36:59,200
+بدون ما نذكر أي شروط أخرى في عقد الزواج في سكن
+
+398
+00:36:59,200 --> 00:37:03,060
+التزام بالسكن في عقد الزواج في نفقة في عقد الزواج
+
+399
+00:37:03,060 --> 00:37:07,000
+في قسم في المبيت إن كنت متزوجا أو إن لم تكنت
+
+400
+00:37:07,000 --> 00:37:10,200
+متزوجا إن لم تكنت متزوجا في التزام بالمبيت الدائم
+
+401
+00:37:10,200 --> 00:37:20,220
+إلا لعذر إتقائهاتمام فالان انت عقدت عقد وقرنته
+
+402
+00:37:20,220 --> 00:37:27,320
+بشرط مخالف مناقض لمقصد للمقاصد للنتائج للأثار
+
+403
+00:37:27,320 --> 00:37:30,840
+المترتبة عليه اي ان كان هذا العقد عقد الزواج عقد
+
+404
+00:37:30,840 --> 00:37:38,720
+بالبيع الان يا أخوان لو ان رجلا باع شيئا لآخر وشرط
+
+405
+00:37:38,720 --> 00:37:44,740
+عليه عدم التملكالأركان موجودة والشروط قد تكون
+
+406
+00:37:44,740 --> 00:37:50,480
+موجودة كلها لكن شرط مخالف من مقتضيات العقد البيع
+
+407
+00:37:50,480 --> 00:37:56,820
+التملك وانت تشترط عدم التملك أيوة من هنا اذا هل
+
+408
+00:37:56,820 --> 00:38:02,120
+يعني بيصير هذا ارأي العلماء هل نصحح العقد ده
+
+409
+00:38:02,120 --> 00:38:10,760
+ونبطله الشرطة؟أم نفسد العقدة والشرطة أم نتوقف هنا
+
+410
+00:38:10,760 --> 00:38:15,820
+هذا هو أساس الخلاف فأساس الخلاف ليس في عقد زواج
+
+411
+00:38:15,820 --> 00:38:20,600
+المسياري فقط وإنما الخلاف في زواج المسياري هو صورة
+
+412
+00:38:20,600 --> 00:38:27,020
+من صور الخلاف في العقود جملة التي تقترن بشروط
+
+413
+00:38:27,020 --> 00:38:30,840
+فاسدة وهو ما نتحدث عنه المرة القادمة إن شاء الله
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/IMUlM4WsPVU_raw.json b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/IMUlM4WsPVU_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..09f04fb3a75552f4db8fe9d012dd05d7ed529651
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/IMUlM4WsPVU_raw.json
@@ -0,0 +1 @@
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0.9658203125}, {"start": 2776.21, "end": 2776.53, "word": " هذه", "probability": 0.9580078125}, {"start": 2776.53, "end": 2777.29, "word": " البطاقات", "probability": 0.98408203125}, {"start": 2777.29, "end": 2777.67, "word": " أو", "probability": 0.83154296875}, {"start": 2777.67, "end": 2778.31, "word": " أعدّله", "probability": 0.55023193359375}, {"start": 2778.31, "end": 2779.15, "word": " فهناك", "probability": 0.874755859375}, {"start": 2779.15, "end": 2780.39, "word": " طرق", "probability": 0.9480794270833334}, {"start": 2780.39, "end": 2781.65, "word": " بديلة", "probability": 0.5926920572916666}, {"start": 2781.65, "end": 2782.65, "word": " للتعامل", "probability": 0.98955078125}, {"start": 2782.65, "end": 2784.09, "word": " سنتحدث", "probability": 0.955078125}, {"start": 2784.09, "end": 2784.23, "word": " في", "probability": 0.931640625}, {"start": 2784.23, "end": 2784.59, "word": " ذلك", "probability": 0.996826171875}, {"start": 2784.59, "end": 2785.15, "word": " كله", 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\ No newline at end of file
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/Md_iemaX9sk_raw.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/Md_iemaX9sk_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..300f08f615afa0e39f5c18880afa90b64816569e
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/Md_iemaX9sk_raw.srt
@@ -0,0 +1,1512 @@
+1
+00:00:20,640 --> 00:00:25,420
+والصلاة والسلام على رسول الله وعلى آله وصحبه وسلم
+
+2
+00:00:25,420 --> 00:00:26,480
+تسليما كثيرا
+
+3
+00:00:28,870 --> 00:00:35,010
+بداية كل عام و أنتم بخير قبل العيد وأسأل الله
+
+4
+00:00:35,010 --> 00:00:42,430
+سبحانه وتعالى أن يتقبل منا و منكم صالح العامة و
+
+5
+00:00:42,430 --> 00:00:48,410
+بعد .. قبل العيد كنا نتحدث أو بدأنا نتحدث في مسألة
+
+6
+00:00:48,410 --> 00:00:57,970
+مصر في سبيل الله و آراء العلماء في النطاق
+
+7
+00:00:58,860 --> 00:01:06,340
+أو في الحدود التي يُصرف فيها هذا المصرف وقلنا بأن
+
+8
+00:01:06,340 --> 00:01:15,080
+العلماء مختلفون أو اختلفوا في المراد بقوله تعالى
+
+9
+00:01:15,080 --> 00:01:22,680
+وفي سبيل الله كمصرف من مصارف الذكاء على ثلاثة آراء
+
+10
+00:01:25,150 --> 00:01:31,750
+رأي يمثله جماهير العلماء قديما وحديثا يقضي بأن
+
+11
+00:01:31,750 --> 00:01:35,990
+المقصودة بقوله تعالى وفي سبيل الله كمصرف من مصارف
+
+12
+00:01:35,990 --> 00:01:41,730
+الذكاء هو الجهاد والغزو والغزاة ولا يتسأل غيرهم
+
+13
+00:01:41,730 --> 00:01:49,510
+وقول آخريعني يشابه هذا القول لكنه يزيد عليه ويوسع
+
+14
+00:01:49,510 --> 00:01:55,510
+نطاقه ليشمل وليضيف اليه الحجاج والعمار أو الحج
+
+15
+00:01:55,510 --> 00:02:02,170
+والعمرة فيمكن ان ينفق على الحجاج والعمار من هذا
+
+16
+00:02:02,170 --> 00:02:11,840
+المصرف وقول ثالث من العمومي او يقول بالعمومبحيث
+
+17
+00:02:11,840 --> 00:02:18,300
+يتسع هذا المصرف مصرف في سبيل الله ليشمل كل وجوه
+
+18
+00:02:18,300 --> 00:02:25,420
+الخير والبر ومنها وعلى رأسها الجهاد ومن خلال
+
+19
+00:02:25,420 --> 00:02:29,960
+استعراض هذه الأراء الثلاثة نستطيع أن نخرج بنقاط
+
+20
+00:02:29,960 --> 00:02:38,120
+منها أنهم على اختلافهم متفقون على أن الجهاد يعني
+
+21
+00:02:38,120 --> 00:02:47,010
+ينفق عليهمن مصرف في سبيل الله ولكنهم
+
+22
+00:02:47,010 --> 00:02:53,170
+مختلفون في أنه هل يقتصر على هذا المعنى فقط على هذا
+
+23
+00:02:53,170 --> 00:02:59,730
+المجال فقط أم أنه يتسع له و لغيره فالجمهور قالوا
+
+24
+00:02:59,730 --> 00:03:06,110
+يقتصر عليه فقطو آخرون قالوا يتسأله و للحجاج
+
+25
+00:03:06,110 --> 00:03:11,530
+والعمار و ثالثون قالوا بأنه يعوم كل وجوه الخيل
+
+26
+00:03:11,530 --> 00:03:17,610
+تحدثنا عن أسباب الخلاف في هذه المسألة وقلنا بأن
+
+27
+00:03:17,610 --> 00:03:25,610
+هناك سببان رئيسا للخلاف في هذه المسألة يتمثلان في
+
+28
+00:03:25,610 --> 00:03:34,100
+تفسير معنى في سبيل اللهوالأحاديث الواردة سبب ثاني
+
+29
+00:03:34,100 --> 00:03:41,460
+مدى صحة الأحاديث والاستدلال وصحة الاستدلال بها على
+
+30
+00:03:41,460 --> 00:03:49,040
+المراد ثم بعد ذلك بدأنا نتحدث عن أدلة كل فريق كل
+
+31
+00:03:49,040 --> 00:03:56,790
+فريق استدل على رأيه وعلى قوله بأدلة متعددةالفريق
+
+32
+00:03:56,790 --> 00:04:03,150
+الأول اللي هم الجمهور اللي قلنا على رأسهم أئمة
+
+33
+00:04:03,150 --> 00:04:08,570
+المذاهب الأربعة الجمهور قديما وحديثا يقولون بأن
+
+34
+00:04:08,570 --> 00:04:14,730
+مصر في سبيل الله يقتصره على الجهاد والمجاهدين وعلى
+
+35
+00:04:14,730 --> 00:04:20,710
+رأس من قال بهذا الرأي أئمة المذاهب الأربعة وكثير
+
+36
+00:04:20,710 --> 00:04:28,220
+من أتباعهمهؤلاء كما قلت استدلوا بمجموعة من الأدلة
+
+37
+00:04:28,220 --> 00:04:32,060
+ذكرناها في مرات سابقة أن هذا المعنى هو المعنى الذي
+
+38
+00:04:32,060 --> 00:04:36,660
+اشتهر فيه القرآن الكريم واشتهرت به السنة بحيث إذا
+
+39
+00:04:36,660 --> 00:04:41,200
+وردت كلمة في سبيل الله قصد بها في العام الأغلب
+
+40
+00:04:41,200 --> 00:04:48,940
+الجهاد والمجاهدين وعلى ذلك إذا وردتمجرد عن القرائن
+
+41
+00:04:48,940 --> 00:04:54,660
+فإن هو تحمل على ما اشتهر معناه به في القرآن الكريم
+
+42
+00:04:54,660 --> 00:04:59,420
+وقد اشتهر معناه أي في سبيل الله بالجهاد و القتال
+
+43
+00:04:59,420 --> 00:05:06,550
+في سبيل اللهحديث .. حديث النبي صلى الله عليه وسلم
+
+44
+00:05:06,550 --> 00:05:12,350
+لا تحل الصدق لغني إلا لخمسة وأولهم الغازي وأن
+
+45
+00:05:12,350 --> 00:05:17,510
+تفسيرة في سبيل الله يعني هو الغازي والغزاة حملوها
+
+46
+00:05:17,510 --> 00:05:24,410
+على هذا المعنى لأن يا أخوات هناك اتفاق بأن مصارف
+
+47
+00:05:24,410 --> 00:05:28,270
+الذكاء لا تزيد عن هذه الثمانية وبالتالي فإن هذا
+
+48
+00:05:28,270 --> 00:05:33,970
+الحديث الذي يبينهلمن تصرف الذكاء أو بعض وجوه صرف
+
+49
+00:05:33,970 --> 00:05:42,070
+الذكاء لابد أن تندرج ضمن واحد من هذه الثمانية ولو
+
+50
+00:05:42,070 --> 00:05:46,310
+أردنا أن نتتبع أين يمكن أن يدرج الغازي سنجد أن
+
+51
+00:05:46,310 --> 00:05:50,170
+أقرب مصرف هو في سبيل الله وبالتالي فهذا هو ما
+
+52
+00:05:50,170 --> 00:05:56,570
+يعنيه وطبعا احنا بياننا المصارف الأخرى بعضها يدرج
+
+53
+00:05:56,570 --> 00:06:06,770
+وبعضها ذكر لبيانأنه يعني مثلة مثلا انه شراء الصدقة
+
+54
+00:06:06,770 --> 00:06:14,550
+من قبل الأغنياء ذكر لدفع شبهةأو الإهداء فإنه يجوز
+
+55
+00:06:14,550 --> 00:06:20,190
+أن يهدي الفقير ما تصدق به عليه من الصداقات لمن شاء
+
+56
+00:06:20,190 --> 00:06:26,710
+ويجوز له أن يبيع لمن شاء فذُكرت ضمن يعني الخامسة
+
+57
+00:06:26,710 --> 00:06:33,870
+لدفع شبهة احتمال عدم جواز بيع الصداقات لمن يملكها
+
+58
+00:06:33,870 --> 00:06:38,550
+أو عدم جواز إهدائها فبيّرت الجواز في هذا الحديث
+
+59
+00:06:40,300 --> 00:06:50,180
+واشتدلوا كذلك بالحديث حديث كعب بن عجرة الذي ورد
+
+60
+00:06:50,180 --> 00:06:56,500
+حيث رأى الصحابة ومعهم النبي صلى الله عليه وسلم رجل
+
+61
+00:06:56,500 --> 00:07:04,910
+رجلا جلدا فقالوا لو كان هذا في سبيل اللهوموضع
+
+62
+00:07:04,910 --> 00:07:08,950
+الاستدلال أن صحابة رسول الله صلى الله عليه وسلم
+
+63
+00:07:08,950 --> 00:07:14,270
+كانوا إذا أطلقت على ألسنتهم كلمة في سبيل الله
+
+64
+00:07:14,270 --> 00:07:21,320
+قصدوا بها الجهادفهم عندما قالوا لو كان هذا في سبيل
+
+65
+00:07:21,320 --> 00:07:27,020
+الله أو أي لو كان هذا مجاهدا أو لو كان هذا النشاط
+
+66
+00:07:27,020 --> 00:07:34,020
+و هذه القوة و هذا الجلد في سبيل الله و في الجهاد و
+
+67
+00:07:34,020 --> 00:07:38,620
+في ألاء كلمات الله سبحانه و تعالى و استدلوا كذلك
+
+68
+00:07:38,620 --> 00:07:45,410
+بأثار وردت عن بعض التابعينالذين أوردهم بعض
+
+69
+00:07:45,410 --> 00:07:50,670
+المفسرين في كتبهم كالطبري والسيوطي عن زيد بن أسلم
+
+70
+00:07:50,670 --> 00:07:57,210
+ومقاتل فسروها بأنها بمعنى الجهاد أو بمعنى الغزاة
+
+71
+00:07:58,400 --> 00:08:01,980
+أما القائلون هذه أدلة أصحاب القول الأول تقريبا أما
+
+72
+00:08:01,980 --> 00:08:06,600
+أدلة أصحاب القول الثاني فأدلة أصحاب القول الأول هي
+
+73
+00:08:06,600 --> 00:08:10,580
+هي يستدلوا بيها القائلون لأنهم لا يخلفون في الجهاد
+
+74
+00:08:10,580 --> 00:08:14,480
+الأصحاب القول الثاني أما بالنسبة لإدراجهم الجهاد
+
+75
+00:08:14,480 --> 00:08:19,040
+في فذا المصر فاستدلوا بمجموعة من الأدلة أعتقد
+
+76
+00:08:19,040 --> 00:08:24,080
+ذكرناها أيضا المرة الماضية حديث أم معقل اللي لا
+
+77
+00:08:24,080 --> 00:08:31,130
+كان لنا جمال وثم مات أو قبل أن يموت زوجها أبو معقل
+
+78
+00:08:31,130 --> 00:08:36,710
+احتبسه في سبيل الله أو أوقفه في سبيل الله ثم مات
+
+79
+00:08:36,710 --> 00:08:41,490
+ثم حج النبي صلى الله عليه وسلم فلم تجد يعني أم
+
+80
+00:08:41,490 --> 00:08:48,390
+معقل ما تحمله ما تحمله
+
+81
+00:08:48,390 --> 00:08:52,470
+نفسها عليه على أعتبار أن هذا الجمل موقوف في سبيل
+
+82
+00:08:52,470 --> 00:08:59,900
+الله فظنت أنهلا يجوز لها أن تسير عليه أو تستخدمه
+
+83
+00:08:59,900 --> 00:09:05,080
+في الحج فلمّا عاد النبي صلى الله عليه وسلم وافتقد
+
+84
+00:09:05,080 --> 00:09:09,540
+أمة معقل وهو يعلم أن لها أن عندها جمل يمكن أن تحج
+
+85
+00:09:09,540 --> 00:09:16,240
+عليه فسأل عن ذلك فقالت له القصة فقال فهل لا حججتي
+
+86
+00:09:16,240 --> 00:09:23,040
+عليه فإن الحج في سبيل اللهفهذا يعني شاهد على أن
+
+87
+00:09:23,040 --> 00:09:30,180
+الحج في سبيل الله وحديث مثل هذا الحديث أيضا يدعمه
+
+88
+00:09:30,180 --> 00:09:35,460
+لكنها قصة أخرى امرأة طلبت من زوجها احججني فقال لقد
+
+89
+00:09:35,460 --> 00:09:41,420
+حبست على هذا الجمل الذي تقصدين الحج عليه فلما يعني
+
+90
+00:09:41,420 --> 00:09:46,470
+سؤل النبي صلى الله عليه وسلم في ذلكقال له أما أنك
+
+91
+00:09:46,470 --> 00:09:51,130
+لو أحججتها عليه لكان في سبيل الله حتى وإن أوقفه
+
+92
+00:09:51,130 --> 00:09:57,410
+حتى وإن كان في سبيل الله ومتخذ للجهاد والمجاهدين
+
+93
+00:09:57,410 --> 00:10:05,090
+فإنه يجوزهأن يحمل الحجاج عليه واستدلوا كذلك
+
+94
+00:10:05,090 --> 00:10:11,890
+بالحديث الذي بين لنا فيه الرواه أن رسول الله صلى
+
+95
+00:10:11,890 --> 00:10:16,950
+الله عليه وسلم كان يحمل يعني ما لا يجد ما يحمل
+
+96
+00:10:16,950 --> 00:10:21,940
+عليه من الحجاج على إبل الصدقةعلى إذن الصدقة وهذا
+
+97
+00:10:21,940 --> 00:10:27,220
+دليل أيضا واضح على أن في
+
+98
+00:10:27,220 --> 00:10:32,500
+سبيل الله تتسع للحجاجي أو للانفاق على الحجاج
+
+99
+00:10:32,500 --> 00:10:40,040
+والعمروحديث آخر استدلوا به حديث في البخاري يعني
+
+100
+00:10:40,040 --> 00:10:48,440
+بيّن أن من معاني مصرف في سبيل الله أن يُعطى أو أن
+
+101
+00:10:48,440 --> 00:10:53,260
+يُعطى لمن لم يحج إضافة إلى المجاهدين وإضافة إلى من
+
+102
+00:10:53,260 --> 00:11:00,780
+اشترى أباه يريد أن يُعتيقه بعد أن كان عبدًاهذه
+
+103
+00:11:00,780 --> 00:11:05,980
+أدلة القول الثاني أما أدلة القول الثالث وهو الرأي
+
+104
+00:11:05,980 --> 00:11:13,000
+الأبرز في طبيعة الخلاف يعني بين الأراء الثلاثة وهو
+
+105
+00:11:13,000 --> 00:11:19,190
+الرأي الذي يقول بالعموموالقاسم المشترك بينه وبين
+
+106
+00:11:19,190 --> 00:11:27,730
+الأراء السابقة هو الجهاد في سبيل الله لكنه لا يقصر
+
+107
+00:11:27,730 --> 00:11:35,970
+الكلام عليه بل يوسع دائرة هذا المصرف ومعناه ليشمل
+
+108
+00:11:35,970 --> 00:11:42,590
+كل معاني الخيروكل وجوه البر ودون أن يقتصر على
+
+109
+00:11:42,590 --> 00:11:48,010
+الجهاد وإن كان الجهاد على رأس هذه المعاني ما أدلتك
+
+110
+00:11:48,010 --> 00:11:52,550
+يا أدلتكم يا أصحاب هذا الرأي قالوا أولا المعنى
+
+111
+00:11:52,550 --> 00:11:58,330
+اللغوي المعنى اللغوي الذي هو الأصل في تفسير ألفاظ
+
+112
+00:11:58,330 --> 00:12:01,930
+القرآن الكريم هذا القرآن الذي نزل باللغة العرب
+
+113
+00:12:02,700 --> 00:12:07,700
+فالأصل أن نحمله على معناه اللغوي وكلمة في سبيل
+
+114
+00:12:07,700 --> 00:12:15,540
+الله معناها بالعرب البسيط الفصيح كل طريق يبتغى بيه
+
+115
+00:12:15,540 --> 00:12:21,100
+وجه الله السبيل هو الطريق وسبيل الله الطريق الذي
+
+116
+00:12:21,100 --> 00:12:26,670
+يبتغى بيه وجه الله وهذا يشمل كل معاني الخيرطب يا
+
+117
+00:12:26,670 --> 00:12:31,030
+عمي طب ألا يمكن أن يكون قد خُصص؟ يمكن يا سيدي أن
+
+118
+00:12:31,030 --> 00:12:37,130
+يكون قد خُصص لكن لا مخصص ولا مخصص مش هم بيقولوا لا
+
+119
+00:12:37,130 --> 00:12:41,850
+يجيز التخصيص لا أحد ينكر إمكانية التخصيص للعام لكن
+
+120
+00:12:41,850 --> 00:12:47,510
+عندما يأتي دليل التخصيص هم يقولون أنه لا دليل
+
+121
+00:12:47,510 --> 00:12:52,030
+للتخصيص وكما سنرى عند المناقشات أن ما استدل به
+
+122
+00:12:52,030 --> 00:12:57,740
+الأولون الذي يعتبر مقابل التخصيص لميعني يرقى عندهم
+
+123
+00:12:57,740 --> 00:13:03,720
+إلى القوة التي يمكن أن يخصص بها هذا الدليل العام
+
+124
+00:13:03,720 --> 00:13:11,970
+هذا دليلأو هذه .. هذا مصرف عام أو مصرف بمعنى اللغة
+
+125
+00:13:11,970 --> 00:13:17,490
+عم بمعنى اللغوي عم وفي سبيل الله أنا إذا بدأ أخصصه
+
+126
+00:13:17,490 --> 00:13:24,450
+لابد من دليل واضح قاطع في تخصيصه بدون ذلك لأقبل
+
+127
+00:13:24,450 --> 00:13:33,310
+التخصيص ويبقى اللفظ في معناه على عمومههذا أول
+
+128
+00:13:33,310 --> 00:13:39,110
+واستدلوا بدليل آخر قالوا باختصار أن رسول الله صلى
+
+129
+00:13:39,110 --> 00:13:47,450
+الله عليه وسلم ودا يعني دفع الدية ودا ذلك الرجل
+
+130
+00:13:47,450 --> 00:13:53,900
+الذي قتل ولم يعرف قاتلهولم يعرف قاتله في هذا الرجل
+
+131
+00:13:53,900 --> 00:13:59,840
+الأنصاري الذي قتل في حي من أحياء اليهود في حي من
+
+132
+00:13:59,840 --> 00:14:06,100
+أحياء اليهود والأصل في أن الرجل الذي يقتل أو الشخص
+
+133
+00:14:06,100 --> 00:14:09,840
+رجل أو امرأالذي يقتل ولا يعرف قاتله في حي من
+
+134
+00:14:09,840 --> 00:14:15,200
+الأحياء أنه تطبق عليهم ما يعرف بالقسامة هذه
+
+135
+00:14:15,200 --> 00:14:21,900
+القسامة يستدعى خمسين رجل من كبار الحي الذي قتل فيه
+
+136
+00:14:21,900 --> 00:14:27,700
+فيقسمون بالله أنهم لم يقتلوا ولم يعلموا قاتله فإذا
+
+137
+00:14:27,700 --> 00:14:35,510
+أقسموا دفعت عنهم التهمةدفعت عنهم التهمة وبرقوا من
+
+138
+00:14:35,510 --> 00:14:40,810
+دمه وإلا تحملوا دمه .. وإلا تحملوا دمه .. طيب
+
+139
+00:14:40,810 --> 00:14:46,250
+اليهودلكن هذا قتل في حقيقية من أحيان اليهود يعني
+
+140
+00:14:46,250 --> 00:14:52,210
+اليهود اللي قتلوا بدهم يعني يتحروا ولا يعني في
+
+141
+00:14:52,210 --> 00:14:58,110
+مسألة اليمين قال الحرام يحلف قال أجان الفرج كيف
+
+142
+00:14:58,110 --> 00:15:02,330
+اليهودي مستعد يحلف فلذلك لم يقبل الصحابة ولا النبي
+
+143
+00:15:02,330 --> 00:15:06,710
+صلى الله عليه وسلم حتى أن يعرضوا القسامة على هؤلاء
+
+144
+00:15:06,710 --> 00:15:11,880
+اليهود لأنهم يدركون أنهم سيحلفون كذبافلذلك الرسول
+
+145
+00:15:11,880 --> 00:15:15,560
+صلى الله عليه وسلم كي لا يضيع دم هذا القتيل هدرا
+
+146
+00:15:15,560 --> 00:15:21,920
+وداه طيب ماذا يعني أنه وداه الشاهد أنه وداه من إبل
+
+147
+00:15:21,920 --> 00:15:27,620
+الصدقةالشاهد أو الوجه الاستدلال أن الديّة التي
+
+148
+00:15:27,620 --> 00:15:32,680
+دفعها لأهل هذه القتيل هي من قبل الصدق في دليل واضح
+
+149
+00:15:32,680 --> 00:15:38,120
+على أن الصدقاء الصدقات الذكوات تدفعوا يعني في غير
+
+150
+00:15:38,120 --> 00:15:42,580
+باب الجهاد في غير باب الجهاد أي في وجوه الخير وهذا
+
+151
+00:15:42,580 --> 00:15:47,760
+وجه بالمناسبة من وجه الخير أن يساهم في دفع الديّة
+
+152
+00:15:47,760 --> 00:15:52,550
+هذا وجه من وجه الخيروانشه من وجهه الخير ويجوزه حتى
+
+153
+00:15:52,550 --> 00:15:56,970
+لل .. لل .. لل .. للقاتل المعفو عنها أو القاتل
+
+154
+00:15:56,970 --> 00:16:01,850
+الخطأ الذي يريد أن يدفع الدية لأهل القتيل يجوز له
+
+155
+00:16:01,850 --> 00:16:05,970
+أن يأخذ من الناس يعني صدقات و ذكوات هذا وانشه من
+
+156
+00:16:05,970 --> 00:16:12,890
+وجهه الخير فلذلكف .. ف .. ف .. ف .. فلمّا ودا أو ف
+
+157
+00:16:12,890 --> 00:16:18,010
+.. دفع رسول الله صلى الله عليه وسلم الدية له أو ل
+
+158
+00:16:18,010 --> 00:16:21,430
+.. ل .. لأهل هذا القتيل من مال الصدقة دليل على
+
+159
+00:16:21,430 --> 00:16:27,370
+أنها تنفق في وجوه الخير طبعا واضح أن دفع الصدقة له
+
+160
+00:16:27,370 --> 00:16:31,490
+في هذا الباب من باب مصرف في سبيل الله لأنه لم
+
+161
+00:16:31,490 --> 00:16:36,210
+يدفعه من باب يعني الفقر ولا من باب الغرم ولا من
+
+162
+00:16:36,210 --> 00:16:41,340
+باب التأليف ولا من باب الرقاب ولا من بابوإنما من
+
+163
+00:16:41,340 --> 00:16:50,360
+باب في سبيل الله ثالثا يعني ولعله من أقوى الأدلة
+
+164
+00:16:50,360 --> 00:16:56,300
+أن .. أن .. أن الخلفاء وحتى في عهد النبي صلى الله
+
+165
+00:16:56,300 --> 00:17:00,040
+عليه وسلم كانوا يدفعون .. كان النبي صلى الله عليه
+
+166
+00:17:00,040 --> 00:17:03,920
+وسلم وكان الخلفاء من بعده يدفعون للصحابة ما يُعرف
+
+167
+00:17:03,920 --> 00:17:10,990
+بالأعطيات، عطايادنانير و .. و .. و دراهم مصاري
+
+168
+00:17:10,990 --> 00:17:17,290
+يدفع لهم يعني ل .. ل .. ل .. ل .. لأنهم يعني
+
+169
+00:17:17,290 --> 00:17:22,750
+لسبقهم في الإسلام لعلم .. لأنهم يعلمون الناس لأنهم
+
+170
+00:17:22,750 --> 00:17:26,650
+.. المهم أنهم كان .. رغم أنهم و ليس بالضرورة دون
+
+171
+00:17:26,650 --> 00:17:29,970
+أن يكونوا بالضرورة فقراء يعني قد يقول يعطوا
+
+172
+00:17:29,970 --> 00:17:35,250
+الفقراء من الصحابة لأ مش بالضرورةو أحيانا يُعطى
+
+173
+00:17:35,250 --> 00:17:39,650
+الفقير أكتر من حاجته دليل على أن المسألة مش للحاجة
+
+174
+00:17:39,650 --> 00:17:45,010
+مش للحاجة بل يُعطى الصحابة الصحابة يا أخوات يعني
+
+175
+00:17:45,010 --> 00:17:51,410
+من دول هيئات الذين تدقوا أبوابهم أو يدقوا أبوابهم
+
+176
+00:17:51,410 --> 00:17:59,590
+أصحاب الحاجات فلذلك كان الخلفاء يعني يُعطونا
+
+177
+00:17:59,590 --> 00:18:07,940
+خبار الصحابةأعطيات ليست قصرة على حاجاتهم بل تزيد
+
+178
+00:18:07,940 --> 00:18:11,260
+وتبلغ آلاف مؤلفة لكن هذه الآلاف التي كانوا
+
+179
+00:18:11,260 --> 00:18:16,660
+يأخذونها لا يأخذونها لأنفسهم وإنما يعني يُعطوا
+
+180
+00:18:16,660 --> 00:18:20,440
+بيها الفقراء والمساكين الذين يدقون أبوابهم أو
+
+181
+00:18:20,440 --> 00:18:24,140
+يسألونهم الحاجات لكن احنا ما بهمنا بعد هيك أو قبل
+
+182
+00:18:24,140 --> 00:18:28,990
+أنه لمن تُعطىأو لمن يعطيها هؤلاء الصحابة المهم أن
+
+183
+00:18:28,990 --> 00:18:37,670
+الصحابة كانوا يعطون أو يأخذون من أموال الصدقات
+
+184
+00:18:37,670 --> 00:18:47,090
+سواء لقضاء حاجاتهم أو لقضاء حاجات الناس التي تدق
+
+185
+00:18:47,090 --> 00:18:54,080
+أبوابهمإذا ليس الأمر مقصورا برضه على إيه؟ على
+
+186
+00:18:54,080 --> 00:19:00,660
+مسألة الجهاد أو على الغزو والغزاة إذا هذا يعني هذه
+
+187
+00:19:00,660 --> 00:19:04,620
+بعض ربما أو أهم الأدلة التي استدل بها القائلون
+
+188
+00:19:04,620 --> 00:19:12,400
+بالعموم واضح يا أخوات إن في عندنا يعني أقراء ثلاثي
+
+189
+00:19:12,400 --> 00:19:17,780
+وكلقول أو كل أصحاب قول يستدلونه بأدلة وكل أدلة
+
+190
+00:19:17,780 --> 00:19:23,240
+تبدو في الظاهر من المنطقية و القبول فما هو الراجح
+
+191
+00:19:23,240 --> 00:19:28,260
+يا ترى قبل الترجح فقط هنا نقف عند بعض المناقشات
+
+192
+00:19:28,260 --> 00:19:34,700
+أصحاب القول الأولالقائلين أصحاب القول الأول جماهير
+
+193
+00:19:34,700 --> 00:19:39,300
+العلماء قالوا أنتوا يعني ردوا أو ناقشوا أدلة
+
+194
+00:19:39,300 --> 00:19:45,580
+القائلين بالعموم الجزئي أو العموم الكلي صح التعبير
+
+195
+00:19:45,580 --> 00:19:49,120
+يعني اللي هم أصحاب القول الثاني عمّوها شوي أو
+
+196
+00:19:49,120 --> 00:19:54,000
+الثالث ردوا عليهم بمجموعة من الردود أو ناقشوا
+
+197
+00:19:54,000 --> 00:20:00,040
+أدلتهم ب .. ب .. ب .. ب .. ب .. بصور متعددة يعني
+
+198
+00:20:00,040 --> 00:20:08,900
+دعني أقولأهم دليل او استدالة بيها القائلون بالعموم
+
+199
+00:20:08,900 --> 00:20:12,120
+القائلين
+
+200
+00:20:12,120 --> 00:20:22,000
+بالعموم استدالوا على أنهم .. نعم أهم دليل استدالة
+
+201
+00:20:22,000 --> 00:20:27,620
+به أصحاب الرأي الثالث مسألة أنه البناء على المعنى
+
+202
+00:20:27,620 --> 00:20:32,340
+اللغوي الذي يقضي بالعموم صح؟بس دال مش هذا هو
+
+203
+00:20:32,340 --> 00:20:35,520
+الدليل الأول، الاعتماد على المعنى اللغوي، والمعنى
+
+204
+00:20:35,520 --> 00:20:42,540
+اللغوي يعوم، بسبب لا تعوم كل وجوه الخير، فردوا
+
+205
+00:20:42,540 --> 00:20:45,980
+عليهم ببساطة، قالهم يا عم صحيح هو المعنى اللغوي
+
+206
+00:20:45,980 --> 00:20:51,480
+يعوم، لكن وجد ما يخصصهماذا .. ماذا .. ما الذي
+
+207
+00:20:51,480 --> 00:21:00,560
+يخصصه المعنى المشتهر في القرآن لهذه اللفظة والذي
+
+208
+00:21:00,560 --> 00:21:08,360
+يتبادر إلى الذهن كلما أطلق هذا المعنىأصبح هو
+
+209
+00:21:08,360 --> 00:21:12,460
+المعنى المتبادل صحيح المعنى اللغوي هو الأصل لكن
+
+210
+00:21:12,460 --> 00:21:18,520
+أحيان المعنى اللغوي يتغير ويصبح المعنى المجازي هو
+
+211
+00:21:18,520 --> 00:21:25,030
+الذي يتبادر إلى الذهنمع .. مع تبا .. مع .. مع
+
+212
+00:21:25,030 --> 00:21:30,450
+تكراره واشتهاره وتعارف الناس عليه أصبح هذا بدليل
+
+213
+00:21:30,450 --> 00:21:32,650
+زي ما قلنا شوفت الصحابة إيش كانوا بيقولوا المعنى
+
+214
+00:21:32,650 --> 00:21:36,110
+في القرآن كل ما ورد قصد كده فهم بيقولوا لا يعني
+
+215
+00:21:36,110 --> 00:21:40,430
+خصص احنا في عندنا دليل ودليله .. دليله التخصيصي هو
+
+216
+00:21:40,430 --> 00:21:46,930
+اشتهار هذا اللغة بهذا المعنى في كتاب ربنا وفي سنة
+
+217
+00:21:46,930 --> 00:21:51,310
+نبينا وعلى لسان أصحاب نبينا صلى الله عليه وسلم هذا
+
+218
+00:21:51,310 --> 00:21:59,300
+أولاثم قالوا أيضا في مناقشات يعني الأحاديث هذه
+
+219
+00:21:59,300 --> 00:22:02,480
+بالنسبة للحجاج والعمار اللي ذاكروها قالوا هذه
+
+220
+00:22:02,480 --> 00:22:08,420
+الأحاديث يعني معظمها متكلم فيها متكلم فيها لا ترق
+
+221
+00:22:08,420 --> 00:22:14,020
+احنا في نظرنا لا تقوى احنا عنا نص قرآني بدي أجر
+
+222
+00:22:14,020 --> 00:22:20,570
+أخصصه بحديث متكلم فيهلأ إذا يبقى الأمر على المعنى
+
+223
+00:22:20,570 --> 00:22:27,990
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+224
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+226
+00:22:37,790 --> 00:22:43,070
+في البخاري صحيحة بس مالكوش كلام قالوا لا لنا كلام
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+227
+00:22:43,070 --> 00:22:46,070
+قصة نفس القصة واردة في البخاري
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+228
+00:22:48,170 --> 00:22:55,770
+وتقول بأن رسول الله صلى الله عليه وسلم وداه من
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+229
+00:22:55,770 --> 00:23:03,210
+ماله الخاص وداه من ماله الخاص إذن الآن في الظاهر
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+230
+00:23:03,210 --> 00:23:08,770
+أنه في نهوء من التعارض بين روايتين صحيحتين رواية
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+231
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+تفيد أنه وداه صلى الله عليه وسلم من إبن الصدقة
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+233
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+234
+00:23:24,630 --> 00:23:32,110
+ال Evil التي ودى بها هذا القتيل من ماله من Evil
+
+235
+00:23:32,110 --> 00:23:37,010
+الصدقةاشتراها من ماله فظن البعض أو في روايات انه
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+وداهم من قبل الصداقة ولم يذكر الشراء و روايات ذكرت
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+237
+00:23:42,230 --> 00:23:50,090
+الشراء و هذا يدفع انه تعارض ويدفع الاستدلال بأن
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+238
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+الصداقات
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+239
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+توزع في كل وجوه الخير المختلفة
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+حتى يعني وإن لم يكن هذا موجودا يعني قد يقول ألم
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+ينص النبي صلى الله عليه وسلم بأن الحج ألم يسمي
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+أحكام الحج أحكام الجهاد وإنما لبيان عظم قدر الحج
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+00:24:35,050 --> 00:24:42,630
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+التي في الجهاد ولكن ليست أحكامه الشرعي ليس المقصود
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+248
+00:24:48,170 --> 00:24:54,580
+من ذلك أن أحكامالحج كأحكام الجهاد فالأمر مختلف إذا
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+249
+00:24:54,580 --> 00:25:00,000
+الأدلة التي استدل بها المنقلة بالعموم الجزية أو
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+250
+00:25:00,000 --> 00:25:05,720
+الكلي مردودة أو ناقشها الأولون وفندوها ولم
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+00:25:05,720 --> 00:25:13,000
+يعتبروها وأقول لأصحاب القول الثاني والثالث وعلى
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+252
+00:25:13,000 --> 00:25:19,980
+الأخص الثالث أن يناقشواأدلت وان لم ي .. يعني يذكر
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+253
+00:25:19,980 --> 00:25:25,940
+هذا بشكل مستقل في الكتاب عندكم لكن نستطيع أن .. أن
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+254
+00:25:25,940 --> 00:25:33,410
+نفصله فنقوللهؤلاء أن يناقشوا أدلة القائلين بالجواز
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+255
+00:25:33,410 --> 00:25:40,930
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+256
+00:25:40,930 --> 00:25:44,650
+بالجهاد استدلوا بأدلة أنا أقول أن أصحاب الرأي
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+257
+00:25:44,650 --> 00:25:49,430
+الثاني والثالث لهم أن يناقشوا من .. من جهة .. يمكن
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+258
+00:25:49,430 --> 00:25:52,870
+في ثانية كلام احنا ممكن الواحد بس أنا حبيت أبرزها
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+259
+00:25:52,870 --> 00:25:53,610
+يعني
+
+260
+00:25:55,890 --> 00:26:00,410
+أهم دليل استدلوا بيه القائد بالجهاد اللي هو
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+261
+00:26:00,410 --> 00:26:07,090
+الاشتهار واعتبروه دليل مخصص
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+262
+00:26:07,090 --> 00:26:14,470
+اقول او يمكن لهؤلاء ان يقولوا بأن قصرامعنى في سبيل
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+263
+00:26:14,470 --> 00:26:18,390
+الله القائلين بالعموم يردوا على القائلين بالتخصيص
+
+264
+00:26:18,390 --> 00:26:27,690
+بالجهاد أن قصر المعنى على الجهاد بدليل
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+265
+00:26:27,690 --> 00:26:29,630
+الاجتهار تحكم
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+266
+00:26:32,190 --> 00:26:35,930
+هذا الاشتهار ليس دليلا ليس دليلا واش يعني لما
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+267
+00:26:35,930 --> 00:26:39,990
+نشتهر المعنى أنا عندما بل على العكس يا أخوات قد
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+268
+00:26:39,990 --> 00:26:44,310
+يكون العكس يعني عندما يرد في القرآن ترد في القرآن
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+269
+00:26:44,310 --> 00:26:49,830
+الكريم كلمة فيه سبيل الله وكل مرة مقترنة بما يدل
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+270
+00:26:49,830 --> 00:26:56,950
+على أنه يقصد بها الجهاد ومرة ألاقيها مجرد عن
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+271
+00:26:56,950 --> 00:27:02,640
+القرينةفي احتمال ايه؟ يحتمل ان يكون مقصود منها
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+272
+00:27:02,640 --> 00:27:07,200
+الجهاد ومحتمل ان يكون مقصود منها غير الجهاد انا
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+273
+00:27:07,200 --> 00:27:13,960
+احتاج الى دليل وإلا .. وإلا فالاصل عموم والاجتهار
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+274
+00:27:13,960 --> 00:27:19,500
+وحده ليس دليلا .. ليس دليلا فالقصه انا .. يعني لهم
+
+275
+00:27:19,500 --> 00:27:24,720
+ان يقولوا القصر والتخصيص بالجهاد هذا نوع تحكم ..
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+276
+00:27:24,720 --> 00:27:30,240
+نوع تحكم انا بدي دليل واضح .. دليل من ..النص
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+277
+00:27:30,240 --> 00:27:35,160
+القرآني من حديث نبوي إلى .. إلى .. إلى غير ذلك
+
+278
+00:27:35,160 --> 00:27:40,540
+وليس ثمة من دليل لم يثبت دليل للتخصيص في عمه في
+
+279
+00:27:40,540 --> 00:27:44,060
+عمه ناهي سيبك .. سيبك من الحديث اللي أنا استدلت
+
+280
+00:27:44,060 --> 00:27:48,400
+فيها المتكلم فيها مش مشكلة يا سيد متكلم فيها بلاش
+
+281
+00:27:48,400 --> 00:27:52,500
+لكن أنا برجع للأصل أه؟ لكن أنا جابها للاستئناس هذه
+
+282
+00:27:52,500 --> 00:28:01,720
+لكن الأصل أنه أصل النصيعوم وليس ثمّة ما يثبت فيه
+
+283
+00:28:01,720 --> 00:28:05,820
+تخصيصه أو ولم يثبت شيء في تخصيصه والاشتهار ليس
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+284
+00:28:05,820 --> 00:28:13,240
+دليلًا حديث يمكن اللي لا تحل الصدقة برضه يعني ممكن
+
+285
+00:28:13,240 --> 00:28:19,000
+نرد عليه بإنه ليس معنى أن يذكر رسول الله صلى الله
+
+286
+00:28:19,000 --> 00:28:26,970
+عليه وسلم الغازي أن الأمر مقتصر عليهلمن بيقول
+
+287
+00:28:26,970 --> 00:28:29,150
+النبي صلى الله عليه و سلم لا تحلوا صدقته لغنيين
+
+288
+00:28:29,150 --> 00:28:33,870
+إلا لخمسة لغازن في سبيل الله يعني هالمعنى ذلك
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+289
+00:28:33,870 --> 00:28:40,710
+الاقتصار يا أخوات الاقتصار المتفق عليه في هذا
+
+290
+00:28:40,710 --> 00:28:50,150
+الجانب أنه لا يجوز أن تدفع الصدقاتلغني من ما سوى
+
+291
+00:28:50,150 --> 00:28:56,490
+هؤلاء لغني لغني لكن احنا نتكلم عن وجوه خير بناء
+
+292
+00:28:56,490 --> 00:29:04,240
+مساجد عن مراكز دعوة عن وجوه بر مختلفةالمتفق عليه
+
+293
+00:29:04,240 --> 00:29:11,240
+أن الغني القادر لا يأخذ من الصدقاء الصحيح إلا إذا
+
+294
+00:29:11,240 --> 00:29:18,460
+كان غزيا لكن هل معناه ذلك أن وجهه خير أخرى ممنوعة؟
+
+295
+00:29:18,460 --> 00:29:23,020
+هل هذا يفيد ذلك؟ ليس بالضرورة لماذا تحملونه عليه؟
+
+296
+00:29:23,020 --> 00:29:29,900
+هذا أيضا نوع تحكم على أي حال هذه المناقشات التي
+
+297
+00:29:29,900 --> 00:29:35,980
+يمكن أن توردبقى أن نقول بعد كل هذه المناقشات أيضا
+
+298
+00:29:35,980 --> 00:29:44,800
+ثمة قول جميل لابد من الإشارة إليه يجمع بين هذه
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+299
+00:29:44,800 --> 00:29:52,700
+الأقوال والجمع حقيقة بين الأقوال يعني أولى من ترك
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+300
+00:29:52,700 --> 00:29:58,680
+بعضها والعمل ببعضها إن عامة .. إن عامة وهو قول
+
+301
+00:29:58,680 --> 00:30:05,050
+الشيخ القرضاويقول جميل، بالمناسبة الشيخ القرضاوي
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+302
+00:30:05,050 --> 00:30:13,690
+هو مع الجمهور في أن المعنى هو الجهاد، معنى في سبيل
+
+303
+00:30:13,690 --> 00:30:18,490
+الله يحمل على الجهاد، هذا ما قال به الجماهير قديما
+
+304
+00:30:18,490 --> 00:30:23,990
+أو علماء العلماء قديما وحديثا أو معظمهم قالوا، لكن
+
+305
+00:30:23,990 --> 00:30:31,550
+هو وبالتالي يعني هو قال ينبغي أن لا نتوسعمما قاله
+
+306
+00:30:31,550 --> 00:30:38,170
+نصًا ينبغي أن لا نتوسع في هذا المصرف لأن التوسع
+
+307
+00:30:38,170 --> 00:30:43,190
+سيكون على حساب الجهاد والمجاهدين والأصل أن تبقى
+
+308
+00:30:43,190 --> 00:30:48,990
+حصة الجهاد والمجاهدين وازنة
+
+309
+00:30:48,990 --> 00:30:57,130
+وثقيلةلأن بالجهاد أساسا تحمى بيضة الأمة وتحمى
+
+310
+00:30:57,130 --> 00:31:01,050
+حدودها وتحمى عقيدتها وتحمى شريعتها وتحمى ديما
+
+311
+00:31:01,050 --> 00:31:10,190
+وابنائها وأعراضهم وحضارتهم وكرمتهم تحمى بالجهاد
+
+312
+00:31:10,190 --> 00:31:16,450
+فالأصل بالفعل يعني من هذا الباب أن تكون هناك حصة
+
+313
+00:31:16,450 --> 00:31:23,810
+كما يقال لاتمس للجهاد والمجاهدينلكي تظل راية
+
+314
+00:31:23,810 --> 00:31:30,470
+الإسلام قوية كلما قوية شوكة المسلمين وقوية مجاهدهم
+
+315
+00:31:30,470 --> 00:31:36,810
+بقيت راية الإسلام مرتفعة والعكس بالعكس فالأصل هو
+
+316
+00:31:36,810 --> 00:31:42,870
+أننا نتوسع على حساب هذا المصر لكن في المقابل لابد
+
+317
+00:31:42,870 --> 00:31:49,830
+أن نفهم الجهاد والكلام القرضاوي بالمعنىأن نفهم
+
+318
+00:31:49,830 --> 00:31:56,650
+معنى الجهاد بمعناه الواسع في فرق أن نفهم معنى
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+319
+00:31:56,650 --> 00:32:02,910
+الجهاد بمعناه الواسع وأن لا نضيق الفهم للجهاد على
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+320
+00:32:02,910 --> 00:32:08,470
+الجهاد بالسلاح على الجهاد العسكري الجهاد العسكري
+
+321
+00:32:08,470 --> 00:32:16,750
+لونوصنف ومحطة ونوع وشكل من أشكال الجهاد لكن الجهاد
+
+322
+00:32:16,750 --> 00:32:22,210
+قد يكون بالقلم وباللسان الجهاد قد يكون سياسيا
+
+323
+00:32:22,210 --> 00:32:30,210
+واجتماعيا واقتصاديا وإعلاميا هذا كله جهاد وبهذه
+
+324
+00:32:30,210 --> 00:32:38,270
+النظرة يمكن أن ينفق على المجاهدين السياسييناللي هم
+
+325
+00:32:38,270 --> 00:32:41,510
+مش ضروري .. والمجاهدين الإعلامين يعني مراكز
+
+326
+00:32:41,510 --> 00:32:51,270
+الإعلام الجهادي صناع السياسة التي تخدم الجهاد أو
+
+327
+00:32:51,270 --> 00:33:01,250
+سياسة الجهاد وها كذا صناع يعني الجهاد الدعوي بناء
+
+328
+00:33:01,250 --> 00:33:06,670
+الرجالالذين أو الشباب وتربيتهم على الدين وعلى
+
+329
+00:33:06,670 --> 00:33:12,250
+الجهاد في المساجد الذين هم نوات المجاهدين الأولى
+
+330
+00:33:12,250 --> 00:33:19,410
+أيضا هذا يكون من قبيل الجهاد في سبيل الله بهذه
+
+331
+00:33:19,410 --> 00:33:25,370
+النظرة الواسعة والعميقة يعني التي نظرها القرضاوي
+
+332
+00:33:25,370 --> 00:33:34,950
+يعني نستطيع أن نقلل الفارقبين ايه؟ بين القرار فلا
+
+333
+00:33:34,950 --> 00:33:42,890
+نقصر الجهاد على الجهاد العسكري والسلاح ولا نوسعه
+
+334
+00:33:42,890 --> 00:33:49,810
+بحيث يشمل كل وجوه الخير لكن وجوه الخير اللي بتخدم
+
+335
+00:33:49,810 --> 00:33:56,450
+الجهادبشكل أو بآخر لا بأس في ذلك فإن هذا من الجهاد
+
+336
+00:33:56,450 --> 00:34:03,370
+إذا كانت المنطقة أو البلد تحتاج إلى مسجد للصلاة
+
+337
+00:34:03,370 --> 00:34:10,990
+لتحفظ القرآن للحلقات كيف تتصور وجود مجاهدين وهم لم
+
+338
+00:34:10,990 --> 00:34:15,610
+يتربوا على كتاب ربنا ولم يعرفوا الصلاة في المساجد
+
+339
+00:34:15,610 --> 00:34:20,090
+كيف هذا؟ هم النواة المسجد هو النواة الأولى فمن هنا
+
+340
+00:34:21,110 --> 00:34:26,630
+بلد بدها دعوة يخشى عليها من التنصير، في عليها هجمة
+
+341
+00:34:26,630 --> 00:34:32,010
+أو من التشيع أو من العلمانة أو من كذا، نتركها، هي
+
+342
+00:34:32,010 --> 00:34:39,230
+لسه خايفين عليهم احنا من أن يذوبوا ومن أن ينصهروا
+
+343
+00:34:39,230 --> 00:34:42,790
+في الأديان الأخرى والمذاهب الأخرى، لسه الجهاد
+
+344
+00:34:42,790 --> 00:34:46,840
+مرحلة متقدمةبعدين، يعني لحظة النبي صلى الله عليه
+
+345
+00:34:46,840 --> 00:34:51,320
+وسلم تلاتة عشر عامة في مكة ولم يفرض الجهاد، ولسة
+
+346
+00:34:51,320 --> 00:34:54,180
+كمان في السنة الأولى من الهجرة، لم يفرض الجهاد،
+
+347
+00:34:54,180 --> 00:34:58,540
+بعد الهجرة، لم يفرض الجهاد العقيدة أولا عندما تبنى
+
+348
+00:34:58,540 --> 00:35:04,360
+العقائد في النفوس تتأهل للجهاد في سبيل اللهفهذا
+
+349
+00:35:04,360 --> 00:35:08,880
+إذن من الجهاد بل قاعدة الجهاد الأساسية هي بناء
+
+350
+00:35:08,880 --> 00:35:12,440
+العقيدة وبناء الشريعة وتعليم الدين وإلى غير ذلك
+
+351
+00:35:12,440 --> 00:35:16,540
+فلا بأس إذن أن تبنى في المساجد تبنى بعض المساجد
+
+352
+00:35:16,540 --> 00:35:20,800
+تبنى بعض المراكز الدعوية لا بأس وهذا ما جاءت به
+
+353
+00:35:20,800 --> 00:35:26,720
+فتاوة بعض الندوات العلمية منها فتوة الندوة الأولى
+
+354
+00:35:26,720 --> 00:35:32,010
+لقماية الذكاء بالقاهرة أنه يراد بيه الجهادلكن
+
+355
+00:35:32,010 --> 00:35:37,890
+بمعناه الواسع الجهاد بمعناه الواسع الجهاد بمعنى
+
+356
+00:35:37,890 --> 00:35:42,690
+تمويل الحركات الجهادية والمقاومة للأعداء والمقاومة
+
+357
+00:35:42,690 --> 00:35:49,510
+والمقاومة للأفكار الهدامة لما لا تعطى هذه هذا من
+
+358
+00:35:49,510 --> 00:35:54,470
+الجهاد طبعا وكذلك لكن لا يقف الأمر عند هذا بل لما
+
+359
+00:35:54,470 --> 00:36:00,720
+لا تعطى لكللكل الجهود، لكل الأفراد والجماعات التي
+
+360
+00:36:00,720 --> 00:36:05,900
+تسعى لإعادة تحكيم شرع الله ولنشر دعوات الإسلام،
+
+361
+00:36:05,900 --> 00:36:10,840
+هذا كله أيضًا يعتبر من قبيل الجهاد بالمعنى العام،
+
+362
+00:36:10,840 --> 00:36:16,110
+لماذا لا تُعطى لمراكز الدعوة؟التي الامنة الموثوقة
+
+363
+00:36:16,110 --> 00:36:19,530
+التي تعمل لخدمة الإسلام وتربي النشأة على الإسلام
+
+364
+00:36:19,530 --> 00:36:25,310
+والجهاد وإلى غير ذلك لماذا لا تُعطى للجهات التي
+
+365
+00:36:25,310 --> 00:36:28,770
+تموّل الأقليات الإسلامية في بلاد الغرب والشرق هنا
+
+366
+00:36:28,770 --> 00:36:33,390
+وهناك حماية لهم وحماية لدينهم وتثبيتًا لهم إذا هذا
+
+367
+00:36:33,390 --> 00:36:39,570
+ما جاءت به هذه الفتاوىوكذلك فتوة يعني هيئة كبار
+
+368
+00:36:39,570 --> 00:36:43,870
+العلماء في السعودية جات يعني صحيح أضيق مطاقا لكن
+
+369
+00:36:43,870 --> 00:36:49,930
+يعني لا تختلف ربما كثيرا يعني هم قالوا بأنه المصرف
+
+370
+00:36:49,930 --> 00:36:55,070
+هذا يعني الجهاد ولكن أضافوا كلمة ممكن احنا نرا
+
+371
+00:36:55,070 --> 00:37:02,880
+فيها توسعة وما قالوا يعني المراد الغزاةوالمجاهدين
+
+372
+00:37:02,880 --> 00:37:09,560
+وما يلزم لهم من استعدادات وكلنا يعلم يا أخوات أن
+
+373
+00:37:09,560 --> 00:37:15,020
+من استعدادات الجهاد والمجاهدين ليس فقط السلاح
+
+374
+00:37:15,020 --> 00:37:18,580
+التعبئة المعنوية التعبئة العلمية التعبئة الإعلامية
+
+375
+00:37:18,580 --> 00:37:24,560
+كل هذا من استعدادات للجهادوالمجاهدين نحن بهذا
+
+376
+00:37:24,560 --> 00:37:31,160
+الرأي يعني المتوسط أو الوسطي الذي يجمع بين الآراء
+
+377
+00:37:31,160 --> 00:37:37,160
+المختلفة نطمئنه اليه ولعله يكون الراجح في هذه
+
+378
+00:37:37,160 --> 00:37:40,160
+المسألة بارك الله فيكم وشكرا لكم
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/NEI3R4Ew8wY_postprocess.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/NEI3R4Ew8wY_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..b971678f4d44cb137e148f2ea90508f55814b03d
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/NEI3R4Ew8wY_postprocess.srt
@@ -0,0 +1,1676 @@
+1
+00:00:20,600 --> 00:00:23,580
+بسم الله الرحمن الرحيم الحمد لله والصلاة والسلام
+
+2
+00:00:23,580 --> 00:00:30,240
+على رسول الله على آله وصحبه وسلم تسليما كثيراوبعد
+
+3
+00:00:30,240 --> 00:00:36,980
+حياكم الله الإخوة الكرام وأهلا وسهلا بكم في هذا
+
+4
+00:00:36,980 --> 00:00:41,740
+اللقاء المتجدد الذي نسأل الله سبحانه وتعالى أن
+
+5
+00:00:41,740 --> 00:00:46,800
+نكون في ميزان حسناتناوأن يعلمنا فيه ما ينفعنا وأن
+
+6
+00:00:46,800 --> 00:00:52,900
+ينفعنا بما علمنا وأن يزيدنا من علمه في المخاضرة
+
+7
+00:00:52,900 --> 00:00:56,620
+السابقة أيها الأخوة الكرام تحدثنا عن
+
+8
+00:01:01,000 --> 00:01:07,080
+المساق الذي نريد أن ندرسه وهو القضايا الفقهية
+
+9
+00:01:07,080 --> 00:01:15,040
+المعاصرة وطوفنا حول مفرداته على وجه الإجمال ثم
+
+10
+00:01:15,040 --> 00:01:23,020
+تحدثنا عن مصطلح القضايا الفقهية المعاصرة وتعريفه
+
+11
+00:01:23,020 --> 00:01:32,880
+وتوضيح معنى التعريفمختتمين كل ذلك ببيان الفوائد
+
+12
+00:01:32,880 --> 00:01:39,860
+والاهنية التي تكمن ورا دراسة أحكام القضايا الفقهية
+
+13
+00:01:39,860 --> 00:01:45,140
+المعاصرة وقد تعرفنا على العديد من الفوائد التي
+
+14
+00:01:45,140 --> 00:01:53,800
+تكمن ورا دراسةمعرفة أحكام القضايا المعاصرة في كل
+
+15
+00:01:53,800 --> 00:02:00,620
+زمن من الأزمنة وعلى الأخص الزمن الذي نعيشه فيه
+
+16
+00:02:00,620 --> 00:02:05,440
+فنحن نتحدث هنا عن القضايا المعاصرة التي تتعلق بأهل
+
+17
+00:02:05,440 --> 00:02:11,220
+زماننا هذا وما أكترها كما قلنا سواء تعلقت
+
+18
+00:02:11,220 --> 00:02:15,760
+بالعبادات أو بالمعاملات أو بغير ذلك من مجالات
+
+19
+00:02:15,760 --> 00:02:21,670
+الفقه المختلفةواليوم نتحدث بإذن الله سبحانه وتعالى
+
+20
+00:02:21,670 --> 00:02:30,450
+عن الشروط التي ينبغي أن تتوفر في من يتصدون لبيان
+
+21
+00:02:30,450 --> 00:02:38,610
+أحكام القضايا الفقهية المحاصرة فيما يعرف قديما أو
+
+22
+00:02:38,610 --> 00:02:42,310
+فيما تحدث فيه العلماء قديما في أصول الفقه بشروط
+
+23
+00:02:42,310 --> 00:02:53,790
+المجتهد فإن منمن يريد أن يتصدى لبيان هذه القضايا
+
+24
+00:02:53,790 --> 00:02:58,350
+وأحكامها لابد أن تتوفر فيه شروط الاجتهاد أي بمعنى
+
+25
+00:02:58,350 --> 00:03:02,530
+أخر لابد أن يكون أهلا لذلك لابد أن يكون مشتهدا لأن
+
+26
+00:03:02,530 --> 00:03:09,310
+هذه قضايا فقهية والقضايا الفقهية لا يتصدى لبيانها
+
+27
+00:03:09,310 --> 00:03:18,330
+إلا المجتهدينإلا العلماء الذين توفر فيهم شروط ولا
+
+28
+00:03:18,330 --> 00:03:24,130
+ينبغي لكل من درس كتابا هنا أو قرأ حديثا هناك أو
+
+29
+00:03:24,130 --> 00:03:28,950
+حافظ آية من هنا أو جزء من القرآن أن يظن في نفسه
+
+30
+00:03:28,950 --> 00:03:35,450
+أنه يستطيع أن يتصدى وأن يبين الحكم الشرعي لمسألة
+
+31
+00:03:35,450 --> 00:03:42,470
+فقهيةأو خاصة من تلك المسائل التي قلنا أنها تحتاج
+
+32
+00:03:42,470 --> 00:03:49,150
+إلى نظر وإلى عمق ولم يبين
+
+33
+00:03:49,150 --> 00:03:54,030
+العلماء القدامى الحكم فيها ولم يتناولها نص في كتاب
+
+34
+00:03:54,030 --> 00:04:03,070
+ربنا ولا في سنة نبينا صلى الله عليه وسلم وهي محل
+
+35
+00:04:03,070 --> 00:04:05,530
+نظر
+
+36
+00:04:09,550 --> 00:04:15,410
+ولذلك هنا يعني لابد أن نشير إلى الشروط التي ينبغي
+
+37
+00:04:15,410 --> 00:04:19,510
+أن تتوفر شروط المجتهد اللي تتحدث عنها القدماء وإن
+
+38
+00:04:19,510 --> 00:04:25,670
+كان ثمة من شروط إضافية أيضا نذكرها ثم نتحدث عن
+
+39
+00:04:25,670 --> 00:04:31,030
+الضوابط أيضا المتعلقة بالاجتهاد في هذه القبائليعني
+
+40
+00:04:31,030 --> 00:04:36,850
+أود فقط قبل أن أبدأ في الحديث عن هذه الشروط سواء
+
+41
+00:04:36,850 --> 00:04:42,410
+الأساسية أو الإضافية أو تلكم الضوابط التي لابد أن
+
+42
+00:04:42,410 --> 00:04:48,170
+تتوفر عند الاجتهاد في المسائل الفقهية يعني أود أن
+
+43
+00:04:48,170 --> 00:04:54,030
+أتحدث بإيجاز عن في ما يتعلق في ما له علاقة مباشرة
+
+44
+00:04:54,030 --> 00:05:03,020
+في هذا الموضوعبأن هذه الشريعة ممثلة في مصادرها
+
+45
+00:05:03,020 --> 00:05:08,460
+الرئيسية ممثلة في مصادرها الرئيسية الكتاب والسنة
+
+46
+00:05:08,460 --> 00:05:17,070
+على وجه الخصوص تحمل عوامل صلاحيةللتطبيق و للتشريع
+
+47
+00:05:17,070 --> 00:05:22,750
+قبل ذلك في كل زمان و مكان هذه الشريعة تحمل في طيات
+
+48
+00:05:22,750 --> 00:05:28,490
+نصوصها و في ثنايا مصادرها عوامل بقائها عوامل
+
+49
+00:05:28,490 --> 00:05:34,950
+خلودها عوامل صلاحيتها لكل زمان و كل مكان و هذه
+
+50
+00:05:34,950 --> 00:05:40,530
+الأرضية هي التي نستند إليها عندما نقول أنه لابد
+
+51
+00:05:40,530 --> 00:05:46,190
+على المجتهدين أن يقوموا ببيانالأحكام الشرعية
+
+52
+00:05:46,190 --> 00:05:52,770
+للقبائل المستجدة لأن المجتهدين
+
+53
+00:05:52,770 --> 00:05:57,290
+من خلال اطلاعهم من خلال اطلاعهم على مصادر هذه
+
+54
+00:05:57,290 --> 00:06:03,470
+الشريعة ستصبح لهم القدرة وتتكون لديهم الأهلية
+
+55
+00:06:03,470 --> 00:06:12,000
+وتتوفر لديهم الإمكانية لمعرفة الحكم الشرعيفلنظروا
+
+56
+00:06:12,000 --> 00:06:21,360
+إلى هذه النصوص حقيقة يجدوا ما يدلل على ذلك وما
+
+57
+00:06:21,360 --> 00:06:28,140
+يثبت ذلك فمصادر هذه الشريعة العظيمة أولا وآخرا هي
+
+58
+00:06:28,140 --> 00:06:33,530
+من عند الله سبحانهوتعالى كتاب ربنا وسنة نبينا سواء
+
+59
+00:06:33,530 --> 00:06:37,130
+طريقة مباشرة أو غير مباشرة عن طريق الوحي الجبريل
+
+60
+00:06:37,130 --> 00:06:43,870
+أو يعني مما ألهم به النبي صلى الله عليه وسلم من
+
+61
+00:06:43,870 --> 00:06:49,710
+أحاديث وسنن كل هذا مرده إلى الله سبحانه وتعالى
+
+62
+00:06:49,710 --> 00:06:55,370
+وبالتالي فإن الله عندما يعني يبين حكما بالفعل
+
+63
+00:06:55,370 --> 00:07:03,520
+سيكون صالحا ويكونمناسبة للبشر لأن الله سبحانه
+
+64
+00:07:03,520 --> 00:07:07,060
+وتعالى هو العليم والخبير هو الخالق لهذه النفس
+
+65
+00:07:07,060 --> 00:07:12,240
+الإنسانية والذي يعلم ما يصلحها وما يفسدها فعندما
+
+66
+00:07:12,240 --> 00:07:18,200
+يقدم لنا ربنا سبحانه وتعالى منة ونعمة منه، انعامة
+
+67
+00:07:18,200 --> 00:07:25,040
+منه علينا حكما شرعيا، يجب أن نفهم ونؤمن ونعتقد
+
+68
+00:07:26,650 --> 00:07:33,210
+ونعلم أن هذا الحكم فيه الصلاحية
+
+69
+00:07:33,210 --> 00:07:44,990
+وفيه المنفعة وفيه الخير لنا ثم إن هذه الشريعة أيضا
+
+70
+00:07:44,990 --> 00:07:49,890
+ناضم في مصادرها وفي تفاصيل أحكامها التي وردت بها
+
+71
+00:07:49,890 --> 00:07:57,860
+نصوصها أنها تراعي العقلوتخاطبه وتراعي الواقع وما
+
+72
+00:07:57,860 --> 00:08:08,060
+يناسبه فهي لا تناقض العقل بل تتوافق معاه لا تعارض
+
+73
+00:08:08,060 --> 00:08:14,140
+بين الشريع والعقل لكن أي عقل إنه العقل السوي العقل
+
+74
+00:08:14,140 --> 00:08:21,200
+السوي وليس العقل المنحرف الذي ضل وانحرف عن الجادة
+
+75
+00:08:21,410 --> 00:08:28,110
+العقل كل ما كان سويا تجده متوافقا متناغما مع هذه
+
+76
+00:08:28,110 --> 00:08:33,690
+الشريعة ومع أحكامها هذه الشريعة إضافة إلى مخطبتها
+
+77
+00:08:33,690 --> 00:08:39,790
+للعقل ومراعتها له فإنها أيضا تراعي هذا الواقع الذي
+
+78
+00:08:39,790 --> 00:08:48,510
+يعيشه الإنسان ومتغيراته واختلاف الزمان فيه والمكان
+
+79
+00:08:48,510 --> 00:08:54,930
+فيأتي الحكم بحسبما يناسب الواقع ولذلك تجد الحكم
+
+80
+00:08:54,930 --> 00:08:59,670
+أحيانا هناك حكما عاما وأحيانا حكم استثنائي عندما
+
+81
+00:08:59,670 --> 00:09:06,050
+يتغير الواقع ربما يتغير الحكم ولعل الأمثلة في ذلك
+
+82
+00:09:06,050 --> 00:09:11,310
+أكثر من أن تحصى ثم إن هذه الأحكام أحكام هذه
+
+83
+00:09:11,310 --> 00:09:18,540
+الشريعة في أساسها وفيما اجتملت عليه نصوصها تتناسب
+
+84
+00:09:18,540 --> 00:09:23,340
+مع الفطرة الفطرة السليمة الفطرة السوية التي خلق
+
+85
+00:09:23,340 --> 00:09:27,680
+وفطر عليها الإنسان ذلك أن الله سبحانه وتعالى هو
+
+86
+00:09:27,680 --> 00:09:33,480
+الذي خلقنا وهو الذي فطرنا على ما فطرنا عليه وجبلنا
+
+87
+00:09:33,480 --> 00:09:37,440
+على ما جبلنا عليه ووضع لنا هو نفسه سبحانه وتعالى
+
+88
+00:09:37,700 --> 00:09:43,480
+أحكاما تتناسب مع هذه الفطرة وهذا كله من دواعي أن
+
+89
+00:09:43,480 --> 00:09:50,940
+تكون هذه الشريعة صالحة ومناسبة لكل الناس في كل
+
+90
+00:09:50,940 --> 00:09:59,620
+زمان وفي كل مكان وليست مجال تجريب لأ بل إن صلاحها
+
+91
+00:09:59,620 --> 00:10:08,000
+صلاح متأقدلأنها من عند الخبير العليم سبحانه وتعالى
+
+92
+00:10:08,000 --> 00:10:16,240
+هذه الأحكام كذلك ترعي مصالح الناس وتدرؤ عنهم وتدفع
+
+93
+00:10:16,240 --> 00:10:21,180
+عنهم المفاسد هذا هو المقياس الذي لو استقرأنا جميع
+
+94
+00:10:21,180 --> 00:10:26,420
+الأحكام الشرعية الواردة في كتاب ربنا وفي سنة نبينا
+
+95
+00:10:26,420 --> 00:10:32,900
+صلى الله عليه وسلم سوف لا نجده أبداحُقماً إلا
+
+96
+00:10:32,900 --> 00:10:37,860
+ويحقق مصلحةً سوف لا نجد أمرا يأمرنا به الله إلا
+
+97
+00:10:37,860 --> 00:10:42,740
+وفيه الخير ولا شيء ينهن عنه الله إلا ويدفع به عن
+
+98
+00:10:42,740 --> 00:10:48,740
+الضرر فحيثما وجدت المصلحة فتم شرع الله وحيثما وجدت
+
+99
+00:10:48,740 --> 00:10:54,540
+المفسدة فينهى عن ذلك الله سبحانه وتعالى تجد النهي
+
+100
+00:10:55,040 --> 00:10:59,460
+من هذه الشريعة حيثما وجدت المفسدة وحيثما وجدت
+
+101
+00:10:59,460 --> 00:11:03,660
+المصطحى تجد الأمر بمفهوم العام الأمر سواء على سبيل
+
+102
+00:11:03,660 --> 00:11:09,380
+الوجوب أو الاستحباب أو حتى الإباحة الأمر بمفهومه
+
+103
+00:11:09,380 --> 00:11:16,120
+العام ثم إنها شريعة العدل والقصة هذه الشريعة التي
+
+104
+00:11:16,120 --> 00:11:21,340
+جاءت من عند العدل سبحانه وتعالى وتأمر بالعدل إن
+
+105
+00:11:21,340 --> 00:11:25,570
+الله يأمركم بالعدلوالإحسان وإيتاء ذي القربة فهي
+
+106
+00:11:25,570 --> 00:11:30,470
+شريعة العدل والعدل أيضًا هو الذي يبحث عنه الناس
+
+107
+00:11:30,470 --> 00:11:36,530
+جميعًا وليس المسلمين فقط العدل هو الذي هو الذي
+
+108
+00:11:36,530 --> 00:11:42,430
+يطمئن الناس على حياتهم هو الحلقة المفقودة في هذا
+
+109
+00:11:42,430 --> 00:11:47,150
+الزمان وفي معظم الأزمنة والذي به تستقر الشعوب
+
+110
+00:11:47,150 --> 00:11:52,320
+وتأمن ولذلك نحن نقول دائمًاأن هذه الشريعة لما كانت
+
+111
+00:11:52,320 --> 00:11:58,120
+شريعة العدل تستقر استقرت فيها استقر الناس معها و
+
+112
+00:11:58,120 --> 00:12:04,960
+تعايشوا معها و أطمأنوا بها و بأحكامها و ارتقوا و
+
+113
+00:12:04,960 --> 00:12:12,080
+عاشوا في أهنئي يعني ما تكون الحياة ثم إن مصادر هذه
+
+114
+00:12:12,080 --> 00:12:16,420
+الشريعة هي مصادر ثابتة ثابتة
+
+115
+00:12:17,440 --> 00:12:24,380
+لا مجال لتغييرها أو لتبديلها من حيث الجملة لا مجال
+
+116
+00:12:24,380 --> 00:12:29,360
+لتغيير أصولها ولا لتغيير نصوصها فهي من هذا الجنب
+
+117
+00:12:29,360 --> 00:12:33,920
+ثابتة وهي في نفس الوقت فيها الصفة وخاصية المرونة
+
+118
+00:12:33,920 --> 00:12:39,220
+المرونة في تطبيقات هذه النصوص وهذه الأحكام على
+
+119
+00:12:39,220 --> 00:12:44,730
+المسائل باختلاف الزمان واختلاف المكانالواقع
+
+120
+00:12:44,730 --> 00:12:50,690
+واختلاف الحال فكل هذا تراعيه هذه الشريعة فهي فيها
+
+121
+00:12:50,690 --> 00:12:57,470
+صفة صفة الثبات وصفة المرونة لما يعالجوا كل
+
+122
+00:12:57,470 --> 00:13:03,950
+المتناقضات التي يعاني منها هذا الإنسان ومن أجل ذلك
+
+123
+00:13:04,990 --> 00:13:10,870
+لو نظرت إلى طبيعتي هذه النصوص التي جاءت بها هذه
+
+124
+00:13:10,870 --> 00:13:16,570
+الشريعة ستجد أنها للتأكيد على مرونة هذه الشريعة
+
+125
+00:13:16,570 --> 00:13:21,310
+وعلى صلاحيتها في كل زمن وفي كل مكان تجد أن نصوصها
+
+126
+00:13:21,310 --> 00:13:27,000
+التي يعنيجاء بها القرآن الكريم والتي هي عبارة عن
+
+127
+00:13:27,000 --> 00:13:31,280
+كلام ربنا سبحانه وتعالى جاءت مجملة غير مفصلة
+
+128
+00:13:31,280 --> 00:13:38,720
+تفصيلا دقيقا مجملة لكي تكون هناك إمكانية لمراعاة
+
+129
+00:13:38,720 --> 00:13:44,560
+المتغيرات ولمراعاة الأحوال وإمكانية الاجتهاد
+
+130
+00:13:44,560 --> 00:13:49,500
+المصلحي المتوافق مع أحوال الإنسان في مختلف ظروفه
+
+131
+00:13:50,050 --> 00:13:56,390
+جاءت مجملة ولم تأتي يعني مفصلة إلا في بعض المسائل
+
+132
+00:13:56,390 --> 00:14:04,790
+التي لو تركت تفصيل فيها للناس لفسدوا وأفسدواولكن
+
+133
+00:14:04,790 --> 00:14:08,450
+في معظم الأحوال في معظم المسائل جاءت الأحكام في
+
+134
+00:14:08,450 --> 00:14:17,650
+كتاب ربنا على وجه الإجمال تأكيدا على صفة المرونة
+
+135
+00:14:17,650 --> 00:14:27,730
+وعلى صفتي الصلاحية لكل زباد و لكل مكانوفيها وهي
+
+136
+00:14:27,730 --> 00:14:34,290
+عندما تأتي على هذا النحو وتتصف بصفة مرونة لا يعني
+
+137
+00:14:34,290 --> 00:14:40,190
+أنها ليست ثابتة فهي من زاوية أخرى كما قلت قبل قليل
+
+138
+00:14:40,190 --> 00:14:48,170
+هي فيها من الثبوت وفيها من الاستقرار
+
+139
+00:14:48,170 --> 00:14:56,080
+وفيها من المرجعيات التي لا تتغير ولا تتبدلحتى لا
+
+140
+00:14:56,080 --> 00:15:04,200
+تضيع هذه الشريعة لأي سبب من الأسباب وفي أي وقت من
+
+141
+00:15:04,200 --> 00:15:08,580
+الأوقات وثبات الشريعة يعني إذا كانت مرونة الشريعة
+
+142
+00:15:08,580 --> 00:15:13,380
+تراعى بها المتغيرات ومتغيرات الواقع والحال فإن
+
+143
+00:15:13,380 --> 00:15:20,990
+ثباتها يراعى فيه ومنهم استقرارالتشريع و تحقق الثقة
+
+144
+00:15:20,990 --> 00:15:26,870
+و بناء يعني و .. و .. و .. و .. و .. و أن تبنى
+
+145
+00:15:26,870 --> 00:15:34,050
+العلاقات بين الناس على دعائمة .. على دعائمة ثابتة
+
+146
+00:15:34,050 --> 00:15:39,830
+و .. و .. و قوية ذلك أن الناس لو علموا أن أصول
+
+147
+00:15:39,830 --> 00:15:44,930
+التشريع أو أصول القانون في أي مكان و في أي زمانغير
+
+148
+00:15:44,930 --> 00:15:48,790
+ثابتة فإن هذا ينعكز سلبيا على استقرار العلاقات
+
+149
+00:15:48,790 --> 00:15:51,610
+بينهم
+
+150
+00:15:53,000 --> 00:15:59,200
+كله يؤكد لنا مدى صلاحية هذه الشريعة لكل زمان و لكل
+
+151
+00:15:59,200 --> 00:16:03,440
+مكان من خلال مصادرها و نصوصها و حتى من خلال
+
+152
+00:16:03,440 --> 00:16:09,300
+اجتهاداتها لنعود إلى مقصودنا الأساس و هو من يتصدى
+
+153
+00:16:09,300 --> 00:16:15,700
+للقضايا المعاصرة و لبيانها قلت بأن من يتصدهم
+
+154
+00:16:15,700 --> 00:16:22,090
+المجتهدونو هم العلماء الذين تحدث علماؤنا و
+
+155
+00:16:22,090 --> 00:16:27,270
+أصليوننا و فقهاؤنا قديما عن الشروط التي ينبغي أن
+
+156
+00:16:27,270 --> 00:16:33,670
+تتوفر فيهم و على رأس هذه الشروط أنا سأذكرها بسرعة
+
+157
+00:16:33,670 --> 00:16:40,110
+يعني هنا فقط و على رأس هذه الشروط أن يكون هذا
+
+158
+00:16:40,110 --> 00:16:50,660
+الشخص الذي يتصدى و الذييتأهل لبيان الحكم أن يكون
+
+159
+00:16:50,660 --> 00:16:57,420
+مكلفا فلا يُعقل أن نأخذ أحكام شريعة ربنا عن إنسان
+
+160
+00:16:57,420 --> 00:17:02,560
+غير عاقل أو إنسان غير بالغ أو إنسان غير رشيد أو
+
+161
+00:17:02,560 --> 00:17:06,860
+إنسان غير مسلم فلبد أن يكون مكلفا أي مسلم بالغا
+
+162
+00:17:06,860 --> 00:17:15,380
+عاقلاوهذا .. هذا أساس .. هذا أساس ثابت فلا يجوز
+
+163
+00:17:15,380 --> 00:17:20,820
+ولا يقبل ممن يتصدى لبيان الأحكام للقضايا المعاصرة
+
+164
+00:17:20,820 --> 00:17:28,340
+أن لا يتصف بهذه الصفة أو بهذا الشرط المجمل
+
+165
+00:17:29,620 --> 00:17:33,780
+ثم إضافة إلى ذلك، لابد أن يكون عالمًا بنصوص كتاب
+
+166
+00:17:33,780 --> 00:17:38,900
+ربنا سبحانه وتعالى وحديث سنة نبينا صلى الله عليه
+
+167
+00:17:38,900 --> 00:17:41,060
+وسلم
+
+168
+00:17:43,950 --> 00:17:49,790
+هنا بعض العلماء اكتفوا بأن يكون على الأقل أن يعلم
+
+169
+00:17:49,790 --> 00:17:56,770
+من الكتاب بنصوص الآيات التي تتعلق بالأحكام وأن
+
+170
+00:17:56,770 --> 00:18:02,810
+يعلم من السنة بنصوص الأحديث التي تتعلق بالأحكام
+
+171
+00:18:02,810 --> 00:18:07,050
+لكن أقول ربما يكون هذا هو الحد الأدنى لكن الأولى
+
+172
+00:18:07,050 --> 00:18:11,420
+والأفضلأن يكون عالمًا بمختلف النصوص أو بأكبر قدر
+
+173
+00:18:11,420 --> 00:18:15,820
+ممكن من نصوص الكتاب على الأقل ومن أحاديث رسول الله
+
+174
+00:18:15,820 --> 00:18:20,280
+صلى الله عليه وسلم وكل ما كان اطلاع الفقيه
+
+175
+00:18:20,280 --> 00:18:24,180
+والمجتهد على أكبر قدر ممكن من نصوص الكتاب ومن
+
+176
+00:18:24,180 --> 00:18:28,120
+أحاديث النبي صلى الله عليه وسلم كانت أهليته
+
+177
+00:18:28,120 --> 00:18:35,360
+الاجتهادي أكبر وكانت الشروط المتوفرة فيه يعني أقوى
+
+178
+00:18:35,360 --> 00:18:44,240
+وامكانيةوإمكانية وصوله للحكم الصحيح أقرن إضافة إلى
+
+179
+00:18:44,240 --> 00:18:49,640
+ذلك فإنه يشترط أن يكون عالمًا بقواعد علم أصول فقه
+
+180
+00:18:49,640 --> 00:18:54,600
+تلك القواعد التي وضعها لنا علماؤنا منذ القرن الأول
+
+181
+00:18:54,600 --> 00:18:58,280
+الهجر الأول أو القرن الهجر الثاني يعني على وجه
+
+182
+00:18:58,280 --> 00:19:03,250
+الوجه الراجحوإن كانت بوادله قد عرفت في القرن الأول
+
+183
+00:19:03,250 --> 00:19:09,310
+أيضا لكن كعلم مستقلا أو علم يعني متكاملا ربما ظهر
+
+184
+00:19:09,310 --> 00:19:13,150
+في القرن الثاني لكن هذه القواعد سواء في الأول أو
+
+185
+00:19:13,150 --> 00:19:17,390
+في الثاني لابد لكل مجتهد أن يريد أن يجتهد في
+
+186
+00:19:17,390 --> 00:19:21,930
+الأحكام الشرعية أن يكون عالما عالما بهذه القضايا
+
+187
+00:19:21,930 --> 00:19:26,770
+أن يعلم أن الأمر يدل على الوجوب وأن النهيه يدل على
+
+188
+00:19:26,770 --> 00:19:35,820
+التحريموأن العام يجتمع الجميع مع الأفراد
+
+189
+00:19:35,820 --> 00:19:45,320
+التي دل عليها وأن النصةالمتأخر ينسخ حكم النص
+
+190
+00:19:45,320 --> 00:19:49,040
+المتقدم إذا كان في نفس .. يعني إذا كانت نفس
+
+191
+00:19:49,040 --> 00:19:55,140
+المسألة مع اختلاف الحكم و هكذا .. يعني هذه قواعد
+
+192
+00:19:55,140 --> 00:19:58,440
+علم أصول الفقه في ما يتعلق بالعموم والخصوص
+
+193
+00:19:58,440 --> 00:20:07,880
+والاشتراك والتقييد والإطلاق والنسخ و ما يتعلق بهذه
+
+194
+00:20:07,880 --> 00:20:13,200
+القواعد لأن هذه القواعدهي التي تضبط عملية الاجتهاد
+
+195
+00:20:13,200 --> 00:20:19,820
+وتساعد المجتهدين على الوصول للحكم الشرعي إضافة إلى
+
+196
+00:20:19,820 --> 00:20:24,770
+ذلك يجب أن يكون عالمًا بلغةاللغة العربية هذه لغة
+
+197
+00:20:24,770 --> 00:20:29,830
+القرآن ولغة نبينا محمد العدنان صلى الله عليه وسلم
+
+198
+00:20:29,830 --> 00:20:34,630
+فإن لم يكن عالم باللغة العربية أن له أن يفهم
+
+199
+00:20:34,630 --> 00:20:39,750
+دلالات ونصوص وأن له أن يعرف الأحكام منها وأن له أن
+
+200
+00:20:39,750 --> 00:20:43,870
+يعرف دلالات سنة النبي صلى الله عليه وسلم وأن يعرف
+
+201
+00:20:43,870 --> 00:20:49,210
+الأحكام منها بالطبعلا نشترض أن يكون عربيا ولكن
+
+202
+00:20:49,210 --> 00:20:53,430
+نشترض أن يكون عالم باللغة العربية حتى لو لم يكن
+
+203
+00:20:53,430 --> 00:20:57,970
+عربي العصر وكثير من المجتهدين الذين وصلوا إلى درجة
+
+204
+00:20:57,970 --> 00:21:02,690
+الاجتهاد وبينوا أحكام شريعة ربنا في مختلف الأزمنة
+
+205
+00:21:02,690 --> 00:21:06,670
+وفي مختلف الأماكن لم يكنوا من العرب فليس الأمر
+
+206
+00:21:06,670 --> 00:21:13,200
+قائما على العصبية ولا على العنصرية أبدا ولكنلابد
+
+207
+00:21:13,200 --> 00:21:17,060
+أن يعرف لغة العرب لا لذات اللغة وإن كنا نعتز بهذه
+
+208
+00:21:17,060 --> 00:21:21,200
+اللغة لأنها لغة القرآن ولغة أهل الجنة في الجنة
+
+209
+00:21:21,200 --> 00:21:24,980
+ولغة نبينا محمد صلى الله عليه وسلم لكن مع ذلك كله
+
+210
+00:21:24,980 --> 00:21:30,120
+وإنما نريد أن نتعرف أو أن يعرف المجتهد هذه اللغة
+
+211
+00:21:30,120 --> 00:21:37,430
+لأن أصولهوالأحكام ونصوص التشريع ومصادر التشريع
+
+212
+00:21:37,430 --> 00:21:44,210
+نزلت بها ولا يفهم روح التشريع ومقاصده وقواعده إلا
+
+213
+00:21:44,210 --> 00:21:52,450
+من فهم دلالات هذه اللغة ومعانيها وروحها
+
+214
+00:21:53,030 --> 00:22:00,010
+ويعني أضيف كثيرا إن قلت أنه يجب كذلك أن يكون عالما
+
+215
+00:22:00,010 --> 00:22:04,210
+بأسباب النزول لأن أسباب النزول للآيات الكريمة
+
+216
+00:22:04,210 --> 00:22:09,820
+يتعلق بها معرفة الحكم وتساعد في معرفة الحكمفمن
+
+217
+00:22:09,820 --> 00:22:19,800
+تعرف على سبب النزول استوضح يعني كثيرا وساعده الأمر
+
+218
+00:22:19,800 --> 00:22:26,100
+كثيرا على التوصل إلى الحكم بخلاف ما لا يعرف سبب
+
+219
+00:22:26,100 --> 00:22:33,890
+النزول للآية الكريمة أو الظروفوورود الحديث الذي
+
+220
+00:22:33,890 --> 00:22:37,630
+تحدث به النبي صلى الله عليه وسلم لبيان حكم معين
+
+221
+00:22:37,630 --> 00:22:42,710
+هذه كلها تحتاجوا يعني من الأهمية بمكان لمعرفة
+
+222
+00:22:42,710 --> 00:22:46,810
+الملابسات والظرف الذي نزلت فيه الآية أو الذي ورد
+
+223
+00:22:46,810 --> 00:22:56,760
+فيه الحديث لكييساعد المجتهد للقياس عليه ولمعرفة
+
+224
+00:22:56,760 --> 00:23:03,980
+الحكم للمسألة المستجدة أخيرا في هذا الجانب أقول من
+
+225
+00:23:03,980 --> 00:23:10,180
+الشؤون أيضا أن يعرف مقاصد التشريع مقاصد التشريع
+
+226
+00:23:10,180 --> 00:23:17,670
+المتمثلة في ضروريات الخمس وأن هذه الأحكامعلى
+
+227
+00:23:17,670 --> 00:23:23,070
+اختلافها وعلى تعددها إن ما يُقصد منها تحقيق مقاصد
+
+228
+00:23:23,070 --> 00:23:28,610
+مقاصد متمثلة في الحفاظ على الدين والنفس والعرض
+
+229
+00:23:28,610 --> 00:23:35,210
+والعقل والمال هذه المقاصد الخامسة التي تصب الأحكام
+
+230
+00:23:35,210 --> 00:23:42,150
+الشرعية للحفاظ عليها لابد أن ندركها جيدا وهذا
+
+231
+00:23:42,150 --> 00:23:48,060
+المجتهدويعلم أن الحكم مهما دار ومهما اختلف لابد أن
+
+232
+00:23:48,060 --> 00:23:53,640
+يخدم مقصدا أو من هذه المقاصد أو مجموعة هذه المقاصد
+
+233
+00:23:53,640 --> 00:24:00,500
+معاه لكن إضافة إلى هذه، هذه هي الشروط الأساسية
+
+234
+00:24:00,500 --> 00:24:06,100
+الرئيسية التي يبقى تتوفر في كل مجتهد سواء في قضايا
+
+235
+00:24:06,100 --> 00:24:11,110
+المعاصرة أو غير المعاصرةلكن من أراد أن يتصدى
+
+236
+00:24:11,110 --> 00:24:15,170
+للقضايا المعاصرة فإنه لابد أن تتوفر فيه أيضًا شروط
+
+237
+00:24:15,170 --> 00:24:19,870
+إضافية أخرى لأن القضايا المعاصرة تحتاج إلى يعني
+
+238
+00:24:19,870 --> 00:24:26,050
+عمق أكثر وربما دراية أكبر ولذلك أضاف بعض العلماء
+
+239
+00:24:26,050 --> 00:24:29,970
+يعني شروطًا أخرى إضافة إلى الشروط العادية التي
+
+240
+00:24:29,970 --> 00:24:35,910
+ذكرها القدامى لابد أن تتوفر لمن يريد أن يتصدى إلى
+
+241
+00:24:35,910 --> 00:24:42,800
+هذه القواعدإلى بيان أحكام المسائل الفقهية المعاصمة
+
+242
+00:24:42,800 --> 00:24:51,040
+منها الملكة الفقهية بمعنى أنه لابد أن تتوفر في
+
+243
+00:24:51,040 --> 00:24:55,620
+المجتهد رسوخ
+
+244
+00:24:55,620 --> 00:25:03,000
+الفقه اللي لا يكون فقط حافظا لهذه الآيات وهذه
+
+245
+00:25:03,000 --> 00:25:10,150
+القواعد وهذه الحديثبل أن يصبح له .. يصبح الفقه
+
+246
+00:25:10,150 --> 00:25:15,690
+لديه سجية وتصبح لديه القدرة وتصبح لديه القدرة على
+
+247
+00:25:15,690 --> 00:25:20,890
+بيان الحكم وتصبح القدرة عنده على بيان الحكم ملكة
+
+248
+00:25:20,890 --> 00:25:28,530
+ملكة بمعنى أنه يعني يسهل عليه ذلك وهذا وتكوين هذه
+
+249
+00:25:28,530 --> 00:25:33,030
+الملكة يحتاج إلى دربة لا تتكون .. لا يولد الإنسان
+
+250
+00:25:33,030 --> 00:25:41,800
+فقيهاولكنالملكة يصبح فقيها و يصبح لديه الملكة بعد
+
+251
+00:25:41,800 --> 00:25:49,600
+أن يقود تجارب و أن يدرس الكتب و القواعد و أن يتأهل
+
+252
+00:25:49,600 --> 00:25:59,040
+لذلك يعني حتى تتحقق له الملكة و يصبح لديه الفقه و
+
+253
+00:25:59,040 --> 00:26:08,470
+بياد الحكم سجية و لا يصعب عليه بعدثم إنه أيضًا
+
+254
+00:26:08,470 --> 00:26:13,830
+لابد أن يتمتع ويتصف بسعة الأفق لأن بغي أن يكون
+
+255
+00:26:13,830 --> 00:26:18,710
+الذي يريد أن يجتهد في بيان الأحكام المعاصرة يعني
+
+256
+00:26:18,710 --> 00:26:23,590
+منغلقًا على نفسه ولا ضيق الأفق ولا جامد لابد أن
+
+257
+00:26:23,590 --> 00:26:29,530
+يكون له سعة .. سعة أفق يعني يحلل الأمور وينظر
+
+258
+00:26:29,530 --> 00:26:35,390
+إليها من جميع زواياها وينظر إلى مقالاتها ومقصدها
+
+259
+00:26:35,830 --> 00:26:42,690
+فهذا كله و يساعد على معرفة الحكم الصحيح و من هنا
+
+260
+00:26:42,690 --> 00:26:50,490
+لابد أن يتصف الفقيه و المتصدى للقضايا المعاصرة
+
+261
+00:26:50,490 --> 00:26:57,250
+بهذه الصفة و كذلك لابد أن يكون لديه دربة على
+
+262
+00:26:57,250 --> 00:27:04,570
+الفتوى يعني قبل أنقبل أن يتصدى لبيان الأحكام يبغى
+
+263
+00:27:04,570 --> 00:27:12,160
+أن يتدرب على الفتاوىال .. الفتاوى التقليدية العامة
+
+264
+00:27:12,160 --> 00:27:20,660
+من خلال مصاحبة مجتهد آخر من خلال مصاحبة العلماء
+
+265
+00:27:20,660 --> 00:27:25,600
+والتعرف على كيفية افتاءاتهم وكيفية اجتهاداتهم
+
+266
+00:27:25,600 --> 00:27:33,780
+وصاحبهم المدة التي تكفل له يعني القدرة بعد ذلك على
+
+267
+00:27:33,780 --> 00:27:40,870
+الافتاءوعلى بيان الأحكام الشرعية لابد كذلك أن يتصف
+
+268
+00:27:40,870 --> 00:27:46,690
+بالفطمة والذكاء يعني
+
+269
+00:27:46,690 --> 00:27:50,750
+القوي هناك
+
+270
+00:27:50,750 --> 00:27:56,040
+من الناس العادلينوالمتعلمين والدارسين الأحكام
+
+271
+00:27:56,040 --> 00:28:03,680
+الشرعية من تغيب عنهم يعني كثير من الجزئيات عند عرض
+
+272
+00:28:03,680 --> 00:28:08,660
+المسائل فيخطئون بعد ذلك في النتائج أو في بيان
+
+273
+00:28:08,660 --> 00:28:15,200
+الأحكام لكن من كان لديه فطنة وعقل ناقدوبصيرة ثاقبة
+
+274
+00:28:15,200 --> 00:28:20,280
+يعني فإن هذا كله يساعده في التعرف على الحكم
+
+275
+00:28:20,280 --> 00:28:26,520
+والوصول إلى الحكم مهما يعني كان هناك تشابك ومهما
+
+276
+00:28:26,520 --> 00:28:33,480
+كان هناك ضبابية فإن ذكاءه وفقنته تساعده على ذلك
+
+277
+00:28:33,480 --> 00:28:38,000
+ولذلك نحن نريد أن يكون المجتهد من الفئة الأذكياء
+
+278
+00:28:38,000 --> 00:28:43,850
+وفئة أصحاب الفقنة وليس من غير ذلك لأنهمإنما
+
+279
+00:28:43,850 --> 00:28:49,350
+يتعاملون و يبيّنون أحكام الله فإن لم يتخذ يعني
+
+280
+00:28:49,350 --> 00:28:56,950
+لبيان حكم الله سبحانه وتعالى النخبة و أصحاب
+
+281
+00:28:56,950 --> 00:29:03,600
+المستوى العالي فليه نترك هذه الشريعة؟نطرقها لغيرهم
+
+282
+00:29:03,600 --> 00:29:10,140
+هذا غير مقبول و غير جائز ثم إنه لابد كذلك أن يكون
+
+283
+00:29:10,140 --> 00:29:17,740
+لديهم معرفة بالناس و بأحوالهم و هذا من خلال
+
+284
+00:29:17,740 --> 00:29:24,140
+الاختلاط معاهم و عدم الإنعزال لا يقبل ولا يعقلأن
+
+285
+00:29:24,140 --> 00:29:28,580
+يفتي أو أن يصدر الأحكام أي المجتهد و هو في برجه
+
+286
+00:29:28,580 --> 00:29:32,940
+العاجي أو و هو في صومعته أو و هو في مسجده أو و هو
+
+287
+00:29:32,940 --> 00:29:38,180
+في مكتبته أو و هو في بيته لا بل لابد أن يتعرف على
+
+288
+00:29:38,180 --> 00:29:43,900
+الناس و يجد ما يحتاجوه و يتعرف على ما يواجههم من
+
+289
+00:29:43,900 --> 00:29:52,420
+.. من أشكالات فإن الناسيعني قد تواجههم قضايا
+
+290
+00:29:52,420 --> 00:29:59,240
+يتحرجون منها لو حُكم بها بكذا وانت مقلوب ان هذه
+
+291
+00:29:59,240 --> 00:30:03,360
+الشريعة هي شريعة رفع الحرج هذه الشريعة هي شريعة
+
+292
+00:30:03,360 --> 00:30:07,720
+التيسير فلذلك يبدأ أن تطلع على ما يؤثر على الناس
+
+293
+00:30:07,720 --> 00:30:13,540
+على ما يرفع الحرج عنهم لكيتفتي بيه خاصة إذا لم يكن
+
+294
+00:30:13,540 --> 00:30:20,300
+فيه مخالفة لنص شرعي و أقول لإن يكون هناك شيء فيه
+
+295
+00:30:20,300 --> 00:30:26,900
+مخالفة لنص شرعي و يوثب على الناس بل على العكس فإن
+
+296
+00:30:26,900 --> 00:30:32,460
+الشريعة كلها يسر و كلها رحمة و كلها عدل و كلها
+
+297
+00:30:32,460 --> 00:30:40,560
+مصلحة للناس جميعا أختم هذه المحاضرة ولعلي قد قطلته
+
+298
+00:30:40,560 --> 00:30:46,560
+أيضايعني ببيان الضوابط التي ينبغي على المجتهد
+
+299
+00:30:46,560 --> 00:30:52,720
+مراعتها بعد أن تتوفر فيه هذه الشروط وبعد أن يتأهل
+
+300
+00:30:52,720 --> 00:30:59,480
+بهذه المؤهلات ليتصدى إلى بيان الأحكام للمسائل
+
+301
+00:30:59,480 --> 00:31:05,280
+الفرخية المؤاصرة لدي ينبغي بعد ذلك كله إذا ما أراد
+
+302
+00:31:05,280 --> 00:31:11,530
+أن يقدم على البيانوأن يعالج المسألة وأن يجتهد فيها
+
+303
+00:31:11,530 --> 00:31:17,330
+عليه أن يراعي الظوابط التالية أولا أن يستفرغ ووسعه
+
+304
+00:31:17,330 --> 00:31:26,330
+في الاجتهاد لمعرفة الحكم للقضية التي تواجهه أن
+
+305
+00:31:26,330 --> 00:31:32,250
+يستفرغ ووسعه فيقلب المسألة من كل جوانبها وأن لا
+
+306
+00:31:32,250 --> 00:31:39,360
+يتصرع في إصدار الحكملعل شيئًا قد يغيب عنه أو لا
+
+307
+00:31:39,360 --> 00:31:44,720
+يراه أو لا يفطن إليه إذا تسرع عليه أن لا يتسرع
+
+308
+00:31:44,720 --> 00:31:50,260
+وعليه أن يقلب وعليه أن يستفرغ الوسعى حتى وإن احتاج
+
+309
+00:31:50,260 --> 00:31:56,040
+الأمر إلى مدارسة الأمر مرة تلو المرة وإلى مراجعة
+
+310
+00:31:56,040 --> 00:32:00,600
+آراء العلماء أو إلى مراجعة نصوص ومراجعة الأحاديث
+
+311
+00:32:00,600 --> 00:32:09,920
+إلى يوم إلى يومين فإناستفراغ الوسعى من الأمور
+
+312
+00:32:09,920 --> 00:32:16,740
+المهمة التي يبغى بل الواجب على المجتهد أن يراعيها
+
+313
+00:32:16,740 --> 00:32:21,720
+ولذلك قالوا في تعريف الاجتهاد بأنه استفراغ الوسعى
+
+314
+00:32:21,720 --> 00:32:27,500
+لا يكون المجتهد مجتهدا إلا إذا استفرغ وسعه واستفرغ
+
+315
+00:32:27,500 --> 00:32:35,450
+طاقته العقليةطاقته البحثية طاقته الاجتهادية لمعرفة
+
+316
+00:32:35,450 --> 00:32:37,890
+الحكم الأحكام الشرعية
+
+317
+00:32:41,580 --> 00:32:49,000
+وأما الضابط الثاني الذي ينبغي أن يراعيه المجتهد في
+
+318
+00:32:49,000 --> 00:32:56,700
+اجتهاده بالقضايا المعاصرة طبعا احنا قلنا انه من
+
+319
+00:32:56,700 --> 00:33:00,180
+الشهود أن يكون عالما بكتاب الله وكتاب رسول الله
+
+320
+00:33:00,180 --> 00:33:06,910
+لكن من الضابط أن لا يجتهد فيما ورد فيه مصرهو مدام
+
+321
+00:33:06,910 --> 00:33:11,630
+يعلم النصوص ويعرف النصوص، نصوص القرآن ونصوص السنة
+
+322
+00:33:11,630 --> 00:33:16,210
+فكل ما كان هناك نص من كتاب ربنا أو من سنة نبينا
+
+323
+00:33:16,210 --> 00:33:21,010
+يبين حكما واضحا، قاطعا، صريحا، فلا مجال للاجتهاد
+
+324
+00:33:21,460 --> 00:33:26,220
+فلعلم هذا تجاوز وهذا افتياط على الله ورسوله صلى
+
+325
+00:33:26,220 --> 00:33:30,920
+الله عليه وسلم ما ينبغي لأحد كائن من كان أن يشتهد
+
+326
+00:33:30,920 --> 00:33:35,580
+في مسألة بينها ربنا سبحانه وتعالى، بماذا تريد أن
+
+327
+00:33:35,580 --> 00:33:41,520
+تأتي بعد بيان الله سبحانه وتعالى؟ وهل بعد الهدى
+
+328
+00:33:41,520 --> 00:33:48,070
+إلا الضلال؟ فلذلك يعني عليه أنيبتعد عن الاجتهاد أن
+
+329
+00:33:48,070 --> 00:33:53,090
+يتجنب الاجتهاد فيما ورد فيه نص قاطع أقول نص قاطع
+
+330
+00:33:53,090 --> 00:33:57,890
+وهذا ما قصده العلماء عندما قالوا لاجتهادة مع النص
+
+331
+00:33:57,890 --> 00:34:02,790
+لاجتهادة مع النص القاطع الدال دلالة واضحة وصريحة
+
+332
+00:34:02,790 --> 00:34:09,530
+وقاطعة على الحكم الشرعي لأنه .. لأن الاجتهادة يكون
+
+333
+00:34:09,530 --> 00:34:17,730
+عبثيا بل يكون محرمافي هذه الحالة ثم ان هناك ضراب
+
+334
+00:34:17,730 --> 00:34:23,810
+الثالث وهو مراعاة الأعراف أعراف الناس وعادات الناس
+
+335
+00:34:23,810 --> 00:34:29,690
+عند إصداره أو قبل إصداره للحكم كثير من الأحكام
+
+336
+00:34:29,690 --> 00:34:34,670
+الشرعية مبنية على الأعراف وعلى العادات والعرفه في
+
+337
+00:34:34,670 --> 00:34:42,010
+الشرع له اعتبار وعليه حكمه قد يداروربنا سبحانه
+
+338
+00:34:42,010 --> 00:34:50,990
+وتعالى أشار في كتابه العزيز إلى ضرورة مراعاة العرف
+
+339
+00:34:50,990 --> 00:35:04,160
+واتباره ضابط من الضوابط الشرعيةالتي ينبغي للمجتهد
+
+340
+00:35:04,160 --> 00:35:13,160
+أن يراعيها فلا يعقل أن تحكمها خاصة مرة أخرى أقول
+
+341
+00:35:13,160 --> 00:35:19,380
+إذا كان هذا العرف لا يناقض ولا يخالف حكما شريعيا
+
+342
+00:35:19,380 --> 00:35:28,320
+أو نصا شريعيا في كتاب ربنا أو في سنة نبينا ذلك أن
+
+343
+00:35:28,320 --> 00:35:35,430
+هذه الأعرافما وجدتما تولدت في مجتمع من المجتمعات
+
+344
+00:35:35,430 --> 00:35:46,230
+أو في أمة من الأمم إلا بناء على تراكم متواصل
+
+345
+00:35:46,230 --> 00:35:50,630
+يحقق للناس المصلحة ما يتعرف الناس على شيء في العام
+
+346
+00:35:50,630 --> 00:35:56,010
+الأغلب إلا فيما يظن أن فيه مصلحة ولذلك الإسلام
+
+347
+00:35:56,010 --> 00:35:59,930
+يراعي على عراف الناس لأنها في الغالب تراعي مصالحهم
+
+348
+00:36:00,170 --> 00:36:03,870
+إلا إذا تعرفوا على شيء يعني مخالف للشريعة وهذا
+
+349
+00:36:03,870 --> 00:36:09,630
+عمره نادر ولكن إذا وقع ترفضه الشريعة وهناك يعني من
+
+350
+00:36:09,630 --> 00:36:17,910
+الأنفلة يعني على يعني ذلك لكن هذه هي القاعدة
+
+351
+00:36:17,910 --> 00:36:25,390
+العامة في هذا الأمر ثم أيضا لابد من مراعاة
+
+352
+00:36:25,390 --> 00:36:32,730
+الضروريات والحاجيات ضروريات والحاجياتالناسيعني
+
+353
+00:36:32,730 --> 00:36:38,210
+يعيشون في أحوال طبيعية لكن في أحوال معينة ربما
+
+354
+00:36:38,210 --> 00:36:45,050
+يمرون بضائقة ربما يمرون بظروف خاصة يضطرون إلى
+
+355
+00:36:45,050 --> 00:36:50,330
+أحكام استثنائية في هذه الحالة يعني الميتة تحرم
+
+356
+00:36:50,330 --> 00:36:55,810
+أكلها في الأحوال العادية و الطبيعية لكن من انقطع
+
+357
+00:36:55,810 --> 00:37:02,620
+في صحراء أو في حرب أو في سجن فلم يجد إلا ميتةهل
+
+358
+00:37:02,620 --> 00:37:09,020
+يبقى الحكم هو هو؟ لا، بل إن الحكم يتغير بناء على
+
+359
+00:37:09,020 --> 00:37:13,440
+الضرورة، بناء على الضرورة، فمن الضرر غير باغن ولا
+
+360
+00:37:13,440 --> 00:37:17,240
+عادل فلا إثم عليه، والضرورات تبيح المحظورات
+
+361
+00:37:20,020 --> 00:37:26,020
+فلذلك يختلف الحكم فيباحوا له أكل ميت في هذه الحالة
+
+362
+00:37:26,020 --> 00:37:31,400
+حفاظا على روحه يباحوا للمسلم حتى أن ينطق بكلمة
+
+363
+00:37:31,400 --> 00:37:38,680
+الكفر إذا كان في ذلك نجاتا له من الكفار مادما قلبه
+
+364
+00:37:38,680 --> 00:37:45,020
+مطمئنا بالإيمانفهذا أيضًا مع أن الانسان في حال
+
+365
+00:37:45,020 --> 00:37:47,840
+الأحوال العادية لا يحق له بحال .. بأي حال من
+
+366
+00:37:47,840 --> 00:37:53,780
+الأحوال أن يمطق أو أن يتلفظ بلفظة الكفر هذه الأمور
+
+367
+00:37:53,780 --> 00:37:58,460
+لابد من مراعاتها فكل ما مرت الأمة أو مرة فرد أو
+
+368
+00:37:58,460 --> 00:38:06,060
+مرت جماعة .. مجموعة من الناس بضرورة فلابد
+
+369
+00:38:06,060 --> 00:38:13,120
+أن يكون الحكم يناسبهذه الضرورة وربما بما يحافظوا
+
+370
+00:38:13,120 --> 00:38:19,380
+عليها وحتى الحاجةوالحاجة فهذه الحاجة التي أقل درجة
+
+371
+00:38:19,380 --> 00:38:24,400
+من الضرورة وإذا لم نراعها يقع الناس في حرج شديد
+
+372
+00:38:24,400 --> 00:38:30,860
+الضرورة التي إذا لم تراعها أوصلتك إلى الهلاء لكن
+
+373
+00:38:30,860 --> 00:38:35,640
+الحاجة إذا لم تراعها وأوقعتك في الحرج الشديد حتى
+
+374
+00:38:35,640 --> 00:38:41,500
+هذا لا يقبله ربنا ولا ترضاه شريعتنا فشريعتنا تدفع
+
+375
+00:38:41,500 --> 00:38:46,370
+الحرج عننا وإذا لذلك إذا كانت الحاجةللمجتمع أو
+
+376
+00:38:46,370 --> 00:38:51,370
+لأمة من الأمم تسبب
+
+377
+00:38:51,370 --> 00:38:57,530
+حرجا فإنها تنزل منزلة الضرورة ويتغير
+
+378
+00:38:57,780 --> 00:39:07,260
+الحكم في هذه الحالة ويصبح ربما الحرام حلالا وربما
+
+379
+00:39:07,260 --> 00:39:13,500
+هذا يعبر عنه بعض العلماء بما يعرف بعموم البلوة إذا
+
+380
+00:39:13,500 --> 00:39:18,410
+ابتلي الناس بشيء فيهيعني من الشبهات وكان الأصل أن
+
+381
+00:39:18,410 --> 00:39:26,530
+يعني يتجنبوه وفق الشريعة لكن يعني ابتلي الناس به
+
+382
+00:39:26,530 --> 00:39:32,590
+لظرف ما وإن لم يفعلوه وقعوا في حرج شديد اليوم مثلا
+
+383
+00:39:32,590 --> 00:39:40,330
+انظروا بعض شركات الكهرباء تلزم الناسفي حال تأخرهم
+
+384
+00:39:40,330 --> 00:39:44,230
+عن الدفع بغرامات
+
+385
+00:39:44,230 --> 00:39:50,470
+مالية هي أشبه بالربح وفيها الظاهر أن هذا محرم
+
+386
+00:39:50,470 --> 00:40:02,470
+وبالتالي هل نقول بعد ذلك بحرمة مد خطوط الكهرباء أو
+
+387
+00:40:02,470 --> 00:40:06,890
+الاشتراك مع هذه الشركات إن هذا يقع الناس في حرج
+
+388
+00:40:06,890 --> 00:40:13,890
+شديدولذلك رغم ذلك فإن الناس فإن العلماء يعني
+
+389
+00:40:13,890 --> 00:40:21,210
+أجازوا أجازوا التواصل والاشتراك مع هذه الشركات
+
+390
+00:40:21,210 --> 00:40:25,210
+الشركات الكهرباء رغم أنها ربما تلزم الناس أحيانا
+
+391
+00:40:25,210 --> 00:40:30,070
+بتفعيل غرامات مالية التي أشبه ما تكون بالربع لأنها
+
+392
+00:40:30,070 --> 00:40:33,450
+لو لم تفعل لأن المجتهدين لو لم يفعلوا ذلك ولو لم
+
+393
+00:40:33,450 --> 00:40:39,250
+يجيزوا ذلك لواقع الناسفي حرج شديد والحاجة تتنزل
+
+394
+00:40:39,250 --> 00:40:45,830
+منزلة الضرورة والضرورة تبيح المحضورات وهكذا لابد
+
+395
+00:40:45,830 --> 00:40:51,310
+بمعنى أخر لابد للمجتهد أن يراعي ضرورات الناس
+
+396
+00:40:51,310 --> 00:40:56,310
+وحاجياتهم بما الشريعة تريد للناس أن يهنأوا في
+
+397
+00:40:56,310 --> 00:41:00,690
+حياتهم تريد للناس أن يستقروا في حياتهم لا تريد لهم
+
+398
+00:41:00,690 --> 00:41:07,920
+نكدا ولا تريد لهم حرجاولا تريد لهم ضيقابل تريدوا
+
+399
+00:41:07,920 --> 00:41:16,560
+أن توسع عليهم في كل حال كذلك الحال لابد من مراعاة
+
+400
+00:41:16,560 --> 00:41:21,500
+المصالح لابد من مراعاة المصالح، مصالح الناس
+
+401
+00:41:21,500 --> 00:41:25,940
+وتجنبهم
+
+402
+00:41:25,940 --> 00:41:32,000
+للمفاسق وهذا كنا قد تحدثنا عنه يعني مرارا وكذلك
+
+403
+00:41:32,000 --> 00:41:37,120
+لابد من مراعاة أحوال التطور التي تمر بها المجتمع
+
+404
+00:41:37,230 --> 00:41:43,330
+ومجاراتها اليوم الناس كل يوم تطور جديد اليوم الناس
+
+405
+00:41:43,330 --> 00:41:48,190
+تعملون عبر الكمبيوتر والإنترنت والفيسبوك لماذا لا
+
+406
+00:41:48,190 --> 00:41:53,910
+تراء هذه الأمور؟ لماذا لا تكون هناك تجرأ لا يوافق؟
+
+407
+00:41:53,910 --> 00:41:59,610
+لماذا لا يحكم بجواز إجراء المعاملات المالية وفق
+
+408
+00:41:59,610 --> 00:42:05,530
+يعني وسائل الإتصال الحديثة؟مثلا لابد ان مراعاة كل
+
+409
+00:42:05,530 --> 00:42:10,590
+ذلك إذا كان يوفر جهدا و يوفر وقتا ولا يخالف نصا او
+
+410
+00:42:10,590 --> 00:42:17,590
+لا يخالف حكما شريعيا ولكن يعني و نحن نقول بمراعاة
+
+411
+00:42:17,590 --> 00:42:25,580
+أحوالالتطور ولابد أن نحضرها من شيء مهم وهو الوقوع
+
+412
+00:42:25,580 --> 00:42:34,660
+تحت ضغط الواقع فإننا مهما كان هناك من تطور فإنه لا
+
+413
+00:42:34,660 --> 00:42:42,780
+يجوز لنا كمجتهدين أو كعلماء أن نبيحلهذا التطور أو
+
+414
+00:42:42,780 --> 00:42:47,620
+بالسبب هذا التطور النبيح ما حرم الله سبحانه وتعالى
+
+415
+00:42:47,620 --> 00:42:53,800
+بلا ضرورة أو بلا حاجة من الحاجيات التي تنزل منزلة
+
+416
+00:42:53,800 --> 00:43:01,460
+الضوء هذه مجمل الشروط الأساسية والاضغفيةوالضوابط
+
+417
+00:43:01,460 --> 00:43:05,980
+التي ينبغي مراعتها اكتفي بهذا القدر ان شاء الله
+
+418
+00:43:05,980 --> 00:43:11,500
+وإلى لقاء آخر يا جماعنا باذن الله سبحانه وتعالى
+
+419
+00:43:11,500 --> 00:43:14,620
+السلام عليكم ورحمة الله وبركاته
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/PDx3-THOYsE.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/PDx3-THOYsE.srt
new file mode 100644
index 0000000000000000000000000000000000000000..aacfb5af077fc7e9ff3af1dcdcf2b2a23a52da88
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/PDx3-THOYsE.srt
@@ -0,0 +1,1592 @@
+1
+00:00:00,000 --> 00:00:00,140
+موسيقى
+
+2
+00:00:20,670 --> 00:00:25,330
+بسم الله الرحمن الرحيم الحمد لله والصلاة والسلام 
+
+3
+00:00:25,330 --> 00:00:30,550
+على رسول الله وعلى آله وصحبه  أن نقتدأ بهديه ونستنى
+
+4
+00:00:30,550 --> 00:00:36,050
+بسنته ليوم الدين، وبعض الأخوات الكريمات نواصل 
+
+5
+00:00:36,050 --> 00:00:45,450
+حديثنا الذي كنا قد بدأنا به وهو حكم وبيان مشروعية 
+
+6
+00:00:45,450 --> 00:00:48,950
+بيان
+
+7
+00:00:48,950 --> 00:00:57,980
+مشروعية إجراء العقود عبر وسائل الاتصال الحديثة كنا 
+
+8
+00:00:57,980 --> 00:01:03,380
+في المحاضرة السابقة قد تحدثنا بإجمال حول بعض 
+
+9
+00:01:03,380 --> 00:01:08,560
+المقدمات المتعلقة بموقف الشريعة الإسلامية وموقف 
+
+10
+00:01:08,560 --> 00:01:16,030
+الإسلام من التطور ومن العلم ومن تحقيق المصالح و
+
+11
+00:01:16,030 --> 00:01:19,810
+التيسير على الناس، وقلنا بأن الإسلام منذ اللحظة 
+
+12
+00:01:19,810 --> 00:01:25,550
+الأولى قد جاء لتحقيق مصالح الناس ولتيسير عليهم و
+
+13
+00:01:25,550 --> 00:01:31,490
+لدفع الحرج عنهم، و لدفعهم إلى الأخذ بأسباب التطور و
+
+14
+00:01:31,490 --> 00:01:40,650
+الارتقاء والاستفادة من كل ما هو جديد، وبالتالي 
+
+15
+00:01:40,650 --> 00:01:47,730
+فعندما يصل الإنسان إلى مراحل متطورة فيما يتعلق 
+
+16
+00:01:47,730 --> 00:01:53,130
+بوسائل التواصل، فمن الطبيعي أن يعمل الإسلام أن يكون 
+
+17
+00:01:53,130 --> 00:01:58,970
+موقف الإسلام في التعاطي والاستفادة من هذه الوسائل بما 
+
+18
+00:01:58,970 --> 00:02:04,750
+يحقق مصالح الناس، وبما يحقق ويوفروا لهم الجهد 
+
+19
+00:02:04,750 --> 00:02:10,370
+والوقت، فالإسلام لا يمانع من هذا كله، وقد فهمنا من 
+
+20
+00:02:10,370 --> 00:02:15,810
+هذه المقدمة أن الشريعة الإسلامية من حيث الجملة لا 
+
+21
+00:02:15,810 --> 00:02:23,510
+تمانع من أن تتم التوافقات أو الاتفاقات والتعاقدات 
+
+22
+00:02:23,510 --> 00:02:29,510
+عبر وسائل الاتصال الحديثة، لكن هذا من حيث الجملة 
+
+23
+00:02:29,510 --> 00:02:36,150
+تُمت تفاصيل ربما تحتاجوا إلى توضيح، ربما تكون هذه 
+
+24
+00:02:36,150 --> 00:02:41,610
+التعاقدات عبر هذه الاتصالات الحديثة تحتاج إلى 
+
+25
+00:02:41,610 --> 00:02:47,310
+بعض القيود وضبط الضوابط كي تتحقق الأركان العامة 
+
+26
+00:02:47,310 --> 00:02:51,610
+والشروط العامة التي ينبغي... والتي تعرف عليها
+
+27
+00:02:51,610 --> 00:02:56,470
+الفقهاء وبينها الفقهاء لنا يعني قديماً في كتبهم 
+
+28
+00:02:56,470 --> 00:03:02,710
+الفقهية المعروفة، ولذلك اقتضى منا الأمر أن نتحدث 
+
+29
+00:03:02,710 --> 00:03:08,250
+باختصار عن العقد وأركانه وبعض ما يتعلق به من 
+
+30
+00:03:08,250 --> 00:03:14,430
+شروط، وقد تحدثنا بالفعل عن العقد وتعريفه بالمعنى
+
+31
+00:03:14,430 --> 00:03:18,990
+اللغوي وبالمعنى الاصطلاحي، وذكرنا أن للعقد له 
+
+32
+00:03:18,990 --> 00:03:23,790
+معنيان، بالمعنى العام يشمل كل التزام ينشأ عن إرادة 
+
+33
+00:03:23,790 --> 00:03:27,030
+واحدة أو عن إرادتين، وبالمعنى الخاص وهو ذلك
+
+34
+00:03:27,030 --> 00:03:32,060
+الالتزام الذي ينشأ عنه يعني أثر شرعي عن توافق 
+
+35
+00:03:32,060 --> 00:03:35,520
+إرادتين، عن توافق إرادتين، هذا هو المعنى المقصود 
+
+36
+00:03:35,520 --> 00:03:39,800
+للفقهاء، والمقصود لنا ونحن نتحدث عن التعاقد عبر 
+
+37
+00:03:39,800 --> 00:03:44,520
+وسائل الاتصال الحديث، لا نقصد تلكم التعاقدات التي 
+
+38
+00:03:44,520 --> 00:03:51,390
+تنشأ عن التزام فردي من وصية أو هبة أو أمثال ذلك أو
+
+39
+00:03:51,390 --> 00:03:56,590
+وقف أو حتى طلاق أو غير ذلك، وإنما نقصد التعاقدات 
+
+40
+00:03:56,590 --> 00:04:01,870
+التي تحدث بين اثنين، ويكون فيها بينهما إيجاب وقبول 
+
+41
+00:04:01,870 --> 00:04:06,550
+أو بينهما تبادل، فهذا يقدم السلعة وهذا يأخذ الثمن 
+
+42
+00:04:06,550 --> 00:04:11,050
+وإلى غير ذلك، هذا ما نقصده عندما نتحدث عن العقود 
+
+43
+00:04:11,050 --> 00:04:17,790
+وإجراءها بوسائل الاتصال الحديثة، وحديثنا عن العقد 
+
+44
+00:04:17,790 --> 00:04:28,050
+وبعض ما يتعلق به من مسائل هو من باب التسهيل لمعرفة 
+
+45
+00:04:28,050 --> 00:04:33,250
+حكم إجراء العقود عبر وسائل الاتصال الحديثة، ذلك أن 
+
+46
+00:04:33,250 --> 00:04:38,170
+معرفتنا بطبيعة العقد وأركانه التي وضعها الفقهاء 
+
+47
+00:04:38,170 --> 00:04:44,730
+والشروط كذلك يسهل علينا معرفة حكم إجراء العقود عبر 
+
+48
+00:04:44,730 --> 00:04:48,950
+وسائل الاتصال الحديثة، ولذلك بعد حديثنا عن العقد
+
+49
+00:04:48,950 --> 00:04:58,820
+تحدثنا عن أركان العقد، ووجدنا أنه ثمة نظريتان في ال
+
+50
+00:04:58,820 --> 00:05:03,740
+... ال... ال... في... لل... للعقدي أو نظريتان ل...
+
+51
+00:05:03,740 --> 00:05:07,360
+ل... ل... للحديث عن أركان أو ل... ل... لأركان
+
+52
+00:05:07,360 --> 00:05:11,500
+العقد بين بعض، والبعض يرى كالحنفية أن العقد له ركن 
+
+53
+00:05:11,500 --> 00:05:17,630
+واحد، والجمهور يرى أنه ثمة ثلاثة أركان، وحاولنا أن 
+
+54
+00:05:17,630 --> 00:05:23,850
+نقرب... يعني ال... نقرب وجهات النظر بين الرأيين
+
+55
+00:05:23,850 --> 00:05:28,810
+على اعتبار أنه... أن من قال بأن العقد له ركن واحد 
+
+56
+00:05:28,810 --> 00:05:35,330
+إن لا... لا ينكر ولا يتجاهل أن ثمَّ عنصرين...
+
+57
+00:05:35,330 --> 00:05:41,410
+عنصرين آخرين هما المتعاقدين ومحل العقد، لكنه لا 
+
+58
+00:05:41,410 --> 00:05:46,630
+يسميهم ببساطة شديدة أركانًا، على اعتبار أنهم يعني من 
+
+59
+00:05:46,630 --> 00:05:52,310
+لوازم الصيغة أو من لوازم الركن الأول وهو الصيغة 
+
+60
+00:05:52,310 --> 00:05:58,980
+فلا صيغة بدون عاقدين، ولا صيغة لها فائدة أيضًا بدون 
+
+61
+00:05:58,980 --> 00:06:07,540
+شيء يتم التعاقد عليه ويتم الحديث عنه، ولذلك كان 
+
+62
+00:06:07,540 --> 00:06:14,020
+الركن الأساسي هو الصيغة، ومن خلال هذه النقطة
+
+63
+00:06:14,020 --> 00:06:19,220
+انطلقنا للحديث عن معنى الصيغة أو عناصر الصيغة 
+
+64
+00:06:19,220 --> 00:06:23,910
+الصيغة التي تتكون من الإيجاب والقبول، والإيجاب هو 
+
+65
+00:06:23,910 --> 00:06:28,250
+الذي يصدره أولاً، والقبول هو الذي يصدره ثانيًا وفق 
+
+66
+00:06:28,250 --> 00:06:33,590
+نظرية الحدثية وهو ما يصدره من المالك أو صاحب 
+
+67
+00:06:33,590 --> 00:06:39,870
+الملك أي الإيجاب وفق نظرية الجمهور، والقبول ما 
+
+68
+00:06:39,870 --> 00:06:43,250
+يصدره من المتملك أو من تنتقل إليه
+
+69
+00:06:45,900 --> 00:06:50,140
+السلعة، وعلى أي حال قلنا أن الخلاف يبدو أو يكاد 
+
+70
+00:06:50,140 --> 00:06:53,920
+يكون شكليًا لولا يعني بعض الجزئيات البسيطة التي 
+
+71
+00:06:53,920 --> 00:06:59,700
+تتمثل في أن أحيانًا يعني إذا ما كان المبتدئ بالحديث 
+
+72
+00:06:59,700 --> 00:07:04,460
+هو يعني الطرف المتكلم بمعنى هو الذي صدر منه الكلام 
+
+73
+00:07:04,460 --> 00:07:09,240
+أولاً على رأي الجمهور فإنه لابد لتمام العقد أنه بعد 
+
+74
+00:07:09,240 --> 00:07:14,340
+أن ينطق الكلام من المالك أن يعود المتملك مرة أخرى
+
+75
+00:07:14,340 --> 00:07:21,160
+ليوافق، وذلك بخلاف الحنفية فإنه مكتفى فقط بكلام من 
+
+76
+00:07:21,160 --> 00:07:26,510
+طرفين، حتى وإن كان البادئ بالكلام هو إيه... هو المتملك 
+
+77
+00:07:26,510 --> 00:07:32,090
+ربما هذه... ربما ثمرة الخلاف في ذلك، لكن يعني ممكن 
+
+78
+00:07:32,090 --> 00:07:39,710
+تضيق دائرة الاختلاف وحتى لو بدأ المتملك بالكلام
+
+79
+00:07:39,710 --> 00:07:47,110
+أولاً، ثم وافق بعد ذلك صاحب الملك فيمكن بأي يعني
+
+80
+00:07:47,110 --> 00:07:51,290
+فعل من الأفعال الصادرة من المتملك الدالة عن القبول 
+
+81
+00:07:51,290 --> 00:07:56,510
+يمكن أن يسد مسد القبول الثاني مرة أخرى، وبذلك تضيق 
+
+82
+00:07:56,510 --> 00:08:02,090
+إلى حد كبير دائرة الخلاف بين نظريتي الحدثية 
+
+83
+00:08:02,090 --> 00:08:07,350
+والجمهور في مفهوم الإيجاب والقبول، وحقيقة لا يبدو 
+
+84
+00:08:07,350 --> 00:08:14,540
+أي أثر قليل أو يعني صغر أو كبر في هذا بين النظريتين 
+
+85
+00:08:14,540 --> 00:08:20,230
+إذا كان البادئ بالكلام هو ما قال المتملك فإنه في
+
+86
+00:08:20,230 --> 00:08:24,770
+كلتا الحالتين، ووفق كلتا النظريتين يعني لا خلافة في 
+
+87
+00:08:24,770 --> 00:08:33,670
+هذه الحالة، ثم إن هذا... هذه الصيغة وبعنصريها 
+
+88
+00:08:33,670 --> 00:08:39,850
+الرئيسين قلنا ليه؟ كي ينعقد بها العقد، لأن الصيغة 
+
+89
+00:08:39,850 --> 00:08:43,730
+هي الركيزة الأساسية والركن الأساسي الذي ينعقد بها
+
+90
+00:08:43,730 --> 00:08:47,300
+العقد لابد أن تتوفر فيها شروط اللي هي الإيجاب
+
+91
+00:08:47,300 --> 00:08:51,880
+والقبول، يعني الصيغة تعني إيجاب وقبول وبهم يتم 
+
+92
+00:08:51,880 --> 00:08:56,960
+العقد، لكن إنما يتم بهم العقد إذا تحققت ثلاثة شروط 
+
+93
+00:08:56,960 --> 00:09:01,880
+وهو ما وقفنا عنده المرة الماضية، الشرط الأول الوضوح 
+
+94
+00:09:02,140 --> 00:09:08,060
+وضوح صيغة الإيجاب ووضوح صيغة القبول، بمعنى بسيط أن 
+
+95
+00:09:08,060 --> 00:09:13,940
+تكون الصيغة مفهومة، والمضمون فيها واضح ومفهوم لدى 
+
+96
+00:09:13,940 --> 00:09:22,060
+الطرف الآخر، أن يفهم كل طرف مضمون ما تحدث به الطرف
+
+97
+00:09:22,060 --> 00:09:27,940
+الآخر، حتى لو كان بأي لغة، مش بالضرورة يعني اللغة
+
+98
+00:09:27,940 --> 00:09:32,200
+العربية أو غيرها، بقى المهم أن يكون الكلام واضحًا،
+
+99
+00:09:32,200 --> 00:09:38,200
+فلا يعقل أن تكون الصيغة فيها غموم، ذلك أنه إنما 
+
+100
+00:09:38,200 --> 00:09:43,400
+كانت الصيغة للاستدلال عن ذلك الشيء الغامض، ألا وهو
+
+101
+00:09:43,400 --> 00:09:47,830
+الرضا الذي هو أمر خفي في النفس، فلا يعقل أن تبقى 
+
+102
+00:09:47,830 --> 00:09:53,450
+غامضة، لأن أنا إنما جعلته من الصيغة دليلًا على ما هو 
+
+103
+00:09:53,450 --> 00:09:57,930
+غامض وعلى ما هو خفي، فلذلك لابد أن تكون هذه الصيغة 
+
+104
+00:09:57,930 --> 00:10:04,870
+واضحة يعني يفهمها الطرفان لكي يعلمها على ما يتفقان
+
+105
+00:10:04,870 --> 00:10:10,110
+يعلمها لكي يعلمها ما يتفقان، ما الذي يتفقان عليه إذا 
+
+106
+00:10:10,110 --> 00:10:18,540
+هذا أولاً، وثانيًا ل... يعني أن يكون... أن يكون هناك توافق 
+
+107
+00:10:18,540 --> 00:10:22,320
+بين الإيجاب
+
+108
+00:10:22,320 --> 00:10:30,020
+والقبول، أو توافق القبول مع الإيجاب، ذلك أنه لا يكفي
+
+109
+00:10:30,020 --> 00:10:38,780
+... لا يكفي وضوح الصيغة يكون هناك توافق تطابق بين 
+
+110
+00:10:38,780 --> 00:10:46,740
+القبول وبين الإيجاب، فلا يقبل أن يكون الإيجاب مثلًا 
+
+111
+00:10:46,740 --> 00:10:52,880
+ببيع شيء بثمن معين بألف دينار، فتقوم ويكون القبول 
+
+112
+00:10:52,880 --> 00:10:58,780
+بثمن مائة، مع الوضوح هذا واضح ومفهوم لكل من الطرفين
+
+113
+00:10:58,780 --> 00:11:02,580
+لكن لم يكن هناك توافق لم ينعقد العقد ولم تتم 
+
+114
+00:11:02,580 --> 00:11:09,620
+الصيغة، وبالتالي يعني لا قيمة ولا قبارة ولا فرحانة 
+
+115
+00:11:19,500 --> 00:11:21,800
+Fail .. fail .. fail .. fail .. fail .. fail ..
+
+116
+00:11:21,800 --> 00:11:26,980
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+117
+00:11:26,980 --> 00:11:28,060
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+118
+00:11:28,060 --> 00:11:28,180
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+119
+00:11:28,180 --> 00:11:28,200
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+120
+00:11:28,200 --> 00:11:28,280
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+121
+00:11:28,280 --> 00:11:28,760
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+122
+00:11:28,760 --> 00:11:28,820
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+123
+00:11:28,820 --> 00:11:30,140
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+124
+00:11:30,140 --> 00:11:30,180
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+125
+00:11:30,180 --> 00:11:30,900
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+126
+00:11:30,900 --> 00:11:31,860
+fail .. fail .. fail .. fail .. fail .. fail ..
+
+127
+00:11:31,860 --> 00:11:36,680
+fail .. fail .. 
+
+128
+00:11:36,680 --> 00:11:45,840
+fail .. fail أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+129
+00:11:45,840 --> 00:11:47,760
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+130
+00:11:47,760 --> 00:11:48,120
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+131
+00:11:48,120 --> 00:11:49,680
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+132
+00:11:49,680 --> 00:11:50,840
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+133
+00:11:50,840 --> 00:11:51,240
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+134
+00:11:51,240 --> 00:11:51,600
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+135
+00:11:51,600 --> 00:11:51,740
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+136
+00:11:51,740 --> 00:11:53,000
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. أنا
+
+137
+00:11:53,000 --> 00:12:02,560
+.. أنا .. أنا .. أنا .. أنا .. أنا .. أنا .. 
+
+138
+00:12:02,560 --> 00:12:07,060
+أنا .. أنا
+
+139
+00:12:13,630 --> 00:12:21,690
+ألا يتم بعد إيجاب يعني مثلًا انفصال حقيقي أو مكاني
+
+140
+00:12:21,690 --> 00:12:27,250
+بخروج أحدهما من المكان قبل موافقة الآخر، كل هذا 
+
+141
+00:12:27,250 --> 00:12:32,010
+الذي قلت هو عبارة عن أشكال من أشكال الانفصال الذي 
+
+142
+00:12:32,010 --> 00:12:39,370
+ينتقض به الاتصال، فالاتصال إذا يعني بعد الوضوح وبعد 
+
+143
+00:12:39,370 --> 00:12:44,970
+التوافق لابد أن يكون الإيجاب والقبول متصلين بمع
+
+144
+00:12:44,970 --> 00:12:48,930
+بعضهم البعض، وعندما نقول متصلين أو اشتراط الاتصال
+
+145
+00:12:48,930 --> 00:12:54,790
+لا نقصد هنا بالضرورة أن يكون الفورية التي تعني أنه 
+
+146
+00:12:54,790 --> 00:13:00,790
+بمجرد النطق بالإيجاب أن يكون هناك نطقه بالقبول، وإنما 
+
+147
+00:13:00,790 --> 00:13:08,570
+نعني أن يكون الإيجاب والقبول في المجلس نفسه، وأن لا 
+
+148
+00:13:08,570 --> 00:13:16,030
+يكون هناك تفرق حكمين ولا حقيقين في المجلس حتى يتم
+
+149
+00:13:16,030 --> 00:13:24,950
+التوافق أو يتم الاختلاف والإعراض والتوقف عن البيع
+
+150
+00:13:24,950 --> 00:13:31,030
+أو عن الشراء أو عن التعاقد، فالمجلس مادام منعقدًا 
+
+151
+00:13:31,030 --> 00:13:39,210
+يعني أن هناك اتصال، مادام المجلس هو مظلة وعلامة
+
+152
+00:13:39,460 --> 00:13:46,600
+وجود الاتصال بين الإيجاب والقبول، فإذا خرج أحدهما 
+
+153
+00:13:46,600 --> 00:13:52,900
+انفك الاتصال وانفك المجلس، فإذا تخلل لكلام أجنبي 
+
+154
+00:13:52,900 --> 00:13:58,340
+انفك الاتصال وانفك المجلس، مجلس العقد، وربما يبقى 
+
+155
+00:13:58,340 --> 00:14:04,120
+المجلس مجلس حديث بينهما، ولكن مجلس العقد ينفك، أنا 
+
+156
+00:14:04,120 --> 00:14:10,470
+جئت لصديق ليه في الدكان... دكانه أو حانوته وأردت أن 
+
+157
+00:14:10,470 --> 00:14:15,530
+أشتري منه جلبابًا أو جلبيه أو بدلة أو طميصًا أو إلى
+
+158
+00:14:15,530 --> 00:14:21,410
+غير ذلك، فلم يعجبني السعر ولم نتوافق وظللنا في 
+
+159
+00:14:21,410 --> 00:14:27,360
+المجلس وبدأنا نتحدث بكلام عن الأسرة وعن الحال 
+
+160
+00:14:27,360 --> 00:14:31,680
+للمجتمع الفلسطيني أو العربي المأساوي اللي بيصير 
+
+161
+00:14:31,680 --> 00:14:37,500
+فهذا كله عبارة عن أيش؟ عبارة عن دليل على انفصال
+
+162
+00:14:37,500 --> 00:14:44,890
+الإيجاب عن القبول وانقطاع المجلس، لم يعود مع إن أنا 
+
+163
+00:14:44,890 --> 00:14:49,930
+في مجلس حقيقة، إذا المجلس إنما في انعقاده له معنى 
+
+164
+00:14:49,930 --> 00:14:53,110
+أكبر من المعنى اللي كان أكبر من إن أنا قاعد وأنا
+
+165
+00:14:53,110 --> 00:14:58,640
+وياك في مجلس، لأ المجلس هذا مجلس عقد يدوروا فيه أمور 
+
+166
+00:14:58,640 --> 00:15:05,420
+تتعلق بالتعاقد حول سلعة معينة، فطالما نجلس معًا 
+
+167
+00:15:05,420 --> 00:15:11,900
+وطالما نتحدث حول ذلك الأمر أي هذه السلعة، وطالما 
+
+168
+00:15:11,900 --> 00:15:17,240
+الفترة التي بين الإيجاب والقبول ليست طويلة فيما عهد
+
+169
+00:15:17,240 --> 00:15:21,440
+في العرف فالمجلس قائم، لكن اللي لم يكن الأمر كذلك 
+
+170
+00:15:21,440 --> 00:15:30,120
+فالمجلس قد انفصل أو قد انفك وانفرط وأصبح كله واحد 
+
+171
+00:15:30,120 --> 00:15:37,510
+مننا بالخيار البيعان بالخيار ما لم يتفرق... ما لم
+
+172
+
+201
+00:18:41,290 --> 00:18:48,130
+عن بعضهم البعض البعيدين عن بعضهم البعض فهل .. ليه؟
+
+202
+00:18:48,130 --> 00:18:56,440
+فهل أجازة الشريعة وأجازة الفقهاء التعاقد بين
+
+203
+00:18:56,440 --> 00:19:04,940
+الغائبين الجواب نعم الجواب نعم ليبقى السؤال مرة
+
+204
+00:19:04,940 --> 00:19:12,260
+أخرى قائم إذا ندم الأمر كذلك إذا كان التعاقد 
+
+205
+00:19:14,320 --> 00:19:20,800
+بين الغائبين جائز، كيف يكون انعقاد المجلس؟ احنا
+
+206
+00:19:20,800 --> 00:19:23,540
+بيهمنا انعقاد المجلس لأن انعقاد المجلس يا أخوات
+
+207
+00:19:23,540 --> 00:19:28,860
+بتتعلق عليه أحكام، خيار الرؤية وخيار الشرط، هذه
+
+208
+00:19:28,860 --> 00:19:36,270
+خيارات متعلقة كيف هيتم ولا يسقط كل ذلك يعني يصح
+
+209
+00:19:36,270 --> 00:19:40,010
+البيع ولا اعتباره بالمجلس مافيش حاجة اسمها مجلس
+
+210
+00:19:40,010 --> 00:19:47,290
+عقد في .. في .. في .. في .. في عقود الغائبين احنا
+
+211
+00:19:47,290 --> 00:19:55,550
+إذا عرفنا كيف بت .. يعني بيصير يعني الأمر بخصوص
+
+212
+00:19:55,550 --> 00:20:01,070
+التعاقد بين الغائبين سيسهل علينا على طول معرفة
+
+213
+00:20:01,070 --> 00:20:03,910
+إجراء العقود بوسائل الاتصال الحديثة لأن إجراء
+
+214
+00:20:03,910 --> 00:20:07,930
+العقود بوسائل الاتصال الحديثة حقيقة هو عبارة عن
+
+215
+00:20:07,930 --> 00:20:13,030
+تعاقد بين الغائبين تعاقد بين المتباعدين ولا لا
+
+216
+00:20:13,030 --> 00:20:18,330
+سواء عبر الهاتف أو عبر الـ fax أو عبر الـ face أو
+
+217
+00:20:18,330 --> 00:20:23,110
+عبر أي وسيلة من وسائل الإنترنت ووسائل الإلكترونية
+
+218
+00:20:23,110 --> 00:20:30,950
+الحديثة نرجع لسؤالنا التعاقد بين الغائبين كيف
+
+219
+00:20:30,950 --> 00:20:37,650
+يكون مجلسهم احنا التعاقد بين الحاضرين المجلس
+
+220
+00:20:37,650 --> 00:20:45,450
+مبين مجلس مكاني مجلس حقيقي حقيقي أنا قاعد أنا وياك
+
+221
+00:20:45,450 --> 00:20:51,310
+في المحل أو في المكان أو في أي وبنتكلم مخاطبة
+
+222
+00:20:51,310 --> 00:20:53,090
+مشفهة مباشرة
+
+223
+00:20:55,350 --> 00:20:59,670
+أنا بعرض عليك وأنت بترد عليّ وبنتفاوض قاعدين ..
+
+224
+00:20:59,670 --> 00:21:04,170
+أه .. وإذا .. إذا أنا أعرض بجانبي عنك .. انتهى
+
+225
+00:21:04,170 --> 00:21:07,450
+المجلس .. إذا تخلّل .. هذا هو .. هذا .. هذا مجلس
+
+226
+00:21:07,450 --> 00:21:13,160
+حقيقي .. مجلس مكاني .. وأحكامه واضحة طب احنا أساسا
+
+227
+00:21:13,160 --> 00:21:20,220
+في التعامل بين الغائبين ابتداء احنا منفصلين مع 
+
+228
+00:21:20,220 --> 00:21:23,640
+البعض واحنا قاعدين بنقول الشرط في الصيغة إيش
+
+229
+00:21:23,640 --> 00:21:29,900
+الاتصال طب احنا اصلا ما كل واحد مشانكة فكيف يمكن أن
+
+230
+00:21:29,900 --> 00:21:36,920
+يتحقق مجلس العقد أم أنه لا اعتبار له؟ لا يا عم
+
+231
+00:21:36,920 --> 00:21:44,040
+مجلس العقد يكون حتى في حالة التعاقد بين الغائبين
+
+232
+00:21:44,040 --> 00:21:50,560
+ويبقى السؤال كيف إذن؟ كيف إذن؟ باختصار أريد أن 
+
+233
+00:21:50,560 --> 00:21:57,490
+أقول مجلس التعاقد بين الغائبين يمكن أن أطلق عليه
+
+234
+00:21:57,490 --> 00:22:04,210
+بأنه مجلس حكمي بأنه مجلس حكمي وليس حقيقي لأن
+
+235
+00:22:04,210 --> 00:22:10,210
+المجلس الحقيقي الذي يظل اثنين على أرض واحدة وفي
+
+236
+00:22:10,210 --> 00:22:16,250
+مكان واحد هذا مجلس حقيقي لكن إذا كل واحد في بلد
+
+237
+00:22:16,250 --> 00:22:23,610
+أنا أعتبره مجلسا حقيقيا أما ممكن إذا هو مجلس حكم
+
+238
+00:22:23,610 --> 00:22:29,890
+اعتباري البعض يسميه مجلس زماني لأنه احنا ربما في
+
+239
+00:22:29,890 --> 00:22:35,350
+زمان خاصة إذا كان التعاقد تليفونيا أو يعني عبر 
+
+240
+00:22:35,350 --> 00:22:39,210
+وسائل الـ face ممكن في نفس الزمان أنا بأرسل رسالة و
+
+241
+00:22:39,210 --> 00:22:42,750
+هو بيبعث رسالة أنا بكتب يعني في نفس ال .. مجلس
+
+242
+00:22:42,750 --> 00:22:48,330
+زمان يجمعونا زمان وليس مكان وقت واحد طيب يجمعهم
+
+243
+00:22:48,330 --> 00:22:55,910
+زمان يسميه حكميا لكن كيف .. كيف صورته أكثر وأكثر؟
+
+244
+00:22:55,910 --> 00:23:05,410
+متى يبدأ؟ متى ينتهي؟ احنا المجلس التعاقد الحقيقي
+
+245
+00:23:05,410 --> 00:23:09,650
+الذي يكون بين حاضرين مفهوم وقتش بيبدأ فأخش أنا
+
+246
+00:23:09,650 --> 00:23:15,370
+على المحل لسه ما بدأش لأ ممكن أنا ما أخشش أشتغل يمكن
+
+247
+00:23:15,370 --> 00:23:20,470
+تخش أشارة، يمكن تخش اللي صار منه من البائع، أضرب 
+
+248
+00:23:20,470 --> 00:23:27,010
+وأشهر، لأ عندما أدخل المحل أو ألتقي بالبائع أو
+
+249
+00:23:27,010 --> 00:23:34,550
+بصاحب السلعة أو كذا وأعرضه وأسأله عن السعر الفلاني
+
+250
+00:23:34,550 --> 00:23:43,830
+مثلا أو .. فيبين لي بأن السعر كذا وكذا عندما هنا
+
+251
+00:23:43,830 --> 00:23:49,950
+يبدأ يبين كذا بكذا بكذا فيتم الشراء والبيع بمجرد 
+
+252
+00:23:49,950 --> 00:23:56,560
+الحديث عن بيع أو شراء سلع معينة أو تأجيرة أو أي
+
+253
+00:23:56,560 --> 00:23:59,520
+ما نحكي عن العقد عموما عقد بيع أو شراء أو أي عقد
+
+254
+00:23:59,520 --> 00:24:05,200
+من عقود المالية بمجرد البدء جاين الأطراف بالحديث 
+
+255
+00:24:05,200 --> 00:24:11,040
+يبدأ المجلس يبدأ المجلس إذا هو ينتهي بالطرق التي 
+
+256
+00:24:11,040 --> 00:24:14,900
+قلنا بالموافقة أو عدم الموافقة بالخروج بالإقراض
+
+257
+00:24:14,900 --> 00:24:20,880
+للصمت الطويل بكلام أجدد اللي متخلل ينتهي طيب
+
+258
+00:24:21,710 --> 00:24:24,910
+الآن احنا هذا واضح في ال .. طب في ال .. في ال ..
+
+259
+00:24:24,910 --> 00:24:28,870
+بين الغائبين بأن احنا في مجلس مش مافيش مجلس متى
+
+260
+00:24:28,870 --> 00:24:34,050
+يبدأ؟ اه طب ال .. بين الغائبين طريق التواصل احنا 
+
+261
+00:24:34,050 --> 00:24:39,090
+قبل ما نتحدث عن طرق الإلكترونية الجديدة في ما كان
+
+262
+00:24:39,090 --> 00:24:43,850
+زمان وهم اتكلموا قديما عن الحديث عن تعاقد بين
+
+263
+00:24:43,850 --> 00:24:47,050
+الغائبين لكن التعاقد بين الغائبين أو بين الغائبين
+
+264
+00:24:47,050 --> 00:24:53,180
+كيف كان يتم أما بالكتابة أو بالرسول واحد .. أنا
+
+265
+00:24:53,180 --> 00:24:56,660
+بأرسل واحد مسافر والله بلغ فلازم إن أنا بدي أبيع
+
+266
+00:24:56,660 --> 00:25:01,240
+إذا بده يشتري أو بدي أشتري إذا بده يبيع أه .. أنا
+
+267
+00:25:01,240 --> 00:25:04,800
+واحد في السعودية اللي وارض هنا اللي وارض هنا
+
+268
+00:25:04,800 --> 00:25:09,400
+بلّغه أخوي من عمي كذا ومسافر في الحج بلغ قوله أنا
+
+269
+00:25:09,400 --> 00:25:14,060
+بدي أشتريها وبتساعد ادفع كذا وكذا أو بدي أبيعها
+
+270
+00:25:14,060 --> 00:25:17,620
+بكن بتبيعها أو إلى غير ذلك أو هو يكون عنده القطع و
+
+271
+00:25:17,620 --> 00:25:23,910
+بدي أبيعها على ال .. كذا هذا اسمه رسول أو بأرسل له
+
+272
+00:25:23,910 --> 00:25:31,370
+كتابة بأرسل ا بأرسل بسجل الكتاب وبحطها في ظرف و هو
+
+273
+00:25:31,370 --> 00:25:33,690
+ممكن ما يكونش عارف الرسول في الحالة هذه أو حامل 
+
+274
+00:25:33,690 --> 00:25:38,610
+رسالة ساعبري بيحمل الرسالة ويوديها طيب متى سيبدأ؟
+
+275
+00:25:39,370 --> 00:25:45,170
+إذا كان .. إذا كانت كتابة بمجرد وصول الكتاب الكتاب
+
+276
+00:25:45,170 --> 00:25:52,430
+إلى صاحبه وصل برضه ما بدأش مش مجرد وصول زي أنا
+
+277
+00:25:52,430 --> 00:25:56,930
+ما خشيت المحل أنا خشيت بدأ؟ لأ ما بدأش بدأ المحل هو 
+
+278
+00:25:56,930 --> 00:25:59,690
+لا شاف ولا .. مش عارفش الكتاب هذا يمكن الله أعلم
+
+279
+00:25:59,690 --> 00:26:06,290
+يمكن في تهم عليه فيه واستدعاء للنيابي يكون مش عارف
+
+280
+00:26:06,290 --> 00:26:08,030
+يفتحه
+
+281
+00:26:12,370 --> 00:26:17,430
+لقى في رسالة السلام عليكم ورحمة الله أخي فلان أنا
+
+282
+00:26:17,430 --> 00:26:20,870
+عند القطعة الفلانية أريد أن أبيعها بكذا وبكذا فهل
+
+283
+00:26:20,870 --> 00:26:25,810
+تريد أن تشتري التأولى من غيرك ومني بدأ المجلس
+
+284
+00:26:25,810 --> 00:26:32,910
+شبكة الكهرباء صار الإيجاب بدأ المجلس صحيح هو مش
+
+285
+00:26:32,910 --> 00:26:38,930
+عندي لكن هو إيش المقصود أنه نصب الكلام هو لما كان 
+
+286
+00:26:38,930 --> 00:26:43,470
+عندي ما كانش بدي المجلس غير لما أنا حكى وهو الآن مش
+
+287
+00:26:43,470 --> 00:26:49,550
+عندي لكن حكى وصلني ولا لا الحكي تبعه كلامه وصلني
+
+288
+00:26:49,550 --> 00:26:54,850
+إذا بدي المجلس لما أنا بجريت الكلام الإيجاب تبعه
+
+289
+00:26:54,850 --> 00:27:02,470
+أنا بدي المجلس والآن أنا صرت في مجلس عقد ترتبت 
+
+290
+00:27:02,470 --> 00:27:12,820
+عليه أحكام بمعنى أنه الآن بدا المجلس و .. الآن
+
+291
+00:27:12,820 --> 00:27:20,060
+في انتظار القبول منك أو الإعراب حتى بعد قبولك بيستمر
+
+292
+00:27:20,060 --> 00:27:24,640
+المجلس ما لم تخرج ويمكنك بعد القبول في ما يعرف
+
+293
+00:27:24,640 --> 00:27:30,000
+بخيار المجلس حتى بعد القبول مدامت أنت لسه أنا يعني 
+
+294
+00:27:30,000 --> 00:27:37,730
+عشان أجرب لك الصورة الآن بعد ما شوفته انظروا الحالات 
+
+295
+00:27:37,730 --> 00:27:44,010
+الافتراضية بعد ما شفت الخطاب أو الكتاب يا إما 
+
+296
+00:27:44,010 --> 00:27:51,790
+ما بدي مش بدي أشتري في سلة ال .. في السنة تمام؟ خلصنا
+
+297
+00:27:51,790 --> 00:27:56,630
+انتهى المجلس وفقط راحت تمام؟ انتهى المجلس خلاص
+
+298
+00:27:56,630 --> 00:28:03,700
+لأنه أنا رفضت هذا يا إما الآن في فترة صمت بفكر لسه 
+
+299
+00:28:03,700 --> 00:28:12,060
+المجلس شغال شغال اه وأنا سكتت ساكت ساكت أنا طولت
+
+300
+00:28:12,060 --> 00:28:16,080
+الصمت زيادة عن اللزوم برضه انتهى زيادة عن عرف 
+
+301
+00:28:16,080 --> 00:28:21,520
+المعتاد وأنا ساكت اجت ناس دخلت طلعت شغلت بكلام
+
+302
+00:28:21,520 --> 00:28:28,360
+أجنبي وبحديث وبأفعال برضه انتهى المجلس طيب
+
+303
+00:28:30,060 --> 00:28:33,780
+كلان صور .. صورة أخرى تهمنا .. طب أنا بعد ما جريت
+
+304
+00:28:33,780 --> 00:28:36,600
+.. اه الله فرصة يا ولادي .. والله أنا موافق .. أنا
+
+305
+00:28:36,600 --> 00:28:43,540
+موافق الآن .. أنا موافق تم العقد .. لكن الشطارة 
+
+306
+00:28:43,540 --> 00:28:49,300
+عشان من باب القضاء .. عشان ديانتك أنت أصبح تم العقد 
+
+307
+00:28:49,300 --> 00:28:54,800
+وأصبحت .. أصبحت السلعة من حقك .. لكن عشان منع
+
+308
+00:28:54,800 --> 00:28:58,720
+للنزاع .. في عندي قاعد اثنين ثلاثي .. يقولون اسمهم
+
+309
+00:28:58,720 --> 00:29:03,340
+..هنا تأتي أهمية الشهادة الشهود في العقد في عقد 
+
+310
+00:29:03,340 --> 00:29:07,580
+البيوع والعقود المالية ليست شرطا لصحة العقد لكنها 
+
+311
+00:29:07,580 --> 00:29:11,520
+مستحبة لكن في الحالة هذه استحببها أكثر بقولهم اسمع
+
+312
+00:29:11,520 --> 00:29:15,300
+والله اجانا هيك هيك وأنا هنا أنا أعلمكم أو أشهدكم
+
+313
+00:29:15,300 --> 00:29:24,340
+أنني قد وافقت على هذا العرض واشتريته يعني الأرض أو
+
+314
+00:29:24,340 --> 00:29:29,830
+الشقة أو السيارة اشتريتها تمام؟ انتهى العقد، انتهى 
+
+315
+00:29:29,830 --> 00:29:34,450
+بالموافقة، بانعقاد العقد، الآن انتهى المجلس
+
+316
+00:29:43,840 --> 00:29:48,620
+انتبهي في هذه النقطة حساسة انتهى ال .. تم العقدة
+
+317
+00:29:48,620 --> 00:29:55,420
+.. انعقدت العقدة ولم ينتهي المجلس بمعنى .. الآن أنا 
+
+318
+00:29:55,420 --> 00:29:58,220
+أقول لهم يا .. يا شباب .. يا جماعة اللي قاعدين
+
+319
+00:29:59,160 --> 00:30:05,340
+والله إذا بعد هيك طلعنا وانفض .. انفض المجلس وثبت 
+
+320
+00:30:05,340 --> 00:30:10,520
+وأصبح العقد لازما لكن انظروا لو أنا بعد ما قلت
+
+321
+00:30:10,520 --> 00:30:13,180
+لهم هيك هيك إلا واحد بيقول لي ابن عمي قاعد أو أخو
+
+322
+00:30:13,180 --> 00:30:17,240
+قال لي إيش أنت اللي شريته؟ أرضي والله الأرض 
+
+323
+00:30:17,240 --> 00:30:21,220
+الفلانية وكذا وبكى قال لي يا زلمة والله غالي مش
+
+324
+00:30:21,220 --> 00:30:25,460
+بدك تفعله يا زلمة أنا بجيب لك أرض أرحس منها أرخص
+
+325
+00:30:25,460 --> 00:30:26,940
+منها من ذلك
+
+326
+00:30:30,190 --> 00:30:38,790
+أنا لازلت في المجلس لازلت في المجلس ومن حقي ما
+
+327
+00:30:38,790 --> 00:30:45,930
+يُعرف بخيار المجلس الواحد 
+
+328
+00:30:45,930 --> 00:30:51,090
+ما هو بيغير وهو بيبدل هو اقتنعت بكلامه قلت بطلت
+
+329
+00:30:51,090 --> 00:30:57,930
+هل التبطيل هنا من حقي؟ نعم لأن المجلس قائم لكن لو
+
+330
+00:30:57,930 --> 00:31:04,890
+بعد الموافقة التابعة لي اللي شهد عليها دولة انفض المجلس
+
+331
+00:31:04,890 --> 00:31:08,830
+بأي صورة من صورة من انفضات بالخروج أو بتخيلهم كلام
+
+332
+00:31:08,830 --> 00:31:14,830
+أجنبي أو بمدة طويلة بعد أو إلى غير ذلك ليس لي أن
+
+333
+00:31:15,250 --> 00:31:20,810
+أعود عن العقد أو أبطله يعني عن العقد لأ إلا بموافقة
+
+334
+00:31:20,810 --> 00:31:25,730
+الآخر بده عقد جديد عقد إقالة جديد العقد خلاص انتهى
+
+335
+00:31:25,730 --> 00:31:30,130
+ولازم صح ولازم في الصورة الأولى صح ولم يلزم
+
+336
+00:31:30,130 --> 00:31:35,850
+لأنه إيش كان فيه لما زال خيار اسمه خيار المجلس حتى
+
+337
+00:31:35,850 --> 00:31:41,520
+بعد الموافقة حتى بعد الموافقة قال لي هيك هيك أو لسه 
+
+338
+00:31:41,520 --> 00:31:45,700
+أنا والله بعد الموافقة اتصلت فيه للولاد اتصلت في
+
+339
+00:31:45,700 --> 00:31:48,720
+المرأة اتصلت في أبوي في أمي في أختي فوالله أنا 
+
+340
+00:31:48,720 --> 00:31:51,680
+شاركت الأرض الفلانية وحضرولي المصاري ايه طب احنا
+
+341
+00:31:51,680 --> 00:31:54,320
+يا عم ما عندناش مصاري أو المصاري اتصرفنا فيها أو بدنا 
+
+342
+00:31:54,320 --> 00:31:59,880
+نعمل بيها جزء آخر المهم عوض راجع نفسه وبطل من حق
+
+343
+00:31:59,880 --> 00:32:02,840
+لزال المجلس قائما
+
+344
+00:32:07,110 --> 00:32:16,450
+مجلس التعاقد بين الغائبين موجود مش ملغي لكن صورته
+
+345
+00:32:16,450 --> 00:32:23,810
+تختلف عن مجلس التعاقد بين الحاضرين من حيث البدء ومن
+
+346
+00:32:23,810 --> 00:32:28,610
+حيثه يعني بعض التفاصيل التي بيان هناك في الحاضرين
+
+347
+00:32:28,610 --> 00:32:33,010
+بيبدأ بمجرد صدور الكلام لكن هذا بمجرد وصول الخطاب
+
+348
+00:32:33,010 --> 00:32:40,030
+وسماع الطرف الآخر له وبعد ذلك كل ما ينسحب على
+
+349
+00:32:40,030 --> 00:32:43,330
+المجلس الحقيقي ينسحب على المجلس الحكومي من حيثه
+
+350
+00:32:43,330 --> 00:32:53,020
+يعني من حيث الأحكام بشكل عام أحكام انتهاؤه بقاءه
+
+351
+00:32:53,020 --> 00:32:59,600
+بشكل عام على الوجه الذي بيناه قبل قليل الآن يا
+
+352
+00:32:59,600 --> 00:33:04,640
+أخوات بعد هذه النقطة نفهم شيء احنا قلنا إن التعاقد
+
+353
+00:33:04,640 --> 00:33:11,260
+بين الغائبين وسيلته الرئيسية الكتابي أو الرسالة أو 
+
+354
+00:33:11,260 --> 00:33:18,790
+المرسل صح فما هو رأي العلماء يا ترى في التعاقد
+
+355
+00:33:18,790 --> 00:33:23,730
+بالكتابة والمراسلة يعني يمكن واحد تقول طب أنت يعني
+
+356
+00:33:23,730 --> 00:33:30,330
+ألا يفهم ألا يفهم من القول بجواز التعاقد بين
+
+357
+00:33:30,330 --> 00:33:36,750
+الغائبين والذي لا يتم إلا بالكتابة والمراسلة أن
+
+358
+00:33:36,750 --> 00:33:44,840
+الكتابة والمراسلة جائزتين نعم أقول يفهم ذلك ولكن
+
+359
+00:33:44,840 --> 00:33:48,420
+سألته 
+
+360
+00:33:48,420 --> 00:33:52,740
+هذا السؤال لأن ثمة بعض التفاصيل ولذلك أنا أقول
+
+361
+00:33:52,740 --> 00:34:00,880
+بالفعل أن التعاقد بالكتابة والمراسلة في الجملة محل
+
+362
+00:34:00,880 --> 00:34:09,380
+اتفاق على جوازه لكن هل من قيود؟ هل من ضوابط أيضا
+
+363
+00:34:09,380 --> 00:34:15,670
+البعض تختلف عن تلكم الضوابط التي تتعلق بـ التعاقد
+
+364
+00:34:15,670 --> 00:34:25,450
+بالكلام هذا ما نريد أن نتحدث فيه وإلا فإن الأصل في
+
+365
+00:34:25,450 --> 00:34:34,070
+التعاقد بالكتابة والمراسلة جاهز على اختلاف بينهما
+
+366
+00:34:34,070 --> 00:34:42,760
+في أنه هل يشترط شروطا أو أن الخطابة كالخطاب يعني
+
+367
+00:34:42,760 --> 00:34:50,720
+التعاقد بالكتاب تماما كما التعاقد بالكلام ولا يعني
+
+368
+00:34:50,720 --> 00:34:58,520
+عليه قيود لا يصح إلا بقيود اللي بيصح حتى بقيود
+
+369
+00:34:58,520 --> 00:35:04,700
+هو يقول بالمشروعية بالأصل العلماء في ذلك لهم نظرية
+
+370
+00:35:04,700 --> 00:35:13,180
+أو على الرأيين جمهورهم إن صح التعبير على القول بأن
+
+371
+00:35:13,180 -->
+
+401
+00:38:15,200 --> 00:38:21,800
+التعبير عن الرضا فيتم بها التعاقد لم لا إذن هذه
+
+402
+00:38:21,800 --> 00:38:27,100
+واحدة الدليل الثاني أن رسول الله صلى الله عليه
+
+403
+00:38:27,100 --> 00:38:33,340
+وسلم اعتمد الكتابة فيما هو أقدسها من عقود البيع
+
+404
+00:38:33,340 --> 00:38:39,560
+والشراء أو العقود المالية وهي مكاتبة الملوك
+
+405
+00:38:39,560 --> 00:38:46,380
+والرؤساء والقياصرة والأكاسرة بدعوتهم للإسلام ودين
+
+406
+00:38:46,380 --> 00:38:51,820
+الإسلام وبالمناسبة الدخول في الإسلام تعاقد، نحن معرض
+
+407
+00:38:51,820 --> 00:38:56,620
+عليه الإسلام فإذا دخل يعني عرض فإذا قبل يعني هذا
+
+408
+00:38:56,620 --> 00:39:02,320
+صار في إجابة قبول يعني ف .. وكان يرسلوا إيه الكتب
+
+409
+00:39:02,320 --> 00:39:10,240
+إذا فكيف نقول بجواز التعاقد على الإسلام على نشر
+
+410
+00:39:10,240 --> 00:39:15,800
+دعوة الإسلام بالكتاب ونجيزها في ما هو دون ذلك من
+
+411
+00:39:15,800 --> 00:39:21,800
+.. من تعاقدات مالية بسيطة فردية، أه .. تمام؟ خلصنا
+
+412
+00:39:21,800 --> 00:39:25,020
+.. هذه .. هذه .. هذا الرأي الأول وانجدت معظمه ..
+
+413
+00:39:25,020 --> 00:39:29,020
+وذلك .. لكن تمت رأي آخر وحوى للشافعية أو لبعض
+
+414
+00:39:29,020 --> 00:39:32,200
+الشافعية حقيقة لأن الشافعية في هذا لهم قولين ..
+
+415
+00:39:32,200 --> 00:39:36,440
+قول مع الجمهور وقول مع ال .. ال .. ال .. وقول آخر
+
+416
+00:39:36,440 --> 00:39:42,440
+خالف رأي الجمهور الشافعية قالوا والله إحنا اللي
+
+417
+00:39:42,440 --> 00:39:47,470
+شايفينه أو الرأي الثاني عند الشافعية قالوا بأننا ..
+
+418
+00:39:47,470 --> 00:39:56,750
+بأننا نقول بأن الكتابة وسيلة من وسائل خلي بعضهم 
+
+419
+00:39:56,750 --> 00:40:01,830
+يقررون في البداية من وسائل التعاقد من حيث الأصل
+
+420
+00:40:01,830 --> 00:40:08,390
+لكننا إنما نقول بذلك بشرط لكن لم يشترطوا لم 
+
+421
+00:40:08,390 --> 00:40:14,780
+يشترطوا إذًا أن نكون مستبينة الكلام ومرسومة، لكن
+
+422
+00:40:14,780 --> 00:40:18,140
+هذول الأش  الرأي الثاني قال لك لا أنا ما تركاش الحبل
+
+423
+00:40:18,140 --> 00:40:25,660
+على الغارب، أنا اثنين قاعدين حاضرين في مجلس واحد لا
+
+424
+00:40:25,660 --> 00:40:32,460
+أقبل ولا أجيز لهما أن يتعاقدا بالكتابة و هما قادرين
+
+425
+00:40:32,460 --> 00:40:40,800
+على إيه؟ على التخاطب وعقد العقد بالكلام لأن
+
+426
+00:40:40,800 --> 00:40:48,160
+الكلام هو الأصل والكتابة في نظرهم يعني .. في
+
+427
+00:40:48,160 --> 00:40:57,220
+الكتابة في نظرهم وسيلة بديلة، وسيلة بديلة كالتيمم 
+
+428
+00:40:57,220 --> 00:41:01,140
+والماء إذا حضر الماء بطل التيمم إذا وجد الكلام
+
+429
+00:41:01,140 --> 00:41:07,140
+فلا كتاب، لكن هناك الكتاب كالخطاب هنا لا الكتاب مش
+
+430
+00:41:07,140 --> 00:41:12,620
+زي الخطاب، إذا ما قدرناش على الخطاب بنستخدم الكتاب،
+
+431
+00:41:12,620 --> 00:41:17,460
+لا بأس في ذلك، ففي الأصل مشروعة، مشروعة، لكن مش
+
+432
+00:41:17,460 --> 00:41:22,140
+داية، ولذلك هم قالوا، في حالة الغيبة يا سيدي ماشي،
+
+433
+00:41:22,140 --> 00:41:26,420
+أبعد كتابه ومنجوز، لما نكون بعيدين عن بعض، أما
+
+434
+00:41:26,420 --> 00:41:29,680
+جاعدين عن بعض، تكتبي ورقة وابعتلك ورقة، هذا إيه
+
+435
+00:41:29,680 --> 00:41:37,150
+المسخرة؟ ما تحكي يا ولد، أو قادرين .. يعني إذا في
+
+436
+00:41:37,150 --> 00:41:40,230
+حالة الغيبة أو في حالة العجز عن الكلام، واحد
+
+437
+00:41:40,230 --> 00:41:48,350
+أخرس، بحكيش، ناشب، غير هيك، أصل الكلام، واستدلوا
+
+438
+00:41:48,350 --> 00:41:54,270
+واختموا بذلك، هؤلاء أيضًا بدليلين، أولًا قالوا
+
+439
+00:41:54,270 --> 00:42:02,760
+الكتابة لم تكن وسيلة معتبرة في عهد رسول الله صلى
+
+440
+00:42:02,760 --> 00:42:07,500
+الله عليه وفي الأصل الوسيلة المعتبرة في عقد العقود
+
+441
+00:42:07,500 --> 00:42:14,800
+هي صيغة الكلام، أما الكتابة فليست وسيلة معتبرة، خاصة
+
+442
+00:42:14,800 --> 00:42:19,240
+أنها تحتمل
+
+443
+00:42:19,240 --> 00:42:24,680
+التزوير لأن غادة الكتابة بدها تنتقل من مكان لمكان و
+
+444
+00:42:24,680 --> 00:42:28,360
+يحتفظ فيها وهذا بقت عند التخاصم طب تحتمل التزوير
+
+445
+00:42:28,360 --> 00:42:34,220
+كل واحد بده .. بده يتملك شيء ممكن يكتب ورقة ويقول
+
+446
+00:42:34,220 --> 00:42:40,100
+والله إيش هذا باسم آخر و يلبس تهمة للآخر اللي باعه
+
+447
+00:42:40,100 --> 00:42:45,380
+و إذا الاحتمال الكتابة ليه التزوير ولأن الكتابة
+
+448
+00:42:45,930 --> 00:42:49,130
+الدليل الثاني ممكن نعتبره لم تشتهر في عهد رسول
+
+449
+00:42:49,130 --> 00:42:53,530
+الله صلى الله عليه وسلم أنها وسيلة من وسائل
+
+450
+00:42:53,530 --> 00:42:58,270
+التعاقد بين فيها العقود المالية على وجه الخصوص
+
+451
+00:42:58,270 --> 00:43:02,330
+وأنا أستطيع أن أقول أن هو يمكن أن يُرد على مسألة
+
+452
+00:43:02,330 --> 00:43:07,850
+التخاطب بالكتابة لذيف الدعوة صحيح الدعوة أقدس لكن
+
+453
+00:43:07,850 --> 00:43:12,770
+لاحظوا إنما كان الخطاب لهم بالكتاب لأنهم متأدعات
+
+454
+00:43:12,770 --> 00:43:16,850
+ولو كانوا في الداخل لما كان لرسول الله صلى الله
+
+455
+00:43:16,850 --> 00:43:21,410
+عليه وسلم إلا أن يخاطبهم بالدعوة الإسلامية مباشرة
+
+456
+00:43:21,410 --> 00:43:23,490
+شكرا لك
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/UxZiDu7pWaU_postprocess.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/UxZiDu7pWaU_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..1fd742b2b5eceeba7ba17d70f272dd661df676ba
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/UxZiDu7pWaU_postprocess.srt
@@ -0,0 +1,1232 @@
+1
+00:00:00,000 --> 00:00:01,300
+موسيقى
+
+2
+00:00:20,750 --> 00:00:23,630
+بسم الله الرحمن الرحيم الحمد لله والصلاة والسلام
+
+3
+00:00:23,630 --> 00:00:27,290
+على رسول الله وعلى آله وصحبه وسلم تسليمًا كثيرًا
+
+4
+00:00:27,290 --> 00:00:33,590
+وبعد اليوم يا أخوات نتحدث عن ثقه الأقليات ربما
+
+5
+00:00:33,590 --> 00:00:40,640
+يعنيبقى علينا في المرة الماضية بعض الجزئيات
+
+6
+00:00:40,640 --> 00:00:49,200
+المتعلقة بقتل الرحمة كان .. يعني يمكن أن نختصرها
+
+7
+00:00:49,200 --> 00:00:54,180
+في نقطتين، نقطة الأولى ما هي البدائل التي وضعها
+
+8
+00:00:54,180 --> 00:00:58,820
+الإسلام و اللي اتحدثنا فيها هذه على أي حال، يمكن
+
+9
+00:00:58,820 --> 00:01:04,750
+احنا بعد ما بياننا الموقف الشرعيوأدلته أو القواعد
+
+10
+00:01:04,750 --> 00:01:09,670
+اللي اعتمد عليها والأدلة اللي استند لها في تحريم
+
+11
+00:01:09,670 --> 00:01:17,870
+قتل الرحمة وكيف رد على الشبه اللتي اعتمد عليها
+
+12
+00:01:17,870 --> 00:01:24,780
+المؤيدون من غير المسلمينلقتل الرحمة وفندق كل ذلك
+
+13
+00:01:24,780 --> 00:01:31,160
+بما تطمأنه إليه النفس وبما يتوافق مع روح الشريعة
+
+14
+00:01:31,160 --> 00:01:39,380
+وقوائدها العامةيعني في ال .. في .. بعد ذلك كله وضع
+
+15
+00:01:39,380 --> 00:01:47,440
+بدائل يعني لأن رب قائل يقول يعني ما الحل إذا حرمتم
+
+16
+00:01:47,440 --> 00:01:51,440
+أنتم تحرمون قتل الرحمة ما الحل لديكم؟بالنسبة
+
+17
+00:01:51,440 --> 00:01:55,440
+لهؤلاء كيف تعالجون النفقات الكثيرة والمصاريف
+
+18
+00:01:55,440 --> 00:02:00,880
+الكثيرة كيف تعملون
+
+19
+00:02:00,880 --> 00:02:06,300
+على تخفيف الآلام التي يعاني منها أهل المريض وإلى
+
+20
+00:02:06,300 --> 00:02:14,490
+غير ذلك ما هي البداء اللي لديكمقلنا بأن ثمة أو
+
+21
+00:02:14,490 --> 00:02:22,390
+بيّن لنا الفقهاء أن ثمة بداء العديد للقول أو عن
+
+22
+00:02:22,390 --> 00:02:29,410
+القول بقتل الرحمة تبدأ أولا من تخصيص أماكن خاصة
+
+23
+00:02:29,410 --> 00:02:33,950
+لهؤلاء الأشخاص أو المرضى الذين
+
+24
+00:02:37,080 --> 00:02:44,300
+يأس الأطباء من معالجتهم لأن توضع لهم أماكن تتناسب
+
+25
+00:02:44,300 --> 00:02:49,000
+معاهم بحيث لا تكلف مثل المستشفيات ليكونوا على حساب
+
+26
+00:02:49,000 --> 00:02:56,480
+المرضى الأخرين لأن الفكرة من البديلإن هؤلاء
+
+27
+00:02:56,480 --> 00:03:01,220
+سيكونون على حساب أو متابعتهم ورعايتهم ستكون على
+
+28
+00:03:01,220 --> 00:03:04,180
+حساب الآخرين لا يا عم احنا مش هيكونوا على حساب
+
+29
+00:03:04,180 --> 00:03:07,940
+الآخرين الدولة يجب عليها أو ينبغي عليها أن تكون
+
+30
+00:03:07,940 --> 00:03:12,980
+بتوفير بداية أماكن معينة تتناسب مع حياته بدون أن
+
+31
+00:03:12,980 --> 00:03:17,180
+تكون فيها تكاليف التي تحتاجها المستشفيات الخاصة
+
+32
+00:03:17,180 --> 00:03:27,360
+بالمرضى الأعاديين إضافة إلى ذلكأن تكون هناك .. أن
+
+33
+00:03:27,360 --> 00:03:33,860
+يكون هناك فريق أيضا متخصص للاشراف على هؤلاء ليس
+
+34
+00:03:33,860 --> 00:03:40,720
+بالضرورة أن يكونوا طباءحقيقيين ربما طباء نفسيين أو
+
+35
+00:03:40,720 --> 00:03:46,880
+مشرفين اجتماعيين يحتاجون او ممرضين فقط لتناول
+
+36
+00:03:46,880 --> 00:03:49,900
+العلاج
+
+37
+00:03:49,900 --> 00:03:55,880
+او الى غير ذلك ايضا بما يخففوا عب المصاريف
+
+38
+00:03:55,880 --> 00:04:04,680
+والنفقات المادية ايضا محاولة تطوير العلاج جات
+
+39
+00:04:05,680 --> 00:04:09,140
+المسكنة هذه لأن الأصل في الميقوس منه أنه يأخذ
+
+40
+00:04:09,140 --> 00:04:14,880
+علاجات مسكنة طب أنت حاول تفكر أن توجد علاجات ناجعة
+
+41
+00:04:14,880 --> 00:04:23,600
+وناجحة وشافية ربما يعني في جانب التسكين من جهة وفي
+
+42
+00:04:23,600 --> 00:04:28,710
+جانب المعالجة من جهة لا تقف عند التسكين فقطحاول أن
+
+43
+00:04:28,710 --> 00:04:34,850
+توجد حلول إبداعية و حلول صلاقة و أن لا تتوقف و
+
+44
+00:04:34,850 --> 00:04:39,950
+تقول هذا ملف مغلق ليس ثمة من ملف المغلق في الطب إن
+
+45
+00:04:39,950 --> 00:04:46,850
+الله جعل لكل دا إندوى بس أنت ابحث و نعم هم طب هم
+
+46
+00:04:46,850 --> 00:04:49,790
+في الأطباء يالا يالا عايشين كيف من غير أطباء يعني
+
+47
+00:04:49,790 --> 00:04:54,850
+ساعد عاملهم هاتا هم أساسي الأطباء مش عاملين لهم
+
+48
+00:04:54,850 --> 00:05:02,100
+حاجةالاطباء يصفون لهم في العام الأغلب علاجات
+
+49
+00:05:02,100 --> 00:05:08,360
+للتسكين لتسكين المرض بحيث لا يحتاج إلى ربما لا
+
+50
+00:05:08,360 --> 00:05:12,540
+يمنع أن يكون في طبيب عام مشرف يأتي بين فترة وفترة
+
+51
+00:05:12,540 --> 00:05:21,040
+لا يمنع وجود يعني حلول وبحوث حول علاجات ناجعة لا
+
+52
+00:05:21,040 --> 00:05:25,500
+مانعة من ذلك لكناحنا بدنا الأماكن الخاصة و الفريق
+
+53
+00:05:25,500 --> 00:05:31,480
+الخاص اللي بحيث لا يكون على حساب مرضى آخرين فلا
+
+54
+00:05:31,480 --> 00:05:35,100
+يقال انه بدنا نتخلص منهم لأ احنا مابدناش احنا
+
+55
+00:05:35,100 --> 00:05:39,580
+بنوفر لهم البيئة المناسبة لهم و في نفس الوقت بما
+
+56
+00:05:39,580 --> 00:05:45,840
+لا يكون على حساب مرضى آخرين بما لا يسببوا نفقات
+
+57
+00:05:45,840 --> 00:05:54,350
+زائدة بما لا يسببوا معاناةزائدة يعني ولذلك لابد من
+
+58
+00:05:54,350 --> 00:05:58,230
+الاهتمام بالجانب النفسي أيضا إلى الجانب المادى
+
+59
+00:05:58,230 --> 00:06:04,050
+المسألة هؤلاء يحتاجون إلى معالجة إلى رعاية نفسية
+
+60
+00:06:04,050 --> 00:06:11,190
+لأن الآلام أيتها الأخوات والمرض المستعصى الأمراض
+
+61
+00:06:11,190 --> 00:06:15,070
+المستعصية هذه لها انعكاسات نفسية كبيرة جدا ما لم
+
+62
+00:06:15,070 --> 00:06:18,850
+يكن الإنسان قد تقوى بإيمان بالإيمان بالله سبحانه
+
+63
+00:06:18,850 --> 00:06:25,300
+وتعالىفإنها نكسات للنفسيين فهم محتاجون إلى إن صح
+
+64
+00:06:25,300 --> 00:06:30,320
+التعبير على خصائيين نفسيين أو يعني إرشادات نفسية
+
+65
+00:06:30,320 --> 00:06:33,860
+من هذا أو من ذاك من الأقارب والأباعد والمختصين
+
+66
+00:06:33,860 --> 00:06:41,660
+وغير المختصين لتخفيف يعني سطوة الألم أو شدة الألم
+
+67
+00:06:41,660 --> 00:06:48,810
+عليهم وعلى نفسهموهذا يعني المريض هذا يحتاجه في هذه
+
+68
+00:06:48,810 --> 00:06:53,490
+الفترة احتياجا كبيرا يعني بل ربما هذا اكثر ما
+
+69
+00:06:53,490 --> 00:07:00,410
+يحتاجه اكثر مش العكس ان انا يعني اشعره او هو يصير
+
+70
+00:07:00,410 --> 00:07:08,290
+كأنه بينه بينه تخوف يا أخوات القتل الرحمة يفضي الى
+
+71
+00:07:08,290 --> 00:07:17,730
+هدم الثقةبين المريض والطبيب وذويه والعكس بالعكس
+
+72
+00:07:17,730 --> 00:07:22,170
+لأن قتل الرحمة مش بالضرورة يكون بطلب المريض ممكن
+
+73
+00:07:22,170 --> 00:07:27,870
+يكون بطلب الأهل أو بفعل الطبيب يمكن الشخص هذا يقبأ
+
+74
+00:07:27,870 --> 00:07:33,050
+ابتداءإن يدخل المستشفى وممكن يكون فيه إمكانية
+
+75
+00:07:33,050 --> 00:07:37,150
+لعلاجه لأنه خايف إنه يقدروا قتل الرحمة أو خايف إن
+
+76
+00:07:37,150 --> 00:07:43,970
+أهله يطلبوا منه كذا أو .. أو .. لكن لو علم أن هناك
+
+77
+00:07:43,970 --> 00:07:50,630
+رعاية نفسية وعاطفية واهتمام وحرص على حياته وتنفيذ
+
+78
+00:07:50,630 --> 00:07:54,960
+له في الأجل كما بينا النبي صلى الله عليه وسلمهذا
+
+79
+00:07:54,960 --> 00:08:00,580
+يعني يخففه من الآلام انتم مش بتقتله عشان تخففه من
+
+80
+00:08:00,580 --> 00:08:06,960
+آلامه أنا بده أخفف من آلامه بدون قتل بده أخفف من
+
+81
+00:08:06,960 --> 00:08:11,160
+آلامه بالكلمة الطيبة بده أخفف من آلامه بالتنفيس
+
+82
+00:08:11,160 --> 00:08:16,980
+بالأجل بده أخفف من آلامه بالأمل بالشفاء بده أخفف
+
+83
+00:08:16,980 --> 00:08:22,440
+من آلامه بالرجاء في الله سبحانه وتعالى بأن يكون
+
+84
+00:08:22,440 --> 00:08:28,850
+هذا المرضيعني كفارة له من ذيوبه بدي أخاف من آلام
+
+85
+00:08:28,850 --> 00:08:32,550
+بكل هذه الوسائل أقول حقيقة يا أخوات هذا يخاف من
+
+86
+00:08:32,550 --> 00:08:37,070
+آلام حقا يخاف من آلام الجسدية عندما ما هي كده
+
+87
+00:08:37,070 --> 00:08:46,420
+عندما الإنسان يتصورهذا الذي اعده الله له من عظيم
+
+88
+00:08:46,420 --> 00:08:49,680
+المتاع
+
+89
+00:08:49,680 --> 00:08:57,320
+او عظيم الفوز في الجنان يعني سيستخف هذه المعاناة
+
+90
+00:08:57,320 --> 00:09:00,940
+هو اللي بيروح يجاهد ويروح على كفه وهو يعلم انه
+
+91
+00:09:00,940 --> 00:09:08,570
+سيقتلو يستعذب ذلك .. يستعذب ذلك في سبيل الله ..
+
+92
+00:09:08,570 --> 00:09:12,290
+بتفكر .. عامل نفسي يا أخوات .. هذا عامل نفسي عندما
+
+93
+00:09:12,290 --> 00:09:16,850
+يوازن و يفكر العاطفة تضغط في هذه الحالة و الناحية
+
+94
+00:09:16,850 --> 00:09:20,410
+النفسية تضغط .. و هو كذلك عندما يشعر أن هذا الألم
+
+95
+00:09:20,410 --> 00:09:23,730
+انت لما تأخذ حبة الحبوب المرة العلجة مول الإبرة
+
+96
+00:09:23,730 --> 00:09:30,100
+اللي بتخوف شكلها .. يعنيو لو كنت في حالة طبيعية
+
+97
+00:09:30,100 --> 00:09:36,460
+تقبأ ذلك لكن انت بتاخدها و انت مستيقظ يعني برضة بل
+
+98
+00:09:36,460 --> 00:09:40,180
+تطالب بذلك و تساحب على ذلك و تقف على الدورة على
+
+99
+00:09:40,180 --> 00:09:44,900
+ذلك من أجل حب الحبوب و حب الدولة و القبلة المرة و
+
+100
+00:09:44,900 --> 00:09:48,500
+اللي بتساعدك عشان يفتحوا لك بطنك و يعملوا لك عملية
+
+101
+00:09:48,500 --> 00:09:57,840
+لأنك تطمع أن تلقى او أن تحقيق مصلحة أعظمفي ذلك و
+
+102
+00:09:57,840 --> 00:10:03,060
+يسهل عليك هذا و بتقولك يا عم اعملولي بدون بنج مثلا
+
+103
+00:10:03,060 --> 00:10:10,020
+أحيانا في ناس معلش فانت انا بقولك تماما المعالجة
+
+104
+00:10:10,020 --> 00:10:16,180
+النفسية لها أثر كبير على تخفيف الألم المادى بهذا
+
+105
+00:10:16,180 --> 00:10:23,130
+الشي يعنيحقيقي و ليس وهم طبعا يعني إذا معي المريض
+
+106
+00:10:23,130 --> 00:10:27,030
+أيضا في الجانب الآخر بدأ أتكلم بإني أنا في معالجة
+
+107
+00:10:27,030 --> 00:10:30,750
+مع ذوي المريض أنا يعني بغي أنا كدولة كمجتمع
+
+108
+00:10:30,750 --> 00:10:37,390
+كمؤسسات كمؤسسات أن لا أترك ذوي المريض لوحدهميعني
+
+109
+00:10:37,390 --> 00:10:42,490
+خاصة إذا كانوا فقراء إذا كانوا يعني محتاجين إلى من
+
+110
+00:10:42,490 --> 00:10:53,110
+يعني يقف معهم أقدم لهم يعني المصاريف والنفقات يعني
+
+111
+00:10:53,110 --> 00:11:01,150
+الاحتياجاتأيضا يعني هذا من سبول العلاج أو سبول
+
+112
+00:11:01,150 --> 00:11:07,970
+البداء الموجودة و الدعم لهم الدعم لأهل المريض
+
+113
+00:11:07,970 --> 00:11:12,990
+معنويا و ماديا و ان شاء الله يعني احنا هنعودكوا
+
+114
+00:11:12,990 --> 00:11:20,350
+احنا كذا و هكذا فلا بد من التواصل معهم ويعني
+
+115
+00:11:20,350 --> 00:11:26,730
+اشراكهم في المسئولية نحو ابنهم أو مشاركتهم في
+
+116
+00:11:26,730 --> 00:11:30,570
+المسئولية وإشراكهم في توصيف طبيعة هذا المريض بده
+
+117
+00:11:30,570 --> 00:11:34,250
+هيك و بده هيك و كيف تتعاملوا معاه و إلى غير ذلك
+
+118
+00:11:35,230 --> 00:11:42,650
+الشاهد في الآخر أن هناك بدائل لا تغلقوا الطريق لا
+
+119
+00:11:42,650 --> 00:11:47,090
+تقولوا أنه ليس فم تطريق إلا الموت إلا القتل هذا
+
+120
+00:11:47,090 --> 00:11:51,830
+ليس من حقكم ولا من حق أحدكم الحياة لله بيد الله
+
+121
+00:11:51,830 --> 00:11:58,130
+ولا ينبغي أن يتجرأ على إيقاف أحد مهما كان الله عز
+
+122
+00:11:58,130 --> 00:12:03,400
+وجل هو المحيي وهو المبيدالحين في طرق البداية عن
+
+123
+00:12:03,400 --> 00:12:09,880
+قتل الرحمة فطرق البداية تقلل من الذكاليب او ال ..
+
+124
+00:12:09,880 --> 00:12:15,420
+يعني ما .. ما يصدروا من عبق من طبع المريض على غيره
+
+125
+00:12:15,420 --> 00:12:20,840
+فليس في تخصيص اماكن حتى ده و الطباء متخصصون فكانوا
+
+126
+00:12:20,840 --> 00:12:24,410
+مرسلين او غيرينزيادة في تكارير أو زيادة في
+
+127
+00:12:24,410 --> 00:12:29,170
+الأعباء؟ لأ أنا بقولك ليش لأ لأن في الغالب يا
+
+128
+00:12:29,170 --> 00:12:33,730
+أخوان اختيار مثل هذه الأماكن يعني انتوا ما هو
+
+129
+00:12:33,730 --> 00:12:39,790
+بالنظر بيكون بالمقارنة أو التقييم بالمقارنة أنا في
+
+130
+00:12:39,790 --> 00:12:46,490
+المستشفيات العادية المستشفيات لها يعني خصوصية في
+
+131
+00:12:46,490 --> 00:12:55,220
+التأثيثأسرة خاصة رعاية خاصة تدفع خاصة إلى غير ذلك
+
+132
+00:12:55,220 --> 00:13:00,540
+يعني خصوصية يعني بحيث تكون أجهزة خاصة ل .. خاصة
+
+133
+00:13:00,540 --> 00:13:04,980
+فيها يعني دور الأناية أو في غرف الأناية المركزة أو
+
+134
+00:13:04,980 --> 00:13:10,200
+حتى في يعني في الغرف العادية تحتاج إلى تقاليد
+
+135
+00:13:10,200 --> 00:13:15,750
+كبيرة بخلاف يعني مثلابخلاف و .. و .. و في مناطق
+
+136
+00:13:15,750 --> 00:13:20,210
+خاصة أيضا يعني تكون قريبة ربما في وسط البلد لكن
+
+137
+00:13:20,210 --> 00:13:24,050
+ربما هذه تكون يعني الآن مستشفى الوفاء اللي فتح في
+
+138
+00:13:24,050 --> 00:13:27,430
+فترة من .. عيد حالات يعني صعبة يعني خليني نقول
+
+139
+00:13:27,430 --> 00:13:32,370
+يعني مستوى طبي وإن .. وإن كان هو الآن تغير واترقى
+
+140
+00:13:32,370 --> 00:13:36,850
+يعني لكن في البداية كان للحالات للتضييق وكذا لا
+
+141
+00:13:36,850 --> 00:13:41,090
+يحتاج إلىأخصائيين لا يحتاج .. بدنا قطعة أرض بعيدة
+
+142
+00:13:41,090 --> 00:13:45,570
+رخيصة لا يحتاج إلى تكاليف تأثيث لل .. لل .. للما
+
+143
+00:13:45,570 --> 00:13:50,190
+.. الماكن و .. ولا .. والأهم من كل ذلك أنه لا يكون
+
+144
+00:13:50,190 --> 00:13:55,290
+على حساب المرضى الآخرين انت هناك كل واحد يعني مصاب
+
+145
+00:13:55,530 --> 00:14:00,470
+بهذا محدد او شخص ميقوس منه بدك تنام على سرير او في
+
+146
+00:14:00,470 --> 00:14:05,350
+غرفة تحجز له غرفة على حساب مريض اخر ربما تحدثوا
+
+147
+00:14:05,350 --> 00:14:09,350
+اشكالات لكن انت عندما توفر له مكانا لا يكون على
+
+148
+00:14:09,350 --> 00:14:13,210
+حساب هذا برضه نظرة اخرى على حساب مريض اخر
+
+149
+00:14:16,020 --> 00:14:20,120
+فانت لا تجعلهم يزاحمون وفي نفس الوقت لا تريد ان
+
+150
+00:14:20,120 --> 00:14:26,980
+تفرط بهم توفر لهم مكانا يتناسب مع حالتهم المرضية
+
+151
+00:14:26,980 --> 00:14:35,120
+هذه اللتي لا تحتاج الى كثير تخصصية و الى نفقات
+
+152
+00:14:35,120 --> 00:14:43,760
+كبرى بدها بعض الرعايةحتى لو كانت التكلفة مشابهة أو
+
+153
+00:14:43,760 --> 00:14:50,140
+مساوية لكن أن توفر مقابل ذلك مكانا للمريض الذي
+
+154
+00:14:50,140 --> 00:14:54,140
+يرجع برؤه ويرجع شفاءه هذا في حد ذاته هذا أيضا
+
+155
+00:14:54,140 --> 00:14:59,140
+إنجاز ينبغي أن يُأخذ بيعين الاعتبار طيب يعني وفقا
+
+156
+00:14:59,140 --> 00:15:05,720
+للظروف الصحية السيئة في قطاع غزة لو حدث أن كان شخص
+
+157
+00:15:05,720 --> 00:15:10,920
+ميقص منهم كأطفال الحضاناتفي خاصة في المستشفيات في
+
+158
+00:15:10,920 --> 00:15:14,740
+قطاع فزة الأماكن اللي هتتسهل أكتر من المريض يعني
+
+159
+00:15:14,740 --> 00:15:19,480
+كجنين يعني مولود جديد يعيش فترة محددة على الأجهزة
+
+160
+00:15:19,480 --> 00:15:23,640
+فالحين احنا لسنا الأجهزة هيموت لكن إذا يعني في
+
+161
+00:15:23,640 --> 00:15:27,400
+حالة أصلح منه يمكن وضعها في الحضانة مكانها ممكن
+
+162
+00:15:27,400 --> 00:15:31,680
+رفع الأجهزة عن هذا الجنون نحن نتحدث عن حرمة قتل
+
+163
+00:15:31,680 --> 00:15:39,400
+الرحمةمن خلال نزل الأجهزة أو إلى غير ذلك في
+
+164
+00:15:39,400 --> 00:15:44,780
+الحالات التي تستطيع الدولة أو يستطيع المستشفى أن
+
+165
+00:15:44,780 --> 00:15:49,760
+يوفر للجميعفيها ذلك يعني أنا استطيع أن أوفر للمريض
+
+166
+00:15:49,760 --> 00:15:53,140
+الذي يرجع برؤه ولمريض اللذي لا يرجع برؤه كل
+
+167
+00:15:53,140 --> 00:15:58,440
+الإمكانيات هنا أقول بالتحريم لكن إذا في حالة لا
+
+168
+00:15:58,440 --> 00:16:03,880
+أستطيع أن أوفر المكان أو الشدواء أو الرعاية أو
+
+169
+00:16:03,880 --> 00:16:09,080
+الطبيب إلا لشخص فانا في عندي حاجة اسمها فقه
+
+170
+00:16:09,080 --> 00:16:14,860
+الأولويات بدوا نصير فيها أولويات أنا ضحيت بالجنين
+
+171
+00:16:15,730 --> 00:16:24,130
+من أجل حياة الأم مع أنه يحرم إجهاض الجني ضحيت فيه
+
+172
+00:16:24,130 --> 00:16:27,830
+في لحظة من اللحظات في لحظة من اللحظات غير الطبيعية
+
+173
+00:16:27,830 --> 00:16:33,870
+وغير العادية فقه الأولويات وهنا أيضا أنا الشخص في
+
+174
+00:16:33,870 --> 00:16:38,830
+عقيدة والله أنا بين حالتين ولا أستطيع إلا أن أقدم
+
+175
+00:16:38,830 --> 00:16:43,610
+مساعدة إلا لواحدة من هتين الحالتين فأقدم الأولى
+
+176
+00:16:43,610 --> 00:16:48,090
+بالرجاء وأترك الأخرىلا بأس هذه ضرورات تبيح
+
+177
+00:16:48,090 --> 00:16:53,330
+المحذورات فيها على طول بقى بنزع المنفسة منه و بقدم
+
+178
+00:16:53,330 --> 00:16:57,410
+الشخص و ده كان يحدث الحروب أثناء الحروب علينا في
+
+179
+00:16:57,410 --> 00:17:03,610
+غزة كان يحدث مثل هذا أقولك أشياء مشابهة أشياء
+
+180
+00:17:03,610 --> 00:17:09,470
+مشابهة أنا الآن في عندي يعني أكمل أخصائي اتنين
+
+181
+00:17:09,470 --> 00:17:17,650
+تلاتة و لو أنا واحدلده يعمل عملية معينة أو واحد
+
+182
+00:17:17,650 --> 00:17:23,350
+عنده إصابة في القدم ربما تحتاج إلى ساعات متعددة
+
+183
+00:17:23,350 --> 00:17:28,410
+ومافيش عند الأهل فريق الطب الواحد عشان أنقذ رجله و
+
+184
+00:17:28,410 --> 00:17:33,870
+هذا الفريق نفسه أجى شخص أجى مصاب آخر إن لم يوجد
+
+185
+00:17:33,870 --> 00:17:39,670
+هذا الفريق ستتأدد حياته بالخطرطب انا ممكن اقص
+
+186
+00:17:39,670 --> 00:17:44,310
+الرجل هذه و اخلص منها في ربع ساعة زمان مع انه ممكن
+
+187
+00:17:44,310 --> 00:17:49,990
+الطيب و انا عشان التفت لمين او اتركها لشخص يجي
+
+188
+00:17:49,990 --> 00:17:55,950
+قصها مش اخصائي يعني و انتقل لشخص انا بإمكاني انقذ
+
+189
+00:17:55,950 --> 00:18:03,380
+حياتهوهكذا يعني النظر يعني الحكم يختلف في حال
+
+190
+00:18:03,380 --> 00:18:06,600
+الأحوال العادية عن الأحوال الاستثنائية دايما
+
+191
+00:18:06,600 --> 00:18:10,000
+الأحوال الاستثنائية لها أحكام استثنائية هذا عمر
+
+192
+00:18:10,000 --> 00:18:19,720
+طبيعي يعني يقدم إذا هناك يعني بدائل ثم إن المبنى
+
+193
+00:18:19,720 --> 00:18:26,540
+الأساسي أو القاعدة الأساسية التي يعتمد عليهاتعتمد
+
+194
+00:18:26,540 --> 00:18:31,200
+عليها النظرة الشرعية هو أن هذه الحياة هي من عند
+
+195
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+الله سبحانه وتعالى ولا يجوز لأحد أن يعتدي عليها
+
+196
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+بغير وجه حق على كل الأحوال ومع
+
+197
+00:18:46,680 --> 00:18:52,800
+ذلك ومع ذلك كله وجدنا بعض الفتاوى التي يعني فيها
+
+198
+00:18:52,800 --> 00:18:59,790
+بعض المرونةفي .. في مسألة قتل الرحمة يعني
+
+199
+00:18:59,790 --> 00:19:04,930
+هل تجيز قتل الرحمة؟ لا طبعا ولكنها تعتبر بعض
+
+200
+00:19:04,930 --> 00:19:10,230
+الحالات ليست من قبيل قتل الرحمة تعتبر بعض الحالات
+
+201
+00:19:10,230 --> 00:19:15,450
+التي يراها البعض قتل الرحمة يعني كمثلة نزل الأجهزة
+
+202
+00:19:15,450 --> 00:19:21,430
+.. نزل الأجهزة عن المريض الذي بين جثينه الميت
+
+203
+00:19:21,430 --> 00:19:28,180
+سريرياالميؤوس من حياته الذي قرر الأطباء بوفاته
+
+204
+00:19:28,180 --> 00:19:35,420
+سريريا وهو يحيى الآن فقط على الأجهزة هل يترك هل
+
+205
+00:19:35,420 --> 00:19:41,970
+يسمحبنزع الأجهزة وإذا نزعت هل يعتبر قتل الرحمة
+
+206
+00:19:41,970 --> 00:19:46,330
+جمهور العلماء نعم الأكثرية نعم لكن قرضاوي له نظرة
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+207
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+خاصة حقيقة وقال وربما وجد معاه عدد من العلماء قال
+
+208
+00:19:51,490 --> 00:19:56,290
+لأ انا هذا والله انا ماباعتبروش قتل الرحمةفقط لكن
+
+209
+00:19:56,290 --> 00:20:03,850
+بعد أن يقرر العلماء أن هذا الشخص ميؤوس طبيا طبيا و
+
+210
+00:20:03,850 --> 00:20:09,330
+لا في كل شئ له فيه معجزة الله قادر على كل شيء طبيا
+
+211
+00:20:09,330 --> 00:20:18,220
+ميؤوس من شفاءهفانا يعني و أن ال .. هذه الجهاز شأنه
+
+212
+00:20:18,220 --> 00:20:24,860
+نزع عنه زي مسألة الامتناع عن أخذ الحبوب لشخص لا
+
+213
+00:20:24,860 --> 00:20:30,160
+تفيده هذه .. هذا الدواء إلا في تسكين الألم فقط في
+
+214
+00:20:30,160 --> 00:20:34,560
+تسكين الألم لا يفيده ما هو الواحد كتير مرات باخد
+
+215
+00:20:34,560 --> 00:20:39,500
+دوة و هو بس لتسكين الألم لكنه لا .. لا يس .. لا
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+216
+00:20:39,500 --> 00:20:44,810
+ينتج عنه أي فائدة حقيقيةبل يمكن أن يكون ضرره أكبر
+
+217
+00:20:44,810 --> 00:20:48,950
+من نفعه يعني يسكن الألم ويضاعف ال .. ال .. ال ..
+
+218
+00:20:48,950 --> 00:20:55,110
+ال .. ويضاعف الداء ويضاعف المرض ويقرب الأجل طيب ..
+
+219
+00:20:55,110 --> 00:20:59,370
+طب إذا كان يا أخوات المسلمين أو علماء المسلمين
+
+220
+00:20:59,370 --> 00:21:03,790
+يعني لم يقولوا أو لم يجمعوا على وجوب أخذ الدواء في
+
+221
+00:21:03,790 --> 00:21:11,490
+حالة كونه نافعا نافعا ضنيا خاصة بينجوسينبل قالوا
+
+222
+00:21:11,490 --> 00:21:14,950
+باستحبابه أو بإباحته ولم يقول بوجوبه إلا العدد
+
+223
+00:21:14,950 --> 00:21:18,270
+القليل يعني اختلفوا منهم من قال بوجوب فئة ومنهم
+
+224
+00:21:18,270 --> 00:21:24,990
+أكثرهم قالوا بالاستحباب إذا كان راجح للنفع وربما و
+
+225
+00:21:24,990 --> 00:21:32,890
+بعضهم قال بالإباحة فكيف بما إذا كان هذا الدواء لا
+
+226
+00:21:32,890 --> 00:21:36,630
+شفاءة أو لا فائدة منه سواء التسكين
+
+227
+00:21:39,750 --> 00:21:46,890
+فهل يُعقل أنه جرّم من يمتنع عن إعطاء هذا المريض
+
+228
+00:21:46,890 --> 00:21:52,110
+يعني حبوب التسكين أو أنه جرّم المريض نفسه هو هاي
+
+229
+00:21:52,110 --> 00:21:59,130
+نظرته أن هذا لكن هو وغيره عندما يكون الدواء أو
+
+230
+00:21:59,130 --> 00:22:06,950
+المنفسة هذهيمكن أن يرجى معها الشفاء يكون قاتل هنا
+
+231
+00:22:06,950 --> 00:22:09,710
+في هذه الحالة هو ممكن يكون قاتل وهذا ما لا يقوله
+
+232
+00:22:09,710 --> 00:22:13,370
+القرضاوي القرضاوي بيقول في حالات معينة حيث لا يرجى
+
+233
+00:22:13,370 --> 00:22:18,030
+الشفاء وتكون هذه المنفسة فقط تطويل المعاناة وتطويل
+
+234
+00:22:18,030 --> 00:22:22,730
+فرطة المرض عليه فمجرد تسكين لا فائدة منها فخياسا
+
+235
+00:22:22,730 --> 00:22:26,710
+على حكم التداوي وهذا من باب او لأنه لا يبتدأ لو
+
+236
+00:22:26,710 --> 00:22:33,010
+واحد لم يأخذ الدواء ومات بنقوله أنت انتحرتلم نسمع
+
+237
+00:22:33,010 --> 00:22:37,450
+بهذا في فقه الأولين ولا في فقه المعاصرين لا يقال
+
+238
+00:22:37,450 --> 00:22:41,870
+مثله هذا يمكن أنا بقدر أقول إلا إذا كان هناك عند
+
+239
+00:22:41,870 --> 00:22:49,890
+من يقولون بالوجوب وكان الدواء من المقطوعأنه يكون
+
+240
+00:22:49,890 --> 00:22:54,270
+معاه الشفاء وهذا نادر ما يكون .. نادر ما يكون يمكن
+
+241
+00:22:54,270 --> 00:22:58,650
+أن أعتبره في هذه الحالة منتحرا أو إلى غير ذلك وعلى
+
+242
+00:22:58,650 --> 00:23:03,230
+رأي البعض فقط لكن عندما يكون مظنونا وهذا .. وهذه
+
+243
+00:23:03,230 --> 00:23:07,810
+صفة عامة الأدوية مظنونة أجسام الناس بتختلف من
+
+244
+00:23:07,810 --> 00:23:12,170
+الشخص ممكن أنا أطيب وانت ماتبيش على نفس الدواءو ..
+
+245
+00:23:12,170 --> 00:23:15,910
+و .. و .. و ان كل واحد عنده قدرات معينة و مناعة
+
+246
+00:23:15,910 --> 00:23:20,190
+شكل مستواه بيختلف عن الآخر و هذا بيسببله أضرار
+
+247
+00:23:20,190 --> 00:23:24,470
+جنبية و هذا ما بيسببله أضرار جنبية فالأدوية مضمونة
+
+248
+00:23:24,470 --> 00:23:28,350
+يعني في نتائجها في الآخر الشافي هو الله سبحانه
+
+249
+00:23:28,350 --> 00:23:32,490
+وتعالى ولذلك حتى البعض اعتبر الدوائسي مكروم و
+
+250
+00:23:32,490 --> 00:23:37,970
+الأصل عن يصفر الإنسانعلى ما .. وإن كنا لا نرجح هذا
+
+251
+00:23:37,970 --> 00:23:42,130
+لكنه رأي يبقى يعني بمعنى آخر أننا لا نستطيع أن
+
+252
+00:23:42,130 --> 00:23:46,350
+نقول أن من يمنع من أخذ الألاج يعتبره يعني عاصيا أو
+
+253
+00:23:46,350 --> 00:23:51,630
+قاتلا لنفسه أو إلى .. إلى .. إلى غير ذلك وهكذا ومن
+
+254
+00:23:51,630 --> 00:23:56,050
+هذا المنطلق كانت رؤية الشيخ القرضاوي في هذا وبيه
+
+255
+00:23:56,130 --> 00:24:00,710
+وهذه تفكّلنا على إقرأ لغزا أو إشكالا في مسألة
+
+256
+00:24:00,710 --> 00:24:04,950
+التعامل مع هؤلاء الذين يعني فمرهم بهم الشهور
+
+257
+00:24:04,950 --> 00:24:10,890
+والسنون وهم يعيشون على المننفسة أو على الأجهزة
+
+258
+00:24:10,890 --> 00:24:16,210
+المختلفة بهذا الرأي وإن كنت أقول إن والله عندما
+
+259
+00:24:16,210 --> 00:24:20,410
+تتوفر الإمكانيات ينبغي يعني الأحوط أن تبقى الأحوط
+
+260
+00:24:20,410 --> 00:24:24,340
+أن تبقىلكن عندما لا تتوفر الإمكانيات يكون رأي
+
+261
+00:24:24,340 --> 00:24:29,380
+الإقتراضاه في هذه الحالة يحل الإشكالية على أية حال
+
+262
+00:24:29,380 --> 00:24:36,700
+هذه يعني هذا ختام حديثنا حول فقه أو حول قتل الرحمة
+
+263
+00:24:36,700 --> 00:24:41,820
+لنتقل للحديث ولو بسرعة في ما تبقى من وقت عن فقه
+
+264
+00:24:41,820 --> 00:24:47,390
+الأقليةالحقيقة يا أخوات هذا موضوع آخر جديد من
+
+265
+00:24:47,390 --> 00:24:55,210
+الموضوعات المسائل أو القضايا المعاصرة تتعلق
+
+266
+00:24:55,210 --> 00:25:01,270
+بالجانب السياسي أو بالمجال السياسة ذلك أننا قلنا
+
+267
+00:25:01,270 --> 00:25:05,970
+عندما بدأنا نتحدث في هذا المساق أن قضايا المعاصرة
+
+268
+00:25:05,970 --> 00:25:10,810
+هذه قضايا الفقه المعاصرة ليستمحصورة في مجال واحد
+
+269
+00:25:10,810 --> 00:25:15,610
+ولا في بوابة واحدة حتى العبادات نفسها دخلتها
+
+270
+00:25:15,610 --> 00:25:20,430
+دخلتها وهي التي في الأصل أن تكون موقوفة تعبدية
+
+271
+00:25:20,430 --> 00:25:24,570
+وتوقيفية وإلى غير ذلك حتى هذه لها علاقة بالقضايا
+
+272
+00:25:24,570 --> 00:25:30,020
+وقمسكنا أمثلة على ذلكفبالتالي فغير مجال العبادات
+
+273
+00:25:30,020 --> 00:25:37,360
+بابه أوسع في أن تدخله القضايا المعاصرة وباب
+
+274
+00:25:37,360 --> 00:25:47,400
+السياسة باب واسع في تجدد القضايااليوم في ظل وجود
+
+275
+00:25:47,400 --> 00:25:54,340
+الأنظمة الجديدة البرلمانات السياسية المختلفة الصور
+
+276
+00:25:54,340 --> 00:26:02,080
+والأنظمة الرئاسية وأنظمة الانتخابات ومشاركة المرأة
+
+277
+00:26:02,080 --> 00:26:07,780
+في الحكم وطريقة الانتخاب والاقتراع اليوم مشاركة
+
+278
+00:26:07,780 --> 00:26:14,220
+المسلمفي .. في الانتخابات في الدول الكافرة ترشيح
+
+279
+00:26:14,220 --> 00:26:21,040
+المسلم نفسه ليكون عضو برلمان في دول كافرة ولا دول
+
+280
+00:26:21,040 --> 00:26:26,280
+معادية يعني احنا المسلمين اللي في داخل فلسطين
+
+281
+00:26:26,280 --> 00:26:32,340
+المحتلة التي تحكمها اسرائيل في .. هناك من .. يعني
+
+282
+00:26:32,340 --> 00:26:36,940
+من المسلمين من .. هم في .. تحت أرواق الكنسة
+
+283
+00:26:36,940 --> 00:26:43,000
+الإسرائيليةأه من عام 1948 والذين كانوا بالأمس يدا
+
+284
+00:26:43,000 --> 00:26:50,440
+بيد مع الشيخ رائد صلاح يخرجون ضد قرار إسرائيل
+
+285
+00:26:50,440 --> 00:26:55,680
+القرار الإسرائيلي بحظر الحركة الإسلامية هؤلاء هم
+
+286
+00:26:55,680 --> 00:27:02,970
+أعضاء كنيسة إسرائيليافلسطينيين مسلمين اجتهدوا بغض
+
+287
+00:27:02,970 --> 00:27:07,330
+النظر عن اجتهادهم ان كانوا صائبا او خاطئا ودخلوا
+
+288
+00:27:07,330 --> 00:27:10,830
+في الكنيسة بقصد تحقيق المصالح لهذه الأقلية
+
+289
+00:27:10,830 --> 00:27:13,510
+الموجودة التي عادة أصبحت أقلية في المجتمع
+
+290
+00:27:13,510 --> 00:27:20,370
+الإسرائيلي اليهودي هناك وهكذا
+
+291
+00:27:20,370 --> 00:27:30,510
+يعني هناك اذاقضايا عديدة تحت مضلة المجال السياسي
+
+292
+00:27:30,510 --> 00:27:38,030
+ومن هذه القضايا قضية فقه الأقليات ماذا يقصد بفقه
+
+293
+00:27:38,030 --> 00:27:47,040
+الأقليات وما هو الحكم في أن يكون هناك فقه خاصهل
+
+294
+00:27:47,040 --> 00:27:52,780
+يقبل أن يكون هناك فقه خاص لبعض المسلمين مختلف عن
+
+295
+00:27:52,780 --> 00:27:59,960
+الآخرين؟ هل الإسلام يتجزأ؟ بمجرد أن يقال فقه
+
+296
+00:27:59,960 --> 00:28:07,880
+أقلياتتتوارد خواطر وتساؤلات متعددة يا أخوان تتوارد
+
+297
+00:28:07,880 --> 00:28:14,380
+فقه أقليات هو فقه مش واحد هو المسلمين مش كلهم يعني
+
+298
+00:28:14,380 --> 00:28:20,020
+الأحكام اللتي طبقوا عليهم واحدة بغض النظر أينما
+
+299
+00:28:20,020 --> 00:28:27,160
+كانوا أليس دينه الإسلام دين عالمي ليحكم المسلمين
+
+300
+00:28:27,160 --> 00:28:33,140
+حيثما وجدوا وحيثما حلوا وحيثما ارتحلواهذه
+
+301
+00:28:33,140 --> 00:28:36,700
+التساؤلات ومن هنا أيها الأخوات كان لابد من أن نعرف
+
+302
+00:28:36,700 --> 00:28:43,420
+هل يسوغ؟ هل يجوز؟ هل يباح؟ هل يمكن أن يكون وفق؟ هل
+
+303
+00:28:43,420 --> 00:28:53,840
+يشرع أن مخصصة فقها وأحكاما خاصة للأقليات المسلمة
+
+304
+00:28:53,840 --> 00:29:01,370
+التي تعيشوا في بلاد الكفر؟في الشرق والغرب أم أنه
+
+305
+00:29:01,370 --> 00:29:08,110
+لا يجوز ذلك وأن ما يحكمهم من أحكام وفقه يجب أن
+
+306
+00:29:08,110 --> 00:29:14,250
+يكون هو هو الفقه الذي يحكم المسلمين في عقر دارهم
+
+307
+00:29:14,250 --> 00:29:20,190
+وفي المجتمعات المسألة محل خلاف وهي ما سنحاول أن
+
+308
+00:29:20,190 --> 00:29:23,750
+نفصلها المرة القادمة ان شاء الله تعالى
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/VLfL7KupIwE_postprocess.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/VLfL7KupIwE_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..bd9ccd73eeb64d77c7a55028651cdeaf07804634
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/VLfL7KupIwE_postprocess.srt
@@ -0,0 +1,1460 @@
+1
+00:00:20,440 --> 00:00:23,700
+بسم الله الرحمن الرحيم الحمد لله والصلاة والسلام
+
+2
+00:00:23,700 --> 00:00:29,730
+على رسول الله وبعناهاليوم نتحدث عن مسألة جديدة من
+
+3
+00:00:29,730 --> 00:00:34,150
+المسائل المعاصرة وهي مسألة متعلقة بفقه الأعقلية
+
+4
+00:00:34,150 --> 00:00:39,010
+احنا حقيقة تكلمنا عن فقه الأعقلية بشكل عام وتكلمنا
+
+5
+00:00:39,010 --> 00:00:47,940
+عن أهم القضايا التيتهم الأقليات وتكثر
+
+6
+00:00:47,940 --> 00:00:57,820
+أسئلتهم واستفتاءاتهم حولها وقلنا بأن المنطلق الذي
+
+7
+00:00:57,820 --> 00:01:03,820
+ينطلق منه العلماء في بيان الأحكام والفتاوى
+
+8
+00:01:03,820 --> 00:01:08,080
+للأقليات المسلمة الذين يعيشون في دول الغرب أو
+
+9
+00:01:08,080 --> 00:01:14,490
+الدول الغيرالمسلمة هو التيسير هي فتاوة التيسير
+
+10
+00:01:14,490 --> 00:01:21,150
+التي تمكنهم من التعايش وفي نفس الوقت تثبتهم على
+
+11
+00:01:21,150 --> 00:01:28,530
+دينهم وتساعدهم على الإبقاء والمحافظة على هويتهم
+
+12
+00:01:28,530 --> 00:01:35,050
+الإسلاميةلكن حقيقة إضافة إلى كل هذه القضايا التي
+
+13
+00:01:35,050 --> 00:01:39,570
+ذكرناها أو لعل الأهم من كل هذه القضايا التي
+
+14
+00:01:39,570 --> 00:01:45,370
+ذكرناها مسألة التجنس هذه المسألة هي التي يبدأ معها
+
+15
+00:01:45,370 --> 00:01:52,270
+مشوار وطريق الأقليات حقيقة اللي هي ايه مسألة
+
+16
+00:01:52,270 --> 00:01:59,210
+التجنس ذلك أن الإنسان يعني في هذه الدنيا وفي هذا
+
+17
+00:01:59,210 --> 00:02:07,220
+العالميعني يتنقل من بلد إلى بلد ومن دولة إلى دولة
+
+18
+00:02:07,220 --> 00:02:12,360
+وفي النهاية له
+
+19
+00:02:12,360 --> 00:02:17,920
+أن يسافر وله حق التنقل والسفر هذا حق تكفله الشرائع
+
+20
+00:02:17,920 --> 00:02:26,640
+الدولية كلها لكن في النهاية هو له بلد ينتمي له هو
+
+21
+00:02:26,640 --> 00:02:32,370
+له جنسيةفيما يسمى اليوم في مصطلح الناس اليوم له
+
+22
+00:02:32,370 --> 00:02:41,650
+جنسيةلدولة معينة هذا سوري وهذا مصري وهذا فلسطيني
+
+23
+00:02:41,650 --> 00:02:47,170
+وهذا أمريكي وهذا صيني وهذا هندي وهذا بمنطلق اليوم
+
+24
+00:02:47,170 --> 00:02:55,970
+وإن كنا هذه التقسيمات لا نؤيدها كثيرا فنحن في
+
+25
+00:02:55,970 --> 00:03:02,950
+الأساس كمسلمين كلنا جنسية واحدة جنسيتنا هي الإسلام
+
+26
+00:03:03,750 --> 00:03:10,270
+حقيقة بالاصلا لكن وفق معايير اليوم ووفق جنسيات
+
+27
+00:03:10,270 --> 00:03:16,010
+اليوم يعني وهذا واقع لابد أن نلتفت إليه عند بيان
+
+28
+00:03:16,010 --> 00:03:20,790
+الحكم الشرعي لما يترتب عليه من التزامات ومن حقوق
+
+29
+00:03:20,790 --> 00:03:23,730
+ومن واجبات ومن
+
+30
+00:03:25,450 --> 00:03:31,350
+منح وموانع وإلى ذلك هذا واقع ولابد أن يراعيه ونحن
+
+31
+00:03:31,350 --> 00:03:37,970
+في حديثنا في البداية عن قضايا المعاصرة ومن هو
+
+32
+00:03:37,970 --> 00:03:42,590
+المجتهد وماذا ينبغي على المجتهد أن يراعي من بوابط
+
+33
+00:03:42,590 --> 00:03:47,470
+قولنا أن الواقع الذي يعيشه هو المجتهد ويعيشه الناس
+
+34
+00:03:47,470 --> 00:03:53,230
+الذين يريدون أن يتعرفوا على حكم لابد أن يكون بين
+
+35
+00:03:53,230 --> 00:04:02,290
+يدي المجتهدومراعة الواقع والعُرف والحالة التي
+
+36
+00:04:02,290 --> 00:04:07,230
+عيشها الناس لابد أن تُأخذ بعين الاعتبار عند بيان
+
+37
+00:04:07,230 --> 00:04:10,890
+الحكم الشرعي فيما لم يرد فيه نص
+
+38
+00:04:14,100 --> 00:04:19,540
+التجنس هذه أو مسألة الجنسية التي عامة اليوم أصبح
+
+39
+00:04:19,540 --> 00:04:25,140
+لكل بلد جنسيته أو لكل قوم جنسيتهم اللتي ينتمون
+
+40
+00:04:25,140 --> 00:04:28,160
+اليها و اللتي ربما يعتزون بيها لكن في الوقت نفسه
+
+41
+00:04:28,160 --> 00:04:33,840
+نرى إضافة إلى ذلك أو إلى جانب ذلك رغم أن اليوم كل
+
+42
+00:04:33,840 --> 00:04:39,760
+مجتمع ينتمي لدولة و يأخذ
+
+43
+00:04:41,520 --> 00:04:46,600
+هذه الجنسية لهذه الدولة لكن في كثير من الأحوال يا
+
+44
+00:04:46,600 --> 00:04:52,260
+أخوات فإن بعض الأفراد بل بعض يعني سواء على صعيد ..
+
+45
+00:04:52,260 --> 00:04:56,420
+على هيد أفراد أو حتى على صعيد جماعات يرتحلون
+
+46
+00:04:56,420 --> 00:05:03,340
+ويلجأون من بلد .. من بلادهم إلى بلاد أخرى
+
+47
+00:05:03,340 --> 00:05:09,320
+بغية الاستقرار البحث عن الأمان البحث عن المال
+
+48
+00:05:09,320 --> 00:05:15,900
+البحث عنالرفاهية البحث عن الحرية إلى غير ذلك من
+
+49
+00:05:15,900 --> 00:05:25,020
+دواعي التنقل والترحال ونحن في زمان نلاحظ ونعايش
+
+50
+00:05:25,020 --> 00:05:31,480
+فيه هذا الوضع بشكل واضح جدا خاصة بعد ما حدث في
+
+51
+00:05:31,480 --> 00:05:38,880
+مجتمعنا العربي مختلف دوله من ثورات وإلى غير ذلك
+
+52
+00:05:39,200 --> 00:05:46,780
+أعقبها دمار وخراب وعدم استقرار في البلدان وحتى قبل
+
+53
+00:05:46,780 --> 00:05:51,440
+الثورات هذه بسبب الدكتورية وبسبب الهيمنة وبسبب
+
+54
+00:05:51,440 --> 00:05:57,340
+الظلم وبسبب الملاحقات لبعض أصحاب الرأي وأصحاب
+
+55
+00:05:57,340 --> 00:06:04,400
+العقول الذين يريدون لبلادهم الحريات ويريدون
+
+56
+00:06:04,400 --> 00:06:12,270
+لبلادهم التطور بما لايوافقوا عقول الرؤساء والحكام
+
+57
+00:06:12,270 --> 00:06:20,150
+يعني نجد أنهم يتركون أو يرغمون باختيارهم أو يرغمون
+
+58
+00:06:20,150 --> 00:06:26,030
+على الترك ليهجروا بلادهم إلى بلاد أخرى حتى إذا
+
+59
+00:06:26,030 --> 00:06:31,070
+انتقلوا إلى تلكم البلاد كما قلت يعني واجهوا
+
+60
+00:06:31,070 --> 00:06:39,090
+التقييد فيما يُعطون من حقوق أو فيما ينبغي أن
+
+61
+00:06:39,090 --> 00:06:45,050
+يُعطوا من حقوق ذلك أن هذه الحقوق التي تُعطيها
+
+62
+00:06:45,050 --> 00:06:51,470
+الدولة الواسعة غالبا ما تُعطاه إلى المواطنين إلى
+
+63
+00:06:51,470 --> 00:06:59,040
+المواطنينالذين ينتمون لهذه الدولة وفق عقد يسمى
+
+64
+00:06:59,040 --> 00:07:05,080
+الجنسية وفق رابطة تسمى رابطة الجنسية رابطة سياسية
+
+65
+00:07:05,080 --> 00:07:10,040
+و رابطة قانونية تربط بين الشخص أو الفرد و المواطن
+
+66
+00:07:10,040 --> 00:07:17,080
+و بين الدولةعندما يلجأ .. عندما يلجأ غير المواطن
+
+67
+00:07:17,080 --> 00:07:20,840
+الذي لا يملكه .. الذي لم يحصل الجنسية إلى هذا
+
+68
+00:07:20,840 --> 00:07:28,940
+البلد يشعر بقيود كثيرة ويشعر كذلك بغمط للحكوم
+
+69
+00:07:28,940 --> 00:07:33,200
+ويصعب عليه .. تصعب عليه الحياة وتصعب عليه التعايش
+
+70
+00:07:33,200 --> 00:07:36,980
+.. تصعب عليه التعايش ويصعب عليه أشياء كثيرة يعني
+
+71
+00:07:36,980 --> 00:07:43,510
+.. حتى التكاليف المادية يعني في .. بينماللمواطنين
+
+72
+00:07:43,510 --> 00:07:47,770
+الحق في الاستفادة من المرافق العامة من المستشفيات
+
+73
+00:07:47,770 --> 00:07:51,450
+مجانا ربما هو من المدارس و من الجامعات او برسوم
+
+74
+00:07:51,450 --> 00:07:55,710
+رمزية في كثير من الدول او في القطارات الركون في
+
+75
+00:07:55,710 --> 00:08:01,050
+القطارات العامة و ربما حتى تذاكر السفر تكون
+
+76
+00:08:01,050 --> 00:08:05,910
+بالنسبة للمواطن مختلفة من حيث ثمنها عن الأجنبي او
+
+77
+00:08:05,910 --> 00:08:11,110
+إلى غير ذلككل هذا يلقي بظلاله الصعبة على اللاجئين
+
+78
+00:08:11,110 --> 00:08:18,560
+إلى تلك الدول والذين يريدون انيعني يستمروا في
+
+79
+00:08:18,560 --> 00:08:24,000
+الحياة في هذا البلد ومن هنا تبدأ رحلة البحث عن
+
+80
+00:08:24,000 --> 00:08:28,360
+الجنسية ورحلة البحث عن الجنسية ليس مثلًا مثلة ورقة
+
+81
+00:08:28,360 --> 00:08:34,700
+وإنما مثلًا لماذا تغطي هذه الجنسية من توسعة في
+
+82
+00:08:34,700 --> 00:08:42,520
+الحقوق لهذا الإنسان وإمكانية للتعايش وإمكانية
+
+83
+00:08:43,090 --> 00:08:51,310
+الحرية في تعبير عن رأيه وبناء مستقبله وإلى غير ذلك
+
+84
+00:08:51,310 --> 00:08:54,990
+فلذلك وجدنا
+
+85
+00:08:54,990 --> 00:09:00,670
+الكثير حقيقة ممن يصلون إلى تلك البلاد يحرصون من
+
+86
+00:09:00,670 --> 00:09:06,610
+اللحظة الأولى أو يعني خاصة إذا ما استقر بهم الأمر
+
+87
+00:09:06,610 --> 00:09:13,350
+أو إذا ما قرروا أن يبقوا في تلك البلاديبدأ البحث
+
+88
+00:09:13,350 --> 00:09:22,670
+عن كيف الحصول على الجنسية ليش؟ لكي أستطيع أخذ
+
+89
+00:09:22,670 --> 00:09:28,190
+حقوقي كاملة كسائر المواطنين الذين أعيش و إياهم و
+
+90
+00:09:28,190 --> 00:09:35,690
+معهم و أنا أصبحت واحدا منهم ربما هذا
+
+91
+00:09:35,690 --> 00:09:40,490
+يدل على أن أساسا يا أخواتيعني الرحلة إلى البلاد
+
+92
+00:09:40,490 --> 00:09:45,050
+الأخرى ليس بالضرورة ابتداء أن تكون من أجل الحصول
+
+93
+00:09:45,050 --> 00:09:49,790
+على الجنسية أو من أجل الإقامة المستمرة كثير ..
+
+94
+00:09:49,790 --> 00:09:55,330
+كثيرا ما يذهب الأفراد أو الناس أو الشخص .. الأشخاص
+
+95
+00:09:55,330 --> 00:10:00,290
+الشباب وغير الشباب لل .. لل .. لل .. للبلاد أخرى
+
+96
+00:10:00,290 --> 00:10:05,850
+بقصد التعلم بقصد التجارة بقصد الألاج بقصد السياحة
+
+97
+00:10:06,590 --> 00:10:11,750
+بمقصد متعدد وهو يقصد ان يغيب عاما عامين اربع عوام
+
+98
+00:10:11,750 --> 00:10:16,110
+خمسة عوام شهر شهرين ثم يعود الى بلاده وليس فى باله
+
+99
+00:10:16,110 --> 00:10:21,150
+حقيقة ولا فى عزمه ونواياه ان يحصل على الجنسية ربما
+
+100
+00:10:21,150 --> 00:10:25,410
+يكون مرتاحا ومطمئنا فى بلده ليس بالضرورة كل البلاد
+
+101
+00:10:25,410 --> 00:10:29,690
+الاسلامية و العربية ان يكون فيها يعني تكدر فى
+
+102
+00:10:29,690 --> 00:10:37,370
+العيش ولا ظلم فى التعامل لكن ربما يعنيلكن مع ذلك
+
+103
+00:10:37,370 --> 00:10:47,750
+كله يجدوا بلدا أكثر رفاهية أكثر نظاما وتنظيما أكثر
+
+104
+00:10:47,750 --> 00:10:55,730
+مساحة في الحريات فيميلوا إلى أن يبقى مستقرا
+
+105
+00:10:55,730 --> 00:11:00,610
+ويعيشوا بقية حياته وعصرته في هذا البلد وليس
+
+106
+00:11:00,610 --> 00:11:07,440
+بالضرورة أن يكون الدافع يعني دافعبسبب ظلم سابق أو
+
+107
+00:11:07,440 --> 00:11:14,040
+بسبب هروب أو بسبب بحث عن الأمان أو إلى غير ذلك هذا
+
+108
+00:11:14,040 --> 00:11:20,480
+ممكن يحدث لكن يعني هذه صورة لكن ممكن يكون الدافع
+
+109
+00:11:20,480 --> 00:11:24,380
+اللي ذكرناه هو الأكثر ممكن يكون الدافع لكن الدوافع
+
+110
+00:11:24,380 --> 00:11:28,390
+الأكثريعني قصدي أقول إنه ابتداء ممكن الواحد يروح
+
+111
+00:11:28,390 --> 00:11:33,850
+مايكونش يحصل التجنس لكن بعد .. أو ربما بعد أن سافر
+
+112
+00:11:33,850 --> 00:11:40,450
+قلّي قد صار فيه تغيرات في بلده تغيرات بحيث لو عاد
+
+113
+00:11:40,450 --> 00:11:47,350
+يعني سي .. يرقى في السجن و لو عاد س .. أو سوف تضيء
+
+114
+00:11:47,350 --> 00:11:52,470
+.. لا يستطيع أن يقوم على مصالحه مصالحه ضاعت،
+
+115
+00:11:52,470 --> 00:11:57,570
+تجارته دمرت أو إلى .. إلى غير ذلكو أحيانا حقيقة
+
+116
+00:11:57,570 --> 00:12:03,550
+بيكون من اللحظة الأولى هو رايح عشان يتجنس من
+
+117
+00:12:03,550 --> 00:12:06,490
+اللحظة الأولى اللجوء السياسي يعني من اللحظة الأولى
+
+118
+00:12:06,490 --> 00:12:10,170
+يعني كما نرا المهاجرين السوريين اليوم أو غير
+
+119
+00:12:10,170 --> 00:12:13,330
+السوريين و العراقيين و اللبنانيين و الأفريقا
+
+120
+00:12:13,330 --> 00:12:22,490
+يذهبون الواحد يخرج من بلده يمزق أساسا كل الوثائق
+
+121
+00:12:22,490 --> 00:12:30,460
+الشخصية بنبعتهيرقي بنفسه إلى هذا البلد القاعا
+
+122
+00:12:30,460 --> 00:12:35,410
+ليكرههم على إعطاءه الجنسية هذا يحدث أيضايعني هاي
+
+123
+00:12:35,410 --> 00:12:38,970
+أنا بينكم و ده برحل و هذا يحدث و غالبا كثير من
+
+124
+00:12:38,970 --> 00:12:43,210
+الدول الأجنبية يعني تستقبل هؤلاء وتعطيهم بتعقاد
+
+125
+00:12:43,210 --> 00:12:48,130
+شخصية جديدة وبعد أوقات معينة تختلف من دولة إلى
+
+126
+00:12:48,130 --> 00:12:51,830
+دولة بعد سنة سنتين شهر شهرين ربما تجنسهم سواء من
+
+127
+00:12:51,830 --> 00:12:57,450
+الشهر الأول أو بعد عام أو بعد عامين أو إلى غيرالى
+
+128
+00:12:57,450 --> 00:13:02,090
+غير ذلك فالدوافع يطلع الأخوات للتجنس كثيرة و
+
+129
+00:13:02,090 --> 00:13:11,270
+متعددة لكن في النهاية نقول انه يجمع هؤلاء و أولئك
+
+130
+00:13:11,270 --> 00:13:16,910
+جميعا بغض النظر عن الدافع يجمعهم انهم يرغبون في
+
+131
+00:13:16,910 --> 00:13:21,850
+النهاية في الاستقرار و الاستمرار في الحياة في هذا
+
+132
+00:13:21,850 --> 00:13:22,410
+البلد
+
+133
+00:13:25,660 --> 00:13:29,300
+بغض النظر عن ما إذا كان هذا القرار جاء من اللحظة
+
+134
+00:13:29,300 --> 00:13:32,960
+الأولى أو جاء متأخرا بعد مضي سنين في كتير بني اللي
+
+135
+00:13:32,960 --> 00:13:38,480
+راحوا .. راحوا يتعلموا بعد أربع .. خمس سنين يعني و
+
+136
+00:13:38,480 --> 00:13:43,640
+خاصة إن الدول تسمح بعد مضي بقاء خمس سنين للأجنبي
+
+137
+00:13:43,640 --> 00:13:47,560
+في بلدها أن تعطيه الجنسية إذا ما كانت خمس سنوات
+
+138
+00:13:47,560 --> 00:13:52,320
+متواصلة مثلا أو يعني بشكل أو بآخر تعطيه الجنسية
+
+139
+00:13:54,200 --> 00:13:58,920
+فيوازن فيجد إن حياته هنا ربما أفضل وسيعطيهم مجال
+
+140
+00:13:58,920 --> 00:14:04,500
+للرفاهية و للحياة الأمنة و الواعدة ربما أكثر
+
+141
+00:14:04,500 --> 00:14:10,640
+فيختار البقاء في هذه البلدأحيانا و هكذا أحيانا
+
+142
+00:14:10,640 --> 00:14:14,080
+يولد له أولاد هم بطبيعة الحال هياخدوا الجنسية لأن
+
+143
+00:14:14,080 --> 00:14:17,720
+الجنسية تقعد في معظم دول العالم أن الأجنبي حتى لو
+
+144
+00:14:17,720 --> 00:14:23,540
+كان أجنبيا يعني اللي أولد له في بلد آخر فولادته في
+
+145
+00:14:23,540 --> 00:14:27,620
+.. مجرد أن يولد هذا الولد في البلد بياخد الجنسية
+
+146
+00:14:27,620 --> 00:14:31,580
+حتى في أمريكا أصعب الدول التي تعطي و تضع ضوابط و
+
+147
+00:14:31,580 --> 00:14:37,630
+قيود للجنسيات الذي يولد فيهابياخد جنسي و لو أبوه و
+
+148
+00:14:37,630 --> 00:14:41,370
+أمه من غير الأمريكان و لذلك هم بيمنعوا المرأة
+
+149
+00:14:41,370 --> 00:14:44,530
+الحامل إذا كانت في الأشهر الأخيرة إذا كانت جاي
+
+150
+00:14:44,530 --> 00:14:48,530
+للزيارة إنها تيجي على بلادهم إذا كانت من غير ..
+
+151
+00:14:48,530 --> 00:14:53,930
+خوفا من أن .. لأنهم هم يريدون الحد لكن .. أحنا
+
+152
+00:14:53,930 --> 00:15:03,170
+بحكي بشكل عام ف .. فلذلكيعني احنا الآن فمسألة
+
+153
+00:15:03,170 --> 00:15:06,490
+التجنس
+
+154
+00:15:06,490 --> 00:15:12,690
+هذه اليوم أصبحت ظاهرة حقيقة يعني يمكن تزداد يوما
+
+155
+00:15:12,690 --> 00:15:17,110
+بعد يوم انتشارا ويبقى السؤال
+
+156
+00:15:19,970 --> 00:15:25,890
+يعني ما حكم التجنس بجنسية أجنبية خاصة عندما يكون
+
+157
+00:15:25,890 --> 00:15:30,290
+التجنس بجنسية دولة غير مسلمة
+
+158
+00:15:34,960 --> 00:15:41,720
+زي ما قلنا الجنسية هي عبارة عن يعني صفة تعبر مدى
+
+159
+00:15:41,720 --> 00:15:47,420
+عن انتماء هذا الفرد لهذه الدولة صفة معينة تعبر عن
+
+160
+00:15:47,420 --> 00:15:53,260
+انتماء أو تدل على انتماء الشخص يعني لدولة معينة
+
+161
+00:15:53,260 --> 00:15:58,880
+تقول هذا جنسي سوري يعني هذا على طول بتاعه يعني هذا
+
+162
+00:15:58,880 --> 00:16:06,850
+سوري يعني أو هذا فلسطين أو ..قبل بيان الحكم هناك
+
+163
+00:16:06,850 --> 00:16:12,690
+أشياء لابد أن نعرفها يعني أولا عندما نتحدث هنا عن
+
+164
+00:16:12,690 --> 00:16:17,870
+حكم الجنسية نقصده على وجه الخصوص التجنس بجنسية
+
+165
+00:16:17,870 --> 00:16:23,830
+أجنبية غير مسلمة ذلك أن تجنس المسلم بأي جنسية من
+
+166
+00:16:23,830 --> 00:16:28,570
+جنسيات دول الوطن العربي والإسلامي لا إشكال فيه
+
+167
+00:16:30,450 --> 00:16:36,890
+والأصل .. والأصل أنه احنا كعارة أن هذه الحدود التي
+
+168
+00:16:36,890 --> 00:16:42,090
+أفرزت تلك الجنسيات هذه لا .. لا يعني طارقة ولا
+
+169
+00:16:42,090 --> 00:16:46,250
+اعتبار لها ونحن ضدها والأصل هو أن المسلمين كلهم
+
+170
+00:16:46,250 --> 00:16:51,520
+جنسية واحدة جنسية الإسلامأبي الإسلام لا أبي ليه
+
+171
+00:16:51,520 --> 00:16:55,440
+سواء يعني الأصل هذا مسلم الذي يميز يعني إذا كان
+
+172
+00:16:55,440 --> 00:17:00,020
+الناس قد توافق اليوم في هذا العالم أن هذا أمريكي و
+
+173
+00:17:00,020 --> 00:17:04,220
+هذا بلجيكي و هذا مصري و هذا سوري و إلى غير ذلك و
+
+174
+00:17:04,220 --> 00:17:09,160
+أن هذا .. لكن الأصل أن المعيار هذا مسلم و هذا غير
+
+175
+00:17:09,160 --> 00:17:15,180
+مسلمهذا الذي نعرفه في شريعتنا وفي الأصل لكن كما
+
+176
+00:17:15,180 --> 00:17:20,280
+قلت ونحن نضع هذا المعيار لا نغفل المعايير التي
+
+177
+00:17:20,280 --> 00:17:25,000
+تعرف عليها الناس اليوم مع ما يترتب عليها من حقوق
+
+178
+00:17:25,000 --> 00:17:30,900
+وواجبات ولابد أن يكون لها اعتبار عند إصدار الحكم
+
+179
+00:17:30,900 --> 00:17:37,610
+الشرعيلابد في ذلك احنا .. و بالمناسبة .. يعني مثل
+
+180
+00:17:37,610 --> 00:17:41,170
+.. اذا هذه نقطة .. نقطة الثانية يعني تجنس بجنسية
+
+181
+00:17:41,170 --> 00:17:44,930
+مسلمة ان يكون فلسطين يصير مصري و لا مصري ياخد
+
+182
+00:17:44,930 --> 00:17:48,730
+جنسية فلسطينية و لا جزائري و لا عراقي لا إشكلة في
+
+183
+00:17:48,730 --> 00:17:54,970
+ذلك إلا في حالة واحدة انا
+
+184
+00:17:54,970 --> 00:18:01,990
+بحكي المسلم إلا في حالة واحدة إذا كانهذا التجنس من
+
+185
+00:18:01,990 --> 00:18:08,930
+بلد مسلم لبلد أخر أو لبلاد أخرى مسلمة الأصل مصموم
+
+186
+00:18:08,930 --> 00:18:19,230
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+
+320
+00:29:58,250 --> 00:30:04,470
+فلا بأس احنا هذه أمور شكلية مصري سوري فلسطيني مش
+
+321
+00:30:04,470 --> 00:30:10,670
+إشكال لكن في اللحظة اللي بده يحصل فيها تغيير ليه؟
+
+322
+00:30:10,770 --> 00:30:16,650
+أو تحقيق الأهداف الأعداء اليهود شمهون بيرس يعني
+
+323
+00:30:16,650 --> 00:30:21,190
+يمكن كل قسمته اللقاء اللي حصل اللي صار في الجنزيرة
+
+324
+00:30:21,190 --> 00:30:28,150
+مع جمال ريان ومن ضمنه جمال ريان بيسأله بيسأل شمهون
+
+325
+00:30:28,150 --> 00:30:34,210
+بيرس بقوله انت قاعد في أرضي انت قاعد في أرضي انا
+
+326
+00:30:34,210 --> 00:30:39,080
+الف دلوقتي اللي في يافاونيف وانت جاعد فيها قالله
+
+327
+00:30:39,080 --> 00:30:42,960
+ان هذي بلدنا وانتوا هاي بلدكوا العرب روحوا كلكوا
+
+328
+00:30:42,960 --> 00:30:47,240
+هناك على البلد العربية فدهي بلدكوا واحنا هاي بلدنا
+
+329
+00:30:47,240 --> 00:30:54,160
+فهي هم يريدون أن يفرجوا هذا البلد من كل فلسطيني
+
+330
+00:30:54,160 --> 00:30:57,340
+هذا ما أعرفه فالمساعد عليه حقيقة
+
+331
+00:31:01,030 --> 00:31:07,150
+ربما يُفتى بتحريمها في هذه الحالة بحسب يعني العمل
+
+332
+00:31:07,150 --> 00:31:14,190
+على .. بحسب ما .. أو بحسب القصرة أو القلة يعني
+
+333
+00:31:14,190 --> 00:31:18,090
+وبحسب الأثر الذي درتب عليه هذا الأمر على كل
+
+334
+00:31:18,090 --> 00:31:23,860
+الأحوالأحنا يعني هذا بشكل عام لكن أنا بدي أقول شغل
+
+335
+00:31:23,860 --> 00:31:28,480
+قبل ما أنهي و أقول خلاص لكن بدي أقول شغل يا أخوات
+
+336
+00:31:28,480 --> 00:31:34,840
+أنه التجنس هذا و الحكم المترتب عليه مسألة تعتبر من
+
+337
+00:31:34,840 --> 00:31:38,880
+مسائل المعاصرة لم يتحدث فيها العلماء علماء
+
+338
+00:31:38,880 --> 00:31:44,520
+المسلمين قديما بوضوح و بصراحة تعتبر من مسائل
+
+339
+00:31:44,520 --> 00:31:52,820
+المعاصرة لكن علماءناتحدثوا عن مسألة شبيهة بمسألة
+
+340
+00:31:52,820 --> 00:32:01,600
+التجنس ولكن بشكل معكوس قالوا وهي لجوء غير المسلمين
+
+341
+00:32:01,600 --> 00:32:08,210
+إلى المسلمين فيما يُعرف بعقد الأمانعقد الأمانة أو
+
+342
+00:32:08,210 --> 00:32:11,490
+الاستئمام هذا العقد عرفه المسلمون منذ اللحظة
+
+343
+00:32:11,490 --> 00:32:15,330
+الأولى وصُطر في كتاب ربنا وانا احد من المشركين
+
+344
+00:32:15,330 --> 00:32:20,490
+استجارك فاجرح حتى يسمع كلام الله ثم أبلغه مأمنة
+
+345
+00:32:20,490 --> 00:32:25,530
+يعني احنا كمسلمين عرفنا هذا لكنهو إيش اللي خلّى
+
+346
+00:32:25,530 --> 00:32:31,390
+المسلمين اليوم يهجروا بلادهم إلا ما وجده من
+
+347
+00:32:31,390 --> 00:32:37,310
+الأسباب والدوافع لكن لم يكن كأن اللي يتصور أن يهجر
+
+348
+00:32:37,310 --> 00:32:43,850
+المسلمونبلادهم إلى غير بلاد المسلمين لأن بلاد
+
+349
+00:32:43,850 --> 00:32:50,210
+المسلمين كانت بلاد عدل و بلاد فطور و بلاد استقرار
+
+350
+00:32:50,210 --> 00:32:56,510
+و إلى غير ذلك ولذلك الآخر هو الذي كان يلتج إلينا و
+
+351
+00:32:56,510 --> 00:33:02,380
+لاحظوا أهل الذمة عموما من يهود و نصارىيعني يعيشون
+
+352
+00:33:02,380 --> 00:33:06,160
+بيننا ولهم حق المواطنة تماما كما هو معروف في
+
+353
+00:33:06,160 --> 00:33:11,080
+الجنسية اليوم لهم حق المواطنة كما المسلمين لهم
+
+354
+00:33:11,080 --> 00:33:17,140
+حقوق كاملة وعليهم واجبات أيضا كما المسلمين في هذا
+
+355
+00:33:17,140 --> 00:33:21,720
+الشأن بل ولم يقف الأمر عند أهل الذمة حتى بالنسبة
+
+356
+00:33:21,720 --> 00:33:27,730
+للمحاربين الذين بيننا وبينهمعداء وبيننا وبينهم حرب
+
+357
+00:33:27,730 --> 00:33:32,650
+لو أن أحدا منهم هذا الفرق بين أهل الذنب والمستعمر
+
+358
+00:33:32,650 --> 00:33:37,930
+جاءنا إلى بلادنا وأمنناهم
+
+359
+00:33:39,260 --> 00:33:43,420
+و فهذا ما يُعرف باللجوء السياسي اللي جاء إلينا
+
+360
+00:33:43,420 --> 00:33:49,360
+سواء لتجارة أو لغير ذلك وله حقوق يعني هي أشبه ما
+
+361
+00:33:49,360 --> 00:33:56,810
+تكون بالحقوق اللتي تفرزها الجنسية اليوميا أخوات
+
+362
+00:33:56,810 --> 00:34:01,770
+فالمسلمون عرفوا ذلك قديما لكن الياء الأمور تنقلب
+
+363
+00:34:01,770 --> 00:34:07,170
+وتتغير وتتبدل على أي حال يعني ان شاء الله المرة
+
+364
+00:34:07,170 --> 00:34:11,950
+القادمة نبين بالتفصيل أحكام التجنس بالجنسية
+
+365
+00:34:11,950 --> 00:34:13,190
+الأجنبية شكرا لكم
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/hSnwvD1y2L4_raw.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/hSnwvD1y2L4_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..8b92ff766fedb92c15c9563f9ca4a14881da6416
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/hSnwvD1y2L4_raw.srt
@@ -0,0 +1,1764 @@
+1
+00:00:00,000 --> 00:00:00,140
+موسيقى
+
+2
+00:00:22,820 --> 00:00:26,500
+الحمد لله رب العالمين والصلاة والسلام على أشرح
+
+3
+00:00:26,500 --> 00:00:31,780
+رسول محمد صلى الله عليه وسلم على آله وصحبه وسلم
+
+4
+00:00:31,780 --> 00:00:38,600
+تسليما كثيرا وبعد نواصل حديثنا حول المسألة الثانية
+
+5
+00:00:38,600 --> 00:00:43,280
+أو القضية الثانية القضايا المعاصرة التي بدأنا
+
+6
+00:00:43,280 --> 00:00:52,760
+نتحدث فيها وهي مسألةمصرف في سبيل الله لمن ينفق ما
+
+7
+00:00:52,760 --> 00:00:59,920
+المراد فيه وقد
+
+8
+00:00:59,920 --> 00:01:07,960
+تحدثنا في المرة الماضية أن العلماء اختلف في تفسير
+
+9
+00:01:07,960 --> 00:01:15,600
+قوله تعالىوفي سبيل الله عند بيانه لمصارف الذكاء
+
+10
+00:01:15,600 --> 00:01:20,060
+الثمانية ومع
+
+11
+00:01:20,060 --> 00:01:28,020
+أن العلماء متفقون على أن مصارف الذكاء محدودة لا
+
+12
+00:01:28,020 --> 00:01:36,280
+تزيد ولا تنقص ومتفقون أيضا على أن الجهاد
+
+13
+00:01:36,280 --> 00:01:43,610
+والمجاهدين يأخذونمن مصرف فيه سبيل الله لكنهم
+
+14
+00:01:43,610 --> 00:01:49,390
+اختلفوا فيما إذا كان هذا المصرف يقتصر على
+
+15
+00:01:49,390 --> 00:01:59,210
+المجاهدين والغزو والغزا فقط أم أنه يتسع لفئات
+
+16
+00:01:59,210 --> 00:02:05,570
+أخرى ولمجالات أخرى أو بمعنى أخر بوجوه أخرى من وجوه
+
+17
+00:02:05,570 --> 00:02:12,430
+الخير كبناء البساجدو بناء المستوصفات و المستشفيات
+
+18
+00:02:12,430 --> 00:02:17,670
+و مراكز الدعوة و العلم و القرآن و غير ذلك مما يعود
+
+19
+00:02:17,670 --> 00:02:26,290
+بالنفع على الأمة و المجتمع المصمم ذكرنا
+
+20
+00:02:26,290 --> 00:02:32,850
+ربما في المرة الماضية أن أساس الخلاف أن أساس
+
+21
+00:02:32,850 --> 00:02:40,200
+الخلاف يعود للاختلاف في فهمه و تفسيرهقوله تعالى
+
+22
+00:02:40,200 --> 00:02:49,580
+وفي سبيل الله في ذلك أن الأصل في قوله تعالى في
+
+23
+00:02:49,580 --> 00:02:55,840
+سبيل الله الأصل في معناه اللغوي يتسع ليشمل كل طرق
+
+24
+00:02:55,840 --> 00:03:03,240
+الخيرفالسبيل هو الطريق، وسبيل الله هو كل طريق
+
+25
+00:03:03,240 --> 00:03:08,020
+يبتغى به وجه الله، وعلى ذلك أن أخذناها على المعنى
+
+26
+00:03:08,020 --> 00:03:14,580
+اللغويفإن .. فإنها تتسع لكل وجوه الخير وانا أقول
+
+27
+00:03:14,580 --> 00:03:19,200
+لكم يا أخوات أن الأصل في تفسير القرآن إذا لم يجد
+
+28
+00:03:19,200 --> 00:03:26,660
+.. إذا لم يوجد ذمتى دليل من حديث النبوي أو آية
+
+29
+00:03:26,660 --> 00:03:31,340
+قرآنية أخرى فإن القرآن يفسر بعضه بعضه فإن الأصل في
+
+30
+00:03:31,340 --> 00:03:36,900
+التفسير هو اللغة هو اللغة فاللغة أحد أهم تفسير
+
+31
+00:03:36,900 --> 00:03:44,060
+القرآن الكريموألفاظه وآياته خاصة عندما لا يمكن ذلك
+
+32
+00:03:44,060 --> 00:03:48,700
+أنه نزل بالعربي فبدّوله كل كلمة بالعربية هو اللذي
+
+33
+00:03:48,700 --> 00:03:53,460
+تعنيها للآية عندما كما قلت لا يوجد دليل آخر على
+
+34
+00:03:53,460 --> 00:03:59,570
+ذلك كحديث أو كآية كآية أخرىإذا .. إذا .. إذا في
+
+35
+00:03:59,570 --> 00:04:05,110
+أصل اللغة يتسع المعنى لكن إن كان ثمة فدلة أخرى
+
+36
+00:04:05,110 --> 00:04:09,830
+تقصر المعنى على .. على .. على فئة محددة فهذا شيء
+
+37
+00:04:09,830 --> 00:04:14,070
+أخر سيطبح علماء طبعا العلماء منهم من أخذ بالمعنى
+
+38
+00:04:14,070 --> 00:04:18,970
+اللغوي ووسعى دائرة مطاق الصرف اللي يتسع لكل وجوه
+
+39
+00:04:18,970 --> 00:04:24,000
+الخير ومنهم من قصره على الجهاد والمجاهدينومنهم من
+
+40
+00:04:24,000 --> 00:04:28,980
+كان ما بين هذا وذاك فأضاف الحج أو الغمرة تفسر في
+
+41
+00:04:28,980 --> 00:04:35,680
+المسألة في ثلاثة آراء لكن احنا حقيقة قبل أن نفصل
+
+42
+00:04:35,680 --> 00:04:39,820
+في هذه الآراء الرئيسية الثلاثة كنا المرة الماضية
+
+43
+00:04:39,820 --> 00:04:46,870
+حتى أبتدأنا ببيان آراء أصحاب المذاهبعلى اعتبار أن
+
+44
+00:04:46,870 --> 00:04:51,890
+أصحاب المداهب الأربعة لهم من الأهمية العلمية
+
+45
+00:04:51,890 --> 00:04:57,430
+والأهمية الشرعية والفقهية في شريعتنا وفي تاريخ
+
+46
+00:04:57,430 --> 00:05:05,270
+فقهنا، ما لها، فجميل أن نتهرقف على آراء الفقهاء
+
+47
+00:05:05,270 --> 00:05:11,150
+الأربعة، الأئمة الأربعة في هذه المسألة، فإن قولهم
+
+48
+00:05:13,990 --> 00:05:19,890
+في مسألة معينة يستأنس به، يرجّح، حقيقة، خاصة إن
+
+49
+00:05:19,890 --> 00:05:25,930
+اجتمعت كلمتهم على رأيه، فهذا مما يزيد هذا الرأي
+
+50
+00:05:25,930 --> 00:05:31,370
+قوته، وعندما استعرضنا أراء الأئم الأربعة، وأقوال
+
+51
+00:05:31,370 --> 00:05:35,570
+الأئم الأربعة، وتلاميذتهم في الأعام الأقلب،
+
+52
+00:05:35,570 --> 00:05:41,470
+وجدناهم متفقيرين،على أنه يقصده مصرفي سبيل الله
+
+53
+00:05:41,470 --> 00:05:51,550
+الجهاد والغزاة والغزو والرباط وما شابه وشكل ذلك
+
+54
+00:05:51,550 --> 00:05:58,130
+على اختلاف بينهم فقط في نطاق وحدود وتضييق وتوسيع
+
+55
+00:05:58,130 --> 00:06:03,830
+دائرة الجهاد لكنهم كلهم متفقونفالحنفية مثلا يضيقون
+
+56
+00:06:03,830 --> 00:06:08,910
+دائرة الدائرة اللي يقول بأن الصرفة إنما يكون أو
+
+57
+00:06:08,910 --> 00:06:14,630
+الدفع للمتقطعين من الغزاة، لأصحاب الحاجة، يعني
+
+58
+00:06:14,630 --> 00:06:20,850
+وليس للإيمياء منهموكذلك الشافعية وجدناهم يقولون
+
+59
+00:06:20,850 --> 00:06:26,770
+بأنهم تصرفوا أموال الذكاء من مصر في سبيل الله
+
+60
+00:06:26,770 --> 00:06:34,130
+للغزاء الذين لا ينتسبون للديوان، لا يأخذون راتبا
+
+61
+00:06:35,190 --> 00:06:39,890
+أما ما سواه من المتطوعين أو المحتاجين فلا بأس في
+
+62
+00:06:39,890 --> 00:06:45,590
+ذلكهم يقتربون شيئا ما من رأي الحلفية أما المالكية
+
+63
+00:06:45,590 --> 00:06:51,190
+فيوسعون الدائرة لتشمل أغنياء المجاهدين وفقراءهم
+
+64
+00:06:51,190 --> 00:06:59,080
+فهي للوزاة عموما وأما الحنابلة فكذلك كالمالكيةغير
+
+65
+00:06:59,080 --> 00:07:03,140
+أنهم يضيفون في بعض العراء الحج و الغمره و هنا غير
+
+66
+00:07:03,140 --> 00:07:06,100
+أيه عند الحنفية أو عند بعض علماء الحنفية و علماء
+
+67
+00:07:06,100 --> 00:07:12,240
+الحج لكن في الجملة كما قلت متفقون على أن المقصود
+
+68
+00:07:12,240 --> 00:07:18,360
+الأهم و الرئيسي هو عنوانه الجهاد والغسل و الغزال
+
+69
+00:07:18,360 --> 00:07:26,240
+عندما نجد هنا اتفاق هذا كما قلت له معنى له دلالةثم
+
+70
+00:07:26,240 --> 00:07:31,220
+إذا استعرضنا أراء العلماء جملة، احنا الكلام
+
+71
+00:07:31,220 --> 00:07:35,860
+الماضي، الكلام الأول، هذا كان أراء أئمة المذاهب،
+
+72
+00:07:35,860 --> 00:07:41,180
+لكن أئمة المذاهب ليسوا هم العلماء كلهم، العلماء
+
+73
+00:07:41,180 --> 00:07:47,120
+كلهم أوسع من الأئمة، جزءمن العلماء جزء مهم نعم لكن
+
+74
+00:07:47,120 --> 00:07:49,700
+.. جزء .. جزء .. جزء .. جزء .. جزء .. جزء .. جزء
+
+75
+00:07:49,700 --> 00:07:52,340
+.. جزء .. جزء .. جزء .. جزء .. جزء .. جزء .. جزء
+
+76
+00:07:52,340 --> 00:07:52,860
+.. جزء .. جزء .. جزء .. جزء .. جزء .. جزء .. جزء
+
+77
+00:07:52,860 --> 00:07:52,960
+.. جزء .. جزء .. جزء .. جزء .. جزء .. جزء .. جزء
+
+78
+00:07:52,960 --> 00:07:52,960
+.. جزء .. جزء .. جزء .. جزء .. جزء .. جزء .. جزء
+
+79
+00:07:52,960 --> 00:07:52,960
+.. جزء .. جزء .. جزء .. جزء .. جزء .. جزء .. جزء
+
+80
+00:07:52,960 --> 00:07:56,120
+.. جزء .. جزء .. جزء .. جزء .. جزء .. جزء .. جزء
+
+81
+00:07:56,120 --> 00:08:03,040
+.. جزء .. جزء .. جزء ..
+
+82
+00:08:03,040 --> 00:08:04,900
+جزء
+
+83
+00:08:06,230 --> 00:08:08,870
+رأي .. رأي .. رأي .. رأي .. رأي .. رأي .. رأي ..
+
+84
+00:08:08,870 --> 00:08:10,990
+رأي .. رأي .. رأي .. رأي .. رأي .. رأي .. رأي ..
+
+85
+00:08:10,990 --> 00:08:12,010
+رأي .. رأي .. رأي .. رأي .. رأي .. رأي .. رأي ..
+
+86
+00:08:12,010 --> 00:08:14,850
+رأي .. رأي .. رأي .. رأي .. رأي .. رأي .. رأي ..
+
+87
+00:08:14,850 --> 00:08:18,350
+رأي .. رأي .. رأي .. رأي .. رأي .. رأي .. رأي ..
+
+88
+00:08:18,350 --> 00:08:19,290
+رأي .. رأي .. رأي .. رأي .. رأي .. رأي .. رأي ..
+
+89
+00:08:19,290 --> 00:08:22,250
+رأي .. رأي .. رأي .. رأي .. رأي .. رأي .. رأي ..
+
+90
+00:08:22,250 --> 00:08:37,280
+رأي .. رأي .. رأي .. رأي .. رأي .. رأي .. رأي ..في
+
+91
+00:08:37,280 --> 00:08:42,560
+سبيل الله هو الجهاد في سبيل الله على اختلاف ايضا
+
+92
+00:08:42,560 --> 00:08:48,080
+مرة اخرى اقول بينهم في الدائرة او في النطاق هذا
+
+93
+00:08:48,080 --> 00:08:54,620
+بين موسع ومضيق ومضير لكنهم يتفقون في انه الجهاد في
+
+94
+00:08:54,620 --> 00:09:01,760
+ان الجهادة هو المقصود بمعنى ان هذا المصرف لا يتسع
+
+95
+00:09:01,760 --> 00:09:08,090
+لغير المجاهدينلا يجوز أن يُصرف من هذا المصرف لبناء
+
+96
+00:09:08,090 --> 00:09:14,550
+مساجد ولا لبناء مراكز خيرية أي إن كانت لتبنى تلكم
+
+97
+00:09:14,550 --> 00:09:21,330
+المساجد ولتبنى تلكم المراكز الخيرية من غير أموال
+
+98
+00:09:21,330 --> 00:09:27,230
+الذكاء لتبنى من غير .. من التبرعات، من الصدقات، من
+
+99
+00:09:27,230 --> 00:09:32,590
+ما .. من .. من ما ..ليست بذكوات من جيوب الناس، من
+
+100
+00:09:32,590 --> 00:09:37,610
+أموالهم، لا بأس في ذلك أما مال الذكات فهذا له
+
+101
+00:09:37,610 --> 00:09:43,070
+مصارفه الخاصة ومصرفه في سبيل الله المقصود به
+
+102
+00:09:43,070 --> 00:09:49,880
+الجهاد والمجاهدين، وهو مقتصر عليهما هي الأدلة سنرى
+
+103
+00:09:49,880 --> 00:09:57,960
+بعد قليل أما الرأي الثاني وهو رأي يعني حقيقة لا
+
+104
+00:09:57,960 --> 00:10:04,650
+يخرج كثيرا عن الرأي الأول بل يوافقه في الجملةعغير
+
+105
+00:10:04,650 --> 00:10:11,650
+أنه يضيف .. يضيف يعني مجال أخر أو فئة أخرة وهم فئة
+
+106
+00:10:11,650 --> 00:10:19,790
+الحجاج والعمار فئة الحجاج والعمار فهؤلاء يعني عند
+
+107
+00:10:19,790 --> 00:10:26,160
+أصحاب هذا الرأي ينضافون إلى المجاهدين فيجوزواأن
+
+108
+00:10:26,160 --> 00:10:32,000
+يُعطوا ويدفعوا لهم من أموال الذكاء من مصرفي في
+
+109
+00:10:32,000 --> 00:10:42,920
+سبيل الله وهذا يعني الرأي قال به عدد من العلماء
+
+110
+00:10:42,920 --> 00:10:46,800
+يعني منهم محمد بن الحسن من الحدثيه وانا أشارنا إلى
+
+111
+00:10:46,800 --> 00:10:52,340
+ذلك عندما تحدثنا عن آراء الأمة الأربعةوأحمد ابن
+
+112
+00:10:52,340 --> 00:10:58,140
+حنبل في رواية وإسحاق وجمع من الصحابة منهم عبد الله
+
+113
+00:10:58,140 --> 00:11:02,220
+ابن عمر وابن عباس يعني قال به البعض وكما قلت هو في
+
+114
+00:11:02,220 --> 00:11:06,100
+الجملة يعني لا يختلف كثير عن الرأي الأول إلا في
+
+115
+00:11:06,100 --> 00:11:11,620
+هذه الإضافة على اعتبار أن الحجة من الجهاد على
+
+116
+00:11:11,620 --> 00:11:16,580
+اعتبار أن الحجة جهاد ومن الجهاد ولهم أيضا أذلتهم
+
+117
+00:11:16,580 --> 00:11:22,610
+على ذلك أما الرأي الثالثالذي يختلفوا اختلافا كبيرا
+
+118
+00:11:22,610 --> 00:11:26,730
+حقيقة عن الرأي الأول والثاني وإن كان يتفق
+
+119
+00:11:26,730 --> 00:11:32,690
+بالمناسبة الرأي الأول والثاني والثالث متفقون على
+
+120
+00:11:32,690 --> 00:11:38,670
+أن الجهاد يُصرف له، يُصرف من هذا الباب، لكن أهو
+
+121
+00:11:38,670 --> 00:11:45,640
+الجهاد وفقط أم الجهاد وغيره؟أصحاب الرأي الثالث
+
+122
+00:11:45,640 --> 00:11:49,700
+يقولون الجهاد وغيره كل وجهه الغيره وعلى الرأس يزيد
+
+123
+00:11:49,700 --> 00:11:54,680
+الجهاد لكن لا يمنع ليس حصرا على الجهاد ليس مقصورا
+
+124
+00:11:54,680 --> 00:12:01,620
+على الجهاد في سبيل الله بل يجوز أن تبنى المساجد من
+
+125
+00:12:01,620 --> 00:12:07,840
+ذكوات الناس على اعتبار أن ذلك في سبيل اللهيجوز أن
+
+126
+00:12:07,840 --> 00:12:12,720
+تبنى المستوصفات ومراكز الدعوى والإرشاد والتوجيه
+
+127
+00:12:12,720 --> 00:12:19,380
+والتحفيظ للقرآن حتى الجسور والأسفلتات والطرق التي
+
+128
+00:12:19,380 --> 00:12:24,900
+تعود بالمنفعة العامة كلها يجوز أن تبنى من أموال
+
+129
+00:12:24,900 --> 00:12:30,580
+الذكاء يعني دعني أضيف شيئا هنا على أن يحسب حساب
+
+130
+00:12:30,580 --> 00:12:34,740
+الجهاد والمجاهدينعلى أن لا يكون على حساب يعني أيضا
+
+131
+00:12:34,740 --> 00:12:40,200
+الجهاد لكن من حيث المبدأ يجوز ذلك فهذه ثلاثة آراء
+
+132
+00:12:40,200 --> 00:12:47,740
+يعني في المسألة كما نرى لكل وجهته ولكل أدلتها
+
+133
+00:12:47,740 --> 00:12:52,380
+تعالوا نشوف يا ترى ما الأدلة التي استدل بها كل
+
+134
+00:12:52,380 --> 00:12:57,910
+فريق وإن بقى من وقت نناقش هذه الأدلةأما الرأي
+
+135
+00:12:57,910 --> 00:13:02,550
+الأول أما الرأي الأول أو أصحاب القول الأول وهم
+
+136
+00:13:02,550 --> 00:13:07,090
+الذين قالوا بإيه قالوا بأنه بأن مصرف في سبيل الله
+
+137
+00:13:07,090 --> 00:13:13,990
+مصرف خاص حصري حصري ثمين في الجهاد وكان بهم يقولون
+
+138
+00:13:13,990 --> 00:13:18,370
+يعني أنتم ألا تراونا يعني قبل الأدلة يعني ألا
+
+139
+00:13:18,370 --> 00:13:24,640
+تراونا أن الجهاد فيه عزكموأن تركه فيه ذلكم؟ أفا ..
+
+140
+00:13:24,640 --> 00:13:31,500
+يعني أفا تستكثرون عليه أن يخصص بثمن الذكاء بنسبة
+
+141
+00:13:31,500 --> 00:13:37,760
+أو بمصرف وهو يمثل الثمن؟ في الدول اليوم القوية
+
+142
+00:13:37,760 --> 00:13:44,630
+الدول الكبيرة يعني تنفقوا أموالا طائلةتزيد عن
+
+143
+00:13:44,630 --> 00:13:49,510
+الثمن والثمنين على وزارات الدفاع وعلى وزارات الحرب
+
+144
+00:13:49,510 --> 00:13:55,050
+وعلى .. وعلى آليات القتال وعلى معدات القتال لأنها
+
+145
+00:13:55,050 --> 00:14:03,590
+تفهم جيدا أن بقاءها وتحصيل رزقها أيضا من الجهاد
+
+146
+00:14:03,590 --> 00:14:08,530
+هذا يعني أمر مفهوم حقيقة لدى كل ذي عقل فيعني مش صح
+
+147
+00:14:08,530 --> 00:14:14,420
+أنه نجي في سهممن ثمانية نيجن شارك المجاهدين
+
+148
+00:14:14,420 --> 00:14:20,300
+والجهاد في غيرهم كأنهم يريدون أقطع ذلك بالقوة لكن
+
+149
+00:14:20,300 --> 00:14:24,780
+دعونا نعود إلى الأدلة ربما نحن في سياق حديثنا أو
+
+150
+00:14:24,780 --> 00:14:29,650
+من بداية الكلام أشهرنا في طيات الكلام إلىبعض
+
+151
+00:14:29,650 --> 00:14:35,530
+الأدلة الدليل الرئيسي يا أخوات الذي استند عليه هذا
+
+152
+00:14:35,530 --> 00:14:43,650
+القول هو تفسيرهم لقوله تعالى في سبيل الله على أنه
+
+153
+00:14:44,790 --> 00:14:48,730
+الغزو والجهاد لكن على ما استندهم دليلهم أن هذا
+
+154
+00:14:48,730 --> 00:14:52,670
+المقصود به في سبيل الله المقصود به الجهاد
+
+155
+00:14:52,670 --> 00:14:56,330
+والمجاهدين طب يا عم ليش؟ مع أنه في سبيل الله في
+
+156
+00:14:56,330 --> 00:15:01,670
+أصل معناها اللغوي يعني كل طريق يبتغى بوجه الله
+
+157
+00:15:01,670 --> 00:15:07,040
+فكيف تحصرنا؟ قالوا لأ احنا بنقول هيكصحيح هي في
+
+158
+00:15:07,040 --> 00:15:12,460
+سبيل الله في الأصل معناها كل طريق الخير لكن تعالوا
+
+159
+00:15:12,460 --> 00:15:18,820
+شوفوا المعنى الذي اشتهرت به كلمة في سبيل الله
+
+160
+00:15:18,820 --> 00:15:24,280
+عندما ترد في كتاب ربنا أو في سنة نبينا أو على
+
+161
+00:15:24,280 --> 00:15:30,680
+ألسنة أصحاب نبينا صلى الله عليه وسلم كلما قالوا إن
+
+162
+00:15:30,680 --> 00:15:34,140
+كلمة في سبيل الله اشتهر المراد منها
+
+163
+00:15:36,980 --> 00:15:46,000
+تعورفة على أن المقصود منها إذا أطلقت ولم يرد دليل
+
+164
+00:15:46,000 --> 00:15:51,180
+على التخصيص أن يكون المقصود بها الجهاد والمجاهدين
+
+165
+00:15:51,500 --> 00:15:55,920
+في معظم الآيات الواردة وكثير من الأحاديث التي
+
+166
+00:15:55,920 --> 00:16:00,920
+اجتملت على كلمة في سبيل الله حتى بدون ما تشير إلى
+
+167
+00:16:00,920 --> 00:16:06,140
+الجهاد يفهم منها الجهاد على طول وقاتلوا ربنا إيش
+
+168
+00:16:06,140 --> 00:16:12,100
+قال؟ وقاتلوا في سبيل الله الجهاد على طول يفهم منها
+
+169
+00:16:12,100 --> 00:16:19,140
+الجهاد قال أيضا وما لكم ألا تنفقوا في سبيل الله أي
+
+170
+00:16:20,100 --> 00:16:25,400
+نفقت الجهاد من دقيقة قليلة في الاية لا يستوي
+
+171
+00:16:25,400 --> 00:16:31,640
+القاعدون غير أيولي الضرري والمجاهدون في سبيل الله
+
+172
+00:16:31,640 --> 00:16:37,480
+يعني صار في زي غرف قرآني سبيل الله على طول طيب
+
+173
+00:16:37,480 --> 00:16:44,740
+تعني مقترن بالجهاد فإذا ما جاءت مجرد عن أي قارنة
+
+174
+00:16:44,740 --> 00:16:50,890
+تحمل على ما اشتهرت عليه او ما اشتهرت بهإذا ما
+
+175
+00:16:50,890 --> 00:16:53,630
+جاءت، إحنا في الآية اللي بين إيدينا، ليس ثم
+
+176
+00:16:53,630 --> 00:16:57,850
+تمنقرين دعنا نقول، فتحملوا على ما اشتهرت به في
+
+177
+00:16:57,850 --> 00:17:02,710
+القرآن الكريم وفي السنة النبويةإلا إذا ده الدليل،
+
+178
+00:17:02,710 --> 00:17:06,230
+والله إذا ده الدليل، بيخصصها العين والرأس، لكن
+
+179
+00:17:06,230 --> 00:17:09,510
+احنا بنقول لا دليل، لا دليل، حتى الأدلة اللي
+
+180
+00:17:09,510 --> 00:17:13,290
+بتستدل فيها الفريق الآخر، هؤلاء يضعفونها كما سنرى
+
+181
+00:17:13,290 --> 00:17:18,130
+لاحقا، حتى إذا يعني في السنة النبوية يعني أيضا
+
+182
+00:17:18,130 --> 00:17:22,030
+الرسول صلى الله عليه وسلم قال مرة عن خالد بن
+
+183
+00:17:22,030 --> 00:17:25,530
+الوليد عندما صارحوا له بعض الكلام يعني من قبل بعض
+
+184
+00:17:25,530 --> 00:17:29,350
+الصحابة يعني قال يعني كيف ذلك وقد احتبس خالد
+
+185
+00:17:29,350 --> 00:17:36,680
+أدراعهأعتاده في سبيل الله يعني كيف تتكلمون على
+
+186
+00:17:36,680 --> 00:17:46,120
+خالد وقد احتبس أو قف ودفع ع الدراع وعدد الحرب
+
+187
+00:17:46,120 --> 00:17:51,440
+وأعتاده في سبيل الله أي للجهادي والمجاهدين فكلمة
+
+188
+00:17:51,440 --> 00:17:55,500
+في سبيل الله إذا وردت في السنة دائما مقترنة
+
+189
+00:17:55,500 --> 00:17:56,640
+بالجهاد
+
+190
+00:17:59,760 --> 00:18:06,440
+المجاهدين هذا يعني دعنا نقول هذا أولا ثانيا ثانيا
+
+191
+00:18:06,440 --> 00:18:13,280
+إذا أولا شغرة المعنى في الكتاب والسنة أو شغرة
+
+192
+00:18:13,280 --> 00:18:17,460
+اللفظ بهذا المعنى شغرة اللفظ بهذا المعنى أو
+
+193
+00:18:17,460 --> 00:18:21,640
+المصدقات ثانيا حديث رسول الله صلى الله عليه وسلم
+
+194
+00:18:21,640 --> 00:18:29,770
+الذي يقول فيه لا تحل الصدقة لغنيلا تحل الصدقة لغني
+
+195
+00:18:29,770 --> 00:18:38,610
+إلا لخمسة لا تحل الصدقة لغني إلا لخمسة أول واحد من
+
+196
+00:18:38,610 --> 00:18:45,700
+الخمسمين لغاز في سبيل اللهلغاز في سبيل الله، قبل
+
+197
+00:18:45,700 --> 00:18:49,040
+ما أبين من الخمسة، حقيقة هذا هو اللي بهمنا احنا
+
+198
+00:18:49,040 --> 00:18:53,320
+الأول، لكن هنشير إلى الثانيات، لغاز في سبيل الله،
+
+199
+00:18:53,320 --> 00:18:57,440
+طيب، الغاز في سبيل الله، احنا الصداقات، آسف،
+
+200
+00:18:57,440 --> 00:19:03,980
+المصارف محدودة، متفقيهواجهة الاستدلال، المصارف
+
+201
+00:19:03,980 --> 00:19:07,380
+محدودة، واحد، اتنين، تلاتة، اربعة، خمسة، ستة،
+
+202
+00:19:07,380 --> 00:19:10,560
+أتنين، تلاتة، أربعة، خمسة، ستة، أتنين، تلاتة،
+
+203
+00:19:10,560 --> 00:19:10,560
+أربعة، خمسة، أتنين، تلاتة، أتنين، تلاتة، أتنين،
+
+204
+00:19:10,560 --> 00:19:10,580
+تلاتة، أتنين، تلاتة، أتنين، تلاتة، أتنين، تلاتة،
+
+205
+00:19:10,580 --> 00:19:10,700
+أتنين، تلاتة، أتنين، تلاتة، أتنين، تلاتة، أتنين،
+
+206
+00:19:10,700 --> 00:19:13,980
+تلاتة، أتنين، تلاتة، أتنين، تلاتة، أتنين، تلاتة،
+
+207
+00:19:13,980 --> 00:19:18,190
+أتنين، تلإن نضيف إن يكون المقصود تاسر لأ، احنا
+
+208
+00:19:18,190 --> 00:19:23,090
+متفقين على إنه ثمانية، وين ممكن يكون المقصود منه؟
+
+209
+00:19:23,090 --> 00:19:27,170
+طلعنا لقنا في سبيل الله هي المقصودة، إذا كأن غازن
+
+210
+00:19:27,170 --> 00:19:31,490
+في سبيل الله جاء تفسيرا لفي سبيل الله، فتحملوا
+
+211
+00:19:31,490 --> 00:19:37,770
+عليهافتحملوا عليها فالحديث دليل على أن المقصودة
+
+212
+00:19:37,770 --> 00:19:43,430
+بقوله تعالى في سبيل الله أو في سبيل الله الغزاة
+
+213
+00:19:43,430 --> 00:19:48,910
+والمجاهدون أما بقيت نقف وقفة عند بقية الخمسة فقط
+
+214
+00:19:48,910 --> 00:19:55,130
+للعلم أو للفائدةلأنه يعني هو الحديث بيقول لا تحلوا
+
+215
+00:19:55,130 --> 00:19:59,330
+الصدقة، الأصل في الصدقات أنها لا تحلوا إلا لهاي
+
+216
+00:19:59,330 --> 00:20:03,850
+مصارفها، فقراء ومساكين، لكن من ضمن من تحلوا لهم من
+
+217
+00:20:03,850 --> 00:20:08,290
+الأغنياء، خمسة، بعضهم موجودين في المصارف وبعضهم
+
+218
+00:20:08,290 --> 00:20:15,240
+موجودين أو مش موجودين في المصارف، موصلةفلذلك يا
+
+219
+00:20:15,240 --> 00:20:18,620
+أخوات يعني أنا أحب أن أقف قليلا في هذه الحديث أن
+
+220
+00:20:18,620 --> 00:20:26,060
+الفئة الثانية أو لعامل في .. أو لعامل عليها لعامل
+
+221
+00:20:26,060 --> 00:20:29,180
+عليها منصوص العامل عليها هل بالضرورة أن يكون
+
+222
+00:20:29,180 --> 00:20:33,500
+محتاجا وفقيرا؟ لأ لأ ممكن يكون غني ويله أراضي ويله
+
+223
+00:20:33,500 --> 00:20:38,580
+كذا وكذا لكن مدام يقومأو يعمل في هذه الوظيفة ويقوم
+
+224
+00:20:38,580 --> 00:20:44,620
+بجباية الذكاء وجمعها له حق له حق كسائر الموظفين
+
+225
+00:20:44,620 --> 00:20:51,380
+الدولي مع أنه غني إذا هذا غني ويستحق من الذكاء
+
+226
+00:20:51,380 --> 00:20:56,850
+كمان الغازي في سبيل اللهليس بالضرورة أن يكون فقيرا
+
+227
+00:20:56,850 --> 00:21:01,890
+ومحتاجا وفيه رد هذا يا أخوات، أيضا ربما على بعض،
+
+228
+00:21:01,890 --> 00:21:06,670
+الأما الذين قالوا أنها لفقراء المجاهدين أو
+
+229
+00:21:06,670 --> 00:21:12,680
+للمتوطوعين منهم أو للمنقطعين أو إلى غير ذلكف ..
+
+230
+00:21:12,680 --> 00:21:19,060
+فلذلك يعني هذا يؤكد على أن للغزاء على الإطلاق
+
+231
+00:21:19,060 --> 00:21:25,860
+أغنياءهم و فقراءهم و كأن في هذا الدلالة يكفيك يعني
+
+232
+00:21:25,860 --> 00:21:31,260
+أن يأتيك الغازي بنفسه مضحيا بنفسهحتى وإن كان قادرا
+
+233
+00:21:31,260 --> 00:21:36,800
+أن يأتي بالمال وأن يأتي بآلات الجهاد لكن هو لم
+
+234
+00:21:36,800 --> 00:21:41,480
+يفعل ذلك ليس واجبا عليه أن تقدم له و لو من ذكاء
+
+235
+00:21:41,480 --> 00:21:48,740
+المال قدم له آلة الجهاد أو السلاح الذي يقوم به
+
+236
+00:21:48,740 --> 00:21:53,840
+بمهاجمة الأعداء و بالدفاع عن الأمة لا بأس في ذلك
+
+237
+00:21:53,840 --> 00:21:57,970
+والله أنا معاي مصر لكن أنا بتخليها للولاد يعنيمكفئ
+
+238
+00:21:57,970 --> 00:22:03,810
+ان انا ممكن اضحى بنفسى لأ بأس في ذلك و ليس شرطا
+
+239
+00:22:03,810 --> 00:22:10,090
+اذا غني و غازى في سبيل الله لأ بأس في ذلك و عامل
+
+240
+00:22:10,090 --> 00:22:14,150
+عليها لو كان غنيا لأ بأس في ذلك طبعا لو كان فقرا
+
+241
+00:22:14,150 --> 00:22:20,430
+من باب اولى هذا بيكون او لغارنين هنا برضه يمكن
+
+242
+00:22:20,430 --> 00:22:27,920
+تساؤل الغارم يعني هل يمكن ان يكون غنيا نعمممكن يا
+
+243
+00:22:27,920 --> 00:22:33,080
+أخوات الأصل في معنى الغارم صحيح هو المدينة لكن من
+
+244
+00:22:33,080 --> 00:22:38,280
+وجوه معاني الغارم ولعلها من أبرز وجوهها أولئك
+
+245
+00:22:38,280 --> 00:22:42,120
+الذين يتحملون
+
+246
+00:22:42,120 --> 00:22:50,630
+محاملة للإصلاح بين الناسفي مشكلة صارت دفع ديات،
+
+247
+00:22:50,630 --> 00:22:57,290
+دفع يعني مجاهات إلى غير ذلك و الناس اللي تسبب في
+
+248
+00:22:57,290 --> 00:23:01,530
+التلف مش قادر يدفع فواحد بيقول يا عم انا بتحمل في
+
+249
+00:23:01,530 --> 00:23:05,770
+سبيل الإصلاح بين الناس فيصبح اسمه غارم و لو كان
+
+250
+00:23:05,770 --> 00:23:11,690
+قادرا على الدفع و لو كان غنيا يجوز أن يدفع له من
+
+251
+00:23:11,690 --> 00:23:17,450
+الذكاء فإن لم يكن قادرا فمن باب أولى أيضاطبعا
+
+252
+00:23:17,450 --> 00:23:20,750
+ويمكن أن يكون الغارم مدينا وفقيرا، لكن ممكن أن
+
+253
+00:23:20,750 --> 00:23:26,150
+يكون غارما وغنيا وقادرا ومع ذلك يجوز أن يدفع له أو
+
+254
+00:23:26,150 --> 00:23:31,930
+أن يساهم له فيما غارم وتحمل، برك الله فيه، تحمل
+
+255
+00:23:31,930 --> 00:23:35,210
+وأصلح بين الناس، ساهموا يا سيدي، بلاش العشرة ألف
+
+256
+00:23:35,210 --> 00:23:38,410
+دولار اللي دا قصدروا عليهم، تحملوا إياهم، وعشان
+
+257
+00:23:38,410 --> 00:23:42,930
+بكرا يشذّانوا ويقولوا عمري ما بتدخل، يعني ساهموا،
+
+258
+00:23:42,930 --> 00:23:47,110
+ويدفعوله خمس ست ألاف عشان مرة ثانيةبرضه يخش في
+
+259
+00:23:47,110 --> 00:23:55,370
+الصلح بين الناس لغارما ايضا او لرجل اشتراها بماله
+
+260
+00:23:55,370 --> 00:24:01,390
+ايش يعني؟ او لرجل اشتراها بماله؟ هي الصدقة بتنبع
+
+261
+00:24:01,390 --> 00:24:07,150
+وبتنشرها؟ ما رأيكم؟ مش عن الصدقة بحكي؟ او لرجل
+
+262
+00:24:07,150 --> 00:24:13,630
+اشتراها بماله؟ يا أخواتهي الصدقة بعد ما ياخذها
+
+263
+00:24:13,630 --> 00:24:19,110
+الفقير، أتصبح ملكا له ولا لا؟ ألا يصبح له الحق في
+
+264
+00:24:19,110 --> 00:24:23,770
+التصرف فيها؟ ألا يصبح له الحق في أن يبيعها؟ ألا
+
+265
+00:24:23,770 --> 00:24:29,190
+يصبح لغيره الحق وإن كان غنيا أن يشتريها؟ نعم، إذا
+
+266
+00:24:29,190 --> 00:24:34,790
+أنا غني، أنا غني، و .. و بعد ما صار الآن الفقراء
+
+267
+00:24:34,790 --> 00:24:41,270
+في مواسم معينيعني في مواسم عيد الفطر مثلا يعني عند
+
+268
+00:24:41,270 --> 00:24:44,350
+من قال بقى أن صدقة الفطر تدفع من التمر و القمح
+
+269
+00:24:44,350 --> 00:24:49,170
+ممكن يصير عنده يعني مئات الكيلو مترا .. كيلوات من
+
+270
+00:24:49,170 --> 00:24:52,930
+.. من التمر و لا من القمح مش بده فيه هيسوس و يقرب
+
+271
+00:24:52,930 --> 00:24:56,890
+انه بده يبيعه عشان يشتري الأولاد شوية يعني بدل و
+
+272
+00:24:56,890 --> 00:25:02,010
+لا شوية جمصان و لا بنتيل و لا ايه لغير ذلك اه فمن
+
+273
+00:25:02,010 --> 00:25:06,700
+اللي بده يشتريها مش الأغنياءإذا الغني ممكن تحلله
+
+274
+00:25:06,700 --> 00:25:10,040
+الصدقة إذا اشتراها، ايه المقصود؟ إذا اشتراها
+
+275
+00:25:10,040 --> 00:25:15,700
+تحلله، والطبعا والفقير يحلله أن يبيعها، فلا بأس في
+
+276
+00:25:15,700 --> 00:25:20,760
+ذلك، يعني مش إنه صدقة في أصلها صارت جربة وصارت ما
+
+277
+00:25:20,760 --> 00:25:25,580
+بتنبع ولا بتنشرهاولا يباع ولا يشتره مش فيه مرة
+
+278
+00:25:25,580 --> 00:25:28,900
+المعونات اللي بتيجي هاه بيبقوا كتبوا ليس للبيع ولا
+
+279
+00:25:28,900 --> 00:25:32,560
+تباع ولا تشتره طب أنا بعد ما ملقتها انت تفرض عليها
+
+280
+00:25:32,560 --> 00:25:35,840
+يعني انا مابيعوش وما اشتري خلاص سيبني في عالم بدي
+
+281
+00:25:35,840 --> 00:25:39,940
+ابيع واشتري اللي بديها انا اسلام دين الواقع وانا
+
+282
+00:25:39,940 --> 00:25:46,320
+كغني يعني بلقيها ربما أرخص شويه ممكن اشتريها مالش
+
+283
+00:25:46,320 --> 00:25:55,010
+لا بأس في ذلك اذا او من اشتراهاأو لرجل اشتراها
+
+284
+00:25:55,010 --> 00:25:59,130
+بماله أو لرجل هذه الخامسة، هذا غني ممكن يقوم ..
+
+285
+00:25:59,130 --> 00:26:04,270
+طبعا هذا ليس من أصناف الذكاء .. بس ان هي تنبيه،
+
+286
+00:26:04,270 --> 00:26:06,670
+هذا الصنف الثاني .. الرابع والخامس اللي بدنا نقوله
+
+287
+00:26:06,670 --> 00:26:13,330
+.. هذا تنبيه لكي لا يظن أحد أن الصداقات لا تباع،
+
+288
+00:26:13,330 --> 00:26:18,990
+لا يا عم بتنبع و بتنشرةلا تباع ولا تهدى، لا تهدى
+
+289
+00:26:18,990 --> 00:26:22,270
+ولا تباع، مش هيك بيقولوا، لا تهدى ولا تباع، أنا
+
+290
+00:26:22,270 --> 00:26:29,630
+الآن فقير، وربنا بعتلي في فترة من الفترات بصداقات
+
+291
+00:26:29,630 --> 00:26:37,830
+عينية ومالية، وانا جاري الغني اللي طول عمرهيعني
+
+292
+00:26:37,830 --> 00:26:42,010
+بينه و بينه معاملة كويسة و بيعطيني هدايا و غير ذلك
+
+293
+00:26:42,010 --> 00:26:46,290
+اه ماصدقت و أصير عندي إمكانية لأن أرد له الهدية
+
+294
+00:26:46,290 --> 00:26:50,210
+أبعتله كيلو التمر و لا أبعتله كيلو لحمة صار عندي
+
+295
+00:26:50,210 --> 00:26:55,330
+عشر كيلو لحمة انتلت التلاجة اه لكل فقير أعطوه
+
+296
+00:26:55,330 --> 00:26:59,890
+أعطوه مثلا طب كيلو لحمة للغني يا سيدي اللي هو يمكن
+
+297
+00:26:59,890 --> 00:27:06,210
+السنة مضحكشفلا بأس في ذلك فلا بأس مع أن أصلها إيه
+
+298
+00:27:06,210 --> 00:27:12,530
+أصلها صدق أصلها ذكاء لكنها حلت الغني عندما أهداها
+
+299
+00:27:12,530 --> 00:27:18,630
+ذلك المسكين لذلك الغني ولذلك إشجال أو لرجل له جار
+
+300
+00:27:18,630 --> 00:27:25,730
+مسكين فأهدا المسكين فاعل مش فأهدا المسكينة فأهدا
+
+301
+00:27:25,730 --> 00:27:32,970
+المسكين للغني فأهدا المسكين إليهلكن احنا حقيقة وجه
+
+302
+00:27:32,970 --> 00:27:36,770
+الشاهد اللي بدنا يأهو الأول او لغازه في سبيل الله
+
+303
+00:27:36,770 --> 00:27:41,330
+وما بعد ذلك هو للتوضيح ولفائدة نعم اشملت من المال
+
+304
+00:27:41,330 --> 00:27:46,750
+احنا
+
+305
+00:27:46,750 --> 00:27:50,670
+بنقول على فرض يعني طلعه احنا لا بأس بيخرجها مالا
+
+306
+00:27:50,670 --> 00:27:55,650
+وقد أفتى بذلك الإمام أبو حنيفة وغيره وهو الراجح
+
+307
+00:27:55,650 --> 00:28:02,920
+الآنوهو الأصلح وهو الأيصر يعني على المخرج والمخرج
+
+308
+00:28:02,920 --> 00:28:06,700
+إليها على الغني اللي بده يدفع وعلى الفجير اللي بده
+
+309
+00:28:06,700 --> 00:28:10,120
+ياخد زي ما قلت هو يضطر في الآخر يبيعوا بنص الثمن
+
+310
+00:28:10,120 --> 00:28:16,940
+لو جبتله إياها مصاري مجاية ما يحصل لجزامك لا
+
+311
+00:28:16,940 --> 00:28:22,060
+يا سيدي احنا مش أحد من الرسول صلى الله عليه وسلم
+
+312
+00:28:22,060 --> 00:28:27,710
+فهو بالمؤمنين رعوف ورحيم بس هم فهم منقاصرهذا هي ..
+
+313
+00:28:27,710 --> 00:28:32,990
+هو الرسول .. في يوم .. في تلك الفترة كان التمر و
+
+314
+00:28:32,990 --> 00:28:37,370
+.. و .. و .. و القمح و الشعير هو عبارة عن القيمة
+
+315
+00:28:37,370 --> 00:28:41,470
+للأشياء، القيمة الرائجة، اه و مافيش مجال للتبخيص و
+
+316
+00:28:41,470 --> 00:28:45,190
+مافيش كذا، يعني اللي عنده قمح و شعير و تمر كأنه
+
+317
+00:28:45,190 --> 00:28:48,770
+عنده مصارى اليوم، لكن اليوم اختلفت، اليوم الطحين و
+
+318
+00:28:48,770 --> 00:28:52,250
+أحسن الطحين تقعد عندك كيس ب .. ب .. بسوس، بتترجف
+
+319
+00:28:52,250 --> 00:28:57,520
+المرأة، اشن يا بنت؟ مافيش فايدة، الخبس جاهزيعني اه
+
+320
+00:28:57,520 --> 00:29:02,600
+الكهرة بقعتها فلذلك يعني الامر اختلف والفتوى تقدر
+
+321
+00:29:02,600 --> 00:29:10,340
+زمانا ومكانا فاحنا مابننكر على من يخرجها عينا ولكن
+
+322
+00:29:10,340 --> 00:29:17,940
+ايضا نراء المصلحة في ذلك وقد ثبت يعني ان يعني كثير
+
+323
+00:29:17,940 --> 00:29:21,400
+من الفقهاء قالوا بذلك وهو لعله الأنسب في عصرنا
+
+324
+00:29:21,400 --> 00:29:29,920
+والله أعلمعلى كل الأحوال، هذا دليل آخر، دليل ثالث
+
+325
+00:29:29,920 --> 00:29:33,800
+من الأدلة التي استدل بها القائلون، لازمنا نستعرض
+
+326
+00:29:33,800 --> 00:29:39,440
+أدلة القائلين بأن في سبيل الله تختص بالجهاد
+
+327
+00:29:39,440 --> 00:29:46,190
+والمجاهدين، وهو ما قاله جماهير العلماءاستدلوا
+
+328
+00:29:46,190 --> 00:29:49,450
+بحديث رواه كعب احد صحابة رسول الله صلى الله عليه
+
+329
+00:29:49,450 --> 00:29:55,330
+وسلم كعب ابن عجرة انه قال مرة رجل على النبي صلى
+
+330
+00:29:55,330 --> 00:30:01,130
+الله عليه وسلم راجل مرة من غير المسلمين مرة على
+
+331
+00:30:01,130 --> 00:30:07,410
+النبي وعصحابه الصحابة يا أخواتزمان وكل مسلم الأصل
+
+332
+00:30:07,410 --> 00:30:12,210
+في كل زمان و في كل مكان يكون هم للدين و للإسلام و
+
+333
+00:30:12,210 --> 00:30:17,490
+الجهاد ذروة سنام الإسلام و الجهاد بيه عزة الإسلام
+
+334
+00:30:17,490 --> 00:30:21,550
+و ذلة الإسلام اللي الصحاب فقهوا هذا جيدا لما شافوا
+
+335
+00:30:21,550 --> 00:30:27,690
+واحد مر رجل لكنه رجل يعني قوي شديدصلب ومن غير
+
+336
+00:30:27,690 --> 00:30:33,010
+المسلمين فهم تحصروا في أنفسهم قالوا لما وجدوه مرة
+
+337
+00:30:33,010 --> 00:30:39,350
+يعني أمام النبي صلى الله عليه وسلم ووجدوا من جلده
+
+338
+00:30:39,350 --> 00:30:45,490
+ونشاطه وقوته قالوا لو كان هذا في سبيل الله لو كان
+
+339
+00:30:45,490 --> 00:30:51,470
+هذا الرجل قوته ونشاطه وجلده لو كانت في سبيل الله
+
+340
+00:30:52,420 --> 00:30:54,600
+يعني كان اخد .. ياريت .. يعني زي ما يقول ياريت هذا
+
+341
+00:30:54,600 --> 00:30:58,240
+يسلم ويكون مجاهد .. ياريت .. اه زي ما كان النبي
+
+342
+00:30:58,240 --> 00:31:00,800
+صلى الله عليه وسلم يقول اللهم أعز الإسلام ب .. ب
+
+343
+00:31:00,800 --> 00:31:04,420
+.. ب .. بأحد العمرين .. اه ياريت انه هذا يعني يدخل
+
+344
+00:31:04,420 --> 00:31:09,960
+الإسلام ويصبح مجاهدا سيقوي شوكة المسلمين الشاهد ..
+
+345
+00:31:09,960 --> 00:31:15,750
+الشاهد ايش؟ انه اه .. انه ..قال إن الصحابة كانوا
+
+346
+00:31:15,750 --> 00:31:21,130
+يفهمون أو كانوا يطلقون ويستخدمون كلمة في سبيل الله
+
+347
+00:31:21,130 --> 00:31:24,730
+ويطلقونها على الجهاد لو كان هذا في سبيل الله أي لو
+
+348
+00:31:24,730 --> 00:31:30,790
+كان هذا .. هذا قوته يعني يدفعها أو يعطيها أو
+
+349
+00:31:30,790 --> 00:31:38,850
+يخصصها للجهاد و للدفاع عن أمة الإسلاموالدليل الأخر
+
+350
+00:31:38,850 --> 00:31:45,150
+والأخر الذي استدلوا به هو ما جاء في بعض الآثار حتى
+
+351
+00:31:45,150 --> 00:31:50,970
+غير الحديث وغير دلالة القرآن وغير يعني كلام
+
+352
+00:31:50,970 --> 00:31:55,770
+الصحابةأيضا من الآثار من آثار التابعين بعد صحابة
+
+353
+00:31:55,770 --> 00:32:00,490
+رسول الله صلى الله عليه وسلم يعني جاء رؤية في
+
+354
+00:32:00,490 --> 00:32:04,110
+تفسير الطبري أو جاء في تفسير الطبري الطبري بينقل
+
+355
+00:32:04,110 --> 00:32:09,470
+عن من قبله من التابعين ومن الصحابة من التابعين زي
+
+356
+00:32:09,470 --> 00:32:15,710
+ابن أسلم أحد قامات التفسيرمن .. من .. من .. من ..
+
+357
+00:32:15,710 --> 00:32:19,310
+من .. من جيل التادعين زيد بن أسلم معروف عند أهل
+
+358
+00:32:19,310 --> 00:32:25,190
+التفسير زيد بن أسلم إيش بقول بقول لما وقف عند قوله
+
+359
+00:32:25,190 --> 00:32:30,230
+تعالى وفي سبيل الله قال الغازي هو الغازي في سبيل
+
+360
+00:32:30,230 --> 00:32:36,080
+اللههو الغازي إذا هذا أثر، أثر عن تابعي وكذلك أثر
+
+361
+00:32:36,080 --> 00:32:42,540
+آخر عن مقاتل الذي جاء في تفسير السيوطي عن ابن أبي
+
+362
+00:32:42,540 --> 00:32:47,340
+حاتم فسرها أيضا بالمجاهدين، مجموعة هذه الأدلة أيضا
+
+363
+00:32:47,340 --> 00:32:54,020
+الأخواتوغيرها ربما دللأ أو رجحة عند أصحاب هذه
+
+364
+00:32:54,020 --> 00:33:00,840
+الفريق بأن في سبيل اللهم الجهاد أو المجاهدين فلا
+
+365
+00:33:00,840 --> 00:33:09,770
+تخلطوا ولا تشركوا معهم أحدهذا مصرف خاص خالص
+
+366
+00:33:09,770 --> 00:33:14,710
+للمجاهدين الله يرضى عليكم، لا تقولوا لمسجد ولا
+
+367
+00:33:14,710 --> 00:33:19,230
+تقولوا لمستوصف ولا غيره، هذا للمجاهدين ودول
+
+368
+00:33:19,230 --> 00:33:23,770
+مكفيهم، واللي عنده زيادة يعطيهم كمانخلّينا في عزة
+
+369
+00:33:23,770 --> 00:33:28,370
+وكرامة، خلّيهم وضلهم أقوياء ويجيبوا سلاح من وين ما
+
+370
+00:33:28,370 --> 00:33:35,430
+كانوا ويقدروا يشتريوا ويصنعوا تحت الأرض وفوق الأرض
+
+371
+00:33:35,430 --> 00:33:44,030
+وكله تمام إيه؟ طيب، جميل، فماذا عشان القائلون
+
+372
+00:33:45,470 --> 00:33:50,630
+بالرأي الثاني الذين قالوا بأن الحقيقة احنا قلنا يا
+
+373
+00:33:50,630 --> 00:33:54,690
+أخوات أن أصحاب القول الثاني لا يختلفون كثيرا عن
+
+374
+00:33:54,690 --> 00:33:57,850
+أصحاب القول الأول غاية ما في الأمر أنهم يعني
+
+375
+00:33:57,850 --> 00:34:02,250
+يضيفون يعني فئة قليلة وهم فئة الحجاج والعمارة معنى
+
+376
+00:34:02,250 --> 00:34:07,530
+ذلك أنهم يقولون بالجهاد ودلتهم على ذلك هي ذات
+
+377
+00:34:07,530 --> 00:34:10,570
+الأدلة التي استدل بها القائلون أصحاب الرأي الأول
+
+378
+00:34:11,270 --> 00:34:16,530
+لكن احنا الآن بدنا معا دلتهم على أنها .. على أنها
+
+379
+00:34:16,530 --> 00:34:21,090
+.. على أن هذا المصرف يتسع أيضا أو يدله أيضا أو
+
+380
+00:34:21,090 --> 00:34:25,310
+يراد به أيضا الجهة .. الحج والعمر أو الحجاج
+
+381
+00:34:25,310 --> 00:34:30,330
+والمعتمرين لعل الحديث المشهور الذي نعرفه جميعا
+
+382
+00:34:30,330 --> 00:34:36,400
+والذي رواته السيدة عائشة الحج جهات لا شوكة فيهالحج
+
+383
+00:34:36,400 --> 00:34:43,800
+جهاد فهو وصف الحج بالجهاد وإذا قلنا بأن المصرف هذا
+
+384
+00:34:43,800 --> 00:34:49,020
+يختص بالجهاد فهذا جهاد بنص حديث رسول الله صلى الله
+
+385
+00:34:49,020 --> 00:34:56,800
+عليه وسلم فيدخل فيه إذا هذا أولا ثانيا أيها
+
+386
+00:34:56,800 --> 00:35:03,480
+الأخوات حديث أم معقلحديث معقل هذا طبعا الحديث يعني
+
+387
+00:35:03,480 --> 00:35:06,740
+ليس في الصحيحين ولذلك فيه كلام هو حديث رواه
+
+388
+00:35:06,740 --> 00:35:11,400
+الترمدي وبن ماجا وغيرهم فيه يعني كلام ولذلك أصحاب
+
+389
+00:35:11,400 --> 00:35:15,580
+الرأي الأول لم يأخذوا به بالمناسبة يعني أو لم يروا
+
+390
+00:35:15,580 --> 00:35:21,860
+فيه حديثا يقوى على الاستدلال لكن هدول اعتبروه يعني
+
+391
+00:35:22,800 --> 00:35:27,520
+دليلا مقبولا ويمكن أن يعتد به بالإضافة إلى أدلة
+
+392
+00:35:27,520 --> 00:35:34,040
+أخرى حديث أم معقل هذا يعني باختصار شديد قصته أنه
+
+393
+00:35:34,040 --> 00:35:38,180
+لما حج رسول الله صلى الله عليه وسلم حجة الوداع
+
+394
+00:35:38,180 --> 00:35:45,660
+بتحكي الأم معقل هذه صحابية أم معقلة تتحدث كأنها
+
+395
+00:35:45,660 --> 00:35:50,220
+تتحدث مع بعض النساء أو في يعني مجلس من المجالس
+
+396
+00:35:50,220 --> 00:35:56,710
+يعنيوكانني بيها تتحصر أنه قد فاتها الحج مع رسول
+
+397
+00:35:56,710 --> 00:36:01,230
+الله صلى الله عليه وسلم بتقول والله لما حج رسول
+
+398
+00:36:01,230 --> 00:36:06,630
+الله صلى الله وسلم فحجت الوداع وكاننا جمل كنا
+
+399
+00:36:06,630 --> 00:36:14,230
+متأملين الحج عليه أبو معقل الله يرحمه جعله في سبيل
+
+400
+00:36:14,230 --> 00:36:22,750
+الله ومش بس هيك و بعد شوية مات كمانيعني هو لو ضله
+
+401
+00:36:22,750 --> 00:36:26,070
+طيب كان ممكن يوفرلنا طريقة ثانية هو جعله في سبيل
+
+402
+00:36:26,070 --> 00:36:31,630
+الله بروح باشتري غيره من حج لكن جعله في سبيل الله
+
+403
+00:36:31,630 --> 00:36:39,390
+ثم مات طيب يعني فحج طبعا فإحنا ماحجين كيبنا الحج
+
+404
+00:36:39,390 --> 00:36:45,310
+الجمل تبعنا موقوف في سبيل الله وماعناش طريقة ثانية
+
+405
+00:36:45,310 --> 00:36:51,120
+الآن يا أخواتيأتي رسول الله أو يعود رسول الله صلى
+
+406
+00:36:51,120 --> 00:36:54,780
+الله عليه وسلم بعد فراغه من الحج يسأل عن أم المعقل
+
+407
+00:36:54,780 --> 00:36:57,560
+وخد فيه إشارة أن النبي صلى الله عليه وسلم كان
+
+408
+00:36:57,560 --> 00:37:01,840
+يتفقد أحوال الناس رجالا ونسان وفي إشارة أخرى أنه
+
+409
+00:37:01,840 --> 00:37:05,320
+يجوز أن يتحدث الرجال مع النساء فيما فيه مصطح للأمة
+
+410
+00:37:05,320 --> 00:37:09,520
+ومصطح للدين ومصطح الشرق كما نتحدث معكم مثلا الآن
+
+411
+00:37:09,520 --> 00:37:16,880
+فسأل طب أنتوا عندكم جمل يعني هافسأل يعني مالذي
+
+412
+00:37:16,880 --> 00:37:21,200
+منعك يا أم معقل؟ فقالت له الخبر يعني والله كان إنه
+
+413
+00:37:21,200 --> 00:37:26,360
+جمل وقف هنا و أبوه معقل و بعدها أبوه معقل ما ..
+
+414
+00:37:26,360 --> 00:37:32,460
+الآن الشاهد .. الآن يأتي الشاهد ليقول ألا أو يعني
+
+415
+00:37:32,460 --> 00:37:38,100
+الرسول صلى الله عليه و سلم أيش بيقول فهل أخرجتي
+
+416
+00:37:40,150 --> 00:37:45,830
+عليه فإن الحجة في سبيل الله هو خلص الوقت ولا ليش؟
+
+417
+00:37:45,830 --> 00:37:51,490
+فالشاهد أنه اعتبر الحجة من باب في سبيل الله يعني
+
+418
+00:37:51,490 --> 00:37:58,170
+أنت لو طلعت عليه كان انت ما تجاوزتي يعني ما فعله
+
+419
+00:37:58,170 --> 00:38:03,210
+زوجك أبو معقل عندما قال في سبيل اللهوحديث اخر هو
+
+420
+00:38:03,210 --> 00:38:09,690
+من نفس الجنس او يعني يدعم ويوافق الحديث الذي قبله
+
+421
+00:38:09,690 --> 00:38:13,050
+حديث ابن عباس امرأة قالت لزوجها حججني زي كل
+
+422
+00:38:13,050 --> 00:38:17,950
+النسوان اللي بتقول تطلب من زوجها حججني يا زلمي قبل
+
+423
+00:38:17,950 --> 00:38:25,050
+مموت احججني مع رسول الله وهي الجمل تبعك قال والله
+
+424
+00:38:25,050 --> 00:38:29,520
+الجمل انا اوقفتههذا الجمل حبسته في سبيل الله
+
+425
+00:38:29,520 --> 00:38:35,340
+أوقفته في سبيل اللهكأن الرسول صلى الله عليه وسلم
+
+426
+00:38:35,340 --> 00:38:41,820
+بعد ذلك سئل في هذه المسألة فقال أما أنك لو أحججتها
+
+427
+00:38:41,820 --> 00:38:47,000
+هذا طيب لسه أما أنك لو أحججتها لكان ذلك في سبيل
+
+428
+00:38:47,000 --> 00:38:50,720
+الله أو كما قال صلى الله عليه وسلم وإضافة إلى كل
+
+429
+00:38:50,720 --> 00:38:54,780
+ذلك فإن رسول الله صلى الله عليه وسلم كما جاء في
+
+430
+00:38:54,780 --> 00:39:02,040
+الخبر كان يحمل من لا يجدون من الصحابةراحلة ما
+
+431
+00:39:02,040 --> 00:39:08,180
+يحملهم على إبل الصدقة إذا إبل الصدقة اللي تعت
+
+432
+00:39:08,180 --> 00:39:14,840
+الذكاء إذا يجوز دفع الذكوات في إعانة الحجاج في
+
+433
+00:39:14,840 --> 00:39:20,040
+مصاريف الحجاج في حمولة الحجاج إلى غير ذلك وأخيرا
+
+434
+00:39:20,040 --> 00:39:25,510
+يعني ما ورد في البخارية عن الحسن قالإن اشترى في
+
+435
+00:39:25,510 --> 00:39:31,510
+بيان ما يجوز صرفه من باب في سبيل الله قال إن اشترى
+
+436
+00:39:31,510 --> 00:39:37,870
+أباه واحد اشترى أبوه رقيق فاشتراه ليحرره إن اشترى
+
+437
+00:39:37,870 --> 00:39:43,290
+أباه ليحرره فهذا في سبيل الله فجاز نعم من الذكاء
+
+438
+00:39:43,290 --> 00:39:47,520
+شراه و لو من ذكاء ماله يعنييجوز ويُعطى في
+
+439
+00:39:47,520 --> 00:39:53,140
+المجاهدين هذا المفروض منه والذي لم يحج والذي لم
+
+440
+00:39:53,140 --> 00:39:57,680
+يحج أي يُعطى من الذكاء ولذلك إيش قال وقال في أيهما
+
+441
+00:39:57,680 --> 00:40:03,300
+في أيها أغطيت أجزأت شكرا لكم
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/lG7qgoZwtnM_raw.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/lG7qgoZwtnM_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..e2cb1325262dd457b659d74bd605d98c126756c3
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/lG7qgoZwtnM_raw.srt
@@ -0,0 +1,1816 @@
+1
+00:00:20,260 --> 00:00:24,620
+بسم الله الرحمن الرحيم الحمد لله والصلاة والسلام
+
+2
+00:00:24,620 --> 00:00:28,420
+على رسول الله وبعد اليوم أيات ولا أخوات
+
+3
+00:00:31,150 --> 00:00:41,110
+نتحدث عن مسألة جديدة من المسائل المعاصرة والتي
+
+4
+00:00:41,110 --> 00:00:48,110
+كثرة شأنها
+
+5
+00:00:48,110 --> 00:00:55,930
+أو كثرة وجودها في هذا الزمان وكثرة تساؤل عنها كذلك
+
+6
+00:00:55,930 --> 00:01:01,950
+وهي مسألة إجهاض الجنين المشوّهوالناتج عند الإتصال
+
+7
+00:01:01,950 --> 00:01:05,930
+أيضا والحقيقة
+
+8
+00:01:05,930 --> 00:01:14,050
+وإن كان مقصودنا الأساسي هو معرفة حكم إجهاض الجنين
+
+9
+00:01:14,050 --> 00:01:22,310
+المشوّه أو الناتج عند الإتصال لكن من
+
+10
+00:01:22,310 --> 00:01:29,020
+الطبيعي وقبل أن نبدأ أو أن نبيّن الحديثعن الحكم
+
+11
+00:01:29,020 --> 00:01:34,500
+قبل أن نبين حكم الجنين المشوّه أو الناتج عن
+
+12
+00:01:34,500 --> 00:01:42,020
+الاختنصاب لابد من بيان بعض المعلومات أو المعطيات
+
+13
+00:01:42,020 --> 00:01:48,840
+التي تمهده لمعرفة هذا الحكم ولتوضيحه
+
+14
+00:01:52,310 --> 00:01:57,150
+فو نحن نتحدث عن الإجهاض عن إجهاض الجنين المشوّه
+
+15
+00:01:57,150 --> 00:02:01,930
+لابد و بشيء من الإجاز أن نتعرف على معنى الجنين و
+
+16
+00:02:01,930 --> 00:02:09,050
+معنى الإجهاض و أن نتعرف على حكم الإجهاض عموما يعني
+
+17
+00:02:09,050 --> 00:02:14,770
+قبل أن نتعرف على حكم الإجهاض للجنين المشوّه لابد
+
+18
+00:02:14,770 --> 00:02:19,470
+أن نعرف ما هو حكم الإجهاض عموما العادى بدون تشويه
+
+19
+00:02:19,470 --> 00:02:26,630
+بدون سببهل هذا موقف الشريعة منهم و لو بشكل موجز
+
+20
+00:02:26,630 --> 00:02:33,170
+وهذا يقتضي منها أن نتحدث عن المراحل التي يتكون
+
+21
+00:02:33,170 --> 00:02:38,170
+منها الجنين أو التي يمر بها الجنين ذلك أن حكم
+
+22
+00:02:38,170 --> 00:02:48,350
+الإجهاض عموما بعيدا عن التشويه مرتبط بالمرحلة التي
+
+23
+00:02:48,350 --> 00:02:57,080
+يمر بها الجنينحكم الإجهاد مرتبط بالمراحل ولذلك
+
+24
+00:02:57,080 --> 00:03:01,700
+ضروري أن نعرف المراحل التي يمروا بها الجنين والحكم
+
+25
+00:03:01,700 --> 00:03:06,620
+المتعلق بكل مرحلة لنتعرف على حكم الإجهاد يعني على
+
+26
+00:03:06,620 --> 00:03:14,850
+وجه العموم يعني هذه ال ..المعاني وغيرها نحاول أن
+
+27
+00:03:14,850 --> 00:03:20,670
+نتحدث عنها أولا قبل أن نبدأ في بيان حكم الإجهاض
+
+28
+00:03:20,670 --> 00:03:24,910
+للجنين المشوّح الأصل
+
+29
+00:03:24,910 --> 00:03:35,490
+يا أخوات في معنى الجنين أو أنه الولد الذي
+
+30
+00:03:35,490 --> 00:03:38,290
+يتكون
+
+31
+00:03:39,760 --> 00:03:44,660
+أو دعني أقول الولد في بطن أمه باختصار الولد ما دام
+
+32
+00:03:44,660 --> 00:03:50,120
+في بطن أمه والولد يشمل الذكر والأنثى الولد ما دام
+
+33
+00:03:50,120 --> 00:03:54,800
+في بطن أمه بعد تكونه يسمى جنة وهنا إشارة إلى أنه
+
+34
+00:03:54,800 --> 00:03:58,640
+قبل التكوين يعني في حالة تكونه مطفى لا يسمى حتى
+
+35
+00:03:58,640 --> 00:04:03,580
+جنة مطفى وعلقة لا يسمى جنية لكن بعد أن يتكون أو
+
+36
+00:04:03,580 --> 00:04:10,340
+يبدأ التخليق له ومراسم الخلقهنا يبدأ يعني يسمى
+
+37
+00:04:10,340 --> 00:04:17,140
+جنينا إلى آخر لحظة قبيل يعني الولادة هذا هو الجنين
+
+38
+00:04:17,140 --> 00:04:24,440
+واصل تسميته بذلك لأنه يعني مختفي عن الأنظار أو لا
+
+39
+00:04:24,440 --> 00:04:25,440
+يراه
+
+40
+00:04:28,740 --> 00:04:35,160
+وأصل الجنين من الفعل جنة بمعنى يعني سطرة بمعنى
+
+41
+00:04:35,160 --> 00:04:43,580
+سطرة فوالجنين صميه بهذا المعنى وحتى المجنون يسمى
+
+42
+00:04:43,580 --> 00:04:49,630
+مجنون لسطر عقله من هذا البابو كثيرة هي المعنى يعني
+
+43
+00:04:49,630 --> 00:04:53,450
+ال .. المترادفات ذات الصلة بهذا أو الاشتقاقات
+
+44
+00:04:53,450 --> 00:05:00,090
+المتعلقة بالفعل جنة فلما جن الليل يعني بمعنى لأن
+
+45
+00:05:00,090 --> 00:05:04,690
+الليل ساتر و يمنع الرؤية فكل ما يمنع الرؤية يسمى
+
+46
+00:05:04,690 --> 00:05:09,190
+يعني .. يعني يأخذ من هذه اللفظة أحد الاشتقاقات
+
+47
+00:05:09,190 --> 00:05:16,450
+المناسبة و منها يعني الجنين سمى بذلك لهذا المعنى
+
+48
+00:05:17,480 --> 00:05:23,940
+وحتى بعد أن أصبح الجنين يمكن أن يعني يصور ويعرف إن
+
+49
+00:05:23,940 --> 00:05:28,360
+كان ذكرا أو أنثى يبقى أيضا يصلح أن يظل اسمه جنينا
+
+50
+00:05:28,360 --> 00:05:33,580
+لأنه حتى وإن صور في لحظة ما أو في ساعة ما يبقى
+
+51
+00:05:33,580 --> 00:05:40,520
+مختفن عن أنظار الناس جميعافإنه مهما خفية شيء عن
+
+52
+00:05:40,520 --> 00:05:48,620
+الناس يبقى واضحاً أمام أخرين أو أمام جهات أخرى و
+
+53
+00:05:48,620 --> 00:05:53,400
+لا يخفى على الله سبحانه وتعالى خافيا أما .. إذا
+
+54
+00:05:53,400 --> 00:05:57,400
+هذا بالنسبة للجنين ولا أنا أحتاج أكتر من ذلك أما
+
+55
+00:05:57,400 --> 00:06:03,080
+بالنسبة للإجهاد الإجهاد
+
+56
+00:06:04,730 --> 00:06:12,910
+بمعنى الإلقاء أو الإسقاط أو الطرح أو الإخراج كل
+
+57
+00:06:12,910 --> 00:06:22,330
+هذه معاني يعني حقيقة للجهاد والأصل
+
+58
+00:06:22,330 --> 00:06:27,500
+فيها المموم جهاد أووأول ما أطلقت .. أو أول ما
+
+59
+00:06:27,500 --> 00:06:34,500
+أطلقت حول إجهاض الجنين تعلقت بجنين أو بإلقاء
+
+60
+00:06:34,500 --> 00:06:42,880
+الناقة ما في بطنها قبل اكتمال مدة الجنين كان ..
+
+61
+00:06:42,880 --> 00:06:49,660
+كان يسمون ذلك إجهاضا ثم أمم لكل أنثى تحمله وتلقي
+
+62
+00:06:49,660 --> 00:06:54,830
+ما في بطنها قبل اكتمال المدةقبل إتمان المدة
+
+63
+00:06:54,830 --> 00:07:00,290
+فالإجهاض هو إذا حقيقة هو إخراج، إلقاء، إسقاط،
+
+64
+00:07:00,290 --> 00:07:05,170
+إنزال الجنين قبل أن يستكمل مدته التسعة أشهر أو
+
+65
+00:07:05,170 --> 00:07:11,880
+السبعة أشهر حسب يعني هذا بالنسباليوهناك حقيقة من
+
+66
+00:07:11,880 --> 00:07:16,640
+العلماء من حاول يفرق بين الإجهاد وبين الإسقاط يعني
+
+67
+00:07:16,640 --> 00:07:19,740
+أنه إن كان متعمدا أو لأن يكن متعمدا لكن هذا
+
+68
+00:07:19,740 --> 00:07:23,840
+التفريق ليس له يعني ما يدل عليه ولا أصله أنا
+
+69
+00:07:23,840 --> 00:07:29,240
+الإجهاد يا عمالانزال عموما لما في البطن قبل اكتمال
+
+70
+00:07:29,240 --> 00:07:33,480
+المدة وبغض النظر عما إذا كان متعمدا أو غير متعمد
+
+71
+00:07:33,480 --> 00:07:37,040
+بسبب أو بغير سبب مشروع أو غير مشروع كله يسمى أجهضة
+
+72
+00:07:37,040 --> 00:07:43,000
+نقول المرأة التي ضربت في بطنها عمدا ونزلت من البطن
+
+73
+00:07:43,000 --> 00:07:49,320
+نقول أجهضت أو أجهضت والتي يعني أنزلت ما في بطنها
+
+74
+00:07:49,320 --> 00:07:57,300
+لمرض أو من غير إرادة أيضا أجهضتفكله يسمى إجهاض
+
+75
+00:07:57,300 --> 00:08:03,460
+والإجهاض له أسباب متعددة الإجهاض له أسباب متعددة
+
+76
+00:08:03,460 --> 00:08:10,540
+يعنيالأسباب الأجهاد قد يكون سببه بغض النظر عن
+
+77
+00:08:10,540 --> 00:08:16,580
+مشروعية أو عدم المشروعية لا أتحدث هنا عن المشروعية
+
+78
+00:08:16,580 --> 00:08:21,640
+قد يكون سببه يعود إلى المرأة نفسه وقد يكون سببه في
+
+79
+00:08:21,640 --> 00:08:27,020
+الجنين نفسه بمعنى أن قد تكون صح المرأة أو الأم
+
+80
+00:08:27,020 --> 00:08:34,220
+حاملة هذا الجنين صحتها لم تحتمل بقاء الجنين فسقط
+
+81
+00:08:35,230 --> 00:08:41,110
+بسبب مرض معين أو إشكال معين في الرحم في القلب في
+
+82
+00:08:41,110 --> 00:08:46,490
+.. في أي عضو من أعضائها أو في صحتها العامة في كثير
+
+83
+00:08:46,490 --> 00:08:48,570
+من النساء يحمل شهر و شهرين و شهرين و شهرين و شهرين
+
+84
+00:08:48,570 --> 00:08:52,960
+و ثلاثة وبعدين بيصير فيه إجهاضلأن صحتها العامة أو
+
+85
+00:08:52,960 --> 00:08:59,180
+بسبب إشكال معين ثم تذهب إلى الطبيب فتتداوى هي من
+
+86
+00:08:59,180 --> 00:09:07,160
+أجل أن يثق الحمل لو قدر الله في مرة .. في مرة أخرى
+
+87
+00:09:07,160 --> 00:09:12,580
+و قد يكون السبب مش المرأة المرأة تكون صحيحة صالحة
+
+88
+00:09:12,580 --> 00:09:18,670
+مائة في المائة لكن الإشكالية في الجنينبسبب مرض في
+
+89
+00:09:18,670 --> 00:09:22,390
+الجنين، بسبب تشوف في الجنين، بسبب ضربة في الجنين،
+
+90
+00:09:22,390 --> 00:09:28,510
+بسبب أي شيء فيسقط الجن أيضاًفتتعدد الأسباب هذا من
+
+91
+00:09:28,510 --> 00:09:34,710
+زاوية من زاوية أخرى فإن الأسباب بعضها ما يكونوا
+
+92
+00:09:34,710 --> 00:09:39,550
+متعمدا يعني احنا نتكلم في الأول يعني بغض عن الجهة
+
+93
+00:09:39,550 --> 00:09:43,770
+بغض النظر عن ما إذا كانت متعمدة أو غير متعمدة التي
+
+94
+00:09:43,770 --> 00:09:52,550
+من ورائها السبب إما أن تكون الأم أو أن تكون المريض
+
+95
+00:09:52,550 --> 00:09:58,270
+نفسه أو آسف الجنين نفسهو قد يكون السبب يا أخوات
+
+96
+00:09:58,270 --> 00:10:03,050
+كما قلت هذا السبب الذي تعرضت له المرأة للاسقاط أو
+
+97
+00:10:03,050 --> 00:10:11,930
+للاجهاد قد يكون متعمدا و قد لا يكون متعمدا و
+
+98
+00:10:11,930 --> 00:10:19,010
+التعمد له صور أو له متعددة قد لا تمتهي و أيضا غير
+
+99
+00:10:19,010 --> 00:10:28,750
+المتعمد له صور متعددة يعني التعمدقد يكون فقط لأنها
+
+100
+00:10:29,500 --> 00:10:32,960
+لا تريد .. لا تريد أولاد كثيرة عندها ثلاثة أربع
+
+101
+00:10:32,960 --> 00:10:37,180
+أولاد و حملت في الولد الخامس قالت أنا يكفيني هذا
+
+102
+00:10:37,180 --> 00:10:41,900
+فأسقطت تعامل عامة بدون سبب فقط لأن عندها أربع خمس
+
+103
+00:10:41,900 --> 00:10:46,460
+أولاد مثلا قد يكون السبب من باب الجير الحفاظ على
+
+104
+00:10:46,460 --> 00:10:51,180
+صحتها العامة قالت أنا أربع خمس أولاد يعني أه وصحتي
+
+105
+00:10:51,180 --> 00:10:55,640
+مابتتحملش أه ربما يكون قد يكون السبب الحلال
+
+106
+00:10:55,640 --> 00:11:01,800
+اقتصادياقد يكون تجهد عمدا بسبب الحالة الاقتصادية
+
+107
+00:11:01,800 --> 00:11:05,440
+يعني بكرا مين بده يعلمه و مين بده يجريه و مين بده
+
+108
+00:11:05,440 --> 00:11:09,840
+يطعمه الويسكي و هكذا احنا لا نتحدث عن مشروعية او
+
+109
+00:11:09,840 --> 00:11:14,140
+عدم مشروعية لكن هذه ربما .. لكن هنتكدث عن عمدية
+
+110
+00:11:14,140 --> 00:11:18,600
+يعني تعمدت او طبعا وقد يكون هذا ال .. هذا العمد
+
+111
+00:11:18,600 --> 00:11:24,580
+مرضه الأم او الأب او الطبيب او غيرهم قد يكون تعمد
+
+112
+00:11:24,580 --> 00:11:33,950
+بسبب نكاية او جرينةضربة في البطن أو يعني بسبب أن
+
+113
+00:11:33,950 --> 00:11:37,650
+هذا الولد الوالد الوحيد للأب وفيه الأخ وإله و بدهم
+
+114
+00:11:37,650 --> 00:11:42,350
+يشيئا مثلا قد نكون ناتج عن جريمة الإسقاط أو الجبهة
+
+115
+00:11:42,350 --> 00:11:46,190
+تتعدى الأسباب العمدية كثيرة جدا وصراها لو بدنا
+
+116
+00:11:46,190 --> 00:11:51,850
+نهزمها ماتنتهيش وهذه العمدية وهذه الأسباب العمدية
+
+117
+00:11:51,850 --> 00:11:57,470
+منها ما هو مشروع لا تظنه ومنها ما هو غير مشروعلأ
+
+118
+00:11:57,470 --> 00:12:00,730
+فالمهم ليس بالضرورة أن كل إسقاط متعمد أن يكون
+
+119
+00:12:00,730 --> 00:12:08,610
+ممنوعا، ليس بالضرورة يعني إذا أحيانا الطبيب يقرر
+
+120
+00:12:08,610 --> 00:12:13,270
+ضرورة إجهاض المرأة وربما تكون في الشهر السابع أو
+
+121
+00:12:13,270 --> 00:12:17,730
+الثامن أو التاسع حفاظا على حياتها لأن حياتها مهددة
+
+122
+00:12:17,730 --> 00:12:22,750
+بالخطر وعلى رأي المثل تبعنا الحقيقي أبقى منهذا مش
+
+123
+00:12:22,750 --> 00:12:29,330
+ميت يعني لكن يعني من حياته متأكدة أولى من من تكون
+
+124
+00:12:29,330 --> 00:12:36,730
+حياته مظلومة فيعني ألقى اليقين و أقدم على الظنف ..
+
+125
+00:12:36,730 --> 00:12:44,950
+لأن هم يجدون او يعني انهم لو .. لو استمرت .. استمر
+
+126
+00:12:44,950 --> 00:12:49,390
+هذا الولد في البطن ربما تموت يعني او في حالة
+
+127
+00:12:49,390 --> 00:12:54,630
+الولادة تموت نساء المرضى بالقلب مثلا نساء مرضى
+
+128
+00:12:54,630 --> 00:12:59,950
+القلب في حين انت الولادة بتموت بالاستقرار اللي
+
+129
+00:12:59,950 --> 00:13:04,340
+عندها مرض في القلبيعني عند الولادة ألم الولادة حد
+
+130
+00:13:04,340 --> 00:13:08,780
+لا تحتمل لها فهكذا في الغالب مثلا و ربما أمراض
+
+131
+00:13:08,780 --> 00:13:14,320
+أخرى يعني لا أدري يعني لكن يعني أحيانا تكون أو
+
+132
+00:13:14,320 --> 00:13:18,680
+ربما كبيرة في السن تحمل و يقرر الطباء عدم إمكانية
+
+133
+00:13:18,680 --> 00:13:23,060
+إنها لو استمر الولد ربما يعرضها لخطر الموت احنا
+
+134
+00:13:23,060 --> 00:13:26,220
+مانتكلمش عن أي خطر يعني عادي خطر الموت هو اللي قد
+
+135
+00:13:26,220 --> 00:13:32,160
+يكون مسور يعني بمعنى إنه الإسقاط المتعمدقد يكونوا
+
+136
+00:13:32,160 --> 00:13:37,380
+مشروعا و قد لا يكونوا مشروعا ولعله في أغلبه غير
+
+137
+00:13:37,380 --> 00:13:41,960
+مشروع لكنه و الإسقاط و في المقابل قد لا يكونوا
+
+138
+00:13:41,960 --> 00:13:50,740
+متعمدا طب المرأة وقعد على الذراجسقط الجنين زوجة
+
+139
+00:13:50,740 --> 00:13:56,540
+خبطها هو هيك مش قاصد سقط الجنين قد يحدث هذا وذاك
+
+140
+00:13:56,540 --> 00:14:04,020
+شربة حبوب لمرض معين قتلت الجنين في أثر سلبي جانبي
+
+141
+00:14:04,020 --> 00:14:12,250
+قد يعني أسباب كثيرة يعني لا إراديةو بالخطأ تحدث
+
+142
+00:14:12,250 --> 00:14:16,950
+هذا كله طبعا هذا لا يعني بالضرورة ان كل اسقاط كان
+
+143
+00:14:16,950 --> 00:14:21,780
+بالخطأ مافيش عليه توابعوكل إسقاط بالعمد وإن كان
+
+144
+00:14:21,780 --> 00:14:25,980
+مشروعا يعني بضرورة أو ممنوعا احنا نتكلمش عن
+
+145
+00:14:25,980 --> 00:14:30,640
+التوابع لأنه او الآثار المترتبة على الإسقاط
+
+146
+00:14:30,640 --> 00:14:34,300
+المشروع او غير المشروع لأنه أساسا هذا مرتبط أصلا
+
+147
+00:14:34,300 --> 00:14:38,200
+أولا بالمرحلة التي تم فيها وقتين الشهر الأول ولا
+
+148
+00:14:38,200 --> 00:14:40,940
+الثاني ولا الثالث ولا الرابع ولا الخامس ولا التاسع
+
+149
+00:14:41,720 --> 00:14:46,560
+ومرتبط بكون هذا العمل يعني عمدا او غير عمدا ومشروع
+
+150
+00:14:46,560 --> 00:14:51,040
+او غير مشروع بعد هيك ترتب الأثار تختلف هل في يعني
+
+151
+00:14:51,040 --> 00:14:55,480
+ديا ولا مافيش ديا في تعزير ولا مافيش تعزير في ..
+
+152
+00:14:55,480 --> 00:14:58,920
+تعتبر جريمي ولا لا تعتبر هذا شيء و آخر لأ نتحدث
+
+153
+00:14:58,920 --> 00:15:03,040
+ليس هو بيت القصيد لكن احنا اللي بدنا نقوله ان
+
+154
+00:15:03,040 --> 00:15:07,260
+الإجهاض له أسباب كثيرة حقيقة متعددة بعضها مشروع
+
+155
+00:15:07,260 --> 00:15:12,140
+وبعضها غير مشروع بعضها متعمد واخر غير متعمدوبعضها
+
+156
+00:15:12,140 --> 00:15:16,280
+يعود للمرأة وبعضها يعود للطفل نفسه أو الوليد
+
+157
+00:15:16,280 --> 00:15:22,620
+وبعضها يعود للطبيب وبعضها يعني أسباب متعددة في هذا
+
+158
+00:15:22,620 --> 00:15:27,480
+الأمر لكن
+
+159
+00:15:27,480 --> 00:15:33,360
+مدام .. مدام الإجهاض يعني له أسباب متعددة ويعني
+
+160
+00:15:33,360 --> 00:15:39,160
+ويمكن الأسباب حقيقة يا أخوات كثير إلها دخل في
+
+161
+00:15:39,160 --> 00:15:46,100
+مسألة الحكملكن إلى جانب الأسباب احنا بدنا نعرف أيش
+
+162
+00:15:46,100 --> 00:15:52,960
+السبب لمعرفة الحكم جيد لكن مع السبب ليكون الحكم
+
+163
+00:15:52,960 --> 00:16:00,040
+دقيقا لابد من معرفة المرحلة أو السن أو العمر تبع
+
+164
+00:16:00,040 --> 00:16:04,020
+الجنين متى تم الإسقاط يعني احنا عشان نعرف الحكم
+
+165
+00:16:04,020 --> 00:16:09,500
+نعرف سبب الإسقاط و متى وقع الإسقاط يعني ممكن أنهم
+
+166
+00:16:09,500 --> 00:16:15,190
+بقواأه بالظبط والحقيقة احنا في عندنا محطة رئيسية
+
+167
+00:16:15,190 --> 00:16:22,010
+اولا لابد يعني هذه قاسم لابد من يتميز يتميز فيه
+
+168
+00:16:22,010 --> 00:16:27,850
+الحكم بجلال لدينا قاسم محطة رئيسية وهي محطة نفخ
+
+169
+00:16:27,850 --> 00:16:34,940
+الروحمحطة نفخ الروح فليس يعني في أن حكم عام فليس
+
+170
+00:16:34,940 --> 00:16:42,020
+الحكم هو يمكن أن يقرر هو أنه ليس الحكم في الإجهاض
+
+171
+00:16:42,020 --> 00:16:50,720
+ما بعد النفخ كالحكم ما قبل النفخ هذا باتفاق باتفاق
+
+172
+00:16:50,720 --> 00:16:55,620
+ليس الحكم أنا ماقررتش حكم تفصيلي كحكم عام بحكي أنا
+
+173
+00:16:55,620 --> 00:17:05,620
+ليس الحكمفي إجهاض الجنين قبل نفخه كإجهاضه بعد نفخه
+
+174
+00:17:05,620 --> 00:17:17,820
+حتى عند من قال حتى عند من قال بالتحريم في كل مراحل
+
+175
+00:17:17,820 --> 00:17:26,350
+تكوين الجنين فإن حرمة تختلف عن حرمةحتى وإن كنا وإن
+
+176
+00:17:26,350 --> 00:17:30,810
+وجدنا بعض العلماء كما سنرى بعد قليل يقولون بتحريم
+
+177
+00:17:30,810 --> 00:17:36,310
+الإجهاد من اللحظة الأولى التي تستقر فيها النطفة في
+
+178
+00:17:36,310 --> 00:17:42,830
+رحم المرأة يحرم لكن حكم التحريم في الأيام الأولى
+
+179
+00:17:42,830 --> 00:17:47,810
+أو في الأشهر الأولى إلى ما قبل نفخ الروح يختلف
+
+180
+00:17:47,810 --> 00:17:58,170
+والأثار كذلك تختلف والأثار كذلك تختلفطيب طيب هذا
+
+181
+00:17:58,170 --> 00:18:03,930
+يعني يدعون إلى شيء ربما مهم و هو متى تنفخ الروح
+
+182
+00:18:03,930 --> 00:18:11,870
+متى تنفخ الروح المعروف لدينا و لديكم ربما أنه أنها
+
+183
+00:18:11,870 --> 00:18:15,490
+تنفخ بعد أربعة شهور يعني أو بعد تحديدا مائة و
+
+184
+00:18:15,490 --> 00:18:23,410
+عشرين و هذا ما عليه جماهير العلماء جمهور العلماء
+
+185
+00:18:23,410 --> 00:18:32,110
+بلإن من العلماء من نقل الإجماعة على ذلك يعني احنا
+
+186
+00:18:32,110 --> 00:18:34,770
+طبعا وعارفين وفاهمين احنا شرعيين وفاهمين لما نقول
+
+187
+00:18:34,770 --> 00:18:40,250
+جمهور يعني في فريق اخر لكن عشان يبينوا ان هذا فريق
+
+188
+00:18:40,250 --> 00:18:46,110
+من الجماهير فريق كبير جدا وربما ان وجد مخالف فهو
+
+189
+00:18:46,110 --> 00:18:51,550
+كشاذ نقل البعض ايه الاجماعة الاجماعة قال هناك
+
+190
+00:18:51,550 --> 00:19:00,780
+اتفاق اتفاقعلى أن الروح تنفخ بعد 120 يوم وهذا
+
+191
+00:19:00,780 --> 00:19:07,360
+الاتفاق دليله الحديث الصحيح دليله الحديث الصحيح
+
+192
+00:19:07,360 --> 00:19:11,840
+الوارد
+
+193
+00:19:11,840 --> 00:19:16,460
+في حديث مسلم أو في صحيح مسلم الذي قال فيه النبي
+
+194
+00:19:16,460 --> 00:19:21,900
+صلى الله عليه وسلم إن أحدكم يجمع خلقه في بطن أمه
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+195
+00:19:21,900 --> 00:19:27,000
+أربعين يوماثم يكونوا
+
+196
+00:19:29,410 --> 00:19:34,630
+يجمعوا خلقوه في بطن أمه اربعين يوما مطفة ثم يكونوا
+
+197
+00:19:34,630 --> 00:19:40,410
+علقة اربعين اخرى يعني مثل ذلك ثم يكونوا مضغة مثل
+
+198
+00:19:40,410 --> 00:19:45,930
+ذلك يعني هاي اربع تلت تلت مراحل اربعين اربعين
+
+199
+00:19:45,930 --> 00:19:49,610
+اربعين يعني كده؟ مائة و عشرين يعني اربعة شهور تلت
+
+200
+00:19:49,610 --> 00:19:53,330
+مراحل لكن اربعة شهور مش تلت اشهر تلت مراحل كل مرحل
+
+201
+00:19:53,330 --> 00:20:00,030
+اربعين يوم اربعين يوم كل اربعين يوميتغير طبيعة
+
+202
+00:20:00,030 --> 00:20:07,810
+الخلق لهذا الجنين اربعين يوم نطفة اربعين يوم علقة
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+203
+00:20:07,810 --> 00:20:14,210
+اربعين يوم مضغة ثم ماذا ينفخ فيه ثم يرسل اليه ملك
+
+204
+00:20:14,210 --> 00:20:20,650
+يرسل ربنا سبحانه وتعالى اليه ملك لينفخ فيه من روحه
+
+205
+00:20:20,650 --> 00:20:25,010
+لتلقى
+
+206
+00:20:25,010 --> 00:20:30,320
+فيه الحياةالى ما قبل ذلك كان كأنه عضو من أعضاء
+
+207
+00:20:30,320 --> 00:20:37,960
+الإنسان لكن الآن ألقيت فيه روح صار نفس .. نفس لكن
+
+208
+00:20:37,960 --> 00:20:42,260
+ربما غير متيقنة فقط ال .. ال .. ال .. غير متيقنة
+
+209
+00:20:42,260 --> 00:20:46,140
+الحياة عند الولادة لكن هي نفس بكل معنى الكلمة من
+
+210
+00:20:46,140 --> 00:20:52,150
+وجهه ولذلك لو أتدى عليها شخصفإنه يكون مجرما إن كان
+
+211
+00:20:52,150 --> 00:20:57,490
+متعمدا وليس له في ذلك يعني مسوغ ويترتب على ذلك
+
+212
+00:20:57,490 --> 00:21:03,490
+يعتبر قاتل لنفسه لكن مافيش فيها قصاص فيها الديا
+
+213
+00:21:03,490 --> 00:21:09,270
+غره يعني عشر أو عشرين أو نص الخلاف بين العلماء عشر
+
+214
+00:21:09,270 --> 00:21:12,810
+الديا يعني حوالي عشرة من القبل وفي بعض الرواية
+
+215
+00:21:12,810 --> 00:21:18,670
+خمسة من القبل على كل الأحوالثم يُرسلوا إليه ملك
+
+216
+00:21:18,670 --> 00:21:26,730
+فينفخ فيه الروح ويأمر بأربع كلمات بكتب رزقه وأجله
+
+217
+00:21:26,730 --> 00:21:32,570
+وشقيه أم سعيد هذا الحديث حقيقة صريح وصحيح وواضح
+
+218
+00:21:32,570 --> 00:21:41,330
+الدلالة فعلا في أن الروح أتنفخ بعد 124
+
+219
+00:21:41,330 --> 00:21:41,590
+أيام
+
+220
+00:21:45,550 --> 00:21:51,210
+قوله صلى الله عليه وسلم فيما يرويه أيضًا الإمام
+
+221
+00:21:51,210 --> 00:21:57,750
+مسلم في صحيحه أنه قال صلى الله عليه وسلم يدخل
+
+222
+00:21:57,750 --> 00:22:02,910
+الملك على النطفة بعد ما تستقر في الرحم باربعين
+
+223
+00:22:02,910 --> 00:22:09,630
+يوما يدخل الملك أقول لو لا هذا الحديثلولا قوله صلى
+
+224
+00:22:09,630 --> 00:22:14,670
+الله عليه وسلم يدخل الملك على النطفة بعدما تستقر
+
+225
+00:22:14,670 --> 00:22:19,970
+في الراحمة أربعين يوما أو خمسة واربعين فيقول يا رب
+
+226
+00:22:19,970 --> 00:22:24,870
+يا شقيقى من سعيد لولا هذا الحديث الذي يومئه أقول
+
+227
+00:22:26,200 --> 00:22:34,040
+ولا يعني يصرح يومي إيمان أو يشير إشارة بأن النفخ
+
+228
+00:22:34,040 --> 00:22:39,760
+يكون بعد أربعين لو لا هذا الحديث لوجدنا إجماعة لكن
+
+229
+00:22:39,760 --> 00:22:48,140
+هذا الحديث الذي قد يفهم منه أن أن الروح تنفخ بعد
+
+230
+00:22:48,140 --> 00:22:51,900
+أربعين يوما لقوله صلى الله عليه وسلم يدخل الملك
+
+231
+00:22:51,900 --> 00:22:58,160
+على النطفة بعدما تستقر في الراحب بأربعين يوماوجدنا
+
+232
+00:22:58,160 --> 00:23:03,180
+بعض العلماء يقول لا يا عمي هذا الروح تنفخ بعد
+
+233
+00:23:03,180 --> 00:23:08,200
+أربعين يوم وهي الحديث وكأن طب الحديث السابق ربما
+
+234
+00:23:08,200 --> 00:23:12,720
+يعتبرون هذا مثلا لأحك وهذا سابق منسوخ أو إلى غير
+
+235
+00:23:12,720 --> 00:23:21,540
+ذلك وجدنا فرق لكن لحظة رأي العلماء في جمهرتهموالذي
+
+236
+00:23:21,540 --> 00:23:26,180
+قد يكون مجماعا على الحديث الأول طيب ما تفسيرهم
+
+237
+00:23:26,180 --> 00:23:29,640
+للحديث الثاني و هو حديثهم الصحيح يبقى هنا يعني
+
+238
+00:23:29,640 --> 00:23:34,540
+سؤال يعني ماذا سيقولون أنا بقول في عندي حديث
+
+239
+00:23:34,540 --> 00:23:41,120
+أربعين يوم حقيقة هناك أكثر من تفسير للحديث أو لرد
+
+240
+00:23:41,120 --> 00:23:45,460
+الحديث طبعا أولا الحديث الأول اللي اعتمدوا عليه
+
+241
+00:23:45,460 --> 00:23:54,540
+حديث صحيح وصريحفي أن الروح تنفخ وذكروا كلمة النفخ
+
+242
+00:23:54,540 --> 00:24:02,180
+صريحة وثابتة في الحديث والتفصيل لكن انظروا إلى
+
+243
+00:24:02,180 --> 00:24:09,140
+الحديث الثاني لم يذكر فيه النفخ ذكر صحيح أن الملك
+
+244
+00:24:09,140 --> 00:24:14,080
+يدخل لكن هل بالضرورة إذا دخل الملك سينفخ؟
+
+245
+00:24:17,570 --> 00:24:23,530
+إذا ليس في الحديث ما يدله دلالة صريحة على أن النفخ
+
+246
+00:24:23,530 --> 00:24:29,030
+وذاك يدله دلالة صريحة أي هما نقدم هذا من جهة من
+
+247
+00:24:29,030 --> 00:24:35,150
+جهة التانية قالوا وهذا يحمل الحديث الثاني حديث
+
+248
+00:24:35,150 --> 00:24:46,900
+يدخل الملك يحمله على أحد وجهين إماأنه إن قلنا أنه
+
+249
+00:24:46,900 --> 00:24:55,020
+يعني أنه تنفخ الروح فلأن بعض الحالات قالوا يمكن أن
+
+250
+00:24:55,020 --> 00:24:59,560
+يكون النفخ بعد الأربعين في بعض الحالات النادرة
+
+251
+00:24:59,560 --> 00:25:04,100
+القليلة فيستوعبها
+
+252
+00:25:04,100 --> 00:25:08,840
+هذا الحديث لكن الأصل أن النفخ يكون بعد أربعين بعد
+
+253
+00:25:08,840 --> 00:25:17,610
+مائة وعشرين يوم لكن يبدو أن هناكحالات ينفخ فيها
+
+254
+00:25:17,610 --> 00:25:25,190
+الروح مبكرا فكان هذا الحديث ولعل هذا يعني تحليل أو
+
+255
+00:25:25,190 --> 00:25:32,410
+تأويل ضعيف لكن الأقوى الوجه الأقوى في أن المقصود
+
+256
+00:25:32,410 --> 00:25:39,490
+أنهيعني أن الملك عندما أن الله عز وجل جعل كما جعل
+
+257
+00:25:39,490 --> 00:25:45,430
+لكل تصرفات الإنسان و لكل شيء في هذا الكون ملائكة
+
+258
+00:25:45,430 --> 00:25:46,430
+تقوم عليها
+
+259
+00:25:49,880 --> 00:25:55,180
+أقرقب وعتيد وإلى غير ذلك ولكل شيء جعل للرحم ملكا
+
+260
+00:25:55,180 --> 00:25:58,400
+فإذا
+
+261
+00:25:58,400 --> 00:26:03,180
+دخلت كما ورد في بعض الشروح فإذا دخلت أو استقرت
+
+262
+00:26:03,180 --> 00:26:11,240
+النطفة دخل الملك إذا استقرت النطفة دخل الملك وقبل
+
+263
+00:26:11,240 --> 00:26:19,720
+أن تنتقل إلى أو تصبح مضغبعد الاربعين اه وبعد ان
+
+264
+00:26:19,720 --> 00:26:27,460
+استقرت دخل الملك فنادى فينادي ربه يدخل الملك ليكون
+
+265
+00:26:27,460 --> 00:26:32,300
+حارسا على هذا الجنين فاذا
+
+266
+00:26:32,300 --> 00:26:37,860
+وصلت او استقرت حتى وصل الاربعين يوم يصير مضغة
+
+267
+00:26:37,860 --> 00:26:43,640
+ينادي رب العزيزي ينادي رب العزيزي هل هذه النطفة
+
+268
+00:26:43,640 --> 00:26:49,690
+ستبقىأم ستفنى يعني لأن الجنين يا أخوات فيه أكتير
+
+269
+00:26:49,690 --> 00:26:58,030
+تحمل تحمل المرأة بعد شهر فلا يكون الله عز وجل قد
+
+270
+00:26:58,030 --> 00:27:04,690
+قدره حتى أن تنتقل إلى مضغة أو إلى علقةفحتى انتقال
+
+271
+00:27:04,690 --> 00:27:10,070
+المراحل
+
+272
+00:27:10,070 --> 00:27:13,730
+الجنين من مرحل لمرحل كله بإذن الله سبحانه وتعالى
+
+273
+00:27:13,730 --> 00:27:21,630
+وملك موكل بهذا الأمر فيقول يا رب هذه النطفا هل
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+274
+00:27:21,630 --> 00:27:26,730
+ستبقى فإن أجيب ببقائها
+
+275
+00:27:28,960 --> 00:27:33,480
+بقيت وتحولت إلى .. فإن انتهت مدتها إلى أن أصبحت
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+276
+00:27:33,480 --> 00:27:40,660
+علقة وعندما تستقر علقة بعد أربعين يوم أخرى أيضا
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+277
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+ينادي ربه هل ستبقى؟ فإن أمر بالبقاء بقيت ثم تحولت
+
+278
+00:27:46,060 --> 00:27:51,850
+إلى مضغةوبعد المضغة إذا هو مجرد سؤال عن أو مجرد
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+279
+00:27:51,850 --> 00:27:59,550
+يعني أنه يدخل لحراسة هذه الجنين ومعرفة ما إذا يعني
+
+280
+00:27:59,550 --> 00:28:08,230
+ما مهمته في التواقل بهذا الأمر حتى تنتهي
+
+281
+00:28:08,230 --> 00:28:13,210
+المرحلة الثالثة وهي مرحلة المضغة فينفخ فيه الروح
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+282
+00:28:13,670 --> 00:28:18,570
+يعني إذا أمر الله سبحانه وتعالى ببقاء مضغة في
+
+283
+00:28:18,570 --> 00:28:25,040
+المرحلة الثالثةأخذ الأمر ببقاء الروح ولعل هذا يعني
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+284
+00:28:25,040 --> 00:28:30,200
+التفسير يكونوا يعني مقبولا يعني يدخل الملك لأنه
+
+285
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+موكل بهذا الأمر كما أن كل شيء في هذه الدنيا موكل
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+286
+00:28:34,080 --> 00:28:38,960
+إليه ملائكة الرياح والبحار وإلى كل شيء له يعني
+
+287
+00:28:38,960 --> 00:28:44,180
+ملائكة موكلة بأعمال هذه الدنيا بعلم الله وبأمر
+
+288
+00:28:44,180 --> 00:28:49,450
+الله سبحانهوتعالى بغض النظر عن هذه التفاصيل لكن
+
+289
+00:28:49,450 --> 00:28:53,990
+احنا نرجع ونقول او هذه التفسيرات نرجع نقول ان
+
+290
+00:28:53,990 --> 00:28:59,790
+جمهور العلماء بل كما قلت يكاد يكون اجماعا ان ال ..
+
+291
+00:28:59,790 --> 00:29:05,590
+ان الروح تنفخ بعد ال 120 وعليه سيعتمد وعليه
+
+292
+00:29:05,590 --> 00:29:10,150
+المؤتمد في حكم الإجهاض وعليه المؤتمد في حكم
+
+293
+00:29:10,150 --> 00:29:17,100
+الإجهاض ومدى بعد 120 يومالان ما قبل ال 120 في حكم
+
+294
+00:29:17,100 --> 00:29:21,360
+عام انه بيختلف عن ما بعد ال 120 لكن مع ذلك ثم
+
+295
+00:29:21,360 --> 00:29:26,420
+تختلاف بين مرحلة و مرحلة برضه يعني مرحلة ال 120
+
+296
+00:29:26,420 --> 00:29:30,400
+يوم الإجهاض في الشهر الأول حكمه يختلف عن الإجهاض
+
+297
+00:29:30,400 --> 00:29:32,620
+في الشهر الثاني أو في المرحلة الأولى دعنا نقول
+
+298
+00:29:32,620 --> 00:29:36,560
+يختلف عن المرحلة الثانية يختلف عن المرحلة الثالثة
+
+299
+00:29:36,560 --> 00:29:43,400
+وأستطيع أن أقول قبل التفصيل أنه كل ما اقترب شكل
+
+300
+00:29:43,400 --> 00:29:51,620
+الجنيةالجنين من نفخ الروح كلما كثر القائلين او قوى
+
+301
+00:29:51,620 --> 00:29:56,460
+قول القائلين بالحرمة وكثر وكلما كان في البداية
+
+302
+00:29:56,460 --> 00:30:02,620
+يعني وجدنا مرونة ووجدنا فريقا واسع يقول بالجواز
+
+303
+00:30:02,620 --> 00:30:06,860
+نعم بس بالنسبة للتفسير التالي اللي قال النادي رباه
+
+304
+00:30:06,860 --> 00:30:11,220
+ايقنع ايقضى فهو من الحديث الذكر يُكتب واشتغل عام
+
+305
+00:30:11,220 --> 00:30:14,510
+سنة من الاربعينوليس إتباعات و إتباعات بيصير
+
+306
+00:30:14,510 --> 00:30:17,850
+إتباعات من جهة تانية، يعني بيكون التفسير اللي قاله
+
+307
+00:30:17,850 --> 00:30:21,170
+يافنا أنه بقى الحديث و هم ينظروا إلى بقى الحديث،
+
+308
+00:30:21,170 --> 00:30:27,230
+لإن بقى الحديث هان يكتبهطب نرجع للحديث شوي الحديث
+
+309
+00:30:27,230 --> 00:30:33,210
+إيش بيقول يدخل الملك على النطفة تمام بعد ما تستقر
+
+310
+00:30:33,210 --> 00:30:37,570
+في الرحم باربعين يوما أو خمسة واربعين فيقول يا ربي
+
+311
+00:30:37,570 --> 00:30:45,750
+أشقي أم سعيد ليس بالضرورة أن يكون قوله يعني الملك
+
+312
+00:30:45,750 --> 00:30:55,300
+لربه أشقي أم سعيد بعد الدخول مباشرة تماموإنما قوله
+
+313
+00:30:55,300 --> 00:31:00,320
+أشقيه أم ساعد بعد نفخ الروح أو وقت تكون أسئلة
+
+314
+00:31:00,320 --> 00:31:05,020
+مضمرة لم يذكرها الحديث هنا اللي جاءت في شروحات
+
+315
+00:31:05,020 --> 00:31:10,260
+أخرى أنه بعد الأربعين هو قام بذلك حتى نفخ فيه
+
+316
+00:31:10,260 --> 00:31:14,720
+الروح قال أشقيه أم ساعد لأن الأسئلة متكررة في كل
+
+317
+00:31:14,720 --> 00:31:19,220
+مرحلة تخدت بالك؟بس أنا فاهم ان ذلك لكن هو لما قال
+
+318
+00:31:19,220 --> 00:31:22,920
+هيقول و الفلاق تدل على التركيب مع الصدقة تدل على
+
+319
+00:31:22,920 --> 00:31:25,640
+القول بس .. على أي حال هو هذا يعني احد .. احنا في
+
+320
+00:31:25,640 --> 00:31:30,360
+تفسير اخر احنا قولناها في الأول ان هذا للدلالة على
+
+321
+00:31:30,360 --> 00:31:36,240
+ان بعض العلماء أو بعض الحالات قد .. نادرة قد يكون
+
+322
+00:31:36,240 --> 00:31:43,980
+فيها يعني نفخ نعم بعد 40 يوم انا لست لدي استقراء
+
+323
+00:31:45,340 --> 00:31:50,300
+ومعرفة الحقيقة الأصلى أن يُسأل الأطباء إذا كان
+
+324
+00:31:50,300 --> 00:31:56,760
+فعلا في حالات معينة هل يمكن بعد أربعين يوما إذا تم
+
+325
+00:31:56,760 --> 00:32:01,900
+الإسقاط هل يمكن أن يهدأ يعني مخلوقا فعلا يعني ما
+
+326
+00:32:01,900 --> 00:32:08,280
+هو لمن ينفخ فيه الروح كأن بيه قد تخلق أم أن هذا
+
+327
+00:32:08,280 --> 00:32:13,700
+التخلق الذي يستحب مع نفخ الروحيعني لا يكونوا إلا
+
+328
+00:32:13,700 --> 00:32:21,420
+بعد أربعة أشهر أو بعد مائة وعشرين يوما إذا ثبت أنا
+
+329
+00:32:21,420 --> 00:32:28,340
+أقول إذا ثبت أنه و لو في حالات معينة بعد أربعين
+
+330
+00:32:28,340 --> 00:32:32,240
+يوما أو خمسين ستين يوم أو يعني يمكن أن يكون هناك
+
+331
+00:32:32,240 --> 00:32:36,360
+تخليق قبل المائة وعشرين ونفخ أو تشعر المرأة بحركة
+
+332
+00:32:36,360 --> 00:32:39,920
+أو إلى غير ذلك لأن المرأة معروفة أنها تشعر بحركة
+
+333
+00:32:39,920 --> 00:32:49,570
+الولد بعد الشهر الرابعلأ طب أنا مجرد لأ
+
+334
+00:32:49,570 --> 00:32:54,070
+لأ لأ هو طبعا ممكن يعني في حالات معينة في الأعام
+
+335
+00:32:54,070 --> 00:32:58,350
+الأغلب في الأعام الأغلب المرأة في الشهر الرابع
+
+336
+00:32:58,350 --> 00:33:07,230
+تبدأ تشعر بحركة الجنين صحيح اه فلذلك يعني لكن انا
+
+337
+00:33:07,230 --> 00:33:15,280
+اقول ان حدث ان أمكن معرفةإن كان فعلا في يعني تخليق
+
+338
+00:33:15,280 --> 00:33:21,200
+بعد قبل هذه المدة طبعا بعد ال 120 الحركة والتخليق
+
+339
+00:33:21,200 --> 00:33:26,160
+بتمأه لكن قبل هذه المدة إن تم تخليق في بعض الحالات
+
+340
+00:33:26,160 --> 00:33:30,180
+النادرة يمكن أن يقبل التفسير الأول ويصبح الحديثين
+
+341
+00:33:30,180 --> 00:33:36,020
+متكاملين ليشمل كل الحالة ليشمل كل الحالة لكن إذا
+
+342
+00:33:36,020 --> 00:33:39,740
+كان والله بالخلال الاستقرار بالفعل لا يكون تخليقا
+
+343
+00:33:39,740 --> 00:33:43,540
+ولا نفخا ولا تحركا إلا في الشهر الرابع أو بعد ال
+
+344
+00:33:43,540 --> 00:33:47,100
+120 يوم يعني ربما يكون التفسير الثاني هو الصحيح اه
+
+345
+00:33:47,100 --> 00:33:47,400
+طبعا
+
+346
+00:33:52,860 --> 00:33:57,320
+يمنع ذلك إذا أنا بقول إذا أنا احنا .. احنا المعيار
+
+347
+00:33:57,320 --> 00:34:04,460
+معيار الحلو الحرمي متفق عليه أنه بعد النفخ بعد
+
+348
+00:34:04,460 --> 00:34:10,800
+النفخ أصلا بعد النفخ يا أخوات سنجد أنه بعد النفخ
+
+349
+00:34:10,800 --> 00:34:17,500
+يحرموا اتفاق فالذين سيقولون أن النفخ بعد الأربعين
+
+350
+00:34:17,500 --> 00:34:24,120
+سيحرم بعد الأربعين المعيار هو النفخو قبل النفخ فيه
+
+351
+00:34:24,120 --> 00:34:29,620
+خلاف بعد النفخ ليس ثمة من خلاف في حرب الإجهاد إذا
+
+352
+00:34:29,620 --> 00:34:36,040
+كان متعمدا و بلا مسور شرعي قبل النفخ سنرى قبل
+
+353
+00:34:36,040 --> 00:34:43,560
+النفخ مرتبط بكل مرحل لدينا ثلاث مراحل لكن .. لكن
+
+354
+00:34:43,560 --> 00:34:49,700
+برضه زي ما قلت في الأول كل حالات الإجهاد اللي بتتم
+
+355
+00:34:49,700 --> 00:34:51,240
+قبل النفخ
+
+356
+00:34:53,340 --> 00:34:59,120
+بغض النظر في أي مرحلة من المراحل حتى وإن قلنا
+
+357
+00:34:59,120 --> 00:35:06,660
+بحرمتها الحرمة فيها ليست كالحرمة التي يقولها التي
+
+358
+00:35:06,660 --> 00:35:14,760
+يقولها القائلون وهو محل الجماعة بعد النفخ يعني
+
+359
+00:35:14,760 --> 00:35:21,660
+مثلا كالمدخنو .. و .. و شارب الخمر هذا حرام و هذا
+
+360
+00:35:21,660 --> 00:35:28,260
+حرام لكن شارب الخمر يعني جريمته أكبر و يترتب عليها
+
+361
+00:35:28,260 --> 00:35:34,480
+أيضا عقوبة واضحة لكن هل شارب الخمر .. المدخن نقول
+
+362
+00:35:34,480 --> 00:35:40,860
+أنه يحرم عليهم لكن هل يعتبر نجلده و لا .. من
+
+363
+00:35:40,860 --> 00:35:44,880
+ثمانين جلدة و لا .. دي اختلف الحالة لكن لا .. لا
+
+364
+00:35:44,880 --> 00:35:50,210
+.. لا نتردد في أنه حرامو هنا حُرمة تختلف عن حُرمة
+
+365
+00:35:50,210 --> 00:35:58,190
+و أثر عن الحُرمة مختلف عن أثر عن الحُرمة و هكذاإذا
+
+366
+00:35:58,190 --> 00:36:02,810
+نفخ الروح على الرأي العلماء والذين قد يصل إلى درجة
+
+367
+00:36:02,810 --> 00:36:08,550
+الإجماع أنه يكون بعد 120 يوما وفي هذه المدة يمر
+
+368
+00:36:08,550 --> 00:36:14,190
+الجنين بثلاث مراحل يعني إلى ما قبل نفخ الروح لكل
+
+369
+00:36:14,190 --> 00:36:24,250
+مرحلة حكومها لكل مرحلة حكومها أما المرحلة الأولى
+
+370
+00:36:24,250 --> 00:36:28,640
+اللي هي مرحلةالمطفة المرحلة الأولى مرحلة المطفة
+
+371
+00:36:28,640 --> 00:36:32,280
+يعني بعد اللي احنا لما اتكلمنا المرة اللي فاتت عن
+
+372
+00:36:32,280 --> 00:36:38,040
+الاستنساخ يعني قشرنا ان عند .. يعني عندما يتم
+
+373
+00:36:38,040 --> 00:36:42,120
+تلقيح السائل المناور مع البويضة تتم اللقيحة وتبدأ
+
+374
+00:36:42,120 --> 00:36:47,620
+المطفة تستقر تبقى مطفةحتى إلى مدة أربعين يوم ..
+
+375
+00:36:47,620 --> 00:36:51,380
+مدة أربعين يوما إلى .. إلى ما قبل أن تتغير إلى
+
+376
+00:36:51,380 --> 00:36:56,480
+علقة شكلا محسوسا يعني شكل مختلف يختلف النطفة تختلف
+
+377
+00:36:56,480 --> 00:37:01,080
+عن العلقة يعني ولذلك المراحل .. في مراحل .. في
+
+378
+00:37:01,080 --> 00:37:07,580
+مراحل حسية مادية مرئية ترى تغيرا في شكل الجنين
+
+379
+00:37:07,580 --> 00:37:15,330
+ومراحل معنوية متعلقة بالنفخالنفخ فاصل مرحلي معنوي
+
+380
+00:37:15,330 --> 00:37:25,010
+لأنه هو لما ينفخ حقيقة بيكون تخلق تخلق تخلق وممكن
+
+381
+00:37:25,010 --> 00:37:28,630
+يعني اه بس في الأساس نعم في الأساس هو معنوي يعني
+
+382
+00:37:28,630 --> 00:37:34,390
+لأن الخلق كما هو ثم نفخت بجه خلق بصورة معينة لكن
+
+383
+00:37:34,390 --> 00:37:40,180
+جامد زي عروس الجفصين ونفخ فيها الروحفصارت تتحرك في
+
+384
+00:37:40,180 --> 00:37:45,440
+هذه الحالة يعني بمعنى أنه يعني الأمر أكتر منه
+
+385
+00:37:45,440 --> 00:37:50,360
+معنوي منه ما .. ماصارش فيه زيادة في الخلق صار ربما
+
+386
+00:37:50,360 --> 00:37:53,640
+زيادة بعد هيك في الحركة و كبر و إلى نيرلر نعم طب
+
+387
+00:37:53,640 --> 00:37:56,820
+عارف ان ضغط القلب عند الجنين تبدأ تقريبا الشهر
+
+388
+00:37:56,820 --> 00:38:02,680
+التالف؟هل نبض القلب همأنه سبب الروح؟ مش عارف و
+
+389
+00:38:02,680 --> 00:38:07,740
+الله .. اه لكن هل مؤكد ان نبض القلب يبدأ من الشهر
+
+390
+00:38:07,740 --> 00:38:14,600
+الثاني؟ انا بقول لا .. لا .. لا بأس و ممكن .. ممكن
+
+391
+00:38:14,600 --> 00:38:19,880
+يكون مالوش علاقة بنفخ الروح لأنه يعني الخلايا هذه
+
+392
+00:38:19,880 --> 00:38:25,950
+تبدأ في التكوينكل خلية لوحدها ويمكن طبيعة القلب
+
+393
+00:38:25,950 --> 00:38:31,430
+كخلية متكام كأضو أنه ينبض من لحظة تكوينه ليس
+
+394
+00:38:31,430 --> 00:38:34,930
+بالضرورة أن يكون هناك علاقة بين النفخ وبين نبض
+
+395
+00:38:34,930 --> 00:38:43,830
+القلب ربما لا يكون ذلك بالضرورة يعني نعم نعم
+
+396
+00:38:43,830 --> 00:38:53,010
+مافيش مشكلة جيبي ونشوف كيففي المرحلة الأولى طيب لو
+
+397
+00:38:53,010 --> 00:39:00,870
+أننا احنا الآن حكم واحدة واحدة خلينا حكم الإجهاد
+
+398
+00:39:00,870 --> 00:39:05,530
+في المرحلة الأولى في الأربعين الأولى في حالة كون
+
+399
+00:39:05,530 --> 00:39:12,270
+الجنين أو ما في البطن النطفة ما .. ما الحكم و بدون
+
+400
+00:39:12,270 --> 00:39:19,930
+أسبابطبعا السؤال هنا الفرضية بدون سبب مشروع يعنى،
+
+401
+00:39:19,930 --> 00:39:26,730
+يعني مش لأنه خايف من الموت أو من الخطر الصحي ومش
+
+402
+00:39:26,730 --> 00:39:36,590
+لأنه مثلا إيش نقول؟ حالة قصادية، مشوّه يعني لأ
+
+403
+00:39:36,590 --> 00:39:40,700
+المشوّه يعني أنا ..هذه محل الخلافة اللي بدنا نصل
+
+404
+00:39:40,700 --> 00:39:45,800
+إليه، يعني ليس تمت سبب مقبول يعني شرعا أنه مثلا
+
+405
+00:39:45,800 --> 00:39:53,920
+الحالة المرأة لا تحتمل أو يعني سقطت لحالها، هل؟ لأ
+
+406
+00:39:54,580 --> 00:39:59,680
+في تعمد بدون وجه شرقي لأن زي ما قلتلكوا قبل بشوية
+
+407
+00:39:59,680 --> 00:40:04,400
+في عندها ولدين تلاتة بدأت بعد بين مسافات الحمل و
+
+408
+00:40:04,400 --> 00:40:08,000
+حمل آخر لسه السنة اللي فاتت ولدت مثلا تقولك انا اش
+
+409
+00:40:08,000 --> 00:40:12,440
+بدي في هالشغل مهل خليني انا اتبح بقى اتريحلي شوية
+
+410
+00:40:12,440 --> 00:40:18,040
+عندها غيلة او إلى غير ذلك فصار في حمل مرات ما هو
+
+411
+00:40:18,040 --> 00:40:24,420
+المرأة تاخد حبوب حمل و تحمليعني او بتركب لأولك
+
+412
+00:40:24,420 --> 00:40:29,840
+وتحمل و إلى غير ذلك بيصير في أشياء زيها فتتفاجأ
+
+413
+00:40:29,840 --> 00:40:35,160
+المرأة فبتقولك على البدري انا اجهز او انزل لأول
+
+414
+00:40:35,160 --> 00:40:39,700
+شخص ما الحكم بدون يعني سبب معقول يعني فقط لأنه
+
+415
+00:40:39,700 --> 00:40:43,600
+صحتها لأن الظروف العامة اللي هي مافيش يعني خطورة
+
+416
+00:40:43,600 --> 00:40:50,020
+معينة أو وجه شرعي سليم جمهور العلماء يعني خلنا
+
+417
+00:40:50,020 --> 00:40:59,000
+نقولجمهور علماء الحنافية انتبهوا وجمهور علماء
+
+418
+00:40:59,000 --> 00:41:07,820
+الشافعية او أكثرهم وكذلك جمهور علماء الحنابلة وبعض
+
+419
+00:41:07,820 --> 00:41:15,620
+المالكية كمان يرون إباحة الإسقاط يجوز مع الكراه
+
+420
+00:41:15,620 --> 00:41:24,440
+بين جثين من غير سببمن غير سبب، يجوز مع الكراها،
+
+421
+00:41:24,440 --> 00:41:30,260
+هذا طبعا .. هذا مش بإرادته من باب أولى، احنا إجهاض
+
+422
+00:41:30,260 --> 00:41:34,400
+متعمد، يا أخوات نحن نتحدث هنا عن إجهاض متعمد،
+
+423
+00:41:34,400 --> 00:41:39,200
+الإجهاض اللي متعمد ما .. ما ..مسلم إنه مافيش مشكلة
+
+424
+00:41:39,200 --> 00:41:44,100
+فيه الإجهاد اللا إرادي لما بعد شهر ولا شهرين بيسقط
+
+425
+00:41:44,100 --> 00:41:49,960
+هذا الجنين و هو .. و لو أنها بتستناه من عشر سنين
+
+426
+00:41:49,960 --> 00:41:55,120
+مرات نصبن عنها أيه ما باليد هي مش بس .. هي مش بس
+
+427
+00:41:55,120 --> 00:41:59,260
+مالهاش إرادة هي بدها .. بتعرفش فيه mask بدها
+
+428
+00:41:59,260 --> 00:42:07,550
+وبسنانها لكن نجي نصبن عنها نحن نتحدث عنإجهاب متعمد
+
+429
+00:42:07,550 --> 00:42:13,990
+بلا سبب مشروع بلا سبب في
+
+430
+00:42:13,990 --> 00:42:17,230
+الشهر الأول أو في المرحلة الأولى في حالة كون
+
+431
+00:42:17,230 --> 00:42:23,590
+الجنين نطفة أكثر العلماء على الإباحة بين جوسين مع
+
+432
+00:42:23,590 --> 00:42:29,160
+الكراها خلافا للمالكيةجمهور المالكية من اللحظة
+
+433
+00:42:29,160 --> 00:42:35,060
+الأولى التي تستقر فيها من اليوم الأول التي تستقر
+
+434
+00:42:35,060 --> 00:42:44,480
+فيها النطفة يحرم الإجهاض وعليه الفتوى عندنا
+
+435
+00:42:44,480 --> 00:42:49,540
+بالمناسبة يعني أي واحد بيسألنا بناخد رأي المالكية
+
+436
+00:42:49,540 --> 00:42:55,740
+احتياطةلكن حقيقة للأمان العلمية وفي العلم الشرعي و
+
+437
+00:42:55,740 --> 00:42:59,500
+التخصصي احنا لابد ان نذكر القرار جمهورنا طبعا
+
+438
+00:42:59,500 --> 00:43:06,140
+لاحظوا جمهور
+
+439
+00:43:06,140 --> 00:43:10,420
+الحنافية يقولون بالجواز لكن بعض الحنافية مع
+
+440
+00:43:10,420 --> 00:43:14,920
+المالكية وبعض الشافعية مع المالكية وبعض الحنابلة
+
+441
+00:43:14,920 --> 00:43:21,280
+مع المالكية برضه يعني برضه في فريقفي فريق قوي يقول
+
+442
+00:43:21,280 --> 00:43:28,940
+بالحرم لكن في فريق ربما اكثر من حيث الكثرة لا من
+
+443
+00:43:28,940 --> 00:43:34,120
+حيث القوة من حيث الكثرة العددية الاكترية يقولون
+
+444
+00:43:34,120 --> 00:43:39,980
+بالجواز ولا علا يعني المسوق عندهم انهم يعنيإنه هذا
+
+445
+00:43:39,980 --> 00:43:46,740
+يعني ليس إنسانا وليس خلقا ويشعر الإنسان .. يعني
+
+446
+00:43:46,740 --> 00:43:52,900
+ربما أقول يشبه كأي زائدة مضرة للإنسان يشتشعر بأنه
+
+447
+00:43:52,900 --> 00:43:57,180
+لا حاجة له فيها فالزائدة اللي بتكون الزوائد هذه
+
+448
+00:43:57,180 --> 00:44:00,550
+اللي في الإنسانيعني أغلب العلماء على جواز بترها
+
+449
+00:44:00,550 --> 00:44:03,950
+يعني لو حتى أصبع زائد مع أنه فيه خلافات لكن الأغلب
+
+450
+00:44:03,950 --> 00:44:08,910
+يجوز بترها ويجوز فهذه ما لم تنفخ فيها الروح تصل في
+
+451
+00:44:08,910 --> 00:44:13,270
+الشهر الأول أو في البدايات هذه يعني .. يعني كما
+
+452
+00:44:13,270 --> 00:44:20,290
+يعني تبروها يعني ك .. يعني كقطر الدم أو قطر تمانيه
+
+453
+00:44:20,290 --> 00:44:24,750
+أو لا غير ده لا .. لا إشكالة في ذلك لا .. فش ..
+
+454
+00:44:24,750 --> 00:44:27,130
+طيب هذا في الح .. في المرحلة الأولى
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/mCAd92EPBDw_raw.json b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/mCAd92EPBDw_raw.json
new file mode 100644
index 0000000000000000000000000000000000000000..9868dae2f57c9e477d46b5d956f463f72518eb39
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/mCAd92EPBDw_raw.json
@@ -0,0 +1 @@
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"end": 2436.78, "word": " أدلة", "probability": 0.8655598958333334}, {"start": 2436.78, "end": 2437.38, "word": " القول", "probability": 0.93359375}, {"start": 2437.38, "end": 2437.66, "word": " ..", "probability": 0.276123046875}, {"start": 2437.66, "end": 2438.06, "word": " يعني", "probability": 0.782958984375}, {"start": 2438.06, "end": 2438.28, "word": " لو", "probability": 0.69873046875}, {"start": 2438.28, "end": 2438.58, "word": " نريد", "probability": 0.84130859375}, {"start": 2438.58, "end": 2438.74, "word": " أن", "probability": 0.93896484375}, {"start": 2438.74, "end": 2439.16, "word": " نستبق", "probability": 0.942626953125}, {"start": 2439.16, "end": 2439.7, "word": " الأحداث", "probability": 0.9747314453125}, {"start": 2439.7, "end": 2440.24, "word": " لكن", "probability": 0.7421875}, {"start": 2440.24, "end": 2440.64, "word": " أدلة", "probability": 0.9754231770833334}, {"start": 2440.64, "end": 2441.0, "word": " القائمة", "probability": 0.677490234375}, {"start": 2441.0, "end": 2441.52, "word": " الجواز", "probability": 0.9635416666666666}, {"start": 2441.52, "end": 2441.88, "word": " هي", "probability": 0.96044921875}, {"start": 2441.88, "end": 2442.08, "word": " من", "probability": 0.974609375}, {"start": 2442.08, "end": 2442.84, "word": " المنطقية", "probability": 0.97626953125}, {"start": 2442.84, "end": 2443.58, "word": " والمعقولية", "probability": 0.8115641276041666}, {"start": 2443.58, "end": 2444.2, "word": " خاصة", "probability": 0.96142578125}, {"start": 2444.2, "end": 2444.34, "word": " ..", "probability": 0.76953125}, {"start": 2444.34, "end": 2445.52, "word": " خاصة", "probability": 0.9876302083333334}, {"start": 2445.52, "end": 2446.06, "word": " إذا", "probability": 0.9384765625}, {"start": 2446.06, "end": 2446.24, "word": " ما", "probability": 0.444580078125}, {"start": 2446.24, "end": 2446.74, "word": " اقترنت", "probability": 0.946533203125}, {"start": 2446.74, "end": 2448.2, "word": " بشروط", "probability": 0.61395263671875}, {"start": 2448.2, "end": 2448.94, "word": " ليكون", "probability": 0.95166015625}, {"start": 2448.94, "end": 2449.34, "word": " هناك", "probability": 0.98876953125}, {"start": 2449.34, "end": 2449.6, "word": " نوع", "probability": 0.99609375}, {"start": 2449.6, "end": 2449.78, "word": " من", "probability": 0.9931640625}, {"start": 2449.78, "end": 2450.52, "word": " التوازن", "probability": 0.9915771484375}, {"start": 2450.52, "end": 2451.08, "word": " ونوع", "probability": 0.88427734375}, {"start": 2451.08, "end": 2451.24, "word": " من", "probability": 0.99560546875}, {"start": 2451.24, "end": 2451.64, "word": " تحقيق", "probability": 0.9935302734375}, {"start": 2451.64, "end": 2452.28, "word": " المصارح", "probability": 0.73822021484375}, {"start": 2452.28, "end": 2452.9, "word": " بين", "probability": 0.9873046875}, {"start": 2452.9, "end": 2453.88, "word": " هؤلاء", "probability": 0.971923828125}, {"start": 2453.88, "end": 2454.4, "word": " وهؤلاء", "probability": 0.885546875}, {"start": 2454.4, "end": 2455.2, "word": " شكرا", "probability": 0.8914388020833334}, {"start": 2455.2, "end": 2455.54, "word": " لكم", "probability": 0.953125}, {"start": 2455.54, "end": 2456.0, "word": " والسلام", "probability": 0.7251790364583334}, {"start": 2456.0, "end": 2456.4, "word": " عليكم", "probability": 0.888671875}], "temperature": 1.0}], "language": "ar", "language_probability": 1.0, "duration": 2457.46075, "duration_after_vad": 2396.5247187499926}
\ No newline at end of file
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/tME1Zcugy78.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/tME1Zcugy78.srt
new file mode 100644
index 0000000000000000000000000000000000000000..17fbfb2c2cbbb754e3a3ac6cb11f50c3612024b3
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/tME1Zcugy78.srt
@@ -0,0 +1,1376 @@
+1
+00:00:00,000 --> 00:00:01,540
+موسيقى
+
+2
+00:00:21,160 --> 00:00:23,680
+بسم الله الرحمن الرحيم الحمد لله رب العالمين
+
+3
+00:00:23,680 --> 00:00:27,200
+والصلاة والسلام على أشرف المرسلين محمد صلى الله 
+
+4
+00:00:27,200 --> 00:00:32,920
+عليه وسلم وعلى آله وصحبه وسلم تسليماً كثيراً حديثنا 
+
+5
+00:00:32,920 --> 00:00:42,580
+اليوم عن قتل الرحمة ماذا 
+
+6
+00:00:42,580 --> 00:00:47,540
+يقصد به؟ متى ظهر 
+
+7
+00:00:50,150 --> 00:00:59,990
+ما هي أشكاله وأنواعه؟ ما هو الموقف الشرعي من 
+
+8
+00:00:59,990 --> 00:01:06,370
+قتل الرحمة؟ وما يتعلق بقتل الرحمة من المسائل؟
+
+9
+00:01:06,370 --> 00:01:13,570
+بدايةً، أيها الأخوات أريد أن أقول أن قتل الرحمة 
+
+10
+00:01:13,570 --> 00:01:20,830
+أو كما يسمى بالموت الرحيم أو قتل الشفقة أو القتل 
+
+11
+00:01:20,830 --> 00:01:27,730
+الموت الميسر أو القتل أو الموت الجيد كما يعبر عنه 
+
+12
+00:01:27,730 --> 00:01:34,050
+باللغة الإنجليزية Good Death أو يعني مسميات كثيرة 
+
+13
+00:01:34,050 --> 00:01:38,630
+لهذا أنه 
+
+14
+00:01:38,630 --> 00:01:43,930
+تدور حول نفس المعنى ونفس الفكرة 
+
+15
+00:01:55,470 --> 00:02:06,450
+هذا القتل المسمى بهذا الاسم بدايةً أقول 
+
+16
+00:02:06,450 --> 00:02:13,370
+أن هذا القتل وراءه دوافع ذلك أن الإنسان بطبيعته 
+
+17
+00:02:13,370 --> 00:02:23,120
+بطبيعته يحب الحياة ويحرص على... ويحافظ على نفسه 
+
+18
+00:02:23,120 --> 00:02:30,300
+من أن تصيبها أي خطر أو أي مرض بل ربما يقاتل الآخر 
+
+19
+00:02:31,420 --> 00:02:34,820
+من أجل الحفاظ على نفسه إذا أراد الآخر أن يعتدي 
+
+20
+00:02:34,820 --> 00:02:40,780
+عليه هذه طبيعة في الإنسان الإنسان يحب الحياة ويدافع 
+
+21
+00:02:40,780 --> 00:02:47,720
+عن حياته بكل الوسائل الإنسان بطبيعته وفي هذه الفترة إذا 
+
+22
+00:02:47,720 --> 00:02:53,680
+أصيب بأي مرض فإنه يسعى للاستشفاء وللدواء و
+
+23
+00:02:53,680 --> 00:02:56,800
+للتطبيب بكل الوسائل 
+
+24
+00:03:00,660 --> 00:03:05,780
+الإنسان بطبيعته إذا 
+
+25
+00:03:05,780 --> 00:03:11,620
+شعر أيضاً كما قلت بأي اعتداء فإنه يواجه هذا 
+
+26
+00:03:11,620 --> 00:03:16,700
+الاعتداء مهما كانت التكاليف لكن في بعض الأحيان في 
+
+27
+00:03:16,700 --> 00:03:19,180
+نفس الوقت هذا هو... هذا... هذا هي... هذه هي 
+
+28
+00:03:19,180 --> 00:03:23,160
+النفسية طبيعة النفس الإنسانية بشكل عام لكن في نفس 
+
+29
+00:03:23,160 --> 00:03:30,660
+الوقت أحياناً قد يمر الإنسان بظروف صحية أو نفسية 
+
+30
+00:03:30,660 --> 00:03:39,820
+صعبة بظروف صحية أو نفسية صعبة للغاية تسبب له آلاماً 
+
+31
+00:03:39,820 --> 00:03:46,100
+أيضاً يعني أقول مادية أو معنوية تسبب له آلاماً شديدة 
+
+32
+00:03:46,100 --> 00:03:53,950
+ومستمرة ومتواصلة بحيث يستشعر بعد ذلك أو أثناء ذلك 
+
+33
+00:03:53,950 --> 00:04:03,550
+برغبته في ترك هذه الحياة يستشعر برغبته في الموت 
+
+34
+00:04:03,550 --> 00:04:08,130
+في قاف الحياة 
+
+35
+00:04:08,130 --> 00:04:15,550
+عنده أو ربما تكون هذه الآلام التي تصيبه المعنوية 
+
+36
+00:04:15,550 --> 00:04:23,950
+أو النفسية تدفع الآخرين ليس هو تدفع الآخرين من ذويه 
+
+37
+00:04:23,950 --> 00:04:29,130
+أو من الأطباء أو من المسؤولين في المجتمع الذي 
+
+38
+00:04:29,130 --> 00:04:35,710
+يعيش فيه تدفعهم في التفكير في إيقاف يعني أو في 
+
+39
+00:04:35,710 --> 00:04:41,830
+وضع حد لحياته بحجة... بحجة مختلفة بحجة إيقاف 
+
+40
+00:04:41,830 --> 00:04:51,770
+المعاناة تبعته أو تخفيف النفقات أو الوضع الاقتصادي 
+
+41
+00:04:51,770 --> 00:04:56,950
+العام أو مراعاة أحوال ذويه أو إلى غير ذلك من أسباب 
+
+42
+00:04:56,950 --> 00:05:05,610
+قد هنا وهناك ومن 
+
+43
+00:05:07,170 --> 00:05:14,050
+وبسبب وجود مثل هذه الدوافع والأسباب ظهر في بعض 
+
+44
+00:05:14,050 --> 00:05:23,290
+الأزمان وعن بعض الأشخاص وفي بعض المجتمعات فكرة 
+
+45
+00:05:23,290 --> 00:05:29,130
+قتل الرحمة فكرة أن يضع الإنسان حدًا لحياته ولكن 
+
+46
+00:05:29,130 --> 00:05:35,470
+بطريقة يعني فيها نوع من الراحة وليس فيها تعذيب ولا 
+
+47
+00:05:35,470 --> 00:05:41,250
+تمثيل ولا إلا غير ذلك بقصد إيقاف هذا الألم المصاحب 
+
+48
+00:05:41,250 --> 00:05:49,370
+لهذا الإنسان ظن منهم ربما... ليس مدافعا... ظن منهم 
+
+49
+00:05:49,370 --> 00:05:54,190
+أن هذا فيه المصلحة وهذا فيه الخير سواء للمريض 
+
+50
+00:05:54,190 --> 00:06:02,970
+نفسه أو لطبيه أو للمجتمع أو لغيره وأولاً وأولاً و 
+
+51
+00:06:02,970 --> 00:06:06,310
+تتم 
+
+52
+00:06:06,310 --> 00:06:15,580
+تتم عملية القتل هذه أو الإماتة هذه بصور متعددة...
+
+53
+00:06:15,580 --> 00:06:21,220
+بصور متعددة مجموعها 
+
+54
+00:06:21,220 --> 00:06:28,000
+في ثلاثة صور مجموعها في ثلاثة صور رئيسية الصور 
+
+55
+00:06:28,000 --> 00:06:35,120
+الأولى عن طريق أخذ جرعات جرعات 
+
+56
+00:06:35,120 --> 00:06:44,410
+الدواء مضادة... مسكنة للألم لكن تكون كبيرة فتكون 
+
+57
+00:06:44,410 --> 00:06:50,110
+مسكنة للحياة مميتة في الآخر يعني أحياناً ممكن واحد 
+
+58
+00:06:50,110 --> 00:06:54,410
+يأخذ حبة دواء مضاد حيوي يعني تكون فيها... يعني 
+
+59
+00:06:54,410 --> 00:06:58,990
+للاستشفاء لو أخذ... لو أخذ شريط كامل ممكن يموت 
+
+60
+00:06:58,990 --> 00:07:06,350
+مضاد حيوي مسكن يعني بعض ال... الأجهزة التي تحس 
+
+61
+00:07:06,350 --> 00:07:11,550
+بالألم لكن شميد كامل ممكن يسكن الجسد كله فما 
+
+62
+00:07:11,550 --> 00:07:16,610
+السبب؟ أيّة مشكلة في نفس الدواء يا ماني؟ كثرتُه...
+
+63
+00:07:16,610 --> 00:07:20,770
+آه كثرتُه تصير الجرعة كبيرة خالص يعني هو الواحد لو 
+
+64
+00:07:20,770 --> 00:07:23,670
+أخذ جرعة سم صغيرة ممكن ما يموتش لو أخذ جرعة سم 
+
+65
+00:07:23,670 --> 00:07:26,610
+كبيرة يموت وهكذا يعني حتى الدواء ما هو الدواء 
+
+66
+00:07:26,610 --> 00:07:31,560
+عبارة عن سموم في أكثرُه يعني ولهِ أعراض جانبية كثيرة 
+
+67
+00:07:31,560 --> 00:07:37,660
+ويقول لماذا نحن في الدواء نشترط وصفة الطبيب لأنه 
+
+68
+00:07:37,660 --> 00:07:41,840
+هو الذي يعطيك الجرعة المناسبة التي يكون فيها 
+
+69
+00:07:41,840 --> 00:07:45,600
+الشفاء ولا يكون فيها الداء ولا يكون فيها المرض أو 
+
+70
+00:07:45,600 --> 00:07:51,220
+... آه نعم إذا أما أن يكون بأخذ جرعة الدواء هي في 
+
+71
+00:07:51,220 --> 00:07:57,010
+الأصل دواء لكن كثيرة كثيرة فتسبب الموت طبعاً جرع 
+
+72
+00:07:57,010 --> 00:08:00,870
+الدواء أو إبرة معينة إبرة في الأصل إنها تكون ممكن 
+
+73
+00:08:00,870 --> 00:08:05,810
+يعني في وضع طبيعي بنسب تخفيف معينة تكون فيها الشفاء 
+
+74
+00:08:05,810 --> 00:08:13,850
+لكن بدون تخفيف تكون فيها الموت والقتل أو عن طريق 
+
+75
+00:08:13,850 --> 00:08:18,970
+يعني في ناس كثير لما في حوادث معينة بمجرد ما يصاب 
+
+76
+00:08:18,970 --> 00:08:23,430
+بالحادث يعني نظراً لحالته الخطيرة والحرجة يركب له 
+
+77
+00:08:23,430 --> 00:08:28,530
+جهاز التنفس لأنه في عنده صعوبة في التنفس إلى أن يتم 
+
+78
+00:08:28,530 --> 00:08:35,730
+يعني شفاؤه وتستقر حالته وتستقر حالته و 
+
+79
+00:08:35,730 --> 00:08:47,610
+أحياناً تستمر مدة اضطراب الحالة وبالتالي تستمر مدة 
+
+80
+00:08:47,610 --> 00:08:57,310
+استمرار استعمال الجهاز عند ذلك بعد استشعار ما ذكرنا 
+
+81
+00:08:57,310 --> 00:09:04,630
+من حالات سواء اشتداد الألم بالنسبة للمريض أو كثرة 
+
+82
+00:09:04,630 --> 00:09:08,070
+النفقات بالنسبة للمستشفى أو كثرة المتاع بالنسبة 
+
+83
+00:09:08,070 --> 00:09:14,450
+للأهل قد يطلب من هؤلاء أو أولئك نزع المنفس، نزع 
+
+84
+00:09:14,450 --> 00:09:19,880
+الجهاز عنه وطبيعي إنه في الغالب هيموت بعد ساعة، 
+
+85
+00:09:19,880 --> 00:09:24,560
+ساعتين، يوم، يومين، يموت هذه أيضاً صورة من صورة 
+
+86
+00:09:24,560 --> 00:09:31,420
+قتل الرحمة، بنزع الأجهزة عنه أو قد تكون صورة ثالثة 
+
+87
+00:09:31,420 --> 00:09:37,860
+بمنع العلاج عنه العلاج العادي، منع العلاج يعني 
+
+88
+00:09:37,860 --> 00:09:41,280
+احنا في الصورة الأولى، لأ أنت مش علاج، أنت بتعطي 
+
+89
+00:09:41,280 --> 00:09:48,120
+مضاد يعني جرعة مميتة مش كعلاج بتعطيه جرعة اللي 
+
+90
+00:09:48,120 --> 00:09:52,600
+تميته لكن الآن أنت هو بياخذ علاج تتوقف حياته عليه 
+
+91
+00:09:52,600 --> 00:09:57,300
+في ناس كثير حياته متوقفة على حبة حبوب يومية على 
+
+92
+00:09:57,300 --> 00:10:03,220
+إبرة في اليوم حياته متوقفة إذا ما أخذهاش معرض للموت 
+
+93
+00:10:03,220 --> 00:10:10,060
+طريقة... ممكن تقول صورة من صورة الموت للرحيم وقف 
+
+94
+00:10:10,060 --> 00:10:16,100
+العلاج عنده خلاص ما بطلبه أنا بقول أما بطلب المريض 
+
+95
+00:10:16,100 --> 00:10:22,000
+لشدة المعاناة أو بطلب الطبيب أو بطلب ذوي المريض أو 
+
+96
+00:10:22,000 --> 00:10:27,360
+بطلب الحاكم ممكن آه ممكن احنا ما نتكلمش عن الشرعية 
+
+97
+00:10:27,360 --> 00:10:33,540
+ وعدم الشرعية لكن احنا الدوافع والأسباب ممكن فهذه 
+
+98
+00:10:33,540 --> 00:10:37,340
+الصور ولو... لو دققتنا قليلاً في هذه الصور الثلاث 
+
+99
+00:10:37,340 --> 00:10:41,960
+بنلاقي الصور الأولى والثانية يعني تكون بتدخل من 
+
+100
+00:10:41,960 --> 00:10:48,720
+الإنسان طبيب أوي بتدخل بإعطاء الجرعة أو نزع المنفاس 
+
+101
+00:10:48,720 --> 00:10:55,140
+بتدخل فعال ولذلك تسمى بالقتل الفعال أو الإيجابي 
+
+102
+00:10:55,140 --> 00:11:02,020
+القتل الإيجابي اللي بيسموه رحيم أو شفقة أو إلى غير 
+
+103
+00:11:02,020 --> 00:11:12,090
+ذلك والصورة الثالثة قتل سلبي بالامتناع عنه هناك 
+
+104
+00:11:12,090 --> 00:11:16,990
+بالتدخل والفعل أنت لما أعطيته جرعة تدخلت لما أنت 
+
+105
+00:11:16,990 --> 00:11:21,650
+نزعت المنفاس تدخلت بيدك نزعتُه لكن الآن ما فعلت شيء 
+
+106
+00:11:21,650 --> 00:11:26,510
+غاية ما في الأرض أنك لم تقدم له ما ينبغي أن يقدم 
+
+107
+00:11:26,510 --> 00:11:32,370
+لم تفعل تماماً كما الغريق 
+
+108
+00:11:33,680 --> 00:11:39,040
+الذي يعني يراه إنسان قادر على إنقاذه فلا يقدم له 
+
+109
+00:11:39,040 --> 00:11:44,760
+شيئاً يمتنع وهو قادر على تقديم فهو قاتل يعتبر 
+
+110
+00:11:44,760 --> 00:11:51,640
+بالتسبب بالتسبب بطريق الامتناع امتنع عن إنقاذه وهو 
+
+111
+00:11:51,640 --> 00:11:56,380
+ويرى يغرق وكان قادر وهو قاتل بالامتناع عن 
+
+112
+00:11:56,380 --> 00:12:01,180
+الفعلي ليس بضرورة أن يكون القتل بالفعل بل بالامتناع 
+
+113
+00:12:01,180 --> 00:12:06,650
+عن الفعل أنت أدخلت واحد في غرفة ما ماتش بيموتش لما 
+
+114
+00:12:06,650 --> 00:12:10,030
+تدخله في الغرفة لكن لما تتركه بلا أكل ولا شرب 
+
+115
+00:12:10,030 --> 00:12:14,190
+أسبوع زمان يموت هذا قتل بالترك أو بالامتناع عن 
+
+116
+00:12:14,190 --> 00:12:20,370
+تقديم ما... ما... ما... ما من شأنه أن تستمر الحياة 
+
+117
+00:12:20,370 --> 00:12:24,770
+من طعام أو غذاء أو شراب أو دواء أنت هنا في الحالة 
+
+118
+00:12:24,770 --> 00:12:29,090
+اللي بين إيدنا تمنع عن إعطائه الدواء اللي تتوقف 
+
+119
+00:12:29,090 --> 00:12:34,230
+حياته عليه ويسمى بالقتل السلبي أو القتل المنفعل 
+
+120
+00:12:34,230 --> 00:12:41,690
+المنفعل هناك فعال وهنا منفعل كما سماه البعض هذا 
+
+121
+00:12:41,690 --> 00:12:48,150
+القتل أيضاً يا أخوات يعني اللي يسمى أو أشد على أنه 
+
+122
+00:12:48,150 --> 00:12:53,170
+يسمى بقتل الرحمة لأنه ليس تمة من قتل اسمه قتل 
+
+123
+00:12:53,170 --> 00:13:01,090
+الرحمة كل أنواع القتل وبأي شكل كان هو اعتداء وهو 
+
+124
+00:13:01,090 --> 00:13:07,610
+ظلم وهو عدوان وهذه مسألة تسميته بالرحمة تسمية 
+
+125
+00:13:07,610 --> 00:13:14,310
+غربية تسمية غربية ونظراً 
+
+126
+00:13:14,310 --> 00:13:21,250
+لمادية الباحثين من أولئك الذين نشأت عندهم هذه الفكرة 
+
+127
+00:13:21,250 --> 00:13:27,130
+هذه فكرة... فكرة قتل الرحمة أساساً منشؤها البيئة 
+
+128
+00:13:27,130 --> 00:13:33,410
+الغربية البيئة المادية التي تسيطر عليها المادة و
+
+129
+00:13:33,410 --> 00:13:41,250
+... و... و ليس لديهم يعني في الغالب إيمان بالقيم وإيمان 
+
+130
+00:13:41,250 --> 00:13:45,330
+ب... بال... بال... حتى بال... بال... بال 
+
+131
+00:13:45,330 --> 00:13:55,460
+... بالآخرة وما يترتب عليها من ثواب أو عقاب ولذلك 
+
+132
+00:13:55,460 --> 00:14:05,000
+لو احنا فتشنا عن تاريخ ظهور فكرة قتل الرحمة 
+
+133
+00:14:05,000 --> 00:14:12,760
+وابتدائها سنجد أنها عند الغرب ومنذ قرون طويلة منذ 
+
+134
+00:14:12,760 --> 00:14:19,760
+أيام فلسفة الغرب اللي هم المشهورين أفلاطون وسقراط 
+
+135
+00:14:19,760 --> 00:14:29,290
+هؤلاء الذين ظهرت في البدايات عندهم الفكرة وكانوا 
+
+136
+00:14:29,290 --> 00:14:36,060
+يسمونها بالتدبير الذاتي للموت بشرف التدبير الذاتي 
+
+137
+00:14:36,060 --> 00:14:44,720
+للموت بشرف كان كما سماها سقراط وكان أفلاطون من 
+
+138
+00:14:44,720 --> 00:14:54,780
+قبله يعني كان يحملوا فكرة أن يترك المرضى للموت دون 
+
+139
+00:14:54,780 --> 00:15:00,080
+أن يقدم لهم العلاج المرضى الذين يعني 
+
+140
+00:15:02,600 --> 00:15:07,640
+يحتاجون إلى علاجات طويلة وكثيرة ويتألمون أن 
+
+141
+00:15:07,640 --> 00:15:14,680
+يتركوا للموت وأن لا يقدموا لهم العلاج لما في ذلك 
+
+142
+00:15:14,680 --> 00:15:21,280
+من تكاليف ولما في ذلك من آلام لأنهم يحتاجوا كثيراً 
+
+143
+00:15:21,280 --> 00:15:25,520
+تلحق بالمرض وتلحق بهذه الفكرة ناشئة من هؤلاء 
+
+144
+00:15:25,520 --> 00:15:30,180
+أصحاب الفلسفة بالنسبة للغرب 
+
+145
+00:15:31,720 --> 00:15:37,460
+المصطلح... مصطلح القتل أو الموت ال... ال... ال...
+
+146
+00:15:37,460 --> 00:15:44,720
+ال... الجيد أو ال... أو الميسر أو القتل الشفقة بدأ 
+
+147
+00:15:44,720 --> 00:15:53,100
+يتبرر ويصبح مصطلحاً في... في عام ألف وتسعمائة أو 
+
+148
+00:15:53,100 --> 00:15:59,810
+ألف و متين و... و... و... و... ونايف يعني في ال... 
+
+149
+00:15:59,810 --> 00:16:04,010
+في منتصف القرن الثالث عشر تقريباً على لسان 
+
+150
+00:16:04,010 --> 00:16:07,150
+الفيلسوف الإنجليزي Roger Bacon هذا اللي... اللي 
+
+151
+00:16:07,150 --> 00:16:10,430
+عاش بين ألف و متين وأربعة عشر لألف و متين وأربعة 
+
+152
+00:16:10,430 --> 00:16:15,430
+وتسعين يعني في منتصف هذا القرن يعني... وعلى لسان 
+
+153
+00:16:15,430 --> 00:16:21,230
+هذا الفيلسوف ظهرت فكرة ال... هذا المصطلح اللي هو 
+
+154
+00:16:21,230 --> 00:16:28,710
+الموت الميسر والذي كان يعني ينادي بأن يعمل الأطباء 
+
+155
+00:16:28,710 --> 00:16:36,490
+على مداواة المرضى لكن إذا يأسوا من تطبيبه يهيئوا 
+
+156
+00:16:36,490 --> 00:16:41,110
+... هاي فلسفته... هاي توجيهته وإرشاده يهيئوا له 
+
+157
+00:16:41,110 --> 00:16:48,350
+موتا مريحا وهادئا وليس متسببا للألم عالجوا أنتو 
+
+158
+00:16:48,350 --> 00:16:54,110
+لكن ما قدرتو تعالجوا خلاص رايحوه بأي... بأي شكل، 
+
+159
+00:16:54,110 --> 00:16:59,890
+بإفرا، بدواء، بنزع... منع العلاج عنه، بحيث خلصوه 
+
+160
+00:16:59,890 --> 00:17:06,430
+من هال... وربما اعتقدوا أن ذلك فيه مصلحة وفيه راحة 
+
+161
+00:17:06,430 --> 00:17:15,590
+وفيه يعني ما فيه من تحقيق ل... لطلب المريض أو طلب 
+
+162
+00:17:15,590 --> 00:17:26,530
+المجتمع و... بعد ذلك يعني في قرون لاحقة بدأت تتفاعل 
+
+163
+00:17:26,530 --> 00:17:33,030
+هذه المطالب أو هذه القضية ل... وأصبح هناك من 
+
+164
+00:17:33,030 --> 00:17:39,510
+ينادي بإباحة قتل الرحمة وعن طريق منظم يعني عن 
+
+165
+00:17:39,510 --> 00:17:46,010
+طريق جمعيات جمعيات تنادي بتسهيل أو بتقنين أو 
+
+166
+00:17:46,010 --> 00:17:51,750
+بشرعنة قتل الرحمة لأن الأصل... الأصل أن القتل 
+
+167
+00:17:51,750 --> 00:17:58,920
+ممنوع الأصل أن القتل ممنوع يعني حتى بالنسبة لقتل 
+
+168
+00:17:58,920 --> 00:18:03,620
+الإنسان نفسه في كل الشرائع وكذلك قتل الإنسان 
+
+169
+00:18:03,620 --> 00:18:10,940
+لغيره من باب أولى ممنوع الآن في ظل مثل هذه الحالات 
+
+170
+00:18:10,940 --> 00:18:15,500
+بدأت مثل هذه الجمعيات تطالب بشرعنة القتل قتل الرحمة 
+
+171
+00:18:15,500 --> 00:18:22,210
+يعني شرعنته للأطباء شرعنة للحاكم شرعنة لذوي المريض 
+
+172
+00:18:22,210 --> 00:18:27,190
+وشرعنة للمريض نفسه أيضاً بأن يطلب الطبيب بذلك 
+
+173
+00:18:27,190 --> 00:18:33,990
+
+201
+00:21:27,430 --> 00:21:36,730
+أعوام دعني أقول ليست بالبعيدة يعني 1970 ظهرت حركات
+
+202
+00:21:36,730 --> 00:21:44,310
+ناشطة للمناداة أيضا بالسماح بقتل الرحمة نتج عنها 
+
+203
+00:21:44,310 --> 00:21:50,390
+أن بعض الولايات في أمريكا 
+
+204
+00:21:50,390 --> 00:21:54,630
+شرعنت شرعنت
+
+205
+00:21:57,030 --> 00:22:03,830
+الحق في أن يقتل الإنسان نفسه بهذه الطريقة أو تلك 
+
+206
+00:22:03,830 --> 00:22:07,390
+أو شرعنة قتل الرحمة باختصار لأنه أن يقتل نفسه أو 
+
+207
+00:22:07,390 --> 00:22:11,610
+أن يقتله غيره بناء على طلبه أو طلب ذوي شرعنة قتل 
+
+208
+00:22:11,610 --> 00:22:18,590
+الرحمة عموما و يمكن هذه كانت من أوائل الحالات اللي 
+
+209
+00:22:18,590 --> 00:22:27,380
+بتنفيها شرعنة أو تقنين قتل الرحمة لأن يا أخوات رغم 
+
+210
+00:22:27,380 --> 00:22:33,180
+كثرة من كان ينادي ووجود 
+
+211
+00:22:33,180 --> 00:22:41,640
+بعض الجمعيات ولكن لم نرى تشريعا في دولة من الدول 
+
+212
+00:22:41,640 --> 00:22:48,830
+يسمح بقتل الرحمة رغم وجود هنا و هناك بعض الجمهيات
+
+213
+00:22:48,830 --> 00:22:54,130
+وبعض الأصوات وبعض في أزمان مختلفة وفي أماكن مختلفة
+
+214
+00:22:54,130 --> 00:22:59,430
+لكن لم نجد دولة تتبنى غاية ما في الأرض وجدنا مثل 
+
+215
+00:22:59,430 --> 00:23:03,330
+هذه الولاية في أمريكا ومعروف أن في أمريكا فيها 
+
+216
+00:23:03,330 --> 00:23:06,710
+خمسين أو واحد وخمسين ولاية كل ولاية لها لها 
+
+217
+00:23:06,710 --> 00:23:10,370
+قانونها الخاص الداخلي في طبعا قانون للسياسات 
+
+218
+00:23:10,370 --> 00:23:15,090
+العامة للدولة كلها لكن كل ولاية لقانونها الخاص
+
+219
+00:23:15,090 --> 00:23:18,530
+فيما يتعلق بشغل الداخلية الطبية والأحوال الشخصية 
+
+220
+00:23:18,530 --> 00:23:22,110
+والمعاملاتية وإلى غير ذلك في هذه الولاية ولاية 
+
+221
+00:23:22,110 --> 00:23:27,380
+California يعني في فترة من الفترات أقرت هذا الحق
+
+222
+00:23:27,380 --> 00:23:31,580
+يعني داني أقول بناء على أنه مدان في حق للإنسان في 
+
+223
+00:23:31,580 --> 00:23:39,730
+الحياة فمن حقه أن يضع حد لهذا .. لهذه الحياة لكن في 
+
+224
+00:23:39,730 --> 00:23:47,130
+المقابل ونحن ورا كل هذه الأصوات يعني دعني أقول بن 
+
+225
+00:23:47,130 --> 00:23:50,670
+جوسين النشاذ التي بتنادي بذلك وجدنا أصوات أخرى 
+
+226
+00:23:50,670 --> 00:23:53,510
+حتى في المجتمع الغربي لازم نحن لا نتكلم هنا عن
+
+227
+00:23:53,510 --> 00:23:57,290
+المجتمع الإسلامي وإنما المجتمع الغربي وجدنا أصوات
+
+228
+00:23:57,290 --> 00:24:07,210
+تنادي بتجريم وتحريم يعني إيه قتل الرحمة واعتبار من 
+
+229
+00:24:07,210 --> 00:24:13,570
+يقوم الطبيب الذي يقوم بذلك مجرما ويحاكم على فعلته 
+
+230
+00:24:13,570 --> 00:24:17,070
+حقيقة 
+
+231
+00:24:17,070 --> 00:24:24,150
+يا أخوات أنه يعني رغم أن هذه الفكرة كما قلت نشأت
+
+232
+00:24:24,150 --> 00:24:29,030
+في الغرب وأن البيئة التي نشأت فيها بيئة مادية صرفة 
+
+233
+00:24:31,240 --> 00:24:39,640
+تهتم بالمصلحة الخاصة لا تهتم بالقيم لا تهتم 
+
+234
+00:24:39,640 --> 00:24:46,580
+بالإيمانيات فوجدت يعني بيئة خاصة ورغم كل ذلك ورغم 
+
+235
+00:24:46,580 --> 00:24:51,800
+كل ذلك لم تجرؤ دولة من هذه الدول على التشريع مثل
+
+236
+00:24:51,800 --> 00:24:56,460
+هذا القانون لأنه في الحقيقة مخالف ومنافي للفطرة
+
+237
+00:24:56,460 --> 00:25:00,640
+الإنسانية التي فطر عليها الإنسان فالإنسان بطبيعته 
+
+238
+00:25:00,640 --> 00:25:10,560
+يحب الحياة والإنسان بطبيعته يتحمل ما يصيبه من آلام 
+
+239
+00:25:10,560 --> 00:25:16,870
+وأمراض وإلى غير ذلك إلى أبعد حد رجاءً أن يعني يشفع
+
+240
+00:25:16,870 --> 00:25:23,630
+في .. و .. فطبيعة الإنسان و كذلك حتى ذوي الإنسان 
+
+241
+00:25:23,630 --> 00:25:28,950
+أهله وأمه في العام الأغلب مسلمين وغير مسلمين يعني 
+
+242
+00:25:28,950 --> 00:25:33,690
+هم من الشفقة بمكان أن يتحملوا ابنهم أو أباهم أو
+
+243
+00:25:33,690 --> 00:25:38,370
+أمهم في الأعوام الأغلب في حالات صحية بتصير ويتحملون 
+
+244
+00:25:38,370 --> 00:25:43,250
+ذلك ولا يقبلون بحال من الأحوال أن يفرضوا فيه أو أن 
+
+245
+00:25:43,250 --> 00:25:49,810
+يطالبوا بقتله بغض النظر أدبا قيما دينا شرعا أو عن 
+
+246
+00:25:49,810 --> 00:25:54,440
+قناعة هذا .. هذا .. هذا .. مما فُطِر عليه الإنسان
+
+247
+00:25:54,440 --> 00:25:58,600
+ومما تعرفت عليه الإنسانية منذ وجودها إلى أن أرف 
+
+248
+00:25:58,600 --> 00:26:04,060
+الله الأرض ومن عليها ولذلك لم نجد وطبعا طبيعي يا 
+
+249
+00:26:04,060 --> 00:26:12,260
+أخوات أنه .. أنه يكون الموقف الشرعي لقتل 
+
+250
+00:26:12,260 --> 00:26:17,460
+الرحمة هو تحريم مطلق وبلا تردد وبلا اختلاف
+
+251
+00:26:17,460 --> 00:26:22,820
+باتفاق يبقى السؤال يعني إذا كان الأمر كذلك فما .. 
+
+252
+00:26:22,820 --> 00:26:25,620
+يعني إذا كان قتل الرحمة محرم ليش احنا يعني
+
+253
+00:26:25,620 --> 00:26:29,300
+أثرنا في مثل هذه القضية على أتبار خاصة إنه احنا 
+
+254
+00:26:29,300 --> 00:26:33,440
+نتكلم عن قضايا لغالب مختلفة فيها وفيها حقيقة يا 
+
+255
+00:26:33,440 --> 00:26:39,680
+أخوات الحديث هنا عن الموقف الشرعي من قتل الرحمة
+
+256
+00:26:39,680 --> 00:26:45,400
+وحكم قتل الرحمة بناء على ما ذكر من قبل المؤيدين
+
+257
+00:26:45,400 --> 00:26:50,300
+ لقتل الرحمة من بعض الشبهة التي قد تنطلي على بعض
+
+258
+00:26:50,300 --> 00:26:55,600
+الناس وبعض المسلمين فيقتنعوا بها مع أنها مجرد شبه 
+
+259
+00:26:55,600 --> 00:27:02,120
+ولا أساس لها من الصحة أو من صحة الاستدلال بها فكان 
+
+260
+00:27:02,120 --> 00:27:08,760
+لابد من الرد على هذه الشبه من خلال بيان الموقف
+
+261
+00:27:08,760 --> 00:27:15,660
+الإسلامي والموقف الشرعي والأدلة التي تحرم ذلك
+
+262
+00:27:15,660 --> 00:27:20,670
+موقف الإسلام من الإنسان وتكريمه لهذا الإنسان ومن 
+
+263
+00:27:20,670 --> 00:27:26,090
+حياة الإنسان وإلى غير ذلك والأدلة على كل ذلك و
+
+264
+00:27:26,090 --> 00:27:30,310
+أعود مرة أخرى لأقول إن من أهم الشبهة التي اعتمد 
+
+265
+00:27:30,310 --> 00:27:34,930
+عليها المؤيدون وعندما أقول المؤيدون لأقصد مؤيدين
+
+266
+00:27:34,930 --> 00:27:40,430
+من المسلمين أبدا المؤيدون من الغرب ما يجييش يقول لوحد
+
+267
+00:27:40,430 --> 00:27:43,730
+إنه بقى المسألة خلافية في مؤيد وفي مخالف بدليل أنه 
+
+268
+00:27:43,730 --> 00:27:48,290
+هي فيه مؤيدين وفيها يوملهم أدلة أو شبه لأ هدول
+
+269
+00:27:48,290 --> 00:27:52,650
+المؤيدين المؤيدون من غير المسلمين وإنما نذكروا ما 
+
+270
+00:27:52,650 --> 00:27:59,590
+قالوا فقط لنزيل الشبهة التي قد تنطلي وقد يعني 
+
+271
+00:27:59,590 --> 00:28:04,510
+يقتنع بها البعض من السذج أو في حالات نفسية معينة
+
+272
+00:28:04,510 --> 00:28:09,500
+أو إلى .. إلى .. إلى .. إلى غير ذلك يعني أنا أذكره
+
+273
+00:28:09,500 --> 00:28:16,200
+باختصار هنا لأن هي فعلا شبه واهية إلى حد كبير يعني
+
+274
+00:28:16,200 --> 00:28:23,420
+هم قالوا أن هذا فيه يعني تأييدهم مبني أو منطلقه أن 
+
+275
+00:28:23,420 --> 00:28:29,560
+هذا فيه مصطحى للمريض المريض هذا يعيش حياته كلها
+
+276
+00:28:29,560 --> 00:28:38,770
+ألم وكلها معاناة و .. فإذا .. وإيقاف حياته وقتله
+
+277
+00:28:38,770 --> 00:28:44,210
+وإماتته يمنع هذه ال .. ال .. يمنع هذا الألم 
+
+278
+00:28:44,210 --> 00:28:50,710
+ويوقفهم ففيه مصطحى وبالتالي يعني من هذه الزاوية 
+
+279
+00:28:50,710 --> 00:28:54,750
+فليه ما لنوقفهم يعني إذا كان فيه مصطحى للشخص نفسه
+
+280
+00:28:54,750 --> 00:28:58,810
+من أحسن يظل يعاني وليس لنا .. احنا مش لاجين الومرة
+
+281
+00:28:58,810 --> 00:29:03,450
+يعني الدواء ولا لاجهينه العلاج ولا عارفينه العلاج
+
+282
+00:29:03,450 --> 00:29:10,270
+يظلوا يعاني ومنهم من يبقى سنوات يعاني يعني قد تجد 
+
+283
+00:29:10,270 --> 00:29:17,050
+لها شكل من أشكال المنطقية والله معقول قد يقال ومن 
+
+284
+00:29:17,050 --> 00:29:24,090
+هنا نحن انتقلنا إلى هذه الشبهة أثناء وسنعود إلى
+
+285
+00:29:24,090 --> 00:29:28,490
+تفنيد هذه الشبهة مصلحة
+
+286
+00:29:28,490 --> 00:29:36,550
+لذوي المريض هو لو عجده كمان بسيطة لكن هو شاغل معاه
+
+287
+00:29:36,550 --> 00:29:46,030
+أهل .. أهل شاغلهم جهدا ووقتا ومالا وإرهاقا معنويا 
+
+288
+00:29:46,030 --> 00:29:51,250
+أيضا وربما احنا حقيقة أيضا هذا له يعني أيضا موجود
+
+289
+00:29:51,250 --> 00:29:54,790
+مش .. مش موجود يعني أنا .. ليش احنا بنقول شبه يعني
+
+290
+00:29:54,790 --> 00:29:58,560
+كان لابد من تفنيدها لأنها لها وجود في الواقع ولذلك
+
+291
+00:29:58,560 --> 00:30:02,040
+احنا حتى لما بيموت واحد اختيار أو واحد مريض مرض ..
+
+292
+00:30:02,040 --> 00:30:07,240
+مرض مزمن وفيه مشكلة اه واستمر سنوات بنقول والله 
+
+293
+00:30:07,240 --> 00:30:12,060
+ارتاح وريح .. ريح اللي حواليه يعني شعور .. بتصير
+
+294
+00:30:12,060 --> 00:30:16,900
+فيه شعورين شعور بالحزن فراقي وشعور يعني بالسرور أو
+
+295
+00:30:16,900 --> 00:30:23,170
+بالرضا لراحة منه ربما يُقال و الله أنه 
+
+296
+00:30:23,170 --> 00:30:26,030
+هذا يعني احنا .. احنا ليش ظللنا مخبيين هذا في
+
+297
+00:30:26,030 --> 00:30:29,750
+قرارة أنفسنا؟ خلينا نكون صريحين مع أنفسنا احنا 
+
+298
+00:30:29,750 --> 00:30:35,890
+مزهوجين منه احنا مش متحملينه بس قدام الناس يعني
+
+299
+00:30:35,890 --> 00:30:42,090
+.. ب .. ب .. ب .. أو بناء على يعني الظاهر فلأ فيه
+
+300
+00:30:42,090 --> 00:30:49,750
+مصطحى لأهل المريض الذين أرهقتهم حالة هذا الشخص بكل
+
+301
+00:30:49,750 --> 00:30:55,710
+وسيلة من الوسائل ماديا ومعنويا وإلى غير ذلك قد 
+
+302
+00:30:55,710 --> 00:31:04,110
+يقال أيضا فيه يعني مصطحى للطبيب والأطباء اللي شغلهم
+
+303
+00:31:04,110 --> 00:31:10,830
+وممكن لو هذا الجهد اللي سخر له وسخر لغيره لكان 
+
+304
+00:31:10,830 --> 00:31:18,590
+أكثر فائدة فيه مصلحة للمجتمع للمجتمع لأنه برضه هذه
+
+305
+00:31:18,590 --> 00:31:23,150
+النفقات وهذه الأوقات وهذه الجهود التي تبذل واختصب
+
+306
+00:31:23,150 --> 00:31:29,830
+هذا المريض الميقوس منه لأن تبذل في ما فيه مصلحة
+
+307
+00:31:29,830 --> 00:31:34,740
+للأحياء أفضل للمجتمع أنا بدل ما أُتعب واحد بده يظلم
+
+308
+00:31:34,740 --> 00:31:39,500
+دوما لو أشتغل وأصبح إنسان منتجا هذا الإنسان اللي
+
+309
+00:31:39,500 --> 00:31:45,700
+موقوف على الرجل المريض بده واحد دايمًا شغال عليه
+
+310
+00:31:45,700 --> 00:31:52,760
+على طول يعني فيها طبعا ولما يكون في أعداد كثيرة 
+
+311
+00:31:52,760 --> 00:31:56,960
+جدا من هذه الحالات قد يكون سببا في إعاقة التنمية
+
+312
+00:31:56,960 --> 00:32:02,700
+الاقتصادية للمجتمع إذن هي يعني دعني أقول شبه كثيرة
+
+313
+00:32:02,700 --> 00:32:06,940
+في ثوب المصلحة للفرد، للمريض، لذوي المريض، 
+
+314
+00:32:06,940 --> 00:32:12,320
+للمجتمع، للمستشفى والأطباء، لكن حقيقة أن هذا كله
+
+315
+00:32:12,320 --> 00:32:15,480
+رغم كل هذه الشبكة فإن هذه الشبكة كلها مرفوضة 
+
+316
+00:32:15,480 --> 00:32:24,660
+ومردودة مرفوضة ومردودة يعني أنا سأقول بعموم في الرد 
+
+317
+00:32:24,660 --> 00:32:28,900
+على هذه الشبهة ذلك أن الإنسان خاصة الإنسان المؤمن
+
+318
+00:32:28,900 --> 00:32:32,580
+احنا نتكلم مردودة في نظر المسلمين يعني قد تكون
+
+319
+00:32:32,580 --> 00:32:37,340
+مردودة عندهم أو عند البعض منهم مش عند الكل وبدليل 
+
+320
+00:32:37,340 --> 00:32:42,200
+وجود الجمعيات التي تنادي بذلك لكن عندنا نحن أصحاب 
+
+321
+00:32:42,200 --> 00:32:45,560
+دين وأصحاب قيم وأخلاق نؤمن بالله وباليوم الآخر
+
+322
+00:32:45,920 --> 00:32:54,580
+يعني نعرف للإنسان حقه ونعرف حرمته وكرامته وإلى 
+
+323
+00:32:54,580 --> 00:33:00,520
+غير ذلك فإن هذا والمصلحة لحظوا يا إخوان لحظوا 
+
+324
+00:33:00,520 --> 00:33:04,860
+كل الشبه اللي شوفناها مبدأ المصلحة مبني فيها على 
+
+325
+00:33:04,860 --> 00:33:13,000
+المصلحة المادية البحتة المصلحة المادية البحتة بينما 
+
+326
+00:33:13,000 --> 00:33:19,380
+نحن كمؤمنين وإن كنا نهتم بالجانب المادي لكن لا
+
+327
+00:33:19,380 --> 00:33:23,900
+ننسى الجانب المعنوي والجانب القيامي والأخلاقي أين 
+
+328
+00:33:23,900 --> 00:33:28,300
+الجانب الأخلاقي؟ هنا كل القضايا التي ذكرتها قضايا
+
+329
+00:33:28,300 --> 00:33:35,720
+آلام آلام يا أقول لو أن هذا المريض وجد منواسيه
+
+330
+00:33:36,590 --> 00:33:42,270
+والله اللي خف عليه المرض والألم الألم نفسه هذا
+
+331
+00:33:42,270 --> 00:33:51,150
+مهما كان بكلمة طيبة بالمواساة بالصبر بالاهتمام
+
+332
+00:33:51,150 --> 00:33:54,830
+أيضا
+
+333
+00:33:56,730 --> 00:34:01,810
+المسألة كمان مسألة مقياس يعني القياس كله بالنظرة
+
+334
+00:34:01,810 --> 00:34:08,970
+المادية يعني هذا مقياس خطأ طب احنا خلينا نقول في 
+
+335
+00:34:08,970 --> 00:34:14,310
+.. احنا 
+
+336
+00:34:14,310 --> 00:34:17,570
+عندنا عقيدة أن الأرزاق بيد الله سبحانه وتعالى
+
+337
+00:34:17,570 --> 00:34:23,030
+الأرزاق بيد الله سبحانه وتعالى وأنه .. والإنسان
+
+338
+00:34:23,030 --> 00:34:31,110
+حتى عندما يسخر وقته وجهده من أجل إنسان مريض سيجد 
+
+339
+00:34:31,110 --> 00:34:35,890
+البركة في رزقه وليس بالضرورة أن هذا يكون عاملًا من 
+
+340
+00:34:35,890 --> 00:34:41,370
+عوامل نقص الرزق أو تردي الجوانب الاقتصادية أو إلى
+
+341
+00:34:41,370 --> 00:34:49,670
+غير ذلك لا تقاس هكذا الأمور بحال من الأحوال بعدين
+
+342
+00:34:49,670 --> 00:34:50,730
+يعني
+
+343
+00:34:54,610 --> 00:35:00,410
+لماذا يقتل هذا .. لماذا يقتل مأثم في قتله حتى من 
+
+344
+00:35:00,410 --> 00:35:04,990
+الجانب المادي .. في الجانب المادي لماذا يقتل مأثم 
+
+345
+00:35:04,990 --> 00:35:13,450
+في قتله قتل أقول للإبداع في البحث عن الدواء يعني 
+
+346
+00:35:13,450 --> 00:35:20,350
+أنت في أي حالة ميقوس منها في نظرك لكن الأصل أنه 
+
+347
+00:35:20,350 --> 00:35:25,830
+ما جعل الله .. أن الله جعل لكل داء دواء ولكن عرفه 
+
+348
+00:35:25,830 --> 00:35:31,030
+من عرفه وجهله من جهله لتكون هذه الحالة حالة عندك 
+
+349
+00:35:31,030 --> 00:35:40,010
+لتعرف على دوائها إذا أنت قتلت الإبداع وقتلت البحث 
+
+350
+00:35:40,010 --> 00:35:47,050
+عن إمكانية 
+
+351
+00:35:47,050 --> 00:35:52,770
+وجود علاج بعد ذلك لحالات أخرى ولذلك اليوم الطب يا
+
+352
+00:35:52,770 --> 00:35:59,330
+أخوات ما وصل إلى ما وصل إليه إلا من خلال التجارب 
+
+353
+00:35:59,330 --> 00:36:02,590
+على الحالات التي ما يقص منها ولم ييأس الناس مر .. 
+
+354
+00:36:02,590 --> 00:36:05,750
+مر ب .. ب .. في المجتمعات التي .. التي على مر
+
+355
+00:36:05,750 --> 00:36:11,090
+التاريخ أمراض كان يظن في يوم من الأيام أنه لا .. 
+
+356
+00:36:11,090 --> 00:36:15,010
+لا مرضة لا .. لا شفاء منها مرض الطاعون ومرض السل 
+
+357
+00:36:15,010 --> 00:36:22,840
+الذي كان في زمن معين أمراض قاتلة وبعد الإصرار و
+
+358
+00:36:22,840 --> 00:36:26,620
+البحث والعزيمة من الأطباء وجدوا لها حتى السرطان
+
+359
+00:36:26,620 --> 00:36:31,160
+اليوم الذي بدأ يكتشف أنه مرض يعني وكثير من
+
+360
+00:36:31,160 --> 00:36:35,520
+حالات السرطان التي تكتشف مبكرا يتم شفاؤها مع أنه 
+
+361
+00:36:35,520 --> 00:36:38,960
+احنا نفسنا عايشنا في فترة قديمة أن السرطان لا 
+
+362
+00:36:38,960 --> 00:36:43,440
+شفاء له في أوائل أعمارنا نحن كان معروف أن الميلون
+
+363
+00:36:43,440 --> 00:36:47,400
+أيام مرض من مرض السرطان انتهى أيامه أو شهوره قليلة
+
+364
+00:36:47,400 --> 00:36:55,510
+ويموت لكن اليوم لأ فيه فهذا يعني فلذلك يعني حقيقة
+
+365
+00:36:55,510 --> 00:37:02,180
+هذه الشبه يعني كما قلت مردها نظرة مادية مقيتة بعيدي
+
+366
+00:37:02,180 --> 00:37:04,860
+عن القيم، بعيدي عن الأخلاق، بعيدي عن الصبر
+
+367
+00:37:04,860 --> 00:37:09,580
+والتحمل، بعيدي عن الرحمة يقال هذا .. هذا قتل
+
+368
+00:37:09,580 --> 00:37:13,460
+الرحمة هذا كل .. هذا منتزع .. منزوع الرحمة .. هذا
+
+369
+00:37:13,460 --> 00:37:19,260
+منزوع الرحمة أن تكون أنت .. أنت طالب بقتل أبيك أو
+
+370
+00:37:19,260 --> 00:37:26,400
+بقتل أمك لأنها مرضت مرضًا يعني عضالا أو بقتل ولدك
+
+371
+00:37:26,400 --> 00:37:35,040
+أو بقتل أخيك هذا بسبب م
+
+Please provide the Arabic/English lecture transcript that you would like me to review and correct for typos and grammatical errors. I will then provide the corrected transcript following your instructions. 
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/uoK4S21Jmsw_postprocess.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/uoK4S21Jmsw_postprocess.srt
new file mode 100644
index 0000000000000000000000000000000000000000..109f1fd014ca3e1a57d49b1f2270a5840f192d3c
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/uoK4S21Jmsw_postprocess.srt
@@ -0,0 +1,1912 @@
+1
+00:00:20,120 --> 00:00:24,940
+بسم الله الرحمن الرحيمالحمد لله والصلاة والسلام
+
+2
+00:00:24,940 --> 00:00:29,600
+على رسول الله وعلى آله وصحبه وسلم تسليما كثيرا
+
+3
+00:00:29,600 --> 00:00:34,520
+لازمنا أيها الأخوات نتحدث عن موضوع التبرع بالأعضاء
+
+4
+00:00:34,520 --> 00:00:37,880
+ومعرفة
+
+5
+00:00:37,880 --> 00:00:41,600
+آراء العلماء المعاصرين في هذه المسألة أو في هذه
+
+6
+00:00:41,600 --> 00:00:46,920
+القضية وكنا
+
+7
+00:00:46,920 --> 00:00:55,000
+في محاضرات سابقة قد تحدثنا عنأهم القواعد الأصولية
+
+8
+00:00:55,000 --> 00:01:00,440
+والفقهية العامة التي تتصل بهذه المسألة كما تحدثنا
+
+9
+00:01:00,440 --> 00:01:07,800
+عن الجذور الفقهية كذلك والأحاديث النبوية والآيات
+
+10
+00:01:07,800 --> 00:01:13,920
+القرانية ذات الصلة بالموضوع ثم
+
+11
+00:01:13,920 --> 00:01:17,160
+بدأنا
+
+12
+00:01:17,160 --> 00:01:23,450
+نتحدث عنأراء العلماء في هذه المسألة وقولها بأن
+
+13
+00:01:23,450 --> 00:01:29,390
+العلماء بعد أن استعرضوا أمامهم القواعد العامة
+
+14
+00:01:29,390 --> 00:01:34,370
+للشريعة الإسلامية وبعض النصوص الجزئية ذات الصلة
+
+15
+00:01:34,370 --> 00:01:40,770
+بالموضوعلم يتفقوا على رأي واختلفوا في هذه المسألة
+
+16
+00:01:40,770 --> 00:01:45,870
+على رأيين رئيسيين وربما يكون أكثر من رأيين وربما
+
+17
+00:01:45,870 --> 00:01:51,310
+يكون رأي بالتوقف لكن الرأيين الأساسيين هم فريق
+
+18
+00:01:51,310 --> 00:01:58,150
+يقول بالمنع وفريق يقول بالجوازو لكل من الفريقين
+
+19
+00:01:58,150 --> 00:02:03,090
+أدلة وحقيقة أو استدل كل من الفريقين ب .. بمجموعة
+
+20
+00:02:03,090 --> 00:02:13,850
+من الأدلة وجدة فيها ما يؤكده ويدعم موقفه وقد تقرأت
+
+21
+00:02:13,850 --> 00:02:18,770
+في المحاضرة السابقة للحديث عن أدلة القائلين بمنع
+
+22
+00:02:19,440 --> 00:02:26,740
+التبرع بحرمة التبرع بالأعضاء ومختصر الأدلة التي
+
+23
+00:02:26,740 --> 00:02:32,620
+استدلوا بها أن هذه الأعضاء ليست مملوكة لهذا
+
+24
+00:02:32,620 --> 00:02:40,710
+الإنسانليست مملوكة لهذا الإنسان حتى يتبرع بها وإذا
+
+25
+00:02:40,710 --> 00:02:44,770
+كانت ليست مملوكة فلا يجوز له ذلك بل إنها مملوكة
+
+26
+00:02:44,770 --> 00:02:51,830
+لرب العالمين خالق هذه الأعضاء وخالق هذا الإنسان ثم
+
+27
+00:02:51,830 --> 00:02:58,370
+إنهم قالوا إن في عملية التبرع هذه تعريض للنفس
+
+28
+00:02:58,370 --> 00:03:03,790
+الإنسانية للجسد البشري الإنساني للتمثيل أو للمثلم
+
+29
+00:03:04,040 --> 00:03:09,000
+مع ما فيه من إيلام ومن تعذيب لهذا الإنسان وكل ذلك
+
+30
+00:03:09,000 --> 00:03:13,680
+ممنوع محرم النصط عليه حديث رسول الله صلى الله عليه
+
+31
+00:03:13,680 --> 00:03:18,760
+وسلم اللذي كان يوصي بأصحابه حتى في الحروب ومع
+
+32
+00:03:18,760 --> 00:03:24,160
+أعداء اللهوأعداء المسلمين يوصل مسلمين بعدم التمثيل
+
+33
+00:03:24,160 --> 00:03:32,360
+بهم وذلك دليل على أن التبرع بالأعضاء لما فيه من
+
+34
+00:03:32,360 --> 00:03:39,340
+شيء من التمثيل والإيلام الذي يلحق بالمتبرع وكذلك
+
+35
+00:03:39,340 --> 00:03:47,350
+يعني فإنهم اعتبروا أن هذا يعني شكل من أشكالالقتل
+
+36
+00:03:47,350 --> 00:03:53,490
+النفس أو ما يُعرف بالانتحار ولكنه انتحار جزئي فإذا
+
+37
+00:03:53,490 --> 00:03:59,310
+كانت الشريعة الإسلامية قد حرمت الانتحار بشكل كلي
+
+38
+00:03:59,310 --> 00:04:05,850
+فكذلك يعني يحرموا لإطلاق و لإعتداء على أي جزء من
+
+39
+00:04:05,850 --> 00:04:13,330
+أجزاء هذا الإنسان الذي يحرموا لإعتداء عليه بالكلية
+
+40
+00:04:13,580 --> 00:04:21,360
+ثم إنهم أيضًا قالوا بأن يعني مسألة الاقترار خاصة
+
+41
+00:04:21,360 --> 00:04:27,740
+أنهم ربما يكونوا قد وجهوا بأن هذا حتى وإن قلنا
+
+42
+00:04:27,740 --> 00:04:35,140
+بمنعه فإن الضرورات تبيح المحظوراتونحن أيه القايلون
+
+43
+00:04:35,140 --> 00:04:38,860
+بالجواز إنما نبيح ذلك في حالة الضرورة فقالوا بأن
+
+44
+00:04:38,860 --> 00:04:44,400
+هذا الحكم مستثنى من حالة الضرورة مستثنى من حالة
+
+45
+00:04:44,400 --> 00:04:48,860
+الضرورة فإن الضرورات تبيح المحظورات في غير هذا
+
+46
+00:04:48,860 --> 00:04:54,380
+الموضع في غير أن يكون هناك تبرع بأعضاء جسم الإنسان
+
+47
+00:04:54,380 --> 00:05:01,420
+لغيرهمن البشر لأن هذا يتنافى مع مبدأ الكرامة
+
+48
+00:05:01,420 --> 00:05:08,640
+الإنسانية ومع مبدأ الشرف الذي ناله هذا الإنسان
+
+49
+00:05:08,640 --> 00:05:14,680
+وإلى غير ذلك وربما إضافة إلى كل ذلك ولعله الدليل
+
+50
+00:05:14,680 --> 00:05:18,940
+الأهم الذي استدلوا به والذي ربما لم نذكره المرة
+
+51
+00:05:18,940 --> 00:05:23,100
+الماضيةولم نذكره صاحب الكتاب بشكل مباشر هنا لكن
+
+52
+00:05:23,100 --> 00:05:32,020
+ربما في طيات الحديث وهو ما يترتب على هذه العملية
+
+53
+00:05:32,020 --> 00:05:41,560
+أو هذا العمل من مفاسد مفاسد كثيرة متمثلة فيما عرف
+
+54
+00:05:41,560 --> 00:05:49,060
+اليوم بالاتجار والبيع والشراء بالأعضاء البشريةوهذا
+
+55
+00:05:49,060 --> 00:05:54,560
+مع العلم أن مسألة البيع متفق عليها متفق على منعها
+
+56
+00:05:54,560 --> 00:05:59,880
+وعلى تحريمها فالحر الإنسان الحر لا يباع ولا يشترى
+
+57
+00:05:59,880 --> 00:06:04,880
+وكذلك أي جزء من أجزائه وفتح بوابة التبرع حتى وإن
+
+58
+00:06:04,880 --> 00:06:09,860
+كانت تبرعا قد يؤدي إلى فتح بوابة البيع وفتح بوابة
+
+59
+00:06:09,860 --> 00:06:15,620
+البيع قد يؤدي إلى مفاسد كبيرة تلحق بالبشر جميعالما
+
+60
+00:06:15,620 --> 00:06:21,860
+في ذلك ويترتب عليه مفاسد كبيرة ليس أقلها وجود تلك
+
+61
+00:06:21,860 --> 00:06:24,860
+العصابات المجرمة
+
+62
+00:06:27,410 --> 00:06:31,870
+من أعضائها بعض الأطباء الذين فقدوا أخلاقيات المهنة
+
+63
+00:06:31,870 --> 00:06:42,190
+الطبية وبدأوا يتعاطون مع هذا العمل لما يترتب
+
+64
+00:06:42,190 --> 00:06:48,350
+عليه من تحصيل أموال كثيرة في هذا الشأن وكثير من
+
+65
+00:06:48,350 --> 00:06:54,050
+البلدان الشرقية بلاد الهند والصين وحتى في مصر وبعض
+
+66
+00:06:54,050 --> 00:06:58,920
+البلدان العربية تعاني منأولئك اللي من تلك العصابات
+
+67
+00:06:58,920 --> 00:07:05,440
+التي تعمل على اتجار بعضاء البشر سواء من خلال
+
+68
+00:07:05,440 --> 00:07:12,000
+التفاوض معهم عند حاجتهم الماسة لفقرهم لحاجتهم
+
+69
+00:07:12,250 --> 00:07:18,810
+وإعطاء .. شراء هذه الأضاع منهم بثمن بخص وعدم إعطاء
+
+70
+00:07:18,810 --> 00:07:23,810
+العملية التي تقوم بها هذه الأصابات العملية
+
+71
+00:07:23,810 --> 00:07:28,510
+الجراحية التي تم الاستقصال والانتزاع فيها ما ينبغي
+
+72
+00:07:28,510 --> 00:07:35,510
+أن تُعطى من أهمية ومن احتياطات طبية وإلى غير ذلك
+
+73
+00:07:35,510 --> 00:07:39,690
+وربما يدعوهم الأمر عند الحاجة إلى خطف بعض الناس،
+
+74
+00:07:39,690 --> 00:07:44,580
+بعض الأفراد، بعض الأطفال، بعض ..ل .. ل .. و .. ل
+
+75
+00:07:44,580 --> 00:07:50,060
+.. من أجل سرقة أعضائهم بشكل أو .. أو بآخر و هذا
+
+76
+00:07:50,060 --> 00:07:56,100
+أصبح يعني أمرا و هاجسا خطيرا يؤرقوا كثيرا من الناس
+
+77
+00:07:56,100 --> 00:08:03,120
+و كثير من الدول و سببه يعني هذا الفتح هذه البوابة
+
+78
+00:08:03,120 --> 00:08:09,940
+فمن الباب السد الذريعةفيمكن أن يقول أن التبرع
+
+79
+00:08:09,940 --> 00:08:15,140
+بالأعضاء ممنوع ومحرم إذن هي مجموعة من الأدلة التي
+
+80
+00:08:15,140 --> 00:08:22,280
+استدل بها القائلون بالمنع تحدثنا فيها وهذا ختامها
+
+81
+00:08:22,280 --> 00:08:28,080
+ولننتقلبعد ذلك إلى الحديث عن وجهة النظر الأخرى
+
+82
+00:08:28,080 --> 00:08:33,540
+وجهة نظر من قالوا بجواز التبرع وفي الحقيقة أن
+
+83
+00:08:33,540 --> 00:08:37,540
+الذين يقولون بجواز التبرع يمثلون الفئة الأكثر
+
+84
+00:08:37,540 --> 00:08:44,120
+يمثلون الجماهير من العلماء ويمثلونأيضا مجامع الفقه
+
+85
+00:08:44,120 --> 00:08:53,200
+واندوات الفقهية ويمثلون الأغلبية العظمة من العلماء
+
+86
+00:08:53,200 --> 00:08:59,480
+المعاصرين معظمهم قالوا بجواز التبرأ بالأعضاء لكن
+
+87
+00:08:59,480 --> 00:09:03,880
+ومن باب الأمانة والموضوعية إنما قالوا بالجواز
+
+88
+00:09:03,880 --> 00:09:11,090
+بضوابط وشروط سنتحدث عنها لكن من حيث المبدأفإنهم
+
+89
+00:09:11,090 --> 00:09:17,430
+قالوا بالجواز رغم يعني ما استدلى به القائلون
+
+90
+00:09:17,430 --> 00:09:24,470
+بالمنع ورغم معرفتهم بهذه الأدلة واطلاعهم على هذه
+
+91
+00:09:24,470 --> 00:09:29,970
+الأدلة لكنهم مع ذلك قالوا أو ربما لم يقتنعوا
+
+92
+00:09:29,970 --> 00:09:38,130
+بأدلتهم ووجه الاستدالة بها وقالوا بأن التبرع
+
+93
+00:09:38,130 --> 00:09:46,780
+بالأعضاءمن حيث المبدأ فإنه جائز قالوا وإنما قالوا
+
+94
+00:09:46,780 --> 00:09:50,900
+بذلك لمجموعة من الأدلة قالوا بأن على رأس هذه
+
+95
+00:09:50,900 --> 00:09:57,340
+الأدلة أن هذا أي التبرع بالأعضاء هو شكل من أشكال
+
+96
+00:09:57,340 --> 00:10:02,320
+التداوي شكل من أشكال التطبيب شكل من أشكال الحفاظ
+
+97
+00:10:02,320 --> 00:10:07,260
+على الصحة العامة لإنسان وكم هو الإنسان
+
+98
+00:10:09,610 --> 00:10:16,570
+وكم الإنسان بطبيعته بحاجة إلى .. إلى .. إلى أن
+
+99
+00:10:16,570 --> 00:10:25,710
+يتعرف على .. أو بأن .. بأن يحرص على صحته وأن
+
+100
+00:10:25,710 --> 00:10:29,330
+يتداوى والإنسان بطبيعته أيها الأخوات إذا ما تعرض
+
+101
+00:10:29,330 --> 00:10:35,630
+لمرض فإنه يبحث عن كل وسيلة من الوسائلمن أجل أن
+
+102
+00:10:35,630 --> 00:10:39,010
+يتخلص من هذا المرض، من أجل أن يشفى من هذا المرض
+
+103
+00:10:39,010 --> 00:10:43,530
+وإن الشريعة جاءت وفق الفطر الإنسانية، الشريعة جاءت
+
+104
+00:10:43,530 --> 00:10:48,270
+حثة على التداوة، بربما آمرا أمرا واجبا الرسول صلى
+
+105
+00:10:48,270 --> 00:10:52,370
+الله عليه وسلم يقول تداووا عباد الله فإن الله جعل
+
+106
+00:10:52,370 --> 00:10:58,780
+لكل دائموالتطبيب والتداوي ليس له شكل معين التطبيب
+
+107
+00:10:58,780 --> 00:11:03,680
+والتداوي لا يكون بياخد حبة الحبوب أو القبر أو
+
+108
+00:11:03,680 --> 00:11:09,920
+العملية الجراحية وإنما بكل الأشكالوهذا شكل من
+
+109
+00:11:09,920 --> 00:11:15,620
+أشكال التطبيب نقل عضو من إنسان لإنسان آخر مريض
+
+110
+00:11:15,620 --> 00:11:20,520
+يحتاج إلى زراعة عضو هو شكل من أشكال التطبيب و
+
+111
+00:11:20,520 --> 00:11:25,640
+الحفاظ على صحة هذا الإنسان المريض ليبقى حيا ما شاء
+
+112
+00:11:25,640 --> 00:11:35,180
+الله له أن يبقى و تركه و ترك هذا المريض في حالة
+
+113
+00:11:35,180 --> 00:11:42,550
+يتعرض فيها للموتونحن مستطيع أن نمد له يد العون دون
+
+114
+00:11:42,550 --> 00:11:49,130
+أن يلحق بنا ضرر فين هذا نوع من نوع يعني القاء
+
+115
+00:11:49,130 --> 00:11:57,560
+النفس إلى التهلكة نوع من أنواعالقتل يعني أن نترك
+
+116
+00:11:57,560 --> 00:12:02,740
+إنسانا يموت ونحن قادرين على إنقاذه هو شكل من أشكال
+
+117
+00:12:02,740 --> 00:12:08,560
+الاعتداء كمن يرى إنسانا غريقا وهو يستطيع أن ينقذه
+
+118
+00:12:08,560 --> 00:12:16,440
+ويتركه يستطيع فإنه مع أن الذي يقدمه على الإنقاذ قد
+
+119
+00:12:16,440 --> 00:12:24,040
+يتعرض قد يتعرض للهلاك وقد يتعرض للمخاطر وكممن
+
+120
+00:12:24,040 --> 00:12:29,820
+الذين قاموا بإنقاذ أو بمحاولات إنقاذ لغرقه تعرضوا
+
+121
+00:12:29,820 --> 00:12:34,800
+هم للغرق وماتوا ومع ذلك لم نسمع أحدا من العلماء
+
+122
+00:12:34,800 --> 00:12:43,120
+يقولوا بأن هذا الفعل محرم وغير جائز في ترك هؤلاء
+
+123
+00:12:43,120 --> 00:12:51,080
+شيء من الاعتداء وشيء من المجافة لبدئيات الأخلاق
+
+124
+00:12:52,590 --> 00:12:57,750
+خاصة إذا كان هذا الأمر في مقدورنا ولو بشيء من
+
+125
+00:12:57,750 --> 00:13:02,450
+التضحية
+
+126
+00:13:02,450 --> 00:13:10,990
+ثم إضافة إلى هذا فإن في ذلك ما فيه من .. أو شكل من
+
+127
+00:13:10,990 --> 00:13:16,290
+أشكال تفريج القرابات وشكل من أشكال التعاون على
+
+128
+00:13:16,290 --> 00:13:22,720
+الخيرات وشكل من أشكال التراح بين الناسإذا كان يعني
+
+129
+00:13:22,720 --> 00:13:29,680
+إذا كان من يقدم لإنسان شيء من المال أو مساعدة يعني
+
+130
+00:13:29,680 --> 00:13:38,120
+مساعدة في حملة شيء يعتبر مفرجا للقربة فكيف بمن كان
+
+131
+00:13:38,120 --> 00:13:45,020
+مساعدته لشخص آخر بإنقاض حياته هذا أعظم وأرقى
+
+132
+00:13:49,370 --> 00:13:55,290
+وأعلى مستويات التفريج للقربات إنسان يواجه خطأ
+
+133
+00:13:55,290 --> 00:14:01,270
+الموت وانت تقدم له يد العون لتنقذه من الموت ليس ثم
+
+134
+00:14:01,270 --> 00:14:06,420
+بعد هذا التفريج ولذلكيعني الرسول صلى الله عليه
+
+135
+00:14:06,420 --> 00:14:12,800
+وسلم في الحديث الذي نعرفه منفرج على مسلم
+
+136
+00:14:12,800 --> 00:14:17,960
+قربة فاروج الله عمه قربة من قربي يوم القيامة وهذا
+
+137
+00:14:17,960 --> 00:14:23,780
+من باب الحث على التفريج وهذا من أرقى وأبهى وأسمى
+
+138
+00:14:23,780 --> 00:14:29,430
+صورالتفريج عن الكروبات ومن أبهر وأسمع أيضا صورة
+
+139
+00:14:29,430 --> 00:14:33,750
+تراهم ذلك أن المسلمين على وجه الخصوص ينبغي أن
+
+140
+00:14:33,750 --> 00:14:40,750
+يكونوا كما الجسد الواحد كما الأخوة متحابين يحبون
+
+141
+00:14:40,750 --> 00:14:44,050
+لأنفسهم ما يحبون لغيرهم او يحبون لغيرهم ما يحبون
+
+142
+00:14:44,050 --> 00:14:50,750
+لأنفسهم يعني إذا كان العلماء قد أجازوا أو في
+
+143
+00:14:50,750 --> 00:15:00,210
+مجموعهم وبإجماع أنأن ينقل الإنسان جزءًا من أعضائه
+
+144
+00:15:00,210 --> 00:15:06,810
+لنفسه، يعني بأخذ جلب مثلًا، رقع أو شريان القلب أو
+
+145
+00:15:06,810 --> 00:15:11,930
+إلى غير ذلك، هذا مما يكاد لا يكون فيه خلاف، على
+
+146
+00:15:11,930 --> 00:15:15,530
+اعتبار أنه في الجسد نفسه، طيب ما أبناء الأمة هم كم
+
+147
+00:15:15,530 --> 00:15:19,850
+الجسد الواحد؟أبناء الأمة هم كما الجسد الواحد وليس
+
+148
+00:15:19,850 --> 00:15:23,710
+لنا متى من فرق بين أن تنقل عضوا أو جزء من أعضاء
+
+149
+00:15:23,710 --> 00:15:30,050
+جسمك لنفسك أنت وبين أن تنقله لغيرك ذلك أن الإسلام
+
+150
+00:15:30,050 --> 00:15:35,430
+يسوي بينك وبينها بل إنه يحثك على أن تحب لأخيك كما
+
+151
+00:15:35,430 --> 00:15:40,310
+قلنا ما تحبه لنفسك وإذا كنت تقبل أن تنقل عضوا من
+
+152
+00:15:40,310 --> 00:15:46,460
+نفسك إلى نفسكوهذا بيجيزه العلماء فكذلك لما لا يكون
+
+153
+00:15:46,460 --> 00:15:52,840
+جائزا في أن تنقله من نفسك إلى غيرك
+
+154
+00:15:52,840 --> 00:15:58,100
+لأن المسلمين كما قلنا كم الجسد الواحد اللي اشتك
+
+155
+00:15:58,100 --> 00:16:04,390
+منه أضم اشتكت منه سائر الأعضاء بالصحة والحمدثم إنه
+
+156
+00:16:04,390 --> 00:16:08,950
+أيضًا شكل من أشكال التضحية بل أعظم أشكال التضحية
+
+157
+00:16:08,950 --> 00:16:14,750
+والإيثار الإيثار الذي حث عليه القرآن الكريم والذي
+
+158
+00:16:14,750 --> 00:16:20,400
+أشارت إليه السنة النبوية الكريمةوهذا الإيثار ليس
+
+159
+00:16:20,400 --> 00:16:25,760
+حتى إيثار بالمال أو إيثار بالجهد بل هو إيثار بعضه
+
+160
+00:16:25,760 --> 00:16:30,380
+بأغلى وأشمى وأكثر شيء خصوصية يعني لما ربنا قال
+
+161
+00:16:30,380 --> 00:16:35,020
+ويؤثرون على أنفسهم و لو كان بيهم خصاصة ليس ثمة من
+
+162
+00:16:35,020 --> 00:16:40,040
+اختصاص أكثر للإنسان أكتر من الأعضاء التي بين جنبيه
+
+163
+00:16:40,040 --> 00:16:47,350
+وجنبتيه يعني خصوصية و القرآن الكريم يشجعه علىعلى
+
+164
+00:16:47,350 --> 00:16:55,250
+ذلك خاصة إذا كان هذا الإيثار وهذا يعني لا يعود
+
+165
+00:16:55,250 --> 00:16:59,670
+بالضرر على الإنسان حتى في بعض الأحوال كان يمكن أن
+
+166
+00:16:59,670 --> 00:17:04,210
+يكون الإيثار يعود بالضرر وما ذلك فإن الشريعة
+
+167
+00:17:04,210 --> 00:17:10,480
+تباركه كلنا يعرف القصةأولئك النفر في معركة اليرموج
+
+168
+00:17:10,480 --> 00:17:15,900
+الذين كانوا يعني في حالة عطش شديد بعد أن جرحوا و
+
+169
+00:17:15,900 --> 00:17:22,080
+أصيبوا جميعا فعندما وصل الماء اليهم أخد كل واحد
+
+170
+00:17:22,080 --> 00:17:31,020
+يقدم الماء لأخيه مؤثرا به نفسهمؤثرا به نفسه ..
+
+171
+00:17:31,020 --> 00:17:36,420
+مؤثرا أخيه على نفسه مع أنه تعرض للهلاك أو يمكن أن
+
+172
+00:17:36,420 --> 00:17:41,100
+يتعرض للهلاك فكيف .. لكن احنا هنا لا نريد أن نقول
+
+173
+00:17:41,100 --> 00:17:47,320
+أو نشترط أن لا يكون المتبرأ غير متعرض للهلاك يعني
+
+174
+00:17:47,320 --> 00:18:00,320
+.. يعني ..فهذا أيضا دليل آخر على جواز مبدأ التبرع
+
+175
+00:18:00,320 --> 00:18:11,560
+بالأعضاء ثميعني أن الأحكام
+
+176
+00:18:11,560 --> 00:18:16,840
+الشرعية منطب المصالح الأحكام الشرعية خاصة عندما لا
+
+177
+00:18:16,840 --> 00:18:23,480
+يوجد هناك نص منطب المصالح وإذا
+
+178
+00:18:23,480 --> 00:18:33,190
+ما تبين وفق الاجتهاد العقلي الذي تكون مرجعيتهمصادر
+
+179
+00:18:33,190 --> 00:18:38,770
+التشريع ونصوصها العامة إذا كان قد توصل الإنسان
+
+180
+00:18:38,770 --> 00:18:46,110
+المجتهد إلى أن ثمة مصالح كبيرة تتحقق نتيجة هذا
+
+181
+00:18:46,110 --> 00:18:51,660
+العمل حتى لو وجدت بعض المفاسدلكن المفسد البسيطة
+
+182
+00:18:51,660 --> 00:19:00,700
+التي لا تنافس ولا يعني توازي هذه المصالح فإن هذا
+
+183
+00:19:00,700 --> 00:19:06,870
+الفعل يكون جائزافإنه في معظم الأحكام المتعلقة
+
+184
+00:19:06,870 --> 00:19:10,930
+بالمسائل ليس تمت من مصالح متمحضة مافيش حاجة اسمها
+
+185
+00:19:10,930 --> 00:19:15,990
+مصلحة في هذه الدنيا يعني خالصة مخلصة من أي مفسدة
+
+186
+00:19:15,990 --> 00:19:21,330
+ولا مفسدة خالصة مخلصة من أي مصدحة فإن المصالح
+
+187
+00:19:21,330 --> 00:19:25,590
+والمفسدة تتشابك وما من فعل نقوم به إلا وفيه
+
+188
+00:19:25,590 --> 00:19:31,130
+الأمرين معاولكن الحكم عليه برجحان المصالح عن
+
+189
+00:19:31,130 --> 00:19:35,310
+المفاسد أو المفاسد عن المصالح فكل ما رجحت المصالح
+
+190
+00:19:35,310 --> 00:19:40,510
+كان الفعل والعمل جائزاً والعكس بالعكس وهنا لو
+
+191
+00:19:40,510 --> 00:19:44,750
+نظرنا في هذه الفعل .. في هذا الفعل وفي هذا العمل
+
+192
+00:19:44,750 --> 00:19:50,250
+التبرع سنجد أن المصلحة متلقلقة والمصلحة واضحة
+
+193
+00:19:50,250 --> 00:19:58,590
+وراجحة أهوال ثمة من مصلحة أعظممن مصلحة متمثلة في
+
+194
+00:19:58,590 --> 00:20:04,430
+الحفاظ على روح الإنسان الحفاظ على النفس مقصد أول
+
+195
+00:20:04,430 --> 00:20:08,770
+من مقاصد التشريع وضرورة أولى من الضروريات الخمس
+
+196
+00:20:08,770 --> 00:20:14,070
+بعد الحفاظ على الدين بعد الحفاظ على الدين أليست
+
+197
+00:20:14,070 --> 00:20:20,600
+مصلحةوالله عز وجل يقول ومن أحياها فقد أحيا الناس
+
+198
+00:20:20,600 --> 00:20:28,580
+جميعا فكأنما أحيا الناس جميعا فهذا كله دليل على أن
+
+199
+00:20:28,580 --> 00:20:36,740
+الحفاظ على النفس هو من أعظم المصالح وهذا التبرع هو
+
+200
+00:20:36,740 --> 00:20:41,240
+مقصوده الأساسي الحفاظ على روح إنسان يتعرض للهلاك
+
+201
+00:20:41,240 --> 00:20:47,420
+الحفاظ على روح إنسان يتعرض للموتفكيف نقول بمنعه؟
+
+202
+00:20:47,420 --> 00:20:52,560
+بل على العكس تركه كذلك دون التبرؤ دون التبرأ هو
+
+203
+00:20:52,560 --> 00:20:57,380
+الذي يمكن أن يكون ممنوع ويمكن أن يكون حراما في حال
+
+204
+00:20:57,380 --> 00:21:01,060
+القدرة ومع ذلك نحن لا نقول بالحرمة ولا نجبر أحدا
+
+205
+00:21:01,060 --> 00:21:06,260
+لا نجبر أحدا على التبرؤ وينبغي أن يكون المتبرع
+
+206
+00:21:06,260 --> 00:21:13,740
+مختاراغير مكره ولا مجبر على ذلك لكن لا أقل من أن
+
+207
+00:21:13,740 --> 00:21:18,920
+نبيح هذا ونجهزه ولا نمنعه ولا نقول بحرمته مع ما
+
+208
+00:21:18,920 --> 00:21:23,440
+يحققه ثم نظره يعني إضافة إلى هذه المصطحة إضافة إلى
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+209
+00:21:23,440 --> 00:21:29,280
+هذه المصطحة وهي كبيرة حقيقة فإن يا أخوات الذي
+
+210
+00:21:29,280 --> 00:21:36,760
+يتعرض للموت وهو يعلم أن ثم تطريق ووسيلة يمكن أن
+
+211
+00:21:36,760 --> 00:21:42,590
+ينجو بهاوالناس قادرون على أن يقدموها له ويمتنعون
+
+212
+00:21:42,590 --> 00:21:48,630
+عن ذلك فإنه يفقد الأمل ويفقد الثقة بهذا المجتمع
+
+213
+00:21:48,630 --> 00:21:56,110
+وبهؤلاء البشر من حوله وعكسه بالعكس وعكسه بمعنى
+
+214
+00:21:56,110 --> 00:22:03,630
+وعندما يجد هذا الشخص الذي يتعرض للموت أن من حوله
+
+215
+00:22:04,430 --> 00:22:09,650
+يقدمون له كل وسيلة و لو كان بهم خصاصة من أجل
+
+216
+00:22:09,650 --> 00:22:15,890
+إنقاذه فإنه يعني تزداد ثقته بمجتمع و يصبح انسان
+
+217
+00:22:15,890 --> 00:22:22,800
+يعني محب من مجتمعه وهذا يتفرع عنهأن نبني مجتمعا
+
+218
+00:22:22,800 --> 00:22:31,440
+متحبا متراحما متقالفا متعاونا هذا وسيلة من وسائل
+
+219
+00:22:31,440 --> 00:22:40,580
+البناء مجتمع لكن لو ترك الأمرقد ينشئوا مجتمعا
+
+220
+00:22:40,580 --> 00:22:46,720
+مختلفا غير متآلف خاصة كما قلت عندما يعلم هذا الشخص
+
+221
+00:22:46,720 --> 00:22:55,280
+أن هناك مجال هناك قدرة هناك إمكانية لعلاجه و الناس
+
+222
+00:22:55,280 --> 00:23:03,640
+يمتنعون عن ذلك مرة أخرى تماما كما ضربت المثال
+
+223
+00:23:03,640 --> 00:23:08,950
+السابق وأضرب مثال آخركمن يجد .. كمن وقع في نار
+
+224
+00:23:08,950 --> 00:23:13,650
+تحرقه وهو ينظر إلى الناس ينظرون إليه وهم قادرون
+
+225
+00:23:13,650 --> 00:23:20,630
+على أن ينقذوه ربما مع شيء .. مع تحمل شيء من الضرر
+
+226
+00:23:20,630 --> 00:23:26,890
+بهم لكنه لا يجد فيهم أحد يريد أن يضحي ولو بحرق
+
+227
+00:23:26,890 --> 00:23:33,900
+شعيرات من شعير رأسهوهو يتعرض للهلاك و .. و .. و ..
+
+228
+00:23:33,900 --> 00:23:38,720
+و الموت كيف ستقوم نظرته أي مجتمع متحاب هذا على كل
+
+229
+00:23:38,720 --> 00:23:43,880
+الأحوال إذا الشاهد أن ثمة مصالح كبيرة متمثلة في
+
+230
+00:23:43,880 --> 00:23:49,020
+إنقاذ الحياة متمثلة في الثقة المزروعة التي تبدأ
+
+231
+00:23:49,020 --> 00:23:52,960
+تنبت و .. و .. و .. و .. و تثمر في .. بين أبناء
+
+232
+00:23:52,960 --> 00:23:57,020
+المجتمع تثمروا محبة و تثمروا تراحمة و تثمروا ثقة
+
+233
+00:23:57,020 --> 00:24:02,160
+بين أبناء هذاال .. ال .. ال .. المجتمع .. فضلوا
+
+234
+00:24:02,160 --> 00:24:06,740
+السيد الحين انت تقول ان بغض من يذهب ال .. ال ..
+
+235
+00:24:06,740 --> 00:24:10,500
+التبرع بالعضاء هم الذين ي .. ي .. يعني سيتوقعون
+
+236
+00:24:10,500 --> 00:24:14,700
+الموت او ي .. يعني مصيرهم الموت الذين يريدون ان
+
+237
+00:24:14,700 --> 00:24:18,740
+يتبرع لهم يتبرع .. يتبرع لهم نعم طب الحين احنا لو
+
+238
+00:24:18,740 --> 00:24:21,980
+بدنا نتبرع لواحد زيه اكيد هيكون اتبرع على متبرع
+
+239
+00:24:21,980 --> 00:24:25,200
+كبيرفانت لما بتقول ان شاء الله مش لما متحقق و انا
+
+240
+00:24:25,200 --> 00:24:29,460
+لسه بتضارب كبير على حسابي انا مهيأنا انسان ممكن في
+
+241
+00:24:29,460 --> 00:24:32,420
+الآخر انا اعوض من مراوطه مش متحقق ما هو احنا ..
+
+242
+00:24:32,420 --> 00:24:37,140
+احنا بنقول انه .. كلام جميل لكن احنا بنقول ان
+
+243
+00:24:37,140 --> 00:24:43,140
+الذين يقولون بجواز التبرع يضعونا شروطا من ضمن هذه
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+244
+00:24:43,140 --> 00:24:48,870
+الشروط الا يلحق ضرر ضيق هولا يمكن يا أخوات انكار
+
+245
+00:24:48,870 --> 00:24:52,750
+وجود ضرر كما قلت الذي يريد ان ينقذ غريقا قد يتعرض
+
+246
+00:24:52,750 --> 00:24:58,610
+للخطر والذي يريد ان ينقذ حريقا قد يتعرض للخطر وفيه
+
+247
+00:24:58,610 --> 00:25:02,170
+نوع من التضحية والذي يدخل جهادا في سبيل الله قد
+
+248
+00:25:02,170 --> 00:25:08,610
+يتعرض للخطر ومع ذلك كل ذلك جائز وفيه من الأجر
+
+249
+00:25:08,610 --> 00:25:16,560
+العظيم وهو من أعظم الإطاعات لله سبحانه وتعالىوهنا
+
+250
+00:25:16,560 --> 00:25:20,960
+أقول لا بأس لو كان هناك ضرر بسيط يمكن أن يتعايش
+
+251
+00:25:20,960 --> 00:25:25,400
+معه الإنسان لكن لو تبين وفق الفحوصات أو وفق
+
+252
+00:25:25,400 --> 00:25:31,180
+التشخيص من قبل الأطباء أن ثمة أن هذا لا يحتمل
+
+253
+00:25:31,180 --> 00:25:37,900
+بنيته لا تحتملإذا قُطع منهم عضو أو إذا تبرعه ربما
+
+254
+00:25:37,900 --> 00:25:41,900
+يؤدي إلى وفاته أو إلى خلل ولذلك الذين قالوا
+
+255
+00:25:41,900 --> 00:25:45,300
+بالتبرع كما سنرى في الشروط وضعوا مثل هذا الشرط ولم
+
+256
+00:25:45,300 --> 00:25:48,540
+يجيزوا التبرع بأي عضو حتى كمان إذا كان هذا العضو
+
+257
+00:25:48,540 --> 00:25:54,000
+الذي تريد أن تتبرع به قد يؤدي إلى هلاكة هل لا يجوز
+
+258
+00:25:54,000 --> 00:25:59,650
+أن يتبرع إنسان بقلبه مثلا؟إلى شخص آخر لأننا لا
+
+259
+00:25:59,650 --> 00:26:04,010
+نريد أن نحيا شخصا على حساب شخص آخر ولكن نريد أن
+
+260
+00:26:04,010 --> 00:26:08,330
+نحيا شخصا مع بقائح الحياة في شخص آخر ولو تعرضت
+
+261
+00:26:08,330 --> 00:26:15,690
+لقليل من الضرر لبأس في ذلك فإن يعني تحمل الضرر
+
+262
+00:26:15,690 --> 00:26:23,750
+الأخففي سبيل دفع الضرر الأكبر هذه قاعدة تحمل أخد
+
+263
+00:26:23,750 --> 00:26:29,430
+في الضررين هذا لا بأس في ذلك لكن والله أنا معاكي
+
+264
+00:26:29,430 --> 00:26:36,510
+إذا تثقن أو ترجح لنا أنه في حالة التبرع هذه سيعود
+
+265
+00:26:36,510 --> 00:26:40,270
+ضرر كبير قد يؤدي إلى الهلاك أو حتى إلى دون الهلاك
+
+266
+00:26:40,270 --> 00:26:46,160
+إلى خلل تبير في حياته لا نقبل ولا نجيز ذلكلكن
+
+267
+00:26:46,160 --> 00:26:50,240
+الحمد لله هذا المتبرع صحته تمام الكليتين تمام تمام
+
+268
+00:26:50,240 --> 00:26:54,120
+إذا اقتطعنا أو إذا استقصلنا كيلية تبقى الكيلية
+
+269
+00:26:54,120 --> 00:27:01,100
+الثانية تقوموا بالعمل على أحسن ما يكون فصحيح هو
+
+270
+00:27:01,100 --> 00:27:06,800
+سيعاني أياما ربما وكل هذا نقوله وفق نظرة وفق رؤية
+
+271
+00:27:06,800 --> 00:27:11,320
+من قالوا بالجواز لكن طبعا للقائلين بالمعنى كما
+
+272
+00:27:11,320 --> 00:27:17,840
+رأينا وجهة نظروجهة نظر أخرى، إذا يعني ثمة مصالح هم
+
+273
+00:27:17,840 --> 00:27:21,940
+يريدون أن يعني كما أن الذين يقولون بالمنع قالوا
+
+274
+00:27:21,940 --> 00:27:26,800
+هناك مفاسد هؤلاء يقولون هناك مصالح والمصالح هذه
+
+275
+00:27:26,800 --> 00:27:30,800
+راجحة على المفاسد والمفاسد التي تقولون يمكن
+
+276
+00:27:30,800 --> 00:27:36,000
+تقييدها ويمكن يعني منعها بشكل أو بأخر بأخر بعض
+
+277
+00:27:36,000 --> 00:27:40,880
+الاحتياطات وبوضع بعض الشروط وبوضع بعض الشروط ولذلك
+
+278
+00:27:40,880 --> 00:27:45,040
+يا أخوانيعني معظم المجامع الفقهية و معظم العلماء
+
+279
+00:27:45,040 --> 00:27:49,600
+المعاصرين هم على القول بالجواز والذين قالوا بالمنع
+
+280
+00:27:49,600 --> 00:27:56,660
+قالوا بالمنع بناء على الفاسد هذه التي وضع لها
+
+281
+00:27:56,660 --> 00:28:02,810
+القائلون بالجوازيعني موابق واحتياطات تمنع من
+
+282
+00:28:02,810 --> 00:28:07,790
+وقوعها ولذلك لم يبقى كبير فرق بين وجهتي النظر وكأن
+
+283
+00:28:07,790 --> 00:28:16,070
+بالقائلين بالمنع قالوا إذا مُنعت هذه المفاسد فإنهم
+
+284
+00:28:16,070 --> 00:28:23,160
+يقولون بالجواز خاصة الأخواتالكل متفق على أنه مبدأ
+
+285
+00:28:23,160 --> 00:28:27,340
+التبرع ببعض أنواع من الأعضاء، يعني الدم مثلا، لا
+
+286
+00:28:27,340 --> 00:28:32,920
+خلافة في ذلك الجلب في بعض المناطق على اعتبار أن
+
+287
+00:28:32,920 --> 00:28:35,920
+هذه أجزاء تتجدد
+
+288
+00:28:37,970 --> 00:28:43,610
+لكن بغض النظر إذا لم يعود
+
+289
+00:28:43,610 --> 00:28:48,730
+الإشكال في أنها مملوكة و غير مملوكة كما استدل
+
+290
+00:28:48,730 --> 00:28:51,890
+القائلون بالجواز إذا كان مملوكة و مش مملوكة، ما
+
+291
+00:28:51,890 --> 00:28:53,950
+لهاش علاقة بالتجدد و غير التجدد
+
+292
+00:28:56,370 --> 00:29:00,490
+يعني إذا أنا بدي .. ليه ما سكتم عن هذه و .. و .. و
+
+293
+00:29:00,490 --> 00:29:03,550
+.. و .. و .. و .. و .. و .. و .. و .. و .. و .. و
+
+294
+00:29:03,550 --> 00:29:04,310
+.. و .. و .. و .. و .. و .. و .. و .. و .. و .. و
+
+295
+00:29:04,310 --> 00:29:04,490
+.. و .. و .. و .. و .. و .. و .. و .. و .. و .. و
+
+296
+00:29:04,490 --> 00:29:04,670
+.. و .. و .. و .. و .. و .. و .. و .. و .. و .. و
+
+297
+00:29:04,670 --> 00:29:05,010
+.. و .. و .. و .. و .. و .. و .. و .. و .. و .. و
+
+298
+00:29:05,010 --> 00:29:08,810
+.. و .. و .. و .. و .. و .. و
+
+299
+00:29:08,810 --> 00:29:09,410
+.. و .. و .. و .. و .. و .. و .. و .. و .. و .. و
+
+300
+00:29:09,410 --> 00:29:17,410
+.. و .. و .. و .. و .. و
+
+301
+00:29:24,250 --> 00:29:28,270
+تماما كما نقول في المال، المال مال الله ولكن نحن
+
+302
+00:29:28,270 --> 00:29:32,650
+أعطينا الحق في التصرف في هذا المال وفق ما شرع الله
+
+303
+00:29:32,650 --> 00:29:39,970
+سبحانه وتعالى ونحن هنا أيضا نجيز ذلكليه القائلين
+
+304
+00:29:39,970 --> 00:29:45,770
+يجيزوا ذلك التبرع مع علمنا بأن هذا الجسد مملوك لله
+
+305
+00:29:45,770 --> 00:29:52,130
+سبحانه وتعالى لكن هناك تمت ولاية بشكل أو بآخر لهذا
+
+306
+00:29:52,130 --> 00:29:56,490
+الإنسان على نفسه من أولى الناس بنفسه بعد ربه
+
+307
+00:29:56,490 --> 00:30:01,330
+سبحانه وتعالى الإنسان هو لذلك اشترط من ضمن على رأس
+
+308
+00:30:01,330 --> 00:30:06,960
+الشروط أن يكون هذا الإنسان بالغا عاقلايعني لكي
+
+309
+00:30:06,960 --> 00:30:11,500
+تكون له الولاية على نفسه و يدرك مقالات الأمور و
+
+310
+00:30:11,500 --> 00:30:17,300
+يتحمل عشان ما يجعش بعضه في الندم و إلى غير ذلك على
+
+311
+00:30:17,300 --> 00:30:22,020
+كل الأحوالإذن هي مجموعة من الأدلة .. مجموعة من
+
+312
+00:30:22,020 --> 00:30:28,580
+الأدلة لكن أخرها كما قلت .. مسألة ال .. أن .. أن
+
+313
+00:30:28,580 --> 00:30:32,480
+هذا الفعل منوطن بالمصالح والمصالح واضحة والمصالح
+
+314
+00:30:32,480 --> 00:30:36,880
+حقيقة يا أخوات .. يعني أنا أكره ده .. هذا دائما ..
+
+315
+00:30:36,880 --> 00:30:42,120
+المصالح مرئية في الشريع الإسلامي .. معتبرةحتى يعني
+
+316
+00:30:42,120 --> 00:30:47,480
+.. و لو نظرنا إلى كل نص أو إلى كل حكم جاء به نص
+
+317
+00:30:47,480 --> 00:30:55,680
+سنجد أن المصلحة في الغالب مراعية مراعية في .. في
+
+318
+00:30:55,680 --> 00:31:01,980
+تشريع هذا الحكم أمرا أو ناهيا مافيش الأحكام حيثما
+
+319
+00:31:01,980 --> 00:31:11,150
+وجدت المصلحة فثم شر الله هكذا يقرر كل العلماءوقل
+
+320
+00:31:11,150 --> 00:31:18,290
+ما نجد حكما لا نعرف حكمته ولا نستبين مصطلحته ومع
+
+321
+00:31:18,290 --> 00:31:21,770
+ذلك فإن العلماء قالوا إن في الأحكام التي لا تظهر
+
+322
+00:31:21,770 --> 00:31:28,390
+فيها حكمة حكمة الحكمة هي متمثلة في الثقة في ذرع
+
+323
+00:31:28,390 --> 00:31:35,070
+ثقتك بربك وبالأحكام التي شرعها لك وإن لم تدرك
+
+324
+00:31:35,070 --> 00:31:40,520
+حكمتهالكن الأعام الأغلب في الأحكام التي شرعها لنا
+
+325
+00:31:40,520 --> 00:31:46,820
+ربنا سبحانه وتعالى أن حكمتها والمصطحة فيها تظهر
+
+326
+00:31:46,820 --> 00:31:53,500
+للإنسان بعقله وتظهر له في حياته العمليةتظهر له
+
+327
+00:31:53,500 --> 00:31:59,580
+بشكل .. وتتناسب و تتلاقم مع فطرته الإنسانية وفي
+
+328
+00:31:59,580 --> 00:32:03,060
+الأعام الأغلب والله لا تجري حكما شرائيا إلا
+
+329
+00:32:03,060 --> 00:32:08,960
+ويتناقم ويتناسق ويتناسب مع فطرة الإنسان وواقع
+
+330
+00:32:08,960 --> 00:32:14,080
+الإنسان ومصلحة الإنسان ومصلحة الإنسان هذه .. ومن
+
+331
+00:32:14,080 --> 00:32:20,550
+هنا .. ولذلك فإن المسائل التي تجدوالتي لم يرد فيها
+
+332
+00:32:20,550 --> 00:32:26,870
+نص إذا ما وجدنا المصلحة فيها واضحة وراجحة وغالبة
+
+333
+00:32:26,870 --> 00:32:34,210
+فمعنى ذلك أن الشريعة تشريعها
+
+334
+00:32:34,210 --> 00:32:40,420
+والشريعة تجيزها والشريعة تؤيدهاوإن وجدنا المفسدة
+
+335
+00:32:40,420 --> 00:32:45,700
+هي الراجعة فالشريعة تمنعها هكذا هو المقياس وهذا هو
+
+336
+00:32:45,700 --> 00:32:51,660
+الميزان وهذا هو الميزان ولذلك ورد عن كثير من
+
+337
+00:32:51,660 --> 00:32:55,900
+العلماء ومنهم شيخ العلماء وسلطان العلماء العزيزي
+
+338
+00:32:55,900 --> 00:33:01,520
+ابن عبد السلام انه في ذلك ربط كثير من المسائل
+
+339
+00:33:01,520 --> 00:33:11,060
+ربطها بالمصلحةو كمعيار للجواز و لعدمه عندما لا
+
+340
+00:33:11,060 --> 00:33:17,360
+يوجد نص أو عندما يعني يختلف الناس في مسألة فيها
+
+341
+00:33:17,360 --> 00:33:22,020
+جانب من المصالح و جانب من المفاسد كيف العمل برجحان
+
+342
+00:33:22,020 --> 00:33:27,360
+المفاسد يعني قال في كلام اللي هو أما إذا لا يمكن
+
+343
+00:33:27,360 --> 00:33:37,990
+إن لم يمكن تحصيل مصلحةإلا بإفساد بعض ال .. بعض ال
+
+344
+00:33:37,990 --> 00:33:43,070
+.. الإنسان يعني واحد يعني زي ما قلنا يعني أنا
+
+345
+00:33:43,070 --> 00:33:51,630
+إنسان أصيب أصيب ب .. ب .. في أصبعه أو في يده أو في
+
+346
+00:33:51,630 --> 00:33:54,990
+قدمه أو في أي عضم الأعضاء بما يُعرف اليوم
+
+347
+00:33:54,990 --> 00:34:02,890
+بالغرغرينة أو بخمج في يده طبالان قطع مضرر .. قطع
+
+348
+00:34:02,890 --> 00:34:10,910
+اليد هذه مفسدة لكن .. لكن هذه المفسدة .. هذه
+
+349
+00:34:10,910 --> 00:34:16,450
+المفسدةينتج عنها مصلحة أعظم بكثير والحفاظ على بقية
+
+350
+00:34:16,450 --> 00:34:22,970
+هذا الإنسان فلذلك أجازة الشريعة تقطع هذا الأصبع أو
+
+351
+00:34:22,970 --> 00:34:32,370
+هذه اليد التي إن لم تقطع ستسببه فناء أو إزهاقلهذه
+
+352
+00:34:32,370 --> 00:34:38,010
+الروح هذا الحكم بالجواز القاطع مبني على إيش؟ مبني
+
+353
+00:34:38,010 --> 00:34:42,850
+على الحفاظ على النفس مبني على مصلحة أعظم في موازنة
+
+354
+00:34:42,850 --> 00:34:49,230
+بين المصالح والمفاسد عندما تتشابك وعندما تتداخل
+
+355
+00:34:49,230 --> 00:34:56,590
+عندما تجيز الشريعة أكل الميتة وأكل المحرمات في
+
+356
+00:34:56,590 --> 00:35:01,490
+حالات الإضطرار أليس من باب المراعاة للمصالح؟لأن
+
+357
+00:35:01,490 --> 00:35:07,200
+ثمة مصطلحة أعظمفمن الضرر غير باغ و لا عادل يعني
+
+358
+00:35:07,200 --> 00:35:11,120
+الأصل أدم جواز ثنور النجاسات أدم جواز أكل الميت
+
+359
+00:35:11,120 --> 00:35:16,880
+لكن ذلك وبيح عندما يكون ذلك هناك مصلحة أعظم ألا
+
+360
+00:35:16,880 --> 00:35:21,600
+وهي مصلحت الحفاظ على هذه النفس ونحن في هذه المسألة
+
+361
+00:35:21,600 --> 00:35:26,020
+مسألتنا هذه إن مقصدنا الأساس هو الحفاظ على نفس
+
+362
+00:35:26,020 --> 00:35:31,300
+الحفاظ على نفس تتعرض للموت يمكننا أن نمد يد العون
+
+363
+00:35:31,300 --> 00:35:37,770
+لها وأنيعني ننقظها بشيء من المفسدة فيه يا سيدي فيه
+
+364
+00:35:37,770 --> 00:35:41,510
+مفسدة مش مافيش فيه ضرر مش مافيش لكن هذا الضرر لا
+
+365
+00:35:41,510 --> 00:35:47,190
+يقاس أمام هذه المصطحة العظيمة المتمثلة في الحفظ
+
+366
+00:35:47,190 --> 00:35:50,830
+على الروح على الروح على الجسد على النفس التي هي
+
+367
+00:35:50,830 --> 00:35:58,330
+بنيان الله في الأرض يعني نحن نحافظ عليها إذا كان
+
+368
+00:35:58,330 --> 00:36:05,610
+الميتوطبعا وانتهاك حرمته ممنوع لكن لو أن امرأة
+
+369
+00:36:05,610 --> 00:36:12,230
+حامل وماتت وكان فيه احتمال يعني انه هالولد لسه ضال
+
+370
+00:36:12,230 --> 00:36:17,570
+طيب في الشهر السابع ولا الثامن ولا التاسع طيب شق
+
+371
+00:36:17,570 --> 00:36:22,170
+البطن الميت او الاعتداء على الميت اه غير جائز لكن
+
+372
+00:36:22,170 --> 00:36:27,030
+في هذه الحالة اجاز العلماء شق بطن المرأة اذا كان
+
+373
+00:36:27,030 --> 00:36:35,410
+فيه املفي إنقاذ هذه الروح المقصد التداوي بالنجاسات
+
+374
+00:36:35,410 --> 00:36:41,530
+نفسهإنما أجازه من أجازه والمسألة خلافية من أجل
+
+375
+00:36:41,530 --> 00:36:45,270
+الحفاظ على .. هناك مقصد أعظم .. مقصد أعظم أيته
+
+376
+00:36:45,270 --> 00:36:49,810
+الأخوات قرّرة الحفاظ .. يعني قررت الشريعة في
+
+377
+00:36:49,810 --> 00:36:54,510
+قوادها العامة وفي نصوصها في مصادر .. وفي مصادرها
+
+378
+00:36:54,510 --> 00:37:00,290
+الجوازة ضرورة الحفاظ عليه وأباحة المحرمات أحيانا
+
+379
+00:37:00,290 --> 00:37:07,670
+من أجل الحفاظ عليهمن أجل الحفاظ عليه فهذا يعني حتى
+
+380
+00:37:07,670 --> 00:37:12,410
+لو قلنا بأن التبرع بالأعضاء من حيث المبدأ هو ممنوع
+
+381
+00:37:12,410 --> 00:37:17,250
+لأن الإنسان لا يملك و لأنه تمثيل و لأنه .. لكن
+
+382
+00:37:17,250 --> 00:37:22,980
+الضرورات تبه المحظورات يا جماعةلكن المصالح العليا
+
+383
+00:37:22,980 --> 00:37:29,500
+مقدمة المصالح الكبيرة مقدمة على المفاسد البسيطة في
+
+384
+00:37:29,500 --> 00:37:37,580
+هذه الحالة إنما لا نجرؤ على تنفيذ مصلحة معينة إذا
+
+385
+00:37:37,580 --> 00:37:41,300
+كانت المفسدة المقابلة لها مفسدة عظيمة توازيها أو
+
+386
+00:37:41,300 --> 00:37:45,220
+تزيد عنها هنا نتوقف إذا كان زي ما قالت الأخر إذا
+
+387
+00:37:45,220 --> 00:37:50,200
+كان في إنقاذ هذه الروح سيسبب هلاك روح أخرى نتوقف
+
+388
+00:37:50,780 --> 00:37:56,940
+نتوقف لأننا لا نريد أن ننقذ نفسا على حساب نفس أخرى
+
+389
+00:37:56,940 --> 00:38:03,760
+ولكن إن أمكننا إنقاذ نفس على حساب أو دون أن تتعرف
+
+390
+00:38:03,760 --> 00:38:09,180
+نفس أخرى لكن في مقتضحية بسيطة مفسدة بسيطة فهذا
+
+391
+00:38:09,180 --> 00:38:13,180
+يكون من باب الموازنات ومن باب ارتكاب أخف الضررين
+
+392
+00:38:13,180 --> 00:38:22,150
+يعني كما .. كما قلناعلى أي حال، هذه مجموعة من
+
+393
+00:38:22,150 --> 00:38:25,770
+الأدلة التي استدلت بها القاهلون بالجواز ثم إنهم
+
+394
+00:38:25,770 --> 00:38:32,990
+وفي سياق الاستدلال على ما قالوا من الجواز ردوا على
+
+395
+00:38:32,990 --> 00:38:40,090
+بعض أدلة المانعين المانعينالمانعين استدلوا بمجموعة
+
+396
+00:38:40,090 --> 00:38:49,950
+من الأدلة الملكية والتمثيل والتغيير لخلق الله وإنه
+
+397
+00:38:49,950 --> 00:38:54,690
+شرط من أشكال انتحار مجموعة وأنه يترطب عليه مفاسد
+
+398
+00:38:54,690 --> 00:38:58,990
+قالوا هذه الأدلة في الجملة مردودة عليهم مردودة
+
+399
+00:38:58,990 --> 00:39:03,670
+يعني مسألة بدءا من الملكية أن هذا ليس ملكك وملك
+
+400
+00:39:03,670 --> 00:39:08,170
+لله قالوا لا طب هاي المال مال اللهومع ذلك يجوزه
+
+401
+00:39:08,170 --> 00:39:13,530
+لنتصرف فيه وليس لأحد أن يمنع أحد أن يتبرأ أبو بكر
+
+402
+00:39:13,530 --> 00:39:20,070
+تبرع بكل ماله أليس بذلك ضررا عليه من جانب من زاوية
+
+403
+00:39:20,070 --> 00:39:25,970
+معينة وعلى أهله فيه ضرر لكن المصطحة الأعظم في
+
+404
+00:39:25,970 --> 00:39:30,510
+مساعدة الدعوة و الوقوف مع الدعوة و مع الدين في
+
+405
+00:39:30,510 --> 00:39:38,700
+بدايته هي التي أجازت لهوجعلت النبي صلى الله عليه
+
+406
+00:39:38,700 --> 00:39:45,120
+وسلم يقره على مثل هذا العمل وهكذا
+
+407
+00:39:45,120 --> 00:39:52,820
+يعنيفإذا كان ماله الله سبحانه وتعالى ويجوز لنا أن
+
+408
+00:39:52,820 --> 00:39:57,940
+نتصرف فيه فحتى لو نحن لا ننكر بأن هذا الجسد هو ملك
+
+409
+00:39:57,940 --> 00:40:04,760
+لله لكن للإنسان نوع ولاية وهو يتصرف في ذلك أيضا
+
+410
+00:40:04,760 --> 00:40:14,310
+وفق مقصود اللهووفق تشريعات الله في الجملة وليس
+
+411
+00:40:14,310 --> 00:40:20,350
+وفق ما يخالف أمر الله سبحانه وتعالى في مسألة
+
+412
+00:40:20,350 --> 00:40:27,420
+التمثيل قالوا هذا التمثيل تمثيل ماذا؟المثلة التي
+
+413
+00:40:27,420 --> 00:40:32,500
+نهى عنها رسولنا نحن نقر كأن بهم يقولون القائلون
+
+414
+00:40:32,500 --> 00:40:37,080
+بالجواز نحن نقر بأن المثلة حرمها لكن أي مثلة هذه
+
+415
+00:40:37,080 --> 00:40:41,960
+التي حرمها الشارع المثلة التي تكون يكون التمثيل
+
+416
+00:40:41,960 --> 00:40:47,530
+فيها مقصود لذاتهمقصود أنا بدي أمثل أنا بدي أقطع ..
+
+417
+00:40:47,530 --> 00:40:52,010
+بدي أقطع أنفه ولا بدي أقطع ذنه ولا بدي أفقع عينه
+
+418
+00:40:52,010 --> 00:40:56,330
+ولا بدي أبعط بطنه لذات .. لذات الشيء تشفيا
+
+419
+00:40:56,330 --> 00:41:01,650
+وانتقاما أثناء الحرب أو إلى غير ذلك هذه المثلة
+
+420
+00:41:01,650 --> 00:41:05,930
+التي نهى عنها رسول الله صلى الله عليه وسلم لكن إذا
+
+421
+00:41:05,930 --> 00:41:12,310
+أنا للرحمةبدي انا انجل عضو من شخص لشخص اخر و انا
+
+422
+00:41:12,310 --> 00:41:17,630
+اصلا بحف و بزف فيه من سرير لسرير و من دوة لدوة و
+
+423
+00:41:17,630 --> 00:41:25,850
+يعني بتعامل معاهكما لو كان ولادي او اخي او مش كانه
+
+424
+00:41:25,850 --> 00:41:31,230
+ولا بقصد التشفي وبعمل كل الاحتياطات من ايه يعني ثم
+
+425
+00:41:31,230 --> 00:41:35,610
+بقصد احياء نفس اخرى هذا ليس تمثيلا اساسا يعني ليس
+
+426
+00:41:35,610 --> 00:41:39,570
+تمثيلا وان سميناه تمثيلا فليس هو التمثيل المقصود
+
+427
+00:41:40,110 --> 00:41:44,870
+بالتحريق التمثيل المقصود بالتحريق هو ذلك الذي كان
+
+428
+00:41:44,870 --> 00:41:51,030
+يحدث في الجاهلية أو أحيانا في زمن المسلمين من قبل
+
+429
+00:41:51,030 --> 00:41:55,570
+البعض يعني للتشفي وهذا ليس من التمثيل بشيء أيضا
+
+430
+00:41:55,570 --> 00:42:01,430
+الأخوات وليس
+
+431
+00:42:01,430 --> 00:42:06,290
+وليس معنى ذلك أن نقول بالتمثيل بجواز التمثيل بجواز
+
+432
+00:42:06,290 --> 00:42:14,360
+المثلبل هذا شيء آخر ثم انظروا كيف أن هذه العملية
+
+433
+00:42:14,360 --> 00:42:20,940
+تتم تحت رعاية مؤسسات حكومية وأقدماء يعني ثقات هكذا
+
+434
+00:42:20,940 --> 00:42:24,440
+ينبغي أن تكون وهذا من الشروط بالمناسبة التي وضعها
+
+435
+00:42:24,440 --> 00:42:31,050
+القائلون بالجوازأن يتم تحت رعاية ناس طباء ثقات
+
+436
+00:42:31,050 --> 00:42:36,050
+ومؤسسات حكومية مش مؤسسات خاصة يمكن أن تكون يعني أن
+
+437
+00:42:36,050 --> 00:42:42,470
+تتلاعب بدماء الناس و بأعضائهم و بمصالحهم
+
+438
+00:42:44,010 --> 00:42:50,230
+فإذا مسألة التمثيل هذه أيضا مرفوضة أو مردود عليها
+
+439
+00:42:50,230 --> 00:42:54,090
+مسألة التغيير قالوا هذا فيه تغيير لخلق الله نظره
+
+440
+00:42:54,090 --> 00:42:58,370
+إلى الظاهر إلى الصورة لكن حقيقة أيضا حتى التغيير
+
+441
+00:42:58,370 --> 00:43:04,540
+الذي نهى عنه الشارعوذنبه .. ليس هذا .. ليس هو هذا
+
+442
+00:43:04,540 --> 00:43:08,960
+التغيير ذلك التغيير اللذي كان يتعلق بما كان يفعله
+
+443
+00:43:08,960 --> 00:43:14,680
+العرب في الجاهلية فيما يتعلق بتغيير بعض صور
+
+444
+00:43:14,680 --> 00:43:21,030
+الحيوانات أو بقطع آذانها أو جدع أنوفهابناء على
+
+445
+00:43:21,030 --> 00:43:26,710
+اتباع لوثأوس شيطانية يعتقدون من خلالها أنهم بفعل
+
+446
+00:43:26,710 --> 00:43:31,790
+هم هذا يحافظون على بقية القطيع أو تحتة البركة فهو
+
+447
+00:43:31,790 --> 00:43:39,210
+نوع من الشركيات ليس إلاوهذا .. أما هذا الذي يحدث
+
+448
+00:43:39,210 --> 00:43:43,810
+اليوم فليس له علاقة لا بوساوة الشيطان بل هو يعني
+
+449
+00:43:43,810 --> 00:43:52,330
+متعلق بمصالح الأنام وقواعد الأحكام
+
+450
+00:43:53,410 --> 00:43:58,170
+ومن ضمن أيضا ما الردود أو المناقشات التي حدثت يعني
+
+451
+00:43:58,170 --> 00:44:02,790
+قالوا بأن القائلون بالمنع قالوا أنتم تنقلوا حتى لو
+
+452
+00:44:02,790 --> 00:44:09,250
+كنا بمفد الجواز قالوا بأنكم تنقلون عضوا نجسا فإن
+
+453
+00:44:09,250 --> 00:44:14,750
+العضو إذا أبين من حيه فإنه يصبح ميتا والميت نجس
+
+454
+00:44:14,750 --> 00:44:23,520
+فهذا أيضا هذا الكلام أيضا مردود عليهم لأنلأن عضو
+
+455
+00:44:23,520 --> 00:44:29,020
+المنقول أو المبتور أو المقطوع من الأدم يختلف عن
+
+456
+00:44:29,020 --> 00:44:33,780
+العضو المقطوع من الحيوان الآخر العضو المقطوع من
+
+457
+00:44:33,780 --> 00:44:41,340
+الحيوان الحي يصبح ميتا نعم وبالتالي نجسا كأنه غير
+
+458
+00:44:41,340 --> 00:44:44,500
+مذكّر لأنه معادل للأكل لكن هذا الإنسان أساسا لا
+
+459
+00:44:44,500 --> 00:44:49,240
+يأكل ولا يشرب ولا يبيع ولا يشترى والإنسان هذا أيضا
+
+460
+00:44:52,470 --> 00:44:58,410
+فالطهارته حيا وميته في حال حياته .. كم هو ورد ..
+
+461
+00:44:58,410 --> 00:45:03,460
+المؤمن لا ينجزالمؤمن لا ينجس أيتها الأخوات بمعنى
+
+462
+00:45:03,460 --> 00:45:08,420
+عموما في حال حياتي وفي أثرا عنه ابن عباس رضي الله
+
+463
+00:45:08,420 --> 00:45:13,360
+عنه قال بصريحة الإبارة المؤمن لا ينجس حيا وميتا
+
+464
+00:45:13,360 --> 00:45:20,180
+نسيت حيا وميتا فبالتالي مثلة نقل العضو من .. أخد
+
+465
+00:45:20,180 --> 00:45:25,780
+نقل قطع العضو أو باتره من شخص لا يكون نجسا أقول
+
+466
+00:45:25,780 --> 00:45:32,490
+وحتى لو قلنا بأنه نجسفإن الضرورة تبيح المحورة
+
+467
+00:45:32,490 --> 00:45:37,090
+ولذلك .. ويعني احنا شوفنا كيف أجازة العلماء
+
+468
+00:45:37,090 --> 00:45:42,250
+التداوي بالمجاسات اضطرارا ومن أجل الحفاظ فكيف بما
+
+469
+00:45:42,250 --> 00:45:45,210
+.. إذا كان جمهور العلماء على أن ما قُطِع من
+
+470
+00:45:45,210 --> 00:45:48,950
+الإنسان من الإنسان ومن البني .. من الأدمي يبقى
+
+471
+00:45:48,950 --> 00:45:54,290
+طاهرا إذا ليس في ذلك أي إشكال على أي حال هذه بعض
+
+472
+00:45:54,290 --> 00:45:59,140
+المناقشات ثم بعد كل هذه المناقشاتبعد كل هذه
+
+473
+00:45:59,140 --> 00:46:04,420
+المناقشات والردود والأدلة فإنهم وضعوا شروطا قالوا
+
+474
+00:46:04,420 --> 00:46:09,620
+ومع ذلك كله احنا هنطمنكوا احنا حاطين شروط لكل
+
+475
+00:46:09,620 --> 00:46:14,120
+عملية نقل تتم إذا اختلت هذه الشروط احنا معاكم
+
+476
+00:46:14,120 --> 00:46:18,200
+نقوله بالجواز نقوله بالمنع في هذه الحالة نتحدث عن
+
+477
+00:46:18,200 --> 00:46:21,400
+هذه الشروط وبعض المسائل ده تصل المرة القادمة ان
+
+478
+00:46:21,400 --> 00:46:21,940
+شاء الله شكرا
+
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/xNyxH6OYlDc.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/xNyxH6OYlDc.srt
new file mode 100644
index 0000000000000000000000000000000000000000..da43bda1436fb1b7882f336c0a8653408b02049c
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/xNyxH6OYlDc.srt
@@ -0,0 +1,1575 @@
+1
+00:00:21,460 --> 00:00:24,460
+أعوذ بالله من الشيطان الرجيم بسم الله الرحمن
+
+2
+00:00:24,460 --> 00:00:28,940
+الرحيم الحمد لله رب العالمين والصلاة والسلام على
+
+3
+00:00:28,940 --> 00:00:32,840
+أشرف المرسلين محمد صلى الله عليه وسلم وعلى آله
+
+4
+00:00:32,840 --> 00:00:39,470
+وصحبه وسلم تسليما كثيرا وبعد، اليوم أيها الإخوة
+
+5
+00:00:39,470 --> 00:00:48,370
+والأخوات نبدأ بالحديث عن مسألتنا الأولى من المسائل
+
+6
+00:00:48,370 --> 00:00:53,790
+والقضايا المعاصرة ضمن 
+
+7
+00:00:53,790 --> 00:00:58,610
+مساق القضايا الفقهية المعاصرة وقد قلنا بأن هذه
+
+8
+00:00:58,610 --> 00:01:05,450
+المسائل بعضها سيكون في مجال العبادات وبعضها في مجال
+
+9
+00:01:05,450 --> 00:01:10,010
+المعاملات وبعضها في مجال الأحوال الشخصية وبعضها في
+
+10
+00:01:10,010 --> 00:01:15,570
+مجال الطب وبعضها في مجال السياسة والفني وإلى ما
+
+11
+00:01:15,570 --> 00:01:20,490
+سوى ذلك، واليوم
+
+12
+00:01:20,490 --> 00:01:25,270
+إن شاء الله نبدأ بالمسألة الأولى التي تكون في مجال
+
+13
+00:01:25,270 --> 00:01:33,970
+العبادات وهي مسألة اعتماد أوائل الشهور القمرية أو 
+
+14
+00:01:33,970 --> 00:01:42,600
+العربية كما تسمى بالحسابات الفلكية، هذه هي المسألة
+
+15
+00:01:42,600 --> 00:01:53,900
+كما نعرف، و كما نسمع، و كما نعايش، يختلف فيها العلماء
+
+16
+00:01:53,900 --> 00:01:58,460
+ويختلف فيها الناس في عصرنا اختلافا واسعا، تختلف
+
+17
+00:01:58,460 --> 00:02:06,750
+البلدان في ذلك في كل عام، خاصة أن هذا الاختلاف تظهر
+
+18
+00:02:06,750 --> 00:02:13,310
+آثاره في أشهر الصيام أو في شهر الصيام أو أشهر
+
+19
+00:02:13,310 --> 00:02:14,650
+الحج أحيانا
+
+20
+00:02:22,520 --> 00:02:29,600
+أثر الاختلافات وذلك الانتماء المسلمي بشهر الصيام
+
+21
+00:02:29,600 --> 00:02:38,260
+ولأنه يرتبط به عبادة من العبادات وربما كان 
+
+22
+00:02:38,260 --> 00:02:45,000
+الإسلام ألا وهو ربما أنا بصيالكن الحقيقة أن 
+
+23
+00:02:45,000 --> 00:02:49,920
+اعتماد أوائل الشهور لا يرتبط فقط بشهر الصيام بل
+
+24
+00:02:49,920 --> 00:02:56,800
+بكل الشهور، ولا يرتبط أيضا بعبادة الصيام بل ربما
+
+25
+00:02:56,800 --> 00:03:03,280
+يتعلق به عبادات كثيرة، الحج كما قلنا له علاقة كذلك
+
+26
+00:03:03,280 --> 00:03:12,720
+النية والكفارات والأيمان وإلى ما سوى ذلك، حتى أيضا
+
+27
+00:03:12,720 --> 00:03:20,680
+ربما الصلاوات، كل ذلك ربما يكون له ارتباط قريب أو من
+
+28
+00:03:20,680 --> 00:03:27,440
+بعيد باعتماد أوائل الشهور بالحسابات الفلسفية، نحن
+
+29
+00:03:27,440 --> 00:03:33,880
+نعرف أن الأصل في اعتماد أوائل الشهور القمرية هو
+
+30
+00:03:33,880 --> 00:03:42,720
+رؤية الهلال، فكلما رؤى الهلال في أوائل الشهر
+
+31
+00:03:42,720 --> 00:03:54,740
+العربي بدأ الحساب لهذا الشهر، وإن لم يرى طبعا هذا
+
+32
+00:03:54,740 --> 00:03:56,700
+في ليلة الثلاثين
+
+33
+00:03:59,100 --> 00:04:08,560
+يسبق يستقبل الهلال فإن رؤي الهلال بدأ شهر جديد، وإن 
+
+34
+00:04:08,560 --> 00:04:17,060
+لم يرى أكمل المسلمون أداء الشهر الذي هم فيه 30
+
+35
+00:04:17,060 --> 00:04:18,980
+يوما، وعلى هذا
+
+36
+00:04:26,030 --> 00:04:31,970
+تحل رؤيته تؤثر له .. ل .. ل .. ل رؤيته، فبدل الشهر
+
+37
+00:04:31,970 --> 00:04:37,330
+الذي بيبدأ بالصيام و بيبدأ بالصيام طبعا يبدأ
+
+38
+00:04:37,330 --> 00:04:46,050
+بالرؤية، و كذلك ينتبي بالرؤية، و
+
+39
+00:04:46,050 --> 00:04:53,830
+إذا كان الصيام .. أو إذا كانت .. إذا كان اعتماده
+
+40
+00:04:53,830 --> 00:04:54,750
+أوائل الشهور
+
+41
+00:05:17,100 --> 00:05:19,580
+وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا
+
+42
+00:05:19,580 --> 00:05:21,400
+وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا
+
+43
+00:05:21,400 --> 00:05:42,420
+وطاوا وطاوا وطاوا وطاااااااااااااااااااااااااااا
+
+44
+00:05:42,650 --> 00:05:47,510
+على الأقل يعني في قطب متوازي مع الرؤية ستظهر
+
+45
+00:05:47,510 --> 00:05:53,050
+الاشتباه في الرؤية عند وجود الغيم، عند وجود الشك أو
+
+46
+00:05:53,050 --> 00:06:01,630
+إلى غير ذلك، ونحن نرى في سنوات متعددة يغم علينا ال
+
+47
+00:06:01,630 --> 00:06:09,190
+.. ال .. ال .. الهلال ويختلف الناس في .. في ذلك
+
+48
+00:06:10,660 --> 00:06:16,620
+فهل ممكن أن .. أن نحسم الأمر ونعتمد على ما تأتنا
+
+49
+00:06:16,620 --> 00:06:20,460
+الحسابات الفلكية من النتائج ونبدأ شهرنا وبالتالي
+
+50
+00:06:20,460 --> 00:06:26,860
+نبدأ عباداتنا من صيام وغير ذلك من مختلف العبادات
+
+51
+00:06:26,860 --> 00:06:31,360
+أم أنها الرؤية والرؤية فقط، الرؤية أو الإكمال
+
+52
+00:06:31,360 --> 00:06:37,120
+للشهر الذي صدق هم الذين أيضا يبدأ بهم أو ما يبدأ
+
+53
+00:06:37,120 --> 00:06:39,320
+بهم الشهر
+
+54
+00:06:41,830 --> 00:06:48,910
+هذه المسألة التي سنحاول مناقشتها في هذه القاضرة
+
+55
+00:06:48,910 --> 00:06:55,230
+وأقول هنا إن العلماء القدامى تكاد تكون كلمتهم
+
+56
+00:06:55,230 --> 00:07:03,110
+مُجْمَعَة على أنه لا اعتبار للحسابات الفلكية
+
+57
+00:07:03,110 --> 00:07:05,650
+باعتماد أوائل الشهور القديم
+
+58
+00:07:09,150 --> 00:07:19,150
+المعتمدة في ذلك هو الرؤية فقط، و
+
+59
+00:07:19,150 --> 00:07:23,710
+ذلك بناء على الحديث والأيات الواردة، وكذلك التي
+
+60
+00:07:23,710 --> 00:07:32,550
+ربما نمر عليها يعني بعد قليل، ولكن يبقى السؤال هنا
+
+61
+00:07:32,550 --> 00:07:39,590
+لماذا كان .. لماذا اتفق العلماء أو لماذا كانت
+
+62
+00:07:39,590 --> 00:07:46,150
+حجة العلماء القدامى متفقة على عدم جواز اعتماد
+
+63
+00:07:46,150 --> 00:07:51,610
+أوائل الشهور بالحسابات الفلكية مع أنهم اليوم
+
+64
+00:07:51,610 --> 00:07:55,570
+بشكل مختلفين كما سنرى يعني العلماء الحديثين
+
+65
+00:07:55,570 --> 00:07:56,590
+مختلفون
+
+66
+00:08:00,110 --> 00:08:07,490
+مُخْتَلِفُونَ في ذلك، ومنهم
+
+67
+00:08:07,490 --> 00:08:11,930
+من يجيز اعتماد أول شهور بالحسابات الفلكية، ومنهم من
+
+68
+00:08:11,930 --> 00:08:18,670
+لا يجيز، لكن القدامى كما قلت لم يجيزوا وكانوا
+
+69
+00:08:18,670 --> 00:08:24,710
+متفقين على أن الحسابات الفلكية أَكْثَرُ لأن يستطيعوا
+
+70
+00:08:24,710 --> 00:08:29,370
+أن اتفاقهم هذا يعود إلى ثلاثة أسباب رئيسيين
+
+71
+00:09:35,450 --> 00:09:35,950
+الله يبكي مني
+
+72
+00:10:08,980 --> 00:10:15,120
+الكهانة والعرابة والتنجيم، مع العلم أن الإسلام قد
+
+73
+00:10:15,120 --> 00:10:22,680
+شن حملة شعواء ضد السحر والسحرة والكهانة والكهنة 
+
+74
+00:10:24,150 --> 00:10:32,430
+والعرافة والعرّافين، ولا يقفأ على أحد منا كيف أن
+
+75
+00:10:32,430 --> 00:10:36,050
+النبي صلى الله عليه وسلم اعتبر السحر من الكبائر 
+
+76
+00:10:36,050 --> 00:10:44,290
+الموبقات واعتبر أن من أتى ساحرا أو كاهنا أو عرافا 
+
+77
+00:10:44,290 --> 00:10:48,670
+لم تقبل له صلاة أربعين يوما أو إلى غير ذلك، كل هذا
+
+78
+00:10:48,670 --> 00:10:54,790
+يؤكد على أن الإسلام حارب السحر والكهانوت فلا يُعقل
+
+79
+00:10:54,790 --> 00:11:02,250
+بالتالي أن يعتمد عليه أو على حسابات مختلطة به في
+
+80
+00:11:02,250 --> 00:11:07,190
+اعتماد أوائل الشهور وإثباتها والتي قد يرتبط بها 
+
+81
+00:11:07,190 --> 00:11:11,570
+كثير من العبادات، لكن
+
+82
+00:11:12,970 --> 00:11:19,210
+بعد أن أصبح ال .. ال .. بعد أن أصبح علم الفلك بعد
+
+83
+00:11:19,210 --> 00:11:27,370
+أن أصبح علم الفلك علما مستقلا بذاته منفصل
+
+84
+00:11:27,370 --> 00:11:35,730
+عن السحر والكهانة، وأصبح له قواعد أساسية وأصبح تل
+
+85
+00:11:35,730 --> 00:11:41,230
+الأمم وأصبح تل الأمم تهتم به اهتماما كبيرا 
+
+86
+00:11:41,630 --> 00:11:48,550
+وتتسابق في تطويره
+
+87
+00:11:48,550 --> 00:11:56,450
+وفي الأخذ بزمام أمره، انتهت
+
+88
+00:11:56,450 --> 00:12:03,510
+الرابط بينهم وبين الكهانة وبين السحر، فانتهى هذا 
+
+89
+00:12:03,510 --> 00:12:09,010
+السبب، وأما بالنسبة للسبب الثاني وهو النتائج غير 
+
+90
+00:12:09,010 --> 00:12:16,250
+دقيقة، اليوم اختلف الحال أيضا، فأصبح علم الفلك يؤتي 
+
+91
+00:12:16,250 --> 00:12:25,990
+نتائج دقيقة جدا لا تكاد تخطئ، ونحن نرى أمثلة على ذلك 
+
+92
+00:12:25,990 --> 00:12:36,250
+كيف أن علماء الفلك يعلنون عن مواقيت مثلا خسوف 
+
+93
+00:12:36,250 --> 00:12:47,130
+القمر وخسوف الشمس بالساعة والدقيقة والثانية ويتأكد 
+
+94
+00:12:47,130 --> 00:12:54,990
+لصحة ذلك بلو يعلنون عن المكان وعن الأجزاء التي
+
+95
+00:12:54,990 --> 00:13:02,410
+يمكن أن يتم بها الخسف والكسف وإلى غير ذلك وكل 
+
+96
+00:13:02,410 --> 00:13:06,510
+ذلك بل يمكن أن يتم الإعلان أو يعرف عن طريق علم
+
+97
+00:13:06,510 --> 00:13:12,890
+الفلك عن كل ذلك لمئات سنوات من السنوات القادمة، و
+
+98
+00:13:12,890 --> 00:13:20,530
+من هنا فإن اختلاف الحال، واختلاف وتغير الأسباب كان
+
+99
+00:13:20,530 --> 00:13:24,090
+مدعوا لإعادة النظر في هذه المسألة بعد أن كان
+
+100
+00:13:24,090 --> 00:13:34,150
+العلماء متفقين تقريبا على عدم جواز اعتماد أوائل
+
+101
+00:13:34,150 --> 00:13:39,290
+الشهور العربي بالحسابات الفلكية
+
+102
+00:13:43,030 --> 00:13:49,130
+وربما وردت نصوص 
+
+103
+00:13:49,130 --> 00:13:55,450
+منسوبة للعلماء القدامى تؤكد بما لا يدع مجالا
+
+104
+00:13:55,450 --> 00:14:02,020
+للشك رفضهم، وعلى سبيل المثال بالأخذ بهذه المسألة
+
+105
+00:14:02,020 --> 00:14:06,820
+وعلى مختلف المذاهب، فمثلا نجد الإمام السرخسي في
+
+106
+00:14:06,820 --> 00:14:13,300
+المذهب الحنفي يقول، ومنهم من قال يرجعوا إلى أهل
+
+107
+00:14:13,300 --> 00:14:21,360
+الحساب أي يقصد في اعتماد أوائل الشهور القمرية، ومنهم
+
+108
+00:14:21,360 --> 00:14:26,160
+من قال يرجعوا إلى أهل الحساب عند الاشتباه، ثم يقول
+
+109
+00:14:26,160 --> 00:14:31,300
+ماذا؟ وهذا بعيد، فإن النبي صلى الله عليه وسلم قال من
+
+110
+00:14:31,300 --> 00:14:36,740
+أتى كاهنا أو عرافا وصدقه بما يقول فقد كفر بما أنزل
+
+111
+00:14:36,740 --> 00:14:41,680
+على محمد، وهذا يؤكد يعني السبب الذي من أجله
+
+112
+00:14:41,680 --> 00:14:47,180
+استبعدوا استبعد هؤلاء اعتماد أوائل الشهور
+
+113
+00:14:47,180 --> 00:14:52,140
+بالحسابات الفلكية لاختلاطه بعلم أو لاختلاطه بالسحر
+
+114
+00:14:52,140 --> 00:15:00,150
+والتنجيم والعرافة، وكذلك فإن الإمام
+
+115
+00:15:00,150 --> 00:15:05,390
+القرافي المالكي المذهب يقول: وقاعدة رؤية الأهلة في
+
+116
+00:15:05,390 --> 00:15:12,970
+الرمضانات لا يجوز إثباتها بالحساب، نفى الأمر، كذلك
+
+117
+00:15:12,970 --> 00:15:20,690
+الإمام النووي من الشافعية يقول في التدليل
+
+118
+00:15:20,690 --> 00:15:27,070
+على عدم اعتماد أوائل الشهور القمرية بالحسابات
+
+119
+00:15:27,070 --> 00:15:32,830
+الفلكية يقول: لأن النجوم والحساب لا مدخلة لها في
+
+120
+00:15:32,830 --> 00:15:35,730
+العبادات
+
+121
+00:15:36,170 --> 00:15:41,550
+ويقول آخر من المذهب الشافعي إن الشارع لم يعتمد 
+
+122
+00:15:41,550 --> 00:15:48,470
+الحساب بل ألغاه بالكلية، وهذا أيضا ابن مفلح
+
+123
+00:15:48,470 --> 00:15:56,400
+الحنبلي يقول: ومن صام بنجوم أو حساب لم يجزئه وإن
+
+124
+00:15:56,400 --> 00:16:02,540
+أصاب ولا يُحكم بطلوع الهلال بهِم ولو كثرت إصابتهم
+
+125
+00:16:02,540 --> 00:16:07,220
+هذا الكلام أو هذه النصوص التي ذكرت وتلقت وتلوت
+
+126
+00:16:07,220 --> 00:16:14,020
+تدلل على أن العلماء القدامى يعني متفقين تقريبا على
+
+127
+00:16:14,020 --> 00:16:20,500
+عدم جواز اعتماد أوائل الشهور القمرية بالحسابات
+
+128
+00:16:20,500 --> 00:16:27,530
+الفلكية، لكن كمان قلت، لكن عندما تغيرت الأسباب 
+
+129
+00:16:27,530 --> 00:16:31,970
+والعلال التي من أجلها كان هذا الاتفاق والتي تمحورت
+
+130
+00:16:31,970 --> 00:16:37,110
+كما قلت في الاختلاط 
+
+131
+00:16:37,110 --> 00:16:43,530
+اختلاط الحساب الفلكي والشعوذة وكذلك عدم إعطائه
+
+132
+00:16:43,530 --> 00:16:47,210
+للنتائج الدقيقة، هذا كله تغير وأصبح الحسابات
+
+133
+00:16:47,210 --> 00:16:50,090
+الفلكية أصبحت وضعت نتائج دقيقة وأصبحت علما
+
+134
+00:16:50,090 --> 00:16:58,670
+مستقلا ومنفصلا فصلا تاما عن السحر
+
+135
+00:16:58,670 --> 00:17:03,670
+والشعوذة، ده كان لابد بالطبع من إعادة النظر، وهذا ما 
+
+136
+00:17:03,670 --> 00:17:12,870
+حدث بالفعل بالنسبة للعلماء المحدثين، وعندما عاد
+
+137
+00:17:12,870 --> 00:17:19,930
+العلماء المحدثين النظر والاجتهاد في هذه المسألة في
+
+138
+00:17:19,930 --> 00:17:28,900
+هذا العصر اختلفوا اختلفوا على فريقين، فمنهم من ظل
+
+139
+00:17:28,900 --> 00:17:32,300
+على ما كان عليه العلماء القدامى من عدم جواز
+
+140
+00:17:32,300 --> 00:17:38,540
+اختلاف، عدم جواز اعتماد أوائل الشهور القمرية 
+
+141
+00:17:38,540 --> 00:17:46,260
+بالحسابات الفلكية، ومنهم من خالف ذلك، من خالف وقال
+
+142
+00:17:46,630 --> 00:17:53,490
+بل يجوز اعتماد أوائل الشهور القمرية بالحسابات
+
+143
+00:17:53,490 --> 00:17:59,330
+الفلكية، يعني بعد أن تغيرت الأسباب والدواعي التي من
+
+144
+00:17:59,330 --> 00:18:05,450
+أجلها كان الإجماع السابق أو الرفض لهذا الاعتماد
+
+145
+00:18:05,450 --> 00:18:13,690
+عند العلماء القدامى، ويبقى السؤال إذا كانت الدواعي
+
+146
+00:18:13,690 --> 00:18:19,740
+قد تغيرت فلماذا نجد اختلافا بين العلماء؟ لماذا 
+
+147
+00:18:19,740 --> 00:18:23,620
+وجدنا فريقا ولعله الفريق الأكبر، فريق الجمهور، ظل
+
+148
+00:18:23,620 --> 00:18:29,700
+على ما كان عليه العلماء القدامى من عدم جواز اعتماد
+
+149
+00:18:29,700 --> 00:18:33,560
+أوائل الشهور أو عدم قبول على الأقل اعتماد أوائل
+
+150
+00:18:33,560 --> 00:18:38,300
+الشهور القمرية بالحسابات الفلكية رغم تغيير
+
+151
+00:18:38,300 --> 00:18:43,130
+الدواعي؟ هذا يدل على أن هناك أسبابا أخرى، وهذه هي
+
+152
+00:18:43,130 --> 00:18:48,450
+الحقيقة، هناك أسباب أخرى أو أدلة أخرى جعلهم إلى ال
+
+153
+00:18:48,450 --> 00:18:54,370
+.. ال .. ال .. التمسك بهذا الرأي والتمسك بالرؤية 
+
+154
+00:18:54,370 --> 00:19:02,130
+ وعدم اعتبار واعتماد الحساب الفلكي، لكن بالنسبة
+
+155
+00:19:02,130 --> 00:19:08,780
+للفريق الآخر، لدى أيضا اعتمد على أدلة أخرى تعالوا 
+
+156
+00:19:08,780 --> 00:19:15,120
+بنا نرى ما هي وجهة نظر كل فريق وما هي الأدلة التي
+
+157
+00:19:15,120 --> 00:19:23,460
+اعتمد عليها الفريق، أما الفريق الأول وهم جمهور
+
+158
+00:19:23,460 --> 00:19:30,560
+العلماء المعاصرين أو أكثر المعاصرين من العلماء والذين
+
+159
+00:19:30,560 --> 00:19:38,360
+قالوا لعدم جواز اعتماد الحساب الفلكي متابعين في
+
+160
+00:19:38,360 --> 00:19:45,260
+ذلك للعلماء القدامى الذين كما قلت وقرروا دائما
+
+161
+00:19:45,260 --> 00:19:49,780
+اتفقوا أو تكاد تكون كلمتهم بحل اتفاق على منع 
+
+162
+00:19:49,780 --> 00:19:55,380
+اعتماد الحساب الفلكي بمنع اعتماد أوائل الشهور 
+
+163
+00:19:55,380 --> 00:20:03,970
+بالحساب الفلكي، هؤلاء يعني يمثلون رأي الجمهور من
+
+164
+00:20:03,970 --> 00:20:12,110
+المعاصرين، واستدلوا بأدلة متعددة، جملة هذه الأدلة
+
+165
+00:20:12,110 --> 00:20:21,150
+يعود إلى أن هناك أدلة يفهم منها الأمر بالأخذ برؤية
+
+166
+00:20:21,150 --> 00:20:28,820
+الهلال للاعتماد أوائل الشهور، وهناك أدلة تمنع الأخذ
+
+167
+00:20:28,820 --> 00:20:35,000
+بغير الرؤية أو تمنع الأخذ بالحساب، هذا جمع ما 
+
+168
+00:20:35,000 --> 00:20:40,300
+اعتمدوا عليه، يعني بمعنى آخر، حتى لو أن الحسابات 
+
+169
+00:20:40,300 --> 00:20:47,760
+أصبحت تؤتي بنتائج دقيقة، وحتى لو أنها استقلت وانفصلت 
+
+170
+00:20:47,760 --> 00:20:52,120
+عن السحر والشعوذة، لكن يبقى الأساس الذي لابد أن
+
+171
+00:20:52,120 --> 00:20:56,340
+نعتمد عليه، والأساس الذي أمرنا به في نصوص الشرع 
+
+172
+00:20:56,340 --> 00:21:03,980
+الحكيم هو الرؤية والرؤية فقط، وهذه النصوص تفيد
+
+173
+00:21:03,980 --> 00:21:08,640
+بطريقنا أو بآخر بالأمر من الأخذ بها والمنأ من 
+
+174
+00:21:08,640 --> 00:21:17,200
+الأخذ بغيرها، فلو 
+
+175
+00:21:17,200 --> 00:21:21,020
+نظرنا مثلا إلى بعض الأدلة الواردة في كتاب ربنا
+
+176
+00:21:21,020 --> 00:21:25,900
+سبحانه وتعالى عندما
+
+201
+00:24:01,280 --> 00:24:07,980
+فاتموا ثلاثين يوما لم
+
+202
+00:24:07,980 --> 00:24:13,660
+يقول فإن غم عليكم فاعتمدوا الحساب ولكن حتى في حالة
+
+203
+00:24:13,660 --> 00:24:19,860
+الاشتباه وفي حالة أن يغم علينا ونشق فيه فإننا نكمل
+
+204
+00:24:19,860 --> 00:24:26,940
+الشهر ولا نعتمد على أي شيء آخر ولو كان الحساب
+
+205
+00:24:26,940 --> 00:24:31,760
+لهؤلاء أن يقولوا ولو كان حسابه معتمدا أو جائزا
+
+206
+00:24:31,760 --> 00:24:36,000
+لقال النبي صلى الله عليه وسلم في ذلك فانغم عليكم
+
+207
+00:24:36,000 --> 00:24:42,200
+فاعتمدوا الحساب ووضع قيدا إذا كان حسابه دقيقة، إذا 
+
+208
+00:24:42,200 --> 00:24:49,100
+كنت مقمئنين إلى حساباتكم وتوصلكم إلى نتائج دقيقة،
+
+209
+00:24:49,100 --> 00:24:54,980
+ولكنه لم يقول ذلك في تأكيد على أن الرؤية هي التي
+
+210
+00:24:54,980 --> 00:25:04,920
+تعتمد في احتساب أوائل الشهور واعتمادها والحديث بهذا
+
+211
+00:25:04,920 --> 00:25:09,700
+المعنى كثير الرسول صلى الله عليه وسلم يقول إذا
+
+212
+00:25:09,700 --> 00:25:15,620
+رأيتمه فصوموا وإذا رأيتمه فافطروا فإن غم عليكم
+
+213
+00:25:15,620 --> 00:25:23,950
+فاقدروا واقدروا هنا وإن كانت تحتمل الحساب، لكنهم 
+
+214
+00:25:23,950 --> 00:25:29,810
+قالوا أن هذا مفسر لقوله صلى الله عليه وسلم في
+
+215
+00:25:29,810 --> 00:25:35,710
+رواية أخرى فاقدروا له ثلاثين أي احسبوا ثلاثين
+
+216
+00:25:35,710 --> 00:25:41,110
+يوما، فالحساب ليس على إطلاق، ولكن حساب الشهر نفسه
+
+217
+00:25:41,110 --> 00:25:46,850
+وليس حساب الفلك أشاهدوا في كل ذلك أن النصوص
+
+218
+00:25:46,850 --> 00:25:58,990
+والأحاديث على رأي هذا الفريق لم تشر إلى الاستعانة
+
+219
+00:25:58,990 --> 00:26:05,790
+بأي وسيلة أخرى من وسائل إثبات أوائل الشهور
+
+220
+00:26:05,790 --> 00:26:08,810
+باستثناء الرؤية
+
+221
+00:26:10,080 --> 00:26:14,740
+لو كانت الاستعانة والإثبات لأوائل الشهور بغير هذا
+
+222
+00:26:14,740 --> 00:26:22,320
+الطريق جائز لأشارة إليه يعني صراحة أو تلميح على
+
+223
+00:26:22,320 --> 00:26:23,840
+الأقل
+
+224
+00:26:27,160 --> 00:26:32,940
+وكذلك الحال يمكن أن يستدل هؤلاء بقوله صلى الله 
+
+225
+00:26:32,940 --> 00:26:38,220
+عليه وسلم إنه من يعش منكم فسيجدوا اختلافا كثيرا
+
+226
+00:26:38,220 --> 00:26:42,420
+فعليكم بسنة وسنة الخلفاء الراشدين المهديين من بعدي
+
+227
+00:26:42,420 --> 00:26:48,440
+تمسكوا بها وعضوا عليها بالنواجذ وإياكم ومحدثات
+
+228
+00:26:48,440 --> 00:26:54,790
+الأمور فإن كل بدعة ضلالة يعني أيضا الحديث الذي
+
+229
+00:26:54,790 --> 00:26:59,910
+يرويه أبو داود يشير
+
+230
+00:26:59,910 --> 00:27:08,450
+إلى أنه في حالة الاختلاف في المسائل التي ربما تحدث
+
+231
+00:27:08,450 --> 00:27:15,090
+بين العلماء الأصل في الفصل والحكم فيها الرجوع إلى
+
+232
+00:27:15,090 --> 00:27:23,800
+السنة ورجوع إلى السنة كما رأينا نتأكد من أن وسيلة
+
+233
+00:27:23,800 --> 00:27:32,740
+الإثبات هي الرؤية والرؤية فقط ثم إن هذا الرأي
+
+234
+00:27:32,740 --> 00:27:37,400
+أيضا الذي يقول به هذا الفريق من العلماء المعاصرين
+
+235
+00:27:37,400 --> 00:27:42,880
+هو رأي العلماء القدامى وأستطيع أن أقول أن العلماء
+
+236
+00:27:42,880 --> 00:27:51,540
+القدامى عندما قالوا بمنع اعتماد الحسابات الفلكية
+
+237
+00:27:51,540 --> 00:28:00,340
+كان الحساب الفلكي معروفا ومع ذلك حتى وإن كان
+
+238
+00:28:00,340 --> 00:28:08,600
+ينتجوا نتائج عن غير دقيقة ومع ذلك فإنهم كانوا
+
+239
+00:28:08,600 --> 00:28:09,900
+يتشددوا
+
+240
+00:28:12,730 --> 00:28:22,190
+بعدم الأخذ به ويمنعونه تماما يمكن أن يقال أيضا
+
+241
+00:28:22,190 --> 00:28:27,810
+أنهم استدلوا بأن ذلك قد يكون اعتماد الحساب الفلكي في
+
+242
+00:28:27,810 --> 00:28:32,590
+إثبات أوائل الشهور قد يكون فيه نوع مشقة ونحن نعلم
+
+243
+00:28:32,590 --> 00:28:37,270
+أن ديننا دين يسر والله عز وجل ما جعل علينا فيه
+
+244
+00:28:37,270 --> 00:28:42,870
+الدين من حاجة ربما هذه مجمل الأدلة اللي تستدل بها
+
+245
+00:28:42,870 --> 00:28:44,110
+القائلون 
+
+246
+00:28:49,210 --> 00:28:55,330
+بأن أوائل الشهور لا تثبت بالحسابات الفلكية لكن
+
+247
+00:28:55,330 --> 00:29:07,050
+فريقا آخر له رأي آخر فريق آخر من العلماء خالفوا
+
+248
+00:29:07,050 --> 00:29:13,570
+هذا الرأي وقالوا لا بل أن اعتماد أوائل الشهور
+
+249
+00:29:13,570 --> 00:29:19,110
+يمكن أن يتم بالحسابات الفلكية بل أنهم يعني لم
+
+250
+00:29:19,110 --> 00:29:24,250
+يقولوا بالجواز فقط بل إنهم استهجنوا واستغربوا من
+
+251
+00:29:24,250 --> 00:29:32,530
+أولئك الذين يمنعون أو من الفريق الذي يمنع واعتبروا
+
+252
+00:29:32,530 --> 00:29:41,190
+رأيهم رأيا بعيدا كل البعد عن الصواب والسداد
+
+253
+00:29:41,190 --> 00:29:48,110
+وأنهم من غير المعقول أن نترك الأخذ بالحساب الفلكي
+
+254
+00:29:48,110 --> 00:29:55,370
+في عصر وفي زمان يعني أصبحت أدنى وأقل منجزات
+
+255
+00:29:55,370 --> 00:29:59,290
+الحسابات الفلكية معرفة أوائل الشهور ومعرفة منازل
+
+256
+00:29:59,290 --> 00:30:04,190
+القمر ومتى يظهر ومتى يمكن أن يرى وإلى غير ذلك في
+
+257
+00:30:04,190 --> 00:30:13,610
+الوقت الذي يصل العلماء في هذا العصر إلى إلى نتائج
+
+258
+00:30:13,610 --> 00:30:18,870
+كثيرة جدا وكبيرة جدا ودقيقة جدا في مختلف جوانب
+
+259
+00:30:18,870 --> 00:30:26,310
+العلم الفلكي ثم 
+
+260
+00:30:26,310 --> 00:30:31,790
+هذا في الجملة يعني ثم إنهم إضافة إلى ذلك قالوا
+
+261
+00:30:31,790 --> 00:30:39,510
+بأننا إنما نقول بذلك ولدينا من الأدلة التي تؤكد
+
+262
+00:30:39,510 --> 00:30:49,730
+على ما نقول وترد على أراء هؤلاء القائلين بالمنع فإن
+
+263
+00:30:49,730 --> 00:30:56,920
+الأحاديث النبوية في هذا الشأن والتي استدل بها
+
+264
+00:30:56,920 --> 00:31:02,300
+القائلون بالمنع نستطيع أن نقول أن هذه الأحاديث
+
+265
+00:31:02,300 --> 00:31:11,460
+نفسها يمكن بنظرة دقيقة عميقة أن نستدل بها على جواز
+
+266
+00:31:11,460 --> 00:31:18,580
+الأخذ بالحسابات الفلكية في اعتماد أوائل الشهور
+
+267
+00:31:18,580 --> 00:31:20,620
+العربية
+
+268
+00:31:24,240 --> 00:31:30,820
+ذلك أن حديثه صلى الله عليه وسلم الذي يقول فيه
+
+269
+00:31:30,820 --> 00:31:35,900
+صوموا لرؤيته وافطروا لرؤيته إنما هو جزء من حديث
+
+270
+00:31:35,900 --> 00:31:43,200
+طويل قال فيه النبي صلى الله عليه وسلم نحن أمة أمية
+
+271
+00:31:43,200 --> 00:31:45,080
+لا نكتب ولا نحسب
+
+272
+00:31:49,850 --> 00:31:56,950
+وبعد ذلك قال صوموا لرؤيته وافطروا لرؤيته بما يدلل
+
+273
+00:31:56,950 --> 00:32:02,570
+على أن اعتماد الرؤية كما قالوا اعتماد الرؤية إنما
+
+274
+00:32:02,570 --> 00:32:08,310
+كان مرتبط بكون هذه الأمة أمة أمية لا تعرف الحساب
+
+275
+00:32:08,310 --> 00:32:13,870
+ولا تعرف الكتاب في إشارة إلى أن العلة التي من
+
+276
+00:32:13,870 --> 00:32:22,560
+أجلها اعتمدت الرؤية هي الأمية وبالتالي في حالة عدم
+
+277
+00:32:22,560 --> 00:32:28,860
+وجود الأمية وفي حالة التعلق العلمي والتطور فإنه 
+
+278
+00:32:28,860 --> 00:32:35,920
+لا بأس بالأخذ بالحساب الفلكي هذا ما يعني فهموه من
+
+279
+00:32:35,920 --> 00:32:42,500
+هذا الحديث أو من مثل هذا الحديث يعني بالمفهوم أنه
+
+280
+00:32:42,500 --> 00:32:45,940
+كأن الرسول صلى الله عليه وسلم عندما قال صوموا
+
+281
+00:32:45,940 --> 00:32:50,740
+لرؤيته وأفطروا لرؤيته إنما جاء تعلينا لكون هذه
+
+282
+00:32:50,740 --> 00:32:54,540
+الأمة أمية لا تعرف الحساب وكأنه يريد أن يقول
+
+283
+00:32:54,540 --> 00:33:00,680
+وبالتالي فإذا جاءت أيام أو جاء زمان يعرف فيه أو
+
+284
+00:33:00,680 --> 00:33:05,220
+عرف فيه المسلمون الحساب فلا بأس أن يعتمدوا الحساب
+
+285
+00:33:05,220 --> 00:33:09,160
+بإثبات أوائل الشهور
+
+286
+00:33:11,400 --> 00:33:15,900
+يعني هذا يا واحد ثانيا من الأدلة قالوا وكأن بهم
+
+287
+00:33:15,900 --> 00:33:18,560
+نظروا إلى الواقع استدلال من الواقع الواقع اللي
+
+288
+00:33:18,560 --> 00:33:24,260
+اللي نعيش أننا نجد اختلافا واسعا بين الدول
+
+289
+00:33:24,260 --> 00:33:28,000
+الإسلامية اليوم قد يصل إلى ثلاث أيام في بعض الشهور
+
+290
+00:33:28,000 --> 00:33:35,360
+خاصة شهر الصيام فمنهم من يصوم يعني قبل دولة تصوم
+
+291
+00:33:35,360 --> 00:33:39,860
+قبل دولة بيوم أو بيومين وهذا يحدث اختلافا ولو
+
+292
+00:33:39,860 --> 00:33:44,780
+اعتمدنا كأن بيهم يريدون القول لو اعتمدنا الحساب
+
+293
+00:33:44,780 --> 00:33:50,040
+الفلكي لوحدنا الأمة مع العلم أن وحدة الأمة مقصد من
+
+294
+00:33:50,040 --> 00:33:56,460
+مقاصد التشريع العظيمة التي يحرص عليها الإسلام ونصت
+
+295
+00:33:56,460 --> 00:34:01,360
+عليها آيات وأحاديث كثيرة في القرآن الكريم وفي
+
+296
+00:34:01,360 --> 00:34:10,040
+السنة النبوية فالوحدة يعني شيء مهم في ديننا وفي
+
+297
+00:34:10,040 --> 00:34:16,320
+شريعتنا وإذا كان هذا الأمر يوحدنا ويوحد قامة
+
+298
+00:34:16,320 --> 00:34:22,240
+شعائرنا ونسقنا فلم لا ويعطينا في نفس الوقت نتائج
+
+299
+00:34:22,240 --> 00:34:27,920
+دقيقة وليس فيه نهي منصريح أيضا في الأحاديث فإن
+
+300
+00:34:27,920 --> 00:34:33,980
+الأحاديث تدلل بالمفهوم على جواز ذلك
+
+301
+00:34:36,650 --> 00:34:41,470
+ثم إنهم قالوا بأن بعض العلماء القدامى صحيح معظمهم
+
+302
+00:34:41,470 --> 00:34:51,690
+يعني كانوا على المنع لكن منعهم كان بسبب ما اختلط
+
+303
+00:34:51,690 --> 00:34:55,290
+فيه الحساب بالتنجيم وبسبب عدم
+
+304
+00:34:58,820 --> 00:35:04,260
+وبسبب عدم النتائج الدقيقة التي يعطيها الحساب
+
+305
+00:35:04,260 --> 00:35:14,920
+الفلكي أما وقد تغيرت كل هذه المعطيات فإننا
+
+306
+00:35:14,920 --> 00:35:19,840
+بقولنا بالجواز حقيقة لا نخالف هؤلاء القدامى ولو
+
+307
+00:35:19,840 --> 00:35:23,220
+عاش هؤلاء العلماء القدامى في عصرنا هذا لقالوا بما
+
+308
+00:35:23,680 --> 00:35:29,100
+بما نقول ناهيك عن أن بعض العلماء القدامى وفي ظل
+
+309
+00:35:29,100 --> 00:35:36,800
+وجود حسابات فلكية غير دقيقة كانوا يطالبون وكانوا
+
+310
+00:35:36,800 --> 00:35:42,580
+يقولون بجواز الحساب الفلكي بجواز اعتماد الحساب
+
+311
+00:35:42,580 --> 00:35:52,240
+الفلكي في أوائل لإثبات أوائل الشهور فلو نظرنا سنجد
+
+312
+00:35:52,240 --> 00:36:00,740
+يعني أنه بعض العلماء القدامى يعني من مقولاتهم أنهم
+
+313
+00:36:00,740 --> 00:36:06,500
+قالوا يعتبروا الهلال إذا غم بالنجوم
+
+314
+00:36:06,500 --> 00:36:17,760
+يعتبروا الهلال أو يحسب حساب الهلال يحسب ظهوره حسابا
+
+315
+00:36:17,760 --> 00:36:24,300
+إذا غم بالنجوم أو بمعنى آخر بطريقة الحساب
+
+316
+00:36:26,080 --> 00:36:31,080
+ثم إنهم إضافة إلى ذلك قالوا بأن قواعد معرفة الحساب
+
+317
+00:36:31,080 --> 00:36:41,200
+اليوم أصبحت متطورة ودقيقة وكذلك اعتمدوا في
+
+318
+00:36:41,200 --> 00:36:46,280
+أدلتهم على القياس على مواقيت الصلاوات فإن مواقيت
+
+319
+00:36:46,280 --> 00:36:52,040
+الصلاوات اليوم التي يعتمدها المسلمون في صلواتهم
+
+320
+00:36:52,040 --> 00:36:58,490
+ويؤقتون بها مواعيد صلواتهم معتمدة على الحسابات
+
+321
+00:36:58,490 --> 00:37:03,670
+الفلكية فإذا كانت الصلاة ومواقيتها تعتمد على
+
+322
+00:37:03,670 --> 00:37:09,050
+الحسابات الفلكية فلم لا نعتمد الصيام مع العلم أن
+
+323
+00:37:09,050 --> 00:37:16,950
+الصلاة ركنها مقدم حتى على الصيام هذه مجموعة الأدلة
+
+324
+00:37:16,950 --> 00:37:22,510
+التي استدلت بها الفريق الثاني ولنا أن نقف يعني
+
+325
+00:37:22,510 --> 00:37:31,090
+وقفة مختصرة في مناقشة أدلة كل فريق لنصل إن شاء
+
+326
+00:37:31,090 --> 00:37:44,040
+الله بعد ذلك إلى الرأي الراجح أما مناقشة المانعين
+
+327
+00:37:44,040 --> 00:37:47,940
+نبدأ بمناقشة المانعين للمجيزين أصحاب الرأي الأول
+
+328
+00:37:47,940 --> 00:37:55,400
+يعني الذين منعوا اعتماد الحساب الفلكي ناقشوا أدلة
+
+329
+00:37:55,400 --> 00:38:00,680
+الرأي الثاني الذين مجيزون
+
+330
+00:38:04,750 --> 00:38:15,590
+بمناقشات متعددة مثلا في الحديث الذي اعتمدوه في
+
+331
+00:38:15,590 --> 00:38:19,990
+قوله صلى الله عليه وسلم فاقدروا وفهموا منه معنى
+
+332
+00:38:19,990 --> 00:38:24,470
+فاحسبوا قالوا يعني أن هذا الحديث
+
+333
+00:38:26,790 --> 00:38:32,490
+مفسر في قوله في روايات أخرى بقوله صلى الله عليه
+
+334
+00:38:32,490 --> 00:38:37,590
+وسلم فقدروا له ثلاثين أي أن الرسول صلى الله عليه
+
+335
+00:38:37,590 --> 00:38:46,510
+وسلم لم يترك الأمر مجملا كي نفسره كيف بل بيانه
+
+336
+00:38:46,510 --> 00:38:51,690
+عندما قال فاقدروا له ثلاثين ليمنع أي احتمال
+
+337
+00:38:51,690 --> 00:38:56,050
+للحسابات الفلكية
+
+338
+00:38:56,630 --> 00:39:01,470
+وردوا على استدلال الفريق المجيز بأن بعض العلماء
+
+339
+00:39:01,470 --> 00:39:07,190
+القدامى يعني يعتمدوا الحساب الفلكي أو جوزوا بأن
+
+340
+00:39:07,190 --> 00:39:11,750
+هذا يعني هذه الآراء التي تبناها بعض العلماء هي
+
+341
+00:39:11,750 --> 00:39:22,270
+تعتبر من قبيل الآراء الشاذة التي لا يعتمد عليها
+
+342
+00:39:23,610 --> 00:39:30,350
+وكذلك بأن
+
+343
+00:39:30,350 --> 00:39:36,150
+مسألة الرؤية مسألة يسيرة على الجميع ومسألة
+
+344
+00:39:36,150 --> 00:39:44,230
+الحسابات الفلكية لا يستطيعها كل المجتمعات فإذا
+
+345
+00:39:44,230 --> 00:39:49,850
+أوجبناها أو فرضناها فإنها 
+
+346
+00:39:49,850 --> 00:39:56,190
+قد تسبب حرجا ناهيك عن شيء مهم أن هؤلاء الذين يقولون
+
+347
+00:39:56,190 --> 00:40:03,610
+بالرؤية بأن الحسابات الفلكية تثبت بها أوائل الشهور
+
+348
+00:40:03,610 --> 00:40:09,310
+بأنهم مختلفون فيما بينهم هؤلاء وهذا شيء آخر يستفيد
+
+349
+00:40:09,310 --> 00:40:14,890
+منه القائلون بالجواز أو بالمنع أصحاب الذين يقولون
+
+350
+00:40:14,890 --> 00:40:19,410
+باعتماد الحسابات الفلكية في إثبات أوائل الشهور
+
+351
+00:40:19,410 --> 00:40:24,890
+مختلفون فيما بينهم هل يكون الاعتماد عند ولادة
+
+352
+00:40:24,890 --> 00:40:33,070
+القمر أو عند إمكانية ظهوره بما يدلل على أن مسألة
+
+353
+00:40:33,070 --> 00:40:38,190
+حتى وإن اعتمدنا الحسابات الفلكية فإنها لا تحقق
+
+354
+00:40:38,190 --> 00:40:45,130
+المراد من حسم الأمر والاتفاق عليه ويبقى الخلاف
+
+355
+00:40:45,130 --> 00:40:49,550
+قائما وإذا كان الأمر كذلك فلنبقى على الأصل ولا
+
+356
+00:40:49,550 --> 00:40:55,750
+نزيد الأمر تشعبا ونبقى على اعتماد الرؤية
+
+357
+00:40:57,350 --> 00:41:04,590
+ولكن المجيزون
+
+358
+00:41:04,590 --> 00:41:10,010
+لم يسكتوا للمانعين وهم أيضا في المقابل ناقشوا
+
+359
+00:41:10,010 --> 00:41:16,490
+أدلتهم فهم يعني بعد أن استدلوا بمجموعة من الأدلة
+
+360
+00:41:16,490 --> 00:41:22,890
+التي ذكرناها ردوا على أدلة أو ناقشوا أدلة المجيزين
+
+361
+00:41:24,840 --> 00:41:32,200
+وقالوا يعني أنه ليس معنى أن يقول النبي صلى الله
+
+362
+00:41:32,200 --> 00:41:38,120
+عليه وسلم صموا لرؤيته أنه يخصصه الرؤية دون غيرها
+
+363
+00:41:38,120 --> 00:41:42,180
+وليس معنى أن يقول الله عز وجل يسألونك عن الأهل
+
+364
+00:41:42,180 --> 00:41:51,640
+لأقول هي موقيت للناس والحج أنه يمنع غيرها خاصة إذا
+
+365
+00:41:51,640 --> 00:42:01,900
+وجدت وسائل دقيقة ووسائل تدلل بوضوح وبسهولة على ذلك
+
+366
+00:42:01,900 --> 00:42:09,080
+فهي هذه الرؤية هي الوسيلة التي كانت معروفة في ذلك
+
+367
+00:42:09,080 --> 00:42:14,000
+الوقت صحيح لكن لا يدل بحالة أن الأحوال على أنها هي
+
+368
+00:42:14,000 --> 00:42:21,730
+الوسيلة الوحيدة وكل ما وجد وسيلة تعيننا على معرفة
+
+369
+00:42:21,730 --> 00:42:27,310
+أدق فلما لا نعمل بها خاصة أن شريعتنا شريعة تواكب
+
+370
+00:42:27,310 --> 00:42:35,810
+التطور وتأخذ بالعلوم ولا تمانع من الأخذ بأسباب
+
+371
+00:42:35,810 --> 00:42:40,030
+العلم والحضارة
+
+372
+00:42:44,190 --> 00:42:50,910
+كذلك من المناقشات أو من الردود والمناقشات لأدلة
+
+373
+00:42:50,910 --> 00:42:59,430
+القائلين بالمنع اللي ذكرها المجيزون
+
+374
+00:43:01,370 --> 00:43:09,670
+بأن الحديث نحن أمة أمية لا نكتب ولا نحسب هذا
+
+375
+00:43:09,670 --> 00:43:13,970
+الحديث كان محل خلاف بين القائلين بالجواز و
+
+376
+00:43:13,970 --> 00:43:22,970
+القائلين بالمنع بالجواز القائلون بالجواز حمل
+
+401
+00:46:03,380 --> 00:46:09,180
+جائزة ومعتمدة حتى في نصوص القرآن وعندما يقول النبي
+
+402
+00:46:09,180 --> 00:46:13,220
+صلى الله عليه وسلم فاقدروا أي فاحسبوا وربما ولم 
+
+403
+00:46:13,220 --> 00:46:17,100
+لا يكون فاقدروا له ثلاثين هذا التفسير هو أحد
+
+404
+00:46:17,100 --> 00:46:26,820
+التفسيرات وفي حالة إمكانية الحساب يعتمد الحساب إذا 
+
+405
+00:46:26,820 --> 00:46:31,360
+هذه بعض المناقشات الواردة هنا وهناك في مسألة
+
+406
+00:46:31,360 --> 00:46:39,660
+الحساب الفلكي لكن حقيقة يعني في نهاية هذه المسألة
+
+407
+00:46:39,660 --> 00:46:49,480
+أود أن أقول أن لكل فريق وجهة نظره المقبولة فيما 
+
+408
+00:46:49,480 --> 00:46:56,280
+قال ولعل الرأي الراجح هو الجمع بين الرأيين وهو رأي
+
+409
+00:46:56,280 --> 00:47:07,050
+الشيخ القرطاوي حفظه الله الذي يقضي بأن الأصل في
+
+410
+00:47:07,050 --> 00:47:13,270
+ذلك الأصل في اعتماد أوائل الشهور هو الرؤية لكن لا 
+
+411
+00:47:13,270 --> 00:47:20,570
+مانع من أن نستأنس بالحسابات الفلكية خاصة في
+
+412
+00:47:20,570 --> 00:47:26,050
+النفي لا في الإثبات في النفي لا في الإثبات في
+
+413
+00:47:26,050 --> 00:47:34,720
+الإثبات نعتمد الرؤية إلى ما تبين أن الحسابات
+
+414
+00:47:34,720 --> 00:47:44,420
+الفلكية تقضي بعدم إمكانية ظهور القمر في هذا الوقت
+
+415
+00:47:45,190 --> 00:47:51,590
+ثم يأتي بعد ذلك شخص يقول شاهدته الهلال أو شاهدته
+
+416
+00:47:51,590 --> 00:47:58,490
+ظهور الهلال مع أن نتائج الحسابات الفلكية تمنع 
+
+417
+00:47:58,490 --> 00:48:03,830
+ذلك بتة ففي هذه الحالة في نفس هذه الحالة فإننا
+
+418
+00:48:03,830 --> 00:48:13,430
+نعتمد الحساب الفلكي في نفي إثبات أول الشهر بالرؤية
+
+419
+00:48:13,430 --> 00:48:19,200
+لأن الرؤية في هذه الحالة تكون مخالفة للحقائق ول
+
+420
+00:48:19,200 --> 00:48:24,380
+الوقائع وديننا وإسلامنا دين الواقعية ودين
+
+421
+00:48:24,380 --> 00:48:30,460
+الحقيقة ومعلوم أن رؤية الشاهد والشاهدين هي رؤية 
+
+422
+00:48:30,460 --> 00:48:35,580
+ظنية وأن هذا لا يقف
+
+423
+00:48:35,580 --> 00:48:41,160
+ولا يثبت أمام النتيجة القطعية التي تأتي بها نتائج
+
+424
+00:48:41,160 --> 00:48:46,900
+الحسابات الفلكية في مثل هذه الأيام التي بلغت فيها
+
+425
+00:48:46,900 --> 00:48:50,700
+الحسابات
+
+426
+00:48:50,700 --> 00:48:57,560
+الفلكية والعلوم الفلكية مبلغًا عظيمًا وجاءت بنتائج
+
+427
+00:48:57,560 --> 00:49:06,080
+دقيقة هذا هو جملة الحديث حول مسألة النتائج، مسألة
+
+428
+00:49:06,080 --> 00:49:15,660
+الحسابات الفلكية ولعل المجامع 
+
+429
+00:49:15,660 --> 00:49:23,620
+الفقهية جاءت على هذا النحو ويعني أتلو هنا قرار مجلس
+
+430
+00:49:23,620 --> 00:49:31,420
+المجمع الفقهي الإسلامي بمكة حول هذه المسألة والذي
+
+431
+00:49:31,420 --> 00:49:35,300
+يقول فيه حكم إثبات أوائل الشهور القمرية بالحساب
+
+432
+00:49:35,300 --> 00:49:40,880
+الفلكي أو حول إثبات أوائل الشهور القمرية بالحساب
+
+433
+00:49:40,880 --> 00:49:48,260
+الفلكي يقول يجب الاعتماد على الرؤية لكنه في نفس 
+
+434
+00:49:48,260 --> 00:49:54,720
+الوقت لا يمنع الاستئناس والاستعانة بالحسابات
+
+435
+00:49:54,720 --> 00:49:59,080
+الفلكية وفي ذلك يقول ويستعان بالحساب الفلكي
+
+436
+00:49:59,080 --> 00:50:04,540
+والمراصد ومراعاة الأحداث النبوية والحقائق العلمية
+
+437
+00:50:05,030 --> 00:50:13,070
+وهذا كله يشعر بضرورة أن نأخذ بالحسابات الفلكية في 
+
+438
+00:50:13,070 --> 00:50:19,290
+خط آخر متوازي مع الرؤية بما يمنع هذا الاختلاف الذي
+
+439
+00:50:19,290 --> 00:50:25,640
+نراه كل يوم نسأل الله سبحانه وتعالى لأمتنا أن تتوحد 
+
+440
+00:50:25,640 --> 00:50:31,600
+وأن تلتزم بشريعة ربنا وبأحكامه وهدي نبينا صلى
+
+441
+00:50:31,600 --> 00:50:40,080
+الله عليه وسلم بارك الله فيكم والسلام عليكم ورحمة
+
+442
+00:50:40,080 --> 00:50:40,840
+الله وبركاته
diff --git a/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/xNyxH6OYlDc_raw.srt b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/xNyxH6OYlDc_raw.srt
new file mode 100644
index 0000000000000000000000000000000000000000..aab832c13608af31a82b8ab51e0e5da4203306aa
--- /dev/null
+++ b/PL9fwy3NUQKwb3sFVl0x0VcZxVug7d_dYU/xNyxH6OYlDc_raw.srt
@@ -0,0 +1,1784 @@
+1
+00:00:21,460 --> 00:00:24,460
+أعوذ بالله من الشيطان الرجيم بسم الله الرحمن
+
+2
+00:00:24,460 --> 00:00:28,940
+الرحيمالحمد لله رب العالمين والصلاة والسلام على
+
+3
+00:00:28,940 --> 00:00:32,840
+أشرف المرسلين محمد صلى الله عليه وسلم وعلى آله
+
+4
+00:00:32,840 --> 00:00:39,470
+وصحبه وسلم تسليما كثيرا وبعداليوم أيها الإخوة
+
+5
+00:00:39,470 --> 00:00:48,370
+والأخوات نبدأ بالحديث عن مسألتنا الأولى من المسائل
+
+6
+00:00:48,370 --> 00:00:53,790
+والقضايا المعاصرة ضمن
+
+7
+00:00:53,790 --> 00:00:58,610
+مساق القضايا الفقهية المعاصرة وقد قلنا بأن هذه
+
+8
+00:00:58,610 --> 00:01:05,450
+المسائل بعضها سيكونفي مجال العبادات وبعضها في مجال
+
+9
+00:01:05,450 --> 00:01:10,010
+المعاملات وبعضها في مجال الأحوال الشخصية وبعضها في
+
+10
+00:01:10,010 --> 00:01:15,570
+مجال الطب وبعضها في مجال السياسة والفني وإلى ما
+
+11
+00:01:15,570 --> 00:01:20,490
+سوى ذلك واليوم
+
+12
+00:01:20,490 --> 00:01:25,270
+إن شاء اللهنبدأ بالمسألة الأولى التي تكون في مجال
+
+13
+00:01:25,270 --> 00:01:33,970
+الإبادات وهي مسألة اعتماد أوائل الشهور القمرية أو
+
+14
+00:01:33,970 --> 00:01:42,600
+العربية كما تسمى بالحسابات الفلكيةهذه هي المسألة
+
+15
+00:01:42,600 --> 00:01:53,900
+كما نعرف و كما نسمع و كما نعايش يختلف فيها العلماء
+
+16
+00:01:53,900 --> 00:01:58,460
+و يختلف فيها الناس في عصرنا اختلافا واسعا تختلف
+
+17
+00:01:58,460 --> 00:02:06,750
+البلدان في ذلكفي كل عام خاصة أن هذا الاختلاف تظهر
+
+18
+00:02:06,750 --> 00:02:13,310
+آثاره في أشهر الصيام أو في شهر الصيام أو أشهر
+
+19
+00:02:13,310 --> 00:02:14,650
+الحجر أحيانا
+
+20
+00:02:22,520 --> 00:02:29,600
+أثر الاختلافات و ذلك الانتمام المسلمي بشهر الصيام
+
+21
+00:02:29,600 --> 00:02:38,260
+و لأنه يرتبط بيه عبادة من العبادات و ربما كان
+
+22
+00:02:38,260 --> 00:02:45,000
+الإسلام ألا و هو ربما انا بصيالكن الحقيقة أن
+
+23
+00:02:45,000 --> 00:02:49,920
+اعتماد أوائل الشهور لا يرتبط فقط بشهر الصيام بل
+
+24
+00:02:49,920 --> 00:02:56,800
+بكل الشهور ولا يرتبط أيضا بعبادة الصيام بل ربما
+
+25
+00:02:56,800 --> 00:03:03,280
+يتعلق به عبادات كثيرة الحج كما قلنا له علاقة كذلك
+
+26
+00:03:03,280 --> 00:03:12,720
+النهو والكفارات والأيمان وإلى ما سوى ذلك حتىأيضا
+
+27
+00:03:12,720 --> 00:03:20,680
+ربما الصلاوات كل ذلك ربما يكون له اتباط قريب او من
+
+28
+00:03:20,680 --> 00:03:27,440
+بعيد باعتماد أوائل الشهور بالحسابات الفلسفية نحن
+
+29
+00:03:27,440 --> 00:03:33,880
+نعرف ان الأصل في اعتماد أوائل الشهور القمرية هو
+
+30
+00:03:33,880 --> 00:03:42,720
+السطوع الهلالفكلما رؤى الهلال في أوائل الشهر
+
+31
+00:03:42,720 --> 00:03:54,740
+العربي بدأ الحساب لهذا الشهر وإن لم يرى طبعا هذا
+
+32
+00:03:54,740 --> 00:03:56,700
+في ليلة التلاتين
+
+33
+00:03:59,100 --> 00:04:08,560
+يسبق يستقبع الهلال فإن رؤي الهلال بدأ شهر جديد وإن
+
+34
+00:04:08,560 --> 00:04:17,060
+لم يرى أكمل المسلمون أدوة الشهر اللذي هم فيه 30
+
+35
+00:04:17,060 --> 00:04:18,980
+يوما وعلى هذا
+
+36
+00:04:26,030 --> 00:04:31,970
+تحط رؤيته تؤثره ل .. ل .. ل .. ل رؤيته فبدال الشهر
+
+37
+00:04:31,970 --> 00:04:37,330
+اللي بيبدأ بالصيانة و بيبدأ بالصيانة طبعا يبدأ
+
+38
+00:04:37,330 --> 00:04:46,050
+بالرؤية و كذلك ينتبي بالرؤية و
+
+39
+00:04:46,050 --> 00:04:53,830
+إذا كان الصيانة .. او إذا كانت .. إذا كان اعتماده
+
+40
+00:04:53,830 --> 00:04:54,750
+أوائل الشهور
+
+41
+00:05:17,100 --> 00:05:19,580
+وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا
+
+42
+00:05:19,580 --> 00:05:21,400
+وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا
+
+43
+00:05:21,400 --> 00:05:21,400
+وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا
+
+44
+00:05:21,400 --> 00:05:21,400
+وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا
+
+45
+00:05:21,400 --> 00:05:21,400
+وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا
+
+46
+00:05:21,400 --> 00:05:21,400
+وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطوا وطاوا
+
+47
+00:05:21,400 --> 00:05:42,420
+وطاوا وطاوا وطااوا وطاااااااااااااااااااااااااااا
+
+48
+00:05:42,650 --> 00:05:47,510
+على الأقل يعني في قطب متوازي مع الرؤية ستظهر
+
+49
+00:05:47,510 --> 00:05:53,050
+الإشتباه في الرؤية عند وجود الغيم عند وجود الشك أو
+
+50
+00:05:53,050 --> 00:06:01,630
+إلى غير ذلك ونحن نرى في سنوات متعددة يغم علينا ال
+
+51
+00:06:01,630 --> 00:06:09,190
+.. ال .. ال .. الهلال و يختلف الناس في .. في ذلك
+
+52
+00:06:10,660 --> 00:06:16,620
+فهل ممكن أن .. أن نحسم الأمر و نعتمد على ما تأتنا
+
+53
+00:06:16,620 --> 00:06:20,460
+الحسابات الفلكية من النتائج و نبدأ شهرنا و بالتالي
+
+54
+00:06:20,460 --> 00:06:26,860
+نبدأ عباداتنا من صيام و غير ذلك من مختلف العبادات
+
+55
+00:06:26,860 --> 00:06:31,360
+أم أنها الرؤية و الرؤية فقط الرؤية أو الإكمال
+
+56
+00:06:31,360 --> 00:06:37,120
+للشهر اللذي صدق هم الذين أيضا يبدأ بهم أو ما يبدأ
+
+57
+00:06:37,120 --> 00:06:39,320
+بهم الشهر
+
+58
+00:06:41,830 --> 00:06:48,910
+هذه المسألة التي سنحاول منقشتها في هذه القاضرة
+
+59
+00:06:48,910 --> 00:06:55,230
+وأقول هنا إن العلماء القدامى تكاد تكون كلمتهم
+
+60
+00:06:55,230 --> 00:07:03,110
+مجنعة على أنه لا اعتبار في منحسابات الفلكية
+
+61
+00:07:03,110 --> 00:07:05,650
+باعتماد أوائل الشهور القديم
+
+62
+00:07:09,150 --> 00:07:19,150
+المعتمدة في ذلك هو الرؤية فقط و
+
+63
+00:07:19,150 --> 00:07:23,710
+ذلك بناء على الحديث و الأيات الواردة و كذلك اللتي
+
+64
+00:07:23,710 --> 00:07:32,550
+ربما نمر عليها يعني بعد قليلولكن يبقى السؤال هنا
+
+65
+00:07:32,550 --> 00:07:39,590
+لماذا كان .. لماذا اتفق الأولماء أو لماذا كانت
+
+66
+00:07:39,590 --> 00:07:46,150
+حكومة الأولماء القدامى متفقة على عدم جواز اعتماد
+
+67
+00:07:46,150 --> 00:07:51,610
+الأوائل الشهور للحسابات الفلسفية مع أنهم اليوم
+
+68
+00:07:51,610 --> 00:07:55,570
+بشكل مختلفين كما سنرى يعني العلماء اللي محدثين
+
+69
+00:07:55,570 --> 00:07:56,590
+مختلفون
+
+70
+00:08:00,110 --> 00:08:07,490
+مخلقون في ذلك ومنهم
+
+71
+00:08:07,490 --> 00:08:11,930
+من يجيز اعتماد اول شهور بالحسابات الفلكية ومنهم من
+
+72
+00:08:11,930 --> 00:08:18,670
+لا يجيز لكن القدامى كما قلت لم يجيزوا وكانوا
+
+73
+00:08:18,670 --> 00:08:24,710
+متفقين على ان المحلقات الفلكية اكثر لأن يستطيعوا
+
+74
+00:08:24,710 --> 00:08:29,370
+ان اتفاقهم هذا يعود الى ثلاثين رئيسيين
+
+75
+00:09:35,450 --> 00:09:35,950
+الله يبكي مني
+
+76
+00:10:08,980 --> 00:10:15,120
+الكهانة والعرابة والتنجين مع العلم أن الإسلام قد
+
+77
+00:10:15,120 --> 00:10:22,680
+شن حملة شعواء ضد السحر والسحرة والكهانة والكهنة
+
+78
+00:10:24,150 --> 00:10:32,430
+والعرافة والعرّافين ولا يقفأ على أحد منا كيف أن
+
+79
+00:10:32,430 --> 00:10:36,050
+النبي صلى الله عليه وسلم اعتبر السحر من السبق
+
+80
+00:10:36,050 --> 00:10:44,290
+الموبقات واعتبر أن من أتى ساحرا أو كاهنا أو عرافا
+
+81
+00:10:44,290 --> 00:10:48,670
+لم تقبل له صلاة أربعين يوما أو إلى غير ذلككل هذا
+
+82
+00:10:48,670 --> 00:10:54,790
+يؤكد على أن الإسلام حارب السحر والكهانوت فلا يُعقل
+
+83
+00:10:54,790 --> 00:11:02,250
+بالتالي أن يعتمد عليه أو على حسابات مختلطة به في
+
+84
+00:11:02,250 --> 00:11:07,190
+اعتماد أوائل الشهور وإثباتها والتي قد يرتبط بها
+
+85
+00:11:07,190 --> 00:11:11,570
+كثير من العذادات لكن
+
+86
+00:11:12,970 --> 00:11:19,210
+بعد أن أصبح ال .. ال .. بعد أن أصبح علم الفلك بعد
+
+87
+00:11:19,210 --> 00:11:27,370
+أن أصبح علم الفلك علما مستقلا بذاته منفصل
+
+88
+00:11:27,370 --> 00:11:35,730
+عن السحر والكهامة و أصبح له قواعد أساسية و أصبح تل
+
+89
+00:11:35,730 --> 00:11:41,230
+الأمم و أصبح تل الأمم تهتموا به اهتماما كبيرا
+
+90
+00:11:41,630 --> 00:11:48,550
+وتتسابق في تطويره
+
+91
+00:11:48,550 --> 00:11:56,450
+وفي الأخذ بزمام أمره انتهت
+
+92
+00:11:56,450 --> 00:12:03,510
+الرابط بينهم وبين الكهانة وبين السحب فانتهى هذا
+
+93
+00:12:03,510 --> 00:12:09,010
+السبب وأما بالنسبة للسبب الثاني وهو النتائج غير
+
+94
+00:12:09,010 --> 00:12:16,250
+دقيقة اليوماختلف الحال أيضا فأصبح علم الفلك يؤتي
+
+95
+00:12:16,250 --> 00:12:25,990
+نتائج تقيقة جدا لا تكاد تخطئونحن نرى أمثلة على ذلك
+
+96
+00:12:25,990 --> 00:12:36,250
+كيف أن علماء الفلك يعلنون عن مواقيت مثلا خصوف
+
+97
+00:12:36,250 --> 00:12:47,130
+القمر وخصوف الشمس بالساعة والدقيقة والثانية ويتأكد
+
+98
+00:12:47,130 --> 00:12:54,990
+لنصحة ذلك بلو يعلنون عن المكان و عن الأجزاء التي
+
+99
+00:12:54,990 --> 00:13:02,410
+يمكن أن يتم بها الخسف و الكسف و إلى غير ذلك و كل
+
+100
+00:13:02,410 --> 00:13:06,510
+ذلك بل يمكن أن يتم الإعلان أو يعرف عن طريق علم
+
+101
+00:13:06,510 --> 00:13:12,890
+الفلك عن كل ذلك لمئات سنوات من السنوات القادمة و
+
+102
+00:13:12,890 --> 00:13:20,530
+من هنافإن اختلاف الحال واختلاف وتغير الأسباب كان
+
+103
+00:13:20,530 --> 00:13:24,090
+مدعوة لإعادة النظر في هذه المسألة بعد أن كان
+
+104
+00:13:24,090 --> 00:13:34,150
+العلماء متفقين تقريبا على عدم جواز اعتماد أوائل
+
+105
+00:13:34,150 --> 00:13:39,290
+الشهور العربي بالحسابات الفلاكية
+
+106
+00:13:43,030 --> 00:13:49,130
+وربما وردت نصوص
+
+107
+00:13:49,130 --> 00:13:55,450
+منسوبة للعلماء القدامى تؤكدوا بما لا يدعم مجانا
+
+108
+00:13:55,450 --> 00:14:02,020
+للشك رفضهم وعلى سبيل الإجماعبالأخذ بهذه المسألة
+
+109
+00:14:02,020 --> 00:14:06,820
+وعلى مختلف المذاهب فمثلا نجد الإمام السرخسي في
+
+110
+00:14:06,820 --> 00:14:13,300
+المذهب الحنفي يقول ومنهم من قال يرجعوا إلى أهل
+
+111
+00:14:13,300 --> 00:14:21,360
+الحساب أي يقصد في أتماد أوائل الشهور القمرية ومنهم
+
+112
+00:14:21,360 --> 00:14:26,160
+من قال يرجعوا إلى أهل الحساب عند الإشتباهثم يقول
+
+113
+00:14:26,160 --> 00:14:31,300
+ماذا وهذا بعيد فإن النبي صلى الله عليه وسلم قال من
+
+114
+00:14:31,300 --> 00:14:36,740
+أتى كاهنا أو عرافا وصدقه بما يقول فقد كفر بما أنزل
+
+115
+00:14:36,740 --> 00:14:41,680
+على محمد وهذا يؤكد يعني السبب الذي من أجله
+
+116
+00:14:41,680 --> 00:14:47,180
+استبعدوا استبعد هؤلاء اعتماد أوائل الشهور
+
+117
+00:14:47,180 --> 00:14:52,140
+بالحسابات الفلكية لاختلاطه بعلم أو لاختلاطه بالسحر
+
+118
+00:14:52,140 --> 00:15:00,150
+والتنجيم والعرافةوكذلك فإن الإمام
+
+119
+00:15:00,150 --> 00:15:05,390
+القرافي المالكي المذهب يقول وقاعدة رؤية الأهلة في
+
+120
+00:15:05,390 --> 00:15:12,970
+الرمضانات لا يجوز إثباتها بالحساب نفى الأمركذلك
+
+121
+00:15:12,970 --> 00:15:20,690
+الإمام النووي من الشفائية يقول في التدليل
+
+122
+00:15:20,690 --> 00:15:27,070
+على عدم اعتماد أوائل الشهور القمرية بالحسابات
+
+123
+00:15:27,070 --> 00:15:32,830
+الفلكية يقول لأن النجوم والحسابة لا مدخلة لها في
+
+124
+00:15:32,830 --> 00:15:35,730
+العبادات
+
+125
+00:15:36,170 --> 00:15:41,550
+ويقول آخر من المذهب الشافعي إن الشارع لم يعتمد
+
+126
+00:15:41,550 --> 00:15:48,470
+الحساب بل ألغاه بالكلية وهذا أيضا ابن مفلح
+
+127
+00:15:48,470 --> 00:15:56,400
+الحنبالي يقول ومن صام بنجوم أو حساب لم يجزئهوإن
+
+128
+00:15:56,400 --> 00:16:02,540
+أصاب ولا يُحكم بطلوع الهلال ديهم ولو كثرت إصابتهم
+
+129
+00:16:02,540 --> 00:16:07,220
+هذا الكلام أو هذه النصوص التي ذكرت وتلقت وتلوت
+
+130
+00:16:07,220 --> 00:16:14,020
+تدلل على أن العلماء القدامى يعني متفقين تقريبا على
+
+131
+00:16:14,020 --> 00:16:20,500
+عدم جواز اعتماد أوائل الشهور القمرية بالحسابات
+
+132
+00:16:20,500 --> 00:16:27,530
+الفلكية لكن كمان قلت لكن عندما تغيرتالدوائي
+
+133
+00:16:27,530 --> 00:16:31,970
+والعلال التي من أجلها كان هذا الاتفاق والتي تمحورت
+
+134
+00:16:31,970 --> 00:16:37,110
+كما قلت في الاختلاط
+
+135
+00:16:37,110 --> 00:16:43,530
+اختلاط الحساب الفلكي والشعوذة وكذلك عدم إعطاءه
+
+136
+00:16:43,530 --> 00:16:47,210
+للنتائج الدقيقة هذا كله تغير وأصبح الحسابات
+
+137
+00:16:47,210 --> 00:16:50,090
+الفلكية أصبحت وضعوا نتائج دقيقة وأصبحت ألمًا
+
+138
+00:16:50,090 --> 00:16:58,670
+مستقلًا ومنفصلًا فصالًا تامًاعن السحر
+
+139
+00:16:58,670 --> 00:17:03,670
+والشعوة ده كان لابد بالطبع من إعادة النظر وهذا ما
+
+140
+00:17:03,670 --> 00:17:12,870
+حدث بالفعل بالنسبة للعلماء المحدثينوعندما عاد
+
+141
+00:17:12,870 --> 00:17:19,930
+العلماء المحدثين النظر والاجتهاد في هذه المسألة في
+
+142
+00:17:19,930 --> 00:17:28,900
+هذا العصر اختلفوا اختلفوا على فريقين فمنهم منظل
+
+143
+00:17:28,900 --> 00:17:32,300
+على ما كان عليه العلماء القدامى من عدم جواز
+
+144
+00:17:32,300 --> 00:17:38,540
+اختلاف، عدم جواز اعتماد الأوائل الشهور القمرية
+
+145
+00:17:38,540 --> 00:17:46,260
+بالحسابات الفلكية ومنهم من خالف ذلك، من خالف وقال
+
+146
+00:17:46,630 --> 00:17:53,490
+بل يجوز اعتماد أوائل الشهور القمرية بالحسابات
+
+147
+00:17:53,490 --> 00:17:59,330
+الفلكية يعني بعد أن تغيرت الأسباب والدواعي التي من
+
+148
+00:17:59,330 --> 00:18:05,450
+أجلها كان الإجماع السابق أو الرفض لهذا الاعتماد
+
+149
+00:18:05,450 --> 00:18:13,690
+عند العلماء القدامى ويبقى السؤال إذا كانت الدواعي
+
+150
+00:18:13,690 --> 00:18:19,740
+قد تغيرتفلماذا نجد اختلافا بين العلماء؟ لماذا
+
+151
+00:18:19,740 --> 00:18:23,620
+وجدنا فريق ولعله الفريق الأكبر، فريق الجمهور، ضال
+
+152
+00:18:23,620 --> 00:18:29,700
+على ما كان عليه العلماء القدامى من عدم جواز اعتماد
+
+153
+00:18:29,700 --> 00:18:33,560
+أوائل الشهور أو عدم قبول على الأقل اعتماد أوائل
+
+154
+00:18:33,560 --> 00:18:38,300
+الشهور القمرية بالحسابات الفلكية رغم تغيير
+
+155
+00:18:38,300 --> 00:18:43,130
+الدواعي؟هذا يدل على أن هناك أسباب أخرى وهذه هي
+
+156
+00:18:43,130 --> 00:18:48,450
+الحقيقة هناك أسباب أخرى أو أدلة أخرى جعتهم إلى ال
+
+157
+00:18:48,450 --> 00:18:54,370
+.. ال .. ال .. التمسك بهذه الرأي والتمسك بالرؤية
+
+158
+00:18:54,370 --> 00:19:02,130
+وعدم اعتبار واعتماد الحساب الفلكي لكن بالنسبة
+
+159
+00:19:02,130 --> 00:19:08,780
+للفريق الآخرلدى ايضا اعتمد على ادلة اخرى تعالوا
+
+160
+00:19:08,780 --> 00:19:15,120
+بنا نرى ماهي وجهة نظر كل فريق وماهي الأدلة التي
+
+161
+00:19:15,120 --> 00:19:23,460
+اعتمد عليها الفريقة اما الفريق الاول وهم جمهور
+
+162
+00:19:23,460 --> 00:19:30,560
+العلماء المعاصر أو اكثر المعاصرين من العلماءوالذين
+
+163
+00:19:30,560 --> 00:19:38,360
+قالوا لعدم جواز اعتماد الحساب الفلكي متابعين في
+
+164
+00:19:38,360 --> 00:19:45,260
+ذلك للعلماء القدامى الذين كما قلت وقرروا دائما
+
+165
+00:19:45,260 --> 00:19:49,780
+اتفقوا او يكاد تكون كلمتهم بحل اتفاق على منع
+
+166
+00:19:49,780 --> 00:19:55,380
+اعتماد الحساب الفلكي بمنع اعتماد أوائل الشهور
+
+167
+00:19:55,380 --> 00:20:03,970
+بالحساب الفلكيهؤلاء يعني يمثلون رأي الجمهور من
+
+168
+00:20:03,970 --> 00:20:12,110
+المعاصرين واستدلوا بأدلة متعددة جماعة هذه الأدلة
+
+169
+00:20:12,110 --> 00:20:21,150
+يعود إلى أن هناك أدلة يفهم منها الأمر بالأخذ برؤية
+
+170
+00:20:21,150 --> 00:20:28,820
+الهلاللاعتماد أوائل الشهور وهناك أذلة تمنع الأخذ
+
+171
+00:20:28,820 --> 00:20:35,000
+بغير الرؤية أو تمنع الأخذ بالحساب هذا جمع ما
+
+172
+00:20:35,000 --> 00:20:40,300
+اعتمدوا عليه يعني بمعنى آخر حتى لو أن الحسابات
+
+173
+00:20:40,300 --> 00:20:47,760
+أصبحت تؤتيبنتائج دقيقة وحتى لو أنها استقلت وانفصلت
+
+174
+00:20:47,760 --> 00:20:52,120
+عن السحر والشعوذة لكن يبقى الأساس الذي لابد أن
+
+175
+00:20:52,120 --> 00:20:56,340
+نعتمد عليه والأساس الذي أمرنا به في نصوص الشرع
+
+176
+00:20:56,340 --> 00:21:03,980
+الحكيم هو الرؤية والرؤية فقطو هذه النصوص تفيد
+
+177
+00:21:03,980 --> 00:21:08,640
+بطريقنا أو بآخر بالأمر من الأخذ بها و المنأ من
+
+178
+00:21:08,640 --> 00:21:17,200
+الأخذ بغيرها فلو
+
+179
+00:21:17,200 --> 00:21:21,020
+نظرنا مثلا إلى بعض الأدلة الواردة في كتاب ربنا
+
+180
+00:21:21,020 --> 00:21:25,900
+سبحانه وتعالى عندما يقول يسألونك عن الأهلة قل هي
+
+181
+00:21:25,900 --> 00:21:33,770
+مواقيت للناس والحجوكأن هؤلاء العلماء يريدون أو
+
+182
+00:21:33,770 --> 00:21:40,450
+يستدلون بهذه الآية ليقولوا أن هذه الآية تدل على
+
+183
+00:21:40,450 --> 00:21:48,980
+وجوبأو على الأمر بالأخذ بالحساب الأمر بالأخذ
+
+184
+00:21:48,980 --> 00:21:54,900
+بالرؤية وهي تمنع أيضا في نفس الوقت من الأخذ بغيرها
+
+185
+00:21:54,900 --> 00:22:01,900
+من الوسائل كالحساب وغيره بدليل التخصيص الوارد في
+
+186
+00:22:01,900 --> 00:22:07,630
+كلمة هي اسألونك عن الأهلة قلهي .. هي لا غيرها
+
+187
+00:22:07,630 --> 00:22:11,390
+وكأنها تشتمل هذه الآية وكأن الآية هذه تشتمل على
+
+188
+00:22:11,390 --> 00:22:17,530
+أمر ونهي أمر بالأخذ بالرؤية
+
+189
+00:22:17,530 --> 00:22:23,550
+ونهي عن غيرها وكذلك في قوله تعالى هو الذي جعل
+
+190
+00:22:23,550 --> 00:22:28,990
+الشمس ضياء والقمر نورا وقدره منازلة لتعلموا عدد
+
+191
+00:22:28,990 --> 00:22:35,760
+السنين والحساب نفس الشمس .. نفس ال ..الأمر فإنها
+
+192
+00:22:35,760 --> 00:22:46,660
+تدلل على اعتماد الرؤية في اثبات
+
+193
+00:22:46,660 --> 00:22:52,720
+أوائل الشهور وأنها
+
+194
+00:22:52,720 --> 00:23:01,460
+هي الأساس وأن ما سواها يعني غير مقمول وغير
+
+195
+00:23:01,460 --> 00:23:09,060
+جاهزوأما من السنة فالسنة هناك حديث متعددة ومشهورة
+
+196
+00:23:09,060 --> 00:23:16,200
+كلها يعني تدل بوضوح وبصراحة على أن أوائل الشهور
+
+197
+00:23:16,200 --> 00:23:20,500
+انما تثبت بالرؤية ومن ذلك حديثه صلى الله عليه وسلم
+
+198
+00:23:20,500 --> 00:23:26,300
+الذي يقول فيه صوم لرؤيتهلرؤيته و أفطره لرؤيته و
+
+199
+00:23:26,300 --> 00:23:29,980
+معلوم أن الصيام يبدأ من أول الشهر و كأنه يريد أن
+
+200
+00:23:29,980 --> 00:23:38,660
+يقول أن أوائل الشهور تثبت بالرؤية لأن الصيام يكون
+
+201
+00:23:38,660 --> 00:23:41,840
+من أول الشهر
+
+202
+00:23:42,460 --> 00:23:48,800
+والذي يؤكد هذه الرؤية أيضًا أو الذي يؤكد هذا الرأي
+
+203
+00:23:48,800 --> 00:23:54,300
+وهذه النظرة لأصحاب هذا القول أن نبي صلى الله عليه
+
+204
+00:23:54,300 --> 00:24:01,280
+وسلم في هذا الحديث وفي غيره ربما قال فإن غم عليكم
+
+205
+00:24:01,280 --> 00:24:07,980
+فاتموا ثلاثين يوما لم
+
+206
+00:24:07,980 --> 00:24:13,660
+يقول فإن غم عليكم فاعتمدوا الحسابولكن حتى في حالة
+
+207
+00:24:13,660 --> 00:24:19,860
+الاشتباه وفي حالة أن يغم علينا ونشق فيه فإننا نكمل
+
+208
+00:24:19,860 --> 00:24:26,940
+الشهر ولا نعتمد على أي شيء آخر ولو كان الحساب
+
+209
+00:24:26,940 --> 00:24:31,760
+لهؤلاء أن يقولوا ولو كان حسابه معتمدا أو جائزا
+
+210
+00:24:31,760 --> 00:24:36,000
+لقال النبي صلى الله عليه وسلم في ذلك فانغم عليكم
+
+211
+00:24:36,000 --> 00:24:42,200
+فاعتمدوا الحساب ووضع قيداإذا كان حسابه دقيقة، إذا
+
+212
+00:24:42,200 --> 00:24:49,100
+كنت مقمئنين إلى حساباتكم وتوصلكم إلى نتائج دقيقة،
+
+213
+00:24:49,100 --> 00:24:54,980
+ولكنه لم يقول ذلك في تأكيد على أن الرؤية هي التي
+
+214
+00:24:54,980 --> 00:25:04,920
+تعتمد في احتساب أوائل الشهور واعتمادهاوالحديث بهذا
+
+215
+00:25:04,920 --> 00:25:09,700
+المعنى كثير الرسول صلى الله عليه وسلم يقول إذا
+
+216
+00:25:09,700 --> 00:25:15,620
+رأيتمه فصوموا وإذا رأيتمه فافطروا فإن غم عليكم
+
+217
+00:25:15,620 --> 00:25:23,950
+فاقدروا واقدروا هنا وإن كانتتحتمل الحساب، لكنهم
+
+218
+00:25:23,950 --> 00:25:29,810
+قالوا أن هذا مفسر لقوله صلى الله عليه وسلم في
+
+219
+00:25:29,810 --> 00:25:35,710
+رواية أخرى فاقدروا له ثلاثين أي احسبوا ثلاثين
+
+220
+00:25:35,710 --> 00:25:41,110
+يوما، فالحساب ليس على إطلاقي، ولكن حساب الشهر نفسه
+
+221
+00:25:41,110 --> 00:25:46,850
+وليس حساب الفلكتر أشاهدوا في كل ذلك أن النصوص
+
+222
+00:25:46,850 --> 00:25:58,990
+والأحاديث على رأي هذا الفريقلم تشر إلى الاستعانة
+
+223
+00:25:58,990 --> 00:26:05,790
+بأي وسيلة أخرى من وسائل إثبات أوائل الشهور
+
+224
+00:26:05,790 --> 00:26:08,810
+باستثناء الرؤية
+
+225
+00:26:10,080 --> 00:26:14,740
+لو كانت الاستعانة والإثبات لأوائل الشهور بغير هذا
+
+226
+00:26:14,740 --> 00:26:22,320
+الطريق جائز لأشارة إليه يعني صراحة أو تلميح على
+
+227
+00:26:22,320 --> 00:26:23,840
+الأقل
+
+228
+00:26:27,160 --> 00:26:32,940
+و كذلك الحال يمكن أن يستذل هؤلاء بقوله صلى الله
+
+229
+00:26:32,940 --> 00:26:38,220
+عليه وسلم إنه من يعش منكم فسيجدوا اختلافا كثيرا
+
+230
+00:26:38,220 --> 00:26:42,420
+فعليكم بسنة وسنة الخلفاء الراشدين المهديين من بعدي
+
+231
+00:26:42,420 --> 00:26:48,440
+تمسكوا بها وعضوا عليها بالنواجذ وإياكم ومحدثات
+
+232
+00:26:48,440 --> 00:26:54,790
+الأمور فإن كل بدعة ضلالة يعني أيضا الحديثالذي
+
+233
+00:26:54,790 --> 00:26:59,910
+يرويه أبو داود يشير
+
+234
+00:26:59,910 --> 00:27:08,450
+إلى أنه في حالة الاختلاف في المسائل التي ربما تحدث
+
+235
+00:27:08,450 --> 00:27:15,090
+بين العلماء الأصل في الفصل والحكم فيها الرجوع إلى
+
+236
+00:27:15,090 --> 00:27:23,800
+السنةورجوع إلى السنة كما رأينا نتأكد من أن وسيلة
+
+237
+00:27:23,800 --> 00:27:32,740
+الإثبات هي الرؤية و الرؤية فقط ثم إن هذا الرأي
+
+238
+00:27:32,740 --> 00:27:37,400
+أيضا الذي يقول به هذا الفريق من العلماء المعاصرين
+
+239
+00:27:37,400 --> 00:27:42,880
+هو رأي العلماء القدامى وأستطيع أن أقول أن العلماء
+
+240
+00:27:42,880 --> 00:27:51,540
+القدامى عندما قالوابمنع اعتماد الحسابات الفلكية
+
+241
+00:27:51,540 --> 00:28:00,340
+كان الحساب الفلكي معروفا ومع ذلك حتى وإن كان
+
+242
+00:28:00,340 --> 00:28:08,600
+ينتجوا نتائج عن غير دقيقة ومع ذلك فإنهم كانوا
+
+243
+00:28:08,600 --> 00:28:09,900
+يتشددوا
+
+244
+00:28:12,730 --> 00:28:22,190
+بعدم الأخذ به ويمنعونه تماما يمكن أن يقال أيضا
+
+245
+00:28:22,190 --> 00:28:27,810
+أنهم استدلوا بأن ذلك قد يكون أتماد الحسابالفلكي في
+
+246
+00:28:27,810 --> 00:28:32,590
+إثبات أوائل الشهور قد يكون فيه نوع مشقة ونحن نعلم
+
+247
+00:28:32,590 --> 00:28:37,270
+أن ديننا دين اليوسف والله عز وجل ما جعل علينا فيه
+
+248
+00:28:37,270 --> 00:28:42,870
+الدين من حاجة ربما هذه مجمل الأدلة اللي تستدل بها
+
+249
+00:28:42,870 --> 00:28:44,110
+القائلون
+
+250
+00:28:49,210 --> 00:28:55,330
+بأن أوائل الشهور لا تثبت بالحسابات الفلكية لكن
+
+251
+00:28:55,330 --> 00:29:07,050
+فريقًا آخر له رأي آخرفريق اخر من العلماء خالفوا
+
+252
+00:29:07,050 --> 00:29:13,570
+هذا الرأي و قالوا لا بل ان اعتماد اوائل الشهور
+
+253
+00:29:13,570 --> 00:29:19,110
+يمكن ان يتم بالحسابات الفلكية بل انهميعني لم
+
+254
+00:29:19,110 --> 00:29:24,250
+يقولوا بالجواز فقط بل إنهم استهجنوا واستغربوا من
+
+255
+00:29:24,250 --> 00:29:32,530
+أولئك الذين يمنعون أو من الفريق الذي يمنع واعتبروا
+
+256
+00:29:32,530 --> 00:29:41,190
+رأيهم رأي رأيا بعيدا كل البعد عن الصواب والسداد
+
+257
+00:29:41,190 --> 00:29:48,110
+وأنهم من غير المعقولأن نترك الأخذ بالحساب الفلكي
+
+258
+00:29:48,110 --> 00:29:55,370
+في عصر وفي زمان يعني أصبحت أدنى وأقل منجزات
+
+259
+00:29:55,370 --> 00:29:59,290
+الحسابات الفلكية معرفة أوائل الشهور ومعرفة منازل
+
+260
+00:29:59,290 --> 00:30:04,190
+القمر ومتى يظهر ومتى يمكن أن يرى وإلى غير ذات في
+
+261
+00:30:04,190 --> 00:30:13,610
+الوقت الذي يصل العلماء في هذا العصر إلىإلى نتائج
+
+262
+00:30:13,610 --> 00:30:18,870
+كثيرة جدا و كبيرة جدا و دقيقة جدا في مختلف جوانب
+
+263
+00:30:18,870 --> 00:30:26,310
+العلم الفلكي ثم
+
+264
+00:30:26,310 --> 00:30:31,790
+هذا في الجملة يعني ثم إنهم إضافة إلى ذلك قالوا
+
+265
+00:30:31,790 --> 00:30:39,510
+بأننا إنما نقول بذلك ولدينا من الأدلة التي تؤكد
+
+266
+00:30:39,510 --> 00:30:49,730
+على ما نقولوترد على أراء هؤلاء القائلين بالمنع فإن
+
+267
+00:30:49,730 --> 00:30:56,920
+الأحاديث النبوية في هذا الشأنوالتي استدل بها
+
+268
+00:30:56,920 --> 00:31:02,300
+القائلون بالمنع نستطيع أن نقول أن هذه الأحاديث
+
+269
+00:31:02,300 --> 00:31:11,460
+نفسها يمكن بنظرة دقيقة عميقة أن نستدل بها على جواز
+
+270
+00:31:11,460 --> 00:31:18,580
+الأخذ بالحسابات الفلكية في اعتماد أوائل الشهور
+
+271
+00:31:18,580 --> 00:31:20,620
+العربية
+
+272
+00:31:24,240 --> 00:31:30,820
+ذلك أن حديثه صلى الله عليه وسلم الذي يقول فيه
+
+273
+00:31:30,820 --> 00:31:35,900
+صوموا لرؤيته وعفطروا لرؤيته إنما هو جزء من حديث
+
+274
+00:31:35,900 --> 00:31:43,200
+طويل قال فيه النبي صلى الله عليه وسلم نحن أمة أمية
+
+275
+00:31:43,200 --> 00:31:45,080
+لا نكتب ولا نحسب
+
+276
+00:31:49,850 --> 00:31:56,950
+وبعد ذلك قال صوموا لرؤيته وعفطروا لرؤيته بما يدلل
+
+277
+00:31:56,950 --> 00:32:02,570
+على أن اعتماد الرؤية كما قالوا اعتماد الرؤية انما
+
+278
+00:32:02,570 --> 00:32:08,310
+كان مرتبط بكون هذه الأمة أمة أمية لا تعرف الحساب
+
+279
+00:32:08,310 --> 00:32:13,870
+ولا تعرف الكتاب في إشارة إلى أن العلة التي من
+
+280
+00:32:13,870 --> 00:32:22,560
+أجلها اعتمدت الرؤيةهي الأممية وبالتالي في حالة عدم
+
+281
+00:32:22,560 --> 00:32:28,860
+موجود الأممية وفي حالة التعلق العلمي والتطور فإنه
+
+282
+00:32:28,860 --> 00:32:35,920
+لا بأس بالأخذ بالحساب الفلفي هذا ما يعني فاهموه من
+
+283
+00:32:35,920 --> 00:32:42,500
+هذا الحديث أو من مثل هذه الحديث يعني بالمفهومإنه
+
+284
+00:32:42,500 --> 00:32:45,940
+كأن الرسول صلى الله عليه وسلم عندما قال صوموا
+
+285
+00:32:45,940 --> 00:32:50,740
+لرؤيته وأفطروا لرؤيته إنما جاء تعلينا لكون هذه
+
+286
+00:32:50,740 --> 00:32:54,540
+الأمة أمية لا تعرف الحساب وكأنه يريد أن يقول
+
+287
+00:32:54,540 --> 00:33:00,680
+وبالتالي فإذا جاءت أيام أو جاء زمان يعرف فيه أو
+
+288
+00:33:00,680 --> 00:33:05,220
+عرف فيه المسلمون الحساب فلا بأس أن يعتمدوا الحسابة
+
+289
+00:33:05,220 --> 00:33:09,160
+بإثبات أوائل الشهور
+
+290
+00:33:11,400 --> 00:33:15,900
+يعني هذا يا واحد ثانيا من الأدلال قالوا وكأن بهم
+
+291
+00:33:15,900 --> 00:33:18,560
+نظروا إلى الواقع استدلال من الواقع الواقع اللي
+
+292
+00:33:18,560 --> 00:33:24,260
+اللي نعيش أننا نجد اختلافا واسعا بين الدول
+
+293
+00:33:24,260 --> 00:33:28,000
+الإسلامية اليوم قد يصل إلى ثلاث أيام في بعض الشهور
+
+294
+00:33:28,000 --> 00:33:35,360
+خاصة شهر الصيام فمنهم من يصوميعني قبل دولة تصوم
+
+295
+00:33:35,360 --> 00:33:39,860
+قبل دولة بيوم أو بيومين وهذا يحدث اختلافا و لو
+
+296
+00:33:39,860 --> 00:33:44,780
+اعتمدنا كأن بيهم يريدون القول لو اعتمدناالحساب
+
+297
+00:33:44,780 --> 00:33:50,040
+الفلكي لوحدنا الأمة مع العلم أن وحدة الأمة مقصد من
+
+298
+00:33:50,040 --> 00:33:56,460
+مقاصد التشريع العظيمة التي يحرص عليها الإسلام ونصت
+
+299
+00:33:56,460 --> 00:34:01,360
+عليها آيات وأحاديث كثيرة في القرآن الكريم وفي
+
+300
+00:34:01,360 --> 00:34:10,040
+السنة النبوية فالوحدة يعني شيء مهمفي ديننا وفي
+
+301
+00:34:10,040 --> 00:34:16,320
+شريعتنا وإذا كان هذا الأمر يوحدنا ويوحد قامة
+
+302
+00:34:16,320 --> 00:34:22,240
+شعائرنا ونسقنا فلم لا ويعطينا في نفس الوقت نتائج
+
+303
+00:34:22,240 --> 00:34:27,920
+دقيقة وليس فيه نهي منصريه أيضا في الأحاديث فإن
+
+304
+00:34:27,920 --> 00:34:33,980
+الأحاديث تتدله بالمفهوم على جواز ذلك
+
+305
+00:34:36,650 --> 00:34:41,470
+ثم إنهم قالوا بأن بعض العلماء القدامى صحيح مظمهم
+
+306
+00:34:41,470 --> 00:34:51,690
+يعني كانوا على المنع لكن منعهم كان بسبب ما اختلط
+
+307
+00:34:51,690 --> 00:34:55,290
+فيه الحساب وبالتنجيم وبسبب عدم
+
+308
+00:34:58,820 --> 00:35:04,260
+وبسبب عدم النتائج الدقيقة التي يعطيها الحساب
+
+309
+00:35:04,260 --> 00:35:14,920
+الفلكي أما وقد تغيرت كل هذه المعطيات فإننا
+
+310
+00:35:14,920 --> 00:35:19,840
+بقولنا بالجواز حقيقة لا نخالف هؤلاء القدامى ولو
+
+311
+00:35:19,840 --> 00:35:23,220
+عاش هؤلاء العلماء القدامى في عصرنا هذا لقالوا بما
+
+312
+00:35:23,680 --> 00:35:29,100
+بما نقول ناهيك عن أن بعض العلماء القدامى وفي ظل
+
+313
+00:35:29,100 --> 00:35:36,800
+وجود حسابات فلكية غير دقيقة كانوا يطالبون وكانوا
+
+314
+00:35:36,800 --> 00:35:42,580
+يقولون بجواز الحساب الفلكى بجواز اعتماد الحساب
+
+315
+00:35:42,580 --> 00:35:52,240
+الفلكى في أوائل لإثبات أوائلالشهور فلو نظرنا سنجد
+
+316
+00:35:52,240 --> 00:36:00,740
+يعني انه بعض العلماء القدامى يعني من مقولاتهم انهم
+
+317
+00:36:00,740 --> 00:36:06,500
+قالوا يعتبروا الهلال إذا غم بالنجوم
+
+318
+00:36:06,500 --> 00:36:17,760
+يعتبروا الهلالأو يحسب حساب الهلال يحسب ظهوره حسابا
+
+319
+00:36:17,760 --> 00:36:24,300
+إذا قم بالنجوم أو بمعنى آخر بطريقة الحساب
+
+320
+00:36:26,080 --> 00:36:31,080
+ثم إنهم إضافة إلى ذلك قالوا بأن قليات معرفة الحساب
+
+321
+00:36:31,080 --> 00:36:41,200
+اليوم أصبحت مُتطورة ودقيقة و كذلك اعتمدوا في
+
+322
+00:36:41,200 --> 00:36:46,280
+أدلتهم على القياس على مواقيت الصلاوات فإن مواقيت
+
+323
+00:36:46,280 --> 00:36:52,040
+الصلاوات اليوم التي يعتمدها المسلمون في صلاواتهم
+
+324
+00:36:52,040 --> 00:36:58,490
+ويؤقتون بهامواعيد صلواتهم معتمدة على الحسابات
+
+325
+00:36:58,490 --> 00:37:03,670
+الفلكية فإذا كانت الصلاة ومواقيتها تعتمد على
+
+326
+00:37:03,670 --> 00:37:09,050
+الحسابات الفلكية فلم لا نعتمد الصيام مع العلم أن
+
+327
+00:37:09,050 --> 00:37:16,950
+الصلاة رقنها مقدم حتى على الصيامهذه مجموعة الأدلة
+
+328
+00:37:16,950 --> 00:37:22,510
+التي استدلت بها الفريق الثاني ولنا أن نقف يعني
+
+329
+00:37:22,510 --> 00:37:31,090
+وقفة مختصرة في مناقشة أدلة كل فريق لنصل ان شاء
+
+330
+00:37:31,090 --> 00:37:44,040
+الله بعد ذلك إلى الرأي الراجحأما مناقشة المانعين
+
+331
+00:37:44,040 --> 00:37:47,940
+نبدأ بمناقشة المانعين للمجلزين أصحاب الرأي الأول
+
+332
+00:37:47,940 --> 00:37:55,400
+يعني الذين منعوا اعتماد الحساب الفلكي ناقشوا أدلة
+
+333
+00:37:55,400 --> 00:38:00,680
+الرأي الثاني الذين مجلزون
+
+334
+00:38:04,750 --> 00:38:15,590
+بمناقشات متعددة مثلا في الحديث الذي اعتمدوه في
+
+335
+00:38:15,590 --> 00:38:19,990
+قوله صلى الله عليه وسلم فاقدروا وفهموا منه معنى
+
+336
+00:38:19,990 --> 00:38:24,470
+فاحسبوا قالوا يعني ان هذا الحديث
+
+337
+00:38:26,790 --> 00:38:32,490
+مفسر في قوله في روايات أخرى بقوله صلى الله عليه
+
+338
+00:38:32,490 --> 00:38:37,590
+وسلم فقدروا له ثلاثين أي أن الرسول صلى الله عليه
+
+339
+00:38:37,590 --> 00:38:46,510
+وسلم لم يترك الأمر مجملا كي نفسره كيفبل بيانه
+
+340
+00:38:46,510 --> 00:38:51,690
+عندما قال فاقدروا له ثلاثين ليمنع اي احتمال
+
+341
+00:38:51,690 --> 00:38:56,050
+للحسابات الفلكية
+
+342
+00:38:56,630 --> 00:39:01,470
+وردوا على استدلال الفريق المجيز بأن بعض العلماء
+
+343
+00:39:01,470 --> 00:39:07,190
+القدامى يعني يعتمدوا الحساب الفلكي أو جوزوا بأن
+
+344
+00:39:07,190 --> 00:39:11,750
+هذا يعني هذه الأراء التي تبناها بعض العلماء هي
+
+345
+00:39:11,750 --> 00:39:22,270
+تعتبر من قبيل الأراء الشاذة التي لا يعتمد عليها
+
+346
+00:39:23,610 --> 00:39:30,350
+و كذلك بأن
+
+347
+00:39:30,350 --> 00:39:36,150
+مسألة الرؤية مسألة ميصورة على الجميع و مسألة
+
+348
+00:39:36,150 --> 00:39:44,230
+الحسابات الفلكي لا يستطيعها كل المجتمعات فإذا
+
+349
+00:39:44,230 --> 00:39:49,850
+أوجبناها أو فرضناها فإنها
+
+350
+00:39:49,850 --> 00:39:56,190
+قد تسبب حرجانهيك عن شيء مهم أن هؤلاء الذين يقولون
+
+351
+00:39:56,190 --> 00:40:03,610
+بالرؤية بأن الحسابات الفلكية تثبت بها أوائل الشهور
+
+352
+00:40:03,610 --> 00:40:09,310
+بأنهم مختلفون فيما بينهم هؤلاء وهذا شيء أخر يستفيد
+
+353
+00:40:09,310 --> 00:40:14,890
+منه القائلون بالجواز أو بالمنع آسفالذين يقولون
+
+354
+00:40:14,890 --> 00:40:19,410
+باعتماد الحسابات الفلكية في إثبات أوائل الشهور
+
+355
+00:40:19,410 --> 00:40:24,890
+مختلفون فيما بينهم هل يكون الاعتماد عند ولادة
+
+356
+00:40:24,890 --> 00:40:33,070
+القمر أو عند إمكانية ظهورهبما يدلل على أن مسألة
+
+357
+00:40:33,070 --> 00:40:38,190
+حتى وإن اعتبدنا الحسابات الفلكية فإنها لا تحقق
+
+358
+00:40:38,190 --> 00:40:45,130
+المراد من حسم الأمر والاتفاق عليه ويبقى الخلاف
+
+359
+00:40:45,130 --> 00:40:49,550
+قائما وإذا كان الأمر كذلك فلنبقى على الأصل ولا
+
+360
+00:40:49,550 --> 00:40:55,750
+نزيد الأمر تشعبا ونبقى على اعتماد الرؤية
+
+361
+00:40:57,350 --> 00:41:04,590
+ولكن المجيزين
+
+362
+00:41:04,590 --> 00:41:10,010
+لم يسكتوا للمانعين وهم أيضا في المقابل ناقشوا
+
+363
+00:41:10,010 --> 00:41:16,490
+أدلتهم فهم يعني بعد أن استدلوا بمجموعة من الأدلة
+
+364
+00:41:16,490 --> 00:41:22,890
+التي ذكرناها ردوا على أدلة أو ناقشوا أدلة المجيزين
+
+365
+00:41:24,840 --> 00:41:32,200
+وقالوا يعني أنه ليس معنى أن يقول النبي صلى الله
+
+366
+00:41:32,200 --> 00:41:38,120
+عليه وسلم صمم لرؤيته أنه يخصصه الرؤية دون غيرها
+
+367
+00:41:38,120 --> 00:41:42,180
+وليس معنى أن يقول الله عز وجل يسألونك عن الأهل
+
+368
+00:41:42,180 --> 00:41:51,640
+لأقول هيموقيته للناس والحج أنه يمنع غيرها خاصة إذا
+
+369
+00:41:51,640 --> 00:42:01,900
+وجدت وسائل دقيقة ووسائل تدلوا بوضوح وبسهولةعلى ذلك
+
+370
+00:42:01,900 --> 00:42:09,080
+فهي هذه الرؤية هي الوسيلة التي كانت معروفة في ذلك
+
+371
+00:42:09,080 --> 00:42:14,000
+الوقت صحيح لكن لا يدل بحالة ان الأحوال على انها هي
+
+372
+00:42:14,000 --> 00:42:21,730
+الوسيلة الوحيدة وكل ما وجد وسائلتعيننا على معرفة
+
+373
+00:42:21,730 --> 00:42:27,310
+أدق فلما لا نعمل بها خاصة أن شريعتنا شريعة تواكم
+
+374
+00:42:27,310 --> 00:42:35,810
+التطور وتأخذ بالعلوم ولا تمانع من الأخذ بأسباب
+
+375
+00:42:35,810 --> 00:42:40,030
+العلم والحضارة
+
+376
+00:42:44,190 --> 00:42:50,910
+كذلك من المناقشات أو من الردود والمناقشات لأدلة
+
+377
+00:42:50,910 --> 00:42:59,430
+القائلين بالمنع اللي ذكرها المجيزون
+
+378
+00:43:01,370 --> 00:43:09,670
+بأن الحديث نحن أمة أمية لا نكتب ولا نحسب هذا
+
+379
+00:43:09,670 --> 00:43:13,970
+الحديث كان محل خلاف بين القائلين بالجواز و
+
+380
+00:43:13,970 --> 00:43:22,970
+القائلين بالمنعبالجواز القايلون بالجواز حملوه على
+
+381
+00:43:22,970 --> 00:43:30,650
+يعني أنه خبر على النفي نحن أمة لا تكتب ولا تحسن
+
+382
+00:43:30,650 --> 00:43:34,630
+نحن أمة أمية لا تكتب ولا تحسن على توصيف الحال
+
+383
+00:43:34,630 --> 00:43:43,720
+والواقع بينما حمله بعض المانعين على أنه نهيومن هنا
+
+384
+00:43:43,720 --> 00:43:53,920
+فإن المجيزين اعترضوا على المانعين في حملهم لهذا
+
+385
+00:43:53,920 --> 00:43:58,160
+الحديث على أنه نوع أو شكل من أشكال النهي وقالوا
+
+386
+00:43:58,160 --> 00:44:05,870
+بأنه بل هو نفيو لحالة
+
+387
+00:44:05,870 --> 00:44:12,850
+او لواقع موجود و ليس نهي عن ذلك وهذا مما تمسك به
+
+388
+00:44:12,850 --> 00:44:19,690
+القائلون بالمنع و هو في غير محله كما بين ذلك
+
+389
+00:44:19,690 --> 00:44:26,990
+القائلون بالجواز نعم ثم
+
+390
+00:44:31,490 --> 00:44:36,690
+إن الحساب اليوم قالوا أيضا في ردهم يعني إن انكار
+
+391
+00:44:36,690 --> 00:44:40,470
+الحساب أصبح مسألة غير مقبولة بحالة من الأحوال ..
+
+392
+00:44:40,470 --> 00:44:46,450
+بحالة من الأحوال مسألة انكار الحسابات الفلكي تعتبر
+
+393
+00:44:46,450 --> 00:44:51,070
+مثلة بقى لو أننا أنكرنا الحساب الفلكي في اعتماد
+
+394
+00:44:51,070 --> 00:44:57,680
+أوائل الشهور هذا شيء غير مقبولومنافي للقواعد
+
+395
+00:44:57,680 --> 00:45:03,040
+والأسس التي جاءت بها هذه الشريعة كما قلنا والتي
+
+396
+00:45:03,040 --> 00:45:10,260
+تواكم العلم والتطور ولعل من أهم
+
+397
+00:45:15,140 --> 00:45:21,220
+المناقشات التي وردت في هذا السياق التي ناقشها بيها
+
+398
+00:45:21,220 --> 00:45:29,760
+المجيزون المانعين ان
+
+399
+00:45:30,290 --> 00:45:35,330
+القرآن آيات القرآن نفسها وحديث النبي صلى الله عليه
+
+400
+00:45:35,330 --> 00:45:40,690
+وسلم أشارت إلى أهمية الحساب وأشارت إلى إمكانية
+
+401
+00:45:40,690 --> 00:45:45,110
+اعتماد الحسابات الفلكية في أوائل الشهور عندما يقول
+
+402
+00:45:45,110 --> 00:45:49,990
+ربنا سبحانه وتعالى والشمس والقمر بحسبان وعندما
+
+403
+00:45:49,990 --> 00:45:54,850
+يقولوا والقمر قدرناه منازل وعندما يقول ربنا تعلموا
+
+404
+00:45:54,850 --> 00:46:03,380
+عدد السنين والحسابكل هذه تؤكد على أن الحسابات
+
+405
+00:46:03,380 --> 00:46:09,180
+جائزة ومعتمدة حتى في نصوص القرآن وعندما يقول النبي
+
+406
+00:46:09,180 --> 00:46:13,220
+صلى الله عليه وسلم فاقدروا أي فاحسبوا وربما و لم
+
+407
+00:46:13,220 --> 00:46:17,100
+لا يكون فاقدروا له ثلاثين هذا التفسير هو أحد
+
+408
+00:46:17,100 --> 00:46:26,820
+التفسيرات وفي حالة إمكانية الحساب يعتمد الحسابإذا
+
+409
+00:46:26,820 --> 00:46:31,360
+هذه بعض المناقشات الواردة هنا و هناك في مسألة
+
+410
+00:46:31,360 --> 00:46:39,660
+الحساب الفلكي لكن حقيقة يعني في نهاية هذه المسألة
+
+411
+00:46:39,660 --> 00:46:49,480
+أود أن أقول أن لكل فريق وجهة نظره المقبولة في ما
+
+412
+00:46:49,480 --> 00:46:56,280
+قال ولعل الرأي الراجح هو الجمع بين الرأيينوهو رأي
+
+413
+00:46:56,280 --> 00:47:07,050
+الشيخ القرطاوي حفظاه اللهالذي يقضي بأن الأصل في
+
+414
+00:47:07,050 --> 00:47:13,270
+ذلك الأصل في اعتماد أوائل الشهور هو الرؤية لكن لا
+
+415
+00:47:13,270 --> 00:47:20,570
+مانعة من أن نستأنسى بالحسابات الفلكية خاصة في
+
+416
+00:47:20,570 --> 00:47:26,050
+النفي لا في الإثبات في النفي لا في الإثبات في
+
+417
+00:47:26,050 --> 00:47:34,720
+الإثبات نعتمد الرؤيةإلى ما تبين أن الحسابات
+
+418
+00:47:34,720 --> 00:47:44,420
+الفلكية تقضي بعدم إمكانية ظهور القمر في هذا الوقت
+
+419
+00:47:45,190 --> 00:47:51,590
+ثم يأتي بعد ذلك شخص يقول شاهدته الهلال أو شاهدته
+
+420
+00:47:51,590 --> 00:47:58,490
+ظهور الهلال مع أن النتائج الحسابات الفلكية تمنع
+
+421
+00:47:58,490 --> 00:48:03,830
+ذلك البتة ففي هذه الحالة في نفس هذه الحالةفإننا
+
+422
+00:48:03,830 --> 00:48:13,430
+نعتمد الحساب الفلكي في نفي اثبات أول الشهر بالرؤية
+
+423
+00:48:13,430 --> 00:48:19,200
+لأن الرؤية في هذه الحالة تكون مخالفة للحقائقوليه
+
+424
+00:48:19,200 --> 00:48:24,380
+الوقائع وديننا وإسلامنا دينه الواقعية ودينه
+
+425
+00:48:24,380 --> 00:48:30,460
+الحقيقة ومعلوم أن رؤية الشاهد والشاهدين هي رؤية
+
+426
+00:48:30,460 --> 00:48:35,580
+ظنية وأن هذا لا يقف
+
+427
+00:48:35,580 --> 00:48:41,160
+ولا يثبت أمام النتيجة القطائية التي تأتي بها نتائج
+
+428
+00:48:41,160 --> 00:48:46,900
+الحسابات الفلكية في مثل هذهالأيام التي بلغت فيها
+
+429
+00:48:46,900 --> 00:48:50,700
+الحسابات
+
+430
+00:48:50,700 --> 00:48:57,560
+الفلكية والعلوم الفلكية مبلغا عظيما وجاءت بنتائج
+
+431
+00:48:57,560 --> 00:49:06,080
+دقيقة هذا هو جماعه الحديثحول مسألة النتائج، مسألة
+
+432
+00:49:06,080 --> 00:49:15,660
+الحسابات الفلكية ولعل المجامع
+
+433
+00:49:15,660 --> 00:49:23,620
+الفقه جاءت على هذا النحو ويعني أتلو هنا قرار مجلس
+
+434
+00:49:23,620 --> 00:49:31,420
+المجمع الفقهالاسلامي بمكة حول هذه المثالة والذي
+
+435
+00:49:31,420 --> 00:49:35,300
+يقول فيه حكم إثبات أوائل الشهور القمرية بالحساب
+
+436
+00:49:35,300 --> 00:49:40,880
+الفلكي أو حول إثبات أوائل الشهور القمرية بالحساب
+
+437
+00:49:40,880 --> 00:49:48,260
+الفلكييقول يجب الاعتماد على الرؤية لكنه في نفس
+
+438
+00:49:48,260 --> 00:49:54,720
+الوقت لا يمنع الاستئنات والاستعانة بالحسابات
+
+439
+00:49:54,720 --> 00:49:59,080
+الفلكية وفي ذلك يقول ويستعانوا بالحساب الفلكي
+
+440
+00:49:59,080 --> 00:50:04,540
+والمراصد ومراعاة الأحداث النبوية والحقائق العلمية
+
+441
+00:50:05,030 --> 00:50:13,070
+وهذا كله يشعر بضرورة أن نأخذ بالحسابات الفلكية في
+
+442
+00:50:13,070 --> 00:50:19,290
+خط آخر متوازي مع الرؤية بما يمنع هذا الاختلاف الذي
+
+443
+00:50:19,290 --> 00:50:25,640
+نراه كل يومنسأل الله سبحانه وتعالى لأمتنا أن تتوحد
+
+444
+00:50:25,640 --> 00:50:31,600
+و أن تلتزم بشريعة ربنا و بأحكامه و هدي نبينا صلى
+
+445
+00:50:31,600 --> 00:50:40,080
+الله عليه وسلم بارك الله فيكم والسلام عليكم ورحمة
+
+446
+00:50:40,080 --> 00:50:40,840
+الله وبركاته
+