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===================== Product Identification =====================
Product ID:BLACK JACK PLASTIC CMT WET/DRY
CAGE:33394
CAGE:33394
============= Composition/Information on Ingredients =============
Ingred Name:STODDARD SOLVENT
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 10-30%
OSHA PEL:500 PPM
ACGIH TLV:100 PPM; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CHRONIC: NONE KNOWN. ACUTE: SKIN:
PROLONGED/ REPEATED CONTACT MAY CAUSE IRRITATION. EYES: MAY CAUSE
IRRITATION, BLURRED VISION. INHAL: EXCESSIVE BREATHING OF HIGH
VAPOR CONCENTRATIONS CAN CAUSE NASAL AND RESPIRATORY IRRITATION,
DIZZINESS, NAUSEA, POSSIBLE UNCONSCIOUSNESS AND EVEN ASPHYXIATION.
(SEE EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INGEST: CAN CAUSE GASTROINTESTINAL
IRRITATION, NAUSEA, VOMITING AND DIARRHEA. ASPIRATION OF MATERIAL
INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.
Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG AND SKIN
DISORDERS.
======================= First Aid Measures =======================
First Aid:SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH WITH LARGE
AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. INHAL: REMOVE PERSON FROM
AFFECTED AREA. IF BREATHING IS DIFFICULT ADMINISTER OXYGEN. IF
BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION. INGEST: DO NOT
INDUCE VOMITING. SEEK MD IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:105F,41C
Lower Limits:7%
Upper Limits:0.8%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . WATER MAY CAUSE FROTHING, APPLY CAUTIOUSLY.
Unusual Fire/Explosion Hazard:KEEP AWAY FROM SOURCES OF IGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE SPILL AREA . RECOVER FREE LIQUID. ADD
ABSORBENT TO SPILL AREA. REMOVE SOURCES OF IGNITION. VENTILATE AREA
IF NECESSARY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION.
USE ONLY WITH ADEQUATE VENTILATION. AVOID PROLONGED/REPEATED
CONTACT WITH SKIN.
Other Precautions:KEEP OUT OF THE REACH OF CHILDREN!
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY NEEDED IN WELL VENTILATED AREA. IF
TLV IS EXCEEDED, A NIOSH/MSHA APPROVED BREATHING APPARATUS IS
RECOMMENDED.
Ventilation:AS NECESSARY TO MAINTAIN EXPOSURE BELOW TLV LEVEL.
Other Protective Equipment:AS NECESSARY.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING, LAUNDER BEFORE
REUSE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:300F,149C
Vapor Pres:2 (25C)
Vapor Density:>1
Spec Gravity:1.1
Evaporation Rate & Reference:<1 (BUAC=1)
Solubility in Water:NIL
Appearance and Odor:BLACK PASTE, SOLVENT ODOR.
Percent Volatiles by Volume:10-30
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT, SPARKS, FLAMES.
Hazardous Decomposition Products:CO2 AND CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ACCORDING TO FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:113A145, 7-STAR RUSTIC TONES OIL SEMI- (SUP
CAGE:ACEHA
CAGE:ACEHA
============= Composition/Information on Ingredients =============
Ingred Name:HYDROTREATED LIGHT DISTILLATE; (MINERAL SPIRITS). VP: 2.0
CAS:64742-47-8
Fraction by Wt: 65%
OSHA PEL:500 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
Ingred Name:HYDROTREATED LIGHT DISTILLATE; (MINERAL SPIRITS (14O
FLASH)). VP: 0.5
CAS:64742-47-8
Fraction by Wt: 10%
OSHA PEL:500 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION IS ANESTHETIC. IRRITATION
OF RESPIRATORY TRACT OR NERVOUS SYSTEM DEPRESSION. HEADACHE, DIZZ,
NAUS, CONFUSN, UNCONSCIOUSNESS, OR COMA. SKIN/EYE CONT: PRIMARY
IRRITATION. REPORTS HAVE ASSOCIA TED REPEATED AND PROLONGED
OCCUPATIONALOVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING, KEEP WARM &
QUIET. NOTIFY PHYS. EYES: FLUSH IMMED WITH RUNNING WATER FOR AT
LEAST 15 MIN. SKIN: WASH WITH SOAP AND WATER AND APPLY SKIN CREAM.
NOTIFY PH YS IN ALL CASES. INGEST: CALL MD .
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:105F,41C
Lower Limits:0.9%
Extinguishing Media:FOAM, "ALCOHOL" FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP.
H2O SPRAY MAY BE INEFTIVE. H2O MAY BE USED TO COOL CLSD CONTR TO
PVNT PRESS BUILD-UP & POSS (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. HEAT MAY CAUSE PRESS TO
BUILD UP IN CLSD CONTR, H2O MAY BE USED TO COOL.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DOL STORAGE CATEGORY 2.
Other Precautions:CONTENTS ARE COMBUSTIBLE. KEEP AWAY FROM HEAT/OPEN
FLAME. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP/SPRAY MIST. AVOID CONT
W/SKIN/ EYES. WASH HANDS AFTER USING. KEEP CONTR CLSD WHEN NOT IN
USE. DO NOT TRA NSFER CONTENTS TO OTHER (SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING AND ADMINISTRATIVE CONTROLS OF
AIR CONTAMINANTS ARE NOT POSSIBLE, USE NIOSH/MSHA APPROVED
RESPIRATORY DEVICES FOR PROTECTION AGAINST SPRAY AND VAPORS.
Ventilation:LOCAL EXHAUST PREFERABLE. MECH(GEN) EXHAUST ACCEPTABLE.
SPECIAL VENTILATION REQUIRED TO KEEP BELOW TLV AND PEL.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING, DISCARD
CONTAMINATED SHOES.
Supplemental Safety and Health
MFR TRADE NAME/PART NO :TRANSPARENT STAIN RUSSET. FIRE FIGHT PROC: AUTO
IGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. OTHER PREC:
CONTAINERS FOR STORAGE. DO NOT TAKE INTERNALLY. KEEP OUT OF REAC H
OF CHILDREN. CONSULT NFPA CODE. USE APPROVED BONDING AND GROUNDING
PROCEDURES.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:>308F,>153C
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:82.9
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORSEEABLE.
Stability Condition to Avoid:HIGH TEMPERATURES, OPEN FLAME.
Hazardous Decomposition Products:BY FIRE: CO2 AND CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL REGULATIONS REGARDING POLLUTION.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:651,TRAFFIC PAINT,YELLOW
CAGE:HO292
CAGE:3N081
CAGE:HO292
============= Composition/Information on Ingredients =============
Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN)
CAS:8030-30-6
RTECS #:SE7555000
OSHA PEL:100 PPM
Ingred Name:NAPHTA (PETROLEUM SPIRITS OR BENZIN)
CAS:8030-30-6
RTECS #:VL8047000
OSHA PEL:100 PPM
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
OSHA PEL:0.05 MG/M3;1910.1025
ACGIH TLV:0.15 MG/M3;DUST 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CHROMIUM (VI) OXIDE
CAS:1333-82-0
RTECS #:GB6650000
Fraction by Wt: 2.79%
OSHA PEL:C, 0.1 MG/M3 (CRO3)
ACGIH TLV:0.05 MG/M3(CR); 8990
Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN)
CAS:8030-30-6
RTECS #:SE7555000
OSHA PEL:100 PPM
===================== Hazards Identification =====================
Effects of Overexposure:ACUTE: INHAL-ANESTHETIC. IRRIT OF RESP
TRACT/ACUTE NERVOUS SYS DEPRESSION W/ADVANCING (SEE OTHR PREC
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE BREATHING. CONSULT
FOR 15 MIN.SKIN-WASH W/SOAP & H*2O. IN BOTH CASES,CONSULT PHYS/CALL
EMER #. I NGEST:DONT INDUCE VOMIT,CONSULT PHYS/CALL EMER #
===================== Fire Fighting Measures =====================
Flash Point:30F (TCC)
Lower Limits:0.90
Extinguishing Media:FOAM,ALCOHOL FOAM,CO*2,DRY CHEMICAL,H*2O FOG
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:IF FLAMMABLE,AVOID EXPOS TO SPARKS,FIRE,HOT
METAL SURFACES.STOP LEAK IF CAN W/O RISK. USE H*2O SPRAY TO REDUCE
VAPORS. TAKE UP W/SAND OR OTHR NON-COMBUSTIBLE ABSORBENT MATL &
PLACE IN CNTNR FOR LATER DISPOSAL;OR DIKE FAR AHEAD OF SPILL
FORLATR DISP
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM HEAT,SPARKS & OPEN FLAME.
USE ADEQUATE VENTILATION. AVOID PROLONGED/REPEATED CONTACT W/SKIN.
DO NOT TAKE INTERNALLY. GROUND & (SEE SUPP DATA
Other Precautions:EFFECTS OF OVEREXP:
STEPS-HEADACHE,DIZZY,STAGGER,CONFUSION,UNCONSCIOUS.
SKIN/EYE:PRIMARY IRRIT. CHRONIC:NOT FULLY INVESTIGATED. EXCESS LEAD
EXPOS-HEADACHE,SEIZURES,NAUSEA,VOMIT,CRAMPS,WEAK.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APROVED SCBA FOR CONCENTRATIONS ABOVE
TLV LIMITS
Ventilation:LOCAL EXHAUST
Other Protective Equipment:EYE BATH & SAFETY SHOWER
Supplemental Safety and Health
SALTS,0.07% (BY WGT),0.5 MG/CUM (MFR). HANDLING,STORING PREC: BOND
CNTNRS WHEN POUR LIQ,POWDR TO AVOID STATIC CHARGE BUILDUP
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:216-390F
Vapor Density:>1
Spec Gravity:1.388
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:55.7
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAME & FIRE
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY CAUSE CARBON
MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE UNDER SAFE CONDITIONS OR DISPOSE OF
IAW LOCAL, STATE, & FEDERAL REGULATIONS..
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:1-BROMOHEXANE, O-611
CAGE:84898
CAGE:84898
CAGE:8Y898
============= Composition/Information on Ingredients =============
Ingred Name:HEXANE, 1-BROMO-; (1-BROMOHEXANE)
CAS:111-25-1
RTECS #:MO0925000
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 550000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTACT LENSES SHOULD NOT BE WORN IN
LAB. ALL CHEMICALS SHOULD BE CONSIDERED HAZ - AVOID DIRECT PHYSICAL
CONTACT. CAN CAUSE EYE IRRIT. CAN BE HARMFUL IF SWALLOWED.
LACHRYMATOR - CAUSES SEVERE EYE IRRI T. CAN BE IRRIT TO MUCOUS
MEMBRANES. POSSIBLE TERATOGEN - CAUSES EMBRYO-FETAL DMG. CAN CAUSE
ADVERSE REPRO EFTS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HLTH HAZ.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:AN ANTIDOTE IS A SUBSTANCE INTENDED TO COUNTERACT EFT OF
POIS. IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE
CAN BE OBTAINED FROM POIS CTRL CTR. EYE: FLUSH CONTINUOUSLY W/WATER
FOR AT LE AST 15-20 MINS. FLUSH SKIN W/WATER FOR 15-20 MINS. IF NO
BURNS HAVE OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL: REMOVE
PATIENT TO FRESH AIR. ADMIN O*2 IF PATIENT IS HAVING DFCLTY
BRTHG.(SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:135F,57C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:EVAC AREA. WEAR APPROP OSHA/NIOSH/MSHA APPRVD
EQUIP. VENT AREA. ABSORB ON VERMICULITE OR SIMILAR MATL. SWEEP UP &
PLACE IN AN APPROP CNTNR. HOLD FOR DISP. WASH CONTAMD SURFACES TO
REMOVE ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLSD & STORE IN COOL DRY
PLACE. STORE ONLY W/COMPATIBLE CHEMICALS. AVOID CONTACT W/SKIN,
EYES & CLTHG.
Other Precautions:THIS PRODUCT IS FURNISHED FOR LAB USE ONLY! PRODUCTS
MAY NOT BE USED AS DRUGS, COSMETICS, AGRICULTURAL OR PESTICIDAL
PRODUCTS, FOOD ADDITIVES OR AS HOUSEHOLD CHEMICALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN HOOD.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: IF PATIENT HAS STOPPED BRTHG ADMIN ARTF RESP. IF
PATIENT IS IN CARD ARREST ADMIN CPR. CONTINUE LIFE SUPPORTING
MEASURES UNTIL MED ASSIST HAS ARRIVED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:316F,158C
Melt/Freeze Pt:M.P/F.P Text:-121F,-85C
Spec Gravity:1.176
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORLESS LIQUID W/ETHER LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG OXIDIZING AGENTS. DO NOT USE MAGNESIUM/ALUMINUM OR
THEIR ALLOYS AS CONTAINERS.
Stability Condition to Avoid:LOW REACTIVITY. COMBUSTIBLE.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN CHEMICAL INCINERATOR EQUIPPED W/AN AFTER
BURNER & SCRUBBER. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:LEAD-ACID BATTERY
CAGE:08163
CAGE:0FGN2
CAGE:20038
CAGE:08163
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 30-40%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL; 9596
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: SEVERE SKIN IRRITATION, DAMAGE
TO CORNEA, UPPER RESPIRATORY. CHRONIC: POSSIBLE EROSION OF TOOTH
ENAMEL; INFLAMMATION OF NOSE, THROAT, AND BRONCHIAL TUBES.
Explanation of Carcinogenicity:CONTAINS I A [7440-38-2]
WHICH IS LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A
CARCINOGEN.
Effects of Overexposure:INHALATION-MAY CAUSE SEVERE RESPIRATORY
IRRITATION. INGESTION-SEVERE IRRITATION OF MOUTH, THROAT, ESOPHAGUS
& STOMACH. SKIN-SEVERE IRRITATION, BURNS & ULCERATIONS. EYE-SEVERE
IRRITATION, BURNS, CORNEA DAMAGE, BLINDNESS.
Medical Cond Aggravated by Exposure:OVEREXPOSURE TO SULFURIC ACID MIST
MAY CAUSE LUNG DAMAGE & AGGRAVATE PULMONARY CONDITIONS. CONTACT OF
SULFURIC ACID WITH SKIN MAY AGGRIVATE SKIN DISEASES SUCH AS ECZEMA
AND CONTACT DERMATITIS.
======================= First Aid Measures =======================
First Aid:INHALATION-REMOVE TO FRESH AIR IMMEDIATELY. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. INGESTION-GIVE LARGE QUANTITIES OF WATER;
DO NOT INDUCE VOMITING; CONSULT PHYSICIAN. SKIN-FLUSH WITH LARGE
AMOUNTS O F WATER FOR AT LEAST 15 MIN. REMOVE CONTAMINATED CLOTHING
COMPLETELY. EYES-FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR
AT LEAST 15 MIN; CONSULT PHYSICIAN.
===================== Fire Fighting Measures =====================
Lower Limits:4.1,HYDROGEN
Upper Limits:74.2HYDROGEN
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:IF BATTERIES ON CHARGE, SHUT OFF POWER. USE
POSITIVE PRESSURE SCBA. WATER APPLIED TO ACID GENERATES HEAT AND
CAUSES SPATTER. WEAR ACID RESISTANT CLOTHING.
Unusual Fire/Explosion Hazard:HIGHLY FLAMMABLE HYDROGEN GAS IS
GENERATED DURING CHARGING & OPERATION OF BATTERY. TO AVOID RISK OF
FIRE OR EXPLOSION, KEEP SPARKS AWAY FROM BATTERIES.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP FLOW OF MATERIAL, CONTAIN/ABSORB SPILL
WITH SAND, EARTH, OR VERMICULITE. DO NOT USE COMBUSTABLE MATERIALS.
NEUTRALIZE WITH SODA ASH, SODIUM BICARBONATE, AND LIME. WEAR
ACID-RESISTANT CLOTHING, BO OTS & FACE SHIELD.
Neutralizing Agent:SODA ASH (SODIUM CARBONATE), BAKING SODA, OR QUICK
LIME (CALCIUM OXIDE).
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY, WELL-VENTILATED
AREA WITH IMPERVIOUS SURFACES AND ADEQUATE CONTAINMENT IN THE EVENT
OF SPILLS. AVOID PHYSICAL DAMAGE TO CONTAINERS
Other Precautions:BATTERIES SHOULD BE STORED UNDER ROOF FOR PROTECTION
AGAINST ADVERSE WEATHER CONDITIONS. SEPARATE FROM INCOMPATIBLE
MATERIALS. KEEP AWAY FROM FIRE,SPARKS AND HEAT. STORE AND HANDLE
ONLY IN AREAS WITHADEQUATE WATER SUPPLY AND SPILL CONTROL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED UNDER NORMAL CONDITIONS. WHEN
CONCENTRATIONS OF SULFURIC ACID MIST ARE KNOWN TO EXCEED PEL, USE
NIOSH OR MSHA-APPROVED RESPIRATORY PROTECTION.
Ventilation:STORE AND HANDLE IN WELL VENTILATED AREAS. IF MECHANICAL
VENTILATION IS USED, COMPONENTS MUST BE ACID-RESISTANT.
Other Protective Equipment:ACID-RESISTANT APRON. UNDER SEVERE EXPOSURE
OR EMERGENCY CONDITIONS, WEAR ACID-RESISTANT CLOTHING & BOOTS.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATNG, DRINKING
OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
IN AREAS WHERE SULFURIC ACID IS HANDLED IN CONCENTRATIONS GREATER THAN
1%, EMERGENCY EYEWASH STATIONS AND SHOWERS SHOULD BE PROVIDED, WITH
UNLIMITED WATER SUPPLY.
================== Physical/Chemical Properties ==================
HCC:Z4
Boiling Pt:B.P. Text:203F,95C
Vapor Pres:17 TO 11
Vapor Density:>1
Spec Gravity:1.230-1.350
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:100%
Appearance and Odor:MFG ARTICLE; NO ODOR. ELECTROLYTE; CLEAR LIQUID,
SHARP, PENETRATING,PUNGENT ODO
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COMBUSTABLES, ORGANIC MATERIAL, STRONG REDUCING AGENTS, METALS, SULFUR
TRIOXIDE GAS, STRONG OXIDIZERS, WATER.
Stability Condition to Avoid:PROLONGED OVERCHARGE; SOURCES OF IGNITION.
Hazardous Decomposition Products:SULFUR TRIOXIDE, CARBON MONOXIDE,
SULFIRIC ACID MIST, SULFUR DIOXIDE, HYDROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS. SEND DAMAGED AND SPENT BATTERIES TO SECONDARY LEAD
SMELTER FOR RECYCLING.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:38-H GRAPHIC ARTS RUBBER CEMENT
Preparer's Name:THOMAS P. GERAS
CAGE:82956
CAGE:82956
============= Composition/Information on Ingredients =============
Ingred Name:N-HEPTANE
CAS:142-82-5
RTECS #:MI7700000
Fraction by Wt: 87.11%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM
ACGIH TLV:400 PPM/500STEL;9394
Ingred Name:ISOPROPYL ALCOHOL (SARA III) [99%]
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 1.49%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL;9394
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONTACT MAY CAUSE SKIN & EYE
IRRITATION. INHALATION MAY CAUSE RESPIRATORY IRRITATION & CNS
DEPRESSION/ DAMAGE. INGESTION MAY CAUSE GI TRACT IRRITATION & CNS
DEPRESSION/DAMAGE. ASPIRATION DURING SWALLOWING OR VOMITING MAY
CAUSE LUNG DAMAGE. CHRONIC
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED: COUGHING, SHORTNESS OF BREATH,
DIZZINESS, DROWSINESS, HEADACHE, NAUSEA, VOMITING, LOSS OF
COORDINATION, FATIGUE. EYES: REDNESS, TEARING, BURNING. SKIN:
REDNESS, BURNING, DRYING & CRACKING. IN GESTED: NAUSEA, VOMITING,
DIARRHEA, DRWOSINESS, DIZZIN
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN, &
RESPIRTAORY DISORDERS; PRE-EXISTING IMPAIRED PERIPHERAL NERVE
FUNCTION MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYE: REMOVE FROM EXPOSURE. FLUSH WITH LOTS OF WATER FOR 10-15
MINUTES. GET MEDICAL AID. SKIN: REMOVE CONTAMINATED CLOTHES. WASH
WITH SOAP & WATER. SEEK MEDICAL AID IF IRRITATION PERSISTS.
INHALED: REM OVE TO FRESH AIR. RESTORE BREATHING IF NEEDED. GET MED
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:25.0F,-3.9C
Lower Limits:1
Upper Limits:11.6
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
BUNKER GEAR.USE WATER TO MINIMIZE VAPORS & COOL FIRE EXPOSED
CONTAINERS.AVOID SPREADING BURNING LIQUID WITH WATER
Unusual Fire/Explosion Hazard:FLASHBACK ALONG VAPOR TRAIL MAY OCCUR.
THIS MATERIAL IS EXTREMELY FLAMMABLE & MAY BE IGNITED BY HEAT,
SPARKS, FLAME OR STATIC ELECTRICITY.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. ISOLATE &
DENY ENTRY. WEAR PROPER PROTECTIVE CLOTHING & EQUIPMENT. RECOVER
FREE PRODUCT. VENTILATE CONFINED SPACES. KEEP OUT OF
SEWERS/WATERWAYS; NOTIFY NATIONAL RES PONSE CENTER AT 800-424-8802
IF SPILL ENTERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM
SOURCES OF IGNITION & STRONG OXIDIZING AGENTS. KEEP CONTAINERS
TIGHTLY CLOSED. USE WITH ADEQUATE VENTILATION.
Other Precautions:AVOID INHALATION OF PRODUCT & ITS VAPORS/MISTS.
"EMPTY" CONTAINERS RETAIN RESSIDUE (LIQUID &/OR VAPOR) AND CAN BE
DANGEROUS. DO NOT GRING, CUT, WELD, BRAZE SOLDER, DRILL, OR EXPOSE
TO HEAT, FLAME OR S PARKS- THEY MAY EXPLODE & CAUSE INJURY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID CHRONIC BREATHING OF VAPORS. IF EXPOSURE
MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE LIMIT, USE NIOSH APPROVED
RESPIRATOR TO PREVENT OVEREXPOSURE.
Ventilation:USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR
LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV/PEL.
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. IMPERVIOUS
CLOTHING SHOULD BE WORN AS NEEDED.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
1ST AID CONT'D- NOTE TO PHYSICIANS: EPINEPHRINE & OTHER SYMPATHOMIMETIC
DRUGS MAY POTENTIATE CARDIAC ARRHYTHMIAS IN PERSONS EXPOSED TO THIS
CHEMICAL. THESE DRUGS SHOULD BE USED CAUTIOUSLY, IF AT ALL A ND
ONLY WITH CARDIAC MONITORING.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:180 TO 209F
Vapor Density:>1
Spec Gravity:0.71
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT AMBER VISCOUS LIQUID, SWEET AROMATIC
Percent Volatiles by Volume:89.98
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS OR BASES & SELECTED AMINES.
Stability Condition to Avoid:KEEP AWAY FROM HEAT,SPARKS,PILOT LIGHTS,
STATIC ELECTRICITY,& OPEN FLAME;STRONG OXIDIZING CONDITIONS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION IN THE PERSENCE
OF AIR MAY YIELD CARBON MONOXIDE AND CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DLA-HMIS: EPA/RCRA WASTE NUMBER D001 MAY APPLY
TO UNUSED/UNCONTAMINATED PRODUCT.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ROYCO 363B
Resp. Party Other MSDS Num.:MSDS #750,060-3
CAGE:07950
CAGE:07950
============= Composition/Information on Ingredients =============
Ingred Name:HYDROTREATED LIGHT NAPHTHENIC DISTILLATES, PETROLEUM
CAS:64742-53-6
RTECS #:PY8036000
Minumum % Wt:80.
Maxumum % Wt:90.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
Ingred Name:MINOR ADDITIVES
< Wt:1.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NONE RECOMMENDED
ACGIH TLV:NONE RECOMMENDED
Ingred Name:SOLVENT REFINED LIGHT NAPHTHENIC DISTILLATE (PETROLEUM)
CAS:64741-97-5
RTECS #:PY8041000
Minumum % Wt:10.
Maxumum % Wt:20.
Ingred Name:ADDITIVE CONTAINING BARIUM
= Wt:2.
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:EYE:PRODUCT IS EXPECTED TO BE NO MORE
THAN MINIMALLY IRRITATING TO THE EYES. SKIN: PRODUCT IS EXPECTED TO
BE NO MORE THAN MILDLY IRRITATING TO THE SKIN. PROLONGED OR
REPEATED CONTACT MAY CAUSE VARIOUSSKIN DISORDERS SUCH AS
DERMATITIS, FOLLICULITIS OR OIL ACNE. INHALE: MAY BE MILDLY
IRRITATING TO NOSE, THROAT, & RESPIRATORY TRACT. INGESTION:
INGESTION OF PRODUCT MAY RESULT IN VOMITING; ASPIRATION OF
VOMITUS INTO LUNGS MUST BE AVOIDED AS EVEN SMALL QUANTITIES MAY
RESULT IN ASPIRATION PNEUMONITIS.
Explanation of Carcinogenicity:THIS PRODUCT DOES NT CONTAIN ANY
CARCINOGENS AS IDENTIFIED BY NTP, IARC, OR OSHA.
Effects of Overexposure:IRRITATION AS NOTED ABOVE. ASPIRATION
PNEUMONITIS MAY BE EVIDENCED BY COUGHING, LABORED BREATHING AND
CYANOSIS (BLUISH SKIN); IN SEVERE CASES DEATH MAY OCCUR.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYES-FLUSH WITH WATER FOR 15 MIN. GET GET MEDICAL ATTENTION.
SKIN-REMOVE CONTAMINATED CLOTHES/SHOES & WIPE EXCESS FROM SKIN.
FLUSH SKIN WITH WATER. FOLLOW BY WASHING WITH SOAP & WATER. IF
IRRITATION O CCURS, GET MEDICAL ATTENTION. DO NOT RESUE CLOTHING
UNTIL CLEANED. INHALATION-REMOVE VICTIM TO FRESH AIR & PROVIDE
OXYGEN IF BREATHING IS DIFFICULT. GET MEDICAL ATTENTION.
INGESTION-DO NOT INDUCE VOMI TING. IF VOMITING OCCURS, KEEP HEAD
BELOW HIPS TO PREVENT ASPIRATION OF LIQUID INTO THE LUNGS. GET
MEDICAL ATTENTION
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=176.7C, 350.F
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
DO NOT USE A DIRECT STREAM OF WATER. PRODUCT WILL FLOAT AND CAN BE
REIGNITED ON SURFACE OF WATER.
Fire Fighting Procedures:MATERIAL WILL NOT BURN UNLESS PREHEATED. DO
NOT ENTER CONFINED FIRE SPACE WITHOUT FULL BUNKER GEAR (HELMET
POSITIVE PRESSURE NIOSH APPR OVED SCBA. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:SULFUR OXIDES AND HYDROGEN SULFIDE, BOTH
OF WHICH ARE TOXIC. MAY RELEASED UPON COMBUSTION.
================== Accidental Release Measures ==================
Spill Release Procedures:MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE
CAUTIOS JUDGEMENT WHEN CLEANING UP LARGE SPILLS. SMALL SPILLS::
TAKE UP WITH AN ABSORBENT MATERIAL AND DISPOSE OF PROPERLY. "SEE
OTHER"
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE WITH
ADEQUATE VENTILATION. KEEP AWAY FROM OPEN FLAMES & HIGH
TEMPERATURES.
Other Precautions:WASH WITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING, APPLYING COSMETICS, OR USING TOILET FACILITIES. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS USE NIOSH-APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE. IN ACCORDANCE WITH 29CFR1910.134 USE EITHER AN
ATMOSPHERE-SUPPLYING RESPIRATOR OR AI R-PURIFYING RESPIRATOR FOR
ORGANIC VAPORS & PARTICULATES.
Ventilation:USE AS APPROPRIATE TO OBTAIN PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:WEAR OTHER CLOTHING AS APPROPIATE TO
MINIMIZE CONTACT.
Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING,
DRINKING, SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED
CLOTHING BEFORE RESUE.
Supplemental Safety and Health
PHYSICIAN: IF MORE THAN 2 ML/KG HAS BEEN INGESTED & VOMITING HAS NOT
OCCURRED, EMESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP HEAD
BELOW HIPS TO PREVENT ASPIRATION. IF SYMPTOMS SUCH AS LOSS OF GAG
RE FLEX, CONVULSION/UNCONSCIOUSNESS OCCURS BEFORE EMESIS, USE
GASTRIC LAVAGE WITH CUFFED ENDOTRACHEAL TUBE.
================== Physical/Chemical Properties ==================
HCC:V6
Spec Gravity:0.88
Viscosity:10.64
Evaporation Rate & Reference:<0.01 APPROX.
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID; STRONG PETROLEUM ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS MAY BE FORMED UPON COMBUSTION.
===================== Ecological Information =====================
Ecological:UNDER EPA-CWA PRODUCT IS CLASSIFIED AS OIL UNDER SEC 311.
SPILLS INTO OR LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE
REPORTED TO THE NATIONALY RESPONSE CENTER:800-424-8802.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF AS HAZARDOUS WASTE D005 BASED ON
BARIUM CONTENT. UNLESS EXTRACTION RESULTS ARE LESS THAN EPA LIMIT.
=================== MSDS Transport Information ===================
Transport Information:NOT HAZARDOUS BY D.O.T. REGULATIONS.
===================== Regulatory Information =====================
Federal Regulatory Information:THE COMPONENTS OF THIS PRODUCT ARE
LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCE.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:LACQUER C/N GLOSS GRAY 16473
Preparer's Name:W.A. ELLISON
CAGE:FO127
CAGE:FO127
CAGE:61196
============= Composition/Information on Ingredients =============
Ingred Name:ISOBUTYL ACETATE
CAS:110-19-0
OSHA PEL:150 PPM 700 MG/CU.M
ACGIH TLV:150 PPM 700 MG/CU.M
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
Ingred Name:NITROCELLULOSE
CAS:9004-70-0
RTECS #:QW0970000
OSHA PEL:NONE ESTABLISHED
ACGIH TLV:NONE ESTABLISHED
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:DI-SEC-OCTYL PHTHALATE (DI-2-ETHYLHEXYL-PHTHALATE)(SARA
III)
CAS:117-81-7
RTECS #:TI0350000
OSHA PEL:5 MG/M3/10 STEL
ACGIH TLV:5 MG/M3; 9192
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:VM&P NAPHTHA
(VAPOR PRESSURE 40 MM HG @ 20C)
CAS:8030-30-6
RTECS #:DE3030000
OSHA PEL:500 PPM
ACGIH TLV:300 PPM 1350 MG/CU.M
Ingred Name:N-HEPTANE
CAS:142-82-5
RTECS #:MI7700000
OSHA PEL:500 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9293
Ingred Name:VOC. ORGANIC CMPD 5.0 LB/GL LESS WATER & NPRS* 600 G/L
LESSWATER VOC 20.6 LB/GAL SOLIDS 2472 G/L SOLIDS CALCULATED.
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SWALLOWING: CAN CAUSE GASTROINTESTINAL
IRR/NAUSEA/VOMIT. ASPIRATION OF MAT'L MAYCAUSE CHEM PNEUMONITIS.
INHALATION: NOSE/THROAT IRRITA. HIGH CONCENTRATION MAY CAUSE
CENTRAL NERVOUS SYSTEM DEPRESSION CHAR BY
HEADACHES/DIZZINESS/NAUSEA/CONFUSION. EYE: MAY CAUSE EYE IRR. SKIN:
MAY CAUSE DEFATTING AND IRRITATION.
Explanation of Carcinogenicity:DI (2-ETHYLHEXYL) PHTHALATE IS LISTED AS
A POTENTIAL CARCINOGEN BY THE NTP.
Effects of Overexposure:REPORTS HAVE ASSOCIATED PROLONGED AND REPEATED
OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING AND INHALINGTHE CONTENTS MAY BE HARMFUL OR FATAL.
======================= First Aid Measures =======================
First Aid:SWALLOWING: DO NOT INDUCE VOMITING/GET MED ATTN. INHALATION:
REMOVE TO FRESH AIRIF BREATHING HAS STOPPED GIVE CPR. GET MED ATTN.
EYE: FLUSH W/WATER FOR 15 MIN LIFTING UPPER/LOWER LIDS. GET MED
ATTN. SKIN: REMOVE CONTAMINATED CLOTHING.WASH AFFECTED AREA.
OBTAIN MED ATTN IF IRR'N PERSISTS. TREATMENT REQ FOR OVER-
EXPOSURE S/B DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL
CONDITIONS.
===================== Fire Fighting Measures =====================
Flash Point:20F -6.67C
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS, DESIGNED TO
EXTINGUISH FLAMMABLE LIQUID FIRES. POLYMER FOAM IS PREFER FOR LG
FIRES.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. WATER
TO COOL CONT TO PREVENT POSSIBLE AUTO-IGNITION OR EXPLOSION. IF
WATER IS USED, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE
TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMP MAY NOT
BE IMMED APPARENT. GET MED ATTN. WARNING! FLAMMABLE
================== Accidental Release Measures ==================
Spill Release Procedures:ELIM ALL IGNITION SOURCES. DIKE/CONTAIN SPILL
WITHINERT MAT'L. TRANSFER LIQ'S/ABSORBENT DIKING MAT'LIN COVERED
METAL CONT'S FOR RECOVERY/DISPOSAL. USEONLY NON-SPARKING TOOLS.
PREVENT CONTAM OF SEWERS/ STREAMS/GROUNDWATER W/SPILLED MAT'L/USED
ABSORBENT
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 95F. STORE
QUANTITIES INCOMPLIANCE WITH OSHA 29CFR1910.106.
Other Precautions:DO NOT REUSE EMPTY CONTAINTERS. DO NOT TAKE
INTERNALLY. CONTAINERS SHOULD BEGROUNDED AND BONDED TO THE
RECEIVING CONTAINER. DO NOT WELD/BRAZE OR CUT CONT'R.NEVER USE
PRESSURE TO EMPTY. DRUM IS NOT A PRESSURE VESSEL. CLOSE AFTER EA
USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WELL VENTILATED AREA-RESP NOT REQ. RESTRICTED
VENT-NIOSH CHEMICAL CARTRIDGE MAY BE REQ. IF SPRAYING, MECH
PREFILTER MAY BE REQ. IF TLV ARE EXCEEDED, USE A PROP FITTED
NIOSH/MSHA RESP W/APPROP PROTECTI ON FACTOR. SEE OSHA 29 CFR
1910.134.
Ventilation:PROVIDE DILUTION/LOCAL EXHAUST VENTILATION TO KEEP CONCENT
OF HAZARDOUS SUBSTANCES BELOW EXPOSURE LIMITS STATED.
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER.
Work Hygienic Practices:WASH WITH SOAP AND WATER HANDS/FACE THROUGHLY
BEFORE EATING OR DRINKING.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:181F 302F
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN AIR
Percent Volatiles by Volume:75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING/CUTTING WILL PRO- DUCE SMOKE/CARBON MONOXIDE/CARBON
DIOXIDE/OXIDES OF NITROGEN
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT, SPARKS AND
FLAME.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE ONLY IN EPA PERMITTED FACILITY.
DISPOSEONLY IAW FED/STATE/LOCAL REGS. DO NOT INCINERATE CLOSED
CONTAINERS. OBSERVE PRECAUTIONS FOR DIS- POSAL OF FLAMMABLE
MAT'LS. CONTAMINATED ABSORBENT MAY BE DISPOSED IN A HAZARDOUS
WASTE LANDFILL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:#6173 STANDARD COLOR REAGENT
CAGE:53390
CAGE:53390
============= Composition/Information on Ingredients =============
Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 3.75%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:COBALT CHLORIDE
CAS:7791-13-1
RTECS #:GG0200000
Fraction by Wt: 0.1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 MG/M3 (CO)
ACGIH TLV:0.05 MG/M3 (CO)
Ingred Name:POTASSIUM CHLOROPLATINATE
CAS:16921-30-5
RTECS #:TP1650000
Fraction by Wt: 0.125%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN IRRITATION ON CONTACT.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:RASH, ITCHING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH LOTS OF WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. SEE DOCTOR. SKIN: REMOVE CONTAMINATED CLOTHES. FLUSH
WITH WATER, THEN WASH WITH SOAP AND WATER. INHALED: REMOVE PERSON
TO FRES H AIR. GIVE RESPIRATORY SUPPORT IF NEEDED. INGESTED: DO NOT
INDUCE VOMITING. IF CONSCIUOS, GIVE MILK OR WATER TO DILUTE. GET
IMMEDIATE MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
BUNKER GEAR.
Unusual Fire/Explosion Hazard:REACTS WITH METALS TO FORM HYDROGEN GAS
WHICH CAN FORM EXPLOSIVE MIXTURES WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:NEUTRALIZE WITH SODA ASH, ABSORB WITH SAND OR
VERMICULITE AND SCOOP UP AND PLACE IN A CONTAINER FOR PROPER
DISPOSAL.
Neutralizing Agent:SODA ASH
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN A COOL, DRY, WELL-VENTILATED PLACE. STORE AWAY FROM
INCOMPATIBLES. KEEP AWAY FROM SOURCES OF IGNITION.
Other Precautions:EMPTY CONTAINERS MAY BE HAZARDOUS DUE TO RETAINED
RESIDUE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR SCBA IN AREAS OF EXTREMELY HIGH
CONCENTRATION OR CONFINED AREAS. USE IN ACCORDANCE WITH 29 CFR
1910.134.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. HMIS: EYE
WASH STATION & SAFETY SHOWER
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:C3
pH:<1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, YELLOW LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALS, STRONG ALKALIS, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:AVOID CONTACT WITH INCOMPATIBLES
Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FF-680 1,2-BIS(TRIBROMOPHENOXY)-ETHANE, 505
Preparer's Name:RESEARCH SERVICES DEPT
CAGE:2E394
CAGE:2E394
============= Composition/Information on Ingredients =============
Ingred Name:BENZENE, 1,1'-(1,2-ETHANEDIYLBIS(OXY)) BIS
(2,4,6-TRIBROMO-; (1,2-BIS(TRIBROPHENOXY)-ETHANE)
CAS:37853-59-1
RTECS #:DA0357000
OSHA PEL:15 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 10 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:GREAT LAKES FF-680 IS NOT A PRIMARY
SKIN IRRITANT & NOT A PRIMARY EYE IRRITANT. NO TEST ANIMAL DEATHS
OCCURED DURING A FOUR HOUR ACUTE INHAL EXPOSURE AND 14 DAY
POST-EXPOSURE PERIOD TO FF-680 AT THE M AX CONC EMPLOYED OF 36.68
MG/L. IN A 90-DAY DIETARY STUDY, NO TREATMENT RELATED CHANGES WERE
OBSERVED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: IN ANIMALS FED 0.1 OR 1.0% FF-680. AT
10%, MINIMAL LIVER CELL ENLARGEMENT WAS OBSERVED. ACUTE HEALTH
HAZARD IS THE POTENTIAL FOR EYE OR SKIN IRRITATION. TEST IN
LABORATORY ANIMALS INDICATE A POTENTIAL FOR LIVER DAMAGE FROM
CHRONIC EXTREMELY HIGH ORAL EXPOSURE. CONTACT MAY CAUSE EYE OR SKIN
IRRITATION.
Medical Cond Aggravated by Exposure:NONE REPORTED. EXISTING DERMATITIS
MAY BE AGGRAVATED BY EXPOSURE.
======================= First Aid Measures =======================
First Aid:EYE: IMMED FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN.
GET PROMPT MEDICAL ATTN IF IRRIT OCCURS. SKIN: WASH EXPOSED SKIN
WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING
(GIVE O *2/ARTF RESP). INGEST: GET MEDICAL ATTENTION IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:ALL CONVENTIONAL EXTINGUISING MEDIA ARE SUITABLE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:COMBUSTION IN THE PRESENCE OF OTHER FUELS
MAY RELEASE HYDROGEN BROMIDE OR OTHER TOXIC GASES.
================== Accidental Release Measures ==================
Spill Release Procedures:VACUUM UP SPILL TO MINIMIZE DUST IN THE AIR
AND PLACE IN A SUITABLE, LABELLED CONTAINER FOR DISPOSAL. AVOID
SKIN OR EYE CONTACT AND INHALATION OF DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:USE REASONABLE CARE TO AVOID SKIN AND
EYE CONTACT. AVOID BREATHING DUSTS. WASH CONTAMINATED CLOTHING
BEFORE REUSE. STORE IN DRY, WELL-VENT AREA.
Other Precautions:AVOID OVERHEATING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED DUST RESPIRATOR WHERE
DUSTING OCCURS.
Ventilation:LOCAL EXHAUST: USE TO MINIMIZE DUSTING. MECHANICAL: USE FOR
GENERAL AREA CONTROL.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:>433F,>223C
Spec Gravity:2.58(H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE CRYSTALLINE POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:HYDROGEN BROMIDE OR OTHER TOXIC GASES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE IN AN APPROVED CHEMICAL
INCINERATOR EQUIPPED WITH A SCURBBER OR IN A CHEMICAL LANDFILL AS
APPROVED BY CURRENT FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:WINDSHIELD WASHER SOLVENT, M5-49
CAGE:77628
CAGE:77628
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 20-30%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM;500 STEL
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 1-10%
OSHA PEL:50 PPM, S
ACGIH TLV:25 PPM, S
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE IRRITATION; BURN ON
PROLONGED USE. SKIN:SLIGHTLY IRRITATING ON PROLONGED USE. SKIN
ABSORBED. INHAL:EXCESSIVE INHALATION MAY CAUSE RESPIRATORY
IRRITATION, HEADACHE, DIZZINESS, INTOXICATIO N. INGEST:HARMFUL IF
SWALLOWED. MAY CAUSE NAUSEA, VOMITING, DIARRHEA. ANIMAL STUDIES
CLEARLY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:DEMONSTRATED DOSE-RELATED ADVERSE
EFFECTS ON THE CNS, HEMATOPOIETIC TISSUES, BLOOD, KIDNEYS & LIVER,
ASSOCIATED W/ADMINISTRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER
(EGBE). (EXTRACTED FROM DHH S (NIOSH) PUBLICATION NO.90-118) .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/WATER FOR AT LEAST 15 MINUTES. IF ADVERSE EFFECTS
PERSIST, CONSULT MD IMMEDIATELY. SKIN:WASH W/WATER. REMOVE
CONTAMINATED CLOTHING & WASH BEFORE RE-USE. INHAL:MOVE TO FRESH
AIR. INGEST:GIV E 2 GLASSES OF WATER & INDUCE VOMITING BY TOUCHING
BACK OF THROAT. CONSULT MD IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:>60F,>16C
Extinguishing Media:WATER FOG, FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH W/WATER. OBSERVING HEALTH HAZARDS
DESCRIBED ABOVE, REMOVE IGNITION SOURCES. VENTILATE AREA. CONFINE &
MOVE TO WASTE DRUM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL AREA AWAY FROM IGNITION
SOURCES.
Other Precautions:KEEP AWAY FROM CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NONE INDICATED.
Ventilation:CONSUMER USE:USE W/ADEQUATE VENTILATION. BULK HANDLING
(PROLONGED EXPOSURE):GENERAL VENTILATION.
Other Protective Equipment:NONE INDICATED.
Work Hygienic Practices:WEARING CONTACT LENSES IS INADVISABLE.
Supplemental Safety and Health
PH:SLIGHTLY ALKALINE. % VOLAT:>99 (WT). EYE PROT:& FULL LENGTH
FACESHIELD(FOR BULK HANDLING (PROLONGED EXPOSURE)).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Spec Gravity:0.96 (H*2O=1)
pH:SUPDAT
Solubility in Water:SOLUBLE
Appearance and Odor:BLUE LIQUID W/ALCOHOL-AMMONIA ODOR.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, STRONG ACIDS & ALKALIS.
Stability Condition to Avoid:NONE KNOWN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W ALL APPLICABLE FEDERAL, STATE &
LOCAL GOVERNMENTAL LAWS & REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MOLECULAR SIEVE TYPE 4AXH5
CAGE:MO950
CAGE:MO950
CAGE:0H8X3
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM OXIDE
CAS:1313-59-3
Fraction by Wt: < 30% %
Other REC Limits:NONE SPECIFIED
Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS
FORMS) (SARA III)
CAS:1344-28-1
RTECS #:BD1200000
Fraction by Wt: < 30% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:SILICA GEL
CAS:112945-52-5
RTECS #:VV7310000
Fraction by Wt: < 50% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:6 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: < 1% %
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PRODUCT GETS HOT AS IT ABSORBS WATER.
BURNS TO MOIST BODY TISSUES CAN RESULT. NOSE/THROAT IRRITATION,
SKIN IRRITATION, EYE IRRITATION.
Explanation of Carcinogenicity:CRYSTALLINE SILICA IS CLASSIFIED AS "2A"
(PROBABLY CARCINOGENIC TO HUMANS) BY IARC.
Effects of Overexposure:COUGH CHEST DISCOMFORT, LOCAL REDNESS ON SKIN
AND/OR BURNS, EXCESS REDNESS OF THE CONJUNTIVA OF THE EYE,
IRRITATION OF THE NOSE & THROAT, LUNG DAMAGE.
Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE
ASTHMA AND INFLAMMATORY OR FIROTIC PULMONARY DISEASE.
======================= First Aid Measures =======================
First Aid:SWALLOWING: IF INGESTED IN LARGE QUANTITIES, DRINK 2 GLASSES
OF WATER. CONTACT PHYSICIAN FOR PERMISSION TO INDUCE VOMITING. SKIN
CONTACT: WASH CONTAMINATED AREA WITH SOAP AND WATER. INHALATION:
REMOVE THE PERSON TO FRESH AIR. EYE CONTACT: FLUSH EYES WITH WATER
FOR 15 MINUTES. NOTES TO PHYSICIAN: THE USED PRODUCT CAN CONTAIN
MATERIAL OF A HAARDOUS NATURE. IDENTIFY MATERIAL AND TREAT
SYMPTOMATICALY
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NONFLAMMABLE
Upper Limits:NONFLAMMABLE
Extinguishing Media:UNUSED MATERIAL DOES NOT BURN. USE MEDIA
APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:DEPENDS ON THE USE OF THE MATERIAL MAY CONTAIN
PRODUCTS OF A HAZARDOUS NATURE. THE USER OF THIS PRODUCT MUST
IDENTIFY THE HAZARDS OF THE RETAINED MATERIAL.
Unusual Fire/Explosion Hazard:IN THEIR FRESH, UNUSED STATE, MOLECULAR
SIEVES ARE NOT FLAMMABLE. WHEN EXPOSED TO WATER (MOISTURE) THEY CAN
GET QUITE HOT. FLOODING WILL REDUCE TEMPERATURES.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP THE SPILL AREA. COLLECT AND PLACE THE
SPILLED MATERIAL IN A WASTE DISPOSAL CONTAINER. AVOID RAISING DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA. AVOID
MOISTURE. KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:OPEN CONTAINER SLOWLY. AVOID CONTACT WITH EYES AND
SKIN. AVOID BREATHING DUST. USE WITH ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH/MSHA APPROVED RESPIRATOR FOR PROTECTION
AGAINST DUST, MIST AND VAPOR IS RECOMMENDED FOR OPERATIONS WHEN THE
PERMISSIBLE EXPOSURE LIMIT MIGHT BE EXCEEDED.
Ventilation:LOCAL EXHAUST VENTILATION IS RECOMMENDED FOR OPERATIONS
WHERE THE PEL MIGHT BE EXCEEDED.
Other Protective Equipment:EMERGENCY EYEWASH AND SHOWER.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
SELECT PROTECTIVE EQUIPMENT IN ACCORDANCE WITH OSHA REGULATIONS -- 29
CFR 1910.132 AND 1910.133
================== Physical/Chemical Properties ==================
HCC:V7
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:1.1
Evaporation Rate & Reference:NIL
Solubility in Water:NOT GIVEN
Appearance and Odor:TAN BEAD, ODORLESS
Percent Volatiles by Volume:0 %
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CHEMICALS HAVING HIGH HEATS OF ABSORPTION SUCH AS OLEFINS, HCL, ETC.
Stability Condition to Avoid:THE ADDITION OF WATER (MOISTURE) WITHOUT
FLOODING CAN CAUSE RISE IN TEMPERATURE FROM HEAT OF ABSORPTION.
Hazardous Decomposition Products:SODIUM OXIDE, ALUMINUM OXIDE, SILICON
OXIDE,AND DECOMPOSITION PRODUCTS FROM ANY RETAINED MATERIAL ON THE
SIEVE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCARD ANY PRODUCT (INCLUDING ANY RETAINED
MATERIALS OF USE) IN DISPOSABLE CONTAINER OR LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER IN FULL COMPLIANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:T-084 NI-173
CAGE:UNICA
CAGE:0FGH2
CAGE:UNICA
============= Composition/Information on Ingredients =============
Ingred Name:COBALT
CAS:7440-48-4
RTECS #:GF8750000
Fraction by Wt: 0-20%
Other REC Limits:0.05 PPM
OSHA PEL:0.1 MG/M3;AS CO
ACGIH TLV:0.05 MG/M3;DUST 9293
Ingred Name:NICKEL (SOLUBLE)
INTENDED CHANGE (IC)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: BALANCE
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
ACGIH TLV:0.05 MG/CUM IC (A1)
Ingred Name:BORON OXIDE, TRIOXIDE
CAS:1303-86-2
RTECS #:ED7900000
Fraction by Wt: 0-5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
Ingred Name:TANTALUM
CAS:7440-25-7
RTECS #:WW5505000
Fraction by Wt: 0-5%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN
CARCINOGEN BY IARC, NTP & ACGIH)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 0-20%
OSHA PEL:1 MG/CUM (CEILING)
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TUNGSTEN (INSOLUBLE), WOLFRAM
CAS:7440-33-7
RTECS #:YO7175000
Fraction by Wt: 0-15%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: 0-5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:TITANIUM (DRY POWDER) (TI)
CAS:7440-32-6
RTECS #:XR1700000
Fraction by Wt: 0-10%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE
CAS:7439-98-7
RTECS #:QA4680000
Fraction by Wt: 0-10%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
Ingred Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
Fraction by Wt: 0-21%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE
CAS:1344-28-1
RTECS #:BD1200000
Fraction by Wt: 0-15%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SKIN: ALLERGIC
DERMATITIS/REDNESS/PAPULAR FORMATION/ULCER/FEVER. EYE:
IRRITATION/CONJUNCTIVA REDNESS. INGESTION: NAUSEA/ABDOMINAL
PAIN/VOMITING/DIARRHEA/CNS DEPRESSION/BURNS. INHALATION: BREATH
SHORTN ESS/DRY COUGH/CHEST PAIN/VOMITING/DIARRHEA/BURN/CNS
DEPRESSION/INTERSTITIAL PNEUMONITIS/RESPIRATORY TRACT
SENSITIZATION.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:INHALATION: EMPHYSEMA/PULMONARY FIBROTIC
DISEASE/SENSITIZATION. SKIN: SENSITIZATION/SPREADING TO THE WHOLE
BODY W/LESIONS/ITCHING/SORENESS/BURNS/REDNESS. EYES: CORNEAL
DAMAGE/POLYCYTHEMIA/HYPERPLASIA OF THE THYROID GLAND, & DAMAGE TO
THE ALPHA CELLS OF THE PANCREAS/SENSITIZATION.
Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE
ASTHMA & INFLAMMATORY OR FIBROTIC PULMONARY DISEASE. MAY AGGRAVATE
AN EXISTING DERMATITIS.
======================= First Aid Measures =======================
First Aid:INGESTION: GIVE 2 GLASSES OF MILK OR WATER. INDUCE VOMITING,
UNLESS UNCONSCIOUS. SKIN: WASH THOROUGHLY W/SOAP & WATER.
INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT
BREATHING. OX YGEN MAY BE GIVEN IF NECESSARY. EYES: FLUSH W/WATER.
IF DISCOMFORT PERSISTS, SEE AN OPTHALMOLOGIST. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:SPECIAL DRY POWDER METAL EXTINGUISHING MATERIAL
Fire Fighting Procedures:USE APPROPRIATE EXTINGUISHER TO EXTINGUISH
COMBUSTIBLE MATERIALS IGNITED BY THERMAL SPRAY FLAME.
Unusual Fire/Explosion Hazard:AIRBORNE/FINELY DIVIDED
SOLIDS/ACCUMULATION OF METAL DUST SHOULD BE TREATED AS EXPLOSIVES.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT TO PROTECT AGAINST
HAZARDS & DISPOSE OF PER WASTE DISPOSAL METHOD.
======================Handling and Storage ======================
Handling and Storage Precautions:ELECTRICITY CAN CAUSE SHOCK THAT CAN
KILL. DON'T TOUCH LIVE ELECTRICAL PARTS. NOISE CAN DAMAGE HEARING.
WEAR PROPER RECOMMENDED PROTECTION.
Other Precautions:PREVENT FIRES. AVOID FUMES, GAS, & DUST, WHICH CAN
HARM YOUR HEALTH. ALWAYS SPRAY W/ENOUGH VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:PERSONAL AIR SAMPLES CAN BE TAKEN & ANALYZED FOR
HAZARDOUS INGREDIENTS & DECOMPOSITION PRODUCTS TO DETERMINE IF &
WHAT TYPE OF RESPIRATOR IS REQUIRED.
Ventilation:TO MINIMIZE DANGER FROM DUST EXPLOSIONS, ADEQUATE
VENTILATION SHOULD BE PROVIDED TO SPRAY BOOTH. LOCAL DUST PICK UP.
Other Protective Equipment:HELMETS
Supplemental Safety and Health
NOTE TO PHYSICIAN: THE HAZARDS OF THIS MATERIAL ARE MAINLY DUE TO ITS
SENSITIZING & MILDLY IRRITATING PROPERTIES. THERE IS NO SPECIFIC
ANTIDOTE. TREATMENT OF OVEREXPOSURE SHOULD BE DIRECTED AT THE CON
TROL OF SYMPTOMS & THE CLINICAL CONDITION.
================== Physical/Chemical Properties ==================
Solubility in Water:INSOLUBLE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:AREA & SPARKS DURING SPRAYING CAN BE A
SOURCE OF IGNITION OF COMBUSTIBLE MATERIALS
Hazardous Decomposition Products:OXIDES, SUB-OXIDES, & COMPLEX OXIDES
OF MATERIALS CONTAINED IN THIS PRODUCT
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE ACCORDING TO LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MURIATIC ACID, 23 DEG BE, HX0606
CAGE:DO242
CAGE:63612
CAGE:DO242
============= Composition/Information on Ingredients =============
Ingred Name:HYDROCHLORIC ACID (SARA 302/313) (CERCLA)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 100%
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM; 9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SUPDAT:TECHNICAL SERVICE DEPARTMENT (609) 354-9200. THE
FOLLOWING EM SCIENCE SPILL-X NEUTRALIZER & ABSORBENT IS (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:RECOMMENDED FOR THIS PRODUCT: SX0861 SPILL-X-A ACID
SPILL TREATMENT KIT.
RTECS #:9999999ZZ
Ingred Name:RESP PROT:ENGINEERING AND/OR ADMINISTRATIVE CONTROLS SHOULD
BE IMPLEMENTED TO REDUCE EXPOSURE.
RTECS #:9999999ZZ
Ingred Name:EYE PROT: AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT CAUSES SEVERE BURNS AND
PERMANENT EYE DAMAGE. SKIN CONTACT CAUSES SEVERE BURNS, POSSIBLE
DEEP ULCERATION. INHALATION CAUSE DAMAGE TO NASAL AND RESPIRATORY
PASSAGES, PULMONARY EDEMA. INGEST ION CAUSES BURNS OF MOUTH, THROAT
AND GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN:
IMMEDIATELY FLUSH THOROUGHLY WITH LARGE AMOUNTS OF WATER. EYES:
IMMEDIATELY FLUSH THOROUGHLY WITH WATER FOR AT LEAST 15 MINUTES.
INHALATION: REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF
BREATHING HAS STOPPED. INGESTION: DO NOT INDUCE VOMITING; GIVE
WATER OR MILD IF CONSCIOUS; GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONCOMBUSTIBLE
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTACT WITH METALS PRODUCES HYDROGEN
WHICH MAY FORM EXPLOSIVE MIXTURES WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE
PROT EQUIP LISTED UNDER EXPOS/PERS PROT. ELIM ANY IGNIT SOURCES
UNTIL AREA IS DETERM TO BE FREE FROM EXPLOSION/FIRE HAZ. CNTN
RELEASE & ELIM ITS SOURCE,IF THIS CAN BE DONE W/OUT RISK. TAKE
UP& (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLOSED. STORE IN A
COOL, WELL-VENT AREA SEPARATED FROM INCOMPAT MATS. DO NOT BRTH VAP.
DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
Other Precautions:HANDLE EMPTY CONTAINERS WITH CAUTION. ADD ACID
CAUTIOUSLY TO WATER WHEN DILUTING - NEVER ADD WATER TO ACID.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOS LIMIT(S) OF PROD/ANY
COMPONENT IS EXCEEDED (SEE TLV/PEL), NIOSH/MSHA APPRVD AIR SUPPLIED
RESP IS ADVISED IS ABSENCE OF PROPER ENVIRON CTRL. OSHA REGS ALSO
PERMIT OTHER NIOSH/MSHA (S EE YOUR SAFETY EQUIP SUPPLIER). (ING 4)
Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME
HOOD OR WITH EQUIVALENT VENTILATION.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY. EYE WASH & SAFETY EQUIPMENT SHOULD BE READILY
AVAILABLE.
Supplemental Safety and Health
SPILL PROC:CONTAINERIZE FOR PROPER DISP AS DESCRIBED UNDER DISPOSAL.
COMPLY W/FED, STATE, & LOCAL REG ON RPTG RELS. REFER REGULATORY
INFO FOR REPORTABLE QTY & OTHER REGULATORY DATA. EM SCIENCE REC SPI
LL-X NEUT & ABSORB AGENTS FOR VARIOUS TYPES OF SPILLS. ADDN INFO ON
SPILL-X PROD CAN BE PROVIDED THRU EM SCIENCE (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:230F,110C
Melt/Freeze Pt:M.P/F.P Text:-101F,-74C
Vapor Pres:160 @ 20C
Vapor Density:1.25
Spec Gravity:1.1885 (H*2O=1)
Evaporation Rate & Reference:2.0 (BUAC = 1)
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; ACRID ODOR.
Percent Volatiles by Volume:+99.9
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES, ALKALIES AND AMINES; CONTACT WITH METALS PRODUCES HYDROGEN.
Stability Condition to Avoid:HEAT; CONTACT WITH METALS.
Hazardous Decomposition Products:TOXIC HYDROGEN CHLORIDE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:SPECIFIED TECHNOLOGY-NEUTRALIZE TO PH 6-9.
CONTACT YOUR LOCAL PERMITTED WASTE DISPOSAL SITE (TSD) FOR
PERMISSIBLE TREATMENT SITES. ALWAYS CONTACT A PERMITTED WASTE
DISPOSER (TSD) TO ASSURE COMPLIANCE W/ALL CURRENT LOCAL, & STATE
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: QUICK DRY SPRAY ENAMEL, 55-B, 55-324
Cage: DO542
Box: 9
=======================================================
Contractor Summary
=======================================================
Cage: PPGXX
Box: UNKNOW
Cage: DO542
Box: 9
=======================================================
Ingredients
=======================================================
% Wt: 10-15
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 13463-67-7
RTECS #: XR2275000
% Wt: 10-15
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 67-64-1
RTECS #: AL3150000
% Wt: 25-30
OSHA PEL: 1000 PPM
ACGIH TLV: 750PPM/1000STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 78-93-3
RTECS #: EL6475000
% Wt: 10-15
OSHA PEL: 200 PPM
ACGIH TLV: 200 PPM/300STEL
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 75-28-5
RTECS #: TZ4300000
% Wt: 10-15
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 74-98-6
RTECS #: TX2275000
% Wt: 10-15
OSHA PEL: 1000 PPM
ACGIH TLV: ASPHYXIANT
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
% Wt: 30-35
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/150STEL
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
% Wt: 15-20
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
-----------------------------
ANIMALS INHALING MASSIVE QTYS OF TITANIUM
-----------------------------
W/HUMANS INVOLVED IN MFR OF THIS PIGMENT
-----------------------------
TITANIUM DIOXIDE DUSTS FROM
-----------------------------
SIGNIFICANT HAZ FOR MAN. METHYL ETHYL
-----------------------------
IN LAB ANIMALS EXPOSED FOR PRLNGD
-----------------------------
CONCS IS EXPECTED TO BE LOW DUE TO IRRIT
-----------------------------
-----------------------------
AVAILABLE.
-----------------------------
EFFECTIVE AND HOW IT IS TO BE PROPERLY FITTED.
-----------------------------
DECOMP PRODS DURING WELDING/FLAME CUTTING ON SURFS
-----------------------------
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INGEST:HARMFUL/FATAL. EYE:CAUSES IRRIT. SKIN:MAY CAUSE MOD
IRRIT. INHAL:VAP & SPRAY MIST MAY BE HARMFUL. VAP IRRITS EYES, NOSE &
THROAT. RPTD EXPOS TO HIGH VAP CONCS MAY CAUSE IRRIT OF RESP SYS & PERM
BRAIN & NERV SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHALING
CONTENTS CAN BE HARMFUL/FATAL. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZS:SIGNS & SYMPS:EYE WATERING,
HDCHS, NAUS, DIZZ & LOSS OF COORD ARE INDICATIONS THAT SOLV LEVELS ARE
TOO HIGH. REDNESS, ITCHING, BURNING SENSATION & VISUAL DISTURBS MAY
INDICATE EXCESSIVE EYE CONT. DRYNESS, ITCHING, CRACKING, BURNING, REDNESS
& SWELL ARE CNDTNS ASSOC W/EXCESSIVE SKIN CONT. CHRONIC:AVOID
First Aid: INGEST:DO NOT INDUCE VOMIT. EYE:FLUSH IMMED W/PLENTY OF WATER FOR AT
LST 15 MIN. SKIN:FLUSH IMMED W/PLENTY OF WATER FOLLOWED BY WATERLESS
HANDCLEANER & SOAP & WATER IF MATL APPEARS TO ADHERE TO SKIN.
INHAL:REMOVE TO FRESH AIR. APPLY ARTF RESP & OTHER SUPPORTIVE MEASURES AS
REQ. OTHER:IF INGEST, ANY TYPE OF OVEREXP/SYMPS OF OVEREXP OCCUR
DURING/FOLLOWING USE OF PROD, CONT POIS CTL CTR, EMER
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: PROVIDE MAX VENT. ONLY PERS EQUIPPED W/PROPER NIOSH
APPRVD RESP & SKIN & EYE PROT SHOULD BE PERMITTED IN AREA. REMOVE ALL
IGNIT SOURCES. TAKE UP SPILLED MATL W/SAWDUST, VERMICULITE/OTHER ABSORB MATL
& PLACE INTO CNTNRS FOR DISP.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE, PROVINCIAL AND LOCAL ENVIROMENTAL CONTROL REGULATIONS. EMPTY
CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WAST E
MANAGEMENT FACILITY.
Handling And Storage Precautions: DO NOT STORE >120F. STORE LARGE QTYS IN
BLDGS DESIGNED & PROTD FOR STOR OF NFPA CLASS IA FLAMMABLE LIQS.
Other Precautions: IF MATL IS PART OF MULTIPLE COMPONENT SYS, READ MSDS(S) FOR
OTHER COMPONENT/COMPONENTS BEFORE BLENDING AS RSLTING MIX MAY HAVE HAZS OF
ALL OF ITS PARTS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point Text: 15.0F,-9.4C
Lower Limits: 2.3%
Extinguishing Media: USE NATL FIRE PROT ASSOC (NFPA) CLASS B EXTINGS (CARBON
DIOXIDE, DRY CHEM/UNIVERSAL AQUEOUS FILM FORMING FOAM) (SUPDAT)
Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
WATER SPRAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED TO COOL CLSD CNTNRS TO
PVNT PRESS BUILD-UP & POSS (SUPDAT)
Unusual Fire/Explosion Hazard: KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM HEAT,
ELEC EQUIP, SPKS & OPEN FLAMES. CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. DO NOT APPLY ON HOT (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: OVEREXP TO VAPS MAY BE PVNTED BY ENSURING VENT CTLS,
VAP EXHST/FRESH AIR ENTRY. NIOSH APPRVD (TC-23C) AIR PURIFYING/AIR SUPP
(TC-19C) RESPS MAY ALSO REDUCE EXPOS. READ RESP MFR'S INSTRUCTIONS &
LITERA TURE CAREFULLY TO DETERM TYPE
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP
CONCS OF INGS BELOW LOWEST SUGGESTED EXPOS LIM,
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
WEAR PROT CLTHG INCLUDING IMPERMEABLE APRON CONSTRUCTED OF
Work Hygienic Practices: CLEAN OR DISCARD CONTAMINATED CLOTHING AND EQUIPMENT.
Supplemental Safety and Health: EXTING MEDIA:DESIGNED TO EXTING NFPA CLASS 1A
FLAM LIQ FIRES. FIRE FIGHT PROC:AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT.
IF WATER IS USED, FOG NOZZS ARE PREF. EXPLO HAZS:SURFS. TOX GASES MAY FORM W
HEN PROD IS CONTACTED BY FLAME/HOT SURFS. AEROSOL CNTNRS HOLD EXTREMELY FLAM
GAS & FLAM LIQ UNDER PRESS.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >-69F,>-56C
Vapor Pres: <74
Vapor Density: HVR/AIR
Spec Gravity: 0.7-0.8
Appearance and Odor: PRESSURIZED CAN CNTNING PAINT & PROPELLANTS W/ODOR
CHARACTS OF SOLVS IN INGS.
Percent Volatiles by Volume: 85-95
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS,
OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRDCE HAZ DECOMP PRODS WHEN HEATED.
WELDING, BRAZING/FLAME-CUTTING ON SURFS COATED W/PROD MAY PRDCE FUMES
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: QUICK DRY SPRAY ENAMEL, 55-B, 55-324
Cage: DO542
Assigned IND: Y
Company Name: PPG INDUSTRIES INC. COATINGS & RESINS GP
Street: 4325 ROSEANNA DR PO BOX 9
PO Box: 9
Zipcode: 15101
Label Required IND: Y
Date Of Label Review: 10/09/1996
Status Code: C
Label Date: 10/09/1996
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: EXTREMELY FLAMMABLE LIQUID. CLASS IA. DO NOT INGEST.
ACUTE:INGESTION:HARMFUL OR FATAL. EYE:CAUSES IRRITATION WITH REDNESS,
ITCHING, BURNING AND VISUAL DISTURBANCES. SKIN:MODERATE IRRITATION WITH DRYNE
SS, ITCHING, CRACKING, BURNING, REDNESSAND SWELLING. INHALATION:MAY BE
HARMFUL. VAPOR IRRITATES EYES, NOSE AND THROAT. HIGH VAPOR CONCENTRATIONS MAY
CAUSE IRRITATION OF RESPIRATORY SYSTEM AND PERMANEN T BRAIN AND NERVOUS
SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIB CONC & INHALINGCONTENTS CAN BE
HARMFUL/FATAL. CHRONIC:METHYL ETHYL KETONE HAS BEEN SHOWN TO CAUSE MINOR
EMBRYOTOX/FETOTOX EFTS IN LAB ANI MALS EXPOSED TO HIGH VAPOR CONCS.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:P27-219 VMK 68N PAINT ON OPAQUE, 12 GRAMS
CAGE:67251
CAGE:67251
============= Composition/Information on Ingredients =============
Ingred Name:NICKEL (SOLUBLE)
INTENDED CHANGE (IC)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: <5%
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
ACGIH TLV:0.05 MG/CUM IC (A1)
Ingred Name:VANADIUM
CAS:1314-62-1
RTECS #:YW1355000
Fraction by Wt: <5%
OSHA PEL:C,0.5 MG/M3
ACGIH TLV:0.05 MG/M3RDUST;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: <5%
OSHA PEL:15MG/M3 TDUST/5 FUME
ACGIH TLV:10MG/M3 TDUST; 9293
Ingred Name:ZIRCONIUM
CAS:7440-67-7
RTECS #:ZH7070000
Fraction by Wt: <5%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE
CAS:1344-28-1
RTECS #:BD1200000
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:BARIUM (SOLUBLE COMPOUNDS)
CAS:7440-39-3
RTECS #:CQ8370000
Fraction by Wt: <5%
OSHA PEL:0.5 MG/CUM
ACGIH TLV:0.5 MG/CUM
Ingred Name:BORON OXIDE, TRIOXIDE
CAS:1303-86-2
RTECS #:ED7900000
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
Ingred Name:CALCIUM OXIDE; LIME
CAS:1305-78-8
RTECS #:EW3100000
Fraction by Wt: <5%
OSHA PEL:5 MG/CUM
ACGIH TLV:2 MG/CUM
Ingred Name:MAGNESIUM OXIDE, MAGNESIA
CAS:1309-48-4
RTECS #:OM3850000
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 PARTICULATE
ACGIH TLV:10 MG/M3;TDUST; 9293
Ingred Name:SILICA, CRYSTALLINE - FUSED
CAS:60676-86-0
RTECS #:VV7328000
Fraction by Wt: <5%
Other REC Limits:30 MG/CUM TOTAL DUST
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:TIN (AS SN)
CAS:7440-31-5
RTECS #:XP7320000
Fraction by Wt: <5%
OSHA PEL:2.0 MG/CUM
ACGIH TLV:2.0 MG/CUM
Ingred Name:TITANIUM DIOXIDE, TITANIUM(IV) OXIDE, TIO2
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN
CARCINOGEN BY IARC, NTP & ACGIH)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: <5%
OSHA PEL:1 MG/CUM
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:COBALT
CAS:7440-48-4
RTECS #:GF8750000
Fraction by Wt: <5%
Other REC Limits:0.05 PPM
OSHA PEL:0.1 MG/M3;AS CO
ACGIH TLV:0.05 MG/M3;DUST 9293
Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC
OXIDE/METAL OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT/IRON
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: <5%
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 9293
Ingred Name:MANGANESE, MN COMPOUNDS
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: <5%
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Explanation of Carcinogenicity:CHROMIUM IS A SUSPECTED A1 HUMAN
CARCINOGEN BY ACGIH.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP SPILLED MATERIAL.
======================Handling and Storage ======================
Other Precautions:AVOID BREATHING CERAMIC DUST. AVOID LICKING CERAMIC
APPLICATION BRUSH.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NUISANCE DUST MASK RECOMMENDED WHILE GRINDING
FIRED PORCELAIN.
Ventilation:MECHANICAL EXHAUST
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>2192F
Melt/Freeze Pt:M.P/F.P Text:1760F
Evaporation Rate & Reference:0
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE OR LIGHT PASTEL COLORED PORCELAIN POWDER W/NO
ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
HYDROFLUORIC ACID
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE AS SOLID WASTE IN ACCORDANCE W/LOCAL,
STATE, & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:834G080 DES 420HS 11136 GLOSS
Kit Part:Y
CAGE:83574
CAGE:83574
============= Composition/Information on Ingredients =============
Ingred Name:XYLENE (SARA 313) (CERCLA) VP 6.6
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/STEL 150
ACGIH TLV:100 PPM STEL 150
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL AMYL KETONE VP 2.1
CAS:110-43-0
RTECS #:MJ5075000
Fraction by Wt: 20.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:50 PPM
Ingred Name:BIS(1,2,2,6,6-PENTAMETHYL-4-PIPERIDINYL) SEBACATE VP 0
CAS:41556-26-7
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
Ingred Name:BENZOTRIAZOLE DERIVATIVE
CAS:127519-17-9
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
Ingred Name:METHYL N-PROPYL KETONE (2-PENTANONE) VP 27.8
CAS:107-87-9
RTECS #:SA7875000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/STEL 250
ACGIH TLV:200 PPM/STEL 250
Ingred Name:METHYL ETHYL KETONE (MEK) (SARA 313) (CERCLA) VP 70
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/STEL 300
ACGIH TLV:200 PPM/STEL 300
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TOLUENE (SARA 313) (CERCLA) VP 23
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <1.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/STEL 150
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:POLYESTER RESIN (NON-HAZARDOUS
CAS:85959-88-2
Other REC Limits:NONE RECOMMENDED
Ingred Name:PYRROLOPYRROL NON-HAZARDOUS
CAS:84632-65-5
Other REC Limits:NONE RECOMMENDED
Ingred Name:C.I. PIGMENT YELLOW 83 NON-HAZARDOUS
CAS:5567-15-7
Other REC Limits:NONE RECOMMENDED
Ingred Name:BARIUM SULFATE NON-HAZARDOUS
CAS:7727-43-7
RTECS #:CR0600000
Other REC Limits:NONE RECOMMENDED
Ingred Name:VOC = 419 GR/L MIXED WITH 930G017 @ 1/1
RTECS #:9999999VO
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: BURNING, TEARING, REDDENING,
IRRIT, TRANSIENT CORNEAL CLOUDING. SKIN: DRYING, CRACKING,
DERMATITIS. MAY BE ABSORBED THROUGH SKIN. INHAL: DIZZY, DROWSY,
FATIGUE, IRRIT, COUGHING, CHEST PAINS, THR OAT IRRIT, HEADACHE,
ANESTHETIC, CNS EFFECTS, LIVER DAMAGE. INGEST: DIZZY, DROWSY,
NAUSEA, MEMORY DISTURBANCE,THINKING *
Explanation of Carcinogenicity:NO
Effects of Overexposure:* ABILITY, EMOTIONS, COORDINATION.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/WATER 15 MINUTES, GET MED AID. SKIN: WASH W/SOAP
& WATER, DONT USE SOLVENTS. REMOVE CONTAM CLOTHING, WASH BEFORE
REUSE, GET MED AID. INHAL: REMOVE TO FRESH AIR. GIVE ARTIF RESP/CPR
IF BRE ATHING DIFFICULT, GET MED AID. INGEST: GET MED AID.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:65.0F,18.3C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WATER SPRAY INEFFECTIVE. COOL FIRE EXPOSED
CONTAINERS W/WATER. FOG NOZZLES PREFERRED. WEAR NIOSH/MSHA SCBA.
PROTECTIVE CLOTHING. PREVENT CONTACT SKIN/EYES.
Unusual Fire/Explosion Hazard:VAPORS MAY ACCUMULATE, FORM EXPLOSIVE
MIXTURES, TRAVEL, FLASH BACK OR FLAME MAY OCCUR. CLOSED CONTAINERS
MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:PROTECT FROM IGNITS. WEAR AIR-SUPPLIED
RESPIRATOR. COVER W/ABSORBENT MATERIAL. SCOOP INTO CONTAINER.
CLEAN RESIDUE W/SUITABLE SOLVENT. CERCLA RQ FOR XYLENE 1000 LBS.
CERCLA RQ FOR MEK 5000 LBS. CERCL A RQ FOR TOLUENE 1000 LBS.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE
FROM HEAT, SPARKS, OPEN FLAME AND ELECTRICAL EQUIP. DONT STORE
>120F.
Other Precautions:EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DO NOT
CUT/PUNCTURE/WELD. VAPORS >AIR, MAY COLLECT IN LOW/CONFINED AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:LIKELY TO PRODUCE AIRBORNE LEVELS OF HAZARDOUS
INGREDIENTS IN EXCESS OF TLV. USE ORGANIC VAPOR CARTRIDGE OR
AIR-SUPPLIED RESPIRATOR.
Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW TLV AND PEL.
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:SAFETY SHOWER, EYEBATH AND WASHING FACILITIES
SHOULD BE AVAILABLE.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:175 TO 300F
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NA
Vapor Pres:NA
Vapor Density:>AIR
Spec Gravity:1.172
pH:NA
Evaporation Rate & Reference:NA
Solubility in Water:NA
Appearance and Odor:RED LIQUID, SOLVENT ODOR.
Percent Volatiles by Volume:39.7
Corrosion Rate:NA
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:IN ACCORDANCE W/FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: OFFSET SHEETFED LOW VOC PRINTING INKS, 8, NS50
Cage: 0WUD3
=======================================================
Contractor Summary
=======================================================
Cage: 0WUD3
=======================================================
Ingredients
=======================================================
Cas: 64742-46-7
RTECS #: JN9379645
(HYDROTREATED MIDDLE DISTILLATE, LITHOGRAPHIC OIL))
% Wt: 4.69
OSHA PEL: 5 MG/M3 (MFR)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 8030-70-4
% Wt: 2
OSHA PEL: 1 MG MN/M3
ACGIH TLV: 1 MG MN/M3
------------------------------
% Wt: 1
OSHA PEL: 0.01 MG/M3 (MFR)
ACGIH TLV: 0.01 MG/M3 (MFR)
-----------------------------
Cas: 5160-02-1
RTECS #: DB5500000
NAPHTHALENYL)AZO)-4-METHYL-, BARIUM SALT; (BARIUM COMPOUND)
% Wt: 27.50
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
-----------------------------
RTECS #: 9999999VO
(VOC LESS WATER & E.S.)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHALATION: MAY CAUSE HEADACHE, DIZZINESS,
DROWSINESS AND NAUSEA. SKIN/EYES: MAY CAUSE LOCAL IRRITATION. SKIN
ABSORPTION: MAY CAUSE MINOR DERMATITIS. MAY CAUSE GASTRIC DISTURBANCES.
CHRONIC: NO T KNOWN.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHALATION: REMOVE FROM EXPOSURE. SKIN: WASH WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES.
CONTACT MD. INGESTION: IF SWALLOWED DO NOT INDUCE VOMITI NG. DRINK LARGE
QUANTITIES OF WATER ANDCONSULT MD IMMEDIATELY.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: WIPE UP, DISPOSE OF WIPERS IN CONTAINERS APPROVED FOR
OILY WASTES.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: STORE IN SEALED CONTAINERS. KEEP AWAY FROM
HEAT, SPARKS, AND OPEN FLAMES.
Other Precautions: DO NOT STORE IN UNMARKED CONTAINERS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: >200F,>93C
Extinguishing Media: USE FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE INEFFECTIVE BUT CAN BE USED TO COOL CONTAINERS
EXPOSED TO HEAT OR FLAME.
Unusual Fire/Explosion Hazard: MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE,
DENSE SMOKE ON BURNING.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE REQUIRED. USE NIOSH/MSHA APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: GENERAL PLAIN VENTILATION.
Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >510F,>266C
Vapor Density: HVR/AIR
Spec Gravity: 1.09 (FP N)
Evaporation Rate & Reference: SLOWER THAN BUTYL ACETATE
Appearance and Odor: CLEAR OR COLORED PASTE, WITH HYDROCARBON ODOR
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: KEEP FROM HEAT, SPARKS, AND OPEN FLAMES.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: OFFSET SHEETFED LOW VOC PRINTING INKS, 8, NS50
Cage: 0WUD3
Company Name: INX INTERNATIONAL INK CO
Street: 7401-A MORTON AVE
Zipcode: 94560
Label Required IND: Y
Date Of Label Review: 10/30/1995
Status Code: C
Label Date: 10/30/1995
Origination Code: G
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: INHALATION: MAY CAUSE HEADACHE,
DIZZINESS, DROWSINESS AND NAUSEA. SKIN/EYES: MAY CAUSE LOCAL IRRITATION. SKIN
ABSORPTION: MAY CAUSE MINOR DERMATITIS. MAY CAUSE GASTRIC DISTURBANCES .
CHRONIC: NOT KNOWN.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MOORGARD LATEX HOUSE PAINT, 103-48
CAGE:09585
CAGE:09585
CAGE:91950
============= Composition/Information on Ingredients =============
Ingred Name:SILICA, CRYSTALLINE - QUARTZ. % WT: 4.5-15.1
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: SEE ING
OSHA PEL:0.1 MG/M3 RDUST
ACGIH TLV:0.1 MG/M3 RDUST
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: 2.5% MAX
OSHA PEL:10MG/M3 TDUST;5 RESP
ACGIH TLV:10MG/M3 TDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: IRRITATION OF
RESPIRATORY TRACT. SKIN/EYE: PRIMARY IRRITATION. INGESTION OF LARGE
AMOUNTS COULD CAUSE SERIOUS INJURY. CHRONIC: NONE KNOWN.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
MONOGRAPHS, SUPPLEMENT. VOL 7, PG 341, 1987: GRP 2A. NTP 6TH ANNUAL
REPORT (SUPP DATA)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE EXPECTED WHEN USED I/A/W SAFE
HANDLING AND USE INFORMATION.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. GET MEDICAL HELP FOR ANY
BREATHING DIFFICULTY. EYE: FLUSH THORO WITH WATER FOR AT LEAST 15
MINUTES. CALL PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. INGEST:
DRINK 1-2 GLASSE S OF WATER TO DILUTE. DO NOT INDUCE VOMITING. CALL
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>250F,>121C
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . COOL EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST IF EXPOSED TO
EXTREME HEAT/FIRE. TOXIC GASES MAY FORM WHEN PRODUCT BURNS.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH W/WATER. ABSORB WITH SAWDUST/RAGS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT THROW OR DROP CONTAINERS.
Other Precautions:AVOID CONT W/EYES AND PROLONGED CONTACT W/SKIN OR
BREATHING OF SPRAY MIST/SANDING DUST. CLOSE CONTAINER AFTER EACH
USE. KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR SPECIFIED FOR
PROTECTION AGAINST PAINT SPRAY PAINT AND SANDING DUST IN RESTRICTED
OR CONFINED AREAS.
Ventilation:ADEQUATE TO MAINTAIN WORKING ATM BELOW TLV & LEL.
MECHANICAL EXHAUST MAY BE REQUIRED IN CONFINED AREAS.
Other Protective Equipment:CLOTHING ADEQUATE TO PROTECT SKIN.
Work Hygienic Practices:REMOVE AND WASH CLOTHING BEFORE REUSE. WASH
HANDS BEFORE EATING, SMOKING OR USING WASHROOM.
Supplemental Safety and Health
% VOLAT: 60.9-69.4. EXPLAN OF CARCIN: ON CARCIN, 1991: ANTIC TO BE
CARCINOGEN.
================== Physical/Chemical Properties ==================
Vapor Density:HVR/AIR
Spec Gravity:1.17-1.28
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:ELEVATED TEMPERATURES.
Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON DIOXIDE AND
CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONVENTIONAL PROCEDURES IN COMPLIANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. DO NOT INCINERATE SEALED
CONTAINERS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RX 7200 TONER
CAGE:S5212
CAGE:S5212
CAGE:S0167
============= Composition/Information on Ingredients =============
Ingred Name:SILICON DIOXIDE (AMORPHOUS)/HYDROPHOBIC SILICON
CAS:67762-90-7
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
Ingred Name:POLYESTER RESIN
Fraction by Wt: >90%
Other REC Limits:NONE SPECIFIED
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9192
Ingred Name:ORGANIC PIGMENT/METAL COMPLEX
CAS:31714-55-3
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
Ingred Name:POLYOLEFIN/POLYPROPYLENE
CAS:9003-07-0
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE- EYE/SKIN:IRRITATION.
INHALATION:IRRITATION OF MUCOUS MEMBRANES. ORAL:UNKNOWN. CHRONIC-
NOT KNOWN.
Effects of Overexposure:EYE AND SKIN:IRRITATION. INHALATION CAUSES
IRRITATION OF MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH SENSITIVE SKIN MAY
BE MORE ADVERSELY AFFECTED.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:FLUSH WITH
PLENTY OF WATER. SKIN:FLUSH WITH PLENTY OF SOAP AND WATER.
INHALATION:REMOVE TO FRESH AIR. INGESTION:SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:AS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:DUST EXPLOSION HAZARD MAY BE CREATED IF
DUST BECOMES AIRBORNE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. CAREFULLY SWEEP UP AND
TRANSFER TO A CONTAINER FOR LATER DISPOSAL. AVOID GENERATING DUSTS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE- STORE IN TIGHTLY CLOSED
CONTAINER.
Other Precautions:WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WITH GOOD VENTILATION.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT.
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.2
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK, ODORLESS POWDER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:FIRE, EXCESSIVE HEAT
Hazardous Decomposition Products:DUST EXPLOSION HAZARD MAY BE CREATED
IF DUST BECOMES AIRBORNE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE OR LOCAL LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SATIN CAST 20 H T
CAGE:FO551
CAGE:FO551
CAGE:6J081
============= Composition/Information on Ingredients =============
Ingred Name:SILICA CRYSTALLINE, SILICA (CRISTOBALITE) (SUSPECTED HUMAN
CARCINOGEN BY IARC, SUSP CARC BY NTP; IARC GROUP 2A) *97-2*
CAS:14464-46-1
RTECS #:VV7325000
Fraction by Wt: 45-50%
Other REC Limits:0.05 MG/CUM NIOSH
OSHA PEL:0.05 MG/CUM
ACGIH TLV:0.05 MG/CUM
Ingred Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN
CARCINOGEN BY IARC-GROUP 2A; SUSPECTED CARCINOGEN NTP) *97-2*
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 25-30%
Other REC Limits:0.05 MG/CUM (NIOSH)
OSHA PEL:0.1 MG/CUM RESP DUST
ACGIH TLV:0.1 MG/CUM RESP DUST
Ingred Name:CALCIUM SULFATE; GYPSUM
CAS:7778-18-9
RTECS #:WS6920000
Fraction by Wt: 25-30%
Other REC Limits:5 MG/CUM (DUST)
OSHA PEL:5 MG/CUM
ACGIH TLV:10 MG/CUM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION.
INHALATION: PROLONGED EXPOSURE TO RESPIRABLE CRYSTALLINE SILICA MAY
CAUSE SILICOSIS. INGESTION: HARDENS WHEN WETTED & MAY CAUSE AN
OBSTRUCTION.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, DRY FEELING ON SKIN.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY WASH W/LARGE AMOUNTS OF WATER. SKIN: WASH
W/SOAP & WATER. USE HAND LOTION. INHALATION: REMOVE TO FRESH AIR.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Unusual Fire/Explosion Hazard:SILICA WILL DISSOLVE IN HYDROFLUORIC ACID
& PRODUCE CORROSIVE SILICON TETRAFLUORIDE GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. SWEEP UP. AVOID UNNECESSARY
STIRRING/HANDLING IN ORDER TO PREVENT FORMATION OF DUST.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T BREATHE DUST. KEEP CONTAINER
CLOSED. FOLLOW PRESCRIBED MIXING PROCEDURE FOR KERR INVESTMENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPROVED EQUIPMENT.
Ventilation:LOCAL EXHAUST: SUFFICIENT TO REDUCE LEVEL OF RESPIRABLE
CRYSTALLINE SILICA TO PEL.
Work Hygienic Practices:HANDLE IAW/GOOD PERSONAL HYGIENE & SAFETY
PRACTICES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:2.4
Solubility in Water:SLIGHT
Appearance and Odor:OFF-WHITE POWDER W/NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
HYDROFLUORIC ACID.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:BY CONTACT W/HYDROFLUORIC ACID:
SILICON TETRAFLUORIDE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A LANDFILL IAW/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ZIRCONIUM SPONGE
CAGE:1B843
CAGE:1B843
============= Composition/Information on Ingredients =============
Ingred Name:ZIRCONIUM
CAS:7440-67-7
RTECS #:ZH7070000
Fraction by Wt: >99%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3;10 STEL
Ingred Name:SUPP DATA:INCLUDING CARBON TETRACHLORIDE, FREONS & TEFLON.
NITRYL FLUORIDE, FNO*2 WILL INITIATE RXN W/ZIRCONIUM (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:METAL AT ROOM TEMPERATURE TO PRODUCE A GLOWING OR
WHITE INCANDESCENCE.
RTECS #:9999999ZZ
Ingred Name:HAZ DECOMP PROD:HYDROGEN, TOXIC FUMES OF NITROGEN OXIDE, OR
CORROSIVE ZIRCONIUM HALIDE VAPORS.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:AVOID ACCUMULATION OF FLAMMABLE DUST.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ZIRCONIUM METAL IS NON-TOXIC. AS A
RESULT OF STUDIES COVERING SEVERAL ZIRCONIUM COMPOUNDS, ZIRCONIUM
WAS CONCLUDED TO BE AN ELEMENT OF LOW TOXICITY.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH
W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM
MD. NORMAL PROCEDURE FOR FOREIGN OBJECT. SKIN:FLUSH W/COPIOUS
AMOUNTS OF WATER. CALL MD . NOTES TO MD:NO SPECIAL PROCEDURE.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY TABLE SALT OR TYPE D FIRE EXTINGUISHER.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
ISOLATE BURNING SPONGE. IT IS ADVISABLE TO ALLOW LG FIRE TO BURN
OUT, KEEPING FIRE FROM SPREADING. SM (SUPDAT)
Unusual Fire/Explosion Hazard:DO NOT SPRAY WATER ON BURNING SPONGE AS
VIOLENT EXPLO MAY OCCUR. THIS EXPLO CHARACT IS CAUSED BY HYDROGEN &
STEAM GENERATED BY RXN OF WATER W/BURNING (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:NO SPECIAL PROCEDURES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID IGNIT SOURCES & HIGH TEMPS. LONG
TERM STOR SHOULD BE IN ARGON-FILLED STEEL DRUMS W/TIGHT FITTING
CLAMP-ON SEALABLE LIDS. KEEP DRY. FLAMM SOLID.
Other Precautions:ALL HNDLG & STOR AREAS SHOULD BE CLEARLY POSTED
W/"HOT WORK AREA PERMIT" SIGNS. MOISTURE CREATES EXPLO HAZ IF
SPONGE IS IGNITED. EVALUATE EACH SITUATION FOR POSSIBILITY OF FLASH
BURNS. WORK AREAS MUST BE PERIODICALLY CLEANED TO (ING 5)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NOT APPLICABLE.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
% VOLAT:NON-VOLATILE. FIRE FIGHT PROC:FIRE CAN BE CONTROLLED BY
SMOTHERING W/DRY TABLE SALT/USING TYPE D DRY-POWDER FIRE EXTING
MATL. EXPLO HAZ:MATL. CARBON DIOXIDE IS NOT EFTIVE IN EXTING
BURNING ZIR CONIUM. MATLS TO AVOID:REACTS EXOTHERMICALLY W/HALOGEN
GASES, FLUORINE, CHLORINE, BROMINE, IODINE & HALOCARBONS, (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:7911F,4377C
Melt/Freeze Pt:M.P/F.P Text:3366F,1852C
Vapor Pres:0 @ 20C
Spec Gravity:6.49 (H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:METALLIC GREY CHUNKS; ODORLESS.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ZIRCONIUM METAL IS RAPIDLY DISSOLVED BY HYDROFLUORIC
ACID/HYDROFLUORIC-NITRIC ACID MIXTS. ABOVE 200C, ZIRCONIUM (SUPDAT)
Stability Condition to Avoid:AVOID HIGH TEMPERATURES, SOURCES OF
IGNITION.
Hazardous Decomposition Products:ZIRCONIUM METAL DOES NOT DECOMPOSE.
ABOVE RXNS W/INCOMPAT MATLS WILL GENERATE HAZ RXN PRODS SUCH AS
FLAMM (ING 4)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . NON-RECYCLABLE SPONGE SHOULD BE BURNED IN SMALL
QUANTITIES UNDER CONTROLLED CONDITIONS. RESULTING ZIRCONIUM OXIDE
IS INERT & MAY BE DE POSITED IN A LANDFILL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BRAYCO 421 MIL-L-2184C,OE/HDO-LO GRADE 10
CAGE:KO518
CAGE:KO518
DIV
CAGE:2R128
============= Composition/Information on Ingredients =============
Ingred Name:REFINED PETROLEUM LUBE OIL STOCK
===================== Hazards Identification =====================
Effects of Overexposure:NOT EXPECTED TO CAUSE ANY ILL EFFECT EXCEPT IN
VERY SENSITIVE INDIV. MAY CAUSE EYE IRRIT.
======================= First Aid Measures =======================
First Aid:EYE: IMMED FLUSH W/WATER AT LEAST 15 MIN, CALL MD. SKIN: WASH
THOROUGHLY W/MILD SOAP & WATER. INGEST: DO NOT INDUCE VOMIT, CALL
MD.
===================== Fire Fighting Measures =====================
Flash Point:400F COC
Extinguishing Media:DRY CHEM, CO*2, FOAM, WATER FOG
Fire Fighting Procedures:USE SELF-CNTND RESP EQUIP IN CONFINED AREA
Unusual Fire/Explosion Hazard:DO NOT USE WATER EXCEPT AS FOG, OR SPRAY
TO COOL CNTNRS OR TANKS TO AVOID HEATING ABOVE FLASH PT.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP FLOW & SHUT OFF SOURCES OF IGNITION. WIPE
OR MOP UP, OR ABSORB W/CLAY, DIATOMACEOUS EARTH, OR OTHER INERT
MATL. STORE IN CLOSED METAL CNTNRS.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE NEAR HEAT, OPEN FLAME, OR
OTHER SOURCES OF IGNIT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQ EXCEPT IF OIL MIST EXCEEDS TLV.
NIOSH/MSHA APPRVD IF NEC.
Ventilation:LOCAL EXHST & MECH, ONLY IF OIL MIST EXCEEDS TLV
Supplemental Safety and Health
MFR STATES PRODUCT IS NON-HAZARDOUS AS DEFINED BY U.S. DEPT. OF LABOR
29CFR,SECTION 1915.2.
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:>500F
Spec Gravity:0.881
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK OILY LIQ, PETROLEUM ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:COMBUSTION MAY PROD CARBON MONOXIDE &
ASPHYXIANTS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED INCINERATION OR METHOD IAW LOCAL,
STATE, FED REG
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ALOX 2028C
CAGE:60773
CAGE:60773
============= Composition/Information on Ingredients =============
Ingred Name:ALIPHATIC MINERAL SPIRITS, CAS# 64742-88-7
Fraction by Wt: 50%
ACGIH TLV:100 PPM
Fraction by Wt: 50%
Ingred Name:**NEUTRALIZED W/BARIUM, THEN BLENDED W/BA SULFONATE &
MINERAL SPIRITS. BARIUM COMPOUNDS (4% IN NON-MINERAL SPIRITS. ***
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED
Ingred Name:***PORTION, 2% IN ALOX 2028C) ARE NOT WATER SOLUBLE).
RTECS #:9999999ZZ
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Effects of Overexposure:INHAL:NAUS,DIZZ,NOSE,THROAT IRRIT,WATERING
EYES.INGEST:IRRIT,VOMIT,DIARR,NAUS.SKIN:HOT MATRL BURNS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR,TREAT SYMPTOM.GIVE O*2 IF BREATH
IMPAIRED.EYE:FLUSH W/ WATER FOR AT LEAST 15 MIN.CALL MD.SKIN:WASH
W/ SOAP & WATER.TREAT BURNS FROM HOT MATRL AS THERMAL
BURNS.INGEST:DO NOT I NDUCE VOMIT.CALL MD.
===================== Fire Fighting Measures =====================
Flash Point:142F,61C TCC
Extinguishing Media:CO*2,DRY CHEMICAL,WATER FOG
Fire Fighting Procedures:DO NOT USE H*2O EXCEPT AS FOG OR TO COOL
CONTNR,FLUSH SPILL
Unusual Fire/Explosion Hazard:WATER STREAMS ON BURNING MATERIAL MAY
SPREAD FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:ATTEMPT TO RECOVER.KEEP PETROLEUM PRODUCTS OUT
OF STREAMS AND WATERWAYS.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID PRLG/RPTD CONTACT.KEEP
CONTAINERS CLOSED WHEN NOT IN USE.WASH BEFORE EATING,SMOKING OR
USING TOILET.WASH SATURATED CLOTHING BEFORE REUSE.
Other Precautions:IF INGESTION & VOMITING OCCURS,MONITOR PATIENT FOR 48
HOURS FOR BREATHING DIFFICULTIES.
============= Exposure Controls/Personal Protection =============
Ventilation:LOCAL EXHAUST PREFERRED
Other Protective Equipment:AS NEEDED TO PROTECT AGAINST HOT
PROD,RPTD/PRLG CONTACT.
Supplemental Safety and Health
MSDS PREP:86197.SPEC TYPE 2 AND CLASS 2.
================== Physical/Chemical Properties ==================
HCC:V2
Boiling Pt:B.P. Text:>302F,>150C
Vapor Pres:<1
Vapor Density:>1
Spec Gravity:0.86
Evaporation Rate & Reference:<1(BUAC=1)
Solubility in Water:NIL
Appearance and Odor:BROWN FLUID W/ THE ODOR OF MINERAL SPIRITS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:TEMPERATURE ABOVE FLASH POINT AND OPEN
FLAMES.
Hazardous Decomposition Products:UNDEFINED ORGANICS,CO,CO*2,OXIDES OF
SULFUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTAINS 2.0% BARIUM.DISPOSE OF AS REQUIRED BY
LOCAL,STATE & FEDERAL REGULATIONS FOR MATERIALS CONTAINING
EXTRACTABLE BARIUM.U.S.EPA-RCRA HAZARDOUS WASTE NUMBER D005.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ACROBE BIOLARVICIDE
CAGE:95416
CAGE:95416
============= Composition/Information on Ingredients =============
Ingred Name:BACTERIA
Fraction by Wt: 1.2%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RATS): >5,000 MG/KG
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:LIKE ALL FORMS OF RESPIRABLE FOREIGN
PROTEIN, THIS MATERIAL WOULD HAVE POTENTIAL FOR CAUSING PULMONARY
SENSITIZATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:LIKE ALL FORMS OF RESPIRABLE FOREIGN PROTEIN,
THIS MATERIAL WOULD HAVE POTENTIAL FOR CAUSING PULMONARY
SENSITIZATION.
Medical Cond Aggravated by Exposure:ALLERGIC BRONCHIAL ASTHMA, CHRONIC
OBSTRUCTIVE PULMONARY DISEASE & ANY IMMUNE DEFICIENCY
DISEASE/STATE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/PHYSIOLOGICAL
SALINE SOLUTION FOR 5 MINS. SKIN: WASH W/PLENTY OF SOAP & WATER.
OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTES TO PHYSICIAN: THIS
MATERIAL C ONTAINS VIABLE SPORES. ALTHOUGH B. THURINGIENSIS ISN'T
NORMALLY PATHOGENIC TO MAN, INHALATION OF MIST CONTAINING HUGE
CONCENTRATIONS OF SPORES MAY CAUSE INFECTION ESPECIALLY IN THE
IMMUNE-IMPAIRED.
===================== Fire Fighting Measures =====================
Extinguishing Media:MATERIAL WILL NOT BURN.
Fire Fighting Procedures:WEAR SELF CONTAINED, POSITIVE PRESSURE
BREATHING APPARATUS & FULL PROTECTIVE CLOTHING. KEEP PEOPLE AWAY.
CONTROL RUNOFF WATER FROM ENTERING DRAINAGE SYSTEM.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/INERT MATERIAL, SUCH AS CLAY & PLACE
IN A CONTAINER FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:TIGHTLY RECLOSE CONTAINERS OF UNUSED
MATERIAL. STORE IN A SECURE, COOL, DRY, WELL-VENTILATED ROOM,
BUILDING/COVERED AREA. STORE <85F.
Other Precautions:DON'T ALLOW PRODUCT TO FREEZE. NOT FOR USE/STORAGE
IN/AROUND THE HOME. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT
W/SKIN, EYES/CLOTHING. AVOID BREATHING SPRAY MIST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE APPROPRIATE RESPIRATOR TO AVOID INHALATION
OF MISTS, FUMES/DUST.
Ventilation:RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY W/SOAP & WATER AFTER HANDLING.
DON'T EAT, SMOKE/DRINK AT WORKPLACE.
Supplemental Safety and Health
DON'T CONTAMINATE WATER, FOOD/FEED BY STORAGE/DISPOSAL. PH: 4.2-4.5.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Spec Gravity:1.05
pH:(SUPP)
Solubility in Water:INSOLUBLE
Appearance and Odor:LIGHT TAN LIQUID W/SLIGHTLY ACIDIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:FREEZING, DIRECT SUNLIGHT, TEMP >110F
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL OF EMPTY CONTAINERS BY INCINERATION IS
RECOMMENDED SINCE THE CONTAINERS WILL NOT READILY BIODEGRADE UNDER
LANDFILL CONDITIONS. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FEL-PRO C-300 PART NO: 51028, 51029, 51030
Preparer's Name:DIANE L. GALLAGHER
CAGE:73165
CAGE:73165
============= Composition/Information on Ingredients =============
Ingred Name:AROMATIC PETROLIUM DISTILLATE
CAS:64742-92-6
Fraction by Wt: 35-45%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
Ingred Name:TOLUENE (SARA 313)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <5.0%
Other REC Limits:STEL 150
OSHA PEL:200 PPM
ACGIH TLV:100 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:MOLYBDENUM DISULFIDE
CAS:1317-33-5
RTECS #:QA4697000
Fraction by Wt: 10-20%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:NON-HAZARDOUS INGREDIENT
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: IRRIT, RED, TEARING, BLURRED
VISION. SKIN: REDNESS, TRANSIENT IRRIT, DEFATTING, DERMATITIS.
INHAL: DIZZY, HEADACHE, NAUSEA.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/TEPID WATER FOR 15 MINUTES, LIFTING LIDS APART.
GET MED AID. SKIN: WASH W/SOAP & WATER. GET MED AID. INHAL: GET
FRESH AIR. KEEP WARM/QUIET, GET MED AID.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:85.0F,29.4C
Lower Limits:1.0
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Unusual Fire/Explosion Hazard:>750F IN PRESENCE OF OXYGEN, MATERIAL MAY
DECOMPOSE TO FORM SULFUR OXIDES.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE IGNITS. VENT AREA. WIPE UP W/RAGS,
ABSORBENT MATERIAL. COMPLETE CLEANUP W/DETERGENT & WATER OR HIGH
FLASH POINT SOLVENT CLEANER W/ADEQUATE VENT.
======================Handling and Storage ======================
Handling and Storage Precautions:USE NORMAL STORAGE/HANDLING. DONT
EXPOSE TO HIGH HEAT, OPEN FLAMES OR STRONG OXIDIZERS.
Other Precautions:KEEP AWAY FROM CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR
RESPIRATOR, IF VENTILATION IS ADEQUATE.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL)
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:290F,143C
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Pres:4 @ 58F
Vapor Density: 4.1
Spec Gravity:1.30
Evaporation Rate & Reference:0.6 (BUAC = 1)
Solubility in Water:INSOLUBLE
Appearance and Odor:DARK GRAY PASTE, AROMATIC SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, PEROXIDES, PERMANGANATES, NITRIC ACIDS, ETC.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:PYROLYSIS, MAY YIELD CO, CO2. IN
COMPLETELY BURNED HYDROCARBONS & POSSIBLE SOX >750.
==================== Disposal Considerations ====================
Waste Disposal Methods:USE CONTROLLED INCINERATION OR BURY IN POSTED
TOXIC SUBSTANCE LANDFILL IN ACCORDANCE W/FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:17A MARKING PAINT-ALL COLORS 265 ORANGE/INVERT A-CAP
Preparer's Name:MIKE A TRAQUINA
CAGE:0UPL1
CAGE:0UPL1
============= Composition/Information on Ingredients =============
Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS
*98-1*
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: <5%
Other REC Limits:525 MG/CUM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:PROPANE (DIMETHYLMETHANE)*98-1*
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 15%
Other REC Limits:1800 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:ISOBUTANE, 2-METHYLPROPANE
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: <5%
Other REC Limits:1000 PPM
OSHA PEL:1800 MG/CUM
ACGIH TLV:1000 PPM
Ingred Name:BUTANE, N-BUTANE *98-1*
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 5%
Other REC Limits:800 PPM
OSHA PEL:800 PPM
ACGIH TLV:1900 MG/CUM
Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *98-1*
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 13%
Other REC Limits:100 PPM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM, SKIN
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE *98-1*
CAS:64742-89-8
Fraction by Wt: 20%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 4300 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: IRRITATION/DERMATITIS. EYES:
IRRITATION. INHALATION: ANESTHETIC, IRRITATION OF THE RESPIRATORY
TRACT/NERVOUS DEPRESSION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:DIZZINESS, NAUSEA, IRRITATION, BURNING
SENSATION, HEADACHE, NAUSEA, UNCONSCIOUSNESS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR & RESTORE BREATHING. SKIN:
WASH AREA. EYES: FLUSH W/WATER FOR 15 MINS. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-250F
Lower Limits:0.7
Upper Limits:9.5
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE, BUT WATER
SPRAY MAY BE USED TO COOL CONTAINERS EXPOSED TO HEAT/FIRE TO
PREVENT PRESSURE BUILD UP.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO
BUILDUP OF PRESSURE FROM EXTREME HEAT/FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE AREA &
SOAK UP W/INERT ABSORBENT USING NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE >120F. DON'T STORE/USE
NEAR HEAT, SPARKS/FLAME.
Other Precautions:DON'T GET IN EYES. DON'T BREATHE VAPORS. AVOID SKIN
CONTACT. DON'T TAKE INTERNALLY. SMOKING IS PROHIBITED. DUST FROM
SANDING THE DRY PAINT FILMS SHOULD BE TREATED AS A NUISANCE DUST
W/A TLV OF 10MG/CM . AVOID PROLONGED/REPEATED CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:OUTDOORS, WE RECOMMEND AN APPROVED PARTICULITE
FILTER TO REMOVE ANY AIRBORNE OVERSPRAY. IN RESTRICTED AREAS, A
NIOSH APPROVED RESPIRATOR W/ORGANIC VAPOR CARTRIDGE IS RECOMMENDED.
Ventilation:ADEQUATELY: IN ORDER TO KEEP BELOW EXPOSURE LIMITS.
Other Protective Equipment:IMPERVIOUS APRON, EYE WASH FOUNTAIN & SAFETY
SHOWER.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:100F
Vapor Density:>1
Spec Gravity:0.8
VOC Grams/Liter:4.7
Evaporation Rate & Reference:FASTER THAN N-BU AC
Solubility in Water:NEGLIGIBLE
Appearance and Odor:OPAQUE LIQUID W/SOLVENT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH TEMPS.
Hazardous Decomposition Products:CO, CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T INCINERATE CLOSED CONTAINERS. UN1950.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:COPPER/COPPER ALLOYS FREE CUTTING BRASS, C3
CAGE:0PAZ9
CAGE:0PAZ9
============= Composition/Information on Ingredients =============
Ingred Name:COPPER
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 61.50%
OSHA PEL:1 MG/M3 DUST
ACGIH TLV:1 MG/M3 DUST
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ZINC OXIDE. PEL: 10 MG/M3 TDUST; 5 MG/M3 RDUST
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: 35.25%
OSHA PEL:15MG/M3 TDUST/5 FUME
ACGIH TLV:10MG/M3 TDUST; 9293
Ingred Name:LEAD
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 3.25%
OSHA PEL:0.05 MG/M3
ACGIH TLV:0.15 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:UNDER NORMAL HANDLING CONDITIONS THE
SOLID ALLOY PRESENTS NO SIGNIFICANT HEALTH HAZARDS. PROCESSING OF
ALLOY BY DUST OR FUME PRODUCING OPERATION (GRINDING, BUFFING,
HEATING, WELDING, ETC.) MAY RESULTIN POTENTIAL FOR EXPOSURE TO
AIRBORNE METAL PARTICULATES OR FUME. THE EXPOSURE LEVELS IN
INGREDIENTS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:INORGANIC LEAD-IARC GROUP 2B.
Effects of Overexposure:HLTH HAZ: SECTION ARE RELEVANT TO FUMES AND
DUSTS. SEE ORIGINAL MSDS FOR SPECIFIC HAZARDS OF INDIVIDUAL
INGREDIENTS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WELL WITH RUNNING WATER FOR AT LEAST 15 MINUTES TO
REMOVE PARTICULATE. GET MEDICAL ATTENTION. SKIN: VACUUM OFF EXCESS
DUST. WASH WELL WITH SOAP AND WATER. INHALATION: REMOVE TO FRESH
AIR. G ET MEDICAL ATTENTION. INGESTION: SEEK MEDICAL ATTENTION IF
LARGE QUANTITIES OF MATERIAL HAVE BEEN INGESTED.
===================== Fire Fighting Measures =====================
Extinguishing Media:MIXTURES OF DRY CHEMICAL OR SAND.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:SOLID MASSIVE FORM IS NOT COMBUST. FIRE &
EXPLO HAZ ARE MODERATE WHEN MATL IS IN FORM OF DUST & EXPOS TO
HEAT, FLAMES, CHEM RXN/IN CONT WITH POWERFUL OXIDIZERS.
================== Accidental Release Measures ==================
Spill Release Procedures:NO SPECIAL PREC ARE NEC FOR SPILLS OF BULK
MATL. IF LRG QTYS OF DUST ARE SPILLED, REMOVE BY VACUUMING/WET
SWEEPING TO PVNT HEAVY CONC OF AIRBORNE DUST. IF LIQS (ACIDS/BASES)
CONT SOLUBILIZED METAL ARESPILLED EVACUATE UNPROT PERSONNEL
FROM(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE MATERIAL AWAY FROM INCOMPATIBLE
MATERIALS AND KEEP DUST FROM SOURCES OF IGNITION.
Other Precautions:SEE ALL OTHER SECTIONS OF THIS MSDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE ABOVE PEL/TLV, USE A NIOSH/MSHA
APPROVED RESPIRATOR FOR FUME OR DUST, DEPENDENT UPON SOURCE OF
AIRBORNE CONTAMINANT.
Ventilation:LOC EXHST REQD IF DUST OR FUME CREATED IN HNDLG/WORKING ON
MATL. MECH AS ABOVE TO REDUCE AIRBORNE DUST OR FUME LEVELS.
Other Protective Equipment:AS REQUIRED FOR WORK DONE ON OR WITH METAL.
Work Hygienic Practices:IN ACCORDANCE WITH OSHA LEAD STANDARD OR
RELEVANT STATE, LOCAL, OR FEDERAL STANDARDS.
Supplemental Safety and Health
SPILL PROC: AREA. ABSORB LIQUID BY MEANS OF VERMICULITE, DRY SAND OR
SIMILAR MATERIAL. FOLLOW FEDERAL, STATE, AND LOCAL REGULATIONS
CONCERNING DISPOSAL OF WASTE.
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:1290F,699C
Spec Gravity:7.45-9
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID SILVER OR YELLOW TO RED WITH NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, BASES, AND OXIDIZERS.
Stability Condition to Avoid:WATER.
Hazardous Decomposition Products:METAL FUME.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE,
AND LOCAL REGULATIONS. CLEANUP PERSONNEL SHOULD WEAR RESPIRATORS
AND PROTECTIVE CLOTHING.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:P105 PARADICHLOROBENZENE
CAGE:GO409
CAGE:GO409
============= Composition/Information on Ingredients =============
Ingred Name:SEC-BUTANOL ALCOHOL
CAS:78-92-2
RTECS #:EO1750000
Other REC Limits:100 PPM
OSHA PEL:150 PPM
ACGIH TLV:303 MG/CUM
Ingred Name:GLYCOL ETHERS
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (CHLOROTHENE NU),
AEROTHANE TT, CHLOROTHENE (IARC CARC - GROUP 3)*95-2*
CAS:71-55-6
RTECS #:KJ2975000
Other REC Limits:450 PPM STEL
OSHA PEL:350 PPM
ACGIH TLV:350 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:DICHLOROMETHANE (METHYLENE CHLORIDE) (SUSP HUMAN CARC BY
ACGIH, SUSP ANIM CARC BY IARC; NTP - IARC GROUP 2B) *95-1*
CAS:75-09-2
RTECS #:PA8050000
ACGIH TLV:174 MG/CUM (A2)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ETHYLENE GLYCOL, GLYCOL
CAS:107-21-1
RTECS #:KW2975000
Other REC Limits:10 MG/CUM
OSHA PEL:50 PPM
ACGIH TLV:C 127 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:BAYGON; PROPOXURE; 2-(1-METHYLETHOXY) PHENOL
METHYLCARBAMATE; O-ISOPROPOXYPHENYLMETHYLCARBAMATE
CAS:114-26-1
RTECS #:FC3150000
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:PERCHLOROETHYLENE (TETRACHLOROETHYLENE) (SUSPECTED ANIMAL
CARCINOGEN BY NTP & IARC - GROUP 2B) *95-1*
CAS:127-18-4
RTECS #:KX3850000
Other REC Limits:50 PPM
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:NITRILOTRIACETIC ACID, NTA, TRIGLYCINE (SUSPECTED
CARCINOGEN BY IARC & NTP, IARC GROUP 2B) *95-1*
CAS:139-13-9
RTECS #:AJ0175000
Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN, IARC
GROUP 3) *95-2*
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM (DUST)
Ingred Name:PHOSPHORIC ACID
CAS:7664-38-2
RTECS #:TB6300000
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
ACGIH TLV:1 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SULFURIC ACID (CONFIRMED HUMAN CARCINOGEN BY IARC - GROUP
1) *95-1*
CAS:7664-93-9
RTECS #:WS5600000
OSHA PEL:1 MG/CUM
ACGIH TLV:1 MG/CUM=IC
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ZINC
CAS:7440-66-6
RTECS #:ZG8600000
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:HYDROCHLORIC ACID, HYDROGEN CHLORIDE, MURIATIC ACID
HYDROCHLORIDE
CAS:7647-01-0
RTECS #:MW4025000
Other REC Limits:7 PPM
OSHA PEL:5 PPM
ACGIH TLV:C 11 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL (IARC - GROUP 3) *95-2*
CAS:1330-20-7
RTECS #:ZE2100000
Other REC Limits:100 PPM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM, SKIN
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:FREON 113, 1,1,2,-TRICHLORO-1,2,2,-TRIFLUOROETHANE,
TRICHLOROTRIFLUROETHANE *95-1*
CAS:76-13-1
RTECS #:KJ4000000
Other REC Limits:1000 PPM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ozone Depleting Chemical:1
Ingred Name:SILVER NITRATE
CAS:7761-88-8
RTECS #:VW4725000
OSHA PEL:10 UG/CUM
ACGIH TLV:10 UG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TOLUENE (IARC CARC- GROUP 3) *95-2*
CAS:108-88-3
RTECS #:XS5250000
Other REC Limits:375 MG/CUM
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHOXYCHLOR (IARC CARCINOGEN - GROUP 3) *95-1*
CAS:72-43-5
RTECS #:KJ3675000
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ACETONE; DIMETHYL KETONE; 2-PROPANONE
CAS:67-64-1
RTECS #:AL3150000
OSHA PEL:2400 MG/CUM
ACGIH TLV:750 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:P-DICHLOROBENZENE, 1,4-DICHLOROBENZENE (PARA); BENZENE,
P-DICHLORO; PARADICHLORBENZENE(ANIMAL CAR IARC/NTP GRP 2B)*95-1*
CAS:106-46-7
RTECS #:CZ4550000
Fraction by Wt: 99%
Other REC Limits:75 PPM A2 CARCINOGEN
OSHA PEL:75 PPM
ACGIH TLV:75 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:FORMALDEHYDE, FORMALIN (SUSPECTED HUMAN CARCINOGEN BY IARC;
ACGIH; SUSPECTED CARCINOGEN BY NTP; IARC - GROUP 2A) *95-1*
CAS:50-00-0
RTECS #:LP8925000
ACGIH TLV:0.37 MG/CUM IC (2A)
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS *95-1*
CAS:67-56-1
RTECS #:PC1400000
Other REC Limits:200 PPM
OSHA PEL:260 MG/CUM
ACGIH TLV:262 MG/CUM (SKIN)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:O-CRESOL*95-1*
CAS:95-48-7
RTECS #:GO6300000
OSHA PEL:22 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:2,4-DICHLOROPHENOXY) ACETIC ACID; (2,4-D)
CAS:94-75-7
RTECS #:AG6825000
OSHA PEL:10 MG/CUM
ACGIH TLV:10 MG/CUM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: IRRITATION/BURNS TO UPPER
RESPIRATORY SYSTEM, INCLUDING NOSE, MOUTH & THROAT. EYES:
IRRITATION. SKIN: IRRITATION, BURNS. INGESTION: IRRITATION, BURNS
TO MOUTH, THROAT & STOMACH.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:IRRITATION, BURNS
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER. SKIN: WASH W/SOAP & WATER. INHALATION:
REMOVE TO FRESH AIR. INGESTION: INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:150F
Extinguishing Media:WATER, FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & SELF CONTAINED
RESPIRATORY PROTECTION.
Unusual Fire/Explosion Hazard:HIGHLY TOXIC GASES (CHLORIDES & CHLORINE)
CAN BE EVOKED IN FIRES OF THIS PRODUCT.
================== Accidental Release Measures ==================
Spill Release Procedures:SCRAPE UP/ABSORB ON CLAY, SAWDUST/OTHER
ABSORBENT MATERIAL IN DRUM & DISPOSE OF IN APPROVED CHEMICAL
LANDFILL IAW/FEDERAL, STATE & LOCAL REGULATIONS. BURY IN CHEMICAL
LANDFILL.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE NEAR STRONG OXIDIZING
AGENTS. KEEP AWAY FROM HEAT & FLAME.
Other Precautions:AVOID SKIN, EYE CONTACT. AVOID INHALATION OF DUST &
VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED
Ventilation:LOCAL EXHAUST, MECHANICAL NOT REQUIRED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:345.2F
Vapor Pres:0.6
Vapor Density:5.1
Spec Gravity:1.458
Solubility in Water:0.08%
Appearance and Odor:WHITE CRYSTALS W/MOTH BALL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, FLAME
Hazardous Decomposition Products:CO, CO2, SMOKE, CHLORIDES, CHLORINE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. BURY IN CHEMICAL LANDFILL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MIL-P-24441/4, FORULA 155
CAGE:KO664
CAGE:KO664
CAGE:60163
============= Composition/Information on Ingredients =============
Ingred Name:N-BUTANOL
Fraction by Wt: 14.5%
ACGIH TLV:S,C 50PPM
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <1%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:NAPHTA (PETROLEUM SPIRITS OR BENZIN)
CAS:8030-30-6
RTECS #:DE3030000
Fraction by Wt: 13.2%
OSHA PEL:100 PPM
Ingred Name:EPOXY RESIN
Fraction by Wt: 24.3%
ACGIH TLV:100 PPM(MFR)
Ingred Name:POLYAMIDE RESIN
Fraction by Wt: 13.6%
ACGIH TLV:100 PPM (MFR)
===================== Hazards Identification =====================
Effects of Overexposure:IRRITATING TO EYE, SKIN & RESPIRATORY TRACT.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH WITH WATER 15 MINUTES. SKIN:WASH WITH SOAP & WATER.
INHALATION:REMOVE FROM EXPISURE CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:99F/37C (PM)
Lower Limits:1
Upper Limits:11.2
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE
Fire Fighting Procedures:WATER-FOG TO COOL EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO
PRESSURE BUILD UP.
================== Accidental Release Measures ==================
Spill Release Procedures:FOLLOW GENERAL CLEANING PROCEDURES IN REMOVING
ANY SPILLED MATERIAL.SMALL SPILLS MAY BE WASHED AWAY WITH WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL DRY AREA AWAY FROM
FLAMES, & PHYSICAL ABUSE. KEEP CONTAINER CLOSED. GROUND CONTAINER
WHEN POURING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELF-CONTAINED BREATHING APPARATUS
Ventilation:LOCAL/MECHANICAL
Other Protective Equipment:AS NEEDED TO PREVENT SKIN CONTACT.
Supplemental Safety and Health
ADD INGREDIENT: MAGNESIUM SILICATE 31.6%. LAMPSBLACK <1%: THIXATROL ST
<1%;POLYAMIDE ADOUCT <1%,TLV:100 PPM (MFR). CONTAINER SIZE: 1 QT
KIT. KEY1:F4.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:240F/115C
Vapor Pres:5.5
Vapor Density:2.6
Spec Gravity:1.49
Evaporation Rate & Reference:<1
Solubility in Water:SLIGHT
Appearance and Odor:BLACK LIQUID, NORMAL ALCOHOL & NAPHTHA ODOR
Percent Volatiles by Volume:42
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER,AQUEOUS SOLUTIONS
==================== Disposal Considerations ====================
Waste Disposal Methods:BY METHODS CONSISTENT WITH LOCAL,STATE & FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:3713001A, SEALTIGHT REZI-WELD GEL PASTE (SUPP DATA)
Kit Part:Y
CAGE:MEADO
CAGE:96022
CAGE:MEADO
============= Composition/Information on Ingredients =============
Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE:ING 1:PRESUMED TO BE IRRIT. EXPOS
MAY CAUSE CORNEAL INJURY. SKIN:ING 1:MAY CAUSE ALLERGIC RXN IN
SUSCEPTIBLE INDIVIDUALS. PRLNG/RPTD EXPOS MAY CAUSE IRRIT & MAY
STAIN SKIN. ING 2:CONT MAY RSLT INSENSIT TO EPOXIES. INDIVIDUALS
WHO HAVEDEVELOPED SENSIT CAN DEVEL THESE SYMPS AS RSLT OF CONT
W/VERY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 7TH ANNUAL RPT ON
CARCINS, (SUPP DATA)
Effects of Overexposure:HLTH HAZ:SM AMTS OF LIQ MATL/AS RSLT OF EXPOS
TO VAP. SENSIT MAY BE TEMPORARY/PERM. ONCE INDIVIDUAL IS DIAGNOSED
AS BEING SENSITIZED, NO FURTHER EXPOS CAN BE PERMITTED. INHAL:ING
1:EXCESSIVE INHAL, EV EN ON SINGLE PRLNG EXPOS, MAY CAUSE ADVERSE
EFTS. THESE INCL SEV IRRIT OF UPPER RESP TRACT, LUNGS, LIVER &
(SUPP DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE & RESP
DISORDERS MAY BE AGGRAVATED BY EXPOS TO THIS PROD. PERS
W/ASTHMATIC-TYPE CNDTNS, CHRONIC BRONCH, OTHER CHRONIC RESP
DISEASES, RECURRENT SKIN ECZEMA, SENSIT/ (ING 16)
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/COPIOUS AMTS OF WATER FOR AT LST 15 MINS
WHILE HOLDING EYELIDS OPEN. SEEK PROMPT MED ATTN. SKIN:REMOVE
CONTAM SHOES & CLTHG. CLEANSE AFFECTED AREA(S) THORO BY WASHING
W/MILD SOAP & W ATER. IF IRRIT/REDNESS DEVELS & PERSISTS, SEEK MED
ATTN. INHAL:REMOVE AFFECTED PERS FROM DUSTY ENVIRON. INGEST:DILUTE
W/LIQ UNLESS VICTIM IS UNCON/VERY DROWSY. IF VOMIT SPONT OCCURS,
KEEP (ING 17)
===================== Fire Fighting Measures =====================
Flash Point:147F,64C
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON
DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WARNING: COMBUSTIBLE. CLEAR AREA OF UNPROTECTED
PERSONNEL.
Unusual Fire/Explosion Hazard:CNTNRS EXPOS TO INTENSE HEAT FROM FIRES
SHOULD BE COOLED W/WATER TO PVNT VAP PRESS BUILDUP WHICH COULD RSLT
IN CNTNR RUPTURE. CNTNR AREAS EXPOS TO (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:LG SPILLS:EVACUATE HAZ AREA OF UNPROT PERS.
WEAR APPROP NIOSH/MSHA APPRVD RESP & PROT CLTHG. SHUT OFF SOURCE OF
LEAK ONLY IF SAFE TO DO SO. DIKE & CONTAIN. REMOVE/EXTING IGNIT
SOURCES. IF VAP CLOUD FO RMS, WATER FOG MAY BE USED TO
SUPPRESS;(ING 19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:EXTING PILOT LIGHTS, CIGARETTES & TURN
OFF OTHER POSS SOURCES OF IGNIT PRIOR TO USE & UNTIL ALL VAPS ARE
GONE. KEEP CNTNRS CLSD WHEN NOT IN USE.
Other Precautions:KEEP LIQ & VAP AWAY FROM HEAT, SPKS & FLAME. SURFS
THAT ARE SUFFICIENTLY HOT MAY IGNITE PROD IN ABSENCE OF SPKS/FLAME.
VAPS MAY ACCUM & TRAVEL TO IGNIT SOURCES DIST FROM HNDLG SITE. USE
W/ADEQ VENT. C NTNRS, EVEN EMPTY, CAN CONTAIN (ING 23)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE EXCEEDS THE PEL/TLV, USE THE
APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE VENT AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS - AT
LEAST 10 AIR CHANGES PER HOUR ARE REC FOR GOOD GEN ROOM VENT.
Other Protective Equipment:WEAR APPROP PROT CLTHG & EQUIP TO PVNT CONT
W/SKIN. EYE WASH FOUNTAINS & SFTY SHOWERS SHOULD BE AVAIL FOR USE
IN EMER.
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMOKING/USING TOILET FACILITIES. CONTACT LENSES SHOULD NOT BE WORN.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:NON-SLUMP COMPONENT A. EXPLO HAZ:DIRECT FLAME
CONT SHOULD BE COOLED W/LG QTYS OF WATER AS NEEDED TO PVNT
WEAKENING OF CNTNR STRUCTURE. EXPLAN OF CARCIN:1994:ANTIC TO BE
CARCIN . EFTS OF OVEREXP:KIDNEYS. ING 3:INHAL OF SILICA DUST MAY
CAUSE DELAYED LUNG DISEASE (SILICOSIS). ING 2:AS RSLT (ING 6)
================== Physical/Chemical Properties ==================
Vapor Pres:SEE ING 1
Vapor Density:>1
Spec Gravity:1.49
Evaporation Rate & Reference:<1 (ETHER=1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID OXIDIZING MATLS, STRONG ACIDS, ALKALINE MATLS, AMINES, POLYAMINES
& POLYAMIDES UNDER UNCONTROLLED CONDITIONS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUST MAY YIELD CARBON DIOXIDE,
CARBON MONOXIDE &/OR INCOMPLETE COMBUST PRODS. DO NOT BREATHE
SMOKE/FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS
REGARDING PROPER DISPOSAL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SURE ANTIFREEZE
Preparer's Name:ERNEST CARTER
CAGE:0A1G5
CAGE:0A1G5
============= Composition/Information on Ingredients =============
Ingred Name:SILICATES
CAS:6834-92-0
Code:F
RTECS #:VV9275000
Minumum % Wt:.02
Maxumum % Wt:.05
Ingred Name:PHOSPHATES
CAS:7664-38-2
Code:F
RTECS #:TB6300000
< Wt:.5
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
Ingred Name:SILICATES
CAS:1303-96-4
Code:F
RTECS #:VZ2275000
Minumum % Wt:.2
Maxumum % Wt:.5
ACGIH TLV:5 MG/M3
Ingred Name:SODIUM NITRATE
CAS:7631-99-4
RTECS #:WC5600000
< Wt:.5
Ingred Name:SODIUM HYDROXIDE
CAS:1310-73-2
RTECS #:WB4900000
Minumum % Wt:.2
Maxumum % Wt:.4
OSHA PEL:2 MG/M3
ACGIH STEL:C2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SODIUM 2-MERCAPTOBENZOTHIAZOLE
CAS:2492-26-4
Minumum % Wt:.1
Maxumum % Wt:.2
Ingred Name:1,2-ETHANEDIOL
CAS:107-21-1
RTECS #:KW2975000
Minumum % Wt:95.
Maxumum % Wt:96.
ACGIH STEL:C127 MG/M3;C50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SODIUM TOLYLTRIAZOLE
CAS:64665-57-2
Minumum % Wt:.05
Maxumum % Wt:.2
Ingred Name:POLYGLYCOL
CAS:9003-11-6
Code:F
RTECS #:MD0907950
Minumum % Wt:.01
Maxumum % Wt:.03
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:EYES: BELIEVED TO CAUSE SLIGHT EYE
IRRITATION. SKIN: BELIEVED TO BE SLIGHTLY IRRITATING UPON
PROLONGED CONTACT.RESPIRATORY SYSTEM: DROWSINESS, NARCOSIS, AND
UNCONSCIOUSNESS POSSIBLE UPON EXPOSURE T O HIGH CONCENTRATIONS IN
POORLY VENTILATED CONFINED SPACES. CHRONIC: LIVER AND KIDNEY DAMAGE
IN 2 YEAR RAT FEEDING STUDY USING 1-2% ETHYLENE GLYCOL PRODUCED
BIRTH DEFECTS IN LAB ANIMALS.
Effects of Overexposure:EYES: BELIEVED TO CAUSE SLIGHT EYE IRRITATION.
SKIN: BELIEVED TO BE SLIGHTLY IRRITATING UPON PROLONGED CONTACT.
RESPIRATORY SYSTEM: DROWSINESS, NARCOSIS, AND UNCONSCIOUSNESS
POSSIBLE UPON EXPOSURE TO HIGH CONCENTRATIONS IN POORLY VENTILATED
CONFINED SPACES. CHRONIC: LIVER AND KIDNEY DAMAGE IN 2-YEAR RAT
FEEDING STUDY USING 1-2% ETHYLENE GLYCOL. ORAL ADMINISTRATION OF
VERY HIGH DOSES OF ETHYLENE GL YCOL PRODUCED BIRTH DEFECTS IN
LABORATORY ANIMALS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR FITEEN MINUTES. SKIN: WASH EXPOSED
AREAS WITH SOAP AND WATER.INGESTION: GIVE LARGE QUANTITIES OF
WATER, THEN INDUCE VOMITING IMMEDIATELY.GET IMMEDIATE MEDICAL
ATTENTION.IN HALATION: REMOVE TO FRESH AIR; IF NOT BREATHING,
APPLY ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION. KEEP AFFECTED
PERSON WARM AND AT REST.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=127.8C, 262.F
Autoignition Temp:=412.8C, 775.F
Lower Limits:3.2%
Upper Limits:15.3%
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM, OR CARBON
DIOXIDE. WATER OR FOAM
Fire Fighting Procedures:WATER OR FOAM MAY CAUSE FROTHING. USE WATER TO
COOL FIRE EXPOSED CONTAINERS. IF A LEAK OR SPILL HAS NOT BEEN
IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS AND TO PROVIDE
PROTECTION FOR PERSONS ATTEM PTING TO STOP THE LEAK.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL IF POSSIBLE. WIPE UP OR ABSORB
ON SUITABLE MATERIAL AND SHOVEL UP.
======================Handling and Storage ======================
Handling and Storage Precautions:MINIMUM FEASIBLE HANDLING TEMPERATURE
SHOULD BE MAINTAINED. PERIODS OF EXPOSURE TO HIGH TEMPERATURE
SHOULD BE MINIMIZED. WATER CONTAMINATION SHOULD BE AVOIDED.
Other Precautions:WARNING!! HARMFUL OR FATAL IF SWALLOWED KEEP OUT OF
REACH OF CHILDREN MAY CAUSE IRRITATION TO EYES. DO NOT DRINK
ANTIFREEZE OR SOLUTION. AVOID CONTACT WITH EYES. WASH THOROUGHLY
AFTER HANDLING.DO NOT STORE IN OPEN OR UNLABELED CONTAINERS.
ETHYLENE GLYCOL BASE. ETHYLENE GLYCOL HAS PRODUCED BIRTH DEF ECTS
IN RODENTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED AIR RESPIRATORY PROTECTION FOR CLEANING
LARGE SPILLS OR UPON ENTRY INTO TANKS, VESSELS, OR OTHER CONFINED
SPACES.
Ventilation:NORMAL.
Other Protective Equipment:EXPOSED EMPLOYEES SHOULD EXERCISE REASONABLE
PERSONAL CLEANLINESS; THIS INCLUDES CLEANSING EXPOSED SKIN AREAS
SEVERAL TIMES DAILY WITH SOAP AND WATER, AND LAUNDERING OR DRY
CLEANING SOILED WORK CLOTHING
Supplemental Safety and Health
PERMISSIBLE CONCENTRATIONS: AIR 10 MG/CUBIC METER FOR PARTICULATE MIST;
50 PPM (125 MG/CUBIC METER) CEILING LIMIT FOR ETHYLENE GLYCOL
(ACGIH 1984-85).
================== Physical/Chemical Properties ==================
Boiling Pt:=160.C, 320.F
Vapor Pres:18 MMHG
Vapor Density:2.14
Spec Gravity:1.127
Viscosity:21 CP @ 20 C
Solubility in Water:SOL
Appearance and Odor:GREEN/MILD GLYCOL
================= Stability and Reactivity Data =================
STRONG OXIDIZERS.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE MAY
BE FORMED ON BURNING IN LIMITED AIR SUPPLY.
==================== Disposal Considerations ====================
Waste Disposal Methods:UNDER RCRA, IT IS THE RESPONSIBILITY OF THE USER
OF PRODUCTS TO DETERMINE, AT THE TIME OF DISPOSAL, WHETHER PRODUCT
MEETS RCRA CRITERIA FOR HAZARDOUS WASTE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FLURAM (FLUORESCAMINE) ROCHE, 43023
CAGE:1Z582
CAGE:1Z582
CAGE:5M976
============= Composition/Information on Ingredients =============
Ingred Name:FLUORESCAMINE; (4-PHENYLSPIRO(FURAN-2(3H),1'
(3'H)-ISOBENZOFURAN)- 3,3'-DIONE)
CAS:38183-12-9
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50>1000MG/KG (ORAL, MUS)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NO INFORMATION AVAILABLE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:UNKNOWN.
======================= First Aid Measures =======================
First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . EYES:
FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN: FLUSH WIT
H PLENTY OF WATER AND WASH CONTACT AREAWITH SOAP AND WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:AS APPROPRIATE FOR FIRE IN SURROUNDING MATERIALS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:UNKNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP DRY POWDER AND PLACE IN SUITABLE
LABELED CONTAINER. WASH SPILL AREA WITH SOAPY WATER AND FLUSH WASH
TO SEWER WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP REAGENT BOTTLES CLOSED WHEN NOT
IN USE. FOLLOW GOOD LABORATORY PRACTICES. WASH THOROUGHLY AFTER
HANDLING.
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. WHEN HANDLING, USE
PROPER PERSONAL PROTECTIVE EQUIPMENT. DO NOT EAT, DRINK OR SMOKE
WHEN REAGENT IS HANDLED. DO NOT PIPET BY MOUTH; USE MECHANICAL
PIPETTING DEVICE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED IF USED ACCORDING TO PACKAGE
INSERT. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN .
Ventilation:MECHANICAL (GENERAL): RECOMMENDED.
Other Protective Equipment:LAB COAT.
Work Hygienic Practices:AS WITH ALL LABORATORY CHEMICALS, GOOD PERSONAL
HYGIENE AND SAFE LABORATORY PRACTICES AND PROCEDURES SHOULD BE
FOLLOWED.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:304F,151C
Solubility in Water:MINIMAL
Appearance and Odor:WHITE TO YELLOW CRYSTALLINE POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
UNKNOWN.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY EMIT TOXIC
PRODUCTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL OR INCINERATE IN COMPLIANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:NIPOL NITRILE (NBR) ELASTOMERS, NIPOL 1041
Resp. Party Other MSDS Num.:Z01591, FORM NUMBER 1A
CAGE:0J3F9
CAGE:0J3F9
============= Composition/Information on Ingredients =============
Ingred Name:ACRYLONITRILE-BUTADIENE POLYMER
CAS:9003-18-3
= Wt:100.
Ingred Name:ACRYLONITRILE
CAS:107-13-1
RTECS #:AT5250000
Fraction by Wt: < 20% PPM
OSHA PEL:SEE 1910.1045
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:BUTADIENE
CAS:106-99-0
RTECS #:EI9275000
Fraction by Wt: < 5% PPM
OSHA PEL:2200 MG/M3;1000 PPM
ACGIH TLV:4.4 MG/M3;2 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE HEALTH EFFECTS: OVEREXPOSURE IS
NOT EXPECTED AT AMBIENT TEMPERATURES. NO ADVERSE HEALTH EFFECTS ARE
EXPECTED DURING NORMAL PROCESSING WHEN POTENTIAL EXPOSURES ARE
ELIMINATED BY GOOD INDUSTRIAL H YGIENE PRACTICE AND WELL VENTILATED
CONDITIONS. AT PROCESSING TEMPERATURES, THE COMBINED INGREDIENTS
(ELASTOMER AND OTHER PROCESSING INGREDIENTS) MAY EMIT FUMES AND
VAPORS THAT CAUSE IRRITATION TO THE RESPIRATORY TRACT, EYES AND/OR
SKIN. TYPICALLY, THESE EFFECTS ARE REVERSIBLE UPON REMOVAL FROM
EXPOSURE AND NO LASTING EFFECTS ARE EXPECTED. MOST IMPORTANTLY, THE
POTENTIAL FOR IRRITATION WILL DEPEND ON THE (EFFECTS OF
OVEREXPOSURE)
Explanation of Carcinogenicity:NOT LISTED BY IARC, NTP, OR OSHA.
Effects of Overexposure:HEALTH HAZARD (CONT): EFFECTIVENESS OF EXHAUST
VENTILATION PROVIDED TO THE PROCESS AREA. OVEREXPOSURE TO
DECOMPOSITION OR COMBUSTION PRODUCTS WILL CAUSE IRRITATION OF THE
RESPIRATORY TRACT, EYES AND S KIN. SYMPTOMS SUCH AS COUGHING,
TEARING, AND IRRITATION SHOULD BE REGARDED AS POTENTIALLY HAZARDOUS
AND MEASURES TAKEN TO AVOID EXPOSURE. CHRONIC HEALTH EFFECTS: NONE
KNOWN.
Medical Cond Aggravated by Exposure:NONE KNOWN FOR PRODUCT AS
DELIVERED.
======================= First Aid Measures =======================
First Aid:IF IRRITATION OCCURS OR PERSISTS FROM ANY ROUTE OF EXPOSURE,
REMOVE THE AFFECTED INDIVIDUAL FROM THE AREA. CALL A PHYSICIAN.
PROVIDE PROTECTION BEFORE ALLOWING REENTRY. EYE CONTACT: FLUSH
EYES WITH R UNNING WATER FOR SEVERAL MINUTES WHILE HOLDING EYELIDS
OPEN. CONSULT A PHYSICIAN IF IRRITATION PERSISTS. SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND WATER. NO
EFFECTS REQUIRIN G FIRST AID ARE EXPECTED.VAPOR INHALATION
(PROCESSING VAPORS OR DECOMPOSITION PRODUCTS): REMOVE THE AFFECTED
INDIVIDUAL TO FRESH AIR. CONSULT A PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Autoignition Temp:=371.1C, 700.F
Lower Limits:NOT ESTAB
Upper Limits:NOT ESTAB
Extinguishing Media:WATER, ABC DRY CHEM OR PROTEIN TYPE AIR FOAMS ARE
RECOM. ORDINARY COMBUSTIBLE (NFPA DEFINED CLASS A). CARBON DIOXIDE
IS NOT RECOM AS A LACK OF COOLING CAPACITY MAY RESULT IN REIGNIT.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED
BRAETHING APPARATUS (SCBA). PERSONNEL NOT HAVING SUITABLE
RESPIRATORY PROTECTION MUST LEAVE THE AREA TO PREVENT SIGNIFICANT
EXPOSURE TO TOXIC COMBUSTION GASSES FR OM ANY SOURCE. IN ENCLOSED
OR POORLY VENTILATED AREAS, WEAR SCBA DURING CLEANUP IMMEDIATELY
AFTER A FIRE.
Unusual Fire/Explosion Hazard:MOST ORGANIC SUBSTANCES WHEN IN THE FORM
OF A FINE DUST OR POWDER PRESENT A DUST EXPLOSION HAZARD. SPECIAL
PRECAUTIONS MUST BE TAKEN IF THESE ELASTOMERS ARE GROUND OR
OTHERWISE FORMED INTO A FINE POWD ER. HYDROGEN CYANIDE GAS IS
FORMED UPON COMBUSTION. THIS REPRESENTS A HAZARD TO FIREFIGHTERS.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP, SHOVEL, OR VACUUM CRUMBS OR CHUNKS INTO
CLOSED CONTAINER FOR REUSE OR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:DURING NORMAL PROCESSING, VIRTUALLY
ALL ELASTOMERS WILL EMIT FUMES AND VAPORS WHEN HEATED TO PROCESSING
TEMPERATURES. THE CONCENTRATION AND COMPOSITION OF THESE VAPORS
WILL DEPEND ON VARIABLE SUCH AS THE SPECIFIC FORMULATION AND
PROCESSING METHOD ANDTEMPERATURE. ALWAYS PROCESS (OTHER
PRECAUTIONS)
Other Precautions:HANDLING AND STORAGE (CONT): ELASTOMERS UNDERWELL
VENTILATED CONDITIONS AND AVOID CONTINUED ORPROLONGED BREATHING OF
PROCESS VAPORS. WASH THOROUGHLY AFTER PROCESSING COMPOUND,
ESPECIALLY BEFORE EATING , SMOKING, OR USING TOILET FACILITIES. DO
NOT STORE OR CONSUME FOOD IN PROCESSING AREAS. (HYGIENE PR ACT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT TYPICALLY REQD DURING NORMAL USE & HANDLING.
MAY BE NEEDED IF PRODUCT IS GROUND INTO POWDER/DUST. ABNORM CONDS
SUCH AS EQUIP MALFUN, IMPROP EQUIP/PROCEDURES, OR HANGUP OR
STAGNATION DURING PROCESS MAY CAUSE DECOMP. IF GEN DILUTION/LOCAL
EXHAUST IS NOT ADEQUATE TO AVOID EXPOS, PROVIDE SUITABLE AIR
SUPPLIED RESP SUCH AS NIOSH APPVD POSITIVE PRESSURE SCBA.
Ventilation:EFFECTIVE GENERAL AND, IF NECESSARY, LOCAL EXHAUST
VENTILATION MUST ALWAYS BE PROVIDED TO DRAW FUMES OR VAPORS AWAY
FROM THE WORKERS TO PREVENT ROUTINE INHAL.
CONTACT.
PARTICULATE MATTER OUT OF EYES
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Work Hygienic Practices:OTHER PRECAUTIONS (CONT): DO NOT USE PROCESSING
EQUIP TO HEAT FOOD. CLEAN UP FOLLOWING NORMAL PROCESSING SHOULD BE
PERFORMED UNDER WELL VENTILATED CONDITIONS. ELASTOMER MAY BE HELD
AT (OTHER INFO)
Supplemental Safety and Health
IGNITION TEMPERATURE: BASED ON SIMILAR PRODUCT (ASTM D-1929). HAZARD
CLASSIFICATIONS: NFPA: HEALTH:2, FLAMMABILITY: 1, REACTIVITY: 0.
HMIS: HEALTH:0, FLAMMABILITY:1, REACTIVITY: 0.
================== Physical/Chemical Properties ==================
Spec Gravity:1 (H20 = 1)
Solubility in Water:INSOLUABLE
Appearance and Odor:TAN TO BROWN SLAB WITH A MILD CHARACTERISTIC ODOR.
Percent Volatiles by Volume:< 1% (BY WT)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NO SPECIFIC INFORMATION IS AVAILABLE, HOWEVER STRONG OXIDIZERS OR
REDUCING AGENTS WHICH ARE GENERALLY NOT COMPATIBLE WITH MANY
ORGANIC COMPOUNDS, ARE NOT COMPATIBLE WITH THESE ELASTOMERS.
Stability Condition to Avoid:OVERHEATING
Hazardous Decomposition Products:FUMES PRODUCED WHEN HEATED TO
DECOMPOSITION TEMPERATURES MAY CONTAIN: OXIDES OF CARBON, HYDROGEN
CYANIDE, AND SMALL AMOUNTS OF AROMATIC HYDROCARBONS. COMBUSTION
PRODUCTS MUST BE CONSIDERED TOXIC.
=================== Toxicological Information===================
Toxicological Information:ACRYLONITRILE: BY SIMULATING MANUFACTURING
CONDITIONS, WE HAVE GENERATED OBJECTIVE DATA INDICATING THAT
RELATED ACRYLONITRILE/BUTADIENE ELASTOMERS ARE INCAPABLE OF
RELEASING ACRYLONITRILE RESULTING IN AIRBORNE CONCENTRATIONS ABOVE
ONE (1) PPM UNDER NORMALLY EXPECTED CONDITIONS OF HANDLING,
PROCESSINGAND USE.EXAGGERATED CONDITIONS, INCLUDING OPEN MIXING
AT ELEVATED TEMPERATURES, INDICATES THE MAX IMUM ACRYLONITRILE
LEVEL TO WHICH A MILL OPERATOR WOULD BE EXPOSED TO IS LESS THAN 0.5
PPM. BASED ON THESE DATA, THESE NBR ELASTOMERS DO NOT REQUIRE
WARNING LABELS UNDER THE ACRYLONITRILE STANDARD (OS HA 1910.1045).
(ECOLOGICAL INFO)
===================== Ecological Information =====================
Ecological:TOX INFO (CONT): CUSTOMERS SHOULD DO TESTING TO ASSURE
COMPLIANCE OF THEIR OPERATIONS. ACRYLONITRILE IS LISTED BY OSHA AS
A CARCINOGEN, IARC AS A GROUP 2A CARCINOGEN, NTP AS AN ANTICIPATED
CARCINOGEN, AND ACGIH AS A SUSPECTED CARCINOGEN. BUTADIENE:
PERSONNEL MONITORING DURING MANUFACTURE OF ELASTOMERS DETERMINED
THAT WORKER EXPOSURE LEVEL WAS BELOW 0.2 PPM. THIS IS BELOW
EXPOSURE LIMITS ESTABLISH ED BY OSHA OR ACGIH. USERS SHOULD CONDUCT
THEIR OWN EXPOSURE ASSESSMENTS. BUTADIENE IS LISTED BY IARC AS A
GROUP 2B CARCINOGEN, NTP AS AN ANTICIPATED CARCINOGEN, AND ACGIH AS
A SUSPECTED CARCINOGEN. ( CONTACT NEHC FOR ADDITIONAL INFO - )
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL OR INCINERATE IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS. THESE PRODUCTS ARE NOT
DEFINED OR DESIGNATED AS HAZARDOUS BY CURRENT PROVISIONS OF THE
FEDERAL (EPA) RESOURCE CONSERVATI ON AND RECOVERY ACT (RCRA, 40 CFR
261).
=================== MSDS Transport Information ===================
Transport Information:FOR DOMESTIC TRANSPORTATION PURPOSES, THESE
PRODUCTS ARE NOT DEFINED OR DESIGNATED AS A HAZARDOUS MATERIAL BY
THE U.S. DEPARTMENT OF TRANSPORTATION UNDER TITLE 49 OF THE CODE OF
FEDERAL REGULATIONS. DOT HAZARD CLASS: NOT REGULATED, DOT PROPER
SHIPPING NAME: NOT APPLICABLE, DOT LABEL: NOT APPLICABLE, UN/NA
HAZARD NO.: NOT APPLICABLE, REPORTABLE QUANTITY (RQ): NOT
APPLICABLE.
===================== Regulatory Information =====================
Federal Regulatory Information:TSCA INVENTORY STATUS: ALL COMPONENTS ON
TSCA INVENTORY.
State Regulatory Information:ACRYLONITRILE AND BUTADIENE: LISTED ON THE
CALIFORNIA LIST OF SUBSTANCES KNOWN TO CAUSE CANCER, MA
EXTRAORDINARILY HAZARDOUS SUBSTANCES ABOVE 1 PPM.
ACRYLONITRILE/BUTADIENE POLYMER: A PA NON-HAZARDOU S SUBSTANCE
ABOVE 5%, A NJ NON-HAZARDOUS SUBSTANCE ABOVE 1%.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FLUID, FYRITE, CO*2, 11-0057
CAGE:05083
CAGE:05083
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM HYDROXIDE (CERCLA). SPEC GRAV: 0.83.
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 26%
OSHA PEL:2 MG/M3, C
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 71%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ALCOHOLS, C7-9-ISO-, C8-RICH; (C7-9). SPEC GRAV: >1. VP: 1
@ 38C. VAP DENS: 4.5.
CAS:68526-83-0
Fraction by Wt: 3%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE CHEMICAL BURNS
W/PERM BLNDNESS. SKIN: MAY CAUSE CHEMICAL BURNS, SEVERITY DEPENDS
ON DURATION OF CONTACT. INHAL: MAY CAUSE EYE, MUC MEMB & RESP
IRRIT. SEV OVEREXP MAY CAUSE PULM E DEMA. INGEST: MAY CAUSE GI
CORRO, PAIN,NAUS, VOMIT, DIARR, COLLAPSE & SHOCK. CHRONIC: CHRONIC
DERM MAY(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: FOLLOW RPTD CONTACT W/ALKALI SOLNS.
MATERIAL IS CORROSIVE TO TISSUES.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN & RESPIRATORY
CONDITIONS MAY BE AGGRAVATED BY EXPOSURE TO THIS MATERIAL.
======================= First Aid Measures =======================
First Aid:EYE: IMMED FLUSH W/COPIOUS AMTS OF WATER, AT LEAST 20 MINS,
LIFTING UPPER/LOWER LIDS. GET IMMED MED ATTN. SKIN: IMMED FLUSH
W/WATER WHILE REMOVING ANY CONTAMD CLTHG. CONTINUE FLUSHING FOR AT
LEAST 20 MINS. GET MED ATTN IF PAIN/IRRIT PERSISTS. INHAL: IF
ACUTE OVEREXP OCCURS, REMOVE VICTIM TO FRESH AIR. GIVE ARTF RESP IF
NEEDED. GET IMMED MED ATTN. INGEST: DO NOT INDUCE VOMITING. DO NOT
GIVE(SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:183F,84C
Extinguishing Media:USE FOAM, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:ISOOCTYL ALCOHOL HAS FLASH PT OF 183F &
IS INSOLUBLE IN WATER. ONLY SMALL AMT IS PRESENT (<5%) SO ONLY
SLIGHT FIRE HAZARD EXISTS. BALANCE IN NOT COMBUSTIBLE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR RECOM PROT EQUIP. DILUTE SPILL W/WATER &
NEUT W/DILUTE ACETIC ACID. ABSORB & PLACE IN CNTNR FOR DISP OR
FLUSH TO SEWER W/WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE, SEPARATE
FROM ACID AND OXIDIZER STORAGE. AVOID CRUSHING CONTAINERS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED FOR NORMAL USE. DO NOT INHALE
VAPORS. SELECTION OF RESPIRATORY PROTECTION DEPENDS ON CONTAMINANT
TYPE, FORM & CONC. SELECT IN ACCORD W/OSHA 1910.134. USE NIOSH/MSHA
APPRVD RESPIRATOR APP ROP FOR EXPOSURE OF CONCERN.
Ventilation:GENERAL VENTILATION SHOULD BE ADEQUATE.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA.
Work Hygienic Practices:GOOD INDUSTRIAL HYGIENE PRACTICE.
Supplemental Safety and Health
FIRST AID PROC: BY MOUTH TO PERS WHO IS UNCON/CONVULSING. IMMED DILUTE
W/1-2 GLASSES OF WATER/MILK. GET IMMED MEDICAL ATTN. MATLS TO
AVOID: ANHYDRIDES, METALS, CHLORINATED HYDROCARBONS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:<32F,<0C
Vapor Pres:SEE ING 3
Vapor Density:SEE ING 3
Spec Gravity:SEE INGS
pH:13-14
Solubility in Water:INSOLUBLE
Appearance and Odor:RED LIQUID W/SLIGHT UNPLEASANT ODOR.
Percent Volatiles by Volume:75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ACIDS, ALDEHYDES, MONOMERS & POLYMERIZABLE
ESTERS, ALKALYENE OXIDES, HALOGENS, ACID (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:RXN W/METALS CAN LIBERATE FLAMMABLE
HYDROGEN GAS. THERMAL DECOMPOSITION MAY YIELD OXIDES OF CARBON AND
POTASSIUM.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS. RCRA HAZARDOUS WASTE CODE: D002.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SWEET DISTILLATES
CAGE:9V333
CAGE:9V333
============= Composition/Information on Ingredients =============
Ingred Name:ALIPHATIC PETROLEUM DISTILLATES;(LIGHT HYDROCRACKED
DISTILLATE). PEL/TLV AS STODDARD SOLVENT.
CAS:64741-77-1
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
Ingred Name:SUPP DATA:WITH APPLIC LAWS. SPILLS MAY NEED TO BE REPORTED
TO NATIONAL RESPONSE CENTER (800-424-9902). SPILLED (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:MATL & ANY WATER OR SOIL WHICH IT HAS CONTACTED MAY
BE HAZARDOUS TO ANIMAL/AQUATIC LIFE.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:SYS. THE CHEM/BIOLOGICAL OXYGEN DEMAND WILL
LIKELY INCREASE. SPILL MATERIAL IS BIODEGRADABLE. IF (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:GRADUALLY EXPOSED TO MICROORGANISMS. A POTENTIAL
DISPOSAL METHOD IS INCINERATION.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:SHOULD BE INSTALLED I/A/W APPLIC REQS OF
NATIONAL ELEC CODE, NFPA. DO NOT USE PROD AS CLEANING AGENT.(ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:WARNING:USE OF ANY HYDROCARBON FUEL IN SPACES W/OUT
ADEQ VENT MAY RSLT IN GENERATION OF HAZ LEVELS OF (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:COMBUSTION PRODS & INADEQUATE O*2 LEVELS FOR BRTHG.
MATLS SIMILAR TO SOME COMPONENTS IN PROD WERE FOUND (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:TO BE MUTAGENIC IN "IN VITRO" & "IN VIVO" TESTS. THE
EXACT RELATIONSHIP BETWEEN RSLTS & POSS HUMAN EFTS (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:IS NOT KNOWN. SINCE SPECIFIC EXPOS STANDARDS/CTRL
LIMITS HAVE NOT BEEN ESTABLISHED, EXPOS LIMITS IN INGRED(ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:SECTION ARE SUGGESTED AS MINIMUM CONTROL GUIDELINES.
AVOID PROLONGED AND/OR REPEATED SKIN CONTACT.
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT:OF TOILET FACILITIES. IMMEDIATELY REMOVE
SOILED CLOTHING & WASH THOROUGHLY BEFORE REUSE. CLEAN (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:OR DISCARD CONTAMINATED LEATHER GOODS. WASH
THOROUGHLY AFTER HANDLING.
RTECS #:9999999ZZ
Ingred Name:EXPLO HAZ:MISTS/SPRAYS MAY BE FLAMMABLE AT TEMPERATURES
BELOW NORMAL FLASH POINT.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:LIQ, MIST OR VAP CNTCT CAN IRRIT
EYES, SKIN & RESP & DIGESTIVE TRACTS. INHAL:VAPS/MISTS CAN IRRIT
NOSE, THROAT & LUNGS & CAUSE SIGNS/SYMPS OF CNS DEPRESS INCL HDCH,
DIZZ, OR DEATH DEPENDING OF C ONC & LENGTH OF EXPOS. EYE:IRRIT MAY
RLST FROM CNTCT W/LIQ, MIST, &/OR VAPS. SKIN:IRRIT MAY OCCUR.
MORE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:SERIOUS DISORDERS MAY OCCUR UPON
PRLNGD/RPTD CNTCT. CNTCT W/HOT MATL MAY CAUSE THERM BURNS.
INGEST:CAN IRRIT MOUTH, THROAT/ STOMACH, & CAUSE NAUS/VOMIT, DIARR,
RESTLESSNESS. CHRONIC:PROD MAY CNTN PETROLEUM DISTILLATES SIMILAR
TO THOSE SHOWN TO PRODUCE SKIN TUMORS ON LAB ANIMALS. AVOID
PRLNGD/RPTD SKIN CNTCT.
Medical Cond Aggravated by Exposure:PERSONNEL WITH PRE-EXISTING CNS
DISEASE, SKIN DISORDERS, OR CHRONIC RESPIRATORY DISEASES SHOULD
AVOID EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:INHAL:MOVE TO FRESH AIR IMMED. FOR RESP DISTRESS GIVE AIR,
O*2 OR CPR IF NEC. GET MD IF DFCLTIES CONTINUE. EYE:FLUSH W/CLEAN,
LOW PRESS WATER FOR AT LEAST 15 MINS OCCASIONALLY LIFTING LIDS. IF
PAIN/RE DNESS PERSIST AFTER FLUSHING, GET MD. SKIN:REMOVE CONTAM
CLTHG. REMOVE/BRUSH EXCESS MATL FROM CONTAM AREA;THEN FLUSH W/SOAP
& WATER. INGEST:RINSE MOUTH W/WATER. DRINK 1-2 GLASSES OF WATER OR
(SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>100F,>38C
Lower Limits:0.6%
Upper Limits:4.6%
Extinguishing Media:FOAM, DRY CHEMICAL, HALON, CARBON DIOXIDE AND WATER
FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . COOL TANKS AND CONTAINERS EXPOSED TO FIRE
WITH WATER.
Unusual Fire/Explosion Hazard:COMBUSTIBLE! WHEN HEATED ABOVE FLASH
POINT, MATL WILL RELS FLAMM VAPS WHICH IF EXPSED TO IGNIT SOURCE
CAN BURN IN OPEN OR BE EXPLO IN CONFINED SPACES. (ING 14)
================== Accidental Release Measures ==================
Spill Release Procedures:CNTN SPILL. REMOVE ALL IGNIT SOURCES & SAFELY
STOP FLOW OF SPILL. SPILL MAY CREATE SLIPPING HAZ. PVNT FROM
ENTERING ALL BODIES OF WATER, IF POSS. EVAC ALL NON-ESSENTIAL PERS.
IN URBAN AREAS, CLEAN UP AS SOON AS POSS; IN NATURAL ENVIRONMENTS,
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNRS CLSD & AWAY FROM
HEAT/IGNIT SOURCES. EMPTY CNTNRS RETAIN SOME LIQ/VAP RESIDUES, AS
HAZ PRECS MUST BE OBSERVED WHEN HNDLG EMPTY CNTNRS.
Other Precautions:SPECIAL SLOW LOAD PROC FOR "SWITCH LOADING" MUST BE
FOLLOWED TO AVOID STATIC IGNIT THAT CAN EXIST WHEN MATL LOADED INTO
TANKS PREVIOUSLY CNTNG GASOLINE OR OTHER LOW FLSH PT PRODS. ALL
ELEC EQUIP IN AR EAS WHERE PROD STORED/HNDLD (ING 6)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR VAPOR CONCENTRATIONS ABOVE EXPOSURE LIMITS
USE NIOSH/MSHA APPROVED ORGANIC VAPOR, SUPPLIED AIR, OR SCBA
RESPIRATOR. RESPIRATOR USE SHOULD FOLLOW OSHA 29 CFR 1910.134 OR
EQUIVALENT.
Ventilation:USE ADEUQATE VENTILATION TO KEEP VAPOR CONCENTRATIONS OF
THIS MATERIAL BELOW APPLICABLE EXPOSURE LIMITS.
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER . APRON,
BOOTS, FACIAL PROTECTION.
Work Hygienic Practices:CNTCT LENSES SHOULD NOT BE WORN. USE GOOD PERS
HYGIENE PRACT. WASH HANDS BEFORE EATING, DRINKING, SMOKING OR
USE(ING 12)
Supplemental Safety and Health
SPEC GRAV:0.79-0.84 (H*2O=1). VP:0.1 PSIA @ 100F. FIRST AID PROC:MILK.
DO NOT INDUCE VOMITING UNLESS DIRECTED BY MD. GET MD.
NOTE:ASPIRATION OF MATERIAL INTO LUNGS MAY CAUSE CHEMICAL
PNEUMONIA. SPILL PROC:CLEANUP ON ADVICE FROM ECOLOGISTS.MATL WILL
FLOAT ON WATER. ABSORB MATL & PADS CAN BE USED. COMPLY (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>320F,>160C
Melt/Freeze Pt:M.P/F.P Text:>-51F,>-46C
Vapor Pres:SUPDAT
Vapor Density:6
Spec Gravity:SUPP DATA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:NEARLY COLORLESS TO LIGHT-AMBER COLORED
LIQUID;KEROSENE ODOR
Percent Volatiles by Volume:SLIGHT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALIES, AND OXIDIZERS SUCH AS LIQUID CHLORINE AND
OXYGEN.
Stability Condition to Avoid:HEAT AND IGNITION SOURCES.
Hazardous Decomposition Products:BURNING OR EXCESSIVE HEAT MAY PRODUCE
CO AND OTHER HARMFUL GASES/VAPOR INCLUDING OXIDES &/OR OTHER CMPDS
OF SULFUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:MAX PROD RECOVER FOR REUSE/RECYCLING. DISP OF
WASTE MATL AS EPA "IGNITABLE HAZARDOUS WASTE" (DOO1), UNLESS PROVEN
OTHERWISE. USE APPRVD TREATMENT, TRANSPORTERS & DISP SITES I/A/W
LOC, STATE & FED LAWS . IF SPILL INTRODUCED INTO WASTEWATER (ING 4)
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: DPD TOTAL CHLORINE REAGENT, 21056
Cage: GO847
Box: 907
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 4T252
Box: 907
Cage: GO847
Box: 907
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50: (ORAL, RAT) 5850 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: THIS PRODUCT MAY BE IRRITATING TO EYES AND RESPIRATORY
TRACT AND MAY CAUSE ALLERGIC SKIN REACTION, SKIN SENSITIZATION. SLIGHTLY
TOXIC. MAY CAUSE CHRONIC "IODISM": SKIN RASH, CONJUNCTIVITIS, RUNNY NOSE ,
SNEEZING, BRONCHITIS, HEADACHE, FEVER, IRRITATION OF MUCOUS MEMBRANES.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: ALLERGY OR SENSITIVITY TO SALTS OF
N,N-DIETHYL-P-PHENYLENEDIAMINE.
First Aid: EYES: IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES.
CALL MD. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH SOAP AND PLENTY
OF WATER. INGESTION: GIVE LARGE QUANTITIES OF WATER. CALL M D IMMEDIATELY.
INHALATION: REMOVE TO FRESH AIR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SWEEP UP POWDER. AVOID BREATHING MATERIAL. DISSOLVE
IN WATER. FLUSH DOWN THE DRAIN WITH EXCESS WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND
LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY, DARK PLACE.
Other Precautions: AVOID CONTACT WITH EYES. AVOID PROLONGED OR REPEATED CONTACT
WITH SKIN. DO NOT BREATHE DUST. WASH THOROUGHLY AFTER HANDLING. KEEP
PROTECTED FROM SUNLIGHT.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: WATER, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: MAY EMIT TOXIC FUMES IN FIRE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: ADEQUATE VENTILATION.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: PH: 6.39 (1% SOLN @ 23C). CORR RATE: METAL
CORROSIVITY - ALUMINUM: 0.006 IN/YR; STEEL: 0.038 IN/YR.
=======================================================
Physical/Chemical Properties
=======================================================
PH: SUPDAT
Solubility in Water: SOLUBLE
Appearance and Odor: WHITE TO PALE PINK POWDER; NO ODOR.
Corrosion Rate: SUPDAT
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXTREME TEMPERATURE, EXCESS MOISTURE, EXPOSURE TO
LIGHT.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: MAY EMIT TOXIC FUMES OF PHOSPHORUS OXIDES,
IODINE, IODINE COMPOUNDS IN FIRE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: DPD TOTAL CHLORINE REAGENT, 21056
Cage: GO847
Assigned IND: Y
Company Name: HACH INC
PO Box: 907
Zipcode: 50010
Label Required IND: Y
Date Of Label Review: 01/15/1997
Status Code: C
Label Date: 01/15/1997
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: DECOMPOSITION PRODUCTS MAY BE TOXIC. ACUTE: MAY BE
IRRITATING TO EYES AND RESPIRATORY TRACT AND MAY CAUSE ALLERGIC SKIN
REACTION, SKIN SENSITIZATION. SLIGHTLY TOXIC. CHRONIC: MAY CAUSE CHRONIC
"IODISM ": SKIN RASH, CONJUNCTIVITIS, RUNNY NOSE, SNEEZING, BRONCHITIS,
HEADACHE, FEVER, IRRITATION OF MUCOUS MEMBRANES. SKIN SENSITIZATION.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FOIL FACED INSULATION
CAGE:FO654
CAGE:FO654
CAGE:45255
============= Composition/Information on Ingredients =============
Ingred Name:GLASS OXIDE, FIBER GLASS WOOL, LEAD BOROSILICATE GLASS
ENAMEL FLUX
CAS:65997-17-3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MECHANICAL IRRITATION OF
MOUTH, NOSE, & THROAT. POSSIBLE IRRITATION OF UPPER RESPIRATORY
TRACT. EYES/SKIN: MECHANICAL IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, ITCHING
======================= First Aid Measures =======================
First Aid:INHALATION: ADMINISTER OXYGEN. SKIN: WASH W/SOAP & RUNNING
WATER. EYES: FLUSH W/RUNNING WATER FOR 15 MINS. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, DRY CHEMICAL
Fire Fighting Procedures:FACING ON KRAFT PAPER & FOIL FACED PRODUCTS
WILL BURN & SHOULDN'T BE LEFT EXPOSED. SPECIAL CARE SHOULD BE TAKEN
WHEN WORKING CLOSE TO THE FACING W/OPEN FLAME.
Unusual Fire/Explosion Hazard:VINYL FACED PRODUCTS IN FIRE CONDITIONS
MAY GIVE OFF HYDROGEN CHLORIDE, A HIGHLY IRRITATING & TOXIC GAS.
EVACUATE THE BUILDING IMMEDIATELY.
======================Handling and Storage ======================
Handling and Storage Precautions:INSULATION SHOULD BE STORED IN DRY
PLACE. FACED MATERIAL SHOULD BE STORED WELL AWAY FROM SOURCES OF
IGNITION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED/IRRITATION OCCURS, USE A
RESPIRATOR SUCH AS 3M MODEL 8710 FOR PROTECTION AGAINST NUISANCE
DUST.
Ventilation:AMBIENT
Other Protective Equipment:LONG SLEEVED, LOOSE FITTING CLOTHING, LONG
PANTS, CAP WHEN HANDLING MATERIAL OVERHEAD
Work Hygienic Practices:SHOWER AT END OF WORK DAY. REMOVE/LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. WIPE OUT WASHER AT END OF
CYCLE.
Supplemental Safety and Health
APPEARANCE & ODOR CONT'D: PINK, YELLOW, TAN/BLACK INSULATION W/FAINT,
RESIN ODOR. SOME PRODUCTS HAVE A VINYL, KRAFT PAPER,
FOIL/POLYPROPYLENE FACING.
================== Physical/Chemical Properties ==================
Solubility in Water:INSOLUBLE
Appearance and Odor:(SEE SUPPLEMENTAL DATA)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:FIRE/OPEN FLAME IN CONTACT W/VINYL FACE
PRODUCTS, TEMPS AT/ABOVE 525F & OTHER IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2, WATER, HYDROGEN CHLORIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:PRIMARY METHOD OF DISPOSAL IS IN A
MUNICIPAL/INDUSTRIAL LANDFILL. DISPOSE OF IN ACCORDANCE W/LOCAL,
STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:NICKEL 1,000 UG/ML OR 10,000 UG/ML, 5738
CAGE:DO811
CAGE:DO811
CAGE:70829
============= Composition/Information on Ingredients =============
Ingred Name:NICKEL (SARA III)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 0.1-1%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:NITRIC ACID (SARA III)
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: <4%
OSHA PEL:2 PPM
ACGIH TLV:2 PPM; 4 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: >95%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HEADACHE, NAUSEA,
VOMITING, DIZZINESS, IRRITATION OF RESPIRATORY SYSTEM. SKIN/EYE
CONTACT: SEVERE IRRITATION. SKIN ABSORPTION: NONE IDENTIFIED.
INGESTION: BURNS TO MOUTH, THROAT AND STOMAC H, KIDNEY DYSFUNCTION.
CHRONIC: NONE IDENTIFIED. TARGET ORGANS: RESPIRATORY SYSTEM, LUNGS,
EYES, SKIN, TEETH.
Explanation of Carcinogenicity:NICKEL: IARC MONOGRAPHS ON THE
EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOL 49, PG
257, 1990: GROUP (SUPDAT)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:DAMAGED SKIN, EYE DISORDERS,
CARDIOPULMONARY DISEASE.
======================= First Aid Measures =======================
First Aid:INGEST: CALL MD. IF SWALLOWED, DO NOT INDUCE VOMITING. IF
CONSCIOUS, GIVE WATER, MILK OR MILK OF MAGNESIA. INHAL: REMOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTF RESP. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. SKIN: IMMED FLUSH SKIN WITH PLENTY OF
WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES.
WASH CLTHG BEFORE REUSE. EYES: IMMED FLUSH WITH PLENTY OF WATER FOR
AT LEAST 15 MIN.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:REACTS WITH MOST METALS TO PRODUCE
HYDROGEN GAS WHICH CAN FORM AN EXPLOSIVE MIXTURE WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
STOP LEAK IF YOU CAN DO SO W/OUT RISK. VENT AREA. NEUTRALIZE SPILL
W/SODA ASH/LIME. W/CLEAN SHOVEL, CAREFULLY PLACE MATL INTO CLEAN,
DRY CNTNR & COVER; R EMOVE FROM AREA. FLUSH SPILL AREA W/WATER.
Neutralizing Agent:NEUTRALIZE SPILL WITH SODA ASH OR LIME.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN SECURE POISON AREA. ISOLATE FROM INCOMPATIBLE MATERIALS.
Other Precautions:CAUSES SEVERE IRRITATION. HARMFUL IF SWALLOWED OR
INHALED. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. DO NOT BREATHE
VAPOR. KEEP IN TIGHTLY CLOSED CONTAINER. LOOSEN CLOSURE CAUTIOUSLY.
USE WITH ADEQUAT E VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:VENT HOOD.
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . LAB COAT & APRON.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLAN OF CARCIN: 2B. NTP 6TH ANNUAL REPORT ON CARCINOGENS, 1991:
ANTICIPATED TO BE CARCINOGEN. HUMAN: LUNGS, NASAL CAVITIES. EYE
PROT: & FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
Solubility in Water:COMPLETE (100%)
Appearance and Odor:COLORLESS LIQUID; ODORLESS.
Percent Volatiles by Volume:99
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG REDUCING AGENTS, ALKALIES, MOST COMMON METALS.
Stability Condition to Avoid:HEAT.
Hazardous Decomposition Products:OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS
WASTE NUMBER: D002 (CORROSIVE WASTE).
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: 119-361 TRANSPARENT RED OXIDE
Cage: LILLI
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: LILLI
=======================================================
Contractor Summary
=======================================================
Cage: LILLI
=======================================================
Ingredients
=======================================================
Cas: 1330-20-7
RTECS #: ZE2100000
% Wt: 11
Other REC Limits: 100 PPM
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM, SKIN
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
% Wt: 13
Other REC Limits: 375 MG/CUM
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 78-93-3
RTECS #: EL6475000
% Wt: 6
Other REC Limits: 590 MG/CUM
OSHA PEL: 200 PPM
ACGIH TLV: 590 MG/CUM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 141-78-6
RTECS #: AH5425000
% Wt: <5
Other REC Limits: 400 PPM
OSHA PEL: 400 PPM
ACGIH TLV: 400 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 108-65-6
RTECS #: AI8925000
% Wt: 14
Other REC Limits: NOT ESTABLISHED
------------------------------
Cas: 100-41-4
RTECS #: DA0700000
% Wt: 6
Other REC Limits: 100 PPM
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: YES
Effects of Exposure: INHALATION: RESPIRATORY IRRITATION, CNS EFFECTS &
POSSIBLE ASPHYXIATION. SKIN: IRRITATION, DERMATITIS. INGESTION: GI
IRRITATION. ASPIRATION INTO LUNGS CAN CAUSE CHEMICAL PNEUMONIA WHICH CAN BE
FATAL. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT
BRAIN, CNS, LIVER/KIDNEY DAMAGE.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, DIZZINESS, WEAKNESS, FATIGUE,
HEADACHE, UNCONSCIOUSNES, REDDNESS, TEARING, BLURRED VISION, DEFATTING,
NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated By Exposure: PRE-EXISTING EYE, SKIN, LIVER, KIDNEY
& RESPIRATORY DISORDERS.
First Aid: EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. SKIN: WASH
THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF
NEEDED. INGESTION: DON'T INDUCE VOMITING. KEEP WARM & QUIET. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: STAY UPWIND & AWAY UNLESS WEARING PROTECTIVE
EQUIPMENT. STOP &/CONTAIN DISCHARGE, SAFELY. KEEP IGNITION SOURCES AWAY.
VENTILATE AREA. USE NON-SPARKING TOOLS FOR CLEAN UP.
Waste Disposal Methods: DON'T FLUSH TO SEWER, WATERSHED/WATERWAY. DISPOSE OF
IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T INCINERATE CLOSED
CONTAINERS. FLAMMABLE LIQUID UN 1263.
Handling And Storage Precautions: DON'T STORE >120F. STORE LARGE QUANTITIES
IN BUILDING DESIGNED TO COMPLY W/OSHA. KEEP AWAY FROM IGNITION SOURCES. KEEP
CONTAINERS TIGHTLY CLOSED.
Other Precautions: KEEP CONTAINERS CLOSED WHEN NOT IN USE & IN UPRIGHT
POSITION. CONTAINERS SHOULD BE GROUNDED WHEN POURING. DON'T TAKE INTERNALLY.
EMPTIED CONTAINERS MAY CONTAIN HAZARDOUS RESIDUE & EXPLOSIVE VAPORS. KE
EP AWAY FROM IGNITION SOURCES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 21F
Lower Limits: 1
Upper Limits: 13.1
Extinguishing Media: FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures: WEAR FULL PROTECTIVE EQUIPMENT INCLUDING SCBA. WATER
SPRAY W/FOG NOZZLES IS PREFERRABLE METHOD TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE IF EXPOSED TO
EXTREME HEAT. VAPORS MAY BE >AIR/TRAVEL ALONG FLOOR BEFORE IGNITION,
FLASHING BACK TO SOURCE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF LIMITS ARE EXCEEDED USE NIOSH/MSHA APPROVED AIR
SUPPLIED RESPIRATOR. OSHA REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA
RESPIRATORS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED CONDITIONS.
Ventilation: MECHANICAL (GENERAL/LOCAL EXHAUST) TO MAINTAIN EXPOSURE <TLVS.
Other Protective Equipment: IMPERVIOUS BOOTS & CLOTHING.
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: INTENTIONAL MISUSE BY DELIBERATELY INHALING
CONTENTS MAY BE HARMFUL/FATAL. KEEP OUT OF REACH OF CHILDREN. INDUSTRIAL USE
ONLY.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 172-279F
Vapor Density: >1
VOC Pounds/Gallon: 4.76
VOC Grams/Liter: 571
Evaporation Rate & Reference: SLOWER THAN ETHER
Solubility in Water: INSOLUBLE
Appearance and Odor: VISCOUS LIQUID W/SOLVENT ODOR.
Percent Volatiles by Volume: 64.56
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT, OPEN FLAMES, STATIC ELECTRICITY, ELECTRIC
EQUIPMENT, SPARKS & OTHER IGNITION SOURCES.
Materials To Avoid: STRONG ACIDS, ALKALIES, OXIDIZERS.
Hazardous Decomposition Products: ORGANIC ACIDS, CO2, CO, SMOKE
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: VOLATILE ORGANIC CONTENT: COATING/MATERIAL: 4.76 LB/GAL; 571
GM/L.
=======================================================
HAZCOM Label
=======================================================
Product ID: 119-361 TRANSPARENT RED OXIDE
Cage: LILLI
Company Name: LILLY INDUSTIES INC
Street: 2601 EAST HENRY AVENUE
Zipcode: 33610-5000
Label Required IND: Y
Date Of Label Review: 12/16/1998
Status Code: C
Label Date: 12/16/1998
Origination Code: G
Hazard And Precautions: INHALATION: RESPIRATORY IRRITATION, CNS EFFECTS &
POSSIBLE ASPHYXIATION. SKIN: IRRITATION, DERMATITIS. INGESTION: GI
IRRITATION. ASPIRATION INTO LUNGS CAN CAUSE CHEMICAL PNEUMONIA WHICH CAN BE
FATAL. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT
BRAIN, CNS, LIVER/KIDNEY DAMAGE. IRRITATION,
DIZZINESS, WEAKNESS, FATIGUE, HEADACHE, UNCONSCIOUSNES, REDDNESS, TE ARING,
BLURRED VISION, DEFATTING, NAUSEA, VOMITING, DIARRHEA.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DRI-DIE INSECTICIDE
CAGE:66146
CAGE:66146
============= Composition/Information on Ingredients =============
Ingred Name:AMORPHOUS SILICA; (AMORPHOUS SILICA GEL)
Fraction by Wt: 95%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILICATE(2), HEXAFLUORO-, DIAMMONIUM; (AMMONIUM
SILICOFLUORIDE) (AMMONIUM FLUOSILICATE) (SARA III)
CAS:16919-19-0
RTECS #:VV7800000
Fraction by Wt: 2%
OSHA PEL:2.5 MG/M3 (F)
ACGIH TLV:N/K
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:INERT INGREDIENTS
Fraction by Wt: 3%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) >5.2 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: MILDLY IRRITATING. SKIN:
PRACTICALLY NON-IRRITATING.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: DRINK A GLASS OF WATER AND INDUCE VOMITING BY
TOUCHING BACK OF THROAT WITH FINGER. CONTACT MD OR POIS CTL CTR
IMMED. DO NOT INDUCE VOMIT OR GIVE ANYTHING BY MOUTH TO AN UNCON
PERSON. INHAL: RE MOVE AFFECTED PERSON TO FRESH AIR. APPLY ARTF
RESP IF INDICATED. EYE/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST
15 MIN. CONTACT MD IF IRRITATION PERSISTS.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:IF CONTAMINATED, SWEEP UP AND DISPOSE, OR WASH
AWAY. IF NOT CONTAMINATED, RETURN TO ORIGINAL CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID INHAL OF DUST. DO NOT USE IN
EDIBLE PROD AREAS OF FOOD PROCESSING PLANTS, RESTAURANTS/OTHER
AREAS WHERE FOOD IS COMMERCIALLY PREPARED/PROCESSED.
Other Precautions:DO NOT USE IN SERVING AREAS WHILE FOOD IS EXPOSED. DO
NOT APPLY DIRECTLY TO STREAMS, LAKES OR PONDS. DO NOT CONTAMINATE
WATER BY CLEANING EQUIPMENT OR DISPOSAL OF WASTES. APPLY THIS
PRODUCT ONLY AS SP ECIFIED ON THIS LABEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF DUSTY CONDITIONS EXIST, USE NIOSH/MSHA
APPROVED DUST MASK.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
WASTE DISP: CNTNR DISP: TRIPLE RINSE (OR EQUIVALENT) THEN OFFER FOR
RECYCLING OR RECONDITIONING, OR PUNCTURE AND DISPOSE OF IN A
SANITARY LANDFILL, OR BY OTHER APPROVED FEDERAL, STATE AND LOCAL
PROCED URES.
================== Physical/Chemical Properties ==================
HCC:N1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT CONTAMINATE WATER, FOOD OR FEED BY
STORAGE OR DISPOSAL. PESTICIDE DISP: PESTICIDE, SPRAY MIX OR RINSE
WATER THAT CANNOT BE USED ACCORDING TO LABEL INSTRUCTIONS MUST BE
DISPOSED OF AT OR BY AN A PPROVED WASTE DISP FACILITY. (SUPP DATA)
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: FICAM WASP & HORNET SPRAY
Cage: 5Y558
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 5Y558
Box: 7495
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50: (ORAL, RAT) > 5,000 G/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT FOR
LIFE-SUSTAININ G USES IN HUMANS ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS
(FP N). UNDER USE CNDTNS (MOSTLY OUTDOORS) (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: AS SPECIFIED ON PROD LABEL,
OVEREXP TO PROD MIST CONSIDERED HIGHLY UNLIKELY. EYES: VAP MAY IRRIT. DIRECT
SPRAY CNTCT W/EYES CAN CAUSE SEV IRRIT. SKIN: RPTD CNTCT MAY IRRIT. MAY BE
HARMFUL IF ABSORBED THRU SKIN. INGEST: MAY BE HARMFUL IF SWALLOWED. INHAL:
EXCESSIVE INHAL IN CONFINED/POORLY VENT AREA
Medical Cond Aggravated By Exposure: OVEREXPOSURE IN A CONFINED AREA MAY
AGGRAVATE PRE-EXISTING CONDITIONS OF THE EYE AND THE UPPER RESPIRATORY
SYSTEM.
First Aid: EYES:FLUSH W/PLENTY OF WATER FOR @ LEAST 15 MIN. CONTACT MD IF IRRIT
PERSISTS. SKIN: REMOVE CONTAMD CLTHG & WASH AFFECTED AREAS OF SKIN W/SOAP
& WATER. CNTCT MD IF IRRIT PERSISTS. WASH CLTHG W/SOAP & WATER
BEFORE REUSE. INGEST: CALL MD/POIS CTL CTR IMMED. DRINK 1 OR 2 GLASSES OF
WATER & INDUCE VOMIT BY TICKLING BACK OF THROAT W/FINGER. DO NOT GIVE
ANYTHING BY MOUTH TO UNCON PERSON. INHAL:
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: USE PROPER PROT EQUIP TO MINIMIZE PERS EXPOS. TAKE
ALL NEC ACTION TO PVNT & REMEDY EFTS OF SPILL. KEEP PEOPLE AWAY &
ISOLATE HAZ AREA. SHUT OFF IGNIT SOURCE. NO FLARES, SMKNG OR FLAMES IN HAZ
AREA. US E WATER SPRAY TO REDUCE VAPS & ISOLATE
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: THIS PRODUCT CONTAINS A RCRA INGREDIENT. WASTE,
INCLUDING SPILLS OR RINSATES AND LEFTOVER PESTICIDE THAT CANNOT BE USED
ACCORDING TO LABEL INSTRUCTIONS, MUST BE DISPOSED OF ACCORDING TO THE
APPLICABLE FEDERAL (RCRA), STATE AND LOCAL PROCEDURES.
Handling And Storage Precautions: STORE IN COOL, DRY PLACE INACCESSIBLE TO
CHILDREN & PETS. CONTENT UNDER PRESS. DO NOT USE/STORE NEAR HEAT/OPEN
FLAME. DO NOT PUNCTURE/INCIN
Other Precautions: NO SMKNG IN AREA OF USE. DO NOT USE IN GEN VICIN OF ARC
WELDING/OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE FORM OF HCL
&/OR PHOSGENE (FPN). MAY BE HARMFUL IF SWALLOWED/ABSORBED THRU SKIN. DO
NOT GET IN EYES. AVOID BRTHG SPRAY MIST.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: >200F,>93C
Extinguishing Media: WATER FOG, FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures: NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL PROT
EQUIP(FP N). AVOID INHAL OF FUMES. REMOVE FROM AREA OF FIRE AT ONCE. DO NOT
USE DIRECT STREAM OF WATER; (SUPDAT)
Unusual Fire/Explosion Hazard: THERMAL DECOMP PRODS MAY INCL HCL & PHOSGENE
(FP N). CONTENTS UNDER PRESS. EXPOS TO TEMPS >130F MAY CAUSE BURSTING. DO
NOT SPRAY IN CONFINED AREA; VAPS (SUDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: ENSURE GOOD VENT BEFORE USE. UNDER USE CNDTNS, VENT IS
SUFFICIENT FOR NORM USE. IF USED IN CONFINED AREA, NIOSH/MSHA APPRVD VAP RESP
FOR ADDED PROT. ALTHOUGH GEN GUIDANCE HAS BEEN PROVIDED, DEGREE OF PROT REQD
IN PARTICULAR
Ventilation: CONTROL AIRBORNE CONCS BELOW EXPOS GUIDELINE. USE W/ADEQ VENT. LOC
EXHST VENT MAY BE NEC, WHEN USED IN CONFINED
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: AVOID CONTACT WITH THE SKIN OR CLOTHING. WASH
THOROUGHLY WITH SOAP AND WATER AFTER HANDLING.
Supplemental Safety and Health: USERS OF "L" VERSION SHLD CONSULT "LR" VERSION
FOR ADDNL INFO (FPN). FIRE FIGHT PROC:MATL MAY FLOAT & REIGNITE. EXPLO
HAZ:MAY DEVELOP FLAM ATM. WHEN HEATED TO PT OF DECOMP (>140C/240F),
BENDIOCARB GIV ES OFF TOX FUME WHICH IS RAPIDLY ELIM BY FIRE/WATER. DO NOT
USE/STORE NEAR HEAT/OPEN FLAME. DO NOT PUNCTURE/INCIN CNTNR.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.320 (20C)
Appearance and Odor: PRESSURIZED CLEAR TO LIGHT BROWN LIQUID; CHLORINATED
SOLVENT-LIKE ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: HCL, PHOSGENE (FP N).
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TT-E-2784A
CAGE:NO367
CAGE:NO367
CAGE:3F338
============= Composition/Information on Ingredients =============
Ingred Name:GLYCOL ETHER (VAPOR PRESSURE 25%)
CAS:111-77-3
RTECS #:KL6125000
Fraction by Wt: 7.20%
Other REC Limits:NONE RECOMMENDED
Ingred Name:GLYCOL ETHER (VAPOR PRESSURE 0.1%)
CAS:770-35-4
Fraction by Wt: 1.30%
Other REC Limits:NONE RECOMMENDED
Ingred Name:VOC = 1.46 G/L, NON-EXEMPT SOLVENT PER ADJUSTED GALLON.
RTECS #:9999999VO
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: IRRITATION. SKIN: IRRITATION.
INHAL: IRRITATING TO NOSE/THROAT. INGEST:TOXIC.
Effects of Overexposure:INHAL: HEADACHE, NAUSEA, VOMITING, DROWSINESS.
Medical Cond Aggravated by Exposure:HEART CONDITIONS, ASTHMA.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/WATER FOR 15 MINUTES, GET MED AID. SKIN: WASH
W/SOAP & WATER. REMOVE CONTAIM CLOTHES. INHAL: GET FRESH AIR. OXGEN
IF NEEDED. INGEST: GIVE TWO GLASSES OF WATER. INDUCE VOMIT.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMBLE
Extinguishing Media:CO2, FOAM.
Fire Fighting Procedures:USE FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:COOL CONTAINERS W/WATER STEAM IN EVENT OF
A FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE & CONTAIN. SOAK UP RESIDUE W/ABSORBENT
MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. PROTECT
FROM FREEZING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:REQUIRED.
Ventilation:REQUIRED.
Other Protective Equipment:APRON.
Work Hygienic Practices:WASH AFTER HANDLING.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,156C
Vapor Density:>AIR
Evaporation Rate & Reference:VALUE NOT STATED
Solubility in Water:100%
Percent Volatiles by Volume:58.9
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS.
Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE & UNIDENTIFIED ORGANIC
COMPOUNDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN RECKA APPROVED FACILITY.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GARD HIGH PERFORMANCE SAE 10W-30
Preparer's Name:MICHAEL S. MCLEMORE
CAGE:1RU67
CAGE:1RU67
============= Composition/Information on Ingredients =============
Ingred Name:HYDROTREATED PARAFINNIC DISTILLATES
Minumum % Wt:80.
Maxumum % Wt:90.
OSHA PEL:5 MG/M3 OIL MIST
ACGIH TLV:5 MG/M3 OIL MIST
ACGIH STEL:10 MG/M3 OIL MIST
Ingred Name:PROPRIETARY ADDITIVES
Minumum % Wt:10.
Maxumum % Wt:20.
OSHA PEL:5 MG/M3 OIL MIST
ACGIH TLV:5 MG/M3 OIL MIST
ACGIH STEL:10 MG/M3 OIL MIST
Ingred Name:ZINC SALTS OF DIALKYLDITHIOPHOSPHORIC ACID
CAS:68649-42-3
< Wt:.5
OSHA PEL:5 MG/M3 OIL MIST
ACGIH TLV:5 MG/M3 OIL MIST
ACGIH STEL:10 MG/M3 OIL MIST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE :NOT EXPECTED TO CAUSE IRRITATION.
MAY CAUSE MILD DISCOMFORT. SKIN:NOT EXPECTED TO CAUSE IRRITATION.
PROLONGED CONTACT MAY LEAD TO AN ALLERGIC SKIN SENSITIZATION.
INHALATION: VAPORS FROM HOT MATER IAL MAY CAUSE NON-SPECIFIC
DISCOMFORT. INGESTION: RELATIVELY NON-TOXIC UNLESS LUNG ASPIRATION
OCCURS. ASPIRATION MAY LEAD TO CHEMICAL PHEUMONITIS.
Explanation of Carcinogenicity:NOT DETERMINED.
Effects of Overexposure:EYES:TEARING, OR BLURRING OF VISION. SKIN:
IRRITATION, ALLERGIC SENSITIZATION (REDDENING OF SKIN & IRRITATION)
INHALATION: NAUSEA, HEADACHE. INGESTION:ABDOMINAL CRAMPS, DIARRHEA.
APIRATION INTO LUNGS IS CHARACTERIZED BY PULMONARY EDEMA,
HEMORRHAGE, DEATH, INCREASED RESPIRATORY RATE, INCREASED HEART
RATE, BLUISH DISCOLORATION OF THE SKIN,
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP AND WATER. IF IRRITATION PERSIST, GET MEDICAL
ATTENTION. INH ALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET
MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING DUE TO
ASPIRATION HAZARD. IMMEDIATELY GIVE 2 GLASSES OF WATER. NEVER GIVE
ANYTHING BY MOUTH IF UNCONSCIOUS. IF VOMITING OCCURS, LOWER HEAD
BELOW KNEES TO AVOID ASPIRATION. SEEK IMMEDIATE MEDICAL HELP.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=240.6C, 465.F
Lower Limits:NOT DETERM
Upper Limits:NOT DETERM
Extinguishing Media:USE DRY CHEMICAL, FOAM, WATER FOG, CARBON DIOXIDE.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE BUT MAY BE USED TO
COOL CONTAINERS EXPOSED TO HEAT OR FLAME. CAUTION SHOULD BE
EXERCISED WHEN USING WATER OR FOAM AS FROTHING MAY OCCUR.
Unusual Fire/Explosion Hazard:DENSE SMOKE MAY BE GENERATED WHILE
BURNING. TOXIC FUMES, GASES OR VAPORS MAY EVOLVE ON BURNING. HEAVY
FLAMMABLE VAPORS MAY TRAVEL TO LOW AREAS AND IGNITE.
================== Accidental Release Measures ==================
Spill Release Procedures:IMMEDIATELY TURN OFF ANY SOURCE OF IGNITION.
EVACUATE AREA AND VENTILATE. CONTAIN MATERIAL WITH INERT MATERIAL
AND COLLECT IN SUITABLE CONTAINERS FOR DISPOSAL. PREVENT MATERIAL
FROM ENTERING SEWERS OR WATERWAYS. IF A LARGE SPILL OCCURS NOTIFY
APPROPRIATE AUTHORITIES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. DO NOT TRANSFER TO UNMARKED CONTAINERS. FIRE EXTINGUISHERS
SHOULD BE KEPT READILY AVAILABLE.
Other Precautions:SEE NFPA 30 AND OSHA 1910.106--FLAMMABLE AND
COMBUSTIBLE LIQUIDS. EMPTY CONTAIENRS RETAIN PRODUCT RESIDUE WHCIH
MAY EXHIBIT HAZARDS OF MATERIAL, THEREFORE DO NOT PRESSURIZE, CUT,
GLAZE, WELD OR USE FO R ANY OTHER PURPOSES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED IF AIRBORNE CONCENTRATIONS ARE
MAINTAINED BELOW THRESHOLD LIMITS. OTHERWISE A RESPIRATORY
PROTECTION PROGRAM MEETING OSHA REQUIREMENTS MUST BE FOLLOWED.
WHERE MISTING MAY OCCUR, WEAR AN MSHA/NIOSH APPROVE HALF-MASK FORM
DUST/ MIST AIR-PURIFYING RESPIRATOR.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION AS
REQUIRED TO MAINTAIN EXPOSURE LEVELS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
LAUNDER CONTAMINATED CLOTHES BEFORE REUSE. DISCARD CONTAMINATED
LEATHER ARTCILES.
Supplemental Safety and Health
COMSUMPTION OF FOOD AND DRINK SHOULD BE AVOIDED IN WORK AREAS WHERE
PRODUCT IS PRESENT.
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NEGLIGIBLE
Vapor Density:> 1
Spec Gravity:0.889
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK BROWN, CLEAR FLUID, MILD PETROLEUM HYDROCARBON
ODOR
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH ACIDS AND OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID HIGH TEMPERATURES AND PRODUCT
CONTAMINATION.
Hazardous Decomposition Products:OXIDES OF CARBON ZINC, CALCIUM,
MAGNESIUM, PHOSPHORUS AND SULFUR, HYDROGEN SULFIDE, ALKYL
MERCAPTANS, OTHER SULFIDES.
=================== Toxicological Information===================
Toxicological Information:ORAL AND DERMAL TOXICIRY: NOT DETERMINED.
INHALATION TOXICITY: ON RARE OCCASIONS, PROLONGED AND REPEATED
EXPOSURE TO ALL MISTS POSES A RISK OF PULMONARY DISEASE SUCH AS
CHRONIC LUNG INFLAMMATION. DERM AL SENSITIZATION: PROLONGED OR
REPEATED CONTACT MAY MAKE SKIN MORE SENSITIVE TO OTHER SENSITIZERS.
MUTAGENICITY: THIS PRODUCT CONTAINS ZINC ALKYL DITHIOPHOSPHATES
(ZDP). SEVERAL ZDPS HAVE BEEN REPORTE D TO HAVE WEAK MUTAGENICITY
ACTIVITY IN CULTURED MAMMALIAN CELLS BUT ONLY AT CONCENTRATIONS
THAT WERE TOXIC TO THE TEST CELLS.
===================== Ecological Information =====================
Ecological:THIS MATERIAL MAY BE TOXIC TO AQUATIC ORGANISMS AND SHOULD
BE KEPT OUT OF SEWAGE AND DRAINAGE SYSTEMS AND ALL BODIES OF WATER.
ENVIRONMENT FATE: NO DATA AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH
FEDERAL, STATE, AND LOCAL REGULATIONS. UNDER RCRA IT IS THE
RESPONSIBILITY OF THE USER OF THE PRODUCT TO DTERMINE AT THE TIME
OF DISPOSAL WHETHER THE PRODUCT MEETS RCRA CRITERIA FOR HAZARDOUS
WASTE.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED BY DOT.
===================== Regulatory Information =====================
SARA Title III Information:CLEAN WATER ACT/OIL POLLUTION ACT: UNDER SEC
311 OF CWA (40CFR 110) 7 OIL POLLUTION ACT OF 1990, THIS MATERIAL
IS CONSIDERED AN OIL. ANY SPILL OR DISCHARGES THAT PRODUCE A
VISIBLE SHEEN OR FILM ON SUR FACE OF WATER, OR IN WATERWAYS, DICHES
OR SEWERS LEADING TO SURFACE WATER MUST BE REPORTED. CONTACT NRC AT
800-424-8802. SEC 313 TOXIC CHEMICALS: ZN <0.1%. SEC 311/312
HAZARD CATEGORIES: ACUTE=YES; DELAYED=NO; FIRE=NO; REACTIVITY AND
FIRE=NO. CERCLA: RQ= ND.
Federal Regulatory Information:TSCA INVENTORY: ALL COMPONENTS OF THIS
PRODUCT ARE LISTED ON THE TSCA INVENTORY.
State Regulatory Information:CALIFORNIA PROPOSITION 65: NOT APPLICABLE.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:KLEEN-A-SEPTIC B
CAGE:0S5V4
CAGE:0S5V4
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL;9394
Ingred Name:2-BUTOXYETHANOL (SARA III)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9394
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION-MAY CAUSE IRRITATION TO
MUCOUS MEMBRANES. SKIN-VERY MILD IRRITANT. INGESTION-IRRITATING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYE-BURNING AND IRRITATING TO EYES.
Medical Cond Aggravated by Exposure:MAY IRRITATE PRE-EXISTING LESIONS.
======================= First Aid Measures =======================
First Aid:EYE-FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL ATTENTION.
SKIN-WASH WITH SOAP AND WATER. INHALATION-MOVE TO FRESH AIR.
INGESTION-DRINK A LARGE VOLUME OF WATER. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:90.0F,32.2C
Autoignition Temp:Autoignition Temp Text:UNK
Lower Limits:UNK
Upper Limits:UNK
Extinguishing Media:WATER, CARBON DIOXIDE.
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE AREA AND PUMP TO AN INTACT CONTAINER.
FLUSH AREA TO SEWER WITH WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL DRY PLACE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED.
Ventilation:NORMAL VENTILATION.
Other Protective Equipment:NONE.
Work Hygienic Practices:WASH HANDS AFTER USE.
Supplemental Safety and Health
NONE.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:24 MMHG
Vapor Density:0.84
Spec Gravity:0.96
Evaporation Rate & Reference:1 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS THIN LIQUID WITH WINTERGREEN ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
AMMONIA.
==================== Disposal Considerations ====================
Waste Disposal Methods:FLUSH TO SEWER WITH WATER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:812057
CAGE:DO532
CAGE:73877
CAGE:DO532
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM CARBONATE
CAS:584-08-7
RTECS #:TS7750000
Fraction by Wt: 23.0%
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 2.0%
OSHA PEL:C, 2 MG/M3
ACGIH TLV:C 2 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:CAUSTIC SOLUTION;WILL CAUSE BURNS ON SKIN
W/PROLONGED EXPOSRE
======================= First Aid Measures =======================
First Aid:SKIN: REMOVE CONTAM CLOTHING; RINSE SKIN THOROUGHLY W/WATER
FOLLOWED BY BORIC ACID SOLUTION. EYES: FLUSH EYES WITH WATER FOR AT
LEAST 15 MIN. GET IMMEDIATE MEDICAL ATTN.
===================== Fire Fighting Measures =====================
Flash Point:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:USE WATER TO KEEP FIRE-EXPOSED CONTAINERS COOL &
FOR DILUTIO
Fire Fighting Procedures:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILLS, TRANSFER TO CONTAINERS FOR
DISPOSAL
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL LOCATION. KEEP
CONTAINERS SECURELY CLOSED AND WELL MARKED
Other Precautions:AVOID CONTACT WITH SKIN OR EYES. WASH THOROUGHLY
AFTER HANDLING
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE
Ventilation:LOCAL EXHAUST AND MECHANICAL IS RECOMMENDED
Supplemental Safety and Health
ITEM IS MADE UP OF TWO PARTS, A & B. PART B IS COVERED UNDER THIS NSN.
PART A IS COVERED SEPARATELY UNDER NSN 675001-005-2137. ITEM HAS
APH OF 6.5. KEY1:C2.
================== Physical/Chemical Properties ==================
HCC:B1
Boiling Pt:B.P. Text:212F
Vapor Pres:15.
Spec Gravity:1.26
Evaporation Rate & Reference:1.0,WATER
Solubility in Water:COMPLETE
Appearance and Odor:NEARLY COLORLESS LIQUID, ESSENTIALLY NO ODOR
Percent Volatiles by Volume:72.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT LOCAL REGULATIONS. SMALL QUANTITIES MAY
BE DILUTED WITH WATER AND FLUSHED TO AN APPROVED DISPOSAL AREA
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ENAMEL, INTERIOR, NONFLAMING (DRY), CHLORINATED ALKYD RESIN,
Preparer's Name:ERNEST CARTER
CAGE:DO670
CAGE:DO670
============= Composition/Information on Ingredients =============
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
= Wt:21.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:ZINC PHOSPHATE
= Wt:16.
Ingred Name:BARIUM METABORATE
= Wt:15.
Ingred Name:CHLORENDIC ALKYD
= Wt:35.
Ingred Name:PAINT THINNER
CAS:8052-41-3
Code:F
RTECS #:WJ8925000
= Wt:9.
OSHA PEL:2900 MG/M3;500 PPM
ACGIH TLV:525 MG/M3;100 PPM
Ingred Name:DRIVERS LEVELING AGENT
CAS:136-52-7
Code:F
= Wt:3.
Ingred Name:ANTISKINNING AGENT THIXATROPIC AGENT
= Wt:1.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INGESTION: KEEP PERSON WARM, QUIET AND
GET IMMEDIATE MEDICAL ATTENTION. EYE CONTACT: CAUSES SEVERE EYE
IRRITATION. SKIN CONTACT: CAUSED PRIMARY SKIN IRRITATION. MAY BE
HARMFUL IF ABSORBED THROUGH THE SKIN. INHALATION: VAPOR AND SPRAY
MIST HARMFUL IF INHALED. VAPOR IRRITATES EYES, NOSE, THROAT. MAY
IRRITATE LUNGS. AVOID LONG TERM AND REPEATED CONTACT. PRODUCT
CONTAINS TITANIUM DIOXIDE.
Effects of Overexposure:EYE WATERING, HEADACHES, NAUSEA, DIZZINESS, AND
LOSS OF COORDINATION ARE INDICATION THAT SOLVENT LEVELS ARE TOO
HIGH. REDNESS, ITCHING, BURNING SENSATION AND VISUAL DISTURBANCES
MAY INDICATE EXCESSIVE EYE CONTACT, DRYNESS, ITCHING, CRACKING,
BURNING, REDNESS, AND SWELLING ARE CONDITIONS ASSOCIATED WITH
EXCESSIVE SKIN CONTACT.
======================= First Aid Measures =======================
First Aid:INGESTION: IF SWALLOWED, GIVE 1 OR 2 GLASSES OF WATER, BUT DO
NOT INDUCE VOMITING. EYE CONTACT: FLUSH EYES IMMEDIATELY WITH
PLENTY OF WATER FOR AT LEAST 30 MINUTES. SKIN CONTACT: FLUSH
IMMEDIATELY WI TH PLENTY OF WATER FOLLOWED BY WASHING WITH SOAP AND
WATER. INHALATION: IF AFFECTED BY INHALATION OF VAPORS OR SPRAY
MIST, REMOVE TO FRESH AIR. INGESTION, ANY TYPE OF OVEREXPOSURE OR
SYMPTOMS OF OVERE XPOSURE OCCURS DURING OR FOLLOWING THE USE OF
THIS PRODUCT.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=40.6C, 105.F
Autoignition Temp:Autoignition Temp Text:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:USE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY CHEMICAL, OR UNIVERSAL
AQUEOUS FILM FOAMING FOAM) DESIGNED TO EXTINGUISH NFPA CLASS.
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. WATER SPRAY
MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP
AND POSSIBLE AUTOIGNITION OF EXPLOSION WHEN EXPOSED TO EXTREME
HEAT. IF WATER IS USED, FO G NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND OPEN FLAMES. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:PROVIDE MAXIMUM VENTILATION. ONLY PERSONNEL
BE PERMITTED IN THE AREA. REMOVE ALL SOURCES OF IGNITION. TAKE UP
SPILLED MATERIAL WITH SAWDUST, VERICULITE, OR OTHER ABSORBENT
MATERIAL AND CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH
AN APPROVED WASTE MANAGEMENT FACILITY.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 120 DEGREES F.
STORE LARGE QUANTITIES IN BUILDING DESIGNED AND PROTECTED FOR
STORAGE OF NFPA CLASS IC FLAMMABLE LIQUIDS.
Other Precautions:IF THIS MATERIAL IS PART OF A MULIPLE COMPONENT
SYSTEM, READ THE MATERIAL SAFETY DATA SHEET(S) FOR THE OTHER
COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE
HAZARDS OF ALL OF ITS PART S.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:(NIOSH/MSHA APPROVED AIR PURIFYING OR AIR
SUPPLIED RESPIRATORS MAY ALSO REDUCE EXPOSURE.
Ventilation:PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN
VOLUME AND PATTERN.
SKIN SURFACES CONSTRUCTED
Other Protective Equipment:CLEAN OR DISCARD CONTAMINATED CLOTHING AND
SHOES.
Work Hygienic Practices:NONE
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
Boiling Pt:=154.4C, 310.F
Melt/Freeze Pt:M.P/F.P Text:NONE
Decomp Temp:Decomp Text:NONE
Vapor Pres:2.000 MMHG AT 68 F
Vapor Density:4.9
Spec Gravity:1.62-1.65
Appearance and Odor:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALIS, STRONG MINERAL ACIDS, OR STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID CONTACT WITH STRONG ALKALIS, STRONG
MINERAL ACIDS, OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE
WITH FEDERAL STATE, PROVINCLAL, AND LOCAL ENVIRONMENTAL CONTROL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:INTERIOR EXTERIOR ENAMEL (SEE SUPP DATA)
CAGE:3F871
CAGE:3F871
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS
CAS:64475-85-0
RTECS #:PY8240000
Fraction by Wt: 100%
Other REC Limits:500 PPM (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CHRONIC EXPOSURE TO ORGANIC SOLVENTS
HAS BEEN ASSOCIATED WITH VARIOUS NEUROTOXIC EFFECTS INCLUDING
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. SYMPTOMS INCLUDE LOSS OF
MEMORY, LOSS OF INTELLECTUAL ABIL ITY, AND LOSS OF COORDINATION.
CHRONIC EXPOSURE HAS ALSO BEEN ASSOCIATED WITH DERMATITIS OR
DEFATTING OF THE SKIN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:ANESTHESIA, HEADACHE, NAUSEA, DIZZINESS, ETC.
LIQUID MODERATELY IRRITATING TO SKIN AND EYES. EYES: CAN CAUSE
CONJUNCTIVITIS. SKIN: DEFATTING, DERMATITIS. MFR IDENTIFIES
INGESTION AS ROUTE OF ENTRY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: DO NOT INDUCE VOMITING. CONTACT MD IMMEDIATELY.
INHAL: REMOVE VICTIM FROM AREA AND RESTORE BREATHING IF REQUIRED.
EYE: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:105F,41C
Lower Limits:1.0
Upper Limits:6.0
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL BELOW IGNITION TEMPERATURE.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND.
================== Accidental Release Measures ==================
Spill Release Procedures:EXTINGUISH ALL SOURCES OF IGNITION IN THE
VICINITY OF SPILL OR RELEASED VAPOR. CLEAN ALL SPILLS AS SOON AS
POSSIBLE. ABSORB LARGE SPILLS WITH CLAY OR DIATOMACEOUS EARTH.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA
AWAY FROM SOURCES OF IGNITION. SHOULD BE LABELED WITH A FLAM LABEL.
WASH HANDS THORO BEFORE EATING OR SMOKING.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A NIOSH/MSHA APPROVED ORGANIC VAPOR
RESPIRATOR OR SCBA.
Ventilation:LOCAL EXHAUST IF CONCENTRATION EXCEEDS TLV.
Other Protective Equipment:USE GOOD HYGIENE PRACTICE.
Work Hygienic Practices:WASH HANDS FREQUENTLY AND THOROUGHLY DURING
CONTACT WITH MATERIAL AND AT END OF WORKDAY .
Supplemental Safety and Health
PART NO: TT-E-489F CLASS A 375-000 (19TE489CA).
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:320F,160C
Vapor Pres:7.0
Vapor Density:4.8
Spec Gravity:0.787
Evaporation Rate & Reference:0.10 (BUTYL ACETATE = 1)
Solubility in Water:NIL
Appearance and Odor:LIGHT COLORED LIQUID - HYDROCARBON ODOR.
Percent Volatiles by Volume:60
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY REACT WITH STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE
AND WATER VAPOR, INCOMPLETE COMBUSTION CAN PRODUCE CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN COMPLIANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FORANE (R) 502, 04007
CAGE:86460
CAGE:86460
============= Composition/Information on Ingredients =============
Ingred Name:CHLORODIFLUOROMETHANE (R-22)
CAS:75-45-6
RTECS #:PA6390000
= Wt:48.8
OSHA PEL:1000 PPM, 3500 MG/M3
ACGIH TLV:3540 MG/M3;1000 PPM
Ozone Depleting Chemical:2
Ingred Name:1-CHLOROPENTAFLUOROETHANE; (CHLOROPENTAFLUOROETHANE
(R-115))
CAS:76-15-3
RTECS #:KH7877500
= Wt:51.2
OSHA PEL:1000 PPM, 6320 MG/M3
ACGIH TLV:6320 MG/M3;1000 PPM
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CHLOROFLUOROCARBON (CFC) MATLS HAVE
PRODUCED SENSITIZATION OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS
& COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G.,
EPINEPHRINE) MAY BE CONTRAINDICATED EXC EPT FOR LIFE-SUSTAINING
USES IN HUMANS ACUTELY/CHRONICALLY EXPOSED TO CFC'S. . FORANE 22:
AS W/MOST LIQUEFIED GASES, CONT W/RAPIDLY VOLATILIZING LIQ/COLD VAP
CAN CAUSE FROSTBITE TO ANY TISS. BA SED ON SINGLE EXPOSURE ANIMAL
TESTS, HCFC 22 IS CONSIDERED TO BE PRACTICALLY NON-TOXIC IF
INHALED. HOWEVER, IF EXPOS TO HCFC 22 GAS @ HIGH CONCS MAY EFT
NERVOUS SYS & PRDCE RAPID ANETSTH EFT. DENSE VA P OF HCFC 22 CAN
REDUCE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZS: OXYG AVAIL FOR BRTHG & PRDCE SYMPS
SUCH AS HDCH, DIZZ, DROW, CYANOSIS & LACK OF MUSC CONTROL FOLLOWED
BY COLLAPSE. PRLGD EXPOS TO OXYG DEFICIENT ATM MAY BE FATAL. INHAL
OF HCFC 22MAY CAU SE INCR IN SENSIT OF HEART TO ADRENALINE, WHICH
COULD RSLT IN IRREG HEART BEATS & REDUCED HEART FUNC. FORANE 115:
AS W/MOST LIQUIFIED GASES, CONT W/RAPIDLY VOLATILIZING LIQ/COLD
VAPS CAN CAUSE FROSTBT TO ANY TISS DUE TO CRYOGENIC (EXTREME LOW
TEMP) EFT OF MATL. ACUTE STUDIES W/ANIMALS INDICATE CFC 115 IS
PRACTICALLY NON-TOX BY INHAL RTE. HOWEVER, EXPOS TO CFC 115 GAS AT
HIGH CONCS MAY EFT NERV SYS & PRDCE RAPID ANESTH EFT. (SUPDAT)
Medical Cond Aggravated by Exposure:WORKERS WITH HEART DISEASE OR
COMROMISED HEART FUNCTION SHOULD LIMIT EXPOSURE TO THIS MATERIAL.
======================= First Aid Measures =======================
First Aid:INGESTION: PRODUCT IS GAS AT AMBIENT CONDITIONS. NEVER GIVE
ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. SKIN: FLUSH W/LUKEWARM
WATER (NOT HOT)-OR USE OTHER MEANS TO WARM SKIN SLOWLY. GET MEDICAL
ATTENTIO N IF FROSTBITTEN BY LIQUID/IF IRRITATIONOCCURS. EYE
CONTACT: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LEAST 15
MINUTES. GET MED ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ART IFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NON FLAMMABLE
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING
FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT . KEEP CONTAINERS COOL.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODS MAY INCL
CHLORIDES, FLUORIDES & PHOSPHENE . MAY DECOMPOSE DURING CONTACT
W/FLAMES, HEATING ELEMENTS OR IN COMBUSTION ENGINES RELEASING
IRRITATING, TOXIC & CORROSIVE G ASES. CONTAINER MAY EXPLODE IF
HEATED DUE TO RESULTING PRESSURE RISE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE OR EXTINGUISH IGNITION/COMBUSTION
SOURCES. EVACUATE ENCLOSED SPACES UNTIL GAS IS DISPERSED. KEEP
UPWIND. STOP LEAK IF POSSIBLE W/OUT RISK. DISPERSE GAS
W/FLOOR-LEVEL FORCED-AIR VENTILATION. EXH AUST VAPORS OUTDOORS.
REMOVE ALL FLAMES,HEATING ELEMENTS & GAS ENGINES. WASH CONTAMINATED
CLOTHES BEFORE USE. DESTROY CONTAMINATED SHOES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NO SMOKING IN AREA OF USE. DO NOT USE
IN GENERAL VICINITY OF ARC WELDING, OPEN FLAMES/HOT SURFACES. HEAT
&/OR UV RADIA MAY CAUSE FORMATION OF CHLORIDES, FLUORIDES &
PHOSGENE . DO NOT GET IN EYES , ON SKIN/CLTHG. DO NOT BRTHE VAP,
MIST/GAS. KEEP CNTNR CLSD. KEEP AWAY FROM HEAT, SPARKS & FLAMES.
Other Precautions:STORE IN TIGHTLY CLOSED CONTAINERS. EMPTY CONTAINER
MAY CONTAIN HAZARDOUS RESIDUE. DO NOT DROP, REUSE/REFILL CONTAINER.
DO NOT SMOKE. READ LABEL BEFORE USE. DO NOT CUT, GRIND OR WELD ON
OR NEAR CONTAI NER DUE TO POSSIBLE TOXIC FUME GENERATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BRTHG VAP, MIST/FUME. USE NIOSH APPRVD
FULL FACE (TC-19C) SUPPLIED AIR RESP/SCBA WHERE AIRBORNE EXPOSURE
IS LIKELY TO EXCEED REC EXPOSURE LIMITS. IF USED, NIOSH APPRVD FULL
FACEPIECE REPLACES NE ED FOR ANSI APPRVD CHEM GOGGS AND/OR
FACESHIELD. IF EXPOS CANNOT BE KEPT AT MIN W/ENGINEERING CTLS, USE
NIOSH APPRVD RESP EQUIP AS NOTED ABOVE. (OTHER INFO)
Ventilation:INVESTIGATE ENGINEERING TECHNIQUES TO REDUCE EXPOS <
AIRBORNE EXPOS LIMS. PROVIDE VENT IF NEC TO CTL EXPOS LEVELS BELOW
AIRBORNE EXPOS LIMS (SEE (OTHER INFO)
REC FOR PROT FROM COLD.
Other Protective Equipment:EMERGENCY EYE WASH & DELUGE SHOWER MEETING
ANSI DERSIGN CRITERIA . WEAR APPROPRIATE CHEMICAL RESISTANT
PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF EXPOS: DENSE VAP OF CFC 115 DISPLACES AIR IN CONFINED PLACES &
REDUCES AVAIL OXYG FOR BRTHG. UPON EXPOS TO SUCH ATM, PERS MAY
EXPER SYMPS OF OXYG DEFICIENCY INCL HDCH, DIZZ, DROW, CYANOSIS & L
ACK OF MUSC CONTROL FOLLOWED BY COLLAPSE. PRLGD EXPOS TO
OXYG-DEFICIENT ATM MAY BE FATAL. AS W/MANY OTHER (OTHER INFO)
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:=-45.6C, -50.F
Vapor Pres:151.3 PSIA @ 70F
Vapor Density:3.8
Spec Gravity:1.22 (H*20 =1)
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, COLORLESS LIQUIFIED GAS WITH FAINT ETHEREAL
(ETHER-LIKE) ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONT W/STRONG ALKALI/ALKALINE EARTH METALS, FINELY POWDERED
METALS SUCH AS ALUMINUM, MAGNESIUM/ZINC & STRONG OXIDIZERS SINCE
THEY MAY REACT W/OR ACCELERATE DECOMPOSITION OF THIS MATERIAL.
Stability Condition to Avoid:THERMAL DECOMPOSITION DUE TO EXPOSURE TO
HEAT (>800F) OR FIRE.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS INCLUDE
HYDROGEN FLUORIDE, HYDROGEN CHLORIDE, CARBON MONOXIDE, CARBON
DIOXIDE & CHLORINE. PHOGENE .
Conditions to Avoid Polymerization:FLAMES, EXTREMELY HOT METAL
SURFACES, HEATING ELEMENTS, COMBUSTION ENGINES, ETC.
=================== Toxicological Information===================
Toxicological Information:TARGET ORGANS: EYES, SKIN, CNS, RESP SYS,
HEART. DATA FROM SCIENTIFIC LITERATURE ON CHLORODIFLUOROMETHANE ARE
SUMMARIZED: SINGLE EXPOS (ACUTE) STUDIES INDICATE: INHAL-PRACT
NON-TOXIC (2 HR-LD50 = 300, 000 (RAT), 390,000 PPM (MOUSE).
INHAL-RAT 10 MIN-EC50 = 140,000 (CNS EFTS) EYE IRRIT-SLIGHTLY IRRIT
TO RABBITS (5-30 SEC EXPOS TO GAS SPRAY). SKIN IRRIT-(MOD) IRRIT TO
RABBITS (LIQUEFIED GAS W/PATCH A PPLIED). THERE HAVE BEEN SEVERAL
ACCIDENTAL DEATHS ASSOC W/EXPOS TO CHLORODIFLUOROMETHANE/MIXTS
W/OTHER FLUOROCARBONS. DEATH WAS GEN ATTRIBUTED TO OXYG DEFICIENCY.
MICROSCOPIC EXAMINATION OF TISS OF S OME OF VICTIMS SHOWED (OTHER
INFO)
===================== Ecological Information =====================
Ecological:OTHER INFO: IN LIVER CELLS. AN INCR IN INCIDENCE OF HEART
PALPITATIONS HAVE BEEN CLAIMED BY INDIV OCCUP EXPOSED TO
CHLORODIFLUOROMETHANE. MONITORING OF WORKERS DURING OCCUP EXPOS TO
CHLORODIFLUOROMETH ANE SHOWED NO CONNECTION TO EXPOS & CARDIAC
ARRHYTHMIA OR NEUROLOGIC DISORDERS. OTHER EPIDEMIOLOGICAL STUDIES
HAVE RPTD SIMILAR RSLTS. RPTD DAILY APPLIC OF 10 SEC SPRAY CAUSED
REDDENING & SLIGHT SWELL OF SKIN & DELAY IN HAIR GROWTH. SKIN
ALLERGY WAS NOT OBSEVED IN GUINEA PIGS FOLLOWING RPTD SKIN EXPOS TO
CHLORODIFLUOROMETHANE. INHAL CAUSES INITIAL STIMULATION & THEN
DEPRESSION OF CNS. SYMPS IN ANI MALS INCL LOSS OF (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE/RECLAIM IF POSSIBLE. RECLAIMED MATERIAL
MAY BE INCINERATED BUT TOXIC & CORROSIVE COMBUSTION PRODUCTS (HF &
HCL) MUST BE HANDLED APPROPRIATELY. CONSULT FEDERAL, STATE, OR
LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES.
=================== MSDS Transport Information ===================
Transport Information:ECOLOGICAL INFO: EQUILIBRIUM, TREMORS, CONVULS,
NARCOSIS & DEATH, USUALLY ATTRIBUTED TO ASPHY. AT LEVS OF
CHLORODIFLUOROMETHANE THAT CAUSED ANESTH, DOGS EXHIBITED CONVULS.
EXPOS BY INHAL AT 300,000 TO 400,000 PPM FOR 10-15 MINS WAS FATAL
TO RABBITS, ALSO CAUSING HEMORRHAGES & EFTS ON LIVER. FOLLOWING
INHAL EXPOS TO CHLORODIFLUOROMETHANE FOR 50,000 PPM FOR 1 MONTH, NO
EFTS WERE RPTD IN GUINEA PIGS ,RATS. DOGS & CATS; 60,000 PPM FOR
2-3 MONTHS ELICITED MILD LIVER EFTS IN RABBITS; 5,000 PPM FOR 3
MONTHS CAUSED NO NEUROTOXIC EFTS IN RATS; 14,000 PPM FOR 10 MONTHS
PRDCED EFTS ON LUNGS, CNS, HEART, LIVER, KIDNEY, SPLEEN OF(FED REG
INFO)
===================== Regulatory Information =====================
SARA Title III Information:HEALTH HAZARD CATEGORIES UNDER CRITERIA OF
SARA TITLE III RULES (40 CFR PART 370): IMMEDIATE. THIS CHEMICAL
(OR CHEMICALS) IS RPTD ON U.S. ENVIRONMENTAL PROT AGENCY TOXIC
SUBSTANCES CTL ACT INVENTORY. THIS PROD CNTNS SUBSTANCE(S) WHICH
AREDEFINED AS TOXIC CHEMS UNDER, & ARE SUBJECT TO RPTG REQUIREMENTS
OF, SECTION 313 OF TITLE III OF SUPERFUND AMENDMENTS &
REAUTHORIZATION ACT OF 1986 & SECTION OF THIS MSDS FOR CHEM
IDENTITIES & CONCS: CHEM FATE INFO: NO DATA AVAIL. HAZARD
CATEGORIES UNDER CRITERIA OF SARA TITLE III RULES (40 CFR PART
370): IMMEDIATE.
Federal Regulatory Information:TRANS INFO: RATS, MICE & RABBITS, WHILE
@ 2,000 PPM NO EFTS WERE RPTD IN RATS & MICE. AN INCR IN MALIGNANT
TUMORS OF SALIVARY GLANDS WAS RPTD IN MALE RATS BUT NOT IN FEMALE
RATS/MICE OF EITHER SEX AFT ER INHAL EXPOS TO 50,000 PPM 5 HR/DAY,
5DAY/WK FOR 21 MONTHS. LONG TERM INHAL OF 5,000 PPM WAS NOT CARCIN
TO RATS & MICE. ORAL DOSING FOR 52 WKS PRDCD NO ADVERSE EFTS IN
RATS. INHAL @ LEVS UP TO 50,00 0 7 100,.000 PPM PRDCD NO ADVERSE
EFTS ON MALE REPRO PERFORMANCE IN RATS & MICE. EYE MALFORMATIONS W
ER RPTD IN RATS EXPOS BY INHAL DURING PREGNANCY AT 50,000 PPM. IN
RATS @ 1000 PPM/IN RABBITS EXPOS @ LEVS UP TO 50,000 PPM. (ST REG
INFO)
State Regulatory Information:FED REG INFO: IN RABBITS, RATS 7 HUMANS,
SM PORTION OF INHALED CHLORODIFLUOROMETHANE WAS DISTRIBUTED INTO
BRAIN, HEART, LUNGS, LIVER, KIDNEYS & FAT. IT WAS RAPIDLY ELIM FROM
BODY IN INHALED AIR. NO SI GNIFICANT METABOLISM OCCURS IN
HUMANS/RATS. RSLTS OF TESTS FOR GENETIC CHGS WERE MIXED. STUDIES
W/MICE, DOGS, RATS, RABBITS, CATS & MONKEYS HAVE SHOWN THAT INHAL
EXPOS CAN CAUSE CARDIAC ARRHYS. NOEL F OR CARDIAC SENSIT IN DOGS IS
25,000 PPM. FORANE 115: SINGLE EXPOS (ACUTE) STUDIES INDICATE
INHAL-PRA CT NON-TOX TO RATS & GUINEA PIGS (4-HR LC50 >800,000
PPM). FOR MORE DETAILED INFO ON TOXICOLOGICAL INFO CONTACT NEHC .
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FORMVAR 15/95E RESIN
CAGE:76541
CAGE:76541
============= Composition/Information on Ingredients =============
Ingred Name:RESP PROT:SUPPLIED AIR RESP. RESP PROT PROGRAMS MUST BE IN
COMPLIANCE W/29CFR1910.134.
RTECS #:9999999ZZ
Ingred Name:VENT:CONSULT NFPA STANDARD 91 FOR DESIGN OF EXHAUST SYSTEM.
RTECS #:9999999ZZ
Ingred Name:POLYVINYL ALCOHOL; (POLYMER FROM POLYVINYL ALCOHOL) MFR CAS
NO:63450-15-7
CAS:9002-89-5
RTECS #:TR8100000
Ingred Name:FORMALDEHYDE (SARA III)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: <0.1%
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:POLYVINYL ACETATE
Ingred Name:SUPDAT:PROSTHETIC SPONGE IMPLANTS USED IN HUMANS, DATA FROM
STUDIES USING IMPLANTS & CONCLUSIONS TO BE DRAWN FROM(ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:THESE STUDIES, ARE NOT CONSIDERED RELEVANT FOR
EVALUATION OF NORMAL WORKPLACE EXPOS TO POLYVINYL ALCOHOL (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:RESIN. THESE MATLS ARE NOT CONSIDERED TO POSE
CARCINOGENIC RISK TO WORKERS.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:OFFICIALS FOR INFORMATION ON SUCH DISPOSAL.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT)>5,010 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROD EXPOS LIM:PEL:15 MG/M3 TDUST, 5
RDUST (MFR). TLV:10 MG/M3 TDUST, 5 RDUST (MFR). ORAL:PRACTICALLY
NON-TOX (RATS). DERMAL:NO MORE THAN SLIGHTLY TOX (RABBITS).
EYE:SLIGHTLY IRRIT (RABBITS). DERMAL C ONT IS EXPECTED TO BE
PRIMARY RTE OF OCCUP EXPOS. OCCUP EXPOS TO MATL HAS NOT BEEN
REPORTED TO CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SIGNIFICANT ADVERSE HLTH EFTS. ON
BASIS OF AVAIL INFO, EXPOS IS NOT EXPECTED TO PRDCE SIGNIFICANT
ADVERSE HUMAN HLTH EFTS WHEN RECOM OCCUP CTL PROCS ARE FOLLOWED.
NUMBER OF STUDIES HAVE BEEN REPORTED IN WHICH ANIMALS WERE SUBJ TO
LONG TERM EXPOS TO POLYVINYL ACETATE/POLYVINYL ALCOHOL BY
SUBCUTANEOUS (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH
W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM
MD. SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD .
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY OR ANY CLASS A EXTINGUISHING AGENT.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . FIRE FIGHTING EQUIPMENT SHOULD BE THOROUGHLY
DECONTAMINATED AFTER USE.
Unusual Fire/Explosion Hazard:DUST WHEN MIXED IN SUFFICIENT QUANTITIES
W/AIR CREATES A POTENTIAL FOR EXPLOSIVE CONCENTRATIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:IN CASE OF SPILL, SWEEP UP POLYMER & DISPOSE
OF IN AS RECOMMENDED IN WASTE DISPOSAL METHOD.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE I/A/W GOOD SAFETY PRACTS. THESE
PRACTS INCL AVOIDING UNNEC EXPOS & REMOVAL OF MATL FROM EYES, SKIN
& CLOTHING. AVOID BREATHING DUST.
Other Precautions:AVOID EYE CONTACT AS GOOD INDUS PRACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPRVD EQUIP WHEN AIRBORNE EXPOS
IS EXCESS. CONSULT RESP MFR TO DETERM APPROP TYPE EQUIP FOR GIVEN
APPLICATN. RESP USE LIMITATIONS SPECIFIED BY NIOSH/MSHA/MFR MUST BE
OBSERVED. HIGH AIR BORNE CONCS MAY REQ USE OF SCBA/ (ING 8)
Ventilation:PROVIDE SUFFICIENT VENT TO MIN EXPOS. LOC MECH EXHST VENT @
SOURCES OF AIR CONTAM SUCH AS OPEN PROCESS EQUIP. (ING 9)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS & CONTAMINATED SKIN AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP:IMPLANTATION. EXPTS USING POLYVINYL ALCOHOL SPONGES
DEMONSTRATED LOC SARCOMA FORM @ SITES OF IMPLANTATION(IARC). ON
BASIS OF THESE REPORTED STUDIES, NIOSH REGISTRY OF TOX EFTS OF CHEM
SUBSTANCES REPORTED CARCIN DETERM OF "ANIMAL POS" FOR POLYVINYL
ALCOHOL. ALTHOUGH FIBROSIS HAS BEEN REPORTED FOR (ING 4)
================== Physical/Chemical Properties ==================
Spec Gravity:1.23 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE TO STRAW-COLORED, FREE-FLOWING POWDER;
SLIGHTLY PUNGENT ODOR.
Percent Volatiles by Volume:<1.5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO, CO*2, FORMALDEHYDE, ACETIC ACID,
ACROLEIN (TRACE).
==================== Disposal Considerations ====================
Waste Disposal Methods:PROD IS NOT "HAZ WASTE" AS THAT TERM IS DEFINED
IN 40CFR261, "IDENTIFICATION & LISTING OF HAZ WASTE". BURN IN
APPRVD INCIN/DISP OF IN APPRVD CHEM LANDFILL I/A/W ALL APPLIC LOC,
STATE & FED LAWS & REGS . CONSULT YOUR ATTORNEY/APPROP REGULATORY
(ING 7)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ESAB TUNGSTEN ELECTRODES
Preparer's Name:MANAGER, PRODUCT SAFETY
CAGE:1C9X2
CAGE:1C9X2
Contract Num:SP0400-00-AB-989-1684
CAGE:61125
============= Composition/Information on Ingredients =============
Ingred Name:TUNGSTEN
CAS:7440-33-7
RTECS #:YO7175000
Minumum % Wt:98.
Maxumum % Wt:100.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOE ESTABLISHED
ACGIH TLV:1 MG/M3/3 STEL; 9596
Ingred Name:CERIUM DIOXIDE
CAS:1345-13-7
RTECS #:FK6400000
Minumum % Wt:0.
Maxumum % Wt:2.
Other REC Limits:NONE RECOMMENDED
Ingred Name:LANTHANUM OXIDE
CAS:1312-81-8
Minumum % Wt:0.
Maxumum % Wt:2.
Other REC Limits:NONE RECOMMENDED
Ingred Name:THORIUM DIOXIDE (SARA 313)
CAS:1314-20-1
RTECS #:XO6950000
Minumum % Wt:0.
Maxumum % Wt:2.
Other REC Limits:NONE RECOMMENDED
Ingred Name:ZIRCONIUM OXIDE
CAS:1314-23-4
RTECS #:ZH8800000
Minumum % Wt:0.
Maxumum % Wt:1.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 TWA
OSHA STEL:5 MG/M3 REVOKED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT AS A WHOLE
Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:ELECTRODES ARE NOT HAZARDOUS AS
SHIPPED/STORED. HAZARD OCCURS WHEN USED IN ELECTRIC ARC WELDING OR
OXY-FUEL AS PROCESSES. FUMES & GASES MAY BE DANGEROUS VIA
INHALATION. HEAT & ARC RAYS CAN INJURE EYE S AND BURN SKIN.
ELECTRIC SHOCK CAN KILL.
Explanation of Carcinogenicity:THORIUM DIOXIDE HAS BEEN IDENTIFIED AS A
CARCINOGEN BY NTP, IARC AND OTHERS. EVIDENCE FOR ITS ABILITY TO
CAUSE CANCER HAS COME SOLELY FROM ITS INTERNAL MEDICAL USE.
Effects of Overexposure:SHORT TERM OVEREXPOSURE TO WELDING FUMES MAY
RESULT IN DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE, THROAT,
EYES. LONG TERM EXPOSURE TO WELDING FUMES CAN LEAD TO SIDEROSIS
(IRON DEPOSITS IN THE LUNG S) AND AFFECT PULMONARY FUNCTIONS.
Medical Cond Aggravated by Exposure:ALLERGIC REACTION IS POSSIBLE IN
SENSITIVE INDIVIDUALS, HOWEVER SUCH REACTION CANNOT BE PREDICTED
DUE TO VARIATION IN COMPOSITION AND QUANTITY OF THE DECOMPOSED
PRODUCTS.
======================= First Aid Measures =======================
First Aid:CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUES RECOMMENDED
BY THE AMERICAN RED CROSS. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL A PHYSICIAN. IF NOT BREATHING, BEGIN ARTIFICIAL RESPIRATION,
PREFE RABLY MOUTH-TO-MOUTH. IF NO DETECTABLE PULSE, BEGIN EXTERNAL
HEART MASSAGE. IMMEDIATELY CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR
SURROUNDING FIRE.
Fire Fighting Procedures:NONFLAMMABLE. USE STANDARD FIREFIGHTING
PROCEDURES FOR SURROUNDING MATERIALS IN THE FIRE.
Unusual Fire/Explosion Hazard:NONFLAMMABLE. WELDING ARC AND SPARKS CAN
IGNITE COMBUSTIBLE AND FLAMMABLE PRODUCTS. SEE ANSI Z49.1 "SAFETY
IN WELDING AND CUTTING" FOR FIRE PREVENTION, ETC.
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT FOR REUSE OR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:THORIUM DIOXIDE IS SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT OF 1986.
Other Precautions:TUNGSTEN ELECTRODES ARE NON-CONSUMABLE. HOWEVER, SOME
LOSS OF ELECTRODE METAL MAY OCCUR DEPENDING ON WELDING CONDITIONS.
THE COMPOSITION AND QUANTITY OF WELDING FUMES AND GASES ARE
DEPENDENT UPON THEMETAL BEING WELDED, THE PROCESS/PROCEDUR
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED
RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR
VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV. SELECT AS PER OSHA 29
CFR 1910.134.
Ventilation:USE ENOUGH VENTILATION LOCAL EXHAUST AT THE ARC OR BOTH TO
KEEP THE FUMES AND GASES BELOW TLVS IN WORKERS BREATHING ZONE
Other Protective Equipment:WEEAR HAND, HEAD AND BODY PROTECTION WHICH
HELP TO PREVENT INJURY FROM RADIATION, SPARKS. SEE ANSI Z49.1.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
WELDER SHOULD BE TRAINED TO KEEP HIS HEAD OUT OF FUMES AND NOT TO TOUCH
LIVE ELECTRICAL PARTS AND TO INSULATE HIMSELF FROM WORK AND GROUND.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:=3126.7C, 5660.F
Melt/Freeze Pt:=1876.7C, ######F
Spec Gravity:19.3
pH:NA
Evaporation Rate & Reference:NIL
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY METAL ROD, NO ODOR
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:GASEOUS REACTION PRODUCTS FROM WELDING
ARC MAY INCLUDE OXIDES OF CARBON, OZONE & NITROGEN OXIDES MAY BE
FORMED BY RADIATION FROM THE ARC.
=================== Toxicological Information===================
Toxicological Information:ACGIH 1988-1989 RECOMMENDED LIMIT FOR WELDING
FUME, NOT OTHERWISE CLASSIFIED (NOC) IS 5 MG/M3. TLV-TWA'S SHOULD
BE USED AS GUIDE IN THE CONTROL OF HEALTH HAZARDS AND NOT AS FINE
LINES BETWEEN SAFE AND DANGEROUS CONCENTRATIONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE
CONTAINER OR LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL
COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
===================== Regulatory Information =====================
SARA Title III Information:THORIUM DIOXIDE IS SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT OF 1986.
State Regulatory Information:CALIFORNIA PROPOSITION 65 - THIS PRODUCT
WHEN USED FOR WELDING/ CUTTING PRODUCES FUMES OR GASES WHICH
CONTAIN CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER,
BIRTH DEFECTS: CARBON MONOXIDE , THORIUM DIOXIDE. INGREDIENTS OF
THIS PRODUCT ARE LISTED ON RIGHT-TO-ACT OF FOLLOWING STATES: MA,
NJ, PA.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DOWEX SBR
CAGE:EO044
CAGE:96717
CAGE:EO044
============= Composition/Information on Ingredients =============
Ingred Name:RESIN WT% RANGE IS 25-62%(DOW)
Ingred Name:WATER, CAS7732-18-5. WT% RANGE IS 38-75% (DOW)
CAS:7732-18-5
RTECS #:ZC0110000
===================== Hazards Identification =====================
Effects of Overexposure:EYE,SKN,INHL:LOW TOX,POSS IRRT &
DEHYDRATION:POSS DEPLETION OF BODY ESSENTIAL METALS.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH 15 MIN W/AMPLE WATER.SKN: WATER WASH.INHL:REMOVETO
DUST FREE AREA.INGESTIL:LOW TOX, RESIN USUALLY PASSES GI TRACT W/O
ABSORBTION
===================== Fire Fighting Measures =====================
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP INTO CLOSED CONTAINERS. PRODUCT MAY
BE REUSED IF NOT CONTAINERS. PRODUCT MAY BE REUSED IF NOT
CONTAMINATED.
======================Handling and Storage ======================
Handling and Storage Precautions:PRACTICE REASONALBEL CARE IN CAUTION.
DO NOT STORE ABOVE 120F (DOW)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE APPD DUST RESP AS REQD.
Ventilation:NO SPECIAL VENT REQD.
Supplemental Safety and Health
ENTRY PER NON-OSHA MSDS DTD 17OCT73. SEE PNI A,B,D, THIS NSN, FOR OTHER
DOW PRODUCTS MEETING SPEC O-I-1279. %VOLATILE RANGE:38-75%.CLASS 2
TRIMETHYLAMINE QUATERNARY ANION EXCH RESIN,STR BASE
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:0.64
Solubility in Water:INSOL
Appearance and Odor:WHITE TO AMBER SOLID BEADS, ODORLESS TO AMINE ODOR
Percent Volatiles by Volume:SUPP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:BURIAL IN APPROVED LANDFILL IAW ALL LOCAL,
STATE, FEDERAL REGS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FEL-POXY FLOOR FIXER, 2421-85 PT A
Preparer's Name:JOHN MICHNA
CAGE:DO270
CAGE:73165
CAGE:DO270
============= Composition/Information on Ingredients =============
Ingred Name:EPOXY RESINS
Fraction by Wt: 95%
Other REC Limits:10 MG/CUM (DUST)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYE: IRRITATION/SENSITIZATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN: IRRITATION/SENSITIZATION.
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & WATER. IF IRRITATION OCCURS, CONSULT
PHYSICIAN. EYES: FLUSH W/TEPID WATER FOR 15 MINUTES. CONSULT
PHYSICIAN. INHALATION: REMOVE TO FRESH AIR, KEEP WARM & QUIET.
CONSULT PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>200F
Extinguishing Media:USE WATER FOG, DRY CHEMICALS, FOAM, CO2
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WHEN
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/INERT ABSORBENT MATERIAL. SWEEP/SCOOP
UP & PUT IN DISPOSAL CONTAINER. FLUSH AREA IMMEDIATELY W/PLENTY OF
WATER. PREVENT WASHINGS FROM ENTERING WATERWAY.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. PRACTICE
REASONABLE CARE & CLEANLINESS.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A NIOSH-MESA APPROVED ORGANIC VAPOR
RESPIRATOR IF VENTILATION IS INADEQUATE.
Ventilation:LOCAL EXHAUST/MECHANICAL: ACCEPTABLE (50 F.P.M.)
Other Protective Equipment:APRON/COVERALLS.
Work Hygienic Practices:PRACTICE REASONABLE CARE/CLEANLINESS.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:500F
Vapor Density:>1
Spec Gravity:1.18
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE LIQUID, CHARACTERISTIC EPOXY RESIN ODOR.
Percent Volatiles by Volume:NEGLIG
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, BASES, AMINES & MERCAPTANS.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:PYROLYSIS YIELDS, CO, CO2 &
INCOMPLETELY BURNED HYDROCARBONS.
Conditions to Avoid Polymerization:PREMATURE REACTION W/ACIDS, AMINES,
MERCAPTANS & BASES.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED INCINERATION/BURY IN A POSTED TOXIC
SUBSTANCES LANDFILL IN ACCORDANCE W/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:EPIPHEN EPOXY RESIN 825-A
Preparer's Name:ERNEST CARTER
CAGE:4Y418
CAGE:4Y418
============= Composition/Information on Ingredients =============
Ingred Name:EPOXIDIZED NOVOLAC RESIN
= Wt:80.
Ingred Name:GLYCERYL TRIGLYCIDYL ETHER
= Wt:20.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYES: MAY CAUSE EYE IRRITATION. SKIN:
MAY CAUSE SKIN IRRITATION.INHALATION: MAY CAUSE RESPIRATORY
SYSTEM IRRITATION. INGESTION: MAY BE HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:EYE CONTACT: WASH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST
15 MINUTES. DO NOT RUB EYES. SEEK MEDICAL ATTENTION. SKIN CONTACT:
WASH THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING.
CALL A PHYSICIAN. INHALATION: MOVE TO FRESH AIR. SEEK MEDICAL
ATTENTION. INGESTION: IF SWALLOWED, IMMEDIATELT DRINK A LARGE
QUANTITY OF WATER AND CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE TO BOILING
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM. AVOID WATER IF
POSSIBLE, AS WATER MAY CAUSE SPATTERING OF HOT MATERIAL AND MAY
SPREAD BURNING.
Unusual Fire/Explosion Hazard:COMBUSTION WILL RESULT IN THE RELEASE OF
THE USUAL DECOMPOSITION PRODUCTS INCLUDING OXIDES OF CARBON AND
NITROGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA AND VENTILATE. STAY UPWIND. WEAR
PROTECTIVE AS OUTLINED BELOW. ELIMINATE IGNITION SOURCES. DIKE TO
CONTROL SPILL. ABSORB WITH INERT MATERIAL. PICK UP MATERIAL AND
PLACE IN CLOSED DRUMS. LABEL FOR DISPOSAL.
Neutralizing Agent:NONE
======================Handling and Storage ======================
AVOID CONTACT WITH THE MATERIAL. AVOID PROLONGED OR REPEATED
EXPOSURE.WASH THOROUGHLY AFTER HANDLING MAT ERIAL.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR
Ventilation:VENTILATION SHOULD BE DESIGNED IN ACCORDANCE WITH GOOD
ENGINEERING PRACTICES.
MATERIAL.
Other Protective Equipment:EYEWASH AND SAFETY SHOWERS SHOULD BE
AVAILABLE AREAS WHERE THIS PRODUCT IS HANDLED.
Work Hygienic Practices:NONE
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NONE
Melt/Freeze Pt:M.P/F.P Text:NONE
Decomp Temp:Decomp Text:NONE
Spec Gravity:(H2O 1.25=1)
Appearance and Odor:LIGHT TAN VISCOUS LIQUID, VERY SLIGHT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:AVOID INTENSE HEAT FOR LONG PERIODS OF
TIME. BASES, EXCESS OF CURING AGENT.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE.
Conditions to Avoid Polymerization:MAY OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:349 STAINLESS
CAGE:EO065
CAGE:EO065
CAGE:6K906
============= Composition/Information on Ingredients =============
Ingred Name:NICKEL (SARA III)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 8.7%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
Ingred Name:TUNGSTEN
CAS:7440-33-7
RTECS #:YO7175000
Fraction by Wt: 1.4%
OSHA PEL:5 MG/M3/ 10 STEL
ACGIH TLV:5 MG/M3/10 STEL;9192
Ingred Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: 67.1%
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 9293
Ingred Name:MANGANESE (SARA III)
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: 1.2%
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
Ingred Name:CHROMIUM (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 18.9%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:DISCOMFORT SUCH AS
DIZZINESS,NAUSEA,DRYNESS,IRRITATION OF NOSE,THROAT & EYES.NI & CT
ARE CARCINOGEN.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH WELL FOR 15MIN.THEN GET MED ATTN;SKIN:WASH WITH
SOAP & WATER;INH:MOVE TO FRESH AIR;ING:GET MED ATTN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:NONE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:SEE AMERICAN NATIONAL STANDARD Z49.1
SAFETY IN WELDING & CUTTING PUBLISHED BY AMERICAN WELDING SOCIETY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRABLE FUME RESPIRATOR
Ventilation:ADEQUATE VENTILATION,LOCAL EXHAUST
Other Protective Equipment:WELDER'S PROTECTIVE CLOTHING.
Supplemental Safety and Health
MSDS DATED 12-85. "OTHER INGRED"
INCLUDE:CARBON,SILICON,MOLYBEDENUM,COLUMBIUM,TITANIUM, & TANTALUM.
================== Physical/Chemical Properties ==================
HCC:N1
Appearance and Odor:SOLID WIRE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CAN NOT BE CLASSIFIED EASILY,DEPENDING
ON PROCESS,MATL,ETC.
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PSI-690 PRIMER
Preparer's Name:E. F. CLUFF
CAGE:0KND3
CAGE:0KND3
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL SILICATE
CAS:78-10-4
RTECS #:VV9450000
Fraction by Wt: 3-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT EST.
ACGIH TLV:NOT EST.
Ingred Name:VOC: 0.4 LB/GL; 40 G/L
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
Ingred Name:DIHYDROXYPOLYDIMETHYLSILOXANE (NONHAZ)
CAS:70131-67-8
Other REC Limits:NONE RECOMMENDED
Ingred Name:POLYDIMETHYL SILOXANE (NONHAZ)
CAS:9016-00-6
RTECS #:TQ2690000
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMORPHOUS SILICA, FUMED (NONHAZ)
CAS:112945-52-5
RTECS #:VV7310000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:80 MG/M3
ACGIH TLV:NOT EST
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES/MUCOUS
MEMBRANES, HEADACHE. CHRONIC: NO LONG-TERM AFFECTS.
Explanation of Carcinogenicity:EXPLANATION: NO.
Effects of Overexposure:IRRITATION OF EYES, SKIN AND UPPER RESPIRATORY
TRACT.
Medical Cond Aggravated by Exposure:EYE, SKIN AND RESPIRATORY DISORDERS
MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:EYES-FLUSH WITH WATER FOR 15 MINUTES. SKIN- WASH WITH SOAP
AND WATER. INHALATION-REMOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING
DIFFICULT. INGESTION-WASH OUT MOUTH WITH WATER. CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:103F,39C
Lower Limits:1
Upper Limits:5.5
Extinguishing Media:CARBON DIOXIDE,, DRY CHEMICAL POWDER, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO
IGNITION SOURCE AND FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. STORE IN
APPROPIATE CONTAINER. AVOID PROLONGED INHALATION OF VAPOR OR
CONTACT WITH LIQUID. WASH RESIDUE WITH LARGE AMOUNTS OF WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID IGNITION SOURCES: FLAME, SPARKS,
EXTREME HEAT. KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions:CONTAINS <1% METHYL CHLOROFORM
(1,1,1-TRICHLOROETHANE). FOR DISPOSAL, MATERIAL MAY BE INCINERATED
WITH CARE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF LARGE AMOUNTS ARE USED IN A POORLY VENTILATED
SPACE, USE A CHEMICAL CARTRIDGE RESPIRATOR WITH ORGANIC VAPOR
CARTRIDGE (MSHA AND NIOSH APPROVED) TO PROTECT AGAINST METHYL
ISOBUTYL CARBINOL VAPORS.
Ventilation:LOCAL EXHAUST MAY BE REQUIRED IN CLOSED SPACES. RECOMMENDED
10 CHANGES PER HOUR.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:270F,132C
Melt/Freeze Pt:M.P/F.P Text:-130F,-90C
Decomp Temp:Decomp Text:NIF
Vapor Pres:3.7 MM
Vapor Density:1.59
Spec Gravity:0.80
pH:7
Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1)
Solubility in Water:98%
Appearance and Odor:COLORLESS LIQUID. PLESANT, SWEET ODOR.
Percent Volatiles by Volume:96
Corrosion Rate:NIF
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACID CHLORIDES AND OXIDIZING AGENTS.
Stability Condition to Avoid:OPEN FLAMES, SPARKS AND EXTREME HEAT.
Hazardous Decomposition Products:ETHYL ALCOHOL FROM MOISTURE CONTACT.
CO & VOLATILE ORGANICS & SILICA AEROSOLS FROM THERMAL DEGRADATION.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:K & N TYPES OF STENCIL INK
CAGE:38512
CAGE:38512
============= Composition/Information on Ingredients =============
Ingred Name:PIGMENTS
Ingred Name:VEHICLE
Ingred Name:SOLVENTS
Ingred Name:ADDITIVE
===================== Hazards Identification =====================
Effects of Overexposure:IRRIT. TO SKIN AND EYES
======================= First Aid Measures =======================
First Aid:WASH SKIN WELL FLUSH EYES WITH WATER FOR 15 MIN. INGESTED:DO
NOT INDUCE VOMIT. CALL DR. IMMED.
===================== Fire Fighting Measures =====================
Flash Point:105F,40.6 CC
Lower Limits:0.9
Upper Limits:6.0
Extinguishing Media:CARBON DIOXIDE
Unusual Fire/Explosion Hazard:AVOID FIRE,HEAT,SPARKS, IGNITION
SOURCES,STORAGE IN DIRECT SUNLIGHT.COMBUSTIBLE.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB IN SWADUST OR CLOTH.CLEAN WITH NAPHTHA.
WASH WITH SOAP AND WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:DRY INSIDE STORAGE.MAXIMUM TEMP.120F.
AVOID PROLONGED CONTACT WITH SKIN OR BREATHING OF VAPOR
Other Precautions:FOR ACCIDENTIAL EYE CONTACT.FLUSH WITH WATER AND
CONTACT DR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:YES,IF INK IS SPRAYED
Ventilation:DESIRABLE IF WORK AREA IS SMALL AND CONFINING
Other Protective Equipment:NONE
Supplemental Safety and Health
PIGMENTS:& EXTENDER PIGMENTS ALUMINUM SILICATE-BD14500;SILICON
DIOXIDE-VV73200;BARIUM SULPHATE(EXCEPT BLACK)THINNERS(ALL
COLORS)MINERIAL SPIRITS NAPHTHA.AROMATIC HYDROCRB.NAPHTHA
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:300F, 148C
Vapor Pres:<1
Vapor Density:3.9
Spec Gravity:86/1.3
Solubility in Water:NEGLIGIBLE
Appearance and Odor:NAPHTHA ODOR WHITE LIQUID
Percent Volatiles by Volume:75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
LACQUER THINNER AND ALCHOL
Stability Condition to Avoid:STORAGE ABOVE 120F
Hazardous Decomposition Products:WHEN EXPOSED TO FLAME,SOLVENT CAN
REACT W/OXIDIZING MATERIAL
Conditions to Avoid Polymerization:STORE ABOVE 120F
==================== Disposal Considerations ====================
Waste Disposal Methods:LOCAL,STATE AND FED. REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TF SOLVENT (LIQUID)
Preparer's Name:MICHAEL S. WATKINS
CAGE:2M589
CAGE:21267
CAGE:2M589
============= Composition/Information on Ingredients =============
Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA
III)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000PPM/1250STEL
ACGIH TLV:1000PPM/1250STEL9192
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(ORAL RAT)= 43,000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAN CAUSE SUFFOCATION BY
REDUCING OXYGEN AVAILABLE FOR BREATHING. MAY LEAD TO NARCOSIS,
CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH. REPEATED LIQUID
CONTACT WITH THE SKIN CAN CAUSE DEFATTI NG OF THE SKIN. CHRONIC:
UNKNOWN.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF
BREATH, IRRITATION OF THE UPPER RESPIRATORY PASSAGES FROM INHALING.
DEFATTING LEADING TO IRRITATION OF THE SKIN.
Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASE.
======================= First Aid Measures =======================
First Aid:EYES- FLUSH WITH WATER FOR AT LEAST 15 MINS. GET MEDICAL AID.
SKIN- WASH WITH MILD SOAP AND WATER. IF IRRITATION PERSISTS, SEE
DR.. INHALE- REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. IF BREATHING HAS STOPPED GIVE ARTIFICIAL RESPIRATION.
INGEST- DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NON-FLAMM.
Upper Limits:NON-FLAMM.
Extinguishing Media:NONFLAMMABLE. USE WATER FOG, CARBON DIOXIDE, FOAM,
OR DRY CHEMICAL FOR SURROUNDING FIRE.
Fire Fighting Procedures:(1/9/95 HMIS INFOMATION-KEEP CONTAINERS COOL
WITH WATER SPRAY. WEAR SELF-CONTAINED BREATHING APPARATUS.)
Unusual Fire/Explosion Hazard:DECOMPOSTION MAY OCCUR.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE OPEN FLAMES OR RED HOT
SURFACES. ALLOW TO EVAPORATE. (1/9/95 HMIS INFORMATION-EVACUATE
AREA. ABSORB SPILLED MATERIAL WITH AN INERT MATERIAL. SHOVEL (SPARK
PROOF) ABSORBENT MATER IAL INTO DRUMS AND CLOSE. PROVIDE
VENTILATION.)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. KEEP AWAY FROM OPEN FLAME, FIRE AND SPARKS. STORE IN COOL, DRY
PLACE.
Other Precautions:WASH CONTAMINATED CLOTHING BEFORE RE-USE. (1/9/95
HMIS INFORMATION-AVOID BREATHING VAPORS. VAPORS ARE HEAVY AND MAY
ACCUMULATE. PROTECT CONTAINERS FROM DAMAGE DURING STORAGE. PREVENT
LEAKAGE. INDOOR U SAGE IN CONFINED SPACE, USE DETECTOR.)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER NORMAL CONDITIONS, NO RESPIRATORY
PROTECTION IS REQUIRED. (1/9/95 HMIS INFORMATION- ABOVE 1,000 PPM,
USE SELF-CONTAINED BREATHING APPARATUS.)
Ventilation:LOCAL EXHAUST SHOULD BE USED WHEN LARGE AMOUNTS ARE
RELEASED. MECHANICAL VENTILATION SHOULD BE USED IN LOW PLACES.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT
AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING AND BEFORE
EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
(1/9/95 HMIS INFORMATION-FREON 113 MAY DILUTE OR DISPLACE OXYGEN BELOW
LEVELS NECESSARY TO SUSTAIN LIFE.)
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:118F,48C
Vapor Pres:334
Vapor Density:6.5
Spec Gravity:1.57
pH:7.0
Evaporation Rate & Reference:>1(N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH SLIGHT ETHEREAL ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:THIS COMPOUND CAN BE DECOMPOSED BY
HIGH TEMPERATURES FORMING HYDROCHLORIC AND HYDROFLUORIC ACIDS,
CARBONYL HALIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. RECLAIM BY DISTILLATION OR REMOVE TO PERMITTED WASTE
DISPOSAL FACILITY.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:(17A) MARKING PAINT-ALL COLORS, 17A
Preparer's Name:MIKE A TRAQUINA
CAGE:AERVE
CAGE:AERVE
CAGE:0UPL1
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS
CAS:8052-41-3
OSHA PEL:100 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
Ingred Name:VM & P NAPHTHA
CAS:64742-89-8
OSHA PEL:500 PPM (MFR)
ACGIH TLV:300 PPM (MFR)
Ingred Name:TOLUENE (SARA 313) (CERCLA) LD50(ORAL,RAT):258 MG/KG
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 16%
OSHA PEL:200 PPM
ACGIH TLV:S, 50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:HEXANE (N-HEXANE) (CERCLA) LD50(ORAL,RAT):287 MG/KG
CAS:110-54-3
RTECS #:MN9275000
Other REC Limits:NOT RELEVANT
OSHA PEL:500 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:XYLENE LD50(ORAL,RAT):30 MG/KG
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 2%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE)
CAS:75-28-5
RTECS #:TZ4300000
OSHA PEL:600 PPM (MFR)
ACGIH TLV:582 PPM (MFR)
Ingred Name:BUTANE; (NORMAL BUTANE)
CAS:106-97-8
RTECS #:EJ4200000
OSHA PEL:800 PPM
ACGIH TLV:800 PPM
Ingred Name:COATING VOLATILE ORGANIC COMPOUND:3.66 LBS/IMP GAL, 4.71
LBS/US GAL, 565 GMS/LTR
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION:ANESTHETIC. IRRITATION OF
THE RESPIRATORY TRACT OR NERVOUS SYSTEM DEPRESSION-CHARACTERIZED BY
HEADACHE, DIZZINESS, NAUSEA OR POSSIBLE UNCONSCIOUSNESS. SKIN/EYE
CONTACT:PRIMARY IRRITATION. P ROLONGED OR REPEATED CONT TO SKIN MAY
CAUSE DERMATITIS. EXERCISE DUE CARE.MAY CAUSE BURNING
SENSATION(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SKIN ABSORPTION:MAY CAUSE IRRITATION OR BURNING
SENSATION. INGESTION:NOT APPLICABLE. TOLUENE APPEARS ON THE NAVY
LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK
CONSULTATION FROM APPROPRIA TE HEALTH PROFESSIONALS CONCERNING
LATEST HAZARD LIST INFORMATION AND SAFE HANDLING AND EXPOSURE
INFORMATION .
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE FROM EXPOSURE AND
RESTORE BREATHING, SEEK MEDICAL ATTENTION. SKIN:WASH AFFECTED AREA,
REMOVE CONTAMINATED CLOTHING, SEE PHYSICIAN IF ANY IRRITATION PERS
ISTS. EYES:FLUSH IMMEDIATELY WITH WATERFOR AT LEAST 15 MINUTES-TAKE
TO A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-26F,-32C
Lower Limits:0.7%
Upper Limits:9.5%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER SPRAY MAY BE INEFTIVE, BUT MAY BE USED TO COOL CNTNRS
EXPOSED TO HEAT/FIRE TO PVNT PRESS BUILD UP.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO
BUILD UP OF PRESSURE FROM EXTREME HEAT OR FIRE. AEROSOL SPRAY IS
EXTREMELY FLAMMABLE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION:FLAMES, SPARKS,
STATIC ELECTRICITY AND ELECTRICAL. VENTILATE AREA AND SOAK UP WITH
INERT ABSORBENT USING NON-SPARKING TYPE TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 120F. DO NOT STORE
OR USE NEAR HEAT, SPARKS OR FLAME. DO NOT GET IN EYES. DO NOT
BREATHE VAPORS. AVOID SKIN CONTACT.
Other Precautions:DO NOT TAKE INTERNALLY. SMOKING WHILE USING THIS
PRODUCT MUST BE STRICLY PROHIBITED. IN ADDITION TO ALL OTHER
HAZARDS AND PRECAUTIONS-DUST FROM SANDING THE DRY PAINT FILMS
SHOULD BE TREATED AS A NUISA NCE DUST WITH TLV OF 10 MG/CUBIC
METER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:OUTDOORS:MFR RECOMMENDS A NIOSH/MSHA APPROVED
PARTICULATE FILTER TO REMOVE ANY AIRBORNE OVERSPRAY. IN RESITRICTED
AREAS WITH POOR VENTILATION AND CLOSE TO THE TLV A NIOSH/MSHA
APPROVED RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE IS RECOMMENDED.
Ventilation:ALL APPLICATION AREAS SHOULD BE ADEQUATELY VENTILATED IN
ORDER TO KEEP THE INGREDIENTS BELOW THEIR EXPOSURE LIMITS.
Other Protective Equipment:EMER EYE WASH & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . IMPERVIOUS APRON IS RECOMMDED TO PRVNT SKIN
CONT.
Work Hygienic Practices:AVOID PROLONGED OR REPEATED CONTACT. DO NOT
BREATHE VAPORS. WASH CONTAMINATED CLOTHING PRIOR TO RE-USE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:-10F,-23C
Vapor Density:HVR/AIR
Spec Gravity:0.8 (H*2O=1)
Evaporation Rate & Reference:FASTER/N-BUTYL ACETATE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:OPAQUE LIQUID WITH SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:4-CYANOPHENOL 95%, C9400-9
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:BENZONITRILE, P-HYDROXY-; (4-HYDROXYBENZONITRILE)
CAS:767-00-0
RTECS #:DI4375000
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF SWALLOWED, INHALED OR
ABSORBED THROUGH SKIN. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES &
UPPER RESPIRATORY TRACT. THE CHEMICAL, PHYSICAL & TOXICOLOGICAL
PROPERTIES HAVE NOT BEEN THOR OUGHLY INVESTIGATED.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN:IMMEDIATELY WASH W/SOAP & COPIOUS AMOUNTS OF
WATER. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL:REMOVE TO
FRESH AIR.IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IF DIFFICULT, GIVE OXYGEN. CALL MD. INGEST:CALL MD
IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY. CO*2, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA, RUBBER BOOTS &
DISPOSAL. AVOID RAISING DUST. VENTILATE AREA & WASH SPILL SITE
AFTER MATERIAL PICKUP IS COMPLET E.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT & INHALATION. DO NOT GET
IN EYES, ON SKIN, ON CLOTHING. TOXIC. IRRITANT. HARMFUL SOLID. KEEP
TIGHTLY CLOSED. STORE IN COOL, DRY PLACE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:SAFETY SHOWER & EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:T4
Melt/Freeze Pt:M.P/F.P Text:230F,110C
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON
DIOXIDE, NITROGEN OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX MATERIAL W/COMBUSTIBLE SOLVENT &
BURN IN CHEMICAL INCINERATOR EQUIPPED W/AFTERBURNER & SCRUBBER.
OBSERVE ALL FEDERAL, STATE & LOCAL LAWS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: SPEED BONDER 326 STRUCTURAL ADHESIVE, 32685
Cage: 05972
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 05972
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE TOXICOLOGICAL INFORMATION.
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: SEVERE EYE IRRITANT. MODERATE SKIN IRRITANT. POSSIBLE
INHALATION IRRITANT. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE KIDNEY OR LIVER
DAMAGE.
Explanation Of Carcinogenicity: SACCHARIN: IARC MONO, SUPP, VOL 7, PG 334,
1997: GRP 2B. ETHYLENE OXIDE: IARC MONO, VOL 60, PG 73, 1994: GRP 1. NTP 8TH
ANNUAL RPT ON CARCINS, 1998: REAS ANTIC TO BE CARCIN. TOLUENE DIISOCYANATE:
IARCMONO, SUPP, VOL 7, PG 56, 1987: GRP 2B. NTP 8TH ANNUAL RPT ON CARCINS,
1998: REAS ANTIC TO BE CARCIN. PROPYLENE OXIDE: IARC MONO, VOL 60, PG 181,
(SUPDAT)
Signs And Symptions Of Overexposure: IRRITATION OF EYES, SKIN, NOSE OR THROAT.
MAY CAUSE DERMATITIS ON PROLONGED CONTACT IN SENSITIVE INDIVIDUALS.
Medical Cond Aggravated By Exposure: ACRYLIC ACID: UPPER RESPIRATORY AND LUNG
DISEASES, DERMATITIS.
First Aid: INGESTION: DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTAIN
MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST,
OBTAIN MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH WITH
WATER FOR AT LEAST 15 MINUTES. OBTAIN MEDICAL ATTENTION.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SOAK UP IN AN INERT ABSORBENT. STORE IN A PARTLY
FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
Waste Disposal Methods: INCINERATE FOLLOWING EPA AND LOCAL REGULATIONS. EPA
HAZARDOUS WASTE NUMBER: NH - NOT A RCRA HAZARDOUS WASTE MATERIAL. DISPOSE OF
IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS (FP N).
Handling And Storage Precautions: STORE BELOW 100F. CONTACT LOCTITE CUSTOMER
SERVICE AT 1-800-243-4874 FOR SHELF LIFE INFORMATION. AVOID PROLONGED SKIN
CONTACT. KEEP AWAY FROM EYES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point: >93.3C, 200.F
Lower Limits: SEE ING 4
Upper Limits: SEE ING 4
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures: NOT AVAILABLE. WEAR NIOSH APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE. HAZARDOUS PRODUCTS FORMED BY FIRE OR
THERMAL DECOMPOSITION: IRRITATING ORGANIC VAPORS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NOT AVAILABLE. WEAR NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: SUFFICIENT TO MAINTAIN VAPOR CONCENTRATION BELOW TLV.
Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER
(FP N).
Supplemental Safety and Health: EXPLAN OF CARCIN: 1994: GRP 2B. NTP 8TH ANNUAL
RPT ON CARCINS, 1998: REAS ANTIC TO BE CARCIN. ACETALDEHYDE/DIOXANE: IARC
MONO, SUPP, VOL 7, PG 77, 1987: GRP 2B. NTP 8TH ANNUAL RPT ON CARCINS, 1998:
RE AS ANTIC TO BE CARCIN.PHYS/CHEM PROP: VOC (EPA METH 24): 54.6%, 606 G/L.
MATLS TO AVOID: HOWEVER, THIS PROD (OTHER INFO)
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >148.9C, 300.F
Vapor Pres: <10 MM @ 80F
Spec Gravity: 1.11 @ 80F
Solubility in Water: SLIGHT
Appearance and Odor: AMBER LIQUID WITH SHARP ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES ENTIONED ABOVE; (SUP DAT)
Stability Condition To Avoid: NOT AVAILABLE.
Materials To Avoid: STRONG OXIDIZERS, PEROXIDES, COPPER & ALLOYS, CARBON STEEL,
IRON, RUST, STRONG BASES, AMINES, ACIDS, FREE RADICAL PRODUCING INITIATORS.
THESE INCOMPATIBILITIES DO NOT PRECLUDE USE OF THIS PROD AS ADHESIVE FOR ANY
SUBSTRATE
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ESTIMATED ORAL D50 MORE THAN 5000 MG/KG. ESTIMATED
DERMAL LD50 MORE THAN 2000 MG/KG.
=======================================================
Ecological Information
=======================================================
Ecological: NO DATA AVAILABLE.
=======================================================
=======================================================
Transport Information: DOT (49 CFR 172): DOMESTIC GROUND TRANSPORT: PROPER
SHIPPING NAME: UNRESTRICTED; HAZARD CLASS OR DIVISION: UNRESTRICTED;
IDENTIFICATION NUMBER: NONE; MARINE POLLUTANT: NONE. IATA: PROPER SHIPPING
NAME : UNRESTRICTED; CLASS OR DIVISION: UNRESTRICTED; UN OR ID NUMBER: NONE.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: THE FOLLOWING COMPONENTS ARE LISTED AS SARA SECTION
313 TOXIC CHEMICALS: ACRYLIC ACID, CUMENE HYDROPEROXIDE.
State Regulatory Information: CALIFORNIA PROPOSITION 65: WARNING: THIS PRODUCT
CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND BIRTH
DEFECTS OR OTHER REPRODUCTIVE HARM: ETHYLENE OXIDE, TOLUENE DIISOCYANATE,
PROPYLENE OXIDE, ACETALDEHYDE, DIOXANE. THIS PRODUCT CONTAINS SACCHARIN. NO
PROPOSITION 65 HAZARD WARNING IS NECESSARY IF THIS PRODUCT IS USED AS
REASONABLY ANTICIPATED.
=======================================================
Other Information
=======================================================
Other Information: ESTIMATED NFPA(R) CODE: HEALTH HAZARD: 2; FIRE HAZARD: 1;
REACTIVITY HAZARD: 1; SPECIFIC HAZARD: DOES NOT APPLY. ESTIMATED (R) CODE:
HEALTH HAZARD: 2; FLAMMABILITY HAZARD: 1; REACTIVITY HAZARD: 1; PERSONAL
PROTECTION: SEE CONTROL MEASURES SECTION. NFPA IS A REGISTERED TRADEMARK OF
THE NATIONAL FIRE PROTECTION ASSOCIATION. IS A REGISTERED TRADEMARK OF THE
NATIONAL PAINT AND COATINGS ASSOCI ATION. PRODUCT TYPE: ANAEROBIC. SUPDAT:
SHOULD NOT BE STORED IN CONTR COMPOSED IN WHOLE/PART OF THESE SUBSTRATES. SEE
TECH DATA SHEET FOR ANY RESTRICTIONS OTHER THAN INCOMPATIBILITY.
=======================================================
HAZCOM Label
=======================================================
Product ID: SPEED BONDER 326 STRUCTURAL ADHESIVE, 32685
Cage: 05972
Company Name: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
Zipcode: 06067-3910
Label Required IND: Y
Date Of Label Review: 09/29/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: SEVERE EYE IRRITANT. MODERATE SKIN IRRITANT.
POSSIBLE INHALATION IRRITANT. MAY BE HARMFUL IF SWALLOWED. MAY CAUSE KIDNEY
OR LIVER DAMAGE. CHRONIC: CANCER HAZARD. CONTAINS CHEMICALS LISTED AS AN IMAL
LIVER LUNG CARCINOGENS (FP N).
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GREASE & OIL WASTEWATR CAT WW-11, PART C (INDIV 504)
CAGE:1R664
CAGE:1R664
============= Composition/Information on Ingredients =============
Ingred Name:OIL; (DISSOLVED IN CFC-113 (3:2 RATIO))
Fraction by Wt: <1.0%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: <1.0%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: PRIMARY IRRITANT. IRRITATES AND
DEFATS THE SKIN. BURNS AND IRRITATES THE EYES. MAY CAUSE COUGH,
UPPER AIRWAY IRRITATION.
Explanation of Carcinogenicity:SULFURIC ACID:IARC MONO ON EVALUATION OF
CARCIN RISK OF CHEM MIST TO MAN, VOL 54, PG 41, 1992:GROUP 1
ANIMAL:PULM IRRIT.
Effects of Overexposure:IRRITATION, BURNING AND REDNESS IN EYES.
IRRITATION AND BURNING OF SKIN. COUGH AND CHEST PAIN.
Medical Cond Aggravated by Exposure:DERMATITIS, BRONCHITIS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. SKIN: WASH WITH CLEAR
WATER. EYES: WASH WITH CLEAR WATER FOR AT LEAST 15 MINUTES.
INGESTION: GIVE 60 ML OF SYRUP OF IPECAC, THEN WATER.
===================== Fire Fighting Measures =====================
Flash Point:NOT IGNITABLE.
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:DILUTE WITH WATER. WASH TO DRAINS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:PROTECT FROM FREEZING. AVOID BREAKAGE.
Other Precautions:NONE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:IF HEATED OR MIST CREATED, USE IN HOOD.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . LABORATORY COAT AND CLOSED SHOES.
Work Hygienic Practices:NO SPECIAL REQUIREMENTS.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:23.76
Spec Gravity:1.00
pH:2.0
Evaporation Rate & Reference:1.00 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASH TO DRAINS, OR ABSORB AND DISPOSE AS
NON-HAZARDOUS. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:4-FLUORANILIN, 99%, F380-0
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:ANILINE, 4-FLUORO- (4-FLUOROANILINE, 99%)
CAS:371-40-4
RTECS #:BY1575000
Fraction by Wt: 99%
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORL,RAT)417 MG/KG; (SEE SUPP DATA)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:MAY BE FATAL IF INHALED,
INGESTED OR ABSORBED THROUGH SKIN. MATL IS EXTREMELY DESTRUCTIVE TO
TISSUE OF MUCOUS MEMBRANES & UPPER RESP TRACT, EYES & SKIN. INHAL
MAY BE FATAL AS RESULT OF SPASM, IN FLAMM & EDEMA OF LARYNX &
BRONCHI, CHEMPNEUMONITIS & PULMONARY EDEMA. ABSORPTION INTO BODY
LEADS TO (SEE SUPP DATA)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR AT LEAST
15 MINUTES. ASSURE ADEQ FLUSHING BY SEPARATING LIDS W/FINGERS.
SKIN:IMMEDIATELY FLUSH W/COPIOUS AMTS OF WATER FOR 15 MINUTES WHILE
REMOVING CONTAMINATED CLOTHING & SHOES. REMOVE/WASH CONTAMINATED
CLTHG PROMPTLY. INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE
O*2/ARTF RESP), CALL MD. INGEST:CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:165F,74C
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER,
ALCOHOL OR POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES.
COMBUSTIBLE.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA,
PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA AND WASH
SPILL SITE AFTER MATE RIAL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. KEEP AWAY
FROM HEAT AND OPEN FLAME. KEEP TIGHTLY CLOSED. DO NOT BREATHE
VAPOR. AVOID PROLONGED OR REPEATED EXPOSURE.
Other Precautions:CORROSIVE. HIGHLY TOXIC. DO NOT GET IN EYES, ON SKIN
OR CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN CHEMICAL FUME HOOD.
Other Protective Equipment:PROTECTIVE CLOTHING. SAFETY SHOWER AND EYE
BATH.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE
EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES .
Supplemental Safety and Health
LD50-LC50 MIX:LD50:(ORL,BWD)100 MG/KG. HLTH HAZ:FORMATION OF
METHEMOGLOBIN WHICH IN SUFFICIENT CONCENTRATION CAUSES CYANOSIS.
ONSET MAY BE DELAYED 2 TO 4 HOURS OR LONGER.
================== Physical/Chemical Properties ==================
HCC:T6
Boiling Pt:B.P. Text:369F,187C
Spec Gravity:1.173
Appearance and Odor:LIGHT-GOLD LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, ACID CHLORIDES, ACID ANHYDRIDES, CHLOROFORMATES, STRONG
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF:CO, CO*2, NO*X,
HYDROGEN FLUORIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMBUSTIBLE MATERIAL MAY BE BURNED IN CHEMICAL
INCINERATOR EQUIPPED W/AFTERBURNER AND SCRUBBER. DISPOSE OF I/A/W
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MIL-L-9000-G GRADE 9250
Preparer's Name:J.R.SWOAP
CAGE:7A348
CAGE:7A348
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM OIL
Fraction by Wt: <95%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/CUM AS OIL MIST
ACGIH TLV:5 MG/CUM AS OIL MIST
Ingred Name:ADDITIVE PACKAGE CONTAINING: NITROGEN, ZINC, CALCIUM,
SULFUR, PHOSPHORUS AND MAGNESIUM
Fraction by Wt: <10%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS >10 G/KG
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CAUSES MINIMAL EYE IRRITATION.
TRANSIENT MINOR IRRITATION MAY BE NOTED FOLLOWING INITIAL CONTACT.
EFFECTS OF DERMAL CONTACT SLIGHT, IF ANY. BELIEVED TO BE MINIMALLY
IRRITATING WHEN INHALED IF NOT IN E XCESS OF PERMISSIBLE
CONCENTRATIONS.
Explanation of Carcinogenicity:USED MOTOR OILS WERE SHOWN TO CAUSE SKIN
CANCER WHEN REPEATEDLY APPLIED TO MICE WITHOUT ANY EFFORT TO REMOVE
IT.
Effects of Overexposure:MAY CAUSE SLIGHT EYE, SKIN & RESPIRATORY TRACT
IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH RUNNING WATER FOR AT LEAST 15
MINUTES WHILE LIFTING EYELIDS OPEN. IF IRRITATION DEVELOPS OR
PERSISTS, GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND PLENTY OF
WATER. IF I RRITATION DEVELOPS OR PERSISTS, GET MEDICAL ATTENTION.
VAPOR INHALATION UNLIKELY: REMOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF REQUIRED. INGESTION: DO NOT INDUCE VOMITING. GET
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:430F,221C
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM, OR CARBON DIOXIDE
Fire Fighting Procedures:WEAR A NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT WHEN FIGHTING FIRES. USE
WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL IF POSSIBLE. WIPE UP OR ABSORB
ON SUITABLE MATERIAL AND SHOVEL UP.
======================Handling and Storage ======================
Handling and Storage Precautions:MINIMUM FEASIBLE HANDLING TEMPERATURES
SHOULD BE MAINTAINED. PERIODS OF EXPOSURE TO HIGH TEMPERATURES
SHOULD BE MINIMIZED. AVOID WATER CONTAMINATION.
Other Precautions:LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED
Ventilation:NORMAL ROOM VENTILATION.
Other Protective Equipment:NORMAL WORK CLOTHING COVERING ARMS & LEGS.
Work Hygienic Practices:EXERCISE REASONABLE PERSONAL CLEANLINESS.
CLEANSE EXPOSED SKIN AREAS SEVERAL TIMES DAILY WITH SOAP & WATER.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:V6
Spec Gravity:0.8927
Viscosity:85 CST @ 40C
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRIGHT & CLEAR OIL, MINERAL OIL ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER CONTAMINATION
Stability Condition to Avoid:MINIMIZE EXPOSURE TO HIGH TEMPERATURES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
ALDEHYDES AND KEYTONES, COMBUSTION PRODUCTS OF NITROGEN AND SULFUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. THIS PRODUCT DOES NOT MEET THE RCRA CRITERIA
OF A HAZARDOUS WASTE IF DISCARDED IN ITS PURCHASED FORM.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:AMPICILLIN SODIUM/SULBACTAM SODIUM IV/IM,UNASYN
CAGE:8K477
CAGE:8K477
CAGE:5M836
CAGE:04517
============= Composition/Information on Ingredients =============
Ingred Name:AMPICILLIN SODIUM
CAS:69-52-3
RTECS #:XH8400000
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM SULBACTAM/PENICILLANIC ACID DIOXIDE SODIUM SALT
CAS:69388-84-7
RTECS #:XH9220000
Other REC Limits:NONE RECOMMENDED
Ingred Name:TRADE SECRET COMPONENT
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) >50 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY
& GI TRACTS. ACUTE- EYES/SKIN:MAY BE IRRITANT RESULTING IN
HYPERSENSITIVITY. INHALE:DUST MAY BE IRRITANT RESULTING IN
HYPERSENSITIVITY/REACTIONS UNDER INGESTION. ORAL: SERIOUS &
OCCASIONALLY FATAL HYPERSENSITIVITY REACTIONS HAVE OCCURED. MAY
CAUSE CONVULSION. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DIARRHEA, RASH, CONVULSION,
HYPERSENSITIVITY
Medical Cond Aggravated by Exposure:PERSONS WITH ASTHMA, SENSITIVITY TO
MULTIPLE ALLERGENS OR KNOWN SENSITIVITY TO PENICILLINS OR
CEPHALOSPORINS
======================= First Aid Measures =======================
First Aid:CALL A DOCTOR IF SYMPTOMS PERSIST. EYE:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP &
WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
ORAL:M AY REQUIRE IMMEDIATE TREATMENT WITH EPINEPHRINE, OXYGEN,
INTRAVENOUS STEROIDS. CALL A PHYSICIAN/POISON CONTROL CENTER
IMMEDIATELY. TREATMENT SHOULD BE PERFORMED BY QUALIFIED MEDICAL
PERSONNEL.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE OR DRY CHEMICAL. USE
WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:THE COMBINATION OF THE TWO MATERIALS MAY
IGNITE OR EXPLODE AND GENERATE HIGH PRESSURE.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY
CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. DO NOT FLUSH SPILLED
MATERIAL INTO SEWER. VENTILATE AND FLUSH AREA WITH WATER TO REMOVE
FINAL TRACES. FOR LARGE SPILLS, WEAR MASK AND PROTECTIVE CLOTHING.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE VIALS UNDAMAGED, BELOW 86F (30C)
& AWAY FROM POISONS. KEEP OUT OF REACH OF CHILDREN. STORE AWAY FROM
INCOMPATIBLE MATERIALS.
Other Precautions:AS A GENERAL RULE, WHEN HANDLING PHARMACEUTICAL
PRODUCTS, AVOID ALL FORMS OF CONTACT AND INHALATION OF DUST, FUMES,
MISTS, AND/OR VAPORS ASSOCIATED WITH THE PRODUCT. IN EVENT OF A
LARGE SCALE BREAKAGE , GROUND EQUIPMENT, AVOID SPARKS & FLAME
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. WEAR A NIOSH-APPROVED
DUST RESPIRATOR OR DUST MASK IN DUSTY SITUATION. WEAR
SELF-CONTAINED BREATHING APPARATUS IN EMERGENCY.
Ventilation:ADEQUATE
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING AND/OR UNIFORM
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
NOTE TO PHYSICIAN: PENICILLINASE (NEUTRAPEN) WILL REVERSE DELAYED
PENICILLIN REACTIONS BUT IS NOT USEFUL IN ANAPHYLAXIS.
PENICILLINASE MAY CAUSE ANAPHYLACTIC REACTIONS. TREAT WITH
EPINEPHRINE, OXYGEN, INTRAVENOUS STEROIDS AND AIRWAY MANAGEMENT
INCLUDING INTUBATION, AS INDICATED.
================== Physical/Chemical Properties ==================
HCC:T6
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:M.P/F.P Text:419F,215C
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE TO OFF-WHITE POWDER, RECONSTITUTED TO PALE
YELLOW TO YELLOW SOLN,ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:TOXIC CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN, SULFUR AND SODIUM
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE SHOULD BE DISPOSED OF IN ACCORDANCE WITH
ALL LOCAL, STATE AND FEDERAL REGULATIONS. INCINERATE IN AN APPROVED
FACILITY. SMALL AMOUNTS MAY BE FLUSHED TO A SANITARY SEWER WHERE
PERMITTED BY REGULAT IONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:85475-01, ISOPROPYL ALCOHOL
Preparer's Name:R.M. CARLSON
CAGE:57020
CAGE:57020
============= Composition/Information on Ingredients =============
Ingred Name:MANUFACTURER LISTED NO INGREDIENTS IN SECTION TITLED
HAZARDOUS INGREDIENTS, INDICATING ISOPROPYL IS "NON-HAZARDOUS".
Other REC Limits:NONE RECOMMENDED
Ingred Name:ISOPROPYL ALCOHOL (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL;9495
===================== Hazards Identification =====================
LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-IRRITATION TO SKIN EYES, LUNGS,
MUCOUS MEMBRANES, G/I TRACT. NAUSEA, NARCOSIS, DROWSINESS,
DIZZINESS. CHRONIC-DERMATITIS.
Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT
CARCINOGENICITY. HMIS FOUND NO LISTING & DOES NOT EXPECT IT TO BE
CARCINOGENIC.
Effects of Overexposure:ACUTE-IRRITATION TO SKIN EYES, LUNGS, MUCOUS
MEMBRANES, G/I TRACT. NAUSEA, NARCOSIS, DROWSINESS, DIZZINESS.
CHRONIC-DERMATITIS.
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN, EYE,
RESPIRATORY DISORDERS MAY BE MORE SUSCEPTIBLE.
======================= First Aid Measures =======================
First Aid:IF ANY IRRITATION PERSISTS OR SEVERE, GET MEDICAL ATTENTION.
EYE:FLUSH W/WATER FOR 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM
CONTAMINAT ED AREA. AID OR RESTORE BREATHING AS NEEDED.
INGESTED:INDUCE VOMITING BY GIVING 2 GLASSES STICKING FINGER IN
THROAT. NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:53.6F,12.0C
Autoignition Temp:Autoignition Temp Text:399C
Lower Limits:2
Upper Limits:12
Extinguishing Media:USE WATER SPRAY, FOAM, CARBON DIOXIDE, DRY
CHEMICAL. WATER SPRAY MAY BE USED TO KEEP EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING. WATER MAY BE USED TO DILUTE SPILLS TO
NON-FLAMMABLE MIXTURE.
Unusual Fire/Explosion Hazard:VAPOR/AIR MIX IS EXPLOSIVE ABOVE FLASH
POINT & BETWEEN EXPLOSION LIMITS. VAPORS ARE HEAVIER THAN AIR, CAN
TRAVEL ALONG SURFACES TO IGNITION SOURCES & FLASH BACK
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE AREA.
USE PERSONAL PROTECTIVE EQUIPMENT. SMALL SPILLS CAN BE ABSORBED ON
PAPER & EVAPORATED IN FUME HOOD. INCINERATE PAPER. RECOVER LIQUID
WHENEVER POSSIBLE.
Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL WELL VENTILATED PLACE.
Other Precautions:READ LABEL BEFORE USING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ORGANIC CARTRIDGE.
Ventilation:USE MECHANICAL (GENERAL) VENTILATION & LOCAL EXHAUST TO
KEEP EXPOSURE <TLV.
Other Protective Equipment:LAB COAT
Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:F3
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:-128F,-89C
Melt/Freeze Pt:M.P/F.P Text:180F,82C
Vapor Pres:33 MM
Vapor Density:2.1
Spec Gravity:0.79
Evaporation Rate & Reference:1.7 (N-BUAC = 1)
Solubility in Water:100%
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILD ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ALUMINUM, PERCHLORIC ACID, CHLORINE, ETHYLENE OXIDE.
Stability Condition to Avoid:AVOID HEAT & IGNITION SOURCES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:CAN BE LIQUID INCINERATED IN RCRA APPROVED
COMBUSTION CHAMBER OR ABSORBED ON INERT MATERIAL. SCOOP UP
W/NON-SPARKING TOOLS & PLACE IN CLOSED CONTAINER. DISPOSE IN RCRA
APPROVED FACILITY I/A/W FEDERAL, STATE & LOCAL REGULATIONS. DO NOT
FLUSH TO SEWER.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: OTR PREMIUM PLUS 4, 44-440-1
Cage: XNDEX
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: XNDEX
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE CONTACT: EYE IRRITANT. BASED ON DATA FROM COMPONENTS
OR SIMILAR MATERIALS. SKIN CONTACT: SKIN IRRITANT. BASED ON DATA FROM
COMPONENTS OR SIMILAR MATERIALS. PROLONGED OR REPEATED SKIN CONTACT MAY C
AUSE DERMATITIS. SYMPTOMS MAY INCLUDE REDNESS, EDEMA, DRYING, DEFATTING AND
CRACKING OF SKIN. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: INHALATION: EXPOSURE TO VAPORS
AT ELEVATED TEMPERATURES MAY CAUSE RESPIRATORY IRRITATION. INGESTION:
SWALLOWING THE MATERIAL MAY CAUSE IRRITATION OF THE GASTROINTESTINAL LINING,
NAUSEA, VOMI TING, DIARRHEA AND ABDOMINAL PAIN.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: FLUSH IMMED W/WATER FOR AT LEAST 15 MIN. GET IMMED MED ATTN.
SKIN: WASH IMMED W/SOAP & WATER. REMOVE CONTAMD CLTHG. GET MED ATTN IF
IRRIT PERSISTS. LAUNDER CONTAMD CLTHG BEFORE REUSE & DISCARD S HOES &
OTHER LEATHER ARTICLES SATURATEDW/MATL. INHAL: REMOVE EXPOS PERSON TO FRESH
AIR. IF ADVERSE EFTS ARE OBSERVED SEEK MED ATTN. INGEST: DO NOT INDUCE VOMIT.
IF CONSCIOUS, GIVE 2 GLASSES (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: PERSONAL PROTECTIVE EQUIPMENT MUST BE WORN. VENT AREA
IF SPILLED IN CONFINED SPACE OR OTHER POORLY VENTD AREAS. PREVENT ENTRY INTO
SEWERS & WATERWAYS. PICK UP FREE LIQUID FOR RECYCLE &/OR DISPOSAL. RE
SIDUAL LIQUID CAN BE ABSORBED ON INERT MATERIAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: CONSULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL TO
ENSURE CONFORMITY TO LOCAL, STATE AND FEDERAL DISPOSAL REGULATIONS.
Handling And Storage Precautions: OPEN CONTAINER IN A WELL VENTILATED AREA.
AVOID BREATHING VAPORS. KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions: WASH THOROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. EMPTY CONTAINER CONTAINS PRODUCT RESIDUE WHICH MAY
EXHIBIT HAZARDS OF PRODUCT.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: 171F,77C
Extinguishing Media: USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS. USE FOAM,
DRY CHEMICAL OR WATER TO EXTINGUISH FIRE.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). USE WATER TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: TOXIC FUMES, GASES OR VAPOR MAY EVOLVE ON
BURNING.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH APPRVD FULL FACE RESPIRATOR W/COMBINATION
ORGANIC VAPOR & HIGH EFFICIENCY FILTER CARTRIDGE IF EXPOSURE LIMIT IS
EXCEEDED. USE NIOSH APPRVD SELF CONTAINED BREATHING APPARATUS FOR ENTRY INTO
C ONFINED SPACE & FOR OTHER (SUPDAT)
Ventilation: USE LOCAL EXHAUST VENTILATION TO CONTROL MISTS OR VAPORS AT A
LEVEL BELOW THE ESTABLISHED EXPOSURE LIMITS.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). LONG
SLEEVE SHIRT & LONG PANTS RECOMD. USE PROTECTIVE BOOTS (SUPDAT)
Work Hygienic Practices: DO NOT WEAR RINGS, WATCHES/SIMILAR APPAREL THAT COULD
ENTRAP MATL & CAUSE SKIN RXN. LAUNDER CONTAMD CLTHG BEFORE REUSE.
Supplemental Safety and Health: HAZ DECOMP PRODS: OXIDES OF THE FOLLOWING
ELEMENTS MAY BE FORMED: NOT DETERMINED. FIRST AID PROC: OF WATER. GET IMMED
MED ATTN. RESP PROT: POORLY VENTILATED AREAS & FOR LARGE SPILL CLEAN-UP
SITES. OTH ER PROT EQUIP: WHEN NECESSARY TO AVOID CONTAMINATING SHOES.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 0.9 @ 60F
Solubility in Water: INSOLUBLE
Appearance and Odor: DARK RED LIQUID; MILD AROMATIC ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: SMOKE, CARBON MONOXIDE, ALDEHYDES AND OTHER
PRODUCTS OF INCOMPLETE COMBUSTION. UNDER COMBUSTION CONDITIONS, (SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: OTR PREMIUM PLUS 4, 44-440-1
Cage: XNDEX
Company Name: INDEX INDUSTRIES INC
Street: 1645 EASTERN AVD SE
Zipcode: 49507
Label Required IND: Y
Date Of Label Review: 12/17/1996
Status Code: C
Label Date: 12/17/1996
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: EYES: IRRITANT. SKIN: IRRITANT.
INHALATION: RESPIRATORY IRRITATION. INGESTION: IRRITATION OF GASTROINTESTINAL
LINING, NAUSEA, VOMITING, DIARRHEA AND ABDOMINAL PAIN. CHRONIC: PROLON GED OR
REPEATED SKIN CONTACT MAY CAUSE DERMATITIS WITH REDNESS, EDEMA, DRYING,
DEFATTING AND CRACKING OF SKIN.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BRAKE SHOE
Preparer's Name:BARBARA BOROUGHF
CAGE:78500
CAGE:78500
============= Composition/Information on Ingredients =============
Ingred Name:ASBESTOS, CHRYSOTILE
CAS:12001-29-5
RTECS #:CI6478500
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:2 FIBERS/CC; A1;9293
Ingred Name:SILICA, SILICATES, CRYSTALLINE - TRIPOLI
CAS:1317-95-9
RTECS #:VV7336000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9293
Ingred Name:GRAPHITE, SYNTHETIC, COAL, COKE
CAS:7440-44-0
RTECS #:FF5250100
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9293
Ingred Name:PHENOLIC, ISOPRENE OR CASHEW RESINS
Other REC Limits:5 MG/M3
OSHA PEL:15 MG/M3 TOTAL DUST
ACGIH TLV:10 MG/M3 TOTAL DUST
Ingred Name:WOOD FLOUR AND OTHER FILLERS
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3/ 10 STEL
ACGIH TLV:1 MG/M3
Ingred Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 9293
Ingred Name:ZINC (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG ZNO/M3
ACGIH TLV:10 MG ZNO/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15MG/M3 DUST/5 FUME
ACGIH TLV:10MG/M3 DUST; 9293
Ingred Name:MAGNESIUM OXIDE
CAS:1309-48-4
RTECS #:OM3850000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 PARTICULATE
ACGIH TLV:10 MG/M3;TDUST; 9293
Ingred Name:COPPER (SARA III)
CAS:7440-50-8
RTECS #:GL5325000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2MG/M3 FUME; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
CAS:1317-65-3
RTECS #:EV9580000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:FLUORIDES (TOTAL), AS FLUORINE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2.5 MG/M3
ACGIH TLV:2.5 MG/M3
Ingred Name:RUBBER
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TOTAL DUST
ACGIH TLV:10 MG/M3 TOTAL DUST
Ingred Name:BARIUM (SARA III)
CAS:7440-39-3
RTECS #:CQ8370000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG/M3; 9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: METAL DUSTS CAN IRRITATE EYES
AND UPPER RESPIRATORY SYSTEM. CASHEW RESINS MAY CAUSE DERMATITIS.
CHRONIC: DUST FROM ABRASIVE ACTIONS CONTAIN ASBESTOS FIBERS.
CHRONIC OVEREXPOSURE TO AIRBORNE FIB ERS MAY LEAD TO ASBESTOSIS AND
MESOTHELIOMA. SMOKING COMBINED WITH FIBER INHALATION GREATLY
INCREASES LUNG CANCER RISK.
Explanation of Carcinogenicity:ASBESTOS IS LISTED BY AIRC, NTP AND
OSHA.
Effects of Overexposure:INHALATION: COUGHING, WHEEZING, SHORTNESS OF
BREATH, IMPAIRED PULMONARY FUNCTION. SKIN: ITCHING, RASH. EYES:
MECHANICAL IRRITATION FROM AIRBORNE DUST. INGESTION:
GASTROINTESTINAL DISTURBANCES.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING SKIN
OR RESPIRATORY CONDITIONS MAY BE MORE AT RISK FROM EXPOSURE TO
DUSTS OF THIS PRODUCT. WILSON'S DISEASE MAY BE AGGRAVATED BY
EXPOSURE TO COPPER.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE. SKIN:
WASH EXPOSED AREA WITH SOAP AND WATER. EYES: FLOOD WITH WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTENTION. INGESTION: DRINK WATER.
DO NOT INDUCE VOMITING. SEE DOCTOR. OTHER: CHANGE CLOTHING AS
REQUIRED TO AVOID CARRYING DUST PARTICLES INTO OTHER AREAS.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER OR CLASS A, B OR C EXTINGUISHER.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMCIAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED
WITH AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS
FIBERS TO THE ATMOSPHERE.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED AND BECOME
AIRBORNE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A NIOSH/
MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED. CONSULT YOUR
SAFETY OFFICE/INDUSTRIAL HYGIENIST PERSONNEL FOR GUIDANCE FOR THE
TASK AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR INDUSTRIAL HYGIENIST
PERSONNEL.
Work Hygienic Practices:DO NOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS.AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
NONE.
================== Physical/Chemical Properties ==================
HCC:T6
Spec Gravity:1.6-3.0
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:BRAKE SHOE. SOLID. LIGHT TAN TO DARK GRAY IN COLOR.
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZERS FOR LININGS WITH RUBBER CONTENT.
Stability Condition to Avoid:AVOID CREATING AND BREATHING DUST.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION MAY CREATE TOXIC
FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FR IABLE OR NON-FRIABLE".
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:LIQUID PHENOLIC RESIN ALPHASET 9015
CAGE:86142
CAGE:86142
============= Composition/Information on Ingredients =============
Ingred Name:ING 6: DETERMINE WHETHER OR NOT YOUR PROGRAMS ARE ADEQUATE.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: IRRIT (PRIMARY SKIN IRRIT INDEX <5.0/8.0)
WHEN TESTED AS DESCRIBED IN 16 CFR PART 1500.41. EYES:(ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: CAUSES BURNS.SIMILAR PROD WAS SEV IRRIT WHEN TESTED
AS DESCRIBED IN 16 CFR PART 1500.42. CHRONIC: ING 1: (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:POTNTL CANCER HAZ. RATS CHRONICALLY EXPOS TO 14 PPM
FORMALDEHYDE CONTRACTED NASAL CANCERS, BASED ON ANIMAL(ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10: DATA & LIMITED EPIDEMIOLOGICAL EVIDENCE, NTP,IARC &
OSHA HAVE LISTED FORMALDEHYDE AS PROBABLE HUMAN (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: HUMAN CARCIN. MAY CAUSE ALLERGIC SKIN RXN. SOME
RPTS SUGGEST FORMALDEHYDE MAY CAUSE ASTHMA AND THAT (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: PRE-EXISTING RESP & SKIN DISORDERS MAY BE
AGGRAVATED BY EXPOS. ING 2: CAN CAUSE CNS DEPRESS. SIGNS & (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:SYMPS MAY INCL HDCH, DIZZ,NAUS, VOMIT & DROW. ING 3:
CAN CAUSE LIVER DMG. CAN CAUSE KIDNEY DMG. CAN CAUSE(ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: CNS DEPRESS. SIGNS & SYMPS MAY INCL HEADACHE,
DIZZINESS, NAUSEA, VOMITING, UNCONSCIOUSNESS & EVEN ASPHYXIATION.
RTECS #:9999999ZZ
Ingred Name:EXPLAN OF CARCIN: IARC MONOGRAPHS VOL SUPPLEMENT 7, P. 211,
1987;OSHA REGULATED, 29CFR1910.1048, REV JUL 1, 1992.
RTECS #:9999999ZZ
Ingred Name:FORMALDEHYDE (SARA III)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: 0.1-1%
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:ETHYL ALCOHOL; (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 1-5%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ingred Name:PHENOL (SARA III)
CAS:108-95-2
RTECS #:SJ3327000
Fraction by Wt: 1-5%
OSHA PEL:5 PPM, S
ACGIH TLV:5 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 10-30%
OSHA PEL:2 MG/M3, C
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SUPP DATA:COMBINATION W/APPROP USE OF PERS PROT EQUIP &
PRUDENT WORK PRACTS. THESE TECHNIQUES MAY NOT NEC ADDRESS(ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: ALL ISSUES PERTAINING TO YOUR OPERS. WE, THEREFORE,
RECOM THAT YOU CONSULT W/EXPERTS OF YOUR CHOICE TO (ING 7)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: SKIN ABSORP: SIMILAR PROD WAS
FOUND TO BE NON-TOX DERMALLY WHEN TESTED AS DESCRIBED IN 16 CFR
PART 1500.3 (C) (1) & (2). INGEST: SIMILAR PROD WAS FOUND TO BE
NON-TOX ORALLY WHEN TESTED AS DESCR IBED IN 16 CFR PART 1500.3 (C)
(1) & (2). INHAL: NOT EXPECTED TO BE HARMFUL UNDER NORM CNDTNS OF
USE, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE: ANTICIPATED TO BE A
CARCINOGEN, NTP SIXTH ANNUAL REPORT ON CARCINOGENS, 1991 SUMMARY;
GROUP 2A, (ING 16)
Effects of Overexposure:HLTH HAZ: HOWEVER, OVEREXP MAY CAUSE CNS
DEPRESS. ALSO, IF ALLOWED TO BECOME AIRBORNE, MAY CAUSE IRRIT OF
NOSE, THROAT & LUNGS. SIMILAR PROD WAS FOUND TO BE NON-TOX BY INHAL
WHEN TESTED AS DESCRIBED I N 16 CFR PART 1500.3 (C) (1) & (2).
SKIN: MAY CAUSE IRRIT ON PRLNGD/RPTD CONT. SIMILAR PROD WAS NOT
PRIMARY (ING 8)
Medical Cond Aggravated by Exposure:FORMALDEHYDE: PRE-EXISTING
RESPIRATORY AND SKIN DISORDERS MAY BE AGGRAVATED BY EXPOSURE.
======================= First Aid Measures =======================
First Aid:INGEST: DILUTE BY DRINKING LARGE QTYS OF WATER. IMMED CONTACT
POISON CONTROL CENTER OR HOSPITAL EMERGENCY ROOM FOR ANY OTHER
ADDITIONAL TREATMENT DIRECTIONS. INHALATION: REMOVE TO FRESH AIR.
SKIN: FLU SH WITH WATER. EYE: IMMEDIATELY FLUSH WITH PLENTY OF
WATER FOR AT LEAST 15 MINUTES. EYELIDS SHOULD BE HELD APART DURING
IRRIGATION TO INSURE WATER CONTACT W/ENTIRE SURF OF EYES & LIDS.
CALL PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:115F,46C
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, "ALCOHOL" FOAM OR CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE WATER TO KEEP FIRE-EXPOSED CONTAINERS
COOL.
Unusual Fire/Explosion Hazard:COMBUSTIBLE. KEEP AWAY FROM HEAT AND
FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. LARGE
QUANTITIES: ENCLOSE WITH DIKING MATERIAL TO PREVENT SEEPAGE INTO
NATURAL BODIES OF WATER, THEN CONSULT BORDEN, INC. SMALL
QUANTITIES: SOAK UP WITH ABSORBENT MATER IAL AND REMOVE TO CHEMICAL
DISPOSAL AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN COOL,
DRY PLACE. EMPTY CONTAINER MAY CONTAIN PRODUCT RESIDUES. DO NOT
CUT, TORCH OR REUSE WITHOUT COMMERCIAL CLEANING.
Other Precautions:USE WITH ADEQUATE VENTILATION. STORAGE LIFE AT 70F-1
MONTH. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID
PROLONGED OR REPEATED CONTACT WITH SKIN. DO NOT GET IN EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE AIR CONTAMS CAN EXCEED ACCEPTABLE
CRITERIA, USE NIOSH/MSHA APPROVED RESP PROTECTION EQUIPMENT.
RESPIRATORS SHOULD BE SELECTED BASED ON FORM & CONCENTRATION OF
CONTAMS IN AIR I/A/W OSHA 29 CFR 19 10.134/OTHER APPLIC STDS OR
GUIDELINES.
Ventilation:IF AIRBORNE CONTAMS ARE GEN WHEN MATL IS HEATED/HNDLD, SUFF
VENT IN VOL & AIR FLOW PATTERNS SHOULD BE PROVIDED (SUPDAT)
Other Protective Equipment:WHERE FULL PROTECTIVE SUIT AND BOOTS IF
CONTACT IS LIKELY.
Work Hygienic Practices:HNDL I/A/W GOOD INDUS HYGIENE & SAFETY PRACT.
PRACTS INCL AVOIDING UNNEC EXPOS & REMOVAL OF MATL FROM EYES,SKIN
(SUPDAT)
Supplemental Safety and Health
SPEC GRAV: 1.205-1.220 @ 25/25C. PH: 11.5-12.30 @ 25C. HYGIENE PRACT: &
CLTHG. WASH THORO AFTER HNDLG. VENT: TO KEEP AIR CONTAM CONC LEVS
BELOW ACCEPTABLE CRITERIA. FOLLOWING EXPOS CNTRL TECHNIQUES MA Y BE
USED TO EFT MIN EMPLOYEE EXPOS: LOC EXHST VENT, ENCLOSED SYS
DESIGN, PROCESS ISOLATION & REMOTE CNTRL IN (ING 5)
================== Physical/Chemical Properties ==================
HCC:F4
Spec Gravity:SUPP DATA
pH:SUPDAT
Appearance and Odor:DARK LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS.
Stability Condition to Avoid:HIGH TEMPERATURES (MAY BECOME UNSTABLE).
Hazardous Decomposition Products:OXIDES OF CARBON, ALDEHYDES (INCLUDING
FORMALDEHYDE), PHENOLS, AROMATIC HYDROCARBONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECOVER FREE LIQUID. ABSORB RESIDUE AND DISPOSE
OF ACCORDING TO LOCAL, STATE/PROVINCIAL, AND FEDERAL REQUIREMENTS.
EMPTY CONTAINER: MAY CONTAIN EXPLOSIVE VAPORS. DO NOT CUT, PUNCTURE
OR WELD ON OR NEA RBY.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MIL-C-46168D, TY II P/C 03Y090
Kit Part:Y
Preparer's Name:NORM GAUL
CAGE:5M511
CAGE:33461
CAGE:5M511
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL 3-ETHOXYPROPIONATE (VAPOR PRESSURE 0.7 MM HG @ 68F)
CAS:763-69-9
RTECS #:UF3325000
Fraction by Wt: 5%
Other REC Limits:50 PPM; STEL 100 PPM
Ingred Name:N-BUTYL ACETATE (SARA III) (VAPOR PRESSURE 13 MM HG @ 68F)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 25%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:150 PPM;STEL 200 PPM
ACGIH TLV:150 PPM;STEL 200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:MINERAL SPIRITS (VAPOR PRESSURE 2 MM HG @ 68F) (NIOSH
LIMIT: 350 MG/M3--8 HOUR; 1800 MG/M3--15 MINUTE SAMPLE)
CAS:64475-85-0
RTECS #:PY8240000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:C8&10 AROMATIC HYDROCARBON (VAPOR PRESSURE 3 MM HG @ 68F)
CAS:64742-95-6
Fraction by Wt: <1%
Other REC Limits:MFR PEL: 100 PPM
Ingred Name:DISPERSION AGENT (VAPOR PRESSURE 0 MM HG)
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ANTI-FLOAT AGENT (VAPOR PRESSURE 0 MM HG)
CAS:1317-65-3
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:YELLOW PIGMENT (VAPOR PRESSURE 0 MM HG)
CAS:36888-99-0
Fraction by Wt: 2.52%
Other REC Limits:NONE RECOMMENDED
Ingred Name:METHYL ISOBUTYL KETONE (SARA III) (VAPOR PRESSURE 15 MM HG
@ 68F)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 6.3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:50 PPM; STEL 75 PPM
ACGIH TLV:50 PPM; STEL 75 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ANTI MAR AGENT (VAPOR PRESSURE 0 MM HG)
Fraction by Wt: <0.1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:XYLENE (SARA III) (VAPOR PRESSURE 21 MM HG @ 100F)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 0.04%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM;STEL 150 PPM
ACGIH TLV:100 PPM;STEL 150 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ETHYL BENZENE (SARA III) (VAPOR PRESSURE 7.1 MM HG @ 68F)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 0.02%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM;STEL 125 PPM
ACGIH TLV:100 PPM;STEL 125 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:DIBUTYLTIN DILAURATE (VAPOR PRESSURE 0.2 MM HG @ 320F)
CAS:77-58-7
RTECS #:WH7000000
Fraction by Wt: <0.1%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:0.1 MG/M3
Ingred Name:VOC: 548 G/L
RTECS #:9999999VO
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: RESP TRACT IRRIT, ACUTE NERVOUS
SYS DEPRESSN (HEADACHE, DIZZY, STAGGERING, CONFUSION, UNCONSCIOUS,
COMA). SKIN: IRRIT (SWELL, RED, RASH). ABSORPTION: IRRIT, DRYING,
DEFATTING (CRACKING). EYE: I RRIT (TEARING, RED, SWELL W/STING).
INGEST: IRRIT, CORROSIVE IN GI TRACT. VOMITING MAY CAUSE
ASPIRATION-CHEM PNEUMONITIS
Effects of Overexposure:ACUTE: VAPORS ARE IRRITATING TO EYES, NOSE, &
THROAT. INHALATION MAY CAUSE HEADACHES, DIFFICULT BREATHING & LOSS
OF CONSCIOUSNESS. CHRONIC: PROLONGED CONTACT
WILL CAUSE DRYING A ND CRACKING OF THE SKIN, DUE TO DEFATTING
ACTION. SKIN SENSITIZATION, ASTHMA OR OTHER ALLERGIC RESPONSES MAY
DEVELOP.
Medical Cond Aggravated by Exposure:HARMFUL IF SWALOWED OR ABSORBED
THROUGH SKIN. MAY CAUSE LIVER OR KIDNEY DAMAGE.
======================= First Aid Measures =======================
First Aid:INHAL: MOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC TYPE
SYMPTOMS MAY DEVELOP (IMMED/DELAYED). GET MEDICAL ATTENTION. SKIN:
REMOVE CONTAMINATED CLOTHING. WASH W/SOAP & WATER. WASH CONTAM
CLOTHING B EFORE REUSE. EYES: FLUSH W/CLEAN LUKEWARM WATER (LOW
PRESSURE) 15 MIN, OCCASIONALLY LIFT EYELID. GET MED AID. INGESTION:
DON'T INDUCE VOMITING. NOTHING BY MOUTH TO UNCONSCIOUS PERSON. GET
MEDICAL AID.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:60.0F,15.6C
Lower Limits:0.90
Upper Limits:8.00
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG,
WATER SPRAY
Fire Fighting Procedures:WEAR FULL FIRE FIGHTING EQUIP W/SCBA & FULL
PROTECTIVE CLOTHING. USE WATER TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP, AUTO IGNITION, OR EXPLOSION.
Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD. KEEP FROM HEAT/IGNIT
SOURCE. CLSD CNTNR MAY EXPLODE W/HEAT. APPLIC TO HOT SURFACE REQ
SPECIAL PRECAUTION. OVEREXPOSURE TO DECOMP PROD-HLTH HZD.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES).
VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND
NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN BUILDINGS DESIGNED TO COMPLY
WITH OSHA 1910.106. AVOID STORING NEAR HIGH TEMPERATURES/IGNITION
SOURCES. STORE IN CLSD CNTNR IN VENTED AREAS.
Other Precautions:KEEP CNTNR TIGHT & UPRIGHT (PREVENT LEAK). PREVENT
PROLONGED VAPOR BREATHING. PROLONGED OVEREXPOSURE MAY CAUSE
ALLERGIC REACTION. AVOID CONTACT W/SKIN & EYES. DON'T INGEST. DON'T
HANDLE TILL MFR SFTY PRECAUTIONS HAVE BEEN READ & UNDERSTOOD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATOR RECOMMENDED FOR ORGANIC VAPOR
ENVIRONMENT (AIR PURIFYING OR FRESH AIR SUPPLIED). OBEY OSHA REGS
FOR RSPRTR USE. PROVIDE VENT TO KEEP EXPOSURE LEVELS BELOW PEL. IF
TLV MAINTAIN, OTHER OSHA/N IOSH RESPIRATOR MAY BE USED.
Ventilation:EXHAUST VENT TO KEEP AIRBORNE CONCENTRATIONS BELOW TLV'S.
REMOVE ALL IGNITION SOURCES.
Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING
IS RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING, OR USING
WASHROOM. SMOKE IN SMOKING AREAS ONLY.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:241 TO 401F
Vapor Density:> AIR
Spec Gravity:1.47419
Viscosity:**
Evaporation Rate & Reference:0.82 X N-BUTYL ACETATE
Solubility in Water:INSOLUBLE
Appearance and Odor:YELLOW LIQUID WITH SOLVENT ODOR
Percent Volatiles by Volume:62.9
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OR OPEN FLAMES
Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON
MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORD WITH FEDERAL, STATE,
& LOCAL ENVIRONMENTAL CONTROL REGULATIONS. HANDLE EMPTY CONTAINERS
W/CARE DUE TO PRODUCT RESIDUE & FLAMMABLE VAPORS. DON'T INCINERATE
CLOSED CONTAINERS.EPA CODE: D001, F003, F005. IGNITABLE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:#2 DIESEL LOW SULFUR
CAGE:JO756
CAGE:8P539
CAGE:JO756
============= Composition/Information on Ingredients =============
Ingred Name:HYDROCARBONS, AROMATIC
Fraction by Wt: 15-45%
Other REC Limits:NONE RECOMMENDED
Ingred Name:OLEFINS (UNSATURATED HYDROCARBONS)
Fraction by Wt: 1-6%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
Ingred Name:PARAFFINS & CYCLOPARAFFINS (SATURATED HYDROCARBONS)
Fraction by Wt: 54-85%
Other REC Limits:NONE RECOMMENDED
Ingred Name:COMPLEX MIXTURE OF PARFFINIC, CYCLOPARAFFINIC, OLEFINIC AND
AROMATIC HYDROCARBONS
Fraction by Wt: N/GIVEN
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL OR FATAL IF SWALLOWED.
PRODUCES SKIN IRRITATION UPON PROLONGED OR REPEATED CONTACT.
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY N/A FOR NTP,
IARC, OSHA.
Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION FOLLOWING
REPEATED CONTACT. INGESTION MAY CAUSE ACUTE GASTRIC. ACUTE CHEMICAL
PNEUMONITIS. ASPIRATION CAN RESULT IN RESPIRATORY DISTRESS.
Medical Cond Aggravated by Exposure:N/A.
======================= First Aid Measures =======================
First Aid:EYE:RINSE THOROUGHLY W/WATER. SKIN:WASH THOROUGHLY W/SOAP &
WATER. INHAL:REMOVE FROM CNTAMINATED AREA. GIE FRESH AIR.
INGEST:GIVE VEGETABLE OIL TO RETARD ABSORBTIN. DO NOT INDUCE VOMIT.
GET IMMED MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:130F,54C (MIN)
Lower Limits:7.5
Upper Limits:0.6
Extinguishing Media:ANY UL APPROVED CLASS B MEDIA SUCH AS FOAM, CARBON
DIOXIDE, OR DRY CHEMICAL.
Fire Fighting Procedures:AVOID USE OF SOLID WATER STREAMS. AVOID
EXCESSIVE WATER SPRAY APPLICATION. WATER CAN BE USED TO COOL
EXPOSED SURFACES.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MFG.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP PUBLIC AWAY.SHUT OFF SOURCE W/O HAZ.
ADVISE POLICE & NATL RESPONSE CENTER 800-424-8802 IF SUBSTANCE
ENTERED WATERCOURSE OR SEWER. CONTAIN LIQUID W/EARTH/SAND. RECOVER
FREE LIQUID BY PUMPING OR SU ITABLE SORBENT.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN RELATIVELY COOL PLACE.STORE
IN CLEARLY MARKED CNTNR.DO NOT EXPOSE TO HEAT OR FLAME.DO NOT STORE
W/OXIDIZERS.USE APPROPRIATE DISPENSING TECHNI
Other Precautions:N/A.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR MISTS AND HIGH VAPOR LEVELS CHEMICAL
CARTRIDGE RESPIRATOR OR AIR SUPPLIED EQUIPMENT.
Ventilation:LOCAL EXHAUST VENTILATION IS REQUIRED. USE MECHANICAL
VENTILATION EQUIPMENT THAT IS EXPLOSION PROOF.
Other Protective Equipment:N/A.
Work Hygienic Practices:WASH HANDS AFTER HANDLING. ANY CONTAMINATED
CLOTHING WASH PRIOR TO REUSE.
Supplemental Safety and Health
BOILING PT RANGE:320-700F.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:320F,160C
Spec Gravity:0.88
Solubility in Water:NEGLIGIBLE.
Appearance and Odor:AMBER TINT LIQUID; AROMATIC.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MFG.
Stability Condition to Avoid:N/A PER MFG. HOWEVER AVOID SOURCES OF
IGNITION.
Hazardous Decomposition Products:NONE SPECIFIED BY MFG.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHERE SOLID ABSORBENTS ARE USED TO CONTROL
SPILLS & USED SORBENT SHOULD BE INCINERATED PER APPLICATION STATE
OR LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BUFFER SOLUTION
CAGE:4R066
CAGE:4R066
============= Composition/Information on Ingredients =============
Ingred Name:AQUEOUS SALT SOLUTION
Fraction by Wt: 100%.
======================= First Aid Measures =======================
First Aid:WASH HANDS AFTER EXPOSURE;EYES:FLUSH WITH WATER,CONSULT A DR.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB ON SUITABLE MATERIAL
======================Handling and Storage ======================
Handling and Storage Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO SPECIAL REQUIREMENTS.
Supplemental Safety and Health
ITEM HAS A PH OF 11.88.
================== Physical/Chemical Properties ==================
HCC:B3
Boiling Pt:B.P. Text:213F.
Vapor Pres:25
Vapor Density:1.5.
Spec Gravity:1.0.
Evaporation Rate & Reference:1.0,WATER.
Solubility in Water:APPRECIABLE
Appearance and Odor:COLORLESS,MOBILE LIQUID.
Percent Volatiles by Volume:86.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL DISPOSAL IS RECOMMENDED
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: SUPER LUBE GREASE
Cage: 4Y181
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 4Y181
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: NO EVIDENCE OF ADVERSE EFFECT FROM AVAILABLE
INFORMATION ON SWALLOWING. SKIN ABSORPTION AND INHALATION: MAY CAUSE SLIGHT
IRRITATION IN CONTACT WITH SKIN AND EYES. SIGNS AND SYMPTOMS OF EXPOSURE :
CONTACT WITH EYES MAY RESULT IN SLIGHT IRRITATION. PROLONGED OR REPEATED SKIN
CONTACT MAY CAUSE MILD IRRITATION.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NOT KNOWN.
First Aid: INGEST: CALL MD IMMEDIATELY (FP N). INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). SKIN: REMOVE BY WIPING AND
WASH WITH SOAP AND WATER. EYES: WASH WITH COPIOUS AMOUNTS OF W ATER FOR AT
LEAST 15 MINUTES.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SPILLS SHOULD BE ABSORBED OR SCRAPED UP.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: USE METHOD OUTLINED IN EPA FEDERAL, STATE AND LOCAL
REGULATIONS. CONTACT YOUR LOCAL EPA OFFICE.
Handling And Storage Precautions: GOOD MANUFACTURING PRACTICES SHOULD BE
FOLLOWED IN HANDLING AND STORAGE.
Other Precautions: SURFACE SUBJECT TO SPILLS WITH THIS PRODUCT CAN BECOME
SLIPPERY.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: COC
Flash Point Text: >428F,>220C
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE KNOWN.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE REQUIRED. NIOSH APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN (FP N).
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NORMAL PRECAUTIONS COMMON TO GOOD MANUFACTURING
PRACTICES SHOULD BE FOLLOWED.
Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR"
VERISON FOR ADDITIONAL INFORMATION (FP N). SPEC GRAV: 0.87 +/0.02 (H*2O=1).
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: SUPDAT
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NOT SOLUBLE
Appearance and Odor: TRANSLUCENT WHITE TO SLIGHTLY YELLOW, SLIGHT ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE KNOWN.
Materials To Avoid: MAY REACT WITH STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: BURNING MAY PRODUCE CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: SUPER LUBE GREASE
Cage: 4Y181
Company Name: SYNCO CHEMICAL CORP
Street: 24 DAVINCI DR
Zipcode: 11716-2601
Label Required IND: Y
Date Of Label Review: 04/24/1998
Status Code: C
Label Date: 04/24/1998
Origination
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: SKIN ABSORPTION AND INHALATION: MAY
CAUSE SLIGHT IRRITATION IN CONTACT WITH SKIN AND EYES. SIGNS AND SYMPTOMS OF
EXPOSURE: CONTACT WITH EYES MAY RESULT IN SLIGHT IRRITATION. PROLON GED OR
REPEATED SKIN CONTACT MAY CAUSE MILD IRRITATION. CHRONIC: NONE LISTED BY
MANUFACTURER.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:AX0684/AX0685, ALUMINUM CHLORIDE, ANHYDROUS
CAGE:EO655
CAGE:63612
CAGE:EO655
============= Composition/Information on Ingredients =============
Ingred Name:ALUMINUM CHLORIDE
CAS:7446-70-0
Fraction by Wt: 100%
OSHA PEL:2 MG/CUM
ACGIH TLV:2 MG/CUM
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 3730 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: SEVERE THERMAL & ACID BURNS.
INHALATION: NASAL & RESPIRATORY PASSAGE BURNS. HARMFUL IF INHALED
OR SWALLOWED.
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:SKIN: FLUSH W/WATER. EYES: FLUSH W/WATER FOR 15 MINS.
INHALATION: REMOVE TO FRESH AIR. IF BREATHING STOPPED, GIVE CPR.
INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point:NON-COMBUSTIBLE
Extinguishing Media:DON'T USE WATER. CO2, DRY CHEMICAL. WEAR SCBA &
FULL PROTECTIVE CLOTHING.
Fire Fighting Procedures:CONTACT W/WATER GENERATES EXCESSIVE HEAT.
Unusual Fire/Explosion Hazard:CONTACT W/WATER MAY CAUSE FIRE OR
EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR SUITABLE PROTECTIVE
EQUIPMENT. ELIMINATE IGNITION SOURCES. CONTAIN MATERIAL IF
POSSIBLE. TAKE UP & CONTAINERIZE.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. VENT
CONTAINERS CAREFULLY BEFORE OPENING. STORE IN COOL, DRY, WELL
VENTILATED AREA.
Other Precautions:DON'T BREATH DUST OR VAPOR. DON'T GET IN EYES OR ON
SKIN OR CLOTHING. RESIDUE IN EMPTY CONTAINERS MAY BE HAZARDOUS.
DON'T HEAT CLOSED CONTAINERS. OPEN CAUTIOUSLY. DON'T TAKE
INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:REQUIRED
Ventilation:USE PRODUCT IN APPROVED FUME HOOD ONLY.
Other Protective Equipment:EYE WASH IN AREA.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
REMOVE & LAUNDER CONTAMINATED CLOTHING BEFORE RE-USE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:356F
Melt/Freeze Pt:M.P/F.P Text:381F
Vapor Density:9.19
Spec Gravity:2.46
Solubility in Water:COMPLETE
Appearance and Odor:YELLOWISH-GRAY TO WHITE GRANULAR POWDER, PUNGENT
HYDROGEN CHLORIDE ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER. CONTACT W/WATER LIBERATES HYDROGEN CHLORIDEGAS.
Stability Condition to Avoid:HEAT & MOISTURE
Hazardous Decomposition Products:HYDROGEN CHLORIDE FUMES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE & FEDERAL
REGULATIONS. UN1726.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ENAMEL ALKYD,SG,GREEN,24533,ID745468
Preparer's Name:W.A. ELLISON
CAGE:61196
CAGE:61196
============= Composition/Information on Ingredients =============
Ingred Name:VM&P NAPHTHA (LIGROINE)
CAS:8032-32-4
RTECS #:OI6180000
OSHA PEL:300 PPM/400 STEL
ACGIH TLV:300 PPM; 9192
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:SILICA, CRYSTALLINE-CRISTOBALITE
CAS:14464-46-1
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.05 MG/M3 RDUST9293
Ingred Name:TALC (CONTAINING NO ASBESTOS)
CAS:14807-96-6
RTECS #:WW2710000
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST; 9192
Ingred Name:MINERAL SPIRITS
(VAPOR PRESSURE 2 MMHG @ 68 F.)
CAS:64742-88-7
RTECS #:PY2400000
OSHA PEL:500 PPM 2950 MG/CU.M
ACGIH TLV:100 PPM 525 MG/CU.M.
Ingred Name:LEAD CHROMATE (OSHA PEL FOR LEAD FROM 29CFR
1910.1025),(CRO3 CEILING 0.1 MG/M3)
CAS:7758-97-6
RTECS #:GB2975000
OSHA PEL:0.05 MG/M3 (PB)
ACGIH TLV:0.05MG/M3(CR)A2;8990
Ingred Name:VOC. ORGANIC CMPD 3.7 LB/GAL LESS WATER & NPRS* 444 G/L
LESS WATER VOC. 8.2 LB/GAL SOLIDS 984 G/L SOLIDS CALCU
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ASPIRATION OF MATERIAL INTO THE LUNGS
CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. REPEATED EXPSR
TO CRYSTALLINE SILICA MAY CAUSE PNEUMOCONIOSIS A DISABLING LUNG
DISEASE. PROLONGED/REPEATED OVR EXPSR MAY CAUSE PERMANENT BRAIN &
NERVSSYS DAMAGE. INTENTIONAL MISUSE CAN BE HARMFUL OR FATAL.
Explanation of Carcinogenicity:AT TLV THE TI02 MANUFACTURER CONCLUDES
THAT THERE IS NO SIGNIFICIANT HAZARD FOR MAN.
Effects of Overexposure:INGST: GASTRONINTESTINAL
IRRITATION,NAUSEA,VOMITING,& DIARRHEA. INHL:
ANESTHETIC,IRRITATION TO NOSE/THROAT, HEADACHES, DIZZINESS, NAUSEA,
& CONFUSION.; SKIN: MAY CAUSE DEFATTING AND I RRITATIONEYE:
IRRITATION
Medical Cond Aggravated by Exposure:REPEATED EXPOSURE MAY CAUSE
PNEUMOCONIOSIS, A PROGRESSIVELY DISABLING LUNG DISEASE.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/LG AMNTS OF WTR, LIFTING EYELIDS, FOR 15
MINS,GET MEDICAL ATTENTIONSKIN: WASH AFFECTED AREA W/SOAP & WTR,
REMOVE CONTAM. CLOTHING.GET MED. ATTN. INHAL: REMOVE TO FRESH AIR
IMMEDIATELY,G IVE ARTIFICIAL RESP. IF NECESSARY, KEEPWARM & QUIET,
GET MEDICAL ATTENTION.
INGST: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>102F/39C
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS,CARBON
DIOXIDE,DRY CHEMICAL,ALCOHOL FOAM. POLYMER FOAM IS PREFERRED FOR
LG. FIRES
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. WATER
MAY BE INEFFECTIVE,MAY BE USED TOCOOL EXPOSED CONTAINERS. IF WATER
IS USED, FOG NOZZLES ARE PREFERRABLE.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT,SPARKS &FLAME. CLOSED CONTAINERS
MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. DIKE/CONTAIN
SPILLW/INERT MATL. PLACE ABSORBENT DIKING MATL IN COVERED METAL
CONTNR FOR DISPOSAL. USE ONLY NON SPARKNGTOOLS. PREVENT CONTAM. OF
SEWERS, GROUNDWATER, AND STREAMS W/SPILLED MATL OR USED ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 95F. CLOSE CONTNR
AFTER EACH USE. EMPTY CONTNRS MUST NOT BE WASHED/REUSED FOR
NEVER USE PRESSURE TO EMPTY.
Other Precautions:DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE
GROUNDED/BONDED TO RECEIVING CONTNRDO NOT WELD,BRAZE OR CUT ON
EMPTY CONTAINERS. DRUM IS NOT A PRESSURE VESSEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESTRICTED AREAS US NIOSH APPROVED CHEMICAL
CARTRIDGE RESPIRATOR. SPRAYING USE AMECHANICAL FILTER RESPIRATOR.
CONFINED AREAS USE A NIOSH APPROVED AIR SUPPLIED RESPIRATOR.
Ventilation:LOCAL EXHAUST VENTILATION OR GENERAL DILUTION
Other Protective Equipment:NONE
Work Hygienic Practices:NONE
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:280-388F
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:55
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS
Stability Condition to Avoid:HEAT AND SOURCES OF IGNITION
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
Conditions to Avoid Polymerization:HEAT SPARKS AND FLAME
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL,STATE,& LOCAL
LAWSINCINERATE ONLY IN EPA PERMITTED FACILITY. DO NOT INCINERATE
CLSD CONTAINERS. CONTAMINATED ABSORBANTMAY BE DISPOSED IN A
HAZARDOUS WASTE LANDFILL.TRAN SFER LIQ TO COVERED METAL CONTAINERS
FOR DISPOSAL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:40:1 POULAN TWO CYCLE ENGINE OIL
CAGE:SPECR
CAGE:SPECR
============= Composition/Information on Ingredients =============
Ingred Name:COMPLEX MIXTURE OF PETROLEUM HYDROCARBON BASE OIL; (COMPLEX
MIXTURE OF PETROLEUM BASE STOCK)
Other REC Limits:5 MG/M3 (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:INHAL OF FUMES MAY RSLT IN
DIZZINESS, HEADACHE & RESPIRTORY IRRITATION. EYE: CONTACT WITH EYES
MAY CAUSE MINIMAL IRRITATION. SKIN: MILD IRRITATION MAY OCCUR WITH
PROLONGED OR REPEATED CONT ACT. INGEST: SLIGHTLY TOXIC. PULMONARY
ASPIRATION HAZARD IF VOMITING OCCURS. CHRONIC: PRODUCT HAS LOW
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: ORDER OF ACUTE ORAL TOXICITY.
INGREDIENTS OF THIS PRODUCT ARE NOT LISTED AS POTENTIAL CARCINOGENS
IN NTP ANNUAL REPORT ON CARCINOGENS, IARC. MONOGRAMS, OR BY OSHA
HAZARD COMMUNICATION STANDA RD (G) (2) (VII).
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: WASH SKIN WITH SOAP AND WARM WATER. WASH CLOTHING
BEFORE RE-USE. EYES: IF SPLASHED INTO EYES FLUSH EYES WITH CLEAR
WATER FOR AT LEAST 15 MIN. INHAL: IF OVERCOME BY FUMES REMOVE FROM
EXPOSURE IMM EDIATELY. INGEST: IF INGESTED, DO NOT INDUCE VOMITING.
CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:210F,99C
Extinguishing Media:WATER FOG, CHEMICAL FOAM, DRY CHEMICAL POWDER,
CO*2.
Fire Fighting Procedures:COOL EXPOSED CONTAINERS WITH WATER SPRAY.
AVOID BREATHING FUMES.
Unusual Fire/Explosion Hazard:PRESSURE INCREASE IN OVER HEATED CLOSED
CONTAINERS. COOL CONTAINERS WITH WATER SPRAY.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE IGNITION SOURCES. RECOVER LIQUID. ADD
ABSORBENT TO SPILL AREA. VENTILATE CONFINED SPACES. ADVISE
AUTHORITIES IF PRODUCT ENTERS SEWERS, ETC.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. DO NOT HANDLE OR STORE NEAR HEAT OR FLAMES. USE CHEMICAL
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:VENTILATE AS NEEDED TO COMPLY WITH EXPOSURE LIMIT.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:IF CLTHG BECOMES CONTAMINATED, CHANGE TO FRESH
CLEAN CLOTHING. DO NOT WEAR UNTIL THOROUGHLY WASHED.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Vapor Pres:1
Vapor Density:1
Spec Gravity:0.8838-0.8767
Evaporation Rate & Reference:1 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK BLUE COLORED LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDANTS
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PARTIAL BURNING PRODUCES FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:ASSURE CONFORMITY WITH APPLICABLE DISPOSAL
REGULATIONS. DISPOSE OF ABSORBED MATERIAL AT APPROVED WASTE SITE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ACETONE
Resp. Party Other MSDS Num.:MSDS 053
CAGE:69267
Contract Num:SP0 450-99-M-C047
CAGE:69267
CAGE:8V248
============= Composition/Information on Ingredients =============
Ingred Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
= Wt:100.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:750PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, CNS,
RESPIRATORYAND GASTROINTESTINAL TRACTS. ACUTE- EYES: MAY CAUSE
IRRITATION, TEARING AND STINGING. SKIN: MAY CAUSE DRYNESS WITH
PROLONGED/REPEATED CONTACT. INHALE: HIGH V APOR CONCENTRATIONS MAY
CAUSE RESPIRATORY IRRITATION AND CNS EFFECTS. SWALLOWING: MAY CAUSE
GASTROINTESTINAL TRACT IRRITATION, HEADACHE, NAUSEA, VOMITING,
DIZZINESS OR DROWSINESS. ASPIRATION HAZARD. C HRONIC- MAY CAUSE
DRYNESS OF SKIN.
Explanation of Carcinogenicity:ACETONE IS NOT LISTED AS A CARCINOGEN OR
SUSPECTED CARCINOGEN BY NTP, IARC, OR REGULATED BY OSHA.
Effects of Overexposure:DEFATTING AND DRYING OF THE SKIN, IRRITATION,
HEADACHE, NAUSEA, VOMITING, DIZZINESS, TEARING
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN
EXISTING DERMATITIS.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALATION: REMOVE TO
FRESH AIR. GIVE ARTIFICAL RESPIRATION IF NOT BREATHING. IF
BREATHING IS DIFFICULT, OXYGEN MAY BE GIVEN BY QUALIFIED PERSONNEL.
EYES CONTACT: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15
MINUTES. HOLD EYELIDS OPEN. DO NOT REMOVE CONTACT LENSES, IF WORN.
SKIN: WASH WITH SOAP & WATER FOR AT LEAST 15 MINUTES. SWALLOWING:
DO NOT INDUCE VOMITIN G. IF PATIENT IS FULLY CONSCIOUS, GIVE TWO
GLASSES OF WATER. SEEK MEDICAL ATTENTION. IF VOMITING OCCURS, KEEP
HEAD BELOW HIPS. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=-17.8C, 0.F
Lower Limits:2.15%
Upper Limits:13.0%
Extinguishing Media:SMALL FIRE: USE DRY CHEMICALS, CARBON DIOXIDE.
LARGE FIRE: USE ALCOHOL-TYPE OR ALL-PURPOSE FOAM.
Fire Fighting Procedures:VERY FALMMABLE, CLEAR FIRE AREA OF UNPROTECTED
PERSONNEL AND ISOLATE. DO NOT ENTER CONFINED FIRE SPACE WITHOUT
FULL BUNKER GEAR. USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS
AND STRUCTURES. USE WAT ER SPRAY TO DISPERSE VAPORS - RE-IGNITION
IS POSSIBLE. USE SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP. VAPORS MAY
SETTLE IN LOW OR CONFINED SPACES . STATIC IGNITION HAZARD CAN
RESULT FROM HANDLING AND USE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. DO NOT WALK THROUGH SPILL; STOP SPILL
IF POSSIBLE. USE A VAPOR SUPPRESSING FOAM TO REDUCE VAPORS. CONTAIN
AND PICK UP WITH NON -FLAMMABLE ABSORBENT SUCH AS SAND,
VERMICULITE. GROUND ALL HANDLING EQUIPMENTS. PREVENT LIQUID FROM
ENTERING SEWERS, WATERWAYS, CONFINED SPACES. SMALL SPILL CAN BE
FLUSHED WITH LARGE AMOUNT OF WATER.
Neutralizing Agent:DILUTE WITH WATER
======================Handling and Storage ======================
Handling and Storage Precautions:FLAMMABLE MATERIAL. STORE IN A COOL,
VENTILATED PLACE. GROUND CONTAINERS WHEN TRANSFERRING PRODUCT. USE
NON-SPARKING TOOLS. KEEP AWAY FROM SPARKS, FLAMES AND HEAT.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATHE VAPORS. AVOID
CONTACT WITH EYES. USE WITH ADEQUATE VENTILATION. CONTAINERS, EVEN
THOSE THAT HAVE BEEN EMPTIED, CAN CONTAIN EXPLOSIVE VAPORS. DO NOT
CUT, DRILL WE LD NEAR CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF TLV IS EXCEEDED OR
FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR
RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A
NIOSH-APPROVED POSITIVE-PRES SURE SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
AND UNIFORM
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
DO NOT WEAR CONTACT LENSES. NOTE FOR DOCTORS: ASPIRATION OF PRODUCT
DURING INDUCE EMESIS CAN RESULT IN LUNG INJURY. IF EVACUATION OF
STOMACH CONTENTS IS CONSIDERED NECESSARY, USE METHOD LEAST LIKELY T
O CAUSE ASPIRATION, SUCH AS GASTRIC LAVAGE AFTER ENDOTRACHEAL
INTUBATION.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:=56.3C, 133.3F
Melt/Freeze Pt:=-96.5C, -141.7F
Vapor Pres:184 MM/HG @20C
Vapor Density:2.0 (AIR=1
Spec Gravity:0.792@ 20/20C
VOC Pounds/Gallon:790
Evaporation Rate & Reference:14.4(BUTYL ACETATE=1)
Solubility in Water:100%@20C
Appearance and Odor:CLEAR COLORLESS LIQUID,CHARACTERISTIC: ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:CARBON MONOXIDE AND UNIDENTIFIED
ORGANIC COMPOUNDS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF SPILL-CLEAN UP AND OTHER WASTES IN
ACCORDANCE WITH LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS.
VAPORS MAY COLLECT IN EMPTY CONTAINERS. TREAT EMPTY CONTAINERS AS
HAZARDOUS.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:2.2'-DIFLUOROBIPHENYL, F400
Resp. Party Other MSDS Num.:CAT#: F400
CAGE:8Y898
CAGE:8Y898
CAGE:SO010
============= Composition/Information on Ingredients =============
Ingred Name:2.2'-DIFLUOROBIPHENYL
CAS:388-82-9
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTACT LENSES SHOULD NOT BE WORN IN
THE LABORATORY. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS -
AVOID DIRECT PHYSICAL CONTACT! OVERALL CHEMICAL, PHYSICAL AND TOXIC
DATA HAS NOT BEEN THOROUGHLY INV ESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:AN ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF
POISON. IT SHOULD BE ADMIN ONLY BY PHYSICIAN OR TRAINED EMER PERS.
MED ADVICE CAN BE OBTAINED FROM POIS CTL CTR. EYES: IN CASE OF
CNTCT, FLUSH EY ES CONTINUOUSLY W/WATER FOR AT LEAST 15 MIN. SKIN:
IN CASE OF CNTCT, FLUSH SKIN W/WATER FOR 15-20 MIN. IF NO BURNS
HAVE OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL: REMOVE
PATIENT TO FRESH AIR. A DMIN OXYG IF PATIENT IS HAVING DFCLTY
BRTHG. IF PATIENT HAS STOPPED BRTHG ADMIN ARTF RESP. IF PATIENT IS
IN CARD ARREST ADMIN CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL
MED ASSISTANCE HAS ARRIVED. R EMOVE & WASH (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:DATA NOT AVAIL
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR SPRAY.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NO EXPLOSION LIMITS ARE AVAILABLE FOR
THIS COMPOUND.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA REGULATED
EQUIPMENT. VENTILATE AREA. SWEEP UP AND PLACE IN AN APPROPRIATE
CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE
ANY RESIDUES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. STORE ONLY
WITH COMPATIBLE CHEMICALS.
Other Precautions:AVOID CONTACT WITH SKIN, EYES AND CLOTHING. DO NOT
BREATHE VAPORS. KEEP TIGHTLY CLOSED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . USE APPROPRIATE OSHA/MSHA APPROVED SAFETY
EQUIPMENT.
Supplemental Safety and Health
FIRST AID PROC: CONTAM CLTHG. IF PATIENT IS EXHIBITING SIGNS OF SHOCK -
KEEP WARM & QUIET. INGEST: CNTCT POIS CTL CTR IMMED IF NEC. DO NOT
ADMIN LIQS OR INDUCE VOMIT TO UNCON OR CONVULSING PERSON. IF
PATIENT IS VOMIT-WATCH CLOSELY TO MAKE SURE AIRWAY DOES NOT BECOME
OBSTRUCTED BY VOMIT. GET MED ATTN IF NECESSARY.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:>118.5C, 245.3F
M.P/F.P Text:118.5-119.5C
Vapor Pres:NOT AVAILABLE
Vapor Density:NOT AVAIL
Spec Gravity:1.393
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:NOT AVAILABLE
Appearance and Odor:WHITE CRYSTALLLINE SOLID; ODOR, NOT AVAILABLE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS WITH ACID HALIDES AND ANHYDRIDES.
=================== Toxicological Information===================
Toxicological Information:NO TOXICITY DATA HAS BEEN FOUND. ASSUME THIS
CHEMICAL TO BE HAZARDOUS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . BURN IN A CHEMICALS INCINERATOR
EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
=================== MSDS Transport Information ===================
Transport Information:DOT (DEPARTMENT OF TRANSPORTATION - PROPER
SHIPPING NAME: PAINT. HAZARD CLASS: COMBUSTIBLE (NOT SUBJECT TO CFR
49, REF 173.150(F), NMFC 149980). UN NUMBER: NOT REGULATED. PACKING
GROUP: NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III (SUPERFUND AMENDMENTS AND
REAUTHORIZATION ACT): NONE KNOWN.
Federal Regulatory Information:TSCA (TOXIC SUBSTANCE CONTROL ACT):
COMPONENTS OF THIS PRODUCT ARE LISTED ON THE TSCA INVENTORY. CERCLA
(COMPREHENSIVE RESPONSE COMPENSATION AND LIABILITY ACT): WE
RECOMMEND YOU CONTACT LOCAL AUTHORIT IES TO DETERMINE IF THERE MAY
BE OTHER LOCAL REPORTING REQUIREMENTS. WHMIS CLASSIFICATION: CLASS
P, DIVISION 3.
State Regulatory Information:CALIFORNIA PROPOSITION 65: WARNING: THIS
PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:5R90094, 1065/4235/5016/5018/5021/5026/5028/ (SUPDAT)
CAGE:0E6G9
CAGE:0E6G9
CAGE:26921
============= Composition/Information on Ingredients =============
Ingred Name:IRON; (STEEL POWDER)
CAS:7439-89-6
RTECS #:NO4565500
Fraction by Wt: >94%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BUTADIENE-STYRENE POLYMER (RUBBER); (STYRENE/BUTADIENE
COPOLYMER)
CAS:9003-55-8
RTECS #:WL6478000
Fraction by Wt: <3.75-4%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:IRON (III) OXIDE; (IRON OXIDE)
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: <0.75-1%
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3 FUME (FE)
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) >10 G/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MINIMAL RESPIRATORY TRACT IRRITATION
MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY NON-TOXIC DUST.
THE RESULTS FROM A XEROX SPONSORED CHRONIC TONER INHAL STUDY,
DEMONSTRATED NO LUNG CHANGE IN RAT S FOR LOWEST (1 MG/M3) EXPOSURE
LEVEL (I.E. LEVEL MOST RELEVANT TO POTENTIAL HUMAN EXPOSURE). A
VERY SLIGHT DEGREE OF FIBROSIS WAS NOTED IN 25% OF ANIMALS AT
MIDDLE (4 MG/M3) EXPOSURE LEVEL, WHILE SLI GHT DEGREE OF FIBROSIS
WAS NOTED IN ALL ANIMALS AT HIGHEST (16 MG/M3) EXPOSURE LEVEL.
THESE FINDINGS ARE ATTRIBUTED TO "LUNG OVERLOADING", A GENERIC
RESPONSE TO EXCESSIVE AMOUNTS OF ANY DUST RETAINEDIN LUNGS FOR
PROLONGED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HEALTH HAZARDS: PERIOD. THIS STUDY WAS
CONDUCTED USING A SPECIAL TEST TONER TO COMPLY WITH EPA TESTING
PROTOCOL. THE TEST TONER WAS TEN TIMES MORE RESPIRABLE THAN
COMMERCIALLY AVAILABLE XEROX TONER AN D WOULD NOT BE FUNCTIONALLY
SUITABLE FOR XEROX EQUIPMENT.
Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY
PRODUCT LITERATURE.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. SKIN:WASH W/SOAP
& WATER. INHAL:REMOVE FROM EXPOSURE. INGEST:DILUTE STOMACH CONTENTS
W/SEVERAL GLASSES OF WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . AVOID INHALATION OF SMOKE.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:IF SPILLED, SWEEP UP OR VACUUM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE.
Other Precautions:AVOID PROLONGED INHALATION OF EXCESSIVE DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX
PRODUCTS. FOR USE OTHER THAN NORMAL CUSTOMER-OPERATING PROCEDURES
(SUCH AS IN BULK TONER PROCESSING FACILITIES), NIOSH APPROVED
RESPIRATORS MAY BE REQUIRED . FOR MORE INFORMATION, CONTACT XEROX.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART
NO:5034/5046/5047/5065/5321/5328/5334/5335/5365/5624/
5626/5818/5820/ XC-1875/XC-2675/CLASS IV DEVELOPER.
================== Physical/Chemical Properties ==================
Spec Gravity:5 (H*2O=1)
Appearance and Odor:BLACK GRANUAR; FAINT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC.
AVOID BREATHING SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE & LOCAL REGULATIONS . WHEN DISPOSED, THIS MATERIAL IS NOT
HAZARDOUS WASTE ACCORDING TO FEDERAL REGULATION 40 CFR 261.
HOWEVER, STATE & LOCAL RE QUIREMENTS MAY BE MORE RESTRICTIVE.
THEREFORE, CONSULTATION WITH APPROPRIATE STATE & LOCAL WASTE DIS
POSAL AUTHORITIES IS ADVISED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BUFFER P1, ENDOFREE PLASMID MEGA KIT, 12381
CAGE:01QTQ
CAGE:01QTQ
============= Composition/Information on Ingredients =============
Ingred Name:TRIS(HYDROXYMETHYL)-AMINOMETHANE. %:AQUEOUS SOLUTION OF 50
MM TRIS(HYDROXYMETHYL)-AMINOMETHANE AND HYDROCHLORIC ACID.
Fraction by Wt: <50% MM
Ingred Name:HYDROCHLORIC ACID. %:AQUEOUS SOLUTION OF 50 MM
TRIS(HYDROXYMETHYL)-AMINOMETHANE AND HYDROCHLORIC ACID.
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: <50% MM
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHYLENEDIAMINETETRAACETIC ACID. %: 10 MM. PH: 8.0 @ 20C.
CAS:60-00-4
RTECS #:AH4025000
Fraction by Wt: 10% MM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY BE HARMFUL BY
INHALATION. EYE/SKIN CONTACT: MAY CAUSE IRRITATION. INGESTION: MAY
BE HARMFUL IF SWALLOWED. CHRONIC: NOT APPLICABLE.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING EYELIDS
WITH FINGERS. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOUNTS
OF WATE R. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION:
WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
CONTAINERS FOR DISPOSAL. VENTIL ATE AREA AND WASH SPILL SITE AFTER
MATERIAL PICKUP IS COMPLETE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. STORE AT 4C
AFTER DISSOLVING RNASE. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
Other Precautions:THE PRODUCT SHOULD BE HANDLED WITH THE NORMAL CAUTION
ACCORDED CHEMICALS. ADDITIONAL HARMFUL PROPERTIES CANNOT BE RULED
OUT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . LAB
COAT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:0.990 G/CM3 @ 20C
pH:SEE INGREDIENTS
Solubility in Water:SOLUBLE @ 20C
Appearance and Odor:COLORLESS LIQUID; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE AND
CARBON DIOXIDE.
=================== Toxicological Information===================
Toxicological Information:NOT APPLICABLE.
===================== Ecological Information =====================
Ecological:NOT APPLICABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:FOR SMALL QUANTITIES FLUSH DOWN SINK WITH WATER.
OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS.
=================== MSDS Transport Information ===================
Transport Information:NOT APPLICABLE.
===================== Regulatory Information =====================
SARA Title III Information:NOT APPLICABLE.
Federal Regulatory Information:NOT APPLICABLE.
State Regulatory Information:NOT APPLICABLE.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:O-TOLIDINE TEST TABLETS
Kit Part:Y
CAGE:LO054
CAGE:0AX00
CAGE:LO054
============= Composition/Information on Ingredients =============
Ingred Name:ORTHO TOLIDINE DIHYDROCHLORIDE ,CAS#612-82-8
Fraction by Wt: 0.4%
ACGIH TLV:NOT SPECIFIED
Ingred Name:POTASSIUM BISULFATE ,CAS#7646-93-7
CAS:7646-93-7
RTECS #:TS7200000
Fraction by Wt: 29.0%
===================== Hazards Identification =====================
Effects of Overexposure:IRRITANT TO EYES,SKIN AND INTESTINAL
TRACT;TOXIC IF INHALE,ABSORBED THRU SKIN OR INGEST;O-TOL SEES.D
======================= First Aid Measures =======================
First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF
NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH;
GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER
SYMPTOMS OF OVEREXPOSURE.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL,FOAM
Fire Fighting Procedures:DO NOT USE WATER.WEAR NIOSH/MSHA APPROVED SCBA
Unusual Fire/Explosion Hazard:MAY PRODUCE TOXIC FUMES IN FIRE,CONTACT
WITH WATEROR ALCOHOLS WILL PRODUCE HEAT AND STEAM.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTION:COLLECT ON
ABSORBENT INERT MATERIAL AND RECOVER FOR PROPER DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL DRY PLACE.KEEP CONTAINER
CLOSED WHEN NOT IN USE.
Other Precautions:AVOID CONTACT WITH SKIN AND EYES,DO NOT TAKE
INTERNALLY:WASH HANDS AFTER HANDLING.WASH WITH SOAP AND WATER AFTER
EACH USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY
CONDITIONS/ADEQUATE VENT.
Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE
VENTILATION
Other Protective Equipment:AS REQUIRED TO PREVENT PROLONGED CONTACT.
Supplemental Safety and Health
MSDS DATED:4/15/87;ORTHOTOLIDNE IS A SUSPECTED CARCINOGEN. KEY1:N1.
================== Physical/Chemical Properties ==================
HCC:T6
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE TO TAN TABLETS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIS,WATER,AL,MG,ALCOHOL
Stability Condition to Avoid:USE TEST METHOD ACCORDING TO THE
INSTRUCTIONS.
Hazardous Decomposition Products:TOXIC FUMES WHEN STRONGLY HEATED
(.180F)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF COLLECTED MATERIAL IN ACCORDANCE WITH
LOCAL STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SCOTCH-WELD EC-3537-NA BASE ADHESIVE SEALANT
Kit Part:Y
CAGE:0KHE3
CAGE:0KHE3
============= Composition/Information on Ingredients =============
Ingred Name:BISPHENOL A DIGLYCIDYL ETHER RESIN, EPOXY RESIN, EPON 820,
ARALDITE 6004, 4,4'-ISOPROPYLIDENEDIPHENOL-EPICHLOROHYDRIN
CAS:25068-38-6
RTECS #:KD4380000
Fraction by Wt: 65-75%
Ingred Name:CLAY (KAOLIN), ALUMINUM SILICATE
CAS:1332-58-7
RTECS #:GF1670500
Fraction by Wt: 25-35%
ACGIH TLV:10 MG/CUM TOTAL DUST
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION UPON DIRECT CONTACT.
SKIN: IRRITATION UPON PROLONGED CONTACT. ALLERGIC SKIN REACTION IN
CERTAIN INDIVIDUALS. INHALATION: VAPORS MAY BE IRRITATING TO
RESPIRATORY SYSTEM. INGESTION: DIG ESTIVE SYSTEM IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR 10 MINS. SKIN: THOROUGHLY
WASH W/SOAP & WATER. INHALATION: REMOVE TO UNCONTAMINATED AIR.
INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point:>200F
Extinguishing Media:CO2, FOAM, DRY CHEMICAL, WATER
Fire Fighting Procedures:USE SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. COLLECT MATERIAL, CLEANUP
RESIDUE USING ABSORBENT MATERIALS AS NEEDED. PLACE IN A U.S.
APPROVED METAL CONTAINER & SEAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
KEEP OUT OF REACH OF CHILDREN. FOR INDUSTRIAL & PROFESSIONAL USE
ONLY.
Other Precautions:USE ONLY W/SUFFICIENT VENTILATION TO MAINTAIN VAPOR
CONCENTRATIONS BELOW EXPOSURE LIMITS. AVOID EYE/SKIN CONTACT &
BREATHING DUST FROM CUTTING/GRINDING/SNADING OPERATIONS. FOR
INDUSTRIAL & PROFESSIONA L USE ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DUST MASK TO AVOID DUST EXPOSURE.
Ventilation:REQUIRED TO MAINTAIN VAPOR CONCENTRATIONS BELOW RECOMMENDED
EXPOSURE LIMITS.
Other Protective Equipment:PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:1.36
Solubility in Water:INSOLUBLE
Appearance and Odor:CREAM PASTE, OFF WHITE W/SLIGHT ODOR.
Percent Volatiles by Volume:0/WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:CO, CO2, NITROGEN & SMOKE
==================== Disposal Considerations ====================
Waste Disposal Methods:MAJOR SPILLS: DISPOSE OF CLEANUP MATERIAL BY
INCINERATION IN AN INDUSTRIAL/COMMERCIAL INCINERATORY. FULLY CURED
RESIDUAL MATERIAL & EMPTY CONTAINERS MAY BE DISPOSED IN A SANITARY
LANDFILL IN ACCORDANC E W/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:VULKEM 922 PART B, 60613000
Kit Part:Y
CAGE:94836
CAGE:94836
============= Composition/Information on Ingredients =============
Ingred Name:ALIPHATIC AMINES
Fraction by Wt: 25%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CORROSIVE LIQUID CAUSES BURNS & SEVERE
EYE DAMAGE. MAY CAUSE SKIN SENSITIZATION. MAY BE EMBRYOTOXIC.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:THOROUGHLY WASH EXPOSED AREA W/SOAP & WATER. EYES:FLUSH
W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL
ATTENTION. INGEST:DO NOT INDUCE VOMITING; GET MEDICAL ATTENTION.
INHAL:REMOVE TO FRESH AIR. IF NECESSARY, ADMINISTEROXYGEN &/OR
ARTIFICIAL RESPIRATION. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>200F,>93C
Extinguishing Media:WATERSPRAY, WATERFOG, DRY CHEMICAL, CO2, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CORROSIVE LIQUID. EXPOSURE TO HEAT MAY
CAUSE PRESSURE TO INCREASE IN CLOSED CONTAINERS. COOL W/WATER
SPRAY.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB INTO VERMICULITE OR OTHER ABSORBENT
MATERIAL & DISPOSE. CLEAN AFFECTED AREA W/LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE IN DIRECT SUNLIGHT. FOR
SAFETY, STORE AWAY FROM SPARKS OR FLAME. FOR MAXIMUM STORAGE LIFE
STORE AT <90F.
Other Precautions:MAINTAIN ADEQUATE VENTILATION. MAY BE EMBRYOTOXIC.
FERTILE WOMEN SHOULD AVOID ALL DIRECT CONTACT W/LIQUID. DO NOT
BREATHE VAPORS. AVOID SKIN & EYE CONTACT. DO NOT TAKE INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE W/ADEQUATE VENTILATION. NIOSH/MSHA APPROVED
RESPIRATORS W/ORGANIC VAPOR CARTRIDGES OR SELF CONTAINED BREATHING
APPARATUS MAY BE USED IN CONFINED AREAS.
Ventilation:LOCAL EXHAUST OR GENERAL MECHANICAL SUFFICIENT TO PREVENT
ACCUMULATION OF FUMES & VAPORS.
Other Protective Equipment:PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT.
EMERGENCY EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
KEY1;C2.
================== Physical/Chemical Properties ==================
HCC:C2
Boiling Pt:B.P. Text:>200F,>93C
Vapor Density:HVR/AIR
Spec Gravity:1.68-1.8
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:55(WT)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:DO NOT STORE IN DIRECT SUNLIGHT. STORE
AWAY FROM SPARKS OR FLAME.
Hazardous Decomposition Products:NITROGEN OXIDES, CARBON MONOXIDE,
CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR LANDFILL I/A/W LOCAL, STATE &
FEDERAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: TRAFFIC PAINT-LCF YELLOW, 7312
Cage: OK2R1
=======================================================
Contractor Summary
=======================================================
Cage: 0K2R1
Cage: OK2R1
=======================================================
Ingredients
=======================================================
Cas: 64742-88-7
% Wt: 10
OSHA PEL: 525 MG/M3 (MFR)
ACGIH TLV: 525 MG/M3 (MFR)
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
% Wt: 3
OSHA PEL: 200 PPM; Z-2
ACGIH TLV: 50 PPM, S
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 64742-89-8
% Wt: 15
OSHA PEL: N/K (FP N)
ACGIH TLV: 1600 MG/M3 (MFR)
------------------------------
RTECS #: 9999999VO
-----------------------------
CONCERNING LATEST HAZARD LIST INFO & SAFE
-----------------------------
-----------------------------
READ AND UNDERSTOOD!!!
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHAL:HIGH VAP CONCS (>1000 PPM) ARE IRRIT TO RESP
TRACT, MAY CAUSE HDCHS & DIZZ, ARE ANESTH & MAY HAVE OTHER NERVOUS
SYS EFTS. SKIN/EYE: HIGH VAP CONCS(>1000 PPM) ARE IRRIT TO EYES & HAVE
SAME EFT AS ABOVE. SKIN(ABSORP): PRLNGD/RPTD CONT TENDS TO REMOVE SKIN OILS
LEADING TO IRRIT &/DERM: HOWEVER IT IS(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:JUDGED NEITHER "CORROSIVE" NOR
"IRRIT" BY OSHA CRITERIA. INGEST: LOW ORDER OF ACUTE ORAL & DERMAL TOX,
BUT MINUTE AMTS ASPIR INTO LUNGS DURING INGEST MAY CAUSE MILD TO SEV PULM
INJURY & POSS DEATH. MAY CAUSE BRTHG DFCLTY, DIZZ, HDCHS & LOSS OF
COORD. EYE CONT MAY CAUSE SEV IRRIT, TEARING, REDNESS(SUPDAT)
Medical Cond Aggravated By Exposure: ANESTHESIA, RESPIRATORY TRACT IRRITATION,
DERMATITIS, NAUSEA, VOMITING.
First Aid: INHAL: REMOVE FROM EXPOS IMMED. CALL MD. IF BRTHG IS IRREG/STOPPED,
START RESUSCITATION, ADMIN O*2. INGEST: DO NOT INDUCE VOMITING. CALL MD.
EYES: FLUSH W/WATER FOR AT LEAST 15 MINS/UNTIL IRRIT SUBSI DES; CALL MD.
SKIN: REMOVE CONTAMD CLTHG, WASH SKIN W/SOAP & WATER.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE ALL IGNIT SOURCES. KEEP PEOPLE AWAY. RECOVER
FREE LIQ. ADD ABSORB(SAND,ETC.) TO SPILL AREA. AVOID BRTHG VAPS. VENT
CONFINED AREA. KEEP OUT OF SEWERS & WATERCOURSES BY DIKING &
IMPOUNDING.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: ASSURE CONFORMITY WITH LOCAL, STATE & FEDERAL
REGULATIONS FOR BOTH SPILLED PRODUCT AND ABSORBED MATERIALS.
Handling And Storage Precautions: KEEP CNTNRS UPRIGHT & CLSD WHEN NOT IN
USE. DO NOT HNDL/STORE NEAR HEAT, SPARKS, FLAME/STRONG OXIDANTS. ADEQ VENT
REQD. NO SMOKING/OPEN LIGHTS.
Other Precautions: AVOID BRTHG VAPS & SKIN CONT. REMOVE CONTAMD CLTHG &
LAUNDER BEFORE REUSE. AVOID BRTHG SANDING DUST. PVNT PRLNGD BRTHG OF
VAP/SPRAY MIST. "EMPTY" CNTNRS MAY BE HAZ FROM RESIDUES OF PROD & VAP
& ALL CA UTIONS APPLY. GROUND CNTNRS WHEN
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 20.0F,-6.7C
Lower Limits: 1.0%
Upper Limits: 7.1%
Extinguishing Media: FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP
N). FULL STREAM WATER MAY BE UNSUITABLE AS EXTING METH, BUT IS HELPFUL IN
KEEPING NEARBY CNTNRS COOL.(SUPDAT)
Unusual Fire/Explosion Hazard: DO NOT APPLY TO HOT SURFS. KEEP AWAY FROM
HEAT/OPEN FLAME. KEEP CNTNRS TIGHTLY CLSD. CLSD CNTNRS MAY EXPLODE WHEN EXPOS
TO EXTREME HEAT. DO NOT STORE/(SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA ORG VAP CANISTER/SUPPLIED-AIR RESP PROT
WHEN TLV IS EXCEEDED OR NIOSH/MSHA APPRVD CHEMICAL/MECH FILTER TO REMOVE
COMBINATION OF SOLID AIRBORNE PARTICLES & VAPOR OF OVERSPRAY DURING SPRA
Y APPLICATION.
Ventilation: PROVIDE SUFF VENT, BOTH IN VOL & PATTERN, W/EXPLOS-PROOF EQUIP
TO MAINTAIN EXPOS LEVELS BELOW TLV.
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER(FP N).
SOLVENT-RESIST APRON/OTHER CLTHG, IF NEEDED, TO AVOID RPTD/PRLNGD CONT.
Work Hygienic Practices: WASH HANDS THOROUGHLY BEFORE EATING/SMOKING.
Supplemental Safety and Health: FIRE FIGHT PROC: AVOID SPREADING BURNING LIQ
W/WATER USED FOR COOLING. EXPLO HAZ: MIX W/STRONG OXIDANTS. EFTS OF OVEREXP:
& BLURRED VISION. MAY CAUSE DRY & DEFAT SKIN CAUSING CRACKS, IRRIT
& DERM. CAN CAUSE GI IRRIT, VOMIT, NAUS & DIARR. NOTE: TOLUENE
APPEARS ON THE NAVY LISTING OF OCCUP CHEMICAL REPRO HAZS.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >201F,>94C
Vapor Pres: SEE INGS
Vapor Density: HVR/AIR
Spec Gravity: 1.4(H*2O=1)
Evaporation Rate & Reference: SLOWER THAN ETHER
Solubility in Water: NON-SOLUBLE
Appearance and Odor: LIQUID W/MILD ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPS &/DIRECT HEATING.
Materials To Avoid: STRONG OXIDANTS. WILL DISSOLVE SOME PLASTICS.
Hazardous Decomposition Products: SMOKE, ACRID FUMES, CARBON MONOXIDE, CARBON
DIOXIDE, VARIOUS HYDROCARBONS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: TRAFFIC PAINT-LCF YELLOW, 7312
Cage: OK2R1
Assigned IND: Y
Company Name: DANIEL BOONE PAINTS INC
Street: 15701 NELSEN PL S
Zipcode: 98188
Label Required IND: Y
Date Of Label Review: 08/22/1995
Status Code: C
Label Date: 08/22/1995
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: INHALATION: HIGH VAPOR CONCENTRATIONS
(>1000 PPM) ARE IRRITATING TO RESPIRATORY TRACT, MAY CAUSE HEADACHES AND
DIZZINESS, ARE ANESTHETIC AND MAY HAVE OTHER NERVOUS SYSTEM EFFECTS. SK
IN/EYE: HIGH VAPOR CONCENTRATIONS(>1000PPM) ARE IRRITATING TO EYES AND
HAVE SAME EFFECT AS ABOVE. SKIN(ABSORP): PROLONGED OR REPEATED CONTACT TENDS
TO REMOVE SKIN OILS LEADING TO IRRITATION AND OR DER MATITIS. INGESTION: LOW
ORDER OF TOXICITY, BUT AMOUNTS ASPIRATED INTO LUNGS MAY CAUSE MILD TO SEVERE
PULMONARY INJURY AND POSSIBLY DEATH. CHRONIC: TOLUENE APPEARS ON THE NAVY
OCCUPATIONAL CHEMICAL REP RODUCTIVE HAZARDS LIST(FP N).
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:KIT PASTE CAR WAX, 602662
CAGE:6N804
CAGE:6N804
============= Composition/Information on Ingredients =============
Ingred Name:AMMONIA (SARA III)
CAS:7664-41-7
RTECS #:BO0875000
Fraction by Wt: <0.1%
Other REC Limits:PEL: 50 PPM (MFR)
OSHA PEL:50 PPM
ACGIH TLV:25 PPM/35 STEL; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:FORMALDEHYDE (SARA III)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: <0.3%
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS)
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 20-35%
Other REC Limits:IDLH 5000 PPM (MFR)
OSHA PEL:500 PPM
ACGIH TLV:100 PPM; 9293
Ingred Name:MORPHOLINE; (DIETHYLENIMIDE OXIDE)
CAS:110-91-8
RTECS #:QD6475000
Fraction by Wt: <0.5%
Other REC Limits:IDLH: 8000 PPM (MFR)
OSHA PEL:20PPM;30PPM STEL,S
ACGIH TLV:20PPM, S
Ingred Name:POLISHING AGENTS; (POLISHING COMPOUND)
Fraction by Wt: <15%
OSHA PEL:10 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: INGEST: MAY BE HARMFUL IF
SWALLOWED. ASPIRATION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL
PNEUMONITIS. EYES: PRODUCT CAN CAUSE IRRITATION. INHAL: MAY CAUSE
BREATHING DIFFICULTY. OVEREXPOSURE OF VAPORS MAY PRODUCE HEADACHE
& DIZZINESS. CHRONIC: NO KNOWN EFFECTS.
Explanation of Carcinogenicity:FORMALDEHYDE: IARC GRP 2A, NTP GRP 2,
OSHA REGULATED.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NOT DETERMINED.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR A MINIMUM OF 15 MINUTES. GET MEDICAL
ATTENTION. SKIN: WASH W/SOAP & WATER. INGEST: DO NOT INDUCE
VOMITING. CONTACT MD &/OR LOCAL POISON CONTROL CENTER. VOMITING MAY
CAUSE ASPIR ATION WHICH CAN RESULT IN CHEMICAL PNEUMONITIS. INHAL:
REMOVE TO FRESH AIR. IF BREATHING DIFFICULTY PERSISTS, GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:116F,47C
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURE
SCBA & FULL PROTECTIVE EQUIPMENT . COOL FIRE EXPOSED CONTAINERS,
SURROUNDING EQUIP AND STRUCTURES W/WATER.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SPILLED MATERIAL IS SLIPPERY. WASH SKIN
THOROUGHLY WITH WATER AFTER HANDLING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID OVERHEATING OR FREEZING.
Other Precautions:DO NOT GET PRODUCT INTO EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WITH NORMAL USE.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH SKIN THOROUGHLY WITH WATER AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:F4
Spec Gravity:1
pH:8.5
Evaporation Rate & Reference:N/K (BUTYL ACETATE=1)
Solubility in Water:CONSIDERABLE
Appearance and Odor:STRAW YELLOW, OPAQUE PASTE WITH NAPHTHA ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NITROUS OXIDES AND AMMONICAL VAPORS
CAN FORM IN LOW LEVELS DURING COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT SHOULD BE CONTAINERIZED AND DISCARDED AS
AN IGNITABLE HAZARDOUS WASTE ACCORDING TO APPLICABLE LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:8020
CAGE:06980
CAGE:06980
============= Composition/Information on Ingredients =============
Ingred Name:THORIUM 232
CAS:7440-29-1
RTECS #:XO6400000
===================== Hazards Identification =====================
Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION.
LATENT EFFECTS:SOMATIC/GENETIC DAMAGE.
======================= First Aid Measures =======================
First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE
COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN
PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT
VICTIM(S) MAY BE CON TAMINATED.
===================== Fire Fighting Measures =====================
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD
BRTHG APP.
Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE
IN HEAT OF FIRE.
================== Accidental Release Measures ==================
======================Handling and Storage ======================
Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION.
PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN
AREA FOR RADIOACTIVE MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK.
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS
CLOTHING.
Supplemental Safety and Health
SOURCE OF DATA-MIL HANDBOOK 600-1 SEP 76.SAFETY & HEALTH DATA DEVELOPED
BY DGSC-STF.
================== Physical/Chemical Properties ==================
HCC:A3
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL
Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION;
FISSION PRODUCTS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH
DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:868 4623 EKTATHERM XLS PRINT PAPER
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:PAPER
Fraction by Wt: >99%
Other REC Limits:NONE RECOMMENDED
Ingred Name:OTHER INGREDIENTS, <1% OR NOT HAZARDOUS
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SILVER (SARA 313) (CERCLA) (PAPER CONTAINS 0.04 GRAINS,
TROY)
CAS:7440-22-4
RTECS #:VW3500000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.1 MG/M3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THERMAL MEDIA RECEIVER(S) ARE NOT
HAZARDOUS TO HEALTH. NO PERSONAL PROTECTION IS NEEDED UNDER
RECOMMENDED CONDITIONS OF USE.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:NONE SPECIFIED BY MANUFACTURER.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:THIS PRODUCT WILL NOT CAUSE ANY
SPECIAL HEALTH OR SAFETY HAZARD, WHEN USED AS INTENDED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:NONE NORMALLY REQUIRED.
Other Protective Equipment:NONE NORMALLY REQUIRED.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PARCTICES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Appearance and Odor:PAPER, SHEET 8.5 INCHES X 12.0 INCHES; CONTAINS
0.040 SILVER GRAINS, TROY.
================= Stability and Reactivity Data =================
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION PRODUCTS DEPEND ON
CONDITIONS DURING BURNING: LIKELY PRODUCTS ARE CO, CO2, OXIDES OF
NITROGEN & SULFUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL OR DISPOSE OF IAW LOCAL, STATE AND
FEDERAL REGULATIONS.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:0.5% SENSORCAINE SOLUTION
CAGE:04473
CAGE:04473
============= Composition/Information on Ingredients =============
Ingred Name:BUPIVACAINE HYDROCHLORIDE, MARCAINE HYDROCHLORIDE *97-4*
CAS:14252-80-3
RTECS #:TK6125000
Fraction by Wt: 0.25%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGESTION: MAY CAUSE TOXIC EFFECTS,
CNS & CARDIOVASCULAR SYSTEM. ALLERGIC REACTIONS MAY OCCUR. MAY
CAUSE IRRITATION TO SENSITIVE TISSUES. INHALATION: MUCOUS MEMBRANE
IRRITATION & RESPIRATORY DEPRESSIO N. EYES: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NUMBNESS, LOSS OF SENSATION,
NERVOUSNESS, CONFUSION, DROWSINESS, BLURRED VISION, VOMITING,
TREMORS, CONVULSIONS, SLOWING OF THE HEART, BLOOD PRESSURE DROP,
UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:HYPERSENSITIVITY TO LOCAL
ANESTHETICS OF THE AMIDE TYPE.
======================= First Aid Measures =======================
First Aid:EYES: WASH THOROUGHLY W/CLEAN WATER FOR 15 MINS. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP W/NORMAL PROCEDURES USED FOR
NON-HAZARDOUS LIQUIDS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. AVOID
EXTREMES OF TEMPS. HANDLE TO AVOID BREAKAGE.
Other Precautions:AVOID INGESTION & CONTACT W/EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:LOCAL EXHAUST
Other Protective Equipment:NONE NORMALLY REQUIRED.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Melt/Freeze Pt:M.P/F.P Text:32F
Vapor Pres:17
Vapor Density:0.6
Spec Gravity:1
Evaporation Rate & Reference:(WATER = 1): 1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COMPOUNDS/MATERIALS WHICH REACT VIOLENTLY W/WATER.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF AS A NON-HAZARDOUS WASTE,
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:LIQUID CARBON DIOXIDE
CAGE:MXDST
CAGE:MXDST
============= Composition/Information on Ingredients =============
Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 99.5%
OSHA PEL:5000 PPM
ACGIH TLV:5000 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:AT 2-3% CONCENTRATION, SYMPTOMS OF
SIMPLE ASPHYXIA OCCUR; 3-5% CAUSES INCREASED RESPIRATION AND
HEADACHE; UP TO 15% CAUSES HEADACHE, NAUSEA, VOMITING AND
UNCONSCIOUSNESS. HIGHER CONCENTRATIONS CAUSE R APID CIRCULATORY
INSUFFICIENCY LEADING TO COMA AND DEATH. CO*2 IS THE MOST POWERFUL
CEREBRAL (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:VASODILATOR KNOWN. FOR SKIN
CONTACT/FROSTBITE SEE FIRST AID.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE
WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD .
SKIN:FOR CONTACT OR FROSTBITE, FLUSH AFFECTED AREA WITH WARM WATE
R. FOR SERIOUS CRYOGENIC BURN, SEE A PHYSICIAN IMMEDIATELY.
INHALATION:REMOVE TO FRESH AIR. GET PROMPT MEDICAL ATTENTION.
ADMINISTER OXYGEN OR ARTF RESP AS NEEDED. RESCUE PERS SHOULD HAVE
SCBA.
===================== Fire Fighting Measures =====================
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NON-FLAMMABLE GAS - CO*2 IS AN EXTINGUISHING AGENT
FOR FIRE-FIGHTING PURPOSE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL CO*2 CONTAINERS
EXPOSED TO HEAT AND FIRE TO PREVENT FROM RUPTURE.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:LIQ CO*2 WILL PARTIALLY FORM DRY ICE SNOW IF
RELSD TO ATM PRESS. CARBON DIOXIDE IS HEAVY GAS & WILL COLLECT IN
LOW SPOT & CONFINED AREAS W/OUT ASSISTED VENT. EVACUATE ALL PERS
FROM AFFECTED AREA. WELL VENT AREA. USE SCBA TO ENTER SPILLED
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:USE ONLY DOT OR ASME CODED CONTAINERS.
PROTECT CONTAINER FORM PHYSICAL DAMAGE. FOLLOW ALL THE SAFTY RULES
RELATED TO CRYOGENIC FLUID.
Other Precautions:AVOID LOW STOR/CONFINED AREAS & CORR CHEMS. REFER TO
CGA SAFETY BULLETIN SB-2 & PAMPHLETS P-1, G-6, G-6.1, G-6.3.
SB-2-"OXYG DEFICIENT ATM", G-6-"CARBON DIOXIDE", G-6.1-"STANDARD
FOR LOW PRESS CO*2 SY S AT CUSTOMER SITES", G-6.3-(SUP DAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED POSITIVE PRESSURE AIR LINE
WITH MASK OR NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:PROVIDE ADEQUATE VENTILATION TO PREVENT CONCENTRATION OVER
ALLOWABLE TWA OR STEL.
Other Protective Equipment:SAFETY SHOES, LOW OXYGEN ALARM (LESS THAN
18%) WHERE NECESSARY.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
BP:109F,43C (SUBLIMES). SPEC GRAV:1.014 @ 2F (H*2O=1). VP:831 PSIG @
68F. SPILL PROC:AREA. STOP LEAK AND FLOW. OTHER PREC:"CARBON
DIOXIDE CYLINDER FILLING AND HANDLING PROCEDURES FOR BEVERAGE
PLANTS, NSDS TD01". EYE PROT:AND FULL LENGTH FACE SHIELD .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SUPP DATA
Vapor Pres:SUPP DATA
Vapor Density:1.53 @ 68F
Spec Gravity:SUPP DATA
Solubility in Water:87.8% (VOL) @ 68F
Appearance and Odor:COLORLESS, SLIGHT PUNGENT ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
FORMS CARBONIC ACID WITH MOISTURE. WILL REACT WITH ALKALINE MATERIAL TO
FORM NEUTRALIZED SALT.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . VENT SLOWLY TO ATMOSPHERE WITH ADEQUATE VENTILATION.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:AQUATECH POOL SHOCK
CAGE:87892
CAGE:87892
============= Composition/Information on Ingredients =============
Ingred Name:CALCIUM HYPOCHLORITE (SARA III)
CAS:7778-54-3
RTECS #:NH3485000
Fraction by Wt: 65%
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MODERATELY IRRITATING TO SKIN, EYES
AND MUCOUS MEMBRANES AND VIA ORAL AND INHALATION ROUTES. TOXICITY
ARISES FROM ITS CORROSIVE ACTIVITY ON SKIN AND MUCOUS MEMBRANES.
TOXIC TO FISH.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: FLUSH WITH WATER. EYES: FLUSH WITH WATER FOR AT LEAST
15 MIN. GET PROMPT MEDICAL ATTENTION. INGEST: GIVE MILK, WATER OR
EGG WHITES. CALL A PHYSICIAN. INHAL: REMOVE TO FRESH AIR. SUPPORT
BREATHIN G. (GIVE O2/ARTF RESP) .
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:WATER
Fire Fighting Procedures:IN FIRES FUELED BY OTHER MATERIALS, MAY
RELEASE CHLORINE GAS. WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:COOL AFFECTED CONTAINERS WITH LARGE
AMOUNTS OF WATER.
================== Accidental Release Measures ==================
Spill Release Procedures:FLOOD AND FLUSH WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. DO NOT STORE
IN DIRECT SUNLIGHT.
Other Precautions:AVOID CONTACT WITH ORGANIC MATERIAL. WHEN DISSOLVING,
ADD SOLID MATERIAL CAUTIOUSLY TO WATER WITH STIRRING AND AVOID
SPLASHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED DUST RESPIRATOR WHERE
DUSTING OCCURS.
Ventilation:LOCAL EXHAUST RECOMMENDED.
Other Protective Equipment:CLOTHING TO MINIMIZE SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:D1
Solubility in Water:APPRECIABLE
Appearance and Odor:FREE FLOWING, WHITE, GRANULAR SOLID WITH CHLORINE
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
DO NOT MIX WITH ANYTHING BUT LARGE QUANTITIES OF WATER.
Stability Condition to Avoid:AVOID TEMPERTURES ABOVE 100 F, ACIDS,
UREA.
Hazardous Decomposition Products:CHLORINE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE IN LARGE AMOUNTS OF WATER, FLUSH TO
SEWER IF PERMITTED BY LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BATTERY ACID
CAGE:FO087
CAGE:84111
CAGE:FO087
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 99%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:CORROSIVE BURNS TO THE UPPER RESP
SYS/SKIN/EYES: SEVERE OR PERMANENT INJURY/BLINDNESS MAY RESULT.
======================= First Aid Measures =======================
First Aid:SKIN OR EYE: FLUSH W/WATER FOR AT LEAST 15 MINS. REMOVE
CONTAMINATED CLOTHING. INGESTED: DRINK WATER OR MILK, GET PROMPT
MEDICAL ATTENTION. DON'T INDUCE VOMITING. INHALED: REMOVE TO FRESH
AIR. IF BREA THING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:DRY CHEMICAL FOR SMALL FIRES; WATER SPRAY. _
Fire Fighting Procedures:AT HIGH TEMPS, H2SO4 MISTS OR SO3 GAS CAN BE
RELEASED.
Unusual Fire/Explosion Hazard:FLAMMABLE & POTENTIALLY EXPLOSIVE
HYDROGEN GAS CAN BE GENERATED IF METAL IS CONTACTED.
================== Accidental Release Measures ==================
Spill Release Procedures:DILUTE SMALL SPILLS CAUTIOUSLY W/PLENTY OF
WATER. NEUTRALIZE RESIDUE W/ALKALI SUCH ASODA ASH OR LIME
W/ADEQUATE VENTILATION. LARGE SPILLS REQUIRE A PREDETERNED PLAN.
DIKING WITH SODA ASH IS RECOMMENDE D.
======================Handling and Storage ======================
Handling and Storage Precautions:ADEQUATE VENTILATION TO REDUCE ACID
MISTS BELOW PERMISSIBLE EXPOSURE LIMITS. PACKAGING UNLOADI AREAS OR
OPEN PROCESS MAY REQUIRE MECHANICAL VENT
Other Precautions:DON'T GET IN EYES, ON SKIN OR CLOTHING. DON'T BREATHE
VAPOR OR MIST. ALWAYS ADD ACID TO WATER. STORE IN COOL, WELL
VENTILATEAREA AWAY FROM COMBUSTIBLES AND REACTIVE CHEMICALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESP W/CHEMICAL CARTRIDGES FOR
SO2 & MIST FILTERS.
Ventilation:LOCAL EXHAUST REQUIRED TO KEEP <PEL.
Supplemental Safety and Health
MSDS DATE: 08/10/82
================== Physical/Chemical Properties ==================
Spec Gravity:1.844
Solubility in Water:COMPLETE
Appearance and Odor:OILY, COLORLESS TO SLIGHTLY YELLOW, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS/ANHYDRIDES/AMINES/CARBIDES/GLYCOLS/CHLORATES/NITRATES.
Hazardous Decomposition Products:SO3 GAS, HYDROGEN GAS ON CONTACT WITH
METALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL OF SULFURIC ACID SHOULD BE CONDUCTED IN
CONFORMANCE WITH FEDERAL, STATE, AND LOCAL AIR, WATER AND SOLID
WASTE REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
NIIN: 01-429-4563
Product ID: TURBINE FUEL, AVIATION, JP-8
Cage: MO636
Box: 840
=======================================================
Contractor Summary
=======================================================
Cage: MO636
Box: 840
Cage: 3K472
=======================================================
Item Description Information
=======================================================
Item Name: TURBINE FUEL,AVIATION
Unit of Issue: GL
UI Container Qty: X
=======================================================
Ingredients
=======================================================
Cas: 8008-20-6
RTECS #: OA5500000
C16)
% Wt: 100
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 91-20-3
RTECS #: QJ0525000
% Wt: 3
OSHA PEL: 10 PPM
ACGIH TLV: 10 PPM;15 STEL
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 25551-13-7
RTECS #: DC3220000
% Wt: 1.1
OSHA PEL: 25 PPM
ACGIH TLV: 25 PPM
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: THIS PRODUCT CONTAINS PETROLEUM HYDROCARBONS. IT MAY CAUSE
IRRITATION TO THE EYES, LUNGS OR SKIN AFTER PROLONGED EXPOSURE.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES. GET MEDICAL AID.
SKIN:REMOVE CONTAMINATED CLOTHING. WASH W/LARGE AMOUNTS OF SOAP & WATER.
IF IRRITATION PERSISTS GET MEDICAL AID. INHAL:REMOVE TO FRESH AIR. IF
BREATHING HAS STOPPED ADMINISTER ARTIFICIAL RESPIRATION. GET MEDICAL AID.
INGEST:DO NOT INDUCE VOMITING. GET MEDICAL AID.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: CONTAIN SPILL. REMOVE AS MUCH AS POSSIBLE BY
VACUUMING OR SOAK UP USING ABSORBENT MATERIALS. KEEP AWAY FROM HEAT OR FLAME.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: FOLLOW FEDERAL, STATE OR LOCAL REGULATIONS. DO NOT
FLUSH TO SURFACE WATER OR SANITARY SEWER SYSTEM. RCRA HAZARDOUS WASTE:YES.
Handling And Storage Precautions: CLASS II FLAMMABLE LIQUID PER NFPA 30-1990.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 122F,50C
Lower Limits: 0.9%
Upper Limits: 6%
Extinguishing Media: FOAM, WATER SPRAY, DRY CHEMICAL, CO*2.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). DO NOT USE STRAIGHT WATER STREAM ON FIRE AS IT WILL SCATTER
FIRE.
Unusual Fire/Explosion Hazard: VAPOR MAY EXPLODE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NORMALLY NOT REQUIRED. NIOSH APPROVED ORGANIC VAPOR
RESPIRATOR TO PREVENT INHALATION WHEN IN CONFINED AREAS.
Ventilation: MECHANICAL EXPLOSION PROOF IN ENCLOSED AREAS.
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N). PROT CLOTHING AS NEC TO PREVENT SKIN CONTACT.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EYE PROT:& FULL LENGTH FACESHIELD (FP N).
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 330F,166C
Vapor Pres: 2
Vapor Density: 4.2
Spec Gravity: 0.825 (H*2O=1)
Evaporation Rate & Reference: 0.5 (ETHER=1)
Solubility in Water: SLIGHT
Appearance and Odor: CLEAR LIQUID; PETROLEUM ODOR.
Percent Volatiles by Volume: 100
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: KEEP AWAY FROM HEAT OR FLAME.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: INCOMPLETE COMBUSTION MAY PRODUCE CARBON
MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 136330
Product ID: TURBINE FUEL, AVIATION, JP-8
Review Date: 01/13/1998
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: GL
Container QTY: X
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: GJL
Symbols: G
DOT Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
Hazard Class: 3
UN ID Num: UN1993
DOT Packaging Group: III
Label: FLAMMABLE LIQUID
Special Provision: B1,B52,T7,T30
Packaging Exception: 150
Non Bulk Pack: 203
Bulk Pack: 242
Max Qty Pass: 60 L
Max Qty Cargo: 220 L
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: HIA
IMO Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. o
IMDG Page Number: 3345
UN Number: 1993
UN Hazard Class: 3.3
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 3-07
MED First Aid Guide NUM: T
=======================================================
Detail IATA Information
=======================================================
IATA PSN CA
IATA UN ID Num: 1993
IATA Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. *
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
UN Packing Group: III
Packing Note Passenger: 309
Max Quant Pass: 60L
Max Quant Cargo: 220L
Packaging Note Cargo: 310
=======================================================
Detail AFI Information
=======================================================
AFI PSN CA
AFI Symbols: *
AFI Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S.
AFI Hazard Class: 3
AFI UN ID NUM: UN1993
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A7.3
=======================================================
HAZCOM Label
=======================================================
Product ID: TURBINE FUEL, AVIATION, JP-8
Cage: MO636
Assigned IND: Y
Company Name: LA GLORIA OIL & GAS COMPANY
Street: UNKNOWN
PO Box: 840
Zipcode: 75710
Label Required IND: Y
Date Of Label Review: 12/04/1997
Status Code: C
Label Date: 12/04/1997
Origination Code: G
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE:THIS PRODUCT CONTAINS PETROLEUM
HYDROCARBONS. IT MAY CAUSE IRRITATION TO THE EYES, LUNGS OR SKIN AFTER
PROLONGED EXPOSURE. CHRONIC:NONE LISTED BY MANUFACTURER.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HTZ FIBER VENEER MODULES
CAGE:8C482
CAGE:8C482
============= Composition/Information on Ingredients =============
Ingred Name:SUPP DATA: ITS USEFUL LIFE (TEAR OUT) DUST GENERATION IS
LIKELY. THE USER SHOULD BE WARNED OF CURRENT PEL & (SEE ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: PREC SHOULD BE TAKEN TO AVOID INHAL OF DUST. THIS
PROD CAN CAUSE IRRIT TO EYES ON CONT & TO SKIN ON (SEE ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: PRLNGD CONT. (ACUTE) IRRIT OF SKIN & UPPER RESP
SYSTEM. (CHRONIC) CAN OCCUR FROM LONG TERM EXCESSIVE(SEE ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:INHAL OF CRYSTALLINE SILICA DUST. CRYSTALLINE SILICA
IN LUNGS CAN PRODUCE A PNEUMOCCONIOSIS, COMMONLY(SEE ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: CALLED SILICOSIS, WHICH IS A SLOWLY DEVELOPING
DISEASE. SYMP ARE USUALLY DELAYED (10 YRS OR MORE). (SEE ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15: SMOKING CAN INCREASE RISK OF INJURY. SUMMARY:
CERAMIC FIBER IS UNDER INVESTIGATION AS A POSS ANIMAL (SEE ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16: CARCIN. ANIMAL STUDIES TO DATE ARE INCONCLUSIVE.
EXPOS TO DUST FROM THIS PROD SHOULD BE MINIMIZED (SEE ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17: UNTIL FURTHER ANIMAL & HUMAN STUDIES ARE COMPLETE.
THIS PRODUCT IS SUSPECTED TO BE AN ANIMAL CARCIN.
RTECS #:9999999ZZ
Ingred Name:INORGANIC GLASS
CAS:65997-17-3
Ingred Name:ALUMINA ZIRCONIA SILICA FIBER
Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE
CAS:14464-46-1
RTECS #:VV7325000
Fraction by Wt: 20%
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.05 MG/M3 RDUST9293
Ingred Name:OTHER PREC: FOR SAFE USE/EXPOS. NIOSH/MSHA APPRVD RESP
SHOULD BE USED FOR DUST LEVS <10X PEL. DUST GENERATION(SEE ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: SHOULD BE MINIMIZED BY USE OF DUST CONTROL
EQUIP/WATER SPRAY. WEAR PROT CLTHG & VACUUM CLEAN PRIOR TO (SEE ING
6)
RTECS #:9999999ZZ
Ingred Name:ING 5: REMOVING CLOTHING.
RTECS #:9999999ZZ
Ingred Name:RESP PROT: SHOULD BE USED TO CONTROL/REDUCE AIRBORNE CONC.
ACCEP NIOSH/MSHA APPRVD RESP REC FOR GIVEN (SEE ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: AIRBORNE CERAMIC FIBER CONC: 2.0-5.0 F/CC-DISP DUST
MASK. 5.0-50.0 F/CC-FULL FACEPIECE FOR HIGH (SEE ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: EFFICIENCY FILTER. 50.0 F/CC-FULL FACEPIECE
SUPPLIED-AIR APPRVD AIR SOURCE REQ. PENDING RESULTS OF (SEE ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: LONG-TERM HLTH EFTS STUDIES, ENGINEERING CONTROL OF
AIRBORNE FIBERS TO LOWEST LEVS ATTAINABLE IS ADVISED.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HTZ FIBER IS AN ALUMINA ZIRCONIA
SILICA FIBER FOR REDUCING HEAT TRANSMISSION THRU FURNACE, KILN &
VESSEL STRUCTURES. THE CURRENT ACGIH, TLV FOR MINERAL WOOL FIBER,
AS DUST IS 10 MG/M3. CRYSTALLINE SIL ICA (CRISTOBALITE) WILL FORM
AFTER SERVICE AT TEMPS 1000C. THE "AFTER SERVICE" DUSTS CAN CONTAIN
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE: GROUP 2A (IARC).
Effects of Overexposure:HLTH HAZ: 0 TO 1% CRISTOBALITE CAS #14464-46-1
(CRYSTALLINE SILICA) WHICH CAN PRESENT A HLTH HAZ IF INHALED OVER
LONG PERIODS OF TIME. "ON THE BASIS OF INITIAL EXPERIMENTAL TESTS
IN ANIMALS & LIMITED EPIDEMILOGICAL STUDIES IN HUMAN POPULATIONS,
THE IARC HAS CONCLUDED THAT THERE IS LIMITED EVIDENCE FOR THE (SUPP
DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING UPPER RESPIRATORY AND
LUNG DISEASES SUCH AS, BUT NOT LIMITED TO, BRONCHITIS, EMPHYSEMA
AND ASTHMA.
======================= First Aid Measures =======================
First Aid:SKIN: WASH OFF THOROUGHLY USING A MILD SOAP AND WATER.
INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR. SUPPORT
BREATHING (GIVE O*2/ARTF RESP) .
===================== Fire Fighting Measures =====================
Flash Point:NON-COMBUSTIBLE
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO THE
SURROUNDING AREA.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THIS PRODUCT IS A NON-COMBUSTIBLE
REFRACTORY.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:BECAUSE OF POSS PRESENCE OF
CRYSTALLINE SILICA IN FIRE REFRACTORY LININGS, PARTICULAR CARE
SHOULD BE EXERCISED DURING TEAR-OUT TO MIN GEN OF DUST.
Other Precautions:ADHERENCE TO PROPER METHODS OF DUST SUPPRESSION AND
CONTROL IS IMPERATIVE. THE FOLLOWING ARE RECOMMENDED PRECAUTIONS TO
BE TAKEN DURING REMOVAL: EMPLOYEES SHOULD BE APPRISED OF HAZARDS
AND PROPER COND ITIONS AND PRECAUTIONS (SEE ING 4)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:PROVIDE WORKERS W/NIOSH/MSHA APPRVD DUST RESP
WHERE DUST LEVS MAY EXCEED PEL. NIOSH/MSHA APPRVD EQUIP ARE REC
WHEN AIRBORNE FIBER EXPOS LIMS ARE EXCEEDED. NIOSH/MSHA APPRVD
BRTHG EQUIP MAY BE REQ FORNON-ROUTINE & EMER USE. VENT (SEE ING
7)
Ventilation:PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION TO
MEET PEL REQUIREMENTS.
Other Protective Equipment:PROTECTIVE CLOTHING AND VACUUM CLEAN PRIOR
TO REMOVING CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: CARCIN OF CRYSTALLINE SILICA TO HUMANS. IARC HAS
CONVENED A SPECIAL TASK FORCE TO REVIEW CARCIN OF SILICA." THE
CURRENT OSHA PEL MAY BE CALCULATED BY USING THE FOLLOWING EQUATION,
5 M G/M3 DIVIDED BY PERCENT FREE SILICA + TWO, AVERAGED OVER AN 8
HR WORK SHIFT. WHEN THIS PROD IS REMOVED AFTER(SEE ING 11)
================== Physical/Chemical Properties ==================
HCC:T6
Appearance and Odor:WHITE TO OFF-WHITE FIBER BLANKET, NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:SOLID WASTE REGULATIONS APPLY. CONSULT LOCAL,
STATE AND FEDERAL REGULATORY AGENCIES TO DETERMINE BEST DISPOSAL
ALTERNATIVES.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:67 PERFORMANCE BARRIER COAT
Preparer's Name:MARK A. RAKAH
CAGE:0PK40
CAGE:70526
CAGE:0PK40
============= Composition/Information on Ingredients =============
Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER
CAS:107-98-2
RTECS #:UB7700000
Fraction by Wt: <5%
Other REC Limits:100 PPM
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
Ingred Name:N-PROPYL ALCOHOL
CAS:71-23-8
RTECS #:UH8225000
Fraction by Wt: <5%
Other REC Limits:200 PPM
OSHA PEL:200 PPM/250 STEL
ACGIH TLV:S,200PPM/250STEL9192
Ingred Name:AMMONIUM HYDROXIDE(SARA III)
CAS:1336-21-6
RTECS #:BQ9625000
Fraction by Wt: TRACE
Other REC Limits:25 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:VOL ORGANIC CMPD: 1.25 LBS/GAL (149.8 G/LITER)
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT
IRRITATION, HARMFUL, FATAL, & PERMANENT CENTRAL NERVOUS CHANGES.
SKIN: IRRITATION & ABSORPTION. EYES/INGESTION: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: RESPIRATORY TRACT IRRITATION,
HARMFUL, FATAL, & PERMANENT CENTRAL NERVOUS SYSTEM CHANGES. SKIN:
IRRITATION & ABSORPTION. EYES/INGESTION: IRRITATION.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/COPIOUS
AMOUNTS OF WATER FOR AT LEAST 15 MINS. SKIN: CLEAN & WASH W/SOAP &
WATER. INGESTION: INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:54-64F
Lower Limits:1.5%
Upper Limits:13.5%
Extinguishing Media:FOAM, CO2, CHEMICAL POWDER, & WATER MIST
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS. WATER MAY BE INEFFECTIVE. IF
WATER IS USED, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:USE WATER TO KEEP FIRE-EXPOSED CLOSED
CONTAINERS COOL TO PREVENT PRESSURE BUILD-UP & EXPLOSION DUE TO
EXTREME HEAT. FLAMMABLE & COMBUSTIBLE LIQUID.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE ALL POSSIBLE SOURCES OF
IGNITION. CONFINE SPILL W/INERT ABSORBENT & CLEAN UP W/SPARK-PROOF
TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE <32F. USE STATIC LINES
WHEN MIXING & TRANSFERRING MATERIAL. DON'T ALLOW MATERIAL TO FREE
FALL MORE THAN 5 INCHES. AVOID CONTACT W/SKIN.
Other Precautions:FOR INDUSTRIAL USE ONLY. DON'T TAKE INTERNALLY. DON'T
FLAME CUT/WELD/BRAZE ON COATED METAL. AVOID INHALATION OF VAPORS.
DON'T STORE NEAR OPEN FLAMES OR EXTREME HEAT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR AN AIR-SUPPLIED RESPIRATOR-TYPE FILTER
SYSTEM SUCH AS NIOSH/MSHA TC23C TO REMOVE A COMBINATION OF
PARTICLES, GAS, & VAPORS.
Ventilation:PROVIDE ADEQUATE GENERAL MECHANICAL VENTILATION IN VOLUME &
PATTERN TO KEEP <TLV.
Other Protective Equipment:RECOMMENDED
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
PRODUCT MAY CONTAIN CHEMICALS LISTED IN THE CALIFORNIA PORPOSITION 65
TO BE KNOWN TO CAUSE CANCER, BIRTH DEFECTS, OR OTHER REPRODUCTIVE
HARM. MISUSE BY CONCENTRATING & INHALING THE CONTENTS MAY BE HAR
MFUL OR FATAL. MANY WATERBORNE PRODUCTSCONTAIN SMALL TRACES OF
ORGANIC SOLVENTS. 10.93 LBS/GAL.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:207-248F
Vapor Pres:17.30
Vapor Density:<AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:69.2%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALIES, & OXIDIZERS
Stability Condition to Avoid:OPEN FLAMES, ELECTRICAL/STATIC DISCHARGE,
EXTREME HEAT & TEMPS <32F
Hazardous Decomposition Products:CO2, CO, & CARBON SMOKE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. LANDFILL OR INCINERATE IN APPROVED FACILITY BY
LICENSED CONTRACTOR. DON'T INCINERATE IN CLOSED CONTAINER.
FLAMMABLE & COMBUSTIBLE LIQUID . DOT UN1263.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:METERPAK #207
CAGE:LO289
CAGE:0SL71
CAGE:LO289
============= Composition/Information on Ingredients =============
Ingred Name:DIMETHYL BENZYL AMMONIUM CHLORIDE
CAS:68391-01-5
Other REC Limits:NOT AVAILABLE
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PRODUCT SOLD IN WATER SOLUBLE POUCHES,
DIRECT CONTACT W/PRODUCT UNLIKELY UNDER NORMAL USE. EYES: CAN CAUSE
SEVERE EYE IRRITATION. SKIN: CAN CAUSE IRRITATION. INGESTION:
GASTROINTESTINAL TRACT IRRITATI ON, NAUSEA, VOMITING, DIARRHEA.
INHALATION: NOSE & THROAT IRRITATION.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/RUNNING WATER AT LEAST 15 MINUTES. GET MEDICAL
ATTN. IF SYMPTOMS PRESENT AFTER WASHING. SKIN: WASH W/WARM WATER.
IF IRRITATION DEVELOPS, CALL DR. INGESTION: DRINK LARGE AMOUNTS
MILK/WATE R. CALL DR. INHALATION: REMOVE TO FRESHAIR, APPLY CPR IF
NECESSARY. SEEK MEDICAL ATTN. IMMEDIATELY IF SYMPTOMS PERSIST.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:FOR SURROUNDING FIRE.
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SPRINKLE W/SWEEPING COMPOUND TO REDUCE
DUSTING. SWEEP UP, PUT INTO AN APPROVED CONTAINER FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:PROTECT FROM FREEZING OR EXCESSIVE
HEAT. WHEN HANDLING LARGE CONTAINERS USE PROTECTIVE EYE SHIELD.
WHEN NOT IN USE, KEEP CONTAINER TIGHTLY CLOSED.*
Other Precautions:NK *USE POLYETHYLENE CONTAINERS FOR INDEFFINITE
PERIOD OF STORAGE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/OSHA APPROVED RESPIRATOR IF DUSTING
LIKELY.
Ventilation:STANDARD ROOM VENTILATION ADEQUATE.
Other Protective Equipment:SUFFICIENT CLOTHING TO PREVENT DIRECT SKIN
CONTACT.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING ANY
CHEMICALS.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:0.9
Evaporation Rate & Reference:NA
Solubility in Water:COMPLETE
Appearance and Odor:BLUE POWDER, PLEASANT FRAGRANCE PACKAGED IN WATER
SOLUBLE POUCH.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
DO NOT MIX W/ACIDS OR OTHER CLEANERS.
Hazardous Decomposition Products:AMMONIACAL VAPORS, OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN ACCORDANCE W/FEDERAL, STATE, LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:NCI-C60399
Preparer's Name:F. KEVIN REILLY
CAGE:DO501
CAGE:DO501
CAGE:0G9K0
============= Composition/Information on Ingredients =============
Ingred Name:MERCURY (SARA 313) (CERCLA)
CAS:7439-97-6
RTECS #:OV4550000
Fraction by Wt: 100%
OSHA PEL:0.1 MG/M3, C
ACGIH TLV:0.025 MG/M3, S
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SUPDAT:DAYS & THEN 2 MG/M3 EVERY 12 HRS FOR TOTAL OF 10
DAYS IF NEC. DIMERCAPROL IS AVAIL AS 10% SOLN IN OIL FOR (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:INTRAMUSC ADMIN. HEMODIALYSIS WILL SPEED REMOVAL OF
MERCURY-DIMERCAPROL COMPLEX. PENICILLAMINE IS ALSO EFT,(ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3:GIVE UP TO 100 MG/KG/DAY DIVIDED INTO 4 DOSES FOR NO
LONGER THAN 1 WK. IF LONGER ADMIN PERIOD IS WARRANTED,(ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:DOSAGE SHOULD NOT EXCEED 40 MG/KG/DAY. GIVE DRUG
ORALLY HALF HR BEFORE MEALS, CHELATING AGENT SHOULD BE (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:CONTINUED UNTIL URINE-MERCURY LEVEL FALLS <50 UG/24
HRS. SHOULD BE ADMIN BY MD. FOR MORE INFO, CONT NEHC .
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:DIARR, PROSTRATION). SYMPS USUALLY SUBSIDE
W/INT 24-36 HRS. SKIN:MAY CAUSE IRRIT & REDNESS. SM (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:AMTS MAY BE ABSORBED THRU INTACT SKIN. SUBCUTANEOUS
INTRODUCTION, FROM HNDLG BROKEN THERMOMETERS, MAY RSLT (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:IN LOC INFLAMM, GRANULOMATOUS RXNS & SLIGHT SIGNS OF
POIS INCL DIGEST DISORDERS, METALLIC TASTE IN MOUTH &(ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:NEUROPSYCHIC DISORDERS. EYE:MAY CAUSE IRRIT &
REDNESS. ANIMAL STUDIES INDICATE DIFFUSION & ABSORPTION OF (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:MERCURY INTO EYE TISSUES. INGEST:MAY CAUSE BURNING
OF MOUTH & THROAT, THIRST, NAUS & VOMIT. RARELY, A LG (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:SINGLE DOSE MAY RSLT IN SIGNS & SYMPS OF CHRONIC
INHAL IF SUFFICIENT AMTS ARE RETAINED IN BODY. CHRONIC: (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:INHAL:MAY CAUSE MERCURIALISM, WHICH IS CHARACT BY
FINE TREMORS & ERETHISM. TREMORS MAY AFFECT HANDS (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:FIRST, BUT MAY ALSO BECOME EVID IN FACE, ARMS &
LEGS. ERETHISM MAY BE MANIFESTED BY ABNORMAL SHYNESS, (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:BLUSHING, SELF-CONSCIOUSNESS, DEPRESS/DESPONDENCY,
RESENTMENT OF CRITICISM, IRRITABILITY/EXCITABILITY, (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:HDCH, FATG, INSOM, HALLUCINATIONS, MEMORY LOSS,
MENTAL DETERIORATION. RENAL INVOLVMENT MAY BE INDICATED (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16:BY PROTEINURIA, ALBUMURIA, ENZYMURIA & ANURIA;
SALIVATION, GINGIVITIS, STOMATITIS, LOOSENING OF TEETH, (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:BLUE LINES ON GUMS, DIARR, WT LOSS, ANOREXIA, SPEECH
& SENSORY DISORDERS, UNSTEADY GAIT, CHRONIC PNEUM & (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:MILD ANEMIA, SENSIT. INTRAUTERINE EXPOS MAY RSLT IN
TREMORS & INVOLUNTARY MOVEMENTS IN INFANTS. MERCURY (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:IS EXCRETED IN BREAST MILK. REPRO EFTS & EFTS ON
FERTILITY IN MALE RATS. SKIN:DERMAL SENSIT & SYSTEMIC (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:EFTS AS IN CHRONIC INHAL. EYE:MERCURIALENTIS,
DISCOLORATION OF CRYSTALLINE LENS, ON SLIT LAMP EXAM. (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21:INGEST:TOX EFTS AS DETAILED IN CHRONIC INHAL. TARGET
EFTS:SENSITIZER - PULM, DERMAL; NEUROTOXIN; (ING 23)
RTECS #:9999999ZZ
Ingred Name:ING 22:NEPHROTOXIN; POIS MAY ALSO AFFECT RESP & GI SYSTEMS.
NOTE:MERCURY APPEARS ON THE NAVY LIST OF OCCUP CHEM (ING 24)
RTECS #:9999999ZZ
Ingred Name:ING 23:REPRO HAZS. SEEK CONSULTATION FROM APPROP HEALTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE (ING 25)
RTECS #:9999999ZZ
Ingred Name:ING 24:HNDLG & EXPOS INFO . FOR MORE SPECIFIC INFORMATION,
CONTACT NEHC .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:DYSP, COUGH, FEVER, NAUS,
VOMIT, DIARR, HDCH, STOMATITIS, SALIVATION, GINGIVITIS, METALLIC
TASTE, CARD ABNORMS, RESP IRRIT, CHEST PAIN & TIGHTNESS,
NECROTIZING BRONCHIOLITIS, PNEUM, PULM E DEMA, PNEUMOTHORAX,
INTERSTITIAL FIBROSIS, DEATH, ACIDOSIS, RENAL DMG, METAL FUME FEVER
(FLU-LIKE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:ILLNESS W/SYMPS SUCH AS SUDDEN ONSET
OF THIRST & SWEET, METALLIC/FOUL TASTE IN MOUTH, UPPER RESP TRACT
IRRIT, COUGH, DRYNESS OF MUC MEMBS, LASS, GENERALIZED FEELING OF
MALAISE, FEVER, CHILLS, MUSC PAIN, MILD TO SEV HDCH, NAUS, OCCAS
VOMIT, EXAGGERATED MENTAL ACTIVITY, PROFUSE SWEAT, EXCESS
URINATION, (ING 7)
Medical Cond Aggravated by Exposure:PERS W/CHRONIC RESP DISEASE, NERV
SYS DISORDERS & KIDNEY DISEASE ARE AT INCR RISK FROM EXPOS.
ALLERGIC RXNS THAT MAY OCCUR IN PREVIOUSLY EXPOS PERS INCL DERM,
ENCEPHALITIS & DEATH.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O*2/ARTF RESP)
. EYES:IMMED FLUSH W/POTABLE WATER FOR MIN OF 15 MINS, SEEK
ASSISTANCE FROM MD . SKIN:FLUSH W/COPIOUS AMTS OF WATER. CALL MD (
). INGEST:REMOVE BY GASTRIC LAVAGE/EMESIS. MAINTAIN BLOOD PRESS &
AIRWAY. GIVE OXYG IF RESP IS DEPRESSED. DO NOT PERFORM GASTRIC
LAVAGE/EMESIS IF VICTIM IS UNCON. GET MED ATTN IMMED. (SUPP DATA)
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR
STANDARD FOAM. FOR LARGER FIRES, USE WATER SPRAY, FOG OR STD FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . MOVE
CNTNRS FROM FIRE AREA IF POSS. COOL CNTNRS EXPOS TO FLAMES W/WATER
FROM SIDE UNTIL WELL AFTER FIRE (SUPDAT)
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT TOUCH SPILL. STOP LEAK IF W/OUT RISK.
SM SPILL:TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR
LATER DISP. LG SPILL:DIKE FAR AHEAD FOR LATER DISP. KEEP UNNEC
PEOPLE AWAY. ISOLATE HAZ A REA & DENY ENTRY. FOR MORE INFO, CONT
NECH .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:OBSERVE ALL FEDERAL, STATE & LOCAL
REGULATIONS WHEN STORING THIS SUBSTANCE. FOR ASSISTANCE, CONTACT
THE DISTRICT DIRECTOR OF THE EPA.
Other Precautions:STORE AWAY FROM INCOMPATIBLE SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SPEC RESP MUST BE NIOSH APPROVED: 0.5 MG/M3-CHEM
CARTRIDGE RESP; SUPPLIED-AIR RESP; SCBA. 1.25 MG/M3-SUPPLIED-AIR
RESP OPERATED IN CONTINUOUS FLOW MODE; POWERED AIR-PURIFYING RESP
W/CANISTER. FOR MORE SPECIFIC INFO, CONTACT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
MEET PELS.
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . MUST WEAR APPROP PROT(IMPERVIOUS) CLTHG & EQUIP TO PVNT
SKIN CONT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:IS OUT. STAY AWAY FROM STOR TANK ENDS. USE AGENTS
SUITABLE FOR TYPE OF FIRE; USE WATER IN FLOODING AMTS AS FOG. AVOID
BRTHG CORR & POIS VAPS, KEEP UPWIND. CNDTNS(STAB):(WOOD, PAPER, OI
L, ETC). EYE PROT:FULL LGTH FSHLD . FIRST AID PROC:ANTIDOTE:GIVE
DIMERCAPROL, 3 MG/M3 EVERY 4 HRS FOR 1ST 2(ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:674F,357C
Melt/Freeze Pt:M.P/F.P Text:-38F,-39C
Vapor Pres:0.002 @25C
Vapor Density:7
Spec Gravity:13.5939
Solubility in Water:INSOLUBLE
Appearance and Odor:SILVERY LIQUID W/METALLIC LUSTER; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALUMINUM, AMINES, CHLORINE, OXIDANTS, POTASSIUM, SODIUM. FOR MORE
COMPLETE LISTING OF MATLS TO AVOID, CONT NEHC .
Stability Condition to Avoid:MAY BURN BUT DOES NOT IGNITE READILY.
FLAMM, POIS GASES MAY ACCUM IN TANKS & HOPPER CARS. MAY IGNITE
COMBUSTS (SUPDAT)
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HIGHLY TOXIC VAPORS OF MERCURY & MERCURY OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE
DISTRICT DIRECTOR OF THE EPA. DISPOSAL MUST BE I/A/W STANDARDS
APPLICABLE TO GENERATORS OF HAZ WASTE, 40 CFR 252, EPA HAZ WASTE
NUMBER U151.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:192 5007 KODAK INDUSTREX FIXER AND REPLENISHER 200 GALS
Kit Part:Y
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 70-80%
Ingred Name:ALUMINUM SULFATE
CAS:10043-01-3
RTECS #:BD1700000
Fraction by Wt: 10-15%
ACGIH TLV:2 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SULFURIC ACID (SUSPECTED HUMAN CARCINOGEN BY IARC - GROUP
1) *94-3*
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 14%
OSHA PEL:1 MG/CUM
ACGIH TLV:1 MG/CUM=IC
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (MALE RAT): 3200 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW
HAZARD FOR RECOMMENDED HANDLING. EYES/SKIN: CAUSES BURNS.
INGESTIION: HARMFUL. MAY CAUSE BURNS TO GI TRACT.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:INHALATION: EXPECTED TO BE A LOW HAZARD FOR
RECOMMENDED HANDLING. EYES/SKIN: CAUSES BURNS. INGESTION: HARMFUL.
MAY CAUSE BURNS TO GI TRACT.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. EYES/SKIN:
FLUSH IMMEDIATELY W/WATER FOR 15 MINS. INGESTION: DON'T INDUCE
VOMITING. GIVE A GLASS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER W/LARGE AMOUNTS OF WATER. MAY
REQUIRE NEUTRALIZATION IF PH <3/>12. ABSORB W/VERMICULITE/OTHER
INERT MATERIAL & PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE THOROUGHLY TO REMOV E RESIDUAL CONTAMINATION.
Neutralizing Agent:SODIUM CARBONATE
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. USE
W/ADEQUATE VENTILATION.
Other Precautions:DON'T GET IN EYES/ON SKIN/CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED
Ventilation:GOOD GENERAL W/10 AIR CHANGES PER HOUR.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER,
FACE SHIELD.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE/LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. DESTROY/THOROUGHLY CLEAN SHOES.
Supplemental Safety and Health
PRODUCT HAS A HIGH POTENTIAL TO AFFECT SOME AQUATIC ORGANISMS &
SECONDARY WASTE TREATMENT MICROBIAL METABOLISM. PRODUCT HAS A LOW
POTENTIAL TO BIOCONCENTRATE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.247
pH:<1
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID W/NO ODOR
Percent Volatiles by Volume:75/WT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES
Hazardous Decomposition Products:SULFUR DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:SMALL: NEUTRALIZE. FLUSH TO SEWER W/LARGE
AMOUNTS OF WATER IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RTV9950
CAGE:01139
CAGE:01139
============= Composition/Information on Ingredients =============
Ingred Name:DIBUTYL TIN DILAURATE (AS TIN)
CAS:77-58-7
RTECS #:WH7000000
Fraction by Wt: 5-10%
Other REC Limits:0.1 MG/CUM (SN)
OSHA PEL:S, 0.1 MG/M3
ACGIH TLV:S, 0.1 MG/M3; 8990
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 175MG/KG (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: CAUSES MODERATE IRRITATION.
INHALATION: CAUSES MODERATE RESPIRATORY IRRITATION, CNS DAMAGE &
RESPIRATORY AILMENTS. EYE: CAUSES SEVERE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: CAUSES MODERATE IRRITATION. INHALATION:
CAUSES MODERATE RESPIRATORY IRRITATION, CNS DAMAGE & RESPIRATORY
AILMENTS. EYE:CAUSES SEVERE IRRITATION.
Medical Cond Aggravated by Exposure:RESPIRATORY AILMENTS, CNS
DISORDERS.
======================= First Aid Measures =======================
First Aid:INGESTION: INDUCE VOMITING BY GIVING 2 GLASSES OF
WATER/STICKING FINGERS DOWN THROAT; NEVER GIVE ANYTHING TO AN
UNCONSCIOUS PERSON. GET MED ATT. SKIN: REMOVE CONTAMINATED
CLOTHING/LAUNDER BEFORE REUSE . WASH W/SOAP & WATER. REMOVE
CONTAMINATED SHOES/DISCARD. GET MED ATT IF IRRITATION PERSISTS.
INHALATION: MOVE PERSON TO FRESH AIR. EYE: FLUSH W/PLENTY OF WATER
FOR AT LEAST 15 MINS. GET MED ATT.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>200F
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE, SCRAPE/SOAK UP IN AN INERT MATERIAL &
PUT IN A CONTAINER FOR DISPOSAL. WASH WALKING SURFACES W/DETERGENT
& WATER TO REDUCE SLIPPING HAZARD. WARN OTHER WORKERS OF SPILL.
INCREASE AREA VENTILATION .
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
AVOID BREATHING VAPORS. AVOID CONTACT W/SKIN & EYES. REMOVE
CONTAMINATED CLOTHING & SHOES/LAUNDER BEFORE REUSE.
Other Precautions:USE ONLY IN A WELL VENTILATED AREA. KEEP AWAY FROM
FOOD/SMOKING MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE IN A WELL VENTILATED AREA. USE APPROVED
NIOSH RESPIRATORY PROTECTION IF TLV EXCEEDED.
Ventilation:USE ONLY IN WELL VENTILATED AREA. MECHANICAL.
SHOWERS/EYEBATH.
Work Hygienic Practices:WASH HANDS BEFORE EATING & SMOKING. REMOVE
CONTAMINATED CLOTHING & SHOES/LAUNDER BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>250F
Spec Gravity: 1.67
Evaporation Rate & Reference:(BU AC = 1): <1
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, WHITE, SALTY ACID ODOR
Percent Volatiles by Volume:<4%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTACT W/OXIDIZING AGENTS.
Hazardous Decomposition Products:CO2, SILICON DIOXIDE, TIN FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:POLY PROSS
CAGE:4Z801
CAGE:4Z801
============= Composition/Information on Ingredients =============
Ingred Name:NON HAZARDOUS INGREDIENTS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN IRRITATION IN SOME
INDIVIDUALS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SKIN IRRITATION.
======================= First Aid Measures =======================
First Aid:SKIN: WASH SKIN WITH SOAP AND WATER. EYES: WASH FOR AT LEAST
15 MINUTES. INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH
AIR. SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) CALL MD
(FP N).
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, FOAM, CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Other Precautions:NORMAL HOUSEKEEPING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED.
Ventilation:LOCAL EXHAUST: SAFTISFACTORY.
Other Protective Equipment:EYE BATH.
Work Hygienic Practices:NORMAL PRECAUTIONS COMMON TO GOOD MANUFACTURING
PRACTICES.
Supplemental Safety and Health
SPEC GRAV: 1.19-1.21 (H*2O=1).
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:SUPP DATA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SMALL DRY OFF WHITE FLAKES; LITTLE OR NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:BURY IN LANDFILL WHERE PERMITTED UNDER
APPROPRIATE FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PR-1422 A-2, PART A
Kit Part:Y
Preparer's Name:JCS
CAGE:DO563
CAGE:83574
CAGE:DO563
============= Composition/Information on Ingredients =============
Ingred Name:DIMETHYL ACETAMIDE (DMAC)
CAS:127-19-5
RTECS #:AB7700000
Fraction by Wt: 30%
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 PPM (SKIN)
ACGIH TLV:10 PPM (SKIN)
Ingred Name:CALCIUM DICHROMATE
CAS:14307-33-6
RTECS #:HX7630000
Fraction by Wt: 20%
Other REC Limits:NONE SPECIFIED
OSHA PEL:CEILING 0.1 MG/M3
ACGIH TLV:0.05 MG/M3
Ingred Name:MAGNESIUM DICHROMATE
CAS:13423-61-5
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:CEILING 0.1 MG/M3
ACGIH TLV:0.05 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: EYE DAMAGE. SKIN: TOXIC BY SKIN
ABSORPTION. LAB TESTS HAVE SHOWN DERMAL APPLIC (DMAC TO PREGNANT
RATS) PRODUCED FETAL ABNORMALITIES. PROLONG/OVEREXPOS--PAINLESS
PENETRATING SKIN ULCERS. INHAL: LI VER DAMAGE. BRONCO ASTHMA.
OVEREXPOS--PENETRATING MUCOUS MEMBRANE/NASAL SEPTUM ULCERS. INGEST:
LIVER/KIDNEY DAMAGE.
Explanation of Carcinogenicity:CHROMIUM COMP NOT DESIGNATED (NTP/IARC).
CALIF SAFE DRINKING WTR & TOXIC ENFORC ACT INCLUDES HEXAVALENT
CHROMIUM COMPS.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. PROLONGED
OVEREXPOSURE MAY CAUSE ALLERGIC SKIN RASH. INHALATION: IRRITATION
OF MUCOUS MEMEBRANES. (VAPOR) IRRITATION, NAUSEA, HEADACHE,
WEAKNESS. INGESTION: IRRITAT ION OF STOMACH AND INTESTINES. NAUSEA,
VOMITING AND DIARRHEA.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH LUKEWARM WATER FOR 15 MINUTES. CONSULT
PHYSICIAN. SKIN: WASH WITH SOAP AND WATER. IF SYMPTOMS PERSIST,
CONSULT A PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. IF SYMPTOMS
ARE PRESENT CO NSULT A PHYSICIAN. INGESTION: CONSULT APHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE COMPLETE PERSONAL PROTECTION.
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE AND COVER THE SPILL WITH A NON-OXIDIZABLE
ABSORBENT. SCOOP INTO CONTAINER. SPRINKLE SODIUM THIOSULFATE ON
RESIDUE. WORK INTO RESIDUE. SCOOP INTO DISPOSAL CONTAINER. CLEAN
AREA WITH WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID INGESTION. DUE TO TOXICITY BY
SKIN ABSORPTION, AVOID ALL SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Ventilation:GENERAL VENTILATION TO MAINTAIN VAPOR BELOW PEL.
Other Protective Equipment:SKIN AREAS SUBJECT TO SPLASH SHOULD BE
PROTECTED WITH NITRILE, BUTYL, NAT RUBBER, POLYETHYLENE APRON OR
COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
SMOKING OR EATING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:1.45
Solubility in Water:COMPLETE
Percent Volatiles by Volume:70
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
EASILY OXIDIZABLE MATERIALS.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN;
CHROMIUM COMPOUNDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:EPA WASTE NO. D-007. DISPOSE OF SPILLAGE IN
COMPLIANCE WITH FEDERAL AND STATE REGULATIONS.
| 1 | eyes_protection_mandatory |
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