text
stringlengths 595
18.7k
| label
int64 0
1
| label_text
stringclasses 2
values |
|---|---|---|
=======================================================
Product ID: 12005 REPLICATING SOLUTION
Cage: LADDR
Box: 1005
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: LADDR
Box: 1005
=======================================================
Contractor Summary
=======================================================
Cage: 33913
Cage: LADDR
Box: 1005
=======================================================
Ingredients
=======================================================
Cas: 67-64-1
RTECS #: AL3150000
% Wt: >90
OSHA PEL: 2400 MG/CUM
ACGIH TLV: 750 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 9012-09-3
% Wt: <10
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: TCLO (HUMAN): 500 PPM
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION: NASAL/THROAT IRRITATION W/LARYNGITIS,
BRONCHITIS & POSSIBLE CENTRAL NERVOUS SYSTEMS. SKIN: IRRITATION. EYES:
MILD IRRITATION.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, COUGHING, HEADACHE, DIZZINESS,
DROWSINESS, WEAKNESS, CONFUSION, NAUSEA, INTOXICATION, SORE THROAT,
RESTLESSNESS, GASTRITIS, VOMITING, HEMATEMESIS, STUPOR, TWITCHNG, COLLAPSE,
UNCONSCIOUSNE SS, CONVULSIONS, PARALYSIS.
First Aid: INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NEEDED. SKIN/EYES:
WASH W/LARGE AMOUNTS OF WATER. INGESTION: IF CONSCIOUS, GIVE 2 TO 4 GLASSES
OF WATER & INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN A LL CASES.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SHUT OFF IGNITION SOURCES. PROVIDE VENTILATION. WEAR
RESPIRATORY PROTECTION WHILE ABSORBING ON SAND/OTHER INERT ABSORBENT.
Waste Disposal Methods: PLACE ABSORBED MATERIAL IN CONTAINER, SEAL & LABEL,
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN COOL, DRY, VENTILATED AREA.
Other Precautions: DON'T WEAR CONTACT LENSES WHILE HANDLING CHEMICALS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: -0.4F
Lower Limits: 2.6%
Upper Limits: 12.8%
Extinguishing Media: CO2, ALCOHOL FOAM, DRY CHEMICAL.
Fire Fighting Procedures: MOVE CONTAINERS FROM FIRE IF POSSIBLE. COOL
CONTAINERS W/WATER SPRAY. AVOID BREATHING VAPORS.
Unusual Fire/Explosion Hazard: DANGEROUS WHEN EXPOSED TO HEAT/FLAME. VAPORS ARE
> THAN AIR & MAY FLASH BACK FROM A CONSIDERABLE DISTANCE. VAPOR-AIR
MIXTURES ARE EXPLOSIVE > FLASH POINT. (SUPP
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR RESPIRATOR W/ORGANIC VAPOR CANISTER.
Ventilation: EXPLOSION-PROOF LOCAL EXHAUST.
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE
REUSE.
Supplemental Safety and Health: EVAPORATION RATE: (CARBON TETRACHLORIDE = 1):
0.8. FIRE HZRD CONT'D: AUTOIGNITION TEMP: 869F.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 133.16F
M.P/F.P Text: -137.74F
Vapor Pres: 181
Vapor Density: 2
Spec Gravity: 0.792
Evaporation Rate & Reference: (SEE SUPP)
Solubility in Water: COMPLETE
Appearance and Odor: TRANSPARENT LIQUID W/PINKISH TINT; ACETONE ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: IGNITION SOURCES.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: 12005 REPLICATING SOLUTION
Cage: LADDR
Company Name: LADD RESEARCH INDUSTRIES INC
PO Box: 1005
Zipcode: 05402-1005
Label Required IND: Y
Date Of Label Review: 12/16/1998
Status Code: C
Label Date: 12/16/1998
Origination Code: G
Hazard And Precautions: SKIN/EYE: IRRITATION. INHALATION: NASAL/THROAT
IRRITATION/LARYNGITIS/BRONCHITIS/COUGHING/RHINORRHEA/CNS
EFFECTS/HEADACHE/DIZZINESS/DROWSINESS/WEAKNESS/CONFUSION/NAUSEA/GENERAL
INTOXICATION/INCOORDINAT ION/COMA. INGESTION: SORE
THROAT/HEADACHE/DIZZINESS/DROWSINESS/RESTLESSNESS/GASTRITIS/NAUSEA/VOMITING
HEMATEMESIS. SKIN: ABSORPTION. EYE: CONJUNCTIVITIS/CORNEAL EROSION.
INHALATION: BREATHING DIF
FICULTY/LARYNGITIS/BRONCHITIS/COUGHING/RHINORRHEA/CNS
EFFECTS/HEADACHE/DIZZINESS/DROWSINESS/WEAKNESS/CONFUSION/NAUSEA/GENERAL
INTOXICATION/INCOORDINATION/COMA. INGESTION: STUPOR/TWITCHING/COLLAPSE/UNC
ONSCIOUSNESS/CONVULSIONS/PARALYSIS.
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:AVIATION TURBINE FUEL,GRADE JP-8
CAGE:1Y204
CAGE:1Y204
============= Composition/Information on Ingredients =============
Ingred Name:AROMATICS
Fraction by Wt: 15% VOL
Other REC Limits:NONE SPECIFIED
Ingred Name:OLEFINS
Fraction by Wt: <1% VOL
Other REC Limits:NONE SPECIFIED
Ingred Name:ANTI STATIC ADDITIVE
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: VAPORS, MISTS, LIQUID CONTACT
MAY CAUSE IRRITATION. SKIN: PROLONGED CONTACT MAY CAUSE IRRITATION
AND DERMATITIS. INHALATION: MAY CAUSE MUCOUS MEMBRANE IRRITATION OF
RESPIRATORY TRACT AND MAY CAU SE HEADACHE AND DROWSINESS.
ASPIRATION OF MATERIAL INTO LUNGS CAN CAUSE CHEMICAL PNEUMONITIS
WHICH CAN BE FATAL.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION, DERMATITIS.
INHALATION: MUCOUS MEMBRANE IRRITATION OF RESPIRATORY TRACT,
HEADACHE, DROWSINESS.
Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING DISEASE
INVOLVING EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED RISK
FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED
CLOTHING. WASH AREA WITH SOAP AND WATER. INHALATION: MOVE TO FRESH
AIR. RESTORE BREATH ING AS REQUIRED. GET MEDICAL
ATTENTION.INGESTION: DO NOT INDUCE VOMITING. GIVE 2-4 OZ VEGETABLE
OR OLIVE OIL AND 1-2 OZ ACTIVATED CHARCOAL. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:113F,45C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER SPRAY.
Fire Fighting Procedures:USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS, STRUCTURES, AND PROTECT PERSONNEL. USE FOAM TO BLANKET
LIQUID. USE AIR-SUPPLIED RESPIRATOR EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS MAY FORM EXPLOSIVE MIXTURES WITH
AIR. VAPORS HEAVIER THAN AIR AND MAY TRAVEL CONSIDERABLE DISTANCE
TO SOURCE OF IGNITION AND FLASH BACK.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR RESPIRATORY PROTECTION. STOP FLOW.
ELIMINATE SOURCES OF IGNITION. CONTAIN SPILL BY DIKING WITH INERT
MATERIAL. RECOVER LIQUID. ABSORB RESIDUE WITH CLAY, VERMICULITE, OR
SIMILAR ABSORBENT MATERIAL . PLACE WASTE IN CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA
AWAY FROM SOURCES OF IGNITION AND STRONG OXIDANTS. KEEP CONTAINERS
CLOSED.PROTECT CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:REMOVE OIL-SOAKED CLOTHING PROMPTLY. IF MATERIAL IS
ACCIDENTALLY RELEASED IN A CONFINED AREA, PROVIDE ADEQUATE
VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. AIR-SUPPLIED
OR FILTERING TYPE WITH ORGANIC VAPOR CARTRIDGES ARE RECOMMENDED.
Ventilation:EXPLOSION-PROOF MECHANICAL VENTILATION RECOMMENDED.
Other Protective Equipment:AN EYEWASH STATION AND SAFETY SHOWER SHOULD
BE AVAILABLE.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:356F,180C
Spec Gravity:0.79-0.82
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BRIGHT AND CLEAR LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, FLAMES, IGNITION SOURCES.
Hazardous Decomposition Products:THERMAL DEGRADATION MAY YIELD VARIOUS
HYDROCARBONS AND THEIR DERIATIVES, CARBON DIOXIDE, CARBON
MONOXIDE,SULFUR DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE MATERIAL IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:B509TB ALKYD SG ODORLESS GREEN 24672
Preparer's Name:PATRICIA SHAW
CAGE:3Z268
CAGE:3Z268
============= Composition/Information on Ingredients =============
Ingred Name:HYDROCARBON MIXTURE (VAPOR PRESSURE 2.0 MM HG @ 68F)
CAS:64741-41-9
Fraction by Wt: 20%
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:SILICA, QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 0.26%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:PETROLEUM HYDROCARBON (VAPOR PRESSURE 50.0 HG MM @ 0 F)
CAS:8008-20-6
RTECS #:OA5500000
Fraction by Wt: 5%
Other REC Limits:100 PPM
OSHA PEL:500 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY IRRIT, CENTRAL
NERVOUS SYS DEPRESSION. SKIN/EYE: PROLONG/REPEAT EXPOSURE--MODERATE
IRRIT, DEFATTING & DERMATITIS. INGEST: DIGESTIVE TRACT IRRIT, LUNG
INFLAMMATION. CAUSES DAMAG ES TO CENTRAL NERVOUS SYSTEM,
RESPIRATORY SYSTEM, LUNGS, EYES, SKIN, GASTROINTESTINAL TRACT,
LIVER, SPLEEN AND KIDNEYS.
Explanation of Carcinogenicity:CRYSTALLINE SILICA IS LISTED (IARC)
CARCINOGEN. ACGIH ASSIGNED TLV'S TO MATERIAL. SEE INGREDS FOR TLV.
Effects of Overexposure:INHALATION: NASAL/RESPIRATORY IRRITATION,
DIZZINESS, WEAKNESS, FATIGUE, NAUSEA AND HEADACHE. EYE: IRRITATION,
TEARING, REDNESS, & BLURRED VISION. SKIN: MODERATE IRRITATION.
INGESTION: ASPIRATION HAZAR D; THIS MATERIAL CAN ENTER THE LUNGS
DURING SWALLOWING OR VOMITING AND CAUSE LUNG INFLAMMATION.
Medical Cond Aggravated by Exposure:RESPIRATORY TRACT IRRITATION,
DERMATITIS, NAUSEA.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/WATER--15 MIN, OCCASIONALLY LIFTING EYELIDS.
OBTAIN MED ATTN. SKIN: REMOVE CONTAM CLOTHING. WASH W/SOAP & WATER.
IF IRRIT PERSISTS, SEE DOCTOR. INHAL: REMOVE TO FRESH AIR. APPLY
ARTIFICIA L RESP OR ADMIN OXYGEN. CONSULT A DR. INGEST: GIVE
UNLESS MEDICAL PERSONNEL ADVISES. MED ADVICE UNAVAILABLE, TAKE TO
EMERG HOSPITAL.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:104F,40C
Lower Limits:0.7%
Upper Limits:6.1%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE EXTINGUISHERS (NFPA FLAMMABLE LIQUID
FIRE). WATER MAY BE INEFFECTIVE, USE AS FOG FOR COOLING. WEAR FULL
PROTECT CLOTH/BREATH APP IF EXPOS TO COMBUST PROD.
Unusual Fire/Explosion Hazard:VAPORS FORM EXPLOSIVE MIX WHICH CAN BE
IGNITED FROM MANY SOURCES. CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. ISOLATE FORM IGNITION SOURCES.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE NON-ESSENTIAL PERSONEL. REMOVE ALL
IGNITION SOURCES. VENTILATE THE AREA. PROVIDE APPROPRIATE
PROTECTIVE EQUIPMENT. DIKE AROUND THE SPILL AREA. COVER SPILL WITH
INERT ABSORBANT AND TRANSFER US ING NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BELOW 80 F IN A CLOSED
CONTAINER. STORE IN ORIGINAL CONAINER. AVOID FLAME & HIGH
TEMPERATURES. DON'T STORE NEAR OXIDIZING AGENTS OR ACIDS.
Other Precautions:VAPOR HEAVIER THAN AIR & MAY TRAVEL DISTANCE TO IGNIT
SOURCES & FLASHBACK. DON'T EAT. NO PROLONG/REPEAT INHAL OF HEATED
VAPORS/ SPRAY MISTS. KEEP FROM HEAT. GROUND ALL CONNECTIONS,
CNTNRS, ETC (POURIN G/ TRANSFERING). USE NON-SPARKING TOOLS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED EQUIPMENT WHEN AIRBORN
EXPOSURE LIMITS ARE EXCEEDED. CONSULT RESPIRATOR MFR TO DETERMINE
APPROPRIATE EQUIPMENT FOR GIVEN APPLICATION. HIGH AIRBORN
CONCENTRATIONS MAY REQUIRE TH E USE OF A SUPPLIED-AIR
RESPIRATOR/SCBA.
Ventilation:PROVIDE SUFFICIENT VENTILATION TO CONTROL EXPOSURE LEVELS
BELOW AIRBORN TLVS. VENT EQUIPMENT MUST BE EXPLOSION PROOF.
Other Protective Equipment:WEAR IMPERMEABLE APRONS AND PROTECTIVE
CLOTHING WHENEVER POSSIBLE TO PREVENT REPEATED OR EXTENDED EXPOSURE
OF SKIN.
Work Hygienic Practices:AFTER USING, WASH BEFORE EATING, TOILETING OR
SMOKING.
Supplemental Safety and Health
THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER OR REPRODUCTIVE HARM. THE USE OF HEAD CAPS WHENEVER
POSSIBLE IS STRONGLY RECOMMENDED.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:315 TO 335F
Vapor Density:> AIR
Spec Gravity:1.4 (WATER=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT SOLUBLE
Appearance and Odor:PIGMENTED LIQUID. SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:DO NOT EXPOSE TO HEAT OR IGNITION SOURCES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON
DIOXIDE AND/OR MONOXIDE, LOW MOLECULAR WEIGHT HYDROCARBONS AND
ORGANIC ACIDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP OUT OF DRAINS, SEWERS, AND WATERWAYS.
DISPOSE OF PRODUCT IN ACCORDANCE WITH FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:PYRENE, 99%, 18551-5
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:PYRENE (SARA III)
CAS:129-00-0
RTECS #:UR2450000
Fraction by Wt: 99%
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE SUPP DATA
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED. MAY BE
HARMFUL IF INHALED. MAY CAUSE EYE OR SKIN IRRITATION. INHALATION
STUDIES IN ANIMALS HAVE CAUSED HEPATIC, PULMONARY & INTRAGASTRIC
PATHOLOGIC CHANGES. NEUTROPHIL, LE UKOCYTE & ERYTHROCYTE LEVELS
DECREASED.CUTANEOUS APPLICATION CAUSED HYPEREMIA, WEIGHT LOSS AND
(SEE EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: HEMATOPOIETIC CHANGES AND DERMATITIS.
PYRENE IS READILY ABSORBED THROUGH THE SKIN . CHRONIC:
LEUKOCYTOSIS. DERMATITIS . TARGET ORGANS: LIVER, KIDNEY, LUNG, SKIN
AND BLOOD SYSTEM .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS
AMOUNTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING,
GIVE ARTIFIC IAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. CALL MD. WASH CONTAMINATED CLOTHING BEFORE REUSE.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY. CO*2, DRY CHEMICAL POWDER, ALCOHOL OR
POLYMER FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS
WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE AREA AND WASH SPILL
SITE AFTER MATERIAL PICKUPIS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL,
DRY PLACE.
Other Precautions:AVOID INHALATION. DO NOT GET IN EYES, ON SKIN OR
CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. HARMFUL VAPOR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:RUBBER BOOTS, SAFETY SHOWER AND EYE BATH
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE
EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES .
Supplemental Safety and Health
LD50-LC50 MIX: LD50: (ORL/RAT)=2700 MG/KG, (ORL/MUS)=800 MG/KG,
(IPR/MUS)=514 MG/KG.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:739F,393C
Melt/Freeze Pt:M.P/F.P Text:300F,149C
Vapor Pres:VERY LOW
Spec Gravity:1.271
Solubility in Water:INSOLUBLE
Appearance and Odor:YELLOW CRYSTALS AND POWDER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF: CO, CO*2
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. DISPOSE I/A/W FEDERAL, STATE AND LOCAL
LAWS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:INK REMOVER 100 FOR F-100 MARKING INK
CAGE:01195
CAGE:01195
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: 45%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
===================== Hazards Identification =====================
Effects of Overexposure:INHAL: MINOR IRRIT. SKIN/EYE: MINOR IRRIT.
INEBRIATION.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. SKIN: WASH W/ WATER. EYE: FLUSH
W/ WATER FOR 15 MIN. INGEST: INDUCE VOMIT.
===================== Fire Fighting Measures =====================
Flash Point:>80F;27C; TOC
Lower Limits:2
Upper Limits:7
Extinguishing Media:CO*2,DRY CHEM FOR SMALL FIRES,ALCOHOL FOAM FOR
LARGE FIRES
Fire Fighting Procedures:DILUTION OF BURNING LIQ W/ WATER REDUCES FLAME
INTENSITY
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:WASH AWAY SPILLED MATERIAL W/ WATER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPRVD AIR-SUPPLIED MASK IN CONFINED
AREAS (MFR)
Ventilation:GENERAL-ACCEPTABLE TO KEEP BELOW TLV.
Other Protective Equipment:SAFETY SHOWER & EYE BATH
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>172F;78C
Vapor Pres:<42
Vapor Density:>2
Spec Gravity:0.806
Evaporation Rate & Reference:<8.14 (BUAC=1)
Appearance and Odor:WATER-WHITE LIQUID,MILD NONRESIDUAL ODOR
Percent Volatiles by Volume:50
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:HEAT,SPARKS,FIRES
Hazardous Decomposition Products:THERMAL DECOMP MAY PRODUCE CO &/OR
CO*2.
==================== Disposal Considerations ====================
Waste Disposal Methods:MFR RECOMMENDS INCINERATION IN FURNACE. DISPOSAL
METHOD MUST BE IAW FED, STATE & LOCAL CODES.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:LEAD/ACID STORAGE BATTERY
CAGE:0W3X1
CAGE:0W3X1
============= Composition/Information on Ingredients =============
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: > 60%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1025
ACGIH TLV:0.15 MG/M3,DUST;9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ANTIMONY (SARA III)
CAS:7440-36-0
RTECS #:CC4025000
Fraction by Wt: 10% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG (SB)/M3; 9394
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ARSENIC (SARA III)
CAS:7440-38-2
RTECS #:CG0525000
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1018
ACGIH TLV:0.01 MG/M3, A1; 9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:NONHAZARDOUS PLASTIC BATTERY CASE
Fraction by Wt: 5% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1018
ACGIH TLV:0.01 MG/M3, A1; 9394
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 10-30% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT GIVEN
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:BATTERY ELECTROLYTE IS CORROSIVE TO
SKIN. NO POSSIBLITY OF OVEREXPOSURE TO LEAD, ETC. UNLESS BATTERY IS
DESTROYED. SULFURIC ACID MIST CAUSES COUGHING AND WILL BURN EYES
AND SKIN.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:BURNS/IRRITATION TO SKIN, EYES, NOSE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEE
PHYDSICIAN. SKIN: FLUSH WITH WATER.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:4 % (H2)
Upper Limits:74.2 % (H2)
Extinguishing Media:HALOGEN TYPE OF DRY CHEMICAL
Fire Fighting Procedures:PROMPT EVACUATION AND/OR RESCUE OF TRAPPED
PERSONNEL IS NEEDED. CONSULT NATIONAL FIRE CODE 1980 VOL 1
Unusual Fire/Explosion Hazard:WILL GENERATE HYDROGEN AND SULFURIC ACID
MIST WHEN OVERCHARGED.
================== Accidental Release Measures ==================
Spill Release Procedures:WASH WITH WATER OR NEUTRALIZE WITH SODIUM
CARBONATE OR BICARBONATE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM FLAMES DURING AND
IMMEDIATELY AFTER SHORTS. DO NOT SHORT BATTERY WITH TOOLS, ETC.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SULFURIC ACID MIST, HALF MASK WITH DUST
Ventilation:CHANGE AIR IN ROOMS 3-4 TIMES PER HOUR.
Other Protective Equipment:RUBBER APRON, EMERGENCY EYEWASH, SHOWER
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
AVOID PROLONGED OVERCHARGE IN CONFINED SPACE.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NOT GIVEN
Appearance and Odor:BATTERY CELL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:PROLONGED OVERCHARGING IN CONFINED SPACES.
Hazardous Decomposition Products:HYDROGEN, ARSINE AND/OR STIBINE
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
=======================================================
NIIN: 01-411-8815
Product ID: 060-55, POSITRON ULTRA HIGH PURITY DIELECTRIC SOLVENT
Cage: 0WU71
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 0WU71
Contract Number: SP0450-01-M-ZH41
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: CLEANING COMPOUND,SOLVENT
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: BX
Quantitative Expression: 00000000004EA
UI Container Qty: 1
Type of Container: JUG (MSDS)
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NO DATA PROVIDED BY MANUFACTURER
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INGESTION: SWALLOWING LARGE AMOUNTS MAY BE HARMFUL BY
CAUSING GASTROINTESTINAL IRRITATION. INHALATION: BREATHING LARGE AMOUNTS MAY
BE HARMFUL BY CAUSING NOSE, THROAT, AND RESPIRATORY TRACT IRRITATION. EYES:
IRRITANT. LIQUID CONTACT WILL IRRITATE EYES AND MAY CAUSE STINGING, TEARING,
AND REDNESS. SKIN OR CONTACT: MAY CAUSE MILD IRRITATION OR REDNESS AND
BURNING.
Explanation Of Carcinogenicity: NTP-NOT LISTED. IARC MONOGRAPHS-NONE. OSHA
REGS-NOT REGULATED
Signs And Symptions Of Overexposure: INGESTION: SWALLOWING LARGE AMOUNTS MAY BE
HARMFUL BY CAUSING GASTROINTESTINAL IRRITATION. INHALATION: BREATHING LARGE
AMOUNTS MAY BE HARMFUL BY CAUSING NOSE, THROAT, AND RESPIRATORY TRACT
IRRITATION. EYES: IRRITANT. LIQUID CONTACT WILL IRRITATE EYES AND MAY CAUSE
STINGING, TEARING, AND REDNESS. SKIN OR CONTACT: MAY CAUSE MILD IRRITATION OR
REDNESS AND BURNING.
Medical Cond Aggravated By Exposure: NO DATA PROVIDED BY MANUFACTURER
First Aid: INGESTION: SEEK MEDICAL ATTENTION IMMEDIATELY. IF INDIVIDUAL IS
DROWSY OR UNCONSCIOUS, DO NOT GIVE ANYTHING BY MOUTH; PLACE INDIVIDUAL ON
LEFT SIDE WITH HEAD DOWN. CONTACT MEDICAL FACILITY OR POISON C ONTROL CENTER
FOR ADVICE ON WHETHER TO INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. KEEP PERSON WARM AND QUIET. SEEK MEDICAL
ATTENTION. EYES: IRRIGATE IMME DIATELY WITH WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: WASH WITH SOAP AND WATER.
THOROUGHLY CLEAN CONTAMINATED CLOTHES AND SHOES BEFORE REUSE. IF SYMPTOMS
PERS IST, SEEK MEDICAL ATTENTION.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SMALL SPILL: ABSORB LIQUID ON VERMICULITE, FLOOR
ABSORBENT, OR OTHER ABSORBENT MATERIAL & TRANSFER TO HOOD. LARGE SPILL:
ELIMINATE ALL IGNITION SOURCES, (FLARES, FLAMES INCLUDING PILOT LIGHTS,
ELECTRI CAL SPARKS). PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE
EXCLUDED FROM AREA OF SPILL UNTIL CLEANUP HAS BEEN COMPLETED. STOP SPILL AT
SOURCE. PREVENT FROM ENTERING DRAINS, SEWERS, STREAMS, ETC.
Neutralizing Agent: NO DATA PROVIDED BY MANUFACTURER
Waste Disposal Methods: POSITRON LIQUID IS NOT CONSIDERED A RCRA REGULATED
SUBSTANCE. SOILS REMOVED DURING CLEANING MAY AFFECT THE HAZARD CLASSIFICATION
OF YOUR WASTE STREAM. IF YOUR WASTE STREAM REMAINS NON-HAZARDOUS (YOU N EED
TO CHECK), THE WASTE MAY BE DISPOSED OF LIKE USED OIL (IN MOST STATES).
PLEASE CALL US IF YOU NE ED ADDITIONAL DISPOSAL INFORMATION.
Handling And Storage Precautions: SINCE EMPTY CONTAINERS CONTAIN PRODUCT
RESIDUES, ALL HAZARD PRECAUTIONS GIVEN IN THE MATERIAL SAFETY DATA SHEET MUST
BE OBSERVED. ALL METAL PAILS OR DRUMS SHOULD BE GROUNDED AND/OR BONDED WHEN
MATERIA L IS TRANSFERRED. KEEP THIS & ALL CHEMCALS OUT OF THE REACH OF
CHILDREN.
Other Precautions: ANY USE OF THIS PRODUCT IN ELEVATED TEMPERATURE PROCESSES
SHOULD BE THOROUGHLY EVALUATED TO ESTABLISH & MAINTAIN SAFE OPERATING
CONDITIONS. SUDDEN RELEASE OF HOT ORGANIC CHEMICAL VAPORS OR MISTS FROM
PROCESS EQUIPMENT OPERATING AT ELEVATED TEMPERATURES MAY RESULT IN IGNITION.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point: =61.1C, 142.F
Lower Limits: 0.7%
Upper Limits: 7.0%
Extinguishing Media: REGULAR FOAM, WATER FOG, CARBON DIOXIDE, DRY CHEMICAL,
CLASS B.
Fire Fighting Procedures: KEEP FIRE EXPOSED CONTAINERS COOL WITH WATER. FIRE
FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL-FACE
PIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WITH APPROPRIATE GEAR AN
D CHEMICAL RESISTANT PERSONAL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard: VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG
THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY HEAT, PILOTS LIGHTS,
OTHER FLAMES AND IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL HANDLING
POINT. NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN EMPTY)
BECAUSE PRODUCT CAN IGNITE EXPLOSIVELY.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NOT REQUIRED UNDER CONDITIONS OF NORMAL USE. IF VAPOR
MIST IS PRESENT, USE NIOSH CERTIFIED ORGANIC VAPOR MASK.
Ventilation: LOCAL EXHAUST/HOOD OR FAN MAY BE USED.
IMMERSION OF HANDS.
CONTACT. NO OTHER PROTECTIVE CLOTHING REQUIRED UNDER NORMAL USE.
Work Hygienic Practices: STORE RAGS USED WITH THIS MATERIAL IN AN AIRTIGHT,
METAL CONTAINER TO PREVENT SPONTANEOUS COMBUSTION. TREAT THIS CHEMICAL WITH
RESPECT AND FOLLOW ALL MSDS INSTRUCTIONS.
Supplemental Safety and Health: NO DATA PROVIDED BY MANUFACTURER
=======================================================
Physical/Chemical Properties
=======================================================
HCC: F4
Boiling Point: =175.6C, 348.F
B.P. Text: @ 760 MMHG
Vapor Pres: .5028 MMHG @20C
Vapor Density: 5.0
Spec Gravity: 0.807
Solubility in Water: NON-MISCIBLE
Appearance and Odor: COLORLESS LIQUID WITH MILD TERPENE ODOR
Percent Volatiles by Volume: 100%
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: SOURCES OF IGNITION SUCH AS SPARKS, HOT SPOTS,
WELDING, FLAMES AND CIGARETTES. IGNITION/FLASH MAY RESULT IF CONCENTRATION OF
PRODUCT IS IN THE FLAMMABLE RANGE.
Materials To Avoid: IF MIXED WITH STRONG OXIDIZING AGENTS AND/OR ACIDS THERE IS
THE POSSIBILITY OF A DANGEROUS CHEMICAL REACTION.
Hazardous Decomposition Products: MAY FORM CARBON DIOXIDE AND CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: NO DATA PROVIDED BY MANUFACTURER
=======================================================
Ecological Information
=======================================================
Ecological: NO DATA PROVIDED BY MANUFACTURER
=======================================================
=======================================================
Transport Information: NO DATA PROVIDED BY MANUFACTURER
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: NO DATA PROVIDED BY MANUFACTURER
Federal Regulatory Information: NO DATA PROVIDED BY MANUFACTURER
State Regulatory Information: NO DATA PROVIDED BY MANUFACTURER
=======================================================
Other Information
=======================================================
Other Information: NO DATA PROVIDED BY MANUFACTURER
=======================================================
Transportation Information
=======================================================
Trans ID NO: 159063
Product ID: 060-55, POSITRON ULTRA HIGH PURITY DIELECTRIC SOLVENT
Review Date: 09/27/2001
Net Unit Weight: 7.3 LBS/GL
Multiple KIT Number: 0
Unit Of Issue: BX
Container QTY: 1
Type Of Container: JUG (MSDS)
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: 060-55, POSITRON ULTRA HIGH PURITY DIELECTRIC SOLVENT
Cage: 0WU71
Company Name: ECOLINK INC
Street: 1481 ROCK MOUNTAIN BLVD
Zipcode: 30083-1505
Label Required IND: Y
Date Of Label Review: 09/27/2001
Status Code: A
Origination Code: F
Signal Word: NONE
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: INGESTION: SWALLOWING LARGE AMOUNTS MAY BE HARMFUL BY
CAUSING GASTROINTESTINAL IRRITATION. INHALATION: BREATHING LARGE AMOUNTS MAY
BE HARMFUL BY CAUSING NOSE, THROAT, AND RESPIRATORY TRACT IRRITATION. EYES:
IRRITANT. LIQUID CONTACT WILL IRRITATE EYES AND MAY CAUSE STINGING, TEARING,
AND REDNESS. SKIN OR CONTACT: MAY CAUSE MILD IRRITATION OR REDNESS AND
BURNING.
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:6-20 SPEEDHIDE WOOD FINISH EXT WHITE/PASTEL
CAGE:EO471
CAGE:EO471
============= Composition/Information on Ingredients =============
Ingred Name:ALUMINUM SILICATE *92-4*
CAS:1335-30-4
Fraction by Wt: 5-10%
Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES
MINERAL SPIRITS *92/4*
CAS:64742-88-7
Fraction by Wt: 20-25%
Other REC Limits:100 PPM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:ISOPARAFFINIC HYDROCARBONS (NAPHTHA PETROLEUM),
HYDROTREATED HEAVY, NON AROMATIC HEAVY NAPHTHA) ISOPAR G *92/4*
CAS:64742-48-9
Fraction by Wt: 5-10%
Ingred Name:FILM FORMERS, RESINS, & ADDITIVES
Fraction by Wt: 30-35%
Ingred Name:WEIGHT PER GALLON IN POUNDS: 10.69
RTECS #:9999999WG
Ingred Name:FOLPET, N-(TRICHLOROMETHYTHIO)PHTHALATE
N-(TRICHLOROMETHYL) THIOPHTHALIMIDE
CAS:133-07-3
RTECS #:TI5685000
Fraction by Wt: 1-2%
Ingred Name:TITANIUM DIOXIDE, TIO2
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 15-20%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 10-15%
OSHA PEL:15 MG/CUM (DUST)
ACGIH TLV:10 MG/CUM (DUST)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: HEADACHE, NAUSEA,
DIZZINESS, LOSS OF COORDINATION, RESPIRATORY SYSTEM IRRITATION, &
HARMFUL. EYES: WATERING, REDNESS, ITCHING, BURNING SENSATION, &
VISUAL DISTURBANCES. SKIN: IRRITATION, D RYNESS, ITCHING, CRACKING,
BURNING, REDNESS & SWELLING. INGESTION: HARMFUL OR FATAL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: PERMANENT BRAIN & NERVOUS SYSTEM
DAMAGE.
======================= First Aid Measures =======================
First Aid:INGESTION: DON'T INDUCE VOMITING. EYES: FLUSH W/PLENTY OF
WATER FOR AT LEAST 15 MINS. SKIN: FLUSH W/PLENTY OF WATER & WAS
W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. APPLY ARTIFICIAL
RESPIRATION & OTHER SUPPORTIVE MEASURES AS REQUIRED. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:113F
Lower Limits:0.9%
Extinguishing Media:CO2, DRY CHEMICAL, OR UNIVERSAL AQUEOUS FILM
FORMING FOAM
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. WEAR
SELF-CONTAINED BREATHING APPARATUS. USE WATER SPRAY TO COOL CLOSED
CONTAINERS, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:COOL CLOSED CONTAINER TO PREVENT PRESSURE
BUILD-UP & POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT. COMBUSTIBLE LIQUID. UN1263.
================== Accidental Release Measures ==================
Spill Release Procedures:PROVIDE MAXIMUM VENTILATION. WEAR PROPER
PROTECTIVE EQUIPMENT. REMOVE ALL SOURCES OF IGNITION. TAKE UP
SPILLED MATERIAL W/SAWDUST, VERMICULITE, OR OTHER ABSORBENT
MATERIAL & PLACE INTO CONTAINERS FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE ABOVE 120F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA
CLASS II COMBUSTIBLE MATERIALS.
Other Precautions:AVOID FREE FALL OF LIQUIDS IN EXCESS OF A FEW INCHES.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS CAN BE HARMFUL OR FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA (TC-23C) OR AIR SUPPLIED (TC-19C)
RESPIRATORS TO REDUCE EXPOSURE. ENSURE VENTILATION CONTROLS.
Ventilation:GENERAL DILUTION OR LOCAL EXHAUST IN VOLUME & PATTERN TO
KEEP CONCENTRATION LIMITS BELOW LEL
Other Protective Equipment:FULL FACE SHIELD, NITRILE RUBBER/BUTYL
Work Hygienic Practices:CLEAN OR DISCARD CONTAMINATED CLOTHING & SHOES
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:136-242C
Vapor Pres:1.8
Vapor Density:>1
Spec Gravity:1.28
Evaporation Rate & Reference:(BU AC = 1):12
Solubility in Water:INSOLUBLE
Appearance and Odor:VISCOUS LIQUID W/SOLVENT CHARACTERISTIC ODOR
Percent Volatiles by Volume:44.90%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, STRONG MINERAL ACIDS, OR STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN
FLAMES, HOT SURFACES, & OTHER IGNITION SOURCES
Hazardous Decomposition Products:CO, HYDROGEN CHLORIDE, CHLORINATED
PRODUCTS
==================== Disposal Considerations ====================
Waste Disposal Methods:EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED
OF THROUGH AN APPROVED WASTE MANAGEMENT FACILITY IN ACCORDANCE
W/FEDERAL, STATE, & LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:CALCIUM CARBONATE
CAGE:62910
CAGE:62910
============= Composition/Information on Ingredients =============
Ingred Name:CALCIUM CARBONATE
CAS:471-34-1
RTECS #:FF9335000
Fraction by Wt: >99%
Other REC Limits:NONE SPECIFIED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:NO INFORMATION FOUND
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: NASAL IRRITATION. CHRONIC:
ALKALOSIS.
Effects of Overexposure:EYES: IRRITATION. SKIN: NOT EXPECTED TO BE A
HAZARD. INHALATION: COUGHING, SNEEZING AND NASAL IRRITATION.
INGESTION: NON-TOXIC.
Medical Cond Aggravated by Exposure:NO INFORMATION FOUND.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH PLENTY OF WATER. IF IRRITATION PERSISTS, SEE
DOCTOR. SKIN: WASH WITH SOAP AND WATER.IF IRRITATION PERSISTS SEE
DOCTOR. INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION.
INGESTIO N: IF LARGE AMOUNT SWALLOWED DRINK LARGE AMOUNT OF WATER,
SEE DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN-UP PERSONNEL REQUIRE PROTECTIVE CLOTHING
& RESPIRATORY PROTECTION FROM DUST. COLLECT BY SWEEPING, MOPPING OR
WET VACUUMING AS APPROPRIATE. COLLECTED WASTE MAY BE TRANSFERRED TO
A CLOSED METAL CO NTAINER. AVOID DUSTING CONDITIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTAINERS AT
COOL, DRY, VENTILATED PLACE. PROTECT AGAINST PHYSICAL DAMAGE.
Other Precautions:AVOID PROLONGED EXPOSURE TO DUST. PRACTICE GOOD
INDUSTRIAL AND PERSONAL HYGIENE AND SFETY PROCEDURES BY AVOIDING
ALL UNNECESSARY EXPOSURE TO CHEMICAL SUBSTANCES. ENSURE PROMPT
REMOVAL FROM SKIN, EYES AND CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. USE NIOSH/MSHA-APPROVED
RESPIRATOR WITH DUST CARTRIDGE IF TLV IS EXCEEDED.
Ventilation:LOCAL AND/OR GENERAL EXHAUST TO MAINTAIN EXPOSURE LEVEL
BELOW TLV.
Other Protective Equipment:EMERGENCY EYE LAVAGE AND SHOWER. LAB COAT,
APRON OR COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. AVOID
GENERATING DUST. CONTACT LENSES SHOULD NOT BE WORN.
Supplemental Safety and Health
NONE.
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:825C DECOMP
Decomp Temp:Decomp Text:1517F,825C
Spec Gravity:2.7-2.95
Solubility in Water:NEGLIGIBLE
Appearance and Odor:FINE WHITE POWDER, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, FLOURINE, MAGNESIUM WITH HYDROGEN
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CALCIUM OXIDE FUMES AND CARBON DIOXIDE
WHEN HEATED TO DECOMPOSITION.
==================== Disposal Considerations ====================
Waste Disposal Methods:COLLECTED WASTE MAY BE TRANSFERRED TO A CLOSED,
PREFERABLY METAL, CONTAINER AND SENT TO A RCRA-APPROVED WASTE
DISPOSAL FACILITY. ENSURE COMPLIANCE WITH LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:CESIUM IODIDE, 210799
Preparer's Name:R.L.
CAGE:IO030
CAGE:30060
CAGE:IO030
============= Composition/Information on Ingredients =============
Ingred Name:CESIUM IODIDE
CAS:7789-17-5
RTECS #:FL0350000
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 2386 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MODERATELY TOXIC BY INGESTION &
INTRAPERITONEAL ROUTES. MODERATE TO SEVERE ERYTHEMA (REDNESS) &
MODERATE EDEMA (RAISED SKIN).
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:REMOVE CONTAM CLTHG, RINSE LIBERALLY W/SOAP & WATER FOR
A CONSIDERABLE PERIOD. CALL MD. INGEST:RINSE MOUTH SEVERAL TIMES
W/WATER, DO NOT SWALLOW. CALL MD OR TAKE PATIENT TO A HOSPITAL.
EYES:RINSELIBERALLY W/WATER FOR AT LEAST 15 MINUTES. CALL MD OR
TAKE PATIENT TO A HOSPITAL. INHAL:TAKE PATIENT INTO FRESH AIR &
ALLOW TO RES. CALL MD OR TAKE PATIENT TO A HOSPITAL.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP INTO SUITABLE CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE: ROOM TEMPERATURE.
USE A HOOD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST REQUIRED. ALWAYS USE A HOOD.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:2336F,1280C
Melt/Freeze Pt:M.P/F.P Text:1150F,621C
Spec Gravity:4.51
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE CRYSTALLINE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF I-.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR LANDFILL AS COMPLIES W/FEDERAL,
STATE & LOCAL LAWS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:EPO-LUX E-20 PRIMER PTA, A07160100A
Kit Part:Y
Preparer's Name:BARBARA STELLER
CAGE:DO668
CAGE:93981
CAGE:DO668
============= Composition/Information on Ingredients =============
Ingred Name:XYLENE (SARA 313) (CERCLA). VP:9 @ 77F. LD50:(ORAL,RAT)
4300 MG/KG.
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 79%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ETHANOL, 2-ETHOXY-; (ETHYL GLYCOL MONOETHYL ETHER)(SARA
313) (CERCLA). VP:3.8 @ 68F.
CAS:110-80-5
RTECS #:KK8050000
Fraction by Wt: 10%
OSHA PEL:200 PPM, S
ACGIH TLV:5 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:BENZENE, TRIMETHYL- (MIXED ISOMERS); (TRIMETHYLBENZENE)
(MFR'S CAS NO:2551-13-7)
CAS:25551-13-7
RTECS #:DC3220000
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC COMPOUNDS (COATING): 3.64 LB/GAL (437
G/L).
RTECS #:9999999VO
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:NASAL & RESP IRRIT, DIZZ,
WEAK, FATG, NAUS, HDCH, POSS UNCON & EVEN DEATH. SKIN CONT:MOD
IRRIT. EYE CONT:SEVERELY IRRIT. MAY CAUSE REDNESS, TEARING/BLURRED
VISION. SKIN ABSORPTION:SAME AS INHAL. INGEST:MAY CAUSE GI
IRRIT/ULCERATION BURNS OF MOUTH & THROAT. PULM ASPIR HAZ-MAY LEAD
TO PNEUM- (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:WHICH CAN BE FATAL. CHRONIC:NOTE:ETHYL
GLYCOL MONOETHYL ETHER APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO
HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING
LATEST HAZ LIST IN FO & SAFE HANDLING & EXPOS INFO .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IF BREATHING STOPS, APPLY
ARTIFICIAL RESPIRATION & SEEK MEDICAL ATTENTION. INGEST:DO NOT
INDUCE VOMITING. CALL MD. SKIN:WASH AFFECTED SKIN W/SOAP & WATER.
LAUNDER CLOTHING B EFORE WEARING. DISCARD CONTAMINATED LEATHER
PRODUCTS. GET MEDICAL ATTENTION PROMPTLY. EYE:FLUSH W/LARGE
QUANTITIES OF WATER FOR AT LEAST 15 MINUTES. GET PROMPT MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:79.0F,26.1C
Lower Limits:1.1%
Upper Limits:6.6%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . BURNING WILL PRODUCE TOXIC FUMES. COOL FIRE EXPOSED
CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY TRAVEL ALONG
GROUND/BE MOVED BY VENT TO IGNIT SOURCES AT LOCATIONS DIST FROM
HNDLG POINT. AVOID SPREADING LIQ & FIRE BY WATER FLOODING.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES & PROVIDE GOOD
VENTILATION. FOR A LARGE SPILL, WEAR APPROPRIATE NIOSH/MSHA
APPROVED RESPIRATORY PROTECTION. DIKE SPILL AREA, SOAK UP W/INERT
ABSORBENT MATERIAL & PLACE IN CL OSED CONTAINERS FOR PROPER
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:MAINTAIN GOOD HOUSEKEEPING.
Other Precautions:THIS COATING CONTAINS MATERIALS CLASSIFIED AS
NUISANCE PARTICULATED; FOR EXAMPLE, TITANIUM DIOXIDE, CALCIUM
CARBONATE, ETC, WHICH MAY BE PRESENT AT HAZARDOUS LEVELS ONLY
DURING SANDING OR ABRADING OF THE DRIED FILM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE EXCEEDS TLV USE APPROPRIATE
NIOSH/MSHA APPROVED RESPIRATORY PROTECTIVE EQUIPMENT W/IN USE
LIMITATIONS OF THESE DEVICES; IN ALL OTHER SITUATIONS USE
NIOSH/MSHA APPROVED SCBA.
Ventilation:EXPLOSION PROOF LOCAL EXHAUST VENTILATION AT POINT OF
CONTAMINANT RELEASE IS RECOMMENDED ALONG W/GOOD GENERAL MECH VENT.
Other Protective Equipment:EMERG EYE WASH AND DELUGE SHOWER WHICH MEETS
ANSI DESIGN CRITERIA , BARRIER CREAM & PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING. WASH
CLOTHES AFTER EACH USE.
Supplemental Safety and Health
EYE PROT:& FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>273F,>134C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.9 (H*2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:EPOXY COATING.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, OXIDIZING AGENTS & BASES/ALIPHATIC AMINES.
Stability Condition to Avoid:EXCESSIVE HEAT & ANY SOURCE OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN,
CARBON DIOXIDE & VARIOUS HYDROCARBONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
=======================================================
Product ID: 9121 FLAT NAVAJO WHITE, LIFEMASTER 2000 INTERIOR (SUP DAT)
Cage: IO491
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 01PD6
Cage: IO491
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHALATION: IRRITATION OF RESPIRATORY TRACT.
PROLONGED INHALATION MAY LEAD TO COUGHING, SNEEZING, RESPIRATORY PROBLEMS,
PNEUMOCONIOSIS. SKIN: IRRITATION. EYES: IRRITATION. PROLONGED OR REPEATED
CONTACT CAN CAUSE TEARING. INGESTION: MAY CAUSE GASTROINTESTINAL
DISTURBANCES.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET MED HELP FOR
ANY BRTHG DFCLTY. REMOVE TO FRESH AIR IMMED IF INHAL CAUSES E YE WATERING,
HDCH, DIZZ/OTHER DISCOMFORT. SKIN: FLUSH W/WATER. THEN WASH THORO W/SOAP
& WATER. REMOVE CONTAM CLTHG. IF IRRIT OCCURS, CONSULT MD. EYES: FLUSH
IMMED W/LGE AMTS OF WATER, ESP (SUP DAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL
REGULATIONS. VENTILATE AREA. PLACE COLLECTED MATERIAL IN PROPER CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS (FP N).
Handling And Storage Precautions: STORE <100F. KEEP FROM FREEZING. USE ONLY
W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID
CONT W/SKIN & EYES.
Other Precautions: AVOID BRTHG OF VAPS. KEEP CONTRS TIGHTLY CLSD & UPRIGHT
WHEN NOT IN USE. AVOID CNDTNS WHICH RSLT IN FORM OF INHALABLE PARTICLES SUCH
AS SPRAYING/ABRADING (SANDING) PAINTED SURFS. IF SUCH CNDTNS CANNOT BE
AVOIDED, USE APPROP NIOSH (SUP DAT)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONE
Extinguishing Media: DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY BURST IF EXPOSED TO HEAT
OR FIRE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED
RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP
OF VAPORS.
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). APRON.
Work Hygienic Practices: WASH HANDS THOROUGHLY AFTER HANDLING, ESPECIALLY
BEFORE EATING OR SMOKING.
Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). TRADE NAME/PART #: FLAT LM 9100 SERIES. FIRST
AID PROC: UNDER LIDS FOR AT LEAST 15 MIN. IF IRRIT/OTHER EFTS PERSIST, OBT
AIN MED TREATMENT. INGEST: OBTAIN MED TREATMENT IMMED. OTHER PREC: APPRVD
RESP PROT AS DIRECTED UNDER SPECIAL PROT INFO.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 212F,100C
Spec Gravity: 1.36 (FP N)
Appearance and Odor: NAVAJO WHITE
Percent Volatiles by Volume: 66.46
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: CONTACT WITH ALUMINUM OR ZINC, STORAGE NEAR
ACIDS, FREEZING.
Materials To Avoid: ACIDS, ALUMINUM, ZINC, MAGNESIUM, SODIUM, POTASSIUM.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXYGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: 9121 FLAT NAVAJO WHITE, LIFEMASTER 2000 INTERIOR (SUP DAT)
Cage: IO491
Assigned IND: Y
Company Name: ICI PAINTS
Street: 925 EUCLID AVE
Zipcode: 44115
Label Required IND: Y
Date Of Label Review: 02/11/1998
Status Code: C
Label Date: 02/11/1998
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHALATION: IRRITATION OF RESPIRATORY TRACT.
PROLONGED INHALATION MAY LEAD TO COUGHING, SNEEZING, RESPIRATORY PROBLEMS,
PNEUMOCONIOSIS. SKIN: IRRITATION. EYES: IRRITATION. PROLONGED OR REPEATED
CONTACT CAN CAUSE TEARING. INGESTION: MAY CAUSE GASTROINTESTINAL
DISTURBANCES. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:SAFETY SILV 54 OR SAFETY SILV 1575
CAGE:27911
CAGE:27911
============= Composition/Information on Ingredients =============
Ingred Name:SILVER (SARA III) *
CAS:7440-22-4
RTECS #:VW3500000
Fraction by Wt: 54%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.01 MG/M3 *
ACGIH TLV:0.1 MG/M3; 9192 *
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:COPPER (SARA III) *
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 40%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2MG/M3 FUME; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ZINC (SARA III) *
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 MG ZNO/M3 *
ACGIH TLV:10 MG ZNO/M3; 9192 *
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:NICKEL (SARA III) *
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3 *
ACGIH TLV:1 MG/M3; 9192 *
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: BRAZING FUMES MAY IRRITATE
RESPIRATORY TRACT, EYES AND SKIN. FUMES MAY CAUSE METAL FUME FEVER.
CHRONIC: FUMES MAY PRODUCE PNEUMOCONIOSIS.
Explanation of Carcinogenicity:CONTAINS NICKEL. NTP LISTS AS A POSSIBLE
CARCINOGEN AND IARC AS A CARCINOGEN.
Effects of Overexposure:INHALATION: COUGHING, WHEEZING, NAUSEA,
HEADACHE, FEVER, CHILLS, BODY ACHE, AND SHORTNESS OF BREATH. EYES:
REDNESS, TEARING. SKIN: REDNESS, RASH, ITCHING.
Medical Cond Aggravated by Exposure:PREEXISTIG RESPIRATORY TRACT OR
SKIN DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO FUMES FROM BRAZING
OPERATIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH WITH PLENTY OF
WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: WASH WITH SOAP AND WATER.
IF IRRITATION PERSISTS; SEE A DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:NONFLAMMABLE. USE MEDIA APPROPRIATE FOR SURROUNDING
FIRE CONDITIONS.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:(NONFLAMMABLE) OPEN FLAME & SPARKS CAN
IGNITE COMBUSTIBLES,SEE ANSI/ASC Z49.1-1983 SECTION 6.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR OR SUPPLIED
AIR RESPIRATOR IN CONFINED SPACES OR WHERE VENTILATION CANNOT KEEP
FUMES UNDER PEL.
Ventilation:LOCAL OR GENERAL MECHANICAL VENTILATION TO KEEP FUME LEVEL
UNDER PEL.
Other Protective Equipment:APPROPRIATE WELDERS CLOTHING. SEE ANSI Z49.1
STANDARD.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING.
Supplemental Safety and Health
READ AND UNDERSTAND MANUFACTURES INSTRUCTIONS AND THE PRECAUTIONARY
LABEL ON THE PRODUCT. FOR MORE DETAIL ON WELDING/BRAZING SAFETY;
SEE ANSI STANDARD Z49.1, "SAFETY IN WELDING AND CUTTING".
================== Physical/Chemical Properties ==================
HCC:N1
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID WIRE OR ROD. ROD IS POSSIBLY COATED WITH
CHEMICAL FLUX-BLUE OR OTHER COLO
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER. STRONG MINERAL ACIDS AND STRONG ALKALIS
Stability Condition to Avoid:HIGH TEMPERATURES
Hazardous Decomposition Products:SILVER (METAL & SOLUBLE CMPDS),COPPER
(FUME), VARIOUS HALOGENS
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL, STATE & LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:309L
CAGE:GO230
CAGE:GO230
CAGE:84021
============= Composition/Information on Ingredients =============
Ingred Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
OSHA PEL:5 MG/CUM
ACGIH TLV:10 MG/CUM
Ingred Name:NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC,
ACGIH) INTENDED CHANGE (IC)
CAS:7440-02-0
RTECS #:QR5950000
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
ACGIH TLV:0.05 MG/CUM IC
Ingred Name:POTASSIUM ALUMINUM SILICATE (FELDSPAR) *93-1*
CAS:68476-25-5
ACGIH TLV:10 MG/CUM
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:TITANIUM DIOXIDE, TIO2
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN
CARCINOGEN BY IARC, NTP & ACGIH)
CAS:7440-47-3
RTECS #:GB4200000
OSHA PEL:1 MG/CUM (CEILING)
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:MANGANESE, MN COMPOUNDS
CAS:7439-96-5
RTECS #:OO9275000
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
Ingred Name:SODIUM METASILICATE; SODIUM SILICATE; WATER GLASS; DISODIUM
SALT SILIC ACID
CAS:6834-92-0
RTECS #:VV9275000
Ingred Name:CALCIUM FLUORIDE, FLUORSPAR, CALCIUM DIFLUORIDE, IRTRAN 3,
LIPARITE
CAS:7789-75-5
RTECS #:EW1760000
Other REC Limits:2.5 MG/CUM (AS F)
OSHA PEL:2.5 MG/CUM (AS F)
ACGIH TLV:2.5 MG/CUM (AS F)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF NOSE, THROAT, EYES. MAY
LEAD TO SIDEROSIS WHICH MAY AFFECT PULMONARY FUNCTION. ARC RAYS CAN
INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. SEE SUPP.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:INHALATION: DIZZINESS, NAUSEA, IRRITATION OF
NOSE OR THROAT. EYES: IRRITATION. SKIN: DRYNESS & BURNS.
======================= First Aid Measures =======================
First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED
CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE
COMBUSTIBLES.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP HEAD OUT OF FUMES, DON'T TOUCH
LIVE ELECTRICAL PARTS, INSULATE FROM WORK AND GROUND.
Other Precautions:TO DETERMINE COMPOSITION & QUANTITY OF FUMES & GASES
TO WHICH WORKERS ARE EXPOSED IS TO TAKE AN AIR SAMPLE INSIDE THE
WELDERS HELMET OR IN THE WORKER'S BREATHING ZONE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED
RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR
VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV.
Ventilation:LOCAL EXHAUST AT THE ARC TO KEEP THE FUMES & GASES BELOW
THE TLV.
Other Protective Equipment:HELMET, ARM PROTECTORS, APRONS, HATS,
Supplemental Safety and Health
THE PRODUCT AS SUPPLIED IS NON-HAZARDOUS. HEALTH HAZARDS OCCUR DURING
OPERATIONS. THE COMPOSITION & QUANTITY OF WELDING FUMES ARE
DEPENDENT ON THE PROCESS, PROCEDURES, MEDIA, CONTAMINENTS IN THE
ATMOS PHERE, & ELECTRODES USED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SEE SUPP
Stability Condition to Avoid:SEE SUPP
Hazardous Decomposition Products:CO, CO2, OZONE & NITROGEN OXIDES
FORMED BY THE RADIATION FROM ARC, WELDING FUMES - COMPLEX OXIDES
FROM INGREDIENTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
W/FEDERAL, STATE, & L OCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:4140, ALLOY STEEL-HR&CR
CAGE:6N313
CAGE:6N313
============= Composition/Information on Ingredients =============
Ingred Name:VANADIUM. PEL & TLV AS V*2O*5
CAS:7440-62-2
RTECS #:YW1355000
Fraction by Wt: <2%
OSHA PEL:C,0.5 MG V2O5/M3 RD
ACGIH TLV:0.05 MG V205/M3;9293
Ingred Name:ALUMINUM. PEL: 15 MG/M3 TDUST; 5 MG/M3 RDUST
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: <2%
OSHA PEL:SEE INGREDIENT NAME
ACGIH TLV:10 MG/M3 DUST
Ingred Name:SULFUR. PEL & TLV AS SO*2
CAS:7704-34-9
RTECS #:WS4250000
Fraction by Wt: <2%
OSHA PEL:2 MG/M3;5 MG/M3 STEL
ACGIH TLV:2 MG/M3;5 MG/M3 STEL
Ingred Name:PHOSPHORUS(WHITE)
CAS:7723-14-0
RTECS #:TH3500000
Fraction by Wt: <1%
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.01 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:BISMUTH
CAS:7440-69-9
RTECS #:EB2600000
Fraction by Wt: <1%
Ingred Name:COPPER
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: <1%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:LEAD ALLOY CONSISTING OF INGREDIENT 17
RTECS #:9999999ZZ
Fraction by Wt: <1%
Ingred Name:LEAD
CAS:7439-92-1
RTECS #:OF7525000
OSHA PEL:0.05 MG/M3
ACGIH TLV:0.15 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SUPP DATA:BEHAVIORAL CHANGES, KIDNEY DAM, CNS DAM & REPROD
EFTS. EXPOS TO HIGH CONC OF NICKEL & CHROMIUM DUSTS/ (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:FUMES CAN CAUSE SENSIT DERM, INFLAMM &/OR ULCERATION
OF UPPER RESP TRACT & POSS CANCER OF NASAL PASSAGES (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:& LUNGS. RECENT EPIDEMIOLOGICAL STUDIES OF WORKERS
MELTING & WORKING ALLOYS CNTNG NICKEL/CHROMIUM HAVE (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:FOUND NO INCR RISK OF CANCER. NOTE: (LEAD CAS #
7439-92-1) APPEARS ON NAVY LIST OF OCCUP REPROD HAZ. (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21:SEEK CONSULTATION FROM APPROPRIATE HEALTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & (ING
23)
RTECS #:9999999ZZ
Ingred Name:ING 22:EXPOSURE RECOMMENDATIONS .
RTECS #:9999999ZZ
Ingred Name:BASE METAL CONSISTING OF INGRED 2
RTECS #:9999999ZZ
Ingred Name:IRON (PEL/TLV AS IRON OXIDE)
CAS:7439-89-6
RTECS #:NO4565500
Fraction by Wt: 86-99%
OSHA PEL:10 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:ALLOYING ELEMENTS CONSISTING OF INGREDIENTS 4-15
RTECS #:9999999ZZ
Ingred Name:NICKEL
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: <5%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:CHROMIUM
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: <5%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:MANGANESE
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: <2%
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
Ingred Name:CARBON
CAS:7440-44-0
RTECS #:FF5250100
Fraction by Wt: <2%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9293
Ingred Name:MOLYBDENUM
CAS:7439-98-7
RTECS #:QA4680000
Fraction by Wt: <2%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NOTE:STEEL PROD IN NATURAL STATE DO
NOT PRESENT AN INHAL, INGEST/CONT HAZ, HOWEVER, OPERATIONS SUCH AS
BURNING, WELDING, SAWING, BRAZING & GRINDING MAY RELEASE FUMES &/OR
DUSTS WHICH MAY PRESENT HLT H AZ IF TLVS ARE EXCEEDED. ACUTE: SHORT
TERM EXPOS TO FUMES/DUST MAY PRDCE IRRIT OF EYES & RESP SYS. (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM: GROUP 1(NTP) GROUP 1(IARC).
NICKEL: GROUP 2(NTP); GROUP 1(IARC). LEAD: GROUP 2B(IARC).
Effects of Overexposure:HLTH HAZ:INHAL OF HIGH CONC OF FRESHLY FORMED
OXIDE FUMES OF IRON, MANGANESE, COPPER & LEAD MAY CAUSE METAL FUME
FEVER, CHARACT BY METALLIC TASTE IN MOUTH, DRYNESS & IRRIT OF
THROAT & INFLUENZA-LIKE S YMP. CHRONIC: CHRONIC INHAL OF HIGH CONC
OF IRON OXIDE FUMES/DUST MAY LEAD TO BENIGN PNEUMOCONIOSIS (SUPP
DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR, SEEK MEDICAL AID IMMEDIATELY.
EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN. SKIN: FLUSH WITH
COPIOUS AMOUNTS OF WATER. CALL MD . INGEST: CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . STEEL PRODUCTS IN THE SOLID STATE PRESENT NO
FIRE OR EXPLOSION HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:IN WELDING, PREC SHOULD BE TAKEN FOR
AIRBORNE CONTAMINANTS WHICH MAY ORIGINATE FROM COMPONENTS OF
WELDING ROD.
Other Precautions:ARC OR SPARK GENERATED WHEN WELDING OR BURNING COULD
BE A SOURCE OF IGNITION FOR COMBUSTIBLE AND FLAMMABLE MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED DUST & FUME, RESPIRATOR
SHOULD BE USED TO AVOID EXCESSIVE INHALATION OF PARTICULATES WHEN
EXPOSURE EXCEEDS TLVS.
Ventilation:LOC EXHAUST VENT SHOULD BE UTILIZED WHEN WELDING, BURNING,
SAWING, BRAZING, GRINDING/MACHINING WHEN EXPOS EXCEEDS TLVS.
Other Protective Equipment:OTHER PROTECTIVE EQUIPMENT SHOULD BE
UTILIZED AS REQUIRED BY THE WELDING STANDARDS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: (SIDEROSIS). INHAL OF HIGH CONC OF FERIC OXIDE MAY
POSS ENHANCE RISK OF LUNG CANCER DEVEL IN WORKERS EXPOS TO PULM
CARCIN. INHAL/INGEST OF LEAD PARTICLES MAY RSLT IN LEAD INDUCED
SYST EMIC TOX. SYMP OF LEAD POISONING INCL ABDOM CRAMPS, ANEMIA,
MUSCLE WEAKNESS & HDCH. PRLNG EXPOS CAN CAUSE (ING 18)
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:>2500F,>137
Spec Gravity:7
Appearance and Odor:GRAY-BLACK ODORLESS SOLID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS WITH STRONG ACIDS TO PROVIDE HYDROGEN GAS.
Hazardous Decomposition Products:METALLIC DUST/FUMES MAY BE PRDCD
DURING WELDING, BURNING, GRINDING & POSSIBLY MACHINING. REFER TO
ANSI Z49.1
==================== Disposal Considerations ====================
Waste Disposal Methods:ACCORDING TO LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:RENE 88 DT, NICKEL BASE ALLOY
Preparer's Name:R.I. THURSTON
CAGE:52224
CAGE:52224
============= Composition/Information on Ingredients =============
Ingred Name:NICKEL; (NI) (SARA III)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 55.4%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:CHROMIUM; (CHROMIUM (CR) CR VI) (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 16.5%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ALUMINUM; (AL) (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 2.3%
OSHA PEL:15 MG/M3 DUST;5 FUME
ACGIH TLV:10 MG/M3 DUST
Ingred Name:MOLYBDENUM; (MO)
CAS:7439-98-7
RTECS #:QA4680000
Fraction by Wt: 4.2%
OSHA PEL:15 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)
Ingred Name:TITANIUM; (TI)
CAS:7440-32-6
RTECS #:XR1700000
Fraction by Wt: 3.9%
OSHA PEL:15 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)
Ingred Name:COBALT ALLOY, CO, CR; (CO)(SARA III)
CAS:11114-92-4
RTECS #:GF9180000
Fraction by Wt: 13.5%
OSHA PEL:0.05 MG/M3
ACGIH TLV:0.05 MG/M3 DUST
Ingred Name:TUNGSTEN; (W)
CAS:7440-33-7
RTECS #:YO7175000
Fraction by Wt: 4.2%
OSHA PEL:15 MG/M3 (MFR)
ACGIH TLV:5 MG/M3 (MFR)
Ingred Name:SUPP DATA:EVAL OF CARCIN RISK OF CHEMS TO MAN, VOL 52, PG
363, 1991:GRP 2B. ANIMAL:PULM FIBROSIS (BLOOD EFTS).
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:LUNG & STOM CANCER MAY RSLT FROM CHRONIC
OVEREXP. SOME STUDIES HAVE SHOWN THAT COBALT MAY CAUSE (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:ALLERGIC DERM, PNEUMOCONIOSIS, COUGH, WHEEZING &
SHORTNESS OF BREATH. LUNG LESIONS HAVE BEEN FOUND IN (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:WORKERS CHRONICALLY EXPOSED TO COBALT.
RTECS #:9999999ZZ
Ingred Name:RESP PROT:FOR PROT AGAINST DUSTS & FUMES THAT MEET
REQUIREMENTS OF 29 CFR 1910.134 IS RECOMMENDED.
RTECS #:9999999ZZ
Ingred Name:VENT:SHOULD BE MAINTAINED BELOW REC EXPOS LIMITS BY USE OF
APPROP LOCAL EXHAUST.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PRLNG/RPTD CONT MAY CAUSE SKIN
IRRIT/OTHER ALLERGIC RXNS TO SENSITIVE INDIVIDUALS. DUST MAY BE
GENERATED DURING CUTTING/GRINDING. INHAL OF DUSTS & FUMES MAY CAUSE
RESP IRRIT, COUGH, VOMIT, DIARR, CHRO NIC LUNG DISEASE, LETHARGY &
COMA. SOMESCIENTIFIC STUDIES HAVE FOUND EXCESS INCIDENTS OF CANCER
OF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NICKEL:IARC MONOGRAPHS ON EVAL OF CARCIN
RISK OF CHEMS TO MAB, VOL 49, PG 257, 1990:GRP 2B. NTP 6TH ANNUAL
RPT (SUPDAT)
Effects of Overexposure:HLTH HAZ:RESP TRACT AMONG WORKERS INVOLVED IN
CERTAIN STEPS OF NICKEL REFINING PROCESS. HOWEVER SEVERAL RELIABLE
STUDIES OF WORKERS EXPOS TO NICKEL & ITS CMPDS HAVE NOT SHOWN ANY
RISK OF CANCER. SOME SCIENTIFIC STUDIES HAVE SHOWN THAT SKIN&
NASAL CANCER & SENSIT MAY RSLT FROM ACUTE OVEREXP TO CHROMIUM VI.
(ING 9)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . EYE:FLUSH W/WATER FOR AT LEAST
15 MINUTES. SKIN:WASH W/SOAP & WATER, DO NOT SCRUB AS THIS COULD
DRIVE METAL INTO SKIN. INHAL:REMOVE TO FRESH AIR, WASH DUST FROM
FACE . CONTACT MD IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE DRY POWDER EXTINGUISHING AGENT.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:METAL POWDER DISPERSED IN AIR MAY CAUSE
FIRE & EXPLOSION HAZARD. GOOD HOUSEKEEPING MUST BE MAINTAINED.
MOLTEN METAL CAN IGNITE COMBUSTIBLES.
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP POWDER OR DUST SPILLS BY METHODS SUCH
AS VACUUMING OR WET MOPPING - PREVENT DUSTY CONDITIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF SOLID NICKEL FORMS OF ALLOYS OF NICKEL,
CHROMIUM/COBALT ARE CONVERTED TO DUST & FUMES & USE/APPROP LOC
EXHST VENT IS NOT ABLE TO MAINTAIN LEVELS OF THESE METALS & THEIR
OXIDES BELOW REC EXPOS LIMS, USE OF NIOSH/MSHA APPRVD RESPS (ING
12)
Ventilation:IF SOLID FORMS OF NICKEL, CHROMIUM/COBALT ARE CONVERTED TO
DUSTS/FUMES, LEVELS OF THESE METALS & THEIR OXIDES (ING 13)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CNDTNS(STAB):MAY PRDCE NICKEL CARBONYL, HIGHLY TOX GAS. EXPLAN OF
CARCIN:ON CARCINS, 1991:ANTIC TO BE CARCIN. HUMAN:LUNGS, NASAL
CAVITIES. CHROMIUM:IARC MONOGRAPHS, VOL 49, PG 49, 1990:GRP 1. NTP
6TH ANNUAL RPT ON CARCINS, 1991:KNOWN TO BECARCIN.
HUMAN/ANIMAL:LUNG CANCER, SKIN ULCERS. COBALT:IARC MONOGRAPHS ON
(ING 8)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:2520F,1382C
Spec Gravity:8.33 (H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:METALLIC GRAY IN COLOR; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ETHYLENE, METHANOL, SULFUR COMPOUNDS, SELENIUM & OXIDES.
Stability Condition to Avoid:CONT W/MINERAL ACIDS WILL RELS HYDROGEN,
DANGEROUS GAS. UNDER CERTAIN SPECIFIC CNDTNS, EXPOS TO CARBON
MONOXIDE (SUPDAT)
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE I/A/W LOCAL, STATE OR FEDERAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:STEELBOND SOLDER 1/8
Preparer's Name:MICHAEL COLE
CAGE:EO081
CAGE:55649
CAGE:EO081
============= Composition/Information on Ingredients =============
Ingred Name:TIN
CAS:7440-31-5
RTECS #:XP7320000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9293
Ingred Name:SILVER (SARA III)
CAS:7440-22-4
RTECS #:VW3500000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.1 MG/M3; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES,
GASES OR DUST MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA,
FEVER, DRYNESS AND/OR IRRITATION OF NOSE, THROAT AND EYES. SKIN
SENSITIVITY MAY ALSO BE NOTED. A CUTE EXPOSURE FROM SOME TOXIC
GASES MAYCAUSE PULMONARY EDEMA, ASPHYXIATION AND EXCESSIVE EXPOSURE
CAN BE FATAL.
Effects of Overexposure:METALLIC TASTE, NAUSEA, TIGHTNESS OF CHEST,
FEVER, DIZZINESS. EYE, NOSE, THROAT DRYNESS AND IRRITATION.
Medical Cond Aggravated by Exposure:PULMONARY DISEASES.
======================= First Aid Measures =======================
First Aid:IN CASE OF ELECTRICAL SHOCK, TURN OFF POWER PRIOR TO REMOVAL
FROM EXPOSURE AREA AND ADMINISTRATION OF FIRST AID. REMOVE FROM
EXPOSURE AREA AND CALL FOR MEDICAL AID. ADMINISTER OXYGEN IF
BREATHING IS D IFFICULT. IF NOT BREATHING, BEGIN ARTIFICIAL
RESPIRATION. IF NO DETECTABLE PULSE, BEGIN EXTERNAL HEART MASSAGE.
EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS.
===================== Fire Fighting Measures =====================
Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE
Unusual Fire/Explosion Hazard:WELDING ARC AND SPARKS CAN IGNITE
COMBUSTIBLE PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUE
AND PLACE IN SUITABLE DOT APPROVED DISPOSAL CONTAINER.
======================Handling and Storage ======================
Other Precautions:TRAIN WELDER TO KEEP HIS HEAD OUT OF THE FUMES.
MONITOR AIR TO ENSURE ACCEPTABLE EXPOSURES. AVOID ELECTRICAL SHOCK
BY MAINTAINING DRY WORK AREA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. USE NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS IF TLV IS EXCEEDED OR WHEN USING
IN CONFINED SPACES.
Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV.
Other Protective Equipment:LONG SLEEVE CLOTHES, ARM PROTECTOR, APRON,
HAT, SHOULDR PROTECTION.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER WELDING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Appearance and Odor:GREY, SOLID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:FUMES OF METALS AND METAL
OXIDES,CO,NO2,O3.
==================== Disposal Considerations ====================
Waste Disposal Methods:SEND FOR RECLAMATION OR DISPOSE OF IN ACCORDANCE
WITH LOCAL,STATE AND FEDERAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:TFE PASTE, 023030
CAGE:IO530
CAGE:51947
CAGE:IO530
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 10-15%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL
Ingred Name:ETHANOL, 2-BUTOXY-; (BUTYL OXITOL)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 13-18%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION:DO NOT INHALE! SIGNS AND
SYMPTOMS:INHALATION:POSSIBLE DIZZINESS AND LIGHT HEADEDNESS;
EYES:RED AND WATERING. CHRONIC:ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFFECTS ON THE CNS, THE HEMATOPOIETIC
TISSUES, THE BLOOD, THE KIDNEYS AND LIVER, ASSOCIATED WITH THE
ADMINISTRATION (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:OF ETHYLENE GLYCOL MONOBUTYL ETHER
(EGBE) (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) .
Medical Cond Aggravated by Exposure:INHALATION:MAY CAUSE HEADACHE,
EYES:MAY CAUSE IRRITATION.
======================= First Aid Measures =======================
First Aid:INGESTION:CALL MD IMMEDIATELY . SKIN:FLUSH W/COPIOUS AMOUNTS
OF WATER. CALL MD . INHALATION:REMOVE TO FRESH AIR, SEEK MEDICAL
ATTENTION IF CONDITION PERSISTS. EYES:FLUSH WITH WATER FOR AT
LEAST 15 MINUTES AND CONSULT A PHYSICIAN IF IRRITATION IS NOT
RELIEVED.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:70.0F,21.1C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP MATERIAL AND PLACE IN TRASH
CONTAINER. CONTAIN SPILL WITH SAND, DIRT OR SAWDUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM HEAT, KEEP CONTAINER
CLOSED AFTER USE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN AND PETS!
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . AVOID PROLONGED BREATHING OF FUMES.
Ventilation:LOCAL EXHAUST:PROVIDE ADEQUATE VENTILATION.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:USE NORMAL GOOD HYGIENIC PRACTICES. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:173F,78C
Vapor Density:1
Spec Gravity:1.41 (H*2O=1)
Solubility in Water:SLIGHT
Appearance and Odor:WHITE PASTE WITH SLIGHT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
LIQUID OXYGEN; LIQUID SODIUM, GASEOUS FLUORINE.
Stability Condition to Avoid:LIQUID OXYGEN SYSTEMS, SOURCES OF
IGNITION.
Hazardous Decomposition Products:NONE.
Conditions to Avoid Polymerization:STRONG OXIDIZING AGENTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE MATERIAL ACCORDING TO
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:A1177B1
Kit Part:Y
Preparer's Name:C PEARSON
CAGE:KO011
CAGE:KO011
CAGE:0GGS8
CAGE:1HS43
============= Composition/Information on Ingredients =============
Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SOME PEOPLE MAY DEVELOP ALLERGIC
REACTION.
Explanation of Carcinogenicity:NONE KNOWN.
Effects of Overexposure:MINOR TRANSIENT IRRITATION OF EYES AND SKIN.
Medical Cond Aggravated by Exposure:SKIN RASHES.
======================= First Aid Measures =======================
First Aid:FLUSH EYE WITH WATER FOR 15 MINUTES HOLDING EYE LIDS OPEN.
SEE A PHYSICIAN. WASH SKIN WITH SOAP AND WATER. SEE A PHYSICIAN IF
RASH DEVELOPS. REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF
NOT BRE ATHING. CONSULT A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:480F,249C
Extinguishing Media:WATER FOG, CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:DO NOT ENTER CONFINED FIRE SPACE WITHOUT
PROPER PROTECTIVE EQUIPMENT, INCLUDING A NIOSH APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:FIRES MAY GIVE OFF TOXIC FUMES.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID EYE AND SKIN CONTACT. SCRAPE UP OR
ABSORB AND PLACE IN CONTAINER FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA, AWAY FROM
SOURCES OF HEAT. KEEP AWAY FROM CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY NECESSARY. USE ORGANIC VAPOR FOR
FUMES FROM HEATED MATERIAL.
Ventilation:LOCAL AT A POINT OF CORE OR HEATING.
Other Protective Equipment:EYE WASH AND SHOWER IN AREA.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>400F,>204C
Decomp Temp:Decomp Text:>400F,>204C
Spec Gravity:1.371 (WATER=1)
Viscosity:100,000 CPS
Solubility in Water:NIL
Appearance and Odor:THICK GREEN LIQUID, EPOXY ODOR.
Percent Volatiles by Volume:0.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, AMINES IN UNCONTROLLED CONDITIONS
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
PHENOL AND OTHER TOXIC FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:THIS MATERIAL IF DISCARDED MAY BE HAZARDOUS.
DISCARD IN ACCORDANCE WITH FEDERAL, STATE & LOCAL REGULATIONS.
INCINERATION IS THE PREFERRED METHOD.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ELBEE
CAGE:9T403
CAGE:9T403
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM HYDROXIDE (SARA III)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: <20%
Other REC Limits:2MG/M3 CEILING NIOSH
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: CORROSIVE, SEVERE BURNS,
IRREVERSIBLE DAMAGE, & IRRITATION. INGESTION: MAY BE FATAL & CAUSE
ESOPHOGICAL/GASTRIC PERFORATION, BURNS TO MOUTH, THROAT & MUCOUS
MEMBRANES. INHALATION: MODERATE TO SEVERE PULMONARY IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN: CORROSIVE, SEVERE BURNS,
IRREVERSIBLE DAMAGE, & IRRITATION. INGESTION: MAY BE FATAL & CAUSE
ESOPHOGICAL/GASTRIC PERFORATION, SEVERE BURNS TO MOUTH, THROAT &
MUCOUS MEMBRANES. INHALATION: MO DERATE TO SEVERE PULMONARY
IRRITATION.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. GET MED ATTN. SKIN:
FLUSH W/WATER. REMOVE/LAUNDER CONTAMINATED CLOTHING/SHOES BEFORE
REUSE. GET MED ATTN. INGESTION: RINSE MOUTH W/WATER & DRINK
WATER/MILK IF VOMITING OCCURS. DON'T INDUCE VOMITING. GET MED
ATTN. INHALATION: MOVE TO FRESH AIR. GIVE MOUTH-TO-MOUTH ARTIFICIAL
RESPIRATION/OXYGEN IF NOT BREATHING/DIFFICULT TO BREATHE. GET MED
ATTN.
===================== Fire Fighting Measures =====================
Flash Point:NOT COMBUSTIBLE
Extinguishing Media:WATER FOG
Fire Fighting Procedures:GOOD FIRE-FIGHTING PRACTICE DICTATES THE USE
OF SELF-CONTAINED BREATHING APPARATUS & TURN-OUT GEAR FOR FIRES IN
AREA WHERE PRODUCT IS STORED.
Unusual Fire/Explosion Hazard:NOT A FIRE HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:FORMS CORROSIVE LIQUID IN WATER. SWEEP UP &
STORE IN A METAL CONTAINER. DISSOLVE IN WATER & NEUTRALIZE W/DILUTE
ACIDS/CO2. DISCHARGE NEUTRALIZED SOLUTION TO SANITARY SEWER OR BURY
IN CHEMICAL LANDFILL . WASH SPILL AREA THOROUGHLY.
Neutralizing Agent:ACIDS, CO2
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN DRY AREA AWAY FROM ACIDS.
KEEP CONTAINER CLOSED WHEN MOVING/NOT IN USE. KEEP OUT OF REACH OF
CHILDREN. DON'T STORE W/FOOD.
Other Precautions:ADD SLOWLY TO WATER WHEN MIXING TO AVOID SPATTERING.
WASH THOROUGHLY AFTER HANDLING OR USING PRODUCT. AVOID DIRECT
CONTACT W/SKIN & EYES. MAY REMOVE PAINT & ORGANIC COATINGS.
REMOVE/LAUNDER CONTAMINAT ED CLOTHING BEFORE REUSE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH APPROVED ALKALINE CARTRIDGE
RESPIRATOR IN AREAS WHERE MIST OR DUST EXCEED TLV.
Ventilation:PROVIDE MECHANICAL VENTILATION TO KEEP <TLV.
Other Protective Equipment:EYE WASH & CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING OR USING PRODUCT.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:70
pH:13.5
Solubility in Water:COMPLETE
Appearance and Odor:SOLID WHITE, GRANULAR POWDER W/PINE ODOR.
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
DON'T MIX W/ACIDS, FLAMMABLE LIQUIDS, ORGANIC HALOGENS, SOFT METALS,
COPPER, BRASS, TIN, & ALUMINUM. OXIDIZING AGENTS.
Stability Condition to Avoid:HEATING & SPATTERING
Hazardous Decomposition Products:NON-TOXIC CO2 WHEN MIXED W/ACIDS, &
CORROSIVE CAUSTIC SODA SOLUTIONS. HYDROGEN GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:LIQUID WASTE SOLUTION IS STRONGLY ALKALINE.
NEUTRALIZE TO A SPECIFIC PH W/DILUTE ACID BEFORE DISPOSAL TO SEWER.
CONSULT LOCAL ENVIRONMENTAL REGULATIONS. ALKALINE SOLUTIONS ARE
TOXIC TO FISH & WILDLIFE . DON'T DISCHARGE TO LAKES, STREAMS OR
PONDS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:MAGNAMINE-327, 1740
Preparer's Name:D. GODWARD
CAGE:21667
CAGE:21667
============= Composition/Information on Ingredients =============
Ingred Name:MORPHOLINE
CAS:110-91-8
RTECS #:QD6475000
Fraction by Wt: <25%
OSHA PEL:20 PPM, S
ACGIH TLV:20 PPM, S
Ingred Name:ETHANOL, 2-(DIETHYLAMINO)-; (DIETHYLAMINOETHANOL)
CAS:100-37-8
RTECS #:KK5075000
Fraction by Wt: <20%
OSHA PEL:10 PPM, S
ACGIH TLV:2 PPM, S
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:MAY CAUSE RESPIRATORY
IRRITATION, SHORTNESS OF BREATH, DIZZINESS IF INHALED. EYES:FUMES
IRRITATING TO MUCOUS MEMBRANES. WILL CAUSE SEVERE BURNS ON CONTACT.
SKIN:CAUSES SEVERE IRRITATI ON OR BURNS. PENETRATION MAY BE SLOW &
EXTENT OF DAMAGE DEPENDS ON DURATION OF EXPOSURE. INGESTION: (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CAUSES BURNS TO MOUTH, THROAT &
STOMACH. CHRONIC:NONE KNOWN.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES & GET MEDICAL
ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING & SHOES. WASH EXPOSED
AREAS W/SOAP & PLENTY OF WATER. IF IRRITATION DEVELOPS, GET MEDICAL
ATTENTIO N. INHAL:REMOVE TO FRESH AIR. IF SYMPTOMS PERSIST, GET
MEDICAL ATTENTION. INGEST:GIVE WATER OR MILK TO DILUTE. DO NOT
INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:163F,73C
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM, WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC VAPORS UNDER FIRE CONDITIONS.
VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL ALONG GROUND TO DISTANT
SOURCE OF IGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL. EXTINGUISH IGNITION SOURCES.
VENTILATE AREA. ABSORB ONTO INERT MATERIAL. FLUSH RESIDUE W/WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME.
USE ONLY W/ADEQUATE VENTILATION. AVOID BREATHING VAPORS.
Other Precautions:AVOID CONTACT W/EYES, SKIN & CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR RECOMMENDED FOR
ORGANIC VAPORS IF AIR LIMITS ARE EXCEEDED.
Ventilation:LOCAL EXHAUST VENTILATION RECOMMENDED.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH:10.5 @ 1% SOLN; 11.9-12 AS DISTRIBUTED. % VOLAT:100(WT). EYE PROT:&
FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
Spec Gravity:1.015 (H*2O=1)
pH:SUPDAT
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR YELLOW TO RED LIQUID; "FISHY" AMINE ODOR.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, REACTIVE METALS, STRONG ACIDS.
Stability Condition to Avoid:KEEP AWAY FROM HEAT & OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
AMMONIA, DISODIUM OXIDE, OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE I/A/W ALL LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
=======================================================
NIIN: 01-464-9266
Product ID: PITT PENN PREMIUM HEAVY DUTY MILITARY ANTIFREEZE, PREMIXED
Cage: 0A1G5
Box: 296
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: ANTIFREEZE
Specification Number: A-A-52624
Type/Grade/Class: TY IP RECYCLED
Unit of Issue: GL
UI Container Qty: 1
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: ORAL, RAT LD50: 4.7-8.5 G/KG
Effects of Exposure: EYE: BELIEVED TO CAUSE SLIGHT EYE IRRITATION. SKIN:
BELIEVED TO BE SLIGHTLY IRRITATING UPON PROLONGED CONTACT. RESPIRATORY
SYSTEM: DROWSINESS, NARCOSIS, AND UNCONSCIOUSNESS POSSIBLE UPON EXPOSURE TO H
IGH CONCENTRATIONS IN POORLY VENTILATED CONFINED SPACES. CHRONIC: LIVER AND
KIDNEY DAMAGE IN A 2 YEAR RAT FEEDING STUDY USING 1-2% ETHYLENE GLYCOL. ORAL
ADMINISTRATION OFF VERY HIGH DOSES OF ETHYLENE GLYCOL PRODUCED BIRTH DEFECTS
IN LABORATORY ANIMALS. SKIN AND RESPIRATORY SENSITIZATION: UNKNOWN.
Signs And Symptions Of Overexposure: RESPIRATORY SYSTEM: DROWSINESS, NARCOSIS,
AND UNCONSCIOUSNESS.
First Aid: EYE: IMMEDIATELY FLUSH WITH LARGE QUANTITIES OF WATER FOR AT LEAST
15 MINUTES AND CALL A PHYSICIAN. SKIN: REMOVE EXCESS WITH CLOTH OR PAPER
TOWEL. WASH THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PE RSISTS, GET
MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. RESTORE AND/OR SUPPORT
BREATHING AS REQUIRED. KEEP VICTIM WARM AND AT REST. SWALLOWED: IMMEDIATELY
CONTACT A PHYSICIAN, POISON CONTROL C ENTER OR EMERGENCY TREATMENT CENTER. DO
NOT INDUCE VOMITING! ASPIRATION HAZARD: PRODUCT MAY BE INHALED INTO LUNGS IF
VOMITED.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: CONTAIN SPILL IF POSSIBLE. WIPE UP OR ABSORB ON
1-800-255-3924.
Waste Disposal Methods: UNDER RCRA, IT IS THE RESPONSIBILITY OF THE USER OF
PRODUCTS TO DETERMINE, AT THE TIME OF DISPOSAL, WHETHER PRODUCT MEETS RCRA
CRITERIA FOR HAZARDOUS WASTE. THIS IS BECAUSE PRODUCT USES TRANSFORMATION S,
MIXTURE, PROCESSES, ETC., MAY RENDER THE RESULTING MATERIAL HAZARDOUS.
DISPOSE OF IN ACCORDANCE W ITH FEDERAL, STATE AND LOCAL LAWS.
Handling And Storage Precautions: MINIMUM FEASIBLE HANDLING TEMPERATURE SHOULD
BE MAINTAINED. PERIODS OF EXPOSURE TO HIGH TEMPERATURE SHOULD BE MINIMIZED.
WATER CONTAMINATION SHOULD BE AVOIDED.
Other Precautions: HARMFUL OR FATAL IF SWALLOWED. KEEP OUT OF REACH OF
CHILDREN. MAY CAUSE IRRITATION TO EYES. DO NOT DRINK ANTIFREEZE OR SOLUTION.
AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER HANDLING. DO NOT STORE I N
OPEN OR UNLABELED CONTAINERS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: COC
Flash Point: >128.C, 262.4F
Autoignition Temp: >413.C, 775.4F
Lower Limits: 3.2
Upper Limits: 15.3
Extinguishing Media: USE WATER SPRAY, DRY CHEMICAL, FOAM, CARBON DIOXIDE
Fire Fighting Procedures: WATER OR FOAM MAY CAUSE FROTHING. USE WATER SPRAY TO
DISPERSE THE VAPORS AND TO PROVIDE PROTECTION FOR PERSON ATTEMPTING TO STOP
THE LEAK.
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: SUPPLIED AIR RESPIRATORY PROTECTION FOR CLEANING LARGE
SPILLS UPON ENTRY INTO TANKS, VESSELS, OR OTHER CONFINED SPACES.
Ventilation: NORMAL TO MAINTAIN EXPOSURE BELOW TLV.
Work Hygienic Practices: EXPOSED EMPLOYEES SHOULD EXERCISE REASONABLE PERSONAL
CLEANLINESS ; THIS INCLUDES CLEANSING EXPOSED SKIN AREAS SEVERAL TIMES DAILY
WITH SOAP/WATER, & LAUNDERING/DRY CLEANING SOILED WORK CLOTHING WEEKLY.
Supplemental Safety and Health: SYNONYMS: ETHYLENE GLYCOL, ETHYLENE GLYCOL
SOLUTION..
=======================================================
Physical/Chemical Properties
=======================================================
HCC: V7
Boiling Point: =110.C, 230.F
Decomp Temp: =412.8C, 775.F
Vapor Pres: NOT DETERMINED
Vapor Density: N/D
Spec Gravity: 1.1
PH: 10-11(NEAT)
Evaporation Rate & Reference: NOT DETERMINED
Solubility in Water: SOLUBLE
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES ABOVE 413 C(775F) (PRODUCT CAN
DECOMPOSE.
Materials To Avoid: STRONG OXIDIZERS.
Hazardous Decomposition Products: CARBON DIOXIDE AND CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: DOES NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: MEDIAN LETHAL DOSE (LD50 LC50 X SPECIES): ORAL:
BELIEVED TO BE 4.7 - 8.5 G/KG (RAT); MODERATELY TOXIC. INHALATION: NOT
DETERMINED. DERMAL: BELIEVED TO BE 1-3 G/KG (RABBIT); SLIGHTLY TOXIC. OTHER:
NOT DETERMINED. IRRITATION INDEX/ESTIMATION OF IRRITATION (SPECIES): SKIN:
BELIEVED TO BE 0.5-1.8/8.0 (RABBIT); SLIGHTLY IRRITATING. EYES: BELIEVED TO
BE 15-25/110 (RABBIT); SLIGHTLY IRRITATING.
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: SARA 313 INFORMATION: CONTAINS FOLLOWING SUBSTANCE
WHICH IS LISTED IN TITLE III: ETHYLENE GLYCOL. SARA HAZARD CATEGORY: AN
IMMEDIATE HEALTH HAZARD. A DELAYED HEALTH HAZARD.
Federal Regulatory Information: ALL COMPONENTS LISTED ON TSCA (USA) INVENTORY.
=======================================================
Other Information
=======================================================
Other Information: ALL COMPONENTS LISTED ON DSL INVENTORY (CANADA).
=======================================================
Transportation Information
=======================================================
Trans ID NO: 156590
Product ID: PITT PENN PREMIUM HEAVY DUTY MILITARY ANTIFREEZE, PREMIXED
Review Date: 04/09/2001
Net Unit Weight: 9.2 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: GL
Container QTY: 1
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: FST
Symbols: G
DOT Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
Hazard Class: 9
UN ID Num: UN3082
DOT Packaging Group: III
Label: CLASS 9
Special Provision: 8,T1
Packaging Exception: 155
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: NONE
Max Qty Cargo: NONE
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: GMW
IMO Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. o
IMDG Page Number: 9028
UN Number: 3082
UN Hazard Class: 9
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: NONE
MED First Aid Guide NUM: NON
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: KTV
IATA UN ID Num: 3082
IATA Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
*
IATA UN Class: 9
IATA Label: MISCELLANEOUS
UN Packing Group: III
Packing Note Passenger: 914
Max Quant Pass: NO LIMIT
Max Quant Cargo: NO LIMIT
Packaging Note Cargo: 914
Exceptions: A97
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: KTV
AFI Symbols: *
AFI Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCES, LIQUID, N.O.S.
AFI Hazard Class: 9
AFI UN ID NUM: UN3082
AFI Packing Group: III
Special Provisions: P5, 8
Back Pack Reference: A13.3
=======================================================
HAZCOM Label
=======================================================
Product ID: PITT PENN PREMIUM HEAVY DUTY MILITARY ANTIFREEZE, PREMIXED
Cage: 0A1G5
Company Name: PITT PENN OIL CO
Street: 426 FREEPORT RD
PO Box: 296
Zipcode: 15030-0296
Label Required IND: Y
Date Of Label Review: 04/09/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: NO
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: EYE: BELIEVED TO CAUSE SLIGHT EYE IRRITATION. SKIN:
BELIEVED TO BE SLIGHTLY IRRITATING UPON PROLONGED CONTACT. RESPIRATORY
SYSTEM: DROWSINESS, NARCOSIS, AND UNCONSCIOUSNESS POSSIBLE UPON EXPOSURE TO H
IGH CONCENTRATIONS IN POORLY VENTILATEDCONFINED SPACES. CHRONIC: LIVER AND
KIDNEY DAMAGE IN A 2 YEAR RAT FEEDING STUDY USING 1-2% ETHYLENE GLYCOL. ORAL
ADMINISTRATION OFF VERY HIGH DOSES OF ETHYLENE G LYCOL PRODUCED BIRTH DEFECTS
IN LABORATORY ANIMALS. SKIN AND RESPIRATORY SENSITIZATION: UNKNOWN.
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:INDUSTRIAL ENAMEL, 977
CAGE:08882
CAGE:08882
============= Composition/Information on Ingredients =============
Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS). VP:2 @ 20C. LEL:1%.
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 30-55%
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:HARMFUL IF INHALED.
MAY AFFECT BRAIN AND NERVOUS SYSTEM CAUSING DIZZINESS, HEADACHE AND
NAUSEA. REPEATED OVEREXPOSURES MAY LEAD PROGRESSIVELY TO STAGGERING
GAIT, CONFUSION, UNCONSCIOU SNESS OR COMA. CAUSES NOSE AND THROAT
IRRITATION. SKIN OR EYE CONTACT:CAUSES IRRITATION WHICH CAN LEAD
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:TO DERMATITIS WITH REPEATED
OVEREXPOSURES. INGESTION:MAY CAUSE GASTROINTESTINAL IRRITATION,
NAUSEA, VOMITING AND DIARRHEA. CHRONIC:REPORTS HAVE ASSOCIATED
REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH
PERMANENTBRAIN AND NERVOUS SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOSURE, RESTORE BREATHING & NOTIFY MD.
EYES:FLUSH IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. NOTIFY MD. SKIN:WASH AFFECTED AREA W/SOAP & WATER, REMOVE
CONTAM CLO THING & WASH BEFORE REUSE. INGEST:DO NOT INDUCE
VOMITING. KEEP PERSON WARM, QUIET & GET MEDICAL ATTENTION.
ASPIRATION OF THIS MATERIAL INTO LUNGS CAN CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:104F,40C
Lower Limits:SEE ING
Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY
CHEMICAL OR FOAM).
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. WATER MAY BE USED TO COOL CLSD CNTNRS TO
PVNT PRESS BUILD-UP & POSS AUTOIGNIT/(SUPDAT)
Unusual Fire/Explosion Hazard:COMBUST LIQ - OSHA CLASS II. KEEP CNTNRS
TIGHTLY CLSD. ISOLATE FROM HEAT, ELEC EQUIP, SPKS & OPEN FLAME.
CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA
& REMOVE W/INERT ABSORBENT & NONSPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 120F. STORE LARGE
QUANTITIES IN BUILDINGS DESIGNED & PROTECTED FOR STORAGE OF NFPA
CLASS II COMBUSTIBLE LIQUIDS.
Other Precautions:CONTAINERS SHOULD BE GROUNDED WHEN POURING. EMPTY
CONTAINERS MAY BE HAZARDOUS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR
(TC23C) TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY & ORGANIC
VAPORS DURING SPRAY APPLICATION. IN CONFINED AREAS:USE NIOSH
APPROVED SUPPLIED-AIR RE SPIRATORS OR HOODS (TC19C).
Ventilation:PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENT IN VOLUME &
PATTERN TO KEEP TLV OF HAZ INGS BELOW ACCEPTABLE LIMITS.
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . USE IMPERVIOUS CLOTHING TO PREVENT PROLONGED SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:EXPLOSION. IF WATER IS USED, FOG NOZZLES ARE PREFERRED.
EXPLO HAZ:HEAT. DO NOT APPLY TO HOT SURFACES.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>307F,>153C
Vapor Pres:SEE ING
Vapor Density:HVR/AIR
Spec Gravity:0.9-1.32
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:51-66
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE W/STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY OPEN FLAME - CARBON MONOXIDE &
CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE & FEDERAL
REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:8R2342 SINGLE STRIKE BLACK CORRECTABLE
CAGE:26921
CAGE:26921
============= Composition/Information on Ingredients =============
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:SILICON DIOXIDE
CAS:7631-86-9
RTECS #:VV3100000
Fraction by Wt: <5%
OSHA PEL:80 MG/CUM
Ingred Name:POLYAMIDE OF C18 FATTY ACID PRIMERS & TETA; POLYAMIDE RESIN
CAS:68410-23-1
Fraction by Wt: <5%
Ingred Name:POLYOLEFIN FILM
Fraction by Wt: >95%
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: <5%
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9192
Ingred Name:MINERAL OIL (EXPOSURE REGULATED AS 'OIL MIST')
CAS:8012-95-1
RTECS #:PY8030000
Fraction by Wt: <5%
Other REC Limits:10 MG/CUM STEL
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3/10 STEL;9192
Ingred Name:BUTYL STEARATE
CAS:123-95-5
RTECS #:WI2900000
Fraction by Wt: <5%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION.
Explanation of Carcinogenicity:CARBON BLACK IS A SUSPECTED HUMAN
CARCINOGEN BY ACGIH.
Effects of Overexposure:SKIN/EYES: IRRITATION.
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO2, WATER, FOAM, OR DRY CHEMICAL
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID INHALATION OF DECOMPOSITION
PRODUCTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE WHEN USED AS INTENDED.
Other Protective Equipment:NONE WHEN USED AS INTENDED.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Vapor Pres:0
Vapor Density:0
Solubility in Water:NEGLIGIBLE
Appearance and Odor:RIBBON CARTRIDGE W/MINIMAL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:CO, CO2, & OTHER TOXIC PRODUCTS OF
DECOMPOSITION
==================== Disposal Considerations ====================
Waste Disposal Methods:NO SPECIAL PROCEDURES.
| 0 |
eyes_protection_not_mandatory
|
===================== Product Identification =====================
Product ID:821 4637 FLEXICOLOR BLEACH III REPLNSHR,PART B,MAKES 12.5GAL
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 80-85%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMMONIUM FERRIC PROPYLENEDIAMINETETRAACETIC ACID
CAS:111687-36-6
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMMONIUM NITRATE
CAS:6484-52-2
RTECS #:BR9050000
Fraction by Wt: 4%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ACETIC ACID (CERCLA)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:1,3-PROPYLENEDIAMINETETRAACETIC ACID
CAS:1939-36-2
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTAINS FERRIC AMMONIUM
PROPYLENEDIAMINETETRAACETIC ACID.EXPO TO HI CONC MAY CAUSE INCR
URINARY EXCRETION OF ZINC & CALCIUM.INHAL:EXPECTED TO BE LOW HAZ
FOR RECOMMENDED HNDLG.VAP MAY BE IRRIT.EYE:CAU SES
IRRIT.SKIN:CAUSES IRRIT.INGEST:EXPECTED TO BE LOW INGESTION HAZ.MAY
CAUSE IRRIT OF GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY
CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE.
Effects of Overexposure:EYE/SKIN/GI IRRITATION.INCREASED URINARY
EXCRETION OF ZINC AND CALCIUM.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:SYMPTOMATIC MOVE TO FRESH AIR.TREAT
SYMPTOMATICALLY.SYMPT PERSIST GET MED ATTN.EYE:IMMED FLUSH W/PLENTY
OF WATER FOR @LEAST 15MINS.SYMPT OCCUR GET MED ATTN.SKIN:IMMED
FLUSH W/PLENTY OF WATER FOR @LEAST 15MINS WHILE REMOVING CONTAM
CLOTH/SHOES.SYMPT OCCUR GET MED ATTN.INGEST:DRINK 1-2GLASSES OF
WATER.SEEK MED ATTN.NEVER GIVE ANYTHING BY MOUTH IF UNCONSC.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE(CO2),
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER W/LG AMTS OF WATER.OTHERWISE
ABSORB SPILL W/VERMICULITE OR OTHER INERT MATL, THEN PLACE IN
CONTAINER FOR CHEMICAL WASTE.CLEAN SURFACE THOROUGHLY TO REMOVE
RESIDUEAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATH MIST/VAP.AVOID
EYE/SKIN/CLOTH CONTACT.USE W/ADEQU VENTI.KEEP FRM CONTACT W/OXIDI
MATLS.KEEP CNTNR TIGHTLY CLSD.KEEP AWAY FRM INCOMP SUBST
Other Precautions:MATL MODERATELY ACIDIC AQU SOLN.PROPERTIES:LOW
BIOCHEM OXY DEMAND,LITTLE POT TO CAUSE OXY DEPLETION IN AQU SYS,LOW
POT TO AFFECT AQUATIC ORGANISMS,LOW POT TO AFFECT 2ND WASTE TREAT
MICROBIAL METABO,HI POT TO AFFECT GERM/EARLY GROWTH(SUPPLE)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ENIGNEER CNTRL DONT MAINTAIN AIRBORNE CONC BEL
RECOMMENDED EXPO LIMITS APPROV RESP MUST BE WORN.RESP TYP:FULLFC
ORG VAP CARTIRDGE.FULLFC +PRESS AIR-SUPPL RESP MUST BE WORN IF HAZ
DECOMPO PRODS LIKELY TO RELEASE/HAVE BEEN RELEASE.RESP(SUPPL)
Ventilation:USE GOOD GEN VENTI(TYP 10AIR CHANGES/HR).MATCH VENTI RATES
W/CONDITIONS.SUPPL LOC EXHAU VENTI,CLSD SYS,RESP PROT (SUPPL)
Other Protective Equipment:PROTECTIVE CLOTHING APPROP FOR RISK OF
EXPO.EYEBATH,SAFETY SHOWER,WASHING FACILITIES.
Work Hygienic Practices:WASH CONTAM CLOTH BEF REUSE.DESTROY/CLEAN WELL
CONTAM SHOES.WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
VENTI:MAY BE NEEDED IN SPEC CIRCUMST(POORLY VENTI SPACE,EVAPOR FRM LG
SURF,SPRAY,HEAT,ETC). RESP:USED INSTITUTE PROGRAM TO ASSURE
COMPLIANCE W/29CFR1910.134. OTH PREC:OF SOME PLANTS,HI POT TO
PHOTCHEM /CHEM DEGRADE,LOW POT TO BIOCONC.AFT DIL W/LOTS OF H2O/2ND
WASTE TREAT MATL NOT EXPECT TO CAUSE ADVERSE ENVIRO EFFECTS.
================== Physical/Chemical Properties ==================
HCC:C3
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.07
pH:4.1
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, GREEN COLOR, VINEGAR ODOR
Percent Volatiles by Volume:85-95
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES,STRONG OXIDIZING AGENTS,SODIUM HYPOCHLORITE(BLEACH).
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN. AMMONIA, CHLORAMINE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHA/TREAT/DISPO MAY BE SUBJ TO NAT/STATE/LOC
LAWS.FLUSH TO SEWER W/LOTS OF H2O.SINCE EMPT CNTNR RETAIN PROD
RESIDUE FOLLOW LABEL WARNS EVEN AFT EMPTIED.CHEM SUBJ TO REPORT
REQMT OF SEC 313 TITLE II I SARA/40CFR372:NITRATE CMPDS-H2O
DISSOC,6484-52-2
| 1 |
eyes_protection_mandatory
|
=======================================================
NIIN: 01-178-4726
Product ID: GARDFLEET MC 30 MIL-PRF-2104G
Cage: 1RU67
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: LUBRICATING OIL,ENGINE
Specification Number: MIL-L-2104
Type/Grade/Class: 30 GRADE
Unit of Issue: QT
UI Container Qty: G
Type of Container: QUARTS
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NOT PROVIDED
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE :NOT EXPECTED TO CAUSE IRRITATION. MAY CAUSE MILD
DISCOMFORT. SKIN:NOT EXPECTED TO CAUSE IRRITATION. PROLONGED CONTACT MAY LEAD
TO AN ALLERGIC SKIN SENSITIZATION. INHALATION: VAPORS FROM HOT MATER IAL MAY
CAUSE NON-SPECIFIC DISCOMFORT. INGESTION: RELATIVELY NON-TOXIC UNLESS LUNG
ASPIRATION OCCURS. ASPIRATION MAY LEAD TO CHEMICAL PHEUMONITIS.
Explanation Of Carcinogenicity: NOT DETERMINED.
Signs And Symptions Of Overexposure: EYES:TEARING, OR BLURRING OF VISION. SKIN:
IRRITATION, ALLERGIC SENSITIZATION (REDDENING OF SKIN & IRRITATION)
INHALATION: NAUSEA, HEADACHE. INGESTION:ABDOMINAL CRAMPS, DIARRHEA. APIRATION
INTO LUNGS IS CHARACTERIZED BY PULMONARY EDEMA, HEMORRHAGE,DEATH,
INCREASED RESPIRATORY RATE, INCREASED HEART RATE, BLUISH DISCOLORATION OF THE
SKIN,
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN.
GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND
WATER. IF IRRITATION PERSIST, GET MEDICAL ATTENTION. INH ALATION: REMOVE TO
FRESH AIR. RESTORE BREATHING. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING DUE TO ASPIRATION HAZARD. IMMEDIATELY GIVE 2 GLASSES OF WATER. NEVER
GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. IF VOMITING OCCURS, LOWER HEAD BELOW
KNEES TO AVOID ASPIRATION. SEEK IMMEDIATE MEDICAL HELP.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: IMMEDIATELY TURN OFF ANY SOURCE OF IGNITION. EVACUATE
AREA AND VENTILATE. CONTAIN MATERIAL WITH INERT MATERIAL AND COLLECT IN
SUITABLE CONTAINERS FOR DISPOSAL. PREVENT MATERIAL FROM ENTERING SEWERS OR
WATERWAYS. IF A LARGE SPILL OCCURS NOTIFY APPROPRIATE AUTHORITIES.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. UNDER RCRA IT IS THE RESPONSIBILITY OF THE USER
OF THE PRODUCT TO DTERMINE AT THE TIME OF DISPOSAL WHETHER THE PRODUCT MEETS
RCRA CRITERIA FOR HAZARDOUS WASTE.
Handling And Storage Precautions: KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO
NOT TRANSFER TO UNMARKED CONTAINERS. FIRE EXTINGUISHERS SHOULD BE KEPT
READILY AVAILABLE.
Other Precautions: SEE NFPA 30 AND OSHA 1910.106--FLAMMABLE AND COMBUSTIBLE
LIQUIDS. EMPTY CONTAIENRS RETAIN PRODUCT RESIDUE WHCIH MAY EXHIBIT HAZARDS OF
MATERIAL, THEREFORE DO NOT PRESSURIZE, CUT, GLAZE, WELD OR USE FO R ANY OTHER
PURPOSES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: COC
Flash Point: =240.6C, 465.F
Lower Limits: NOT DETERM
Upper Limits: NOT DETERM
Extinguishing Media: USE DRY CHEMICAL, FOAM, WATER FOG, CARBON DIOXIDE.
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE BUT MAY BE USED TO COOL
CONTAINERS EXPOSED TO HEAT OR FLAME. CAUTION SHOULD BE EXERCISED WHEN USING
WATER OR FOAM AS FROTHING MAY OCCUR.
Unusual Fire/Explosion Hazard: DENSE SMOKE MAY BE GENERATED WHILE BURNING.
TOXIC FUMES, GASES OR VAPORS MAY EVOLVE ON BURNING. HEAVY FLAMMABLE VAPORS
MAY TRAVEL TO LOW AREAS AND IGNITE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE REQUIRED IF AIRBORNE CONCENTRATIONS ARE MAINTAINED
BELOW THRESHOLD LIMITS. OTHERWISE A RESPIRATORY PROTECTION PROGRAM MEETING
OSHA REQUIREMENTS MUST BE FOLLOWED. WHERE MISTING MAY OCCUR, WEAR AN
MSHA/NIOSH APPROVE HALF-MASK FORM DUST/ MIST AIR-PURIFYING RESPIRATOR.
Ventilation: LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION AS REQUIRED TO
MAINTAIN EXPOSURE LEVELS.
Other Protective Equipment: CHEMICAL RESISTANT CLOTHING AS NECESSARY TO PREVENT
SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE.
Work Hygienic Practices: WASH HANDS THOROUGHLY WITH SOAP AND WATER BEFORE
EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMINATED
CLOTHES BEFORE REUSE. DISCARD CONTAMINATED LEATHER ARTCILES.
Supplemental Safety and Health: COMSUMPTION OF FOOD AND DRINK SHOULD BE AVOIDED
IN WORK AREAS WHERE PRODUCT IS PRESENT.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: V6
B.P. Text: NOT GIVEN
M.P/F.P Text: NOT GIVEN
Decomp Text: UNKNOWN
Vapor Pres: NEGLIGIBLE
Vapor Density: > 1
Spec Gravity: 0.889
Evaporation Rate & Reference: NEGLIGIBLE
Solubility in Water: NEGLIGIBLE
Appearance and Odor: DARK BROWN, CLEAR FLUID, MILD PETROLEUM HYDROCARBON ODOR
Percent Volatiles by Volume: NIL
Corrosion Rate: UNKNOWN
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID HIGH TEMPERATURES AND PRODUCT
CONTAMINATION.
Materials To Avoid: AVOID CONTACT WITH ACIDS AND OXIDIZING MATERIALS.
Hazardous Decomposition Products: OXIDES OF CARBON ZINC, CALCIUM, MAGNESIUM,
PHOSPHORUS AND SULFUR, HYDROGEN SULFIDE, ALKYL MERCAPTANS, OTHER SULFIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE. WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ORAL AND DERMAL TOXICIRY: NOT DETERMINED. INHALATION
TOXICITY: ON RARE OCCASIONS, PROLONGED AND REPEATED EXPOSURE TO ALL MISTS
POSES A RISK OF PULMONARY DISEASE SUCH AS CHRONIC LUNG INFLAMMATION. DERM AL
SENSITIZATION: PROLONGED OR REPEATED CONTACT MAY MAKE SKIN MORE SENSITIVE TO
OTHER SENSITIZERS. MUTAGENICITY: THIS PRODUCT CONTAINS ZINC ALKYL
DITHIOPHOSPHATES (ZDP). SEVERAL ZDPS HAVE BEEN REPORTE D TO HAVE WEAK
MUTAGENICITY ACTIVITY IN CULTURED MAMMALIAN CELLS BUT ONLY AT CONCENTRATIONS
THAT WERE TOXIC TO THE TEST CELLS.
=======================================================
Ecological Information
=======================================================
Ecological: THIS MATERIAL MAY BE TOXIC TO AQUATIC ORGANISMS AND SHOULD BE KEPT
OUT OF SEWAGE AND DRAINAGE SYSTEMS AND ALL BODIES OF WATER. ENVIRONMENT FATE:
NO DATA AVAILABLE.
=======================================================
=======================================================
Transport Information: NOT REGULATED BY DOT.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: CLEAN WATER ACT/OIL POLLUTION ACT: UNDER SEC 311 OF
CWA (40CFR 110) 7 OIL POLLUTION ACT OF 1990, THIS MATERIAL IS CONSIDERED AN
OIL. ANY SPILL OR DISCHARGES THAT PRODUCE A VISIBLE SHEEN OR FILM ON SUR FACE
OF WATER, OR IN WATERWAYS, DICHES OR SEWERS LEADING TO SURFACE WATER MUST BE
REPORTED. CONTACT NRC AT 800-424-8802. SEC 313 TOXIC CHEMICALS: ZN <0.1%.
SEC 311/312 HAZARD CATEGORIES: ACUTE=YES; DELAYED=NO; FIRE=NO; REACTIVITY
AND FIRE=NO.
CERCLA: RQ= ND.
Federal Regulatory Information: TSCA INVENTORY: ALL COMPONENTS OF THIS PRODUCT
ARE LISTED ON THE TSCA INVENTORY.
=======================================================
Other Information
=======================================================
Other Information: NFPA RATINGS: HEALTH =1; FIRE =1; REACITVITY =0.
=======================================================
Transportation Information
=======================================================
Trans ID NO: 156318
Product ID: GARDFLEET MC 30 MIL-PRF-2104G
Review Date: 03/19/2001
Net Unit Weight: 1 QT
Multiple KIT Number: 0
Unit Of Issue: QT
Container QTY: G
Type Of Container: QUARTS
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: GARDFLEET MC 30 MIL-PRF-2104G
Cage: 1RU67
Company Name: UNIMARK OIL CO LLC
Street: 2727 ROE LANE
Zipcode: 66103-1543
Label Required IND: Y
Date Of Label Review: 03/19/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: EYE :NOT EXPECTED TO CAUSE IRRITATION. MAY CAUSE MILD
DISCOMFORT. SKIN:NOT EXPECTED TO CAUSE IRRITATION. PROLONGED CONTACT MAY LEAD
TO AN ALLERGIC SKIN SENSITIZATION. INHALATION: VAPORS FROM HOT MATER IAL MAY
CAUSE NON-SPECIFIC DISCOMFORT. INGESTION: RELATIVELY NON-TOXIC UNLESS LUNG
ASPIRATION OCCURS. ASPIRATION MAY LEAD TO CHEMICAL PHEUMONITIS.
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:CRONALITH LIQUID BLENDER EQUALIZER,CLBE
CAGE:19898
CAGE:18873
CAGE:19898
============= Composition/Information on Ingredients =============
Ingred Name:DIETHANOLAMINE (SARA III)
CAS:111-42-2
RTECS #:KL2975000
Fraction by Wt: 8.0%
OSHA PEL:3 PPM
ACGIH TLV:3 PPM; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SODIUM SULFITE;CAS #7758-83-7
CAS:7757-83-7
RTECS #:WE2150000
Fraction by Wt: 3.0%
ACGIH TLV:UNK
Ingred Name:POTASSIUM CARBONATE;CAS #584-08-7
CAS:584-08-7
RTECS #:TS7750000
Fraction by Wt: 20.0%
Ingred Name:AQUEOUS SOLUTION,HAZARD UNKNOWN,UNIDENTIFIED;WT % BY
DIFFERENCE 69%.
Fraction by Wt: 69.0%
===================== Hazards Identification =====================
Effects of Overexposure:CAUSES EYE BURNS & SKIN IRRITATION.
======================= First Aid Measures =======================
First Aid:IF INGESTED,CALL PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:CO*2, FOAM, DRY CHEM.
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO CHEM SEWER W/H*20.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
Other Precautions:AVOID CONTAT W/EYES,SKIN & CLOTHING.WASH THOROUGHLY
AFTER HANDLING.USE W/ADEQUATE VENTILATION.WASH CLOTHES BEFORE
REUSE.AVOID BREATHING MIST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED
Ventilation:LOCAL EXHAUST TO MAINTAIN ADEQUATE VENTILATION
Supplemental Safety and Health
MSDS FM MFR DATED 4/12/76-L WHICH IS BEING REVISED BY MFR & CAN BE
OBTAINED ON REQUEST IN 1985;PH OF SOLUTION IS:11.5
================== Physical/Chemical Properties ==================
HCC:B3
Boiling Pt:B.P. Text:>212F
Vapor Pres:UNK
Vapor Density:UNK
Spec Gravity:1.328
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID W/AMMONIA ODOR.
Percent Volatiles by Volume:UNK
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE KNOWN
==================== Disposal Considerations ====================
Waste Disposal Methods:MFR NOTES,FLUSH TO CHEMICAL OR INDUSTRIAL
PROCESS SEWER.
| 1 |
eyes_protection_mandatory
|
=======================================================
Product ID: PART A POLY 74 SERIES
Cage: 0BVZ7
Box: 384
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 0BVZ7
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ISOCYANATE VAPORS MAY CAUSE IRRITATION OF RESPIRATORY
SYSTEM & IN SOME INDIVIDUALS SENSITIZATION LEADING TO ASTHMA-TYPE SPASMS.
FOR MORE INFORMATION ON TDI, CONSULT OSHA PUBLICATION 2248/TDI MFR'S MSD S
AVAILABLE FROM POLYTEK UPON REQUEST.
Explanation Of Carcinogenicity: SEE "LR" VERSION FOR ADDITIONAL INFORMATION (FP
N). (SEE ING 5)
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST:CALL MD IMMEDIATELY (FP N). EYE:FLUSH W/PLENTY OF WATER FOR
AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN:WIPE OFF. WASH W/RUBBING
ALCOHOL OR WATERLESS HAND CLEANER FOLLOWED BY SOAP & WATER. INHAL:REMOVE
TO FRESH AIR. TREAT SYMPTOMATICALLY.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SCRAPE & SOAK UP ON ABSORB MATL. NEUT W/HOUSEHOLD
AMMONIA, CLEAN UP W/STRONG LIQ CLEANER/SOAP & WATER BEFORE MATL REACTS
W/MOISTURE IN AIR TO FORM A DFCLT TO REMOVE RUBBER. DO NOT SEAL CONTAM CNTNRS
A S CARBON DIOXIDE IS GENERATED UPON CONTW/(SUPDAT)
Neutralizing Agent: HOUSEHOLD AMMONIA.
Waste Disposal Methods: NEUTRALIZED OR MOISTURE CURED MATERIAL IS
NON-HAZARDOUS. DISPOSE OF PER LOCAL, STATE & FEDERAL REGULATIONS.
Handling And Storage Precautions: AVOID SKIN & EYE CONTACT. USE IN A WELL
VENTILATED AREA. VAPOR CAN IRRITATE RESPIRATORY SYSTEM & EYES PRIOR TO
CURING.
Other Precautions: MAINTAIN WORK AREA BELOW PEL. USE W/ADEQUATE AIR CIRCULATION
TO AVOID VAPOR CONCENTRATION.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TOC
Flash Point Text: 270F,132C
Extinguishing Media: WATER FOG, FOAM, CO*2.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). AVOID BREATHING COMBUSTION PRODUCTS.
Unusual Fire/Explosion Hazard: NONE KNOWN.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IN THE ABSENCE OF GOOD VENTILATION, UNDER EMERGENCY
SITUATION OR FOR HIGH CONCENTRATIONS, NIOSH/MSHA APPROVED SELF-CONTAINED AIR
SUPPLIED RESP PROT IS RECOMMENDED. NIOSH/MSHA APPROVED RESP SHOULD BE E
QUIPPED W/ORGANIC VAPOR CARTRIDGES.
Ventilation: MECHANICAL VENTILATION IS RECOMMENDED IF PRODUCT IS USED IN
CONFINED AREA OR IS SPRAYED OR HEATED.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NOTE:USERS OF THE "L" VERSION SHOULD CONSULT
THE "LR" VERSION FOR ADDNL INFO (FP N). CNDTNS (STAB):OF EXPOSED MASS. SPILL
PROC:MOISTURE & DANGEROUS PRESSURE BUILDUP COULD OCCUR.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1
Solubility in Water: NIL-REACTS SLOWLY
Appearance and Odor: CLEAR TO AMBER SYRUP; SLIGHT SWEET ODOR.
Percent Volatiles by Volume: NIL
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: UPON EXPOS TO MOISTURE IN AIR, PART A FORMS AN
INERT NON-HAZ RUB IN SEVERAL DAYS/LONGER, DEPENDING ON THICKNESS (SUPDAT)
Materials To Avoid: WATER, AMINES, ALCOHOLS, BASIC COMPOUNDS.
Hazardous Decomposition Products: WHEN OVEREHEATED OR BURNED: TDI VAPORS, NO*X,
CO*2, HCN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: PART A POLY 74 SERIES
Cage: 0BVZ7
Company Name: POLYTEK DEVELOPMENT CORP
Street: UNKNOWN
Zipcode: 08888
Label Required IND: Y
Date Of Label Review: 03/17/1994
Status Code: C
Label Date: 03/17/1994
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: USE IN WELL VENTILATED AREA. AVOID SKIN & EYE
CONTACT. ACUTE:ISOCYANATE VAPORS MAY CAUSE IRRITATION OF RESPIRATORY SYSTEM
& IN SOME INDIVIDUALS SENSITIZATION LEADING TO ASTHMA-TYPE SPASMS. FOR
MORE IN FORMATION, CONSULT OSHA PUBLICATION 2248/TDI MFR'S MSDS AVAILABLE
FROM POLYTEK UPON REQUEST. CHRONIC:CANCER HAZARD. CONTAINS MATERIAL WHICH IS
LISTED AS A CARCINOGEN (FP N).
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:PNEUMATIC/HYDRAULIC SEAL 545, 54505
Preparer's Name:STEPHEN REPETTO
CAGE:62377
CAGE:62377
============= Composition/Information on Ingredients =============
Ingred Name:HEXANOIC ACID, 2-ETHYL-, DIESTER WITH TETRAETHYLENE GLYCOL;
(POLYGLYCOL DIOCTANOATE)
CAS:18268-70-7
RTECS #:MD7710000
Fraction by Wt: 40-45%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POLYETHYLENE GLYCOL DIMETHACRYLATE; (POLYGLYCOL
DIMETHACRYLATE)
CAS:25852-47-5
Fraction by Wt: 20-25%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:METHACRYLIC ACID, 2-HYDROXYETHYL ESTER; (HYDROXYALKYL
METHACRYLATE)
CAS:868-77-9
RTECS #:OZ4725000
Fraction by Wt: 20-25%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:HYDROPEROXIDE, ALPHA, ALPHA-DIMETHYLBENZYL-; (CUMENE
HYDROPEROXIDE) (SARA 313) (CERCLA)
CAS:80-15-9
RTECS #:MX2450000
Fraction by Wt: 3-5%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:N,N-DIALKYLTOLUIDINE
CAS:613-48-9
Fraction by Wt: 1-3%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ACETIC ACID, 2-PHENYLHYDRAZIDE;
(1-ACETYL-2-PHENYLHYDRAZINE)
CAS:114-83-0
RTECS #:AJ2900000
Fraction by Wt: 0.1-1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MALEIC ACID (CERCLA)
CAS:110-16-7
RTECS #:OM9625000
Fraction by Wt: 0.1-1%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:1,2-BENZISOTHIAZOLIN-3-ONE, 1,1-DIOXIDE; (SACCHARIN) (SARA
313) (CERCLA)
CAS:81-07-2
RTECS #:DE4200000
Fraction by Wt: 0.1-1%
OSHA PEL:N/K
ACGIH TLV:N/K
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:SILICA, AMORPHOUS (FUMED); (SILICA, AMORPHOUS TREATED)
CAS:112945-52-5
RTECS #:VV7310000
Fraction by Wt: 0.1-1%
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:VOLATILE ORGANIC COMPOUND (EPA METHOD 24):31.5%
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50(ORAL):>5000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE DERMATITIS ON PROLONGED
CONTACT IN SENSITIVE INDIVIDUALS. TARGET ORGAN & OTHER HLTH
EFTS:POLYGLYCOL DIMETHACRYLATE:SKIN ALLERGEN. HYDROXYALKYL
METHACRYLATE:NERV. CUMENE HYDROPEROXIDE:IRRITAN T. MUTAGEN. NERVOUS
SYSTEM. MALEIC ACID:GI IRRITANT. NERVOUS SYSTEM. SACCHARIN:MUTAGEN.
SILICA, AMORPHOUS TREATED:LUNG.
Explanation of Carcinogenicity:SACCHARIN:IARC MONOGRAPHS, SUPP, VOL 7,
PG 334, 1987:GROUP 2B.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE
O*2/ARTF RESP) . INGESTION:DO NOT INDUCE VOMITING. KEEP INDIVIDUAL
CALM. OBTAIN MEDICAL ATTENTION. SKIN:FLUSH WITH WATER. EYES:FLUSH
WITH WATER FOR AT LEAST 15 MINUTES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>200F,>93C
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP IN AN INERT ABSORBENT. STORE IN A
PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BELOW 110F. AVOID PROLONGED SKIN
CONTACT.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NOT APPLICABLE.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:<5 @ 80F
Spec Gravity:1.2 @ 80F
Solubility in Water:SLIGHT
Appearance and Odor:PURPLE LIQUID WITH A MILD ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HAZARDOUS PRODUCTS FORMED BY FIRE OR
THERMAL DECOMPOSITION:IRRITATING ORGANIC VAPORS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . INCINERATE FOLLOWING EPA AND LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:AIR; COMPRESSED AIR, BREATHING QUALITY
CAGE:00742
CAGE:00742
CAGE:2X264
CAGE:53655
============= Composition/Information on Ingredients =============
Ingred Name:AIR
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:AIR IS NON-TOXIC AND NO EXPOSURE
LIMITS HAVE BEEN ESTABLISHED. EXPOSURES TO HIGH PRESSURES OF AIR
WHERE THE PARTIAL PRESSURES OF OXYGEN IS IN EXCESS OF TWO
ATMOSPHERES MAY PRODUCE A VARIETY OF CENTRAL NERVOUS SYSTEM
MANIFESTATIONS.
Explanation of Carcinogenicity:AIR IS NOT LISTED AS A CARCINOGEN BY
NTP, IARC OR OSHA.
Effects of Overexposure:HIGH PRESSURE SITUATIONS: TINGLING OF TOES &
FINGERS, VISUAL & ACOUSTICAL DISTURBANCES, ABNORMAL SENSATIONS,
IMPAIRED COORDIANTION, CONFUSION, MUSCLE TWITCHING, EPILEPTIC
SEIZURES. SEVERE HAZARDS MAY BE PRESENT WHEN CONFUSION & IMPAIRED
JUDGEMENT LEAD TO OPERATIONAL ERRORS. MAY ALSO RESULT IN NITROGEN
NARCOSIS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:FACILITIES AT WHICH AIR IS BREATHED UNDER PRESSURE SHOULD BE
PREPEARED TO DEAL WITH ILLNESS RELEATED TO A HYPERBARIC
ENVIRONMENT. DECOMPRESSION EQUIPMENT MAY BE REQUIRED.
===================== Fire Fighting Measures =====================
Extinguishing Media:NOT APPLICABLE. DLA-HMIS: USE MEDIA APPROPRIATE FOR
SURROUNDING FIRE.
Fire Fighting Procedures:NOT APPLICABLE. DLA-HMIS: WEAR SELF-CONTAINED
BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTETCIVE GEAR. COOL
FIRE EXPOSED CYLINDERS WITH WATER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:NO HAZARD.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CYLINDERS AWAY FROM SOURCES OF
HEAT. STORE OUT OF HIGH TRAFFIC AREAS. VALVE CAPS WILL REMAIN IN
PLACE ON CYLINDERS NOT CONNECTED FOR USE.
Other Precautions:SEGREGATE EMPTY & FULL CYLINDERS. STORAGE AREAS
SHOULD BE FREE OF COMBUSTIBLE MATERIAL. AVOID EXPOSURE TO AREAS
WHERE SALT OR OTHER CORROSIVE CHEMICALS ARE PRESENT. STORE
COMPRESSED GAS CYLINDERS WITH VALVE UP.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:NONE NORMALLY REQUIRED.
Other Protective Equipment:SAFETY TOE SHOES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
COMPRESSED GAS CYLINDERS CONTAIN GAS UNDER EXTREMELY HIGH PRESSURE AND
SHOULD BE HANDLED WITH CARE. USE A PRESSURE REDUCING REGULATOR WHEN
CONNECTING TO LOWER PRESSURE EQUIPMENT AND PIPING SYSTEMS. SE CURE
CYLINDERS WHEN IN USE.
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:B.P. Text:-318F,-194C
Melt/Freeze Pt:M.P/F.P Text:-351F,-213C
Vapor Density:0.0752
Spec Gravity:1.00
Evaporation Rate & Reference:NONE SPECIFIED BY MFR
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GASEOUS AIR IS ODORLESS AND COLORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:AVOID THE USE OF OIL IN SYSTEMS AT FULL
CYLINDER PRESSURE.
Hazardous Decomposition Products:NONE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:A.O. MAGIC SANITIZING MIST
CAGE:05732
CAGE:02622
CAGE:05732
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL ALCOHOL (ETHANOL)
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: >50%
Other REC Limits:1900 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
Ingred Name:ISOBUTANE
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: >10%
Other REC Limits:1000 PPM
OSHA PEL:1800 MG/CUM
ACGIH TLV:1000 PPM
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: >10%
Other REC Limits:1800 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9192
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: IRRITATION.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH LIBERALLY WITH WATER.
===================== Fire Fighting Measures =====================
Flash Point:80F
Extinguishing Media:WATER OR FIRE EXTINGUISHER
Fire Fighting Procedures:CONVENTIONAL
Unusual Fire/Explosion Hazard:AEROSOL CANS MAY RUPTURE WHEN EXPOSED TO
TEMPERATURES EXCEEDING 120F. DON'T PUNCTURE OR INCINERATE.
================== Accidental Release Measures ==================
Spill Release Procedures:SAFE IN CASE OF SPILL
======================Handling and Storage ======================
Handling and Storage Precautions:STORE <120F. KEEP OUT OF REACH OF
CHILDREN. DON'T SPRAY IN EYES.
============= Exposure Controls/Personal Protection =============
Ventilation:LOCAL EXHAUST/MECHANICAL
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:185F
Vapor Pres:68
Vapor Density:>AIR
Spec Gravity:0.96
Solubility in Water:COMPLETE
Appearance and Odor:ALCOHOL ODOR.
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:STORE <120F.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:CONVENTIONAL
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:SN60 366
Preparer's Name:ROBERT L. GILBERT
CAGE:03051
CAGE:03051
============= Composition/Information on Ingredients =============
Ingred Name:ROSIN ACID; (ROSIN). MAY DECOMP DURING SOLDERING TO FORM
FORMALDEHYDE, TLV:0.1 MG/M3 OR TURPENTINE, TLV:100 PPM (MFR)
CAS:8050-09-7
Fraction by Wt: 2-3%
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 55-60%
OSHA PEL:0.05 MG/M3
ACGIH TLV:0.15 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TIN
CAS:7440-31-5
RTECS #:XP7320000
Fraction by Wt: 35-40%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:WEAKNESS, VOMITING, LOSS OF
APPETITE, CONVULSIONS, STUPOR AND POSSIBLY COMA. CHRONIC:WEAKNESS,
INSOMNIA, HYPERTENSION, SLIGHT IRRITATION OF EYES, HEADACHE,
POSSIBLE PARALYSIS. CHRONIC OVEREXPOSU RE TO LEAD MAY RESULT IN
DAMAGE TO BLOOD FORMING, NERVOUS, URINARY AND REPRODUCTIVE SYSTEM.
(EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:LEAD AND CERTAIN LEAD COMPOUNDS:IARC GRP
2B. FORMALDEHYE:IARC GRP 2A, NTP GRP 2, ACGIH GRP A2, OSHA REG.
Effects of Overexposure:HLTH HAZ:FORMALDEHYDE FORMED DURING
DECOMPOSITION OF ROSIN FLUX IS LISTED AS A SUPECTED HUMAN
CARCINOGEN BY ACGIH. DUST, VAPOR/FUMES MAY IRRITATE SKIN, EYES,
RESPIRATORY SYSTEM.
Medical Cond Aggravated by Exposure:NOTE TO MD:LEAD AND ITS INORGANIC
COMPOUNDS ARE NEUROTOXINS WHICH MAY PRODUCE NEUROPATHY. ROSIN IS AN
ALLERGEN.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH COPIOUS QUATITIES OF WATER FOR AT LEAST 15
MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN:WASH WITH SOAP AND
WATER. INHAL:REMOVE FROM EXPOSURE. GET MEDICAL ATTENTION IF
EXPERIENCING EF FECTS OF OVEREXPOSURE. INGEST:GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DO NOT USE WATER ON FIRES WHERE MOLTEN
METAL IS PRESENT. HIGH TEMPERATURES MAY PRODUCE HEAVY METAL FUMES,
DUST AND/OR VAPOR.
================== Accidental Release Measures ==================
Spill Release Procedures:PARTICULATE MATTER SHOULD BE STORED IN DRY
CONTAINERS FOR LATER DISPOSAL. DUST MATERIALS SHOULD BE VACUUMED OR
WET SWEPT. DO NOT USE COMPRESSED AIR OR DRY SWEEPING AS A MEANS OF
CLEANING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:WASH HANDS WITH SOAP AND WATER AFTER
HANDLING SOLDERS. STORE IN DRY AREAS. AVOID SKIN CONTACT. AVOID
BREATHING SMOKE DURING SOLDERING.
Other Precautions:NONE KNOWN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR AS SPECIFIED
BY 29 CFR 1910.1025 (F) IF EXPOSURE EXCEEDS PEL.
Ventilation:USE LOCAL EXHAUST TO REMOVE SMOKE FROM BREATHING AREA.
MEHANICAL (GENERAL) VENTILATION IS ADEQUATE.
Other Protective Equipment:PERSONAL CLOTHING AND SHOES SHOULD BE
PROTECTED FROM CONTAMINATION.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE IN WORK AREAS. WASH
HANDS THOROUGHLY BEFORE EATING OR SMOKING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:361F,183C
Spec Gravity:8 @ 25C
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY METAL WITH NEUTRAL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:HIGH TEMPERATURES MAY PRODUCE HEAVY
METAL FUMES, DUST AND/OR VAPORS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF HAZARDOUS WASTE IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. CONSULT A LICENSED HAZARDOUS
WASTE COMPANY.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:0054-3555 METHADONE HYDROCHLORIDE ORAL SOLUTION USP 5MG/5ML
CAGE:FO676
CAGE:34471
CAGE:FO676
============= Composition/Information on Ingredients =============
Ingred Name:METHADONE HYDROCHLORIDE *95-1*
CAS:1095-90-5
RTECS #:MJ6300000
Ingred Name:ALCOHOLS (TYPE NOT SPECIFIED)
Fraction by Wt: 8%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXCESS INGESTION MAY CAUSE
RESPIRATORY/CIRCULATORY DEPRESSION, RESPIRATORY/CARDIAC ARREST,
BRADYCARDIA, DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:LIGHTHEADEDNESS, DIZZINESS, SEDATION, NAUSEA,
VOMITING, SWEATING, SHOCK, EUPHORIA, DYSPHORIA, WEAKNESS, HEADACE,
INSOMNIA, AGITATION, DISORIENTATION, VISUAL DISTURBANCES, DRY
MOUTH, ANOREXIA, CONSTIPA TION, BILIARY TRACT SPASM, FLUSHING,
PALPITATION, FAINTNESS, SYNCOPE, URINARY PROBLEMS, RASHES.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: FLUSH W/WATER. EYES:
FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB & CLEAN AREA.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A TIGHTLY CLOSED CONTAINER
AWAY FROM DIRECT SUNLIGHT. KEEP OUT OF REACH OF CHILDREN. METHADONE
HYDROCHLORIDE MAY BE HABIT FORMING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:NORMAL ROOM VENTILATION.
Other Protective Equipment:NONE REQUIRED
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:COMPLETE
Appearance and Odor:ORANGE LIQUID W/LEMON FLAVOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 0 |
eyes_protection_not_mandatory
|
===================== Product Identification =====================
Product ID:LEMON PLEDGE, 10338-32
Preparer's Name:TERRY A MEYERS
CAGE:GO109
CAGE:GO109
CAGE:32204
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS; (ISOPARAFFINIC HYDROCARBON SOLVENT)
CAS:64475-85-0
RTECS #:PY8240000
Fraction by Wt: 10-20%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DOW CORNING 360 FLUID; (SILICONE)
CAS:63148-62-9
RTECS #:JJ6484500
Fraction by Wt: 3-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BUTANE
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 3-5%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 3-5%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 60-70%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC COMPOUND AS PACKAGED, MINUS H*2O:
ISOPARAFFINIC HYDROCARBON SOLVENT, BUTANE, PROPANE.
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:THEORETICAL VOLATILE ORGANIC COMPOUND (LB/GAL):1.98
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:DIRECT CONTACT OF PRODUCT WITH
EYES CAN CAUSE IRRITATION. CHRONIC:NONE LISTED BY MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:FLUSH W/COPIOUS
AMOUNTS OF WATER. CALL MD . EYES:FLUSH WITH WATER FOR AT LEAT 15
MINUTES. IF IRRITATION PERSISTS, SEEK MEDICAL AID. TREAT
SYMPTOMATICALLY.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:<20F,<-7C
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT . NORM FIRE FIGHT PROC MAY BE USED. FIGHT FIRE FROM MAX
DIST/PROTECTED AREA. COOL & USE (SUPDAT)
Unusual Fire/Explosion Hazard:NO SPECIAL HAZARDS KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. RINSE AFFECTED
AREA THOROUGHLY WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CAUTION:CONTENTS UNDER PRESSURE.
FLAMMABLE. DO NOT USE NEAR FIRE/FLAME. DO NOT SET/STORE CONTAINER
WHERE TEMPERATURE EXCEEDS 120F AS CNTNR MAY BURST.
Other Precautions:DO NOT PUNCTURE OR INCINERATE. DO NOT SPRAY OR USE ON
FLOORS. KEEP OUT OF REACH OF CHILDREN. DO NOT PRESSURIZE, CUT,
HEAT, WELD OR EXPOSE CONTAINER TO FLAME; EXPLOSION COULD OCCUR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO SPECIAL REQUIREMENTS UNDER NORMAL USE
CONDITIONS. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN .
Ventilation:GENERAL ROOM VENTILATION ADEQUATE.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FL PT:<20F,<-7C (PROPELLANT). FIRE FIGHT PROC:CAUTION WHEN
APPROACHING/HANDLING FIRE-EXPOSED CONTAINERS.
================== Physical/Chemical Properties ==================
Spec Gravity:0.9 (H*2O=1)
Solubility in Water:MODERATE
Appearance and Odor:DISPENSED AS A SPRAY MIST WITH LEMON ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:WHEN EXPOSED TO FIRE, PRODUCES NORMAL
PRODUCTS OF COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . RECYCLE EMPTY AEROSOL CAN TO NEAREST STEEL RECYCLING
CENTER. USE UP PACKAGE OR GIVE TO SOMEONE WHO CAN.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ANDEROL 500 SYNTHETIC COMPRESSOR OIL
Preparer's Name:NOT PROVIDED
CAGE:TO156
Contract Num:SP0450-01-M-LA81
CAGE:82956
CAGE:TO156
============= Composition/Information on Ingredients =============
Ingred Name:N-PHENYL-1-NAPHTHYLAMINE
CAS:90-30-2
RTECS #:QM4500000
Fraction by Wt: N/AV
Other REC Limits:NOT PROVIDED
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:BASED ON DATA AVAILABLE TO ANDEROL,
THIS PRODUCT IS NOT HAZARDOUS UNDER OSHA HAZARD COMMUNICATION (29
CFR 1910.1200). ACUTE EFFECTS ON HUMAN: NOT AVAILABLE. CHRONIC
EFFECTS ON HUMAN: NOT APPLICABLE.
Explanation of Carcinogenicity:NOT PROVIDED
Effects of Overexposure:NO HAZARD EXPECTED IN NORMAL USE.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER. OBTAIN
MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. SKIN: WASH
WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INHALTION:REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET IMMEDIATE MEDICAL
ATTENTION.INGESTION: NO ADVERSE EFFECTS EXPECTED BY THIS ROUTE OF
EXPOSURE. IF SYMPTOM S DEVELOP GET MEDICAL ATTENTION. NEVER GIVE AN
UNCONSCIOUS PERSON ANYTHING TO INGEST. SEEK MEDICAL ATTENTION. IF
SWALLOWED DO NOT INDUCE VOMTING.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=232.2C, 450.F
Extinguishing Media:WATER SPRAY OR FOG, FOAM, CARBON DIOXIDE OR DRY
CHEMICAL.
Fire Fighting Procedures:AS WITH ANY FIRE, WEAR FULL PROTECTIVE GEAR
AND NIOSH-APPROVED (OR EQUIVALENT) SELF-CONTAINED BREATHING
APPARATUS TO AVOID INHALATION OF HAZARDOUS DECOMPOSTION PRODUCTS OR
SMOKE.
Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST DUE TO EXTREME HEAT;
COOL WITH WATER SPRAY. FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION
OF HAZARDOUS DECOMPOSITION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. ABSORB SPILL WITH INERT
MATERIAL AND PLACE IN A CHEMICAL WASTE CONTAINER. OBEY RELEVANT
LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS. DO NOT CONTAMINATE
ANY LAKES, STREAMS, PONDS, GRO UNDWATER OR SOIL. USE PERSONAL
PROTECTIVE EQUIPMENT.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP
CONTAINERS CLOSED WHEN NOT IN USE. KEEP AWAY FROM OPEN FLAMES AND
HIGH TEMPERATURES.
Other Precautions:AVOID BREATHING VAPOR OR MIST. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. KEEP CONTAINER DRY. AFTER HANDLING, ALWAYS
WASH HANDS THOROUGHLY WITH SOAP AND WATER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS, WEAR A NIOSH APPROVED RESPIRATOR TO PREVENT
OVEREXPOSURE IN ACCORDANCE WITH 29 CFR 1910.134. USE EITHER AN
ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING RESPIRATOR FOR
ORGANIC VAPORS AND PARTICULATES.
Ventilation:ADEQUATE
PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE SKIN CONTACT.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K =
UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED.
================== Physical/Chemical Properties ==================
HCC:V6
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:>348.9C, 660.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:<0.02 @ 300F
Vapor Density:>1
Spec Gravity:0.96
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:<1 (BUTYL ACETATE = 10
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT AMBER OIL - MILD ODOR
Percent Volatiles by Volume:NOT PROVIDED
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS
Stability Condition to Avoid:HEAT AND FLAME
Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON
DIOXIDE.
=================== Toxicological Information===================
Toxicological Information:NOT AVAILABLE
===================== Ecological Information =====================
Ecological:NOT PROVIDED
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS. INCINERATION IS THE PREFERRED
METHOD.
=================== MSDS Transport Information ===================
Transport Information:DOT: NOT A DOT CONTROLLED MATERIAL.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT DOES NOT CONTAIN ANY MATERIAL
WHICH IS SUBJECT TO THE ANNUAL REPORTING REQUIREMENTS UNDER SECTION
313 OF SARA, TITLE I I I.
Federal Regulatory Information:THE COMPONENTS OF THIS PRODUCT ARE
LISTED ON THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES.
State Regulatory Information:NOT PROVIDED
======================= Other Information =======================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:DURSBAN ANT & TURF GRANULES
CAGE:SAGRC
CAGE:SAGRC
============= Composition/Information on Ingredients =============
Ingred Name:PHOSPHOROTHIOIC ACID, O,O-DIETHYL
O-(3,5,6-TRICHLORO-2-PYRIDYL) ESTER; (CHLORPYRIFOS) (CERCLA) SOL
IN H*2O: 1.2 PPM
CAS:2921-88-2
RTECS #:TF6300000
Fraction by Wt: 0.5%
OSHA PEL:0.2 MG/M3, S
ACGIH TLV:0.2 MG/M3, S
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:INERT INGREDIENTS
Fraction by Wt: 95.5%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE EYE IRRITATION. CORNEAL
INJURY IS POSSIBLE. CHOLINERGIC EFFECTS, DIZZINESS, NAUSEA,
ABDOMINAL CRAMPS, PINPOINT PUPILS. IF SYMPTOMS PERSIST SEE MD.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH EYES W/WATER FOR AT LEAST 15 MIN & GET MED ATTN
IF IRRIT PERSISTS. SKIN: WASH THORO W/SOAP & WATER & CHANGE TO
FRESHLY LAUNDERED CLTHG. SEE MD IF SKIN IRRIT OCCURS. INHAL: REMOVE
TO FRESH AIR & ADMIN ARTF RESP &/OR OXYGEN IF NEEDED. INGEST: WASH
MOUTH OUT W/WATER. DRINK 1 OR 2 GLASSES OF WATER & INDUCE VOMIT BY
TOUCHING FINGER IN BACK OF THROAT. CONTACT MD IMMED. NOTE TO MD:
(SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:388F,198C
Extinguishing Media:WATER FOG, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . WATER FOG TO COOL MATERIAL.
Unusual Fire/Explosion Hazard:TOXIC, IRRITATING, FLAMMABLE GASES MAY BE
FORMED. AVOID BREATHING SMOKE AND FUMES. CHLORPYRIFOS RAPIDLY
DECOMPOSES AT 160C TO 200C.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN AND SWEEP UP SPILLED MATERIAL. KEEP
DUST TO MINIMUM DURING CLEAN UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. DO NOT
CONTAM FEED OR FOOD. DO NOT STORE WHERE TEMPS WOULD EXCEED 120F. DO
NOT PLACE DAMAGED/LEAKING CNTNRS IN INVENTORY.
Other Precautions:DO NOT CONTAMINATE ANY BODY OF WATER. KEEP OUT OF
REACH OF CHILDREN OR DOMESTIC ANIMALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BREATHING DUST. UNDER DUSTY CONDITIONS
WEAR A NIOSH/MSHA APPROVED RESPIRATOR WITH PESTICIDE CARTRIDGE.
Ventilation:GENERAL. HANDLE WITH GOOD VENTILATION. HANDLE TO PRODUCE A
MINIMUM OF DUST.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
CLEAN FRESHLY LAUNDERED WORK CLTHG. DO NOT WEAR CONTAMINATED CLTHG.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CNDTNS TO AVOID: INTERNAL HEATING & DECOMPOSITION OF CHLORPYRIFOS.
FIRST AID PROC: ATROPINE BY INJECTION IS THE PREFERABLE ANTIDOTE.
================== Physical/Chemical Properties ==================
Solubility in Water:SEE ING 1
Appearance and Odor:LIGHT TAN, FINELY GROUND GRANULES WITH
HYDROCARBON/PEPPER LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
ALKALI MEDIA AND STRONG ACIDIC CONDITIONS.
Stability Condition to Avoid:UNSTABLE AT TEMPS ABOVE 120F. DO NOT ALLOW
TO GET WET IN STORAGE. MOISTURE MAY INDUCE FERMENTATION PRODUCING
(SUPDAT)
Hazardous Decomposition Products:HIGH TEMP DECOMPOSITION OF
CHLORPYRIFOS PRODUCES VOLATILE ORGANIC SULFIDES WHICH ARE
FLAMMABLE, ODOROUS & MAY BE TOXIC.
==================== Disposal Considerations ====================
Waste Disposal Methods:SPILLED PRODUCT THAT CAN NOT BE USED ACCORDING
TO LABELED INSTRUCTION MUST BE DISPOSED ACCORDING TO APPLICABLE
LOCAL, STATE AND FEDERAL PROCEDURES.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:CHAIRMAN CONCENTRATE PART B, 06-033
Kit Part:Y
CAGE:63160
CAGE:63160
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER)
CAS:111-76-2
RTECS #:KJ8575000
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES:CONTACT WILL BE PAINFUL AND
IRRITATING. SKIN:PROLONGED CONTACT MAY CAUSE IRRITATION.
INHALATION:MAY IRRITATE NOSE, THROAT AND CHEST. CHRONIC:ANIMAL
STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFTS ON THE
CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER ASSOC W/ADMIN OF
ETHYLENE GLYCOL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:MONOBUTYL ETHER (EGBE). (EXTRACTED
FROM DHHS (NIOSH) PUB NO. 90-118) .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEPARATE
EYELIDS TO BE SURE OF TOTAL COVERAGE. SKIN:REMOVE CONTAMINATED
CLOTHING. FLUSH WITH WATER. INHAL:REMOVE TO FRESH AIR. IF SYMPTOMS
PERSIST, CONTA CT PHYSICIAN IMMEDIATELY. INGEST:CONTACT PHYSICIAN
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER. CLASS
A, BC, OR ABC FIRE EXTINGUISHER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . WATER CAN BE USED TO COOL CONTAINERS
ADJACENT TO FIRE.
Unusual Fire/Explosion Hazard:PRESSURE MAY DEVELOP IN CLOSED CONTAINERS
IF TEMPERATURES OVER 195F ARE ACHIEVED.
================== Accidental Release Measures ==================
Spill Release Procedures:FOR MINOR SPILLS SOAK UP WITH SWEEPING
COMPOUND OR SAND AND TRANSFER TO A DISPOSAL CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE BETWEEN 40 AND 100 DEGREES IS
RECOMMENDED. BE SURE TO KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:DO NOT TAKE INTERNALLY OR INHALE VAPORS. AVOID EYE
CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY NEEDED. NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST:PREFERABLE. MECHANICAL (GENERAL):ACCEPTABLE.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NOT RELEVANT.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:195F,91C
Vapor Density:HVR/AIR
Spec Gravity:0.0987 @ 25C
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID WITH BUTYL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS OR ANYTHING REACTIVE WITH WATER.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURY, INCINERATE OR FLUSH TO SEWAGE DISPOSAL
SYSTEM IN ACCORDANCE WITH ALL FEDERAL, STATE, AND LOCAL REGULATION.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:BUTYL ALCOHOL,NORMAL
CAGE:EO303
CAGE:70829
CAGE:EO303
CAGE:0YED2
============= Composition/Information on Ingredients =============
Ingred Name:N-BUTYL ALCOHOL (SARA 313) (CERCLA)
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 99- 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) 790 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS,
RESPIRATORY & GI TRACTS. ACUTE- INHALATION CAUSES UPPER RESPIRATORY
IRRITATION. INGESTION CAUSES NARCOTIC EFFECTS, ABDOMINAL PAIN. MAY
CAUSE EYE & SKIN IRRITATION. CAN BE ABSORBED THROUGH SKIN.
CHRONIC- MAY CAUSE SKIN DRYNESS, HEARING LOSS, SENSE OF BALANCE,
LIVER & KIDNEY EFFECTS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, DROWSINESS,
NAUSEA, VOMITING, TEARING, DEFATTING OF SKIN, CRACKING, BURNING
SENSATION, PAIN, UNCONSCIOUSNESS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE/SKIN:
IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN.
INHALED: MOVE TO FRESH AIR. PROVIDE OXYGEN/CPR IF NEEDED. ORAL: IF
CONSCIOUS, INDUC E VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL
PERSONNEL. CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:99.0F,37.2C
Autoignition Temp:Autoignition Temp Text:649F
Lower Limits:1.4
Upper Limits:11.2
Extinguishing Media:USE FOAM, DRY CHEMICAL OR CARBON DIOXIDE. WATER
SHOULD BE USED TO COOL FIRE-EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. REMOVE SPILL WITH NON-FLAMMABLE
ABSORBENT SUCH AS SAND. PLACE IN CONTAINER FOR REUSE/RECYCLING OR
DISPOSAL. PREVENT LIQUID FRO M ENTERING SEWERS, WATERWAYS OR LOW
AREAS.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA, AWAY
FROM IGNITION SOURCES & INCOMPATIBLES. KEEP CONTAINER TIGHTLY
CLOSED.
Other Precautions:WARNING! FLAMMABLE. "EMPTY" CONTAINERS RETAIN RESIDUE
AND CAN BE DANGEROUS. FOLLOW LABEL INSTRUCTIONS. KEEP OUT OF REACH
OF CHILDREN. AVOID BREATHING VAPORS. DO NOT GET IN EYE, ON SKIN OR
ON CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED OR FOR SYMPTOMS OF OVER
EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR SUPPLIED
AIR RESPIRATOR. IN EMERGENCY, WEAR A NIOSH-APPROVED
POSITIVE-PRESSURE SELF-CONTAINED BREAT HING APPARATUS.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWERS SHOULD BE
AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:-128F,-89C
Vapor Pres:5 @ 68F
Vapor Density:3.6
Spec Gravity:0.87
Evaporation Rate & Reference:0.46 (N-BUTYL ACETATE=1)
Solubility in Water:9 ML/100ML @ 25C/77F
Appearance and Odor:CLEAR, COLORLESS LIQUID - MILD ALCOHOLIC ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, HALOGENS, ALUMINUM,
CHROMIUM TRIOXIDE, ALKALI METALS
Stability Condition to Avoid:HIGH HEAT, SPARKS, FLAMES, HOT SURFACES
AND OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:MAY EMIT CARBON MONOXIDE, CARBON
DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN AN APPROVED INCINERATOR/CONTRACT WITH
LICENSED CHEMICAL WASTE DISPOSAL SERVICE. DISCHARGE,
TREATMENT/DISPOSAL IS SUBJECT TO FEDERAL, STATE OR LOCAL LAWS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:FORM SEAL 245
CAGE:EO936
CAGE:16268
CAGE:EO936
============= Composition/Information on Ingredients =============
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)
CAS:584-84-9
RTECS #:CZ6300000
OSHA PEL:C,0.02 PPM/0.02 STEL
ACGIH TLV:0.005PPM/0.02STEL;93
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
Effects of Overexposure:SKIN:DRYING,POSS IRRIT.EYE:SEVERE
IRRIT.INHAL:HEADACHE,DIZZY,NAUSEA,VOMIT,UNCONSCIOUS(SEE SUPP DATA)
======================= First Aid Measures =======================
First Aid:EYE:IMMEDIATELY FLUSH W/PLENTY OF H*20 FOR @ LEAST 15 MIN.GET
MED ATTN. SKIN:GENTLY WIPE OFF MAJOR AMT OF SOLUTION & WASH
AFFECTED AREA W/SOAP & H*20 OR FLUSH W/H*20 FOR @ LEAST 15 MIN.
INHAL:REMOVE F ROM AREA.
===================== Fire Fighting Measures =====================
Flash Point:81F (27C)
Extinguishing Media:CO*2/DRY CHEM FOR SMALL FIRES,ORDINARY FORM FOR
LARGE FIRES.
Fire Fighting Procedures:WEAR SCBA.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:RECOVER THE MATERIAL WHICH CAN BE EASILY
PICKEDUP.FLUSH THE REMAINDER HEAVILY W/H*20.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS & FIRE.DO
NOT LEAVE CONTAINER OPEN.USE W/ADEQUATE VENT.AVOID PRLNG/RPTD
BREATHING OF VAP.AVOID EYE & SKIN CONTACT.
Other Precautions:FOR INDUSTRIAL USE ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED AIR SUPPLIED MASK FOR CONC
ABOVE 100 PPM.
Ventilation:SHOULD NOT BE USED IN ENCLOSED,UNVENTILATED AREA.
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER.
Supplemental Safety and Health
OVEREXP EFTS:POSS MUCOUS MEMBRANE IRRIT.SOME PEOPLE MAY DEVELOP
HYPERSENSITIVITY TO VAPORS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:290-311F
Vapor Density:> 1
Spec Gravity:0.985
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR LIQUID
Percent Volatiles by Volume:69
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
AOVID MIXING W/AMINES/H*20.AVOID HEAT & FIRES.
Hazardous Decomposition Products:TOLUENE DIISOCYANATE.THERMAL
DECOMP-CO*2,CO & NITROUS OXIDES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IAW FEDERAL,STATE & LOCAL
REGULATIONS.INCINERATE IN A FURNACE.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:6604548 MSIGG1-ECD
Preparer's Name:S HEALY
CAGE:FO645
CAGE:FO645
CAGE:6Z677
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM AZIDE, AZIDE *96-4*
CAS:26628-22-8
RTECS #:VY8050000
Other REC Limits:0.1 PPM
ACGIH TLV:C 0.29 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: NASAL IRRITATION. SKIN:
IRRITATION, ABSORPTION, ALLERGIC REACTION. EYES: IRRITATIONS,
CONJUNCTIVITIS. INGESTION: BRONCHIAL IRRITATION, RESPIRATORY
IRRITATION, RESPIRATORY FAILURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, FAINTNESS,
NAUSEA, LOW BLOOD PRESSURE, BLURRED VISION, SHORTNESS OF BREATH,
COLLAPSE, BRONCHITIS, PALPITATION, WEAKNESS & UNSTEADINESS, COMA,
CONVULSIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR.
IF BREATHING IS DIFFICULT GIVE OXYGEN. SKIN: WASH OFF THOROUGHLY
FOR 15 MINS. EYES: RINSE THOROUGHLY W/WATER & GIVE PLENTY OF WATER
TO DRIN K. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICALS SUCH AS AN SODIUM CARBONATE/SAND.
Fire Fighting Procedures:BURNING SODIUM AZIDE WILL EXPLODE IF WATER IS
USED AS AN EXTINGUISHING MEDIA. SCBA MUST BE WORN.
Unusual Fire/Explosion Hazard:MAY EXPLODE & RELEASE TOXIC FUMES UPON
HEATING. DON'T ALLOW TO CONTACT METALS AT HIGH TEMPS.
(SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:DILUTE W/RUNNING WATER BEFORE DISCHARGE.
DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM METALS & ACIDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:GENERAL/LOCAL EXHAUST TO MEET TLV REQUIREMENTS
Other Protective Equipment:ADEQUATE LABORATORY ATTIRE
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
UNUSUAL FIRE CONT'D: FORMS HIGHLY SENSITIVE EXPLOSIVE COMPOUNDS W/HEAVY
METALS SUCH AS LEAD, SILVER & COPPER. WHEN HEATED TO 662F IT
DECOMPOSES EXOTHERMICALLY, BURNING W/A VERY HOT FLAME & PRODUCING N
ITROGEN & MOLTEN SODIUM.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:527F
Spec Gravity:1.85
Solubility in Water:40.16
Appearance and Odor:WHITE-COLORLESS CRYSTALS/POWDER, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALS, ACIDS, ACID CHLORIDES & STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:NITROGEN OXIDES, HYDRAZOIC ACID
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:9681 QCS NOR UNASY 25 ML
CAGE:0X6L2
CAGE:0X6L2
============= Composition/Information on Ingredients =============
Ingred Name:NON HAZARDOUS INGREDIENTS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH W/LARGE AMOUNTS OF WATER. SKIN: WASH
AFFECTED AREAS W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:PUT ON SAFETY GLASSES, NOSE & MOUTH
SUITABLE ABSORBENT. CLEAN AREA W/DETERGENT, THEN DISINFECTANT &
FINALLY A WATER RINSE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AT TEMPERATURE INDICATED IN
PRODUCT LABELING.
============= Exposure Controls/Personal Protection =============
Ventilation:GENERALLY NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
Other Protective Equipment:IF RISK OF SPLASH/DROPLET GENERATION, USE
MOUTH & NOSE PROTECTION.
Supplemental Safety and Health
DISINFECT PORTION OF EQUIPMENT THAT HAS COME IN CONTACT W/THIS MATERIAL
BEFORE PERFORMING REPAIR & MAINTENANCE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ENAMEL ALKYD SG BLUE 25053
Preparer's Name:W. A. ELLISON
CAGE:61196
CAGE:61196
============= Composition/Information on Ingredients =============
Ingred Name:NAPHTHA, MEDIUM ALIPHATIC
CAS:64742-88-7
Fraction by Wt: 40%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3 RDUST; Z-3
ACGIH TLV:0.1 MG/M3 RDUST;9394
Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE
CAS:14464-46-1
RTECS #:VV7325000
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.05 MG/M3 RDUST9394
Ingred Name:TALC
CAS:14807-96-6
RTECS #:MW2700000
Fraction by Wt: 5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:0.2 FIBERS/CC; 9394
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9394
Ingred Name:SILICA, AMORPHOUS HYDRATED (PIGMENT)
CAS:112945-52-5
RTECS #:VV7310000
Fraction by Wt: 15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:TALC (PIGMENT)
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3; 20 MPPCF
ACGIH TLV:2 MG/M3; 15 MPPCF
Ingred Name:VOC: 3.01 LB/GAL LESS WATER & NEGLIGIBLY PHOTOCHEMICALLY
REACTIVE MATERIALS; 361 G/L LESS WATER; CALCULATED
RTECS #:9999999VO
Other REC Limits:NONE RECOMMENDED
Ingred Name:N-BUTYL ACETATE (CERCLA)(VP = 10.0 @ 20C)(LFL 1.7, UFL 7.6)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:150 PPM/STEL 200
ACGIH TLV:150 PPM/STEL 200
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHYL BENZENE (SARA 313)(LFL 1.0, UFL 6.7)(VP = 1.0 @ 20C)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/STEL 125
ACGIH TLV:100 PPM/STEL 125
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENE (SARA 313) (CERCLA)(LFL 1.0, UFL 7.0)(VP = 5.0 @
20C)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 10.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/STEL 150
ACGIH TLV:100 PPM/STEL 150
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL ISOAMYL KETONE
CAS:110-12-3
RTECS #:MP3850000
Fraction by Wt: 5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SWALLOWING-CAN CAUSE GASTROINTESTINAL
IRRITATION. ASPIRATION OF CHEMICAL INTO LUNGS CAN CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL.INHALATION-MAY CAUSE NOSE OR THROAT
IRRITATION. HIGH CONCENTRATION S MAY CAUSE CNS DEPRESSION. EYE-MAY
CAUSE EYE IRRITATI
Explanation of Carcinogenicity:TITANIUM DIOXIDE IS NOT LISTED AS A
POTENTIAL CARCINOGEN BY NTP, IARC, OSHA OR ACGIH.
Effects of Overexposure:SWALLOWING-CAN CAUSE NAUSEA AND VOMITING.
INHALATION-MAY CAUSE HEADACHES, DIZZINESS, NAUSEA AND CONFUSION.
Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.
======================= First Aid Measures =======================
First Aid:SWALLOWING-DO NOT INDUCE VOMITING. CALL POISON CONTROL
CENTER, HOSPITAL EMERGENCY OR PHYSICIAN IMMEDIATELY.
INHALATION-REMOVE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. K EEP WARM & QUIET. GET MEDICAL
ATTENTIONIMMEDIATELY. E
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:59.0F,15.0C
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS DESIGNATED TO
EXTINGUISH FLAMMABLE LIQUID FIRES. USE POLYMER FOAM FOR LARGE
FIRES.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED
BREATHING APPARATUS. WATER MAY BE INEFFECTIVE, BUT MAY BE USED TO
COOL EXPOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS CLOSED. ISOLATE FROM
HEAT, ELECTRICAL EQUIPMENT, SPARKS & FLAME. CLOSED CONTAINERS MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE ALL IGNITION
SOURCES. DIKE & CONTAIN SPILL WITH INERT MATERIAL. TRANSFER LIQUIDS
TO COVERED METAL CONTAINERS FOR RECOVERY OR DISPOSAL, OR REMOVE
WITH INERT ABSORBENT. U SE ONLY NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 95 DEGREES F. STORE
LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29CFR1910.106.
Other Precautions:DO NOT TAKE INTERNALLY. CLOSE CONTAINER AFTER EACH
USE. DO NOT BREATHE SANDING DUST. EMPTY CONTAINER MUST NOT BE
WASHED & RE-USED FOR ANY PURPOSE. CONTAINERS SHOULD BE GROUNDED AND
BONDED TO THE RECEI VING CONTAINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:PROPER SELECTION OF RESPIRATORY PROTECTION
DEPENDS UPON MANY FACTORS INCLUDING DURATION/LEVEL OF EXPOSURE AND
CONDITIONS OF USE. IN RESTRICTED VENTILATION AREAS A NIOSH CHEMICAL
CARTRIDGE RESPIRATOR M AY BE REQUIRED.
Ventilation:PROVIDE GENERAL DILUTION & LOCAL EXHAUST VENTILATION IN
SUFFICIENT VOLUME & PATTERN TO MAINTAIN CONCENTRATIONS BELOW TLV
Other Protective Equipment:NOT LIKELY TO BE NEEDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NOTES TO PHYSICIAN: ANY TREATMENT THAT MIGHT BE REQUIRED FOR
OVEREXPOSURE SHOULD BE DIRECTED TO THE CONTROL OF SYMPTOMS & THE
CLINICAL CONDITIONS. FIRE: IF WATER IS USED, FOG NOZZLES ARE
PREFERRED. OT HER PRECAUTIONS: DO NOT WELD/BRAZE/CUT ON EMPTY
CONTAI
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:1.3 TO 410F
Melt/Freeze Pt:M.P/F.P Text:-50F,-46C
Vapor Pres:2 MMHG
Vapor Density:>AIR
Spec Gravity:1.1
pH:4-7
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT IN WATER.
Appearance and Odor:LIQUID, SOLVENT ODOR.
Percent Volatiles by Volume:43.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT (>115F) AND SOURCES
OF IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL LAWS. INCINERATE ONLY IN EPA PERMITTED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS. OBSERVE PRECAUTIONS FOR DISPOSAL OF
FLAMMABLE MATERIALS. RCRA CLASSIFICATION WOULD BE D001.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:1071, MARATHON ENAMEL TAN
Preparer's Name:J. BURNWORTH
CAGE:9H480
CAGE:9H480
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS. VP: 2.068F
CAS:64742-88-7
Fraction by Wt: 45%
OSHA PEL:500 PPM (MFR)
ACGIH TLV:100 PPM (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: (SHORT TERM) OVEREXP CAN CAUSE
SKIN & EYE IRRIT. INHALATION CAN CAUSE ACUTE NERV SYS DEPRESS
CHARACTERIZED BY NASAL IRRIT, HDCH, DIZZ, CONFUSN/UNCON. CHRONIC:
(LONG TERM) OVEREXP TO VAP MAY CAU SE KIDNEY/LIVER DAM. INHAL OF
HIGH CONCOF VAP MAY LEAD TO NASAL IRRIT, HDCH, NAUS, ASPHY/UNCON.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SKIN/EYE: RPTD CONT CAN DEFAT SKIN
CAUSING IRRIT & DERM. EYE CONT CAN CAUSE SEV IRRIT, REDNESS,
TEAR/BLURRED VISION. SKIN ABSORPTION: NONE ARE KNOWN @ THIS TIME.
INGEST: SWALLOWING CAN CAUSE GI IRRIT, NAUS, VOMIT & DIARR. VOMIT
CAN RSLT IN ASPIR OF MATL INTO LUNGS WHICH CAN CAUSE CHEM
PNEUMONITIS. (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE KNOWN AT THIS TIME.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, APPLY
ARTF RESP. CONSULT PHYS. EYE: WASH WITH CLEAN WATER FOR AT LEAST 15
MIN. CONSULT PHYS. SKIN: WASH AFFECTED AREA WITH SOAP AND WATER,
REMOVE CONTAMD CLOTHING. CONSULT PHYS IF IRRITPERSIST. INGEST:
DRINK 1-2 GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMIT. CONSULT
PHYS OR POISON CONTROL CENTER.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:105F,41C
Lower Limits:1.0%
Upper Limits:6.0%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. H*2O
MAY BE USED TO COOL CLSD CONTR TO PVNT PRESS BUILDUP & POSS
AUTO-IGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:KEEP CONTR TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CONTR MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. DURING EMER CNDTNS, (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF IGNITION
(FLAME, HOT SURFACES, ELECTRICAL, STATIC OR FRICTIONAL SPARKS).
AVOID SKIN CONTACT AND BREATHING VAPORS. CONTAIN AND REMOVE WITH
INERT ABSORBENT AND NON- SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA
AWAY FROM SOURCES OF IGNITION. STORE LG QTY ONLY IN BUILDINGS
DESIGNED TO COMPLY WITH OSHA 1910.106.
Other Precautions:DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF
CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR PROPERLY FITTED NIOSH/MSHA APPROVED
VAPOR/PARTICULATE RESPIRATOR OR AN AIR-SUPPLYING RESP UNLESS VENT
IS ADEQ TO KEEP AIRBORNE CONTAMINATION BELOW APPLICABLE OSHA PEL OR
ACGIH TLV OCCUPATIONAL EX POSURE LIMITS.
Ventilation:PROVIDE SUFFICIENT VENT IN VOL & PATTERN, W/EXPLO PROOF
EQUIP TO KEEP AIR CONTAM CONC BELOW APPLIC OSHA PEL (SUPP DATA)
SPRAY APPLICATN. PROT CREAMS MAY BE USED FOR EASE OF CLEAN-UP, NOT
FOR PROT.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING RESTROOM.
Supplemental Safety and Health
EXPLO HAZ:OVEREXP TO DECOMP PROD MAY CAUSE HLTH HAZ. EFTS OF
OVEREXP:LAB STUDIES W/RATS HAVE SHOWN THAT PETROLEUM DISTILLATES
CAUSE KIDNEY & LIVER DAM/TUMORS. SEVERAL STUDIES EVALUATING
PETROLEUM WORK ERS HAVE NOT SHOWN SIGNIFICANT INCR OF KIDNEY DAM;
NOR KIDNEY OR LIVER TUMORS. VENT: OR ACGIH TLV OCCUPATIONAL LIMITS.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:314F,157C
Vapor Pres:SEE ING 1
Vapor Density:HVR/AIR
Spec Gravity:1.1
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:TAN COLORED LIQUID WITH ALIPHATIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:EXTREME HEAT, SPARKS OR OPEN FLAME.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION CAN PRODUCE CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE WATER
SYSTEMS. ABSORB LARGE SPILLS WITH SAND, CLAY OR DIATOMACEOUS EARTH.
DISPOSE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL DISPOSAL
REQUIREMENTS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:RP X-RAY DEVELOPER/REPLENISHER PART C, 1002
Kit Part:Y
Preparer's Name:ENGINEERING DEPT
CAGE:47720
CAGE:47720
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 40-70%
Ingred Name:GLUTARALDEHYDE; (GLUTARALDEHYDE BIS-)
CAS:111-30-8
RTECS #:MA2450000
Fraction by Wt: 25-35%
OSHA PEL:0.2 PPM,C
ACGIH TLV:0.2 PPM,C
Ingred Name:SULFITE, HYDROGEN;(BISULFITE) (MFR'S CAS # 7420-89-5)
CAS:15181-46-1
RTECS #:WQ6870000
Fraction by Wt: 25-35%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:CAUSES BURNS AND EYE IRRITATION.
CHRONIC:MAY CAUSE AN ALLERGIC SKIN REACTION. IRRITANCY OF
PRODUCT:SEVERE TO EYES.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES AND GET MD. SKIN:FLUSH WITH PLENTY OF WATER. IF AN ALLERGIC
SKIN REACTION DEVELOPS, GET MD. INHAL:REMOVE FROM EXPOSURE.
INGEST:CALL M D IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:NEUTRALIZE WITH SODIUM BICARBONATE. SMALL
SPILLS:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. LARGE
SPILLS:ABSORB MATERIAL IN VERMICULITE OR OTHER SUITABLE ABSORBENT
AND PLACE IN IMPERVIOUS CONTAINER.
Neutralizing Agent:NEUTRALIZE WITH SODIUM BICARBONATE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BETWEEN 50-80F (10-25C).
Other Precautions:AVOID CONTACT WITH EYES AND SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:VENTILATION TO GIVE TEN ROOM VOLUMES PER HOUR.
Other Protective Equipment:APPROPRIATE CLOTHING TO COVER SKIN. NORMAL
FOOTWEAR.EMERG EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>212F,>100C
Spec Gravity:1.20
pH:<3.0
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID WITH SHARP ODOR
Percent Volatiles by Volume:75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO*2 & PROBABLY CO, ALSO SO*X MAY BE
PRESENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:NO SPECIFIC METHOD NEC IF NEUTRALIZED. DISPOSAL
MUST BE I/A/W ALL LOCAL, STATE, & FEDERAL REGULATIONS . EMTPY
CNTNRS (THOSE CNTNG <3% BY WT OF TOT CAPACITY OF CNTNR) ARE NOT
REGULATED UNDER HAZ WASTE REGS & MAY BE DISPOSED OF IN NORMAL
MANNER.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ORTHO DIQUAT HERBICIDE-H/A
CAGE:7L865
CAGE:7L865
============= Composition/Information on Ingredients =============
Ingred Name:DIQUAT (SARA III)
CAS:85-00-7
RTECS #:JM5690000
Fraction by Wt: 35.3%
OSHA PEL:0.5 MG/M3
ACGIH TLV:O.5 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:INERT INGREDIENTS
Fraction by Wt: 64.7%
ACGIH TLV:NOT SPECIFIED
Ingred Name:ETHYLENE DIBROMIDE(SARA III)
CAS:106-93-4
RTECS #:KH9275000
Fraction by Wt: <.01%
OSHA PEL:20PPM/C,30PPM; Z2
ACGIH TLV:S; A2; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:MAY BE FATAL IF SWALLOWED.PROLONGED CONTACT CAN
IRRITATE SKIN, EYES,UPPER RESPIRATORY TRACT
======================= First Aid Measures =======================
First Aid:INGESTION-INDUCE VOMITING IMMEDIATELY.SKIN-WASH SKIN
THOROUGHLY WITH SOAP & WATER.EYES-FLUSH WITH WATER FOR ATLEAST 15
MIN.-GET DOCTOR IMMEDIATELY.INHALATION-REMOVE FROM EXPOSURE.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:CO*2, FOAM, DRY CHEM.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD
BRTHG APP.
Unusual Fire/Explosion Hazard:NORMAL COMBUSTION:CO*2,H*2O VAPORS &
BROMINE. INCOMPLETE COMBUSTION: CO GAS. AVOID INHALING SMOKE.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP SPILL IMMED.NOTE PRECAUTIONS IN
SPEC.PROTECT.INFO.& ON PRD.LABEL; COVER SPILL W/LARGE AMTS.OF CLAY
OR LOAM SOIL.USE STIFF BROOM TO MIX WELL.SWEEP UP/PLACE IN DISPOS.
CONTAIN. SCRUB CONTAMIN. AREA W/DETERG. & WATER. USE
ABSORBENT-PICKUP
======================Handling and Storage ======================
Handling and Storage Precautions:READ AND OBSERVE PRECAUTIONS ON
PRODUCT LABEL.
Other Precautions:AVOID INHALING SMOKE/MISTS.AVOID CONTACT WITH FALLOUT
& RUNOFF WATER.DO NOT ENTER ENCLOSED AREA WITHOUT SELF CONTAINED
BREATH- ING APPARATUS.
============= Exposure Controls/Personal Protection =============
Ventilation:USE ADEQUATE VENTILATION TO KEEP CONC BELOW STANDARDS
Other Protective Equipment:RUBBER APRON WHEN HANDLING CONCENTR.;
WATERPROOF WHEN SPRAY.
Supplemental Safety and Health
MSDS DATED:12/31/82;PRODUCT CONTAIN EDB A SUSPECTED CARCINOGEN AS AN
IMPURITY & IN A VERY SMALL AMOUNT;PROLONGED CONT.MAY DAMAGE SKIN
OVEREXP;NOSEBLEED,SORE THROAT,COUGHING(SPRAY MIST)-PH <7.0
================== Physical/Chemical Properties ==================
HCC:T5
Vapor Pres:UNK
Vapor Density:UNKN
Spec Gravity:1.25
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR RED ODORLESS LIQUID
Percent Volatiles by Volume:0.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS,ANIONIC WETTING AGNT(ALKYL & ALKYLARYL SULFON
Stability Condition to Avoid:SITUATIONS WHERE SPILLS MAY OCCUR
Hazardous Decomposition Products:TOXIC BROMINE CMPS, OXIDES OF
NITROGEN;
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTAMINATED MATERIALS MAY BE HAZ.REFER TO
SPECIAL PROTECTIVE INFORM BEFORE HANDLING. CONTAMINATED MATERIALS
SHOULD BE PLACE IN DISPOSABLE CONTAINERS & BURIED IN AN APPROVED
DUMPING AREA.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:02-00380DG04 E DESICCANT CAN INDICATING SILICA GEL
)
Resp. Party Other MSDS Num.:M28
Preparer's Name:G.E. MCKEDY
CAGE:22627
Contract Num:SP0450-00-M-SD97
CAGE:22627
============= Composition/Information on Ingredients =============
Ingred Name:SILICA GEL
CAS:1343-98-2
Minumum % Wt:70.
Maxumum % Wt:80.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:COBALT CHLORIDE
CAS:7646-79-9
RTECS #:GF9800000
= Wt:.5
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.05 MG C0/M3
ACGIH TLV:0.05 MG C0/M3
Ingred Name:ALUMINUM (SARA 313)
CAS:7429-90-5
RTECS #:BD0330000
Minumum % Wt:20.
Maxumum % Wt:30.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 DUST
ACGIH TLV:10 MG/M3 DUST; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE: EXPOSURE MAY CAUSE SKIN, EYE
AND MUCOUSE MEMBRANE IRRITATION. CHRONIC: PROLONGED INHALATION MAY
CAUSE LUNG DAMAGE.
Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Effects of Overexposure:DRYING, IRRITATION.
Medical Cond Aggravated by Exposure:ASTHMA.
======================= First Aid Measures =======================
First Aid:SEEK MEDICAL ASSISTANCE FOR FURTHER TREATMENT, OBSERVATION
AND SUPPORT IF NEEDED. EYES-FLUSH WITH WATER FOR 15 MINUTES.
SKIN-WASH AFFECTED AREA WITH SOAP AND WATER. INHALATION: REMOVE
AFFECTED PERSON TO FRESH AIR. INGESTION:DRINK AT LEAST 2
GLASSES WATER.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER AND SPRAY FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS.
CARBON DIOXIDE IS NOT GENERALLY RECOMMENDED BECAUSE OF LACK OF
COOLING CAPAPCITY MAY PERMIT RE-IGNITION OF THE POLYMER..
Unusual Fire/Explosion Hazard:WHEN EXPOSED TO WATER THE SILICA GEL CAN
GET HOT ENOUGH TO APPROACH BOILING POINT OF WATER. FLOODING WITH
WATER WILL REDUCE TEMPERATURE TO SAFE LIMTS.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP OR VACUUM AND PLACE SPILLED MATERIAL IN
A WASTE DISPOSAL CONTAINER. AVOID RAISING DUST.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================Handling and Storage ======================
Handling and Storage Precautions:COVER PROMPTLY TO AVOID BLOWING DUST.
WASH AFTER HANDLING.
Other Precautions:KEEP IN SEALED CONTAINERS AWAY FROM MOISTURE. SILICA
GEL READILY ABSORBS MOISTURE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A NIOSH APPROVED DUST MASK OR RESPIRATOR.
Ventilation:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Other Protective Equipment:NONE.
Work Hygienic Practices:AVOID RAISING DUST
Supplemental Safety and Health
NO DATA PROVIDED BY RESPONSIBLE PARTY.
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:2.1
Solubility in Water:INSOLUBLE
Appearance and Odor:SILVER METAL BOX CONTAINING BLUE SILICA GEL BEADS;
NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER.
Stability Condition to Avoid:MOISTURE AND HIGH HUMIDITY ENVIRONMENTS.
Hazardous Decomposition Products:HYDROCARBONS, CARBON MONOXIDE,
HYDROGEN CYANIDE, WATER, CARBON DIOXIDE, NITROGEN OXIDES.
=================== Toxicological Information===================
Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
===================== Ecological Information =====================
Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSEIN AN APPROVED LANDFILL ACCORDING TO
LOCAL, STATE AND FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
===================== Regulatory Information =====================
SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================= Other Information =======================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ACETIC ACID, GLACIAL, A38S 212
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:ACETIC ACID (CERCLA) LD50 (ORAL RAT): 3310 MG/KG
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 97%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SUP DAT: ISOCYANATE, PHOSPHORUS TRICHLORIDE, POTASSIUM
HYDROXIDE, POTASSIUM-T-BUTOXIDE, SODIUM HYDROXIDE, (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2: SODIUM PEROXIDE, AND XYLENE.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: INHAL: GET MED AID IMMED. REMOVE FROM EXPOS
TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: TREAT
SYMPTOMATICALLY & SUPPORTIVELY. NO SPECIFIC ANTIDOTE EXISTS.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC: INCOMPATIBLE SUBSTANCES. STORE IN SUITABLE
CONTR IN DRY AREA ABOVE SUBSTANCE'S FREEZING POINT.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: SEV IRRIT. CONT W/LIQ/VAP
CAUSES SEV BURNS & POSS IRREVERSIBLE EYE DMG. SKIN: SEV IRRIT. MAY
CAUSE SKIN SENSIT, AN ALLERGIC RXN, WHICH BECOMES EVIDENT UPON
RE-EXPOS TO THIS MATL. INGEST: M AY CAUSE SEV & PERM DMG TO
DIGESTIVE TRACT. CAUSES SEV PAIN, NAUS, VOMIT, DIARR, & SHOCK.
(EFFECTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INHAL: EFTS MAY BE DELAYED. CAUSES
RESP TRACT IRRIT. CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE DERM.
RPTD INHAL MAY CAUSE CHRONIC BRONCHITIS. RPTD EXPOS MAY CAUSE
EROSION OF TEETH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCAS
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: GET MED AID
IMMED. IMMED FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LEAST 15
MIN WHILE REM OVING CONTAM CLTHG & SHOES. INGEST: DO NOT INDUCE
VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF
MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERS. GET MED
AID IMMED. (ING 4)
===================== Fire Fighting Measures =====================
Flash Point:103F,39C
Lower Limits:5.4%
Upper Limits:16%
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:REACTS WITH MOST METALS TO FORM HIGHLY
FLAMMABLE HYDROGEN GAS WHICH CAN FORM EXPLOSIVE MIXTURES WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SPILL W/INERT MATL (E.G., DRY
SAND/EARTH), THEN PLACE INTO CHEM WASTE CONTR. USE WATER SPRAY TO
DILUTE SPILL TO A NON-FLAMM MIX. AVOID RUNOFF INTO STORM SEWERS &
DITCHES WHICH LEAD TO WATERWAYS . REMOVE ALL SOURCES OF IGNITION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:USE W/ADEQ VENT. EMPTY CONTRS RETAIN
PROD RESIDUE (LIQ &/VAP), & CAN BE DANGEROUS. DO NOT GET ON SKIN/IN
EYES. AVOID INGEST & INHALATION.
Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE SUCH CONTRS TO HEAT, SPKS/OPEN FLAMES. AVOID CONT
W/HEAT, SPKS & FLAME. KEEP AWAY FROM HEAT, SPKS, & FLAME. STORE IN
COOL, DRY, WELL-VE NTILATED AREA, AWAY FROM (ING 6)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29CFR 1910.134. ALWAYS USE A NIOSH APPROVED RESPIRATOR WHEN
NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
PH: 2.4 (1M), 2.9 (0.1M). SOL IN H*2O: SOL; RELEASES HEAT/VAP. MATLS TO
AVOID: ACID, CHROMIC ACID, CHROMIC ANHYDRIDE + ACETIC ANHYDRIDE,
DIALLYL METHYL CARBINOL + OZONE, ETHYLENE DIAMINE, ETHYLENEIMIN E,
HYDROGEN PEROXIDE, NITRIC ACID, NITRIC ACID + ACETONE, OLEUM,
PERCHLORIC ACID, PERMANGANATES, PHOSPHORUS (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:244F,118C
Melt/Freeze Pt:M.P/F.P Text:62.0F,16.7C
Vapor Pres:11.4
Vapor Density:2.10
Spec Gravity:1.05 (H*2O=1)
pH:SUPDAT
Evaporation Rate & Reference:0.97 (N-BUTYL ACETATE=1)
Solubility in Water:SUP DAT
Appearance and Odor:COLORLESS LIQUID, PUNGENT (VINEGAR) ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACETALDEHYDE, 2-AMINOETHANOL, AMMONIUM NITRATE, BROMINE PENTAFLUORIDE,
CHLORINE TRIFLUORIDE, CHLOROSULFONIC (SUP DAT)
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES,
EXCESS HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
=======================================================
NIIN: 01-440-4837
Product ID: SEALED LEAD ACID BATTERY
Article: Y
Cage: 0UJ55
Resp. Party Other MSDS No.: OBI-0001G
=======================================================
Contractor Summary
=======================================================
Cage: 0UJ55
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: BATTERY,STORAGE
Unit of Issue: EA
=======================================================
Regulated Components
=======================================================
Regulated Component Name: SULFURIC ACID ELECTROLYTE
CAS: 7664-93-9
Percent Text: 17-25%
Regulated Component Name: CASE MATERIAL POLYPROPYLENE
CAS: 9003-07-0
Percent Text: 2-6%
Regulated Component Name: SEPERATOR/PASTER PAPER FIBROUS GLASS
CAS: 65997-17-3
Percent Text: 1-4%
Regulated Component Name: LEAD COMPOUNDS
CAS: 7439-92-1
Percent Text: 63-81%
=======================================================
Health Hazards Data
=======================================================
Carcinogenicity Inds - NTP: NO
IARC: NO
Effects of Exposure: POTENTIAL HEALTH EFFECTS: NONE EXPECTED FOR FINISHED
PRODUCT UNDER NORMAL CONDITIONS OF USE. CHRONIC EXPOSURE: NONE EXPECTED FOR
FINISHED PRODUCT UNDER NORMAL CONDITIONS OF USE.
Explanation Of Carcinogenicity: FOR FINISHED PRODUCT UNDER NORMAL CONDITIONS OF
USE.
Signs And Symptions Of Overexposure: SIGNS AND SYMPTOMS OF ACUTE EXPOSURE: NONE
EXPECTED FOR FINISHED PRODUCT UNDER NORMAL CONDITIONS OF USE. EFFECTS OF
OVEREXPOSURE: NO EXPOSURE EXPECTED FOR FINISHED PRODUCT. HOWEVER, DO NOT
PUNCTURE O R OPEN BATTERY CASE. ACID ELECTROLYTE MAY BE RELEASED. USE ONLY
STANDARD CHARGING METHODS. IF OVERCHARGED, BATTERY MAY RELEASE GASES HYDOGEN
AND OXYGEN).
Medical Cond Aggravated By Exposure: NONE EXPECTED FOR FINISHED PRODUCT UNDER
NORMAL CONDITIONS OF USE.
First Aid: INHALATION-NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.
HOWEVER, IF ACID VAPOR IS RELEASED DUE TO OVERCHARGING/ABUSE OF THE BATTERY,
REMOVE EXPOSED PERSON TO FRESH AIR. IF BREATHING IS DIF FICULT, OXYGEN MAY BE
GIVEN. IF BREATHING HAS STOPPED, ARTIFICIAL RESPIRATION SHOULD BE STARTED
IMMEDIATELY. SEEK MEDICAL AID. EYES-EXPOSURE NOT EXPECTED FOR PRODUCT UNDER
NORMAL CONDITIONS OF USE. HO WEVER, IF ACID FROM BROKEN BATTERY CASE ENTERS
EYES, FLUSH WITH WATER FOR 15 MINS. IF IRRITATION DEVELOPS, SEEK PROMPT
MEDICAL AID. SKIN-EXPOSURE NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS
OF US E. INGESTION-SEEK PROMPT MEDICAL AID.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AVOID CONTACT WITH ACID MATERIALS. USE SODA ASH,
BAKING SODA OR LIME TO NEUTRALIZE ACID IF RELEASED.
Neutralizing Agent: USE SODA ASH, BAKING SODA OR LIME.
Waste Disposal Methods: SEND TO A LEAD RECYCLING FACILITY THAT FOLLOWS
APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS FOR ROUTINE DISPOSITION OF
SPENT OR DAMAGED BATTERIES. THE DISTRIBUTOR/USER IS RESPONSIBLE TO KNOW THAT
"SP ENT" &/OR "DAMAGED" BATTEIES ARE DISPOSED OF IN AN ENVIRONMENTALLY
SOUND WAY IN ACCORDANCE WITH FEDE RAL, STATE & LOCAL ENVIRONMENTAL
REGULATIONS.
Handling And Storage Precautions: HANDLING: DO NOT CARRY BATTERY BY TERMINALS.
DO NOT DROP BATTERY, PUNCTURE OR ATTEMPT TO OPEN BATTERY CASE. KEEP AWAY FROM
FLAMES DURING AND IMMEDIATELY AFTER CHARGE. AVOID PROLONGED OVERCHARGES IN CO
NFINED AREAS.
Other Precautions: STORAGE: STORE AT AMBIENT ROOM TEMPERATURE. DO NOT SUBJECT
PRODUCT TO OPEN FLAME OR FIRE. AVOID CONDITION WHICH COULD CAUSE ARCING
BETWEEN BATTERY TERMINALS> HYGIENE: WASH HANDS THOROUGHLY BEFORE EATI NG
OR SMOKING AFTER HANDLING BATTERIES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: MULTIPURPOSE DRY CHEMICAL OR MULTIPURPOSE CO2.
Fire Fighting Procedures: EVACUATE AREA. SELF-CONTAINED BREATHING APPARATUS
MUST BE WORN TO PREVENT POSSIBLE INHALATION OF ACID MISTS, SMOKE AND
DECOMPOSITION PRODUCTS IN A FIRE. REMOVE ALL IGNITION SOURCES. COOL
BATTERY(S) TO PREVENT RUPTURE.
Unusual Fire/Explosion Hazard: HYDROGEN GAS MAY BE PRODUCED AND MAY EXPLODE IF
IGNITED. REMOVE ALL IGNITION SOURCES. VENTILATE AREA.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NOT NECESSARY UNDER NORMAL CONDITONS OF USE FOR
FINISHED PRODUCT.
Ventilation: NOT NECESSARY UNDER NORMAL CONDITONS OF USE FOR FINISHED PRODUCT.
PRODUCT.
PRODUCT.
Work Hygienic Practices: NOT NECESSARY UNDER NORMAL CONDITONS OF USE FOR
FINISHED PRODUCT.
Supplemental Safety and Health: OPTIMA BATTERIES ARE 100% RECYCLABLE BY ANY
LICENSED RECLAMATION OPERATION.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: Z4
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID SHORTING, USE ONLY APPROVED CHARGING
METHODS. DO NOT PUNCTURE BATTERY CASE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
Transport Information: DEALED LEAD ACID BATTERY IS NOT A DOT HAZARDOUS
MATERIAL.
=======================================================
Regulatory Information
=======================================================
Federal Regulatory Information: ACCORDING TO THE OSHA HAZARD COMMUNICATION
STANDARD, SEALED LEAD ACID BATTERY IN ITS MANUFACTURER AND SUPPLIED STATE IS
CONSIDERED NON-HAZARDOUS.
State Regulatory Information: PROPOSITION 65 WARNING (CALIFORNIA): BATTERY
POSTS, TERMINALS, AND RELATED ACCESSORIES CONTAIN LEAD AND LEAD COMPOUNDS,
CHEMICALS KNOWN TO THE STATE OF CLAIFORNIA TO CAUSE CANCER AND REPRODUCTIVE
HARM . WASH HANDS AFTER HANDLING.
=======================================================
Other Information
=======================================================
Other Information: PER DOT, IATA, ICAO AND IMDG RULES AND REGULATIONS, THESE
BATTERIES ARE EXEMPT FROM "UN2800" CLASSIFICATIONS AS A RESULT OF SUCCESSFUL
COMPLETION OF THE FOLLOWING TESTS: 1) VIBRATION TESTS; 2) PRESSUR E
DIFFERENTIAL TESTS; 3) CASE RUPTURING TESTS (NO FREE LIQUIDS). ALL BATTERIES
MUST BE IDENTIFIED AS "NON-SPILLABLE" OR "NON-SPILLABLE BATTERY" ON THE
BATTERY AND THE SHIPMENT PER 49CFR173.159(D)(2) A ND BATTERY TERMINALS MUST
BE PROTECTED FROM SHORT CIRCUITING.
=======================================================
Transportation Information
=======================================================
Trans ID NO: 157974
Product ID: SEALED LEAD ACID BATTERY
Review Date: 07/24/2001
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: EA
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: SEALED LEAD ACID BATTERY
Cage: 0UJ55
Company Name: OPTIMA BATTERIES INC
Street: 17500 E 22ND AVENUE
Zipcode: 80011
Label Required IND: Y
Date Of Label Review: 07/24/2001
Status Code: A
Origination Code: F
Skin Protection IND: NO
Signal Word: NONE
Respiratory Protection IND: NO
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: EMERGENCY OVERVIEW: EXPOSURE NOT EXPECTED FOR PRODUCT
UNDER NORMAL CONDITIONS OF USE. IN ITS MANUFACTURERED AND SUPPLIED STATE, THE
PRODUCT IS CONSIDERED NON-HAZARDOUS. KEEP AWAY FROM FLAMES DURING AN D
IMMEDIATELY AFTER CHARGE. NO SIGNIFICANT HEALTH EFFECTS ARE ASSOCIATED WITH
THE PRODUCT.
=======================================================
| 0 |
eyes_protection_not_mandatory
|
===================== Product Identification =====================
Product ID:SCOTCHCAST BRAND RESIN NO.2104
CAGE:76381
CAGE:76381
============= Composition/Information on Ingredients =============
Ingred Name:POLYMERIC DIISOCYANATE(40-50%)
Fraction by Wt: 45.0%
ACGIH TLV:0.02PPM
Ingred Name:HYDROCARBON POLYOLS (SEE SUPP. DATA)
Fraction by Wt: 55.0%
ACGIH TLV:NOT SPECIFIED
Ingred Name:DYES (GREEN)
Fraction by Wt: <0.1%
ACGIH TLV:NOT SPECIFIED
===================== Hazards Identification =====================
Effects of Overexposure:EYES:MAY CAUSE EYE IRRITATION ON
CONTACT.SKIN:IRRITION CONT.INHAL:RESP.IRRITANT AND SENSITIZATION.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/LARGE AMOUNTS OF WATER.CALL MEDICAL ATTENTION
IMMEDIATELY.SKIN:-WASH SKIN W/WATER,USE SOAP IF REQUIRED,DO NOT
REMOVE COMPOUND FROM SKIN WITH SOLVENT.INHALATION:-REMOVE PATIENT
IN FRESH AI R,IF SYMPTOMS DEVELOP,GET MEDICAL ATTENTION
===================== Fire Fighting Measures =====================
Flash Point:366F T.C.C.
Lower Limits:UNKN
Upper Limits:UNKN
Extinguishing Media:CO*2,FOAM,DRY CHEMICAL
Fire Fighting Procedures:NONE SPECIFIED BY THE MFR.
Unusual Fire/Explosion Hazard:AVOID SOURCES OF IGNITION
================== Accidental Release Measures ==================
Spill Release Procedures:USE APPROVED PERSONAL PROTECTIVE EQUIPMENT
POUR ADSORBENT OVER SPILL. COLLECT AND DRUM.
======================Handling and Storage ======================
Handling and Storage Precautions:NORMAL WAREHOUSE INFORMATION.USE
NORMAL PROCEDURES WITH ADEQUATE VENTILATION.
Other Precautions:AVOID EYE AND SKIN CONTACT.USE ONLY WITH ADEQUATE
VENTILATION. AVOID USE IN CONFINED SPACES
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED SCBA
Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV.
Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE
WASH STATION
Supplemental Safety and Health
HYDROCARBON POLYOLS CONTAINS 97% HYDROCARBON POLYOL,ANTIOXIDANT 2% AND
A CATALYST <2 %. NOTE:SCOTCHCAST BRAND RESIN#4401 IS REPLACED BY #
2104. MSDS DATED JULY 1981.
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.0498
Solubility in Water:PREPOLY REA
Appearance and Odor:VISCOUS LIQUID
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
PREPOLYMER REACTS WITH WATER AND ALCOHOL.
Stability Condition to Avoid:NOT SPECIFIED
Hazardous Decomposition Products:COMBUSTION PRODUCTS MAY INCLUDE OXIDES
OF CARBON,CYANIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:MAY BE BURIED IN A SECURED LANDFILL OR
INCINERATE IN ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:F CATALYST
CAGE:5D028
CAGE:5D028
CAGE:71984
============= Composition/Information on Ingredients =============
Ingred Name:SILLICA, AMOOHPOUS DIATOMACEOUS EARTH
CAS:68855-54-9
Fraction by Wt: 8%
Other REC Limits:NONE RECOMMENDED
Ingred Name:CRISTOBALITE, UP TO 22.
CAS:14464-46-1
RTECS #:VV7325000
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.05 MG/M3 RDUST9596
Ingred Name:QUARTZ, UP TO 2%.
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: SEE ING
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3 RDUST;9596
Ingred Name:STANNOUS OCTOATE
CAS:301-10-0
Fraction by Wt: 5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POLY (DIMETHYLSILOXANE)
CAS:63148-62-9
RTECS #:JJ6484500
Other REC Limits:NONE RECOMMENDED
Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA)
CAS:123-31-9
RTECS #:MX3500000
Fraction by Wt: <0.1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:DIRECT CONTACT IRRIT MAY BE
SERIOUS W/RED,SWELL,SOME CORNEAL INJURY.SKIN:SINGEL RELATIVELY
SHORT EXPO IRRIT.SEVERAL REP/PROL EXPO IRRIT SERIOUSLY,MAY BURN
MILDLY.OVEREXPO MAY INJURE INTERNALLY IF ABSORBED.INHAL:MIST
INJURE RESP SYS.INGEST:SM AMTS TRANFERED TO MOUTH BY FINGERS DURING
USE,ETC SHOULD NOT INJURE.(SUPP)
Explanation of Carcinogenicity:PER MSDS:CARCINOGENS:NONE KNOWN.
Effects of Overexposure:SERIOUS EYE IRRIT, REDNESS, SWELLING, SOME
CORNEAL INJURY. SERIOUSLY IRRIT SKIN, BURN MILDLY. MAY INJURE
INTERNALLY IF ABSORBED. INJURE RESPIRATORY SYSTEM. INGEST LG AMTS
MAY CAUSE DIGESTIVE DISCOMFOR T.
Medical Cond Aggravated by Exposure:OVEREXPO TO ANY CHEMICAL MAY RESULT
IN ENHANCEMENT OF PRE-EXISTING ADVERSE MED CONDITIONS & ALLERGIC
REACTIONS.
======================= First Aid Measures =======================
First Aid:EYE:IMMED FLUSH W/WATER FOR 15MINS.GET MED ATTN. SKIN:FLUSH
W/WATER FOR 15MINS.GET MED ATTN IF ILL EFFECTS DEVELOP.
INHAL:REMOVE TO FRESH AIR.GET MED ATTN IF ILL EFFECTS PERSIST.
ORAL:NOT FIRST AID SH OULD BE NEEDED. COMMENTS:NONE.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>212F,>100C
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:N/DETERMINED
Upper Limits:N/DETEMRINED
Extinguishing Media:WATER FOG, CARBON DIOXIDE (CO2), DRY CHEMICAL,
FOAM.
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING SHOULD BE WORN IN FIGHTING FIRES INVOLVING
CHEM.
Unusual Fire/Explosion Hazard:MAY RELEASE IRRITATING FUMES DURING
COMBUSTION.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSORBENT MATL TO COLLECT & CONTAIN FOR
SLAVAGE/DISPO.USE CHEM WORKER GOGG.IF SPLASH OCCURS CHANGE CONTAMIN
CLOTH ASAP/THOROUGHLY FLUSH AFFECTED AREAS W/COOL
NEEDED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BEL 90F/32C.USE REASONABLE
CARE/CAUT.FOR INDUSTRIAL USE ONLY.NOT FOR FOOD/DRUG/SOCMETIC/MED
DEVICE USE.AVOID EYE/SKIN CONTACT/CREAT/BREATH MIST.
Other Precautions:WHEN HEATED TO TEMP >180C IN PRESENCE OF AIR PROD CAN
FORM FORMALDEHYDE VAP(POT CANC HAZ,SKIN/RESP SENS,IRRITANT).SAFE
HNDLG CONDITIONS MAY BE MAINTAINED BY KEEPING VAP CONC W/IN OSHA
PEL.2-ETHYLHEXAN OIC ACID MAY FORM DURING USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO RESPIRATORY PROTECTION SHOULD BE NEEDED.
Ventilation:LOC EXHAUST:NONE SHOULD BE NEEDED. GEN
VENTILATION:RECOMMENDED.
Other Protective Equipment:USE @ELEVATED TEMP/AEROSOL/SPRAY
APPLICATIONS MAY REQUIRE ADDED PRECAUTIONS.
Work Hygienic Practices:WASH @MEALTIME/END OF SHIFT ADQUATE.SPLASH
OCCURS CHANGE CONTAMIN CLOTH ASAP/FLUSH WELL W/COOL WATER.
Supplemental Safety and Health
HEALTH HAZ:LG MATS CAUSE GI DISCOMFORT.PROL/REP CRISTOBALITE/QUARTZ
OVEREXPO MAY CAUSE SILICOSIS. DISPO:(0.05%),RQ OF PROD:2000LBS. FOR
SILICON RUB SEE PNIND:C SAME NSN.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NP
Vapor Pres:<5MM
Vapor Density:NA
Spec Gravity:1.22 @25C
pH:NA
Viscosity:25000 MPA.S
Evaporation Rate & Reference:NA
Solubility in Water:<0.1 NEGLIGIBLE.
Appearance and Odor:VERY LITTLE ODOR, PASTE-LIKE, BUFF COLOR.
Percent Volatiles by Volume:<5
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS CAN CAUSE REACTION.
Hazardous Decomposition Products:TIN OXIDES, SILICON DIOXIDE, CARBON
DIOXIDE, & TRACES OF INCOMPLETE BURNED CARBON PRODUCTS, INCLUDES
FORMALDEHYDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DOW CORNING SUGGEST THAT ALL LOC/STATE/FED REGS
CONCERNING HEALTH/POLLUTION BE REVIEWED TO DETERMINE APPROVED DISPO
PROCEDURES.CONTACT DOW CORNING IF THERE'RE ANY DISPO
QUESTIONS.ANITMONY CMPDS EPA CE RCLA CLEAN IAR ACT SEC112
REPORTABLE(RQ:1LB(SUPP)
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:PARAFORMALDEHYDE PRILLS 95-97%
CAGE:02687
CAGE:02687
============= Composition/Information on Ingredients =============
Ingred Name:PARAFORMALDEHYDE (SARA III)
CAS:30525-89-4
RTECS #:RV0540000
Fraction by Wt: 95-97%
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SUPP DATA:CARCIN:FORMALDEHYDE IS CARCINOGENIC TO ANIMALS
(NASAL CANCER, LIFETIME INHAL STUDY, RATS). LISTED (SEE ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:AS EXPTL ANIMAL CARCINOGEN (IARC,NTP), PROBABLE HUMAN
CARCINOGEN (IARC) & POTNTL CANCER HAZ (OSHA). (SEE ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3:REPRO:FORMALDEHYDE SHOWED NO EVIDENCE OF REPRO
EFFECTS IN ANIMAL STUDIES (MICE,RATS,DOGS). OTHER: (SEE ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:FORMALDEHYDE-NO EVIDENCE OF EFFECTS ON LIVER,
KIDNEYS, NERVOUS SYSTEM OR BLOOD IN 180-DAY STUDIES OF (SEE ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:RATS, MONKEYS OR HAMSTERS. FIRST AID PROC:EDEMA CAN
OCCUR. SIGNS/SYMPS OF PULM EDEMA CAN BE DELAYED SEVERAL HOURS.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:IN FEDERAL/STATE APPROVED FACILITY.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORL,RAT)0.68 G/KG,(DRM,RBT)>2 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:INGEST:CAUSES SEVERE IRRIT &
INFLAMM OF MOUTH, THROAT & STOM. SEVERE STOM PAINS FOLLOW, W/POSS
LOSS OF CONSCIOUSNESS. SLIGHTLY TOXIC TO ANIMALS. INHAL:HIGHLY
IRRIT TO NASAL PASSAGES. CAN CAUSE I NFLAMM OF LINING OF NOSE,
THROAT & LUNGS. CAN CAUSE PNEUMONIA & ABNORMAL ACCUM OF FLUID IN
LUNGS. (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:FORMALDEHYDE:IARC-2A &
NTP-2:EXPERIMENTAL ANIMAL CARCIN. IARC:PROBABLE HUMAN CARCIN.
OSHA:POTENTIAL CANCER HAZ.ACGIH-A2
Effects of Overexposure:HLTH HAZ:SENSITIZER (ALLERGIC RXN POSS). MAY
CAUSE SENSIT OF RESP SYS. MODERATELY TOXIC TO ANIMALS. SKIN:CAN
CAUSE MOD INJURY-REDDENING & SWELLING. SENSITIZER (ALLERGIC RXN
POSS). DUST CAN CAUSE DRYIN G, CRACKING & SCALING. RPTD/PRLNGD
CNTCT CAUSES HARDENING (TANNING). SLIGHTLY TOXIC TO ANIMALS BY
ABSORP.(SEE SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:IMMED INDUCE VOMIT IF CONSCIOUS BY GIVING 2 GLASSES OF
WATER & PRESSING FINGER DOWN THROAT. CNTCT MD IMMED. INHAL:REMOVE
FROM CONTAMD AREA. IF BRTHG STOPPED, GIVE ARTF RESP, THEN O*2 IF
NEEDED. CNTCT MD IMMED. SKIN:REMOVE CONTAMD CLTHG/WASH CONTAMD
SKIN W/LG AMTS OF WATER. IF IRRT PERSIST, CONTACT MD. EYE:FLUSH
W/WATER FOR AT LEAST 15 MIN. CALL MD IMMED. NOTE TO MD:PULMONARY
(SEE INGRED 6)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:157F,69C
Lower Limits:7.0%
Upper Limits:73.0%
Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRES,
ALCOHOL-TYPE AQUEOUS FILM-FORMING FOAM OR WATER SPRAY FOR LARGE
FIRES.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA/COMPLETE PERSONAL
PROT EQUIP WHEN POTNTL FOR EXPOS TO VAPS/PRODS OF COMBUST EXISTS.
USE WATER SPRAY TO COOL FIRE- (SEE SUPP DATA)
Unusual Fire/Explosion Hazard:DO NOT USE COMPRESSED AIR TO TRANSFER
MATERIAL.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNIT SOURCES. AVOID EYE/SKIN CNTCT.
PLACE LEAKING CNTNRS IN WELL-VENT AREA. NEUT W/AMMONIUM
HYDROXIDE/SODIUM SULFITE. NOTE:RXN IS REVERSIBLE. USE STANDARD
CLEAN-UP PROCEDURES SUCH AS VACUUM ING OR SWEEPING.
Neutralizing Agent:AMMONIUM HYDROXIDE OR SODIUM SULFITE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, WELL-VENT AREA. DO NOT
EXPOSE TO TEMPS ABOVE 100F. KEEP AWAY FROM HEAT, SPARKS & FLAME.
KEEP CNTNRS CLOSED. USE ONLY DOT APPRVD CNTNRS.
Other Precautions:PROVIDE EMERGENCY EXHAUST. AVOID BRTHG DUST OR VAPOR.
WHEN TRANSFERRING FOLLOW PROPER GROUNDING PROCEDURES. AVOID CONTACT
W/EYES, SKIN & CLTHG. DO NOT ENTER STORAGE AREA UNLESS ADEQUATELY
VENTILATED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPRVD FULL-FACE FORMALDEHYDE OR
ACID GAS CARTRIDGE OR CANISTER RESPIRATOR W/PARTICULATE FILTER
WITHIN USE LIMITATIONS OF THESE DEVICES; IN ALL OTHER SITUATIONS,
USE NIOSH/MSHA APPRVD S CBA.
Ventilation:LOCAL EXHST:RECOMM WHEN APPROPRIATE TO CONTROL EXPOS. MECH
(GEN):NOT RECOMM AS SOLE MEANS OF CONTROLLING EXPOS.
Other Protective Equipment:FOR OPERATIONS WHERE SPILLS CAN OCCUR, USE
IMPERVIOUS BODY COVERING & BOOTS. SAFETY SHOWER & EYE BATH.
Work Hygienic Practices:WASH THOROUGHLY W/SOAP & WATER AFTER HANDLING.
WASH CONTAMD CLTHG THORO BEFORE RE-USE. DISCARD CONTAMD LEATHER
CLTHG.
Supplemental Safety and Health
FIRE FIGHT PROC:EXPOSED STRUCTURES & VESSELS. EFTS OF OVEREXP:EYE:CAN
CAUSE CHEM BURN-DMG IRREVERSIBLE. EXPOS TO HIGH VAP CONCS/DUST,
CAUSES IRRIT/TEARING. CHRONIC:MUTAG:IN VITRO, FORMALDEHYDE IS MUTA
G (MUTAG ACTIVITY DETECTED IN E.COLI, PSEUDOMONAS FLUORESCENS, &
SACCHAROMYCES CERVISIAE). IN VIVO, NO INFO. (SEE ING 2)
================== Physical/Chemical Properties ==================
HCC:F8
Melt/Freeze Pt:M.P/F.P Text:248F,120C
Vapor Pres:1.45
Vapor Density:1.03
Solubility in Water:COMPLETE.
Appearance and Odor:WHITE FREE-FLOWING SOLID PRILL W/STRONG, PUNGENT
FORMALDEHYDE ODOR.
Percent Volatiles by Volume:<10
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CAUSTIC SODA, SODA ASH & OTHER ALKALIS; ACIDS, AMINES, OXYGEN, HYDROGEN
PEROXIDE & OTHER STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:TEMPERATURES ABOVE 100F, SPARKS, FLAME.
Hazardous Decomposition Products:CO, FORMALDEHYDE VAPOR.
==================== Disposal Considerations ====================
Waste Disposal Methods:PROD WHEN SPILLED/DISPOSED IS NON-HAZ SOLID
WASTE AS DEFINED IN RESOURCE CONSERVATION RECOVERY ACT REGS
(40CFR261). PROD MUST BE DISPOSED OF PROPERLY UNDER STATE REGS FOR
INDUSTRIAL WASTE. PREFERRED M ETHOD IS INCIN/BIOLOGICAL TREATMENT
(SEE INGRED 7)
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:TRA-BOND 2111 HARDENER
Kit Part:Y
CAGE:KO275
CAGE:22835
CAGE:KO275
============= Composition/Information on Ingredients =============
Ingred Name:POLYGLYCOL BIS PROPYLAMINE AND/OR SIMILAR ISOMERS OR
HOMOLOGS
CAS:4246-51-9
RTECS #:ID6475000
Fraction by Wt: <100%
Ingred Name:OTHER INGREDIENTS; (EITHER LESS THAN 0.1% EACH OR
NON-HAZARDOUS)
Fraction by Wt: <30%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS CORROSIVE TO BODY TISSUES
AND IS A STRONG SENSITIZER.
Effects of Overexposure:EYE/SKIN CONTACT:SEVERE IRRITATION,BURNING.
INHALED:RESPIRATORY IRRITATION,SENSITIZATION.
Medical Cond Aggravated by Exposure:ALLERGIES ESPECIALLY SENSITIZED
PERSONS.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER.
INHALED:REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION OR OXYGEN
AS NEEDED. INGESTED:DO NOT INDUCE VOMITING. GIVE LARGE QUANTITY OF
MILD OR WATER.(NOTHING BY MOUTH IF UNCONSCIOUS.) GET IMMEDIATE
MEDICAL ATTENTION. IF ANY IRRITATION PERSISTS OR IS SEVERE,GET
PROMPT MEDICAL CARE.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>250F/121C
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,WATER FOG OR SPRAY.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE UP WITH PAPER OR CLOTH TOWEL.AVOID
CONTACT WITH SKIN. PLACE IN COVERED CONTAINER. CLEAN WITH SOLVENT &
OBSERVE ANY SOLVENT FLAMMABILITY.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED
AREA. KEEP TIGHTLY CLOSED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR EQUIPPED WITH
CARTRIDGE FOR ORGANIC VAPORS/MISTS OR SUPPLIED AIR RESPIRATOR IF
EXPOSED ABOVE TLV/PEL.
Ventilation:USE NORMAL ROOM VENTILATION. MAY REQUIRE LOCAL EXHAUST.
Other Protective Equipment:EYE WASH,SAFETY SHOWER. CLOTHING AS NEEDED
TO PREVENT CONTACT WITH SKIN.
Work Hygienic Practices:USE CHEMICAL HYGIENE PRACTICE. AVOID ANY
POSSIBLE CONTACT.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>400F/204C
Vapor Pres:LOW
Vapor Density:>2
Spec Gravity:1.0
Evaporation Rate & Reference:LOW
Solubility in Water:HIGH
Appearance and Odor:TRANSLUCENT AMBER LIQUID,SLIGHT AMINE ODOR.
Percent Volatiles by Volume:LOW
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COPPER,COPPER ALLOYS,STRONG ACIDS,OXIDIZING AGENTS,CHLORINATED
COMPOUNDS.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:CO,CO*2,ALDEHYDES,NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL EXOTHERM WITH EPOXY RESINS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
MFR SUGGESTS INCINERATION,OR LANDFILL.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:EASYPOXY PLATINUM, 3711
CAGE:HO213
CAGE:11111
CAGE:HO213
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS; (ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)).
VP:10. LD50:(ORAL,RAT) >25 ML/KG.
CAS:64742-88-7
Fraction by Wt: 25-35%
Other REC Limits:100 PPM (MFR)
Ingred Name:RUTILE; (TITANIUM DIOXIDE). LD50:(ORAL,RAT) >9500 MG/KG.
CAS:1317-80-2
RTECS #:VM2940000
Fraction by Wt: 0-35%
OSHA PEL:10 MG/M3 TDUST
ACGIH TLV:10 MG/M3
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 0-4%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:CALCIUM CARBONATE
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 0-20%
OSHA PEL:15MG/M3 TDUST;5 RESP
ACGIH TLV:10 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE .
Explanation of Carcinogenicity:NOT APPLICABLE
Effects of Overexposure:INHALATION OF HIGH VAPOR CONCENTRATIONS MAY
HAVE RESULTS RANGING FROM DIZZINESS,HEADACHES,GIDDINESS,NAUSE TO
UNCONSCIOUSNESS.PROLONG/REPEATED LIQUID CONTACT W/SKIN WILL DRY &
DEFAT SKIN, LEADING TO IR RITATION & DERMATITIS.
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
First Aid:EYES:IMME FLUSH W/LGE AMTS OF WATER FOR AT LEAST 15 MIN OR
UNTIL IRRITATION SUBSIDES.INGES:DO NOT INDUCE VOM,CALL PHYS.IF VOM
OCCUR,KEEP HEAD BELOW HIPS TO KEEP LIQ OUT OF LUNGS.SKIN:REMOVE ANY
CONTAM CLTHNG,& WASH SKIN W/SOAP & WATER. INHALATION:REMOVE FROM
EXPOSURE IMMEDIATELY.IF BREATHING IS IRREGULAR/STOPPED,START
RESUSCITATION,ADMINISTER OXYGEN.CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:105F/40.6C
Lower Limits:1
Upper Limits:N/K
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG.DO NOT USE A
DIRECT STREAM OF WATER. PRODUCT WILL FLOAT & CAN BE REIGNITED.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT FROM
FIRES SHOULD BE COOLED W/WATER TO PREVENT VAPOR PRESSURE BUILDUP,
WHICH COULD RESULT IN CONTAINER RUPTURE.
================== Accidental Release Measures ==================
Spill Release Procedures:RMOV ALL IGN SOURCE.KEEP PEOPLE AWAY.RCOVR
FREE LIQ.ADD ABSOR(SAND,EARTH,SAWDUST,ETC.)TO SPILL AREA.AVOID
BRTHNG VAPR.VENT CONFIND SPACE.OPEN ALL WINDOW & DOOR.KEEP PETRO
PROD OUT OF SEWR & WTRCOURSE BY DIKNG/IMPOUNDNG.ADVISE AUTH IF
PROD (SUP DAT)
Neutralizing Agent:N/K
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. DO NOT HANDLE/STORE NEAR HEAT, SPARK, FLAME/STRONG OXIDANTS.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A NIOSH/MSHA APPROVED HYDROCARBON VAPOR
CANNISTER/SUPPLIED-AIR RESPIRATORY PROTECTION IN CONFINED/ENCLOSED
PLACES IF OCCUPATIONAL EXPOSURE LIMITS ARE EXCEEDED.
Ventilation:EXHAUST AT OVER 60 FPM.
Other Protective Equipment:USE A NIOSH/MSHA APPROVED DUST RESPIRATOR
WHEN SANDING THESE PRODUCTS IF OCCUPATIONAL EXPOSURE LIMITS ARE
EXCEEDED.
Work Hygienic Practices:N/K
Supplemental Safety and Health
SPILL RELEASE:HAS ENTERED/MAY ENTER SEWER, WATERCOURSE OR EXTENSIVE
LAND AREAS.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:>373F,>189C
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:HV THN AIR
Spec Gravity:1.08-1.50
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:N/K
Appearance and Odor:N/K
Percent Volatiles by Volume:40-50
Corrosion Rate:
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS LIKE:LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM,
CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:FUMES, SMOKE & CARBON MONOXIDE, IN THE
CASE OF INCOMPLETE COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:ASSURE CONFORMITY W/APPLICABLE FEDERAL, STATE &
LOCAL REGULATIONS. DISPOSE OF ABSORBED MATERIAL AT AN RCRA APPROVED
DISPOSAL SITE OR FACILITY.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:5356
CAGE:66376
CAGE:66376
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM
CAS:7439-95-4
RTECS #:OM2100000
Fraction by Wt: 4.5-5.5%
Other REC Limits:NONE SPECIFIED
Ingred Name:CHROMIUM (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: <0.2%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 93%
Other REC Limits:NONE SPECIFIED
OSHA PEL:15MG/M3 DUST/5 FUME
ACGIH TLV:10MG/M3 DUST; 9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:UNCLASSIFIED WELDING FUMES=5MG/M3 PEL
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES,
GASES OR DUST MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA,
FEVER, DRYNESS AND/OR IRRITATION OF NOSE, THROAT AND EYES. SKIN
SENSITIVITY MAY ALSO BE NOTED. A CUTE EXPOSURE FROM SOME TOXIC
GASES MAYCAUSE PULMONARY EDEMA, ASPHYXIATION AND EXCESSIVE EXPOSURE
CAN BE FATAL.
Explanation of Carcinogenicity:CHROMIUM IS CONSIDERED A POSSIBLE
CARCINOGEN. RESPIRATORY CANCER FROM WELDING IS UNCONFIRMED.
Effects of Overexposure:EXPOSURE TO WELDING FUMES MAY RESULT IN
DISCOMFORT SUCH AS DIZZINESS, NAUSEA, FEVER, DRYNESS AND/OR
IRRITATION OF NOSE, THROAT AND EYES. SKIN SENSITIVITY MAY ALSO BE
NOTED. WATERY EYES, HEADACHE, BREA THING DIFFICULTY, FREQUENT
COUGHING AND/OR CHEST PAINS MAY OCCUR FROM ACUTE EXPOSURE. TOXIC
GASES CAN BE FATAL.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH IMPAIRED PULMONARY
FUNCTIONS OR ILLNESS MAY HAVE SYMPTOMS EXACERBATED BY FUME
IRRITANTS.
======================= First Aid Measures =======================
First Aid:IN CASE OF ELECTRICAL SHOCK, TURN OFF POWER PRIOR TO REMOVAL
FROM EXPOSURE AREA AND ADMINISTRATION OF FIRST AID. REMOVE FROM
EXPOSURE AREA AND CALL FOR MEDICAL AID. ADMINISTER OXYGEN IF
BREATHING IS D IFFICULT. IF NOT BREATHING, BEGIN ARTIFICIAL
RESPIRATION. IF NO DETECTABLE PULSE, BEGIN EXTERNAL HEART MASSAGE.
EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:WELDING ARC, OPEN FLAME AND SPARKS CAN
IGNITE COMBUSTIBLES. SEE ANSI/ASC Z49.1-1983 SECTION 6.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUES
AND PLACE IN SUITABLE DOT APPROVED CONTAINERS AND DISPOSE OF IN
FULL COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. AVOID
INHALATION AND SKIN EXPOSU RE.
======================Handling and Storage ======================
CLOTHING WHEN CUTTING, GRINDING OR WELDING. DO NOT EXPOSE SKIN TO
RADIATION WHEN HOT CUTTING OR WELDING.
Other Precautions:PROVIDE PROTECTIVE SCREENS TO SHIELD OTHERS. WHEN
ELECTRODES AND FLUXES ARE CONSUMED, THE FUME AND GAS DECOMPOSITION
PRODUCTS GENERATED ARE DIFFERENT IN FORM FROM THE INGREDIENTS
LISTED. NEW COMPOUNDS NOT IN THE ELECTRODES MAY FORM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE WELD FUME RESPIRATOR OR AIR SUPPLIED
RESPIRATOR WHEN CUTTING, GRINDING OR WELDING IN A CONFINED SPACE OR
WHERE LOCAL EXHAUST OR GENERAL VENTILATION DOES NOT KEEP EXPOSURE
BELOW RECOMMENDED LIMITS. USE ONLY NIOSH APPROVED RESPIRATORS.
Ventilation:USE ENOUGH VENTILATION WHEN CUTTING, GRINDING OR WELDING TO
KEEP THE DUST, FUMES & GASES FROM THE WORKERS BREATHING ZONE
Other Protective Equipment:FLAME RETARDANT CLOTHING WHEN CUTTING,
GRINDING OR WELDING. DO NOT EXPOSE SKIN TO RADIATION WHEN HOT
CUTTING OR WELDING.
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING OR SMOKING.
LAUNDER CONTAMINATIED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
WELDING AND HOT CUTTING FUMES & GASES CANNOT BE CLASSIFIED SIMPLY.
THEIR COMPOSITION AND QUANTITY ARE DEPENDENT ON THE METAL BEING
WELDED, THE PROCEDURES, PROCESSES AND THE TYPE OF WIRE OR
ELECTRODESUSED. OTHER INFLUENCING FACTORS ARE THEPRESENCE OF
CONTAMINANTS. CHLORINATED SOLVENTS MAY DECOMPOSE TO TOXIC GASES.
================== Physical/Chemical Properties ==================
HCC:N1
Vapor Pres:0
Solubility in Water:NEGLIGIBLE
Appearance and Odor:ALUMINUM ALLOY FILLER WELDING ROD 0.094 INCHES
DIAMETER BY 36 INCHES LONG.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG MINERAL ACIDS OR STRONG ALKALIS
Hazardous Decomposition Products:WELDING OPERATION MAY INCLUDE OXIDES
OF THE METALS, CHROMATES, FLUORIDES, COMPLEX METALLICS, AND OZONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE & LOCAL REGULATIONS
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:DEX-O-TEX,UNDERLAYMENT,N-38,PASTE,MIL-D3135
CAGE:88167
CAGE:88167
============= Composition/Information on Ingredients =============
Ingred Name:SYNTHETIC RUBBER LATEX (NEOPRENE)
===================== Hazards Identification =====================
Effects of Overexposure:EYE CONT: IRREVERSIBLE DAMAGE. SKIN:
IRRITATION.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH WATER 15 MIN,CONTACT MD. SKIN: FLUSH WITH
WATER,SEE MD
===================== Fire Fighting Measures =====================
Flash Point:>350F/176C (OC)
Extinguishing Media:STANDARD DRY TYPE
================== Accidental Release Measures ==================
Spill Release Procedures:CLEANUP,AVOID SKIN CONTACT,ACIDS CAUSE
COAGULATION. LATEX MAY DESTROY CLOTHS AND SPONGES USED TO CLEAN UP
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM FREEZING,DO NOT STORE
AGAINST RADIATORS OR AT PROLONGED HIGH TEMPS.
Other Precautions:WILL CAUSE HOLES IN FABRICS CUE TO HIGH ALKALINITY.
============= Exposure Controls/Personal Protection =============
Other Protective Equipment:AS REQUIRED TO PREVENT SKIN CONTACT
Supplemental Safety and Health
PART C OF A THREE PART KIT. TYPE 1. PH: 11.5 ALKALINE. RAW LATEX, IF
HEATED RAPIDLY, WILL BOIL AND FOAM OVER 200F.KEY1:C4
================== Physical/Chemical Properties ==================
HCC:B3
Boiling Pt:B.P. Text:220F/104C
Spec Gravity:1.10
Solubility in Water:COMPATIBLE
Appearance and Odor:MILKY,SLIGHT ODOR
Percent Volatiles by Volume:60
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS & TEMPS BELOW 32F/0C
Stability Condition to Avoid:ACIDS,STRONG OXIDIZERS & WATER CAUSE
COAGULATION IF SHAKEN
==================== Disposal Considerations ====================
Waste Disposal Methods:FLUSH DOWN DRAIN WITH HOSE AND BROOM.
LOCAL,STATE AND FEDERAL LAWS APPLY.
| 1 |
eyes_protection_mandatory
|
=======================================================
Product ID: 3M TYPE 648 TONER
Cage: EO130
=======================================================
Contractor Summary
=======================================================
Cage: 28174
Cage: EO130
=======================================================
Ingredients
=======================================================
Cas: 25767-47-9
% Wt: 40-70
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 27136-15-8
% Wt: 15-40
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 1333-86-4
RTECS #: FF5800000
% Wt: 3-7
OSHA PEL: 3.5 MG/M3
ACGIH TLV: 3.5 MG/M3
------------------------------
Cas: 1317-38-0
RTECS #: GL7900000
% Wt: 3-7
OSHA PEL: 1 MG CU/M3
ACGIH TLV: 1 MG CU/M3
------------------------------
Cas: 8005-02-5
% Wt: 3-7
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 9003-07-0
RTECS #: TR5000000
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: EYE: MOD IRRIT: SIGNS/SYMPS CAN INCL REDNESS,
SWELL, PAIN, TEARING, & HAZY VISION. SKIN: PRLNGD/RPTD EXPOS MAY CAUSE:
MECH SKIN IRRIT: SIGNS/SYMPS CAN INCL ITCHING & REDNESS. INHAL: IRRIT
(UPPE R RESP): SIGNS/SYMPS CAN INCL SORENESS OF NOSE & THROAT, COUGH
& SNEEZING. PRLNGD/RPTD OVEREXP, ABOVE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CARBON BLACK: IARC MONO ON EVAL OF CARCIN RISK
OF CHEMS TO MAN, VOL 65, PG 149, 1996: GROUP 2B.
Signs And Symptions Of Overexposure: HLTH HAZ: REC GUIDLINES, MAY CAUSE: NERV
SYS EFTS: SIGNS/SYMPS CAN INCL EMOTIONAL CHANGES, LACK OF COORDINATION,
TREMORS & SENSORY LOSS. WHILE FOLLOWING EFTS ARE ASSOC W/ONE OR MORE OF
INDIVIDUAL INGR EDS IN PROD & ARE REQD TO BE INCL ON MSDS BY U.S. OSHA
HAZ COMMUNICATION STD, THEY ARE NOT EXPECTED EFTS DURING FORESEEABLE USE OF
THIS PROD: HEART EFTS: SIGNS/SYMPS CAN INCL ARRHY, HEART ATTACK & DEA TH.
PNEUMOCONIOSIS (GEN): SIGNS/SYMPS CAN INCL PERSISTENT COUGH & SHORTNESS
OF BREATH. INGEST: IRRIT OF GI TISS: SIGNS/SYMPS CAN INCL PAIN, VOMIT, ABDOM
TENDERNESS, NAUS, BLOOD IN VOMITUS, AND BLOOD I N FECES.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE CONT: IMMED FLUSH W/LG AMTS OF WATER FOR AT LEAST 15 MINUTES.
GET IMMED MED ATTN. SKIN CONT: WASH AFFECTED AREA W/SOAP & WATER. INHAL:
IF SIGNS/SYMPS OCCUR, REMOVE TO FRESH AIR. IF SIGNS/SYMPS CON TINUE, CALL
PHYSICIAN. INGEST: DRINK 2 GLASSES OF WATER. CALL PHYSICIAN.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: OBSERVE PRECAUTIONS FROM OTHER SECTIONS. EXTINGUISH
ALL IGNIT SOURCES. COLLECT SPILLED MATERIAL. USE WET SWEEPING COMPOUND OR
WATER TO AVOID DUSTING. PLACE IN APPROVED METAL CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE IN INDUSTRIAL OR COMMERCIAL FACILITY.
DISPOSE OF WATER PROD IN SANITARY LANDFILL. RECLAIM IF FEASIBLE. DISPOSAL
MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS (FP N).
Handling And Storage Precautions: KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP
OUT OF REACH OF CHILDREN.
Other Precautions: AVOID SKIN CONTACT.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: UNDER FIRE CONDITIONS, COPPER OXIDE FUME CAN
CAUSE FEVER, CHILLS, PROFUSE SWEATING AND WEAKNESS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: AVOID BREATHING OF DUST. NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: USE W/APPROP LOC EXHAST VENT. PROVIDE SUFFICIENT VENT TO MAINTAIN
EMISSIONS BELOW REC EXPOSURE LIMITS.
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: WASH HANDS AFTER HANDLING AND BEFORE EATING. DO NOT
INGEST.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.2 WATER =1
Solubility in Water: NEGLIGIBLE
Appearance and Odor: FINE POWDER (LESS THAN 10UM IN DIAMETER), BLACK,
ESSENTIALLY ODORLESS.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE KNOWN.
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: TONER POWDER IS STABLE UNDER NORMAL USE
CNDTNS. COMBUST PRODS CAN INCL OXIDES OF CARBON, HYDROCARBONS, & COPPER OXIDE
FUMES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: 3M TYPE 648 TONER
Cage: EO130
Assigned IND: Y
Company Name: IMATION ENTERPRISES CORPORATION
Street: 1 IMATION PLACE
Zipcode: 55128-1110
Label Required IND: Y
Date Of Label Review: 01/19/1998
Status Code: C
Label Date: 01/19/1998
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: EYE: MODERATE IRRITATION:
SIGNS/SYMPS CAN INCLUDE REDNESS, SWELLING, PAIN, TEARING, & HAZY VISION.
SKIN: PROLONGED OR REPEATED EXPOSURE MAY CAUSE: MECHANICAL SKIN IRRITATION:
SIGNS /SYMPS CAN INCLUDE ITCHING & REDNESS. INHALATION: IRRITATION (UPPER
RESPIRATORY): SIGNS/SYMPS CAN INCLUDE SORENESS OF NOSE & THROAT, COUGHING
& SNEEZING. CHRONIC: CANCER HAZARD. CONTAINS CARBON BLACK, WHICH IS
LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N). INHALATION: MAY CAUSE NERVOUS
SYSTEM EFFECTS.
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:TRACTOR HYDRAULIC OIL 5 GAL CAN, 022168-5G1
CAGE:57526
CAGE:57526
CAGE:23040
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM SULFONATE
CAS:61789-87-5
Ingred Name:MINERAL OIL, PETROLUEM DISTILLATES, LIGHT NAPHTHENIC;
(LIGHT NAPHTHENIC OIL)
CAS:64741-88-4
RTECS #:PY8040500
Other REC Limits:2.5 MG/M3 (MFR)
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY
PARAFFINIC
CAS:64741-88-4
RTECS #:PY8040500
Other REC Limits:2.5 MG/M3 (MFR)
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED LIGHT
PARAFFINIC; (PETROLEUM OIL)
CAS:64741-89-5
RTECS #:PY8041500
Other REC Limits:2.5 MG/M3 (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NO SIGNIFICANT EYE IRRITATION
EXPECTED. NO SKIN IRRITATION FOR SINGLE SHORT TERM EXPOSURE.
PROLONGED OR REPEATED CONTACT MAY PRODUCE SOME IRRITATION.
MAGNESIUM SULFONATES HAVE PRODUCED TESTICULAR AND LIVER EFFECTS.
CONCENTRATION OF THIS COMPOUND IS BELOW THAT WHICH PRODUCED EFFECTS
IN ANIMALS. (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:MINERAL OIL:IARC - GROUP 1.
Effects of Overexposure:HLTH HAZ:ASPIRED INTO LUNGS MAY CAUSE CHEMICAL
PNEUMONITIS, TREAT APPROPRIATELY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:WASH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. SEEK MD ADVICE. INGEST:GET IMMEDIATE MD ATTENTION OR
ADVICE. GIVE SEVERAL GLASSES OF WATER OR MILK. INHAL:NOT A PROBLEM
DURING NORMA L CONDITIONS OF USE. SKIN:FLUSH WITH COPIOUS AMOUNTS
OF WATER CALL MD . NOTE TO MD:ASPIRATION HAZARD.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>199F,>93C
Extinguishing Media:USE EXTINGUISHING MEDIA FOR CLASS B HAZARD.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:TREAT AS OIL SPILL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. AVOID
CONTACT WITH EYES. AVOID PROLONGED OR REPEATED SKIN CONTACT. USE
WITH ADEQUATE VENTILATION.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:ADEQUATE VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:V6
Spec Gravity:0.890
Appearance and Odor:LIQUID UNDER NORMAL CONDITIONS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE ACCORDING TO LOCAL, STATE AND FEDERAL
ENVIRONMENTAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:NPM-105, PESTICIDES MIXTURE #5 FOR METHOD 507
CAGE:0MU35
CAGE:0MU35
============= Composition/Information on Ingredients =============
Ingred Name:METHYL TERT BUTYL ETHER (MTBE), 2-METHOXY-2-METHYL PROPANE
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: 98.94%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:DICHLORVOS (DDVP), 2,2DICHLOR-VINYL DIMETHYL PHOSPHATE
CAS:62-73-7
RTECS #:TC0350000
Fraction by Wt: 0.132%
Other REC Limits:1 PPM
ACGIH TLV:.01 MG/CUM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:FENARIMOL
CAS:60168-88-9
RTECS #:UV9279400
Fraction by Wt: 0.132%
Ingred Name:FLURIDONE
CAS:59756-60-4
RTECS #:UU7786500
Fraction by Wt: 0.132%
Ingred Name:NAPROPAMIDE
CAS:15299-99-7
RTECS #:UE3600000
Fraction by Wt: 0.132%
Ingred Name:SIMETRYNE
CAS:1014-70-6
RTECS #:XY4025000
Fraction by Wt: 0.132%
Ingred
Name:N-(5-(1,1-DIMETHYLETHYL)-1,3,4-THIADIAZOL-2-YL)-N,N'-DIMETHYLU
REA, TEBUTHIURON
CAS:34014-18-1
RTECS #:YS4250000
Fraction by Wt: 0.132%
Ingred Name:TERBACIL
CAS:5902-51-2
RTECS #:YQ9360000
Fraction by Wt: 0.132%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:DIRECT PHYSICAL CONTACT SHOULD BE
AVOIDED. TOXIC, IRRITANT.
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:EYES & SKIN: FLUSH W/WATER. INHALATION: REMOVE TO FRESH AIR,
GIVE OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO2, DRY CHEMICAL POWDER, WATER SPRAY
Fire Fighting Procedures:COMBUSTIBLE LIQUID
================== Accidental Release Measures ==================
Spill Release Procedures:LEAKING BOTTLE MAY BE PLACED IN PLASTIC BAG.
LIQUID MAY BE ABSORBED ON VERMICULITE OR SAND.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLOSED IN A COOL, DRY
PLACE.
============= Exposure Controls/Personal Protection =============
Other Protective Equipment:WEAR OSHA/MSMA APPROVED SAFETY EQUIPMENT
INCLUDING CHEMICAL RESISTANT CLOTHING, LABORATORY COAT, RUBBER
APRON.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED
W/AFTERBURNER & SCRUBBER I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
=======================================================
Product ID: UH2225 WHITE-HIGH HIDING, ULTRA-HIDE (SUPDAT)
Cage: IO491
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 01PD6
Cage: IO491
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHAL: IRRIT OF RESP TRACT, LUNGS. PRLNGD INHAL MAY
LEAD TO MUC MEMB IRRIT, DROW, DIZZ &/OR LTHEAD, HDCH, NAUS, VOMIT, GI
DISTURB, COUGHING, APATHY, CNS DEPRESS, RESP PROBLEMS, ANESTHETIC EFT/N ARC,
BLOOD ABNORM, KIDNEY DMG, LOSS OF CONSCIOUSNESS. SKIN: IRRIT OF SKIN.
PRLNGD/RPTD CONT CAN CAUSE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: DERM, DEFAT. SKIN CONT MAY RSLT
IN DERMAL ABSORPTION OF COMPONENT(S) OF PROD WHICH MAY CAUSE APATHY. EYE:
IRRIT OF EYES. PRLNGD/RPTD CONT CAN CAUSE CONJUNCTIVITIS, CORNEAL INJ.
INGEST: INGES T MAY CAUSE FATG, DROW, DIZZ &/OR LTHEAD, HDCH, NAUS,
VOMIT, DIARR, GI DISTURB, SEV ABDOM PAIN, APATHY, CNS
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS, KIDNEY
DISORDERS, LIVER DISORDERS, NERVOUS SYSTEM DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT BRTHG. GET EMER
MED ATTN. HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET MED HELP FOR ANY BRTHG
DFCLTY. REMOVE TO FRESH AIR IF INHAL CAUSES EYE WATERING, HDC H, DIZZ/OTHER
DISCOMFORT. SKIN: FLUSH FROM SKIN W/WATER. WASH THORO W/SOAP & WATER.
REMOVE CONTAMD CLTHG. WASH CONTAMD CLTHG BEFORE RE-USE. IF IRRIT OCCURS,
CONSULT PHYS. EYE: FLUSH IMMED W/ (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: COMPLY W/ALL APPLIC HLTH & ENVIRON REGS. ELIM ALL
SOURCES OF IGNIT. VENT AREA. SPILLS MAY BE COLLECTED W/ABSORB MATLS. EVAC ALL
UNNECESSARY PERSONNEL. PLACE COLLECTED MATL IN PROPER CNTNR. VACUUM CLEA N
SPILLAGE. COMPLETE PERSONAL PROT EQUIP
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
Handling And Storage Precautions: STORE BELOW 100F. KEEP AWAY FROM HEAT, SPARKS
AND OPEN FLAME. KEEP FROM FREEZING. USE ONLY WITH ADEQUATE VENTILATION. DO
NOT TAKE INTERNALLY.
Other Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID CONT W/SKIN & EYES,
& BRTHG OF VAPS. WASH HANDS THORO AFTER HNDLG, ESPEC BEFORE
EATING/SMOKING. KEEP CNTNRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID
CNDTNS WH ICH RSLT IN FORM OF INHALABLE
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONE
Extinguishing Media: DRY CHEMICAL OR FOAM WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: VAPS ARE HVR/AIR & MAY TRAVEL LONG DISTANCES
TO SOURCE OF IGNIT & FLASH BACK. CLSD CNTNRS MAY BURST IF EXPOS TO
EXTREME HEAT/FIRE. IN CLSD TANKS, WATER/(SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED
RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP
OF VAPORS.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING, APRON.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USERS OF "L" VERSION CONSULT "LR" VERSION FOR
ADDNL INFO (FP N). TRADE NAME/PART #: SPEEDCOTE LATEX FLAT UH 2200 SERIES..
EXPLO HAZ: FOAM MAY CAUSE FROTHING/ERUPTION. FIRST AID PROC: LRG AMTS OF
WATER , ESPEC UNDER LIDS FOR AT LST 15 MINS. IF IRRIT/OTHER EFTS PERSIST,
OBTAIN MED TREATMENT. INGEST: OBTAIN MED TREATMENT.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: >212F,>100C
Spec Gravity: 1.28 (FP N)
VOC Grams/Liter: 129
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume: 73.86
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPS, CONTACT W/OXIDIZING AGENT, CONT
WITH ALUMINUM OR ZINC, HIGH CONC OF DUST, FREEZING, SPARKS, OPEN FLAME.
Materials To Avoid: OXIDIZERS, ACIDS, REDUCING AGENTS, BASES, ALUMINUM, ZINC,
MAGNESIUM, SODIUM, POTASSIUM.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE, OXYGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: UH2225 WHITE-HIGH HIDING, ULTRA-HIDE (SUPDAT)
Cage: IO491
Assigned IND: Y
Company Name: ICI PAINTS
Street: 925 EUCLID AVE
Zipcode: 44115
Label Required IND: Y
Date Of Label Review: 02/04/1998
Status Code: C
Label Date: 02/04/1998
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHAL: IRRIT. DROW, DIZZ &/OR LTHEAD, HDCH,
NAUS, VOMIT, GI DISTURB, COUGHING, APATHY, CNS DEPRESS, RESP PROBLEMS,
ANESTHETIC EFT/NARC, BLOOD ABNORM, KIDNEY DMG, LOSS OF CONSCIOUSNESS. SKIN:
IR RIT OF SKIN. DERM, DEFAT. ABSORPTION: APATHY. EYE: IRRIT, CONJUNCT,
CORNEAL INJ. INGEST: FATG, DROW, DIZZ, LT HEAD, HDCH, NAUS, VOMIT, DIARR. GI
DISTURB, SEV ABDOM PAIN. APATHY. CNS DEPRESS, RESP PROB LEMS, INTOXICATION,
CNS DMG, LIVER DMG, KIDNEY DMG, BLADDER DMG, PULM EDEMA, LOSS OF
CONSCIOUSNESS, CYANOSIS, POIS, RESP FAILURE, CARD FAILURE, DEATH. CHRONIC:
LUNG, LIVER AND KIDNEY DAMAGE. TERATOGEN .
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ENRICH WATER BASE WIPING STAIN, EWS
CAGE:3D277
CAGE:TRUTE
CAGE:3D277
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOL, 2-(2-ETHOXYETHOXY)-; (DIETHYLENE GLYCOL MONOETHYL
ETHER)
CAS:111-90-0
RTECS #:KK8750000
Fraction by Wt: 8-10%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ETHYLENE GLYCOL (SARA III). VP:0.1 @ 20C.
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 2-5%
OSHA PEL:50 PPM, C
ACGIH TLV:50 PPM, VAP/MIST, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER)
(EGBE). VP:0.9 @ 20C.
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 1-3%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS).
VP:2.6 @ 20C.
CAS:64742-47-8
RTECS #:OA5504000
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA)
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 2-6%
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:VOLATILE ORGANIC COMPOUNDS
RTECS #:9999999VO
Fraction by Wt: <380%G/L
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SEVERE EYE IRRITATION, DRYING OF SKIN,
EXCESSIVE INHALATION CAUSES HEADACHE, DIZZINESS & NAUSEA. IN
DIATOMACEOUS SILICA IS CRYSTALLINE SILICA (CS) WHICH IS CONSIDERED
A HAZARD BY INHALATION. ANIMAL ST UDIES CLEARLY DEMONSTRATED
DOSE-RELATEDADVERSE EFFECTS ON CENTRAL NERVOUS SYSTEM,
HEMATOPOIETIC (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, SUPP, VOL 7, PG 341, 1987:GRP 2A. NTP 6TH ANNUAL RPT ON
CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ:TISSUES, BLOOD, KIDNEYS & LIVER,
ASSOCIATED W/ADMINISTRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER
(EGBE). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO.90-118) .
Medical Cond Aggravated by Exposure:NONE KNOWN TO TRU-TEST
MANUFACTURING.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES.
GET MEDICAL ATTENTION. SKIN:WASH W/SOAP & WATER. INHAL:REMOVE TO
FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF NECESSARY. GET MEDICAL
ATTENTIO N. INGEST:DO NOT INDUCE VOMITING. KEEP PERSON WARM &
QUIET. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:180F,82C
Lower Limits:1.1%
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
TREAT AS VOLATILE LIQ FIRE. WATER SPRAY MAY BE INEFT. IF WATER
SPRAY IS USED, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, SPARKS & OPEN FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE & CONTAIN SPILL W/INERT MATERIAL (SAND,
EARTH, ETC). TRANSFER LIQUID TO CONTAINERS FOR RECOVERY OR
DISPOSAL. KEEP SPILL OUT OF SEWERS & OPEN BODIES OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:"KEEP FROM FREEZING". AVOID PROLONGED
CONTACT W/SKIN. DO NOT TAKE INTERNALLY.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN BRUSHED OR ROLLED NONE REQUIRED IF GOOD
VENTILATION MAINTAINED. DURING SPRAY APPLICATION, A NIOSH/MSHA
APPROVED MECHANICAL FILTER RESPIRATOR TO REMOVE AIRBORNE PARTICLES
OF OVERSPRAY.
Ventilation:SUFFICIENT VENT SHOULD BE PROVIDED TO KEEP AIR CONTAMINANT
CONCENTRATION BELOW CURRENT APPLIC OSHA PEL/ACGIH TLV LIMITS.
Other Protective Equipment:EYE WASH FACILITY, PROTECTIVE CLOTHING TO
AVOID EXCESSIVE SKIN CONTACT.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
WASHROOM.
Supplemental Safety and Health
EXPLAN OF CARCIN:1991:ANTICIPATED TO BE CARCINOGEN.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.23
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:77
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:ISOLATE FROM HEAT & OPEN FIRE.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:LIQUID MATERIAL & CONTAMINATED DIKING MATERIAL
SHOULD BE LANDFILLED ACCORDING TO CURRENT LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:NITROGEN, COMPRESSED (SEE SUPPLEMENTAL DATA)
Resp. Party Other MSDS Num.:1011
CAGE:00742
Contract Num:SP0450-01-M-ZF49
CAGE:00742
============= Composition/Information on Ingredients =============
Ingred Name:NITROGEN (AS PURE NITROGEN IN NITROGEN, OXYGEN, HYDROGEN
CALIBRATING GAS MIXTURE)
CAS:7727-37-9
RTECS #:QW9700000
> Wt:99.
Other REC Limits:N/E (NIOSH)
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MSDS DATA FOR PURE NITROGEN. EMERGENCY
OVERVIEW: NITROGEN IS A NONTOXIC, ODORLESS, NONFLAMMABLE
COMPRESSED GAS STORED IN CYLINDERS AT HIGH PRESSURE. IT CAN CAUSE
RAPID SUFFOCATION WHEN CONCENTRATIONS ARE SUFFICIENT TO REDUCE
OXYGEN LEVELS BELOW 19.5%. SELF CONTAINED BREATHING APPARATUS
(SCBA) MAY BE REQUIRED. HEALTH HAZARD: INHALATION: SIMPLE
ASPHYXIANT. NITROGEN IS NONTOXIC, BUT MAY CAUSE SUFFO CATION BY
DISPLACING THE OXYGEN IN AIR. LACK OF SUFFICIENT OXYGEN CAN CAUSE
SERIOUS INJURY OR DEATH. EYE CONTACT: NO ADVERSE EFFECT. SKIN
CONTACT: NO ADVERSE EFFECT. TARGET ORGANS: NONE.
Explanation of Carcinogenicity:NITROGEN IS NOT LISTED AS A CARCINOGEN
OR POTENTIAL CARCINOGEN BY NTP, IARC, OSHA.
Effects of Overexposure:EXPOSURE TO AN OXYGEN DEFICIENT ATMOSPHERE
(<19.5%) MAY CAUSE DIZZINESS, DROWSINESS, NAUSEA, VOMITING, EXCESS
SALIVATION, DIMINISHED MENTAL ALERTNESS, LOSS OF CONSCIOUSNESS AND
DEATH. EXPOSURE TO ATMO SPHERES CONTAINING 8-10 OR LESS OXYGEN WILL
BRING ABOUT UNCONSCIOUSNESS WITHOUT WARNING AND SO QUICKLY THAT THE
INDIVIDUALS CANNOT HELP THEMSELVES.
Medical Cond Aggravated by Exposure:NONE.
======================= First Aid Measures =======================
First Aid:INHALATION: PERSONS SUFFERING FROM LACK OF OXYGEN SHOULD BE
MOVED TO FRESH AIR. IF VICTIM IS NOT BREATHING, ADMINISTER
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, ADMINISTER
OXYGEN. OBTAIN PROM PT MEDICAL ATTENTION. EYE CONTACT: NOT
APPLICABLE. SKIN CONTACT: NOT APPLICABLE.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:NA
Extinguishing Media:NITROGEN IS NONFLAMMABLE AND DOES NOT SUPPORT
COMBUSTION. USE EXTINGUISHING MEDIA APPROPRIATE FOR THE SURROUNDING
FIRE.
Fire Fighting Procedures:NITROGEN IS A SIMPLE ASPHYXIANT. IF POSSIBLE,
REMOVE NITROGEN CYLINDERS FROM FIRE AREA OR COOL WITH WATER. SCBA
MAY BE REQUIRED BY RESCUE WORKERS.
Unusual Fire/Explosion Hazard:UPON EXPOSURE TO INTENSE HEAT OR FLAME
CYLINDER MAY VENT RAPIDLY AND/OR RUPTURE VIOLENTLY. MOST CYLINDERS
ARE DESIGNED TO VENT CONTENTS WHEN EXPOSED TO ELEVATED
TEMPERATURES. PRESSURE IN A CONTAINER C AN BUILD UP DUE TO HEAT AND
IT MAY RUPTURE IF PRESSURE RELIEF DEVICES SHOULD FAIL TO FUNCTION.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL PERSONNEL FROM AFFECTED AREA.
INCREASE VENTILATION TO RELEASE AREA AND MONITOR OXYGEN LEVEL. USE
APPROPRIATE PROTECTIVE EQUIPMENT (SCBA). IF LEAK IS FROM CONTAINER
LEAK IN IN USER'S SYSTEM CLOSE CYLINDER VALVE AND VENT PRESSURE
BEFORE ATTEMPTING REPAIRS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE: STORE UPRIGHT IN
WELL-VENTILATED, SECURED AREA, PROTECTED FROM WEATHER.
TEMPERATURES SHOULD NOT EXCEED 125F, AND AREA FREE OF COMBUSTIBLE
MATERIALS. STORE AWAY FROM HEAVILY TRAVELED AREAS AN D EMERGENCY
EXITS. AVOID EXCESSIVE INVENTORY AND STORAGE TIME. USE A FIRST-IN
FIRST-OUT SYSTEM.
Other Precautions:HANDLING: DO NOT DRAG, ROLL, OR SLIDE CYLINDER. USE
SUITABLE HANDTRUCK DESIGNED FOR CYLINDER MOVEMENT. NEVER ATTEMPT TO
LIFT CYLINDER BY ITS CAP. SECURE CYLINDERS AT ALL TIMES WHILE IN
USE. USE A PRES SURE REDUCING REGULATOR OR SEPARATE CONTROL VALVE.
DO NOT HEAT CYLINDER TO INCREASE PRESSURE OR DISC HARGE RATE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:GENERAL USE: NONE REQUIRED. EMERGENCY: USE SCBA
OR POSITIVE PRESSURE AIR LINE WITH MASK AND ESCAPE PACK IN AREAS
WHERE OXYGEN CONCENTRATION IS LESS THAN 19.5%. AIR PURIFYING
RESPIRATORS WILL NOT PROVI DE PROTECTION.
Ventilation:PROVIDE GOOD VENTILATION AND/OR LOCAL EXHAUST TO PREVENT
ACCUMULATION OF HIGH CONCENTRATIONS OF GAS. OXYGEN LEVELS IN WORK
AREA SHOULD BE MONITORED.
CYLINDERS.
Other Protective Equipment:SAFETY SHOES RECOMMENDED WHEN HANDLING
CYLINDERS.
Supplemental Safety and Health
NSN IS FOR CALIBRATING GAS MIXTURE COMPOSED OF NITROGEN, OXYGEN,
HYDROGEN. THIS MSDS DESCRIBES NITROGEN CONTENT(77.00 % MIN.) IN
MIXTURE (SERIAL NUMBER "CLHHD"). SEE SAME NSN, SERIAL NUMBER
"CLHHQ" FO R OXYGEN GAS (20.50 % MIN) INGREDIENT DATA AND SERIAL
NUMBER "CLHJF" FOR HYDROGEN GAS (2.5% MIN) INGREDIENT DATA.
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:=-195.6C, -320.4F
Melt/Freeze Pt:=-209.7C, -345.8F
Vapor Pres:N/A AT 70F
Spec Gravity:0.967(AIR=1)
Solubility in Water:0.023 (VOL/VOL @32F)
Appearance and Odor:COLORLESS GAS, ODORLESS. (GAS DENSITY @ 70F AND 1
ATM)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information===================
Toxicological Information:NITROGEN IS A SIMPLE ASPHYXIANT.
===================== Ecological Information =====================
Ecological:THE ATMOSPHERE CONTAINS APPROXIMATELY 78% NITROGEN. NO
ADVERSE ECOLOGICAL EFFECTS ARE EXPECTED. NITROGEN DOES NOT CONTAIN
ANY CLASS I OR CLASS I I OZONE DEPLETING CHEMICALS. NITROGEN IS NOT
LISTED AS A MARINE POLLUTANT BY DOT (49 CFR 171).
==================== Disposal Considerations ====================
Waste Disposal Methods:UNUSED PRODUCT/EMPTY CONTAINER: RETURN CYLINDER
AND UNUSED PRODUCT TO SUPPLIER. DO NOT ATTEMPT TO DISPOSE OF
RESIDUAL OR UNUSED QUANTITIES. DISPOSAL: FOR EMERGENCY DISPOSAL,
SECURE THE CYLINDER AND SL OWLY DISCHARGE GAS TO THE ATMOSPHERE IN
A WELL VENTLATED AREA OR OUTDOORS.
=================== MSDS Transport Information ===================
Transport Information:FOR MSDS'S PURE NITROGEN: DOT HAZARD CLASS: 2.2.
DOT SHIPPING NAME: NITROGEN, COMPRESSED. DOT SHIPPING LABEL:
NONFLAMMABLE GAS; UN 1066. NONE. CYLINDERS SHOULD BE TRANSPORTED
IN SECURE UPRIGHT POSITI ON IN WELL VENTILATED TRUCK. NEVER
TRANSPORT IN PASSENGER COMPARTMENT OF A VEHICLE. COMPRESSED GAS
CYLINDERS SHALL NOT BE REFILED EXCEPT BY QUALIFIED PRODUCERS OF
COMPRESSED GASES. SHIPMENT OF A COMPR ESSED GAS CYLINDER WHICH HAS
NOT BEEN FILLED BY THE OWNER OR WITH THE OWNER'S WRITTEN CONSENT IS
A VIOLATION OF FEDERAL LAW. SEE TRANSPORTATION FOR PSN FOR NSN
PRODUCT (COMPRESSED GAS, N.O.S., UN 1956 .)
===================== Regulatory Information =====================
SARA Title III Information:CERCLA: REPORTABLE QUANTITY: NONE. SECTION
302/304:REQUIRES EMERGENCY PLANNING ON THRESHOLD PLANNING
QUANTITIES (TPQ) AND RELEASE REPORTING BASED ON REPORTABLE
QUANTITIES (RQ) OF EPA'S EXTREMELY HAZA RDOUS SUBSTANCES (40 CFR
355). NITROGEN IS NOT LISTED AS AN EXTREMELY HAZARDOUS SUBSTANCE.
THRESHOLD PLANNING QUANTITY (TPQ): NONE. SECTION 311/ 312: THE
HAZARD CLASSES OF THIS PRODUCT ARE: IMMEDIATE HEALTH: NO; DELAYED
HEALTH: NO; PRESSURE: YES; REACTIVITY: NO; FIRE: NO. SECTION 313:
NITROGEN DOES NOT REQUIRE REPORTING UNDER SECTION 313.
Federal Regulatory Information:TSCA (TOXIC SUBSTANCES CONTROL ACT):
NITROGEN IS LISTED ON THE TSCA INVENTORY. OSHA: 29 CFR 1910.119:
PROCESS SAFETY MANAGEMENT OF HIGHLY HAZARDOUS CHEMICALS: REQUIRES
FACILITIES TO DEVELOP A PROCESS SAFETY MANAGEMENT PROGRAM BASED ON
THRESHOLD QUANTITIES (TQ) OF HIGHLY HAZARDOUS CHEMICALS. NITROGEN
IS NOT LISTED IN APPENDIX A AS A HIGHLY HAZARDOUS CHEMICAL. 40 CFR
PART 88: RISK MANAGEMENT FOR CHE MICAL ACCIDENT RELEASE PERVENTION:
REQUIRES DEVELOPMENT AND IMPLEMENTATION OF RISK MANAGEMENT PROGRA
MS: NITROGEN IS NOT LISTED AS A REGULATED SUBSTANCE.
State Regulatory Information:CALIFORNIA: PROPOSITION 65: THIS PRODUCT
DOES NOT CONTAIN ANY LISTED SUBSTANCES WHICH THE STATE OF
CALIFORNIA REQUIRES WARNING UNDER THIS STATUTE. SCAQMD RULE: VOC:
NOT APPLICABLE.
======================= Other Information =======================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:SAFER INSECTICIDAL SOAP CONCENTRATE 20-1201
CAGE:SAFER
CAGE:SAFER
============= Composition/Information on Ingredients =============
Ingred Name:ALCOHOLS (TYPE NOT SPECIFIED)
Fraction by Wt: 30%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): >5.0 ML/KG
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION.
Explanation of Carcinogenicity:NONE
Medical Cond Aggravated by Exposure:SOAP ALLERGIES
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/WATER. SKIN:
FLUSH W/WATER. INGESTION: GIVE DEMULCENT (MILK). OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:33F
Extinguishing Media:WATER, ALCOHOL FOAM
Fire Fighting Procedures:WATER SHOULD BE SUFFICIENT TO DILUTE THE
ALCOHOL & EXTINGUISH THE FLAME. USE ALCOHOL FOAM.
Unusual Fire/Explosion Hazard:PRODUCT IS 30% ALCOHOL WHICH CONTRIBUTES
TO ITS FLAMMABILITY.
================== Accidental Release Measures ==================
Spill Release Procedures:RINSE W/ABUNDANT WATER AND MOP UP.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM OPEN FLAME.
Other Precautions:AVOID SPLASHING CONCENTRATE IN EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED
Ventilation:MECHANICAL/GENERAL: ACCEPTABLE
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:93C
Melt/Freeze Pt:M.P/F.P Text:-5C
Vapor Pres:1
Spec Gravity:0.93
Solubility in Water:COMPLETE
Appearance and Odor:AMBER LIQUID W/LARD ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONCENTRATED MINERAL SUPPLEMENTS (FERTILIZERS).
Stability Condition to Avoid:OPEN FLAMES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 0 |
eyes_protection_not_mandatory
|
===================== Product Identification =====================
Product ID:CHLORINE
Resp. Party Other MSDS Num.:G-23
Preparer's Name:LOSS CONTROL
CAGE:TO954
CAGE:TO955
CAGE:TO954
============= Composition/Information on Ingredients =============
Ingred Name:CHLORINE. (FORMULA CI2)
CAS:7782-50-5
RTECS #:FO2100000
= Wt:100.
OSHA PEL:1 PPM CEILING
ACGIH TLV:0.5 PPM
ACGIH STEL:1 PPM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LC 50: 293 PPM/1 HR (RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE EFFECTS: CORROSIVE AND IRRITATING
TO THE EYES. CONTACT WITH LIQUID OR VAPOR CAUSES PAINFUL BURNS AND
ULCERATIONS. BURNS TO EYES RESULT IN LESIONS AND POSSIBLE LOSS OF
VISION. SKIN EFFECTS: CORROSI VE AND IRRITATING TO THE SKIN AND ALL
LIVING TISSUE. IT HYDROLYZES VERY RAPIDLY, YIELDING HYDROCHLORIC
ACID. SKIN BURNS AND MUCOSAL IRRITATION ARE LIKE THAT FROM EXPOSURE
TO VOLATILE INORGANIC ACIDS. CHLORINE BURNS EXHIBIT SEVERE PAIN,
REDNESS, POSSIBLE SWELLING AND EARLY NECROSIS. INGESTION EFFECTS:
INGESTION UNLIKELY. INHALATION EFFECTS: CORROSIVE AND IRRITATING TO
UPPER AND LOWER RESPIRATORY TR ACT (SIGNS AND SYMPTOMS OF
OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT): AND
ALL MUCOSAL TISSUE. SYMPTOMS INCLUDE LACRIMATION, COUGH, LABORED
BREATHING AND EXCESSIVE SALIVARY AND SPUTUM FORMATION. EXCESSIVE
IRRITATION OF THE LUNGS C AUSES ACUTE PNEUMONITIS AND PULMONARY
EDEMA, WHICH COULD BE FATAL. RESIDUAL PULMONARY MALFUNCTION MAY
ALSO OCCUR. CHEMICAL PNEUMONITIS AND PULMONARY EDEMA MAY RESULT
FROM EXPOSURE TO LOWER RESPIRATORYTRACT AND DEEP LUNG. SOME
EXPERIMENTAL EVIDENCE INDICATES CHLORINE CAUSES MUTAGENIC,
TERATOGENIC, AND REPRODUCTIVE EFFECTS IN ANIMAL STUDIES. EXPOSURE
LIMITS: YES. ( )
======================= First Aid Measures =======================
First Aid:EYES: PERSONS WITH POTENTIAL EXPOSURE SHOULD NOT WEAR CONTACT
LENSES. FLUSH CONTAMINATED EYE(S) WITH COPIOUS QUANTITIES OF WATER.
PART EYELIDS TO ASSURE COMPLETE FLUSHING. CONTINUE FOR A MINIMUM OF
15MINUTES. SEEK IMMEDIATE MEDICAL ATTENTION. SKIN: REMOVE
CONTAMINATED CLOTHING AS RAPIDLY AS POSSIBLE. FLUSH AFFECTED AREA
WITH COPIOUS QUANTITIES OF WATER. SEEK IMMEDIATE MEDICAL ATTENTION.
INGESTION : CONTACT A PHYSICIAN IMMEDIATELY . INHALATION: PROMPT
MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE. RESCUE
PERSONNEL SHOULD BE EQUIPPED WITH SELF CONTAINED BREATHING
APPARATUS. C ONSCIOUS PERSONS SHOULD BE (ECOLOGICAL)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NONE REQUIRED. USE MEDIA SUITABLE FOR SURROUNDING
MATERIALS.
Fire Fighting Procedures:USE NIOSH-APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:HAZARDOUS COMBUSTION PRODUCTS,
SENSITIVITY TO MECHANICAL SHOCK, SENSITIVITY TO STATIC DISCHARGE:
NONE. COMBUSTIBLE MATERIALS BURN IN CHLORINE AS THEY DO IN OXYGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE
APPROPRIATE PROTECTIVE EQUIPMENT. IF LEAK IN USER'S EQUIP, BE
CERTAIN TO PURGE PIPING WITH INERT GAS PRIOR TO ATTEMPTING REPAIRS.
IF LEAK IS IN CONTAINER OR CONTAINER VALVE, CONTACT APPROPRIATE
LOCATION.
======================Handling and Storage ======================
Handling and Storage Precautions:ELECTRICAL CLASSIFICATION:
NON-HAZARDOUS. MOST METALS CORRODE RAPIDLY WITH WET CHLORINE.
SYSTEMS MUST BE KEPT DRY. LEAD, GOLD, HASTELLOY MOST RESISTANT TO
WET CHLORINE. USE ONLY IN WELL-VENTILATED AR EAS.VALVE PROTECTION
CAPS MUST REMAIN IN PLACE UNLESS CONTAINER IS SECURED WITH VALVE
(ECOLOGICAL)
Other Precautions:NEVER CARRY A COMPRESSED GAS CYLINDER OR A CONTAINER
OF A GAS IN CRYOGENIC LIQUID FORM IN AN ENCLOSED SPACE SUCH AS A
CAR TRUNK, VAN OR STATION WAGON. A LEAK CAN RESULT IN A FIRE,
EXPLOSION, ASPHYXIAT ION OR A TOXIC EXPOSURE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:POSITIVE PRESSURE AIR LINE WITH FULL FACE MASK
AND ESCAPE BOTTLE OR SELF-CONTAINED BREATHING APPARATUS (NIOSH
APPROVED - ) SHOULD BE AVAILABLE FOR EMERGENCY USE. EXPOSURE
LIMITS: CHLORINE: PEL-OS HA 1PPM CEILING; TLV-ACGIH 0.5 PPM TWA, 1
PPM STEL.
Ventilation:HOOD WITH FORCED VENTILATION. USE LOCAL VENTILATION TO
PREVENT ACCUMULATION ABOVE THE EXPOSURE LIMIT.
APPROVED - ).
Other Protective Equipment:SAFETY SHOES, SAFETY SHOWER (MEETING ANSI
DESIGNS CRITERIA - ), EYEWASH "FOUNTAIN" (MEETING ANSI DESIGN
CRITERIA - ), FACE SHIELD. SKIN PROTECTION: PVC, KEL-F OR TEFLON.
Supplemental Safety and Health
COMPRESSED GAS CYLINDERS SHALL NOT BE REFILLED WITHOUT THE EXPRESS
WRITTEN PERMISSION OF THE OWNER. SHIPMENT OF A COMPRESSED GAS
CYLINDER WHICH HAS NOT BEEN FILLED BY THE OWNER OR WITH HIS / HER
(WRIT TEN) CONSENT IS A VIOLATION OF TRANSPORT REGULATIONS.
================== Physical/Chemical Properties ==================
Boiling Pt:=-33.9C, -29.3F
Melt/Freeze Pt:=-101.C, -149.8F
M.P/F.P Text:(FREEZEING POINT)
Vapor Pres:100.2 PSIA @ 70F
Vapor Density:2.47 AIR=1
Spec Gravity:NOT AVAILABLE
pH:NOT AVAILABLE
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:VERY SOLUBLE
Appearance and Odor:GREENISH-YELLOW GAS WITH SHARP, SUFFOCATING ODOR;
LIQUID IS AMBER COLORED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
HYDROCARBONS, AMMONIA, ETHER, HYDROGEN, ACETYLENE, TURPENTINE, POWDERED
METALS AND OTHER REDUCING AGENTS.
=================== Toxicological Information===================
Toxicological Information:TUMORGENIC: EVIDENCE OF CARCINOGENIC ACTIVITY
IN EXPERIMENTAL RATS EXPOSED ORALLY. REPRODUCTIVE: EMBRYO AND
FETOTOXICITY OBSERVED AFTER EXPOS OF FEMALE RATS EXPOSED AT 565
MG/KG PRIOR TO MATING. EFFEC TS ALSO OBSERVED FROM EXPOSURE OF
PREGNANT RATS AT SAME LEVEL. MUTAGENIC: MUTAGENIC EFFECTS SEEN IN
BACTERIAL, MAMMALIAN AND INSECT ASSAY SYSTEMS. OTHER: TOXIC EFFECTS
REPORTED INRENAL SYSTEM, BLOOD A ND SPLEEN FROM INHALATION EXPOSURE
OF RATS.
===================== Ecological Information =====================
Ecological:NO DATA GIVEN. FIRST AID (CONT): ASSISTED TO
UNCONTAMINATED AREA AND INHALE FRESH AIR. UNCONSCIOUS PERSONS
SHOULD BE MOVED TO AN UNCONTAMINATED AREA AND GIVEN ARTIFICIAL
RESUSCITATION AND SUPPLEMENT AL OXYGEN. ASSURE THAT MUCOUS OR
VOMITED MATERIAL DOES NOT OBSTRUCT AIRWAY BY USE OF POTENTIAL
DRAINAGE. DELAYED PULMONARY EDEMA MAY OCCUR. KEEP PATIENT UNDER
MEDICAL OBSERVATION FOR AT LEAST 24 HRS. HANDLING AND STORAGE
ORECAUTIONS (CONT): OUTLET PIPED TO USE POINT. DO NOT DRAG, SLIDE
OR ROLL CYLINDERS. USE SUITABLE HAND TRUCK FOR CYLINDER MOVEMENT.
USE PRESSURE-REDUCING REGULATOR WHEN CONNECTIN G CYLINDER TO LOWER
(FEDERAL REGULATORY)
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF RESIDUAL WASTE OR
UNUSED QUANTITIES. RETURN IN THE SHIPPING CONTAINER PROPERLY
LABELED, WITH ANY VALVE OUTLET PLUGS OR CAPS SECURED AND VALVE
PROTECTION CAP IN PLACE TO BO C GASES OR AUTHORIZED DISTRIBUTOR FOR
PROPER DISPOSAL. DISPOSE OF IAW ALL FEDERAL, STATE & LOCAL REG
ULATIONS .
=================== MSDS Transport Information ===================
Transport Information:U.S. D.O.T.-PROPER SHIPPING NAME: CHLORINE,
HAZARD CLASS: 2.3, ID #: UN 1017, SHIPPING LABEL: POISON GAS,
CORROSIVE.CANADA TDG: PROPER SHIPING NAME: CHLORINE, HAZARD
CLASS: 2.3 (5.1), ID #: UN 1017, SHIPPING LABEL: POISON GAS,
OXIDIZER. ADDITIONAL MARKING REQURIEMENT: "INHALATION HAZARD". IF
NET WEIGHT OF PRODUCT > OR = 10 LBS, CONTAINER MUST ALSO BE MARKED
WITH LETTERS "RQ".ADDITIONAL SHIPPIN G PAPER DESCRIPTION
REQUIREMENT: "POISON-INHALATION HAZARD, ZONE B". IN NET WEIGHT OF
PRODUCT > OR = 10 LBS, SHIPPING PAPERS MUST BE MARKED WITH LETTERS
"RQ".
===================== Regulatory Information =====================
SARA Title III Information:CHLORINE LISTED AS EXTREMELY HAZARDOUS
SUBSTANCE (EHS) SUBJ TO STATE/LOCAL REPORTING UNDER SEC 304 OF SARA
TITLE II (EPCRA). PRESENCE OF CHLORINE IN QTYS IN EXCESS OF
THRESHOLD PLANNING QTY (TPQ) OF 1 00 LBS REQUIRES CERTAIN EMERGENCY
PLANNING ACTIVITIES TO BE CONDUCTED. RELEASES OF CHLORINE IN QTYS =
OR > RQ OF 10 LBS ARE SUBJ TO REPORTING TO NAT'L RESPONSE CNTR
UNDER CERCLA. SECTION 304 SARA TITL E III.SARA TITLE III-HAZARD
CLASSES: ACUTE HEALTH HAZ, CHRONIC HEALTH HAZ, FIRE HAZ, SUDDEN
RELEASE OF PRESSURE HAZ, REACTIVITY HAZ. SEC 313: PRODUCT CONTAINS
CHLORINE-SUBJ TO REPORTING RQMTS OF SEC 312 OF EPCRA OF 1986 & 40
CFR 372.
Federal Regulatory Information:CHLORINE LISTED UNDER ACCIDENT
PREVENTION PROVISIONS OF SEC 112(R) OF THE CLEAN AIR ACT WITH A
THRESHOLD QTY (TQ) OF 2500 POUNDS. SIGNS AND SYMPTOMS OF
OVEREXPOSURE (CONT): IRRITANT: YES. SENSITIZA TION: NO.
TERATOGEN: YES. REPRODUCTIVE HAZARD: YES.MUTAGEN: YES.
SYNERGISTIC EFFECTS: OTHER AGENTS THAT IRRITATE THE RESPIRATORY
SYSTEM. ECOLOGICAL INFO (CONT): PRESSURE (<250 PSIG) PIPING OR SY
STEMS. DO NOT HEAT CYLINDER BY ANY MEANS TO INCREASE RATE OF
PRODUCT FROM THE CYLINDER. USE A CHECK VALVE OR TRAP IN THE
DISCHARGE LINE TO PREVENT HAZARDOUS BACK FLOW INTO CYLINDER.
PROTECT CYLINDERS FROM PHYSICAL DAMAGE. (STATE REGULATORY)
State Regulatory Information:N/P. ECOLOGICAL INFO (CONT): STORE IN
COOL, DRY, WELL-VENTILATED AREAS OF NON-COMBUSTIBLE CONSTRUCTION
AWAY FROM HEAVILY TRAFFICKED AREAS AND EMERGENCY EXITS. DO NOT
ALLOW THE TEMPERATURE WHERE CYLIN DERS ARE STORED TO EXCEED 125F
(52C). CYLINDERS SHOULD BE STORED UPRIGHT AND FIRMLY SECURED TO
PREVENT FALLING OR BEING KNOCKED OVER. FULL & EMPTY CYLINDERS
SHOULD BE SEGREGATED. USE A "FIRST IN-FIRST OUT" INVENTORY SYSTEM
TO PREVENT FULL CYLINDERS FROM BEING STORED FOR EXCESSIVE PERIODS
OF TIME. F OR ADDITIONAL STORAGE RECOMMENDATIONS, CONSULT
COMPRESSED GAS ASSOCIATION'S PAMPHLET P-1.
======================= Other Information =======================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ETERNZFLEX PT-B URETHANE SEALANT 1720-000
CAGE:EO591
CAGE:33394
CAGE:EO591
============= Composition/Information on Ingredients =============
Ingred Name:ADDUCT OF TOLUENE DIISOCYANATE & POLYHYDRIC ALCOHOL
Fraction by Wt: 100%
===================== Hazards Identification =====================
Effects of Overexposure:BREATHLESSNESS,TIGHTNESS OF CHEST,MUCOUS MEMB
IRRIT.LUNG INJURY & PULMON EDEMA AFTER SERIOUS VPR EX
======================= First Aid Measures =======================
First Aid:SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/WATER FOR 15 MIN.
CONSULT MD. INTERN: DRINK WATER & INDUCE VOMIT. SEE MD. ALSO REFER
TO CHEM SAFETY DATA SHEET SD-73, TOULENE DIISOCYANATE PUB BY MFG
CHEMISTS ASSOC.
===================== Fire Fighting Measures =====================
Flash Point:>270C
Extinguishing Media:CO*2, DRY CHEM, CHEM FOAM
Fire Fighting Procedures:SELF-CONTAINED BRTHNG APPARATUS AGAINST FUMES,
NO*2 & TDI
Unusual Fire/Explosion Hazard:KEEP AWAY FROM OPEN FLAME
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB IN ABSORBENT MATL SUCH AS "OIL DRY" OR
SAWDUST. PLACE IN OPEN TOP CONTAINERS & TREAT W/WATER CONTAINING 1%
AMMONIA. PROTECTIVE EQUIP. SHOULD BE WORN BY PERSONNEL ENGAGED IN
CLEAN-UP & PROPER VE NTILATION UTILIZED.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID BODY CONTACT AND INHALATION.
PROTECT FROM WATER VAPOR AND HEAT. KEEP DRY ATMOSPHERE IN STORAGE
CONTAINERS
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELF-CONTAINED BRTHNG APPAR, POST. PRESS HOSE
MASK, CNISTER-TY
Ventilation:LOCAL EXHAUST-ADEQUATE TO KEEP VAPOR BELOW TLV
Other Protective Equipment:PROTECTIVE CLOTHING,BOOTS,&CAP.EYEWASH &
SAFETY SHOWER
Supplemental Safety and Health
V-P IS 0.01, VAP DENS.-HEAVIER THAN AIR. MFR'S ADDRESS IS: 2366
WOODHILL RD., CLEVELAND, OH 44106
================== Physical/Chemical Properties ==================
NRC/State Lic Num:NA
Boiling Pt:B.P. Text:>500F
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:0.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER BASIC CMPDS, ALCOHOLS
Stability Condition to Avoid:PROLONGED TEMP >120F & WATER CONTAMINATION
Hazardous Decomposition Products:NITROGEN DIOXIDE FUMES & TDI VAPORS
Conditions to Avoid Polymerization:CONTAM MAY CAUSE HEAT & PRESS
BUILDUP IN TIGHT CONTAINER
==================== Disposal Considerations ====================
Waste Disposal Methods:REFER TO STEPS TO BE TAKEN IN CASE OF SPILLAGE.
COMPLY W/FED, STATE, LOCAL REG REGARDING ENVIRONMENTAL CONTROL.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:AMERZINE 15 CORROSION INHIBITOR
Resp. Party Other MSDS Num.:305.0181583-010.007
Preparer's Name:NOT PROVIDED.
CAGE:34897
CAGE:34897
Contract Num:SP0450-00-M-D635
CAGE:1KH20
============= Composition/Information on Ingredients =============
Ingred Name:HYDRAZINE (SARA 302/313) (CERCLA)
CAS:302-01-2
RTECS #:MU7175000
= Wt:15.
Other REC Limits:NOT PROVIDED.
OSHA PEL:S, 1 PPM
ACGIH TLV:S, 0.01 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT PROVIDED.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: LIVER.EYE: CAN CAUSE
SEVERE IRRITATION, STINGING, TEARING, REDNESS, SWELLING. CAN INJURE
EYE TISSUE. SKIN: CAN CAUSE IRRITATION. SYMPTOMS MAY INCLUDE
REDNESS, BURNING, SKIN DAMAGE. MA Y CAUSE ALLERGIC SKIN REACTION
AND BLISTERING. SWALLOWING: MAY BE HARMFUL OR FATAL. SYMPTOMS MAY
INCLUDE SEVERE STOMACH AND INTESTINAL IRRITATION, NAUSEA, VOMITING,
DIARRHEA. MAY CAUSE BURNS AND DESTR OY TISSUES IN THE MOUTH,
THROAT, AND DIGESTIVE TRACT. LOW BLOOD PRESSURE AND SHOCK MAY OCCUR
AS A RESULT OF SEVERE TISSUE INJURY. INHALATION: MAY BE HARMFUL OR
FATAL. MAY CAUSE SEVERE IRRITATION AND B URNS TO NOSE, THROAT,
RESPIRATORY TRACT.
Explanation of Carcinogenicity:HYDRAZINE HAS BEEN SHOWN TO CAUSE CANCER
IN LABORATORY ANIMALS EXPOSED ORALLY, BY INHALATION, OR BY
INJECTION INTO THE ABDOMEN. IT IS LISTED AS CARCINOGENIC BY IARC
AND NTP.
Effects of Overexposure:SIGNS AND SYMPTOMS OF OVEREXPOSURE TO THIS
MATERIAL THROUGH BREATHING, SWALLOWING, AND/OR PASSAGE OF THE
MATERIAL THROUGH THE SKIN MAY INCLUDE: CENTRAL NERVOUS SYSTEM
DEPRESSION (DIZZINESS, DROWSINESS , WEAKNESS, FATIGUE, NAUSEA,
HEADACHE, UNCONSCIOUSNESS), BLOOD ABNORMALITIES (BREAKAGE OF RED
BLOOD CELLS), KIDNEY DAMAGE, LIVER DAMAGE, CONVULSIONS.
Medical Cond Aggravated by Exposure:PREEXISTING DISORDERS OF THE
FOLLOWING ORGANS (OR ORGAN SYSTEMS) MAY BE AGGRAVATED BY EXPOSURE
TO THIS MATERIAL: SKIN, LUNGS (FOR EXAMPLE, ASTHMA-LIKE
CONDITIONS), LIVER, KIDNEY.
======================= First Aid Measures =======================
First Aid:EYES: REMOVE FROM EXPOSURE. IMMEDIATELY FLUSH EYES GENTLY
WITH WATER FOR AT LEAST 15 MINUTES WHILE HOLDING EYELIDS APART.
SEEK MEDICAL ATTENTION. SKIN: FLUSH SKIN WITH WATER FOR 15 MINUTES
WHILE REMOV ING CONTAMINATED CLOTHING. SEEK MEDICAL ATTENTION.
SWALLOWING: SEEK MEDICAL ATTENTION. IF INDIVIDUAL IS DROWSY OR
UNCONSCIOUS, DO NOT GIVE ANYTHING BY MOUTH; PLACE ON LEFT SIDE WITH
THE HEAD DOWN. CON TACT PHYSICIAN WHETHER TO INDUCE VOMITING. IF
POSSIBLE, DO NOT LEAVE INDIVIDUAL UNATTENDED. INHALATION: MOVE TO
FRESH AIR. SEEK MEDICAL ATTENTION. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BRE ATHING IS DIFFICULT, ADMINISTER
OXYGEN.
===================== Fire Fighting Measures =====================
Flash Point:>93.3C, 200.F
Lower Limits:4.7
Upper Limits:99.0
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:WATER MAY BE USED TO KEEP FIE-EXPOSED
CONTAINERS COOL UNTIL FIRE IS OUT. WEAR A SELF-CONTAINED BREATHING
APPARATUS WITH A FULL FACEPIECE OPERATED IN POSITIVE PRESSURE
DEMAND MODE WITH APPROPRIATE TURN -OUT GEAR AND CHEMICAL RESISTANT
PERSONAL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:FLAMMABLE AIR-VAPOR MIXTURE MAY FORM.
HYDRAZINE CAN IGNITE SPONTANEOUSLY WHEN DISPERSED IN AIR AND WHEN
IN CONTACT WITH POROUS MATERIALS SUCH AS EARTH, ASBESTOS, WOOD OR
CLOTH (RAGS SHOULD NEVER BE US ED TO WIPE-UP SPILLS).
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: COVER WITH SODA ASH OR SODIUM
BICARBONATE AND MIX. IF EFFERVESCENT, WAIT UNTIL REACTION IS
COMPLETE. SCOOP INTO LARGE BEAKER. LARGE SPILL: ELIMINATE IGNITION
SOURCES. WEAR PROTECTIVE EQUI PMENT. STOP SPILL AT SOURCE. PREVENT
FROM ENTERING SEWERS, DRAINS. IF RUNOFF OCCURS, NOTIFY AUTHORITIES
AS REQUIRED. TRANSFER TO CONTAINERS FOR RECOVERY. ABSORB
UNRECOVERABLE MATERIAL FOR DISPOSAL.
Neutralizing Agent:NOT PROVIDED.
======================Handling and Storage ======================
Handling and Storage Precautions:HYDRAZINE-CONTAINING PRODUCTS SHOULD
BE STORED AT TEMPERATURES WELL BELOW THEIR BOILING POINTS, AWAY
FROM IGNITION SOURCES AND OXIDANTS, AND PREFERABLY OUTDOORS. IT
SHOULD BE SHELTERED OUTDOORS AGAINS T DIRECT SUNLIGHT, DIRT, SNOW,
WATER, AND ICE ACCUMULATION. TANK SHOULD BE ELECTRICALLY GROUNDED.
Other Precautions:FOR INDOOR STORAGE AREAS, CONTINUOUS VENTILATION
SHOULD BE PROVIDED. MAJOR STORAGE AREAS SHOULD BE DIKED WITH
CONCRETE TO HOLD AT LEAST 110% OF THE TOTAL STORAGE CAPACITY AND
HAVE A CONCRETE SLAB BELO W THE STORAGE TANK, SO THAT SPILLED
HYDRAZINE WILL NOT BE SOAKED INTO GROUND. CONTAINERS MAY BE HAZA
RDOUS WHEN EMPTIED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WORKPLACE SHOULD BE MONITORED IF EXPOSURE TO
VAPOR/MISTS EXCEEDS PEL/TLV. ONLY NIOSH APPROVED RESPIRATOR &
CARTRIDGE (TC-23C) IS TO BE USED. MONITOR RESULTS TO ASSESS PROPER
LEVEL OF RESPIRATORY PROTE CTION NECESSARY (FULL FACE PIECE
RESPIRATOR WITH CHEMICAL CARTRIDGES/SELF-CONTAINED BREATHING
APPARATUS). OBSERVE REQUIREMENTS ESTABLISHED IN 29 CFR 1910.134.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL)
EXHAUST VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
REGULATIONS ARE ADVISED.
Other Protective Equipment:TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS
FULL-BODY PROTECTIVE CLOTHING.
Work Hygienic Practices:NOT PROVIDED.
Supplemental Safety and Health
OSHA REGULATIONS ALSO PERMIT OTHER TYPE SAFETY GLASSES. (CONSULT YOUR
INDUSTRIAL HYGIENIST.)
================== Physical/Chemical Properties ==================
HCC:T4
NRC/State Lic Num:NOT RELEVANT.
Boiling Pt:=100.C, 212.F
B.P. Text:@ 760MMHG
Melt/Freeze Pt:=-13.9C, 7.F
Decomp Temp:Decomp Text:NOT PROVIDED.
Vapor Pres:NO DATA
Vapor Density:>1.00AIR=1
Volatile Org Content %:15
Spec Gravity:1.012 @ 77F
pH:10.5-11.5
Viscosity:NOT PROVIDED.
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Solubility in Water:NOT PROVIDED.
Appearance and Odor:PALE YELLOW LIQUID; ODOR NOT DETERMINED
Percent Volatiles by Volume:85.0 - 100
Corrosion Rate:NOT PROVIDED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COPPER, COPPER ALLOYS, LEAD, LEAD ALLOYS, ORGANIC MATERIALS, STRONG
MINERAL ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:AMMONIA, CARBON DIOXIDE, CARBON
MONOXIDE, NITROGEN COMPOUNDS.
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.
=================== Toxicological Information===================
Toxicological Information:NO DATA.
===================== Ecological Information =====================
Ecological:NO DATA.
==================== Disposal Considerations ====================
Waste Disposal Methods:MIX WITH EQUAL VOLUME OF SODA ASH AND ADD WATER
TO FORM A SLURRY IN A LARGE CONTAINER. ADD CALCIUM HYPOCHLORITE,
ADD MORE WATER AND LET STAND FOR 2 HRS, NEUTRALIZE AND WASH DOWN
DRAIN WITH EXCESS WATE R IN ACCORDANCE WITH APPLICABLE REGULATIONS.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STA TE AND
FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:DOT DESCRIPTION: HYDRAZINE, AQUEOUS SOLUTIONS,
6.1, UN3293, III. CONTAINER/MODE: 55 GAL DRUM/TRUCK PACKAGE.
===================== Regulatory Information =====================
SARA Title III Information:CERCLA REPORTABLE QUANTITY (RQ) : 1 POUND.
SARA 302 COMPONENTS - 40 CFR 355 APPENDIX A: TPQ: 1000 LBS. SECTION
311/312 HAZARD CLASS: IMMEDIATE AND DELAYED. SECTION 313
COMPONENT(S): HYDRAZINE 302-01- 2 15.01%
Federal Regulatory Information:TSCA (TOXIC SUBSTANCES CONTROL ACT)
STATUS: TSCA (UNITED STATES) THE INTENTIONAL INGREDIENTS OF THIS
PRODUCT ARE LISTED. EPA ACCIDENTAL RELEASE PREVENTION 40 CFR 68:
HYDRAZINE TQ: 15000 LBS.
State Regulatory Information:CALIFORNIA PROPOSITION 65: THE FOLLOWING
STATEMENT IS MADE IN ORDER TO COMPLY WITH THE CALIFORNIA SAFE
DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986: THIS PRODUCT
CONTAINS THE FOLLOWING SUBSTANCE(S ) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. HYDRAZINE. NEW JERSEY RIGHT-TO-KNOW
LABEL INFORMATION: HYDRAZINE 302-01-2. PENNSYLVANIA RIGHT-TO-KNOW
LABEL INFORMATION: HYDRAZINE 302-01-2.
======================= Other Information =======================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:DIBUTYL PHTHALATE 99%, AC166600000
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:DIBUTYL PHTHALATE
CAS:84-74-2
RTECS #:TI0875000
= Wt:99.
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 8 GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: CONTACT PRODUCES
IRRITATION, TEARING, AND BURNING PAIN. SKIN: MAY CAUSE SKIN
IRRITATION. MAY CAUSE ALLERGIC DERMATITIS. INGESTION: INGESTION OF
LARGE AMOUNTS MAY CAUSE GASTROINTESTINAL IRR ITATION. INHALATION:
MAY CAUSE RESPIRATORY TRACT IRRITATION. INHALATION OF A MIST OF
THIS MATERIAL MAY CAUSE RESPIRATORY TRACT IRRITATION. TARGET
ORGANS: NONE KNOWN. CHRONIC: NO INFORMATION FOUND.
Effects of Overexposure:SEE HEALTH HAZARDS. OTHER INFO: OEL-RUSSIA:
STEL 0.5 MG/M3 OEL-SWEDEN:TWA 3 MG/M3; STEL 5 MG/M3
OEL-SWITZERLAND: TWA 5 MG/M3 OEL-UNITED KINGDOM: TWA 5 MG/M3; STEL
10 MG/M3 JAN9 OEL IN BULGARIA, COLOM BIA, JORDAN, KOREA CHECK ACGIH
TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM CHECK ACGI TLV.
======================= First Aid Measures =======================
First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS,
OCCASNLY LIFTING UPPER & LOWER LIDS. GET MEDICAL AID IMMEDIATELY.
SKIN: FLUSH W/PLENTY OF SOAP & WATER FOR AT LST 15 MINS WHILE
REMOVING CONTAMD CLTHG & SHOES. GET MEDICAL AID IF IRRIT
DEVELOPS/PERSISTS. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4
CUPFULS OF MILK/WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON
PERSON. GET MEDICAL AID. INHAL : REMOVE TO FRESH AIR IMMED. IF NOT
BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. GET MEDICAL
AID. NOTES TO PHYS: TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
===================== Fire Fighting Measures =====================
Flash Point:=171.C, 339.7F
Autoignition Temp:=399.C, 750.2F
Extinguishing Media:WATER OR FOAM MAY CAUSE FROTHING. USE WATER SPRAY
TO COOL FIRE-EXPOSED CONTAINERS. USE CARBON DIOXIDE OR DRY
CHEMICAL.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR
EQUIVALENT), AND FULL PROTECTIVE GEAR.
================== Accidental Release Measures ==================
Spill Release Procedures:GEN INFO: USE PROPER PERSONAL PROT EQUIP AS
INDICATED IN SECTION 8. SPILLS/LEAKS: SWEEP UP OR ABSORB MATERIAL,
THEN PLACE IN A SUITABLE CLEAN, DRY, CLOSED CONTAINER FOR DISPOSAL.
PROVIDE VENTILATION.
======================Handling and Storage ======================
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. USE
ONLY IN A WELL VENTILATED AREA. AVOID CONTACT WITH EYES, SKIN, AND
CLOTHING. AVOID INGESTION AND INHALATION.
Other Precautions:STORE IN A TIGHTLY CLOSED CONTAINER. STORE IN A COOL,
DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
FEDERAL REGULATORY INFO: UNDER THE CWA. OSHA: NONE OF CHEMICALS IN PROD
ARE CONSIDERED HIGH HAZARDOUS BY OSHA. EUROPEAN/INTERNATIONAL REGS.
EUROPEAN LABELING I/A/W EC DIRECTIVES. HAZARD SYMBOLS: NOT A
VAILABLE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:340760.00 DEG C
Melt/Freeze Pt:=-35.C, -31.F
Vapor Pres:<0.01 @ 20C
Vapor Density:9.5
Spec Gravity:1.0430 G/CM3
Viscosity:22 CP 20 DEG C
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID. WEAK AROMATIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES, LIQUID CHLORINE,
NITRATES.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
=================== Toxicological Information===================
Toxicological Information:RTECS#: CAS# 84-74-2: TI0875000. LD50/LC50:
CAS# 84-740-2: INHALATION, MOUSE: LC50 = 25 GM/M3/2H; INHALATION,
RAT: LC50 = 4250 MG/M3; ORAL, MOUSE: LD50 = 5289 MG/KG; ORAL, RAT:
LD50 = 8 GM/KG; SKIN, R ABBIT: LD50 = >20 GM/KG; CARCINOGENICITY:
CAS# 84-74-2: NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA.
EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE EFTS, NEUROTOXICITY,
MUTAGENICITY & OTHER STUDIES: NO DATA AVAILABLE.
===================== Ecological Information =====================
Ecological:ECOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL, OTHER:
NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONC OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOX REFERENCE
LEVELS: NONE LISTED. RCRA F & P SERIES: NONE LISTED. RCRA
U-SERIES: CAS # 84-74-2: WASTE NUMBER U069.
=================== MSDS Transport Information ===================
Transport Information:SHIPPING NAME: US DOT: NO INFORMATION AVAILABLE.
IATA: NOT REGULATED AS A HAZARDOUS MATERIAL. RID/ADR: NOT REGULATED
AS A HAZARDOUS MATERIAL. IMO: NOT REGULATED AS A HAZARDOUS
MATERIAL. NO INFORMATION AVAILABLE.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302(RQ). CAS# 84-74-2: FINAL RQ = 10
POUNDS (4.54 KG). SECTION 302 (TPQ). NONE OF CHEMS IN PROD HAVE
TPQ. SECTION 313. THIS MATL CNTNS DIBUTYL PHTHALATE (CAS# 84-74-2,
99%), WHICH IS SUBJECT T O RPTG REQUIREMENTS OF SECTION 313 OF SARA
TITLE III & 40 CFR PART 373. CLEAN AIR ACT: CAS# 84-74-2 IS LISTED
AS HAZ AIR POLLUTANT (HAP). THIS MATL DOES NOT CNTN ANY CLASS 1
OZONE DEPLETORS. THIS MATLDOES NOT CNTN ANY CLASS 2 OZONE
DEPLETORS. CLEAN WATER ACT: CAS# 84-74-2 LISTED AS HAZ SUBSTANCE
UNDER CWA, & AS PRIORITY POLLUTANT UNDER CLEAN WATER ACT. NONE OF
CHEMS IN PROD ARE LISTED AS TOXIC PO LLUTANTS (SUPDAT)
Federal Regulatory Information:TSCA. CAS# 84-74-2 IS LISTED ON TSCA
INVENTORY. HEALTH & SAFETY REPORTING LIST. NONE OF CHEMICALS ARE ON
HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST RULES. NONE OF THE
CHEMICALS IN THIS RPOD ARE UND ER CHEMICAL TEST RULE. SECTION 12B.
CAS# 84-74-2: EXPORT NOTIFICATION REQD - SECTION 4. TSCA
SIGNIFICANT NEW USE RULE. NONE OF CHEMICALS IN THIS MATERIAL HAVE A
SNUR UNDER TSCA.
State Regulatory Information:CAS# 84-74-2 CAN BE FOUND ON THE FOLLOWING
STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA,
PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT
RISK LEVEL: NONE OF THE CHEMICA LS IN THIS PRODUCT ARE LISTED.
======================= Other Information =======================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:845 0306 KODAK FLEXICOLOR DEVELOPER REPLENISHER LORR, SOLN
Kit Part:Y
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 90-95%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POTASSIUM CARBONATE
CAS:584-08-7
RTECS #:TS7750000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:4-(N-ETHYL-N-2-HYDROXYETHYL)-2-METHYLPHENYLENEDIAMINE
SULFATE
CAS:25646-77-9
RTECS #:KJ6477000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:PENIETIC ACID, PENTA SODIUM SALT
CAS:140-01-2
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION:A LOW HAZARD FOR
RECOMMENDED HANDLING. EYE: MAY CAUSE TRANSIENT IRRITATION. SKIN:
MAY CAUSE ALLERGIC SKIN REACTION. INGESTION:EXPECTED TO BE LOW
HAZARD FOR RECOMMENDED HANDLING. MAY CAUSE I RRITATION OF THE G/I
SYSTEM.
Explanation of Carcinogenicity:IN ADDITION TO THE ABOVE, PRODUCT IS
NEGATIVE W/REGARD TO:ACGIH CANCER, CALIFORNIA CANCER & REPRODUCTIVE
EFFECTS.
Effects of Overexposure:EYE IRRITATION. G/I TRACT IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:IF ANY SYMPTOMS OCCUR, GET IMMEDIATE MEDICAL ATTENTION.
INHALATION:IF SYMPTOMATIC,MOVE TO FRESH AIR. EYE:FLUSH W/PLENTY OF
WATER FOR 15 MIN. SKIN:FLUSH W/WATER 15 MIN. REMOVE CONTAMINATED
CLOTHING & L AUNDER BEFORE REUSE. INGESTION:DRINK 1-2 GLASSES OF
WATER & GET IMMEDIATE MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER W/LARGE AMOUNTS OF WATER. MAY
REQUIRE NEUTRALIZATION IF PH <2.0 OR >12.5.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:NO SPECIAL PRECAUTIONARY MEASURES SHOULD BE NEEDED
UNDER ANTICIPATED CONDITIONS OF USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:USE GOOD GENERAL VENTILATION (10 CHANGES/HR). MATCH
VENTILATION RATES TO CONDITIONS.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK OF EXPOSURE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
THIS ENTRY FOR WORKING SOLUTION.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.04
pH:10.1
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS. ODORLESS. LIQUID.
Percent Volatiles by Volume:90-959
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY
REASONABLY COME INTO CONTACT.
Stability Condition to Avoid:STABLE.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH
<2.0 OR >12.5. FLUSH TO SEWER W/LARGE AMOUNTS OF WATER.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:879 5007 RP X-OMAT DVLPR & REPLNSHER,TO MAKE 1 LITER, PART B
Kit Part:Y
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:ACETIC ACID (CERCLA)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 70-75%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 15-20%
Other REC Limits:NONE RECOMMENDED
Ingred Name:1-PHENYL-3-PYRAZOLIDONE
CAS:92-43-3
RTECS #:UQ8750000
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
Ingred Name:5-NITRO-1H-INDAZOLE
CAS:5401-94-5
RTECS #:NK7962000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTAINS DIETHYLENE GLYCOL.CAN CAUSE
KID DMG & CNS EFFECTS AFAT INGEST.CONTAINS ACETIC ACID.ACUTE
OVEREXP TO EXT HI AIRBONRE CONC OF RESP IRRIT HAS BEEN ASSOC
W/DVLPMT OF ASTHMA-LIKE AIRWAYS SYNDROME( RADS)IN SUSCEPTIBLE
PEOPLE WHICH ARE NOT GENERATED DURING NORM CONDITIONS OF USE BUT
MAY OCCUR IN SPILL-DEPENDS(SIGN/SY)
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY
CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE.
Effects of Overexposure:HEALTH:ON PHYS FACTORS(SOLN CONC,SPILL VOL,SURF
AREA,RM SIZE,VENTI RATE).INHAL:VAP EXTREMELY IRRIT.EYE:CAUSES
SEVERE BURNS,VAP EXTREMELY IRRIT.SKIN:CAUSES SEVERE BURNS.MAY CAUSE
ALLERGIC SKIN RX BASED ON HUMAN EXPERIENCE.INGEST:POISON.MAY BE
FATAL OR HARMFUL IF SWALLOWED.MAY CAUSE BURNS OF GI TRACT IF
SWALLOWED..
Medical Cond Aggravated by Exposure:ACUTE OVEREXPO TO EXTREMELY HIGH
AIRBORNE CONC OF RESP IRRITANTS HAS BEEN ASSOC W/DEVELOPMENT OF
ASTHMA-LIKE REACTIVE AIRWAYS SYNDROME(RADS)IN SUSCEPTIBLE
INDIVIDUALS.
======================= First Aid Measures =======================
First Aid:INHAL:MOVE TO FRESH AIR.BREATH DIFFI GIVE OXY;NOT BREATH GIVE
ART RESP.GET MED ATTN.EYE:IMMED FLUSH W/PLENTY OF H2O FOR @LEAST
15MINS.GET MED ATTN IMMED.IRRIT FRM AIRBORNE EXPO MOVE TO FRESH
AIR.SKIN: IMMED FLUSH W/PLENTY OF H2O FOR @LEAST 15MINS.GET MED
ATTN IMMED.INGEST:DONT INDUCE VOMIT.GIVE GLASS OF WATER.NEVER GIVE
ANYTHING BY MOUTH IF UNCONSC.CALL DR/POIS CNTRL CNTR IMMED.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:115F,46C
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE(CO2),
ALCOHOL FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAIN BREATH APPARATUS &
PROTECTIVE CLOTH.FIRE/EXCESSIVE HEAT MAY PRODUCE HAZS DECOMPOSITION
PRODUCTS.USE WATER SPRAY TO KEEP FIRE-EXPO CNTNR COOL.
Unusual Fire/Explosion Hazard:CLASSIFIED AS COMBUSTIBLE.MATERIAL
CONTAINS COMBUSTIBLE SOLVENT THAT MAY ACCUMULATE IN CONTAINER
HEADSPACE.MAY FORM PEROXIDES OF UNKNOWN STABILITY.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGN SOURCES.FLUSH TO SEWER W/LG
AMTS OF H2O.OTHERWISE ABSORB SPILL W/VERMICULITE/OTHER INERT
MATL,THEN PLACE IN CNTNR FOR CHEM WASTE.CLEAN SURFACE THOROUGHLY TO
REMOVE RESIDUEAL CONTAMIN ATIO
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DONT BREATH VAP @CONC >EXPO
LIMITS.DONT GET IN EYE/SKIN/CLOTH.USE ONLY W/ADEQU VENTI.KEEP FRM
CONTACT W/OXID MATL,AWAY FROM HEAT/FLAME.KEEP CNTNR CLSD
Other Precautions:PEROXIDE FORMATION SUSPECTED DONT OPN/MOVE CNTNR.MIN
EXPO TO AIR.STORE AWAY FROM HEAT/LIGHT.MATL STRONGLY ACIDIC AQU
SOLN.PROPERTIES:HI BIOCHEM OXY DEMAND,POT TO CAUSE OXY DEPLETION IN
AQU SYS,HI POT TO AFFECT AQUATIC ORGANISMS,HI POT(SUPP)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ENGINEER CNTRL DONT MAINTAIN AIRBORNE CONC BELOW
RECOMMENDED EXPO LIMITS APPROV RESP MUST BE WORN.RESP TYP:ORGANIC
VAPOR,FULL-FC ORG VAP CARTRIGDE.RESP USED PROGRAM SHOULD BE
INSTITUTED TO ASSURE COMP LIANCE WITH 29CFR1910.134.
Ventilation:USE GOOD GEN VENTI(TYP 10AIR CHANGES/HR).MATCH VENTI RATES
W/CONDITIONS.USE PROCESS ENCLOSURES,LOC EXHAU VENTI, (SUPPL)
Other Protective Equipment:PROTECTIVE CLOTHING APPROP FOR RISK OF
EXPO.EYEBATH,SAFETY SHOWER,WASHING FACILITIES.
Work Hygienic Practices:WASH CONTAM CLOTH BEF REUSE.DESTROY/CLEAN WELL
CONTAM SHOES.WASH WELL AFT HNDLG.
Supplemental Safety and Health
VENTI:OTHER ENGINEER CNTRL TO MAINTAIN AIRBONRE LEVELS BEL RECOMMENDED
EXPO LIMITS. OTH PREC:AFFECT PLANT GERM/GROWTH,LOW POT TO PERSIST
IN ENVIRO,LOW POT TO BIOCONC.AFT DIL W/LG AMT OF H2O THEN 2ND W
ASTE TREAT MATL NOT EXPECTED TO CAUSE ADVERSE ENVIRO EFFECTS.
KEY1=HCC:F6.
================== Physical/Chemical Properties ==================
HCC:F6
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:N/AVAI
Vapor Density:N/AVAI
Spec Gravity:1.08
pH:<1.0
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID, ORANGE COLOR, VINEGAR ODOR
Percent Volatiles by Volume:70-75
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, BASES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HAZ COMBUST PROD:CARBON DIOXIDE,CARBON
MONOXIDE,OXIDES OF NITROGEN. HAZ DECOMP PRODS:NONE SPECIFIED BY
MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHAR/TREAT/DISPO MAY BE SUBJ TO NAT/STATE/LOC
LAWS.FLUSH TO SEWER W/LG AMTS OF H2O.SINCE EMPT CNTNR RETAIN PROD
RESIDUE FOLLOW LABEL WARNS EVEN AFT CNTNR EMPTIED.CHEM SUBJ TO
REPORT REQMT OF SEC 31 3 TITLE III SARA/40CFR372:NONE.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:MIL-T-50036 A,TYPE T1,TALC TECHNICAL POWDER
Preparer's Name:C. A. EISENHARD
CAGE:8K477
CAGE:60777
CAGE:8K477
============= Composition/Information on Ingredients =============
Ingred Name:TALC (CONTAINING NO ASBESTOS)
CAS:14807-96-6
RTECS #:WW2710000
Other REC Limits:NONE SPECIFIED
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST; 9192
Ingred Name:SILICA, CRYSTALLINE
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE- EYES/SKIN:ABRASION MAY CAUSE
IRRITATION. INHALATION:MAY CAUSE IRRITATION TO THE UPPER
RESPIRATORY TRACT. LONG TERM, EXCESSIVE EXPOSURE MAY CAUSE SEVERE
AND PERMANENT DAMAGE TO THE LUNGS. ORAL:N ONE KNOWN. CHRONIC- MAY
CAUSE LUNG DAMAGE.
Explanation of Carcinogenicity:TALC CONTAINS CRYSTALLINE SILICA AT
LEVELS GREATER THAN 0.1%, BUT LESS THAN 1.0%.
Effects of Overexposure:ABRASION MAY CAUSE EYE OR SKIN IRRITATION.
INHALATION OF DUST MAY CAUSE IRRITATION OF THE UPPER RESPIRATORY
TRACT. LONG TERM, EXCESSIVE EXPOSURE MAY CAUSE SEVERE AND PERMANENT
DAMAGE TO THE LUNGS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:WASH WITH
SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS
OPEN. INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.
ORAL:IF C ONSCIOUS, DRINK LARGE AMOUNT OF WATER TO INDUCE VOMITING.
GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:AS APPROPRIATE FOR SURROUNDING COMBUSTIBLES. WATER
SPRAY MAY BE USED TO WET DOWN AND REDUCE AIRBORNE PARTICULATE
LEVELS.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS FOR DUST PROTECTION WHEN THIS FINE POWDER IS AIRBORNE IN
A FIRE SITUATION.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:THOSE INVOLVED IN CLEAN-UP SHOULD USE
RESPIRATORY PROTECTION FOR AIRBORNE DUST. VACUUM/SCOOP UP SPILLED
MATERIAL FOR RECOVERY/DISPOSAL, AVOIDING DUSTING CONDITIONS & USING
GOOD VENTILATION. WETTING SP ILLS WITH WATER SPRAY KEEPS DUST
LEVELSDOWN.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE IN AIRTIGHT CONTAINER.
USE WITH ADEQUATE DUST CONTROL.
Other Precautions:DO NOT RAISE DUST. AVOID CONTACT WITH EYES AND SKIN.
AVOID BREATHING DUST. WASH THOROUGHLY AFTER HANDLING MATERIAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF WORKPLACE EXPOSURE
LIMIT IS EXCEEDED, A NIOSH APPROVED AIR SUPPLIED RESPIRATOR OR DUST
RESPIRATOR IS ADVISED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER,
APPROPRIATE LABORATORY COAT TO COVER EXPOSED SKIN
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:2.5 - 2.8
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE POWDER; ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:TALC IS NOT CONSIDERED TO BE A RCRA HAZARDOUS
WASTE AND MAY BE DISPOSED OF IN A SITE SUITABLE FOR INDUSTRIAL
WASTES. REFER TO ANY LOCAL, STATE OR FEDERAL REGULATIONS FOR
SPECIFIC DISPOSAL INFORMATION.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:POLYTHIOETHER POLYMER COMPOUND PR1828 B-1/2
Kit Part:Y
CAGE:DO563
CAGE:83574
CAGE:DO563
============= Composition/Information on Ingredients =============
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 20.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:METHYL ETHYL KETONE (MEK) (SARA 313) (CERCLA) (VP = 70.0
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/STEL 300
ACGIH TLV:200 PPM/STEL 300
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:MERCAPTAN TERM. POLYTHIOETHR (NONHAZARDOUS)
CAS:119147-78-3
Other REC Limits:NONE RECOMMENDED
Ingred Name:SILICA DERIVATIVES (NON-HAZAARDOUS)
CAS:67762-90-7
Other REC Limits:NONE RECOMMENDED
Ingred Name:ALUMINUM HYDROXIDE (NON-HAZARDOUS)
CAS:21645-51-2
RTECS #:BD0940000
Other REC Limits:NONE RECOMMENDED
Ingred Name:VOC = 26 GR/L (COMBINED PART A & B)
RTECS #:9999999VO
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: BURN/TEAR/RED/CORNEAL CLOUDING.
SKIN: RED/BURN/DRYING/CRACKING. INHAL: COUGHING/CHEST PAIN, THROAT
IRRIT/HEADACHE/DIZZY/ANESTHETIC & CNS EFFECTS/LIVER DAMAGE. INGEST:
DROWSY/DIZZY/NAUSEA.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/LUKEWARM WATER FOR 15 MINUTES, GET MED AID.
SKIN: WASH W/SOAP & WATER, GET MED AID. INHAL: GET FRESH AIR, GET
MED AID. INGEST: GET MED AID.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:150F,66C
Lower Limits:1.8
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER.
Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN UP RESIDUE
W/SUITABLE SOLVENT. (CERCLA RQ FOR MEK IS 5000 LBS).
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. DONT
STORE >120F. GROUND/BOND WHEN TRANSPORTING.
Other Precautions:EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DONT CUT,
PUNCTURE, WELD ON OR NEAR DRUM. VAPORS >AIR & MAY COLLECT IN LOW OR
CONFINED AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ORGANIC VAPOR CARTRIDGE OR AIR SUPPLIED
RESPIRATOR.
Ventilation:GENERAL.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING OR BEFORE
SMOKING OR EATING.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Vapor Density:>AIR
Spec Gravity:1.42
Evaporation Rate & Reference:UNAVAILABLE
Appearance and Odor:WHITE THIXOTROPIC PASTE.
Percent Volatiles by Volume:2.5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:OXIDES OF CARBON, SULFUR DIOXIDE,
TRACES OF HYDROGEN SULFIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN ACCORDANCE W/FEDERAL, STATE, LOCAL & EPA
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:THERMALBOND PART B (RT-7)
Preparer's Name:KEITH MANDELL
CAGE:HO893
CAGE:13103
CAGE:HO893
============= Composition/Information on Ingredients =============
Ingred Name:PIPERAZINE
CAS:110-85-0
RTECS #:TK7800000
Fraction by Wt: <3%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PIPERAZINE, 1-(2-AMINOETHYL)-; (N-AMINOETHYLPIPERAZINE)
CAS:140-31-8
RTECS #:TK8050000
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ETHANOL, 2,2',2"-NITRILOTRI-; (TRIETHYLNOLAMINE)
CAS:102-71-6
RTECS #:KL9275000
Fraction by Wt: <7%
OSHA PEL:N/K
ACGIH TLV:5 MG/M3
Ingred Name:SUPDAT:MOST LTD RE-EXPOS TO OFFENDING CHEMS & HAVE TO BE
REMOVED FROM FURTHER CONTACT W/THEM.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:MANY EPOXY HARDENERS & TO LESS EXTENT RESINS
THEMSELVES, ARE PRIMARY SKIN IRRITS & SENSITIZING AGENTS.(ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:URETHANE SYS CNTNG ISOCYANATES AS WELL AS SOME EPOXY
HARDENERS, CAN BE IRRIT TO LUNGS IF HNDLD W/OUT ADEQ (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:VENT. PROCESSING OF THESE MATLS IN ENCLSD SYS
W/AUTOMATED EQUIP IS IDEAL SOLN TO THESE PROBS. WHEN USE OF (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:SUCH EQUIP IS NOT PRACTICAL SFTY PRECS SHOULD BE
CONSCIENTIOUSLY OBSERVED. SENSIT OF EPOXY CURING AGENTS & (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:RESINS CAN RSLT FROM FAILURE TO FOLLOW REC HNDLG
PROCS. CMPDS BASED ON LIQ EPOXY, RESINS HAVE GENRLY GOOD (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:STOR STABILITY IN CLSD CNTNRS. ONE COMPONENT SYS
CNTNG LATENT CATALYSTS HAVE LTD SHELF LIFE & SHOULD BE (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:STORED IN COOL PLACE. EPOXY RESINS & TO GREATER
DEGREE AMINE & ANHYDRIDE HARDENERS, ARE HYGROSCOPIC & (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:SHOULD BE PROT FROM MOISTURE. PRINCIPAL PROB IN
STORING FILLED CMPDS IS THAT OF FILLER SETTLING. AFTER (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:PRLNG STOR FILLERS IN SOME SYS WILL SETTLE INTO HARD
CAKE WHICH IS DFCLT TO DISPERSE. IT IS IMPORTANT TO (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:ROTATE STOCKS OF THESE MATLS/TO STIR THEM
PERIODICALLY. RATE OF FILLER SETTLING IS SUBSTANTIALLY REDUCED (ING
15)
RTECS #:9999999ZZ
Ingred Name:ING 14:IN LOW TEMP STOR. FEW RESINS & HARDENERS MAY FORM
CRYSTALS IN STOR. THIS CNDTN IS APPARENT ON VISUAL EXAM(ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:& CRYSTALS CAN BE RETURNED TO SOLUTION W/MODERATE
HEAT.
RTECS #:9999999ZZ
Ingred Name:VENT:DUCTING TO PROVIDE FOR REMOVAL OF FUMES. DUCT SHOULD
BE POSITIONED TO DRAW FUMES AWAY FROM WORKER RATHER (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:THAN DIRECTLY OVERHEAD. MIXING ON PRODUCTION BASIS
SHOULD TAKE PLACE UNDER AN EXHAUST HOOD.
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP:SELECTION OF SPECIFIC ITEMS SUCH AS BOOTS,
APRON/FULL-BODY SUIT WILL DEPEND UPON OPERATION. (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:THESE INCL BARRIER CREAMS, PAPER WORK COATS & OTHER
PROT GARMENTS. DISPOSABLE CNTNRS ARE PREF TO ONES (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:THAT REQ CLEANING & WORK BENCHES SHOULD BE COVERED
W/PAPER REPLACED AT FREQUENT INTERVALS. MILD SOAPS, (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21:EMULSIONS & NON-ABRASIVE SCRUBBERS SHOULD BE USED
FOR PERSONAL CLEAN-UP. WATERLESS CLEANERS ARE USEFUL (ING 23)
RTECS #:9999999ZZ
Ingred Name:ING 22:FOR IN-PROCESS CLEANING. DENATURED ALCOHOL IS PREF
TO SOLVS SUCH AS TOLUENE & ACETONE WHICH REMOVE OILS (ING 24)
RTECS #:9999999ZZ
Ingred Name:ING 23:FROM SKIN & WHICH THEMSELVES MAY CAUSE DERM. HAND
CREAM CNTNG LANOLIN IS USEFUL AS POST-CLEANUP SKIN CNDTNR.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE SEV IRRIT W/CORNEAL
INJURY WHICH MAY RSLT IN PERM IMPAIRMENT OF VISION, EVEN BLINDNESS.
INHAL:EXCESSIVE EXPOS MAY CAUSE IRRIT TO UPPER RESP TRACT. MAY
CAUSE RESP SENSIT/ASTHMA IN SUSCEPT IBLE INDIVIDUALS. SKIN:SHORT
SINGLE EXPOS MAY CAUSE BURNS, MAY CAUSE ALLERGIC RXN IN SUSCEPTIBLE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INDIVIDUALS. SINGLE PRLNG EXPOS MAY
RSLT IN MATL BEING ABSORBED IN HARMFUL AMTS. MOST INDIVIDUALS ARE
ENDOWED W/INITIAL RESIST TO EPOXY HARDENERS & RESINS WHICH
ENCOURAGES CARELESSNESS IN HND LG THEM. FIRST SIGN OF IRRIT, OFTEN
RASH RESEMBLING POIS IVY ON WRISTS/FOREARMS, CALLS FOR REVIEW OF
HNLDG (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/WATER FOR AT LST 30 MINS, PROMPT MED CONSULTATION
IS ESSNTL. SKIN:REMOVE CONTAM CLTHG IMMED. REMOVE UNCURED PROD
W/DRY CLOTH/TOWEL. WASH THORO W/SOAP & WATER. CONSULT MD IF IRRIT
DEVELOPS. DO NOT USE SOLV TO REMOVE PROD. LAUNDER CLTHG SEPARATELY
BEFORE REUSE. INHAL:REMOVE TO FRESH AIR IF EFTS OCCUR. CONSULT MD.
INGEST:DO NOT INDUCE VOMIT. GIVE LG AMTS OF WATER/MILK IF AVAIL &
(SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:335F,168C
Extinguishing Media:MOST STANDARD FIREFIGHTING AGENTS ARE SUITABLE,
I.E., SAND, ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICALS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:DURING A FIRE IRRITATING &/OR TOXIC GASES
MAY BE PRESENT FROM DECOMPOSITION/COMBUSTION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER SPILLS W/DRY ABSORBENT MATERIAL SUCH AS
SAND OR SAWDUST; SCOOP UP & PLACE IN AN APPROPRIATE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CORROSIVE. STOR TEMP:AMBIENT(80F,20C).
SPECIAL SENSITIVITY:MOISTURE & EXCESSIVE HEAT. STORE IN DRY AREA
AWAY FROM EXCESSIVE HEAT.
Other Precautions:GROUND ALL TRANSFER EQUIP. HOLD BULK STOR UNDER
NITROGEN BLANKET. THIS PROD SHOULD NOT COME INTO CONT W/COPPER OR
COPPER-BEARING ALLOYS. FEW REACTIVE RESIN SYS ARE ENTIRELY FREE
FROM HNDLG HAZS & INST RUCTED IN APPROP SFTY PROCS. (ING 5)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VAPOR EXPOSURE CAUSES IRRITATION, USE A
NIOSH/MSHA APPROVED FULL-FACE RESPIRATOR. SPRAYING SHOULD BE
CARRIED OUT IN A SPRAY BOOTH WITH A NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY W/ADEQ VENT. LOC EXHST VENT MAY BE NEC FOR SOME
OPERATIONS. WORK AREAS SHOULD BE EQUIPPED W/SUITABLE (ING 17)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA. USE PROT CLTHG IMPERVIOUS TO THIS MATL.(ING
19)
Work Hygienic Practices:SYSTEMATIC WASHING OF HANDS & WORK CLOTHES. KEY
TO SUCCESSFUL HNDLG OF REACTIVE RESINS IS PREVENTATIVE HYGIENE.
Supplemental Safety and Health
FIRST AID PROC:TRANSPORT TO MED FACILITY. EYE PROT:& FULL LNGTH FCSHLD
. EFTS OF OVEREXP:PROCS. NEGLECT MAY LEAD TO DEVEL OF DEEP SEATED
BLISTERS & SENSIT OF AFFECTED WORKER. SUSCEPTIBILITY WILL VARY
GREATLY FROM ONE INDIVIDUAL TO ANOTHER, LIGHT COMPLECTED PERS WHO
BECOME ALLERGIC ARE LIKELY TO BE IRRIT BY(ING 4)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:435F,224C
Vapor Pres:0.001 @20C
Vapor Density:0.6
Spec Gravity:1.01
Solubility in Water:MIXES COMPLETELY
Appearance and Odor:CLEAR, LOW VISCOUS LIQUID; MILDLY AMMONIACAL ODOR.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACID, OXIDIZING MATERIALS, HALOGENATED ORGANIC COMPOUNDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION WILL PRODUCE
NITROGEN OXIDES WHEN BURNED.
==================== Disposal Considerations ====================
Waste Disposal Methods:LANDFILL OR INCINERATE UNDER CONDITIONS WHICH
MEET FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
=======================================================
NIIN: 00-951-7157
Product ID: DERMASHIELD
Cage: BENCH
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: BENCH
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: SKIN PROTECTIVE COMPOUND,CHEMICAL BARRIER
Specification Number: NONE
Type/Grade/Class: NONE
Unit of Issue: BX
Quantitative Expression: 00000000006EA
UI Container Qty: 1
Type of Container: CAN, AEROSOL
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYES: MAY CAUSE MILD IRRITATION. SKIN: NO OUTER
SKIN IRRITATION KNOWN. INHAL: UNLIKELY ROUTE OF EXPOSURE, POSSIBLE IRRITATION
OF FOAM IS INHALED IN LUNGS. INGEST: UNLIKELY ROUTE OF EXPOSURE, IN GESTION
OF SMALL QTY IS NOT LIKELY TO BE TOXIC. CHRONIC: NONE CURRENTLY KNOWN.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: SKIN: NONIRRITANT. EYES: WASH WITH WATER FOR AT LEAST 15 MINUTES.
INGEST: IN CASE OF LARGE AMOUNTS, GIVE 2 GLASSES OF WATER AND INDUCE
VOMITING. INHAL: NO EMERGENCY CARE ANTICIPATED. REMOVE TO FRESH A IR. SUPPORT
BRTHG (GIVE O*2/ARTF RESP) (FP N).
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: FLUSHED W/LARGE QTY OF WATER. COLLECT WITH ABSORBENT
MATERIAL, TRANSFER TO CLOSED CONTAINER. INCINERATE OR LANDFILL ACCORDING TO
LOCAL, STATE AND FEDERAL REGULATIONS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DO NOT PUNCTURE OR INCINERATE CONTAINERS. GIVE EMPTY
LEADING OR FULL CONTAINERS TO A DISPOSAL SERVICE EQUIPPED TO SAFELY HANDLE
PRESURIZED CANS. INCINERATE OR LANDFILL ACCORDING TO LOCAL, STATE AND FE
DERAL REGS.
Handling And Storage Precautions: AVOID PUNCTURE CONTAINERS OR BOXES DURING
SHIPPING AND HANDLING. DO NOT STORE AT TEMPERATURES ABOVE 120F. KEEP AWAY
FROM CHILDREN.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NON-FLAMMABLE
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures: NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP(FP N).
KEEP CONTR COOL. USE EQUIP/SHIELDING AS REQD TO PROT PERS AGAINST BURST,
RUPTUR/VENT OF CONTRS.
Unusual Fire/Explosion Hazard: @ ELEVATED TEMPS (OVER 54C, 130F) CONTAINERS MAY
VENT, RUPTURE OR BURST. IF THIS OCCURS, SMALL AMOUNT OF FLAMMABLE VAPORS MAY
BE RELEASED.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE UNDER NORMAL USE. USE NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: NONE UNDER NORMAL USE.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: VP: 130PSI @ 130F.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: N1
B.P. Text: 212F,100C
Vapor Pres: SUPP DATA
Vapor Density: HVR/AIR
Spec Gravity: 0.94
Evaporation Rate & Reference: SLOWER (ETHYL ETHER=1)
Solubility in Water: YES
Appearance and Odor: A WHITE LOTION OR MOUSSE, A VERY PLEASANT ODOR
Percent Volatiles by Volume: 87(WT)
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE CURRENTLY KNOWN.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 94571
Product ID: DERMASHIELD
Review Date: 03/22/1994
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: BX
Container QTY: 1
Type Of Container: CAN, AEROSOL
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: DERMASHIELD
Cage: BENCH
Company Name: BENCHMARK ENTERPRISES INC
Street: 1905 SOUTH REDWOOD RD
Zipcode: 84104
Label Required IND: Y
Date Of Label Review: 04/20/1993
Status Code: C
Label Date: 04/20/1993
Origination Code: G
Signal Word: CAUTION
Health Hazard: None
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: DO NOT EXPOSE CONTAINERS TO ELEVATED TEMPERATURES (OVER
120F). CONTAINERS MAY VENT, RUPTURE OR BURST. ACUTE: EYES: MAY CAUSE MILD
IRRITATION. SKIN: NO OUTER SKIN IRRITATION KNOWN. INHAL: POSSIBLE IRRI TATION
OF FOAM IS INHALED IN LUNGS. INGEST: NOT LIKELY TO BE TOXIC. CHRONIC: NONE
LISTED BY MANUFACTURER.
=======================================================
| 0 |
eyes_protection_not_mandatory
|
===================== Product Identification =====================
Product ID:SPOTCHECK PENETRANT SKL-SP, 55 GALLON
CAGE:59042
CAGE:37676
CAGE:59042
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL OIL, WHITE (PETROLEUM)
CAS:8042-47-5
RTECS #:PY8047000
Fraction by Wt: 40-70%
OSHA PEL:5 MG/M3 (MFR)
ACGIH TLV:5 MG/M3 (MFR)
Ingred Name:PHTHALIC ACID, DIBUTYL ESTER; (1,2-BENZENEDICARBOXYLIC
ACID, DIBUTYL ESTER) (SARA 313) (CERCLA) LD50 (ORAL RAT): 8 G/KG
CAS:84-74-2
RTECS #:TI0875000
Fraction by Wt: 10-30%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE) (PROPELLANT)
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 30%
OSHA PEL:1000 PPM (MFR)
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 2.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: CAN IRRITATE BY REMOVING
NATURAL SKIN OILS ON LONG OR REPEATED EXPOSURES. EYES: MAY
IRRITATE. INHALATION: WHEN HEATED OR SPRAYED, VAPORS MAY CAUSE
DIZZINESS AND NAUSEA. INGESTION: NOT SIG NIFICANT IN SMALL
(MOUTHFULLS) AMOUNTS.CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE.
======================= First Aid Measures =======================
First Aid:SKIN: WASH OFF W/SOAP & WATER. USE SOOTHING LOTION. EYES:
RINSE CAREFULLY UNDER UPPER & LOWER EYELIDS USING PLENTY OF WATER
FOR AT LEAST 15 MIN. INHAL: REMOVE TO FRESH AIR IF DIZZY/NAUSEATED.
INGEST: DO NOT INDUCE VOMIT. ACCIDENTAL INGEST OF A SMALL MOUTHFUL
NOT EXPECTED TO CAUSE SIGNIFICANT HARM. IN ALL SEV CASES, CONT MD
CTR.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>100C
Lower Limits:1%
Upper Limits:6%
Extinguishing Media:CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. KEEP CONTRS COOL W/WATER SPRAY. DO NOT SPRAY WATER DIRECTLY ON
BURNING PROD. IT MAY FLOAT & SPREAD FIRE.
Unusual Fire/Explosion Hazard:AEROSOL CANS MAY BURST AT TEMPERATURES
OVER 130F (54C) AND SPRAY CONTENTS INTO A FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:MOP UP OR SWEEP UP WITH ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM HEAT SOURCE. AVOID EYE
CONTACT. AVOID REPEATED OR PROLONGED SKIN CONTACT. AVOID BREATHING
SPRAY MIST. DO NOT SPRAY AROUND ARCS/FLAMES.
Other Precautions:USE WHERE VENTILATION WILL CARRY SPRAY MIST AWAY FROM
OCCUPIED AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR WITH FILTER
IF SPRAYED IN ENCLOSED UNVENTILATED SPACE.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VP: AEROSOL: 60 PSI @ 75F (24C); BULK: <0.10 MM @ 70F (21C).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>455F,>235C
Vapor Pres:(SUP DAT)
Vapor Density:HVR/AIR
Spec Gravity:0.89
pH:NEUT
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:0
Appearance and Odor:DARK RED OILY LIQUID, WITH MILD OILY ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:SMOKE, SOOT, OXIDES OF CARBON AND
NITROGEN WHEN BURNING.
==================== Disposal Considerations ====================
Waste Disposal Methods:AS A NON-HAZARDOUS OILY WASTE, INCINERATE OR
SEND TO WASTE HANDLER WHO CAN BLEND IT INTO SECONDARY FUELS. EMPTY
AEROSOL CANS BEFORE DISPOSAL. DISPOSE OF IN ACCORDANCE W/LOCAL,
STATE & FEDERAL REGULATI ONS .
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:LINDE 29 SOLID STEEL WELDING WIRE/RODS
CAGE:GO651
CAGE:GO651
CAGE:55019
============= Composition/Information on Ingredients =============
Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS
(IARC CARC GROUP 3) - *96-4*
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: <0.50%
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/CUM
ACGIH TLV:3.5 MG/CUM
Ingred Name:MANGANESE *96-4*
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: <2.50%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM (DUST)
Ingred Name:SILICON * 96-4 *
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: <0.50%
ACGIH TLV:10 MG/CUM
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER *96-4*
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: <0.50%
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND)
CAS:7439-98-7
RTECS #:QA4680000
Fraction by Wt: <0.75%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:IRON *96-4*
CAS:7439-89-6
RTECS #:NO4565500
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES:
DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF THE
NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES:
RESPIRATORY PROBLEMS, IRON BUILDUP IN THE LUNGS, BONE ER OSION,
REDUCED PULMONARY FUNCTIONS & NERVOUS DISORDERS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:SHORT TERM EXPOSURE TO WELDING FUMES:
DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF THE
NOSE/THROAT/LUNGS/EYES. LONG TERM EXPOSURE TO WELDING FUMES:
RESPIRATORY PROBLEMS, IRON BUILD UP IN THE LUNGS, BONE E ROSION,
REDUCED PULMONARY FUNCTIONS & NERVOUS DISORDERS.
Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY/ALLERGIC
CONDITIONS.
======================= First Aid Measures =======================
First Aid:IF OVERCOME BY SMOKE/FUMES, REMOVE VICTIM TO FRESH AIR.
EMPLOY FIRST TECHNIQUES RECOMMENDED BY THE RED CROSS. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE
COMBUSTIBLE & FLAMMABLE PRODUCTS.
======================Handling and Storage ======================
Handling and Storage Precautions:MONITOR THE AIR TO ENSURE THE LEVELS
ARE < THE RECOMMENDED LIMITS. WEAR APPROPRIATE EQUIPMENT TO PREVENT
INJURY FROM RADIATION/SPARKS/ELECTRIC SHOCK.
Other Precautions:TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS &
INSULATE THEMSELVES FROM WORK & GROUND.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED
RESPIRATOR WHEN WELDING IN CONFINED SPACE, WHERE LOCAL
EXHAUST/VENTILATION DOESN'T KEEP EXPOSURE < TLV.
Ventilation:LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES < TLV IN WORKER'S
BREATHING ZONE & GENERAL AREA.
Other Protective Equipment:ARM PROTECTOR, APRONS, HATS, SHOULDER
PROTECTION, DARD SUBSTANTIAL CLOTHING.
Supplemental Safety and Health
PRODUCT IS NON-HAZARDOUS UNTIL USED AS IN WELDING PURPOSES. THE
COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING
WELDED, PROCESS, PROCEDURES, ELECTRODES USED, COATINGS, POSITION OF
WELDERS HEAD W/RESPECT TO THE PLUME & AS WELL AS THE PRESENCE OF
CONTAMINANTS IN THE ATMOSPHERE.
================== Physical/Chemical Properties ==================
Appearance and Odor:COPPER COATED/BARE SOLID STEEL WIRE/RODS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
(SEE SUPPLEMENTAL DATA)
Stability Condition to Avoid:(SEE SUPPLEMENTAL DATA)
Hazardous Decomposition Products:COMPLEX OXIDES OF IRON, MANGANESE,
SILICON, CHROMIUM, NICKEL, MOLYBDENUM, CALCIUM, MAGNESIUM,
TITANIUM, CO, CO2. (SUPP)
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE
CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:COMPOUND 1125A LB INTER
Kit Part:Y
Preparer's Name:D.C. MOLBERG
CAGE:60775
CAGE:60775
CAGE:5W425
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM OXIDE; (MAGNESIA)
CAS:1309-48-4
RTECS #:OM3850000
Fraction by Wt: 9.4%
OSHA PEL:10 MG/M3 RESPIRABLE
ACGIH TLV:10 MG/M3; FUME
Ingred Name:AMORPHOUS SILICA; (SILICON DIOXIDE, SILICA)
CAS:112945-52-5
RTECS #:VV7310000
Fraction by Wt: 4.3%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGEST:NO HAZARD KNOWN AT THIS TIME.
SKIN ABSORPTION:NO HAZARD KNOWN AT THIS TIME. INHALATION:IRRITATION
FROM FUMES FROM HOT MATERIAL. EYES:INGREDIENT CAUSES EYE
IRRITATION. CHRONIC: NONE KNOWN TO MAN UFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . SKIN:
FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYES: IN CASE OF
CONTACT, IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES. CALL MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN TO MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP MATERIAL USING SWEEPING COMPOUND AND
PACKAGE THE SOLID PRODUCT IN STEEL DRUMS WHICH ARE IN GOOD
CONDITION. THOROUGHLY CLEAN AREA WHERE SPILL OCCURRED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL LOCATION (60-80F) AWAY
FROM SUNLIGHT & ANY SOURCE OF HEAT, SPARKS OR FLAME. KEEP CONTAINER
TIGHTLY CLOSED WHEN NOT BEING USED.
Other Precautions:USE WITH ADEQUATE VENTILATION. AVOID PROLONGED OR
REPEATED BREATHING OF VAPORS. AVOID SKIN CONTACT. USE IN AN AREA
FREE FROM FLAME AND SPARKS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST IS PREFERRED, MECHANICAL EXHAUST ACCEPTABLE.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
KEY1;T6.HAZ DECOMP PROD:VAPOR, OXIDES OF NITROGEN/ WIDE VARIETY OF
INNOCOUS/TOX FUMES. HYDROGEN CHLORIDE MAY ALSO BE PRDCED. WASTE
DISP METH:CLASSIFIED AS A HAZ WASTE UNDER FED REGS IN EFFECT AT
================== Physical/Chemical Properties ==================
HCC:T6
Spec Gravity:1.32
Solubility in Water:0.0%
Appearance and Odor:AN AMBER SOLID WITH A CHARACTERISTIC ODOR.
Percent Volatiles by Volume:0.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CARBON DIOXIDE, WATER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:UNKNOWN DUE TO COMPLEX NATURE OF MATL.
FUMES FROM COMPLETE/INCOMPLETE COMBUST OF MATL MAY INCL CO2, CO,
WATER (SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W/FED, STATE & LOCAL REGS. BE
AWARE THAT STATE & LOCAL REQUIREMENTS MAY DIFFER WIDELY DEPENDING
ON LOCATION & IN MANY CASES MAY BE DIFFERENT FROM FED RULES. WHEN
INTENDING TO DISPOSE OF MATL, USER ADVISED PROD WOULD NOT BE
(SUPDAT)
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:FR-1072 BASE COMPONENT
Kit Part:Y
Preparer's Name:SAM ENGEL, SR
CAGE:DO271
CAGE:0HB93
CAGE:DO271
============= Composition/Information on Ingredients =============
Ingred Name:POLYSULFIDE POLYMER
CAS:68611-50-7
Fraction by Wt: 60-70%
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <3%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 20-30%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9192
Ingred Name:KAOLIN
CAS:1332-58-7
RTECS #:GF1670500
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9293
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: <1%
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:MODERATE IRRITATION TO EYES AND SKIN.
======================= First Aid Measures =======================
First Aid:SKIN: WASH AFFECTED AREA WITH SOAP AND WATER. EYES: FLUSH
IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES. CALL A
PHYSICIAN. INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING IF
NECESSARY.
===================== Fire Fighting Measures =====================
Flash Point:400F,204C
Extinguishing Media:CO2, WATER SPRAY, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
================== Accidental Release Measures ==================
MATERIAL. RESIDUE MAY BE REMOVED WITH CHLORINATED OR AROMATIC
SOLVENT.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AT 77 DEG F OR BELOW.
Other Precautions:MATERIAL IS RELATIVELY NON-HAZARDOUS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY REQUIRED
Ventilation:MECHANICAL VENTILATION
Other Protective Equipment:AFTER WASH-UP, APPLY PROTECTIVE HAND CREAM.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>300F,>149C
Decomp Temp:Decomp Text:>400F,>204C
Vapor Density:1
Spec Gravity:1.5
Viscosity:1 M CPS
Solubility in Water:INSOLUBLE
Appearance and Odor:HEAVY, WHITE PASTE; SLIGHT AROMATIC.
Percent Volatiles by Volume:5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:AVOID CONTACT WITH STRONG ACIDS OR BASES.
Hazardous Decomposition Products:COMBUSTION WILL PRODUCE CARBON
MONOXIDE AND CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:MATERIAL CONTAINS NO RAW MATERIALS WITH KNOWN
LEVELS OF TCLP CONSTITUENTS. INCINERATE OR DISPOSE OF IN APPROVED
LANDFILL.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ENAM ALKYD LSTRLESS LO VOC OD 34052 771402
Preparer's Name:W. A. ELLISON
CAGE:PRATT
CAGE:PRATT
CAGE:61196
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ISOAMYL KETONE
CAS:110-12-3
RTECS #:MP3850000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9293
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 10%
Other REC Limits:LFL 1.0/UFL 7.0
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: < 5%
Other REC Limits:LFL 1.0/UFL 6.7
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:NAPHTHA, LIGHT AROMATIC
CAS:64742-95-6
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:N-BUTYL ACETATE (SARA III)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 5%
Other REC Limits:LFL 1.7/UFL 7.6
OSHA PEL:150 PPM/200 STEL
ACGIH TLV:150 PPM/200STEL;9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TALC (CONTAINING NO ASBESTOS)
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 45%
Other REC Limits:NONE SPECIFIED
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST; 9192
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: < 1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 5%
Other REC Limits:LFL 2.0/UFL 10.0
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VOC 3.05 LB/GAL LESS WATER & NEGLIGIBLY PHOTOCHEMICALLY
REACTIVE MATERIALS 366 G/L LESS WATER
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
Ingred Name:VOC 5.33 LB/GAL SOLIDS 640 G/L SOLIDS
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SWALLOWING, INHALATION, SKIN
ABSORPTION, OR IF PRODUCT GETS INTO EYES COULD CAUSE SEVERE
IRRITATION REACTION. OTHER EFFECTS: CHEMICAL PNEUMONITIS, LUNG
DISEASE, DAMAGE TO LIVER, KIDNEYS & BLOOD, RESPI RATORY CONDITIONS,
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE & DEATH.
Explanation of Carcinogenicity:CRYSTALLINE SILICA MAY CAUSE LUNG
DISEASE AND IS LISTED AS A CARCINOGEN BY THE IARC.
Effects of Overexposure:NAUSEA, VOMITING, HEADACHES, DIZZINESS,
DEPRESSION, CONFUSION AND SEVERE IRRITATION IF SWALLOWED, INHALED,
ABSORBED THROUGH SKIN, OR IF PRODUCT GETS INTO EYES.
Medical Cond Aggravated by Exposure:CHEMICAL PNEUMONITIS, LUNG DISEASE,
RESPIRATORY CONDITIONS, DAMAGE TO LIVER, KIDNEYS & BLOOD, PERMANENT
BRAIN & NERVOUS SYSTEM DAMAGE & DEATH.
======================= First Aid Measures =======================
First Aid:SWALLOWING: DO NOT INDUCE VOMITING. CALL POISON CONTROL
CENTER IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR IMMEDIATELY. IF
BREATHING STOPPED, GIVE CPR & KEEP WARM & QUIET. EYE: FLUSH WITH
LARGE AMOUN TS OF WATER FOR 15 MINUTES LIFTING UPPER/LOWER LIDS
CONTINUOUSLY. SKIN: REMOVE CONTAMINATED CLOTHING & WASH AFFECTED
AREA WITH SOAP & WATER. GET MEDICAL ATTEN IMMEDIATELY FOR ANY OF
THESE CONDITIONS.
===================== Fire Fighting Measures =====================
Flash Point:24F/-4C
Lower Limits:SEE INGRED.
Upper Limits:SEE INGRED.
Extinguishing Media:USE CARBON DIOXIDE, ALCOHOL FOAM OR DRY CHEMICAL TO
EXTINGUISH FLAMMABLE LIQUID FIRES. USE POLYMER FOAM FOR LARGE
FIRES.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE BUT USED TO COOL
EXPOSED CONTAINERS TO PREVENT PRESURE BUILDUP & POSSIBLE
AUTO-IGNITE/EXPLOSION. WEAR FOG NOZZLES WHEN USING WATER.
Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMPOSITION PRODUCTS
MAY CAUSE HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.
OBTAIN MEDICAL ATTENTION.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR RESPIRATORS, APPROPRIATE BODY PROTECTION.
KEEP SPECTATORS AWAY, ELIMINATE ALL IGNITE SOURCES, CONTAIN SPILL
W/INERT MATERIAL, TRANSFER LIQ TO COV METAL CONTAINER FOR DISPOSAL.
USE NON-SPARK TOOLS ONLY. PREVENT CONTAMINATION OF
SEWERS/GROUNDWATER
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 95 DEGREES F.
STORE LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29CFR1910.106.
Other Precautions:DO NOT TAKE INTERNALLY. CLOSE CONTAINER AFTER USE.
EMPTY CONTAINERS SHOULD NOT BE WASHED OR REUSED FOR ANY PURPOSE AND
SHOULD BE GROUNDED & BONDED TO RECEIVING CONTAINER. AVOID PRESSURE
TO EMPTY CONTA INERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN WELL VENTILATED AREAS, RESPIRATORY PROTECTION
MAY NOT BE REQUIRED. IN RESTRICTED AREAS USE A NIOSH APPROVED
CHEMICAL CARTRIDGE RESPIRATOR. FOR SPRAYING USE MECH PREFILTER. IN
CONFINED AREAS USE NIO SH/MSHA APPR AIR SUPPLIED RESPIRATOR.
Ventilation:DILUTE & LOCAL EXHAUST RECOMMENDED TO CONTROL CONCENTRATE
OF HAZARDOUS INGREDIENTS.
Work Hygienic Practices:EYEWASH FACILITY, SAFETY SHOWER. DO NOT TAKE
INTERNALLY. CLOSE CONTAINER AFTER EACH USE & DO NOT BREATHE SANDING
DUST.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:139 TO 348F
Vapor Density:> THAN AIR
Spec Gravity:1.4
Evaporation Rate & Reference:SLOWER THAN ETHER.
Percent Volatiles by Volume:42
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALINE OR OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT SPARKS AND
FLAME.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN I/A/W FEDERAL, STATE & LOCAL LAWS.
INCINERATE ONLY IN EPA PERMITTED FACILITY. DO NOT INCINERATE CLOSED
CONTAINERS. OBSERVE PRECAUTIONS FOR DISP OF FLAMMABLE MATERIALS.
CONTAMINATED ABSOR BENT MAY BE DISPOSED IN A HAZARD WASTE LANDFILL.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ENAMEL, ALKYD, LUSTERLESS LO VOC OD 34127
Preparer's Name:W. A. ELLISON
CAGE:61196
CAGE:61196
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ISOAMYL KETONE
CAS:110-12-3
RTECS #:MP3850000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9293
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SOLVENT NAPTHA, LIGHT AROMATIC (SOLVENT)
CAS:64742-95-6
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:N-BUTYL ACETATE (SARA III)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:150 PPM/200 STEL
ACGIH TLV:150 PPM/200STEL;9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:MINERAL SPIRITS (VAPOR PRESSURE 2 MM HG @ 20 C) (LFL 1.0;
UFL 7.0) (SOLVENT)
CAS:64475-85-0
RTECS #:PY8240000
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM; 525 MG/M3
ACGIH TLV:100 PPM; 525 MG/M3
Ingred Name:TALC (CONTAINING NO ASBESTOS)
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 35%
Other REC Limits:NONE SPECIFIED
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST; 9192
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VOC 2.99 LB/GAL LESS WATER & NPRS* 359 G/L LESS WATER
CALCULATED (*NEGLIGIBLY PHOTOCHEMICALLY REACTIVE MATERIALS)
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
Ingred Name:VOC 5.22 LB/GAL SOLIDS 626 G/L SOLIDS CALCULATED
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SWALLOWING: GASTROINTESTINAL
IRRITATION. ASPIRATION OF MATERIAL INTO LUNG MAY CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL. INHALATION: NOSE OR THROAT
IRRITATION. ACUTE CENTRAL NERVOUS SYSTEM DEPRESS ION. EYE/SKIN:
SEVERE IRRITATION. CORNEAL DAMAGE. PNEUMOCONIOSIS. LIVER, KIDNEY,
BLOOD INJURY. PERIPHERAL NEUROPATHY.
Explanation of Carcinogenicity:IARC CONSIDERS CRYSTALLINE SILICA TO
HAVE LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS. (1ARC GROUP
2A).
Effects of Overexposure:SWALLOW: NAUSEA, VOMITING. INHALE: HEADACHES,
DIZZINESS, NAUSEA & CONFUSION. SKIN: LIQUID MATERIAL MAY BE
ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. REPORTS ASSOCIATE
PROLONGED/REPEATED OVEREXPOSURE TOSOLVENTS W/PERMANENT BRAIN &
NERVOUS SYSTEM DAMAGE. DELIBERATELY CONCENTRATING & INHALING COULD
BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:PREXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.
======================= First Aid Measures =======================
First Aid:SWALLOWING: DO NOT INDUCE VOMITING. CALL POISON CONTROL,
EMERGENCY ROOM OR PHYSICIAN IMMED. INHALE: REMOVE TO FRESH AIR
IMMED. IF BREATHING HAS STOPPED, GIVE CPR. KEEP WARM & QUIET. GET
IMMED MEDICAL CARE. EYE: FLUSH W/LARGE AMOUNTS WATER.LIFT UPPER &
LOWER LIDS OCCASIONALLY-15 MIN. GET MEDICAL ATTN. SKIN: REMOVE
CONTAM CLOTHING. WASH AFFECTED AREA W/SOAP & WATER. PERSISTANT
IRRIT/MEDICAL AID.
===================== Fire Fighting Measures =====================
Flash Point:24.0F,-4.4C
Autoignition Temp:Autoignition Temp Text:572 F
Lower Limits:1.0
Upper Limits:10.0
Extinguishing Media:NFPA CLASS B FIRE EXT. (CO2, ALL PURPOSE DRY
CHEMICAL OR ALCOHOL FOAM.) POLYMER FOAM IS PREFERRED FOR LARGE
FIRES.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, USE TO COOL
CONTAINERS (FOG NOZZLES PREFERABLE) TO PREVENT PRESSURE BUILD-UP &
AUTO-IGNITE OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE
TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY
NOT BE IMMEDIATELY APPARENT. GET MEDICAL ATTENTION.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR APPROPRIATE PROTECTION. KEEP SPECTATORS
AWAY. REMOVE IGNITE SOURCES. DIKE, CONTAIN & REMOVE SPILL W/INERT
MATERIAL. USE COVERED METAL CONTAINERS FOR RECOVERY/DISPOSAL. USE
NON-SPARKING TOOLS. PRE VENT CONTAM OF SEWERS, STREAMS, AND
GROUNDWATER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 100 F (38 C). STORE
LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29CFR1910.106. DO NOT TAKE
INTERNALLY. CLOSE CONTAINER AFTER EACH USE.
Other Precautions:DO NOT BREATHE SANDING DUST. DO NOT WASH OR RE-USE
EMPTY CONTAINERS FOR ANY PURPOSE. GROUND & BOND CONTAINERS TO THE
RECEIVING CONTAINER. DO NOT WELD, BRAZE OR CUT ON EMPTY CONTAINER.
NEVER EMPTY W/PR ESSURE. DRUM IS NOT A PRESSURE VESSEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESTRICTED AREA: NIOSH APPR'D CHEMICAL CARTRIDGE
RESPIRATOR. SPRAYING: MECHANICAL PREFILTER MAY BE REQUIRED.
CONFINED AREAS: NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR.
EXCEEDED TLV AREA:NIOSH/MSHA A PPR'D RESPIRATOR W/RIGHT PROTECT
FACTOR.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENTILATION IN SUFFICIENT
VOLUME & PATTERN TO KEEP CONCENTRATIONS BELOW EXPOSURE LIMITS.
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER.
Supplemental Safety and Health
FLAMMABLE. THIS PRODUCT, IF DISCARDED DIRECTLY, WOULD BE CLASSIFIED A
HAZARDOUS WASTE BASED ON ITS IGNITABILITY CHARACTERISTIC.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:139 TO 399F
Melt/Freeze Pt:M.P/F.P Text:-50F,-46C
Decomp Temp:Decomp Text:1832F,1000C
Vapor Pres:70 @ 68 F
Vapor Density:> AIR
Spec Gravity:1.4
pH:4-7 *
Viscosity:67-77 KU
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT IN WATER
Appearance and Odor:LIQUID, SOLVENT ODOR.
Percent Volatiles by Volume:42
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT (>100 F (38 C)) AND
SOURCES OF IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL LAWS & REGULATIONS. INCINERATE ONLY IN EPA FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.USE PRECAUTIONS FOR DISPOSAL OF
FLAMMABLE MATERIALS-D001. USE HAZARDOUS WASTE LANDFILL FOR USED
ABSORBENTS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:LATENT PRINT POWDER, INDESTRUCTIBLE WHITE, BPP1916
CAGE:94514
CAGE:94514
============= Composition/Information on Ingredients =============
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <45%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:ZINC STEARATE
CAS:557-05-1
RTECS #:ZH5200000
Fraction by Wt: 30%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:N/K
Ingred Name:ARABIC GUM; (GUM ARABIC)
CAS:9000-01-5
RTECS #:CE5945000
Fraction by Wt: >10%
OSHA PEL:N/K
ACGIH TLV:10 MG/M3 (MFR)
Ingred Name:LYCOPODIUM
CAS:8023-70-9
Fraction by Wt: >10%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED EXPOSURE MAY CAUSE SLIGHT
SKIN IRRITATION AND MILD TO MODERATE EYE AND MUCOUS MEMBRANE
IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL
A PHYSICIAN. EYES:FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT
LEAST 15 MINU TES. CALL MD. SKIN:CMPD NOT LIKELY TO BE HAZ, BUT
CLEANSING SKIN AFTER USE IS ADVISABLE. INGEST:NO SPECIFIC
INTERVENTION IS INDICATED AS CMPD IS NOT LIKELY TO BE HAZ. IF SYMPS
OCCUR, CONSULT MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, CO*2.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . NONE.
Unusual Fire/Explosion Hazard:ALL DUSTS AND POWDERS CAN POSE DUST
EXPLOSION HAZARD IF DISPERSED IN AIR. AVOID IGNITION SOURCES.
================== Accidental Release Measures ==================
Spill Release Procedures:DRY SWEEP SPILL INTO CONTAINER. DISPOSE OF IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP IN DRY CONTAINER. AVOID CREATING
DUST.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BREATHING DUST. USE NIOSH APPROVED DUST
MASK.
Ventilation:SUFFICIENT TO KEEP AIR CONTAMINATION BELOW EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Solubility in Water:PARTIALLY
Appearance and Odor:FINE WHITE POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, STRONG ALKALIES, STRONG BASES, STRONG OXIDIZERS.
Stability Condition to Avoid:EXPOSURE TO WATER.
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:HYSOL PC16M, PART A
Kit Part:Y
Preparer's Name:JAMES P HORNBURG
CAGE:04347
CAGE:04347
CAGE:7B953
============= Composition/Information on Ingredients =============
Ingred Name:EPOXY RESIN
CAS:25068-38-6
RTECS #:KC2100000
Fraction by Wt: 60-100%
Other REC Limits:NONE RECOMMENDED
Ingred Name:N-BUTYL GLYCIDYL ETHER (BGE)
CAS:2426-08-6
RTECS #:TX4200000
Fraction by Wt: 6.612%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:50 PPM
ACGIH TLV:25 PPM; 9394
===================== Hazards Identification =====================
LD50 LC50 Mixture:PERMISSIBLE EXPOSURE LEVEL - N.E.
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT-PRODUCT MAY BE MODERATELY
IRRITATING TO THE EYES. CONTACT WITH PRODUCT AT ELEVATED
TEMPERATURES CAN RESULT IN THERMAL BURNS. SKIN CONTACT-PRODUCT MAY
BE MODERATELY IRRITATING TO THE SKIN. INHALATION-PRODUCT IS NOT
LIKELY TO BE AN INHALATION HAZARD. INGESTION-PRODUCT PRESUMED TO
HAVE A LOW ORDER OF TOXICITY.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:IRRITATION AS NOTED. SKIN SENSITIZATION
(ALLERGY) MAY BE EVIDENCED BY RASHES, ESPECIALLY HIVES.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND EYE DISORDERS
MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT. PREEXISTING SKIN OR
LUNG ALERGIES MAY INCREASE THE CHANCE OF DEVELOPING INCREASED
ALLERGY SYMPTOMS FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:EYE-FLUSH WITH WATER FOR 15 MIN. GET MEDICAL ATTENTION. IF
CONTACT WITH HOT PRODUCT OCCURS, IMMEDIATELY FLUSH WITH COOL WATER
FOR 15 MIN. GET MEDICAL ATTENTION. SKIN REMOVE CONTAMINATED CLOTHES
& WIPE OFF EXCESS. FLUSH WITH WATER. FOLLOW BY WASHING WITH SOAP &
WATER. GET MEDICAL ATTENTION. INHALATION-REMOVE TO FRESH AIR &
PROVIDE OXYGEN. GET MEDICAL ATTENTION. INGEST-DO NOT INDUCE
VOMITING.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:155F,68C
Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRES;
FOAM (ALCOHOL, POLYMER OR ORDINARY) FOR LARGE FIRES.
Fire Fighting Procedures:NONE - AVOID BREATHING SMOKE.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEANUP AND DISPOSAL SHOULD BE IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A DRY AREA, AVOID SKIN
CONTACT.
Other Precautions:NONE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:U.S BUREAU OF MINES APPROVED CANNISTER MASK, AIR
HOSE MASKS.
Ventilation:LOCAL EXHAUST OR MECHANICAL, GENERAL DILUTION TYPE.
Other Protective Equipment:WEAR COVERALLS OR APRON TO AVOID CLOTHING
AND SKIN CONTAMINATION.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NOTE TO PHYSICIAN: *IN GENERAL, EMESIS INDUCTION IS UNNECESSARY IN HIGH
VESCOSITY, LOW VOLATILITY PRODUCTS, E.G., NEAT EPOXY RESINS.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:N.A.
Vapor Pres:N.A.
Vapor Density:N.A.
Spec Gravity:1.08
Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1)
Solubility in Water:0
Appearance and Odor:AMBER, MEDIUM VISCOSITY LIQUID, VERY SLIGHT
CHARACTERISTIC ODOR.
Percent Volatiles by Volume:8
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTAMINATION WITH ALKALIES, ACIDS, AMINES AND WATER.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON MONOXIDE, ALDEHYDES, ACIDS AND
OTHER ORGANIC COMPOUNDS.
Conditions to Avoid Polymerization:EXOTHERMIC CURE MAY OCCUR WHEN LARGE
QUANTITIES ARE MIXED WITH CURING AGENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:X17GS5565 SODIUM SACCHARIN GRANULAR
CAGE:PMCSP
CAGE:0T805
CAGE:PMCSP
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM SACCHARINE, SODIUM SACCHARIN (ANIMAL CARCINOGEN BY
IARC; SUSPECTED CARCINOGEN BY NTP; IARC - GROUP 2B) *98-2*
CAS:128-44-9
RTECS #:DE4550000
Fraction by Wt: 85-86%
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 14-15%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:IRRITATION TO THE EYES, SKIN &
RESPIRATORY TRACT.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION.
======================= First Aid Measures =======================
First Aid:SKIN/EYES: WASH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP & RECLAIM/PLACE IN A COVERED WASTE
DISPOSAL CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID EXCESSIVE HEAT ON STORAGE TO
PREVENT CAKING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:3M 9900, AMER. OPTICAL R 5030, WILLSON 1211,
NORTON 7506/EQUIVALENT NIOSH TC-21C.
Ventilation:LOCAL EXAUST RECOMMENDED FOR DUST CONTROL.
Other Protective Equipment:NONE
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:>1
Solubility in Water:46%/WT
Appearance and Odor:WHITE NON DUSTING GRANULES
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Stability Condition to Avoid:EXCESSIVE HEAT.
Hazardous Decomposition Products:CO, NITROGEN OXIDES, SULFUR OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T INCINERATE/HEAT IN A CLOSED CONTAINER.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:FREON 11A & FREON 11C
Preparer's Name:K P BROWN
CAGE:0ERJ7
CAGE:0ERJ7
CAGE:18873
============= Composition/Information on Ingredients =============
Ingred Name:SUPP DATA:EFTS OF EXCLUSION OF O*2 W/GROSSLY EXCESSIVE
EXPOS. CHLOROCARBON/CHLOROFLUOROCARBON (CFC) MATLS (SEE ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3:HAVE PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN
LAB ANIMALS & COULD HAVE A SIMILAR EFT IN HUMANS. (SEE ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:ADRENOMIMETICS (E.G.,EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS (SEE ING
6)
RTECS #:9999999ZZ
Ingred Name:ING 5:ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS OR
CFC'S .
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:IN SITUATIONS OF EMERGENCY LIFE SUPPORT.
RTECS #:9999999ZZ
Ingred Name:VENT:SHOULD BE USED IN LOW PLACES. USE EXPLOSION- PROOF
EQUIPMENT.
RTECS #:9999999ZZ
Ingred Name:TRICHLOROFLUOROMETHANE (CFC-11) (SARA III)
CAS:75-69-4
RTECS #:PB6125000
Fraction by Wt: SEE ING
OSHA PEL:1000 PPM
ACGIH TLV:C, 1000 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ozone Depleting Chemical:1
Ingred Name:ALPHA-METHYL STYRENE
CAS:98-83-9
RTECS #:WL5075300
OSHA PEL:50 PPM/100 STEL
ACGIH TLV:50 PPM/100 STEL;9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT)>4000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL OF HIGH CONCS OF VAP IS HARMFUL
& MAY CAUSE HEART IRREGS, UNCON/DEATH. INTENTIONAL MISUSE CAN BE
FATAL. VAP REDUCES O2 AVAIL FOR BRTHG & IS HEAVIER THAN AIR. CMPD
IS NOT SKIN IRRIT, MILD EYE IRR IT & UNTESTED FOR ANIMAL SENSIT.
TOX EFTS DESCRIBED IN ANIMALS FROM EXPOS BY INHAL INCLUDE CNS (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:EFTS & ANESTHETIC EFTS. CHGS IN LUNGS,
LIVER, BRAIN & SPLEEN WERE OBSERVED IN RATS RPTD EXPOSED BY INHAL
TO CONCS OF 12000PPM/GREATER. HUMAN HLTH EFTS OF OVEREXPOS:EYE:MAY
INCLUDE IRRIT W/DIS COMFORT, TEARING/BLURRING OF VISION. SKIN:CNTCT
W/LIQ MAY CAUSE DRYING W/RPTD CNTCT RESULTING IN MILD IRRIT (SUPP
DATA)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING DISEASES
OF THE CENTRAL NERVOUS OR CARDIOVASCULAR SYSTEM MAY HAVE INCREASED
SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURES.
======================= First Aid Measures =======================
First Aid:INHAL:IMMED REMOVE TO FRESH AIR. KEEP CALM. IF NOT BRTHG,
GIVE ARTF RESP. IF BRTHG DFCLT, GIVE O2.CALL MD. SKIN:FLUSH
W/WATER. TREAT FOR FROSTBITE IF NEC. EYE:IMMED FLUSH W/PLENTY OF
WATER FOR AT LEAS T 15 MIN.CALL MD. INGEST:NOT CONSIDEREDPOTNTL RTE
OF EXPOS. NOTE TO MD:BECAUSE OF POSS DISTURB OF CARDIAC RHYTHM,
CATECHOLAMINE DRUGS,SUCH AS EPINEPHRINE,SHOULD BE USED W/SPECIAL
CAUTION (SEE ING 7)
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING
FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE CONDITIONS.
DECOMPOSITION PRODUCTS MAY INCLUDE CHLORIDES, FLUORIDES AND
PHOSGENE .
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA. DO NOT FLUSH INTO SEWERS. DIKE
SPILL. COLLECT ON ABSORB MATL & TRANSFER TO STEEL DRUMS FOR
RECOVERY OR DISPOSAL. COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS
ON REPORTING RELEASES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLEAN, DRY AREA. DO NOT HEAT
ABOVE 125F.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES AND/OR
PHOSGENE (FP N).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS, NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
NIOSH/MSHA APPROVED SCBA IS REQUIRED IF LARGE RELEASE OCCURS.
Ventilation:NORMAL VENT FOR STD MFG PROCEDURES GEN ADEQ. LOCAL EXHAUST
SHOULD BE USED WHEN LG AMTS RELEASED. MECH VENT (SEE ING 8)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID:CATALYSTS SUCH AS ALCL3 & FECL3. EFTS OF
OVEREXP:W/DISCOMFORT/RASH. INHAL:MAY CAUSE TEMPORARY NERVOUS SYS
DEPRESS W/ANESTHETIC EFTS SUCH AS DIZZ, HDCH, CONFUSION, INCOORD, &
LOSS OF CON SCIOUS; TEMPORARY ALTERATION OF HEART'SELEC ACTIVITY
W/IRREG PULSE, PALPITATIONS/INADEQ CIRCULATION, OR (SEE ING 3)
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:75.0F,23.9C
Vapor Pres:792 @ 77F
Vapor Density:4.9
pH:NEUT
Evaporation Rate & Reference:0.1 (CCL4 = 1).
Solubility in Water:0.1% BY WT @ 77F.
Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHT ETHEREAL ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, POWDERED AL, ZN, BE, ETC. AVOID CNTCT
W/ACIDS, BASES, OXIDIZING AGENTS & (SUPP DATA)
Stability Condition to Avoid:OPEN FLAMES & HIGH TEMPERATURES.
Hazardous Decomposition Products:HIGH TEMPS CAN FORM HYDROCHLORIC &
HYDROFLUORIC ACIDS, POSS CARBONYL HALIDES, CHLORIDES, FLUORIDES AND
PHOSGENE .
==================== Disposal Considerations ====================
Waste Disposal Methods:EPA HAZARDOUS WASTE NO. U121; F001; F002. COMPLY
W/FEDERAL, STATE & LOCAL REGULATIONS. RECLAIM BY DISTILLATION OR
REMOVE TO PERMITTED WASTE DISPOSAL FACILITY.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:LITHIUM MOLY EP 2 (MC 2127A)
CAGE:1CMP3
CAGE:1CMP3
Contract Num:SP0450-99-M-NF76
CAGE:0PGK2
============= Composition/Information on Ingredients =============
Ingred Name:HYDROTREATED HEAVY NAPHTHENIC DISTILLATE, PETROLEUM (INGRED
#1 + INGRED #2 = 70-90%)
CAS:64742-52-5
RTECS #:PY8035000
Minumum % Wt:70.
Maxumum % Wt:90.
Other REC Limits:NONE SPECIFIED
Ingred Name:DISTILLATES (PETROLEUM), SOLVENT-REFINED LIGHT NAPHTHENIC
(INGREDIENT #1 + INGRED #2 = 70 - 90%)
CAS:64741-97-5
RTECS #:PY8041000
Minumum % Wt:70.
Maxumum % Wt:90.
OSHA PEL:5 MG/M3 OIL MIST
ACGIH TLV:5 MG/M3 OIL MIST
Ingred Name:MOLYBDENUM DISULFIDE
CAS:1317-33-5
RTECS #:QA4697000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:10 MG/M3 AS MO
ACGIH TLV:10 MG/M3 AS MO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYES:IRRITATION. SKIN:PROLONGED
OR REPEATED CONTACT MAY CAUSE IRRITATION. INHALATION/INGESTION:
UNLIKELY UNDER NORMAL USE.CHRONIC-NOT GIVEN.
Effects of Overexposure:EYES AND SKIN IRRITATION.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE PRE-EXISTING SKIN AND
EYE DISORDERS.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. INHALATION:
UNLIKELY AT AMBIENT TEMPERATURE. IF OVERCOME BY VAPORS FROM HOT
PRODUCT, IMMEDIATELY MOVE TO FRESH AIR. EYES:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES. SKIN:WASH AFFECTED AREA WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING. INGESTION:DO NOT INDUCE VOMITING.
OBTAIN MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=232.2C, 450.F
LOWEST OIL
Lower Limits:0.9
Upper Limits:7.0
Extinguishing Media:USE WATER SPRAY/FOG, CARBON DIOXIDE, FOAM, DRY
CHEMICAL, EARTH OR SAND. DO NOT USE A SOLID STREAM OF WATER, IT MAY
CAUSE FROTHING.
Fire Fighting Procedures:TREAT AS PETROLEUM FIRE .USE POSITIVE PRESSURE
NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS & FULL PROTECTIVE
CLOTHING. COOL CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:PRESSURE WILL INCREASE IN OVERHEATED
CLOSED CONTAINERS.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ANY SOURCES OF IGNITION. WEAR
APPROPRIATE RESPIRATORY PROTECTION AND PROTECTIVE CLOTHING. CONTAIN
SPILL. SCOOP UP AS MUCH AS POSSIBLE. COVER REMAINDER WITH AN
ABSORBENT AND PLACE IN NON-LEANINGCONTAINERS FOR DISPOSAL.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE IN A COOL, DRY PLACE
AWAY FROM FLAMES AND EXTREME HEAT. KEEP CONTAINER CLOSED.
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. WASH HANDS BEFORE
EATING OR DRINKING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. AIR SUPPLIED BREATHING
EQUIPMENT IF OIL MIST IS GENERATED.
Ventilation:VENTILATE AS NEEDED TO COMPLY WITH EXPOSURE LIMIT.
Other Protective Equipment:EYE WASH STATION.LONG SLEEVE CLOTHING TO
MINIMIZE SKIN CONTACT.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:V6
Melt/Freeze Pt:=185.C, 365.F
Vapor Pres:<1
Vapor Density:>5
Spec Gravity:0.9 @60F
Evaporation Rate & Reference:<0.01 (BU ACETATE =1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BALCK GREASE, MILD BLAND PETROLEUM ODOR
Percent Volatiles by Volume:<0.01
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS LIQUID CHLORINE, CONCENTRATED OXYGEN,
SODIUM HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON MONOXIDE, DIOXIDE AND OXIDES OF
SULFUR
==================== Disposal Considerations ====================
Waste Disposal Methods:SPILLED MATERIAL, UNUSED CONTENTS AND EMPTY
CONTAINERS MUST BE DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:SEC 302 EXTREMELY HAZ SUBSTANCES= NONE; SEC
311/312 HAZ CATEGORIES = NONE; SEC 313 TOXIC CHEMICALS = CONTAINS
LESS THAN 1% ZINC COMPOUNDS.
Federal Regulatory Information:TSCA INVENTORY: NONE LISTED; CERCLA RQ =
NONE
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:METHANOL, 9263
Preparer's Name:QUALITY ASSURANCE DEPT
CAGE:70829
CAGE:70829
============= Composition/Information on Ingredients =============
Ingred Name:METHANOL; (METHYL ALCOHOL)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 90-100%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT)5628 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL:HARMFUL & MAY BE FATAL,
HEADACHE, NAUSEA, VOMITING, DIZZINESS, NARCOSIS, RESPIRATORY
FAILURE, LOW BLOOD PRESSURE, CENTRAL NERVOUS SYSTEM DEPRESSION.
SKIN:IRRITATION, PROLONGED CONTACT MAY CAUSE DERMATITIS.
EYE:IRRITATION, MAY CAUSE TEMPORARY CORNEAL DAMAGE. INGEST:HARMFUL
& MAY BE FATAL, (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:BLINDNESS, HEADACHE, NAUSEA, VOMITING,
DIZZINESS, GASTROINTESTINAL IRRITATION, CENTRAL NERVOUS SYSTEM
DEPRESSION, HEARING LOSS. CHRONIC: KIDNEY & LIVER DAMAGE. TARGET
ORGANS:EYES, SKIN, CENTR AL NERVOUS SYSTEM, GI TRACT, RESPIRATORY
SYSTEM, LUNGS.
Medical Cond Aggravated by Exposure:EYE DISORDERS, SKIN DISORDERS,
LIVER OR KIDNEY DISORDERS.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD. IF CONSCIOUS, GIVE LG AMTS OF WATER. INDUCE
VOMITING. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP.
IF BRTHG DFCLT, GIVE O*2. SKIN:IMMED FLUSH W/PLENTY OF WATER FOR AT
LEAST 15 MIN WHILE REMOVING CONTAMD CLTHG & SHOES. WASH CLTHG
BEFORE RE-USE. EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15
MIN.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:54.0F,12.2C
Lower Limits:6%
Upper Limits:36%
Extinguishing Media:USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON DIOXIDE.
(WATER MAY BE INEFFECTIVE.)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. MOVE CNTNRS FROM FIRE AREA IF CAN BE DONE W/O RISK. USE WATER TO
KEEP FIRE-EXPOSED CNTNRS COOL.
Unusual Fire/Explosion Hazard:VAPS MAY FLOW ALONG SURFS TO DISTANT
IGNIT SOURCES & FLASH BACK. CLOSED CNTNRS EXPOSED TO HEAT MAY
EXPLODE. CNTCT W/STRONG OXIDIZERS MAY CAUSE FIRE. (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
SHUT OFF IGNIT SOURCES; NO FLARES, SMOKING/FLAMES IN AREA. STOP
LEAK IF CAN DO SO W/O RISK. USE WATER SPRAY TO REDUCE VAPS. TAKE UP
W/SAND/OTHER NON-COMB UST ABSORB MATL & PLACE INTO CNTNR FOR (SUPP
DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN COOL, DRY, WELL-VENTILATED, FLAMMABLE LIQUID STORAGE AREA.
Other Precautions:BOND & GROUND CNTNRS WHEN TRANSFERRING LIQ. FLAMM.
CANNOT BE MADE NON-POISONOUS. KEEP AWAY FROM HEAT, SPARKS, FLAME.
DO NOT GET IN EYES, ON SKIN/CLTHG. AVOID BRTHG VAP. USE W/ADEQ
VENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS ABOVE 200 PPM, A
NIOSH/MSHA APPROVED SCBA IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Other Protective Equipment:UNIFORM AND PROTECTIVE SUIT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ:BURNS W/CLEAR, ALMOST INVISIBLE FLAME. SPILL PROC:LATER
DISPOSAL. FLUSH AREA W/WATER. J.T. BAKER SOLUSORB(R) SOLVENT
ADSORBENT IS RECOMMENDED FOR SPILLS OF THIS PRODUCT.
================== Physical/Chemical Properties ==================
HCC:F5
Boiling Pt:B.P. Text:149F,65C
Melt/Freeze Pt:M.P/F.P Text:-144F,-98C
Vapor Pres:96 @ 20C
Vapor Density:1.11
Spec Gravity:0.79
Evaporation Rate & Reference:4.6 (BUTYL ACETATE = 1)
Solubility in Water:COMPLETE (100%)
Appearance and Odor:CLEAR, COLORLESS LIQUID, PUNGENT ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, ZINC, ALUMINUM, MAGNESIUM.
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CO, CO*2, FORMALDEHYDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE, AND
LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZ WASTE #U154.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:TIGTECTIC 1851
CAGE:72271
CAGE:72271
============= Composition/Information on Ingredients =============
Ingred Name:ING 8: CLEANSING & DEGREASING ACTIVITIES). WHEN ELECTRODE
IS CONSUMED,FUME & GAS DECOMP PRODS GEN ARE DIFFERENT (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: IN PERCENT & FORM FROM INGS LISTED.DECOMP PRODS OF
NORM OPER INCL THOSE ORIGINATING FROM VOLATILIZATION, (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10: RXN/OXIDATION OF MATLS SHOWN IN ING SEC,PLUS THOSE
FROM BASE METAL & COATING, ETC., AS NOTED.REASONABLY (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:EXPECTED CONSTITUENTS OF FUME WOULD INCL:FLUORIDES,
COMPLEX OXIDES OF IRON,MANGANESE, SILICON, CHROMIUM, (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: NICKEL, MOLYBDENUM, COPPER,& OTHER METALS LISTED IN
ING SEC. GASEOUS RXN PRODS MAY INCL CARBON MONOXIDE (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13: AND CARBON DIOXIDE. OZONE AND NITROGEN OXIDES MAY
BE FORMED BY RADIATION FROM ARC.
RTECS #:9999999ZZ
Ingred Name:COPPER (SARA III)
CAS:7440-50-8
RTECS #:GL5325000
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2MG/M3 FUME;1 DUST
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
OSHA PEL:15 MG/M3 DUST;5 FUME
ACGIH TLV:10 MG/M3 DUST;5 FUME
Ingred Name:SUPP DATA:NEC, TO SHIELD OTHERS.AS RULE, START W/SHADE THAT
IS TOO DARK TO SEE WELD ZONE.THEN GO TO NEXT LIGHTER (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3: SHADE WHICH GIVES SUFFICIENT VIEW OF WELD ZONE.
RTECS #:9999999ZZ
Ingred Name:HAZ DECOMP PRODS: WELDED, PROCESS, PROD,& ELECTRODES
USED.OTHER CNDTNS WHICH ALSO INFLUENCE COMPOSITION & QTY OF (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: FUMES & GASES TO WHICH WORKERS MAY BE EXPOS INCL:
COATINGS ON METAL BEING WELDED (SUCH AS PAINT, PLATING/ (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: GALVANIZING), NUMBER OF WELDERS & VOL OF WORK AREA,
QTY & AMT OF VENT,POSITION OF WELDER'S HEAD W/RESPECT (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: TO FUME PLUME, AS WELL AS PRESENCE OF CONTAM IN
ATMOSPHERE (SUCH AS CHLORINATED HYDROCARBON VAPS FROM (ING 9)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: OVEREXPOSURE TO WELDING FUMES
MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA, OR DRYNESS OR
IRRITATION OF NOSE, THROAT OR EYES. COPPER: METAL FUMES FEVER CAN
BE CAUSED BY FRESH COPPER OXIDE FUME. CHRONIC: MAY LEAD TO
SIDEROSIS (IRON DEPOSITS IN LUNGS) AND MAY AFFECT PULMONARY
FUNCTIONS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: COPPER: NO ADVERSE LONG TERM EFFFECTS
DUE TO COPPER AND COPPER OXIDE HAVE BEEN REPORTED IN LITERATURE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:REMOVE TO WELL VENTILATED AREA. CALL FOR MEDICAL AID. EMPLOY
FIRST-AID TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS. INHALATION:
REMOVE FROM EXPOSURE. SUPPORT BREATHING (GIVE ARTIFICIAL
RESPIRATION/OX YGEN) . INGESTION: CALL MD IMMEDIATELY . SKIN: FLUSH
WITH COPIOUS AMOUNTS OF WATER . EYE: FLUSH WITH WATER FOR AT LEAST
15 MINUTES .
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WELDING ARC AND SPARKS AND BRAZING FLAMES
CAN IGNITE COMBUSTIBLES AND FLAMMABLES. REFER TO ANSI Z49.1 FOR
FIRE PREVENTION DURING USE OF WELDING AND ALLIED PROC.
================== Accidental Release Measures ==================
Spill Release Procedures:NOT APPLICABLE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRABLE FUME
RESPIRATORY OR AIR SUPPLIED RESPIRATOR WHEN WORKING IN CONFINED
SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE
BELOW RECOMMENDED EXPOSURE LI MIT.
Ventilation:USE ENOUGH GEN VENT & LOC EXHST AT ARC/BOTH, TO KEEP FUMES
& GASES FROM WORKER'S BRTHG ZONE & GEN AREA. TRAIN (SUPDAT)
Other Protective Equipment:WEAR HEAD & BODY PROT WHICH HELP TO PVNT INJ
FROM RADIA, SPARKS & ELEC SHOCK. SEE ANSI Z49.1. AT MIN, THIS INCL
(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VENT:WORKER TO KEEP HIS HEAD OUT OF FUMES. OTHER PROT EQUIP:ARM PROT,
APRONS, HATS, SHOULDER PROT, AS WELL AS DARK SUBSTANTIAL
CLTHG.TRAIN WORKER NOT TO TOUCH LIVE ELEC PARTS & TO INSULATE
HIMSELF FRO M WORK & GROUND.EYE PROT: .WEAR HELMET/USE FACE SHIELD
W/FILTER LENS. PROVIDE PROT SCREENS & FLASH GOG, IF (ING 3)
================== Physical/Chemical Properties ==================
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:WELDING FUMES & GASES CANNOT BE
CLASSIFIED SIMPLY. COMPOSITION & QTY OF BOTH ARE DEPENDENT UPON
METAL BEING (ING 5)
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
WITH FEDERAL, STATE, A ND LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:92-65150-1 QUICKSILVER EXHAUST TUBE SEALER KIT, PART B
Kit Part:Y
CAGE:GO139
CAGE:88907
CAGE:GO139
============= Composition/Information on Ingredients =============
Ingred Name:POLYAMIDE RESIN
Fraction by Wt: >10%
Ingred Name:WEIGHT PER GALLON IN POUNDS: 8.
RTECS #:9999999WG
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN: IRRITATION.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
KEEP WARM/QUIET. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>200F
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL OR CO2
Fire Fighting Procedures:USE STANDARD FIRE FIGHTING PROCEDURES. WEAR
SELF-CONTAINED BREATHING APPARATUS.
================== Accidental Release Measures ==================
MATERIAL. RESIDUE MAY BE REMOVED W/CHLORINATED SOLVENT.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID SKIN CONTACT W/PRODUCT. STORE IN
A COOL, DRY PLACE. KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED.
Ventilation:MECHANICAL (GENERAL): STANDARD.
Other Protective Equipment:IMPERVIOUS CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Appearance and Odor:LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:LOW MOLECULAR WEIGHT HYDROCARBONS, CO,
& NITROGEN COMPOUNDS
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR DISPOSE OF IN AN APPROVED
INDUSTRIAL LANDFILL, CONSULT YOUR STATE OR LOCAL AUTHORITIES IN THE
EVENT MORE RESTRICTIVE REQUIREMENTS APPLY.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:PR-1524 AMBER PART A
Kit Part:Y
CAGE:DO563
CAGE:60777
CAGE:83574
CAGE:DO563
============= Composition/Information on Ingredients =============
Ingred Name:4,4'-METHYLENE BIS (2-CHLOROANILINE) MOCA (SARA III)
CAS:101-14-4
RTECS #:CY1050000
OSHA PEL:S, 0.02 PPM
ACGIH TLV:S, 0.01 PPM,A2; 9394
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:POLYURETHANE POLYMER
CAS:9009-54-5
RTECS #:TR7875000
Fraction by Wt: 75.0%
ACGIH TLV:0.14 MG/CUM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS IRRITANT AND MAY CAUSE
CYANOSIS.
Explanation of Carcinogenicity:IARC REFERENCE 1987 GROUP 2A
Effects of Overexposure:EYES:IRRITATION. SKIN:ABSORBED THRU SKIN. MAY
CAUSE CYANOSIS. INHALED:MAY CAUSE CYANOSIS. INGESTED:MAY CAUSE
CYANOSIS. SLIGHTLY TOXIC.
Medical Cond Aggravated by Exposure:NONE REPORTED
======================= First Aid Measures =======================
First Aid:EYE:FLUSH WITH WATER 15 MIN. SKIN:WASH WITH SOAP & WATER.
CONSULT A PHYSICIAN. INHALED:REMOVE TO FRESH AIR. IF SYMPTOMS ARE
PRESENT,GET MEDICAL ATTENTION. INGESTED:GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM,WATER FOG
Fire Fighting Procedures:USE COMPLETE PERSONAL PROTECTION.
Unusual Fire/Explosion Hazard:ASHES AND VAPORS MAY CONTAIN CARCINOGENS
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR APPROPRIATE PERSONAL PROTECTION. ABSORB
WITH INERT MATERIAL. CLEAN RESIDUE WITH 1,1,1-TRICHLOROETHANE.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL-VENTILATED
AREA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN EXPOSED ABOVE TLV,USE APPROPRIATE NIOSH
CARTRIDGE OR SUPPLIED AIR RESPIRATOR.
Ventilation:USE LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV.
Other Protective Equipment:USE FULL PROTECTIVE CLOTHING (IMPERVIOUS)
WHEN SKIN CONTACT IS LIKELY. DISPOSE OR DECOMTAMINATE
PROTECT.EQUIPMENT DAILY.
Work Hygienic Practices:USE VERY STRICT CHEMICAL HYGIENE PRACTICE.
Supplemental Safety and Health
KEY1:T6. THIS PRODUCT IS A KIT CONSISTING OF TWO PARTS. PART A HAS PNI
A; PART B HAS PNI B, SAME NSN.
================== Physical/Chemical Properties ==================
HCC:T3
Spec Gravity:1.012
Solubility in Water:NEGLIGIBLE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REPORTED
Stability Condition to Avoid:NONE REPORTED
Hazardous Decomposition Products:EMITS TOXIC FUMES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:MICRODUSTER OS,ACCUDUSTER II OS,ACCUDUSTER
CAGE:21994
CAGE:21994
============= Composition/Information on Ingredients =============
Ingred Name:CHLORODIFLUOROMETHANE
CAS:75-45-6
RTECS #:PA6390000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000 PPM
ACGIH TLV:1000PPM; 9192
Ozone Depleting Chemical:2
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV IS 1000 PPM.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPOR IS HEAVIER THAN AIR
AND CAN CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR
BREATHING. BREATHING HIGH CONCENTRATIONS OF VAPOR MAY CAUSE
LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF B REATH, AND MAY LEAD TO
NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH.
SKIN/EYE: IRRITATION AND FROSTBITE.
Explanation of Carcinogenicity:CHLORODIFLUOROMETHANE (FREON 22) IS NOT
LISTED AS A CARCINOGEN BY IARC, NTP OR OSHA.
Effects of Overexposure:BREATHING HIGH CONCENTRATIONS OF VAPOR MAY
CAUSE LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, AND MAY
LEAD TO NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH.
LIQUID IS IRRITATING TO S KIN AND EYES, AND MAY CAUSE FROSTBITE.
Medical Cond Aggravated by Exposure:PERSONS WITH KNOWN HISTORY OF HEART
DISEASE OR IRREGULARITIES OF HEARTBEAT SHOULD BE PARTICULARY
CAREFUL TO AVOID OVEREXPOSURE TO THESE VAPORS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR, CALL A PHYSICIAN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS. EYE: FLUSH
WITH WATE R FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. SKIN:
WASH WITH SOAP AND WATER. IF FROSTBITE, WARM SKIN SLOWLY. GET
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CO2, FOAM/DRY CHEMICAL. WATER SPRAY
MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS
AWAY.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:OTHER BURNING MATERIALS CAN CAUSE
COMPOUND TO BURN.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. VENTIALTE AREA,
ESPECIALLY LOW PLACES WHERE HEAVY VAPORS MIGHT COLLECT. REMOVE
GLOWING METAL SURFACES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY AND
WELL-VENTILATED AREA OF LOW FIRE RISK. PROTECT CONTAINERS FROM
PHYSICAL DAMAGE AND KEEP TIGHTLY CLOSED.
Other Precautions:AVOID BREATHING VAPOR, LIQUID CONTACT WITH EYES, SKIN
OR CLOTHING. DO NOT DROP, REUSE, OR REFILL CONTAINER. DO NOT STORE
NEAR HEAT OR IN DIRECT SUN. KEEP CONTAINERS BELOW 120 F. READ LABEL
BEFORE USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK
SITUATIONS. FOR ACCIDENTAL OR NON-VENTILATED SITUATIONS, USE A
SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR RESPIRATOR,
APPROVED BY NIOSH.
Ventilation:PROVIDE LOCAL AND MECHANICAL EXHAUST WHEN USED.
Other Protective Equipment:USE IMPERVIOUS CLOTHING TO PROTECT EXPOSED
SKIN FROM LIQUID CONTACT.
Work Hygienic Practices:DO NOT SMOKE IN AREA WHILE PRODUCT IS IN USE.
Supplemental Safety and Health
AVOID BREATHING OF VAPORS AND CONTACT WITH EYES/SKIN.
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:B.P. Text:-41F,-41C
Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN
Decomp Temp:Decomp Text:NOT KNOWN
Vapor Pres:7807 @ 77F
Vapor Density:3.03 @ 77F
Spec Gravity:1.194
Evaporation Rate & Reference:GAS
Solubility in Water:0.30% @ 77F (25C)
Appearance and Odor:CLEAR, LIQUEFIED GAS, SLIGHT ETHEREAL ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, POWDERED ALUMINUM, ZINC, BERRYLIUM.
Stability Condition to Avoid:EXCESSIVE HEAT, OPEN FLAMES, GLOWING METAL
SURFACES
Hazardous Decomposition Products:HYDROCHLORIC ACID, HYDROFLUORIC ACID
AND POSSIBLY CARBONYL HALIDES
==================== Disposal Considerations ====================
Waste Disposal Methods:BEST TO RECYCLE OR RECLAIM, IF POSSIBLE. WASTE
MATERIAL MAY BE A LAND-BANNED HAZARDOUS WASTE. CONSULT FEDERAL,
STATE, OR LOCAL AUTHORITIES FOR PROPER DISPOSAL PROCEDURES.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:93353, N-(TRIS(HYDROXYMETHYL)METHYL)-2-AMINO- (SUP DAT)
CAGE:63181
CAGE:63181
============= Composition/Information on Ingredients =============
Ingred Name:N-(TRIS(HYDROXYMETHYL)METHYL)-2-AMINO- ET HANESULFONIC ACID
CAS:7365-44-8
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. MAY CAUSE EYE IRRITATION. MAY CAUSE
SKIN IRRITATION. TO THE BEST OF MANUFACTURER'S KNOWLEDGE, THE
CHEMICAL, PHYSICAL, AND TOXICOLOGI CAL PROPERTIES HAVE NOT BEEN
THOROUGHLY INVESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS
AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE AR TIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON
IS CONSCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING BEFORE
REUSE.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
PLACE IN A BAG AND HOLD FOR DISPOSAL. AVOID RAISING DUST. VENTILATE
AREA AND WASH SPILL SITE AF TER MATERIAL PICK UP IS COMPLETE.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID INHALATION. AVOID CONTACT WITH
EYES, SKIN AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. KEEP
TIGHTLY CLOSED. STORE IN A COOL DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
TRADE NAME/PART NUMBER: ET HANESULFONIC ACID.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:=225.C, 437.F
Appearance and Odor:WHITE POWDER.
================= Stability and Reactivity Data =================
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE, CARBON
DIOXIDE, NITROGEN OXIDES, SULFUR OXIDES.
=================== Toxicological Information===================
Toxicological Information:SEE HEALTH HAZARDS.
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX WITH THE MATERIAL WITH A
COMBUSTIBLE SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED
WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATION S.
=================== MSDS Transport Information ===================
Transport Information:CONTACT FLUKA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
SARA Title III Information:DATA NOT AVAILABLE.
Federal Regulatory Information:DATA NOT AVAILABLE.
State Regulatory Information:DATA NOT AVAILABLE.
======================= Other Information =======================
| 1 |
eyes_protection_mandatory
|
=======================================================
NIIN: 01-228-3163
Product ID: CHEMGLAZE A471 LIGHT GRAY
Cage: 30676
Box: 10038
=======================================================
Contractor Summary
=======================================================
Cage: 30676
=======================================================
Item Description Information
=======================================================
Item Name: POLYURETHANE COATING
=======================================================
Ingredients
=======================================================
Cas: 100-41-4
RTECS #: DA0700000
% Wt: 10.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/STEL 125
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 108-10-1
RTECS #: SA9275000
% Wt: 3.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM/STEL 75
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 108-65-6
RTECS #: AI8925000
% Wt: 10.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 108-88-3
RTECS #: XS5250000
% Wt: 5.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 200 PPM/STEL 300
ACGIH TLV: 50 PM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 1330-20-7
RTECS #: ZE2100000
% Wt: 25.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM/STEL 150
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 1344-37-2
% Wt: 1.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 0.05 MG/M3
ACGIH TLV: 0.05 MG/M3
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
% Wt: 20.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 5 MG/M3
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 4098-71-9
RTECS #: NQ9370000
% Wt: 2.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: 0.005PPM/STEL 0.02
------------------------------
Cas: 5124-30-1
RTECS #: NQ9250000
% Wt: 4.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: 0.005 PPM
------------------------------
Cas: 64742-95-6
% Wt: 10.0
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
RTECS #: 9999999VO
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT RELEVANT
ACGIH TLV: NOT RELEVANT
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: IRRITATION. SKIN: SENSITIZATION, DERMATITIS,
IRRITATION. INHAL: IRRITATION, (DRYNESS OF THROAT, TIGHTNESS OF CHEST,
SHORTNESS OF BREATH), ALLERGIC REACTION, ASTHMA, CNS DEPRESSION, (HEADACHE,
DIZ ZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, COMA), NAUSEA,
CYANOSIS, RESPIRATORY SENSITIZATION & LUNG DAMAGE. *
Signs And Symptions Of Overexposure: * INGEST: HARMFUL. CHRONIC: LIVER, KIDNEY,
CNS, LUNG, NERVOUS SYSTEM, URINARY TRACT, REPRODUCTIVE SYSTEM. TARGETS: GI
TRACT, BLOOD, BLOOD FORMING ORGANS, DERMATITIS.
First Aid: EYE: FLUSH IMMED W/LARGE AMOUNTS WATER FOR >15 MIN, LIFT LIDS.
GET IMMED MED AID. SKIN: FLUSH W/LARGE AMOUNTS WATER, REMOVE CONTAM CLOTHES,
WASH BEFORE REUSE. WASH W/SOAP & WATER, GET MED AID. INHAL: GET FRESH
AIR. RESTORE/SUPPORT BREATHING. IF BREATHING IS DIFFICULT, GIVE OXYGEN, GET
IMMED MED AID. INGEST: DON'T INDUCE VOMIT, GIVE 1-2 GLASSES WATER/MILK CALL
DR/POISON CONTROL. *
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EVAC AREA. REMOVE IGNITS, USE SCBA. NOTIFY
AUTHORITIES IF NECESSARY. DIKE W/ABSORBENT. REMOVE W/NONSPARKING TOOLS. AVOID
CONTACT W/MATERIAL.
Waste Disposal Methods: IN ACCORDANCE W/FEDERAL/STATE/LOCAL ENVIRONMENTAL
CONTROL REGULATIONS. IF WASTE IS HAZARDOUS, USE LICENSED HAZARDOUS WASTE
TRANSPORTER & DISPOSAL FACILITY.
Handling And Storage Precautions: DON'T STORE OR USE NEAR IGNITS. STORE IN WELL
VENTED AREA. DON'T PUNCTURE, DRAG OR SLIDE CONTAINER. KEEP CONTAINER CLOSED
WHEN NOT IN USE.
Other Precautions: GROUND/BOND CONTAINER WHEN TRANSFERRING. DON'T HANDLE UNTIL
SAFETY PRECAUTIONS HAVE BEEN READ/UNDERSTOOD. DON'T REUSE CONTAINER. EMPTY
CONTAINER RETAINS FLAMMABLE RESIDUE. DON'T CUT, PUNCTURE OR WELD ON/NEAR
EMPTY CONTAINER.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point Text: 70.0F,21.1C
Autoignition Temp Text: NE
Lower Limits: 1.0
Upper Limits: 13.1
Extinguishing Media: CO2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures: USE FULL FIREFIGHTING PROTECTIVE CLOTHING, INCLUDING
SCBA. WATER SPRAY MAY BE INEFFECTIVE. FOG NOZZLES PREFERRED.
Unusual Fire/Explosion Hazard: CONTAINER MAY RUPTURE WHEN EXPOSED TO EXTREME
HEAT. USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR.
Ventilation: SUFFICIENT EXPLOSION-PROOF EQUIPMENT.
Other Protective Equipment: DISPOSABLE/IMPERVIOUS CLOTHING, INCLUDING HEAD
COVERING, FACE SHIELD & OVERSHOES.
Work Hygienic Practices: WASH HANDS BEFORE EATING/SMOKING/USING RESTROOM. DON'T
EAT/DRINK NEAR PRODUCT. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: MORE INFORMATION ON FILE.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 232 TO 316F
M.P/F.P Text: NE
Vapor Pres: NE
Vapor Density: >AIR
Spec Gravity: 1.13
PH: NA
Evaporation Rate & Reference: SLOWER THAN ETHER.
Solubility in Water: INSOLUBLE.
Appearance and Odor: GRAY LIQUID, W/SOLVENT ODOR.
Percent Volatiles by Volume: 58.5
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURE & IGNITION SOURCES.
Materials To Avoid: AMINES, ACIDS, WATER, HYDROXYL & ACTIVE HYDROGEN COMPOUNDS.
Hazardous Decomposition Products: MONOMERIC ISOCYONATE, HYDROGEN CYANIDE,
NITROGEN DIOXIDE, CO2, CO, CHLORINE, HYDROGEN CHLORIDE, PHOSJEAN & LEAD
FUMES.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 116577
Product ID: CHEMGLAZE A471 LIGHT GRAY
Review Date: 10/08/1997
Multiple KIT Number: 0
Review IND: Y
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: LFD
DOT Proper Shipping Name: PAINT
DOT PSN Modifier: INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER, AND LIQUID LACQUER BASE
Hazard Class: 3
UN ID Num: UN1263
DOT Packaging Group: II
Label: FLAMMABLE LIQUID
Special Provision: B52,T7,T30
Packaging Exception: 150
Non Bulk Pack: 173
Bulk Pack: 242
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: LCP
IMO Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL
IMO PSN Modifier: (INCLUDING PAINT, LACQUER, ENAMEL, STAIN, SHELLAC SOLUTIONS,
VARNISH, POLISH, LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDING PAINT
THINNING OR REDUCING COMPOUND) o
IMDG Page Number: 3268
UN Number: 1263
UN Hazard Class: 3.2
IMO Packaging Group: I/II *
Subsidiary Risk Label: -
EMS Number: 3-05
MED First Aid Guide NUM: 310
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: SXI
IATA UN ID Num: 1263
IATA Proper Shipping Name: PAINT
IATA PSN Modifier: (INCLUDING
PAINT,LACQUER,ENAMEL,STAIN,SHELLAC,VARNISH,POLISH,LIQUID FILLER AND LIQUID
LACQUER BASE)
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
UN Packing Group: II
Packing Note Passenger: 305
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 307
Exceptions: A7,A72
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: SXI
AFI Proper Shipping Name: PAINT OR PAINT RELATED MATERIAL
AFI PSN Modifier: (INCLUDING PAINT,LACQUER,ENAMEL,STAIN,SHELLAC
SOLUTIONS,VARNISH,POLISH,LIQUID FILLER AND LIQUID LACQUER BASE) OR (INCLUDING
PAINT THINNING OR REDUCING COMPOUNDS)
AFI Hazard Class: 3
AFI UN ID NUM: UN1263
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A7.3
=======================================================
HAZCOM Label
=======================================================
Product ID: CHEMGLAZE A471 LIGHT GRAY
Cage: 30676
Company Name: LORD CORPORATION, CHEMICAL PRODUCTS DIVISION
Street: 2000 WEST GRANDVIEW BLVD
Zipcode: 16514-0038
Label Required IND: Y
Date Of Label Review: 10/12/1999
Status Code: A
Origination Code: G
Hazard And Precautions: EYE: IRRITATION. SKIN: SENSITIZATION, DERMATITIS,
IRRITATION. INHAL: IRRITATION, (DRYNESS OF THROAT, TIGHTNESS OF CHEST,
SHORTNESS OF BREATH), ALLERGIC REACTION, ASTHMA, CNS DEPRESSION, (HEADACHE,
DIZ ZINESS, STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS, COMA), NAUSEA,
CYANOSIS, RESPIRATORY SENSITIZATION & LUNG DAMAGE. *
=======================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:51871 ZEFAZONE IV SOLUTION
CAGE:GO374
CAGE:93703
CAGE:GO374
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: <95%
Ingred Name:NON HAZARDOUS INGREDIENTS
Ingred Name:CEFMETAZOLE SODIUM *94-4*
CAS:56796-39-5
RTECS #:XI0372200
Fraction by Wt: 2-4%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 3,204 MG/KG (SEE SUPP)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:OVEREXPOSURE TO CEFMETAZOLE SOIUM
COULD CAUSE MILD TO SEVERE ALLERGIC
REACTIONS/BRONCHOSPASM/ANGIOEDEMA & ANAPHYLAXIS. ALLERGIC REACTIONS
INCLUDE STEVENS-JOHNSON SYNDROME & ERYTHEMA MULTIFORME. GASTRO
INTESTINAL EFFECTS. PSEUDOMEMBRANOUS COLITIS MAY RANGE IN SEVERITY
FROM MILD TO LIFE THREATENING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:RASH, FEVER, SWELLING, ASTHMATIC BREAHTING,
HIVES, NAUSEA, VOMITING, DIARRHEA
Medical Cond Aggravated by Exposure:HYPERSENSITIVITY TO
CEFMETAZOLE/CEPHALOSPORIN GROUP OF ANTIBIOTICS, BETA-LACTAM
ANTIBIOTICS, RENAL/HEPTATIC IMPAIRMENT, POOR NUTRITIONAL STATE/GI
DISEASE/CURRENTLY BEING TREATED W/AN AMINOGLYCOSIDE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER.
INHALATION: REMOVE FROM EXPOSURE. OBTAIN MEDICAL ATTENTION IN ALL
CASES. NOTES TO PHYSICIAN: IN THE EVENT OF SERIOUS TOXIC REACTIONS
FROM OV EREXPOSURE, HEMODIALYSIS/PERITONEAL DIALYSIS MAY AID IN THE
REMOVAL OF CEFMETAZOLE FROM THE BODY, ESPECIALLY IF RENAL FUNCTION
IS COMPROMISED.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:WATER, CO2/DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF CONTAINED BREAHTING APPARATUS & FULL
BODY PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:PROVIDE VENTILATION & PERSONAL PROTECTION.
KEEP PRODUCT OUT OF DRAINS; PREVENT ENTRY TO SURFACE
WATER/GROUNDWATER & SOIL. SMALL: ABSORB W/PAPER TOWELS/OTHER
APPROPRIATE MEDIA. LARGE: VACUUM/SCOOP & PL ACE IN A SUITABLE
CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE & PROTECT
FROM LIGHT. THE UNDILUTED PRODUCT SHOULD BE STORED IN A CONSTANT
FREEZER AT -4F.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN,
EYES & CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED.
Ventilation:LOCAL EXHAUST.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
ZEFAZONE IV SOLUTION IS A HUMAN DRUG USED IN THE TREATMENT OF SERIOUS
INFECTIONS INVOLVING THE URINARY TRACT, LOWER RESPITORY TRACT,
SKIN/SUPPORTING STRUCTURES, INTRAABDOMINAL INFECTIONS & SOME SEXUAL
LY TRANSMITTED DISEASES. PH: 4.2-6.2 (THAWED). ORAL LD50
INFORMATION IS FOR: CEFMETAZOLE SODIUM.
================== Physical/Chemical Properties ==================
pH:(SUPP)
Solubility in Water:COMPLETE
Appearance and Odor:FROZEN, PREMIXED SOLUTION (W/1-2 G CEFMETAZOLE
SODIUM) IN 50 ML PLASTIC BAGS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:THAWED- >21 DAYS AT TEMP >46F/>48 HOURS AT
TEMP >77F.
Hazardous Decomposition Products:CO, CO2, NITROGEN OXIDES, SULFUR
OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF BY INCINERATION IN ACCORDANCE
W/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:SULFIDE 1 REAGENT, 1816
CAGE:4T252
CAGE:4T252
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA 302/313) (CERCLA)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: <65%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:OTHER COMPONENTS
Fraction by Wt: <1%
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: TO 100%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:THIS PRODUCT MAY BE: CORROSIVE TO
EYES, SKIN AND RESPIRATORY TRACT. ACUTE TOXICITY: MODERATELY TOXIC.
CHRONIC TOXICITY: CHRONIC IRRITATION OR INFLAMMATION, TEETH
EROSION. TARGET ORGANS: TEETH, LUNGS. CARCIN: TARGET ORGANS: NASAL
CAVITY, PARANASAL SINUS, LUNGS, LARYNX. OVEREXPOSURE: SEVERELY
BURNS ANY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SULFURIC ACID: IARC MONO ON EVAL OF
CARCIN RISK OF CHEMS TO MAN, VOL 54, PG 41, 1992:GROUP 1.
ANIMAL:PULMONARY IRRIT.
Effects of Overexposure:HLTH HAZ: TISSUE CONTACTED. BREATHING IN THE
MIST OR VAPOR MAY CAUSE MOUTH SORENESS, TEETH EROSION AND
DIFFICULTY IN BREATHING. INHALATION OF THE MIST/VAPOR OF CONC
SULFURIC ACID CAN CAUSE CANCER OF N ASAL TISSUE, LUNGS AND LARYNX.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN AND
RESPIRATORY CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYE AND SKIN CONTACT: IMMED FLUSH EYES & SKIN W/WATER FOR AT
LST 15 MINUTES. REMOVE CONTAMD CLTHG. CALL PHYS. INGEST: DO NOT
INDUCE VOMITING. GIVE 1-2 GLASSES OF WATER. CALL PHYS IMMED. NEVER
GIVE ANY THING BY MOUTH TO UNCONSCIOUS PERSON. INHAL: REMOVE TO
FRESH AIR. GIVE ARTF RESP IF NECESSARY. CALL PHYS.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL. DO NOT USE WATER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY EMIT TOXIC FUMES IN FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER SPILL W/EXCESS SODA ASH OR SODA
BICARBONATE. SCOOP SLURRY TO BEAKER. ADJUST PH TO BETWEEN 6 AND 9.
FLUSH TO DRAIN WITH EXCESS WATER. WASH SITE WITH AN ALKALI
SOLUTION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL PLACE AWAY FROM
OXIDIZERS AND REDUCERS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
Other Precautions:DO NOT BREATHE MIST OR VAPOR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:ADEQUATE VENTILATION.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . LAB
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:148F,100C
Spec Gravity:1.500
pH:<0.5
Evaporation Rate & Reference:HYGRO
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS OR LIGHT BROWN LIQUID. NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
HEAT, FLAMES, CONTACT WITH OXIDIZERS OR REDUCERS, CAUSTICS & CAUSTIC
FUMES, ACETIC ACID, CHLOROSULFONIC ACID.
Stability Condition to Avoid:HEAT, FLAMES, CONTACT WITH OXIDIZERS OR
REDUCERS, CAUSTICS & CAUSTIC FUMES, ACETIC ACID, CHLOROSULFONIC
ACID.
Hazardous Decomposition Products:MAY EMIT TOXIC FUMES OF SULFUR OXIDES
IN FIRE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE,
AND LOCAL REGULATIONS.
======================================================================
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:SIKAFLEX 201, MB BRONZE
CAGE:0PMN0
CAGE:0PMN0
============= Composition/Information on Ingredients =============
Ingred Name:XYLENE; (XYLENE, MIXED ISOMERS) (SARA 313) (CERCLA)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: <18%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM; 150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE A REVERSIBLE
INFLAMMATORY EFFECT ON THE UPPER RESPIRATORY SYSTEM. SKIN: MAY
CAUSE A REVERSIBLE INFLAMMATORY EFFECT ON SKIN OR TISSUE AT THE
SITE OF CONTACT. CAUSES AN ALLERGIC SE NSITIZATION IN A SUBSTANTIAL
PROPORTIONOF HUMANS OR ANIMALS IN NORMAL TISSUE AFTER REPEATED
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: EXPOSURES. EYES: IRRITANT. INGESTION:
NOT NORMALLY INGESTED. MISCELLANEOUS TOXICOLOGICAL INFORMATION:
TESTS ACCORDING TO FHSLA 16 CFR-1500 HAS SHOWN: PRIMARY SKIN
IRRITANT. EYE IRRITANT. NOT TOXIC ORALLY. NOT TOXIC BY
INHALATION.NOT TOXIC DERMALLY.
Medical Cond Aggravated by Exposure:ASTHMA TYPE CONDITIONS, CHRONIC
BRONCHITIS AND OTHER CHRONIC RESPIRATORY CONDITIONS. RECURRENT SKIN
ECZEMA, PRESENSITIZATION TO PRODUCT.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED,
INSTITUTE ARTIFICIAL RESPIRATION. CONSULT WITH MD. SKIN: WASH SKIN
THOROUGHLY WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. IF
SYMPTOMS PERSISTS CONSULT MD. EYES: RINSE EYES THOROUGHLY WITH
WATER FOR AT LEAST 15 MINUTES. CONSULT MD. INGESTION: DILUTE WITH
WATER. DO NOT INDUCE VOMITING. CONTACT MD.
===================== Fire Fighting Measures =====================
Flash Point:143F,62C
Extinguishing Media:FOAM/WATER FOG/DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING AND/OR TOXIC
GASES AND AEROSOLS FROM THE DECOMPOSITION/COMBUSTION PRODUCTS MAY
BE PRESENT.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT. CONTAIN
SPILL AND COLLECT WITH ABSORBENT MATERIAL AND TRANSFER INTO
SUITABLE CONTAINERS. AVOID CONTACT. VENTILATE ENCLOSED AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & OPEN
FLAME. STORE IN TIGHTLY CLOSED CONTAINER & PROTECT FROM MOISTURE &
FOREIGN MATL. STORAGE TEMP 32F MIN - 122F MAX.
Other Precautions:IF CLOSED CONTAINER OF MATERIAL IS EXPOSED TO HEAT,
PRESSURE CAN BUILD UP. IF MOISTURE ENTERS DRUM, PRESSURE BUILD UP
DUE TO REACTION. AT MAXIMUM STORAGE TEMP NOTED, MATERIAL MAY
POLYMERIZE WITHOUT HA ZARD. IDEAL STORAGE TEMP IS 50-81F.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR
RECOMMENDED IF VENTILATION IS NOT ADEQUATE.
Ventilation:LOCAL EXHAUST HIGHLY RECOMMENDED. MECHANICAL EXHAUST HIGHLY
RECOMMENDED.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
AVOID SKIN CONTACT. WEAR LONG SLEEVE SHIRT AND LONG PANTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Vapor Density:>AIR
Spec Gravity:1.19
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:PASTE; XYLENE ODOR.
Percent Volatiles by Volume:<6
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOL, AMINES.
Stability Condition to Avoid:OPEN FLAME, HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:KODAK EKTACOLOR RA BLEACH FIX REPLENISHER NR,PART B
Kit Part:Y
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:AMMONIUM FERRIC ETHYLENEDIAMINETETRAACETIC ACID *93-1*
CAS:21265-50-9
Fraction by Wt: 35-40%
Ingred Name:DIAMMONIUM ETHYLENEDIAMINE TETRAACETIC ACID *93-3*
CAS:20824-56-0
Fraction by Wt: 1-5%
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 60-65%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION/SKIN/INGESTION: LOW HAZARD.
EYES: TRANSIENT IRRITATION.
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: WASH OUT IMMEDIATELY
W/WATER. SKIN: WASH W/SOAP & WATER. INGESTION: DRINK 1-2 GLASSES OF
WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN CONTAINER FOR CHEMICAL WASTE. PRODUCT EXPECTED TO
HAVE: LOW BIOCHEMICAL OXYGEN DEMAND & LITTLE POTENTIAL TO CAUSE
OXYGEN DEPLETION IN AQUEOU S SYSTEMS. (SEE SUPP)
======================Handling and Storage ======================
Handling and Storage Precautions:USE W/ADEQUATE VENTILATION. KEEP FROM
CONTACT W/OXIDIZING MATERIALS. KEEP CONTAINER CLOSED.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. AFTER DILUTION
W/PLENTY OF WATER, FOLLOWED BY SECONDARY WASTE TREATMENT, THIS
MATERIAL IS NOT EXPECTED TO CAUSE ADVERSE ENVIRONMENTAL EFFECTS.
============= Exposure Controls/Personal Protection =============
Ventilation:GOOD GENERAL (TYPICALLY 10 AIR CHANGES PER HOUR). RATES
SHOULD BE MATCHED TO CONDITIONS
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
LOW POTENTIAL TO: AFFECT AQUATIC ORGANISMS, AFFECT SECONDARY WASTE
TREATMENT MICROBIAL METABOLISM, AFFECT THE GERMINATION &/OR EARLY
GROWTH OF SOME PLANT, BIODEGRADE W/UNACCLIMATED MICROORGANISMS FROM
ACTIVATED SLUDGE, BIOCONCENTRATE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F/100C
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.22
pH:7.1
Solubility in Water:COMPLETE
Appearance and Odor:DARK BROWN LIQUID W/SLIGHT AMMONIA ODOR
Percent Volatiles by Volume:60-65
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:AMMONIA, CO, CO2, OXIDES OF NITROGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:FLUSH TO SEWER W/PLENTY OF WATER. LARGE AMOUNTS:
CONTRACT W/LICENSED CHEMICAL DISPOSAL AGENCY. DISCHARGE, TREATMENT
OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE & LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:ADHESIVE CARPET PROTECTOR,PROD CODE 901A1007P20
CAGE:80797
CAGE:80797
============= Composition/Information on Ingredients =============
Ingred Name:ACRYLIC-VINYL COPOLYMER ADHESIVE
Other REC Limits:NONE RECOMMENDED
Ingred Name:POLYETHYLENE
CAS:9002-88-4
RTECS #:TQ3325000
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:ADHESIVE MAY BE
IRRITATING.EYE:SOLID CONTACT MAY CAUSE IRRITATION.INGEST:MAY CAUSE
CHOKING.INHAL:UNLIKELY DUE TO PHYSICAL PROPERTIES.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:MECHANICAL IRRITATION,SKIN IRRITATION.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:SKIN:WASH WITH SOAP AND WATER.EYE:MECHANICAL IRRITATION
REQUIRES MEDICAL ATTENTION.INGEST:GET PROMPT QUALIFIED MEDICAL
ATTENTION.INHAL:FIRST AID NOT LIKELY TO BE NEEDED.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:REGULAR FOAM,WATER FOG,CARBON DIOXIDE,DRY CHEMICAL.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS IN
POSITIVE PRESSURE MODE AND FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:DENSE SMOKE EMITTED WHEN BURNED WITHOUT
SUFFICIENT OXYGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP AND DISCARD.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:NO SPECIAL REQUIREMENTS.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NEEDED IN NORMAL SERVICE.
Ventilation:GENERAL MECHANICAL DILUTION VENTILATION.
Other Protective Equipment:NONE
Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS ITEM.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:0.91-0.97
Solubility in Water:NIL
Appearance and Odor:GRAY FILM(ADHESIVE)APPLIED OVER WHITE
FILM(POLYETHYLENE);SLIGHT ISOPROPANOL ODO
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,VARIOUS
HYDROCARBONS,UNIDENTIFIED TOXIC MATERIELS.
==================== Disposal Considerations ====================
Waste Disposal Methods:BURY IN A LANDFILL OR INCINERATE IN ACCORDANCE
WITH FEDERAL,STATE AND LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:LACQUER SPRAYING GREEN 14260
Preparer's Name:W.A. ELLISON
CAGE:FO127
CAGE:FO127
CAGE:61196
============= Composition/Information on Ingredients =============
Ingred Name:ISOBUTYL ACETATE (SARA III)
CAS:110-19-0
RTECS #:AI4025000
OSHA PEL:150 PPM
ACGIH TLV:150 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
Ingred Name:NITROCELLULOSE
CAS:9004-70-0
RTECS #:QW0970000
OSHA PEL:NONE ESTABLISHED
ACGIH TLV:NONE ESTABLISHED
Ingred Name:ISOBUTYL ALCOHOL (SARA III)
CAS:78-83-1
RTECS #:NP9625000
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER
CAS:107-98-2
RTECS #:UB7700000
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN)
CAS:8030-30-6
RTECS #:SE7555000
OSHA PEL:100 PPM
Ingred Name:DI-SEC-OCTYL PHTHALATE (DI-2-ETHYLHEXYL-PHTHALATE)(SARA
III)
CAS:117-81-7
RTECS #:TI0350000
OSHA PEL:5 MG/M3/10 STEL
ACGIH TLV:5 MG/M3; 9192
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:N-HEPTANE
CAS:142-82-5
RTECS #:MI7700000
OSHA PEL:500 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9293
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VOC. ORGANIC CMPD 5.4 LB/GAL LESS WATER & NPRS* 648 G/L
LESS WATER VOC. 26.5 LB/GAL SOLIDS 3180 G/L SOLIDS CALCU
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ASPIRATION OF MATL INTO LUNG MAY CAUSE
CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. HIGH CONCENT. MAY CAUSE
ACUTE CENTL NERVOUS SYS. DEPRESS.; PROLONGED/REPEATED EXPOSURE TO
SOLVENT W/PERMANENT BRAIN DA MAGE,NERVOUS SYSTEM DAMAGE.
INTENTIONALMISUSE CAN BE HARMFUL OR FATAL.
Explanation of Carcinogenicity:THERE IS NO SIGNIFICANT HAZARD FOR MAN
Effects of Overexposure:EYE: IRRITATION
SKIN: IRRITATION
INHAL: NOSE,THROAT
IRRITATION, HEADACHES , DIZZINESS, NAUSEA, & CONFUSIONINGST:
GASTROINTESTINAL IRRITATION,NAUSEA, & VOMITING.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/LG AMOUNTS OF WTR, FOR 15 MINS. LIFTING
EYELIDS,GET MEDICAL ATTN. SKIN: WASH AFFECTED AREA W/SOAP & WTR.
REMOVE CONTAM CLOTHING,GET MEDICAL ATTN. INHAL: REMOVE TO FRESH AIR
IMMEDIATELY,G IVE ARTIFICIAL RESPIRATION IF NEEDED,GETMEDICAL
ATTENTION.
INGST: DO NOT INDUCE VOMITING, GET MEDICAL ATTENTION
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:20F/-6.67C
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS. POLYMER FOAM
IS PREFER-RED FOR LARGE FIRES.
Fire Fighting Procedures:SHOULD WEAR SCBA; WATER MAY INEFFECTIVE, BUT
MAY BE USED TO COOL EXPOSED CONTNRSTO PREVENT PRESS BUILD UP &
POSS. IGNITION.IF WTR IS USED, FOG NOZZLE PREFERABLE
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELEC EQUIP,SPARKS & FLAMES. CLOSED CONTAINERS MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNTION. DIKE &
CONTAIN SPILL W/INERT MATL. USE ONLY NON SPARKING TOOLS. PLACE
ABSORBENT DIKING MATL IN COVERED METAL CONT-AINERS FOR DISPOSAL.
PREVENT CONTAMINATION OF SEW- ERS,STREAMS,& GROUNDWATER W/SPILLED
MATL OR ABSORB
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 95F. STORE LARGE
QUANTITIES IN COMPLIANCE WITH OSHA 29CFR 1910.106. CLOSE
CONTNRSAFTER EACH USE. NEVER USE PRESSURE TO EMPTY CONTNR
Other Precautions:DO NOT TAKE INTERNALLY. EMPTY CONTAINERS MUST NOT BE
WASHED AND REUSED FOR ANY PURPOSE. CONTAINERS SHOULD BE GROUNDED
AND BONDED TO THE RECEIVING CONTAINER. DO NOT WELD, BRAZE, OR CUT
ON EMPTY CONT AINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESTRICTED AREAS USE A NIOSH APPROVED CHEMICAL
CARTRIDGE RESPIRATOR.; SPRAYING USE A MECHANICAL PREFILTER; IN
CONFINED AREAS USE A NIOSH/MSHA APPROVED AIR SUPPLIED
RESPIRATOR.
Ventilation:LOCAL EXHAUST OR MECHANICAL VENTILATION
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:175-302F
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:79
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS, OXIDIZING MATERIALS
Stability Condition to Avoid:EXCESSIVE HEAT AND SOURCES OF IGNITION
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING,CUTTING, WILL PRO-DUCE SMOKE, CARBON MONOXIDE/DIOXIDE
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT SPARKS, AND
FLAME
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE ONLY IN EPA FACILITY. DO NOT
INCINERATECLOSED CONTAINERS. DISPOSE ONLY IN ACCORDANCE
WITHFEDERAL, STATE, AND LOCAL REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:AS 509, WATER-BASED SPRAY PAINT
Preparer's Name:TECHNICAL GROUP
CAGE:ZPRXX
CAGE:ZPRXX
============= Composition/Information on Ingredients =============
Ingred Name:SEC-BUTYL ALCOHOL; (SEC-BUTANOL). LD50: (ORAL, RAT) 6480
MG/KG.
CAS:78-92-2
RTECS #:EO1750000
Fraction by Wt: 1-5%
OSHA PEL:150 PPM
ACGIH TLV:100 PPM; 9293
Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL). LD50: (ORAL, RAT)
4420-5840 MG/KG.
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 1-5%
OSHA PEL:400 PPM;500 PPM STEL
ACGIH TLV:400 PPM;500 PPM STEL
Ingred Name:METHYL ETHER; (DIMETHYL OXIDE)
CAS:115-10-6
RTECS #:PM4780000
Fraction by Wt: 15-40%
OSHA PEL:1000 PPM (MFR)
Ingred Name:N-BUTYL ALCOHOL; (BUTYL ALCOHOL). LD50: (ORAL, RAT) 4360
MG/KG.
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 1-5%
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:2-BUTOXYETHANOL; (ETHYLENE GLYCOL MONOBUTYL ETHER). LD50:
(ORAL, RAT) 530-1480 MG/KG.
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 5-10%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: DIZZINESS, NAUSEA, IRRITATION
TO SKIN AND EYES. CHRONIC: SOLVENTS MAY CAUSE DEFATTING DERMATITIS.
ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFFECTS ON
THE CNS, THE HEMATOPOIETICTISSUES, THE BLOOD, THE KIDNEYS AND
THELIVER, ASSOCD W/THE ADMINISTRATION OF ETHYLENE GLYCOL (EFTS OF
OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:MONOBUTYL ETHER (EGBE) AND ETHYLENE
GLYCOL MONOBUTYL ETHER ACETATE (EGBEA). (EXTRACTED FROM DHHS
(NIOSH) PUBLICATION NO. 90-118) .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. SKIN: FLUSH EXPOSED SKIN WITH
COPIOUS AMOUNTS OF WATER. EYES: FLUSH EYES WITH COPIOUS AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES. INGEST: DO NOT INDUCE VOMITING. CALL
MD IMME DIATELY.
===================== Fire Fighting Measures =====================
Flash Point:SUPP DATA
Lower Limits:1.4%
Upper Limits:12%
Extinguishing Media:DRY CHEMICAL, CO*2, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER FOR FOGGING NOZ MAY BE USED TO COOL CLSD CNTNRS TO PVNT
PRESS BUILD-UP IF EXPOS TO EXTREME TEMPS.
Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE IF EXPOSED TO
TEMPERATURES GREATER THAN 120F.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. USE INERT
ABSORBENT MATERIAL AND NON-SPARKING TOOLS. AVOID BREATHING FUMES.
VENTILATE AREA. PREVENT FROM ENTERING WATERCOURSE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA
NOT TO EXCEED 120F.
Other Precautions:DO NOT PUNCTURE OR INCINERATE CONTAINERS, EVEN WHEN
EMPTY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF USED INDOORS ON A CONTINUOUS BASIS, USE OF A
NIOSH/MSHA APPROVED CARTRIDGE TYPE RESPIRATOR IS RECOMMENDED.
Ventilation:LOCAL.
Other Protective Equipment:NOT NORMALLY REQUIRED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH:8.7-9.5. FP: >54F (CONCENTRATE), NON FLAMMABLE BY FLAME PROJECTION
(AEROSOL). MP: <-103F, <-75C.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>181F,>83C
Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
Vapor Pres:55-60@20C
Vapor Density:2.07-4.1
Spec Gravity:1 (H*2O=1)
pH:SUPDAT
Evaporation Rate & Reference:0.08-12.7 (BUAC=1)
Solubility in Water:30-45%
Appearance and Odor:COLORED LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:STORAGE IN HOT, UNVENTILATED AREAS.
Hazardous Decomposition Products:HYDROCARBON FUMES AND SMOKE. CO WHERE
COMBUSTION IS INCOMPLETE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:CARTRIDGE, CARBON DIOXIDE
CAGE:99539
Contract Num:SP0560-00-M-H062
CAGE:99539
============= Composition/Information on Ingredients =============
Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
= Wt:100.
OSHA PEL:9000 MG/M3;5000 PPM
ACGIH TLV:9000 MG/M3;5000 PPM
ACGIH STEL:54000 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTACT WITH LIQUID OR SOLID MAY CAUSE
FROSTBITE. HMIS: CARBON DIOXIDE IS A SIMPLE ASPHYXIANT.
Explanation of Carcinogenicity:NOT LISTED.
================== Accidental Release Measures ==================
Spill Release Procedures:IF RELEASED CARBON DIOXIDE WILL DIFFUSE INTO
ATMOSPHERE.
======================Handling and Storage ======================
Handling and Storage Precautions:PROTECT CARTRIDGE FROM PHYSICAL
DAMAGE. DO NOT REMOVE SAFETY CAP UNTIL CARTRIDGE IS TO BE ATTACHED
TO FIRE EXTINGUISHER. DO NOT PUNCTURE CARTRIDGE SEAL. DO NOT EXPOSE
TO TEMPERATURE ABOVE 130F.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NEEDED. HMIS:IN CONFINED SPACES USE NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS.
Ventilation:NOT NEEDED.
Other Protective Equipment:NOT NEEDED.
Work Hygienic Practices:AVOID CONTACT WITH CONTENTS OF CARTRIDGE. HMIS:
USE IN A WELL VENTILATED AREA.
Supplemental Safety and Health
ADDITIONAL P/N: YP1001880DD713.
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:=-78.5C, -109.3F
Melt/Freeze Pt:=-78.5C, -109.3F
M.P/F.P Text:SUBLIMES
Vapor Pres:850 PSI@70F
Vapor Density:1.53
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS, ODORLESS GAS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:WILL NOT OCCUR
| 0 |
eyes_protection_not_mandatory
|
===================== Product Identification =====================
Product ID:HALON 1301 897893
CAGE:MO903
CAGE:MO903
CAGE:61423
============= Composition/Information on Ingredients =============
Ingred Name:TRIFLUOROBROMOMETHANE (HALON 1301) (SARA III)
CAS:75-63-8
RTECS #:PA5425000
Fraction by Wt: >99%
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9192
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:MAY CAUSE LIGHT HEADEDNESS, GIDDINESS,
DIZZINESS, SHORTNESS OF BREATH
Medical Cond Aggravated by Exposure:AT CONCENTRATIONS OF 10% BY VOLUME
& HIGHER MAY CAUSE POSSIBLE NARCOSIS & CARDIAC ARRHYTHMIAS
======================= First Aid Measures =======================
First Aid:REMOVE TO FRESH AIR. CALL A MD. DO NOT GIVE EPINEPHRINE OR
SIMILAR DRUGS. FLUSH W/ WATER FOR SKIN OR EYE CONTACT.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:HALON 1301
Fire Fighting Procedures:SCBA TO PROTECT AGAINST VAPORIZED MATERIAL
DECOMPOSITION PRODUCTS (BROMINE, FLUORINE, HALOGEN ACIDS & CARBONYL
HALIDES)
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA - ESPECIALLY LOW PLACES WHERE
HEAVY VAPORS MAY COLLECT. REMOVE OPEN FLAMES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE CONTAINERS IN A CLEAN, DRY AREA
DO NOT HEAT >125F
Other Precautions:AVOID CONTAINER DAMAGE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE FULL FACE PIECE SUPPLIED AIR RESPIRATOR OR
SCBA FOR CONCENTRATIONS > TLV
Ventilation:IF TLV IS EXCEEDED. LEV IF TLV IS EXCEEDED. VENTILATE SUMPS
& PITS WHERE VAPORS MAY COLLECT
Other Protective Equipment:SAFETY SHOWER & EYE WASH STATION NEAR WORK
AREA.
Work Hygienic Practices:GOOD HYGIENE PRACTICES AS WITH ANY INDUSTRIAL
CHEMICAL
Supplemental Safety and Health
THIS IS PART "B" OF A TWO PART PRODUCT BUT NOT A KIT.
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:B.P. Text:72.0F,22.2C
Vapor Pres:12,152
Vapor Density:8.71 G/L
Spec Gravity:1.538 G/L
Solubility in Water:0.03 @ 77F
Appearance and Odor:SLIGHT ETHERAL ODOR, COLORLESS GAS & LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
LIQUID CONTACT W/ ALKALI & ALKALINE EARTH METALS - POWDERED ALUMINIUM,
ZINC, BERYLLIUM, ETC.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS - AVOID
CONTACT W/ OPEN FLAMES OR TEMPS ABOVE 1000 F
Hazardous Decomposition Products:HYDROGEN FLOURIDES, HYDROGEN
BROMIDES,FREE BROMINE & CARBONYL HALIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:EVAPORATE OUT DOORS
| 1 |
eyes_protection_mandatory
|
===================== Product Identification =====================
Product ID:P6142 POTASSIUM PERMANGANATE
CAGE:21076
CAGE:21076
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM PERMANGANATE (SARA III)
CAS:7722-64-7
RTECS #:SD6475000
Fraction by Wt: 100%
OSHA PEL:5 MG MN/M3;CEILING
ACGIH TLV:5 MG MN/M3; 9192
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) IS 1090 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED,INHALED,OR
ABSORBED THROUGH SKIN.MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE
OF THE MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT,EYES AND
SKIN.OVEREXPOSURE CAN RESULT IN ANEMIA,SW ELLING OF THE THROAT WITH
THE POSSIBILITY OF SUFFOCATION AND KIDNEY DAMAGE.INHALATION MAY BE
FATAL.
Explanation of Carcinogenicity:THIS PRODUCT IS NOT LISTED BY IARC, NTP
OR OSHA AS A CARCINOGEN.
Effects of Overexposure:SYMPTOMS OF EXPOSURE MAY INCLUDE BURNING
SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH,
HEADACHE, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN AND
RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:EYES:IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT
LEAST 15 MINUTES. SKIN:IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF
WATER WHILE REMOVING CONTAMINATED CLOTHING AND SHOES.
INHALATION:REMOVE TO FRES H AIR.IF NOT BREATHING GIVE ARTICIAL
RESPIRATION.IF BREATHING IS DIFFICULT,GIVE OXYGEN.SEE DOCTOR.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. CONTACT WITH OTHER
MATERIALS MAY CAUSE FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA.SHUT OFF IGNITION
SOURCES.VENTILATE.WEAR SCBA,RUBBER BOOTS AND HEAVY RUBBER
CONTAINERS USING NON-SPARKING TOOLS AND TRANSPORT OUTDOORS.WASH
AREA WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE REQUIRED
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENTILATED
AREA.KEEP AWAY FROM COMBUSTIBLE MATERIALS, HEAT AND IGNITION
SOURCES. KEEP CONTAINERS CLOSED.
Other Precautions:AVOID BREATHING DUST. DO NOT GET IN EYES, SKIN OR
CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR AS PER
CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH-RESPIRATOR
SELECTION.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER EQUIPMENT
AS REQUIRED TO MINIMIZE EXPOSURE FROM PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING AND BEFORE
EATING.LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.DISCARD
CONTAMINATED SHOES.
Supplemental Safety and Health
SEE CASE HISTORY 90200A FOR MORE INFORMATION ON WASTE DISPOSAL
PROCEDURES AND ON INCOMPATIBLE MATERIALS THAT MAY RESULT IN
IGNITION, INCREASED SENSITIVITY TO HEAT OR FRICTION, VIOLENT
REACTIONS, OR EX PLOSIONS.-THIS PRODUCT CAUSES EFFECTS ON MALE
FERTILITY.
================== Physical/Chemical Properties ==================
HCC:D1
Spec Gravity:2.703
Solubility in Water:COMPLETE
Appearance and Odor:BLACK OR DEEP PURPLE CRYSTALS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG REDUCING AGENTS,FINELY POWDERED
METALS,PEROXIDES,ALUMINUM,ZINC,LEAD,COPPER,AND THEIR ALLOYS.
Stability Condition to Avoid:HIGH TEMPERATURES, OPEN FLAMES.
Hazardous Decomposition Products:NATURE OF DECOMPOSITION PRODUCTS NOT
KNOWN.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER. A
SPECIAL PRECIPITATION PROCEDURE MUST BE FOLLOWED PRIOR TO DISPOSAL.
FOLLOW MANUFACTURER'S INSTRUCTIONS. DISPOSE OF IN ACCORDANCE WITH
ALL APPLICABLE FEDERAL , STATE AND LOCAL LAWS AND REGULATIONS.
| 1 |
eyes_protection_mandatory
|
Subsets and Splits
No community queries yet
The top public SQL queries from the community will appear here once available.