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=======================================================
Product ID: METHYLENE BLUE INJECTION
Cage: LPOLD
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: LPOLD
Assigned Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 32288
Cage: LPOLD
=======================================================
Ingredients
=======================================================
Cas: 7220-79-3
RTECS #: SP5740000
------------------------------
Cas: 61-73-4
RTECS #: SO5600000
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION/INGESTED/SKIN: ALLERGIC REACTION.
EYES/SKIN/RESPIRATORY TRACT: IRRITATION. POSSIBLE HYPERSENSITIZATION.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, HYPERSENSITIZATION
First Aid: INHALATION: REMOVE TO FRESH AIR. INGESTION: FLUSH MOUTH OUT W/WATER.
SKIN: FLUSH W/WATER. EYES: FLUSH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT.
VACUUM SPILLAGE W/A VACUUM CLEANER HAVING A HIGH EFFECIENCY PARTICULATE
FILTER/ABSORB LIQUID W/PAPER TOWELS. WIPE WORKING SURFACES TO DRYNESS, THEN
WASHW/SOAP & WATER.
Waste Disposal Methods: DON'T MIX W/OTHER SUBSTANCES. DISPOSE OF IAW/LOCAL,
STATE & FEDERAL REGULATIONS.
Handling And Storage Precautions: AS A GENERAL RULE, WHEN HANDLING
PARMACEUTICAL PRODUCTS, AVOID ALL CONTACT & INHALATION OF DUST, FUMES,
MISTS/VAPORS. DON'T MIX W/OTHER DRUGS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: WATER SPRAY, CO2, DRY CHEMICAL/FOAM AS APPROPRIATE FOR
SURROUNDING FIRE & MATERIAL.
Fire Fighting Procedures: WEAR SCBA & PROTECTIVE CLOTHING.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED RESPIRATOR SHOULD BE AVAILABLE.
Ventilation: LOCAL EXHAUST RECOMMENDED
Other Protective Equipment: DISPOSABLE PROTECTIVE CLOTHING
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
=======================================================
Physical/Chemical Properties
=======================================================
PH: 3-4.5
Solubility in Water: COMPLETE
Appearance and Odor: DEEP BLUE SOLUTION, W/RELATIVELY NO ODOR
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: TOXIC FUMES
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: METHYLENE BLUE INJECTION
Cage: LPOLD
Assigned IND: Y
Company Name: LUTTPOLD PHARMACEUTICALS INC
Street: ONE LUTTPOLD DR
Zipcode: 11967-5000
Label Required IND: Y
Date Of Label Review: 12/16/1998
Status Code: C
Label Date: 12/16/1998
Origination Code: G
Hazard And Precautions: INHALATION/INGESTED/SKIN: ALLERGIC REACTION.
EYES/SKIN/RESPIRATORY TRACT: IRRITATION. POSSIBLE HYPERSENSITIZATION.
IRRITA
TION, HYPERSENSITIZATION
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:80 6200 HLOOM SAND SEALER
Resp. Party Other MSDS Num.:80-0006200
Preparer's Name:REGULATORY AFFAIRS DEPT
CAGE:13418
CAGE:13418
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF INHALED. MAY AFFECT
THE BRAIN, NERVOUS SYSTEM OR RESPIRATORY SYSTEM, CAUSING DIZZINESS,
HEADACHE, NAUSEA OR RESPIRATORY IRRITATION. OVEREXPOSURE TO
INGREDIENTS IN THIS PRODUCT MAY CA USE EYE IRRITATION. DELAYED
EFFECTS (CHRONIC): NONE KNOWN.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:ANY RESPIRATORY OR SKIN CONDITION.
======================= First Aid Measures =======================
First Aid:NONE. INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH
AIR. SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . EYES:
IMMEDIATELY FLUSH W/POTABLE WATER FOR AT LEAST 15 MINUTES, SE EK
ASSISTANCE FROM MD . SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. .
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=93.3C, 200.F
SUPDAT
Lower Limits:2.0%
Upper Limits:17.0
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, AND/OR WATER
FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . CONTAINERS EXPOSED TO FIRE SHOULD BE KEPT COOL WITH
WATER SPRAY.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE SPILLS WITH INERT
ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. DO NOT STORE ABOVE 120 DEG F (49 DEG C). KEEP FROM FREEZING.
EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUE. DO NOT CUT, PUNCTURE
OR WELD CONTAINERS. ALL LABEL WA RNINGS MUST BE OSBERVED UNTIL
CONTAINER HAS BEEN CLEANED, RECONDITIONED OR PROPERLY DISPOSED OF.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNLESS AIR MONITORING DEMONSTRATES VAPOR/MIST
LEVELS ABOVE APPLICABLE LIMITS, NO RESPIRATOR IS REQUIRED. IF
RESPIRATOR IS REQUIRED, THE APPROPRIATE, PROPERLY FITTED RESPIRATOR
(NIOSH APPROVED) SHOULD BE WORN DURING APPLICATION. FOLLOW
RESPIRATOR MANUFACTURERS DIRECTIONS FOR RESPIRATOR USE.
Ventilation:REQUIRED WHEN SPRAYING OR APPLYING IN CONFINED AREA.
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . USUAL CLOTHING FOR PAINTING OPERATIONS.
Supplemental Safety and Health
FL PT: 200F,93.3C WILL NOT SUSTAIN COMBUSTION. THEORETICAL VOC: 2.60
LBS/GALLON. THEORETICAL VOC: 311 GRAMS/LITER.
================== Physical/Chemical Properties ==================
Boiling Pt:=100.C, 212.F
Vapor Pres:24 @ 77F,25C
Vapor Density:7.4(AIR=1)
Spec Gravity:1.02
VOC Pounds/Gallon:311
VOC Grams/Liter:2.6
Evaporation Rate & Reference:0.4 (BUTYL ACETATE =1)
Solubility in Water:YES
Appearance and Odor:NORMAL FOR A COATINGS PRODUCT.
Percent Volatiles by Volume:81.26
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID WATER-REACTIVE MATERIALS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON DIOXIDE/MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN CHEMICAL DISPOSAL AREA OR IN A MANNER
THAT COMPLIES WITH LOCAL, STATE, PROVINCIAL AND FEDERAL
REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
===================== Regulatory Information =====================
SARA Title III Information:THERE ARE NO SARA 313 CHEMICALS IN THIS
PRODUCT.
Federal Regulatory Information:ALL COMPONENTS OF THIS PRODUCT ARE IN
COMPLIANCE WITH U.S. TSCA CHEMICAL SUBSTANCE INVENTORY
REQUIREMENTS. NO HAZARDOUS CHEMICALS PRESENT.
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DELLNER SKP, AIRFLEX PRODUCT MODEL
Preparer's Name:PAUL SHOWALTER
CAGE:13654
CAGE:13654
============= Composition/Information on Ingredients =============
Ingred Name:NON HAZARDOUS INGREDIENTS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES AND/OR RESPIRATORY
SYSTEM. WHILE THIS MATERIAL PRESENTS NO SIGNIFICANT HEALTH HAZARDS
DURING NORMAL STORAGE, HANDLING AND USE, EXPOSURE TO DUST OR FUMES
FROM THIS MATERIAL CAN BE A HEALTH HAZARD.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:RESPIRATORY PROBLEMS IN GENERAL AND
DERMATITIS.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE VICTIM TO FRESH AIR, OBTAIN MED ATTN. EYES:
FLUSH WITH WATER TO REMOVE PARTICULATE, OBTAIN MED ATTN. SKIN: WASH
THOROUGHLY W/SOAP AND WATER. IF IRRITATION DEVELOPS, OBTAIN MEDICAL
ATTN. INGEST: OBTAIN MEDICAL ATTENTION IF QTYS ARE INGESTED.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DUST MAY PRESENT AN EXPLOSION HAZARD IF
FINELY DIVIDED, DISPERSED IN AIR, AND EXPOSED TO A SOURCE OF
IGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:ANY RELEASE OR SPILL WHICH MAY INVOLVE DUST
SHOULD BE VACUUMED OR WET-SWEPT TO AVOID GENERATING AIRBORNE DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTACT WITH INCOMPATIBLE MATERIALS
SHOULD BE AVOIDED AS STATED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR IF EXPOSURE
TO DUST OR FUME IS POSSIBLE.
Ventilation:LOCAL &/GENERAL EXHAUST SHOULD BE USED TO KEEP AIRBORNE
CONTAMINANTS BELOW TLVS.
Other Protective Equipment:BARRIER CREAMS TO PREVENT DERMATITIS.
Work Hygienic Practices:GOOD HOUSEKEEPING PRACTICES SHOULD BE OBSERVED
TO PREVENT ANY ACCUMULATIONS OF DUST.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:FOLLOW LOCAL, STATE AND FEDERAL REGULATIONS FOR
DISP OF SOLID, ENCAPSULATED OR POWDERED WASTE CONTAINING SPECIFIED
HAZARDOUS INGREDIENTS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:876 0506, KODAK PROFESSIONAL DEV REPL CONCENTRATE MX 1613
Kit Part:Y
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:HYDROQUINONE (SARA 302/313) (CERCLA)
CAS:123-31-9
RTECS #:MX3500000
Fraction by Wt: 8%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9596
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:POTASSIUM CARBONATE
CAS:584-08-7
RTECS #:TS7750000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POTASSIUM CHLORIDE
CAS:7447-40-7
RTECS #:TS8050000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 50-55%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POTASSIUM SULFITE
CAS:10117-38-1
RTECS #:WT3530000
Fraction by Wt: 20-25%
Other REC Limits:NONE RECOMMENDED
Ingred Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 10%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV: HYDROQUINONE: 2 MG/M3 TWA
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW
HAZARD FOR RECOMMENDED HANDLING. SKIN: CAUSES IRRITATION.
INGESTION: HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:EYES-CAUSES BURNS. INGESTION-MAY CAUSE BURNS OF
THE GASTROINTESTINAL TRACT IF SWALLOWED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION-MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF
SYMPTOMS OCCUR. EYES-IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT
LEAST 15 MIN. GET MEDICAL ATTENTION. SKIN-IMMEDIATELY REMOVE
CONTAMINATED CLOT HING/SHOES & WASH WITH SOAP & PLENTY OFWATER. GET
MEDCIAL ATTENTION. INGESTED-DO NOT INDUCE VOMITING. GIVE VICTIM A
GLASS OF WATER. CALL A PHYSICIAN OR POISON CONTROL CENTER
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND
POSSIBILITY OF A SK IN REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
WEAR PROTECTIVE CLOTHING APPROPIATE FOR THE RISK OF EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
DANGER! CONTAINS: HYDROQUINONE.
================== Physical/Chemical Properties ==================
HCC:B3
Spec Gravity:1.34
pH:11.8
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID. YELLOW. ODORLESS.
Percent Volatiles by Volume:50-55
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF SULFUR.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ELECTRON VACUUM TUBES,7233
CAGE:KO050
CAGE:KO050
CAGE:33173
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS/COMPONENTS
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT RELEVANT
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE AND CHRONIC- ELECTRON TUBES
OPERATE AT TEMPERATURES THAT CAN PRODUCE BURNS TO SKIN IF CONTACT
IS MADE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:MINOR SKIN BURNS
======================= First Aid Measures =======================
First Aid:NO EMERGENCY CARE ANTICIPATED.
===================== Fire Fighting Measures =====================
Flash Point:NOT RELEVANT
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
================== Accidental Release Measures ==================
Spill Release Procedures:IF BROKEN, COLLECT AND TRANSFER TO PROPER
CONTAINER FOR DISPOSAL.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE WITH CARE.
Other Precautions:INTERNAL HEATER WIRE FILAMENTS IS NOMINALLY 2%
RHENIUM 187 (SPECIFIC ACTIVITY 0.00445 MICROCURIE/G). CALCULATED
SPECIFIC ACTIVITY OF FILAMENT IS 0.000089 MICROCURIE/G.
MIL-HBDK-600 SPECIFIES >0.002 MI CROCURIE/G IS RADIO ACTIVE.
NON-HZARDOUS
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE
Ventilation:NONE
Other Protective Equipment:NONE
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Decomp Temp:Decomp Text:NOT KNOWN
Spec Gravity:NOT RELEVANT
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVANT
Appearance and Odor:PRODUCT IS AN ARTICLE (ELECTRON TUBE).
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CHLORHEXIDINE GLUCONATE SOLUTION 4% (W/W) TF8666D
CAGE:NO652
CAGE:0AWE2
CAGE:NO652
============= Composition/Information on Ingredients =============
Ingred Name:PARA-CHLOROANILINE (PCA)
Fraction by Wt: NA
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:500 PPM
Ingred Name:CHLORHEXIDINE
CAS:18472-51-0
RTECS #:DU1950000
Other REC Limits:NONE RECOMMENDED
Ingred Name:ISOPROPYL ALCOHOL (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 4.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50: 1.8G/KG (RAT)
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: FLUSH W/WATER. HAZARDOUS TO
MIDDLE EAR, PERFORATION OF EARDRUM.
Effects of Overexposure:SKIN AND EYE IRRITATION.
Medical Cond Aggravated by Exposure:DERMATITIS
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER EYES/EARS AT LEAST 15MINUTES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:125F,52C
Extinguishing Media:FOAM, DRY CHEMICAL, CO2, WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APROVED SCBA. COOL FIRE EXPOSED
CONTAINERS W/WATER SPRAY.
Unusual Fire/Explosion Hazard:MAY PRODUCE TOXIC FUMES OF AMMONIA,
HYDROGEN CHLORIDE, OXIDES OF CARBON AND NITROGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH W/WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:DONT SPILL ON SKIN OR INTO EYES/EARS.
Other Precautions:HANDLE W/CARE. IN CASE OF CONTACT W/EYES FLUSH
W/PLENTY OF WATER. IF IRRITATION PERSISTS, GET MED AID.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NA
Ventilation:LOCAL EXHAUST
Other Protective Equipment:NONE NEEDED
Work Hygienic Practices:HANDLE W/CARE.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:206F,97C
Melt/Freeze Pt:M.P/F.P Text:NA-LIQUID
Decomp Temp:Decomp Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:1.06
pH:NA
Evaporation Rate & Reference: SAME AS WATER
Solubility in Water:SOLUBLE
Appearance and Odor:ALMOST COLORLESS OR PALE STRAW COLOR.
Percent Volatiles by Volume:NA
Corrosion Rate:NA
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NA
Stability Condition to Avoid:STORAGE >37C
Hazardous Decomposition Products:PCA
Conditions to Avoid Polymerization:STORAGE IN EXCESS HEAT 37C 104F OVER
LONG PERIOD OF TIME.
==================== Disposal Considerations ====================
Waste Disposal Methods:FLUSH W/WATER. DISPOSE OF IN ACCORDANCE
W/FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:20804-1251 SMDC SHIELDED MILD DETONATING CORD
Preparer's Name:S SCHOOLFIELD/J KOHRING
CAGE:17610
CAGE:17610
============= Composition/Information on Ingredients =============
Ingred Name:X-CHORD, 2.5 GRAINS/FT, SILVER SHEATH
ACGIH TLV:0.1 MG/CUM
Ingred Name:HEXANITROSTILBENE I
ACGIH TLV:10.0 MG/CUM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION TO THE NOSE,
THROAT & MUCOUS MEMBRANE, ALLERGIC REACTIONS. SKIN: IRRITATION &
ABSORPTION, ALLERGIC REACTIONS. EYES: IRRITATION. INGESTION: TOXIC,
MAY CAUSE DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, REDNESS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER.
INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Fire Fighting Procedures:DON'T ATTEMPT TO EXTINGUISH. EVACUATE AREA.
USE SCBA TO CONTAIN RESULTING FIRE.
Unusual Fire/Explosion Hazard:IF EXPOSED TO FIRE, THE UNIT MAY
ACTUATE/EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:CALL LOCAL HAZARDOUS MATERIALS TEAM. REMOVE
IGNITION SOURCES. COVER ANY EXPOSED MATERIAL W/VEGETABLE OIL &
REMOVE FOR APPROVED DISPOSAL. USE FLAME RETARDANT CLOTHING, SAFETY
GLASSES & NON-SPARKING TOO LS.
======================Handling and Storage ======================
Handling and Storage Precautions:ANTI-STATIC ARE TO BE USED FOR STORAGE
& SHIPPING.
Other Precautions:THIS MSDS ISN'T INTENDED TO BE AN ORDNANCE HANDLING
DOCUMENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE A NIOSH APPROVED HEPA RESPIRATOR IF PEL/TLV
IS EXCEEDED.
Ventilation:LOCAL EXHAUST: REQUIRED FOR TEST FIRING.
Other Protective Equipment:FLAME RETARDANT COAT & GROUNDING STRAPS TO
PREVENT ELECTROSTATIC DISCHARGE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:INSOLUBLE
Appearance and Odor:SMDC: SILVER; ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIS, ACIDS, BRONZE, CORROSIVES & OXIDIZERS.
Stability Condition to Avoid:MECHANICAL SHOCK, STATIC ELECTRICITY,
HEAT, FLAME/SPARKS.
Hazardous Decomposition Products:CO, NITROGEN, NITROUS OXIDES,
HYDROGEN, CARBON, CO2 & WATER.
==================== Disposal Considerations ====================
Waste Disposal Methods:UNFIRED UNITS/WASTE SHOULD BE DISPOSED AS
REACTIVE (D003) & TOXIC (D011) HAZARDOUS WASTE, IAW/FEDERAL, STATE
& LOCAL REGULATIONS. UN-0367.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:MARQUISE
CAGE:89044
CAGE:89044
============= Composition/Information on Ingredients =============
Ingred Name:CONTAINS NO COMPONENTS CONSIDERED HAZARDOUS PER 29 CFR
1910.1200. CONTAINS 4% GLYCOL ETHERS FOR SARA 313 REPORTING.
Fraction by Wt: NA
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: MAY CAUSE IRRITATION. IF
SWALLOWED MAY CAUSE STOMACH DISTRESS, NAUSEA, VOMITING.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH IMMEDIATELY W/PLENTY OF COOL RUNNING WATER.
REMOVE CONTACTS & FLUSH AGAIN. SKIN: FLUSH W/WATER, THEN WASH
W/SOAP & WATER. INGESTION: RINSE MOUTH, THEN DRINK 1-2 GLASSES OF
WATER. DO NOT IN DUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH TO
UNCONSCIOUS PERSON. IF IRRITATION OR DISCOMFORT PERSISTS, CALL DR.
===================== Fire Fighting Measures =====================
Extinguishing Media:PRODUCT DOES NOT SUPPORT COMBUSTION.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE OR DAM LARGE SPILLS. PUMP TO CONTAINERS
OR SOAK UP ON INERT ABSORBENT. FLUSH RESIDUE TO SANITARY SEWER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM FREEZING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO REQUIREMENTS BEYOND STANDARD INDUSTRIAL
HYGIENE PRACTICES
Ventilation:NO REQUIREMENTS BEYOND STANDARD INDUSTRIAL HYGIENE
PRACTICES.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Spec Gravity:1.0
pH:9.0
Solubility in Water:EMULSION
Appearance and Odor:LIGHT TAN OPAQUE LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NK
Stability Condition to Avoid:DO NOT MIX W/ANYTHING BUT WATER.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT STATE & LOCAL AUTHORITIES FOR
RESTRICTIONS ON DISPOSAL OF CHEMICAL WASTE.
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:VINYL AQUA DECK
CAGE:OO295
CAGE:OO295
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ISOBUTYL KETONE (SARA III)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 13%
OSHA PEL:100 PPM/75 STEL
ACGIH TLV:50 PPM/75 STEL; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 70%
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:EYE/SKIN: IRRITATION. VAPORS: NARCOSIS.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH WATER 15 MINUTES,CONSULT PHSICIAN. SKIN: WASH
WITH SOAP & WATER. INHALATION: REMOVE TO FRESH AIR,GIVE ARTIF RESP
IF NEEDED,CONSULT PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:50F/10C(COC)
Extinguishing Media:DRY CHEMICAL,CO*2,FOAM.
Unusual Fire/Explosion Hazard:DANGEROUS WHEN EXPOSED TO HEAT OR FLAME.
REACTS WITH OXIDIZING MATERIALS.
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE IMMEDIATELY WITH ABSORBING MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED TO PREVENT
FOREIGN MATERIAL CONTAMINATION & EVAPORATION OF SOLVENT. STORE AWAY
FROM HEAT OR FLAME.
============= Exposure Controls/Personal Protection =============
Ventilation:MECHANICAL
Other Protective Equipment:AS NEEDED TO PREVENT SKIN CONTACT.
Supplemental Safety and Health
MFR ADDRESS: 1631 S. 10TH STREET,SAN JOSE,CALIF 95112
================== Physical/Chemical Properties ==================
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DEPENDENT ON PIGMENT,ACETONE LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS & REDUCING MATERIALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH LOCAL,STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:165K
CAGE:0FY61
CAGE:0FY61
============= Composition/Information on Ingredients =============
Ingred Name:OIL; (INERT OIL). BP:>300F,>149C. FL PT:>610F,>321C.
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SURFACTANT. VAP DENS:21.
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ETHYLENE, TETRAFLUORO-, POLYMER; (PTFE)
CAS:116-14-3
RTECS #:KX4025000
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NOT CONSIDERED A HAZARDOUS MATERIAL.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH
W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM
MD. SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD .
===================== Fire Fighting Measures =====================
Flash Point:>610F,>321C
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:PTFE WILL BURN WHEN IGNITED IN 100%
OXYGEN.
================== Accidental Release Measures ==================
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:IN CASE IT IS IN A FIRE, AVOID
BREATHING AIR.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:MECHANICAL (GENERAL) VENTILATION.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS W/SOAP & WATER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SEE INGS
Melt/Freeze Pt:M.P/F.P Text:<34F,<1C
Vapor Pres:<5
Vapor Density:SEE INGS
Spec Gravity:1.2 (H*2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:NIL
Appearance and Odor:BLACK FIBER OR BLACK & YELLOW FIBER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT COMPATIBLE W/MOLTEN ALKALI METALS, ELEMENTAL FLUORINE & SOME
INTERHALOGENS.
Stability Condition to Avoid:ELEVATED TEMPERATURES & INCINERATIONS.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . DISPOSE BY BURIAL METHODS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:06-985 SONOPRIME ACTIVATOR
Preparer's Name:CATHY GRIFFITH
CAGE:GO273
CAGE:63472
CAGE:GO273
============= Composition/Information on Ingredients =============
Ingred Name:ETHYLENE GLYCOL PROPYL ETHER, EKTASOLVE EP
CAS:2807-30-9
RTECS #:KM2800000
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITANT & REVERSIBLE CORNEAL
INJURY. SKIN: IRRITANT, DERMATITIS, & SENSITIZATION. INHALATION:
RESPIRATORY TRACT IRRITATION. CHRONIC: XYLENE MAY CAUSE INJURY TO
KIDNEYS, CNS, OR FORMED ELEMENTS OF THE BLOOD. REPEATED/PROLONGED
OVEREXPOSURE TO SOLVENTS MAY CAUSE INJURY TO KIDNEYS, LIVER OR CNS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: ALLERGIC RESPONSES. INHALATION: HEADACHE
& DIZZINESS. INGESTION: NAUSEA & VOMITING. ASPIRATION INTO LUNGS
MAY CAUSE CHEMICAL PNEUMONITIS.
Medical Cond Aggravated by Exposure:PULMONARY & DERMATOLOGICAL
DISORDERS
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. SKIN:
REMOVE CONTAMINATED CLOTHING. WASH W/SOAP & WATER. INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF
BREATHING STOPS , ADMINISTER ARTIFICIAL RESPIRATION. INGESTION:
DON'T INDUCE VOMITING. GIVE WATER/MILK IF CONSCIOUS & NOT DROWSY.
IF VOMITING OCCURS, KEEP HEAD BELOW HIPS. OBTAIN MEDICAL ATTENTION
IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:200F
Lower Limits:1.3%
Upper Limits:15.85
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING. USE WATER TO
COOL FIRE EXPOSED CONTAINERS. WATER STREAM DIRECTED INTO FIRE MAY
CAUSE FROTHING & SPREAD OF FIRE.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY RUPTURE OR EXPLODE
DUE TO PRESSURE BUILD-UP WHEN EXPOSED TO EXTREME HEAT. COMBUSTIBLE
LIQUID.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT.
CONTAIN & ABSORB W/INERT MATERIAL SUCH AS VERMICULITE. PLACE INTO
CONTAINER W/LIDS. COVER LOOSELY & REMOVE TO APPROPRIATE WASTE AREA.
WASH AREA. PREVENT WASH INGS FROM ENTERING WATERWAYS.
======================Handling and Storage ======================
Handling and Storage Precautions:TIGHTLY RESEAL ALL PARTIALLY USED
CONTAINERS. USE ONLY W/ADEQUATE VENTILATION. KEEP USED & UNUSED
CONTAINER OUT OF REACH OF CHILDREN.
Other Precautions:FOR PROFESSIONAL USE ONLY. DON'T TAKE INTERNALLY.
AVOID CONTACT W/EYES, SKIN & CLOTHING. AVOID BREATHING
VAPOR/DUST/MIST. DON'T REUSE EMPTY CONTAINER WITHOUT COMMERCIAL
CLEAN OR RECONDITION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED, USE NIOSH APPROVED ORGANIC
VAPOR CARTRIDGE RESPIRATOR.
Ventilation:LOCAL EXHAUST TO CONTROL VAPOR/DUST LEVELS BELOW
RECOMMENDED LEVELS
Other Protective Equipment:EYE WASH & SAFETY SHOWER, CLEAN PROTECTIVE
CLOTHING
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Vapor Pres:1.3
Vapor Density:<1
Spec Gravity:1.03
pH:>7
Evaporation Rate & Reference:(N-BU AC = 1): <1
Solubility in Water:APPRECIABLE
Appearance and Odor:CLEAR LIQUID W/MILD ODOR
Percent Volatiles by Volume:19.73
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES OR OXIDANTS. STRONG LEWIS OR MINERAL ACIDS.
Hazardous Decomposition Products:ACRID FUMES, OXIDES OF CARBON,
ALDEHYDES & ACIDS, PHENOLS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CLEOCIN PHOSPHATE STERILE SOLUTION
CAGE:93703
CAGE:93703
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 84%
Other REC Limits:NONE RECOMMENDED
Ingred Name:NON-HAZARDOUS INGREDIENTS
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:CLINDAMYCIN-2-PHOSPHATE
CAS:24729-96-2
RTECS #:GF2625000
Fraction by Wt: 15%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 1,832 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE GASTROINTESTINAL EFFECTS.
IN ADDITION, PSEUDOMEMBRANOUS COLITIS AND ESOPHAGITIS HAVE
OCCURRED. SEVERE COLITIS MAY BE FATAL. ABNORMALITIES IN LIVER
FUNCTION TESTS AND RENAL DYSFUNCTION. R ARE CASES OF POLYARTHRITIS
HAVE BEEN REPORTED WITH THE USE OF CLINDAMYCIN PHOSPHATE.
IRRITATION TO EYES AND SKIN.
Effects of Overexposure:NAUSEA, VOMITING, DIARRHEA, ABDOMINAL PAIN,
PASSAGE OF MUCOUS AND BLOOD IN THE STOOLS.HYPERSENSITIVITY
REACTIONS SUCH AS SKIN RASH, REDNESS AND ITCHING. SORE THROAT AND
FEVER. UNUSUAL BLEEDING OR BRUISING; JAUNDICE.
Medical Cond Aggravated by Exposure:HISTORY OF HYPERSENSITIVITY TO
CLINDAMYCIN, LINCOMYCIN OR OTHER RELATED FAMILIES OF ANTIBIOTICS, A
HISTORY OF REGIONAL ENTERITIS OR ULCERATIVE COLITIS. PRE-EXISTING
SKIN, EYE, LIVER OR KIDNEY PROBLEMS
======================= First Aid Measures =======================
First Aid:EYES- FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN TO
ASSURE COMPLETE CONTACT WITH WATER. SKIN- WASH WITH SOAP AND
WATER. REMOVE CONTAMINATED CLOTHING. INHALATION- REMOVE FROM
EXPOSURE. INGES TION- CONTACT A PHYSICIAN OR POISON CONTROL
CENTER.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, WATER.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL-BODY PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:PROVIDE VENTILATION & RESPIRATORY, SKIN & EYE
PROTECTION. KEEP OUT OF DRAINS; PREVENT ENTRY TO SURFACE WATER,
GROUNDWATER & SOIL. SMALL AMOUNTS OF THE PRODUCT CAN BE DILUTED
WITH ALCOHOL AND WIPED UP WITH PAPER TOWEL. LARGE SPILLS:
VACUUM/ABSORB.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. WASH THROUGHLY AFTER HANDLING. LAUNDER CONTAMINATED
CLOTHES BEFORE REUSE. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:STORE IN A COOL, DRY PLACE AND PROTECT FROM LIGHT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:LOCAL EXHAUST
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING THIS
MATERIAL.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
Appearance and Odor:CLEAR LIQUID IN VIALS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
NITROGEN OXIDES, SULFUR OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF BY INCINERATION IN ACCORDANCE WITH
APPLICABLE INTERNATIONAL, NATIONAL, STATE AND/OR LOCAL WASTE
DISPOSAL REGULATIONS.
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:4674, POTASSIUM HYDROXIDE (10-45%) (SUPDAT)
CAGE:HO851
CAGE:HO851
CAGE:70829
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM HYDROXIDE (CERCLA). LD50: (ORAL, RAT) 273 MG/KG.
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 10-45%
OSHA PEL:2 MG/M3, C
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 55-90%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:EFTS OF OVEREXP: TO INCREASED SUSCEPTIBILITY TO RESP
ILLNESS. POTASSIUM HYDROXIDE: INVESTIGATED AS A MUTAGEN.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: OF WATER FOR AT LEAST 15 MINUTES, LIFTING
LOWER & UPPER EYELIDS OCCASIONALLY. GET MED ATTN IMMED.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: SAWDUST. DO NOT FLUSH TO SEWER! US REGS
(CERCLA) REQ REPORTING SPILLS & RELEASES TO SOIL, WATER & (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: AIR IN EXCESS OF REPORTABLE QTYS. TOLL FREE NUMBER
FOR US COAST GUARD NATIONAL RRESPONSE CENTER IS (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: 1-800-424-8802. JT BAKER NEUTRACIT(TM)-2 OR
BUCAIM(TM) CAUSTIC NEUTRALIZERS ARE RECOM FOR SPILLS OF THIS PROD.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH: DISP REQS. PROCESSING, USE OR CONTAM OF
PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: DISP REGS MAY DIFFER FROM FED DISP REGS. DISPOSE OF
CNTNR & UNUSED CONTENTS I/A/W FED, STATE & LOCAL REQS.
RTECS #:9999999ZZ
Ingred Name:RESP PROT: PIECE DUST/MIST RESP MAY BE WORN UP TO 50 TIMES
EXPOS LIMIT OR MAX USE CONC SPECIFIED BY APPROP (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10: REGULATORY AGENCY OR RESP SUPPLIER, WHICHEVER IS
LOWEST. FOR EMERGENCIES OR INSTANCES WHERE EXPOS (ING 12
RTECS #:9999999ZZ
Ingred Name:ING 11: LEVELS ARE NOT KNOWN, USE NIOSH APPRVD
FULL-FACEPIECE POSITIVE-PRESSURE, AIR-SUPPLIED RESP. WARNING: (ING
13)
RTECS #:9999999ZZ
Ingred Name:ING 12: PURIFYING RESPS DO NOT PROTECT WORKERS IN
OXYGEN-DEFICIENT ATMOSPHERES.
RTECS #:9999999ZZ
Ingred Name:VENT: GENERALLY PREFERRED BECAUSE IT CAN CTL EMISSIONS OF
CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT(ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: INTO THE GENERAL WORK AREA. PLEASE REFER TO ACGIH
DOCUMENT, INDUSTRIAL VENTILATION, A MANUAL OF (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15: RECOMMENDED PRACTICES, MOST RECENT EDITION, FOR
DETAILS.
RTECS #:9999999ZZ
Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: RESP TRACT IRRITANT, MAY CAUSE
SERIOUS BURNS ON ACUTE CNTCT. SEV INJURY IS USUALLY AVOIDED BY
SELF-LIMITING COUGH & SNEEZING SYMPS. INGEST: TOXIC! CORR TO MUC
MEMBS & MAY CAUSE PERFORATION OF E SOPHAGUS & STOMACH. ABDOM PAIN,
NAUS, VOMIT, GENERAL GI UPSET CAN BE EXPECTED. SKIN CNTCT:
IRRITANT, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: POSSIBLY CORR IF CNTCT IS PRLNGD.
SORENESS, REDNESS, DESTRUCTION OF SKIN MAY RSLT. EYE CNTCT:
IRRITANT, POSSIBLY CORR TO EYE TISSUES. TEARING, REDNESS, PAIN,
IMPAIRED VISION ARE SYMPS. CHRON IC: DEVELOPMENT OF DEFAT DERM ON
PRLNGDCNTCT W/POTASSIUM HYDROXIDE HAS BEEN REPORTED. CONTINUED
IRRIT MAY LEAD (ING 3)
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. INGEST: DO NOT INDUCE VOMIT.
GIVE LARGE QTYS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCON
PERSO N. CALL MD IMMED. SKIN: IN CASE OF CNTCT, IMMED FLUSH SKIN
W/PLENTY OF WATER FOR AT LST 15 MIN. REMOVE CONTAM CLTHG & SHOES.
WASH CLTHG BEFORE REUSE. CALL MD. EYES: IMMED FLUSH EYES W/PLENTY
(ING 4)
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE. AVOID DIRECT CONTACT OF LIQUID WITH WATER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE OR EXPLOSION
HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENT AREA OF LEAK OR SPILL. WEAR APPROP
PERSONAL PROT EQUIP. CONTAIN & RECOVER LIQ WHEN POSS. COLLECT LIQ
IN APPROP CNTNR OR ABSORB W/INERT MATL (EG VERMICULITE, DRY SAND,
EARTH) & PLACE IN CHEM WASTE CNTNR. DO NOT USE COMBUST MATLS SUCH
AS (ING 5)
Neutralizing Agent:JT BAKER NEUTRACIT(TM)-2 OR BUCAIM(TM) CAUSTIC
NEUTRALIZERS.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER.
STORE IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. SEPARATE FROM ACIDS AND ALKALIS.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (VAPORS, LIQUID); OBSERVE
ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, NIOSH APPRVD
HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO TEN TIMES EXPOS
LIMIT OR MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY OR RESP
SUPPLIER, WHICHEVER IS LOWES T. NIOSH APPROVD FULL-FACE (ING 10)
Ventilation:SYS OF LOC &/OR GEN EXHST IS RECOM TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS (ING 14)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
IMPERVIOUS PROT CLTHG INCL BOOTS, LAB COAT, APRON/COVERALLS AS
APPROP.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: SOLUTIONS AND CONCENTRATES. BP: 10% SOLUTION:
213F,101C TO 45% SOLUTION: 270F,132C. SPEC GRAV: 10% SOLUTION: 1.1
TO 45% SOLUTION: 1.45. VP: 10% SOLUTION: N/K TO 45% SOLUTION: 2 @
20C. MP: 10% SOLUTION: 27F,-3C TO45% SOLUTION: 84F,-29C. PH: 13.5
(0.1 MOLAR SOLUTION). % VOLAT: 90 (AS WATER).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SUPDAT
Melt/Freeze Pt:M.P/F.P Text:SUPDAT
Vapor Pres:SUPDAT
Spec Gravity:SUPDAT
pH:SUPDAT
Solubility in Water:COMPLETELY SOLUBLE
Appearance and Odor:CLEAR, COLORLESS SOLUTION; ODORLESS.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALUMINUM, TIN, ZINC, CHLORINATED HYDROCARBONS, ACETONE.
Stability Condition to Avoid:HEAT, INCOMPATIBLES.
Hazardous Decomposition Products:POTASSIUM OXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY OR
RECYCLING SHOULD BE MANAGED IN APPROP & APPRVD WASTE FACILITY.
ALTHOUGH NOT LISTED RCRA HAZ WASTE, THIS MATL MAY EXHIBIT ONE/MORE
CHARACTS OF HAZ WASTE & REQ A PPROP ANALYSIS TO DETERMINE SPECIFIC
(ING 8)
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:BLEND 9429 CP-15
CAGE:2T409
CAGE:2T409
============= Composition/Information on Ingredients =============
Ingred Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 50%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 18%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM;250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VM & P NAPHTHA; (LIGHT ALIPHATIC SOLVENT NAPHTHA)
CAS:64742-89-8
OSHA PEL:500 PPM (MFR)
ACGIH TLV:300 PPM (MFR)
Ingred Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM;1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: <3%
OSHA PEL:50 PPM, S
ACGIH TLV:25 PPM, S
Ingred Name:BENZENE; (BENZENE, CUMENE)(SARA 313) (CERCLA)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: <0.1%
OSHA PEL:SEE 1910.1028
ACGIH TLV:10 PPM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:ING 7:(NONEXEMPT (CVOC)):85.5%, 707.2 G/L, 5.89 LBS/GAL.
(NONEXEMPT PARTIAL PRESS (@ 20C)):48.4.
RTECS #:9999999ZZ
Ingred Name:SUPDAT:CNTNS BENZENE & TOLUENE, KNOWN TO STATE OF
CALIFORNIA TO CAUSE CANCER & REPRO TOX. NOTE:TOLUENE APPEARS (ING
10)
RTECS #:9999999ZZ
Ingred Name:ING 9:ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK
CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST (ING
11)
RTECS #:9999999ZZ
Ingred Name:ING 10:HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . ANIMAL
STUDIES CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS &
LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER(ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:(EGBE). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION
NO.90-118) .
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:VOMIT HAS BEEN INDUCED, GIVE 2 TEASPOONFULS
OF BAKING SODA IN GLASS OF WATER. CALL MD. NEVER GIVE(ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:ANYTHING BY MOUTH TO UNCON PERS. HAVE PATIENT LIE
DOWN & KEEP WARM. COVER EYES TO EXCLUDE LIGHT.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:TURN OFF HEATERS, ELEC EQUIP & OTHER IGNIT
SOURCES DURING USE & UNTIL ALL VAPS ARE GONE. DO NOT STORE(ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16:>49C(120F). STORE LG AMTS IN STRUCTURES MADE FOR
OSHA CLASS IB LIQS. KEEP CNTNR TIGHTLY CLSD & UPRIGHT (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:WHEN NOT IN USE TO PREVENT LEAKAGE. READ THIS MSDS
BEFORE HANDLING & DISPOSING OF THIS PRODUCT.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:SKIN CONT:PRIMARY IRRIT, DEFAT,
DERM. ABSORP INCRS EXPOS. EYE CONT:PRIMARY IRRIT, REDNESS, TEARING,
BLURRED VISION. LIQ CAN CAUSE IRRIT. INHAL:ANESTH. IRRITS RESP
TRACT. OVEREXP CAN CAUSE SERIOU S NERV SYS DEPRESS. VAP HARMFUL.
BRTHG VAP CAN CAUSE IRRIT. RPTD EXPOS OVER TLV CAN CAUSE BLINDNESS.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INGEST:CAN BE FATAL/CAUSE BLINDNESS.
CANNOT BE MADE NON-POIS. POISON! CAN CAUSE IRREVERSIBLE NERV SYS
DMG & DEATH. HARMFUL/FATAL. CAN CAUSE ABDOM IRRIT, NAUS, VOMIT &
DIARR. CHRONIC:OVEREXP C AN CAUSE DMG TO KIDNEYS, BLOOD,
NERVES,LIVER & LUNGS. BENZENE:ABSORPTION THRU SKIN MAY BE HARMFUL.
STUDIES W/ (SUPDAT)
Medical Cond Aggravated by Exposure:PERSONS W/SEVERE SKIN, LIVER OR
KIDNEY PROBLEMS SHOULD AVOID USE.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS & GET MED
ATTN. SKIN:IMMED REMOVE & CONTAM CLTHG. WASH THORO W/SOAP & WATER.
WASH CONTAM CLTHG BEFORE REUSE. (DISCARD CONTAM SHOES).
INHAL:REMOVE TO FRE SH AIR. IF BRTHG IS DFCLT, GIVE OXYG. IF BRTHG
HAS STOPPED GIVE ARTF RESP. CALL MD IMMED! INGEST:INDUCE VOMIT
PROMPTLY USING MD'S INSTRUCTIONS/BY HAVING PATIENT STICK FINGER
DOWN THROAT. AFTER(ING 14)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:1F,-17C
Lower Limits:2.6%
Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE OR FOAM)
FOR CLASS IB LIQUID FIRES.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT ON FIRE BUT CAN PROT FIRE-FIGHTERS. USE
FOG NOZZS IF WATER IS USED.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. VAPS CAN CAUSE FLASH
FIRE. KEEP CNTNR TIGHTLY CLSD. ISOLATE FROM OXIDIZERS, HEAT, SPKS,
ELEC EQUIP & OPEN FLAME. CLSD CNTNRS MAY (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:STOP SPILL AT SOURCE. DIKE AREA & CONTAIN.
CLEAN UP REMAINDER W/ABSORBENT MATERIALS. MOP UP & DISPOSE OF.
PERSONS W/OUT PROPER PROTECTION SHOULD BE KEPT FROM AREA UNTIL
CLEANED UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:ISOLATE FROM OXIDIZERS, HEAT, SPKS,
ELEC EQUIP & OPEN FLAMES. USE ONLY W/ADEQ VENT. AVOID BRTHG
VAP/SPRAY MIST. DO NOT GET IN EYES, ON SKIN/CLTHG.
Other Precautions:AVOID FREE FALL OF LIQ. GROUND CNTNRS WHEN
TRANSFERRING. DO NOT FLAME CUT, SAW, DRILL, BRAZE/WELD. EMPTY CNTNR
VERY HAZ! CONTINUE ALL LBL PRECS! VAPS MAY IGNITE EXPLO & SPREAD
LONG DISTS. PVNT VAP BUI LDUP. PUT OUT PILOT LIGHTS & (ING 16)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF OVER TLV, I/A/W 29 CFR 1910.134, USE NIOSH
APPROVED POSITIVE PRESSURE SELF-CONTAINED BREATHING APPARATUS.
CONSULT SAFETY EQUIPMENT SUPPLIER.
Ventilation:VENT TO KEEP VAPS OF THIS MATL <50 PPM. USE EXPLO-PROOF
EQUIP. LOCAL EXHAUST:NECESSARY. MECHANICAL (GENERAL):ACCEPTABLE.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . CONSULT SAFETY EQUIP SUPPLIER. WEAR (SUPDAT)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. WASH CLOTHING
BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ:EXPLODE IF EXPOS TO EXTREME HEAT. APPLYING TO HOT SURFS REQS
SPECIAL PRECS. EMPTY CNTNR VERY HAZ! CONTINUE ALL LBL PRECS! EYE
PROT:& FULL LGTH FCSHLD . OTHER PROT EQUIP:APRON & FOOTWEA R
IMPERVIOUS TO THIS MATL. EFTS OF OVEREXP:LAB ANIMALS INDICATE THIS
PROD CAN CAUSE DMG TO FETUS. THIS PROD (ING 9)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>133F,>56C
Vapor Pres:77.5 @ 20C
Vapor Density:2.2
Spec Gravity:0.822 (H*2O=1)
VOC Pounds/Gallon:822
Solubility in Water:APPRECIABLE
Appearance and Odor:WATER-WHITE LIQUID; KETONE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ISOLATE FROM STRONG OXIDIZERS SUCH AS PERMANGANATES, CHROMATES &
PEROXIDES.
Stability Condition to Avoid:ISOLATE FROM HEAT, SPARKS, ELECTRIC
EQUIPMENT & OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE FROM
BURNING.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE OR DISPOSE OF OBSERVING LOCAL, STATE &
FEDERAL HEALTH, SAFETY & POLLUTION LAWS. IF QUESTIONS EXIST,
CONTACT APPROPRIATE AGENCIES.
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:UREA, PRILLED
Resp. Party Other MSDS Num.:17172939306 MCC MSDS NO: 040
CAGE:1G8T8
CAGE:1G8T8
Contract Num:SP0450-01M-D709
CAGE:0V485
============= Composition/Information on Ingredients =============
Ingred Name:UREA
CAS:57-13-6
RTECS #:YR6250000
Minumum % Wt:97.
Maxumum % Wt:99.
OSHA PEL:15 MG/M3
Ingred Name:BIURET
CAS:108-19-0
= Wt:1.5
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
= Wt:.4
Ingred Name:AMMONIA, FREE
CAS:7664-41-7
RTECS #:BO0875000
Fraction by Wt: 130% PPM
OSHA PEL:35 MG/M3
ACGIH TLV:17 MG/M3;25 PPM
ACGIH STEL:24 MG/M3;35 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:METHYLENEDIUREA
= Wt:.7
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL - DOMESTIC ANIMAL LDLO: 511 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: UREA IS A DIURETIC AT THE RATE
OF 0.35 TO 1.49 KG/DAY. A SINGLE DOES OF 100 GRAMS OF UREA HAS
REPORTEDLY CAUSED MILD CENTRAL NERVOUS SYSTEM DEPRESSION SUCH AS
DROWSINESS, SLOW REFLEXES, AND SLU RRED SPEECH. CHRONIC: NONE
KNOWN.
Effects of Overexposure:EYES: WILL PRODUCE PAIN AND IRRITATION. SKIN:
REPEATED OR PROLONGED CONTACT MAY CAUSE SKIN IRRITATION.
INHALATION: NO INCIDENTS OF DUST INHALATION HEALTH EFFECTS
REPORTED. INGESTION: UREA IS A DIURETI C AT THE RATE OF 0.35 TO
1.49 KG/DAY. A SINGLE DOSE OF 100 GRAMS OF UREA HAS REPORTEDLY
CAUSED MILD CENTRAL NERVOUS SYSTEM DEPRESSION SUCH AS DROWSINESS,
SLOW RELEXES, AND SLURRED SPEECH.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH LARGE QUANTITIES OF WATER FOR AT
LEAST 20 MINUTES. SEEK MEDICAL ATTENTION. SKIN: WASH THOROUGHLY
WITH WATER AND SOAP. INHALATION: REMOVE TO FRESH AIR. IF PERSON IS
NOT BRE ATHING ADMINISTER ARTIFICIAL RESPIRATION. SEEK MEDICAL
ATTENTION. INGESTION: IF SWALLOWED AND THE PERSON IS CONSCIOUS,
DILUTE STOMACH CONTENTS WITH WATER AND MAKE PERSON VOMIT. SEEK
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND APPROVED
SELF-CONTAINED BREATHING APPARATUS. CAUTION: WET UREA IS SLIPPERY.
Unusual Fire/Explosion Hazard:AT ELEVATED TEMPERATURES, UREA MAY
DECOMPOSE TO CYANURIC ACID, AMMONIA, BIURET AND NITROGEN OXIDES.
================== Accidental Release Measures ==================
Spill Release Procedures:PREVENT LARGE QUANTITIES FROM CONTACTING
VEGETATION OR WATERWAYS. KEEP ANIMALS AWAY FROM LARGE SPILLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE UREA WITH AMMONIUM
NITRATE AS THE MIXTURE ABSORBS MOISTURE QUICKLY, MAKING IT MUSHY
AND WET. KEEP DRY; WET UREA CAN CAUSE SLIPPERY CONDITIONS.
Other Precautions:CAUTION: THIS AND SIMILAR FERTILIZERS ARE HARMFUL IF
SWALLOWED AND MAY CAUSE BURNS. AVOID INHALATION AND CONTACT WITH
SKIN, EYES AND CLOTHING. KEEP OUT OF REACH OF CHILDREN. WASH
THOROUGHLY AFTER HAND LING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH APPROVED DUST RESPIRATOR SHALL BE USED
WHEN EXPOSURE EXCEEDS THE OSHA PEL OF 15 MG/M3 FOR NUISANCE DUST;
OR IF AMMONIA VAPORS EXCEED 35 PPM A FULL FACE GAS MASK WITH
AMMONIA CARTRIDGE SHALL BEUSED. OTHER: WASHING FACILITIES SHALL
BE AVAILABLE.
Ventilation:PROVIDE LOCAL OR GENERAL VENTILATION TO KEEP BELOW OSHA'S
PEL OF 15 MG/M3 FOR NUISANCE DUST AND 35 PPM FOR AMMONIA.
Other Protective Equipment:NONE NORMALLY REQUIRED. IF IRRITATION
Work Hygienic Practices:WASHING FACILITIES SHALL BE AVAILABLE.
Supplemental Safety and Health
PRODUCT NAME: UREA, PRILLED. CHEMICAL NAME: UREA, CARBAMIDE. FORMULA:
CO(NH2)2. CHEMICAL FAMILY: AMIDE. CAS NUMBER: 57-13-6. MCC MSDA NO:
040.
================== Physical/Chemical Properties ==================
HCC:T5
Boiling Pt:B.P. Text:DECOMPOSES AT 1 ATM.
Melt/Freeze Pt:=132.7C, 270.9F
Spec Gravity:1.335 20/4C
Appearance and Odor:WHITE, SOLID GRANULA PRILL OR POWDER. SLIGHT
AMMONIA ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH NANO2; P2C15: NITROSYL PARCHLORATE. MAY REACT WITH
NITRATES, ALKALIES, OXIDIZING AGENTS, HYPOCHLORIDES, ALDEHYDES,
INORGANIC ACIDS, OLEFINS, POLYMERIZABLE ESTERS. CORROSIVE TO COPPER
AND COPPER ALLOYS.
Stability Condition to Avoid:STABLE. HEATING ABOVE 132.7C (271F).
Hazardous Decomposition Products:ABOVE 132.7C (271F) UREA DECOMPOSES TO
BIURET, CYANURIC ACID AND NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL IMPACT: UREA IS A PLANT AND RUMINANT ANIMAL
FOOD. HOWEVER, LARGE SPILLS COULD POSSIBLY KILL VEGETATION OR CAUSE
ILLNESS IN ANIMALS. CONTAMINATION OF WATERWAYS MAY CAUSE FISH
KILLS.
=================== MSDS Transport Information ===================
Transport Information:THIS MATERIAL IS NOT CLASSIFIED AS A HAZARDOUS
MATERIAL BY THE DEPARTMENT OF TRANSPORTATION.
======================= Other Information =======================
======================================================================
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:MD-4L, COPYMIX FOR MINOLTA ELECTROGRAPHIC 1
CAGE:1EV20
CAGE:1EV20
============= Composition/Information on Ingredients =============
Ingred Name:ING 2: ALL OTHER CONTRS SHLD BE DISPOSED OF IN
ENVIRONMENTALLY SAFE MANNER & IN ACCORDANCE W/GOVERNMENTAL
REGULATIONS.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: EFTS IN MALE RATS. PROD HAS LOW ORDER OF
ACUTE ORAL/DERMAL TOXICITY, BUT MINUTE AMTS ASPIRATED (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: INTO LUNGS DURING INGEST MAY CAUSE MILD TO SEVERE
PULMONARY INJURY & POSSIBLY DEATH.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: DIKING/IMPOUNDING. ADVISE AUTH IF PROD HAS
ENTERED OR MAY ENTER SEWERS/WATERCOURSES/ EXTENSIVE LAND (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: AREAS. ASSURE CONFORMITY W/APPLIC GOVERN REGS.
CONTINUE TO OBSERVE PREC FOR VOLATILE, COMBUST VAPS FROM (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: ABSORBED MATL. FOR FURTHER INFO RELATIVE TO SPILLS
RSLTG FROM TRANSPORTATION INCIDENTS, REFER TO LATEST (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: DOT EMERGENCY RESPONSE GUIDEBOOK FOR HAZ MATLS
INCIDENTS, DOT P5800.3. DOT IDENTIFICATION NUMBER: UN1255.
RTECS #:9999999ZZ
Ingred Name:VENT: USE EXPLOSION-PROOF EQUIPMENT.
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT: AT END OF WORK PERIOD. PROD IS READILY
REMOVED FROM SKIN BY WATERLESS HAND CLEANERS FOLLOWED BY (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: WASHING THOROUGHLY WITH SOAP AND WATER.
RTECS #:9999999ZZ
Ingred Name:HYDROTREATED HEAVY NAPHTHA (PETROLEUM); (ISOPAR, CONSISTS
PREDOMINATLY OF C8-C14 ISOPARAFFINIC HYDROCARBONS)
CAS:64742-48-9
Fraction by Wt: 99.74%
Other REC Limits:300 PPM (MFR)
Ingred Name:SUPP DATA: EMPTY DRUMS SHLD BE COMPLETELY DRAINED/PROPERLY
BUNGED/PROMPLY RETURNED TO A DRUM RECONDITIONER. (ING 3)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL, RAT) >5 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HLTH STUDIES HAVE SHOWN THAT MANY
PETROLEUM HYDROCARBONS & SYNTH LUBRICANTS POSE POTNTL HUMAN HLTH
RISKS WHICH MAY VARY FROM PERSON TO PERSON. AS A PREC, EXPOS TO
LIQ/VAPS/MISTS/FUMES SHLD BE MINIMIZE D. HIGH VAP CONC (>APPROX
100PPM) ARE IRRIT TO EYES/RESP TRACT, MAY CAUSE HDACH/DIZZ, ARE
ANESTHETIC, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: AND MAY HAVE OTHER CNS EFTS.
PRLNG/RPTD SKIN CONT W/PROD TENDS TO REMOVE SKIN OILS POSSIBLY
LEADING TO IRRIT/DERMAT. MAY CAUSE EYE IRRITATION. LAB ANIMAL
STUDIES HAVE SHOWN THAT PRLNG/RPTD I NHAL EXPOS TO LIGHT HYDROCARB
VAPS IN THE SAME NAPHTHA BOILING RANGE AS THIS PROD CAN PRDCE
ADVERSE KIDNEY (ING 4)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/CLEAR WATER FOR A MINIMUM OF 15 MIN OR UNTIL
IRRIT SUBSIDES. IF IRRIT PERSISTS, CALL MD. SKIN: REMOVE ANY
CONTAMD CLTHG & WASH SKIN THOROUGHLY W/SOAP & WATER. INHAL: REMOVE
FROM EXPOS & CALL MD IMMED. IF BRTHG IS IRREGULAR ORHAS STOPPED,
START RESUSCITATION, ADMINISTER OXYGEN, IF AVAIL. INGEST: DO NOT
INDUCE VOMITING; CALL MD IMMED.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:100F,38C
Lower Limits:0.8%
Upper Limits:7%
Extinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEMICAL, C*O2 &
VAPORIZING LIQUID TYPE EXTINGUISHING AGENTS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER MAY BE INEFTIVE, BUT SHLD BE USED TO KEEP FIRE-EXPOSED
CONTRS COOL. IF LEAK/SPILL HAS (SUPP DATA)
Unusual Fire/Explosion Hazard:EMPTY CONTRS RETAIN RESIDUE (LIQ/VAP) &
CAN BE DANGEROUS. DO NOT PRESSURIZE/CUT/WELD/
BRAZE/SOLDER/DRILL/GRIND OR EXPOSE SUCH CONTRS TO HEAT/FLAME (SUPP
DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF & ELIM ALL IGNIT SOURCES. KEEP PEOPLE
AWAY. RECOVER FREE PROD. ADD SAND/EARTH/OTHER SUITABLE ABSORB TO
SPILL AREA. MINIMIZE BRTHG VAPS/SKIN CONT. VENT CONFINED SPACES.
OPEN ALL WINDOWS/DOORS. KEEP PROD OUT OF SEWERS/ WATERCOURSES BY
(ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP PROD AWAY FROM HEAT/SPARKS/PILOT
LIGHTS/ STATIC ELECTRICITY/OPEN FLAME. KEEP CONTRS/STORAGE CONTRS
CLOSED WHEN NOT IN USE.
Other Precautions:DO NOT STORE NEAR HEAT/SPARKS/FLAME OR STRONG
OXIDANTS. TO PVNT FIRE/EXPLOS RISK FROM STATIC ACCUM/DISCHARGE,
EFTIVELY GROUND PROD TRANSFER SYS I/A/W NFPA STD FOR PETROLEUM
PRODS. MINIMIZE BRTHG OF VA PS. AVOID PRLNG/RPTD CONT W/SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED SUPPLIED-AIR RESPIRATORY
PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:USE ONLY W/VENT SUFFICIENT TO PVNT EXCEEDING RECOMMENDED
EXPOSURE LIMIT/BUILDUP OF EXPLOSIVE CONC OF VAP IN AIR.(ING 10)
Other Protective Equipment:CHEMICAL-RESISTANT APRON/OTHER IMPERVIOUS
CLTHG TO AVOID CONTAM REGULAR CLTHG WHICH COULD RSLT IN PRLNG/RPTD
SKIN CONT.
Work Hygienic Practices:LAUNDER & DRY-CLEAN CONTAMD CLTHG/SHOES BEFORE
REUSE. CLEANSE SKIN THORO AFTER CONT, BEFORE BREAKS/MEALS, AND (ING
11)
Supplemental Safety and Health
FIRE FIGHT PROC: IGNITED, USE WATER SPRAY TO DISPERSE VAPS & TO PROT
MEN ATTEMPTING TO STOP A LEAK. WATER SPRAY MAY BE USED TO FLUSH
SPILLS AWAY FROM EXPOS. EXPLO HAZ: SPARKS OR OTHER SOURCES OF IGNIT
; THEY MAY EXPLODE & CAUSE INJURY/DEATH. DO NOT ATTEMPT TO CLEAN
SINCE RESIDUE IS DFCLT TO REMOVE. (ING 2)
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:>311F,>155C
Melt/Freeze Pt:M.P/F.P Text:<0F,<-18C
Vapor Pres:<10 @ 25C
Vapor Density:5
Spec Gravity:0.75
pH:NEUT
Evaporation Rate & Reference:0.3(BUAC=1)@1 ATM AND 25C
Solubility in Water:NEGLIGIBLE; <0.1%
Appearance and Odor:BLACK LIQUID, FAINT PETROLEUM HYDROCARBON ODOR.
Percent Volatiles by Volume:99.74
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONT W/STRONG OXIDANTS SUCH AS LIQUID CHLORINE, CONCENTRATED
OXYGEN, SODIUM HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:UNDER FIRE CNDTNS: FUMES, SMOKE,
CARBON MONOXIDE, ALDEHYDES & OTHER DECOMP PRODS, IN THE CASE OF
INCOMPLETE COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE, AND LOCAL
REGULATIONS .
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:KODAK DEKTOL DEVELOPER (SINGLE POWDER), CONCENTRATE
Kit Part:Y
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM CARBONATE
CAS:5968-11-6
Fraction by Wt: 50-55%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM SULFITE
CAS:7757-83-7
RTECS #:WE2150000
Fraction by Wt: 30-35%
Other REC Limits:NONE RECOMMENDED
Ingred Name:HYDROQUINONE
CAS:123-31-9
RTECS #:MX3500000
Fraction by Wt: 6%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:P-METHYLAMINOPHENOL SULFATE (METOL)
CAS:55-55-1
RTECS #:SL8650000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM HEXAMETAPHOSPHATE
CAS:10124-56-8
RTECS #:OY3675000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:POTASSIUM BROMIDE
CAS:7758-02-3
RTECS #:TS7650000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 0.5-5.0 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: AIRBORNE DUST IRRITATING.
MAY CAUSE IRRITATION TO THE MUCOUS MEMBRANES & UPPER RESPIRATORY
TRACT. EYES: CAUSES IRRITATION. AIRBORNE DUST IRRITATING. SKIN:
CAUSES IRRITATION. MAY CAUSE ALLE RGIC SKIN REACTION. INGESTION:
HARMFUL IF SWALLOWED.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION-MOVE TO FRESH AIR. TREAT AYMPTOMATICALLY. GET
MEDICAL ATTENTION IF SYMPTOMS OCCUR. EYES-IMMEDIATELY FLUSH WITH
PLENTY OF WATER FOR AT LEAST 15 MIN. GET MEDICAL ATTENTION.
SKIN-IMMEDIATELY F LUSH WITH PLENTY OF WATER & WASH WITH
ANON-ALKALINE SKIN CLEANER. GET MEDCIAL ATTENTION. INGESTED-INDUCE
VOMITING AS DIRECTED BY MEDICAL PERSONNEL. CALL A PHYSICIAN OR
POISON CONTROL CENTER QUICKLY.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, SWEEP UP AND PLACE IN A CONTAINER FOR CHEMICAL WASTE.
CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED. KEEP AWAY FROM
INCOMPATIBLE SUBSTANCES.
Other Precautions:AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN &
CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN.
Ventilation:GOOD GENERAL VENTILATION (10 AIR CHANGES PER HOUR) SHOULD
BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
Other Protective Equipment:EYE BATH, WASHING FACILITIES, SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
Vapor Pres:NEGLIGIBLE
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:APPRECIABLE
Appearance and Odor:SOLID, WHITE, ODORLESS.
Percent Volatiles by Volume:NEGLIE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
SULFUR DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:RX-500
CAGE:62522
CAGE:62522
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL-2-CYANOACRYLATE
CAS:7085-85-0
Other REC Limits:2-5 PPM
Ingred Name:POLYMETHYLMETHACRYLATE, METHYL METHACRYLATE POLYMER
CAS:9011-14-7
RTECS #:TR0400000
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RATS LD50 = 12.2 CC/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MUCOUS MEMBRANES W/SOME
COUGHING. EYES: IRRITATION, TEARING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: MUCOUS MEMBRANES W/SOME COUGHING.
EYES: IRRITATION, TEARING.
Medical Cond Aggravated by Exposure:SKIN, EYE & RESPIRATORY DISORDERS
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: FLUSH AREAS OF CONTACT
W/WATER. WIPE AWAY LIQUID ADHESIVE WHERE POSSIBLE W/RESIDUALS BEING
REJECTED BY SOAKING IN WATER. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:176F
Extinguishing Media:FLUSH W/LARGE AMOUNTS OF WATER OR DRY CHEMICAL
EXTINGUISHER.
Fire Fighting Procedures:FUMES MAY BE IRRITATING IF NOT BURNING &
WATER OR DRY CHEMICAL.
Unusual Fire/Explosion Hazard:NONE, COMBUSTIBLE REQUIRING THE ABOVE
PROCEDURES.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB W/PAPER TOWELS OR CLOTH; SWEEP INTO
TRAY FOR LIQUID TO BE REACTED W/WATER FOR SOLID WASTE TREATMENT.
AVOID OVER EXPOSURE TO FUMES W/LARGE SPILLS & POOR VENTILATION.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID MOISTURE, DIRECT UV-SUNLIGHT &
DON'T STORE >77F. KEEP CONTAINERS CLOSED TIGHTLY WHEN NOT IN USE.
IDEAL STORAGE IS AT 41-50F.
Other Precautions:AVOID BREATHING VAPOR, CONTACT W/EYES & SKIN. DON'T
STORE AT -5C WHICH FREEZES PRODUCT TO USELESS STATE. PRODUCT NOT
DAMAGED BY FREEZING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NORMALLY NOT NECESSARY, A NIOSH APPROVED ORGANIC
VAPOR CANISTER MAY BE USED.
Ventilation:MECHANICAL/LOCAL EXHAUST: LARGE QUANTITIES USED TO 2 PPM.
Other Protective Equipment:APRON PROTECTS CLOTHING FROM HARDENED GLUE,
SOAP & WATER HELPS REMOVE ADHESIVE FROM SKIN.
Supplemental Safety and Health
POLYMETHYLMETHACRYLATE IMPLANTED UNDER THE SKIN OF EXPERIMENTAL ANIMALS
CAUSED TUMORS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:149F
Vapor Pres:1
Spec Gravity:1.05
Solubility in Water:INSOLUBLE
Appearance and Odor:TRANSPARENT WATER-WHITE TO STRAW COLORED LIQUID
W/STIMULATIVE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOL, AMINES, ALKALINE MATERIALS & DIOXIDE.
Stability Condition to Avoid:HEAT >176, MOISTURE, ALKALINES,
UV-SUNLIGHT.
Hazardous Decomposition Products:CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE SOLID COMBUSTIBLE WASTE OR DUMP AS
CHEMICAL WASTE ACCORDING TO LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
=======================================================
Product ID: 23-216 DL PERMATEX FAST ORANGE SMOOTH LOTION HAND CLEANER
Cage: 08028
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: 08028
=======================================================
Contractor Summary
=======================================================
Cage: 08028
=======================================================
Ingredients
=======================================================
Cas: 7732-18-5
RTECS #: ZC0110000
% Wt: 75-85
------------------------------
Cas: 68647-72-3
% Wt: 10-15
------------------------------
Cas: 68154-97-2
% Wt: 5-10
------------------------------
Cas: 102-71-6
RTECS #: KL9275000
CHANGE (IC)
% Wt: 0.1-1
Other REC Limits: A2 CARCINOGEN
ACGIH TLV: 3.1 MG/CUM IC
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: ORAL LD50 (LAB ANIMAL): >5,000 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: NONE UNDER NORMAL CONDITIONS OF USE
Explanation Of Carcinogenicity: SEE INGREDIENTS
First Aid: INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR.
SKIN/EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. OBTAIN MEDICAL ATTENTION IN
ALL CASES.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: RINSE AWAY W/WATER OR WIPE UP W/TOWEL.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, & FEDERAL
REGULATIONS.
Handling And Storage Precautions: HAND CLEANER SHOULD BE STORED BETWEEN
40F-100F IN ORDER TO ENSURE LONG LIFE OF THE EMULSION.
Other Precautions: KEEP AWAY FROM CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point Text: 193F
Extinguishing Media: CO2, DRY CHEMICAL POWDER
=======================================================
Control Measures
=======================================================
Ventilation: SOME LOCAL MAY BE DESIRED FOR EXPOSURE IN CONFINED AREAS
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 0.97
PH: 5.5
Solubility in Water: COMPLETE
Appearance and Odor: WHITE VISCOUS LOTION W/ORANGE SCENT
Percent Volatiles by Volume: 10.2
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Hazardous Decomposition Products: IRRITATING ORGANIC VAPORS
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: 23-216 DL PERMATEX FAST ORANGE SMOOTH LOTION HAND CLEANER
Cage: 08028
Company Name: LOCTITE CORP AUTOMOTIVE AND CONSUMER GROUP
Street: 4450 CRANWOOD COURT
Zipcode: 44128-4004
Label Required IND: Y
Date Of Label Review: 01/20/1994
Status Code: C
Label Date: 01/20/1994
Origination Code: F
Signal Word: WARNING
Health Hazard: None
Contact Hazard: None
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: NONE UNDER NORMAL CONDITIONS OF USE. SUSPECTED
CARCINOGEN: TRIETHANOLAMINE. EYES: IRRITATION. INGESTION:
GASTROINTESTINAL IRRITATION & IRRITATION OF MOUTH & THROAT. SKIN:
IRRITATION . INHALATION: EXCESSIVE EXPOSURE MAY CAUSE RE
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:NITTY-GRITTY (6X1 GAL), K454
Preparer's Name:RICHARD STOLLEY
CAGE:KEMMF
CAGE:KEMMF
============= Composition/Information on Ingredients =============
Ingred Name:1-PROPANOL, 2-(2-(2-METHOXYPROPOXY) PROPOXY)-;
(TRIPROPYLENE GLYCOL METHYL ETHER)
CAS:10213-77-1
RTECS #:UB8050000
Ingred Name:STODDARD SOLVENT; (PARAFFINIC/NAPHTHENIC SOLVENT)
CAS:8052-41-3
RTECS #:WJ8925000
Other REC Limits:PEL:525 MG/M3 (MFR)
OSHA PEL:500 PPM
ACGIH TLV:100 PPM; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 3300 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:DIRECT CONTACT W/EYES MAY CAUSE
IRRITATION. CHRONIC:DIRECT CONTACT W/EYES FOR PROLONGED PERIOD OF
TIME WILL CAUSE IRRITATION & REDDENING.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL:NOT USUALLY A HAZARD, BUT GET TO FRESH AIR IF OVERCOME.
EYE:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL
ATTENTION IF ANY IRRITATION PERSISTS. SKIN:FLUSH W/COPIOUS AMOUNTS
OF WA TER. CALL MD. . INGEST:IF SWALLOWED, DRINK TWO GLASSES OF
WATER. SEE MD IF DISCOMFORT OCCURS.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
================== Accidental Release Measures ==================
Spill Release Procedures:FLOOD SURFACE W/PLENTY OF WATER & FLUSH DOWN
DRAIN.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE INDOOR/OUTDOOR AT STORAGE TEMP
OF 120F (MAX), 32F (MIN). STORE AT MODERATE TEMPERATURES.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL
BEFORE USING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . TYPICAL USE OF THIS PRODUCT DOES NOT
REQUIRE RESPIRATORY PROTECTION.
Ventilation:GENERAL EXHAUST IS ADEQUATE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:212F,100C
Spec Gravity:0.865 (H*2O=1)
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:VISCOUS, OPAQUE, LIGHT ORANGE; FLORAL ODOR.
Percent Volatiles by Volume:75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR OXIDANTS.
Hazardous Decomposition Products:OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W STATE, FEDERAL & LOCAL
REGULATIONS CONCERNING HEALTH POLLUTION.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:428 FIBERGLASS PANEL ADHESIVE
Preparer's Name:S ABDUL RAZZAK
CAGE:16522
CAGE:16522
============= Composition/Information on Ingredients =============
Ingred Name:UNSATURATED POLYESTER RESINS
CAS:26123-45-5
Fraction by Wt: >50%
Ingred Name:STYRENE, MONOMER (SARA III)
CAS:100-42-5
RTECS #:WL3675000
Fraction by Wt: <20%
OSHA PEL:100 PPM
ACGIH TLV:S,50PPM/100STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TALC (CONTAINING NO ASBESTOS)
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: <50%
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST; 9192
Ingred Name:FIBROUS GLASS
CAS:65997-17-3
OSHA PEL:15 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)
Ingred Name:MUSCOVITE;(SILICEOUS MICA)
CAS:1318-94-1
OSHA PEL:3 MG/M3 RDUST
ACGIH TLV:3 MG/M3 RDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE AND UPPER RESPIRATORY
IRRITATION FROM VAPOR INHALATION. MINOR SKIN IRRITATION FROM
CONTACT WITH MATERIAL. CHRONIC:MAY FEEL DRUGGED, BECOME SLEEPY OR
UNCONSCIOUS. REPEATED SKIN CONTACT MAY CA USE RASH, WITH PROLONGED
EXPOSURE POSSIBLE DEVELOPING TO DERMATITIS. IF ECZEMATOUS DEVELOPS,
THIS (EFTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:STYRENE:CLASS 2B (IARC).
Effects of Overexposure:HLTH HAZ:MOST OFTEN OCCURS ON THE BACK OF
HANDS, WRISTS AND FOREARMS.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH CHRONIC
RESPIRATORY CONDITIONS (I.E., ASTHMA, CHRONIC BRONCHITIS,
EMPHYSEMA, ETC.) MAY BE ADVERSELY AFFECTED BY ANY FUME OR AIRBORNE
PARTICULATE MATTER EXPOSURE.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES, LIFTING UPPER & LOWER LIDS OCCASIONALLY. GET MD. SKIN:
REMOVE CONTAMINATED CLOTHING. WASH SKIN THOROUGHLY WITH SOAP &
WATER. IF IRRITATIO N OCCURS, GET MD. INHAL:REMOVE FROM EXPOSURE.
IF BREATHING HAS STOPPED OR IS DIFFICULT, GIVE ARTF RESP OR OXYGEN
AS INDICATED. GET MD. IF SYMPS PERSIST, CALL MD. INGEST:DO NOT
INDUCE VOMITING. GET MD.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:SEE INGREDIENT 2
Lower Limits:1.1%
Upper Limits:6.1%
Extinguishing Media:SMALL FIRES:CARBON DIOXIDE, DRY CHEMICAL. LARGE
FIRES:FOAM OR WATER FOG (LARGE FIRES).
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIP . DENSE SMOKE SERIOUSLY LIMITS VISIBLILTY. VENT SMOKE.
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELECTRICAL EQIUPMENT,
SPARKS AND OPEN FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. INCR VENT TO
MAXIMIZE VAP DISPERSAL. DIKE LARGE SPILLS TO PVNT RUNOFF INTO
SEWERS OR WATERWAYS. MAY BE REMOVED BY ORDINARY PHYSICAL MEANS,
I.E., SHOVELING, WIPING. SWEEP/C LEAN W/INERT MATLS, SUCH AS SAND,
(SEE SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY AREA, OUT OF DIRECT
SUNLT. AVOID PRLNGD/RPTD CONTACT W/SKIN. AVOID EYE CONT. WORK
W/ADEQ GEN & LOC EXHST VENT TO MIN EXPOS TO VAPS.
Other Precautions:BOND & GROUND CNTNRS FOR TRANSFER OF PRODUCT TO
PREVENT STATIC SPARKS. STYRENE VAPS ARE UNINHIBITED & MAY CAUSE
BLOCKAGE OF VENTS DUE TO POLYMERIZATION. PERIODIC INSPECTION MAY BE
NEC TO PREVENT BLOCK AGE. AVOID IMPROPER (SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ADEQUATE VENTILATION. NIOSH/MSHA APPROVED
ORGANIC VAPOR/DUST RESPIRATOR TO AVOID INHALATION OF EXCESSIVE AIR
CONTAMINANTS.
Ventilation:LOC EXHST SHOULD BE USED TO CNTRL EMISSION OF AIR CONTAM.
GEN DILUTION VENT MAY ASSIST W/REDUCTION OF AIR CONTAM CONC.
Other Protective Equipment:SAFETY SHOWERS AND EYE WASH STATIONS.
Work Hygienic Practices:CLEAN HANDS WITH SOAP & WATER AFTER EVERY USE.
Supplemental Safety and Health
SPILL PROC:VERMICULITE AND PLACE IN CLOSED CONTAINERS FOR DISPOSAL AS
SOLID WASTE. OTHER PREC:ADDITION OF PROMOTERS AND OXIDIZING AGENTS.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:ING 2
Vapor Pres:ING 2
Vapor Density:3.6
Spec Gravity:1.44
Evaporation Rate & Reference:LESS (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GREY, STYRENE ODOR
Percent Volatiles by Volume:<20
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, PEROXIDES, AND OTHER OXIDIZING AGENTS.
Stability Condition to Avoid:UNREGULATED CONTACT WITH ORGANIC
PEROXIDES, EXPOSURE TO HEAT,OPEN FLAME, AND PROLONGED STORAGE ABOVE
100F.
Hazardous Decomposition Products:CO, CO2, LOW MOLECULAR WEIGHT
HYDROCARBONS, ORGANIC ACIDS.
Conditions to Avoid Polymerization:UNREGULATED CONTACT WITH ORGANIC
PEROXIDES, EXPOSURE TO HEAT, OPEN FLAME, AND PROLONGED STORAGE
ABOVE 100F.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CARBOWAX PEG 8000, P155 10 001
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:POLY(OXY-1,2-ETHANEDIYL), .ALPHA.-HYDRO-.OMEGA.-HYDROXY-
EINECS/ELINCS: UNLISTED.
CAS:25322-68-3
RTECS #:TQ3500000
Fraction by Wt: 100%
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT)28 GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: MAY CAUSE MILD EYE
IRRITATION. SKIN: LOW HAZARD FOR USUAL INDUSTRIAL HANDLING.
INGESTION: MAY CAUSE GASTROINTESTINAL IRRITATION WITH NAUSEA,
VOMITING AND DIARRHEA. INHALATION: NO HAZARD EX PECTED IN NORMAL
INDUSTRIAL USE. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY
CAUSE DERMATITIS. TARGET ORGANS: NONE.
Explanation of Carcinogenicity:CAS# 25322-68-3: NOT LISTED BY ACGIH,
IARC, NIOSH, NTP, OR OSHA.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LST 15
MINS, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN:
FLUSH WITH PLENTY OF SOAP AND WATER FOR AT LST 15 MINS WHILE
REMOVING CONTA MD CLOTHING & SHOES. GET MED AID IF IRRIT DEVELOPS
OR PERSISTS. INGEST: IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4
CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO
UNCONSCIOUS PERSON. GET MED A ID. INHAL: REMOVE FROM EXPOSURE TO
FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT,
GIVE OXYGEN. GET MED AID. NOTES TO PHYS: TREAT SYMPTOMATICALLY &
SUPPORTIVELY.
===================== Fire Fighting Measures =====================
Flash Point:=268.C, 514.4F
Extinguishing Media:IN CASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL
FOAM, OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR
EQUIVALENT), AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:DUSTS A SUFFICIENT CONCENTRATIONS CAN
FORM EXPLOSIVE MIXTURES WITH AIR. DURING A FIRE, IRRITATING AND
HIGHLY TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OF
COMBUSTION.
================== Accidental Release Measures ==================
Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN EXPOSURE CONTROLS, PERSONAL
PROTECTION (SECTION 8). SPILLS/LEAKS: SWEEP UP OR ABSORB MATERIAL,
THEN PLACE INTO A SUITABLECLEAN, DRY, CLOSED CONTAINER FOR
DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:CAUTION! THIS IS EXPECTED TO BE A LOW
HAZARD FOR USUAL INDUSTRIAL HANDLING. MAY CAUSE IRRITATION. USE
WITH ADEQUATE VENTILATION.
Other Precautions:STORE IN A COOL, DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL
AIRBORNE LEVELS.
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
FED REGULATORY INFO: UNDER CWA. OSHA: NONE OF CHEMS IN THIS PROD ARE
CONSIDERED HIGHLY HAZ BY OSHA. SECTION 302(RQ): NONE OF CHEMS IN
MATL HAVE RQ. SECTION 302(TPQ): NONE OF CHEMS IN PROD HAVE TPQ. OS
HA: NONE OF CHEMS IN PROD ARE CONSIDERED HIGH HAZ BY OSHA.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:=60.C, 140.F
Vapor Pres:NOT AVAILABLE
Vapor Density:NOT AVAIL
Spec Gravity:1.20
pH:NOT AVAIL
Viscosity:NOT AVAIL
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE SOLID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
=================== Toxicological Information===================
Toxicological Information:LD50/LC50: CAS# 25322-68-3: ORAL,MOUSE = 34
GM/KG; ORAL, RABBIT: LD50 = 14 GM/KG; ORAL, RAT: DL50 = 28 GM/KG;
SKIN, RABBIT: LD50 = >20 GM/KG. EPIDEMIOLOGY, TERATOGENICITY,
REPRODUCTIVE EFFECTS, NEUROT OXICITY, MUTAGENICITY, AND OTHER
STUDIES: NO DATA AVAILABLE.
===================== Ecological Information =====================
Ecological:ECOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL AND
OTHER: NOT AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAX CONC OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LISTED. RCRA F, P, & U SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:NO INFORMATION AVAILABLE.
===================== Regulatory Information =====================
SARA Title III Information:NO CHEMICAL ARE REPORTABLE UNDER SECTION
313.
Federal Regulatory Information:TSCA CAS #25322-68-3 IS LISTED ON TSCA
INVENTORY. HLTH & SFTY RPTG LIST: NONE OF CHEMS IN PROD ARE UNDER
CHEM TEST RULE. SECTON 12B: NONE OF CHEMS ARE LISTED UNDER TSCA
SECTION 12B. TSCA SIGNIFICANT N EW USE FULE: NONE OF CHEMS IN MATL
HAVESNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL DOES NOT CNTN ANY HAZ
AIR POLLUTANTS. THIS MATL DOES NOT CNTN ANY CLASS 1 OZONE
DEPLETORS. THIS MATL DOES NOT CNTN ANY CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ SUBSTANCES
UNDER C WA. NONE OF CHEMS IN PROD ARE LISTED AS TOXIC POLLUTANTS
(SUPDAT)
State Regulatory Information:CAS# 25322-68-3 CAN BE FOUND ON FOLLOWING
STATE RIGHT TO KNOW LISTS: MINNESOTA. CALIFORNIA NO SIGNIFICANT
RISK LEVEL: NONE OF CHEMS IN THIS PROD ARE LISTED.
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ACTIVATOR FOR KOROTHERM 910X407 PART B
Kit Part:Y
CAGE:UO301
CAGE:UO301
CAGE:85570
============= Composition/Information on Ingredients =============
Ingred Name:METHYLENE BISPHENYL ISOCYANATE (MDI) (SARA III)
CAS:101-68-8
RTECS #:NQ9350000
Fraction by Wt: 45%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.02 PPM
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:OLIGOMERS OF MDI
CAS:9016-87-9
RTECS #:TR0350000
Fraction by Wt: 55%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:NO
Health Hazards Acute and Chronic:ACUTE-INHALATION:ALLERGIC
SENSITIZATION, IRRITATION. SKIN:IRRITATION. EYE:IRRITATION.
INGESTION: GI IRRITATION. CHRONIC:SKIN SENSITIZATION. TARGET
ORGANS:SKIN AND LUNGS.
Effects of Overexposure:INHALATION:IRRITATION, TIGHTNESS IN BREATH,
COUGHING , HEADACHE, SHORTNESS OF BREATH, ASTHMA LIKE ATTACKS MAY
FOLLOW. SKIN:IRRITATION. INGESTION:NAUSEA, VOMITING AND DIARRHEA.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, LUNG AND EYE
CONDITIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR FROM EXPOSURE. GIVE
ARTIFICIAL RESPIRATION OR CARDIOPULMONARY RESUSCITATION (CPR) IF
NEEDED. IF BREATHING DIFFICULT, GIVE OXYGEN. KEEP WARM & QUIET. GET
MED AID. SKIN: WASH W/SOAP & WATER. DO NOT USE SOLVENTS. REMOVE
CONTAMINATED CLOTHING & WASH BEFORE REUSE. GET MED AID. EYE
CONTACT: FLUSH W/WATER 15 MIN. GET MED AID. INGESTION: GET MEDICAL
HELP.
===================== Fire Fighting Measures =====================
Flash Point:>200F,>93C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR PROTECTIVE CLOTHING
AND SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE IN THE HEAT
OF FORE. FIRE OR EXCESSIVE HEAT MAY CAUSE PRODUCTION OF HAZARDOUS
DECOMPOSITION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:REPORT SPILL(NAT'L RESPONSE CTR
800-424-8802/LOCAL & STATE AGENCIES).REMOVE IGNITION SOURCE,WEAR
PROTECT EQUIP,USE NON-SPARK TOOL. SMALL:DIKE & ABSORB W/INERT
ABSORMENT. COLLECT IN OPEN DRUM, ISOLATE, FILL WITH
DECONTAMINATION SOLUTION TO NEUTRALIZE.
Neutralizing Agent:90-95% WATER, 2%DETERGENT, 3-8% AMMONIA.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED. ISOLATE FROM
HEAT, ELECTRICAL EQUIP, SPARKS & FLAME. STORE IN CLOSED CONTAINERS
& PROTECT FROM MOISTURE & FOREIGN MATERIAL.
Other Precautions:IDEAL STORAGE TEMPERATURES RANGE IS 64-68 F.
ISOCYANATES REACT SLOWLY WITH WATER TO FORM CO2 GAS WHICH CAN CAUSE
CONTAINER TO EXPAND OR RUPTURE. DONT INGEST. PREVENT CONTACT WITH
CONTAMINATED CLOTHING . OBSERVE PRECAUTIONARY LABEL WARNINGS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXCEED TLV OR SPRAY MIST, USE NIOSH/MSHA RESP
PROTECTION. IN CONFINED AREA USE NIOSH/MSHA AIR SUPPLIED
RESPIRATOR. FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS AND OSHA
REGULATIONS (29 CFR 1910.134) FOR RESPIRATOR USE.
Ventilation:WHERE EMPLOYEES EXPOSED, GENERAL DILUTION/LOCAL EXHAUST
VENT TO KEEP CONC BELOW PEL/TLV. IF NO EMPLOYEES, KEEP <25% LEL
Other Protective Equipment:AVOID SKIN CONTACT BY USE OF OTHER
PROTECTIVE CLOTHING. SAFETY SHOWER, EYE BATH AND WASH FACILITES
SHOULD BE AVAILABLE.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE. WASH
HANDS AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T6
Spec Gravity:1.24
Evaporation Rate & Reference:NON VOLATILE
Appearance and Odor:LIQUID, SOLVENT ODOR
Percent Volatiles by Volume:00
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH WATER, ALCOHOLS, AND AMINES.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE HAZARDOUS
INCLUDING CARBON MONOXIDE AND CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHEN DISPOSING OF MAT'L, ENSURE PACKAGED,
STORED, TRANSPORTED, MANAGED IN ACCORD W/LOCAL, STATE & FEDERAL
REGULATIONS. NO DISPOSAL METHOD THAT POSES ENVIRONMENTAL/HUMAN
HEALTH THREAT INCLUDING ANY WHI CH WOULD CONTAMINATE GROUND OR
SURFACE WATER.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:OUTDOOR RUST INHIBITOR 5081
Preparer's Name:BOB SILVA
CAGE:FO805
CAGE:FO805
============= Composition/Information on Ingredients =============
Ingred Name:ALIPHATIC PETROLEUM DISTILLATE (STODDARD SOLVENT)
CAS:8052-41-3
RTECS #:WJ8925000
Other REC Limits:N/K
OSHA PEL:500 PPM
ACGIH TLV:100 PPM; 9293
Ingred Name:ISOBUTANE
CAS:75-28-5
RTECS #:TZ4300000
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FIRST AID PROC:THRU LUNGS MAY OCCUR).IF LAVAGE IS
USED,SUGGEST ENDOTRACHEAL/ESOPHAGEAL CONTROL.WEIGH DANGER (SEE ING
6)
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 5: AGAINST TOXICITY. NO SPECIFIC ANTIDOTE. SUPPORTIVE
CARE. TREATMENT BASED ON JUDGMENT OF PHYSICIAN.
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:1,1,1-TRICHLOROETHANE.LD50 RAT ORAL:10,300 MG/KG.
CAS:71-55-6
RTECS #:KJ2975000
Other REC Limits:N/K
OSHA PEL:350 PPM
ACGIH TLV:350 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Other REC Limits:N/K
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:OVEREXPOSURE CAN CAUSE UNCONSCIOUSNESS
AND EVEN DEATH AT EXTREME DOSES.ACUTE EXPOSURE IN THE 1000 PPM
RANGE CAUSES NARCOSIS.PROLONGED OR REPEATED SKIN CONTACT CAN CAUSE
DERMATITIS.CHRONIC OVEREXPOSURE TO EYES MAY CAUSE CONJUNCTIVITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:CAN CAUSE MILD IRRITATION;OVEREXPOSURE MAY
CAUSE CONJUNCTIVITIS.SKIN:MILD IRRITATION;PROLONGED OR REPEATED
CONTACT CAN CAUSE DEFATTING.INGESTION:SMALL QUANTITIES NOT LIKELY
TO BE TOXIC.INHALATION :CAN CAUSE DIZZINESS,DRUNKENESS,DROWSINESS.
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/ WATER FOR AT LEAST 15 MIN,HOLDING LIDS
APART.SEE MD IF IRRIT PERSISTS.SKIN:REMOVE CONTAM CLTHG & FLUSH
EXPOSED AREAS W/ WATER FOR 5-10 MIN.INGEST:DO NOT INDUCE VOMIT.GIVE
LG QTIES OF WAT ER OR CITRUS JUICE.GET MED ATTN IMMED.NEVER GIVE
ANYTHING BY MOUTH TO UNCON PERSON.INH:MOVE TO FRESH AIR.TREAT
SYMP.DFCLT BRTHG-GIVE O*2.IF BRTHG STOPS-GIVE ARTF RESP.GET MED
HELP.MD NOTE:(SEE SUPP)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:150F,66C
Extinguishing Media:FOAM,CO2,DRY CHEMICAL.
Fire Fighting Procedures:WEAR PRESSURE-DEMAND SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:SPRAY AEROSOL CONTAINERS WITH WATER TO
COOL THEM AND PREVENT RUPTURING. FLAME EXTENSION:12 INCHES;
BURNBACK:NONE. HAZ DECOMP PROD:HCL,PHOSGENE,CO.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION.PREVENT FROM
ENTERING SEWER OR WATER SOURCES.VENTILATE ENCLOSED SPACE.WEAR
RESPIRATOR.CLEAN UP (ANY ELECTRIC CLEANING EQUIPMENT MUST BE
EXPLOSION-PROOF) OR SOAK UP WITH SAND,COTTON WASTE OR OTHER
ABSORBENT MATERIAL.
Neutralizing Agent:N/K
======================Handling and Storage ======================
Handling and Storage Precautions:STORE INDOORS BETWEEN 30 AND 120F (-1
AND 49C).FOLLOW LABEL DIRECTIONS.KEEP OUT OF REACH OF CHILDREN.
Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING,OPEN FLAMES OR HOT SURFACES.HEAT MAY CAUSE
THE FORMATION OF HCL AND/OR PHOSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:APPRVD ORGANIC VAPOR-TYPE RESPIRATOR REQ IN
ABSENCE OF PROPER ENVIRON CONTROL.FOR EMER,A POS-PRESS BRTHG APPAR
OR A FULL-FACE RESPIRATOR WITH AN APPRVD ORG VAPOR CANISTER IS
RECOM.DUE TO AEROSOL PACKA GING,NEED FOR ABOVE IS HIGHLY UNLIKELY.
Ventilation:GENERAL EXHAUST IS MORE THAN ADEQUATE TO PROTECT WORKER
FROM EXPOSURE TO LEVELS ABOVE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:IT IS RECOMMENDED THAT AN EYEWASH FOUNTAIN
BE AVAILABLE;WEAR APRON,DEPENDING ON EXTENT AND SEVERITY OF
EXPOSURE LIKELY.
Supplemental Safety and Health
ROUTES OF ENTRY:SKIN/INGEST .FIRST AID PROC:1,1,1-TRICHLOROETHANE HAS
PRODUCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFFECT IN HUMANS.USE ADRENERGICS (EPINEPHRI NE) ONLY
FOR LIFE-SUSTAINING USES IN HUMANS .MD SHOULD DECIDE WHETHER TO
INDUCE VOMITING (RAPID ABSORPTION (ING 5)
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:160F,71C
Decomp Temp:Decomp Text:N/K
Vapor Pres:100 MMHG
Vapor Density:4.2,AIR=1
Spec Gravity:1.010 (WATER=1)
Evaporation Rate & Reference:0.75 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:HAZY, BLUE-BROWN, VISCOUS; CHLORINATED HYDROCARBON
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:AVOID OPEN FLAMES OR OTHER HIGH
TEMPERATURE SOURCES WHICH INDUCE THERMAL DECOMPOSITION.
Hazardous Decomposition Products:CARBON MONOXIDE,HYDROGEN
CHLORIDE,PHOSGENE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP MUST BE IAW FEDERAL,STATE AND LOCAL
REGULATIONS .WRAP EMPTY AEROSOL CANS WITH SEVERAL LAYERS OF
NEWSPAPER AND DISCARD IN TRASH.1,1,1-TRICHLOROETHANE:SUBJECT TO
REPORTING REQUIREMENTS OF SAR A TITLE III SECTION 313 & 40 CFR PART
372.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:PAINT, LATEX, TT-P-19D EXTERIOR, TT-P-29K INTERIOR
CAGE:1BH90
CAGE:1BH90
============= Composition/Information on Ingredients =============
Ingred Name:PROPYLENE GLYCOL
CAS:57-55-6
RTECS #:TY2000000
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 @ 68F
ACGIH TLV:NOT EST.
Ingred Name:TEXANOL ESTER ALCOHOL
CAS:25265-77-4
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 @ 68F
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:AVAILABLE INFORMATION PROVIDES NO
EVIDENCE OF CHRONIC OR DELAYED HEALTH HAZARDS ASSOCIATED W/EXPOSURE
TO THIS PRODUCT.
Effects of Overexposure:INHAL: VAPOR/SPRAY MIST MAY BE HARMFUL. VAPOR
GENERATED AT ELEVATED TEMPS IRRITATES EYES/NOSE/THROAT. EYE:
POSSIBLE IRRITATION/REDNESS/TEARING. SKIN: POSSIBLE TRANSIENT
REDDENING W/PROLONGED CONTACT. INGESTION: HARMFUL OR FATAL IF
SWALLOWED.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN, RESPIRATORY
SYSTEM DISORDERS, AND UNUSUAL ALLERGIC SENSITIVITY.
======================= First Aid Measures =======================
First Aid:INGESTION: HAVE VICTIM DRINK ENOUGH WATER TO ENSURE DILUTION.
DO NOT INDUCE VOMITING. CALL EMERGENCY MED CARE. EYES: FLUSH
IMMEDIATELY W/PLENTY WATER >15 MIN. SKIN: FLUSH IMMEDIATELY
W/PLENTY WATER TH EN WASH THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHES. INHALATION:REMOVE TO FRESH AIR. APPLY
ARTIFICIAL RESP/OTHER SUPPORTIVE MEASURES AS REQUIRED.*
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:USE NFPA CLASS B EXTINGUISHERS (C02/DRY
CHEMICAL/UNIVERSAL AQUEOUS FILM FORMING FOAM) FOR NFPA CLASS IIIB
LIQUID FIRES.
Fire Fighting Procedures:H20 SPRAY MAY BE INEFFECTIVE. WEAR SCBA. USE
H20 SPRAY TO COOL CLOSED CONTNERS/PREVENT PRESSURE
BUILDUP/AUTOIGNITION/EXPLOSION. FOG NOZZLES PREFERRED IF USE H20
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE OR BURST
DUE TO BUILD-UP OF STEAM PRESSURE WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE & ABSORB SPILLED LIQUID W/INERT MATERIAL
SUCH AS CLAY GRANULES, SAND, EARTH OR SAWDUST. USE RAGS TO CLEAN UP
SMALL AMOUNTS OF SPILLED MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. DON'T HANDLE/STORE NEAR HEAT/FLAME/STRONG
OXIDIZERS/ACIDS/ALKALIS. STORE IN COOL, WELL-VENTILATED AREA.
Other Precautions:ROTATE STOCK, USE OLDER MATERIAL FIRST. INSPECT ALL
CONTAINERS FOR LEAKS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR SPRAY APPLICATION, USE PARTICULATE FILTER
MASK TO AVOID BREATHING SPRAY MIST. EXPOSED PERSON WITH UNUSUAL
ALLERGIC SENSITIVITY MAY NEED ORGANIC VAPOR RESPIRATOR (NIOSH/MSHA
TC 23C OR EQUIVALENT).
Ventilation:FOR INTERIOR USE, GENERAL MECHANICAL MAY BE SUFFICIENT TO
DISPERSE VAPOR. OTHERWISE OPEN DOORS/WINDOWS OR USE FANS.
Other Protective Equipment:WATERPROOF HEADCOVERING AND GENERAL
PROTECTIVE CLOTHING RECOMMENDED.
Work Hygienic Practices:WASH HANDS AND FACE BEFORE EATING, DRINKING OR
SMOKING.
Supplemental Safety and Health
DO NOT STORE IN AREAS SUBJECT TO FREEZING TEMPERATURES. KEEP ABOVE 40F
AT ALL TIMES. USE ONLY WITH ADEQUATE VENTILATION OR PROTECTION.
AVOID BREATHING SPRAY MIST OR VAPOR. DO NOT INGEST. AVOID CONTACT
WITH SKIN. CLOSE CONTAINER AFTER EACH USE. KEEP OUT OF REACH OF
CHILDREN.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:100 TO 296F
Vapor Density:>AIR
Spec Gravity:1.2-1.4
Evaporation Rate & Reference:<34.0
Solubility in Water:<52.0%
Percent Volatiles by Volume:48-52%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NK
Hazardous Decomposition Products:WELDING/BRAZING/FLAME-CUTTING ON
SURFACES COATED W/THIS PRODUCT MAY PRODUCE FUMES INCLUDING CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE
WITH FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
EMPTY CONTAINERS SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN
APPROVED WASTE MANAGEMENT FACILITY.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:BLUE SUPER-SPOT, E&I 23 24
Preparer's Name:DOYLE YODER
CAGE:17833
CAGE:17833
============= Composition/Information on Ingredients =============
Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: <15%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM; 250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:STODDARD SOLVENT; (ALIPHATIC HYDROCARBONS)
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: <35%
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:SUPDAT: CNTNRS TO HEAT, FLAME, SPKS, STATIC ELEC OR OTHER
SOURCES OF IGNIT; THEY MAY EXPLODE & CAUSE INJURY OR (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:DEATH. EMPTY DRUMS SHOULD BE COMPLETELY DRAINED,
PROPERLY BUNGED & PROMPTLY RETURNED TO DRUM RECONDITIONER (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: OR PROPERLY DISPOSED OF. KEEP CNTNRS TIGHTLY CLOSED.
ISOLATE FROM HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO EXTREME
HEAT.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: SYSTEM DMG. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING CONTENTS MAY BE
HARMFUL/FATAL.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: METHANOL WHICH CAN CAUSE INTOXICATION & CNS
DEPRESS. METHANOL IS METABOLIZED TO FORMIC ACID & (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: FORMALDEHYDE. THESE METABOLITES CAN CAUSE METABOLIC
ACIDOSIS, VISUAL DISTURBS & BLINDNESS. SINCE (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10: METABOLISM IS REQD FOR THESE TOX SYMPS, THEIR ONSET
MAY BE DELAYED FROM 6-30 HRS FOLLOWING INGEST. (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: ETHANOL COMPETES FOR SAME METABOLIC PATHWAY & HAS
BEEN USED TO PVNT METHANOL METABOLISM. ETHANOL ADMIN (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: IS INDICATED IN SYMPTOMATIC PATIENTS OR AT METHANOL
CONCS ABOVE 20 UG/DL. METHANOL IS EFTIVELY REMOVED (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13: BY HEMODIALYSIS. KEEP WARM, QUIET & GET IMMED MED
ATTN. DO NOT INDUCE VOMIT BECAUSE ASPIR OF MATL INTO (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: LUNGS FROM VOMIT CAN CAUSE CHEM PNEUMIT WHICH CAN
BE FATAL.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: AVOID RUNOFF INTO STORM SEWERS AND DITCHES
WHICH LEAD TO WATERWAYS.
RTECS #:9999999ZZ
Ingred Name:RESP PROT: USE NIOSH APPRVD POS PRESS AIR SUPPLIED RESP IF
THERE IS ANY POTENTIAL FOR UNCONTROLLED RELEASE, (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17: EXPOS LEVELS ARE NOT KNOWN OR ANY OTHER
CIRCUMSTANCES WHERE AIR PURIFYING RESPS MAY NOT PROVIDE ADEQ
PROTECTION.
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT: ALL HAZARD PRECS GIVEN IN DATA SHEET MUST BE
OBSERVED. WASH HANDS BEFORE EATING OR SMOKING. (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19: REMOVE CONTAMD CLTHG & WASH BEFORE REUSE. USE ONLY
IN WELL VENTILATED AREA. GROUND & BOND CNTNRS WHEN (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20: TRANSFERRING MATL. USE SPARK-PROOF TOOLS &
EXPLOSION PROOF EQUIP. AVOID PRLNGD/RPTD CONTACT W/SKIN. (ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21: AVOID BRTHG VAPORS FROM HEATED MATL. AVOID CONTACT
W/EYES, SKIN & CLOTHING.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT: LIQ, AEROSOLS & VAPS OF
PROD ARE IRRITATING & CAN CAUSE PAIN, TEARING, REDDENING & SWELL
ACCOMPANIED BY STINGING SENSATION &/OR FEELING LIKE THAT OF FINE
DUST IN EYES. SKIN CONTACT: PRLNG D/RPTD CONTACT CAN RSLT IN DEFAT
& DRYING OF SKIN WHICH MAY RSLT IN SKIN IRRIT & DERM (RASH). INHAL:
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: HDCHS, DIZZ, NAUS, DECRD BLOOD PRESS,
CHGS IN HEART RATE & CYANOSIS (CHARACT BY BLUISH DISCOLORATION OF
SKIN & NAILS) MAY RSLT FROM OVEREXP TO VAP OR SKIN EXPOS. INGEST:
THIS MATL MAY BE HAR MFUL/FATAL IF SWALLOWED. CHRONIC: REPORTS HAVE
ASSOC RPTD & PRLNGD OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS
(ING 8)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN. GET
IMMED MED ATTN. SKIN: IMMED FLUSH SKIN W/PLENTY OF WATER. WASH
W/SOAP & WATER. REMOVE SOILED CLTHG. WASH CLTHG SEPARATELY BEFORE
REUSE. GETMED ATTN IF IRRIT DEVELOPS OR PERSISTS. INHAL: REMOVE
TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE
OXYGEN. GET IMMED MED ATTN. INGEST: NOTE TO MD: THIS PROD CONTAINS
(ING 9)
===================== Fire Fighting Measures =====================
Flash Point:72.0F,22.2C
Lower Limits:1.0%
Upper Limits:36.0%
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
CNTNRS CAN BUILD UP PRESS IF EXPOSED TO HEAT (FIRE). WATER RUNOFF
CAN CAUSE ENVIRONMENTAL DAMAGE. DIKE (SUPDAT)
Unusual Fire/Explosion Hazard:AVOID BRTHG DUSTS & FUMES FROM BURNING
MATL. VAPS MAY FORM EXPLO MIX W/AIR. VAPS CAN TRAVEL TO A SOURCE OF
IGNIT & FLASH BACK. "EMPTY" CNTNRS RETAIN (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSNTL PERS. REMOVE ALL
SOURCES OF IGNIT. VENT AREA. EQUIP EMPLOYEES W/APPROP PROT EQUIP.
DIKE AROUND SPILLED MATL. COVER SPILL W/ABSORB MATL & SHOVEL WITH
NON-SPARKING TOOLS INTO CNT NR. REMOVE CNTNRS TO SAFE AREA & SEAL.
(ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM HEAT,
SPARKS & FLAME. KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:DO NOT INHALE MIST OR VAPOR. KEEP OUT OF REACH OF
CHILDREN. APPLY WITH BACK TO WIND DURING OUTDOOR APPLICATION. DO
NOT WEAR CONTACT LENSES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPRVD AIR PURIFYING RESP W/ORGANIC VAPOR
CARTRIDGE OR CANISTER MAY BE PERMISSIBLE UNDER CERTAIN
CIRCUMSTANCES WHERE AIRBORNE CONCS ARE EXPECTED TO EXCEED EXPOS
LIMS. PROTECTION PROVIDED BY AIR PURIFYING RESPS IS LIMITED. (ING
17)
Ventilation:LOCAL EXHAUST VENTILATION MAY BE NECESSARY TO CONTROL ANY
AIR CONTAMINANTS TO WITHIN THEIR TLVS DURING USE OF PRODUCT.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WHERE CONTACT IS LIKELY, WEAR CHEMICAL SUIT & RUBBER BOOTS.
Work Hygienic Practices:CNTNRS OF THIS MATL MAY BE HAZ WHEN EMPTIED.
SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ, &/OR SOLID),
(ING 19)
Supplemental Safety and Health
FIRE FIGHT PROC: & COLLECT WATER USED TO FIGHT FIRE. WATER SPRAY MAY BE
USED FOR COOLING CNTNRS TO PVNT POSS PRESS BUILD-UP & AUTO-IGNIT OR
EXPLO WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: PROD RESIDUE (LIQ
&/OR VAP) & CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND OR EXPOSE SUCH (ING 4)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>147F,>64C
Vapor Density:HVR/AIR
Spec Gravity:1.0372
VOC Grams/Liter:5.19
Evaporation Rate & Reference:FASTER THAN BUTYL ACETATE
Solubility in Water:PARTIAL
Appearance and Odor:BLUE LIQUID; SLIGHT SOLVENT ODOR.
Percent Volatiles by Volume:85.3
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
NO*X.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL LAWS. DO NOT DISCHARGE INTO WATERWAYS WITHOUT PROPER
AUTHORITY.
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:NAPAKOOL 4050 FAMILY (LIQUID INHIBITOR)
CAGE:59549
CAGE:59549
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM NITRATE
CAS:7631-99-4
RTECS #:WC5600000
Fraction by Wt: 5%
Ingred Name:SODIUM NITRITE (SARA III)
CAS:7632-00-0
RTECS #:RA1225000
Fraction by Wt: 5%
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:SODIUM HYDROXIDE (SARA III)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 1%
Other REC Limits:2MG/M3 CEILING NIOSH
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/INGESTION: IRRITATION. SKIN:
IRRITATION, DERMATITIS & BURNS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/INGESTION: IRRITATION. SKIN: IRRITATION,
DERMATITIS, & BURNS.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN.
INGESTION: DON'T INDUCE VOMITING, GIVE LARGE QUANTITIES OF WATER OR
SEVERAL GLASSES OF MILK. NEVER GIVE ANYTHING TO AN UNCONSCIOUS
PERSON. OBTAI N MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Unusual Fire/Explosion Hazard:DON'T MIX W/PAPER, COMPOST HEAPS, OR
OTHER DECAYING ORGANIC MATTER COMBINATION OF NITRATES W/ORGANIC
MATTER COULD CAUSE EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR OSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS & PROTECTIVE CLOTHING.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T INGEST INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE OSHA APPROVED SELF CONTAINED BREATHING
APPARATUS.
Ventilation:AIR ROOM
Other Protective Equipment:PROTECTIVE CLOTHING
Work Hygienic Practices:WASH HANDS AFTER HANDLING MATERIAL.
REMOVE/LAUNDER CONTAMINATED CLOTHES/FOOTWEAR BEFORE REUSE.
Supplemental Safety and Health
THIS PRODUCT IS AN OXIDANT.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:216F
Vapor Pres:AS WATER
Vapor Density:AS WATER
Spec Gravity:1.16 - 1.17
pH:11.3
Solubility in Water:COMPLETE
Appearance and Odor:RED COLOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
DECAYING ORGANIC MATTER, COMPOST HEAPS & PAPER.
Stability Condition to Avoid:TEMPERATURS >800F.
Hazardous Decomposition Products:NITRITES & NITRATES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:26412 URSA SUPER PLUS MOTOR OILS (SUPPLEMENTAL)
Preparer's Name:MANAGER, PRODUCT SAFETY
CAGE:EO306
CAGE:TEXLU
CAGE:EO306
CAGE:2R503
============= Composition/Information on Ingredients =============
Ingred Name:SOLVENT=DEWAXED HEAVY PARAFFINIC PETROLEUM DISTILLATES
CAS:64742-65-0
RTECS #:PY8038501
Fraction by Wt: 65-79.9%
Other REC Limits:NONE RECOMMENDED
Ingred Name:HYDROTREATED HEAVY PARAFFINIC PETROLEUM DISTILLATES
CAS:64742-54-7
RTECS #:PY8035501
Fraction by Wt: 20-34.9%
Other REC Limits:NONE RECOMMENDED
Ingred Name:RESIDUAL OILS, PETROLEUM HYDROTREATED
CAS:64742-57-0
Fraction by Wt: 1-2.99%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ZINC DIALKYLDITHIOPHOSPHATE,
CAS:84605-29-8
Fraction by Wt: 0.1-0.9%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ZINC 0,0-BISISODECYL DITHIOPHOSPHATE
CAS:25103-54-2
Fraction by Wt: 0.1-0.9%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL, RAT >5.00G/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:MIN IRRIT,EXPERIENCED AS
TEMP DISCOMFT.SKIN:BRIEF CONTACT SLIGHT IRRIT.PROL CONTACT MORE
SEVERE IRRIT,DISCOMFT,LOCAL REDNESS,SWELLING.INHAL:IRRIT OF
NOSE/THROAT,HEAD,NAU,DROWS.INGEST:MORE TH AN SEVERAL MOUTHFULS
RESULT IN ABD DISCOMFT,NAU,DIARR.CHRONIC:NO ADVERSE EFFECTS HAVE
BEEN DOC IN HUMANS.(SUPPLEMENTAL)
Explanation of Carcinogenicity:PER MSDS:PRODUCT &/OR COMPONENT(S)
CARCINOGENIC ACCORDINT TO:NONE.
Effects of Overexposure:MIN EYE IRRIT, TEMP DISCOMFORT,SLIGHT SKIN
IRRIT;SEVERE IRRIT,DISCOMFT,LOCAL REDNESS,SWELLING W/PROLONGED
CONTACT.IRRIT NOSE/THROAT,HEADACHES,NAUSEA,DROWSINESS. ABDOMINAL
DISCOMFORT,NAUSEA,DIARRHEA.
Medical Cond Aggravated by Exposure:BECAUSE OF ITS IRRITATING
PROPERTIES REPEATED SKIN CONTACT MAY AGGRAVATE EXISTING DERMATITIS
(SKIN CONDITION).
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/PLENTY OF WATER FOR SEVERAL MINS.IRRIT PERSIST
GET MED ATTN.SKIN:WASH W/PLENTY OF SOAP/WATER FOR SEVERAL
MINS.IRRIT DEVELOPS/PERSIST GET MED ATTN.INGEST:>SEVERAL MOUTHFULS
GIVE 2 GLASSES O F WATER(16OZ).GET MED ATTN.INHAL:REMOVETO FRESH
AIR.BREATH BECOMES DIFF/RESP IRRIT PERSIST GET MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>400F,>204C
Autoignition Temp:Autoignition Temp Text:N/DETR
Lower Limits:N/DETERMINED
Upper Limits:N/DETERMINED
Extinguishing Media:USE WATERSPRAY,DRY CHEM,FOAM,CO2 TO EXTINGUISH
FLAMES.COLL FIRE-EXPO CNTNRS W/WATERSPRAY.WATER/FOAM MAY CAUSE
FROTHING.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & POSITIVE
PRESSURE BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:HYDROGEN SULFIDE (H2S) MAY BE RELEASED IF
OVERHEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTI AREA.AVOID BREATH VAP.WEAR APPROPRIATE
PPE(INCLUDE RESP PROTECTION).CONTAIN SPILL IF POSSIBLE.WIPE
UP/ABSORB ON SUITABLE MATL.SHOVEL UP.PREVENT ENTRY INTO
SEWERS/WATERWAYS.AVOID CONTACT W/SKIN/E YE/CLOTHING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:MAINTAIN MIN FEASIBLE HNDLG TEMP.PER
OF EXPO TO HI TEMP SHOULD BE MIN.WATER CONTAMINATION SHOULD BE
AVOIDED.
Other Precautions:WARNING:USED GASOLLINE MOTOR OIL POSSIBLE SKIN CANC
HAZ BASED ON ANINAL DATA.USED GASOLINE MOTOR OILS HAVE BEEN SHOWN
TO CAUSE SKIN CANC WHEN REPEAT APPLIED TO MOUSE SKIN W/O ANY EFFORT
TO REMOVE MATL BETWEEN APPLICATIONS.NO (SUPPLEMENTAL)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:KEEP AIRBORNE CONC TO LOWEST LEVELS
POSSIBLE.VAP/MIST/DUST GENERAT/OCCUPAT EXPO LIMIT OF PROD/COMPO
EXCEEDED USE APPROPRIATE NIOSH/MSHA APPROV AIR PURIF/AIR SUPP RESP
AFT DETERMINE AIRBORNE CONTAM CON C.AIR SUPP RESP FOR UNK
OXY/CONTAM CONC.
Ventilation:ADEQUATE TO MEET COMPONENT OCCUPATIONAL EXPOSURE LIMITS.
Other Protective Equipment:WASH EXPO SKIN SEVERAL TIMES DAILY
W/SOAP/WATER.
Work Hygienic Practices:DRYCLEAN(MORE EFFECTIVE)/LAUNDER CLOTH
SOAK/SOIL W/MATL BEF REUSE.INFORM WASHER/CLEANER OF CLOTH OF POT
HAZ W/HNDLG CLOT
Supplemental Safety and Health
HEALTH HAZ:WHEN OVERHEAT MAY RELEASE H2S GAS-IRRIT EYE/RESP
TRACT,HEAD,DIZZ,NAU,VOMIT,DIARR,PULM EDEMA @>PERMISS CONC.@>300PPM
RESP PARALYSIS,UNCONSC,DEATH CAN OCCUR. OTHER PRECAUT:EVIDENCE OF
CAUSAL RELATIONSHIP BETWEEN SKIN CAN IN HUMANS& EXPO TO USED MOTOR
OIL. PRODUCTS:02109,02110,02111,02112,02113,02114.
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:N/DETERMINE
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NP
Vapor Pres:N/DETERMIN
Vapor Density:N/DETERMIN
Spec Gravity:0.88-0.91
pH:NA
Viscosity:45.1-215CST
Evaporation Rate & Reference:NONE SPECIFIED BY MANUFA.
Solubility in Water:NOT DETERMINED.
Appearance and Odor:BRIGHT AND CLEAR LIQUID, ODOR NOT DETERMINED.
Percent Volatiles by Volume:NP
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS VIOLENTLY W/STRONG OXIDIZERS.
Stability Condition to Avoid:UNDER EXTREME TEMP OR EXTENDED STORAGE
PERIODS,HYDROGEN SULFIDE (H2S) GAS MAY ACCUMULATE IN HEAD-SPACE OF
CONTAINER.
Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE,CARBON
DIOXIDE,IRRIT ALDEHYDES & KETONES & COMBUST PROD OR CMPDS OF
SULFUR(INCLUDE H2S).
==================== Disposal Considerations ====================
Waste Disposal Methods:PROD EVALUATED FOR RCRA CHARACTER-DOESN/T MEET
CRITERIA OF HAZ WASTE IF DISCARDED IN PURCHASED FORM.PER RCRA USER
RESPONSIBILITY TO DETERMINE @TIME OF DISPO WHETHER HAZ WASTE
BECAUSE USES/TRANSFORM/MI XTURES/PROCESS/ETC MAY RENDER HAZ.NO SARA
SEC 313.
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:011006-05 WC-106
CAGE:GO132
CAGE:GO132
CAGE:0FGH2
============= Composition/Information on Ingredients =============
Ingred Name:TUNGSTEN,AS W,SOLUBLE COMPOUNDS.
CAS:7440-33-7
RTECS #:YO7175000
Fraction by Wt: >75%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOE ESTABLISHED
ACGIH TLV:1 MG/M3/3 STEL; 9596
Ingred Name:COBALT (SARA 313)
CAS:7440-48-4
RTECS #:GF8750000
Fraction by Wt: 5-20%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.02 MG/M3; A3; 9596
Ingred Name:CARBON
CAS:7440-44-0
RTECS #:FF5250100
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9596
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:MAY CAUSE ALLERGIC DERM
W/REDNESS,PAPULAR FORMATION IN SUSCEPTABLE INDIVIDUALS WHICH
USUALLY OCCURS IN FOLDS OF SKIN.EYE:MAY CAUSE IRRIT,EXPERIENCED AS
REDNESS & EXCESS REDNESS OF CONJUNCTIVA.ING EST:MAY CAUSE NAU,ABD
PAIN,VOMIT,DIARR,BURNING SENS.INHAL:MAY CAUSE VOMIT,DIARR,BURNING
SENS.MAY ALSO CAUSE (SIGN/SYMPT)
Explanation of Carcinogenicity:PER MSDS:CARCINOGEN:IARC/NTP/OSHA:NO.
Effects of Overexposure:HEALTH:INTERSTITIAL PNEUMONITIS & SENSITIZATION
OF RESPIRAOTRY TRACT IN SUSCEPTIBEL INDIVIDUALS.REP OVEREXPO:MAY
CAUSA SENS OF RESP TRACT,SKIN IN SUSCEPTIBLE INDIVIDUALS.CHRONIC
EXPO TO EYE CAN CAUSE CORNEAL DMG.CHRONIC EXPO MAY ALSO
CAUSEPOLYCYTHEMIA,HYPERPLASIA OF THYROID GLAND,DMG OT ALPHA CELLS
OF PANCREAS.
Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE
ASTHMA & INFLAMMATORY OR FIBROTIC PULMONARY DISEASE.MAY ALSO
AGGRAVATE AN EXISTING DERMATITIS.
======================= First Aid Measures =======================
First Aid:INGEST:GIVE @LEAST 2 GLASSES OF MILK OR WATER.INDUCE VOMIT
UNLESS PATIENT IS UNCONSC.CALL PHYSICIAN.SKIN:WASH THOROUGHLY
W/SOAP/WATER.INHAL:REMOVE TO FRESH AIR.GIVE ARTIFICIAL RESPIRATION
IF NOT BREAT HING.OXYGEN MAY BE GIVEN IF NECESSARY.CALL
PHYSICIAN.EYE:FLUSH THOROUGHLY W/PLENTY OF WATER.IF DISCOMFT
PERSIST SEEK MED ATTN PREFER OPTHALMOLOGIST.NOTES TO DR:HAZ OF MATL
MAINLY DUE TO (SUPPLEMENTAL)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:0.00
Extinguishing Media:USE SPECIAL DRY POWDER METAL EXT MATL TO EXT METAL
FIRE.USE APPROPR EXT TO EXT COMBUST MATL IGN BY THERM SPRAY FLAME.
Fire Fighting Procedures:CONSULT/COMPLY W/ANSI Z49.1,NFPA 51B FOR FIRE
PREVENT IN USE OF CUT/WELD PROCESSES.NFPA 51 OXY-FUEL GAS SYS FOR
WELD/CUT,NFPA 58 STD FOR STORAGE/HNDLG LIQ PETRO
Unusual Fire/Explosion Hazard:AIRNORNE DUST PARTICLES ESPECIALLY METAL
DUST & ACCUMULATION OF SUCH SHOULD BE TREATED AS EXPLOSIVES.TO MIN
DANGER FOR DUST EXPLO ADEQ VNETI SHOULD BE (SUPPLEM)
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQPMT TO PROTECT AGAINST
HAZARDS & DISPOSE OF PER WASTE DISPOSAL METHOD.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CAUT:WHEN THERMAL SPRAYING-ELECTRICITY
CAN CAUSE FATAL SHOCK.DONT TOUCH LIVE ELECT PARTS.ARC RAYS CAN BURN
EYE/SKIN.,WEAR RECOMMENDED EYE/BODY PROTECT
Other Precautions:FUME/GAS/DUST HARMFUL.PROVIDE ENOUGH VENTI/WEAR RESP
IF REQUIRE.CAN TAK PERSONAL AIR SPLS(AWS F1.1-76)/ANALYZ FOR HAZ
INGRED/DECOMPO PROD TO DETERMINE IF/WHAT TYPE RESP REQUIRE.BEF USE
REF:AMER WELD S OC "THERM SPRAY PRACT".AREA/SPARK(SUPPL)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DEPENDS UPON SPECIFIC USE,CONDITION, &
LOCATION.IF THERE IS DUSTINESS,WEAR RESPIRATOR SELECTED PER OSHA
1910.134 & OSHA 29CFR 1901.252 & ANSI Z49.1.
Ventilation:LOCAL DUST PICK UP & VENTILATION RECOMMENDED.ALWAYS SPRAY
W/ENOUGH VENTILATION.
Other Protective Equipment:SEE ANSI Z49.1,ANSI X87.1,ANSI Z88.2 FOR
Work Hygienic Practices:BEF USE REFER TO OTHER SECS OF THIS DOCUMENT &
PUBLICATIONS REFERENCED THEREIN.REF:NFPA 51B.
Supplemental Safety and Health
FIRE/EXPLO:PROVIDED TO SPRAY BOOTH IAW AMER WELD SOC AWSC2.1-73 & ACGIH
"INDUSTR VENTI". DECOMPO PROD:FRM THERMAL SPRAY POWDER INCLUDE
OXIDES,SUB-OXIDES,COMPLEX OXIDES OF MATLS LISTED AS INGREDS. 1STA
ID:SENS/MILD IRRIT PROPERTIES.NO SPEC ANTIDOTE.TREAT BE DIRECT
SYMPT CNTRL/CLINICAL CONDITIONS. OTHER PREC:DUR SPRAY-IGN
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NONE
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:NP
Vapor Density:NON-VOLATI
Spec Gravity:NP
pH:NP
Viscosity:NP
Evaporation Rate & Reference:UNAVAILABLE
Solubility in Water:NP
Appearance and Odor:DUSTY DARK GRAY POWDER
Percent Volatiles by Volume:0
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERM SPRAYING DECOMPO PROD WILL VARY
W/OPERATING CONDITIONS.REASONABLY EXPECTED DECOMPO PROD OF NORMAL
OPERATION (SUPP)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WAASTE PER LOC/STATE/FED
REGULATIONS.SARA TITLE III SEC 313:COBALT <20%
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:AMMONIA PH-ADJUSTING ISA, 951211
CAGE:30260
CAGE:30260
============= Composition/Information on Ingredients =============
Ingred Name:ACETIC ACID,(ETHYLENEDINITRILO)TETRA-,DISODIUM
SALT,DIHYDRATE; (DISODIUM EDTA (NA2C10H1403N2) LD50(ORAL RAT):200
MG/KG
CAS:6381-92-6
RTECS #:AH4410000
Fraction by Wt: 1.8%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:THYMOLPTHALEIN (C28H30O4)
CAS:125-20-2
Fraction by Wt: 1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER; (DEINOZIED WATER (H2O))
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 67.2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA) VAP DENS:
1.1
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 10%
OSHA PEL:200 PPM, S
ACGIH TLV:200PPM/250STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SODIUM HYDROXIDE (CERCLA)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 20%
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MILD TO SEV IRRIT, LGE
DOSES-DELAYED PULM EDEMA, SML SKIN BURNS W/DEEP ULCERATION, SEV
BURNS, & DISINTEGRATION OF CONJUNCTIVAL & CORNEAL EPITHELIUM. CORR
OF LIPS, MOUTH, THROAT, TONGUE, & PHARYNX, VOMIT OF MUCOSA.
ASPHYXIA CAN OCCUR FROM SWELLING OF THROAT. CHRONIC: BRONCHIAL
IRRITANT, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: COUGHING, PNEUMONIA, GI DISTURBANCES,
DERM, CONJUNCTIVITIS. SIGNS & SYMPS OF EXPOS: SORE THROAT,
COUGHING, LABORED BRTHG. BURNS OF SKIN, EYES, MUC MEMB.
Medical Cond Aggravated by Exposure:LUNG CONDITIONS, IRRITATED OR
SENSITIVE SKIN.
======================= First Aid Measures =======================
First Aid:ALL: GET MEDICAL ATTENTION. INHALATION: FRESH AIR, ARTIFICIAL
RESPIRATION IF NECESSARY. KEEP WARM AND AT REST. SKIN: WASH WITH
SOAP AND LARGE AMOUNTS OF WATER WHILE REMOVING CONTAMINATED
CLOTHING. EYE S: FLUSH WITH LARGE AMOUNTS OF WATER WHILE LIFTING
LIDS (15-20 MINUTES). INGESTION: GIVE LARGE AMOUNTS OF MILK OR
WATER AND ALLOW VOMITING TO OCCUR, DO NOT INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:104F,40C
Lower Limits:6%
Upper Limits:36.5%
Extinguishing Media:ANY EXTINGUISHING MEDIA.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
MOVE CONTRS AWAY IF POSS; COOL FROM SIDE. USE FLOODING QTYS OF
WATER AS A FOG. APPLY FROM DIST, STAY (SUP DAT)
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP AND SET ASIDE FOR WASTE DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP COOL AND WELL-SEALED. STORE AWAY
FROM ACIDS, FLAMMABLES. CORROSIVE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NIOSH APPROVED SCBA FULL FACEPLATE.
Ventilation:LOCAL EXHAUST TO MEET EXPOSURE LIMITS.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . IMPERVIOUS CLOTHING.
Work Hygienic Practices:NO EATING OR DRINKING WHILE USING.
Supplemental Safety and Health
PH: STRONGLY ALKALINE (14). FIRE FIGHT PROC: UPWIND; AVOID BRTHG. RESP
PROT: AND FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:30.0F,-1.1C
Vapor Density:SEE ING 2
Spec Gravity:1.0 (H*2O=1)
pH:SUPDAT
Solubility in Water:MISCIBLE
Appearance and Odor:DARK BLUE SOLUTION, SLIGHT ALCOHOL ODOR
Percent Volatiles by Volume:10(WT)
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONT W/WATER MAY CAUSE HEAT TO BE RELEASED. CONT W/ACIDS, FLAMMABLE
LIQUID, & ORGANIC HALOGEN COMPOUNDS MAY CAUSE FIRE.
Stability Condition to Avoid:STORING NEAR ACIDS OR ORGANIC HALOGENS.
Hazardous Decomposition Products:MAY RELEASE TOXIC FUMES OF SODIUM
OXIDE WHICH CAN REACT WITH WATER OR STREAM TO PRODUCE HEAT OR
FLAMMABLE H*2 GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE
AND LOCAL LAWS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:COOLING SYSTEM FAST FLUSH, VZ-5537, #2212N
CAGE:18773
CAGE:18773
CAGE:18873
============= Composition/Information on Ingredients =============
Ingred Name:CHROMIUM (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 1.1%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ALKALINE ADDITIVES
Fraction by Wt: 6%
===================== Hazards Identification =====================
Effects of Overexposure:HEADACHE/NAUSEA/IMPAIRMENT OF REACTION TIME AND
COORDINATION.
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO FRESH AIR TO RESTORE BREATHING. SKIN
CONTACT: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING.
EYE CONTACT: FLUSH WITH WATER FOR AT LEAST 15 MINUTES; CALL A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:>150F (TOC)
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WATER COOL CONTAINERS TO PREVENT PRESSURE
BUILD-UP
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID PROLONGED CONTACT WITH SKIN AND
BREATHING OF VAPOR. REMOVE SOURCES OF IGNITIONREMOVE WITH INERT
ABSORBENT AND NON-SPARKING TOOLS. VENTILATE AREA.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND OPEN
FLAME. CLOSE CONTAINER AFTER EACH USE. DO NOT STORE >120
Other Precautions:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
SMOKING. CONTAINERS SHOULD BE GROUNDED WHEN POURING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ADEQUATE VENTILATION.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP BELOW TLV.
Supplemental Safety and Health
MSDS DATE: 22 JUL 74.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:210-220F
Vapor Pres:23.
Vapor Density:0.62
Spec Gravity:1.048
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:COMPLETE
Appearance and Odor:YELLOW OPAQUE LIQUID, MILD ODOR
Percent Volatiles by Volume:88.1
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Hazardous Decomposition Products:CO, CO2, SMOKE AND OXIDES OF CHROMIUM
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL METHOD MUST COMPLY WITH LOCAL, STATE,
AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ACETONITRILE 00170, BW1140RT50
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:ACETONITRILE LD50: (ORAL, RAT) 2730 MG/KG
CAS:75-05-8
RTECS #:AL7700000
= Wt:99.
OSHA PEL:70 MG/M3;40 PPM
ACGIH TLV:67 MG/M3;40 PPM
ACGIH STEL:101 MG/M3;60 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE MODERATE EYE IRRIT.
VAPS MAY CAUSE EYE IRRIT. SKIN: MAY BE HARMFUL IF ABSORBED THRU
SKIN. MAY BE METABOLIZED TO CYANIDE WHICH IN TURN ACTS BY
INHIBITING CYTOCHROME OXIDASE IMPAIRING CEL LULAR RESPIRATION.
INGEST: MAY CAUSE IRRIT OF DIGESTIVE TRACT. MAY CAUSE EFTS SIMILAR
TO THOSE FOR INHAL EXPOS. INHAL: HARMFUL IF INHALED. INHAL OF HIGH
CONCS MAY CAUSE CNS EFTS CHARACTERIZED BY HDCH, DIZZ, UNCON &
COMA. MAY CAUSE LIVER & KIDNEY DMG. VAPS MAY CAUSE DIZZ OR
SUFFOCATION. MAY CAUSE NAUS, DIZZ & HDCH. INHAL MAY LEAD TO DIZZ,
WEAK & DROW, LEADING TO STUPOR, UNCON & EVEN DEATH. INHAL MA Y LEAD
TO(EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: HEMATEMESIS, CONVULSIONS, CHOCK, COMA
& POSSIBLE DEATH. CHRONIC: CHRONIC INHAL & INGEST MAY CAUSE EFTS
SIMILAR TO THOSE OF ACUTE INHAL & INGEST. MAY BE METABOLIZED TO
CYANIDE WHICH IN TURN A CTS BY INHIBITING CYTOCHROME OXIDASE
IMPAIRING CELLULAR RESPIRATION. ANIMAL STUDIES HAVE REPORTED THAT
FETAL EFTS/ABNORMALITIES MAY OCCUR WHEN MATERNAL TOXICITY IS SEEN.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN, OCCASNLY
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. SKIN: GET MED AID
IMMED. FLUSH SKIN W/PLENTY OF SOAP & WATER FOR AT LEAST 15 MIN
WHILE REMOV ING CONTAM CLTHG & SHOES. INGEST: IF VICTIM CONSCIOUS &
ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY
MOUTH TO UNCON PERSON. GET MED AID IMMED. INHAL: GET MED AID
IMMED. REMOVE FRO M EXPOS TO FRESH AIR IMMED. IF BRTHG IS DFCLT,
GIVE OXYG. NOTES TO MD: EXPOS SHOULD BE TREATED AS CYANIDE
POISONING. EFTS MAY BE DELAYED. ANTIDOTE: ALWAYS HAVE CYANIDE
ANTIDOTE KIT ON HAND WHEN WORING W/CYANIDE CMPDS. GET MED ADVICE
TO USE.
===================== Fire Fighting Measures =====================
Flash Point:=6.C, 42.8F
Autoignition Temp:=524.C, 975.2F
Lower Limits:4.4%
Upper Limits:16.0%
Extinguishing Media:SM FIRES:USE DRY CHEM, CO*2, WATER
SPRAY/ALCOHOL-RESIST FOAM. USE WATER SPRAY TO COOL FIRE-EXPOS
CNTNRS. WATER MAY BE INEFFECTIVE. DO NOT USE STRAIGHT STREAMS OF
WATER. LG (SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . NFPA RATING: HEALTH-2; FLAMMABILITY-3; REACTIVITY-0.
Unusual Fire/Explosion Hazard:CNTNRS CAN BUILD UP PRESS IF EXPOS TO
HEAT &/OR FIRE. VAPS MAY FORM EXPLO MIX W/AIR. VAPS CAN TRAVEL TO
IGNIT SOURCE & FLASH BACK. COMBUST GENERATES TOX FUMES. USE WATER
SPRAY TO KEEP FIRE-EXPOS CNTNR S COOL. FLAM LIQ. VAPS MAY BE
HVR/AIR. THEY CAN SPREAD ALONG GROUND & COLLECT IN LOW/CONFINED
AREAS. CNTNRS MAY (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
AVOID RUNOFF INTO STORM SEWERS AND DITCHES WHICH LEAD TO WATERWAYS.
REMOVE ALL SOURCES OF IGNITION. ABSORB SPILL USING AN ABSORBENT,
NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SAND OR VERMICULITE. A
VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS. WATER SPRAY
MAY REDUCE VAPOR BUT MAY NOT PREVENT IGNITION IN CLOSED SPACES.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & FLAME.
KEEP AWAY FROM SOURCES OF IGNIT. STORE IN TIGHTLY CLOSED CNTNR.
KEEP FROM CNTCT W/OXIDIZING MATLS. STORE IN COOL, DRY, WELL-VENTD
AREA AWAY FROM INCOMPAT SUBSTANCES. WASH THOROUGHLY AFTER HNDLG.
REMOVE CONTAM CLTHG & WASH BEFORE USE. USE ONLY IN WELL VENTD AREA.
Other Precautions:GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. AVOID
CNTCT W/EYES, SKIN & CLTHG. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ
&/OR VAP) & CAN BE DANGEROUS. KEEP CNTNR TIGHTLY CLSD. AVOID CNTCT
W/HEAT, SPKS & F LAME. DO NOT INGEST/INHALE. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY C NTNRS TO
(SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQ GEN/LOC EXHST VENT TO KEEP AIRBORNE CONCS BELOW
PEL. ACETONITRILE: EXPOS LIMS: ACGIH-40PPM; 67 MG/M3; 60PPM STEL;
101 MG/M3 STEL. NIOSH-20PPM (SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Supplemental Safety and Health
OTHER PRECS:HEAT, SPKS/OPEN FLAME. EXTING MEDIA:FIRES:USE DRY CHEM,
CO*2, ALCOHOL-RESIST FOAM/WATER SPRAY. COOL CNTNRS W/FLOODING QTYS
OF WATER UNTIL WELL AFTER FIRE IS OUT. EXPLO HAZ:MAY EXPLODE WHEN
HEATED. VENT:TWA; 34MG/M3 TWA; 500PPM IDLH. OSHA-40PPM TWA; 70
MG/M3 TWA. OSHA VACATED PELS:40PPM TWA; 70MG/M3 TWA.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:=-50.C, -58.F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:73 MM HG
Vapor Density:1.4(AIR=1)
Spec Gravity:0.7810
pH:NOT AVAILABLE
Viscosity:0.36 CP 20 DEG
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; SWEETISH ODOR - AROMATIC
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CHLORINE FLUORIDE, FLUORINE, 2-CYANO-2-PROPYL NITRATE, DINITROGEN
TETRAOXIDE, INDIUM, DIPHENYL SULFOXIDE, TRICHLOROSILANE, N-FLUORO
CMPDS, IRON (III) PERCHLORATE, LANTHANIDE, NITRIC ACID, PERCHLORIC
ACID, SULFURIC ACID, SUL
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID INCOMPATIBLE MATERIALS, IGNITION SOURCES.
Hazardous Decomposition Products:HYDROGEN CYANIDE, NITROGEN OXIDES,
CARBON MONOXIDE, CARBON DIOXIDE.
=================== Toxicological Information===================
Toxicological Information:CAS #75-05-8, RTECS #AL7700000. LD50/LC50 -
INHAL, MOUSE: LC50=2693 PPM/1H; INHAL, RABBIT: LC50=2828 PPM/4H;
INHAL, RAT: LC50=7551 PPM/8H; ORAL, MOUSE: LD50=269 MG/KG; ORAL,
RABBIT: LD50=50 MG/KG; ORA L, RAT: LD50=2730 MG/KG; SKIN,
RABBIT:LD50=1250 MG/KG; CARCINOGENICITY - ACGIH: A4 - NOT
CLASSIFIABLE AS HUMAN CARCIN. EPIDEMIOLOGY - NO INFO AVAIL.
TETRAGENICITY - EMBRYO OR FETUS: STUNTED FETUS, IHL -HAMSTER
TCLO=8000 PPM/1H. SPECIFIC DEVELOPMENTAL ABNORMS: MUSCULOSKELETAL,
ORL-HAMSTER TCLO=300 MG/KG. REPRO EFTS - FERTILITY:
POST-IMPLANTATION MORTALITY, ORL-HAMSTER TDLO=400 MG/KG &
IHL-HAMSTER TC LO=5000 PPM/1H. (OTHER INFO)
===================== Ecological Information =====================
Ecological:EXOTOXICITY: FATHEAD MINNOW (HARD WATER) TLM=1150 PPM/24H.
ENVIRONMENTAL FATE: NO INFO REPORTED. PHYSICAL/CHEMICAL: NO INFO
AVAIL. OTHER: NONE. OTHER INFO: ADVICE IMMED (SHOW LABEL WHERE
POSS). WGK (W ATER DANGER/PROT) CAS #75-05-8: 2. CANADA: CAS
#75-05-8 IS LISTED ON CANADA'S DSL/NDSL LIST, HAS A WHMIS
CLASSIFICATION OF B2, D1B, D2B. IT IS NOT LISTED ON CANADA'S INGRED
DISCLOSURE LIST. EXPOS LIMS : CAS #75-05-8: OEL-ARAB REPUBLIC OF
EGYPT:TWA 40 PPM (70 MG/M3); SKIN OEL-AUSTRALIA: TWA 40 PPM (70
MG/M3); STEL 60 PPM; SKIN OEL-AUSTRIA; TWA 40 PPM (70 MG/M3)
OEL-BELGIUM:TWA 40 PPM (67 MG/M3); STE L 60 PPM (10 MG/M3);
(TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: CAS #75-05-8: WASTE #U00 3 (IGNITABLE
WASTE; TOXIC WASTE).
=================== MSDS Transport Information ===================
Transport Information:SHIPPING NAME - US DOT: ACETONITRILE; IATA: NO
INFO AVAIL; RID/ADR: NO INFO AVAIL. IMO: NO INFO AVAIL.
ACETONITRILE. HAZ CLASS - US DOT: 3; IMO: 3(6.1). UN NUMBER: US
DOT: UN1648; IMO: UN1648. PACKING GROUP: US DOT: II; IMO: II.
ADDNL INFO: IMO: FLASHPOINT 6C. ECOLOGICAL INFO: SKIN
OEL-DENMARK:TWA 40 PPM (70 MG/M3); STEL 60 PPM (10 MG/M3);
OEL-FINLAND: TWA 40 PPM (70 MG/M3); STEL 60 PPM (10 MG/M3) ;
OEL-FRANCE: TWA 50 MG/M3; STEL 100 MG/M3; SKIN JAN9 OEL-THE
NETHERLANDS: TWA 40 PPM (70 MG/M3) OEL-THE PHILIPPINES: TWA 40 PPM
(70 MG/M3) OEL-RUSSIA: STEL 10 MG/M3; OEL-SWITZERLAND: TWA 40 PPM
(70 M G/M3); STEL 80 PPM; (STATE REG INFO)
===================== Regulatory Information =====================
SARA Title III Information:CAS #75-05-8: SARA SECTION 302(RQ): FINAL
RQ=5000 LBS (2270 KG). SECTION 302(TPQ): NONE OF CHEMICALS IN
PRODUCT HAVE TPQ. SARA CODES: ACUTE, CHRONIC, FLAMMABLE. SECTION
313: MATERIAL CONTAINS ACETONIT RILE (CAS #75-05-8, 99%) WHICH IS
SUBJECT TO REPORTING REQS OF SECTION 313 OF SARA TITLE III & 40 CFR
PART 373.
Federal Regulatory Information:CAS #75-05-8: TSCA: LISTED ON TSCA
INVENTORY. HLTH & SFTY REPORTING LIST: EFTIVE DATE: OCT 4, 1982;
SUNSET DATE: OCT 4, 1992. CHEM TEST RULES: NONE OF CHEMS IN PROD
UNDER CHEM TEST RULE. SECTION 12B:NONE OF CHEMS LISTED UNDER TSCA
SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMS IN MATL
HAVE SNUR UNDER TSCA. CLEAN AIR ACT: LISTED AS HAZ AIR POLLUTANT
(HAP). MATL DOES NOT CNTN ANY CLASS 1 OR CLASS 2 OZONE DEPLETORS.
CLEAN WATER ACT: NONE OF CHEMS IN PROD LISTED AS HAZ SUBSTANCES
UNDER C WA. NONE OF CHEMS LISTED AS PRIORITY OR TOX POLLUTANTS
UNDER CWA. NONE CONSIDERED HIGHLY HAZ BY OSHA.
EUROPEAN/INTERNATIONAL (OTHER INFO)
State Regulatory Information:CAS #75-05-8 CAN BE FOUND ON FOLLOWING
STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, FLORIDA,
PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO SIGNIFICANT
RISK LEVEL: NONE OF CHEMS IN THIS P ROD ARE LISTED. TRANSPORT INFO:
SKIN OEL-TURKEY: TWA 40 PPM (70 MG/M3) OEL-UNITED KINGDOM:TWA 40
PPM (70 MG/M3); STEL 60 PPM; OEL IN BULGARIA, COLOMBIA, JORDAN,
KOREA CHECK ACGIH. TLV OEL IN NEW ZEALA ND, SINGAPORE, VIETNAM
CHECK ACGIH TLV.
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:FERROUS SULFATE,HEPTAHYDRATE
CAGE:63415
CAGE:60777
CAGE:63415
============= Composition/Information on Ingredients =============
Ingred Name:FERROUS SULFATE (SARA III)
CAS:7782-63-0
RTECS #:NO8510000
Fraction by Wt: >99.0%
OSHA PEL:1 MG FE/M3
ACGIH TLV:1 MG FE/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:OTHER COMPONENTS (CL,PO*4,CU,FE,MN,ZN,INSOLUBLE MATTER)
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL MOUSE 1520 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE- INHALATION MAY CAUSE IRRITATION
OF THE RESPIRATORY TRACT. SKIN CONTACT MAY CAUSE IRRITATION.
CONTACT WITH THE EYE MAY CAUSE SEVERE IRRITAITON & CORROSIVE
ACTION. CORROSIVE AND TOXIC BY INGESTIO N. CHRONIC- DERMATITIS,
CONJUNCTIVITIS,REPRODUCTIVE EFFECTS (IN ANIMALS).
Effects of Overexposure:EYE:SEVERE IRRITATION. SKIN:MILD
IRRITATION;CONTACT DERMATITIS. INHALED:RESPIRATORY
IRRITATION,COUGHING. INGESTION:G/I
IRRITATION,NAUSEA,VOMITING,DIARRHEA,ABDOMINAL PAIN.
Medical Cond Aggravated by Exposure:NOT KNOWN
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:WASH WITH
SOAP & WATER. EYE:FLUSH WITH WATER FOR 15 MINUTES, HOLDING EYELIDS
OPEN. INHALED:REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.
ORAL:IF C ONSCIOUS, INDUCE VOMITING OR PROVIDE GASTRIC LAVAGE. CALL
PHYSICIAN IMMEDIATELY. NOTE TO PHYSICIAN:ANTIDOTE- DEFEROXAMINE, 15
MG/KG/HOUR BY CONTINOUS IV INFUSION TO A MAXIMUM OF 80 MG/KG/12
HOURS.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE WATER SPRAY, HALON, CARBON DIOXIDE, STANDARD
FOAM OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS/AVOID BREATHING VAPORS OR DUSTS. KEEP UPWIND. MOVE
CONTAINER FROM FIRE AREA IF POSSIBLE.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HZARD WHEN EXPOSED TO
HEAT OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP MATERIAL, PLACE IN A CONTAINER AND
HOLD FOR WASTE DISPOSAL. VENTILATE AREA AND WASH SPILL SITE AFTER
MATERIAL PICKUP IS COMPLETE. DO NOT FLUSH WITH WATER TO DRAIN.
Neutralizing Agent:SODIUM BICARBONATE, LIME
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINER AWAY
FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:DO NOT GET IN EYES OR ON SKIN. DO NOT GENERATE DUST.
DO NOT BREATHE DUST, MIST OR FUMES. KEEP OUT OF REACH OF CHILDREN.
DO NOT TAKE INTERNALLY. WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR CONDITIONS WHERE EXPOSURE TO DUST OR FUMES
IS APPARENT, A NIOSH APPROVED RESPIRATOR FOR DUST MISTS AND FUMES
APPROPRIATE TO THE CONCENTRATION MAY BE WORN. IN EMERGENCY, WEAR
SELF-CONTAINED BREATHI NG APPARATUS OPERATED IN + PRESSURE.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHING
AND EQUIPMENT, EYEWASH FOUNTAIN, EMERGENCY SHOWER
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, DRINKING OR
SMOKING.
Supplemental Safety and Health
PH OF A 10% SOLUTION IS 3.7.
================== Physical/Chemical Properties ==================
HCC:C3
Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES
Decomp Temp:Decomp Text:NOT KNOWN
Spec Gravity:1.898
pH:3.7
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:15.65% @ 68F (20C)
Appearance and Odor:HYGROSCOPIC, BLUE-GREEN, MONOCLINIC CRYSTALS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIES, ARSENIC TRIOXIDE+SODIUM NITRATE, METHYL ISOCYANOACETATE,
OXIDIZERS
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY RELEASE
TOXIC FUMES OF SULFUR OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE DISPOSAL TO BE PERFORMED IN COMPLIANCE
WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. REPORTABLE
QUANTITY (RQ) IS 1000 LBS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:121 3636 REV. BATH & REPLEN. E-6,E-7 & E-6
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 95 - 99%
Other REC Limits:NONE SPECIFIED
Ingred Name:PROPIONIC ACID (SARA III)
CAS:79-09-4
RTECS #:UE5950000
Fraction by Wt: 1 - 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:(NITRILOTRIS(METHYLENE)TRIPHOSPHONIC ACID, K SALT
CAS:2235-43-0
Fraction by Wt: 5 - 10%
Other REC Limits:NONE SPECIFIED
Ingred Name:STANNOUS CHLORIDE
CAS:7772-99-8
RTECS #:XP8700000
Fraction by Wt: 1 - 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:PROPIONIC ACID (SARA III)
CAS:79-09-4
RTECS #:UE5950000
Fraction by Wt: 1 - 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:PHOSPHONIC ACID (NITRILO TRIS(METHYLENE))TRI-
CAS:6419-19-8
RTECS #:SZ9860000
Fraction by Wt: 5 - 10%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE- EYE:NO SPECIFIC HAZARD KNOWN.
HOWEVER, ANY MATERIAL THAT CONTACTS THE EYE MAY BE IRRITATING.
SKIN/INHALATION:LOW HAZARD FOR RECOMMENDED HANDLING. ORAL:NONE
KNOWN. CHRONIC-NONE KNOWN.
Effects of Overexposure:ANY MATERIAL THAT CONTACTS THE EYE MAY BE
IRRITATING. LOW HAZARD FOR RECOMMENDED HANDLING.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH SENSITIVE SKIN MAY
BE MORE ADVERSELY AFFECTED.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:FLUSH WITH
PLENTY OF WATER. SKIN:FLUSH WITH PLENTY OF SOAP AND WATER.
INHALATION:REMOVE TO FRESH AIR. INGESTION:SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:AS APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH MATERIAL TO SEWER WITH LARGE AMOUNTS OF
WATER IF REGULATIONS ALLOW.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE AND HANDLING- NONE.
Other Precautions:WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WITH GOOD VENTILATION.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT.
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
THIS IS FOR FRESHLY MADE WORKING SOLUTION. FOR ORIGINAL, SEE PIN A,
SAME NSN.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres: 18 @ 20C
Vapor Density: 0.6
Spec Gravity:1.01
pH:5.8
Evaporation Rate & Reference:0.4 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID
Percent Volatiles by Volume: 95
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE PRODUCT MAY
REASONABLY COME INTO CONTACT.
Stability Condition to Avoid:FIRE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE OR LOCAL LAWS.
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===================== Product Identification =====================
Product ID:BROMICHLOR (524-3), 7103
CAGE:NCHEM
CAGE:NCHEM
============= Composition/Information on Ingredients =============
Ingred Name:HYDANTION, 3-BROMO-1-CHLORO-5,5-DIMETHYL-;
(1-BROMO-3-CHLORO-5, 5-DIMETHYL-HYDANTOIN)
CAS:126-06-7
RTECS #:MT9195500
Fraction by Wt: 93.5%
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 1.39 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE DERMAL TOXICITY IS 2.0 G/KG.
SKIN: CORROSIVE TO SKIN. EYE: CORROSIVE TO EYES. INHAL: MAY BE
IRRITATING TO THROAT, NASAL PASSAGES AND MUCOUS MEMBRANES. INGEST:
CORROSIVE TO THROAT AND STOMACH.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: RINSE IMMEDIATELY WITH WATER. SEEK MEDICAL ATTENTION.
EYES: FLUSH IMMEDIATELY WITH PLENTY OF WATER FOR AT LEAST 15 MIN.
CONSULT PHYSICIAN. INHAL: MOVE TO FRESH AIR. IF IRRITATION
PERSISTS, SEEK MEDICAL ATTENTION. INGEST: FEED BREAD SOAKED IN
MILK, FOLLOWED BY OLIVE OIL (OR COOKING OIL). DO NOT INDUCE
VOMITING.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:MAY RELEASE HYDRO. BROMIDE/BROMINE. WEAR
NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DO NOT USE AMMONIUM PHOSPHATE
EXTINGUISHERS.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP SPILLED MATERIAL AND PLACE IN A
CLEAN, SUITABLE CONTAINER. AVOID CONTACT AND INHALATION OF DUST.
WASH AREA OF SPILL WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
AVOID PROLONGED EXPOSURE TO VAPORS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED DUST MASK.
Ventilation:GOOD LOCAL EXHAUST.
Other Protective Equipment:APRON. EMERGENCY EYEWASH AND DELUGE SHOWER
MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
WASTE DISPOSAL: FOR APPROVED ALTERNATIVE PROCEDURES.
================== Physical/Chemical Properties ==================
HCC:T6
Solubility in Water:0.15G/100G@77F
Appearance and Odor:WHITE GRANULAR SOLID WITH FAINT HALOGEN ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ORGANIC AND OTHER STRONG REDUCING AGENTS.
Stability Condition to Avoid:MIX ONLY WITH WATER.
Hazardous Decomposition Products:HYDROGEN BROMIDE, BROMINE, HCL,
CHLORIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:PESTICIDE, SPRAY MIXTURE OR RINSATE THAT CANNOT
BE USED OR CHEMICALLY REPROCESSED SHOULD BE DISPOSED OF IN A
LANDFILL APPROVED FOR PESTICIDES, OR BURIED IN A SAFE PLACE AWAY
FROM WATER SUPPLIES. CONSU LT YOUR LOCAL, STATE & FED GUIDELINES
(SUPP DATA)
| 1 | gloves_mandatory |
=======================================================
Product ID: CT-818 HEAVY DUTY CLEANER 1 GAL JUG
Cage: 0LZ78
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 0LZ78
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:MOD EYE IRRIT. SLIGHT SKIN IRRITANT. SLIGHT SKIN
ABSORPTION HAZ. SLIGHT INHAL HAZ. SLIGHT INGEST HAZ. CHRONIC:PRLNGD/RPTD
CNTCT MAY CAUSE SKIN TO BECOME DRY OR CRACKED. MAY BE DERM SENSIT. SIGNS
/SYMPS:MAY CAUSE MOD EYE IRRIT, INCL BURNING SENSATION, TEARING, REDNESS OR
SWELLING. SKIN ABSORP: (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:EXTENSIVE, PRLNGD/RPTD EXPOS TO
MATL CAN RSLT IN SIGNIF ABSORP. MAY PRODUCE SKIN IRRIT. INGEST:MAY BE
SLIGHTLY TOX IF INGESTED IN LRG QTYS. CHRONIC:NO INFO AVAIL. ANIMAL STUDIES
CLEARLY DEMON STRATED DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUE,
BLOOD, LIVER & KIDNEYS ASSOC W/ADMIN OF ETHYLENE(SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:MOVE TO FRESH AIR IMMED. GIVE O*2 OR ARTF RESP AS NEEDED. GET
MD. IMMED ACTION ESSENTIAL. EYE:IMMED RINSE W/CLEAN WATER FOR 20-30 MINS.
RETRACT EYEIDS OFTEN. GET MD. SKIN:REMOVE CONTAM CLTHG AS NEEDED. WASH SKIN
THORO W/MILD SOAP/WATER. FLUSH W/LUKEWARM WATER FOR 15 MINS. IF STICKY, USE
WATERLESS CLEANER FIRST. INGEST:GIVE LUKEWARM WATER (PINT) IF VICTIM
COMPLETELY CONSCIOUS/ALERT.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SOAK UP SPILLS WITH INERT SOLIDS, SUCH AS CLAY OR
DIATOMACEOUS EARTH AS SOON AS POSSIBLE. SWEEP/SHOVEL INTO SUITABLE DISPOSAL
CONTAINERS. SPILL AREA MAY BE SLIPPERY. SPREAD GRANULAR COVER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: CONTAM PROD/SOIL/WATER SHOULD NOT BE DESIGNATED RCRA
HAZARDOUS WASTE. LANDFILL SOLIDS AT PERMITTED SITES. USE REGISTERED
TRANSPORTERS. COMPLY WITH APPLICABLE REGULATIONS. DISPOSAL MUST BE IN
ACCORDANC E WITH LOCAL, STATE & FEDERAL REGULATIONS (FP N).
Handling And Storage Precautions: COMBUSTIBLE UPON EVAPORATION OF ALL WATER.
KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. STORE AWAY FROM HEAT, OPEN
FLAME AND DIRECT SUNLIGHT.
Other Precautions: STORE DRUMS WITH BUNG IN UP POSITION. FOLLOW STANDARD PLANT
PROCEDURES OR SUPERVISOR'S INSTRUCTIONS FOR DECONTAMINATION OPERATIONS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >190F,>88C
Extinguishing Media: CARBON DIOXIDE, FOAM, WATERSPRAY.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). FIGHT FIRE FROM SAFE DISTANCE/PROTECTED LOCATION. USE
WATERSPRAY OR WATERFOG FOR COOLING.
Unusual Fire/Explosion Hazard: MAY BECOME COMBUSTIBLE IF AQUEOUS CARRIER
EVAPORATES.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NO SPECIAL RESPIRATORY PROTECTION EQUIPMENT IS
RECOMMENDED UNDER NORMAL CONDITIONS OF ANTICIPATED USE WITH ADEQUATE
VENTILATION. NIOSH/MSHA APPROVED RESPRIATOR APPROPRIATE FOR EXPOSURE OF
CONCERN (FP N).
Ventilation: NO SPECIAL VENTILATION IS USUALLY REQUIRED BEYOND THAT NEEDED FOR
NORMAL COMFORT CONTROL.
Other Protective Equipment: APRONS.
Work Hygienic Practices: USE GOOD PERS HYGIENE PRACT. WASH HANDS BEFORE EATING,
DRINKING, SMOKING, OR USING TOILET FACILITIES. IMMED (SUPDAT)
Supplemental Safety and Health: HYGIENE PRACT:REMOVE SOILED CLOTHING/WASH THORO
BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP & WATER. EFTS OF
OVEREXP:GLYCOL MONOBUTYL ETHER (EGBE) (EXTRACTED FROM DHHS (NIOSH)
PUBLICATION NO. 90-118) (FP N). FIRE FIGHT PROC:SPRAY OR WATERFOG FOR
COOLING. NOTE: LR VERSION CONTAINS ADDITIONAL INFORMATION.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 212F,100C
Vapor Pres: >1
Vapor Density: >1
Spec Gravity: 0.999(H*2O=1)
PH: 8.9
Appearance and Odor: CLEAR, COLORLESS LIQUID WITH A MILD ODOR
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: KEEP AWAY FROM HEAT, SPARKS, AND OPEN FLAME.
Materials To Avoid: STRONG OXIDIZERS AND STRONG REDUCING AGENTS.
Hazardous Decomposition Products: INCOMPLETE COMBUSTION MAY RELEASE POISONOUS
CARBON MONOXIDE AND OTHER TOXIC VAPORS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: CT-818 HEAVY DUTY CLEANER 1 GAL JUG
Cage: 0LZ78
Company Name: CHEM-TECH INTL INC
Street: 1113 KERRIA AVE
Zipcode: 78501-3830
Label Required IND: Y
Date Of Label Review: 03/31/1993
Status Code: C
Label Date: 03/31/1993
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE UPON EVAPORATION OF ALL WATER. STORE AWAY
FROM HEAT, OPEN FLAME & DIRECT SUNLIGHT. ACUTE:MODERATE EYE IRRITANT.
SLIGHT SKIN IRRITANT. SLIGHT SKIN ABSORPTION HAZARD. SLIGHT INHALATION HAZAR
D. SLIGHT INGESTION HAZARD. CHRONIC:PROLONGED OR REPEATED CONTACT MAY CAUSE
SKIN TO BECOME DRY OR CRACKED. MAY BE DERMATITIS SENSITIZER. ANIMAL STUDIES
CLEARLY DEMONSTRATED DOSE-RELATED ADVERSE EFFECT S ON CNS, BLOODFORMING
TISSUE, BLOOD, LIVER & KIDNEYS ASSOCIATED W/ADMINISTRATION OF ETHYLENE
GLYCOL MONOBUTYL ETHER.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:5962, ELECTRON TUBE
Preparer's Name:ROBERT A. JUCIUS
CAGE:JO931
CAGE:JO931
CAGE:63060
============= Composition/Information on Ingredients =============
Ingred Name:NICKEL (SARA III)PRODUCT YIELDS 0.05 TO 0.10 MICROCURIES
CAS:7440-02-0
RTECS #:QR5950000
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:METAL PRODUCTS IN THE NATURAL STATE DO
NOT PRESENT AN INHALATION, INGESTION OR CONTACT HAZARD, HOWEVER,
OPERATIONS SUCH AS BURNING, WELDING, SAWING, BRAZING AND GRINDING
MAY RELEASE FUMES/DUSTS WHICH MAY PRESENT HEALTH HAZARDS IF TLV'S
AREEXCEEDED. THE RADIOACTIVE MATERIAL IN THE DEVICES REPRESENT NO
SIGNIFICANT HAZRD
Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS
CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:BECAUSE OF THE AMOUNT OF NICKEL-63 CONTAINED IN
THE PRODUCT THIS SECTION IS NOT CONSIDERED APPLICABLE BY
MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:NONE SPECIFIED BY MANUFACTURER.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:EXTINQUISH WITH AGENT SUITABLE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF
CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:SOME OF MATERIAL MAY BURN. CONTAINER MAY
EXPLODE IN HEAT OF FIRE.
================== Accidental Release Measures ==================
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION.
PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN
AREA FOR RADIOACTIVE MATERIALS.
Other Precautions:THE MICROCURIE QUANTITIES OF NICKEL-63 REPRESENT NO
SIGINIFICANT EXTERNAL EXPOSURE HAZARD SINCE THE LOW ENERGY BETAS
EMITTED CANNOT PENETRATE THE OUTER SKIN LAYER. THE MATERIAL IS
CONTAINED IN AN INER T SEALED VESSEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SPECIFIED BY MANUFACTURER.
Ventilation:PROVIDE MECHANICAL (GENERAL/LOCAL EXHAUST) VENTILATION TO
MAINTAIN CONCENTRATIONS 2300F,>126
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:ABOUT 7
Evaporation Rate & Reference:NIL
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GRAYISH TO BLACK PLAITING ON ANODES
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS WITH STRONG ACIDS
Stability Condition to Avoid:PHYSICAL DAMAGE
Hazardous Decomposition Products:HYDROGEN GAS, METALLIC DUST/FUMES
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH
DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:PEEL-PLY E-761
CAGE:57929
CAGE:57929
============= Composition/Information on Ingredients =============
Ingred Name:WOVEN NYLON FABRIC
Minumum % Wt:35.
Maxumum % Wt:60.
Ingred Name:PROPRIETARY CATALYZED EPOXY MIXTURE
Minumum % Wt:40.
Maxumum % Wt:65.
Ingred Name:RESIDUAL ORGANIC SOLVENTS
< Wt:2.
Ingred Name:ACETONE
CAS:67-64-1
RTECS #:AL3150000
< Wt:1.
OSHA PEL:2400 MG/M3;750 PPM
ACGIH TLV:1780 MG/M3;750 PPM
ACGIH STEL:2380 MG/M3;1000 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:METHYL ETHYL KETONE
CAS:78-93-3
RTECS #:EL6475000
< Wt:1.
OSHA PEL:590 MG/M3;200 PPM
ACGIH TLV:590 MG/M3;200 PPM
ACGIH STEL:885 MG/M3;300 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED SKIN EXPOSURE CAN CAUSE
MODERATE IRRITATION AND/OR DERMATITIS. EXCESSIVE INHALATION CAN
CAUSE NASAL AND/OR RESIRATORY IRRIATION, FATIGUE, WEAKNESS,
CONFUSION, EUPHORIA, DIZZINESS AND HEADACH E. INGESTION CAN CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING AND DIARRHEA.
Explanation of Carcinogenicity:NO SIGNIFICANT CARCINOGENIC OR
REPRODUCTIVE EFFECTS HAVE BEEN OBSERVED IN ANIMAL TESTS
Medical Cond Aggravated by Exposure:PREEXISTING DERMAL, BRONCHIAL AND
RESPIRATORY PROBLEMS
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/ WATER FOR 15 MINS. SKIN: WASH WITH MILD SOAP
AND WATER.INGESTION: INDUCE VOMITING. CALL A PHYSICIAN
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=-26.1C, -15.F
Extinguishing Media:DRY CHEMICAL,WATER FOG
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FLAMMABLE LIMITS (% VOLUME IN AIR)
LFL=2.6, UFL = 12.8 (ACETONE)
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP SEALED TO AVOID ABSORPTION OF
WATER FROM HUMID AIR. KEEP AWAY FROM HEAT. STORE UNDER CONTROLLED
LOW TEMPERATURE CONDITION. STORE AT 0 DEG F IF POSSIBLE. AFTER LOW
TEMPERATURE STORAGE, ALLOW PACKA GE TO RETURN TO ROOM TEMPERATURE
BEFORE OPENING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATORY PROTECTION. N/A WITH
LOCAL EXHAUST
Ventilation:LOCAL EXHAUST RECOMMENDED WHEN CURING. MECHANICAL
(GENERAL) RECOMMENDED
Other Protective Equipment:AS REQUIRED TO PREVENT SKIN CONTACT
Work Hygienic Practices:WASH THOROUGHLY AFTER WORKING, AND BEFORE
EATING OR DRINKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:INSOLUBLE
Appearance and Odor:NATURAL COLOR PRE-IMPREGNATED NYLON CLOTH
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES AND OXIDIZERS - WILL CURE
Stability Condition to Avoid:ELEVATED TEMPERATURES WILL CURE.
UNCONTROLLED HEAT MAY CAUSE RUNAWAY EXOTHERM
Hazardous Decomposition Products:ALDEHYDES, PHENOLICS, CARBON MONOXIDE
AND/OR DIOXIDES AND OXIDES OF NITROGEN
=================== Toxicological Information===================
Toxicological Information:RTECS#: CAS# 85-85-8 UNLISTED. LD50/LC50: NOT
AVAILABLE. CARCINOGENICITY: 2-NAPHTHALENOL, 1-(2-PYRIDINYLAZO)--
NOT LISTED BY ACGIH, IARC, NIOSH, NTP, OR OSHA. EPIDEMIOLOGY: NO
DATA AVAIL. TERATOGENICI TY: NO DATA AVAIL. REPRODUCTIVE EFTS: NO
DATA AVAIL. NEUROTOXICITY: NO DATA AVAIL. MUTAGENICITY: NO DATA
AVAIL. OTHER STUDIES: NO DATA AVAIL.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAIL. ENVIRONMENTAL FATE: NOT AVAIL.
PHYSICAL/CHEMICAL: NOT AVAIL. OTHER: NOT AVAIL.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS IN AN APPROVED LAND FILL
=================== MSDS Transport Information ===================
Transport Information:US DOT: NO INFO AVAIL. IMO: NO INFO AVAIL. IATA:
NO INFO AVAIL. RID/ADR: NO INFO AVAIL. CANADIAN TDG: NO INFO AVAIL
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF CHEMS IN THIS MATL
HAVE AN RQ. SECTION 302 (TPQ): NONE OF CHEMS IN THIS PROD HAVE A
TPQ. SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER SECTION 313.
Federal Regulatory Information:TSCA CAS# 85-85-8 IS LISTED ON TSCA
INVENTORY. HLTH & SFTY RPTG LIST: NONE OF CHEMS ARE ON HLTH & SFTY
RPTG LIST. CHEM TEST RULES: NONE OF CHEMS IN THIS PROD ARE UNDER
CHEM TEST RULE. SECTION 12B: NON E OF CHEMS ARE LISTED UNDER TSCA
SECTION12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMS IN THIS
MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL DOES NOT CNTN
ANY HAZ AIR POLLUTANTS, CLASS 1 OZON E DEPLETORS, OR CLASS 2 OZONE
DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN THIS PROD ARE LISTED
AS H AZ SUBSTANCES, PRIORITY POLLUTANTS OR TOXIC POLLUTANTS UNDER
CWA. OSHA: NONE OF CHEMS IN THIS PROD ARE CONSIDERED HIGHLY HAZ.
State Regulatory Information:2-NAPHTHALENOL, 1-(2-PYRIDINYLAZO)- IS NOT
PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ. CALIFORNIA
NO SIGNIFICANT RISK LEVEL: NONE OF CHEMICALS TO THIS PRODUCT ARE
LISTED. EUROPEAN/INTERNATI ONAL REGULATIONS: EUROPEAN LABELING
I/A/W EC DIRECTIVES. HAZARD SYMBOLS: XN. RISK PHRASES: R 22 HARMFUL
IF SWALLOWED. SFTY PHRASES: S 24/25 AVOID CONT W/SKIN & EYES.
WGK(WATER DANGER/PROTECTION) CAS 8 5-85-8: NO INFO AVAIL. CANADA:
CAS# 85-85-8 IS LISTED ON CANADA'S DSL/NDSL LIST. THIS PROD HAS
WHMIS CLASSIFICATION OF NOT CONTROLLED. CAS #85-85-8 IS NOT LISTED
ON CANADA'S INGRED DISCLOSURE LIST.
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:PRIMER CTG C/N ALKYD ID 727002
CAGE:PRATT
CAGE:PRATT
CAGE:61196
============= Composition/Information on Ingredients =============
Ingred Name:VM&P NAPHTHA (SOLVENT) (VAPOR PRESSURE 40 MM HG @ 20 C)
(LFL 1.0; UFL 6.0)
CAS:8030-30-6
RTECS #:DE3030000
Fraction by Wt: 5%
Other REC Limits:*1350/1800 MG/CU.M
OSHA PEL:300PPM;400PPM STEL*
ACGIH TLV:300 PPM; 1350 MG/M3
Ingred Name:ISOBUTYL ALCOHOL (SOLVENT) (VAPOR PRESSURE 10 MM HG @ 20C)
(LFL: 1.0/UFL: 11.0)
CAS:78-83-1
RTECS #:NP9625000
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ZINC CHROMATE (PIGMENT) (SARA 313)
CAS:13530-65-9
RTECS #:GB3290000
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.1 MG/M3 CEIL
ACGIH TLV:0.01 MG/M3 CEIL
Ingred Name:ISOBUTYL ACETATE (SOLVENT) (LFL: 2.0/UFL: 11.0)
CAS:110-19-0
RTECS #:AI4025000
Fraction by Wt: 20%
Other REC Limits:NONE SPECIFIED
OSHA PEL:150 PPM/700 MG/CU.M
ACGIH TLV:150 PPM/700 MG/CU.M
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TOLUENE (SOLVENT) (SARA 313) (VAPOR PRESSURE 22 MM HG @
20C) (LFL: 1.7/UFL 7.1)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <5%
Other REC Limits:*375MG/CU.M-560 STEL
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:N-HEPTANE (SOLVENT) (VAPOR PRESSURE 40 MM HG @ 20C) (LFL:
1.0/UFL: 7.0)
CAS:142-82-5
RTECS #:MI7700000
Fraction by Wt: 5%
Other REC Limits:*1600/2000 MG/CU.M
OSHA PEL:500 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9293
Ingred Name:HEXANE (SOLVENT) (VAPOR PRESSURE 120 MM HG @ 20C) (LFL:
1.0/UFL: 8.0)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ISOPROPYL ALCOHOL (SOLVENT) (VAPOR PRESSURE 33 MM HG @ 20C)
(LFL: 3.0/UFL: 13.0)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 5%
Other REC Limits:*980/1225 MG/CU.M
OSHA PEL:400 PPM/500 STEL*
ACGIH TLV:400 PPM/500 STEL*
Ingred Name:NITROCELLULOSE (RESIN)
CAS:9004-70-0
RTECS #:QW0970000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:NONE ESTABLISHED
ACGIH TLV:NONE ESTABLISHED
Ingred Name:METHYL ETHYL KETONE (SOLVENT) (SARA 313) (VAPOR PRESSURE 70
MM HG @ 20C) (LFL: 2.0/UFL: 10.0)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: <5%
Other REC Limits:*590/885 MG/CU.M
OSHA PEL:200 PPM/300 STEL*
ACGIH TLV:200 PPM/300 STEL*
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGEST: GASTROINTESTINAL
IRRIT/NAUSEA/VOMIT. ASPIR OF MATL INTO LUNG-POSS CHEM
PNEUMONITIS-POSS FATAL. INHAL: NOSE/ THROAT IRRIT. HIGH CONC-ACUTE
CNTRL NERV SYS DEPRESS W/HEADACHE/DIZZINESS/ NAUSEA/CO NFUSION.
EYE: SEVERE IRRIT/CORNEAL DAMAGE. SKIN: LIQUID MAY BE ABSORBED
THROUGH SKIN IN HARMFUL AMOUNTS-SEVERE IRRITATIO
Explanation of Carcinogenicity:ZINC CHROMATE HAS BEEN LISTED AS A
POTENTIAL CARCINOGEN.
Effects of Overexposure:LUNG CANCER. LIVER DAMAGE. PERIPHERAL NERVOUS
SYSTEM DAMAGE. PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
INTENTIONAL MISUSE MAY BE HARMFUL OR FATAL. TOLUENE HAS BEEN FOUND
TO CAUSE KIDNEY, LUNG AND SPL EEN DAMAGE TO LAB ANIMALS. METHYL
ETHYLKETONE MAY BE EMBRYOTOXIC, FETOTOXIC AND TERATOGENIC.
Medical Cond Aggravated by Exposure:N/K NOTES TO PHYSICIAN: ANY
TREATMENT THAT MIGHT BE REQUIRED FOR OVEREXPOSURE SHOULD BE
DIRECTED AT THE CONTROL OF SYMPTOMS AND THE CLINICAL CONDITIONS.
======================= First Aid Measures =======================
First Aid:INGEST: DO NOT INDUCE VOMITING. CALL POISON CTR, HOSP EMERG
ROOM OR DR IMMED. INHAL: REMOVE TO FRESH AIR IMMED. IF BREATHING
STOPPED-GIVE ARTIFICIAL RESP. KEEP WARM/QUIET. GET MED ATTN IMMED.
EYE: FLU SH WITH LARGE AMOUNTS OF WATER, LIFTINGLIDS OCCASIONALLY
FOR 15 MINS. GET MED ATTN. SKIN: IMMED FLUSH CONTAM AREA WITH LARGE
AMOUNTS OF WATER. REMOVE CONTAM CLOTHING AS WATER IS APPLIED.
CONSULT DR.
===================== Fire Fighting Measures =====================
Flash Point:-9F,-23C
Autoignition Temp:Autoignition Temp Text:572F
Lower Limits:1.0%
Upper Limits:13.0%
Extinguishing Media:NFPA CLASS B FIRE EXTING (CO2, ALL-PURPOSE DRY
CHEM, ALCOHOL FOAM) FOR FLAMM LIQ FIRES. POLYMER FOAM PREFERRED-LG
FIRES
Fire Fighting Procedures:WEAR SCBA. WTR MAY BE INEFFECT-MAY USE TO COOL
EXPOS CNTNRS TO PREVENT PRESS BLDUP & POSS AUTO-IGNIT OR EXPLOSION
W/ EXTREME HEAT. PREFER FOG NOZZLES IF WTR USE
Unusual Fire/Explosion Hazard:EMERG CONDITIONS-OVEREXPOSURE TO DECOMP
PRODUCTS-MAY CAUSE HEALTH HAZ. SYMPTOMS DELAYED. OBTAIN MED ATTN.
DANGER- EXTREMELY FLAMM. VAPORS MAY CAUSE FLASH FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR RESP, EYE/HAND/BODY PROTECT APPROP
(DEPEND-SIZE OF SPILL/EXPOS). EVAC AREA. ELIM ALL IGNIT SRCS
(FLAMES/HOT SURFACES/SRCS OF ELECT/STATIC/FRICTNL SPARKS).
DIKE/CONTAIN SPILL W/INERT MATL (SAND/EA RTH). TRANS LIQ TO COVERED
METAL CNTNR FOR RECVRY#
Neutralizing Agent:N/K SYMP-FLU-LIKE ILL, W/FEVER/CHILLS/COUGH. AIR
PURFYING/SUPPLIED AIR RESP+
======================Handling and Storage ======================
Handling and Storage Precautions:DONT STORE ABOVE 115F (46C). STORE LG
QTY IN COMPLIANCE W/OSHA 29CFR1910.106 +REQ DEPEND ON EXPOS LEVEL.
CONSULT QUALIFIED HEALTH/SFTY PROFESSIONAL
Other Precautions:DO NOT INGEST. CLOSE CNTNR AFTER USE. MUST NOT WASH
EMPTY CNTNRS OR REUSED FOR ANY PURPOSE. CNTNRS SHOULD BE
GROUNDED/BONDED TO THE RECEIVING CNTNR. DO NOT WELD/BRAZE/CUT ON
EMPTY CNTNR. NEVER USE PRE SS TO EMPTY. DRUM IS NOT A PRESS VESSEL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE IN WELL VENT AREA. RESTRICT VENT-NIOSH
ORGANIC VAPOR RESP. SPRAYING: POSS REQ MECH PREFILTER. CONFINED
AREAS: NIOSH/MSHA RESP W/APPROP PROTECT FACTOR. REFER TO OSHA
29CFR1910.134 "RESP PROTECT"/" RESP PROTECT A MANUAL & GUIDELINE,
Ventilation:GEN DILUT/LOCAL EXHST-SUFFIC VOL/PTRN TO KEEP CONC OF HAZ
INGRED BELOW LOWEST EXPOS LIMIT STATED. RMV DECOMP PRODUCTS++
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER.
Work Hygienic Practices:N/K ++THAT ARE GENERATED W/WELD/CUT/BRAZE
OBJECTS COATED W/PROD.
Supplemental Safety and Health
WASTE-RESIDUE OF THIS PRODUCT MAY QUALIFY AS HAZARDOUS WASTE (40 CFR
PART 261.74 - CHARACTERISTIC OF EP TOXICITY). ##PLACE ABSORB DIKE
MATL IN CVRD METAL CNTNRS FOR DISPOS. PREVENT CONTAM OF SEWERS/ST
REAMS/GROUNDWTR W/SPILLED MATL/USED ABSORB. AMERICAN INDUSTRIAL
HYGIENE ASSOCIATION."
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:156-475F
Melt/Freeze Pt:M.P/F.P Text:-50F
Decomp Temp:Decomp Text:1832F,1000C
Vapor Pres:120 @ 68F
Vapor Density:> THAN AIR
Spec Gravity:1.1
pH:4-7STD
Viscosity:200 CST
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID, SOLVENT ODOR
Percent Volatiles by Volume:72
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
Stability Condition to Avoid:EXCESSIVE HEAT (>115F (46C) AND SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, IF HEATED BY WELD/CUT-WILL
PRODUCE SMOKE/CO/CO2. OXIDES OF NITROGEN/CHROMIUM/ZINC MAY BE
GENERATED. WELD/ BRAZE
Conditions to Avoid Polymerization:TORCH CUT MATL COATED W/PROD MAY
PRODUCE METAL OXIDES. OVEREXPOS TO METAL OXIDES MAY RESULT IN
"METAL FUME FEVER".
==================== Disposal Considerations ====================
Waste Disposal Methods:ACCORDANCE W/FED/ST/LOCAL LAWS-REGS. INCINERATE
(NO CLSD CNTNRS) ONLY IN EPA PERMITTED FACILITY. OBSERVE PRECAUTION
FOR DISPOS OF FLAMM MATL. CONTAM ABSORB MAY BE DISPOS IN HAZ WASTE
LANDFILL. #DISPOS /RMV W/INERT ABSORB. USE ONLY NON-SPARKTOOLS.##
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:5760/5765 MAGENTA DEVELOPER, XCL: 5R566
CAGE:0E6G9
CAGE:0E6G9
CAGE:26921
============= Composition/Information on Ingredients =============
Ingred Name:CARRIER CONTAINING INGREDIENTS 2 AND 3
Fraction by Wt: >90%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:KAOLIN; (CU-ZN FERRITE POWDER)
CAS:66402-68-4
Fraction by Wt: >95%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:STYRENE/ACRYLATES POLYMER (SARA 313)
Fraction by Wt: <1%
OSHA PEL:100 PPM
ACGIH TLV:50PPM/100STEL, S
Ingred Name:TONER CONTAINING INGREDIENTS 5 TO 7
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POLYESTER
CAS:128781-91-9
Fraction by Wt: >90%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:2-NAPHTHALENECARBOXYLIC ACID,
3HYDROXY4[4-METHYL2SULFOPHENYL)AZO)-,CALCIUM SALT(1:1); (RED
PIGMENT)
CAS:5281-04-9
Fraction by Wt: 4-8%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <2%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT): > 5 G/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MIN RESP TRACT IRRIT MAY OCCUR
AS W/EXPOS TO LGE AMTS OF ANY NON-TOX DUST. IN A XEROX SPONSORED
CHRONIC INHAL STUDY IN RATS USING SPEC TEST TONER, VERY SLIGHT
DEGREE OF FIBROSIS WAS NOTED IN 25 % OF ANIMALS AT MIDDLE EXPOS
LEVEL (4 MG/M3) WHILE SLIGHT DEGREE OF FIBROSIS WAS OBSERVED AT
HIGHEST (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: EXPOS LEVEL (16 MG/M3) IN ALL
ANIMALS. THESE FINDINGS ARE ATTRIBUTED TO "LUNG OVERLOADING", A
GENERIC RESPONSE TO EXCESS AMTS OF ANY DUST RETAINED IN LUNGS FOR
PRLNG INTERVAL. SPEC TEST TONE R WAS 10 TIMES MORE RESP THAN
COMMERCIALLY AVAIL XEROX TONER TO COMPLY W/EPA TESTING PROTOCOL &
WOULD NOT (SUP DAT)
Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY
PRODUCT LITERATURE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: WASH
WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION:
DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE WATER, DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures:AVOID INHALATION OF SMOKE. WEAR NIOSH/MSHA
APPROVED SCBA & FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. LIKE MOST
ORGANIC MATERIALS IN POWDER FORM, WHEN DISPERSED IN AIR, IT CAN
FORM EXPLOSIVE MIXTURES.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP/VACUUM SPILLED TONER & CAREFULLY
TRANSFER INTO SEALABLE WASTE CONTR. SWEEP SLOWLY TO MIN GENERATION
OF DUST DURING CLEAN-UP. IF VACUUM IS USED, MOTOR MUST BE RATED AS
DUST TIGHT. CONDUCTIVE H OSE BONDED TO MACHINE SHOULD BE USED
TO(SUP DAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE.
Other Precautions:AVOID PROLONGED INHALATION OF EXCESSIVE DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX
EQUIPMENT. USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: FUNCTION PROPERLY IN XEROX EQUIPMENT. SPILL PROC:
REDUCE STATIC BUILD-UP. RESIDUE CAN BE REMOVED W/SOAP & COLD WATER.
GARMENTS MAY BE WASHED/DRY CLEANED, AFTER REMOVAL OF LOOSE TONER.
================== Physical/Chemical Properties ==================
Appearance and Odor:DARK RED POWDER, WITH FAINT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC.
AVOID BREATHING SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULTATION WITH THE APPROPRIATE STATE, LOCAL,
AND FEDERAL WASTE DISPOSAL AUTHORITIES IS ADVISED. INCINERATE ONLY
IN A CLOSED CONTAINER.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:BUILD 50 PART B
CAGE:0J2D7
CAGE:0J2D7
============= Composition/Information on Ingredients =============
Ingred Name:POLYOXYALKYLENEAMINE
Fraction by Wt: 45-55%
Ingred Name:NONYL PHENOL
CAS:25154-52-3
RTECS #:SM5600000
Fraction by Wt: 30-40%
Ingred Name:AMINO ETHYL PIPERAZINE
CAS:10171-78-5
RTECS #:TX8050000
Fraction by Wt: 10-20%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 0.58 G/KG
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: TISSUE IRRITATION & PERMANENT
INJURY. SKIN: CORROSIVE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: TISSUE IRRITATION & PERMANENT INJURY.
SKIN: CORROSIVE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER. SKIN: WASH W/MILD SOAP &
WATER. DON'T COVER. TREAT AS 1ST DEGREE BURN. INHALATION: REMOVE TO
FRESH AIR. INGESTION: DRINK LIQUIDS. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCO NSCIOUS PERSON. DON'T INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:205F
Lower Limits:1%
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM & CO2.
Fire Fighting Procedures:IF A LEAK OR SPILL HASN'T IGNITED, USE WATER
TO DISPERSE VAPOR.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID ALL PERSONAL CONTACT. CONTAIN SPILL.
WIPE UP OR ABSORB ON SUITABLE MATERIAL FOR PROPER DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM HIGH TEMPS. AVOID
CONTAMINATION OF WATER. AVOID ALL PERSONAL CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED.
Ventilation:POSITIVE VENTILATION SHOULD BE PROVIDED.
Supplemental Safety and Health
LD50 DATA IS FOR NONYLPHENOL.
================== Physical/Chemical Properties ==================
Spec Gravity:1.1
pH:10-12
Appearance and Odor:CLEAR VISCOUS LIQUID W/MILD AMMONIACAL ODOR.
Percent Volatiles by Volume:0%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS & ACIDS
Stability Condition to Avoid:HIGH TEMPERATURES
Hazardous Decomposition Products:CO & CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT HAS BEEN EVALUATED FOR RCRA
CHARACTERISTICS & DOESN'T MEET CRITERIA OF HAZARDOUS WASTE IF
DISCARDED IN ITS PURCHASED FORM. UNDER RCRA IT IS THE
RESPONSIBILITY OF USER OF PRODUCTS TO DETERMINE PROPER DISPOSAL
METHOD. UN 1760/2815/1719.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:6603827 3A1-RD1
Preparer's Name:S HEALY
CAGE:FO645
CAGE:FO645
CAGE:6Z677
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM AZIDE, AZIDE *96-4*
CAS:26628-22-8
RTECS #:VY8050000
Other REC Limits:0.1 PPM
ACGIH TLV:C 0.29 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: NASAL IRRITATION. SKIN:
IRRITATION, ABSORPTION, ALLERGIC REACTION. EYES: IRRITATIONS,
CONJUNCTIVITIS. INGESTION: BRONCHIAL IRRITATION, RESPIRATORY
IRRITATION, RESPIRATORY FAILURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS, FAINTNESS,
NAUSEA, LOW BLOOD PRESSURE, BLURRED VISION, SHORTNESS OF BREATH,
COLLAPSE, BRONCHITIS, PALPITATION, WEAKNESS & UNSTEADINESS, COMA,
CONVULSIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE CPR.
IF BREATHING IS DIFFICULT GIVE OXYGEN. SKIN: WASH OFF THOROUGHLY
FOR 15 MINS. EYES: RINSE THOROUGHLY W/WATER & GIVE PLENTY OF WATER
TO DRIN K. INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICALS SUCH AS AN SODIUM CARBONATE/SAND.
Fire Fighting Procedures:BURNING SODIUM AZIDE WILL EXPLODE IF WATER IS
USED AS AN EXTINGUISHING MEDIA. SCBA MUST BE WORN.
Unusual Fire/Explosion Hazard:MAY EXPLODE & RELEASE TOXIC FUMES UPON
HEATING. DON'T ALLOW TO CONTACT METALS AT HIGH TEMPS.
(SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:DILUTE W/RUNNING WATER BEFORE DISCHARGE.
DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM METALS & ACIDS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:GENERAL/LOCAL EXHAUST TO MEET TLV REQUIREMENTS
Other Protective Equipment:ADEQUATE LABORATORY ATTIRE
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
UNUSUAL FIRE CONT'D: FORMS HIGHLY SENSITIVE EXPLOSIVE COMPOUNDS W/HEAVY
METALS SUCH AS LEAD, SILVER & COPPER. WHEN HEATED TO 662F IT
DECOMPOSES EXOTHERMICALLY, BURNING W/A VERY HOT FLAME & PRODUCING N
ITROGEN & MOLTEN SODIUM.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:527F
Spec Gravity:1.85
Solubility in Water:40.16
Appearance and Odor:WHITE-COLORLESS CRYSTALS/POWDER, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALS, ACIDS, ACID CHLORIDES & STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:NITROGEN OXIDES, HYDRAZOIC ACID
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:RICE HULL FLOUR
CAGE:98231
CAGE:98231
CAGE:NO672
============= Composition/Information on Ingredients =============
Ingred Name:PAINTS,PRESERVATIVES & SOLVENTS
Fraction by Wt: NONE
Other REC Limits:NONE RECOMMENDED
Ingred Name:ALLOYS AND METALLIC COATINGS
Fraction by Wt: NONE
Other REC Limits:NONE RECOMMENDED
Ingred Name:HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS OR GAS
Fraction by Wt: NONE
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:PRODUCT'S LD50 (ORAL RAT) WAS NOT STATED
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NO EFFECTS
Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT
CARCINOGENICITY. HMIS FOUND NO LISTING & DOES NOT EXPECT IT TO BE
CARCINOGENIC.
Effects of Overexposure:NO EFFECTS
Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION OF MSDS.
======================= First Aid Measures =======================
First Aid:NONE
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP
Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:UNNECESSARY
Ventilation:NORMAL
Other Protective Equipment:MFR GAVE NO INFORMATION OF MSDS.
Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:N/A.
Vapor Pres:N/A.
Spec Gravity:1.12
Evaporation Rate & Reference:N/A.
Solubility in Water:SLIGHT TO NIL
Appearance and Odor:FINE GRANULAR PARTICLES, PRACTICALLY ODORLESS
Percent Volatiles by Volume:N/A.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MFR GAVE NO INFORMATION OF MSDS.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:MFR GAVE NO INFORMATION OF MSDS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:NORMAL WASTE DISPOSAL
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:SEALTIGHT CM-60 TWO PART POLYSULFIDE SEALAN
Kit Part:Y
CAGE:MEADO
CAGE:96022
CAGE:MEADO
============= Composition/Information on Ingredients =============
Ingred Name:ING 17: SOLNS AS ABOVE. SMALL SPILLS: TAKE UP W/ABSORB MATL
& PLACE IN NON-LEAKING CNTNRS; SEAL TIGHTLY FOR PROPER DISP.
RTECS #:9999999ZZ
Ingred Name:ING 3:ABILITY,& LOSS OF COORD. OTHER: BASED ON PRESENCE OF
ING 1 CHRONIC OVEREXP TO DUST MAY CAUSE SLIGHT LUNG FIBROSIS.
RTECS #:9999999ZZ
Ingred Name:HLTH HAZ: WHICH MAY RSLT IN DERM. INHAL: BASED ON PRESENCE
OF ING 2 EXPOSURE TO EXCESSIVE VAP CONCS MAY CAUSE (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: SIGNS OF TRANSIENT CNS DEPRESS (E.G. HDCH, DROW,
LOSS OF COORDINATION, & FATG). RPTS HAVE ASSOC RPTD & (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:PRLNGD OCCUP OVEREXP TO SOLV W/PERM BRAIN & NERV SYS
DMG. INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS(ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: MAY BE HARMFUL/FATAL. INGEST: BASED ON PRESENCE OF
ING 2 SML AMTS OF LIQ ASPIR INTO LUNGS DURING INGEST/ (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: FROM VOMIT MAY RSLT IN SEV LUNG DMG. WHILE MATL HAS
LOW DEGREE OF TOX, INGESTION OF EXCESSIVE QTYS MAY (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: CAUSE SIGNS OF CNS DEPRESSION (E.G. HEADACHE,
FATIGUE, DROWSINESS, DIZZINESS, AND LOSS OF COORDINATION).
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: IMMED BEGIN ARTF RESP. IF BRTHG DFCLTYS
DEVELOP, OXYGEN SHOULD BE ADMIN BY QUALIFIED PERS. SEEK (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:IMMED MED ATTN. INGEST:DO NOT INDUCE VOMIT. IF VOMIT
SPONT OCCURS, KEEP VICTIM'S HEAD BELOW HIPS TO PVNT (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:ASPIR INTO LUNGS. SINCE ASPIR INTO LUNGS CAN CAUSE
VERY SERIOUS, PERM DMG, DECISION OF WHETHER TO INDUCE (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13: VOMIT/NOT SHOULD BE MADE BY PHYS. DANGER FROM LUNG
ASPIR MUST BE WEIGHED AGAINST TOX WHEN CONSIDERING (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: EMPTYING STOM. CONSULT PHYS, HOSPITAL/POIS CNTRL
CNTR AND/OR TRANSPORT TO AN EMERGENCY FACILITY IMMEDIATELY.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP
RESIDUE W/ABSORB SUCH AS CLAY, SAND/OTHER SUITABLE MATL; (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16: PLACE IN NON-LEAKING CNTNRS FOR PROPER DISP. FLUSH
AREA W/WATER TO REMOVE TRACE RESIDUE; DISP OF FLUSH (ING 18)
RTECS #:9999999ZZ
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 1-5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:XYLENE (SARA III). VP: 6.60 @ 20C. LEL: 1.10% @ 25C.
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 1-5%
OSHA PEL:100 PPM;150 PPM STEL
ACGIH TLV:100 PPM;150 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SUPP DATA:AND DEATH MAY OCCUR. SYMPTOMS OF CHRONIC
OVEREXPOSURE INCLUDE LOSS OF MEMORY, LOSS OF INTELLECTUAL (ING 4)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: BASED ON PRESENCE OF ING 2 PROD
IS PRESUMED TO BE MOD IRRIT TO EYES. EXPOS MAY CAUSE CORNEAL INJ.
PROD VAPS &/OR MISTS MAY ALSO BE IRRIT TO EYES. SKIN: BASED ON
PRESENCE OF ING 2 PROD IS PRESUMEDTO BE MOD IRRIT TO SKIN.PRLNGD
CONT MAY CAUSE DMG TO SKIN. PRLNGD/RPTD CONT MAY RSLT IN DEFAT &
DRYING OF SKIN (ING 5)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SYMPS OF EYE IRRIT INCL PAIN, TEARING,
REDDENING,& SWELLING. SYMPS OF SKIN IRRIT INCL REDDENING, SWELLING,
RASH,& REDNESS. SYMPS OF RESP IRRIT INCL RUNNY NOSE, SORE THROAT,
COUGHING, CHEST DISCOMFORT, SHORTNESS OF BREATH, & REDUCED LUNG
FUNC. SYMPS OF GI IRRIT INCL SORE THROAT, ABDOM PAIN, NAUS, VOMIT,
& DIARR.(SUPDAT)
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN,EYE,& RESP
DISORDERS MAY BE AGGRAVATED BY EXPOS TO PROD. IMPAIRED ASTHMATIC
CNDTNS MAY BE AGGRAVATED FROM PRLNGD & CONTINUOUS EXPOS TO
DUST.FUNCS FROM PRE-EXISTING DISORDERS (SUPDAT)
======================= First Aid Measures =======================
First Aid:EYE: MOVE VICTIM AWAY FROM EXPOS SOURCE & INTO FRESH
AIR.FLUSH W/WATER FOR AT LST 15 MINS. IF SYMPS PERSISTS, SEEK MED
ATTN. SKIN: REMOVE CONTAMD SHOES & CLTHG. CLEANSE AFFECTED AREA(S)
THORO BY WASHI NG W/MILD SOAP & WATER. IF IRRIT/REDNESS DEVELOPS &
PERSISTS, SEEK MED ATTN. INHAL:MOVE VICTIM AWAY FROM EXPOS SOURCE &
INTO FRESH AIR.IF SYMPS PERSIST, SEEK MED ATTN. IF VICTIM IS NOT
BRTHG, (ING 11)
===================== Fire Fighting Measures =====================
Flash Point:>230F,>110C
Lower Limits:ING 2
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, OR CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . CLEAR AREA OF UNPROTECTED PERSONNEL.
Unusual Fire/Explosion Hazard:CNTNRS EXPOS TO INTENSE HEAT FROM FIRES
SHOULD BE COOLED W/WATER TO PVNT VAP PRESS BUILDUP WHICH COULD RSLT
IN CNTNR RUPTURE.CNTNR AREAS EXPOS TO DIRECT(SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:LRG SPILLS:EVAC HAZ AREA OF UNPROT PERS.WEAR
APPROP NIOSH/MSHA APPRVD RESP & PROT CLTHG.SHUT OFF SOURCE OF LEAK
ONLY IF SAFE TO DO SO.DIKE & CONTAIN.IF VAP CLOUD FORMS,WATER FOG
MAY BE USED TO SUPRESS ;CONTAIN RUN-OFF.REMOVE W/VACUUM TRUCK OR
(ING 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTAINS CAN CONTAIN HAZARDOUS PRODUCT
RESIDUES EVEN WHEN EMPTY.
Other Precautions:WASH WITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE EXCEEDS PEL/TLV, USE AN APPROPRIATE
NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE VENT AS REQUIRED TO CONTROL VAP CONCS-AT LST 10 AIR
CHANGES PER HOUR ARE RECOMMENDED FOR GOOD GEN ROOM VENTILATION.
Other Protective Equipment:WEAR APPROP PROT CLTHG TO PRVNT CONT W/SKIN
& CLTHG.EYE WASH FOUNTAINS & SAFETY SHOWERS SHOULD BE AVAIL FOR USE
IN EMER.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. WASH W/SOAP
AND WATER BEFORE EATING, DRINKING, SMOKING OR USING TOILET
FACILITIES.
Supplemental Safety and Health
TRADE NAME/PART #:COMPONENT B, 4510175B. EXPLO HAZ:FLAME CONT SHOULD BE
COOLED W/LRG QTYS OF WATER AS NEEDED TO PVNT WEAKENING OF CNTNR
STRUCTURE.MED CNDTNS: MAY BE AGGRAVATED BY EXPOS TO PROD.EFTS OF
OVEREXP:TRANSIENT CNS DEPRESS MAY BE EVIDENCED BY HDCH,DIZZ,NAUS,&
SYMPS OF INTOXICATION;IN EXTREME CASES,UNCON (ING 3)
================== Physical/Chemical Properties ==================
Vapor Pres:ING 2
Vapor Density:>1
Spec Gravity:1.5
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:3.00
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUSTION MAY YIELD CARBON DIOXIDE,
CARBON MONOXIDE, AND/OR INCOMPLETE COMBUSTION PRODUCTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
REGARDING PROPER DISPOSAL.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:4263 BLACK PART A ONLY, 8070730
Kit Part:Y
CAGE:DO804
CAGE:DO804
CAGE:38360
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-; (DIETHYLENE GLYCOL MONOBUTYL
ETHER). SPEC GRAV:0.954. VP:0.02. EVAP RATE:<0.01 (ING 2)
CAS:112-34-5
RTECS #:KJ9100000
Fraction by Wt: 10-30%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 1:(N-BUTYL ACETATE=1). SOL IN H*2O:100%.
LD50:(ORAL,RAT) 5,660 MG/KG.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:GAMMA-GLYXIDOXYPROPYLTRIMETHOXYSILANE. SPEC GRAV:1.069.
CAS:2530-83-8
RTECS #:VV4025000
Fraction by Wt: 1-5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM;250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:BIS (TRI-N-BUTYLTIN) OXIDE
CAS:56-35-9
RTECS #:JN8750000
OSHA PEL:0.1 MG/M3 (SN), S
ACGIH TLV:0.1 MG/M3 (SN), S
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:SUPDAT:DILUTION. NOTIFY AUTHS IF LIQ ENTERS SEWERS/OTHER
PUBLIC WATERS. WATER MAY NOT BE EFTIVE TO EXTING FIRE. (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS & TO
PROTECT PERSONNEL.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:MOISTURE, FOR EX, IN STOM, TO FORM
METHANOL. THERE MAY BE DELAY OF SEVERAL HRS BTWN SWALLOWING &(ING
10)
RTECS #:9999999ZZ
Ingred Name:ING 9:ONSET OF VISUAL IMPAIRMENT, SYMP OF EXPOS TO
METHANOL. TARGET ORGANS:HEART, LIVER, KIDNEYS, EYES, SKIN, (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:NERVOUS SYSTEM, LUNGS, DIGESTIVE TRACT.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:CONTACTED IMMED & BE PROVIDED W/THIS MSDS.
RECENT INFO SUGGEST THAT RISK ASSOC W/INDUCING VOMIT (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:EXCEEDS POIS RISK OF SUBSTANCE, ESP FOR SM QTYS
LIKELY TO BE INGESTED UNDER NORM INDUS USE. GET MED ATTN (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:IMMED. DRINK 2 GLASSES OF WATER. CONT POIS INFO
SERVICE. STOM EVACUATION MAY BE APPROP, AS REC BY MED (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14:PROFESSIONALS, ONLY IF SIGNIFICANT QTY OF MATLS HAS
BEEN INGESTED. STOM EVACUATION SHOULD ONLY BE CARRIED(ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:OUT BE TRAINED & PROPERLY EQUIPPED MEDICAL
PERSONNEL.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC:FOR DEALING W/SPILL OF ANY SIZE. PPE NEEDS MUST
BE EVALUATED BASED ON INFO PROVIDED ON THIS MSDS & (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:SPECIAL CIRCUMSTANCES CREATED BY SPILL INCL; MATL
SPILLED, QTY, AREA IN WHICH IT OCCURRED; & EXPERTISE OF(ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:EMPLOYEES IN AREA RESPONDING TO SPILL. NEVER EXCEED
ANY OCCUP EXPOS LIMS & CONSIDER THAT EVAP OF VOLAT (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:SOLVS CAN LEAD TO DISPLACEMENT OF AIR CREATING
ENVIRON THAT CAN CAUSE ASPHY. ECOLOGICAL INFO:AQ SCREENING(ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:TEST DATA INDICATE THAT BIODEGRADATION MAY BE
IMPORTANT REMOVAL MECH OF DIETHYLENE GLYCOL MONOBUTYL ETHER(ING 22)
RTECS #:9999999ZZ
Ingred Name:ING 21:FROM AEROBIC SOIL & WATER. IN ATM, DIETHYLENE GLYCOL
MONOBUTYL ETHER IS EXPECTED TO EXIST ALMOST ENTIRELY(ING 23)
RTECS #:9999999ZZ
Ingred Name:ING 22:IN VAP PHASE & RXNS W/PHOTOCHEMICALLY PRDCD HYDROXYL
RADICALS SHOULD BE IMPORTANT(ESTIMATED HALF-LIFE OF 11 HRS).
RTECS #:9999999ZZ
Ingred Name:VENT:CONTAMS BELOW TLV, PEL/OTHER REL &/OR MAINTAIN
OPERATOR COMFORT. THESE CONTROLS SHOULD BE EXPLO-PROOF WHEN (ING
25)
RTECS #:9999999ZZ
Ingred Name:ING 24:EXHAUSTING FLAMMABLE VAPORS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE CONT:CAN CAUSE SEV IRRIT,
TEARING & REDDENING, BUT NOT LIKELY TO PERM INJURE TISS. TEMPORARY
VISION IMPAIRMENT (CLOUDY/BLURRED VISION) IS POSS. SKIN CONT:CAN
CAUSE MINOR IRRIT, DEFAT & DERM. SKIN ABSORPTION:TOX IF ABSORBED
THRU SKIN CAUSING SYSTEMIC DMG. INHAL:CAN CAUSE RESP IRRIT, DIZZ,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:CARBON BLACK:IARC MONOGRAPHS, VOL 65, PG
149, 1996:GROUP 2B.
Effects of Overexposure:HLTH HAZ:WEAK, FATG, NAUS, HDCH & POSS UNCON.
CAN LEAD TO VISION DISTURBS. INGEST:TOX. IF SWALLOWED, MAY CAUSE
ABDOM DISCOMFORT, NAUS, VOMIT, DIARR & SYSTEMIC POIS. UPON INGEST
OF LG QTY OF THIS MATL, VISUAL DISTURBS MAY OCCUR. ONSET OF
RESPONSE MAY BE DELAYED. ORGANOSILANE ESTER:THIS SUBSTANCE REACTS
W/ (ING 9)
Medical Cond Aggravated by Exposure:NO DATA FOUND.
======================= First Aid Measures =======================
First Aid:EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 20 MINS
RETRACTING LIDS OFTEN. GET IMMED MED ATTN. SKIN:WASH W/SOAP &
WATER. REMOVE CONTAM CLTHG & LAUNDER. GET MED ATTN IF IRRIT
DEVELOPS/PERSISTS. INHAL :REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE
ARTF RESP/HAVE TRAINED INDIVIDUAL ADMIN OXYGEN. GET MED ATTN IMMED.
INGEST:INFO PRESENTED IN THIS SECTION IS ONLY A GUIDE. EMERGENCY
PERS SHOULD BE (ING 12)
===================== Fire Fighting Measures =====================
Flash Point:220F,104C
Lower Limits:0.9%
Upper Limits:24.6%
Extinguishing Media:USE ALCOHOL FOAM, CARBON DIOXIDE (CO*2), OR DRY
CHEMICAL.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
FIGHT FIRE FROM SAFE DIST & PROT LOCATION. HEAT MAY BUILD PRESS &
RUPTURE CLSD CNTNRS, SPREADING FIRE & (SUPDAT)
Unusual Fire/Explosion Hazard:MATERIAL MAY BE IGNITED IF PREHEATED TO
TEMPERATURES ABOVE FLASH POINT IN PRESENCE OF A SOURCE OF IGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:PVNT SPREAD OF ANY SPILL TO MIN HARM TO HUMAN
HLTH & ENVIRON. DIKE W/SUITABLE ABSORB MATL LIKE SPEEDIDRI. WEAR
COMPLETE & PROPER PPE & VENT SPACE INVOLVED. FOLLOW GUIDELINES OF
EXPOS CONTROLS & PERSON AL PROT SECTION (& FOLLOW 29 CFR
1910.120)(ING 17)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT W/MATERIAL, AVOID
BREATHING VAPORS, USE ONLY IN A WELL-VENTILATED AREA. STORE IN A
COOL, DRY PLACE. ISOLATE FROM INCOMPATIBLE MATERIALS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:COMPONENT OF THIS MATL HAS EXTREMELY LOW
ESTABISHED EXPOS LIM. IF AIR MONITORING INDICATES AIRBORNE CONCS
AT/ABOVE PEL/TLV, NIOSH APPRVD RESP PROT PROGRAM IS REQD I/A/W OSHA
STD 1910.134. ENHANCED ENG INEERING CONTROLS TO REDUCE (SUPP DATA)
Ventilation:LOC EXHST VENT/OTHER ENGINEERING CONTROLS ARE NORMALLY REQD
WHEN HNDLG/USING THIS PROD TO KEEP EXPOS TO AIRBORNE(ING 24)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . PREVENT SKIN CONTACT BY WEARING APRON & BOOTS.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN. ALL EQUIP
SHOULD BE CLEANED THORO AFTER EACH USE & SHOULD NOT LEAVE THE WORK
PLACE.
Supplemental Safety and Health
RESP PROT:EXPOS BELOW PEL/TLV IS PREF TO RESP PROGRAM. PROT
PROT:FULL LGTH FSHLD . FIRE FIGHT PROC:INCR RISK OF BURNS/INJURIES
. USE WATER SPRAY/FOG FOR COOLING. EVENIF MATL IS WATER SOL, IT MAY
NOT BE PRACTICAL TO EXTING FIRE BY WATER (ING 7)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:448F,231C
Vapor Pres:<0.01
Vapor Density:HVR/AIR
Spec Gravity:1.35
Evaporation Rate & Reference:0.01-0.1 (N-BUAC=1)
Solubility in Water:SEE ING 1
Appearance and Odor:LIQUID, SEMI-SOLID OR SOLID; MILD SOLVENT ODOR.
Percent Volatiles by Volume:23
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS; ACIDS; CAUSTICS (BASES).
Stability Condition to Avoid:ELEVATED TEMPERATURES IN COMBINATION
W/SPARKS, OPEN FLAMES OR OTHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON DIOXIDE; CARBON MONOXIDE;
SILICON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF BY INCINERATION OR WASTE WATER
TREATMENT FOLLOWING FEDERAL, STATE, PROVINCIAL OR LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ETERNACELL LITHIUM SDX
Preparer's Name:K. ERRICKSON
CAGE:5G978
CAGE:5G978
Contract Num:SP0430-99-M-AS24
CAGE:0LEJ1
============= Composition/Information on Ingredients =============
Ingred Name:SULFUR DIOXIDE (SARA 302)
CAS:7446-09-5
RTECS #:WS4550000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 PPM
ACGIH TLV:2 PPM/5 STEL; 9495
Ingred Name:LITHIUM METAL (<0.5 GRAMS)
CAS:7439-93-2
RTECS #:OJ5540000
Other REC Limits:NONE RECOMMENDED
Ingred Name:PROPYLENE (PROPENE) (SARA 313)
CAS:115-07-1
RTECS #:UC6740000
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:ASPHIXIANT; 9495
Ingred Name:ACETONITRILE (SARA 313) (CERCLA)
CAS:75-05-8
RTECS #:AL7700000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:40 PPM
ACGIH TLV:40 PPM/60 STEL; 9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:LITHIUM SALTS MIXTURE
Other REC Limits:NONE RECOMMENDED
Ingred Name:STEEL CASING, & NON-HAZARDOUS COMPONENTS
CAS:116-14-3
Other REC Limits:NONE RECOMMENDED
Ingred Name:TEFLON
CAS:9002-84-0
RTECS #:KX4025000
OSHA PEL:15 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: ELECTROLYTE IS SEVERE IRRITANT.
INTACT LITHIUM IS REACTIVE. AVOID CONTACT. CHRONIC: MAY CAUSE
DERMATITIS. SOME COMPONENTS HAVE BEEN SHOWN TO BE TERATOGENIC TO
ANIMALS.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:EXPOSURE TO SKIN OR EYES MAY CAUSE IRRITATION.
INHALATION MAY RESULT IN DIFFICULTY BREATHING.
Medical Cond Aggravated by Exposure:NONE KNOWN
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES. SEEK MEDICAL
ASSISTANCE. SKIN: FLUSH WITH WATER FOR 15 MINUTES. SEEK MEDICAL
ASSISTANCE. INHALATION: REMOVE TO FRESH AIR. SEEK MEDICAL
ASSISTANCE.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:LITH-X, DRY SAND
Fire Fighting Procedures:COOL BATTERY WITH EXTINGUISHING MEDIA, REMOVE
ADJACENT COMBUSTIBLE MATERIALS IF SAFE TO DO SO. SCBA REQUIRED.
Unusual Fire/Explosion Hazard:DO NOT USE WATER TO EXTINGUISH FIRES,
CELLS CAN REACT WITH WATER VIOLENTLY. CELLS CAN VENT ELECTROLYTE IF
SUBJECT TO TEMPERATURES OF 185F OR GREATER.
================== Accidental Release Measures ==================
Spill Release Procedures:ALLOW BATTERY TO COOL AND VAPOR TO DISSIPATE.
AVOID CONTACT. AVOID INHALATION OF VAPORS. REMOVE SPILLED
ELECTROLYTE WITH ABSORBANT MATERIAL. WEAR FULL FACE ACID/ORGANIC
CARTRIDGE RESPIRATOR.
======================Handling and Storage ======================
Handling and Storage Precautions:BATTERIES MAY EXPLODE, IGNITE, OR VENT
ELECTROLYTE IF CRUSHED, OPENED, PUNCTURED OR EXPOSED TO
TEMPERATURES IN EXCESS OF 185F.
Other Precautions:DO NOT SHORT CIRCUIT, INSTALL WITH INCORRECT
POLARITY, OR ATTEMPT TO RECHARGE. DO NOT INCINERATE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE FULL FACE ACID/ORGANIC VAPOR RESPIRATOR IF
CELL VENTS.
Ventilation:PROVIDE IF CELL VENTS.
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER (HMIS)
Work Hygienic Practices:AVOID EXPOSURE. WASH HANDS AFTER HANDLING.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:Z6
Appearance and Odor:SEALED CELL, LITHIUM BATTERY. CYLINDERICAL OR
BOXLIKE APPEARANCE.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
DO NOT EXPOSE TO WATER.
Stability Condition to Avoid:DO NOT HEAT ABOVE 185F, PUNCTURE, OR OPEN
CELL, SHORT CIRCUIT, OR ATTEMPT TO RECHARGE.
Hazardous Decomposition Products:MAY INCLUDE CARBON MONOXIDE AND
CAUSTIC LITHIUM OXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:FULLY DISCHARGE PRIOR TO DISPOSAL. DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE. AND FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:LITHIUM CELLS AND BATTERIES CONTAINING LESS THAN
1.0 G OF LITHIUM ARE NOT SUBJECT TO 49 CFR 173.185 (B)(1)(2). THIS
BATTEY CONTAINS LESS THAN 0.5 G OF LITHIUM.
======================================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:3443 CONDENSATE TREATMENT A1
CAGE:AQUAS
CAGE:42889
CAGE:AQUAS
============= Composition/Information on Ingredients =============
Ingred Name:2-DIETHYLAMINOETHANOL
CAS:100-37-8
RTECS #:KK5075000
OSHA PEL:S, 10 PPM
ACGIH TLV:S, 10 PPM; 9192
Ingred Name:CYCLOHEXYLAMINE (SARA III)
CAS:108-91-8
RTECS #:GX0700000
Other REC Limits:10 PPM
OSHA PEL:10 PPM
ACGIH TLV:10 PPM; 9192
Ingred Name:MORPHOLINE
CAS:110-91-8
RTECS #:QD6475000
Other REC Limits:20 PPM
OSHA PEL:S,20 PPM/30 STEL
ACGIH TLV:S, 20 PPM; 9192
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION & POSSIBLE
DAMAGE. SKIN: SEVERE IRRITATION, POSSIBLE BURNS, & DERMATITIS.
INGESTION: SEVERE IRRITATION OF MOUTH/THROAT. INHALATION: SEVERE
RESPIRATORY IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: SEVERE IRRITATION & POSSIBLE DAMAGE.
SKIN: SEVERE IRRITATION, POSSIBLE BURNS, & DERMATITIS, DESTRUCTION
OF TISSUE. INGESTION: SEVERE IRRITATION OF MOUTH/THROAT.
INHALATION: SEVERE RESPIRATORY IR RITATION.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/WATER FOR 15 MINS. INGESTION: DON'T INDUCE
VOMITING. DRINK WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:IRRITATING VAPORS MAY BE EMITTED DURING A
FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP SPILLS W/SAND OR OTHER ABSORBENT.
PLACE INTO CHEMICAL WASTE CONTAINER FOR DISPOSAL. FLUSH SPILL AREA
W/WATER. WEAR PROTECTIVE CLOTHING.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL PROTECTED LOCATION.
KEEP CONTAINER CLOSED WHEN NOT IN USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ORGANIC VAPOR RESPIRATOR IF VENTILATION IS
INADEQUATE.
Ventilation:MECHANICAL: RECOMMENDED FOR ENCLOSED AREAS. LOCAL EXHAUST:
AS REUQIRED
Other Protective Equipment:PROTECTIVE CLOTHING, EYE WASH STATION, SINK
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:210F
Spec Gravity:0.988
pH:12.4
Evaporation Rate & Reference:(WATER = 1): >1
Solubility in Water:COMPLETE
Appearance and Odor:PALE YELLOW LIQUID, AMMONICAL ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG CAUSTIC
Hazardous Decomposition Products:AMMONIA
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF AT APPROVED CHEMICAL WASTE
REPROCESSING FACILITY IN ACCORDANCE W/FEDERAL, STATE & LOCAL
REGULATIONS. RINSE CONTAINER BEFORE REUSE OR DISPOSAL.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:SODIUM FLUORIDE
Resp. Party Other MSDS Num.:SS 535
Preparer's Name:ALEXANDER A. PICCIRILLI
CAGE:EO227
CAGE:EO227
Contract Num:MDA414-99-P3451
CAGE:63759
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM FLUORIDE (CERCLA)
CAS:7681-49-4
RTECS #:WB0350000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2.5 PPM (F)
ACGIH TLV:2.5 MG (F/)M3; 9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) 64 MG/KG (RTECS).
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY &
GI TRACTS. ACUTE- POISON. EYE:MAY CAUSE BURNS. SKIN:DERMATITIS.
INGESTION:TOXIC. SEVERE VOMITING, ABDOMINAL DISTRESS, DIARRHEA,
STUPOR, WEAKNESS. INHALATION:TOXI C IF INHALED. CAUSES IRRITATION
OF MUCOUS MEMBRANES, CHILLS, LABORED BREATHING, FEVER, UNPRODUCTIVE
COUGH. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BURNS, DERMATITIS, SEVERE VOMITING, ABDOMINAL
DISTRESS, DIARRHEA, STUPOR, WEAKNESS, IRRITATION, CHILLS, LABORED
BREATHING, FEVER, UNPRODUCTIVE COUGH
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE FROM EXPOSURE,TREAT SYMPTOMATICALLY, GET
MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR
AT LEAST 15 MINUTES,LIFTING OPEN LIDS OCCASIONALLY.GET PROMPT
MEDICAL ATTE NTION.SKIN:FLUSH WITH PLENTY OF WATER.IF IRRITATION
DEVELOPS,GET MEDICAL ATTENTION.INGESTION:IF CONSCIOUS,IMMEDIATELY
GIVE SEVERAL GLASSES OF MILK OR OTHER CALCIUM CONTAINING LIQUID IF
AVAILABLE,OTHER WISE GIVE LARGE AMOUNTS OF WATER.GET IMMEDIATE
MEDICAL ATTENTION.NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.FORMS HYDROFLUORIC ACID UPON CONTACT WITH ACID.
===================== Fire Fighting Measures =====================
Flash Point:NON-COMBUSTABLE
Extinguishing Media:WATER, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
(ABC).WATER SPRAY WOULD TEND TO REDUCE FUMES AND DISPERSE VAPORS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO
PREVENT CONTACT WITH SKIN AND ACID FUMES. DUST PESENTS A
RESPIRATORY AND EYE HAZARD. MODERATEL Y WATER SOLUBLE. SEE 1990
EMERGENCY RESPONSE GUIDEBOOK, GUIDE NO 54.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS;CAN REACT VIGOROUSLY WITH ACID TO
LIBERATE CORROSIVE AND TOXIC HYDROGEN FLUORIDE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING. AVOID
MAKING DUST. RECOVER FOR REUSE IF NOT CONTAMINATED. SWEEP UP AND
PLACE IN A SUITABLE CONTAINER FOR PROPER DISPOSAL AVOIDING DUSTY
CONDITIONS. WASH SPILL SITE W ELL WITH SOAP AND WATER AFTER PICK UP
IS COMPLETE.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, VENTILATED PLACE
AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions:POISON. AVOID INHALATION AND INGESTION AVOID CONTACT
WITH SKIN AND EYES. REMOVE AND WASH CONTAMINATED CLOTHING. KEEP OUT
OF REACH OF CHILDREN. OBEY HAZARD WARNING LABEL. FOR LABORATORY USE
ONLY. NOT FOR DRUG, FOOD OR HOUSEHOLD USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED IN NORMAL LABORATORY
HANDLING. IF DUSTY CONDITIONS PREVAIL, WORK IN A VENTILATION HOOD
OR WEAR A NIOSH-APPROVED DUST RESPIRATOR OR DUST MASK. IN
EMERGENCY, WEAR NIOSH-APPROVED SE LF-CONTAINED BREATHING APPARATUS.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Other Protective Equipment:SMOCK.APRON,EYE WASH STATION, AND
VENTILATION HOOD.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
WARD'S P/N: 37W5518
================== Physical/Chemical Properties ==================
HCC:T4
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=1704.C, 3099.2F
Melt/Freeze Pt:=993.C, ######F
Vapor Pres:1MM@1077C
Vapor Density:1.45
Spec Gravity:2.558
Viscosity:NOT RELEVANT
Solubility in Water:4.22G
Appearance and Odor:WHITE CRYSTALLINE POWDER - ODORLESS.
Percent Volatiles by Volume:NEGLIGIBLE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS (REACTS WITH ACIDS TO FORM CORROSIVE AND TOXIC HYDROGEN
FLUORIDE).WATER FORMS SOLUTION CORRROSIVE TO MANY MATERIALS,
INCLUDING GLASS.
Stability Condition to Avoid:EXCESSIVE HEAT AND TEMPERATURE, MOISTURE.
Hazardous Decomposition Products:MAY FORM HYDROGEN FLUORIDE, FLUORINE
AND SODIUM OXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE,TREATMENT,OR DISPOSAL MAY BE SUBJECT
TO FEDERAL,STATE,AND LOCAL LAWS.THESE DISPOSAL GUIDELINES ARE
INTENDED FOR CATALOG-SIZE QUANTITIES ONLY. DISPOSE OF CONTAINER AND
ANY RESIDUE ACCORDING T O LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:D.O.T.: SODIUM FLUORIDE, CLASS 6.1, UN1690
| 1 | gloves_mandatory |
=======================================================
NIIN: 00-417-0491
Product ID: BRAKE LINING
Cage: 81349
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: 81349
Box: MANUAL
=======================================================
Contractor Summary
=======================================================
Cage: 81349
Box: MANUAL
=======================================================
Item Description Information
=======================================================
Item Manager: S9C
Item Name: LINING
Unit of Issue: EA
UI Container Qty: Z
Type of Container: UNKNOWN
=======================================================
Ingredients
=======================================================
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTALBISHED
ACGIH TLV: NOT ESTABLISHED
-----------------------------
Cas: 12001-29-5
RTECS #: CI6478500
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 0.2 FIBERS/CC
ACGIH TLV: 2 FIBERS/CC; A1;9192
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NOT ESTABLISHED
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: ACUTE:EYE/SKIN:IRRITATION. CHRONIC: INHALATION:ASBESTOSIS
AND CANCER
Explanation Of Carcinogenicity: ASBESTOS IS A HUMAN CARCINOGEN
Signs And Symptions Of Overexposure: ASBESTOSIS IS ASSOCIATED WITH SYMPTOMS OF
LABORED BREATHING,CHEST PAINS,WEAKNESS,AND CHEST TIGHTNESS. SYMPTOMS ARE NOT
USUALLY MANIFEST UNTIL 15-20 YEARS AFTER EXPOSURE.
Medical Cond Aggravated By Exposure: RESPIRATORY AILMENTS. SMOKING INCREASES
RISK TO HEALTH.
First Aid: EYES: GENTLY RISE WITH WATER. SKIN: WASH THOROUGHLY WITH WATER.
INHALATION:REMOVE TO FRESH AIR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: VACCUMING USING HEPA-FILTERED EQUIPMENT OR WET
CLEANING IF DUST IS INVOLVED.
Neutralizing Agent: NONE KNOWN
Waste Disposal Methods: DISPOSE OF WASTE MATERIAL IN SEALED IMPERMEABLE BAGS OR
OTHER IMPERMEABLE CLOSED CONTAINERS USING PROPER LABELS. DISPOSE OF IN
ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: AVOID CREATING DUST.
Other Precautions: AVOID PHYSICAL DAMAGE.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NONFLAMMABLE
Lower Limits: NOT GIVEN
Upper Limits: NOT GIVEN
Extinguishing Media: NONFLAMMABLE. USE MEDIA SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures: NONFLAMMABLE. USE PROCEDURES SUITABLE FOR SURROUNDING
FIRE.
Unusual Fire/Explosion Hazard: FIRE MAY RELEASE ASBESTOS FIBERS TO THE AIR.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH APPROVED IF P.E.L. IS EXCEEDED.
Ventilation: LOCAL EXHAUST IF ENGINEERING CONTROS ARE INADEQUATE.
Other Protective Equipment: PROTECTIVE WORK CLOTHING AND EQUIPMENT IS REQUIRED
IF THE P.E.L. IS EXCEEDED.
Work Hygienic Practices: WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT AND
BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health: ITEM AS SHIPPED IS NOT HAZARDOUS. HAZARD OCCURS
WHEN ASBESTOS FIBERS ARE RELEASED FROM BRAKE LINING MATERIAL.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: T7
B.P. Text: NOT KNOWN
M.P/F.P Text: NOT KNOWN
Decomp Text: UNKNOWN
Vapor Pres: NOT KNOWN
Vapor Density: NOT KNOWN
Spec Gravity: 1.50 MIN
Evaporation Rate & Reference: NIL
Solubility in Water: NEGLIGIBLE
Appearance and Odor: LIGHT BROWN.SLIGHT PHENOLIC ODOR.
Percent Volatiles by Volume: NIL
Corrosion Rate: UNKNOWN
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: PHYSICAL DAMAGE.
Materials To Avoid: NONE
Hazardous Decomposition Products: INCOMPLETE COMBUSTION MAY RELEASE TOXIC
MATERIALS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE. WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 71375
Product ID: BRAKE LINING
Review Date: 12/11/1992
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: EA
Container QTY: Z
Type Of Container: UNKNOWN
Additional Data: THE REPORTABLE QUANTITY FOR ASBESTOS IS 1 POUND.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: BRAKE LINING
Cage: 81349
Company Name: MILITARY SPECIFICATIONS PROMULGATED BY MILITARY
Street: DEPTS/AGENCIES UNDER AUTH OF DEF STD
PO Box: MANUAL
Zipcode: 00000
Label Required IND: Y
Date Of Label Review: 12/11/1992
Status Code: C
MFG Label NO: NONE
Label Date: 12/11/1992
Origination Code: G
Chronic Hazard IND: Y
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ASBESTOS IS A HUMAN CARCINOGEN AVOID CREATING DUST.
FIRST AID: EYES: GENTLY RISE WITH WATER. SKIN: WASH THOROUGHLY WITH WATER.
INHALATION:REMOVE TO FRESH AIR.
=======================================================
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:4402 ULTRA-FLAT 4400 SERIES,ANTIQUE WHITE
CAGE:01PD6
CAGE:01PD6
============= Composition/Information on Ingredients =============
Ingred Name:CALCIUM CARBONATE, DOMOLITE, LIMESTONE, WHITING *96-2*
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 5-30%
ACGIH TLV:10 MG/CUM (DUST)
Ingred Name:GROG; CALCIUM-BARIUM PHOSPHOSILICATE, ALUMINUM SILICATE
FLUX *96-2*
CAS:66402-68-4
Fraction by Wt: 5-10%
Ingred Name:DIETHYLENE GLYCOL BUTYL ETHER ACETATE, ETHANOL, 2-
(2-BUTOXYETHOXY), BUTYL CARBITOL ACETATE
CAS:124-17-4
RTECS #:KJ9275000
Fraction by Wt: 1-5%
Ingred Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN
CARCINOGEN BY IARC-GROUP 2A; SUSPECTED CARCINOGEN NTP) *96-2*
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 0.1-1%
Other REC Limits:0.05 MG/CUM (NIOSH)
OSHA PEL:10 MG/CUM %RESP SIO2
ACGIH TLV:0.1 MG/CUM RESP DUST
Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
CARCINOGEN, IARC GROUP 3)*96-2*
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 10-20%
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM (DUST)
Ingred Name:VINYL ACRYLIC COPOLYMER
Fraction by Wt: 5-10%
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 40-50%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT
IRRITANT. CENTRAL NERVOUS SYSTEM DEPRESSION, ANESTHETIC EFFECT.
SKIN: SEVERE IRRITATION, POSSIBLE SENSITIZATION. EYES: SEVERE
IRRITATION, CORNEAL INJURY. INGESTION: MAY C AUSE GASTROINTESTINAL
DISTURBANCES, ANESTHETIC EFFECT.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, DROWSINESS, DIZZINESS,
LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA, COUGHING,
SNEEZING, RESPIRATORY PROBLEMS, NARCOSIS, LOSS OF CONSCIOUSNESS,
BLISTERING, TEARING, REDNESS, VOMITING, DIARRHEA, GI DISTURBANCES.
Medical Cond Aggravated by Exposure:EYE, SKIN & RESPIRATORY DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED
BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. SKIN:
FLUSH W/WATER, THEN WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH
IMMEDIATELY W/LARGE AMOUNTS OF WATER FOR 15 MINS. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL/FOAM, WATER FOG, CO2
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT/FIRE. VAPORS ARE >AIR & MAY TRAVEL LONG
DISTANCES TO IGNITION SOURCE & FLASHBACK.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE/EVACUATE
AREA. COLLECT W/ABSORBENT MATERIAL. PLACE COLLECTED MATERIAL IN
PROPER CONTAINER. USE PROTECTIVE EQUIPMENT DURING CLEANUP. LARGE:
SHUT OFF LEAK SAFELY. D IKE/CONTAIN. PUMP TO STORAGE/SALVAGE
VESSEL. (SUPP
======================Handling and Storage ======================
Handling and Storage Precautions:STORE <100F. KEEP AWAY FROM IGNITION
SOURCES. KEEP FROM FREEZING. KEEP CONTAINERS TIGHTLY CLOSED &
UPRIGHT WHEN NOT IN USE. DON'T TAKE INTERNALLY.
Other Precautions:USE ONLY W/ADEQUATE VENTILATION. KEEP OUT OF REACH OF
CHILDREN. AVOID CONTACT W/SKIN & EYES & BREATHING OF VAPORS. EMPTY
CONTAINERS MAY CONTAIN HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN
TRANSFERRING T O PREVENT ACCUMULATION OF STATIC CHARGE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE RESPIRATORY PROTECTION IS REQUIRED, USE
ONLY NIOSH/MSHA APPROVED RESPIRATORS IAW/OSHA STANDARD 29 CFR
1910.134.
Ventilation:PROVIDE DILUTION VENTILATION/LOCAL EXHAUST TO PREVENT
BUILD-UP OF VAPORS.
Other Protective Equipment:EYE WASH, SAFETY SHOWER, IMPERVIOUS
CLOTHING, APRON
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. REMOVE/DISPOSE OF CONTAMINATED LEATHER ITEMS/SHOES/BELTS.
Supplemental Safety and Health
SPILL PROC CONT'D: USE ABSORBENT TO PICK UP REXCESS RESIDUE. KEEP
SALVAGEABLE MATERIAL & RINSE WATER OUT OF SEWERS & WATER COURSES.
SMALL: USE ABSORBENT TO PICK UP RESIDUE & DISPOSE OF PROPERLY.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212-477F
VOC Pounds/Gallon:89
Percent Volatiles by Volume:68.67
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS/ACIDS/REDUCING
AGENTS/BASES/ALUMINUM/ZINC/PEROXIDES/MAGNESIUM/CAUSTICS/MINERAL
ACIDS/SODIUM/POTASSIUM.
Stability Condition to Avoid:ELEVATED TEMPS, ULTRAVIOLET LIGHT,
FREEZING, SPARKS, OPEN FLAME & OTHER IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2, ACRID FUMES, OXYGEN,
ALDEHYDES, ACIDS
==================== Disposal Considerations ====================
Waste Disposal Methods:AVOID DISCHARGE TO NATURAL WATERS. DISPOSE OF IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:COLOR SHADES, 6808 SHELL WHITE
CAGE:72818
CAGE:72818
CAGE:01PD6
============= Composition/Information on Ingredients =============
Ingred Name:CERAMIC BONDED ALUMINA
CAS:66402-68-4
Fraction by Wt: 10-20%
OSHA PEL:10 MG/M3 (MFR)
ACGIH TLV:5 MG/M3 (MFR)
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FILBERS
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: 5-10%
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:0.2 FIBER/CC, A1
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 1-15%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:VINYL ACRYLIC COPOLYMER
CAS:25586-24-7
Fraction by Wt: 5-10%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 60-70%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC COMPOUND:23.62
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT:RATS (LUNG & ADRENAL TUMORS) & SOME EVID OF CARCIN
IN MALE RATS (ADRENAL TUMORS). NO EVID OF CARCIN WAS (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:DEMONSTRATED IN MALE & FEMALE MICE EXPOS UNDER SAME
CNDNTNS. MICROSCOPIC EXAMINATION OF LUNGS OF RATS & (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:MICE EXPOSED TO TALC REVEALED ADDNL EXPOS RELATED
EFTS PRIMARILY ASSOC W/INFLAMMATORY REPONSE.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:IMMED W/LG AMTS OF WATER, ESPECIALLY UNDER
LIDS FOR AT LST 15 MINS. IF IRRIT/OTHER EFTS PERSIST, (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:OBTAIN MED TREATMENT. INGEST:OBTAIN MEDICAL
TREATMENT IMMEDIATELY.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC:LEAK IF SAFE TO TO DO. DIKE & CONTAIN SPILL.
PUMP TO STOR/SALV VESSELS. USE ABSORB TO PICK UP EXCESS (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:RESIDUE. KEEP SALVAGEABLE MATL & RINSE WATER OUT OF
SEWERS & WATER COURSES. SM SPILLS:USE ABSORB TO PICK (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:UP RESIDUE AND DISPOSE OF PROPERLY.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:AVOIDED, USE APPROP NIOSH APPRVD RESP PROT AS
DIRECTED UNDER SPEC PROT INFO. EMPTY CNTNRS MAY CONTAIN(ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:HAZ RESIDUES. GROUND EQUIP WHEN TRANSFERRING TO PVNT
ACCUM OF STATIC CHARGE.
RTECS #:9999999ZZ
Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:IRRIT OF RESP TRACT,
LUNGS. PRLNGD INHAL MAY LEAD TO DROW, DIZZ AND/OR LT HEAD,
UNCOORDINATION, COUGH, SNEEZING, RESP PROBLEMS, ANESTH EFT/NARCOS,
LOSS OF CONSCIOUSNESS. SKIN:IRRIT. PRLNGD /RPTD CONT CAN CAUSE
DERM, BLISTERING, SEV SKIN IRRIT. POSSIBLE SENSIT TO SKIN.
EYE:IRRIT. PRLNGD/RPTD (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CONT CAN CAUSE TEARING, REDNESS, SEV
IRRIT, CORNEAL INJURY. INGEST:MAY CAUSE DROW, DIZZ AND/OR LT HEAD,
HDCH, NAUS, VOMIT, DIARR, GI DISTURB, CNS DEPRESS, ANESTH
EFT/NARCOS, KIDNEY DMG, LOSS OF CONSCIOUSNESS. INHAL OF
NON-ASBESTIFORM COSMETIC GRADE TALC FOR 2 YRS @ 6 & 18 MG/M3 PRDCED
CLEAR EVID OF (SUPDAT)
Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYG IF NEC. GET MED
HELP FOR ANY BRTHG DFCLTY. REMOVE TO FRESH AIR IF INHAL CAUSES EYE
WATERI NG, HDCH, DIZZ/OTHER DISCOMFORT. SKIN:FLUSH W/WATER. THEN
WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAMD CLTHG. WASH CONTAMD
CLTHG BEFORE RE-USE. IF IRRIT OCCURS, CONSULT PHYS. EYE:FLUSH (ING
10)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL OR FOAM WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO
EXTREME HEAT/FIRE. VAPS ARE HVR/AIR & MAY TRAVEL LONG DIST TO
SOURCE OF IGNIT & FLASH BACK. VAPS CAN FORM EXPLO (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:COMPLY W/ALL APPLIC HLTH & ENVIR REGS. ELIM
ALL SOURCES OF IGNIT. VENTIALTE AREA. EVAC ALL UNNEC PERS. PLACE
COLLECTED MATL IN PROPER CNTNR. VACUUM CLEAN SPILLAGE. COMPLETE
PERSONAL PROT EQUIP MUST BE USED DURING CLEANUP. LG SPILLS-SHUT
OFF (ING 12)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE <100F. KEEP AWAY FROM HEAT, SPKS
& OPEN FLAME. KEEP FROM FREEZING. USE ONLY W/ADEQ VENT. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:AVOID CONT W/SKIN & EYES, & BRTHG OF VAPS. KEEP
CNTNRS TIGHTLY CLSD & UPRIGHT WHEN NOT IN USE. AVOID CNDTNS WHICH
RSLT IN FORMATION OF INHALABLE PARTICLES SUCH AS
SPRAYING/ABRADING(SANDING) PAINTED SU RF. IF SUCH CNDTNS CANNOT BE
(ING 15)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:CONTROL ENVIR CONCS BELOW APPLIC STDS. USE ONLY
NIOSH APPROVED RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR
1910.134.
Ventilation:PROVIDE DILUTION VENTLALTION OR LOCAL EXHAUST TO PREVENT
BUILD-UP OF VAPORS.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
IMPERVIOUS CLOTHING, APRON.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HNDLG, ESPECIALLY
BEFORE EATING OR SMOKING.
Supplemental Safety and Health
EXPLO HAZ:MIX IN AIR & ELEVATED TEMPS. CLSD CNTNRS MAY BURST IF EXPOS
TO EXTREME HEAT/FIRE. IN CLSD TANKS, WATER/FOAM MAY CAUSE
FROTHING/ERUPTION. CNDTNS TO AVOID:FREEZING, SPKS, OPEN FLAME.
MATLS TO AVOID:HYDROGEN FLUORIDE, MAGNESIUM, CAUSTICS, MINERAL
ACIDS, SODIUM, POTASSIUM. EFTS OF OVEREXP:CARCIN IN FEMALE (ING 7)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:SHELL WHITE.
Percent Volatiles by Volume:77.69
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, REDUCING AGENTS, BASES, ALUMINUM, ZINC, METALS,
PEROXIDE, NITRIC ACID, HYDROFLUORIC ACID, (SUPDAT)
Stability Condition to Avoid:ELEVATED TEMPS, CONT W/OXIDIZING AGENT,
ALUMINUM/ZINC, ULTRAVIOLET LIGHT, HIGH CONC OF DUST, STOR NEAR
ACIDS, (SUPDAT)
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, ACRID
FUMES, OXYGEN, ALDEHYDES, TOXIC GASES, ACIDS, PROPIONALDEHYDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:KGL3500
CAGE:14655
CAGE:14655
============= Composition/Information on Ingredients =============
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
CAS:1336-36-3
RTECS #:TQ1350000
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA)
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE
TO FRESH AIR,GIVE ART.RESPIR AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE
LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIOUS
PER SON VOMIT.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES
EYES,NOSE,THROAT.
================== Physical/Chemical Properties ==================
HCC:Z3
Appearance and Odor:LIGHT STRAW COLORED LIQUID,AROMATIC ODOR
================= Stability and Reactivity Data =================
STRONG OXIDIZERS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Preparer's Name:DOD HMIS/DGSC-SSH
CAGE:JO772
CAGE:14153
CAGE:JO772
============= Composition/Information on Ingredients =============
Ingred Name:ASBESTOS, CHRYSOTILE
CAS:12001-29-5
RTECS #:CI6478500
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:2 FIBERS/CC; A1;9192
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER COMPOSITION
RTECS #:9999999ZZ
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
RTECS #:9999999ZZ
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
================== Physical/Chemical Properties ==================
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
==================== Disposal Considerations ====================
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:AXAREL 2200 HEAVY DUTY DEFLUXER/DEGREASER, 1694 BULK
CAGE:DO677
CAGE:54700
CAGE:DO677
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS; (MIXED ALIPHATIC HYDROCARBONS)
CAS:64475-85-0
RTECS #:PY8240000
Fraction by Wt: 30-60%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:2-PROPANOL, 1-PROPOXY-; (1-PROPOXY-2-PROPANOL)
CAS:1569-01-3
RTECS #:UB9351000
Fraction by Wt: 30-60%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT): 39,000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: LITTLE, IF ANY, EFTS
CAUSED BY INHAL OF VAPS FROM THIS PROD. IN HIGH CONCS, HDCH, GIDD,
MENTAL CONFUSION, NAUS, IRRIT OF UPPER RESP PASSAGES. EYES: SEV
IRRIT, NOT LIKELY TO CAUSE PERM DM G. SKIN: MILD TO SEV IRRIT.
PRLNG CONT CAN CAUSE REDNESS, SWELL & CRACKING OF SKIN. INGEST:
NAUS & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DIARR POSS. TOX INFO
(1-PROPOXY-2-ROPANOL): THIS MATL CAN BE ABSORBED THRU SKIN IN TOX
AMTS. RPTD AIRBORNE EXPOS TO 500-2000 PPM CAUSED INJURY TO CORNEA
IN RATS. INHAL EXPOS OF PREGNANT RATS TO 1500 PPM RESULTED IN
FETUS HAVING POORLY OSSIFIED HINGE LIMB PHALANGES. THIS TEST NOT
TOX FOR RABBITS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: MOVE TO FRESH AIR. IF BRTHG HAS STOPPED, GIVE ARTF
RESP. CALL FOR PROMPT MED ATTN. EYES: FLUSH W/LGE AMTS OF WATER FOR
AT LEAST 15 MIN/UNTIL IRRIT SUBSIDES. IF IRRIT PERSISTS, GET MED
ATTN. SKI N: REMOVE CONTAM CLTHG (INCL SHOES) & WASH BEFORE REUSE.
FLUSH W/LGE AMTS OF WATER. USE SOAP IF AVAIL. IF IRRIT PERSISTS,
SEEK MED ATTN. INGEST: DO NOT INDUCE VOMIT UNLESS DIRECTED BY MD.
(SUP DAT)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:111F,44C
Extinguishing Media:WATER, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL TANK WITH WATER SPRAY. EVACUATE PERSONNEL TO A
SAFE AREA.
Unusual Fire/Explosion Hazard:COMBUSTIBLE. HEATING CAN RELEASE VAPORS
WHICH CAN BE IGNITED.
================== Accidental Release Measures ==================
Spill Release Procedures:LAND SPILL: ABSORB LIQ ON APPROP MATL. PLACE
IN SEALED CONTR FOR DISP. WASTE CONCENTRATE CAN BE INCINERATED IN
APPROVED FUELS INCINERATION PROGRAM I/A/W STATE & LOCAL
REQUIREMENTS. PREVENT SPILLED MAT ERIAL FROM ENTERING SEWERS,
WATERWAYS/LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURE. STORE AT
ATMOSPHERIC PRESSURE. KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:STORE IN COOL, WELL-VENTILATED PLACE OUT OF DIRECT
SUNLIGHT AND AWAY FROM INCOMPATIBLE MATERIALS. FOLLOW ALL MSDS
SHEET AND LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF CONCS ARE OVER EXPOS LIMIT & ARE KNOWN, NIOSH
APPRVD AIR PURIFYING RESP W/ORG VAP CARTRIDGES MAY BE ACCEPTABLE.
REFER TO CARTRIDGES FOR ACCEPTABLE LEVELS. IF CONCS ARE BELOW EXPOS
LIMIT & ARE UNKNO WN, USE NIOSH APPRVD SUPPLIED AIR RESP.
Ventilation:LOCAL EXHAUST VENTILATION ACCEPTABLE.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: IF CONSCIOUS & ALERT, GIVE 2 GLASSES OF WATER. SEEK MED
ATTN IMMED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:300F,149C
Vapor Density:5.0
pH:NEUT
Solubility in Water:60%
Appearance and Odor:CLEAR LIQUID WITH ALCOHOL ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTIVE ALKALI METALS, STRONG ACIDS AND BASES.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:SMOKE, FUMES AND OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:RCRA 40 CFR 261 CLASSIFICATION: FEDERAL, STATE,
AND LOCAL LAWS GOVERNING DISPOSAL OF MATERIALS CAN DIFFER. ENSURE
PROPER DISPOSAL COMPLIANCE WITH PROPER AUTHORITIES BEFORE DISPOSAL.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:REPROSIL PUTTY BASE
CAGE:11107
CAGE:11107
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
Fraction by Wt: 100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY IRRITATE EYES, SKIN. SKIN:
POSSIBLE REDDISH RASHES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: POSSIBLE REDDISH RASHES. MAY IRRITATE
EYES & SKIN.
Medical Cond Aggravated by Exposure:REDDISH SKIN RASHES
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/LARGE AMOUNTS OF WATER, CONSULT PHYSICIAN. SKIN:
WASH THOROUGHLY W/SOAP & WATER. CONSULT PHYSICIAN. INGESTION:
CNSULT PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>415F
Extinguishing Media:SAND, FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:DURING A FIRE, IRRITATING/TOXIC GASES &
AEROSOLS MAY BE PRESENT FROM THE DECOMPOSITION/COMBUSTION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:COVER WITH AN ABSORBENT MATERIAL SUCH AS SAND
OR SAWDUST; SCOOP UP & PLACE IN AN APPROPRIATELY MARKED CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM FOODSTUFFS, BEVERAGES
& EXTREME HEAT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:LOCAL EXHAUST
Other Protective Equipment:RUBBER APRON
Work Hygienic Practices:OBSERVE NORMAL CARE FOR WORKING WITH CHEMICALS.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>392F
Spec Gravity:1.5
Evaporation Rate & Reference:(BU AC = 1): <1
Solubility in Water:NOT SOLUBLE
Appearance and Odor:REDDISH BROWN COLORED PASTE W/FAINT SWEET ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONDENSATION SILICONE
Stability Condition to Avoid:EXTREME HEAT
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MATERIAL MAY BE INCINERATED UNDER
CONDITIONS WHICH MEET FEDERAL, STATE & LOCAL ENVIRONMENTAL CONTROL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:A101113 BE SERIES AUTOMOTIVE REINHIBITOR 1
Kit Part:Y
CAGE:30255
CAGE:30255
============= Composition/Information on Ingredients =============
Ingred Name:ETHYLENE GLYCOL (SARA III)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 30-40%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:C 50 PPM,VAPOR; 9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 0-3.2%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUN MERCAPTOBENZOTHIAZOLE
CAS:2492-26-4
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POTASSIUM HYDROXIDE (SARA III) [MFR GAVE CAS# 1310-58-2
WHICH IS INCORRECT].
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 7-13%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 2 MG/M3
ACGIH TLV:C 2 MG/M3; 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SODIUM SILICATE
CAS:1344-09-8
Fraction by Wt: 3-6%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM TOLYLTRIAZOLE
CAS:64665-57-2
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM TETRABORATE, DECAHYDRATE
CAS:1303-96-4
RTECS #:VZ2275000
Fraction by Wt: 7-13%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3
ACGIH TLV:5 MG/M3; 9394
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 20-50%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION MAY CAUSE SEVERE
RESPIRATORY IRRITATION/LUNG DAMAGE;CNS EFFECTS.INGESTION MAY CAUSE
GI TRACT DISTURBANCES,BURNS TO LIPS/MOUTH/THROAT/ESOPHAGUS;CNS
EFFECTS;KIDNEY DAMAGE,CARDIAC FAILUR E.CONTACT WITH SKIN/EYES MAY
CAUSE SEVERE IRRITATION/BURNS.CHRONIC:PROLONGED EXPOSURE MAY CAUSE
DERMATITIS/SENSITIZATION
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED:HOARSENESS,DIFFICULT
BREATHING,RESPIRATORY
DISTRESS,NAUSEA,VOMITING,HEADACHE,DIZZINESS,IRREGULAR EYE
MOVEMENTS. SKIN:IRRITATION/BURNS-PAIN,REDNESS,SWELLING.
EYES:IRRITATION/BURNS-PAIN,TEARING, SWELLING,REDNESS.
INGESTED:DROOLING,DIFFICULY BREATHING/SWALLOWING/SPEAKING,ABDOMINAL
PAIN,NAUSEA,VOMITING,DIZZINESS....
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING KIDNEY
DISEASE.
======================= First Aid Measures =======================
First Aid:INHALATION-REMOVE TO FRESH AIR. RESTORE BREATHING IF NEEDED.
GET MEDICAL ATTENTION. EYE-IMMEDIATELY FLUSH WITH LOTS OF WATER FOR
30 MINUTES. GET MEDICAL ATTENTION. SKIN-FLUSH WITH WATER. REMOVE
CONTAM INATED CLOTHING. GET MEDICAL ATTENTION IF IRRITATION
DEVELOPS. INGESTION-DO NOT INDUCE VOMITING. IF CONSCIOUS, RINSE
MOUTH & DRINK GLASS OF MILK OR WATER. GET MEDICAL ATTENTION
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:WATER FOG, CARBON DIXOIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS WHEN
ENTERING A CONFINED SPACE.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR APPROPRIATE PERSONAL PROTECTIVE
CLOTHING/EQUIPMENT FOR HANDLING CORROSIVE MATERIALS. COLLECT FOR
DISPOSAL USING AN ABSORBENT MATERIAL, IE. VERMICULITE, AND PLACE IN
A CONTAINER SUITABLE FOR CORRO SIVE WASTE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VEWNTILATED
PLACE AWAY FROM INCOMPATIBLE MATERIALS. DO NOT STORE IN OPEN OR
UNLABELED CONTAINERS. KEEP TIGHTLY CLOSED.
Other Precautions:USE ONLY WITH PROPER VENTILATION.WEAR PROPER CLOTHING
WHEN HANDLING. PREVENT CONTACT WITH SKIN, CLOTHES, EYES. DO NOT
BREATH VAPORS OR MISTS THAT MAY BE GENERATED IN USING THE
CHEMICALS. KEEP AWAY FRO M COMBUSTIBLE MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF ENGINEERING CONTROLS
FAIL OR NON-ROUTINE USE OR EMERGENCY OCCURS; USE NIOSH/MSHA
APPROVED RESPIRATOR OR SUPPLIED AIR RESPIRATOR OR SCBA, AS
REQUIRED. USE IAW 29 CFR 1910.134 AND MANUFACTURER'S
RECOMMENDATIONS.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:PROTECTIVE CLOTHING (APRON,COVERALL,BOOTS)
TO PREVENT SKIN CONTACT. SUITABLE EYE WASH STATION & SAFETY SHOWER
IN AREA.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
KEY1=C2. PART A OF 2 PART KIT. FOR PART B SEE PNI B THIS NSN/CAGE.
================== Physical/Chemical Properties ==================
HCC:B1
Boiling Pt:>104.4C, 220.F
Melt/Freeze Pt:<-15.C, 5.F
Spec Gravity:1.289
pH:14.0
Solubility in Water:COMPLETE
Appearance and Odor:ORANGE-YELLOW LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NORMALLY NON-REACTIVE; HOWEVER, AVOID STRONG ACIDS, STRONG OXIDIZING
AGENTS, & MATERIALS THAT REACT W/HYDROXYL CMPDS.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON MONOXIDE
AND/OR CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MATERIAL IS A RCRA HAZARDOUS WASTE DUE TO
CORROSIVITY (D002). DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:MAGNIFLOC 6140 FLOCCULANT
CAGE:06404
CAGE:06404
============= Composition/Information on Ingredients =============
Ingred Name:NON HAZARDOUS INGREDIENTS; (ANIONIC POLYACRYLAMIDE)
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL, RAT) > 5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION OF THE VAPORS IS NOT LIKELY
TO CAUSE ADVERSE HEALTH EFFECTS. DIRECT CONTACT WITH THIS MATERIAL
MAY CAUSE MINIMAL EYE AND SKIN IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . SKIN: WASH
AFFECTED AREAS OF SKIN WITH SOAP AND WATER. EYES: IMMEDIATELY
IRRIGATE WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE WATER, CARBON DIOXIDE OR DRY CHEMICAL TO
EXTINGUISH FIRES.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:AS WITH MANY SOLIDS, ANY DUST THAT IS
GENERATED MAY BE EXPLOSIVE IF MIXED WITH AIR IN CRITICAL
PROPORTIONS AND IN THE PRESENCE OF A SOURCE OF IGNITION.
================== Accidental Release Measures ==================
Spill Release Procedures:SPILLED MATL BECOMES VERY SLIPPERY WHEN WET.
SWEEP UP SPILLS & PLACE IN WASTE DISP CNTNR. FLUSH AREA THORO
W/WATER & SCRUB TO REMOVE RESIDUE. IF SLIPPERINESS REMAINS, APPLY
MORE DRY-SWEEPING COMPOUND. DO NOT FLUSH LG QTY OF MATL TO SEWER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:MAINTAIN GOOD HOUSEKEEPING TO CONTROL
DUST ACCUMULATIONS. TO AVOID PROD DEGRADATION & EQUIP CORR, DO NOT
USE IRON, COPPER OR ALUMINUM CNTNRS/EQUIP.
Other Precautions:AVOID UNNECESSARY SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:ENGINEERING CONTROLS ARE NOT USUALLY NECESSARY IF GOOD
HYGIENE PRACTICES ARE FOLLOWED.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:BEFORE EATING, DRINKING OR SMOKING, WASH FACE
AND HANDS THOROUGHLY WITH SOAP AND WATER.
Supplemental Safety and Health
% VOLAT: 8-12 (H*2O=1)
================== Physical/Chemical Properties ==================
Solubility in Water:LIMITED BY VISCOSITY
Appearance and Odor:OFF-WHITE GRANULAR SOLID.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION
MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, AMMONIA &/OR OXIDES OF
NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE MADE IN ACCORDANCE WITH
APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:BATTERY FLUID,ACID
CAGE:2L633
CAGE:2L633
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 29%.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER,CAS#7732-18-5
CAS:7732-18-5
RTECS #:ZC0110000
===================== Hazards Identification =====================
Effects of Overexposure:FUMES NOT PRESENT AT AMBIEN TEMPS.LIQUID CAUSES
SEVERE BURNS OF SKIN & EYES.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/WTR 15MIN HOLDING EYELID OPEN.SEE DR;SKIN:BLOT IF
PRACTICAL,FLUSH W/LG AMTS OF WTR.REMOVE CLOTHNG IF CONTAMINATED,SEE
DOCTOR/
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE
Fire Fighting Procedures:COOL OUTSIDE CONT.W/WTR.DO NOT LET WTR TO
CONTACT ACID.
Unusual Fire/Explosion Hazard:MAY CAUSE FIRE IN CONTACT W/ORG.MTLS.WILL
ATTACK SOME METLS&RELEASE FLAMM&EXPL.H*2 GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:ZONE OFF CONTAM.AREA.NEUTRALIZED W/SODA
ASH,CAUSTIC SODA,LIME,AMMONIA OR OTHER ALK.AGTS.FLUSH AREA
W/LG.AMTS OF WTR FROM SAFE DISTANCE.
======================Handling and Storage ======================
Handling and Storage Precautions:STOR.ONLY IN APPVD TYPE CONT.AVOID
ROUGH HANDLING OF DRUMS.VENT DRUMS WKLY TO RELEASE PRESS.ALWAYS
HAVE WTR SAFETY SHOWERS & EYEWASH STATIONS.
Other Precautions:NO SMOKING REGULATION MUST BE ENFORCED BECAUSE OF
PRESENCE OF HYDROGEN GAS.SEE MCA CHEMICAL SAFETY DATA SHEET SD-20
SULFURIC ACID.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:PROPER ACID CANNISTER TYPE-FULL FACE PIECE(SEE
MCA DATA SHEET SD-20)
Ventilation:LOCAL EXH.& MECH.GNL TO MEET TLV.-USE CORR.RESIST.MATERIAL.
Other Protective Equipment:HARD/SOFT HATS,RUBBER SFTY SHOES W/STEEL
TOE,RUBBER APRON.
Supplemental Safety and Health
MSDS DATED 09-16-85/
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:225F,107C
Vapor Pres:<1.
Spec Gravity:1.21
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,COLORLESS,SOMETIMES CLOUDY,USUALLY ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
COMBUSTIBLE MTLS&ORGANIC MTLS.
Stability Condition to Avoid:ADDITION OF WATER.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW ALL GOVERNMENTAL REGS.-SEE MCA
MANUAL,SHEET W-3 ON NEUTRALIZATION OF ACID & ALKALINE PLT
EFFLUENTS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:MT-STARTER VI/RP507(N-P)
CAGE:4K684
CAGE:4K684
============= Composition/Information on Ingredients =============
Ingred Name:IRON ZINC OXIDE
CAS:12063-19-3
Fraction by Wt: <93%
Ingred Name:POLYPROPYLENE
CAS:9003-07-4
RTECS #:UD1842000
Fraction by Wt: <7%
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: <7%
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3; 9192
Ingred Name:POLYESTER RESIN
Fraction by Wt: <93%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50: >5G/KG (RATS)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MINIMAL RESPIRATORY TRACT IRRITATION
MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY NON-TOXIC DUST.
INHALATION: SAME AS NORMAL DUST, MAY COUGH AND RAISE THE PHLEGM.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:MINIMAL RESPIRATORY TRACT IRRITATION MAY OCCUR
AS THE EXPOSURE TO LARGE AMOUNTS OF ANY NON-TOXIC DUST. INHALATION:
SAME AS NORMAL DUST, MAY COUGH AND RAISE THE PHLEGM.
======================= First Aid Measures =======================
First Aid:SKIN: WASH WITH SOAP & WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, DRY CHEMICAL
Fire Fighting Procedures:AVOID INHALATION OF SMOKE.
Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. WHEN
DISPERSED IN AIR, IT FORMS EXPLOSIVE MIXTURES.
================== Accidental Release Measures ==================
Spill Release Procedures:IF SPILLED, SWEEP UP OR VACUUM
======================Handling and Storage ======================
Handling and Storage Precautions:NONE
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED WHEN USED AS INTENDED IN MINOLTA
EQUIPMENT.
Other Protective Equipment:FOR USE OTHER THAN NORMAL CUSTOMER, USE OF
Work Hygienic Practices:NONE
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:2.9
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK POWDER/FAINT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE TOXIC.
AVOID BREATHING OF SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:NO SPECIAL TECHNIQUES BEYOND NORMAL PRACTICE.
INSURE CONFORMITY WITH FEDERAL, STATE OR LOCAL REGULATIONS.
| 0 | gloves_not_mandatory |
===================== Product Identification =====================
Product ID:CREATIVE WOOD STAINS, ENGLISH WALNUT
CAGE:25461
CAGE:25461
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS (MFR INVALID CAS #:64747-88-7)
CAS:64742-88-7
Fraction by Wt: 55-85%
OSHA PEL:500 PPM (MFR)
ACGIH TLV:200 PPM (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION MAY CAUSE DEPRESSION
CHARACTERIZED BY THE FOLLOWING:HEADACHE, DIZZINESS, STAGGERING
GAIT, CONFUSION, UNCONSCIOUSNESS OR COMA. IRRITATION OF RESPIRATORY
TRACT. SKIN/EYES:IRRITATION. AB SORPTION THROUGH SKIN:IRRITATION.
INGESTION:MAY RESULT IN VOMITING; ASPIRATION OF LIQUID INTO LUNGS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:MUST BE AVOIDED. CHRONIC:PROLONGED
SKIN CONTACT MAY CAUSE SKIN TO CRACK OR DRY.
Medical Cond Aggravated by Exposure:DERMATITIS, ASTHMA, ALLERGIES.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH IMMED W/LG AMTS OF WATER FOR @ LST 15 MIN. TAKE TO
MD. SKIN:WASH W/SOAP & WATER. REMOVE CONTAM CLTHG & DO NOT REUSE
UNTIL LAUNDERED. IF PERSISTANT IRRIT OCCURS, GET MED ATTN.
INHAL:REMOVE V ICTIM TO FRESH AIR & PROVIDE OXYG IF BRTHG IS DFCLT.
GIVE ARTF RESP IF NOT BRTHG. GET MED ATTN. INGEST:DO NOT INDUCE
VOMIT. IF VOMIT OCCURS, KEEP HEAD BELOW HIPS TO PVNT ASPIR OF LIQ
INTO (SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:103F,39C
Lower Limits:1.0%
Upper Limits:6.0%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DO NOT USE WATER, EXCLUDE AIR, CONSULT LOCAL
FIRE MARSHAL.
Unusual Fire/Explosion Hazard:HANDLE AS FLAMMABLE LIQUID. CLOSED
CONTAINER MAY RUPTURE WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT
SURFACES AND ELECTRICAL STATIC OR FRICTIONAL SPARKS). VENTILATE
AREAS, CONTAIN BY DIKING OR ABSORBENT. CONTAIN AND REMOVE WITH
INERT ABSORBENTS AND NON-SPAR KING TOOLS. DO NOT INCINERATE CLOSED
CONTAINERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 120F. AVOID
PROLONGED SKIN CONTACT.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED ORGANIC CANISTER MASK OR AIR
PACK. USE RESPIRATORY PROTECTION UNLESS EXPOSURES ARE KNOWN TO BE
BELOW SAFE LIMITS.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS OF
THIS MATERIAL BELOW THE EXPOSURE STANDARD.
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING, PROVIDE
EMERGENCY SHOWERS AND EYEWASH.
Work Hygienic Practices:TRAIN EMPLOYEES ON ALL SPECIAL HANDLING
PROCEDURES IN HNDLG & STOR BEFORE THEY WORK WITH THIS PRODUCT.
Supplemental Safety and Health
FIRST AID PROC:LUNGS. GET MEDICAL ATTENTION.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>300F,>149C
Vapor Pres:4.5 @ 20C
Vapor Density:1
Spec Gravity:1.2
Evaporation Rate & Reference:1 (BUTYL ACETATE=1)
Solubility in Water:NIL
Appearance and Odor:TYPICAL MINERAL SPIRITS (PAINT THINNER) ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:SMOKE, TOXIC VAPORS, FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ALL WASTES IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:RTV, 51386 BLUE
Preparer's Name:CATHY GRIFFITH
CAGE:GO402
CAGE:GO402
CAGE:FELPR
============= Composition/Information on Ingredients =============
Ingred Name:ACETIC ACID (RELEASED DURING CURE) (CERCLA) VP:11.4
LD50(ORAL,RAT):3310 MG/KG LEL:5%
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 3.5%MAX
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:SEVERE IRRITANT. PROLONGED
CONTACT MAY CAUSE PERMANENT CORNEAL INJURY. SKIN:MODERATE IRRITANT.
MAY CAUSE REDNESS AND DERMATITIS. INHALATION:MAY CAUSE IRRITATION
OF RESPIRATORY TRACT. OVEREX POSURE MAY CAUSE HEADACHE, NAUSEA, AND
VOMITING. MATERIAL ASPIRATED INTO LUNGS MAY CAUSE CHEMICAL (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:PNEUMONITIS. INGESTION:MAY CAUSE
IRRITATION OF MOUTH, THROAT AND STOMACH. SYMPTOMS MAY INCLUDE
NAUSEA, ABDOMINAL PAIN AND POSSIBLE COLLAPSE.
Medical Cond Aggravated by Exposure:PREEXISTING PULMONARY AND
DERMATOLOGICAL DYSFUNCTIONS MAY BE AGGRAVATED BY EXPOSURE TO
HAZARDOUS COMPONENTS.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/PLENTY OF WATER @ LST 15 MIN. OBTAIN IMMED MED
ATTN. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREA(S) THORO W/SOAP
& WATER. CONSULT MD. INHAL:REMOVE TO FRESH AIR. IF BRTHG IS DFCLT,
GIVE O XYG. ADMIN ARTF RESP IF NOT BRTHG. OBTAIN MED ATTN.
INGEST:DO NOT INDUCE VOMIT. GIVE WATER/MILK IF CONSCIOUS & NOT
DROW. SHOULD VOMIT OCCUR, BE SURE TO KEEP HEAD BELOW HIPS TO AVOID
ASPIR OF (SUP DAT)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:300F,149C
Lower Limits:5.4%
Upper Limits:16.0%
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIP . USE WATER TO COOL EXPOSED CNTNRS. WATER STREAM DIRECTED
INTO FIRE MAY CAUSE FROTHING WITH (SUPP DATA)
Unusual Fire/Explosion Hazard:IRRIT &/OR TOX GASES/FUMES MAY BE
GENERATED BY THERMAL DECOMP/COMBUST. CLSD CNTNRS MAY
RUPTURE/EXPLODE (DUE TO PRESS BUILD-UP) WHEN EXPOSED TO EXTREME
HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. WEAR APPROPRIATE PROTECTIVE
EQUIPMENT. ABSORB WITH INERT MATERIAL. SWEEP INTO CONTAINERS WITH
LIDS. COVER LOOSELY AND REMOVE TO APPROPRIATE WASTE AREA. WASH
SPILL AREA WITH SOAP AND WA TER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE TLV IS EXCEEDED, IF USE IS PERFORMED IN A
POORLY VENTILATED SPACE OR AREA WITH LIMITED VENTILATION, USE
NIOSH/MSHA APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR IN
ACCORDANCE WITH 29 CFR 1910.134 .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:SUBSEQUENT SPREAD OF FIRE. FIRST AID PROC:VOMITUS INTO
LUNGS. OBTAIN IMMEDIATE MEDICAL ATTENTION.
================== Physical/Chemical Properties ==================
Vapor Pres:SEE ING 1
Vapor Density:HVR/AIR
Spec Gravity:1.04
pH:ACIDIC
Evaporation Rate & Reference:SLOWER (RELATIVE TO BUAC)
Solubility in Water:SLIGHT (0.1-1.0)
Appearance and Odor:SMOOTH PASTE WITH VINEGAR ODOR.
Percent Volatiles by Volume:<5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Stability Condition to Avoid:CONTAMINATION WITH MOISTURE.
Hazardous Decomposition Products:ACRID FUMES. OXIDES OF CARBON. OXIDES
OF SILICONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:REVIEW ALL LOCAL, STATE AND FEDERAL REGULATIONS
CONCERNING HEALTH AND POLLUTION FOR APPROPRIATE DISPOSAL
PROCEDURES.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:24-475 (6CO 24T)
CAGE:08163
CAGE:08163
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 35%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 65.0%
===================== Hazards Identification =====================
Effects of Overexposure:LIQUID CAUSES SEVERE BURNS OF SKIN & EYES.ACID
IS IRRITATING TO EYES, NOSE & THROAT, ULCERATION.
======================= First Aid Measures =======================
First Aid:IRRIGATE EYES WITH WATER W/LARGE QUANTITIES OF WATER FOR AT
LEAST 15 MINS WHILE REMOVING CONTAMINATED CLOTHES OR SHOES. CALL
DR. IN CASE OF EYE CONTACT.WASH CLOTHING BEFORE REUSE.DISCARD
CONTAMINATED SHOES. IN CASE OF EYE OR RESPIR. IRRIT.REMOVE PERS
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, USE H*2O CAREFULLY TO AVOID SPLATTER
& HT.
Fire Fighting Procedures:WEAR PROTECTIVE EQUIPMENT & BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:ATTACKS MANY METALS, RELEASING FLAMMABLE
HYDROGEN GAS. AVOID SPARKS, DO NOT SMOKE OR USE OPEN FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE EQUIPMENT. COVER
SPILL WITH SODIUM CARNONATE OR AN EQUAL MIXTURE OF SOA ASH & SLAKED
LIME. AFTER MIXING, ADD WATER IF NECESSARY TO FORM A SCURRY.
======================Handling and Storage ======================
Handling and Storage Precautions:PROTECT CONTAINERS AGAINST PHYSICAL
DAMAGE & PREVENT CONTACTS WITH WATER.SEPARATE FROM
CARBIDES,CHLORATES,FULMINATES,NITRATES,PICRATES & POWDERED MTLS
============= Exposure Controls/Personal Protection =============
Respiratory Protection:CHEMICAL CARTRIDGE RESPIRATOR WHEN REQUIRED.
Ventilation:LOCAL EXHAUST IS REQUIRED. MECHANICAL IS ACCEPTABLE.
Other Protective Equipment:EYEWASH FOUNTAIN & SAFETY SHOWER, RUBBER
BOOTS.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:111F
Vapor Pres:12
Spec Gravity:1.2
Viscosity:NOT RELEVANT
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR TO SLIGHTLY CLOUDY, ODORLESS.
Percent Volatiles by Volume:65.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MANY METALS (POWDERED),CARBIDES,CHLORATES,NITRATES,PICRATES.
Stability Condition to Avoid:CONTACT WITH METALS.
Hazardous Decomposition Products:SULFUR TRIOXIDE & SULFUR DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW UN-NEUTRALIZED ACID TO GET IN
SEWERS. ADD SLOWLY TO A LARGE AMOUNT OF SOLUTION OF SODA ASH &
SLAKED LIME BY STIRRING FOR NEUTRALIZATION. DISCHARGE THE SOLUTION
WITH A LARGE AMOUNT OF WATE R INTO AN APPROVED DISPOSAL AREA.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:4087 SPRED-ULTRA FLAT LATEX WALL & TRIM PAINT
CAGE:01PD6
CAGE:72818
CAGE:01PD6
============= Composition/Information on Ingredients =============
Ingred Name:WATER, H2O
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 43-48%
Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 13-18%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9192
Ingred Name:KAOLIN
CAS:1332-58-7
RTECS #:GF1670500
Fraction by Wt: 1-5%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9293
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 11-16%
Other REC Limits:NUISANCE PARTICULATE
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:VINYL ACRYLIC RESIN
CAS:25067-01-0
Fraction by Wt: 16-21%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MUCOUS MEMBRANE
IRRITATION, DROWSINESS, DIZZINESS, LIGHTHEADEDNESS, & HEADACHE.
SKIN/EYES: IRRITATION. INGESTION: LARGE AMOUNTS COULD CAUSE SERIOUS
INJURY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: MUCOUS MEMBRANE IRRITATION,
DROWSINESS, DIZZINESS, LIGHTHEADEDNESS, & HEADACHE. SKIN/EYES:
IRRITATION. INGESTION: LARGE AMOUNTS COULD CAUSE SERIOUS INJURY.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN,
RESPIRATORY, LUNG, & KIDNEY DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF
NEEDED. SKIN: WASH W/PLENTY OF WATER, THEN SOAP & WATER. EYES:
FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINS. INGESTION: OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:>200F
Extinguishing Media:DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST IF EXPOSED TO
EXTREME HEAT OR FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:COMPLY W/ALL APPLICABLE HEALTH & ENVIRONMENTAL
REGULATIONS. VENTILATE AREA. COLLECT W/ABSORBENT MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE <100F. KEEP FROM FREEZING. USE
ONLY W/ADEQUATE VENTILATION. KEEP CONTAINERS TIGHTLY CLOSED &
UPRIGHT WHEN NOT IN USE. DON'T TAKE INTERNALLY.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN,
EYES, & BREATHING VAPORS. IF SANDING IS DONE, WEAR A DUST MASK TO
AVOID BREATHING OF SANDING DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR. WEAR A DUST
MASK, IF SANDING.
Ventilation:PROVIDE MECHANICAL/LOCAL EXHAUST VENTILATION TO PREVENT
BUILD-UP OF VAPORS.
Other Protective Equipment:EYE WASH, SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING, OR
SMOKING.
Supplemental Safety and Health
11 LB/GAL.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text: 212F
Appearance and Odor:LIQUID
Percent Volatiles by Volume:62.4%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS,
Stability Condition to Avoid:ELEVATED TEMPERATURES >100F, FREEZING
Hazardous Decomposition Products:CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
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===================== Product Identification =====================
Product ID:REGENCY EXTERIOR ACRYLIC MOD WOOD & MASONRY (SUPDAT)
CAGE:FO133
CAGE:97903
CAGE:FO133
============= Composition/Information on Ingredients =============
Ingred Name:ETHYLENE GLYCOL (SARA III). VP:0.1 @ 68F. LEL:3.2%.
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:50 PPM, VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:PROPIONIC ACID, 2-METHYL-, MONOESTER
W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL. VP:1 @ 188F. LEL:0.62%.
CAS:25265-77-4
RTECS #:UF6000000
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ISOPHTHALONITRILE, TETRACHLORO-; (CHLOROTHALONIL). VP:9.2 @
338F.
CAS:1897-45-6
RTECS #:NT2600000
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BICYCLIC OXAZOLIDINES SOLUTION (HEMIACETALS); (NUOSEPT95)
CAS:56709-13-8
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC COMPOUNDS. %:137.6 LBS/GAL.
RTECS #:9999999VO
Fraction by Wt: SEE ING
Ingred Name:SUPDAT:DESIGNED TO REMOVE COMBINATION OF PARTICULATES &
VAP. WHEN USED IN CONFINED AREAS, WEAR NIOSH/MSHA APPRVD(ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:AIR SUPPLY RESPS/HOODS. USE NIOSH/MSHA APPRVD RESPS
WHEN FLAME CUTTING, WELDING, BRAZING & SANDING MATL (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:COATED W/THIS PROD. FOLLOW RESP MFR'S DIRECTIONS FOR
RESP USE.
RTECS #:9999999ZZ
Ingred Name:VENT:STDS IN MIXING, APPLICATION & CURING AREAS & TO REMOVE
SANDING DUSTS OF DRIED COATING & DECOMP PROD DURING (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:WELDING & FLAME CUTTING ON SURFACES COATED W/THIS
PRODUCT.
RTECS #:9999999ZZ
Ingred Name:CALCIUM CARBONATE
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 15%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 30%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 20%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:IRRITATION OF RESPIRATORY
TRACT; HEADACHE, NAUSEA, DIZZINESS. EYE/SKIN CONTACT:MAY CAUSE
IRRITATION. INGEST:NO EFFECTS ANTICIPATED FROM INGESTION INCIDENTAL
TO NORMAL USE. LARGER QUANTITIE S MAY CAUSE DISTRESS OF DIGESTIVE
TRACT& NAUSEA. CHRONIC:PROLONGED & REPEATED BREATHING OF SPRAY MIST
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:&/OR SANDING DUST OVER A PERIOD OF
YEARS MAY CAUSE DUST DISEASE OF THE LUNGS.
Medical Cond Aggravated by Exposure:NONE WHEN USED I/A/W SAFE HANDLING
& USE INFORMATION.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. EYES:FLUSH W/LARGE AMOUNTS OF
WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ASSISTANCE. SKIN:REMOVE
W/SOAP & WATER. REMOVE SOILED CLOTHING. INGEST:DRINK 1-2 GLASSES OF
WATER TO DILUTE. DO NOT INDUCE VOMITING. CONSULT MD IMMEDIATELY.
TREAT SYMPTOMATICALLY. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:NONE
Lower Limits:SEE INGS
Extinguishing Media:IN CASE OF FIRE, USE CO*2, DRY CHEMICAL, FOAM OR
OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
SUMMON PROFESSIONAL FIREFIGHTERS. WATER SPRAY MAY BE INEFT. IF
WATER IS USED, FOG NOZZ ARE PREF. IF(SUPDAT)
Unusual Fire/Explosion Hazard:DUE TO PRESS BUILD-UP, CLSD CNTNRS EXPOS
TO EXTREME HEAT MAY EXPLODE. AFTER WATER EVAPS, REMAINING MATL WILL
BURN. DURING EMER CNDTNS, OVEREXP TO DECOMP(SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:WASH W/WATER. BEFORE ATTEMPTING CLEAN-UP,
REFER TO HAZARD CAUTION INFORMATION IN OTHER SECTIONS OF THIS MSDS.
CONTAIN SPILLED MATERIAL & REMOVE W/INERT ABSORBENT. STORE IN
CLOSED CONTAINER UNTIL PROPE RLY DISPOSED OF.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE <110F & KEEP FROM FREEZING. KEEP
CONTAINER CLOSED WHEN NOT IN USE. DO NOT REUSE EMPTY CONTAINERS.
KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DO NOT GET IN EYES. DO NOT BREATHE VAPORS, SPRAY MIST
OR SANDING DUST. USE ONLY W/ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN SPRAY APPLIED IN OUTDOOR/OPEN AREAS
W/UNRESTRICTED VENT & DURING SANDING/GRINDING OPERATIONS, USE
NIOSH/MSHA APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE
PARTICLES OF OVERSPRAY & SANDING DUST . WHEN USED IN RESTRICTED
AREAS,(SUPDAT)
Ventilation:PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO
KEEP AIR CONTAM CONC BELOW CURRENT APPLIC SFTY & HLTH (ING 12)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. EYE PROT:
SPLASH GUARDS/SIDE SHIELDS .
Work Hygienic Practices:REMOVE & WASH SOILED CLTHG BEFORE REUSE. WASH
HANDS BEFORE EATING, SMOKING/USING THE WASHROOM.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:FINISH, W79 PATIO YELLOW. FIRE FIGHT
PROC:EXPOS TO FIRE/EXTREME HEAT, WATER SHOULD BE USED TO COOL CLSD
CNTNRS & PVNT PRESS BUILD-UP/POSS AUTO-IGNIT. EXPLO HAZ:PRODS MAY
CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN.
RESP PROT:WEAR NIOSH/MSHA APPRVD CHEM/MECH FILTERS (ING 9)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.38
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:66.4
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/MATERIALS THAT ARE INCOMPATIBLE W/WATER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY CAUSE HAZ FUMES WHEN HEATED TO
DECOMP. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE & OXIDES
OF METALS IN INGS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CALCOMP CLEANER CL58
Preparer's Name:DAVE GOLD
CAGE:14656
CAGE:14656
============= Composition/Information on Ingredients =============
Ingred Name:ISOPARAFFINIC HYDROCARBONS (NAPHTHA PETROLEUM),
HYDROTREATED HEAVY, NON AROMATIC HEAVY NAPHTHA) ISOPAR G *93-3*
CAS:64742-48-9
Fraction by Wt: 100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INHALATION:
RESPIRATORY TRACT IRRITATION, CENTRAL NERVOUS SYSTEM EFFECTS,
ANESTHETIC EFFECTSM POSSIBLE DEATH. ASPIRATION MILD TO SEVERE
PULMONARY INJURY, POSSIBLY DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: DRYING. INHALATION: HEADACHES, DIZZINESS,
ANESTHETIA.
Medical Cond Aggravated by Exposure:SENSITIVITY, DERMATITS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR 15 MINUTES. SKIN: REMOVE CONTAMINATED
CLOTHING. WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO
FRESH AIR. IF BREATHING IRREGULAR OR STOPPED, START CPR OR
ADMINISTER OXYG EN. INGESTION: DILUTE CONTENTS OF STOMACH W/SEVERAL
GLASSES OF WATER. DON'T INDUCE VOMITING. OBTAIN MEDICAL ATTENTION
IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:104F
Lower Limits:0.8%
Upper Limits:7%
Extinguishing Media:FOAM, DRY CHEMICAL, CO2, WATER SPRAY
Fire Fighting Procedures:NORMAL PROCEDURE FOR COMBUSTIBLE LIQUIDS.
Unusual Fire/Explosion Hazard:KEEP PRODUCT AWAY FROM SOURCES OF
IGNITION SUCH AS HEAT, SPARKS, PILOT LIGHTS, ELECTRICAL APPLIANCES
& OPEN FLAMES. AVOID EXTINGUISHMENT W/WATER.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. RECOVER FREE
PRODUCT W/SAND/EARTH/OTHER SUITABLE ABSORBENT TO THE SPILLED
LIQUID. AVOID BRETHING VAPORS. VENTILATE AREA. CLEANUP/DISPOSE OF
PROPERLY. OBSERVE PRECAUTIONS FO R VOLATILE/COMBUSTIBLE VAPORS FROM
MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. DON'T SMOKE WHEN USING PRODUCT. MINIMIZE BREATHING VAPOR OR
MIST. USE ADEQUATE VENTILATION.
Other Precautions:AVOID PROLONGED OR REPEATED SKIN CONTACT. EMPTY
CONTAINERS MAY RETAIN RESIDUE & CAN BE DANGEROUS. DISPOSE OF
PROPERLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:CHEMICAL CARTRIDGE RESPIRATOR EFFECTIVE FOR
ORGANIC VAPORS.
Ventilation:ADEQUATE
Other Protective Equipment:CHEMICAL RESISTANT APRON
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:311-348F
Melt/Freeze Pt:M.P/F.P Text:<0F
Vapor Pres:<10
Vapor Density: 5.0
Spec Gravity:0.75
pH: 7
Evaporation Rate & Reference:(N-BU AC = 1): 0.3
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, WATER WHITE LIQUID. FAINT PETROLEUM
HYDROCARBON ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, CHLORINE, CONCENTRATED OXYGEN, SODIUM HYPOCHLORITE OR
CALCIUM HYPOCHORITE.
Stability Condition to Avoid:WATER, IGNTION SOURCES
Hazardous Decomposition Products:SMOKE, CO, ALDEHYDES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS. INCINERATION OR RECYCLING FOR USE AS PARTS
CLEANING SOLVENTS. RECYCLED MATERIALS SHOULD NOT BE USED W/CALCOMP
PLOTTERS. D001.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:PETROLEUM ETHER
Preparer's Name:C.A.EISENHARD
CAGE:63415
CAGE:60777
CAGE:63415
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM ETHER
CAS:8030-30-6
Fraction by Wt: 100%
Other REC Limits:100 PPM
OSHA PEL:100 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HAZARDOUS LIQUID AND VAPORS. MAY CAUSE
HEMORRGHAGES INTO VITAL ORAGANS. INHALATION: ANESTHETIC EFFECTS,
INTOXICATION. INGESTION: NARCOSIS, DROWSINESS. SKIN:MILD
IRRITATION. CHRONIC: INCREASED SUSCEPTI BILITY TO ALCOHOL,
DERMATITIS.
Effects of Overexposure:INTOXICATION, HEADACHE, NAUSEA, COMA, VOMITING,
DROWSINESS, UNCONSCIOUSNESS, PULMONARY EDEMA.
Medical Cond Aggravated by Exposure:ALCOHOLISM.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/OXYGEN IF NEEDED.
EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. GET MEDICAL HELP. SKIN
CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS
PERSIS T. INGESTION:DO NOT INDUCE VOMITING, GETMEDICAL HELP
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:-50F ESTIMATED
Lower Limits:1.1
Upper Limits:5.9
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS
Unusual Fire/Explosion Hazard:CONFINED MATERIAL MAY EXPLODE UPON
HEATING.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. VENTILATE THE
AREA. ABSORB ON INERT MATERIAL. STORE IN CLOSED CONTAINERS.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA.
KEEP CONTAINERS TIGHTLY CLOSED. KEEP AWAY FROM IGNITION SOURCES.
Other Precautions:USE CAUTION WHEN HANDLING OR CLEANING EMPTY
CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR FOR ORGANIC VAPOR OR
SUPPLIED AIR RESPIRATOR OR SELF CONTAINED BREATHING APPARATUS IF
OVER TLV
Ventilation:MECHANICAL OR LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV.
Other Protective Equipment:EYE WASH, QUICK DRENCH SHOWER.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE WHILE WORKING WITH
THIS PRODUCT.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:=30.C, 86.F
B.P. Text:86.0F,30.0C
Vapor Pres:760 MMHG
Vapor Density:2.5
Spec Gravity:0.642
Evaporation Rate & Reference:>1 (BU AC =1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS TO LIGHT YELLOW LIQUID, ETHER ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS.
Stability Condition to Avoid:IGNITION SOURCES, HIGH TEMPERATURES, HOT
SURFACES.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:FORMULA 2000
CAGE:53542
CAGE:53542
============= Composition/Information on Ingredients =============
Ingred Name:NITRIC ACID (SARA III)
CAS:7697-37-2
RTECS #:QU5775000
OSHA PEL:2 PPM/4 STEL
ACGIH TLV:2 PPM/4 STEL; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:THIOUREA (SARA III)
CAS:62-56-6
RTECS #:YU2800000
Fraction by Wt: 5%
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION OR DAMAGE TO TISSUE.
SKIN: IRRITATION. INHALATION: MAY CAUSE IRRITATION TO NASAL MUCOUS
MEMBRANES & RESPIRATORY TRACT. INGESTION: IRRITATION OR CORROSION
TO DIGESTIVE TRACT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: IRRITATION OR DAMAGE TO TISSUE. SKIN:
IRRITATION. INHALATION: IRRITATION TO NASAL MUCOUS MEMBRANES &
RESPIRATORY TRACT. INGESTION: IRRITATION OR CORROSION TO DIGESTIVE
TRACT.
======================= First Aid Measures =======================
First Aid:EYES: IRRIGATE W/WATER FOR AT LEAST15 MINS. SKIN: RINSE RINSE
W/COPIOUS AMOUNTS OF WATER &/OR WASH W/SOAP & WATER. INHALATION:
REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING, HAVE CERTIFIED
INDIVIDUAL A DMINISTER FIRST AID/CPR. INGESTION: ADMINISTER 2-4
GLASSES OF MILK OR WATER. CONTACT PHYSICIAN OR POISON CONTROL
CENTRAL IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:ANY APPLICABLE TO PRIMARY CAUSE OF FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APARATUS WHEN ENTERING BUILDING.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE SPILL & SOAP UP W/SAND OR A COMMERCIALLY
AVAILABLE ACID SPILL KIT. SWEEP UP ABSORBENT & PLACE IN A HAZARDOUS
WASTE CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T STORE FOOD, DRINK OR TOBACCO IN
AREA WHERE THEY MAY BECOME CONTAMINATED W/THIS MATERIAL. STORE IN
WELL-VENTILATED AREA.
Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED. DON'T STORE NEAR HEAT
OR <32FF.
============= Exposure Controls/Personal Protection =============
Ventilation:LOCAL EXHAUST/MECHANICAL: USE ONLY IN ADEQUATELY VENTILATED
ROOM
Other Protective Equipment:RUBBER OR PLASTIC APRON
Work Hygienic Practices:REMOVE/WASH CONTAMINATED CLOTHING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Spec Gravity:1.058
pH:1.0
Evaporation Rate & Reference:(BU AC = 1): AS WATER
Solubility in Water:COMPLETE
Appearance and Odor:SCENTED LIQUID, RED COLOR ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALI
Stability Condition to Avoid:UNDILUTED CONCENTRATES (COMPONENTS 1 & 2)
MUSTN'T BE MIXED. DON'T STORE NEAR HEAT OR <32F.
Hazardous Decomposition Products:NITRATES OF OXYGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:REMOVE FREE LIQUID & DISPOSE OF IN ACCORDANCE
W/FEDERAL, STATE & LOCAL REGULATIONS.
======================================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ROYCO 60MS
CAGE:07950
CAGE:07950
============= Composition/Information on Ingredients =============
Fraction by Wt: >70%
Ingred Name:SODIUM NITRITE (SARA III)
CAS:7632-00-0
RTECS #:RA1225000
Fraction by Wt: <2%
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Fraction by Wt: <28%
===================== Hazards Identification =====================
Effects of Overexposure:EYES:IRRIT.INGEST:CAUSE GI
DISTURB:CATHARSIS,DIARRHEA.ASPIR W/ SUBSEQ PULMONARY INFIL MAY
OCCUR.SUPP
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/ H*20 FOR 15 MIN,HOLD EYELIDS OPEN.GET MED
ATTN.SKIN:WASH W/ SOAP & WATER.GET MED ATTN IF IRRIT PERSISTS OR
INJECT UNDER SKIN.LAUNDER CONTAM CLOTH.INHAL:REMOVE VICTIM TO FRESH
AIR,PROVIDE O*2 IF BREATH IS DIFFICULT.GET MED ATTN.OTH PRECAU
===================== Fire Fighting Measures =====================
Flash Point:500F,260C COC
Extinguishing Media:CO*2,DRY CHEM POWDER,FOAM EXTINGUISHER.DO NOT USE
H*20 JET
Fire Fighting Procedures:USE SCBA,PROTECT EQUIP.WATER
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP EXCESS GREASE.CLEAN AREA W/
APPROPRIATE CLEANER
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL,DRY PLACE W/ ADEQUATE
VENT.KEEP AWAY FROM IGNIT SOURCES.MINIMIZE SKIN CONTACT.WASH W/
SOAP & WATER BEFORE EATING,SMOKING,USING TOILET
Other Precautions:FIRST AID:INGEST:DO NOT INDUCE VOMIT.IF VOMIT
OCCUR,KEEP HEAD LOWER THAN HIPS TO HELP PREVENT ASPIR.TREAT
SYMPTOMATICALLY,SUPPORTIVELY.GET MED ATTN.LAUNDER CONTAM CLOTH
BEFORE REUSE.
============= Exposure Controls/Personal Protection =============
Ventilation:LOCAL EXHAUST
Other Protective Equipment:OTHER CLOTH AS NEEDED TO MINIMIZE SKIN
CONTACT
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:N/R PER MFR
Evaporation Rate & Reference:N/K PER MFR
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER BUTTERY CLAY THICKENED GREASE W/ SLIGHT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT,OPEN FLAME
Hazardous Decomposition Products:THERMAL:CARBON MONOXIDE & UNIDENTIFIED
ORGANIC COMPOUNDS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN AN APPROPRIATE DISPOSAL FACILITY
IN COMPLIANCE W/ LOCAL REGULATIONS.ANY WATER COURSES OR SEWERS
ENTERING/LEAVING TO SURFACE WATERS THAT CAUSE A SHEEN MUST BE
REPORTED TO THE NATIONAL RES PONSE CENTER 800-424-8802
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ATOMIZED ALUMINUM POWDER, CODE:01-0840
CAGE:60728
CAGE:60728
============= Composition/Information on Ingredients =============
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: >98.5%
OSHA PEL:15MG/M3 DUST/5 FUME
ACGIH TLV:10MG/M3 DUST; 9192
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:DUST MAY CAUSE RESPIRATORY TRACT
IRRITATION.
Effects of Overexposure:INHALATION:HIGH CONCENTRATION CAN CAUSE
RESPIRATORY TRACT IRRITATION;EYES:DUST MAY CAUSE
IRRITATION;SKIN:REPEATED AND PROLONGED CONTACT MAY CAUSE SLIGHT
IRRITATION;INGESTION:NEGLIGIBLE EFFECTS.
Medical Cond Aggravated by Exposure:PRE-EXISTING UPPER RESPIRATORY AND
LUNG DISEASE SUCH AS,BUT NOT LIMITED TO,BRONCHITIS,EMPHYSEMA AND
ASTHMA.
======================= First Aid Measures =======================
First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF
NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH;
GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER
SYMPTOMS OF OVEREXPOSURE.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE CLASS"D" DRY CHEMICAL EXTINGUISHING AGENTS SUCH
AS DRY SAND; DO NOT USE WATER OR HALOGENATED AGENT AS EXTINGUISHER.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS IN
PRESSURE DEMAND MODE;GENTLY COVER THE BURNING POWDER WITH
EXTINGUISHER(DO NOT MIX WITH POWDER).PREVENT DUST FORMATION.
Unusual Fire/Explosion Hazard:WATER & BURNING ALUMINUM POWDER REACT
VIOLENTLY FORMING HYDROGEN & ALUMINUM OXIDE.ALUMINUM DUST MAY BE
IGNITED BY STATIC DISCHARGE.DUST IN AIR MAY BE EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL IGNITION SOURCES.USE NON-SPARKING
TOOLS(SHOVELS).WEAR APPROPRIATE PROTECTIVE EQUIPMENTS.TRANSFER
SPILLED MATERIAL TO A LEAK PROOF CONTAINER FOR HAZARDOUS WASTE
DISPOSAL.IF VACUUM CLEANER IS USED,IT SHOULD BE GROUNDED TO
PREVENT STATIC.
======================Handling and Storage ======================
Handling and Storage Precautions:USE NON-SPARKING HANDLING
EQUIPMENT.COVER AND RESEAL PARTIALLY EMPTY CONTAINERS.KEP
COMPLETELY DRY.STORAGE AREA MUST BE OF FIRE RESISTANT CONSTRUCTN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROVED DUST MASK
Ventilation:LOCAL EXHAUST TO KEEP BELOW TLV LIMITS.
Supplemental Safety and Health
TYPE II MATERIAL OF SPEC MIL-P-14067 IS ALUMINUM
POWDER,ATOMIZED,SPHEROIDAL OR GRANULAL SHAPED; FOR SHIPPING
INFORMATION OF THIS PRODUCT CHECK DGSC-SLM CASE HISTORY
NO.87252H,PARAGRAPH 3(D).
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:2.70
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SILVERY METALLIC,NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER,HALOGENATED HYDROCARBONS,MINERAL ACIDS,ALKALIS AND STRONG
OXIDIZING MATERIALS.
Stability Condition to Avoid:IMPROPER STORAGE WHICH WOULD ALLOW
INTRODUCTION OF WATER/MOISTURE,HEAT,SPARKS & FOREIGN MATERIAL.
Hazardous Decomposition Products:ALUMINUM WHEN REACTS WITH WATER,ACIDS
OR ALKALIS,IT FORMS COMBUSTIBLE HYDROGEN GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:FOR DISPOSAL OF THIS MATERIAL AS A WASTE,ACT IN
ACCORDANCE WITH ALL APPLICABLE FEDERAL,STATE & LOCAL WASTE
MANAGEMENT REGULATIONS.
| 0 | gloves_not_mandatory |
=======================================================
NIIN: 00-056-3617
Product ID: SHIELD ARC 85, AWS E7010-A1
Cage: 36232
=======================================================
Contractor Summary
=======================================================
Cage: 36232
=======================================================
Item Description Information
=======================================================
Item Name: ELECTRODE,WELDING
=======================================================
Ingredients
=======================================================
Cas: 1309-37-1
RTECS #: NO7400000
% Wt: <5
OSHA PEL: 10 MG/M3 (FE)
ACGIH TLV: 5MG(FE)/M3FUME,B2
------------------------------
Cas: 65996-61-4
% Wt: <5
OSHA PEL: 10 MG/M3 (MFR)
ACGIH TLV: 10 MG/M3 (MFR)
------------------------------
Cas: 1344-09-8
% Wt: <5
OSHA PEL: 10 MG/M3 (MFR)
ACGIH TLV: 10 MG/M3 (MFR)
------------------------------
Cas: 1332-58-7
RTECS #: GF1670500
% Wt: <5
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 2 MG/M3 TDUST
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
% Wt: <5
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 7439-96-5
RTECS #: OO9275000
% Wt: 1
OSHA PEL: C 5 MG/M3 DUST
ACGIH TLV: 5 MG/M3 DUST
------------------------------
Cas: 65996-74-9
% Wt: 0.5
OSHA PEL: 10 MG/M3
ACGIH TLV: 5 MG/M3
------------------------------
Cas: 7439-98-7
RTECS #: QA4680000
% Wt: 0.5
OSHA PEL: 10 PPM
ACGIH TLV: 10 PPM
------------------------------
Cas: 7439-89-6
RTECS #: NO4565500
% Wt: 80
OSHA PEL: 10 MG/M3 (MFR)
ACGIH TLV: 10 MG/M3 (MFR)
------------------------------
OPERATION INCL THOSE ORIGINATING FROM VOLAT,
-----------------------------
METAL & COATING, ETC, AS NOTED ABOVE.
-----------------------------
PRIMARILY IRON OXIDE, SECONDARILY COMPLEX
-----------------------------
MAX FUME EXPOS GUIDELINE & PEL FOR PROD IS
-----------------------------
DIOXIDE. OZONE & NITROGEN OXIDES MAY BE
-----------------------------
GASES TO WHICH WORKERS ARE EXPOSED BY TAKING
-----------------------------
ZONE. IMPROVE VENT IF EXPOS ARE NOT
-----------------------------
AMERICAN WELDING SOCIETY, 550NW LEJEUNE RD, MIAMI FL 33126.
-----------------------------
STRUCTURES/WHEN IN CRAMPED POSITIONS
-----------------------------
UNAVOIDABLE/ACCIDENTAL CONT W/WORKPIECE, USE THE FOLLOWING
-----------------------------
ARC WELDER WITH REDUCED VOLTAGE CONTROL.
-----------------------------
-----------------------------
-----------------------------
-----------------------------
WELL AS DARK SUBSTANTIAL CLTHG. TRAIN THE
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ELEC ARC WELDING MAY CREATE ONE/MORE OF THE FOLLOWING HLTH
HAZ: FUMES & GASES CAN BE DANGEROUS TO YOUR HLTH. COMMON ENTRY IS INHAL.
OTHER POSS RTES ARE SKIN CONT & INGEST. ACUTE: OVEREXP TO WELDING FU MES
MAY RSLT IN DISCOMFORT SUCH AS METAL FUME FEVER, DIZZ, NAUS/DRYNESS/IRRIT OF
NOSE, THROAT/EYES. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: CHRONIC: OVEREXP TO WELDING
FUMES CAN LEAD TO SIDEROSIS (IRON DEPOSITS IN LUNG) & MAY AFFECT PULM
FUNCTION. MANGANESE OVEREXP CAN AFFECT CNS, RSLTG IN IMPAIRED SPEECH &
MOVEMENT. BRONCH & SO ME LUNG FIBROSIS HAVE BEEN REPORTED. ARC RAYS CAN
INJURE EYES & BURN SKIN. ELEC SHOCK CAN KILL. IF WELDING MUST
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: CALL FOR MD AID. EMPLOY FIRST AID TECHNIQUES REC BY AMERICAN RED
CROSS. INHAL:IF BRTHG DFCLT GIVE OXYGEN. IF NOT BRTHG, EMPLOY CPR
(CARDIOPULMONARY RESUSCITATION) TECHNIQUES. IN CASE OF ELEC SHOCK, TU RN OFF
POWER & FOLLOW REC TREATMENT. INALL CASES CALL MD. EYES:FLUSH W/POTABLE
WATER FOR AT LEAST 15 MIN. SEE MD(FP N). SKIN:FLUSH W/COPIOUS AMTS OF WATER.
SEE MD(FP N). INGEST:CALL MD IMMED(FP N).
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR
LINER AS ORDINARY WASTE IN AN ENVIRONMENTALLY ACCEPTABLE MANNER UNLESS
OTHERWISE NOTED. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULAT IONS (FP N).
Handling And Storage Precautions: READ & UNDERSTAND MFR'S INSTRUCTIONS
& PREC LABEL ON PROD. REQUEST LINCOLN SFTY PUBLICATION E205.
Other Precautions: SEE AMERICAN NATIONAL STD Z49.1, 'SFTY IN WELDING &
CUTTING' PUBLISHED BY AMERICAN WELDING SOCIETY, 550 NW LEJEUNE RD, MIAMI, FL
33126 & OSHA PUB 2206 (29CFR1910), US GOVERNMENT PRINTING OFFICE, WASHI
NGTON DC 20402 FOR MORE DETAILS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NON FLAMMABLE.
Extinguishing Media: USE MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: WELDING ARC AND SPARKS CAN IGNITE COMBUSTIBLES
AND FLAMMABLE PRODUCTS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRABLE FUME/AIR-SUPPLIED
RESPIRATORS WHEN WELDING IN CONFINED SPACE/GENERAL WORK AREA WHEN LOCAL
EXHAUST/VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV.
Ventilation: USE ENOUGH VENTILATION, LOCAL EXHAUST AT ARC/BOTH TO KEEP FUMES
& GASES FROM WORKER'S BRTHG ZONE & GEN AREA.
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
WEAR HAND, HEAD & BODY PROT WHICH HELP TO PREVENT INJURY FROM
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: CNDTNS TO AVOID: QUALITY & AMT OF VENT,
POSITION OF WELDER'S HEAD W/RESPECT TO FUME PLUME, PRESENCE OF CONTAMINANTS
IN ATM (SUCH AS CHLORINATED HYDROCARBON VAPS FROM CLEANING & DEGREASING
ACTIVITIES).HAZ DECOMP PROD: WELDED, PROC & ELECTRODES USED. WHEN
ELECTRODE IS CONSUMED, FUME & GAS DECOMP PROD GENERATED
=======================================================
Physical/Chemical Properties
=======================================================
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: COATINGS ON METAL BEING WELDED (SUCH AS PAINT,
PLATING/GALVANIZING), NUMBER OF WELDERS & VOL OF WORK AREA, (SUP DAT)
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: WELDING FUMES & GASES CANNOT BE CLASSIFIED
SIMPLY. COMPOSITION & QTY OF BOTH ARE DEPENDENT UPON METAL BEING (SUP DAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 45032
Product ID: SHIELD ARC 85, AWS E7010-A1
Review Date: 02/13/1997
Multiple KIT Number: 0
Review IND: Y
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: SHIELD ARC 85, AWS E7010-A1
Cage: 36232
Company Name: THE LINCOLN ELECTRIC CO
Street: 22801 ST CLAIR AVE
Zipcode: 44117-1199
Label Required IND: Y
Date Of Label Review: 07/06/1995
Status Code: C
Label Date: 07/06/1995
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: OVEREXPOSURE TO WELDING FUMES MAY RESULT IN
DISCOMFORT SUCH AS METAL FUME FEVER, DIZZINESS, NAUSEA, DRYNESS, OR
IRRITATION OF NOSE, THROAT OR EYES. CHRONIC: MAY LEAD TO SIDEROSIS, AND MAY
AFFEC T LUNG FUNCTION. OVEREXPOSURE TO MANGANESE CAN AFFECT THE CENTRAL
NERVOUS SYSTEM.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:58101 BAR-OX INT-EXT ALKYD QUICK DRY GLOSS ENAMEL WHITE
CAGE:EO559
CAGE:EO559
CAGE:6R552
============= Composition/Information on Ingredients =============
Ingred Name:MEDIUM ALIPHATIC NAPHTHA (AROMATIC 100), PARAFFIN-NAPTHANES
MINERAL SPIRITS *93-4*
CAS:64742-88-7
Fraction by Wt: 35%
Other REC Limits:100 PPM
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:ALKYD RESINS*92-3*
CAS:63148-69-6
Fraction by Wt: 30%
Ingred Name:TITANIUM DIOXIDE, TIO2
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 25%
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM (DUST)
Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE*93/4*
CAS:64742-89-8
Fraction by Wt: <5%
OSHA PEL:300 PPM
ACGIH TLV:300 PPM
Ingred Name:HYDRATED ALUMINA, ALUMINUM HYDROXIDE, ALUMINUM OXIDE
HYDRATEALUMINA TRIHYDRATE, ALUMINUM TRIHYDROXIDE
CAS:21645-51-2
RTECS #:BD0940000
Fraction by Wt: <5%
OSHA PEL:15 MG/CUM (DUST)
ACGIH TLV:2 MG/CUM (DUST)
Ingred Name:VOL ORGANIC CMPD: 3.72 LBS/GAL LESS WATER
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY IRRITATION,
BRAIN/NS AFFECTS. EXTREME EXPOSURE CAN RESULT IN RESPIRATORY
ARREST. EYES/SKIN: IRRITATION. INGESTION: GI IRRITATION.
REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MA Y CAUSE PERMANENT
BRAIN/NS DAMAGE. PROLONGED/REPEATED BREATHING OF MIST/DUST OVER
YEARS MAY CAUSE DUST DISEASE OF LUNGS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DIZZINESS, HEADACHE, NAUSEA,
WEAKNESS, FATIGUE, UNCONSCIOUSNESS, VOMITING, DIARRHEA.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. ADMINISTER CPR IF NEEDED.
EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN:
WASH THOROUGHLY W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING.
ASPIRAT ION HAZARD. OBTAIN MEDICAL ATTENTION INALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:92F
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, OTHER NFPA APPROVED METHOD
FOR TREATING CLSS B FIRE
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT INCLUDING SCBA.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. COOL CLOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HEAT MAY
EXPLODE. DON'T USE WELDING/CUTTING TORCH ON/NEAR CONTAINER AS
PRODUCT/ITS RESIDUE MAY IGNITE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. DON'T SMOKE.
AVOID BREATHING VAPORS. VENTILATE AREA. CONTAIN & REMOVE W/INERT
ABSORBENT & NON-SPARKING TOOLS. STORE IN CLOSED CONTAINERS UNTIL
PROPERLY DISPOSED OF.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM IGNITION SOURCES. DON'T
STORE >120F. VAPORS MAY IGNITE EXPLOSIVELY/CAUSE A FLASH FIRE.
MAINTAIN CONTINUOUS FLOW OF FRESH AIR.
Other Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. DON'T
TRANSFER TO BOTTLES/OTHER UNLABELLED CONTAINERS. DON'T REUSE EMPTY
CONTAINERS. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRA TING & INHALING MAY BE HARMFUL/FATAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:OUTDOOR/OPEN AREAS/DURING SANDING/GRINDING
OPERATIONS: USE NIOSH/MSHA APPROVED MECHANICAL FILTER. RESTRICTED
AREAS: NIOSH/MSHA APPROVED CHEMICAL/MECHANICAL FILTERS. CONFINED
AREAS: NIOSH/MSHA APPROVEDAIR SUPPLY/HOODS.
Ventilation:GENERAL DILUTION, LOCAL EXHAUST. EXPLOSION PROOF.
Other Protective Equipment:SOLVENT IMPERMEABLE CLOTHING & BOOTS, SPLASH
GUARDS/SIDESHIELDS
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS BEFORE EATING, SMOKING, USING WASHROOM.
Supplemental Safety and Health
HEAVY SOLVENT VAPORS SHOULD BE REMOVED FROM LOWER LEVELS OF THE WORK
AREA & ALL IGNITION SOURCES SHOULD BE ELIMINATED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:246-390F
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN EHTER
Percent Volatiles by Volume:58
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, FLAME, SPARKS, TEMP >120F & OTHER
IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2, OXIDES OF METALS LISTED IN
THE INGREDIENTS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CRAYOLA WASHABLE PAINT, 54-2129, 048-TURQUOISE
CAGE:85419
CAGE:85419
============= Composition/Information on Ingredients =============
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)
CAS:14807-96-6
RTECS #:WW2710000
Other REC Limits:20 MPPCF (MFR)
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST
Ingred Name:CLAY (KAOLIN); (KAOLIN)
CAS:1332-58-7
RTECS #:GF1670500
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE/CHRONIC:NONE KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:NONE KNOWN.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. CONTACT
MD. SKIN:WASH THOROUGHLY W/SOAP & WATER. INGEST:DO NOT INDUCE
VOMITING. CONTACT MD OR POISON CONTROL CENTER. INHAL:REMOVE PERSON
TO FRESH AIR.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:WATER, FOAM, CO*2.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:DIKE TO CONTAIN SPILL. KEEP OUT OF SEWERS &
WATERCOURSES. ABSORB W/INERT & PLACE IN CONTAINER FOR DISPOSAL.
FLUSH RESIDUAL W/COPIOUS AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NOT REQUIRED.
Ventilation:NOT REQUIRED.
Other Protective Equipment:NOT REQUIRED.
Work Hygienic Practices:CLEAN, SAFE WORK PRACTICES.
Supplemental Safety and Health
SPEC GRAV:1.19-1.31 (H*2O=1).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>215F,>102C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Density:<1
Spec Gravity:SUPP DATA
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:DISPERSES IN WATER
Appearance and Odor:VARIOUS COLORS; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE & CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:N-ACETYL-DL-ALLYLGLYCINE, A7637
CAGE:21076
CAGE:21076
============= Composition/Information on Ingredients =============
Ingred Name:N-ACETYL-DL-ALLYLGLYCINE
CAS:50299-14-4
= Wt:100.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL BY INHALATION,
INGESTION OR SKIN ABSORPTION. CAUSES IRRITATION. MATERIAL IS
IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:INGESTION: WASH OUT MOUTH WITH WATER PROVIDED PERSON IS
CONSCIOUS. CALL MD. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. CALL
MD. INHALATI ON: REMOVE TO FRESH AIR. IF BREATHING BECOMES
DIFFICULT, CALL MD. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING THE
EYELIDS WITH FINGERS. CA LL MD.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH APPROVED RESPIRATOR, CHEMICAL
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SPILL S ITE AFTER MATERIAL PICKUP IS
COMPLETE.
======================Handling and Storage ======================
Handling and Storage Precautions:LABEL PRECAUTIONARY STATEMENTS:
IRRITANT. IRRITATING TO EYES, RESPIRATORY SYSTEM AND SKIN.
Other Precautions:CAUTION: SUBSTANCE NOT YET FULLY TESTED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . WEAR OTHER SUITABLE PROTECTIVE CLOTHING.
Supplemental Safety and Health
MFR'S INFORMATION ON INGREDIENTS: MF: C7H11NO3.
================== Physical/Chemical Properties ==================
Solubility in Water:SOLUBLE
Appearance and Odor:SOLID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE, AND NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information===================
Toxicological Information:THE TOXICOLOGICAL PROPERTIES HAVE NOT BEEN
THOROUGHLY INVESTIGATED.
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
Federal Regulatory Information:EUROPEAN INFORMATION: CAUTION: SUBSTANCE
NOT YET FULLY TESTED. IRRITANT. R 36/37/38 - IRRITATING TO EYES,
RESPIRATORY SYSTEM AND SKIN. S 26 - IN CASE OF CONTACT WITH EYES,
RINSE IMMEDIATELY WITH PLENT Y OF WATER AND SEEK MEDICAL ADVICE. S
36 - WEAR SUITABLE PROTECTIVE CLOTHING.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CALCIUM HYPOCHLORITE
Preparer's Name:DGSC-SSH
CAGE:1JK82
CAGE:98092
CAGE:1JK82
============= Composition/Information on Ingredients =============
Ingred Name:CALCIUM HYPOCHLORITE
CAS:22464-76-2
RTECS #:NH3485500
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Health Hazards Acute and Chronic:INHALE:DUST IS EXTREMELY CORROSIVE TO
THE ENTIRE RESPIRATORY TRACT; & VERY CORROSIVE TO THE EYES & SKIN
ON CONTACT; IF INGESTED:CORROSIVE TO THE MOUTH & THROAT.
Effects of Overexposure:MAY PRODUCE SEVERE CHEMICAL BURNS. DO NOT ALLOW
CONTACT WITH EYES,SKIN,MUCOUS MEMBRANES OR CLOTHING.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS
======================= First Aid Measures =======================
First Aid:SEE A DOCTOR.INH:REMOVE TO FRESH AIR,GIVE CPR IF NEEDED;
EYE:FLUSH EYES WITH LOTS OF WATER,LIFTING UPPER & LOWER EYELIDS
OCCASIONALLY; SKIN:FLUSH WITH LOTS OF RUNNING WATER FOR 15
MINUTES,REMOVE CONTA MINATED CLOTHING & SHOES,WASH BEFORE REUS E;
ING: DO NOT INDUCE VOMITING,IF CONSCIOUS,GIVE LOTS OF WATER OR
MILK.DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS OR CONVULSING
PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER, PREFERABLY SPRAY
Fire Fighting Procedures:DRENCH WITH WATER & COOL THE SURROUNDING DRUMS
& AREA WITH WATER.
Unusual Fire/Explosion Hazard:NOT A COMBUSTIBLE MATERIAL. CONTAMINATION
OR MIXING WITH FOREIGN MATERIALS MAY RESULT IN FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NECESSARY PROTECTION (SEE RESPIRATOR
PROTECTION), SWEEP UP & PUT IN DOT-APPROVED WASTE CONTAINERS. DO
NOT RAISE DUST.
======================Handling and Storage ======================
Handling and Storage Precautions:MIX ONLY W/WATER.HTH IS A POWERFUL
OXIDANT. KEEP AWAY FROM COMBUSTIBLE ORGANIC MATERIAL.DO NOT
CONTAMINATE WITH ANY FOREIGN MATERIAL.STORE IN DRY AREA
Other Precautions:USE ONLY A CLEAN, DRY CONTAINER TO MEASURE OR CARRY
HTH DRY CHLORINE.DO NOT DROP,ROLL OR SKID CONTAINER.DO NOT TAKE
INTERNALLY. AVOID CONTACT W/EYES,SKIN,MUCOUS MEMBRANES OR
CLOTHING.AVOID FLAME.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN CONDITIONS GENERATING DUST,WEAR A NIOSH-
APPROVED FULL-FACEPIECE OR A HALF-MASK AIR-PURIFYING CARTRIDGE
RESPIRATOR WITH PARTICULATE FILTERS/ACID GASES.
Ventilation:LOCAL EXHAUST.
Other Protective Equipment:EYEWASH FOUNTAIN, EMERGENCY SHOWER
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MSDS WAS NOT AVAILABLE FROM MANUFACTURER. DGSC-SSH PROFESSIONALS
GENERATED THIS MSDS.
================== Physical/Chemical Properties ==================
HCC:D1
Melt/Freeze Pt:M.P/F.P Text:662F/350C
Spec Gravity:2.35
Solubility in Water:21%
Appearance and Odor:FREE-FLOWING,WHITE,GRANULAR,SLIGHT CHLORINOUS ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
HOUSEHOLD SOAP,PAINT PRODUCTS,SOLVENTS,ACIDS,VINEGAR
Stability Condition to Avoid:WHEN HEATED ABOVE 350F IT DECOMPOSES
RAPIDLY WITH OXYGEN AND HEAT.
Hazardous Decomposition Products:DECOMPES RAPIDLY W/CHEMICAL FUMING
DURING EVOLUTION OF O*2.
==================== Disposal Considerations ====================
Waste Disposal Methods:ADD HTH TO LARGE VOLUME OF WATER, THEN DISPOSE
OF SOLUTION TO WASTE. DISPOSAL IS DONE IN ACCORDANCE WITH LOCAL,
STATE, & FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:3744/3760/3770/3780 BLIDE ACRYLIC B-B WHITE/PASTEL
CAGE:GO254
CAGE:1FR68
CAGE:GO254
============= Composition/Information on Ingredients =============
Ingred Name:NON HAZARDOUS INGREDIENTS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION & SENSITIZATION
AFTER PROLONGED/REPEATED CONTACT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
Medical Cond Aggravated by Exposure:PRE-EXISTING DERMATITIS,
EYE/RESPIRATORY DISORDERS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER.
INGESTION: CONSULT POISON CONTROL CENTER. OBTAIN MEDICAL ATTENTION
IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:200F
Extinguishing Media:CO2, DRY CHEMICAL FOAM
Fire Fighting Procedures:WATER MAY BE USED TO COOL CONTAINERS TO
PREVENT PRESSURE BUILDUP & POSSIBLE AUTOIGNITION/EXPLOSION. WEAR
FULL PROTECTIVE EQUIPMENT INCLUDING NIOSH SCBA. (SUPP)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. ABSORB ONTO
INERT MATERIAL SUCH AS VERMICULITE, SAND, ETC. COLLECT IN
CONTAINERS FOR RE-USE, RECYCLING/WASTE DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:DON'T TAKE INTERNALLY. AVOID PROLONGED CONTACT
W/SKIN. KEEP OUT OF REACH OF CHILDREN. AVOID EYE CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:GENERAL (MECHANICAL) ROOM VENTILATION IS EXPECTED TO BE
SATISFACTORY
Other Protective Equipment:AS REQUIRED TO AVOID WETTING CLOTHES.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS W/SOAP & WATER BEFORE CONTACT W/SKIN/EYES.
Supplemental Safety and Health
SPECIAL FIRE CONT'D: WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED,
FOG NOZZLES ARE PREFERABLE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:999F
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN BU AC
Solubility in Water:COMPLETE
Appearance and Odor:OPAQUE LIQUID W/MILD ODOR
Percent Volatiles by Volume:65.2
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MATERIALS THAT REACT W/WATER.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, FREEZING, TEMP
>120F.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE SALVAGEABLE MATERIAL. FLUSH AREA W/WATER
IF POSSIBLE. DISPOSE OF RAGS & WASTED MATERIAL CAUTIOUSLY &
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:MIL-V-173C (V-112C-66) VARNISH MOISTURE AND
CAGE:00297
CAGE:00297
============= Composition/Information on Ingredients =============
Ingred Name:N-BUTYL ACETATE (SARA III)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: <25%
Other REC Limits:NONE SPECIFIED
OSHA PEL:150 PPM/200 STEL
ACGIH TLV:150 PPM/200STEL;9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VM&P NAPHTHA (LIGROINE)
CAS:8032-32-4
RTECS #:OI6180000
Fraction by Wt: <25%
Other REC Limits:NONE SPECIFIED
OSHA PEL:300 PPM/400 STEL
ACGIH TLV:300 PPM; 9192
Ingred Name:1-METHYLPYRROLIDONE
CAS:872-50-4
RTECS #:UY5790000
Fraction by Wt: <2%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYES/SKIN:IRRITATION.
INHALATION:IRRITATION TO THE RESPIRATORY TRACT, DIZZINESS,
HEADACHE, UNCONSCIOUSNESS. INGESTION: INTESTINAL DISORDERS, NAUSEA,
VOMITING, ASPIRATION INTO LUNGS MAY CAUSE CHE MICAL PNEUMONITIS
WHICH CAN BE FATAL. CHRONIC-DERMATITS, LIVER AND KIDNEY DAMAGE.
Effects of Overexposure:NAUSEA,VOMITING,RINGING IN EARS,DIZZ,
HEADACHE,CONFUSION,RAPID PULSE & BREATHING,SWEATING.
Medical Cond Aggravated by Exposure:SKIN, EYES, RESPIRATORY SYSTEM,
KIDNEY, LIVER AND CNS.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/OXYGEN IF NEEDED.
EYE CONTACT:FLUSH WITH WATER FOR 15 MINUTES. SKIN CONTACT:WASH WITH
SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS PERSIST. INGESTION:DO
NO T INDUCE VOMITING, GET MEDICAL HELP IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:78.0F,25.6C
Extinguishing Media:DRY CHEMICAL,CARBON DIOXIDE,FOAM. WATER MAY BE
INEFFECTIVE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR PROTECTIVE CLOTHING
AND SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:VAPORS FORM EXPLOSIVE MIXTURE IN AIR.
VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL TO IGNITION SOURCE AND
FLASHBACK.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: WIPE UP WITH RAGS OR TOWELS.
LARGE SPILLS: EVACUATE AREA. WEAR NIOSH APPROVED RESPIRATOR.
VENTILATE AREA. DIKE TO RETAIN FLUID. PUMP UP FREE LIQUID. RESIDUE
WILL EVAPORATE QUICKLY. DO NOT FLUSH TO SEWER OR WATERWAY.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 120F. KEEP
CONTAINER CLOSED TIGHTLY WHEN NOT IN USE. GROUND AND BOND DRUMS.
Other Precautions:EMPTY CONTAINERS RETAIN RESIDUE. DO NOT WELD, SAND,
PRESSURIZE EMPTY CONTAINERS, FIRE AND EXPLOSION HAZARD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR SUITABLE FOR
ORGANIC VAPORS.
Ventilation:LOCAL EXHAUST OR OPEN AIR
Other Protective Equipment:LONG SLEEVE WORK CLOTHES.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE WHILE WORKING WITH
THIS PRODUCT.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F3
Vapor Density:>1
Spec Gravity:8 LBS/GAL
pH:UNK
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:SLIGHT
Appearance and Odor:AMBER LIQUID WITH CHARACTERISTIC LACQUER-LIKE ODOR.
Percent Volatiles by Volume:48
Corrosion Rate:UNK
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:HIGH TEMP AND OPEN FLAMES.
Hazardous Decomposition Products:OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCARD IN METAL CONTNR I/A/W LOCAL,STATE &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:BUNKERSOL-D SLUDGE SOLVENT/DISPERSANT
CAGE:52454
CAGE:52454
============= Composition/Information on Ingredients =============
Ingred Name:DICHLOROTOLUENE
CAS:29797-40-8
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TOLUENE, AR-CHLORO; (MONOCHLOROTOLUENE)
CAS:25168-05-2
OSHA PEL:50 PPM (MFR)
ACGIH TLV:50 PPM (MFR)
Ingred Name:MATLS TO AVOID: THERMAL DECOMPOSITION RELEASING HYDROGEN
CHLORIDE AND SMALL AMOUNTS OF PHOSGENE AND CHLORINE.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: OXYGEN. IF BRTHG HAS STOPPED GIVE ARTF
RESP. KEEP PERS WARM, QUIET & GET MEDICAL ATTENTION.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: STREAMS/OTHER BODIES OF WATER. PVNT FROM
SPREADING. IF RUNOFF OCCURS, NOTIFY AUTH AS REQUIRED. PUMP/ (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: VACUUM TRANSFER SPILLED PROD TO CLEAN CONTRS FOR
RECOVERY. ABSORB UNRECOVERABLE PROD. TRANSFER CONTAM (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: ABSORB, SOIL & OTHER MATLS TO CONTRS FOR DISP. PVNT
RUN-OFF TO SEWERS, STREAMS/OTHER BODIES OF WATER. (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: IF RUN-OFF OCCURS, NOTIFY PROPER AUTHORITIES AS
REQUIRED, THAT A SPILL HAS OCCURRED.
RTECS #:9999999ZZ
Ingred Name:RESP PROT: (SEE YOUR SFTY EQUIP SUPPLIER).
ENGINEERING/ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE
EXPOSURE.
RTECS #:9999999ZZ
Ingred Name:COCO AMIDE; (AMIDES, COCO, N,N-BIS(HYDROXYETHYL))
CAS:8051-30-7
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PETROLEUM MINERAL OIL; (AROMATIC PETROLEUM DISTILLATES)
CAS:64742-06-9
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CAN CAUSE SEV IRRIT,
REDNESS, TEARING, BLURRED VISION. INGEST: CAN CAUSE GI IRRIT, NAUS,
VOMIT, & DIARR. ASPIR OF MATL INTO LUNGS CAN CAUSE CHEM PNEUMIT
WHICH CAN BE FATAL. INHAL: EXCESS INHAL OF VAPS CAN CAUSE NASAL &
RESP IRRIT, CNS EFTS INCL DIZZ, WEAK, FATG, NAUS, HDCH & POSS
UNCON, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: & EVEN DEATH. SKIN: PRLNG/RPTD CONT
CAUSES SEV IRRIT, DEFAT, DERM. CHRONIC: THIS PROD CONTAINS AN
AROMATIC PETROLEUM DISTILLATE WHICH MAY CONTAIN SUBSTANCES THAT
HAVE BEEN FOUND TO CAUSE SKI N CANCER IN LABORATORY ANIMAL TESTS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: THORO WASH EXPOSED AREA W/SOAP & WATER. REMOVE CONTAM
CLTHG & LAUNDER BEFORE REUSE. EYE: FLUSH W/LGE AMTS OF WATER,
LIFTING UPPER & LOWER LIDS OCCAS, FOR AT LEAST 15 MIN. GET MED
ATTN. INGEST: D O NOT INDUCE VOMIT. KEEP PERS WARM, QUIET & GET MED
ATTN. ASPIR OF MATL INTO LUNGS DUE TO VOMIT CAN CAUSE CHEM PNEUMIT
WHICH CAN BE FATAL. INHAL: REMOVE TO FRESH AIR. IF BRTHG DFCLT,
ADMIN (ING 6)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:150F,66C
Lower Limits:0.8%
Upper Limits:6.0%
Extinguishing Media:USE REGULAR FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT & POSS
ENDANGER LIFE OF FIREFIGHTER, (SUP DAT)
Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR
DRUM (EVEN EMPTY) BECAUSE PROD (EVEN JUST RESIDUE) CAN IGNITE
EXPLO. VAPS HVR/AIR & MAY TRAVEL ALONG GROUND/BE (SUP DAT)
================== Accidental Release Measures ==================
Spill Release Procedures:SML SPILL: ELIM ALL IGNIT SOURCES (FLARES,
FLAMES INCL PILOT LIGHTS, ELEC SPARKS). PERS NOT WEARING PROT EQUIP
SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP HAS BEEN
COMPLETED. STOP SPILL AT SO URCE. PVNT FROM ENTERING DRAINS,
SEWERS, (ING 7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED.
Other Precautions:SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES
(VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS
MSDS MUST BE OBSERVED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOS LIM OF PROD/ANY COMPONENT IS
EXCEEDED, A NIOSH/MSHA APPRVD AIR SUPP RESP IS ADVISED IN ABSENCE
OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA
APPRVD (NEG PRESS TYPE) UNDER SPECIFIED CNDTNS (ING 11)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION OT MAINTAIN EXPOSURE BELOW TLV.
Other Protective Equipment:WEAR IMPERVIOUS CLOTHING AND BOOTS.
EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: ESPECIALLY IF SPRAYED INTO CONTRS OF HOT, BURNING LIQ.
WATER MAY BE USED TO KEEP FIRE-EXPOSED CONTRS COOL UNTIL FIRE IS
OUT. EXPLO HAZ: MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS,
OTHER FLAMES & IGNIT SOURCES AT LOCATIONS DISTANT FROM MATERIAL
HANDLING POINT. EYE PROT: & FULL LENGTH FSHLD .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:318F,159C
Vapor Pres:<2.00
Spec Gravity:1.050
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
Percent Volatiles by Volume:55-70
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONT W/STRONG OXIDIZING AGENTS, OPEN FLAME, WELDING ARCS,
RESISTANCE HEATERS, ETC, WHICH CAN RSLT IN (ING 5)
Stability Condition to Avoid:AVOID HEAT, OPEN FLAME, AND PROLONGED
STORAGE AT ELEVATED TEMPERATURES.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CARBON
DIOXIDE AND CARBON MONOXIDE, HYDROGEN CHLORIDE, VARIOUS
HYDROCARBONS, ETC.
==================== Disposal Considerations ====================
Waste Disposal Methods:SML SPILL: ALLOW VOLAT PORTION TO EVAP IN HOOD.
ALLOW SUFFICIENT TIME TO COMPLETELY CLEAR HOOD DUCT WORK. DISP OF
REMAINING MATL I/A/W APPLIC REGS. LGE SPILL: DISP OF I/A/W ALL
LOCAL, STATE, AND FEDER AL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DIRT FIGHTER INTERIOR LATEX SEMI-GLOSS,(SUP
CAGE:85231
CAGE:59019
CAGE:85231
============= Composition/Information on Ingredients =============
Ingred Name:OTHER PREC: BRTHG VAP/SPRAY MIST. AVOID CNTCT W/SKIN &
EYES. KEEP OUT OF REACH OF CHILDREN. LMTS FOR NIUSANCE (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: DUSTS ARE ACGIH TLV 10 MG/M3 (TDUST), OSHA PEL 15
MG/M3 (TDUST), 5 MG/M3 (RESP).
RTECS #:9999999ZZ
Ingred Name:2-(2-BUTOXYETHOXY)-ETHANOL;(DIETHYLENE GLYCOL MONOBUTYL
ETHER). VP: 0.1
CAS:112-34-5
RTECS #:KJ9100000
Fraction by Wt: 0-5%
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
Ingred Name:ETHYLENE GLYCOL. VP: 0.1
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 0-5%
OSHA PEL:50 PPM, C
ACGIH TLV:50 PPM,VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 5-20%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:SUPP DATA: AT 250 MG/M3 DEVELOPED LUNG CANCER, HOWEVER,
SUCH EXPOSURE LEVELS ARE NOT ATTAINABLE IN WORKPLACE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & UPPER
RESP SYS. IN CONFINED AREA VAPS IN HIGH CONC MAY CAUSE HEADACHE,
NAUSEA/DIZZ. CHRONIC: ETHYLENE GLYCOL IS CONSIDERED AN ANIMAL
TERATOGEN. IT HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS/MICE
AT HIGH DOSES WHEN GIVEN IN DRINKING WATER/BY GAVAGE. THERE IS NO
EVIDENCE (SUPP DATA)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:REDNESS AND ITCHING OR BURNING SENSATION MAY
INDICATE EYE OR EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE.
EYES: F LUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. INGEST: CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>199F,>93C
Extinguishing Media:CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP(F PN). WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG
NOZZ ARE PREF. WATER MAY BE USED TO COOL CLSD(SUPP DATA)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. TRANS
ONLY TO APPRVD CNTNR W/COMPLETE & APPROP LABELING. DO NOT TAKE
INTERNALLY. USE ONLY W/ADEQ VENT. AVOID (ING 6)
Other Precautions:COATING MAY CONTAIN MATLS CLASSIFIED AS NUISANCE
PARTICULATES, SUCH AS TITANIUM DIOXIDE OR CALCIUM CARBONATE WHICH
MAY BE PRESENT AT HAZ LEVELS ONLY DURING SANDING & ABRADING OF
DRIED FILM. IF NO SPEC DUST ARE LISTED, THE APPLIC (ING 5)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERS EXPOS CAN'T BE CONTROLLED < APPLIC LMTS
BY VENT, WEAR NIOSH/MSHA APPRVD ORG VAP/PARTICULATE RESP. WHEN
SANDING/ABRADING DRIED FILM, WEAR NOISH/MSHA APPRVD DUST/MIST RESP
FOR DUST GENERATED FRO M PROD, UNDERLYING PAINT/ABRASIVE.
Ventilation:LOCAL EXHAUST PREF. GENL EXHST ACCEPTABLE IF EXPOS TO MATLS
IS MAINT < APPLIC LMTS. REFER TO OSHA STDS 1910.94,107,108.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
TRADE NAME/PART #: 573-82 MINT FROST. FIRE FIGHT PROC: CNTNRS TO PVNT
PRESS BUILDUP & POSS AUTOIGNIT/EXPLOS WHEN EXPOS TO EXTREME HEAT.
HEALTH HAZ: TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. PRLNG D
OVEREXP TO SOLV ING MAY CAUSE ADVERSEEFTS TO LIVER/URINARY SYS.
RATS EXPOS TO TITANIUM DIOXIDE DUST (ING 4)
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
pH:SUPDAT
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:66-75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PRODUCT IS NOT HAZARDOUS AS
DEFINED UNDER THE RCRA 40 CFR 261. INCINERATE IN APPROVED FACILITY.
DO NOT INCINERATE CLOSED CONTAINER. DISPOSE OF I/A/W FEDERAL, STATE
AND LOCAL REGULATION S REGARDING POLLUTION.
| 1 | gloves_mandatory |
=======================================================
Product ID: CLOVER SILICON CARBIDE GREASE MIX-ALL GRADES,51807
Cage: 05972
=======================================================
Contractor Summary
=======================================================
Cage: 05972
=======================================================
Ingredients
=======================================================
Cas: 64742-53-6
RTECS #: PY8036000
HYDROCARBON)
% low Wt: 30.
% high Wt: 60.
OSHA PEL: 5 MG/M3
ACGIH TLV: 5 MG/M3
------------------------------
Cas: 409-21-2
RTECS #: VW0450000
> Wt: 3.
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 64755-01-7
> Wt: 3.
------------------------------
Cas: 64742-52-5
RTECS #: PY8035000
> Wt: 3.
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYE CONTACT: MECHANICAL IRRITANT. CONTACT MAY CAUSE
TEARING AND REDNESS. SKIN CONTACT AND INHALATION: NO HAZARD IN NORMAL
INDUSTRIAL USE. INGESTION; MAY CAUSE NAUSEA AND VOMITING. CHRONIC: PREE
XISTING PULMONARY AND DERMATOLOGICAL DISORDERS MAY BE AGGRAVATED BY EXPOSUE
TO HAZARDOUS COMPONENTS.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: RECLAIM CLEAN MATERIAL. CONTAMINATED MATERIAL SHOULD
BE SWEPT OR SHOVELED INTO APPROPRIATE WASTE CONTAINER AND DISPOSED OF IN
ACCORDANCE WITH APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
Waste Disposal Methods: REVIEW ALL CURRENT FEDERAL, STATE, AND LOCAL
REGULATIONS REGARDING HEALTH AND DISPOSAL FOR APPROPRIATE DISPOSAL
PROCEDURES. INCINERATION PREFERRED.
Handling And Storage Precautions: HANDLING: WASH HANDS BEFORE EATING. AVOID
PROLONGED OR REPEATED CONTACT WITH SKIN. DO NOT TAKE INTERNALLY. FOR
INDUSTRIAL USE ONLY. STORAGE: STORE AWAY FROM HEAT. KEEP OUT OF THE REACH OF
CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: COC
Flash Point: =204.4C, 400.F
Lower Limits: N.A.
Upper Limits: N.A
Extinguishing Media: ALCOHOL FOAM, CO*2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). USE WATER TO COOL EXPOSED CONTAINERS. WATER STREAM DIRECTED
INTO FIRE MAY CAUSE FROTHING WITH SUBSEQUENT SPREAD OF FLAME.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY RUPTURE OR EXPLODE (DUE TO
PRESSURE BUILD-UP) WHEN EXPOSED TO EXTREME HEAT. IRRITATING AND/OR TOXIC
GASES OF FUMES MAY BE GENERATED BY THERMAL DECOMPOSITION OR COMBUSTION.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE NORMALLY REQUIRED UNDER GENERAL VENTILATION. IF
EXPOSURE LEVELS ARE UNKNOWN, IF LEVELS EXCEED TLV/PEL, OR IF EFFECTS OCCUR,
USE NIOSH-APPROVED DUST/MIST RESPIRATOR IN ACCORDANCE WITH APPLICABLE H EALTH
AND SAFETY REGULATIONS AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation: GENERAL VENTILATION USUALLY ADEQUATE.
Other Protective Equipment: EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N).
Work Hygienic Practices: FOLLOW GOOD GENERAL INDUSTRIAL SAFETY PRACTICES DURING
USE. DO NOT REUSE EMPTY CONTAINERS WITHOUT COMMERICAL CLEAN OR RECONDITION.
FOLLOW ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >140.6C, 285.F
B.P. Text: 285-900-F
Vapor Density: HVR/AIR
Spec Gravity: 1.3548
Viscosity: HIGH
Evaporation Rate & Reference: IS SLOWER THAN BU AC
Solubility in Water: NEGLIGIBLE
Appearance and Odor: GRAY LIQUID; MILD OIL ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: PROLONGED EXPOSURE TO HEAT.
Hazardous Decomposition Products: OXIDES OF CARBON. VARIOUS HYDROCARBONS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: NO PRODUCT OR COMPONENT TOXICOLOGICAL INFORMATION IS
AVAILABLE.
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: SARA SECTION 313: THIS PRODUCT CONTAINS THE
FOLLOWING SUBSTANCE SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 40
CFR PART 372: CHEMICAL NAME, CAS NUMBER WT/WT % IS LESS THAN: NO SARA SECTION
31 3 COMPONENTS EXIST IN THIS PRODUCT.
State Regulatory Information: U S STATE REGULATIONS: AS FOLLOWS: NJ
RIGHT-TO-KNOW: FOLLOWING MATLS ARE NON-HAZARDOUS, BUT ARE AMONG TOP FIVE
COMPONENTS IN THIS PROD: CHEM NAME & CAS NUMBERS: HYDROTREATED PETROLEUM
DISTILLATES 6474 2-52-5, SILICON CARBIDE 409-21-2, FATTY ACIDS, TALLOW,
CALCIUM SALTS 64755-01-7; HYDROTREATED PETROLEUM HYDROCARBON 64742-52-5. PA
RIGHT-TO-KNOW: FOLLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN PRO D AT
GREATER THAN 3%: CHEM NAME & CAS NUMBERS: HYDROTREATED PETROLEUM
DISTILLATES 64742-52-5, SILIC ON CARBIDE 409-21-2, FATTY ACIDS, TALLOW,
CALCIUM SALTS 64755-01-7; HYDROTREATED PETROLEUM HYDROCARBON 64742-52-5.
(OTHER INFO)
=======================================================
Other Information
=======================================================
Other Information: RATINGS - HEALTH: 0; FLAMMABILITY: 1; REACTIVITY: 0.
PREVIOUS MSDS REVISION DATE: 05/17/96. REASON FOR REVISION: COMPLETE UPDATE.
VOLATILE ORGANIC COMPOUNDS (VOCS): 0 GRAMS/LTR. --STATE REGULATOR Y INFO:
CALIFORNIA PROPOSITION 65: NO PROPOSITION 65 CHEMICALS KNOWN TO EXIST IN THIS
PRODUCT.
=======================================================
HAZCOM Label
=======================================================
Product ID: CLOVER SILICON CARBIDE GREASE MIX-ALL GRADES,51807
Cage: 05972
Company Name: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
Zipcode: 06067-3910
Label Required IND: Y
Date Of Label Review: 06/22/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYE CONTACT: MECHANICAL IRRITANT. CONTACT MAY
CAUSE TEARING AND REDNESS. SKIN CONTACT AND INHALATION: NO HAZARD IN NORMAL
INDUSTRIAL USE. INGESTION; MAY CAUSE NAUSEA AND VOMITING. CHRONIC: PREE
XISTING PULMONARY AND DERMATOLOGICAL DISORDERS MAY BE AGGRAVATED BY EXPOSUE
TO HAZARDOUS COMPONENTS.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:DATAKOAT CAT. #04176
CAGE:EO486
CAGE:19471
CAGE:EO486
============= Composition/Information on Ingredients =============
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 61%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 5%
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:INHALATION: ANESTHETIC. IRRITATION OF
RESP.TRACT OR ACUTE NERVOUS SYSTEM DEPRESSION.
======================= First Aid Measures =======================
First Aid:VAPORS: REMOVE FROM EXPOSURE, RESTORE BREATHING. NOTIFY
PHYSICIAN. EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR
15 MINUTES. TAKE TO PHYSICIAN FOR MEDICAL TREATMENT. SKIN: WASH
AFFECTED AREA S WITH WATER. REMOVE CONTAMINATED CLOTHING.
===================== Fire Fighting Measures =====================
Flash Point:55F, T.O.C.
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICALS; FOAM FOR LARGER
FIRES.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT, SELF CONTAINED
BREATHING APPAR.
Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMPOSITION PRODUCTS
MAY CAUSE A HEALTH HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS. VENTILATE AREA. CONTAIN AND MOVE WITH INERT
ABSORBENT AND NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE LARGE QUANTITIES ONLY IN
BUILDINGS DESIGNED TO COMPLY WITH OSHA 1910.106. KEEP CLOSURES GHT
AND CONTAINER UPRIGHT TO PREVENT LEAKAGE.
Other Precautions:DO NOT STORE OR USE NEAR HEAT, SPARKS OR FLAME. STORE
ONLY IN WELL VENTILATED AREAS. DRUMS SHOULD BE GROUNDED DURING
POURINGNEVER USE PRESSURE TO EMPTY. FOR INDUSTRIAL USE ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:MECHANICAL FILTER OR CHEMICAL MECHANICAL FILTER
TO REMOVE OVERSPRAY
Ventilation:IN ACCORDANCE TO OSHA REG. 29CFR.
Other Protective Equipment:EYE BATH AND SAFETY SHOWER.
Supplemental Safety and Health
65 SEVENTY-FIRST STREET, GUTTENBERG, NJ 07093.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:230-285
Vapor Density:>1
Evaporation Rate & Reference:< ETHER
Percent Volatiles by Volume:70.9
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE RECOGNIZED
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, AND FIRE.
Hazardous Decomposition Products:CARBON MONOXIDE AND/OR CARBON
DIOXIDE-THERMAL DECOMPOSITION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS. INCINERATE IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:FUEL, ENGINE PRIMER TYPE II
CAGE:12625
CAGE:12625
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL ETHER (SARA III)
CAS:60-29-7
RTECS #:KI5775000
Fraction by Wt: 60%
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400PPM/500STEL; 9192
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:N-HEPTANE
CAS:142-82-5
RTECS #:MI7700000
Fraction by Wt: 33%
OSHA PEL:500 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9293
Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 6%
OSHA PEL:5000 PPM
ACGIH TLV:5000PPM/30000STEL;93
Ingred Name:UPPER CYLINDER LUBRICANT
Fraction by Wt: 1%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:REPEATED AND PROLONGED EXPOSURE TO
SOLVENTS MAY CAUSE PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE.
Effects of Overexposure:INHALATION: MAY CAUSE HEADACHE, DIZZINESS,
NAUSEA, AND LOSS OF CONSCIOUSNESS.MAY CAUSE CENTRAL NERVOUS
SYSTEM DEPRESSION AND IRRITATE MUCOUS MEMBRANES OF THERESPIRATORY
TRACT. SKIN: MAY CAUSE DEF ATTING AND DRYING OF THE SKIN.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED
GIVE ARTIFICIALRESPIRATION. SKIN: WASH WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING. EYES: FLUSH WITH WATER FOR 15
MINUTES, IF IRRITATION PERSISTS, CALL PHYSICIAN.INGESTION: DO NOT
INDUCE VOMITING. CALL PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:-49F/>-44.44C
Lower Limits:1.85
Upper Limits:48
Extinguishing Media:FOAM, DRY CHEMICALS, CO2
Fire Fighting Procedures:HANDLE AS EXTREMELY FLAMMABLE LIQUID, COOL
CONTAINERS EXPOSED TO HEAT WITH WATERUSE AIR-SUPPLIED BREATHING
EQUIPMENT FOR ENCLOSED AREAS.
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESSURE.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE SOURCES OF HEAT OR IGNITION.
VENTILATE AREA. APPLY ABSORBENT MATERIAL TO SPILL AREA.
======================Handling and Storage ======================
Handling and Storage Precautions:EXTREMELY FLAMMABLE. STORE AND USE
AWAY FROM ALL HEAT AND IGNITION SOURCES. USE ADEQUATE VENTILA-
TION, HAZARDOUS WAST NUMBER U117,D001
Other Precautions:CONTENTS UNDER PRESSURE. DO NOT STORE ABOVE 120F.
DO NOT PUNCTURE ORINCINERATE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF
VENTILATION IS INADEQUATE.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) IF REQUIRED.
Other Protective Equipment:NONE
Work Hygienic Practices:AVOID BREATHING VAPOR AND EYE AND SKIN
EXPOSURE. KEEP OUT OF REACH OF CHILDREN.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
HCC:V3
Boiling Pt:B.P. Text:95F
Melt/Freeze Pt:M.P/F.P Text:-177F
Vapor Pres:537
Vapor Density:2.55
Spec Gravity:.713
Evaporation Rate & Reference:37.5
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR/ETHER SMELL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:AVOID OXIDIZERS. KEEP AWAY FROM HEAT,
SPARKS, OR OPEN FLAMEDO NOT STORE ABOVE 120F
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE MAY BE
FORMED DURING COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:ABSORBING MATERIAL OR DEFECTIVE CONTAINERS
SHOULD BE DISPOSED AT A RCRA APPROVED TS & D FACILITY ANDACCORDING
TO FEDERAL, STATE AND LOCAL LAWS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:HH-66 VINYL CEMENT
CAGE:NO467
CAGE:25592
CAGE:NO467
============= Composition/Information on Ingredients =============
Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (SARA 313) (CERCLA)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 52%
OSHA PEL:200 PPM
ACGIH TLV:200 PPM; 300 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ACETONE (SARA 313) (CERCLA) BP: 132F,56C
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 18%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM; 1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TOLUENE (SARA 313) (CERCLA)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 15%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TOLUENE APPEARS ON THE NAVY LIST OF
OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . EYES: LIQ MILDLY IRRIT. OV EREXP MAY ALSO CAUSE IRRIT.
REDNESS, TEARING & SWELLING. SKIN: DRYNESS OF SKIN INCLUDING
CRACKING. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: PRLNGD CNTCT CAN CAUSE DEFATTING &
POSS DERMATITIS. INHAL: OVEREXP MAY CAUSE IRRIT TO RESP SYS
INCLUDING DIZZINESS, HEADACHE, NAUSEA & LT HEAD. EXTREME OVEREXP TO
VAPS COULD RESULT IN CNS, L IVER & KIDNEY DAMAGE. INGEST: MAY
CAUSEGI IRRIT. ASPIRATION INTO LUNGS AS RESULT OF VOMITING MAY
CAUSE LUNG DAMAGE.
Medical Cond Aggravated by Exposure:SKIN:PRLNGD CNTCT WILL DEFAT SKIN &
CAUSE DERM. INHAL:EXTREME OVEREXP OF TOLUENE VAPS MAY CAUSE NERVS
SYS DMG. INGEST: NAUS, VOMIT & DIARR. ASPIR INTO LUNGS AS RSLT OF
VOMIT MAY CAUSE LUNG DMG.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH IMMEDIATELY WITH WATER FOR AT LEAST 15 MINUTES.
CALL MD. SKIN: WASH AREA WITH SOAP AND WATER. INHAL: MOVE AFFECTED
PERSON TO FRESH AIR AT ONCE. RESTORE BREATHING. CALL MD IF
DIFFICULTIES P ERSIST. INGEST: DO NOT INDUCE VOMITING.CALL MD. GIVE
WATER TO VICTIM. IF VOMITING OCCURS, PREVENT ASPIRATION INTO LUNGS.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:6F,-14C
Lower Limits:1%
Upper Limits:12%
Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. OVERHEATED, CLOSED
CONTAINER NEAR TO FIRE COULD EXPLODE DUE TO PRESSURE BUILDUP.
================== Accidental Release Measures ==================
Spill Release Procedures:EXTINGUISH ALL SOURCES OF IGNITION IN AREA.
COLLECT SPILLED MATERIAL AND PLACE IN A CLOSED CONTAINER FOR
DISPOSAL OR SALVAGE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, OPEN FLAMES &
SPARKS. USE & STORE WITH ADEQUATE VENTILATION TO PREVENT VAPOR
BUILDUP. VAPORS RELEASED BY PROD CAN EASILY IGNITE.
Other Precautions:AVOID CONTACT WITH SKIN AND EYES. AVOID PROLONGED
BREATHING OF VAPORS. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP
OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE EXCEEDS OCCUPATIONAL EXPOSURE
LIMITS, USE A NIOSH APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE.
PER 29 CFR 1910.134. NIOSH APPROVED CCROV OR SA TYPES RECOMMENDED.
Ventilation:LOC EXHST & MECH (GEN) SHOULD BE USED TO MAINTAIN EXPOS
BELOW TLV(S). EXPLO PROOF VENT MAY BE REQD TO CTL VAP CONCS.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WORK APRON TO AVOID CONTACT WITH PERSONAL CLOTHING AND SKIN.
Work Hygienic Practices:KEEP AREA CLEAN. WASH HANDS THOROUGHLY AFTER
WORKING WITH PRODUCT.
Supplemental Safety and Health
SPEC GRAV: 0.78-0.88 (H*2O=1).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:132F,56C
Vapor Pres:180 @ 68F
Vapor Density:HVR/AIR
Spec Gravity:SUPDAT
Evaporation Rate & Reference:SLOWER (BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR; FRAGRANT MINT-LIKE ODOR, SHARP.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE
WHEN SUBJECTED TO FLAMES OR EXCESSIVE HEAT.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS. EPA HAZARDOUS WASTE NUMBER: D035 (IGNITABLE).
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:SPARVAR INTERIOR/EXTERIOR SPRAY PAINT (SUPP
CAGE:HO445
CAGE:86142
CAGE:HO445
============= Composition/Information on Ingredients =============
Ingred Name:ACETONE (SARA III)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 18-23%
OSHA PEL:1000PPM
ACGIH TLV:750PPM/1000STEL;9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 18-20%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9192
Ingred Name:HEXANE
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: 14-22%
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:1-METHOXY 2-PROPANOL ACETATE; (2-PROPANOL, 1-METHOXY-,
ACETATE)
CAS:108-65-6
RTECS #:AI8925000
Fraction by Wt: 8.0%
ACGIH TLV:NOT ESTAB (MFR)
Ingred Name:VM&P NAPHTHA
CAS:8032-32-4
RTECS #:OI6180000
Fraction by Wt: 15-25%
OSHA PEL:300 PPM/400 STEL
ACGIH TLV:300 PPM; 9192
Ingred Name:SUPDAT:W/EXPERTS TO DETERMINE IF PROGRAMS ARE ADEQUATE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:NOT EXPECTED TO BE
HARMFUL UNDER NORMAL CNDTNS OF USE. INHAL:MAY BE HARMFUL IF
INHALED. LIQ/VAP CAN CAUSE IRRIT OF NOSE, THROAT & LUNGS.
SKIN/EYE:CAUSES IRRIT. INGS 1 & 5:CAN CAUSE CNS DE PRESS. SIGNS &
SYMPS MAY INCL HDCH, DIZZ, NAUS, VOMIT, UNCON & EVEN ASPHY. ING
2:MATL IS SIMPLE ASPHY. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SIGNS & SYMPS OF OVEREXP INCL
CYANOSIS, RESP DISTRESS, HDCH, DIZZ, DROW, UNCON & ASPHY. CAN CAUSE
CNS DEPRESS. ING 3:CHRONIC EXPOS HAVE CAUSED PERIPHERAL NEUROPATHY.
CAN CAUSE CNS DEPRESS, SI GNS & SYMPS MAY INCL HDCH, DIZZ, NAUS,
VOMIT & DROW.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:IMMED FLUSH W/WATER FOR @ LST 15 MINS. IF IRRIT
PERSISTS, CALL MD. INGEST:DILUTE BY DRINKING LG QTYS OF WATER.
IMMED CONT POIS CTL CTR/HOSP EMER RM FOR ANY OTHER ADDNL TREATMENT
DIRECTIONS. INHAL :REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF
RESP, PREF MOUTH-TO-MOUTH. IF BRTHG IS DFCLT, GIVE OXYGEN, CALL MD.
EYES:IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS. EYELIDS
SHOULD BE HELD (SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point:EXTREMELY FLAMM
Extinguishing Media:DRY CHEMICAL,FOAM/CO*2;H*2O MAY BE INEFFECTIVE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . USE WATER TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESS; EXPOS TO HIGH TEMPS
MAY CAUSE POSS BURSTING. AVOID HEAT SOURCES. DON'T PUNCTURE/BURN
CNTNR. DON'T SPRAY NEAR OPEN FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH
ABSORBENT MATERIAL & REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT
ENTRY INTO NATURAL BODIES OF H*2O.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE AT TEMP OVER 120F. AVOID
EYE, SKIN/CLTHG CONT. AVOID BRTHG VAP/MIST. USE W/ADEQ VENT.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE AIR CONTAMINANTS EXCEED ACCEPTABLE
CRITERIA, USE NIOSH/MSHA APPROVED RESPIRATORY PROTECTION EQUIPMENT.
REFER TO OSHA 29 CFR 1910.134 AS GUIDELINE.
Ventilation:SUFFICIENT VENT IN VOL & PATTERN TO KEEP CONTAMINANT LEVELS
BELOW ACCEPT CRITERIA:LOC EXHST VENT, ENCLSD SYS (SUPDAT)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. HANDLE W/GOOD
INDUSTRIAL HYGIENE & SAFETY PRACTICES.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:CHEVROLET ORANGE ENGINE COLOR, S-171. VP:60
PSIG @ 70F. % VOLAT BY VOL:78-89 (WT). FIRST AID PROC:APART DURING
IRRIGATION TO INSURE WATER CONT W/ENTIRE SURF OF EYES & LIDS. CA LL
MD. VENT:DESIGN, PROCESS ISOLATION, REMOTE CONTROL IN COMBINATION
W/PROT EQUIP & PRUDENT WORK PRACTS. CONSULT (ING 6)
================== Physical/Chemical Properties ==================
HCC:V3
Vapor Pres:SUPP DATA
Vapor Density:HVR/AIR
Spec Gravity:LIGHTER/WATER
Evaporation Rate & Reference:FASTER THAN BUAC
Solubility in Water:SLIGHT
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL,STATE &
FEDERAL REGULATIONS. EMPTY CONTAINERS MAY CONTAIN EXPLOSIVE VAPORS.
DO NOT CUT,PUNCTURE OR WELD ON OR NEARBY. INCINERATION WILL CAUSE
CONTAINER TO BURST VIO LENTLY.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:CARBON DIOXIDE
CAGE:63140
CAGE:63140
============= Composition/Information on Ingredients =============
Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 1/0.5%
OSHA PEL:5000 PPM
ACGIH TLV:5000PPM/30000STEL;93
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:A SIMPLE ASPHYXIANT. HIGH CONCS OF
CARBON DIOXIDE IN AMBIENT AIR CAN REDUCE OXYGEN CONTENT NEC TO
SUPPORT LIFE. IN SOLID PHASE (DRY ICE), CONT W/BODY TISS WILL PRDCE
COLD BURNS/FROSTBT W/IN SEV SEC. A CCRD TO CGA PHAMPLET#G-6, THE
MAX EXPOSLIM OF A HLTHY MALE UNDER EXERCISING CNDTNS IN AIR HAVING
A 7% CONC OF (SUPDAT)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SHORTNESS OF BREATH, HEADACHE, DIZZINESS,
WEAKNESS, DROWSINESS AND RINGING IN EARS. DRY ICE IN CONTACT WITH
BODY TISSUE PRODUCES A "BURNING" SENSATION; AND FROSTBITE OCCURS
WITHIN SEVERAL SECONDS.
Medical Cond Aggravated by Exposure:ANY CONDITION THAT WOULD BE
AGGRAVATED BY A REDUCED QUANTITY OF NORMAL QUALITY BREATHING AIR.
======================= First Aid Measures =======================
First Aid:INHAL: DO NOT ATTEMPT TO REMOVE AN INDIVIDUAL FROM SCENE OF
AN OVEREXP W/O UTILIZING PROPER RESCUE EQUIP OR YOU MAY BECOME A
CASUALTY. REMOVE VICTIM FROM CARBON DIOXIDE, PROVIDE PLENTY OF
FRESH AIR WH ILE KEEPING SUCH PERSON WARM/DRY/QUIET.IF BRTHG HAS
STOPPED, PERFORM ARTF RESP. GET IMMED MED ATTN. INGEST: CALL MD
IMMED . EYES: IMMED FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MIN,
(SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:NOT APPLICABLE. CARBON DIOXIDE IS INERT &
NON-FLAMM. IN CASE OF FIRE, USE MEDIA SUITABLE FOR SURROUNDING FIRE
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CONFINEMENT OF CARBON DIOXIDE IN VESSELS
OR CONTAINERS OF IMPROPER DESIGN CAN RESULT IN EXPLOSION OR RUPTURE
FROM OVER-PRESSURIZATION.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA OF SPILL OR RELEASE, EMPLOY
EMERGENCY FIRST AID PROCEDURES, PROVIDE PLENTY OF FRESH AIR. REMOVE
DRY ICE RESIDUAL & ALLOW TO SUBLIME IN A SECURED, WELL-VENTILATED
AREA & CONTACT THE MFR'S SAFETY DEPARTMENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:LIQ/VAPS STORAGE CONTRS ARE UNDER HIGH
PRESS. DO NOT MIS-HANDLE OR ABUSE CONTRS. USE ONLY CONTRS/EQUIP
SPECIFICALLY DESIGNED FOR CARBON DIOXIDE.
Other Precautions:AVOID DIRECT SKIN CONTACT W/DRY ICE OR VENTING CO*2
LIQUID OR VAPOR. USE PROTECTIVE EQUIPMENT & CLOTHING AND GET PROPER
TRAINING BEFORE HANDLING CARBON DIOXIDE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS. USE IN STRICT ACCORDANCE WITH THE MANUFACTURER'S
RECOMMENDATIONS.
Ventilation:FRESH AIR. LOC EXHST:PASSIVE SYS-FLOOR LEVEL, OPENINGS TO
OUTDOOR ATMOSPHERE. MECH (GEN):ELEC FANS-REMOVE CO*2 (SUPDAT)
Other Protective Equipment:HARD HATS & EAR PROTECTION SHOULD BE WORN
WHEN WORKING W/PRESSURIZED CARBON DIOXIDE.
Work Hygienic Practices:PERSONS HANDLING CARBON DIOXIDE SHOULD BE FULLY
TRAINED IN ADVANCE.
Supplemental Safety and Health
HLTH HAZ: CO*2 BY VOL IS <3 MIN. FIRST AID PROC: SEEK ASSISTANCE FROM
MD . SKIN: FLUSH W/COPIOUS AMTS OF WATER. CALL MD . VENT: FROM
FLOOR/LOW AREAS - EXHAUST OUTDOORS. BE SURE HEAVY CO*2 VAPORS
CAN'T ACCUMULATE. VP:0.1234 LB/FT3. SOL IN H*2: @60F AND O PSIG 1
VOLUME OF CO*2 WILL DISSOLVE IN 1 VOL OF H*2O.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:-109F,-79C
Vapor Pres:838 PSIG
Vapor Density:SUPDAT
Spec Gravity:1.5240 (AIR=1)
Solubility in Water:VERY SOLUBLE(SUPDAT)
Appearance and Odor:IN SOLID PHASE-TRANSLUCENT WHITE/ODORLESS. IN
GAS/LIQ PHASE-COLORLESS/ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NO DATA AVAILABLE.
Hazardous Decomposition Products:HEATING ABOVE 1700C CAUSES
DECOMPOSITON TO CO AND O*2.
==================== Disposal Considerations ====================
Waste Disposal Methods:ALLOW CARBON DIOXIDE TO RELEASE, SUBLIME OR
DISSIPATE IN THE OPEN AIR. AVOID RELEASING IN COURTYARDS OR INDOORS
OR ANY AREAS WHERE HEAVY CARBON DIOXIDE VAPORS CAN ACCUMULATE.
DISPOSAL MUST BE I/A/W FE DERAL, STATE, AND LOCAL REGULATIONS
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:KT PAINT ORANGE
CAGE:BROCK
CAGE:BROCK
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA III)
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:400 PPM;500 STEL
ACGIH TLV:400 PPM;500 STEL
Ingred Name:CHROMIC ACID, LEAD (2+) SALT (1:1); (LEAD CHROMATE)
CAS:7758-97-6
RTECS #:GB2975000
OSHA PEL:.05 MG/M3 (CR)
ACGIH TLV:.05 MG/M3 (CR)
Ingred Name:MINERAL SPIRITS
OSHA PEL:500 PPM (MFR)
ACGIH TLV:500 PPM (MFR)
Ingred Name:ETHANOL, 2-BUTOXY; (ETHYLENE GLYCOL ETHER EB ACETATE)
(SARA III)
CAS:111-76-2
RTECS #:KJ8575000
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (SARA III)
CAS:123-86-4
RTECS #:AF7350000
OSHA PEL:150 PPM;200 STEL
ACGIH TLV:150 PPM;200 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOBUTYL ALCOHOL; (ISOBUTANOL)
CAS:78-83-1
RTECS #:NP9625000
Other REC Limits:100 PPM (MFR)
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:LIGROINE; (V M & P NAPHTHA)
CAS:8032-32-4
RTECS #:OI6180000
Other REC Limits:500 PPM (MFR)
OSHA PEL:300 PPM;400 STEL
ACGIH TLV:300 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE- RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUE, BLOOD,
KIDNEY & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER
ACETATE (EGBEA). (EXTRACTED FROM DH HS (NIOSH) PUBLICATION NO.
90-118) . ANETHETIC, IRRIT OF RESP TRACT/NERVOUS SYS. INGEST (EFTS
OF OVEREXPOS)
Explanation of Carcinogenicity:LEAD CHROMATE: GROUP 1 (NTP, IARC)
Effects of Overexposure:HLTH HAZ:OF LARGE AMOUNTS MAY CAUSE LEAD
POISONING. CONTACT WITH SKIN MAY CAUSE DERMATITIS/EYE CONTACT MAY
CAUSE IRRITATION. DEPRESSION, HEADACHE, DIZZINESS AND NAUSEA.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOSURE AND RESTORE BREATHING, SEEK MD
ATTENTION. EYES:SPLASH WITH WATER FOR AT LEAST 15 MINUTES. SEE MD
IF IRRITATION PERSISTS. SKIN:FLUSH WITH COPIOUS AMOUNTS OF WATER.
CALL MD (F P N). INGEST:CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point:19.0F,-7.2C
Lower Limits:0.9%
Extinguishing Media:FAOM, ALCOHOL FOAM, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT, BUT WATER SPRAY MAY BE USED TO COOL
CONTRS EXPOSED TO HEAT OR FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA
AND SOAK UP WITH INERT ABSORBENT USING NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:ALL AREAS SHOULD BE ADEQUATELY
VENTILATED. DO NOT STORE ABOVE 120F. DO NOT STORE NEAR HEAT, SPARKS
OR FLAME.
Other Precautions:DO NOT ALLOW TO COME IN CONTACT WITH EYES OR SKIN.
AVOID PROLONGED EXPOSURE TO VAPORS. DO NOT TAKE INTERNALLY. DO NOT
SMOKE WHILE USING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:USE PARTICULATE FILTER MECHANICAL (GENERAL) VENTILATION.
Other Protective Equipment:WASH CONTAMINATED CLOTHING
Work Hygienic Practices:AVOID PROLONGED OR REPEATED CONTACT. DO NOT
BREATH VAPORS.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:>130F,>54C
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NO
Appearance and Odor:STRONG LAQUER ODOR. COLOR AND CONSISTANCY VARIES.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:CO, CO2 AND OXIDES OF LEAD AND
CHROMIUM.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:AMERCOAT, 187
Preparer's Name:H KLINE
CAGE:0Y2E4
CAGE:55849
CAGE:0Y2E4
============= Composition/Information on Ingredients =============
Ingred Name:CYCLOHEXANONE (SARA III)
CAS:108-94-1
RTECS #:GW1050000
Fraction by Wt: 16.28%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: <15%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 11.58%
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:HYDROTREATED HEAVY NAPHTHA; (VM & P NAPTHA). VP:5.2.
LD50:ORAL(RAT)5 G/KG.
CAS:64742-48-9
Fraction by Wt: 11.43%
OSHA PEL:500 PPM (MFR)
ACGIH TLV:300 PPM (MFR)
Ingred Name:METHYL N-AMYL KETONE
CAS:110-43-0
RTECS #:MJ5075000
Fraction by Wt: 7.79%
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9192
Ingred Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: <10%
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 9293
Ingred Name:EPON 820; (EPOXY RESIN). LD50:ORAL(RAT)11.4 G/KG.
CAS:25068-38-6
RTECS #:KC2100000
Fraction by Wt: <10%
ACGIH TLV:2 PPM, S (MFR)
Ingred Name:N-BUTYL ACETATE (SARA III)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 4.91%
OSHA PEL:150 PPM/200 STEL
ACGIH TLV:150 PPM/200STEL;9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ACETIC ACID, VINYL ESTER, POLYMER W/CHLOROETHYLENE; (VINYL
CHLORIDE RESIN-VINYL ACETATE POLYMER)
CAS:9003-22-9
RTECS #:AK0950000
Fraction by Wt: <5%
OSHA PEL:1 PPM (MFR)
ACGIH TLV:5 PPM (MFR)
Ingred Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 4.15%
OSHA PEL:100 PPM/125 STEL
ACGIH TLV:100 PPM/125STEL 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL ISOBUTYL KETONE (SARA III)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 4.07%
OSHA PEL:100 PPM/75 STEL
ACGIH TLV:50 PPM/75 STEL; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 3.28%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:PHENOLIC RESIN
CAS:68648-57-7
Fraction by Wt: <5%
ACGIH TLV:5 MG/M3 (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VAP/SPRAY MIST &/OR DUST CAN BE
HARMFUL. IRRIT TO SKIN/MUC MEMB/EYES/RESP SYS. EXCESSIVE INHAL CAN
CAUSE HDCH/DIZZ/ ASPHY. RPTD/PRLNG OCCUP OVEREXP TO SOLVS IS ASSOC
W/PERM BRAIN & NERV SYS DMG. CAN B E HARMFUL/FATAL IF SWALLOWED.
CAN BE HARMFUL IF INHALED/ABSORBED THRU SKIN. OVEREXP CAN DMG CNS.
OVEREXP(EFTS OF OVEREXP
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OR INGESTION CAN CAUSE LUNG, KIDNEY
&/OR LIVER DMG. OVEREXP CAN CAUSE SKIN & EYE BURNS &/OR INJURY.
SKIN & RESPIRATORY SENSITIZATION & ALLERGIC REACTION CAN OCCUR.
Medical Cond Aggravated by Exposure:RESPIRATORY, ALLERGIES. KIDNEY &
LIVER DISORDERS. SKIN. HEART.
======================= First Aid Measures =======================
First Aid:INHAL:PROVIDE FRESH AIR. IF BRTHG LABORED, GIVE O2/ARTF RESP.
SKIN:WASH THORO W/SOAP & WATER. EYES:FLUSH IMMED W/ PLENTY OF WATER
FOR AT LEAST 15 MINUTES & GET MD. INGEST:DRINK 1 OR 2 GLASSES OF
WATER TO DILUTE. DO NOT INDUCE VOMIT. CONSULT MD OR POISON CONTROL
CENTER IMMED. TREAT SYMPTOMATICALLY.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:44.0F,6.7C
Lower Limits:0.9%
Upper Limits:12.8%
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. ISOLATE FROM HEAT/ELEC EQUIP/SPKS/OPEN FLAME. KEEP
UPWIND. VAPS MAY SPREAD LONG DISTS, CAUSE FLASH(SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID BRTHG VAPS/DUST. USE ABSORB CLEANUP
MATLS/SWEEP UP. PLACE IN SEPARATE CNTNR. KEEP OUT OF PUBLIC SEWERS
& WATERWAYS. IF ENTRY IS THREATENED/OCCURS, NOTIFY LOCAL
AUTHORITIES. ELIMINATE ALL SOURCESOF IGNITION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNR CLSD, UPRIGHT WHEN NOT IN
USE. STORE IN COOL/DRY/WELL-VENTED AREA. AVOID STOR TEMPS ABOVE
100F. DO NOT TAKE INTERNALLY.
Other Precautions:AVOID PRLNG BRTHG OF DUST/VAPS/SPRAY MIST/CONT W/SKIN
& EYES. DO NOT WELD/FLAME CUT EMPTY CNTNR. GROUND CNTNRS WHEN
POURING. DESTROY CONTAM LEATHER & ABSORB SHOES WHICH CANNOT BE
DECONTAM. SUBJ TO RPR TG REQS OF SARA & 40 CFR 302, 355, 372.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPRVD CERTIFIED RESP. FOR SPEC
CNDTNS REFER TO NIOSH POCKET GUIDE TO CHEM HAZS. USE NIOSH/MSHA
APPRVD AIR-LINE RESP IN CONFINED/RESTRICTED VENT AREAS, OR
W/POLYURETHANE OR ISOCYANATES. REF ER TO CFR, OSHA PARTS 1910,
1915(SUPDAT)
Ventilation:SUFFICIENT VENT, IN VOL & PATT, SHOULD BE PROVIDED TO KEEP
AIR CONTAM CONC BELOW TLV LIM. REMOVE WELDING/FLAME (SUPDAT)
Other Protective Equipment:FULL PROTECTIVE CLTHG. SPARK-PROOF
EQUIPMENT. EMERGENCY EYEWASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING OR USING
WASHROOM. LAUNDER CONTAM CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EVAP RATE:(BUTYL ACETATE=1). EXPLO HAZ:FIRE OR IGNITE EXPLOSIVELY. RESP
PROT:AND 1916 FOR COATING OPERATIONS. VENT: CUTTING DECOMP
PRODUCTS. REFER TO 29 CFR, OSHA PARTS 1910, 1915 & 1916 FOR COATING
O PERATIONS.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:175F,79C
Vapor Pres:SEE INGRED
Vapor Density:>AIR
Evaporation Rate & Reference:LOW:0.2 HIGH:4.6 (SUPDAT)
Appearance and Odor:LIQUID, SOLVENT ODOR.
Percent Volatiles by Volume:78
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, ALKALIES.
Stability Condition to Avoid:HEAT, OPEN FLAME, ARC OR SPARKS.
Hazardous Decomposition Products:CO & CO2. HYDROGEN CHLORIDE FUMES.
IRON OXIDE FUMES. ALDEHYDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:IN SEPARATE, CLOSED METAL CONTAINER I/A/W ALL
APPLICABLE LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
=======================================================
NIIN: 01-331-6119
Product ID: ECO SURE BLUE #15102 (0674-152)
Cage: 0FTT5
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: 0FTT5
=======================================================
Contractor Summary
=======================================================
Cage: 0FTT5
=======================================================
Item Description Information
=======================================================
Item Manager: GSA
Item Name: ENAMEL
Specification Number: A-A-2787
Type/Grade/Class: TYPE I
Unit of Issue: PT
UI Container Qty: 0
=======================================================
Ingredients
=======================================================
Cas: 1330-20-7
RTECS #: ZE2100000
% Wt: <20.72
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 100 PPM
ACGIH TLV: 100 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 74-98-6
RTECS #: TX2275000
% Wt: 14.48
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 1000 PPM
ACGIH TLV: 1000 PPM
------------------------------
Cas: 115-10-6
RTECS #: PM4780000
% Wt: 8.05
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 110-12-3
RTECS #: MP3850000
% Wt: 5.97
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 50 PPM
ACGIH TLV: 50 PPM
------------------------------
Cas: 64742-95-6
% Wt: 5.97
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: 50 PPM
------------------------------
Cas: 64742-95-6
% Wt: <2.99
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: 5 PPM
------------------------------
Cas: 107-87-9
RTECS #: SA7875000
% Wt: <2.99
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 200 PPM
ACGIH TLV: 200 PPM
------------------------------
Cas: 108-10-1
RTECS #: SA9275000
% Wt: <2.99
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 100 PPM
ACGIH TLV: 50 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 95-63-6
RTECS #: DC3325000
% Wt: <2.99
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: 25 PPM
------------------------------
Cas: 71-36-3
RTECS #: EO1400000
% Wt: <2.99
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 50 PPM
ACGIH TLV: 100 PPM
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: IRRIT. SKIN: IRRIT. INHAL: HARMFUL, FATAL, BRAIN/NS
DAMAGE, ANESTHETIC, IRRIT TO RESPIRATORY TRACT, LIGHTHEADED, STAGGERING GAIT,
GIDDY, NAUSEA, THROAT IRRIT, VOMITING, HEADACHE. INGEST: HARMFUL.
Explanation Of Carcinogenicity: NO
Medical Cond Aggravated By Exposure: RESPIRATORY AILMENTS
First Aid: EYE: FLUSH W/WATER FOR 15 MINUTES. SKIN: WASH W/SOAP & WATER.
WASH CLOTHES BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. ARTIF RESP IF NEEDED.
INGEST: DONT INDUCE VOMIT. IN ALL CASES, GET MED AID.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE IGNITS. VENT AREA. MOP SPILLS W/INERT
ABSORBENT. AVOID BREATHING VAPORS.
Waste Disposal Methods: IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
DONT PUNCTURE, INCINERATE OR STORE >120F. EXPOSURE TO HEAT OR PROLONGED
EXPOSURE TO SUN MAY CAUSE CAN TO BURST. DISCARD EMPTY CAN IN TRASH PICK-UP.
DONT PLACE IN HOME TRASH COMPACTOR.
Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. CAUTION:
CONTENTS UNDER PRESSURE: DONT STORE WHERE TEMPS EXCEED 120F.
Other Precautions: USE W/GOOD VENTILATION. READ ENTIRE LABEL BEFORE USING.
FOLLOW ALL LABEL DIRECTIONS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: -156F,-104C
Autoignition Temp Text: 662F
Lower Limits: 2.2
Upper Limits: 18.0
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, SAND, WATER SPRAY.
AVOID SPREADING ANY BURNING LIQUID W/WATER SPRAY.
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE. USE WATER TO COOL
CONTAINERS. USE SCBA. USE SHIELDING TO PROTECT PERSONNEL AGAINST BURSTING,
RUPTURING, VENTING OF CONTAINERS.
Unusual Fire/Explosion Hazard: DONT SPRAY NEAR OPEN FLAME. AT TEMPS >120F
CONTAINERS MAY VENT, RUPTURE, BURST. AEROSOL CONTAINERS: DO NOT EXPOSE TO
TEMPS >120F.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED MASK ABOVE TLV.
Ventilation: LOCAL EXHAUST PREFFERED. MECHANICAL (GENERAL) ACCEPTABLE AT POINT
OF MIST OR SPRAY RELEASE.
Other Protective Equipment: IMPRVIOUS CLOTHES TO PROTECT SKIN, EYEWASH STATION.
Work Hygienic Practices: DONT EAT, DRINK OR SMOKE WHILE USING THIS PRODUCT.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: NA
M.P/F.P Text: NA
Decomp Text: NA
Vapor Pres: 70 @ 68F
Vapor Density: >1.522
Spec Gravity: 0.890 (AEROSOL)
PH: NA
VOC Grams/Liter: 576
Viscosity: NA
Solubility in Water: INSOLUBLE
Appearance and Odor: BLUE PAINT
Corrosion Rate: NA
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT
Materials To Avoid: NA
Hazardous Decomposition Products: CARBON MONOXIDE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NA
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: VOC = 576 G/L
=======================================================
Transportation Information
=======================================================
Trans ID NO: 126078
Product ID: ECO SURE BLUE #15102 (0674-152)
Review Date: 04/29/1998
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: PT
Container QTY: 0
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: DTJ
Symbols: D
DOT Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
Label: NONE
Non Bulk Pack: 156,306
Bulk Pack: NONE
Max Qty Pass: 30KGGROSS
Max Qty Cargo: 30KGGROSS
Vessel Stow Req: A
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: AKH
IMO Proper Shipping Name: AEROSOLS/AEROSOL PRODUCT ?
IMDG Page Number: SEE 9022
UN Number: 1950
UN Hazard Class: 9?
IMO Packaging Group: -
Subsidiary Risk Label: -
EMS Number: 2-13
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ALS
IATA UN ID Num: 1950
IATA Proper Shipping Name: AEROSOLS, FLAMMABLE
IATA PSN Modifier: (EACH NOT EXCEEDING 1 L CAPACITY)
IATA UN Class: 2.1
IATA Label: FLAMMABLE GAS
Packing Note Passenger: 203
Max Quant Pass: 75KG
Max Quant Cargo: 150KG
Packaging Note Cargo: 203
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ALR
AFI Symbols: *
AFI Proper Shipping Name: AEROSOLS, FLAMMABLE, N.O.S.
AFI PSN Modifier: (EACH NOT EXCEEDING 1L CAPACITY)
AFI Hazard Class: 2.1
AFI UN ID NUM: UN1950
Special Provisions: P4
Back Pack Reference: A6.3
=======================================================
HAZCOM Label
=======================================================
Product ID: ECO SURE BLUE #15102 (0674-152)
Cage: 0FTT5
Company Name: LHB INDUSTRIES
Street: 8833 FLEISCHER PLACE
Zipcode: 63134
Label Required IND: Y
Date Of Label Review: 10/12/1999
Status Code: A
Origination Code: G
Hazard And Precautions: EYE: IRRIT. SKIN: IRRIT. INHAL: HARMFUL, FATAL,
BRAIN/NS DAMAGE, ANESTHETIC, IRRIT TO RESPIRATORY TRACT, LIGHTHEADED,
STAGGERING GAIT, GIDDY, NAUSEA, THROAT IRRIT, VOMITING, HEADACHE. INGEST:
HARMFUL.
=======================================================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:2U092 PULL UP
CAGE:EO320
CAGE:EO320
============= Composition/Information on Ingredients =============
Ingred Name:2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER), BUTYL
CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB * 96-1 *
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: <5%
Other REC Limits:25 PPM (SKIN)
OSHA PEL:50 PPM (SKIN)
ACGIH TLV:25 PPM (SKIN)
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Ingred Name:ACETIC ACID (ETHYLENEDIAMINETETRAACETIC ACID), EDTA
CAS:60-00-4
RTECS #:AH4025000
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VOLATILE ORGANIC CONTENT: 43 GM/L
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: NAUSEA, HEADACHE,
IRRITATION OF NASAL PASSAGES. INGESTION: MAY CAUSE
GASTRO-INTESTINAL DISTURBANCES. SKIN: REDNESS, DRYING, IRRITATION.
EYES: REDNESS & TEARING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: NAUSEA, HEADACHE, IRRITATION OF
NASAL PASSAGES. INGESTION: MAY CAUSE GASTRO-INTESTINAL
DISTURBANCES. SKIN: REDNESS, DRYING, IRRITATION. EYES: REDNESS,
TEARING.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH THOROUGHLY W/WATER. REMOVE ANY CONTACT LENSES.
CONTINUE TO FLUSH W/WATER FOR 15 MINS. INHALATION: MOVE TO FRESH
AIR. INGESTION: DRINK PLENTY OF WATER. NEVER GIVE ANYTHING BY
MOUTH/INDUCE V OMITING IF UNCONSCIOUS. SKIN: WASH THOROUGHLY W/SOAP
& WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:MOP UP MATERIAL/PICK UP W/ABSORBENT. RINSE
W/WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE
Ventilation:LOCAL EXHAUST
Other Protective Equipment:EYEWASH, PROTECTIVE CLOTHING
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Spec Gravity:1.07
pH:12
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, BLUE-GREEN LIQUID W/LEMON ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:FINE SILVER ALLOY, 27342
Preparer's Name:SEE OTHER INFORMATION.
CAGE:86337
CAGE:86337
============= Composition/Information on Ingredients =============
Ingred Name:SILVER (FORMULA AG)
CAS:7440-22-4
RTECS #:VW3500000
Minumum % Wt:99.8
Maxumum % Wt:99.99
Other REC Limits:N/K
OSHA PEL:0.01 MG/M3
OSHA STEL:N/K
ACGIH TLV:0.1 MG/M3
ACGIH STEL:N/K
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT AVAILABLE.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES/SKIN: MAY CAUSE
IRRITATION. INHALATION: MAY CAUSE IRRITATION IF EXPOSURE IS
PROLONGED OR EXCESSIVE. INGESTION: NO ADVERSE EFFECTS EXPECTED.
INGESTION OF LARGE AMOUNTS MAY BE HARMFUL. NOTE: THE POTENTIAL
HEALTH EFFECTS DESCRIBED ABOVE ONLY APPLY IF DUST OR FUME IS
FORMED. CHRONIC: THE ABSORPTION OF SILVER COMPOUNDS INTO THE
CIRCULATION AND THE SUBSEQUENT DEPOSITION OF REDUCED SILVER IN
VARIOUS TISSUES OF THE BODY MAY RESULT IN THE PRODUCTION OF A
GENERALIZED GREYISH PIGMENTATION OF THE SKIN AND MUCOUS MEMBRANE
(ARGYRIA). GENERALIZED ARGYRIA DEVELOPS AFTER 2 TO 25 YEARS OF
EXPOSURE. (EFFECTS OF OVEREXPOSURE)
Effects of Overexposure:HEALTH HAZARDS: THERE ARE NO SYSTEMIC EFFECTS
OR SYMPTOMS AND NO PHYSICAL DISABILITY. ONCE DEPOSITED, THERE IS NO
KNOWN MEANS BY WHICH THIS SILVER CAN BE ELIMINATED; THE
PIGMENTATION IS PERMANENT.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF
IRRITATION DEVELOPS, CALL A PHYSICIAN. SKIN: IMMEDIATELY WASH WITH
SOAP AND PLENTY OF WATER. IF IRRITATION PERSISTS, CALL A PHYSICIAN.
INHA LATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, OXYGEN
SHOULD BE ADMINISTERED BY QUALIFIED PERSONNEL. CALL A PHYSICIAN.
INGESTION: PROCEDURES NORMALLY NOT NEEDED. IF LARGE QUANTITIES ARE
INGES TED, SEEK MEDICAL ADVICE.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE CARBON DIOXIDE, CHEMICAL FOAM OR DRY CHEMICAL.
USE ANY MEANS FOR EXTINGUISHING SURROUNDING FIRE. DO NOT USE WATER
ON METAL FIRES.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT A FIRE OR EXPLOSION HAZARD IN SOLID
FORM. FINELY DIVIDED DUST MAY IGNITE AND BURN RAPIDLY WHEN MIXED
WITH AIR IN THE PROPER PROPORTIONS. TOXIC METAL FUMES MAY BE
RELEASED IN A FIRE SITUATION.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILLAGE & SCOOP UP/VACUUM. AVOID
DUSTING. NOTIFICATION OF NATL RESPONSE CTR (800-424-8802) MAY BE
REQUIRED. REFER TO EPA, DPT & APPLIC STATE & LOC REGS FOR CURRENT
RESPONSE INFO. IT IS REC TH AT EACH USER ESTABLISH SPILL
PREVENTION, CTL & COUNTERMEASURE PLAN (SPCC). SUCH PLAN SHOULD INCL
PROC APPLIC TO PROPER STOR, CTL & CLEAN-UP OF SPILLS, INCL
REUSE/DISP AS APPROP (SEE DISP). (SUP DAT)
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
HEAT, SPARKS AND FLAME. STORE IN A COOL, DRY LOCATION AWAY FROM
INCOMPATIBLE MATERIALS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
AVOID BREATHING ANY DUST, MIST OR FUMES RESULTING FROM THE USE OF
THIS PRODUCT.
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. DO NOT EAT,
DRINK, OR SMOKE IN WORK AREA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF DUST OR FUME IS GENERATED, A NIOSH APPROVED
RESPIRATOR MAY BE NECESSARY. FOLLOW ALL REQUIREMENTS FOR
RESPIRATORY PROGRAMS AND SELECTION SET FORTH IN THE OSHA
REGULATIONS (29 CFR 1910.134) AND IN AN SI Z88.2-92 (PRACTICES FOR
RESPIRATORY PROTECTION).
Ventilation:GENERAL; LOCAL EXHAUST VENTILATION AS NECESSARY TO CONTROL
ANY AIR CONTAMINANTS TO WITHIN THEIR PELS OR TLVS DURING THE USE OF
THIS PRODUCT.
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . BODY PROTECTION AS NECESSARY TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. PERSONNEL
SAMPLING PROCEDURE: FOR SILVER: REFER TO NIOSH MANUAL OF ANALYTICAL
METHODS (NMAM), 4TH EDITION, METHOD 7300.
Supplemental Safety and Health
SPILL PROC: NOTE: IN THE EVENT OF AN ACCIDENTAL RELEASE OF THIS
MATERIAL, THE ABOVE PROCEDURES SHOULD BE FOLLOWED. ADDITIONALLY,
PROPER EXPOSURE CONTROLS AND PERSONAL PROTECTION EQUIPMENT SHOULD
BE US ED (SEE CONTROL MEASURES SECTION), AND DISPOSAL OF THE
MATERIAL SHOULD BE IN ACCORDANCE WITH WASTE DISPOSAL SECTION.
================== Physical/Chemical Properties ==================
Boiling Pt:=2000.C, 3632.F
Melt/Freeze Pt:=961.0C, ######F
Spec Gravity:10.53 (H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:METALLIC WIRE, RED OR STRIP; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND BASES, ACETYLENE, AMMONIA, AND HYDROGEN PEROXIDE.
Stability Condition to Avoid:NONE EXPECTED.
Hazardous Decomposition Products:TOXIC METAL OXIDES ARE EMITTED WHEN
HEATED ABOVE THE MELTING POINT. THE AMOUNT OF FUME EVOLVED
INCREASES AS THE TEMPERATURE RISES.
=================== Toxicological Information===================
Toxicological Information:LD50/LC50 NOT AVAILABLE. SEE HEALTH HAZARDS,
CONTROL MEASURES, AND ECOLOGICAL INFORMATION FOR ADDITIONAL
INFORMATION. EXPOSURE LIMITS: INGREDIENT: SILVER CAS NO.:
7440-22-4 PEL-OSHA: 0.01 MG/M3; TLV- ACGIH: 0.1 MG/M3. NOTE: BOTH
OSHA AND THE ACGIH LIST WELDING FUMES AS HAVING AN EXPOSURE LIMIT
OF 5 MG/M3 (TOTAL PARTICULATE NO OTHERWISE CLASSIFIED). HOWEVER,
THE ACGIH STATES THAT WELDING FUMES MUS T BE TESTED FREQUENTLY FOR
INDIVIDUAL COMPONENTS WHICH ARE LIKELY TO BE PRESENT TO DETERMINE
WHETHER SPECIFIC EXPOSURE LIMITS ARE EXCEEDED. NOTE: THE
PERMISSIBLE EXPOSURE LIMITS (PELS), THRESHOLD (E COLOGICAL INFO)
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NO DATA AVAILABLE. ENVIRONMENTAL FATE: NO DATA
AVAILABLE. TOXICOLOGICAL INFO: LIMIT VALUES (TLVS), POTENTIAL HLTH
EFTS STATEMENTS AND SARA HAZ CATEGORIES MAY NOT BE APPLIC AS THE
HAZ INGR ED LISTED ARE IN THE SOLID FORM. IF DUST, POWDER/FUME IS
GENERATED THEN THESE STATEMENTS WILL BE APPLIC. UNLESS OTHERWISE
NOTED, ALL VALUES ARE REPORTED AS 8-HR TIME-WEIGHTED AVERAGES
(TWAS) & TOTAL DUST (PARTICULATES ONLY). ALL ACGIH TLVS REFER TO
THE 1995-96 STDS. ALL OSHA PELS REFER TO 29 CFR PART 1910 AIR
CONTAMINANTS: FINAL RULE, JAN 19, 1989*. (*NOTE: AS A RESULT OF THE
JULY 7, 1992 DECISIO N BY (STATE REG INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:US EPA WASTE #: D011. PROD CONTAINS
SILVER/SILVER CMPDS & DISP MAY BE REGULATED UNDER EPA HAZ WASTE
REGS, WASTE # D011. BEFORE DISP, PROD/MIXTS CONTAINING PROD SHOULD
BE TESTED FOR TOXICITY CHARACTS ( TC) UNDER CURRENT EPA HAZ WASTE
REGS TCLP TESTING PROC, 40 CFR PART 261 ET SEQ.
DISP/RECYCLING/RECLA MATION REQS WILL VARY BY LOCATION (OTHER INFO)
=================== MSDS Transport Information ===================
Transport Information:INTERNATIONAL: UN NUMBER: NOT REGULATED. UNITED
STATES: EPA WASTE NUMBERL D011; DOT CLASSIFICATION: NOT REGULATED.
CANADA: PIN NUMBER: NOT REGULATED; TDG CLASS: NOT REGULATED. EC:
DGL: NOT DETERMINED.
===================== Regulatory Information =====================
SARA Title III Information:SARA 311 AND 312 HAZARD CATEGORIES:
IMMEDIATE (ACUTE) HEALTH HAZARD: YES; DELAYED (CHRONIC) HEALTH
HAZARD: YES; FIRE HAZARD: NO; REACTIVITY HAZARD: NO; SUDDEN RELEASE
OF PRESSURE: NO. SARA SECTION 313 NOTIFICATION: THIS PRODUCT
CONTAINS A TOXIC CHEMICAL (OR CHEMICALS) SUBJECT TO THE REPORTING
REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 4 0 CFR PART 372:
SILVER, CAS # 7440-22-4; 99.8-99.99% WEIGHT.
Federal Regulatory Information:US FEDERAL REGULATIONS: TSCA: IN TSCA;
OZONE DEPLETING SUBSTANCES (ODS): THIS PRODUCT NEITHER CONTAINS NOR
IS MANUFACTURED WITH AN OZONE DEPLETING SUBSTANCE SUBJECT TO THE
LABELLING REQUIREMENTS OF TH E CLEAN AIR ACT AMENDMENTS 1990 AND 40
CFR PART 82; VOLATILE ORGANIC COMPOUNDS (VOC): NONE. CANADIAN
REGULATIONS: DSL/NDSL: DSL; WHMIS CLASSIFICATION: CLASS D DIVISION
2 SUBDIVISION B. EUROPEAN REGULA TIONS: EINECS: YES. OTHER
REGULATIONS: MITI: YES; AICS: YES.
State Regulatory Information:VOLATILE ORGANIC COMPOUND (CARB): NOT
DETERMINED. ECOLOGICAL INFO: THE U.S. CIRCUIT COURT OF APPEALS
(AFL-CIO B. OSHA) TO VACATE THE 1989 PELS, OSHA WILL NO LONGER
ENFORCE THESE NEW LIMITS AND WILL R ETURN TO THE PRE-1989 PELS.)
======================= Other Information =======================
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:28F30
CAGE:JO842
CAGE:24446
CAGE:JO842
============= Composition/Information on Ingredients =============
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
CAS:1336-36-3
RTECS #:TQ1350000
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA)
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE
TO FRESH AIR,GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL
ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE
UNCONSCIOUS PE RSON VOMIT.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES
EYES,NOSE,THROAT.
================== Physical/Chemical Properties ==================
HCC:V1
Appearance and Odor:LIGHT STRAW COLORED LIQUID,AROMATIC ODOR.
================= Stability and Reactivity Data =================
STRONG OXIDIZERS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APROVED DISPOSAL OPERATOR PERMITTED.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:LEAD/ACID STORAGE BATTERY-HYBRID
CAGE:08163
CAGE:08163
============= Composition/Information on Ingredients =============
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: > 60%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.05 MG/M3;1910.1025
ACGIH TLV:0.15 MG/M3;DUST 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 10 - 30%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ANTIMONY (SARA III)
CAS:7440-36-0
RTECS #:CC4025000
Fraction by Wt: > 2%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG SB/M3; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ARSENIC (SARA III)
CAS:7440-38-2
RTECS #:CG0525000
Fraction by Wt: < 0.2%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.5 MG/M3 (AS)
ACGIH TLV:0.01,A1 MG/M3; 9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CALCIUM, METAL
CAS:7440-70-2
RTECS #:EV8040000
Fraction by Wt: < 0.2%
Other REC Limits:NONE SPECIFIED
Ingred Name:POLYPROPYLENE
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE & CHRONIC-LEAD:STOMACH
CRAMPS,ANEMIA,NERVE DAMAGE(NO EXPOSURE UNDER NORMAL CONDITION OF
USE).SULFURIC AID:EROSION OF TEETH,INFLAMMATION OF NOSE,THROAT &
BRONCHIAL TUBES.WILL ALSO CAUSE BURNS,SEV ERE IRRITATION OF
SKIN,EYES,MOUTH,THROAT,ESOPHAGUS & STOMACH.
Effects of Overexposure:CONTACT WITH SULFURIC ACID RESULTS IN RAPID
DESTRUCTION OF BODY TISSUE (BURNS).COUGHING (FROM ACID MIST),
STINGING, BURNING SENSATION ON SKIN. EYE IRRITATION.
Medical Cond Aggravated by Exposure:EXPOSURE TO SULFURIC ACID MIST MAY
CAUSE LUNG DAMAGE AND AGGRAVATE PULMONARY CONDITIONS.
======================= First Aid Measures =======================
First Aid:SEE A DOCTOR.EYES/SKIN:FLUSH WITH WATER FOR 15
MINUTES.INHALATION OF SULFUR OXIDE:REMOVE TO FRESH AIR.DISCONNECT
BATTERIES & VENTILATE THE AREA.INGESTION:DRINK LARGE QUANTITIES OF
MILK/WATER,FOLLOWED BY MILK OF MAGNESIA(NO CARBONATES),BEATEN EGGS
OR VEGETABLE OIL.SEE DOCTOR IMMEDIATELY.
===================== Fire Fighting Measures =====================
Lower Limits:4.1
Upper Limits:74.2
Extinguishing Media:CO2, FOAM, DRY CHEMICAL
Fire Fighting Procedures:IF ON CHARGE, SHUT OFF POWER.
Unusual Fire/Explosion Hazard:WHILE BATTERIES ARE BEING
CHARGED,HYDROGEN GAS IS GENERATED.AVOID OPEN FLAMES,SPARKS/LIGHTED
MATCHES.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID CONTACT WITH SULFURIC ACID ELECTROLYTE
FROM BATTERY. LIME OR SODA MAY BE USED TO NEUTRALIZE AFTER DILUTING
WITH WATER. CONTAIN LARGER SPILLS WITH SAWDUST OR OTHER ABSORBING
CLOTHING.
Neutralizing Agent:LIME OR SODA
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID SKIN CONTACT.VENTILATE AREA WHEN
CHARGING BATTERIES.KEEP AWAY FROM IGNITION SOURCES DURING & AFTER
CHARGING.
Other Precautions:KEEP TERMINALS COVERED IN PLASTIC CASE.AVOID SHORTING
BATTERIES.DO NOT CRACK OR OVERCHARGE BATTERIES.KEEP LIGHTED
CIGARETTES,SPARKS,AND FLAMES AWAY FROM CHARGING BATTERIES.KEEP
BATTERIES AWAY FROM CHI LDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH-APPROVED RESPIRATOR IF 1 MG/M3 TWA IS
EXCEEDED (ACID).
Ventilation:LOCAL EXHAUST AT CHARGING STATIONS
Other Protective Equipment:RUBBER APRON AND BOOTS.EYES WASH STATION AND
SAFETY SHOWER. USE ACID-PROOF CLOTHING FOR MAJOR SPILLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:C1
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING OR REDUCING MATERIALS. MAY PRODUCE TOXIC SULFUR DIOXIDE FUMES
AND SULFURIC ACID MIST ON OVERCHARGE.
Stability Condition to Avoid:PROLONGED OVERCHARGE, CONTACT OF SULFURIC
ACID WITH ORGANIC COMPOUNDS,METALS. HIGH TEMPERATURES, SPARKS, AND
OPEN FLAMES
Hazardous Decomposition Products:MAY GENERATES ARSINE, AND/OR SULFURIC
ACID MIST ON OVERCHARGE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL ENVIRONMENTAL REGULATIONS FOR ACID OR LEAD SCRAP.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:O338225 LIGHT GREEN SF YELLOWISH
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:LIGHT GREEN SF
CAS:5141-20-8
RTECS #:BQ4900000
Fraction by Wt: >99%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): >2 GM/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE TRANSIENT IRRITATION.
SKIN: PROLONGED &/REPEATED CONTACT MAY CAUSE IRRITATION
&/DERMATITIS. INGESTION: MAY CAUSE GI IRRITATION. INHALATION: MAY
CAUSE RESPIRATORY TRACT IRRITATION. PROL ONGED/REPEATED EXPOSURE
MAY CAUSE ADVERSE REPRODUCTIVE EFFECTS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DRYING, CRACKING, NAUSEA, VOMITING,
DIARRHEA, METHEMOGLOBINEMIA.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF WATER FOR 15 MINS. SKIN:
IMMEDIATELY FLUSH W/PLENTY OF SOAP & WATER FOR 15 MINS. INGESTION:
IF CONSCIOUS & ALERT, GIVE 2-4 CUPFULLS OF MILK/WATER. INHALATION:
IMMED IATELY REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED. OBTAIN
MEDICAL ATTENTION IN ALL CASES. NOTES TO PHYSICIAN: INTRAVENOUS
INJECTION OF METHYLENE BLUE MAY BE USED IN TREATING
METHEMOGLOBINEMIA.
===================== Fire Fighting Measures =====================
Extinguishing Media:SMALL: WATER SPRAY, DRY CHEMICAL, CO2, CHEMICAL
FOAM.
Fire Fighting Procedures:WEAR A NIOSH/MSHA APPROVED SCBA IN
PRESSURE-DEMAND & FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:DUSTS AT SUFFICIENT CONCENTRATIONS CAN
FORM EXPLOSIVE MIXTURES W/AIR. COMBUSTION GENERATES TOXIC FUMES.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROPER PERSONAL PROTECTIVE EQUIPMENT.
SWEEP UP, THEN PLACE INTO A SUITABLE CONTAINER FOR DISPOSAL. AVOID
GENERATING DUSTY CONDITIONS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA AWAY FROM INCOMPATIBLE SUBSTANCES. USE W/ADEQUATE VENTILATION.
KEEP CONTAINER TIGHTLY CLOSED
Other Precautions:MINIMIZE DUST GENERATION & ACCUMULATION. AVOID
CONTACT W/SKIN & EYES. AVOID INGESTION & INHALATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A NIOSH APPROVED RESPIRATOR WHEN NEEDED.
Ventilation:LOCAL EXHAUST: MAY BE NECESSARY TO CONTROL CONCENTRATIONS
TO ACCEPTABLE LEVELS. GOOD GENERAL SHOULD BE SUFFICIENT.
Other Protective Equipment:APPROPRIATE PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:550.4F
Decomp Temp:Decomp Text:550.4F
Solubility in Water:COMPLETE
Appearance and Odor:RED-BROWN TO PUPLE POWDER W/NO ODOR REPORTED.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:EXCESS HEAT.
Hazardous Decomposition Products:NITROGEN OXIDES, CO, OXIDES OF SULFUR,
CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:HSTR956-0380-400
CAGE:50054
CAGE:83003
CAGE:50054
============= Composition/Information on Ingredients =============
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
CAS:1336-36-3
RTECS #:TQ1350000
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER (SUP DATA
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE
TO FRESH AIR,GIVE ART.RESPIR.AS NEEDED INGEST:GET MEDICAL ATTN.GIVE
LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIOUS
PER SON VOMIT.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSROBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT.
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES
EYES,NOSE THROAT.
================== Physical/Chemical Properties ==================
Appearance and Odor:LIGHT STRAW-COLORED LIQUID AROMATIC ODOR
================= Stability and Reactivity Data =================
STRONG OXIDIZERS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:TIN/LEAD SOLDER ALLOY
CAGE:56244
CAGE:56244
CAGE:076J3
============= Composition/Information on Ingredients =============
Ingred Name:TIN
CAS:7440-31-5
RTECS #:XP7320000
Fraction by Wt: 50.0%
Other REC Limits:2 MG/M3
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3; 9192
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 48.5%
Other REC Limits:0.05 MG/M3
OSHA PEL:0.05 MG/M3;1910.1025
ACGIH TLV:0.15 MG/M3;DUST 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ROSIN ACID
CAS:8050-09-7
Fraction by Wt: 1.5%
Other REC Limits:NONTOXIC
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: WHILE IT IS POSSIBLE FOR LEAD
TAKEN IN EXTREMELY LARGE DOSES TO CAUSE ENCEPHALOPATHY, A BRAIN
CONDITION THAT CAN RESULT IN SEIZURES, COMA AND DEATH, EXPOSURES OF
THIS MAGNITUDE ARE HIGHLY UNUSU AL. CHRONIC: MAY RESULT IN DAMAGE
TO THEBLOOD-FORMING, NERVOUS, URINARY AND REPRODUCTIVE SYSTEMS.
Explanation of Carcinogenicity:NOT LISTED BY NTP, IARC OR OSHA AS A
CARCINOGEN.
Effects of Overexposure:LOSS OF APPETITE, METALLIC TASTE IN THE MOUTH,
ANXIETY, CONSTIPATION, NAUSEA, PALLOR, EXCESSIVE TIREDNESS,
WEAKNESS, INSOMNIA, HEADACHE, NERVOUS IRRITABILITY, MUSCLE AND
JOINT SORENESS, TREMORS, DIZZI NESS, AND ABDOMINAL PAIN.
Medical Cond Aggravated by Exposure:DISEASES OF THE BLOOD-FORMING,
NERVOUS, URINARY AND REPRODUCTIVE SYSTEMS. EXPOSURE TO LEAD MAY
RESULT IN INJURY TO A DEVELOPING FETUS.
======================= First Aid Measures =======================
First Aid:IF A PERSON BREATHES IN A LARGE AMOUNT OF FUMES, REMOVE FROM
EXPOSURE. IF BREATHING HAS STOPPED, PERFORM ARTIFICIAL RESPIRATION.
CALL A PHYSICIAN. INGESTION IS NOT LIKELY. CALL A PHYSICIAN. IF
LEAD GE TS IN EYES, FLUSH WITH A LARGE AMOUNT OFWATER. CALL A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER
FOG.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:MATERIAL IS IN SOLID FORM; PICK UP AND REUSE.
WHEN MOLTEN, LET SOLIDIFY AND REUSE IF NOT CONTAMINATED. IF
CONTAMINATED, SELL FOR RECYCLING. FINE DUST SHOULD BE VACUUMED.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE REQUIRED.
Other Precautions:WEAR FUME AND DUST MASK WHEN SOLDERING AND TAKE ALL
NECESSARY PRECAUTIONSREQUIRED FOR SOLDERING AND WELDING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR LEAD, IF
EXPOSURES EXCEED THE OSHA LIMIT.
Ventilation:USE ENOUGH VENTILATION WHEN SOLDERING TO KEEP THE METAL AND
FLUX FUMES AWAY FROM THE WORKERS BREATHING ZONE & BELOW PEL.
Other Protective Equipment:NONE REQUIRED
SOLDERING. IF WIRE HANDLED WITH BARE HANDS, ALWAYS WASH THOROUGHLY
BEFORE EATING OR SMOKING
Supplemental Safety and Health
EXPOSURE TO LEAD IS REGULATED BY OSHA 1910.1025
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:=3406.7C, 6164.F
B.P. Text:3164F,1740C
Melt/Freeze Pt:=181.1C, 358.F
M.P/F.P Text:358F,181C
Vapor Pres:1
Spec Gravity:8.55
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SOLID SILVER GREY METAL WITH FLUX CORE; NO ODOR
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:HIGH TEMPERATURES CAN PRODUCE METAL
VAPORS/FUMES, CARBON DIOXIDE AND MONOXIDE, VARIOUS HYDROCARBONS,
METAL OXIDES & NOX.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL LAWS AND REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:KARMEX DF HERBICIDE
Preparer's Name:AGRICULTURAL PROD DIV.
CAGE:2S827
CAGE:2S827
CAGE:8C885
CAGE:0TNN7
CAGE:1HB45
============= Composition/Information on Ingredients =============
Ingred Name:DIURON (CERCLA)
CAS:330-54-1
RTECS #:YS8925000
Fraction by Wt: 80%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3; 9596
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:INERT INGREDIENTS
Fraction by Wt: 20%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 2900 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONTACT MAY CAUSE SKIN & EYE
IRRITATION. INHALATION/INGESTION MAY CAUSE LIVER ENLARGEMENT,
SPLEEN & THYROID EFFECTS, DESTRUCTION OF RED BLOOD CELLS. CHRONIC:
NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:SKIN:IRRITATION, RASH. EYES:IRRITATION,
TEARING, BLURRED VISION. INHALED/INGESTED:
METHEMOGLOBINEMIA:CYANOSIS (BLUISH SKIN), WEAKNESS, SHORTNESS OF
BREATH.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
DISEASES OF THE LIVER OR BONE MARROW MAY HAVE INCREASED
SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE. NO ADEQUATE
EPIDEMIOLOGICAL STUDIES ARE AVAILABLE FOR PRODUCT
======================= First Aid Measures =======================
First Aid:IN ALL CASES GET MEDICAL ATTENTION. EYES-IMMEDIATELY FLUSH
WITH WATER FOR 15 MINUTES. SKIN-REMOVE CONTAMINATED CLOTHES. WASH
WITH MILD SOAP & WATER. INHALED-REMOVE TO FRESH AIR. ADMINISTER
OXYGEN OR A RTIFICIAL RESPIRATION AS NEEDED. INGESTED-IF CONSCIOUS,
IMMEDIATELY GIVE 2 GLASSES WATER & INDUCE VOMITING. CALL A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:851F
Lower Limits:0.07 G/L
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT. WATER USE MAY INCREASE CONTAMINATION
HAZARD. CONSIDER ALLOWING FIRE TO BURN ITSELF OUT.
Unusual Fire/Explosion Hazard:LIKE MOST ORGANIC POWDERS OR CRYSTALS,
UNDER SEVERE DUSTING CONDITIONS, THIS MATERIAL MAY FORM EXPLOSIVE
MIXTURES WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:USE APPROPRIATE PERSONAL PROTECTIVE
GEAR/EQUIPMENT, INCLUDING SCBA. EVAUATE PERSONNEL. VENTILATE AREA.
DIKE SPILL. PREVENT MATERIAL FROM ENTERING SEWERS, WATERWAYS OR LOW
AREAS. SHOVEL OR SWEEP UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A WELL-VENTILATED AREA. KEEP
CONTAINER TIGHTLY CLOSED. DO NOT STORE OR CONSUME FOOD, DRINK OR
TOBACCO IN AREAS WHERE THEY MAY BE CONTAMINATED
Other Precautions:AVOID BREATHING VAPORS OR MIST. AVOID BREATHING DUST.
AVOID CONTACT WITH EYES, SKIN OR CLOTHING. WASH THOROUGHLY AFTER
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DLA-HMIS: IF ENGINEERING CONTROLS FAIL OR
NON-ROUTINE USE OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED
RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE OR AN AIR-SUPPLIED
RESPIRATOR OR SCBA, AS REQUIRED . USE IAW 29 CFR 1910.134.
Ventilation:USE ONLY WITH ADEQUATE VENTILATION. KEEP CONTAINERS TIGHTLY
CLOSED.
Other Protective Equipment:LONG SLEEVED SHIRT & LONG PANTS. SHOES PLUS
SOCKS. DLA-HMIS: EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
EPA REG # 352-508.
================== Physical/Chemical Properties ==================
HCC:T4
NRC/State Lic Num:NONE
Solubility in Water:DISPERSIBLE
Appearance and Odor:BROWN GRANULES, ODORLESS. BULK DENSITY 32.5-39.5
LB/ FT3
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORSEEABLE.
Stability Condition to Avoid:STABLE AT NORMAL TEMPERATURES AND STORAGE
CONDITIONS.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MUST BE IAW
NATIONAL, STATE/PROVINCIAL OR LOCAL REGULATIONS. REMOVE NONUSEABLE
SOLID MATERIAL &/OR CONTAMINATED SOIL FOR DISPOSAL IN AN APPROVED &
PERMITTED LANDFILL. DO NOT FLUSH TO SURFACE WATER OR SANITARY
SEWER.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:140 FLASH NAPTHA
CAGE:91341
CAGE:91341
============= Composition/Information on Ingredients =============
Ingred Name:HYDROCARBONS,SATURATED; TLV PER MFG.
Fraction by Wt: 94.6%
ACGIH TLV:200 PPM
Ingred Name:HYDROCARBONS,AROMATIC;TLV PER MFG
Fraction by Wt: 5.4%
ACGIH TLV:200 PPM
===================== Hazards Identification =====================
Effects of Overexposure:INHALE:IRRITNT,DROWSY,COLLAPSE,TWITCH,COMA, &
LATER PNEUMONIA,EYE/SKIN:IRRITNT;INGEST: HARMFUL
======================= First Aid Measures =======================
First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF
NEED;EYES/SKIN:FLUSH W LG AMTS H*2O FOR 15 MIN;INGEST:RINSE MOUTH,
GET IMMEDIATE MEDICAL ATTENTION(DO NOT INDUCE VOMIT;DRINKING OF
VEGETABLE OIL, IE OLIVE O IL, IS INDICATED IN LITERATURE.
===================== Fire Fighting Measures =====================
Flash Point:143F,61.7C TCC
Extinguishing Media:CO*2,DRY CHEM,FOAM,WATER SPRAY (DOT P 5800.2)
Fire Fighting Procedures:SELF-CNTND BRTHG APP;H*2O SPRAY COOL CONT.
Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE IN HEAT OF FIRE
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION
SOURCES. PROVIDE VENTILATION. STOP LEAK. H*2O SPRAY COOL CONT, IF
HOT; ABSORB W COMMERCIAL ABSORBENT, PLACE IN COVERED CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW
FIRE RISK AREA. KEEP CONTAINERS TIGHTLY CLOSED. PROTECT FROM
PHYSICAL DAMAGE.
Other Precautions:MAINTAIN STRICT HYGIENE,AVOID PHYSICAL CONTACT,
REMOVE & WASH COMTAMINATED CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR EXPOSURE:SELF-CNTND BRTH APP/APPR RESPIRATOR
Ventilation:MECHANICAL(GENERAL/LOCAL EXHAUST)
Other Protective Equipment:FULL WORK CLOTHING.
Supplemental Safety and Health
II TYPE;BOILING POINT RANGE:360-410;PROLONGED CONTACT WITH SKIN MAY
CAUSE DERMATITIS.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:385F,196C
Vapor Pres:2.3
Vapor Density:5.5
Spec Gravity:0.7728
Evaporation Rate & Reference:3
Solubility in Water:NEGLIGIBLE
Appearance and Odor:TRANSPARENT LIQUID; HYDROCARBON SOLVENT ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE NOTED
Stability Condition to Avoid:IGNITION SOURCES
Hazardous Decomposition Products:EXPECT CO FROM INCOMPLETE COMBUSTION
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED CONTAINERS PENDING DISPOSAL.
HANDLE AND DISPOSE IN FULL COMPLIANCE WIT ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ACTUSOL T-776
Resp. Party Other MSDS Num.:00245
CAGE:72008
CAGE:72008
Contract Num:SP0450-99-M-NE51
CAGE:1HP53
============= Composition/Information on Ingredients =============
Ingred Name:KEROSENE
CAS:8008-20-6
RTECS #:OA5500000
Fraction by Wt: <40%
OSHA PEL:100 MG/M3
ACGIH TLV:100 MG/M3
Ingred Name:CYCLOHEXANOL
CAS:108-93-0
RTECS #:GV7875000
Fraction by Wt: <5%
OSHA PEL:206 MG/M3,SKIN
ACGIH TLV:206 MG/M3;50 PPM
Ingred Name:HEXYLENE GLYCOL
CAS:107-41-5
RTECS #:SA0810000
Fraction by Wt: <3%
OSHA PEL:C 121 MG/M3
ACGIH TLV:C 121 MG/M3
ACGIH STEL:C121 MG/M3;C25 PPM
Ingred Name:DIETHANOLAMINE
CAS:111-42-2
RTECS #:KL2975000
Fraction by Wt: <2%
ACGIH TLV:2 MG/M3;0.46PPM(SKIN
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TRIETHANOLAMIN
CAS:102-71-6
RTECS #:KL9275000
Fraction by Wt: <9%
ACGIH TLV:5 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: DEFATS SKIN, IRRITATES EYES,
OVEREXPOSURE TO MIST OR VAPORS MAY CAUSE DIZZINESS, HEADACHE OR
NAUSEA. CHRONIC: SAME AS ACUTE
Explanation of Carcinogenicity:MFG LISTED CARCINOGENS: NONE
Effects of Overexposure:OVER EXPOSURE TO MIST OR VAPORS MAY CAUSE
DIZZINESS, HEADACHE OR NAUSEA
Medical Cond Aggravated by Exposure:IMPAIRED PULMONARY FUNCTION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH THOROUGHLY WITH FRESH WATER FOR AT LEAST 15
MINUTES, GET MEDICAL ATTENTION. SKIN; FLUSH WITH FRESH WATER, WASH
WITH SOAP AND WATER. REMOVE CONAMINATED CLOTHES AND SHOES. GET
MEDICAL ATTENT ION. INGESTION: GIVE WATER. DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON. INHALATION: REMOVE TO FRESH AIR. GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:=57.2C, 135.F
Lower Limits:1.0
Upper Limits:6.0
Extinguishing Media:CO2,FOAM,DRY CHEMICALS
Fire Fighting Procedures:SAME AS FOR KEROSENE TYPE SOLVENTS
Unusual Fire/Explosion Hazard:NONE KNOWN
================== Accidental Release Measures ==================
Spill Release Procedures:IF MATERIAL IS RELEASED OR SPILLED : COLLECT
WITH FLOOR DRY MATERIAL AND DISPOSE TO SOLID WASTE.
======================Handling and Storage ======================
Handling and Storage Precautions:NO SPECIAL SEPARATION. KEEP AWAY FROM
HEAT, SPARKS, AND OPEN FLAMES. DO NOT PRESSURE TO EMPTY DRUM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV/PEL MAY BE EXCEEDED, USE A NIOSH APPROVED
ORGANIC VAPOR RESPIRATOR WITH A HIGH EFFICIENCY PARTICULATE FILTER.
Other Protective Equipment:NONE
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T6
Boiling Pt:=204.4C, 400.F
Spec Gravity:0.8700
Solubility in Water:>10
Appearance and Odor:BROWN LIQUID, ODOR=PINE
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Hazardous Decomposition Products:CO,SO2, WITH INCOMPLETE COMBUSTION
==================== Disposal Considerations ====================
Waste Disposal Methods:TREAT BY BREAKING EMUSTION AND COLLECTION OF
INSOLUBLE SOLVENTS FOR BURNINGOR SOLVENT DISPOSAL. DEFACE OR REMOVE
LABEL BEFORE DISPOSAL OF DRUM.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED UP TO 119 GALOON QUANTITIES. OVER
119 GALLONS: COMBUSTABLE NA 1993
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING SARA
REPORTABLES; CYCLOHEXANOL(108-93-0) AT 5%, DIETHANOLAMINE
(111-42-2) AT 1.5%
State Regulatory Information:STATE RIGHT -TO- KNOW INFORMATION:
KEROSENE-CAS #8008-20-6.LINEAR ALCOHOL ETHOXYLATE CAS
#68439-46-3.TRIETHANOLAMINE-CAS #102-27-6.PINE OIL-CAS #8002-90-3.
CYCLOHEXANOL-CAS #108-93-0. HEXYLENE GLYCOL -CAS #107-41-5.
SURFACTANT -CAS #2624-05-1. DIEHANOLAMINE -CAS#111-42-2
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:ARMSTRONG RESIN C-7.
Kit Part:Y
CAGE:DO043
CAGE:DO043
CAGE:98911
============= Composition/Information on Ingredients =============
Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT
===================== Hazards Identification =====================
Effects of Overexposure:PRIMARY IRRIT OF SKIN-ONPROLNG OR REPEATED
CONTACT.MINOR TRANSIENT IRRIT TO EYE CONTCT-NO CORNEA INJ
======================= First Aid Measures =======================
First Aid:REMOVE FR SKIN W/WATER OR WATERLESS SKIN CLEANER.REMOV CONTAM
CLOTHNG & WASH BEFORE REUSE.EYES:FLSH EYES,IF ANY ILL EFFCTS
DEVEL,GET MED ATTN.INHAL:REMOV PERSON TO FRESH AIR,GET MED
ATTN.INGEST:NOT LI KELY PROB.NO KNOWN ANTIDOTE,TREAT SYST.INDUC
VOMIT
===================== Fire Fighting Measures =====================
Flash Point:480 F COC 249 C
Extinguishing Media:WATER SPRAY, FOAM, CO*2, DRY CHEMICALS
Fire Fighting Procedures:NONE-AVOID BREATHING SMOKE.
Unusual Fire/Explosion Hazard:NO UNUSUAL HAZARDS
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN W/A CLOTH-OBSERVE FIRE HAZARD IF
SOLVENTS ARE USED.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL PLACE. PRACTICE GOOD
AUTION & PERSONAL CLEANLINESS TO AVOID SKIN & EYE CONTACT. AVD
BREATHING VAP OF HEATED MATERIAL
Other Precautions:HANDLE IN ACCORDANCE W/HAZARDOUS POTENTIALITIES OF
THE CURING AGENT WHEN MIXED THEREWITH. SPI CLASSIFICATION 2.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT ORDINARILY REQD
Ventilation:LOC EXHAUST-ONLY IF HEATED,MECHANICAL-NOT ORDINARILY
NEEDED.
Supplemental Safety and Health
MSDS UNDATED. LD50>2000MG/KG-RAT. CHEM
NAME:4,4ISOPROPYLIDENEDIPHENOL-EPICHLORHYDRIN RESIN.
CHEM.FORMULA:(C*15H*16O*2.C*3H*5C*10)*X.
================== Physical/Chemical Properties ==================
Spec Gravity:1.17
Appearance and Odor:AMBER LIQUID,MILD AROMATIC ODOR
Percent Volatiles by Volume:1.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:EXCESS HEATING OVER LONG PERIODS OF TIME
DEGRADES RESIN
Hazardous Decomposition Products:CARBON MONOXIDE,ALDEHYDES ACIDS, ETC.
Conditions to Avoid Polymerization:EXOTHERMS WHEN CURED.
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:104 5053 FLEXICOLOR DEVELOPER REPLENISHER LORR, PART A
Kit Part:Y
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 55-60%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POTASSIUM CARBONATE
CAS:584-08-7
RTECS #:TS7750000
Fraction by Wt: 30-35%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM SULFITE
CAS:7757-83-7
RTECS #:WE2150000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:PENIETIC ACID, PENTA SODIUM SALT
CAS:140-01-2
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POTASSIUM SULFITE
CAS:10117-38-1
RTECS #:WT3530000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM BROMIDE
CAS:7647-15-6
RTECS #:VZ3150000
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): NOT GIVEN
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPECTED TO BE A LOW INHALATION HAZARD
FOR RECOMMENDED HANDLING. EYE CONTACT CAUSES IRRITATION. SKIN
CONTACT CAUSES IRRITATION. EXPECTED TO BE A LOW INGESTION HAZARD.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMEEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS
OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE TO REMOVE RESIDUA L CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions:THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND
CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL HELP MINIMIZE
THE POSSIBILITY OF A SKIN REACTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. KEY1:C4.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.413
pH:11.7
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID, NO ODOR
Percent Volatiles by Volume:55-60%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY
REASONABLY COME INTO CONTACT.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. DISPOSE OF IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
===================== Product Identification =====================
Product ID:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE, IEA T1784, T1784LC
Resp. Party Other MSDS Num.:26370
CAGE:DO274
Contract Num:N00406-00-P-9734
CAGE:56524
CAGE:DO274
============= Composition/Information on Ingredients =============
Ingred Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE. (EINECS# 200-936-1)
CAS:76-13-1
RTECS #:KJ4000000
= Wt:100.
Other REC Limits:2000 PPM NIOSH IDLH
OSHA PEL:1000 PPM, 7600 MG/M3
ACGIH TLV:1000 PPM, 7670 MG/M3
ACGIH STEL:1250 PPM, 9590 MG/M3
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL, RAT: LD50 = 43 GM/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EMERGENCY OVERVIEW: CAUTION: MAY CAUSE
EYE IRRITATION. VAPOR REDUCES OXYGEN AVAILABLE FOR BREATHING. MAY
CAUSE CENTRAL NERVOUS SYSTEM EFFECTS, RESPIRATORY AND DIGESTIVE
TRACT IRRITATION, CARDIAC DISTU RBANCES, DERMATITIS. TARGET ORGANS:
HEART, CENTRAL NERVOUS SYSTEM. POTENTIAL HEALTH EFFECTS: EYE:
CONTACT PRODUCES IRRITATION, TEARING, BURNING PAIN; MAY CAUSE
CONJUNCTIVITIS. SKIN: MAY CAUSE IRRITAT ION. PROLONGED/REPEATED
CONTACT MAY CAUSE DEFATTING OF SKIN AND DERMATITIS. INGESTION:
LARGE AMOUNTS MAY CAUSE GASTROINTESTINAL IRRITATION. EXPECTED TO BE
A LOW INGESTION HAZARD. INHALATION: INHALATIO N OF (SIGNS &
SYMPTOMS OF OVEREXPOSURE)
Explanation of
Carcinogenicity:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE-ACGIH: A4-NOT
CLASSIFIABLE AS A HUMAN CARCINOGEN.
Effects of Overexposure:HEALTH HAZARDS ACUTE AND CHRONIC (CONT): HIGH
CONCENTRATIONS MAY CAUSE CENTRAL NERVOUS SYSTEM EFFECTS
CHARACTERIZED BY HEADACHE, DIZZINESS, UNCONSCIOUSNESS AND COMA.
VAPOR REDUCES OXYGEN AVAILABLE FO R BREATHING. MAY CAUSE REPIRATORY
TRACT IRRITATION, HEART DISTURBANCES-POSSIBLY LEADING TO CARDIAC
ARREST AND DEATH. MAY CAUSE NARCOTIC EFFECTS IN HIGH CONCENTRATION.
CHLOROFLUOROCARBON (CFC) MATERIAL S MAY SENSITIZE THE HEART TO
EPINEPHRINE. THE USE OF EPINEPHRINE MAY BE CONTRA-INDICATED EXCEPT
FOR LIFE-SUSTAINING USES IN HUMANS EXPOSED TO CFC'S. CHRONIC:
PROLONGED OR REPEATED SKIN CONTACT MAY CA USE DEFATTING AND
DERMATITIS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15 MINUTES,
OCCASIONALLY LIFTING UPPER AND LOWER EYELIDS. GET MEDICAL AID.
SKIN: FLUSH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES,
WHILE REMO VING CONTAMINATED CLOTHING AND SHOES. GET MEDICAL AID IF
IRRITATION DEVELOPS OR PERSISTS. WASH CLOTHING BEFORE REUSE.
INGESTION: IF THE VICTIM IS CONSCIOUS AND ALERT, GIVE 2 - 4 CUPFULS
OF MILK OR WAT ER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL AID. INHALATION: REMOVE FROM EXPOSURE TO FRESH
AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING DIFFI CULT, GIVE OXYGEN. (OTHER INFORMATION)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:=680.C, 1256.F
Extinguishing Media:FOR SMALL FIRES, USDE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE OR CHEMICAL FOAM. USE EXTINGUISHING MEDIA MOST
APPROPRIATE FOR THE SURROUNDING FIRE. (UNUSUAL FIRE & EXPLOSION
HAZARD)
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE-DEMAND, NIOSH (APPROVED OR
EQUIVALENT), AND FULL PROTECTIVE GEAR. DURING A FIRE, IRRITATING
AND HIGHLY TOXIC GASSES MAY BE GENERAT ED BY THERMAL DECOMPOSITION
OR COMBUSTION. VAPORS MAY BE FLAMMABLE IN VESSELS OF (UNUSUAL FIRE
AND EXPLOSION HAZARD)
Unusual Fire/Explosion Hazard:N/P. EXTINGUISHING MEDIA (CONT):
COOL CONTAINERS WITH FLOODING QUANTITIES OF WATER UNTIL WELL AFTER
FIRE IS OUT. FIRE FIGHTING PROCEDURE (CONT): ADEQUATE SIZE.
VAPORS MAY BE HEAVIER THANAIR. THEY CAN SPREAD ALONG THE GROUND
AND COLLECT IN LOW OR CONFINED AREAS. NFPA RATING: NOT
PUBLISHED.
================== Accidental Release Measures ==================
Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN (CONTROL MEASURES) SECTION.
SPILLS / LEAKS: ABSORB WITH INERT MATERIAL (E.G., DRY SAND OR
EARTH), THEN PLACE INTO A C HEMICAL WASTE CONTAINER. REMOVE ALL
SOURCES OF IGNITION. PROVIDE VENTILATION.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLING: WASH THOROUGHLY AFTER
HANDLING. REMOVE CONTAMINATED CLOTHING AND WASH BEFORE REUSE. USE
WITH ADEQUATE VENTILATION. AVOID CONTACT WITH SKIN AND EYES. AVOID
INGESTION AND INHALATION. STORAGE: KEEP FROM CONTACT WITH
OXIDIZING MATERIALS. STORE IN A COOL, DRY, (OTHER PRECAUTIONS)
Other Precautions:HANDLING AND STORAGE PRECAUTIONS (CONT):
WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES. KEEP AWAY
FROM METALS. KEEP CONTAINERS TIGHTLY CLOSED. DO NOT STORE IN
ALUMINUM CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN149 APPROVED RESPIRATOR WHEN NECESSARY.
EXPOSURE LIMITS (CONT INUED FROM INGREDIENT SECTION): NIOSH: 1000
PPM TWA, 7600 MG/M3 TWA.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT TO CONTROL
AIRBORNE LEVELS. USE PROCESS ENCLOSURE, LOCAL EXHAUST VENTILATION
OR (SUPPLEMENTAL SAFETY AND HEALTH)
PREVENT SKIN EXPOSURE
SAFETY AND HEALTH)
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . CLOTHING: WEAR APPROPRIATE PROTECTIVE CLOTHING
TO MINIMIZE CONTACT WITH SKIN.
Work Hygienic Practices:N/P. NO SMOKING IN AREA OF USE. DO NOT USE
IN THE VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT
AND / OR UV RADIATION MAY CAUSE THE FORMATION OF FLUORIDES,
CHLORIDES AND PHOSGENE
Supplemental Safety and Health
VENTILATION (CONT): OTHER ENGINEERING CONTROLS TO CONTROL AIRBORNE
P ROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD
EN166
================== Physical/Chemical Properties ==================
Boiling Pt:=45.8C, 114.4F
Melt/Freeze Pt:=-36.4C, -33.5F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:273 MMHG @ 20C
Vapor Density:6 (AIR=1)
Spec Gravity:1.6 @ 25C
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Evaporation Rate & Reference:0.45 (ACETONE=1)
Solubility in Water:0.028%
Appearance and Odor:CLEAR, COLORLESS LIQUID; ETHEREAL ODOR (WEAK ODOR).
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS SUCH AS SODIUM, POTASSIUM, ALUMINUM,
BARIUM, LITHIUM, SAMARIUM, SODIUM-POTASSIUM ALLOY, TITANIUM, ZINC,
MAGNESIUM AND BERYLLIUM.
Stability Condition to Avoid:STABLE UNDER NORMAL TEMPERATURES AND
PRESSURES. AVOID INCOMPATIBLE MATERIALS, IGNITION SOURCES, METALS,
STRONG OXIDANTS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CARBON
MONOXIDE, IRRITATING AND TOXIC FUMES AND GASES, CARBON DIOXIDE,
HYDROGEN FLUORIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
=================== Toxicological Information===================
Toxicological Information:EPIDEMIOLOGY, TERATOGENICITY, REPRODUCTIVE
EFFECTS, NEUROTOXICITY, MUTAGENICITY: NO INFORMATION AVAILABLE.
OTHER STUDIES: NO DATA AVAILABLE. FEDERAL REGULATORY
(CONT): OF THE CHEMICALS IN THI S PRODUCT ARE LISTED AS HAZARDOUS
SUBSTANCES UNDER THE CWA. NONE OF THE CHEMICALS IN PRODUCT ARE
LISTED AS PRIORITY POLLUTANTS UNDER THE CWA. NONE OF THE CHEMICALS
IN THIS PRODUCT ARE LISTED AS TOX IC POLLUTANTS UNDER THE CWA.
OSHA: NONE OF THE CHEMICALS IN THIS PRODUCT ARE CONSIDERED HIGHLY
HAZARDOUS BY OSHA.
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAILABLE.ENVIRONMENTAL FATE: HAS VERY
LIMITED SOLUBILITY IN WATER AND IS HIGHLY VOLATILE. EXPECTED TO BE
EVENTUALLY CONVEYED TO ATMOSPHERE. HAS SOME POTENTIAL TO PETURB
STRATOSPHER IC OZONE. PHYSICAL / CHEMICAL: NOT AVAILABLE.OTHER:
NOT AVAILABLE. STATE REGULATORY (CONT): WGK (WATER DANGER /
PROTECTION) CAS # 76-13-1: 2. CANADA: CAS # 76-13-1 IS LISTED ON
CANADA'S DS L / NDSL LIST.THIS PRODUCT HAS A WHMIS CLASSIFICATION
OF D2B. CAS # 76-13-1 IS NOT LISTED ON CANADA'S INGREDIENT
DISCLOSURE LIST. EXPOSURE LIMITS CAS 76-13-1: OEL - AUSTRALIA:
TWA 1000 PPM (7600MG/M3); STEL 1250 PPM. (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA P-SERIES: NONE LISTED. RCRA
U-SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:US DOT: NO INFORMATION AVAILABLE. CANADIAN TDG:
NO INFORMATION AVAILABLE. ECOLOGICAL INFO (CONT): OEL -
BELGIUM: TWA 1000 PPM (7670 MG/M3); STEL 1250 PPM.OEL - DENMARK:
TWA 500 PPM (3800 MG/ M3).OEL - FINLAND: TWA 1000 PPM (7600
MG/M3); STEL 1250 PPM. OEL - FRANCE: TWA 1000 PPM (7600 MG/M3);
STEL 1250 PPM. OEL - GERMANY: TWA 500 PPM (3800 MG/M3). OEL -
HUNGARY: STEL 40 MG/M3. OEL - JAPAN: TWA 500 PPM (380 MG/M3).
OEL - THE NETHERLANDS: TWA 1000 PPM (7600 MG/M3). OEL - THE
PHILLIPINES: TWA 1000 PPM (7600 MG/M3). OEL - RUSSIA: TWA 500 PPM;
STEL 5000 MG/M3. OEL - SWEEDEN: TWA 5 00 PPM (4000 MG/M3); (SARA
III)
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN
THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS
IN THIS PRODUCT HAVE A TPQ. SARA CODES: CAS# 76-13-1: ACUTE,
CHRONIC. SECTION 313: THIS MATERIAL CONTAINS 1,1,2-
TRICHLORO-1,2,2-TRIFLUOR (CAS# 76-13-1, 100%), WHICH IS SUBJECT TO
REPORTING REQUIREMENTS OF SECTION 313 OF SARA TITLE III AND 40 CFR
PART 372. TRANSPORT INFO (CONT): STEL 750 PPM (6000 MG/M3).
OEL - SWITZERLAND: TWA 500 PPM (3800 MG/M3). OEL - TURKEY: TWA
1000 PPM (7600 MG/M3). OEL - UNITED KINGDOM: TWA 1000 PPM (7600
MG/M3); STEL 1250 PPM. OEL IN BULGARIA, CO LOMBIA CHECK ACGIH TLV.
(OTHER INFO)
Federal Regulatory Information:TSCA CAS# 76-13-1 IS LISTED ON TSCA
INVENTORY.HEALTH AND SAFETY REPORTING LIST CAS# 76-13-1:
EFFECTIVE DATE 13 APRIL 1989; SUNSET DATE 19 DEC 1995. CHEMICAL
TEST RULES: NONE OF CHEMICALS IN THIS PR ODUCT ARE UNDER CHEMICAL
TEST RULE.SECTION 12B: NONE OF CHEMICALS LISTED UNDER TSCA
SECTION 12B. TSCA SIGNIFICANT NEW USE RULE: NONE OF CHEMICALS IN
THIS MATERIAL HAVE A SNUR UNDER TSCA. CLEAN AI R ACT: THIS
MATERIAL DOES NOT CONTAIN ANY HAZARDOUS AIR POLLUTANTS. DEPLETION
POTENTIAL = 0.8; GLOBA L WARMING POTENTIAL = 5000 (20). THIS
MATERIAL DOES NOT CONTAIN ANY CLASS 2 OZONE DEPLETORS. CLEAN WATER
ACT: NONE OF (TOXICOLOGICAL INFO)
State Regulatory Information:1,1,2-TRICHLORO-1,2,2-TRIFLUOR CAN BE
FOUND ON THE FOLLOWING STATE RIGHT-TO-KNOW LISTS: CALIFORNIA, NEW
JERSEY, FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS.
CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN
THIS PRODUCT ARE LISTED. EUROPEAN / INTERNATIONAL REGULATIONS:
EUROPEAN LABELING IN ACCORDANCE WITH EC DIRECTIVES: HAZARD SYMBOLS:
XN N. RISK PHRASES: R 20/22 HARMFUL BY I NHALATION AND IF
SWALLOWED, R 59 DANGEROUS FOR OZONE LAYER. SAFETY PHRASES: S 44 IF
YOU FEEL UNWELL, SEEK MEDICAL ADVICE (SHOW THE LABEL WHERE
POSSIBLE); S 9 KEEP THE CONTAINER IN A WELL-VENTILATED PLACE.
(ECOLOGICAL INFO)
======================= Other Information =======================
| 1 | gloves_mandatory |
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