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* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED. IF OXYGEN DEFICIENT
BREATHING APPARATUS.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING.
Supplemental Safety and Health
MSDS WAS PROVIDED BY VENDOR ALONG WITH ONE FOR AN OIL (SEE PNI A THIS
NSN/CAGE) THAT IS ALSO PRESENT IN THE ACTUATING CYLINDER. HCC &
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NITROGEN
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: ASPHYXIATION. CONTACT MAY CAUSE
FROSTBITE. CHRONIC: NONE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:CONTACT-FROSTBITE. INHALATION: RAPID
RESPIRATION & PULSE, SHORTNESS OF BREATH, DIFFICULTY BREATHING,
UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESUSCITATE IF NEEDED. TREAT
SYMPTOMATICALLY & SUPPORTIVELY. GET MEDICAL ATTENTION. FROSTBITE:
WARM AREA WITH WARM(!), NOT HOT, WATER SOAKED TOWELS OR SIMILAR
MATERIAL . GET IMMEDIATE MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE MEDIA FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR. COOL CONTAINERS WITH FLOODING AMOUNTS OF
WATER UNTIL WELL AFTER FIRE IS OUT.
Unusual Fire/Explosion Hazard:GAS UNDER PRESSURE. CYLINDER MAY EXPLODE
IF EXPOSED TO FIRE OR HIGH TEMPERATURES.
* Accidental Release Measures *
Spill Release Procedures:TRY TO STOP LEAK IF IT CAN BE DONE AT NO RISK.
VENTILATE AREA. DISPELL VAPORS WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY AREA.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:G3
Spec Gravity:0.8
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, ODORLESS GAS OR LIQUID IN A CYLINDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
LITHIUM, MAGNESIUM, NEODYMIUM, OZONE, TITANIUM.
Stability Condition to Avoid:HIGH TEMPERATURES, OPEN FLAME.
Hazardous Decomposition Products:OXIDES OF NITROGEN
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT
BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES & PRESSURES.
* Disposal Considerations *
Waste Disposal Methods:CONTACT LOCAL ENVIRONMENTAL MANAGER. DISPOSE OF
IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APP RESP PROT FOR EXP OF CONCERN
Ventilation:LOCAL: OPEN WINDOW. MECH: FANS, MFG REC
Supplemental Safety and Health
* Product Identification *
CAGE:OBRN9
CAGE:OBRN9
* Composition/Information on Ingredients *
Ingred Name:ADDITIVES, .5-1%
* Hazards Identification *
Effects of Overexposure:DIZZINESS
* First Aid Measures *
First Aid:REMOVE TO FRESH AIR. SKIN & EYES: FLUSH W/WATER.
* Fire Fighting Measures *
Extinguishing Media:CO*2
* Accidental Release Measures *
Spill Release Procedures:WIPE UP
*Handling and Storage *
BECAUSE OF EXPANSION OF CONTAINER CONTENTS
Other Precautions:DO NOT FREEZE. DOT: COMBUSTIBLE.
* Physical/Chemical Properties *
HCC:F4
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IAW FED, STATE, LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:ASSURE THAT VENTILATION IS ADEQUATE.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:USE GOOD PERS & INDUS HYGIENE PRACTS.WASH THORO
AFTER USING PROD.KEEP PROD OFF OF CLTHG & EQUIP.LAUNDER CONTAMD
(SUPDAT)
Supplemental Safety and Health
ATTN IF BRTHG DFCLTY DEVELOPS.NOTES TO PHYS:CONT HAZ INFO SERVICES
FOR ASSIST W/MANAGEMENT OF EXPOS TO THIS PROD. HYGIENE PRACT:CL THG
BEFORE RE-USE. DO NOT EAT, DRINK, OR SMOKE IN ANY WORK AREA. IT IS
ALWAYS GOOD HYGIENE PRACT TO LIMIT, TO (ING 6)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PROPIONIC ACID, 2-METHYL-, MONOESTER WITH
2,2,4-TRIMETHYL-1,3--PENTANEDIOL;
(2,2,4-TRIMETHYL-1,3-PENTANEDIOL(ING 2)
Fraction by Wt: <5%
GRAM/KG.
Fraction by Wt: <5%
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:SUPP DATA: EXTENT FEASIBLE, SKIN AND EYE CONTACT AND
INHALATION OF CHEMICAL PRODUCTS.
Ingred Name:SPILL PROC:SPILLS INVOLVING MULTIPLE UNITS: RESP IF VENT IS
ADEQ, NO RESP PROT IS NEC.IF RESP IS DEEMED TO BE NEC(ING 8)
Ingred Name:ING 7:SEEK PROFESSIONAL ADVICE PRIOR TO RESP SELECTION &
Ingred Name:ING 8:IS POTNTL FOR UNCONTROLLED RELS, EXPOS LEVS ARE NOT
Ingred Name:ING 9: RESPIRATORS MAY NOT PROVIDE ADEQUATE PROTECTION, USE
A POSITIVE PRESSURE AIR SUPPLIED RESPIRATOR.
Ingred Name:EFTS OF OVEREXP:2,2,4-TRIMETHYL-1,3-PENTANEDIOL
2,2,4-TRIMETHYL-1,3-PENTANEDIOL MONOISOBUTYRATE IS OF LOW ORDER OF
COLORLESS, ODORLESS, WATER-SOLUBLE LIQ. BECAUSE OF IT'S LOW (ING
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: LOCAL EFFECTS (EYES, SKIN,
NOSE, THROAT, STOMACH, ETC.) MAY CAUSE SLIGHT IRRITATION TO THOSE
WITH SENSITIVE SKIN.THIS SECTION PROVIDES RELEVANT INFO W/REGARD TO
ANY TOX STUDIES PERFORMED ON PRO D,OR "PURE" FORM OF
COMPONENT(S).INFO CAN BE SUBJECT TO MISINTERPRETATION. ESSNTL (EFTS
OF OVEREXP)
Effects of Overexposure:HLTH HAZ:THAT FOLLOWING INFO BE INTERPRETED BY
INDIVS TRAINED IN ITS EVAL FOR ASSIST W/INTERPRETING INFO,CONT HAZ
HOURS-A-DAY. PROD BA SED: SKIN TESTING W/FORMULA SHOWED POTNTL FOR
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYE:IMMED FLUSH W/PLENTY OF WATER.REMOVE CONT LENSES &
& PERSISTS.SKIN: REMOVE CONTAMD CLTHG. FLUSH AFFECTED AREA W/WATER,
THEN WASH THORO W/MILD SOAP & WATER.SEEK MD ATTNIF IRRIT DEVELOPS
& PERSISTS.INGEST: WIPE OUT MOUTH & GIVE 1-2 GLASSES OF WATER.CONT
PHYS/POIS CNTRL CENTER. INHAL: REMOVE TO FRESH AIR IMMED.SEEK MD
* Fire Fighting Measures *
Flash Point Method:SCC
Flash Point:NONE TO BOILING
Extinguishing Media:USE MATERIAL COMPATIBLE WITH OTHER BURNING
MATERIAL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT LIKELY TO CONTRIBUTE TO A FIRE
HAZARD. HAZARDOUS COMBUSTION PRODUCTS: CARBON MONOXIDE, CARBON
DIOXIDE.
* Accidental Release Measures *
Spill Release Procedures:DO NOT ATTEMPT TO CLEAN UP CHEM SPILLS W/OUT
APPROP PERS PROT EQUIP. COLLECT SPILLED PROD & TRANSFER TO SEALABLE
CNTNR FOR REUSE/DISP. RINSE AREA & COLLECT WATER FOR DISP. KEEP
WASTE OUT OF SEWERS, WA TERSHEDS, & WATERWAYS. FOR CLEANING UP (ING
7)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
MATERIALS. USE WITH PROPER PERSONAL PROTECTIVE EQUIPMENT.
Other Precautions:EMPTY CNTNRS MAY RETAIN HAZ PROPERTIES, FOLLOW ALL
MSDS/LABEL WARNINGS EVEN AFTER CNTNR IS EMPTIED. DO NOT REUSE EMPTY
CONTAINER FOR FOOD, CLOTHING, OR PRODS FOR HUMAN OR ANIMAL
CONSUMPTION. KEEP THIS AND ALL CHEMS OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
Vapor Density:>1
Volatile Org Content %:9
pH:SUPDAT
Evaporation Rate & Reference:<1(N-BUTYL ACETATE=1)
Solubility in Water:DILUTABLE
Appearance and Odor:OPAQUE, VISCOUS LIQUID WITH SLIGHT AMMONIA ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS. DO NOT MIX WITH OTHER MATERIALS UNLESS
SPECIFIED ON THE LABEL.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:CONSULT LOCAL EXPERT FOR ADVICE ON THE DISPOSAL
OF THIS MATERIAL. CHARACTERISTICS OF RECOVERED MATERIAL MAY DIFFER
FROM THOSE OF ORIGINAL MATERIAL. ENSURE THAT DISPOSAL IS IN
COMPLIANCE WITH LOCAL, ST ATE AND FEDERAL REGULATIONS.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:PROVIDE LOCAL EXHAUST TO KEEP TLV INGREDIENTS BELOW
ACCEPTABLE LIMITS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:JOHN M. BIRSCH SR
* Composition/Information on Ingredients *
Ingred Name:GLYCOLS, POLYETHYLENE, MONO(P-NONYLPHENYL) ETHER; (NONIONIC
SURFACTANT)
Fraction by Wt: <4%
Ingred Name:ETHYL ALCOHOL; (ETHANOL)
Fraction by Wt: <0.5%
Ingred Name:SCENT
Fraction by Wt: <2%
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: PROLONGED OR REPEATED
CONTACT MAY CAUSE DERMATITIS. EYES: EYE IRRITANT. MAY CAUSE REDNESS
OR SWELLING. INHAL: NOT APPLICABLE. INGEST: MAY BE IRRITATING TO
MOUTH, THROAT & GI SYSTEM. VOMIT ING AND DIARRHEA EXPECTED WITH
LARGE DOSES.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:SKIN: FLUSH WITH WATER. SEEK MEDICAL ATTENTION IF IRRITATION
MINUTES, HOLDING LIDS OPEN. SEEK MEDICAL ATTENTION. INHAL: REMOVE
TO FRESH AI R. SUPPORT BRTHG (GIVE O*2/ARTF RESP) . INGEST: DILUTE
W/2 GLASSES OF WATER. SEEK MEDICAL ATTENTION IF SYMPTOMS PERSIST.
* Fire Fighting Measures *
Flash Point:ABOVE BOILING PT
Extinguishing Media:WATER, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:FLUSH WITH WATER INTO SEWER SYSTEM.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:DO NOT STACK OVER THREE HIGH.
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Vapor Pres:SAME
Vapor Density:>1
Spec Gravity:1
pH:8
Evaporation Rate & Reference:<1(WATER=1)
Solubility in Water:YES
Appearance and Odor:LIGHT RED LIQUID, SPRING/CLEAN SMELL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
DO NOT MIX WITH ANY OTHER CHEMICALS.
Stability Condition to Avoid:
Hazardous Decomposition Products:
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK.
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS
CLOTHING.
Supplemental Safety and Health
BY DGSC-STF.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:COBALT (SARA III)
OSHA PEL:0.1 MG/M3;AS CO
* Hazards Identification *
Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION.
LATENT EFFECTS:SOMATIC/GENETIC DAMAGE.
* First Aid Measures *
First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE
COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN
PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT
VICTIM(S) MAY BE CON TAMINATED.
* Fire Fighting Measures *
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD
BRTHG APP.
Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE
IN HEAT OF FIRE.
* Accidental Release Measures *
*Handling and Storage *
Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION.
PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN
AREA FOR RADIOACTIVE MATERIALS.
* Physical/Chemical Properties *
HCC:A2
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL
Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION;
FISSION PRODUCTS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH
DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS
NIOSH-RESPIRATOR SELECTION. USE MESA /OSHA RESPIRATOR WHEN CUTTING
& GRINDING
Ventilation:CHECK GOVERNEMENT STANDARDS OF EMISSION CONTROL.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. INDUSTRIAL TYPE
WORK CLOTHING AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. DO
NOT SMOKE.
Supplemental Safety and Health
DO NOT TAKE PROTECTIVE GEAR OR CLOTHING HOME THAT HAS BEEN EXPOSED TO
DUST.
* Product Identification *
Product ID:ASBESTOS FILLED SPIRAL WOUND GASKET
Preparer's Name:DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS, CHRYSOTILE
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.2 FIBERS/CC
Ingred Name:NON HAZARDOUS INGREDIENTS
Other REC Limits:NONE SPECIFIED
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE CITED
IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:DUST MAY CAUSE SKIN/EYE
IRRITATION. CHRONIC:OVEREXPOSURE TO ASBESTOS MAY LEAD TO NUMEROUS
RESPIRATORY PROBLEMS ASSOCIATED WITH ASBESTOSIS.
Explanation of Carcinogenicity:ASBESTOS IS A RECOGNIZED HUMAN
CARCINOGEN AND IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:ASBESTOSIS IS ASSOCIATED WITH SYMPTOMS OF
LABORED BREATHING, CHEST PAIN AND CHEST TIGHTNESS. SYMPTOMS ARE NOT
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF
RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. INHALATION:
REMOVE TO FRESH AIR.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL AS APPROPRIATE FOR SURROUNDINGS.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS. THIS MATERIAL
ITSELF IS NON-FLAMMABLE.
* Accidental Release Measures *
Spill Release Procedures:USE WET-MOP TECHNIQUES TO COLLECT
DUST/SHAVINGS. DO NOT USE PRESSURIZED AIR TO CLEAN. PLACE WASTE IN
DOT APPROVED CONTAINER FOR DISPOSAL.
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:AVOID CREATING AIRBORNE DUST. WET
SURFACES/ FLOORS BEFORE SWEEPING AND USE APPROPRIATE DUST MASK.
Other Precautions:AVOID CREATION OF PARTICULATE ASBESTOS.
* Physical/Chemical Properties *
HCC:T6
Solubility in Water:INSOLUBLE
Appearance and Odor:GASKET, BLACK TO GREY IN COLOR, NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:PHYSICAL DAMAGE.
Hazardous Decomposition Products:WILL NOT DECOMPOSE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS FOR PROPER ASBESTOS DISPOSAL.
ALL WASTE MATERIALS MUST BE SEALED AND BAGGED.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE ORGANIC VAPOR CANISTER/SUPPLIED AIR
RESPIRATORY PROTECTION WHEN TLV IS EXCEEDED.
Ventilation:ALL APPLICATION AREAS SHOULD PROVIDE SUFFICIENT MECHANICAL
VENT W/EXPLOSION PROOF EQUIP TO MAINTAIN EXPSR LVL BELW TLV
Work Hygienic Practices:PROTECTIVE CREAM WHERE SKIN CONTACT IS LIKELY
Supplemental Safety and Health
TO PREVENT REPEATED OR PROLONGED SKIN CONTACT WEAR IMPERVIOUS CLOTHING
AND BOOTSWASH HANDS BEFORE EATING OR USING THE WASHROOM. SMOKE IN
SMOKING AREA ONLY.
* Product Identification *
Preparer's Name:DOUGLAS KIER
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL (SARA III)
Fraction by Wt: <5%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:AMMONIA
Fraction by Wt: < 1%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Effects of Overexposure:INHL:HEALTH EFFECT FROM VAPORS/SPRAY MISTS IN
POORLY VENT AREAS MAY INCLUDE IRRITATION OF MUCOUS MEMBRANES OF THE
NOSE,THROAT & RESPIRATORY TRACT & SYMPTOMS OF HEADACHE & NAUSEA.
SKIN/EYE: PROLONGED E XPOSURE TO PRODUCT MAY CAUSE
IRRITATION.DIRECT CONTACT W/PRODUCT MAY RESULT IN EYE IRRITATION.
* First Aid Measures *
First Aid:INHL: REMOVE SUBJECT TO FRESH AIR. SKIN/EYE:
IRRITATION PERSISTS. REMOVE CONTAMINATED CLOTHING WASHSKIN W/SOAP
AND WATER, WASH CLOTHING BEF ORE REUSE. INGST: IF VICTIM IS
CONSCIOUSGIVE TWO GLASSES OF WATER TO DRINK/CALL PHYSICAN. DONOT
GIVE ANYTHING TO AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Extinguishing Media:PAINT WILL NOT BURN UNTIL WATER EVAPORATES. FOR
RESIDUAL SOLIDS USE: FOAM, ALCOHOL FOAM,CO2,DRY CHEMICAL,OR WATER
FOG
Fire Fighting Procedures:CLOSED CONTAINERS MAY EXPLODE IN EXTREME HEAT.
WATER MAY BE USED TO COOL UNRUPT URED CONTNRS.AVOID SPREADING
BURNING LIQ. W/WTR USED FOR COOLING PURPOSES.
Unusual Fire/Explosion Hazard:MATERIAL CAN SPLATTER IF TEMP EXCEEDS
BOILING PT.RESIDUAL SOLIDS ARE CAPABLE OF BURNING,GIVING OFF CARBON
MONOXIDE/DIOXIDE.BREATHING APPARATUS NEEDED TO PROTCT
* Accidental Release Measures *
Spill Release Procedures:RECOVER FREE LIQUID. PICK UP REMAINING LIQUID
W/ABSORBANT MATERIAL AND PLACE INTO CONTAINER FOR DISPOSAL. WASH
AREA W/WATER & DETERGENT. DONOT WASH INTO PUBLIC WATER SOURCE.
*Handling and Storage *
Handling and Storage Precautions:PRODUCT SHOULD BE STORED ROOM TEMP. TO
PROLONG STORAGE LIFE. KEEP FROM FREEZING. DONOT APPLY WHEN
Other Precautions:DONOT TAKE INTERNALLY. AVOID PROLONGED CONTACT WITH
SKIN/BREATHING OF SPRAY MISTCLOSE CONTAINER AFTER EACH USE.
* Physical/Chemical Properties *
Vapor Density:< AIR
Evaporation Rate & Reference:SLOWER THAN AIR
Solubility in Water:COMPLETE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NK
Hazardous Decomposition Products:WHEN PRODUCT IS HEATED MAY PRODUCE
FUMES THAT CONTAIN CARBONMONOXIDE/DIOXIDE.
Conditions to Avoid Polymerization:HIGH TEMPERATURES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL,STATE & LOCAL
REGULATION. BEFORE ATTEMPTING CLEAN UP. REFER TO HAZARD CAUTION
INFORMATION IN OTHER SECTION.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR FITTED POS PRESSR AIR SUPPLD RSPRTR
(RSPRTR MFR RECOMM FOR ISOCYANATE VAPOR/MIST). WEAR RSPRTR WHILE
MIX,SPRAY,UNTIL VAPOR/MIST GONE. FOLLOW RSPRTR MFR DIRECTIONS.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENT TO KEEP CONC BELOW
LOWEST TLV.RMV DECOMP PROD GENERATED WHEN WELDING,CUTTING,BRAZING
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER. AS REQUIRED
TO PREVENT SKIN CONTACT.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:METHYL ISOBUTYL KETONE (SOLVENT) (SARA III) (VAPOR
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
(LFL 1.7, UFL 7.6)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
(LFL 1.0, UFL 7.0)
Other REC Limits:NONE SPECIFIED
Ingred Name:ETHYL BENZENE (SOLVENT) (SARA III) (VAPOR PRESSURE 1 MM HG
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:SILICA, CRYSTALLINE - QUARTZ (PIGMENT)
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE (PIGMENT)
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
Ingred Name:SILICA, AMORPHOUS DIATOMACEOUS EARTH (PIGMENT)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:SILICA, CRYSTALLINE (PIGMENT)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
Ingred Name:CHROMIUM III OXIDE (PIGMENT)
Other REC Limits:NONE SPECIFIED
Ingred Name:DIBUTYL TIN DILAURATE (ADDITIVE)
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
Ingred Name:POLYMERIC HEXAMETHYLENE DIISOCYANATE (RESIN)
Other REC Limits:MFR: 1 MG/M3
Ingred Name:SOLVENT, NAPHTHA, LIGHT AROMATIC (SOLVENT)
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:1,6 HEXANE METHYLENE DIISOCYANATE (RESIN)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:ACUTE; INGEST:GI IRRIT,NAUSEA, VOMIT,
ASPIRATION INTO LUNGS MAY CAUSE CHEM PNEUMONITIS. INHAL: FLU LIKE
SYMPTOM.HARMFUL.LUNG DAMAGE.RESP SENSITIZATION,NOSE/THROAT
IRRIT.CENTRL NERV SYS DEPRESSION.(HEA
DACHE,DIZZINESS,NAUSEA,CONFUSION).EYE:SEVERE IRRIT.
SKIN:SENSITIZATION,ALLERGIC REACTION,DEFAT & IRRIT.
Explanation of Carcinogenicity:IARC: CRYSTALLINE SILICA: LIMITED
EVIDENCE OF CARCIOGENICITY IN HUMANS, SUFFICIENT EVIDENCE IN
ANIMALS (GROUP 2A).
Effects of Overexposure:CHRONIC; SILICOSIS (DISABLING LUNG DISEASE);
LIVER, KIDNEY, BLOOD INJURY. RESP SENSITIVITY: ASTHMA LIKE SYMPTOMS
AT LATER EXPOS BELOW TLV. PERMENANT CNS DAMAGE. CONC & INHAL
PRODUCT: HARMFUL/FATAL.
Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.
* First Aid Measures *
First Aid:INGEST: DONT INDUCE VOMIT. CALL POISON CNTRL CTR/EMERG
ROOM/DR IMMED. INHAL REMOVE TO FRESH AIR IMMED. IF BREATHING
STOPPED, GIVE ARTIF RESP. KEEP WARM & QUIET. EYE: FLUSH W/LRG AMT
CONTAM CLOTHES. WASH W/SOAP & WATER. GET MED AID IF IRRIT PERSISTS.
NOTES TO DR: DIRECT TREATMENT AT SYMPTOM CONTROL & CLINICAL
CONDITIONS.
* Fire Fighting Measures *
Lower Limits:1.0
Upper Limits:8.0
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS (CO2, ALL
PURPOSE DRY CHEM, ALCOHOL FOAM). POLYMER FOAM PREFERRED FOR LARGE
FIRES.
Fire Fighting Procedures:WEAR SCBA. WATER MAY BE INEFFECTIVE, USE TO
COOL (FOG NOZZLES PREFERRED) EXPOSED CNTNRS TO PREVENT PRESSURE
BLDUP, AUTOIGNIT, EXPLOSION WHEN EXPOSED TO HEAT.
Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMPOSITION PRODUCTS
MAY CAUSE HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.
OBTAIN MEDICAL ATTENTION. WARNING, FLAMMABLE.
* Accidental Release Measures *
RSPRTR,EYE,HAND &BODY PROTECTION.KEEP SPECTATORS AWAY.ELIM IGNIT
SOURCES.DIKE/CNTN W/INERT MAT'L. TRANSFR LIQ TO COVRD METAL
CNTNRS/REMV W/INERT ABSORB. USE NON-SPARK.P LACE ABSORB IN COVERED
METAL CNTNRS.
*Handling and Storage *
BREATH.DONT GET IN EYES,ON SKIN,CLOTHES.
Other Precautions:WASH AFTER HANDLING. KEEP FROM HEAT,IGNIT SOURCE.USE
ONLY W/VENT.EMPTY CNTNRS MUST NOT BE WASHED/REUSED FOR ANY
PURPOSE.GROUND/BOND CNTNRS TO RECEIVING CNTNRS.DONT WELD,BRAZE,CUT
ON EMPTY CNTNR. NEVER USE PRESSR TO EMPTY--NOT PRESSR VESSEL.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:> AIR
Spec Gravity:1.3
pH:4-7STD
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT IN WATER
Appearance and Odor:LIQUID, SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
OF IGNITION.
Hazardous Decomposition Products:COMBUSTION: OXIDES OF: NITROGEN,
CHROMIUM. CO2, CO. METAL OXIDES. REACTION: CO2 GAS (PRESSURIZE
CLOSED CNTNR).
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORD W/FED,STATE,LOCAL LAWS/REGS.
INCINERATE IN EPA PERMITTED FACILITY. DONT INCINERATE CLOSED
CNTNRS. OBSERVE PRECAUTIONS FOR DISPOSAL OF FLAMM MAT'L.DISPOSE OF
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NEEDED IN NORMAL USE/HANDLING.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT
Other Protective Equipment:EYE WASH & SAFETY SHOWER
Work Hygienic Practices:WASH HANDS BEFORE BATHING/DRINKING.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:AMMONIUM THIOSULFATE
Other REC Limits:NONE ESTABLISHED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE EYES/SKIN IRRITATION.
Effects of Overexposure:EYE:IRR;SKIN/INH:LOW HAZ FOR USUAL IND.HANDLING
* First Aid Measures *
First Aid:IN CASE OF EYE CONTACT,FLUSH W.PLENTY OF WATER
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARTUS &
PROCTCTIVE CLOTHING TO PREVENT CONTACT WITH SKIN 6 EYES.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO AN ACID-FREE SEWER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED WHEN
NOT IN USE;KEEP AWAY FROM ALKALI OR ACIDS.
Other Precautions:NONE
* Physical/Chemical Properties *
HCC:C1
Vapor Density:0.6
pH:5.7
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR PALE GREENISH-YELLOW SOLUTION,SLIGHT ACETIC
ACID ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & STRONG ALKALI
Stability Condition to Avoid:HEAT,HIGH TEMPERATURES
Hazardous Decomposition Products:AMMONIA,OXIDES OF CARBON & NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE,TREATMENT,OR DISPOSAL MAY BE SUBJECT
TO FEDERAL,STATE OR LOCAL LAWS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AIRBORNE CONCS SHOULD BE KEPT TO LOWEST LEVELS
POSS. IF VAP, MIST OR DUST IS GENERATED & OCCUP EXPOS LIM OF
PROD/ANY COMPONENT IS EXCEEDED, USE APPROP NIOSH/MSHA APPRVD AIR
PURIFYING OR AIR SUPPLIED R ESP AFTER DETERMINING AIRBORNE (ING 4)
Ventilation:ADEQUATE TO MEET OCCUPATIONAL EXPOSURE LIMITS.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WORKERS SHOULD WASH EXPOSED SKIN SEVERAL TIMES
DAILY W/SOAP & WATER. SOILED WORK CLTHG SHOULD BE
LAUNDERED/DRY-CLEANED.
Supplemental Safety and Health
EFTS OF OVEREXP: CHRONIC EXPOS. SOME LOW VISCOSITY NAPHTHENIC OILS HAVE
CAUSED SKIN IRRIT & SKIN TUMORS IN LAB ANIMALS WHEN REPEATEDLY
APPLIED & LEFT IN PLACE BETWEEN APPLICATIONS. SIGNIFICANCE OF THI S
EFT TO HUMANS HAS NOT BEEN ESTABLISHED.
* Product Identification *
CAGE:OTTJ3
CAGE:OTTJ3
* Composition/Information on Ingredients *
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, ACID-TREATED HEAVY
NAPHTHENIC (SEVERE SOLVENT-REFINING &/OR HYDROTREATMENT) (ING 2)
Ingred Name:ING 1: (ACID TREATED HEAVY NAPHTHENIC PETROLEUM
DISTILLATES)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MINERAL OIL, PETRO DISTILLATES, HYDROTREATED (SEV) LIGHT
NAPHTHENIC; (LIGHT NAPHTHENIC HYDROTREATED PETRO DISTILLATE)
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
Ingred Name:WASTE DISP METH: BECAUSE PROD USES, TRANSFORMATIONS,
MIXTURES, PROCESSES, ETC. MAY RENDER RESULTING MATLS HAZ.
Ingred Name:RESP PROT: CONC OF CONTAMINANT. NIOSH/MSHA APPRVD AIR
SUPPLIED RESPS SHOULD ALWAYS BE WORN WHEN AIRBORNE CONC (ING 6)
Ingred Name:ING 5: OF THE CONTAMINANT OR OXYGEN CONTENT IS UNKNOWN.
Ingred Name:OTHER PRECS: AVOID PRLNG BRTHG OF VAP, MIST OR GAS. MISUSE
OF EMPTY CNTNR CAN BE HAZ. EMPTY CNTNRS CAN BE HAZ (ING 8)
Ingred Name:ING 7: IF USED TO STORE TOXIC, FLAMM OR REACTIVE MATLS.
CUTTING/WELDING OF EMPTY CNTNRS MIGHT CAUSE FIRE, EXPLOS (ING 9)
Ingred Name:ING 8: OR TOXIC FUMES FROM RESIDUES. DO NOT PRESSURIZE OR
Ingred Name:ING 9: BUNGS IN PLACE.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE MINIMAL IRRIT,
EXPERIENCED AS TEMPORARY DISCOMFORT. SKIN: BRIEF CNTCT IS NOT
IRRIT. PRLNG CNTCT, AS W/CLTHG WETTED W/MATL, MAY CAUSE DEFAT OF
SKIN OR IRRIT SEEN AS LOC REDNESS W/POSS M ILD DISCOMFORT. INHAL:
VAPS/MIST IN EXCESS OF PERMISSIBLE CONCS OR IN UNUSUALLY HIGH CONCS
GENERATED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: FROM SPRAYING, HEATING MATL OR AS
FROM EXPOS IN POORLY VENT AREAS OR CONFINED SPACES MAY CAUSE IRRIT
OF NOSE & THROAT, HDCH, NAUS & DROW. INGEST: IF MORE THAN SEVERAL
MOUTHFULS ARE SWALLOWED , ABDOM DISCOMFORT, NAUS & DIARR MAY OCCUR.
CHRONIC: NO ADVERSE EFTS HAVE BEEN DOCUMENTED IN HUMANS AS RSLT OF
(SUPDAT)
Medical Cond Aggravated by Exposure:BECAUSE OF ITS DEFATTING
PROPERTIES, PROLONGED AND REPEATED SKIN CONTACT MAY AGGRAVATE AN
EXISTING DERMATITIS (SKIN CONDITION).
* First Aid Measures *
ATTN IF IRRIT PERSISTS. SKIN: WASH W/PLENTY OF SOAP & WATER FOR
SEVERAL MIN. GET MED ATTN IF IRRIT DEVELOPS/PERSISTS. INGEST:IF
MORE THAN SEVE RAL MOUTHFULS OF MATL SWALLOWED, GIVE 2GLASSES OF
OCCURS, REMOVE TO FRESH AIR. GET MED ATTN IF BRTHG BECOMES DFCLT OR
RESP IRRIT PERSISTS.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM OR CARBON
DIOXIDE TO EXTINGUISH FLAMES.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOS
CONTAINERS. WATER OR FOAM MAY CAUSE FROTHING.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. AVOID BRTHG VAP. WEAR APPROP
PERSONAL PROTECTIVE EQUIP, INCL APPROP RESP PROT. CNTN SPILL IF
POSS. WIPE UP OR ABSORB ON SUITABLE MATL & SHOVEL UP. PREVENT ENTRY
INTO SEWERS & WATERWAYS . AVOID CONTACT WITH SKIN, EYE OR CLOTHING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:MINIMUM FEASIBLE HANDLING TEMPS SHOULD
BE MAINTAINED. PERIODS OF EXPOSURE TO HIGH TEMP SHOULD BE
MINIMIZED. WASTE CONTAMINATION SHOULD BE AVOIDED.
Other Precautions:REMOVE & DRY-CLEAN/LAUNDER CLTHG SOAKED/SOILED W/THIS
MATL BEFORE REUSE. DRY CLEANING OF CONTAMD CLTHG MAY BE MORE EFTIVE
THAN NORM LAUNDERING. INFORM INDIVIDUALS RESPONSIBLE FOR CLEANING
OF POTNTL HA ZS ASSOC W/HNDLG CONTAMD CLTHG. (ING 7)
* Physical/Chemical Properties *
Appearance and Odor:CLEAR YELLOW LIQUID; BLAND ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE,
CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES.
* Disposal Considerations *
Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . PROD
HAS BEEN EVALUATED FOR RCRA CHARACTS IN PURCHASED FORM. UNDER RCRA,
IT IS RESPONSIBILITY OF PROD USER TO DETERM AT TIME OF DISP WHETHER
PROD MEETSRCRA CRITERIA FOR HAZ WASTE. THIS IS (ING 3)
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* Exposure Controls/Personal Protection *
Respiratory Protection:FULL FACEPIECE, SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:LOCAL EXHAUST, MUST COMPLY WITH REGULATIONS.
Other Protective Equipment:COVERALLS WITH LONG SLEEVES MADE OF
MATERIALS RESISTANT TO PRODUCT.
SURVEILLANCE REQUIREMENTS.
Supplemental Safety and Health
FORMALDEHYDE REACTS WITH HYDROCHLORIC ACID TO FORM THE POTENT
CARCINOGEN, BIS-CHLOROMETHYL ETHER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:FORMALDEHYDE
Minumum % Wt:8.
Ingred Name:METHYL ALCOHOL
Maxumum % Wt:1.
Ingred Name:ACETIC ACID
Minumum % Wt:4.5
Maxumum % Wt:5.
Ingred Name:PICRIC ACID
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.1 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:STRONGLY IRRITATING TO SKIN, EYES,
RESPIRATORY TRACT & MUCOUS MEMBRANES. MAY CAUSE ALLERGIC REACTIONS.
MAY CAUSE PERMANENT EYE DAMAGE. INHALATION (BREATHING): HARMFUL IF
INHALED. SKIN CONTACT: HARMFUL IF ABSORBED THROUGH SKIN CAUSED
GENERAL TISSUE DAMAGE. EYE CONTACT: CAUSES EYE BURNS. INGESTION
(SWALLOWED): FATAL OR MAY CAUSE BLINDNESS.
Explanation of Carcinogenicity:LISTED AS A CARCINOGEN ON THE FOLLOWING:
IARC, NTP, OSHA, ACGIH.
Effects of Overexposure:IRRITATION OF SKIN, EYES, RESPIRATORY TRACT,
AND MUCOUS MEMBRANES FROM FUMES. INGESTION CAUSES SEVERE
GASTROINTESTINAL SYMPTOMS.
Medical Cond Aggravated by Exposure:RESPIRATORY AILMENTS, SKIN
CONDITIONS, EYE CONDITIONS.
* First Aid Measures *
MINS), CALL A PHYSICIAN. SKIN CONTACT-FLUSH SKIN IMMEDIATELY WITH
PHYSICIAN.INHALATION-MOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT USE OXYGEN.
INGESTION-DRINK TWO GLASSES OF WATER IMMEDIATELY AND INDUCE
VOMITING, GIVE ACTIVATED CHARCOAL SLURRY. CALL PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:7.0
Extinguishing Media:FOAM, WATER SPRAY, CARBON DIOXIDE, OR DRY CHEMICAL.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE. WEAR PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:FORMS HAZARDOUS FUMES, CARBON MONOXIDE,
CARBON DIOXIDE. EVACUATE AFFECTED AREA. COOL CONTAINER WITH WATER
SPRAY TO ABSORB ESCAPING FUMES.
* Accidental Release Measures *
Spill Release Procedures:SOAK UP SMALL SPILLS WITH EARTH, SAND, OR
OTHER NONCOMBUSTIBLE ABSORBENT MATERIAL & REMOVE IN COVERED METAL
CONTAINERS. DIKE LARGE SPILLS & NEUTRALIZE WITH DILUTE (5%)
SOLUTIONS OF AMMONIA, SODIUM SUL FITE, OR SODIUM BISULFITE &
REMOVE. FLUSH AREA WITH PLENTY OF WATER. COMPLY WITH FEDERAL, STATE
AND LOCAL REGULATIONS ON REPORTING RELEASES.
Neutralizing Agent:DILUTE (5%) SOLUTIONS OF AMMONIA, SODIUM SULFITE, OR
SODIUM BISULFITE.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
HEAT AND FLAME. STORE IN A HEATED TANK OR WARM RROMN, ABOVE MINIMUM
STORAGE TEMPERATURE FOR GRADE HANDLED.
* Physical/Chemical Properties *
HCC:C2
Vapor Density:1.0
Evaporation Rate & Reference:>1
Solubility in Water:COMPLETE.
Appearance and Odor:CLEAR LIQUID WITH STRONG, PUNGENT ODOR.
* Stability and Reactivity Data *
STRONG OXIDIZING AGENTS, CAUSTICS, STRONG ALKALIS, ISOCYANATES,
ANHYDRIDES, OXIDES, AND INORGANIC ACIDS.
Stability Condition to Avoid:STORAGE AT HIGH TEMPERATURES.
Hazardous Decomposition Products:FORMALDEHYDE REACTS WITH NITROGEN
DIOXIDE, NITROMETHANE, PERCHLORIC ACID & ANILINE OR PEROXYFORMIC
ACID TO YIELD EXPLOSIVE COMPOUNDS. A VIOLENT REACTION OCCURS WHEN
FORMALDEHYDE IS MIXED WITH STRONG OX
* Toxicological Information*
* Disposal Considerations *
Waste Disposal Methods:CONSULT LOCAL, STATE & FEDRAL AUTHORITIES FOR
PROPER DISPOSAL METHODS.
* MSDS Transport Information *
FORMALDEHYDE. PLACARD: 8, CORROSIVE.
* Regulatory Information *
SARA Title III Information:SARA TITLE III-IN COMPLIANCE WITH SECTION
PRESENT-FORMALDEHYDE.
Federal Regulatory Information:"REPORTABLE QUANTITY" (RQ) TO NATIONAL
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT KEEP INHALATION
EXPOSURES BELOW PEL/TLV, USE NIOSH/MSHA APPROVED RESPIRATORS AS PER
Ventilation:PROVIDE SUFFICIENT GENERAL/LOCAL EXHAUST VENTILATION IN
PATTERN/VOLUME TO CONTROL INHALATION EXPOSURES BELOW PEL/TLV.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER & ACID
RESISTANT CLOTHING TO MINIMIZE EXPOSURE FOR TASK AT HAND.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE GUIDELINES &
RECOMMENDED PROCEDURES SET FORTH BY SAFETY OFFICE & OPERATION TECH
MANUAL.
Supplemental Safety and Health
DO NOT GET ON SKIN, OR IN EYES!
* Product Identification *
Kit Part:Y
Preparer's Name:JCS
* Composition/Information on Ingredients *
Ingred Name:SULFURIC ACID (SARA III)
OSHA PEL:1 MG/M3
Ingred Name:CHROMIC ACID (SARA III)
Fraction by Wt: 5%.
OSHA PEL:0.1 MG CRO3/M3;CEILG
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: CORROSIVE TO TISSUE, W/ SEVERE
BURNS TO EYES, SKIN, RESPIRATORY TRACT. CHRONIC:KIDNEY DAMAGE MAY
OCCUR W/ REPEATED OR PROLONGED EXPOSURE.
Explanation of Carcinogenicity:CHROMIUM(HEXAVALENT); NTP:HUMAN
CARCINOGEN; IARC:HUMAN CARCINOGEN(GROUP 1) ALSO ON CALIFORNIA LIST
OF CARCINOGENS.
Effects of Overexposure:EYES:SEVERE IRRITATION, BURNS, PERMANENT
DAMAGE; SKIN: CORROSIVE, BURNS, CHROME SORES, MASSIVE ABSORPTION
MAY CAUSE KIDNEY FAILURE; INHAL:RESPIRATORY MUCOUS MEMBRANE
IRRITATION. EXCESSIVE INHALATION M AY CAUSE LOSS OF CONSCIOUSNESS;
INGEST:TISSUE DESTRUCTION & KIDNEY FAILURE.
Medical Cond Aggravated by Exposure:NO INFORMATION PROVIDED;
RESPIRATORY AND/OR SKIN DISORDERS .
* First Aid Measures *
MED. ATTN.; SKIN: FLUSH AFFECTED AREA W/ WATER & GET MED ATTN;
INHAL: REMOVE TO FRESH AIR, IF NOT BREATHING,GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MED ATTN
AS REQUIRED; INGEST: IRRIGATE MOUTH W/ WATER. GIVE MILK OR WATER TO
DRINK. DONOT INDUCE VOMITING. GET MEDICAL ATTN.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER.
Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE COMPLETE
PERSONAL PROTECTION.
Unusual Fire/Explosion Hazard:YIELDS A POISONOUS GAS.
* Accidental Release Measures *
Spill Release Procedures:DILUTE W/ WATER, NEUTRALIZE W/ SODIUM
CARBONATE OR SODA ASH.
Neutralizing Agent:SODIUM CARBONATE OR SODA ASH.
*Handling and Storage *
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
A COOL,DRY AREA. KEEP AWAY FROM OXIDIZABLE MATERIALS.
Other Precautions:PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS
* Physical/Chemical Properties *
HCC:C1
Spec Gravity:1.1
pH:<1.
Solubility in Water:COMPLETE
Appearance and Odor:THICK RED LIQUID W/ A STRONG ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
METALS, HYDROCARBONS, SOLVENTS, WOOD, PAPER.
Stability Condition to Avoid:MFR PROVIDES NONE!
Hazardous Decomposition Products:OXIDES OF SULFUR, CHROMIUM COMPOUNDS.
* Disposal Considerations *
I/A/W FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NON REQUIRED IF VENTILATION IS ADEQUATE.
Ventilation:ADEQUATE GENERAL/LOCAL EXHAUST. USE INSIDE A LAB HOOD.
Other Protective Equipment:EYE WASH STATIONS, DELUGE SHOWERS, LAB COAT.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SPILLS: UPON COMPLETION OF OBSERVE APPROPRIATE CHEMICAL HYGIENE. CLEAN
UP, WASH SITE W/WATER. PH: REAGENT: 2.
* Product Identification *
Kit Part:Y
Preparer's Name:MICHAEL A FAZIO
* Composition/Information on Ingredients *
Ingred Name:HYDROCHLORIC ACID, HYDROGEN CHLORIDE, MURIATIC ACID
HYDROCHLORIDE
Other REC Limits:7 PPM
OSHA PEL:5 PPM
Ingred Name:DETERGENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTAINS DETERGENT & HYDROCHLORIC
ACID, BOTH MAY BE CONSIDERED IRRITATING TO EXPOSED AREAS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:CONTAINS DETERGENT & HYDROCHLORIC ACID, BOTH
MAY BE CONSIDERED IRRITATING TO EXPOSED AREAS.
Medical Cond Aggravated by Exposure:NONE
* First Aid Measures *
QUIET. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NEEDED.
OBTA IN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:USE MEDIA SPECIFIC FOR SITE CONDITIONS.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE GARMENTS. IF POSSIBLE,
HAVE THIS PRODUCT REMOVED FROM THE SCENE.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. IF DRY, MOP UP, PLACE IN A
SUITABLE CONTAINER, SEAL, LABEL & HOLD FOR DISPOSAL. SOLUTION: USE
AN ABSORBENT MATERIAL TO CONTAIN/PICKUP. ONCE SPENT, PLACE
CONTAMINATED DISPOSABLE INTO A SUITABLE CONTAINER/SEAL/LABEL &
HOLD FOR DISPOSAL.
*Handling and Storage *
Other Precautions:AVOID CONTACT W/SKIN/EYES. DON'T EAT, DRINK/SMOKE
WHILE WORKING W/REAGENTS. DON'T MOUTH PIPETTE.
* Physical/Chemical Properties *
pH:(SUPP)
Solubility in Water:COMPLETE (REAGENT)
Appearance and Odor:CLEAR COLORLESS LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:EXCESS HEAT, FLAME, PRESSURE.
Hazardous Decomposition Products:COTAINS DETERGENT & HYDROCHLORIC ACID.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED ACID GAS CHEMICAL CARTRIDGE
RESPIRATOR OR FULL FACE RESPIRATOR WITH CANISTER. FOR UNKNOWN
CONCENTRATIONS, USE SCBA.
Ventilation:LOCAL EXHAUST:SHOULD BE USED WHENEVER POSSIBLE TO REMOVE
IRRITATING FUMES.
Other Protective Equipment:RUBBER BOOTS & RAIN SUIT TO AVOID SKIN
CNTCT. EMERGENCY EYE BATH & DELUGE SHOWER MEETING ANSI DESIGN
STANDARDS .
Work Hygienic Practices:WASH EQUIPMENT WITH SOAP & WATER FOLLOWING USE.
REMOVE & WASH ANY CLOTHING WHICH HAS BEEN IN CONTACT WITH PRODUCT.
Supplemental Safety and Health
* Product Identification *
Product ID:SODIUM HYPOCHLORITE WHILCHLOR II
* Composition/Information on Ingredients *
Ingred Name:SODIUM HYPOCHLORITE (SARA III)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SODIUM HYDROXIDE (SARA III)
Fraction by Wt: 0.2-2.0%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3, C
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SODIUM CHLORIDE
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:CAUSES SEVERE IRRIT AND REDDENING
OF SKIN. EYE CONTACT:CAUSES SEVERE IRRITATION. INHALATION:CAUSES
COUGHING AND IRRITATION OF THE RESPIRATORY TRACT. INGEST:CAN CAUSE
CORROSION OF MUCOUS MEMBRANES , PERFORATION OF ESOPHAGUS AND
STOMACH,LARYNGEAL EDEMA; MAY LEAD TO CONVULSION, COMA AND DEATH.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:ACUTE/CHRONIC: SEVERE IRRITATANT TO
SKIN, EYES, THROAT AND GI TRACT. CHRONIC:CORROSIVE TO SKIN, EYES,
ESOPHAGUS, STOMACH. CAN LEAD TO CONVULSION, COMA AND DEATH.
Medical Cond Aggravated by Exposure:NORMALLY NONE BUT VAPORS MAY
AGGRAVATE RESPIRATORY AILMENTS.
* First Aid Measures *
ATTENTION. SKIN:REMOVE CONTAMINATED CLOTHING AND WASH WITH SOAP AND
WATER. IF SKIN IS BURNED, CALL PHYSICIAN. LAUNDER CLOTHES BEFORE
REUSE. I NHAL:REMOVE TO FRESH AIR. CALL A PHYSICIAN IF BREATHING IS
DIFFICULT. INGEST:RINSE MOUTH WITH WATER. DRINK LARGE QUANTITIES OF
MILK OR WATER. DO NOT INDUCE VOMITING. CALL A PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE .
KEEP MATERIAL COOL USING A WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . AVOID INHAL OF FUMES AND BODY CONTACT.
Unusual Fire/Explosion Hazard:MANY REACTIONS CAN CAUSE FIRE & EXPLOS.
REACTS VIGOROUSLY WITH OXIDIZABLE MATLS. TOX FUMES CAN BE LIBERATED
BY HEAT. WILL REACT W/SOME METALS TO RELEASE OXYGEN.
* Accidental Release Measures *
Spill Release Procedures:TOXIC TO FISH AND AQUATIC LIFE. KEEP SPILLS
FROM ENTERING SEWERS, STREAMS, STORM DRAINS. PERSONNEL INVOLVED IN
THE CLEANUP MUST WEAR NIOSH/MSHA APPROVED RESPIRATORY
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT USE COMBUSTIBLE MATERIALS FOR
DIKING OR AS AN ABSORBENT.
Other Precautions:DO NOT USE CLEANING AGENTS CONTAINING ACIDS OR
AMMONIA IN CLEANUP OF SPILLS.
* Physical/Chemical Properties *
HCC:C2
Vapor Pres:SUPP DATA
Spec Gravity:SUPP DATA
pH:SUPDAT
Evaporation Rate & Reference:1 (WATER=1.0)
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT YELLOW TO GREEN LIQUID WITH CHARACTERISTIC
CHLORINE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, AMMONIA, METALS (NICKEL, COBALT, COPPER, ALUMINUM AND IRON),
OXIDIZABLE MATERIALS, AND CHLORINATED ISOCYANURATES
Stability Condition to Avoid:EXCESSIVE EXPOSURE TO HEAT AND LIGHT.
Hazardous Decomposition Products:CHLORINE, HYDROCHLORIC ACID;
HYPOCHLOROUS ACID, AND OXYGEN.
* Disposal Considerations *
Waste Disposal Methods:CONTAIN SPILLS IN AS SMALL AN AREA AS POSSIBLE
FOR DILUTION AND NEUTRALIZATION. USE OF PLASTIC DRUMS FOR
CONTAINMENT IS RECOMMENDED. DISPOSE OF IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS.
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* Exposure Controls/Personal Protection *
Ventilation:NORMAL ROOM
Supplemental Safety and Health
* Product Identification *
Product ID:CEE BEE ADDITIVE GO-2L
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
* First Aid Measures *
First Aid:EYES/SKIN: FLUSH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Flash Point Method:TCC
Flash Point:NONE
* Accidental Release Measures *
Spill Release Procedures:MOP UP/FLUSH TO SEWER W/PLENTY OF WATER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY AREA.
* Physical/Chemical Properties *
Vapor Pres:AS WATER
Vapor Density:AS WATER
pH:6-8
Evaporation Rate & Reference:(WATER = 1): 1
Solubility in Water:COMPLETE
Appearance and Odor:WHITE TO AMBER LIQUID W/NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING & REDUCING AGENTS
* Disposal Considerations *
Waste Disposal Methods:FLUSH TO SEWER W/PLENTY OF WATER. DISPOSE OF IN
ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AIRBORNE CONC SHOULD BE KEPT TO LOWEST LEVEL
POSSIBLE.VAP/MIST/DUST GENERATED & OCCUPATIONAL EXPO LIMIT OF PROD
OR ANY COMPO IS EXCEEDED USE APPROPRIATE NIOSH/MSHA APPROV AIR
PURIFYING OR AIR SUPPLIED RESP AFT DETERMINING AIRBORNE CONC OF
CONTAMINANT.AIR SUPPLIED RESP SHOULD ALWAYS BE WORN WHEN AIRBORNE
CONC OF CONTAMINANT OR OXY CONTENT IS UNK.
Ventilation:LOC EXHAU VENTI RECOMMENDED IF GENERATING VAP/DUST/MIST.IF
EXHAU VENTI NOT AVAI OR INADEQUATE USE MSHA/NIOSH APPROV RESP AS
APPROPRIATE.
Work Hygienic Practices:WORKERS SHOULD WASH EXPOSED SKIN SEVERAL TIMES
DAILY WITH SOAP & WATER. SOILED WORK CLOTHING SHOULD BE LAUNDERED
OR DRY-CLEANED.
Supplemental Safety and Health
* Product Identification *
Product ID:REUSABLE HOT/COLD GEL PACK
Preparer's Name:COORDINATOR, PRODUCT SAFE
* Composition/Information on Ingredients *
Ingred Name:1,2-PROPANEDIOL
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CAUTION!ASPIRATION HAZ IF INGESTED.CAN
ENTER LUNGS&CAUSE DMG.ACUTE:MAY CAUSE MINIMAL EYE IRRIT,
EXPERIENCED AS TEMP DISCOMFT.BRIEF SKIN CONTACT NOT IRRIT.PROLONGED
CONTACT MAY CAUSE DEFFATING /SKIN/IR RIT SEEN AS LOC RED W/POSSIBLE
MILD DISCOMFT.VAP/MIST INHAL IN EXCESS OF PERMISSIBLE CONC OR
UNUSUALLY HI CONC GENERATED FRM SPRAY,HEATING,EXPO IN POORLY VENTI
AREA/CONF SPACE MAY CAUSE NOSE&THROAT IR RIT,HEAD,NAU,DROWS.IF MORE
THAN SEVERAL MOUTHFULS INGESTED ABD DICOMFT,NAU,DIARR MAY
OCCUR.ASPIRATION MAY OCCUR DURING INGEST/VOMIT RESULTING IN LUNG
DMG.CHRONIC:NO ADVERSE EFFECTS HAVE BEEN DOCUMENTE D IN HUMANS AS A
RESULT OF CHRONIC EXPO.
Explanation of Carcinogenicity:PRODUCT &/OR COMPONENT(S) CARCINOGENIC
ACCORDING TO:NONE.
Effects of Overexposure:EYE:IRRIT,TEMPORARY DISCOMFORT. SKIN:DEFATTING,
SKIN OR IRRITATION, LOCAL REDNESS WITH POSSIBLE MILD DISCOMFORT.
NOSE & THROAT IRRIT, HEADACHE, NAUSEA, DROWSINESS. ABDOMINAL
DISCOMFORT, NAUSEA, DIARRH EA. ASPIRATION MAY OCCUR RESULTING IN
LUNG DAMAGE.
Medical Cond Aggravated by Exposure:THERE IS NO EVIDENCE THAT THIS
PRODUCT AGGRAVATES AN EXISTING MEDICAL CONDIITON.
* First Aid Measures *
First Aid:FLUSH EYES W/LOTS OF H2O FOR SEVERAL MINS.IRRIT PERSISTS GET
MED ATTN.WASH SKIN W/LOTS OF SOAP/H2O FOR SEVERAL MINS.IRRIT
DVLPS/PERSISTS GET MED ATTN.IF CONSCIOUS & CAN SWALLOW GIVE 2
GLASSES OF H2O(1 6OZ) BUT DON'T INDUCE VOMIT.IF VOMIT OCCURS GIVE
FLUIDS AGAIN.HAVE MED PERSON DETERMINE IF EVACUATION OF STOMACH OR
INDUCTION OF VOMTING IS NECESSARY.DON?T GIVE ANYTHING BY MOUTH IF
UNCONSC/CONVULS.IN HAL:IRRIT,HEAD,NAU,DROWS OCCURS MOVE TO FRESH
AIR.BREATH BECOMES DIFFICULT/RESP IRRIT PERSISTS GET MED
ATTN.PRODUCT ASPIRATION DURING INDUCED EMESIS MAY RESULT IN SEVERE
LUNG INJURY.(CONTD OTHER INFO)
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:2.6
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, FOAM, OR CARBON
DIOXIDE TO EXTINGUISH FLAMES. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS. WATER OR FOAM MAY CAUSE FROTHING.
Fire Fighting Procedures:NO SPECIAL EQUIPMENT OR PROCEDURES REQUIRED.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL IF POSSIBLE,CONTAINS WITH
ABSORBENT MATERIALS SUCH AS CLAY OR SOIL, AND SHOVEL UP. AVOID SKIN
AND EYE CONTACT.
*Handling and Storage *
Handling and Storage Precautions:PRECAUTIONS TO BE TAKEN IN
HANDLING:MINIMUM FEASIBLE HANDLING TEMPERATURES SHOULD BE
MAINTAINED. STORAGE:PERIODS OF EXPOSURE TO HIGH TEMPERATURES SHOULD
BE MINIMIZED.WATER CONTAMINATION SHOULD BE AVOI DED.
* Physical/Chemical Properties *
HCC:N1
Vapor Pres:<1
Vapor Density:2.6
pH:8
Appearance and Odor:COLORLESS MOBILE LIQUID, MILD ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE,
CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES.
* Toxicological Information*
Toxicological Information:INHALATION:BELIEVED TO BE PRACTICALLY
NON-TOXIC.IRRITATIONG INDEX ESTIMATION OF IRRITATION
APPRECIABLE EFFECT.SENSITIZATION:NOT DETERMINED.OTHER:NONE.
* Ecological Information *
DETERMIEND. PERSISTENCE & BIODEGRADABILITY:THIS PRODUCT IS REPORTED
BIODEGRADATION.POTENTIAL TO BIOACCUMULATE:THIS PRODUCT IS REPROTED
TO HAVE LOW POTENTIAL TO BIOCONCENTRATE.
* Disposal Considerations *
Waste Disposal Methods:PROD HAS BEEN EVALUATED FOR RCRA CHARACTERISTICS
& DOESN'T MEET CRITERIA OF HAZ WASTE IF DISCARDED IN ITS PURCHASED
FORM.UNDER RCRA IT?S RESPONSIBILITY OF THE USER OF PROD TO
DETERMINE @TIME OF DISPO WHETHER PROD MEETS RCRA CRITERIA FOR HAZ
WASTE.THIS IS BECAUSE PROD USES,TRANSFORMATIONS,MIXTURES,PR
OCESSES,ETC MAY RENDER THE RESULTING MATLS HAZ.
* MSDS Transport Information *
Transport Information:DOT/IMDG/ICAO/TDG:NOT REGULATED.
* Regulatory Information *
SARA Title III Information:SARA & CERCLA NONE.
Federal Regulatory Information:PRODUCT & COMPONENTS ARE LISTED ON OR
ARE EXEMPT FROM TSCA INVENTORY. THIS PRODUCT IS CURRENTLY ON THE
FDA'S CRAS (GENERALLY REGARDED AS SAFE) LIST.
State Regulatory Information:STATE RIGHT TO KNOW
REGULATIONS:1,2-PROPANEDIOL LISTED IN PA & RI.
* Other Information *
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* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY REQUIRED
Other Protective Equipment:ACID TYPE SUIT
Supplemental Safety and Health
BATTERY CONTAINS POTASSIUM HYDROXIDE ELECTROLYTE
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
OSHA PEL:C, 2 MG/M3
* Hazards Identification *
Effects of Overexposure:CORROSIVE TO SKIN AND MUCOUS MEMBRANES.CAUSES
SEVERE AND RAPID BURNS
* First Aid Measures *
First Aid:REMOVE FROM SKIN AS SOON AS POSSIBLE. WASH AFFECTED AREA WITH
* Fire Fighting Measures *
Flash Point:NONE
* Accidental Release Measures *
Spill Release Procedures:DILUTE AND WASH AWAY WITH LARGE AMOUNTS OF
WATER.CAN BE NEUTRALIZED WITH ACID AFTER DILUTING
*Handling and Storage *
MANUAL SHEET TC-3
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:VISCOUS,WATER WHITE LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACID
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL FEDERAL,STATE, AN
LOCAL REGULATIONS
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:THIS CHEM SHOULD BE HANDLED ONLY IN A HOOD.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
TUMORS. EFTS OF OVEREXP:HLTH EFTS. NARCOTIC @ HIGH CONC. FIRST AID
PROC:ASSISTANCE HAS ARRIVED. REMOVE & WASH CONTAMD CLTHG. IF PATI
ENT IS EXHIBITING SIGNS OF SHOCK-KEEP WARM & QUIET. CONT POIS CTL
CTR IMMED IF NEC. DO NOT ADMIN LIQ/INDUCE (ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE, TETRACHLORO-; (TETRACHLOROETHYLENE) (SARA III)
Ingred Name:SUPDAT:VOMIT TO AN UNCON/CONVULSING PERSON. IF PATIENT IS
VOMIT-WATCH CLOSELY TO MAKE SURE AIRWAY DOES NOT (ING 3)
Ingred Name:ING 2:BECOME OBSTRUCTED BY VOMIT. GET MED ATTN IF NEC. AN
ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF (ING 4)
Ingred Name:ING 3:POISON. IT SHOULD BE ADMIN ONLY BY PHYS/TRAINED EMER
PERS. MED ADVICE CAN BE OBTAINED FROM POIS CTL CTR.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CONT LENSES SHOULD NOT BE WORN IN LAB.
ALL CHEM SHOULD BE CONSIDERED HAZ. AVOID DIRECT PHYSICAL CONTACT!
SUSPECTED CARCINOGEN - MAY PRODUCE CANCER. CAN CAUSE EYE IRRIT. CAN
CAUSE SKIN IRRIT. DUST AND/ OR VAPORS CAN CAUSE IRRIT TO RESP
TRACT. CAN BE IRRITATING TO MUCOUS MEMBRANES. MAY BE HARMFUL IF
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:TETRACHLOROETHYLENE:IARC MONOGRAPHS,
(SUPDAT)
Effects of Overexposure:HLTH HAZ:ABSORB THRU SKIN. MAY BE HARMFUL IF
INHALED OR SWALLOWED. PRLNGD EXPOS MAY CAUSE NAUS/HDCH/DIZZ AND/OR
EYE DMG. EXPOS CAN CAUSE LIVER DMG. EXPOS CAN CAUSE KIDNEY DMG.
AVOID CONSUMPTION OF ALC OHOL BEFORE & AFTER HNDLG OF THIS CMPD
BECAUSE IT WILL INCREASE TOX OF CMPD. CAN CAUSE DELAYED ADVERSE
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMEDIATELY . EYES:FLUSH CONTINUOUSLY W/WATER
OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL:REMOVE PATIENT TO
FRESH AIR. ADMIN OXYG IF PATIENT IS HAVING DFCLTY BRTHG. IF PATIENT
HAS STOPPED BRTHG ADMIN ARTF RESP. IF PATIENT IS IN CARDIAC ARREST
ADMIN CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL MED (SUPDAT)
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:NO FIRE OR EXPLOSION. MEDIA SUITABLE FOR
SURROUNDING FIRE CONDITIONS .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NO EXPLOSION LIMITS ARE AVAIL FOR THIS
COMPOUND.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. WEAR APPROP OSHA REGULATED
EQUIP. VENTILATE AREA. ABSORB ON VERMICULITE/SIMILAR MATL. SWEEP UP
& PLACE IN AN APPROP CNTNR. HOLD FOR DISP. WASH CONTAMD SURF TO
REMOVE ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:EYE SHIELDS SHOULD BE WORN. USE APPROP
OSHA/MSHA APPRVD SFTY EQUIP. STORE ONLY W/COMPATIBLE CHEMICALS.
Other Precautions:AVOID CONT W/SKIN, EYES AND CLTHG. KEEP TIGHTLY CLSD
IN COOL DRY PLACE.
* Physical/Chemical Properties *
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:VERY SLIGHT SOLUBLE
Appearance and Odor:COLORLESS LIQUID, ETHER LIKE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG BASES. DECOMPOSITION LIBERATES TOX FUMES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMPOSITION PRODUCTS ARE CORROSIVE.
EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Disposal Considerations *
Waste Disposal Methods:BURN IN A CHEM INCIN EQUIPPED W/AN AFTERBURNER &
SCRUBBER. DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL REGULATIONS
.
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* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED. IF WORKPLACE EXPOSURE
LIMIT IS EXCEEDED, A NIOSH APPROVED AIR SUPPLIED RESPIRATOR OR DUST
RESPIRATOR IS ADVISED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER
Work Hygienic Practices:SHOWER AT THE END OF WORK DAY. WASH WORK
CLOTHES SEPARATELY AND WIPE OUT WASHER AT THE END OF CYCLE.
Supplemental Safety and Health
* Product Identification *
Product ID:CHOPPED STRAND MAT,CONTINOUS STRAND MAT,BI-
* Composition/Information on Ingredients *
Ingred Name:GLASS, FIBROUS
Other REC Limits:3MIL FIBERS/M3,NIOSH
Ingred Name:POLYESTER
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE- THE FIBERS FROM THIS PRODUCT
ARE MECHANICAL IRRITANTS & MAY CAUSE TRANSITORY IRRITATION TO
EXPOSED AREAS SUCH AS EYES, SKIN & UPPER RESPIRATORY TRACTS.
CHRONIC-ANIMAL INHALATION STUDIES HAVE NO T SHOWN ANY IRREVERSIBLE
DISEASE EFFECTS RELATED TO FIBER GLASS EXPOSURE. MAY INCREASE THE
RATE OF LUNG CANCER.
Explanation of Carcinogenicity:ARTIFICIAL IMPLANTATION/INJECTION OF
FINE GLASS FIBERS INTO THE CHEST OF LABORATORY ANIMALS HAS PRODUCED
CANCER (MSDS).
Effects of Overexposure:THE FIBERS FROM THIS PRODUCT ARE MECHANICAL
IRRITANTS & MAY CAUSE TRANSITORY IRRITATION TO EXPOSED AREAS SUCH
AS EYES, SKIN & UPPER RESPIRATORY TRACTS. LONG TERM ANIMAL
INHALATION STUDIES HAVE NOT SHO WN ANY IRREVERSIBLE DISEASE EFFECTS
RELATED TO FIBER GLASS EXPOSURE. MAY INCREASE THE RATE OF LUNG
CANCER.
Medical Cond Aggravated by Exposure:ANY CONDITION GENERALLY AGGRAVATED
BY MECHANICAL IRRITANTS IN AIR OR ON SKIN.
* First Aid Measures *
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE: FLUSH WITH
WATER. INHALED: REMOVE TO FRESH AIR & PROVIDE OXYGEN/CPR IF NEEDED.
ORAL: UN LIKELY.
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY, CO2, FOAM/DRY CHEMICAL. WATER SPRAY
MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL & FLUSH SPILLS
AWAY.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS, IF NEEDED.
Unusual Fire/Explosion Hazard:MAY PRODUCE CARBON MONOXIDE, CARBON
DIOXIDE.
* Accidental Release Measures *
Spill Release Procedures:PICK UP LARGE PIECES. WEAR APPROVED RESPIRATOR
SPILLAGE. AVOID CREATING DUST. PLACE SPILLAGE IN APPROPRIATE
CONTAINER FOR WASTE DISPOSAL. VENTILATE AREA AND WASH SPILL SITE.
Neutralizing Agent:NOT APPLICABLE.
*Handling and Storage *
Handling and Storage Precautions:STORAGE- STORE AT ROOM TEMPERATURE.
Other Precautions:AVOID INHALATION OF FIBERS. AVOID CONTACT WITH EYES
AND SKIN. WASH THOROUGHLY AFTER HANDLING MATERIAL. KEEP OUT OF
REACH OF CHILDREN. DO NOT ALLOW EATING OR DRINKING AT WORK AREA.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE ROLL - NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:FIRE
Hazardous Decomposition Products:MAY PRODUCE CARBON MONOXIDE, CARBON
DIOXIDE, AND WATER.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. THE PRIMARY METHOD OF DISPOSAL IS IN A
MUNICIPAL OR INDUSTRIAL LANDFILL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AIR SUPPLIED HOOD.
Ventilation:LOCAL EXHAUST OR BIOLOGICAL SAFETY CABINET.
Other Protective Equipment:TYVEK JUMP SUIT.
Work Hygienic Practices:WASH THROUGHLY AFTER HANDLING AND BEFORE
EATING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE.
* Product Identification *
Product ID:PURINETHOL
* Composition/Information on Ingredients *
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MOST CONSISTENT,DOSE-RELATED TOXICITY
IS BONE MARROW SUPPRESSION.THIS MAY CAUSE
ANEMIA,THROMBOCYTOPENIA,LEUKOPENIA OR ANY
COMBINATION.MERCAPTOPURINE IS HEPATOTOXIC,CAN CAUSE FETAL HARM,AND
CHROMOSOMAL ABERRATIONS.INDUCES DOMINANT-LETHAL MUTATIONS IN MALE
MICE.
Explanation of Carcinogenicity:MANUFACTURER STATES THAT MERCAPTOPURINE
IS A SUSPECTED HUMAN CARCINOGEN.
Effects of Overexposure:MANUFACTURER DID NOT SPECIFY.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH OF BLOOD AND LIVER
DISEASES,AND PREGNANT WOMEN SHOULD NOT BE EXPOSED TO THIS PRODUCT.
* First Aid Measures *
First Aid:EYES:RINSE IMMEDIATELY WITH PLENTY OF WATER.CONTACT
PHYSICIAN. SKIN:WASH SKIN OFF WITH PLENTY OF WATER.CONTACT
PHYSICIAN IF CONTACT IS PROLONGED. INGESTION:WASH OUT MOUTH.GIVE
PLENTY OF FLUIDS.CONTACT PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:USE CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR WATER
FOG.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF TOXIC OR IRRITANT FUMES.
* Accidental Release Measures *
Spill Release Procedures:WEAR SUITABLE PROTECTIVE EQUIPMENT AND
CLOTHING.SWEEP UP MINIMIZING DUST EVOLUTION.TRANSFER TO CLOSED
CONTAINER FOR DISPOSAL.DECONTAMINATE AREA WITH DILUTE ALKALINE
PERMANGANATE SOLUTION THEN WASH WIT H WATER.CLEAN AREA WITH
DETERGENT.
Neutralizing Agent:DILUTE ALKALINE PERMANGANATE SOLUTION.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN ORIGINAL CONTAINER TIGHTLY
CLOSED. PROTECT FROM LIGHT.
Other Precautions:
* Physical/Chemical Properties *
HCC:T6
Solubility in Water:APPRECIABLE.
Appearance and Odor:YELLOW,ODORLESS,ALMOST TASTELESS,CRYSTALLINE
POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE NOTED.
Stability Condition to Avoid:
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
INCOMPLETELY BURNED CARBON PRODUCTS.
* Disposal Considerations *
Waste Disposal Methods:ARRANGE FOR CHEMICAL INCINERATION. WASH WATER
AND RINSES SHOULD BE DISCHARGED TO AN APPROVED SEWERAGE SYSTEM.
DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND
LOCAL LAWS AND REGULATIONSREGARDING DISPOSAL OF POTENT
MEDICINALWASTE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:SUFFICIENT MECHANICAL (GENERAL) &/OR LOCAL EXHAUST TO KEEP
EXPOSURE BELOW TLV. OPEN WINDOWS/DOORS TO ENSURE FRESH AIR.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS BEFORE EATING OR USING WASHROOM.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL
Ingred Name:HYDROCARBON PROPELLANT, PETROLEUM GASES LIQUEFIED
Ingred Name:WEIGHT PER GALLON IN POUNDS: 7.8-8 (PAINT)
Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL
CARBINOL
Fraction by Wt: 0-5%
Ingred Name:ACETONE; DIMETHYL KETONE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: NASAL & RESPIRATORY
IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, HEADACHE,
POSSIBLE UNCONSCIOUSNESS & ASPHYXIATION. EYES: IRRITATION, REDNESS,
TEARING, & BLURRED VISION. INGESTION: GA STROINTESTINAL IRRITATION,
NAUSEA, VOMITING, & DIARRHEA. SKIN: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: PERMANENT BRAIN & NERVOUS SYSTEM
DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING
THE CONTENTS MAY BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:RESPIRATORY &/OR SKIN REACTION
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT
ADMINISTER OXYGEN. IF BREATHING STOPS, GIVE ARTIFICIAL RESPIRATION.
ASPIRA TION OF MATERIAL INTO LUNGS CAN CAUSE PNEUMONITIS, WHICH CAN
BE FATAL. KEEP WARM & QUIET. SKIN: WASH W/SOAP & WATER OR VARIOUS
HAND CLEANERS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Lower Limits:1%
Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE, BUT MAY BE
USED TO COOL CLOSED CONTAINERS. FOG NOZZLES ARE PREFERABLE IF USING
WATER. WEAR SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE/AUTOIGNITE
DUE TO PRESSURE BUILD-UP & EXPOSURE TO EXTREME HEAT. VAPORS ARE
HEAVIER THAN AIR & MAY TRAVEL ALONG GROUND. FLAMMABLE.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE
AREA. ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT OR OTHER
ABSORBENT MATERIAL & TRANSFER TO CLOSED CONTAINER.
*Handling and Storage *
SUNLIGHT. DON'T PUNCTURE OR INCINERATE.
Other Precautions:STORE LARGE QUANTITIES IN BUILDING PROTECTED FOR
STORAGE OF FLAMMABLE LIQUIDS. AVOID BREATHING VAPORS OR SPRAY MIST.
* Physical/Chemical Properties *
Vapor Density:>1
Spec Gravity:<1
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT TO MODERATE
Appearance and Odor:TYPICAL SOLVENT PAINT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, PILOT LIGHTS, FLAMES, SPARKS,
HEATERS, SMOKING, ELECTRIC MOTORS, & OTHER IGNITION SOURCES
Hazardous Decomposition Products:CO2, CO, VARIOUS HYDROCARBONS,
NITROGEN COMPOUNDS
* Disposal Considerations *
Waste Disposal Methods:DEPOSIT ABSORBENT MATERIAL IN A POSTED TOXIC
SUBSTANCE LANDFILL IN ACCORDANCE W/FEDERAL, STATE, & LOCAL
REGULATIONS.
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* Exposure Controls/Personal Protection *
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD.
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES
STILLBIRTHS.IRRITATES,EYES,NOSE,THROAT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA)
* First Aid Measures *
First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE
TO FRESH AIR.GIVE ART.RESPIR. AS NEEDED.INGEST:GET MEDICAL
ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE
UNCONSCIOUS PE RSON VOMIT.
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
*Handling and Storage *
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
* Physical/Chemical Properties *
HCC:Z3
Appearance and Odor:LIGHT STRAW COLORED LIQUID,AROMATIC ODOR.
* Stability and Reactivity Data *
STRONG OXIDIZERS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NON REQUIRED UNDER NORMAL CONDITIONS. IF MISTING
IS OCCURRING, USE NIOSH-APPROVED SUPPLIED AIR RESPIRATOR, OR AN
AIR-PURIFYING RESPIRATOR FOR ACID.
Ventilation:LOCAL EXHAUST OR MECHANICAL (GENERAL) VENTILATION AS
REQUIRED.
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER,
RUBBER COVERALLS, RUBBER HOOD, RUBBER SHOES
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
DIFFERENT FOLRMULA.
* Product Identification *
CAGE:0FGN2
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY
& GI TRACTS. ACUTE- CORROSIVE. CAN CAUSE SEVERE EYE BURNS &
BLINDNESS, ULCERATION OF SKIN, SEVERE RESPIRATORY IRRITATION BY
INHALING ACID MISTS & SEVERE BURNS OF MOUTH, THROAT, STOMACH BY
INGESTION. CHRONIC- EROSION OF TEETH, INFLAMMATION OF NOSE, THROAT
& BRONCHIAL TUBES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:COUGH, INCREASED RESPIRATORY RATE, STINGING AND
BURNING SENSATION OF SKIN, EYE IRRITATION AND BURNS, DISCOLORATION
OF TEETH, PAIN
Medical Cond Aggravated by Exposure:SKIN IRRITATION MAY BE AGGRAVATED
IN PERSONS WITH EXISTING SKIN LESION. MAY AGGRAVATE PRE-EXISTING
EYE, TEETH AND PULMONARY DISEASES.
* First Aid Measures *
First Aid:SPEED IS ESSENTIAL. START FIRST AID & GET MEDICAL CARE AT
EYELIDS OPEN. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF
NEEDED. ORAL:D O NOT INDUCE VOMITING. IF CONSCIOUS, DRINK LARGE
AMOUNT OF WATER. WASH OUT MOUTH. GARGLE TO WASH THROAT.
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER FROM A DISTANCE, CARBON DIOXIDE, DRY CHEMICAL
OR WATER FOG. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR FULL ACID PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:NON-FLAMMABLE, BUT MAY CAUSE IGNITION BY
CONTACT WITH COMBUSTIBLES. FIRE MAY PRODUCE POISONOUS GASES. WORK
UPWIND IF POSSIBLE. DO NOT GET WATER INSIDE CONTAINER
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. ELIMINATE IGNITION
SOURCES (H2 MAY BE GENERATED). VENTILATE AREA. DIKE SPILL.
CONTAIN/ABSORB SPILLS WITH DRY SAND, EARTH, VERMICULITE. CAREFULLY
NEUTRALIZE WITH SODA ASH, S ODIUM BICARBONATE, LIME. DO NOT FLUSH
TO SEWER.
Neutralizing Agent:LIME OR SODA ASH
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL PLACE AWAY FROM
ALWAYS ADD WATER CAUTIOUSLY TO ACID, NOT ACID TO WATER.
Other Precautions:AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES,
ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. KEEP OUT
OF REACH OF C HILDREN.
* Physical/Chemical Properties *
HCC:C1
NRC/State Lic Num:NOT RELEVANT
pH:<1
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID - ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CYANIDES, CHLORATES, CARBIDES, PICRATES, METALS, STRONG BASES, REDUCING
AGENTS, COMBUSTILE & ORGANIC ACID, ACETATES
Stability Condition to Avoid:WATER, HEAT, SPARKS, FLAME (HYDROGEN GAS
MAY BE PRESENT)
Hazardous Decomposition Products:SULFUR TRIOXIDE, SULFUR DIOXIDE,
SULFURIC ACID MIST, HYDROGEN SULFIDE
* Disposal Considerations *
Waste Disposal Methods:SHOVEL NEUTRALIZED SLURRY INTO SEALED
CONTAINERS. DISPOSE OF IN A SECURED SANITARY LANDFILL IF PERMITTED.
CONSULT APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXCED TLV,NIOSH/MSHA APPR SELF-CNTND BRTHG
APP (POS PR MODE)
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:NONE
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM CARBONATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Effects of Overexposure:EYE:MODERATE IRRITATION,REDNESS & TEARING;
SKIN:IRRITATION; INH:DUST CAN CAUSE IRRITATION OF NASAL &
RESPIRATORY PASSAGE; ING:RESULT IN SEVERE DAMAGE TO MUCOUS
MEMBRANES.
* First Aid Measures *
First Aid:EYE:FLUSH WITH WATER,LIFTING LIDS OCCASIONALLY; SKIN:WASH
W/SOAP & WATER,REMOVE CONTAMINATED CLOTHING; INH:REMOVE TO FRESH
AIR; ING:DO NOT INDUCE VOMITING,VOMITING WILL CAUSE FURTHER DAMAGE
TO THE THR OAT.DILUTE BY GIVING WATER,GIVE MILK OFMAGNESIA.KEEP
WARM & QUIET.GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:SELF CONTAINED BREATHING APPARATUS WITH A FULL
FACE PIECE OPERATOR IN A PRESSURE DEMAND OR OTHER POSITIVE PRESSURE
MODE.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP MATERIAL ONTO PAPER.
*Handling and Storage *
Handling and Storage Precautions:NONE
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:COMPLETE
Appearance and Odor:WHITE POWDER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG MINERAL ACID.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:FLUSH MATERIAL TO SEWER WITH LARGE AMOUNTS OF
WATER. DISCHARGE,TREATMENT,OR DISPOSAL MAY BE SUBJECT TO
FEDERAL,STATE OR LOCAL LAWS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS
NIOSH-RESPIRATOR SELECTION.
Ventilation:MECHANICAL (GENERAL) VENTILATION IS USUALLY ADEQUATE.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. INDUSTRIAL TYPE
WORK CLOTHING AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
USE AIR-SUPPLIED RESPIRATORY EQUIPMENT IF EXPOSED TO HOT FUMES. TREAT
EMPTY CONTAINERS AS DANGEROUS; DO NOT PRESSURIZE, CUT, WELD, BRAZE,
SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT, FLAME, SPAR KS,
PILOT LIGHTS, STATIC ELECTRICITY. RESIDUE MAY BE DIFFICULT TO
REMOVE.
* Product Identification *
CAGE:0BJL6
CAGE:0BJL6
* Composition/Information on Ingredients *
Ingred Name:MIXED TRIMETHYLOLPROPANE ESTERS
Other REC Limits:NONE SPECIFIED
Ingred Name:OILS (MISC. DISTILLATES)
Other REC Limits:NONE SPECIFIED
OSHA PEL:5 MG/M3 MIST
ACGIH TLV:5 MG/M3 MIST
Ingred Name:NEOPENTYL GLYCOL, CAPRYLIC/CAPRIC ESTERS
Other REC Limits:NONE SPECIFIED
Ingred Name:TAR ACIDS, CRESYLIC,PHENYL,PHOSPHATE (<0.2% ORTHO)
Other REC Limits:NONE SPECIFIED
Ingred Name:N-PHENYL ALPHA NAPHTHYLAMINE
Other REC Limits:NONE SPECIFIED
Ingred Name:DIOCTYLDIPHENYLAMINE
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION. AVOID BREATHING
OF MIST. PROLONGED OVEREXPOSURE MAY RESULT IN DERMATITIS AND
RESPIRATORY DIFFICULTIES. ANIMAL STUDIES ALSO SHOW AN EFFECT ON
THE KIDNEYS FOR EXPOSURE TO MATERI ALS SIMILAR TO THIS. AT HIGH
TEMPERATURES, ASPIRATION INTO THE LUNGS IS A HAZARD.
Explanation of Carcinogenicity:NONE OF THE CHEMICALS IN THIS PRODUCT IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN. ** SEE OTHER
PRECAUTIONS **
Effects of Overexposure:IRRITATION OF EYES AND SKIN UPON CONTACT.
IRRITATION OF THE RESPIRATORY TRACT, HEADACHES, DIZZINESS,
ANESTHETIC EFFECT AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS
INCLUDING DEATH IN RARE CASES. INGESTI ON MAY CAUSE CRAMPS AND
DIARRHEA.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF EYE, SKIN
AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND WATER. INHALATION:
REMOVE TO FRESH AIR. IF BREATHING IS IRREGULAR OR HAS STOPPED,
START RESU SCITATION AND ADMINISTER OXYGEN. GET MEDICAL HELP
IMMEDIATELY. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION AT ONCE. IN CASE OF SUBCUTANEOUS OR INTRAMUSCULAR
INJECTION, SEEK HELP AT ONCE.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT, ELIMINATE SOURCES
OF IGNITION, AND VENTILATE AREA AS REQUIRED. RECOVER FREE LIQUID.
ABSORB SMALL SPILL WITH INERT MATERIAL. PLACE WASTE IN DOT APPROVED
CONTAINER FOR DISPOSA L. KEEP MATERIAL FROM WATERWAYS.
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA AWAY FROM SOURCES OF IGNITION. KEEP CONTAINER CLOSED WHEN NOT
IN USE. PROTECT FROM PHYSICAL DAMAGE.
Other Precautions:AVOID BREATHING OF MIST. MINIMIZE PERIODS OF
EXPOSURE TO HIGH TEMPERATURE. AVOID WATER CONTAMINATION. CONTAINS
TRICRESYL PHOSPHATE (<0.2% ORTHO ISOMER) WHICH IS CLASSIFIED AS
NEUROTOXIN.
* Physical/Chemical Properties *
HCC:V6
Vapor Pres:NEGLIGIBLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER CLEAR LIQUID,MILD,SLIGHT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, CAUSTIC OR ACIDIC SOLUTIONS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,
ALDEHYDES AND KETONES, AND OTHER COMBUSTION PRODUCTS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AS REQUIRED
Ventilation:LOCAL EXHAUST
Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS
USED.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:DICK KARBO
CAGE:KMADD
CAGE:KMADD
* Composition/Information on Ingredients *
Ingred Name:COPPER COMPOUND
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN
CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
* First Aid Measures *
First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA
W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
* Accidental Release Measures *
Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE
CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS.
Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:INSOLUBLE
Appearance and Odor:OILY
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF WORKPLACE EXPOS LIMIT(S) OF PROD/ANY
COMPONENT IS EXCEEDED (SEE TLV/PEL), NIOSH/MSHA APPRVD AIR SUPP
RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CNTRL. OSHA REGS ALSO
PERMIT OTHER NIOSH/MSHA APPRV D RESP (NEG PRESS TYPE) UNDER
(SUPDAT)
Ventilation:MATERIAL MUST BE HANDLED OR TRANSFERRED IN AN APPROVED FUME
HOOD OR WITH EQUIVALENT VENTILATION.
Other Protective Equipment:PROT CLTHG (IMPERVIOUS) SHOULD BE WORN WHEN
HANDLING THIS MATERIAL. EYE WASH & SAFETY EQUIP SHOULD BE READILY
AVAILABLE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY.
Supplemental Safety and Health
SPILL PROCEDURE: CONTAINERIZE FOR PROPER DISPOSAL AS DESCRIBED.
RESPIRATORY PROTECTION: SPECIFIED CONDITIONS (SEE YOUR SAFETY
EQUIPMENT SUPPLIER). ENGINEERING AND/OR ADMINISTRATIVE CONTROLS
SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:P-CRESOL (SARA III)
OSHA PEL:5 PPM, S
ACGIH TLV:5 PPM, S
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TOXIC BY INGESTION, INHALATION AND
SKIN ABSORPTION. CAUSES BURNS ON CONTACT. CAN CAUSE DAMAGE TO
CENTRAL NERVOUS SYSTEM, LUNGS, LIVER AND KIDNEYS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:LIVER, KIDNEY, NERVOUS AND
RESPIRATORY CONDITIONS.
* First Aid Measures *
First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN:
IMMEDIATELY FLUSH THOROUGHLY WITH LARGE AMOUNTS OF WATER. EYES:
INHALATION: REMOVE TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF
BREATHING HAS STOPPED. INGESTION: DO NOT INDUCE VOMITING; GET
IMMEDIATE MEDICAL ATTENTION. REMOVE CONTAMINATED CLOTHING AND WASH
BEFORE REUSE.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCES TOXIC
FUMES.
* Accidental Release Measures *
Spill Release Procedures:EVAC AREA OF ALL UNNEC PERS. WEAR SUITABLE
PROT EQUIP LISTED UNDER PERS PROT. ELIM ANY IGNIT SOURCES UNTIL
AREA IS DETERMINED TO BE FREE FROM EXPLO/FIRE HAZS. CONTAIN RELS &
ELIM ITS SOURCE, IF THIS C AN BE DONE W/OUT RISK. TAKE UP & (SUPP
DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN COOL, DRY AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS.
Other Precautions:DO NOT BREATHE VAPOR OR MIST. DO NOT GET IN EYES, ON
SKIN OR ON CLOTHING.
* Physical/Chemical Properties *
Spec Gravity:1.0 (H*2O=1)
Solubility in Water:SLIGHT
Appearance and Odor:OFF-WHITE CRYSTALS, SWEET, TARRY ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS.
Stability Condition to Avoid:HEAT, CONTACT WITH IGNITION SOURCES.
Hazardous Decomposition Products:OXIDES OF CARBON.
* Disposal Considerations *
Waste Disposal Methods:COMPLY WITH FEDERAL, STATE, AND LOCAL
REGULATIONS ON REPORTING RELEASES. REFER TO REGULATORY INFORMATION
FOR REPORTABLE QUANTITY AND OTHER REGULATORY DATA. DISPOSE OF IN
ACCORDANCE WITH FEDERAL, STATE , AND LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .VENTILATE OVEN.
Other Protective Equipment:N/K
Work Hygienic Practices:AVOID SKIN CONTACT.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:DI-SEC-OCTYL PHTHALATE (DI-2-ETHYLHEXYL-PHTHALATE)(SARA
III)
Fraction by Wt: 6.3%
Other REC Limits:N/K
Ingred Name:CYCLOHEXANONE (SARA III)
Fraction by Wt: 7.2%
Other REC Limits:N/K
Ingred Name:METHYL ISOBUTYL KETONE (SARA III)
Other REC Limits:N/K
Ingred Name:N-AMYL ACETATE (SARA III)
Fraction by Wt: 1.0%
Other REC Limits:N/K
Ingred Name:TETRAHYDROFURAN (SARA III)
Fraction by Wt: 1.9%
Other REC Limits:N/K
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Other REC Limits:N/K
* Hazards Identification *
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF
OVEREXPOSURE.
Explanation of Carcinogenicity:DI (ETHYLHEXYL) PHTHALATE:INADEQ DATA
Effects of Overexposure:EYES:N/K .SKIN:POSSIBLE DRYING OR CHAPPING OF
HANDS.INGESTION/INHALATION:NAUSEA,DIZZINESS,HEADACHES.
Medical Cond Aggravated by Exposure:N/K
* First Aid Measures *
PHYSICIAN.SKIN:WIPE WITH SOLVENT,WASH WITH SOAP AND
WATER.INGESTION:SEE PHYSICIAN.INHALATION:REMOVE TO FRESH AIR.IF
SYMPTOMS PERSIST SEE PHYSICIAN .
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:N/K
Upper Limits:N/K
Extinguishing Media:CO*2,DRY CHEMICAL,WATER FOG SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .TREAT LIKE A LACQUER OR PAINT FIRE.
Unusual Fire/Explosion Hazard:AT EXTREME HIGH HEAT WILL CAUSE A DENSE
BLACK,CHOKING SMOKE.DENSE SOLVENT VAPORS CAN EXPLODE.HAZARDOUS
DECOMPOSITION PRODUCTS ARE CO,CO*2,MUCH SMOKE.
* Accidental Release Measures *
Spill Release Procedures:DIKE AREA-KEEP SPARKS OR FLAME FROM SPILL
AREA.WIPE UP OR SOAK UP WITH SAND OR ABSORBENT MATERIAL.
Neutralizing Agent:N/K
*Handling and Storage *
SPLASHING.KEEP TIGHTLY SEALED IN VENTILATED AREA AWAY FROM
HEAT.STORE OUT OF DIRECT SUNLIGHT.
* Physical/Chemical Properties *
HCC:F3
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:ND
Vapor Density:ND
Spec Gravity:SEE SUPP DATA
Evaporation Rate & Reference:ND
Appearance and Odor:THICK VISCOUS LIQUID,KETONE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:CO,CO*2,MUCH SMOKE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE OR DISPOSE OF IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:EMERGENCY USE: SELF CONTAINED BREATHING
APPARATUS (SCBA) OR POSITIVE PRESSURE AIR LINE WITH FULL-FACE MASK
AND ESCAPE PACK ARE TO BE USED IN OXYGEN DEFICIENT ATMOSPHERE. AIR
PURIFYING RESPIRATOR WILL NOT PROVIDE PROTECTION.
Ventilation:PROVIDE ADEQUATE VENTILATION AND/OR LOCAL EXHAUST TO
PREVENT ACCUMULATION OF SULFUR HEXAFLUORIDE CONCENTRATIONS ABOVE
Other Protective Equipment:SAFETY SHOES WHEN HANDLING CYLINDERS. SAFETY
GLASSES ARE RECOMMENDED WHEN HANDLING, CONNECTING, DISCONNECTING
CYLINDERS, AND WHEN PRESSURIZING SYSTEMS.
Work Hygienic Practices:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Supplemental Safety and Health
NOTES TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE. TREATMENT FOR
OVEREXPOSURE SHOULD BE DIRECTED AT THE CONTROL OF SYMPTOMS AND THE
CLINICAL CONDITION.
* Product Identification *
Product ID:SULFUR HEXAFLUORIDE
* Composition/Information on Ingredients *
Ingred Name:SULFUR HEXAFLUORIDE
* Hazards Identification *
Health Hazards Acute and Chronic:TARGE ORGANS: NONE. EYE: CONTACT WITH
LIQUID OR COLD VAPOR CAN CAUSE FREEZING OF TISSUE. INGESTION:
INGESTION IS NOT A LIKELY ROUTE OF EXPOSURE FOR SULFUR
HEXAFLUORIDE. INHALATION: SULFUR HEXAFLUORIDE IS AN ASPHYXIANT.
CAUSE DIZZINESS, DROWSINESS, NAUSEA, VOMITING, EXCESS SALIVATION,
DIMINISHED MENTAL ALERTNESS, LOSS OF CONSCIOUSNESSAND DEATH.
ABOUT UNCONSCIOUSNESS WITHOUT WARNING AND SO QUICKLY THAT THE
INDIVIDUALS CANNOT HELP THEMSELVES. SKIN: CONTACT WITH LIQU ID OR
COLD VAPOR CAN CAUSE FROSTBITE.
Explanation of Carcinogenicity:SULFUR HEXAFLUORIDE IS NOT LISTED AS A
CARCINOGEN OR POTENTIAL CARCINOGEN BY NTP, IARC, OR OSHA SUBPART Z.
Effects of Overexposure:EYES: FREEZING OF TISSUE. SKIN: FROSTBITE.
INHALATION: DIZZINESS, DROWSINESS, NAUSEA, VOMITING, EXCESS
SALIVATION, DIMINISHED MENTAL ALERTNESS, LOSS OF CONSCIOUSNESS,
DEATH.
Medical Cond Aggravated by Exposure:NONE
* First Aid Measures *
First Aid:EYE: FLUSH EYES WITH PLENTY OF LUKEWARM WATER FOR SEVERAL
MINUTES. SEEK MEDICAL ATTENTION IMMEDIATELY. INGESTION: INGESTION
IS NOT A LIKELY ROUTE OF EXPOSURE FOR SULFUR HEXAFLUORIDE.
INHALATION: REMOV E PERSON TO FRESH AIR. IF NOT BREATHING,
ADMINISTER ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
ADMINISTER OXYGEN. OBTAIN PROMPT MEDICAL ATTENTION. SKIN: IF LIQUID
SULFUR HEXAFLUORIDE COMES IN CONTACT WITH SKIN, REMOVE
CONTAMINATED CLOTHING AND FLUSH WITH PLENTY OF LUKEWARM WATER FOR
SEVERAL MINUTES. SEEK MEDICAL ATTENTION IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:SULFUR HEXAFLUORIDE IS NONFLAMMABLE AND DOES NOT
SUPPORT COMBUSTION. USE EXTINGUISHING MEDIA APPROPRIATE FOR THE
SURROUNDING FIRE.
Fire Fighting Procedures:EVACUATE ALL PERSONNEL FROM AREA. IF POSSIBLE,
REMOVE CYLINDERS FROM FIRE AREA OR COOL WITH WATER. SELF-CONTAINED
BREATHING APPARATUS (SCBA) MAY BE REQUIRED.
Unusual Fire/Explosion Hazard:MOST CYLINDERS ARE DESIGNED TO VENT
CONTENTS WHEN EXPOSED TO ELEVATED TEMPERATURES. PRESSURE IN A
CYLINDER CAN BUILD UP DUE TO HEAT & IT MAY RUPTURE IF PRESSURE
RELIEF DEVICES SHOULD FAIL TO FUNCTION .
* Accidental Release Measures *
Spill Release Procedures:EVACUATE IMMEDIATE AREA. INCREASE VENTILATION
TO RELEASE AREA AND MONITOR OXYGEN LEVEL. USE APPROPRIATE
PROTECTIVE EQUIPMENT (SCBA). SHUT OFF SOURCE OF LEAK IF POSSIBLE.
ISOLATE ANY LEAKING CYLINDER. IF LEAK IS FROM CONTAINER, PRESSURE
RELIEF DEVICE OR ITS VALVE, CONTACT YOUR SUPPLIER. IF LEAK IS IN
USER'S SYSTEM, CLOSE CYLINDER VALVE AND VENT PRESSURE BEFORE
ATTEMPTING REPAIRS.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.
*Handling and Storage *
Handling and Storage Precautions:STORE CYLINDERS IN A WELL-VENTILATED,
SECURE AREA, PROTECTED FROM THE WEATHER. CYLINDERS SHOULD BE STORED
UPRIGHT WITH VALVE OUTLET SEALS & VALVE PROTECTION CAPS IN PLACE.
SHOULD BE AWAY FROM HEAVILY TRAVELED AREAS & EMERGENCY EXITS.
Other Precautions:FULL & EMPTY CYLINDERS SHOULD BE SEGREGATED. USE A
FIRST-IN, FIRST -OUT INVENTORY SYSTEM TO PREVENT FULL CONTAINERS
FROM BEING STORED FOR LONG PERIODS OF TIME. DO NOT DRAG, ROLL,
SLIDE OR DROP CYLINDE R. USE A SUITABLE HAND TRUCK DESIGNED FOR
CYLINDER MOVEMENT. NEVER ATTEMPT TO LIFT A CYLINDER BY ITSCAP.
* Physical/Chemical Properties *
HCC:G3
B.P. Text:[SUBLIMATION POINT]
Appearance and Odor:COLORLESS AND ODORLESS GAS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT OF A LIQUEFIED GAS, SUCH AS SULFUR HEXAFLUORIDE, WITH
WATER OR HOT REACTIVE METALS.
Stability Condition to Avoid:CYLINDERS SHOULD NOT BE EXPOSED TO
Hazardous Decomposition Products:UPON EXPOSURE TO HIGH TEMPERATURE OR
ELECTRIC ARCING, SULFUR HEXAFLUORIDE WILL FORM A NUMBER OF SULFUR
(SF4) PREDOMINATING.
Conditions to Avoid Polymerization:WILL NOT OCCUR
* Toxicological Information*
CORROSIVITY: SULFUR HEXAFLUORIDE IS NOT CORROSIVE TO THE SKIN.
ADDITIONAL NOTES: NONE.
* Ecological Information *
Ecological:AQUATIC TOXICITY:NOT AVAILABLE. MOBILITY:NOT AVAILABLE.
PERSISTENCE & BIODEGRADABILITY:NOT AVAILABLE. POTENTIAL TO
BIOACCUMULATE:HIGH. REMARKS:SULFUR HEXAFLUORIDE DOES NOT CONTAIN
CLASS I OR CLASS II OZONE DEPLETING CHEMICALS.SULFUR HEXAFLUORIDE
HAS BEEN IDENTIFIED AS HAVING THE POTENTIAL TO CONTRIBUTE TO GLOBAL
WARMING.EMISSIONS COULD POTENTIALLY CONTRIBUTE TO LONG-TERM GLOBAL
THE EXPECTED GLOBAL TEMPERATURE RISE BASED ON SULFUR HEXAFLUORIDE
CO2 WILL CONTRIBUTE T O A RISE OF 0.8C IN THE SAME TIME PERIOD
* Disposal Considerations *
Waste Disposal Methods:UNUSED PRODUCT/EMPTY CYLINDER: RETURN CYINDER
AND UNUSED PRODUCT TO SUPPLIER. DO NOT ATTEMPT TO DISPOSE OF UNUSED
PRODUCT. FOR EMERGENCY DISPOSAL, SECURE THE CYLINDER AND SLOWLY
DISCHARGE GAS AT THE A TMOSPHERE IN A WELL VENTILATED AREA OR
OUTDOORS.
* MSDS Transport Information *
Transport Information:DOT SHIPPING NAME: SULFUR HEXAFLUORIDE. HAZARD
NONFLAMMABLE GAS. PACARD: NONFLAMMABLE GAS. SPECIAL SHIPPING
INFORMATION: CYLINDERS SHOULD BE TRANSPORTED IN A SECURE UPRIGHT
POSITION IN A WELL-VENTILATED TRUCK. NEVER TRANSPORT IN PASSENGER
COMPARTMENT OF A VEHICLE. ENSURE CYLINDER VALVE IS PROPERLY CLOSED,
VALVE OUTLET HAS BEEN RE-INSTALLED , AND VALVE PROTECTION CAP IS
SECURED BEFORE SHIPPING CYLINDER. CAUTION: COMPRESSED GAS CYLINDERS
SHALL NOT BE REFILLED EXCEPT BY QUALIFIED PRODUCERS OF COMPRESSED
GAS.
* Regulatory Information *
APPLICABLE. THRESHOLD PLANNING QUANTITY (TPQ): NOT APPLICABLE.
YES; DELAYED HEALTH: NO; PRESSURE: YES; REACTIVITY: NO; FLAMMABLE:
SECTION. THRESHOLD PLANNING QUA NTITY (TPQ): NOT APPLICABLE. TSCA:
TOXIC SUBSTANCE CONTROL ACT: SULFFUR HEXAFLUORIDE IS LISTED ON THE
OF HIGHLY HAZARDOUS CHEMICALS SU LFUR HEXAFLUORIDE IS NOT LISTED IN
APPENDIX A AS A HIGHLY HAZARDOUS CHEMICAL. THRESHOLD PLANNNG QUAN
TITY(RQ): NOT APPLICABLE.
IS NOT A LISTED SUBSTANCE WHICH THE STATE OF CALIFORNIA REQUIRES
WARNING UNDER THIS STATUTE.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHEN CONCENTRATIONS EXCEED THE TLV, USE AN
APPROVED ORGANIC VAPOR OR SUPPLIED AIR RESPIRATOR IN POSITIVE
PRESSURE MODE. FOLLOW MANUFACTURERS RECOMMENDATIONS AND LIMITATION.
Ventilation:GENERALLY, MECHANICAL VENTILATION IS ADEQUATE.
Other Protective Equipment:HIMS SUGGESTS: ANSI APPROVED EMERGENCY
EYEWASH & DELUGE.
Work Hygienic Practices:HMIS SUGGESTS: OBSERVE GOOD INDUSTRIAL HYGIENE
PRACTICES AND RECOMMENDED PROCEDURES. WASH AFTER HANDLING AND
BEFORE EATING OR DRINKING.
Supplemental Safety and Health
THIS PRODUCT IS MANUFACTURED IN STRICT ACCORDANCE WITH MIL SPEC
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MONOETHANOLAMINE (ETHANOLAMINE; MEA; ETHANOL, 2-AMINO)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:3 PPM
Ingred Name:SODIUM DIETHANOLGLYCINATE (SODIUM SALT OF
N,N-BIS(2-HYDROXYETHYL)GLYCINE)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES-SEVERE EYE DAMAGE, MAY CAUSE
SWELLING OF THE CONJUNCTIVA. SKIN-PROLONGED OR WIDESPREAD SKIN
CONTACT MAY RESULT IN THE ABSORPTION OF POTENTIALLY HRAMFUL AMOUNTS
OF MATERIAL. INHALATION-PROLONGED O VEREXPOSURE MAY RESULT IN LUNG
DAMAGE. INGESTION-KIDNEY AND LIVER DAMAGE HAS BEEN DESCRIBED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES-CAUSES IRRITATION, SEEN AS REDNESS AND
SWELLING OF THE EYE AND CHEMICAL BURNS OF THE EYE. SKIN-CAUSES
SEVERE EXCESS REDNESS AND SWELLING WITH CHEMICAL BURNS.
INHALATION-VAPORS OR MISTS ARE IRRITA TING AND CAUSE NASAL
DISCHARGE, COUGHINGAND DISCOMFORT OF THE EYES, NOSE, THROAT, AND
CHEST. INGESTION-CAUSES BURNING OF THE MOUTH, THROAT AND STOMACH
WITH ABDOMINAL AND CHEST PAIN, NAUSEA, VOMITING, DIARRHEA, THIRST,
WEAKNESS, COLLAPSE, AND COMA.
Medical Cond Aggravated by Exposure:OVEREXPOSURE MAY AGGRAVATE EXISTING
RESPIRATORY CONDITIONS, SUCH AS ASTHMA, BRONCHITIS, AND
INFLAMMATORY OR FIBROTIC RESPIRATORY DISEASE.
* First Aid Measures *
First Aid:EYES-FLUSH EYES WITH LARGE AMOUNTS OF RUNNING WATER FOR AT
RMOVE CON TAMINATED CLOTHING & SHOES. SEEK MEDICALATTENTION. WASH
CLOTHING BEFORE RESUE. INHALATION-REMOVE TO FRESH AIR. GIVE
ARTIFICIAL RESPIRATION IF NOT BREATHING. OXYGEN MAY BE GIVEN BY
QUALIFIED INDIVIDUAL . SEEK MEDICAL ATTENTION. INGESTION-IF PATIENT
DO NOT INDUCE VOMITING. SEEK IMMEDIATE MEDICAL ATTENTION. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS/CONVULSING PERSON.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:CARBON DIOXIDE, ALCOHOL FOAM, DRY CHEMICAL MEDIA.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. AVOID BREATHING VAPOR. CONTAIN
SPILL. ABSORB WITH VERMICULITE, CLAY OR DIATOMACEOUS EARTH. COLLECT
MATERIAL IN DRUMS AND DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL,
STATE AND LOCAL HAZA RDOUS MATERIAL REGULATIONS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY PLACE, AWAY FROM EXTREME
Other Precautions:1) INHALATION OF THIS PRODUCT MAY CAUSE AN
ASTHMA-LIKE REACTION. 2) REPEATED SKIN CONTACT MAY CAUSE A
PERSISTENT IRRITATION OR DERMATITIS.
* Physical/Chemical Properties *
HCC:B2
NRC/State Lic Num:NOT RELEVANT
pH:ALKALI
Appearance and Odor:WATER-WHITE LIQUID, WITH AMMONIEA-LIKE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST- ADEQUATE. MECHANICAL(GENERAL)- ADEQUATE.
SPECIAL- N/A. OTHER- N/A.
Other Protective Equipment:EYE WASH / SHOWER FACILITY NEARBY.
Work Hygienic Practices:GOOD HOUSEKEEPING PRACTICES. AVOID SKIN / EYE
CONTACT.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM SULFATE
OSHA PEL:N/E
ACGIH TLV:N/E
Ingred Name:LAURAMIDE MEA
OSHA PEL:N/E
ACGIH TLV:N/E
OSHA PEL:N/E
ACGIH TLV:N/E
Ingred Name:VIABLE BACTERIAL CULTURES
OSHA PEL:N/E
ACGIH TLV:N/E
OSHA PEL:N/E
ACGIH TLV:N/E
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HEALTH HAZARDS (ACUTE & CHRONIC):
INGESTION MAY CAUSE GASTRIC DISTURBANCE. INDUCE VOMITING AND
CONTACT A PHYSICIAN. SKIN AND EYE IRRITANT; AVOID PROLONGED
Effects of Overexposure:NONE KNOWN.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
First Aid:EYE CONTACT- FLUSH WITH WATER. IF INGESTED, GIVE LARGE
AMOUNTS OF WATER AND INDUCE VOMITING: GET MEDICAL ATTENTION. SKIN:
FLUSH WITH COPIOUS AMOUNTS OF WATER. CONTACT PHYSICIAN .
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY FOAM, WATER SPRAY.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP.
*Handling and Storage *
Handling and Storage Precautions:STORAGE: DO NOT STORE NEAR HEAT OR
OPEN FLAME.
Other Precautions:DO NOT STORE NEAR HEAT OR OPEN FLAME.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:N/D
Melt/Freeze Pt:M.P/F.P Text:N/D
Spec Gravity:N/D
Evaporation Rate & Reference:N/D
Appearance and Odor:BLUE CYLINDRICAL BLOCK WITH ENZYM AND FRAGRANCE,
CASED IN A PLASTIC SCREEN.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS SUCH AS NITRIC ACID.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE.
* Disposal Considerations *
Waste Disposal Methods:INCINERATION OR LANDFILL FOR ABSORBANT MATERIAL.
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR NIOSH/MSHA APPROVED
RESPIRATORY DEVICE.
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR PT#/TRADE NAME: SOLIDS ENAMEL NON-LEAD. FIRE FIGHT
PROC:AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT. IF
WATER IS USED, FOG NOZZLES ARE PREFERABLE. EXPLO HAZ:REQUIRES
SPECIAL PRECAUTIONS . DURING EMER CONDITIONS OVEREXP TO DECOMP
PRODS MAY CAUSE A HEALTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. GET
MD.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:KEROSENE(PETROLEUM),HYDROTREATED;(MINERAL SPIRITS).VP:2.
Ingred Name:BENZENE, ETHYL-;(ETHYL BENZENE) (SARA III). VP:7.1.
Fraction by Wt: <5%
Ingred Name:XYLENE. VP:5.9
Ingred Name:SOLVENT NAPHTHA, LIGHT AROMATIC; (LIGHT AROMATIC NAPHTHA).
VP:3.8
Ingred Name:TITANIUM OXIDE;(TITANIUM DIOXIDE)
Ingred Name:OTHER PREC:ELEC TOOLS & APPLIANCES, & ANY OTHER SOURCES OF
IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING/GROUNDING(ING 7)
Ingred Name:ING 6:PROC. KEEP CNTNR CLSD WHEN NOT IN USE. TRANSFER ONLY
TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT (ING 8)
Ingred Name:ING 7:TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN. THIS
COATING CNTNS HAZ MATLS CLASSIFIED AS NUISANCE (ING 9)
Ingred Name:ING 8:PARTICULATES, FOR EXAMPLE TITANIUM DIOXIDE, CALCIUM
Ingred Name:ING 9:ONLY DURING SANDING/ABRADING OF DRIED FILM.
INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS MAY BE (ING
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:OVEREXPOSURE CAUSES EYE, SKIN
AND RESPIRATORY IRRITATION. MAY CAUSE NERVOUS SYSTEM DEPRESSION
ACCOMPANIED BY HEADACHE, DIZZINESS, NAUSEA, CONFUSION & STAGGERING
GAIT. EXTREME OVEREXPOSURE MAY RE SULT IN UNCONSCIOUSNESS &
POSSIBLY DEATH. CHRONIC: PROLONGED OVEREXPOSURE TO INGREDIENTS MAY
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:ADVERSE EFFECTS TO THE LIVER, URINARY,
& REPRODUCTIVE SYSTEMS. REPORTS HAVE ASSOCIATED REPEATED AND
PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS
SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:MOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH THOROUGHLY WITH SOAP & WATER. REMOVE CONTAMINATED
CLOTHING AND LAUNDER BEFORE REUSE. EYE:FLUSH WITH LARGE AMOUNTS OF
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:0.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIP . WATER SPRAY MAY BE INEFTIVE BUT MAY BE USED TO COOL CLSD
CNTNRS TO PVNT PRESS BUILDUP & POSS (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS, & OPEN FLAME. CLSD CNTNRS MAY EXPLODE
WHEN EXPOSED TO EXTREME HEAT. APPLIC TO HOT SURFS(SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE ONLY W/ADEQUATE VENTILATION. AVOID
BREATHING VAPOR & SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES.
KEEP AWAY FROM HEAT, SPARKS, & OPEN FLAME.
Other Precautions:PROTECT AGAINST DUST WHICH MAY BE GENERATED BY
SANDING OR ABRADING DRIED FILM. CONTENTS ARE FLAMMABLE. DURING USE
& UNTIL ALL VAPS ARE GONE:KEEP AREA VENT-DO NOT SMOKE-EXTING ALL
FLAMES, PILOT LIGHTS & HEATERS-TURN OFF STOVES, (ING 6)
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:SEE ING
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CO, CO2.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT
INCIN CLSD CNTNR. DISP OF I/A/W FED, STATE & LOC REGS REGARDING
POLLUTION.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR EMERGENCY OCCURS; USE NIOSH/MSHA APPROVED SUPPLIED AIR
MANUFACTURER'S RECOMMENDATIONS.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
MAITAIN EXPOSURE BELOW PUBLISHED LIMITS.
Other Protective Equipment:IMPERVIOUS CLOTHING INCLUDING BOOTS TO
PREVENT PROLONGED OR REPEATED SKIN CONTACT IF NEEDED.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
TYPE 2 AND CLASS 2.
* Product Identification *
Product ID:STARRETT M-1 ALL PURPOSE LUBRICANT
Kit Part:Y
Preparer's Name:HENRY FRIEDBERG
* Composition/Information on Ingredients *
Ingred Name:BLEND OF MINERAL SPIRITS
Other REC Limits:NONE SPECIFIED
Ingred Name:PETROLATUM
Other REC Limits:NONE SPECIFIED
Ingred Name:ADDITIVES (PROPRIETARY COMPOSITION)
Other REC Limits:NONE SPECIFIED
Ingred Name:PROPANE
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONTACT CAN CAUSE SKIN AND EYE
IRRITATION. INHALATION MAY CAUSE SEVERE RESPIRATORY IRRITATION.
INGESTION MAY CAUSE SEVERE GI TRACT IRRITATION. ASPIRATION MAY
CAUSE CHEMICAL PNEUMONITIS WHICH CA N BE FATAL. CHRONIC: NONE
SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NO INGREDIENTS OF A CONCENTRATION OF
0.1% OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED: COUGHING, WHEEZING, SNEEZING,
SHORTNESS OF BREATH, DIZZINESS, FATIGUE, WEAKNESS. EYES: REDNESS,
BLURRED VISION, TEARING. SKIN: DEFATTING, DRYING, REDNESS,
DISCOMFORT. INGESTED: NAUSEA, VOMITI NG.
* First Aid Measures *
First Aid:IN ALL CASES, GET IMMEDIATE MEDICAL ATTENTION.
INHALATION-REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION IF NOT
SKIN-WASH WITH SOAP & WATE R. REMOVE CONTAMINATED CLOTHING.
INGESTION-DO NOT INDUCE VOMITING.
* Fire Fighting Measures *
Flash Point Method:TOC
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:FIREFIGHTER SHOULD WEAR FULL PROTECTIVE
CLOTHING INCLUDING POSITIVE-PRESSURE SELF-CONTAINED BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR; MAY TRAVEL
TO DISTANT SOURCE OF IGNITION AND FLASHBACK.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. ELIMINATE ALL
SOURCES OF IGNITION. STOP AND CONTAIN SPILL. PUMP TO SALVAGE OR
ABSORB ON INERT MATERIAL. PREVENT RUN-OFF INTO SURFACE WATERS OR
SEWERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP FROM STRONG OXIDIZING AGENTS,
AEROSOL CANS.
Other Precautions:ANY CONTAINER OF THIS MATERIAL WHEN EMPTIED, MAY
CONTAIN HAZARDOUS RESIDUES. ALL PRECAUTIONS OF THIS DATA SHEET MUST
BE OBSERVED. AVOID CONTACT WITH SKIN AND EYES. DO NOT BREATHE
VAPORS AND/OR MIST.
* Physical/Chemical Properties *
HCC:V3
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER LIQUID; PLEASANT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:
AVOID EXPOSURE TO SOURCES OF IGNITION AND STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
DLA-HMIS: PROBABLY CARBON MONOXIDE AND CARBON DIOXIDE
* Disposal Considerations *
Waste Disposal Methods:DESTROY BY LIQUID INCINERATION AND/OR DISPOSE
MATERIAL COLLECTED IN A PERMITTED HAZWASTE LANDFILL. DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
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* Exposure Controls/Personal Protection *
Respiratory Protection:MFR RECOMMENDS NIOSH/MSHA APPRVD FILTER FOR
FUME, MIST & DUST.
Ventilation:USE ADEQUATE VENTILATION.
Supplemental Safety and Health
INGREDIENTS: DIAZINON IS CONTAINED POLYMERIC MICROCAPSULES DISPERSED &
SUSPENDED IN WATER. THIS FORMULATION HAS SIGNIFICANTLY REDUCED THE
HAZARD OF THE ACTIVE INGREDIENT.
* Product Identification *
Product ID:KNOX OUT 2FM
* Composition/Information on Ingredients *
Ingred Name:DIAZINON (SARA III)
OSHA PEL:S, 0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Effects of Overexposure:CHOLINESTERASE INHIBITOR-REPEATED EXPOSURE MAY
PRODUCE EFFECTS WITHOUT SYMPTOMS, AND MAY BE FATA.
* First Aid Measures *
SOAP & WATER, SEE MD. INGEST: INDUCE VOMIT, SEE MD. ATROPINE IS
ANTIDOTE. INHAL: REMOVE TO FRESH AIR, SEE MD.
* Fire Fighting Measures *
Extinguishing Media:COMPATIBLE WITH ALL MEDIA
Fire Fighting Procedures:WEAR SELF-CONT-BREATH-APPAR & PROTECTIVE
EQUIPMENT.
Unusual Fire/Explosion Hazard:POSSIBLE TOXIC FUMES
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH SAND OR INERT MATERIAL. SWEEP OR
SCOOP UP AND REMOVE. FLUSH AREA W/ WATER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE W/ FOOD OR FEED. WASH
THOROUGHLY AFTER HANDLING. WATCH FOR SIGNS OF CHOLINESTERASE INH
Other Precautions:EMPTY CONTAINER MAY CONTAIN HAZARDOUS RESIDUE. DO NOT
BREATHE VAPOR,MIST,GAS,DUST. AVOID CONTACT WITH EYES,SKIN &
CLOTHING. CONTACT THE NAVY ENVIRONMENTAL HEALTH CENTER FOR MORE
HEALTH INFO.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SAME AS WATER
Solubility in Water:DISPERSES
Appearance and Odor:BEIGE LIQUID, CHARACTERISTIC ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MATERIALS THAT REACT IN WATER
Hazardous Decomposition Products:THERMAL-POSSIBLE TOXIC SUBSTANCES
* Disposal Considerations *
Waste Disposal Methods:MFR RECOMMENDS TO TRANSPORT SOLID MATRL TO
APPRVD DUMP WHERE CONTAMINATION OF FEED,WATER OR PLANTS WILL NOT
OCCUR. FLUSH WATER WASHING TO DRAIN THAT WILL NOT CONTAMINATE WATER
SOURCES. DISPOSAL METHOD MUST BE IAW FEDERAL, STATE & LOCAL CODES.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE UNDER NORMAL USE CONDITIONS. USE NIOSH
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:GENERAL VENTILATION UNDER NORMAL USE CONDITIONS.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER .
Work Hygienic Practices:KEEP BATTERIES AWAY FROM SMALL CHILDREN.
Supplemental Safety and Health
FIRST AID PROC: NOTES TO MD: 1) POTENTIAL LEAKAGE OF DIMETHOXYETHANE,
PROPYLENE CARBONATE & LITHIUM TRIFLUOROMETHANE SULFONATE. 2)
DIMETHOXYETHANE RAPIDLY EVAPS. 3) UNDER CERTAIN MISUSE CNDTNS & BY
ABUSIVELY OPENING BATTERY, EXPOSED LITHIUM CAN REACT W/WATER OR
MOISTURE IN AIR CAUSING POTENTIAL THERMAL BURNS/FIRE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MANGANESE DIOXIDE
Other REC Limits:N/K
OSHA PEL:C5 MG/M3
OSHA STEL:N/K
ACGIH TLV:5 MG/M3
ACGIH STEL:N/K
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Ingred Name:LITHIUM
Minumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Ingred Name:PROPYLENE CARBONATE
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Ingred Name:ETHYLENE CARBONATE
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Ingred Name:CARBON BLACK
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:3.5 MG/M3
OSHA STEL:N/K
ACGIH TLV:3.5 MG/M3
ACGIH STEL:N/K
Ingred Name:LITHIUM TRIFLUOROMETHANESULFONATE
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:THESE CHEMICALS & METALS ARE CONTAINED
IN SEALED CAN. FOR CONSUMER USE, ADEQUATE HAZ WARNINGS ARE
INCLUDED ON BOTH PACKAGE & ON BATTERY. POTENTIAL FOR EXPOS SHOULD
NOT EXIST UNLESS BATTERY LEAKS, ISEXPOSED TO HIGH TEMPERATURE/IS
MECHANICALLY, PHYSICALLY/ELECTRICALLY ABUSED. ACUTE: INHAL: NOT
ANTICIPATED. RESPIRATORY (& EYE) IRRIT MAY OCCUR IF FUMES ARE
RELEASED DUE TO HEAT/ABUNDANCE OF LEAKI NG BATTERIES. INGEST:
IRRIT TO INTERNAL/EXTERNAL MOUTH AREA. SKIN CONT: IRRITMAY OCCUR
FOLLOWING EXPOS TO LEAKING BATTERY. SKIN ABSORPTION: NOT
ANTICIPATED. EYE CONTACT: IRRIT MAY OCCUR FOLLOWING EXPOS TO
LEAKING BATTERY.
* First Aid Measures *
First Aid:EYES: NOT ANTIC. IF BATTERY IS LEAKING & MATL CONTACTS EYES,
ONCE. SKIN: NOT ANTIC. IF BATTERY IS LEAKING, IRRIGATE EXPOSED
IRRIT, INJURY/PAIN PERSISTS, CONSULT MD. INHAL: NOT ANTIC. IF
BATTERY IS LEAKING, CONTENTS MAY BE IRRITATING TO RESP PASSAGES.
REMOVE T O FRESH AIR. CONT MD IF IRRIT PERSISTS. INGEST: NOT
ANTIC. RINSE MOUTH & SURROUNDING AREA W/CLEAR, TEPID WATER FOR AT
INVOLVEMENT OF ESO PHAGUS & OTHER TISS. (SUP DAT)
* Fire Fighting Measures *
Flash Point:SEE ING 2
Extinguishing Media:WATER.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL FIRE-EXPOSED BATTERIES AND ADJACENT STRUCTURES
WITH WATER SPRAY FROM A DISTANCE.
Unusual Fire/Explosion Hazard:BATTERIES MAY BURST AND RELEASE HAZARDOUS
DECOMPOSITION PRODUCTS WHEN EXPOSED TO A FIRE SITUATION.
* Accidental Release Measures *
Spill Release Procedures:NOTIFY SAFETY PERSONNEL OF LARGE SPILLS.
EVACUATE THE AREA AND ALLOW VAPORS TO DISSIPATE. INCREASE
VENTILATION. AVOID EYE OR SKIN CONTACT. DO NOT INHALE VAPORS.
CLEAN-UP PERSONNEL SHOULD WEAR APP ROPRIATE PROTECTIVE GEAR.
REMOVE SPILLED LIQUID WITH ABSORBENT AND CONTAIN FOR DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. AVOID
MECHANICAL OR ELECTRICAL ABUSE. DO NOT SHORT OR INSTALL
INCORRECTLY. BATTERIES MAY EXPLODE, PYROLIZE OR VENT IF
DISASSEMBLED, CRUSHED, RECHARGED OR EXPOSED TO HIGH TEMPERATURES.
INSTALL BATTERIES IN ACCORDANCE WITH EQUIPMENT INSTRUCTIONS.
Other Precautions:DO NOT MIX BATTERY SYSTEMS, SUCH AS ALKALINE AND ZINC
CARBON, IN THE SAME EQUIPMENT. REPLACE ALL BATTERIES IN EQUIPMENT
AT THE SAME TIME. DO NOT CARRY BATTERIES LOOSE IN POCKET OR BAG.
* Physical/Chemical Properties *
HCC:T6
Appearance and Odor:SMALL CYLINDRICAL BATTERIES. CONTENTS DARK IN
COLOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTENTS INCOMPATIBLE WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:DO NOT HEAT, CRUSH, DISASSEMBLE, SHORT
CIRCUIT OR RECHARGE.
Hazardous Decomposition Products:THERMAL DEGRADATION MAY PRODUCE
HAZARDOUS FUMES OF MANGANESE AND LITHIUM; HYDROFLUORIC ACID;
OXIDES OF CARBON AND SULFUR AND OTHER TOXIC BY-PRODUCTS.
* Ecological Information *
Ecological:THESE BATTERIES PASS THE U.S. EPA'S TOXICITY CHARACTERISTIC
LEACHING PROCEDURE AND THEREFORE, MAY BE DISPOSED OF WITH NORMAL
WASTE.
* Disposal Considerations *
Waste Disposal Methods:NO SPECIAL PRECAUTIONS ARE REQUIRED FOR SMALL
QUANTITIES. LARGE QUANTITIES OF OPEN BATTERIES SHOULD BE TREATED
AS HAZARDOUS WASTE. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE
AND LOCAL REGULATIONS. DO NOT INCINERATE, SINCE BATTERIES
MAYEXPLODE AT EXCESSIVE TEMPERATURES.
* MSDS Transport Information *
Transport Information:DOT HAZARD CLASS/DOT SHIPPING NAME: NOT
APPLICABLE.
* Regulatory Information *
Federal Regulatory Information:ALL INGREDIENTS LISTED IN TSCA
INVENTORY.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH APPROVED RESPIRATORY PROTECTION WHEN
THE PRODUCT IS MIXED OR APPLIED IN A POORLY VENTILATED AREA OR IF
WORKPLACE LEVELS OF INGREDIENTS EXCEED THE TLV. FOLLOW APPLICABLE
FEDERAL, STATE, AND LOCAL REGULATIONS.
Ventilation:USE LOCAL EXHAUST (E.G., OPEN WINDOWS, FANS) AS NEEDED TO
KEEP VAPOR/DUST LEVELS BELOW RECOMMENDED LIMITS.
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
WEAR CLEAN PROT CLTHG TO COVER ARMS & LEGS & KEEP EXPOS TO A
MINIMUM.
Work Hygienic Practices:WASH THOROUGHLY AFTER USING. AVOID WEARING
Supplemental Safety and Health
FIRE FIGHT PROC: FROTHING W/SUBSEQUENT SPREAD OF FIRE. EXPLO HAZ:
HVR/AIR & MAY TRAVEL ALONG GROUND/FLOOR & BE IGNITED AT LOCATIONS
DISTANT FROM SOURCE. EXPLAN OF CARCIN: CARCIN. HUMAN: LUNG. EFTS OF
OVEREXP: INGEST: MAY CAUSE IRRIT IF SWALLOWED. CHRONIC: PRLNG &/OR
RPTD OVEREXP TO FREE RESPIRABLE SILICA MAY (ING 7)
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: <5%
Fraction by Wt: 1-5%
OSHA PEL:5 MG/M3
ACGIH TLV:2 MG/M3
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC
Fraction by Wt: 1-5%
ACGIH TLV:2 MG/M3 RDUST
Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICONE DIOXIDE) VP: NONE @
Fraction by Wt: 0.1-1%
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3 RDUST
Ingred Name:CALCIUM CARBONATE; (CALCIUM CARBONATE (LIMESTONE)) VP: NONE
Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS (STODDARD TYPE)) VP: 2 @
Ingred Name:SUP DAT: CAUSE SILICOSIS/OTHER DELAYED & SERIOUS LUNG
INJURY. DUST COULD ALSO CONTAIN PARTICLES OF TITANIUM (ING 8)
Ingred Name:ING 7: DIOXIDE, CALCIUM OXIDE, TALC, ALUMINUM SULFATE, &/OR
CALCIUM CARBONATE. CHRONIC OVEREXP TO DUSTS OF THESE (ING 9)
Ingred Name:ING 8: SUBSTANCES MAY CAUSE DELAYED & SERIOUS LUNG INJURY.
Ingred Name:ING 9: SKIN SENSITIZER. RPTD/PRLNG OVEREXP CAN LEAD TO
"SNIFFING") MAY BE HARMFUL OR FATAL.
Ingred Name:FIRST AID PROC: OXYGEN. ADMIN ARTF RESP IF VICTIM IS NOT
Ingred Name:SPILL PROC: DIKE/IMPOUND SPILLED LIQ. COVER SPILL W/ABSORB
SEWER. AVOID CONTACT WITH EYES AND SKIN.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: MOD IRRIT. MAY CAUSE
TEARING, REDDENING & REVERSIBLE CORNEAL INJURY. SKIN: SEV IRRIT.
PROD MAY CONTAIN TRACE AMTS OF A SKIN SENSITIZER. CONT MAY CAUSE
DERM, ALLERGIC RESPONSES, &, IN SENS ITIVE INDIVIDUALS, REDNESS,
SWELL & BLISTERS. INHAL: SEV IRRIT. PROD MAY CONTAIN TRACE AMTS OF
A RESP (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONO,
TO BE (SUP DAT)
Effects of Overexposure:HLTH HAZ: SENSITIZER. EXPOS TO EXCESS CONCS MAY
PRDCE IRRIT OF RESP TRACT, COUGHING, CHEST DISCOMFORT, SHORTNESS OF
BREATH. INDIVIDUALS W/PREEXISTING RESP CNDTNS CAN DEVELOP MORE SEV
SYMPS SUCH AS BRO NCH, BRONCH SPASMS, & PULM EDEMA (FLUIDIN LUNGS).
FOR MOST INDIVIDUALS, THESE EFTS ARE REVERSIBLE. (SUP DAT)
Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY OR SKIN
CONDITION(S) MAY BE AGGRAVATED BY EXPOSURE.
* First Aid Measures *
GENTLY HOLD EYELIDS OPEN DURING FLUSH. OBTAIN IMMED MED ATTN. SKIN:
REMOVE CONTAM CLTHG & SHOES. WASH AFFECTED AREA(S) THORO W/SOAP &
WATER. WIPE/FLUSH AFFECTED SKIN W/ISOPROPYL ALCOHOL (RUBBING
ALCOHOL). WASH AGAIN THORO W/SOAP & WATER. IF IRRIT PERSISTS, SEEK
MED ATTN. INHAL: MOVE TO FRESH AIR. IF VICTIM HAS DFCLTY BRTHG,
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:0.9%
Upper Limits:7.0%
Extinguishing Media:WATER SPRAY (FOG), FOAM, DRY CHEMICAL OR CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP .
CONTRS EXPOSED TO FIRE SHOULD BE KEPT COOL W/WATER SPRAY. WATER
STREAM DIRECTED INTO FIRE MAY CAUSE (SUP DAT)
Unusual Fire/Explosion Hazard:CLSD CONTRS MAY EXPLODE DUE TO BUILD-UP
OF PRESS WHEN EXPOSED TO HEAT. THERMAL DECOMP/COMBUST OF PROD MAY
GENERATE IRRITATING &/OR TOX GASES. VAP IS (SUP DAT)
* Accidental Release Measures *
Spill Release Procedures:VENT AREA & REMOVE ALL SOURCES OF IGNIT.
EVACUATE UNNEC PERS. WIPE UP SML SPILLS W/RAGS/TOWELS. PUT SPENT
RAGS/TOWELS IN LOOSELY COVERED CONTRS IN WELL-VENTILATED AREA. LGE
SPILLS SHOULD BE HANDLED CA REFULLY. PUT ON NIOSH APPRVD RESP
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT BREATHE VAPORS. AVOID CONTACT
WITH EYES, CLOTHING, AND SKIN. KEEP CONTAINER CLOSED WHEN NOT IN
USE. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DO NOT TAKE INTERNALLY. WEAR PROTECTIVE CLOTHING AT
ALL TIMES. USE ONLY WITH ADEQUATE VENTILATION.
* Physical/Chemical Properties *
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN N-BU AC
Solubility in Water:SLIGHT (<0.1%)
Appearance and Odor:SMOOTH PIGMENTED VISCOUS PASTE; TYPICAL PAINT
THINNER ODOR
Percent Volatiles by Volume:6-8
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, AMINES, STRONG OXIDANTS, STRONG BASES OR ACCIDS.
Stability Condition to Avoid:CONTACT WITH WATER VAPOR. SOURCES OF
IGNITION. LONG TERM EXPOSURE TO ELEVATED TEMPERATURES.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN,
HYDROGEN CYANIDE GAS, OTHER ACRID AND TOXIC FUMES.
* Disposal Considerations *
Waste Disposal Methods:REVIEW ALL LOCAL, STATE, AND FEDERAL REGULATIONS
CONCERNING HEALTH AND POLLUTION FOR APPROPRIATE DISPOSAL
PROCEDURES. DO NOT INCINERATE CLOSED CONTAINERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
Ventilation:USE PROCESS ENCLOSURE, LOCAL EXHAUST VENTILATION, OR OTHER
ENGINEERING CONTROLS TO CONTROL AIRBORNE LEVELS BELOW RECOMMENDED
EXPOSURE LIMITS.
FACESHIELD .
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
FIRST AID PROC: NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY.
MATLS TO AVOID: AMMONIUM IRON (III) SULFATE DODECAHYDRATE, AMMONI
UM TRIPERCHROMATE, ANILINE + GLYCEROL + NITROBENZENE, BENZYL
ALCOHOL, BROMATES + METALS, TERT-BUTYL-M- (OTHER INFO)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SULFURIC ACID
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
ACGIH STEL:3 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAUSES SEVERE EYE BURNS. MAY
CAUSE IRREVERSIBLE EYE INJURY. SKIN: CAUSES SKIN BURNS. INGESTION:
MAY CAUSE SEVERE AND PERMANENT DAMAGE TO THE DIGESTIVE TRACT.
CAUSES GASTROINTESTINAL TRACT BURNS . INHALATION: HARMFUL IF
INHALED, MAY CAUSE SEVERE IRRITATION OF THE RESPIRATORY TRACT WITH
SORE THROAT, COUGHING, SHORTNESS OF BREATH AND DELAYED LUNG EDEMA.
CAUSES CHEMICAL BURNS TO THE RESPIRATORY TRACT. CHRONIC: PROLONGED
OR REPEATED INHALATION MAY CAUSE NOSEBLEED, NASAL CONGESTION,
EROSION OF THE TEETH, PERFORATION OF THE NASAL SEPTUM, CHEST PAIN
AND BRONCHITIS. PROLONGED OR REPEATED EYE CONT ACT MAY CAUSE CONJ.
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM
TO RUB/KEEP EYES CLOSED. SKIN: GET MED AID IMMED. FLUSH SKIN
CLTHG & SHOES. SPEEDY ACTION IS CRITICAL! INGEST: DO NOT INDUCE
VOMIT. IF VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF
MILK/H*2O. NEVER GIVE ANY THING BY MOUTH TO UNCON PERS. GET MED AID
IMMED. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR
IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. DO NOT USE MOUTH- TO-MOUTH RESPIRATION. (SUPDAT)
* Fire Fighting Measures *
Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL. DO NOT GET
WATER INSIDE CONTAINERS. COOL CONTAINERS WITH FLOODING QUANTITIES
OF WATER UNTIL WELL AFTER FIRE IS OUT.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROT EQUIP .
STRONG OXIDIZER. CONTACT W/COMBUSTIBLE MATLS MAY CAUSE A FIRE.
CONTACT W/H*2O CAN CAUSE VIOLENT LIBERATION OF HEAT & SPLATTERING
OF THE MATERIAL. CONT ACT W/ METALS MAY EVOLVE FLAMMABLE HYDROGEN
GAS. CONTAINERS MAY EXPLODE WHEN HEATED OR IF CONTAMINATED W/H*2O.
Unusual Fire/Explosion Hazard:HEALTH: 3; FLAMMABILITY: 0; REACTIVITY:
2.
* Accidental Release Measures *
Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN SECTION 8. SPILLS/LEAKS:
CLEAN UP SPILLS IMMEDIATELY, OBSERVING PRECAUTIONS IN THE
PROTECTIVE EQUIPMENT SECTION. COVER WI TH SAND, DRY LIME OR SODA
ASH AND PLACE IN A CLOSED CONTAINER FOR DISPOSAL. USE WATER SPRAY
TO REDUCE VAPORS, DO NOT PUT WATER DIRECTLY ON LEAK, SPILL AREA OR
INSIDE CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:HANDLING: DO NOT GET IN EYES, ON SKIN,
OR ON CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. DO NOT INGEST OR
INHALE. DO NOT ALLOW CONTACT WITH WATER. USE ONLY IN A CHEMICAL
FUME HOOD. STORAGE: DO NOT STORE NEAR COMBUSTIBLE MATERIALS.
Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. STORE IN A
COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES.
DO NOT STORE NEAR ALKALINE SUBSTANCES.
* Physical/Chemical Properties *
Vapor Density:1.2 KG/M3
pH:0.3 (IN SOLN)
Viscosity:NEGLIBLE
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:SOL IN WATER & ETHANOL
Appearance and Odor:COLOURLESS LIQUID; ODORLESS.
Percent Volatiles by Volume:NEGLIBLE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACETIC ANHYDRIDE, ACETONE CYANHYDRIN, ACETONE + NITRIC ACID, ACETONE +
POTASSIUM DICHROMATE, ACETONITRILE + SULFUR TRIOXIDE, ACROLEIN,
ACRYLONITRILE, ALCOHOLS + HYDROGEN PEROXIDE, ALLYL ALCOHOL, ALLYL
CHLORIDE, 2-AMINOETHAN
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, CONTACT WITH
WATER, METALS, EXCESS HEAT, COMBUSTIBLE MATERIALS, ORGANIC
MATERIALS, OXIDIZERS, AMINES, BASED.
Hazardous Decomposition Products:OXIDES OF SULFUR.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
* Toxicological Information*
CONTAINED IN STRONG INORGANIC ACID MISTS): A2 - SUSPECTED. OSHA:
SELECT CARCINOGEN. IARC: GROUP 1 CARCINOGEN. WORKERS EXPOSED TO
INDUSTRIAL SULFURIC ACID MIST SHOWED A STATISTICAL INCREASE IN
LARYNGEAL CANCER. THIS DATA SUGGESTS A POSSIBLE RELATIONSHIP
BETWEEN CARCINOGENISIS & INHALATION OF SULFURIC ACID MIST.
TERATOGENICITY, REPRODUCTIVE EFFECTS, NEUROTOXICITY, MUTAGENICITY &
OTHER STUDIES: NO DATA AVAILABLE.
* Ecological Information *
Ecological:ECOTOXICITY: SULFURIC ACID IS HARMFUL TO AQUATIC LIFE IN
VERY LOW CONCENTRATIONS. IT MAY BE DANGEROUS IF IT ENTERS H*2O
HR, WHICH WA S LETHAL. ENVIRONMENTAL FATE, PHYSICAL/CHEM & OTHER:
NOT AVAIL CLEAN AIR ACT: THIS MATL DOES NOT CONTAIN ANY HAZ AIR
POLLUTANTS. THIS MATL DOES NOT CONTAIN ANY CLASS , OZONE DEPLETORS.
THIS MATL DOES NOT CONTAIN & CLASS 2 OZONE DEPLETORS. CLEAN WATER
CHEMS IN THIS PROD ARE LISTED AS PRIORITY POLLUTANTS UNDER CWA.
NONE OF CHEMS IN TH IS PRODUCT ARE LISTED AS TOX POLLUTANTS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION
OF CONTAMINANTS, RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS,
RCRA F-SERIES, RCRA P-SERIES, RCRA U-SERIES. NOT LISTED AS A
MATERIAL BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
* MSDS Transport Information *
Transport Information:US DOT: SHIPPING NAME: SULFURIC ACID. HAZARD
NO INFORMATION AVAILABLE. CANADIAN TDG: SHIPPING NAME: SUFLURIC
* Regulatory Information *
TSCA INVENTORY. HEALTH & SAFETY REPORTING LIST: NONE OF THE
CHEMICALS ARE ON THE HEALTH & SAFETY REPORTING LIST. CHEMICAL TEST
RULES: NONE OF THE CHEMICLS ALS INTHIS PRODUCT ARE UNDER A
CHEMICALS IN THIS MATERIAL HAVE A SNUR CHE MICAL UNDER TSCA.
State Regulatory Information:SULFURIC ACID CAN BE FOUND ON THE
FOLLOWING STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY,
FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE CHEMIC ALS IN THIS PRODUCT ARE
LISTED.
* Other Information *
| 1 | eyes_protection_mandatory |
Control Measures
*
Cage: 0TNM0
Proprietary Ind: Y
*
Contractor Summary
*
Cage: 0TNM0
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: TOXIC BY INGESTION OR INHALATION. CAUSES LETHARGY,
HEADACHE, GASTROINTESTINAL UPSET, ANEMIA, DAMAGE TO CNS, KIDNEY, LIVER, AND
TESTES. PRINCIPAL ROUTES OF ABSORPTION: DERMAL, INHALTION, ORAL, R EPEATED
EXPOSURE CAN HAVE CUMULATIVE EFFECT. NOT KNOWN TO BE CARCINOGENIC.
EXPERIMENTAL MUTAGENIC, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: TERATOGENIC, REPRODUCTIVE
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
PERSISTS, GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR, CALL
PHYSICIAN. INGESTION: GIVE WATER OR MILK AND INDUCE VOMITING I F CONSCIOUS.
CALL A PHYSICIAN.
*
Handling and Disposal
*
Spill Release Procedures: ELIMINATE IGNITION SOURCES, NEUTRALIZE WITH SODA ASH
OR TAKE UP WITH ABSORBENT.
Neutralizing Agent: SODA ASH.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL LOCAL, STATE, AND
FEDERAL REGULATIONS.
Other Precautions: KEEP CONTAINERS TIGHTLY CLOSED.
*
Fire and Explosion Hazard Information
*
Lower Limits: 2%
Extinguishing Media: WATER SPRAY, FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: WILL RELEASE TOXIC COMPOUNDS WHEN BURNING.
*
*
Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF
CONCERN (FP N).
Ventilation: USE IN WELL VENTILATED HOOD.
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
*
Physical/Chemical Properties
*
Vapor Density: 2.6
Spec Gravity: 0.9
PH: 6
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: SOLUBLE
Appearance and Odor: YELLOW LIQUID WITH SULFUR DIOXIDE ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: AVOID OXIDIZERS, IGNITION SOURCES, HEAT.
Materials To Avoid: AVOID OXIDIZERS, IGNITION SOURCES, HEAT.
Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Cage: 0TNM0
Company Name: GFS CHEMICALS INC
Label Required IND: Y
Status Code: C
Origination
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: TOXIC BY INGESTION OR INHALATION.
CAUSES LETHARGY, HEADACHE, GASTROINTESTINAL UPSET, ANEMIA, DAMAGE TO CNS,
KIDNEY, LIVER, AND TESTES. PRINCIPAL ROUTES OF ABSORPTION: DERMAL, INHAL
ATION, ORAL, REPEATED EXPOSURE CAN HAVECUMULATIVE EFFECT. CHRONIC:
EXPERIMENTAL MUTAGENIC, TERATOGENIC, REPRODUCTIVE EFFECTS.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE.
Ventilation:USE LOCAL EXHAUST.
Other Protective Equipment:SAFETY TOE SHOES FOR HANDING CYLINDERS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
AVOID THE USE OF OIL IN CYLINDER.
* Product Identification *
Product ID:OXYGEN GAS
CAGE:MINIF
CAGE:MINIF
* Composition/Information on Ingredients *
Ingred Name:OXYGEN
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL:ACUTE EYE IRRITATION AND CENTRAL
NERVOUS SYSTEM EFFECTS. CHRONIC: HYPOTHERMIA, LUNG DAMAGE.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:DIZZINESS, HEADACHE,DEPRESSION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:PROMPT MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF
OVEREXPOSURE TO OXYGEN. RESCUE PERSONNEL SHOULD BE EQUIPPED WITH
SELF-CONTAINED BREATHING APPARATUS. VICTIMS SHOULD BE ASSISTED TO
AN UNCONTAMINAT ED AREA AND INHALE FRESH AIR. UNCONSCIOUS PERSONS
SHOULD BE MOVED TO AN UNCONTAMINATED AREA, AND IF BREATHING HAS
STOPPED, ADMINISTER ARTIFICIAL RESUSCITATION AND SUPPLEMENTAL
OXYGEN.
* Fire Fighting Measures *
Extinguishing Media:NON-ELECTRICAL:WATER.ELECTRICAL:CARBON DIOXIDE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE CLOTHING. SHUT OFF OXYGEN GAS IF POSSIBLE. USE
WATER SPRAY TO KEEP FIRE EXPOSED CYLINDERS COOL.
Unusual Fire/Explosion Hazard:HIGH OXIDIZING ATMOSPHERES INCREASE
LIKELIHOOD OF FIRES. OXYGEN VIGOROUSLY SUPPORTS COMBUSTION.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE PERSONNEL. VENTILATE AREA. REMOVE
HEAT AND IGNITION SOURCES. ATTEMPT TO STOP RELEASE IF SAFE TO DO
SO. CAUTION SHOULD BE EXERTED FOR NOISE OR INJURY BY PROPELLED
MOTION OF CYLINDER IF LEAKING . VENT GAS TO ATMOSPHERE IN AN OPEN
AREA.
*Handling and Storage *
HEAT,SPARKS,FALMES AND INCOMPATIBLE MATERIALS.SECURE CYLINDERS WHEN
IN USE. CYLINDERS SHOULD BE STORED UPRIGHT.
Other Precautions:STORE AWAY FROM HEAVY TRAFFIC AND COMBUSTIBLE
MATERIALS. KEEP AWAY FROM HEAT SOURCES, SALT AND CORROSIVE
CHEMICALS.
* Physical/Chemical Properties *
HCC:G4
Vapor Density:1.1
Appearance and Odor:COLORLESS, ODORLESS GAS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
OTHER SOURCES OF IGNITION
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE
* Disposal Considerations *
Waste Disposal Methods:DO NOT ATTEMPT TO DISPOSE OF RESIDUAL OXYGEN IN
COMPRESSED GAS CYLINDERS. RETURN TO MANUFACTURER WITH THE CYLINDER
VALVE TIGHTLY CLOSED, POSITIVE PRESSURE IN THE CYLINDER, AND VALVE
CAP IN PLACE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME, VAPOR/DUST
RESPIRATOR/AIR SUPPLIED RESPIRATOR WHEN USING PRODUCTS/WHEN
WELDING/BRAZING/SOLDERING IN CONFINED SPACE/WHERE LOCAL
EXHAUST/VENTILATION DOESN'T KEEP EXPO SURE BELOW TLV.
Ventilation:LOCAL EXHAUST: TO KEEP THE FUMES & GASES BELOW THE TLV'S IN
THE WORKERS BREATHING ZONE & THE GENERAL AREA.
Other Protective Equipment:SAFETY EYEWASH STATION, CHEMICAL RESISTANT
APRONS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. USE GOOD HOUSEKEEPING PRACTICES. WASH HANDS AFTER HANDLING.
Supplemental Safety and Health
DON'T SMOKE, EAT/DRINK IN WORK AREA.
* Product Identification *
Preparer's Name:KEN HEARREAN
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. INHALATION: MAY
CAUSE IRRITATION OF THE RESPIRATORY TRACT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DISCOMFORT.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING & GIVE
OXYGEN IF NECESSARY. SKIN: CLEAN WIPES IS INTENDED FOR USE AS A
LARGE AMOUNTS O F WATER/MILK TO DILUTE. DON'T INDUCE VOMITING.
GASTRIC LAVAGE. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, WATER FOG, FOAM, CO2.
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. WATER
MAY BE USED TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:AEROSOL PRODUCTS ARE UNDER PRESSURE.
* Accidental Release Measures *
Spill Release Procedures:REMOVE SOURCES OF HEAT/IGNITION. WIPE UP
PRODUCTS W/A RAG/USE ABSORBENT SWEEPING COMPOUND & WASH AREA DOWN
W/SOAP & WATER. DISPOSE OF RESIDUE IN SEALED CONTAINERS. KEEP
AIRBORNE DUST AS A MINIMUM WHEN CLEANING UP. AVOID INHALATION OF
DUST.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. AVOID
EXTREME HEAT/COLD TO MAINTAIN QUALITY. VAPORS MAY COLLECT IN LOW
LYING AREAS. KEEP AWAY FROM HEAT/SPARKS/OPEN FLAMES.
Other Precautions:AVOID CONTACT W/EYES, SKIN/CLOTHING.
* Physical/Chemical Properties *
Vapor Density:0
Evaporation Rate & Reference:(BU AC = 1): <1
Solubility in Water:MISCIBLE
Appearance and Odor:VISCOUS OFF WHITE LIQUID(CLEAN WIPES IN SATURATED
TOWEL FORM)W/SWEET ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALINES, OXIDIZERS.
Stability Condition to Avoid:OPEN FLAMES, WELDING ARCS, HIGH HEAT
SOURCE.
* Disposal Considerations *
Waste Disposal Methods:DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE
CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER
IAW/FEDERAL, STATE & LOCAL REGULATIONS. DON'T PUNCTURE/INCINERATE
AEROSOL CONTAINERS. PRIME-CUT BIOLOGI CAL DECOMPOSITION IN SANITARY
SEWER IS ACCEPTABLE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED FOR NORMAL CONDITIONS.
Ventilation:PROVIDE ADEQUATE VENTILATION
Other Protective Equipment:FACESHIELD, IMPERVIOUS CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PETROLEUM OIL BASED STOCKS
Ingred Name:LITHIUM SOAP
Fraction by Wt: MIXTURE
Ingred Name:GRAPHITE
Other REC Limits:2.5MG/CUM
ACGIH TLV:2 MG/CUM RESP IC
Ingred Name:PRIMARY ADDITIVES
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NAUSEA
* First Aid Measures *
THOROUGHLY W/WATER & SOAP. INGESTION: DON'T INDUCE VOMITING. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:CO2, WATER FOG, DRY CHEMICAL/FOAM
Fire Fighting Procedures:USE APPROPRIATE MEDIA TO EXTINGUISH FIRE.
Unusual Fire/Explosion Hazard:CONTACT W/WATER WILL GENERATE HYDROGEN
GAS.
* Accidental Release Measures *
Spill Release Procedures:ABSORB SMALL LEAKS W/CLAY, DIATOMACEOUS
EARTH/OTHER INERT MATERIAL. LARGE: SHOULD BE SCRAPPED & PLACED IN
WASTE CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, VENTILATED AREAS AWAY
FROM EXCESSIVE HEAT & SOURCES OF IGNITION. AVOID STORAGE NEAR
STRONG OXIDANTS.
Other Precautions:KEEP CONTAINERS CLOSED WHEN MATERIAL IS NOT IN USE.
LIMIT EXPOSURE TO VAPORS, MISTS & FUMES. DON'T INGEST.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:FASTER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY SEMI-SOLID GREASE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, LIQUID CHLORINE, CONCENTRATED OXYGEN, SODIUM
HYPO CHLORITE & CALCIUM
Hazardous Decomposition Products:ACROLEING, VARIOUS ALDEHYDES, KETONES,
CO2, SMOKE, CO, ZINC OXIDE, SULFUR OXIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRABLE FUME
RESPIRATOR OR AIR SUPPLIED RESPIRATORS WHEN WORKING IN CONFINED
SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE
BELOW RECOMMENDED EXPOSURE LI MIT.
Ventilation:USE ENOUGH GENERAL VENT & LOCAL EXHAUST AT WORK SITE TO
KEEP FUMES, GASES/DUSTS FROM WORKER'S BREATHING ZONE & GEN AREA.
Other Protective Equipment:ARM PROTECTORS, APRONS, HATS, SHOULDER
PROTECTION, AS WELL AS DARK SUBSTANTIAL CLOTHING. PROVIDE PROT
Work Hygienic Practices:TRAIN WORKER TO KEEP HIS HEAD OUT OF THE FUMES.
Supplemental Safety and Health
HAZ DECOMP PRODS:PLUS THOSE FROM BASE METAL & COATING, ETC. AS NOTED.
REASONABLY EXPECTED CONSTITUENTS OF FUME WOULD INCLUDE COMPLEX
OXIDES OF METALS LISTED. GASEOUS RXN PRODS MAY INCL CARBON MONOXIDE
& CARBON DIOXIDE. OZONE & NITROGEN OXIDES MAY BE FORMED BY
RADIATION. EFTS OF OVEREXP:MANGANESE:LONG TERM (ING 6)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MANGANESE (SARA III)
OSHA PEL:(C) 5 MG/M3 DUST
Ingred Name:SILICON
Ingred Name:CARBON;(GRAPHITE, SYNTHETIC)
Ingred Name:SUPP DATA:OVEREXP TO MANGANESE CMPDS MAY AFFECT CNS. SYMPS
INCL MUSCULAR WEAKNESS, TREMORS SIMILAR TO PARKINSON'S(ING 7)
Ingred Name:ING 6:DISEASE. BEHAVORIAL CHANGES IN HANDWRITING MAY ALSO
APPEAR. EMPLOYEES EXPOSED TO MANGANESE CMPDS SHOULD GET(ING 8)
Ingred Name:ING 7:QUARTERLY MD EXAMS FOR EARLY DETECTION OF MANGANESE
POISONING. SILICON/SILICON DIOXIDE:OVEREXP TO AMORPHOUS(ING 9)
Ingred Name:ING 8:SILICA CAN CAUSE A PNEUMOCONIOSIS. CHROMIUM:STUDIES
Ingred Name:ING 9:HEXAVALENT CHROMIUM CMPDS HAVE AN EXCESS OF LUNG
EXPOS TO CHROMIUM (VI) MATLS. RADIA CAN INJURE EYES/BURN SKIN.
SUFFICIENT VIEW OF WORK.
Ingred Name:IRON (PEL/TLV FOR IRON OXIDE FUME AS FE)
ACGIH TLV:5 MG/M3
Ingred Name:CHROMIUM (SARA III)
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:OVEREXPOSURE TO FUMES, GASES AND
DUSTS MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA, OR
DRYNESS OR IRRITATION OF NOSE, THROAT OR EYES. SILICON:POSSIBLE EYE
IRRITANT. CHROMIUM:INHAL OF FUME W/CHROMIUM (VI) CMPDS CAN CAUSE
IRRIT OF RESP SYS, DMG TO LUNGS & ASTHMA LIKE SYMPS. SWALLOWING
(EFTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:CHROMIUM:KNOWN CARCINOGEN (NTP), GROUP 1
(IARC).
Effects of Overexposure:HLTH HAZ:CHROMIUM (VI) SALTS CAN CAUSE SEVERE
INJURY OR DEATH. DUSTS ON SKIN CAN FORM ULCERS. EYES MAY BE BURNED
BY CHROMIUM (VI) CMPDS. ALLERG RXNS LIKELY IN SOME PEOPLE FROM
CHROMIUM CMPDS. CHRONIC: OVEREXP TO FUMES, GASES, & DUSTS MAY LEAD
TO SIDEROSIS (IRON DEPOSITS IN LUNGS) & MAY AFFECT PULM FUNCTIONS.
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:SKIN:WASH WITH SOAP & WATER. EYE:REMOVE BY IRRIGATING
WELL-VENTILATED AREA. APPLY ARTIFICIAL RESPIRATION, IF NEEDED. CALL
MD. EMPLOY FIRS T-AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED
CROSS. INGEST:CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:METAL POWDER DUST MAY PRESENT A FIRE OR
EXPLOSION HAZARD UNDER FAVORABLE CONDITIONS OF PARTICLE SIZE,
DISPERSION AND STRONG IGNITION SOURCE.
* Accidental Release Measures *
Spill Release Procedures:CLEAN-UP BY VACUUMING, WET DUSTMOP, OR WET
CLEAN-UP. AVOID DUST GENERATION. USE AN APPROP FILTER WITH VACUUM
EQUIPMENT TO PREVENT AIRBORNE DUST LEVELS WHICH EXCEED PEL/TLV. IF
AIRBORNE DUST GENERATED, USE APPROP NIOSH/MSHA APPROVED RESP FOR
CLEANUP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:MAINTAIN EXPOSURE BELOW PEL/TLV. USE
INDUSTRIAL HYGIENE MONITORING TO ENSURE THAT USE OF PRODUCT DOES
NOT CREATE EXPOSURE EXCEEDING THE PEL/TLV.
Other Precautions:READ AND UNDERSTAND THE MANUFACTURERS INSTRUCTIONS
AND THE PRECAUTIONARY LABEL ON PRODUCT.
* Physical/Chemical Properties *
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DECOMP PRODS OF NORMAL OPER INCL THOSE
ORIGNINATING FROM VOLAT, RXN OR OXIDATION OF MATLS LISTED IN
INGREDS (SUPP DATA)
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
WITH FEDERAL, STATE AN D LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED
Ventilation:MECHANICAL(GENERAL) RECOMMENDED,LOCAL EXHAUST IF NEEDED
Other Protective Equipment:NONE NEEDED,BUT GOOD INDUSTRIAL HYGN PRCTC
SHOULD BE FOLLOWD
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:AMMONIUM BROMIDE
Ingred Name:ACETIC ACID (SARA III)
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NOT STATED BY THE MANUFACTURER.
Effects of Overexposure:MANUFACTURER STATES ITEM IS OF LOW HAZARD.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR, GIVE CPR/O*2 IF NEED;
RINSE MOUTH; GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY,
OR OTHER S YMPTOMS OF OVEREXPOSURE.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE
CONTR.
Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE IGNITION SOURCES. STOP LEAK.
EVACUATE AREA. DO NOT TOUCH SPILLAGE.SMALL SPILL: ABSORB WITH INERT
ABSORBENT. PLACE IN CLOSED CONTAINER. FLUSH AREA WITH WATER. LARGE
SPILL: DIKE AHEAD FOR LATE R DISPOSAL. NOTIFY AUTHORITIES.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
Other Precautions:AVOID CONTACT W/SKIN,EYES & CLOTHINGS. AVOID STORAGE
NEAR STRONG ALKALIS.
* Physical/Chemical Properties *
HCC:N1
Vapor Density:0.6
pH:2.0
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS SOLUTION; SLIGHT ACETIC ACID ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT KNOWN
Stability Condition to Avoid:EXCESSIVE HEAT
Hazardous Decomposition Products:MAY EMIT, AMMONIA, BROMIN AND HYDROGEN
BROMIDE GASES & ALSO OXIDES OF CARBON,NITROGEN ON COMBSTION
* Disposal Considerations *
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
(ACRYLONITRILE/BUTADIENE/STYRENE RESIN)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 0-2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 0-2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: <0.3
------------------------------
% Wt: <0.1
------------------------------
ACGIH TLV: 2 PPM, A2, S
------------------------------
SUPPLIED, MONOMER IS NOT LIKELY TO BE
-----------------------------
MONOMER MAY BE RELEASED DURING PROCESSING
-----------------------------
DEPENDING ON ACTUAL EXPOSURE CONDITIONS.
-----------------------------
-----------------------------
OVER MANAGEMENT PRACT/MFG PROCESSES
-----------------------------
ONLY TO PROD AS SHIPPED IN ITS INTENDED
-----------------------------
PROD, PREF OPTIONS INCLUDE SENDING TO LICENSED,
-----------------------------
DEVICE, & LANDFILL. AS SERVICE TO ITS
-----------------------------
REPROCESS/MANAGE CHEMICALS/PLASTICS, &
-----------------------------
-----------------------------
FROM PROCESSING MACHINE IS THEREFORE RECOMMENDED.
-----------------------------
-----------------------------
CARCINOGENIC. ANIMAL: LIVER.
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: EYES: SOLID/DUST MAY CAUSE IRRIT/CORNEAL INJURY DUE
TO MECH ACTION. SKIN: ESSENTIALLY NON-IRRITATING. MECH INJURY ONLY. SKIN
ABSORPTION IS UNLIKELY DUE TO PHYSICAL PROPERTIES. INGEST: SINGLE DO SE ORAL
TOX CONSIDERED TO BE EXTREMELY LOW. NO HAZS ANTIC FROM SWALLOWING SML AMTS
INCIDENTAL TO NORM (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: STYRENE: IARC MONOGRAPHS, SUPPLEMENT, VOLUME 7,
Signs And Symptions Of Overexposure: HLTH HAZ: HDNLG OPERATIONS. INHAL: DUST
MAY CAUSE IRRIT TO UPPER RESP TRACT. SYSTEMIC (OTHER TARGET ORGAN) EFTS:
ADDITIVES ARE ENCAPSULATED IN PROD & ARE NOT EXPECTED TO BE RELEASED
UNDER NORM PROCESS ING CNDTNS/FORESEEABLE EMER. VERY SML QTYS OF MONOMER, AS
INDICATED IN ING SECTION, ARE NOT EXPECTED TO CAUSE
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
SKIN: WASH OFF IN FLOWING WATER/SHOWER. INGEST: IF SWALLOWED, SEEK MED ATTN.
DO NOT INDUCE VOMIT UNLESS DIRECTED TO DO SO BY MED PERS . INHAL: REMOVE TO
FRESH AIR IF EFTS OCCUR. CONSULT MD. NOTE TO MD: NO SPECIFIC ANTIDOTE.
SUPPORTIVE CARE. TREATMENT BASED ON JUDGMENT OF MD IN RESPONSE TO REACTIONS
OF PATIENT.
*
Handling and Disposal
*
Spill Release Procedures: PROTECT PEOPLE: PELLETS OR BEADS MAY PRESENT A
SLIPPING HAZARD. PROTECT ENVIRONMENT: KEEP OUT OF IRRIGATION DITCHES, SEWERS,
AND WATER SUPPLIES. SPILLS SHOULD BE COLLECTED TO PREVENT CONTAMINATION OF
WATERWAYS. CLEANUP: SWEEP UP.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DO NOT PUMP INTO ANY SEWERS, ON GROUND/INTO ANY BODY OF
WATER. ALL DISP METHS MUST BE IN COMPLIANCE W/ALL FED, STATE & LOC LAWS
& REGS. REGS MAY VARY IN DIFFERENT LOCATIONS. WASTE CHARACTERIZATIONS
& COMPLIANCE W/APPLIC LAWS ARE THE
Handling And Storage Precautions: WORKERS SHOULD BE PROTECTED FROM POSS OF CONT
W/MOLTEN RESIN DURING FABRICATION. MECH HNDLG EQUIP CAN CAUSE FORM OF DUSTS.
MAINTAIN GOOD HOUSEKEEPING.
Other Precautions: DUST LAYERS SHOULD NOT BE PERMITTED TO ACCUM IN ORDER TO
AVOID ANY POTENTIAL FOR DUST EXPLO HAZS. I/A/W GOOD MFR PRACT, GOOD GEN VENT
OF POLYMER PROCESSING AREA IS REC. AT TEMPS EXCEEDING MELT TEMP PO LYMER
DECOMP CAN OCCUR.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NONE
Extinguishing Media: WATER, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). SOAK THOROUGHLY WITH WATER TO COOL AND PREVENT REIGNITION.
Unusual Fire/Explosion Hazard: DENSE SMOKE IS EMITTED WHEN BURNED W/OUT
SUFFICIENT OXYGEN. MECH HNDLG CAN CAUSE FORM OF DUSTS. TO REDUCE POTENTIAL
FOR DUST EXPLO, DO NOT PERMIT DUST (SUP DAT)
*
*
Respiratory Protection: ATMOSPHERIC LEVELS SHOULD BE MAINTAINED BELOW THE
EXPOSURE GUIDELINE. WHEN RESPIRATORY PROTECTION IS REQUIRED FOR CERTAIN
OPERATIONS, USE A NIOSH APPROVED AIR-PURIFYING RESPIRATOR. IN DUSTY
ATMOSPHERE S, USE A NIOSH APPROVED DUST RESPIRATOR.
Ventilation: PROVIDE GENERAL AND/OR LOCAL EXHAUST VENTILATION TO CONTROL
AIRBORNE LEVELS BELOW THE EXPOSURE GUIDELINES.
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). WEAR CLEAN BODY-COVERING CLOTHING.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLOSION HAZARDS: TO ACCUMULATE. HAZARDOUS
COMBUSTION PRODUCTS MAY INCLUDE AND ARE NOT LIMITED TO: CARBON DIOXIDE,
CARBON MONOXIDE, ACRYLONITRILE, HYDROGEN CYANIDE, NITROGEN OXIDES. HAZARDOUS
DECOMPO SITION PRODUCTS: AT TEMPERATURES EXCEEDING MELT TEMPERATURES POLYMER
FRAGMENTS CAN OCCUR.
*
Physical/Chemical Properties
*
Solubility in Water: NIL
Appearance and Odor: MILKY WHITE OR COLORED SOLID WITH NO ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: PROCESSING MAY RELEASE FUMES WHICH MAY
INCLUDE POLYMER FRAGMENTS & OTHER DECOMP PRODS. FUMES CAN BE IRRITATING.(SUP
DAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: DOW CORNING CORP
Label Required IND: Y
Status Code: C
Origination
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYES: SOLID OR DUST MAY CAUSE IRRITATION OR
CORNEAL INJURY DUE TO MECHANICAL ACTION. SKIN: ESSENTIALLY NON-IRRITATING.
MECHANICAL INJURY ONLY. SKIN ABSORPTION IS UNLIKELY DUE TO PHYSICAL PROPER
TIES. INGESTION: SINGLE DOSE ORAL TOXICITY CONSIDERED TO BE EXTREMELY LOW. NO
HAZARDS ANTICIPATED FROM SWALLOWING SMALL AMOUNTS INCIDENTAL TO NORMAL
HANDLING OPERATIONS. INHALATION: DUST MAY CAUSE IRR ITATION TO UPPER
RESPIRATORY TRACT. CHRONIC: CANCER HAZARD. CONTAINS STYRENE AND
ACRYLONITRILE, WHICH ARE LISTED AS ANIMAL NERVOUS SYSTEM AND LIVER
CARCINOGENS (FP N).
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN XEROX
EQUIPMENT. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:OVERLOADING," A GENERIC RESPONSE TO EXCESSIVE AMOUNTS
OF ANY DUST RETAINED IN THE LUNGS FOR A PROLONGED INTERVAL. THE
SPECIAL TEST TONER WAS TEN TIMES MORE RESPIRABLE THAN COMMERICALLY
AVAILABLE XEROX TONER TO COMPLY WITH EPA TESTING PROTOCOL AND WOULD
NOT FUNCTION PROPERLY IN XEROX EQUIPMENT.
* Product Identification *
CAGE:0E6G9
CAGE:0E6G9
* Composition/Information on Ingredients *
Ingred Name:CARRIER (CONTAINING ING 2 & 3)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:KAOLIN; (CU-ZN FERRITE POWDER)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:STYRENE ACRYLIC POLYMER; (STYRENE/ACRYLOYL/ACRYLATES
POLYMER)
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TONER (CONTAINING ING 5-7)
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:COPPER, (PHTHALOCYANINATO)(2-))-; (BLUE PIGMENT)
Fraction by Wt: 4-8%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Fraction by Wt: <2%
Ingred Name:SPILL PROC:REDUCE STATIC BUILDUP (SEE FIRE & EXPLOSION DATA
SECTION). RESIDUE CAN BE REMOVED W/SOAP & COLD H*2O.(ING 9)
Ingred Name:ING 8:GARMENTS MAY BE WASHED OR DRY CLEANED, AFTER REMOVAL
OF LOOSE TONER.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MINIMAL RESPIRATORY TRACT IRRITATION
MAY OCCUR AS WITH EXPOSURE TO LARGE AMOUNTS OF ANY NON-TOXIC DUST.
ADDITIONAL INFORMATION:THE INFORMATION NOTED ABOVE IS TOXICITY DATA
FOR TONER. IN A XEROX SPONSO RED CHRONIC INHALATION STUDY IN RATS
USING A SPECIAL TEST TONER, THERE WERE NO LUNG CHANGES AT ALL IN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:LOWEST EXPOS LEVEL (1MG/M3), MOST
RELEVANT LEVEL TO POTENTIAL HUMAN EXPOS. A VERY SLIGHT DEGREE OF
WHILE SLIGHT DEGREE OF F IBROSIS WAS OBSERVED AT HIGHEST EXPOS
"LUNG (SUPDAT)
Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY
PRODUCT LITERATURE IN FIRE AND EXPLOSION DATA AND SPECIAL
PROTECTION INFORMATION.
* First Aid Measures *
WITH SOAP AND WATER. INHALATION: REMOVE FROM EXPOSURE. INGESTION:
DILUTE STOMACH CONTENTS WITH SEVERAL GLASSES OF WATER.
* Fire Fighting Measures *
Extinguishing Media:WATER, DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . AVOID INHALATION OF SMOKE.
Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. LIKE MOST
ORGANIC MATERIALS IN POWDER FORM, WHEN DISPERSED IN AIR, IT CAN
FORM EXPLOSIVE MIXTURES.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP/VACUUM SPILLED TONER & CAREFULLY
TRANSFER INTO SEALABLE WASTE CNTNR. SWEEP SLOWLY TO MIN GENERATION
OF DUST DURING CLEAN UP. IF VACUUM IS USED, MOTOR MUST BE RATED AS
DUST TIGHT. CONDUCTIVE H OSE BONDED TO MACHINE SHOULD BE USED
TO(ING 8)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NONE.
Other Precautions:AVOID PROLONGED INHALATION OF DUST. FOR USE OTHER
THAN NORMAL CUSTOMER-OPERATING PROCEDURES (SUCH AS IN BULK TONER
MAY BE REQUIRED. FO R MORE INFORMATION, CONTACT XEROX.
* Physical/Chemical Properties *
Appearance and Odor:BLUE POWDER/FAINT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC.
AVOID BREATHING SMOKE.
* Disposal Considerations *
Waste Disposal Methods:WHEN DISP, THIS MATL IS NOT HAZ WASTE ACCORDING
MORE RESTRICTIVE. THEREFORE, CONSULTATION W/APPROP FEDERAL, STATE &
LOCAL WASTE DISP AUTH IS ADVISED. INCINERATE ONLY IN CLOSED CNTNR.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:TYPICAL USE OF THIS PRODUCT DOES NOT REQUIRE A
SPECIAL RESPIRATOR.
Ventilation:GENERAL EXHAUST IS MORE THAN ADEQUATE TO PROTECT WORKER
FROM EXPOSURE TO LEVELS ABOVE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:APRON
Supplemental Safety and Health
PH:8.5-9.5.ROUTES OF ENTRY:INHALATION,INGESTION .
* Product Identification *
Preparer's Name:BOB SILVA
* Composition/Information on Ingredients *
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF
OVEREXPOSURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:CAN CAUSE IRRITATION IF UNDILUTED PRODUCT
IS DIRECTLY INTRODUCED INTO THE EYE.MARKED IRRITATION ON
DIRECT,CHRONIC EXPOSURE.SKIN/INGESTION/INHALATION:N/K .
Medical Cond Aggravated by Exposure:N/K
* First Aid Measures *
APART OCCASIONALLY.SEEK MEDICAL ATTENTION IF IRRITATION
PERSISTS.SKIN:APPLY HAND CREAM AFTER LONG-TERM EXPOSURE.IF
IRRITATION PERSISTS,SEEK M EDICAL ATTENTION.INGESTION:GIVE TWO
GLASSES OF WATER AND SEEK MEDICAL ATTENTION IF LARGE AMOUNT HAS
BEEN SWALLOWED.INHALATION:NOT A HAZARD (MFR).
* Fire Fighting Measures *
Flash Point Method:TCC
Flash Point:NONFLAMMABLE
Extinguishing Media:USE FOAM,ALCOHOL FOAM,CARBON DIOXIDE,DRY
CHEMICAL,WATER SPRAY.CHOICE OF EXTINGUISHING MEDIA DEPENDS ON
NATURE OF FIRE.
Fire Fighting Procedures:PRODUCT IS NONFLAMMABLE.CHOICE OF
EXTINGUISHING MEDIA DEPENDS ON NATURE OF FIRE.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL AND PICK UP MATERIAL.REUSE IF
POSSIBLE.PLACE INTO LABELED CONTAINERS.FLUSH REMAINDER DOWN DRAIN
WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:N/K
*Handling and Storage *
Handling and Storage Precautions:KEEP OUT OF EYES.STORE BETWEEN
COMPOUNDS.MIXING MAY FORM NITROSAMINES.
Other Precautions:READ ENTIRE LABEL BEFORE USING PRODUCT.KEEP OUT OF
REACH OF CHILDREN.
* Physical/Chemical Properties *
Decomp Temp:Decomp Text:N/K
Vapor Density:0.6,AIR=1
pH:SUP DA
Solubility in Water:COMPLETE
Appearance and Odor:TRANSPARENT,SEMI-VISCOUS,FLUORESCENT
YELLOW-GREEN;SLIGHTLY SWEET ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
DO NOT MIX WITH NITRATE OR NITRITE COMPOUNDS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IAW FEDERAL,STATE AND LOCAL
REGULATIONS .INGREDIENTS NOT REGULATED AS HAZARDOUS MATERIALS BY
EPA.PRODUCT MAY BE FLUSHED TO SANITARY SEWER.AFTER USE IT WILL BE
NECESSARY TO SKIM TRAMP OIL & ELIMINATE SOLIDS BEFORE FLUSHING.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE A NIOSH APPROVED PARTICULATE FILTER
Ventilation:LOCAL & MECHANICAL EXHAUST RECOMMENDED
Other Protective Equipment:NOT REQUIRED
Supplemental Safety and Health
* Product Identification *
Product ID:ACTIVATED CARBON TYPE: FORMASORB
Preparer's Name:MOHAMMED A BAYATI
* Composition/Information on Ingredients *
Ingred Name:CARBON, ACTIVATED CARBON, GRAPHITE
Ingred Name:POTASSIUM IODIDE, POTIDE, HYDRIOCIC ACID, POTASSIUM SALT
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SLIGHT IRRITATION OF EYES & NOSE MAY
RESULT FROM CONTACT W/CARBON FINES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SLIGHT IRRITATION OF EYES & NOSE MAY RESULT
FROM CONTACT W/CARBON FINES.
* First Aid Measures *
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:FLOOD W/PLENTY OF WATER/INERT GAS, NITROGEN, CO2
Fire Fighting Procedures:NONE
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP UNUSED CARBON & DISCARD IN REFUSE
CONTAINER/REPACKAGE FOR FURTHER USE.
*Handling and Storage *
Handling and Storage Precautions:AVOID GENERATION OF DUST & FINES
DURING HANDLING.
Other Precautions:AVOID CONTACT W/HIGH CONCENTRATION OF KETONE IN
AIR/LIQUID. WET ACTIVATED CARBON REMOVE OXYGEN FROM AIR CAUSING A
SEVERE HAZARD TO WORKERS IN CARBON VESSELS/ENCLOSED/CONFINED
SPACES. BEFORE ENTERING S UCH PLACES, ENSURE AMPLE OXYGEN.
* Physical/Chemical Properties *
Spec Gravity:1.9-2.2
Appearance and Odor:BLACK GRANULAR/POWDER W/NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS; OZONE, LIQUID OXYGEN, CHLORINE, PERMANGANATE & KETONE
Hazardous Decomposition Products:CO
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE RESPIRATORY PROTECTION IS REQUIRED, USE
ONLY NIOSH/MSHA APPROVED RESPIRATORS.
Ventilation:DILUTION/LOCAL EXHAUST TO PREVENT BUILD UP OF VAPORS. USE
EXPLOSION PROOF EQUIPMENT.
Other Protective Equipment:EYE WASH, SAFETY SHOWER, IMPERVIOUS
CLOTHING, APRON, BOOTS(POLY VINYL CHLORIDE/NITRILE).
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DISPOSE OF CONTAMINATED LEATHER ITEMS SUCH AS SHOES & BELTS.
Supplemental Safety and Health
WASH HANDS THOROUGHLY AFTER HANDLING/BEFORE EATING/SMOKING. FIRE HZRD:
VAPORS ARE > THAN AIR & MAY TRAVEL LONG DISTANCES TO SOURCE OF
IGNITION & FLASH BACK. HLTH HZRD: OVEREXPOSURE TO SOLVENTS MAY CAU
SE PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. MATERIALS: HALOGENATED
COMPOUNDS/SODIUM/POTASSIUM. SPILLS: KEEP SALVAGEABLE.
* Product Identification *
* Composition/Information on Ingredients *
W/ETHYLENEDIAMINE/PENTAERYTHRIOTOL/PHTHALIC ANHYDRIDE & TALL-OIL
Ingred Name:FATTY ACIDS, TALL-OIL, POLYMER W/GLYCEROL, PENTAERYTHRITOL
Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS
Fraction by Wt: 1-5%
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/CUM
ACGIH TLV:3.5 MG/CUM
Fraction by Wt: 0.1-1%
OSHA PEL:0.1 MG/CUM
Ingred Name:CHLOROTHALONIL; TETRACHLOROISOPHTHALONITRILE; DACONIL;
Fraction by Wt: 1-5%
Ingred Name:LINSEED OIL
Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS
Fraction by Wt: 1-5%
Fraction by Wt: 1-5%
Ingred Name:BENZENE (HUMAN CARCINOGEN BY IARC GROUP 1, OSHA, NTP &
OSHA PEL:1 PPM
ACGIH TLV:0.5 MG/CUM (A1)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY
TRACT, MUCOUS MEMBRANES, CNS DEPRESSION, ANESTHETIC EFFECT,
PNEUMOCONIOSIS, ASPHYXIATION/DEATH. SKIN: IRRITATION/DERMATITIS,
ABSORPTION, BURNS. EYES: IRRITATION/B URNS. INGESTION: LUNG
INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS, CNS
DEPRESSION. (SEE SUPP)
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, FATIGUE, DROWSINESS, DIZZINESS,
LIGHTHEADEDNESS, HEADACHE, UNCOORDINATION, NAUSEA, VOMITING,
COUGHING, SNEEZING, NUMBNESS, RESPIRATORY PROBLEMS, NARCOSIS,
ALLERGIC RESPONSE, LOSS OF CONSCI OUSNESS, DEFATTING, BURNS,
BLURRED VISION, REDNESS, TEARING, DIARRHEA, GI DSTURBANCES,
DIFFICULTY BREATHING.
Medical Cond Aggravated by Exposure:EYES, SKIN, RESPIRATORY & LUNG
DISORDERS, ASTHMA-LIKE CONDITIONS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT BREATHING.
HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. SKIN: FLUSH W/WATER,
THEN WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:DRY CHEMICAL/FOAM, WATER FOG, CO2.
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT
CONTAINERS. USE FULL PROTECTIVE CLOTHING & SCBA.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT/FIRE. VAPORS MAY IGNITE EXPLOSIVELY AT
AMBIENT TEMPS & FORM EXPLOSIVES MIXTURES IN AIR. (SEE SUPP)
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. VENTILATE AREA.
COLLECT W/ABSORBENT MATERIALS. EVACUATE & PLACE COLLECTED MATERIAL
IN PROPER CONTAINER. LARGE: SHUT OFF LEAK SAFELY. DIKE & CONTAIN.
PUMP TO STORAGE/SALV AGE VESSELS. USE ABSORBENT TO PICKUP
RESIDUE.(SUPP
*Handling and Storage *
SPARKS & OPEN FLAME. USE ONLY W/ADEQUATE VENTILATION. KEEP
CONTAINERS TIGHTLY CLOSED & UPRIGHT WHEN NOT IN USE.
Other Precautions:DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
AVOID CONTACT W/SKIN & EYES. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING & INHALING THE CONTENTS MAY BE HARMFUL/FATAL. GROUND
EQUIPMENT WHEN TRANSFERRING.
* Physical/Chemical Properties *
Appearance and Odor:BLACK
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS/ACIDS/BASES/AMINES/ALKALIS
WATER/ALUMINUM/ZINC/HYPOCHLORITES/PEROXIDES/NITRIC
ACID/HYDRAZIDES/MAGNESIUM.(SUPP)
Stability Condition to Avoid:SUNLIGHT, ELEVATED TEMPS, SPARKS, OPEN
FLAME & IGNITION SOURCES.
Hazardous Decomposition Products:CO, CO2, OXIDES OF NITROGEN, ACROLEIN,
OXIDES OF SULFUR, AMMONIA, OXYGEN, HYDROGEN CHLORIDE, ALDEHYDES,
TOXIC GASES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR IF
VENTILATION DOES NOT MAINTAIN INHALATION EXPOSURES BELOW PEL/TLV.
WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR HIGH LEVELS
OF CONTAMINATES.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
Other Protective Equipment:INDUSTRIAL-TYPE WORK CLOTHING, HAT AND APRON
AS REQUIRED.
Work Hygienic Practices:USE WITH ADEQUATE VENTILATION. AVOID BREATHING
VAPOR/SPRAY MIST. AVOID CONTACT WITH SKIN & EYES. WASH HANDS AFTER
USE.
Supplemental Safety and Health
THIS PRODUCT HAS UNDERGONE SEVERAL FORMULATION CHANGES. INFORMATION FOR
THESE ARE PROVIDED UNDER OTHER P/N INDS., THIS NSN.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TOLUENE (SARA III)
Other REC Limits:NONE SPECIFIED
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Other REC Limits:NONE SPECIFIED
Ingred Name:MINERAL SPIRITS
Other REC Limits:NONE SPECIFIED
Ingred Name:DICHLORODIFLUOROMETHANE (SARA III)
Other REC Limits:NONE SPECIFIED
Ozone Depleting Chemical:1
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VAPORS IN HIGH CONCENTRATION ARE
ANESTHETIC. OVEREXPOSURE MAY RESULT IN FATIGUE, WEAKNESS, CONFUSION
EUPHORIA, DIZZINESS, HEADACHE, DILATED PUPILS, LACRIMATION,
NERVOUSNESS, MUSCLE FATIGUE, INSOMNIA, PARESTHESIA, DERMATITIS,
AND PHOTOPHOBIA.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:POSSIBLE DIZZINESS OR NAUSEA
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN,
RESPIRATORY TRACT OR NERVOUS SYSTEM MAY BE AT INCREASED RISK FROM
EXPOSURE.
* First Aid Measures *
EYELID. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP &
WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ADVICE.
INHALATION: REMOV E TO FRESH AIR. GIVE MOUTH-TO-MOUTH RESUSCITATION
IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE
VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET MEDICAL
ATTENTION IMMEDIATELY.
* Fire Fighting Measures *
Flash Point:N/R, AEROSOL
Lower Limits:1
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY. CONTAIN RUNOFF.
Unusual Fire/Explosion Hazard:DO NOT SPRAY ;NEAR OPEN FLAME. KEEP AT
ROOM TEMPERATURE AS EXPOSURE TO DIRECT SUNLIGHT OR OTHER HEAT MAY
CAUSE BURSTING.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:CONTENTS ARE FLAMMABLE. KEEP AWAY FROM
HEAT, SPARKS, AND OPEN FLAME. DURING USE AND UNTIL ALL VAPORS ARE
GONE: KEEP AREA VENTILATED-DO NOT SMOKE.
Other Precautions:THIS COATING CONTAINS MATERIALS CLASSIFIED AS
NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZARDOUS LEVELS ONLY
DURING SANDING OR ABRADING OF THE DRIED FILM. INTENTIONAL MISUSE BY
INHALING CONCENTRA TED VAPORS CAN BE HARMFUL OR FATAL.
* Physical/Chemical Properties *
HCC:V3
Vapor Density:>1
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AEROSOL PAINT CAN, MODERATELY SHARP, FRAGRANT,
MINT- OR ACETONE-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON MONOXIDE AND TOXIC
FUMES OF CHLORIDES AND FLUORIDES.
* Disposal Considerations *
Waste Disposal Methods:DO NOT INCINERATE. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS REGARDING POLLUTION.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR A NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS IN HIGH USE CONCENTRATION.
Ventilation:NOT APPLICABLE.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: 2%
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (PETROLEUM DISITLLATES)
Fraction by Wt: 1%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES, SKIN, INGESTION, &
INHALATION IRRITATION. CHRONIC: PROLONGED & REPEATED CONTACT MAY
CAUSE IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SKIN AND EYE: MAY CAUSE IRRITATION. INGEST: MAY
CAUSE STOMACH DISTRESS, NAUSEA OR VOMITING.
Medical Cond Aggravated by Exposure:NONE.
* First Aid Measures *
REMOVE CONTACT LENSES. SKIN: FLUSH SKIN WITH SOAP AND WATER.
INGESTION: RINSE MOUTH, THEN DRINK 1 OR 2 LARGE GLASSES OF WATER.
INHALATION: M OVE TO FRESH AIR.
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY FLASH BACK. TREAT AS OIL FIRE.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILLED PRODUCT TO PREVENT
ENVIROMENTAL CONTAMINATION. KEEP OUT OF STORM SEWERS OR SURFACE
WATERS. SMALL AMOUNTS SHOULD BE SWEPT OR MOPPED UP & USED FOR
RELATING CLEANING TASKS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN ORGINAL CNTNR IN A COOL, DRY
PLACE AWAY FROM INCOMPATIBLE. AVOID INGEST & INHALATION. WEAR
APPROPRIATE EQUIPMENT TO AVOID EYE & SKIN CONTACT.
Other Precautions:SPILLS:LRG AMTS SHOULD BE ABSORBED ON VERMICULATE,
CLAY, ETC. & DISPOSED OF AS INDUSTRIAL WASTES. IF SPILLED MATL HAS
BEEN DISCHARGED INTO EVIR NOTIFY STATE FED & AGENCIES.
* Physical/Chemical Properties *
Solubility in Water:MISCIBLE
Appearance and Odor:MILKY WHITE LIQUID; PREFUMED ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, HEAT, OPEN FLAMES, SOURCES OF IGNITION.
Stability Condition to Avoid:HEAT, OPEN FLAMES, SOURCES OF IGNITION.
Hazardous Decomposition Products:NOT APPLICABLE.
* Disposal Considerations *
Waste Disposal Methods:CONSULT STATE AND LOCAL AUTHORITIES FOR
RESTRICTIONS ON DISPOSAL OF CHEMICAL WASTE. REGISTRATION OF WASTES
IS GENERALLY REQUIRED BY LAW PRIOR TO TRANSPORTATION OR DISPOSAL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. USE NIOSH
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:GEN VENT & LOC EXHST REC. THIS IS A SOLV BASED PROD & AS
SUCH PROPER VENT IS REQUIRED. BUILD UP OF FUMES/MISTS (SUP DAT)
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:MAINTAIN HIGH STANDARD OF PERSONAL HYGIENE.
Supplemental Safety and Health
VENT: IN WORKING ATM MUST BE PREVENTED. ELEC & MECH EQUIP SHOULD BE
SPARK-PROOF.
* Product Identification *
Product ID:MOTOR OIL
DIV
* Composition/Information on Ingredients *
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (LIGHT HYDROTREATED
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONT WILL CAUSE SKIN & EYE
IRRIT. ELEVATED TEMPS/MECH ACTION MAY FORM VAPS, MISTS/FUMES WHICH
MAY BE IRRITATING TO EYES, NOSE, THROAT & UPPER RESP TRACT.
CHRONIC: MAY CAUSE DERM & DEFAT. INTENS IVE EXPOS MAY CAUSE CNS
DEPRESS WHICH MAY LEAD TO LOSS OF COORD & IMPAIRED JUDGMENT. PRLNG
EXPOS MAY RSLT IN UNCON.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MINUTES. CONSULT MD IF IRRIT DEVELOPS. SKIN: REMOVE CONTAMINATED
CLOTHING IMMED & WASH BEFORE REUSE. WASH AFFECTED AREAS IMMED
W/SOAP & WAT ER. CONSULT MD IF IRRIT DEVELOPS. INGEST: SEEK IMMED
MEDICAL ATTENTION. DO NOT INDUCE VOMITING BECAUSE OF RISK OF ASPIR.
INHAL: MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CONSULT MD.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:CARBON DIOXIDE, DRY POWDER, SAND.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER MAY CAUSE FROTHING, ONLY USE TO COOL FIRE-EXPOSED
SURFACES.
Unusual Fire/Explosion Hazard:HAZARDOUS COMBUSTION PRODUCTS: OXIDES OF
CARBON. PROTECT PERSONNEL, AND/OR SUPPRESS EXPLOSIVE VAPORS.
* Accidental Release Measures *
Spill Release Procedures:PREVENT ENTRY INTO WATER SOURCES. SOAK UP WITH
A SUITABLE ABSORBENT SUCH AS SAND OR DIATOMACEOUS EARTH.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID REPEATED AND PROLONGED SKIN
CONTACT. PREVENT EYE CONTACT. AVOID BREATHING MISTS OR VAPORS.
Other Precautions:STORE IN A COOL, DRY WELL-VENTILATED AREA, AWAY FROM
HEAT AND IGNITION SOURCES. KEEP DRUMS AND CONTAINERS CLOSED WHEN
NOT IN USE. COMBUSTIBLE LIQUID. KEEP AWAY FROM HEAT.
* Physical/Chemical Properties *
Solubility in Water:INSOLUBLE
Appearance and Odor:LIQUID BLUE OIL, WITH PETROLEUM ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MAY REACT WITH STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE AND
CARBON DIOXIDE ARE PRODUCED ON COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN APPROVED INCINERATOR OR USE
LICENSED WASTE DISPOSAL FACILITY. DISPOSE OF IN ACCORDANCE W/LOCAL,
STATE & FEDERAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOS MAY/DOES EXCEED OCCUP EXPOS LIM USE
EITHER NIOSH/MSHA APPRVD ATM-SUPP RESP OR NIOSH/MSHA PPRVD
AIR-PURIFYING RESP FOR ORG V APS & PARTICULATES.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO MIN SKIN
CONTACT. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Work Hygienic Practices:WASH WITH SOAP & WATER BEFORE EATING, DRINKING,
SMOKING/USING TOILET FACILITIES. LAUNDER CONTAMINATED CLOTHING (ING
Supplemental Safety and Health
HAZ DECOMP PROD: GASES WILL EVOLVE WHEN MATL UNDERGOES
PYROLYSIS/COMBUST. CARBON MONOXIDE, OXIDES OF SULFUR, NITROGEN &
PHOSPHOROUS & OTHER UNIDENTIFIED ORG CMPDS MAY BE FORMED UPON
COMBUST. FIRST AIDPROC: GET MD ATTN. NOTE TO MD: IN GEN,EMESIS
INDUCTION UNNEC IN HIGH VISC/LOW VOLAT PROD, I.E., MOST OILS &
GREASES.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, HYDROTREATED (SEVERE),
HEAVY PARAFFINIC
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, CATLYTIC DEWAXED, HEAVY
PARAFFINIC (SEVERE SOLVENT-REFINING AND/OR HYDROTREATMENT)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, ACID-TREATED HEAVY
NAPHTHENIC (SEVERE SOLVENT-REFINING AND/OR (ING 4)
Other REC Limits:NONE RECOMMENDED
Ingred Name:ING 3: HYDROTREATMENT); (SOL. REF., HYDROTREATED, ACID
TREATED HEAVY NAPHTHENIC DIST)
Ingred Name:ADDITIVE CONTAINING INGREDIENTS 5 - 7
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PHOSPHORODITHIOIC ACID, DIALKYL ESTER, ZINC SALT; (ZINC
DIALKYL DITHIOPHOSPHATE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CALCIUM ALKYL DITHIOPHOSPHATE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MAGNESIUM ALKARYL SULFONATE; (MAGNESIUM LONG-CHAIN ALKARYL
SULFONATE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MINOR ADDITIVE
Fraction by Wt: <1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SPILL PROC: VESSELS. SOAK UP RESIDUE W/ABSORB SUCH AS CLAY,
TAKE UP W/ABSORB MATL & DISPOSE OF PROPERLY.
DISPOSAL FACILITY IN COMPLIANCE W/LOC, FED & STATE REGS.
Ingred Name:HYGIENE PRACT: BEFORE REUSE. PROPERLY DISP OF CONTAMINATED
LEATHER ARTICLES, INCL SHOES, THAT CANNOT BE DECONTAMINATED.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: GEN CONSIDERED NO MORE
THAN MIN IRRIT TO EYES. SKIN: GEN CONSIDERED NO MORE THAN MILDLY
IRRIT TO SKIN. PRLNG/RPTD CONT MAY RSLT IN VARIOUS SKIN DISORDERS
SUCH AS DERM, FOLLICULITIS/OIL AC NE. INHAL: VAP (GENERATED AT HIGH
TEMPSONLY)/OIL MIST FROM PROD MAY RSLT IN MILD IRRIT OF UPPER RESP
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: TRACT. INGEST: GEN CONSIDERED NO MORE
THAN SLIGHTLY TOX IF SWALLOWED. IARC HAS DETERMINED THERE IS
SUFFICIENT EVIDENCE FOR CARCINOGENICITY IN EXPERIMENTAL ANIMALS OF
USED MOTOR OILS. HNDLG P ROC & SFTY PREC IN MSDS SHOULD BE FOLLOWED
TO MINIMIZE EMPLOYEE'S EXPOS TO USED PROD.
Medical Cond Aggravated by Exposure:PREEXISTING SKIN AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
* First Aid Measures *
OPEN. GET MD ATTN. SKIN:REMOVE CONTAM CLTHG & WIPE EXCESS OFF. WASH
W/SOAP & WATER/WATERLESS HAND CLEANER FOLLOWED BY SOAP & WATER. IF
IRRI T OCCURS GET MD ATTN. INHAL:REMOVE TO FRESH AIR & PROVIDE
OXYGEN IF BRTHG IS DFCLT. GET MD ATTN. INGEST:DO NOT INDUCE VOMIT.
IN GEN NO TREATMENT NEC UNLESS LGE QTYS OF PROD INGEST. HOWEVER,
(SUP DAT)
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:USE WATER FOG, DRY CHEM/CO*2. DO NOT USE DIRECT
STREAM OF WATER. PROD WILL FLOAT & CAN BE REIGNITED ON SURF OF
WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . MATERIAL WILL NOT BURN UNLESS PREHEATED.
COOL FIRE-EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:MAY BURN ALTHOUGH NOT READILY IGNIT. USE
CAUTIOUS JUDGMENT WHEN CLEANING UP LGE SPILLS. LGE SPILLS: WEAR
RESP & PROT CLTHG AS APPROP. SHUT OFF SOURCE OF LEAK IF SAFE TO DO
SO. DIKE & CONTAIN. REMOVE W /VACUUM, TRUCKS/PUMP TO STORAGE
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:MINIMIZE SKIN CONTACT. STORE IN A
COOL, DRY PLACE WITH ADEQUATE VENTILATION. KEEP AWAY FROM OPEN
FLAMES AND HIGH TEMPERATURES.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK AMBER OIL, WITH SLIGHT HYDROCARBON ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID HEAT AND OPEN FLAMES.
Hazardous Decomposition Products:THERMAL DECOMP PROD ARE HIGHLY
DEPENDENT ON COMBUST CNDTNS. COMPLEX MIX OF AIRBORNE SOLID, LIQ,
PARTICULATES & (SUP DAT)
* Disposal Considerations *
Waste Disposal Methods:THIS PRODUCT IS CLASSIFIED AS AN OIL UNDER
WATER/ANY WATER COURSES/SEWERS ENTERING/LEADING TO SURFACE WATERS
THAT CAUSE A SHEEN MUST BE REPO RTED TO THE NATIONAL RESPONSE
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* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED IF ADEQUATE EXHAUST
VENTILATIONS IS PROVIDED. IN SITUATIONS WHERE DUSTS MAY FORM, USE A
NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:PROVIDE ADQUATE GENERAL OR LOCAL EXHAUST VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE TO PREVENT
ACCIDENTAL EXPOSURE.
Supplemental Safety and Health
PH:(OF 2% SLURRY) <3
* Product Identification *
Preparer's Name:ANGELA BOGGS
* Composition/Information on Ingredients *
Ingred Name:SILICA, CRYSTALLINE - FUSED
OSHA PEL:SEE TABLE Z3
Ingred Name:PROPRIETARY INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:CONTACT WITH EYES, SKIN OR
MUCOUS MEMBRANES MAY CAUSE IRRITATION. CHRONIC:NONE KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMEDIATELY. EYE:FLUSH WITH WATER IMMEDIATELY
WATER. CALL MD IF IRRITATION PERSISTS. INHAL:MOVE TO FRESH AIR.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE.
* Accidental Release Measures *
Spill Release Procedures:SPILLS MAY BE SCOOPED UP & PLACED IN CONTAINER
FOR DISPOSAL. FLUSH AREA WITH COLD WATER INTO WASTE TREATMENT
SYSTEM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CAUTION! TREAT AS AN ACIDIC, ABRASIVE
CLEANER. STORE IN CLOSED ORIGNIAL CONTAINER IN A COOL, DRY AREA AT
Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. AVOID SKIN
CONTACT.
* Physical/Chemical Properties *
HCC:C3
pH:SUPDAT
Solubility in Water:APPRECIABLE
Appearance and Odor:A LIGHT GRAY POWDER WITH NO APPRECIABLE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:DO NOT STORE NEAR OXIDIZING AGENTS.
Hazardous Decomposition Products:NOT APPLICABLE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE
AND LOCAL REGULATIONS. CONTACT SHIPLEY TECHNICAL SERVICE
REPRESENTATIVE IF FURTHER ASSISTANCE IS NEEDED.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NO RESPIRATORY PROTECTION SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT FOR MOST
CONDITIONS.
Other Protective Equipment:NO PRECAUTIONS OTHER THAN CLEAN
BODY-COVERING CLOTHING SHOULD BE NEEDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PROD:THERMAL DECOMP PROD OF EPOXY RESINS THEREFORE SHOULD BE
TREATED AS POTENTIALLY HAZ SUBSTANCES, & APPROP PREC SHOULD BE
TAKEN. EFTS OF OVEREXP: WT DIGLYCIDYL ETHER OF BISPHENOL A ARE NO T
ANTICIPATED TO CAUSE ANY SIGNIFICANT ADVERSE EFTS. CANCER INFO: A
POORLY CHARAC SAMPLE OF LOW MOLECULAR WEIGHT (ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:REACTION PRODUCTS OF EPICHLOROHYDRIN & BISPHENOL A
Ingred Name:SUPP DATA: DIGLYCIDYL ETHER OF BISPHENOL A HAS BEEN
REPORTED TO PRODUCE SKIN CANCER IN A HIGHLY SENSITIVE STRAIN (ING
3)
Ingred Name:ING 2: OF MICE. HOWEVER HIGH LEVELS OF IMPURITIES
(INCLUDING A KNOWN ANIMAL SKIN CARCINOGEN) COMPROMISE THE (ING 4)
Ingred Name:ING 3: VALIDITY OF THE FINDINGS. DIGLYCIDYL ETHER OF
BISPHENOL A THAT IS REPRESENTATIVE OF CURRENT MANUFACTURING(ING 5)
Ingred Name:ING 4: PROCESSES IS NOT BELIEVED TO BE A CANCER HAZ TO
HUMANS. TERATOLOGY: DID NOT CAUSE BIRTH DEFECTS OR OTHER (ING 6)
Ingred Name:ING 5: ADVERSE EFTS ON THE FETUS WHEN PREGNANT RABBITS WERE
EXP BY SKIN CONTACT, THE MOST LIKELY ROUTE OF EXP. (ING 7)
Ingred Name:ING 8: MUTAGENICITY: RESULTS OF MUTAG TESTS IN ANIMALS HAVE
BEEN NEG. HAS BEEN SHOWN TO BE NEG IN SOME IN VITRO (ING 8)
Ingred Name:ING 7: ('TEST TUBE') MUTAGENICITY TESTS AND POSITIVE IN
OTHERS.
Ingred Name:SPILL PROC: CONSULT APPROP SOLV MSDS FOR HANDLING
Ingred Name:ING 9: EQUIPMENT AWAY. FOR LARGE SPILLS EVACUATE UPWIND OF
SPILLS AND CONTAIN WITH DIKE.
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE SLIGHT TRANSIENT EYE
IRRIT. CORNEAL INJURY IS UNLIKELY. SKIN:PRLNG EXP NOT LIKELY TO
CAUSE SIGNIFICANT SKIN IRRIT. RPTD EXP MAY CAUSE SKIN IRRIT. HAS
CAUSED ALLERGIC SKIN RXN IN HUMANS. SKIN ABSORP: SINGLE PRLNG EXP
IS NOT LIKELY TO RESULT IN MATL BEING ABSORBED THRU SKIN IN HARMFUL
AMTS.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
ANTICIPATED FROM SWALLOWING SML AMTS INCIDENTAL TO NORMAL HANDLING
OPERATIONS. INHAL: VAPS AR E UNLIKELY DUE TO PHYSICAL PROPERTIES.
SYSTEMIC EFTS: EXCEPT FOR SKIN SENSIT, RPTD EXP TO LOW MOLECULAR
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
WASH OFF IN FLOWING WATER OR SHOWER. INGEST: NO ADVERSE EFFECTS
ANTICIPATED BY THIS ROUTE OF EXPOSURE INCIDENTAL TO PROPER
INDUSTRIAL HANDLIN G. INHAL: REMOVE TO FRESH AIR IF EFFECTS OCCUR.
CONSULT A PHYSICIAN. NOTE TO MD: NO SPEC ANTIDOTE. SUPPORTIVE CARE.
TRTMT BASED ON JUDGMENT OF THE PHYSICIAN IN RESPONSE TO REACTIONS
OF THE PATIENT.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
* Accidental Release Measures *
Spill Release Procedures:SOAK UP IN ABSORB MATL SUCH AS SAND & COLLECT
IN SUITABLE CNTNRS. RESIDUAL RESIN MAY BE REMOVED USING STEAM/HOT
SOAPY H*2O. SOLV ARE NOT REC FOR CLEANUP UNLESS THE REC EXP
GUIDELINES & SAFE HNDLG PRAC TICES FOR THE SPEC SOLV ARE FOLLOWED.
(ING 9)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:SEE DOW BULLETIN ENTITLED, "DOW EPOXY
RESINS, SAFE HNDLG & STORAGE GUIDE." PRACTICE GOOD CAUTION &
PERSONAL CLEANLINESS TO AVOID SKIN AND EYE CONTACT.
Other Precautions:AVOID BREATHING VAPORS OF HEATED MATERIAL.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NONE
Appearance and Odor:H*2O-WHITE TO YELLOW LIQ TO SEMI-SOLID. FAINT EPOXY
ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BASE, ACID, AMINES AND OXIDIZING MATERIALS.
Stability Condition to Avoid:EXCESS HEATING OVER LONG PERIODS OF TIME
DEGRADES THE RESIN.
Hazardous Decomposition Products:THE BY-PROD EXPECTED IN INCOMPLETE
PYROLYSIS/COMBUST OF EPOXY RESINS ARE MAINLY PHENOLICS, CO AND
H*2O. (SUPP DATA)
Conditions to Avoid Polymerization:MASSES > 1 LB OF PROD PLUS AN
ALIPHATIC AMINE WILL CAUSE IRREVERSIBLE POLYMERIZATION WITH
CONSIDERABLE HEAT BUILDUP.
* Disposal Considerations *
Waste Disposal Methods:BURN IN ADEQUATE INCINERATOR OR BURY IN AN
APPROVED LANDFILL; IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE A NIOSH APPROVED RESPIRATOR FOR MINERAL
DUSTS WHEN WORKING W/THIS PRODUCT.
Ventilation:USE ADEQUATE VENTILATION TO MEET EXPOSURE CONTROLS.
Other Protective Equipment:WORK CLOTHING, LONG SLEEVED CLOTHING
Work Hygienic Practices:WASH WORK CLOTHING SEPARATELY; RINSE WASHING
MACHINE THOROUGHY AFTER USE.
Supplemental Safety and Health
* Product Identification *
Product ID:INSWOOL M BULK
Preparer's Name:ELLIS J SMITH
* Composition/Information on Ingredients *
Ingred Name:REFRACTORIES FIBERS, ALUMINOSILICATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MECHANICAL IRRITATION. SKIN: MAY
CAUSE IRRITATION. INHALATION: LONG TERM EXPOSURE TO DUST MAY CAUSE
LUNG DAMAGE. PROLONGED EXPOSURE TO DUST MAY CAUSE SILICOSIS, A
PROGRESSIVE PNEUMOCONIOSIS/OTHE R RESPIRATORY DISEASES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, BREATHING DISCOMFORT, TRANSITORY
SKIN RASH
* First Aid Measures *
WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DON'T INDUCE
VOMITING UNLESS INSTRUCTED TO DO SO BY PHYSICIAN. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NON FLAMMABLE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:DAMPEN, THEN PICK UP/SCOOP UP & PLACE IN A
CONTAINER FOR DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A DRY PLACE, AWAY FROM
EXTREME HEAT. PRODUCT IS NON-FLAMMABLE, BUT PACKAGING IS
COMBUSTIBLE.
Other Precautions:AS SUPPLIED PRODUCT CONTAINS NO CRYSTALLINE SILICA,
CRISTOBALITE, A FORM OF CRYSTALLINE SILICA MAY FORM.
* Physical/Chemical Properties *
pH:7
Solubility in Water:NONE
Appearance and Odor:WHITE TO OFF WHITE FIBER, IN BLANKET/BULK FORM W/NO
ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONCENTRATED ACIDS
* Disposal Considerations *
Waste Disposal Methods:PRODUCT MAY BE DISPOSED OF IN AN APPROVED
LANDFILL IAW/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
.
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT
SKIN EXPOSURE.
Supplemental Safety and Health
MOLECULAR FORMULA: ZNO. FED REGS: OSHA: NONE OF CHEMS IN PROD ARE
CONSIDERED HIGHLY HAZ BY OSHA. EUROPEAN/INTERNATIONAL REGS:
EUROPEAN LABELING I/A/W EC DIRECTIVES: HAZ SYMBOLS: NOT AVAIL. WGK
IS LISTED ON CANADA'S DSL/NDSL LIST. (ECOL INFO)
* Product Identification *
* Composition/Information on Ingredients *
Other REC Limits:N/K
OSHA STEL:N/K
ACGIH TLV:5 MG/M3
ACGIH STEL:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: DUST MAY CAUSE MECHANICAL
IRRITATION. SKIN: MAY CAUSE SKIN IRRITATION. INGESTION: MODERATELY
TOXIC TO HUMANS BY INGESTION. INHALATION: EFFECTS MAY BE DELAYED.
INHALATION OF FUMES MAY CAUS E METAL FUME FEVER, WHICH IS
CHARACTERIZED BY FLU-LIKE SYMPTOMS WITH METALLIC TASTE, FEVER,
CHILLS, COUGH, WEAKNESS, CHEST PAIN, MUSCLE PAIN AND INCREASED
WHITE BLOOD CELL COUNT. ZINC OXIDE DUST IS CO NSIDERED TO BE OF LOW
TOXICITY AND IS CLASSIFIED AS A NUISANCE PARTICULATE BY THE ACGIH.
HOWEVER, INHALATION OF FUMES OR VERY FINE DUST MAY CAUSE "ZINC FUME
FEVER", WHICH IS CHARACTERIZED BY FLU-LIKESYMPTOMS WITH (EFFECTS
OF OVEREXPOSURE)
Explanation of Carcinogenicity:NOT LISTED.
Effects of Overexposure:HEALTH HAZARDS: METALLIC TASTE, COUGHING,
WEAKNESS, FATIGUE, MUSCULAR PAIN, AND NAUSEA, FOLLOWED BY FEVER AND
CHRONIC: NO INFORMATION FOUND.
* First Aid Measures *
OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS. GET MEDICAL AID.
SKIN: GET MEDICAL AID. FLUSH WITH PLENTY OF SOAP AND WATER FOR AT
INGESTION: IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF
MILK OR WATER. GET MEDICAL AID. INHALATION: REMOVE FROM EXPOSURE TO
FRESH AIR IMM EDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL
AFTER EXPOSURE.
* Fire Fighting Measures *
Extinguishing Media:SUBSTANCE IS NON-COMBUSTIBLE; USE AGENT MOST
APPROPRIATE TO EXTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NFPA RATING: NOT PUBLISHED.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN CONTROL MEASURES SECTION. VACUUM OR SWEEP UP MATERIAL
AND PLACE INTO A SUITABLE DISPOSAL CONTAINER. AVOID GENERATING
DUSTY CONDITIONS.
*Handling and Storage *
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION.
MINIMIZE DUST GENERATION AND ACCUMULATION. AVOID BREATHING DUST,
VAPOR, MIST, OR GAS. AVOID CONTACT WITH EYES, SKIN, AND CLOTHING.
STORE IN A DRY AREA.
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE TO YELLOW-WHITE SOLID; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS EXPLOSIVELY WITH MAGNESIUM WHEN HEATED. MIXTURES OF CHLORINATED
Stability Condition to Avoid:INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:TOXIC FUMES OF ZINC OXIDE.
* Toxicological Information*
NEUROTOXICITY, MUTAGENICITY, O THER STUDIES: NO DATA AVAILABLE.
* Ecological Information *
Ecological:ECOTOXICITY, ENVIRONMENTAL FATE, PHYSICAL/CHEMICAL, OTHER:
NO INFO FOUND. --SUPDAT: PROD HAS A WHMIS CLASSIFICATION OF D2B.
PROD IS NOT LISTED ON CANADA'S ING DISCLOSURE LIST. EXPOS LIMS:
OEL-DENMARK: TWA 4 MG/M3 (FUME). OEL-DENMARK: TWA 4 MG/M3 (DUST).
OEL-FRANCE: TWA 5 MG/M3 (FUME). OE L-GERMANY: TWA 5 MG/M3
(TRANSPORT INFO)
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION
OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY
REFERENCE LEVELS: NONE LI STED. RCRA F-SERIES: NONE LISTED. RCRA
P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED.
* MSDS Transport Information *
Transport Information:US DOT, IATA, RID/ADR, IMO, CANADA TDG: NO
INFORMATION AVAILABLE. --ECOL INFO: (FUME). OEL-HUNGARY: TWA 5
MG/M3. OEL-JAPAN: TWA 5 MG/M3 (FUME). OEL-THE NETHERLANDS: TWA 5
MG/M3. OEL-THE PHILIPPINES: TWA 1 MG/M3. OEL-POLAND: TWA 4 MG/M3
(FUME). OEL-SWEDEN: TWA 5 MG/M3. OEL-SWITZERLAND: TWA 5 MG/M3.
OEL-SWITZERLAND: TWA 5 MG/M3 (FUME). OEL-THAILAND: TWA 5 MG/M3
(FUME). OEL-TURKEY: TWA 5 MG/M3. OEL- UNITED KINGDOM: TWA 5 MG/M3;
(FUME). OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA, NEW ZEALAND,
SINGAPORE, VIETNAM CHECK ACGIH TLV.
* Regulatory Information *
INVENTORY. HLTH & SFTY REPORTING LIST: NONE OF CHEMS ARE ON HLTH &
SFTY REPORTING LIST. CHEM TEST RULES: NONE OF CHEMS IN PROD ARE
MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT: MATL DOES NOT CONTAIN ANY
HAZ AIR POLLUTANTS, ANY CLASS 1 OZONE DEPLETORS/ANY CLASS 2 OZONE
DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS
HAZ SUBSTANCES, PRIORITY POLLUTANTS/TOX POLLUTANTS UNDER CWA. (SUP
DAT)
FOLLOWING STATE RIGHT-TO-KNOW LISTS: CALIFORNIA, NEW JERSEY,
FLORIDA, PENNSYLVANIA, MINNESOTA, MASSACHUSETTS. CALIFORNIA NO
SIGNIFICANT RISK LEVEL: NONE OF THE CHEM ICALS IN THIS PRODUCT ARE
LISTED.
* Other Information *
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* Exposure Controls/Personal Protection *
Respiratory Protection:DUST MASK.
Ventilation:LOCAL EXHAUST
Other Protective Equipment:PROTECTIVE CLOTHING
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM CHLORATE
Fraction by Wt: UNK
* Hazards Identification *
Effects of Overexposure:SORE THROAT,COUGHING,HEADACHE,DIZZINESS, BLUISH
SKIN,IRRITATES EYES,NAUSEA,ABDOM.PAIN,DIARRHEA,FAINT.
* First Aid Measures *
First Aid:INHALATION:FRESH AIR,REST & CALL DOCTOR; SKIN:REMOVE
CONTAMINATED CLOTHES,RINSE SKIN W/PLENTY OF H2O;EYES:FIRST RINSE
W/PLENTY OF WATER,THEN SEE DOCTOR,INGESTION:RINSE MOUTH,GIVE PLENTY
OF WATER TO DR INK INDUCE VOMITING & CARRY TO HOSPITAL.
* Fire Fighting Measures *
Fire Fighting Procedures:FLOOD W/H2O;WEAR SELF-CONTAINED BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:MAY CAUSE FIRE W/COMBUSTIBLES;POISONOUS
GASES ARE PRODUCED IN FIRE;WHEN HTD GIVES OFF O2;IGN BY SHK
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP SPILLED SUBSTANCE.DO NOT CONTAMINATE
& REMOVE TO SAFE PLACE,WASH AWAY REMAINDER W/LARGE AMTS OF WATER,DO
NOT ABSORB IN SAWDUST OR OTHER COMBUSTIBLE SUBSTANCES,USE EXTRA
PERSONAL PROTECTION;CA LSS 2B PART.FILTER RESP.ELIM.IGNITION
SOURCES
*Handling and Storage *
Handling and Storage Precautions:SEPARATE FROM COMBUSTIBLE SUBSTANCES &
REDUCING AGENTS,SEPARATE FROM STRONG ACIDS.PROTECT CONTAINERS
AGAINST PHYSICAL DAMAGE.SEPARATE FR POWDERED MTLS
Other Precautions:SEPARATE FROM OXIDIZERS,AMMONIUM SALTS,SULFUR &
FLAMMABLE VAPORS.USE ADEQUATE VENTILATION.PREVENT DISPERSION OF
DUST.AVOID CONTAMINATION.AVOID MECH.SHOCK OR FRICTION.KEEP CONTS
CLOSED.
* Physical/Chemical Properties *
HCC:D1
Solubility in Water:APPRECIABLE
Appearance and Odor:SOLID,WHITE,ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
COMBUSTIBLES,REDUCING MATLS,NH3 COMPDS,POWDERED METALS,ACID
Stability Condition to Avoid:AVOID COMBUSTIBLES.
Hazardous Decomposition Products:TOXIC FUMES,CHLORINE DIOXIDE FR
REACTION W/ STRONG ACIDS.
* Disposal Considerations *
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL.HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS;OR USE VAST SOL.OF
CONC.SOLN OF REDUCING AGENT(BISULFITE S).NEUTRALIZE W/SODA ASH OR
DILUTE HCL;DR W/H2O.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:LONG SLEEVE SHIRT AND LONG TROUSERS ARE
RECOMMENDED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:FLUSH PROD FROM HANDS W/SOAPY WATER. CARE
SHOULD BE TAKEN TO AVOID CONTACT W/EYES UNTIL HANDS HAVE BEEN (SEE
SUPP DATA)
Supplemental Safety and Health
PH: 6-9 IN AQUEOUS SLURRY. HNDLG/STOR PREC: WITH STRONG OXIDIZING
AGENTS SUCH AS NITRIC ACID. OTHER PREC: IN THE WORK SPACE MUST BE
OBSERVED. HYGIENE PRACT: COMPLETELY CLEANED. PROD HAS A TENDENCY TO
CLING TO SKIN DUE TO STATIC CHARGE. CARE MUST BE EXERCISED TO
REMOVE ALL PRODUCT FROM SKIN.
* Product Identification *
Preparer's Name:REGULATORY AFFAIRS
* Composition/Information on Ingredients *
Ingred Name:BENZENE DIETHENYL-, POLYMER WITH ETHENYLBENZENE AND
ETHENYLETHYLBENZENE, SULFONATED, SODIUM SALTS.
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE/CHRONIC: CAN PRODUCE MECHANICAL
IRRITATION TO THE EYE. MAY CAUSE SKIN IRRITATION OF HYPERSENSITIVE
PERSONNEL.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:RED, IRRITATED EYES, ITCHING AND FEELING THAT A
PARTICLE EXISTS BETWEEN THE EYELID AND EYE.
* First Aid Measures *
First Aid:EYES/SKIN: FLUSH WITH COPIOUS QUANTITIES OF WATER FOR AT
CROSS. INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR.
SUPPORT B REATHING (GIVE O*2/ARTIFICIAL RESPIRATION) .
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE OR WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . GUARD AGAINST CONTACT OF PRODUCT WITH EYE
DURING SALVAGE OPERATION.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:SWEEP AREA OF PRODUCT, COLLECTING IN A
CONTAINER FOR DISPOSAL. AREAS OF SPILL CAN BECOME EXTREMELY
SLIPPERY. ALL NORMAL SAFETY PRECAUTIONS SHOULD BE OBSERVED.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
BECAUSE PROD CONTAINS WATER WHICH WILL FREEZE & DAM PROD/DRY-OUT
ALSO DAMAGING PROD. AVOID CONT (SEE SUPP DATA)
Other Precautions:AVOID PACKING PROD IN AN UNPROTECTED GLASS COLUMN.
EXPANSION OF THE PROD CAN CAUSE GLASS COLUMN TO SHATTER. WHEN
TRANSFERRING PROD TO OTHER CNTNRS VIA HYDRAULIC (WATER) SLURRY ALL
SAFETY PRACTICES EST ABLISHED FOR USE OF WATER (SUPP DATA)
* Physical/Chemical Properties *
Vapor Pres:SEE ING 2
Vapor Density:SEE ING 2
Spec Gravity:1.3
pH:SUPDAT
Evaporation Rate & Reference:1 (H*2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID SPHERICAL BEADS; ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS NITRIC ACID.
EXPLOSIVE REACTIONS CAN OCCUR IN THE PRESENCE OF STRONG OXIDIZING
AGENTS.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
STYRENE, DIVINYLBENZENE.
* Disposal Considerations *
Waste Disposal Methods:NEW, UNUSED PRODUCT CAN BE DISPOSED OF AS
ORDINARY TRASH I/A/W ALL FEDERAL, STATE, AND LOCAL REGULATIONS.
USED PRODUCT MUST BE TESTED FOR CONTAMINATION BY HAZARDOUS MATERIAL
AND DISPOSED OF ACCORDINGL Y.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPRVD MECH RESPIRAT TO REMOV OVERSPRAY
WHN SPRAYING IN OUTDR
Ventilation:PROVID GEN DILUT/LOC EXHAUST VENT TO KP CONCENT BELO ACEP
TL
Other Protective Equipment:PROTECTV EQPMT TO PRVNT SKN CONTCT.SE
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MINERAL SPIRITS
Ingred Name:METHYL ETHYL KETOXIME
Fraction by Wt: <0.5%
* Hazards Identification *
Effects of Overexposure:IRRIT OF NOSE,THROAT,EYES & POSS DIZZINESS &
NAUSEA.SPRAY MIST CONTN LEAD.
* First Aid Measures *
First Aid:INHAL:REMOVE FR EXPOSR & PROVID FRESH AIR.SPLASH EYES-FLUSH
CLOTHING & WASH ALL AFFECT AREA W/WATR.INGEST:DO NOT INDUC
VOMITNG.CONSULT A DR . IMMED IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CLASS B EXTING, CARBON DIOXIDE, DRY CHEM OR ALCOHOL
FOAM
Fire Fighting Procedures:SELF CONTAINED BREATH APPARAT.WATER MAY BE
INEFECTIVE.
Unusual Fire/Explosion Hazard:KEEP CONTNRS TIGHTHLY CLOS.ISOLAT FR
HEAT,ELECTR EQPMT,SPARKS & OPN FLAME.DO NOT APPLY TO VRYHOT SUR
* Accidental Release Measures *
Spill Release Procedures:REMOV ALL SOURCES OF IGNIT (FLAMES,HOT
SURFACES,ELECTRICAL, STATIC OR FRICTIONAL SPARKS).VENTILAT AREA &
AVOID BRATHING VAPORS.REMOV W/ INERT ABSORB & NON-SPARKING
TOOLS.STEPS MUST BE TAKN TO PREVNT C ONTAM OF GROUND WATR OR
STREAMS.
*Handling and Storage *
BONDED TO THE RECEIVING CONTNR.
Other Precautions:DO NOT CUT OR WELD ON EMPTY CONTAINER. DO NOT USE
UNTIL ALL SAFETY PRECAUTIONS HAVE BEEN READ & FULLY UNDERSTOOD BY
THE USER.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:>AIR
Evaporation Rate & Reference:<ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTCT W/STRONG ACIDS OR AKALINE MATERIALS.
Stability Condition to Avoid:FIRES,HEAT & HOT SURFACES.
Hazardous Decomposition Products:BURNING WILL PRODUCE SMOKE & OXIDES OF
CARBON & LEAD.
Conditions to Avoid Polymerization:DO NOT ADD DRIERS OR REACTIV CHEM
W/O TECHN SUPERVISION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORD W/LOCAL, STATE & FEDERAL
REGULATIONS.INCINERATIN EPA APPRVD FACILITY.DO NOT INCINERAT CLOSED
CONTAINERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIIOSH/MSHA APPROVED DUST RESPIRATOR IF
EXCESSIVE DUSTING OCCURS.
Ventilation:LOCAL MECHANICAL EXHAUST VENTILATION RECOMMENDED TO
MINIMIZE EMPLOYEE EXPOSURE.
Other Protective Equipment:CHEMICAL RESISTANT COVERALLS AND BOOTS. AN
EMERGENCY EYEWASH AND SHOWER SHOULD BE AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
THERE IS A POSSIBILITY BICYCLIC PHOSPHATES OR PHOSPHITES CAN BE
PRODUCED AS A RESULT OF THE THERMAL DECOMPOSITION OF THIS PRODUCT
IN COMBINATION WITH TRIMETHYLOL PROPANE, TRIMETHYLOL PROPANE
DERIVED P RODUCTS OR THEIR CORRESPONDING TRIMETHYLOL ALKANE
HOMOLOGS.
* Product Identification *
Product ID:SODIUM POLYSPHOPHATES
* Composition/Information on Ingredients *
Ingred Name:METAPHOSPHORIC ACID, HEXASODIUM SALT (CERCLA)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE EYE OR SKIN IRRITATION.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYES: FLUSH THOROUGHLY WITH LUKEWARM WATER. GET MEDICAL
ATTENTION IF IRRITATION DEVELOPS. SKIN: WASH THOROUGHLY WITH SOAP
AND WARM WATER. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS.
INHALATION: IMME DIATELY REMOVE TO FRESH AIR. GET MEDICAL ATTENTION
IF RESPIRATORY IRRITATION DEVELOPS. INGESTION: DO NOT GIVE ANYTHING
BY MOUTH IF UNCONSCIOUS. OTHERWISE, GIVE SEVERAL GLASSES OF WATER.
CALL PHYSICIAN
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED POSITIVE PRESSURE
SELF-CONTAINED BREATHING APPARATUS WHEN ANY CHEMICAL MATERIAL IS
INVOLVED IN FIRE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:REPORT SPILLS AS REQUIRED TO APPROPRIATE
AUTHORITIES. WEAR NIOSH/MSHA APPROVED DUST RESPIRATOR. WEAR
NUMBER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
PLACE. AVOID CONTACT WITH EYES, SKIN OR CLOTHING. AVOID BREATHING
DUST OR MIST FROM SOLUTIONS.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
Boiling Pt:B.P. Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:1.2
Viscosity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:VERY SOLUBLE
Appearance and Odor:CLEAR GLASSY PARTICLES
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:EXCESS HEAT.
Hazardous Decomposition Products:PHOSPHORUS OXIDES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF CONTAMINATED PRODUCT, EMPTY
CONTAINERS AND MATERIAL USED CLEANING UP SPILLS OR LEAKS IN A
MANNER CONSISTANT WITH FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED
Ventilation:LOCAL EXHAUST TO ELIMINATE MISTS/FUMES/GASES.
Other Protective Equipment:NORMAL WORK CLOTHING COVERING ARMS & LEGS.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
III)
Ozone Depleting Chemical:1
ACGIH TLV:5MG/CUM(MIST)
* Hazards Identification *
Effects of Overexposure:EYES:MAY IRRIT;SKIN:PROLONGD CONTACT CAUSES
DEFATG/DERMTITIS;INHAL:DIZZ,NARCOSIS EFFECT.CNS DEPPRSN.
* First Aid Measures *
First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF
GET MEDICAL ATTENTION FOR EYES, BREATHING DIFFICULTY, OR OTHER
SYMPTOMS OF OVEREXPOSURE.
* Fire Fighting Measures *
Flash Point:NONE(AEROSOLS)
Extinguishing Media:CO*2, FOAM, DRY CHEM & H*2O FOG.
CONTR.
Unusual Fire/Explosion Hazard:NONE NOTED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES,VENTILATE AREA
WELL.ABSORB WITH VERMICULITE OR OTHER MATERIALS, SUCH AS
SAWDUST,RAGS,PAPER & PLACE IN CLOSED CONTAINER. USE NON SPARKING
TOOLS. WEAR PROPER PROTECTIVE EQUIPMENT DURING CLEAN UP.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
PROLONGED OR REPEATED CONTACT WITH SKIN.DO NOT PUNCTURE OR
INCINERATE CANS.
* Physical/Chemical Properties *
HCC:V3
Solubility in Water:NEGLIGIBLE
Appearance and Odor:MIXTURE:CLEAR,ORANGE LIQ W/SLIGHT PET-HYDROCARODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANT E.G. LIQ CL*2,SOD/CAL HYPO
Stability Condition to Avoid:HEAT, IGNITION SOURCES
Hazardous Decomposition Products:HCL,HF,POSS PHOSGENE,CO,SO*2,ALDEHYDES
& OTHER DECOMP PROD.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN APPROVED INCINERATOR OR DISPOSE OF
IN APPROVED CHEMICAL DUMP IN ACCORDANCE WITH LOCAL,STATE & FEDERAL
REGULATIONS.
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* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPRVD RESP PROT DEPENDING ON CONDS
OF USE(SEE SUPP DATA)
Ventilation:LOC EXHST:PREFERABLE, MECH:ACCEPTABLE. KEEP BELOW TLV.
Other Protective Equipment:N/A (MFR)
Supplemental Safety and Health
AIR PACK ACCD TO MFR. RECM RESP PROT MAY NOT BE SUIT FOR ALL
SITUATIONS. CONSULT IND HYGIENIST/SAF OFF IF UNSURE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TOLUENE (SARA III)
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
Ingred Name:N-BUTYL ALCOHOL (SARA III)
Ingred Name:ISOBUTYL ACETATE (SARA III)
* Hazards Identification *
Effects of Overexposure:INHALATION ANESTETIC, IRRITATES. CNS DEPRESS W/
HDCH, DIZZ, STAGGERING, CONFUSION, COMA.
* First Aid Measures *
VAPORS:REMOVE FROM EXPOSURE. RESTORE BREATHING. SWALLOWING: CALL
PHYSICIAN. DO NOT INDUCE VOMITING.
* Fire Fighting Measures *
Flash Point:2F
Lower Limits:1.7
Extinguishing Media:CO2, DRY CHEMICAL OR FOAM. WATER MAY BE INEFFECT ON
FIRE.
Fire Fighting Procedures:AIR-SUPP BR MASK. WATER FOG TO COOL CLOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD & AWAY FROM ALL
SOURCES OF IGNT. CLSD CNTNRS MAY EXPLO IF EXPO TO EXTM HEAT
* Accidental Release Measures *
Spill Release Procedures:REMOVE SOURCES OF IGNITION. AAVOID BREATHING
VAPOR. REMOVE WITH INERT, ABSORBENT, NON-SPARKING PRODUCTS.
*Handling and Storage *
Handling and Storage Precautions:PREVENT BUILD-UP OF VAPS, MAY SPREAD
STRUCTURES FOR OSHA CLASS 1B LIQUIDS.
Other Precautions:EXTING ALL SOURCES OF IGNIT UNTIL VAPS ARE GONE. DO
NOT FLAME CUT, SAW, BRAZE, OR WELD. EMPTY CNTNRS ARE HAZ. CONT ALL
PRECAUTIONS. GROUND CNTNRS WHEN POURING. AVOID FREE OF LIQUID.
* Physical/Chemical Properties *
Vapor Density:3.0
Evaporation Rate & Reference:4.9 (ETHER=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:CLEAR, WATER-WHITE, KETONE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE FROM BURNING.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE ACCORDING TO AIR POLLUTION
REGULATIONS. DO NOT INCINERATE IN CLOSED CONTAINERS. DSPOSE IAW
FEDERAL, STATE, LOCAL CODES.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:MAY BE NEEDED IN SPECIAL CIRCUMSTANCES.
Ventilation:GOOD: SHOULD BE SUFFICIENT.
Other Protective Equipment:MAY BE REQUIRED.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:WATER
Ingred Name:THIOCYANIC ACID, AMMONIUM SALT, AMMONIUM THIOCYANATE
Ingred Name:AMMONIUM THIOSULFATE
Ingred Name:SODIUM SULFITE
Other REC Limits:5 MG/CUM (DUST)
Ingred Name:POTASSIUM SULFITE
Fraction by Wt: <5%
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MAY BE IRRITATING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: WASH OUT IMMEDIATELY
W/WATER. SKIN: WASH AFTER EACH CONTACT. INGESTION: DRINK 1-2
GLASSES OF WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CO2.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FIRE/EXCESSIVE HEAT MAY CAUSE PRODUCTION
OF HAZARDOUS DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:FLUSH MATERIAL TO SEWER W/LARGE AMOUNTS OF
WATER.
*Handling and Storage *
Handling and Storage Precautions:KEEP FROM CONTACT W/OXIDIZING
MATERIALS.
Other Precautions:AVOID MINERAL ACIDS, ALKALIS.
* Physical/Chemical Properties *
Vapor Density:0.6
pH:5
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS TO SLIGHTLY PINK SOLUTION W/VINEGAR ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALKALI, MINERAL, ACIDS, STRONG OXIDIZERS.
Hazardous Decomposition Products:AMMONIA, SULFUR DIOXIDE, CARBON, CO2.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE TREATMENT/DISPOSE IAW/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF DUSTY, WEAR MASK
Ventilation:LOC EXHAUST- NATURAL
Supplemental Safety and Health
* Product Identification *
Product ID:SCOURING POWDER, TYPE II
* Composition/Information on Ingredients *
Ingred Name:NON HAZARDOUS INGREDIENTS
* Hazards Identification *
Effects of Overexposure:SCOURING POWDER IS NOT TOXIC ORALLY, IS NOT
IRRIT. TO THE SKIN & IS AN EYE IRRITANT.
* First Aid Measures *
First Aid:EYES-FLUSH W/WATER,GET MEDICAL ATTN. SKIN-WASH W/WATER.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:NO FIRE OR EXPLOSIVE HAZARD
Fire Fighting Procedures:NONE
* Accidental Release Measures *
Spill Release Procedures:NORMAL CLEAN UP
*Handling and Storage *
Handling and Storage Precautions:DRY STORAGE AREA
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:PARTIALLY
Appearance and Odor:WHITE POWDER, ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:AVOID CONTACT W/ACIDS
* Disposal Considerations *
Waste Disposal Methods:REMOVE TO DUMP
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRABLE FUME
RESPIRATOR OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED
SPACE OR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE
BELOW TLV.
Ventilation:USE ENOUGH VENT, LOC EXHST @ ARC/BOTH, TO KEEP FUMES &
GASES BELOW TLV IN WORKERS BRTHG ZONE & GEN AREA.
Other Protective Equipment:ARM PROTECTORS, APRONS, HATS, SHOULDER
PROTECTION & DARK SUBSTANTIAL CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PROD: VANADIUM OXIDE FUMES, NITROGEN DIOXIDE & OZONE. EYE
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:COPPER. PEL:0.1 MG(CU)/M3 FUME;1 MG(CU)/M3 DUST. TLV:0.2
MG(CU)/M3 FUME;1 MG(CU)/M3 DUST.
OSHA PEL:SEE INGRED NAME
ACGIH TLV:SEE INGRED NAME
Ingred Name:BARIUM CARBONATE (1:1); (BARIUM CARBONATE)
OSHA PEL:0.5 MG(BA)/M3
ACGIH TLV:0.5 MG(BA)/M3
Ingred Name:STRONTIUM CARBONATE
ACGIH TLV:9 MG/M3 (MFR)
Ingred Name:BARIUM FLUORIDE
OSHA PEL:0.5 MG(BA)/M3
ACGIH TLV:0.5 MG(BA)/M3
OSHA PEL:2.5 MG(FL)/M3
ACGIH TLV:2.5 MG(FL)/M3
Ingred Name:SILICA, CRYSTALLINE - QUARTZ (SILICON DIOXIDE)
OSHA PEL:SEE TABLE Z3
OSHA PEL:SEE INGRED NAME
Ingred Name:SODIUM SILICATE
ACGIH TLV:0.3 MG/M3 (MFR)
OSHA PEL:SEE INGRED NAME
Ingred Name:CARBON
Ingred Name:MANGANESE. PEL AND TLV AS MN FUME.
OSHA PEL:(C) 5 MG/M3 DUST
Ingred Name:NICKEL
OSHA PEL:1 MG(NI)/M3
ACGIH TLV:1 MG(NI)/M3
Ingred Name:IRON
ACGIH TLV:5 MG(FE)/M3
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:SHORT TERM OVEREXP TO WELDING
FUMES MAY RESULT IN DISCOMFORT SUCH AS:DIZZ, NAUS OR DRYNESS/IRRIT
OF NOSE, THROAT, LUNGS OR EYES. CHRONIC:LONG TERM OVEREXP TO
WELDING FUMES CAN RESULT IN:CHRONIC RESP PROBLEMS, IRON BUILDUP IN
LUNGS, BONE EROSION, REDUCED PULM FUNC & NERV DISORDERS. SOME
STUDIES (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NICKEL:GROUP 1 (IARC); GROUP 2 (NTP).
CRYSTALLINE SILICA:GROUP 2A (IARC).
Effects of Overexposure:HLTH HAZ:HAVE SHOWN HIGHER LEVEL OF LUNG
RELATED PROBLEMS AMONG OLDER WELDERS WHO SMOKED THAN THOSE WHO DID
NOT SMOKE.
Medical Cond Aggravated by Exposure:AGGRAVATION OF PRE-EXISTING
RESPIRATORY OR ALLERGIC CONDITIONS MAY OCCUR IN SOME WORKERS EVEN
IF CONC OF FUMES IS MAINTAINED BELOW RECOMMENDED LIMITS.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMED . INHAL:REMOVE TO FRESH AIR. SUPPORT
BRTHG (GIVE O2/ARTF RESP) CALL MD. EYES:IMMED FLUSH W/ POTABLE
IOUS AMTS OF WATER CALL MD .
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT
EQUIP .
Unusual Fire/Explosion Hazard:NONFLAMMABLE WELDING ARC & SPARKS CAN
IGNITE COMBUSTIBLE & FLAMMABLE PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:TRAIN WELDER TO KEEP HIS HEAD OUT OF
FUMES & NOT TO TOUCH LIVE ELEC PARTS & INSULATE HIMSELF FROM WORK &
GROUND.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
Appearance and Odor:SOLID STEEL CORE ROD WITH CHEMICAL & ALLOY
COVERING.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CALCIUM FLUORIDE, CHROMIUM METAL,
CHROMIUM II&III, CHROMIUM VI COMPOUND, COBALT/COPPER/IRON
OXIDE/MANGANESE/ (SUPP DATA)
* Disposal Considerations *
Waste Disposal Methods:PVNT WASTE FROM CONTAM SURROUNDING ENVIRON.
DISCARD ANY PRODUCT, RESIDUE, DISP CNTNR OR LINER IN
ENVIRONMENTALLY ACCEPTABLE MANNER. DISP OF I/A/W FEDERAL, STATE &
LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT APPLICABLE UNDER NORMAL CONDITIONS OF USE.
NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:WHERE ADEQUATE NATURAL VENTILATION IS NOT AVAILABLE PROVIDE
SUITABLE LOCAL EXHAUST VENTILATION.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
SUITABLE PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH HANDS W/SOAP & WATER & USE HAND CREAM.
REMOVE CONTAMD CLTHG & WASH BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN, EYES AND RESPIRATORY
TRACT IRRITATION. VAPORS ARE CENTRAL NERVOUS SYSTEM (CNS)
DEPRESSANT, INHALATION OF VAPORS ALSO CAUSES NAUSEA, VOMITING,
DIZZINESS, DISORIENTATION AND UNCONSCIOUSNESS MAY OCCUR AT HIGH
CONCENTRATIONS. CHRONIC: IRRITATION, DERMATITIS.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SKIN, EYE, RESPIRATORY TRACT AND
CNS CONDITIONS.
* First Aid Measures *
First Aid:INHAL: REMOVE SOURCE OF CONTAM &/OR MOVE VICTIM TO FRESH AIR.
IF RECOVERY IS DELAYED/THERE ARE SIGNS OF DISTRESS OBTAIN MED ATTN
IF A NY IRRIT PERSISTS. SKIN CONT: IMMED REMOVE EXCESS W/CLEAN
CLOTH & WASH SKIN THORO W/SOAP & WATER. IF IRRIT/INFLAMM PERSISTS,
SEEK MED ADVICE. INGEST: DO NOT INDUCE VOMIT. RINSE MOUTH W/WATER
(SUPDAT)
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1.1%
Upper Limits:6.1%
Extinguishing Media:WATER SPRAY, FOG OR MIST, FOAM, CARBON DIOXIDE, DRY
CHEMICALS, SAND ETC.
Fire Fighting Procedures:NIOSH APPRVD SCBA & FULL PROT EQUIP . USE SAND
TO CNTN BURNING MATL. COOL CNTNRS EXPOSED TO FLAMES W/WATER. KEEP
RUN-OFF WATER OUT OF SEWERS OR (SUPDAT)
Unusual Fire/Explosion Hazard:VAPORS CAN FORM EXPLOSIVE MIST W/AIR &
VAPORS MAY TRAVEL CONSIDERABLE DISTANCE TO ANY SOURCES OF IGNIT &
FLASH BACK. DECOMPOSITION & COMBUST MAY BE HAZARDOUS.
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH AN INERT MATERIAL (E.G. EARTH OR
SAND). SWEEP UP, PLACE INTO SUITABLE LABELLED CONTAINERS, SEAL AND
DISPOSE OF PROPERLY. FLUSH AREA WITH DETERGENT AND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:OVERHEATING MAY CAUSE CONTAINERS TO
RUPTURE. CONTAINERS SHOULD BE STORED UNDER COOL, DRY CONDITIONS.
Other Precautions:EMPTY CONTAINERS WILL RETAIN RESIDUE AND MAY BE
DANGEROUS. CHECK ALL CONTAINERS FOR LEAKS AT REGULAR INTERVALS &
BEFORE USE. AVOID CONTACT WITH SKIN AND EYES.
SOURCES. IF WATER POLLUTION OCCURS, NOTIFY APPROP AUTH IMMED. FIRST
AID PROC: & DRINK PLENTY OF WATER. CALL TAMPA BAY REGIONAL P OIS
NITRILE OR PVC.
* Physical/Chemical Properties *
Vapor Density:3.6
Evaporation Rate & Reference:0.4 (BUAC =1)
Solubility in Water:SUPP DATA
Appearance and Odor:CLEAR BROWN LIQUID WITH STYRENE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND ACIDS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:GASEOUS COMBINATIONS OF CARBON,
HYDROGEN AND OXYGEN MAY OCCUR AT ELEVATED TEMPERATURES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A
NIOSH/MSHA APPROVED DUST/MIST RESPIRATOR IS RECOMMENDED. IF
CONCENTRATION EXCEEDS CAPACITY OF RESP, A NIOSH/MSHA APPROVED SCBA
IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Other Protective Equipment:UNIFORM AND APRON ARE RECOMMENDED. VENT
HOOD. EMERGANCY EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:WASH CLOTHING BEFORE REUSE. WASH THOROUGHLY
AFTER HANDLING.
Supplemental Safety and Health
OTHER PREC:FROM FOOD STUFFS. DO NOT BREATHE DUST.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM FLUORIDE (SARA III)
OSHA PEL:2.5 MG/M3 (F)
ACGIH TLV:2.5 MG/M3 (F)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL & INGEST ARE HARMFUL & MAY BE
FATAL. INHAL MAY CAUSE NAUSEA, VOMIT, DIFF BRTHG. ACUTE:INHALATION
OF DUST MAY CAUSE SEVERE IRRITATION OF RESPIRATORY SYSTEM. CONTACT
WITH SKIN OR EYES MAY CAUSE SE VERE IRRITATION OR BURNS. INGESTION
MAYCAUSE HEADACHE, NAUSEA, VOMITING, GI IRRITATION, CONVULSIONS,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:AND BURNS TO MOUTH, THROAT AND
STOMACH. CHRONIC:INCREASED BONE DENSITY, CALCIUM DEPOSITS IN
LIGAMENTS AND MOTTLED TOOTH ENAMEL.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.
* First Aid Measures *
First Aid:INGEST:IF CONSCIOUS, IMMED INDUCE VOMIT. INHAL:REMOVE TO
FRESH AIR. IF NOT BRTHG, GIVE ARTIF RESP. IF BRTHG IS DFCLT, GIVE
REMOVING CON TAM CLTHG & SHOES. WASH CLTHG BEFORE REUSE. EYES:IMMED
EXCRETION LEV HAVE BEEN USEFUL IN EVALUATING INDUSTRIAL EXPOS TO
FLOURIDE DUST.
* Fire Fighting Measures *
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HEAT MAY
EXPLODE. HYDROGEN FLUORIDE PRODUCED.
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL
AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTR TIGHTLY CLSD. STORE IN
SECURE POISON AREA. DO NOT STORE IN GLASS. USE WITH ADEQUATE
VENTILATION.
Other Precautions:SODIUM FLUORIDE REACTS W/ACIDS TO FORM HYDROGEN
FLUORIDE, WHICH IS HIGHLY CORROSIVE & POISONOUS - KEEP AWAY FROM
STRONG ACIDS. POISON! CAUSES SEV IRRIT. MAY BE FATAL IF
INGEST/INHALED. DO NOT GET IN E YES, ON SKIN/CLTHG. STORE AWAY
(SUPDAT)
* Physical/Chemical Properties *
HCC:T4
Vapor Density:1.4
Appearance and Odor:WHITE ODORLESS POWDER OR CRYSTAL.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, GLASS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:HYDROGEN FLUORIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL,
STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS IF TLV LIMIT IS EXCEEDED.
Ventilation:POSITIVE DOWN DRAFT EXHAUST SHOULD BE PROVIDED TO MAINTAIN
VAPOR CONCENTRATIONS BELOW TLV.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . NITRILE OR POLYETHYLENE APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CNDTNS (POLYM): CAUSING SMOKE, SKIN BURNS & STRONG IRRIT VAPS.FIRST
AID PROC:ACCIDENTS DUE TO CYANOACRYLATES ARE HNDLD BEST BY PASSIVE,
NON-SURGICAL FIRST AID: PULL SURFS APART W/DIRECT OPPOSING ACT ION.
EYELID TO EYELID/EYELID TO EYEBALL ADHESION:IN EVENT EYELIDS ARE
STUCK TOGETHER/BONDED TO EYEBALL, WASH(OTHER INFO)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:2-PROPENOIC ACID, 2-CYANO-, ETHYL ESTER; (ETHYL
CYANOACRYLATE)
Other REC Limits:2 PPM (MFR)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POLYMETHYLMETHACRYLATE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILICA, AMORPHOUS (FUMED); (SILICA AMORPHOUS)
OSHA PEL:6 MG/M3
Ingred Name:HYDROQUINONE; (HYDROQUINONE (1,4-BENZENEDIOL, HYDROQUINOL))
Fraction by Wt: 0.1-0.5%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:BONDS SKIN RAPIDLY AND STRONGLY.
SKIN AND EYE IRRITANT. SYMPS:VAPOR IS IRRITATING TO EYES AND MUCOUS
MEMBRANE ABOVE TLV. PROLONGED OR REPEATED OVEREXPOSURE TO VAPORS
MAY PRODUCE ALLERGIC REACTIO NS WITH ASTHMA LIKE SYMPTOMS IN
SENSITIVE INDIVIDUALS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMED . INHAL:REMOVE TO FRESH AIR. IF SYMPS
PERSIST, OBTAIN MED ATTN. SKIN:SOAK IN WARM WATER. EYE:FLUSH
FOR AD HESION OF HUMAN SKIN TO ITSELF IF CAUSED BY CYANOACRYLATE
ADHESIVES:CYANOACRYLATE ADHESIVE IS VERY FAST SETTING & STRONG
ADHESIVE. IT BONDS HUMAN SKIN IN SECONDS. EXPER HAS SHOWN THAT
TREATMENT OF SPE CIFIED TYPES OF ACCIDENTS ARE GIVEN:SKIN
ADHESION:FIRST IMMERSE BONDED SURFS IN WARM SOAPY WATER. PEEL/ROLL
SURFS APART W/AID OF BLUNT EDGE, E.G. SPATULA/TEASPOON HNDL, THEN
REMOVE ADHESIVE FROM SKIN W/SOAP & WATER. DO NOT TRY TO (SUP DAT)
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:FLOOD WITH WATER TO POLYMERIZE COMPLETELY.
SOAK UP WITH AN INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
SKIN AND EYES. AVOID BREATHING VAPOR.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Vapor Density:3
Solubility in Water:POLYMERIZED BY WATER
Appearance and Odor:CLEAR LIQUID/SHARP, IRRITATING ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
POLYMERIZED BY WATER, ALCOHOLS, AMINES OR ALKALIES.
Stability Condition to Avoid:ANY SITUATION CONTRIBUTING TO
POLYMERIZATION.
Hazardous Decomposition Products:THERMAL:IRRITATING ORGANIC FRAGMENTS.
NON-THERMAL:NONE.
Conditions to Avoid Polymerization:AVOID CONT W/CLOTHES, FABRICS,
RAGS/TISS. CONT W/THESE MATLS MAY CAUSE POLYM. POLYM OF LG AMTS
WILL GENERATE HEAT (SUP DAT)
* Toxicological Information*
Toxicological Information:OTHER INFO: MOUTH:IF LIPS ARE ACCIDENTALLY
STUCK TOGETHER, APPLY LOTS OF WARM WATER TO LIPS & ENCOURAGE MAX
WETTING & PRESS FROM SALIVA INSIDE MOUTH. PEEL/ROLL LIPS APART. DO
NOT TRY TO PULL LIPS W/DI RECT OPPOSING ACTION. IT IS IMPOSS TO
SWALLOW CYANOACRYLATE. ADHESIVE SOLIDIFIES & ADHERES IN MOUTH.
SALIVA WILL LIFT ADHESIVE IN 1/2-2 DAYS. IN CASE LUMP FORMS IN
MOUTH, POSITION PATIENT TO PVNT INGE ST OF LUMP WHEN IT DETACHES.
BURNS:CYANOACRYLATES GIVE HEAT ON SOLIDIFICATION. IN RARE CASES LG
DROP WILL INCR IN TEMP ENOUGH TO CAUSE BURN. BURNS SHOULD BE
TREATED NORMALLY AFTER LUMP OF CYANOACRYLAT E IS RELS FROM TISS AS
(ECOL INFO)
* Ecological Information *
Ecological:TOX INFO: DESCRIBED. SURGERY:IT SHOULD NEVER BE NECESSARY TO
USE SUCH A DRASTIC METHOD TO SEPARATE ACCIDENTALLY BONDED SKIN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . POLYMERIZE AS SHOWN IN SPILL PROCEDURES. INCINERATE
FOLLOWING EPA AND LOCAL REGULATIONS.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
NECESSARY.
Ventilation:USE ADEQUATE VENTILATION OR LOCAL EXHAUST VENTILATION TO
KEEP AIRBORNE CONCENTRATIONS BELOW PEL.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
FIRST AID PROC: IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE
OXYGEN. NOTES TO MD: TREAT SYMPTOMATICALLY & SUPPORTIVELY. OTHER
PREC: DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE SUBSTANCES .
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: KIDNEYS, CNS, LIVER.
ACUTE: EYES: IRRIT, TEARING, & BURNING PAIN. VAPS CAUSE IRRIT.
SKIN: IRRIT W/BURNING PAIN, ITCH, & REDNESS. INGEST: HARMFUL IF
SWALLOWED. MAY CAUSE CNS DEPRESS, KID NEY DMG, & LIVER DMG. EXPOS
TO SUBSTANCE HAS CAUSED CHANGES IN ORGAN WTS (INCL KIDNEY, LIVER,
HEART, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: LUNG, & BRAIN). INHAL: MAY CAUSE RESP
TRACT IRRIT, LIVER & KIDNEY DMG, DROW, UNCON, & CNS DEPRESS.
CHRONIC: PRLNG/RPTD EXPOS MAY CAUSE ADVERSE REPRO EFTS. MAY CAUSE
LIVER & KIDNEY DMG, FETAL EFTS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
OCCAS LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: IMMED FLUSH
CLTHG & SHO ES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF
CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID
IMMED. INHAL: GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR
IMMED. (SUP DAT)
* Fire Fighting Measures *
Lower Limits:2.2%
Upper Limits:9.2%
Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE, OR CHEMICAL FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:COMBUSTION GENERATES TOXIC GASES.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
REMOVE ALL SOURCES OF IGNITION. ABSORB SPILL USING AN ABSORBENT,
NON-COMBUSTIBLE MATERIAL SUCH AS EARTH, SAND, OR VERMICULITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE W/ADEQ VENT. AVOID CONT W/SKIN &
EYES. EMPTY CONTRS RETAIN PROD RESIDUE (LIQ &/VAP), & CAN BE
DANGEROUS.
Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE SUCH CONTRS TO HEAT, SPKS/OPEN FLAMES. KEEP CONTR
TIGHTLY CLSD. AVOID INGEST & INHAL. KEEP AWAY FROM SOURCES OF
IGNIT. STORE IN TIGHTLY CLSD CONTR. STORE IN COOL, (SUP DAT)
* Physical/Chemical Properties *
Evaporation Rate & Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:PRACTICALLY INSOL
Appearance and Odor:COLORLESS LIQUID; AROMATIC ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ALUMINUM.
Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CHLORINE, CARBON
MONOXIDE, CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
THIS MATERIAL IS BANNED FROM LAND DISPOSAL ACCORDING TO RCRA.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED < APPLIC
LIM BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD
BY NIOSH/ MSHA. WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST
RESP APPRVD BY NIOSH/ MSHA FOR PROT AGAINST NON-VOLATILE MATLS
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS MAINTAINED <
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:ENAMELS BULK-3. FIRE FIGHT PROC:PVNT PRESS
BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS TO EXTREME HEAT. EXPLO
HAZ:EMER CNDTNS OVEREXP TO DECOMP PROD MAY CAUSE HLTH HAZ. SYMP MA
Y NOT BE IMMED APPARENT. OBTAIN MED ATTN.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS) VP:
2
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:HNDLG/STOR PREC:OFF STOVES, ELEC TOOLS & APPLIANCES & ANY
OTHER SOURCES OF IGNIT. CONSULT NFPA CODE. USE APPRVD (ING 5)
Ingred Name:ING 4:BONDING & GROUNDING PROC. KEEP CNTNR CLSD WHEN NOT IN
USE. TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & (ING 6)
Ingred Name:ING 5:APPROP LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF
THE REACH OF CHILDREN.
Ingred Name:OTHER PREC:PRESENT AT HAZ LEVELS ONLY DURING
SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED,
(ING 8)
Ingred Name:ING 8: 5 MG/M3 (RESPIRABLE FRACTION).
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORDINATION ARE INDICATIONS
OF EXCESSIVE EXPOS TO VAP/S PRAY MISTS. REDNESS & ITCHING/BURNING
SENSATION MAY INDICATE EYE/ EXCESSIVE SKIN EXPOSURE. CHRONIC: (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:PRLNG OVEREXP TO SOLV INGRED IN PROD
MAY CAUSE ADVERSE EFTS TO LIVER & URINARY SYS. RATS EXPOS TO
SUCH EXPOS LEVELS ARE NOT ATTAINABLE IN THE WORKPLACE. RPTS HAVE
ASSOC RPTD & PRLNG OVEREXP TO SOLV W/PERM BRAIN & NERVOUS SYS DMG.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND
WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
MINUTES. GET MEDICAL ATTENTION. INGESTION: SEEK MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:1.0%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFTIVE. IF WATER USED, FOG NOZZ PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELEC EQUIP, SPK & OPEN
FLAME. CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME HEAT.
APPLICATN TO HOT SURF REQ SPECIAL PREC. DURING (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CONTENTS ARE COMBUST. KEEP AWAY FROM
HEAT, SPK & OPEN FLAME. VAP WILL ACCUM READILY & MAY IGNITE EXPLO.
DURING USE & UNTIL ALL VAP GONE:TURN (ING 4)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS
CAN BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY
MIST. AVOID CNTCT W/SKIN & EYES. COATINGS MAY CNTN MATLS CLASSIFIED
AS NUISANCE PARTICULATES WHICH MAY BE (ING 7)
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:SEE ING
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
EPA HAZ WASTE NOS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD
CNTNR. DISPOSE OF I/ A/ W FED, STATE & LOCAL REGS REGARDING
POLLUTION.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . LAB COAT. WEAR CHEMICAL RESISTANT CLOTHING.
Work Hygienic Practices:WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:OF CALCIUM IN 5% NITRIC ACID. EXPLO
* Product Identification *
Preparer's Name:VANAJA SIVAKUMAR
* Composition/Information on Ingredients *
Fraction by Wt: 2-5%
OSHA PEL:2 PPM
ACGIH TLV:2 PPM;4 STEL
Fraction by Wt: <2.5%
OSHA PEL:N/K
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPP DATA:CAUSE VIOLENT SPLATTERING.
Ingred Name:EFTS OF OVEREXP:CONC SOLNS CAUSE DEEP ULCERS & STAIN SKIN
BRIGHT YELLOW/YELLOWISH BROWN COLOR. VAP & MIST MAY (ING 6)
Ingred Name:ING 5:ERODE EXPOS TEETH W/PRLNG EXPOS. INGEST OF LIQ WILL
CAUSE IMMED PAIN & BURNS OF MOUTH, ESOPHAGUS & GI (ING 7)
Ingred Name:ING 6:TRACT. INHAL MAY BE FATAL CAUSING SPASM, INFLAMM &
EDEMA OF THE LARYNX & BRONCHI, CHEM PNEUM & PULM EDEMA. (ING 8)
Ingred Name:ING 7:SYMPS INCL; BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA & VOMITING.
Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD .
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SYMPS & HLTH HAZS FOR DILUTE NITRIC
ACID ARE EXPECTED TO BE LESS SEV THAN EXPOS TO CONC NITRIC ACID.
GREATER, HLTH HAZS FOR CONC NITRIC A CID ARE GIVEN. THIS SOLN IS
HARMFUL IF INHALED, INGESTED/CONTACTED W/SKIN OR EYES. CALCIUM
CARBONATE IS(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SEV TO MOD SKIN IRRIT. CONC NITRIC
ACID MAY BE FATAL IF TOO MUCH IS INHALED/ABSORBED THRU SKIN. CONC
NITRIC ACID VAP/MIST IS IRRIT OF EYES, MUC MEMBS & SKIN. IN CONT
W/EYES, IT PRDCES SEV BUR NS WHICH MAY RSLT IN PERM DMG & VISUAL
IMPAIRMENT. ON SKIN, LIQ/CONC VAP PRDCES IMMED, SEV & PENETRATING
BURNS; (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
LIFTING UPPER & LOWER EYELIDS. SKIN:REMOVE CONTAMINATED
THOROUGHLY BEFORE REU SE. INHAL:MOVE TO FRESH AIR. IF IRRITATION
CONTINUES, GET MEDICAL ATTENTION IMMEDIATELY. INGEST:GET MEDICAL
ATTENTION IMMEDIATELY. IF THE VICTIM IS CONSCIOUS, GIVE LARGE
AMOUNTS OF WATER OR MILK.
* Fire Fighting Measures *
Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONC HNO*3 IS NOT COMBUST, BUT IS STRONG
OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTS MAY CAUSE
IGNIT. CAN REACT W/METALS TO RELS FLAMM (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUT W/SODA
ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR PROPER
DISPOSAL. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS
APPROVED RESP.
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.
*Handling and Storage *
Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK
SOME FORMS OF PLASTICS, RUBBER & COATINGS. STORE AT ROOM
TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:IRRITANT, OXIDIZER & CORROSIVE LIQUID. AVOID
INHALATION, INGESTION & CONTACT W/EYES & SKIN.
HAZ:HYDROGEN GAS. CONC HNO*3 REACTS EXPLO W/COMBUST ORG/READILY
OXIDIZABLE MATLS SUCH AS; ALCOHOL, WOOD, TURPENTINE, METAL PWDRS,
HYDROGEN SULFIDE, ETC. MATLS TO AVOID:WOOD, TURPENTINE, METAL
PWDRS, HYDROGEN SULFIDE, ETC. CONT W/STRONG BASES WILL (ING 4)
* Physical/Chemical Properties *
Spec Gravity:1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT W/ACRID ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONC HNO*3 IS POWERFUL OXIDIZING AGENT. IT REACTS EXPLO W/COMBUST
ORG/READILY OXIDIZABLE MATLS SUCH AS; ALCOHOL,(SUPDAT)
Stability Condition to Avoid:ELEVATED TEMPERATURES MAY CAUSE CONTAINERS
TO BURST & LIBERATE TOXIC OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES & VAPORS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE DISPOSAL
AGENCY FOR REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS.CAUSES STILLBIRTHS.IRRITATES
EYES,NOSE,THROAT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA)
* First Aid Measures *
First Aid:EYES:FLUSH W/WATER IMMED.SKIN:WASH W/SOAP IMMED.INHAL:REMOVE
TO FRESH AIR.GIVE ART.RESPIR.AS NEEDED.INGEST:GET MEDICAL ATTN.GIVE
LARGE QTY OF SALT WATER,INDUCE VOMITING,BUT DO NOT MAKE UNCONSCIOUS
PER SON VOMIT.
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
*Handling and Storage *
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
* Physical/Chemical Properties *
HCC:Z3
Appearance and Odor:LIGHT STRAW COLORED LIQUID,AROMATIC ODOR.
* Stability and Reactivity Data *
STRONG OXIDIZERS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AVOID PROLONGED BREATHING OF VAPOR. USE NIOSH
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NONE REQUIRED.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA: REIGNITED ON SURF OF WATER. EXPLO HAZ: BUILD-UP WHICH
COULD RSLT IN CONTR RUPTURE.
* Product Identification *
CAGE:THOMP
CAGE:THOMP
* Composition/Information on Ingredients *
OSHA PEL:0.5 MG/M3 (MFR)
ACGIH TLV:0.5 MG/M3 (MFR)
Ingred Name:NAPHTHA, HEAVY STRAIGHT RUN; (NAPHTHA (PETROLEUM), HEAVY
STRAIGHT-RUN)
Fraction by Wt: 1-2%
Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC
Ingred Name:STODDARD SOLVENT
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: AVOID PROLONGED
BREATHING OF VAPOR OR SPRAY MIST. SKIN/EYES/INGESTION: NONE
EXPECTED. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PREEXISTING LUNG DISORDERS MAY BE
AGGRAVATED BY INHALATION DURING USE.
* First Aid Measures *
First Aid:INHALATION: IF BREATHING IS AFFECTED, IMMEDIATELY MOVE TO
FRESH AIR. SKIN: IN KEEPING WITH GOOD HYGIENIC PRACTICES, WASH
THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, CONTACT MD.
EYES: AS IN THE CASE WHEN ANY FOREIGN MATTER CONTACT THE EYE,
RINSE THOROUGHLY WITH WATER. INGESTION: CONTACT MD OR A POISON
CONTROL CENTER.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEM/CARBON DIOXIDE. DO NOT
USE DIRECT STREAM OF WATER. PROD WILL FLOAT & CAN BE (SUP DAT)
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . COMBUSTIBLE. USE WATER SPRAY TO COOL FIRE-EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:COMBUST. CONTAINS PETRO DISTILS. KEEP
AWAY FROM HEAT & FLAME. CONTRS EXPOSED TO INTENSE HEAT FROM FIRES
SHOULD BE COOLED W/WATER TO PVNT VAP PRESS (SUP DAT)
* Accidental Release Measures *
Spill Release Procedures:ABSORB SMALL SPILLS W/SAND/OTHER SUITABLE
ABSORB MATL & PLACE IN CONTR FOR DISP. FOR LARGE SPILLS, AREA MAY
BE SLIPPERY, DIKE AROUND SPILL W/ABSORB MATL. TRANSFER LIQS &
CONTAM DIKING MATL TO SEPARATE , SUITABLE CONTRS FOR
RECOVERY/DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:COMBUSTIBLE. CONTAINS PETROLEUM
DISTILLATES. AVOID PROLONGED BREATHING OF VAPOR. KEEP OUT OF REACH
OF CHILDREN.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Vapor Density:4.8
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORED, VISCOUS LIQUID WITH PETROLEUM SOLVENT ODOR
Percent Volatiles by Volume:SUPDAT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, ALL SOURCES OF
HEAT OR IGNITION.
Hazardous Decomposition Products:HYDROCARBON FUMES, SMOKE, CARBON
MONOXIDE (WHERE COMBUSTION IS INCOMPLETE) MAY BE FORMED DURING
THERMAL DECOMPOSITION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH CERTIFIED MIST RESPIRATORY WHERE
Ventilation:USE WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED.
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Work Hygienic Practices:AVOID CONTACT WITH EYES, SKIN, AND CLOTHING.
WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SPILL PROC: NATRL WATERWAYS. IF CONTAINMENT IS IMPOSSIBLE, NEUT CONTAMD
AREA & FLUSH W/LG QTYS OF WATER. CLEAN UP ANY REMAINING SOLIDS &
DISPOSE OF I/A/W FED, STATE/LOC REQUIREMENTS. COMPLY W/APPLIC E
NVIR REGS. AIR SPILL: ONLY WATER WILL EVAP FROM SPILL. MATL DOES
NOT CONSTITUTE AIR POLLUTION HAZARD. (OTHER INFO)
* Product Identification *
Product ID:N (R) SODIUM SILICATE
Resp. Party Other MSDS Num.:PQN
CAGE:0STM5
CAGE:0STM5
* Composition/Information on Ingredients *
Ingred Name:WATER
Ingred Name:SODIUM SILICATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:POTENTIAL HEALTH EFFECTS: ACUTE: EYE
CONT: CAUSES EYE IRRITATION. SKIN CONT: CAUSES SKIN IRRITATION.
INGEST: MAY CAUSE IRRITATION TO MOUTH, ESOPHAGUS, AND STOMACH.
INHAL: INHALATION OF SPRAY MIST CAUS ES IRRITATION TO RESPIRATORY
TRACT. SIGNS & SYMPTOMS OF EXPOSURE: EYES: PAIN, REDNESS, AND
TEARING. SKIN: REDNESS, ITCHING OR BURNING. INGEST: BITTER TASTE,
PAIN IN MOUTH OR DIGESTIVE TRACT, NAUSEA. I NHAL: SNEEZING,
COUGHING, BURNING OR ITCHING IN NOSE AND THROAT. POTENTIAL PHYSICAL
HAZARDS: CHRONIC: REPEATED INGESTION OF LARGE QUANTITIES (>1 GRAM)
MAY CAUSE KIDNEY STONES OR OTHER KIDNEY CHANGES. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:THERE ARE NO KNOWN REPORTS OF
CARCINOGENICITY OF SODIUM SILICATES.
Effects of Overexposure:HLTH HAZS: DRIES TO FORM GLASS FILM WHICH CAN
EASILY CUT SKIN. SPILLS ARE VERY SLIPPERY. CAN ETCH GLASS IF NOT
PROMPTLY REMOVED. TARGET ORGANS: ACUTE ORAL LETHALITY RSLTS FROM
NONSPECIFIC CAUSES. TARG ET ORGANS FOR ACUTE SKIN, EYE, &
INHALATION EXPOSURE ARE THE SITES OF EXPOSURE; NO SYSTEMIC TOXICITY
IS OBSERVED.
Medical Cond Aggravated by Exposure:INHALATION OF SPRAY MIST MAY
AGGRAVATE ASTHMA AND LUNG DISEASES. CONTACT WITH SKIN MAY AGGRAVATE
PREEXISTING SKIN CONDITIONS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYGEN. EYE CONT: IMMEDIATELY FLUSH W/PLENTY
FLUSH W /PLENTY OF WATER. REMOVE CONTAMD CLOTHING & SHOES. GET
MEDICAL ATTN. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES
BEFORE REUSE. INGEST: DO NOT INDUE VOMITING. GET MEDICAL ATTN
IMMEDIATELY. IF VI CTIM IS FULLY CONSCIOUS, GIVE CUPFUL OF WATER.
NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Extinguishing Media:NOT APPLICABLE. NONCOMBUSTIBLE. MEDIA SUITABLE FOR
SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
* Accidental Release Measures *
Spill Release Procedures:RELEASE NOTES: THERE IS NO CERCLA REPORTABLE
QTY DESIGNATED FOR MATL. IF SPILL GOES OFF SITE, NOTIFICATION OF
STATE & LOC AUTH IS REC. SM SPILL: MOP UP & NEUT LIQ, THEN
DISCHARGE TO SEWER I/A/W FED, S TATE, & LOC REGS/PERMITS. LG SPILL:
ISOLATE, DIKE & STORE DISCHARGED MATL, IF POSS. USE SAND/EARTH TO
CNTN SPILL MATL. PVNT RUNOFF FROM ENTERING INTO STORM SEWERS &
DITCHES WHICH LEAD TO (SUPDAT)
*Handling and Storage *
KEEP CNTNR CLSD. PROMPTLY CLEAN RESIDUE FROM CLOSURES W/CLOTH
DAMPENED W/WATER. SHELF LIFE: INDEFINITE, IF STORED W/IN SPECIFIED
TEMPS IN TIGHTLY CLSD CNTNRS TO PVNT EVAPORATION & CONTAMINATION.
Other Precautions:STORE IN CLEAN STEEL, OR PLASTIC CONTAINERS. SEPARATE
FROM ACIDS, REACTIVE METALS, AND AMMONIUM SALTS. SPEC SENSITIVITY:
DO NOT STORE IN ALUMINUM, FIBERGLASS, COPPER, BRASS, ZINC OR
GALVANIZED CONTAIN ERS.
* Physical/Chemical Properties *
Evaporation Rate & Reference:NOT DETERMINED
Solubility in Water:COMPLETELY MISCIBLE
Appearance and Odor:CLEAR TO HAZY, THICK LIQUID. COLORLESS. ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
GELS & GENERATES HEAT WHEN MIXED W/ACID. MAY REACT WITH AMMONIUM SALTS
RESULTING IN EVOLUTION OF AMMONIA GAS.
Stability Condition to Avoid:FLAMMABLE HYDROGEN GAS MAY BE PRODUCED ON
PROLONGED CONTACT WITH ALUMINUM, TIN, LEAD AND ZINC.
Hazardous Decomposition Products:HYDROGEN.
* Toxicological Information*
Toxicological Information:LIFETIME FEEDING STUDY OF ZEOLITE A (WHICH
RAPIDLY DECOMPOSES TO AMORPHOUS SODIUM ALUMINATES & SODIUM SILICATE
0.1% IN DIET OF RATS DI D NOT PRDCE CANCER/CHRONIC ORGAN TOX.
FREQUENT INGEST OVER EXTENDED PERIODS OF TIME OF GRAM QTYS OF
SILICATES IS ASSOC W/FORMATION KIDNEY STONE & OTHER SILICEOUS
URINARY CALCULI IN HUMANS. MUTAGENCITY : SODIUM SILICATE WAS NOT
MUTAGENIC TO BACTERIUM E. COLI WHEN TESTED IN MUTAGENICITY
BIOASSAY. REPRODUCTION: ONE STUDY RPTD DECR NUMBERS OF BIRTHS
(TRANSPORT INFO)
* Ecological Information *
Ecological:CHEM FATE INFO: DILUTE MATL RAPIDLY DEPOLYMERIZES TO YIELD
DISSOLVED SILICA IN FORM THAT IS INDISTINGUISHABLE FROM NATRL
DISSOLVED SILICA. DOES NOT CONTRIBUTE TO BOD. DISTRIBUTION: ONLY
WATER CONTENT WILL EVAP TO AIR. WHERE ABNORMALLY LOW NATRL SILICA
CONCS EXIST (<0.1PPM), DISSOLVED SILICA MAY BE LIMITIING NUTRIENT
FOR DIATOMS & FEW OTHER AQUATIC ALGAL SPECIES. HOWEVER, ADDN OF
EXCESS DISSOLVED S ILICA OVER LIMITING CONC WILL NOT STIMULATE
GROWTH OF DIATOM POPULATIONS; THEIR GROWTH RATE IS INDEPENDENT OF
SILICA CONC ONCE LIMITING CONC IS EXCEEDED. (SARA TITLE III)
* Disposal Considerations *
Waste Disposal Methods:RCRA HAZARD CLASS: NOT RCRA HAZ WASTE. DISPOSAL:
NEUT & LANDFILL SOLIDS ACCORDING TO LOCA, STATE, AND FEDERAL REGS.
FLUSH NEUT LIQ TO SEWER I/A/W FEDERAL, STATE, AND LOCAL REGULATIONS
OR PERMITS.
* MSDS Transport Information *
Transport Information:DOMESTIC (U.S. D.O.T.). OTHER SHIPPING INFO:
SODIUM SILICATE. SPECIAL SHIPPING NOTES: THIS MATEIRAL IS NOT A
DOT REGULATED HAZARDOUS MATERIAL. FOOTNOTES. THIS IS NOT A DOT
REGULATD HAZ MATL. TOX INFO : & SURVIVAL TO WEANING IN RATS FED
NO OTHER RPTS OF ADVERSE REPRO EFTS OF SODIUM SILICATE. FOR MORE
SPECIFIC INFORMATION CONT NEHC .
* Regulatory Information *
Y.--ECOLOGICAL INFO: NEITHER SILICA NOR SODIUM WILL APPRECIABLY
BIOCONCENTRATE UP FOOD CHAIN. ECOTOX INFO: FOLLOWING DATA IS RPTD
INFO CONT NECH .
Federal Regulatory Information:CERCLA REGULATORY: THERE IS NO CERCLA
REPORTABLE QTY FOR THIS MATL. GEN REGULATORY: USE OF SODIUM
SILICATE IS AUTHORIZED BY FDA: AS BOILER WATER ADDITIVE FOR
WHEN MIGRATING FROM COTTON/COTTON FABRIC US ED IN DRY SUBSTANCE
INFO)
State Regulatory Information:FED REGULATORY: OF THIS PROD APPEAR ON
MATL IS NOT A RCRA HAZ WAST E. TSCA REGULATORY: ALL CHEM
SUBSTANCESCOMPRISING THIS RPOD ARE LISTED ON TSCA INVENTORY. TSCA
STATUS: ALL COMPONENTS OF THIS PROD ARE LISTED ON TSCA INVENTORY.
OTHER INFO: BOOTS. GENERAL PROCEDURES: ISOLATE HAZARD AREA. SHUT
OFF LEAK IF SAFE TO DO SO.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED UNDER NORMAL OPERATING CONDITIONS.
HOWEVER, IF GENERATION OF DUST ALLOWS PEL'S TO BE EXCEEDED, WEAR
NIOSH APPROVED RESPIRATOR FOR DUSTS.
Ventilation:USE LOCAL EXHAUST TO REMOVE DUST OR FUMES IF GENERATED.
Other Protective Equipment:EYE WASH & DELUGE SHWR MTG ANDI DESIGN CRIT.
USE CLOTHING SUFFICIENT TO PREVENT SKIN CONT FROM DUST/FUMES WHEN
NEEDED. BARRIER CREAMS MAY HELP TO PREVENT SKIN IRRITATION IN
HYPERSENSITIVE PERSONS.
Work Hygienic Practices:WASH HANDS THOROUGHLY BEFORE EATING OR SMOKING.
NO CONTACT LENSES.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:F. COOPER
* Composition/Information on Ingredients *
Ingred Name:GRAPHITE. NIOSH REL: 2.5 MG/M3 RESP (M).
ACGIH TLV:2 MG/M3
Ingred Name:ACRYLIC POLYMERS
Ingred Name:VINYL ALCOHOL POLYMER
< Wt:1.
ACGIH TLV:0.1 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NONE UNDER NORMAL CONDITIONS OF USE.
HOWEVER, OVEREXPOSURE TO DUST MAY PRODUCE SYMPTOMS INCLUDING
CHILLS, FEVER, MUSCULAR PAIN, NAUSEA AND VOMITING. CHRONIC EXPOSURE
TO DUST MAY CAUSE RESPIRATORY TRAC T IRRITATION. PROLONGED EXPOSURE
TO DUST MAY RESULT IN DECREASED PULMONARY FUNCTION, PROGRESSIVE
RESPIRATORY SYMPTOMS (SILICOSIS). LUNG FIBROSIS AND BLACK SPUTUM.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC
Effects of Overexposure:NONE UNDER NORMAL CONDITIONS OF USE. HOWEVER,
IF GENERATION OF DUST OR PARTICULATE MATTER OCCURS, IRRITATION TO
EYES, SKIN AND UPPER RESPIRATORY TRACT MAY RESULT.
Medical Cond Aggravated by Exposure:INHALATION OF DUST MAY BE AN
IRRITANT TO PRE-EXISTING RESPIRATORY CONDITIONS.
* First Aid Measures *
First Aid:INHALATION: SYMPTOMS RESULTING FROM INHALATION OVEREXPOSURE
MEDICAL ATTENTION. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . INGESTION:
UNLIKELY. CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM. DO NOT USE
WATER.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . EVACUATE ALL NON-ESSENTIAL PERSONNEL FROM AREA. DO NOT
SPREAD BURNING MATERIAL. SMOTHER AND ALLOW FIRE TO GO OUT.
Unusual Fire/Explosion Hazard:DRY DUST MAY FORM AN EXPLOSIVE MIXTURE
WITH AIR. TOXIC DECOMPOSITION FUMES MAY BE EMITTED IN A FIRE.
HAZARD RATING: HEALTH - 2; FLAMMABILITY - 0; REACTIVITY - 1.
* Accidental Release Measures *
Spill Release Procedures:SWEEP OR SHOVEL SOLID MATERIAL. IF DUST IS
GENERATED, SWEEP OR VACUUM IN A MANNER SO AS NOT TO CREATE ANY
ADDITIONAL DUST. PROHIBIT SMOKING AND AVOID ALL IGNITION SOURCES.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY, VENTILATED AREA
SEPARATE FROM ACIDS AND ALKALIS.
Other Precautions:AVOID CREATING DUST. FOLLOW GOOD INDUSTRIAL
HOUSEKEEPING AND PERSONAL HYGIENE PRACTICES.
* Physical/Chemical Properties *
Solubility in Water:INSOLUBLE
Appearance and Odor:BLACK BRAIDED YARN COATED WITH FINE GRAY DUST.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS INCLUDING SUCH AS FLUORINE, CHLORINE TRIFLUORIDE,
HYDROGEN PEROXIDE, ACETYLENE, AMMONIA AND POTASSIM PEROXIDE.
Stability Condition to Avoid:STRONG OXIDIZERS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE AND
VARIOUS OTHER TOXIC DECOMPOSITION PRODUCTS MAY BE EMITTED IN A
FIRE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Toxicological Information*
Toxicological Information:NO SPECIFIC INFORMATION IS AVAILABLE. PLEASE
REFER TO HEALTH HAZARDS SECTION FOR AVAILABLE INFORMATION ON
POTENTIAL HEALTH EFFECTS.
* Ecological Information *
Ecological:NO SPECIFIC ECOLOGICAL INFO IS AVAILABLE FOR THIS PROD.
FIRE & EXPLOS HAZ:AEROSOL CNTNRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT. PROD VAPORS ARE HVR/AIR & MAY TRAVEL A LONG DIST TO A
SOURCE OF IG NIT & FLASH BACK. WATER SPRAY SHOULD NOT BE USED
EXCEPT TO KEEP DOWN VAPS/ COOL CLSD CNTNRS TO PVNT BUILD-UP OF
PRESS. IF WATER IS USED, FOG NOZZLES ARE PREFERRED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL
REGULATIONS. CONTAIN IN DRY CLOSED CONTAINER. NOT CONSIDERED AN
RCRA WASTE. MATERIAL CAN BE LANDFILLED AT A PERMITTED FACILITY.
* MSDS Transport Information *
Transport Information:PROPER SHIPPING NAME: BRAIDED PACKING. UN NO:
N/A. HAZARD CLASS: N/A. LABELS REQUIRED: N/A.
* Regulatory Information *
SARA Title III Information:ZINC AND LEAD ARE REPORTABLE UNDER SARA
State Regulatory Information:
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO SPECIAL REQUIREMENTS.
Ventilation:NO SPECIAL REQUIREMENTS.
Other Protective Equipment:NO SPECIAL REQUIREMENTS.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:AQUEOUS SOLUTION,HAZARD UNKNOWN,UNIDENTIFIED INGREDIENTS
Fraction by Wt: 7.5%
* Hazards Identification *
Effects of Overexposure:EYES:CONTACT WITH LIQUID CAUSES
BURNS.SKIN:PROLONGED OR REPEATED CONTACT MAY CAUSE IRRITATION.
* First Aid Measures *
First Aid:INHALE:REMOVE TO FRESH AIR, GIVE CPR/O*2 IF
* Fire Fighting Measures *
Extinguishing Media:NON FLAMMABLE:USE MEDIA SUITABLE FOR SURROUNDING
FIRE
Fire Fighting Procedures:SELF-CNTND BRTHG APP;H*2O SPRAY COOL CONT.
Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE IN HEAT OF FIRE.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. PROVIDE
VENTILATION. STOP LEAK. H*2O SPRAY COOL CONT(IF HOT).SM
SPILL:ABSORB W COMMERCIAL ABSORBENT,SHOVEL INTO METAL DRUMS;LG
SPILL:DIKE W COMMERCIAL ABSORBENT,PUMP INTO COVERED DRUMS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY WELL VENTILATED
AREA.KEEP CONTAINERS TIGHTLY CLOSED.PROTECT FORM PHYSICAL DAMAGE.DO
Other Precautions:MAINTAIN STANDARD HYGIENE FOR CHEMICAL HANDLING.WASH
HANDS THOROUGHLY AFTER HANDLING.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID,NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:KEEP IN COVERED CONTAINERS PENDING DISPOSAL.
HANDLE ANDDISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE AND LOCAL REGULATIONS.MANUFACTURER
STATES MATERIAL MAY BE DISPOSED BYCONTROLLED BURNING.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS ARE INADEQUATE TO
CONTROL DUST CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A
NIOSH-APPROVED DUST RESPIRATOR IS RECOMMENDED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Other Protective Equipment:LONG SLEEVE WORK CLOTHING, EYE WASH
FOUNTAIN, WASHING FACILITY
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, DRINKING OR
SMOKING. VACUUM UP ANY DUST. LAUNDER CLOTHING BEFORE REUSE.
Supplemental Safety and Health
THE RESPIRABLE FRACTION OF CRYSTALLINE SILICA QUARTZ IS ONLY 0.1 -
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
Fraction by Wt: 1 - 3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE TABLE Z-3
Ingred Name:ALUMINUM SILICATE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY
TRACT. ACUTE- EYES:MAY CAUSE IRRITATION & DISCOMFORT. SKIN:MAY
CAUSE IRRITATION, REDNESS. INHALE:CAUSES RESPIRATORY TRACT
IRRITATION & MAY CAUSE DISABLING, PROGRES SIVE PULMONARY FIBROSIS
(SILICOSIS). ORAL:NO ADVERSE EFFECTS EXPECTED. CHRONIC- INHALATION
MAY CAUSE LUNG DAMAGE.
Explanation of Carcinogenicity:CONTAINS CRYSTALLINE SILICA (QUARTZ).
Effects of Overexposure:IRRITATION, COUGH, WHEEZING, CHEST DISCOMFORT,
TEARING
Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE
EXISTING MEDICAL CONDITIONS SUCH AS RESPIRATORY AILMENTS.
* First Aid Measures *
First Aid:GET MEDICAL CARE IF SYMPTOMS PERSIST. EYES: IMMEDIATELY FLUSH
WATER. INHALED: MOVE TO FRESH AIR. IF BREATHING IS DIFFICULT,
PROVIDE OX YGEN. ORAL: PROCEDURES NORMALLY NOT NEEDED. IF LARGE
QUANTITIES INGESTED, CONTACT PHYSICIAN. NOTE TO PHYSICAN:DESICCANT
GENERATES HEAT AS IT ADSORBS WATER. USED PRODUCT CAN CONTAIN
HAZARDOUS CHEMICALS
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:UNUSED MATERIAL WILL NOT BURN. USE WATER, CARBON
DIOXIDE OR FOAM FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. USED MATERIAL MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. CAREFULLY SWEEP OR
VACUUM THE SPILL AREA. COLLECT AND PLACE THE SPILLED MATERIAL IN A
WASTE DISPOSAL CONTAINER. AVOID DUSTING. SPILL BECOMES SLIPPERY
WHEN WET. WASH SPILL SI TE AFTER PICK-UP IS COMPLETE.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY PLACE, IN TIGHTLY CLOSED
CONTAINER, AWAY FROM INCOMPATIBLE MATERIALS. KEEP OUT OF REACH OF
CHILDREN. AVOID DUST COLLECTION.
PROPERLY FITTED NIOSH-APPROVED DUST RESPIRATOR FOR DUSTY
CONDITIONS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. AVOID CONTACT WIT H EYES. OPEN CONTAINER SLOWLY.
* Physical/Chemical Properties *
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN
Spec Gravity:2.0
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GREY TO OFF-WHITE GRANULES; ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ALKALI, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:MOISTURE
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:DISCARD ANY PRODUCT (INCLUDING ANY RETAINED
MATERIALS OF USE), DISPOSABLE CONTAINERS OR LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS. US EPA WASTE NUMBER: NOT REGULATED.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR
VAPORS DURING SPRAY APPLICATION. IN CONFINED AREAS: USE NIOSH
Ventilation:PROVIDE GENERAL DILUTION/LOCAL EXHAUST VENT IN VOL &
PATTERN TO KEEP TLV OF HAZ INGREDIENTS BELOW ACCEPTABLE LIMITS.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:RWB/AMB
* Composition/Information on Ingredients *
Fraction by Wt: 0.5%
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL). LEL: 1.1% VP: 0.9 @
Fraction by Wt: 0-3%
Fraction by Wt: 1-4%
Fraction by Wt: 1%
Ingred Name:SUPDAT: WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Ingred Name:ING 9:ASSOCIATED WITH LIVER, KIDNEY, LUNG, SPLEEN AND EYE
ABNORMALITIES IN LAB ANIMALS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUES, BLOOD,
KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER
APPEARS ON THE NAVY LISTING OF OCCUP CHEM REPROD HAZ. SEEK (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . ACUTE: INHAL: HARMFUL IF INHALED. MAY AFFECT BRAIN/NERVOUS
SYS CAUSING DIZZ, HDC H/NAUSEA. RPTD OVEREXPS MAY PROGRESSIVELY
LEAD TO STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS/COMA. CAUSES
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: REMOVE FROM EXPOSURE, RESTORE BREATHING & NOTIFY A MD.
MIN. NOTIFY A MD. SKIN: WASH AFFECTED AREA W/SOAP & WATER, REMOVE
CONTAMIN ATED CLOTHING & WASH BEFORE REUSE. INGEST: DO NOT INDUCE
VOMITING. KEEP PERSON WARM, QUIET & GET MED ATTN. ASPIRATION OF
THIS MATERIAL INTO THE LUNGS CAN CAUSE CHEM PNEUMONITIS WHICH CAN
BE FATAL.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:SEE INGRED
Extinguishing Media:HFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY
CHEMICAL OR FOAM).
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. H*2O MAY BE USED TO COOL CLSD CNTNRS TO
PVNT PRESS BUILD-UP & POSSIBLE (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. DO NOT APPLY TO HOT SURFS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA
AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
PUNCTURE/INCINERATE CNTNRS. INTENTIONAL MISUSE BY DELIB
CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL OR FATAL.
CONTAIN CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH
DEFECTS OR OTHER REPRODUCTIVE HARM.
FIRE FIGHT PROC: AUTOIGNITION/EXPLOSION. IF H*2O IS USED, FOG NOZZLES
ARE PREFERRED. EFTS OF OVEREXP: NOSE & THROAT IRRIT. SKIN/EYES:
CAUSES EYE & SKIN IRRIT WHICH CAN LEAD TO DERM W/RPTD OVEREXP. ING
EST: MAY CAUSE GI IRRIT, NAUSEA, VOMIT & DIARR. CHRONIC: RPTS HAVE
ASSOC RPTD & PRLNGD OCCUP OVERXP TO SOLVENTS (ING 9)
* Physical/Chemical Properties *
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER (ETHER = 1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY OPEN FLAME: CARBON MONOXIDE AND
CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL
REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN.
Ventilation:SUFFICIENT MECHANICAL(GENL) &/OR LOCAL EXHAUST TO KEEP <
TLV
Other Protective Equipment:LONG SLEEVES,EYEWASH FOUNTAIN,SFTY
SHOWER,IMPERV APRON,BOOTS
Supplemental Safety and Health
SPECIAL FIRE PROC:FACEPIECE,FULL PROT CLTHG. OVEREXP EFTS:IRRIT,POSS
BURNS.INGEST:MOUTH,THROAT,DIGESTIVE TISSUE IRRIT &/OR BURNS. DATE
* Product Identification *
Product ID:ALKASTRIP SQ
* Composition/Information on Ingredients *
Ingred Name:ETHANOLAMINE
OSHA PEL:3 PPM/6 STEL
* Hazards Identification *
Effects of Overexposure:EYE/SKIN:LIQ OR MIST POSS IRRIT OR
BURNS.INHAL:EXCESS MIST OR VAPOR POSS NASAL,RESP (SEE SUPP DATA)
* First Aid Measures *
CLTHG,SHOES.WASH BEFORE REUSE(DESTROY CONTAM SHOES).CALL
MD.INHAL:RMV TO FRE SH AIR;IF BRTHG DIFFICULT,CALL MD.(SEE OTHR
PREC)
* Fire Fighting Measures *
Flash Point:NONE;H*2O SOLN
Extinguishing Media:N/A (MFR)
Fire Fighting Procedures:NIOSH/MSHA APPRVD PRESS DEMAND SCBA W/FULL
(SEE SUPP DATA)
Unusual Fire/Explosion Hazard:CORROSIVE ALKALINE LIQ.PRLNG CONTCT
W/AMPHOTERIC METALS(AL) MAY GENERATE HYDROGEN-FLAM,EXPLOSIVE.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROT CLTHG/EQUIP DESCRIBED IN SPECIAL
PROT INFORMATION SECTION.ABSORB SPILL W/INERT ABSORBENT MATL(SUCH
AS SPILL PILLOWS) & TRANSFER TO A SUITABLE WASTE
CONTAINER.FOLLOWING REMOVAL OF ABSORBENTS, FLUSH SPILL SITE
W/PLENTY OF H*2O.
*Handling and Storage *
DIRECT SUN & AWAY FROM INCOMPATIBLES.DONT GET IN EYES,ON
SKIN/CLTHG.WASH WELL AFTER HANDLE.KEEP CNTNR CLOSED.
Other Precautions:AVOID BRTHG MIST/VAPOR.USE W/ADEQUATE VENT.DONT
INGEST. FIRST AID PROC:INGEST:DONT INDUCE VOMIT.GIVE PLENTY OF
H*2O,FOLLOWED BY @ LEAST 1 OZ. VINEGAR OR LEMON JUICE IN EQUAL AMT
H*2O,CALL MD.
* Physical/Chemical Properties *
Vapor Pres:< 5
Vapor Density:> 1
Spec Gravity:1
Evaporation Rate & Reference:<1 (BU ACET)
Solubility in Water:COMPLETE
Appearance and Odor:WATER-WHITE LIQUID;MILD AMMONIA-LIKE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDIC MATL,ALUMINUM,TIN,ZINC,COPPER (ALLOYS OF THESE METALS
Hazardous Decomposition Products:CO,CO*2,POSSIBLE NO*X.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE &
LOCAL REGULATIONS.SPILL-CONTAMINATED ABSORBENTS CAN BE SENT TO
APPROVED CHEMICAL WASTE LANDFILL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED ORGANIC RESPIRATOR IF TWA/TLV
LIMITS ARE EXCEEDED.
Ventilation:USE GENERAL & LOCAL EXHAUST VENTILATION TO MAINTAIN PEL/TLV
BELOW LIMITS. USE NON SPARKING EQUIPMENT.
Other Protective Equipment:NONE.
Work Hygienic Practices:MFR GAVE NO INFORMATION OF MSDS.
Supplemental Safety and Health
NONE
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MOLYBDENUM DISULFIDE
Other REC Limits: SPECIFIED
Ingred Name:GRAPHITE
Other REC Limits: SPECIFIED
Ingred Name:NON-IONIC WETTING AGENT
Other REC Limits: SPECIFIED
Ingred Name:INORGANIC SILICATE BINDER
Other REC Limits: SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MOLYBDENUM COMPOUNDS MAY BE SLIGHTLY
IRRITATING. GRAPHITE DUST CAN PRODUCE PNEUMONOCONIOSIS. NON-IONIC
WETTING AGENT IS A SEVERE EYE & MODERATE SKIN IRRITANT. THIS
INORGANIC BINDER IS A SKIN AND SEVER E EYE IRRITANT AND CAUSES
Explanation of Carcinogenicity:MFR GAVE THE ABOVE LISTINGS ON THE MSDS
BUT NO OTHER COMMENTS ABOUT CARCINOGENICITY WERE RECORDED.
Effects of Overexposure:EYES:IRRITATION, REDNESS, BLURRED VISION.
SKIN:IRRITATION, NAUSEA, VOMITING & DIARRHEA. INGESTION:G/I
IRRITATION, NAUSEA, VOMITING, & DIARRHEA.
Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION OF MSDS.
* First Aid Measures *
First Aid:SKIN:WASH W/SOAP & WATER. EYES:FLUSH W/COPIOUS AMOUNTS OF
WATER, GET MEDICAL ATTENTION. INGESTION:DO NOT INDUCE VOMITING,
KEEP WARM, GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Lower Limits:NOT DETERMIN
Upper Limits:NOT DETERMIN
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL, OR HALON.
Fire Fighting Procedures:
Unusual Fire/Explosion Hazard:.
* Accidental Release Measures *
Spill Release Procedures:CLEAN SPILL W/ABSORBENT MATERIAL. FLUSH
W/LARGE QUANTITIES OF WATER INTO INDUSTRIAL SEWER. CONSULT LOCAL,
TWA'S ARE EXCEEDED.
Neutralizing Agent:MFR GAVE NO INFORMATION OF MSDS.
*Handling and Storage *
Handling and Storage Precautions:PROTECT FROM PHYSICAL DAMAGE. STORE IN
A COOL, DRY, VENTILATED AREA AWAY FROM ACIDS, ALKALIS & OPEN
FLAMES.
Other Precautions:.
* Physical/Chemical Properties *
HCC:V6
NRC/State Lic Num:
Boiling Pt:B.P. Text:N/A.
Melt/Freeze Pt:M.P/F.P Text:N/A.
Vapor Pres:N/A.
Vapor Density:N/A.
Evaporation Rate & Reference:N/A.
Solubility in Water:COMPLETE
Percent Volatiles by Volume:0.0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:
Hazardous Decomposition Products:IRRITATING AND/OR TOXIC FUMES
INCLUDING CARBON, SULFUR AND SILICON OXIDES MAY BE RELEASED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN A CHEMICAL LANDFILL AS
APPROVED BY CURRENT LOCAL, STATE AND FEDERAL LAWS & REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHEN SPRAYING OR APPLYING IN CIRCUMSTANCES
LIKELY TO PRODUCE AIRBORNE LEVELS OF HAZARDOUS INGREDIENTS IN
EXCESS OF TLV, USE ORGANIC VAPOR CARTRIDGE OR AIR SUPPLIED
RESPIRATOR.
Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW PEL AND TLV.
Other Protective Equipment:AVOID SKIN CONTACT BY USE OF OTHER
PROTECTIVE EQUIPMENT. DURING SPRAY APPLICATION COMPLETE SKIN
PROTECTION REQUIRED.
Work Hygienic Practices:SAFETY SHOWER, EYE BATH AND WASHING FACILITIES.
Supplemental Safety and Health
NK
* Product Identification *
* Composition/Information on Ingredients *
LBS.
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Ingred Name:2,4-PENTANEDIONE (VP = 7.0 MM HG)
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ETHYL-3-ETHOXYPROPIONATE (VP = 1.1 MM HG)
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AROMATIC HYDROCARBON SOLVENT NAPHTHA (PETROLEUM), LIGHT
AROMATIC.
Fraction by Wt: 5.0%
Other REC Limits:NONE RECOMMENDED
Ingred Name:TRIMER HDI (VP = 0 MM HG)
Other REC Limits:NONE RECOMMENDED
Ingred Name:AROMATIC SOLVENT (VP = 0 MM HG)
Fraction by Wt: <5.0%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: IRRIT, BURNING, TEARING,
REDDENING, CORNEAL INJURY, CONJUNCTIVA SWELLING. SKIN: DRYING,
CRACKING, REDNESS, BURNING, DERMATITIS, DEFATTING. INHAL: DIZZY,
DROWSY, FATIGUE, COUGHING, CHEST PAINS, TH ROAT/RESP/MUCOUS
MEMBRANE IRRIT, HEADACHE, ANESTHETIC, CNS EFFECTS, NAUSEA,
UNCONSCIOUS, WEAKNESS, LIVER/KIDNEY DAMAGE.
Effects of Overexposure:INGEST: DROWSY, DIZZY, NAUSEA, DIARRHEA,
ABDOMENAL DISCOMFORT, DISTURBANCE IN MEMORY/THIING
ABILITY/EMOTIONS/COORDINATION, CNS DEPRESSION, UNCONSCIOUS.
* First Aid Measures *
DONT USE SOLVENTS. REMOVE CONTAM CLOTHES, WASH BEFORE REUSE. INHAL:
REMOVE TO FRESH AIR. ARTIF RESP/CPR IF NEEDED. INGEST: CALL DR. IN
ALL CASES, GET IMMED MED AID.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. COOL
CONTAINERS W/WATER. FOG NOZZLES PREFERRED. USE SCBA AND PROTECTIVE
CLOTHES. CLOSED CONTAINERS EXPLODE IN HIGH HEAT.
Unusual Fire/Explosion Hazard:VAPORS COLLECT IN POORLY VENTED OR
CONFINED AREAS. VAPORS FORM EXPLOSIVE MIXTURES W/AIR. VAPORS TRAVEL
TO IGNITS AND FLASH BACK.
* Accidental Release Measures *
Spill Release Procedures:PROTECT FROM IGNITS. USE AIR SUPPLIED
FOR UNVENTED SPILLS. COVER W/ABSORBENT. ADD DECOMP
Neutralizing Agent:*DECOMP SOLUTION: 5% CONCENTRATED AMMONIA, 2%
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE
Other Precautions:EMPTY DRUMS MAY CONTAIN EXPLOSIVE VAPORS. DONT CUT,
PUNCTUREOR WELD ON OR NEAR DRUM. DURING A FIRE, IRRITATING AND
TOXIC GASES AND AEROSOLS FROM DECOMPOSITION/COMBUSTION PRODUCTS MAY
BE PRESENT.
* Physical/Chemical Properties *
Vapor Density:>AIR
Evaporation Rate & Reference:NA
Appearance and Odor:CLEAR LIQUID, SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTACT W/WATER, ALCOHOLS AND AMINES.
Hazardous Decomposition Products:CARBON DIOXIDES AND CARBON MONOXIDE.
MAY ALSO INCLUDE OXIDES OF NITROGEN AND TRACES OF HCN AND
ISOCYANATE MONOMER.
* Disposal Considerations *
Waste Disposal Methods:WHEN DISPOSING OF THIS MATERIAL, INSURE THAT IT
IS PACKAGED, STORED, TRANSPORTED AND OTHERWISE PACKAGED IN
ACCORDANCE W/FEDERAL, STATE AND LOCAL REGULATIONS.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR A MSHA/NIOSH APPROVED RESPIRATOR/USE ANY
SCBA W/A FULL FACEPIECE OPERATED IN PRESSURE-DEMAND/OTHER POSITIVE
PRESSURE MODE. FOR EMERGENCY/NONROUTINE OPERATIONS, WEAR AN SCBA.
DON'T WEAR AIR-PURIFY ING RESPIRATORS.
Ventilation:GENERAL & LOCAL EXHAUST TO MAINTAIN AIRBORNE CONCENTRATIONS
BELOW PEL LIMITS. LOCAL EXHAUST IS PREFERRED.
Other Protective Equipment:CHEMICALLY PROTECTIVE BOOTS, APRONS,
EMERGENCY EYEWASH STATIONS, SAFETY QUICK DRENCH SHOWERS & WASHING
FACILITIES.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. NEVER EAT, DRINK/SMOKE IN AREAS. PRACTICE GOOD PERSONAL
HYGIENE AFTER
Supplemental Safety and Health
BEFORE EATING, DRINKING, SMOKING/USING THE TOILET/APPLYING COSMETICS.
AVOID MAT: POTASSIUM PERMANGANTE/PERFORMIC ACID/PERCHLORIC
ACID/ANILINE/NITROGEN DIOXIDE. HLTH HZRD: FORMALIN IS CORROSIVE TO
SKIN & MUCOUS MEMBRANES, SENSITIZATION & CAN CAUSE KIDNEY DAMAGE.
FIRST AID: OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Product Identification *
CAGE:0H0Z7
CAGE:0H0Z7
* Composition/Information on Ingredients *
Ingred Name:FORMALDEHYDE, FORMALIN (SUSPECTED HUMAN CARCINOGEN BY IARC;
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF EYES, NOSE,
UPPER RESPIRATORY TRACT. BURNING OF NOSE & THROAT, MUCOUS MEMBRANE
IRRITATION, SEVERE EDEMA INJURY, PNEUMONITIS & DEATH. SKIN:
IMMEDIATE & DELAYED EFFECTS. SYSTEM IC EFFECTS OCCUR AFTER HEAVY
EXPOSURES,CNS DEPRESSION & METABILIC ACIDOSIS. FORMALDEHYDE: VERY
TOXIC & IRRITATING.(SUPP
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, WATERING EYES, TEARING, BREATHING
DIFFICULTY, COUGH, BURNS, REDNESS, BLISTERING, VERTIGO,
CONVULSIONS, STUPOR, COMA, RESPIRATORY FAILURE.
Medical Cond Aggravated by Exposure:DERMATITIS, KIDNEY & RESPIRATORY
DISORDERS.
* First Aid Measures *
First Aid:EYES: DON'T RUB/KEEP TIGHTLY SHUT. FLUSH W/LARGE AMOUNTS OF
W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR & SUPPORT
BREATHING. INGESTION : NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS/CONVULSING PERSON. IF CONSCIOUS, GIVE 1-2 GLASSES OF
WATER/MILK W/AMMONIUM ACETATE, THEN INDUCE VOMITING. FOLLOW BY
* Fire Fighting Measures *
Lower Limits:7
Extinguishing Media:DRY CHEMICAL, CO2, WATER SPRAY/ALCOHOL RESISTANT
FOAM.
Fire Fighting Procedures:WEAR SCBA W/A FULL FACEPIECE OPERATED IN THE
PRESSURE DEMAND/POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:VAPORS MAY TRAVEL TO AN IGNITION SOURCE &
FLASH BACK. CONTAINER MAY EXPLODE IN HEAT OF FIRE. FORMALIN POSES A
VAPOR EXPLOSION HAZARD INDOORS, OUTDOORS & SEWERS.
* Accidental Release Measures *
Spill Release Procedures:NOTIFY SAFETY PERSONNEL, ISOLATE & VENTILATE
AREA, DENY ENTRY & SATY UPWIND. SHUT OFF IGNITION SOURCES & GAS
FLOW. INSTALL A PRESSURE CONTROL/RELEASE COVER OVER VALVE ASSEMBLY.
USE WATER SPRAY TO COOL VAPORS & DILUTE. TAKE UP W/ABSORBENT
MATERIAL.
Neutralizing Agent:SODIUM BISULFITE SOLUTION.
*Handling and Storage *
Handling and Storage Precautions:STORE LIQUID IN A DRY, WELL VENTILATED
FLOORS THAT SLANT TOWARDS A DRAIN/CURBED AREAS.
Other Precautions:STORE IN STAINLESS STEEL/LINED CARBON STEEL
CONTAINERS.
* Physical/Chemical Properties *
Spec Gravity:1.1
pH:2.8
Solubility in Water:MISCIBLE
Appearance and Odor:FLAMMABLE, COLORLESS GAS/LIQUID W/A PUNGENT
SUFFOCATING ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLES W/HYDROGEN PEROXIDE, MAGNESIUM CARBONATE HYDROXIDE,
NITROMETHANE, PEROXYFORMIC ACID, PHENOL. (SEE SUPP)
Stability Condition to Avoid:HEAT, IGNITION SOURCES.
Hazardous Decomposition Products:THERMAL: CO2, ACRID SMOKE & TOXIC
VAPORS.
Conditions to Avoid Polymerization:FORMALDEHYDE POLYMERIZES READILY IN
BOTH ITS GASEOUS & LIQUID STATE & SLOWLY OXIDIZES IN AIR TO FORMIC
ACID.
* Disposal Considerations *
Waste Disposal Methods:FORMALDEHYDE MAY BE REMOVED FROM WASTE WATER BY
AIR STRIPPING, IAW/FEDERAL, STATE & LOCAL REGULATIONS. CONTACT YOUR
SUPPLIER/A LICENSED CONTRACTOR FOR DETAILED RECOMMENDATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURE BELOW TLV(PEL) USE MSHA/NIOSH APPROVED UNITS. USE UNITS
AND WARNINGS. IF WITHIN O SHA PROTECTION FACTOR, AIR PURIFYING
OV/FILTER UNITS OK FOR USE.
Ventilation:LOCAL AND MECHANICAL EXHAUST.
Other Protective Equipment:EYE BATH AND SAFETY SHOWER.
Work Hygienic Practices:MAINTAIN GOOD PERSONAL HYGIENE. DO NOT USE IN
CONFINED AREA WITHOUT ADEQUATE VENTILATION.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:HENRY SIMMONS
* Composition/Information on Ingredients *
Ingred Name:LIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM)
Ingred Name:SOLVENT NAPHTHA, STODDARD
Ingred Name:XYLENE
= Wt:5.1
Ingred Name:MAGNESIUM SILICATE (MG2SI3O8)
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:DIRECT CONTACT TO EYES MAY CAUSE
IRRITATION, PROLONG AND/OR REPEATED MAY CAUSE SKIN IRRITATION.
INHALATION OF HIGH CONCENTRATIONS OF VAPORS MAY LEAD TO LUNG
CHANGES, NAUSEA, VOMITING, COUGH, PULMONARY IRRITATION, AND
CENTRAL NERVOUS SYSTEM DEPRESION. INGESTION MAY CAUSE
GASTRINTESTINAL DISTURBANCES. ASPIRATIONS OF THIS PRODUCT INTO THE
LUNGS MAY CAUSE PNEMONITIS, PULMONARY EDEMA AND HEMORRAGE.
Effects of Overexposure:INHALATION HEALTH RISK AND SYMPTONS OF EXPOSURE
BREATHING OF HIGH VAPOR CONCENTRATIONS MAY CAUSE DROWSINESS,
DIZZINESS, FATIGUE, FOLLOWED BY COMA.SKIN AND EYE CONTACT HEALTH
RISKS AND SYMPTONS OF EXP OSURE EYE: DIRECT CONTACT AND/OR CONTACT
WITH VAPORS MAY CAUSE IRRITATION SKIN: PROLONGED OR REPEATED
CONTACT MAY CAUSE IRRITATION AND/OR DERMITITIS THROUGH THE
SKIN.SKIN ABSORPTION HEALTH RISKS AND SYMPTONS OF EXPOSURE
PROLONGED OR REPEATED EXPOSURE CAN CAUSE MODERATE IRRITATION,
DEFATTING, AND HERMITITIS.INGESTION HEALTH RISKS AND SYMPTONS OF
EXPOSURE ASPIRATION OF THIS PRODUCT MAY CAUSE INT O THE LUNGS MAY
CAUSE PNEMONTITIS.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASES IN OR HISTORY OF AILMENTS INVOLVING SKINCENTRAL NERVOUS
SYSTEM, LIVER, AND KIDNEY.
* First Aid Measures *
First Aid:EYE CONTACT: IMMEDIATELY FLUSH WITH LARGE AMOUINTS OF WATER
AND WATER. SEEK MEDICAL AID IF IRRITAITON PERSISTS. INGESTIONS:
IMMEDIATELY SEEK MEDICAL AID. DO NOT INDUCE VOMITING. DO NOT
ATTEMPT TO GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:.9%
Fire Fighting Procedures:APPROVED GAS MASK REQUIRED FOR FIRE FIGHTING
PERSONEL, WATER MAY BE INEFFECTIVE, WATER MAY BE USED TO COOL
CONTAINERS. IF WATER IS USED, FOG MOZZLES ARE PREFERRED.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELETRICAL EQUIPMENT, SPARKS, AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO HEAT.
* Accidental Release Measures *
Spill Release Procedures:N/PSTOP LEAK IF NO RISK INVOLVED. REMOVE ALL
SOURCES OF IGNITION. STAY UPWIND. ABSORB WITH INERT MATERIAL. FLUSH
HAS BEEN DECLARED S AFE.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS CLOSED AND UPRIGHT TO
PREVENT LEAKAGE. AVOID FLAMES, WELDING, OPEN LIGHTS, ETC. AVOID
BREATHING OF VAPOR AND SPRAY MIST. AVOID SKIN AND EYE CONTACT.
Other Precautions:MAINTAIN GOOD PERSONAL HYGIENE. DO NOT USE INCONFINED
AREA, TANK OR PIT, WITHOUT ADEQUATE VENTILATION.
* Physical/Chemical Properties *
Vapor Density:>AIR
Spec Gravity:1.2
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:ESSENTIALLY NIL
Appearance and Odor:VISCOUS LIQUID WITH TYPICAL PAINT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDING AGENTS.
Stability Condition to Avoid:FLAMES. SPARKS, SMOKING AND HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR
* Disposal Considerations *
Waste Disposal Methods:USE INERT ABSORBENT MATERIALS ON SPILLS. DISPOSE
OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR IF AIRBORN
CONCENTRATIONS EXCEED EXPOSURE LIMITS.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION.
Other Protective Equipment:APRON OF RUBBER OR BUTYL.
Work Hygienic Practices:WASH HANDS AFTER EACH USE. LAUNDER CLOTHING
BEFORE REUSE.
Supplemental Safety and Health
EMPTY DRUMS SHOULD BE COMPLETELY DRAINED, PROPERLY BUMGED, AND PROMPTLY
SHIPPED TO SUPPLIER OR DRUM RECONDITIONER. IF DISPOSING OF THESE
CONTAINERS, DISPOSAL SHOULD BE IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
* Product Identification *
Product ID:PAINT,OIL,TINT BASE
Preparer's Name:CHARLES FRIEDMAN
* Composition/Information on Ingredients *
Ingred Name:TITANIUM DIOXIDE
Other REC Limits:NONE SPECIFIED
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
Ingred Name:LINSEED OIL
Other REC Limits:NONE SPECIFIED
Ingred Name:ALKYD RESIN
Other REC Limits:NONE SPECIFIED
Ingred Name:STODDARD SOLVENT
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION-IRRITATION OF MUCOUS
MEMBRANES. EYES-IRRITATION. SKIN-MINOR IRRITATION.
INGESTION-IRRITATION AND INFLAMMMATION OF GI TRACT. CHRONIC:
INHALATION-NERVOUS SYSTEM DEPRESSION. EYES-IRRITAT ION.
SKIN-REDNESS,BURNING AND DRYING AND CRACKING. INGESTION- NERVOUS
SYSTEM DERESSION.
Explanation of Carcinogenicity:IARC LISTS SILICA AS A SUSPECTED
CARCINOGEN WITH LIMITED EVIDENCE TO SUPPORT THIS DESIGNATION.
Effects of Overexposure:INHALATION: BURNING OF MOUTH AND THROAT.
DROWSINESS,DIZZINESS,LOSS OF COORDINATION AND FATIGUE. EYES:
STINGING,TEARING. SKIN: IRRITATION. DRYING, CRACKING OF SKIN.
INGESTION: BURNING OF MOUTH AND THRO AT. DIZZINESS, FATIGUE,
DROWSINESS.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY OVEREXPOSURE TO THIS MATERIAL.
* First Aid Measures *
First Aid:INHALATION: MOVE TO FRESH AIR. IF SYMPTOMS PERSIST, SEE
SKIN: REMOVE CLOTHING. WASH THOROUGHLY.IF RASH DEVELOPS, SEE
DOCTOR. INGESTIO N: DO NOT INDUCE VOMITING! OR GIVE ANYTHING BY
MOUTH. IF DROWSY DO NOT LEAVE UNATTENDED, SEE DOCTOR.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:0.8
Upper Limits:5.0
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, OR FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. WATER
MAY BE USED TO COOL CONTAINERS AND TO MINIMIZE VAPORS. AVOID
SPREADING BURNING LIQUID WITH COOLING WATER.
Unusual Fire/Explosion Hazard:MATERIAL IS COMBUSTIBLE AND MAY BE
IGNITED BY HEAT OR FLAME. THIS MATERIAL WILL BURN, BUT WILL NOT
IGNITE READILY.
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBANT PADS. DO NOT FLUSH DOWN DRAIN.
CONTACT LOCAL ENVIRONMENTAL MANAGER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS CLOSED. KEEP
CONTAINERS COOL, DRY, AWAY FROM SOURCES OF IGNITION. USE/STORE IN
WELL VENTILATED AREA.
Other Precautions:EMPTY CONTAINERS HAVE RESIDUE AND CAN BE DANGEROUS.
DO NOT PRESSURIZE,CUT,WELD,BRAZE,SOLDER,DRILL,GRIND, OR EXPOSE SUCH
CONTAINERS TO HEAT,FLAME, SPARKS OR OTHER SOURCES OF IGNITION.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:3
Vapor Density:4.8
Solubility in Water:INSOLUBLE
Appearance and Odor:TINTS, PAINT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
INCOMPATIBLE WITH STRONG ACIDS OR BASES, OXIDIZING AGENTS, AND SELECTED
AMINES.
Stability Condition to Avoid:HEAT, IGNITION SOURCES.
Hazardous Decomposition Products:OXIDES OF CARBON.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE IF EXPOSURE LEVELS EXCEED TLV/PEL
GUIDELINES.
Ventilation:LOCAL EXHAUST: MAY BE NEEDED. MECHANICAL (GENERAL):
RECOMMENDED. PROVIDE TO CONTROL W/IN LIMITS.
Work Hygienic Practices:REMOVE & LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. REMOVE CHEMICAL FROM SKIN BEFORE EATING/SMOKING.
Supplemental Safety and Health
PRECAUTIONS ARE FOR ROOM TEMPERATURE HANDLING. USE AT ELEVATED
TEMPS/AEROSOL/SPRAY APPLICATIONS MAY REQUIRE ADDED PRECAUTIONS.
* Product Identification *
Preparer's Name:JACK L. SHENEBERGER
* Composition/Information on Ingredients *
Ingred Name:METHYLTRIACETOXYSILANE, ALKYL TRIACETOXY SILANE
Fraction by Wt: 2%
Fraction by Wt: 2%
Fraction by Wt: 8%
OSHA PEL:6 MG/CUM
ACGIH TLV:0.2 MG/CUM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: SLIGHT TO MODERATE IRRITATION.
SKIN: IRRITATION. INHALATION: EYE, NOSE & THROAT IRRITATION.
INGESTION: DIGESTIVE DISCOMFORT. CHRONIC: REPEATED/PROLONGED
CONTACT MAY CAUSE MODERATE SKIN IRRITATIO N.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, REDNESS, SWELLING, DISCOMFORT
Medical Cond Aggravated by Exposure:ALLERGIC CONDITIONS
* First Aid Measures *
FLUSH W/WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:OC
Extinguishing Media:WATER FOG, CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:REMOVE & CONTAIN FOR SALVAGE/DISPOSAL.
*Handling and Storage *
CAUTION. KEEP CONTAINER CLOSED.
Other Precautions:USE ONLY W/ADEQUATE VENTILATION. DON'T TAKE
INTERNALLY. AVOID BREATHING VAPORS & SKIN & EYE CONTACT.
* Physical/Chemical Properties *
Vapor Pres:<6
Solubility in Water:NEGLIGIBLE
Appearance and Odor:ALUMINUM COLORED PASTE W/ACETIC ACID-LIKE ODOR
Percent Volatiles by Volume:<5/WT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS, WATER, HUMID AIR
Hazardous Decomposition Products:ACETIC ACID, SILICON DIOXIDE, CO2,
INCOMPLETELY BURNED CARBON PRODUCTS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO SPECIAL EQUIPMENT NEEDED IF VENTILATION IS
ADEQUATE. IF NOT, USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:DESIGN ADEQ VENT TO KEEP VAP CONC BELOW TLV, GEN MECH VENT
IS NORMALLY ADEQ FOR OCCASIONAL USE IN OPEN AREAS;(SUPP DATA)
Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO PREVENT
SKIN CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER USING THIS MATERIAL,
ESPECIALLY BEFORE EATING OR SMOKING.
Supplemental Safety and Health
KEY1: F5. THIS ENTRY DESCRIBES PART A OF A TWO PART KIT. SEE THIS SAME
NSN, P/N IND B, FOR PART B DATA. LOCAL EXHAUST IS RECOMMENDED FOR
REPEATED USE OR IN CONFINED AREAS.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:BENZENE, 2,4-DIISOCYANATO-1-METHYL-;(2,4-TOLUENE
DIISOCYANATE (TDI))
Fraction by Wt: 1-5%
Ingred Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE
ESTER;(4,4'-DIPHENYLMETHANE DIISOCYANATE (MDI))
Fraction by Wt: 1-5%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:POLYETHER PREPOLYMER;(POLYETHER PREPOLYMERS OF TID AND MDI)
Ingred Name:2-BUTANONE;(METHYL ETHYL KETONE (MEK))
Ingred Name:P-CRESOL, 2-6-DI-TERT-BUTYL-;(BUTYLATED HYDROXYTOLUENE
(BHT))
Fraction by Wt: 1-5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:MAY CAUSE MODERATE TO SEVERE
IRRITATION. SKIN:MAY CAUSE LOCALIZED IRRITATION, SWELLING AND
DRYNESS OF SKIN. INHAL:MAY CAUSE IRRITATION OF THE RESPIRATORY
TRACT, HEADACHE, DIZZINESS, NAUSEA. INGEST:NO DATA WERE FOUND ON
ACUTE EFFECTS.
Explanation of Carcinogenicity:TDI:GROUP 2B (IARC), GROUP 2 (NTP).
Effects of Overexposure:CHRONIC:MAY PRODUCE SKIN AND RESPIRATORY
SENSITIZATION. TDI WAS FOUND CARCINOGENIC IN ANIMAL TESTS BY
INGESTION AND MAY BE CARCINOGENIC BY INHALATION.
Medical Cond Aggravated by Exposure:PEOPLE WITH BRONCHIAL
HYPERREACTIVITY OR ISOCYANATE HYPERSENSITIVITY WILL BE AFFECTED BY
CONCENTRATIONS BELOW TLV.
* First Aid Measures *
GENTLY HOLDING EYELIDS OPEN. GET MD. SKIN:REMOVE CONTAMINATED
CLOTHING. WASH WITH GREEN/PLAIN SOAP & WATER. INHAL:MOVE TO FRESH
AIR; GIVE ARTIF ICIAL RESPIRATION/O2 AS NEEDED; GET MD.INGEST:IF
CONSCIOUS, INDUCE VOMITING WITH WARM SALT WATER (1 TBSP PER CUP).
FOLLOW WITH LOTS OF MILK; GET MD IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.4%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY PRODUCE IRRITATING GASES OR MISTS
FROM DECOMPOSITION OR COMBUSTION.
* Accidental Release Measures *
Spill Release Procedures:PREVENT SKIN & EYE CONTACT. ABSORB SPILLAGE ON
INERT MATERIAL; TRANSFER TO AN OPEN CONTAINER IN A WELL VENTILATED
WASH SPILL AREA WITH S TRONG DETERGENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. STORE
CONTAINERS CLOSED. KEEP AWAY FROM INTENSE HEAT, SPARKS AND OPEN
FLAME.
Other Precautions:KEEP MOISTURE OUT OF CONTAINERS-IT WILL CAUSE RELEASE
OF CARBON DIOXIDE WHICH COULD BURST A CLOSED CONTAINER. KEEP HANDS
AWAY FROM EYES WHEN HANDLING THIS MATERIAL.
* Physical/Chemical Properties *
HCC:F5
pH:5
Evaporation Rate & Reference:>1 (BUTYL ACETATE=1)
Solubility in Water:SLIGHT;REACTS
Appearance and Odor:CLEAR, VISCOUS LIQUID WITH SWEET ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MOISTURE (REACTS SLOWLY, RELEASING CO2); ALCOHOLS, AMINES, BASES,
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH HEAT AND FLAME.
Hazardous Decomposition Products:ISOCYANATES AND AMINES; MORE COMPLETE
COMBUSTION WILL PRODUCE COX, NOX AND TRACES OF HCN.
* Disposal Considerations *
Waste Disposal Methods:DISCARD TREATED WASTE IN A FACILITY COMPLYING
WITH STATE AND LOCAL REGULATIONS FOR ORGANIC AMINES AND AMINE
ADDUCTS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYE WASH, DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PH: 2 (FULL STRENGTH).
* Product Identification *
Preparer's Name:JEFF TIEGER
* Composition/Information on Ingredients *
Ingred Name:OXALIC ACID
OSHA PEL:1 MG/M3/2 STEL
ACGIH TLV:1 MG/M3/2 STEL
Ingred Name:2-BUTOXYETHANOL; (ETHYLENE GLYCOL MONOBUTYL ETHER)(EGBE)
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:TRANSIENT IRRIT. SKIN:DEFATTING.
NON-SENSIT. ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED
ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUES, BLOOD, KIDNEYS & LIVER,
ASSOC W/ADMIN OF ETHYLENE GLYCOL M ONOBUTYL ETHER (EGBE) & ETHYLENE
GLYCOLMONOBUTYL ETHER ACETATE (EGBEA)(EXTRACTED FROM DHHS(NIOSH)PUB
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST: DRINK WATER. DO NOT INDUCE VOMITING. INHAL: REMOVE TO
FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN: WASH WITH
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
TO ABSORB SPILL. USE A SHOVEL TO SCOOP UP ABSORBED SOLUTION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NONE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
pH:SUPDAT
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID W/ACIDIC ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE ACCORDING TO LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED UNDER NORMAL OPERATING CONDITIONS.
WEAR A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IN AREAS WHERE
TLVS MAY BE EXCEEDED/IF SPRAY MIST IS PRESENT.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST TO MINIMIZE EMPLOYEE
Other Protective Equipment:OTHER PROTECTIVE CLOTHING, SAFETY SHOWER,
EYE BATH & WASHING FACILITIES.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:MODIFIED ALIPHATIC AMINE
Ingred Name:ETHYLENE GLYCOL PROPYL ETHER, EKTASOLVE EP,
2-PROPOXYETHANOL
Ingred Name:NON-HAZARDOUS ADDITIVES, RESINS & PIGMENTS
Fraction by Wt: <5%
Ingred Name:2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER), BUTYL
CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE RESPIRATORY
IRRITATION. SKIN/EYES: MAY CAUSE MILD IRRITATION. INGESTION: MAY
CAUSE GI IRRITATION. OVEREXPOSURE TO A COMPONENT OF THIS PRODUCT
MAY CAUSE LIVER & KIDNEY DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION.
Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY & SKIN
CONDITIONS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
KEEP WARM & QUIET. SKIN: WASH AFFECTED AREAS W/SOAP & WATER. DON'T
ATTENTION I N ALL CASES.
* Fire Fighting Measures *
Lower Limits:1.1
Extinguishing Media:CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:COOL FIRE EXPOSED CONTAINERS W/WATER. WEAR A
NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE
CLOTHING.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY RUPTURE/EXPLODE
WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT TO AVOID
BREATHING VAPORS & SKIN & EYE CONTACT. SMALL: DIKE & ABSORB W/INERT
MATERIAL.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. DON'T
TAKE INTERNALLY. PREVENT CONTACT W/CONTAMINATED CLOTHING. FOLLOW
LABEL WARNINGS.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN N-BU AC
Appearance and Odor:LIQUID W/SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:EXTREME HEAT, FIRE.
Hazardous Decomposition Products:CO, CO2, CARBON.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T USE ANY METHOD WHICH WOULD POSE AN
ENVIRONMENTAL/HUMAN HEALTH THREAT INCLUDING ANY WHICH WOULD
| 1 | eyes_protection_mandatory |
Control Measures
*
Product ID: SILVER-COPPER-PHOSPHORUS BRAZING ALLOYS
*
Contractor Summary
*
*
Item Description Information
*
Item Manager: S9G
Item Name: BRAZING ALLOY,SILVER
Unit of Issue: LB
UI Container Qty: Z
Type of Container: UNKNOWN
*
Ingredients
*
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 0.1MG/M3 FUME/1 DUST
------------------------------
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
% low Wt: .9
Other REC Limits: NONE RECOMMENDED
ACGIH TLV: 0.1 MG/M3 (METAL)
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TARGET ORGANS: LIVER, KIDNEY, SPLEEN, PANCREAS, BRAIN, ().
ACUTE - INHALATION: IT IS NOT KNOWN TO CAUSE SIGNIFICANT RISK TO HEALTH.
EXCESSIVELY HIGH OR PROLONGED EXPOSURE MAY CAUSE IRRITATION, FEV ER,
WEAKNESS, METALLIC TASTE. SKIN: MAY CAUSE ARGYRIA, IRRITATION, DISCOLORATION,
CONTACT DERMATITIS. EYES: THESE PRODUCTS IN FINELY DIVIDED FORMS MAY CAUSE
IRRITATION, ARGYRIA, CONJUNCTIVITS, AND/OR ULCERATION OF THE CORNEA.
INGESTION: MAY CAUSE NAUSEA, VOMITING, AND GASTROINTESTINAL IRRITATION.
CHRONIC - MAY DAMAGE LIVER, KIDNEY, SPLEEN, PANCREAS, BRAIN, AND
GASTROINTESTINAL SYSTEM. MAY PRODUCEARGYRIA, DISCOLORATION, DERMATITIS.
Explanation Of Carcinogenicity: NONE OF THE COMPONENTS OF THIS SUBSTANCE IS
LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Signs And Symptions Of Overexposure: IRRITATION, FEVER, WEAKNESS, METALLIC
TASTE, ARGYRIA (A PERMANENT BLUE-GRAY DISCOLORATION OF THE SKIN, EYES, MUCOUS
MEMBRANES, AND RESPIRATORY TRACT), CONTACT DERMATITIS, CONJUNCTIVITS,
ULCERATION OF THE CORNEA, NAUSEA, VOMITING
Medical Cond Aggravated By Exposure: PRE-EXISTING PULMONARY DISEASES MAY BE
AGGRAVATED BY INHALATION EXPOSURE TO THIS MATERIAL, PARTICULARLY AS FUMES.
CHRONIC EXPOSURE MAY AGGRAVATE PRE-EXISTING DISEASES OF LIVER, KIDNEYS AND GI
TRACT.
First Aid: INHALATION: REMOVE SUBJECT FROM CONTAMINATED AREA, ADMINISTER
OXYGEN, AND SEEK MEDICAL ATTENTION. KEEP SUBJECT WARM AND AT REST. PERFORM
ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. SKIN: REMOVE C ONTAMINATED
CLOTHING. WASH AFFECTED AREA WITH PLENTY OF WATER FOR AT LEAST FIVE MINUTES.
SEEK MEDICAL ASSISTANCE IF NECESSARY. EYES: FLUSH AFFECTED AREAS WITH WATER
FOR AT LEAST FIFTEEN MINUTES. SEEK MEDICAL ASSISTANCE IF NECESSARY.
INGESTION: IF SUBJECT IS CONSCIOUS, INDUCE VOMITING. IF UNCONSCIOUS OR
CONVULSIVE, SEEK IMMEDIATE MEDICAL ASISTANCE.
*
Handling and Disposal
*
Spill Release Procedures: IF A FINELY-DIVIDED FORM OF PRODUCT IS SPILLED, CLEAN
UP SPILLAGE SO AS TO MINIMIZE DISPERSION OF DUST. WET SWEEPING OR VACUUMING
USING HEPA FILTRATION ARE RECOMMENDED.
Waste Disposal Methods: CONSULT THE MANUFACTURER FOR DIPOSITION OF UNUSED OR
UNUSABLE PRODUCT.
Handling And Storage Precautions: DO NOT STORE IN PROXIMITY TO INCOMPATIBLE
MATERIALS.
Other Precautions: KEEP OUT OF REACH OF CHILDREN.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: USE DRY POWDER. DO NOT USE WATER.
Fire Fighting Procedures: IF FIGHTING A FIRE IN WHICH THESE PRODUCTS ARE
PRESENT, WEAR A SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE
OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard: IN FINELY-DIVIDED FORM, THESE PRODUCTS MAY
IGNITE WHEN EXPOSED TO FLAME OR BY REACTION WITH INCOMPATIBLE MATERIALS. IF
PRESENT IN A FIRE OR EXPLOSION, THEY MAY EMIT FUMES OF THE CONSTITUENT METAL
OXID ES AND PHOSPHORUS PENTOXIDE.
*
*
Respiratory Protection: IF EXPOSURE LEVELS EXCEED THE OSHA PEL OR OTHER
APPLICABLE STANDARD, USE A NIOSH-APPROVED RESPIRATOR HAVING A CONFIGURATION
APPROPRIATE TO THE CONCENTRATION OF THE CONTAMINANTS GENERATED. FOR GUIDANCE
ON SELECTION AND USE OF RESPITATORY PROTECTION, CONSULT AMERICAN NATIONAL
Ventilation: USE APPROPRIATE VENTILATION ADEQUATE TO MAINTAIN CONCENTRATIONS OF
ALL COMPONENTS AND THEIR DECOMPOSITION BYPRODUCTS TO WITHIN THEIR RESPECTIVE
PELS.
Other Protective Equipment: WEAR PROTECTIVE CLOTHING. EYE BATH, WASHING
FACILITY, EMERGENCY SHOWER SHOULD BE NEARBY.
Work Hygienic Practices: TO AVOID INGESTION OF MATERIAL, WASH HANDS AND FACE
BEFORE EATING, DRINKING OR CONSUMPTION OF TOBACCO.
Supplemental Safety and Health: NONE
*
Physical/Chemical Properties
*
HCC: N1
Solubility in Water: INSOLUBLE.
Appearance and Odor: ODORLESS LIGHT-COPPER (WIRE, ROD, STRIP, POWDER, TAPE,
GRAIN, OR PREFORM SHAPE)
*
Reactivity Data
*
Stability Indicator: YES N DISULFIDE; FERRIC CARBONYL
Stability Condition To Avoid: STABLE AT ROOM TEMPERATURE. SILVER AND COPPER CAN
FORM UNSTABLE ACETYLIDES UPON CONTACT WITH ACETYLENE GAS.
BROMATES, IODATES; INORGANIC AND ORGANIC PEROXIDES; PEROXYFORMIC ACID;
NITROBENZENE; HALOGENS; PERMONOSULFURIC ACID; SEOCL; SEOF; SEF4; HYDRAZINE
MONONITRATE; CARB
Hazardous Decomposition Products: HEATING TO ELEVATED TEMPERATURES MAY LIBERATE
METAL/METAL OXIDE FUME AND PHOSPHORUS PENTOXIDE.
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Product ID: SILVER-COPPER-PHOSPHORUS BRAZING ALLOYS
Net Unit Weight: 1 LB
Multiple KIT Number: 0
Unit Of Issue: LB
Container QTY: Z
Type Of Container: UNKNOWN
Additional Data: NOT REGULATED, PER MSDS.
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Product ID: SILVER-COPPER-PHOSPHORUS BRAZING ALLOYS
Company Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Label Required IND: Y
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: NO
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: LIVER, KIDNEY, SPLEEN, PANCREAS, BRAIN,
(). ACUTE - INHALATION: IT IS NOT KNOWN TO CAUSE SIGNIFICANT RISK TO HEALTH.
EXCESSIVELY HIGH OR PROLONGED EXPOSURE MAY CAUSE IRRITATION, FEV ER,
WEAKNESS, METALLIC TASTE. SKIN: MAYCAUSE ARGYRIA, IRRITATION, DISCOLORATION,
CONTACT DERMATITIS. EYES: THESE PRODUCTS IN FINELY DIVIDED FORMS MAY CAUSE
IRRITATION, ARGYRIA, CONJUNCTIVITS, AND/OR U LCERATION OF THE CORNEA.
INGESTION: MAY CAUSE NAUSEA, VOMITING, AND GASTROINTESTINAL IRRITATION.
CHRONIC - MAY DAMAGE LIVER, KIDNEY, SPLEEN, PANCREAS, BRAIN, AND
GASTROINTESTINAL SYSTEM. MAY PRODUCE A RGYRIA, DISCOLORATION, DERMATITIS.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY REQUIRED IF VENTILATION ADEQUATE.
Ventilation:YES
Other Protective Equipment:PROTECTIVE COVERALLS-DO TAKE CONTAMINATED
CLOTHING HOME.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:BERYLLIUM OXIDE (AS BERYLLIUM)
* Hazards Identification *
Effects of Overexposure:ACUTE: PNEUMONITIS. ACUTE LOCAL: IRRITATION
INHALATION: BERYLLIOLSIS. POSSIBLE CARCINOGEN.
* First Aid Measures *
First Aid:IMMEDIATELY CLEAN ALL MATERIAL IMPLANTED IN SKIN WITH
MUCH WATER. CUTS OR PUNCTURE WOUNDS REQUIRE IMMEDIATE
ATTENTION.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN. HIGHLY TOXIC BY INHALATION. DO NOT
DRY SWEEP OR CAUSE MATERIAL TO BECOME AIRBORNE.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:THIS MATERIAL IS A HAZARD ONLY IF THE TUBE IS
BROKEN AND B O IS CAUSED TO BECOME AIRBORNE OR CONTAMINATE THE
WORKPLACE OR CLOTHING, SKIN OF INDIVIDUALS.
* Physical/Chemical Properties *
HCC:M1
Appearance and Odor:WHITE POWDER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:SKIN CONTACT OR INHALATION OF POWDER.
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH ALL LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE EXPOSURE TO DECOMPOSITION PRODUCTS EXIST
DUE TO HEATING/ELEVATED TEMPERATURES, WEAR NIOSH/MSHA APPROVED
RESPIRATORY PROTECTION AS APPROPRIATE.
Ventilation:REQUIRED
PANTS & JACKET
Supplemental Safety and Health
* Product Identification *
CAGE:0UFA8
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE, TETRAFLUORO- POLYMER (POLYTETRAFLUOROETHYLENE),
PTFE, TEFLON
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: IRRITANT, PROLONGED CONTACT
CAUSES INFLAMMATION OF THE HAIR FOLLICLES W/O SENSITIZATION. EYES:
CAUSE LUNG IRRITATION & PULMONA RY EDEMA. FUMES/SMOKE FROM
OVERHEATING/BURNING MAY CAUSE POLYMER FUME FEVER, REPEATED EPISODES
MAY CAUSE LUNG DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DISCOMFORT, RASH, REDNESS,
INFLAMMATION, TEARING, BLURRING OF VISION, FEVER, CHILLS, COUGH
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
INGESTION: DON'T INDUCE VOMITING. GIVE 2 GLASSES OF WATER. NEVER
GIVE ANYTH ING BY MOUTH IF UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN
ALL CASES. NOTES TO PHYSICIANS: GIVE ACITIVATED CHARCOAL MIXTURE:
FOR ADULT
* Fire Fighting Measures *
Flash Point Method:PMCC
Flash Point:DOESN'T IGNITE
Extinguishing Media:AS APPROPRIATE FOR COMBUSTIBLES IN AREA
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. WEAR
FULL PROTECTIVE EQUIPMENT. AVOID BREATHING DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:DECOMPOSITION AT FLAME TEMPERATURES MAY
FORM TOXIC FLUORINE COMPOUNDS.
* Accidental Release Measures *
Spill Release Procedures:REVIEW FIRE FIGHTING MEASURES & HANDLING
BEFORE PROCEEDING W/CLEAN-UP. USE APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT DURING CLEAN-UP. PLACE IN CONTAINER F0R DISPOSAL. REMOVE
SOURCE OF HEAT & FLAME.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM HEAT & FLAMES TO AVOID DECOMPOSITION PRODUCTS.
Other Precautions:DON'T STORE/CONSUME FOOD, DRINK/TOBACCO IN AREAS
WHERE THEY MAY BECOME CONTAMINATED W/THIS MATERIAL. AVOID CONTACT
W/EYES & SKIN. AVOID BREATHING DECOMPOSITION PRODUCTS.
* Physical/Chemical Properties *
pH:7
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SOLID, WHITE WAXY GREASE W/NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
METAL OXIDES AT TEMPS
Hazardous Decomposition Products:TOXIC FLUORINE COMPOUNDS
Conditions to Avoid Polymerization:PRESENCE OF METAL OXIDES AT TEMPS
* Disposal Considerations *
Waste Disposal Methods:TREATMENT, STORAGE, TRANSPORTATION & DISPOSAL
MUST BE IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS. DON'T
FLUSH TO SURFACE WATER/SANITARY SEWER SYSTEM.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE LIKELY TO BE NEEDED
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYEWASH AND SHOWER
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
* Product Identification *
CAGE:0BTT2
CAGE:0BTT2
* Composition/Information on Ingredients *
Ingred Name:PERMETHRIN
Other REC Limits:NONE RECOMMENDED
Ingred Name:RELATED COMPOUNDS
Other REC Limits:NONE RECOMMENDED
Ingred Name:A PROPRIETARY MIXTURE OF SOLVENT, ANIONIC, AND NONIONIC
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NON-IRRITATING TO EYES, MODERATELY
IRRITATING TO SKIN
Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS
CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:SKIN IRRITATION
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGESTION: CONTACT PHYSICIAN IMMEDIATELY. DO NOT INDUCE
VOMITING UNLESS DIRECTED BY PHYSICIAN. INHALATION: REMOVE AFFECTED
PERSON TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF INDICATED.
EYES: FLUSH W ITH PLENTY OF WATER. CONTACT A PHYSICIAN IF
IRRITATION PERSISTS. SKIN: REMOVE CONTAMINATED CLOTHING. WASH
AFFECTED AREAS WITH SOAP AND WATER. CONTACT PHYSICIAN IF IRRITATION
PERSISTS.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL & WATER FOG
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. COOL
FIRE EXPOSED AREAS & EQUIPMENT
Unusual Fire/Explosion Hazard:DO NOT USE DIRECT TREAM OF WATER;
MATERIAL MAY FLOAT AND REIGNITE.
* Accidental Release Measures *
Spill Release Procedures:SOAK UP WITH AN ABSORBENT MATERIAL SUCH AS
SAND, SAWDUST, EARTH, FULLER'S EARTH, ETC.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT CONTAMINATE WATER, FOOD OR FEED
BY STORAGE OR DISPOSAL.
Other Precautions:THIS PRODUCT IS TOXIC TO FISH. DO NOT APPLY DIRECTLY
TO LAKES, STREAMS, PONDS, TIDAL MARSHES OR ESTUARIES. DO NOT APPLY
WHERE RUNOFF IS LIKELY TO OCCUR. DO NOT APPLY WHEN WEATHER
CONDITIONS FAVOR DRIF T.
* Physical/Chemical Properties *
HCC:T5
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:EMULSIFIABLE
Appearance and Odor:AROMATIC ODOR, APPEARENCE NOT GIVEN
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:DUST MASK/DUST RESPIR.SEE SUPP DATA
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:AS REQUIRED BY OPERATION BEING PERFORMED
Supplemental Safety and Health
PRODUCING OPERATION(SAWING,GRINDING)IS PERFORMED. RESPIRATORY
PROTECION IS NECESSARY FOR DUST PRODUCING OPERATIONS ONLY
* Product Identification *
Product ID:HEXCEL WR-II HONEYCOMB
* Composition/Information on Ingredients *
Ingred Name:GLASS, FIBROUS
* Hazards Identification *
Effects of Overexposure:IRRITATION OF EYE,SKIN,RESPIRATORY TRACT.
* First Aid Measures *
First Aid:WASH SKIN WITH SOAP & WATER, FLUSH EYES WITH WATER, CONSULT A
PHYSICIAN IF IRRITATION PERSISTS
* Fire Fighting Measures *
Extinguishing Media:CO*2, FOAM, DRY CHEM & H*2O FOG.
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP
Unusual Fire/Explosion Hazard:AVOID DUST BUILD-UP
* Accidental Release Measures *
Spill Release Procedures:NONE
*Handling and Storage *
Handling and Storage Precautions:NONE
* Physical/Chemical Properties *
HCC:N1
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:SEE SUP. DATA
Hazardous Decomposition Products:CO*2, CO
* Disposal Considerations *
Waste Disposal Methods:LANDFILL OBEYING FEDERAL,STATE AND LOCAL
REGULATIONS
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VAPOR CONCENTRATION EXCEEDS THE TLV, USE
NIOSH/MSHA APPROVED RESPIRATOR WITH ORGANIC CHEMICAL CARTRIDGE.
CONTACT A REPUTABLE SAFETY SUPPLY COMPANY FOR THE APPROPRIATE
RESPIRATOR.
Ventilation:AS REQUIRED TO KEEP VAPOR CONCENTRATION BELOW TLV.
Other Protective Equipment:SOLVENT RESISTANT APRONS AND EYE WASH.
Work Hygienic Practices:SMOKE IN DESIGNATED AREAS ONLY. WASH W/SOAP &
WATER BEFORE EATING, SMOKING OR USING TOILET FACILITIES. REMOVE
(SUPDAT)
Supplemental Safety and Health
HYGIENE PRACT:CONTAMINATED CLOTHING TO PREVENT PROLONGED SKIN CONTACT.
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: 0-5%
Fraction by Wt: <5%
Ingred Name:METAL ALKANOATE
Fraction by Wt: <5%
Fraction by Wt: <5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:LIQUID, VAPOR OR MIST MAY CAUSE EYE
IRRITATION. SKIN CONTACT MAY CAUSE IRRITATION INCLUDING DRYNESS,
CHAPPING & REDNESS. INHALATION MAY CAUSE RESPIRATORY TRACT
IRRITATION OR NERVOUS SYSTEM DISORDERS S UCH AS HEADACHES,
DIZZINESS AND FATIGUE. INGESTION MAY CAUSE GASTROINTESTINAL TRACT
IRRITATION AND (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:SIGNS OF NERVOUS SYSTEM DEPRESSION.
REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM
DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALINGTHE CONTENTS MAY BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN OR
LUNG DISORDERS MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS
MATERIAL.
* First Aid Measures *
First Aid:SKIN:WASH WITH SOAP & WATER, CALL MD IF IRRITATION PERSISTS.
MD IF IRRITATION PERSISTS. INHAL:REMOVE TO FRESH AIR, RESTORE
BREATHING , CALL MD. INGEST:CONTACT MD OR POISON CONTROL CENTER
IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1%
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . WATER MAY BE INEFFECTIVE BUT MAY BE USED TO
COOL CONTAINERS.
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT,
SPARKS, AND OPEN FLAME. CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED
TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE
AREA. AVOID BREATHING VAPORS. CONTAIN RELEASE AND REMOVE WITH INERT
ABSORBENT. AVOID CONTACT. USE NON-SPARKING TOOLS TO PLACE MATERIAL
IN APPROPRIATE CONTAINE R FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS IN COOL,
DRY, WELL VENTILATED AREA AWAY FROM SOURCES OF IGNITION. KEEP
CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:AVOID PROLONGED OR REPEATED OVEREXPOSURE TO THIS
PRODUCT. EMPTY CONTAINERS SHOULD BE DISPOSED OF IN AN
ENVIRONMENTALLY SAFE MANNER IN ACCORDANCE WITH APPLICABLE
REGULATIONS.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:SEE ING
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAMES.
Hazardous Decomposition Products:CO, CO*2 AND OTHER NOXIOUS GASES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LOCAL,
COUNTY, STATE, AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR
AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE
LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV.
Ventilation:USE ENOUGH VENT, LOCAL EXHAUST AT ARC OR BOTH, TO KEEP
FUMES & GASES BELOW TLVS IN WORKER'S BRTHG ZONE & GEN AREA. TRAIN
WELDER TO KEEP HIS HEAD OUT OF FUMES.
(TOXICOLOGICAL INFO)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
HEAD, HAND & BODY PROT WHICH HELP TO PVNT INJURY FROM RADIA, SPKS &
(TOXICOLOGICAL INFO)
Work Hygienic Practices:TRAIN THE WELDER NOT TO TOUCH LIVE ELECTRICAL
PARTS AND TO INSULATE HIMSELF FROM WORK AND GROUND.
Supplemental Safety and Health
EFTS OF OVEREXP: IN MSDS ARE FOLLOWED, OVEREXP TO HAZ SUBSTANCES WILL
NOT OCCUR. ELEC ARC WORKING MAY CREATE ONE/MORE OF FOLLOWING HLTH
OR PHYSICAL HAZS. FUMES & GASES CAN BE DANGEROUS TO HLTH. ELEC S
HOCK CAN KILL. ARC RAYS CAN INJURE EYES & BURN SKIN. NOISE (OTHER
INFO)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MANGANESE
= Wt:2.
OSHA PEL:1 MG/M3 (FUME)
OSHA STEL:3 MG/M3
ACGIH TLV:0.2 MG/M3 (FUME)
ACGIH STEL:C 5 MG/M3
Ingred Name:MANGANESE COMPOUNDS. (AS MANGANESE)
< Wt:1.
OSHA PEL:1 MG/M3 (FUME)
OSHA STEL:3 MG/M3
ACGIH TLV:0.2 MG/M3 (FUME)
ACGIH STEL:C 5 MG/M3
Ingred Name:CHROMIUM
Minumum % Wt:2.
Maxumum % Wt:3.
OSHA PEL:1 MG/M3/C 0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SODIUM TITANATE. (MANUFACTURER'S INVALID CAS NUMBER
OSHA PEL:5 MG/M3 (RESP FRAC)
Ingred Name:POTASSIUM TITANATE
OSHA PEL:5 MG/M3 (RESP FRAC)
Ingred Name:SILICON
OSHA PEL:5 MG/M3 (RESPIRABLE)
Ingred Name:SILICA, USE QUARTZ FORMULA. (SIO2)
ACGIH TLV:0.1 MG/M3
Ingred Name:TITANIUM DIOXIDE
OSHA PEL:5 MG/M3 (RESPIRABLE)
Ingred Name:MOLYBDENUM
OSHA PEL:5 MG/M3 (SOLUABLE)
ACGIH TLV:5 MG/M3 (SOLUABLE)
Ingred Name:ZIRCONIUM
OSHA PEL:5 MG/M3 (AS ZR)
ACGIH TLV:5 MG/M3 (AS ZR)
Ingred Name:IRON
ACGIH TLV:5 MG/M3 (OX FUME)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE OVEREXP TO GASES, FUMES & DUSTS
MAY INCL IRRIT OF EYES, LUNGS, NOSE & THROAT. SOME TOX GASES ASSOC
W/WELDING MAY CAUSE PULM EDEMA, ASPHY & DEATH. ACUTE OVEREXP MAY
INCL SIGNS & SYMPS SUCH AS WAT ERY EYES, NOSE & THROAT IRRIT, HDCH,
DIZZ, DFCLTY BRTHG, FREQUENT COUGH OR CHEST PAIN. PRESENCE OF
NICKEL CMPDS IN FUME CAN CAUSE METALLIC TASTE, NAUS, TIGHTNESS OF
CHEST, FEVER & ALLERGIC RXN. CHRONI C OVEREXP TO AIR CONTAMINANTS
MAY LEAD TO THEIR ACCUM IN LUNGS, CNDTN WHICH MAY BE SEEN AS DENSE
AREAS ON CHEST X-RAYS. SEVERITY OF CHG IS PROPORTIONAL TO LENGTH OF
EXPOS. CHGS SEEN ARE NOT NECESSARIL Y (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CRYSTALLINE SILICA-QUARTZ: GROUP 1, IARC
Effects of Overexposure:HLTH HAZS: ASSOC W/SYMPS OR SIGNS OF REDUCED
LUNG FUNC/DISEASE. IN ADDN, CHGS ON X-RAYS MAY BE CAUSED BY
NON-WORK FACTORS SUCH AS SMKNG, ETC. NICKEL IS CONSIDERED CARCIN.
LONG TERM OVEREXP TO NICKEL F UMES MAY ALSO CAUSE PULM FIBROSIS &
EDEMA. OVEREXP TO MANGANESE CMPDS MAY AFFECT CNS, W/SYMPS OF
LANGUOR, SLEEPINESS, MUSC WEAK, EMOTIONAL DISTURBS & SPASTIC GAIT.
WELDING FUME IS 5 MG/M3. TLV-TWAS SHOULD BE USED AS GUIDE IN CTL OF
HLTH HAZS & NOT AS FINE LINES BETWEEN SAFE & EXCESSIVE CONCS. WHEN
PRODS USED AS RECOM BY ESAB GROUP,& PREVENTIVE MEASURES TAUGHT
(SUPDAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/ALLERGIES OR IMPAIRED
RESP FUNC MAY HAVE SYMPS WORSENED BY EXPOS TO WELDING FUMES;
HOWEVER, SUCH REACTION CANNOT BE PREDICTED DUE TO VARIATION IN
COMPOSITION & QTY OF DECOMP PRODS.
* First Aid Measures *
First Aid:INGESTION: CALL MD IMMEDIATELY . EYES: IMMEDIATELY FLUSH EYES
. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER. CALL MD (FP N ). IN
CASE OF EMERGENCY, CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUE
RECOMMENDED BY RED CROSS. INHALATION: IF BREATHING IS DIFFICULT,
GIVE OXYGEN AND CALL FOR MD. FOR ELECTRIC SHOCK, DISCONNECT A ND
TURN OFF THE POWER. IF NOT BREATHING, BEGIN ARTIFICIAL RESPIRATION,
PREFERABLY MOUTH-TO-MOUTH. IF NO DETECTABLE PULSE, BEGIN CPR.
IMMEDIATELY CALL MD. FOR ARC BURN, APPLY COLD, CLEAN COMPRESSES & C
ALL MD.
* Fire Fighting Measures *
Extinguishing Media:THIS PROD WILL NOT BURN; HOWEVER, WELDING ARCS &
SPKS CAN IGNITE COMBUST & FLAM MATLS. USE EXTING MEDIA RECOM FOR
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:FLAMMABLE/EXPLOSIVE: NO. ONLY THE
PACKAGING FOR THIS PRODUCT WILL BURN.
* Accidental Release Measures *
Spill Release Procedures:NOT APPLICABLE.
*Handling and Storage *
Handling and Storage Precautions:READ & UNDERSTAND MFR'S INSTRUCTION &
Other Precautions:ESAB GROUP REQUESTS USERS OF PRODS STUDY MSDS &
BECOME AWARE OF HAZS & SFTY INFO. TO PROMOTE SAFE USE OF PRODS,
USER SHOULD 1)NOTIFY EMPLOYEES, AGENTS & CONTRACTORS OF INFO ON
MSDS & ANY PROD HAZS & SFTY INFO, 2)FURNISH SAME INFO TO CUSTOMERS
FOR THESE PRODS & 3)REQUEST SUCH CUSTOMERS NOTIFY THEIR (STAB COND
TO AVOID)
* Physical/Chemical Properties *
Appearance and Odor:TUBULAR STEEL WIRE CONTAINING MINERALS AND ALLOYS;
ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE CURRENTLY KNOWN.
Stability Condition to Avoid:N/P. OTHER PREC:EMPLOYEES AND
CUSTOMERS, FOR THESE PRODUCTS, OF THE SAME PRODUCT HAZARDS AND
SAFETY INFORMATION.
Hazardous Decomposition Products:WELDING FUMES & GASES CANNOT BE
CLASSIFIED SIMPLY. COMPOSITION & QTY OF BOTH DEPEND ON MATL BEING
WORKED, PROCESS, PROCS & CONSUMABLES USED. OTHER CNDTNS INFLUENCING
COMPOSITION & QTY OF (ECOL INFO)
* Toxicological Information*
Toxicological Information:N/P. EXTING MEDIA:"SFTY IN WELDING & CUTTING"
FOR ADDNL FIRE PREVENTION & PROT INFO. EYE PROT: USE FILTER LENS.
AS RULE OF THUMB, START W/SHADE WHICH IS TOO DARK TO SEE WELD ZONE.
THEN GO TO NEXT LIGHTER SHADE WHICH GIVES SUFFICIENT VIEW OF WELD
ZONE. PROVIDE PROT SCREEN S & FLASH GOGGS, IF NEC, TO SHIELD
OTHERS. OTHER PROT EQUIP: & PROT FSHLD & MAY INCL ARM PROTECTORS,
APRONS, HAT, SHOULDER PROTECTION AS WELL AS DARK SUBSTANTIAL CLTHG.
* Ecological Information *
Ecological:N/P. PHYSICAL DATA: AS SHIPPED, THESE PRODS ARE
NONFLAMMABLE, NON-EXPLOSIVE, NON-REACTIVE & NON-HAZARDOUS. PHYSICAL
STATE: SOLID. HAZ DECOMP PRODS: FUMES & GASES TO WHICH WORKERS MAY
BE EXPOSED INCL: COATINGS ON MATL BEING WORKED (SUCH AS PAINT,
PLATING OR GALVANIZING), NUMBER OF WELDING OPERATIONS & VOL OF WORK
AREA, QUALITY & AMT OF VENT, POSITION OF WORKER'S HEAD W/RESPECT TO
FUME PLUME, AS WEL L AS PRESENCE OF CONTAMINANTS IN ATM (SUCH AS
CHLORINATED HYDROCARB VAPS FROM CLEANING OR PAINTING ACTIVITIES).
WHEN MATLS CONSUMED, FUME & GAS DECOMP PRODS GENERATED ARE
DIFFERENT IN PERCENT & FORM F ROM INGREDS LISTED IN (TRANSPORT
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
WITH FEDERAL, STATE AN D LOCAL REGULATIONS.
* MSDS Transport Information *
Transport Information:N/P. ECOLOGICAL INFO: SECTION II. DECOMP PRODS OF
NORMAL OPERATION INCL THOSE ORIGINATING FROM VOLATILIZATION, RXN OR
OXIDATION OF INGREDS, PLUS THOSE FROM MATL BEING WORKED & COATINGS
ETC, NOTED ABOV E. REASONABLY EXPECTED DECOMP PRODS FROM NORM USE
OF THESE PRODS INCL COMPLEX OF OXIDES & FLUORIDES OF MATLS LISTED,
AS WELL AS CARBON MONOXIDE, CARBON DIOXIDE, OZONE & NITROGEN OXIDES
(REFER TO "CHAR ACTERIZATION OF ARC WELDING FUME" AVAIL FROM AWS).
TLV FOR MANGANESE (0.2 MG/M3) WILL BE REACHED BEFORE GEN LIMIT FOR
WELDING FUMES OF 5 MG/M3 IS REACHED. ONLY WAY TO DETERMINE TRUE
IDENTITY OF DECOMPPRODS IS BY (SARA REG INFO)
* Regulatory Information *
SARA Title III Information:MANGANESE & CHROMIUM ARE TOX CHEMS SUBJECT
SAMPLING & ANLAYSIS. COMPOSITION & QTY OF FUMES & GASES TO WHICH
WORKER MAY BE OVEREXPOSED CAN BE DETERMINED FROM SAMPLE OBTAINED
FROM INSIDE WELDER'S HELMET, IF WORN, OR IN WORKERS BRTHG ZONE. SEE
ANSI/AWS F1.1 "METHOD FOR SAMPLINGAIRBORNE PARTICLES GENERATED BY
WELDING & ALLIED PROCESSES," AVAIL FROM AMERICAN WELDING SOCIETY.
Federal Regulatory Information:N/P. HAZARDOUS INGREDS LISTED IN SECTION
II, COVERS MATLS FROM WHICH PROD IS MANUFACTURED. FUMES & GASES
PRODUCED DURING NORMAL USE OF THESE PRODS ARE COVERED IN REACTIVITY
DATA SECTION. TERM HAZARDOU S SHOULD BE INTERPRETED AS TERM
REQUIRED & DEFINED BY LAWS, STATUTES OR REGS & DOES NOT NECESSARILY
IMPLY THE EXISTENCE OF ANY HAZARD WHEN THE PRODUCTS ARE USED AS
DIRECTED BY THE ESAB GROUP.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS OR PRODUCES
A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER AND
BIRTH DEFECTS (OR OTHER REPRODUCTIVE HARM) (CALIFORNIA HEALTH &
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:A NIOSH/MSHA-APPROVED RESPIRATOR IS RECOMMENDED
IF DUST IS GENERATED.
Ventilation:GENERAL; LOCAL EXHAUST VENTILATION AS NECESSARY TO CONTROL
ANY AIR CONTAMINANTS TO WITHIN THEIR PELS OR TLVS DURING THE USE OF
THIS PRODUCT.
CUTTING, AND ALLIED PROCESSES)
Other Protective Equipment:BODY PROTECTION AS NECESSARY TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
WELDING RODS AS SUCH ARE NOT HAZARDOUS, BUT WHEN USED IN WELDING, THEY
GENERATE HAZARDOUS FUMES AND DUST. WORKERS MUST WEAR PROTECTIVE
EQUIPMENT DURING WELDING PROCEDURES TO AVOID OVEREXPOSURE.
* Product Identification *
Preparer's Name:CORPORATE ENVIRONMENT
* Composition/Information on Ingredients *
Ingred Name:CADMIUM
Minumum % Wt:5.
Ingred Name:COPPER
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:SILVER
ACGIH TLV:0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ZINC
Ingred Name:NICKEL
Minumum % Wt:0.
Maxumum % Wt:3.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE/SKIN: MAY CAUSE IRRITATION.
INHALATION: MAY CAUSE EXCESSIVE CADMIUM ABSORPTION RESULTING IN
PULMONARY EMPHYSEMA AND/OR KIDNEY DYSFUNCTION. INGESTION: HARMFUL.
MAY CAUSE ABDOMINAL PAIN, NUASEA, VOM ITING AND DIARRHEA. COPPER
POISONING CAN RESULT IN HEMOLYTIC ANEMIA AND KIDNEY, LIVER AND
SPLEEN DAMAGE. NOTE: INHALATION OF FUMES MAY CAUSE A FLU-LIKE
ILLNESS CALLED METAL FUME FEVER. TYPICALLY METAL FUME FEVER BEGINS
EFFECTS DESCRIBED ABOVE ONLY APPLY IF DUST OR FU ME IS FORMED.
Explanation of Carcinogenicity:IN EVALUATING CADMIUM AND CADMIUM
COMPOUNDS, THE IARC HAS DETERMINED THAT THERE IS SUFFICIENT
EVIDENCE OF CARCONOGENCITY IN HUMANS (GROUP 1). SIMILAR
CARCONOGENCITY RESULTS FOR NICKEL. NTP, OSHA AND A CGIH CONSIDERS
CADMIUM AND CADMIUM COMPOUNDS TO BE SUSPECT HUMAN CANCER HAZARD.
(A2).
Effects of Overexposure:IRRITATION, PULMONARY EMPHYSEMA AND/OR KIDNEY
DYSFUNCTION, ABDOMINAL PAIN, NAUSEA, COMITING, DIARRHEA, HEMOLYTIC
ANEMIA, KIDNEY, LIVER AND SPLEEN DAMAGE, METAL FUME FEVER, METALLIC
TASTE, DRYNESS, COU GH, SHORTNESS OF BREATH, HEADACHE, FATIGUE,
VOMITING, MUSCLE AND JOINT PAIN, FEVER, AND CHILLS. CHRONIC:
PROLONGED OR EXCESSIVE EXPOSURE MAY RESULT IN ARGYRIA, A PERMANENT
LOCALIZED BLUE-GRAY DISCOLOR ATION OF THE EYES, SKIN OR MUCOUS
MEMBRANES. REPEATED OR LONG-TERM EXPOSURE TO CADMIUM OR NICKEL,
EVEN AT RELATIVELY LOW CONCENTRATIONS, MAY RESULT IN KIDNEY DAMAGE
AND AN INCREASED RISK OF LUNG CANCE R.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING MEDICAL
CONDITIONS SUCH AS RESPIRATORY AND/OR KIDNEY AILMENTS. INDIVIDUALS
WITH WILSON'S DISEASE ARE AT INCREASED RISK OF COPPER POISONING.
* First Aid Measures *
First Aid:EYE CONTACT: FLUSH EYES WITH PLENTY OF WATER. IF IRRITATION
DEVELOPS, CALL A PHYSICIAN. SKIN CONTACT: IMMEDIATELY WASH SKIN
WITH SOAP AND PLENTY OF WATER. IF IRRITATION PERSISTS, CALL A
PHYSICIAN. INH ALATION: IF EXPOSED TO EXCESSIVE LEVEL OF METAL
FUMES, REMOVE TO FRESH AIR AND SEEK MEDICAL ATTENTION. INGESTION:
PROCEDURES NORMALLY NOT NEEDED. IF LARGE QUANTITIES ARE INGESTED,
SEEK MEDICAL ADVICE.
* Fire Fighting Measures *
Extinguishing Media:USE CARBON DIOXIDE, CHEMICAL FOAM OR DRY CHEMICAL.
USE ANY MEANS FOR EXTINGUISHING SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED POSITIVE PRESSURE
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NOT A FIRE OR EXPLOSION HAZARD IN SOLID
FORM. FINELY DIVIDED DUST MAY IGNITE AND BURN RAPIDLY WHEN MIXED
WITH AIR IN THE PROPER PROPORTIONS. TOXIC METAL FUMES MAY BE
RELEASED IN A FIRE SITUATION.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILLAGE AND SCOOP UP OR VACUUM.
REQUIRED REFER TO EPA, DOT & APPLICABLE STATE AND LOCAL REGULATIONS
FOR CURRENT RESPONSE INF ORMATION. IT IS RECOMMENDED THAT EACH USER
ESTABLISH A SPILL PREVENTION, CONTROL AND COUNTERMEASURE PLAN
(SPCC). SUCH PLAN SHOULD INCLUDE PROCEDURES FOR PROPER STORAGE,
CONTROL & CLEAN-UP OF SPILLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY LOCATION AWAY
FROM INCOMPATIBLE MATERIALS. AVOID CONTACT WITH DUST MISTS OR FUMES
RESULTING FROM THE USE OF THIS PRODUCT. USE ONLY WITH ADEQUATE
VENTILATION.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. DO NOT EAT, DRINK OR
SMOKE IN WORK AREA. NOTE: CONSULT THE MOST RECENT OSHA CADMIUM
REQUIREMENTS, SO ME OF WHICH ARE NOT COVERED IN THE MSDS.
* Physical/Chemical Properties *
HCC:N1
Boiling Pt:B.P. Text:N/D
Solubility in Water:INSOLUBLE
Appearance and Odor:METALLIC WIRE, ROD OR STRIP; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, STRONG OXIDIZERS, ACETYLENE, AMMONIA, HYDROGEN
PEROXIDE, MAGNESIUM METAL, AMMONIUM NITRATE, HYDROGEN SULFIDE,
ELEMENTAL SULFUR, SELENIUM, TELLUMIUM, CHLORINATED RUBBER.
Stability Condition to Avoid:NONE EXPECTED.
Hazardous Decomposition Products:TOXIC METAL OXIDES ARE EMITTED WHEN
HEATED ABOVE THE MELTING POINT. THE AMOUNT OF FUME EVOLVED
INCREASES AS THE TEMPERATURE RISES.
* Disposal Considerations *
PRODUCT OR MIXTURES CONTAINING THIS PRODUCT SHOULD BE TESTED FOR
TOXICITY CHARACTERISTICS (TC) BY FOLLOWING EPA TCLP TESTING
REQUIREMENTS WILL VARY BY TYPE OF DISPOSAL SELECTED. CONSULT WITH
STATE & LOCAL AUTHORITIES.
* MSDS Transport Information *
Transport Information:NOT REGULATED FOR TRANSPORTATION.
* Regulatory Information *
DELAYED: YES. FIRE, REACTIVITY AND SUDDEN RELEASE OF PRESSURE:
NICKEL, SILVER, AND ZINC (AS OXIDE).
Federal Regulatory Information:COMPONENTS OF THIS MATERIAL ARE LISTED
CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS AND OTHER REPRODUCTIVE HARM: VOLATILE ORGANIC
COMPOUNDS(CARB): NOT DETERMINE D. CANDIAN REGS, EUROPEAN REGS: NOT
DETERMINED.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SPECIFIED
Ventilation:MECHANICAL (GENERAL/LOCAL EXHAUST)
Other Protective Equipment:NORMAL WORK CLOTHING COVERING ARMS & LEGS.
Supplemental Safety and Health
MSDS IS UNDATED
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:LUBRICATING OIL (ACGIH TLV 5MG/CUM AS OIL MIST
ACGIH TLV:NOT SPECIFIED
* Hazards Identification *
Effects of Overexposure:NONE NOTED BY MFR. LOW TOXICITY & LOW HAZARD TO
HEALTH.
* First Aid Measures *
First Aid:SKIN:WASH WITH MILD SOAP & WATER. EYES:FLOOE IMMEDIATELY WITH
WATER. SEEK MEDICAL ATTENTION.
* Fire Fighting Measures *
Lower Limits:UNKN
Upper Limits:UNKN
Extinguishing Media:ALCOHOL FOAM, CO*2,DRY CHEMICAL
Fire Fighting Procedures:NORMAL
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY THE MFGR.
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH VERMICULITE OR SNAD. SCOOP UP INTO
PAPER CONTAINERS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COO,DRY PLACE.AVOID SKIN
CONTACT DURING HANDLING.
Other Precautions:NONE SPECIFIED.
* Physical/Chemical Properties *
HCC:V6
Spec Gravity:0.9
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER LIQUID,CHARACTERISTIC PETROLEUM ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED
Stability Condition to Avoid:NOT SPECIFIED
Hazardous Decomposition Products:NOT SPECIFIED
* Disposal Considerations *
Waste Disposal Methods:CNA BE INCINERATED OR BURIED IN LANDFILL AREA
ACCORDING TO LOCAL,STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .
Other Protective Equipment:USE LONG SLEEVE AND LONG LEG CLOTHING.
Work Hygienic Practices:REMOVE & WASH CLOTHING BEFORE REUSE.WASH HANDS
BEFORE EATING,SMOKING, OR USING WASH ROOM.SMOKE IN SMOKING AREAS
ONLY.
Supplemental Safety and Health
EXPLO HAZ:HOT SURFACES REQ SPEC PREC.IN EMER CONDITIONS,OVEREXPOS TO
DECOMP PROD MAY CAUSE HLTH HAZ.SYMP MAY NOT BE IMMED APPARENT.HAZ
* Product Identification *
Preparer's Name:N GAUL
* Composition/Information on Ingredients *
Ingred Name:BIURET OF 1,6-HEXAMETHYLENE DIISOCYANATE.ACGIH IS FOR
OSHA PEL:N/K
Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)
Fraction by Wt: 5%
Other REC Limits:N/K
Ingred Name:METHYL ISOBUTYL KETONE (SARA III)
Other REC Limits:N/K
Ingred Name:TOLUENE (SARA III)
Fraction by Wt: <5.0%
Other REC Limits:N/K
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Fraction by Wt: <5.0%
Other REC Limits:N/K
Ingred Name:N-BUTYL ACETATE (SARA III)
Fraction by Wt: <5.0%
Other REC Limits:N/K
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Other REC Limits:N/K
Ingred Name:EFTS OF OVEREXP:TRACT CAUSING RUNNY NOSE,SORE
THROAT,COUGH,CHEST DISCOMFORT,SHORTNESS OF BREATH & REDUCED LUNG
FUNCTION.
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NIOSH STUDIES INDICATE 2-ETHOXYETHYL
ACETATE HAS CAUSED REPRO DISORDERS IN LAB ANIM (RATS OR MICE) & MAY
HAVE POTNTL FOR CAUSING SIMILAR DISORDERS IN HUMANS .PRLGD/RPTD
EXPOS:MOD IRRIT,DRYING & DEFAT OF SKIN CAUSING
CRACKING/DERMAT.RPTD OVEREXPOS OR SINGLE LRG DOSE MAY CAUSE
ISOCYANATE SENSIT IN CERTAIN PERSONS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYE:LIQ,AEROSOLS,VAP:IRRIT.POSS
TEARING,REDNESS,SWELLING W/ STINGING SENSATION.SKIN:ISOCYANATES
REACT W/ SKIN PROTEIN & MOISTURE CAUSING IRRIT.POSS
SWELLING,REDNESS,RASH.INGEST:POSS IRRIT & CORROSIVE TO MOUTH,STOM
& DIGEST TRACT.VOM MAY CAUSE ASPIR W/ CHEM PNEUMONITIS.INHAL:RESP
IRRIT & NERVOUS SYSTEM DEPRESS (SEE SUP)
Medical Cond Aggravated by Exposure:ISOCYANATE
SENSITIZATION.ASTHMA.DERMATITIS.
* First Aid Measures *
First Aid:EYES:FLUSH W/ CLEAN,LUKEWARM WATER (LOW PRESSURE) FOR AT
CONTAM CLTHG;WASH BEFORE REUSE.WASH AFFECTED AREAS WELL W/
SOAP/WATER.INGEST:DO NOT INDUCE VOM.DO NOT GIVE ANYTHING BYMOUTH
TO UNCON PERSON.GET MED ATTN.INHAL:MOVE TO EXPOSURE-FREE
AREA.RESTORE BREATHING.ASTHMATIC-TYPE SYMP MAY DEVELOP & MAY BE
IMMED OR DELAYED BY SEVERAL HRS.
* Fire Fighting Measures *
Flash Point Method:TCC
Upper Limits:1.0%
Extinguishing Media:FOAM,CO*2,DRY CHEMICAL,WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:KEEP CONTR TIGHTLY CLOSED.ISOLATE FROM
HEAT,SPARKS,ELECTRICAL EQUIP & OPEN FLAME.CLOSED CONTRS MAY EXPLODE
WHEN EXPOSED TO EXT HEAT.APPLICATION TO (SEE SUP DAT)
* Accidental Release Measures *
Spill Release Procedures:EVACUATE ALL NONESSENTIAL PERSONNEL.REMOVE ALL
SOURCES OF IGNITION (FLAME,HOT SURFACES,SPARK SOURCES).VENTILATE
AREA.CONTAIN AND REMOVE WITH INERT ABSORBENT & NON-SPARKING TOOLS.
Neutralizing Agent:N/K
*Handling and Storage *
Handling and Storage Precautions:STORE IN WELL-VENT BUILDINGS DESIGNED
NOT HANDLE UNTIL MRF PREC READ/UNDERSTOOD.
Other Precautions:KEEP CONTR TIGHT/UPRIGHT TO PRVT LEAKS.PRVT
PRLNG/RPTD BRTHG OF VAPOR/MIST.KEEP TIGHTLY CLOSED TO PRVT MOISTURE
CONTAM WHICH CAN CAUSE PRESS BUILDUP FROM A RXN PRODUCING
CO*2,CAUSING SEALED CONTR TO B URST.DO NOT RESEAL IF CONTAM
SUSPECTED.
DECOMP PROD:CO*2,CO,OXIDES OF N,TRACES OF HCN,HDI.EFTS OF OVEREXP
:W/ THESE PROGRESSIVE STEPS:HEADACHE,DIZZ,STAGGERING
GAIT,CONFUSION,UNCON,COMA.VAP/MIST CAN IRRIT RESP (SEE INGRED #8)
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:>1 (AIR=1)
Spec Gravity:0.9 (WATER=1)
Evaporation Rate & Reference:>1 (ETHER=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR,LIGHT AMBER LIQUID WITH SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER,AMINES,STRONG BASES,ALCOHOLS,METAL COMPOUNDS,SURFACE ACTIVE
MATERIALS,MATERIALS WHICH REACT WITH ISOCYANATES.
Stability Condition to Avoid:CONTACT WITH MOISTURE,HIGH TEMPERATURES.
Hazardous Decomposition Products:BY HIGH HEAT AND FIRE:CARBON
DIOXIDE,CARBON MONOXIDE,OXIDES OF NITROGEN,TRACES OF HCN,HDI.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .EMPTY CONTAINERS MUST BE
HANDLED WITH CARE DUE TO PRODUCT RESIDUE AND FLAMMABLE VAPOR.DO NOT
INCINERATE CLOSED CONTAINERS .OBSERVE ALL OTHER PRECAUTIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH
ORGANIC VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS
Ventilation:USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR
LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:CLOTHES TO PREVENT PROLONGED/REPEATED SKIN
CONTACT. DLA-HMSI: EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE TABLE Z-3
Ingred Name:PETROLEUM DISTILLATE, ALIPHATIC HYDROCARBON OR PETROLEUM
HYDROCARBON
Fraction by Wt: 0-7%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 0-4%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 0-4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C, 5 MG/M3 (FUME)
Ingred Name:HEAVY AROMATIC NAPHTHA (SOLVENT NAPHTHA)
Fraction by Wt: 0-3%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: <3%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ETHYL ALCOHOL (ETHANOL)
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1MG/M3 FUME/1 DUST
Ingred Name:NAPHTHA, LIGHT AROMATIC (SOLVENT NAPHTHA)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EXPOSURE MAY CAUSE IRRITATION OF EYES.
PROLONGED/REPEATED SKIN CONTACT MAY CAUSE IRRITATION OR DERMATITIS.
INHALATION MAY CAUSE RESPIRATORY IRRITATION, CNS EFFECTS. INGESTION
MAY CAUSE GI TRACT IRRITA TION. PROLONGED/REPEATED OVEREXPOSURE MAY
CAUSE DIGESTIVE/BLOOD/URINARY/NERVOUS/REPRODUCTIVE DISORDERS;
SILICOSIS.
Explanation of Carcinogenicity:CRYSTALLINE SILICA (NTP & IARC-2A).
Effects of Overexposure:EYES-IRRITATION. SKIN CONTACT-IRRITATION. SKIN
ABSORPTION/INHALATION-KIDNEY/LIVER/BLOOD DAMAGE.
INHALATION-RESPIRATORY IRRITATION, HEADACHE, DIZZINESS, STAGGERING
GAIT, CONFUSION, UNCONSCIOUSNESS, COM A. INGESTED-NONE SPECIFIED BY
MANUFACTURER.
Medical Cond Aggravated by Exposure:PERSONS WITH SKIN OR LUNG DISORDERS
MAY BE MORE SUSCEPTIBLE TO EFFECTS OF THIS PRODUCT. REPEATED &
PROLONGED OVEREXPOSURE &/OR INDIVIDUAL SENSITIVITY MAY INCREASE
DEGREE OF ADVERSE HEALTH EFFCTS.
* First Aid Measures *
First Aid:IN ALL CASES GET MEDICAL ATTENTION. EYES-FLUSH WITH WATER FOR
WATER. INHALED-REMOVE TO FRESH AIR. ADMINISTER OXYGEN OR ARTIFICIAL
RE SPIRATION AS NEEDED. INGESTED-CONTACT POISON CONTROL CENTER AND
OBTAIN IMMEDIATE MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1.0
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL FIRE FIGHTER'S PROTECTIVE GEAR. USE WATER TO COOL FIRE EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS. VENTILATE AREA. REMOVE WITH INERT ABSORBENT &
NON-SPARKING TOOLS. AVOID CONTACT. PLACE IN A CONTAINER FOR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
PLACE AWAY FROM SOURCES OF IGNITION & STRONG OXIDIZING AGENTS.
Other Precautions:DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE BONDED &
GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUIDS IN EXCESS OF A
FEW INCHES. DO NOT FLAME CUT, BRAZE OR WELD WITHOUT MSHA OR NIOSH
APPROVED RESPIR ATOR OR APPROPRIATE VENTILATION.
* Physical/Chemical Properties *
HCC:F3
Vapor Density:>1
Evaporation Rate & Reference:<1 (ETHER=1)
Appearance and Odor:BROWN LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
OTHER NOXIOUS GASES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL ENVIRONMENTAL REGULATIONS. DO NOT INCINERATE CLOSED
CONTAINERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNLESS VAPOR CONCENTRATIONS ARE
EXCESSIVE. A NIOSH APPROVED ORGANIC VAPOR CARTRIDGE RESPIRATOR CAN
BE USED.
Ventilation:NONE REQUIRED, BUT LOCAL EXHAUST/DILUTION VENTILATION WILL
HELP DISSIPATE VAPORS IN ENCLOSED/POORLY VENTILATED AREAS.
Other Protective Equipment:PROTECTIVE CLOTHING
Supplemental Safety and Health
OTHER HAZARDOUS INGREDIENTS AS ESTABLISHED BY ACGIH/STANDARDS
PROMULGATE D BY OSHA.
* Product Identification *
Kit Part:Y
Preparer's Name:BART CASE
* Composition/Information on Ingredients *
Fraction by Wt: 2%
Ingred Name:BUTANOL, N-BUTYL ALCOHOL, PROPYL CARBINOL, BUTYL ALCOHOL
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (KNOWN CARCINOGEN BY NTP;
Fraction by Wt: 4-5%
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ZINC
Ingred Name:ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE
* First Aid Measures *
DRY CLOTH/TOWEL, WASH THOROUGHLY W/SOAP & WATER. DON'T USE A
SOLVENT OT REMOVE PRODUCT. INHALATION: REMOVE TO FRESH AIR, GIVE
CPR/OXYGEN I F NEEDED. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:SAND, FOAM, CO2, DRY CHEMICALS
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING W/A SELF
CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:VAPORS MAY FORM EXPLOSIVE MIXTURE W/AIR.
MATERIAL IS FLAMMABLE/COMBUSTIBLE & MAY EXPLODE IN HEAT OF FIRE.
* Accidental Release Measures *
Spill Release Procedures:COVER W/DRY ABSORBENT SUCH AS SAND/SAWDUST;
SCOOP UP & PLACE IN AN APPROPRIATE CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY AREA AWAY FROM EXCESSIVE
IN ORIGINAL SEALED CONTAINERS.
* Physical/Chemical Properties *
Vapor Density:>1
Spec Gravity:0.9 G/CC
Solubility in Water:MODERATE
Appearance and Odor:YELLOW, NONVISCOUS LIQUID W/LACQUER ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDIC/BASIC OXIDIZING AGENTS
Stability Condition to Avoid:MOISTURE, EXCESSIVE HEAT, FLAMES, LIGHT
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
Waste Disposal Methods:LANDFILL/INCINERATE/DISPOSE OF IN ACCORDANCE
| 1 | eyes_protection_mandatory |
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