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* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
TLV BY VENTILATION, USE A NIOSH/MSHA PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR. WHEN SANDING OR ABRADING FILM, USE A
NIOSH/MSHA DUST/MIST RES PIRATOR.
Ventilation:LOCAL EXHAUST: PREFERABLE. GENERAL EXHAUST: ACCEPTABLE IF
THE EXPOSURE TO HAZARDOUS INGREDIENTS IF KEPT BELOW TLV.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS AFTER USING.
Supplemental Safety and Health
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS CAN BE HARMFUL/FATAL.
* Product Identification *
Product ID:ALKYD FLAT, S-G & EG-SHEL FINISHES-WEATHER PERFECT
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL, GLYCOL
Fraction by Wt: <5%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; PETROLEUM DISTILLATE,
HYDROTREATED ,(MINERAL SPIRITS)
Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM
SILICATE
ACGIH TLV:2 MG/CUM (RESP DUST)
Ingred Name:TITANIUM DIOXIDE, TIO2
Fraction by Wt: 8%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE, SKIN, OR RESPIRATORY IRRITANT.
NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY CAUSE DEATH, OR
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. LONG TERM EXPOSURE TO HIGH
LEVELS OF SILICA MAY CAUSE S ILICOSIS & POSSIBLY CANCER. PROLONGED
OVEREXPOSURE TO SOLVENTS MAY CAUSE EFFECTS TO LIVER/URINARY
SYSTEMS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: HEADACHE, DIZZINESS, NAUSEA, LOSS
OF COORDINATION, UNCONSCIOUSNESS, DEATH. EYES/SKIN: REDNESS,
ITCHING OR BURNING SENSATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM
& QUIET. SKIN: WASH W/SOAP & WATER. EYES: FLUSH W/PLENTY OF WATER
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:0.9%
Upper Limits:6%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIP & SCBA. WATER SPRAY
MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE.
USE WATER TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES
SPECIAL PRECAUTIONS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:USE ONLY W/ADEQUATE VENTILATION. KEEP
CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO APPROVED
CONTAINERS W/COMPLETE & APPROPRIATE LABELING.
Other Precautions:DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
AVOID BREATHING VAPOR & SPRAY MIST & CONTACT W/SKIN & EYES. CONSULT
NFPA CODE. USE APPROVED BONDING & GROUNDING PROCEDURES.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME OR OTHER IGNITION
SOURCES.
Hazardous Decomposition Products:BY FIRE: CO2, CO
* Disposal Considerations *
Waste Disposal Methods:WASTE MAY BE HAZARDOUS UNDER THE RCRA. TEST
WASTE FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS
WASTE NUMBERS. INCINERATE IN APPROVED FACILITY. DON'T INCINERATE
CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Product ID: SPEEDHIDE LATEXHOUSE PAINT, 6-I
Box: 9
*
Contractor Summary
*
Cage: PPGXX
Box: UNKNOW
Box: 9
*
Ingredients
*
OSHA PEL: SEE TABLE Z-3
ACGIH TLV: 0.1 MG/M3 RDUST
------------------------------
------------------------------
------------------------------
------------------------------
% Wt: 2-5
OSHA PEL: SEE TABLE Z-3
ACGIH TLV: 0.1 MG/M3 RDUST
------------------------------
% Wt: 1-2
OSHA PEL: N/K (FP N)
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
% Wt: 1-2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
VERY LIMITED. SINCE OVEREXP ARE NOT
-----------------------------
MAY CAUSE KIDNEY & LIVER DMG & HAS BEEN
-----------------------------
EFFECTS HAS BEEN FOUND IN HUMANS.
-----------------------------
& VISUAL DISTURBS MAY INDICATE EXCESS EYE
-----------------------------
ARE CONDITIONS ASSOCIATED W/EXCESSIVE SKIN CONT.
-----------------------------
PRODUCTS DURING WELDING OR FLAME CUTTING.
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: INGEST: HARMFUL/FATAL. EYES: IRRIT. SKIN: MAY CAUSE
SLIGHT IRRIT. INHAL: VAP & SPRAY MIST MAY BE HARMFUL. SANDING &
GRINDING DUSTS MAY BE HARMFUL. VAP GENERATED AT ELEVATED TEMPS IRRITATES EYES
, NOSE & THROAT. CHRONIC: AVOID LONG TERM & RPTD CONT. LONG-TERM
EXPOS TO CRYSTALLINE SILICA/QUARTZ (EFTS OF OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZ: MAY LEAD TO DISABLING INJURY
KNOWN AS SILICOSIS. THESE EFTS ARE ASSOC W/BRTHG EXCESS AMTS OF SILICA DUST.
APPLICATIONS OF THIS PROD IS NOT EXPECTED TO GENERATE EXCESS AMTS OF
RESPIRABLE SILI CA/QUARTZ SO POTENTIAL HAZ FOR HUMANS IS LIMITED. ANIMALS
INHALING MASSIVE QTYS OF TITANIUM DIOXIDE DUST IN A (SUP DAT)
First Aid: INGEST: DO NOT INDUCE VOMIT. EYES: FLUSH IMMED W/PLENTY OF WATER FOR
W/SOAP & WATER. INHAL: REMOVE TO FRESH AIR. APPLY ARTF RES P & OTHER
SUPPORTIVE MEASURES AS REQUIRED. IF INGEST, ANY TYPE OF OVEREXP/SYMPS OF
OVEREXP OCCUR DURING/FOLLOWING USE OF PROD, CONT POIS CTL CTR, EMER ROOM/MD
IMMED; HAVE MSDS INFO AVAIL.
*
Handling and Disposal
*
Spill Release Procedures: PROVIDE MAXIMUM VENT. ONLY PERS EQUIPPED W/PROPER
NIOSH APPROVED RESP & SKIN & EYE PROT SHOULD BE PERMITTED IN AREA.
REMOVE ALL SOURCES OF IGNITION. TAKE UP SPILLED MATL W/SAWDUST,
VERMICULITE/OTHER A BSORBENT MATL & PLACE INTO CONTRS FOR DISPOSAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF IN ACCORDANCE WITH
FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS
SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEME NT
FACILITY.
QUANTITIES IN BUILDINGS DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS IIIB
COMBUSTIBLE LIQUIDS.
Other Precautions: PROTECT FROM FREEZING. IF THIS MATERIAL IS PART OF A
MULTIPLE COMPONENT SYSTEM, READ THE MSDS(S) FOR THE OTHER COMPONENT OR
COMPONENTS BEFORE BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF
ALL OF ITS PARTS.
*
Fire and Explosion Hazard Information
*
Flash Point Method: PMCC
Extinguishing Media: USE NFPA CLASS B EXTINGS (CARBON DIOXIDE, DRY
CHEM/UNIVERSAL AQUEOUS FILM-FORMING FOAM) DESIGNED TO EXTING NFPA(SUP DAT)
Fire Fighting Procedures: WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N).
WATER SPRAY MAY BE INEFFECTIVE, BUT MAY BE USED TO COOL CLSD CONTRS TO PVNT
PRESS BUILD-UP & POSS (SUP DAT)
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE OR BURST (DUE TO
THE BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
*
*
Respiratory Protection: WHERE VENTILATION IS INADEQUATE, USE A SUITABLE NIOSH
APPROVED RESPIRATOR.
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP
CONC OF INGS LISTED BELOW LOWEST SUGGESTED EXPOS
Other Protective Equipment: ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER
(FP N). WEAR PROTECTIVE CLOTHING, INCLUDING IMPERMEABLE APRON.
Work Hygienic Practices: CLEAN OR DISCARD CONTAMINATED CLOTHING AND SHOES.
Supplemental Safety and Health: EXTING MEDIA: CLASS IIIB COMBUST LIQ FIRES.
FIRE FIGHT PROC: AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER IS
USED, FOG NOZZ ARE PREF. EFTS OF OVEREXP: LONG-TERM STUDY DEVELOPED LUNG
TUMORS. STUDIES W/HUMANS INVOLVED IN MANUFACTURE OF THIS PIGMENT INDICATE NO
INCRD RISK OF CANCER FROM EXPOS.
*
Physical/Chemical Properties
*
Vapor Density: HVR/AIR
Spec Gravity: 1.2-1.4
Appearance and Odor: VISCOUS LIQUID W/ODOR CHARACTERISTIC OF CHEMICAL FAMILY &
ANY SOLVENTS LISTED.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS,
OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRODUCE HAZ DECOMP PRODUCTS WHEN HEATED.
WELDING, BRAZING/FLAME-CUTTING MAY PRODUCE FUMES INCLUDING CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: SPEEDHIDE LATEXHOUSE PAINT, 6-I
Assigned IND: Y
Company Name: PPG INDUSTRIES INC. COATINGS & RESINS GP
PO Box: 9
Label Required IND: Y
Status Code: C
Origination
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INGESTION: HARMFUL OR FATAL. EYES: IRRITATION.
SKIN: MAY CAUSE SLIGHT IRRITATION. INHALATION: VAPOR AND SPRAY MIST MAY BE
HARMFUL. SANDING AND GRINDING DUSTS MAY BE HARMFUL. VAPOR GENERATED AT
ELEVATED TEMPERATURES IRRITATES EYES, NOSE AND THROAT. CHRONIC: CANCER
HAZARD. CONTAINS CRYSTALLINE SILICA-QUARTZ, WHICH IS LISTED AS A HUMAN LUNG
CARCINOGEN (FP N). AVOID LONG TERM AND REPEATED CONTA CT. LONG-TERM EXPOSURE
TO CRYSTALLINE SILICA/QUARTZ MAY LEAD TO DISABLING LUNG INJURY CALLED
SILICOSIS.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SPECIFIED BY MANUFACTURER.
Ventilation:DOES NOT APPLY.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:STANDARD INDUSTRIAL HYGIENE PRACTICES.
Supplemental Safety and Health
NONE
* Product Identification *
Product ID:NATURAL BLUE CLEANER & DETERGENT
Preparer's Name:STEPHEN REPETTO
* Composition/Information on Ingredients *
Ingred Name:MONOETHANOLAMINE OLEATE
Fraction by Wt: 1-5%
Other REC Limits: RECOMMENDED
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE IRRITANT. MILD SKIN IRRITANT.
Explanation of Carcinogenicity:NOT LISTD AS A CARCINOGEN.
Effects of Overexposure:IRRITATION OF EYES OR SKIN; STOMACH DISTRESS,
NAUSEA, OR VOMITING IF SWALLOWED.
Medical Cond Aggravated by Exposure: KNOWN.
* First Aid Measures *
First Aid:INGESTION-DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM.
OBTAIN MEDICAL ATTENTION. INHALATION-DOES NOT APPLY. SKIN
CONTACT-FLUSH WITH WATER. THEN WASH WITH SOAP AND WATER. EYE
ATTENTION.
* Fire Fighting Measures *
Flash Point:
Extinguishing Media: NORMALLY NEEDED.
Fire Fighting Procedures: SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:.
* Accidental Release Measures *
Spill Release Procedures:DIKE OR DAM LARGE SPILLS. PUMP TO CONTAINERS
OR SOAK UP ON AN INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:NO SPECIAL PROCEDURES. AVOID PROLONGED
SKIN CONTACT. KEEP AWAY FROM EYES.
Other Precautions:AMINE SOAP.
* Physical/Chemical Properties *
HCC:B3
Evaporation Rate & Reference:MORE THAN 1
Appearance and Odor:BLUE LIQUID, PINE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:
Hazardous Decomposition Products:
* Disposal Considerations *
Waste Disposal Methods:ALL COMPONENTS OF THIS PRODUCT ARE COMPATIBLE
WITH BIOLOGICAL TREATMENT. THIS PRODUCT CAN BE FLUSHED TO SANITARY
SEWERS. CONSULT WITH STATE AND LOCAL AUTHORITIES FOR ANY
RESTRICTIONS ON DISPOSAL OF CH EMICAL WASTE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED < APPLIC
LIM BY VENT, WEAR PROPERLY FITTED ORG VAP/PARTICULATE RESP APPRVD
BY NIOSH/MSHA. WHEN SANDING, WIREBRUSHING, ABRADING,
BURNING/WELDING DRIED FILM, WEAR PARTICULATE RESP APPRVD BY (ING
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATL
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLOS WHEN
EXPOS TO EXTREME HEAT. EFTS OF OVEREXP:OVEREXP TO SOLV W/PERM BRAIN
& NERVOUS SYS DMG. HNDLG/STOR PREC:KEEP AREA VENT. DO NOT SMOKE.
EXTING ALL FLAMES, PILOT LIGHTS & HEATERS. TURN OFF STOVES, ELEC
TOOLS & APPLIANCES & OTHER SOURCES (ING 7)
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: 5%
Ingred Name:XYLENE (SARA III)VP: 5.9
Ingred Name:PROPIONIC ACID, 3-ETHOXY-, ETHYL ESTER; (ETHYL
3-ETHOXYPROPIONATE) VP: 1.1
Fraction by Wt: 3%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT:OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING &
GROUNDING PROC. CONTENTS UNDER PRESS. DO NOT PUNCTURE, (ING 8)
RADIATORS, STOVES, HOT WATER & OTHER HEAT SOURCES COULD (ING 9)
Ingred Name:ING 8:CAUSE CNTNR TO BURST. DO NOT TAKE INTERNALLY. KEEP
OUT OF THE REACH OF CHILDREN.
Ingred Name:OTHER PREC:AT HAZ LEVELS ONLY DURING SANDING/ABRADING OF
DUST), 5 MG/M3 (RESPIRABLE FRACTION).
Ingred Name:RESP PROT:NIOSH/MSHA FOR PROT AGAINST NON-VOLATILE
MATERIALS.
ACGIH TLV:ASPHYXIANT
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORDINATION ARE INDICATIONS
OF EXCESSIVE EXPOS TO VAP/S PRAY MISTS. REDNESS & ITCHING/BURNING
SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:TOLUENE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:APPEARS ON NAVY LISTING OF OCCUP CHEM
REPROD HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST HAZ LIST INFORMATION & SAFE HNDLG & EXPOS
INFORMATION . PRLNG OVERE XP TO SOLV INGRED IN PROD MAY CAUSE
ADVERSE EFTS TO LIVER, URINARY & REPROD SYS. RPTS HAVE ASSOC RPTD &
PRLNG (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:INHALATION: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM & QUIET. SKIN: WASH AREA THORO WITH SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES:FLUSH WITH LARGE
INGESTION:NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO
NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:0.7%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFTIVE. IF WATER USED, FOG NOZZ PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CONTENTS EXTREMELY FLAM. KEEP AWAY
FROM HEAT, SPK, & OPEN FLAME. VAP WILL ACCUM READILY & MAY IGNITE
EXPLOS. DURING USE & UNTIL ALL VAP GONE: (SUPDAT)
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL CONTENTS CAN
BE HARMFUL/FATAL. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY
MIST. AVOID CNTCT W/SKIN & EYES. COATING MAY CONTAIN MATLS CLASSED
* Physical/Chemical Properties *
HCC:V3
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENTS.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
WASTE NUMBERS. DO NOT INCIN. DEPRESSURIZE CNTNR. DISPOSE OF IN
ACCORDANCE W/FEDERAL , STATE & LOCAL REGULATIONS REGARDING
POLLUTION.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF 8-HOUR EXPOSURE LIMIT/VALUE IS EXCEEDED FOR
ANY COMPONENT, USE APPROVED NIOSH/MSHA RESPIRATOR. CONSULT YOUR
RESPIRATOR REQUIREMEN TS.
Ventilation:PROVIDE SUFFICIENT MECH VENT (LOCAL/GENL EXHAUST) TO
MAINTAIN EXPOSURE BELOW LIMITS & VALUES.
Other Protective Equipment:EMERG EYE WASH AND DELUGE SHOWER WHICH MEETS
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPILL PROC: DRIED MATL & PLACE INTO CNTNRS. PREVENT RUN-OFF TO SEWERS,
STREAMS, LAKES OR OTHER BODIES OF WATER. NOTIFY LOCAL HEALTH &
WILDLIFE OFFICIALS IF RUN-OFF OCCURS.
* Product Identification *
Product ID:DAP BLACK-TITE ROOF SEALANT
Preparer's Name:C L JOHNSON
* Composition/Information on Ingredients *
Ingred Name:BENZIN;(MINERAL SPIRITS)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CALCIUM CARBONATE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ASPHALT
OSHA PEL:N/K
ACGIH TLV:5 MG/M3; (FUME)
Ingred Name:INERT INGREDIENTS(TYPE NOT SPECIFIED); (INERT ADDITIVES)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: VAPOR MAY CAUSE IRRIT OF EYES,
SKIN & RESP TRACT. MAY CAUSE CNS DEPRESSION: HEADACHE, DIZZINESS,
NAUSEA OR UNCONSCIOUSNESS. IF INGESTED WILL CAUSE VOMITING,
DIARRHEA, DEPRESSED RESPIRATION. CHR ONIC: PROLONGED EXPOSURE TO
SKIN MAY CAUSE DRYING.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS &
IMPAIRED PULMONARY FUNCTIONS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. RESTORE BREATHING IF NECESSARY.
MINS. CONTACT MD. SKIN: WASH WITH SOAP & WATER. CONSULT MD IF IRRIT
DEVE LOPS. INGEST: DO NOT INDUCE VOMITING. IF VICTIM IS CONSCIOUS,
GIVE WATER OR MILK. CONTACT A MD IMMED.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:1.0%
Upper Limits:7.0%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
DO NOT USE STRAIGHT HOSE WATER STREAMS. COOL EXPOSED CONTAINERS
WITH WATER.
Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE IF EXPOSED TO
EXTREME HEAT; ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS &
OPEN FLAMES. DO NOT PUT IN CONTACT W/OXIDATIZING MATLS.
* Accidental Release Measures *
Spill Release Procedures:SMLL: USE ABSORB MATL/SCRAP UP DRIED MATL &
PLACE INTO CNTNR. LGE: WEAR PROT EQUIP. ELIM ALL SOURCES OF
IGNIT(OPEN FLAMES, PILOT LIGHTS, ELEC SPARKS) & VENT SPILL AREA.
CONTAIN SPILL BY DIKING TO PVNT SPREADING. USE ABSORB MATL/SCRAPE
UP (SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CNTNRS FROM EXCESS HEAT &
FREEZING. PROVIDE CROSS VENT IN STOR AREA. KEEP CNTNRS TIGHTLY
CLOSED WHEN NOT IN USE. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:HARMFUL OR FATAL IF SWALLOWED. USE ONLY WITH ADEQUATE
VENTILATION & ELIMINATE SOURCES OF IGNITION WHEN PRODUCT IS USED.
AVOID PLNGD/RPTD BREATHING OF VAPOR(S) & CONTACT WITH SKIN. REMOVE
& WASH CONTAM D CLOTHING BEFORE REUSE.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:6.0
Spec Gravity:1.6 (H2O=1)
Solubility in Water:NEGLIGIBLE.
Appearance and Odor:BLACK PASTE WITH A GASOLINE-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:EXCESSIVE HEAT.
Hazardous Decomposition Products:NORMAL COMBUSTION PRODUCTS, I.E., COX,
NOX.
* Disposal Considerations *
Waste Disposal Methods:DISCARDED SPILL RESIDUE MAY BE INCINERATED. DO
NOT INCINERATE SEALED CONTAINERS. DISPOSE OF IN ACCORDANCE WITH
LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED, NIOSH/MSHA APPRVD SCBA,
POSITIVE PRESS HOSE MASK/AN NIOSH/MSHA AIR LINE MASK IS ADVISED.
THESE SHOULD HAVE A FULL FACE PEICE & BE OPERATED IN POSITIVE PRESS
Ventilation:MAINTAIN SUFFICIENT MECHANICAL VENT TO KEEP CONCENTRATION
BELOW TLV.
Other Protective Equipment:BOOTS & APRON MADE OF SOLV RESISTANT MATL
(E.G. NEOPRENE, VITON, ETC.). PROTECTIVE SUIT NOT NORMALLY REQD.
Work Hygienic Practices:WASH HANDS & FACE W/SOAP & WATER BEFORE
SMOKING/EATING. IMMED REMOVE ALL CONTAMD CLTHG. LAUNDER SEPARATELY
Supplemental Safety and Health
SPONT, KEEP HEAD BELOW HIP LEV TO REDUCE POSSIBILITY OF ASPIR
PNEUM. IF VICTIM IS CONSCIOUS, DILUTE BY GIVING LG VOLUMES OF MILK
/WATER. OBTAIN IMMED MED ATTN. NEVER ATTEMPT TO INDUCE VOMIT/GIVE
ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SOLVENT NAPHTHA; (HEAVY AROMATIC NAPHTHA)
ACGIH TLV:N/K
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:AMMONIUM HYDROXIDE (SARA III)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:1-HEXYN-3-OL; (HEXYNOL)
OSHA PEL:N/K
ACGIH TLV:N/K
COMPOSITION)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SPILL RELEASE:PLACE IN DOT-APPRVD DRUMS FOR DISP. WASH AREA
W/WATER. COLLECT WASHINGS & PLACE IN DOT-APPRVD DRUMS(ING 7)
Ingred Name:ING 6:FOR DISP. KEEP CONC & WASH WATER FROM ENTERING
SEWERS/WATERWAYS. USE SOLUTION:AS FOR CONCENTRATE, IF APPLIC.
Ingred Name:WASTE DISP METH:SOLN & RINSES CAN BE NEUTRALIZED, &
FLOATABLE SOIL & SEPARATED SOLV SKIMMED OFF. RESIDUAL ORG (ING 9)
Ingred Name:ING 8:MATTER MAY BE REMOVED BY OXIDATION AND/OR CARBON
Ingred Name:ING 9:LOCAL REGULATIONS PERMIT. DISPOSE OF I/A/W FED, STATE
& LOCAL REGULATIONS .
Ingred Name:VENT:NIOSH/MSHA FULL FACE MASK W/CARTRIDGE OR CANISTER
Ingred Name:HYGIENE PRACT:BEFORE REUSE. DISCARD SHOES THAT BECOME
CONTAMINATED ON THE INTERIOR.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:MAY CAUSE MODERATE TO
SEVERE IRRIT. SKIN:MAY CAUSE MODERATE TO SEVERE IRRIT, DRYING,
DEFATTING. INHAL:VAPORS:MOD IRRIT, DIZZINESS, HDCH. MISTS:SEVERE
RESP IRRIT, NAUS. INGEST:MOD TO SEVERE IRRIT OF GI TRACT, NAUSEA.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NO KNOWN CHRONIC EFFECTS THAT
DIFFER FROM ACUTE EFFECTS.
* First Aid Measures *
IRRIT PERSISTS, OBTAIN MED ATTN. SKIN:FLUSH AFFECTED AREA W/LG
VOLUMES OF WATER. WASH W/SOAP & WATER. RINSE THORO. IF IRRIT IS
EVIDENT/BLISTERI NG OCCURS, OBTAIN MED ATTN. INHAL:REMOVE TO FRESH
AIR. IF BRTHG IS DFCLT, ADMIN OXYG. IF BRTHG HAS STOPPED, APPLY
ARTF RESP. OBTAIN MED ATTN. INGEST:DO NOT INDUCE VOMIT EXCEPT ON
ADVICE OF (SUPDAT)
* Fire Fighting Measures *
Flash Point Method:TCC
Flash Point:NONE TO BOIL
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:CONCENTRATE. CONTAIN SPILLAGE. STOP LEAK @
SOURCE IF THIS CAN BE DONE SAFELY. VENTILATE AREA. NONESSENTIAL
PERS SHOULD LEAVE AREA UNTIL CLEANUP IS COMPLETED. PUMP LIQ INTO
DOT-APPRVD DRUMS FOR DISP. A BSORB REMAINING LIQ ONTO INERT ABSORB
&(ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY PROT AREA AWAY FROM
STRONG OXIDIZING AGENTS. MIXING:USE CARE TO AVOID SPLASHING. USE
APPROP PROT EQUP.
Other Precautions:REPAIR & MAINTENANCE OF CONTAMD EQUIP:RELIEVE ANY
PRESS. COVER OPENINGS TO AVOID SPURTING. CLEAN EXTERIOR & INTERIOR
BY FLUSHING W/WATER. COLLECT FLUSHINGS FOR DISP. USE PROT EQUIP FOR
EYES, SKIN AND INHALATION.
* Physical/Chemical Properties *
HCC:B3
Vapor Density:>1
Evaporation Rate & Reference:<1 (BUAC=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:LIGHT BLUE EMULSION, AMMONIACAL ODOR
Percent Volatiles by Volume:SUPDAT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, DIOXIDE AND OTHER TOXIC VOLATILE ORGANIC
COMPOUNDS.
* Disposal Considerations *
Waste Disposal Methods:CONCENTRATE:(1)TRANSFER TO RECLAIMING CENTER FOR
RECYCLING/REUSE, IF POSS. (2)TRANSFER TO LICENSED WASTE
TREATMENT/DISP SITE FOR DISPOSITION UNDER APPLIC LOC, ST & REGIONAL
REGS. SPENT SOLN & RINSES:DISPOSE PER (1) OR (2) ABOVE, OR SPENT
(ING 8)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC
VAPOR IF ABOVE PEL/TLV OR SCBA IN CASE OF LARGE SPILL OR CONFINED
AREA.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV.
Other Protective Equipment:APRON,EYE-WASH FACILITIES.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN;DO NOT BREATHE
VAPOR/MIST IF ABOVE PEL/TLV.WASH THOROUGHLY AFTER EACH USE.
Supplemental Safety and Health
* Product Identification *
Product ID:FREON TMC CLEANING AGENT
Preparer's Name:K.P. BROWN
* Composition/Information on Ingredients *
III)
Ozone Depleting Chemical:1
Ingred Name:METHYLENE CHLORIDE(SARA III)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES AND
SKIN;INHALATION MAY CAUSE HEATH IRREGULARITIES,UNCONSCIOUSNESS OR
DEATH;MISUSE CAN BE FATAL;CNS EFFECTS LIKE
HEADACHE,DIZZINESS,CONFUSION,INC-ORDINATION;VAPOR MAY REDUCE A
VAILABLE OXYGEN/BLOOD OXYGEN CARRYING CAPACITY DUE TO METHYLENE
CHLORIDE.
Explanation of Carcinogenicity:LISTED BY IARC AND ACGIH AS SUSPECTED
CARCINOGEN TO ANIMALS OR HUMAN.
Effects of Overexposure:SEE HEALTH HAZARDS DATA.
Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS MAY BE
WORSEN.
* First Aid Measures *
First Aid:INHALATION:REMOVE TO FRESH AIR;CPR OR OXYGEN IF NEEDED;CALL A
PHYSICIAN IMMEDIATELY. EYES & SKIN:FLUSH WITH PLENTY OF WATER FOR
VOMITING;C ALL A PHYSICIAN IMMEDIATELY.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE ANY SUITABLE MEDIA FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA IN AN ENCLOSED
Unusual Fire/Explosion Hazard:USE WATER SPRAY OR FOG TO COOL
CONTAINERS;DRUMS MAY RUPTURE UNDER FIRE CONDITIONS;DECOMPOSITION
MAY OCCUR.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTTION;REMOVE ALL
IGNITION SOURCES;CONTAIN FREE LIQUID IF POSSIBLE;USE SUITABLE INERT
ABSORBENT MATERIAL AD RECOVER FOR PROPER DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLEAN,DRY AREA;DO NOT HEAT
* Physical/Chemical Properties *
HCC:T4
Vapor Density:4.7 (AIR=1
pH:NEUTRL
Appearance and Odor:CLEAR LIQUID,COLORLESS,SLIGHT ETHEREAL .
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS;AL,ZNC,BE ETC IN POWERED FORM.
Stability Condition to Avoid:OPEN FLAME AND HIGH TEMPERATURE.
Hazardous Decomposition Products:HCL,HF AND POSSIBLY CARBONYL HALIDES.
* Disposal Considerations *
Waste Disposal Methods:CONSULT LOCAL AUTHORITIES;DISPOSAL MUST BE IN
ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRABLE FUME
RESPIRATORY OR AIR SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED
SPACE OR WHERE LOCAL EXHST/VENT DOES NOT KEEP EXPOS BELOW
RECOMMENDED EXPOSURE LIMIT.
Ventilation:USE ENOUGH VENT, LOCAL EXHST AT ARC, OR BOTH, TO KEEP FUMES
& GASES FROM WORKER'S BRTHG ZONE & GEN AREA. TRAIN (SUP DAT)
Other Protective Equipment:HAND, HEAD AND BODY PROT WHICH HELP PVNT INJ
FROM RADIA, SPARKS, & ELEC SHOCK. ARM PROT, APRONS, HATS,
SHOULDER(SUP DAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VENT: WELDER TO KEEP HEAD OUT OF FUMES. OTHER PROT EQUIP: PROT, AS WELL
AS DARK SUBSTANTIAL CLTHG. TRAIN WELDER NOT TO TOUCH LIVE ELEC
PARTS & TO INSULATE HIMSELF FROM WORK & GROUND. EYE PROT: FILTER
LENS. PROVIDE PROT SCREENS & FLASH GOG,IF NEC, TO SHIELD OTHERS. AS
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SUPP DATA: DARK TO SEE WELD ZONE. THEN GO THE NEXT LIGHTER
SHADE WHICH GIVES SUFFICIENT VIEW OF WELD ZONE.
Ingred Name:IRON
Ingred Name:MANGANESE (SARA III)
Fraction by Wt: 0.5-2.0%
OSHA PEL:(C) 5 MG/M3 DUST
Ingred Name:SILICON
Fraction by Wt: 0.1-1%
Ingred Name:CHROMIUM (SARA III)
Fraction by Wt: 0-3.5%
OSHA PEL:1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:MOLYBDENUM
Fraction by Wt: 0-1.0%
Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
Ingred Name:FLUORSPAR; (CALCIUM FLUORIDE)
OSHA PEL:2.5 MG/M3 AS F
ACGIH TLV:2.5 MG/M3 AS F
Ingred Name:POTASSIUM TITANATE
Fraction by Wt: 0-2%
Ingred Name:FELDSPAR
Fraction by Wt: 0-2%
ACGIH TLV:2 MG/M3 (MFR)
Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS
FORMS) (SARA III)
Fraction by Wt: 0-1%
Ingred Name:SILICON DIOXIDE
Fraction by Wt: 0-2%
OSHA PEL:5 MG/M3 (MFR)
ACGIH TLV:3 MG/M3 (MFR)
Ingred Name:TITANIUM DIOXIDE
Fraction by Wt: 0-3%
Ingred Name:POTASSIUM SILICATE
Fraction by Wt: 0-3%
ACGIH TLV:5 MG/M3 (MFR)
Ingred Name:SODIUM SILICATE
Fraction by Wt: 0-5%
ACGIH TLV:5 MG/M3 (MFR)
Ingred Name:SODIUM FLUOALUMINATE; (CRYOLITE)
Fraction by Wt: 0-2%
OSHA PEL:2.5 MG/M3 AS F
ACGIH TLV:2.5 MG/M3 AS F
Ingred Name:MAGNESITE
Fraction by Wt: 0-2%
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
Fraction by Wt: 0-.5%
OSHA PEL:C, 2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SHORT TERM OVEREXPOS TO WELDING FUMES
MAY RSLT IN DISCOMFORT SUCH AS: DIZZ, NAUS/DRYNESS/IRRIT OF NOSE,
THROAT/EYES, TIGHTNESS IN CHEST, FEVER AND ALLERGIC REACTIONS. LONG
TERM OVEREXPOSURE TO WELDING FUMES MAY LEAD TO SIDEROSIS (IRON
DEPOSIT IN LUNGS) AND IS BELIEVED BY SOME INVESTIGATORS TO (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM & CERTAIN CR CMPDS: IARC GROUP
1, ACGIH GROUP A1, NTP KNOWN HUMAN CARCINOGEN.
Effects of Overexposure:HLTH HAZ: AFFECT PULMONARY FUNCTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY AMERICAN RED
CROSS. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION.
INGEST: CALL MD IMMEDIATELY . SKIN: FLUSH W/COPIOUS AMOUNTS OF
MINUTES. SEE MD .
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE
COMBUSTIBLES AND FLAMMABLES. REFER TO AMERICAN NATIONAL STANDARD
* Accidental Release Measures *
Spill Release Procedures:NOT APPLICABLE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:USE EXHAUST SYSTEM TO CLEAR WELDING FUMES. MAKE SURE
THAT INHALED AIR DOES NOT CONTAIN FUME CONSTITUENTS ABOVE
PERMISSIBLE EXPOSURE LEVELS.
* Physical/Chemical Properties *
Evaporation Rate & Reference:NOT APPLICABLE.
Solubility in Water:NOT APPLICABLE.
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE; UNLESS OTHERWISE SPECIFIED.
Hazardous Decomposition Products:SEE ORIGINAL MSDS .
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT RESIDUE, DISPOSABLE CONTAINER OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Kit Part: Y
*
Preparer Co. when other than Responsible Party Co.
*
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
Other REC Limits: 4 MG/CUM
OSHA PEL: 1 PPM (SKIN)
ACGIH TLV: 1 PPM (SKIN)
------------------------------
------------------------------
------------------------------
% Wt: <6
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SKIN/EYES: IRRITATION. INHALATION: PULMONARY EFFECTS.
INGESTION: MODERATELY TOXIC.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: SKIN: SENSITIZATION & DERMATITIS.
First Aid: INGESTION: DON'T INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
*
Handling and Disposal
*
Spill Release Procedures: SCRAPE UP RESIDUE W/ABSORBENT MATERIAL & STORE IN
CLOSED CONTAINER UNTIL DISPOSAL.
Waste Disposal Methods: LANDFILL OR INCINERATE IN ACCORDANCE W/LOCAL, STATE,
& FEDERAL REGULATIONS.
Handling And Storage Precautions: STORE IN COOL, DRY AREA. AVOID SKIN & EYE
CONTACT.
*
Fire and Explosion Hazard Information
*
Flash Point Method: OC
Extinguishing Media: CO2, DRY CHEMICAL, FOAM.
*
*
Ventilation: NONE NORMALY NEEDED IF GOOD CROSS VENTILATION IS MAINTAINED
*
Physical/Chemical Properties
*
Solubility in Water: INSOLUBLE
Appearance and Odor: BEIGE; SULFUR ODOR
*
Reactivity Data
*
Stability Indicator: YES
Materials To Avoid: OXIDIZING AGENTS
Hazardous Decomposition Products: CO, CO2
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: LOCTITE CORP AUTOMOTIVE AND CONSUMER GROUP
Label Required IND: Y
Status Code: C
Origination Code: G
Hazard And Precautions: SKIN/EYES: IRRITATION. INHALATION: PULMONARY EFFECTS.
INGESTION: MODERATELY TOXIC.
SKIN: SENSITIZATION & DERMATITIS.
*
| 1 | eyes_protection_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INHAL MAY BE IRRIT TO MUC MEMB & CAN LEAD TO CNS
DEPRESS W/EFTS OF HDCH, DIZZ & NAUS & LOSS OF CONSCIOUSNESS. EYE
IRRITANT, & DEFATS SKIN WHICH CAN LEAD TO IRRIT. INGEST MAY RSLT IN
VOMIT; ASPIRMAY CAUSE CHEM PNEUM. CHRONIC:MARKED IRRIT OF SKIN & EYES
UPON CHRONIC OVEREXP. POSS INFECTION RSLTG (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:FROM IRRIT. RPTD LONG TERM
OVEREXP TO XYLENE CAN DMG LIVER, KIDNEYS, NERV SYS. TARGET ORGANS:CNS,
KIDNEYS, LIVER. LIFETIME SKIN PAINTING STUDIES CONDUCTED BY AMERICAN PETRO
INSTITUTE, & OTHER S HAVE SHOWN THAT SIMILAR DISTILLATES PRODS MAY PRDCE
SKIN TUMORS &/OR SKIN CANCER IN LAB MICE. DEGREE OF
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE TO FRESH AIR. SEEK MED ATTN IF RESP IRRIT DEVELOPS/IF
BRTHG IS DFCLT. EYE:IMMED RINSE W/WATER. REMOVE ANY CONT LENSES &
ENTIRE SURF OF EYES & LIDS W/WATER. GET IMMED MED ATTN. SKIN:WASH
AFFECTED AREA W/PLENTY OF SOAP & WATER FOR SEVERAL MINS. SEEK MED ATTN IF
IRRIT DEVELOPS. INGEST:GIVE 3-4 GLASSES (SUPDAT)
*
Handling and Disposal
*
Spill Release Procedures: ELIM ALL SOURCES OF IGNIT. SM SPILLS:TAKE UP W/ABSORB
& PLACE IN LBLD CNTNR FOR DISP. LG SPILLS:EVAC AREA OF UNPROTECTED PERS.
STOP LEAK & CNTN SPILL. REMOVE VIA VACUUM TRUCKS. TAKE UP REMAINDER W/ABS
ORB & PLACE IN LBLD CNTNR FOR DISP. DO
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL STATE, FEDERAL AND
LOCAL REGULATIONS.
FROM IGNIT SOURCES. STORE @ MOD TEMPS. KEEP OUT OF REACH OF CHILDREN. READ
ENTIRE LBL BEFORE USING PROD.
Other Precautions: IF UE (USE EMEXPTION) APPEARS UNDER UPPER % LIM, END USERS
ARE EXEMPT FROM NOTIFICATION BECAUSE PROD IS USED & LBLD FOR ROUTINE
JANITORIAL WORK/PROD IS USED & LBLD FOR FACILITY GROUNDS MAINTENANCE (SU
CH AS FERTILIZERS &
*
Fire and Explosion Hazard Information
*
Flash Point Method: TCC
Extinguishing Media: FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures: NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). EVACUTE UNPROTECTED PERSONNEL. COOL FIRE-EXPOSED CONTAINERS
WITH WATER.
Unusual Fire/Explosion Hazard: VAPS ARE HVR/AIR & MAY ACCUM IN LOW
AREAS/AREAS INADEQUATELY VENTILATED. VAPS MAY ALSO TRAVEL ALONG GROUND TO BE
IGNITED @ LOCATIONS DISTANT FROM HNDLG SITE.
*
*
Respiratory Protection: TYPICAL USE DOES NOT REQUIRE RESPIRATORS. IF HANDLED IN
CONFINED POORLY VENTILATED AREAS USE A NIOSH/MSHA APPROVED SOLVENT RESPIRATOR
OR NIOSH/MSHA APPROVED SUPPLIED DEVICE.
Ventilation: TYPICAL USE OF PROD DOES NOT REQUIRE SPEC VENT. SUPPLY MECHANICAL
EXHAUST IS HANDLED IN CONFINED AREA.
Other Protective Equipment: ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER (FP
N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). FIRST AID PROC:OF WATER, BUT DO NOT INDUCE
VOMIT. IF VOMIT OCCURS, GIVE FLUIDS AGAIN. GET IMMED MED ATTN. DO NOT GIVE AN
YTHING BY MOUTH TO UNCON/CONVULSING PERSON. NOTES TO PHYS:IF LG AMT HAS BEEN
INGEST & VOMIT HAS NOT OCCURRED,
*
Physical/Chemical Properties
*
Vapor Pres: 0.4
Solubility in Water: SLIGHT
Appearance and Odor: OPAQUE RED, SHARP SOLVENT ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXTREME TEMPERATURES.
Materials To Avoid: OPEN FLAME, STRONG OXIDIZERS.
Hazardous Decomposition Products: CARBON MONOXIDE, NITROGEN COMPOUNDS, AND
SMOKE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: NCH CORP/ MANTEK DIV
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE:INHALATION MAY BE IRRITATING TO
MUCOUS MEMBRANE & CAN LEAD TO CENTRAL NERVOUS SYSTEM DEPRESSION WITH
EFFECTS OF HEADACHE, DIZZINESS & NAUSEA & LOSS OF CONSCIOUSNESS. EYE
IRRITANT, & DEFATS SKIN WHICH CAN LEAD TO IRRITATION. INGESTION MAY
RESULT IN VOMITING; ASPIRATION MAY CAUSE CHEMICAL PNEUMONITIS. CHRONIC:MARKED
IRRITATION OF SKIN & EYES UPON CHRONIC OVEREXPOSURE. POSSIBLE INF ECTION
RESULTING FROM IRRITATION. MAY DAMAGE LIVER, KIDNEYS AND NERVOUS
SYSTEM.TARGET ORGANS:KIDNEYS, LIVER.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:ANY SUPPLIED AIR RESPIRATOR W/FULL FACEPIECE &
IS OPERATED IN A PRESSURE/POSITIVE DEMAND MODE. DUST & MIST
RESPIRATOR.
Ventilation:LOCAL EXHAUST/GENERAL DILUTION TO MEET EXPOSURE LIMITS.
Other Protective Equipment:NOT REQUIRED
Supplemental Safety and Health
HLTH HZD CONT'D: INGESTION: MAINTAIN AIRWAY/BLOOD PRESSURE &
RESPIRATION. IF VOMITING OCCURS, KEEP HEAD LOWER THAN HIPS TO
PREVENT ASPIRATION. DON'T GIVE ANYTHING BY MOUTH/INDUCE VOMITING IF
CONSCIOUS . INDUCE EMESIS. PERFORM GASTRIC LAVAGE. RINSE MOUTH
W/WATER, GIVE MILK/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Product Identification *
Product ID:DOPAMINE HYDROCHLORIDE INJECTION
* Composition/Information on Ingredients *
Fraction by Wt: 4-8%
Ingred Name:SODIUM BISULFITE
Fraction by Wt: 1%
ACGIH TLV:5 MG/CUM
Ingred Name:WATER
Fraction by Wt: >1%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION/SKIN: MAY CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. KEEP
WARM & QUIET. TREAT SYMPTOMATICALLY & SUPPORTIVELY. SKIN: WASH
EYES: WASH IMMED IATELY W/LARGE AMOUNTS OF WATER/NORMAL SALINE FOR
MAINTAIN AIRWAY, BLOOD PRESSURE & RESPIRATION. (SEE SUPP)
* Fire Fighting Measures *
Extinguishing Media:USE APPROPRIATE MEDIA FOR SURROUNDING FIRE.
Fire Fighting Procedures:MOVE CONTAINER FROM FIRE AREA IF POSSIBLE.
AVOID BREATHING VAPORS/DUSTS; KEEP UPWIND. ANY SUPPLIED AIR
RESPIRATOR W/FULL FACEPIECE & A SCBA IN PRESSURE MODE.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT/FLAME.
* Accidental Release Measures *
Spill Release Procedures:SOAK UP W/VERMICULITE/OTHER ABSORBENT MATERIAL
& PLACE INTO SUITABLE CONTAINERS FOR LATER DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
SUBSTANCES.
* Physical/Chemical Properties *
pH:2.5-5
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS SOLUTION
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, BASES, OXIDIZERS
Stability Condition to Avoid:TEMPS, PRESSURES.
Hazardous Decomposition Products:TOXIC &/HAZARDOUS GASES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR PROPERLY FITTED NIOSH/MSHA APPRVD SCBA OR
INDUSTRIAL TYPE CANISTER MASK IN ENCLOSED AREAS W/POOR/NO VENT SYS.
IF AIR CONTAM SUSPECTED, CONTAM SHOULD BE VERIFIED BY AIR
MONITORING BEFORE SELECTION OF RESPIRATOR PROT EQUP IS MADE.
Ventilation:LOCAL EXHAUST:PREFERRED. MECHANICAL:ACCEPTABLE.
Other Protective Equipment:HYDROCARBON INSOLUBLE APRONS, EYE WASH &
SAFETY SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SHOULD BE WORN WHEN WORKING WITH LOW VISCOSITY MATERIALS.
* Product Identification *
Preparer's Name:RICHARD HALL
* Composition/Information on Ingredients *
Ingred Name:METHYL HEXAHYDROPHTHALIC ANHYDRIDE
Ingred Name:7-OXABICYCLO(4.1.0)HEPTANE-3-CARBOXYLIC ACID,
7-OXABICYCLO(4.1.0)HEPT-3-YLMETHYL ESTER (CYCLOALIPHATIC EPOXY
RESIN)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ING 1:EYES:LIQUID CAUSES BURNS.
SKIN:MAY CAUSE MILD IRRITATION. INHAL:FUMES DEVELOP AT HIGH
TEMPERATURES WHICH MAY CAUSE IRRITATION & CHOKING. ING
2:EYES/SKIN:MAY CAUSE SLIGHT IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:ING 1:EYE:FLUSH W/COPIOUS AMTS OF LUKEWARM WATER FOR AT LEAST
THORO W/SOAP/WATER. INGEST:CALL MD. ING 2:EYE:FLUSH W/WATER FOR AT
INHAL:REMOVE TO FRESH AIR. INGEST:GIVE 2 GLASSES OF WATER & INDUCE
VOMIT BY PUTTING FINGER DOWN THROAT.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICALS, FOAM, WATER SPRAY OR
FOG.
Fire Fighting Procedures:PERSONNEL ENGAGED IN FIGHTING FIRES SHOULD
WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT ESTABLISHED.
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES. PROVIDE ADEQUATE
VENTILATION. COVER SPILL W/ABSORBENT MATERIAL & REMOVE TO WASTE
CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS IN COOL,
DRY AREA AWAY FROM HEAT. USE ONLY W/ADEQUATE VENTILATION. STORE AT
Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS OR
CONTACT W/SKIN.
* Physical/Chemical Properties *
HCC:N1
Vapor Pres:<0.1
Solubility in Water:SLIGHT.
Appearance and Odor:BLACK MEDIUM VISCOSITY LIQUID W/MILD CHARACTERISTIC
ODOR.
Percent Volatiles by Volume:0%
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTAMINATION W/ALKALIES, ACIDS, AMINE, WATER & STRONG OXIDIZING
AGENTS.
Stability Condition to Avoid:NOT ESTABLISHED.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE CO &
CO*2.
Conditions to Avoid Polymerization:ACIDS.
* Disposal Considerations *
Waste Disposal Methods:SHOULD BE I/A/W FEDERAL, STATE & LOCAL
ENVIRONMENTAL CONTROL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Kit Part: Y
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
NAPHTHENIC; (PETRO ELEC INSULATING OIL)
% Wt: 5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INHALATION:TEMPORARY IRRITATION TO MUCOUS MEMBRANES
OF NOSE & MOUTH MAY RESULT FROM EXCESSIVE DUST. EYES:MAY CAUSE
IRRITATION. SKIN:REPEATED SKIN EXPOSURE MAY CAUSE ALLERGIC CONTACT
DERMATITIS. MAY BE ABSORBED THROUGH SKIN & MAY TEMPORARILY REDUCE THE
OXYGEN TRANSFORMABILITY OF THE BLOOD. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:CHRONIC:REPEATED SKIN EXPOSURE
MAY CAUSE ALLERGIC CONTACT DERMATITIS. A NATIONAL CANCER INSTITUTE (NCI)
REPORT IDENTIFIED P-QUINONE DIOXIME AS AN "ANIMAL POSITIVE" CARCINOGEN. IARC
DOWNGRADED THIS CONCLUSION BY IDENTIFYING P-QUINONE DIOXIME AS ONLY AN
"ANIMAL SUSPECTED" CARCINOGEN.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST:CALL MD IMMED (FP N). INHAL:REMOVE TO FRESH AIR. GIVE OXYGEN
IF BRTHG IS DFCLT. OBTAIN IMMED MED ATTN. EYES:FLUSH THORO W/WATER FOR @
SKIN:PROMPTLY WASH THORO W/MILDSOAP & WATER. REMOVE CONTAMD CLTHG.
CONSULT MD IF IRRIT PERSISTS. IMMED REMOVE CONTAMD CLTHG/SHOES. WIPE EXCESS
FROM SKIN & FLUSH W/PLENTY WATER FOR @ (SUPDAT)
*
Handling and Disposal
*
Spill Release Procedures: AVOID ALL PERSONAL CONTACT. CONTAIN SPILL IF
POSSIBLE. WIPE UP OR ABSORB ON SUITABLE MATERIAL AND SHOVEL UP. CLEAN UP WITH
SUITABLE VENTILATION.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: CONTROLLED INCINERATION OR BURY IN LEGAL LANDFILL.
HANDLE IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL PROTECTION
AGENCY REGULATIONS.
Handling And Storage Precautions: NONE SPECIFIED BY MANUFACTURER.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
*
*
Respiratory Protection: IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL/VENTILATION,
WEAR RESPIRATOR APPROVED BY NIOSH/MSHA WNENEVER EXPOSED TO FUMES/VAPORS.
ATHING APPARATUS IN HIGH CONCENTRATIONS.
Ventilation: LOCAL EXHAUST RECOMMENDED.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
OR FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE CLTHG UNTIL THORO
CLEANED. GET MED ATTN. CONTAMD LEATHER ARTICLES, INCLUDING SHOES, CANNOT BE
DECONTAMI NATED & SHOULD BE DESTROYED.
*
Physical/Chemical Properties
*
HCC: N1
B.P. Text: NONE
Evaporation Rate & Reference: 0.0 X N-BUTYL ACETATE
Appearance and Odor: LIQUID
Percent Volatiles by Volume: 0.4
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES, OPEN FLAME, SPARKS.
Materials To Avoid: OXIDIZING AGENTS.
Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE, NITROGEN
OXIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: HARDMAN INC
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHALATION:TEMPORARY IRRITATION TO MUCOUS
MEMBRANES OF NOSE AND MOUTH MAY RESULT FROM EXCESSIVE DUST. EYES:MAY CAUSE
IRRITATION. SKIN:REPEATED SKIN EXPOSURE MAY CAUSE ALLERGIC CONTACT DERMATITI
S. MAY BE ABSORBED THROUGH SKIN AND MAYTEMPORARILY REDUCE THE OXYGEN
TRANSFORMABILITY OF THE BLOOD. CHRONIC: REPEATED SKIN EXPOSURE MAY CAUSE
ALLERGIC CONTACT DERMATITIS.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AVOID EXCESSIVE INHALATION, PROVIDE VENTILATED
AREAS.
Ventilation:GENERAL ROOM VENTILATION.
Other Protective Equipment:RUBBER SHOES & APRONS
Work Hygienic Practices:MFR GAVE NO INFORMATION ON MSDS.
Supplemental Safety and Health
* Product Identification *
Product ID:CORROSION REMOVING COMPOUND
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
Ingred Name:GLYCOL ETHER EB OR 2-BUTOXYETHANOL
Other REC Limits:NONE RECOMMENDED
Ingred Name:OCTYLPHENOXYPOLYETHANOL
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:FIRST DEGREE BURNS.
Explanation of Carcinogenicity:NONE KNOWN
Effects of Overexposure:BURNING SENSATION WHEN EXPOSED TO SKIN. OVER
INHALATION DIZZY FEELING.
Medical Cond Aggravated by Exposure:NONE KNOWN
* First Aid Measures *
First Aid:NEUTRALIZE W/WATE, FLUSH EXPOSED AREAS W/ LOTS OF WATER, CALL
DOCTOR.
* Fire Fighting Measures *
Flash Point Method:OC
Lower Limits:0
Upper Limits:0
Extinguishing Media:NOT FLAMABLE
Fire Fighting Procedures:NOT NEEDED
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE CLOTHING, DILUTE W/LOTS OF
WATER.
Neutralizing Agent:WATER & LIMESTONE SODA
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM HEAT & STRONG
ALKALIES.
Other Precautions:NOT KNOWN
* Physical/Chemical Properties *
HCC:C1
NRC/State Lic Num:NONE
Evaporation Rate & Reference:BUTYL ACETATE=1
Solubility in Water:COMPLETE
Appearance and Odor:WATER WHITE
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS WITH ALKALIES PRODUCING HEAT, WITH MANY METALS PRODUCING HEAT &
FLAMMABLE HYDROGEN GAS.
Stability Condition to Avoid:AVOID DIRECT CONTACT WITH SKIN & EYES.
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:FLUSH TO RETENTION AREA, NEUTRALIZE W/LIMESTONE,
CAUSTIC SODA BEFORE DISCHARGE TO SEWER.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY REQUIRED
Ventilation:GENERAL VENTILATION. SOURCE POINT EXHAUST
Supplemental Safety and Health
* Product Identification *
Product ID:HANDY SPRAY INK
* Composition/Information on Ingredients *
Ingred Name:TOLUENE
Ingred Name:ACETONE
Ingred Name:XYLENE
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:PROPANE
Ingred Name:BUTANE
Minumum % Wt:3.
Maxumum % Wt:7.
Ingred Name:ISOBUTANE
Minumum % Wt:3.
Maxumum % Wt:7.
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE ANESTHETIC
IRRITATION OF RESPIRATORY TRACT AND ACUTE NSD DEPRESSION SUCH AS
HEADACHE, DIZZINESS, POSSIABLE UNCONSIOUSNESS AND ASPHYXIATION. EYE
CONTACT: MAY CAUSE SEVERE IRRITATI ON, REDNESS,TEARING, BLURRED
VISION. SKIN CONTACT: MAY CAUSE PRIMARY IRRITATION, DEFATTING OF
THE SKIN AND DERMITITIS. INGESTION: MATERIAL MAY ASPIRATE INTO
LUNGS CAUSING CHEMICAL PNEUMONIA AND PULMON ARY EDEMA. OVEREXPOSURE
HAS CAUSED LIVER ABNORMALITIES, KIDNEY, EYE, NASAL BRAIN AND LUNG
DAMAGE IN LABORATORY ANIMALS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
CALL A PHYSICIAN IMMEDIATELY. EYE CONTACT: IMMEDIATELY FLUSH EYES
WITH PLENTY OF WATER. CALL A PHYSICIAN IF IRRITATION PERSISTS.
SKIN CONTACT: WASH WITH SOAP AND WATER. INGESTION: DO NOT INDUCE
VOMITING. CALL A PHYSICIAN IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.8
Upper Limits:9.5
Extinguishing Media:ALCOHOL FOAM, DRY CHEMICAL, CO2
FLAMMABLE CONTENTS. USE WATER SPRAY TO COOL CONTAINERS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES AND VVENTILATE
AREA. ALLOW PROPELLANT TO ESCAPE, ABSORB SPILLED MATERIAL AND PLACE
INA CONTAINER FOR DISPOSAL IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS.
*Handling and Storage *
Handling and Storage Precautions:DO NOT PUNCTURE OR INCINERATE CANS.
SINCE WMPTIED CANS CONTAIN HAZARDOUS RESIDUES, OBSERVE ALL
QUANITIES SHOULD BE KEPT IN AREA DESIG NED FOR NFPA CLASS 1A
FLAMMABLE LIQUIDS.
Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING THE CONTENTS MAY BE HARMFUL OR FATAL.
* Physical/Chemical Properties *
Vapor Density:>1
VOC Grams/Liter:6.5
Appearance and Odor:COLORED LIQUID IN ARESOL CAN SHARP ODOR
* Stability and Reactivity Data *
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:CO, CO2, HYSROCARBON COMBUSTION
PRODUCTS.
* Ecological Information *
Ecological:AVOID CONTAMINATION OF NATURAL WATERWAYS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE
AND LOCAL LAWS.
* Regulatory Information *
State Regulatory Information:THIS PRODUCT CONTAINS A CHEMICAL KNOWN TO
THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . LAB
COAT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
MM TRIS(HYDROXYMETHYL)-AMINOMETHANE AND HYDROCHLORIC ACID.
TRIS(HYDROXYMETHYL)-AMINOMETHANE AND HYDROCHLORIC ACID.
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY BE HARMFUL BY
INHALATION. EYE/SKIN CONTACT: MAY CAUSE IRRITATION. INGESTION: MAY
BE HARMFUL IF SWALLOWED. CHRONIC: NOT APPLICABLE.
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
WITH FINGERS. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS AMOUNTS
OF WATE R. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION:
WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD.
* Fire Fighting Measures *
Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
CONTAINERS FOR DISPOSAL. VENTIL ATE AREA AND WASH SPILL SITE AFTER
MATERIAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. STORE AT 4C
AFTER DISSOLVING RNASE. DO NOT GET IN EYES, ON SKIN, OR ON
CLOTHING.
Other Precautions:THE PRODUCT SHOULD BE HANDLED WITH THE NORMAL CAUTION
ACCORDED CHEMICALS. ADDITIONAL HARMFUL PROPERTIES CANNOT BE RULED
OUT.
* Physical/Chemical Properties *
pH:SEE INGREDIENTS
Appearance and Odor:COLORLESS LIQUID; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Hazardous Decomposition Products:TOXIC FUMES OF CARBON MONOXIDE AND
CARBON DIOXIDE.
* Toxicological Information*
Toxicological Information:NOT APPLICABLE.
* Ecological Information *
Ecological:NOT APPLICABLE.
* Disposal Considerations *
Waste Disposal Methods:FOR SMALL QUANTITIES FLUSH DOWN SINK WITH WATER.
OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS.
* MSDS Transport Information *
Transport Information:NOT APPLICABLE.
* Regulatory Information *
SARA Title III Information:NOT APPLICABLE.
Federal Regulatory Information:NOT APPLICABLE.
State Regulatory Information:NOT APPLICABLE.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:RESPIRATORY PROTECTION REQUIRED IF AIRBORNE
APPROVED SELF-CONTAINED BREATHING APPARATUS IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
CONTAMINATED WITH PRODUCT SHOULD BE DISCARDED.
Supplemental Safety and Health
EXPLO HAZ: HEAT MAY EXPLODE. TOXIC GASES PRODUCED: HYDROGEN CHLORIDE,
PHOSGENE, CHLORINE, CARBON MONOXIDE, CARBON DIOXIDE. MATL TO AVOID:
AMINES, PLASTICS, RUBBER, SODIUM, POTASSIUM. EXPLAN OF CARCIN:
GLAND (TUMORS).
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:EFTS OF OVEREXP: VOMITING, DIZZINESS, NARCOSIS, WEAKNESS,
FATIGUE, GI IRRIT, CNS DEPRESS, CAUSES METHEMOGLOBULIN (ING 3)
Ingred Name:ING 2: FORMATION IN THE BLOOD, UNCONSCIOUSNESS & MAY BE
FATAL. CHRONIC EFTS: DAMAGE TO LIVER, KIDNEYS, LUNGS, (ING 4)
Ingred Name:ING 3: BLOOD, CNS. TARGET ORGANS: RESP SYS, LUNGS, CVS,
CNS, LIVER, KIDNEYS, EYES, SKIN. TESTS ON LAB ANIMALS (ING 5)
Ingred Name:ING 4: INDICATE MATERIAL MAY BE MUTAGENIC.
Ingred Name:SPILL PROC: ALLOW SPILL TO ENTER DRAINS, SEWER SYSTEM OR
NATURAL WATER SUPPLIES.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIMILAR
EFT IN HUMANS. ADRENOMIMETICS (EG, EPINEPHRINE) MAY BE
CONTRA-INDICATED EXCEPT FOR LIFE-SUSTAININ G USES IN HUMANS
ACUTELY/CHRONICALLY EXPOS TO CHLOROCARBONS . INHAL: HDCH, NAUS,
VOMIT, DIZZ, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC MONOGRAPHS,
CARCINS,(SUPDAT)
Effects of Overexposure:HLTH HAZ: NARC, WEAK, FATG, IRRIT OF UPPER RESP
TRACT, CNS DEPRESS, CAUSES METHEMOGLOBULIN FORM IN BLOOD, PULM
EDEMA, UNCON & MAY BE FATAL. SKIN CNTCT: IRRIT, MAY BE HARMFUL,
PRLNGD CNTCT MAY CAUSE DE RM. EYE CNTCT: IRRIT, MAY CAUSE TEMPORARY
CORNEAL DMG. SKIN ABSORPTION: MAY BE HARMFUL. INGEST: HDCH, NAUS,
(ING 2)
Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISORDERS, HEART
DISORDERS, LIVER OR KIDNEY DISORDERS, CENTRAL NERVOUS SYSTEM
DISORDERS, HEAVY DRINKERS, HEAVY SMOKERS.
* First Aid Measures *
First Aid:INGEST: CALL MD. IF SWALLOWED, DO NOT INDUCE VOMIT. INHAL: IF
INHALED, REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYGEN. PROMPT ACTION IS ESSNTL. SKIN: IN CASE
WHILE REMOVING CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE REUSE.
EYES: IN CASE OF CONTACT, IMMED FLUSH W/PLENTY OF WATER FOR AT
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP . MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT
RISK. USE WATER TO KEEP FIRE-EXPOS CNTNRS COOL.
Unusual Fire/Explosion Hazard:CONCD VAP CAN BE IGNITED BY HIGH
INTENSITY IGNIT SOURCE. VAP MAY FORM FLAM MIX IN ATM THAT CONTAINS
A HIGH PERCENTAGE OF OXYGEN. CLSD CNTNRS EXPOSED TO (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT CLTHG. STOP
LEAK IF YOU CAN DO SO W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS.
TAKE UP W/SAND OR OTHER NON-COMBUST ABSORB MATL & PLACE INTO CNTNR
FOR LATER DISP. DO N OT FLUSH SPILL AREA W/WATER. DO NOT (ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN SECURE POISON AREA. KEEP CONTAINERS OUT OF SUN & AWAY FROM HEAT.
MATERIAL IS HYGROSCOPIC.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE .
* Physical/Chemical Properties *
Vapor Density:2.9
Appearance and Odor:CLEAR, COLORLESS LIQUID; CHLORINE-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALKALI METALS, STRONG OXIDIZING AGENTS, STRONG BASES, OXIDES OF
NITROGEN, ZINC, ALUMINUM, WATER, MAGNESIUM, (SUPDAT)
Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION,
MOISTURE, LIGHT.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE,
CARBON MONOXIDE, CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS. EPA HAZARDOUS
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED W/ADEQUATE VENTILATION
Ventilation:GENERAL EXHAUST
Other Protective Equipment:EYE WASH STATIONS, DELUGE SHOWERS, LAB COAT
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING. OBSERVE APPROPRIATE CHEMCIAL
HYGIENE.
Supplemental Safety and Health
SPIL PROC CONT'D: ONCE USED, PLACE CONTAMINATED DISPOSABLES INTO A
SUITABLE CONTAINER/SEAL/LABEL & HOLD FOR DISPOSAL.
* Product Identification *
Preparer's Name:MICHAEL A FAZIO
* Composition/Information on Ingredients *
Ingred Name:BORIC ACID, ORTHOBORIC ACID
Fraction by Wt: 4%
Ingred Name:GENTAMICIN SULFATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:BORIC ACID-IN A PURE FORM, MAY BE
HARMFUL BY ALL ROUTES OF ENTRY.ITS READILY ABSORBED BY THE SKIN,
CAN CAUSE CYANOSIS/IRRITATION. INGESTION: TOXIC. GENTAMINCIN
SULFATE-IN PURE FORM, IS A TERATOGEN WHI CH CAN CAUSE ALLERGIC SKIN
REACTIONS. MAY CAUSE DAMAGE TO KIDNEYS & IMPAIR THE ABILITY TO
HEAR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BORIC ACID-GASTROINTESTINAL DISTURBANCE,
STOMACH PAIN, VOMITING, DIARRHEA, SKIN DISCOLORATION. GENTAMICIN
SULFATE-HEADACHES.
Medical Cond Aggravated by Exposure:NONE
* First Aid Measures *
INGESTION: KEEP VICTIM WARM & CALM. INHALATION: REMOVE TO FRESH
AIR. GIVE OXYGEN/CPR IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Extinguishing Media:USE MEDIA SPECIFIC FOR SITE CONDITIONS.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE GARMENTS.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE. CLEAN UP W/EQUIPMENT. IF DRY, MOP
UP, PLACE IN SUITABLE CONTAINER, SEAL/LABEL/HOLD FOR DISPOSAL. IF
IN SOLUTION, USE AN ABSORBENT MATERIAL TO CONTAIN/PICK UP
SOLUTION.(SEE SUPP)
*Handling and Storage *
Other Precautions:AVOID CONTACT W/SKIN & EYES. DON'T MOUTH PIPETTE.
GOOD LABORATORY TECHNIQUE SHOULD BE USED WHEN HANDLING THIS
PRODUCT. DON'T EAT, DRINK/SMOKE WHILE WORKING W/REAGENTS.
* Physical/Chemical Properties *
Solubility in Water:REAGENT-COMPLETE
Appearance and Odor:CLEAR, COLORLESS SOLUTION
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:EXCESS HEAT, FLAME/PRESSURE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED. FOR DUST, FUME OR MIST, WEAR
NIOSH-APPROVED RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS.
Ventilation:ADEQUATE
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER, COVERALL
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
* Product Identification *
Product ID:DRY CHARGED BATTERY-NO ELECTROLYTE ADDED
CAGE:0ABZ3
CAGE:0ABZ3
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Fraction by Wt: 0.2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.5 MG/M3
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CALCIUM, METAL
Other REC Limits:NONE RECOMMENDED
Ingred Name:TIN
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
Ingred Name:CASE MATERIAL: INCLUDES INGREDIENTS 7 AND 8.
Fraction by Wt: 6 - 8%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POLYPROPYLENE
Fraction by Wt: SEE # 6%
Other REC Limits:NONE RECOMMENDED
Ingred Name:HARD RUBBER
Fraction by Wt: SEE # 6%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:NONE. ACUTE- PRODUCT IS
A DRY CHARGED BATTERY. NO HAZARD IS ANTICIPATED. HAZARDOUS EXPOSURE
CAN OCCUR WHEN PRODUCT IS IN FIRE/BROKEN: LEAD COMPOUNDS MAY CAUSE
EYE & RESPIRATORY IRRITATIO N. TOXIC IF INGESTED. CHRONIC- LEAD
COMPOUNDS MAY CAUSE ANEMIA, KIDNEY DAMAGE, NERVE DAMAGE (WRIST
DROP).
%.
Effects of Overexposure:NONE. IF IN FIRE OR BROKEN, DUST OR FUMES MAY
CAUSE: IRRITATION, ANEMIA, ABDOMINAL PAIN, NAUSEA, VOMITING,
CONSTIPATION, HEADACHE, FATIGUE, LOSS OF APPETITE, MUSCULAR ACHES
AND WEAKNESS, SLEEP DISTURB ANCES
Medical Cond Aggravated by Exposure:LEAD AND ITS COMPONENTS CAN
AGGRAVATE SOME FORMS OF KIDNEY, LIVER AND NEUROLOGIC DISEASES.
* First Aid Measures *
First Aid:INHALATION - LEAD: REMOVE FROM EXPOSURE, GARGLE, WASH NOSE
AND LIPS; CONSULT PHYSICIAN. INGESTION - LEAD: CONSULT PHYSICIAN
IMMEDIATELY. SKIN - LEAD: WASH IMMEDIATELY WITH SOAP AND WATER.
EYES - LEAD: FLUSH IMMEDIATELY WITH LARGE AMOUNT OFWATER FOR AT
* Fire Fighting Measures *
Flash Point:NOT RELEVANT
Lower Limits:4.1%HYDROGEN
Extinguishing Media:BATTERY CASE WILL BURN. USE CARBON DIOXIDE,
FOAM/DRY CHEMICAL EXTINGUISHER. WATER MAY CAUSE SPATTERING OF
MOLTEN LEAD.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:MOLTEN METALS PRODUCE FUMES, VAPORS
AND/OR DUST THAT MAY BE TOXIC AND/OR RESPIRATORY IRRITANTS.
* Accidental Release Measures *
Spill Release Procedures:IF BROKEN, LEAD DUST OR PARTICULATE SHOULD BE
VACUUMED (USING HEPA FILTER) OR WET-SWEPT. DO NOT DRY SWEEP OR USE
FORCED AIR. PLACE IN DRY, CLOSED CONTAINER FOR DISPOSAL OR
RECYCLING.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE BATTERIES IN COOL, DRY,
WELL-VENTILATED AREAS, UNDER THE ROOF. SEPARATE FROM INCOMPATIBLE
MATERIALS. KEEP AWAY FROM HEAT, SPARKS AND FIRE.
Other Precautions:WASH HANDS BEFORE EATING OR DRINKING. KEEP OUT OF
REACH OF CHILDREN. AVOID THE USE OF UNINSULATED TOOLS. DO NOT MAKE
A CONNECTION BETWEEN THE TWO BATTERY TERMINALS AS SEVERE SPARKING
MAY OCCUR WHICH C OULD RESULT IN AN EXPLOSION.
* Physical/Chemical Properties *
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Decomp Temp:Decomp Text:NOT KNOWN
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVANT
Appearance and Odor:PRODUCT IS A DRY CHARGED BATTERY.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
LEAD COMPOUNDS: STRONG ACIDS, STRONG ALKALIS, HALIDES, HALOGENATES,
POTASSIUM NITRATE, REDUCING AGENTS, WATER, PEROXIDES
Stability Condition to Avoid:PROLONGED OVERCHARGE, SOURCES OF IGNITION
Hazardous Decomposition Products:TOXIC METAL FUMES, VAPOR OR DUST,
TOXIC ARSINE GAS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. MATERIAL SHOULD BE RECYCLED AT A SECONDARY
LEAD SMELTER.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED
RESPIRATOR WHEN IN CONFINED SPACE, WHERE LOCAL EXHAUST/VENTILATION
DOES NOT KEEP EXPOSURE <TLV.
Ventilation:LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES <TLV IN WORKER'S
BREATHING ZONE & GENERAL AREA.
Other Protective Equipment:ARM PROTECTOR, APRON, HAT, SHOULDER
PROTECTION, DARK SUBSTANTIAL CLOTHING.
Supplemental Safety and Health
PRODUCT IS NON-HAZARDOUS UNTIL USED AS IN WELDING PURPOSES. THE
COMPOSITION & QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING
WELDED, PROCESS, PROCEDURES, ELECTRODES USED, COATINGS, POSITION OF
WELDERS HEAD W/RESPECT TO THE PLUME & AS WELL AS THE PRESENCE OF
CONTAMINANTS IN THE ATMOSPHERE.
* Product Identification *
Product ID:NICKEL/HIGH NICKEL BARE WIRE B
* Composition/Information on Ingredients *
Fraction by Wt: 1%
ACGIH TLV:5 MG/CUM
Ingred Name:VANADIUM
Fraction by Wt: 0.2-0.4%
Other REC Limits:0.1 MG/CUM
Ingred Name:THIS "INGREDIENT" IS LISTED TO INFORM THE READER OF THE PEL
& TLV FOR WELDING FUMES AS TOTAL PARTICULATES.
Ingred Name:CARBON, ACTIVATED CARBON, GRAPHITE
Ingred Name:CHROMIUM, CHROMIUM METAL, CHROME (CARCINOGEN BY NTP; IARC
Fraction by Wt: 1%
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Fraction by Wt: 2.5%
OSHA PEL:0.1 MG/CUM
Fraction by Wt: 0.5%
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC
OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT
Fraction by Wt: 4-7%
ACGIH TLV:5 MG/CUM (FE)
Fraction by Wt: 1%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM (DUST)
Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND)
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:NICKEL (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B,
Fraction by Wt: BALANCE
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
Ingred Name:CRYSTALLINE-FUSED SILICA, SILICON DIOXIDE, AMORPHOUS QUARTZ
Fraction by Wt: 1%
ACGIH TLV:0.1 MG/CUM RESP DUST
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES:
DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES.
LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON
BUILD UP IN THE LUNGS, BONE EROSI ON, REDUCED PULMONARY FUNCTIONS &
NERVOUS DISORDERS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:SHORT TERM EXPOSURE TO WELDING FUMES:
DIZZINESS, NAUSEA, DRYNESS/IRRITATION OF NOSE/THROAT/LUNGS/EYES.
LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON
BUILDUP IN THE LUNGS, BONE EROSIO N, REDUCED PULMONARY FUNCTIONS &
NERVOUS DISORDERS.
Medical Cond Aggravated by Exposure:PRE-EXISTING RESPIRATORY/ALLERGETIC
CONDITIONS.
* First Aid Measures *
First Aid:REMOVE VICTIM TO FRESH AIR. EMPLOY FIRST TECHNIQUES
RECOMMENDED BY THE RED CROSS. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO THE
SURROUNDING FIRE.
Fire Fighting Procedures:TO EXTINGUISH A METAL POWDER FIRE USE DRY
SAND, DRY GRAPHITE/OTHER CLASS D FIRE EXTINGUISHER.
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE
COMBUSTIBLE & FLAMMABLE PRODUCTS.
*Handling and Storage *
Handling and Storage Precautions:MONITOR THE AIR TO ENSURE THE LEVELS
AREA <THE RECOMMENDED LIMITS. WEAR APPROPRIATE EQUIPMENT TO PREVENT
INJURY FROM RADIATION/SPARKS/ELECTRIC SHOCK.
Other Precautions:TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS &
INSULATE THEMSELVES FROM WORK & GROUND.
* Physical/Chemical Properties *
Appearance and Odor:SOLID WIRE/ROD, GRAY TO SILVER IN COLOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS, OXIDIZING AGENTS (SEE SUPPLEMENTAL DATA)
Stability Condition to Avoid:(SEE SUPPLEMENTAL DATA)
Hazardous Decomposition Products:COMPLEX OXIDES OF IRON, MANGANESE,
SILICON, CHROMIUM, NICKEL, MOLYBDENUM, CALCIUM, MAGNESIUM, TITANIUM
(SEE SUPP)
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE
CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER IAW/LOCAL,
STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:EYE BATH, WASHING FACILITIES, SAFETY SHOWERS.
WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits: RECOMMENDED
Ingred Name:POTASSIUM SULFITE
Other REC Limits: RECOMMENDED
Other REC Limits: RECOMMENDED
OSHA PEL:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:DIETHYLENE GLYCOL
Fraction by Wt: 9%
Other REC Limits: RECOMMENDED
Ingred Name:POTASSIUM CARBONATE
Fraction by Wt: 1-5%
Other REC Limits: RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION-EXPECTED TO BE A LOW HAZARD
FOR RECOMMENDED HANDLING. EYES-CAUSES IRRITATION. SKIN-CAUSES
IRRITATION. MAY CAUSE ALLERGIC SKIN REACTIONS. INGESTION-HARMFUL IF
SWALLOWED. CAN CAUSE KIDNEY DAM AGE.
Explanation of Carcinogenicity:NOT CARCINOGENIC.
Effects of Overexposure:INHALATION-SOME ASTHMATICS OR SULFITE SENSITIVE
INDIVIDUALS MAY EXPERIENCE WHEEZING OR CHEST TIGHTNESS.
INGESTION-SOME ASTHMATICS OR SULFITE-SENSITIVE INDIVIDUALS MAY
EXPERIENCE WHEEZING, CHEST TIGHTN ESS, STOMACH UPSET, HIVES,
FASINTNESS, WEAKNESS AND DIARRHEA.
Medical Cond Aggravated by Exposure: SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR. EYES-IMMEDIATELY FLUSH WITH PLENTY OF
CLOTHES/SHOES. GET MEDICAL ATTENTION. INGESTION-INDUCE VOMITING AS
DIRECTED BY MEDICAL PERSONNEL. CALL A PHYSICIAN OR POISON CONTROL C
* Fire Fighting Measures *
Flash Point:
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:FOR SMALL AMOUNTS-FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. CLEAN SURFACE THOROUGHLY TO REMOVE RESIDUAL
CONTAMINATION. FOR LARGE SPILL-ABSORB SPILL WITH VERMICULITE OR
OTHER INERT MATERIAL, THEN PLA CE IN A CONTAINER FOR CHEMICAL
WASTE.
Neutralizing Agent: SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING.
* Physical/Chemical Properties *
HCC:B3
Vapor Density:0.6
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID. LIGHT YELLOW. ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:
Hazardous Decomposition Products:CARBON DIOIXDE, CARBON MONOXIDE,
OXIDES OF SULFUR.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL IS SUBJECT TO
NATIONAL, STATE OR LOCAL LAWS. SMALL-FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER. LARGE-CONTRACT WITH A LICENSED CHEMICAL DISPOSAL
AGENCY.
| 1 | eyes_protection_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:NONE LISTED BY MANUFACTURER. CHRONIC:PROLONGED
CONTACT MAY RESULT IN IRREVERSIBLE EYE DAMAGE, AND SKIN IRRITATION OR RASH.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
SKIN:WASH W/SOAP & WATER. INHAL:REMOVE TO FRESH AIR. CONT A PHYS IMMED.
INGEST:DO NOT INDUCE VOMIT. CONT A PHYS OR REGIONAL POIS CTL C TR
IMMEDIATELY.
*
Handling and Disposal
*
Spill Release Procedures: DIKE SPILL AREA. ABSORB REMAINING LIQUID WITH
ABSORBENT MATERIAL AND PLACE INTO CONTAINERS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE, AND LOCAL
REGULATIONS. DISCARDED MATERIAL SHOULD BE INCINERATED AT A PERMITTED
FACILITY.
Handling And Storage Precautions: STORE AWAY FROM CAUSTICS AND OXIDIZERS. KEEP
CONTAINERS AWAY FROM EXCESSIVE HEAT AND FREEZING. KEEP CONTAINERS TIGHTLY
CLOSED WHEN NOT IN USE.
Other Precautions: KEEP OUT OF REACH OF CHILDREN.
*
Fire and Explosion Hazard Information
*
Flash Point Method: CC
Extinguishing Media: FOAM, CARBON DIOXIDE, DRY CHEMICALS.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). USE WATER SPRAY TO COOL EXPOSED SURFACES.
Unusual Fire/Explosion Hazard: NONE KNOWN.
*
*
Respiratory Protection: NOT REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: PROVIDE SUFFICIENT MECH VENT (LOC/GEN EXHAUST) TO MAINTAIN EXPOS
BELOW TLV. VAPS ARE HVR/AIR & WILL COLLECT IN (SUPDAT)
Other Protective Equipment: IMPERVIOUS APRONS. ANSI APPRVD EMERGENCY EYE WASH &
DELUGE SHOWER (FP N).
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT THE
"LR" VERSION FOR ADDITIONAL INFORMATION (FP N). VENT:LOW AREAS. CHECK ALL LOW
AREAS (BASEMENTS, SUMPS, ETC.) BEFORE ENTERING. EYE PROT:FULL LENGTH FACES
HIELD (FP N).
*
Physical/Chemical Properties
*
Vapor Density: >1.0
Solubility in Water: MISCIBLE
Appearance and Odor: LIQUID WITH FAINT AMINE ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXCESSIVE HEAT AND FREEZING.
Materials To Avoid: STRONG OXIDIZERS AND CAUSTICS.
Hazardous Decomposition Products: NORMAL COMBUSTION PRODUCTS, I.E. CO*X, NO*X.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: DAP INC.
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: AVOID EYE AND SKIN CONTACT. ACUTE:NONE LISTED BY
MANUFACTURER. CHRONIC:PROLONGED CONTACT MAY RESULT IN IRREVERSIBLE EYE
DAMAGE, AND SKIN IRRITATION OR RASH.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESP FOR DUSTS & MISTS.
Ventilation:GOOD INDUSTRIAL HYGIENE PRACTICE DICTATES THAT WORK AREA
SHOULD BE ISOLATED & CONTAINED & PROVIDED (SEE INGRED 9)
Other Protective Equipment:PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: SUPERFICIAL DESTRUCTION OF SKIN/PRIMARY IRRIT
DERMATITIS. SEV BURNS MAY RSLT W/DEEP ULCERATION & ULTIMATE
SCARRING. CHRONIC EYE EXP CAN LEAD TO DESTRUCTION OF EYE TISSUE ON
CONTACT & POTENTIAL BLINDNESS. CHRONIC INGEST CANRSLT IN SEV BURNS
& COMPLETE TISSUE PERFORATION.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:FIRST AID PROC: WASH CONTAMINATED SKIN W/PLENTY OF WATER.
THIS MAY BE FOLLOWED W/RINSE W/VINEGAR/DILUTE (SEE INGERED 5)
Ingred Name:INGRED4:ACETIC ACID (3% SOLUTION)IF AVAIL.REMOVE CONTAM
CLOTHING &FOOTWEAR & WASH CLOTHING BEFORE REUSE.(SEE INGRED 6)
Ingred Name:INGRED 5: SEEK MED ATTN IF IRRIT PERSISTS. INGEST: DON'T
INDUCE VOMIT. GIVE LRG QTYS OF WATER. IF AVAIL (SEE INGRED 7)
Ingred Name:INGRED 6: GIVE SEVERAL GLASSES OF MILK. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON. SEEK MED ATTN IMMED.
Ingred Name:WASTE DISP METH: PERSONAL PROTECTIVE EQUIP AND CLOTHING.
Ingred Name:VENT: W/ADEQ LOCAL EXHAUST VENT OR OTHER CONTROLS TO
Ingred Name:INGRED 9: BELOW 2.0 MG/M3 AS REQUIRED BY OSHA.
WORN WHEN HANDLING.
Ingred Name:SODIUM HYDROXIDE (SARA III)
Other REC Limits:NONE SPECIFIED
OSHA PEL:2 MG/M3
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED (ALIPHATIC PETROLEUM
Ingred Name:ALUMINUM (SARA III)
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SPRAY MIST/DUST IS STRONGLY
IRRIT TO UPPER RESP TRACT WHICH IS USUALLY ASSOC W/SNEEZING,
COUGHING & DISCOMFORT. CONT W/SKIN CAN CAUSE REDDENING, IRRIT,
BURNS & DISCOMFORT. THIS PROD IS DESTRUCT TO EYE TISS ON CONT &
WILL RSLT IN SEVERE BURNS. INGEST PRDCES SEV BURNS & COMPLETE TISS
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: PERFORATION OF MOUTH, THROAT,
ESOPHAGUS & STOMACH & DEATH DEPENDING ON SEVERITY OF EXP. CHRONIC:
AIRBORNE CONCENTRATIONS OF MIST,SPRAY/DUST MAY CAUSE DAMAGE TO
UPPER RESP TRACT & EVEN TO THE LUNG TISS PROPER WHICH COULD PRDCE
PNEUMONIA,DEPENDING ON SEVERITY OF EXP.CHRONIC LOCAL EFT IS AREA
OF(SEE SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: GET PERSON OUT OF CONTAM AREA TO FRESH AIR. IF BRTHG
HAS STOPPED, ARTF RESP SHOULD BE STARTED. O*2 MAY BE ADMIN, IF
READILY AVAIL. SEEK MED ATTN IMMED. EYE: IMMED FLUSH EYES W/LRG
FLUSHING OF ENTIRE EYE SURFACE. WASHING EYES W/IN 1 MIN IS ESSNTL
TO ACHIEVE MAX EFTIVNESS. SEEK MED ATTN IMMED. SKIN: IMMED (SEE
INGRED 4)
* Fire Fighting Measures *
Flash Point:NON-FLAM
Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL
Fire Fighting Procedures:NIOSH/MSHA APPROVED PRESS DEMAND,
SELF-CONTAINED RESP PROT & PROT CLOTHING SHOULD BE WORN BY
FIREFIGHTERS IN AREAS WHERE PROD IS STORED. PROD IS NON FLAM.
Unusual Fire/Explosion Hazard:YIELDS GASEOUS OXIDES OF NITROGEN.
CONTACT WITH NITRO-COMPOUNDS MAY FORM SHOCK SENSITIVE SALTS.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL. RMV AS MUCH AS POSS. NEUT
LIBERAL COVERING OF SODIUM BICARBONATE. REUSE SPILLED MATL
OTHERWISE PLACE IN CLSD, LBLD CONTR & STOR IN SAFE PLACE TO AWAIT
PROPER DISP.
Neutralizing Agent:SEE SPILL/RELEASE PROCEDURES
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. FOLLOW LABEL
DIRECTIONS. KEEP OUT OF REACH OF CHILDREN. THIS PROD CAN REACT
VIOLENTLY/EXP W/ACIDS & MANY ORGANIC CHEM.
Other Precautions:CONSIDERABLE HEAT IS GENERATED WHEN WATER IS ADDED TO
THIS PRODUCT. WHEN MAKING SOLUTIONS. ALWAYS ADD CA-NF TO WATER WITH
WITH HOT WATE R.
* Physical/Chemical Properties *
HCC:C2
Spec Gravity:GRANULAR
Solubility in Water:APPRECIABLE
Appearance and Odor:BLUE, ODOR NOT OBJECTIONABLE
Percent Volatiles by Volume:1
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER ACIDS, FLAMMABLE LIQUIDS, ORGANIC HALOGENS; METALS: ALUMINUM,
ZINC. TIN: NITROMETHANE AND NITRO COMPOUNDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HAZARDOUS OXIDES OF NITROGEN
* Disposal Considerations *
Waste Disposal Methods:CAUTION: THIS PROD MAY REACT VIOLENTLY W/ACIDS &
WATER. DISP IN ACCORD W/ALL FED, STATE & LOCAL REGS CONCERNING HLTH
& POLLUTION. DISP VIA APPRVD CHEM WASTE DISP METHOD. IF REGS
PERMIT. PERSONS PERFOR MING THIS WORK SHOULD WEAR ADEQ (SEE INGRED
8)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHEN SPRAY APPLIED IN OUTDOOR/OPEN AREAS
W/UNRESTRICTED VENT, & DURING SANDING/GRINDING OPERATIONS, USE
NIOSH/MSHA APPRVD MECH FILTER RESP TO REMOVE SOLID AIRBORNE
PARTICLES OF OVERSPRAY/SANDING DUST. WHEN USED IN RESTRICTED
AREAS, (ING 9)
Ventilation:PROVIDE GEN DILUTION OR LOC EXHST VENT IN VOL/PATTERN TO
Other Protective Equipment:NOT REQUIRED.
Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE.
WASH HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM.
Supplemental Safety and Health
MFRS TRADE NAME/PART NO:GLOSS ENAMEL. VAP DENS:HVR/LIGHTER THAN AIR;
WATER IS LIGHTER THAN AIR. FIRE FIGHT PROC:WATER SHOULD BE USED TO
COOL CLSD CONTRS & PVNT PRESS BUILD-UP OR POSS AUTOIGNITION. EXP LO
HAZ:DECOMP PRODS MAY CAUSE HLTH HAZ.SYMPS MAY BE IMMED APPARENT.
OBTAIN MED ATTN.
* Product Identification *
* Composition/Information on Ingredients *
COATED W/THIS PROD. FOLLOW RESP MFRS DIRECTIONS FOR RESP USE.
Ingred Name:VENT:STANDARDS IN MIXING, APPLICATN & CURING AREAS, & TO
W/THIS PRODUCT.
Ingred Name:WATER
Ingred Name:VINYL ACRYLIC RESIN
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Fraction by Wt: <5%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:PROPIONIC ACID, 2-METHYL-, MONOESTER
W/2,2,4-TRIMETHYL-1,3-PENTANEDIOL; (2,2,4 TRIMETHYLPENTANEDIOL-1,3
(ING 6)
Fraction by Wt: <5%
Ingred Name:HAZ DECOMP PROD:METALS LISTED IN INGREDIENT SECTION.
Ingred Name:RESP PROT:WEAR NIOSH/MSHA APPRVD CHEM/MECH FILTERS DESIGNED
Ingred Name:ING 9:USED IN CONFINED AREAS, WEAR NIOSH/MSHA APPRVD AIR
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:IRRIT OF RESP TRACT; MAY
AFFECT BRAIN OR NERV SYS CAUSING DIZZ, HDCH & NAUS. EYE/SKIN:CONT
CAUSES IRRIT. INGEST:CAN CAUSE STOM &/OR INTESTINAL IRRIT, NAUS,
VOM & DIARR. ASPIR OF VOM CAN C AUSE CHEMICAL PNEUMONITIS, WHICH
CAN BEFATAL. CHRONIC: PRLNGD/RPTD BRTHG OF SPRAY MIST/SANDING DUST
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:OVER A PERIOD OF YEARS MAY CAUSE DUST
DISEASE OF THE LUNGS.
Medical Cond Aggravated by Exposure:NONE WHEN USED IN ACCORDANCE W/SAFE
HANDLING & USE INFORMATION.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. EYES:FLUSH W/LARGE AMOUNTS OF
W/SOAP & WATER. REMOVE SOILED CLOTHING. INGEST:DRINK 1 OR 2 GLASSES
OF WATER. D O NOT INDUCE VOMITING. CONSULT MD IMMEDIATELY. TREAT
SYMPTOMATICALLY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON.
* Fire Fighting Measures *
Flash Point Method:SCC
Flash Point:NONE
Lower Limits:SEE INGREDS
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL, FOAM OR OTHER
NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF. IF
EXPOSED TO FIRE/EXTREME HEAT, (SUP DAT)
Unusual Fire/Explosion Hazard:DUE TO PRESS BUILD-UP, CLSD CONTRS
EXPOSED TO EXTREME HEAT MAY EXPLODE. AFTER WATER EVAPS, REMAINING
MATL WILL BURN. DURING EMER CNDTNS, OVEREXPOS TO (SUP DAT)
* Accidental Release Measures *
Spill Release Procedures:WASH W/WATER. BEFORE ATTEMPTING CLEAN-UP,
REFER TO HAZARD INFORMATION IN OTHER SECTIONS OF THIS MSDS. CONTAIN
SPILLED MATERIAL & REMOVE W/INERT ABSORBENT. STORE IN CLOSED
CONTAINERS UNTIL PROPERLY DIS POSED OF.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
KEEP CONTAINER CLOSED WHEN NOT IN USE. DO NOT REUSE EMPTY
CONTAINERS. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:DO NOT BREATHE VAPORS, SPRAY MIST OR SANDING DUST.
USE ONLY W/ADEQUATE VENTILATION. DO NOT GET IN EYES. CONTAINS A
CHEMICAL KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH
DEFECTS & OTHER REPRODUC TIVE HARM.
* Physical/Chemical Properties *
Vapor Pres:SEE INGRED
Vapor Density:SUPP DATA
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/MATERIALS THAT ARE UNSTABLE W/WATER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY CAUSE HAZ FUMES WHEN HEATED TO
DECOMP. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE & OXIDES
OF (ING 8)
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK.
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS
CLOTHING.
Supplemental Safety and Health
BY DGSC-STF.
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION.
LATENT EFFECTS:SOMATIC/GENETIC DAMAGE.
* First Aid Measures *
First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE
COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN
PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT
VICTIM(S) MAY BE CON TAMINATED.
* Fire Fighting Measures *
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD
BRTHG APP.
Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE
IN HEAT OF FIRE.
* Accidental Release Measures *
*Handling and Storage *
Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION.
PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN
AREA FOR RADIOACTIVE MATERIALS.
* Physical/Chemical Properties *
HCC:A3
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL
Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION;
FISSION PRODUCTS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH
DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED IN NORMAL CONDITIONS.
Ventilation:MECHANICAL(GENERAL) IF NEEDED
Other Protective Equipment:AS NEEDED BY LOCAL AUTHORITIES.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SOLID,HAZARD UNKNOWN,UNIDENTIFIED
* Hazards Identification *
Effects of Overexposure:PER MFR MSDS,OVEREXPOSURED EFFECTS ARE OF LOW
HAZARD TO HEALTH
* First Aid Measures *
ATTN IF IRRIT SYMPTOMS OCCUR;EMERGENCY PROCEDURES NONE INDICATED BY
MANUFACTURER.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:CO*2, FOAM, DRY CHEM.
Fire Fighting Procedures:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:EVACUATE UNPROTECTD PERSONS.ELIM IGN
SOURCES.USE PROTECTV CLOTHING/SAFETY GLASSES;SWEEP UP AS MUCH AS
POSS & PLACE IN COVERED DRUMS.VACUUM THE REST & PLACE IN THE SAME
DRUM PENDING DISPOSAL;MFR RECOMM FLUSH REMAINDER TO SEWER LAW
FED,STATE/LOCAL LAWS
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL DRY,WELL VENTILATED
AREA.KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:NONE KNOWN
* Physical/Chemical Properties *
HCC:N1
Vapor Pres:NEG
Spec Gravity:>1.0
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE CRYSTALS-LITTLE ODOR.
Percent Volatiles by Volume:NEGL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:KEEP IN COVERD CONTNRS PENDING
DISPOSAL.HANCLE/DISPOSE BY NORMAL SOLID WASTE DISPOSAL PROCEDURES
&/OR SHIP TO APPRVD LANDFILL LAW FED,STATE & LOCAL REGS.DISPOSER
MUST COMPLY W/ALL APPLICABLE INTNL,FED ,STATE/LOCAL REG.MFR NOTES
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE COMBINATION NIOSH/MSHA APPROVED PARTICULATE/
GAS RESPIRATOR, CLASS B, (INORGANIC VAPOR).
Ventilation:MAINTAIN CONC BELOW RECOM EXPOS LIMIT. LOCAL EXHAUST VENT
USUALLY REQUIRED. KEEP CNTNRS IN WELL-VENT AREA.
Other Protective Equipment:OVERALLS, SPLASH APRON, RUBBER BOOTS.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER USE AND BEFORE
EATING, DRINKING, SMOKING OR USING SANITARY FACILITIES .
Supplemental Safety and Health
MTLS TO AVOID:COPPER/COPPER ALLOYS. KEEP AWAY FROM CYANIDES/SULPHIDES.
FIRST AID PROC:MASSAGE. SUPPORT BRTHG (GIVE O2/ARTF RESP),CALL MD.
INGEST:RINSE MOUTH THORO W/WATER IMMED. GIVE WATER/ MILK TO DR INK.
DO NOT INDUCE VOMIT, MAY CAUSE FURTHER DMG TO THROAT. CALL MD
IMMED. SPILL PROC:USE NIOSH/MSHA APPRVD(SEE INGRED 2
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III)
OSHA PEL:C 5 PPM
Ingred Name:WATER
Fraction by Wt: BALANCE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:HIGHLY CORROSIVE TO EYES;
CAN RESULT IN PERMANENT INJURY. HIGH CONC OF VAPS WILL CAUSE IRRIT.
SKIN:CNTCT WILL RESULT IN SEVERE IRRIT. HARMFUL & CORROSIVE; MAY
CAUSE BURNS. INHAL: IRRIT TO MU C MEMB & RESP TRACT. POSS HARMFUL
CORROSIVE EFTS. ASPHYXIANT, EXPOS TO HIGH CONCS WILL CAUSE (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SUFFOCATION. INGEST:CAN KILL. MAY
CAUSE SEVERE BURNS TO MOUTH, THROAT & STOMACH. WILL CAUSE SEVERE
DAMAGE TO MUCOUS MEMBRANES. CHRONIC:PRLNGD EXPOSURE MAY CAUSE
BRONCHITIS, PNEUMONIA & PULMON ARY EDEMA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
WHILE HOLDING LIDS OPEN. GET MD. SKIN:WASH AFFECTED AREAS W/COPIOUS
QTYS OF WATER IMMED. IF IRRIT OCCURS GET MD. REMOVE CONTAM CLTHG/
WASH BEFORE RE-USE. TREAT SKIN/CLTHG W/1% SODIUM BICARBONATE SOLN
TO NEUT ACID RESIDUES. INHAL:REMOVE TO FRESH AIR. KEEP COMFORTABLE,
WARM, AT REST. FOR CARDIAC ARREST, APPLY EXTERNAL CARDIAC(SEE SUPP
DATA
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:USE WATER SPRAY.
Fire Fighting Procedures:EVACUATE IMMEDIATE AREA. FIRE FIGHTERS SHOULD
WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT IF RISK
OF EXPOSURE TO VAPOR OR PRODS OF COMBUSTION.
Unusual Fire/Explosion Hazard:DECOMPOSES ON HEATING EMITTING TOXIC
FUMES. HEATING CAN CAUSE EXPANSION OR DECOMP LEADING TO VIOLENT
RUPTURE OF CONTAINERS. USE WATER TO KEEP SUBSTANCE COOL.
* Accidental Release Measures *
Spill Release Procedures:CLEAR AREA OF UNPROTECTED PERSONNEL. LG:
NOTIFY EMER SERVICES. CONTAIN/PVNT CONTAM OF DRAINS/WATERWAYS. USE
ABSORBENT. COLLECT & SEAL IN PROPERLY LABELLED DRUMS FOR DISPOSAL.
FLUSH TO SEWER AS GREATLY DILUTED SOLN. WEAR FULL PROT CLTHG.(SEE
SUPP DATA
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL PLACE OUT OF DIRECT
SUNLIGHT; WELL-VENT AREA; AWAY FROM OXIDIZING AGENTS; AWAY FROM
FOODSTUFFS. KEEP CNTNRS SECURELY (SEE INGRED 2)
Other Precautions:WILL REACT W/WATER OR STEAM TO PRDCE TOXIC/CORR
FUMES. KEEP AWAY FROM STRONG OXIDIZING AGENTS, STRONG BASES. AVOID
CNTCT W/METALS. REACTS W/ZINC, BRASS, GALVINIZED IRON, ALUMINUM,
COPPER & COPPER ALLO YS. KEEP AWAY FROM CYANIDES & SULPHIDES.
* Physical/Chemical Properties *
HCC:C1
pH:<1
Appearance and Odor:COLORLESS TO YELLOW, CLEAR LIQUID, CHARACTERISTIC
FUMES.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG BASES. CONTACT W/ METALS. REACTS
W/ZINC, BRASS, GALVINIZED IRON, ALUMINUM (SEE SUPP DATA
Stability Condition to Avoid:WILL REACT W/WATER OR STEAM TO PRODUCE
TOXIC & CORROSIVE FUMES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE.
* Disposal Considerations *
Waste Disposal Methods:AVOID CONTAMINATING WATERWAYS. DISPOSE OF I/A/W
FEDERAL, STATE AND LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE THE FOLLOWING NIOSH/MSHA APPRVD RESP:ANY
DUST & MIST RESP W/FULL FACEPIECE;ANY AIR-PURIFYING FULL FACEPIECE
RESP W/HIGH-EFFICIENCY PARTICULATE FILTER;ANY POWERED AIR-PURIFYING
Ventilation:PROVIDE LOCAL EXHAUST/PROCESS ENCLOSURE VENTILATION.
VENTILATION EQUIP MUST BE EXPLOSION-PROOF.
Other Protective Equipment:WEAR APPROP PROT (IMPERV CLTHG & EQUIP TO
PVNT RPTD/PRLNGD SKIN CONT W/SUBSTANCE. PROVIDE EYEWASH FOUNTAIN
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
APPEAR & ODOR: POWDER W/SLIGHT ODOR OF CHLORINE & WHICH SLOWLY
DECOMPOSES IN AIR. FIRE FIGHT PROC: WATER THAN NEEDED FOR FIRE
CONTROL. DIKE FIRE CONTROL WATER FOR LATER DISPOSAL. USE AGENTS
SUITABLE F OR TYPE OF SURROUNDING FIRE. AVOID BRTHG HAZARDOUS VAPS,
* Product Identification *
Product ID:CHLORAMINE T
* Composition/Information on Ingredients *
Ingred Name:ING 9:FORMS METHEMOGLOBIN, WHICH COMBINES W/CYANIDE TO FORM
ADMINISTERED BY QUALIFIED MEDICAL PERSONNEL.
Ingred Name:RESP PROT: PARTICULATE FILTER; ANY TYPE "C" SUPPLIED-AIR
PRESSURE MODE.
Ingred Name:OTHER PROT EQUIP: WITHIN THE IMMEDIATE WORK AREA FOR
EMERGENCY USE.
Ingred Name:P-TOLUENESULFONAMIDE, N-CHLORO-, SODIUM SALT; (CHLORAMINE
T) (CHLORAZENE)
Ingred Name:FIRST AID PROC: OCCASIONALLY LIFTING LIDS, UNTIL NO EVID OF
Ingred Name:ING 3: INGEST:REMOVE BY IPECAC EMESIS FOLLOWED BY ACTIVATED
CHARCOAL/EVAPORATED MILK. AIRWAY-PROTECTED GASTRIC (ING 4)
Ingred Name:ING 3: LAVAGE MAY BE NEC IN SYMPTOMATIC PATIENTS.
Ingred Name:ING 4:SHLD BE PERFORMED BY QUALIFIED MED PERS.GET MED ATTN
IMMED.ANTIDOTE:THE FOLLOWING ANTIDOTE HAS BEEN RECD.(ING 6)
Ingred Name:ING 5:HOWEVER, THE DECISION AS TO WHETHER THE SEVERITY OF
POISONING REQS ADMIN OF ANY ANTIDOTE & ACTUAL DOSE REQD(ING 7)
OSHA PEL:NOT APPLICABLENOT AP
ACGIH TLV:NOT APPLICABLENOT AP
Ingred Name:ING 6: SHLD BE MADE BY QUALIFIED MED PERS. ADMIN IN THE
PRESENCE OF SYMPS FROM CYANIDE POISONING. ALL CYANIDE (ING 8)
Ingred Name:ING 7:ANTIDOTES ARE TOX & UNNEC THERAPY IS DANGEROUS. AS
SOON AS POSS, GIVE 3% SODIUM NITRITE SOLN INTRAVENOUSLY (ING 9)
Ingred Name:ING 8: @ A RATE OF 2.5-5.0 ML/MIN. STOP ADMIN IF SYSTOLIC
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE IRRIT, VASOMOTOR
RHINITIS & ASTHMA.SKIN:MAY CAUSE IRRIT & ALLERGIC SKIN
REACTIONS.EYE:DUST MAY CAUSE IRRIT & CONJUNCTIVITIS.INGEST:MAY
CAUSE RAPID ONSET OF RESP EMBARRASSMENT, FR OTHING @ MOUTH, VOMIT,
CYANOSIS, MARKEDHYPOTENSION, SUBNORMAL TEMP, ABDOMINAL PAIN,
COLLAPSE & (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CONVULSIONS. DEATH FROM RESP FAILURE
USUALLY OCCURS W/IN A FEW MINS IF LG AMT HAS BEEN INGESTED. IT HAS
BEEN SUGGESTED THAT CHLORAMINE T CAN REACT W/SOME AMINO ACIDS IN GI
TRACT TO FORM TOXIC CYANOGEN COMPOUNDS. CHRONIC: INHAL/EYE/INGEST:
NO DATA AVAILABLE. SKIN: RPTD & PRLNGD CONT W/IRRITANTS MAY CAUSE
DERM.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:MOVE FROM EXPOS AREA TO FRESH AIR IMMED.IF BRTHG HAS
STOPPED, PERFORM ARTF RESP.KEEP PERS WARM & AT REST. TREAT
SYMPTOMATICALLY & SUPPORTIVELY.GET MED ATTN IMMED.SKIN:REMOVE
CONTAMD CLTHG & SHOE S IMMED.WASH AFFECTED AREA W/SOAP/MILD
DETERGENT & LG AMTS OF WATER UNTIL NO EVID OF CHEM REMAINS (APPROX
WATER/NORM SALINE, (ING 2)
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY OR FOAM.
FOR LARGER FIRES, USE WATER SPRAY, FOG OR ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . MOVE CONTAINER FROM FIRE AREA IF POSSIBLE.
DO NOT SCATTER SPILLED MATERIAL W/MORE(SUPP DATA)
Unusual Fire/Explosion Hazard:DECOMPOSES EXPLOSIVELY ON HEATING TO
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE (FIBERBOARD)
CONTAINERS FOR RECLAMATION OR LATER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN TIGHTLY CAPPED CONTAINERS
SUBSTANCES.
Other Precautions:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS WHEN
STORING THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE DISTRICT
DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY.
* Physical/Chemical Properties *
HCC:T6
Melt/Freeze Pt:M.P/F.P Text:SUPP DATA
pH:NEUT
Solubility in Water:SOLUBLE
Appearance and Odor:COLORLESS TO WHITE/FAINTLY YELLOW EFFLORESCENT
PRISMS/CRYSTALLINE (SUPP DATA)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ISONITRILES + CALCIUM CARBONATE: EXPLOSION ON WARMING.
Hazardous Decomposition Products:THERMAL DECOMP PRODS MAY INCLUDE TOX
OXIDES OF NITROGEN, SULFUR, & CARBON, & TOXIC & CORROSIVE FUMES OF
CHLORIDES.
* Disposal Considerations *
Waste Disposal Methods:OBSERVE ALL FEDERAL, STATE AND LOCAL REGULATIONS
WHEN DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE, CONTACT THE
DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
NECESSARY.
Ventilation:USE ADEQUATE GENERAL/LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH & DELUGE
SHOWER . WEAR APRON & PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC:GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH AIR IMMED.
IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES
TO MD:TREAT SYMPTOMATICALLY & SUPPORTIVELY. NO SPECIFIC ANTI DOTE
EXISTS. OTHER PREC:IN TIGHTLY CLSDCONTR. STORE IN COOL, DRY,
WELL-VENTD AREA AWAY FROM INCOMPATIBLE SUBSTANCES.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CYCLOHEXANE, METHYL-; (METHYLCYCLOHEXANE)
Fraction by Wt: 0.2%
Ingred Name:HEPTANE; (HEPTANE (N-))
Ingred Name:ISOOCTANE (VAN)
Fraction by Wt: 0.1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DIMETHYLCYCLOPENTANES
Fraction by Wt: 0.1%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: MAY CAUSE MILD IRRIT.
SKIN: MAY CAUSE MOD IRRIT. PRLNG &/RPTD CONT MAY CAUSE DEFAT OF
SKIN & DERM. INGEST: ASPIR HAZ. CAUSES GI IRRIT W/NAUS, VOMIT &
DIARR. ASPIR OF MATL INTO LUNGS MAY C AUSE CHEM PNEUMIT, WHICH CAN
BE FATAL. INHAL: INHAL OF HIGH CONCS MAY CAUSE CNS DEPRESS
CHARACTERIZED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: BY HDCH, DIZZ, UNCON & COMA. MAY
CAUSE RESP TRACT IRRIT. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT
MAY CAUSE DERMATITIS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN:FLUSH W/PLENTY OF
SHOES. GET MED AI D IF IRRIT DEVELOPS/PERSISTS. WASH CLTHG BEFORE
REUSE. INGEST:DO NOT INDUCE VOMIT. IF VICTIM IS CONSCIOUS & ALERT,
GIVE 2-4 CUPFULS OF MILK/WATER. POSS ASPIR HAZ. GET MED AID IMMED.
INHAL: (SUP DAT)
* Fire Fighting Measures *
Lower Limits:1.1%
Extinguishing Media:DO NOT USE WATER DIRECTLY ON FIRE. USE FOAM, DRY
CHEMICAL, OR CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO A SOURCE OF IGNITION
AND FLASH BACK. EXTREMELY FLAMMABLE. MATERIAL WILL READILY IGNITE
AT ROOM TEMPERATURE.
* Accidental Release Measures *
Spill Release Procedures:ABSORB SPILL W/INERT MATL (E.G., DRY
SAND/EARTH), THEN PLACE INTO CHEM WASTE CONTR. WEAR NIOSH APPRVD
SCBA & APPROP PERS PROT. SCOOP UP W/NON-SPK TOOL, THEN PLACE INTO
SUITABLE CONTR FOR DISP. REMOVE ALL SOURCES OF IGNITION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE ONLY IN WELL VENTILATED AREA. USE
SPARK-PROOF TOOLS AND EXPLOSION PROOF EQUIPMENT. AVOID CONTACT WITH
EYES, SKIN, AND CLOTHING.
Other Precautions:EMPTY CONTRS RETAIN PROD RESIDUE (LIQ &/VAP), & CAN
BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE SUCH CONTRS TO HEAT, SPKS/OPEN FLAMES. AVOID INGEST &
INHAL. KEEP AWA Y FROM SOURCES OF IGNIT. STORE (SUP DAT)
* Physical/Chemical Properties *
Vapor Density:3.5
Evaporation Rate & Reference:2.8 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILD GASOLINE-LIKE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES.
Hazardous Decomposition Products:OXIDES OF CARBON.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED.
Ventilation:NONE
Other Protective Equipment:NONE
Work Hygienic Practices:GOOD LABORATORY PROCEDURES.
Supplemental Safety and Health
REACTIVITY IN WATER:NOT REACTIVE.AUTOIGNITION TEMP:UNKNOWN.ROUTES OF
ENTRY:INGESTION .
Preparer's Name:DJ PETRAITIS
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS INGREDIENT
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF
OVEREXPOSURE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:IF RUBBED INTO EYES MAY CAUSE SLIGHT
TEMPORARY DISCOMFORT.SKIN:NOT A ROUTE OF ENTRY.INGESTION:NOT A
HAZARD.INHALATION:NOT A ROUTE OF ENTRY.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
First Aid:EYES:IF RUBBED INTO EYES,WASH WITH CLEAR
WATER.SKIN/INGESTION/INHALATION:N/K .
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CARBON DIOXIDE,FOAM.
Fire Fighting Procedures:DO NOT SPRAY POOL FIRES DIRECTLY,COULD CAUSE
FROTHING.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:SCOOP AND DISCARD.
Neutralizing Agent:N/K
*Handling and Storage *
Handling and Storage Precautions:NONE
Other Precautions:NONE
* Physical/Chemical Properties *
Decomp Temp:Decomp Text:N/K
Vapor Pres:1 MMHG
Evaporation Rate & Reference:N/K
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR,THICK LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,SILICON
DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS.COORDINATION WITH SUPPORTING
INSTALLATION AND/OR MACOM ENVIRONMENTAL COORDINATION PRIOR TO
DISPOSAL IS RECOMMENDED TO DETERMINE APPROPRIATE DISPOSAL METHODS
.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPRVD DUST/MIST RESPIRATOR (HIGH
EFFICIENCY CARTRIDGES ADVISED) IF SPRAYING/SANDING. USE NIOSH/MSHA
APPRVD ORGANIC VAP CARTRIDGE RESPIRATOR IF TLV FOR SOLV COMPONENTS
Ventilation:USE LOCAL EXHAUST WHEN APPLYING THIS PAINT IN CONFINED
AREAS. KEEP VAPORS BELOW TLV.
Other Protective Equipment:USE PROT CLTHG & CHANGE CONTAM CLTHG IMMED.
PROVIDE EMER SHOWERS & EYEWASH @ STATIONARY PAINT APPLICATION
FACILITIES.
Work Hygienic Practices:TRAIN EMPLOYEES ON ALL SPECIAL HANDLING
PROCEDURES BEFORE THEY WORK W/THIS PRODUCT.
Supplemental Safety and Health
FIRE FIGHT PROC:DIFFICULTIES. PREVENT HUMAN EXPOSURE TO FIRE, SMOKE,
FUMES, ETC.
* Product Identification *
Preparer's Name:E. SOETERIK
* Composition/Information on Ingredients *
Ingred Name:ALKYD RESIN, SOLUTION (CONTAINING INGREDIENTS 2 & 3)
Fraction by Wt: SEE ING
Ingred Name:XYLENE. %:2% OF ING 1.
Fraction by Wt: SEE ING
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:CALCIUM CARBONATE
Ingred Name:KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS (MFR
Ingred Name:NAPHTHENIC ACID, LEAD SALT; (LEAD NAPTHENATE CONTAINING ING
8)
Ingred Name:LIGROINE; (MINERAL SPIRITS). %:1% OF ING 7.
Fraction by Wt: SEE ING
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ODOR IS NOT AN ADEQ WARNING OF INTOX.
ACUTE: NAUS, DIZZ, HDCH & CONVLS. INHAL:INHAL OF HIGH VAP CONCS MAY
HAVE RESULTS RANGING FROM DIZZ & HDCH TO UNCON. CONT W/SKIN:BURNING
SENSATION FROM VAP/ LIQ. D ERM, SENSIT. CONT W/EYES:CAN CAUSE SEV
IRRIT, REDNESS, TEARING & BLURRED VISION. INGEST:TOX IF
SWALLOWED.(EFTS OF OVEREX
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:CAN CAUSE BURNING SENSATION, VOMIT,
DIARR, DROW. CHRONIC:CONTINUOUS RPTD &/OR PRLNG IRRIT CAN LEAD TO
INFECTIONS. REPORTS HAVE ASSOC RPTD & PRLNG OCCUP OVEREXP TO SOLVS
W/PERM BRAIN & NERV SY S DMG. INTENT MISUSE BY DELIB CONC &
INHALING CONTENTS MAY BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:ASTHMA/SKIN ALLERGIES. CAN CAUSE
DISCOMFORT TO PERS W/THESE ALLERGIES, BUT NORM IS NOT PROB.
* First Aid Measures *
First Aid:EYE:FLUSH IMMED W/FRESH WATER BY EYE WASH APPARATUS/BY HAND
W/SOAP & WATER, RINSE IMMED. SEE MD. INHAL:MOVE PERSON TO FRESH
AIR; ARTF RESP IF NECESSARY. SEE MD. INGEST:SEE MD. RECOM TO MD:IN
ACUTE CASES SEE MD IMMED. FOR WORKERS WHO MAY BE EXPOSED REG,
PROVIDE DETAILED PERIODIC EXAMS.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1%
Upper Limits:6%
Extinguishing Media:WATER FOG, FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. BLANKET FLAME W/ONE OF EXTING MEDIA. VAPS OF COMBUST MAY BE IRRIT
TO RESP TRACT. MAY CAUSE BRTHG (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP MATERIAL AWAY FROM HEAT, SPARKS &
OPEN FLAMES.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL TYPES OF IGNIT SOURCES. PROVIDE
CORP RESP & GOGGS. USE METAL CNTNR MARKED "DO NOT REUSE". PUT MATL
IN THIS CNTNR. USE VERMICU LITE/OTHER INERT ABSORB. KEEP AWAY
FROMSEWER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DMG TO CNTNRS
& SPILLAGE. STORE IN COOL, WELL VENTED AREA W/SPRINKLER SYS. KEEP
AWAY FROM HEAT. POST NO SMOKING SIGNS.
Other Precautions:FLAMMABLE. USE ONLY WITH ADEQUATE VENTILATION.
PROTECTIVE MEASURES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:4.8
Solubility in Water:NIL
Appearance and Odor:OPAQUE COLORED LIQUID W/MILD HYDROCARBON ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, SPARKS & OPEN FLAMES. DO NOT ALLOW
VAPORS TO ACCUMULATE.
Hazardous Decomposition Products:FLAMM FUMES MAY ACCUM IN CONFINED AREA
& SPARKS/OPEN FLAMES MAY IGNITE IT. COMBUST WILL PRODUCE SOME CO2 &
CO.
Conditions to Avoid Polymerization:EXTREME HEAT.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF ALL WASTES I/A/W FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
Ventilation:USE ADEQUATE MECHANICAL VENTILATION OR LOCAL EXHAUST TO
MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:CHRISTOPHER RUSSO
* Composition/Information on Ingredients *
Ingred Name:GRAPHITE, SYNTHETIC
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1MG/M3 FUME/1 DUST
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPOSURE TO DUST MAY CAUSE SKIN & EYE
IRRITATION. INHALATION OF DUST MAY CAUSE IRRITATION OF NOSE OR
THROAT. INGESTION HAS NO HEALTH HAZARD. CHRONIC: PROLONGED/REPEATED
EXPOSURE MAY CAUSE INFLAMMATION & POSSIBLE SCARRING OF LUNG
TISSUE.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:EYES-IRRITATION. SKIN-REDNESS, BURNING.
INHALED-IRRITATION OF NOSE & THROAT, COUGHING. INGESTED-NONE NOTED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYES-FLUSH WITH CLEAN WATER. SEEK MEDICAL ATTENTION IF
SYMPTOMS DEVELOP. SKIN-NORMALLY NONE REQUIRED; HOWEVER, IF
IRRITATION DEVELOPS-REMOVE CONTAMINATED CLOTHES & FLUSH AFFECTED
AREAS WITH WATER. SEE K MEDICAL ATTENTION IF SYMPTOMS PERSIST.
INHALATION-REMOVE FROM EXPOSURE. SEEK MEDICAL ATTENTION IF SYMPTOMS
PERSIST. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION; IF
DIFFICULT BREATHING, GIVE OXYGEN
* Fire Fighting Measures *
Extinguishing Media:THE USE OF WATER SPRAY, SAND OR FOG OR FOAM IS
RECOMMENDED.
Fire Fighting Procedures:COOL WITH WATER.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:REMOVE BY MECHANICAL MEANS & PLACE MATERIAL IN
METAL CONTAINER FOR LATER DISPOSAL. CLEAN UP PROCEDURE SHOULD
ENSURE MINIMIZING DUST; VACUUM RATHER THAN SWEEP, FOR EXAMPLE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP AWAY
FROM INCOMPATIBLE MATERIALS (STRONG OXIDIZING AGENTS).
Other Precautions:NONE.
* Physical/Chemical Properties *
HCC:N1
Appearance and Odor:STEEL GREY TO BLACK WELDING ELECTRODE; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:COMBUSTION OF ORGANIC MATERIALS
PRODUCES CARBON MONOXIDE AND CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED SCBA IN HIGH VAPOR
AREAS.
Ventilation:PROVIDE ADEQUATE GENERAL AND LOCAL EXHAUST VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:SODIUM HYDROXIDE
* Composition/Information on Ingredients *
Ingred Name:SODIUM HYDROXIDE (SARA III)
Fraction by Wt: 8%
OSHA PEL:2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED OR INHALED. BURNS
EYES, SKIN, NASAL AND RESPIRATORY PASSAGES ON CONTACT. VAPOR
IRRITATES EYES AND RESPIRATORY PASSAGES. SEVERE EYE HAZARD!
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
MEDICAL ASSISTANCE. SKIN: REMOVE CONTAMINATED CLOTHING AND WASH
WITH SOAP AND WATER. INHAL: REMOVE TO FRESH AIR AND GIVE ARTF RESP
IF BREATHIN G HAS STOPPED. INGEST: DO NOT INDUCE VOMITING, IF
CONSCIOUS GIVE WATER AND GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING MATERIAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CAN REACT WITH CERTAIN METALS. (AL,
ZN,SN) TO FORM EXPLOSIVE HYDROGEN GAS.
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH SAND OR VERMICULITE AND SCOOP UP
AND CONTAINERIZE FOR PROPER DISPOSAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN COOL, DRY, WELL VENTILATED AREA. KEEP AWAY FROM IGNITION SOURCE,
ACIDS, OXIDIZERS. WASH THORO AFTER HANDLING.
Other Precautions:EMPTY CONTAINER MAY BE HAZARDOUS DUE TO RETAINED
RESIDUE. DO NOT BREATHE VAPORS OR MIST. DO NOT GET IN EYES, ON SKIN
OR CLOTHING.
* Physical/Chemical Properties *
HCC:C2
Appearance and Odor:CLEAR, COLORLESS LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALUMINUM, TIN, ZINC, ORGANIC HALOGENS & NITRO COMPOUNDS.
Stability Condition to Avoid:
Hazardous Decomposition Products:NA2O
* Disposal Considerations *
Waste Disposal Methods:COMPLY WITH ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED UNDER NORMAL USE.
Ventilation:GENERAL ROOM VENTILATION
Other Protective Equipment:EYEBATH
Supplemental Safety and Health
* Product Identification *
Product ID:VACUTAINER BRAND TUBES
CAGE:BDVAC
CAGE:BDVAC
* Composition/Information on Ingredients *
Ingred Name:SODIUM HEPARIN
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:LOCAL IRRITATION, ULCERATION,
GASTROINTESTINAL IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, PAIN, ERYTHEMA, HEMATOMA, NAUSEA,
VOMITING, DIARRHEA, NOSEBLEEDS, BLOOD IN URINE.
Medical Cond Aggravated by Exposure:HYPERTENSION, CONDITIONS ASSOCIATED
W/INCREASED BLEEDING TENDENCIES, MENSTRUATION, LIVER DISEASE
W/IMPAIRED HEMOSTASIS.
* First Aid Measures *
First Aid:EYES/SKIN: WASH W/LARGE AMOUNTS OF WATER. INHALATION: MOVE TO
FRESH AIR. INGESTION: GIVE 2 GLASSES OF WATER, INDUCE VOMITING.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:USE APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:NONE
* Accidental Release Measures *
Spill Release Procedures:FLUSH W/WATER.
*Handling and Storage *
Handling and Storage Precautions:STORE & HANDLE ACCORDING TO PACKAGED
INSTRUCTIONS.
Other Precautions:BECAUSE HEPARIN IS A MIXTURE OF ACTIVE PRINCIPLES
HAVING THE PROPERTY OF PROLONGING CLOTTING TIME OF BLOOD, IT IS
NECESSARY TO PREVENT INHALATION.
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:WHITE POWDER W/NO CHARACTERISTIC ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AS REQUIRED
Ventilation:LOCAL EXHAUST
Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS
USED.
Supplemental Safety and Health
* Product Identification *
Product ID:GREEN ROTARY
Preparer's Name:DICK KARBO
CAGE:KMADD
CAGE:KMADD
* Composition/Information on Ingredients *
Ingred Name:COPPER COMPOUND
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN
CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
* First Aid Measures *
First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA
W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
* Accidental Release Measures *
Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE
CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS.
Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:INSOLUBLE
Appearance and Odor:OILY
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOR OTHER THAN VERY SMALLL AMOUNTS, A NIOSH/MSHA
APPROVED POSITIVE PRESSURE AIR LINE WITH MASK OR A SELF CONTAINED
BREATHING APPARATUS SHOULD BE AVAILABLE FOR EMERGENCY USE.
Ventilation:USE LOCAL EXHAUST TO PREVENT HELIUM ACCUMULATION THAT WILL
Other Protective Equipment:SAFETY SHOES FOR CYLINDER HANDLING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
KEY1:G3. THIS ENTRY DESCRIBES PART B OF A 2 PART KIT. SEE PN IND A,
THIS NSN, FOR PART A DATA. MOST OF THE SAFETY INFORMATION IN THIS
MSDS IS FOR HANDLING CYLINDERS AND OPERATING HELIUM SYSTEM INVOLVI
NG FAIRLY LARGE AMOUNTS OF HELIUM. THISMATERIAL IS CONTAINED IN A
THERMAL IMAGING SYSTEM MFG BY HUGHES AIRCRAFT CO.
* Product Identification *
Product ID:HELIUM
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:HELIUM
Other REC Limits:NONE SPECIFIED
ACGIH TLV:SIMPLE ASPHYXIANT
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HELIUM IS NONTOXIC BUT THE LIBERATION
OF A LARGE AMOUNT IN A CONFINED AREA COULD DISPLACE THE AMOUNT OF
OXYGEN IN AIR NECESSARY TO SUPPORT LIFE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HEADACHE, DIZZINESS, LABORED BREATHING, AND
EVENTUAL UNCONSCIOUSNESS. BREATHING MIXTURES OF HELIUM WITH
ADEQUATE OXYGEN TO SUPPORT LIFE MODIFIES THE VOICE SOUND SO THAT IT
IS HIGHER "PITCHED".
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: MOVE TO FRESH AIR. IF NOT BREATHING GIVE CPR. IF
BREATHING DIFFICULT GIVE OXYGEN. GET MEDICAL ATTENTION. PROMPT
MEDICAL ATTENTION IS MANDATORY IN ALL CASES OF OVEREXPOSURE TO
HELIUM. RESCU E PERSONNEL SHOULD BE EQUIPPED WITH SELF-CONTAINED
BREATHING APPARATUS.
* Fire Fighting Measures *
Extinguishing Media:NONFLAMMABLE, INERT GAS. USE MEDIA SUITABLE FOR
SURROUNDING FIRE.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:FOR OTHER THAN SMALL QUANTITIES OF HELIUM,
EVACUATE ALL PERSONNEL FROM AFFECTED AREA. USE APPROPRIATE
PROTECTIVE EQUIPMENT. IF LEAK IS IN CONTAINER OR CONTAINER VALVE,
CONTACT CHEMTREC FOR EMERGENCY A SSISTANCE OR YOUR CLOSEST AIRCO
LOCATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:FOR OTHER THAN VERY SMALL AMOUNTS, USE
ONLY IN WELL-VENTILATED AREAS. STORE CYLINDERS IN COOL WELL
Other Precautions:PROTECT CONTAINERS FROM PHYSICAL DAMAGE. STORE
CYLINDERS UPRIGHT AND FIRMLY SECURED TO PREVENT FALLING. USE
PRESSURE REDUCING REGULATOR WHEN CONNECTING CYLINDER TO LOWER
PRESSURE SYSTEM. DO NOT HEAT C YLINDER TO INCREASE DISCHARGE RATE.
* Physical/Chemical Properties *
HCC:A1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, ODORLESS GAS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:FOR OTHER THAN VERY SMALL AMOUNTS, DO NOT
ATTEMPT TO DISPOSE OF RESIDUAL OR UNUSED HELIUM. RETURN IN SHIPPING
CONTAINER, PROPERLY LABELED, AND VALVE PROTECTION CAP IN PLACE TO
AIRCO FOR PROPER DISPOSA L. FOLLOW FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IN DUSTY ATMOSPHERE, USE A NIOSH APPROVED DUST
RESPIRATOR.
Ventilation:ADEQ VENT TO AVOID CHRONIC INHAL OF DUST. GEN & LOC EXHST
VENT AS REC BY GOOD MFG PRACTICES SHOULD BE SUFFICIENT(SUPDAT)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . WEAR IMPERVIOUS PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
VENT:FOR NORMAL OPERATIONS.
* Product Identification *
CAGE:SXNXC
CAGE:SXNXC
* Composition/Information on Ingredients *
Ingred Name:GUANIDINE, 1,3-DIPHENYL-; (1,3 DIPHENYLGUANIDINE).
OSHA PEL:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:SKIN CONTACT:MAY CAUSE
IRRITATION. MAY RESULT IN DEVELOPMENT OF ALLERGIC REACTION. SKIN
ABSORPTION:HARMFUL IF ABSORBED THROUGH SKIN. EYE CONTACT:MAY CAUSE
IRRITATION. INHALATION:EXPOSURE TO EXCE SSIVE CONCENTRATION OF ANY
NUISANCE DUST MAY CAUSE RESPIRATORY DISCOMFORT. INGESTION:HARMFUL
IF (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SWALLOWED. EYE IRRIT:MOD. SKIN:
NON-IRRITANT. MAY CAUSE ALLERGIC SKIN REACTION. CHRONIC:
EMBRYOTOXIC & SPERM ABNORMS IN ANIMALS, MAY CAUSE ADVERSE REPRO
EFFECTS SUCH AS BIRTH DEFECTS, MISCARR IAGES OR INFERTILITY BASED
ON ANIMAL STUDIES. MUTAGENICITY:POS IN SALMONELLA/MAMMALIAN
MICROSOME ASSAY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
EYELIDS APART DURING RINSING TO ENSURE FLUSHING OF ENTIRE SURFACE
OF EYE & LIDS W/WATER. SEEK MEDICAL ATTENTION. SKIN:WASH W/SOAP &
WATER. WASH CLOTHING BEFORE REUSE. INHAL:REMOVE TOFRESH AIR. KEEP
PERSON WARM & SEEK MEDICAL ATTENTION. INGEST:OBTAIN MEDICAL
ATTENTION IMMEDIATELY. DO NOT INDUCE VOMITING.
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:USE EYE & SKIN PROTECTION. DO NOT BREATHE
DUST. KEEP DUST TO A MINIMUM. SWEEP, SCOOP OR VACUUM DISCHARGED
MATERIAL. COLLECT & CONTAIN IN SUITABLE DISPOSAL CONTAINERS. FLUSH
AREA W/WATER TO REMOVE TRAC E RESIDUE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID BREATHING DUST OR MIST. AVOID
CONTACT W/EYES, SKIN & CLOTHING. HANDLE I/A/W GOOD INDUSTRIAL
HYGIENE & SAFETY PRACTICES.
Other Precautions:NORMAL STORAGE CONDITIONS. DO NOT CONTAMINATE
DRINKING WATER, FOOD OR FEED BY STORAGE OR DISPOSAL.
* Physical/Chemical Properties *
Solubility in Water:INSOLUBLE
Appearance and Odor:CREAM COLORED POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:PRODUCT STABLE UNDER NORMAL CONDITIONS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD:
CARBON MONOXIDE, CARBON DIOXIDE, OXIDES OF NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:WASTE DISPOSAL I/A/W MUNICIPAL, PROVINCIAL,
FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TWA OR PEL IS EXCEEDED, RESPIRATORY
PROTECTIVE EQUIPMENT MUST BE PROVIDED IAW OSHA REGULATIONS.
Ventilation:IF TWA OR PEL IS EXCEEDED, APPROPRIATE VENTILATION MUST BE
PROVIDED
Other Protective Equipment:WEAR LONG SLEEVE PROTECTIVE CLOTHING WHEN
HANDLING PRODUCT. AVOID BREATHING DUST.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
NOTE TO PHYSICIAN: PROBABLE MUSCOSAL DAMAGE MAY CONTRAINDICATE THE USE
OF GASTRIC LAVAGE. MEASURES AGAINST CIRCULATORY SHOCK, RESPIRATORY
DEPRESSION AND CONVULSION MAY BE NEEDED.
* Product Identification *
Product ID:COPPER SULFATE
Preparer's Name:DR. ARTHUR F. GOHLKE
CAGE:TENNC
CAGE:TENNC
* Composition/Information on Ingredients *
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INHALATION: IRRIATANT & SENSITIZER TO
NASAL MEMBRANES. SKIN: IRRITANT & SENSITIZER ESPECIALLY TO SOME
INDIVIDUALS. SKIN: NOT TOXIC DERMALLY. EYE: CORROSIVE TO EYE
TISSUE. INGESTION: MODERATE TOXICITY IN HUMANS ORALLY. HIGH
INTRAPERITONEAL TOXICITY.
Explanation of Carcinogenicity:NOT PROVIDED
Effects of Overexposure:INGESTION: COPPER SULFATE MAY INDUCE SEVERE
GASTROENTERIC DISTRESS (VOMITING, GASTROENTERIC PAIN, LOCAL
CORROSION & HEMORRAGES). PROSTRATION, ANURIA, HEMATURIA, ANEMIA,
INCREASE IN WHITE BLOOD CELLS, COMA, RESPIRATORY DIFFICULTIES &
CIRCULATORY FAILURE. EYES: CORROSIVE TO EYE TISSUE. CHRONIC
OVEREXPOSURE IS REPORTED TO BE SYSTEMIC EFFECT IN HUMANS WHICH
EFFECTS THE METABOLIC & EXCRETORY FUNCTION O F THE LIVER & KIDNEY.
Medical Cond Aggravated by Exposure:NOT PROVIDED
* First Aid Measures *
MIN. HOLD EYELIDS APART DURING IRRIGATION. SEND TO PHYSICIAN
IMMEDIATELY. SKIN: WASH OR SHOWER THOROUGHLY WITH WATER. REMOVE &
WASH CONTAMINA TED CLOTHES BEFORE REUSE. INHALATION: REMOVE WORKER
FROM EXPOSURE & SEEK MEDICAL AID. INGESTION: CALL PHYSICIAN OR
POISON CONTROL CENTER. DRINK 1 OR 2 GLASSES OF WATER & INDUCE
VOMITING BY TOUCHING BA CK OF THROAT WITH FINGER OR, IF AVAILABLE,
BY ADMINISTERING SYRUP OF IPECAC. DO NOT INDUCE VOMITING OR GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Extinguishing Media:COPPER SULFATE DOES NOR BURN, NOR WILL IT SUPPORT
COMBUSTION. IF STORED WITH OTHER COMBUSTIBLE PRODUCTS, USE WATER,
CO2, OR DRY CHEMICAL.
BE USED TO KEEP SUCH WATER OUT OF STREAMS OR OTHER WATER BODIES.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:CONTACT APPROPRIATE LOCAL, STATE, OR FEDERAL
POLLUTION CONTROL OFFICIALS IF WARRENTED & ESPECIALLY IF SPILLED
INTO PUBLIC WATERS. IF SPILL IS CONFINED TO USE SITE, NEUTRALIZE
WITH LIME OR SODA ASH, US E ABSORBENT & REMOVE TO APPROVED
LANDFILL.
Neutralizing Agent:SODA ASH OR LIME
*Handling and Storage *
Handling and Storage Precautions:STORE PRODUCT IN A DRY PLACE
Other Precautions:UNDER SOME USE CONDITIONS COPPER SULFATE DUIST MAY BE
IRRITATING TO THE SKIN OF SOME INDIVIDUALS. PROBLEM USE CONDITIONS
SEEM TO BE AGGRAVATED BY HIGH HUMIDITY & SWEATING WHEN COPPER
SULFATE IS APPLIE D UNDILUTED & DUST CONTACT OCCURS.
* Physical/Chemical Properties *
HCC:V7
Vapor Density:N/D
pH:4.0 @ 5% SOLN
Appearance and Odor:BLUE CRYSTALS OR POWDER, NO ODOR
Percent Volatiles by Volume:N/D
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
NONE KNOWN WHEN PRODUCT REMAINS DRY. PRODUCT READILY DISSOLVES IN
WATER. SOLUTIONS ARE CORROSIVE TO MILD STEEL. STORE SOLUTIONS IN
Stability Condition to Avoid:NONE KNOWN. PRODUCT IS HIGHLY SOLUBLE IN
WATER, BUT DOES NOT REACT WITH WATER
Hazardous Decomposition Products:NONE AT NORMAL TEMPERATURES &
RELEASED.
* Toxicological Information*
* Ecological Information *
MG/L, BLUEGILL: 1.5 MG/L. ALL VALUES ARE EXPRESSED AS COPPER
SULFATE PENTAHYDRATE. TEST WATER IS SOFT.
* Disposal Considerations *
Waste Disposal Methods:SWEEP UP CRYSTAL OR POWDERED PRODUCT & DISPOSE
OF IN AN APPROVED LANDFILL. IF PRODUCT IS IN CONFINED SOLUTION,
INTRODUCE LIME OR SODA ASH TO FORM INSOLUBLE COPPER SALTS AND THEN
* MSDS Transport Information *
Transport Information:NOT REGULATED
* Regulatory Information *
SARA
State Regulatory Information:NOT PROVIDED
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. HOWEVER,
AIR-SUPPLIED RESPIRATORS ARE REQUIRED WHILE WORKING IN CONFINED
SPACES WITH THIS PRODUCT. THE RESPIRATORY PROTECTION USE MUST
Ventilation:LOCAL EXHAUST TO PREVENT ACCUMULATION OF OXYGEN
CONCENTRATION. MECHANICAL (GENERAL) IS ACCETABLE.
Other Protective Equipment:METATARSAL SHOES FOR CYLINDER HANDLING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING CYLINDERS.
Supplemental Safety and Health
MFR:UNKNOWN. THIS MSDS WAS GENERATED USING AVAILABLE INFORMATION IN
HMIS. OXYGEN SHOULD NOT BE USED AS A SUBSTITUTE FOR COMPRESSED AIR.
EQUIPMENT TO CONTAIN OXYGEN MUST BE "CLEANED FOR OXYGEN SERVICE" .
COMPRESSED GAS CYLINDERS SHOULD NOT BE REFILLED EXCEPT BY QUALIFIED
PRODUCERS OF COMPRESSED GASES. READ LABELS.
Product ID:OXYGEN
Preparer's Name:DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:OXYGEN
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE- EYE/SKIN/ORAL:NO ADVERSE
CHEST PAIN & BREATHING DIFFICULTY. BREATHING PURE OXYGEN UNDER
PRESSURE MAY CAUSE LUNG DAMAGE & CNS E FFECTS RESULTING IN
DIZZINESS, POOR COORDINATION, VISUAL & HEARING DISTURBANCES,
UNCONSCIOUSNESS. CHRONIC- NONE.
Explanation of Carcinogenicity:OXYGEN IS NOT LISTED AS A CARCINOGEN BY
THE IARC, NTP OR OSHA.
Effects of Overexposure:COUGH, SORE THROAT, CHEST PAIN, DIZZINESS,
TINGLING SENSATION, MUSCULAR TWITCHING AND CONVULISONS. BREATHING
OXYGEN UNDER PRESSURE MAY CAUSE PROLONGATION OF ADAPTION TO
DARKNESS AND REDUCED PERIPHERAL VISION. RETINAL DAMAGE AND
THAN ATMOSPHERE PRESSURE.
Medical Cond Aggravated by Exposure:NOT KNOWN
* First Aid Measures *
First Aid:THIS PRODUCT IS A GAS AT NORMAL TEMPERATURE & PRESSURE. NO
FIRST AID IS REQUIRED FOR SWALLOWING, EYE/SKIN CONTAT. FOR
INHALATION, MOVE TO FRESH AIR. PROVIDE ARTIFICIAL RESPIRATION IF
NOT BREATHING. KE EP VICTIM WARM & AT REST. CALL A PHYSICIAN. NOTE
TO PHYSICIAN:SUPPORTIVE TREATMENT SHOULD INCLUDE IMMEDIATE
SEDATION, ANTI-CONVULSIVE THERAPY IF NEEDED & REST. DECREASE
VITAMIN E MAY INCREASE TOXICITY
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM/DRY CHEMICAL FOR
SURROUNDING FIRE. WATER IS PREFERRED EXTINGUISHER FOR CLOTHING
FIRES.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS. MOVE CONTAINERS AWAY IF POSSIBLE. STOP FLOW OF OXYGEN
WHICH IS SUPPORTING THE FIRE.
Unusual Fire/Explosion Hazard:ACCELERATES COMBUSTION. CONTACT WITH
EASILY OXIDIZABLE ORGANIC/COMBUSTIBLE MATERIALS MAY RESULT IN
IGNITION, VIOLENT COMBUSTION OR EXPLOSION.
* Accidental Release Measures *
Spill Release Procedures:STOP LEAK IF WITHOUT RISK. VENTILATE AREA OR
MOVE LEAKING CONTAINER TO WELL-VENTILATED AREA. REMOVE ALL
FLAMMABLE MATERIALS. OXYGEN MUST NEVER BE PERMITTED TO STRIKE AN
OILY SURFACE, GREASY CLOTHES, O R OTHER COMBUSTIBLE MATERIAL.
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, WELL VENTILATED AREA
AWAY FROM HEAVILY TRAFFICKED AREAS & AWAY FROM FULL/EMPTY CYLINDERS
CONTAINING FLAMMABLE PRODUCTS.
Other Precautions:HIGH PRESSURE GAS. VIGOROUSLY ACCELERATES COMBUSTION.
AVOID CONTACT WITH OILS, GREASES AND OTHER FLAMMABLE MATERIALS.
NOTE:REVERSE FLOW INTO CYLINDER MAY CAUSE RUPTURE. NEVER WORK ON A
PRESSURIZED SYS TEM. NEVER LUBRICATE USING COMBUSTIBLES.
* Physical/Chemical Properties *
HCC:G4
NRC/State Lic Num:NOT RELEVANT
Vapor Density:1.1
Spec Gravity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, ODORLESS GAS AT NORMAL TEMPERATURE AND
PRESSURE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALL FLAMMABLE MATERIALS ESPECIALLY OILS AND GREASES, COMBUSTIBLE
MATERIALS, ASPHALT
Stability Condition to Avoid:HEATING CYLINDERS TO INCREASE FLOW RATE
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:SLOWLY RELEASE INTO ATMOSPHERE, IN AN OPEN,
OUTDOORS AREA. REMOVE ALL FLAMMABLE MATERIALS FROM VICINITY.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:ADEQUATE. NO SPECIAL VENTILATION NECESSARY.
Supplemental Safety and Health
DEFINED IN THE FED HAZ SUBSTANCES LABELING ACT.PT A OF A 3 PT KT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ETHYL SILICATE
Fraction by Wt: <5.0%
* Hazards Identification *
Effects of Overexposure:MAY CAUSE EYE IRRITATION UPON CONTACT.
* First Aid Measures *
* Fire Fighting Measures *
Extinguishing Media:ALL STANDARD FIRE FIGHTING AGENTS ARE SUITABLE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:NO SPECIAL PRECAUTIONS NECESSARY. WIPE OR
SCRAPE UP TO REDUCE SLIPPING HAZARD & PUT IN A CONTAINER FOR
DISPOSAL.
*Handling and Storage *
Other Precautions:CURED RTV REQUIRES NO SPECIAL PRECAUTIONS.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE POURABLE MATERIAL, ESSENTIALLY ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:CO*2 & SIO*2 FROM THERMAL DECOMP AT
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN A LANDFILL IN ACCORDANCE W/FED.,
STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:PROPERLY FITTED HALF-MASK OR FULL FACEPIECE
RESPIRATOR, NIOSH/MSHA APPROVED.
Ventilation:SUFFICIENT.
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH HANDS BEFORE EATING/SMOKING/USING
RESTROOM. REMOVE CONTAM CLOTHES TO AVOID FLAMMABILITY HAZARD. WASH
BEFORE REUSE.
Supplemental Safety and Health
NK
* Product Identification *
Preparer's Name:MICHAEL LICHATOWICH
* Composition/Information on Ingredients *
Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Ingred Name:MINERAL SPIRITS
Other REC Limits:NONE RECOMMENDED
Ingred Name:TITANIUM DIOXIDE
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 6.0%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 3.0%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: <1.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1 MG/M3
ACGIH TLV:2.0 MG/M3
Ingred Name:PROPRIETARY INGREDIENT
Fraction by Wt: BALANCE
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: IRRITATION, TEARING, REDNESS,
BLURRED VISION, VISUAL DISTURBANCE, EYEBURN. SKIN: ABSORPTION.
INHAL: IRRIT, CNS DEPRESSION, (DIZZY, DROWSY, WEAK, FATIGUE
CONFUSION) NAUSEA, HEADACHE, VERTIGO, UNCO NSCIOUSNESS,
ASPHYXIATION. INGEST: IRRIT, ABDOMINAL PAIN, NAUSEA, VOMITING,
DIARRHEA, BLINDNESS, DEATH. TARGETS: *
Effects of Overexposure:* LIVER, KIDNEYS, CNS, SKIN, EYES, RESPIRATORY
SYSTEM & GI TRACT, & LUNGS.
* First Aid Measures *
First Aid:INHAL: GET FRESH AIR. IF BREATHING IS STOPPED GIVE ARTIFICIAL
RESPIRATION, GET MED AID ASAP. SKIN: WASH W/SOAP & WATER. EYE:
GET IMMED MED AID. DONT WEAR CONTACTS WHEN WORKING W/PRODUCT.
INGEST: INDUCE VOMIT IMMED. GIVE 1-2 GLASSES WATER, STICK FINGER
DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.
GET IMMED MED AID.
* Fire Fighting Measures *
Flash Point Method:TCC
Autoignition Temp:Autoignition Temp Text:NE
Lower Limits:0.8
Extinguishing Media:DRY CHEMICAL, FOAM, CO2.
Fire Fighting Procedures:USE SCBA W/FULL FACE PIECE IN POSITIVE
PRESSURE MODE/PROTECTIVE CLOTHES. USE WATER TO COOL CLOSED
CONTAINERS. PREVENT PRESSURE BUILD-UP/AUTOIGNIT/EXPLOSION.
Unusual Fire/Explosion Hazard:KEEP CONTAINER TIGHTLY CLOSED. KEEP FROM
IGNITS. APPLIC TO HOT SURFACE REQUIRES SPECIAL PRECAUTIONS. DECOMP
PRODUCTS HAZARDOUS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITS. AVOID VAPOR BREATHING/SKIN
CONTACT. ABSORB/SHOVEL INTO DRUMS AND DISPOSE. DIKE.
*Handling and Storage *
Handling and Storage Precautions:DON'T STORE IN HIGH HEAT/NEAR IGNITS.
KEEP CONTAINER CLOSED WHEN NOT IN USE. AVOID ROUGH HANDLING.
Other Precautions:CONTAINERS HAZARDOUS WHEN EMPTY. DON'T WELD/FLAME CUT
ON EMPTY DRUM. SHOCK FROM DROPPING MAY SPLIT CONTAINER.
* Physical/Chemical Properties *
Decomp Temp:Decomp Text:NE
Vapor Density:>AIR.
pH:NA
Evaporation Rate & Reference:SLOWER THAN ETHER.
Solubility in Water:YES
Appearance and Odor:LIQUID, ODOR OF SOLVENTS.
Corrosion Rate:MINIMAL.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXICIZERS.
Stability Condition to Avoid:HIGH TEMPERATURES
* Disposal Considerations *
Waste Disposal Methods:ACCORDING TO FEDERAL, STATE, LOCAL REGS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE HYDROCARBON VAPOR CANISTER OR SUPPLIED AIR
RESPIRATOR IN CONFINED AREAS.
ADEQUATE VENTILATION. MECHANICAL: EXPLOSION PROOF EQUIPMENT.
Other Protective Equipment:USE CHEMICAL RESISTANT APRON OR CLOTHING.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:FRED ARMSTRONG
* Composition/Information on Ingredients *
Ingred Name:STODDARD SOLVENT
Ingred Name:SUPER HIFLASH NAPTHA, PETROLEUM SOLVENT
Fraction by Wt: 6%
Ingred Name:PM ACETATE, (ESTER SOLVENT)
Fraction by Wt: 9%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Health Hazards Acute and Chronic:OVEREXPOSURE-NAUSEA, HEADACHE,
DIZZINESS CAUSED BY OVER INHALATION.
Effects of Overexposure:OVEREXPOSURE-NAUSEA, HEADACHE, DIZZINESS CAUSED
IRRITATING TO EYES & RESPIRATORY TRACT, ARE ANESTHETIC & MAY HAVE
OTHER CENTRAL NERVOUS SY STEM EFFECTS.
Medical Cond Aggravated by Exposure:NONE GENERALLY KNOWN.
* First Aid Measures *
SUBSIDES. IF IRRITATION PERSISTS, CALL PHYSICIAN. SKIN CONTACT:
REMOVE CONTAMINATED CLOTHING & WASH THOROUGHLY WITH SOAP & WATER.
INHALATIO N: IF OVERCOME BY VAPORS, REMOVE TO FRESH AIR, CALL A
PHYSICIAN. INGESTION: DO NOT INDUCE VOMITING, CALL A PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:0.7
Extinguishing Media:CARBON DIOXIDE, FOAM, WATER FOG, DRY CHEMICAL.
Fire Fighting Procedures:USE AIR SUPPLIED BREATHING EQUIPMENT. COOL
ENCLOSED CONTAINERS WITH WATER SPRAY. AVOID BREATHING VAPORS OR
FUMES.
Unusual Fire/Explosion Hazard:IF LEAK OR SPILL HAS IGNITED, USE WATER
SPRAY TO DISPERSE THE VAPORS FROM FIRE FIGHTERS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. KEEP FROM HEAT,
SPARKS & OPEN FLAME. ADD ABSORBENT (SAND, EARTH, SAWDUST) TO SPILL.
VENTILATE AREA (OPEN WINDOWS, DOORS). LARGE SPILL: KEEP FROM
ENTERING SEWERS & WATERCOU RSES BY DIKING. ADVISE AUTHORITIES IF
DOES ENTER.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM IGNITION SOURCES. KEEP
IN COOL, DRY, WELL VENTILATED AREAS. AVOID DIRECT SUNLIGHT &
EXTREME TEMPERATURES, HOT OR COLD.
Other Precautions:AVOID EYE &/OR SKIN CONTACT. INHALATION &/OR
INGESTION OF MISTS, SPRAY OR VAPORS. AVOID BREATHING SANDING OR
BLASTING DUST.
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE
Appearance and Odor:MEDIUM DARK GRAY LIQUID WITH KEROSENE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CAN REACT WITH OXIDIZING MATERIAL WHEN HEATED TO DECOMPOSITION.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:ASSURE CONFORMITY WITH APPLICABLE DISPOSAL
REGULATIONS. DISPOSE OF ABSORBED MATERIAL AT AN APPROVED DISPOSAL
SITE OR FACILITY. DISPOSE IN CONFORMITY WITH STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:MSHA/NIOSH APPROVED ORGANIC VAPOR CARTRIDGE
Ventilation:LOCAL EXHAUST PREFERABLE,MECHANICAL ACCEPTABLE
Other Protective Equipment:EYE WASH,SAFETY SHOWER
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)
Fraction by Wt: 6-7%
* Hazards Identification *
Effects of Overexposure:INHAL,SKIN,EYE:IRRIT;NO ACUTE DATA
AVAIL.RESIDUAL TDI DOES POSSESS IRRITANCY & SENSITIZATION POTENT
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR.SKIN:WASH W/ SOAP AND
VOMITING.GET MEDICAL ATTN IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:CO*2,DRY CHEMICAL,WATER SPRAY,FOAM
Fire Fighting Procedures:USE SCBA TO PROTECT AGAINST INHALATION OF
CYANATE VAPORS
Unusual Fire/Explosion Hazard:NONE PER MFR.
* Accidental Release Measures *
Spill Release Procedures:SOAK UP W/ ABSORBENT MATERIAL.TRANSFER TO OPEN
CONTAINERS OUTSIDE OR IN WELL VENTILATED AREA.SOAK W/ DILUTE
AMMONIUM HYDROXIDE.ALLOW TIME FOR REACTION TO BE COMPLETE BEFORE
DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT W/ SKIN & EYES,STORE IN
CLOSED CONTAINER IN COOL DRY PLACE.SEAL CONTAINERS W/ A DRY
NITROGEN BLANKET
Other Precautions:HAZARD CLASSIFICATION:NOT REGULATED
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NIL
Appearance and Odor:HONEY COLORED LIQUID,SLIGHTLY PUNGENT ODOR
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
MOISTURE,STRONG OXIDIZERS,ALCOHOLS,AMINES.
Stability Condition to Avoid:CONTACT WITH WATER OR HUMID AIR GENERATES
PRESSURE
Hazardous Decomposition Products:CO,CO*2,OXIDES OF NITROGEN,SMALL
AMOUNTS OF HCN(BURN CONDIT)
* Disposal Considerations *
Waste Disposal Methods:BURY IN APPRVD LANDFILL IN ACCORDANCE W/
FEDERAL,STATE AND FEDERAL REGULATION REGARDING POLYMERIC WASTE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE CARTRIDGES PLUS PARTICULATE FILTERS.
Ventilation:MECH: APPROVED CLASS D EXPLOSION-PROOF MOTORS/SWITCHES
Other Protective Equipment:SAFETY SHOWER & EYE BATH.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)
Fraction by Wt: 6%
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
* Hazards Identification *
Effects of Overexposure:ANESTHESIA/HEADACHE/NAUSEA/DIZZINESS/BREATHING
VAPOR WILL BE IRRITATION TO NOSE/THROAT/SKIN/EYES.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR/RESTORE BREATHING IF
REQUIRED. SKIN: REMOVE WITH SOAP & WATER. EYES: FLUSH WITH WATER.
GET MEDICAL CARE IF DISCOMFORT PERSISTS. INGESTION: DO NOT INDUCE
VOMITING. CALL PHYSICIAN IMMEDIATELY.
* Fire Fighting Measures *
Lower Limits:1.0%
Extinguishing Media:EXCLUDE AIR, FOAM, CO2, OR DRY CHEMICAL
Fire Fighting Procedures:VAPOR FORMS EXPLOSIVE MIXTURE W/AIR
UPPER/LOWER EXPLOSIVE.
Unusual Fire/Explosion Hazard:DO NOT USE WATER, EXCLUDE AIR. CONSULT
LOCAL FIRE MARSHAL.
* Accidental Release Measures *
Spill Release Procedures:AVOID HEAT, OPEN FLAME OR SPARK SOURCES.
PROVIDE ADEQUATE VENTILATION.
*Handling and Storage *
Handling and Storage Precautions:AVOID HEAT, OPEN FLAME & SPARK
SOURCES. AVOID SPLASH FILLING. USE ONLY IN A WELL VENTILATED AR.
Other Precautions:WARNING! FLAMMABLE. AVOID BREATHING OF VAPOR/SPRAY
MIST. CLOSE CONTAINER AFTER EACH USE. DO NOT TRANSFER TO BOTTLES OR
OTHERNLABELED CONTAINERS. KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:AVOID CONTAMINATED WITH STRONG ALKALIES.
Hazardous Decomposition Products:CO, CO2
Conditions to Avoid Polymerization:AVOID HEAT, OPEN FLAME OR SPARK
SOURCES
* Disposal Considerations *
Waste Disposal Methods:FLUSH WITH WATER TO AN OPEN WELL VENTILATED
AREA. USE OIL SEWER IF AVAILABLE. REMOVE TO CONTAINER.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
Other REC Limits: 5 MG/M3 TOTAL DUST
OSHA PEL: NONE ESTABLISHED
ACGIH TLV: 5MG/M3, 8HR TWA
-----------------------------
< Wt: 4.
-----------------------------
OSHA PEL: NONE ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ADDITIONAL HEALTH EFFECTS: READ "ZYTEL" MOLDING GUIDE
BEFORE USING THIS PRODUCT. POLYHEXAMETHYLENE ADIPAMIDE: IN GENERAL SKIN
ER, A SMALL PERCENTAGE OF SUBJECTS MAY RESPOND TO PROLONGED CONTACT WITH
REDNESS OF SKIN. SIGNIFICANT SKIN PERMEATION AND SYSTEMIC TOXICITY AFTER
CONTACT APPEARS UNLIKELY. THERE ARE NO REPORTS OF HUMA N SENSITIZATION. IF
PAIN OR BLURRED VISION MAY RESULT. FIBERGLASS: THE MECHANICAL ACTION OF THE
SHARP FIBERS FROM FIBERGLAS S MAY (SIGNS & SYMPTOMS OF OVEREXPOSURE)
Explanation Of Carcinogenicity: NONE OF COMPONENTS PRESENT IN THIS MATERIAL AT
CONCENTRATIONS EQUAL TO OR GREATER THAN 0.1% ARE LISTED BY IARC, NTP, OSHA OR
ACGIH AS A CARCINOGEN.
Signs And Symptions Of Overexposure: HEALTH HAZARDS ACUTE AND CHRONIC (CONT):
CAUSE SKIN IRRITATION WITH DISCOMFORT OR RASH. INHALATION OF FIBERGLASS
PARTICLES MAY CAUSE IRRITATION OF THE UPPER RESPIRATORY PASSAGES, WITH
COUGHING AND DIS COMFORT. RESULTS FROM EPIDEMIOLOGY STUDIES SUGGEST NO LINK
BETWEEN FIBERGLASS EXPOSURE AND CANCER. ONE EPIDEMIOLOGY STUDY INDICATES
SLIGHT INCREASE IN LUNG CANCER DEATHS. THE EVIDENCE THAT FIBERGLASS IS
RELATED TO THESE INCREASED LUNG CANCER DEATHS IS CONSIDERED WEAK.
Medical Cond Aggravated By Exposure: INDIVIDUALS WITH PRE-EXISTING DISEASES OF
LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO TOXICITY OF EXCESSIVE EXPOSURES.
First Aid: INHALATION: NO SPECIFIC INTERVENTION IS INDICATED AS THE COMPOUND IS
NOT LIKELY TO BE HAZARDOUS BY INHALATION. CONSULT A PHYSICIAN IF NECESSARY.
IF EXPOSED TO FUMES FROM OVERHEATING OR COMBUSTION, MOV E TO FRESH AIR.
CONSULT PHYSICIAN IF SYMPTOMS PERSIST. SKIN CONTACT: THE COMPOUND IS NOT
LIKELY TO BE HAZARDOUS BY SKIN CONTACT, BUT CLEANSING THE SKIN AFTER EACH USE
IS ADVISABLE. IF MOLTEN POLYMER GETS ON SKIN, COOL RAPIDLY WITH COLD WATER.
DO NOT ATTEMPT TO PEEL POLYMER FRM SKIN. OBTAIN MEDICAL TREATMENT FOR THERMAL
BURN. EYE CONTACT: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF
W ATER FOR (SUPPLEMENTAL SAFETY & HEALTH)
*
Handling and Disposal
*
Spill Release Procedures: SAFEGUARDS (PERSONNEL): NOTE: REVIEW FIRE FIGHTING
MEASURES/HANDLING (PERSONNEL) SECTIONS BEFORE PROCEEDING WITH CLEAN-UP. USE
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING CLEAN-UP. SPILL CLEAN UP:
SWEEP UP TO AVOID SLIPPING HAZARD.
Waste Disposal Methods: PREFERRED OPTIONS: RECYCLING, INCINERATION WITH ENERGY
RECOVERYAND LANDFILL. HIGH FUEL VALUE OF PRODUCT MAKES OPTION OF INCINERATION
VERY DESIRABLE FOR MATERIAL THAT CANNOT BE RECYCLED. TREATMENT, STO RAGE,
TRANSPORTATION AND DISPOSAL MUST BE IN ACCORDANCE WITH APPLICABLE FEDERAL,
STATE/PROVINCIAL A ND LOCAL REGULATIONS.
Handling And Storage Precautions: HANDLING: SEE FIRST AID AND PERSONAL
PROTECTIVE EQUIPMENT SECTIONS. STORAGE: STORE IN COOL, DRY PLACE. KEEP
CONTAINERS TIGHTLY CLOSED TO PREVENT MOISTURE ABSORPTION AND CONTAMINATION.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: WATER, FOAM, DRY CHEMICAL, CO2.
Fire Fighting Procedures: KEEP PERSONNEL UPWIND OF FIRE. WEAR SELF-CONTAINED
BREATHING APPARATUS (NIOSH APPROVED - FP N).
Unusual Fire/Explosion Hazard: LARGE MOLTEN MASSES MAY IGNITE SPONTANEOUSLY IN
AIR. WATER QUENCHING OF SUCH MASSES IS GOOD PRACTICE. HAZARDOUS GASES/VAPORS
PRODUCED IN FIRE ARE AMMONIA, CARBON MONOXIDE, SMALL AMOUNTS OF HYDROGEN CY
ANIDE, AND ALDEHYDES.
*
*
Respiratory Protection: A NIOSH APPROVED AIR PURIFYING RESP WITH AN ORGANIC
VAPOR CARTRIDGE WITH A DUST/MIST FILTER WHEN AIRBORNE CONCENTRATIONS EXPECTED
TO EXCEED EXPOSURE LIMITS. USE POSITIVE-PRESSURE AIR SUPPLIED RESP IF ANY
POTENTIAL FOR UNCONTROLLED RELEASE, EXPOS LEVELS NOT KNOWN OR ANY OTHER
CIRCUMSTANCES WHERE AIR-PURIFYING RESPIRATORS MAY NOT PROVIDE ADEQUATE
PROTECTION.
Ventilation: USE LOCAL EXHAUST TO COMPLETELY REMOVE VAPORS, FUMES AND
PLASTICIZER LIBERATED DURING HOT PROCESSING FROM THE WORK AREA.
HYGENIC PRACTICES)
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). IF THERE IS POTENTIAL FOR CONTACT WITH HOT / MOLTEN
MATERIAL, WEAR HEAT RESISTANT CLOTHING AND FOOTWEAR.
FOR EYE AND FACE CONTACT DUE TO SPLASHING OR SPRAYING OF MOLTEN MATERIAL.
PHYSICIAN. INGESTION: NO SPECIFIC INTERVENTION IS INDICATED AS COMPOUND IS
NOT LIKELY TO BE HAZARDOUS BY INGESTION. CONSULT A PHYSICIAN IF NECESSARY.
*
Physical/Chemical Properties
*
Solubility in Water: INSOLUBLE
Appearance and Odor: GRANULES, NO ODOR.
Percent Volatiles by Volume: CA 1%- WATER
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: STABLE AT NORMAL TEMPERATURES AND STORAGE
Materials To Avoid: INCOMPATIBLE OR CAN REACT WITH STRONG ACIDS, OXIDIZING
AGENTS.
Hazardous Decomposition Products: CYCLOPENTANONE, CARBON MONOXIDE, ALDEHYDES
AND AMMONIA.
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
EXPOSURE BY INGESTION TO HIGH DOSES CAUSED DECREASED BODY WEIGHT. LONG-TERM
EXPOSURE CAUSED NO SIGNIFICANT TOXICOLOGICAL EFFECTS. REPEATED INHALATION
EXPOSURE CAUSED HISTOPATHOLOGICAL CHANGES OF THE LUNGS, & KIDNEYS. IN
AVAILABLE TO DEFINE DEVELOPMENTAL, REPRODUCTIVE OR MUTAGENIC HAZARDS.
FIBERGLASS: SKIN IRRITATION AND MILD EYE IRRITATION OCCURRED IN ANIMALS, BUT
EFFECTS ATTRIBUTED TO MECHANICAL DAMAGE RATHER THAN CHEMICAL (TRANSPORT
INFO)
*
Ecological Information
*
Ecological: AQUATIC TOXICITY: NO INFO AVAILABLE. TOXICITY EXPECTED LOW BASED ON
INSOLUBILITY IN WATER. DO NOT DISCHARGE TO PONDS/STREAMS/LAKES/SEWERS.
*
*
Transport Information: SHIPPING INFO: DOT-PROPER SHIPPING NAME: NOT REGULATED.
TDG: NOT REGULATED. TOXICOLOGICAL INFO (CONT) EFFECT. THE EFFECTS IN
MICE FROM SINGLE EXPOS BY INTRATRACHAEL INSTILLATION W/FIBERGLASS INCL
INFLAMMATORY RESPONSE. REPEATED INHAL EXPOS INVOKED PULMONARY MACROPHAGE
REACTIONS SIMILAR TO BIOLOGICALLY INERT DUSTS. TESTS IN SOME ANIMALS
DEMONSTRATE CARCINOGENIC ACTIVITY. STUDIES WERE BY ARTF I
MPLANTATION/INJECTION OF FINE GLASS FIBERS INTO CHEST/ABDOMINAL
CAVITY/TRACHEA & JUDGED TO BE IRRELEVANT TO INDUST. EXPOS. CHRONIC INHAL
EXPOS OF ANIMALS AT LOW CONCENTRATIONS PRODUCED MINIMAL FIBROSI S IN (STATE
REG)
*
Regulatory Information
*
Sara Title III Information: MATERIAL IS NOT KNOWN TO CONTAIN TOXIC CHEMICALS
Federal Regulatory Information: TSCA INVENTORY STATUS: ALL COMPONENTS IN
COMPLIANCE WITH TSCA INVENTORY REQUIREMENTS.
State Regulatory Information: STATE RIGHT-TO-KNOW LAWS: NO SUBSTANCES ON STATE
HAZ SUBST LIST PRESENT AT CONCENTRATION OF 1% OR MORE. FOR SPECIAL HAZ SUBST:
NONE KNOWN. SUBST ON NEW JERSEY WORKPLACE HAZ SUBST LIST PRESENT AT CONCE
NTRATION OF 1% OR MORE (0.1% FOR SUBSTANCES ID'D AS CARCINOGENS, MUTAGENS OR
TERATOGENS): NONE KNOWN. TRANSPORT INFO (CONT): ONE STUDY & NO
ADVERSE EFFECTS IN DIFFERENT STUDY. NO ANIMAL TEST REP ORTS AVAIL TO DEFINE
MUTAGENIC/DEVELOPMENTAL/REPRODUCTIVE HAZARDS. RESPONSIBILITY FOR MSDS: J.
*
Other Information
*
Other Information:: HEALTH -2, FIRE -1, REACTIVITY -0. EXPOSURE LIMITS: "ZYTEL"
TOTAL DUST. 5 MG/M3, 8 HR TWA, RESPIRABLE DUST. SHORT GLASS FIBERS: AEL
(DUPONT)-5 MG/M3 TOTAL DUST-8 HR TWA, NON-R ESPIRABLE FIBER (>3 MICRONS IN
DIAMETER) NON-FIBROUS PARTICULATE. AEL IS DUPONT'S ACCEPTABLE EXPOSURE LIMIT.
WHERE GOVERNMENTALLY IMPOSED OCCUPATIONAL EXPOS LIMITS WHICH ARE LOWER THAN
AEL ARE IN EFFE CT, SUCH LIMITS SHALL TAKE PRECEDENCE.
*
HAZCOM Label
*
Company Name: DUPONT E I DE NEMOURS AND CO INC, POLYMER PRODUCT-TEFLON CO.
Label Required IND: Y
Status Code: A
Origination Code: F
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: MAY CAUSE SKIN IRRITATION WITH DISCOMFORT OR
RASH. PROLONGED CONTACT MAY CAUSE REDNESS OF SKIN . SIGNIFICANT SKIN
PERMEATION AND SYSTEMIC TOXICITY AFTER CONTACT APPEARS UNLIKELY. THERE ARE NO
R EPORTS OF HUMAN SENSITIZATION. IF PARTICLES CONTACT THE EYE, MECHANICAL
IRRITATION WITH TEARING, PAIN OR BLURRED VISION MAY RESULT. INHALATION OF
FIBERGLASS PARTICLES MAY CAUSE IRRITAION OF THE UPPE R RESPIRATORY PASSAGES
WITH COUGHING AND DISCOMFORT. CHRONIC: NONE SPECIFIED BYMANUFACTURER (FP N)
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:LICENSED NIOSH APPROVED RESPIRATOR IF
CONCENTRATION HI.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:V HAGEMAN
* Composition/Information on Ingredients *
Ingred Name:ETHANOL, 2-ETHOXY-, ACETATE; (2-ETHOXYETHYL ACETATE)
(EGEEA)
ACGIH TLV:S, 5 PPM
Ingred Name:POLYMERS
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:2(3H)-FURANONE, DIHYDRO-; (BUTYROLACTONE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PROPANE
ACGIH TLV:ASPHYXIANT
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:MODERATELY TOXIC.
EYE:IRRITATION. SKIN:IRRITATION. INGESTION:MODERATELY TOXIC.
CHRONIC:NONE LISTED BY MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
PHYSICIAN. SKIN:WASH WITH SOAP AND WATER. INHAL:FRESH AIR, OXYGEN,
ARTIFICIAL RESPIRATION - CONSULT PHYSICIAN. INGEST:CONSULT
PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:OC
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:HEAT & FLAME MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:PICK UP WITH INERT ABSORBENT MATERIAL - STORE
IN METAL CONTAINER FOR DISPOSAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY AREA AWAY FROM
STRONG OXIDIZERS.
Other Precautions:AVOID SKIN CONTACT - ESPECIALLY REPEATED OR
PROLONGED.
* Physical/Chemical Properties *
Vapor Pres:<3
Vapor Density:4.3
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:SLIGHT
Appearance and Odor:YELLOW VISCOUS LIQUID - SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HIGH TEMPERATURES.
Hazardous Decomposition Products:CO, CO*2.
* Disposal Considerations *
Waste Disposal Methods:LICENSED INCINERTOR. DISPOSAL MUST BE I/A/W
FEDERAL, STATE & LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO SPECIAL REQUIREMENT.
Ventilation:ANY COMBINATION OF LOCAL AND GENERAL VENTILATION, TO DRAW
FUMES AWAY FROM WORKERS.
Other Protective Equipment:PROTECTIVE CLOTHING, SHOES, EYE WASH STATION
AND SAFETY SHOWERS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
CAGE:HUNTI
CAGE:HUNTI
* Composition/Information on Ingredients *
Ingred Name:BENZOYL PEROXIDE (SARA III)
OSHA PEL:5 MG/M3
Ingred Name:NON-HAZARDOUS INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL OR FATAL IF SWALLOWED!
IRRITANT WHEN IN CONTACT WITH EYES OR WITH OPEN, ABRADED SKIN.
TRACE AMOUNTS OF ETHYLENE OXIDE, A SUBSTANCE WHICH MAY BE A HUMAN
CARCINOGEN AND A REPRODUCTIVE TOXICANT, MAY BE CONTAINED IN THIS
PRODUCT. THE LEVEL IN THIS PRODUCT DOES NOT CONSTITUTE A
SIGNIFICANT RISK.
Explanation of Carcinogenicity:
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:EYES: FLUSH PROMPTLY WITH COPIOUS AMOUNTS OF WATER FOR AT
SOAP AND WATER. REMOVE CONTAM CLOTH AND SEEK MED ATTN. INGEST:
RINSE MOUTH. DRINK A GLASS FULL OF WATER OR MILK. IFDISCOMFORT
PERSISTS, SEEK MED ATTN. INHAL: REMOVE TO FRESH AIR. SUPPORT
BREATHING. GIVE (O2/ARTF RESP).
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:DRY CHEMICAL, FOAM AND CO2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT TO AVOID INHALATION OF SMOKE AND VAPOR. COOL
SURROUNDING AREA WITH WATER.
Unusual Fire/Explosion Hazard:IF EXPOSED TO ELEVATED TEMPERATURE FOR
EXTENDED LENGTH OF TIME AN EXPLOSIVE DECOMPOSITION MAY OCCUR.
* Accidental Release Measures *
Spill Release Procedures:EXTINGUISH ALL SOURCES OF FLAME AND IGNITION.
ABSORB WITH INERT MATL SUCH AS VERMICULITE OR SAND. SWEEP UP AND
COLLECT IN CNTRS TO DISPOSE AS SOLID WASTE. WASH AREA WITH
TRI-SODIUM PHOSPHATE AND WATER .
Neutralizing Agent:
*Handling and Storage *
KEEP AWAY FROM SOURCES OF HEAT AND IGNITION. USE EXPLOSION PROOF
EQUIPMENTS.
Other Precautions:OPEN CONTAINERS SLOWLY TO RELIEVE ANY INTERNAL
PRESSURE. USE WITH ADEQUATE VENTILATION. KEEP OUT OF REACH OF
CHILDREN!
* Physical/Chemical Properties *
HCC:V4
Boiling Pt:B.P. Text:DECOMPOSES
Vapor Density:<1
Spec Gravity:1.2
Evaporation Rate & Reference:FASTER THAN DIETHYL ETHER
Appearance and Odor:PIGMENTED PASTE.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
STRONG ACIDS, STRONG ALKALIS, STRONG OXIDIZERS, REDUCING AGENTS,
MINERAL ACIDS, METAL SALT CATALYSTS.
Stability Condition to Avoid:MATL IS UNSTABLE IF EXPOSED TO TEMPS
TO HEAT/FLAME.
Hazardous Decomposition Products:
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE, AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH-APPROVED RESPIRATOR EXPOSURE IS >TLV.
USE EITHER AN ATMOSPHERE-SUPPLYING RESPIRATOR OR AN AIR-PURIFYING
RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:EXPLOSION-PROOF GENERAL VENTILATION MAY HAVE TO BE
SUPPLEMENTED BY LOCAL EXHAUST TO KEEP <TLV IN WHERE VAPORS ESCAPE.
Other Protective Equipment:FULL PROTECTIVE CLOTHING.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
NOTE TO PHYSICIAN: IF VICTIM IS A CHILD, GIVE 1 GLASS OF WATER & 1
TABLESPOON OF SYRUP OF IPECAC. IF LOSS OF GAG REFLEX, CONVULSIONS
OR UNCONSCIOUSNESS OCCUR BEFORE EMESIS, GASTRIC LAVAGE MAY BE INDIC
ATED.
* Product Identification *
Preparer's Name:BARYY JOHNSON
CAGE:AMFUE
CAGE:AMFUE
* Composition/Information on Ingredients *
Ingred Name:ADHESIVE (MEK BASED)
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION,
DEFATTING, DRYNESS & DERMATITIS. INHALATION: IRRITATION TO NOSE,
THROAT RESPIRATORY TRACT, CENTRAL NERVOUS SYSTEM DEPRESSION &
BREATHING DIFFICULTY. INGESTION: TOXI C, HARMFUL, CENTRAL NERVOUS
SYSTEM DEPRESSION, UNCONSCIOUSNESS & DROWSY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION, DEFATTING,
DRYNESS & DERMATITIS. INHALATION: IRRITATION TO NOSE, THROAT,
RESPIRATORY TRACT, CENTRAL NERVOUS SYSTEM DEPRESSION & BREATHING
DIFFICULTY. INGESTION: TOX IC, HARMFUL, CENTRAL NERVOUS SYSTEM
DEPRESSION, UNCONSCIOUSNESS & DROWSY.
Medical Cond Aggravated by Exposure:EYE, SKIN & RESPIRATORY DISORDERS
* First Aid Measures *
INHALATION: REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEEDED.
INGESTION: DRINK 2 GLASSES OF WATER & INDUCE VOMITING BY GIVING 2
TABLE SPOONS S YRUP OF IPECAC OR BY TOUCHING FINGER TOBACK OF
VICTIM'S THROAT & KEEP VICTIM'S HEAD BELOW HIPS. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS/DROWSY PERSON. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.8%
Extinguishing Media:WATER (FOG), ALCOHOL FOAM, DRY CHEMICAL & CO2
Fire Fighting Procedures:FLAMMABLE. EVACUATE AREA. FULL PROTECTIVE
CLOTHING, INCLUDING SELF-CONTAINED BREATHING APPARATUS. COOL FIRE
EXPOSED CONTAINERS W/WATER.
Unusual Fire/Explosion Hazard:CONTAINERS EXPOSED TO INTENSE HEAT FROM
FIRES SHOULD BE COOLED W/WATER TO PREVENT VAPOR PRESSURE BUILD-UP
WHICH COULD RESULT IN CONTAINER RUPTURE.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. VENTILATE
AREA. SMALL SPILLS MAY BE COLLECTED W/ABSORBENT MATERIALS & PLACED
IN NON-LEAKING CONTAINERS. LARGE SPILL SHUT OFF LEAK IF SAFE TO DO
SO. DIKE & CONTAIN. S OAK UP RESIDUE W/AN ABSORBENT SUCH AS
CLAY/SAND.
*Handling and Storage *
Handling and Storage Precautions:DON'T CUT/DRILL/GRIND/WELD/PERFORM
SIMILAR OPERATIONS ON/NEAR CONTAINERS. STATIC ELECTRICITY MAY
ACCUMULATE & CREATE FIRE HAZARD. NO SMOKING.
Other Precautions:VAPOR MAY ACCUMULATE & TRAVEL TO IGNITION SOURCES
DISTANT FROM THE HANDLING SITE; FLASH-FIRE CAN RESULT. CONTAINERS
MAY BE HAZARDOUS WHEN EMPTY/CAN CONTAIN EXPLOSIVE VAPORS. AVOID
CONTACT W/SKIN & EYE S. GROUND/BOND CONTAINER/EQUIPMENT.
* Physical/Chemical Properties *
HCC:F2
Evaporation Rate & Reference:(N-BU AC = 1): 4.6
Solubility in Water:APPRECIABLE
Appearance and Odor:BLACK VISCOUS LIQUID W/KETONE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS & FLAME
Hazardous Decomposition Products:CO & UNIDENTIFIED ORGANIC COMPOUNDS
* Disposal Considerations *
Waste Disposal Methods:REFER TO LATEST EPA OR STATE REGULATIONS
REGARDING PROPER DISPOSAL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WELL VENTED AREA MAY NOT REQUIRE USE OF RSPRTR.
RESTRICTED VENTILATION:CHEM CARTRIDGE RSPRTR MAY BE REQUIRED.
SPRAY:USE MECH PREFILTER. CONFINED AREA:USE AIR SUPPLIED RSPRTR. IF
OVER TLV USE PROPERLY FITTED RSPRTR WITH PROTECTION FACTOR
Ventilation:GEN DILUTE/LOCAL EXHAUST IN VOL/PATTERN TO KEEP CONCENTRATE
OF HAZARD INGRED BELOW LOWEST LIMITS. REMOVE DECOMP PRODUCTS
Other Protective Equipment:AS REQUIRED TO PREVENT SKIN CONTACT. SEE
* Product Identification *
Preparer's Name:W.A. ELLISON
CAGE:PRATT
CAGE:PRATT
* Composition/Information on Ingredients *
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/CU.M.
ACGIH TLV:1 MG/CU.M.
Ingred Name:ISOBUTYL ACETATE (SARA III)
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
Fraction by Wt: 5%
Ingred Name:NITROCELLULOSE
Other REC Limits:NONE SPECIFIED
Ingred Name:ISOBUTYL ALCOHOL (SARA III)
Ingred Name:TITANIUM DIOXIDE
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
Ingred Name:DI-SEC-OCTYL PHTHALATE (DI-2-ETHYLHEXYL-PHTHALATE)(SARA
III)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Other REC Limits:LFL 1.0 UFL 6.0
CALCULATED
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:LEAD-SEVERE DAMAGE TO BLOOD
FORMING,NERVOUS,URNINARY,REPRODUCTIVE SYSTEM,LOSS OF
APPETITE,METALLIC
TASTE,ANXIETY,CONSTIPATE,NAUSEA,WEAK,INSOMNIA,HEADACHE,MUSCLE/JOINT
PAIN,TREMORS,NUMBNESS,DIZZINESS,H YPER ACTIVE,COLIC.POSSIBLE
PERMANENT BRAIN & NERVOUS SYST DAMAGE, MISUSE BY CONCENTRATE/INHALE
MAY BE HARMFUL OR FATAL
Explanation of Carcinogenicity:DI(2-ETHYLHEXYL)PHTHALATE IS LISTED A
POTENTIAL CARCINOGEN BY NTP. CHROMATES ARE LISTED A CARCINOGEN. SEE
FILE FOR INFO
Effects of Overexposure:SWALLOW:CAN CAUSE GASTRO IRRIT, NAUSEA &
VOMITING. ASPIRATION INTO LUNGS MAY CAUSE CHEM PNEUMONITIS WHICH
CAN BE FATAL. INHALED:NOSE OR THROAT IRRIT. HIGH CONCENTRATE MAY
CAUSE ACUTE CENTRAL NERVOUS S YSTEM DEPRESSION CHARACTERIZED BY
HEADACHES, DIZZ, NAUSEA & CONFUSION. EYES: IRRIT. SKIN:MAY CAUSE
DEFATTING OR IRRIT.
Medical Cond Aggravated by Exposure:PREXISTING KIDNEY CONDITIONS MAY BE
AGGRAVATED BY EXPOSURES TO LEAD.
* First Aid Measures *
First Aid:SWALLOW:DO NOT INDUCE VOMIT. CALL PCC/HOSPITAL/PHYSICIAN
IMMED. INHALED:REMOVE TO FRESH AIR IMMED. IF BREATH STOPPED, GIVE
CPR. KEEP WARM/QUIET. GET MED ATTN IMMED. EYES:FLUSH W/H2O, LIFTING
AFFECTED AREA W/SOAP & H2O. OBTAIN MED ATTN IF IRRIT PERSIST. NOTE
TO PHYSICIAN:DIRECT TREATMENT AT CONTROL OF SYMPTOMS & CLINICAL
CONDITIONS.
* Fire Fighting Measures *
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS DESIGNED FOR
FLAMMABLE LIQUID FIRES. POLYMER FOAM IS PREFERRED FOR LARGE FIRES.
Fire Fighting Procedures:USE WATER TO COOL EXPOSED CONTAINERS TO
PREVENT PRESSURE BUILD-UP/AUTO-IGNITE/EXPLOSION FROM EXTREME HEAT.
IF WATER USED, FOG NOZZLES ARE PREFERRABLE.
Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMPOSITION PRODUCTS
MAY CAUSE HEALTH HAZARDS. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.
GET MEDICAL ATTENTION. WARNING! FLAMMABLE!
* Accidental Release Measures *
Spill Release Procedures:KEEP SPECTATORS AWAY. ELIM IGNITE SOURCES.
DIKE & CONTAIN W/INERT MATERIAL(SAND)TRANSFER LIQ TO COVERED METAL
CONTAIN FOR RECOVERY/DISPOSAL. REMOVE W/INERT ABSORB. USE ONLY
NON-SPARK TOOLS. PREVENT CO NTAM OF SEWERS,GROUNDWATERS
W/MATERIAL/ABSORB
Neutralizing Agent:N/K.
*Handling and Storage *
CONTAINER AFTER EACH USE. KEEP FROM CHILDREN.
Other Precautions:EMPTY CONTAINERS MUST NOT BE WASHED & RE-USED FOR ANY
PURPOSE. CONTAINERS SHOULD BE GROUNDED AND BONDED TO RECEIVING
CONTAINER. DO NOT WELD, BRAZE OR CUT ON EMPTY CONTAINER. NEVER USE
PRESSURE TO EMPT Y. DRUM IS NOT A PRESSURE VESSEL.
OSHA STANDARD FOR LEAD. ** WEAR FACE SHIELD AS NECESSARY WHEN
SPRAYING.
Work Hygienic Practices:WASH HANDS AND FACE THOROUGHLY BEFORE EATING OR
DRINKING.
Supplemental Safety and Health
WOULD BE CLASS HAZARD WASTE BASED ON IGNITABILITY CHARACTER, I.E.
* Physical/Chemical Properties *
Vapor Density:> THAN AIR
Spec Gravity:.9
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT & SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELD/CUTTING, WILL PRODUCE SMOKE, CO, CO2, OXIDES OF NITROGEN,
CHROMIUM & LEAD."METAL*
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT,SPARK,FLAME.
*FUME FEVER"MAY RESULT FROM OVEREXPOSURE TO OBJECTS COATED
W/PRODUCT BY FLAME CUTTING.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL LAWS. INCINERATE ONLY EPA PERMITTED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS. OBSERVE PRECAUTIONS FOR DISPOSAL OF
FLAMMABLE MATERIALS. CONTAMINAT ED ABSORB MAY BE DISPOSED IN HAZARD
WASTE LANDFILL
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:PROPER RESPIRATOR SELECTION SHOULD BE DETERMINED
BY ADEQUATELY TRAINED PERSONNEL, BASED ON THE CONTAMINANTS, THE
DEGREE OF POTENTIAL EXPOSURE AND PUBLISHED RESPIRATORY PROTECTION
FACTORS. THIS SHOULD BE AVAILABLE FOR ROUTINE AND NONROUTINE
Ventilation:USE IN WELL VENTILATED AREA. IN CONFINED SPACE, MECHANICAL
VENTILATION MAY BE NECESSARY TO KEEP BELOW PEL/TLVS
Other Protective Equipment:IMPERVIOUS CLOTHING/BOOTS, EMERGENCY
EYEWASH/SHOWER. NOTTE: DO NOT CONTACT LENSES WHEN WORKING AROUND
THIS PRODUCT.
Work Hygienic Practices:LEATHER GOODS CONTAMINATED WITH THIS PRODUCT
SHOULD BE DISCARDED. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
VAPORS MAY ACCUMULATE IN LOW AREAS. VAPORS MAY CONCENTRATE IN CONFINED
AREAS. USE ADEQUATE GROUNDING TO PREVENT STATIC BUILDUP. RUNOFF TO
SEWER MAY CAUSE FIRE OR EXPLOSION HAZARD. CONTAMINATED CLOTHIN G,
RAGS OR SIMILAR ORGANIC MATERIAL STORED IN CLOSED SPACE MAY
SPONTANEOUSLY IGNITE.
* Product Identification *
Product ID:CRUDE OIL
Preparer's Name:SUE BOTTOM
* Composition/Information on Ingredients *
Ingred Name:BENZENE (SARA III)
Fraction by Wt: 0.1-5%
Other REC Limits:NONE SPECIFIED
Ingred Name:BUTANE
Fraction by Wt: 1-7% %
Other REC Limits:NONE SPECIFIED
Ingred Name:CYCLOHEXANE (SARA III)
Fraction by Wt: <1-4% %
Other REC Limits:NONE SPECIFIED
Ingred Name:CYCLOPENTANE
Fraction by Wt: <1-2% %
Other REC Limits:NONE SPECIFIED
Ingred Name:ETHYL BENZENE (SARA III)
Fraction by Wt: <1-3%
Other REC Limits:NONE SPECIFIED
Ingred Name:N-HEPTANE
Fraction by Wt: 1-5% %
Other REC Limits:NONE SPECIFIED
Ingred Name:HEXANE (N-HEXANE)
Fraction by Wt: 2-8% %
Other REC Limits:NONE SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:HYDROGEN SULFIDE (SARA III)
Fraction by Wt: <0.1-3%
Other REC Limits:NONE SPECIFIED
Ingred Name:METHYLCYCLOHEXANE
Fraction by Wt: 1-4% %
Other REC Limits:NONE SPECIFIED
Ingred Name:NONANE
Fraction by Wt: 1-4% %
Other REC Limits:NONE SPECIFIED
Ingred Name:OCTANE
Fraction by Wt: 1-5% %
Other REC Limits:NONE SPECIFIED
Ingred Name:PENTANE
Fraction by Wt: 1-6% %
Other REC Limits:NONE SPECIFIED
Ingred Name:PROPANE
Fraction by Wt: 1-4% %
Other REC Limits:NONE SPECIFIED
Ingred Name:SULFUR
Fraction by Wt: <0.1-3%
Other REC Limits:NONE SPECIFIED
Ingred Name:TOLUENE (SARA III)
Fraction by Wt: <1-2% %
Other REC Limits:NONE SPECIFIED
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Fraction by Wt: <1-3% %
Other REC Limits:NONE SPECIFIED
Ingred Name:HEXANE (ISOMERS OTHER THAN N-HEXANE)
Fraction by Wt: 1-5% %
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:MAY CAUSE SEVERE EYE IRRITATION,
CONJUNCTIVITIS, MAY CAUSE MODERATE SKIN IRRITATION, DEFATTING,
DERMATITIS, NASAL AND RESPIRATORY TRACT IRRITATION, CENTRAL NERVOUS
SYSTEM EFFECTS, POSSIBLE SECONDARY I NFECTION, ANEMIA, IRREGULAR
HEART RHYTHM, BEHAVIORAL CHANGES, HARMFUL OR FATAL IF SWALLOWED,
GASTROINTESTINAL DISTURBANE
Explanation of Carcinogenicity:BENZENE, A COMPONENT OF CRUDE OIL, IS
LISTED AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:EYE IRRITATION, REDNESS, TEARING, BLURRED
VISION, SKIN IRRITATION, CRACKING, REDNESS, ITCHING, INFLAMMATION,
EXCITATION, EUPHORIA, CONTRACTED EYE PUPILS, DIZZINESS, DROWSINESS,
FATIGUE, NAUSEA, HEADAC HE, LOSS OF REFLEXES, TREMORS, CONVULSIONS,
SEIZURES, LOSS OF CONSCIOUSNESS, COMA, DEPRESSION, DIARRHEA,
VOMITING.
Medical Cond Aggravated by Exposure:PREEXISTING EYE, SKIN, HEART,
CENTRAL NERVOUS SYSTEM AND RESPIRATORY DISORDERS MAY BE AGGRAVATED
BY EXPOSURE TO THIS PRODUCT. IMPAIRED KIDNEY, LIVER AND BLOOD
DISORDERS MAY BE AGGRAVATED.
* First Aid Measures *
First Aid:EYES: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER FOR AT
WATER. REMOVE CONTAMINATED CLOTHING PROMPTLY. HIGH PRESSURE SKIN
INJECTION S ARE SERIOUS MEDICAL EMERGENCIES! GET IMMEDIATE MEDICAL
ATTENTION. INHALATION: REMOVE TO FRESH AIR. TREAT SYMPTOMATICALLY.
INGESTION: DO NOT INDUCE VOMITING. GIVE VEGETABLE OIL. GET MEDICAL
ATTENTION
* Fire Fighting Measures *
Lower Limits:0.4 %
Extinguishing Media:DRY CHEMICAL, HALON, FOAM AND CARBON DIOXIDE ARE
PREFERRED. FOAM AND WATER FOG CAN CAUSE FROTHING.
Fire Fighting Procedures:PRODUCT WILL RELEASE FLAMMABLE VAPORS WHICH
CAN BURN IN OPEN OR BE EXPLOSIVE IN CONFINED SPACE. PUMP CONTENTS
FROM TANK AND COOL TANKS WITH WATER.
Unusual Fire/Explosion Hazard:IMPROPER USE OF WATER MAY CAUSE FROTHING
AND SPREAD FIRE OVER LARGER AREA. VAPOR OR GAS MAY SPREAD TO
DISTANT IGNITION SOURCES AND FLASH BACK.
* Accidental Release Measures *
Spill Release Procedures:STAY UPWIND AND AWAY FROM SPILL. DO NOT ENTER
OR STAY IN AREA UNLESS MONITORING INDICATES OK. ISOLATE HAZARD
AREA; RESTRICT ENTRY. RECOVER AS MUCH AS POSSIBLE. THEN ABSORB AND
HANDLE IAW ENVIRONMENTAL REGULATIONS. KEEP OUT OF
SEWERS/WATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARK AND FLAMES.
DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL ON OR NEAR THIS
CONTAINER. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:SPECIAL H2S WARNING: CARE MUST BE TAKEN BY THOSE WHO
ARE RENDERING AID TO THE VICTIM BECAUSE H2S MAY BE IN AREA AND MAY
ALSO OVERCOME RESCUERS UNLESS IT HAS BEEN DETERMINED THAT THE AREA
IS FREE OF HY DROGEN SULFIDE.
* Physical/Chemical Properties *
HCC:F4
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Density:> 1
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:SLIGHT
Appearance and Odor:DARK BROWN/BLACK LIQUID WITH HYDROCARBON/SULFIDE
ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS (PEROXIDE, DICHROMATE, PERMANGANATE,
CHLORINE, ETC), STRONG ACIDS, CAUSTICS AND HALOGENS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, STATIC
ELECTRICITY OR OTHER POTENTIAL IGNITION SOURCES SHOULD BE AVOIDED.
DO NOT SWITCH LOAD.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
REACTIVE HYDROCARBONS (ALDEHYDES, AROMATICS, ETC) COMPOUNDS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF MATERIAL IN ACCORDANCE WITH LOCAL,
COUNTY, STATE AND FEDRAL REGULATIONS. CONTACT STATE AND FEDERAL
REGULATORS TO DETERMINE WASTE CLASSIFICATION. USE LICENSED
TRANSPORTER AND DISPOSAL FACILI TY.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:CARTRIDGE/AIR SUPPLIED FOR EMERGENCIES
Ventilation:LOCAL EXHAUST: HOODS & MECHANICAL: EXPLOSION PROOF
Other Protective Equipment:EYEWASH/SHOWER STATIONS; IMPERVIOUS (RUBBER,
PLASTIC, PVC)
Work Hygienic Practices:NO SMOKING AREA
Supplemental Safety and Health
* Product Identification *
Preparer's Name:L.E. GAUDETTE, PHD
* Composition/Information on Ingredients *
III)
Ozone Depleting Chemical:1
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION/INGESTION: REMOVE WET
APPAREL TO AVOID FIRE HAZARDS (ALCOHOL). ADVISE PHYSICIAN OF CV
SENSITIZATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INGESTION/INHALATION: REMOVE WET APPAREL TO
AVOID FIRE HAZARD (ALCOHOL). ADVISE PHYSICIAN OF CV SENSITIZATION.
* First Aid Measures *
First Aid:EYES: IRRIGATE WITH COPIOUS QUANTITIES OF WATER. CONTACT
PHYSICIAN TO ASSESS FOR FROSTBITE. SKIN: WASH WITH SOAP & WATER.
APPLY LANOLIN CREAM. AVOID RE-EXPOSURE UNTIL CLEAR. INHALATION:
REMOVE TO FRES H AIR; ARTIFICIAL RESPIRATION AS NEEDED; CONTACT
PHYSICIAN IMMEDIATELY. INGESTION: INDUCE SALTWATER EMESIS UNLESS
COMATOSE OR CONVULSING; CONTACT PHYSICIAN IMMEDIATELY.
* Fire Fighting Measures *
Flash Point:NONE TO BOIL
Lower Limits:2.0%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM (TO CONTROL ALCOHOL)
Fire Fighting Procedures:AIR SUPPLIED RESPIRATORS FOR TOXIC FUMES.
ALCOHOL ENRICHMENT CREATES A 1B FLAMMABLE LIQUID.
Unusual Fire/Explosion Hazard:ALCOHOL CONSTITUTES A SOURCE OF MODERATE
EXPLOSIVE HAZARD IN THE PRESENCE OF HEAT & FLAMES.
* Accidental Release Measures *
Spill Release Procedures:SMALL SPILLS: ABSORB ON PAPER OR SOLID
ABSORBENT. LARGE SPILLS: CONTAIN LIQUID, COLLECT EXCESS INTO CLOSED
CONTAINERS, ABSORB RESIDUAL ONTO SOLID ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:ADEQUATE VENTILATION. AVOID HEAT,
FLAMES, IGNITION SOURCES. NO SMOKING AREA. COOL, CLEAN AREAS.
Other Precautions:SAFETY CANS FOR SMALL QUANTITIES. GROUNDED
DISPENSERS.
* Physical/Chemical Properties *
Vapor Density:3.0
Appearance and Odor:CLEAR, COLORLESS LIQUID, SWEET ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS; HYDROGEN/PALLADIUM PARTICLES, REACTIVE METALS & AL,
ZN, MG.
Stability Condition to Avoid:HEAT & FLAMES
Hazardous Decomposition Products:OXIDES OF CARBON & NITROGEN, HALOGEN
ACIDS, & CARBONYLHALIDES.
* Disposal Considerations *
Waste Disposal Methods:RECLAMATION OR INCINERATION AT LICENSED DISPOSAL
FACILITY. PRECAUTIONS SHOULD BE TAKEN TO PREVENT PHOSGENE
GENERATION. COMPLY WITH ALL GOVERNMENT REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:VAP RESPIRATOR.BE SURE TO USE MSHA/NIOSH APPROV
RESPIRATOR OR EQUIVALENT.WEAR APPROPRIATE RESPIRATOR WHEN
VENTILATION IS INADEQUATE.FOR SPILL SCBA TO AVOID PRODUCT INHAL.
Ventilation:PROVIDE EXHAU VENTI/OTHER ENGINEER CNTRL-KEEP AIRBORNE VAP
CONC BEL TLV.
Other Protective Equipment:ENSURE EYEWASH STATION/SAFETY SHOWER IN
PROXIMAL WORKSTATION LOCATION.FULL SUIT,BOOTS.SPILL:CONSULT
SPECIALIST BEF HNDLG
Work Hygienic Practices:WASH CONTAM CLOTHING BEF REUSE.DONT
INGEST/BREATH GAS/FUMES/VAP/SPRAY.
Supplemental Safety and Health
HEALTH:PROL EXPO MAY RESULT IN SKIN BURNS/ULCERATIONS.OVEREXPO INHAL
MAY CAUSE RESP IRRIT.SEVERE OVEREXPO CAN RESULT IN DEATH.CAN BE
FATAL IF INHAL/INGEST.MAY IRRIT EYE/SKIN UPON CONTACT,INFLAMM OF EY
E/SKIN.TOXIC TO LUNGS/MUC MEMBRANES. 1STAID:GLASSES OF MILK/H2O.GET
IMMED MED ATTN.
* Product Identification *
Preparer's Name:E.BRULL
* Composition/Information on Ingredients *
Fraction by Wt: 0.1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 1.4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 PPM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:YES
Health Hazards Acute and Chronic:VERY DANGEROUS SKIN
CONTACT-CORRO,IRRIT,PERMEATOR,EYE
CONTACT-IRRIT,INGEST,INHAL.NON-SENS SKIN.CORRO TO EYE/SKIN ON
CONTACT.LIQ/SPRAY MIST MAY PRODUCE TISSUE DMG PARTICULARLY ON MUC
MEMB OF EYES/MOUTH /RESP TRACT.SKIN CONTACT MAY PRODUCE BURNS.SPRAY
MIST INHAL MAY PROUDCE SEVERE IRRIT RSP TRACT.SEVERE EYE
IRRIT.(SUPPLE)
Explanation of Carcinogenicity:PER MSDS:CARCINOGENIC EFFECTS:CALSSIFIED
A2 BY ACGIH, 2 BY NTP(BERYLLIUM).STATE OF CALIFORNIA:BERYLLIUM.
Effects of Overexposure:SKIN:CORRO,IRRIT,PERMEATOR.EYE:IRRIT.VERY
DANAGEROUS TO EYE/SKIN/INGEST/INHAL.TISSUE DMG ON MUC MEMB OF
EYE/MOUTH/RESP TRACT,SKIN BURNS/ULCERATION,SEVERE IRRIT OF RESP
TRACT-COUGH,CHOKE,SHORTNESS OF B REATH.FATAL IF INHAL/INGEST.EYE
INFLAMM-RED,WATERING,ITCH.SKIN
INFLAMM-ITCH,SACRING,RED,BLISTERING.BRONCHIAL INFECTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYE:CHECK/REMOVE CONTACT LENS.IMMED FLUSH W/H2O @LEAST
CONTAM CLOTH QUICKLY.PLACE UNDER DELUGE SHOWER.WASH
W/H2O/NONABRASIVE SOAP.IRRI T PERSIST GET MED ATTN.INHAL:REST IN
WELL VENTI AREA.GET IMMED MED ATTN.DIFFI BREATH GIVE OXY;NOT BREATH
MOUTH-TO-MOUTH RESUSCI.GET IMMED MED ATTN.INGEST:DONT INDUCE
VOMIT.CONSC DRINK SEVEREAL(SUPP)
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Autoignition Temp:Autoignition Temp Text:NA
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:NON-FLAMMABLE.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:SLIGHT EXPLO-EXPLO W/REDUC MATLS,COMBUST
MATLS,ORG MATLS.NON-CORROSIVE IN PRESENCE OF GLASS.
* Accidental Release Measures *
Spill Release Procedures:SM:DILUTE W/H2O;MOPUP/ABSORB W/INERT DRY
MATL.PLACE IN APPRO WASTE DISPO CNTNR.LG:STOP LEAK W/O RISK.ABSORB
W/DRY EARTH,SAND,NON-COMBUST MATL.DONT GET H2O IN CNTNR.AVOID
CONTACT W/COMBUST MATL.KEEP DA MP W/H2OSPRAY.DONT TOUCH SPILL.USE
H2O(OTHR PREC)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP LOCKEDUP,CNTNR DRY,AWAY FRM
HEAT/IGN SOURCE/COMBUST MATL.NEVER ADD H2O TO PROD.INSUFF VENTI
WEAR SUITABLE RESP EQPMT.
Other Precautions:CORRO MATL STORE IN SAF STORAGE
CABINET/RM.SPILL:SPRAY CURTAIN TO DIVERT VAP DRIFT & H2OSPARY TO
RED VAP.PREVENT ENTRY INTO SEWER/BASEMENT/CONF AREA;DIKE.CALL
ASSIST ON DISPO.
* Physical/Chemical Properties *
HCC:C1
Melt/Freeze Pt:M.P/F.P Text:N/AVAI
Decomp Temp:Decomp Text:NP
Spec Gravity:1
pH:NEURAL
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID, ODOR/TASTE/COLOR-NOT AVAILABLE
Percent Volatiles by Volume:N/AVAI
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HIGHLY REACTIVE W/ALKALIS;SLIGHTLY REACTIVE-REACTIVE W/RED
AGENTS,COMBUST MATLS,ORG,METALS;
Stability Condition to Avoid:NO ADDN REMARK.
* Disposal Considerations *
Waste Disposal Methods:RECYCLE TO PROCESS IF POSSIBLE.CONSULT
LOC/REGIONAL AUTHORITIES.BIODEGRADATION PROD:SOME METALLIC
OXIDES.PRODS OF DEGRADATION ARE MORE TOXIC.CERCLA/SARA
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED DURING NORMAL USAGE.
Ventilation:NOT REQUIRED DURING NORMAL USAGE.
Other Protective Equipment:IF PROLONGED DIRECT CONTACT IS REQUIRED THEN
Work Hygienic Practices:NONE OTHER THAN AS DIRECTED ON LABEL OF
CONTAINER. AVOID EXCESSIVE CONTACT WITH SKIN.
Supplemental Safety and Health
* Product Identification *
Product ID:SPARKLEEN
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL MONOBUTYL ETHER
Ingred Name:DIETHYLAMINE
= Wt:1.
Ingred Name:SURFACTANT
= Wt:4.
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THIS PPRODUCT HAVING BEEN TESTED BY
F.H.S.A. PROCEDURES IS CONSIDERED SAFE UNDER NORMAL USE AS DIRECTED
ON LABEL. F.H.S.A. TEST RESULTS APPLY WHEN ACCIDENTALLY EXPOSED TO;
1.) EYE - "PRIME IRRITATION" , 2.) SKIN - "2.2" (ON "PRIME
IRRITATION INDEX" SCALE OF 8), 3.) ORAL INGESTION - "TOXIC".
Explanation of Carcinogenicity:NONE LISTED.
Effects of Overexposure:IF SWALLOWED MAY PRODUCE ATAXIA (CRAMPING). IF
EXPOSED TO EYE WILL CAUSE IRRITATION AND REDNESS.
* First Aid Measures *
First Aid:IF INHALATION CAUSES NAUSEA OR DIZZINESS MOVE TO FRESH AIR.
INGESTED, DO NOT INDUCE VOMITING BUT ADMINISTER WATER OR MILK AND
CALL A DOCTOR.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOG VAPOR (DOES NOT
SUPPORT COMBUSTION)
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:CLEAN UP SMALL SPILLS WITH PAPER TOWELS AND
DISPOSE IN WASTE RECIPRICOL. SOAK UP LARGE SPILLS WITH INERT
ABSORBENT AND SHOVEL INTO CONTAINER OR FLUSH SPILL AREA TO TREATED
DO NOT REUSE CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN PROTECTED AREA AND AWAY FROM
OPEN FLAME TO PREVENT PUNCTURE OR FIRE FROM PACKAGING CONTAINERS.
Other Precautions:NONE.
* Physical/Chemical Properties *
HCC:N1
Evaporation Rate & Reference:<1
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR APPEARANCE WITH SLIGHTLY AMMONIATED ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID MATERIALS THAT REACT VIOLENTLY WITH WATER.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NOT EXPECTED TO OCCUR.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Regulatory Information *
CHEMICALS: PRODUCT CONTAINS TOXIC CHEMICALS LISTED BELOW WHICH ARE
THIS PRODUCT CONTAINS FLAMMALBE/COMBUSTIBLE SOLVENTS. MATERIALS OF
CONSTRUCTION/COMPATIBILITY: MA TERIAL IS COMMONLY STORED IN CLOSED
STAINLESS STEEL OR GLASS LINED STEEL PIPING & STORAGE TANKS (AT
AMBIENT TEMPERATURE). ANY OTHER MATERIALS SUCH AS REINFORCE
FIBERGLASS, PLASTIC, ETC, MUST BE TESTED FOR COMPATIBILITY BEFORE
(FEDERAL REGS)
Federal Regulatory Information:CPSC CLASSIFICATION: NA. WHMIS HAZARD
CLASS: B2 FLAMMABLE LIQUIDS, D2B TOXIC CHEMICALS. WHMIS TRADE
INVENTORY (ACOIN). SARA (CON'T): USE. CONSULT SUPPLIER FOR
MATERIALS FOR GASKETS, PACKING, ETC. CONDITION FOR SAFE STORAGE:
BULK STORAGE DESIGN FACTORS TO CONSIDER AR E VENTING, DIKING,
SEPARATION DISTANCES BETWEEN TANKS & OTHER STRUCTURES. STORAGE
REQUIREMENTS SHOUL D BE DETERMINED THROUGH CONSULTATION WITH
QUALIFIED DESIGN & FIRE PROTECTION ENGINEERS & FIRE INSURANCE
CARRIERS. (STATE REGS)
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS A CHEMICAL
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR
FACTORY MUTUAL HANDBOOK OF INDUSTR IAL LOSS PREVENTION. RECOMMENDED
TANK DESIGN: FOR PRESSURE VESSELS, SEE AMERICAN SOCIETY OF MECHANIC
FULL VACUUM. STORAGE EQUIPMENT: CORROSION PROTECTION, (OTHER
INFORMATION)
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL AND GENERAL VENTILATION NECESSARY TO KEEP AIR
CONCENTRATION BELOW TLV .VENT CURING OVEN TO OUTDOORS.
Other Protective Equipment:PROTECTIVE EQUIPMENT TO COVER EXPOSED AREAS.
Work Hygienic Practices:GOOD INDUSTRIAL HYGIENE PRACTICES SHOULD BE
FOLLOWED WHEN HANDLING THIS PRODUCT.
Supplemental Safety and Health
VOLATILE BY WT:<1%.EXPLAN OF CARCIN:HUMANS;LIMITED EVIDENCE FOR CARC IN
ALLOW AN EVALUATION OF CARC IN HUMANS;SUFFICIENT EVIDENCE FO R CARC
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SILVER (SARA III)
Other REC Limits:N/K
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:VINYL CYCLOHEXENE DIOXIDE
Other REC Limits:N/K
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:4,4'-ISOPROPYLIDENEDIPHENOL (SARA III)
Other REC Limits:N/K
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE DERMAT,SENSIT,SKIN
CANCER.RESORCINOL DIGLYCIDYL ETHER:REPEAT/PROLONGED SKIN CONTACT
WILL CAUSE SEVERE INJURY.
Explanation of Carcinogenicity:VINYL CYCLOHEXENE DIOXIDE:ACGIH A2=SUSP
IN (SEE SUPP)
Effects of Overexposure:EYES:EXTREME IRRIT.SKIN:MAY CAUSE
DERMAT,SENSIT,RASH.ABSORB-MAY CAUSE NAUSEA,VOMIT,OTHER ILLNESS
SIGNS.VINYLCYCLOHEXENE DIOXIDE-SWELL,REDNESS LIKE BURN.RESORCINOL
DIGLYCIDYL ETHER-SEVERE IRRIT.REPEAT/ PROLONG CONTACT CAUSE SEVERE
INJURY.SYMP LIKE POISON IVY/SUMAC.INGEST:SLIGHT ORAL
TOXICITY.INHAL:HARMFUL TO RESP SYS.
Medical Cond Aggravated by Exposure:N/K
* First Aid Measures *
ATTENTION.SKIN:WASH IMMEDIATELY WITH SOAP & WATER.IF IRRITATION
PERSISTS,GET MEDICAL ATTENTION IMMEDIATELY.INGESTION:GET MEDICAL
ATTENTION IMM EDIATELY AND SHOW INSERT CARD.INHALATION:REMOVE TO
FRESH AIR IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.HAZARDOUS DECOMPOSITION
PRODUCTS (INCLUDING COMBUSTION PRODUCTS):CARBON MONOXIDE &/OR
CARBON DIOXIDE.
* Accidental Release Measures *
Spill Release Procedures:WIPE UP WITH SOLVENT SATURATED TOWELING AND
COLLECT IN AN APPROPRIATE CONTAINER FOR DISPOSAL.
Neutralizing Agent:N/K
*Handling and Storage *
Handling and Storage Precautions:STORE REGRIGERATED AT ALL TIMES.VENT
CURING OVEN TO OUTDOORS.SKIN BARRIER CREAM EFFECTIVELY PROTECTS
MOST PERSONNEL ROUTINELY HANDLING THESE INGRED.
Other Precautions:DURING MAINTENANCE OF CONTAMINATED EQUIPMENT AVOID
CONTACT WITH SKIN,EYES,CLOTHING.GOOD HOUSEKEEPING IS REQUIRED.AVOID
INHALATION OF VAPORS.
* Physical/Chemical Properties *
Decomp Temp:Decomp Text:N/K
Vapor Pres:0.1 MMHG
Vapor Density:N/K
Spec Gravity:3.2 (WATER=1)
Evaporation Rate & Reference:N/K
Solubility in Water:NIL
Appearance and Odor:SILVER PASTE;PLEASANT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT PRIOR TO CURE.
Hazardous Decomposition Products:(INCLUDING COMBUSTION PRODUCTS):CARBON
MONOXIDE AND/OR CARBON DIOXIDE.
Conditions to Avoid Polymerization:EXCESSIVE HEAT.IF NOT USED FOR THIN
BOND LINE APPLICATN,VIOLENT CHEM RXN CAN RESULT.USE W/ CAUTION UPON
CURING.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DISPOSE IN APPROVED CHEMICAL
DISPOSAL AREA OR IN A MANNER WHICH COMPLIES WITH ABOVE REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED DURING NORMAL USE OF THIS PRODUCT.
Ventilation:NONE REQUIRED DURING NORMAL USE OF THIS PRODUCT.
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER
Work Hygienic Practices:WASH HANDS BEFORE EATING OR DRINKING. OBSERVE
NORMAL CARE FOR WORKING WITH CHEMICALS.
Supplemental Safety and Health
* Product Identification *
Product ID:PRISMA AP H
* Composition/Information on Ingredients *
Ingred Name:NON HAZARDOUS INGREDIENTS
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE AND CHRONIC- PERSONS SUSCEPTIBLE
TO METHACRYLATES, ACRYLATES AND URETHANES MAY DEVELOP ALLERGIC
RESPONSE. CONTACT WITH SKIN MAY CAUSE REDNESS OR IRRITATION. SEVERE
ALLERGIC RESPONSE MAY RESULT I N PERSONS WITH BREATHING
DIFFICULTIES.
Effects of Overexposure:PERSONS SUSCEPTIBLE TO METHACRYLATES, ACRYLATES
AND URETHANES MAY DEVELOP ALLERGIC RESPONSE. CONTACT WITH SKIN MAY
CAUSE REDNESS OR IRRITATION. SEVERE ALLERGIC RESPONSE MAY RESULT IN
PERSONS WITH BREA THING DIFFICULTIES.
Medical Cond Aggravated by Exposure:ALLERGIES TO METHACRYLATES,
ACRYLATES AND URETHANES
* First Aid Measures *
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYE:FLUSH WITH
WATER. INHALED:UNLIKELY. INGESTED:CONSULT A PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, SAND, DRY CHEMICAL, FOAM. WATER
SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS COOL.
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS AND PROTOCTIVE CLOTHING.
Unusual Fire/Explosion Hazard:IRRITATING GASES MAY BE FORMED.
* Accidental Release Measures *
Spill Release Procedures:COLLECT SPILLED MATERIAL. PLACE IN A CONTAINER
FOR DISPOSAL. CLEAN UP RESIDUE. AVOID GROSS SKIN CONTACT TO
MINIMIZE THE POSSIBILITY OF CONTACT DERMATITIS TO SENSITIVE
INDIVIDUALS.
Neutralizing Agent:NOT APPLICABLE.
*Handling and Storage *
Handling and Storage Precautions:STORAGE- STORE AT ROOM TEMPERATURE
AWAY FROM FOOD, BEVERAGES AND VISIBLE LIGHT. AVOID STORAGE
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. WASH THOROUGHLY
AFTER HANDLING MATERIAL. DO NOT INGEST.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:2.2
Solubility in Water:INSOLUBLE
Appearance and Odor:CREAMY PASTE, SHADES OFF-WHITE TO YELLOW GREY WITH
ACRYLATE ESTER ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:VISIBLE LIGHT ON PASTE, PROLONGED HEAT
Hazardous Decomposition Products:POSSIBLE METHACRYLATES
Conditions to Avoid Polymerization:VISIBLE LIGHT. WILL HARDEN DURING
EXPOSURE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE GEN DILUTION/LOC EXHAUST FAILS TO ADEQ
DILUTE TWA/PEL OF MATL, THEN RESP PROT SHOULD BE USED AS FOLLOWS:DO
NOT BREATHE VAP/SPRAY MIST. WEAR APPROP, PROPERLY FITTED RESP
APPRVD BY NIOSH/MSHA WHEN EXPOS. AIR LINE RESP (SUPDAT)
Ventilation:PROVIDE GEN DILUTION/LOC EXHAUST VENT TO KEEP TWA & LEL
BELOW APPLIC LIM & TO REMOVE DECOMP PRODUCTS.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
LESS/A PPLIC EXPOS LIM.
* Product Identification *
Preparer's Name:MASTROIK
CAGE:0S4B8
CAGE:0S4B8
* Composition/Information on Ingredients *
Ingred Name:HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)
OSHA PEL:N/K
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS;
((HOMOPOLYMER) HEXAMETHYLENE DIISOCYANATE) (HDI)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ACETIC ACID, BUTYL ESTER; (BUTYL ACETATE) (CERCLA). VP:8.0
Ingred Name:VOLATILE ORGANIC CONTENT:2.2 POUNDS PER GALLON LESS WATER
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:OVEREXPOSURE BY INHALATION MAY
CAUSE IRRITATION OF RESPIRATORY TRACT, HEADACHE, DIZZINESS, OR
DROWSINESS. SKIN OR EYE CONTACT:IRRITANT TO EYES AND SKIN, AND SKIN
SENSITIVITY. CHRONIC:MAY AFFECT RESPIRATORY TRACT. ALLERGIC
RESPIRATORY/SKIN REACTION-CENTRAL NERVOUS
SYSTEM-KIDNEYS-LIVER-CARDIAC (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:SENSITIZATION.
Medical Cond Aggravated by Exposure:RESPIRATORY PROBLEMS.
* First Aid Measures *
First Aid:INHAL:REMOVE FROM EXPOSURE. EYE:FLUSH IMMED W/LG AMTS OF
WASH SKIN WITH SOAP & WATER. INGEST:DRINK WATER. IF NECESSARY,
CONSULT PHYSIC IAN FOR ANY OF THESE CONDITIONS.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, OR CARBON
DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, AVOID
BREATHING VAPORS, VENTILATE AREA, AND REMOVE W/INERT ABSORB &
NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT TAKE INTERNALLY. CNTNRS SHOULD
BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUID IN EXCESS OF
FEW INCHES.
Other Precautions:MAKE SURE DRUM IS COMPLETELY EMPTY BEFORE ATTEMPTING
TO WELD/BRAZE. DRUM SHOULD BE INDUSTRIALLY CLEANED PRIOR TO REUSE.
DO NOT FLAME CUT, BRAZE, OR WELD W/OUT NIOSH/MSHA APPRVD
RESP/APPROP VENT.
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:WILL REACT WITH WATER OR WATER CONTAINING
PROD TO GIVE OFF HEAT & FUMES. DO NOT ALLOW WATER TO ENTER SEALED
(SUPDAT)
Hazardous Decomposition Products:FUMES MAY CNTN CARBON MONOXIDE &
OXIDES OF NITROGEN. MAY PRODUCE HAZ FUMES WHEN HEATED TO DECOMP AS
IN WELDING.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS. BEFORE ATTEMPTING TO CLEAN UP.
| 1 | eyes_protection_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Item Description Information
*
Item Name: GREASE,SPECIAL PURPOSE
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EXTENSIVE STUDIES HAVE BEEN CONDUCTED ON HALOCARBON OILS
SIMILAR TO ONES FOUND IN PROD. BASED ON ALL AVAIL DATA IN 3 SPECIES OF
ANIMALS, LIM EXPOS TO PROD SHOULD NOT BE HARMFUL TO ANY PORTION OF HUMAN
ANATOMY. STUDIES CONDUCTED BY AIR FORCE HAVE DEMONSTRATED LIVER TOX IN
RODENTS BUT NOT IN PRIMATES. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:OBSERVED LIVER TOX IS BELIEVED TO
BE SPECIFIC FOR RODENTS & NOT RELEVANT TO HUMANS. HALOCARBON OILS ARE NOT
IRRIT TO SKIN BUT SIMPLE SKIN PROT SHOULD BE USED TO PVNT RTPD EXPOS &
POSS OF SENS IT. ACUTE: FROM ANIMAL STUDIES, SIGNS OF FLUORIDE POISONING MAY
BE EXPECTED. THESE INCL NAUS, SHORT OF BRTH & (SUPDAT)
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING(GIVE O*2/ARTF RESP)(FP
MINUTES. INGEST: DILUTE BY DRINKING LARGE QUANTITIES OF WATER. IF VOMITING
OCCURS ADMINISTER MORE WATER.
*
Handling and Disposal
*
Spill Release Procedures: SPILLS MAY BE WIPED UP WITH ABSORBENT MATERIAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: MAY BE INCINERATED BY LICENSED WASTE DISPOSAL COMPANY.
OBSERVE ALL FEDERAL, STATE & LOCAL REGULATIONS.
Handling And Storage Precautions: NONE SPECIFIED BY MANUFACTURER.
Other Precautions: SINCE THE POTENTIAL FOR HUMAN TOXICITY CANNOT BE RULED OUT
PROPER WORK PRACTICES SHOULD BE EMPLOYED.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NONE
Extinguishing Media: NON-FLAMMABLE. USE AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT(FP N).
Unusual Fire/Explosion Hazard: THERMAL DECOMPOSITION PRODUCTS ARE ACIDIC AND
TOXIC.
*
*
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN(FP N).
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment: EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA(FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USERS OF THE "L" VERSION OF TO CONSULT THE
CHLORINE TRIFLUORIDE. EFTS OF OVEREXP: LOSS OF APPETITE. CHRONIC: NONE
KNOWN.
*
Physical/Chemical Properties
*
B.P. Text: SUPDAT
Vapor Pres: <0.1
Solubility in Water: NEGLIGIBLE
Appearance and Odor: COLORLESS, OPAQUE GREASE.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: ALUM THREADED CONNECTIONS WHERE GALLING & SEIZURE MAY
INITIATE RXN. REACTS W/METALS LIKE SODIUM & POTASSIUM, (SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Company Name: HALOCARBON PRODUCTS CORPORATION
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EXTENSIVE STUDIES HAVE BEEN CONDUCTED ON
HALOCARBON OILS SIMILAR TO ONES FOUND IN PROD. BASED ON ALL AVAIL DATA IN 3
SPECIES OF ANIMALS, LIM EXPOS TO PROD SHOULD NOT BE HARMFUL TO ANY PORTION O
F HUMAN ANATOMY. STUDIES CONDUCTED BY AIR FORCE HAVE DEMONSTRATED LIVER TOX
IN RODENTS BUT NOT IN PRIMATES. FROM THE ANIMAL STUDIES, SIGNS OF FLOURIDE
POISONING MAY BE EXPECTED. THESE INCLUDE NAUSEA, SHORTNESS OF BREATH &
LOSS OF APPETITE. CHRONIC: NONE LISTED BY MANUFACTURER.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD
LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP
SUPPLIER, WHICHEVER IS LOWEST. A NIOS H APPRVD FULL-FACE PIECE
SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (SUP DAT)
Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF BECAUSE IT
CAN CTL EMISSIONS OF (OTHER INFO)
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR CLEAN BODY-COVERING CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
RESP PROT: WHICHEVER IS LOWEST. FOR EMERS/INSTANCES WHERE EXPOS LEVELS
ARE NOT KNOWN, USE A NIOSH APPRVD FULL-FACEPIECE POS-PRESS,
AIR-SUPPLIED RESP. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT
WORKER S IN OXYGEN-DEFICIENT ATMS. PHYSICAL/CHEM PROPERTIES:
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM CHLORIDE
Other REC Limits:N/K
OSHA STEL:N/K
ACGIH STEL:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: INHALATION OF HIGH
CONCENTRATIONS OF DUST MAY CAUSE NASAL OR LUNG IRRITATION.
INGESTION: LARGE QUANTITIES CAN PRODUCE GASTROINTESTINAL IRRITATION
AND VOMITING. MAY PRODUCE WEAKNESSAND CIRCULATORY PROBLEMS. MAY
AFFECT HEART. IN SEVERE CASES, INGESTION MAY BE FATAL. SKIN:
CONTACT MAY CAUSE IRRITATION OR RASH, PARTICULARLY WITH MOIST SKIN.
EYES: POTASSIUM CHLORIDE IS A MODERATE EY E IRRITANT. REDNESS,
TEARING, POSSIBLE ABRASION CAN OCCUR. CHRONIC: NO INFORMATION
FOUND.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED KIDNEY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL
PERSONNEL. NEVER G IVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CALL A PHYSICIAN. SKIN: REMOVE ANY CONTAMINATED CLOTHING. WASH SKIN
IF IRRITATION DEV ELOPS OR PERSISTS. EYES: IN CASE OF CONTACT,
MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. CALL A
PHYSICIAN IF IRRITATION PERSISTS.
* Fire Fighting Measures *
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. NOT
CONSIDERED TO BE AN EXPLOSION HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN CONTROL
MEASURES SECTION. PICK UP AND PLACE IN A SUITABLE CONTAINER FOR
RECLAMATION OR DISPOSAL, USING A METHOD THAT DOES NOT GENERATE
DUST.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY
SINCE THEY RETAIN PRODUCT RESIDUES(DUST, SOLIDS); OBSERVE ALL
WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT.
Other Precautions:AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH
ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
* Physical/Chemical Properties *
B.P. Text:SUBLIMES
pH:SEE SUP DAT
Appearance and Odor:WHITE CRYSTALS OR POWDER; ODORLESS.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BROMINE TRIFLUORIDE; POTASSIUM PERMANGANATE PLUS SULFURIC ACID.
Stability Condition to Avoid:NO INFORMATION FOUND.
Hazardous Decomposition Products:OXIDES OF THE CONTAINED METAL AND
HALOGEN, POSSIBLY ALSO FREE, OR IONIC HALOGEN.
* Toxicological Information*
MUTAGEN.
* Ecological Information *
Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL
TOXICITY: NO INFORMATION FOUND.
* Disposal Considerations *
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROPRIATE & APPROVED WASTE DISPOSAL
FACILITY. PROCESSING, USE/CONTAMINATION OF PROD MAY CHANGE WASTE
MANAGEMENT OPTIONS. STATE & LOCAL DISP REGULATIONS MAY DIFFER FROM
FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER & UNUSED C
ONTENTS I/A/W FEDERAL, STATE & LOCAL REQUIREMENTS.
* MSDS Transport Information *
Transport Information:NOT REGULATED. OTHER INFORMATION: LAB PROTECTIVE
STORAGE). EMERGENCY OVERVIEW: CAUTION! MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE IRRITAT ION TO SKIN, EYES, AND RESPIRATORY TRACT.
* Regulatory Information *
NO; FIRE: NO; PRESSURE: NO; REACGIVITY: NO (PURE/SOLID).
Federal Regulatory Information:POTASSIUM CHLORIDE LISTED IN TSCA, EC,
JAPAN, AUSTRALIA, KOREA, CANADA DSL; NOT LISTED IN CANADA NDSL,
FOUND. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS: THIS MSDS HAS
BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED
PRODUCTS REGULATIONS (CPR) AND T HE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
State Regulatory Information:POTASSIUM CHLORIDE LISTED IN PHILADELPHIA.
* Other Information *
| 1 | eyes_protection_mandatory |
Control Measures
*
Product ID: SCOTCHBOND MULTI-PURPOSE PRIMER
*
Contractor Summary
*
*
Ingredients
*
------------------------------
------------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: SEVERE IRRIT WHICH CAN INCL REDNESS, SWELLING, PAIN,
TEARING, CLOUDY APPEARANCE OF CORNEA, IMPAIRED VISION & POSS PERM
IMPAIRED VISION. SKIN:ALLERGIC SKIN RXN WHICH CAN INCL REDNES, SWELLING, BLI
STERING & ITCHING. MILD SKIN IRRIT WHICH CAN INCL REDNESS, SWELLING &
ITCHING. INHAL/INGEST:NO ADVERSE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ:HEALTH EFFECTS ARE EXPECTED.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
MINS. GET MD IMMEDIATELY. SKIN:FLUSH W/LARGE AMOUNTS OF WATER. IF IRRITATION
PERSISTS, CALL MD. WASH CONTAMINATED CLOTHING BEFORE REUSE. INHAL:REMOVE TO
FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTF RESP) (FP N). INGEST:DO NOT INDUCE
VOMITING. DRINK TWO GLASSES OF WATER. CALL MD.
*
Handling and Disposal
*
Spill Release Procedures: OBSERVE PRECAUTION FROM OTHER SECTIONS. VENTILATE
AREA. COVER W/ABSORBENT MATERIAL. PLACE IN METAL CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISP I/A/W POLICIES/PROCS CONTAINED IN 3M WASTE
MANAGEMENT PROGRAM MANUAL & INSTRUCTIONS PROVIDED ON WASTE STREAM PROFILE
REFERENCE SHEET. CONSULT WASTE MANAGEMENT (RCRA) COORDINATOR W/ANY QUESTIONS.
DISP OF COMPLETELY CURED (POLYMERIZED) (SUPP DATA)
Handling And Storage Precautions: STORE AT ROOM TEMPERATURE. AVOID EYE CONTACT
& INHALATION OF VAPORS. DO NOT INGEST.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS (FP N).
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
*
*
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: WASTE DISP METH:MATERIAL IN A SANITARY
LANDFILL. SINCE REGULATIONS VARY, CONSULT APPLICABLE REGULATIONS OR
AUTHORITES BEFORE DISPOSAL.
*
Physical/Chemical Properties
*
HCC: C3
PH: 2.9-4
Appearance and Odor: CLEAR, SLIGHT YELLOW; SLIGHT ACRYLATE ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: SCOTCHBOND MULTI-PURPOSE PRIMER
Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: CAN CAUSE SEVERE EYE IRRITATION,
REDNESS, SWELLING, TEARING, CLOUDY CORNEA, POSSIBLE PERMANENT VISION
IMPAIRMENT, SKIN IRRITATION AND ALLERGIC REACTION. CHRONIC: NONE LISTED BY
MAN UFACTURER.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED UNDER NORMAL CONDITIONS OF USE.
HOWEVER, IF OIL MISTS ARE GENERATED ABOVE RECOMMENDED PEL/TLV OF 5
MG/M3, THEN A NIOSH/MSHA APPROVED RESP IS ADVISED IN ABSENCE OF
PROPER ENVIRONMENTAL CON TROL. (SEE YOUR SAFETY EQUIP SUPPLIER.)
Ventilation:NOT REQ UNDER NORM CNDTNS OF USE. HOWEVER, IF UNUSUAL
OPERATING CNDTNS EXIST, THEN PROVIDE SUFFICIENT MECHANICAL (ING 3)
Other Protective Equipment:NORMAL WORK CLOTHING COVERING ARMS & LEGS.
EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: SPRAYED INTO CONTRS OF HOT, BURNING LIQ. DENSE SMOKE
MAY BE GENETATED WHILE BURNING. SPILL PROC: SHOULD BE EXCLUDED FROM
AREA OF SPILL UNTIL CLEAN-UP HAS BEEN COMPLETED. STOP SPILL AT
SOURCE, DIKE AREA OF SPILL TO PVNT SPREADING, PUMP LIQ TO SALVAGE
TANK. REMAINING LIQ MAY BE TAKEN UP ON SAND, (ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATE, SOLVENT DEWAXED
(SEVERE), HEAVY PARAFFINIC; (PETROLEUM LUBE OIL)
OSHA PEL:5 MG/M3 (MFR)
ACGIH TLV:5 MG/M3 (MFR)
Ingred Name:SUP DAT: CLAY, EARTH, FLOOR ABSORBENT, OR OTHER ABSORBENT
MATERIAL AND SHOVELED INTO CONTAINERS.
Ingred Name:VENT: (GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO
MAINTAIN EXPOSURE BELOW PEL/TLV.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: NOT EXPECTED TO CAUSE
IRRITATION DURING NORMAL CONDITIONS OF USE. SKIN: PROLONGED OR
REPEATED CONTACT MAY BE MILDLY IRRITATING TO SKIN AND MAY CAUSE
DERMATITIS. INGESTION: NOT EXPECTED TO BE TOXIC BY INGESTION.
PRODUCT HAS LAXATIVE PROPERTIES AND MAY CAUSE NAUSEA, ABDOMINAL
CRAMPS AND (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DIARRHEA. INHALATION: NOT EXPECTED TO
BE AN INHALATION HAZARD AT NORMAL ROOM TEMPERATURE. HOWEVER, IF
EXPOSURES EXCEED THE PEL/TLV OF 5 MG/M3 FOR OIL MIST, THEN
INHALATION OF MIST MAY RESULT IN RESPIRATORY IRRITATION AND
POSSIBLEDISCOMFORT.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:SKIN: THORO WASH EXPOSED AREA W/SOAP & WATER. REMOVE CONTAM
CLTHG & LAUNDER BEFORE REUSE. EYES: FLUSH W/LGE AMTS OF WATER,
LIFTING UPPER & LOWER LIDS OCCAS. GET MED ATTN IF IRRIT PERSISTS.
INGEST: DONOT INDUCE VOMIT. KEEP PERS WARM & QUIET, & GET MED
ATTN. INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYGEN.
IF BRTHG HAS STOPPED GIVE ARTF RESP. KEEP PERS WARM, QUIET & GET
MED ATTN.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:USE REGULAR FOAM, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER/FOAM MAY CAUSE FROTHING WHICH CAN BE VIOLENT & POSS
ENDANGER LIFE OF FIREFIGHTER, ESP IF (SUP DAT)
Unusual Fire/Explosion Hazard:NEVER USE WELDING OR CUTTING TORCH ON OR
NEAR DRUM (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN
IGNITE EXPLOSIVELY.
* Accidental Release Measures *
Spill Release Procedures:SML SPILL: ABSORB LIQ ON VERMICULITE, FLOOR
ABSORB/OTHER ABSORB MATL. LGE SPILL: PVNT RUN-OFF TO SEWER,
STREAMS/OTHER BODIES OF WATER. IF RUN-OFF OCCURS, NOTIFY PROPER
AUTH AS REQ, THAT A SPILL HAS OC CURRED. PERS NOT WEARING PROT
EQUIP (SUP DAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID PROLONGED OR REPEATED CONTACT TO
SKIN. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTIED.
Other Precautions:SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES
(VAPOR, LIQUID AND/OR SOLID), ALL HAZARD PRECAUTIONS GIVEN IN THIS
MSDS MUST BE OBSERVED.
* Physical/Chemical Properties *
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:LIGHT AMBER LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:SMALL SPILL/LARGE SPILL: DISPOSE OF IN
ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:MFR RECOMMENDS NONE
Ventilation:MFR RECOMMENDS NONE
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PETROLEUM HYDROCARBON
* Hazards Identification *
Effects of Overexposure:IRRITANT TO SKIN & EYES W/PROLONGED CONTACT
* First Aid Measures *
WASH THOROUGHLY WITH SOAP AND WATER. INGESTION: CALL PHYSICIAN
IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, FOAM, SAND, EARTH, WATERFOG, CO*2.
Fire Fighting Procedures:WEAR SELF CONTAINING BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:DENSE SMOKE.
* Accidental Release Measures *
Spill Release Procedures:TRANSFER BULK OF MATERIAL INTO ANOTHER
CONTAINER. ABSORB REMAINING MATERIAL WITH PROPER ABSORBENT SUCH AS
SAND, EARTH, VERMICULITE. SWEEP UP AND DISPOSE AS SOLID WASTE.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS CLOSED
* Physical/Chemical Properties *
HCC:V6
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER LIQUID WITH MINERAL OIL ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS: CHROMIC ACID, H*2O*2, BROMINE
Hazardous Decomposition Products:CO & CO*2
* Disposal Considerations *
Waste Disposal Methods:WASTE DISPOSAL METHOD MUST BE IAW FEDERAL, STATE
AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR DUST MASK.
Ventilation:LOCAL EXHAUST: AS REQUIRED. MECHANICAL (GENERAL): VENT FAN.
Supplemental Safety and Health
SOLUBILITY IN WATER: POWDERS-APPRECIABLE. LIQUIDS-MISCIBLE.
* Product Identification *
Product ID:POLYPHENOL OXIDASE
* Composition/Information on Ingredients *
Ingred Name:POLYPHENOL OXIDASE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN, EYE/RESPIRATORY TRACT
IRRITATION UPON CONTACT. ALLERGIC REACTIONS IN CERTAIN SENSITIVE
INDIVIDUALS MAY DEVELOP.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, ALLERGIC REACTIONS.
Medical Cond Aggravated by Exposure:ALLERGIES, ASTHMA.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES/SKIN: WASH THOROUGHLY
W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:AVOID PHYSICAL CONTACT & DUST DURING REMOVAL.
USE NORMAL CLEAN-UP PROCEDURES & WASH THOROUGHLY W/WATER.
*Handling and Storage *
Handling and Storage Precautions:NONE
Other Precautions:NONE
* Physical/Chemical Properties *
Solubility in Water:(SEE SUPP)
Appearance and Odor:POWDERS- WHITE TO TAN. LIQUIDS-WHITE TO BROWN. BOTH
HAVE TYPICAL ENZYME ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:FLUSH IN SEWERAGE SYSTEM W/WATER IAW/FEDERAL,
STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:UNLESS AIR MONITORING DEMONSTRATES VAPOR/MIST
LEVELS >APPLICABLE LIMITS, NO RESPIRATOR IS REQUIRED. USE PROPERLY
FITTED RESPIRATOR NIOSH/MSHA APPROVED DURING APPLICATION. FOLLOW
MANUFACTURER DIRECTION S FOR RESPIRATOR USE.
Ventilation:REQUIRED FOR SPRAYING/IN CONFINED AREA. VENTILATION
EQUIPMENT SHOULD BE EXPLOSION PROOF.
Other Protective Equipment:NEOPRENE/PLASTIC APRON, PROTECTIVE CLOTHING
COVERING EXPOSED SKIN AREAS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE
CONTENTS MAY BE HARMFUL/FATAL.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NAPHTHA (PETROLEUM), HEAVY STRAIGHT RUN NAPHTHA (PETROLEUM)
Fraction by Wt: 5%
Ingred Name:GILSONITE
Ingred Name:ETHYLENE GLYCOL PROPYL ETHER, EKTASOLVE EP,
2-PROPOXYETHANOL
Fraction by Wt: 1%
THEORETICAL
Ingred Name:STODDARD SOLVENT (PETROLEUM DISTILLATE), MINERAL SPIRITS
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED, SWALLOWED/ABSORBED
THROUGH THE SKIN. INHALATION: MAY AFFECT THE BRAIN, NERVOUS SYSTEM
& RESPIRATORY SYSTEM. OVEREXPOSURE MAY CAUSE
NOSE/THROAT/RESPIRATORY IRRITATION. SKIN/EYE IRRI TATION. MAY CAUSE
KIDNEY/BLOOD/EYE DAMAGE. OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, DIZZINESS, HEADACHE, NAUSEA
Medical Cond Aggravated by Exposure:ANY RESPIRATORY/SKIN CONDITIONS.
* First Aid Measures *
WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1
Upper Limits:6
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG
Fire Fighting Procedures:MUST WEAR SELF CONTAINED BREATHING
APPARATUS/AIR MASKS. CONTAINERS EXPOSED TO FIRE SHOULD BE KEPT COOL
W/WATER SPRAY.
Unusual Fire/Explosion Hazard:CONTAMINATED RAGS/WIPES/SAWDUST MAY CATCH
FIRE SPONTANEOUSLY. STORE WASTE UNDER WATER IN CLOSED METAL
CONTAINERS UNTIL DISPOSED OF.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. AVOID BREATHING VAPORS. USE
SELF CONTAINED BREATHING APPARATUS/AIRMASK FOR LARGE LEAKS IN A
CONFINED AREA. AVOID ALL PERSONAL CONTACT.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
SUITABLE STORAGE SHOULD BE PROVIDED IAW/OSHA.
Other Precautions:EMPTY CONTAINERS MAY CONTAIN PRODUCT
RESIDUES/FLAMMABLE/EXPLOSIVE VAPORS. DON'T CUT/PUNCTURE/WELD
ON/NEAR CONTAINER. ALL LABEL WARNINGS MUST BE OBSERVED UNTIL THE
CONTAINER HAS BEEN CLEANED/RECONDITIO NED. AVOID BREATHING VAPORS.
* Physical/Chemical Properties *
Vapor Pres:3
Vapor Density:5.1
Evaporation Rate & Reference:(BUTYL ACETATE=1): 0.2
Solubility in Water:INSOLUBLE
Appearance and Odor:NORMAL FOR A COATINGS PRODUCT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:FIRE
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
Waste Disposal Methods:DON'T INCINERATE CLOSED CONTAINERS. DISPOSE IN
CHEMICAL DISPOSAL AREA IAW/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:THE SPECIFIC RESPIRATOR SELECTED MUST BE BASED
ON CONTAMINATION LEVELS FOUND IN THE WORK PLACE.
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION TO
MEET PUBLISHED EXPOSURE LIMITS.
Other Protective Equipment:EYEWASH STATION, SAFETY SHOWER AND
PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE
* Product Identification *
Product ID:PERMOUNT SOLUTION
* Composition/Information on Ingredients *
Other REC Limits: RECOMMENDED
Ingred Name:BETA-PINENE POLYMER
Other REC Limits: RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: IRRITANT, NARCOTIC,
NEUROTOXIN. INGESTION: NARCOTIC. MAY CAUSE NAUSEA, DIARRHEA,
DYSURIA, HEMATURA, UNCONSCIOUSNESS, AND CONVULSIONS. SKIN: MAY
CAUSE IRRITATION. EYES: IRRITATION AN D CORNEAL BURNS. CHRONIC:
PROLONGED EXPOSURE MAY CAUSE KIDNEY AND BLADDER DAMAGE, CHRONIC
NEPHRITIS WITH ALBUMINURIA.
Explanation of Carcinogenicity: SPECIFIED BY MANUFACTURER.
Effects of Overexposure:IRRITATION, FATIGUE, WEAKNESS, CONFUSION,
HEADACHE, NAUSEA, IMPAIRED COORDINATION AND REACTION TIME,
PARESTHESIAS OF THE SKIN, DIZZINESS, EUPHORIA, DIALATED PUPILS,
NASAL MUCOUS SECRETION, METALLIC TA STE, DROWSINESS, TINNITUS, AND
IMPAIREDBALANCE. AFTEREFFECTS INCLUDE NERVOUSNESS, MUSCULAR
FATIGUE, AND INSOMNIA.
Medical Cond Aggravated by Exposure: SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYES: WASH WITH LARGE AMOUNTS OF WATER OR NORMAL SALINE. GET
MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AREA
WITH SOAP AND WATER. GET MEDICAL ATTENTION. INHALATION: MOVE TO
FRESH AIR AND RESTORE BREATHING IF NECESSARY. GETMEDICAL
ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION.
* Fire Fighting Measures *
Lower Limits:1.4
Upper Limits:6.7
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
* Accidental Release Measures *
Spill Release Procedures:SHUT OFF IGNITION SOURCES. STOP LEAK IF YOU
CAN DO SO WITHOUT RISK. USE WATER SPRAY TO REDUCE VAPORS. FOR SMALL
SPILL, TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL AND PLACE INTO
CONTAINERS FOR LATER DISPOSAL.
Neutralizing Agent: SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, VENTILATED AREA. KEEP
CONTAINERS CLOSED WHEN NOT IN USE. PROTECT FROM PHYSICAL DAMAGE.
Other Precautions:EMPTY CONTAINERS CAN BE HAZARDOUS DUE TO RESIDUE OF
FLAMMABLE LIQUID.
* Physical/Chemical Properties *
HCC:F2
Solubility in Water:INSOLUBLE
Appearance and Odor:YELLOW LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS. MAY ALSO REACT WITH MANY OTHER CHEMICALS WITH
VIGOROUS AND EXPLOSIVE REACTIONS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION.
Hazardous Decomposition Products:TOXIC OXIDES OF CARBON.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION HAS NOT
BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRABLE FUME RESPIRATOR OR
AIR SUPPLIED RESPIRATOR WHEN WELDING IN A CONFINED SPACE OR WHERE
LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW THE
RECOMMENDED EXPOSURE LI MIT.
Ventilation:USE ENOUGH VENTILATION, LOCAL EXHAUST AT ARC OR BOTH TO
KEEP FUMES & GASES FROM WORKER'S BREATHING ZONE & GENERAL AREA.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
HAND, HEAD & BODY PROT WHICH HELP PVNT INJURY FROM RADIATION, (ING
Work Hygienic Practices:TRAIN THE WELDER TO KEEP HIS/HER HEAD OUT OF
THE FUMES.
Supplemental Safety and Health
HAZ DECOMP PRODS: OTHER CNDTNS WHICH ALSO INFLUENCE COMPOSITION & QTY
OF FUMES & GASES TO WHICH WORKERS MAY BE EXPOSED INCL: COATINGS ON
METAL BEING WELDED (SUCH AS PAINT, PLATING OR GALVANIZING), NUM BER
OF WELDERS & VOL OF WORK AREA, QUALITY & AMT OF VENT, POSITION OF
WELDER'S HEAD W/RESPECT TO FUME PLUME, (ING 8)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:IRON
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:MOLYBDENUM
OSHA PEL:5 MG/M3 DUST, C
ACGIH TLV:5 MG/M3 DUST
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SILICON
Ingred Name:NIOBIUM; (COLUMBIUM)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT:AS WELL AS PRESENCE OF CONTAMINANTS IN ATM (SUCH AS
CHLORINATED HYDROCARB VAPS FROM CLEANING & DEGREASING (ING 9)
Ingred Name:ING 8: ACTIVITIES). WHEN ELECTRODE IS CONSUMED, FUME & GAS
Ingred Name:ING 9:LISTED INGREDS. FUMES & GAS DECOMP PRODS & NOT
FROM AWS. SEE AWS PUB: "FUMES & GASES IN WELDING ENVIRONMENT."
Ingred Name:EYE PROT: & FULL LENGTH FACESHIELDW/FILTER LENS. PROVIDE
PROT, AS WELL AS DARK SUBSTANTIAL CLOTHING.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ELECTRIC ARC-WELDING MAY CREATE ONE OR
MORE OF THE FOLLOWING HEALTH HAZARDS: FUMES AND GASES CAN BE
DANGEROUS TO HEALTH. ARC RAYS CAN INJURE EYES AND BURN SKIN.
ELECTRIC SHOCK CAN KILL. SHORT-TERM OVE REXPOSURE TO WELDING FUMES
MAY RESULT IN DISCOMFORT SUCH AS: DIZZINESS, NAUSEA OR DRYNESS OR
(EFTS OF OVEREXP)
CARCIN.
Effects of Overexposure:HLTH HAZ: IRRITATION OF NOSE, THROAT OR EYES,
TIGHTNESS IN CHEST, FEVER AND ALLERGIC REACTIONS. LONG TERM
(CHRONIC) OVEREXPOSURE TO WELDING FUMES MAY LEAD TO SIDEROSIS (IRON
DEPOSIT IN LUNGS) AND IS B ELIEVED BY SOME INVESTIGATORS TO
AFFECTPULMONARY FUNCTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:REMOVE TO FRESH AIR, OBTAIN MEDICAL ATTENTION. EMPLOY FIRST
AID TECHNIQUES RECOMMENDED BY THE AMERICAN RED CROSS. INGEST: CALL
MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIV
E OXYGEN/ARTIFICIAL RESPIRATION) . EYES: IMMEDIATELY FLUSH
MD . SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD .
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE COMBUSTS
PREVENTION DURING USE OF WELDING & ALLIED PROCEDURES.
* Accidental Release Measures *
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:READ & UNDERSTAND MFR'S INSTRUCTIONS &
PREC LABEL ON PROD. TRAIN WELDER NOT TO TOUCH LIVE ELEC PARTS & TO
INSULATE HIMSELF/HERSELF FROM WORK & GROUND.
Other Precautions:USE EXHST SYS TO CLEAR WELD FUMES. MAKE SURE INHALED
AIR DOES NOT CNTN FUME CONSTITUENTS ABOVE PEL. NOTE:OTHER PRECS FOR
WELDING & CU TTING, WELDING HANDBOOK, VOL 1, CH 9.
* Physical/Chemical Properties *
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE UNLESS OTHERWISE SPECIFIED.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:COMPOSITION & QUALITY OF WELDING FUMES
& GASES DEPEND ON METAL BEING WELDED, PROCESS, PROC & ELECTRODES
USED. (SUPDAT)
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT RESIDUE, DISPOSABLE CONTAINER OR
LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNDER NORMAL USE CONDITIONS.
Ventilation:NO SPECIAL REQUIREMENTS
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. USE GOOD PERSONAL HYGIENE PRACTICES. WASH THOROUGHLY AFTER
HANDLING.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:TERRY A MEYERS
* Composition/Information on Ingredients *
Ingred Name:TETRASODIUM SALT OF ETHYLENEDIAMINETETRAACETIC ACID, SODIUM
EDTA, SODIUM (DI) ETHYLENEDIAMINE TETRAACETATE
Fraction by Wt: 1-3%
Ingred Name:WATER
Ingred Name:QUARTERNARY AMMONIUM COMPOUNDS,
ETHYLBIS(HYDROXYETHYL)TALLOWALKYL, ETHOXYLATED, ET SULFATES
Fraction by Wt: 1-3%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: DIRECT CONTACT MAY CAUSE
IRRITATION. SKIN: PROLONGED/REPEATED CONTACT MAY CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
Medical Cond Aggravated by Exposure:INDIVIDUALS W/CHRONIC RESPIRATORY
DISORDERS; ASTHMA, CHRONIC BRONCHITIS, EMPHYSEMA
* First Aid Measures *
WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG
Fire Fighting Procedures:NORMAL FIRE FIGHTING PROCEDURES MAY BE USED.
COOL & USE CAUTION WHEN APPROACHING/HANDLING FIRE EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CONTAINER MAY BURST IN HEAT OF FIRE.
* Accidental Release Measures *
Spill Release Procedures:ABSORB W/OIL-DRI/SIMILAR INERT MATERIAL.
SWEEP/SCRAPE UP & CONTAINERIZE. RINSE AREA THOROUGHLY W/WATER.
WEAR/USE APPROPRIATE PROTECTIVE EQUIPMENT.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE W/ADEQUATE
VENTILATION. KEEP FROM FREEZING. PRODUCT RESIDUE MAY REMAIN ON/IN
EMPTY CONTAINERS.
Other Precautions:ALL PRECAUTIONS FOR HANDLING THE PRODUCT MUST BE USED
IN HANDLING THE EMPTY CONTIANER & RESIDUE. AVOID CONTACT W/EYES.
AVOID INHALATION OF EXPOSURES TO ANY MAN-MADE FOG, MIST/DUST.
* Physical/Chemical Properties *
pH:(SUPP)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, ORANGE LIQUID W/NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS; MURIATIC ACID
Stability Condition to Avoid:FREEZING
Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:WASTE MAY BE SEWERED TO A PUBLIC-OWNED TREATMENT
WORKS/DISPOSED OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED CERTIFIED MASK FOR DUST
AND MISTS.
Ventilation:USE VENTILATION AS REQUIRED TO CONTROL VAPOR
CONCENTRATIONS.
Other Protective Equipment:EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD
BE AVAILABLE FOR USE IN AN EMERGENCY.
Work Hygienic Practices:DO NOT INHAL SPRAY FROM AIR BRUSH/SANDING
OPERATION.
Supplemental Safety and Health
* Product Identification *
CAGE:BINNE
CAGE:BINNE
* Composition/Information on Ingredients *
Ingred Name:SPILL PROC: CONTAINERS; SEAL TIGHTLY FOR PROPER DISPOSAL.
Ingred Name:TITANIUM DIOXIDE
Ingred Name:SILICA GEL
OSHA PEL:6 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: INERT, NUISANCE PARTICULATE DUST.
AMORPHOUS SILICA CAN AFFECT BODY IF IT COMES IN CONT W/EYES. SKIN:
NON-TOXIC. INHAL: INERT, NUISANCE PARTICULATE DUST. SEE OTHER PREC.
PRLNGD INHAL OF AMORPHOUS SILICA MAY CAUSE SILICOSIS W/SCAR OF
LUNGS, COUGH, & SHORT OF BRTH. INGEST: PROD MAY BE IRRIT TO GI
TRACT IF INGESTED.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:NO SPECIFIC HAZARD IS KNOWN.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN, EYE AND
RESPIRATOR DISORDERS, IMPAIRED FUNCTIONS FROM PRE-EXISTING
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
* First Aid Measures *
MINUTES. SEEK MEDICAL ATTENTION IF ANY SYMPTOMS PERSIST. SKIN: WIPE
EXCESS FROM SKIN AND FLUSH WITH WATER USING SOAP IF AVAILABLE. SEEK
MEDICAL A TTENTION IF IRRITATION OCCURS. INHALATION: REMOVE VICTIM
TO FRESH AIR AND TREAT SYMPTOMATICALLY. INGESTION: CONSULT
PHYSICIAN, HOSPITAL OR POISON CONTROL CENTER IF PRODUCT IS
INGESTED.
* Fire Fighting Measures *
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL OR CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:PRODUCT AS SUPPLIED WILL SPLATTER AND
* Accidental Release Measures *
Spill Release Procedures:SOAK UP RESIDUE W/ABSORB SUCH AS CLAY,
SAND/OTHER SUITABLE MATL; PLACE IN NON-LEAKING CNTNRS FOR PROPER
DISP. FLUSH AREA W/H*2O TO REMOVE TRACE RESIDUE; DISP OF FLUSH SOLN
AS ABOVE. SMALL SPILLS-TAKE UP W/ABSORB MATL & PLACE IN
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT INHALE SPRAY FROM AIR BRUSH.
USE WINDOW TO EXHAUST FAN TO REMOVE VAPORS AND ASSURE ADEQUATE
CROSS VENTILATION. DO NOT INHAL FROM SANDING OPER.
Other Precautions:FOR AIR BRUSHING/SANDING DRIED PAINT: USE NIOSH/MSHA
APPROVED CERTIFIED RESPIRATOR.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:<1 (ETHER=1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE AND
UNIDENTIFIED (UNKNOWN) ORGANIC COMPOUNDS MAY BE FORMED DURING
COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:REFER TO LATEST EPA OR FEDERAL, STATE, OR LOCAL
REGULATIONS REGARDING PROPER DISPOSAL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE CATRIDGE-TYPE IAW MFR DIRCTION AIR CONTMNTS
UNCONTRLABLE
Ventilation:LOCAL & MECH PROVIDE SUFFICIENT VENT TO KEEP BELOW TLV
LEVEL
Other Protective Equipment:USE APPROPRIATE INDUSTRIAL HYGIENE
PRACTICES.
Supplemental Safety and Health
MSDS FM MFR DATED:UNKNOWN;VAP PRESSURE/DENSITY NOTED OF PRINCIPAL
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
ACGIH TLV:0.5 MG/CUM
Ingred Name:ZINC (SARA III)
Fraction by Wt: 6.3%
Ingred Name:AROMATIC PETROLEUM DISTILLATE(BY ANALOGY TO XYLENE)
Fraction by Wt: 3.0%
Ingred Name:ETHER ALCOHOL
Fraction by Wt: 5.0%
* Hazards Identification *
Effects of Overexposure:CAUSES HEADACHE,NAUSEA,IMPAIRMENT OF REACTION
TIME AND COORDINATION.
* First Aid Measures *
First Aid:INHALATION:MOVE TO FRESH AIR TO IMPROVE BREATHING;SKIN:WASH
WITH SOAP & WATER.REMOVE CONTAMINATED CLOTHING;EYES:FLUSH WITH
* Fire Fighting Measures *
Lower Limits:1.1
Extinguishing Media:CO*2, FOAM, DRY CHEM.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION
SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM
FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL
ABSORBENT,SHOVEL INTO METAL DRUMS:LG SPILL:DI KE W COMMERCIAL
ABSORBENT,PUMP INTO COVERED DRUMS.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT,SPARKS & OPEN
FLAMES.CLOSE CONTAINERS AFTER EACH USE.DO NOT STORE ABOVE
Other Precautions:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
SMOKING;OBSERVE LABEL PRECAUTIONS;CONTAINERS SHOULD BE GROUNDED
WHEN POURING;USE NON-SPARKING TOOLS TO REMOVE SPILL;AVOID BREATHING
VAPORS.
* Physical/Chemical Properties *
HCC:F4
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MODERATE
Appearance and Odor:BROWN,SEMI-VISCOUS LIQUID;STRONG SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, CORROSIVES
Stability Condition to Avoid:HEAT, IGNITION SOURCES
Hazardous Decomposition Products:CO,CO*2,SMOKE, & OXIDES OF CHROMIUM &
ZINC.
* Disposal Considerations *
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS IF NEEDED.
Ventilation:GENRAL VENTILATION IS SUFFICIENT.
Other Protective Equipment:USE CHEMICAL RESISTANT APRON OR OTHER
IMPERVIOUS CLOTHING,IF NEEDED,TO AVOID CONTAMINATING REGULAR
CLOTHING.EYE-WASH FAC
Supplemental Safety and Health
METHOD B, LEVEL 3.
* Product Identification *
Product ID:FLAW-FINDER AG-FL EMULSIFIER
Preparer's Name:GEORGE KOSEL,CHIEF CHEM
* Composition/Information on Ingredients *
Ingred Name:PER MANUFACTURER'S MSDS,ITEM CONTAINS NO HAZARDOUS
INGREDIENTS ACCORDING TO THE PROVISIONS GIVEN IN
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CAUSES IRRITATION OF EYES, AND
SKIN; INGESTION MAY CAUSE NAUSEA, VOMITING,ETC..
Effects of Overexposure:INHALATION: DUE TO ITS LOW VOLATILITY, EXPOSURE
TO THIS MATERIAL UNDER AMBIENT CONDITIONS IS NOT EXPECTED TO
PRODUCE ADVERSE HEALTH EFFECTS FOLLOWING NORMAL WORKPLACE EXPOSURE;
SKIN: CAN CAUSE MODERAT E IRRITATION; EYES: MAY CAUSE CORNEAL
INJURY; INGESTION: MAY CAUSE NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:NONE CURRENTLY KNOWN.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR; SKIN AND EYES: FLUSH WITH
IRRITATION PERSISTS; INGESTION: DRINK TWO (2) GLASSES OF WATER AND
INDUCE VOMITING. CALL A PHYSICIAN.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE WATER SPRAY, ARBON DIOXIDE,DRY
CHEMICAL,ALCOHOAL TYPE OR UNIVERSAL TYPE FOAMS APPLIED BY MFR
RECOMMENDED TECHNIQUES.
Fire Fighting Procedures:DO NOT SPRAY POOL FIRES DIRECTLY.A SOLID
STREAM OF WATER DIRECTED INTO HOT,BURNING LIQUID COULD CAUSE
FROTHING.AVOID BREATHING VAPOR OR FUMES.USE PROTCTV EQUIP.
Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST/EXPLODE IN HEAT OF
FIRE.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION; RECOVER FREE
LIQUID; USE SUITABLE INERT ABSORBENT SUCH AS SAND, CLAY, ETC..TO
ABSORB LIQUID. THIS MATERIAL IS HIGHLY TOXIC TO FISH. AVOID
DISCHARGE TO NATURAL WATERS. A VOID DRAINAGE OF LARGE SPILLS TO
SEWERS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP
CONTAINERS CLOSED AND PLAINLY LABELED.
Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER
SOURCES OF IGNITION.
* Physical/Chemical Properties *
HCC:N1
Vapor Density:>1.0(AIR=1
Evaporation Rate & Reference:<1.0 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, RED LIQUID SLIGHT, MILD ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENT.
Stability Condition to Avoid:EXTREME HEAT
Hazardous Decomposition Products:BURNING CAN PRODUCE CARBON DIOXIDE
AND/OR CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE LOCAL,STATE AND FEDERAL REGULATIONS.AT VERY LOW
A BIOLOGICAL WASTEWATER TRE ATMENT PLANT;AT HI-CONC.,IT CAUSES
FOAMING PROBLM.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:GENERAL MECHANICAL OR LOCAL EXHAUST. USE NIOSH/MNSHA
APPROVED SELF-CONTAINED RESPIRATOR.
Other Protective Equipment:IMMEDIATE ACCESS TO SAFETY SHOWER AND EYE
WASH.
Work Hygienic Practices:PROVIDE PROPER WASH/CLEAN UP FACILITIES FOR
PROPER HYGENE. CONTACT LENSES SHOULD NOT BE WORN WHEN WORKING WITH
THIS MATERIAL.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:T.J ATKINSON/G.M. HOUSE
* Composition/Information on Ingredients *
Ingred Name:DIETHYLENETRIAMINE LIQUID RESIN ADDUCT
Code:F
Ingred Name:POLYOXYPROPYLENEDIAMINE
Ingred Name:TETRAETHYLENEPENTAMINE
Ingred Name:REACTION PRODUCTS OF TETA AND PROPYLENE OXIDE
Code:F
Ingred Name:TRIETHYLENETETRAMINE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: EXCESSIVE EXPOSURE
TO VAPOR OR MISTS IRRITATES UPPER RESPIRATORY TRACT: NASAL
DISCHARGE, COUGHING, DISCOMFORT IN EYES, NOSE, THROAT, CHEST. MAY
CAUSE DIFFICULTY BREATHING AND LUNG DAMAGE. CHRONIC INHAL: MAY
CAUSE LUNG DAMAGE/RESPIRATORY SENSITIZATION. ACUTE SKIN: CORROSIVE.
MAY CAUSE SEVERE SKIN DAMAGE W/BURNS/BLISTERING, & ALLERGIC
REACTION. CHRONIC SKIN: PERSISTANT IRRITATION AND DERMATITIS.
ABSORBTION OF MATERIAL IN HARMFUL AMOUNTS. EYE: BLURRED VISION,
IRRITATION, CORNEAL INJURY W/PERMANENT IMPAIRMENT. INGESTION:
MODERATELY TOXIC. GASTROINTESTINAL IRRITATION/ULCERATION. MAY
CAUSE BURNS OF MOUTH/THROAT.
Effects of Overexposure:SKIN: BURNS/BLISTERING. IRRITATION OF NOSE AND
THROAT. HEADACHE, NAUSEA, VOMITING. EYE IRRITATION/BLURRED VISION.
DANGER: STRONG SKIN SENSITIZER. CORROSIVE. MAY CAUSE SEVERE BURNS
TO EYES AND SKIN. HA RMFUL IF SWALLOWED. RESPIRATORY TRACT
IRRITATION.
Medical Cond Aggravated by Exposure:EXISTING RESPIRATORY CONDITIONS,
SUCH AS ASTHMA AND BRONCHITIS. EXISTING SKIN CONDITIONS.
* First Aid Measures *
First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH COPIOUS AMOUNTS
OF WATER WITH SOAP. DO NOT APPLY GREASES OR OINTMENTS. SEE DR.
MEDICAL ATTENT ION. INHALATION: REMOVE TO FRESH AIR. CALL DR.
INGESTION: IF CONSCIOUS, DRINK PLENTY OF WATER. DO NOT INDUCE
VOMITING. IF VOMITING OCCURS, KEEP AIRWAY CLEAR. CALL DR.
* Fire Fighting Measures *
Flash Point Method:OC
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, CARBON
DIOXIDE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
COMPLETE FULL-BODY PERSONAL PROTECTIVE EQUIPMENT. IF SPILL HAS
IGNITED, USE WATER SPRAY TO DISPERSE VAPORS AND PROTECT PERSONEL
ATTEMPTING TO STOP LEAK. USE W ATER TO COOL FIRE EXPOSED CONTS.
Unusual Fire/Explosion Hazard:WHEN MIXED WITH SAWDUST, WOODCHIPS, OR
OTHER CELLULOSIC MATERIAL, SPONTANEOUS COMBUSTION CAN OCCUR UNDER
CERTAIN CONDITIONS. HARDENER, MIXED W/ SAWDUST, HEAT IS GENERATED
AS AIR OXIDIZES AMINE. IF HEA T IS NOT DISSIPATED, IT CAN IGNITE
THE SAWDUST.
* Accidental Release Measures *
Spill Release Procedures:STOP LEAK WITHOUT ADDITIONAL RISK. DIKE &
CONTAIN SPILL. VENTILATE AREA. LARGE SPILL: DIKE & PUMP INTO PROPER
CONT. SMALL SPILL: DILUTE W/WATER & RECOVER/OR USE INERT,
NONCOMBUSTABLE ABSORBANT MATERIA L (EG. SAND) & SHOVEL INTO
SUITABLE CONT. DO NOT USE SAWDUST, WOOD CHIPS OR OTHER CELLULOSIC
MATERIALS, SINCE RISK OF SPONTANEOUS COMBUSTION EXISTS. WASH SPILL
RESIDUE W/ WARM SOAPY WATER.
*Handling and Storage *
TWO YEARS OR MORE IN ORIGINAL SEALED CONTAINER. STORE IN COOL DRY
PLACE WITH ADEQUATE VENTILATION.
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. AVOID CONTACT
WITH SKIN AND EYES. WASH THOROUGHLY AFTER HANDLING.
* Physical/Chemical Properties *
Vapor Density:>AIR
Solubility in Water:APPRECIABLE
Appearance and Odor:LIQUID, LIGHT YELLOW, AMONIA-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MAY REACT VIOLENTLY WHEN IN CONTACT WITH OXIDIZING MATERIALS, ACIDS, OR
HALOGENATED COMPOUNDS SUCH AS METHYLENE CHLORIDE. REACTIONS MAY BE
SLOW INNITIALLY, THEN RAPIDLY GENERATE HEAT AND VAPOR PRESSURE
Hazardous Decomposition Products:BURNING OR EXCESSIVE HEAT MAY PRODUCE
TOXIC LEVELS OF AMMONIA. OXIDES OF NITROGEN AND IRRITATING
ALDEHYDES.
* Toxicological Information*
Toxicological Information:ORAL: SLIGHTLY TOXIC. INHALATION: NO
REMARKABLE EFFECTS. DERMAL: SLIGHTLY TOXIC. CORROSIVE.
* Disposal Considerations *
Waste Disposal Methods:EVALUATION OF THIS PRODUCT BY RCRA CRITERIA IS
NOT A HAZARDOUS WASTE IN ITS PURCHASED FORM. IT IS RESPONSIBILITY
OF USER TO DETERMINE PROPER DISPOSAL METHODS. INCINERATION OR
LANDFILL MAY BE PREFERRED METHODS WHEN IN ACCORDANCE FED, STATE,
AND LOCAL REGULATIONS.
* MSDS Transport Information *
Transport Information:DOT SHIPPING NAME: POLYAMINES, LIQUID,
CORROSIVE, N.O.S.; TECHNICAL SHIPPING NAME: DIETHYLENETRIAMINE,
III
* Regulatory Information *
SARA Title III Information:NONE
Federal Regulatory Information:OSHA: CORROSIVE, STRONG IRRITANT,
SENSITIZER; TSCA:ALL COMPONENTS ARE LISTED ON TSCA INVENTORY
State Regulatory Information:NONE
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD
LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP
SUPPLIER, WHICHEVER IS LOWEST. A NIOS H APPRVD FULL-FACE PIECE
SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (SUP DAT)
Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF BECAUSE IT
CAN CTL EMISSIONS OF (OTHER INFO)
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR CLEAN BODY-COVERING CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
RESP PROT: WHICHEVER IS LOWEST. FOR EMERS/INSTANCES WHERE EXPOS LEVELS
ARE NOT KNOWN, USE A NIOSH APPRVD FULL-FACEPIECE POS-PRESS,
AIR-SUPPLIED RESP. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT
WORKER S IN OXYGEN-DEFICIENT ATMS. PHYSICAL/CHEM PROPERTIES:
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM CHLORIDE
Other REC Limits:N/K
OSHA STEL:N/K
ACGIH STEL:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: INHALATION OF HIGH
CONCENTRATIONS OF DUST MAY CAUSE NASAL OR LUNG IRRITATION.
INGESTION: LARGE QUANTITIES CAN PRODUCE GASTROINTESTINAL IRRITATION
AND VOMITING. MAY PRODUCE WEAKNESSAND CIRCULATORY PROBLEMS. MAY
AFFECT HEART. IN SEVERE CASES, INGESTION MAY BE FATAL. SKIN:
CONTACT MAY CAUSE IRRITATION OR RASH, PARTICULARLY WITH MOIST SKIN.
EYES: POTASSIUM CHLORIDE IS A MODERATE EY E IRRITANT. REDNESS,
TEARING, POSSIBLE ABRASION CAN OCCUR. CHRONIC: NO INFORMATION
FOUND.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:PERSONS WITH IMPAIRED KIDNEY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL
PERSONNEL. NEVER G IVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CALL A PHYSICIAN. SKIN: REMOVE ANY CONTAMINATED CLOTHING. WASH SKIN
IF IRRITATION DEV ELOPS OR PERSISTS. EYES: IN CASE OF CONTACT,
MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. CALL A
PHYSICIAN IF IRRITATION PERSISTS.
* Fire Fighting Measures *
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. NOT
CONSIDERED TO BE AN EXPLOSION HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN CONTROL
MEASURES SECTION. PICK UP AND PLACE IN A SUITABLE CONTAINER FOR
RECLAMATION OR DISPOSAL, USING A METHOD THAT DOES NOT GENERATE
DUST.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY
SINCE THEY RETAIN PRODUCT RESIDUES(DUST, SOLIDS); OBSERVE ALL
WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT.
Other Precautions:AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH
ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
* Physical/Chemical Properties *
B.P. Text:SUBLIMES
pH:SEE SUP DAT
Appearance and Odor:WHITE CRYSTALS OR POWDER; ODORLESS.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BROMINE TRIFLUORIDE; POTASSIUM PERMANGANATE PLUS SULFURIC ACID.
Stability Condition to Avoid:NO INFORMATION FOUND.
Hazardous Decomposition Products:OXIDES OF THE CONTAINED METAL AND
HALOGEN, POSSIBLY ALSO FREE, OR IONIC HALOGEN.
* Toxicological Information*
MUTAGEN.
* Ecological Information *
Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL
TOXICITY: NO INFORMATION FOUND.
* Disposal Considerations *
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROPRIATE & APPROVED WASTE DISPOSAL
FACILITY. PROCESSING, USE/CONTAMINATION OF PROD MAY CHANGE WASTE
MANAGEMENT OPTIONS. STATE & LOCAL DISP REGULATIONS MAY DIFFER FROM
FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER & UNUSED C
ONTENTS I/A/W FEDERAL, STATE & LOCAL REQUIREMENTS.
* MSDS Transport Information *
Transport Information:NOT REGULATED. OTHER INFORMATION: LAB PROTECTIVE
STORAGE). EMERGENCY OVERVIEW: CAUTION! MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE IRRITAT ION TO SKIN, EYES, AND RESPIRATORY TRACT.
* Regulatory Information *
NO; FIRE: NO; PRESSURE: NO; REACGIVITY: NO (PURE/SOLID).
Federal Regulatory Information:POTASSIUM CHLORIDE LISTED IN TSCA, EC,
JAPAN, AUSTRALIA, KOREA, CANADA DSL; NOT LISTED IN CANADA NDSL,
FOUND. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS: THIS MSDS HAS
BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED
PRODUCTS REGULATIONS (CPR) AND T HE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
State Regulatory Information:POTASSIUM CHLORIDE LISTED IN PHILADELPHIA.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:ANY NIOSH APPROVED FULL FACEPIECE RESPIRATOR
WITH AN ORGANIC VAPOR CARTRIDGE, ANY NIOSH APPROVED ESCAPE TYPE
SCBA, ANY NIOSH APPROVED FULL FACEPIECE PRESSURE DEMAND SCBA, ANY
NIOSH APPROVED FULL-FACE PIECE POSITIVE PRESSURE, SUPPLIED-AIR.
Ventilation:LOCAL EXHAUST - NECESSARY IF TLV (TWA) EXCEEDED.
Other Protective Equipment:HOODED CHEMICAL-RESISTANT CLOTHING (OVERALLS
& LONG SLEEVE JACKET, OR 1 OR 2 PIECE CHEMICAL SPLASH SUIT) &
CHEMICAL BOOT
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING.
Supplemental Safety and Health
CORROSIVE!
* Product Identification *
Product ID:DECONTAMINATING AGENT, DS2
* Composition/Information on Ingredients *
Ingred Name:DIETHYLENE TRIAMINE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 PPM
Ingred Name:SODIUM HYDROXIDE (SARA III)
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
Ingred Name:2-METHOXYETHANOL (EGME) (SARA III)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:DS2 IS AN ALKALI & WITH DIRECT CONTACT
WILL CORRODE TISSUE, SKIN, EYE, RESPIRATORY MUCOSA OR GASTRIC
MUCOSA. THE EFFECTS EXHIBITED DEPEND ON ROUTE OF EXPOSURE, AMOUNT
OF SUBSTANCE PRESENT, & DURATION OF EXPOSURE. HEALTH EFFECTS RANGE
FROM MILD BURNS & PRIMARY IRRITATION TO CORNEAL OPACIFICATION,
SEVERE BURNS.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EXPOSURE TO HIGH VAPOR CONCENTRATIONS OF DS2
CAN CAUSE NAUSEA, VOMITING, AND RESPIRATORY IRRITATION AS ACUTE
EFFECTS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION-REMOVE TO FRESH AIR. IF STOP BREATHING, GIVE CPR.
IF HARD TO BREATH, GIVE OXYGEN. SEE PHYSICIAN. EYE-FLUSH EYES WITH
SKIN-FLUSHAWAY THE DS2 FROM THE SKIN WITH WATER UNTIL "SOAPINESS"
IS NO LONGER PRESENT. SEE PHYSICIAN. INGESTION-IF CONSCIOUS, GIVE
AS MUCH MILK/WATER AS POSSIBLE. DO NOT INDUCE VOMITING. SEE
PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:CARBON DIOXIDE, ALCOHOL FOAM, WATER.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:NEVER MIX OR STORE ACIDS, OXIDIZING
AGENTS, STB (SUPERTROPICAL BLEACH) OR HTH (HIGH TEST HYPOCHLORITE)
TOGETHER WITH DS2; FIRE OR EXPLOSION MAY RESULT.
* Accidental Release Measures *
Spill Release Procedures:SPILLS ON POROUS SURFACES SHOULD BE CLEANED &
NEUTRALIZED IMMEDIATELY. ALL SPILLS MUST BE COVERED WITH DRY SODIUM
BISULFATE TO NEUTRALIZE & THEN ABSORBING ON VERMICULITE, CLAY OR
DIATOMACEOUS EARTH. S COOP UP & PLACE IN AN EPOXYCOATED DRUM
&LABELED.
Neutralizing Agent:SODIUM BISULFATE.
*Handling and Storage *
DEG F) DURING STORAGE.
Other Precautions:MILITARY PERSONNEL WILL USE STANDARD ISSUE EQUIPMENT
DURING TRAINING OPERATIONS.
* Physical/Chemical Properties *
HCC:B2
Viscosity:9.9 CST
Appearance and Odor:CLEAR AMBER SOLUTION WITH AMMONIA-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALUMINUN, CADMIUN, TIN, ZINC, LEXAN, CELLULOSE ACETATE, POLYVINYL
CHLORIDE, MYLAR, ACRYLIC, PAINT, WOOL, OXIDIZERS, ACID
Stability Condition to Avoid:DS2 WILL DETERIORATE IN AIR. EXPOSURE OF
FORMING ON SURFAC
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DS2 HAS BEEN TESTED & IS A HAZARDOUS WASTE WITH
ACCUMULATED SPILL CLEANUP RESIDUE MUST COMPLY WITH RCRA, STATE AND
LOCAL HAZARDOUS WASTE R EGULATIONS & PROCEDURES.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED DUST/PESTICIDE RESPIRATOR.
Ventilation:REQUIRED
Other Protective Equipment:RUBBER BOOTS, LONG-SLEEVED SHIRT, LONG PANTS
& HAT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NOTE TO PHYSICIAN CONT'D: IF LARGE AMOUNTS ARE INGESTED & EMESIS HAS
BEEN INADEQUATE, LAVAGE STOMACH. 5MG/KG OF ACTIVATEED CHARCOAL
SUSPENSION CAN BE LEFT IN THE STOMACH TO ABSORB THE REMAINING
TOXICA NT.
* Product Identification *
Product ID:PRINCEP 4L
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL, GLYCOL
Fraction by Wt: 7%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SIMAZINE
Ingred Name:DUST,NUISANCE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPOSURE TO PRINCEP 4L CAN IRRITATE
EYES, SKIN, NOSE & THROAT. IF SWALLOWED, NAUSEA & VOMITING MAY
OCCUR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EXPOSURE TO PRINCEP 4L CAN IRRITATE EYES, SKIN,
NOSE & THROAT. IF SWALLOWED, NAUSEA & VOMITING MAY OCCUR.
* First Aid Measures *
First Aid:INGESTION: IF CONSCIOUS, GIVE 1-2 GLASSES OF WATER TO DRINK &
INDUCE VOMITING. NEVER GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. EYES:
RINSE W/PLENTY OF WATER. SKIN: WASH W/PLENTY OF SOAP & WATER,
INCLUDIN G HAIR/UNDER FINGERNAILS. INHALATION: MOVE TO FRESH AIR.
APPLY CPR IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE
TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE IF INGESTED. (SEE SUPP)
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, FOAM/CO2
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING & SCBA. EVACUATE
AREA. PREVENT USE OF CONTAMINATED BUILDINGS, AREA & EQUIPMENT UNTIL
DECONTAMINATED.
Unusual Fire/Explosion Hazard:PRINCEP 4L IS AN NFPA CLASS IIIB LIQUID.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. SMALL: COVER
MATERIAL W/ABSORBENT. SWEEP UP & PLACE IN AN APPROVED CHEMICAL
CONTAINER. WASH AREA W/WATER CONTAINING A STRONG DETERGENT. ABSORB
W/PET LITTER/OTHER ABSORBENT. FLUSH AREA W/WATER. DON'T
CONTAMINATE WATER SUPPLY
*Handling and Storage *
Handling and Storage Precautions:STORE IN A WELL VENTILATED, SECURE
AREA, OUT OF REACH OF CHILDREN/DOMESTIC ANIMALS. DON'T STORE
FOOD/BEVERAGES/TOBACCO PRODUCTS IN THE STRORAGE AREA.
Other Precautions:PREVENT AREAS WHERE THERE IS A POTENTIAL FOR EXPOSURE
TO THE MATERIAL.
* Physical/Chemical Properties *
Vapor Pres:0
Solubility in Water:6.2 MG/1
Appearance and Odor:LIGHT TAN LIQUID, ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DON'T REUSE PRODUCT CONTAINERS. DISPOSE OF IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED ONLY IN AN
APPROVED FUME HOOD OR WITH ADEQUATE VENTILATION.
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY. EYE WASH AND SAFETY EQUIPMENT SHOULD BE READILY
AVAILABLE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM SULFATE (2:1); (SULFURIC ACID, DIPOTASSIUM SALT)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SWALLOWING LARGE DOSES CAUSES SEVERE
GASTROINTESTINAL IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE.
* First Aid Measures *
First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. EYES:
SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. INGEST: INDUCE
VOMITING.
* Fire Fighting Measures *
Flash Point:NONCOMBUSTIBLE
Extinguishing Media:ANY SUITABLE FOR ADJACENT MATERIAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:TAKE UP AND CONTAINERIZE FOR PROPER DISPOSAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED. DO NOT BREATHE
DUST. DO NOT GET IN EYES. AVOID PROLONGED SKIN CONTACT. DO NOT TAKE
INTERNALLY.
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Appearance and Odor:WHITE CRYSTALLINE POWDER.
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:SOX AND K2O.
* Disposal Considerations *
Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:LOCAL EXHAUST: RECOMMENDED
Other Protective Equipment:RUBBER APRON
Work Hygienic Practices:ALWAYS WASH BEFORE EATING.
Supplemental Safety and Health
THIS COMPANY OF THIS PRODUCT HAS DISCONTINUED PRODUCTION & DISTRIBUTION
* Product Identification *
CAGE:RYCOL
CAGE:RYCOL
* Composition/Information on Ingredients *
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN
CARCINOGEN BY IARC, NTP & ACGIH)
Fraction by Wt: 1-3%
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ANY QUANTITY TAKEN BY MOUTH MAY HAVE
SERIOUS EFFECTS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: WASH THOROUGHLY
IMMEDIATELY. REMOVE CONTAMINATED CLOTHING. INGESTION: INDUCE
VOMITING. SEE A DOCTOR AT ONCE. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
* Accidental Release Measures *
Spill Release Procedures:MOP UP W/SOAP & WATER OR FLUSH DOWN DRAIN
W/LARGE QUANTITY OF WATER. NEUTRALIZE & FLUSH W/WATER.
Neutralizing Agent:ALKALINE SUCH AS SODA ASH
*Handling and Storage *
Handling and Storage Precautions:AVOID EXCESSIVE HEAT. STORE AT ROOM
TEMPERATURE. DON'T FREEZE. AVOID EASILY OXIDIZED MATERIALS. ACIDIC
SOLUTION. AVOID CONTACT W/SKIN & EYES.
Other Precautions:DON'T FLAME CUT, SAW OR WELD EMPTY CONTAINERS. THIS
IS A NON-FLAMMABLE WATER SOLUTION. THE ONLY HAZARD ASSOCIATED
W/THIS PRODUCT IS THAT OF NORMAL HAZARDS W/STRONGLY ACIDIC
SOLUTIONS OF HEAVY METALS.
* Physical/Chemical Properties *
pH:2.5
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR ORANGE SOLUTION, NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ALKALI, EASILY OXIDIZED MATERIALS
Stability Condition to Avoid:EXCESSIVE HEAT, FREEZING
* Disposal Considerations *
Waste Disposal Methods:REFER TO LOCAL, STATE, & FEDERAL REGULATIONS.
AVOID DIRECT DISPOSAL TO STREAMS & CONTAMINATION OF UNDERGROUND
WATER.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:TYPICAL USE DOES NOT REQUIRE RESPIRATORY
PROTECTION. IN AN EMER FOLLOW RESP ARE RECOMM: NIOSH/MSHA APPRVD
GAS MASK W/ORG VAP CANISTER FULL FACE PLATE/SUPPLIED AIR W/FULL
FACEPLATE/SCBA W/FULL FACEPLA TE.
Ventilation:GENERAL EXHAUST VENT SUFFICIENT TO MAINTAIN WORKPLACE CONC
BELOW PERMISSBIBLE EXPOSURE LIMITS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
UNCON PERSON. SEEK MED ATTN IMMED. NOTES TO PHYS: DUE TO LOW % OF
AMMONIUM HYDROXIDE CORR EFTS SHOULD NOT BE EVIDENT BUT WILL AC T AS
AN IRRITANT. PRIMARY RTE OF ENTRY IS SKIN & CNDTNS OF SKIN WILL BE
EXACERBATED WHEN PRLNGD /RPTD EXPOS HAS OCCURED.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:AMMONIA; (AMMONIUM HYDROXIDE)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: CONT TO ALKALINE MIXT MAY RSLT
IN IRRIT TO MUC MEMB, EYES & SKIN. EYE SYMPS RANGE FROM LACRIMATION
TO CORNEAL ULCERATION AND POSSIBLE BLINDNESS. IRRITATING BY INHAL
AND BY MIST TO UPPER RESPIRA TORY TRACT. ACCIDENTAL INGEST MAY
CAUSENAUSEA, DIARRHEA & POSSIBLE PERFORATION OF INTESTINAL LINING.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CHRONIC: PRLNGD CONT MAY RSLT IN
BURNS/BLISTER FORM TO LOCALIZED VASCULAR DAM SKIN/MUC MEMB. EXPOS
TO MIST MAY RSLT IN CHRONIC INFLAMM OF UPPER RESP TRACT. INGEST CAN
CAUS NAUS & POSS PERFOR ATION OF INTESTINAL LINING. PRLNGD EYE
CONTACT CAN LEAD TO ULCERATION AND POSSIBLE BLINDNESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:REMOVE FROM AREA TO FRESH AIR.SEEK MED ATTN IMMED.
EYE:OBJECT IS TO SEEK MED ATTN IMMED. IMMED FLUSH W/PLENTY OF WATER
EYE SURF. SEEK MED ATTN IMMED. SKIN:WASH W/PLENTYOF WATER. WASH
CLTHG BEFORE REUSE. IF ANY IRRIT PERSISTS, SEEK MED ATTN. INGEST:DO
NOT INDUCE VOMIT. GIVE LG QTY OF WATER IF AVAIL. GIVE SEVERAL
GLASSES(SUPDAT)
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:FOAM, "ALCOHOL" FOAM, CO*2, DRY CHEMICAL, WATER
SPRAY.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT . USE OF EXTING MATL DEPENDS UPON NATURE OF FIRE. USE
WATER SPRAY TO COOL EXPOSED PRESSURIZED CONTRS.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:SM SPILL-FLUSH DOWN DRAIN I/A/W APPLIC REGS.
LG SPILL-POUR INTO LARGE TANK OF WATER AND NEUTRALIZE. FLUSH TO
DRAIN WITH LARGE VOLUMES OF WATER I/A/W APPLICABLE REGS.
Neutralizing Agent:WATER.
*Handling and Storage *
Handling and Storage Precautions:STORE AT MODERATE TEMPERATURES.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. READ ENTIRE LABEL
BEFORE USING.
* Physical/Chemical Properties *
pH:SUPDAT
Solubility in Water:COMPLETE
Appearance and Odor:WHITE FOAMING, AMMONIA ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, HYPOCHLORITE BLEACHES.
Stability Condition to Avoid:ALKALIS METALS.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W STATE, FEDERAL AND LOCAL
REGULATIONS CONCERNING HLTH POLLUTION. NORM PROC. SKIM OFF FLOATING
OIL AND GREASE AND FLUSH DOWN DRAIN OR SEPARATE IN AUTOMATIC
OIL/WATER SEPARATOR AND FLUSH DOWN DRAIN.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH OR BUREAU OF MINES APPROVED ORGANIC
VAPOR-TYPE RESPIRATOR IS REQUIRED IN ABSENCE OF PROPER
ENVIRONMENTAL CONTROL.
Ventilation:PROVIDE MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST
VENTILATION AS NEEDED TO KEEP PRODUCT CONCENTRATIONS BELOW TLV.
Other Protective Equipment:USE IMPERVIOUS CLOTHING IF THERE IS DANGER
OF REPEATED OR PROLONGED CONTACT WITH LIQUID.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:A.B.BASTIAN
* Composition/Information on Ingredients *
III)
Other REC Limits:NONE SPECIFIED
Ozone Depleting Chemical:1
Ingred Name:TETRAFLUOROETHYLENE TELOMER
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: SLIGHT IRRITATION, SLIGHT
TRANSIENT CORNEAL INJURY. SKIN: PROLONGED CONTACT MAY CAUSE
IRRITATION, DEFATTING. INHALATION: TEMPORARY NERVOUS SYSTEM
DEPRESSION, DIZZINESS, HEADACHE, CONFUSION, INCO ORDINATION, HEART
IRREULARITIES, UNCONSCIOUSNESS, DEATH. INGESTION: SINGLE DOSE ORAL
TOXICITY LOW.
Explanation of Carcinogenicity:IS NOT LISTED AS A CARCINOGEN BY IARC,
NTP OR OSHA.
Effects of Overexposure:EYES: IRRITATION, PAIN. SKIN: IRRITATION,
DEFATTING. INHALATION: DIZZINESS, HEADACHE, CONFUSION,
INCOORDINATION, HEART IRREGULARITIES, UNCONSCIOUSNESS, DEATH.
INGESTION: ORAL TOXICITY LOW.
Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING DISEASES
OF THE CENTRAL NERVOUS SYSTEM OR CARDIOVASCULAR SYSTEM MAY HAVE
INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURE.
* First Aid Measures *
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION
PERSISTS GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
FLUSH AREA WITH LARGE AMOUNTS OF WATER. INHALATION: MOVE TO FRESH
AIR. IF NOT BREATHING GIVE CPR. IF BREATHING DIFFICULT GIVE
OXYGEN. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:WATER FOG, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED
SELF-CONTAINED, POSITIVE PRESSURE RESPIRATORY EQUIPMENT.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES. VENTILATE AREA.
CONTAIN LIQUIDS AND TRANSFER TO CLOSED CONTAINERS FOR DISPOSAL.
KEEP OUT OF DRAINS, SEWERS, WATERWAYS. COLLECT RESIDUE ON ABSORBENT
MATERIAL AND TRANSFER TO ST EEL DRUMS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY AND
FROM PHYSICAL DAMAGE AND KEEP CLOSED.
Other Precautions:VAPORS ARE HEAVIER THAN AIR AND WILL COLLECT IN LOW
AREAS. USE OF THIS PRODUCT IN A POORLY VENTILATED AREA OR CLOSED
AREA SHOULD BE AVOIDED SINCE THIS VAPOR WILL REDUCE THE OXYGEN
AVAILABLE FOR BREATH ING.
* Physical/Chemical Properties *
HCC:V6
Vapor Density:>1
Spec Gravity:1.6
Evaporation Rate & Reference:>1 (BU AC=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:MILKY WHITE LIQUID, IRRITATING ODOR AT HIGH
CONCENTRATION.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CHEM. ACTIVE METALS. OXIDIZERS. SODIUM, POTASSIUM, CALCIUM, ETC.
ALKALINE EARTH METALS. POWDERED AL, ZN, MG, BE, ETC.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT, IGNITION SOURCES,
OPEN FLAMES, OR OTHER HIGH TEMPERATURES WHICH INDUCE THERMAL
DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, HYDROFLUORIC ACID,
SMALL AMOUNTS OF PHOSGENE AND CHLORINE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS. DO NOT INCINERATE CLOSED OR EMPTY
CONTAINERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IN CONFINED AREA USE U.S. BUR. OF MINES APPROVED
RESPIRATOR
Ventilation:LOCAL-SUFFICIENT TO KEEP CONCENTRATION BELOW GIVEN TLV
Other Protective Equipment:NORMAL PROTECTIVE CLOTHING
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ALIPHATIC NAPHTHA
Ingred Name:XYLENE SUBSTITUTE
Ingred Name:N-BUTYL ACETATE (SARA III)
Ingred Name:ALIPHATIC HYDROCARBONS
Fraction by Wt: <5.0%
Ingred Name:N-BUTYL ALCOHOL (SARA III)
Fraction by Wt: <5.0%
* Hazards Identification *
Effects of Overexposure:INHALATION-HEADACHE, NAUSEA, DIZZINESS.
PROLONGED OR REPEATED CONTACT MAY CAUSE SKIN IRRITATION.
* First Aid Measures *
First Aid:INHALATION-MOVE TO FRESH AIR. SKIN CONTACT-FLUSH WITH LARGE
AMOUNT OF WATER; REMOVE CONTAMINATED CLOTHING. EYE CONTACT-FLUSH
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS SHOULD BE
WORN BY FIREMEN
Unusual Fire/Explosion Hazard:USE WATER TO COOL CONTAINERS EXPOSED TO
FIRE
* Accidental Release Measures *
Spill Release Procedures:AVOID BREATHING VAPORS, EXTINGUISH IGNITION
SOURCES IN AREA. AVOID CONTACT WITH LIQUID.
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE AT ELEVATED TEMPERATURES.
Other Precautions:CLOSE CONTAINERS AFTER USE.
* Physical/Chemical Properties *
HCC:V3
Vapor Density:>1.0
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:MOBILE LIQUID CONTAINING VOLATILE SOLVENTS. RED
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS SOFTEN RUBBER
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN CLOSED CONTAINERS AWAY FROM
IGNITION SOURCES.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:MECHANICAL (GENERAL)
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING, SMOKING
OR USING SANITARY FACILITIES .
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:ETHER
* Composition/Information on Ingredients *
Ingred Name:ETHYL ETHER (SARA III)
Ingred Name:ETHYL ALCOHOL (ETHANOL)
Fraction by Wt: <5%
Ingred Name:WATER
Fraction by Wt: <5%
Ingred Name:INHIBITOR
Fraction by Wt: <0.5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:WILL CAUSE DROWSINESS, STUPOR OR
UNCONSCIOUSNESS ON PROLONGED EXPOSURE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:REMOVE TO FRESH AIR. INGEST:CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:WATER, ALCOHOL FOAM, CARBON DIOXIDE OR DRY
CHEMICALS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT
* Accidental Release Measures *
Spill Release Procedures:KEEP HEAT AND IGNITION SOURCES AWAY. SMALL
AMOUNTS MAY BE FLUSHED AWAY WITH WATER. LARGE AMOUNTS MAY BE
COLLECTED FOR CONTROLLED INCINERATION.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM HEAT OR ALL IGNITION
SOURCES AND OXIDIZING MATERIALS. USE ADEQUATE VENTILATION.
Other Precautions:MAY FORM PEROXIDES DURING STORAGE. IF THESE ARE
PRESENT, THEY MUST BE DECOMPOSED BEFORE ETHER CAN BE USED FOR SOME
APPLICATIONS.
* Physical/Chemical Properties *
Evaporation Rate & Reference:6.9 (N-BUTYL ACETATE = 1)
Solubility in Water:6.5
Appearance and Odor:COLORLESS LIQUID; SWEET PUNGENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
OXIDIZING MATERIALS
Stability Condition to Avoid:CONDITIONS FAVORING PEROXIDE FORMATION.
Hazardous Decomposition Products:CO*2
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE AND LOCAL
REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:SAFETY SHOWER, EYE BATH, PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PHENYL ISOTHIOCYANATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED/SWALLOWED. CAUSES
BURNS. EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES &
UPPER RESPIRATORY TRACT/EYES/SKIN. LUNG IRRITANT/FATAL. INHALATION:
MAY RESULT IN SPASM, INFLAMMAT ION & EDEMA OF THE LARYNX/BRONCHI,
CHEMICAL PNEUMONITIS/PULMONARY EDEMA. CAUSES ALLERGIC
RESPIRATORY/SKIN REACTIONS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:BURNS, IRRITATION, INFLAMMATION, COUGHING,
WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA &
VOMITING, ASTHMA, CHEST PAIN
* First Aid Measures *
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
NECESSARY. INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN
MEDICAL ATTEN TION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL POWDER
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL IGNITION SOURCES.
WEAR SELF CONTAINED BREATHING APPARATUS, RUBBER BOOTS/HEAVY RUBBER
DISPOSAL. VENTILATE & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP
TIGHTLY CLOSED & AWAY FROM HEAT & OPEN FLAME. MOISTURE SENSITIVE.
WEAR SUITABLE PROTECTIVE CLOTHING.
Other Precautions:DON'T BREATHE VAPOR. DON'T GET IN EYES, ON SKIN/ON
CLOTHING. AVOID PROLONGED/REPEATED EXPOSURE. TOXIC, LACHRYMATOR.
* Physical/Chemical Properties *
Appearance and Odor:LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, ALCOHOLS, STRONG BASES, AMINES, ACIDS, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:FIRE, HEAT, MOISTURE
Hazardous Decomposition Products:BY THERMAL DECOMPOSITION: CO, CO2,
NITROGEN OXIDES, SULFUR OXIDES
* Disposal Considerations *
Waste Disposal Methods:COMBUSTIBLE MATERIAL MAY BE BURNED IN A CHEMICAL
INCINERATOR EQUIPPED W/AN AFTER BURNER & SCRUBBER. DISPOSE OF
IAW/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Supplemental Safety and Health
* Product Identification *
Product ID:TERGISYL DETERGENT-DISINFECTANT
* Composition/Information on Ingredients *
Ingred Name:SODIUM CARBONATE (MAJOR INGRED)
Ingred Name:POTASSIUM O-BENZYL-P-CHLOROPHENATE
Ingred Name:TETRASODIUM ETHYLENE DIAMINE TETRAACETATE
* Hazards Identification *
Effects of Overexposure:CAUSES EYE & SKIN IRRITATION.HARMFUL IF
SWALLOWED
* First Aid Measures *
MILK,EGG WHITES OR GELATIN SOLUTION.IF NOT AVAILABLE,DRINK LG QTY
OF WATER.AV OID ALCOHOL.CALL DR.
* Fire Fighting Measures *
Extinguishing Media:MFR STATES PRODUCT IS NOT FLAMMABLE
*Handling and Storage *
Handling and Storage Precautions:CAUSES EYE OR SKIN IRRITATION.DO NOT
GET EITHER POWDERED CONC OR SOLUTINS IN EYES,ON SKIN OR ON
CLOTHING.DO NOT HANDLE POUCHES W/WET HANDS
Other Precautions:AVOID CONTAMINATION OF FOOD.DO NOT REMOVE POUCHES
FROM PACKAGE UNTIL YOU ARE READY TO USE THEM.STORE IN COOL,DRY
PLACE.DO NOT REUSE CONTAINER.DESTROY WHEN EMPTY.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:COMPLETE
Appearance and Odor:TURQUOISE GREEN FREE FLOWING GRANULES
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IAW FED,STATE & LOCAL CODES.DO NOT REUSE
CONTAINER.DESTROY WHEN EMPTY (MFR).
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNDER NORMAL USE.
Ventilation:USE LOCAL EXHAUST.
Other Protective Equipment:NONE.
Work Hygienic Practices:WASH HANDS AFTER USE & BEFORE EATING OR
SMOKING. AVOID PROLONGED BREATHING OF VAPORS AND CONTACT WITH SKIN
AND CLOTHES.
Supplemental Safety and Health
* Product Identification *
Product ID:VERSAGEL PART A
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:POLYMERIC DIPHENYL
Other REC Limits:NONE SPECIFIED
Ingred Name:METHYLENE BISPHENYL ISOCYANATE (MDI) (SARA III)
Other REC Limits:NONE SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Health Hazards Acute and Chronic:LABORED BREATHING, IRRITATION OF THE
UPPER RESPIRATORY SYSTEM, BRONCHITIS. OVER-EXPOSURE CAN LEAD TO
ALLERGENIC SENSITIVITY.
* First Aid Measures *
First Aid:REMOVE PERSON TO AN UNCONTAMINATED AREA, ADMINISTER OXYGEN IF
NECESSARY. FOR CONTACT WITH SKIN, WASH THOROUGHLY WITH SOAP AND
WATER. FOR EYE CONTAMINATION, IRRIGATE EYES THOROUGHLY WITH WATER
IF CONSCIOUS GIVE PLENTY OF WATER TO DRINK. INDUCE VOMITING.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:CHEMICAL FIRE EXTINGUISHERS, CO2 OR FOAM.
Fire Fighting Procedures:AIR-SUPPLIED MASKS OF THE FULL-FACED TYPE MUST
BE WORN BY FIRE FIGHTING PERSONNEL EXPOSED TO VAPORS.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSTION PRODUCTS ARE TOXIC.
* Accidental Release Measures *
Spill Release Procedures:ABSORB IN AN ABSORBENT SWEEPING COMPOUND AND
DISPOSE. NEUTRALIZE CONTAMINATED AREAS WITH 1% AMMONIA SOLUTION OR
ISOPROPYL ALCOHOL.
Neutralizing Agent:1% AMMONIA SOLUTION, ISOPROPYL ALCOHOL.
*Handling and Storage *
Handling and Storage Precautions:STORE INDOORS IN A COOL, DRY PLACE;
AVOID MOISTURE CONTAMINATION.
* Physical/Chemical Properties *
Vapor Density:> 1
Evaporation Rate & Reference:NIL (BUTYL ACETATE)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR AMBER LIQUID.
Percent Volatiles by Volume:< 1
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH MOISTURE.
Hazardous Decomposition Products:HCN, CO, OXIDES OF NITROGEN AND OTHER
TOXIC GASES.
* Disposal Considerations *
Waste Disposal Methods:BURY WASTE OR DISPOSE IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS OF ENVIRONMENTAL CONTROL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR
Ventilation:LOCAL EXHAUST: WELL VENTILATED AREA
Supplemental Safety and Health
* Product Identification *
Product ID:N-METHYL PYRROLIDONE
* Composition/Information on Ingredients *
Ingred Name:N-METHYL PYRROLIDONE
* Hazards Identification *
Effects of Overexposure:INHALATION:
HEADACHE/GIDDINESS/CONFUSION/NAUSEA. SKIN:
REDNESS/SWELLING/CRACKING/EYE BURNS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION.
GIVE OXYGEN. CALL A PHYSICIAN. EYES: IMMEDIATELY FLUSH W/WATER FOR
INDUCE VOMITING IMMEDIATELY. CALL A PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:WATER, ALCOHOL FOAM, DRY CHEMICAL, CO2
Fire Fighting Procedures:FIREFIGHTERS SHOULD BE EQUIPPED WITH SCBA/TURN
OUT GEAR.
Unusual Fire/Explosion Hazard:MODERATE FIRE HAZARD WHEN EXPOSED TO HEAT
OR FLAME.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE SOURCES OF IGNITION. ABSORB WITH
EARTH, SAND, OR SIMILAR INERT MATERIAL ANDISPOSE OF ACCORDING TO
FEDERAL, STATE, AND LOCAL REGULATIONS. FLUSH AREWITH WATER.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT WITH EYES/SKIN. WASH
THOROUGHLY AFTER HANDLING. AVOID BREATHING VAPORS. USE WITHDEQUATE
VENTILATION.
Other Precautions:KEEP THIS CONTAINER AND VAPOR FROM THIS CONTAINER
AWAY FROM HEAT AND FLAME. KEEP CONTAINER CLOSED.
* Physical/Chemical Properties *
Vapor Pres:0.2
Solubility in Water:MISCIBLE
Appearance and Odor:WATER-LIKE LIQUID, MILD AMINE-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING OR REDUCING AGENTS
Hazardous Decomposition Products:CO/NOX FUMES EMITTED WHEN HEATED TO
DECOMPOSITION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WITH LIQUID WASTE ACCORDING TO
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: IF
ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE OR AN EMERGENCY
OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR AN AIR-SUPPLIED
Ventilation:DLA-HMIS: USE ADEQUATE MECHANICAL VENTILATION OR LOCAL
EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:
EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:DLA-HMIS: WASH HANDS AFTER HANDLING AND BEFORE
EATING, DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE
REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:PRY GEL
Preparer's Name:LORI HALLER
CAGE:0T1E8
CAGE:0T1E8
* Composition/Information on Ingredients *
Ingred Name:OXALIC ACID
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
Ingred Name:PROPYLENE GLYCOL
Other REC Limits:NONE RECOMMENDED
Ingred Name:LANOLIN
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION OF DUST MAY CAUSE
IRRITATION OF UPPER RESPIRATORY TRACT. INGESTION MAY CAUSE
IRRITATION OF DIGESTIVE TRACT AND POSSIBLE CORROSIVE BURNS TO
MOUTH, THROAT & STOMACH. CONTACT WILL CAUSE EYE IRRITATION; IN
EXTREME & PROLONGEDCASES, EYES BURNS & CONJUNCTIVITIS MAY OCCUR.
NOT HARMFUL TO SKIN. CHRONIC:NONE.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED-COUGHING, SHORTNESS OF BREATH,
SNEEZING. SEYES-PAIN, BURNING/STINGING, REDNESS, TEARING.
INGESTED-NAUSEA, VOMITING, DIARRHEA, BURNS TO MOUTH/THROAT/STOMACH,
ABDOMINAL PAIN.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
LIFTING LIDS. SEE A PHYSICIAN. SKIN-WASH WITH SOAP & WATER, THEN
FLUSH WITH WATER WHILE REMOVING CONTAMINATED CLOTHES/SHOES. SEE A
PHYSICIAN.INHALED-REMOVE TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION IF NOT BREATHING. SEE A PHYSICIAN. INGESTED-DO NOT
INDUCE VOMITING! IF CONSCIOUS, DILUTE W/WATER. GET IMMEDIATE
MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: MEDIA
APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: WEAR
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP SPILLAGE IMMEDIATELY WITH MINIMUM OF
DUSTING. COLLECT IN CONTAINERS AND LABEL APPROPRIATELY WITH
MATERIAL CHEMICAL WARNING LABEL. IT IS RECOMMENDED EACH USER
ESTABLISH A SPILL PREVENTION, CON TROL AND COUNTERMEASURE PLAN
(SPCC).
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AND AWAY
FROM FOOD & FEED PRODUCTS. KEEP CONTAINERS CLOSED. DO NOT USE WHEN
MATERIALS BEING CLEANED ARE HOT.
Other Precautions:DO NOT GET INTO EYES, ON SKIN OR CLOTHING. DO NOT
BREATH DUST.
* Physical/Chemical Properties *
HCC:T6
Spec Gravity:1.1
Evaporation Rate & Reference:<1 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:WHITE GEL; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW PELS.
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN
EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING & WASH BEFORE REUSE.
Supplemental Safety and Health
MATLS TO AVOID:EXPLOSIVELY W/ORGANIC MATLS & COMBUSTS. FIRST AID
PROC:BY MOUTH TO UNCON PERS. GET MED AID IMMED. INHAL:REMOVE FROM
EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS
D FCLT, GIVE OXYG. GET MED AID. NOTE TO MD:TREAT SYMPTOMATICALLY &
SUPPORTIVELY. EYE PROT:& FULL LGTH FACESHIELD .
* Product Identification *
* Composition/Information on Ingredients *
OSHA PEL:2 PPM
ACGIH TLV:2 PPM;4 STEL
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYE:CAUSES SEVERE BURNS. MAY
CAUSE IRREVERSIBLE INJURY. SKIN:MAY CAUSE SEVERE IRRITATION. CAUSES
BURNS. MAY CAUSE DEEP, PENETRATING ULCERS. INGESTION:CAUSES
GASTROINTESTINAL TRACT BURNS. MAY CAU SE PERFORATION OF DIGESTIVE
TRACT. INHALATION:MAY BE FATAL IF INHALED. EFFECTS MAY (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:BE DELAYED. MAY CAUSE IRRIT OF RESP
TRACT W/BURNING PAIN IN NOSE & THROAT, COUGH, WHEEZING, SHORTNESS
OF BREATH & PULM EDEMA. CHRONIC:RPTD INHAL MAY CAUSE CHRONIC
BRONCH. RPTD EXPOS MAY CAUSE EROSION OF TEETH. TOX
INFO:TERATOGENICITY:EFTS ON NEWBORN:BIOCHEMICAL & METABOLIC;
FETOXICITY:STUNTED FETUS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW VICTIM
TO RUB/KEEP EYES CLSD. SKIN:GET MED AID IMMED. FLUSH W/PLENTY OF
SHOES. WASH CLTHG BEFORE REUSE. INGEST:DO NOT INDUCE VOMIT. IF
VICTIM IS CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. NEVER
GIVE ANYTHING(SUPDAT)
* Fire Fighting Measures *
Extinguishing Media:SUBSTANCE IS NONCOMBUSTIBLE; USE AGENT MOST
APPROPRIATE TO EXTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
SUBSTANCE IS NONCOMBUSTIBLE.
Unusual Fire/Explosion Hazard:STRONG OXIDIZER. CONTACT W/COMBUSTIBLE
MATERIALS MAY CAUSE A FIRE.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PPE AS INDICATED IN EXPOS CONTROLS,
PERSONAL PROT SECTION. ABSORB SPILL W/INERT MATL, (E.G., DRY
SAND/EARTH), THEN PLACE INTO CHEM WASTE CNTNR. NEUT SPILL W/SODIUM
BICARBONATE. A VAP SUPPRE SSING FOAM MAY BE USED TO REDUCE VAPORS.
Neutralizing Agent:SODIUM BICARBONATE.
*Handling and Storage *
Handling and Storage Precautions:USE W/ADEQUATE VENTILATION. DO NOT GET
IN EYES, ON SKIN OR ON CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. DO
NOT INGEST OR INHALE.
Other Precautions:DANGER! STRONG OXIDIZER. CONTACT W/OTHER MATERIAL MAY
CAUSE A FIRE. CORROSIVE. STORE IN A TIGHTLY CLOSED CONTAINER. STORE
IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM INCOMPATIBLE
SUBSTANCES.
* Physical/Chemical Properties *
Vapor Pres:6.8
Spec Gravity:1.5
pH:1
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR TO YELLOW LIQUID; STRONG, ACRID ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NFPA FIRE PROT GUIDE FOR SPECIFICS. REACTS (SUPDAT)
Stability Condition to Avoid:DECOMPOSES WHEN IN CONT W/AIR,
LIGHT/ORGANIC MATTER. AVOID HIGH TEMPS, INCOMPAT MATLS & MOISTURE.
Hazardous Decomposition Products:NITROGEN OXIDES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT W/FEDERAL,
STATE & LOCAL REGULATIONS. NOT LISTED AS A MATERIAL BANNED FROM
LAND DISPOSAL ACCORDING TO RCRA.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED NIOSH/MSHA
APPROVED ORGANIC VAPOR/PARTICULATE RESPIRATOR FOR PROTECTION
AGAINST INGREDIENTS.
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPT IF EXPOS TO MATLS IN
INGS SECTION IS MAINTAINED BELOW APPLIC EXPOS LIMS. (ING 8)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO
WHEN EXPOS TO EXTREME HEAT. EXPLO HAZ:REQS SPECIAL PRECS. DURING
EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY
NOT BE IMMED APPARENT. OBTAIN MED ATTN.EFTS OF OVEREXP:HNDLG &
EXPOS INFO . WASTE DISP METH:REGARDING POLLUTION.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (SARA III).
GM.
Fraction by Wt: SEE ING
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:OTHER PREC:ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP
LABELING. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF (ING 6)
Ingred Name:ING 5:CHILDREN. INTENTIONAL MISUSE BY DELIB CONCENTRATING &
INHALING CONTENTS CAN BE HARMFUL/FATAL. USE ONLY W/ (ING 7)
Ingred Name:ING 6:ADEQUATE VENTILATION. AVOID BREATHING VAPOR & SPRAY
MIST. AVOID CONTACT W/SKIN & EYES.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERV SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE EXPOS TO VAPS/SPRAY MIST S. REDNESS & ITCH/BURNING
SENSATION MAYINDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG
OVEREXP TO (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:SOLV INGS MAY CAUSE ADVERSE EFTS TO
LIVER, URINARY, BLOOD FORMING & CVS. RPTS HAVE ASSOC RPTD & PRLNG
OVEREXP TO SOLVS W/PERM BRAIN & NERV SYS DMG. NOTE:TOLUENE APPEARS
ON NAVY LISTING OF OCC UP CHEM REPRO HAZS. SEEK CONSULTATION FROM
APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
INGEST:NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. DO NOT
INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE
PREFERABLE. WATER MAY BE USED TO COOL CLSD(SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS(SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DOL STOR CATEGORY-1B. CONTENTS ARE
FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. CONSULT NFPA CODE.
USE APPRVD BONDING & GROUNDING PROCS.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA
VENTILATED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS &
HEATERS; TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER
SOURCES OF IGNIT. KEEP CNTNR CL SD WHEN NOT IN USE. TRANSFER (ING
5)
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM THIS PROD MAY BE HAZ AS DEFINED UNDER
DETERMINE APPLIC EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY.
DO NOT INCIN CLSD CNTNR. DISP OF I/A/W FED, STATE & LOC REGS (SUPP
DATA)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:IF CONTACT SHOULD OCCUR, WASH CONTAMINATED AREA
PROMPTLY. LAUNDER CONTAMINATED CLOTHING & CLEAN PROTECTIVE
EQUIPMENT BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:LISTERINE ANTISEPTIC
Preparer's Name:MITCHELL STEWART
CO
* Composition/Information on Ingredients *
Ingred Name:ETHYL ALCOHOL
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE TOXICITY SECTION.
* First Aid Measures *
First Aid:THERAPEUTIC CLASS: ORAL ANTI-BACTERIA RINSE. EYES:FLUSH WITH
INHALATION:REMOVE TO FRESH AIR, SEEK MEDICAL ATTENTION. SKIN:WASH
WITH SOAP & WATER UNTI L FREE OF RESIDUE. INGESTION:SEEK
PROMPTMEDICAL ATTENTION. FOR ADDITIONAL FIRST AID INFORMATION CALL:
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:3.3%
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER SPRAY, WATER.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
DECOMPOSITION OR COMBUSTION PRODUCTS: OXIDES OF CARBON.
* Accidental Release Measures *
Spill Release Procedures:PREVENT EXPOSURE. WIPE OR MOP UP SPILLED
MATERIAL. USE CARE IN THE CLEANUP OF BROKEN GLASS. WASH ALL
CONTAMINATED SURROUNDINGS W/SOAP & WATER. PLACE WASTE IN
APPROPRIATE CONTAINER(S) FOR FUTURE REUSE.
*Handling and Storage *
Handling and Storage Precautions:STORE AS STATED IN PRODUCT LABELING.
Other Precautions:MATERIAL SHOULD BE HANDLED IN SUCH A WAY AS TO AVOID
SKIN AND EYE CONTACT.
* Physical/Chemical Properties *
Solubility in Water:YES (INFINITE).
Appearance and Odor:CLEAR AMBER LIQUID; NO ODOR DETERMINED.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:UNDER LABELED STORAGE CONDITIONS, THIS
PRODUCT IS STABLE.
Hazardous Decomposition Products:OXIDES OF CARBON.
Conditions to Avoid Polymerization:HAZARDOUS POLYMERIZATION SHOULD NOT
OCCUR.
* Toxicological Information*
3 TIMES DAILY FOR 2 W EEKS) IN HUMANS DID NOT REVEAL ANY UNEXPECTED
SOFT TISSUE CONDITIONS. TWO CASES OF WHITE, DIFFUSE LESIONS AFTER
PROLONGED ORAL SURFACE CONTACT REPORTED IN HUMANS. NOT MUTAGENIC IN
AMES BACTERIAL MUTAG ENICITY TEST, MICRONUCLEOUS TEST & RAT PRIMARY
HEPATOCYTE CULTURE/REPAIR ASSAY.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS OR THE AUTHORITY HAVING JURISDICTION. INCINERATION IN A
PERMITTED INCINERATOR IS THE PREFERRED DISPOSAL METHOD.
* MSDS Transport Information *
Transport Information:SHIPPING REGULATIONS AND LIMITATIONS: PROPER
SHIPPING NAME: CONSUMER COMMODITY. ID/UN NUMBER: N/A. CONTAINER
SPECIFICATION: N/A. HAZARD CLASS: ORM-D. LABEL: N/A. PACKAGING
GROUP: N/A. SHIPPING LIMITA TIONS:SURFACE TRANSPORTATION ONLY.
MARKING: ORM-D. OTHER COMMENTS: NONE.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AS REQUIRED
Ventilation:LOCAL EXHAUST
Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS
USED.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:DICK KARBO
CAGE:KMADD
CAGE:KMADD
* Composition/Information on Ingredients *
Ingred Name:COPPER COMPOUND
Fraction by Wt: 3%
Ingred Name:BARIUM COMPOUNDS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN
CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
* First Aid Measures *
First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA
W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
* Accidental Release Measures *
Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE
CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS.
Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:INSOLUBLE
Appearance and Odor:OILY
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NEEDED WITH GOOD INDUSTRIAL VENTILATION,
UNLESS GRINDING, DRY SANDING OR MACHINING CURED MATERIAL. A NIOSH
APPROVED RESPIRATOR OR HALF MASK DUST RESPIRATOR IS NEEDED.
Ventilation:LOCAL EXHAUST WHEN GRINDING, CUTTING OR SANDING CURED
MATERIAL.
Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD
BE LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF
EXPOSURE.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE WHILE WORKING WITH
THIS PRODUCT.
Supplemental Safety and Health
USE WATER AS A LUBRICANT ON MACHINING TOOLS TO ELIMINATE DUST AND
IMPROVE MACHINABILITY OF CURED PARTS.
* Product Identification *
* Composition/Information on Ingredients *
SECRET.
Other REC Limits:NONE RECOMMENDED
Ingred Name:EPOXY RESIN
Other REC Limits:2 PPM
Ingred Name:P,P'-DIAMINODIPHENYL SULFONE (4-AMINOPHENYL SULFONE)
Other REC Limits:0.1 PPM
Ingred Name:EPOXY RESIN
Other REC Limits:7.6 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY
TRACT. ACUTE- INHALE:VAPORS OF HEATED MATERIAL/DUST FROM GRINDING,
CUTTING/MACHINING MAY CAUSE IRRITATION OF RESPIRATORY TRACT.
EYES:IRRITATION. SKIN:IRRITATION, A LLERGINC REACTIONS.
ORAL:IRRITATION OF GI TRACT. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION OF EYES, SKIN, RESPIRATORY AND
GASTROINTESTINAL TRACTS; EYE REDNESS, SWELLING, PAIN AND TEARING;
SKIN ITCHING, REDNESS, SWELLING AND BLISTERING; COUGHING. ABDOMINAL
PAIN, VOMITING, NAUSEA, BLOOD IN VOMITOUS AND FECE
Medical Cond Aggravated by Exposure:SKIN AND LUNG DISORDERS.
* First Aid Measures *
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP & WATER. ORAL:DO
NOT IN DUCE VOMITING. IF CONSCIOUS, DRINK TWO GLASSES OF WATER. GET
MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NOT RELEVANT
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:NOT RELEVANT. SOLID FILM.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
RETURN TO ROOM TEMPERATURE BEFORE REUSE. KEEP OUT OF REACH OF
CHILDREN.
Other Precautions:AVOID BREATHING VAPOR OR DUST. DO NOT GET IN EYES, ON
SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. LAUNDER
BEFORE REUSE.
* Physical/Chemical Properties *
HCC:T6
NRC/State Lic Num:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID FILM, ODORLESS.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HIGH HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN AND SULFUR.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE UNCURED WASTE IN AN APPROVED
INCINERATOR. DISPOSE OF COMPLETELY CURED MATERIAL IN A SANITORY
LANDFILL. OBSERVE ALL LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED. USE NIOSH APPROVED
ORGANIC VAPOR RESPIRATOR IF WORKING W/O ADEQUATE VENTILATION.
Ventilation:ADEQUATE - LOCAL EXHAUST.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING TO PREVENT SKIN
CONTACT. WASH HANDS W/SOAP & WATER AFTER HANDLING.
Work Hygienic Practices:MFR:?.HMIS:USE GOOD CHEMICAL HYGIENE
PRACTICES. AVOID CONTACT IF POSSIBLE. WASH THOROUGHLY AFTER
HANDLING.
Supplemental Safety and Health
NONE
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:DIPROPYLENE GLYCOL METHYL ETHER
Other REC Limits: SPECIFIED
Fraction by Wt: <1%
Other REC Limits: RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-MAY BE IRRITATING TO SKIN &
EYES. CHRONIC- EXPECTED AT INDUSTRIAL USE LEVELS WHEN GOOD
PERSONAL HYGIENE PRACTICES ARE FOLLOWED.
Explanation of Carcinogenicity:MFR GAVE THE ABOVE LISTINGS ON THE MSDS
BUT NO OTHER COMMENTS WERE RECORDED.
Effects of Overexposure:EYE:CAN CAUSE IRRITATION, BURNING, REDNESS.
SKIN:BRIEF CONTACT SHOULD NOT PRODUCE HARMFUL EFFECTS. PROLONGED
CONTACT MAY CAUSE IRRITATION, BURNING. INHALED:IN CONCENTRATED FORM
MAY CAUSE HEADACHE, DIZ ZINESS, NAUSEA & IRRITATION OF UPPER
RESPIRATORY TRACT. INGESTED:CAN CAUSE NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION ON MSDS.
* First Aid Measures *
First Aid:IF IRRITATION PERSISTS OR IS SEVERE, GET MEDICAL ATTENTION.
CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM
EXPOSURE. AI D OR RESTORE BREATHING AS NEEDED. INGESTED:DO NOT
INDUCE VOMITING. GIVE WATER TO DRINK TO CAUSE DILAUTION IN STOMACH
AND GET IMMEDIATE MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:TCC
Flash Point: TO BOILING
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
COOL FIRE-EXPOSED CONTAINERS WITH WATER SPRAY.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS WHEN ENTERING CONFINED FIRE
SPACES.
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL. ELIMINATE ANY IGNITION SOURCES.
AVOID BREATHING VAPORS. ABSORBSMALL SPILLS W/SAND, DIRT OR CLAY.
LARGE SPILLS MAY BE PUMPED INTO CONTAINERS FOR RECOVERY OR
DISPOSAL.
Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS.
*Handling and Storage *
CONTAMINATED CLOTHING BEFORE REUSE. STORE DRUMS IN A COOL PLACE,
BUNG UP & CLOSED TIGHTLY.
Other Precautions:HAVE EYE WASH STATION, SAFETY SHOWER & WASHING
FACILITIES AVAILABLE.
* Physical/Chemical Properties *
HCC:N1
NRC/State Lic Num:
Spec Gravity:1.0
pH:9.0
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, AMBER LIQUID WITH MILD ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS
Stability Condition to Avoid:EXTREME HEAT
Hazardous Decomposition Products:BURNING WILL PRODUCE OXIDES OF CARBON
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:FIRST CONSULT FEDERAL, STATE & LOCAL
REGULATIONS. CONTAMINATED ABSORBENT MAY BE DEPOSITED IN A LANDILL
OR WASTE MAY BE INCINTERATED. EPA HAZARDOUS WASTE CODE:
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NUISANCE DUST MASK RECOMMENDED WHILE GRINDING
FIRED CERAMIC.
Ventilation:MECHANICAL EXHAUST: RECOMMENDED WHILE GRINDING FIRED
CERAMIC.
Other Protective Equipment:NOT REQUIRED
Work Hygienic Practices:AVOID LICKING CERAMIC APPLICATION BRUSH.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
ACGIH TLV:5 MG/CUM
Ingred Name:CHROMIUM, CHROMIUM METAL, CHROME (CARCINOGEN BY NTP; IARC
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
OSHA PEL:0.1 MG/CUM
Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC
OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT
ACGIH TLV:5 MG/CUM (FE)
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM (DUST)
Ingred Name:NICKEL (SUSPECTED ANIMAL/HUMAN CARCINOGEN BY IARC GROUP 2B,
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
OSHA PEL:2 MG/CUM
ACGIH TLV:2.0 MG/CUM
Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
OSHA PEL:0.5 MG/CUM
Ingred Name:ZIRCONIUM
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE
OSHA PEL:0.5 MG/CUM
ACGIH TLV:0.5 MG/CUM
Ingred Name:BORON OXIDE, TRIOXIDE
Ingred Name:CALCIUM OXIDE; LIME
OSHA PEL:5 MG/CUM
ACGIH TLV:2 MG/CUM
Ingred Name:MAGNESIUM OXIDE, MAGNESIA
Ingred Name:POTASSIUM DIOXIDE
Ingred Name:SODIUM OXIDE
OSHA PEL:2 MG/CUM
ACGIH TLV:2.0 MG/CUM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Explanation of Carcinogenicity:SEE INGREDIENTS.
* First Aid Measures *
First Aid:INHALATION: AVOID BREATHING CERAMIC DUST. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP AS SOLID WASTE. AVOID BREATHING DUST.
*Handling and Storage *
Handling and Storage Precautions:AVOID BREATHING CERAMIC DUST.
Other Precautions:NONE
* Physical/Chemical Properties *
Evaporation Rate & Reference:NONE
Solubility in Water:INSOLUBLE
Appearance and Odor:PASTEL COLOR PORCELAINS W/NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONCENTRATED HYDROFLUORIC ACID
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF SOLID WASTE IN ACCORDANCE W/LOCAL,
STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHAL:IRRIT OF RESP TRACT. PRLNG INHAL MAY LEAD TO FATG,
DROW, DIZZ &/OR LT HEAD, HDCH, LACK OF COORD, NAUS, VOMIT, CNS DEPRESS,
ANESTH EFT/NARCOS. SKIN CONT:IRRIT. PRLNG/RPTD CONT CAN CAUSE DERM, DEF AT.
EYE CONT:IRRIT. PRLNG/RPTD CONT CANCAUSE BLURRED VISION, REDNESS, TEARING,
SEV IRRIT. INGEST:AMTS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLT HAZ:INGESTED INCIDENTAL TO CONSUMER
& INDUS HNDLG ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, INGEST OF LGR AMTS
MAY CAUSE LUNG INFLAMM & DMG DUE TO ASPIR OF MATL INTO LUNGS. NOTICE:RPTS
HAVE ASSOC R PTD & PRLNG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV
SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHALING (SUPP DATA)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET EMERGENCY MED ATTN. SKIN:WASH OFF
QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER; REMOVE CONTAM CLTHG. WASH
CONTAM CLTHG BEFORE REUSE. EYE:FLUSH IMMED W/LG AMTS OF WATER, ESP UNDER
TREATMENT IMMED.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION (FLAME, HOT SURFACES
& ELECTRICAL, STATIC SPARKS). VENTILATE AREA & AVOID BREATHING
VAPORS. CONTAIN & REMOVE W/INERT ABSORBENT MATERIAL USING NON-SPARKING
TOOLS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.
IN BLDGS DESIGNED FOR STOR OF FLAMM/COMBUST LIQS. DO NOT TAKE INTERNALLY.
KEEP OUT OF REACH OF CHILDREN.
Other Precautions: DO NOT WELD/FLAME CUT W/OUT PROPER VENT TO INSURE AREA IS
FREE OF FLAMM VAPS. DO NOT CUT, PUNCTURE/WELD ON/NEAR CNTNR. ENTRANCE INTO
CLSD STOR TANKS - USE APPROP NIOSH/MSHA APPRVD RESP/AIRLINE FOR POS S EXPOS
TO SOLV/CHEM FUMES. RAGS(SUPDAT)
*
Fire and Explosion Hazard Information
*
Flash Point Method: SCC
Lower Limits: SEE INGS
Extinguishing Media: DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT/FIRE. VAPS CAN FORM EXPLO MIXTS IN AIR AT ELEVATED TEMPS. MAY DECOMPOSE
UNDER FIRE CNDTNS EMITTING (SUPDAT)
*
*
Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTER RESPIRATOR DESIGNED
Ventilation: ALL APPLICATION AREAS SHOULD BE VENTILATED I/A/W OSHA REGULATION
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: MFR'S TRADE NAME/PART NO:WOOD FINISH-SATIN.
NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR" VERSION FOR ADDNL INFO (FP N).
EXPLO HAZ:IRRIT &/OR TOX GASES. EFTS OF OVEREXP:CONTENTS MAY BE
HARMFUL/FATAL. OTHER PREC:OR WASTE CNTNG OIL BASED PAINT/VARNISH THAT
PRESENT LG AIR-TO-OIL INTERFACE WILL OXIDIZE & MAY IGNITE
*
Physical/Chemical Properties
*
Vapor Pres: SEE INGS
Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES. CONTACT W/OXIDIZING
AGENTS.
Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: M A BRUDER & SONS INC
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE:INHAL:IRRIT OF RESP TRACT. PRLNG INHAL
MAY LEAD TO FATG, DROW, DIZZ &/OR LT HEAD, HDCH, LACK OF COORD, NAUS,
VOMIT, CNS DEPRESS, ANESTH EFT/NARCOS. SKIN CONT:IRRIT. PRLNG/RPTD CONT CA N
CAUSE DERM, DEFAT. EYE CONT:IRRIT. PRLNG/RPTD CONT CAN CAUSE BLURRED VISION,
REDNESS, TEARING, SEV IRRIT. INGEST:INGESTION OF LARGER AMOUNTS MAY CAUSE
LUNG INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS.
CHRONIC:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRA TING & INHALING CONTENTS MAY
BE HARMFUL/FATAL.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED SUPPLIED-AIR RESPIRATORY
PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:USE ONLY W/ADEQ VENT (MECH/GEN) USE EXPLO-PROOF EQUIP.
AVOID POTENTIAL IGNITION SOURCES.
Other Protective Equipment:USE CHEMICAL-RESISTANT APRON OR OTHER
CLOTHING, IF NEEDED TO AVOID REPEATED OR PROLONGED SKIN CONTACT.
Work Hygienic Practices:REMOVE CONTAMD CLTHG; LAUNDER BEFORE REUSE.
REMOVE CONTAMD SHOES & THORO DRY BEFORE REUSE. WASH SKIN W/SOAP
(ING 7)
Supplemental Safety and Health
EXTING MEDIA:FOAM IS PREFERRED FOR LG FIRES. FIRE FIGHT PROC: POSS
AUTO-IGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED,
FOG NOZ ARE PREF. EXPLO HAZ: HCL & PHOSGENE . EFTS OF OVEREXP: MAY
BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS
ACUTELY OR CHRONICALLY EXOSED TO CHLOROCARBONS .
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (AROMATIC
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ETHANE,1,1,1-TRICHLORO-; (1,1,1-TRICHLOROETHANE). VP:
Ozone Depleting Chemical:1
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FIRST AID PROC: WILL CAUSE DEFATTING AND DERMATITIS.
Ingred Name:SPILL PROC: WATERCOURSES. THIS PROD IS SUBJECT TO
Ingred Name:WASTE DISP METH: HAZ WASTE LANDFILL. DISPOSE ONLY IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
Ingred Name:HYGIENE PRACT: & WATER AFTER CONTACT, BEFORE BREAKS AND
MEALS & AT END OF WORK PERIOD.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST: CAN CAUSE GI IRRIT,
NAUS, & VOMIT. ASPIR OF MATL INTO LUNG MAY CAUSE MILD TO SEV PULM
PNEUM & POSS DEATH. INHAL: MAY CAUSE IRRIT OF NOSE & THROAT, &
ACUTE NERV SYS DEPRESS. CHARACT BY H DCH, DIZZ, CONFUSN, NAUS, &
UNCON. EYE:MAY CAUSE IRRIT. SKIN: PRIMARY IRRITANT. CHRONIC: RPTS
HAVE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: ASSOC PRLNGD & RPTD OCCUP OVEREXP TO
SOLV W/PERM BRAIN & NERV SYS DAM. INTENTIONAL MISUSE BY DELIB CONC
& INHALING CONTENTS MAY BE HARMFUL/FATAL. CHLOROCARBON MATLS HAVE
PRDCD SENSIT OF MYOC ARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE)
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST: DO NOT INDUCE VOMIT. CALL POIS CTL CTR, HOSP EMER
ROOM/PHYS IMMED. INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG HAS
STOPPED GIVE ARTF RESP. KEEP WARM & QUIET. GET MED ATTN. EYE: FLUSH
GET MED ATTN. SKIN: REMOVE CONTAMD CLTHG. WASH AFFECTED AREA W/SOAP
& WATER. OBTAIN MED ATTN IF IRRIT PERSISTS. PRLNGD/RPTD SKIN CONT
(ING 4)
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:USE CLASS B FIRE EXTING (CARBON DIOXIDE/ALL PURPOSE
DRY CHEM/ALCOHOL FOAM) DESIGNED TO EXTING FLAMM LIQ.
POLYMER(SUPDAT)
Fire Fighting Procedures:NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP. WATER MAY BE INEFTIVE, BUT MAY BE USED TO COOL EXPOSED
CONTRS TO PVNT PRESS BUILD-UP & (SUPP DATA)
Unusual Fire/Explosion Hazard:DURING EMER CNDTNS, OVEREXP TO DECOMP
PRODS MAY CAUSE A HLTH HAZ. SYMP MAY NOT BE IMMED APPARENT. OBTAIN
MED ATTN. THERMAL DECOMP PROD MAY INCL (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL POSS IGNIT SOURCES. AVOID BRTHG
VAPS. KEEP PEOPLE AWAY. RECOVER FREE LIQ. ADD ABSORB (SAND, EARTH,
SAWDUST, OR VERMICULITE) TO SPILL AREA. VENT CONFINED SPACES, OPEN
ALL WINDOWS & DOORS, KE EP PETROLEUM PROD OUT OF SEWERS & (ING 5)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTRS CLSD WHEN NOT IN USE. DO
NOT HANDLE/STORE NEAR HEAT, SPARKS, FLAME/STRONG OXIDANT. MINIMIZE
BRTHG VAPS. AVOID PRLNGD/RPTD CONT W/SKIN.
Other Precautions:ADEQ VENT REQD. (MEANS SUFFICIENT TO PVNT BUILD UP OF
TOX/EXPLOS CONC OF VAPS IN AIR. NO SMOKING IN AREA OF USE. DO NOT
USE IN GEN VICIN OF ARC WELD, OPEN FLAMES/HOT SURF. HEAT &/OR UV
RADIA MAY CAUSE FORM OF HCL &/OR PHOSGENE .
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANT SUCH AS LIQUID CLORINE, CONCENTRATED OXYGEN, SODIUM-OR
CALCIUM HYPOCHLORIDE. HYPOCHLORITE.
Stability Condition to Avoid:HEAT, SPARKS, AND FLAMES.
Hazardous Decomposition Products:FUMES, SMOKE AND CARBON MONOXIDE. HCL
AND PHOSGENE .
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W FED, ST & LOC REG. CONTAMD ABSORB
MAY BE DISPOSED IN EPA PERMITTED HAZ WASTE LANDFILLS. INCIN ONLY IN
EPA PERMITTED FACILITY. DO NOT INCIN CLSD CONTR. OBSERVE PREC FOR
DISP OF COMBUST MA TL. CONTAMD ABSORB MAY BE DISPOSED IN A(ING 6)
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
ACGIH TLV: 5 (FUME) (MFR)
------------------------------
ACGIH TLV: 5 MG/M3 FUME, B2
------------------------------
% Wt: <1
ACGIH TLV: 2 MG/M3 TDUST
-----------------------------
OSHA PEL: 3.5 MG/M3
ACGIH TLV: 3.5 MG/M3
------------------------------
OSHA PEL: C 5 MG/M3 DUST
ACGIH TLV: 5 MG/M3 DUST
------------------------------
% Wt: 1.6
------------------------------
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 1.0
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: EYES: CAN CAUSE IRRITATION. SKIN: CAN CAUSE
IRRITATION. INHALATION: CAN IRRITATE THROAT AND MILDLY IRRITATE MUCOUS
MEMBRANES; MAY EXPERIENCE METALLIC TASTE IN MOUTH. INGESTION: NOT AVAILABLE.
A CUTE OVEREXPOSURE: CAN CAUSE METAL FUMEFEVER. CHRONIC OVEREXPOSURE: CAN
CAUSE PULMONARY EFFECTS, (EFTS OF OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZ: SIDEROSIS, BRONCHITIS, LACK OF
COORDINATION, OR BENIGN PNEUMOCONIOSIS OF THE LUNGS(STANNOSIS).
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: FLUSH THOROUGHLY WITH RUNNING WATER TO REMOVE PARTICULATE FOR
WASHING THOROUGHLY WITH SOAP AND WATER. SEEK MEDICAL ATTENT ION IF CONDITIONS
PERSISTS. INHALATION:REMOVE TO FRESH AIR; IF CONDITION CONTINUES, CONSULT A
PHYSICIAN. INGESTION: IF SIGNIFICANT AMOUNTS OF METAL ARE INGESTED, CONSULT
PHYSICIAN.
*
Handling and Disposal
*
Spill Release Procedures: SMALL/LARGE SPILL: FINE TURNINGS SHOULD BE SWEPT OR
VACUUMED. SCRAP METAL CAN BE RECLAIMED FOR RE-USE.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: USED OR UNUSED PRODUCT SHOULD BE DISPOSED OF IN
ACCORDANCE WITH FEDERAL, STATE OR LOCAL LAWS AND REGULATIONS. DISPOSER MUST
COMPLY WITH FEDERAL, STATE AND LOCAL DISPOSAL OR DISCHARGE LAWS.
Handling And Storage Precautions: KEEP CONTAINER CLOSED. IN WELDING, PRECAUTION
SHOULD BE TAKEN FOR AIRBORNE CONTAMINANTS WHICH MAY ORIGINATE FROM COMPONENTS
OF THE WELDING ROD.
Other Precautions: ARC OR GENERATED SPARK WHEN WELDING OR BURNING COULD BE A
SOURCE OF IGNITION FOR COMBUSTION AND FLAMMABLE MATERIALS. AVOID GENERATION
OF AIRBORNE FUME AND DUST.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NONE
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: DO NOT USE WATER ON MOLTEN METAL. MEDIA SUITABLE FOR
SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: STEEL WIRE DOES NOT PRESENT FIRE/EXPLO HAZ UNDER
NORM CNDTNS. FINE METAL PARTICLES SUCH AS PRDCED WHEN SAWING/GRINDING CAN
BURN. HIGH CONCS OF METALLIC (SUPDAT)
*
*
Respiratory Protection: APPROPRIATE DUST/FUME/MIST RESPIRATOR SHOULD BE USED TO
AVOID EXCESS INHALATION OF PARTICULATES. IF EXPOSURE LIMITS ARE REACHED OR
EXCEEDED, USE NIOSH APPROVED EQUIPMENT.
Ventilation: AS REQUIRED DEPENDING ON OPERATIONS AND SAFETY CODES.
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). AS
REQUIRED DEPENDING ON OPERATIONS AND SAFETY CODES.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: MFR TRADE NAME/PART NO: OXYGEN,OR SULFUR IN
STEEL (CALIBRATION SAMPLE). EXPLO HAZ: FINES IN AIR MAY PRESENT EXPLO HAZARD.
MATLS TO AVOID: OF IRON & ALLOYING ELEMENTS.
*
Physical/Chemical Properties
*
Spec Gravity: 7
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NOT KNOWN
Appearance and Odor: GREY OR BLACK METAL. NO ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: REACTS W/STRONG ACIDS TO FORM HYDROGEN GAS. STEEL AT TEMPS
ABOVE MELTING POINT MAY LIBERATE FUME CNTNG OXIDES (SUPDAT)
Hazardous Decomposition Products: METALLIC DUST OR FUMES DURING WELDING,
BURNING, GRINDING AND POSSIBLY MACHINING.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: LECO CORPORATION
Label Required IND: Y
Status Code: C
Origination
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYES: CAN CAUSE IRRITATION. SKIN: CAN CAUSE
IRRITATION. INHALATION: CAN IRRITATE THROAT AND MILDLY IRRITATE MUCOUS
MEMBRANES; MAY EXPERIENCE METALLIC TASTE IN MOUTH. INGESTION: NOT AVAILABLE.
A CUTE OVEREXPOSURE: CAN CAUSE METAL FUMEFEVER. CHRONIC OVEREXPOSURE: CANCER
HAZARD. CONTAINS CARBON BLACK WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN
(FP N). CAN CAUSE PULMONARY EFFECTS, SIDEROSIS, BR ONCHITIS, LACK OF
COORDINATION, OR BENIGN PNEUMOCONIOSIS OF LUNGS(STANNOSIS)
*
| 1 | eyes_protection_mandatory |
Control Measures
*
Cage: 0AVE3
Proprietary Ind: Y
*
Contractor Summary
*
Cage: 0AVE3
*
Item Description Information
*
Item Name: INK,RECORDING INSTRUMENT
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: NON-IRRITANT. INGEST:PRACTICALLY NON-TOXIC.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP)
WATER. INGEST:IN CASE OF INGESTION OF A LARGE QUANTITY, SEEK ME DICAL
ATTENTION.
*
Handling and Disposal
*
Spill Release Procedures: WIPE SPILL & RINSE W/WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS (FP N). NO UNUSUAL DISPOSAL PROCEDURES.
Handling And Storage Precautions: NONE.
Other Precautions: NONE.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NOT FLAMMABLE
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
*
*
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N). NOT NORMALLY NECESSARY.
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
*
Physical/Chemical Properties
*
Spec Gravity: 1
Solubility in Water: SOLUBLE
Appearance and Odor: BLACK, BLUE, RED OR YELLOW LIQUID; NO ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Cage: 0AVE3
Company Name: TEKTRONIX INC
Street: UNKOWN
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: NONE
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE/CHRONIC:NONE LISTED BY MANUFACTURER.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
THIS ENTRY FOR WORKING SOLUTION.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM CARBONATE
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred
Name:4-(N-ETHYL-N-2-METHANESULFONYLAMINOETHYL)-2-METHYLPHENYLENEDIA
MINE
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:(NITRILOTRIS(METHYLENE)TRIPHOSPHONIC ACID, K SALT
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM SULFITE
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPECTED TO BE A LOW INHALATION HAZARD
FOR RECOMMENDED HANDLING. MAY CAUSE TRANSIENT EYE IRRITATION. SKIN
CONTACT MAY CAUSE ALLERGIC REACTION. EXPECTED TO BE A LOW INGESTION
HAZARD. MAY CAUSE IRRITATI ON OF THE GASTROINTESTINAL SYSTEM
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, ALLERGIC SKIN REACTION, GI
TRACT IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR
SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS
OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE TO REMOVE RESIDUA L CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. USE WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED.
Other Precautions:THE ROUTINE USE OF A NONALKALINE (ACID) TYPE OF HAND
CLEANER AND REGULAR CLEANING OF WORKING SURFACES WILL HELP MINIMIZE
THE POSSIBILITY OF A SKIN REACTION.
* Physical/Chemical Properties *
HCC:B3
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Density:0.6
Viscosity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID, NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY
REASONABLY COME INTO CONTACT.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH
FEDERAL, STATE ANDLOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE A HALF MASK RESPIRATOR W/ORGANIC VAPOR
CARTRIDGE APPROVED BY NIOSH/MSHA. IF EXPOSURE EXCEEDS TLV, USE A
NIOSH APPROVED RESPIRATOR. DURING/AFTER APPLICATION, WEAR AN
APPROPRIATE PROPERLY FITTED RES PIRATOR(NIOSH/MSHA APPROVED).
Ventilation:REQUIRED
SHOWERS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY BEFORE EATING & USING WASHROOM.
Supplemental Safety and Health
FIRE HZRD: COOL CONTAINERS W/WATER. SPILLS: CONTACT FIRE AUTHORITIES.
DON'T FLUSH TO SEWER, WATERSHED/WATERWAY. PREC: CONTAINERS MAY BE
HAZARDOUS WHEN EMPTIED, SINCE EMPTIED CONTAINERS RETAIN RESIDUES
ALL PRECAUTIONS MUST BE OBSERVED. DON'T FLAME CUT/WELD EMPTY DRUMS.
* Product Identification *
Preparer's Name:JIM SCHMIDT
CAGE:0ULT0
CAGE:0ULT0
* Composition/Information on Ingredients *
Ingred Name:HEXONE, METHYL ISOBUTYL KETONE (MIBK), 4-METHYL-2-PENTANONE
Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/CUM
ACGIH TLV:3.5 MG/CUM
Ingred Name:2,4-PENTANEDIONE, ACETYLACETONE
Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM
OSHA PEL:2 MG/CUM (RESP DUST)
ACGIH TLV:2 MG/CUM (RESP DUST)
Ingred Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN
ACGIH TLV:0.1 MG/CUM RESP DUST
Ingred Name:CATALYST AMORPHOUS SILICA, DI-ME SILOXANES & SILICONES
Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE,
1-METHOXY-2-PROPANOL ACETATE
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CARBON BLACK-INGESTION: HARMFUL.
REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT
BRAIN & NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:CARBON BLACK-INGESTION: HARMFUL.
* First Aid Measures *
W/COPIOUS AMOUNTS OF LUKE WARM WATER. INHALATION: REMOVE TO FRESH
AIR. RESTORE BREATHING IF REQUIRED. INGESTION: RINSE MOUTH
IMMEDIATELY. G IVE PERSON 6-8 OUNCES OF LIQUID. NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON. DON'T INDUCE VOMITING. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Lower Limits:1
Extinguishing Media:CO2, DRY CHEMICALS/ALCOHOL FOAM.
Fire Fighting Procedures:EVACUATE AREA. DON'T ENTER CONFINED SPACE W/O
PROTECTIVE EQUIPMENT & POSITIVE PRESSURE NIOSH APPROVED SCBA. FIGHT
FIRE FROM A SAFE DISTANCE/LOCATION. (SEE SUPP)
Unusual Fire/Explosion Hazard:THIS LIQUID IS A FIRE & EXPLOSIN HAZARD.
VAPORS MAY BE > THAN AIR & MAY TRAVEL ALONG THE GROUND TO DISTANT
IGNITION SOURCE & FLASH BACK.
* Accidental Release Measures *
Spill Release Procedures:STAY UPWIND & AWAY. WEAR APPROPRIATE
PROTECTIVE EQUIPMENT. STOP &/CONTAIN DISCHARGE SAFELY. KEEP SOURCES
OF IGNITION AWAY. VENTILATE AREA. USE NON-SPARKING TOOLS FOR
CLEANUP. COVER W/INERT MATERIAL. K EEP OUT OF DRAINS,
SEWERS/WATERWAYS. (SEE SUPP)
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS COOL, DRY & AWAY FORM
SOURCES OF IGNITION. USE & STORE W/ADEQUATE VENTILATION. DON'T
SMOKE IN STORAGE AREAS.
Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
ISOLATE FROM IGNITION SOURCES. SPRINKLER IS DESIRABLE IN STORAGE &
HANDLING USE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING THE CONTENT S MAY BE HARMFUL/FATAL. (SEE SUPP)
* Physical/Chemical Properties *
Vapor Density:>1
VOC Grams/Liter:2.7
Evaporation Rate & Reference:FASTER THAN BU AC
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY LIQUID W/MODERATE KETONE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:SPARKS, OPEN FLAME, HOT SURFACES, SOURCES
OF IGNITION.
Hazardous Decomposition Products:THERMAL: OXIDES OF CARBON & VARIOUS
HDYROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
GASOLINE,FIREFIGHTING OR UNKNOWN CONCEN SCBA W/POS PRESSURE.
Ventilation:MAINTAIN LOC/DILUTION VENTI TO KEEP AIR CONCEN <1PPM
Other Protective Equipment:NONE SPECIFIED BY MFG.
Work Hygienic Practices:WASH HANDS AFT HANDLING. LAUNDER CONTAMIN
CLOTHING BEFORE WEARING.
Supplemental Safety and Health
REQUEST ASSISTANCE OF SAFETY & INDUSTRIAL HYGIENE PERSONNEL IN
DETERMINING AIR CONCEN FOR PROPER VENTILATION.
* Product Identification *
Product ID:UNLEADED GASOLINE
Preparer's Name:KEITH W. BUNSELMEYER
* Composition/Information on Ingredients *
Ingred Name:GASOLINE (CAS# MIXTURE).
Other REC Limits:NONE RECOMMENDED
Ingred Name:METHYL TERT-BUTYL ETHER (SARA III) (MTBE)
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:BENZENE (SARA III)
Fraction by Wt: 0-3%
Other REC Limits:NONE RECOMMENDED
Ingred Name:TOLUENE (SARA III)
Other REC Limits:NONE RECOMMENDED
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Other REC Limits:NONE RECOMMENDED
Ingred Name:ETHYL BENZENE (SARA III)
Fraction by Wt: 0-2%
Other REC Limits:NONE RECOMMENDED
Ingred Name:CUMENE (SARA III)
Fraction by Wt: 0-1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:CYCLOHEXANE (SARA III)
Fraction by Wt: 0-1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III)
Fraction by Wt: 0-3%
Other REC Limits:NONE RECOMMENDED
Ingred Name:NAPHTHALENE (SARA III)
Fraction by Wt: 0-1%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:INHAL:HEAD,NASAL/RESP
IRRIT,NAU,DROW,BREATHLESSNESS,GATIGUE,CNS DEPRESS,CONVULSIONS,LOSS
OF CONSC.SKIN/EYES:IRRIT.INGEST:ASPIRATION
HAZ.HEAD,NAU,DROW,FATIGUE,PNEUITIS,PULM EDEMA,CNS DEPRESS,CONV
ULSIONS,LOSS OF CONSC.CHRONIC:CNS/KIDNEY/LIVER/BLOOD
DISORDERS,ANEMIA,LEUKEMIA,DERM,CANCER IN LAB ANIMALS.
Explanation of Carcinogenicity:CONTAINS BENZENE & GASOLINE. PER MSDS
LISTED AS POTENTIAL CARCIN OR CARCIN BY OSHA.
Effects of Overexposure:HEADACHE, NAUSEA, DROW, BREATHLESSNESS,
FATIGUE, CNS DEPRESS, CONVULSIONS, LOSS OF CONSC. DERMITITIS.
Medical Cond Aggravated by Exposure:KIDNEY, LIVER, BLOOD DISORDERS.
* First Aid Measures *
First Aid:INHAL:MOVE TO FRESH AIR. IF BREATHING HAS STOPPED, PERFOMR
ARTIFICIAL RESP. GET MED ATTN ASAP. SKIN:IMMED REMOVE CONTAMIN
CLOTH. WASH AREA W/SOAP & WATER. GET MED ATTN IMMED. EYES:IMMED
INGEST:CALL DR IMMED. ONLY INDUCE VOMIT @ INSTRUCTION OF DR. NEVER
GIVE ANTHING BY MOUTH TO UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:CARBON DIOXIDE,DRY CHEM, FOAM.WATERSTREAM MAY
SPREAD FIRE,USE WATERSPRAY ONLY TO COOL CNTNRS EXPOSED TO FIRE.
Fire Fighting Procedures:USE WATERSPRAY TO DISPERSE VAP IN
SPILL.EXPLOSION HAZ IN FIRE SITUATION.
Unusual Fire/Explosion Hazard:INCOMPLETE COMBUST CAN YEILD CO & VAR
HYDROCARBONS.CAN FORM FLAMM MIXTURE W/AIR & FLASH @ RM TEMP.VAP
HEAVEIR THAN AIR & CAN TRAVEL TO IGN SOURCE & FLASHBACK.
* Accidental Release Measures *
Spill Release Procedures:NOTIFY EMERGENCY RESPONSE PERSONNEL. EVACUATE
AREA. REMOVE IGN SOURCES. BUILD DIKE TO CONTAIN FLOW. REMOVE FREE
LIQ. DO NOT FLUSH TO SEWER OR OPEN WATER. PICK UP W/INERT
ABSORBENT. PLACE IN CLOSED CON TAINER FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MFG.
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE WITH STRONG OXIDIZERS.
STORE AS OSHA CLASS 1B FLAMM LIQ.
Other Precautions:NONE SPECIFIED BY MFG.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:3-4
Evaporation Rate & Reference:2X SLOWER,ETHYLETHER=1.
Solubility in Water:NEGLIGIBLE.
Appearance and Odor:CLEAR TO RED LIQUID, GASOLINE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:HEAT AND FLAMES AND SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, VARIOUS HYDROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:UTILIZE LICENSED WASTE DISPOSAL COMPANY.
CONSIDER RECYCLING OR INCINERATION. UTILIZE PERMITTED HAZARDOUS
WSTE DISPOSAL SITE OR INDUSTRIAL WSTE DISPOSAL SITE AS APPROPRIATE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED ACID GAS/MIST RESP IF EXPOSURE
EXCEEDS >TLV.
Ventilation:USE IN LABORATORY FUME HOOD OR EQUIVALENT
Other Protective Equipment:ARM SLEEVES AND APRON
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SULFURIC ACID (SARA III)
OSHA PEL:1 MG/M3
Ingred Name:P-DIMETHYLAMINOBENZALDEHYDE
* Hazards Identification *
Effects of Overexposure:EYE/NOSE/THROAT IRRITATION/PULMONARY
EDEMA/BRONCHITIS/PRO CONJUNCTIVITIS/STOMATITIS/DENTAL EROSION
* First Aid Measures *
First Aid:INHALATION: MOVE TO FRESH AIR. SKIN CONTACT: FLUSH WITH WATER
REMOVE CONTAMINATED CLOTHING. EYE CONTACT: IMMEDIATELY FLUSH WITH
PHYSICI AN.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:CO2, FOAM, DRY CHEMICAL
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH VERMICULITE.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM ALKALI AND ORGANIC
MATERIAL.
Other Precautions:NONE
* Physical/Chemical Properties *
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARTENT YELLOW LIQUID
Percent Volatiles by Volume:0%
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALKALI, ORGANIC MATERIAL
Stability Condition to Avoid:HIGH HEAT, ALKALI, ORGANIC MATERIAL
Hazardous Decomposition Products:SOX, NOX
* Disposal Considerations *
Waste Disposal Methods:FEDERAL, LOCAL, STATE REGULATION.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE FUME/ORGANIC VAPOR RESPIRATOR OR AIR
SUPPLIED RESPIRATOR WHEN SOLDERING IN A CONFINED SPACE OR WHERE
LOCAL EXHAUST OR GENERAL VENTILATION DOES NOT KEEP EXPOSURE BELOW
RECOMMENDED LIMITS. USE ONLY NIOSH APPROVED RESPIRATORS.
Ventilation:USE ENOUGH VENTILATION WHEN SOLDERING TO KEEP THE DUST,
FUMES & GASES BELOW TLV.
WHEN SOLDERING.
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING OR SMOKING.
LAUNDER CONTAMINATIED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:ACTIVATED ROSIN CORE SOLDER
* Composition/Information on Ingredients *
Ingred Name:LEAD (SARA III)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TIN
Other REC Limits:NONE SPECIFIED
OSHA PEL:2 MG/M3
Ingred Name:ROSIN ACID
Fraction by Wt: 3.3%
Other REC Limits:1 PPM FORMALDEHYDE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-INHALATION OF FUMES(DURING
SOLDERING):IRRITATION OF EYES AND RESPIRATORY TRACT SYSTEM.
CHRONIC:LONG AND REPEATED EXPOSURE TO METAL FUMES MAY CAUSE
HEADACHE, NAUSEA/VOMITING, ACHING BONES, FATIGU E, DECREASED
APPETITE, ABDOMINAL CRAMPING, ANEMIA, BRAIN, HEART, LUNG, LIVER AND
KIDNEY DEGENERATIVE CHANGES.
Explanation of Carcinogenicity:FORMALDEHYDE IS LISTED AS A PROBABLE
CARCINOGEN BY NTP,IARC, EPA,& IT IS REGULATED BY OSHA.
Effects of Overexposure:EXPOSURE TO FUMES MAY RESULT IN IRRITATION OF
NOSE, THROAT, EYES AND SKIN. BURNS FROM SKIN CONTACT OF MOLTEN
SOLDER. WATERY EYES, HEADACHE, BREATHING DIFFICULTY, FREQUENT
COUGHING.
Medical Cond Aggravated by Exposure:SOME WORKERS WITH PRE-EXISTING
CONDITIONS OF LUNGS, EYES, SKIN, AND THOSE PREVIOUSLY EXPOSED TO
LEAD & ANTMONY MAY BE AT INCREASED RISK.
* First Aid Measures *
First Aid:SKIN BURNS:FLUSH WITH COLD WATER OR APPLY ICE. IN CASE OF
SEVERE BURNS GET MEDICAL HELP. EYE IRRITATION:FLUSH WITH WATER FOR
BREATHING IS DIFFICULT. IF NOT BREATHING, BEGIN ARTIFICIAL
RESPIRATION. GET MEDICAL HELP. INGESTION:GET MEDICAL HELP.
* Fire Fighting Measures *
Extinguishing Media:NON-FLAMMABLE
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS, SUCH AS OXIDES OF
TIN & LEAD, AND FORMALDEHYDE ON PYROLSIS.
* Accidental Release Measures *
Spill Release Procedures:CLEAN UP ANY DUST OR WASTE RESIDUES AND PLACE
IN SUITABLE DOT APPROVED CONTAINERS AND DISPOSE OF IN FULL
COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. AVOID
INHALATION AND SKIN EXPOSURE.
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:NO SPECIAL REQUIREMENTS FOR STORAGE.
Other Precautions:NONE
* Physical/Chemical Properties *
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID,SILVER TO GREY METALLIC WITH YELLOW CORE.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,ACTIVE METALS: SODIUM & POTASSIUM, CHLORINE &
TERPENTINE.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:TOXIC METAL FUMES ABOVE MELTING POINT.
FROM THE ROSIN CORE; FORMALDEHYDE, CARBON MONOXIDE & DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF ACCORDING TO FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
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