text
stringlengths 307
13.1k
| label
int64 0
1
| label_text
stringclasses 2
values |
|---|---|---|
* Exposure Controls/Personal Protection *
Supplemental Safety and Health
* Product Identification *
Product ID:MEDALLION
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:MINERAL SPIRITS (HEAVY NAPHTHA) * (NIOSH RECOMMENDATION
Other REC Limits:*
Ingred Name:DIETHYLENEGLYCOL MONOBUTYLETHER
Other REC Limits:NONE RECOMMENDED
Ingred Name:MINERAL SEAL OIL
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 (AS MIST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EYE: IRRITATION, LOSS OF NATURAL
LUBRICATION. SKIN: PROLONGED CONTACT MAY DEFAT SKIN, LEADING TO
IRRITATION & DERMATITIS. IF SWALLOWED: HARMFUL/FATAL IF SWALLOWED.
IF INHALED: DIZZINESS, HEADACHE, RES PIRATORY IRRITATION. UNDER
RECOMMENDED USE CONDITIONS, VAPOR LEVEL WILL BE TOO LOW TO PRESENT
INHALATION HAZARD.
* First Aid Measures *
First Aid:EYES: FLUSH IMMED W/PLENTY OF COOL RUNNING WATER. REMOVE
RUNNING WATER. WASH THOROUGHLY WITH SOAP & WATER. INGEST: RINSE
MOUTH. DON'T INDUCE VOMITING. IN CASE OF NAUSEA OR SPONTANEOUS
VOMITING, KEEP VICTIM'S HEAD BELOW HIPS. NOTHING BY MOUTH TO
UNCONSCIOUS PERSON. INHAL MOVE TO FRESH AIR. IF BREATH DIFFICULT,
GIVE OXYGEN.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:USE FOG, FOAM OR FINE WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. MAXIMIZE
VENTILATION. DIKE OR DAM LARGE SPILLS. RECOVER IF POSSIBLE. ADD
ABSORBENT MATERIAL TO SOAK UP LIQUID. RINSE SPILL AREA THOROUGHLY
WITH WATER.
*Handling and Storage *
Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
Vapor Density:> AIR
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, YELLOW LIQUID; SOLVENT-LIGHT LEMON ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
DO NOT STORE NEAR STRONG OXIDIZERS SUCH AS CHLORINE OR OXYGEN.
Stability Condition to Avoid:KEEP AWAY FROM OPEN FLAME OR OTHER
IGNITION SOURCES.
* Disposal Considerations *
Waste Disposal Methods:CONSULT STATE AND LOCAL AUTHORITIES FOR
RESTRICTIONS ON DISPOSAL OF CHEMICAL WASTE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:GOOD VENTILATION;HOWEVER,USE NIOSH APPRVD RESP
IF NEEDED FOR PAINTS.
Ventilation:USE ADEQUATE VENTILATION W/EXHAUST FAN
Other Protective Equipment:USE CARTRIDGE TYPE RESPIRATOR W/PARTICULATE
FILTERS.
Supplemental Safety and Health
BASE ALSO CONTAINS DESPERSING AGENT 1%, ANTI-MAR AGENT <0.5% & NON-AQ
BASE/CATLST; THIS IS BASE; SEE P/N IND "B" FOR CATALYST;SPEC
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)
Ingred Name:N-BUTYL ACETATE (SARA III)
Ingred Name:DIBUTYL TIN DILAURATE (AS TIN)
OSHA PEL:S, 0.1 MG/M3
Ingred Name:CHLOROBENZENE (SARA III)
Fraction by Wt: 5.0%
* Hazards Identification *
Effects of Overexposure:EYES:MODERATE IRRIT;SKIN:POSSIBLE IRRIT BY
SOLVENTS;INH:SOLVENT VAPORS CAN CAUSE IRRIT OR NARCOSIS.
* First Aid Measures *
MIN & CONSULT AN EYE PHYSICIAN;INH:REMOVE TO FRESH AIR.GIVE
CPR/OXYGEN IF NEEDE D.
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE,FOAM OR DRY CHEMICALS.
Fire Fighting Procedures:USE SELF-CNTND BRTHNG APP;CAN USE H*2O
SPRAY/FOG EFFECTIVLY.
Unusual Fire/Explosion Hazard:CAUTION AGAINST APPLICATION TO HOT
SURFACES & USE IN AREASWHERE SOURCES OF IGNITION MAY BE PRESENT.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE UNPROTCTD PERSONS.ELIM IGN
SOURCES.USE SAFETY EQUIP.VENTLATE AREA.STOP LEAK W/O RISK;ABSORB SM
SPILL W/OIL ABSORBING COMPD/RAGS.PER MFR,FLUSH AREA W/LG AMT
H*2O;DIKE LG SPILL.PUMP LIQ TO SALV AGE TANK.SHOVEL UP RESIDUE INTO
COVEREDCONTNRS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VETNILATED,LOW
FIRE RISK AREA.KEEP CONTAINERS TIGHTLY CLOSED.PROTECT FROM PHYSICAL
DAMAGE.
Other Precautions:AVOID PROLONGED INHALATION OF VAPORS.IF VENTILATION
IS POOR,USE A FRESH AIR SUPPLY MASK.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:>1.0
Evaporation Rate & Reference:<1(SLWR THAN ETHR)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:THIN ORGANIC LIQUID-ODOR OR MEK.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CORROSIVE/OXIDIZING MATERIALS
Stability Condition to Avoid:SOURCES OF IGNITION
Hazardous Decomposition Products:CO,CO
* Disposal Considerations *
Waste Disposal Methods:KEEP IN CLOSED CONTNRS PENDING DISPOSAL.MFR
SUGGESTED,DISPOSE IN TIGHTLY CLOSED CONTAINERS & FINALLY DISPOSE BY
SANITARY LANDFILL IAW APPLICABLE REGS;HANDLE & DISPOSE IN FULL
COMPLIANCE W/ALL FED,STAT E,& LOCAL REGULATIONS CONCERNING WASTE
DISPOSAL.
| 1 | gloves_mandatory |
Control Measures
*
Cage: 0FTT5
*
Preparer Co. when other than Responsible Party Co.
*
Cage: 0FTT5
*
Contractor Summary
*
Cage: 0FTT5
*
Item Description Information
*
Item Manager: GSA
Item Name: DEICING-DEFROSTING FLUID
Unit of Issue: CN
UI Container Qty: L
*
Ingredients
*
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: SEVERE IRRITATION/REDNESS/TEARING/ BLURRED VISION.
SKIN: PROLONGED/REPEATED CONTACT; MODERATE IRRITATION/ DEFATTING/DERMATITIS.
INHALE: NASAL/RESPIRATORY IRRITATION/CENTRAL NERVOUS SYSTEM EFFECT
S/DIZZINESS/NAUSEA/UNCONSCIOUSNESS/DEATH. INGEST: GASTROINTESTINAL IRRIT,
NAUSEA, VOMITING, DIARRHEA, BLINDNESS, DEATH.
Signs And Symptions Of Overexposure: IRRITATION TO EYES/THROAT/RESPIRATORY
TRACT. MAY CAUSE HEADACHES/NAUSEA/VOMITING.
Medical Cond Aggravated By Exposure: OPEN CUT AND SORES.
First Aid: SKIN/CLOTHES: WASH W/SOAP/WATER; WASH CLOTHES BEFORE REUSE. EYES:
INGEST: GIVE LARGE AMOUNTS WATER/MILK/INDUCE VOMITING. GE T IMMEDIATE MEDICAL
ATTENTION. INHALE: REMOVE TO FRESH AIR, GIVE ARTIFICIAL RESPIRATION IF
NECESSARY. GET MED AID IF NECESSARY. NEVER GIVE ANYTHING BY MOUTH TO
UNCONSCIOUS PERSON.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION AND VENTILATE AREA.
PICK UP SPILLAGE WITH INERT ABSORBENT MATERIAL AND SWEEP UP TO A CLOSABLE
CONTAINER. AVOID BREATHING VAPORS. DO NOT CONTAMINATE FOOD/FEED/WATERWAYS.
Waste Disposal Methods: DISPOSE IN ACCORDANCE W/APPLICABLE LOCAL, STATE AND
HEAT/PROLONGED EXPOSURE TO SUN MAY CAUSE CAN TO BURST. DISCARD EMPTY CAN IN T
RASH PICK-UP. DO NOT PLACE IN HOME TRASHCOMPACTOR.
Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. CAUTION-
BREATHING SPRAY/MIST/VAPOR.
Other Precautions: AVOID CONTACT W/EYES/SKIN. USE WITH GOOD VENTILATION. READ
ENTIRE LABEL BEFORE USING. FOLLOW ALL LABEL DIRECTIONS. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING AND INHALING OR SWALLOWING CONTENTS MAY BE
HARMFUL OR FATAL.
*
Fire and Explosion Hazard Information
*
Flash Point Method: TOC
Lower Limits: 5.5
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, SAND, WATER SPRAY.
AVOID SPREADING ANY BURNING LIQUID WITH WATER SPRAY.
Fire Fighting Procedures: WATER INEFFECTIVE BUT USED TO KEEP EXPOSED CONTAINERS
COOL. WEAR SCBA W/FULL FACEPIECE. USE SHIELDING TO PROTECT PERSONNEL FROM
RUPTURE/BURST/VENT CONTAINERS.
Unusual Fire/Explosion Hazard: DO NOT SPRAY NEAR OPEN FLAME. AT ELEVATED
*
*
Respiratory Protection: NONE BELOW TLV. USE NIOSH/MSHA APPROVED MASK ABOVE TLV.
Ventilation: LOCAL EXHAUST: PREFERRED. MECHANICAL: ACCEPTABLE AT POINT OF MIST
OR SPRAY RELEASE.
Other Protective Equipment: IMPERVIOUS CLOTHES TO PROTECT SKIN. EYEWASH
STATION.
Work Hygienic Practices: USE GOOD HYGIENE. DO NOT EAT, DRINK OR SMOKE WHILE
USING PRODUCT.
*
Physical/Chemical Properties
*
HCC: V3
Vapor Density: 1.1
Evaporation Rate & Reference: 3.1 (BUAC=1)
Solubility in Water: COMPLETE
Appearance and Odor: CLEAR THIN LIQUID; ALCOHOL ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS SUCH AS
NITRATES, PERCHLORATES OR SULFURIC ACID.
Hazardous Decomposition Products: TOXIC GASES AND VAPORS (CARBON MONOXIDE,
FORMALDEHYDE) MAY BE RELEASED IN METHANOL FIRE.
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CN
Container QTY: L
*
Detail DOT Information
*
DOT PSN Code: DTJ
Symbols: D
DOT Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
Label: NONE
Bulk Pack: NONE
Vessel Stow Req: A
*
Detail IMO Information
*
IMO PSN Code: AKH
IMO Proper Shipping Name: AEROSOLS/AEROSOL PRODUCT ?
UN Hazard Class: 9?
IMO Packaging Group: -
Subsidiary Risk Label: -
*
Detail IATA Information
*
IATA PSN Code: ALS
IATA Proper Shipping Name: AEROSOLS, FLAMMABLE
IATA PSN Modifier: (EACH NOT EXCEEDING 1 L CAPACITY)
IATA UN Class: 2.1
IATA Label: FLAMMABLE GAS
*
Detail AFI Information
*
AFI PSN Code: ALR
AFI Symbols: *
AFI Proper Shipping Name: AEROSOLS, FLAMMABLE, N.O.S.
AFI PSN Modifier: (EACH NOT EXCEEDING 1L CAPACITY)
AFI Hazard Class: 2.1
Special Provisions: P4
Back Pack Reference: A6.3
*
HAZCOM Label
*
Cage: 0FTT5
Company Name: LHB INDUSTRIES
Label Required IND: Y
Status Code: A
Origination Code: G
Hazard And Precautions: EYES: SEVERE IRRITATION/REDNESS/TEARING/ BLURRED
VISION. SKIN: PROLONGED/REPEATED CONTACT; MODERATE IRRITATION/
DEFATTING/DERMATITIS. INHALE: NASAL/RESPIRATORY IRRITATION/CENTRAL NERVOUS
SYSTEM EFFECT S/DIZZINESS/NAUSEA/UNCONSCIOUSNESS/DEATH. INGEST:
GASTROINTESTINAL IRRIT, NAUSEA, VOMITING, DIARRHEA, BLINDNESS, DEATH.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF OPERATING CONDITIONS CAUSE HIGH VAPOR
CONCENTRATION OR TLV IS EXCEEDED, USE NIOSH/MSHA APPROVED
SUPPLIED-AIR RESPIRATOR.
Ventilation:USE WITH ADEQUATE VENTILATION.
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
DECOMP PRODS: CO AND/OR CO2 AND OTHER HARMFUL PRODUCTS. EFTS OF
OVEREXP: AND DEATH IN A SHORT PERIOD OF TIME. LAB ANIMALS EXPOSED
TO RPTD APPLICATNS OF ASPHALT MATLS FOR THEIR ENTIRE LIFETIME HAVE
DEV ELOPED SKIN TUMORS PRIMARILY AT THE SITE OF APPLICATN. FINDINGS
INCL BRONCHITIS, PNEUM & ABSCESS FORMATION, (SEE ING 3)
* Product Identification *
Product ID:AMOCO NO. 3 KORITE ASPHALT
* Composition/Information on Ingredients *
Ingred Name:PETROLEUM ASPHALT, OXIDIZED. ACGIH TLV AS PETROLEUM ASPHALT
FUMES.
ACGIH TLV:5 MG/M3
Ingred Name:HYDROGEN SULFIDE (SARA III)
Ingred Name:SUPP DATA: AMONG OTHERS, SIMILAR TO PROBLEMS CAUSED BY
OTHER NON-SPECIFIC IRRITANTS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: HEATED MATERIAL CAN CAUSE THERMAL
BURNS. SKIN: HEATED MATL CAN CAUSE THERMAL BURNS. COLD MATL: NONE
EXPECTED FOR SINGLE SHORT-TERM EXPOSURES. CAN CAUSE SKIN IRRIT ON
PRLNG OR RPTD CONT. INHAL: VA PS CONTAINING HYDROGEN SULFIDE MAY
ACCUMULATE DURING STORAGE OR TRANSPORT OF ASPHALTIC MATLS, (SEE
EFTS OF OVEREXP)
Effects of Overexposure:HLTH HAZ: PARTICULARLY THOSE THAT CONTAIN
LITTLE DILUENT. INGEST: NO SIGNIFICANT HEALTH HAZARDS IDENTIFIED.
SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYE: HOT & COLD MATL: IMMED FLUSH EYES W/ PLENTY OF WATER FOR
SKIN W/ WATERLESS HAND CLEANER. INHAL: IF ADVERSE EFTS OCCUR,
REMOVE TO UNCONTAM AREA. GIVE ARTF RESP IF NOT BRTHG. GET MD.
INGEST: IF LRG AMT SWALLOWED, INDUCE VOMIT. GET MD.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:AGENTS APPROVED FOR CLASS B (E.G., DRY CHEM, CO2,
HALOGENATED AGENTS, FOAM, STEAM) OR WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:IF HYDROGEN SULFIDE IS PRESENT, FLAM LIMS
FORMATION OF PYROPHORIC IRON COMPOUNDS.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN AND REMOVE BY MECHANICAL MEANS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP ADEQ VENT. OUTSIDE STORAGE IS
REC. HYDROGEN SULFIDE (H2S) GAS MAY ACCUM IN STORAGE TANKS & BULK
TRANSPORT COMPARTMENTS CONTAINING ASPHALTS.
Other Precautions:ALWAYS EXERCISE CAUTION WHEN WORKING AROUND CLSD BULK
CNTNRS OF ASPHALTS. WARNING! VAPOR MAY CONTAIN HYDROGEN SULFIDE
(H2S) GAS WHICH CAN BE HARMFUL OR FATAL IF INHALED. HEATED MATL MAY
CAUSE SEVERE B URNS. COLD MATL CAN CAUSE SKIN IRRIT.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:1 (WATER = 1)
Solubility in Water:NEG, BELOW 0.1%
Appearance and Odor:DARK BROWN TO BLACK VISCOUS FLUID.
* Stability and Reactivity Data *
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:HYDROGEN SULFIDE AND OTHER TOXIC VAPORS
ARE GIVEN OFF AT ROOM TEMPERATURE.
Hazardous Decomposition Products:TOXIC HYDROGEN SULFIDE GAS & OTHER
SULFUR- CONTAINING GASES CAN BE GIVEN OFF WHEN HEATED. BURNING CAN
PRODUCE (SUPP DATA
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE W/APPLICABLE FED,
ST, OR LOC REGS. ENCLSD-CONTROLLED INCIN IS REC UNLESS DIRECTED
OTHERWISE BY APPLICABLE ORDINANCES.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED DUST MASK AS A MINIMUM.SELF CONT
APP FOR DUSTING COND
Ventilation:PROVIDE GOOD LOCAL VENTILATION TO KEEP BELOW PEL
Other Protective Equipment:FULL WORK CLOTHING TO PREVENT REPEATED OR
PROLONGED CONTACT.
Supplemental Safety and Health
SAFETY DATA DEVELOPED BY DGSC-STF.STORAGE CODE BASED ON FACT THAT
ASBESTOS IS BOUND UP & NOT LOOSE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS (AMIANTHUS, OBSOLETE AMOSITE), (FOR OSHA PEL, SEE
OSHA PEL:0.2 FIBERS/CC
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Effects of Overexposure:ASBESTOS DUST IN KNOWN HUMAN CARCINOGEN.ALSO
COUGH,SHORT OF BREATH,WEAKNESS,CYANOSIS,ETC.
* First Aid Measures *
First Aid:SKIN:CONSULT DOCTOR FOR DERMATITIS.EYES:FLUSH WITH WATER
FOLLOWED BY TREATMENTS OF OPTHALMOLOGIST.INHALATION:CONSULT
PHYSICIAN AT ONCE.
* Fire Fighting Measures *
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP
* Accidental Release Measures *
Spill Release Procedures:PICK UP MATERIAL & RETURN TO CONTAINER.IF ANY
BROKEN MATERIAL EXISTS,BE CAREFUL TO AVOID DUSTING CONDITIONS.PLACE
BROKEN MATERIAL INTO A SEALED CONTAINER.VACUUM OR WET CLEAN ONLY.DO
NTO DRY SWEEP.
*Handling and Storage *
Handling and Storage Precautions:AVOID CUTTING OR GRINDING ON
ITEM.AVOID ANY DUSTING CONDITIONS.MAINTAIN GOOD HOUSEKEEPING.
* Physical/Chemical Properties *
HCC:T6
Appearance and Odor:ASBESTOS FIBERS IN BOUND FORM IN FRICTION LINING.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Hazardous Decomposition Products:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:PLACE IN SEALED PLASTIC BAG OR
CONTAINER.ULTIMATE DISPOSAL MUST COMPLY WITH ALL LOCAL,STATE &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR WITH ORGANIC VAPOR
CANISTER.
Ventilation:LOCAL EXHAUST; YES, MECHANICAL (GENERAL);FAN
Other Protective Equipment:APRON & SAFETY SHOES
Work Hygienic Practices:DO NOT SMOKE, DRINK OR EAT IN WORK AREAS.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:HERBERT MOORE
* Composition/Information on Ingredients *
Ingred Name:2,4,6-TRI (DIMETHYL AMINO METHYL) PHENOL
Fraction by Wt: 5%
Other REC Limits:5 PPM SKIN
Ingred Name:VOC 1 GM/LITER
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VAPORS/MIST CAN IRRITATE THE NOSE &
THROAT. SEVERLY IRRITATING TO EYES & SKIN. MATERIAL CAN CAUSE SKIN
SENSITIZATION AND DERMATITIS.
Effects of Overexposure:HEADACHE, DIZZINESS, TEARING OF EYES & NOSE
IRRITATION. ITCHING OF SKIN WITH SIGN OF REDNESS.
Medical Cond Aggravated by Exposure:ASTHMA, LIVER.
* First Aid Measures *
First Aid:INHALATION; REMOVE TO FRESH AIR. INGESTION; CONTACT
PHYSICIAN. EYE & SKIN CONTACT; FLUSH EYES WITH WATER FOR AT LEAST
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER SPRAY
Fire Fighting Procedures:IN CONFINED AREAS WEAR SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:OXIDES OF NITROGEN, MAY BE PRODUCTS OF
COMBUSTION.
* Accidental Release Measures *
Spill Release Procedures:SCOOP UP & RETURN TO CONTAINER. WASH AREA WITH
SOAP AND WATER.
Neutralizing Agent:ACID
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL DRY AREAS AWAY FROM
DIRECT SUNLIGHT. KEEP IN CLOSED CONTAINERS.
Other Precautions:AVOID CONTACT WITH SKIN, EYES & CLOTHING. WASH
CONTAMINATED CLOTHING BEFORE RE-USE.
* Physical/Chemical Properties *
HCC:B3
Melt/Freeze Pt:M.P/F.P Text:*
Solubility in Water:SLIGHT
Appearance and Odor:TAN PASTE, AMINE ODOR. LIQUID AT ROOM TEMPERATURE.
Percent Volatiles by Volume:0.1
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING & REDUCING AGENT.
Stability Condition to Avoid:EXCESSIVE HEAT
* Disposal Considerations *
Waste Disposal Methods:REACT WITH BASE COMPONENT & DISPOSE AS NON-
HAZARDOUS WASTE ACCORDING TO FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE:INHALATION:IRRITATION OF RESPIRATORY TRACT.
PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DROWSINESS,
AND/OR LIGHT-HEADEDNESS, HEADACHE, NAUSEA. SKIN:IRRITATION. PROLONGED OR REPE
ATED CONTACT CAN CAUSE DERMATITIS. EYE:IRRITATION. PROLONGED OR REPEATED
CONTACT CAN CREATE BLURRED (EFTS OF OVEREXP)
INFORMATION (FP N).
Signs And Symptions Of Overexposure: HLTH HAZ:VISION, CORNEAL INJURY.
INGESTION:AMOUNTS INGESTED INCIDENTAL TO CONSUMER AND INDUSTRIAL HANDLING ARE
NOT LIKELY TO CAUSE INJURY; HOWEVER, INGESTION OF LARGER AMOUNTS COULD CAUSE
SERIOUS INJU RY.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
HAVE TRAINED PERSON GIVE OXYG IF NECESSARY. GET EMER MED ATTN. SKIN:WASH OFF
QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER; REMOVE CONTAMD CLTHG. WASH
CONTAMD CLTHG BEFORE REUSE.EYE:FLUSH IMMED W/LG AMTS OF WATER, ESPECIALLY
MEDICAL TREATMENT IMMEDIATELY.
*
Handling and Disposal
*
Spill Release Procedures: COLLECT IN CONTAINER FOR DISPOSAL, ACCORDING TO
HEALTH AND ENVIRONMENTAL REGULATIONS. CLEAN UP WITH WATER BEFORE ALLOWING TO
DRY.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Other Precautions: DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NON FLAMMABLE
Lower Limits: SEE INGS
Extinguishing Media: DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). NON-FLAMMABLE. WATER MAY BE USED TO COOL AND PROTECT EXPOSED
CONTAINERS.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY BURST IF EXPOSED TO
EXTREME HEAT OR FIRE.
*
*
Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLIC
STANDARDS. WHERE RESP PROT IS REQUIRED, USE ONLY NIOSH APPRVD RESPIRATORS IN
Ventilation: MAINTAIN ADEQUATE VENTILATION TO ENSURE AIR ENTRY DURING
APPLICATION & DRYING TO PREVENT BUILD-UP OF VAPORS.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). SKIN
CREAM (IF NEEDED).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: USER OF "L" VERSION OFSHOULD CONSULT "LR"
VERSION FOR ADDITIONAL INFORMATION (FP N). MFR TRADE NAME/PART NO:LATEX HOUSE
PAINT.
*
Physical/Chemical Properties
*
Vapor Pres: SEE INGS
Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER
Solubility in Water: NOT KNOWN
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES. CONTACT WITH OXIDIZING
AGENTS.
Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES.
Hazardous Decomposition Products: IF INVOLVED IN FIRE (FROM OTHER SOURCES)
COULD CONCEIVABLY RESULT IN RELEASE OF CARBON DIOXIDE & CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Assigned IND: Y
Company Name: MA BRUDER & SONS INC
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:INHALATION:IRRITATION OF RESPIRATORY TRACT.
PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBRANE IRRITATION, DROWSINESS,
AND/OR LIGHT-HEADEDNESS, HEADACHE, NAUSEA. SKIN:IRRITATION. PROLONGED OR REPE
ATED CONTACT CAN CAUSE DERMATITIS. EYE:IRRITATION. PROLONGED OR REPEATED
CONTACT CAN CREATE BLURRED VISION, CORNEAL INJURY. INGESTION:AMOUNTS INGESTED
INCIDENTAL TO CONSUMER & INDUSTRIAL HANDLING ARENOT LIKELY TO CAUSE
INJURY; HOWEVER, INGESTION OF LARGER AMOUNTS COULD CAUSE SERIOUS INJURY.
CHRONIC:CANCER HAZARDS. CONTAINS MATERIALS WHICH ARE LISTED AS ANIMAL LUNG
CARCINOGENS (FP N).
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOR CASUAL/OCCAS USE-TO AVOID BRTHG VAPS/SPRAY
MIST, OPEN WINDOWS & DOORS/USE OTHER MEANS TO ENSURE FRESH AIR
ENTRY DURING APPLICATN & DRYING. IF YOU EXPER EYE WATERING,
HDCHS/DIZZ, INCREASE FRESH AIR . WEAR RESP PROT (NIOSH/MSHA (SUPP
DATA)
Ventilation:PROVIDE SUFFICIENT MECH (GEN) &/OR LOCAL EXHAUST
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV'S IN INGREDIENTS.
Other Protective Equipment:WHERE SPECIAL OR UNUSUAL CONDITIONS EXIST,
THE EXPERT ASSISTANCE OF AN INDUSTRIAL HYGIENIST SHOULD BE SOUGHT.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING WASHROOM. AS
WITH ALL CHEMICALS, MINIMIZE PERSONAL CONTACT AND BREATHING OF
VAPORS.
Supplemental Safety and Health
FIRE FIGHT PROC:AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER
IS USED, FOG NOZZS PREF. EXPLO HAZS:LIGHTS, OTHER FLAMES, SPKS,
HEATERS, SMKNG, ELEC MOTORS/OTHER IGNIT SOURCES AT LOCATIONS DIST
FROM MATL HNDLG PT. FIRST AID PROC:WASH CLTHG BEFORE REUSE. RESP
* Product Identification *
Product ID:IMPERIAL ENAMELS, NIMBUS GRAY
* Composition/Information on Ingredients *
Fraction by Wt: 5%
FASTER THAN ETHER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PROPANE
ACGIH TLV:ASPHYXIANT
Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE MIXTURE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BUTANE; (N-BUTANE)
Ingred Name:NON-HAZARDOUS INGREDIENTS
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:EYE PROT:AND FULL LENGTH FACE SHIELD .
Ingred Name:OTHER PROT EQUIP:ANSI APPROVED EYE BATH AND DELUGE SHOWER .
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:EXCESSIVE INHAL OF VAPS
CAN CAUSE NASAL & RESP IRRIT, DIZZ, WEAK, FATG, NAUS, HDCH, POSS
UNCON & EVEN ASPHY. EYES:CAN CAUSE SEV IRRIT, REDNESS, TEARING,
BLURRED VISION. INGEST:CAN CAUSE GI IRRIT, NAUS, VOMIT, DIARR.
SKIN:CAN CAUSE IRRIT FOR SOME PERSONS. CHRONIC:RPTS HAVE ASSOC RPTD
& (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:PRLNGD OCCUP OVEREXP TO SOLVS W/PERM
BRAIN & NERV SYS DMG. SEV OVEREXP IN LAB ANIMALS HAS ALSO CAUSED
LIVER ABNORMALITIES AND DAMAGE TO KIDNEYS, LUNGS AND SPLEEN.
INTENTIONAL MISUSE BY DELIB ERATELY CONCENTRATING AND INHALING THE
CONTENTS MAY BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:CAN CAUSE ALLERGIC RESPIRATORY
AND/OR SKIN REACTION.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN OXYG. IF
BRTHG HAS STOPPED, GIVE ARTF RESP & SEEK MED HELP. EYES:FLUSH
ATTN. ING EST:DO NOT INDUCE VOMIT (ASPIR OF MATL INTO LUNGS CAN
CAUSE CHEM PNEUM, WHICH CAN BE FATAL). KEEP WARM, QUIET & GET MED
ATTN/POIS CTL CTR. SKIN:WASH W/SOAP & WATER/VARIOUS HAND CLEANERS,
& (SUPP DATA)
* Fire Fighting Measures *
Lower Limits:1.0%
Extinguishing Media:"ALCOHOL" FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
WATER SPRAY MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLSD CNTNRS
TO PVNT PRESS BUILD-UP & POSS (SUP DAT)
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE &/OR AUTOIGNITE
WHEN EXPOSED TO EXTREME HEAT. VAPS ARE HVR/AIR & MAY TRAVEL ALONG
GROUND/MAY BE MOVED BY VENT & IGNITED BY PILOT(SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE
AREA. ABSORB LIQUID ON PAPER, VERMICULITE, FLOOR ABSORBENT, OR
OTHER ABSORBENT MATERIAL AND TRANSFER TO A CLOSED CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
DIRECT SUNLIGHT, OR NEAR HEAT OR OPEN FLAMES. DO NOT PUNCTURE OR
INCINERATE.
Other Precautions:STORE LARGE QUANTITIES IN BUILDINGS PROTECTED FOR
STORAGE OF NFPA CLASS IC FLAMMABLE LIQUIDS.
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:<1 (H*2O=1)
Evaporation Rate & Reference:>1 (BUAC=1) SLOWER/ETHER
Solubility in Water:SLIGHT TO MODERATE
Appearance and Odor:TYPICAL SOLVENT PAINT.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS AND HEAT.
Stability Condition to Avoid:HEAT, SPARKS, AND OPEN FLAME.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS, CARBON
DIOXIDE/CARBON MONOXIDE, VARIOUS HYDROCARBS, NITROGEN CMPDS, ETC.,
WHEN BURNED.
* Disposal Considerations *
Waste Disposal Methods:MATERIAL COLLECTED ON ABSORBENT MATERIAL MAY BE
DEPOSITED IN A POSTED TOXIC SUBSTANCES LANDFILL IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:PROVIDE ADEQUATE MECHANICAL EXHAUST VENTILATION.
Work Hygienic Practices:WASH SKIN & HANDS AFTER USE.
Supplemental Safety and Health
THIS PRODUCT CONTAINS A CHEMICAL SUBJECT TO THE REPORTING REQUIREMENTS
* Product Identification *
Product ID:EASY GLAZE
* Composition/Information on Ingredients *
ISOPARAFFINIC HYDROCARBONS
Fraction by Wt: 5%
Ingred Name:ETHYLENE GLYCOL (SARA III)
Fraction by Wt: 2%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
ACID, ACRYLIC RESIN, ACRYLIC OLIGOMER (EMULSION)
Ingred Name:BUTYL BENZYL PHTHALATE (SARA III)
Other REC Limits:5 MG/CUM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: DIZZINESS, ABDOMINAL
DISCOMFORT, CENTRAL NERVOUS SYSTEM DEPRESSION, HEADACHE, NAUSEA, &
MUCOUS MEMBRANE IRRITATION. EYES: CONJUNCTIVITIS. SKIN/INGESTION:
IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: DIZZINESS, ABDOMINAL DISCOMFORT,
CENTRAL NERVOUS SYSTEM DEPRESSION, HEADACHE, NAUSEA, & MUCOUS
MEMBRANE IRRITATION. EYES: CONJUNCTIVITIS. SKIN/INGESTION:
IRRITATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN/EYES: FLUSH W/WATER FOR
MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:TOC
Lower Limits:1%
Upper Limits:6%
Extinguishing Media:CO2, FOAM, DRY CHEMICAL, OR WATER
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN
POSITIVE PRESSURE MODE & FULL PROTECTIVE GEAR.
* Accidental Release Measures *
Spill Release Procedures:SCRAPE INTO CONTAINERS.
*Handling and Storage *
Handling and Storage Precautions:DON'T INGEST. DON'T STORE NEAR HEAT
KEEP AWAY FROM CHILDREN.
Other Precautions:USE IN PROPERLY VENTILATED AREAS.
* Physical/Chemical Properties *
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN BU AC
Solubility in Water:COMPLETE
Appearance and Odor:WHITE SEMI-SOLID W/SLIGHT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS & ACIDS
Stability Condition to Avoid:HEAT SOURCES, SPARKS, FLAMES, FREEZING.
Hazardous Decomposition Products:CO, CO2, TOXIC GASES & AEROSOLS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF BY SANITARY LANDFILL IN ACCORDANCE
W/FEDERAL, STATE, & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR DUST MASK.
Ventilation:LOCAL EXHAUST: AS REQUIRED. MECHANICAL (GENERAL): VENT FAN.
Supplemental Safety and Health
SOLUBILITY IN WATER: POWDERS-APPRECIABLE. LIQUIDS-MISCIBLE.
* Product Identification *
Product ID:ALCOHOL DEHYDROGENASE
* Composition/Information on Ingredients *
Ingred Name:ALCOHOL DEHYDROGENASE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN, EYE/RESPIRATORY TRACT
IRRITATION UPON CONTACT. ALLERGIC REACTIONS IN CERTAIN SENSITIVE
INDIVIDUALS MAY DEVELOP.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, ALLERGIC REACTIONS.
Medical Cond Aggravated by Exposure:ALLERGIES, ASTHMA.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES/SKIN: WASH THOROUGHLY
W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:AVOID PHYSICAL CONTACT & DUST DURING REMOVAL.
USE NORMAL CLEAN-UP PROCEDURES & WASH THOROUGHLY W/WATER.
*Handling and Storage *
Handling and Storage Precautions:NONE
Other Precautions:NONE
* Physical/Chemical Properties *
Solubility in Water:(SEE SUPP)
Appearance and Odor:POWDERS- WHITE TO TAN. LIQUIDS-WHITE TO BROWN. BOTH
HAVE TYPICAL ENZYME ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:FLUSH IN SEWERAGE SYSTEM W/WATER IAW/FEDERAL,
STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED. MECHANICAL DEVICE IN
CONFINED AREAS.
Ventilation:NORMALLY NOT NEEDED. MECHANICAL/GENERAL DEVICE IN CONFINED
AREAS.
Other Protective Equipment:NORMALLY NOT NEEDED.
Work Hygienic Practices:ALWAYS USE GOOD HYGIENE.
Supplemental Safety and Health
* Product Identification *
Product ID:GRISOLVE PEG-2
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS INGREDIENTS
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: EYE, SKIN, RESPIRATORY
AND GASTROINTESTINAL TRACTS. EYES:REMOVE CONTACT LENSES.
INHALATION: SEEK FRESH AIR. SKIN:REMOVE CONTAMINATED CLOTHING.
INGESTION:DRINK WATER TO DILUTE SUBSTANCE .
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NAUSEA, VOMITING, PAIN, TEARING
Medical Cond Aggravated by Exposure:CAN CAUSE EYE DAMAGE AND SKIN
IRRITATION.HARMFUL IF SWALLOWED. INHALATION MAY CAUSE NAUSEA.
* First Aid Measures *
First Aid:INHALED - REMOVE TO FRESH AIR. EYES: REMOVE CONTACT LENSES.
CLOTHES. WASH SKIN WITH PLENTY OF SOAP & WATER. INGESTED: DRINK
WATER TO DILUT E SUBSTANCE. CALL PHYSICIAN IF NEEDED. NOT A PRIMARY
IRRITANT.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE (CO2), WATER BY
SPRAY ONLY.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-PPROVED
SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION
PRODUCTS (CARBON MONOXIDE, CARBON DIOXIDE,FUMES) MAY BE FORMED.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. AVOID, HEAT, SPARK
AND OPEN FLAME. MOST OIL-BASED PRODUCTS CONTAMINATED WITH RAGS AND
ABSORBENTS SOAKED WITH THIS PRODUCT MAY IGNITE SPONTANEOUSLY.
ALWAYS PLACE USED MATERIALS IN A IR TIGHT METAL CAN CONTAINING
SOAPY WATER. DO NOT DISPOSE OF MATERIALS IN OPEN TRASH BINS OR
DUMPSTERS.
* Accidental Release Measures *
Spill Release Procedures:SMALL SPILLS SHOULD BE ABSORBED BY DIRT, SAND
OR SUITABLE ABSORBENT. LARGE SPILLS MAY BE DIKED WITH EARTH OR
PUMPED TO CLOSED CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE NEAR STRONG OXIDIZING
AGENTS.
Other Precautions:AVOID BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN
OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. LAUNDER BEFORE
REUSE. KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
HCC:V4
Vapor Density:CA.4.6
Solubility in Water:SOLUBLE
Appearance and Odor:PALE YELLOW/ PINE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE AT A GOVERNMENT APPROVED LANDFILL,
INCINERATION OR RECOVERY FACILITY. OBSERVE LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:LOCAL EXHAUST IS ADEQUATE.
Work Hygienic Practices:WASH SKIN W/SOAP & WATER AFTER USE. DO NOT
SMOKE/DRINK/EAT NEAR PRODUCT.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:PATRICK PASIERB
* Composition/Information on Ingredients *
Ingred Name:METHYLENE CHLORIDE(SARA III)
Other REC Limits:NONE RECOMMENDED
Ingred Name:HYDROCARBON PROPELLANT (LIQUIFIED PETROLEUM GAS, SWEETENED)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION:SHORTNESS OF BREATH,
DIZZINESS, LIGHT HEADEDNESS.ANESTHETIC EFFECTS MAY OCCUR @ HIGH
CONC. INGESTION:MAY CAUSE CHEM PNEUMONIA IF ASPIRATED INTO LUNGS.
EYE IRRITANT. SKINCONTACT:PROLONGED/ REPEATED CONTACT-MINOR TO
MILD IRRITATION. SKIN ABSORPTION:VERY LOW TOXICITY.
Explanation of Carcinogenicity:PER MFG'S MSDS:IARC-CURRENTLY LISTED AS
GROUP 3 SUBSTANCE (INADEQUATE EVIDENCE IN HUMANS/ANIMALS TO
EVALUATE CARCINOGEN)
Effects of Overexposure:PROLONGED/REPEATED CONTACT RESULTS IN MINOR TO
MILD IRRITATION. PROLONGED EXPOSURE ABOVE OSHA PERMISSIBLE EXPOSURE
LIMITS MAY RESULT IN KIDNEY & LIVERY DAMAGE.
Medical Cond Aggravated by Exposure:MAY CAUSE MYOCARDIAL IRRITABILITY.
AVOID EPINEPHRINE OR SIMILAR DRUGS IF AT ALL POSSIBLE.
* First Aid Measures *
SUBSIDES. SKIN:REMOVE CONTAMINATED ITEMS; WASH SKIN W/SOAP&WATER.
INHALATION:REMOVE FROM EXPOSURE. BREATHING STOPPED/IRREGULAR BEGIN
ARTIFI. RESPIR. & GIVE OXYGEN. INGESTION:DRINK LG AMTS OF WATER.
DON'T INDUCE VOMITING.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.8
Upper Limits:9.5
Extinguishing Media:CARBON DIOXIDE, FOAM AND DRY CHEMICAL
Fire Fighting Procedures:TREAT AS CYLINDERS OF COMPRESSED GAS.
FIREFIGHTERS SHOULD USE A SELF-CONTAINED POSITIVE PRESSURE
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:TREAT AS CYLINDERS OF CONPRESSED GAS.
CANS MAY EXPLODE IN FIRE.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
CLEANUP W/INERT MATLS & DISPOSE IAW LOCAL/STATE/FEDERAL
REGULATIONS.
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE IN DIRECT SUNLIGHT/OPEN
DIRECTED.
Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING
VAPORS AND INHALING CONTENTS CAN BE HARMFUL OR FATAL.
* Physical/Chemical Properties *
HCC:V3
Vapor Density:UNK
Spec Gravity:>1
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:SLIGHTLY
Appearance and Odor:CLEAR W/ETHEREAL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALUMINUM, TITANIUM ALKALI METALS.
Stability Condition to Avoid:OPEN FLAMES AND ELECTRICAL ARCS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION WILL RESULT IN
THE FORMATION OF HYDROGEN CHLORIDE AND PHOSGENE IN SMALL AMOUNTS.
* Disposal Considerations *
Waste Disposal Methods:AEROSOL CONTAINER: DO NOT PUNCTURE/INCINERATE.
EMPTY CONTAINERS MAY BE DISPOSED OF THROUGH NORMAL CHANNELS.
FULL/PARTIALLY FILLED CONTAINERS ARE CONSIDERED HAZARDOUS WASTE.
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHAL:IRRIT OF RESP TRACT. PRLNG INHAL MAY LEAD TO FATG,
DROW, DIZZ &/OR LT HEAD, HDCH, LACK OF COORD, NAUS, VOMIT, CNS DEPRESS,
ANESTH EFT/NARCOS. SKIN CONT:IRRIT. PRLNG/RPTD CONT CAN CAUSE DERM, DEF AT.
EYE CONT:IRRIT. PRLNG/RPTD CONT CANCAUSE BLURRED VISION, REDNESS, TEARING,
SEV IRRIT. INGEST:AMTS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLT HAZ:INGESTED INCIDENTAL TO CONSUMER
& INDUS HNDLG ARE NOT LIKELY TO CAUSE INJURY; HOWEVER, INGEST OF LGR AMTS
MAY CAUSE LUNG INFLAMM & DMG DUE TO ASPIR OF MATL INTO LUNGS. NOTICE:RPTS
HAVE ASSOC R PTD & PRLNG OCCUP OVEREXP TO SOLVS W/PERM BRAIN & NERV
SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHALING (SUPP DATA)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET EMERGENCY MED ATTN. SKIN:WASH OFF
QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER; REMOVE CONTAM CLTHG. WASH
CONTAM CLTHG BEFORE REUSE. EYE:FLUSH IMMED W/LG AMTS OF WATER, ESP UNDER
TREATMENT IMMED.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION (FLAME, HOT SURFACES
& ELECTRICAL, STATIC SPARKS). VENTILATE AREA & AVOID BREATHING
VAPORS. CONTAIN & REMOVE W/INERT ABSORBENT MATERIAL USING NON-SPARKING
TOOLS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
AVOID DISCHARGE TO NATURAL WATERS.
IN BLDGS DESIGNED FOR STOR OF FLAMM/COMBUST LIQS. DO NOT TAKE INTERNALLY.
KEEP OUT OF REACH OF CHILDREN.
Other Precautions: DO NOT WELD/FLAME CUT W/OUT PROPER VENT TO INSURE AREA IS
FREE OF FLAMM VAPS. DO NOT CUT, PUNCTURE/WELD ON/NEAR CNTNR. ENTRANCE INTO
CLSD STOR TANKS - USE APPROP NIOSH/MSHA APPRVD RESP/AIRLINE FOR POS S EXPOS
TO SOLV/CHEM FUMES. RAGS(SUPDAT)
*
Fire and Explosion Hazard Information
*
Flash Point Method: SCC
Lower Limits: SEE INGS
Extinguishing Media: DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). WATER MAY BE USED TO COOL & PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLSD CNTNRS MAY EXPLODE WHEN EXPOS TO EXTREME
HEAT/FIRE. VAPS CAN FORM EXPLO MIXTS IN AIR AT ELEVATED TEMPS. MAY DECOMPOSE
UNDER FIRE CNDTNS EMITTING (SUPDAT)
*
*
Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTER RESPIRATOR DESIGNED
Ventilation: ALL APPLICATION AREAS SHOULD BE VENTILATED I/A/W OSHA REGULATION
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). EXPLO HAZ:IRRIT &/OR TOX GASES. EFTS OF
OVEREXP:CONTENTS MAY BE HARMFUL/FATAL. OTHER PREC:OR WASTE CNTNG OIL BASED
PAINT/VA RNISH THAT PRESENT LG AIR-TO-OIL INTERFACE WILL OXIDIZE & MAY
IGNITE SPONT & SHOULD BE PLACED IN METAL CNTNR.
*
Physical/Chemical Properties
*
Vapor Pres: SEE INGS
Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURES. CONTACT W/OXIDIZING
AGENTS.
Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: M A BRUDER & SONS INC
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE:INHAL:IRRIT OF RESP TRACT. PRLNG INHAL
MAY LEAD TO FATG, DROW, DIZZ &/OR LT HEAD, HDCH, LACK OF COORD, NAUS,
VOMIT, CNS DEPRESS, ANESTH EFT/NARCOS. SKIN CONT:IRRIT. PRLNG/RPTD CONT CA N
CAUSE DERM, DEFAT. EYE CONT:IRRIT. PRLNG/RPTD CONT CAN CAUSE BLURRED VISION,
REDNESS, TEARING, SEV IRRIT. INGEST:INGESTION OF LARGER AMOUNTS MAY CAUSE
LUNG INFLAMMATION & DAMAGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS.
CHRONIC:REPORTS HAVE ASSOCIATED REPEATED & PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
INTENTIONAL MISUSE BY DELIBERATELY CONCENTRA TING & INHALING CONTENTS MAY
BE HARMFUL/FATAL.
*
| 1 | gloves_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: N/K (FP N)
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
------------------------------
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 5-5.8
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
PHOSPHATE)
% Wt: 3.3-3.9
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 2-2.4
ACGIH TLV: 5 MG/M3
------------------------------
% Wt: 1.9-2.2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
G/L.
-----------------------------
COMMUNICATION STD, THEY ARE NOT EXPECTED EFTS
-----------------------------
DISORDERS:SIGNS/SYMPS CAN INCL PRLNG WEAK & FATG.
-----------------------------
INGEST:NOT LIKELY RTE OF EXPOS TO THIS PROD.
-----------------------------
TENDERNESS, NAUS, BLOOD IN VOMITUS & BLOOD IN FECES.
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE CONT:MOD IRRIT:SIGNS/SYMPS CAN INCL REDNESS, SWELL,
PAIN, TEARING & HAZY VISION. SKIN CONT:MILD IRRIT(AFTER PRLNG/RPTD
CONT):SIGNS/SYMPS CAN INCL REDNESS, SWELL & ITCH. MAY BE ABSORBED &
PRDCE EFT S SIMILAR TO THOSE CAUSED BY INHAL &/ORINGEST. INHAL:CNS
DEPRESS:SIGNS/SYMPS CAN INCL HDCH, DIZZ, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:DROW, INCOORD, SLOWED RXN TIME,
SLURRED SPEECH, GIDD & UNCON. IRRIT(UPPER RESP): SIGNS/SYMPS CAN INCL
SORENESS OF NOSE & THROAT, COUGH & SNEEZING. PRLNG/RPTD OVEREXP,
ABOVE REC GUIDELINES, MA Y CAUSE:KIDNEY EFTS:SIGNS/ SYMPS CAN INCL REDUCED
URINE VOL, BLOOD IN URINE & BACK PAIN. LIVER EFTS:SIGNS/SYMPS (SUPDAT)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN:FLUSH W/LARGE AMOUNTS OF
WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. INHAL:REMO VE PERSON TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GET IMMEDIATE MEDICAL ATTENTION. INGEST:DO NOT INDUCE VOMITING,
DRINK TWO GLASSES OF WATER. CALL MD.
*
Handling and Disposal
*
Spill Release Procedures: REFER TO OTHER SECTIONS OF THIS MSDS FOR INFO
REGARDING PHYSICAL & HLTH HAZS, RESP PROT, VENT & PPE. IN USA, CALL
IGNIT SO URCES. COVER W/ABSORB MATL. COLLECT USING (SUPDAT)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISP MUST BE I/A/W FED, STATE & LOC REGS (FP N).
INCIN IN PERMITTED HAZ WASTE INCIN IN PRESENCE OF COMBUST MATL. DISP OF
COMPLETELY CURED (OR POLYMERIZED) MATL IN SANIT LANDFILL. SINCE REGS VARY,
CONS ULT APPLIC REGS/AUTHS BEFORE DISP. U.S.(SUPDAT)
Handling And Storage Precautions: AVOID EYE CONTACT. AVOID PROLONGED OR
REPEATED SKIN CONTACT. USE IN A WELL-VENTILATED AREA. AVOID PROLONGED
BREATHING OF VAPORS. DO NOT INGEST.
Other Precautions: KEEP CONTAINER TIGHTLY CLOSED. FLAMMABLE LIQUID & VAPOR.
KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME & OTHER SOURCES OF IGNITION.
PRECAUTIONARY INFORMATION & FLASH POINT REFER TO UNCURED PRODUCT BEFORE
AP PLICATION.
*
Fire and Explosion Hazard Information
*
Flash Point Method: PMCC
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS EXPOSED TO HEAT FROM FIRE MAY
BUILD PRESSURE & EXPLODE. VAPORS MAY TRAVEL LONG DISTANCES ALONG
GROUND/FLOOR TO IGNITION SOURCE & FLASH BACK.
*
*
Respiratory Protection: SELECT ONE OF THE FOLLOWING NIOSH APPROVED RESPIRATORS
BASED ON AIRBORNE CONCENTRATION OF CONTAMINANTS & I/A/W OSHA REGULATIONS:
HALF-MASK ORGANIC VAPOR RESPIRATOR.
Ventilation: PROVIDE SUFFICIENT VENT TO MAINTAIN EMISSIONS BELOW RELS. IF EXHST
VENT IS NOT ADEQ, USE APPROP NIOSH APPRVD RESP PROT.
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
NO-SAG CAULK. SPILL PROC:NON-SPARKING TOOLS. PLACE IN U.S. DOT-APPRVD CNTNR.
YELLOW SKIN(JAUN) & TENDERNESS OF UPPER ABDOMEN. WHILE FOLLOWING EFTS
ARE ASSOC W/ONE OR MORE OF INDIVIDUAL INGS IN
*
Physical/Chemical Properties
*
Solubility in Water: NIL
Appearance and Odor: REDDISH BROWN PASTE; SOLVENT ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Hazardous Decomposition Products: CARBON MONOXIDE & CARBON DIOXIDE, HYDROGEN
CHLORIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE:EYE CONT:IRRIT; REDNESS, SWELLING,
PAIN, TEARING & HAZY VISION. SKIN CONT:IRRIT; REDNESS, SWELLING &
ITCHING. MAY BE ABSORBED & PRDCE EFTS SIMILAR TO THOSE CAUSED BY INHAL
&/OR INGEST . INHAL:CNS DEPRESS:HDCH, DIZZ, DROW, INCOORD, SLOWED
REACTION TIME, SLURRED SPEECH, GIDDINESS, UNCONSCIOUSNESS. IRRIT; SORE NOSE
& THROAT, COUGHING, SNEEZING. BLOOD DISORDERS, PROLONGED WEAKNESS, FAT
IGUE. HEART EFTS:ARRHYTHMIA, HEART ATTACK & DEATH. INGEST:IRRIT; PAIN,
VOMIT, ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMIT & FECES.
CHRONIC:KIDNEY EFTS, REDUCED URINE VOLUME, BLOOD IN URINE, BACK PAIN .
LIVER:YELLOW SKIN, TENDERNESS OF UPPER ABDOMEN.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED PAINT SPRAY RESPIRATOR
EXHAUSTED. IF PRODUCT IS USED WITH ISOCYANATE ADDITIVE (DULUX
Ventilation:LOCAL AND MECHANICAL(GENERAL) EXHAUST TO PROVIDE ADEQUATE
VENTILATION.
Other Protective Equipment:WEAR INDUSTRIAL WORK CLOTHING. COVERALLS ARE
RECOMMENDED. HAVE EMERGENCY EYE WASH AND SAFETY SHOWER AVAILABLE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MIST. DO NOT INGEST. READ PRECAUTIONS ON
LABEL BEFORE USE.
* Product Identification *
CAGE:0ERJ7
CAGE:0ERJ7
* Composition/Information on Ingredients *
Ingred Name:TOLUENE (SARA III)
Fraction by Wt: 3%
Other REC Limits:NONE SPECIFIED
Ingred Name:CARBON BLACK
Other REC Limits:NONE SPECIFIED
OSHA PEL:3.5 MG/M3
Ingred Name:VM&P NAPHTHA
Other REC Limits:NONE SPECIFIED
Ingred Name:MEDIUM MINERAL SPIRITS
Other REC Limits:NONE SPECIFIED
Ingred Name:LEAD DRIER, (NAPHTHENIC ACID, LEAD SALT)
Fraction by Wt: 1%
Other REC Limits:NONE SPECIFIED
Ingred Name:ALKYD RESIN
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE IRRITATION OR BURNING
OF EYES. INHALATION: MAY CAUSE NOSE AND THROAT IRRITATION.
OVEREXPOSURE TO SOLVENTS MAY LEAD TO PERMANENT BRAIN AND NERVOUS
SYSTEM DAMAGE AND LIVER AND KIDNEY INJ URY. SKIN: PROLONGED CONTACT
MAY CAUSE ABSORBTION OF HARMFUL AMOUNTS OF LEAD. INGESTION:
GASTRO-INTESTINAL DISTRESS.
Effects of Overexposure:IRRITATION OF THE EYES, SKIN AND RESPIRATORY
TRACT. MAY ALSO CAUSE EYES WATERING, HEADACHES, NAUSEA, DIZZINESS
AND LOSS OF COORDINATION. MAY ALSO CAUSE ASTHMA-LIKE REACTIONS WITH
SHORTNESS OF BREATH, WHEEZING, COUGH OR LUNG SENSATION. THISEFFECT
MAY BE DELAYED FOR SEVERAL HOURS AFTER EXPOSURE.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN OR RESPIRATORY
TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
SKIN: WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET
MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: REMOVE TO
FRESH AI R. IF BREATHING DIFFICULTY PERSISTS GETMEDICAL ATTENTION.
INGESTION: IN THE UNLIKELY EVENT OF INGESTION, GET MEDICAL
ATTENTION AND HAVE THE NAMES OF INGREDIENTS AVAILABLE.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:0.8
Extinguishing Media:USE WATER SPRAY,CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT
INCLUDING SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY TO PREVENT PRESSURE BUILDUP.
Unusual Fire/Explosion Hazard:HEATED ABOVE FLASH POINT, EMITS FLAMMABLE
VAPORS WHICH WHEN MIXED WITH AIR, CAN BURN OR BE EXPLOSIVE. FINE
MISTS OR SPRAYS MAY BE FLAMMABLE BELOW FLASH POINT.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT AND BREATHING OF VAPORS. WEAR APROPERLY FITTED
VAPOR/PARTICULATE RESPIRATOR (USE NIOSH/MSHA APPROVED RESPIRATOR
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, AND
FLAME. KEEP CONTAINERS CLOSED WHEN NOT USING. GROUND CONTAINERS
Other Precautions:DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING
WITHOUT A NIOSH/MSHA APPROVED RESPIRATOR OR APPROPRIATE
* Physical/Chemical Properties *
HCC:F2
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MISCIBLE
Appearance and Odor:LIQUID PAINT WITH CHARACTERISTIC ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MANUFACTURER STATES THAT NONE ARE REASONABLY FORESEEABLE. HOWEVER,
AVOID STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
SMOKE, OXIDES OF HEAVY METALS INCLUDED IN THIS SPECIFIC PRODUCT.
* Disposal Considerations *
Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE WITH
REGULATIONS. DO NOT ALLOW MATERIALTO CONTAMINATE GROUND WATER
SYSTEMS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED DUST MASK FOR ORDINARY USE,
NIOSH/MSHA APPROVED SCBA FOR EMERGENCY USE.
Other Protective Equipment:LAB COAT AND APRON, FLAME & CHEMICAL
RESISTANT COVERALLS, EYEWASH CAPABLE OF SUSTAINED FLUSHING, SAFETY
DRENCH (ING 9)
Work Hygienic Practices:WASH THOROUGHLY AFTER USE.
Supplemental Safety and Health
APPEAR & ODOR: DISCOLORS RAPIDLY ON EXPOSURE TO MOIST AIR. EXTING
MEDIA: DRY GROUND DOLOMITE. MATLS TO AVOID: MATERIAL IS OXIDIZER.
EFTS OF OVEREXP: POLYCYTHEMIA, CARDIAC FAILURE, VOMITING,
CONVULSION S & THYROID ENLARGEMENT. (ING 2)
* Product Identification *
CAGE:0JVJ1
CAGE:0JVJ1
* Composition/Information on Ingredients *
Ingred Name:COBALT (III) FLOURIDE
OSHA PEL:2.5 MG/M3 (F)
ACGIH TLV:2.5 MG/M3 (F)
Ingred Name:SUPP DATA: SKIN: REPEATED EXPOSURE TO COBALT MAY CAUSE
ALLERGIC DERMATITIS. INHAL: COBALT (ING 3)
Ingred Name:ING 2: FUMES AND DUST MAY CAUSE BENIGN PNEUMOCONIOSIS, PULM
SENSITIZATION. OTHER: INTAKE (ING 4)
Ingred Name:ING 3: OF MORE THAN 6 MG OF FLUORIDE PER DAY MAY RESULT IN
FLUOROSIS. HYPOCALCEMIA AND HYPOMAGNESEMA CAN OCCUR (ING 5)
Ingred Name:ING 4: FROM ABSORPTION OF FLUORIDE IONS INTO BLOOD STREAM.
COBALT HAS PRODUCED TUMORS IN EXPERIMENTAL ANIMALS (ING 6)
Ingred Name:ING 5: AND COBALT HAS BEEN ASSOCIATED WITH KIDNEY DAMAGE.
Ingred Name:CARCIN COMMENTS: ANIMAL: PULM FIBROSIS (BLOOD EFTS).
Ingred Name:FIRST AID PROC: GIVE OXYGEN. GET MEDICAL HELP IMMEDIATELY.
Ingred Name:OTHER PROT EQUIP: SHOWER AND HYGIENIC FACILITIES FOR
WASHING.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:CORR. MAY CAUSE SORE
THROAT, ABDOM PAIN, DIARR, VOMIT & SEV BURNS OF DIGEST TRACT.
SKIN:MAY CAUSE SERIOUS SKIN BURNS WHICH MIGHT NOT BE IMMED
APPARENT/PAINFUL. SYMP MAY BE DELAYED 8 HRS O R MORE. THE FLUORIDE
ION READILY PENETRATES SKIN CAUSING DESTRUCTION OF DEEP TISS LAYERS
& EVEN BONE.(EFTS OF OVEREXP)
Explanation of Carcinogenicity:COBALT: IARC MONOGRAPHS ON THE
GROUP 2B. (ING 7)
Effects of Overexposure:HLTH HAZ:EYE:MAY CAUSE REDNESS, PAIN & BLURRED
VISION. PERM EYE DMG MAY OCCUR. INHAL:MAY BE CORR TO RESP TRACT.
MAY CAUSE SORE THROAT, COUGHING, LABORED BRTHG & LUNG CONGESTION OR
INFLAMM. CHRONIC: IN GEST:CHRONIC INGEST OF COBALT CMPNDS MAY RSLT
IN HYPOTENSION, PERICARDIAL EFFUSION, POLYCARDIAL EFFUSION, (SUPP
DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS, EYE
PROBLEMS, IMPAIRED KIDNEY OR RESPIRATORY FUNCTION.
* First Aid Measures *
First Aid:INGEST:DO NOT INDUCE VOMIT. IF PATIENT IS CONSCIOUS, GIVE LRG
QTYS OF WATER/MILK. SEND TO HOSPITAL IMMED. SKIN:REMOVE CONTAM
CLTHG, FLOOD SKIN W/LARGE AMTS OF WATER. GET MED ATTN IMMED. EYE:
APART & AWAY FROM EYEBALLS. GET MED ATTN IMMED. INHAL:MOVE TO FRESH
AIR. IF PATIENT IS UNCONSCIOUS GIVE ARTF RESP. IF BRTHG IS DFCLT
(ING 8)
* Fire Fighting Measures *
Extinguishing Media:IF INVOLVED IN FIRE DO NOT USE WATER. USE CARBON
DIOXIDE, DRY CHEMICAL EXTINGUISHING AGENTS, DRY SAND, OR (SUPP
DATA)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . IF WITHOUT RISK REMOVE MATERIAL FROM FIRE
AREA.
Unusual Fire/Explosion Hazard:NOT COMBUST, BUT SUBSTANCE IS AN OXIDIZER
& ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTIBLES MAY CAUSE
IGNITION.
* Accidental Release Measures *
Spill Release Procedures:WEARING FULL PROTECTIVE EQUIPMENT, COVER SPILL
WITH DRY SAND OR VERMICULITE. MIX WELL AND CAREFULLY TRANSFER TO A
CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE ONLY IN APPROVED CONTAINERS
UNDER A DRY NITROGEN ATMOSPHERE. KEEP CONTAINER TIGHTLY CLOSED.
STORE IN A COOL, DRY, WELL-VENTILATED AREA.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:REACTS WITH WATER
Appearance and Odor:LIGHT BROWN POWDER; NO ODOR EXCEPT THE ODOR OF HF
IN MOIST AIR. (SUPP DATA)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AIR, MOISTURE, REDUCING AGENTS, ORGANIC MATERIALS, SILICON COMBUSTIBLS.
REACTS W/WATER TO FORM DECOM PRODS.(SUPP DATA)
Stability Condition to Avoid:INCOMPATIBLES, THERMAL DECOMPOSITION.
Hazardous Decomposition Products:HYDROGEN FLUORIDE, COBALT HYDROXIDE,
OXYGEN.
* Disposal Considerations *
Waste Disposal Methods:CONSULT STATE, LOCAL OR FEDERAL EPA REGULATIONS
FOR PROPER DISPOSAL. DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IN ABSENCE OF ADEQUATE VENTILATION, USE
NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN
.
Ventilation:LOCAL EXHAUST.
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:JOHN M. BIRSCH SR
* Composition/Information on Ingredients *
Ingred Name:PROPANE
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:ISOPARAFFIN SOLVENT; (C8-C9 ISOPARAFFIN) (MFR CAS#:
Fraction by Wt: 1-5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE TRANSIENT EYE PAIN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:EYES: FLUSH WITH PLENTY OF WATER WHILE REMOVING ANY CONTACT
LENSES, THEN HOLD EYELID OPEN AND CONTINUE FLUSHING FOR A MINIMUM
REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTF RESP) .
INGEST: CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:FOAM, DRY CHEMICAL, OR CO2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . KEEP CONTR COOL. USE SHIELDING TO PROTECT
PERS AGAINST BURSTING, RUPTURING OR VENTING CONTR.
CONTAINERS MAY VENT, RUPTURE OR BURST.
* Accidental Release Measures *
Spill Release Procedures:REMOVE SOURCE OF FLAME, SPARK OR HEAT. PROVIDE
ADEQUATE VENTILATION. WIPE UP SPILLS.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:CAUTION! CONTENTS UNDER PRESSURE. KEEP
OUT OF REACH OF CHILDREN. STORE IN A COOL DRY AREA. DO NOT STORE
Other Precautions:DO NOT INHALE. AVOID CONTACT WITH EYES & SKIN. READ
ENTIRE LABEL BEFORE USING.
* Physical/Chemical Properties *
HCC:F3
Evaporation Rate & Reference:<1 (ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:VISCOUS, WHITE LIQUID WITH MILD ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:OXIDES OR CARBON MAY BE FORMED UPON
COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:REPLACE CAP AND DISCARD CONTAINER IN TRASH. DO
NOT PUNCTURE OR INCINERATE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH
Ventilation:USE CLOSED SYSTEM HANDLING, LABORATORY BENCH HOOD OR LOCAL
EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:
EYE WASH STATION & SAFETY SHOWER, LAB COAT.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
PH OF 1-2% SOLUTION=8-8.2.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:LEUCOVORIN CALCIUM OR CALCIUM FOLINATE
Other REC Limits:5 MG/M3 (ACCO-TWA)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN AND EYE CONTACT MAY CAUSE
IRRITATION. INHALATION MAY CAUSE MILD RESPIRATORY TRACT IRRITATION.
INGESTION MAY CAUSE GI TRACT IRRITATION, RESPIRATORY DISTRESS. MAY
CAUSE ALLERGIC REACTIONS, IMPAIREDRENAL FUNCTION, CONGESTIVE
HEART FAILURE, HYPERNATREMIA.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INGESTION-NAUSEA, VOMITING, DIARRHEA, ABDOMINAL
CRAMPS, THIRST, TEARING, SWEATING, FEVER, HYPOTENSION, TACHYCARDIA,
RENAL FAILURE, PERIPHERAL & PULMONARY EDEMA, RESPIRATORY ARREST,
HEADACHE, DIZZINESS , RESTLESSNESS, IRRITABILIT, WEAKNESS, MUSCULAR
TWITCHING, RIGIDITY, CONVULSIONS, COMA, DEATH. SKIN/EYE-IRRITATION.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
IRRITATION PERSISTS. SKIN-WASH WITH SOAP & WATER. REMOVE
CONTAMINATED CLOTHES. SEE DOCTOR IF IRRITATION PERSISTS.
INHALED-REMOVE TO FRESH AIR. G IVE ARTIFICIAL RESPIRATION IF NOT
BREATHING; OXYGEN IF BREATHING DIFICULT. CALL A DOCTOR. INGESTED-DO
NOT INDUCE VOMITING UNLES DIRECTED BY DOCTOR. DO NOT INDUCE
VOMITING IF UNCONSCIOUS CALL A DOCTOR.
* Fire Fighting Measures *
Extinguishing Media:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: USE MEDIA
APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: WEAR
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
AND A DISPOSABLE DUST MASK OR APPROVED AIR-PURIFYING RESPIRATOR
WITH HIGH EFFICIENCY CARTRIDGES, CONTAIN AND COLLECT SPILLED
MATERIALS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
MINIMIZE EXCESS HANDLING. WASH HANDS, FACE, & EXPOSED BODY PARTS AT
LUNCH & AT BREAKS & AT THE END OF SHIFT.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:K2
Solubility in Water:APPRECIABLE
Appearance and Odor:BUFF YELLOW LYOPHILIZED CAKE OR POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT AVAILABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NOT AVAILABLE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:THIS IS NOT A RCRA-REGULATED WASTE. DISPOSE OF
IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL ENVIRONMENTAL
REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
------------------------------
% Wt: 2-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 2-5
------------------------------
% Wt: 2-6
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: <2
OSHA PEL: C 5 MG/M3 DUST
------------------------------
OSHA PEL: 1 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
OSHA PEL: 1 MG/M3
-----------------------------
% Wt: <2
------------------------------
% Wt: <2
------------------------------
% Wt: <2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: <3
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 3-8
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
WORK AREA, QTY & AMT OF VENT, POSITION
-----------------------------
CONTAM IN ATM (SUCH AS CHLORINATED
-----------------------------
ELECTRODE IS CONSUMED, FUME & GAS DECOMP
-----------------------------
LISTED IN SECTION 2. DECOMPS PRODS OF NORM
-----------------------------
MATLS SHOWN IN SECTION 2 PLUS
-----------------------------
FOR MORE SPECIFIC INFORMATION CONTACT NEHC (FP N).
-----------------------------
& ACHING OF BODY. RECOVERY IS
-----------------------------
W/CHROMIUM (VI) COMPOUNDS CAN CAUSE
-----------------------------
CHROMIUM (VI) SALTS CAN CAUSE SEV
-----------------------------
INFORMATION CONTACT NEHC (FP N).
-----------------------------
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ELECTRIC ARC WELDING MAY CREATE ONE/MORE OF FOLLOWING HLTH
HAZS: ARC RAYS CAN INJURE EYES & BURN SKIN. ELECTRIC SHOCK CAN KILL. SEE
SECTION 7. FUMES & GASES CAN BE DANGEROUS TO YOUR HLTH. ACUTE: WELDI NG
FUMES MAY RSLT IN DISCOMFORT SUCH ASDIZZ, NAUS/DRYNESS/IRRIT OF NOSE,
THROAT/EYES. ING 1: IRRIT OF (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NICKEL/NICKEL COMPOUND: IARC MONOGRAPHS ON THE
Signs And Symptions Of Overexposure: HLTH HAZ: RESP SYS. ING 2: FLUORIDE COMPDS
EVOLVED MAY CAUSE SKIN & EYE BURNS, PULM EDEMA & BRONCH. ING 2:
DUST/FUMES MAY CAUSE IRRIT OF RESP SYS, SKIN & EYES. ING 4: DUST MAY
CAUSE IRRIT OF RESP SYS, SKIN & EYES. ING 5: NONE ARE KNOWN. TREAT AS
NUISANCE DUST/FUMES. ING 6: METAL FUME FEVER CHARACTERIZED
Medical Cond Aggravated By Exposure: PERSONS WITH PRE-EXISTING IMPAIRED LUNG
FUNCTIONS (ASTHMA-LIKE CONDITION).
First Aid: CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY THE
AMERICAN RED CROSS. INGEST: CALL MD IMMEDIATELY (FP N). INHAL: REMOVE TO
FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) (FP N). EYES & SKIN:
IF IRRITATION OR FLASH BURNS DEVELOP AFTER EXPOSURE, CONSULT A PHYSICIAN.
ASSISTANCE FROM MD (FP N).
*
Handling and Disposal
*
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: PREVENT WASTE FROM CONTAMINANTING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER OR LINER IN
AN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH FEDERAL, STATE,
AND LOCAL REGULATIONS.
Handling And Storage Precautions: IMPORTANT:MAINTAIN EXPOS BELOW PEL/TLV. USE
INDUS HYGIENE MONITORING TO ASSURE THAT YOUR USE OF THIS MATL DOES NOT CREATE
EXPOS WHICH EXCEEDS PEL/TLV.
Other Precautions: ALWAYS USE EXHAUST VENTILATION. REFER TO THE FOLLOWING
*
Fire and Explosion Hazard Information
*
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: WELDING CONSUMABLES APPLIC TO THIS SHEET AS
SHIPPED ARE NONREACTIVE, NONFLAMMABLE, NONEXPLOSIVE & ESSENTIALLY NONHAZ
UNTIL WELDED. WELDING ARC & SPARKS (SUPDAT)
*
*
Respiratory Protection: USE NIOSH APPROVED OR EQUIVALENT FUME RESPIRATOR OR AIR
SUPPLIED RESPIRATOR WHEN WELDING IN CONFINED SPACE OR WHERE LOCAL EXHAUST OR
VENTILATION DOES NOT KEEP EXPOSURE BELOW PEL/TLV.
Ventilation: USE VENT TO KEEP FUMES & GASES < TLV. FOR MORE SPECIFIC
INFORMATION CONTACT NEHC (FP N).
Other Protective Equipment: ANSI APPRVD EMER EYE WASH & DELUGE SHOWER (FP N).
FOR MORE SPECIFIC INFORMATION CONTACT NEHC (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLO HAZ: CAN IGNITE COMBUST & FLAMM
DECOMP PROD: WELDED, PROCESS, PROC & ELECTRODES USED. OTHER CNDTNS WHICH
ALSO INFLUENCE C OMPOSITION & QTY OF FUMES & GASES TO WHICH WORKERS
MAY BE EXPOSED INCL: COATINGS ON METAL BEING WELDED (SUCH
*
Physical/Chemical Properties
*
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: WELDING FUMES & GASSES CANNOT BE CLASSIFIED
SIMPLY. COMPOSITION & QTY OF BOTH ARE DEPENDENT UPON METAL BEING (SUPDAT)
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: HOBART BROTHERS CO
Label Required IND: Y
Status Code: C
Origination
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYES OR SKIN: IRRITATION. INGESTION: SEVERE
INJURY OR DEATH. INHALATION: METAL FUME FEVER, IRRITATION, DIZZINESS, LUNG
DAMAGE. CHRONIC: CANCER HAZARD. CONTAINS NICKEL/NICKEL COMPOUNDS, WHICH IS
LISTED AS A HUMAN LUNG CARCINOGEN (FP N). SIDEROSIS, CNS EFFECTS.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE A NIOSH/MSHA APPROVED POSITIVE-PRESSURE,
SUPPLIED AIR RESPIRATOR WITH ESCAPE BOTTLE OR SELF-CONTAINED
BREATHING APPARATUS FOR GAS CONCENTRATIONS ABOVE OCCUPATIONAL
EXPOSURE LIMITS.
Ventilation:USE ADEQUATE VENTILATION AND EXPLOSION-PROOF EQUIPMENT AND
LIGHTING IN CLASSIFIED/CONTROLLED AREAS.
Other Protective Equipment:WEAR APRON.
Supplemental Safety and Health
* Product Identification *
Product ID:NATURAL GAS (ODORIZED)
* Composition/Information on Ingredients *
Ingred Name:METHANE
Ingred Name:ETHANE
Fraction by Wt: BALANCE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THIS PRODUCT IS A SIMPLE ASPHYXIANT.
IN HIGHT CONCENTRATION IT WILL DISPLACE OXYGEN FROM THE BREATHING
ATMOSPHERE, PARTICULARLY IN CONFINED SPACES. SIGNS OF ASPHYXIATION
IN SEVERAL STAGES.ON EYE OR SKIN CONTACT, NOT IRRITATING.
HOWEVER, CONTACT WITH PRESSURIZED VAPOR MAY CAUSE FROSTBITE, FREEZE
BURNS, AND PERMANENT EYE DAMAGE.
Explanation of Carcinogenicity:NONE LISTED.
Effects of Overexposure:A "CHILLY" FEELING, AND VOMITING HAVE BEEN
REPORTED FROM ACCIDENTAL EXPOSURE TO HIGH CONCENTRATIONS. SYMPTOMS
OF ASPHYXIATION MAY INCLUDE RAPID BREATHING AND PULSE RATE,
HEADACHE, DIZZINESS, VISUAL DI STURBANCES, MENTAL CONFUSION,
INCOORDINATION, MOOD CHANGES, MUSCULAR WEAKNESS, TREMORS, CYANOSIS,
NARCOSIS AND NUMBNESS OF THE EXTREMITIES.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
CONDITIONS OF THE HEART, LUNGS, AND BLOOD MAY HAVE INCREASED
SUSCEPTIBILITY TO SYMPTOMS OF ASPHYXIA.
* First Aid Measures *
First Aid:EYE: IN CASE OF FREEZE BURN COVER EYES TO PROTECT FROM LIGHT.
SEEK MEDICAL HELP. SKIN: IN CASE OF FROSTBITE OR FREEZE BURNS SEEK
MEDICAL HELP. INGEST: UNLIKELY. INHALE: REMOVE PERSON TO FRESH AIR.
IFPERSON IS NOT BREATHING, PROVIDE ARTIFICIAL RESPIRATION. IF
NECESSARY, PROVIDE ADDITIONAL OXYGEN ONCE BREATHING IS RESTORED IF
TRAINED TO DO SO. SEEK MEDICAL HELP.
* Fire Fighting Measures *
Flash Point:FLAMMABLE GAS
Lower Limits:3.8-6.5%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON OR WATER.
HOWEVER, FIRE SHOULD NOT BE EXTINGUISHED UNLESS FLOW OF GAS CAN BE
IMMERDIATELY STOPPED.
Fire Fighting Procedures:GAS FIRES SHOULD NOT BE EXTINGUISHED UNLESS
FLOW OF GAS CAN BE IMMEDIATELY STOPPED. SHUT OFF GAS SOURCE AND
ALLOW GAS TO BURN OUT. IF SPILL OR LEAK HAS NOT IGNITED, DETERMINE
IF WATER SPRAY MAY ASSIST IN DISPERSING GS OR VAPOR TO PROTECT
PERSONNEL ATTEMPTING TO STOP LEAK.
Unusual Fire/Explosion Hazard:NATURAL GS IS LIGHTER THAN AIR AND MAY
TRAVEL LONG DISTANCES TO A POINT OF IGNITION AND FLASH
BACK.CONTAINERS MAY EXPLODE IN HEAT OR FIRE.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE NONESSENTIAL PERSONNEL AND SECURE ALL
IGNITION SOURCES. NO ROAD FLARES, SMOKING OR FLAMES IN HAZARD AREA.
STAY UPWIND IF POSSIBLE. STOP SOURCE OF THE RELEASE IF SAFE TO DO
SO. CONSIDER THE US E OF WATER SPRAY TO DISPERSE VAPORS. ISOLATE
THE AREA UNTIL GAS HAS DISPERSED. VENTILATE AND GAS TEST AREA
BEFORE ENTERING.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM FLAMES, SPARKS AND
EXCESSIVE TEMPERATURES. STORE ONLY IN APPROVED CONTAINERS. BOND AND
GROUND CONTAINERS. USE ONLY IN WELL VENTILATED AREAS.
* Physical/Chemical Properties *
HCC:G2
Vapor Density:0.6
Spec Gravity:0.4
Solubility in Water:3.5%
Appearance and Odor:COLORLESS GAS. A DISTINCTIVE, DISAGREEABLE "NATURAL
GAS" TYPE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:KEEP AWAY FROM STRONG OXIDIZERS, IGNITION
SOURCES AND HEAT.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
NON-COMBUSTED HYDROCARBONS.
* Toxicological Information*
Toxicological Information:METHANE AND ETHANE, THE MAIN COMPONENTS OF
NATURAL GAS, ARE CONSIDERED PARCTICALLY INERT IN TERMS OF
PHYSIOLOGICAL EFFECTS. AT HIGH CONCENTRATIONS THESE MATERIALS ACT
AS SIMPLE ASPHYXIANTS AND MAY CAU SE DEATH DUE TO LACK OF OXYGEN.
* Ecological Information *
Ecological:THIS PRODUCT IS EXPECTED TO EXIST ENTIRELY IN THE VAPOR
PHASE IN AMBIENT AIR.
* Disposal Considerations *
Waste Disposal Methods:CONSULT FEDERAL, STATE AND LOCAL WASTE
REGULATIONS TO DETERMINE APPROPRIATE WASTE CHARACTERIZATION OF
MATERIAL AND ALLOWABLE DISPOSAL METHODS.
* MSDS Transport Information *
Transport Information:DOT: NATURAL GAS, COMPRESSED, HAZARD CLASS 2.1,
* Regulatory Information *
Federal Regulatory Information:THIS PRODUCT AND ITS CONSTITIENTS LISTED
HEREIN ARE ON THE EPA TSCA INVENTORY. ANY SPILL OR UNCONTROLLED
RELEASE OF THIS PRODUCT, INCLUDING ANY SUBSTANTIAL THREAT OF
RELEASE, MAY BE SUBJECT TO FEDERAL , STATE AND/OR LOCAL REPORTING
REQUIREMENTS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:AS REQUIRED
Supplemental Safety and Health
* Product Identification *
Product ID:DEAD LEVEL ASPHALT
CAGE:0FUJ8
CAGE:0FUJ8
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: HOT ASPHALT FUMES MAY
PRODUCE NAUSEA & IRRITATION OF UPPER RESPIRATORY TRACT. SKIN
CONTACT & EYE CONTACT W/HOT ASPHALT WILL RESULT IN THERMAL BURNS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: NAUSEA, DIZZINESS, UPPER
RESPIRATORY TRACT IRRITATION. SKIN/EYES: BURNS.
* First Aid Measures *
First Aid:SKIN/EYES: COOL AFFECTED AREAS W/WATER. INHALATION: REMOVE TO
FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE PROPER BREATHING EQUIPMENT IN CONFINED
SPACES.
Unusual Fire/Explosion Hazard:CAUTION SHOULD BE USED IN APPLYING WATER
TO HOT ASPHALT, THIS MAY CREATE A BOIL OVER OR FROTHING AFFECT BY
THE ASPHALT.
* Accidental Release Measures *
Spill Release Procedures:IF POSSIBLE COOL & SOLIDIFY. SAND, DRY DIRT OR
AN ABSORBENT CAN BE PLACED ON SPILL.
*Handling and Storage *
Handling and Storage Precautions:PRODUCT SHOULD BE STORED, TRANSPORTED
& DISTRIBUTED IN A CLEAN, DRY & UNCONTAMINATED TANK. AVOID CONTACT
W/HOT ASPHALT.
Other Precautions:USE MINERAL SPIRITS OR MINERAL OIL TO REMOVE FROM
SKIN. USE NO SOLVENTS. USE CAUTION WHEN APPLYING WATER TO HOT
ASPHALT.
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:SEE SUPP
Solubility in Water:INSOLUBLE
Appearance and Odor:ODORLESS; BLACK SIMI SOLID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:LANDFILL IN ACCORDANCE W/LOCAL, STATE, & FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED A NIOSH APPRVD FULL FACEPIECE
USE CONC SPECIFIED BY THE RESP SUPPLIER, WHICHEVER IS LESS.
ALTERNATIVELY, A NIOSH AP PROVED SUPPLIED AIR (SUPDAT)
Ventilation:A SYS OF LOCAL &/GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
BELOW THE AIRBORNE EXPOS LIMS. LOC EXHST VENT IS (SUPDAT)
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB COAT, APRON OR (ING 4)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:OXALIC ACID
OSHA PEL:1 MG/M3
Ingred Name:SUPDAT:PREVENTING DISPERSION OF IT INTO THE GENERAL WORK
AREA. PLEASE REFER TO THE ACGIH DOCUMENT, INDUSTRIAL (ING 3)
Ingred Name:ING 2:VENTILATION, A MANUAL OF RECOMMENDED PRACTICES, MOST
RECENT EDITION FOR DETAILS.
Ingred Name:OTHER PROT EQUIP:COVERALLS TO PREVENT SKIN CONTACT.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:INHAL OF MIST/VAP MAY
CAUSE IRRIT TO MUC MEM OF THE RESP TRACT. INGEST:CORR TOX. MAY
CAUSE BURNS OF THE MOUTH & ESOPHAGUS, NAUS, GASTROENTERITIS &
SHOCK. ABSORPTION CAN OCCUR CAUSING SYSTE MEMIC POISONING. SYMPS
MAY INCL HDCH, WEAK PULSE, & MUSC CRAMPS. MAY CAUSE KIDNEY DMG.
SEVERE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:POISONING MAY BE FATAL. SKIN CNTCT:AN
IRRITANT TO THE SKIN. MAY CAUSE REDNESS, PAIN, & BURNS TO THE SKIN.
EYE CNTCT:SPLASHES MAY CAUSE SEVERE IRRIT & POSSIBLE EYE DAMAGE.
CHRONIC:PROLONGED IN HAL OF MIST MAY CAUSE INFLAMMATION OF UPPER
RESP TRACT. SKIN CONTACT MAY CAUSE DERMATITIS. MAY CAUSE KIDNEY
DAMAGE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS OR IMPAIRED LIVER OR KIDNEY FUNCTION MAY
BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. GET MED ATTN FOR ANY BRTHG
DIFFICULTY. INGEST:IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE LRG
QTIES OF H*2O/MILK IF AVAIL. CALL A MD IMMED. NEVER GIVE ANYTHING
BY MOUTH TO AN UN CON PERSON. SKIN EXPOS:IN CASE OF CNTCT, IMMED
CONTAMD CLTHG & SHOES. WASH CLTHG BEFORE REUSE. CALL A MD IMMED.
EYE EXPOS: (SUPDAT)
* Fire Fighting Measures *
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED
CONTAINERS COOL.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENT AREA OF LEAK/SPILL. CLEAN-UP PERS REQ
PROT CLTHG & RESP PROT FROM VAPS. CONTAIN & RECOVER LIQ WHEN POSS.
ABSORB W/VERMICULITE, DRY SAND, EARTH/SIMILAR MATL. SCOOP UP
W/NON-SPARKING TOOLS & PLACE IN CLSD CNTNR, & DISPOSE OF IN A RCRA
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN A TIGHTLY CLSD CNTNR. PROT
FROM PHYSICAL DMG. STORE IN A COOL, DRY, VENTILATED AREA AWAY FROM
SOURCES OF HEAT, MOISTURE & INCOMPATIBILITIES.
Other Precautions:PROTECT FROM FREEZING. CONTACT LENSES SHOULD NOT BE
WORN WHEN WORKING WITH THIS MATERIAL. AVOID CONTACT W/EYES, SKIN
AND CLOTHING.
LOWER & UPPER EYELIDS OCCAS. GET MED ATTN IMMED. SPILL PROC:APPRVD
FACILITY. RESP PROT:FULL FACEPIECE RESP/NIOSH APPRVD AIRLINED HOOD
MAY BE WORN. VENT:GENERALLY PREFERRED BECAUSE IT CAN CONTROL THE
EMISSIONS OF THE CONTAM AT ITS SOURCE, (ING 2)
* Physical/Chemical Properties *
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS SOLUTION; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
STRONG OXIDIZERS, SILVER, SODIUM CHLORITE, SODIUM HYPOCHLORITE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION EMITS
TOXIC FUMES OF CARBON MONOXIDE OR FORMIC ACID.
* Disposal Considerations *
Waste Disposal Methods:ENSURE COMPLIANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
Preparer's Name:A.S.
* Composition/Information on Ingredients *
Ingred Name:LEAD DIOXIDE
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:LEAD DIOXIDE THOROUGHLY/PERMANENTLY
WETTED, & DOESN'T PRESENT RISK OF EXPOS TO DUST PARTICLE. INORGANIC
LEAD COMPND TOXIC BY INGESTION, ALTHOUGH NOT READILY ABSORBED.
ANEMIA/CENTRAL NERV SYS EFFECTS/A BDOM COLIC/KIDNEY FUNCTION LOSS
* First Aid Measures *
First Aid:EYES: IMMEDIATELY FLUSH WITH WATER. IF IRRITATION PERSISTS,
CONSULT A PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER.
INHALATION: NOT APPLICABLE. INGESTION: CONSULT A PHYSICIAN.
* Fire Fighting Measures *
Flash Point:NOT FLAMMABLE
Extinguishing Media:WATER
Unusual Fire/Explosion Hazard:OXIDIZER
* Accidental Release Measures *
Spill Release Procedures:SCOOP UP SPILLED MATERIAL. CLEAN UP RESIDUE
WITH RAGS AND NON-FLAMMABLE SOLVENT.
*Handling and Storage *
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING AND
BEFORE SMOKING OR EATING. AVOID INGESTION.
Other Precautions:THIS PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS
* Physical/Chemical Properties *
HCC:D1
Spec Gravity:2.6
Solubility in Water:NEGLIGIBLE
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:SMOKE, SOOT, CARBON MONOXIDE, CARBON
DIOXIDE, LEAD COMPOUNDS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN COMPLIANCE WITH FEDERAL AND STATE
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN EXPOSURES BELOW
PEL(TLV) LIMITS USE MSHA/NIOSH UNITS. IF WITHIN OSHA PROTECTION
FACTOR AIR PURIFYING OV/FILTER UNITS ARE OKAY.
Ventilation:PROVIDE SUFFICIENT GENERAL/LOCAL EXHAUST VENT IN
VOL/PATTERNTO CONTROL INHALATION EXPOSURES BELOW CURRENT LIMITS.
Other Protective Equipment:WEAR INDUSTRIAL-TYPE WORK CLOTHING, SAFETY
FOOTWEAR, PROTECTGARMENTS HEAD/NECK, APRONS, JACKETS, PANTS,
COVERALLS, BOOTS
Work Hygienic Practices:WASH EXPOSED AREA PROMPTLY, THOROUGHLY AFTER
CONTACT, BEFOREEATING, DRINKING, USING TOBACCO PRODUCTS OR
RESTROOMS.
Supplemental Safety and Health
NOTE TO PHYSICIAN: THERE IS NO SPECIFIC ANTIDOTE FOR EFFECTS FROM OVER
EXPOSURE TO THIS MATERIAL. TREATMENT SHOULD BE DIRECTED AT THE
CONTROL OF SYMPTOMS AND THE CLINICAL CONDITION.
* Product Identification *
Kit Part:Y
Preparer's Name:C. A. HOPE
* Composition/Information on Ingredients *
Ingred Name:TOLUENE (SARA III)
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
Ingred Name:N-PROPYL ALCOHOL
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: PROLONGED
EXPOSURE MAY CAUSE DEFATTING OF SKIN, REDNESS,CRACKING, BLISTERING,
IRRIT & DERMATITIS. MAY BE ABSORBED THROUGH THE SKIN, MAY CAUSE
ADVERSE EFFECTS. INHALE: RESPIR SY STEM IRRIT NERV SYS DEPRESS,
LIVER, KID-NEY. INGEST: VOMIT, GASTRO DISTRUB, ASPIRATION INTO
LUNGS MAY BE HARMFUL/FATAL.
Explanation of Carcinogenicity:NO KNOWN INGREDIENTS WHICH OCCUR AT
GREATER THAN 0.1% ARE LISTED AS A CARCINOGENS.
Effects of Overexposure:EYE: IRRIT SKIN: IRRIT RED, CRACKING, BLISTER,
DERMATITIS. INHALE: RESPIR IRRIT HEADACHE, WEAKNESS, DIZZINESS,
INCOORDINATION, POSSIBLE COLLAPSE, INGEST: GASTRODISTURBANCES,
CENTRAL NERVOUS SYSTEM DEP RESSION, NAUSEA, VOMITING, DIARRHEA,
IFASPIRATION INTO THE LUNGS CAN BE HARMFUL AND/OR FATAL.
Medical Cond Aggravated by Exposure:AILMENTS OF SKIN, RESPIRATORY
TRACT, LIVER, KIDNEYCENTRAL NERV SYSTEM PEOPLE W/PRE-EXISTING
DISEASE OR MORE SENSITIZIED THAN OTHERS MAY BE PRONE TO THESE AND
OTHER ADVERSE EFFECTS WHEN EXPOSED.
* First Aid Measures *
MINUTES. SEEK MEDICAL AID.SKIN: WASH THOROUGHLY W/SOAP/WATER. IF
RED-ITCHING, BURNING, SYMPTOMS PERSIST SEEK MED. ATTN. INGEST: DO
ACTIVATED CHARCOAL IN WATER TO VICTIM AS TOLERATED. SEEK
MEDATTENTION: DO NOT ATTEMPT TO GIVE ANYTHING TO UNCONSCIOUS
PERSON.
* Fire Fighting Measures *
Extinguishing Media:USE CARBON DIOXIDE, DRY CHEMICAL/FOAM PER MFG
RECOMMENDATIONWATER SPRAY MAY BE INEFFECTIVE, BUT USED TO COOL
CONTAINERS.
Fire Fighting Procedures:WEAR COMPLETE FIRE SERVICE PROTECTIVE
EQUIPMENT, INCLUDING FULL-FACE MSHA/NIOSH APPROVED SELF-CONTAINED
BREATHING APPARATUS. USE WATER TO COOL FIRE-EXPOSE CONTR
Unusual Fire/Explosion Hazard:VAPORS FORM FLAMMABLE EXPLOSIVE MIXTURES
IN AIR, MAY TRAVEL AT GROUND LEVEL TO IGNITION SOURCE-FLASH.
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. STAY UPWIND.
TAKEUPSMALL SPILLS W/SAND/NONCOMBUSTIBLE ABSORBENT MATERIAL. FLUSH
AREA W/WATER, FOR LRG-SPILL DIKE,CONTN RUNOFF FROM FIRE, DILUTION
OF WATER, IF RELEASED INTO ENVIRNT, WATER SOURCES, CALL:
*Handling and Storage *
Handling and Storage Precautions:AVOID PROLONGED OR REPEATED CONTACT,
Other Precautions:GROUND AND BOND DRUMS. DON'T USE PRESSURE TO EMPTY
DRUMS. WASH SELF AND CLOTHINGONCE CONTAMINATED. DISCARD CONTAM
FOOTWEAR. THIS IS A FLAMMABLE LIQUID-KEEP AWAYFROM HEAT AND OPEN
FLAME, MAY EMIT IRRIT ATING TOXIC GAS AND/OR FUMES.
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Density:>1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID WITH A TYPICAL SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID OXIDIZING AGENTS, HEAT, SPARKS AND OPEN FLAMES
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE
UPON THERMAL DECOMPOSI- TION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:LOCAL EXHAUST OR BREATHING PROTECTION(DUST
FILTER RESPIR)
Ventilation:GEN/LOCAL EXHAUST.AVOID DUSTING CONDITIONS
Other Protective Equipment:EMERG:AIR LINE/SELF-CNTND BRTHG APP;FULL
PROTECT CLOTHNG,BOO
Supplemental Safety and Health
FIRST AID CONT:USE AMYL NITRATE BEFORE/AFTER INDUCE VOMIT(SEE
INHALE).REPEAT AMYL NITRATE AT 3MIN INTERVALS UNTIL USED 4
* Product Identification *
Product ID:POTASSIUM CYANIDE
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM CYANIDE (SARA III)
OSHA PEL:5 MG/M3 (CN)
* Hazards Identification *
Effects of Overexposure:HIGHLY
TOXIC.EYES/SKIN:IRRITNT.INHALE/INGEST:PAIN,FAINTNESS,HARD
BREATHING,UNCONSCIOUS,RAPID FATAL
* First Aid Measures *
MOUTH,DRINK PINT 1%SODIUM THIOSULFATE SOLN(OR SOAPY OR MUSTARD
H*2O),INDUCE VOMIT,REPEAT VOMIT UNTIL CLEAR:CONT IN SUPP DATA
* Fire Fighting Measures *
Extinguishing Media:NOT COMBUSTIBLE;USE AIR FOAM OR WATER FOG FOR NEAR
BY FIRE.
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP.DONT USE H*2O ON
MATERIAL ITSELF.
Unusual Fire/Explosion Hazard:HEAT LIBERATES FLAMMABLE HCN
GAS(TOXIC).KNOCK VAPOR DOWN W H*2O SPRAY.DO NOT SEWER.SEE AVOID
INFO
* Accidental Release Measures *
Spill Release Procedures:EVACUATE UNPROTECTED PERSONS.ELIM IGNITION
SOURCES.PROTECTED PERSONNEL STOP LEAK,PROVIDE
VENTILATION,SWEEP/SHOVEL MATERIAL INTO COVERED
CONTAINER.DECONTAMINATE SPILL AREA W SODIUM OR CALCIUM HYPOCHLOR
ITE SOLUTION.DIKE/PREVENT SEWER OF KCN SOLN.
*Handling and Storage *
Handling and Storage Precautions:STRICT HYGIENE;PROHIBIT ANY DIRECT
CONTACT W CHEMICAL.SEE AVOID.STORE IN COOL,DRY,WELL VENT,LOW FIRE
RISK AREA.CONT TIGHTLY CLOSED.NO FOOD EXPOSE.
Other Precautions:NOTE:REQUIRE SAFETY TRAINING/SUPPLIES BEFORE PRODUCT
USE.ENFORCE STRICT HYGIENE.ABSORBS H*2O FROM AIR & SLOWLY
DECOMPOSES.DO NOT SEWER;MAY RELEASE
PEARLS.EYES/SKIN;FLUSH W LG AMTS H*2O.ALL CASES:GET PHYSICIAN
IMMED.
* Physical/Chemical Properties *
HCC:T2
Evaporation Rate & Reference:NIL
Solubility in Water:COMPLETE
Appearance and Odor:WHITE, GRANULAR, ODORLESS
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALL ACIDS,OXIDANTS,WEAK ALKALIES.
Stability Condition to Avoid:CONTACT W ACIDS,WEAK ALKALIES,HI
HEAT,FIRE,WATER,ACID FUMES
Hazardous Decomposition Products:HCN GAS(POISON,FLAMMABLE)ALSO TOXIC
NITROGEN OXIDES VIA FIRE
Conditions to Avoid Polymerization:ACID CNTCT
* Disposal Considerations *
Waste Disposal Methods:KEEP IN COVERED DRUMS PENDING DISPOSAL.IF
APPROVED,MAY NEUTRALIZE W SODIUM OR CALCIUM HYPOCHLORITE OR
HYDROGEN PEROXIDE.DISPOSE INLY IN FULL COMPLIANCE WITH APPLICABLE
INTERNATIONAL,FEDERAL,STATE,& LO CAL REGS.W FULL PERSONNEL
PROTECTION.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE RESPIRATORY PROTECTION IS REQUIRED. USE
PARTICLES BY SPRAYING/ABRA DING SANDING PAINTED SURFACES.
Ventilation:DILUTION VENTILATON/LOCAL EXHAUST TO PREVENT BUILDUP OF
VAPORS. USE EXPLOSION PROOF EQUIPMENT/NON-SPARKING TOOLS.
Other Protective Equipment:EYE WASH, IMPERVIOUS CLOTHING, APRON, BOOTS,
SAFETY SHOWER.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING/SMOKING.
Supplemental Safety and Health
FIRE HAZ CONT'D: VAPORS MAY IGNITE EXPLOSIVELY AT AMBIENT TEMPS. HEALTH
HAZ CONT'D: REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANENT BRAIN/NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY I
NHALING THE CONTENTS MAY BE HARMFUL/FATAL. MAY CAUSE NEONATAL
EFFECTS. SPILL: RINSE WATER OUT OF SEWERS & WATERCOURSES.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:HYDROCARBON PROPELLANT, PETROLEUM GASES LIQUIFIED
Ingred Name:BENZENE (HUMAN CARCINOGEN BY IARC GROUP 1, OSHA, NTP &
OSHA PEL:1 PPM
ACGIH TLV:0.5 MG/CUM (A1)
Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS
Fraction by Wt: 0.1-1%
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/CUM
ACGIH TLV:3.5 MG/CUM
Fraction by Wt: 1-5%
Fraction by Wt: 1-5%
Fraction by Wt: 1-5%
Other REC Limits:5 MG/M3 RESP DUST
Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM
Fraction by Wt: 1-5%
OSHA PEL:2 MG/CUM (RESP DUST)
ACGIH TLV:2 MG/CUM (RESP DUST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: IRRITATION OF RESPIRATORY
TRACT/MUCOUS MEMBRANE. CNS DEPRESSION/ANESTHETIC EFFECT. MAY CAUSE
BLOOD ABNORMALITIES, DAMAGE TO LIVER/KIDNEY/RESPIRATORY
FAILURE/DEATH. SKIN: IRRITATION/DERMATI TIS. EYES: SEVERE
IRRITANT/CORNEAL INJURY. INGESTION: LUNG INFLAMMATION/DAMAGE DUE TO
ASPIRATION. SKIN ABSORPTION. (SUPP
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of
Overexposure:IRRITATION/FATIGUE/DROWSINESS/DIZZINESS/LIGHTHEADEDNES
S/HEADACHE/UNCOORDINATION/NAUSEA/VOMITING/ABDOMINAL
PAIN/COUGHING/DIFFICULTY W/SPEECH/W/BREATHING/RESPIRATORY
PROBLEMS/INTOXICATION/TIGHTNESS IN C HEST/CONFUSION/NARCOSIS/LOSS
OF CONSCIOUSNESS/ASPHYXIATION/DEFATTING/BLISTERING OF SKIN/BLURRED
VISION/TEARING/REDNESS
Medical Cond Aggravated by Exposure:EYE/SKIN/RESPIRATORY DISORDERS.
DISORDERS OF THE KIDNEYS, LIVER. CARDIAC ABNORMALITIES. ASTHMA-LIKE
CONDITIONS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT BREATHING.
HAVE TRAINED PERSON GIVE OXYGEN. SKIN: FLUSH W/WATER. WASH
THOROUGHLY W/SOAP & WATER. EYES: FLUSH IMMEDIATELY W/LARGE AMOUNTS
* Fire Fighting Measures *
Flash Point Method:SCC
Flash Point:1F
Lower Limits:2.5
Extinguishing Media:DRY CHEMICAL/FOAM, WATER FOG, CO2
Fire Fighting Procedures:WATER MAY BE USED TO COOL & PROTECT EXPOSED
CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE/BURST WHEN
EXPOSED TO EXTREME HEAT/FIRE. VAPORS >AIR TRAVEL DISTANCES TO
IGNITION SOURCES/FLASHBACK. MAY EMIT TOXIC GASES. (SUPP)
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE IGNITION SOURCES. EVACUATE,
VENTILATE AREA W/EXPLOSION PROOF EQUIPMENT. COLLECT W/ABSORBENT
MATERIAL USING NON-SPARKING TOOLS. PLACE MATERIAL IN CONTAINERS.
LARGE: SHUT OFF LEAK SAFELY. DIKE /CONTAIN. PUMP TO STORAGE/SALVAGE
VESSELS. (SUPP)
*Handling and Storage *
IGNITION SOURCES. USE ONLY W/ADEQUATE VENTILATION. KEEP CONTAINERS
TIGHTLY CLOSED & UPRIGHT WHEN NOT IN USE.
Other Precautions:KEEP OUT OF CHILDRENS REACH. DON'T TAKE INTERNALLY.
AVOID CONTACT W/SKIN & EYES & BREATHING OF VAPORS. EMPTY CONTAINERS
MAY CONTAIN HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN TRANSFERRING
TO PREVENT AC CUMULATION OF STATIC CHARGE.
* Physical/Chemical Properties *
Appearance and Odor:AEROSOL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, AMINES, NITRIC ACID, VINYL POLYMERS
Stability Condition to Avoid:EXTREME HEAT/FIRE, AMBIENT TEMPS, SPARKS,
OPEN FLAME, ELEVATED TEMPS & OTHER IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
Waste Disposal Methods:AVOID DISCHARGE TO NATURAL WATERS. DISPOSE OF IN
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE WITH NORMAL USE. NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:PRODUCT SHOULD BE USED WITH ADEQUATE LOC EXHST VENTILATION
SUFFICIENT TO MAINTAIN EXPOSURES BELOW APPLICABLE LIMITS.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING.
Supplemental Safety and Health
EXPLO HAZ:GROUND TO OTHER LOCATIONS. VAPORS CAN BE IGNITED BY SPARKS OR
FLAMES AT LOCATIONS FAR REMOVED FROM HANDLING LOCATION. HAZ DECOMP
PRODS:METHACRYLATE, ETHYL ACRYLATE, NOX. EFTS OF OVEREXP:PROD UCING
EFTS OF SYSTEMIC TOX. NIOSH RECOMMENDS THAT 2-ETHOXY ETHYL ACETATE
BE REGARDED IN WORKPLACE AS HAVING (ING 8)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ING 6:IN PLASTIC BOTTLE & SHAKE WELL. GIVE 5 MG/KG (2.3
Ingred Name:SUPP DATA:POTENTIAL TO CAUSE ADVERSE REPRODUCTIVE EFFECTS
IN MALE AND FEMALE WORKERS .
Ingred Name:ACETIC ACID, BUTYL ESTER;; (BUTYL ACETATE)
Ingred Name:ETHANOL, 2-ETHOXY-, ACETATE; (ETHYLENE GLYCOL MONOETHYL
ETHER ACETATE)
ACGIH TLV:5 PPM, S
Ingred Name:PHTHALLIC ACID, DIBUTYL ESTER; (DIBUTYL PHTHALATE)(SARA
III)
Fraction by Wt: <3%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:SILVER; (SILVER, METALLIC)
ACGIH TLV:0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ACRYLIC RESINS
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:FIRST AID PROC:TO MD:TO PREPARE ACTIVATED CHARCOAL SLURRY
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MOD TO SEV SKIN IRRIT. CORR TO SKIN.
MOD TO SEV EYE IRRIT. IRRIT TO MUCOSAL SURF. BLOOD SYS EFTS.
NON-SPECIFIC EFTS (E. G., WEIGHT LOSS & IRRIT). CNS EFTS, REDUCED
SPERMATOGENS. LIVER EFTS, TESTICULAR EFTS, KIDNEY EFTS. TESTING IN
ANIMALS HAS SHOWN:EMBRYOTIXIC ACTIVITY,MUTAGENIC ACTIVITY IN
BACTERIAL (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:OR MAMMALIAN CELL CULTURES, REPRO
ACTIVITY. HUMAN HLTH EFTS INCLUDE:SKIN IRRIT W/DISCOMFORT/RASH, EYE
IRRIT W/DISCOMFORT, TEARING/BLURRING OF VISION, NON SPECIFIC
DISCOMFORT (E.G., NAUS, HDCH /WEAKNESS), IRRIT OR UPPER RESP
PASSAGES. CHRONIC:ARGYRIA. SKIN PERMEATION CAN OCCUR IN AMTS
CAPABLE OF (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:SKIN:IMMEDIATELY WASH W/SOAP & PLENTY OF WATER. EYE:IMMED
INHAL:MOVE TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF RESP, PREF
MOUTH TO MOUTH. IF BRTHG DFCLT, GIVE O2. CALL MD. INGEST:DO NOT
INDUCE VOMIT. IMMED GIVE 2 GLASSES OF WATER OR ACTIVATED CHARCOAL
SLURRY. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. CALL MD IMMED.
NOTE (ING 6)
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.7%
Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . AVOID CONTACT WITH BURNING MATERIAL. AT
ELEVATED TEMPS, TOX FUMES OR VAPORS MAY BE FORMED.
Unusual Fire/Explosion Hazard:KEEP AWAY FROM SPARKS & OPEN FLAMES. DO
NOT SMOKE OR PERMIT OTHERS TO DO SO. VAPS ARE HEAVIER THAN AIR &
MAY COLLECT IN DEPRESSIONS & TRAVEL ALONG (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:AVOID PROLONGED CONTACT WITH SKIN AND
BREATHING OF VAPOR. REMOVE IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE PRODUCT IN COOL, DRY LOCATION.
DO NOT STORE FLAMMABLE MATERIALS IN AREAS WHERE VAPS MAY COME INTO
CONTACT WITH FLAMES, SPARKS, OR HEAT.
STABILITY. OBSERVE LABEL PRECAUTIONS.
* Physical/Chemical Properties *
HCC:F4
Evaporation Rate & Reference:1 (BUTYL ACETATE=1)
Solubility in Water:SLIGHT
Appearance and Odor:GREY LIQUID WITH MILD FRUITY ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZING AGENTS, POTASSIUM TERT-BUTOXIDE, BASES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AT ELEVATED TEMPERATURES, VAPORS OR
CONDEDSED VAPORS OF FOLLOWING MAY BE PRODUCED:C/COX, WATER VAP,
METHYL (SUPP DATA)
* Disposal Considerations *
Waste Disposal Methods:WIPE UP WITH RAGS OR OTHER ABSORBENT MATERIAL OR
ABSORB WITH SAND. CONSULT APPLICABLE FEDERAL, STATE AND LOCAL
REGULATIONS FOR ALLOWABLE DISPOSAL METHODS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED DUST RESPIRATOR IF TLV
IS EXCEEDED. DO NOT BREATHE DUST.
Ventilation:WORK AREAS SHOULD BE WELL VENTILATED TO MINIMIZE THE
POSSIBILITY OF EXCEEDING TLV LEVELS.
Other Protective Equipment:LOOSE-FITTING CLOTHING.
Work Hygienic Practices:WASH AFTER HANDLING. LAUNDER WORK CLOTHES
SEPARATELY AND CLEAN WASHER AFTER USE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:FBX LOOSE GRANULATED WOOL
* Composition/Information on Ingredients *
Ingred Name:MINERAL FIBERS; (VITREOUS MINERAL FIBER)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: FIBERS AND DUST FROM HANDLING
PRODUCT MAY CAUSE TRANSITORY IRRITATION OR RASH TO SKIN, EYES OR
RESPIRATORY TRACT. CHRONIC: NO CHRONIC EFFECTS ARE KNOWN. THIS MSDS
WILL BE UPDATED AS NEW MEDICAL FINDINGS ARE PUBLISHED.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
IF IRRITATION CONTINUES, CONSULT MD. SKIN: WASH PARTICLES FROM SKIN
WITH SOAP AND WATER. DO NOT RUB. IF IRRITATION PERSISTS, CONSULT
MD. INH AL: REMOVE TO FRESH AIR. INGEST: CONSULT MD.
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:NONFLAMMABLE
Upper Limits:NONFLAMMABLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:USE VACUUM OR WET CLEANUP PROCEDURES TO
MINIMIZE AIRBORNE DUST.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE TO GRAY, NEGLIGIBLE.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, STRONG ALKALIS.
Stability Condition to Avoid:
Hazardous Decomposition Products:EMITS NORMAL COMBUSTION PRODUCTS (E.G.
CO & CO2) IF EXPOSED TO FIRE OR HIGH TEMPERATURES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE TO SOLID WASTE LANDFILL IN ACCORDANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS OR CHEMICAL CARTRIDGE.
Ventilation:LOCAL EXHAUST: FUMEHOOD TO MEET TLV REQUIREMENTS. SPECIAL:
CANCER INDICATIONS.
Other Protective Equipment:PROTECTIVE CLOTHING. PROVIDE SAFETY SHOWERS
AND EYEWASH STATION NEAR WORKPLACE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
% VOLAT: SIGNIFICANT, SUBLIMES.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NAPHTHALENE; (NAPHTHENE) (TAR CAMPHOR) (SARA III)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NAUSEA, VOMITING, FEVER, CONVULSIONS,
COMA, LIVER DAMAGE, CANCER INDICATIONS, IRRITATION (EYE), HEMOLYTIC
AGENT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MINUTES. INHAL: REMOVE TO FRESH AIR, ARTIFICIAL RESPIRATION OR
OXYGEN IF NECESSARY. INGEST: GIVE WATER AND INDUCE VOMITING. ALL
EXPOSURES:SUMMON MD.
* Fire Fighting Measures *
Flash Point Method:OC
Lower Limits:0.9%
Upper Limits:5.9%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:COMBUSTIBLE, CANCER INDICATIONS.
* Accidental Release Measures *
Spill Release Procedures:PROVIDE ADEQUATE IGNITION PROOF VENTILATION.
CAREFULLY SCOOP UP AND TRANSFER TO A CLOSED CONTAINER. REMOVE ALL
HEAT AND IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:PROTECT FROM LIGHT. PROTECT FROM HEAT
AND IGNITION SOURCES.
Other Precautions:USE WITH ADEQUATE VENTILATION.
* Physical/Chemical Properties *
HCC:F8
Solubility in Water:<0.1%
Appearance and Odor:WHITE SOLID, AROMATIC MOTH-BALL ODOR.
Percent Volatiles by Volume:SUPDAT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE/CARBON MONOXIDE ON
COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:VIA LICENSED DISPOSAL COMPANY. DISPOSE OF
ACCORDING TO FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATORY PROTECTION (DUST,
FUME,HIGH EFFICIENCY DUST/FUME MASK FOR LEAD, OR OTHER (ORGANIC
VAPOR) AS SPECIFIED BY AN INDUSTRIAL HYGIENIST OR OTHE RQUALIFIED
PROFESSIONAL IF CONCE NTRATIONS EXCEED THE LIMITS LISTED IN
INGREDIENTS SECTION.
Ventilation:USE WITH ADEQUATE EXPLOSION PROOF VENTILATION TO MEET
EXPOSURE LIMITS.
Other Protective Equipment:ADEQUATE PROTECTIVE CLOTHING SHOULD BE
PROVIDED TO PREVENT CONTAMINATION OF PERSONAL CLOTHING.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING. GOOD INDUSTRIAL
HYGIENE PRACTICES, INCLUDING REDUCING OCCUPATIONAL EXPOSURES TO AS
LOW AS REASONABLY ACHIEVABLE, ARE RECOMMENDED.
Supplemental Safety and Health
CHEMICAL FORMULA: MIXTURE. OTHER DESOGNATIONS: ALCOTEC
ALMIGWELD(ALUMINUM SPOOLED ELECTRODE), ALCOTEC ALTIGWELD (ALUMINUM
STRAIGHT LENGTH WELDING ROD), ALUMINUM METALLIZING WIRE (COILS AND
SPOOLS). PR ODUCT USE: WELDING, FILLER METAL, METALLIZING, BRAZING.
* Product Identification *
Preparer's Name:HAZARDOUS MATERIALS
* Composition/Information on Ingredients *
Ingred Name:SILICON
Minumum % Wt:9.3
Ingred Name:IRON
= Wt:.8
ACGIH TLV:5 MG/M3
Ingred Name:COPPER
Minumum % Wt:3.3
Maxumum % Wt:4.7
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:ZINC
= Wt:.2
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:OTHERS EACH
Ingred Name:OTHERS TOTAL
Ingred Name:ALUMINUM
Fraction by Wt: REMAINDER
Ingred Name:MANGANESE
OSHA PEL:DUST (CEILING)
ACGIH TLV:0.2 MG/M3
Ingred Name:MAGNESIUM
Ingred Name:CHROMIUM
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: FUME CAN CAUSE IRRITATION.
ULTRAVIOLET RADIATION FROM WELDING CAN CAUSE FLASH BURNS. SKIN: CAN
CAUSE IRRITATION. ULTRAVIOLET RADIATION FROM WELDING CAN CAUSE
FLASH BURNS. INHALTION: CAN CAUSE RE SPIRATORY TRACT IRRITATION,
METAL FUME FEVER, AND OTHER HEALTH EFFECTS LISTED BELOW. CANCER
HAZARD.
Explanation of Carcinogenicity:WELDING FUMES ARE CARCINOGENIC & ARE
LISTED AS AN IARC GROUP 2B. "SEE MSDS FOR DETAILS."
Effects of Overexposure:ALUMINUM IS WELDED IN A PROTECTIVE, INERT
ATMOSPHERE SUCH AS ARGON OR HELIUM USING THE MIG OR TIG PROCESS.
WELDING PROCESSES GENERATE WELDING FUMES AND AN INTENSE ULTRAVIOLET
RADIATION THAT RESULTS IN THE FORMATION OF OZONE, AND OXIDES OF
NITROGEN. ULTRAVIOLET RADIATION FROM WLEDING CAN ALSO CAUSE FLASH
BURNS TO THE EYES AND SKIN.
Medical Cond Aggravated by Exposure:CHRONIC LUNG DISEASE, SKIN RASHES,
AND ASTHMA.
* First Aid Measures *
First Aid:EYES: FLUSH EYES WITH PLENTY OF WATER OR SALINE FOR AT LEAST
AND WATER. CONSULT A PHYSICIAN IF IRRITATION PERSISTS. INHALTION:
REMOVE TO FRESH AIR. CHECK FOR AIRWAY, BREATHING, AND PRESENCE OF
PULSE. PROVIDE CPR FOR PERSONS WITHOUT PULSE OR RESPIRATION.
CONSULT A PHYSICIAN IMMEDIATELY.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:USE METHODS APPROPRIATE FOR SURROUNDING FIRE. USE
COARSE WATER SPRAY ON CHIPS OR TURNINGS. FOR FINES, DUST, MOLTEN
ALUMINUM, USE CLASS D EXTINGUISHING AGENTS.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR NIOSH APPROVED,
POSITIVE PRESSURE, SELF-CONTAINED BREATHING APPARATUS AND FULL
PROTECTIVE CLOTHING WHEN APPROPRIATE. DO NOT USE: HALOGENTAED
EXTINGUISHING AGENTS ON SMALL CHIP S/FINES. DO NOT USE WATER IN
FIGHTING FIRES AROUND MOLTEN ALUMINUM.
Unusual Fire/Explosion Hazard:MAY BE A POTENTIAL HAZARD UNDER THE
FOLLOWING CONDITIONS: DUSTS OR FINES DISPERSED IN THE AIR CAN BE
EXPLOSIVE. CHIPS, FINES, DUST IN CONTACT WITH WATER CAN GENERATE
FLAMMABLE/EXPLOSIVE HYDROGEN GAS. FINES & DUST IN CONTACT WITH
CERTAIN METAL OXIDES. M0LTEN ALUMINUM IN CONTACT WITH
WATER/MOISTURE OR OTHER METAL OXIDES.
* Accidental Release Measures *
Spill Release Procedures:IF MOLTEN: CONTAIN THE FLOW USING DRY SAND OR
SAIL FLUX AS DAM. DO NOT USE SHOVELS OR HAND TOOLS TO HALT THE FLOW
OF MOLTEN ALUMINUM. ALLOW THE SPILL TO COOL BEFORE REMELTING AS
SCRAP.
*Handling and Storage *
Handling and Storage Precautions:PRODUCT SHOULD BE KEPT DRY. AVOID
GENERATING DUST. AVOID CONTACT WITH SHARP EDGES OR HEATED METAL.
HOT AND COLD ALUMINUM ARE NOT VISUALLY DIFFERENT.
Other Precautions:USE NON-SPARKING HANDLING EQUIPMENT. COVER AND RESEAL
PARTIALLY EMPTY CONTAINERS. PROVIDE GROUNDING AND BONDING WHERE
NECESSARY TO PREVENT ACCUMULATION OF STATIC CHARGES DURING ALUMINUM
DUST HANDLING AND TRANSFER OPERATIONS.
* Physical/Chemical Properties *
HCC:N1
NRC/State Lic Num:NONE
Spec Gravity:NOT DETERMINED
Solubility in Water:NONE
Appearance and Odor:SILVERY COLOR, SOLID WELDING ELECTRODE, NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MOLTEN OR FINELY DIVIDED ALUMINUM MAY REACT VIOLENTLY WITH WATER, HEAT,
STRONG OXIDIZERS, ACIDS AND ALKALIES,HALOGENATED COMPOUNDS, IRON
OXIDES(RUST) AND OTHER METAL OXIDES AND IRON POWDER.
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS OF USE,
STORAGE, & TRANSPORTATION AS SHIPPED.
* Toxicological Information*
NOTED. *POSSIBLE HAZARDS DURING PROCESSING BY WELDING, OR ARC
SPRAY METALLIZING: OZONE, ACGIH TLV=0.1 PPM )CEILING), OSHA P
NITROGEN DIOXIDE, ACGIH TLV=3,5 PPM 9STEL), OSHA PEL=5 PPM
(CEILING). WELDING FUMES, ACGIH=5 MG/M3.
* Ecological Information *
Ecological:ECOTOXICOLOGICAL/CHEMICAL FATE INFORMATION: NOT AVAILABLE.
* Disposal Considerations *
Waste Disposal Methods:COLLECT SCRAP FOR REMELTING AND RECYCLING. TO
MAINTAIN METAL PURITY, IT MAY BE DESIRABLE TO SEGREGATE THIS SCRAP
* MSDS Transport Information *
Transport Information:USA DOT: NOT EGULATED - ENTER THE PROPER FREIGHT
CLASSIFICATION, "MSDS NUMBER" AND "PRODUCT NAME" ON THE SHIPPING
PAPERWORK. CANADIAN TDG HAZARD CLASS & PIN: NOT REGULATED.
* Regulatory Information *
CATEGORIES: IMMEDIATE (ACUTE), DELAYED (CHRONIC) IF
TOXIC CHEMICALS: ALUMINUM (FUME/DUST), BE RYLLIUM, CHROMIUM,
COPPER, LEAD, MANGANESE, NICKEL, VANADIUM (FUME/DUST) AND ZINC
(FUME/DUST).
Federal Regulatory Information:U.S.TSCA STATUS: ALL COMPONENTS OF THIS
PRODUCT ARE LISTE ON THE TSCA INVENTORY. CERCLA HAZARDOUS
SUBSTANCES: BERYLLIUM, CHROMIUM, CHROMIUM COMPOUNDS, COPPER, LEAD,
MANGANESE, NICKEL, ZINC. ALL ELECTR ICAL EQUIPMENT MUST BE SUITABLE
FOR USE IN HAZARDOUS ATMOSPHERES INVOLVING ALUMINUM POWDER IN
EQUIPMENT & INSTALLATION, WHICH WILL MEET THIS REQUIREMENT.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINA OR PRODUCES
A CHEMICAL KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER & BIRTH
DEFECTS (OR OTHER REPRODUCTIVE HARM). (CALIFORNIA HEALTH & SAFETY
BERYLLIUM, NICKEL, CHROMIUM COMPOUNDS, HEXAVALENT.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NEEDED IN NORMAL SERVICE.
Ventilation:EITHER GOOD ROOM VENTILATION OR LOCAL EXHAUST.
Other Protective Equipment:CLOTHING TO PREVENT EXCESSIVE SKIN
CONTACT,AS NEEDED.
Work Hygienic Practices:TREAT AS A PHARMACEUTICAL;EXERCISE REASONABLE
CARE.
Supplemental Safety and Health
THIS IS A 3% SOLUTION.
* Product Identification *
Product ID:ADENOCARD
Preparer's Name:PAT HARTMAN
* Composition/Information on Ingredients *
Ingred Name:ADENOSINE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL:NO HAZARD EXPECTED.INHALED
ADENOSINE MAY CAUSE BRONCHOCONSTRICTION IN ASTHMATICS(BUT NOT IN
NORMAL PEOPLE).SKIN:MAY CAUSE MILD IRRITATION.EYES:MAY CAUSE MILD
IRRITATION.INGEST:NOT REPORTED.
Explanation of Carcinogenicity:ADENOSINE,LIKE OTHER NEUCLEOSIDES,MAY
CAUSE CHROMOSOMAL ALTERATIONS.
Effects of Overexposure:POSSIBLE EYE AND SKIN IRRITATION.
Medical Cond Aggravated by Exposure:ASTHMATICS MAY SUFFER
BRONCHOCONSTRICTION FROM INHALED ADENOSINE.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR.GIVE ARTIFICIAL RESPIRATION,OXYGEN
OR CPR IF NEEDED.KEEP WARM AND QUIET WHILE GETTING MEDICAL
ATTENTION.INGEST:FLUSH OUT OF MOUTH WITH WATER.GET MEDICAL
ATTENTION.SKIN:REMOVE CONTAMINATED CLOTHING;FLUSH WITH WATER.GET
ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CARBON IDOXIDE OR FOAM
..AS APPROPRIATE.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PROTECTIVE EQUIPMENT.SOAK UP WITH
AN INERT MATERIEL AND PLACE IN AN APPROPRIATE CONTAINER FOR
DISPOSAL.
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:WHEN HANDLING A PHARMACEUTICAL,AVOID
SKIN AND EYE CONTACT;DO NOT BREATH VAPORS OR MISTS.
Other Precautions:NONE
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID;CLEAR;ODOR NOT REPORTED
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:HMIS SUGGESTS CARBON DIOXIDE AND
CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:RESTRICTED AREAS US NIOSH APPROVED CHEMICAL
CARTRIDGE RESPIRATOR. SPRAYING USE AMECHANICAL FILTER RESPIRATOR.
CONFINED AREAS USE A NIOSH APPROVED AIR SUPPLIED RESPIRATOR.
Ventilation:LOCAL EXHAUST VENTILATION OR GENERAL DILUTION
Other Protective Equipment:AS REQUIRED TO PREVENT SKIN CONTACT
Work Hygienic Practices:NONE
Supplemental Safety and Health
NK
* Product Identification *
Preparer's Name:W.A. ELLISON
* Composition/Information on Ingredients *
Ingred Name:MINERAL SPIRITS
Ingred Name:SILICA, CRYSTALLINE-CRISTOBALITE
Fraction by Wt: 5%
OSHA PEL:SEE TABLE Z3
Ingred Name:CARBON BLACK
Fraction by Wt: 5%
OSHA PEL:3.5 MG/M3
Ingred Name:LEAD CHROMATE
Ingred Name:SILICA, AMORPHOUS, DIATOMACEOUS EARTH, CONTAINING LESS THAN
1% CRYSTALLINE SILICA
Fraction by Wt: <5%
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
Fraction by Wt: <1%
OSHA PEL:SEE TABLE Z3
Ingred Name:TALC (CONTAINING NO ASBESTOS)
OSHA PEL:2 MG/M3 RDUST
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
Fraction by Wt: <1%
OSHA PEL:SEE TABLE Z3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ASPIRATION OF MATERIAL INTO THE LUNGS
CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. REPEATED EXPSR
TO CRYSTALLINE SILICA MAY CAUSE PNEUMOCONIOSIS A DISABLING LUNG
DISEASE. PROLONGED/REPEATED OVR EXPSR MAY CAUSE PERMANENT BRAIN &
NERVSSYS DAMAGE. INTENTIONAL MISUSE CAN BE HARMFUL OR FATAL.
THAT THERE IS NO SIGNIFICIANT HAZARD FOR MAN.
Effects of Overexposure:INGST: GASTRONINTESTINAL
IRRITATION,NAUSEA,VOMITING,& DIARRHEA. INHL:
ANESTHETIC,IRRITATION TO NOSE/THROAT, HEADACHES, DIZZINESS, NAUSEA,
& CONFUSION.; SKIN: MAY CAUSE DEFATTING AND I RRITATIONEYE:
IRRITATION
Medical Cond Aggravated by Exposure:REPEATED EXPOSURE MAY CAUSE
PNEUMOCONIOSIS, A PROGRESSIVELY DISABLING LUNG DISEASE.
* First Aid Measures *
GET MEDICAL ATTENTIONSKIN: WASH AFFECTED AREA W/SOAP & WTR, REMOVE
CONTAM. CLOTHING.GET MED. ATTN. INHAL: REMOVE TO FRESH AIR
IMMEDIATELY,G IVE ARTIFICIAL RESP. IF NECESSARY, KEEPWARM & QUIET,
GET MEDICAL ATTENTION.
INGST: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION IMMEDIATELY
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:USE NFPA CLASS B FIRE EXTINGUISHERS,CARBON
DIOXIDE,DRY CHEMICAL,ALCOHOL FOAM. POLYMER FOAM IS PREFERRED FOR
LG. FIRES
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. WATER
MAY BE INEFFECTIVE,MAY BE USED TOCOOL EXPOSED CONTAINERS. IF WATER
IS USED, FOG NOZZLES ARE PREFERRABLE.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT,SPARKS &FLAME. CLOSED CONTAINERS
MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. DIKE/CONTAIN
SPILLW/INERT MATL. PLACE ABSORBENT DIKING MATL IN COVERED METAL
CONTNR FOR DISPOSAL. USE ONLY NON SPARK TOOLS. PREVENT CONTAM. OF
SEWERS, GROUNDWATER, AND STREAMS W/SPILLED MATL OR USED ABSORBENT.
*Handling and Storage *
AFTER EACH USE. EMPTY CONTNRS MUST NOT BE WASHED/REUSED FOR
NEVER USE PRESSURE TO EMPTY.
Other Precautions:DO NOT TAKE INTERNALLY. CONTAINERS SHOULD BE
GROUNDED/BONDED TO RECEIVING CONTNRDO NOT WELD,BRAZE OR CUT ON
EMPTY CONTAINERS. DRUM IS NOT A PRESSURE VESSEL.
* Physical/Chemical Properties *
Vapor Density:> AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS
Stability Condition to Avoid:HEAT AND SOURCES OF IGNITION
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
Conditions to Avoid Polymerization:HEAT SPARKS AND FLAME
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL,STATE,& LOCAL
LAWSINCINERATE ONLY IN EPA PERMITTED FACILITY. DO NOT INCINERATE
CLSD CONTAINERS. CONTAMINATED ABSORBANTMAY BE DISPOSED IN A
HAZARDOUS WASTE LANDFILL.TRAN SFER LIQ TO COVERED METAL CONTAINERS
FOR DISPOSAL.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:MULTICUT PLASTIC ACRYLIC ABRASIVE MEDIA
CAGE:PLYPA
CAGE:PLYPA
* Composition/Information on Ingredients *
Ingred Name:METHACRYLIC ACID, METHYL ESTER; (METHYL METHACRYLATE)
Fraction by Wt: <0.5%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:TOXICOLOGY INFO ON REGULATED
MMA MAY CAUSE PRIMARY EYE OR SKIN IRRITATION. ALLERGIC SKIN
REACTIONS MAYOCCUR BY REPEATED DIRECT CONTACT. VAPOR OVEREXPOS MAY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CAUSE IRRIT TO EYES OF RESP TRACT AND
MAY CAUSE CNS DEPRESSION. MMA WAS NOT CARCINOGENIC TO RATS & MICE
NATL TOXICOLOGY PROGR AM. THESE CONC PRODUCED CHRONIC NASAL IRRIT
RSLTG IN INFLAMM OF NASAL CAVITY & DEGENERATION OF OLFACTORY
EPLTHELLUM.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:NO SPECIFIC FIRST AID PROCEDURES ARE NEC FOR ACCIDENTAL EXPOS
TO THIS PROD. INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH
AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATEL Y
FROM MD . SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD .
* Fire Fighting Measures *
Extinguishing Media:WATER, CARBON DIOXIDE, OR DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP SPILLS & PLACE IN WASTE DISPOSAL
CONTAINER.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:CUTTING, GRINDING/SANDING MAY GENERATE
SM QTYS OF METHYL METHACRYLATE MONOMER & MAY CREATE NUISANCE
PARTICULATES & RESPIRABLE DUST PARTICLES.
Other Precautions:STORE IN CLSD, PROPERLY LBLD CNTNRS IN COOL
VENTILATED AREA. KEEP AWAY FROM HEAT, OPEN FLAMES & OXIDIZING
AGENTS. DO NOT TRANSFER TO UNMARKED CNTNRS. DETERM COMPLIANCE WITH
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GRANULAR, CLEAR, NO COLOR WITH NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:THERMAL DECOMP OR COMBUSTION MAY
PRODUCE CARBON MONOXIDE, CARBON DIOXIDE AND/OR METHYL METHACRYLATE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE I/A/W APPLICABLE FEDERAL, STATE
AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF AIRBORNE DUST OR FIBERS EXCEED THE TLV OR IF
UPPER RESPIRATORY IRRITATION OCCURS, USE A NIOSH APPROVED
RESPIRATOR DESIGNED FOR NUISANCE TYPE DUSTS.
Ventilation:NORMAL AREA VENTILATION IS SUFFICIENT IN MOST CASES TO KEEP
DUST AND FIBER LEVELS BELOW THE TLV.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:FIBROUS GLASS (TEXTILE GRADE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:RESPIRABLE FIBROUS GLASS DUST
OSHA PEL:5 MG/M3 (MFR)
Ingred Name:ORGANICALLY BOUND SILANES
Fraction by Wt: 0.4%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: DIRECT SKIN CONTACT WITH
FIBROUS GLASS OR ITS DUST MAY CAUSE MECHANICAL IRRITATION AND
TRANSITORY DERMATITIS. BREATHING OF FIBERS OR DUST MAY CAUSE
MECHANICAL IRRITATION OF THE MOUTH, NOSE, AND THROAT. CHRONIC:
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:INHALATION: MOVE TO FRESH AIR AREA. INGESTION: NOT LIKELY TO
OCCUR THROUGH NORMAL USE. CALL MD IMMEDIATELY . EYES: FLUSH WITH
W ATER FOLLOWED BY WASHING WITH MILD SOAPTO REMOVE ACCUMULATED
FIBERS.
* Fire Fighting Measures *
Extinguishing Media:WATER, DRY POWDER, OR FOAM (NEEDED FOR PACKAGING
ONLY).
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:DUST OR LOOSE FIBERS CAN BE VACUUMED OR SWEPT
WITH THE AID OF A DUST SUPPRESSANT.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY AREA.
Other Precautions:
* Physical/Chemical Properties *
Spec Gravity:2.5
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE SOLID; NO DISTINCTIVE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE GENERATED UNDER NORMAL STORAGE OR
HANDLING CONDITIONS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE ACCORDING TO LOCAL, STATE, AND FEDERAL
LAWS. THIS MATERIAL IS NOT REGULATED UNDER RCRA HAZARDOUS WASTE
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED UNDER NORMAL USE. USE NIOSH/MSHA
APPROVED REPIRATORS WHERE DUST, MIST, OR SPRAY MAY BE GENERATED.
Ventilation:SPECIAL VENTILATION IS NOT REQUIRED UNDER NORMAL USE.USE
LOCAL EXHAUST VENTILATION WHERE MIST OR SPRAY MAY BE GENERATED.
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING AND CHEMICAL
RESISTANT SAFETY SHOES SHOULD BE WORN TO MINIMIZE CONTACT.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
PROVIDE WORKING AREA WITH EYE WASH STATION AND SAFETY SHOWER.
RETURNABLE CONTAINERS SHOULD BE SHIPPED IN ACCORDANCE WITH
SUPPLIER'S RECOMMENDATIONS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
Other REC Limits:NONE SPECIFIED
OSHA PEL:C, 2 MG/M3
Ingred Name:WATER
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE BURNS, EYE DAMAGE,
BLINDNESS. SKIN: IRRITATION, SEVERE BURNS, TISSUE DESTRUCTION.
INHALATION: MISTS OR SPRAYS MAY CAUSE DAMAGE TO UPPER-RESPIRATORY
TRACT AND LUNG TISSUE. INGESTION: CAN C AUSE SEVERE BURNS AND
COMPLETE TISSUE PERFORATION OF MUCOUS MEMBRANES OF THE MOUTH,
THROAT, ESOPHAGUS AND STOMACH.
Explanation of Carcinogenicity:NOT LISTED AS CARCINOGEN BY NTP, IARC,
OSHA.
Effects of Overexposure:EYES: BURNS, EYE DAMAGE, BLINDNESS. SKIN:
IRRITATION, BURNS, TISSUE DESTRUCTION. INHALATION: DAMAGE TO UPPER
RESPIRATORY TRACT AND LUNG TISSUE. INGESTION: BURNS AND PERFORATION
OF MUCOUS MEMBRANES OF THE MOUTH, THROAT, ESOPHAGUS AND STOMACH.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING DISEASE
INVOLVING THE EYES, SKIN OR RESPIRATORY TRACT MAY BE AT INCREASED
RISK FROM EXPOSURE.
* First Aid Measures *
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH AREA WITH
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION: MOVE TO
FRESH AIR. IF NOT BREATHING GIVE CPR. IF BREATHING DIFFICULT GIVE
OXYGEN. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING.
GIVE LARGE AMOUNTS OF WATER OR SEVERAL GLASSES OF MILK. GET MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:PRODUCT NOT COMBUSTABLE. USE MEDIA APPROPRIATE FOR
SURROUNDING FIRE. WATER SPRAY, FOAM, CARBON DIOXIDE, DRY CHEMICALS.
Fire Fighting Procedures:AVOID DIRECT CONTACT OF THIS PRODUCT WITH
WATER SINCE THIS CAN CAUSE A VIOLENT EXOTHERMIC REACTION. WEAR
PROTECTIVE CLOTHING AND SCBA FOR FIREFIGHTING IN AREA.
Unusual Fire/Explosion Hazard:DO NOT MIX WITH STRONG ACIDS WITHOUT
DILUTION AND AGITATION TO PREVENT VIOLENT OR EXPLOSIVE REACTION.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILLS. NEUTRALIZE SPILL WITH ANY
DILUTE INORGANIC ACID. FLUSH SPILL AREA WITH WATER FOLLOWED BY
LIBERAL COVERING OF SODIUM BICARBONATE. COLLECT CLEAN-UP MATERIAL
IN APPROVED CONTAINERS FOR PR OPER DISPOSAL.
Neutralizing Agent:USE DILUTE HYDROCHLORIC, SULFURIC, NITRIC,
PHOSPHORIC, OR ACETIC ACID.
*Handling and Storage *
Handling and Storage Precautions:STORE AND USE IN WELL VENTILATED AREA.
KEEP CONTAINERS CLOSED. NEVER ADD WATER TO PRODUCT. ALWAYS ADD
PRODUCT, WITH CONSTANT STIRRING,SLOWLY TO WATER.
Other Precautions:ALWAYS EMPTY AND CLEAN CONTAINERS OF ALL RESIDUES
BEFORE ADDING PRODUCT TO AVOID POSSIBLE EXPLOSIVE REACTION BETWEEN
PRODUCT AND UNKNOWN RESIDUE. ALL RESIDUAL CAUSTIC POTASH SHOULD BE
REMOVED FROM CON TAINERS PRIOR TO DISPOSAL.
* Physical/Chemical Properties *
HCC:B1
pH:BASIC
Solubility in Water:COMPLETELY
Appearance and Odor:CLEAR LIQUID. NO ODOR.
Percent Volatiles by Volume:UNKNON
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALUMINUM, TIN, ZINC, AND ALLOYS CONTAINING THESE METALS, LEATHER,
ORGANIC HALOGENS AND ORGANIC NITRO COMPOUND,ACID,WOOL.
Stability Condition to Avoid:AVOID DIRECT CONTACT WITH WATER.
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:MATERIAL IS NOT KNOWN TO POLYMERIZE.
* Disposal Considerations *
Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NEEDED IN NORMAL LABORATORY HANDLING. IF
DUSTY CONDITONS PREVAIL WORK IN VENTILATION HOOD OR WEAR
NIOSH-APPROVED DUST MASK OR RESPIRATOR.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL):RECOMMENDED.
Work Hygienic Practices:WASH WELL AFT HANDLING.REMOVE & WASTH CONTAMIN
CLOTH.KEEP OUT OF REACH OF CHILDREN.NOT FOR DRUG/FOOD/HOUSEHOLD
USE.
Supplemental Safety and Health
FIREFIGHTING:INTENSE HEAT/HIGHLY IRRIT/CORR MIST.EXPLO/FIRE
HAZ:HOT/MOLTEN MATL WILL REACT VIOLENTLY W/WATER LIBERATING
HEAT/CAUSING SPLASHING.SEVERE EYE HAZ;SOLID/CONC SOLN DESTROYS
TISSUE ON CONTACT .DISPOSAL:VIOLENT SPATTERING.NEUTRALIZEW/SODIUM
BISULFATE.FLUSH TO SEWER W/COPIOUS AMTS OF WATER.
* Product Identification *
Product ID:POTASSIUM HYDROXIDE
Preparer's Name:ALEXANDER A. PICCIRILLI
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGEST:POISON.MAY RESULT IN SEVERE
INTESTINAL IRRIT W/BURNS TO MOUTH. SKIN/EYES:CONTACT W/SKIN/EYES
MAY CAUSE SEVERE IRRIT OR BURNS. INHAL:DUST VERY IRRITATING TO
UPPER RESP TRACT. MAIN EFFECT. TISSUE DAMAGE.
Effects of Overexposure:POISON. SEVERE INTESTINAL IRRITATION W/BURNS TO
MOUTH. SEVERE EYE/SKIN IRRITATION/BURNS. IRRITATING TO UPPER RESP
TRACT. TISSUE DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST:DO NOT INDUCE VOMIT.IF CONSC GIVE LG AMTS OF
WATER.CALL DR IMMED.NEVER GIVE ANYTHING BY MOUTH IF
EYELIDS.GET PROMPT MED ATTN.SKIN: FLOOD W/WATER THEN WASH
W/VINEGAR.INHAL:REMOVE TO FRESH AIR.IF IRRIT/ILLNESS OCCURS GET MED
ATTN.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:USE WATER ON FIRE INVOLVING THIS MATERIAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROT
CLOTH.MUST INCLUDE COMPLETE EYE PROT.FLOOD W/WATER USING CARE NOT
TO SPLATTER/SPLASH MATL.CONTACT W/WATER PRODUCES (SUPPLE)
Unusual Fire/Explosion Hazard:NOT COMBUST BUT SOLID FORM IN CONTACT
W/MOISTURE/WATER MAY GENERATE SUFFICIENT HEAT TO IGN COMBUST
MATLS.COTNACT W/SOME METALS CAN GENERATE HYDROGEN GAS.(SUPPL)
* Accidental Release Measures *
Spill Release Procedures:CAREFULLY & WEARING PROTECTIVE CLOTHING SWEEP
UP & PLACE IN SUITABLE CNTNR. FLUSH SPILL AREA W/WATER RINSE
W/DILUTE ACID, PREFERABLY ACETIC & FINALLY W/WATER.
Neutralizing Agent:SODIUM BISULFATE.
*Handling and Storage *
Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD.STORE IN COOL
DRY PLACE;PROTECT AGAINST MOISTURE/WATER.SEPARATE FROM
ACIDS/METALS/EXPLOSIVES/ORG PEROXIDES & EASILY IGN MATLS.
Other Precautions:READ LABEL ONCNTNR BEF USING.DONOT WEAR CONTACT
LENSES WHEN SORKING W/CHEM.PROD IS DELIQUESCENT;ABSORBS WATER & CO2
FRM AIR.KOH & TRICHLOROETHYLENE ARE ESPECIALLY HAZ SINCE REACT TO
FROM SPONT FLAMM D ICHLOROACETYLENE.FOR LAB USE ONLY.
* Physical/Chemical Properties *
HCC:B1
Evaporation Rate & Reference:NON-VOLATILE
Appearance and Odor:NEAR WHITE PELLETS OR FLAKES; NO ODOR
Percent Volatiles by Volume:NONVOL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER CAN REACT VIOLENTLY W/ACIDS & W/MANY ORG CMPDS,MOST COMMON METALS
(ZN, AL, SN, PB,ETC)LIBERATING FLAMM HYDROGEN.
Stability Condition to Avoid:MOISTURE, ACIDS & ACID FUMES.
Hazardous Decomposition Products:REACTION W/VARIOUS FOOD SUGARS MAY
FORM CARBON MONOIXDE.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE/TREATMENT/DISPOSAL MAY BE SUBJECT TO
FED/STATE/LOC LAWS.THESE DISPOSAL GUIDELINES ARE INTENDED FOR
DISPOSAL OF CATALOG-SIZE QUANT ONLY.SLOWLY DISSOLVE SPILL IN
WWTER.WHILE MAKING SOLN ADD SL OWLU TO SURFACE OF STIRRED LIQ TO
AVOID(SUPPLEME)
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AS REQUIRED.
Ventilation:MECHANICAL (GENERAL)
Supplemental Safety and Health
* Product Identification *
Product ID:SPARTON AIR HORN
Preparer's Name:SIDNEY K SAKSENBERG
* Composition/Information on Ingredients *
Ozone Depleting Chemical:1
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: FROSTBITE. INHALATION:
SUFFOCATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: LIGHT HEADEDNESS, GIDDINESS,
SHORTNESS OF BREATH, NARCOSIS, CARDIAC IRREGULARITIES,
UNCONSCIOUSNESS, & POSSIBLE DEATH.
* First Aid Measures *
First Aid:EYES: FLUSH W/PLENTY OF WATER. SKIN: WASH W/WATER, TREAT FOR
FROST BITE. INHALATION: REMOVE TO FRESH AIR. APPLY ARTIFICIAL
RESPIRATION IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:NONFLAMMABLE
Unusual Fire/Explosion Hazard:PRODUCT IS PACKED UNDER PRESSURE. STORAGE
THAN AIR.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. ESPECIALLY LOW AREAS WHERE
HEAVY VAPORS MAY COLLECT.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM HEAT & OPEN FLAMES.
Other Precautions:READ & FOLLOW LABEL DIRECTIONS. AVOID BREATHING
VAPORS & SKIN CONTACT.
* Physical/Chemical Properties *
Vapor Density:4.2
Appearance and Odor:CLEAR W/A SLIGHT ETHEREAL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:COMPLY W/FEDERAL, STATE & LOCAL REGULATIONS. EPA
| 1 | gloves_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SKIN: BASED ON SIMILAR PRODUCT TESTING PRODUCT IS
MODERATELY IRRITATING TO SKIN & MAY CAUSE SKIN SENSITIZATION. CONTACT
WITH PRODUCT AT ELEVATED TEMPERATURES CAN RESULT IN THERMAL BURNS. EYES:
BASED O N SIMILAR PRODUCT TESTING PRODUCT IS MODERATELY IRRITATING TO EYES.
CONTACT W/PRODUCT AT ELEVATED TEMPERATURES CAN RESULT IN THERMAL BURNS.
INHALATION: BECAUSE OF ITS LOW VOLATILITY THIS PRODUCT IS NO T LIKELY TO BE
AN INHALATION HAZARD. INGESTION: BASED ON PRODUCT TESTING PRODUCT IS
CONSIDERED TO HAVE A LOW ORDER OF ACUTE ORAL TOXICITY. SIGNS & SYMPTOMS:
IRRITATION. SKIN SENSITIZER (ALLERGY) MAY B E EVIDENCED BY RASHES, ESPECIALLY
HIVES.
Medical Cond Aggravated By Exposure: PREEXISTING EYE, SKIN & RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO PRODUCT. PREEXISTING SKIN/LUNG
ALLERGY MAY INCREASE CHANCE OF DEVELOPING INCREASED ALLERGY SYMPS FROM
EXPOSURE TO PRODUCT.
First Aid: SKIN: REMOVE CONTAMINATED CLOTHING/SHOES. WIPE EXCESS FROM SKIN
& WASH WITH PLENTY OF SOAP & WATER. GET PROMPT MEDICAL ATTENTION IF
IRRITATION OCCURS. IF CONTACT WITH HOT PRODUCT OCCURS, IMMEDIATELY F LUSH
WITH COOL WATER FOR FIFTEEN MINUTES. CAREFULLY REMOVE CLOTHING; IF CLOTHING
IS STUCK TO A BURN AREA DO NOT PULL IT OFF, BUT CUT AROUND IT. COVER BURN
AREA WITH CLEAN MATERIAL. GET MEDICAL ATTENTI ON IMMEDIATELY. EYES: IRRIGATE
GET MEDICAL ATTENTION. (OTHER INFO)
*
Handling and Disposal
*
Spill Release Procedures: MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE CAUTIOUS
JUDGEMENT WHEN CLEANING UP LARGE SPILLS. LARGE SPILLS: WEAR RESPIRATOR AND
PROTECTIVE CLOTHING AS APPROPRIATE. SHUT OFF SOURCE OF LEAK IF SAFE TO DO
SO. DIKE AND CONTAIN. REMOVE WITH AN ABSORBENT SUCH AS CLAY, SAND OR OTHER
SUITABLE MATERIAL; DISPOSE OF PROPERLY, FLUSH AREA WITH WATER TO REMOVE TRACE
RESIDUE. SMALL SPILLS: TAKE (NEUT AGENT)
Neutralizing Agent: N/P. SPILL PROCEDURES (CONT'D): UP WITH AN ABSORBENT
MATERIAL ANDDISPOSE OF PROPERLY.
Waste Disposal Methods: INCINERATE OR BURY IN AN APPROVED CHEMICAL DISPOSAL
FACILITY IN A MANNER WHICH COMPLIES WITH ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: PRACTICE & OBSERVE GOOD HOUSEKEEPING
PROCEDURES IN PERSONAL HYGIENE & CLEANLINESS. AVOID SKIN & EYE
CONTACT, AS WELL AS, BREATHING OF VAPOR/FUMES ESPECIALLY WHEN MATERIAL IS
HEATED. TO PREVENT THERMAL S BURNS, AVOID SKIN &EYE CONTACT W/HOT
LIQUID. CONTAINERS, EVEN THOSE THAT HAVE BEEN (OTHER PREC)
Other Precautions: HNDLG/STOR (CONT'D): EMPTIED, CAN CONTAIN HAZARDOUS PRODUCT
RESIDUES. HANDLE IN ACCORDANCE WITH HAZARD POTENTIAL OF CURING AGENT(S) USED.
STORE IN COOL, DRY AREA. KEEP AWAY FROM OPEN FLAMES & HIGH TE MPS. IF
THIS RESIN IS HANDLED, SHIPPED, OR STORED IN BULK, THE RECOMMENDED PUMPING
*
Fire and Explosion Hazard Information
*
Flash Point Method: PMCC
Extinguishing Media: USE WATER FOG, FOAM, DRY CHEMICAL, OR CO2.
Fire Fighting Procedures: MATERIAL WILL NOT BURN UNLESS PREHEATED. DO NOT ENTER
CONFINED FIRE SPACE W/O FULL BUNKER GEAR (HELMET WITH FACESHIELD, BUNKER
INCLUDING NIOSH APPROVED SCBA. USE COLD SPRAY TO COOL DOWN FIRE & HEAT
EXPOSED CONTAINERS TO KEEP THEM FROM RUPTURING.
MAY OCCUR. SOME CURING AGENTS, E.G. ALIPHATIC POLYAMINES CAN PRODUCE EXOTH
ERMIC REACTIONS, WHICH IN LARGE MASSES CAN CAUSE RUNAWAY POLYMERIZATION AND
(STATE REG)
*
*
Respiratory Protection: NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE EXPOSURE
OF CONCERN (FP N). NOT ORDINARILY REQUIRED (MFR).
Ventilation: LOCAL EXHAUST RECOMMENDED.
RECOMMENDED.
Other Protective Equipment: WEAR CHEMICAL RESISTANT CLOTHING TO MINIMIZE
CONTACT. EYE WASH FOUNTAINS AND SAFETY SHOWERS MEETING ANSI DESIGN CRITERIA
SHOULD BE AVAILABLE FOR EMERGENCY USE.
Work Hygienic Practices: WASH WIITH SOAP AND WATER BEFORE EATING, DRINKING,
SMOKING, APPLYING COSMETICS, OR USING TOILET FACILITIES. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE. CONTAMINATED LEATHER ARTICLES,(SUPP
SFTY)
Supplemental Safety and Health: HYGIENE PRACTICE (CONT'D): INCLUDING SHOES, CAN
NOT BE DECONTAMINATED AND SHOULD BE DESTROYED TO PREVENT USE.
*
Physical/Chemical Properties
*
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: LIQUID FORM, MILD ODOR.
*
Reactivity Data
*
Stability Indicator: YES E HEAT. (CNDTNS, STAB)
Stability Condition To Avoid: N/P. MATERIALS TO AVOID (CONT'D): RUNAWAY
CHAIN REACTIONS MAY CHAR AND DECOMOSE THE RESIN SYSTEM, GENERATING
UNIDENTIFIED FUMES AND VAPORS THAT MAY BE TOXIC.
Materials To Avoid: CAN REACT VIGOROUSLY WITH STRONG OXIDATION AGENTS, STRONG
LEWIS OR MINERAL ACIDS, AND STRONG MINERAL, ORGANIC BASES/ESPECIALLY PRIMARY
AND SECONDARY ALIPHATIC AMINES. REACTIONS WITH SOME CURING AGENTS MAY PRODUCE
CONSIDERAB
Hazardous Decomposition Products: CARBON MONOXIDE, ALDEHYDES, ACIDS, AND OTHER
TEMPERATURE DEGRADATION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL N OT OCCUR.
*
Toxicological Information
*
Toxicological Information: PRODUCT IS AN EPOXY RESIN PRODUCED BY THE
CONDENSATION REACTION OF EPICHLOROHYDRIN & BISPHENOL-A. THESE RAW
MATERIALS ARE CONSUMED IN THE PROCESS. RESIDUAL LEVELS OF EPICHLOROHYDRIN ARE
CONTROLLED TO 1 PPM. MA. IN THE PRODUCT. ACUTE TOXICITY DATA: ORAL (RAT)
BE RELEVANT DUE TO LOW VOLATILITY OF THE RESIN. CHRONIC STUDIES: RECENT
2-YEAR BIOASSAYS IN MICE EXPOSED BY THE DERMAL ROUTE TO THE DIGLYCIDYL ETHER
OF BISPHENOL-A RESIN (DGEBPA) OR TWO OTHER CO MMERCIAL RESINS WHICH ARE
(SARA)
*
Ecological Information
*
Ecological: KEEP OUT OF SURFACE WATERS, SEWERS AND WATERWAYS ENTERING OR
LEADING TO SURFACE WATERS. NOTIFY AUTHORITIES IF ANY EXPOSURE TO THE GENERAL
PUBLIC OR ENVIRONMENTAL OCCURS OR IS LIKELY TO OCCUR. IF THIS PRODUCT
REGULATIONS.
*
*
Transport Information: D.O.T. SHIPPING NAME: NOT A REGULATED MATERIAL.
TECHNICAL SHIPPING NAME: NONE ESTABLISHED. D.O.T. HAZARD CLASS: NONE
ESTABLISHED. UN/NA NUMBER: NONE ESTABLISHED. OTHER PRECAUTIONS (CONT'D):
CAUTION: M AY CAUSE IRRITATION. AVOID CONTACT WITH EYES. AVOID PROLONGED AND
REPEATED CONTACT WITH SKIN.
*
Regulatory Information
*
Sara Title III Information: N/P. TOXICOLOGICAL INFO (CONT'D): COMPOSED
PREDOMINANTLY OF DIGLYCIDYL ETHER OF BISPHENOL-A HAVE YIELDED VERY LITTLE
EVIDENCE OF WEAK CARCINOGENICITY. DGEBPA IS A COMPONENT OF THIS RESIN.
AUTHORS OF THIS WORK CONCLUDED THAT RENAL TUMOR EVIDENCE WITH THIS RESIN
"WAS OF NO BIOLOGICAL SIGNIFICANCE" & THAT THE RESIN "IS NOT A SYSTEMATIC
CARCINOGEN WHEN APPLIED TO DORSAL SKIN OF CF1 MICE." BASED UPON THIS &
ALL OTHER AVAILABLE INFORMATION. THE INTERNAL AGENCY FOR RESEARCH ON CANCER
GROUP 3) BASED ON THE FOLLOWING: HUMAN EVIDENCE - INADEQUATE: ANIMAL (FED
REG)
Federal Regulatory Information: ALL INGREDIENTS OF THIS COMPOUND ARE LISTED ON
THE EPA/TSCA INVENTORY OF CHEMICAL SUBSTANCES. PROTECTION OF STRATOSPHERIC
MANUFACTURES WITH ANY CLASS 1 OR CLASS 2 OZONE DEPLETING SUBSTANCES.SARA
(CONT'D): EVIDENCE -- INADEQUATE. MUTAGENICITY: DGEBPA (A COMP ONENT OF THIS
PRODUCT) HAVE PROVED TO BE INACTIVE WHEN TESTED BY IN VIVO MUTAGENICITY
ASSAYS. IT HAS SHOWN ACTIVITY BY IN VITRO MICROBIAL MUTAGENICITY SCREENING
& HAVE BOTH PRODUCED CHROMOSOMAL ABERRATIONS IN CULTURED RAT LIVER.
State Regulatory Information: N/P. FEDERAL REGS (CONT): THE SIGNIFICANCE OF
THIS INFORMATION TO MAN IS UNKOWN. EXPLOSION HAZARDS (CONT'D): CHARRING OF
THE REACTANTS. FUMES & VAPORS FROM THESE THERMAL & CHEMICAL
DECOMPOSITIONS VAR Y WIDELY IN COMPOSITION & TOXICITY. DO NOT BREATHE
FUMES. USE A NIOSH APPROVED RESPIRATOR AS REQUIRED TO PREVENT OVEREXPOSURE.
AN AIR-PURIFYING RESPIRATOR FOR ORGANIC VAPORS.
*
Other Information
*
Other Information: FIRST AID (CONT'D): IF CONTACT WITH HOT PRODUCT OCCURS
IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR, GIVE OXYGEN IF BREATHING IS DI
FFICULT. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. IN
GENERAL, NO TREATMENT IS NECESSARY UNLESS LARGE QUANTITIES OF PRODUCT ARE
INGESTED. HOWEVER, GET MEDICAL ADVICE. NOTE TO PHYSICIAN : IN GENERAL EMISIS
INDUCTION UNNECESSARY IN HIGH VISCOSITY, LOW VOLATILITY PRODUCTS, E.G., NEAT
EPOXY RESINS. : HEALTH -2, FLAMMABILITY-1, REACTIVITY-0. CHEMICAL FAMILY:
EPOXY RESIN.FORMULA: P ROPRIETARY/TRADE SECRET.
*
HAZCOM Label
*
Assigned IND: Y
Company Name: EPOXIES, ETC...
Label Required IND: Y
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: ACUTE: SKIN: BASED ON SIMILAR PROD TESTING PROD IS
MODERATELY IRRIT TO SKIN. BASED ON SIMILAR PROD TESTING PROD MAY CAUSE SKIN
SENSITIZATION. CONTACT W/PRODUCT AT ELEVATED TEMP CAN RESULT IN THERMAL B
URNS. EYES: BASED ON SIMILAR PRODTESTINGPROD IS MODERATELY IRRIT TO EYES.
CONTACT W/PROD AT ELEVATED TEMP CAN RESULT IN THERMAL BURNS. INHAL: BECAUSE
OF ITS LOW VOLATILITY THIS PROD IS NOT LIKELY TO B E AN INHAL HAZ. INGEST:
BASED ON PROD TESTING PROD IS CONSIDERED TO HAVE A LOW ORDER OF ACUTE ORAL
TOXICITY. SIGNS & SYMPTOMS: IRRITATION. CHRONIC: SKIN SENSITIZER
(ALLERGY) MAY BE EVIDENCED BY RASHES , ESPECIALLY HIVES.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED NUISANCE DUST RESPIRATOR IF >TLV
Ventilation:GENERAL MECHANICAL. LOCAL EXHAUST IF >TLV.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PORTLAND CEMENT
* Hazards Identification *
Effects of Overexposure:EYES IRRITATION. SKIN: MAY DEVELOP SUFFICIENT
HEAT CAUSE BURNS. DUST IS CONSIDERED A NUISANCE DUST
* First Aid Measures *
IF IRRITATION CONTINUES, SEE PHYSICIAN. INGESTION: GYPSUM CEMENT
HARDENS WHEN WETTED & IF INGESTED MAY RESULT IN OBSTRUCTION. SEE
PHYSICIAN .
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:NOT COMBUSTIBLE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP. AVOID CREATING EXCESSIVE DUST.
SLURRY MAY PLUG DRAINS.
*Handling and Storage *
Handling and Storage Precautions:DEW POINT CONDITIONS OR OTHER
CONDITIONS CAUSING PRESENCE OF LIQUID WATER DURING STORAGE WILL
RDEN GYPSUM CEMENT.
* Physical/Chemical Properties *
Spec Gravity:2.7
Solubility in Water:0.2%
Appearance and Odor:GRAY OR PIGMENTED POWDER. LOW ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:PER MFG NOT NECESSARY UNDER NORMAL CONDITIONS.
Ventilation:PER MFG NOT NECESSARY UNDER NORMAL CONDITONS.
Other Protective Equipment:FOR OPEN/LEAKING BATTERY:USE SAFETY GLASSES
Work Hygienic Practices:DON'T OBSTRUCT SAFETY RELEASE
VENTS.ENCAPSULATION(POTTING)WON'T ALLOW CELL VENTING & MAY CAUSE HI
PRES RUPTURE.
Supplemental Safety and Health
UNDER NORMAL USE, IT DOES NOT RELEASE OR OTHERWISE RESULT IN
EXPOSURE TO A HAZ CHEML. AS AN ARTICLE, BATTERY & CONTENTS NOT
SUBJECT TO REQMTS OF EMERG PLAN & COMM RIGHT-TO-KNOW ACT.
* Product Identification *
Product ID:CLASSIC, SUPER HEAVY DUTY, INDUSTRIAL BATTERY (CARBON-ZINC)
CAGE:0B0Y5
* Composition/Information on Ingredients *
Ingred Name:MANGANESE DIOXIDE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3 CEILING
ACGIH TLV:5 MG/M3 (AS MN DUST)
Ingred Name:MERCURY (SARA III)
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ZINC CHLORIDE (SARA III)
Fraction by Wt: 2-7%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3 (FUME)
Ingred Name:ZINC (SARA III)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTENTS OF OPENED BATTERY CAN CAUSE
SEVERE SKIN & EYE IRRIT, CHEMICAL EYE BURNS, RESPIR IRRT, AND
SERIOUS CHEMICAL BURNS FO MOUTH, ESOPHAGUS, & GASTROINTESTINAL
TRACT.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS BATTERY
ARE KNOWN OR SUSPECT CARCINOGENS.
Effects of Overexposure:EYE:IRRIT & CHEMICAL BURNS. SKIN:IRRIT.
INHAL:RESPIRATORY IRRIT. INGEST: SERIOUS CHEMICAL BURNS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST:DO;NOT INDUCE VOMITING NOR GIVE FOOD OR DRINK. SEEK
MED ATTN IMMED. CALL NATIONAL BATTERY INGESTION
CALL DOCTOR. SKIN:REMOVE CON TAMINATED CLOHTING. WASH SKIN W/SOAP &
WATER. IF IRRIT PERSISTS, SEEK MED ATTN. EYE:IMMED FLUSH EYEES
* Fire Fighting Measures *
Flash Point:NOT GIVEN
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:PERMISSIBLE TO USE ANY CLASS OF EXTINGUISHING
MEDIUM ON THESE BATTERIES OR THEIR PACKING MATERIAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL EXTERIOR IF
EXPOSED TO FIRE TO PREVENT RUPTURE.
Unusual Fire/Explosion Hazard:COMBUSTION/HEAT OF FIRE MAY PRODUCE HAZ
DECOMPOSITION PRODUCTS & VAPORS.NORMAL USE PRODUCES HYDROGEN WHICH
COMBINED W/OXY FROM AIR CAUSES COMBUS/EXP IF NOT VENT
* Accidental Release Measures *
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER. USE NEOPREN OR
HANDLING AN OPEN OR LEAKING BATTERY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:ACCIDENTAL SHORT CIRCUIT FOR FEW SECS
WILL NOT SERIOUSLY AFFECT BATTERY.PROLONGED SHORT CIRCUIT WILL
CAUSE LOSE OF ENERGY & MAY OPEN SAFETY RELEASE VE
Other Precautions:SHORT CIRCUITS SOURCES:JUMBLED BATTERIES IN BULK
CONTAINERS,METAL JEWELRY,METAL COVERED TABLES/METAL BELTS USED FOR
ASSY OF BATTERIES INTO DEVICES.FOR SOLDER/WELD TO BATTERY CONSULT
EVEREADY FOR PROPE R PRECAUTIONS TO PREVENT SEAL DAM/SHO CI
* Physical/Chemical Properties *
HCC:N1
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:NOT GIVEN
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BATTERY CELLS CAN SHORT CIRCUIT IN WATER OR IN CONTACT WITH METAL
OBJECTS (JEWELRY, OTHER BATTERIES, ETC.)
Stability Condition to Avoid:HIGH HEAT, PHYSICAL DAMAGE, CHARGING,
SHORT CIRCUITS, STATIC SPARKS, SOURCES OF IGNITION.
Hazardous Decomposition Products:COMBUSTIBLE PRODUCTS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN LANDFILL OR APPROPRIATE INCINERATION
FACILITY IAW ALL APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS.
DO NOT DISPOSE IN FIRE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ: MAY BE GENERATED BY THERMAL DECOMP/COMBUST. FLAM LIQ. CAN
RELEASE VAPS THAT FORM EXPLO MIXTS AT TEMPS ABOVE FLASH POINT.
MATLS TO AVOID: SODIUM HYPOCHLORITE). ACTIVE METALS (SUCH AS
POTASSI UM & MAGNESIUM). SUBSTANCE IS ALSO INCOMPATIBLE W/SPECIFIC
CHEMS INCL: ACETYL BROMIDE, ALKYL ALUMINUM SALTS, (ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SUP DAT: BERYLLIUM DIHYDRIDE, CARBON TETRACHLORIDE +
METALS, CHLOROFORM + HEAT, CHLOROFORM + SODIUM HYDROXIDE, (ING 3)
Ingred Name:ING 2: CYANURIC CHLORIDE, DIETHYL ZINC, NITRIC ACID, &
POTASSIUM TERTBUTOXIDE. PLEASE REFER TO THE NFPA FIRE (ING 4)
Ingred Name:ING 3: PROTECTION GUIDE FOR ALL SPECIFICS.
Ingred Name:EFTS OF OVEREXP: CHRONIC: PRLNG/RPTD SKIN CONT MAY CAUSE
DERM. CHRONIC INHAL & INGEST MAY CAUSE EFTS SIMILAR TO (ING 6)
Ingred Name:ING 5: THOSE OF ACUTE INHALATION AND INGESTION.
Ingred Name:FIRST AID PROC: INDUCE VOMIT BY GIVING 1 TEASPOON OF SYRUP
OF IPECAC. INHAL: GET MED AID IMMED. REMOVE FROM (ING 8)
Ingred Name:ING 7: EXPOS TO FRESH AIR IMMED. IF NOT BRTHG, GIVE ARTF
RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. NOTES TO MD: EFTS (ING 9)
Ingred Name:ING 8: MAY BE DELAYED. ETHANOL MAY INHIBIT METABOLISM.
ANTIDOTE: NO SPECIFIC ANTIDOTE EXISTS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: MOD IRRIT. VAPS MAY CAUSE
IRRIT. MAY CAUSE PAINFUL SENSIT TO LIGHT. SKIN: MAY CAUSE IRRIT.
MAY BE ABSORBED THRU SKIN IN HARMFUL AMTS. INGEST: MAY CAUSE IRRIT
OF DIGESTIVE TRACT. MAY CAUSE CNS DEPRESS, INCL EXCITEMENT,
FOLLOWEDBY HDCH, DIZZ, DROW, & NAUS. ADVANCED STAGES MAY CAUSE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: COLLAPSE, UNCON, COMA & POSS DEATH
DUE TO RESP FAILURE. MAY CAUSE KIDNEY FAILURE. INHAL: MAY CAUSE
RESP TRACT IRRIT, LIVER & KIDNEY DAMAGE, ADVERSE CNS EFTS INCLUDING
HDCH, CONVULSIONS, & PO SS DEATH. MAY CAUSE VISUAL IMPAIRMENT &POSS
PERM BLINDNESS, & EFTS SIMILAR TO THOSE DESCRIBED FOR INGEST. (ING
5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT
ALLOW VICTIM TO RUB/KEEP EYES CLOSED. SKIN: FLUSH W/PLENTY OF SOAP
SHOES. GET MED AID IF IRRIT DEVELOPS/PERSISTS. INGEST: IF CONSCIOUS
& ALERT, GIVE 2-4 CUPFULS OF MILK/WATER. GET MED AID IMMED. (ING 7)
* Fire Fighting Measures *
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEMICAL, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . USE WATER SPRAY TO COOL FIRE-EXPOSED CONTAINERS. WATER
MAY BE INEFFECTIVE.
Unusual Fire/Explosion Hazard:CONTRS CAN BUILD-UP PRESS IF EXPOSED TO
HEAT &/OR FIRE. VAPS CAN TRAVEL TO SOURCE OF IGNIT & FLASH BACK.
DURING FIRE, IRRITATING & HIGHLY TOX GASES (SUP DAT)
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERS PROT EQUIP AS INDICATED. SCOOP
UP W/NON-SPARKING TOOL, THEN PLACE INTO SUITABLE CONTR FOR DISP.
USE WATER SPRAY TO DISPERSE GAS/VAP. REMOVE SOURCES OF IGNIT.
ABSORB SPILL USING ABSORB,NON-COMBUST MATL SUCH AS EARTH,
SAND/VERMICULITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE W/ADEQUATE VENT. EMPTY CONTAINERS
RETAIN PROD RESIDUE (LIQUID, &/OR VAPOR), & CAN BE DANGEROUS. DO
NOT GET ON SKIN/IN EYES. DO NOT INGEST/INHALE.
Other Precautions:DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL,
GRIND/EXPOSE EMPTY CONTAINERS TO HEAT, SPARKS/OPEN FLAMES. KEEP
AWAY FROM SOURCES OF IGNITION. STORE IN COOL, DRY, WELL-VENTILATED
AREA AWAY FROM IN COMPATIBLE SUBSTANCES. FLAMMABLES-AREA.
* Physical/Chemical Properties *
Vapor Density:1.1
Evaporation Rate & Reference:5.2 (ETHER=1)
Solubility in Water:MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH SLIGHT ALCOHOL-LIKE
ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDANTS (SUCH AS BARIUM PERCHLORATE, BROMINE, CHLORINE, HYDROGEN
PEROXIDE, LEAD PERCHLORATE, PERCHLORIC ACID, (SUP DAT)
Stability Condition to Avoid:HIGH TEMPERATURES, INCOMPATIBLE MATERIALS,
IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
FORMALDEHYDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
(IGNITABLE WASTE). THIS MATERIAL IS BANNED FROM LAND DISPOSAL
ACCORDING TO RCRA.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
* Product Identification *
Preparer's Name:DOD HMIS/DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS, CHRYSOTILE
OSHA PEL:0.2 FIBERS/CC
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & STEEL COMPOSITION
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
*Handling and Storage *
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
* Physical/Chemical Properties *
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED USE A NIOSH APPROVED
RESPIRATOR OR SCBA.UUSE MECHANICAL FILTER TO REMOVE SOLID AIRBORNE
PARTICLES DURING SPRAY APPLICATION.
Ventilation:GENERAL MECHANICAL VENTILATION MAY BE SUFFICIENT TO KEEP
EXPOSURE BELOW TLV.USE ONLY W/ EXPLO PROOF VENT W/ FLAME MAT.
Other Protective Equipment:APRONS,EYES WASHES,SAFETY SHOWERS.
Work Hygienic Practices:OBSERVE GOOD WORK HYGIENE PRACTICES
Supplemental Safety and Health
SPREADING BURNING LIQUID WHICH MAY FLOAT & BURN ON TOP OF WATER
SURFACE.UNUSUAL FIRE & EXPLOSION HAZ:UP PRESSURE WHEN EXPOSED TO
HEAT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MINERAL SPIRITS
OSHA PEL:
ACGIH TLV:
Ingred Name:BENZENE (SARA III)
Fraction by Wt:
Other REC Limits:
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SEE SIGNS & SYMPTOMS OF OVEREXPOSURE.
Explanation of Carcinogenicity:BENZENE:NTP,KNOWN TO BE CARC;IARC,HUMAN
CARC GROUP 1;OSHA,SUBSTANCE REG AS CARC.ACGIH;SUSPECTED HUMAN
CARC(A2).
Effects of Overexposure:ACUTE:HEADACHE,NAUSEA,DIZZINESS,LASSITUDE,LOSS
OF COORDINATION OR CONSCIOUSNESS.CHRONIC:NONE RECOGNIZED.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR,GIVE ARTIFICIAL RESPIRATION IF
BREATHING HAS STOPPED.EYE:FLUSH EYES W/ COPIOUS AMOUNTS OF WATER
& SH OESS.INGEST:DO NOT INDUCE VOMITING.ASPIRATION OF VOMITUS MAY
RESULT IN CHEMICAL PNEUMONITIS AND/OR PULMONARY EDEMA,CALL A
PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:
Upper Limits:
Extinguishing Media:USE FOAM,DRY CHEMICAL OR CO*2.
Fire Fighting Procedures:SCBA RECOMMENDED.H*2O MAY BE UNSUITABLE AS AN
EXTINGUISHING MEDIUM,BUT HELPFUL IN COOLING CONTRS & SURFACES.NEVER
USE A DIRECT STREAM OF H*2O.USE H*2O(SUP DATA)
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR & MAY
ACCUMULATE IN LOW AREAS OF POOR VENT.VAPOR CAN TRAVEL ALONG GROUND
TO REMOTE IGNITION SITES.CLOSED CONTR.CAN BUILD (SUP DATA)
* Accidental Release Measures *
Spill Release Procedures:REMOVE SOURCES OF IGNITION,INCLUDING HOT METAL
SURFACES.CLEAN UP SPILL IMMEDIATELY BY SOAKING UP W/ ABSORBANTS
SUCH AS CLAY,SAND,DIATOMACEOUS EARTH,ETC.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP COOL,DRY,AND AWAY FROM IGNITION
SOURCES.STORE IN WELL VENTILATED AREA.
Other Precautions:AVOID PERSONAL CONTACT(SKIN,EYES,ETC.).USE W/
ADEQUATE VENT,DO NOT INHAL VAPORS. GROUND DRUMS WHEN POURING OR
OTHERWISE DISPENSING.DO NOT WELD,DRILL,CUT OR HEAT FULL,PARTIAL,OR
EVEN EMPTY CONTAINERS.
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:
Decomp Temp:Decomp Text:
Vapor Pres:
Vapor Density:HEAV.AIR
pH:
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:
Appearance and Odor:
Corrosion Rate:
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,STRONG ACIDS & BASES,SELECTED AMINES.
Stability Condition to Avoid:
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON
DIOXIDE,UNIDENTIFIED ORGANIC COMPOUNDS.
Conditions to Avoid Polymerization:HEAT,SPARKS,OPEN FLAME.
* Disposal Considerations *
Waste Disposal Methods:PLACE IN NON-LEAKING CONTAINERS AND DISPOSE OF
IN ACCORDANCE W/ APPLICABLE LOCAL,COUNTY,STATE & FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
Cage: SHELO
Proprietary Ind: Y
*
Contractor Summary
*
Cage: SHELO
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: MAY BE SEV IRRIT. SKIN: MAY BE SEV IRRIT. MAY CAUSE
SKIN SENSIT (ALLERGY) EVID BY RASHES, ESP HIVES. MAY BE TOX IF ABSORBED THRU
SKIN. INHAL: MAY CAUSE IRRIT TO NOSE, THROAT & RESP TRACT, ESP IF HEATED
OR IF MISTS ARE PRDCED. MAY CAUSE RESP TRACT SENSIT (E.G. ALLERGY, ASTHMA)
EVID BY WHEEZ WITH (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: SHORTNESS OF BREATH & COUGH.
INGEST: MAY BE TOX. ING 1 HAS CAUSED CANCER & PANCREATIC TOX IN LAB
ANIMALS IN 1 ORAL BIOASSAY. IT HAS CAUSED INCR INCIDENCE OF LIVER, THYROID
Medical Cond Aggravated By Exposure: PREEXISTING EYE, SKIN & RESP DISORDERS
MAY BE AGGRAVATED BY EXPOS TO PROD. PREEXISTING SKIN/LUNG ALLERGIES MAY INCR
CHANCE OF DEVELOPING INCREASED ALLERGY SYMPTOMS FROM EXPOS TO PROD. IMPAIRED
HOLDING LIDS OPEN. GET MED ATTN. SKIN: IMMED REMOVE CONTAMD CLTHG/SHOES. WIPE
IF AVAIL OR FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE CLTHG UNTIL
THORO CLEANED. GET MED ATTN. CONTAMD LEATHER ARTICLES, INCL SHOES, CANNOT BE
DECONTAMD & SHOULD BE DESTROYED
*
Handling and Disposal
*
Spill Release Procedures: MAY BURN ALTHOUGH NOT READILY IGNIT. USE CAUTIOUS
JUDGMENT WHEN CLEANING UP LG SPILLS. LG SPILLS:WEAR NIOSH/MSHA APPRVD RESP
& PROT CLTHG AS APPROP. SHUT OFF SOURCE OF LEAK IF SAFE TO DO SO. DIKE
& CO NTAIN. REMOVE W/VACUUM TRUCKS OR PUMP TO
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN COMPLIANCE
WITH FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY PLACE WITH ADEQUATE
VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES.
Other Precautions: HEATING THIS CURING AGENT IN PRESENCE OF AIR MAY CAUSE
THERMAL & OXIDATIVE DECOMP W/SOME EPOXY RESINS. IT MAY PRDCE EXOTHERMIC
RXNS WHICH IN LG MASSES CAN CAUSE RUNAWAY POLYM & CHARRING OF REACTANTS.
FUMES & VAPS FROM THESE THERMAL
*
Fire and Explosion Hazard Information
*
Flash Point Method: SCC
Extinguishing Media: USE WATER FOG, "ALCOHOL" FOAM, DRY CHEMICAL OR CARBON
DIOXIDE.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). MATERIAL WILL NOT BURN UNLESS PREHEATED. COOL FIRE EXPOSED
CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard: RAPID & HAZ POLYM MAY OCCUR UNDER FIRE
CNDTNS. CNTNRS EXPOS TO INTENSE HEAT FROM FIRES SHOULD BE COOLED W/WATER TO
PVNT VAP PRESS BUILDUP WHICH COULD (SUPDAT)
*
*
Respiratory Protection: AVOID BRTHG VAPORS/MISTS. IF EXPOS MAY OR DOES EXCEED
OCCUP EXPOS LIMITS, USE NIOSH/MSHA APPRVD RESP TO PVNT OVEREXP. IN ACCORD
-PURIFYING RESP FOR ORGANIC VAPORS.
Ventilation: USE VENTILATION AS REQUIRED TO CONTROL VAPOR CONCENTRATIONS.
Other Protective Equipment: AVOID CONTACT W/EYES, SKIN & CLTHG. WEAR PROT
CLTHG. EYE WASH FOUNTAINS & SAFETY SHOWERS SHOULD BE AVAIL FOR EMER USE.
Work Hygienic Practices: WASH W/SOAP & WATER BEFORE EATING, DRINKING, SMKNG,
APPLYING COSMETICS OR USING TOILET FACILITIES. LAUNDER
Supplemental Safety and Health: USERS OF "L" VERSION OF SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). EXPLO HAZ: RSLT IN CNTNR RUPTURE. CNTNR AREAS
EXPOS TO DIRECT FLAME CNTCT SHOULD BE COOLED W/LG QTYS OF WATER AS NEEDED TO
PVNT WEAKENING OF CNTNR STRUCTURE. DELAYED LUNG DMG (PULM EDEMA) CAN BE
EXPERIENCED AFTER EXPOS TO COMBUST
*
Physical/Chemical Properties
*
Solubility in Water: SLIGHT
Appearance and Odor: BROWN LIQUID.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: AVOID HEAT AND FLAME.
Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS SUCH AS
PEROXIDES. AVOID IRON, RUST & OXYGEN DEFICIENT ATMOSPHERES.
Hazardous Decomposition Products: NITROGEN OXIDES, CARBON MONOXIDE &
UNIDENTIFIED ORG CMPDS MAY BE FORMED DURING THERMAL OR OXIDATIVE DECOMP OR
COMBUST.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: AVOID HEAT, FLAME & CNTCT W/STRONG
OXIDIZING AGENTS SUCH AS PEROXIDES. AVOID IRON, RUST & OXYGEN DEFICIENT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Cage: SHELO
Assigned IND: Y
Company Name: SHELL OIL CO
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: COMBUSTIBLE. EXOTHERMIC REACTIONS IN LARGE MASSES.
ACUTE: EYES: MAY BE SEVERELY IRRITATING. SKIN: MAY BE SEVERELY IRRITATING.
MAY CAUSE SENSITIZATION WITH RASHES, ESPECIALLY HIVES. MAY BE TOXIC IF ABS
ORBED THROUGH THE SKIN. INHALATION: MAYCAUSE IRRITATION TO NSOE, THROAT &
RESPIRATORY TRACT. MAY CAUSE RESPIRATORY TRACT SENSITIZATIONEVIDENCED BY
WHEEZING WITH SHORTNESS OF BREATH AND COUGH. INGEST ION: MAY BE TOXIC IF
SWALLOWED. CHRONIC: DIETHYLTOLUENEDIAMINE HAS CAUSED CANCER AND PANCREATIC
TOXICITY IN LAB ANIMALS. ANIMAL STUDIES ALSO SHOW EFFECTS TO LIVER, THYROID,
PITUITARY, SPLEEN, KIDNEY, BONE MARROW, LYMPH SYSTEM.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS. USE
MECHANICAL FILTER RESPIRATOR OUTDOORS OR IN OPEN AREAS.
W/RESTRICTED VENTILATION USE CHEMICAL/MECHANICAL FILTER RESPIRATOR.
IN CONFINED ARAA USE AIR SUPPLY RES PIRATOR OR USE HOODS.
Ventilation:PROVIDE GENERAL DILUTION/LOCAL EXHAUST VENTILATION
SUFFICIENT TO KEEP AIR CONTAMINATION BELOW CURRENT STANDARDS.
Other Protective Equipment:SOLVENT IMPERMEABLE CLOTHING AND BOOTS TO
PREVENT SKIN CONTACT ARE RECOMMENDED.
Work Hygienic Practices:REMOVE AND WASH SOILED CLOTHING BEFORE REUSE.
WASH HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
DURING EMERGENCY CONDITIONS OVEREXPOSURE TO DICOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD. SYMPTOMS MAY NOT BE IMMEDIATELY APPARENT.
OBTAIN MEDICAL ATTENTION. MSDS ENTERED INTO THE HMIS BY DGSC AT
REQUEST OF GSA.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:AMINE COMPOUND
Ingred Name:N-BUTYL ALCOHOL (SARA III)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:SEE HEALTH HAZARDS.
CHRONIC:REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM
DAMAGE. PROLONGED OR REPEATED BREATHING O F SPRAY MIST AND/OR
SANDING DUST OVER APERIOD OF YEARS MAY CAUSE DUST DISEASE OF THE
LUNGS.
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS A CHEMICAL KNOWN
BY CALIFORNIA TO CAUSE CANCER, BIRTH DEFECTS OR REPRODUCTIVE HARM.
Effects of Overexposure:IRRITATION OF RESPIRATORY TRACT,HEADACHE,
NAUSEA,DIZZINESS,WEAKNESS,FATIGUE. EXTREME EXPOSURE CAN RESULT IN
UNCONSCIOUSNESS,RESPIRATORY ARREST. CAUSES EYE/SKIN IRRITATION. MAY
BE ABSORBED THROUGH SKIN . CAN CAUSE STOMACH &/OR INTESTINAL
IRRITATION, NAUSEA,VOMITING,DIARRHEA.
Medical Cond Aggravated by Exposure:NONE, WHEN USED IN ACCORDANCE WITH
SAFE HANDLING AND USE INFORMATION.
* First Aid Measures *
First Aid:IF IRRITATION OR SYMPTOMS PERSIST OR ARE SEVERE, SEE A
SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE
REUSE. INHALED:REM OVE TO FRESH AIR. AID/RESTORE BREATHINGIF
NECESSARY. INGESTED: GET IMMEDIATE MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1
Extinguishing Media:IN CASE OF FIRE USE CO2, DRY CHEMICAL, FOAM, OR
OTHER NFPA APPROVED METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT INCLUDING SCBA.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED,USE WATER FOG. USE
WATER TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:KEEP CONAITNERS TIGHTLY CLOSED. ISOLATE
FROM IGNITION SOURCES. CONTAINERS EXPOSED TO EXTREME HEAT MAY
EXPLODE. DO NOT WELD OR CUT CONTAINER. SEE SUPP DATA.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. PREVENT
BREATHING OF VAPORS. VENTILATE AREA. CONTAIN SPILLED MATERIAL &
REMOVE W/ INERT ABSORBENT & NON-SPARKING TOOLS. STORE CLOSED
CONTAINER UNTIL PROPERLY DISPOSED O F.
Neutralizing Agent:NO INFORMATION GIVEN BY MFR ON MSDS.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT/SPARKS/FLAME. DO
NOT SMOKE. PREVENT VAPOR BUILDUP BY A CONTINUOUS FLOW OF AIR. DO
Other Precautions:STORE LARGE QUANTITIES IN BUILDINGS PER OSHA
CONTAINERS. DO NOT PUT IN UNLABELED CONTAINERS. IF PRODUCT IS PART
OF A 2 PART SYSTEM, THE MIXTURE WILL HAVE HAZARDS OF BOTH PARTS!
* Physical/Chemical Properties *
HCC:F4
NRC/State Lic Num:NONE
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NO INFORMATION GIVEN BY MFR ON MSDS.
Hazardous Decomposition Products:MAY CAUSE TOXIC FUMES WHEN HEATED TO
DECOMPOSITION. FUMES MAY CONTAIN CARBON MONOXIDE, CARBON DIOXIDE
AND NOX.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR.
Ventilation:USE UNDER FUME HOOD.
FACESHIELD .
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR PROTECTIVE APRON.
Supplemental Safety and Health
* Product Identification *
Resp. Party Other MSDS Num.:PLMG2/CLMG2
Preparer's Name:SUSHA RAMANE
* Composition/Information on Ingredients *
Ingred Name:NITRIC ACID; (HNO*3)
Minumum % Wt:2.
Maxumum % Wt:5.
Other REC Limits:N/K
OSHA PEL:5 MG/M3;2 PPM
OSHA STEL:N/K
ACGIH TLV:5.2 MG/M3;2 PPM
Ingred Name:MAGNESIUM; (MG)
Minumum % Wt:.1
Maxumum % Wt:1.
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
Ingred Name:WATER
Other REC Limits:N/K
OSHA PEL:N/K
OSHA STEL:N/K
ACGIH TLV:N/K
ACGIH STEL:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CORROSIVE. HARMFUL BY INGESTION.
IRRITATING TO THE EYES AND SKIN UPON CONTACT.
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
First Aid:GENERAL: REMOVE CONTAMINATED CLOTHING, WASH THOROUGHLY BEFORE
LIFTING UPPER AND LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING
AND FLUSH WITH WATER THOROUGHLY. INHALATION: MOVE TO FRESH AIR.
CONSULT DOCTOR IF SYMPTOMS PERSIST. INGESTION: GET IMMEDIATE
MEDICAL HELP. IF THE PATIENT IS CONSCIOUS, GIVE LARGE QUANTITIES OF
WATER.
* Fire Fighting Measures *
Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:OXIDES OF NITROGEN CAN BE RELEASED IN
CASE OF FIRE. NOT EXPLOSIVE. NOT SELF-IGNITING.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT. DO
NOT ALLOW TO ENTER DRAINAGE SYSTEMS OR WATERWAYS. DILUTE SPILL WITH
WATER AND NEUTRALIZE WITH SODA ASH, LIMESTONE, ETC. WIPE UP AND PUT
INTO A SEALED CONT AINER FOR PROPER DISPOSAL. WASH SPILL SITE WITH
WATER AFTER MATERIAL PICK UP IS COMPLETE. WEAR CHEMICAL RESISTANT
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.
*Handling and Storage *
Handling and Storage Precautions:ENSURE GOOD VENTILATION/EXHAUSTION AT
WORK PLACE. HAVE AN IMMEDIATE AVAILABILITY OF AN EYE WASH IN CASE
OF EMERGENCY. STORE AT ROOM TEMPERATURE. KEEP THE CONTAINER TIGHTLY
CLOSED.
* Physical/Chemical Properties *
Spec Gravity:APPROXIMATELY 1.0
pH:1 TO 2
Solubility in Water:MISCIBLE
Appearance and Odor:TRANSPARENT LIQUID WITH ACRID ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS WITH STRONG ALKALI, VARIOUS METALS, AND ORGANIC SUBSTANCES.
Stability Condition to Avoid:STABLE UNDER NORMAL STORAGE AND USE.
Hazardous Decomposition Products:TOXIC FUMES UNDER CONDITIONS OF FIRE.
* Toxicological Information*
Toxicological Information:MAY PRODUCE CAUSTIC EFFECT ON SKIN, MUCOUS
MEMBRANES AND EYES. SWALLOWING WILL LEAD TO A STRONG CAUSTIC EFFECT
ON MOUTH AND THROAT AND TO THE DANGER OF PERFORATION OF ESOPHAGUS
AND STOMACH. THERE IS N O INFORMATION AVAILABLE ON THE HEALTH
HAZARDS OF MAGNESIUM. TOXICITY DATA: CONCENTRATED HNO*3 -
* Ecological Information *
Ecological:DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER BODIES OR
SEWAGE SYSTEM.
* Disposal Considerations *
Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE
DISPOSAL AGENCY FOR REGULATIONS. DISPOSE OF IN ACCORDANCE WITH
LOCAL, STATE, AND FEDERAL REGULATIONS .
* MSDS Transport Information *
GROUP: III; PROPER SHIPPING NAME: CORROSIVE LIQUID, ACIDIC,
INORGANIC, N.O.S. (NITRIC ACID SOLUTION).
* Regulatory Information *
SARA Title III Information:SUBJECT TO THE REPORTING REQUIREMENTS OF
Federal Regulatory Information:USA: COMPONENTS OF THIS SOLUTION ARE
REPORTED IN EPA TSCA INVENTORY LIST. WHMIS CLASSIFICATION (CANADA):
WITH EYES, RINSE IMMEDIATELY WITH PLENTY OF WATER AND SEEK MEDICAL
MEDICAL ADVICE IMMEDIATELY.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR NIOSH/MSHA APPRVD, PROPERLY FITTED ORG
VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN
EXPOS TO EXTREME HEAT. EXPLO HAZ: REQS SPEC PRECS. DURING EMER
CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE
I MMED APPARENT. OBTAIN MED ATTN. EFTS OFOVEREXP: W/PERM BRAIN &
NERVOUS SYS DMG. INTENTIONAL MISUSE BY DELIB (ING 6)
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: <5%
Ingred Name:2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT: CONCENTRATING & INHALING CONTENTS CAN BE
HARMFUL/FATAL.
Ingred Name:HNDLG/STOR PRECS: APPLIANCES & ANY OTHER SOURCES OF IGNIT.
CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING (ING 8)
Ingred Name:ING 7: PROCEDURES. KEEP CNTNR CLSD WHEN NOT IN USE.
TRANSFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. (ING
9)
Ingred Name:ING 8: DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF
CHILDREN.
Ingred Name:RESP PROT: GENERATED FROM THIS PRODUCT, UNDERLYING PAINT OR
ABRASIVE.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CNTCT DEPENDING ON CNDTNS OF USE. ALCOHOLS & ACETATES CAN BE
ABSORBED THRU SKIN. FOLLOW RECOMS FOR PROPER USE, VENT & PERSONAL
PROT EQUIP TO MIN EXPOS. IRRIT OF EYE S, SKIN & RESP SYS. MAY CAUSE
NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS
DEATH. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: HDCH, DIZZ, NAUS & LOSS OF
COORDINATION ARE INDICATIONS OF EXCESS EXPOS TO VAPS/SPRAY MISTS.
REDNESS & ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN
EXPOS. CHRONIC: PRLNG OVEREXP TO SO LV INGREDS MAY CAUSE ADVERSE
EFTS TO LIVER, URINARY & REPRO SYS. RPTS HAVE ASSOC RPTD & PRLNG
OVEREXP TO SOLVS (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN: WASH AFFECTED AREA THORO W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE REUSE. EYES: FLUSH EYES
ATTENTION. INGEST: NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. DO NOT INDUCE VOMITING. GIVE SEVERAL GLASSES OF WATER. SEEK
MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP WATER
SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF. WATER
MAY BE USED TO COOL CLSD CNTNRS (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. APPLICATN TO HOT SURFS (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CONTENTS ARE FLAMM. KEEP AWAY FROM
HEAT, SPKS & OPEN FLAME. DURING USE & UNTIL ALL VAPS ARE GONE: KEEP
AREA VENT. DO NOT SMOKE. EXTING ALL (ING 7)
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. AVOID BREATHING
VAPOR AND SPRAY MIST. AVOID CONTACT WITH SKIN AND EYES. WASH HANDS
AFTER USING.
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
* Disposal Considerations *
WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD CNTNR.
DISPOSE OF I/A/W FED, STATE & LOCAL REGS REGARDING POLLUTION.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NECESSARY WHEN HANDLING PART B BY ITSELF.
Ventilation:NORMAL ROOM VENTILATION
Work Hygienic Practices:USE NORMAL INDUSTRIAL HYGIENE PRACTICE. SEE P/N
IND A THIS NSN FOR PRECAUTIONS WHEN WORKING WITH COMPLETE KIT.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
Preparer's Name:AS
* Composition/Information on Ingredients *
Ingred Name:PHENOL POLYMER WITH FORMALDEHYDE
Ingred Name:4,4'-ISOPROPYLIDENEDIPHENOL EPICHLOROHYDRIN POLYMER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS IRRITATING. IT MAY ALSO
SENSITIZE SKIN ALLERGIES IN SOME PEOPLE AND/OR CONTRIBUTE TO KIDNEY
OR LIVER DAMAGE.
Explanation of Carcinogenicity:MFR LISTS FORMALDEHYDE IN INGREDIENT 1.
MFR STATES CONCENTRATION IS BELOW 0.1% & NO FREE FORMALDEHYDE WAS
FOUND IN TESTS
Effects of Overexposure:EYE:IRRITATION. SKIN:IRRITATION AND POSSIBLE
ALLERGIC DERMATITIS. INHALED:RESPIRATORY IRRITATION. INGESTED:G/I
IRRITATION,NAUSEA,VOMITING,ABDOMINAL PAIN. MAY CAUSE KIDNEY,LIVER
DAMAGE.
Medical Cond Aggravated by Exposure:NONE REPORTED.HMIS:EXPECT SKIN
ALLERGIES,KIDNEY OR LIVER DISORDERS TO BE AGGRAVATED.
* First Aid Measures *
INHALED:REMOVE FROM EXPOSURE. IF SYMPTOMS PERSIST OR PRODUCT IS
INGESTED,GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL,FOAM,WATER
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:SCOOP INTO CONTAINERS. CLEAN AREA WITH
SOLVENT.
Neutralizing Agent:1,1,1-TRICHLOROETHANE (SOLVENT)
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY AREA.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NEGLIGIBLE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:NONE REPORTED
Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION,SULFUR
OXIDES,HYDROGEN SULFIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
MFR STATES PRODUCT IS NOT A HAZARDOUS WASTE BY EPA DEFINITION.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF WORKPLACE EXPOSURE LIMITS OF PRODUCT OR ANY
COMPONENT IS EXCEEDED, NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR
IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA
REGULATIONS ALSO PERMIT OT HER NIOSH/MSHA RESPIRATORS (NEGATIVE
PRESSURE TYPE) UNDER SPECIFIED CONDITIONS. ENGINEERING OR
ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
RUBBER.
COMPLIANCE OSHA REGULATIONS
Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN
CONTACT, WEAR IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE AND
DISCARD CONTAMINATED SHOES
Supplemental Safety and Health
CYANIDE ANTIDOTE KITS ARE AVAILABLE BY PRESCRIPTION: TO OBTAINA KIT YOU
MUST 1-OBTAIN A PRESCRIPTION FROM PHYSICIAN, 2- GO TO LOCAL
PHARMACY & ORDER KIT, 3-PLACE KIT IN SAFETY OR FIRST AID KIT. KIT
WI LL HAVE EXPIRATION DATE-REPLACE BEFORE IT EXPIRES.
* Product Identification *
Product ID:SODIUM CYANIDE, CYANOBRIK
Preparer's Name:NOT PROVIDED.
CAGE:0YED2
* Composition/Information on Ingredients *
Ingred Name:SODIUM CYANIDE (SARA III)
Other REC Limits:5 MG/M3 AEL DUPONT
OSHA PEL:5 MG/M3 (CN)
ACGIH TLV:S; 5 MG/M3 (CN)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: CAN CAUSE SEVERE EYE IRRITATION.
CAN INJURE EYE TISSUE. SKIN: CAN CAUSE PERMANENT SKIN DAMAGE.
PASSAGE OF THIS MATERIAL INTO THE BODY THROUGH THE SKIN IS
POSSIBLE, AND SKIN CONTACT MAY BE HARMFUL . SWALLOWING: SWALLOWING
THIS MATERIAL MAY BE HARMFUL OR FATAL. INHALATION: THIS MATERIAL IS
A DUST OR MAY PRODUCE DUST. BREATHING THIS MATERIAL MAY BE HARMFUL
OR FATAL. SYMPTOMS USUALLY OCCUR AT AIR CONCENTRATIONS HIGHER THAN
THE RECOMMENDED EXPOSURE LIMITS.
Explanation of Carcinogenicity:NO DATA
Effects of Overexposure:EYE CONTACT: STINGING, TEARING, REDNESS, AND
SWELLING OF EYES. SKIN CONTACT: SYMPTOMS MAY INCLUDE REDNESS,
BURNING, AND SWELLING OF SKIN, BURNS, AND OTHER SKIN DAMAGE. SKIN
ABSORPTION/INHALATION/INGES TION: REDNESS OF FACE & NECK,
IRRITATION (NOSE/THROAT/AIRWAYS), HEADACHE, CENTRAL NERVOUS SYSTEM
EXCITATION (GIDDINESS, LIVLINESS, LIGHT-HEADED) FOLLOWED BY CENTRAL
NERVOUS SYSTEM DEPRESSION (DIZZINES S, DROWSINESS, WEAKNESS,
FATGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS), MUSCLE WEAKNESS,
EFEFCTS ON HEART & BREATHING RATE, CONFUSION, CYANOSIS, NARCOSIS,
CONVULSIONS, RESPIRATORY FAILURE, COMA, DEATH.
Medical Cond Aggravated by Exposure:EXPOSURE TO THIS MATERIAL MAY
AGGRAVATE ANY PREEXISTING CONDITION SENSITIVE TO A DECREASE IN
AVAILABLE OXYGEN, SUCH AS CHRONIC LUNG DISEASE, CORONARY ARTERY
DISEASE OR ANEMIAS.
* First Aid Measures *
LIDS APART. IF SYMPTOMS DEVELOP, IMMEDIATELY MOVE INDIVIDUAL AWAY
FROM EXPOSURE & INTO FRESH AIR BEFORE FLUSHING. SEEK IMMEDIATE
MEDICAL ATTE NTION. SKIN: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST
IMMEDIATE MEDICAL ATTENTION. SWALLOWING: SEEK MEDICAL ATTENTION. IF
INDIVIDUAL IS D ROWSY OR UNCONSCIOUS. NOTHING BY MOUTH. INHALATION:
REMOVE VICTIM FROM EXPOSURE AND INTO FRESH AIR. SEEK IMMEDIATE
MEDICAL ATTENTION.IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF
BREATHING DIFFICU LT, GIVE OXYGEN. SEE OTHER INFORMATION:
* Fire Fighting Measures *
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS WITH
A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WITH
APPROPRIATE TURN-OUT GEAR AND CHEMICAL RESISTANT PERSONAL
PROTECTIVE EQUIPMENT. REFER TO THE PERSONAL PROTECTIVE EQUIPMENT
SECTION OF THIS MSDS.
Unusual Fire/Explosion Hazard:DO NOT USE CARBON DIOXIDE. MAY REACT WITH
CYANIDE IN PRESENCE OF MOISTURE TO PRODUCE HCN. WATER MAY BE USED
ON FIRES NEAR CYANIDE, BUT SHOULD NOT BE USED IF CONTAINERS OPENED
OR BURNED. DISSOLVES READ ILY IN WATER. WATER RUNOFF FROM OPEN OR
BURNED CONTAINERS SHOULD BE CONTAINED TO AVOID ENVIRONMENTAL OR
SAFETY HAZARDS.
* Accidental Release Measures *
Spill Release Procedures:SMALL SPILL: SWEEP UP MATERIAL FOR DISPOSAL OR
RECOVERY. LARGE SPILL: USE PROTECTIVE CLOTHING AND DEVICES AS
REQUIRED. STOP SPILL AT SOURCE. SCOOP OR VACUUM TRANSFER SPILLED
PRODUCT TO CLEAN CONTAINER S FOR RECOVERY. SWEEP UP UNRECOVERABLE
PRODUCT. TRANSFER SWEEPINGS, CONTAMINATED SOIL, AND OTHER MATERIALS
TO CONTAINERS FOR DISPOSAL.
Neutralizing Agent:NO DATA PROVIDED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT
RESIDUES (VAPOR, LIQUID, AND/OR SOLID), ALL HAZARD PRECAUTIONS
GIVEN IN THE DATA SHEET MUST BE OBSERV ED.
Other Precautions:NO DATA PROVIDED BY MANUFACTURER
* Physical/Chemical Properties *
HCC:T2
Vapor Density:NIL
pH:NOT APPLICABLE.
Viscosity:NOT APPLICABLE.
Evaporation Rate & Reference:NOT APPLICABLE.
Appearance and Odor:WHITE SOLID BRIQUETTES. ODOR: NO DATA
Percent Volatiles by Volume:NO DATA
Corrosion Rate:N/P.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS VIOLENTLY WITH STRONG OXIDIZING AGENTS. WATER OR WEAK ALKALINE
SOLUTION CAN PRODUCE DANGEROUS AMOUNTS OF HCN IN CONFINED AREAS.
Stability Condition to Avoid:STABLE. LARGE AMOUNTS OF POISONOUS,
FLAMMABLE HYDROGEN CYANIDE (HCN) GAS WILL BE EVOLVED FROM CONTACT
WITH ACIDS.
Hazardous Decomposition Products:MAY FORM: HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:PRODUCT WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.
* Toxicological Information*
* Ecological Information *
MG/L, EXTREMELY TOXIC.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL REGULATIONS. FOR ASSISTANCE WITH YOUR
WASTE MANAGEMENT NEEDS - INCLUDING DISPOSAL, RECYCLING AND WASTE
STREAM REDUCTION, CONTACT A SHLAND DISTRIBUTION COMPANY, IC&S
* MSDS Transport Information *
* Regulatory Information *
YES. SARA EXTREMELY HAZARDOUS SUBSTANCE: YES. CERCLA: HAZARDOUS
SUBSTANCE: YES. SARA TOXIC CHEMICAL: YES.
Federal Regulatory Information:TSCA INVENTORY STATUS:
REPORTED/INCLUDED.
PENNSYLVANIA RTK LABEL INFORMATION: SODIUM CYANIDE (NA) (CN), CAS#
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED CHEMICAL-RESPIRATOR MASK
WHENEVER SPRAY APPLICATION IS TAKING PLACE.
Ventilation:GEN MECH: EXHAUST VENT CAPABLE OF MAINTAINING EMISSIONS AT
POINT OF USE BELOW PEL. LOC EXHAUST: OPEN DOORS (SUP DAT)
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER.
CHEM-RESIST APRON/COVERALLS MAY BE NEEDED IN HIGH SITUATIONS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRS AID PROC: INDUCE VOMIT! CALL POIS CTL CTR/MD IMMED. AVOID
ALCOHOLIC BEVERAGES. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS.
VENT: AND WINDOWS. IF USED IN ENCLOSED AREA, USE FANS TO REMOVE
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:2-BUTANONE, PEROXIDE; (METHYL ETHYL KETONE PEROXIDE) (MEKP)
(CERCLA)
OSHA PEL:C 0.7 PPM
ACGIH TLV:C 0.2 PPM
Ingred Name:2,4-PENTANEDIONE PEROXIDE; (ACETYL ACETONE PEROXIDE
SOLUTION WITH <= 9% BY WEIGHT ACTIVE OXYGEN)
OSHA PEL:N/K
ACGIH TLV:N/K
Fraction by Wt: 0-5%
OSHA PEL:1 PPM
ACGIH TLV:1 PPM
Ingred Name:2,4-PENTANEDIOL, 2-METHYL-; (HEXYLENE GLYCOL)
Ingred Name:FIRE RETARDANTS
Fraction by Wt: 5%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE IRRIT/BURNS OF
NOSE, THROAT, MOUTH, SNEEZING, COUGHING, SALIVATION, RESP DEPRESS,
HDCH, DIZZ, FAINTING, TREMORS, METABOLIC ACIDOSIS, COMA & DEATH.
SKIN: MAY CAUSE IRRIT, BURNS & DERM UPON CONT. MAY BE ABSORBED
THRU SKIN. EYES: MAY CAUSE IRRIT, OCULAR PAIN, IMMED CORNEAL DMG &
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: BLND UPON CONT. VAPS MAY CAUSE
TEARING & EYE IRRIT. INGEST: MAY CAUSE BURNS OF MOUTH, THROAT,
ESOPHAGUS & GI TRACT. LGE INGEST OF HEXYLENE GLYCOL MAY CAUSE
KIDNEY DMG. TARGET ORGANS: CNS, EY E, SKIN, LUNG, KIDNEY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:SKIN: FLUSH W/WATER, THEN WASH THORO W/SOAP & WATER. REMOVE
CONTAM CLTHG & WASH BEFORE REUSE. CALL POIS CTL CTE/MD IF IRRIT
CTR/MD IF IRRIT PERSISTS. INHAL: MOVE TO FRESH AIR. IF BRTHG IS
DFCLT, GIVE OXYGEN. IF NOT BRTHG, GIVE ARTF RESP. KEEP VICTIM QUIET
& WARM. CALL POIS CTL CTR/MD IMMED. INGEST: DRINK WATER. DO NOT
(SUP DAT)
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:FOR SML FIRES: DRY CHEMICAL, CARBON DIOXIDE, WATER
OR FOAM EXTINGUISHER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . FOR LGE FIRES: EVACUATE AREA AND CALL FIRE
DEPARTMENT IMMEDIATELY.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA, STOP LEAK IF IT CAN BE DONE
WITHOUT RISK. TAKE UP WITH SAND, EARTH OR OTHER ABSORBING MATERIAL
AND PLACE IN A CLEAN, DRY LEAD-PROOF CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, FLAMES.
IRON & RUB SHOULD NOT BE IN CONT W/HARDENER.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:DECOMPOSES
Appearance and Odor:CLEAN, COLORLESS LIQUID WITH SLIGHT ACRID ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
STRONG REDUCING AGENTS, ACCELERATORS.
Stability Condition to Avoid:CONTAMINATION AND THERMAL DECOMPOSITION.
Hazardous Decomposition Products:NOT DETERMINED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AVOID PROLONGED BREATHING OF VAPOR. USE
APPROPRIATE NIOSH-APPROVED RESPIRATORY PROTECTION, WHEN NECESSARY.
USE SUPPLIED-AIR RESPIRATORY PROTECTION IN CONFINED OR ENCLOSED
SPACES.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS.
Other Protective Equipment:CHEMICAL-RESISTANT APRON OR OTHER IMPERVIOUS
CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING THIS MATERIAL.
Supplemental Safety and Health
NONE
* Product Identification *
Product ID:NUMBER 2 DIESEL FUEL/ NUMBER 2 HEATING OIL
Preparer's Name:J.L. JACKSON
* Composition/Information on Ingredients *
Ingred Name:HYDROCARBONS
Other REC Limits: SPECIFIED
Ingred Name:NAPHTHALENE (SARA III)
Fraction by Wt: 3%
Other REC Limits: SPECIFIED
Ingred Name:BENZENE (SARA III)
Fraction by Wt: 0 - 5%
Other REC Limits: SPECIFIED
Ingred Name:HEXANE (N-HEXANE)
Fraction by Wt: 0 - 5%
Other REC Limits: SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TOLUENE (SARA III)
Other REC Limits: SPECIFIED
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Fraction by Wt: 0 - 5%
Other REC Limits: SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: MINOR
IRRITATION FOLLOWING PROLONGED OR FREQUENTLY REPEATED CONTACT.
INHALATION: CENTRAL NERVOUS SYSTEM EFFECTS. INGESTION: LOW ORDER
OF TOXICITY, BUT MINUTE AMOUNTS ASPIRAT ED INTO THE LUNGS DURING
INGESTION MAY CAUSE SEVERE PULMONARY INJURY OR DEATH.
Explanation of Carcinogenicity:THIS MATERIAL CONTAINS BENZENE.
Effects of Overexposure:CENTRAL NERVOUS SYSTEM EFFECTS INCLUDE
WEAKNESS, HEADACHE, NAUSEA, CONFUSION, BLURRED VISION, DROWSINESS,
DIZZINESS, SLURRED SPEECH, FLUSHED FACE, UNCONSCIOUSNESS OR
CONVULSIONS.
Medical Cond Aggravated by Exposure: SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MINUTES. SKIN: IMMEDIATELY WASH SKIN THOROUGHLY WITH SOAP AND
PLENTY OF WATER. LAUNDER CONTAMINATED CLOTHING. INHALATION: REMOVE
TO FRES H AIR AND CALL A PHYSICIAN IMMEDIATELY. INGESTION: DO NOT
INDUCE VOMITING. CALL A PHYSICIAN IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:0.4
Upper Limits:6
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR WATER SPRAY,
AND VAPORIZING LIQUIDS.
Fire Fighting Procedures:USE WATER TO COOL FIRE EXPOSED CONTAINERS. USE
WATER TO DISPERSE VAPORS. DO NOT ENTER AN ENCLOSED OR CONFINED
SPACE WITH OUT PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:PRODUCT IS COMBUSTIBLE. VAPORS CAN
EXPLODE. LIQUID EVAPORATES AND FORMS VAPORS WHICH CAN SPREAD EASILY
AND CAN BE SET ON FIRE BY MANY SOURCES.
* Accidental Release Measures *
Spill Release Procedures:THIS MATERIAL IS COMBUSTIBLE. CONTAIN SPILL
IMMEDIATELY IN SMALLEST POSSIBLE AREA USING ABSORBENT BOOMS, DIKING
OR IMPOUNDING. ADD SAND, CLAY, DIATOMACEOUS EARTH OR SUITABLE
ABSORBENT TO SPILL AREA.
Neutralizing Agent: SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN ACCORDANCE WITH NATIONAL FIRE
PROTECTION ASSOCIATION REGULATIONS.
Other Precautions:DO NOT WELD, HEAT OR DRILL EMPTY CONTAINERS. THIS
PRODUCT IS NOT TO BE USED AS AN APPLIANCE FUEL.
* Physical/Chemical Properties *
HCC:V4
Vapor Pres:0
Spec Gravity:0.8
Solubility in Water:INSOLUBLE
Appearance and Odor:STRAW YELLOW LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:UNDUE EXPOSURE TO AIR, HEAT, AND FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH APPLICABLE LOCAL,
STATE, AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IT IS ESSENTIAL TO CONTROL ENVIRONMENTAL
CONCENTRATIONS BELOW APPLICABLE STANDARDS WHEN USING THIS MATERIAL.
RESPIRATORY PROTECTION IS REQUIRED. USE ONLY NIOSH/MSHA APPROVED
Ventilation:PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT
BUILD-UP OF VAPORS. USE EXPLOSION-PROOF EQUIPMENT.
Other Protective Equipment:EYE WASH, SAFETY SHOWER, IMPERVIOUS
CLOTHING, FACE SHIELD, APRON, BOOTS.
Work Hygienic Practices:AVOID CONDITIONS WHICH FORM INHALABLE PARTICLES
SUCH AS SPRAYING OR ABRADING/SANDING PAINTED SURFACES. WEAR CLEAN
WORK CLOTHES DAILY.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:FATTY ACIDS, TALL-OIL, POLYMERS WITH GLYCEROL,
PENTAERYTHRITOL AND PHTHALIC ANHYDRIDE
Ingred Name:BENZENE
Maxumum % Wt:.1
OSHA PEL:1 PPM
OSHA STEL:5 PPM
Ingred Name:STODDARD SOLVENT
Ingred Name:CASTOR OIL DERIVATIVE/CLAY COMPLEX
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:HEXANOIC ACID, 2-ETHYL-, COBALT(2+) SALT
Minumum % Wt:.1
Maxumum % Wt:1.
Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROM.
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:TITANIUM OXIDE
Ingred Name:SOLVENT NAPHTHA (PETROLEUM), MEDIUM ALIPH.
Minumum % Wt:5.
Ingred Name:ALKYD RESIN
Minumum % Wt:5.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:PROLONGED INHALATION MAY LEAD TO
FLU-LIKE SYMPTOMS, COUGHING, SNEEZING, NUMBNESS, CNS DEPRESSION,
RESPIRATORY PROBLEMS, INTOXICATION, CONFUSION, ANESTHETIC EFFECTS
OR NARCOSIS. ASPIRATION OF MATERIAL INTO LUNGS MAY CAUSE LUNG
IRRITATION OR DAMAGE, PULMONARY EDEMA, CONVULSIONS, PNEUMOCONIOSIS,
LOSS OF CONSCIOUSNESS, ASPHYXIATION, DEATH. EXCESSIVE INHALATION OF
FUMES MAY LEAD TO METAL FUME FEVER. RE PORTS HAVE ASSOCIATED
REPEATED & PROLONGED OCCUPACTIONAL OVEREXPOSURE TO SOLVENTS
W/PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING THE CONTENTS MA Y BE HARMFUL
OR FATAL.
Explanation of Carcinogenicity:BENZENE IS CONSIDERED CARCINOGENIC BY
NTP, IARC AND OSHA. HEXANOIC ACID, 2-ETHYL-, COBALT(2+) SALT IS
CONSIDERED CARCINOGENIC BY IARC.
Effects of Overexposure:INHALATION:IRRITATION OF RESPIRATORY
TRACT,LUNGS. PROLONGED INHALATION MAY LEAD TO LOSS OF
APPETITE,MUCOUS MEMBRANE IRRITATION,FATIGUE,DROWSINESS,DIZZINESS
AND/OR LIGHTHEADEDNESS,HEADACHE,UNCOORDINATI
ON,NAUSEA,VOMITING,DIARRHEA. SKIN:IRRITATION OF SKIN.
DERMATITIS,DEFATTING,ALLERGIC RESPONSE,SEVERE SKIN IRRITATION OR
BURNS. EYE:IRRITATION OF EYES. CAN CAUSE CONJUNCTIVITIS,BLURRED
VISION,TEARING OF EYES,REDNESS OF EYES,SEVERE EYE IRRITATION.
INGESTION:LUNG INFLAMMATION AND DAMAGE DUE TO ASPIRATION OF
MATERIAL INTO LUNGS,MOUTH AND THROAT IRRITATION,MUCOUS MEMBRANE
IRRITATION.
Medical Cond Aggravated by Exposure:EYE, SKIN, RESPIRATORY DISORDERS,
LUNG DISORDERS, ASTHMA-LIKE CONDITIONS, KIDNEY DISORDERS, LIVER
DISORDERS, NERVOUS SYSTEM DISORDERS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT
CONTINUED BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY.
SKIN: FLUSH WITH SKIN FROM WATER. THEN WASH THOROUGHLY WITH SOAP
AND WATER. REMO VE CONTAMINATED CLOTHING. EYE: FLUSH IMMEDIATELY
MINUTES. IN ALL CASES, SEEK MEDICAL ATTENTION IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL OR FOAM WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures:WATER MAY BE USED TO COOL AND PROTECT EXPOSED
CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE
PROTECTION, AND SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT OR FIRE. VAPORS ARE HEAVIER THAN AIR AND
MAY TRAVEL LONG DISTANCES TO A SOURCE OF IGNITION AND FLASH BACK.
VAPORS CAN FORM EXPLOSIVE MIXTURESIN AIR AT ELEVATED
TEMPERATURES. CLOSED CONTAINERS MAY BURST IF EXPOSED TO EXTREME
HEAT OR FIRE.
* Accidental Release Measures *
Spill Release Procedures:COMPLY WITH ALL APPLICABLE HEALTH AND
ENVIRONMENTAL REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION.
VENTILATE AREA W/ EXPLOSION-PROOF EQUIPMENT. SPILLS MAY BE
COLLECTED W/ABSORBENT MATERIALS. EVACUATE ALL UNNECESSARY
PERSONNEL. PLACE COLLECTED MATERIAL IN PROPER CONTAINER. USE
PERSONAL PROTECTIVE EQUIPMENT. PUMP TO STORAGE OR SALVAGE VESSELS.
USE ABSORBENT TO PICK UP RESIDUE & DISPOSE.
*Handling and Storage *
HEAT, SPARKS AND OPEN FLAME. EMPTY CONTAINERS MAY CONTAIN HAZARDOUS
RESIDUES. GROUND EQUIPMENT WHEN TRANSFERRING TO PREVENT
ACCUMULATION OF STATIC CHARGE. AVOID SPONTANEOUS COMBUSTION OF
CONTAMINATED RAGS & OTHER EASILY IGNITABLE ORGANIC ACCUMULATIONS.
Other Precautions:USE ONLY WITH ADEQUATE VENTILATION. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN
AND EYES, AND BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER
HANDLING, ESPECIALLY B EFORE EATING OR SMOKING. KEEP CONTAINERS
TIGHTLY CLOSED AND UPRIGHT WHEN NOT IN USE.
* Physical/Chemical Properties *
Appearance and Odor:PASTEL TINT BASE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, BASES, HALOGENS, AMINES, CARBON TETRACHLORIDE,
ALUMINUM, ZINC, HYPOCHLORITES, PEROXIDES, NITRIC ACID, HYDROFLUORIC
ACID, METAL COMPOUNDS, HYDROGEN FLUORIDE, MAGNESIUM, SODIUM,
POTASSIUM.
Stability Condition to Avoid:ELEVATED TEMPERATURES, MOISTURE, CONTACT
WITH OXIDIZING AGENT, CONTACT WITH ALUMINUM OR ZINC, STORAGE NEAR
ACIDS, SPARKS, OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN, ACRID FUMES, ACROLEIN, OXIDES OF SULFUR,
AMMONIA, OXYGEN, HYDROGEN CHLORIDE, ALDEHYDES, TOXIC GASES, SMOKE
AND SOOT.
* Toxicological Information*
Toxicological Information:OTHER EFFECTS OF OVEREXPOSURE MAY INCLUDE
TOXICITY TO LIVER, KIDNEY, LUNGS, BLOOD, HEART, PANCREAS. MAY BE
ABSORBED THROUGH SKIN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
* MSDS Transport Information *
* Regulatory Information *
SARA Title III Information:NONE
Federal Regulatory Information:CERCLA: BENZENE
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER, EYE BATH
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:CHLOROFORM (TRICHLOROMETHANE)(ANIMAL CARCINOGEN BY IARC -
OSHA PEL:2 PPM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF INHALED,
SWALLOWED/ABSORBED THROUGH SKIN. MAY BE IRRITATING TO EYES, MUCOUS
MEMBRANES & UPPER RESPIRATORY TRACT. CAUSE SKIN
IRRITATION/ABSORPTION. NERVOUS SYSTEM DISTURBANCES. MAY ALTE R
GENETIC MATERIAL. MAY AFFECT THE NERVES, HEART, LIVER & KIDNEYS.
HIGHLY TOXIC. MAY CAUSE CANCER.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, NAUSEA, DIZZINESS, HEADACHE,
NERVOUS SYSTEM DISTURBANCES
* First Aid Measures *
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
NECESSARY. INGESTION: WASH OUT MOUTH W/WATER IF CONSCIOUS. OBTAIN
MEDICAL ATTEN TION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING
FIRE CONDITIONS.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. WEAR SELF CONTAINED BREATHING
SAND/VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL.
VENTILATE AREA & WASH SITE AFTER MATER IAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. KEEP
EYE/FACE PROTECTION.
Other Precautions:DON'T BREATHE VAPOR. AVOID ALL CONTACT. DON'T GET IN
EYES, ON SKIN/ON CLOTHING.
* Physical/Chemical Properties *
Vapor Density:4.1
Appearance and Odor:LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BASES, ALUMINUM
Stability Condition to Avoid:FIRE, SENSITIVE TO LIGHT
Hazardous Decomposition Products:HYDROGEN CHLORIDE GAS, PHOSGENE GAS,
CO, CO2
* Disposal Considerations *
Waste Disposal Methods:SHOULD BE IGNITED IN PRESENCE OF SODIUM
CARBONATE & SLAKED LIME; MIXED W/VERMICULITE, THEN W/THE DRY
CAUSTICS, WRAPPED IN PAPER & BURNED IN A CHEMICAL INCINERATOR
EQUIPPED W/AN AFTERBURNER/SCRUBBER. D ISPOSE OF IAW/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED, NIOSH APPRVD DUST/MIST RESP
RESP SUPPLIER FOR LIMITATIONS. ALTERNATIVELY, A NIOSH APPRVD
SUPPLIED AIR FULL FACE RE SP/AIRLINED HOOD MAY BE WORN.
Ventilation:SYS OF LOCAL &/OR GEN EXHAUST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHAUST VENT IS (SUPDAT)
LAB COAT, APRON/COVERALLS. ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. CONTACT LENSES
SHOULD NOT BE WORN WHEN WORKING WITH THIS MATERIAL.
Supplemental Safety and Health
* Product Identification *
Product ID:SODIUM NITROFERRICYANIDE
* Composition/Information on Ingredients *
Ingred Name:FERRATE(2-),PENTACYANONITROSYL-,DISODIUM,DIHYDRATE; (SODIUM
NITROFERRICYANIDE,DIHYDRATE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FERRATE (2-), PENTACYANONITROSYL-, DISODIUM; (SODIUM
NITROFERRICYANIDE (ANHYDROUS))
OSHA PEL:5 MG/M3 (CYANIDES)
ACGIH TLV:S, 5 MG/M3 CYANIDES
Ingred Name:SUPDAT:INTO THE GENERAL WORK AREA. PLEASE REFER TO ACGIH
DOCUMENT "INDUST VENT, A MANUAL OF RECOMMENDED (ING 4)
Fraction by Wt: 5%
Ingred Name:ING 3:PRACTICES", MOST RECENT EDITION, FOR DETAILS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:MAY CAUSE IRRIT TO RESP
TRACT & SYSTEMIC POISONING W/SYMPS PARALLELING INGEST.
INGESTION:TOXIC EFTS MAY BE SIMILAR TO NITRITE POISONING; SYMPS MAY
INCL HDCH, FLUSHING OF SKIN, VOMIT, COLIC & DIARR, MUSCULAR WEAK,
DIZZ, COLLAPSE, FALL IN BLOOD PRESS, CYANOSIS, CONVLS, COMA, RESP
PARALYSIS, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:DEATH DUE TO CIRCULATORY COLLAPSE. IT
HAS BEEN SUGGESTED THIS MATL MAY RELEASE CYANIDE IN SOME CASES.
SKIN:MAY CAUSE IRRIT, REDNESS, & PAIN. MAY BE ABSORBED THRU SKIN,
CAUSING SYSTEMIC POISON ING W/SYMPS PARALLELING INGEST.
EYE:MAYCAUSE IRRIT, REDNESS, & PAIN. CHRONIC:RPTD, PRLNGD EXPOSURE
THRU ANY (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE OXYG. CALL PHYS. INGEST:INDUCE VOMIT IMMED BY
GIVING 2 GLASSES OF WATER & STICKING FINGER DOWN THROAT. NEVER GIVE
ANYTH ING BY MOUTH TO UNCON PERSON. CALL PHYSIMMED. SKIN:IMMED
CLTHG & SHOES. CALL PHYS. EYE:WASH W/PLENTY OF WATER FOR AT LEAST
(SUPDAT)
* Fire Fighting Measures *
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE OR EXPLOSION
HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. CLEAN-UP
PERSONNEL MAY REQUIRE RESPIRATORY PROT FROM DUST. SPILLS:SWEEP UP &
CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET SWEEPING
MAY BE USED TO AVOID D UST DISPERSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR, STORED IN
COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DMG.
Other Precautions:WARNING! HARMFUL IF SWALLOWED, INHALED/ABSORBED THRU
SKIN. AVOID BRTHG DUST. AVOID CONT W/EYES, SKIN & CLTHG. KEEP CNTNR
CLSD. USE WITH ADEQUATE VENTILATION.
LIFTING LOWER & UPPER EYELIDS OCCASNLY. GET MED ATTN IMMED. VENT:G
ENERALLY PREFERRED BECAUSE IT CAN CONTROL EMISSIONS OF CONTAMINANT
@ ITS SOURCE, PREVENTING DISPERSION OF IT (ING 3)
* Physical/Chemical Properties *
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:SUPP DATA
Appearance and Odor:RED TRANSPARENT CRYSTALS, ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NO DATA FOUND.
Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE
AND STORAGE.
Hazardous Decomposition Products:EMITS TOXIC FUMES OF NITROGEN OXIDES,
CYANIDE AND SODIUM OXIDE WHEN HEATED TO DECOMPOSITION.
* Disposal Considerations *
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE
DELIVERED TO AN APPROVED WASTE DISPOSAL FACILITY. ENSURE COMPLIANCE
WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF THE OSHA-PEL IS EXCEEDED, A NIOSH APPROVED
RESPIRATOR WITH SUPPLIED AIR IS REQUIRED.
Ventilation:LOCAL EXHUAST-REQUIRED. MECHANICAL-AS A SUPPLEMENT TO THE
LOCAL EXHAUST SYSTEM.
Other Protective Equipment:RUBBER APRON, RUBBER BOOTS, EYEWASH, SAFETY
SHIWER.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:EDWARD DOHENY
CAGE:GREA1
CAGE:GREA1
CAGE:1CVE8
* Composition/Information on Ingredients *
Ingred Name:NITRIC ACID (SARA III)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 PPM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE-"DANGER" CORROSIVE. SKIN"DANGER"
CORROSIVE. INHALATION-HRAMFUL IF INHALED. INGESTION-HARMFUL IF
SWALLOWED.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:SKIN IRRITATION/BURNS, EYE IRRITATION/BURNS,
RESPRIATORY TRACT IRRITATION, GI TRACT DAMAGE.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:EYES-IMMEDIATELY FLUSH WITH PLENTY OF CLEAN WATER FOR AT
PHYSICIAN INTERNAL-D O NOT INDUCE VOMITING. IMMEDIATELY DRINK A
LAREG QUANTITY OF MILK OR WATER ABD CALL A PHYSICIAN.
INHALATION-IMMEIDTAELY MOVE TO FRESH AIR. IF NOT BREATHING PERFORM
CPR. IF HARD BREATHE, GIVE OXYGEN.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER, FOAM, CARBON DIOXIDE AND DRY CHEMICAL.
Fire Fighting Procedures:WHEN FIRE FIHJTING, WEAR FULL PROTECTIVE
EQUIPMENT INCLUDING SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:WILL PRODUCE HAZARDOUS FUMES & HAZARDOUS
DECOMPOSITION PRODUCTS. OXIDIZER! WILL SUPPORT COMBUSTION & CAN
INCREASE THE FLAMMIBILITY OF COMBUSTIBLES, ETC.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL. WEARING RECOMMENDED PROTECTIVE
EQUIPMENT, CAREFULLY ADD LIME OR SODIUM BICARBONATE TO NEUTRALIZE
SPILL AREA. PICK UP & CONTAINERIZE RESIDUES FOR DISPOSAL. FLUSH
AREA WITH WATER; COLLECT RINSATES FOR DISPOSAL OR SEWER, AS
APPROPIATE.
Neutralizing Agent:LIME OR SODIUM BICARBONATE.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED.
Other Precautions:FOR INDUSTRIAL USE ONLY. KEEP OUT OF REACH OF
CHILDREN. DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. USE ONLY WITH
ADEQUATE VENTILATION.
* Physical/Chemical Properties *
HCC:C1
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
pH:<1.0
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS TO PALE YELLOW LIQUID WITH A SHARP
ACIDIC ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALKALI, OXIDIZABLE ORGANICS, OTHER OXIDIZERS, CHLORINE RELEASERS,
SULFUR, SUIFIDES, CYANIDES, ALUMINUM, MAGNESEIUM AND .
Stability Condition to Avoid:
Hazardous Decomposition Products:WHEN HEATED TO DECOMPOSITION, IT EMITS
TOXC NITRIC ACID FUMES AND TOXIC OXIDES OF NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF PRODUCT IN A LECENSED HAZARDOUS WASTE
DISPOSAL FACILITY IN ACCORDANCE WITH ALL APPLICABLE LAWS. WHEN
EMPTY THOROUGHLY RINSE CONTAINER WITH WATER BEFORE DISPOSAL, RETURN
TO MANUFACTURER OR A NY OTHER INDUSTRIAL USE.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF WORKPLACE EXPOS LIMIT(S) OF PROD/ANY
COMPONENT IS EXCEEDED, A NIOSH/MSHA APPRVD AIR-SUPP RESP IS ADVISED
IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT OTHER
NIOSH/MSHA APPRVD RESP (NEG PR ESS TYPE) UNDER SPECIFIED (SUPP
DATA)
Ventilation:MATL MUST BE HNDLD OR TRANSFERRED IN APPRVD FUME HOOD OR
W/EQUIVALENT VENTILATION.
Other Protective Equipment:PROTECTIVE CLOTHING. EMERGENCY EYEWASH &
DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP: FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY/CHRONICALLY
EXPOSED TO CHLOROCARBONS . HNDLG/STOR PREC: OR ON CLTHG. DO NOT
TAKE INTERNALLY. EMPTY CONTRS MAY BE HAZ DUE TO RETAINED R ESIDUE;
USE CAUTION. RESP PROT: CNDTNS.ENGINEERING &/OR ADMINISTRATIVE
CONTROLS SHLD BE IMPLEMENTED TO REDUCE EXPOSURE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:METHYLENE CHLORIDE(SARA III)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGEST: TOXIC. MAY CAUSE IRRIT OF THE
GI TRACT W/VOMIT. IF VOMIT OCCURS, METHYLENE CHLORIDE CAN BE
ASPIRATED INTO THE LUNGS WHICH CAN CAUSE CHEM PNEUM/SYSTEMIC EFT.
INHAL: TOXIC. INHAL OF HIGH VAP CON C CAUSES
DIZZ/NAUS/HDACH/NARCOSIS/IRREGULAR HEART BEATS/COMA & DEATH.
EYE/SKIN: IRRIT ON CONT W/SKIN, (EFT OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: GROUP 2B(IARC),
GROUP 2(NTP).
Effects of Overexposure:HLTH HAZ: EYES OR MUC MEMB. MAY CAUSE EYE
INJURY. EXCESSIVE EXPOS MAY CAUSE BLOOD DEFECTS & CAN AFFECT
LIVER/KIDNEYS/CNS. CHLOROCARBON MATLS HAVE PRDCED SENSIT OF THE
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & MAY HAVE A SIMILAR EFT
IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT (SUPP DATA)
Medical Cond Aggravated by Exposure:HEART, KIDNEY & LIVER CONDITIONS.
* First Aid Measures *
First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURES. SKIN:
WASH THOROUGHLY W/SOAP & WATER. EYES: IMMED FLUSH THOROUGHLY
GIVE ARTF RES P IF BREATHING HAS STOPPED. INGEST: DO NOT INDUCE
VOMITING. GET IMMED MED ATTN.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FORMS FLAMMABLE VAPOR-AIR MIXTURES ABOVE
AMBIENT TEMPERATURE. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL
& PHOSGENE .
* Accidental Release Measures *
Spill Release Procedures:DIKE SPILL; TAKE UP WITH ABSORBENT;
CONTAINERIZE FOR PROPER DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTR TIGHTLY CLOSED. STORE IN A
COOL, WELL-VENT AREA AWAY FROM OPEN FLAMES. DO NOT BREATHE
VAPS/MISTS. DO NOT GET IN EYES, ON SKIN, (SUPP DATA)
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV
RADIATION MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE .
* Physical/Chemical Properties *
HCC:T4
Solubility in Water:2%
Appearance and Odor:COLORLESS LIQUID, ETHER-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG BASES & STRONG OXIDIZERS. OTHER: ALKALI METALS, ALUMINUM &
MAGNESIUM POWDER, SODIUM, POTASSIUM, & LITHIUM.
Stability Condition to Avoid:CONTACT W/OPEN FLAME, WELDING ARCS, HOT
SURFACES.
Hazardous Decomposition Products:HCL, PHOSGENE, CHLORINE.
* Disposal Considerations *
Waste Disposal Methods:TO BE PERFORMED IN COMPLIANCE WITH ALL CURRENT
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH-APPROVED RESPIRATOR IF TLV EXCEEDED.
Ventilation:GENERAL MECHANICAL VENTILATION IS USUALLY ADEQUATE UNDER
NORMAL USE.
Other Protective Equipment:PROTECTIVE CLOTHING.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CONTAINERS POTENTIALLY HAZARDOUS WHEN EMPTY.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:FORMALDEHYDE (SARA III)
Fraction by Wt: 4%
Other REC Limits:NONE SPECIFIED
Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III)
Fraction by Wt: 1%
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE AND SKIN IRRITANT. INHALATION:
IRRITATION AND POSSIBLE UNCONSCIOUSNESS. INGESTION: IRRITATION.
Explanation of Carcinogenicity:NTP-ANTICIPATED TO BE A CARCINOGEN.
IARC-PROBABLY CARCINOGENIC TO HUMANS. OSHA-REGULATED AS A
CARCINOGEN.
Effects of Overexposure:INHALATION-HEADACHE, UNCONSCIOUSNESS.
INGESTION:NAUSEA, VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION:REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED,
GIVE ARTIFICIAL RESPIRATION. INGESTION:ADMINISTER 4 GLASSES OF
WATER AND INDUCE VOMITING BY TOUCHING BACK OF THROAT WITH FINGER.
* Fire Fighting Measures *
Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:MAY PRODUCE HAZARDOUS DECOMPOSITION
PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:ABSORB ON PAPER, VERMICULITE, ETC.
*Handling and Storage *
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:T4
Solubility in Water:UNLIMITED
Appearance and Odor:COLORLESS LIQUID, PUNGENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS AND STRONG BASES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:CONSULT FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA.
Ventilation:LOCAL EXHAUST PREFERRED. GENERAL EXHAUST ACCEPTABLE IF
EXPOSURE IS MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. WASH HANDS AFTER USING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL
< Wt:5.
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:2-(2-BUTOXYETHOXY)ETHANOL
Minumum % Wt:0.
Maxumum % Wt:2.
Ingred Name:CRISTOBALITE
Minumum % Wt:.1
Maxumum % Wt:.8
OSHA PEL:see Table Z-3
Ingred Name:KAOLIN
Minumum % Wt:0.
Maxumum % Wt:1.
ACGIH TLV:2 MG/M3
Ingred Name:TITANIUM DIOXIDE
Minumum % Wt:0.
Ingred Name:ZINC OXIDE (ZNO)
Minumum % Wt:0.
Maxumum % Wt:2.
Ingred Name:CARBON BLACK
Minumum % Wt:0.
Maxumum % Wt:2.
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:ZINC COMPOUND
Minumum % Wt:0.
Maxumum % Wt:2.
* Hazards Identification *
Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION OF
EYES, SKIN & UPPER RESPIRATORY SYSTEM. BURNING SENSATION MAY
INDICATE EYE/SKIN EXPOSURE. CRYSTALLINE SILICA: MAY CAUSE LUNG
DAMAGE (SILICOSIS) & POSSIBLY CANCER. PR OLONGED OVEREXPOSURE TO
SOLVENTS MAY CAUSE ADVERSE EFFECTS TO THE LIVER & URINARY SYSTEMS.
Explanation of Carcinogenicity:CRYSTALLINE SILICA: LONG TERM EXPOSURE
TO HIGH LEVELS OF SILICA DUST, WHICH MAY OCCUR ONLY WHEN
SANDING/ABRADING THE DRY FILM.
Effects of Overexposure:IRRITATION, HEADACHE, NAUSEA, DIZZINESS,
REDNESS, ITCHING, BURNING
Medical Cond Aggravated by Exposure:NONE
* First Aid Measures *
First Aid:INHALATION: REMOVE FROM EXPOUSRE. RESTORE BREATHING. KEEP
WARM & QUIET. SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH
ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT W/SELF CONTAINED
BREATHING APPARATUS. WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS
USED, FOG NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLOSED
CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO
PRESSURE BUILD-UP & POSSIBLE AUTOIGNITION/EXPLOSION WHEN EXPOSED TO
EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. VENTILATE &
REMOVE W/INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE & APPROPRIATE
LABELING. USE ONLY W/ADEQUATE VENTILATION.
Other Precautions:DON'T TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
AVOID BREATHING VAPOR & SPRAY MIST. AVOID CONTACT W/SKIN & EYES.
* Physical/Chemical Properties *
Vapor Density:>1
pH:9-9.5
VOC Grams/Liter:.5
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:IGNITION SOURCES
Hazardous Decomposition Products:BY FIRE: CO2, CO
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DON'T
INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE W/LOCAL,
STATE & FEDERAL REGULATIONS.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TRIS(HYDROXYMETHYL)AMINOMETHANE
Ingred Name:HYDROCHLORIC ACID
OSHA PEL:C7 MG/M3;C5 PPM
ACGIH STEL:C7.5 MG/M3;C5 PPM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY BE HARMFUL BY
INHALATION. EYE CONTACT: MAY CAUSE IRRITATION. SKIN CONTACT: MAY
CAUSE IRRITATION. INGESTION: MAY BE HARMFUL IF SWALLOWED. CHRONIC:
NOT APPLICABLE.
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
First Aid:EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
EYELIDS WITH FINGERS. SKIN: IMMEDIATELY WASH WITH SOAP AND COPIOUS
AMOUNTS OF WATER. REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. INGESTION:
WASH OUT MO UTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD.
* Fire Fighting Measures *
Extinguishing Media:NONCOMBUSTIBLE. USE EXTINGUISHING MEDIA APPROPRIATE
TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
CONTAINERS FOR DISPOSAL. VENTIL ATE AREA AND WASH SPILL SITE AFTER
MATERIAL PICKUP IS COMPLETE.
*Handling and Storage *
TIGHTLY CLOSED. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO NOT
BREATHE VAPOR. STORE IN A DRY PLACE.
Other Precautions:SEVERE EYE IRRITANT.
* Physical/Chemical Properties *
Appearance and Odor:COLORLESS LIQUID; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Hazardous Decomposition Products:NOT APPLICABLE.
* Toxicological Information*
Toxicological Information:TOXICITY DATA: NOT APPLICABLE. ADDITIONAL
INFORMATION: THE PRODUCT SHOULD BE HANDLED WITH THE NORMAL CAUTION
ACCORDED CHEMICALS. ADDITIONAL HARMFUL PROPERTIES CANNOT BE RULED
OUT.
* Ecological Information *
Ecological:NOT APPLICABLE.
* Disposal Considerations *
Waste Disposal Methods:FOR SMALL QUANTITIES FLUSH DOWN SINK WITH WATER.
OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS.
* MSDS Transport Information *
Transport Information:NOT APPLICABLE.
* Regulatory Information *
SARA Title III Information:NOT APPLICABLE.
Federal Regulatory Information:NOT APPLICABLE.
State Regulatory Information:NOT APPLICABLE.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:APPROPRIATE NIOSH/MSHA APPROVED RESPIRATORY
PROTECTION FOR CONCENTRATIONS ABOVE THE EXPOSURE LIMITS.
Ventilation:IF VENT IS TO BE USED TO CONVEY FINELY DIVIDED ALUM
Other Protective Equipment:MOLTEN METAL HNDLNG REQS USE OF BOTH
SECONDARY & PRIMARY PERSONAL PROT EQUIP, REFER TO ALUM ASSOC'S
GUIDELINES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:DIVIDED ALUM REACTS W/HALOGEN ACIDS. WATER & SODIUM HYDROXIDE
TO PRDCE HYDROGEN GAS. CNDTNS (STAB): CAUTION NEEDS TO BE EXERCISED
IF METAL COULD BE HOT. MATL TO AVOID:CAN FORM EXPLOS MIX W/B
ROMATES, IODATES & AMMONIUM NITRATE. FINELY DIVIDED ALUM CAN
THERMITE IN PRESENCE OF OXIDES OF COPPER, LEAD OR IRON.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ALUMINUM (SARA III)
Ingred Name:IRON (PEL/TLV AS IRON OXIDE)
ACGIH TLV:5 (FE)MG/M3
Ingred Name:COPPER (SARA III).
Fraction by Wt: 0.1%
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2MG/M3 FUME;1 DUST
Ingred Name:MAGNESIUM
Fraction by Wt: 1.1-1.4%
Ingred Name:ZINC (SARA III). (PEL/TLV AS ZINC OXIDE)
Fraction by Wt: SEE ING
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:EFTS OF OVEREXP:DUST MAY CAUSE IRRIT TO MUC MEMB & PHARYNX,
& HEAVY CONC OF MANGANESE DUST MAY AFFECT CENTRAL (ING 8)
Ingred Name:ING 7:NERV SYS. MIG WELDING OR PLASMA ARC CUTTING OF ALUM
ALLOYS CAN GENERATE OZONE, NITRIC OXIDES & UV RADIA. (ING 9)
Ingred Name:ING 8:OZONE OVEREXPOSURE MAY RESULT IN MUCOUS MEMBRANE
IRRITATION, AS WELL AS OTHER PULMONARY DISCOMFORT.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL:ALUM DUSTS ARE CONSIDERED
NUISANCE PARTICULATES, WHICH HAVE LITTLE ADVERSE EFT ON LUNGS & DO
NOT PRDCE SIGNIFICANT ORG DISEASE OR TOX EFTS WHEN EXPOS ARE KEPT
UNDER REASONABLE CONTROL. ALUM FUME S GENERATED IN MELTING/WELDING
ARE CONSIDERED TO BE LOW HLTH RISK. DUE TO LOW CONC OF OTHER LISTED
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INGREDS THEIR PRESENCE IS LESS LIKELY
TO CAUSE HLTH CONCERN. EYE:ALUM DUST MAY CAUSE ABRASIONS. SUPP
INFO: SILICON DUSTS ARE CONSIDERED NUISANCE PARTICULATES. HEAVY
CONC OF FRESHLY FORMED FUM ES OF OXIDES OF COPPER, MAGNESIUM,
MANGANESE & ZINC CAN PRDCE SYMPS OF METAL FUME FEVER. HIGH CONC OF
COPPER (ING 7)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:IN CASE OF DISCOMFORT, MOVE TO A VENTILATED AREA. IF
DISCOMFORT PERSISTS, SEEK MEDICAL ATTENTION. SKIN:FLUSH W/COPIOUS
AMOUNTS OF WATER. CALL MD . EYES:IN CASE OF DISCOMFORT, FLUSH
MEDICAL ATTENTION. INGEST:CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Extinguishing Media:NOT A FIRE HAZARD EXCEPT IN FINELY DIVIDED FORM. IN
CASE OF ALUM FIRE, USE A CLASS D DRY POWDER EXTING OR DRY SAND.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . DO NOT USE WATER OR HALOGENATED
EXTINGUISHING MEDIA.
Unusual Fire/Explosion Hazard:MOLTEN ALUM MAY EXPLODE UPON CONT
W/WATER. FINELY DIVIDED ALUM MAY EXPLODE WHEN MIXED W/HALOGEN
ACIDS, HALOGENATED SOLV OR AMMONIUM NITRATE. FINELY (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:NOT APPLICABLE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NOT APPLICABLE.
Other Precautions:HANDLING MOLTEN ALUMINUM PRESENTS A SPECIAL HAZARD.
FOR MORE INFORMATION ON MOLTEN ALUMINUM, REQUEST A COPY OF
"GUIDELINE FOR HANDLING MOLTEN ALUMINUM FROM THE ALUMINUM
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:2.5-2.9(H2O=1)
Appearance and Odor:GREY TO SILVERY METALLIC SOLID; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALUM CAN GENERATE EXPLOS MIX OF HYDROGEN IN PRESENCE OF HALOGEN ACIDS
OR SODIUM HYDROXIDE. FINELY DIVIDED ALUM (SUP DAT)
Stability Condition to Avoid:ALUM SCRAP MUST BE THORO DRIED PRIOR TO
REMELTING. HOT ALUM DOES NOT EXHIBIT WARNING COLOR CHANGES,
THEREFORE, (SUP DAT)
Hazardous Decomposition Products:NOT APPLICABLE.
* Disposal Considerations *
Waste Disposal Methods:RECYCLE. FINELY DIVIDED ALUMINUM MAY BE REACTIVE
& ITS HAZARD CHARACTERISTICS SHOULD BE DETERMINED PRIOR TO
DISPOSAL. DISPOSER MUST COMPLY W/FEDERAL, STATE OR LOCAL WASTE
DISPOSAL LAWS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:DUST MASK REQUIRED IF TOTAL DUST EXCEEDS
Other Protective Equipment:FULL COVER CLOTHING, APRON WHEN WORKING
W/SOLUTIONS.
Work Hygienic Practices:NO SPECIAL RQUIREMENTS.
Supplemental Safety and Health
PH 1% SOLUTION 8.2
* Product Identification *
Product ID:SODIUM BICARBONATE
CAGE:0WTR2
* Composition/Information on Ingredients *
Ingred Name:SODIUM BICARBONATE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE/SKIN NOT AN IRRIT. INGEST: MATL
NONTOXIC SMALL AMTS. 1-2TBSPS) SWALLOWED DURING NORMAL HANDLING
OPERATIONS NOT LIKELY TO CAUSE INJURY AS LONG AS STOMACH IS NOT
FULL.SWALLOWING LARGER AMTS MAY CAUS E INJURY. SUBCHRONIC
ACUTE INHALATION.
* First Aid Measures *
First Aid:EYES: CHECK FOR & REMOVE CONTACTS, FLOOD EYES W/CLEAN FLOWING
WATER, LOW PRESSURE & LUKEWARM IF POSSIBLE, LIFTING EYELIDS.
INGEST: IF LG AMTS SWALLOWED DO NOT INDUCE VOMITING, ADMINISTER
WATER IF CONS CIOUS, NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS
PERSON. NOTE TO DR. LG DOSES MAY PRODUCE SYSTEMIC
ALKALOSIS/EXPANSION IN EXTRACELLULAR FLUID VOLUME W/EDEMA.
* Fire Fighting Measures *
Flash Point:NONCOMBUSTIBLE.
Lower Limits:NA
Upper Limits:NA
Extinguishing Media:NONCOMBUSTIBLE MATL USE EXTINGUISHING MEDIA
APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:CARBON DIOXIDE MAY BE GENERATED MAKING IT
NECESSARY TO USE SCBA & OTHER PROT EQPT (BUNKER GEAR). CO2 IS AN
Unusual Fire/Explosion Hazard:NK *RESPIRATORY/EYE/SKIN IRRIT. AVOID
INHALATION/EYE/SKIN CONTACT W/SODIUM OXIDE DUST.
* Accidental Release Measures *
Spill Release Procedures:SCOOP UP INTO DRY CLEAN CONTNRS. WASH AWAY
UNCONTAM RESIDUE W/WATER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL DRY AREAS AWAY FROM
INCOMPATIBLE SUBSTANCES. SODIUM BICARBONATE REACTS W/ACIDS TO YIELD
CARBON DIXOIDE WHICH CAN ACCUMULATE IN ***
Other Precautions:NK ***CONFINED SPACES. DO NOT ENTER AREA UNTIL WELL
VENT & CO2/OXYGEN LEVELS ARE DETERMINED SAFE.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:NA
Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:2.2
pH:NA
Appearance and Odor:WHITE CRYSTALLINE POWDER, NO ODOR.
Percent Volatiles by Volume:NA
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS W/ACIDS TO YIELD CARBON DIOXIDE YIELDS FREE CAUSTIC IN PRESENCE
OF LIME DUST & MOISTURE.
CO2 IN CONFINED AREA SODIUM OXIDE:AVOID INHAL/EYE/SKIN CONTACT.
* Disposal Considerations *
Waste Disposal Methods:BURRY IN SECURED LANDFILL IN ACCORDANCE
W/LOCAL/STATE/FEDERAL ENVIRONMENTAL REGULATIONS. EMPTY CNTNRS MAY
BE INCINERATED OR DISCARDED AS GENERAL TRASH.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:AFTER CONTACT WITH SKIN, WASH IMMEDIATELY WITH
PLENTY OF WATER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SILICA GEL; (OCTYL BONDED SILICA GEL)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: IRRITATION OF UPPER
RESPIRATORY TRACT, EXCESSIVE INHALATION MAY CAUSE LUNG DAMAGE,
PNEUMOCONIOSIS, SILICOSIS, CYANOSIS, COUGHING, DIFFICULT BREATHING.
SKIN/EYES: IRRITATION. CHRONIC : LUNG DAMAGE, CONGESTION OF HEART,
LIVER, KIDNEY, & SPLEEN, ALTER BLOOD COMPOSITION. TARGET ORGANS:
LUNGS, RESP SYSTEM.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE.
* First Aid Measures *
First Aid:INGESTION: CALL MD. IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY
INDUCE VOMITING. INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF
NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. PROMPT ACTION IS ESSENTIAL. SKIN: FLUSH
WITH WATER. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE IDENTIFIED.
* Accidental Release Measures *
Spill Release Procedures:WEAR SUITABLE PROTECTIVE CLOTHING. CAREFULLY
SWEEP UP AND REMOVE.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT WITH EYES. KEEP
CONTAINER TIGHTLY CLOSED. SUITABLE FOR ANY GENERAL CHEMICAL STORAGE
AREA.
Other Precautions:
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE (<0.1%)
Appearance and Odor:WHITE GRANULAR POWDER, ODORLESS
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HYDROGEN FLUORIDE, STRONG ACIDS, STRONG BASES.
Stability Condition to Avoid:MOISTURE.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
LOCAL, STATE AND FEDERAL ENVIRONMENTAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR MSHA/NIOSH APPROVED DUST RESPIRATOR. IF
EXCESSIVE VISIBLE DUST LEVELS AREA EXPECTED.
Ventilation:GENERAL PURPOSE
Supplemental Safety and Health
* Product Identification *
Product ID:SODIUM BICARBONATE
* Composition/Information on Ingredients *
Ingred Name:SODIUM BICARBONATE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: MILD IRRITATION (RABBIT). SKIN:
MILD IRRITATION. SKIN ABSORPTION: NO DATA AVAILABLE. INHALATION: NO
DATA AVAILABLE. INGESTION: PRACTICALLY NON-TOXIC. ACUTE: SODIUM
BICARBONATE IS GENERALLY RECOGN IZED AS SAFE FOOD INGREDIENT. NO
SIGNIFICANT TOXICITY EXPECTED. MAY BE IRRITATING TO SKIN & EYES. *
Effects of Overexposure:* CHRONIC: ADMINISTRATION OF LARGE DOSES OF
SODIUM DICARBONATE TO PATIENTS WITH RENAL INSUFFICIENCY CAN PRODUCE
SYSTEMIC ALKALOSIS.
* First Aid Measures *
PERSISTS, OBTAIN MEDICAL ATTENTION. INHALATION:REMOVE FROM
EXPOSURE. IF DISCOMFOR T OCCURS & PERSISTS,OBTAIN MEDICAL ADVICE BY
DR:INTERNAL TOXICTY LOW. TREATMENT FOLLOWS STANDARD PROTOCOL & IS
SYMPTOMATIC & SUPPORTIVE.
* Fire Fighting Measures *
Flash Point:NON COMBUSTIBLE
Extinguishing Media:ALL
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP AS MUCH AS POSSIBLE FOR SALVAGE OR
DISPOSAL. WASH AWAY RESIDUE WITH WATER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY AREAS & AWAY FROM
CHEMICAL THAT MAY CONTAMINATE PRODUCT. MINIMIZE THE FREE FALL WHEN
HANDLING TO MINIMIZE THE DUST GENERATED.
RESPIRATOR TO PREVENT IRRITATION WHERE EXCESSIVE DUST MAY BE
EXPECTED. CARBON DIOXIDE GAS CAN FORM IN CONFINED SPACES IS SODIUM
BICARBONATE CONTACTS ACID S. DO NOT ENTER CONFINED SPACES TILL **
** THEY HAVE BEEN WELL VENTILATED AND CARBON DIOXIDE AND OXYGEN LEVELS
HAVE BEEN DETERMINED TO BE SAFE. CONTINUE TO MONITOR ATMOSPHERE
FROM OXYGEN DEFICIENCY.
* Physical/Chemical Properties *
Vapor Pres:NIL
pH:8.3-1%
Appearance and Odor:WHITE GRANULAR SOLID, ODORLESS
Percent Volatiles by Volume:NIL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS WITH ACIDS TO RELEASE CARBON DIOXIDE GAS AND HEAT.
Stability Condition to Avoid:CONTACT W/ACIDS EXCEPT UNDER CONTROLLED
CONDTIONS. CO2 CAN FORM IN CONFINED SPACES WHEN ALKALINE PRODUCT
CONTACT ACIDS.
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:IF MATERIAL CANNOT BE SALVAGED, THE PREFERRED
METHOD OF DISPOSAL IS IN A SECURED LANDFILL IN ACCORDANCE WITH
LOCAL, STATE, & FEDERAL ENVIRONMENTAL REGULATIONS. EMPTY CONTAINERS
MAY BE INCINERATED OR D ISCARDED AS GENERAL TRASH.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED
Ventilation:MECHANICAL (GENERAL) &/LOCAL EXHAUST.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: 3.0%
Fraction by Wt: 1-2%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION & BURNING. SKIN:
SLIGHT IRRITATION & DERMATITIS. INHALATION: MAY CAUSE IRRITATION TO
NOSE & THROAT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, BURNING, TEARING, REDNESS, PAIN,
DISTRESS, NAUSEA.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS.
* First Aid Measures *
First Aid:EYES: FLUSH W/COPIOUS AMOUNTS OF CLEAN WATER. SKIN: WASH
THOROUGHLY W/MILD SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
INGESTION: GIVE 3-4 GLASSES OF WATER. INDUCE VOMITING, IF CONSCIOUS
UNDER DIRE CTIONS FROM A PHYSICIAN/POISON CONTROL CENTER. VOMITING
CAN BE INDUCED BY GIVING 3 TBLS OF LIQUID DISHWASHING SOAP MIXED
W/WATER. DON'T LEAVE VICTIM UNATTENDED. OBTAIN MEDICAL ATTENTION IN
ALL CASES.
* Fire Fighting Measures *
Fire Fighting Procedures:WEAR SCBA.
Unusual Fire/Explosion Hazard:PRODUCT WILL NOT BURN UNTIL WATER CONTENT
HAS EVAPORATED. DECOMPOSITION BY PRODUCTS MAY BE TOXIC.
* Accidental Release Measures *
Spill Release Procedures:COVER W/ABSORBENT MATERIAL, TRANSFER TO CLOSED
CONTAINERS.
*Handling and Storage *
Handling and Storage Precautions:KEEP FROM FREEZING. CLOSE CONTAINER
AFTER USE.
* Physical/Chemical Properties *
Vapor Pres:AS WATER
Vapor Density:AS WATER
Evaporation Rate & Reference:SAME AS WATER
Solubility in Water:DILUTETABLE
Appearance and Odor:WHITE HEAVY PASTE W/ACRYLIC ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:FREEZING
Hazardous Decomposition Products:CO, CO2, TRACES OF NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY NEEDED.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:PROPANE (LIQUEFIED PETROLEUM GAS)
Other REC Limits:NONE RECOMMENDED
Ingred Name:OXYGEN (GAS)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL:OXYGEN HAS TONIC EFFECT ON
HUMANS.PROPANE- HEADACH,DROWSINESS,MAY CAUSE FROSTBURN.SKIN:MAY
CAUSE FROSTBURN(PROPANE).INGEST:NO ROUTE OF ENTRY.EYE:PROPANE MAY
CAUSE FROSTBURN.
Explanation of Carcinogenicity:PER
MSDS:CARCINOGENICITY:HNTP/IARC/OSHA:NO.
Effects of Overexposure:FROSTBURN, HEADACHE,DROWSINESS.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR.SKIN:TREAT FOR FROSTBURN.CALL
PHYSICIAN IF EXPOSURE WAS SEVERE.EYE:TREAT FOR FROSTBURN.IMMED CALL
PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:CC
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:2.1 PROPANE
Upper Limits:9.5 PROPANE
Extinguishing Media:STOP FLOW OF GAS OR OXYGEN.
Fire Fighting Procedures:USE WATER TO COOL CYLINDERS.
Unusual Fire/Explosion Hazard:OXYGEN SUPPORTS COMBUSTION.PROPANE
DISTANCE TO SOURCE OF IGNITION & FLASH BACK.
* Accidental Release Measures *
Spill Release Procedures:PROPANE-REMOVE ANY IGN SOURCES.VENTILATE AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
VENTILATED,SPARK FREE,FLAMM FREE AREA.AVOID PROLONGED EXPOSURE TO
SUNLIGHT.KEEP OUT OF REACH OF CHILDREN.
Other Precautions:FOR APPLICATIONS WHICH INVOLVE HIGH CONCENTRATIONS OF
GASEOUS OXYGEN OR LIQUID OXYGEN THE USER SHOULD REFER TO THE OXYGEN
SUPPLIER TO DETERMINE IF ANY FIRE/EXPLOSION RISKS EXIST.
* Physical/Chemical Properties *
HCC:G2
Melt/Freeze Pt:M.P/F.P Text:NA
Decomp Temp:Decomp Text:NP
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NA
Solubility in Water:NA FOR PROPANE
Appearance and Odor:PROPANE:COLORLESS, ROTTEN EGG ODOR.
OXYGEN:COLORLESS,ODORLESS.
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
KEEP OXYGEN AWAY FROM COMBISTIBLES OR CORROSIVES IN UN-CONTROLLED
SITUATION.
Stability Condition to Avoid:KEEP OXYGEN AWAY FROM COMBUSTIOBES OR
CORROSIVES IN UN-CONTROLLED SITUATIONS.
Hazardous Decomposition Products:OXY-NA. PROPANE-NORMAL BY-PRODUCTS OF
COMBISTION.CO2,WATER.
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: OVEREXPOSURE:CAUSES SEVERE EYE AND MODERATE SKIN
IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. CHRONIC OVEREXPOSURE:MAY
CAUSE EFFECTS DUE TO THE ABILITY OF CITRIC ACID TO CHELATE METALS, WHICH C
OULD IMPAIR THE BODY'S ABILITY TO ABSORB CALCIUM AND IRON.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: PRE-EXISTING EYE, SKIN AND RESPIRATORY
TRACT CONDITIONS.
PHYSICIAN. SKIN:FLUSH SKIN WITH PLENTY OF WATER. INGESTION:GIVE LARGE
QUANTITIES OF WATER. CALL PHYSICIAN IMMEDIATELY. INHALATION:R EMOVE TO FRESH
AIR.
*
Handling and Disposal
*
Spill Release Procedures: SCOOP SPILLED MATERIAL INTO A BEAKER AND DISSOLVE
WITH WATER. NEUTRALIZE TO A PH BETWEEN 6 AND 9 WITH AN ALKALI SUCH AS SODA
ASH. FLUSH NEUTRALIZED WASTE TO THE DRAIN WITH AN EXCESS OF WATER.
Neutralizing Agent: NEUTRALIZE TO A PH BETWEEN 6 AND 9 WITH AN ALKALI SUCH AS
SODA ASH.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND
LOCAL REGULATIONS.
Handling And Storage Precautions: STORE TIGHTLY CLOSED IN A COOL, DRY PLACE.
Other Precautions: AVOID CONTACT WITH EYES AND SKIN. DO NOT BREATHE DUST.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: WATER, CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: POTENTIALLY EXPLOSIVE REACTION WITH METAL
NITRATES. EMITS TOXIC FUMES OF CO AND CO*2.
*
*
Respiratory Protection: USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE
OF CONCERN (FP N).
Ventilation: ADEQUATE VENTILATION.
Other Protective Equipment: ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER
(FP N). LAB COAT.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: PH OF 0.1 N. SOLN:2.2. EYE PROT:AND FULL LENGTH
FACESHIELD (FP N).
*
Physical/Chemical Properties
*
PH: SUPDAT
Appearance and Odor: SOLID, COLORLESS CRYSTALS; NO ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXPOSURE TO MOISTURE, OXIDIZERS, FLAMES.
POTENTIALLY EXPLOSIVE REACTION IN CONTACT WITH METAL NITRATES.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: EMITS ACRID SMOKE AND FUMES IN FIRE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: HACH COMPANY
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: AVOID EYE CONTACT. ACUTE:CAUSES SEVERE EYE AND MODERATE
SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION. CHRONIC:MAY CAUSE
EFFECTS DUE TO THE ABILITY OF CITRIC ACID TO CHELATE METALS, WHICH CO ULD
IMPAIR THE BODY'S ABILITY TO ABSORBCALCIUM AND IRON.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
* Product Identification *
Preparer's Name:DOD HMIS/DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS, CHRYSOTILE
OSHA PEL:0.2 FIBERS/CC
Ingred Name:ASBESTOS & SYNTHETIC RUBBER COMPOSITION
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
*Handling and Storage *
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
* Physical/Chemical Properties *
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SEE MSDS FOR HARDENER.
Ventilation:SEE MSDS FOR HARDENER.
Other Protective Equipment:OTHER PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
DESTROY LEATHER ARTICLES, INCLUDING SHOES THAT CAN'T BE DECONTAMINATED.
* Product Identification *
Product ID:PLASTIC STEEL LIQUID B RESIN
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:EPOXY RESIN
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE MILD IRRITATION. SKIN:
MAY CAUSE MILD IRRITATION & POSSIBLE SENSITIZATION WHEN MIXED
W/HARDENER.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION.
* First Aid Measures *
MINS. INGESTION: IF CONSCIOUS, GIVE 2 GLASSES OF WATER. NEVER
ADMINISTER LIQUIDS TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL
ATTENTION IN ALL CA SES.
* Fire Fighting Measures *
Flash Point Method:TOC
Extinguishing Media:CO2, DRY CHEMICALS. LARGE: POLYMER FOAM.
Fire Fighting Procedures:AVOID BREATHING SMOKE.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:PREVENT SKIN & EYE CONTACT. SCRAPE UP &
DISCARD IN SUITABLE CONTAINERS. USE ABSORBENT MATERIAL IF
NECESSARY. WASH AREA W/AN INDUSTRIAL CLEANING AGENT. IF A SOLVENT
IS USED FOR CLEANING, TAKE PRECAUTIO NS AGAINST FIRE & PERSONAL
OVEREXPOSURE.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE. HANDLE
IAW/POTENTIAL HAZARD OF CURING AGENT USED.
Other Precautions:WEAR ADEQUATE PROTECTIVE EQUIPMENT TO PREVENT
OVEREXPOSURE TO NUISANCE PARTICULATES. IF CURED MATERIAL IS
SANDED/MACHINED USE PROPER PRECAUTIONS. HEAT IS GENERATED WHEN
MIXED W/EPOXY HARDENER. USE CAU TION WHEN MIXING LARGE QUANTITIES.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:2.8
pH:7
Solubility in Water:INSOLUBLE
Appearance and Odor:DARK GRAY PASTE W/LOW ODOR.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS & STRONG ACIDS.
Stability Condition to Avoid:OPEN FLAME & EXCESSIVE HEAT.
Hazardous Decomposition Products:FROM INCOMPLETE COMBUSTION: OXIDES OF
CARBON, ALDEHYDES & ACIDS.
* Disposal Considerations *
Waste Disposal Methods:REMOVE TO A WASTE DISPOSAL FACILTIY OPERATING
IAW/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . N/A.
Ventilation:N/A.
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:DIETHYLENE GLYCOL MONOETHYL ETHER; (DIETHYLENE GLYCOL
MONOMOHTYL ETHER)
= Wt:4.
Ingred Name:WATER
Fraction by Wt: BALANCE
* Hazards Identification *
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE
OXYGEN/ARTIFICIAL
RESPIRATION) . EYE CONTACT: IMMED FLUSH EYE W/LARGE QTYS OF RUNNING
WATER FOR A
ENSURE FLUSHING
OF ENTIRE SURFACE OF EYE LID W/WATER. GET MED ATTN IF IRRIT PERSISTS.
SKIN CONTACT:FLUSH AFFECTED AREA W/LARGE QTYS OF RUNNING WATER
WHILE REMOVING CONTAMI NATED
CLOTHES & SHOES. WASH CLOTHING BEFORE REUSE. GET MED ATTN IF IRRIT
PERSISTS. INGEST:REQUIRES IMMED MED MANAGEMENT. DRINK MILK OR WATER
& GET MED ADVICE. VOMITING
SHOULD BE INDUCED ONLY ON RECOM MENDATION OF MED PERS.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:C0*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . NORMAL FIRE FIGHTING PROCEDURES MAY BE USED. COOL AND
USE CAUTION WHEN APPROACHING OR HANDLING FIRE-EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CONTAINERS MAY BURST IN HEAT.
* Accidental Release Measures *
Spill Release Procedures:FOR SMALL SPILLS, DILUTE WITH WATER AND PICK
UP WITH MOP AND PAIL OR WET PICK UP
VACUUM. FOR LARGE SPILLS, DIKE AREA TO CONTAIN SPILL. CLEAN UP USING
ABSORBENT
MATERIAL. PLACE ALL CONTAMINATED MATERIA L IN A CLOSED CONTAINER FOR
DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE.
* Physical/Chemical Properties *
Vapor Pres:N/D
Vapor Density:N/D
pH:9.0
Evaporation Rate & Reference:1
Solubility in Water:SOLUBLE
Appearance and Odor:MILKY WHITE; SWEET SCENT.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN TO NATIONAL SANITARY SUPPLY COMPANY.
Stability Condition to Avoid:NONE KNOWN TO NATIONAL SANITARY SUPPLY
COMPANY.
Hazardous Decomposition Products:WHEN EXPOSED TO FIRE, PRODUCES NORMAL
PRODUCTS OF COMBUSTION.
* Ecological Information *
Ecological:GENERAL: THIS CHEMICAL FORMULATION HAS NOT BEEN TESTED FOR
ENVIRONMENTAL EFFECTS. ALTHOUGH, IN A SPILL SITUATION THIS
FORMULATION MAY BE AESTHETICALLY UNPLEASANT, IT IS WATER INSOLUBLE
& IS NOT EXPECT ED TO SHOW ANY ADVERSE ENVIRONMENTAL EFFECTS.
* Disposal Considerations *
Waste Disposal Methods:WASTE FOR DILUTED PRODUCT MAY BE FLUSHED TO
SEWER. UNDILUTED PRODUCT RECOVERED
FROM SPILLS MAY BE SENT TO LICENSED DISPOSAL FACILITY TO BE DISPOSED OF
IN ACCORDANCE
WITH FEDERAL & STATE REGS AND LOCAL ORDINANCES. TRIPLE RINSE EMPTY
CNTNR
THOROUGHLY W/WATER & DISCARD IN REGULAR TRASH COLLECTION IF AL LOWED BY
LOCAL,
STATE AND FEDERAL REGS.
* Regulatory Information *
SARA Title III Information:DIMETHYLENE GLYCOL MONOMOHTYL ETHER IS
SUBJECT TO THE REPORTING REQUIREMENTS UNDER SARA TITLE III, SECTION
CHRONIC: NO; FIRE: NO, PRESS URE RELEASE: NO, REACTIVE: NO.
State Regulatory Information:
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR IF VENTILATION IF
POOR.
Ventilation:GOOD VENTILATION. LOCAL EXHAUST. MECHANICAL (GENERAL).
Other Protective Equipment:AS NEEDED TO PROTECT SKIN CONTACT. EMERGENCY
EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CYCLOALIPHATIC AMINE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FUMED SILICA
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MINOR BURNING TO EYES, NOSE,
THROAT AND SKIN. CHRONIC: DEFATTING TO THE SKIN. DIZZINESS AND
NAUSEA.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NOT KNOWN.
* First Aid Measures *
First Aid:INHALATION: MOVE SUBJECT TO FRESH AIR. EYES: FLUSH WITH WATER
INGESTION: DO NOT INDUCE VOMITING. CALL MD.
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:TOXIC FUMES WILL BE EVOLVED WHEN THIS
MATERIAL IS INVOLVED IN A FIRE.
* Accidental Release Measures *
Spill Release Procedures:SPREAD ABSORBENT MATERIAL OVER SPILL AND PLACE
IN CLOSED CONTAINER. REMOVE ALL SOURCES OF IGNITION.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY AREA. PROTECTIVE
Other Precautions:AVOID IHHALATION OF HEATED VAPORS AND SPRAY MISTS.
* Physical/Chemical Properties *
Vapor Pres:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NEGLIGIBLE
Appearance and Odor:PALE STRAW LIQUID; MODERATE AMINE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS. AVOID CONTACT WITH EPOXY RESINS IN
UNCONTROLLED CONDITIONS.
Stability Condition to Avoid:AVOID HIGH TEMPERATURES.
Hazardous Decomposition Products:
Conditions to Avoid Polymerization:AVOID CONTACT WITH EPOXY RESINS
UNTIL READY FOR APPLICATION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN SANITARY LANDFILL ACCORDING TO
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED FILTER-DUST, FUME, MIST
RESPIRATOR.
Ventilation:USE WITH ADEQUATE VENTILATION.
Other Protective Equipment:USE RUBBER APRON OR BOOTS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PRODUCT MIXES WITH ALL PROPORTIONS OF WATER-SHOULD BE USED ONLY IN
DILUTED FORM.
* Product Identification *
Preparer's Name:THOMAS G. MUSILLI
CAGE:KIMES
* Composition/Information on Ingredients *
Ingred Name:SEVERLY HYDROTREATED HEAVY NAPHTHENIC DISTILLATE
Other REC Limits:NONE SPECIFIED
Ingred Name:POLYOXYETHYLENESORBITOL OLEATE
Fraction by Wt: 1%
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES-MILD TRANSIENT IRRITATION.
SKIN-MILD TRANSIENT IRRITATION.
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS NO KNOWN
CARCINOGENS OR MUTAGENS AS DEFINED BY OSHA OR IARC.
Effects of Overexposure:MAY CAUSE EYE, SKIN & RESPIRATORY TRACT
IRRITATION.
Medical Cond Aggravated by Exposure:THIS PRODUCT IS A SKIN AND
RESPIRATORY SENSITIZER.
* First Aid Measures *
First Aid:INGESTION-DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
SKIN-WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING.
ATTENTION. INH ALATION-REMOVE TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION IF NOT BREATHING. GIVE OXYGEN. GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, FOAM,
EARTH OR SAND.
Fire Fighting Procedures:WATER MAY CAUSE FROTHING.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH SAND OR INERT MATERIAL. SWEEP OR
SCOOP UP AND REMOVE.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN MATERIAL
IS NOT IN USE. KEEP AWAY FROM SPARKS AND OPEN FLAMES.
Other Precautions:DO NOT GET IN EYES OR ON CLOTHING. DO NOT BREATH
DUST, VAPOR, MIST, GAS.
* Physical/Chemical Properties *
HCC:V6
Appearance and Odor:FLUID OIL, BLAND.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:OXIDES OF CARBON.
* Disposal Considerations *
Waste Disposal Methods:RECYCLE IN ACCORDANCE WITH APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK
SITUATIONS. USE NIOSH-APPROVED PRESSURE-DEMAND SELF-CONTAINED OR
SUPPLIED-AIR RESPIRATOR WHERE THE PLACE IS CONFINED,OR ENCLOSED.
Ventilation:LOCAL EXHAUST FOR FILLING ZONES & MECHANICAL FOR STORAGE
AREAS.
Other Protective Equipment:EYE BATH & SAFETY SHOWER
Work Hygienic Practices:USE NORMAL HYGIENIC PRACTICES.
Supplemental Safety and Health
* Product Identification *
Product ID:BLACO-TRON TCM
CAGE:BARON
CAGE:BARON
POLYMERS
* Composition/Information on Ingredients *
III)
Ozone Depleting Chemical:1
Ingred Name:METHYLENE CHLORIDE(SARA III)
Ingred Name:CYCLOPENTANE
Fraction by Wt: 9%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:CHRONIC:CAN CAUSE HEADACHE,MENTAL
CONFUSION,DEPRESSION,FATIGUE,COUGH,ETC;PROLONGED SKIN CONTACT MAY
CAUSE DERMATITIS; ACUTE:PRIMARILY A CENTRAL NERVOUS SYSTEM
DEPRESSANT.INHALATION CAUSES IRRITATION,N AUSEA,ETC;EYE CONTACT CAN
CAUSE DISCOMFORT OR PAIN.
STUDY REPORTED CARCINOGENICITY IN MICE & FEMALE RATS.
Effects of Overexposure:INH:SYMPTOMS OF CENTRAL NERVOUS SYSTEM
DEPRESSION,LIGHT-HEADEDNESS,NAUSEA,VOMITING,UNCONSCIOUSNESS;
EYE/SKIN:IRRITATION; ING:IRRITATION OF THE GASTROINTESTINAL TRACT
WITH VOMITING,IF VOMITING RESULTS IN ASPIRATION,CHEMICAL PNEUMONIA
COULD FOLLOW.
Medical Cond Aggravated by Exposure:NONE STATED.
* First Aid Measures *
First Aid:INH:REMOVE TO FRESH AIR,GIVE MOUTH-TO-MOUTH RESUSCITATION IF
BREATHING HAS STOPPED,GIVE OXYGEN AS NECESSARY,DO NOT GIVE
ADRENALIN(EPINEPHRINE); ING:IF CONSCIOUS,INDUCE VOMITING BY GIVING
2-4 GLASSES O F WATER & TOUCH FINGER TO BACK OF THROAT,TAKE TO A
EYELIDS; SKIN:WASH WITH SOAP & WATER,REMOVE CONTAMINATED CLOTHING &
SHOES.
* Fire Fighting Measures *
Extinguishing Media:USE PROPER EXTINGUISHING MEDIA FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS FOR POSSIBLE EXPOSURE TO HYDROCHLORIC &
HYDROFLUORIC ACIDS & PHOSGENE.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA.PROVIDE MAX
VENTILATION.UNPROTECTED PERSONNEL SHOULD STAY UPWIND OF SPILL.WEAR
PROPER PROTECTIVE CLOTHING.DIKE AREA & CONTAIN SPILL.PREVENT
CONTAMINATION OF GROUND & SURFACE WATER.USE SA WDUST OR
VERMICULATE,SWEEP INTO CONTAINER & CLOSE.
*Handling and Storage *
Handling and Storage Precautions:DO NOT USE IN POORLY VENTILATED
KEEP CONTAINERS CLOSED WHEN NOT IN USE.AVOID CONTAMINATION OF
WATER SUPPLIES.
Other Precautions:AVOID PROLONGED OR REPEATED BREATHING OF VAPORS.AVOID
CONTACT WITH EYES & SKIN.DO NOT TAKE INTERNALLY.DO NOT EAT,DRINK OR
SMOKE IN WORK AREAS.
* Physical/Chemical Properties *
HCC:T4
Vapor Density:4.3
pH:7
Appearance and Odor:COLORLESS LIQUID WITH ETHEREAL & FAINT SWEETISH
ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS & STRONG ALKALIS REACTIVE METAL:POWDERED
ALUMINUM,MAGNESIUM,ZINC,MOLTEN BARIUM,LITHIUM SHAVINGS,ETC.
SPARKS,HOT SPOTS,WELDING,FLAMES & CIGARETTES.
Hazardous Decomposition Products:HYDROCHLORIC ACID,HYDROFLUORIC
ACID,PHOSGENE.
* Disposal Considerations *
Waste Disposal Methods:CONTAMINATED ABSORBENT MAY BE DISPOSED OF IN A
PERMITTED HAZARDOUS WASTE FACILITY.RECOVERED LIQUID MAY BE
REPROCESSED OR INCINERATED OR TREATED IN A WASTE MANAGEMENT
FACILITY.FOLLOW FEDERAL,STATE & LO CAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED APPROPRIATE FOR EXPOSURE OF
CONCERN .
Ventilation:LOCAL EXHAUST REQUIRED.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:RL
* Composition/Information on Ingredients *
Ingred Name:PYRAZINE, ETHYL-; (2-ETHYLPYRAZINE) (ETHYLPYRAZINE)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TOXICOLOGICAL PROPERTIES HAVE NOT BEEN
THOROUGHLY INVESTIGATED. POSSIBLE TOXIC VIA ORAL, SKIN AND MUCOUS
MEMBRANES. PROLONGED OR EXCESSIVE EXPOSURE MAY CAUSE IRRITATION IN
SENSITIVE INDIVIDUALS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:SKIN:REMOVE CONTAM CLTHG, RINSE LIBERALLY WITH SOAP AND WATER
FOR A CONSIDERABLE PERIOD. CALL A DOCTOR. INGEST:RINSE MOUTH
SEVERAL TIMES W/WATER, DO NOT SWALLOW. CALL A MD OR TAKE PATIENT TO
CALL A DOCTOR OR TAKE PATIENT TO A HOSPITAL. INHAL:TAKE THE PATIENT
INTO THE FRESH AIR AND ALLOW TO REST. CALL MD OR TAKE PATIENT TO A
HOSPITAL.
* Fire Fighting Measures *
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS EXPOSED TO HEAT OR FLAMES.
* Accidental Release Measures *
Spill Release Procedures:SWEEP INTO SUITABLE CONTAINER FOR DISPOSAL.
ABSORB THE LIQUID IN DRY SAND, DIATONITE, VERMICULITE, ETC. SHOVEL
THE MIXTURE INTO PLASTIC BAGS AND REMOVE TO THE CENTRAL DEPOT FOR
CHEMICAL WASTE.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:ROOM TEMPERATURE.
* Physical/Chemical Properties *
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS
Stability Condition to Avoid:
Hazardous Decomposition Products:TOXIC FUMES OF NO*X, CO, CO*2
* Disposal Considerations *
Waste Disposal Methods:INCINERATE OR LANDFILL AS COMPLIES WITH FEDERAL,
STATE AND LOCAL LAWS .
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED DUST RESPIRATOR WHERE
CONCENTRATIONS EXCEED LIMITS.
Ventilation:ADEQUATE TO MAINTAIN DUST BELOW LIMITS.
Other Protective Equipment:NOT REQUIRED. EMERGENCY EYEWASH AND DELUGE
SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CARBON BLACK
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:LYCOPODIUM
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE IRRITATION. CHRONIC:
PROLONGED OVEREXPOSURE MAY CAUSE SIDEROSIS. LOW ORAL TOXICITY.
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOLUME
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE
OXYGEN OR ARTIFICIAL RESPIRATION) . EYES: FLUSH THOROUGHLY WITH
SURFACES , SEEK MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN:
WASH WITH SOAP AND WATER. INGESTION: CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:THIS MATERIAL IS A SLIGHT FIRE HAZARD
WHEN EXPOSED TO HEAT OR FLAME. UNLESS STIRRED AND SPARKS ARE
APPARENT BURNING MAY NOT BE NOTICED.
* Accidental Release Measures *
Spill Release Procedures:RECOMMENDED USE OF A VACUUM WITH A HEPA
FILTER. WHEN SWEEPING USE A DUST SUPPRESSANT.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:
Other Precautions:
* Physical/Chemical Properties *
Spec Gravity:1.4
Solubility in Water:PARTIALLY SOLUBLE
Appearance and Odor:BLACK POWDER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
PURE OXYGEN OR OTHER STRONG OXIDIZERS.
Stability Condition to Avoid:GENERATION OF AIRBORNE DUST.
Hazardous Decomposition Products:NONE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL REGULATIONS.
DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS
.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE
NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR OR RESPIRATOR FOR ACID
REGULATIONS PERTAINING TO RESPIRATOR USE.
Ventilation:NOT NORMALLY REQUIRED. USE LAB HOOD OR OTHER LOCAL EXHAUST
TO MAINTAIN EXPOSURE BELOW PEL/TLV.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER, LAB COAT
OR APRON TO PROTECT EXPOSED SKIN.
Work Hygienic Practices:USE GOOD CHEMICAL HYGIENE PRACTICE. AVOID ALL
CONTACT IF POSSIBLE.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SULFURIC ACID (SARA III)
< Wt:5.
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
Ingred Name:CADMIUM (SARA III)
Fraction by Wt: <0.1%
Other REC Limits:NONE SPECIFIED
Ingred Name:FERROUS AMMONIUM SULFATE
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG FE/M3
ACGIH TLV:1 MG FE/M3
Ingred Name:WATER
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SULFURIC ACID IS CORROSIVE TO ALL BODY
TISSUES, PRODUCING BURNS ON CONTACT. ITS TOXICITY IS DUE TO ITS
CORROSIVITY. CHRONIC EXPOSURE TO LOW LEVEL FUMES OR MIST MAY CAUSE
TOOTH EROSION AND/OR LUNG SC ARRING.
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS CADMIUM, LISTED BY
IARC AND NTP A CARCINOGEN.SEE INDIVIDUAL REPORTS FOR DETAILS.
Effects of Overexposure:EYE: SEVERE IRRITATION,BURNS SKIN:SEVERE
IRRITATION,BURNS. INHALED;IRRITATION,BURNS TO RESPIRATORY
TRACT,COUGHING. INGESTED:G/I DISTRESS,BURNS. CHRONIC OVEREXPOSURE
MAY RESULT IN IRON POISONING.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT OR
LIVER MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE
REUSE. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING IF
NECESSARY.INGESTED:D O NOT INDUCE VOMITING. GIVE 2 LARGE GLASSES
OF MILK OR WATER AND GET IMMEDIATE MEDICAL CARE. GIVE NOTHING BY
MOUTH IF UNCONSCIOUS. IF IRRITATION PERSISTS OR IS SEVERE,SEE A
DOCTOR.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:PRODUCT IS NON FLAMMABLE. EXTINGUISH FIRE WITH
MEDIA APPROPRIATE FOR SOURCE OF FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:COVER WITH NEUTRALIZER. WIPE UP WITH CLOTH OR
PAPER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN COOL DRY AREA.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. AVOID CONTACT WITH
EYES ,SKIN, CLOTHING. DO NOT BREATHE CHEMICALS. OBSERVE
INCOMPATIBILITIES.
* Physical/Chemical Properties *
HCC:C1
NRC/State Lic Num:NOT RELEVANT
pH:0.9
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIGHT GREEN LIQUID, NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG BASES
Stability Condition to Avoid:HEAT, LIGHT, EXPOSURE TO AIR
Hazardous Decomposition Products:OXIDES OF SULFUR AND HYDROGEN
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL
REGULATIONS. MANUFACTURER SUGGESTS THAT DISPOSAL MAY BE DONE BY
FLUSHING NEUTRALIZED MATERIAL TO DRAIN.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR RESPIRABLE FUME RESPIRATOR/AIR SUPPLIED
RESPIRATOR WHEN WELDING IN CONFINED SPACE, WHERE LOCAL
EXHAUST/VENTILATION DOES NOT KEEP EXPOSURE BELOW TLV.
Ventilation:LOCAL EXHAUST AT ARC TO KEEP FUMES/GASES BELOW TLV IN
WORKER'S BREATHING ZONE & GENERAL AREA.
Other Protective Equipment:ARM PROTECTOR, APRON, HAT, SHOULDER
PROTECTION, DARK SUBSTANTIAL CLOTHING.
Supplemental Safety and Health
IS NON HAZARDOUS UNTIL USED AS IN WELDING PURPOSES. THE COMPOSITION &
QUANTITY OF FUMES/GASES DEPENDS ON METAL BEING WELDED, PROCESS,
PROCEDURES, ELECTRODES USED, COATINGS, POSITION OF WELDERS HEAD W/
RESPECT TO THE PLUME & AS WELL AS THE PRESENCE OF CONTAMINANTS IN
THE ATMOSPHERE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MANGANESE
Minumum % Wt:2.
Maxumum % Wt:3.
OSHA PEL:C5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:NATURAL CALCIUM CARBONATE
Ingred Name:FLUORSPAR
Ingred Name:QUARTZ
OSHA PEL:see Table Z-3
ACGIH TLV:0.1 MG/M3
Ingred Name:SODIUM SILICATE
Ingred Name:SILICATE BINDER
Ingred Name:TITANIUM DIOXIDE
Ingred Name:ZIRCONIUM SILICATES
ACGIH TLV:5 MG/M3
Ingred Name:IRON
Ingred Name:NICKEL
Minumum % Wt:1.
Maxumum % Wt:2.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:CHROMIUM
< Wt:1.
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:MOLYBDENUM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES:
DIZZINESS, NAUSEA, DRYNESS, IRRITATION OF NOSE/THROAT/LUNGS & EYES,
LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON
BUILDUP IN THE LUNGS, BONE ERO SION, REDUCED PULMONARY FUNCTIONS &
NERVOUS DISORDERS.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:SHORT TERM EXPOSURE TO WELDING FUMES:
DIZZINESS, NAUSEA, DRYNESS, IRRITATION OF NOSE/THROAT/LUNGS & EYES.
LONG TERM EXPOSURE TO WELDING FUMES: RESPIRATORY PROBLEMS, IRON
BUILDUP IN THE LUNGS, BONE ERO SION, REDUCED PULMONARY FUNCTIONS &
NERVOUS DISORDERS.
Medical Cond Aggravated by Exposure:PRE-EXISTING IMPAIRED
RESPIRATORYFUNCTIONS/INDIVIDUALS W/ALLERGIC CONDITIONS.
* First Aid Measures *
First Aid:IF OVERCOME BY SMOKE/FUMES, INHALATION: REMOVE TO FRESH AIR.
GIVE OXYGEN IF NEEDED. EMPLOY FIRST AID TECHNIQUES RECOMMENDED BY
THE RED CROSS. FOR ELECTRIC SHOCK: DISCONNECT & TURN OFF THE POWER.
IF N OT BREATHING, GIVE MOUTH TO MOUTH. IF NO PULSE, GIVE CPR. FOR
ARC BURN: APPLY COLD CLEAN COMPRESSES. OBTAIN MEDICAL ATTENTION IN
ALL CASES.
* Fire Fighting Measures *
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE
COMBUSTIBLE & FLAMMABLE PRODUCTS.
*Handling and Storage *
Handling and Storage Precautions:MONITOR THE AIR TO ENSURE THE LEVELS
ARE <THE RECOMMENDED LIMITS. WEAR APPROPRIATE EQUIPMENT TO PREVENT
INJURY FROM RADIATION/SPARKS/ELECTRIC SHOCK.
Other Precautions:TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS &
INSULATE THEMSELVES FROM WORK & GROUND. ELECTRIC ARC WORKING, FUMES
& GASES CAN BE DANGEROUS TO YOUR HEALTH. ELECTRIC SHOCK CAN KILL
YOU. ARC RAYS CAN INJURE EYES & BURN SKIN. NOISE CAN DAMAGE
HEARING.
* Physical/Chemical Properties *
Appearance and Odor:SOLID, FLUX COATED STEEL CORE WIRE, ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
(SEE SUPPLEMENTAL DATA)
Stability Condition to Avoid:(SEE SUPPLEMENTAL DATA)
Hazardous Decomposition Products:COMPLEX OF OXIDES OF IRON, MANGANESE,
SILICON, CHROMIUM, NICKEL, MOLYBDENUM, CALCIUM, MAGNESIUM,
TITANIUM, CO, CO2, OZONE & NITROGEN OXIDES
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE
CONTAINER/LINER IN AN ENVIRONMENTALLY ACCEPTABLE MANNER. DISPOSE OF
IN ACCORDANCE W/LOCAL, STATE & FE DERAL REGULATIONS.
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR
VAPORS DURING SPRAY APPLICATION. IN CONFINED AREAS: USE NIOSH
Ventilation:PROVIDE GENERAL DILUTION/LOCAL EXHAUST VENT IN VOL &
PATTERN TO KEEP TLV OF HAZ INGREDIENTS BELOW ACCEPTABLE LIMITS.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . CLOTHING TO PREVENT SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:RWB/AMB
* Composition/Information on Ingredients *
Fraction by Wt: 0.5%
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL). LEL: 1.1% VP: 0.9 @
Fraction by Wt: 0-3%
Fraction by Wt: 1-4%
Fraction by Wt: 1%
Ingred Name:SUPDAT: WITH PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE.
Ingred Name:ING 9:ASSOCIATED WITH LIVER, KIDNEY, LUNG, SPLEEN AND EYE
ABNORMALITIES IN LAB ANIMALS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISSUES, BLOOD,
KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER
APPEARS ON THE NAVY LISTING OF OCCUP CHEM REPROD HAZ. SEEK (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . ACUTE: INHAL: HARMFUL IF INHALED. MAY AFFECT BRAIN/NERVOUS
SYS CAUSING DIZZ, HDC H/NAUSEA. RPTD OVEREXPS MAY PROGRESSIVELY
LEAD TO STAGGERING GAIT, CONFUSION, UNCONSCIOUSNESS/COMA. CAUSES
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: REMOVE FROM EXPOSURE, RESTORE BREATHING & NOTIFY A MD.
MIN. NOTIFY A MD. SKIN: WASH AFFECTED AREA W/SOAP & WATER, REMOVE
CONTAMIN ATED CLOTHING & WASH BEFORE REUSE. INGEST: DO NOT INDUCE
VOMITING. KEEP PERSON WARM, QUIET & GET MED ATTN. ASPIRATION OF
THIS MATERIAL INTO THE LUNGS CAN CAUSE CHEM PNEUMONITIS WHICH CAN
BE FATAL.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:SEE INGRED
Extinguishing Media:HFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY
CHEMICAL OR FOAM).
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. H*2O MAY BE USED TO COOL CLSD CNTNRS TO
PVNT PRESS BUILD-UP & POSSIBLE (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPARKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. DO NOT APPLY TO HOT SURFS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA
AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
PUNCTURE/INCINERATE CNTNRS. INTENTIONAL MISUSE BY DELIB
CONCENTRATING & INHALING CONTENTS MAY BE HARMFUL OR FATAL.
CONTAIN CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSE BIRTH
DEFECTS OR OTHER REPRODUCTIVE HARM.
FIRE FIGHT PROC: AUTOIGNITION/EXPLOSION. IF H*2O IS USED, FOG NOZZLES
ARE PREFERRED. EFTS OF OVEREXP: NOSE & THROAT IRRIT. SKIN/EYES:
CAUSES EYE & SKIN IRRIT WHICH CAN LEAD TO DERM W/RPTD OVEREXP. ING
EST: MAY CAUSE GI IRRIT, NAUSEA, VOMIT & DIARR. CHRONIC: RPTS HAVE
ASSOC RPTD & PRLNGD OCCUP OVERXP TO SOLVENTS (ING 9)
* Physical/Chemical Properties *
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER (ETHER = 1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY OPEN FLAME: CARBON MONOXIDE AND
CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL
REGULATIONS. DO NOT INCINERATE CLOSED CONTAINERS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED WITH ADEQUATE VENTILATION. USE
NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN
.
Ventilation:LOCAL/MECHANICAL: ACCEPTABLE.
Other Protective Equipment:NONE REQUIRED.
Work Hygienic Practices:USE NORMAL GOOD HOUSEKEEPING PRACTICES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:NEVER FREEZE COPPER PASTE
* Composition/Information on Ingredients *
Ingred Name:COPPER
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2MG/M3 FUME
Ingred Name:GRAPHITE
ACGIH TLV:2 MG/M3 RDUST
Ingred Name:PETROLEUM CARRIER
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NO ACUTE OR CHRONIC HEALTH HAZARDS
KNOWN. TOXICOLOGICAL STUDIES INDICATE PRODUCT IS NONIRRITATING TO
SKIN/EYES AND IS NONTOXIC BY INGEST.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
LIDS APART, GET MED ATTN. SKIN: WASH WITH SOAP AND WATER. INGEST:
LARGE AMOUNTS MAY RESULT IN DIARRHEA. GET MED ATTN; TREAT
SYMPTOMATICALLY . INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE
O*2/ARTF RESP) .
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:USE WATER FOG, DRY CHEMICALS, FOAM/CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE, EXCEPT AS FOR PETROLEUM GREASE
FIRES.
* Accidental Release Measures *
Spill Release Procedures:WIPE UP WITH RAGS/ABSORBENT MATERIAL. COMPLETE
CLEAN-UP USING DETERGENT AND WATER, OR CHLORINATED SOLVENT OR HIGH
FLASH POINT SOLVENT CLEANER WITH ADEQUATE VENTILATION.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:USE NORMAL STORAGE AND HANDLING. DO
NOT EXPOSE TO HIGH HEAT, OPEN FLAMES, OR STRONG OXIDIZERS.
Other Precautions:CONTAINS HYDROCARBONS-DO NOT USE IN OXYGEN SERVICE.
KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
Vapor Pres:NEGLIGLBLE
Solubility in Water:INSOLUBLE
Appearance and Odor:COPPER COLORED PASTE, SLIGHT PETROLATUM ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS (PEROXIDES, PERMANGANATES, NITRIC ACID,
ETC).
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:PYROLYSIS YIELDS CO, CO*2, AND
INCOMPLETELY BURNED HYDROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE, AND FEDERAL
REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NOISH APPROVED, SELF-CONTAINED BREATHING
BY NIOSH. CONSULT ANSI STANDARD &OSHA REGULATIONS CONCERNING THE
USE OF RESPIRATORY EQU IPMENT. AVOID PROLONGED EXPOSURE TO
EXCESSIVE CONCENTRATIONS.
Ventilation:LOCAL EXHAUST: MATERIAL TRANSFER& HANDLING SHOULD BE
CONDUCTED WITH AN EXHAUST SYSTEM. MECHANICAL: ALL INDOOR AREAS
SHOULD BE WELL VENTILATED.
POSSIBILITY.
NOT WEAR CONTACT LENSES.
Other Protective Equipment:NONE
Work Hygienic Practices:DETERMINE THAT PIPING IS EMPTY BEFORE DOING
MAINTENANCE WORK. PERIODICALLY CHECK CYLINDERS TO ENSURE VALVES ARE
NOT LEAKING.
Supplemental Safety and Health
NONE
* Product Identification *
Resp. Party Other MSDS Num.:
Preparer's Name:RESEARCH SERVICES DEPT
CAGE:1CSX7
* Composition/Information on Ingredients *
Ingred Name:BROMOTRIFLUOROMETHANE
Code:F
Ozone Depleting Chemical:1
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:APPROX. LETHAL CONCENTRATIONS OF HALON
HRS. THE COMPOUND IS REPORTED TO BE NON-MUTAGENIC IN THE AMES
LABORATORIES CLASSIFICATION OF COMPARATIVE LIFE HAZARDS OF FIRE
EXTINGUISHING AGENTS. (CONTINUED IN "SIGNS AND SYMPTOMS OF
OVEREXPOSURE" FIELD/SCREEN.)
Explanation of Carcinogenicity:NTP: NO. IARC MONOGRAPHS: NO. OSHA
REGULATED: NO.
Effects of Overexposure:SMOKING WHERE THIS CHEMICAL IS RELEASED CAN
CAUSE FORMATION OF TOXIC AND IRRITATING HALOGENS AND HALOGEN ACIDS
WHICH COULD BE INHALED WITH THE SMOKE. AVOID EXPOSURE TO THE
PRODUCT AND DECOMPOSITION PR ODUCTS WHEN WEARING CONTACT LENSES;
INTOXICATION. ANESTHETIC EFFECTS END RAPIDLY AFTER EXPOSURE IS
Medical Cond Aggravated by Exposure:CARDIAC CONDITIONS MAY BE
AGGRAVATED BY OVEREXPOSURE.
* First Aid Measures *
First Aid:INHALATION: MOVE PERSON TO FRESH AIR; IF NOT BREATHING, GIVE
CPR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION.
SKIN: FLUSH WITH WATER. GET MEDICAL ATTENTION IF FROSTBITE OCCURS.
EYE S: FLUSH WITH WATER, GET MEDICAL ATTENTION. NOTE: EPINEPHRINE
IS CONTRAINDICATED IN THE TREATMENT OF OVER-EXPOSURE TO THIS
PRODUCT.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE.
SPRAY TO COOL CYLINDER INVOLVED IN FIRES. USE MEDIA SUITABLE FOR
FLAMMABLE MATERIALS IN THE AREA.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:PREDOMINANT DECOMPOSITION PRODUCTS ARE
HYDROGEN FLUORIDE & HYDROGEN BROMIDE IN FIRE SITUATIONS. THE
PRODUCTS ARE IRRITATING & POTENTIALLY TOXIC IF FIRE EXTINGUISHMENT
HYDROGEN FLUORIDE, HYDROGEN BROMIDE, CARBONYL FLUORIDE & CARBONYL
BROMIDE.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. WEAR SELF-CONTAINED BREATHING
APPARATUS, VENTILATE ENCLOSED AREAS IN CASE OF DISCHARGE.
*Handling and Storage *
Handling and Storage Precautions:PROTECT CYLINDERS FROM PHYSICAL
SHOULD BE SECURED FOR STORAGE WITH VALVE PROTECTION CAP IN PLACE
Other Precautions:DOT: COMPRESSED GAS. N.O.S. (BROMOTRIFLUOROMETHANE)
* Physical/Chemical Properties *
HCC:G3
Vapor Density:5.1
Evaporation Rate & Reference:NOT AVAILABLE
Appearance and Odor:ODORLESS, COLORLESS GAS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACTIVE METALS, FIRE OF METAL HYDRIDES, MATERIAL CONTAINING OWN OXYGEN.
PRODUCT WILL NOT EXTINGUISH FIRES OF THESE MATERIALS. PRODUCT MAY
DEGRADE CERTAIN POLYMERIC MATERIALS.
Stability Condition to Avoid: LISTED.
Hazardous Decomposition Products:IN THE PRESENCE OF FLAMES OR HOT
SURFACES: HYDROGEN FLUORIDE, HYDROGEN BROMIDE, BROMINE, CARBONYL
FLUORIDE, & CARBONYL BROMIDE. SMOKING CAN CAUSE FORMATION OF THESE
CHEMICALS & MUST BE AVOIDED.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:RETURN CYLINDERS TO GREAT LAKES CHEMICAL
CORPORATION, EL DORADO, ARKANSAS.
* MSDS Transport Information *
Transport Information:DOT: PSN: BROMOTRIFLUOROMETHANE, NONFLAMMABLE
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED SCBA IN OXYGEN-DEFICIENT
ATMOSPHERES. CAUTION! RESPIRATORS WILL NOT FUNCTION. USE MAY RESULT
IN ASPHYXIATION.
Ventilation:NATURAL OR MECH WHERE GAS/VAP ARE PRESENT. LOCAL & MECH AS
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:FROM EXPOS TO LIQ ARGON OR COLD ARGON GAS. FIRST AID
PROC:BURNS WHICH RSLT IN BLISTERING OR DEEPER TISS FREEZING SHOULD
BE SEEN PROMPTLY BY A MD. SPILL PROC:THAN AIR & MAY TEND TO COLL
ECT IN LOW AREAS IF VENT IS NOT ADEQ. WASTE DISP METH:CYL TO AIR
PRODS W/RESIDUAL PRESS, CYL VALVE (SEE INGRED 2)
* Product Identification *
Product ID:ARGON OR LAR (IN CRYOGENIC LIQUID STATE)
* Composition/Information on Ingredients *
Ingred Name:ING 8:INTO STOR CONTR. AVOID DRAGGING, ROLLING OR SLIDING
Ingred Name:ING 9:TRUCK. FOR ADDNL HNDLG RECOMMONDATIONS ON COMPRESSED
SPECIFICAITON OR ASME CODES.
Ingred Name:OTHER PREC:EXCEPT BY QUALIFIED PRODUCERS OF COMPRESSED
Ingred Name:VENT:THAN NORM CONC OF ARGON IN WORK AREAS.
Ingred Name:ING 7:CYL WHEN IN USE. NEVER USE DIRECT FLAME TO HEAT A
COMPRESSED GAS CYL. USE A CHECK VALVE TO PVNT BACKFLOW (ING 9)
Ingred Name:ARGON
Ingred Name:SUPP DATA:TIGHTLY CLOSED & VALVE CAPS IN PLACE.
Ingred Name:HNDLG/STOR PREC:ACCIDENTAL KNOCKING OVER OR DAM FROM
PASSING OR FALLING OBJECTS. VALVE CAPS SHOULD REMAIN ON CYL (ING 4)
Ingred Name:ING 3:NOT CONNECTED FOR USE. SEGREGATE FULL & EMPTY CYL.
STOR AREAS SHOULD BE FREE OF COMBUST MATL. AVOID EXPOS (ING 5)
Ingred Name:ING 4:TO AREAS WHERE SALT OR OTHER CORR CHEMS ARE PRESENT.
PVNT CONT OF LIQ ARGON W/EXPOSED SKIN. PVNT ENTRAPMENT(ING 6)
Ingred Name:ING 5:OF LIQ IN CLSD SYS. USE ONLY IN WELL VENTD AREAS.
COMPRESSED GAS CYL CONTAIN ARGON AT EXTREMELY HIGH PRESS (ING 7)
Ingred Name:ING 6:& SHOULD BE HNDLD W/CARE. USE A PRESS-REDUCING
REGULATOR WHEN CONNECTING TO LOWER PRESS PIPING SYS. SECURE (ING 8)
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ARGON IS A SIMPLE ASPHY & HAS NO TLV.
ARGON IS ODORLESS & NONTOX, BUT MAY PRDCE SUFFOCATION BY DILUTING
THE CONC OF O2 IN AIR BELOW LEVELS NEC TO SUPPORT LIFE. PERS, INCL
RESCUE WORKERS, SHOULD NOT EN TER AREAS WHERE THE O2 CONC IS BELOW
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:RESP. EXPOS TO O2-DEFICIENT ATM MAY
PRDCE DIZZ, NAUS, VOM, LOSS OF CONSCIOUSNESS & DEATH. DEATH MAY
RSLT FROM ERRORS IN JUDGMENT, CONFUSION OR LOSS OF CONSCIOUSNESS
WHICH PVNTS SELF RESCUE. A T LOW O2 CONC UNCON & DEATH MAY OCCUR IN
SECONDS W/OUT WARNING. EXTENSIVE TISS DAM OR BURNS CAN RSLT (SEE
SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:PERS SUFFERING FROM LACK OF O2 SHOULD BE MOVED TO AREAS
W/NORM ATMS. NIOSH/MSHA SCBA MAY BE REQD TO PVNT ASPHY OF RESCUE
WORKERS. ASSISTED RESP & SUPP O2 SHOULD BE GIVEN IF THE VICTIM IS
NOT BRT HG. EYE/SKIN:IF CRYOGENIC LIQ OR COLD BOIL-OFF GAS CONTACTS
A WORKERS SKIN OR EYES, FROZEN TISS SHOULD BE FLOODED OR SOAKED
DATA)_
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS .
Fire Fighting Procedures:NOT APPLICABLE.
Unusual Fire/Explosion Hazard:NOT APPLICABLE.
* Accidental Release Measures *
Spill Release Procedures:AVOID CONT OF SKIN W/LIQ ARGON OR ITS COLD
BOIL-OFF GAS. FLUSH LIQ ARGON SPILL W/WATER TO DISPERSE. VENT
ENCLSD AREAS TO PVNT FORMATION OF O2-DEFICIENT ATM CAUSED BY THE
EVAP OF LIQ ARGON OR THE RELS OF GASEOUS ARGON. ARGON IS HVR (SEE
SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE LIQ CONTRS & CYL IN WELL-VENTD
AREAS. KEEP CYL AWAY FROM SOURCES OF HEAT. STOR SHOULD NOT BE IN
HEAVY TRAFFIC AREAS TO PVNT (SEE INGRED 3)
Other Precautions:LIQ ARGON IS CRYOGENIC LIQ. MATLS OF CONSTRUCT MUST
BE SELECTED FOR COMPATIBILITY W/EXTREMELY LOW TEMPS. AVOID USE OF
CARBON STELL & OTHER MATLS WHICH BECOME BRITTLE AT LOW TEMPS.
* Physical/Chemical Properties *
HCC:G3
Appearance and Odor:BOTH LIQUID AND GASEOUS ARGON ARE COLORLESS &
ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:ALLOW LIQ ARGON TO EVAP IN A WELL VENTD OUTDOOR
LOCATION REMOTE FROM WORK AREAS. VENT ARGON GAS SLOWLY TO A WELL
VENTD OUTDOOR LOCATION REMOTE FROM WORK AREAS. DO NOT ATTEMPT TO
DISPOSE OF RESIDUAL AR GON IN COMPRESSED GAS CYL. RETURN (SEE SUPP
DATA)
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV OF THE PRODUCT OR ANY COMPONENT IS
EXCEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR. IF VAPOR EXPOSURE
CAUSES EYE DISCOMFORT, USE A NIOSH/MSHA APPROVED FULL-FACE
RESPIRATOR.
Ventilation:PROVIDE GENERAL AND/OR EXHAUST VENTILATION TO CONTROL
AIRBORNE LEVEL BELOW THE EXPOSURE GUIDELINES.
Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN
CONTACT, WEAR IMPERVIOUS CLOTHING AND SHOES.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING IMMEDIATELY. WASH
SKIN AREA WITH SOAP & WATER. LAUNDER CLOTHES BEFORE REUSE.
Supplemental Safety and Health
EFTS OF OVEREXP: ANIMAL STUDIES CLEARLY DEMONSTRATED DOSE-RELATED
ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER,
ASSOC W/ADMINISTRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE).
RESPIRATORY SYMPTOMS DEVELOP, CONSULT MED PERS.
* Product Identification *
Preparer's Name:PATRICE BLACKMON
* Composition/Information on Ingredients *
Fraction by Wt: 9%
Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (SILICA (QUARTZ))
OSHA PEL:SEE TABLE Z3
Ingred Name:PHTHALIC ACID, DIBUTYL ESTER; (DIBUTYL PHTHALATE) (SARA
Fraction by Wt: 2%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:HNDLG/STOR PREC: BELOW TLV. CONTRS OF PROD MAY BE HAZARDOUS
WHEN EMPTIED - ALL HAZARD PREC MUST BE OBSERVED. (ING 5)
Ingred Name:ING 4: KEEP OUT OF REACH OF CHILDREN.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL:INHAL OF HIGH CONC OF
VAPS CAN INDUCE ANEMIA, LIVER/KIDNEY INJURY & CLOUDING OF CORNEA.
MAY IRRIT NOSE/ THROAT/RESP PASSAGES. HIGHER CONC CAN INDUCE
HDACH/DIZZ/NAUS/DROW/SHORTNESS OF BREA TH. SKIN CONT: NO IRRIT IS
LIKELY TO DEVELOP FOLLOWING SHORT CONT. PRLNG/RPD EXPOS CAN LEAD TO
REDNESS/ (EFTS OF OVEREXP
Explanation of Carcinogenicity:SILICA (QUARTZ): GROUP 2 (NTP), GROUP 2A
(IARC). CARBON BLACK EXTRACTS: GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ: SWELLING/NECROSIS. EYE CONT: CAN
INDUCE PAIN/MOD IRRIT. SKIN ABSORPTION: ADVERSE SYSTEMIC EFTS CAN
DEVELOP FOLLOWING RPTD/PRLNG CONT. INGEST: A SINGLE DOSE IS MOD
TOXIC. CHRONIC: PRLNG OVERE XP BY INHAL MAY CAUSE DELAYED LUNG
INJURY/ DISEASE (SILICOSIS). TAKE APPROPRIATE MEASURE TO AVOID
BRTHG DUST.(SUPP DATA)
Medical Cond Aggravated by Exposure:PULMONARY AND/OR RESPIRATORY
DISEASES.
* First Aid Measures *
First Aid:SKIN: REMOVE CONTAMD CLTHG/FOOTWEAR. WASH SKIN W/SOAP &
WATER. IF REDNESS/ITCHING &/OR BURNING SENSATION DEVELOPS, GET MED
ATTN. WASH CONTAMD CLTHG & DECONTAM FOOTWEAR BEFORE REUSE. EYES:
MED PERS. INGEST: GIVE 1-2 GLASSES OF WATER TO DRINK. INDUCE VOMIT.
REFER VICTIM TO MED PERS. INHAL: MOVE TO FRESH AIR. IF COUGH/OTHER
(SUPP DATA)
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:0.5%
Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE/EXPLOSION HAZARDS ARE
KNOWN FOR THIS PRODUCT. AS TYPICAL OF CLOSED CONTAINERS CONTAINING
LIQUID, THEY MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:DIKE AND CONTAIN SPILL WITH INERT MATERIALS
(SAND, CLAY, EARTH, ETC.). TRANSFER THE LIQUID TO CONTAINERS FOR
RECOVERY OR DISPOSAL. KEEP SPILL OUT OF SEWERS AND OPEN BODIES OF
WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP FROM FREEZING. KEEP AWAY FROM
HEAT/OPEN FLAME. AVOID BRTHG VAP. AVOID CONT WITH EYES/ SKIN/CLTHG.
USE W/VENT ADEQ TO MAINTAIN VAP CONC (ING 4)
* Physical/Chemical Properties *
HCC:N1
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:1.1-1.3(H2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MISCIBLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIAL & HYDROFLUORIC ACID.
Stability Condition to Avoid:EXCESSIVE HEAT.
Hazardous Decomposition Products:COMBUSTION PRODUCTS: CO2, CO.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REQUIREMENTS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR SPILL OCCURS;
USE NIOSH/MSHA APPROVED RESPIRATOR WITH HEPA CARTRIDGE, OR SUPPLIED
Ventilation:USE LOCAL EXHAUST OR GENERAL MACHANICAL VENTILATION TO KEEP
EXOOSURE LEVELS BELOW REGULATORY LIMITS.
Other Protective Equipment:AS APPROPRIATE TO PROTECT AGAINST PROLONGED
OR REPEATED CONTACT. HMIS: EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFOR REUSE.
Supplemental Safety and Health
FIRST AID CONTINUED: INGESTED: DIURETIC MAY SPEED UP LOSS OF SELENIUM.
USE VITAMIN B COMPLEX, VITAMIN C, AND METHIONE SUPLLEMENT AS
RECOMMENDED.
* Product Identification *
Preparer's Name:NONE
* Composition/Information on Ingredients *
Ingred Name:SELENIOUS ACID (SARA III)
Fraction by Wt: <4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 MG SE/M3
Ingred Name:CUPRIC NITRATE (SARA III)
Fraction by Wt: <4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG CU/M3
Ingred Name:NITRIC ACID (SARA III)
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 PPM/4 STEL
Ingred Name:PHOSPHORIC ACID (SARA III)
Fraction by Wt: <3%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3/3 STEL
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION OF MISTS MAY CAUSE
IRRITATION OF RESPIRATORY SYSTEM AND CENTRAL NERVOUS SYTEM EFFECTS.
CONTACT WITH SKIN AND EYES MAY CAUSE IRRITATION, CONJUNCTIVITIS, OR
SKIN SENSITIZATION. INGESTI ON MAY CAUSE SEVERE DIGESTIVE TRACT
DISTURBANCES AND CENTRAL NERVOUS SYSTEM EFFECTS. CHRONIC: KIDNEY
AND LIVER DAMAGE.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALATION: COUGHING, SHORTNESS OF BREATH, LOSS
OF SMELL, GARLIC ODOR OF BREATH, HEADACHE, DIZZINESS, LASSITUDE,
TREMORS, DIFFICULTY BREATHING. EYES: REDNESS, SWELLING, TEARING.
SKIN: REDNESS, DISCOMF ORT. INGESTED: MEATLLIC TASTE, NAUSEA,
VOMITING, ABDOMINAL PAIN, HEADACE, DIZZINESS, LASSITUDE, DIFFICULTY
BREATHING.
Medical Cond Aggravated by Exposure:THOSE WITH WILSON'S DISEASE,
PRE-EXISTING SKIN, LUNG, LIVER, KIDNEY OR GASTROINTESTINAL DISEASES
SHOULD BE PRECLUDED FROM EXPOSURE FROM THIS MATERIAL.
* First Aid Measures *
First Aid:INHALED: MOVE TO FRESH AIR. IF BREATHING DIFFICULT, GIVE
OXYGEN. IF BREATHING STOPPED, GIVE ARTIFICIAL RESPIRATION. SEE
THIOSULFATE S OLUTION. SEE DOCTOR. SKIN: REMOVE CONTAMINATED
CLOTHES. WASH WITH SOAP AND WATER. INGESTED: IF VICTIM CONSCIOUS
AND NOT VOMITING, INDUCE VOMITING. GET IMMEDIATE MEDICAL ATTENTION.
SEE SUPP. DATA
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
BUNKER GEAR.
Unusual Fire/Explosion Hazard:NON-FLAMMABLE/NON-EXPLOSIVE EXCEPT WITH
WATER REACTIVE COMPAONDS.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROPER PROETCTIVE CLOTHING. RECOVER AS
MUCH LIQUID AS POSSIBLE AND COLLECT IN AN ACID-PROOF CONTAINER. USE
ABSOBENT TO PICK-UP RESIDUE. AVOID DICHARGING LIQUID DIRECTLY TO
SEWER OR SURFACE WATERS . CERCLA REPORTABLE QUANTITY IS 1
POUND(SELENIUM)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. HMIS: SODIUM
BICARBONATE OR LIME.
*Handling and Storage *
Handling and Storage Precautions:AVOID CO-LOADING OR STORAGE WITH
CYANIDES, WATER REACTIVE COMPOUNDS, OR STRONG REDUCING AGENTS.
STORE IN ACID RESISTENT CONTAINERS.
Other Precautions:WORKERS HANDLING THIS PRODUCT SHOULD WASH HANDS AFTER
USE AND BEFORE EATING, DRINKING, OR SMOKING.
* Physical/Chemical Properties *
HCC:C1
Vapor Density:<1 (AIR=1)
pH:1.4
Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:ODORLESS, BLUE LIQUID
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CYANIDES, WATER-REACTIVE COMPOUNDS, ORGANIC SOLVENTS, OILS, STRONG
REDUCING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:ORGANOSELENIDES OR HYDROGEN SELENIDES
FROM REACTIONS. SELENIUM DIXODE, OXIDES OF NITROGEN AND PHOSPHOROUS
FROM HEAT.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCODRDANCE WITH LOCAL, STATE AND
(SELENIUM-TOXICITY).
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:DO NOT BREATHE VAPS/MIST. WEAR APPROP, PROPERLY
FITTED NIOSH/MSHA APPROVED RESP DURING & AFTER APPLICATION UNLESS
AIR MONITORING DEMONSTRATES VAP/MIST LEVELS ARE BELOW APPLIC LIMS.
FOLLOW RESPIRATOR M FR'S DIRECTIONS FOR RESPIRATOR USE.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP
CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Other Protective Equipment:EMER EYE WASH & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA.COVERALLS REC. PROTECTIVE CREAMS (WORK HYGENIC
PRAC)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING
PROT.
Supplemental Safety and Health
EXPLO HAZ:PROPELLING CONTENTS ACROSS AREA. ING 7 CAN CHEM REACT
W/ALUMINUM IN SPRAY EQUIP & OTHER DEVICES & CAUSE EXPLO HAZ. PRODS
CNTNG THIS SOLV SHOULD NEVER BE USED W/SPRAY EQUIP WHERE COATING
COME S IN CONT W/ALUMINUM. CONT W/ALUMINUM PARTS IN PRESSURIZABLE
FLUID SYS MAY CAUSE VIOLENT RXN.
* Product Identification *
* Composition/Information on Ingredients *
LIST INFO & SAFE HNDLG & EXPOS INFO .
Ingred Name:OTHER PREC:MAY CAUSE THE FORMATION OF HCL &/OR PHOSGENE .
Ingred Name:ARIEN; (HYDROCARBON RESIN)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:IRON (III) OXIDE; (IRON OXIDE)
ACGIH TLV:5 MG/M3 FUME (FE)
Ingred Name:PROPANE; (LIQUIFIED COMPRESSED GAS)
ACGIH TLV:ASPHYXIANT
Ingred Name:MINERAL SPIRITS; (MEDIUM MINERAL SPIRITS)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA III).
Ingred Name:NONHAZARDOUS INGREDIENTS; (NON-HAZARDOUS POLYMER)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SILICONE RESIN
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:VM&P NAPHTHA; (ALIPHATIC HYDROCARBON)
Ingred Name:EXPLAN OF CARCIN:TO BE CARCIN. ANIMAL:LUNG, LIVER,
SALIVARY, MAMMARY GLAND (TUMORS).
Ingred Name:EFTS OF OVEREXP:MED ATTN. MAY CAUSE CNS EFTS SUCH AS
Ingred Name:ALKYD RESIN
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT AROMATIC; (AROMATIC
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGEST:GI DISTRESS. INHAL:OVEREXP MAY
CAUSE NOSE & THROAT IRRIT. MAY CAUSE CNS EFTS SUCH AS DIZZ, HDCH,
NAUS, STAG GAIT, CONFUSN & UNCON. RPTS HAVE ASSOC RPTD & PRLNG
OVEREXP TO SOLVS W/PERM BRAIN & N ERV SYS DMG, EYE WATERING, HDCHS,
NAUS,DIZZ & LOSS OF COORD ARE SIGNS THAT SOLV LEVELS ARE TOO HIGH.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS,
Effects of Overexposure:HLTH HAZ:SKIN/EYE CONT:MAY CAUSE EYE
IRRIT/BURNING. RPTD/PRLNG LIQ CONT MAY CAUSE SKIN IRRIT
LIVER & KIDNEY INJURY. ING 5:LIQUIFIED C OMPRESSED GAS MAY POSS
CAUSE MODEST INITIAL IRRIT, FOLLOWED IN HRS BY SEV SHORTNESS OF
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMEDIATELY & HAVE NAMES OF INGREDIENTS
AVAILABLE. DO NOT INDUCE VOMITING. INHAL:REMOVE TO FRESH AIR. IF
NOT BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH TO
MOUTH. IF BREATH ING DIFFICULTY PERSISTS OR OCCURS LATER, CONSULT
MINUTES; CALL MD. SKIN:WASH W/SOAP & WATER. IF IRRITATION OCCURS
CONTACT MD.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP. WATER MAY BE INEFT. WATER FROM FOG NOZZ MAY BE USED TO
COOL CLSD CNTNRS TO PVNT PRESS BUILD UP.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL HCL &
PHOSGENE . CONTENTS UNDER PRESS. KEEP AT ROOM TEMP AS EXPOS TO
SUNLIGHT/OTHER HEAT MAY CAUSE CANS TO BURST, (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT & BREATHING OF VAPOR. CONFINE & REMOVE W/INERT
ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:OBSERVE LBL PRECS. KEEP AWAY FROM
SUNLIGHT TO AVOID BURSTING. DO NOT PUNCTURE.
Other Precautions:DO NOT SAND, FLAME CUT, BRAZE/WELD DRY COATING W/OUT
NIOSH/MSHA APPRVD RESP/APPROP VENT. DO NOT SPRAY NEAR FIRE/OPEN
FLAME. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF ARC
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
Solubility in Water:MOD - APPRECIABLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Hazardous Decomposition Products:HCL, PHOSGENE . CO, CO*2, SMOKE OXIDES
OF HEAVY METALS REPORTED IN INGS.
* Disposal Considerations *
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL I/A/W FEDERAL, STATE &
LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:GENERAL VENTILATION SUFFICIENT TO KEEP AIRBORNE
CONCENTRATIONS BELOW EXPOSURE LIMITS .
Other Protective Equipment:BARRIER CREAM FOR SENSITIVE SKINS.
Work Hygienic Practices:NO SMOKING, EATING, DRINKING WHILE USING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:MAINTAIN WALLTEC
CAGE:0F2V0
CAGE:0F2V0
* Composition/Information on Ingredients *
Ingred Name:EPOXY RESIN; (LOW VISCOSITY EPOXY RESIN (BISPHENOL F
BASED))
Ingred Name:WATER SOLUBLE SOLVENT (POLYAMIDE)
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:IRON OXIDE
Ingred Name:WATER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED EXPOSURE MAY IRRITATE
SENSITIVE SKIN.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SENSITIVE SKIN.
* First Aid Measures *
ADVICE IF REQUIRED. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER .
INHALATION: REMOVE FROM EXPOSURE. SUPPORT BREATHING (GIVE
ARTIFICIAL RE SPIRATION/OXYGEN) . INGESTION: CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:RESIN COMPONENT MAY IGNITE WITH STRONG
OXIDIZING AGENTS.
* Accidental Release Measures *
Spill Release Procedures:ABSORB ONTO SAND OR PROPRIETARY ABSORBENT.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:1.1 (H*2O=1)
Solubility in Water:DILUTABLE
Appearance and Odor:YELLOW-BROWN LIQUID, VIRTUALLY ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:
Hazardous Decomposition Products:AMMONIA.
Conditions to Avoid Polymerization:VERY STRONG ACIDS.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE OR ALLOW TO CURE THEN DISPOSE.
DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS
.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY REQUIRED WHEN ADEQUATE EXHAUST IS
PROVIDED. IN SITUATIONS WHERE VAPOR CONCENTRATIONS MAY EXCEED THE
TLV'S USE A NIOSH/MSHA APPROVED RESPIRATOR WITH AN ORGANIC VAPOR
CARTRIDGE.
Ventilation:PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION.
Other Protective Equipment:ADEQUATE PROTECTIVE CLOTHING TO PREVENT SKIN
CONTACT.
Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE TO PREVENT
ACCIDENTAL EXPOSURE.
Supplemental Safety and Health
% VOL:VARIES WITH DILUTION. EFTS OF OVEREXP:OBSERVED. NIOSH RECOMMENEDS
THAT 2-ETHOXYETHYL ACETATE BE REGUARDED IN THE WORKPLACE AS HAVING
POTENTIAL TO CAUSE ADVERSE EFFECTS IN MALE & FEMALE WORKERS ( ).
* Product Identification *
Preparer's Name:ANGELA BOGGS
* Composition/Information on Ingredients *
Ingred Name:ETHANOL, 2-ETHOXY-, ACETATE;(2-ETHOXYETHYL ACETATE). VP:1.2
ACGIH TLV:5 PPM, S
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (SARA III).
Fraction by Wt: 9%
Fraction by Wt: 9%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VAPS ARE IRRIT TO EYES, NOSE, AND RESP
TRACT. OVEREXPOS TO VAP MAY RESULT IN HDCH, NAUS, VOM. VAPS HAVE AN
OBJECTIONABLE ODOR. INGEST MAY CAUSE HDCH, NAUS, VOM, DIZZ, WEAK.
POSS KIDNEY DAMAGE MAY RESU LT FROM INGEST OF LG QTYS OF MATL.
CHRONIC EFTS:CNTCT W/SKIN MAY CAUSE IRRIT W/PRLNGD CNTCT. (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:PRLNGD, RPTD CNTCT MAY RESULT IN DERM.
PRLNGD/WIDESPREAD CNTCT W/SKIN MAY LEAD TO ABSORP OF HARMFUL AMTS
OF SOLV W/ACCOMPANYING SIGNS & SYMP OF TOX AS DESCRIBED FOR
SWALLOWING. NOTE:WHEN LAB ANIMALS HAVE BEEN OVEREXPOS TO
2-ETHOXYETHYL ACETATE, BIRTH DEFECTS & ADVERSE EFTS ON PREGNANCY
HAVE BEEN (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST:CONTACT PHYSICIAN. EYE CONTACT:FLUSH WITH WATER
CONTACT:FLUSH SKIN WITH PLENTY OF WATER. CONTACT A PHYSICIAN IF
IRRITATION PE RSISTS. INHAL:MOVE TO FRESH AIR. SUPPORT BREATHING
(GIVE O*2/ARTF RESPIRATION .
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:SEE INGS
Extinguishing Media:ALCOHOL FOAM, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . USE NORMAL PROCEDURES FOR FLAMMABLE LIQUID
FIRES. CNTNRS NEAR FIRE MAY BE COOLED W/WATER.
Unusual Fire/Explosion Hazard:PRESSURE MAY BUILD UP IN CLOSED
CONTAINERS. THIS IS ACCELERATED BY HEAT WITH POSSIBLE LIBERATION OF
COMBUSTIBLE VAPORS.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE SOURCES OF IGNITION, PROVIDE
ADEQUATE VENTILATION AND SUITABLE PROTECTIVE CLOTHING. COLLECT WITH
ABSORBENT MATERIAL INTO SUITABLE CLOSED CONTAINER. TRANSPORT TO
OUTSIDE LOCATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CAUTION! COMBUST LIQ. STORE IN CLSD
OXIDANTS, HEAT & SOURCES OF IGNIT.
Other Precautions:AVOID STORING LONGER THAN 1 YEAR. AVOID SKIN CONTACT.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT SOLUBLE.
Appearance and Odor:RED/AMBER VISCOUS SOLUTION WITH SLIGHTLY SWEET
ODOR.
Percent Volatiles by Volume:SUPDAT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDANTS
Stability Condition to Avoid:HEAT, SPARKS, FLAME
Hazardous Decomposition Products:DETAILS UNKNOWN. MAY EMIT TOXIC FUMES
IF BURNED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL,
STATE, AND LOCAL REGULATIONS. CONTACT SHIPLEY TECHNICAL SERVICE
REPRESENTATIVE IF FURTHER ASSISTANCE IS NEEDED.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPRVD RESPIRATOR IF REQUIRED
Ventilation:LOCAL EXHAUST TO KEEP BELOW TLV=
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM HYDROXIDE (SARA III)
Fraction by Wt: 5%
OSHA PEL:2 MG/M3
Ingred Name:SODIUM BICHROMATE (SARA III)
OSHA PEL:0.1 PPM CRO3;CEILING
Ingred Name:PENTACHLOROPHENOL (SARA III)
Fraction by Wt: 5%
OSHA PEL:S, 0.5 MG/M3
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
Fraction by Wt: 5%
* Hazards Identification *
Effects of Overexposure:HIGHLY CORROSIVE TO SKIN AND MUCOUS MEMBRANES.
INGEST:VERY TOXIC.
* First Aid Measures *
First Aid:SKIN:WASH W/ SOAP AND WATER. INGEST:TREAT FOR CHROMIUM
IMMED.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:NON-FLAMMABLE
* Accidental Release Measures *
CONTACT WITH SKIN AND CLOTHING. MOP UP AND DISPOSE WITH SOLVENT
RECLAIMER.
*Handling and Storage *
Handling and Storage Precautions:KEEP FROM FREEZING
Other Precautions:AVOID CONTACT W SKIN & EYES.
* Physical/Chemical Properties *
Vapor Density:0.7
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR YELLOW MEDIUM VISCOUS LIQ,ISOPROPANOL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:MFR RECOMMENDS DISPOSING OF WITH SOLVENT
RECLAIMER. DISPOSAL METHOD MUST BE IAW FEDERAL, STATE AND LOCAL
REGULATIONS.
| 1 | gloves_mandatory |
Control Measures
*
Cage: 0K0U5
*
Contractor Summary
*
Cage: 0K0U5
*
Item Description Information
*
Item Name: ADHESIVE,DENTAL,SPE
*
Ingredients
*
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT RELEVANT
ACGIH TLV: NOT RELEVANT
------------------------------
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TARGET ORGANS:EYE, SKIN, RESPIRATORY AND GASTROINTESTINAL
TRACTS. ACUTE- INHALATION:MAY CAUSE UPPER RESPIRATORY TRACT IRRITATION.
EYE:MAY CAUSE SEVERE IRRITATION. SKIN:MAY CAUSE ALLERGIC REACTION. ING
ESTION:IRRITATION OF GASTROINTESTINAL TISSUES. CHRONIC-NONE SPECIFIED BY
MANUFACTURER.
Explanation Of Carcinogenicity: NONE SPECIFIED BY MANUFACTURER.
Signs And Symptions Of Overexposure: EYES-REDNESS, SWELLING, PAIN, TEARING,
CLOUDY, APPEARANCE OF THE CORNEA, IMPAIRED VISION AND POSSIBLY PERMANENTLY
IMPAIRED VISION. SKIN-REDNESS, SWELLING, BLISTERING, ITCHING.
INHALED-SORENESS OF NOSE AND THROAT, COUGHING, SNEEZING. SWALLOWED-PAIN,
ABDOMINAL TENDERNESS, NAUSEA, BLOOD IN VOMITUS, BLOOD IN
FECES,BLEEDING/REDNESS/SWELLING/PAIN OF THE GUMS. A SMALL PERCENTAGE OF THE
POPULATION IS KNOW N TO HAVE AN ALLERGIC RESPONSE TO ACRYLATE RESINS LIKE
2-HYDROXYETHYLMETHACRYLATE.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
GET IMMEDIATE MEDICAL ATTENTION. SKIN-FLUSH WITH LOTS OF WATER. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION. INHALED-REMOVE PERSON TO FRESH AIR. IF
SIGNS/SYMPTOMS OCCUR, CALL A PHYSICIAN. SWALLOWED-DRINK TWO GLASSES OF WATER.
CALL A PHYSICIAN.
*
Handling and Disposal
*
Spill Release Procedures: OBSERVE PRECAUTIONS FROM OTHER SECTIONS. VENTILATE
AREA. COVER WITH ABSORBENT MATERIAL. PLACE IN A METAL CONTAINER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF ACCORDING TO THE POLICIES/PROCEDURES
CONTAINED IN THE 3M WASTE MANAGEMENT PROGRAM MANUAL AND THE INSTRUCTIONS
PROVIDED ON THE WASTE STREAM PROFILE REFERENCE SHEET. CONSULT YOUR WASTE
MANAG EMENT (RCRA) COORDINATOR WITH ANY QUESTIONS. DISPOSE OF COMPLETELY
CURED MATERIAL IN A SANITARY LAND FILL.
Handling And Storage Precautions: STORE IN COOL PLACE. DO NOT INGEST. KEEP
CONTAINER TIGHTLY CLOSED.
RECOMMENDED.
*
Fire and Explosion Hazard Information
*
*
*
Respiratory Protection: AVOID PROLONGED BREATHING OF VAPORS.
Ventilation: USE WITH ADEQUATE VENTILATION.
THIS MATERIAL.
Other Protective Equipment: PROVIDE EYE WASH & SAFETY SHOWER (DLA- FP). LATEX
Work Hygienic Practices: OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
*
Physical/Chemical Properties
*
HCC: C3
PH: 2.9- 4
Appearance and Odor: CLEAR, SLIGHT YELLOW LIQUID - SLIGHT ACRYLATE ODOR
Corrosion Rate: UNKNOWN
*
Reactivity Data
*
Stability Indicator: YES
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
Sara Title III Information: EPCRA HAZARD CLASS: FIRE-NO; PRESSURE-NO;
REACTIVITY-NO; ACUTE-YES; CHRONIC-NO.
& EXEMPT SOLVENTS: N/A. US EPA HAZARDOUS WASTE NUMBER: NONE (NOT US EPA
HAZARDOUS).
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Cage: 0K0U5
Company Name: MINNESOTA MINING AND MFG CO DENTAL PRODUCTS DIV
Street: 3M CENTER
Label Required IND: Y
Status Code: A
Origination Code: F
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: SKIN, EYES, RESPIRATORY TRACT. OBSERVE
PRECAUTIONS FROM OTHER SECTIONS. VENTILATE AREA. COVER WITH ABSORBENT
MATERIAL. PLACE IN A METAL CONTAINER. FIARST AID: EYES: IMMEDIATELY FLUSH WI
SKIN-FLUSH WITH LOTS OF WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INHALED-REMOVE PERSON TO FRESH AIR. IF SIGNS/SYM PTOMS OCCUR, CALL A
PHYSICIAN. SWALLOWED-DRINK TWO GLASSES OF WATER. CALL A PHYSICIAN.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED WITH ADEQUATE
VENTILATION. NIOSH/MSHA RESPIRATOR WITH ORGANIC VAPOR CARTRIDGE
APPROPIATE FOR EXPOSURE OF CONCERN OR SCBA IF TLV IS EXCEEDED.
Ventilation:SUFFICIENT MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST
VENTILATION IN CONFINED SPACES. USE EXPLOSION-PROOF EQUIPMENT.
Other Protective Equipment:FULL BODY LONG-SLEEVED GARMENTS TO PREVENT
REPEATED OR PROLONGED SKIN CONTACT. EYE WASH STATION AND SAFETY
SHOWER.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN. DO NOT
BREATHE VAPORS. WASH THOROUGHLY AFTER HANDLING. LAUNDER
CONTAMINATED CLOTHING.
Supplemental Safety and Health
THESE PRECAUTIONS ARE FOR NORMAL USES AND CONDITIONS. WHERE SPECIAL OR
UNUSUAL CONDITIONS EXIST, CONSULT AN INDUSTRIAL HYGIENIST.
* Product Identification *
Product ID:DIESEL FUELS
Preparer's Name:ENV. HEALTH&SAFETY DEPT.
* Composition/Information on Ingredients *
Ingred Name:PETROLEUM OIL (NO. 2 DIESEL)
Fraction by Wt: MAJOR
Other REC Limits:NONE RECOMMENDED
Ingred Name:POLYCYCLIC AROMATIC HYDROCARBONS
Fraction by Wt: TRACE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:SLIGHT IRRITANT.DERMALLY
NON-TOXIC.INHAL:IRRITANT.INGEST:SLIGHTLY TOXIC.ASPIRATION
HAZARD.SLIGHTLY TOXIC.EYES:EXPECTED TO BE
NON-IRRITATING.CHRONIC:TRACE POLYCYCLIC AROMATIC HYDROCARBONS ARE
SUSP ECTED CARCINOGENS.
FUEL AS A TUMORIGEN.MANUFACTURER LINKS DIESEL FUEL TO LUNG CANCER.
Effects of Overexposure:INHAL:DIZZINESS,NAUSEA,UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:MATERIEL MAY CONTAIN TRACES OF
POLYCYCLIC AROMATIC HYDROCARBONS[PCAH].WITH POOR HYGIENE AND
PROLONGED EXPOSURE,SKIN CANCER MAY DEVELOP.
* First Aid Measures *
SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH SOAP AND
WATER.SEE DOCTOR. INHALATION: REMOVE VICTIM TO FRESH AIR.GIVE
OXYGEN/CPR IF NEEDED.SEE DOCTOR. INGESTION: DO NOT INDUCE
VOMITING.ADMINISTER VEGETABLE OIL.GET PROMPT QUALIFIED MEDICAL
HELP.CAUTION:LUNG DAMAGE CAN RESULT FROM VOMITING.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL. HMIS
SUGGESTS DO NOT USE WATER STREAM. IT MAY CAUSE FROTHING.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTIBLE MATERIEL.VAPORS HEAVIER THAN
AIR. MAY TRAVEL ALONG GROUND AND FLASHBACK. CONTAINERS EXPOSED TO
FIRE MAY IGNITE EXPLOSIVELY.
* Accidental Release Measures *
Spill Release Procedures:ADSORB ON FIRE RESISTANT TREATED SAWDUSTOR
DIATOMACEOUS EARTH.SHOVEL INTO A CONTAINER FOR DISPOSAL.NOTIFY
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
PLACE,AWAY FROM HEAT,IGNITION SOURCES AND INCOMPATIBLE
MATERIALS.KEEP CONTAINERS CLOSED WHEN NOT IN USE.
Other Precautions:AVOID BREATHING VAPORS, AND EYE AND SKIN CONTACT. USE
ONLY WITH ADEQUATE VENTILATION. DO NOT SIPHON BY MOUTH. BOND AND
GROUND CONTAINERS DURING TRANSFER.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:0.5
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID;CLEAR TO AMBER;CHARACTERISTIC HYDROCARBON
ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HALOGENS,STRONG ACIDS,ALKALIES,STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION(EG.STATIC ELECTRICITY BUILDUP).
Hazardous Decomposition Products:DIESEL ENGINE EXHAUST:CO,NITROGEN
COMPOUNDS,OXIDES OF SULFUR,HYDROCARBONS(GASES AND PARTICULATES).
* Disposal Considerations *
Waste Disposal Methods:MATERIEL IS SUITABLE FOR BURNIG FOR FUEL VALUE
IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATORY PROTECTION EQUIP
APPROP TO MATL OR COMPONENTS WHERE AIRBORNE EXPOSURE IS LIKELY.
OBSERVE RESPIRATOR USE LIMITATIONS SPECIFIED BY NIOSH OR MFG.
EMERGENCY & OTHER CONDITIO NS FOR EXPOSURE, USE APPROVED FULL FACE
POSITIVE-PRESSURE, SELFCONTAINED BREATHING APPARATUS OR
POSITIVE-PRESSURE AIRLINE W/AUXILIARY SELFCONTAINED AIR SUPPLY.
Ventilation:IF PRACTICAL, LOCAL MECHANICAL EXHAUST VENTILATION AT
SOURCES OF AIR CONTAMINATION. CONSULT ACGIH VENTILATION MANUAL OR
MATERIAL.
IMMEDIATELY AVAILABLE.
Other Protective Equipment:INVESTIGATE ENGINEERING TECHNIQUES TO REDUCE
EXPOSURES. PROVIDE VENTILATION NECESSARY TO MINIMIZE EXPOSURES.
Work Hygienic Practices:RINSE IMMEDIATELY IF SKIN IS CONTAMINATED. WASH
CONTAMINATED CLOTHING & CLEAN PROTECTIVE EQUIPMENT BEFORE REUSE.
PROVIDE A SAFETY SHOWER WHERE SKIN CONTACT CAN OCCUR. WASH SKIN
THOROUGH AFTER HANDLING.
Supplemental Safety and Health
DO NOT BREATH DUST. IF EXPOSURES CANNOT BE KEPT AT A MINIMUM WITH
ENGINEERING CONTROLS, CONSULT RESPIRATOR MANUFACTURER TO DETERMINE
APPROPRIATE TYPE EQUIPMENT FOR A GIVEN APPLICATION. RESPIRATORY PRO
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM HYDROXIDE
ACGIH STEL:C2 MG/M3
Ingred Name:POTASSIUM PERMANGANATE
OSHA PEL:C5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:SODIUM FLUORIDE
Minumum % Wt:5.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IT IS ANTICIPATED TO BE MODERATELY
TOXIC IF SWALLOWED, NO MORE THAN SLIGHTLY TOXIC IF ABSORBED THROUGH
SKIN AND CORROSIVE TO EYES AND SKIN. INHALATION OF DUST MAY CAUSE
EYE AND UPPER RESPOIRATORY TRAC T IRRITATION AND IN SEVERE CASES,
DELAYED PULMONARY EDEMA AND DEATH. LONG TERM EXPOSURE MAY CAUSE
WEIGHT LOSS, MUSCLE PAIN, LIVER DAMAGE AND BRAIN DAMAGE.
Explanation of Carcinogenicity:NONE LISTED.
Effects of Overexposure:SYMPTOMS INCLUDES SLEEPING DIFFICULTIES,
DECREASED SEX DRIVE AND HEADACHES PROGRESSING TO DECRASED ABILITY
TO PERFORM SKILLED MOVEMENTS, SPEAKING DIFFICULTIES, EMOTIONAL
OUTBREAKS, IRRITABILITY, HALLU CINATIONS AND PARKINSONIAN-LIKE
TREMORS AND FACIAL TICS. REPEATED OR PROLONGED EXPOSURE MAY GREATLY
INCREASE THE SUSCEPTABILITY OF AN INDIVIDUAL TO LUNG INFECTIONS,
KIDNEY DAMAGE AND BONE EFFECTS INCL UDING JOINT PAIN, TOOTH EROSION
AND DISCOLORATION.
Medical Cond Aggravated by Exposure:MEDICAL CONDITIONS AGGRAVATED BY
EXPOSURE TO THIS MATERIAL INCLUDE KIDNEY DISEASE AND LUNG DISEASE.
* First Aid Measures *
First Aid:EYE: SPEED IS ESSENTIAL. IMMEDIATELY FLUSH WITH PLENTY OF
WITH PLENTY OF WATER. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH
CLOTHING B EFORE REUSE. DESTROY CONTAMINATED SHOES. INGEST: DO NOT
INDUCE VOMITING. GIVE WATER TO DRINK. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. INHALE: REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. GET MEDICAL HELP.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING
FIRE CONDITIONS.
Fire Fighting Procedures:FIRE FIGHTERS AND OTHERS WHO MAY BE EXPOSED TO
PRODUCTS OF COMBUSTION SHOULD WEAR FULL FIRE FIGHTING TURN OUT
GEAR(FULL BUNKER GEAR) & SELF-CONTAINED BREATHING
APPARATUS(PRESSURE DEMAND NIOSH APPROVED OR EQUIVALENT). FIRE
FIGHTING EQUIPMENT SHOULD BE THOROUGHLY DECONTAMINATED AFTER USE.
Unusual Fire/Explosion Hazard:CONTACT WITH METAL CAN FORM HYDROGEN GAS.
HYDROGEN IS EXTREMELY FLAMMABLE AND CAN FORM EXPLOSIVE MIXTURES
WITH AIR. OXIDIZING MATERIAL. FORMS EXPLOSIVE MIXTURES WITH
COMBUSTIBLE, ORGANIC OR OTHER EASI LY OXIDIZABLE MATERIALS. THESE
MIXTURES ARE EASILY IGNITED BY FRICTION OR HEAT.
* Accidental Release Measures *
Spill Release Procedures:SHOVEL DRY SPILL INTO DOT-APPROVED DRUMS FOR
DISPOSAL. KEEP SPILL DRY UNTIL AS POSSIBLE HAS BEEN SWEPT UP AND
SHOVELED INTO DISPOSAL DRUMS. DISSOLVE RESIDUAL AMOUNTS IN WATER
AND COLLECT SOLUTION IN D OT-APPROVED DRUMS FOR DISPOSAL.DO NOT
ALLOW PRODUCT OR RINSE WATER FROM SPILL TO ENTER SEWER OR WATERWAY.
Neutralizing Agent:N/P.
*Handling and Storage *
Handling and Storage Precautions:DO NOT BREATHE DUST. DO NOT GET IN
EYES, ON SKIN OR CLOTHING. WASH THOROUGHLY AFTER HANDLING. DO NOT
ENTER CONFINED SPACES UNLESS ADEQUATELY VENTILATED. TO AVOID RAPID
TEMPERATURE RISE, VIOLENT SPATTE RING, OR EXPLOSIVE ERUPTIONS,
ALWAYS ADD CAUSTIC TO WATER WHEN MIXING. NEVER ADD WATER TO A
CAUSTIC.
Other Precautions:STORE IN A COOL, DRY PLACE. AVOID EXCESSIVE HEAT.
STORE OUT OF DIRECT SUNLIGHT IN A COOL, WELL-VENTILATED PLACE.
* Physical/Chemical Properties *
HCC:B1
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE & VIOLET GRANULAR MIX; LITTLE OR NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG ACIDS, REACTIVE METALS, ORGANIC MATERIALS.
PERMANGANATES MAY DECOMPOSE VIOLENTLY WHEN EXPOSED TO HIGH HEAT. IF
CONFINED, THIS DECOMPOSITION MAY BECOME EXPLOSIVE.
Stability Condition to Avoid:THIS MATERIAL IS CHEMICALLY STABLE UNDER
SPECIFIED CONDITIONS OR STORAGE, SHIPMENT AND/OR USE.
Hazardous Decomposition Products:NONE KNOWN.
* Toxicological Information*
MG/KG, AND CORROSIVE TO RABBIT SKIN. SOLUTIONS OF THIS MATERIAL ARE
HIGHLY ALKALINE AND ARE ABLE TO RAPIDLY DISSOLVE AND DESTROY UPON
THAN SLIGHTLY TOXIC TO RATS IF A BSORBED THROUGH SKIN.
* Ecological Information *
PRATICALLY NON-TOXIC TO ASIATIC CLAM AND PINK SHRIMP, AND
MODERATELY TO H IGHLY TOXIC TO SEVERAL FRESHWASTER VERTEBRATES.
* Disposal Considerations *
Waste Disposal Methods:CONSULT A REGULATORY SPECIALIST TO DETERMINE
APPROPIRATE STATE OR LOAL REPORTING REQUIREMENTS, FOR ASSISTANCE
WITH WASTE CHARACTERIZATION AND/OR HAZARDOUS WASTE DISPOSAL AND
OTHER REQUIREMENTS LISTED IN PERTINENT ENVIRONMENTAL PERMITS.
* MSDS Transport Information *
Transport Information:DOT: OXIDIZING SOLID, CORROSIVE, N.O.S. HAZARD
* Regulatory Information *
SARA Title III Information:CERCLA REPORTABLE QUANTIITIES: POTASSIUM
State Regulatory Information:THIS PRODUCT CONTAINS THE CHEMICALS ON THE
FOLLOWING STATES' RIGHT TO KNOW: MASSACHUSETETS, NEW JERSEY,
PENNSYLVANIA.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN.
Ventilation:NONE.
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:RAY D. LAWSON
* Composition/Information on Ingredients *
Ingred Name:PETROLEUM HYDROCARBONS. OTHER RECOM LIM: 5MG/M3 TWA/PEL
(MINERAL OIL MIST) (MFR)
Other REC Limits:SEE INGRED NAME
Ingred Name:ADDITIVES
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: NO DATA AVAILABLE. CHRONIC:
NONE WHEN USED WITH GOOD PERSONAL HYGIENE PRACTICES. MAY OTHERWISE
CAUSE SKIN AND EYE IRRITATION UPON PROLONGED OR REPEATED CONTACT.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:EYES: IMMED FLUSH WITH LARGE QUANTITIES OF WATER FOR AT LEAST
THOROUGHLY WITH SOAP AND WATER. INHAL: REMOVE EXPOSED PERSON TO
FRESH AIR IF DISCOMFORT IS EXPERIENCED WHILE HANDLING HOT PRODUCT.
INGEST: CONTACT PHYS IMMED.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:DRY CHEMICAL, WATER FOG OR SAND/EARTH. CLOSED
CONTAINERS EXPOSED TO FIRE MAY BE COOLED WITH WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DENSE SMOKE.
* Accidental Release Measures *
Spill Release Procedures:TRANSFER BULK OF MIXTURE INTO ANOTHER
CONTAINER. ABSORB RESIDUE WITH AN INERT MATERIAL SUCH AS EARTH,
SAND, OR VERMICULITE. SWEEP UP AND DISPOSE AS SOLID WASTE IN
ACCORDANCE WTH LOCAL, STATE, AND FEDE RAL REGULATIONS.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED UNTIL READY FOR
USE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
HCC:V6
Appearance and Odor:OILY AMBER LIQUID WITH MINERAL OIL ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS SUCH AS HYDROGEN PEROXIDE, BROMINE, AND CHROMIC ACID.
Stability Condition to Avoid:
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE
FROM BURNING. OXIDES OF NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE HIGH EFFICIENCY PARTICLE MASKS OR DUST
RESPIRATORS THAT HAVE NIOSH/MSHA APPROVALS.
Ventilation:LOCAL EXHAUST SHOULD BE USED, IF NECESSARY, TO CONTROL
AIRBORNE DUST LEVELS BELOW RECOMMENDED TLV'S.
Other Protective Equipment:DISPOSABLE COVERALLS MAY BE CONSIDERED TO
PROTECT EXPOSED SKIN AND CLOTHING. EMERGENCY EYEWASH & DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
CARCINOGEN. EFTS OF OVEREXP:ESOPHAGUS & DIGESTIVE TRACT.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA)
OSHA PEL:0.1 MG/M3 RDUST
ACGIH TLV:0.1 MG/M3 RDUST
Ingred Name:PORTLAND CEMENT
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES:DUST CAN IRRIT, DIRECT CNTCT
(WET/DRY) CAN CAUSE SERIOUS BURNS. RPTD EXPOS TO DUST MAY CAUSE
INFLAMM OF CORNEAS. SKIN:ALKALI CONTENT CAN DRY SKIN & CAUSE
CRACKING. RPTD/PRLNG EXPOS MAY RSLT IN BU RNS &/OR DERM.
HYPERSENSITIVE INDIVIDUALS MAY BE EXTREMELY SUSCEPTIBLE. INHAL:DUST
CAN CAUSE IRRIT/ (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
ANNUAL REPORT ON (SUPDAT)
Effects of Overexposure:HLTH HAZ:INFLAMM OF UPPER RESP SYS. RPTD/ PRLNG
EXPOS TO DUST CONTAINING FREE SLILICA MAY RSLT IN SCARRING OF LUNGS
W/COUGH & SHORTNESS OF BRTH. DELAYED LUNG INJURY, SILICOSIS, COULD
RSLT FROM RPTD BR THG OF FREE SICLICA DUST PARTICLES. INGEST:ALKALI
PROPERTIES OF PROD COULD RSLT IN SERIOUS BURNS TO MOUTH, (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
PROMPT MED ATTN. SKIN:WASH W/MILD SOAP & WATER. IF IRRIT (CRACKING,
REDNESS) PERSISTS, SEEK MED ATTN. INHAL:REMOVE TO FRESH AIR. IF
IRRIT/I NFLAMM OF UPPER RESP SYS DEVELOPS/PERSISTS, SEEK PROMPT MED
ATTN. INGEST:DILUTE BY DRINKING SEVERAL GLASSES WATER. DO NOT
INDUCE VOMIT. PROD IS SLIGHTLY ALKALI & CAN CAUSE BURNS. SEEK IMMED
MED ATTN.
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NOT A
FLAMMABLE HAZARD.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:KEEP DUST LEVELS TO A MINIMUM. IF AIRBORNE
DUST DEVELOPS, TAKE APPROPRIATE STEPS FOR RESPIRATORY PROTECTION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP DRY UNTIL USED. KEEP CONTAINERS
CLOSED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:T6
Spec Gravity:2.9-3.2
Solubility in Water:SLIGHT
Appearance and Odor:DRY GREY POWDER; CHARACTERISTIC CEMENT ODOR.
Percent Volatiles by Volume:<1
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE.
* Disposal Considerations *
Waste Disposal Methods:SWEEP OR VACUUM MATERIAL. DISPOSE AS SOLID WASTE
IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SELECT A NIOSH APPROVED RESPIRATOR BASED ON
AIRBORNE CONCENTRATION OF CONTAMINANTS AND IN ACCORDANCE W/OSHA:
HALF-MASK ORGANIC VAPOR RESPIRATOR, FULL-FACE ORGANIC VAPOR
RESPIRATOR.
Ventilation:LOCAL EXHAUST AT TRANSFER POINTS. PROVIDE SUFFICIENT
VENTILATION TO MAINTAIN EMISSIONS BELOW EXPOSURE LIMITS.
Work Hygienic Practices:DONT EAT OR SMOKE WHEN USING THIS PRODUCT. WASH
EXPOSED AREAS THOROUGHLY W/SOAP AND WATER.
Supplemental Safety and Health
NK
* Product Identification *
CAGE:0F0U5
CAGE:0F0U5
* Composition/Information on Ingredients *
Ingred Name:GLASS BEADS
Ingred Name:STODDARD SOLVENT
Other REC Limits:NONE RECOMMENDED
Ingred Name:TITANIUM DIOXIDE
Other REC Limits:NONE RECOMMENDED
Ingred Name:MODIFIED ALKYD RESIN
Other REC Limits:NONE RECOMMENDED
Ingred Name:SILICA
Other REC Limits:NONE RECOMMENDED
Ingred Name:MEDIUM ALIPHATIC SOLVENT NAPHTHA
Fraction by Wt: 3-7%
Ingred Name:SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC
Fraction by Wt: 1-5%
Ingred Name:LEAD NAPHTHENATE
Other REC Limits:NONE RECOMMENDED
Ingred Name:LEAD 2-ETHYLHEXANOATE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE: IRRIT, RED, SWELL, PAIN, TEAR.
SKIN: IRRIT, RED, SWELL, ITCH. INHAL: CNS DEPRESS, HEADACHE, DIZZY,
DROWSY, INCOORDINATION, SLOW REACT TIME, SLURRED SPEECH, GIDDY,
UNCONSCIOUS, RESP IRRIT, SORE NO SE/THROAT, COUGH, SNEEZE. INGEST:
GI TISUE IRRIT, PAIN, VOMIT, TENDER ABDOMEN, NAUSEA, BLOOD IN
VOMIT/FECES, CNS DEPRES*
Explanation of Carcinogenicity:CONTAINS A CHEMICAL WHICH CAN CAUSE
CANCER (LEAD COMPOUNDS).
Effects of Overexposure:* HEADACHE, DIZZY, DROWSY, MUSCULAR WEAKNESS,
INCORDINATION, SLOW REACT TIME, FATIGUE, BLURRED VISION, SLURRED
SPEECH, GIDDY, TREMORS AND CONVULTIONS.
* First Aid Measures *
First Aid:EYE: FLUSH W/WATER. SKIN: FLUSH W/WATER. INHAL: GET FRESH
AIR. INGEST: CALL DR. IN ALL CASES, GET MED AID.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:NO DATA
Upper Limits:NO DATA
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE FULL PROTECTIVE CLOTHES, W/HELMET, SCBA
(POSITIVE PRESSURE), BUER COAT AND PANTS, BANDS AROUND ARMS,
WAIST AND LEGS, FACE MASK, PROTECTIVE COVER FOR HEAD.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL TO IGNITS AND FLASH BACK.
* Accidental Release Measures *
ASSISTANCE. VENTILATE AREA. EXTINGUISH IGNITS. CONTAIN SPILL. COVER
W/INORGANIC ABSORBENT MATERIAL. COLLECT SPILLED MATERIAL. CLEAN UP
RESIDUE. PLACE IN U .S. DOT APPROVED CONTAINER AND SEAL.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM HEAT. KEEP CONTAINER
CLOSED WHEN NOT IN USE. KEEP IN A WELL VENTILATED AREA.
Other Precautions:FLAMMABLE LIQUID/VAPOR. KEEP AWAY FROM IGNITS. GROUND
CONTAINERS SECURELY WHEN TRANSFERRING CONTENTS. WEAR LOW STATIC OR
PROPERLY GROUNDED SHOES. VAPORS MAY IGNITE EXPLOSIVELY. AVOID
STATIC DISCHARGE.
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:NO DATA
Vapor Density:>1.0 AIR=1
pH:NA
Viscosity:THIXOTROPIC
Evaporation Rate & Reference:NO DATA
Solubility in Water:NIL
Appearance and Odor:THIXOTROPIC-LIQUID/GEL, WHITE, SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE AND
HYDROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE PRODUCT IN A HAZARDOUS WASTE
FACILITY. RECLAIM IF FEASIBLE IN ACCORDANCE W/FEDERAL, STATE &
(LEAD).
* Other Information *
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR APPROPRIATE NIOSH APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
OTHER PROTECTIVE CLOTHNG.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CRYSTAL VIOLET
Ingred Name:4,4'-BIS(DIMETHYLAMINO)BENZOPHENONE (MICHLER'S KETONE)
= Wt:.2
Ingred Name:ZINC; (ZINC COMPOUNDS)
= Wt:1.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF INHALED OR
SWALLOWED. CAUSES SEVERE EYE IRRITATION. CAUSE SKIN IRRITATION.
MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER RESPIRATORY
TRACT. PROLONGED EXPOSURE CAN CAUSE: NAUSE A, HEADACHE AND
VOMITING. CHRONIC: CARCINOGEN. MAY ALTER GENETIC MATERIAL.
Explanation of Carcinogenicity:MICHLERS KETONE: NTP 8TH ANNUAL REPORT
CARCINOGEN.
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
First Aid:IN CASE OF CONTACT, IMMED FLUSH EYES OR SKIN WITH COPIOUS
CLOTHING & SHOES. ASSURE ADEQUATE FLUSHING OF EYES BY SEPARATING
THE EYELIDS W ITH FINGERS. IF INHALED, REMOVE TO FRESH AIR. IF NOT
BREATHING GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED
PERSON IS CONSCIOUS . CALL A PHYSICIAN. WASH CONTAMINATED CLOTHING
BEFORE REUSE.
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER. WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN AND
EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH APPRVD SCBA, RUBBER
DISCARD THEM AFTER USE. SWEEP UP, PLACE IN A BAG AND HOLD FOR WASTE
DISPOSAL. AVOID RAISING D UST. VENTILATE ARA AND WASH SPILL SITE
AFTER MATERIAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:TOXIC. MAY CAUSE CANCER. MAY CAUSE
HERITABLE GENETIC DMG. TOXIC BY INHAL & IF SWALLOWED. IRRITATING TO
RESP SYS & SKIN. RISK OF SERIOUS DMG TO EYES. WEAR SUITABLE
BREATHE DUST.
Other Precautions:DO NOT BREATHE DUST. DO NOT GET IN EYES, ON SKIN, ON
CLTHG. AVOID PROLONGED OR REPEATED EXPOSURE. WASH THOROUGHLY AFTER
HANDLING. IRRITANT. CARCINOGEN. MUTAGEN. KEEP TIGHTLY CLOSED.
PROTECT FROM LIGHT . STORE IN A COOL DRY PLACE..
THORAX/RESP (ACUTE PULM EDEMA). GASTROINTESTINAL (HYPERMOTILITY,
DIARRHEA), (NAUS/VOMIT). EFTS ON FERTILITY: (POST-IMPLANTATION MO
RTALITY). EFTS ON EMBRYO OR FETUS (FETOTOXICITY). SPECIFIC
DEVELOPMENTAL ABNORMALITES (MUSCULOSKELETAL SYS),(ECOL INFO)
* Physical/Chemical Properties *
Appearance and Odor:GREEN TO OLIVE GREEN POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, SENSITIVE TO LIGHT.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
NITROGEN OXIDES, HYDROGEN CHLORIDE GAS.
* Toxicological Information*
(4-(BIS(P-DIMETHYLAMINO)PHENYL)METHYLENE)-2,5-CYCLOHEXADIEN-1-YLIDE
INTAKE), (ATAXIA). (SUPDAT)
* Ecological Information *
Ecological:DATA NOT YET AVAILABLE. --SUPDAT: (UROGENITAL SYS), (OTHER
DEVELOPMENTAL ABNORMS). NUTRITIONAL & GROSS METABOLIC (WT
LOSS/DECREASED WT GAIN). ONLY SELECTED REGISTRY OF TOXIC EFFECTS OF
CHEMICAL SUBSTA NCES (RTECS) DATA IS PRESENTED HERE. SEE ACTUAL
ENTRY IN RTECS FOR COMPLETE INFO.
* Disposal Considerations *
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULAT IONS.
* MSDS Transport Information *
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
* Regulatory Information *
SARA Title III Information:US INFORMATION: 1.0% ZINC COMPOUNDS. 0.2%
REQUIREMENTS.
CASE OF CONT W/EYES, RINSE IMMED W/PLENTY OF WATER & SEEK MED
State Regulatory Information:N/P --FED REGS: REVIEWS, STDS & REGS:
MELANOGASTER SEX-LINKED LETHAL. EPA TSCA SECTION 8(B) CHEM
INVENTORY. EP A TSCA TEST SUBMISSION (TSCATS) DATA BASE, DECEMBER
* Other Information *
| 1 | gloves_mandatory |
Control Measures
*
Product ID: SAIL PINK LIQUID DISHWASH
Cage: CXAST
Proprietary Ind: Y
*
Contractor Summary
*
Cage: CXAST
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: MAY CAUSE EYE IRRITATION. MAY BE HARMFUL IF
SWALLOWED. CHRONIC: NONE LISTED BY MANUFACTURER.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE.
First Aid: INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP)
PERSISTS GET MEDICAL AID. SKIN: FLUSH THOROUGHLY WITH WATER. ING EST: DO NOT
INDUCE VOMIT. GIVE LARGE QUANTITIES OF WATER. GET MEDICAL ADVICE.
*
Handling and Disposal
*
Spill Release Procedures: RECONTAINERIZE BY MOPPING, WET VACUUM OR USING A
SUITABLE ABSORBENT. RINSE REMAINING MATERIAL TO DRAINS. BE CAUTIOUS OF
SLIPPERY FLOORS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: FOLLOW LOCAL, STATE, AND FEDERAL REGULATIONS.
Other Precautions: KEEP OUT OF REACH OF CHILDREN. FOR SALE TO, USE AND STORAGE
BY SERVICE PERSONNEL ONLY.
*
Fire and Explosion Hazard Information
*
Flash Point Method: TOC
Flash Point Text: NONE TO BOILING
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE.
*
*
Respiratory Protection: NOT REQUIRED. NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: NOT REQUIRED.
Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
*
Physical/Chemical Properties
*
Vapor Pres: TO WATER
Vapor Density: TO WATER
PH: 8.5
Evaporation Rate & Reference: TO WATER
Solubility in Water: COMPLETE
Appearance and Odor: OPAQUE, VISCOUS, PINK LIQUID. FRUITY ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE.
Materials To Avoid: STRONG ACIDS AND OXIDIZERS.
Hazardous Decomposition Products: CARBON OXIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: SAIL PINK LIQUID DISHWASH
Cage: CXAST
Company Name: COASTAL PAPER & SAIL CO
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: MAY CAUSE EYE IRRITATION. MAY BE
HARMFUL IF SWALLOWED. CHRONIC: NONE LISTED BY MANUFACTURER.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHEN SPRAYING, APPLYING IN CONFINED AREAS, OR IN
OTHER CIRCUMSTANCES LIKELY TO PRODUCE AIRBORNE LEVELS OF SOLVENT IN
EXCESS OF PEL, USE AN ORGANIC VAPOR CARTRIDGE OR AIR-SUPPLIED
RESPIRATOR.
Ventilation:PROVIDE MECHANICAL VENTILATION TO KEEP <TLV.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TOLUENE (SARA III)
Fraction by Wt: <5%
Ingred Name:DISULFIRAM
Fraction by Wt: <5%
OSHA PEL:2 MG/M3
Ingred Name:ETHYL ALCOHOL (ETHANOL)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: IRRITATION & ALLERGIC RASH.
INHALATION: IRRITATION TO NOSE & THROAT, HEADACHE, FATIGUE,
CONFUSION, DIZZINESS, DROWSINESS, NUMBNESS & UNCONSCIOUSNESS.
INGESTION: NAUSEA, VOMITING, LIVER & KI DNEY DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN: IRRITATION & ALLERGIC RASH.
INHALATION: IRRITATION TO NOSE & THROAT, HEADACHE, FATIGUE,
CONFUSION, DIZZINESS, DROWSINESS, NUMBNESS & UNCONSCIOUSNESS.
INGESTION: NAUSEA, VOMITING, LIVER & KI DNEY DAMAGE.
Medical Cond Aggravated by Exposure:ALLERGIC SKIN RASH.
* First Aid Measures *
WASH W/SOAP & WATER. CONSULT PHYSICIAN. INHALATION: REMOVE TO FRESH
AIR. CONSULT PHYSICIAN. INGESTION: CONSULT PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:3.4%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:USE COMPLETE PERSONAL PROTECTION. USE WATER TO
COOL HEAT-EXPOSED CONTAINERS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. WEAR AIR-SUPPLIED
RESPIRATOR FOR MAJOR UNVENTILATED SPILL. COVER W/ABSORBANT. SCOOP
INTO CONTAINERS. CLEAN-UP RESIDUE W/1,1,1 -TRICHLOROETHANE.
*Handling and Storage *
Handling and Storage Precautions:THIS PRODUCT CONTAINS A TOXIC CHEMICAL
OR CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS.
* Physical/Chemical Properties *
Vapor Density:1.7
Evaporation Rate & Reference:(TOLUENE): 2.9
Solubility in Water:SLIGHT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:IGNITION SOURCES
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
COMPLIANCE W/FEDERAL & STATE REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:DO NOT BRTH VAP, SPRAY MIST/SANDING DUST. WHEN
SPRAY APPLIED IN OUTDOOR/OPEN AREAS W/UNRESTRICTED VENT, & DURING
SANDING/GRINDING OPER, USE NIOSH/MSHA APPRVD MECH FILTER RESP TO
Ventilation:USE ONLY W/ADEQ VENT. PROVIDE GEN DILUTION/LOCAL EXHAUST
Other Protective Equipment:IMPERMEABLE CLOTHING & BOOTS TO PVNT CONTACT
ARE RECOM.
Work Hygienic Practices:REMOVE AND WASH SOILED CLOTHING BEFORE REUSE.
WASH HANDS BEFORE EATING, SMOKING OR USING WASHROOM.
Supplemental Safety and Health
FIRE FIGHT PROC: ARE PREFERABLE. IF EXPOSED TO FIRE/EXTREME HEAT, WATER
SHOULD BE USED TO COOL CLSD CONTRS & PVNT PRESS BUILD-UP/POS
AUTO-IGNIT. EXPLO HAZ: CUTTING TORCH ON/NEAR CONTR (EVEN EMPTY) AS
PROD/ITS RESIDUE MAY IGNITE. DURING EMER CONDITIONS, OVEREXPOS TO
DECOMP PROD MAY CAUSE HLTH HAZ. SYMP (SEE ING 8)
* Product Identification *
Product ID:WONDER WOOD SATIN INTERIOR VARNISH
* Composition/Information on Ingredients *
Ingred Name:OTHER PREC: CONTRS. KEEP OUT OF REACH OF CHILDREN. WARNING:
OTHER REPRODUCTIVE HARM.
Ingred Name:RESP PROT: & SANDING DUST. WHEN USED IN RESTRICTED AREAS,
DIRECTIONS FOR RESPIRATOR USE.
Ingred Name:VENT: BELOW CURRENT APPLIC SFTY & HLTH STANDARDS IN MIXING,
AND ALL IGNITION SOURCES SHOULD BE ELIMINATED.
Ingred Name:STODDARD SOLVENT
Ingred Name:TALL OIL ALKYD RESIN
Ingred Name:ALKYD RESIN
Ingred Name:METHYL ISOBUTYL KETONE (SARA III)
Ingred Name:CYCLOHEXANONE (SARA III)
Fraction by Wt: <5%
Ingred Name:SUPP DATA: MAY NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL
ATTENTION.
Ingred Name:FIRST AID PROC: CONSULT PHYS IMMEDIATELY. ASPIRATION OF
VOMITUS CAN CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL.
Ingred Name:SPILL PROC: TOOLS. STORE IN CLOSED CONTAINERS UNTIL
PROPERLY DISPOSED OF.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: IRRIT OF RESP TRACT;
HDCH, NAUSEA, DIZZ, WEAK & FATIGUE. EXTREME EXPOS CAN RSLT IN
UNCONSCIOUSNESS & EVEN RESP ARREST. SKIN/EYE CONTACT: PRIMARY
IRRIT. INGEST: CAN CAUSE STOMACH &/OR INT ESTINAL IRRIT, NAUSEA,
VOMIT & DIARRHEA. ASPIR OF VOMITUS CAN CAUSE CHEM PNEUMONITIS,
WHICH CAN BE (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: FATAL. CHRONIC: REPORTS HAVE
ASSOCIATED RPTD AND PROLONGED OCCUPATIONAL OVEREXPOS TO SOLV W/PERM
BRAIN AND NERVOUS SYS DAMAGE. PROLONGED AND REPEATED BREATHING OF
SPRAY MIST AND/OR SANDING D UST OVER PERIOD OF YEARS MAY CAUSE
DUSTDISEASE OF LUNGS.
Medical Cond Aggravated by Exposure:NONE WHEN USED IN ACCORDANCE WITH
SAFE HANDLING AND USE INFORMATION.
* First Aid Measures *
First Aid:INHAL: LEAVE AREA TO OBTAIN FRESH AIR. IF CONTINUED DFCLTY IS
EXPER, SUMMON MED ASSISTANCE IMMED. IF BRTHG CEASES, RESTORE USING
APPRVD CPR TECHNIQUES & SUMMON MED ASSISTANCE IMMED. EYE: FLUSH
WASH AREA THORO W/SOAP & H*2O. REMOVE SOILED CLTHG. GET MED
ASSISTANCE IF IRRIT PERSISTS. INGEST: DO NOT INDUCE VOMIT. (SEE
INGRED 9)
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:SEE INGRED
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM OR OTHER NATIONAL FIRE
PROTECTION ASSOCIATION APPROVED METHOD FOR TREATING CLASS B FIRE.
Fire Fighting Procedures:SUMMON PROFESSIONAL FIREFIGHTERS. USE
NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP . H*2O SPRAY MAY BE
INEFFECTIVE. IF WATER IS USED, FOG NOZ (SEE SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CONTR TIGHTLY CLSD. ISOLATE FROM
HEAT & FLAME. DUE TO PRESS BUILD-UP CLSD CONTRS EXPOSED TO EXTREME
HEAT MAY EXPLODE. NEVER USE WELDING/ (SEE SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION(HEAT,FLAME). DO
NOT SMOKE. AVOID BRTHG VAPS. BEFORE ATTEMPTING CLEAN-UP REFER TO
HAZ CAUTION INFORM IN OTHER SECTIONS THIS MSDS FORM. VENT AREA.
CONTAIN SPILLED MATL & R EMOVE W/INERT ABSORB &
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT AND FLAME. DO NOT
SMOKE. PVNT BUILD-UP OF VAPORS BY MAINTAINING CONTINUOUS FLOW OF
Other Precautions:DO NOT STORE NEAR FIRE/OPEN FLAME. STORE LRG QTYS IN
NOT IN USE. DO NOT TRANSFER CONTENTS TO BOTTLES OR OTHER UNLABELLED
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY CAUSE HAZ FUMES WHEN HEATED TO
DECOMP. FUMES MAY CONTAIN CO, CO*2 & OXIDES OF METALS LISTED IN
INGREDIENTS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. INCINERATE ONLY IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.
| 1 | gloves_mandatory |
Control Measures
*
Product ID: WET OR DRY TRI-M-ITE PRODUCTS
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: DUST FROM ABRADED SURFACE MAY CAUSE MECHANICAL IRRITATION.
SKIN CONTACT/INGEST:NO ADVERSE HEALTH EFFECTS EXPECTED. INHAL:OVEREXPOSURE TO
DUST FROM ABRADED SURFACE MAY CAUSE RESPIRATORY SYSTEM IRRITATI ON, HAZARD
DEGREE BASED ON MATERIAL BEING ABRADED.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST:CALL MD IMMEDIATELY (FP N). SKIN:FLUSH W/COPIOUS AMOUNTS OF
& CALL MD IF IRRITATION PERSISTS. INHAL:PROVIDE FRESH AIR - TREAT FOR
SUBSTRATE MATERIAL BEING ABRADED.
*
Handling and Disposal
*
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS (FP N). COLLECT MATERIAL & DISPOSE IN A LOCAL SANITARY
LANDFILL.
Handling And Storage Precautions: PREVENT EYE & SKIN CONTACT W/DUST CREATED
FROM GRINDING SUBSTRATE. AVOID BREATHING DUST FROM MATERIAL BEING GROUNDED.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: WATER, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE.
*
*
Respiratory Protection: WEAR NIOSH/MSHA APPROVED PARTICULATE FACE MASK WHERE
DUST IS GENERATED.
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
*
Physical/Chemical Properties
*
Appearance and Odor: SOLID ABRASIVE PRODUCT; NO ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NOT DETERMINED.
Hazardous Decomposition Products: THERMAL DEGRADATION WILL PRODUCE CO, CO*2 &
SMOKE PARTICULATES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: WET OR DRY TRI-M-ITE PRODUCTS
Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:DUST FROM ABRADED SURFACE MAY CAUSE MECHANICAL
IRRITATION. SKIN CONTACT/INGEST:NO ADVERSE HEALTH EFFECTS EXPECTED.
INHAL:OVEREXPOSURE TO DUST FROM ABRADED SURFACE MAY CAUSE RESPIRATORY SYSTEM
IR RITATION, HAZARD DEGREE BASED ON MATERIAL BEING ABRADED. CHRONIC:NONE
LISTED BY MANUFACTURER.
*
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED RESPIRATORY PROTECTION
EQUIPMENT. CONCENTRATION IN AIR DETERMINES PROTECTION REQUIRED.
Ventilation:PROVIDE LOCAL EXHAUST AND MECHANICAL(GENERAL) VENTILATION
TO MAINTAIN EXPOSURE BELOW RECOMMENDED EXPOSURE LIMITS.
Other Protective Equipment:WEAR INDUSTRIAL WORK CLOTHING. USE RUBBER
APRON OR BOOTS IF NEEDED. HAVE EMERGENCY EYE WASH AND SAFETY SHOWER
AVAILABLE.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:JET FUEL JP-5
* Composition/Information on Ingredients *
Ingred Name:KEROSENE
Other REC Limits:NONE SPECIFIED
Ingred Name:DIETHYLENE GLYCOL
Other REC Limits:NONE SPECIFIED
Ingred Name:MONOMETHYL ETHER
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MODERATELY IRRITATING. SKIN:
MODERATELY IRRITATING WITH PROLONGED OR REPEATED CONTACT.
INHALATION: IRRITATING TO MUCOUS MEMBRANES AND RESPIRATORY TRACT.
MAY CAUSE DIZZINESS, INCOORDINATION, LOSS OF BALANCE, HEADACHE,
UNCONSCIOUSNESS,RESPIRATORY FAILURE. INGESTION: PRACTICALLY
NON-TOXIC.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. INHALATION:
MUCOUS MEMBRANE AND RESPIRATORY TRACT IRRITATION, DIZZINESS,
INCOORDINATION, LOSS OF BALANCE, HEADACHE, WEAKNESS,
UNCONSCIOUSNESS, RESPIRATORY FAILURE. INGESTION: PRACTICALLY
NON-TOXIC.
Medical Cond Aggravated by Exposure:PERSON WITH PRE-EXISTING DISEASE
INVOLVING THE EYES, SKIN, OR RESPIRATORY TRACT MAY BE AT INCREASED
RISK FROM EXPOSURE.
* First Aid Measures *
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED
CLOTHING. WASH AREA WITH SOAP AND WATER. INHALATION: MOVE TO FRESH
AIR. IF NOT BREATHI NG GIVE CPR. IF BREATHING DIFFICULT, GIVE
OXYGEN. GET MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING.
GET MEDICAL ATTENTION. SMALL AMOUNTS WHICH MAY ENTER MOUTH SHOULD
BE RINSED OUT.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:0.7
Upper Limits:5.0
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER.
Fire Fighting Procedures:USE WATER TO KEEP FIRE-EXPOSED CONTAINERS
COOL. IF A LEAK OR SPILL HAS NOT IGNITED, USE WATER SPRAY TO
DISPERSE THE VAPORS AND TO PROTECT FIREFIGHTERS.
Unusual Fire/Explosion Hazard:WEAR SELF-CONTAINED BREATHING EQUIPMENT
WHEN FIRE FIGHTING IN CONFINED SPACES.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. STOP LEAK.
VENTILATE AREA. CONTAIN SPILL BY DIKING. RECOVER LIQUID PRODUCT.
ABSORB RESIDUE WITH SUITABLE ABSORBENT. COLLECT WASTE IN SUITABLE
CONTAINERS FOR DISPOSAL .DO NOT PERMIT SPILL TO ENTER SEWERS
ORWATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA
AWAY FROM HEAT, FIRE, SPARKS, AND FLAME. KEEP CONTAINER TIGHTLY
CLOSED. NFPA CLASS II LIQUID STORAGE.
Other Precautions:PROTECT CONTAINER FROM PHYSICAL DAMAGE.
* Physical/Chemical Properties *
HCC:F4
Solubility in Water:NIL
Appearance and Odor:COLORLESS LIQUID. LIGHT KEROSENE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, OPEN FLAMES AND
OTHER POSSIBLE IGNITION SOURCES.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE MAY BE
FORMED ON BURNING IN LIMITED AIR SUPPLY.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE IN WELL VENTILATED AREAS.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:COPPER CYANIDE (SARA III)
Fraction by Wt: 0.0%
OSHA PEL:1 MG CU/M3
ACGIH TLV:1 MG CU/M3
Ingred Name:SODIUM CYANIDE (SARA III)
OSHA PEL:5 MG/M3 (CN)
* First Aid Measures *
First Aid:IF SPILLED ON CLOTHING ON SKIN,RINSE OFF WITH WATER.IF TAKEN
INTERNALLY,CALL DR.IMMEDIATELY & TREAT AS SHOWN ON JAR LABEL.IF
SPLASHED IN EYES,FLUSH W/WATER & CALL DOCTOR.
* Accidental Release Measures *
Spill Release Procedures:WIPE WITH RAGS.RINSE THOROUGHLY WITH WATER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM ACIDS & FOOD
STUFFS.WASH HANDS AFTER USING.OBSERVE INSTRUCTIONS ON LABEL.
* Physical/Chemical Properties *
HCC:T3
Appearance and Odor:RED COLOR LIQUID,SLIGHT AMMONIA ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
KEEP AWAY FROM ACIDS.
Hazardous Decomposition Products:HYDROGEN CYANIDE GAS IF MIXED WITH
ACIDS.
* Disposal Considerations *
Waste Disposal Methods:SHIP IN APPROVED DISPOSAL CONTAINERS TO AN
APPROVED DISPOSAL AREA.
| 1 | gloves_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NEEDED IN NORMAL USE WITH PROPER
VENTILATION. IN POORLY VENTILATED AREAS USE NIOSH-APPROVED ORGANIC
VAPOR RESPIRATOR.
Ventilation:GENERAL MECHANICAL VENTILATION IS ADEQUATE FOR OCCASIONAL
USE. FOR PROLONGED OR REPEATED USE, LOCAL EXHAUST.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING AND LAUNDER
THOROUGHLY BEFORE REUSE.
Supplemental Safety and Health
PROPER SHIPPING NAME: CORROSIVE LIQUID, N.O.S.. (CONTAINER<1 PINT ARE
ORM-D).
* Product Identification *
Product ID:STAINLESS STEEL PUTTY(ST) HARDNER
CAGE:0RZG3
CAGE:0RZG3
* Composition/Information on Ingredients *
Ingred Name:TRIETHYLENE TETRAMINE
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES-SEVERE IRRITATION OR BURNS.
SKIN-SEVERE IRRITATION OR BURNS. INHALATION-IRRITATION OF NOSE AND
THROAT; NAUSEA AND VOMITING IN SEVERE CASES. INGESTION-MAY CAUSE
BURNS OF MOUTH AND THROAT AND GAST ROINTESTINAL IRRITATION OR
ULCERATION.
Explanation of Carcinogenicity:INGREDIENTS LISTED: NO
Effects of Overexposure:REPEATED SKIN CONTACT OR INHALATION OF FUMES
CAN CAUSE SENSITIZATION, WITH ITCHING, RASHES, OR SWELLING OF THE
SKIN OR AN ASTHMA-LIKE RESPIRATORY REACTION ON LATER EXPOSURE TO
THE PRODUCT. REPEATED OV EREXPOSURE TO TETA CAN CAUSE LIVER AND
KIDNEY EFFECTS.
Medical Cond Aggravated by Exposure:ASTHMA, BRONCHITIS OR SKIN
IRRITATION.
* First Aid Measures *
WHILE GENTLY HOLDING EYELIDS OPEN. GET MEDICAL HELP AS SOON AS
POSSIBLE. SKIN-IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND WASH
WELL WITH D OAP AND WARM WATER. SEE DOCTOR IF IRRITATION DEVELOPS.
INHALATION-REMOVE PATIENT TO FRESH AIR. GIVE OXYGEN OR CPR IF
NEEDED. INGEATION-DO NOT INDUCE VOMITING. DILUTE WITH MILK/WATER &
GET MEDICAL AID.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR SELF-CONTAINED
BREATHING APPARATUS AND SUFFICIENT PROTECTIVE GEAR TO PREVENT ALL
SKIN AND EYE CONTACT WITH THIS MATERIAL.
Unusual Fire/Explosion Hazard:DECOMPOSITION PRODUCES HAZARDOUS FUMES.
* Accidental Release Measures *
Spill Release Procedures:PREVENT SKIN AND EYE CONTACT; REMOVE
CONTAMINATED CLOTHING AND SHOES. ABSORB SPILL ON INERT MATERIAL
SUCH AS VERMICULITE; SCRAPE UP AND TRANSFER TO IMPERVIOUS
CONTAINERS. SCRUB SPILL AREA WITH STRONG DETERGENT AND WATER.
*Handling and Storage *
Handling and Storage Precautions:STORE WELL-CLOSED IN A COOL, DRY
PLACE. KEEP HANDS AWAY FROM EYES WHEN HANDLING, AND UNTIL HANDS ARE
WASHED AFETR USING MATERIALS.
Other Precautions:IF THIS PRODUCT IS SANDED OR MACHINED AFTER CURING,
TAKE APPROPIATE PRECAUTIONS AGAINST INHALATION OF NUISANCE
PARTICLES.
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:N/D
Vapor Density:>1
Evaporation Rate & Reference:<1
Appearance and Odor:WHITE PASTE WITH MILD AMMONIA-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS AND CHLORINATED ORGANIC COMPOUNDS.
Stability Condition to Avoid:EXTREME HEAT OR OPEN FLAMES.
Hazardous Decomposition Products:ACRIDS AND TOXIC FUMES WITH ORGANIC
AMINES, AMMONIA, OXIDES OF CARBON AND NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:KEEP OUT OF PUBLIC WATER SUPPLIES. INCINERATE IN
APPROVED FACILITY WHERE PERMITTED BY STATE AND LOCAL REGULATION.
| 1 | gloves_mandatory |