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Acid | In food | In food
thumb|Carbonated water (H2CO3 aqueous solution) is commonly added to soft drinks to make them effervesce.
Tartaric acid is an important component of some commonly used foods like unripened mangoes and tamarind. Natural fruits and vegetables also contain acids. Citric acid is present in oranges, lemon and other citrus fruits. Oxalic acid is present in tomatoes, spinach, and especially in carambola and rhubarb; rhubarb leaves and unripe carambolas are toxic because of high concentrations of oxalic acid. Ascorbic acid (Vitamin C) is an essential vitamin for the human body and is present in such foods as amla (Indian gooseberry), lemon, citrus fruits, and guava.
Many acids can be found in various kinds of food as additives, as they alter their taste and serve as preservatives. Phosphoric acid, for example, is a component of cola drinks. Acetic acid is used in day-to-day life as vinegar. Citric acid is used as a preservative in sauces and pickles.
Carbonic acid is one of the most common acid additives that are widely added in soft drinks. During the manufacturing process, CO2 is usually pressurized to dissolve in these drinks to generate carbonic acid. Carbonic acid is very unstable and tends to decompose into water and CO2 at room temperature and pressure. Therefore, when bottles or cans of these kinds of soft drinks are opened, the soft drinks fizz and effervesce as CO2 bubbles come out.
Certain acids are used as drugs. Acetylsalicylic acid (Aspirin) is used as a pain killer and for bringing down fevers. |
Acid | In human bodies | In human bodies
Acids play important roles in the human body. The hydrochloric acid present in the stomach aids digestion by breaking down large and complex food molecules. Amino acids are required for synthesis of proteins required for growth and repair of body tissues. Fatty acids are also required for growth and repair of body tissues. Nucleic acids are important for the manufacturing of DNA and RNA and transmitting of traits to offspring through genes. Carbonic acid is important for maintenance of pH equilibrium in the body.
Human bodies contain a variety of organic and inorganic compounds, among those dicarboxylic acids play an essential role in many biological behaviors. Many of those acids are amino acids, which mainly serve as materials for the synthesis of proteins. Other weak acids serve as buffers with their conjugate bases to keep the body's pH from undergoing large scale changes that would be harmful to cells. The rest of the dicarboxylic acids also participate in the synthesis of various biologically important compounds in human bodies. |
Acid | Acid catalysis | Acid catalysis
Acids are used as catalysts in industrial and organic chemistry; for example, sulfuric acid is used in very large quantities in the alkylation process to produce gasoline. Some acids, such as sulfuric, phosphoric, and hydrochloric acids, also effect dehydration and condensation reactions. In biochemistry, many enzymes employ acid catalysis. |
Acid | Biological occurrence | Biological occurrence
thumb|left|Basic structure of an amino acidMany biologically important molecules are acids. Nucleic acids, which contain acidic phosphate groups, include DNA and RNA. Nucleic acids contain the genetic code that determines many of an organism's characteristics, and is passed from parents to offspring. DNA contains the chemical blueprint for the synthesis of proteins, which are made up of amino acid subunits. Cell membranes contain fatty acid esters such as phospholipids.
An α-amino acid has a central carbon (the α or alpha carbon) that is covalently bonded to a carboxyl group (thus they are carboxylic acids), an amino group, a hydrogen atom and a variable group. The variable group, also called the R group or side chain, determines the identity and many of the properties of a specific amino acid. In glycine, the simplest amino acid, the R group is a hydrogen atom, but in all other amino acids it is contains one or more carbon atoms bonded to hydrogens, and may contain other elements such as sulfur, oxygen or nitrogen. With the exception of glycine, naturally occurring amino acids are chiral and almost invariably occur in the L-configuration. Peptidoglycan, found in some bacterial cell walls contains some D-amino acids. At physiological pH, typically around 7, free amino acids exist in a charged form, where the acidic carboxyl group (-COOH) loses a proton (-COO−) and the basic amine group (-NH2) gains a proton (-NH). The entire molecule has a net neutral charge and is a zwitterion, with the exception of amino acids with basic or acidic side chains. Aspartic acid, for example, possesses one protonated amine and two deprotonated carboxyl groups, for a net charge of −1 at physiological pH.
Fatty acids and fatty acid derivatives are another group of carboxylic acids that play a significant role in biology. These contain long hydrocarbon chains and a carboxylic acid group on one end. The cell membrane of nearly all organisms is primarily made up of a phospholipid bilayer, a micelle of hydrophobic fatty acid esters with polar, hydrophilic phosphate "head" groups. Membranes contain additional components, some of which can participate in acid–base reactions.
In humans and many other animals, hydrochloric acid is a part of the gastric acid secreted within the stomach to help hydrolyze proteins and polysaccharides, as well as converting the inactive pro-enzyme, pepsinogen into the enzyme, pepsin. Some organisms produce acids for defense; for example, ants produce formic acid.
Acid–base equilibrium plays a critical role in regulating mammalian breathing. Oxygen gas (O2) drives cellular respiration, the process by which animals release the chemical potential energy stored in food, producing carbon dioxide (CO2) as a byproduct. Oxygen and carbon dioxide are exchanged in the lungs, and the body responds to changing energy demands by adjusting the rate of ventilation. For example, during periods of exertion the body rapidly breaks down stored carbohydrates and fat, releasing CO2 into the blood stream. In aqueous solutions such as blood CO2 exists in equilibrium with carbonic acid and bicarbonate ion.
It is the decrease in pH that signals the brain to breathe faster and deeper, expelling the excess CO2 and resupplying the cells with O2.
thumb|right|Aspirin (acetylsalicylic acid) is a carboxylic acid.
Cell membranes are generally impermeable to charged or large, polar molecules because of the lipophilic fatty acyl chains comprising their interior. Many biologically important molecules, including a number of pharmaceutical agents, are organic weak acids that can cross the membrane in their protonated, uncharged form but not in their charged form (i.e., as the conjugate base). For this reason the activity of many drugs can be enhanced or inhibited by the use of antacids or acidic foods. The charged form, however, is often more soluble in blood and cytosol, both aqueous environments. When the extracellular environment is more acidic than the neutral pH within the cell, certain acids will exist in their neutral form and will be membrane soluble, allowing them to cross the phospholipid bilayer. Acids that lose a proton at the intracellular pH will exist in their soluble, charged form and are thus able to diffuse through the cytosol to their target. Ibuprofen, aspirin and penicillin are examples of drugs that are weak acids. |
Acid | Common acids | Common acids |
Acid | Mineral acids (inorganic acids) | Mineral acids (inorganic acids)
Hydrogen halides and their solutions: hydrofluoric acid (HF), hydrochloric acid (HCl), hydrobromic acid (HBr), hydroiodic acid (HI)
Halogen oxoacids: hypochlorous acid (HClO), chlorous acid (HClO2), chloric acid (HClO3), perchloric acid (HClO4), and corresponding analogs for bromine and iodine
Hypofluorous acid (HFO), the only known oxoacid for fluorine.
Sulfuric acid (H2SO4)
Fluorosulfuric acid (HSO3F)
Nitric acid (HNO3)
Phosphoric acid (H3PO4)
Fluoroantimonic acid (HSbF6)
Fluoroboric acid (HBF4)
Hexafluorophosphoric acid (HPF6)
Chromic acid (H2CrO4)
Boric acid (H3BO3) |
Acid | Sulfonic acids | Sulfonic acids
A sulfonic acid has the general formula RS(=O)2–OH, where R is an organic radical.
Methanesulfonic acid (or mesylic acid, CH3SO3H)
Ethanesulfonic acid (or esylic acid, CH3CH2SO3H)
Benzenesulfonic acid (or besylic acid, C6H5SO3H)
p-Toluenesulfonic acid (or tosylic acid, CH3C6H4SO3H)
Trifluoromethanesulfonic acid (or triflic acid, CF3SO3H)
Polystyrene sulfonic acid (sulfonated polystyrene, [CH2CH(C6H4)SO3H]n) |
Acid | Carboxylic acids | Carboxylic acids
A carboxylic acid has the general formula R-C(O)OH, where R is an organic radical. The carboxyl group -C(O)OH contains a carbonyl group, C=O, and a hydroxyl group, O-H.
Acetic acid (CH3COOH)
Citric acid (C6H8O7)
Formic acid (HCOOH)
Gluconic acid HOCH2-(CHOH)4-COOH
Lactic acid (CH3-CHOH-COOH)
Oxalic acid (HOOC-COOH)
Tartaric acid (HOOC-CHOH-CHOH-COOH) |
Acid | Halogenated carboxylic acids | Halogenated carboxylic acids
Halogenation at alpha position increases acid strength, so that the following acids are all stronger than acetic acid.
Fluoroacetic acid
Trifluoroacetic acid
Chloroacetic acid
Dichloroacetic acid
Trichloroacetic acid |
Acid | Vinylogous carboxylic acids | Vinylogous carboxylic acids
Normal carboxylic acids are the direct union of a carbonyl group and a hydroxyl group. In vinylogous carboxylic acids, a carbon-carbon double bond separates the carbonyl and hydroxyl groups.
Ascorbic acid |
Acid | Nucleic acids | Nucleic acids
Deoxyribonucleic acid (DNA)
Ribonucleic acid (RNA) |
Acid | References | References
Listing of strengths of common acids and bases
|
Acid | External links | External links
Curtipot: Acid–Base equilibria diagrams, pH calculation and titration curves simulation and analysis – freeware
Category:Acid–base chemistry |
Acid | Table of Content | pp-semi-indef, Definitions and concepts, Arrhenius acids, Brønsted–Lowry acids{{anchor, Lewis acids, Dissociation and equilibrium, Nomenclature, Acid strength, Lewis acid strength in non-aqueous solutions, Chemical characteristics, Monoprotic acids, Polyprotic acids, Neutralization, Weak acid–weak base equilibrium, Titration, Example: Diprotic acid, Equivalence points, Buffer regions and midpoints, Applications of acids, In industry, In food, In human bodies, Acid catalysis, Biological occurrence, Common acids, Mineral acids (inorganic acids), Sulfonic acids, Carboxylic acids, Halogenated carboxylic acids, Vinylogous carboxylic acids, Nucleic acids, References, External links |
Bitumen | short description | 300px|thumb|Natural bitumen from the Dead Sea
thumb|Refined bitumen
thumb|upright|The University of Queensland pitch drop experiment, demonstrating the viscosity of bitumen
Bitumen ( , ) is an immensely viscous constituent of petroleum. Depending on its exact composition, it can be a sticky, black liquid or an apparently solid mass that behaves as a liquid over very large time scales. In American English, the material is commonly referred to as asphalt or tar. Whether found in natural deposits or refined from petroleum, the substance is classed as a pitch. Prior to the 20th century, the term asphaltum was in general use. The word derives from the Ancient Greek word (), which referred to natural bitumen or pitch. The largest natural deposit of bitumen in the world is the Pitch Lake of southwest Trinidad, which is estimated to contain 10 million tons.
About 70% of annual bitumen production is destined for road construction, its primary use. In this application, bitumen is used to bind aggregate particles like gravel and forms a substance referred to as asphalt concrete, which is colloquially termed asphalt. Its other main uses lie in bituminous waterproofing products, such as roofing felt and roof sealant.
In material sciences and engineering, the terms asphalt and bitumen are often used interchangeably and refer both to natural and manufactured forms of the substance, although there is regional variation as to which term is most common. Worldwide, geologists tend to favor the term bitumen for the naturally occurring material. For the manufactured material, which is a refined residue from the distillation process of selected crude oils, bitumen is the prevalent term in much of the world; however, in American English, asphalt is more commonly used. To help avoid confusion, the terms "liquid asphalt", "asphalt binder", or "asphalt cement" are used in the U.S. to distinguish it from asphalt concrete. Colloquially, various forms of bitumen are sometimes referred to as "tar", as in the name of the La Brea Tar Pits.
Naturally occurring bitumen is sometimes specified by the term crude bitumen. Its viscosity is similar to that of cold molasses while the material obtained from the fractional distillation of crude oil boiling at is sometimes referred to as "refined bitumen". The Canadian province of Alberta has most of the world's reserves of natural bitumen in the Athabasca oil sands, which cover , an area larger than England. |
Bitumen | Terminology | Terminology |
Bitumen | Etymology | Etymology
The Latin word traces to the Proto-Indo-European root *gʷet- "pitch".
The word "asphalt" is derived from the late Middle English, in turn from French asphalte, based on Late Latin asphaltum, which is the latinisation of the Greek (ásphaltos), a word meaning "asphalt/bitumen/pitch",. which perhaps derives from , "not, without", i.e. the alpha privative, and (sphallein), "to cause to fall, baffle, (in passive) err, (in passive) be balked of"..
The first use of asphalt by the ancients was as a cement to secure or join various objects, and it thus seems likely that the name itself was expressive of this application. Specifically, Herodotus mentioned that bitumen was brought to Babylon to build its gigantic fortification wall.Herodotus, The Histories, 1.179.4, on Perseus.
From the Greek, the word passed into late Latin, and thence into French (asphalte) and English ("asphaltum" and "asphalt"). In French, the term asphalte is used for naturally occurring asphalt-soaked limestone deposits, and for specialised manufactured products with fewer voids or greater bitumen content than the "asphaltic concrete" used to pave roads. |
Bitumen | Modern terminology | Modern terminology
Bitumen mixed with clay was usually called "asphaltum", but the term is less commonly used today.
In American English, "asphalt" is equivalent to the British "bitumen". However, "asphalt" is also commonly used as a shortened form of "asphalt concrete" (therefore equivalent to the British "asphalt" or "tarmac").
In Canadian English, the word "bitumen" is used to refer to the vast Canadian deposits of extremely heavy crude oil, while "asphalt" is used for the oil refinery product. Diluted bitumen (diluted with naphtha to make it flow in pipelines) is known as "dilbit" in the Canadian petroleum industry, while bitumen "upgraded" to synthetic crude oil is known as "syncrude", and syncrude blended with bitumen is called "synbit".
"Bitumen" is still the preferred geological term for naturally occurring deposits of the solid or semi-solid form of petroleum. "Bituminous rock" is a form of sandstone impregnated with bitumen. The oil sands of Alberta, Canada are a similar material.
Neither of the terms "asphalt" or "bitumen" should be confused with tar or coal tars. Tar is the thick liquid product of the dry distillation and pyrolysis of organic hydrocarbons primarily sourced from vegetation masses, whether fossilized as with coal, or freshly harvested. The majority of bitumen, on the other hand, was formed naturally when vast quantities of organic animal materials were deposited by water and buried hundreds of metres deep at the diagenetic point, where the disorganized fatty hydrocarbon molecules joined in long chains in the absence of oxygen. Bitumen occurs as a solid or highly viscous liquid. It may even be mixed in with coal deposits. Bitumen, and coal using the Bergius process, can be refined into petrols such as gasoline, and bitumen may be distilled into tar, not the other way around. |
Bitumen | Composition | Composition |
Bitumen | Normal composition | Normal composition
The components of bitumen include four main classes of compounds:
Naphthene aromatics (naphthalene), consisting of partially hydrogenated polycyclic aromatic compounds
Polar aromatics, consisting of high molecular weight phenols and carboxylic acids produced by partial oxidation of the material
Saturated hydrocarbons; the percentage of saturated compounds in asphalt correlates with its softening point
Asphaltenes, consisting of high molecular weight phenols and heterocyclic compounds
Bitumen typically contains, elementally 80% by weight of carbon; 10% hydrogen; up to 6% sulfur; and molecularly, between 5 and 25% by weight of asphaltenes dispersed in 90% to 65% maltenes. Most natural bitumens also contain organosulfur compounds, nickel and vanadium are found at <10 parts per million, as is typical of some petroleum. The substance is soluble in carbon disulfide. It is commonly modelled as a colloid, with asphaltenes as the dispersed phase and maltenes as the continuous phase. "It is almost impossible to separate and identify all the different molecules of bitumen, because the number of molecules with different chemical structure is extremely large".Muhammad Abdul Quddus (1992), p. 99, in ch. 5 pdf
Asphalt may be confused with coal tar, which is a visually similar black, thermoplastic material produced by the destructive distillation of coal. During the early and mid-20th century, when town gas was produced, coal tar was a readily available byproduct and extensively used as the binder for road aggregates. The addition of coal tar to macadam roads led to the word "tarmac", which is now used in common parlance to refer to road-making materials. However, since the 1970s, when natural gas succeeded town gas, bitumen has completely overtaken the use of coal tar in these applications. Other examples of this confusion include La Brea Tar Pits and the Canadian tar sands, both of which actually contain natural bitumen rather than tar. "Pitch" is another term sometimes informally used at times to refer to asphalt, as in Pitch Lake. |
Bitumen | Additives, mixtures and contaminants | Additives, mixtures and contaminants
For economic and other reasons, bitumen is sometimes sold combined with other materials, often without being labeled as anything other than simply "bitumen".Arnold, Terence S. (senior research chemist, Pavement Materials Team, Office of Infrastructure Research and Development, Federal Highway Administration; Federal lab manager for the chemistry lab, Turner-Fairbank Highway Research Center; fellow of the Royal Society of Chemistry in the United Kingdom), "What's in Your Asphalt?," September 2017 (last modified 25 October 2017), Public Roads, FHWA-HRT-17-006.htm," Office of Research, Development, and Technology, Office of Corporate Research, Technology, and Innovation Management, Federal Highway Administration, U.S. Department of Transportation
Of particular note is the use of re-refined engine oil bottoms – "REOB" or "REOBs"the residue of recycled automotive engine oil collected from the bottoms of re-refining vacuum distillation towers, in the manufacture of asphalt. REOB contains various elements and compounds found in recycled engine oil: additives to the original oil and materials accumulating from its circulation in the engine (typically iron and copper). Some research has indicated a correlation between this adulteration of bitumen and poorer-performing pavement. |
Bitumen | Occurrence | Occurrence
thumb|right|upright|Bituminous outcrop of the Puy de la Poix, Clermont-Ferrand, France
The majority of bitumen used commercially is obtained from petroleum. Nonetheless, large amounts of bitumen occur in concentrated form in nature. Naturally occurring deposits of bitumen are formed from the remains of ancient, microscopic algae (diatoms) and other once-living things. These natural deposits of bitumen have been formed during the Carboniferous period, when giant swamp forests dominated many parts of the Earth. They were deposited in the mud on the bottom of the ocean or lake where the organisms lived. Under the heat (above 50°C) and pressure of burial deep in the earth, the remains were transformed into materials such as bitumen, kerogen, or petroleum.
Natural deposits of bitumen include lakes such as the Pitch Lake in Trinidad and Tobago and Lake Bermudez in Venezuela. Natural seeps occur in the La Brea Tar Pits and the McKittrick Tar Pits in California, as well as in the Dead Sea.
Bitumen also occurs in unconsolidated sandstones known as "oil sands" in Alberta, Canada, and the similar "tar sands" in Utah, US.
The Canadian province of Alberta has most of the world's reserves, in three huge deposits covering , an area larger than England or New York state. These bituminous sands contain of commercially established oil reserves, giving Canada the third largest oil reserves in the world. Although historically it was used without refining to pave roads, nearly all of the output is now used as raw material for oil refineries in Canada and the United States.
The world's largest deposit of natural bitumen, known as the Athabasca oil sands, is located in the McMurray Formation of Northern Alberta. This formation is from the early Cretaceous, and is composed of numerous lenses of oil-bearing sand with up to 20% oil. Isotopic studies show the oil deposits to be about 110 million years old. Two smaller but still very large formations occur in the Peace River oil sands and the Cold Lake oil sands, to the west and southeast of the Athabasca oil sands, respectively. Of the Alberta deposits, only parts of the Athabasca oil sands are shallow enough to be suitable for surface mining. The other 80% has to be produced by oil wells using enhanced oil recovery techniques like steam-assisted gravity drainage.
Much smaller heavy oil or bitumen deposits also occur in the Uinta Basin in Utah, US. The Tar Sand Triangle deposit, for example, is roughly 6% bitumen.
Bitumen may occur in hydrothermal veins. An example of this is within the Uinta Basin of Utah, in the US, where there is a swarm of laterally and vertically extensive veins composed of a solid hydrocarbon termed Gilsonite. These veins formed by the polymerization and solidification of hydrocarbons that were mobilized from the deeper oil shales of the Green River Formation during burial and diagenesis.
Bitumen is similar to the organic matter in carbonaceous meteorites. However, detailed studies have shown these materials to be distinct. The vast Alberta bitumen resources are considered to have started out as living material from marine plants and animals, mainly algae, that died millions of years ago when an ancient ocean covered Alberta. They were covered by mud, buried deeply over time, and gently cooked into oil by geothermal heat at a temperature of . Due to pressure from the rising of the Rocky Mountains in southwestern Alberta, 80 to 55 million years ago, the oil was driven northeast hundreds of kilometres and trapped into underground sand deposits left behind by ancient river beds and ocean beaches, thus forming the oil sands. |
Bitumen | History | History |
Bitumen | Paleolithic times | Paleolithic times
Bitumen use goes back to the Middle Paleolithic, where it was shaped into tool handles or used as an adhesive for attaching stone tools to hafts.
The earliest evidence of bitumen use was discovered when archeologists identified bitumen material on Levallois flint artefacts that date to about 71,000 years BP at the Umm el Tlel open-air site, located on the northern slope of the Qdeir Plateau in el Kowm Basin in Central Syria. Microscopic analyses found bituminous residue on two-thirds of the stone artefacts, suggesting that bitumen was an important and frequently-used component of tool making for people in that region at that time. Geochemical analyses of the asphaltic residues places its source to localized natural bitumen outcroppings in the Bichri Massif, about 40 km northeast of the Umm el Tlel archeological site.
A re-examination of artifacts uncovered in 1908 at Le Moustier rock shelters in France has identified Mousterian stone tools that were attached to grips made of ochre and bitumen. The grips were formulated with 55% ground goethite ochre and 45% cooked liquid bitumen to create a moldable putty that hardened into handles. Earlier, less-careful excavations at Le Moustier prevent conclusive identification of the archaeological culture and age, but the European Mousterian style of these tools suggests they are associated with Neanderthals during the late Middle Paleolithic into the early Upper Paleolithic between 60,000 and 35,000 years before present. It is the earliest evidence of multicomponent adhesive in Europe. |
Bitumen | Ancient times | Ancient times
The use of natural bitumen for waterproofing and as an adhesive dates at least to the fifth millennium BC, with a crop storage basket discovered in Mehrgarh, of the Indus Valley civilization, lined with it.McIntosh, Jane. The Ancient Indus Valley. p. 57 By the 3rd millennium BC refined rock asphalt was in use in the region, and was used to waterproof the Great Bath in Mohenjo-daro.
In the ancient Near East, the Sumerians used natural bitumen deposits for mortar between bricks and stones, to cement parts of carvings, such as eyes, into place, for ship caulking, and for waterproofing. The Greek historian Herodotus said hot bitumen was used as mortar in the walls of Babylon.Herodotus, Book I, 179
The long Euphrates Tunnel beneath the river Euphrates at Babylon in the time of Queen Semiramis () was reportedly constructed of burnt bricks covered with bitumen as a waterproofing agent.
Bitumen was used by ancient Egyptians to embalm mummies. The Persian word for asphalt is moom, which is related to the English word mummy. The Egyptians' primary source of bitumen was the Dead Sea, which the Romans knew as Palus Asphaltites (Asphalt Lake).
In approximately 40 AD, Dioscorides described the Dead Sea material as Judaicum bitumen, and noted other places in the region where it could be found. Original written c. 40 AD, translated by Goodyer (1655) or (Greek/Latin) compiled by Sprengel (1829) p. 100 (p. 145 in PDF). The Sidon bitumen is thought to refer to material found at Hasbeya in Lebanon. Pliny also refers to bitumen being found in Epirus. Bitumen was a valuable strategic resource. It was the object of the first known battle for a hydrocarbon deposit – between the Seleucids and the Nabateans in 312 BC.
In the ancient Far East, natural bitumen was slowly boiled to get rid of the higher fractions, leaving a thermoplastic material of higher molecular weight that, when layered on objects, became hard upon cooling. This was used to cover objects that needed waterproofing, such as scabbards and other items. Statuettes of household deities were also cast with this type of material in Japan, and probably also in China.
In North America, archaeological recovery has indicated that bitumen was sometimes used to adhere stone projectile points to wooden shafts. In Canada, aboriginal people used bitumen seeping out of the banks of the Athabasca and other rivers to waterproof birch bark canoes, and also heated it in smudge pots to ward off mosquitoes in the summer. Bitumen was also used to waterproof plank canoes used by indigenous peoples in pre-colonial southern California. |
Bitumen | Continental Europe | Continental Europe
In 1553, Pierre Belon described in his work Observations that pissasphalto, a mixture of pitch and bitumen, was used in the Republic of Ragusa (now Dubrovnik, Croatia) for tarring of ships.
An 1838 edition of Mechanics Magazine cites an early use of asphalt in France. A pamphlet dated 1621, by "a certain Monsieur d'Eyrinys, states that he had discovered the existence (of asphaltum) in large quantities in the vicinity of Neufchatel", and that he proposed to use it in a variety of ways – "principally in the construction of air-proof granaries, and in protecting, by means of the arches, the water-courses in the city of Paris from the intrusion of dirt and filth", which at that time made the water unusable. "He expatiates also on the excellence of this material for forming level and durable terraces" in palaces, "the notion of forming such terraces in the streets not one likely to cross the brain of a Parisian of that generation".
But the substance was generally neglected in France until the revolution of 1830. In the 1830s there was a surge of interest, and asphalt became widely used "for pavements, flat roofs, and the lining of cisterns, and in England, some use of it had been made of it for similar purposes". Its rise in Europe was "a sudden phenomenon", after natural deposits were found "in France at Osbann (Bas-Rhin), the Parc (Ain) and the Puy-de-la-Poix (Puy-de-Dôme)", although it could also be made artificially.. Note: different sections of Miles' online work were written in different years, as evidenced at the top of each page (not including the heading page of each section). This particular section appears to have been written in 2000 One of the earliest uses in France was the laying of about 24,000 square yards of Seyssel asphalt at the Place de la Concorde in 1835. |
Bitumen | United Kingdom | United Kingdom
Among the earlier uses of bitumen in the United Kingdom was for etching. William Salmon's Polygraphice (1673) provides a recipe for varnish used in etching, consisting of three ounces of virgin wax, two ounces of mastic, and one ounce of asphaltum. By the fifth edition in 1685, he had included more asphaltum recipes from other sources.
The first British patent for the use of asphalt was "Cassell's patent asphalte or bitumen" in 1834. Then on 25 November 1837, Richard Tappin Claridge patented the use of Seyssel asphalt (patent #7849), for use in asphalte pavement, Writer is replying to note or query from previous publication, cited as 9th S. xi. 30 having seen it employed in France and Belgium when visiting with Frederick Walter Simms, who worked with him on the introduction of asphalt to Britain. Dr T. Lamb Phipson writes that his father, Samuel Ryland Phipson, a friend of Claridge, was also "instrumental in introducing the asphalte pavement (in 1836)". Full text at Internet Archive (archive.org)
Claridge obtained a patent in Scotland on 27 March 1838, and obtained a patent in Ireland on 23 April 1838. In 1851, extensions for the 1837 patent and for both 1838 patents were sought by the trustees of a company previously formed by Claridge. Claridge's Patent Asphalte Companyformed in 1838 for the purpose of introducing to Britain "Asphalte in its natural state from the mine at Pyrimont Seysell in France","laid one of the first asphalt pavements in Whitehall".Miles, Lewis (2000), pp.10.06.1–2 Trials were made of the pavement in 1838 on the footway in Whitehall, the stable at Knightsbridge Barracks,Comments on asphalt patents of R.T. Claridge, Esq (1904), p. 18 "and subsequently on the space at the bottom of the steps leading from Waterloo Place to St. James Park". "The formation in 1838 of Claridge's Patent Asphalte Company (with a distinguished list of aristocratic patrons, and Marc and Isambard Brunel as, respectively, a trustee and consulting engineer), gave an enormous impetus to the development of a British asphalt industry". "By the end of 1838, at least two other companies, Robinson's and the Bastenne company, were in production",Miles, Lewis (2000), p. 10.06.2 with asphalt being laid as paving at Brighton, Herne Bay, Canterbury, Kensington, the Strand, and a large floor area in Bunhill-row, while meantime Claridge's Whitehall paving "continue(d) in good order". The Bonnington Chemical Works manufactured asphalt using coal tar and by 1839 had installed it in Bonnington.
In 1838, there was a flurry of entrepreneurial activity involving bitumen, which had uses beyond paving. For example, bitumen could also be used for flooring, damp proofing in buildings, and for waterproofing of various types of pools and baths, both of which were also proliferating in the 19th century. (Enter "asphalt" into the search field for list of pages discussing the subject) One of the earliest surviving examples of its use can be seen at Highgate Cemetery where it was used in 1839 to seal the roof of the terrace catacombs. On the London stockmarket, there were various claims as to the exclusivity of bitumen quality from France, Germany and England. And numerous patents were granted in France, with similar numbers of patent applications being denied in England due to their similarity to each other. In England, "Claridge's was the type most used in the 1840s and 50s".
In 1914, Claridge's Company entered into a joint venture to produce tar-bound macadam, with materials manufactured through a subsidiary company called Clarmac Roads Ltd. Two products resulted, namely Clarmac, and Clarphalte, with the former being manufactured by Clarmac Roads and the latter by Claridge's Patent Asphalte Co., although Clarmac was more widely used. However, the First World War ruined the Clarmac Company, which entered into liquidation in 1915.Clarmac financial difficults due to WW1 Debentures deposited The Law Reports: Chancery Division, (1921) Vol. 1 p. 545. Retrieved 17 June 2010. The failure of Clarmac Roads Ltd had a flow-on effect to Claridge's Company, which was itself compulsorily wound up,Claridge's Patent Asphalte Co. compulsorily wound up Funds invested in new company The Law Times Reports (1921) Vol.125, p. 256. Retrieved 15 June 2010. ceasing operations in 1917, having invested a substantial amount of funds into the new venture, both at the outset and in a subsequent attempt to save the Clarmac Company.
Bitumen was thought in 19th century Britain to contain chemicals with medicinal properties. Extracts from bitumen were used to treat catarrh and some forms of asthma and as a remedy against worms, especially the tapeworm.The National Cyclopaedia of Useful Knowledge, Vol III, (1847) London, Charles Knight, p. 380. |
Bitumen | United States | United States
The first use of bitumen in the New World was by aboriginal peoples. On the west coast, as early as the 13th century, the Tongva, Luiseño and Chumash peoples collected the naturally occurring bitumen that seeped to the surface above underlying petroleum deposits. All three groups used the substance as an adhesive. It is found on many different artifacts of tools and ceremonial items. For example, it was used on rattles to adhere gourds or turtle shells to rattle handles. It was also used in decorations. Small round shell beads were often set in asphaltum to provide decorations. It was used as a sealant on baskets to make them watertight for carrying water, possibly poisoning those who drank the water. Asphalt was used also to seal the planks on ocean-going canoes.
Asphalt was first used to pave streets in the 1870s. At first naturally occurring "bituminous rock" was used, such as at Ritchie Mines in Macfarlan in Ritchie County, West Virginia from 1852 to 1873. In 1876, asphalt-based paving was used to pave Pennsylvania Avenue in Washington DC, in time for the celebration of the national centennial.
In the horse-drawn era, US streets were mostly unpaved and covered with dirt or gravel. Especially where mud or trenching often made streets difficult to pass, pavements were sometimes made of diverse materials including wooden planks, cobble stones or other stone blocks, or bricks. Unpaved roads produced uneven wear and hazards for pedestrians. In the late 19th century with the rise of the popular bicycle, bicycle clubs were important in pushing for more general pavement of streets. Advocacy for pavement increased in the early 20th century with the rise of the automobile. Asphalt gradually became an ever more common method of paving. St. Charles Avenue in New Orleans was paved its whole length with asphalt by 1889.
In 1900, Manhattan alone had 130,000 horses, pulling streetcars, wagons, and carriages, and leaving their waste behind. They were not fast, and pedestrians could dodge and scramble their way across the crowded streets. Small towns continued to rely on dirt and gravel, but larger cities wanted much better streets. They looked to wood or granite blocks by the 1850s.David O. Whitten, "A Century of Parquet Pavements: Wood as a Paving Material in the United States And Abroad, 1840–1940." Essays in Economic and Business History 15 (1997): 209–26. In 1890, a third of Chicago's 2000 miles of streets were paved, chiefly with wooden blocks, which gave better traction than mud. Brick surfacing was a good compromise, but even better was asphalt paving, which was easy to install and to cut through to get at sewers. With London and Paris serving as models, Washington laid 400,000 square yards of asphalt paving by 1882; it became the model for Buffalo, Philadelphia and elsewhere. By the end of the century, American cities boasted 30 million square yards of asphalt paving, well ahead of brick.Arthur Maier Schlesinger, The Rise of the City: 1878–1898 (1933), pp. 88–93. The streets became faster and more dangerous so electric traffic lights were installed. Electric trolleys (at 12 miles per hour) became the main transportation service for middle class shoppers and office workers until they bought automobiles after 1945 and commuted from more distant suburbs in privacy and comfort on asphalt highways.John D. Fairfield, "Rapid Transit: Automobility and Settlement in Urban America" Reviews in American History 23#1 (1995), pp. 80–85 online. |
Bitumen | Canada | Canada
Canada has the world's largest deposit of natural bitumen in the Athabasca oil sands, and Canadian First Nations along the Athabasca River had long used it to waterproof their canoes. In 1719, a Cree named Wa-Pa-Su brought a sample for trade to Henry Kelsey of the Hudson's Bay Company, who was the first recorded European to see it. However, it wasn't until 1787 that fur trader and explorer Alexander MacKenzie saw the Athabasca oil sands and said, "At about 24 miles from the fork (of the Athabasca and Clearwater Rivers) are some bituminous fountains into which a pole of 20 feet long may be inserted without the least resistance."
The value of the deposit was obvious from the start, but the means of extracting the bitumen was not. The nearest town, Fort McMurray, Alberta, was a small fur trading post, other markets were far away, and transportation costs were too high to ship the raw bituminous sand for paving. In 1915, Sidney Ells of the Federal Mines Branch experimented with separation techniques and used the product to pave 600 feet of road in Edmonton, Alberta. Other roads in Alberta were paved with material extracted from oil sands, but it was generally not economic. During the 1920s Dr. Karl A. Clark of the Alberta Research Council patented a hot water oil separation process and entrepreneur Robert C. Fitzsimmons built the Bitumount oil separation plant, which between 1925 and 1958 produced up to per day of bitumen using Dr. Clark's method. Most of the bitumen was used for waterproofing roofs, but other uses included fuels, lubrication oils, printers ink, medicines, rust- and acid-proof paints, fireproof roofing, street paving, patent leather, and fence post preservatives. Eventually Fitzsimmons ran out of money and the plant was taken over by the Alberta government. Today the Bitumount plant is a Provincial Historic Site. |
Bitumen | Photography and art | Photography and art
Bitumen was used in early photographic technology. In 1826, or 1827, it was used by French scientist Joseph Nicéphore Niépce to make the oldest surviving photograph from nature. The bitumen was thinly coated onto a pewter plate which was then exposed in a camera. Exposure to light hardened the bitumen and made it insoluble, so that when it was subsequently rinsed with a solvent only the sufficiently light-struck areas remained. Many hours of exposure in the camera were required, making bitumen impractical for ordinary photography, but from the 1850s to the 1920s it was in common use as a photoresist in the production of printing plates for various photomechanical printing processes.Niépce Museum history pages. Retrieved 27 October 2012. The First Photograph (Harry Ransom Center, University of Texas at Austin). Retrieved 27 October 2012.
Bitumen was the nemesis of many artists during the 19th century. Although widely used for a time, it ultimately proved unstable for use in oil painting, especially when mixed with the most common diluents, such as linseed oil, varnish and turpentine. Unless thoroughly diluted, bitumen never fully solidifies and will in time corrupt the other pigments with which it comes into contact. The use of bitumen as a glaze to set in shadow or mixed with other colors to render a darker tone resulted in the eventual deterioration of many paintings, for instance those of Delacroix. Perhaps the most famous example of the destructiveness of bitumen is Théodore Géricault's Raft of the Medusa (1818–1819), where his use of bitumen caused the brilliant colors to degenerate into dark greens and blacks and the paint and canvas to buckle. |
Bitumen | Modern use | Modern use |
Bitumen | Global use | Global use
The vast majority of refined bitumen is used in construction: primarily as a constituent of products used in paving and roofing applications. According to the requirements of the end use, bitumen is produced to specification. This is achieved either by refining or blending. It is estimated that the current world use of bitumen is approximately 102 million tonnes per year. Approximately 85% of all the bitumen produced is used as the binder in asphalt concrete for roads. It is also used in other paved areas such as airport runways, car parks and footways. Typically, the production of asphalt concrete involves mixing fine and coarse aggregates such as sand, gravel and crushed rock with asphalt, which acts as the binding agent. Other materials, such as recycled polymers (e.g., rubber tyres), may be added to the bitumen to modify its properties according to the application for which the bitumen is ultimately intended.
A further 10% of global bitumen production is used in roofing applications, where its waterproofing qualities are invaluable.
The remaining 5% of bitumen is used mainly for sealing and insulating purposes in a variety of building materials, such as pipe coatings, carpet tile backing and paint. Bitumen is applied in the construction and maintenance of many structures, systems, and components, such as:
Highways
Airport runways
Footways and pedestrian ways
Car parks
Racetracks
Tennis courts
Roofing
Damp proofing
Dams
Reservoir and pool linings
Soundproofing
Pipe coatings
Cable coatings
Paints
Building water proofing
Tile underlying waterproofing
Newspaper ink production |
Bitumen | Rolled asphalt concrete | Rolled asphalt concrete
The largest use of bitumen is for making asphalt concrete for road surfaces; this accounts for approximately 85% of the bitumen consumed in the United States. There are about 4,000 asphalt concrete mixing plants in the US, and a similar number in Europe.
thumb|Asphalt concrete is usually placed on top in a road.
Asphalt concrete pavement mixes are typically composed of 5% bitumen (known as asphalt cement in the US) and 95% aggregates (stone, sand, and gravel). Due to its highly viscous nature, bitumen must be heated so it can be mixed with the aggregates at the asphalt mixing facility. The temperature required varies depending upon characteristics of the bitumen and the aggregates, but warm-mix asphalt technologies allow producers to reduce the temperature required.
The weight of an asphalt pavement depends upon the aggregate type, the bitumen, and the air void content. An average example in the United States is about 112 pounds per square yard, per inch of pavement thickness.
When maintenance is performed on asphalt pavements, such as milling to remove a worn or damaged surface, the removed material can be returned to a facility for processing into new pavement mixtures. The bitumen in the removed material can be reactivated and put back to use in new pavement mixes. With some 95% of paved roads being constructed of or surfaced with asphalt, a substantial amount of asphalt pavement material is reclaimed each year. According to industry surveys conducted annually by the Federal Highway Administration and the National Asphalt Pavement Association, more than 99% of the bitumen removed each year from road surfaces during widening and resurfacing projects is reused as part of new pavements, roadbeds, shoulders and embankments or stockpiled for future use.
Asphalt concrete paving is widely used in airports around the world. Due to the sturdiness and ability to be repaired quickly, it is widely used for runways. |
Bitumen | Mastic asphalt | Mastic asphalt
Mastic asphalt is a type of asphalt that differs from dense graded asphalt (asphalt concrete) in that it has a higher bitumen (binder) content, usually around 7–10% of the whole aggregate mix, as opposed to rolled asphalt concrete, which has only around 5% asphalt. This thermoplastic substance is widely used in the building industry for waterproofing flat roofs and tanking underground. Mastic asphalt is heated to a temperature of and is spread in layers to form an impervious barrier about thick. |
Bitumen | Bitumen emulsion | Bitumen emulsion
thumb|Volume-weighted particle size distribution of 2 different asphalt emulsions determined by laser diffraction
Bitumen emulsions are colloidal mixtures of bitumen and water. Due to the different surface tensions of the two liquids, stable emulsions cannot be created simply by mixing. Therefore, various emulsifiers and stabilizers are added. Emulsifiers are amphiphilic molecules that differ in the charge of their polar head group. They reduce the surface tension of the emulsion and thus prevent bitumen particles from fusing. The emulsifier charge defines the type of emulsion: anionic (negatively charged) and cationic (positively charged). The concentration of an emulsifier is a critical parameter affecting the size of the bitumen particles—higher concentrations lead to smaller bitumen particles. Thus, emulsifiers have a great impact on the stability, viscosity, breaking strength, and adhesion of the bitumen emulsion. The size of bitumen particles is usually between 0.1 and 50μm with a main fraction between 1μm and 10μm. Laser diffraction techniques can be used to determine the particle size distribution quickly and easily. Cationic emulsifiers primarily include long-chain amines such as imidazolines, amido-amines, and diamines, which acquire a positive charge when an acid is added. Anionic emulsifiers are often fatty acids extracted from lignin, tall oil, or tree resin saponified with bases such as NaOH, which creates a negative charge.
During the storage of bitumen emulsions, bitumen particles sediment, agglomerate (flocculation), or fuse (coagulation), which leads to a certain instability of the bitumen emulsion. How fast this process occurs depends on the formulation of the bitumen emulsion but also storage conditions such as temperature and humidity. When emulsified bitumen gets into contact with aggregates, emulsifiers lose their effectiveness, the emulsion breaks down, and an adhering bitumen film is formed referred to as 'breaking'. Bitumen particles almost instantly create a continuous bitumen film by coagulating and separating from water which evaporates. Not each asphalt emulsion reacts as fast as the other when it gets into contact with aggregates. That enables a classification into Rapid-setting (R), Slow-setting (SS), and Medium-setting (MS) emulsions, but also an individual, application-specific optimization of the formulation and a wide field of application (1). For example, Slow-breaking emulsions ensure a longer processing time which is particularly advantageous for fine aggregates (1).
Adhesion problems are reported for anionic emulsions in contact with quartz-rich aggregates. They are substituted by cationic emulsions achieving better adhesion. The extensive range of bitumen emulsions is covered insufficiently by standardization. DIN EN 13808 for cationic asphalt emulsions has been existing since July 2005. Here, a classification of bitumen emulsions based on letters and numbers is described, considering charges, viscosities, and the type of bitumen. The production process of bitumen emulsions is very complex. Two methods are commonly used, the "Colloid mill" method and the "High Internal Phase Ratio (HIPR)" method. In the "Colloid mill" method, a rotor moves at high speed within a stator by adding bitumen and a water-emulsifier mixture. The resulting shear forces generate bitumen particles between 5μm and 10μm coated with emulsifiers. The "High Internal Phase Ratio (HIPR)" method is used for creating smaller bitumen particles, monomodal, narrow particle size distributions, and very high bitumen concentrations. Here, a highly concentrated bitumen emulsion is produced first by moderate stirring and diluted afterward. In contrast to the "Colloid-Mill" method, the aqueous phase is introduced into hot bitumen, enabling very high bitumen concentrations.
T The "High Internal Phase Ratio (HIPR)" method is used for creating smaller bitumen particles, monomodal, narrow particle size distributions, and very high bitumen concentrations. Here, a highly concentrated bitumen emulsion is produced first by moderate stirring and diluted afterward. In contrast to the "Colloid-Mill" method, the aqueous phase is introduced into hot bitumen, enabling very high bitumen concentrations (1).he "High Internal Phase Ratio (HIPR)" method is used for creating smaller bitumen particles, monomodal, narrow particle size distributions, and very high bitumen concentrations. Here, a highly concentrated bitumen emulsion is produced first by moderate stirring and diluted afterward. In contrast to the "Colloid-Mill" method, the aqueous phase is introduced into hot bitumen, enabling very high bitumen concentrations (1).
Bitumen emulsions are used in a wide variety of applications. They are used in road construction and building protection and primarily include the application in cold recycling mixtures, adhesive coating, and surface treatment (1). Due to the lower viscosity in comparison to hot bitumen, processing requires less energy and is associated with significantly less risk of fire and burns. Chipseal involves spraying the road surface with bitumen emulsion followed by a layer of crushed rock, gravel or crushed slag. Slurry seal is a mixture of bitumen emulsion and fine crushed aggregate that is spread on the surface of a road. Cold-mixed asphalt can also be made from bitumen emulsion to create pavements similar to hot-mixed asphalt, several inches in depth, and bitumen emulsions are also blended into recycled hot-mix asphalt to create low-cost pavements. Bitumen emulsion based techniques are known to be useful for all classes of roads, their use may also be possible in the following applications: 1. Asphalts for heavily trafficked roads (based on the use of polymer modified emulsions) 2. Warm emulsion based mixtures, to improve both their maturation time and mechanical properties 3. Half-warm technology, in which aggregates are heated up to 100 degrees, producing mixtures with similar properties to those of hot asphalts 4. High performance surface dressing.Read, J. and Whiteoak, D., 2003. The Shell Bitumen Handbook. Thomas Telford. |
Bitumen | Synthetic crude oil | Synthetic crude oil
Synthetic crude oil, also known as syncrude, is the output from a bitumen upgrader facility used in connection with oil sand production in Canada. Bituminous sands are mined using enormous (100-ton capacity) power shovels and loaded into even larger (400-ton capacity) dump trucks for movement to an upgrading facility. The process used to extract the bitumen from the sand is a hot water process originally developed by Dr. Karl Clark of the University of Alberta during the 1920s. After extraction from the sand, the bitumen is fed into a bitumen upgrader which converts it into a light crude oil equivalent. This synthetic substance is fluid enough to be transferred through conventional oil pipelines and can be fed into conventional oil refineries without any further treatment. By 2015 Canadian bitumen upgraders were producing over per day of synthetic crude oil, of which 75% was exported to oil refineries in the United States.
In Alberta, five bitumen upgraders produce synthetic crude oil and a variety of other products: The Suncor Energy upgrader near Fort McMurray, Alberta produces synthetic crude oil plus diesel fuel; the Syncrude Canada, Canadian Natural Resources, and Nexen upgraders near Fort McMurray produce synthetic crude oil; and the Shell Scotford Upgrader near Edmonton produces synthetic crude oil plus an intermediate feedstock for the nearby Shell Oil Refinery. A sixth upgrader, under construction in 2015 near Redwater, Alberta, will upgrade half of its crude bitumen directly to diesel fuel, with the remainder of the output being sold as feedstock to nearby oil refineries and petrochemical plants. |
Bitumen | Non-upgraded crude bitumen | Non-upgraded crude bitumen
Canadian bitumen does not differ substantially from oils such as Venezuelan extra-heavy and Mexican heavy oil in chemical composition, and the real difficulty is moving the extremely viscous bitumen through oil pipelines to the refinery. Many modern oil refineries are extremely sophisticated and can process non-upgraded bitumen directly into products such as gasoline, diesel fuel, and refined asphalt without any preprocessing. This is particularly common in areas such as the US Gulf coast, where refineries were designed to process Venezuelan and Mexican oil, and in areas such as the US Midwest where refineries were rebuilt to process heavy oil as domestic light oil production declined. Given the choice, such heavy oil refineries usually prefer to buy bitumen rather than synthetic oil because the cost is lower, and in some cases because they prefer to produce more diesel fuel and less gasoline. By 2015 Canadian production and exports of non-upgraded bitumen exceeded that of synthetic crude oil at over per day, of which about 65% was exported to the United States.
Because of the difficulty of moving crude bitumen through pipelines, non-upgraded bitumen is usually diluted with natural-gas condensate in a form called dilbit or with synthetic crude oil, called synbit. However, to meet international competition, much non-upgraded bitumen is now sold as a blend of multiple grades of bitumen, conventional crude oil, synthetic crude oil, and condensate in a standardized benchmark product such as Western Canadian Select. This sour, heavy crude oil blend is designed to have uniform refining characteristics to compete with internationally marketed heavy oils such as Mexican Mayan or Arabian Dubai Crude. |
Bitumen | Radioactive waste encapsulation matrix | Radioactive waste encapsulation matrix
Bitumen was used starting in the 1960s as a hydrophobic matrix aiming to encapsulate radioactive waste such as medium-activity salts (mainly soluble sodium nitrate and sodium sulfate) produced by the reprocessing of spent nuclear fuels or radioactive sludges from sedimentation ponds.Rodier, J., Scheidhauer, J., & Malabre, M. (1961). The conditioning of radioactive waste by bitumen (No. CEA-R1992). CEA Marcoule.Lefillatre, G., Rodier, J., Hullo, R., Cudel, Y., & Rodi, L. (1969). Use of a thin-film evaporator for bitumen coating of radioactive concentrates (No. CEA-R3742). CEA Marcoule. Bituminised radioactive waste containing highly radiotoxic alpha-emitting transuranic elements from nuclear reprocessing plants have been produced at industrial scale in France, Belgium and Japan, but this type of waste conditioning has been abandoned because operational safety issues (risks of fire, as occurred in a bituminisation plant at Tokai Works in Japan)Sato, Y., Miura, A., Kato, Y., Suzuki, H., Shigetome, Y., Koyama, T., ... & Yamanouchi, T. (2000). Study on the cause of the fire and explosion incident at Bituminization Demonstration Facility of PNC Tokai Works. In Nuclear waste: from research to industrial maturity. International conference (pp. 179–190).Okada, K., Nur, R. M., & Fujii, Y. (1999). The formation of explosive compounds in bitumen/nitrate mixtures. Journal of hazardous materials, 69(3), 245–256. and long-term stability problems related to their geological disposal in deep rock formations. One of the main problems is the swelling of bitumen exposed to radiation and to water. Bitumen swelling is first induced by radiation because of the presence of hydrogen gas bubbles generated by alpha and gamma radiolysis.Johnson, D.I., Hitchon, J.W., & Phillips, D.C. (1986). Further observations of the swelling of bitumens and simulated bitumen wasteforms during γ-irradiation (No. AERE-R12292). UKAEA Harwell Lab. Materials Development Division.Phillips, D. C., Hitchon, J. W., Johnson, D. I., & Matthews, J. R. (1984). The radiation swelling of bitumens and bitumenised wastes. Journal of nuclear materials, 125(2), 202–218. A second mechanism is the matrix swelling when the encapsulated hygroscopic salts exposed to water or moisture start to rehydrate and to dissolve. The high concentration of salt in the pore solution inside the bituminised matrix is then responsible for osmotic effects inside the bituminised matrix. The water moves in the direction of the concentrated salts, the bitumen acting as a semi-permeable membrane. This also causes the matrix to swell. The swelling pressure due to osmotic effect under constant volume can be as high as 200 bar. If not properly managed, this high pressure can cause fractures in the near field of a disposal gallery of bituminised medium-level waste. When the bituminised matrix has been altered by swelling, encapsulated radionuclides are easily leached by the contact of ground water and released in the geosphere. The high ionic strength of the concentrated saline solution also favours the migration of radionuclides in clay host rocks. The presence of chemically reactive nitrate can also affect the redox conditions prevailing in the host rock by establishing oxidizing conditions, preventing the reduction of redox-sensitive radionuclides. Under their higher valences, radionuclides of elements such as selenium, technetium, uranium, neptunium and plutonium have a higher solubility and are also often present in water as non-retarded anions. This makes the disposal of medium-level bituminised waste very challenging.
Different types of bitumen have been used: blown bitumen (partly oxidized with air oxygen at high temperature after distillation, and harder) and direct distillation bitumen (softer). Blown bitumens like Mexphalte, with a high content of saturated hydrocarbons, are more easily biodegraded by microorganisms than direct distillation bitumen, with a low content of saturated hydrocarbons and a high content of aromatic hydrocarbons.Ait-Langomazino, N., Sellier, R., Jouquet, G., & Trescinski, M. (1991). Microbial degradation of bitumen. Experientia, 47(6), 533–539.
Concrete encapsulation of radwaste is presently considered a safer alternative by the nuclear industry and the waste management organisations. |
Bitumen | Other uses | Other uses
Roofing shingles and roll roofing account for most of the remaining bitumen consumption. Other uses include cattle sprays, fence-post treatments, and waterproofing for fabrics. Bitumen is used to make Japan black, a lacquer known especially for its use on iron and steel, and it is also used in paint and marker inks by some exterior paint supply companies to increase the weather resistance and permanence of the paint or ink, and to make the color darker. Bitumen is also used to seal some alkaline batteries during the manufacturing process. Bitumen is also commonly used as a ground in the etching process of intaglio printmaking. |
Bitumen | Production | Production
thumbnail|right|Typical asphalt plant for making asphalt
About 164,000,000 tons were produced in 2019. It is obtained as the "heavy" (i.e., difficult to distill) fraction. Material with a boiling point greater than around 500°C is considered asphalt. Vacuum distillation separates it from the other components in crude oil (such as naphtha, gasoline and diesel). The resulting material is typically further treated to extract small but valuable amounts of lubricants and to adjust the properties of the material to suit applications. In a de-asphalting unit, the crude bitumen is treated with either propane or butane in a supercritical phase to extract the lighter molecules, which are then separated. Further processing is possible by "blowing" the product: namely reacting it with oxygen. This step makes the product harder and more viscous.
thumb|NYC Internet Provider, Stealth Communications, laying down asphalt over fiber-optic trench
Bitumen is typically stored and transported at temperatures around . Sometimes diesel oil or kerosene are mixed in before shipping to retain liquidity; upon delivery, these lighter materials are separated out of the mixture. This mixture is often called "bitumen feedstock", or BFS. Some dump trucks route the hot engine exhaust through pipes in the dump body to keep the material warm. The backs of tippers carrying asphalt, as well as some handling equipment, are also commonly sprayed with a releasing agent before filling to aid release. Diesel oil is no longer used as a release agent due to environmental concerns. |
Bitumen | Oil sands | Oil sands
Naturally occurring crude bitumen impregnated in sedimentary rock is the prime feed stock for petroleum production from "oil sands", currently under development in Alberta, Canada. Canada has most of the world's supply of natural bitumen, covering 140,000 square kilometres (an area larger than England), giving it the second-largest proven oil reserves in the world. The Athabasca oil sands are the largest bitumen deposit in Canada and the only one accessible to surface mining, although recent technological breakthroughs have resulted in deeper deposits becoming producible by in situ methods. Because of oil price increases after 2003, producing bitumen became highly profitable, but as a result of the decline after 2014 it became uneconomic to build new plants again. By 2014, Canadian crude bitumen production averaged about per day and was projected to rise to per day by 2020. The total amount of crude bitumen in Alberta that could be extracted is estimated to be about , which at a rate of would last about 200 years. |
Bitumen | Alternatives and bioasphalt | Alternatives and bioasphalt
Although uncompetitive economically, bitumen can be made from nonpetroleum-based renewable resources such as sugar, molasses and rice, corn and potato starches. Bitumen can also be made from waste material by fractional distillation of used motor oil, which is sometimes otherwise disposed of by burning or dumping into landfills. Use of motor oil may cause premature cracking in colder climates, resulting in roads that need to be repaved more frequently.
Nonpetroleum-based asphalt binders can be made light-colored. Lighter-colored roads absorb less heat from solar radiation, reducing their contribution to the urban heat island effect.Heat Island Effect. From the website of the US Environmental Protection Agency. Parking lots that use bitumen alternatives are called green parking lots. |
Bitumen | Albanian deposits | Albanian deposits
Selenizza is a naturally occurring solid hydrocarbon bitumen found in native deposits in Selenice, in Albania, the only European asphalt mine still in use. The bitumen is found in the form of veins, filling cracks in a more or less horizontal direction. The bitumen content varies from 83% to 92% (soluble in carbon disulphide), with a penetration value near to zero and a softening point (ring and ball) around 120°C. The insoluble matter, consisting mainly of silica ore, ranges from 8% to 17%.
Albanian bitumen extraction has a long history and was practiced in an organized way by the Romans. After centuries of silence, the first mentions of Albanian bitumen appeared only in 1868, when the Frenchman Coquand published the first geological description of the deposits of Albanian bitumen. In 1875, the exploitation rights were granted to the Ottoman government and in 1912, they were transferred to the Italian company Simsa. Since 1945, the mine was exploited by the Albanian government and from 2001 to date, the management passed to a French company, which organized the mining process for the manufacture of the natural bitumen on an industrial scale.
Today the mine is predominantly exploited in an open pit quarry but several of the many underground mines (deep and extending over several km) still remain viable. Selenizza is produced primarily in granular form, after melting the bitumen pieces selected in the mine.
Selenizza , Selenice Bitumi for more information about Selenizza is mainly used as an additive in the road construction sector. It is mixed with traditional bitumen to improve both the viscoelastic properties and the resistance to ageing. It may be blended with the hot bitumen in tanks, but its granular form allows it to be fed in the mixer or in the recycling ring of normal asphalt plants. Other typical applications include the production of mastic asphalts for sidewalks, bridges, car-parks and urban roads as well as drilling fluid additives for the oil and gas industry. Selenizza is available in powder or in granular material of various particle sizes and is packaged in sacks or in thermal fusible polyethylene bags.
A life-cycle assessment study of the natural selenizza compared with petroleum bitumen has shown that the environmental impact of the selenizza is about half the impact of the road asphalt produced in oil refineries in terms of carbon dioxide emission. |
Bitumen | Recycling | Recycling
Bitumen is a commonly recycled material in the construction industry. The two most common recycled materials that contain bitumen are reclaimed asphalt pavement (RAP) and reclaimed asphalt shingles (RAS). RAP is recycled at a greater rate than any other material in the United States, and typically contains approximately 5–6% bitumen binder. Asphalt shingles typically contain 20–40% bitumen binder.
Bitumen naturally becomes stiffer over time due to oxidation, evaporation, exudation, and physical hardening. For this reason, recycled asphalt is typically combined with virgin asphalt, softening agents, and/or rejuvenating additives to restore its physical and chemical properties. |
Bitumen | Economics | Economics
Although bitumen typically makes up only 4 to 5 percent (by weight) of the pavement mixture, as the pavement's binder, it is also the most expensive part of the cost of the road-paving material.
During bitumen's early use in modern paving, oil refiners gave it away. However, bitumen is a highly traded commodity today. Its prices increased substantially in the early 21st Century. A U.S. government report states:
"In 2002, asphalt sold for approximately $160 per ton. By the end of 2006, the cost had doubled to approximately $320 per ton, and then it almost doubled again in 2012 to approximately $610 per ton."
The report indicates that an "average" 1-mile (1.6-kilometer)-long, four-lane highway would include "300 tons of asphalt," which, "in 2002 would have cost around $48,000. By 2006 this would have increased to $96,000 and by 2012 to $183,000... an increase of about $135,000 for every mile of highway in just 10 years."
The Middle East is a significant exporter of bitumen, particularly to India and China. According to the Argus Bitumen Report (2024/07/12), India is the largest importer, driven by extensive infrastructure projects. The report projects a CAGR of 4.5% for India's bitumen imports over the next five years, while China's imports are expected to grow at a CAGR of 3.8%. The current export price to India is approximately $350 per metric ton, and for China, it is around $360 per metric ton. The Middle East's strategic advantage in crude oil production underpins its capacity to meet these demands. |
Bitumen | Health and safety | Health and safety
thumb|An asphalt mixing plant for hot aggregate
People can be exposed to bitumen in the workplace by breathing in fumes or skin absorption. The National Institute for Occupational Safety and Health (NIOSH) has set a recommended exposure limit of 5mg/m3 over a 15-minute period.
Bitumen is a largely inert material that must be heated or diluted to a point where it becomes workable for the production of materials for paving, roofing, and other applications. In examining the potential health hazards associated with bitumen, the International Agency for Research on Cancer (IARC) determined that it is the application parameters, predominantly temperature, that affect occupational exposure and the potential bioavailable carcinogenic hazard/risk of the bitumen emissions. In particular, temperatures greater than 199°C (390°F), were shown to produce a greater exposure risk than when bitumen was heated to lower temperatures, such as those typically used in asphalt pavement mix production and placement. IARC has classified paving asphalt fumes as a Class 2B possible carcinogen, indicating inadequate evidence of carcinogenicity in humans.
In 2020, scientists reported that bitumen currently is a significant and largely overlooked source of air pollution in urban areas, especially during hot and sunny periods.
A bitumen-like substance found in the Himalayas and known as shilajit is sometimes used as an Ayurveda medicine, but is not in fact a tar, resin or bitumen. |
Bitumen | See also | See also
Asphalt plant
Asphaltene
Bioasphalt
Bitumen-based fuel
Bituminous coal
Bituminous rocks
Blacktop
Cariphalte
Duxit
Macadam
Oil sands
Pitch drop experiment
Pitch (resin)
Road surface
Tar
Tarmac
Sealcoat
Stamped asphalt |
Bitumen | Notes | Notes |
Bitumen | References | References |
Bitumen | Sources | Sources
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Bitumen | External links | External links
Pavement Interactive – Asphalt
CSU Sacramento, The World Famous Asphalt Museum!
National Institute for Occupational Safety and Health – Asphalt Fumes
Scientific American, "Asphalt", 20 August 1881, pp.121
Category:Amorphous solids
Category:Building materials
Category:Chemical mixtures
Category:IARC Group 2B carcinogens
Category:Pavements
Category:Petroleum products
Category:Road construction materials |
Bitumen | Table of Content | short description, Terminology, Etymology, Modern terminology, Composition, Normal composition, Additives, mixtures and contaminants, Occurrence, History, Paleolithic times, Ancient times, Continental Europe, United Kingdom, United States, Canada, Photography and art, Modern use, Global use, Rolled asphalt concrete, Mastic asphalt, Bitumen emulsion, Synthetic crude oil, Non-upgraded crude bitumen, Radioactive waste encapsulation matrix, Other uses, Production, Oil sands, Alternatives and bioasphalt, Albanian deposits, Recycling, Economics, Health and safety, See also, Notes, References, Sources, External links |
American National Standards Institute | Short description | The American National Standards Institute (ANSI ) is a private nonprofit organization that oversees the development of voluntary consensus standards for products, services, processes, systems, and personnel in the United States. The organization also coordinates U.S. standards with international standards so that American products can be used worldwide.
ANSI accredits standards that are developed by representatives of other standards organizations, government agencies, consumer groups, companies, and others. These standards ensure that the characteristics and performance of products are consistent, that people use the same definitions and terms, and that products are tested the same way. ANSI also accredits organizations that carry out product or personnel certification in accordance with requirements defined in international standards.ANSI 2009 Annual Report
The organization's headquarters are in Washington, D.C. ANSI's operations office is located in New York City. The ANSI annual operating budget is funded by the sale of publications, membership dues and fees, accreditation services, fee-based programs, and international standards programs.
Many ANSI regulations are incorporated by reference into United States federal statutes (i.e. by OSHA regulations referring to individual ANSI specifications). ANSI does not make these standards publicly available, and charges money for access to these documents; it further claims that it is copyright infringement for them to be provided to the public by others free of charge. These assertions have been the subject of criticism and litigation. |
American National Standards Institute | History | History
ANSI was most likely formed in 1918, when five engineering societies and three government agencies founded the American Engineering Standards Committee (AESC). In 1928, the AESC became the American Standards Association (ASA). In 1966, the ASA was reorganized and became United States of America Standards Institute (USASI). The present name was adopted in 1969.
Prior to 1918, these five founding engineering societies:
American Institute of Electrical Engineers (AIEE, now IEEE)
American Society of Mechanical Engineers (ASME)
American Society of Civil Engineers (ASCE)
American Institute of Mining Engineers (AIME, now American Institute of Mining, Metallurgical, and Petroleum Engineers)
American Society for Testing and Materials (now ASTM International)
had been members of the United Engineering Society (UES). At the behest of the AIEE, they invited the U.S. government Departments of War, Navy (combined in 1947 to become the Department of Defense or DOD) and CommerceANSI history- Retrieved 2011-09-27 to join in founding a national standards organization.
According to Adam Stanton, the first permanent secretary and head of staff in 1919, AESC started as an ambitious program and little else. Staff for the first year consisted of one executive, Clifford B. LePage, who was on loan from a founding member, ASME. An annual budget of $7,500 was provided by the founding bodies.
In 1931, the organization (renamed ASA in 1928) became affiliated with the U.S. National Committee of the International Electrotechnical Commission (IEC), which had been formed in 1904 to develop electrical and electronics standards. |
American National Standards Institute | Members | Members
ANSI's members are government agencies, organizations, academic and international bodies, and individuals. In total,
the Institute represents the interests of more than 270,000 companies and organizations and 30 million professionals worldwide.
ANSI's market-driven, decentralized approach has been criticized in comparison with more planned and organized international approaches to standardization. An underlying issue is the difficulty of balancing "the interests of both the nation's industrial and commercial sectors and the nation as a whole." |
American National Standards Institute | Process | Process
Although ANSI itself does not develop standards, the Institute oversees the development and use of standards by accrediting the procedures of standards developing organizations. ANSI accreditation signifies that the procedures used by standards developing organizations meet the institute's requirements for openness, balance, consensus, and due process.
ANSI also designates specific standards as American National Standards, or ANS, when the Institute determines that the standards were developed in an environment that is equitable, accessible and responsive to the requirements of various stakeholders.
Voluntary consensus standards quicken the market acceptance of products while making clear how to improve the safety of those products for the protection of consumers. There are approximately 9,500 American National Standards that carry the ANSI designation.
The American National Standards process involves:
consensus by a group that is open to representatives from all interested parties
broad-based public review and comment on draft standards
consideration of and response to comments
incorporation of submitted changes that meet the same consensus requirements into a draft standard
availability of an appeal by any participant alleging that these principles were not respected during the standards-development process. |
American National Standards Institute | International activities | International activities
In addition to facilitating the formation of standards in the United States, ANSI promotes the use of U.S. standards internationally, advocates U.S. policy and technical positions in international and regional standards organizations, and encourages the adoption of international standards as national standards where appropriate.
The institute is the official U.S. representative to the two major international standards organizations, the International Organization for Standardization (ISO), as a founding member,ISO founding member- Retrieved 2011-09-27 and the International Electrotechnical Commission (IEC), via the U.S. National Committee (USNC). ANSI participates in almost the entire technical program of both the ISO and the IEC, and administers many key committees and subgroups. In many instances, U.S. standards are taken forward to ISO and IEC, through ANSI or the USNC, where they are adopted in whole or in part as international standards.
Adoption of ISO and IEC standards as American standards increased from 0.2% in 1986 to 15.5% in May 2012. |
American National Standards Institute | Standards panels | Standards panels
The Institute administers nine standards panels:Overview. Ansi.org. Retrieved on 2013-08-12.
ANSI Homeland Defense and Security Standardization Collaborative (HDSSC)
ANSI Nanotechnology Standards Panel (ANSI-NSP)
ID Theft Prevention and ID Management Standards Panel (IDSP)
ANSI Energy Efficiency Standardization Coordination Collaborative (EESCC)
Nuclear Energy Standards Coordination Collaborative (NESCC)
Electric Vehicles Standards Panel (EVSP)
ANSI-NAM Network on Chemical Regulation
ANSI Biofuels Standards Coordination Panel
Healthcare Information Technology Standards Panel (HITSP)
Each of the panels works to identify, coordinate, and harmonize voluntary standards relevant to these areas.
In 2009, ANSI and the National Institute of Standards and Technology (NIST) formed the Nuclear Energy Standards Coordination Collaborative (NESCC). NESCC is a joint initiative to identify and respond to the current need for standards in the nuclear industry. |
American National Standards Institute | American national standards | American national standards
The ASA (as for American Standards Association) photographic exposure system, originally defined in ASA Z38.2.1 (since 1943) and ASA PH2.5 (since 1954), together with the DIN system (DIN 4512 since 1934), became the basis for the ISO system (since 1974), currently used worldwide (ISO 6, ISO 2240, ISO 5800, ISO 12232).
A standard for the set of values used to represent characters in digital computers. The ANSI code standard extended the previously created ASCII seven bit code standard (ASA X3.4-1963), with additional codes for European alphabets (see also Extended Binary Coded Decimal Interchange Code or EBCDIC). In Microsoft Windows, the phrase "ANSI" refers to the Windows ANSI code pages (even though they are not ANSI standards). Most of these are fixed width, though some characters for ideographic languages are variable width. Since these characters are based on a draft of the ISO-8859 series, some of Microsoft's symbols are visually very similar to the ISO symbols, leading many to falsely assume that they are identical.
The first computer programming language standard was "American Standard Fortran" (informally known as "FORTRAN 66"), approved in March 1966 and published as ASA X3.9-1966.
The programming language COBOL had ANSI standards in 1968, 1974, and 1985. The COBOL 2002 standard was issued by ISO.
The original standard implementation of the C programming language was standardized as ANSI X3.159-1989, becoming the well-known ANSI C.
The X3J13 committee was created in 1986 to formalize the ongoing consolidation of Common Lisp, culminating in 1994 with the publication of ANSI's first object-oriented programming standard.
A popular Unified Thread Standard for nuts and bolts is ANSI/ASME B1.1 which was defined in 1935, 1949, 1989, and 2003.
The ANSI-NSF International standards used for commercial kitchens, such as restaurants, cafeterias, delis, etc.
The ANSI/APSP (Association of Pool & Spa Professionals) standards used for pools, spas, hot tubs, barriers, and suction entrapment avoidance.
The ANSI/HI (Hydraulic Institute) standards used for pumps.
The ANSI for eye protection is Z87.1, which gives a specific impact resistance rating to the eyewear. This standard is commonly used for shop glasses, shooting glasses, and many other examples of protective eyewear. While compliance to this standard is required by United States federal law, it is not made freely available by ANSI, who charges $65 to read a PDF of it.
The ANSI paper sizes (ANSI/ASME Y14.1). |
American National Standards Institute | See also | See also
Accredited Crane Operator Certification
ANSI ASC X9
ANSI ASC X12
ANSI C
Institute of Environmental Sciences and Technology (IEST)
Institute of Nuclear Materials Management (INMM)
ISO (to which ANSI is the official US representative)
National Information Standards Organization (NISO)
National Institute of Standards and Technology (NIST)
Open standards |
American National Standards Institute | References | References |
American National Standards Institute | External links | External links
Category:1918 establishments in the United States
Category:501(c)(3) organizations
Category:Charities based in Washington, D.C.
Category:ISO member bodies
Category:Organizations established in 1918
Category:Technical specifications
Category:Standards organizations in the United States
Category:Occupational safety and health organizations |
American National Standards Institute | Table of Content | Short description, History, Members, Process, International activities, Standards panels, American national standards, See also, References, External links |
Argument (disambiguation) | Wiktionary | In logic and philosophy, an argument is an attempt to persuade someone of something, or give evidence or reasons for accepting a particular conclusion.
Argument may also refer to: |
Argument (disambiguation) | <span class="anchor" id="Mathematics"></span>Mathematics and computer science | Mathematics and computer science
Argument (complex analysis), a function which returns the polar angle of a complex number
Command-line argument, an item of information provided to a program when it is started
Parameter (computer programming), a piece of data provided as input to a subroutine
Argument principle, a theorem in complex analysis
An argument of a function, also known as an independent variable |
Argument (disambiguation) | Language and rhetoric | Language and rhetoric
Argument (literature), a brief summary, often in prose, of a poem or section of a poem or other work
Argument (linguistics), a phrase that appears in a syntactic relationship with the verb in a clause
Oral argument in the United States, a spoken presentation to a judge or appellate court by a lawyer (or parties when representing themselves) of the legal reasons why they should prevail
Closing argument, in law, the concluding statement of each party's counsel reiterating the important arguments in a court case |
Argument (disambiguation) | Other uses | Other uses
Musical argument, a concept in the theory of musical form
Argument (ship), an Australian sloop wrecked in 1809
Das Argument, a German academic journal
Argument Clinic, a Monty Python sketch
A disagreement between two or more parties or the discussion of the disagreement
Argument (horse) |
Argument (disambiguation) | See also | See also
The Argument (disambiguation)
argumentation
|
Argument (disambiguation) | Table of Content | Wiktionary, <span class="anchor" id="Mathematics"></span>Mathematics and computer science, Language and rhetoric, Other uses, See also |
Apollo 11 | Short description | Apollo 11 was a spaceflight conducted from July 16 to 24, 1969, by the United States and launched by NASA. It marked the first time that humans landed on the Moon. Commander Neil Armstrong and Lunar Module Pilot Buzz Aldrin landed the Apollo Lunar Module Eagle on July 20, 1969, at 20:17 UTC, and Armstrong became the first person to step onto the Moon's surface six hours and 39 minutes later, on July 21 at 02:56 UTC. Aldrin joined him 19 minutes later, and they spent about two and a quarter hours together exploring the site they had named Tranquility Base upon landing. Armstrong and Aldrin collected of lunar material to bring back to Earth as pilot Michael Collins flew the Command Module Columbia in lunar orbit, and were on the Moon's surface for 21 hours, 36 minutes, before lifting off to rejoin Columbia.
Apollo 11 was launched by a Saturn V rocket from Kennedy Space Center on Merritt Island, Florida, on July 16 at 13:32 UTC. It was the fifth crewed mission of NASA's Apollo program. The Apollo spacecraft had three parts: a command module (CM) with a cabin for the three astronauts, the only part that returned to Earth; a service module (SM), which supported the command module with propulsion, electrical power, oxygen, and water; and a lunar module (LM) that had two stages—a descent stage for landing on the Moon and an ascent stage to place the astronauts back into lunar orbit.
After being sent to the Moon by the Saturn V's third stage, the astronauts separated the spacecraft from it and traveled for three days until they entered lunar orbit. Armstrong and Aldrin then moved into Eagle and landed in the Sea of Tranquility on July 20. The astronauts used Eagles ascent stage to lift off from the lunar surface and rejoin Collins in the command module. They jettisoned Eagle before they performed the maneuvers that propelled Columbia out of the last of its 30 lunar orbits onto a trajectory back to Earth. They returned to Earth and splashed down in the Pacific Ocean on July 24 after more than eight days in space.
Armstrong's first step onto the lunar surface was broadcast on live TV to a worldwide audience. He described the event as "one small step for [a] man, one giant leap for mankind." Apollo 11 effectively proved U.S. victory in the Space Race to demonstrate spaceflight superiority, by fulfilling a national goal proposed in 1961 by President John F. Kennedy, "before this decade is out, of landing a man on the Moon and returning him safely to the Earth." |
Apollo 11 | Background | Background
In the late 1950s and early 1960s, the United States was engaged in the Cold War, a geopolitical rivalry with the Soviet Union. On October 4, 1957, the Soviet Union launched Sputnik 1, the first artificial satellite. This surprise success fired fears and imaginations around the world. It demonstrated that the Soviet Union had the capability to deliver nuclear weapons over intercontinental distances, and challenged American claims of military, economic, and technological superiority. This precipitated the Sputnik crisis, and triggered the Space Race to prove which superpower would achieve superior spaceflight capability. President Dwight D. Eisenhower responded to the Sputnik challenge by creating the National Aeronautics and Space Administration (NASA), and initiating Project Mercury, which aimed to launch a man into Earth orbit. But on April 12, 1961, Soviet cosmonaut Yuri Gagarin became the first person in space, and the first to orbit the Earth. Nearly a month later, on May 5, 1961, Alan Shepard became the first American in space, completing a 15-minute suborbital journey.
Since the Soviet Union had higher lift capacity launch vehicles, Eisenhower's successor, John F. Kennedy chose, from among options presented by NASA, a challenge beyond the capacity of the existing generation of rocketry, so that the US and Soviet Union would be starting from a position of equality. A crewed mission to the Moon would serve this purpose.
On May 25, 1961, Kennedy addressed the United States Congress on "Urgent National Needs" and declared:
On September 12, 1962, Kennedy delivered another speech before a crowd of about 40,000 people in the Rice University football stadium in Houston, Texas. A widely quoted refrain from the middle portion of the speech reads as follows:
thumb|left|upright|alt=Kennedy, in a blue suit and tie, speaks at a wooden podium bearing the seal of the President of the United States. Vice President Lyndon Johnson and other dignitaries stand behind him.|President John F. Kennedy speaking at Rice University on September 12, 1962
In spite of that, the proposed program faced the opposition of many Americans and was dubbed a "moondoggle" by Norbert Wiener, a mathematician at the Massachusetts Institute of Technology. The effort to land a man on the Moon already had a name: Project Apollo. When Kennedy met with Nikita Khrushchev, the Premier of the Soviet Union in June 1961, he proposed making the Moon landing a joint project, but Khrushchev did not take up the offer. Kennedy again proposed a joint expedition to the Moon in a speech to the United Nations General Assembly on September 20, 1963. The idea of a joint Moon mission was abandoned after Kennedy's death.
An early and crucial decision was choosing lunar orbit rendezvous over both direct ascent and Earth orbit rendezvous. A space rendezvous is an orbital maneuver in which two spacecraft navigate through space and meet up. In July 1962 NASA head James Webb announced that lunar orbit rendezvous would be used and that the Apollo spacecraft would have three major parts: a command module (CM) with a cabin for the three astronauts, and the only part that returned to Earth; a service module (SM), which supported the command module with propulsion, electrical power, oxygen, and water; and a lunar module (LM) that had two stages—a descent stage for landing on the Moon, and an ascent stage to place the astronauts back into lunar orbit. This design meant the spacecraft could be launched by a single Saturn V rocket that was then under development.
Technologies and techniques required for Apollo were developed by Project Gemini. The Apollo project was enabled by NASA's adoption of new advances in semiconductor device, including metal–oxide–semiconductor field-effect transistors (MOSFETs) in the Interplanetary Monitoring Platform (IMP) and silicon integrated circuit (IC) chips in the Apollo Guidance Computer (AGC).
Project Apollo was abruptly halted by the Apollo 1 fire on January 27, 1967, in which astronauts Gus Grissom, Ed White, and Roger B. Chaffee died, and the subsequent investigation. In October 1968, Apollo 7 evaluated the command module in Earth orbit, and in December Apollo 8 tested it in lunar orbit. In March 1969, Apollo 9 put the lunar module through its paces in Earth orbit, and in May Apollo 10 conducted a "dress rehearsal" in lunar orbit. By July 1969, all was in readiness for Apollo 11 to take the final step onto the Moon.
The Soviet Union appeared to be winning the Space Race by beating the US to firsts, but its early lead was overtaken by the US Gemini program and Soviet failure to develop the N1 launcher, which would have been comparable to the Saturn V. The Soviets tried to beat the US to return lunar material to the Earth by means of uncrewed probes. On July 13, three days before Apollo 11's launch, the Soviet Union launched Luna 15, which reached lunar orbit before Apollo 11. During descent, a malfunction caused Luna 15 to crash in Mare Crisium about two hours before Armstrong and Aldrin took off from the Moon's surface to begin their voyage home. The Nuffield Radio Astronomy Laboratories radio telescope in England recorded transmissions from Luna 15 during its descent, and these were released in July 2009 for the 40th anniversary of Apollo 11. |
Apollo 11 | Personnel | Personnel |
Apollo 11 | Prime crew | Prime crew
The initial crew assignment of Commander Neil Armstrong, Command Module Pilot (CMP) Jim Lovell, and Lunar Module Pilot (LMP) Buzz Aldrin on the backup crew for Apollo 9 was officially announced on November 20, 1967. Lovell and Aldrin had previously flown together as the crew of Gemini 12. Due to design and manufacturing delays in the LM, Apollo 8 and Apollo 9 swapped prime and backup crews, and Armstrong's crew became the backup for Apollo 8. Based on the normal crew rotation scheme, Armstrong was then expected to command Apollo 11.
There would be one change. Michael Collins, the CMP on the Apollo 8 crew, began experiencing trouble with his legs. Doctors diagnosed a bony growth between his fifth and sixth vertebrae, requiring surgery. Lovell took his place on the Apollo 8 crew, and when Collins recovered he joined Armstrong's crew as CMP. In the meantime, Fred Haise filled in as backup LMP, and Aldrin as backup CMP for Apollo 8. Apollo 11 was the second American mission where all the crew members had prior spaceflight experience, the first being Apollo 10. The next was STS-26 in 1988.
Deke Slayton gave Armstrong the option to replace Aldrin with Lovell, since some thought Aldrin was difficult to work with. Armstrong had no issues working with Aldrin but thought it over for a day before declining. He thought Lovell deserved to command his own mission (eventually Apollo 13).
The Apollo 11 prime crew had none of the close cheerful camaraderie characterized by that of Apollo 12. Instead, they forged an amiable working relationship. Armstrong in particular was notoriously aloof, but Collins, who considered himself a loner, confessed to rebuffing Aldrin's attempts to create a more personal relationship. Aldrin and Collins described the crew as "amiable strangers". Armstrong did not agree with the assessment, and said "all the crews I was on worked very well together." |
Apollo 11 | Backup crew | Backup crew
The backup crew consisted of Lovell as Commander, William Anders as CMP, and Haise as LMP. Anders had flown with Lovell on Apollo 8. In early 1969, Anders accepted a job with the National Aeronautics and Space Council effective August 1969, and announced he would retire as an astronaut at that time. Ken Mattingly was moved from the support crew into parallel training with Anders as backup CMP in case Apollo 11 was delayed past its intended July launch date, at which point Anders would be unavailable.
By the normal crew rotation in place during Apollo, Lovell, Mattingly, and Haise were scheduled to fly on Apollo 14, but the three of them were bumped to Apollo 13: there was a crew issue for Apollo 13 as none of them except Edgar Mitchell flew in space again. George Mueller rejected the crew and this was the first time an Apollo crew was rejected. To give Alan Shepard more training time, Lovell's crew were bumped to Apollo 13. Mattingly would later be replaced by Jack Swigert as CMP on Apollo 13. |
Apollo 11 | Support crew | Support crew
During Projects Mercury and Gemini, each mission had a prime and a backup crew. For Apollo, a third crew of astronauts was added, known as the support crew. The support crew maintained the flight plan, checklists and mission ground rules, and ensured the prime and backup crews were apprised of changes. They developed procedures, especially those for emergency situations, so these were ready for when the prime and backup crews came to train in the simulators, allowing them to concentrate on practicing and mastering them. For Apollo 11, the support crew consisted of Ken Mattingly, Ronald Evans and Bill Pogue. |
Apollo 11 | Capsule communicators | Capsule communicators
thumb|CAPCOM Charles Duke (left), with backup crewmen Jim Lovell and Fred Haise listening in during Apollo 11's descent
The capsule communicator (CAPCOM) was an astronaut at the Mission Control Center in Houston, Texas, who was the only person who communicated directly with the flight crew. For Apollo 11, the CAPCOMs were: Charles Duke, Ronald Evans, Bruce McCandless II, James Lovell, William Anders, Ken Mattingly, Fred Haise, Don L. Lind, Owen K. Garriott and Harrison Schmitt. |
Apollo 11 | Flight directors | Flight directors
The flight directors for this mission were:
+ Apollo 11 flight directors Name Shift Team Activities Clifford E. Charlesworth 1 Green Launch and extravehicular activity (EVA) Gerald D. Griffin 1 Gold Backup for shift 1 Gene Kranz 2 White Lunar landing Glynn Lunney 3 Black Lunar ascent Milton Windler 4 Maroon Planning |
Apollo 11 | Other key personnel | Other key personnel
Other key personnel who played important roles in the Apollo 11 mission include the following.
+ Other personnel Name Activities Farouk El-Baz Geologist, studied geology of the Moon, identified landing locations, trained pilots Kurt Debus Rocket scientist, supervised construction of launch pads and infrastructure Jamye Flowers Secretary for astronauts Eleanor Foraker Tailor who designed space suits Jack Garman Computer engineer and technician Millicent Goldschmidt Microbiologist who designed aseptic lunar material collection techniques and trained astronauts Eldon C. Hall Apollo Guidance Computer hardware designer Margaret Hamilton Onboard flight computer software engineer John Houbolt Route planner Gene Shoemaker Geologist who trained astronauts in field geology Bill Tindall Coordinated mission techniques |
Apollo 11 | Preparations | Preparations |
Apollo 11 | Insignia | Insignia
thumb|Apollo 11 insignia
The Apollo 11 mission emblem was designed by Collins, who wanted a symbol for "peaceful lunar landing by the United States". At Lovell's suggestion, he chose the bald eagle, the national bird of the United States, as the symbol. Tom Wilson, a simulator instructor, suggested an olive branch in its beak to represent their peaceful mission. Collins added a lunar background with the Earth in the distance. The sunlight in the image was coming from the wrong direction; the shadow should have been in the lower part of the Earth instead of the left. Aldrin, Armstrong and Collins decided the Eagle and the Moon would be in their natural colors, and decided on a blue and gold border. Armstrong was concerned that "eleven" would not be understood by non-English speakers, so they went with "Apollo 11", and they decided not to put their names on the patch, so it would "be representative of everyone who had worked toward a lunar landing".
An illustrator at the Manned Spacecraft Center (MSC) did the artwork, which was then sent off to NASA officials for approval. The design was rejected. Bob Gilruth, the director of the MSC felt the talons of the eagle looked "too warlike". After some discussion, the olive branch was moved to the talons. When the Eisenhower dollar coin was released in 1971, the patch design provided the eagle for its reverse side. The design was also used for the smaller Susan B. Anthony dollar unveiled in 1979. |
Apollo 11 | Call signs | Call signs
thumb|Original cockpit of the command module (CM) with three seats, photographed from above. It is located in the National Air and Space Museum, the very high resolution image was produced in 2007 by the Smithsonian Institution.
After the crew of Apollo 10 named their spacecraft Charlie Brown and Snoopy, assistant manager for public affairs Julian Scheer wrote to George Low, the Manager of the Apollo Spacecraft Program Office at the MSC, to suggest the Apollo 11 crew be less flippant in naming their craft. The name Snowcone was used for the CM and Haystack was used for the LM in both internal and external communications during early mission planning.
The LM was named Eagle after the motif which was featured prominently on the mission insignia. At Scheer's suggestion, the CM was named Columbia after Columbiad, the giant cannon that launched a spacecraft (also from Florida) in Jules Verne's 1865 novel From the Earth to the Moon. It also referred to Columbia, a historical name of the United States. In Collins' 1976 book, he said Columbia was in reference to Christopher Columbus. |
Apollo 11 | Mementos | Mementos
thumb|alt=see caption|Apollo 11 space-flown silver Robbins medallion
The astronauts had personal preference kits (PPKs), small bags containing personal items of significance they wanted to take with them on the mission. Five PPKs were carried on Apollo 11: three (one for each astronaut) were stowed on Columbia before launch, and two on Eagle.
Neil Armstrong's LM PPK contained a piece of wood from the Wright brothers' 1903 Wright Flyers left propeller and a piece of fabric from its wing, along with a diamond-studded astronaut pin originally given to Slayton by the widows of the Apollo 1 crew. This pin had been intended to be flown on that mission and given to Slayton afterwards, but following the disastrous launch pad fire and subsequent funerals, the widows gave the pin to Slayton. Armstrong took it with him on Apollo 11. |
Apollo 11 | Site selection | Site selection
NASA's Apollo Site Selection Board announced five potential landing sites on February 8, 1968. These were the result of two years' worth of studies based on high-resolution photography of the lunar surface by the five uncrewed probes of the Lunar Orbiter program and information about surface conditions provided by the Surveyor program. The best Earth-bound telescopes could not resolve features with the resolution Project Apollo required. The landing site had to be close to the lunar equator to minimize the amount of propellant required, clear of obstacles to minimize maneuvering, and flat to simplify the task of the landing radar. Scientific value was not a consideration.
Areas that appeared promising on photographs taken on Earth were often found to be totally unacceptable. The original requirement that the site be free of craters had to be relaxed, as no such site was found. Five sites were considered: Sites 1 and 2 were in the Sea of Tranquility (Mare Tranquillitatis); Site 3 was in the Central Bay (); and Sites 4 and 5 were in the Ocean of Storms (Oceanus Procellarum).
The final site selection was based on seven criteria:
The site needed to be smooth, with relatively few craters;
with approach paths free of large hills, tall cliffs or deep craters that might confuse the landing radar and cause it to issue incorrect readings;
reachable with a minimum amount of propellant;
allowing for delays in the launch countdown;
providing the Apollo spacecraft with a free-return trajectory, one that would allow it to coast around the Moon and safely return to Earth without requiring any engine firings should a problem arise on the way to the Moon;
with good visibility during the landing approach, meaning the Sun would be between 7 and 20 degrees behind the LM; and
a general slope of less than two degrees in the landing area.
The requirement for the Sun angle was particularly restrictive, limiting the launch date to one day per month. A landing just after dawn was chosen to limit the temperature extremes the astronauts would experience. The Apollo Site Selection Board selected Site 2, with Sites 3 and 5 as backups in the event of the launch being delayed. In May 1969, Apollo 10's lunar module flew to within of Site 2, and reported it was acceptable. |
Apollo 11 | First-step decision | First-step decision
During the first press conference after the Apollo 11 crew was announced, the first question was, "Which one of you gentlemen will be the first man to step onto the lunar surface?" Slayton told the reporter it had not been decided, and Armstrong added that it was "not based on individual desire".
One of the first versions of the egress checklist had the lunar module pilot exit the spacecraft before the commander, which matched what had been done on Gemini missions, where the commander had never performed the spacewalk. Reporters wrote in early 1969 that Aldrin would be the first man to walk on the Moon, and Associate Administrator George Mueller told reporters he would be first as well. Aldrin heard that Armstrong would be the first because Armstrong was a civilian, which made Aldrin livid. Aldrin attempted to persuade other lunar module pilots he should be first, but they responded cynically about what they perceived as a lobbying campaign. Attempting to stem interdepartmental conflict, Slayton told Aldrin that Armstrong would be first since he was the commander. The decision was announced in a press conference on April 14, 1969.
For decades, Aldrin believed the final decision was largely driven by the lunar module's hatch location. Because the astronauts had their spacesuits on and the spacecraft was so small, maneuvering to exit the spacecraft was difficult. The crew tried a simulation in which Aldrin left the spacecraft first, but he damaged the simulator while attempting to egress. While this was enough for mission planners to make their decision, Aldrin and Armstrong were left in the dark on the decision until late spring. Slayton told Armstrong the plan was to have him leave the spacecraft first, if he agreed. Armstrong said, "Yes, that's the way to do it."
The media accused Armstrong of exercising his commander's prerogative to exit the spacecraft first. Chris Kraft revealed in his 2001 autobiography that a meeting occurred between Gilruth, Slayton, Low, and himself to make sure Aldrin would not be the first to walk on the Moon. They argued that the first person to walk on the Moon should be like Charles Lindbergh, a calm and quiet person. They made the decision to change the flight plan so the commander was the first to egress from the spacecraft. |
Apollo 11 | Pre-launch | Pre-launch
thumb|upright=1.3|left|Saturn V SA-506, the rocket carrying the Apollo 11 spacecraft, moves out of the Vehicle Assembly Building towards Launch Complex 39.
The ascent stage of LM-5 Eagle arrived at the Kennedy Space Center on January 8, 1969, followed by the descent stage four days later, and CSM-107 Columbia on January 23. There were several differences between Eagle and Apollo 10's LM-4 Snoopy; Eagle had a VHF radio antenna to facilitate communication with the astronauts during their EVA on the lunar surface; a lighter ascent engine; more thermal protection on the landing gear; and a package of scientific experiments known as the Early Apollo Scientific Experiments Package (EASEP). The only change in the configuration of the command module was the removal of some insulation from the forward hatch. The CSM was mated on January 29, and moved from the Operations and Checkout Building to the Vehicle Assembly Building on April 14.
The S-IVB third stage of Saturn V AS-506 had arrived on January 18, followed by the S-II second stage on February 6, S-IC first stage on February 20, and the Saturn V Instrument Unit on February 27. At 12:30 on May 20, the assembly departed the Vehicle Assembly Building atop the crawler-transporter, bound for Launch Pad 39A, part of Launch Complex 39, while Apollo 10 was still on its way to the Moon. A countdown test commenced on June 26, and concluded on July 2. The launch complex was floodlit on the night of July 15, when the crawler-transporter carried the mobile service structure back to its parking area. In the early hours of the morning, the fuel tanks of the S-II and S-IVB stages were filled with liquid hydrogen. Fueling was completed by three hours before launch. Launch operations were partly automated, with 43 programs written in the ATOLL programming language.
Slayton roused the crew shortly after 04:00, and they showered, shaved, and had the traditional pre-flight breakfast of steak and eggs with Slayton and the backup crew. They then donned their space suits and began breathing pure oxygen. At 06:30, they headed out to Launch Complex 39. Haise entered Columbia about three hours and ten minutes before launch time. Along with a technician, he helped Armstrong into the left-hand couch at 06:54. Five minutes later, Collins joined him, taking up his position on the right-hand couch. Finally, Aldrin entered, taking the center couch. Haise left around two hours and ten minutes before launch. The closeout crew sealed the hatch, and the cabin was purged and pressurized. The closeout crew then left the launch complex about an hour before launch time. The countdown became automated at three minutes and twenty seconds before launch time. Over 450 personnel were at the consoles in the firing room. |
Apollo 11 | Mission | Mission |
Apollo 11 | Launch and flight to lunar orbit | Launch and flight to lunar orbit
alt=|thumb|The Apollo 11 Saturn V space vehicle lifts off with astronauts Neil A. Armstrong, Michael Collins and Edwin E. Aldrin Jr. at 9:32 am. EDT July 16, 1969, from Kennedy Space Center's Launch Complex 39A.
An estimated one million spectators watched the launch of Apollo 11 from the highways and beaches in the vicinity of the launch site. Dignitaries included the Chief of Staff of the United States Army, General William Westmoreland, four cabinet members, 19 state governors, 40 mayors, 60 ambassadors and 200 congressmen. Vice President Spiro Agnew viewed the launch with former president Lyndon B. Johnson and his wife Lady Bird Johnson. Around 3,500 media representatives were present. About two-thirds were from the United States; the rest came from 55 other countries. The launch was televised live in 33 countries, with an estimated 25 million viewers in the United States alone. Millions more around the world listened to radio broadcasts. President Richard Nixon viewed the launch from his office in the White House with his NASA liaison officer, Apollo astronaut Frank Borman. Lodging near Cape Canaveral was reported as being booked months ahead in advance for the launch by a Florida newspaper.
Saturn V AS-506 launched Apollo 11 on July 16, 1969, at 13:32:00 UTC (9:32:00 EDT). At 13.2 seconds into the flight, the launch vehicle began to roll into its flight azimuth of 72.058°. Full shutdown of the first-stage engines occurred about 2 minutes and 42 seconds into the mission, followed by separation of the S-IC and ignition of the S-II engines. The second stage engines then cut off and separated at about 9 minutes and 8 seconds, allowing the first ignition of the S-IVB engine a few seconds later.
Apollo 11 entered a near-circular Earth orbit at an altitude of by , twelve minutes into its flight. After one and a half orbits, a second ignition of the S-IVB engine pushed the spacecraft onto its trajectory toward the Moon with the trans-lunar injection (TLI) burn at 16:22:13 UTC. About 30 minutes later, with Collins in the left seat and at the controls, the transposition, docking, and extraction maneuver was performed. This involved separating Columbia from the spent S-IVB stage, turning around, and docking with Eagle still attached to the stage. After the LM was extracted, the combined spacecraft headed for the Moon, while the rocket stage flew on a trajectory past the Moon. This was done to avoid the third stage colliding with the spacecraft, the Earth, or the Moon. A slingshot effect from passing around the Moon threw it into an orbit around the Sun.
On July 19 at 17:21:50 UTC, Apollo 11 passed behind the Moon and fired its service propulsion engine to enter lunar orbit. In the thirty orbits that followed, the crew saw passing views of their landing site in the southern Sea of Tranquility about southwest of the crater Sabine D. The site was selected in part because it had been characterized as relatively flat and smooth by the automated Ranger 8 and Surveyor 5 landers and the Lunar Orbiter mapping spacecraft, and because it was unlikely to present major landing or EVA challenges. It lay about southeast of the Surveyor 5 landing site, and southwest of Ranger 8's crash site. |
Apollo 11 | Lunar descent | Lunar descent
thumb|upright=1.2|left|Columbia in lunar orbit, photographed from Eagle|alt=The top of the silvery command module is seen over a grey, cratered lunar surface
At 12:52:00 UTC on July 20, Aldrin and Armstrong entered Eagle, and began the final preparations for lunar descent. At 17:44:00 Eagle separated from Columbia. Collins, alone aboard Columbia, inspected Eagle as it pirouetted before him to ensure the craft was not damaged, and that the landing gear was correctly deployed. Armstrong exclaimed: "The Eagle has wings!"
As the descent began, Armstrong and Aldrin found themselves passing landmarks on the surface two or three seconds early, and reported that they were "long"; they would land miles west of their target point. Eagle was traveling too fast. The problem could have been mascons—concentrations of high mass in a region or regions of the Moon's crust that contains a gravitational anomaly, potentially altering Eagle trajectory. Flight Director Gene Kranz speculated that it could have resulted from extra air pressure in the docking tunnel, or a result of Eagles pirouette maneuver.
Five minutes into the descent burn, and above the surface of the Moon, the LM guidance computer (LGC) distracted the crew with the first of several unexpected 1201 and 1202 program alarms. Inside Mission Control Center, computer engineer Jack Garman told Guidance Officer Steve Bales it was safe to continue the descent, and this was relayed to the crew. The program alarms indicated "executive overflows", meaning the guidance computer could not complete all its tasks in real-time and had to postpone some of them. Margaret Hamilton, the Director of Apollo Flight Computer Programming at the MIT Charles Stark Draper Laboratory later recalled:
thumb|upright=1.25|right|Eagle in lunar orbit photographed from Columbia
During the mission, the cause was diagnosed as the rendezvous radar switch being in the wrong position, causing the computer to process data from both the rendezvous and landing radars at the same time. Software engineer Don Eyles concluded in a 2005 Guidance and Control Conference paper that the problem was due to a hardware design bug previously seen during testing of the first uncrewed LM in Apollo 5. Having the rendezvous radar on (so it was warmed up in case of an emergency landing abort) should have been irrelevant to the computer, but an electrical phasing mismatch between two parts of the rendezvous radar system could cause the stationary antenna to appear to the computer as dithering back and forth between two positions, depending upon how the hardware randomly powered up. The extra spurious cycle stealing, as the rendezvous radar updated an involuntary counter, caused the computer alarms. |
Apollo 11 | Landing | Landing
thumb|Armstrong pilots Eagle to its landing on the Moon, July 20, 1969.
When Armstrong again looked outside, he saw that the computer's landing target was in a boulder-strewn area just north and east of a crater (later determined to be West crater), so he took semi-automatic control. Armstrong considered landing short of the boulder field so they could collect geological samples from it, but could not since their horizontal velocity was too high. Throughout the descent, Aldrin called out navigation data to Armstrong, who was busy piloting Eagle. Now above the surface, Armstrong knew their propellant supply was dwindling and was determined to land at the first possible landing site.
Armstrong found a clear patch of ground and maneuvered the spacecraft towards it. As he got closer, now above the surface, he discovered his new landing site had a crater in it. He cleared the crater and found another patch of level ground. They were now from the surface, with only 90 seconds of propellant remaining. Lunar dust kicked up by the LM's engine began to impair his ability to determine the spacecraft's motion. Some large rocks jutted out of the dust cloud, and Armstrong focused on them during his descent so he could determine the spacecraft's speed.
A light informed Aldrin that at least one of the probes hanging from Eagle footpads had touched the surface a few moments before the landing and he said: "Contact light!" Armstrong was supposed to immediately shut the engine down, as the engineers suspected the pressure caused by the engine's own exhaust reflecting off the lunar surface could make it explode, but he forgot. Three seconds later, Eagle landed and Armstrong shut the engine down. Aldrin immediately said "Okay, engine stop. ACA—out of detent." Armstrong acknowledged: "Out of detent. Auto." Aldrin continued: "Mode control—both auto. Descent engine command override off. Engine arm—off. 413 is in."
thumb|left|Landing site relative to West crater
ACA was the Attitude Control Assembly—the LM's control stick. Output went to the LGC to command the reaction control system (RCS) jets to fire. "Out of Detent" meant the stick had moved away from its centered position; it was spring-centered like the turn indicator in a car. Address 413 of the Abort Guidance System (AGS) contained the variable that indicated the LM had landed.
Eagle landed at 20:17:40 UTC on Sunday July 20 with of usable fuel remaining. Information available to the crew and mission controllers during the landing showed the LM had enough fuel for another 25 seconds of powered flight before an abort without touchdown would have become unsafe, but post-mission analysis showed that the real figure was probably closer to 50 seconds. Apollo 11 landed with less fuel than most subsequent missions, and the astronauts encountered a premature low fuel warning. This was later found to be the result of the propellant sloshing more than expected, uncovering a fuel sensor. On subsequent missions, extra anti-slosh baffles were added to the tanks to prevent this.
Armstrong acknowledged Aldrin's completion of the post-landing checklist with "Engine arm is off", before responding to the CAPCOM, Charles Duke, with the words, "Houston, Tranquility Base here. The Eagle has landed." Armstrong's unrehearsed change of call sign from "Eagle" to "Tranquility Base" emphasized to listeners that landing was complete and successful. Duke expressed the relief at Mission Control: "Roger, Twan—Tranquility, we copy you on the ground. You got a bunch of guys about to turn blue. We're breathing again. Thanks a lot."
thumb|3-D view from the Lunar Reconnaissance Orbiter (LRO) of Apollo 11 landing site
Two and a half hours after landing, before preparations began for the EVA, Aldrin radioed to Earth:
He then took communion privately. At this time NASA was still fighting a lawsuit brought by atheist Madalyn Murray O'Hair (who had objected to the Apollo 8 crew reading from the Book of Genesis) demanding that their astronauts refrain from broadcasting religious activities while in space. For this reason, Aldrin chose to refrain from directly mentioning taking communion on the Moon. Aldrin was an elder at the Webster Presbyterian Church, and his communion kit was prepared by the pastor of the church, Dean Woodruff. Webster Presbyterian possesses the chalice used on the Moon and commemorates the event each year on the Sunday closest to July 20. The schedule for the mission called for the astronauts to follow the landing with a five-hour sleep period, but they chose to begin preparations for the EVA early, thinking they would be unable to sleep. |
Apollo 11 | Lunar surface operations | Lunar surface operations
Preparations for Neil Armstrong and Buzz Aldrin to walk on the Moon began at 23:43 UTC. These took longer than expected; three and a half hours instead of two. During training on Earth, everything required had been neatly laid out in advance, but on the Moon the cabin contained a large number of other items as well, such as checklists, food packets, and tools. Six hours and thirty-nine minutes after landing, Armstrong and Aldrin were ready to go outside, and Eagle was depressurized.
Eagles hatch was opened at 02:39:33. Armstrong initially had some difficulties squeezing through the hatch with his portable life support system (PLSS). Some of the highest heart rates recorded from Apollo astronauts occurred during LM egress and ingress. At 02:51 Armstrong began his descent to the lunar surface. The remote control unit on his chest kept him from seeing his feet. Climbing down the nine-rung ladder, Armstrong pulled a D-ring to deploy the modular equipment stowage assembly (MESA) folded against Eagle side and activate the TV camera.
Apollo 11 used slow-scan television (TV) incompatible with broadcast TV, so it was displayed on a special monitor and a conventional TV camera viewed this monitor (thus, a broadcast of a broadcast), significantly reducing the quality of the picture. The signal was received at Goldstone in the United States, but with better fidelity by Honeysuckle Creek Tracking Station near Canberra in Australia. Minutes later the feed was switched to the more sensitive Parkes radio telescope in Australia. Despite some technical and weather difficulties, black and white images of the first lunar EVA were received and broadcast to at least 600 million people on Earth. Copies of this video in broadcast format were saved and are widely available, but recordings of the original slow scan source transmission from the lunar surface were likely destroyed during routine magnetic tape re-use at NASA.
thumb|right|Video of Neil Armstrong and the first step on the Moon
After describing the surface dust as "very fine-grained" and "almost like a powder", at 02:56:15, six and a half hours after landing, Armstrong stepped off Eagle landing pad and declared: "That's one small step for [a] man, one giant leap for mankind." Includes the "a" article as intended.
Armstrong intended to say "That's one small step for a man", but the word "a" is not audible in the transmission, and thus was not initially reported by most observers of the live broadcast. When later asked about his quote, Armstrong said he believed he said "for a man", and subsequent printed versions of the quote included the "a" in square brackets. One explanation for the absence may be that his accent caused him to slur the words "for a" together; another is the intermittent nature of the audio and video links to Earth, partly because of storms near Parkes Observatory. A more recent digital analysis of the tape claims to reveal the "a" may have been spoken but obscured by static. Other analysis points to the claims of static and slurring as "face-saving fabrication", and that Armstrong himself later admitted to misspeaking the line.
About seven minutes after stepping onto the Moon's surface, Armstrong collected a contingency soil sample using a sample bag on a stick. He then folded the bag and tucked it into a pocket on his right thigh. This was to guarantee there would be some lunar soil brought back in case an emergency required the astronauts to abandon the EVA and return to the LM. Twelve minutes after the sample was collected, he removed the TV camera from the MESA and made a panoramic sweep, then mounted it on a tripod. The TV camera cable remained partly coiled and presented a tripping hazard throughout the EVA. Still photography was accomplished with a Hasselblad camera that could be operated hand-held or mounted on Armstrong's Apollo space suit. Aldrin joined Armstrong on the surface. He described the view with the simple phrase: "Magnificent desolation."
Armstrong said moving in the lunar gravity, one-sixth of Earth's, was "even perhaps easier than the simulations ... It's absolutely no trouble to walk around." Aldrin joined him on the surface and tested methods for moving around, including two-footed kangaroo hops. The PLSS backpack created a tendency to tip backward, but neither astronaut had serious problems maintaining balance. Loping became the preferred method of movement. The astronauts reported that they needed to plan their movements six or seven steps ahead. The fine soil was quite slippery. Aldrin remarked that moving from sunlight into Eagle shadow produced no temperature change inside the suit, but the helmet was warmer in sunlight, so he felt cooler in shadow. The MESA failed to provide a stable work platform and was in shadow, slowing work somewhat. As they worked, the moonwalkers kicked up gray dust, which soiled the outer part of their suits.
thumb|left|Aldrin salutes the deployed United States flag on the lunar surface.
The astronauts planted the Lunar Flag Assembly containing a flag of the United States on the lunar surface, in clear view of the TV camera. Aldrin remembered, "Of all the jobs I had to do on the Moon the one I wanted to go the smoothest was the flag raising." But the astronauts struggled with the telescoping rod and could only insert the pole about into the hard lunar surface. Aldrin was afraid it might topple in front of TV viewers, but gave "a crisp West Point salute". Before Aldrin could take a photo of Armstrong with the flag, President Richard Nixon spoke to them through a telephone-radio transmission, which Nixon called "the most historic phone call ever made from the White House." Nixon originally had a long speech prepared to read during the phone call, but Frank Borman, who was at the White House as a NASA liaison during Apollo 11, convinced Nixon to keep his words brief.
thumb|right|Aldrin's bootprint; part of an experiment to test the properties of the lunar regolith
They deployed the EASEP, which included a Passive Seismic Experiment Package used to measure moonquakes and a retroreflector array used for the lunar laser ranging experiment. Then Armstrong walked from the LM to take photographs at the rim of Little West Crater while Aldrin collected two core samples. He used the geologist's hammer to pound in the tubes—the only time the hammer was used on Apollo 11—but was unable to penetrate more than deep. The astronauts then collected rock samples using scoops and tongs on extension handles. Many of the surface activities took longer than expected, so they had to stop documenting sample collection halfway through the allotted 34 minutes. Aldrin shoveled of soil into the box of rocks to pack them in tightly. Two types of rocks were found in the geological samples: basalt and breccia. Three new minerals were discovered in the rock samples collected by the astronauts: armalcolite, tranquillityite, and pyroxferroite. Armalcolite was named after Armstrong, Aldrin, and Collins. All have subsequently been found on Earth.
right|thumb|The plaque left on the ladder of Eagle
While on the surface, Armstrong uncovered a plaque mounted on the LM ladder, bearing two drawings of Earth (of the Western and Eastern Hemispheres), an inscription, and signatures of the astronauts and President Nixon. The inscription read:
At the behest of the Nixon administration to add a reference to God, NASA included the vague date as a reason to include A.D., which stands for Anno Domini ("in the year of our Lord").
Mission Control used a coded phrase to warn Armstrong his metabolic rates were high, and that he should slow down. He was moving rapidly from task to task as time ran out. As metabolic rates remained generally lower than expected for both astronauts throughout the walk, Mission Control granted the astronauts a 15-minute extension. In a 2010 interview, Armstrong explained that NASA limited the first moonwalk's time and distance because there was no empirical proof of how much cooling water the astronauts' PLSS backpacks would consume to handle their body heat generation while working on the Moon. |
Apollo 11 | Lunar ascent | Lunar ascent
Aldrin entered Eagle first. With some difficulty the astronauts lifted film and two sample boxes containing of lunar surface material to the LM hatch using a flat cable pulley device called the Lunar Equipment Conveyor (LEC). This proved to be an inefficient tool, and later missions preferred to carry equipment and samples up to the LM by hand. Armstrong reminded Aldrin of a bag of memorial items in his sleeve pocket, and Aldrin tossed the bag down. Armstrong then jumped onto the ladder's third rung, and climbed into the LM. After transferring to LM life support, the explorers lightened the ascent stage for the return to lunar orbit by tossing out their PLSS backpacks, lunar overshoes, an empty Hasselblad camera, and other equipment. The hatch was closed again at 05:11:13. They then pressurized the LM and settled down to sleep.
thumb|upright=1.4|left|Aldrin next to the Passive Seismic Experiment Package with the Lunar Module Eagle in the background
Presidential speech writer William Safire had prepared an In Event of Moon Disaster announcement for Nixon to read in the event the Apollo 11 astronauts were stranded on the Moon. Scanned copy of the "In Event of Moon Disaster" memo. The remarks were in a memo from Safire to Nixon's White House Chief of Staff H. R. Haldeman, in which Safire suggested a protocol the administration might follow in reaction to such a disaster. According to the plan, Mission Control would "close down communications" with the LM, and a clergyman would "commend their souls to the deepest of the deep" in a public ritual likened to burial at sea. The last line of the prepared text contained an allusion to Rupert Brooke's World War I poem "The Soldier". The script for the speech does not make reference to Collins; as he remained onboard Columbia in orbit around the Moon, it was expected that he would be able to return the module to Earth in the event of a mission failure.
While moving inside the cabin, Aldrin accidentally damaged the circuit breaker that would arm the main engine for liftoff from the Moon. There was a concern this would prevent firing the engine, stranding them on the Moon. The nonconductive tip of a Duro felt-tip pen was sufficient to activate the switch.
After more than hours on the lunar surface, in addition to the scientific instruments, the astronauts left behind: an Apollo 1 mission patch in memory of astronauts Roger Chaffee, Gus Grissom, and Edward White, who died when their command module caught fire during a test in January 1967; two memorial medals of Soviet cosmonauts Vladimir Komarov and Yuri Gagarin, who died in 1967 and 1968 respectively; a memorial bag containing a gold replica of an olive branch as a traditional symbol of peace; and a silicon message disk carrying the goodwill statements by presidents Eisenhower, Kennedy, Johnson, and Nixon along with messages from leaders of 73 countries around the world. The disk also carries a listing of the leadership of the US Congress, a listing of members of the four committees of the House and Senate responsible for the NASA legislation, and the names of NASA's past and then-current top management.
thumb|upright=1.3|right|Map showing landing site and photos taken
After about seven hours of rest, the crew was awakened by Houston to prepare for the return flight.
At that time, unknown to them, some hundred kilometers away from them the Soviet probe Luna 15 was about to descend and impact. Despite having been known to be orbiting the Moon at the same time, through a ground-breaking precautious goodwill exchange of data, the mission control of Luna 15 unexpectedly hastened its robotic sample-return mission, initiating descent, in an attempt to return before Apollo 11. Just two hours before Apollo 11's launch Luna 15 crashed at 15:50 UTC, with British astronomers monitoring Luna 15 and recording the situation one commented: "I say, this has really been drama of the highest order", bringing the Space Race to a culmination.
Roughly two hours later, at 17:54:00 UTC, the Apollo 11 crew on the surface safely lifted off in Eagle ascent stage to rejoin Collins aboard Columbia in lunar orbit. Film taken from the LM ascent stage upon liftoff from the Moon reveals the American flag, planted some from the descent stage, whipping violently in the exhaust of the ascent stage engine. Aldrin looked up in time to witness the flag topple: "The ascent stage of the LM separated ... I was concentrating on the computers, and Neil was studying the attitude indicator, but I looked up long enough to see the flag fall over." Subsequent Apollo missions planted their flags farther from the LM. |
Apollo 11 | ''Columbia'' in lunar orbit | Columbia in lunar orbit
During his day flying solo around the Moon, Collins never felt lonely. Although it has been said "not since Adam has any human known such solitude", Collins felt very much a part of the mission. In his autobiography he wrote: "this venture has been structured for three men, and I consider my third to be as necessary as either of the other two". In the 48 minutes of each orbit when he was out of radio contact with the Earth while Columbia passed round the far side of the Moon, the feeling he reported was not fear or loneliness, but rather "awareness, anticipation, satisfaction, confidence, almost exultation".
One of Collins' first tasks was to identify the lunar module on the ground. To give Collins an idea where to look, Mission Control radioed that they believed the lunar module landed about off target. Each time he passed over the suspected lunar landing site, he tried in vain to find the module. On his first orbits on the back side of the Moon, Collins performed maintenance activities such as dumping excess water produced by the fuel cells and preparing the cabin for Armstrong and Aldrin to return.
Just before he reached the dark side on the third orbit, Mission Control informed Collins there was a problem with the temperature of the coolant. If it became too cold, parts of Columbia might freeze. Mission Control advised him to assume manual control and implement Environmental Control System Malfunction Procedure 17. Instead, Collins flicked the switch on the system from automatic to manual and back to automatic again, and carried on with normal housekeeping chores, while keeping an eye on the temperature. When Columbia came back around to the near side of the Moon again, he was able to report that the problem had been resolved. For the next couple of orbits, he described his time on the back side of the Moon as "relaxing". After Aldrin and Armstrong completed their EVA, Collins slept so he could be rested for the rendezvous. While the flight plan called for Eagle to meet up with Columbia, Collins was prepared for a contingency in which he would fly Columbia down to meet Eagle. |
Apollo 11 | Return | Return
thumb|Eagle ascent stage approaching Columbia
Eagle rendezvoused with Columbia at 21:24 UTC on July 21, and the two docked at 21:35. Eagles ascent stage was jettisoned into lunar orbit at 23:41. Just before the Apollo 12 flight, it was noted that Eagle was still likely to be orbiting the Moon. Later NASA reports mentioned that Eagle orbit had decayed, resulting in it impacting in an "uncertain location" on the lunar surface. In 2021, however, some calculations show that the lander may still be in orbit.
On July 23, the last night before splashdown, the three astronauts made a television broadcast in which Collins commented: "All this is possible only through the blood, sweat, and tears of a number of people ... All you see is the three of us, but beneath the surface are thousands and thousands of others, and to all of those, I would like to say, 'Thank you very much'." Aldrin added: "This has been far more than three men on a mission to the Moon; more, still, than the efforts of a government and industry team; more, even, than the efforts of one nation. We feel that this stands as a symbol of the insatiable curiosity of all mankind to explore the unknown ..."
Armstrong concluded:
On the return to Earth, a bearing at the Guam tracking station failed, potentially preventing communication on the last segment of the Earth return. A regular repair was not possible in the available time but the station director, Charles Force, had his ten-year-old son Greg use his small hands to reach into the housing and pack it with grease. Greg was later thanked by Armstrong. |
Apollo 11 | Splashdown and quarantine | Splashdown and quarantine
thumb|Columbia floats on the ocean as Navy divers assist in retrieving the astronauts.
The aircraft carrier , under the command of Captain Carl J. Seiberlich, was selected as the primary recovery ship (PRS) for Apollo 11 on June 5, replacing its sister ship, the LPH , which had recovered Apollo 10 on May 26. Hornet was then at her home port of Long Beach, California. On reaching Pearl Harbor on July 5, Hornet embarked the Sikorsky SH-3 Sea King helicopters of HS-4, a unit which specialized in recovery of Apollo spacecraft, specialized divers of UDT Detachment Apollo, a 35-man NASA recovery team, and about 120 media representatives. To make room, most of Hornets air wing was left behind in Long Beach. Special recovery equipment was also loaded, including a boilerplate command module used for training.
On July 12, with Apollo 11 still on the launch pad, Hornet departed Pearl Harbor for the recovery area in the central Pacific, in the vicinity of . A presidential party consisting of Nixon, Borman, Secretary of State William P. Rogers and National Security Advisor Henry Kissinger flew to Johnston Atoll on Air Force One, then to the command ship USS Arlington in Marine One. After a night on board, they would fly to Hornet in Marine One for a few hours of ceremonies. On arrival aboard Hornet, the party was greeted by the Commander-in-Chief, Pacific Command (CINCPAC), Admiral John S. McCain Jr., and NASA Administrator Thomas O. Paine, who flew to Hornet from Pago Pago in one of Hornets carrier onboard delivery aircraft.
Weather satellites were not yet common, but US Air Force Captain Hank Brandli had access to top-secret spy satellite images. He realized that a storm front was headed for the Apollo recovery area. Poor visibility which could make locating the capsule difficult, and strong upper-level winds which "would have ripped their parachutes to shreds" according to Brandli, posed a serious threat to the safety of the mission. Brandli alerted Navy Captain Willard S. Houston Jr., the commander of the Fleet Weather Center at Pearl Harbor, who had the required security clearance. On their recommendation, Rear Admiral Donald C. Davis, commander of Manned Spaceflight Recovery Forces, Pacific, advised NASA to change the recovery area, each man risking his career. A new location was selected northeast.
This altered the flight plan. A different sequence of computer programs was used, one never before attempted. In a conventional entry, trajectory event P64 was followed by P67. For a skip-out re-entry, P65 and P66 were employed to handle the exit and entry parts of the skip. In this case, because they were extending the re-entry but not actually skipping out, P66 was not invoked and instead, P65 led directly to P67. The crew were also warned they would not be in a full-lift (heads-down) attitude when they entered P67. The first program's acceleration subjected the astronauts to ; the second, to .
Before dawn on July 24, Hornet launched four Sea King helicopters and three Grumman E-1 Tracers. Two of the E-1s were designated as "air boss" while the third acted as a communications relay aircraft. Two of the Sea Kings carried divers and recovery equipment. The third carried photographic equipment, and the fourth carried the decontamination swimmer and the flight surgeon. At 16:44 UTC (05:44 local time) Columbias drogue parachutes were deployed. This was observed by the helicopters. Seven minutes later Columbia struck the water forcefully east of Wake Island, south of Johnston Atoll, and from Hornet, at . with seas and winds at from the east were reported under broken clouds at with visibility of at the recovery site. Reconnaissance aircraft flying to the original splashdown location reported the conditions Brandli and Houston had predicted.
During splashdown, Columbia landed upside down but was righted within ten minutes by flotation bags activated by the astronauts. A diver from the Navy helicopter hovering above attached a sea anchor to prevent it from drifting. More divers attached flotation collars to stabilize the module and positioned rafts for astronaut extraction.
The divers then passed biological isolation garments (BIGs) to the astronauts, and assisted them into the life raft. The possibility of bringing back pathogens from the lunar surface was considered remote, but NASA took precautions at the recovery site. The astronauts were rubbed down with a sodium hypochlorite solution and Columbia wiped with Povidone-iodine to remove any lunar dust that might be present. The astronauts were winched on board the recovery helicopter. BIGs were worn until they reached isolation facilities on board Hornet. The raft containing decontamination materials was intentionally sunk.
After touchdown on Hornet at 17:53 UTC, the helicopter was lowered by the elevator into the hangar bay, where the astronauts walked the to the mobile quarantine facility (MQF), where they would begin the Earth-based portion of their 21 days of quarantine. This practice would continue for two more Apollo missions, Apollo 12 and Apollo 14, before the Moon was proven to be barren of life, and the quarantine process dropped. Nixon welcomed the astronauts back to Earth. He told them: "[A]s a result of what you've done, the world has never been closer together before."
After Nixon departed, Hornet was brought alongside the Columbia, which was lifted aboard by the ship's crane, placed on a dolly and moved next to the MQF. It was then attached to the MQF with a flexible tunnel, allowing the lunar samples, film, data tapes and other items to be removed. Hornet returned to Pearl Harbor, where the MQF was loaded onto a Lockheed C-141 Starlifter and airlifted to the Manned Spacecraft Center. The astronauts arrived at the Lunar Receiving Laboratory at 10:00 UTC on July 28. Columbia was taken to Ford Island for deactivation, and its pyrotechnics made safe. It was then taken to Hickham Air Force Base, from whence it was flown to Houston in a Douglas C-133 Cargomaster, reaching the Lunar Receiving Laboratory on July 30.
In accordance with the Extra-Terrestrial Exposure Law, a set of regulations promulgated by NASA on July 16 to codify its quarantine protocol,Extra-Terrestrial Exposure, 34 Federal Register 11975 (July 16, 1969), codified at Federal Aviation Regulation pt. 1200 the astronauts continued in quarantine. After three weeks in confinement (first in the Apollo spacecraft, then in their trailer on Hornet, and finally in the Lunar Receiving Laboratory), the astronauts were given a clean bill of health. On August 10, 1969, the Interagency Committee on Back Contamination met in Atlanta and lifted the quarantine on the astronauts, on those who had joined them in quarantine (NASA physician William Carpentier and MQF project engineer John Hirasaki), and on Columbia itself. Loose equipment from the spacecraft remained in isolation until the lunar samples were released for study. |
Apollo 11 | Celebrations | Celebrations
thumb|Ticker tape parade in New York City
On August 13, the three astronauts rode in ticker-tape parades in their honor in New York and Chicago, with an estimated six million attendees. On the same evening in Los Angeles there was an official state dinner to celebrate the flight, attended by members of Congress, 44 governors, Chief Justice of the United States Warren E. Burger and his predecessor, Earl Warren, and ambassadors from 83 nations at the Century Plaza Hotel. Nixon and Agnew honored each astronaut with a presentation of the Presidential Medal of Freedom.
The three astronauts spoke before a joint session of Congress on September 16, 1969. They presented two US flags, one to the House of Representatives and the other to the Senate, that they had carried with them to the surface of the Moon. The flag of American Samoa on Apollo 11 is on display at the Jean P. Haydon Museum in Pago Pago, the capital of American Samoa.
This celebration began a 38-day world tour that brought the astronauts to 22 countries and included visits with many world leaders. The crew toured from September 29 to November 5. The world tour started in Mexico City and ended in Tokyo. Stops on the tour in order were: Mexico City, Bogota, Buenos Aires, Rio de Janeiro, Las Palmas in the Canary Islands, Madrid, Paris, Amsterdam, Brussels, Oslo, Cologne, Berlin, London, Rome, Belgrade, Ankara, Kinshasa, Tehran, Mumbai, Dhaka, Bangkok, Darwin, Sydney, Guam, Seoul, Tokyo and Honolulu.
Many nations honored the first human Moon landing with special features in magazines or by issuing Apollo 11 commemorative postage stamps or coins. |
Apollo 11 | Legacy | Legacy |
Apollo 11 | Cultural significance | Cultural significance
thumb|A girl holding The Washington Post newspaper stating "'The Eagle Has Landed' – Two Men Walk on the Moon"
Humans walking on the Moon and returning safely to Earth accomplished Kennedy's goal set eight years earlier. In Mission Control during the Apollo 11 landing, Kennedy's speech flashed on the screen, followed by the words "TASK ACCOMPLISHED, July 1969". The success of Apollo 11 demonstrated the United States' technological superiority; and with the success of Apollo 11, America had won the Space Race.
New phrases permeated into the English language. "If they can send a man to the Moon, why can't they ...?" became a common saying following Apollo 11. Armstrong's words on the lunar surface also spun off various parodies.
While most people celebrated the accomplishment, disenfranchised Americans saw it as a symbol of the divide in America, evidenced by protesters led by Ralph Abernathy outside of Kennedy Space Center the day before Apollo 11 launched. NASA Administrator Thomas Paine met with Abernathy at the occasion, both hoping that the space program can spur progress also in other regards, such as poverty in the US. Paine was then asked, and agreed, to host protesters as spectators at the launch, and Abernathy, awestruck by the spectacle, prayed for the astronauts. Racial and financial inequalities frustrated citizens who wondered why money spent on the Apollo program was not spent taking care of humans on Earth. A poem by Gil Scott-Heron called "Whitey on the Moon" (1970) illustrated the racial inequality in the United States that was highlighted by the Space Race. The poem starts with:
Twenty percent of the world's population watched humans walk on the Moon for the first time. While Apollo 11 sparked the interest of the world, the follow-on Apollo missions did not hold the interest of the nation. One possible explanation was the shift in complexity. Landing someone on the Moon was an easy goal to understand; lunar geology was too abstract for the average person. Another is that Kennedy's goal of landing humans on the Moon had already been accomplished. A well-defined objective helped Project Apollo accomplish its goal, but after it was completed it was hard to justify continuing the lunar missions.
While most Americans were proud of their nation's achievements in space exploration, only once during the late 1960s did the Gallup Poll indicate that a majority of Americans favored "doing more" in space as opposed to "doing less". By 1973, 59 percent of those polled favored cutting spending on space exploration. The Space Race had been won, and Cold War tensions were easing as the US and Soviet Union entered the era of détente. This was also a time when inflation was rising, which put pressure on the government to reduce spending. What saved the space program was that it was one of the few government programs that had achieved something great. Drastic cuts, warned Caspar Weinberger, the deputy director of the Office of Management and Budget, might send a signal that "our best years are behind us".
After the Apollo 11 mission, officials from the Soviet Union said landing humans on the Moon was dangerous and unnecessary. At the time the Soviet Union was attempting to retrieve lunar samples robotically. The Soviets publicly denied there was a race to the Moon, and indicated they were not making an attempt. Mstislav Keldysh said in July 1969, "We are concentrating wholly on the creation of large satellite systems." It was revealed in 1989 that the Soviets had tried to send people to the Moon, but were unable due to technological difficulties. The public's reaction in the Soviet Union was mixed. The Soviet government limited the release of information about the lunar landing, which affected the reaction. A portion of the populace did not give it any attention, and another portion was angered by it.
The Apollo 11 landing is referenced in the songs "Armstrong, Aldrin and Collins" by the Byrds on the 1969 album Ballad of Easy Rider, "Coon on the Moon" by Howlin' Wolf on the 1973 album The Back Door Wolf, and "One Small Step" by Ayreon on the 2000 album Universal Migrator Part 1: The Dream Sequencer. |
Apollo 11 | Spacecraft | Spacecraft
thumb|left|Columbia on display in the Milestones of Flight exhibition hall at the National Air and Space Museum
The command module Columbia went on a tour of the United States, visiting 49 state capitals, the District of Columbia, and Anchorage, Alaska. In 1971, it was transferred to the Smithsonian Institution, and was displayed at the National Air and Space Museum (NASM) in Washington, DC. It was in the central Milestones of Flight exhibition hall in front of the Jefferson Drive entrance, sharing the main hall with other pioneering flight vehicles such as the Wright Flyer, Spirit of St. Louis, Bell X-1, North American X-15 and Friendship 7.
Columbia was moved in 2017 to the NASM Mary Baker Engen Restoration Hangar at the Steven F. Udvar-Hazy Center in Chantilly, Virginia, to be readied for a four-city tour titled Destination Moon: The Apollo 11 Mission. This included Space Center Houston from October 14, 2017, to March 18, 2018, the Saint Louis Science Center from April 14 to September 3, 2018, the Senator John Heinz History Center in Pittsburgh from September 29, 2018, to February 18, 2019, and its last location at Museum of Flight in Seattle from March 16 to September 2, 2019. Continued renovations at the Smithsonian allowed time for an additional stop for the capsule, and it was moved to the Cincinnati Museum Center. The ribbon cutting ceremony was on September 29, 2019.
For 40 years Armstrong's and Aldrin's space suits were displayed in the museum's Apollo to the Moon exhibit, until it permanently closed on December 3, 2018, to be replaced by a new gallery which was scheduled to open in 2022. A special display of Armstrong's suit was unveiled for the 50th anniversary of Apollo 11 in July 2019. The quarantine trailer, the flotation collar and the flotation bags are in the Smithsonian's Steven F. Udvar-Hazy Center annex near Washington Dulles International Airport in Chantilly, Virginia, where they are on display along with a test lunar module.
left|thumb|Armstrong's space suit on display at the National Air and Space Museum in its new exhibit
The descent stage of the LM Eagle remains on the Moon. In 2009, the Lunar Reconnaissance Orbiter (LRO) imaged the various Apollo landing sites on the surface of the Moon, for the first time with sufficient resolution to see the descent stages of the lunar modules, scientific instruments, and foot trails made by the astronauts.
The remains of the ascent stage are assumed to lie at an unknown location on the lunar surface. The ascent stage, Eagle, was not tracked after it was jettisoned. The lunar gravity field is sufficiently non-uniform to make low Moon orbits unstable after a short time, leading the orbiting object to impact the surface. However, using a program developed by NASA, and high-resolution lunar gravity data, a paper was published, in 2021, indicating that Eagle might still be in orbit as late as 2020. Using the orbital elements published by NASA, a Monte Carlo method was used to generate parameter sets that bracket the uncertainties in these elements. All simulations, of the orbit, predicted that Eagle would never impact the lunar surface.
In March 2012 a team of specialists financed by Amazon founder Jeff Bezos located the F-1 engines from the S-IC stage that launched Apollo 11 into space. They were found on the Atlantic seabed using advanced sonar scanning. His team brought parts of two of the five engines to the surface. In July 2013, a conservator discovered a serial number under the rust on one of the engines raised from the Atlantic, which NASA confirmed was from Apollo 11. The S-IVB third stage which performed Apollo 11's trans-lunar injection remains in a solar orbit near to that of Earth.
thumb|Pieces of fabric and wood from the first airplane, the 1903 Wright Flyer, traveled to the Moon in Apollo 11's Lunar Module Eagle and are displayed at the Wright Brothers National Memorial. |
Apollo 11 | Moon rocks | Moon rocks
The main repository for the Apollo Moon rocks is the Lunar Sample Laboratory Facility at the Lyndon B. Johnson Space Center in Houston, Texas. For safekeeping, there is also a smaller collection stored at White Sands Test Facility near Las Cruces, New Mexico. Most of the rocks are stored in nitrogen to keep them free of moisture. They are handled only indirectly, using special tools. Over 100 research laboratories worldwide conduct studies of the samples; approximately 500 samples are prepared and sent to investigators every year.
In November 1969, Nixon asked NASA to make up about 250 presentation Apollo 11 lunar sample displays for 135 nations, the fifty states of the United States and its possessions, and the United Nations. Each display included Moon dust from Apollo 11 and flags, including one of the Soviet Union, taken along by Apollo 11. The rice-sized particles were four small pieces of Moon soil weighing about 50 mg and were enveloped in a clear acrylic button about as big as a United States half-dollar coin. This acrylic button magnified the grains of lunar dust. Nixon gave the Apollo 11 lunar sample displays as goodwill gifts in 1970.Earth magazine, March 2011, pp. 42–51 |
Apollo 11 | Experiment results | Experiment results
The Passive Seismic Experiment ran until the command uplink failed on August 25, 1969. The downlink failed on December 14, 1969. , the Lunar Laser Ranging experiment remains operational. |
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