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msmarco_v2.1_doc_00_5822843#1_8475722
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
Dimensions are 21″ x 14″ x 8″ and the weight is 4.4 lbs……or 3.5 lbs. ( More on this later). It’s made of a combination of 840d and 900d twisted polyester. The volume, according to eBags, is 1948 cu in/31.9 cu liters. Like most bags in this line, this one is not lacking in details. The front compartment of the bag has a “Napolean” type zipper pocket for boarding passes, magazines, etc. Behind it is an organizer pocket. There is an additional smaller pocket with a free-floating divider at the side/bottom of the bag. This type of pocket is found on all TLS bags. It is large enough to hold a 3-1-1 bag.
547
1,152
msmarco_v2.1_doc_00_5822843#2_8476757
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
The front compartment of the bag has a “Napolean” type zipper pocket for boarding passes, magazines, etc. Behind it is an organizer pocket. There is an additional smaller pocket with a free-floating divider at the side/bottom of the bag. This type of pocket is found on all TLS bags. It is large enough to hold a 3-1-1 bag. The rear of the bag has a trolley handle pass through with a mesh back panel. However, the orientation of this one is vertical, like seen in the photo to the left. It might actually be longer than the handles of some wheeled bags. Not sure why they did it this way. There are also padded, hideaway backpack straps with a sternum strap.
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1,488
msmarco_v2.1_doc_00_5822843#3_8477816
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
The rear of the bag has a trolley handle pass through with a mesh back panel. However, the orientation of this one is vertical, like seen in the photo to the left. It might actually be longer than the handles of some wheeled bags. Not sure why they did it this way. There are also padded, hideaway backpack straps with a sternum strap. They feel as comfortable as the other bags I have in this line. At the bottom of the rear of the bag is another compartment holding a removable, hard-shell, adapter/cord storage compartment. This container is what adds the extra weight to the bag. With it removed, the bag is about 10 ounces lighter. ( Thus the difference between 4.4 lbs and 3.5 lbs.–approximately.)
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msmarco_v2.1_doc_00_5822843#4_8478915
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
They feel as comfortable as the other bags I have in this line. At the bottom of the rear of the bag is another compartment holding a removable, hard-shell, adapter/cord storage compartment. This container is what adds the extra weight to the bag. With it removed, the bag is about 10 ounces lighter. ( Thus the difference between 4.4 lbs and 3.5 lbs.–approximately.) However, with in inserted and zipped closed, it adds a bit of lumbar support when wearing the bag on your back. The bag has a clamshell style opening and contains two zippered, internal compartments. The front side has a tablet sleeve as well as room for clothes. ( The tablet sleeve is also accessible through a zippered opening at the top of the bag) The rear side has an L-shaped zippered opening and a neoprene laptop sleeve. It can hold laptops up to 18″ x 14″ x 2″. The bag, and eBags, states that this compartment is checkpoint friendly so you don’t have to remove your laptop from the bag.
1,489
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msmarco_v2.1_doc_00_5822843#5_8480297
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
However, with in inserted and zipped closed, it adds a bit of lumbar support when wearing the bag on your back. The bag has a clamshell style opening and contains two zippered, internal compartments. The front side has a tablet sleeve as well as room for clothes. ( The tablet sleeve is also accessible through a zippered opening at the top of the bag) The rear side has an L-shaped zippered opening and a neoprene laptop sleeve. It can hold laptops up to 18″ x 14″ x 2″. The bag, and eBags, states that this compartment is checkpoint friendly so you don’t have to remove your laptop from the bag. However, that padded rear compartment mentioned earlier is at the bottom of this side and I always thought that nothing else could be with your laptop to make it checkpoint friendly. There are both top and side grab handles. They are flush with the bag thanks to elastic on either end of the handles. Zippers are YKK, lockable and most can be attached to small “d” rings placed throughout the bag. This makes it impossible to move the zippers.
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2,896
msmarco_v2.1_doc_00_5822843#6_8481760
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
However, that padded rear compartment mentioned earlier is at the bottom of this side and I always thought that nothing else could be with your laptop to make it checkpoint friendly. There are both top and side grab handles. They are flush with the bag thanks to elastic on either end of the handles. Zippers are YKK, lockable and most can be attached to small “d” rings placed throughout the bag. This makes it impossible to move the zippers. There’s even a side mounted water bottle pocket. ( Although it is fairly small.) As with all eBags bags, the lining is orange throughout which makes findings things easier. A shoulder strap is included. I told you this was a detailed, oriented bag.
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msmarco_v2.1_doc_00_5822843#7_8482858
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
There’s even a side mounted water bottle pocket. ( Although it is fairly small.) As with all eBags bags, the lining is orange throughout which makes findings things easier. A shoulder strap is included. I told you this was a detailed, oriented bag. The bag lives up to its claims. It looks good, is extremely functional, and comes at a reasonable price. On the down side, the bag is heavy. Very heavy when compared to other convertible bags. My suggestion, if you can, is to remove the small container at the rear of the bag to lighten the load.
2,896
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msmarco_v2.1_doc_00_5822843#8_8483799
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
The bag lives up to its claims. It looks good, is extremely functional, and comes at a reasonable price. On the down side, the bag is heavy. Very heavy when compared to other convertible bags. My suggestion, if you can, is to remove the small container at the rear of the bag to lighten the load. Unless you are carrying something ultra-fragile, I don’t think it’s needed. YMMV. The other negative is if you take this bag along with a wheeled suitcase. As mentioned earlier, the orientation of the pass through sleeve makes the bag, in some cases, longer than the handles on those wheeled bags. If you’re a leisure traveler who doesn’t have to carry a heavy load, my suggestion is to stick with the other products in the eBags TLS line.
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msmarco_v2.1_doc_00_5822843#9_8484946
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
Unless you are carrying something ultra-fragile, I don’t think it’s needed. YMMV. The other negative is if you take this bag along with a wheeled suitcase. As mentioned earlier, the orientation of the pass through sleeve makes the bag, in some cases, longer than the handles on those wheeled bags. If you’re a leisure traveler who doesn’t have to carry a heavy load, my suggestion is to stick with the other products in the eBags TLS line. As most of you know, I’m a lousy photographer. If you want better photos, go to the eBags website for this product. The eBags TLS Professional Weekender is only available in black. $149 (Subscribe to their daily emails and you should be able to get a the bag at a lower price.) eBags supplied the bag for review.
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msmarco_v2.1_doc_00_5822843#10_8486114
http://1bag1world.com/2014/09/gear-review-ebags-tls-professional-weekender/
Gear Review: eBags TLS Professional Weekender - One Bag, One World
Gear Review: eBags TLS Professional Weekender Gear Review: eBags TLS Professional Weekender Like this:
As most of you know, I’m a lousy photographer. If you want better photos, go to the eBags website for this product. The eBags TLS Professional Weekender is only available in black. $149 (Subscribe to their daily emails and you should be able to get a the bag at a lower price.) eBags supplied the bag for review. This, however, had no influence on the review itself. Like this: Like Loading... ← Size Matters Travel Adapter Map →
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msmarco_v2.1_doc_00_5827642#0_8486953
http://1bag1world.com/obow-tutorials/personal-item/
The Personal Item - One Bag, One World
The Personal Item The Personal Item
The Personal Item - One Bag, One World The Personal Item Quite often I get asked about “the personal item,” the smaller carry-on bag that most airlines allow passengers to take on board to keep under the seat in front of them. And the question asked is always the same: Why don’t you allow people to carry personal items? My response is always the same: Who says I don’t? I carry a personal item. It’s usually a smaller bag that does double duty. When traveling, it has in it everything I need during the flight, train or bus trip while my main carry-on bag is in the overhead compartment. When at my destination, it becomes as my day bag. The only difference I suggest is when traveling, place the “personal item” INSIDE your carry-on bag and take it out at your seat.
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msmarco_v2.1_doc_00_5827642#1_8488024
http://1bag1world.com/obow-tutorials/personal-item/
The Personal Item - One Bag, One World
The Personal Item The Personal Item
I carry a personal item. It’s usually a smaller bag that does double duty. When traveling, it has in it everything I need during the flight, train or bus trip while my main carry-on bag is in the overhead compartment. When at my destination, it becomes as my day bag. The only difference I suggest is when traveling, place the “personal item” INSIDE your carry-on bag and take it out at your seat. This way you only have ONE BAG to worry about at all other times. I make note of this in section 7 of “Core Principles of One Bag Travel:” 7) Everything you eventually take with you must fit in one, wheel-less*, carry on bag measuring no more than standard carry-on dimensions: 22″ x 14″ x 9″/56cm x 35cm x 22cm. ( This will vary depending on the airline you are flying.)
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msmarco_v2.1_doc_00_5827642#2_8489101
http://1bag1world.com/obow-tutorials/personal-item/
The Personal Item - One Bag, One World
The Personal Item The Personal Item
This way you only have ONE BAG to worry about at all other times. I make note of this in section 7 of “Core Principles of One Bag Travel:” 7) Everything you eventually take with you must fit in one, wheel-less*, carry on bag measuring no more than standard carry-on dimensions: 22″ x 14″ x 9″/56cm x 35cm x 22cm. ( This will vary depending on the airline you are flying.) The use of a second, smaller, personal item is optional. ( Gold stars to those who can put their personal item inside their carry-on.) I hope this clears up any confusion for those who thought I meant no second bag at all was allowed and everything had to be kept loose in their one bag.
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msmarco_v2.1_doc_00_5829357#0_8490053
http://1bagatatime.com/learn/plastic-bags-oceans/
Plastic Bags in Our Oceans | 1 Bag at a Time
Plastic Bags in Our Oceans Plastic Bags in Our Oceans Plastic bags in our oceans are a source of dioxin and other pollutants that are changing marine habitats and polluting our food chain.
Plastic Bags in Our Oceans | 1 Bag at a Time Plastic Bags in Our Oceans Plastic bags in our oceans are a source of dioxin and other pollutants that are changing marine habitats and polluting our food chain. No matter how much we try to keep our cities clean, many plastic bags end up as litter. If your city is like mine, Los Angeles, you see them on the streets every day. Some are cleaned up at public expense, but most get washed into the gutter and into our waterways. There, they break up into tiny pieces as they make their way to the oceans. Plastic from cities around the world is accumulating at an alarming rate. In 2004, researchers found 6 pounds of plastic for every pound of plankton in the North Pacific Gyre. In 2008, researchers from Algalita Marine Research Institute found 42 pounds of plastic for every pound of plankton. That’s 8 times more plastic in just 4 years. A recent study by the Ellen MacArthur Foundation and the World Economic Forum claims that the equivalent of one dump truck full of plastic enters the ocean every minute.
0
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msmarco_v2.1_doc_00_5829357#1_8491542
http://1bagatatime.com/learn/plastic-bags-oceans/
Plastic Bags in Our Oceans | 1 Bag at a Time
Plastic Bags in Our Oceans Plastic Bags in Our Oceans Plastic bags in our oceans are a source of dioxin and other pollutants that are changing marine habitats and polluting our food chain.
Plastic from cities around the world is accumulating at an alarming rate. In 2004, researchers found 6 pounds of plastic for every pound of plankton in the North Pacific Gyre. In 2008, researchers from Algalita Marine Research Institute found 42 pounds of plastic for every pound of plankton. That’s 8 times more plastic in just 4 years. A recent study by the Ellen MacArthur Foundation and the World Economic Forum claims that the equivalent of one dump truck full of plastic enters the ocean every minute. Scientists estimate that there will be more plastic in the ocean than fish by 2020 unless we drastically change our plastic habits. Thousands of marine animals choke and die from ingesting this plastic, and many more are being slowly poisoned by the dioxin and other pollutants introduced by this mass of plastic. Dioxin is an endocrine disrupter, a so-called gender-bender pollutant because it causes gender mutations in fish and land animals that eat fish, like sea bass, seals, and even polar bears. The plastic in our oceans affects us all. It enters our food chain.
548
1,627
msmarco_v2.1_doc_00_5829357#2_8493053
http://1bagatatime.com/learn/plastic-bags-oceans/
Plastic Bags in Our Oceans | 1 Bag at a Time
Plastic Bags in Our Oceans Plastic Bags in Our Oceans Plastic bags in our oceans are a source of dioxin and other pollutants that are changing marine habitats and polluting our food chain.
Scientists estimate that there will be more plastic in the ocean than fish by 2020 unless we drastically change our plastic habits. Thousands of marine animals choke and die from ingesting this plastic, and many more are being slowly poisoned by the dioxin and other pollutants introduced by this mass of plastic. Dioxin is an endocrine disrupter, a so-called gender-bender pollutant because it causes gender mutations in fish and land animals that eat fish, like sea bass, seals, and even polar bears. The plastic in our oceans affects us all. It enters our food chain. It contributes to extinction. It pollutes the very water that replenishes our planet. Help stop the accumulation of plastic in our oceans by using reusable bags and reducing plastic in your other consumer choices as well. Every bag counts and you can help! « Plastic Bags and Climate Change Plastic Bags in Our Forests »
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msmarco_v2.1_doc_00_5831708#0_8494384
http://1c.extensionfile.net/
Open 1C File
Open 1C File Open 1C File How to Open 1C file What is 1C File? 1C File Applications
Open 1C File Open 1C File To open 1C file you need to find an application which works with that kind of file. 1C file extension is used by operating systems to recognize files with content of type 1C. Here is some information which will get you started. How to Open 1C file To see if you have an application which support 1C file format you need to double click on the file. This will either open it with matching application or Windows will suggest you to look for an application for file extension 1C either on web or on local computer. If there is no application on your computer which can open 1C files you need to search on the internet which application can open 1C files. What is 1C File? File extensions help computers locate correct application for specific files. Operating systems will not look into the content of the files to be opened, but instead, it will immediately locate the file extension of the file and locate for associated application that can open 1C files. This helps the computer to organize its functions and work much faster. Most operating systems (Windows) require the use of file extensions, but others do not (Unix).
0
1,150
msmarco_v2.1_doc_00_5831708#1_8495808
http://1c.extensionfile.net/
Open 1C File
Open 1C File Open 1C File How to Open 1C file What is 1C File? 1C File Applications
What is 1C File? File extensions help computers locate correct application for specific files. Operating systems will not look into the content of the files to be opened, but instead, it will immediately locate the file extension of the file and locate for associated application that can open 1C files. This helps the computer to organize its functions and work much faster. Most operating systems (Windows) require the use of file extensions, but others do not (Unix). These file extensions are also beneficial for us. By simply looking at the filename, we can determine what type of information is stored to that and what applications can open these files. Have you noticed that when your computer acquires an unknown file, it will ask your permission to look for associated program to open it or look for these programs over the Internet? Yes! These file extensions make the work of the computer easy.
679
1,585
msmarco_v2.1_doc_00_5831708#2_8496985
http://1c.extensionfile.net/
Open 1C File
Open 1C File Open 1C File How to Open 1C file What is 1C File? 1C File Applications
These file extensions are also beneficial for us. By simply looking at the filename, we can determine what type of information is stored to that and what applications can open these files. Have you noticed that when your computer acquires an unknown file, it will ask your permission to look for associated program to open it or look for these programs over the Internet? Yes! These file extensions make the work of the computer easy. Once there is no application associated with the file, then the computer will immediately ask the users assistance to help look for the source files. 1C File Applications If you know which application opens file extension 1C and it is not mentioned on our site please e-mail us via contact form. For more information on how to open 1C files read other articles on this website.
1,150
1,963
msmarco_v2.1_doc_00_5833906#0_8498071
http://1callbenefits.com/computers/
1 Call Benefits is under construction
1 Call Benefits is under construction Thank you for being patient. We are doing some work on the site and will be back shortly.
0
127
msmarco_v2.1_doc_00_5834201#0_8498413
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
Called Out Believer: Satisfied With Jesus Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus Therefore I, the prisoner of the Lord, implore you to walk in a manner worthy of the calling with which you have been called, Ephesians 4:1 …so that you will walk in a manner worthy of the Lord, to please Him in all respects, bearing fruit in every good work and increasing in the knowledge of God; Colossians 1:10 …so that you would walk in a manner worthy of the God who calls you into His own kingdom and glory. I Thessalonians 2:12 As many know, I have a background in music. Specifically church music. As a result lyrics quite often nail me between the eyes and stick with me for long periods of time. For the last few months the text of a hymn has haunted me. The words and music were both written by the famed hymn writer B. B. McKinney. The title of the hymn is Satisfied with Jesus:
0
940
msmarco_v2.1_doc_00_5834201#1_8499758
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
Specifically church music. As a result lyrics quite often nail me between the eyes and stick with me for long periods of time. For the last few months the text of a hymn has haunted me. The words and music were both written by the famed hymn writer B. B. McKinney. The title of the hymn is Satisfied with Jesus: I am satisfied with Jesus, He has done so much for me: He has suffered to redeem me, He has died to set me free. He is with me in my trials, Best of friends of all is He; I can always count on Jesus, Can He always count on me? I can hear the voice of Jesus, Calling out so pleadingly, “Go and win the lost and straying”:
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1,261
msmarco_v2.1_doc_00_5834201#2_8500795
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
I am satisfied with Jesus, He has done so much for me: He has suffered to redeem me, He has died to set me free. He is with me in my trials, Best of friends of all is He; I can always count on Jesus, Can He always count on me? I can hear the voice of Jesus, Calling out so pleadingly, “Go and win the lost and straying”: Is He satisfied with me? When my work on earth is ended, And I cross the mystic sea, Oh, that I could hear Him saying, “I am satisfied with thee.” I am satisfied, I am satisfied, I am satisfied with Jesus, But the question comes to me, As I think of Calvary, Is my Master satisfied with me? The last three lines of the refrain are what nail me to the wall. The question about our Christianity is not whether we are satisfied with the peace and grace that are so freely given, but is our Master satisfied with us?
940
1,774
msmarco_v2.1_doc_00_5834201#3_8502050
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
Is He satisfied with me? When my work on earth is ended, And I cross the mystic sea, Oh, that I could hear Him saying, “I am satisfied with thee.” I am satisfied, I am satisfied, I am satisfied with Jesus, But the question comes to me, As I think of Calvary, Is my Master satisfied with me? The last three lines of the refrain are what nail me to the wall. The question about our Christianity is not whether we are satisfied with the peace and grace that are so freely given, but is our Master satisfied with us? Are we walking in a manner that pleases God? Three separate times, in three different epistles, Paul uses the phrase translated, “…walk in a manner worthy…”: In Ephesians 4:1 he urges believers to “…walk in a manner worthy of the calling with which you have been called….” In Colossians 1:10 he again urges “…walk in a manner worthy of the Lord, to please Him in all respects, bearing fruit in every good work and increasing in the knowledge of God…” In I Thessalonians 2:12 he urges believers to “…walk in a manner worthy of the God who calls you into His own kingdom and glory. So as the hymn asks, “…the question comes to me, as I think of Calvary, is my Master satisfied with me?”
1,261
2,459
msmarco_v2.1_doc_00_5834201#4_8503740
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
Are we walking in a manner that pleases God? Three separate times, in three different epistles, Paul uses the phrase translated, “…walk in a manner worthy…”: In Ephesians 4:1 he urges believers to “…walk in a manner worthy of the calling with which you have been called….” In Colossians 1:10 he again urges “…walk in a manner worthy of the Lord, to please Him in all respects, bearing fruit in every good work and increasing in the knowledge of God…” In I Thessalonians 2:12 he urges believers to “…walk in a manner worthy of the God who calls you into His own kingdom and glory. So as the hymn asks, “…the question comes to me, as I think of Calvary, is my Master satisfied with me?” If I am to be honest I must confess that far too often the answer to that question is a resounding “No”. When I ponder this many times I am quite angry with myself and often discouraged. But is this the point of the hymn? My answer to that question would also be, no. The point of the hymn is not to make us feel dejected because we have failed to live up to the standard set by Christ.
1,775
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msmarco_v2.1_doc_00_5834201#5_8505297
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
If I am to be honest I must confess that far too often the answer to that question is a resounding “No”. When I ponder this many times I am quite angry with myself and often discouraged. But is this the point of the hymn? My answer to that question would also be, no. The point of the hymn is not to make us feel dejected because we have failed to live up to the standard set by Christ. That is the whole point. We desperately need Christ to provide salvation on our behalf. We are unable to live up to the standard on our own and whenever we attempt to do this in our own strength we will utterly fail. The point of the hymn is to drive us to our knees in gratitude for the gift of God’s grace that has been poured out on us. As Paul writes in Romans 5:5 – 6, “and hope does not disappoint, because the love of God has been poured out within our hearts through the Holy Spirit who was given to us.
2,460
3,358
msmarco_v2.1_doc_00_5834201#6_8506610
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
That is the whole point. We desperately need Christ to provide salvation on our behalf. We are unable to live up to the standard on our own and whenever we attempt to do this in our own strength we will utterly fail. The point of the hymn is to drive us to our knees in gratitude for the gift of God’s grace that has been poured out on us. As Paul writes in Romans 5:5 – 6, “and hope does not disappoint, because the love of God has been poured out within our hearts through the Holy Spirit who was given to us. For while we were still helpless, at the right time Christ died for the ungodly.” Here are the facts: We are in desperate need of salvation. We cannot earn salvation on our own. Jesus has provided the one and only way of salvation through His death on the cross.
2,847
3,621
msmarco_v2.1_doc_00_5834201#7_8507794
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
For while we were still helpless, at the right time Christ died for the ungodly.” Here are the facts: We are in desperate need of salvation. We cannot earn salvation on our own. Jesus has provided the one and only way of salvation through His death on the cross. We can never do enough or live righteously enough to repay the debt that Christ has paid on our behalf. Does this mean that we can simply live any way we choose and still be called by the name of Christ? No. If we have genuinely received the indescribable gift of grace and salvation, how could we possibly thumb our noses at what that gift cost our Savior? Though we cannot repay the debt (nor should we try) we must strive to “walk in a manner worthy” of the One who has called us and saved us from the eternal consequences of our own actions.
3,359
4,167
msmarco_v2.1_doc_00_5834201#8_8509007
http://1calledoutbeliever.blogspot.com/2007/11/satisfied-with-jesus.html
Called Out Believer: Satisfied With Jesus
Called Out Believer Called Out Believer Monday, November 26, 2007 Satisfied With Jesus Just Three Verses: Satisfied with Jesus
We can never do enough or live righteously enough to repay the debt that Christ has paid on our behalf. Does this mean that we can simply live any way we choose and still be called by the name of Christ? No. If we have genuinely received the indescribable gift of grace and salvation, how could we possibly thumb our noses at what that gift cost our Savior? Though we cannot repay the debt (nor should we try) we must strive to “walk in a manner worthy” of the One who has called us and saved us from the eternal consequences of our own actions. May His grace continually motivate us to reflect the love that we have been shown. So that in the end He may look at us and say, “Well done, good and faithful servant.” Posted by Doyl McMurry at 2:43 PM
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
1chapteraday.com — A Simple Bible Reading Plan 1chapteraday.com Bible Reading = Spiritual Maturity by Bruce on March 16, 2018 Did you know that research shows a direct link between reading the Bible and spiritual maturity. Brad Waggoner’s book The Shape of Faith to Come reveals the results of a Lifeway Research study. The findings conclusively demonstrated that reading the Bible is the best predictor of spiritual maturity. In other words, if you are reading the Bible daily, you are growing spiritually. { 0 comments } Exodus 2 — 03-16-15 by Bruce on March 15, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: 23 Many years later, Egypt’s king died. The Israelites continued to moan because of their bondage, and they cried out to be rescued from their oppression. Their cry for help ascended to God. 24 He heard their pleas and remembered the covenant He made with Abraham, Isaac, and Jacob. 25 God saw the situation the people of Israel were in, and He was moved to take action.
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23 Many years later, Egypt’s king died. The Israelites continued to moan because of their bondage, and they cried out to be rescued from their oppression. Their cry for help ascended to God. 24 He heard their pleas and remembered the covenant He made with Abraham, Isaac, and Jacob. 25 God saw the situation the people of Israel were in, and He was moved to take action. In verse 23, the Israelites continued to moan–so we know that they had been griping and moaning about their bondage for awhile. But what caused God to take action? When they cried out to be rescued. It doesn’t say that they calmly asked, but that they cried out. They were serious about their request!
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
In verse 23, the Israelites continued to moan–so we know that they had been griping and moaning about their bondage for awhile. But what caused God to take action? When they cried out to be rescued. It doesn’t say that they calmly asked, but that they cried out. They were serious about their request! The key to freedom from an oppressive situation is to cry out to God for help. Click Here to Read the Bible Online What is your take? Share the verse that was special to you today and why. Be brief. Read the comments of others.
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
The key to freedom from an oppressive situation is to cry out to God for help. Click Here to Read the Bible Online What is your take? Share the verse that was special to you today and why. Be brief. Read the comments of others. Interact with them. Be encouraging. { 1 comment } Exodus 1 — 03-11-15 March 11, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: 17 But the midwives respected God more than they feared Pharaoh, so they did not carry out the Egyptian king’s command. Instead, they let all the boys live.
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
Interact with them. Be encouraging. { 1 comment } Exodus 1 — 03-11-15 March 11, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: 17 But the midwives respected God more than they feared Pharaoh, so they did not carry out the Egyptian king’s command. Instead, they let all the boys live. 21 Because the midwives respected God, He blessed them with families of their own. The […] Read the full article → Genesis 50 — 03-07-15 March 6, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: Joseph:19 Don’t be afraid. Am I to judge instead of God? It is not my place.
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
21 Because the midwives respected God, He blessed them with families of their own. The […] Read the full article → Genesis 50 — 03-07-15 March 6, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: Joseph:19 Don’t be afraid. Am I to judge instead of God? It is not my place. 20 Even though you intended to harm me, God intended it only for good, and through me, He preserved the lives of countless people, as He is […] Read the full article → Genesis 49 — 03-06-15 March 6, 2015 1 Chapter a Day’s take In Chapter 49, Jacob blesses his sons and tells what their futures hold–their long term futures. We see that his first three sons gave up the leadership role of the family by their behavior as young men. Judah, the fourth son, was the one who was given that role instead, […] Read the full article → Genesis 48 — 03-05-15 March 4, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: Joseph: 18 No, Father!
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
20 Even though you intended to harm me, God intended it only for good, and through me, He preserved the lives of countless people, as He is […] Read the full article → Genesis 49 — 03-06-15 March 6, 2015 1 Chapter a Day’s take In Chapter 49, Jacob blesses his sons and tells what their futures hold–their long term futures. We see that his first three sons gave up the leadership role of the family by their behavior as young men. Judah, the fourth son, was the one who was given that role instead, […] Read the full article → Genesis 48 — 03-05-15 March 4, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: Joseph: 18 No, Father! Since this one is the firstborn, put your right hand on his head. 19 But Israel refused. Jacob: I know, my son, I know. Manasseh will also become a people, and he will be great.
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
Since this one is the firstborn, put your right hand on his head. 19 But Israel refused. Jacob: I know, my son, I know. Manasseh will also become a people, and he will be great. Nevertheless, his younger brother […] Read the full article → Genesis 47 — 03-04-15 March 4, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: 9 I have journeyed through life for 130 years. My life has been short and hard. But they don’t compare with the many years my ancestors traveled this earth. Jacob indicates that his life has been short–an indication that he knows that […] Read the full article → Genesis 46 — 02-26-15 February 26, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was:
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
Nevertheless, his younger brother […] Read the full article → Genesis 47 — 03-04-15 March 4, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: 9 I have journeyed through life for 130 years. My life has been short and hard. But they don’t compare with the many years my ancestors traveled this earth. Jacob indicates that his life has been short–an indication that he knows that […] Read the full article → Genesis 46 — 02-26-15 February 26, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: 2 God spoke there to Israel in visions during the night. God: Jacob, Jacob! Jacob: I’m here.
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
2 God spoke there to Israel in visions during the night. God: Jacob, Jacob! Jacob: I’m here. I’m listening! There is a difference between listening to God and listening! to God and it’s obvious in this verse that Jacob is intensely listening! […] Read the full article → Genesis 45 — 02-25-15 February 25, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: 24 Then he sent his brothers off.
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1chapteraday.com — A Simple Bible Reading Plan
1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
I’m listening! There is a difference between listening to God and listening! to God and it’s obvious in this verse that Jacob is intensely listening! […] Read the full article → Genesis 45 — 02-25-15 February 25, 2015 1 Chapter a Day’s take The verse that was meaningful to me today was: 24 Then he sent his brothers off. As they left he told them, “Take it easy on the journey; try to get along with each other.” So often family members are like Joseph’s family–hard on each other. After being apart from his […] Read the full article → Genesis 44 — 02-23-15 February 23, 2015 1 Chapter a Day’s take 16 Judah as spokesman for the brothers said, “What can we say, master? What is there to say?
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1chapteraday.com 1chapteraday.com Bible Reading = Spiritual Maturity Exodus 2 — 03-16-15 1 Chapter a Day’s take What is your take? Exodus 1 — 03-11-15 Genesis 50 — 03-07-15 Genesis 49 — 03-06-15 Genesis 48 — 03-05-15 Genesis 47 — 03-04-15 Genesis 46 — 02-26-15 Genesis 45 — 02-25-15 Genesis 44 — 02-23-15 Calendar Archives
As they left he told them, “Take it easy on the journey; try to get along with each other.” So often family members are like Joseph’s family–hard on each other. After being apart from his […] Read the full article → Genesis 44 — 02-23-15 February 23, 2015 1 Chapter a Day’s take 16 Judah as spokesman for the brothers said, “What can we say, master? What is there to say? How can we prove our innocence? God is behind this, exposing how bad we are. We stand guilty before you and ready to be your slaves—we’re all in this together, the rest of […] Read the full article → ← Previous Entries Calendar May 2021 S M T W T F S « Mar 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 Archives March 2018 March 2015 February 2015 January 2015 October 2014 September 2014 August 2014 July 2014 June 2014 May 2014 April 2014 March 2014 February 2014 January 2014 December 2013 November 2013 October 2013 September 2013 August 2013 July 2013 June 2013 May 2013 April 2013 March 2013 February 2013 January 2013 December 2012 November 2012 October 2012 September 2012 August 2012 July 2012 June 2012 May 2012 April 2012 March 2012 February 2012 January 2012 December 2011
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
One Part of Chemistry: Physical and chemical properties of alcohols One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols Objectives: 1. To study the physical and chemical properties of alcohols 2. To identify the two unknown liquids from their experimental observations 3. To study the difference between primary alcohols, secondary alcohols and tertiary alcohols. Introduction: The hydrocarbon chains that attached with a hydroxyl group, OH - to a carbon atom are known as alcohols. If the carbon atom is bonded to three hydrogen in addition to the OH -, the alcohol is called methanol. Methanol, CH 3 OH is the most simple alcohol molecule.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
To study the difference between primary alcohols, secondary alcohols and tertiary alcohols. Introduction: The hydrocarbon chains that attached with a hydroxyl group, OH - to a carbon atom are known as alcohols. If the carbon atom is bonded to three hydrogen in addition to the OH -, the alcohol is called methanol. Methanol, CH 3 OH is the most simple alcohol molecule. The category of the alcohol is classified as three groups which are primary (1 ) alcohol, secondary (2 ) alcohols and tertiary (3 ) alcohol. If the alcohol bonded to one alkyl group, the alcohol is primary alcohol. The secondary alcohol is defined as the alcohol which one of the carbons is bonded to two alkyl groups and one hydrogen atom. If one of the carbons in alcohol is bonded to three alkyl groups is called tertiary alcohol. All these alcohols share some similar characteristics but other characteristics are different owing to their different molecular structures.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
The category of the alcohol is classified as three groups which are primary (1 ) alcohol, secondary (2 ) alcohols and tertiary (3 ) alcohol. If the alcohol bonded to one alkyl group, the alcohol is primary alcohol. The secondary alcohol is defined as the alcohol which one of the carbons is bonded to two alkyl groups and one hydrogen atom. If one of the carbons in alcohol is bonded to three alkyl groups is called tertiary alcohol. All these alcohols share some similar characteristics but other characteristics are different owing to their different molecular structures. For physical properties, the size of alcohol determines its boiling point. Usually, the larger the size of the alcohol, the higher the boiling point. This is because the bigger the size of the molecules, the stronger the Van der Waals force between the alcohol molecules. So, more heat energy is needed to be absorbed in order to break down the intermolecular force between each alcohol molecules. Hence, the boiling point of the alcohols increases with the size of the alcohols.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
For physical properties, the size of alcohol determines its boiling point. Usually, the larger the size of the alcohol, the higher the boiling point. This is because the bigger the size of the molecules, the stronger the Van der Waals force between the alcohol molecules. So, more heat energy is needed to be absorbed in order to break down the intermolecular force between each alcohol molecules. Hence, the boiling point of the alcohols increases with the size of the alcohols. The solubility of the alcohol is depends on the size of molecules. Small alcohols are water soluble because the hydroxyl group can form hydrogen bond with water molecules. But, as the size of the alkyl group increases, the solubility of alcohol in water decreases as the hydrophobic property of alcohol increases. For example, if the carbon molecules in alcohol more than six per molecule, the particular alcohol definitely are not soluble in water. This is the result of the alkyl group disrupting the hydrogen bond among the water molecules.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
The solubility of the alcohol is depends on the size of molecules. Small alcohols are water soluble because the hydroxyl group can form hydrogen bond with water molecules. But, as the size of the alkyl group increases, the solubility of alcohol in water decreases as the hydrophobic property of alcohol increases. For example, if the carbon molecules in alcohol more than six per molecule, the particular alcohol definitely are not soluble in water. This is the result of the alkyl group disrupting the hydrogen bond among the water molecules. If the disruption becomes larger enough, the water molecules will repel the alcohol molecules effectively to reestablish hydrogen bonding. The classification of an alcohol as primary, secondary or tertiary (see above) affects the chemical properties of the alcohols. Due to their different classes, the alcohols may give out different chemical properties when they react with the same compounds. Based on their chemical properties, we are able to differentiate among the classes of alcohols. Generally, Lucas test and chromic acid test is the two common tests that we always use to distinguish and categorize the classes of alcohols.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
If the disruption becomes larger enough, the water molecules will repel the alcohol molecules effectively to reestablish hydrogen bonding. The classification of an alcohol as primary, secondary or tertiary (see above) affects the chemical properties of the alcohols. Due to their different classes, the alcohols may give out different chemical properties when they react with the same compounds. Based on their chemical properties, we are able to differentiate among the classes of alcohols. Generally, Lucas test and chromic acid test is the two common tests that we always use to distinguish and categorize the classes of alcohols. Lucas test Water soluble alcohols are always tested by using the Lucas reagent to differentiate among the primary, secondary, and tertiary alcohols. This test depends on the appearance of an alkyl chloride as an insoluble second layer. Lucas reagent is the mixture of zinc chloride and hydrochloric acid. Zinc chloride is a Lewis acid which is added with hydrochloric acid to make its property becomes more acidic. The tertiary alcohol (water soluble) reacts with Lucas reagent almost immediately to form an alkyl chloride which is insoluble in the aqueous solution.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
Lucas test Water soluble alcohols are always tested by using the Lucas reagent to differentiate among the primary, secondary, and tertiary alcohols. This test depends on the appearance of an alkyl chloride as an insoluble second layer. Lucas reagent is the mixture of zinc chloride and hydrochloric acid. Zinc chloride is a Lewis acid which is added with hydrochloric acid to make its property becomes more acidic. The tertiary alcohol (water soluble) reacts with Lucas reagent almost immediately to form an alkyl chloride which is insoluble in the aqueous solution. The formation of a second layer liquid phase in the test tube almost as soon as the alcohol initially dissolves is indicative of a tertiary alcohol. The secondary alcohol reacts slowly with Lucas reagent, and it gives a second phase after heating for 10 minutes whereas the primary alcohol and methanol do not react with Lucas reagent under normal condition. The chemical equation is as shown below (if the reaction takes place) ZnCl 2 R-OH + HCl ------------------> R-Cl + H 2 O Chromic acid test Chromic acid is a strong oxidizing agent which uses to oxidize the alcohols. This test is based on the reduction of chromium (VI) ions to chromium (III) ion. When chromic acid reacts with alcohols, the change in colour of the solution from red-brown to green is a positive test.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
The formation of a second layer liquid phase in the test tube almost as soon as the alcohol initially dissolves is indicative of a tertiary alcohol. The secondary alcohol reacts slowly with Lucas reagent, and it gives a second phase after heating for 10 minutes whereas the primary alcohol and methanol do not react with Lucas reagent under normal condition. The chemical equation is as shown below (if the reaction takes place) ZnCl 2 R-OH + HCl ------------------> R-Cl + H 2 O Chromic acid test Chromic acid is a strong oxidizing agent which uses to oxidize the alcohols. This test is based on the reduction of chromium (VI) ions to chromium (III) ion. When chromic acid reacts with alcohols, the change in colour of the solution from red-brown to green is a positive test. Primary alcohols are oxidized to carboxylic acid by chromic acid. The Cr 6+ in the chromic acid which is red-brown is reduced to green Cr 3+; secondary alcohols are oxidized to ketones by the reagent with the same colour change. Tertiary alcohols are not oxidized at all by the chromic acid. Hence, this reaction can be used to distinguish tertiary alcohols form primary and secondary alcohols.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
Primary alcohols are oxidized to carboxylic acid by chromic acid. The Cr 6+ in the chromic acid which is red-brown is reduced to green Cr 3+; secondary alcohols are oxidized to ketones by the reagent with the same colour change. Tertiary alcohols are not oxidized at all by the chromic acid. Hence, this reaction can be used to distinguish tertiary alcohols form primary and secondary alcohols. For tertiary alcohols, the alcohols would not be oxidized by the reagent. Hence, this test is used to distinguish the tertiary alcohols from primary and secondary alcohols. Reaction with sodium metal The acidic properties of alcohol can be shown by adding the sodium metal into alcohol. The alcohols are weak acids when they react with sodium metal. The hydroxyl group can act as a porton donor to form an alkoxide ion.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
For tertiary alcohols, the alcohols would not be oxidized by the reagent. Hence, this test is used to distinguish the tertiary alcohols from primary and secondary alcohols. Reaction with sodium metal The acidic properties of alcohol can be shown by adding the sodium metal into alcohol. The alcohols are weak acids when they react with sodium metal. The hydroxyl group can act as a porton donor to form an alkoxide ion. Alkoxide ions dissolved in alcohol are strong bases which can be prepared by the reaction of an alcohol with sodium metal. Hydrogen gas is released by the reaction. 2 R-OH + 2 Na -------> 2 R-O - Na + + H 2 The hydrogen gas can be collected and tested by using a burning wooden splinter. A pop sound will be produced. Apparatus:
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
Alkoxide ions dissolved in alcohol are strong bases which can be prepared by the reaction of an alcohol with sodium metal. Hydrogen gas is released by the reaction. 2 R-OH + 2 Na -------> 2 R-O - Na + + H 2 The hydrogen gas can be collected and tested by using a burning wooden splinter. A pop sound will be produced. Apparatus: test tube, measuring cylinder, droppers Materials: ethanol (C 2 H 5 OH), isopropyl alcohol (C 3 H 7 OH), t-butyl alcohol (C 4 H 9 OH), Lucas reagent (mixture of concentrated HCl and ZnCl), chromic acid (H 2 CrO 4 ), sodium metal Procedure: A. Solubility of alcohols 1. In three separate dry test tubes, ethanol, isopropyl alcohol and t-butyl alcohol are added into each test tube. 2.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
test tube, measuring cylinder, droppers Materials: ethanol (C 2 H 5 OH), isopropyl alcohol (C 3 H 7 OH), t-butyl alcohol (C 4 H 9 OH), Lucas reagent (mixture of concentrated HCl and ZnCl), chromic acid (H 2 CrO 4 ), sodium metal Procedure: A. Solubility of alcohols 1. In three separate dry test tubes, ethanol, isopropyl alcohol and t-butyl alcohol are added into each test tube. 2. Water is added to each tubes, the contents are mixed and observed. 3. The results are recorded in a table. 4. The above procedures are repeated with two unknown liquids and observations are being made.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
Water is added to each tubes, the contents are mixed and observed. 3. The results are recorded in a table. 4. The above procedures are repeated with two unknown liquids and observations are being made. B. Lucas test 1. Ethanol, isopropyl alcohol and t-butyl alcohol are added into separate dry test tubes and Lucas reagent is added at room temperature. 2. The tubes are closed with a cork, the tubes are shaken and the length of time it takes for the mixture to become cloudy or separate two layers. 3.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
B. Lucas test 1. Ethanol, isopropyl alcohol and t-butyl alcohol are added into separate dry test tubes and Lucas reagent is added at room temperature. 2. The tubes are closed with a cork, the tubes are shaken and the length of time it takes for the mixture to become cloudy or separate two layers. 3. The results are recorded. 4. The above procedures are repeated with the two unknown liquids and observations are being made. C. Chromic acid test 1. Ethanol, isopropyl alcohol and t-butyl alcohol are added into separate dry test tubes.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
The results are recorded. 4. The above procedures are repeated with the two unknown liquids and observations are being made. C. Chromic acid test 1. Ethanol, isopropyl alcohol and t-butyl alcohol are added into separate dry test tubes. 2. A small piece of sodium metal is added and any reactions occur are noted. 3. The step 1 and step 2 are repeated with two unknown liquids and any observations are made. Results:
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
2. A small piece of sodium metal is added and any reactions occur are noted. 3. The step 1 and step 2 are repeated with two unknown liquids and any observations are made. Results: Part A Table 1 The solubility of alcohols and their observations Alcohols Observation Reaction equations (if any) Deduction/conclusion/discussion Ethanol Soluble in water to form colourless solution C 2 H 5 OH (aq) + H 2 O (l) ---> C 2 H 5 O - (aq)+ H + (aq) Soluble in water Isopropyl alcohol Soluble in water to form colourless solution C 3 H 7 OH (aq) + H 2 O (l) ---> C 3 H 7 O - (aq) + H + (aq) Soluble in water t-butyl alcohol Soluble in water to form colourless solution C 4 H 9 OH (aq) + H 2 O (l) -----> C 4 H 9 O - (aq) + H + (aq) Soluble in water Unknown A Soluble in water to form colourless solution - Soluble in water Unknown B Soluble in water to form colourless solution - Soluble in water Part B Table 2 The reaction between alcohols and Lucas Reagent Alcohols Observation Reaction equations (if any) Deduction/conclusion/discussion Ethanol Yellowish solution remains unchanged after heating. No reaction between ethanol and Lucas reagent. Isopropyl alcohol Yellowish solution remains unchanged within 10 minutes, but turns into cloudy solution after heating. C 3 H 7 OH (aq) + HCl (aq) -----> C 3 H 7 Cl (aq) + H 2 O (l) The reaction between isopropyl alcohol and Lucas reagent occur after heating for 10 minutes. t-butyl alcohol Cloudy solution is formed immediately and two layers are formed.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
Part A Table 1 The solubility of alcohols and their observations Alcohols Observation Reaction equations (if any) Deduction/conclusion/discussion Ethanol Soluble in water to form colourless solution C 2 H 5 OH (aq) + H 2 O (l) ---> C 2 H 5 O - (aq)+ H + (aq) Soluble in water Isopropyl alcohol Soluble in water to form colourless solution C 3 H 7 OH (aq) + H 2 O (l) ---> C 3 H 7 O - (aq) + H + (aq) Soluble in water t-butyl alcohol Soluble in water to form colourless solution C 4 H 9 OH (aq) + H 2 O (l) -----> C 4 H 9 O - (aq) + H + (aq) Soluble in water Unknown A Soluble in water to form colourless solution - Soluble in water Unknown B Soluble in water to form colourless solution - Soluble in water Part B Table 2 The reaction between alcohols and Lucas Reagent Alcohols Observation Reaction equations (if any) Deduction/conclusion/discussion Ethanol Yellowish solution remains unchanged after heating. No reaction between ethanol and Lucas reagent. Isopropyl alcohol Yellowish solution remains unchanged within 10 minutes, but turns into cloudy solution after heating. C 3 H 7 OH (aq) + HCl (aq) -----> C 3 H 7 Cl (aq) + H 2 O (l) The reaction between isopropyl alcohol and Lucas reagent occur after heating for 10 minutes. t-butyl alcohol Cloudy solution is formed immediately and two layers are formed. Upper layer is clear while lower layer is cloudy. C 4 H 9 OH (aq) + HCl (aq) C 4 H 9 Cl (aq) + H 2 O (l) The reaction between t-buytl alcohol and Lucas reagent is instant reaction. Unknown A Yellowish solution remains unchanged within 10 minutes, but turns into cloudy solution after heating. Unknown A is isopropyl alcohol because it has the similar reaction with it. Unknown B Cloudy solution is formed immediately and two layers are formed.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
Upper layer is clear while lower layer is cloudy. C 4 H 9 OH (aq) + HCl (aq) C 4 H 9 Cl (aq) + H 2 O (l) The reaction between t-buytl alcohol and Lucas reagent is instant reaction. Unknown A Yellowish solution remains unchanged within 10 minutes, but turns into cloudy solution after heating. Unknown A is isopropyl alcohol because it has the similar reaction with it. Unknown B Cloudy solution is formed immediately and two layers are formed. Upper layer is clear while lower layer is cloudy. Unknown B is t-butyl alcohol because it has the same reaction with it. Part C Table 3 The reaction of alcohols with chromic acid Alcohols Observation Reaction equations (if any) Deduction/conclusion/discussion Ethanol The solution turns from colourless to green 3 CH 3 CH 2 OH + 2 CrO 4- + 10 H + à 3 CH 3 CHO + 2 Cr 3+ +8 H 2 O Ethanol is oxidized by the chromic acid. Isopropyl alcohol Two layers are formed. Upper layer is green while lower layer is black.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
Upper layer is clear while lower layer is cloudy. Unknown B is t-butyl alcohol because it has the same reaction with it. Part C Table 3 The reaction of alcohols with chromic acid Alcohols Observation Reaction equations (if any) Deduction/conclusion/discussion Ethanol The solution turns from colourless to green 3 CH 3 CH 2 OH + 2 CrO 4- + 10 H + à 3 CH 3 CHO + 2 Cr 3+ +8 H 2 O Ethanol is oxidized by the chromic acid. Isopropyl alcohol Two layers are formed. Upper layer is green while lower layer is black. C 3 H 7 OH (aq) + H 2 CrO 4 (aq) -----> C 2 H 6 CO (aq) + Cr 2 (SO 4) 3 (aq) + H 2 O (l)3 (CH 3) 2 CHOH + 2 CrO 4- + 10 H + à3 (CH 3) 2 CO + 2 Cr 3+ +8 H 2 O Isopropyl alcohol is oxidized by the chromic acid. t-butyl alcohol Two layers are formed. Then, the precipitate dissolves in solution to become reddish brown solution. - No reaction. Unknown A Two layers are formed.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
C 3 H 7 OH (aq) + H 2 CrO 4 (aq) -----> C 2 H 6 CO (aq) + Cr 2 (SO 4) 3 (aq) + H 2 O (l)3 (CH 3) 2 CHOH + 2 CrO 4- + 10 H + à3 (CH 3) 2 CO + 2 Cr 3+ +8 H 2 O Isopropyl alcohol is oxidized by the chromic acid. t-butyl alcohol Two layers are formed. Then, the precipitate dissolves in solution to become reddish brown solution. - No reaction. Unknown A Two layers are formed. Upper layer is green while lower layer is black. Unknown A is isopropyl alcohol because it has the similar reaction with isopropyl alcohol. Unknown B Two layers are formed. Then, the precipitate dissolves in solution to become reddish brown solution. Unknown B is t-butyl alcohol because it has the similar reaction with t-butyl alcohol.
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One Part of Chemistry: Physical and chemical properties of alcohols
One Part of Chemistry One Part of Chemistry Wednesday, May 11, 2011 Physical and chemical properties of alcohols
Upper layer is green while lower layer is black. Unknown A is isopropyl alcohol because it has the similar reaction with isopropyl alcohol. Unknown B Two layers are formed. Then, the precipitate dissolves in solution to become reddish brown solution. Unknown B is t-butyl alcohol because it has the similar reaction with t-butyl alcohol. Part D Table 4 The reaction between alcohols and sodium metal Alcohols Observation Reaction equations (if any) Deduction/conclusion/discussion Ethanol Bubbles of colourless gas released quickly. A pop sound is produced when tested with burning wooden splinter. 2C 2 H 5 OH (aq) + 2Na (s) ------> 2C 2 H 5 ONa (aq
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol One Part of Chemistry Objective: 1. To synthesis triphenylmethanol from Grignard reaction 2. To study the method to produce Grignard reagent Introduction: Grignard reagents are organomagnesium halides (RMgX), and are one of the most synthetically useful and versatile classes of reagents available to the organic chemist. An alkyl, benzyl, or aromatic halide is reacted with a magnesium metal by using an anhydrous solvent in order to produce Grignard reagent. Ether or tetrahydrofuran are usually can be used as the anhydrous solvent in producing the particular reagent. Tetrahydrofuran is a strong base and it has a better solvating ability, it may used when Grignard reagent does not readily form in diethyl ether. This is considered as an organometallic compound which consists of the combination of a metal and organic molecule.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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Grignard reagents are organomagnesium halides (RMgX), and are one of the most synthetically useful and versatile classes of reagents available to the organic chemist. An alkyl, benzyl, or aromatic halide is reacted with a magnesium metal by using an anhydrous solvent in order to produce Grignard reagent. Ether or tetrahydrofuran are usually can be used as the anhydrous solvent in producing the particular reagent. Tetrahydrofuran is a strong base and it has a better solvating ability, it may used when Grignard reagent does not readily form in diethyl ether. This is considered as an organometallic compound which consists of the combination of a metal and organic molecule. Figure 1 in below shows the general reaction mechanism for the formation of Grignard reagent. The chemical reaction between an organic halide and a magnesium metal can produce an alkyl or aryl free radical and magnesium free radical. The formation of Grignard reagent has been occurs. The bonding between carbon and magnesium is a covalent bond but it is highly polarized because the magnesium is bonded to halide which is an electron withdrawing group. This causes the formation of partial positively charge and partial negatively charge on the magnesium atom and alkyl or aryl group respectively.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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Figure 1 in below shows the general reaction mechanism for the formation of Grignard reagent. The chemical reaction between an organic halide and a magnesium metal can produce an alkyl or aryl free radical and magnesium free radical. The formation of Grignard reagent has been occurs. The bonding between carbon and magnesium is a covalent bond but it is highly polarized because the magnesium is bonded to halide which is an electron withdrawing group. This causes the formation of partial positively charge and partial negatively charge on the magnesium atom and alkyl or aryl group respectively. Hence, the carbanion has both characteristics of a good nucleophile and a strong base. Its basicity allows it to react with the electrophile carbon in a carbonyl group. Besides, Grignard reagent also works with acidic compound such as carboxylic acid, phenol, thiol, alcohol, and even water. One of the most important reactions is the addition of Grignard reagent to the carbonyl compound like aldehyde, ketone, and ester in order to produce the corresponding secondary alcohol and tertiary alcohol. Figure 2 The most challenging part of this experiment is to avoid the Grignard reagent contact with water.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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Hence, the carbanion has both characteristics of a good nucleophile and a strong base. Its basicity allows it to react with the electrophile carbon in a carbonyl group. Besides, Grignard reagent also works with acidic compound such as carboxylic acid, phenol, thiol, alcohol, and even water. One of the most important reactions is the addition of Grignard reagent to the carbonyl compound like aldehyde, ketone, and ester in order to produce the corresponding secondary alcohol and tertiary alcohol. Figure 2 The most challenging part of this experiment is to avoid the Grignard reagent contact with water. The partial negative charge on the carbon atom that bonded to magnesium exhibits a very basic property. The water molecule will destroy the nucleophilic property of Grignard reagent. So, several precaution steps must be taken in the procedures to avoid the Grignard reagent reacts with water: the reaction flask is dried in the oven before use; iodine is vaporized in the flask tie up traces of water and to activate the surface of magnesium;
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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The partial negative charge on the carbon atom that bonded to magnesium exhibits a very basic property. The water molecule will destroy the nucleophilic property of Grignard reagent. So, several precaution steps must be taken in the procedures to avoid the Grignard reagent reacts with water: the reaction flask is dried in the oven before use; iodine is vaporized in the flask tie up traces of water and to activate the surface of magnesium; the anhydrous diethyl ether should be used. Figure 3 The figure 3 above shows the Grignard reagent and water reaction. The metal hydroxide (alkoxide) formed in the above reaction is appears as insoluble white solid (HO-MgBr or RO-MgBr) in the diethyl ether solvent. Thus, the process of producing Grignard reagent must be start over again in a dry glass if the insoluble white solid is observable during the formation of Grignard reagent. For a variety of reasons, anhydrous diethyl ether is the solvent choice for carrying out a Grignard synthesis.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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the anhydrous diethyl ether should be used. Figure 3 The figure 3 above shows the Grignard reagent and water reaction. The metal hydroxide (alkoxide) formed in the above reaction is appears as insoluble white solid (HO-MgBr or RO-MgBr) in the diethyl ether solvent. Thus, the process of producing Grignard reagent must be start over again in a dry glass if the insoluble white solid is observable during the formation of Grignard reagent. For a variety of reasons, anhydrous diethyl ether is the solvent choice for carrying out a Grignard synthesis. One of the reasons is the vapors of the highly volatile diethyl ether helps to prevent the oxygen in the atmosphere to reach the reaction solution. Grignard reagent will reacts with oxygen which hydroperoxides is produced. This compound is highly unstable if exposed to the air so that the compound is usually not isolated from the solvent. Other than that, the basic oxygen atoms in ether molecules are actually coordinate with and help to stabilize the Grignard reagent. The figure 4 below shows how the anhydrous diethyl ether protects Grignard reagent from oxidation:
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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One of the reasons is the vapors of the highly volatile diethyl ether helps to prevent the oxygen in the atmosphere to reach the reaction solution. Grignard reagent will reacts with oxygen which hydroperoxides is produced. This compound is highly unstable if exposed to the air so that the compound is usually not isolated from the solvent. Other than that, the basic oxygen atoms in ether molecules are actually coordinate with and help to stabilize the Grignard reagent. The figure 4 below shows how the anhydrous diethyl ether protects Grignard reagent from oxidation: Figure 4 There is a layer of oxide coated on the surface of magnesium which used to synthesis Grignard reagent. The oxide layer works to prevent it to react with alkyl bromide. The formation of Grignard reagent is highly exothermic which will produce a lot of heat energy from the system. Once the reaction has been initiated, the system will reflux itself in the bottom flask without any external heat source. The adding of a drying tube that contains calcium chloride to the reflux apparatus is used to protect the reaction from atmospheric moisture.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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Figure 4 There is a layer of oxide coated on the surface of magnesium which used to synthesis Grignard reagent. The oxide layer works to prevent it to react with alkyl bromide. The formation of Grignard reagent is highly exothermic which will produce a lot of heat energy from the system. Once the reaction has been initiated, the system will reflux itself in the bottom flask without any external heat source. The adding of a drying tube that contains calcium chloride to the reflux apparatus is used to protect the reaction from atmospheric moisture. In this experiment, bromobenzene is the alkyl halide used to generate Grignard reagent. Figure 5 Once the Grignard reagent is readily formed, the carbonyl compound has been introduced into the reagent in order to synthesis the expected product. The methyl benzoate (ester) acts as the carbonyl containing compound in the experiment. The reaction between methyl benzoate and Grignard reagent is showing in the following figure 6: Figure 6 Dissociation of magnesium alkoxide produces a ketone which tends to react further with more Grignard reagent.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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In this experiment, bromobenzene is the alkyl halide used to generate Grignard reagent. Figure 5 Once the Grignard reagent is readily formed, the carbonyl compound has been introduced into the reagent in order to synthesis the expected product. The methyl benzoate (ester) acts as the carbonyl containing compound in the experiment. The reaction between methyl benzoate and Grignard reagent is showing in the following figure 6: Figure 6 Dissociation of magnesium alkoxide produces a ketone which tends to react further with more Grignard reagent. The final step of the synthesis is involving hydrolysis of the magnesium alkoxide by using a mineral acid. As the result, the reaction synthesizes an alcohol, triphenylmethanol and magnesium salt (water soluble). A side reaction may take place in the reaction between phenylmagnesium bromide and bromobenzene. The side product has been produced is biphenyl which consists of two phenyl rings. The biphenyl is known as impurity in the experiment.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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The final step of the synthesis is involving hydrolysis of the magnesium alkoxide by using a mineral acid. As the result, the reaction synthesizes an alcohol, triphenylmethanol and magnesium salt (water soluble). A side reaction may take place in the reaction between phenylmagnesium bromide and bromobenzene. The side product has been produced is biphenyl which consists of two phenyl rings. The biphenyl is known as impurity in the experiment. The impurity can be removed from the product through a method of recrystallization since biphenyl is much more soluble in ligroin compared to triphenylmethanol. Apparatus: dropping funnel, two neck round bottomed flask, drying tube, condenser, sonicator, magnetic stirrer, hot plate, separating funnel, beaker, Buchner funnel, glass funnel, melting point apparatus Materials: magnesium turning, anhydrous diethyl ether, bromobenzene, calcium chloride, methyl benzoate, iodine crystal, 10% H 2 SO 4, ice, sodium bisulfate, sodium sulfate anhydrous, petroleum ether, methyl spirit Procedure: Part A – Preparation of phenylmagnesium bromide (phenyl Grignard reagent) 1.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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The impurity can be removed from the product through a method of recrystallization since biphenyl is much more soluble in ligroin compared to triphenylmethanol. Apparatus: dropping funnel, two neck round bottomed flask, drying tube, condenser, sonicator, magnetic stirrer, hot plate, separating funnel, beaker, Buchner funnel, glass funnel, melting point apparatus Materials: magnesium turning, anhydrous diethyl ether, bromobenzene, calcium chloride, methyl benzoate, iodine crystal, 10% H 2 SO 4, ice, sodium bisulfate, sodium sulfate anhydrous, petroleum ether, methyl spirit Procedure: Part A – Preparation of phenylmagnesium bromide (phenyl Grignard reagent) 1. A condenser and a 50ml dropping funnel were set up to a 250ml two neck round bottom flask. 2. A calcium chloride drying tube was inserted into the top of the condenser. 3. 1.4g of magnesium turning was weighed and placed into the two neck round bottom flask with a stir bar.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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A condenser and a 50ml dropping funnel were set up to a 250ml two neck round bottom flask. 2. A calcium chloride drying tube was inserted into the top of the condenser. 3. 1.4g of magnesium turning was weighed and placed into the two neck round bottom flask with a stir bar. 10ml of anhydrous diethyl ether was added immediately into the two neck bottom flask. 4. 6.2ml of bromobenzene and 30ml of anhydrous diethyl ether were added into the 50ml dropping funnel. 5. 5ml of the mixture in dropping funnel was added to the ether/magnesium mixture.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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10ml of anhydrous diethyl ether was added immediately into the two neck bottom flask. 4. 6.2ml of bromobenzene and 30ml of anhydrous diethyl ether were added into the 50ml dropping funnel. 5. 5ml of the mixture in dropping funnel was added to the ether/magnesium mixture. The mixture is stirred with a magnetic stirrer. 6. If the reaction does not begin immediately, both palms were placed around the bottom of the flask to keep it warm. 7. A small amount of iodine crystal was added directly into the magnesium surface if the reaction does not take place after 5-10minutes.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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The mixture is stirred with a magnetic stirrer. 6. If the reaction does not begin immediately, both palms were placed around the bottom of the flask to keep it warm. 7. A small amount of iodine crystal was added directly into the magnesium surface if the reaction does not take place after 5-10minutes. 8. Once the reaction was initiated and the formation of Grignard reagent became steady, the ether refluxed itself. The remaining mixture in dropping funnel was added dropwise into the round bottom flask. 9. The solution was allowed to reflux for 10 minutes.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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8. Once the reaction was initiated and the formation of Grignard reagent became steady, the ether refluxed itself. The remaining mixture in dropping funnel was added dropwise into the round bottom flask. 9. The solution was allowed to reflux for 10 minutes. Part B – Preparation of triphenylmethanol from Grignard reagent 1. After reflux, the round bottom flask was cooled down in ice bath and a solution of 3.2 ml of benzoate dissolved in 15ml anhydrous diethyl ether was placed in the dropping funnel. 2. The solution was added over 5 minutes to avoid the solution to get too exothermic. 3.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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Part B – Preparation of triphenylmethanol from Grignard reagent 1. After reflux, the round bottom flask was cooled down in ice bath and a solution of 3.2 ml of benzoate dissolved in 15ml anhydrous diethyl ether was placed in the dropping funnel. 2. The solution was added over 5 minutes to avoid the solution to get too exothermic. 3. Once the reaction was completed, the solution was heated to reflux for 10 minutes to complete the reaction. 4. After reflux, the round bottom flask was cooled with ice bath and the mixture was poured into a 600ml beaker with contains 75g of ice and 30ml of 10% H 2 SO 4. 5. The mixture was stirred until all white solid was dissolved.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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Once the reaction was completed, the solution was heated to reflux for 10 minutes to complete the reaction. 4. After reflux, the round bottom flask was cooled with ice bath and the mixture was poured into a 600ml beaker with contains 75g of ice and 30ml of 10% H 2 SO 4. 5. The mixture was stirred until all white solid was dissolved. 6. The mixture was poured into the separating funnel and separated the two layers. The ether layer was washed with 15ml of H 2 SO 4, followed by 15ml of water and then with a solution of 1g of sodium bisulfite dissolved in 12ml of water. 7. The ether layer was dried over sodium sulfate anhydrous and filtered with cotton wool.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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6. The mixture was poured into the separating funnel and separated the two layers. The ether layer was washed with 15ml of H 2 SO 4, followed by 15ml of water and then with a solution of 1g of sodium bisulfite dissolved in 12ml of water. 7. The ether layer was dried over sodium sulfate anhydrous and filtered with cotton wool. 15ml of petroleum ether was added to the ether layer. The ether layer was concentrated over a steam bath at 60-80 °C until the triphenylmethanol was formed. The product was cooled in an ice bath. 8. The product was recrystallized from methyl spirit.
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One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
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15ml of petroleum ether was added to the ether layer. The ether layer was concentrated over a steam bath at 60-80 °C until the triphenylmethanol was formed. The product was cooled in an ice bath. 8. The product was recrystallized from methyl spirit. 9. The weight, yield and melting point of triphenylmethanol were determined. Results and calculation Weight of magnesium = 1.4009g Volume of bromobenzene = 6.2ml Volume of methyl benzoate = 3.2ml Weight of watch glass = 14.8091g Weight of watch glass + weight of product = 13.7410 Weight of product = 1.0681g Atomic weight of magnesium = 24.31g/mol Number of mole of magnesium = 1.4009 g / 24.31 g mol -1 = 0.0576mol Molecular weight of bromobenzene = 157g/mol Density of bromobenzene = 1.495 g/cm 3 Weight of bromobenzene = density x volume = 1.495 g/cm 3 x 6.2cm 3 = 9.269g Number of mole of bromobenzene = 9.269g/ 157 g mol -1 = 0.0590mol Since the magnesium is limiting reagent, so the number of mole of Grignard reagent produced is limited by number of mole of magnesium. Number of mole of Grignard reagent produced = 0.0576mol Density of methyl benzoate = 1.0837 g/cm 3 Weight of methyl benzoate = density x volume = 1.0837 g/cm 3 x 3.2cm 3 = 3.468 g Molecular weight of methyl benzoate = 136.144g/mol Number of mole of methyl benzoate = 3.468 g / 136.144g mol -1 = 0.0255 mol Since the Grignard reagent is excess, the product is limited by methyl benzoate so that it is limiting reagent in the reaction. Thus, the number of mole of triphenylmethanol = 0.0255 mol.
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http://1chemistry.blogspot.com/2011/11/grignard-synthesis-of-triphenylmethanol.html
One Part of Chemistry: Grignard Synthesis of Triphenylmethanol
One Part of Chemistry One Part of Chemistry
9. The weight, yield and melting point of triphenylmethanol were determined. Results and calculation Weight of magnesium = 1.4009g Volume of bromobenzene = 6.2ml Volume of methyl benzoate = 3.2ml Weight of watch glass = 14.8091g Weight of watch glass + weight of product = 13.7410 Weight of product = 1.0681g Atomic weight of magnesium = 24.31g/mol Number of mole of magnesium = 1.4009 g / 24.31 g mol -1 = 0.0576mol Molecular weight of bromobenzene = 157g/mol Density of bromobenzene = 1.495 g/cm 3 Weight of bromobenzene = density x volume = 1.495 g/cm 3 x 6.2cm 3 = 9.269g Number of mole of bromobenzene = 9.269g/ 157 g mol -1 = 0.0590mol Since the magnesium is limiting reagent, so the number of mole of Grignard reagent produced is limited by number of mole of magnesium. Number of mole of Grignard reagent produced = 0.0576mol Density of methyl benzoate = 1.0837 g/cm 3 Weight of methyl benzoate = density x volume = 1.0837 g/cm 3 x 3.2cm 3 = 3.468 g Molecular weight of methyl benzoate = 136.144g/mol Number of mole of methyl benzoate = 3.468 g / 136.144g mol -1 = 0.0255 mol Since the Grignard reagent is excess, the product is limited by methyl benzoate so that it is limiting reagent in the reaction. Thus, the number of mole of triphenylmethanol = 0.0255 mol. Molecular weight of triphenylmethanol = 260.318g/mol Theoretical weight of triphenylmethanol = 0.0255mol x 260.318g/mol = 6.6381 g Actual weight of triphenylmethanol = Percentage yield = actual yield / theoretical yield x 100% = 1.0681g / 6.6381g x 100% = 16.09% Melting point of triphenylmethanol = 153°C ~ 156°C Discussion: The purpose of this experiment is to synthesis triphenylmethanol by using Grignard reagent. In order to synthesis triphenylmethanol, Grignard reagent is playing an i
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msmarco_v2.1_doc_00_5882296#0_8580757
http://1chinesefood.com/lunch.html
No. 1 Chinese Restaurant - Lunch Specials
No. 1 Chinese Restaurant - Lunch Specials Lunch Special 11:00 AM to 3:00 PM Served with Chicken Fried Rice and Crab Rangoon (1 pc.) $6.25 Each L 1. Chicken w. Mixed Vegetable L 2. Vegetable Lo Mein L 3. Chicken w. Mushroom L 4. Chicken Lo Mein L 5. Roast Pork w. Chinese Vegetable L 6. Roast Pork w. Mushroom L 7. Chicken w. Broccoli L 8.
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msmarco_v2.1_doc_00_5882296#1_8581323
http://1chinesefood.com/lunch.html
No. 1 Chinese Restaurant - Lunch Specials
Chicken w. Mushroom L 4. Chicken Lo Mein L 5. Roast Pork w. Chinese Vegetable L 6. Roast Pork w. Mushroom L 7. Chicken w. Broccoli L 8. Moo Goo Gai Pan L 9. Chicken w. Curry Sauce = Hot and Spicy We can alter the spicy according to your taste. L 10. Mixed Vegetable L 11. Shrimp w. Lobster Sauce L 12.
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msmarco_v2.1_doc_00_5882296#2_8581859
http://1chinesefood.com/lunch.html
No. 1 Chinese Restaurant - Lunch Specials
Moo Goo Gai Pan L 9. Chicken w. Curry Sauce = Hot and Spicy We can alter the spicy according to your taste. L 10. Mixed Vegetable L 11. Shrimp w. Lobster Sauce L 12. Shrimp w. Broccoli L 13. Almond Boneless Chicken L 14. Beef w. Mixed Vegetable. L 15. Beef with Broccoli L 16.
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msmarco_v2.1_doc_00_5882296#3_8582368
http://1chinesefood.com/lunch.html
No. 1 Chinese Restaurant - Lunch Specials
Shrimp w. Broccoli L 13. Almond Boneless Chicken L 14. Beef w. Mixed Vegetable. L 15. Beef with Broccoli L 16. Pepper Steak w. Onion L 17. Bar-B-Q Boneless Spare Ribs L 18. Teryaki Chicken (4 Skewers) L 19. Chicken w. Snow Peas L 20. Sweet & Sour Chicken L 21.
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788
msmarco_v2.1_doc_00_5882296#4_8582855
http://1chinesefood.com/lunch.html
No. 1 Chinese Restaurant - Lunch Specials
Pepper Steak w. Onion L 17. Bar-B-Q Boneless Spare Ribs L 18. Teryaki Chicken (4 Skewers) L 19. Chicken w. Snow Peas L 20. Sweet & Sour Chicken L 21. Honey Chicken L 22. Szechuan Chicken L 23. General Tso's Chicken L 24. Sesame Chicken L 25. Hunan Beef or Chicken L 26.
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913
msmarco_v2.1_doc_00_5882296#5_8583353
http://1chinesefood.com/lunch.html
No. 1 Chinese Restaurant - Lunch Specials
Honey Chicken L 22. Szechuan Chicken L 23. General Tso's Chicken L 24. Sesame Chicken L 25. Hunan Beef or Chicken L 26. Chicken w. Garlic Sauce L 27. Shrimp w. Garlic Sauce L 28. Kung Pao Chicken w. Peanuts L 29. Szechuan Beef L 30. Mongolian Beef or Chicken L 31.
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msmarco_v2.1_doc_00_5882296#6_8583847
http://1chinesefood.com/lunch.html
No. 1 Chinese Restaurant - Lunch Specials
Chicken w. Garlic Sauce L 27. Shrimp w. Garlic Sauce L 28. Kung Pao Chicken w. Peanuts L 29. Szechuan Beef L 30. Mongolian Beef or Chicken L 31. Orange Chicken L 32. Tai Chien Chicken
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msmarco_v2.1_doc_00_5883675#0_8584256
http://1clickpethotels.com/
Pet Friendly Hotels and Motels Only
Pet Friendly Hotels and Motels by 1Click
Pet Friendly Hotels and Motels Only Pet Friendly Hotels and Motels by 1Click Free Online Directory of pet friendly hotels, motels & resorts that allow dogs, cats, etc. PLUS Studio, 1 and 2 Bedroom Suite Pet Friendly Hotels with Fully Equipped Stovetop Kitchens Look for K next to Hotel Name All hotels on this site are pet friendly hotels and most of them also allow, accept or take cats and other pets as well, unless otherwise specified. Check out our Pet Travel Links for tips, guidelines and fun things to do when your pet takes you with it. "These Pet Friendly Hotels also take humans" Book On-line for Maximum Savings - Or - Call 800-620-2752 for assistance - anytime Click on State or Province for Pet Friendly Hotel City Listings Popular Cities Alabama Maine Ohio Anaheim Alaska Manitoba Oklahoma Albuquerque Alberta Maryland Ontario Amarillo Arizona Massachusetts Oregon Asheville Arkansas Michigan Pennsylvania Atlanta British Colum Minnesota Quebec Atlantic City California Mississippi Rhode Island Charlotte Colorado Missouri Saskatchewan Chattanooga Connecticut Montana South Carolina Flagstaff Delaware Nebraska South Dakota Florence SC Dist of Columb Nevada Tennessee Jacksonville Florida New Brunswick Texas Las Vegas Georgia New Hampshire Utah Los Angeles Idaho New Jersey Vermont Memphis Illinois New Mexico Virginia Myrtle Beach Indiana New York Washington Nashville Iowa North Carolina West Virginia Orlando Kansas North Dakota Wisconsin Phoenix Kentucky Nova Scotia Wyoming Raleigh Louisiana Reno Tucson San Diego San Francisco Savannah Niagara Falls At 1Click Pet Hotels we specialize in hotels that allow, that accept and that take pets. All hotels on this site are dog friendly hotels, dog friendly motels and dog friendly resorts. These are hotels that allow, that accept and that take cats and other pets unless otherwise specified. Useful Pet Friendly Links Find a Pet Friendly Hotel / Pet Friendly Hotels / Pet Friendly Hotel Chains Las Vegas to Florida Pet Friendly Hotels / Are all Hotels in a Chain Pet Friendly Florence to Savannah Pet Friendly Hotels / Pet Friendly Hotels S ite Map 1Click Pet Hotels Home / Help ©1999, 2000, 2001, 2002, 2003, 2004, 2005, 2006 all rights reserved by 1 Click Pet Hotels
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2,450
msmarco_v2.1_doc_00_5886646#0_8587213
http://1cupawesome.com/air-fryer-bread-recipe/
Air fryer bread recipe
Air fryer bread recipe Air fryer bread recipe The estimated time to cook: Ingredients for pumpkin and sunflower seed soft bums fruit cake: How to cook it? Check The Complete Air Fryer Cookbook
Air fryer bread recipe You are here: Home / Recipes / Air fryer bread recipe Air fryer bread recipe May 7, 2016 Awesome Admin Facebook 0 Twitter 0 Google+ 0 Pinterest 1 LinkedIn 0 Have you ever think about purchasing a bread maker to have fresh bread at home? It’s not a good idea because, with your air fryer, you can do more than bake a cake and simple meals. Now you can even make bread with it! In this article, we will provide you some simple steps to make a pumpkin and sunflower seed soft bums with air fryer. This is a type of bread with the pumpkin shape with sunflower seed above it. The estimated time to cook: This bread may take you about 3 hours to prepare the bread but only about 5-10 minutes to bake it in the air fryer. Also, you need to adjust the time based on the size of bread and temperature you use. Ingredients for pumpkin and sunflower seed soft bums fruit cake:
0
888
msmarco_v2.1_doc_00_5886646#1_8588527
http://1cupawesome.com/air-fryer-bread-recipe/
Air fryer bread recipe
Air fryer bread recipe Air fryer bread recipe The estimated time to cook: Ingredients for pumpkin and sunflower seed soft bums fruit cake: How to cook it? Check The Complete Air Fryer Cookbook
This is a type of bread with the pumpkin shape with sunflower seed above it. The estimated time to cook: This bread may take you about 3 hours to prepare the bread but only about 5-10 minutes to bake it in the air fryer. Also, you need to adjust the time based on the size of bread and temperature you use. Ingredients for pumpkin and sunflower seed soft bums fruit cake: Below are the ingredients to have 15 buns and 25 grams for each of them. However, you can add or remove the ingredients to have the best taste. – 215 grams all-purpose flour or plain flour – 30 grams sugar – 100 grams milk (it should be fresh milk) – 30 grams butter – 1/3 egg – 1 teaspoon of instant yeast – 1 teaspoon of salt How to cook it? After preparing all the essential ingredients above, let’s cook the pumpkin and sunflower seed soft bums now. Step 1:
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1,350
msmarco_v2.1_doc_00_5886646#2_8589817
http://1cupawesome.com/air-fryer-bread-recipe/
Air fryer bread recipe
Air fryer bread recipe Air fryer bread recipe The estimated time to cook: Ingredients for pumpkin and sunflower seed soft bums fruit cake: How to cook it? Check The Complete Air Fryer Cookbook
Below are the ingredients to have 15 buns and 25 grams for each of them. However, you can add or remove the ingredients to have the best taste. – 215 grams all-purpose flour or plain flour – 30 grams sugar – 100 grams milk (it should be fresh milk) – 30 grams butter – 1/3 egg – 1 teaspoon of instant yeast – 1 teaspoon of salt How to cook it? After preparing all the essential ingredients above, let’s cook the pumpkin and sunflower seed soft bums now. Step 1: Firstly, all the ingredients without butter should be mixed together. When the mixture’s smooth and elastic, please add the butter then continue to mix all of them. Step 2: Now the bread should be proofed in 2 hours 45 minutes to have the dough double in size. After that, it should be covered with a lid or cling wrap.
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1,670
msmarco_v2.1_doc_00_5886646#3_8591060
http://1cupawesome.com/air-fryer-bread-recipe/
Air fryer bread recipe
Air fryer bread recipe Air fryer bread recipe The estimated time to cook: Ingredients for pumpkin and sunflower seed soft bums fruit cake: How to cook it? Check The Complete Air Fryer Cookbook
Firstly, all the ingredients without butter should be mixed together. When the mixture’s smooth and elastic, please add the butter then continue to mix all of them. Step 2: Now the bread should be proofed in 2 hours 45 minutes to have the dough double in size. After that, it should be covered with a lid or cling wrap. Also, you should prevent all the wind from dry up the bread. Step 3: Here, the dough should be divided into balls of 25 grams and rest them for about 10 minutes. Step 4: Mix the egg yolk with milk or water to have the egg wash.
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msmarco_v2.1_doc_00_5886646#4_8592023
http://1cupawesome.com/air-fryer-bread-recipe/
Air fryer bread recipe
Air fryer bread recipe Air fryer bread recipe The estimated time to cook: Ingredients for pumpkin and sunflower seed soft bums fruit cake: How to cook it? Check The Complete Air Fryer Cookbook
Also, you should prevent all the wind from dry up the bread. Step 3: Here, the dough should be divided into balls of 25 grams and rest them for about 10 minutes. Step 4: Mix the egg yolk with milk or water to have the egg wash. Step 5: Now, you just need to shape the mixture into the ball and put them on the baking paper. You can have a different shape as you want. After that, cover them with egg wash above. Step 6:
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msmarco_v2.1_doc_00_5886646#5_8592853
http://1cupawesome.com/air-fryer-bread-recipe/
Air fryer bread recipe
Air fryer bread recipe Air fryer bread recipe The estimated time to cook: Ingredients for pumpkin and sunflower seed soft bums fruit cake: How to cook it? Check The Complete Air Fryer Cookbook
Step 5: Now, you just need to shape the mixture into the ball and put them on the baking paper. You can have a different shape as you want. After that, cover them with egg wash above. Step 6: After that, the dough needs proofing again in 45 minutes to have doubled in size and have all of them in a warm condition. Step 7: After 45 minutes, take it out and spray them with a water to provide extra moisture. Then, bake them in the air fryer at 160 degrees C for 5 minutes. Step 8:
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2,379
msmarco_v2.1_doc_00_5886646#6_8593744
http://1cupawesome.com/air-fryer-bread-recipe/
Air fryer bread recipe
Air fryer bread recipe Air fryer bread recipe The estimated time to cook: Ingredients for pumpkin and sunflower seed soft bums fruit cake: How to cook it? Check The Complete Air Fryer Cookbook
After that, the dough needs proofing again in 45 minutes to have doubled in size and have all of them in a warm condition. Step 7: After 45 minutes, take it out and spray them with a water to provide extra moisture. Then, bake them in the air fryer at 160 degrees C for 5 minutes. Step 8: After all, you just need to brush the bun with some butter and enjoy it. While mixing the ingredients, you should do until they are no longer sticky but shiny and smooth. Also, please prevent all the wind from the dough to be not dry them and you can speed up the proofing time by a kitchen with warmer temperature. Check The Complete Air Fryer Cookbook
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msmarco_v2.1_doc_00_5889827#0_8594797
http://1cupawesome.com/air-fryer-salmon-recipe/
Air fryer salmon recipe 1 Cup Awesome Random Awesomeness Recipes BUYING GUIDES Air fryer You are here: Home/Recipes/Air fryer salmon recipe Air fryer salmon recipe May 12, 2016Awesome Admin Facebook0 Twitter0 Google+0 Pinterest43 LinkedIn0 How to make salmon using air fryer Air fryer is not only born to fry. With this machine, you can not only make fried fish, roast potatoes but also crispy French fries, chicken wings, and many other amazing dishes. Moreover, you can also use your great air fryer to cook meat, steak and even fish. In this post, we will provide you with very basic and simple steps to cook salmon using your air fryer. Just after following this recipe, you will easily do it yourself. The estimated time to cook salmon: In general, the salmon will take you about 15 minutes to be ready to be served. This time includes the preparation times and cooking time in from about 8 to 12 minutes. However, you can adjust this figure due to the thickness of the salmon and your taste.
0
998
msmarco_v2.1_doc_00_5889827#1_8595998
http://1cupawesome.com/air-fryer-salmon-recipe/
Just after following this recipe, you will easily do it yourself. The estimated time to cook salmon: In general, the salmon will take you about 15 minutes to be ready to be served. This time includes the preparation times and cooking time in from about 8 to 12 minutes. However, you can adjust this figure due to the thickness of the salmon and your taste. Ingredients for salmon: The ingredients here are simply some slice of salmon and your favorite spices. You can choose the spices that you want or are the best for your taste. For one server, you will need a slice of salmon. – Slice of salmon – Salt – Lemon juice – Olive oil – And any other spices you want How to cook salmon using your air fryer?
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1,346
msmarco_v2.1_doc_00_5889827#2_8596924
http://1cupawesome.com/air-fryer-salmon-recipe/
Ingredients for salmon: The ingredients here are simply some slice of salmon and your favorite spices. You can choose the spices that you want or are the best for your taste. For one server, you will need a slice of salmon. – Slice of salmon – Salt – Lemon juice – Olive oil – And any other spices you want How to cook salmon using your air fryer? After preparing all the ingredients you need for the salmon, let’s start to cook your salmon with your air fryer right now. Step 1: Firstly, you should take the salmon out of the refrigerator and leave it some minutes outside. Step 2: After that, let’s use your favorite spices including salt, olive, lemon juice or anything else to season the salmon.
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