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All ideal gases at a temperature of 25 ºC and pressure of 10 bar have the same:
Density.
Number of molecules per unit of volume.
Number of moles.
Chemistry
Molecular mass.
161
1
b4754479-efbf-4318-8e8d-b918be92ace5
2020
The chemical reaction: A(g) ↔ 2 B (g) is exothermic and is in equilibrium under given P and T conditions. The equilibrium constant is K0. When the temperature increases:
K0 decreases.
K0 increases.
It cannot be predicted what will happen, it will depend on the value of the standard entropy change.
Chemistry
K0 does not vary.
162
2
a4dcece2-6859-4c4b-ac7d-4ec77ef3857e
2020
A gas can be considered to behave in an ideal manner:
At high pressures and high temperatures.
At high pressures and low temperatures.
At low pressures and low temperatures.
Chemistry
At low pressures and high temperatures.
164
3
42bab228-765d-498c-9525-72bb929428f9
2020
The Clausius-Clapeyron equation is strictly adhered to in the phase transition:
Freezing of cyclohexane at 6.5 ºC.
Conversion of diamonds under pressure.
Conversion of diatomic oxygen, O2 (g), into triatomic ozone, O3 (g).
Chemistry
Sublimation of ice in the freezer.
167
3
9e585d77-877a-49a4-b395-a86cb303fccc
2020
In which units is the rate constant of a chemical reaction expressed?
If the overall order of the reaction is one, in mol.L-1s-1.
If the reaction is of zero order, in mol.L-1s-1.
If the overall order of the reaction is three, in s-1.
Chemistry
If the reaction is of zero order with respect to one reagent and of first order with respect to another, in mol.L-1s-1.
168
1
b27cb1f1-9649-41e5-b13b-3bf22ad51a1a
2020
A gas can be liquefied through isothermal compression:
At its critical temperature.
At temperatures higher than its critical temperature.
At any temperature.
Chemistry
At temperatures lower than its critical temperature.
169
3
da895272-9251-4640-b539-488daebdc35f
2020
Non-ideal (real) gases tend to behave ideally at :
Low temperatures and high pressures.
Low temperatures and low pressures.
High temperatures and high pressures.
Chemistry
High temperatures and low pressures.
170
3
74cbcaa7-477f-4828-9469-dcc26997d09d
2020
Which of the following statements can be proven from the second law of thermodynamics:
The entropy of an isolated system must remain constant.
In a closed system, equilibrium corresponds to the position of maximum entropy of the system.
The entropy of a closed system can never decrease.
Chemistry
For a system enclosed in impermeable adiabatic walls, the entropy of the system is maximized at equilibrium.
171
4
4ef89137-cbcc-42de-9476-d2b30319b349
2020
If under certain conditions the fugacity of a gas is greater than the pressure, what would we say about the interactions between the gas molecules?
Repulsive interactions dominate.
The attractive and repulsive interactions are balanced.
Attractive interactions dominate.
Chemistry
The gas is ideal, there are no interactions between the gas molecules.
172
2
1233868a-c9d1-40f1-9100-edc3040966fa
2020
In a reactor where a chemical reaction takes place between ideal gases, how does the isochoric addition of an inert gas at constant temperature affect the equilibrium?
Increases the conversion of reactants into products.
It does not modify the equilibrium conversion.
Increase the concentration of the reactants.
Chemistry
Decreases the conversion of reactants into products.
173
1
54ee620c-ba5c-44bc-8a01-85e244e61bc9
2020
In an electrolysis experiment, an electric current of 0.10 A circulates through a 10cm2 surface electrode and through a solution with a conductivity of 0.010 Ω-1cm-1. The intensity of the electric field is:
100 V cm-1.
0.10 A.
100 J C-1.
Chemistry
100 N C -1.
174
3
efd163f9-ed1c-4dfb-a234-0317ee52ced7
2020
What is the Langmuir isotherm, in the context of adsorption on solid surfaces?
A function that relates the moles adsorbed with the amount of adsorbent present in the reaction medium.
A graph of the number of moles adsorbed as a function of temperature.
A physical adsorption model in which the formation of several layers on the surface of the adsorbent is taken into account.
Chemistry
An adsorption isotherm obtained assuming that only the first layer is coated on the adsorbent, that all its adsorption sites are equivalent, and that adsorption and desorption are non-cooperative processes.
175
3
c2e1a699-f9e4-447d-8285-5e16d34995f9
2020
In a mass spectrum, what is referred to as the base peak?
To the peak of the ion whose abundance is the smallest.
To the peak of the ion whose abundance is 0%.
To the peak of the ion whose abundance is 50%.
Chemistry
To the peak of the ion whose abundance is the greatest.
176
3
f014da83-59a3-473a-ab29-c52b9d42467c
2020
A technique widely used for protein separation is sodium dodecyl sulfate polyacrylamide gel electrophoresis (SDS-PAGE), in which sodium dodecyl sulfate (SDS) is used as a denaturing agent. In this technique, the proteins are separated:
Due to the difference in their isoelectric points.
Due to the difference in their molecular weight.
Due to the difference in their charge.
Chemistry
Due to the difference in their charge/radius ratio.
177
1
cba540bc-6bd9-4cb1-a7a0-bb8ba50f78fa
2020
The α helices of proteins are due to:
A random organization.
The formation of intramolecular hydrogen bonds between nearby residues.
To the absence of inter- or intramolecular hydrogen bridges.
Chemistry
The formation of intermolecular hydrogen bonds between neighboring residues.
178
1
1d4ce046-212e-4ffc-8f63-74d26656e4b4
2020
Which of the following biomolecules contains copper in the active center?:
Ascorbate oxidase.
Alcohol Dehydrogenase.
Vitamin B12.
Chemistry
Carbonic Anhydrase.
180
2
0599440e-0109-4ca8-a04e-0207ac7feb15
2020
Which of the following metal ions can be found in the active centers of superoxide dismutase enzymes?:
Mg2+.
Mn3+.
Co3+.
Chemistry
Cr3+.
181
1
36423899-40b6-4050-b041-ff2152e309b7
2020
Which of the following processes are catalyzed by Mn-catalase enzymes?:
2O2- + 2H+ → O2 + H2O2.
O2 + 4H+ + 4e- → 2H2O.
2H2O2 → 2H2O + O2.
Chemistry
2H2O → O2 + 4H+ + 4e-.
182
4
4ffaedcb-a459-42d0-a8cd-8352a9df6319
2020
If we ask for 96° alcohol in a pharmacy, they are selling us:
An azeotropic mixture of 96% alcohol and 4% water with a boiling point between the boiling point of water and the boiling point of alcohol.
Pure alcohol.
An azeotropic mixture of 96% alcohol and 4% water with a boiling point lower than the boiling point of water and the boiling point of alcohol.
Chemistry
Alcohol that has a boiling point of 96 °C.
183
4
f6033747-6dc7-4641-9812-8f79fc13d783
2020
The critical point of a pure substance:
It depends on the temperature at which it is determined.
It is the temperature that needs to be reached to liquefy a gas.
It is an invariant point of pressure and temperature for each substance.
Chemistry
It depends on the pressure at which it is determined.
184
4
eae01b91-e444-402f-9279-a8a7cc1e1bb3
2020
The mass balance of a saturated aqueous solution of the salt Ag3PO4 is:
[Ag+] = 3·([PO43-] + [HPO42-] + [H2PO4-] + [H3PO4])
3· [Ag+] = [PO43-] + [HPO42-] + [H2PO4-] + [H3PO4]
[Ag+] = [PO43-]3.
Chemistry
[Ag+] + [H+] = 3·([PO43-] + [HPO42-] + [H2PO4-]) + [OH-]
185
2
2d2974ec-ba73-4dc1-a103-5343f83f0ab3
2020