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=======================================================
Product ID: BENZOYL PEROXIDE CREAM HARDENER, 3609
Cage: CMPST
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: CMPST
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: HARMFUL OR FATAL IF SWALLOWED! IRRITANT WHEN IN CONTACT
WITH EYES OR WITH OPEN, ABRADED SKIN. TRACE AMOUNTS OF ETHYLENE OXIDE, A
SUBSTANCE WHICH MAY BE A HUMAN CARCINOGEN & A REPRODUCTIVE TOXICANT, MA Y
BE CONTAINED IN THIS PRODUCT. THE LEVEL IN THIS PRODUCT DOES NOT CONSTITUTE A
SIGNIFICANT RISK.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE
OXYGEN/ARTIFICIAL RESPIRATION) (FP N). EYES: FLUSH PROMPTLY W/COPIOUS AMOUNTS
OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ATTENTION IMMEDIATELY. SKIN:
WASH THORO W/SOAP & WATER. REMOVECONTAMINATED CLTHG & SEEK MEDICAL
ATTENTION IF NECESSARY. INGEST: RINSE MOUTH. DRINK A GLASS FULL OF
WATER/MILK. IF DISCOMFORT PERSISTS, SEEK MEDICAL ATTENTION.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: EXTINGUISH ALL SOURCES OF FLAME OR IGNITION. ABSORB
WITH INERT MATERIAL SUCH AS VERMICULITE OR SAND. SWEEP UP & COLLECT IN
CONTAINERS TO DISPOSE OF AS SOLID WASTE. WASH THE AREA WITH TRISODIUM PHOSPHA
TE & WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL REGULATIONS REGARDING WASTE.
Handling And Storage Precautions: STORE BELOW 100F IN COOL, DRY PLACE. KEEP
AWAY FROM SOURCES OF HEAT & IGNITION. USE EXPLOSION PROOF EQUIPMENT.
Other Precautions: OPEN CONTAINERS SLOWLY TO RELIEVE ANY INTERNAL PRESSURE. USE
WITH ADEQUATE VENTILATION. KEEP OUT OF REACH OF CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: 184F,84C
Extinguishing Media: DRY CHEMICAL, FOAM & CARBON DIOXIDE.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N). COOL SURROUNDING AREA WITH WATER.
Unusual Fire/Explosion Hazard: IF EXPOSED TO ELEVATED TEMPERATURE FOR EXTENDED
LENGTH OF TIME, AN EXPLOSIVE DECOMPOSITION MAY OCCUR.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: ANY COMBINATION OF LOCAL & GENERAL VENTILATION TO DRAW FUMES
AWAY FROM WORKERS.
Other Protective Equipment: PROTECTIVE CLOTHING, SHOES, ANSI APPRVD EYE WASH
STATION & SAFETY SHOWERS SHOULD BE AVAILABLE.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: P1
B.P. Text: DECOMPOSES
Vapor Density: <1
Spec Gravity: 1.2
Evaporation Rate & Reference: FASTER THAN DIETHYL ETHER
Appearance and Odor: PIGMENTED PASTE.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: STORAGE IN OPEN CONTAINERS, PROLONGED STORAGE
ABOVE 105F, EXPOSURE TO EXCESSIVE HEAT OR OPEN FLAMES.
Materials To Avoid: STRONG ACIDS, STRONG ALKALIS, STRONG OXIDIZERS, REDUCING
AGENTS, MINERAL ACIDS, METAL SALT CATALYSTS.
Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: BENZOYL PEROXIDE CREAM HARDENER, 3609
Cage: CMPST
Company Name: COMPOSITITE INC
Street: 265 S WEST ST
Zipcode: 45036
Label Required IND: Y
Date Of Label Review: 01/11/1994
Status Code: C
Label Date: 01/11/1994
Origination Code: G
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Moderate
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: HARMFUL OR FATAL IF SWALLOWED!
IRRITANT WHEN IN CONTACT WITH EYES OR WITH OPEN, ABRADED SKIN. CHRONIC: NONE
SPECIFIED BY MANUFACTURER.
=======================================================
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: SHAPE (0624A)
Cage: EO617
=======================================================
Contractor Summary
=======================================================
Cage: 28745
Cage: EO617
Box: 909
=======================================================
Ingredients
=======================================================
Cas: 1314-13-2
RTECS #: ZH4810000
% Wt: <0.1
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 63744-68-3
ACID COPOLYMER; (ACRYLATE COPOLYMER)
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 111-77-3
RTECS #: KL6125000
% Wt: 3-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 68527-08-2
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
Cas: 78-51-3
RTECS #: KJ9800000
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: NONE KNOWN. CHRONIC: NONE SPECIFIED BY
MANUFACTURER.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: NONE KNOWN TO MANUFACTURER.
Medical Cond Aggravated By Exposure: NONE KNOWN TO MANUFACTURER.
First Aid: EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SKIN: FLUSH WITH
WATER. INGESTION: DRINK LARGE QUANTITY OF WATER. INDUCE VOMITING. CALL MD.
INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXY GEN OR
ARTIFICIAL RESPIRATION) (FP N).
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: PICK UP WITH MOP OR WET VAC AND WASH AWAY WITH WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: WASH SML QTYS DOWN SEWER W/LGE AMT OF WATER. KEEP
SPILLS & CLEANING RUNOFFS OUT OF MUNICIPAL SEWERS & OPEN BODIED OF
WATER. LGE SPILLS SHOULD BE PICKED UP W/WET VAC/ABSORB MATL. LANDFILL/INCIN
SOLIDS. DISP OF LIQ PER LOC, STATE & FED REGS.
Handling And Storage Precautions: FREEZING OF PRODUCT MAY RUPTURE CONTAINER.
PRODUCT SHELF LIFE IS BEST RETAINED BY STORAGE AT 45-100F TEMPERATURES.
Other Precautions: INHALATION EXPOSURE TO SPRAY MIST SHOULD BE MAINTAINED AT
LESS THAN 10 MG/M3 PER EIGHT HOUR EXPOSURE (TWA LIMIT ESTABLISHED FOR
NUISANCE DUST).
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: NONE
Extinguishing Media: USE MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: MATERIAL MAY SPATTER IF TEMPERATURES EXCEED
BOILING POINT. POLYMER FILM CAN BURN.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE REQUIRED IF GOOD VENTILATION IS MAINTAINED. USE
NIOSH APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: LOCAL EXHAUST: NOT REQUIRED. MECHANICAL (GENERAL): SUGGESTED.
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N).
Work Hygienic Practices: DO NOT TAKE INTERNALLY. WASH CONTAMINATED CLOTHING AND
EQUIPMENT BEFORE REUSE.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 205F,96C
Vapor Pres: 18
Vapor Density: 1.0
Spec Gravity: 1.02 (H*2O=1)
Solubility in Water: APPRECIABLE
Appearance and Odor: CREAMY, WHITE EMULSION; NON-OBJECTIONABLE ODOR
Percent Volatiles by Volume: 83.7
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE KNOWN TO MANUFACTURER.
Hazardous Decomposition Products: NONE KNOWN TO MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: SHAPE (0624A)
Cage: EO617
Assigned IND: Y
Company Name: HILLYARD INDUSTRIES
Street: 302 N 4TH
PO Box: 909
Zipcode: 64502
Label Required IND: Y
Date Of Label Review: 10/31/1996
Status Code: C
Label Date: 10/31/1996
Origination Code: G
Skin Protection IND: YES
Signal Word: NONE
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: NONE KNOWN. CHRONIC: NONE SPECIFIED BY
MANUFACTURER.
=======================================================
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: TITANIUM PUTTY HARDENER, DE032
Cage: 16059
Resp. Party Other MSDS No.: 0619, PART NO. 0214
=======================================================
Contractor Summary
=======================================================
Cage: 16059
=======================================================
Ingredients
=======================================================
Cas: 32610-77-8
% low Wt: 30.
% high Wt: 50.
-----------------------------
Cas: 931-36-2
% low Wt: 5.
% high Wt: 10.
------------------------------
Cas: 112-24-3
RTECS #: YE6650000
% low Wt: 1.
% high Wt: 10.
------------------------------
Cas: 108-95-2
RTECS #: SJ3325000
< Wt: 5.
Other REC Limits: 5 PPM CANADA (MFR)
OSHA PEL: 19 MG/M3;5 PPM
ACGIH TLV: 19 MG/M3;5 PPM
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 14807-96-6
RTECS #: WW2710000
% low Wt: 10.
% high Wt: 30.
Other REC Limits: NIOSH 2MG/M3 (MFR)
OSHA PEL: see Table Z-3
ACGIH TLV: 2 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 65997-17-3
% low Wt: 5.
% high Wt: 20.
OSHA PEL: 5 MG/M3 (RESIN)
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 14808-60-7
RTECS #: VV7330000
< Wt: 1.
Other REC Limits: OSHA 0.1 MG/M3 (MFR)
OSHA PEL: see Table Z-3
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50: (ORAL,RAT) >2200 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: SKIN: SEV IRRITANT. POTNTL SENSITIZER. EYES: SEV
IRRITANT. INHAL: IRRIT OF NOSE & THROAT; NAUS & VOMIT IN SEV CASES.
INGEST: MAY CAUSE BLEEDING OF GI TRACT & VOMIT OF BLOOD. CHRONIC: RPTD
SKINCONT CAN CAUSE SENSITIZ, W/ITCHING, RASHES/SWELL OF SKIN. TETA MAY
CAUSE RESP SENSITIZ & CHRONIC LUNG TOXICITY (COUGH, TIGHTNESS OF CHEST,
SHORTNESS OF BREATH). OTHER EFTS: RPTD AND/OR PRLNGD EXPOSURE TO LOW CONCS
OF VAP MAY CAUSE :SORE THROAT, EYE IRRIT, NAUS, FAINTNESS, HDCH, WHICH ARE
TRANSIENT. RPTD AND/OR PRLNGD EXPOSURES MAY RSLT IN: ADVERSE SKIN EFTS (SUCH
AS DEFAT, RASH, IRRIT OR CORR), AD VERSE EYE EFTS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA., CRYSTALLINE-QUARTZ: IARC MONOGRAPHS,
SUPPLEMENT. VOL68 , PG 41, 1997: GROUP 1. NTP 7TH ANNUAL RPT ON CARCINOGENS,
1994: ANTICIPATED TO BE CARCINOGEN.
Signs And Symptions Of Overexposure: EFTS OF OVEREXP: (SUCH AS CONJ/CORNEAL
DMG). PHENOL IS HUMAN POISON BY INGESTION.
Medical Cond Aggravated By Exposure: ASTHMA. CHRONIC RESPIRATORY DISEASE (E.G.
BRONCHITIS, EMPHYSEMA). EYE DISEASE. SKIN DISORDERS AND ALLERGIES.
First Aid: EYES: IMMED FLUSH W/CLEAN WATER FOR AT LST 15 MINS WHILE GENTLY
HOLDING EYELIDS OPEN. GET MED HELP AS SOON AS POSSIBLE. SKIN: IMMED REMOVE
CONTAMD CLTHG & SHOES & WASH WELL W/SOAP & WATER. SEE MD IF I
RRIT DEVELOPS. INHAL: REMOVE TO FRESH AIR. GIVE OXYG/ARTF RESP IF NEEDED. SEE
MD IF SYMPTOMS PERSIST. INGEST: DO NOT INDUCE VOMIT. DILUTE W/LOTS OF
MILK/WATER & GET IMMEDIATE MEDICAL HELP.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AVOID PERSONAL CONTACT. ELIM IGNIT SOURCES. VENTILATE
AREA. DIKE, CNTN & ABSORB W/CLAY, SAND OR OTHER SUITABLE MATL. FOR LG
SPILLS, PUMP TO STORAGE/SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB SUCH AS CL
AY, SAND, OR OTHER SUITABLE MATL & DISPOSE OF PROPERLY. FLUSH W/WATER TO
REMOVE TRACE RESIDUE. PVNT SPILL FROM ENTERING DRAINAGE/SEWER SYS, WATERWAYS,
& SURFACE WATERS.
Waste Disposal Methods: IF THIS MATERIAL BECOMES WASTE, IT WOULD NOT BE
HAZARDOUS WASTE BY RCRA CRITERIA (40CFR 261). DISPOSE OF ACCORDING TO
APPLICABLE FEDERAL, STATE, AND LOCAL REGULATIONS.
Handling And Storage Precautions: CONT W/SKIN, EYES/CLTHG. WASH THORO W/SOAP
& WATER AFTER USING & PARTICULARLY BEFORE EATING, DRINKING, SMOKING,
APPLYING COSMETICS/USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG & PROT
GEAR BEFORE REU SE. DISCARD CONTAMD LEATHER ARTICLES.
Other Precautions: HNDL MIXED RESIN & HARDENER I/A/W POTNTL HAZARD OF
CURING AGENT USED. PROVIDE APPROP VENT/NIOSH APPRVD RESP PROT AGAINST DECOMP
PRODS(SEE STABILITY & REACTIVITY SECTION) DURING WELDING/FLAME CUTTING O
PEATIONS & TO PROTECT AGAINST SILICA DUST DURING SANDING/GRINDING OF
CURED PRODUCT. (SUPDAT)
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point: =136.1C, 277.F
Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N).
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: TOXIC FUMES WILL BE RELEASED WHEN THIS MATL
BURNS OR IS THERMALLY DECOMPOSED. OXIDES OF CARBON, OXIDES OF NITROGEN,
AMMONIA AND UNIDENTIFIED ORGANIC COMBUSTION PRODUCTS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE REQUIRED IN NORMAL USE WITH GOOD VENTILATION; IN
POORLY VENTILATED AREAS, WEAR NIOSH-APPROVED ORGANIC VAPOR MASK.
Ventilation: LOC EXHST IS REC FOR CONFINED AREAS & FOR PRLNGD/RPTD USE OF
PROD. GEN MECH VENT IS ADEQUATE FOR NORMAL USE.
Other Protective Equipment: OTHER PROTECTIVE GEAR AS REQUIRED TO PREVENT SKIN
CONTACT. EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N).
Work Hygienic Practices: WASH THORO W/SOAP & WATER AFTER USING & PARTICULARLY
BEFORE EATING, DRINKING, SMKNG, APPLYING COSMETICS/USING TOILET FACILITIES.
Supplemental Safety and Health: OTHER PREC: STORE IN COOL, DRY AREA AWAY FROM
HIGH TEMPERATURES AND FLAMES. PH: (5% SOLUTION/SLURRY IN WATER): 9.5-10.0.
VOC (GRAMS/LITER): 0.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >176.7C, 350.F
Vapor Pres: <1 AT 70 F
Spec Gravity: 1.78
PH: SUPDAT
Solubility in Water: APPRECIABLE
Appearance and Odor: OFF-WHITE PASTE WITH AMMONIACAL ODOR.
Percent Volatiles by Volume: 0
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXPOSURE TO OPEN FLAME OR EXTREME HEAT.
Materials To Avoid: STRONG OXIDIZING AGENTS, ACIDS, AND CHLORINATED ORGANIC
COMPOUNDS.
Hazardous Decomposition Products: OXIDES OF NITROGEN AND CARBON, AMMONIA.
Hazardous Polymerization Indicator: YES
Conditions To Avoid Polymerization: HEAT IS RELEASED WHEN MATL IS MIXED W/EPOXY
RESIN; BE CAREFUL WHEN MIXING A POUND OR MORE.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: ACUTE DERMAL EFTS: MOD IRRIT TO SKIN OF RABBIT.
PHENOL RAPIDLY ABSORB THRU SKIN & CAN CAUSE DEATH. EYE IRRIT: SEV IRRIT
OF RABBIT. OTHER CHRONIC EFTS: GEN OBSERVED IN ANIMAL STUDIES THAT
ALIPHATIC AMINES CAN CAUSE CHANGES IN LUNGS & HEART. TETA FOUND TO PROD
LIVER & KIDNEY DAMAGE& BRAIN CONGESTION IN DERMALLY EXPOSED ANIMALS.
2-ETHYL-4-METHYLLMIDAZOLE:ORAL LD50 (RAT): 3400 MG/KG; DERMAL LD50 (RABBIT):
>2000 MG/KG; INHAL LC50 4HR,(RAT): >10 MG/L. TRIETHYLENETETRAMINE: ORAL
LD50(RAT): 2460 MG/KG; DERMAL LD50(RABBIT): 850 MG/KG. PHENOL: ORAL
LD50(RAT): 317 MG/KG; DERMAL LD50(RABBIT): 850 MG/ KG; INHAL LC50 4HR, (RAT):
316 MG/M3.
=======================================================
Ecological Information
=======================================================
Ecological: MOBILITY AND PERSISTENCE: PHENOL: BIODEGRADABILITY = 99.5% AT 7
DAYS.
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: FOR PURPOSES OF SARA SECTION 312 HAZARDOUS
MATERIALS INVENTORY REPORTING, THE FOLLOWING HAZARD CLASSES APPLY TO THIS
MATERIAL: IMMEDIATE HEALTH HAZARD - DELAYED HEALTH HAZARD
Federal Regulatory Information: TSCA: ALL INGREDIENTS OF THIS PRODUCT ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY. PHENOL: CERCLA RQ
(LBS): 1000.0.
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: TITANIUM PUTTY HARDENER, DE032
Cage: 16059
Company Name: DEVCON CORP
Street: 30 ENDICOTT ST
Zipcode: 01923-3753
Label Required IND: Y
Date Of Label Review: 09/09/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: Slight
Hazard And Precautions: HAZ POLYMERIZATION MAY OCCUR. ACUTE: SKIN: SEV IRRIT.
EYES: SEV IRRIT. INHAL: IRRIT OF NOSE & THROAT; NAUS & VOMIT.
INGEST: BLEEDING OF GI TRACT & VOMIT OF BLOOD. CHRONIC: CANCER HAZ.
CONTAINS SIL ICA, CRYSTALLINE QUARTZ WHICH IS LISTED AS A HUMAN LUNG
CARCINOGEN (FP N). CAN CAUSE SKIN SENSITIZ, W/ITCHING, RASHES/SWELLING. RESP
SENSITIZ & LUNG TOXICITY. RPTD/PRLNGD EXPOS TO LOW CONCS OF VAP MAY
CAUSE: SORE THROAT, EYE IRRIT, NAUS, FAINTNESS, HDCH, WHICH ARE TRANSIENT.
RPTD/PRLNGD EXPOS MAY RSLT IN ADVERSE SKIN EFTS (SUCH AS DEFAT, RASH,
IRRIT/CORR), ADVERSE EYE EFTS (SUCH AS CONJ/CORNEAL DA M). PHENOL HUMAN
POISON.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RTV162
CAGE:01139
CAGE:01139
============= Composition/Information on Ingredients =============
Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT
===================== Hazards Identification =====================
Effects of Overexposure:EYE CONTACT MAY CAUSE TRANSIENT IRRIT.
======================= First Aid Measures =======================
First Aid:FLUSH EYES WITH WATER FOR 15 MIN.IF IRRIT.PERSISTS HAVE
WORKER EXAMINED BY A MD.
===================== Fire Fighting Measures =====================
Flash Point:400F,204 C TOC
Extinguishing Media:ALL STANDARD FIREFIGHTING AGENTS.
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE UP OR SCRAPE UP AND DISPOSE IN WASTE
RECEPTACLE.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.05
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE PASTE,MILD ALCOHOL ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Hazardous Decomposition Products:AT TEMP.>400F, CO*2 AND SIO*2 ARE
PRODUCED.
==================== Disposal Considerations ====================
Waste Disposal Methods:THIS MATERIAL WHEN DISCARDED IS NOT A HAZARDOUS
WASTE PER FED.REGULATIONS 40CFR PART 261. DISPOSAL SHOULD BE IAW
APPLICABLE STATE AND LOCAL ORDANCES FOR THE DISPOSAL OF INDUSTRIAL
WASTE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:NEUTRAL AQUEOUS DEVELOPER
CAGE:02687
CAGE:02687
============= Composition/Information on Ingredients =============
Ingred Name:OCTYL SODIUM SULFATE
CAS:142-31-4
RTECS #:WT1175000
Fraction by Wt: 3%
Ingred Name:LITHIUM BENZOATE
CAS:553-54-8
RTECS #:OJ5720000
Fraction by Wt: 7.5%
Ingred Name:WATER, H2O
CAS:7732-18-5
RTECS #:ZC0110000
Ingred Name:POTASSIUM SORBATE
CAS:590-00-1
RTECS #:WG2160000
Fraction by Wt: 2.5%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INGESTION:
VOMITING, DIARRHEA, DROWSINESS, MUSCULAR WEAKNESS, & LACK OF
COORDINATION, CNS EFFECTS, KIDNEY DAMAGE, THYROID DISTURBANCES, GI
DISTURBANCES. INHALATION: RESPIRATORY PASSAGES IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN/EYES: IRRITATION. INGESTION: VOMITING,
DIARRHEA, DROWSINESS, MUSCULAR WEAKNESS, & LACK OF COORDINATION,
CNS EFFECTS, KIDNEY DAMAGE, THYROID DISTURBANCES, GI DISTURBANCES.
INHALATION: RESPIRATORY PASSAGES IRRITATION.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH THOROUGHLY W/WATER FOR 15 MINS. SKIN: WASH W/SOAP
& WATER. INGESTION/INHALATION: OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>212F
Extinguishing Media:NON-FLAMMABLE
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING.
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT INTO SUITABLE CONTAINER. RINSE
RESIDUAL W/WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT W/SKIN & CLOTHING.
CONTACT LENSES SHOULDN'T BE WORN WHEN WORKING WITH THIS CHEMICAL.
============= Exposure Controls/Personal Protection =============
Ventilation:LOCAL EXHAUST
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
pH:7.0
Appearance and Odor:COLORLESS LIQUID, MILD DETERGENT ODOR.
Percent Volatiles by Volume:86%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS
Hazardous Decomposition Products:CO2, CO, OXIDES OF SULFUR, & TOXIC
FUMES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. THIS PRODUCT, AS SHIPPED, WOULDN'T BE A
HAZARDOUS WASTE UNDER RCRA WHEN DISPOSED OF.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CHEVRON UNLEADED GASOLINE, PRODUCT CODE:CPS201110
Preparer's Name:(MSDS#:000372)
CAGE:0AHD1
CAGE:0AHD1
CAGE:7W738
CAGE:9V384
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL BENZENE (SARA III)
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: <1.4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/125STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:P-XYLENE (P-DIMETHYLBENZENE) (SARA III)
CAS:106-42-3
RTECS #:ZE2625000
Fraction by Wt: <0.9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:M-XYLENE (M-DIMETHYLBENZENE) (SARA III)
CAS:108-38-3
RTECS #:ZE2275000
Fraction by Wt: <4.6%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/15OSTEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:O-XYLENE (O-DIMETHYLBENZENE) (SARA III)
CAS:95-47-6
RTECS #:ZE2450000
Fraction by Wt: <2.2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100PPM
ACGIH TLV:100 PPM/150STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: <6.5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:HEXANE (N-HEXANE)
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: <3.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CYCLOHEXANE (SARA III)
CAS:110-82-7
RTECS #:GU6300000
Fraction by Wt: <2.4%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM, 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL TERT-BUTYL ETHER (SARA III)
CAS:1634-04-4
RTECS #:KN5250000
Fraction by Wt: <15.0%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:BENZENE (SARA III)
CAS:71-43-2
RTECS #:CY1400000
Fraction by Wt: <4.9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1028
ACGIH TLV:10 PPM; A2; 9394
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:GASOLINE, CHEVRON UNLEADED GASOLINE (GENERIC), WHICH
CONTAINS INGREDS #1-10.
CAS:8006-61-9
RTECS #:LX3300000
Fraction by Wt: 100.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM/500STEL;9394
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL,RATS)=>5ML/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE:SLIGHTLY IRRIT,MAY CAUSE
PROLONG(DAYS)IMPAIRMENT OF VISION. SKIN:PROL/REP CONTACT MAY CAUSE
SKIN TO CRACK/DRY FROM DEFATTING.NON-TOXIC IF ABSORBED THRU SKIN.
INHAL/INGEST:SLIGHTLY TOXIC TO INTERNA L ORGANS.INHAL:EFFECTS
CNS,LOSS OF CONSC,COMA/DEATH.PUL EDEMA,BRONCHITIS. INGEST:EFFECTS
CNS.ASPIRATION MAY OCCUR
Explanation of Carcinogenicity:CONTAINS BENZENE. GASOLINE CONSIDERED TO
BE POTENTIAL CARCINOGEN BY IARC.
Effects of Overexposure:EYE:PAIN, TEARS, SWELLING, REDNESS, BLURRED
VISION. INHAL:HEADACHE, DIZZ, LOSS OF APPETITE, WEAKNESS, LOSS OF
COORDINATION. COMA, DEATH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MFG.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH IMMED W/FRESH WATER FOR @ LEAST 15MINS LIFTING
EYELIDS.REMOVE CONTACT LENSES IF WORN.IRRIT PERSISTS SEE DR.
SKIN:AS PRECAUTION WASH THOROUGHLY W/SOAP & WATER.REMOVE CONTAMIN
CLOTH. INHAL:MOV E TO FRESH AIR IF IRRIT/SYMP OCCUR.IF CONTINUE SEE
DR. INGEST:GIVE WATER OR MILK TO DRINK.GET MED ADVICE/EMERG
RM/CNTR.DO NOT INDUCE VOMIT UNLESS DIRECTED TO DO SO BY MED
PERSONNEL. (SEE SUPPLE)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:<-49F,<-45C
Lower Limits:1.4
Upper Limits:7.6
Extinguishing Media:FIRE FIGHTING FOAM:ALCOHOL RESISTANT TYPE (AR),
AFFF, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:DO NOT ENTER ENCLOSE/CONFINE FIRE SPACE W/O
PPE INCLUDING SELF-CONTAINED BREATH APPARATUS TO PROTECT AGAINS HAZ
COMBUST PRODUCTS/OXY DEFICIENCY.READ ENTIR MSDS.
Unusual Fire/Explosion Hazard:EXTREME FIRE HAZ.VERY QUICKLY EVAPORATES
EVEN @ LOW TEMP.FORMS VAP WHICH CAN CATCH FIRE & BURN W/EXPLOSIVE
VIOLENCE.VAP SPREADS EASILY & SET ON FIRE BY IGN SOUR
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL IGN SOURCES.CLEANUP IMMED W/SORBENT
MATL.OBSERVE PROT EMPMT SEC.CONSIDER A WATER POLLUTANT & RELEASES
SHOULD BE PREVENTED FROM CONTAMIN SOIL/WATER/ENTERING
DRAINAGE/SEWER.IF SO REPORT TO US COAST GUARD NAT RESP CNTR
800-424-8802.
Neutralizing Agent:NONE SPECIFIED BY MFG.
======================Handling and Storage ======================
Handling and Storage Precautions:NEVER SIPHON BY MOUTH.READ/OBSERVE ALL
PRECAUTIONS ON PRODUCT LABEL.USE ONLY AS MOTOR FUEL.DO NOT USE FOR
CLEANING/PRESSURE APPLIANCE FUEL/OTHER USE.
Other Precautions:DO NOT USE/STORE NEAR FLAME/SPARKS/HOT SURFACES.USE
ONLY IN WELL VENTILATED AREA.KEPP CNTNR CLOSED.DO NOT TRANSFER LIQ
TO AN UNLABELED CNTNR.DO NOT WELD/HEAT/DRILL CNTNR.REPLACE
CAP/BUNG.EMPTIED CNTNR STILL CONTAINS HAZ/EXPLOSIVE VAP/LIQ.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO SPECIAL RESP PROT IS NORMALLY
REQUIRED.HOWEVER IF OPERATING CONDITIONS CREATE AIRBORNE CONCEN
WHICH EXCEED RECOMMENDED EXPOSURE STDS USE OF APPROVED RESP IS
REQUIRED.REFER TO OSHA BENZENE STD TO DE TERMINE TYP OF RESP BASED
ON EXP LEVELS.
Ventilation:USE THIS MATERIAL ONLY IN WELL VENTILATED AREAS.
Other Protective Equipment:PROTECTIVE CLOTHING TO MIN SKIN CONTACT.
Work Hygienic Practices:WASH CONTAMIN CLOTHING PRIOR TO REUSE. FOLLOW
GOOD WORK HYG PRACTICES.
Supplemental Safety and Health
PHYSICIAN:INGEST OF PRODUCT OR SUBSEQUENT VOMITING CAN RESULT IN
ASPIRATION OF LIGHT HYDROCARBON LIQ WHICH CAN CAUSE PNEUMONITIS.
================== Physical/Chemical Properties ==================
HCC:F1
Boiling Pt:B.P. Text:23.0F,-5.0C
Vapor Pres:5-15PSI
Vapor Density:3-4
Spec Gravity:0.7-0.8
Solubility in Water:INSOLUBLE.
Appearance and Odor:ORANGE TO BRONZE LIQUID.
Percent Volatiles by Volume:99+
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY REACT W/STRONG OXIDIZNG AGENTS SUCH AS CHLORATES, NITRATES,
PEROXIDES, ETC.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, AND OTHER
SOURCES OF IGNITION.
Hazardous Decomposition Products:NORMAL COMBUSTION FORMS CARBON DIOXIDE
AND WATER VAPOR; INCOMPLETE COMBUSTION CAN PRODUCE CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:PLACE CONTAMIN MATLS IN DISPOSABLE CNTNRS &
DISPOSE OF IN A MANNER CONSISTANT W/APPLICABLE REGS.CONTACT LOC
ENVIRO/HEALTH AUTHORITIES FOR APPROVED DISPOSAL OF MATL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GUN SCRUBBER
Preparer's Name:DEREK J BEMIS
CAGE:51243
CAGE:51243
============= Composition/Information on Ingredients =============
Ingred Name:CARBON DIOXIDE
CAS:124-38-9
RTECS #:FF6400000
Fraction by Wt: 2-20%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5000 PPM
ACGIH TLV:5000PPM9394
Ingred Name:1,1,1-TRICHLOROETHANE (SARA III)
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 80-98%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:350 PPM
ACGIH TLV:350 PPM/450STEL;9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS UNKNOWN.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: IRRITATION. SKIN:
IRRITATION. INHALATION: CNS DEPRESSION, HEADACHES, NAUSEA,
DIZZINESS, LOSS OF CONSCIOUSNESS. INGESTION: NOT LIKELY SOURCE OF
EXPOSURE. CHRONIC: PROLONGED CONTACT COULD R ESULT IN PERMANENT EYE
DAMAGE AND DEFATTING OF SKIN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: IRRITATION, EYE DAMAGE. SKIN: IRRITATION,
DEFATTING. INHALATION: CNS DEPRESSION, HEADACHE, NAUSEA, DIZZINESS,
LOSS OF CONSCIOUSNESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED
CLOTHING. WASH SKIN AREA WITH SOAP AND WATER. IF IRRITATION
DEVELOPS, GET MEDICAL ATTE NTION. INHALATION: MOVE TO FRESH AIR.
ADMINISTER OXYGEN OR CPR IF NEEDED AND GET MEDICAL ATTENTION.
INGESTION: GET MEDICAL ATTENTION. TREATMENT IS DEPENDENT ON
CONDITION OF VICTIM.
===================== Fire Fighting Measures =====================
Flash Point:NOT FLAMMABLE
Lower Limits:7
Upper Limits:15
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:SCBA AND PROTECTIVE CLOTHING SHOULD BE WORN IN
FIGHTING FIRES INVOLVING CHEMICALS. AVOID ACCUMULTIONS OF VAPORS AT
FLOOR LEVEL, AS VAPOR IS HEAVIER THAN AIR.
Unusual Fire/Explosion Hazard:AVOID POSSIBLE BURSTING OF AEROSOL CAN.
DO NOT STORE WHERE TEMPERATURE MAY EXCEED 120F. DO NOT PUNCTURE OR
INCINERATE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA WELL. SOAK UP ON SUITABLE
ABSORBENT MATERIAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM
FIRE, SPARKS, OR FLAME. DO NOT STORE WHERE TEMPERATURES MAY EXCEED
120F.
Other Precautions:DO NOT USE NEAR HEAT, FIRE, FLAME, OR SPARKS. AVOID
EXCESSIVE BREATHING OF VAPOR. DO NOT SPRAY IN DIRECTION OF BODY.
USE ONLY IN ACCORDANCE WITH DIRECTIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NECESSARY UNDER NORMAL USE. IF TLV EXCEEDED
OR IN CONFINED AREAS USE NIOSH/MSHA APPROVED SELF-CONTAINED
BREATHING DEVICE OR RESPIRATOR.
Ventilation:MUST BE ADEQUATE TO MAINTAIN VAPORS AT LESS THAN 350 PPM,
PARTICULARLY AT FLOOR LEVEL AS VAPORS ARE HEAVIER THAN AIR.
Other Protective Equipment:NORMALLY NOT NECESSARY.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:AEROSOL
Vapor Pres:90 PSIG
Vapor Density:4.3
Spec Gravity:1.30
Evaporation Rate & Reference:<1 (ETHER = 1)
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR LIQUID. CHLORINATED ODOR.
Percent Volatiles by Volume:97
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ALKALIES, ALUMINUM.
Stability Condition to Avoid:HEAT, SPARKS, FLAMES. DO NOT STORE AT
TEMPERATURES ABOVE 120F.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
HYDROGEN CHLORIDE VAPORS, TRACES OF PHOSGENE, AND UNIDENTIFIED
ORGANIC MATERIALS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS. DO NOT PUNCTURE OR INCINERATE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TYPE 1, ALIPHATIC ISOCYANATE
Preparer's Name:ERNEST CARTER
CAGE:33461
CAGE:33461
============= Composition/Information on Ingredients =============
Ingred Name:TOLUENE
CAS:108-88-3
RTECS #:XS5250000
= Wt:15.
OSHA PEL:SEE TABLE Z-2
ACGIH TLV:188 MG/M3;50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL ISOBUTYL KETONE
CAS:108-10-1
RTECS #:SA9275000
= Wt:40.
OSHA PEL:410 MG/M3;100 PPM
ACGIH TLV:205 MG/M3;50 PPM
ACGIH STEL:307 MG/M3;75 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:1,3,5-TRIS(6-HYDROXYHEXYL)BIURET TRIISOCYANATE
CAS:4035-89-6
RTECS #:NR0195000
= Wt:45.
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VAPORS ARE IRRITATION TO EYES, NOSE
AND THROAT. INHALATION MAY CAUSE HEADACHES, DIFFICULT BREATHING AND
LOSS OF CONSCIOUSNESS. AS A RESULT OF PREVIOUS REPEATED
OVEREXPOSURE OR A SINGLE LARGE DOSE, CER TAIN INDIVIDUALS WILL
DEVELOP ISOCYANATE SENSITIZATION WHICH WILL CAUSE THEM TO REACT TO
A LATER EXPOSURE OF ISOCYANATE LEVELS WELL BELOW THE TLV VALUE OF
ISOCYANATES.
Effects of Overexposure:INHALATION: IRRITATION OF THE RESPIRATORY TRACT
& ACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY THE FOLLOWING
PROGRESSIVE STEPS: HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION,
UNCONSCIOUSNESS ORCOMA. SKIN: ISOCYANATES REACT WITH SKIN PROTEIN
AND MOISTURE AND CAN CAUSE IRRITATION. SYMPTOMS MAY BE SWELLING,
REDNESS, AND RASH. EYES: LIQUID, AEROSOLS, OR VAPORS ARE IRRITATING
AND MAY CAUSE TEARI NG, REDNESS, AND SWELLING ACCOMPANIED BY A
STINGING SENSATION. INGESTION: ACUTE: CAN RESULT IN IRRITATION AND
POSSIBLE CORROSIVE ACTION IN THE MOUTH, STOMACH TISSUE AND
DIGESTIVE TRACT. VOMITING MAY C AUSE ASPIRATION OF THE SOLVENT,
RESULT
Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY
DISORDERS, SKIN ALLERGIES, ECZEMA, AND DERMATITIS. ISOCYANATE
SENSITIZATION.
======================= First Aid Measures =======================
First Aid:INHALATION: MOVE TO AN AREA FREE FROM RISK OF FURTHER
EXPOSURE. RESTORE BREATHING. ASTHMATIC TYPE SYMPTOMS MAY DEVELOP
AND MAY BE IMMEDIATE OR DELAYED BY SEVERAL HOURS. OBTAIN MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREAS
THOROUGHLY WITH SOAP AND WATER, WASH CONTAMINATED CLOTHING
THOROUGHLY BEFORE REUSE. EYES: FLUSH WITH LUKE WARM WATER (LOW
PRESSURE) FOR AT LEAST 15 M INUTES, OCCASIONALLY LIFTING EYELIDS,
OBTAIN MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. DO NOT
GIVE ANYTHING TO AN UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=7.2C, 45.F
Lower Limits:1.00%
Upper Limits:8.00%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG,
WATER SPRAY.
Fire Fighting Procedures:FULL FIRE FIGHTING EQUIPMENT WITH SELF
CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING SHOULD
BE WORN BY FIRE FIGHTERS. WATER MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD UP, AUTO IGNITION OR
EXPLOSION. DURING A FIRE HDI VAPORS AND OTHER IRRITATING VAPORS MAY
BE GENERATED BY COMBUSTION OR
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, SPARKS, ELECTRICAL EQUIPMENT AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. APPLICATION TO
HOT SURFACES REQUIRES SPECIAL PRECAUTIONS. DURING EMERGENCY
CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A
HEALTH HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES).
VENTILATE AREA CONTAIN AND REMOVE WITH INERT ABSORBENT AND
NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN BUILDINGS DESIGNED TO COMPLY
WITH OSHA 1910.106 AVOID STORING NEAR HIGH TEMPERATURES, FIRE, OPEN
FLAMES, AND SPARK SOURCES. STORE IN TIGHTLY CLOSED CONTAINERS.
STORE IN WELL VENTILATED AREAS.
Other Precautions:KEEP CONTAINERS TIGHT AND UPRIGHT TO PREVENT LEAKAGE.
PREVENT PROLONGED BREATHING OF VAPORS OR SPRAY MISTS. PROLONGED
OVEREXPOSURE MAY CAUSE AN ALLERGIC REACTIO. AVOID CONTACT WITH SKIN
AND EYES. DO N OT TAKE INTERNALLY. DO NOT HANDLE UNTIL THE
MANUFACTURERS SAFETY PRECAUTIONS HAVE BEEN READ AND UNDE RSTOOD.
WASH HANDS B
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATOR THAT IS RECOMMENDED OR APPROVED FOR
USE IN AN ORGANIC VAPOR ENVIRONMENT (AIR PURIFYING OR FRESH AIR
SUPPLIED) IS NECESSARY. OBSERVE OSHA REGULATIONS FOR RESPIRATOR
USE. VENTILATION SHOULD BE APPROVED TO KEEP EXPOSURE LEVELS BELOW
THE OSHA PERMISSIBLE LIMITS.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE
CONCENTRATIONS OF SOLVENT, HDI AND POLYISOCYANATES BELOW THEIR
RESPECTIVE TLV'S MUST BE UTILIZED.
RUBBER, POLYETHYLENE) TO P
SHIELDS.
Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING
IS RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:230-428 DEG.F
Vapor Density:HEAVIER
VOC Pounds/Gallon:495
VOC Grams/Liter:7.78
Viscosity:THIN LIQUID TO HEAVY
Evaporation Rate & Reference:1.39
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume:61.2%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH
REACT WITH ISOCYANATES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND
OXIDES OF NITROGEN, TRACES OF HCN AND HDI.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MUST BE DISPOSED OF IN ACCORADNCE WITH
FEDERAL, STATE, AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY
CONTAINERS MUST BE HANDLED WITH CARE, DUE TO PRODUCT RESIDUE AND
FLAMMABLE VAPOR DO NOT INCINERATE CLOSED CONTAINERS.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
THE EMERGENCY PLANNING AND COMMUNITY TO KNOW 1986 AND 40 CFR 372:
108-83-3 TOLUENE, 108-20-3METHYL ISOBUTYL KETONE
State Regulatory Information:THIS PRODUCT CONTAINS A CHEMICAL KNOWN BY
THE STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER
REPRODUCTIVE HARM. 108-83-3.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:VCL-101
Preparer's Name:MARGARITA KHARSHAN
CAGE:GO488
CAGE:GO488
CAGE:44695
============= Composition/Information on Ingredients =============
Ingred Name:POLYURETHANE FOAM
Fraction by Wt: 9%
Ingred Name:CORROSION INHIBITOR PROPRIETARY
Fraction by Wt: 3.5%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 675 MG/KG
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES/SKIN: MAY CAUSE IRRITATION.
INGESTION: MAY BE HARMFUL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR 15 MINS. SKIN: WASH W/SOAP & WATER.
INHALATION: REMOVE TO AN UNCONTAMINATED AREA, ADMINISTER OXYGEN IF
NECESSARY. IF BREATHING HAS STOPPED, BEGIN CPR. INGESTION: GIVE
WATER/MIL K & INDUCE VOMITING. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, CO2/OTHER DRY CHEMICAL FIRE FIGHTING AGENTS
Fire Fighting Procedures:WEAR SCBA.
Unusual Fire/Explosion Hazard:POLYURETHANE FOAM BURNS VERY RAPIDLY
FORMING THICK SMOKE & POSSIBLE TOXIC DECOMPOSITION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT AS NORMAL SOLID WASTE.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID EYE CONTACT & PROLONGED/REPEATED
SKIN CONTACT. WORKERS SHOULD THOROUGHLY WASH HANDS W/SOAP & WATER
BEFORE EATING EATING, DRINKING/SMOKING.
Other Precautions:WORKERS SHOULD THOROUGHLY WASH HANDS W/SOAP & WATER
BEFORE USING LAVORATORY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NECESSARY
Ventilation:NOT NECESSARY
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Appearance and Odor:OFF WHITE TO YELLOW OPEN CELL FOAM W/SLIGHT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALIS AND OXIDIZING AGENTS
Hazardous Decomposition Products:CO, OXIDES OF NITROGEN, HYDROGEN
CYANIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:8010PX1-61 FLAT OLIVE DRAB
Preparer's Name:STEVE BUSSJAEGER
CAGE:ENVIR
CAGE:ENVIR
CAGE:0NWE2
============= Composition/Information on Ingredients =============
Ingred Name:2-BUTOXYETHANOL (ETHYLENE GLYCOL MONOBUTYL ETHER), BUTYL
CELLOSOLVE, BUTYL GLYCOL, GLYCOL ETHER EB * 96-1 *
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 3-5%
Other REC Limits:25 PPM (SKIN)
OSHA PEL:50 PPM (SKIN)
ACGIH TLV:25 PPM (SKIN)
Ingred Name:BUTANOL, N-BUTYL ALCOHOL, PROPYL CARBINOL, BUTYL ALCOHOL
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 1-5%
Other REC Limits:300 MG/CUM
OSHA PEL:100 PPM
ACGIH TLV:C 152 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL
CARBINOL
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 3-5%
Other REC Limits:400 PPM
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
Ingred Name:DIMETHYL ETHER, METHYL ETHER
CAS:115-10-6
RTECS #:PM4780000
Fraction by Wt: 15-40%
ACGIH TLV:NONE
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 4420-5840 MG/KG (SEE SUP
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: MAY CAUSE IRRITATION.
SOLVENTS MAY CAUSE DEFATTING DERMATITIS. ETHYLENE GLYCOL MONOBUTYL
ETHER/BUTANOL: POISON. DIMETHYL OXIDE: ASPHYXIANT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DIZZINESS, NAUSEA, DEFATTING.
DIMETHYL OXIDE: ASPHYXIATION.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN/EYES: FLUSH W/COPIOUS
AMOUNTS OF WATER. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:53.6-159.8F
Lower Limits:1
Upper Limits:12
Extinguishing Media:DRY CHEMICAL, CO2, FOAM
Fire Fighting Procedures:WATER FROM FOGGING NOZZLES MAY BE USED TO COOL
CLOSED CONTAINERS TO PREVENT PRESSURE BUILD-UP IF EXPOSED TO
EXTREME TEMPERATURES.
Unusual Fire/Explosion Hazard:CONTAINERS MAY EXPLODE IF EXPOSED TO
TEMPERATURES >122F. AUTOIGNITION TEMP: 473-852.8F.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. USE AN INERT
ABSORBENT MATERIAL & NON-SPARKING TOOLS. VENTILATE AREA. PREVENT
FROM ENTERING A WATERCOURSE. AVOID BREATHING FUMES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA,
NOT TO EXCEED 122F.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF USED INDOORS ON A CONTINUOUS BASIS, USE A
CARTRIDGE TYPE RESPIRATOR NIOSH/MSHA APPROVED.
Ventilation:LOCAL VENTILATION REQUIRED
Other Protective Equipment:NOT NORMALLY REQUIRED
Supplemental Safety and Health
PH: 8.7-9.5. ORAL LD50 INFORMATION IS FOR: ISOPROPANOL.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:179.6-338F
Melt/Freeze Pt:M.P/F.P Text:-129 TO 32F
Vapor Pres:55-60
Vapor Density:2-4
Spec Gravity:1
pH:(SUPP)
Evaporation Rate & Reference:(BU ACETATE=1): 0.1-1.7
Solubility in Water:36-39%/WT
Appearance and Odor:VARIOUS COLORS W/ALCOHOLIC ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:STORAGE IN HOT, UNVENTILATED AREAS.
Hazardous Decomposition Products:HYDROCARBON FUMES & SMOKE, CO BY
COMBUSTION IF INCOMPLETE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DON'T PUNCTURE/INCINERATE CONTAINERS, EVEN WHEN
EMPTY. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:WAX, GASKET SEALING
CAGE:78583
CAGE:78583
============= Composition/Information on Ingredients =============
Ingred Name:MANUFACTURER STATES THAT THE INGREDIENTS ARE PROPRIETARY
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IF HOT WAX COMES IN CONTACT WITH THE
SKIN, MAY CAUSE BURNS. THIS PRODUCT IS ESSENTIALLY NON-TOXIC.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:TREAT FOR BURN IF HOT WAX COMES IN CONTACT WITH THE SKIN.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>425F,>218C
Extinguishing Media:CARBON DIOXIDE, WATER FOG, DRY CHEMICALS
Fire Fighting Procedures:DO NOT USE WATER EXCEPT AS A FOG.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:DAM MOLTEN WAX. ALLOW TO COOL. SCRAPE OR
SHOVEL WAX AND DISPOSE.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM HEAT.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BREATHING FUMES IF PRODUCT IS HEATED.
Ventilation:LOCAL EXHAUST RECOMMENDED.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>500F,>260C
Vapor Pres:<0.1
Spec Gravity:0.93
Solubility in Water:INSOLUBLE
Appearance and Odor:YELLOW WAX.
================= Stability and Reactivity Data =================
NONE DETERMINED
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RB68C ELECTROSTATIC TONER REPLENISHER, 1713
Preparer's Name:CRAIG SUNDQUIST
CAGE:IO122
CAGE:IO122
CAGE:14668
============= Composition/Information on Ingredients =============
Ingred Name:ING 15:UNDER SOME CNDTNS OF USE/COMBINATIONS OF EQUIP,
OFFICE VENT MAY NOT BE ADEQ. USERS SHOULD ASSURE THAT (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16:VENT IS SUFFICIENT TO PVNT EXCEEDING EXPOS LIM.
USERS SHOULD CONSULT A QUALIFIED VENT ENGINEER (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:&/OR INDUSTRIAL HYGIENIST IF A CONCERN REGARDING
EXPOSURE ARISES.
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP:AS REPLENISHERS MAY STAIN CLOTHING.
RTECS #:9999999ZZ
Ingred Name:ACRYLIC POLYMER/RESIN; (ACRYLIC COPOLYMER/RESIN)
CAS:28430-58-2
Fraction by Wt: <4%
Ingred Name:BLUE (PIGMENT)
Fraction by Wt: <4%
Ingred Name:HYDROCARBON PARAFFINIC SOLVENT; (ISOPARAFFINIC SOLVENT)
CAS:64742-48-9
Fraction by Wt: >91%
Other REC Limits:300 PPM (MFR)
Ingred Name:SUPP DATA:PRDCE ADVERSE KIDNEY EFTS IN MALE RATS. HOWEVER,
THESE EFTS WERE NOT OBSERVED IN SIMILAR STUDIES WITH (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:FEMALE RATS & MALE & FEMALE MICE & IN LIM STUDIES
W/OTHER ANIMAL SPECIES. ADDNLY, IN A NUMBER OF HUMAN (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5:STUDIES, THERE WAS NO CLINICAL EVIDENCE OF SUCH EFTS
@ NORM OCCUP LEVELS. IT IS THEREFORE HIGHLY UNLIKELY (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:THAT KIDNEY EFTS OBSERVED IN MALE RATS HAVE
SIGNIFICANT IMPLICATIONS FOR HUMANS EXPOS @/BELOW RECOM VAP (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:LIMITS IN THE WORKPLACE.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: GLASSES OF WATER. DO NOT INDUCE VOMITING.
CALL PHYS IMMED.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: FOR VOLATILE, COMBUSTIBLE VAPS FROM ABSORBED
MATL. THERE IS NO REPORTABLE QTY (RQ) UNDER CERCLA (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:REPORTING REQUIREMENTS.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:SOLV & PETROLEUM BASED OILS. CONT A
LICENSED HAZ WASTE DISP COMPANY/ENVIRONMENTAL CTL AGENCY (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:FOR ASSISTANCE. POSS DISP METH INCL INCIN/RECYCLING
FOR USE AS PARTS CLEANING SOLV. RECYCLED MATLS (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:SHOULD NOT BE USED WITH CALCOMP PLOTTERS.
RTECS #:9999999ZZ
Ingred Name:VENT: OF HEATING, AIR CONDITION, & REFRIGERATING ENGINEERS
(ASHRAE) 1980 STD IS ADEQ UNDER NORM CNDTNS OF USE. (ING 16)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT)5 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: CAN CAUSE DRY OF
SKIN/IRRIT. EYES: CONT MAY CAUSE IRRIT. LUNGS:INHAL OF VAPS MAY
CAUSE HDCH & DIZZ. INGEST: PROD HAS LOW ORDER OF ACUTE ORAL &
DERMAL TOX, BUT IF ASPIRATED INTO LUNGS DURI NG INGEST/VOMIT, MAY
CAUSE MILD TO SEV PULM INJURY & POSS DEATH. PROD HAS BEEN
EXTENSIVELY TESTED. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: WHEN USED AS INTENDED, IT DOES NOT
REPRESENT ANY KNOWN HLTH/SFTY HAZ. HIGH VAP CONC (>1000PPM) ARE
IRRITATING TO EYES & RESP TRACT, MAY CAUSE HDCH & DIZZ, ARE ANESTH,
& MAY HAVE OTHER CNS EF TS. DEATH IS POSS IF EXPOS TO VERY HIGHCONC
FOR PRLNGD PERIODS. PERSONS SENSITIVE TO HYDROCARBON EXPOS (SUPP
DATA)
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN
EXISTING DERMATITIS.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/CLEAR WATER FOR @ LST 15 MIN/UNTIL IRRIT
SUBSIDES. IF IRRIT PERSISTS, CONT PHYS. SKIN: REMOVE CONTAMD CLTHG.
WASH SKIN THORO W/SOAP & WATER. DO NOT REUSE CONTAMD CLTHG UNTIL
SOLV HAS BEEN REMOVED. INHAL: REMOVE TO FRESH AIR.CALL PHYS IMMED.
IF BRTHG IS IRREGULAR OR STOPPED, START RESUSCITATION IF TRAINED.
ADMINISTER OXYGEN IF AVAIL. INGEST: DILUTE CONTENTS OF STOM
W/SEVERAL (ING 9)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>102F,>39C
Lower Limits:0.8%
Upper Limits:7%
Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE, OR WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . AVOID WATER, IT TENDS TO SPREAD HYDROCARBON
FIRES.
Unusual Fire/Explosion Hazard:KEEP PROD AWAY FROM SOURCES OF IGNIT SUCH
AS HEAT/SPARKS/PILOT LIGHTS, STATIC ELECTRICITY, ELEC APPLIANCES &
OPEN FLAMES.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIM ALL IGNIT SOURCES. RECOVER FREE PROD BY
ADDING SAND, EARTH/OTHER SUITABLE ABSORB TO SPILLED LIQ. KEEP
NON-ESSENTIAL PERS AWAY. AVOID BRTHG VAPS. VENT CONFINED SPACES.
CLEAN-UP ABSORB MATL & DISPO SE OF PROPERLY. CONTINUE TO OBSERVE
PREC (ING 10)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTR CLSD WHEN NOT IN USE. DO
NOT SMOKE WHEN USING PROD. MINIMIZE BRTHG VAP/MIST. USE W/ADEQ
VENT. AVOID PRLNGD/RPTD SKIN CONT.
Other Precautions:"EMPTY CONTAINERS RETAIN RESIDUE (LIQ AND/OR VAP) AND
CAN BE DANGEROUS. DISPOSE OF PROPERLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NEEDED WHEN USED AS INTENDED W/CALCOMP PROD.
IN CONCENTRATIONS EXCEEDING THE RECOMMENDED SAFE EXPOSURE LIMIT,
SUCH AS DURING A MAJOR SPILL, USE A NIOSH/MSHA APPROVED CHEMICAL
CARTRIDGE RESPIRATOR EFFECTIVE FOR ORGANIC VAPORS.
Ventilation:NO SPECIAL VENT IS NEEDED WHEN USED AS INTENDED W/CALCOMP
PROD. NORM OFFICE VENT CONFORMING TO AMERICAN SOCIETY (ING 15)
Other Protective Equipment:SHOULD NOT BE NEEDED WHEN USED AS INTENDED
IN CALCOMP PRODUCTS. WEAR CHEM RESISTANT APRON WHEN CLEANING
MACHINES(ING 19)
Work Hygienic Practices:WHENEVERR HNDLG CHEM, ALWAYS USE GOOD PERSONAL
HYGIENE PRACTICES, SUCH AS WASHING YOUR HANDS AFTER DONE.
Supplemental Safety and Health
PH:ESSENTIALLY NEUT. EVAP RATE:0.25-0.45(N-BUTYL ACETATE=1). %
VOLAT:100 @1 ATM & 25C (77F). EFTS OF OVEREXP:MAY EXPER DISCOMFORT
WHEN EXPOS TO CONC BELOW ESTAB SAFE EXPOS LIMIT. LAB ANIMAL STUDIES
HA VE SHOWN THAT PRLNGD & RPTD INHAL EXPOSTO LIGHT HYDROCARBON VAPS
IN SAME NAPHTHA BOILING RANGE AS PROD CAN (ING 4)
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:>320F,>160C
Vapor Pres:1@20C/68F
Vapor Density:5
Spec Gravity:0.76(H*2O=1)
pH:SUPDAT
Evaporation Rate & Reference:SUPP DATA
Solubility in Water:IMMISCIBLE
Appearance and Odor:YELLOW LIQUID WITH SLIGHT PETROLEUM ODOR.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS LIKE LIQUID CHLORINE, CONCENTRATED OXYGEN, AND SODIUM
HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:SOURCES OF IGNITION.
Hazardous Decomposition Products:SMOKE, CARBON MONOXIDE, ALDEHYDES, &
OTHER DECOMP PROD WHICH MAY OCCUR IN THE EVENT OF INCOMPLETE
COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:RCRA HAZ WASTE NO.-D001. WASTE TONERS &
REPLENISHERS ARE HAZ WASTE AS DEFINED BY 40CFR CHAPTER
1(FLAMMABILITY). ASSURE CONFORMITY W/ALL APPLIC FED/ST, & LOC DISP
REGS. WASTE TONERS & REPLENISHERS ARE COMPATIBLE FOR DISP W/MOST
NON-HALOGENATED(ING 12)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SILVER IODATE, 98%, 33910-5
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:SILVER IODATE. (MOLECULAR FORMULA: AGIO3)
CAS:7783-97-3
= Wt:98.
ACGIH TLV:TWA: 0.01 MG/M3
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY BE HARMFUL BY
INHALATION, INGESTION OR SKIN ABSORPTION. CAUSES EYE & SKIN
IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND UPPER
RESPIRATORY TRACT. MAY CAUSE ARGYRIA (A SL ATE-GRAY OR BLUISH
DISCOLORATION OF SKIN & DEEP TISSUES DUE TO THE DEPOSIT OF
INSOLUBLE ALBUMINATE OF SILVER). TO THE BEST OF OUR KNOWLEDGE, THE
CHEMICAL, PHYSICAL & TOXICOLOGICAL PROPERTIES HAVE NOT BEEN
THOROUGHLY INVESTIGATED.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING & SHOES. IF INHALED, REMOVE TO FRESH AIR. IF
NOT BREATHING , GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS
DIFFICULT, GIVE OXYGEN. IF SWALLOWED, WASH OUT MOUTH WITH WATER
PROVIDED PERSON IS CONCIOUS. CALL A PHYSICIAN. WASH CONTAMINATED
CLOTHING BEFORE REUSE.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING TO PREVENT CONTACT WITH SKIN & EYES. OXIDIZER.
Unusual Fire/Explosion Hazard:CONTACT WITH OTHER MATERIAL MAY CAUSE
FIRE. EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR SELF CONTAINED BREATHING
OR SODA ASH. PICK-UP, KEEP IN CLOSED CONTAINER & HOLD FOR WASTE
DISPOSAL. VENTILATE AREA & WASH SPILL SITE AFTER MATERIAL PICK-UP
IS COMPLETE.
Neutralizing Agent:LIME OR SODA ASH
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLING: WEAR APPROPRIATE
HOOD. SAFETY SHOWER & EYE BATH. AVOID BREATHING DUST. DO NOT GET
IN EYES, ON SKIN, ON CLOTHING. AVOID (OTHER PRECAUTIONS)
Other Precautions:HANDLING & STORAGE PRECAUTIONS (CONT): PROLONGED OR
REPEATED EXP. WASH THOROUGHLY AFTER HANDL. IRRITANT. STORAGE: KEEP
TIGHTLY CLOSED. KEEP AWAY FROM COMBUSTIBLE MATERIALS,
HEAT,SPARKS,&OPEN FLAME. PR OTECT FROM LIGHT. STORE IN COOL,DRY
PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:APPROPRIATE NIOSH-APPROVED RESPIRATOR.
Ventilation:USE ONLY IN CHEMICAL FUME HOOD.
Other Protective Equipment:EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Work Hygienic Practices:DO NOT GET IN EYES, ON SKIN, ON CLOTHING. WASH
THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
AVOID BREATHING DUST.
================== Physical/Chemical Properties ==================
Spec Gravity:5.525
Appearance and Odor:WHITE POWDER AND CHUNKS. ODOR: NONE SPECIFIED BY
MANUFACTURER .
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG REDUCING AGENTS. FINELY POWDERED METALS. REACTS VIOLENTLY WITH
SODIUM AND POTASSIUM.
Stability Condition to Avoid:SENSITIVE TO LIGHT
Hazardous Decomposition Products:HYDROGEN IODIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CATALYSTS AND EXPENSIVE METALS SHOULD BE
RECOVERED FOR REUSE OR RECYCLING.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT IS SUBJECT TO SARA SECTION 313
REPORTING REQUIREMENTS.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:32-SERIES, ACRYLIC LACQUER SYSTEM, LAC-LF (SUPDAT)
CAGE:16772
CAGE:16772
============= Composition/Information on Ingredients =============
Ingred Name:ING 9: ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE
(EGBEA). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO: (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10: 90-118) . METHYL ETHYL KETONE MAY INCR NERVOUS SYS
EFTS OF OTHER SOLVS. PRLNG OVEREXP TO SOLVS (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: LISTED IN INGREDS MAY CAUSE ADVERSE EFTS TO LIVER,
URINARY, BLOOD FORMING, CARDIOVASCULAR & REPRO SYS. (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: RATS EXPOS TO TITANIUM DIOXIDE DUST AT 250 MG/M3
DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13: NOT ATTAINABLE IN WORKPLACE. REPORTS HAVE ASSOC
RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN & NERVOUS (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: SYS DMG. INTENTIONAL MISUSE BY DELIB CONC & INHAL
CONTENTS CAN BE HARMFUL OR FATAL.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH: FACILITY. DO NOT INCIN CLSD CNTNR. DISPOSE
OF I/A/W FEDERAL, STATE & LOCAL REGS REGARDING POLLUTION.
RTECS #:9999999ZZ
Ingred Name:HNDLG/STOR PRECS: FLAMES, PILOT LIGHTS & HEATERS. TURN OFF
STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17: OF IGNIT. CONSULT NFPA CODE. USE APPRVD BONDING &
GROUNDING PROCS. KEEP CNTNR CLSD WHEN NOT IN USE. (ING 19)
RTECS #:9999999ZZ
Ingred Name:OTHER PRECS: DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED,
APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV 10 MG/M3 (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19: (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3
(RESPIRABLE FRACTION).
RTECS #:9999999ZZ
Ingred Name:RESP PROT: BY NIOSH/MSHA FOR PROTECTION AGAINST
NON-VOLATILE MATERIALS.
RTECS #:9999999ZZ
Ingred Name:TOLUENE (SARA 313) (CERCLA) VP: 22
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 25-40%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ISOPROPYL ALCOHOL; (2-PROPANOL) (SARA 313) VP: 33
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: <5%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM; 500 STEL
Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (MEK) (SARA 313) (CERCLA)
VP: 70
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 5-25%
OSHA PEL:200 PPM
ACGIH TLV:200 PPM; 300 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:2-PENTANONE, 4-METHYL-; (METHYL ISOBUTYL KETONE) (SARA 313)
(CERCLA) VP: 16
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 1-10%
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 75 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHANOL, 2-BUTOXY-, ACETATE; (2-BUTOXYETHYL ACETATE)
(EGBEA) VP: 1
CAS:112-07-2
RTECS #:KJ8925000
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 0-10%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:VOLATILE ORGANIC COMPOUND: 5.2-5.8 LBS/GAL; VOC LESS WATER
& EXEMPT SOLVENTS: 5.2-5.8 LBS/GAL
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MATLS TO AVOID: DANGEROUSLY INCREASED PRESSURES IN CLOSED
CONTAINERS.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: SHOWN DOSE-RELATED ADVERSE EFTS TO CNS,
HEMATOPOIETIC TISS, BLOOD, KIDNEYS & LIVER ASSOC W/THE (ING 10)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN OR EYE
CNTCT DEPENDING ON CNDTNS OF USE. ALCOHOLS & ACETATES CAN BE
ABSORBED THRU SKIN. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY CAUSE
NERVOUS SYS DEPRESS. EXTREME OVE REXP MAY RSLT IN UNCON & POSS
DEATH. HDCH, DIZZ, NAUS & LOSS OF COORDINATION ARE INDICATIONS OF
EXCESS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MISTS. REDNESS &
ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOS. CHRONIC:
TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK
CONSULTATION FROM APPROP H LTH PROFESSIONALS CONCERNING LATEST
HAZLIST INFO & SAFE HNDLG & EXPOS INFO . ANIMAL STUDIES HAVE
CLEARLY (ING 9)
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:INHAL: LEAVE AREA & GET FRESH AIR. IF PROBLEMS REMAIN OR
OCCUR LATER, IMMEDIATELY GET MEDICAL ATTENTION. SKIN: WASH AFFECTED
AREA THOROUGHLY WITH SOAP & WATER. REMOVE CONTAMINATED CLOTHING &
LAUNDER B EFORE RE-USE. EYES: FLUSH WITH LARGE AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES. GET MEDICAL ATTENTION. INGEST: GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:21.0F,-6.1C
Lower Limits:0.5%
Upper Limits:3.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF.
WATER MAY BE USED TO COOL CLSD (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. APPLICATN TO HOT SURFS (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTENTS ARE FLAMM. KEEP AWAY FROM
HEAT, SPARK & OPEN FLAME. DURING USE & UNTIL ALL VAPS ARE GONE:
KEEP AREA VENT. DO NOT SMOKE. EXTING ALL (ING 17)
Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST.
AVOID CNTCT W/SKIN & EYES. WASH HANDS AFTER USING. COATING MAY CNTN
MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE PRESENT AT
HAZ LEVELS ONL Y DURING SANDING/ABRADING OF (ING 19)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT WEAR NIOSH/MSHA APPRVD, PROPERLY FITTED ORG
VAP/PARTICULATE RESP. WHEN SANDING, WIREBRUSHING, ABRADING, BURNING
OR WELDING DRIED FILM, WEAR PARTICULATE RESP APPRVD (ING 21)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94,107,108.
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: NON-LEAD COLORS. FIRE FIGHT PROC: CNTNRS TO
PVNT PRESS BUILD-UP & POSS AUTOIGNIT OR EXPLOS WHEN EXPOSED TO
EXTREME HEAT. EXPLO HAZ: REQS SPEC PRECS. DURING EMER CNDTNS OVEREX
P TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT BE IMMED
APPARENT. OBTAIN MED ATTN.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>132F,>56C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.90-0.99
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:75-85
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALLICS CNTN ALUMINUM. CONTAM W/WATER, ACIDS OR ALKALIS CAN CAUSE
EVOLUTION OF HYDROGEN, WHICH MAY RSLT IN (ING 8)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE. CARBON
MONOXIDE. OXIDES OF METALS LISTED IN INGREDIENTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
40CFR 261. WASTE MUST BE TESTED FOR IGNIT TO DETERMINE APPLIC EPA
HAZ WASTE NUMBERS. WASTE FROM PRODS CONTAINING METHYL ETHYL KETONE
MAY REQ TESTING FO R EXTRACTABILITY. INCIN IN APPRVD (ING 16)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CADMIUM PLATED AIRCRAFT PART,2609688
CAGE:55284
CAGE:55284
============= Composition/Information on Ingredients =============
Ingred Name:CADMIUM (SARA 313) (CERCLA)
CAS:7440-43-9
RTECS #:EU9800000
Fraction by Wt: TRACE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 MG/M3 DUST; Z-2
ACGIH TLV:0.01 MG/M3 DUST;9596
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) IS NOT RELEVENT.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, LUNG, KIDNEY,
PROSTATE. PRODUCT IS NOT HAZARDOUS. HEALTH HAZARDS ARE DUE TO
DUSTS/FUMES CREATED DURING MACHINING. ACUTE- EYE:MAY CAUSE PAIN.
SKIN/INHALE:MAY CAUSE IRRITATION. ORAL:MAY CAUSE HEADACHE,
VOMITING, SORETHROAT. CHRONIC- MAY CAUSE KIDNEY DAMAGE, LUNG AND
PROSTATE CANCER.
Explanation of Carcinogenicity:CONTAINS C[7440-43-9] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:IRRITATION, SHORTNESS OF BREATH, CHEST PAIN,
FLU-LIKE SYMPTOMS SUCH AS WEAKNESS, HEADACHE, CHILLS AND MUSCULAR
PAIN, NAUSEA, VOMITING, DIARRHEA, SORE THROAT, REDNESS AND PAIN OF
EYES, SWEATING, FEVER
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, KIDNEYS, CNS MAY HAVE
INCREASED SUSCEPTIBILITY TO THE TOXICITY OF EXCESSIVE EXPOSURES.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IMMEDIATELY. EYE:FLUSH WITH WATER FOR
15 MINUTES. HOLD EYELIDS OPEN. SKIN:REMOVE CONTAMINATED CLOTHING.
WASH SKIN WITH SOAP/MILD DETERGENT & LARGE AMOUNT OF WATER.
INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
ORAL:TREATMENT MUST BE ADMINISTERED BY MEDICAL PERSONNEL. ADVICE TO
PHYSICIAN:DO NOT PERFORM CHELATION THERAPY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY SAND, DRY DOLOMITE, DRY GRAPHITE OR SODIUM
CHLORIDE
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:CADMIUM DUST CREATED DURING MACHINING MAY
PRESENT A MODERATE EXPLOSION HAZARD WHEN EXPOSED TO FLAME. DUST AND
STRONG OXIDIZERS MAY CAUSE FIRE OR EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. VACUUM OR SWEEP UP
SPILLAGE. AVOID CREATING DUST. PLACE SPILLAGE IN APPROPRIATE
CONTAINER FOR WASTE DISPOSAL. VENTILATE AREA. SPILLS AND RELEASES
MAY HAVE TO BE REPORTED TOFEDERAL AND/OR LOCAL AUTHORITIES.
Neutralizing Agent:NOT RELEVENT
======================Handling and Storage ======================
Handling and Storage Precautions:SHIPPING & STORAGE MUST FOLLOW
INSTRUCTIONS AS SPECIFIED IN 29 CFR 1910.1027 BEARING WARNING
LABLE: DANGER, CONTAINS CADMIUM. CANCER HAZARD.
Other Precautions:AVOID CREATING DUST. AVOID CONTACT TO EYES AND SKIN.
AVOID INHALATION OF DUST. WASH THOROUGHLY AFTER HANDLING. KEEP OUT
OF REACH OF CHILDREN. OBEY HAZARD WARNING LABEL. USE WITH ADEQUATE
VENTILATION. CAN CAUSE LUNG AND KIDNEY DISEASES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV <0.05 MG/M3:WEAR NIOSH-APPROVED HALF-MASK
AIR-PURIFYING WITH HEPA FILTER. IF TLV <5 MG/M3:WEAR NIOSH-APPROVED
SUPPLIED-AIR RESPIRATOR WITH FULL FACEPIECE OPERATED IN POSITIVE
PRESSUR EMODE. IF >5 MG/M3/UNKNOWN, WEAR SCBA.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP DUST AND
FUME LEVELS BELOW TLV.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING AND/OR UNIFORM
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
THIS METAL AIRCRAFT PART IS PLATED WITH CADMIUM. THE PART ITSELF IS NOT
HAZARDOUS. HAZARDS ARE ASSOCIATED WITH THE CADMIUM DUSTS AND FUMES
THAT MAY BE GENERATED IF THE PART IS MACHINED DURING MAINTENA NCE
ACTIVITIES.
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVENT
Appearance and Odor:SOLID, MATTED TEXTURE METALLIC TO POLISHED METAL
FINISH - ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, HYDROCHLORIC AND NITRIC ACID
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS.
Hazardous Decomposition Products:NOT RELEVENT
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. RECYCLE IF POSSIBLE. RCRA NUMBER: D006.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:H-640
Preparer's Name:P.J. MALONEY
CAGE:86035
CAGE:86035
============= Composition/Information on Ingredients =============
Ingred Name:TERBUTHYLAZINE
CAS:5915-41-3
= Wt:44.7
OSHA PEL:NONE ESTABLISHED
ACGIH TLV:NONE ESTABLISHED
Ingred Name:ETHYLENE GLYCOL
CAS:107-21-1
RTECS #:KW2975000
= Wt:5.
OSHA PEL:C50 PPM
ACGIH STEL:C50 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CAUTION! HARMFUL IF SWALLOWED OR
ABSORBED THROUGH SKIN. LONG TERM EXPOSURE MAY CAUSE LYMPHATIC
ORGAN DAMAGE AND/OR OTHER ADVERSE EFFECTS.
Explanation of Carcinogenicity:TERBUTHYLAZINE HAS BEEN TESTED IN THE
RAT,RABBIT OR MOUSE FOR PERIODS FROM 4 WEEKS TO 2 YEARS BY EITHER
THE ORAL OR DERMAL ROUTES.SOME OF THESE STUDIES SHOWED TOXIC
EFFECTS IN LYMPHATIC ORGANS.THE ORA L NO OBSERVABLE EFFECT LEVEL IN
THE RAT WAS 8 MG/KG/DAY OVER 4 WEEKS AND 0.35 MG/KG/DAY OVER 2
YEARS AND 17MG/KG/DAY OVER 2 YEARS IN THE MOUSE.
Effects of Overexposure:EYE:THIS PRODUCT WOULD NOT BE EXPECTED TO
PRODUCE SIGNIFICANT IRRITATION UPON CONTACT WITH THE EYE.
SKIN:REPEATED EXPOSURES CAN CAUSE PROBLEMS. INGESTION:THIS PRODUCT
WOULD BE EXPECTED TO BE MODERATEL Y TOXIC BY INGESTION. INGESTION
OF LARGEVOLUMES OF ETHYLENE GLYCOL MAY RESULT IN CENTRAL NERVOUS
SYSTEM DEPRESSION AND KIDNEY DAMAGE. CARDIAC FAILURE AND PULMONARY
EDEMA MAY DEVELOP. INHALATION:THIS P RODUCT IS NOT EXPECTED TO
PRESENT AND INHALATION HAZARD UNLESS MISTS OR VAPORS ARE GENERATED.
SIGNIFICANT AIR CONCENTRATIONS ARE NOT ACHIEVED UNLESS THE PRODUCT
IS HEATED.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:EYE: IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY
OF WATER. SEEK MEDICAL AID IF IRRITATION PERSISTS. SKIN: FLUSH SKIN
WITH PLENTY OF WATER OR WASH WITH MILD SOAP AND WATER. INGESTION:
IF SWA LLOWED, CALL A PHYSICIAN OR A POISON CONTROL CENTER. DO NOT
INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION:
IF INHALEDAND IRRITATION OR DIFFICULTY IN BREATHING OCCURS,
REMOVE TO FRESH AIR. SEEK MEDICAL AID IF IRRITATION OR DISCOMFORT
PERSISTS.
===================== Fire Fighting Measures =====================
Flash Point:>93.3C, 200.F
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:EXERCISE CAUTION WHEN FIGHTING ANY CHEMICAL
FIRE. A SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING
ARE ESSENTIAL.
Unusual Fire/Explosion Hazard:PRODUCT EMITS TOXIC GASES UNDER FIRE
CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEARING APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT, CONTAIN SPILL, COLLECT ONTO INERT ABSORBENT AND PLACE
INTO SUITABLE CONTAINER. CONTROL RUNOFF AS IT MAY INJURE LAWNS,
TREES, SHRUBS, AND OTHER PLANTS .
======================Handling and Storage ======================
Handling and Storage Precautions:IT IS A VIOLATION OF FEDERAL LAW TO
USE THIS PRODUCT IN A MANNER INCONSISTENT WITH ITS LABELING. AVOID
CONTACT WITH EYES,SKIN,AND CLOTHING. DO NOT CONTAMINATE
WATER,FOOD,OR FEED BY STORAGE. DO NOT EXP OSE TO EXTREME
TEMPERATURES. AVOID BREATHING VAPOR OR MIST. USE WITH ADEQUATE
VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF AIRBORNE CONCENTRATIONS EXCEED PUBLISHED
EXPOSURE LIMITS, USE A NIOSH APPROVED RESPIRATOR IN ACCORDANCE WITH
OSHA RESPIRATORY PROTECTION REQUIREMENTS.
Ventilation:USE LOCAL EXHAUST VENTILATION AT ELEVATED TEMPERATURES OR
IF MISTS ARE GENERATED.
Other Protective Equipment:PROTECTIVE CLOTHING
Supplemental Safety and Health
HMIS RATINGS: HEALTH=1, FLAMMABILITY=1, REACTIVITY=0*THERE ARE
POTENTIAL CHRONIC HEALTH EFFECTS TO CONSIDER. % VOLATILES BY WT =
NOT DETERMINED
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NOT DETERMINED
Melt/Freeze Pt:=-2.2C, 28.F
Vapor Pres:0.12
Vapor Density:2.14
Spec Gravity:1.05-1.15
pH:7.0-9.0
Solubility in Water:MISCIBLE
Appearance and Odor:WHITE TO BEIGE, LOW VISCOSITYPASTE WITH SLIGHT
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG BASES, ACIDS, AND OXIDIZERS.
Stability Condition to Avoid:AVOID HIGH TEMPERATURES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION
MAY PRODUCE CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN OXIDES, AND
SULFUR OXIDES. CHLORINE COMPOUNDS AND OTHER TOXIC SPECIES MAY ALSO
BE FORMED.
=================== Toxicological Information===================
Toxicological Information:ORAL LD50 (RAT):1350 MG/KG;DERMAL LD50
(RABBIT):>4400 MG/KG TWO-YEAR STUDIES ON TERBUTHYLAZINE SHOWED A
SMALL INCREASED INCIDENCE OF MAMMARY TUMORS IN THE HIGH DOSE
FEMALES RATS WITH NO INCREASED TUM OR INCIDENCE IN THE MOUSE. THIS
DATA IS NOT CONSIDERED TO BE REVELANT TO HUMANS. IN ONE STUDY, WHEN
ETHYLENE GLYCOL WAS ADMINISTERED IN THE DIET AT DAILY DOSES UP TO
1.0 G/KG TO PREGNANT RATS, NO MATE RNAL TOXICITY, NO EMBRYOTOXICTY
NOR TERATOGENICITY WERE OBSERVED. IN A MORE RECENT STUDY, WHEN
ETHYLENE GLYCOL WAS ADMINISTERED BY GAVAGE AT DAILY DOSES OF 1.25
G/KG AND ABOVE TO PREGNANT RATS.
===================== Ecological Information =====================
Ecological:DO NOT DISCHARGE EFFLUENT CONTAINING THIS PRODUCT INTO
LAKES, STREAMS, PONDS, ESTUARIES, OCEANS, OR OTHER WATERS UNLESS IN
ACCORDANCE WITH THE REQUIREMENTS OF A NATIONAL POLLUTANT DISCHARGE
ELIMINATIO N SYSTEM PERMIT AND THE PERMITTING AUTHORITY HAS BEEN
NOTIFIED IN WRITING PRIOR TO DISCHARGE. DO NOT DISCHARGE EFFLUENT
CONTAINING THIS PRODUCT TO SEWER SYSTEMS WITHOUT PREVIOUSLY
NOTIFYING THE LOCAL SEWAGE TREATMENT PLANT AUTHORITY. FOR GUIDANCE
CONTACT YOUR STATE WATER BOARD OR REGIONAL OFFICE OF THE EPA.
INHIBITORY CONCENTRATION ON RESPIRATION OF AEROBIC WASTE WATER
BACTERIA: IC20, IC50, IC80>1 00 PPM .
==================== Disposal Considerations ====================
Waste Disposal Methods:RCRA STATUS:PRODUCT IS A PESTICIDE AND MUST BE
DISPOSED OF IN A MANNER APPROVED BY EPA RESOURCE CONSERVATION AND
RECOVERY ACT. PESTICIDE WASTES ARE ACUTELY HAZARDOUS. IMPROPER
DISPOSAL OF EXCESS PESTI CIDE,SPRAY MIXTURE,OR RINSATE IS A
VIOLATION OF FEDERAL LAW.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES:
THERE ARE NO SARA 302 EXTREMELY HAZARDOUS SUBSTANCES IN THIS
PRODUCT. SECTION 311 AND 312 HEALTH AND PHYSICAL HAZARDS:
IMMEDIATE=YES, DELAYED=YES, FIRE=NO, PRESSURE=NO, REACTIVITY=NO.
SECTION 313 TOXIC CHEMICALS: ETHYLENE GLYCOL
Federal Regulatory Information:OSHA HAZARD COMMUNICATION STATUS:
HAZARDOUS; TSCA: PESTICIDES ARE EXEMPTED BY TSCA FROM THE
PROVISIONS OF THE ACT. CERCLA: REPORTABLE QUANTITY OF EPA
HAZARDOUS SUBSTANCES IN THIS PRODUCT: ETHYLENE GL YCOL: RQ=5000 LB,
PRODUCT RQ=100,000 LB.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:WHITE OPAQUE CLEAR PRINT STAMP PAD INK 9
CAGE:88303
CAGE:88303
============= Composition/Information on Ingredients =============
Ingred Name:DIACETONE ALCOHOL (4-HYDROXY-4-METHYL-2-PENTANONE)
CAS:123-42-2
RTECS #:SA9100000
Fraction by Wt: 52.3%
OSHA PEL:50 PPM
ACGIH TLV:50 PPM; 9192
Ingred Name:RESINS
Fraction by Wt: 20.0%
Ingred Name:PIGMENTS
Fraction by Wt: 27.7%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:OVEREXPOSURE TO COMPONENTS HAS
APPARENTLY BEEN FOUND TO CAUSE THE FOLLOWING EFFECTS IN LABORATORY
ANIMALS: ANEMIA, LIVER ABNORMALITIES, KIDNEY DAMAGE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:EYES:CAN CAUSE SEVERE
IRRIT,REDNESS,TEARING,BLURRED VISION.SKIN:PRLNGD/RPTD CNTCT CAN
CAUSE MOD IRRIT,DEFATTING,DERMATITIS.INHAL:EXCESSIVE INHAL OF VAPS
CAN CAUSE NASAL & RESP IRRIT,DIZZ,WEAKNESS,FATI
GUE,NAUSEA,HDCH,POSS UNCONSCIOUSNESS AND ASPHYXIATION.INGEST:CAN
CAUSE GI IRRIT,NAUSEA,VOMIT,DIARRHEA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:THOROUGHLY WASH EXPSD AREA W/SOAP & WATER.REMOVE CONTAM
CLTHNG,LAUNDER BEFORE REUSE.EYES:FLUSH W/LGE AMTS OF WATER,LIFT
UPPER/LOWER LIDS OCCASNLY,GET MD.INGEST:DO NOT INDUCE VOMIT,KEEP
WARM,QUIET& GET MD.ASPIR OF MATL INTO LUNGS DUE TO VOMIT CAN
CAUSE CHEM PNEUMONITIS WHICH CAN BE FATAL.INHAL:REMOVE TO FRESH
AIR.IF BRTHNG DFLCT,GIVE O*2.IF BRTHNG STOPPED GIVE ARTF RESP.KEEP
WARM,QUIET,GET MD
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:133F,56C
Lower Limits:1.8
Extinguishing Media:ALCOHOL FOAM, FOAM, CARBON DIOXIDE, AND DRY
CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA WITH A FULL
FACEPIECE OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE
MODE.
Unusual Fire/Explosion Hazard:VAPS ARE HVR THAN AIR,MAY TRAVEL ALONG
GROUND OR MOVE BY VENT & IGNITED BY HEAT,PILOT LIGHTS,OTHER FLAMES
& IGNITION SOURCES AT LOCATIONS FROM MATL HNDLNG POINT
================== Accidental Release Measures ==================
Spill Release Procedures:SML SPILL:ABSORB LIQ ON
PAPER,VERMICULITE,FLOOR ABSORBENT,OTHER ABSORB MATL & TRANSFER TO
HOOD.LGE SPILL:ELIM ALL IGNITION SOURCES.PERSONS NOT WEARING PROT
EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL UNTIL CLEAN-UP
COMPLETE. (SEE SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:CONTAINERS OF THIS MATL MAY BE HAZARDOUS WHEN
EMPTIED,SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES (VAPOR,
LIQUID, AND SOLID).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV EXCEEDED, WEAR NIOSH/MSHA APPROVED AIR
SUPPLIED RESPIRATOR IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL.
OSHA REGS PERMIT OTHER NIOSH/MSHA APPRVD RESPS.
Ventilation:PROVIDE ENOUGH MECHANICAL (GENERAL/LOCAL EXHAUST)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:TO PREVENT REPEATED OR PROLONGED SKIN
CONTACT WEAR IMPERVIOUS CLOTHING AND BOOTS.EMERGENCY EYE WASH
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
(SPILL/RELEASE PROCEDURE,CON'T):STOP SPILL AT SOURCE,DIKE AREA OF SPILL
TO PREVENT SPREADING,PUMP LIQUID TO SALVAGE TANK.REMAINING LIQUID
MAY BE TAKEN UP ON SAND,CLAY,EARTH,FLOOR ABSORBENT, OR OTHER A
BSORBENT MATERIAL AND SHOVELED INTO CONTAINERS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:337F,169C
Vapor Pres:0.8
Vapor Density:4.00
Evaporation Rate & Reference:0.14 (N-BUTYL ACETATE=1)
Solubility in Water:52.3%
Appearance and Odor:WHITE LIQUID, FAINT PLEASANT ODOR.
Percent Volatiles by Volume:52.3
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS, STRONG ALKALIS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS; CARBON
DIOXIDE AND CARBON MONOXIDE, VARIOUS HYDROCARBONS, ETC.
==================== Disposal Considerations ====================
Waste Disposal Methods:SML SPILL:ALLOW VOLAT PORTION TO EVAP IN
HOOD.ALLOW ENOUGH TIME FOR VAPS TO COMPLETELY CLEAR HOOD DUCT
WORK.DISP OF REMAINING MATL BY APPLIC REGS.LGE SPILL:DESTROY BY LIQ
INCIN.CONTAM ABSORB MAY BE DE POSITED IN LANDFILL I/A/W
FEDERAL,STATE,LOCAL REGS
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===================== Product Identification =====================
Product ID:PERIODIC ACID, 99.999%, 37989-1
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:ING 2:TO PRECIPITATE FOR BURIAL AS HAZ WASTE. DESTROY
EXCESS SULFIDE, NEUT & FLUSH SOLN DOWN DRAIN. DISPOSE OF (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3: I/A/W FEDERAL, STATE AND LOCAL REGULATIONS (FP N ).
RTECS #:9999999ZZ
Ingred Name:PERIODIC ACID. MFR CAS# 10450-60-9
CAS:13444-71-8
Fraction by Wt: 99.999%
Ingred Name:SUPP DATA: MORE ACID. IF MANGANESE, CHROMIUM, OR MOLYBDNEUM
ARE PRESENT ADJUST PH OF SOLN TO 7 & TREAT W/SULFIDE (ING 3)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THRU SKIN. MATERIAL IS EXTREMELY DESTRUCTIVE TO TISSUE
OF MUCOUS MEMBRANES AND UPPER RESPIRATORY TRACT, EYES AND SKIN.
INHALATION MAY BE FATAL AS A RE SULT OF SPASM, INFLAMMATION AND
EDEMA OF LARYNX AND BRONCHI, CHEMICAL PNEUMONITIS & PULMONARY
EDEMA. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SYMPTOMS OF EXPOSURE MAY INCLUDE
BURNING SENSATION, COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF
BREATH, HEADACHE, NAUSEA AND VOMITING. TO THE BEST OF MFR
KNOWLEDGE, THE CHEMICAL, PHYSICAL,AND TOXICOLOGICAL PROPERTIES
HAVE NOT BEEN THOROUGHLY INVESTIGATED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMED FLUSH WITH COPIOUS AMTS OF WATER FOR @ LST 15 MIN
& SEEK MED ADVICE. SKIN: IMMED FLUSH W/COPIOUS AMTS OF WATER FOR @
LST 15 MIN WHILE REMOVING CONTAMINATED CLOTHING & SHOES. WASH
CONTAMINA TED CLOTHING BEFORE REUSE. INHAL: REMOVE TO FRESH AIR. IF
NOT BREATHING GIVE ARTF RESP. IF BREATHING IS DFCLT, GIVE OXYGEN.
INGEST: WASH OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL A
PHYS.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:WEA NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . STRONG OXIDIZER.
Unusual Fire/Explosion Hazard:CONTACT WITH OTHER MATERIAL MAY CAUSE
FIRE. EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA,
UP, KEEP IN A CLOSED CONTAINER AND HOLD FOR WASTE DISPOSAL.
VENTILATE AREA AND WASH SPI LL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL
DRY PLACE. AVOID BREATHING DUST. DO NOT GET IN EYES, ON SKIN, ON
CLOTHING. AVOID PRLNGD/RPTD EXPOSURE.
Other Precautions:CORROSIVE. TOXIC. KEEP AWAY FROM COMBUSTIBLE
MATERIALS, HEAT, SPARKS, AND OPEN FLAME. HYGROSCOPIC.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:OTHER PROTECTIVE CLOTHING, SAFETY SHOWER AND
.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MATL TO AVOID: (DMSO) HAVE BEEN RPTD TO EXPLODE AFTER STANDING A FEW
MIN. EVAP OF AN AQUEOUS SOLN OF TETRAETHYLAMMONIUM HYDROXIDE CNTNG
A SLIGHT EXCESS OF PERIODIC ACID RESULTED IN AN EXPLO AFTER VACU UM
EVAP OF MOST OF WATER. WASTE DISP METH:OF ABOUT 10% OF SODIUM
BISULFITE SOLN INITIATE IT BY CAUTIOUSLY ADDING (ING 2)
================== Physical/Chemical Properties ==================
Appearance and Odor:WHITE CRYSTALS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG REDUCING AGENTS, FINELY POWDERED METALS, STRONG BASES. SOLN OF
PERIODIC ACID IN METHYL SULFOXIDE (SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HYDROGEN IODIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CAUTIOUSLY ACIDIFY A 3% SOLN/A SUSPENSION OF
MATL TO PH 2 W/SULFURIC ACID. GRADUALLY ADD A 50% EXCESS OF AQUEOUS
SODIUM BISULFITE W/STIRRING @ ROOM TEMP. AN INCR IN TEMP INDICATES
THAT A RXN IS TAKING PLACE. IF NO RXN IS OBSERVED ON ADDN (SUPP
DATA)
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===================== Product Identification =====================
Product ID:0042555 SURFASIL/DRI-FILM
CAGE:60088
CAGE:60088
============= Composition/Information on Ingredients =============
Ingred Name:1,7-DICHLOROOCTAMETHYLTETRASILOXANE
CAS:2474-02-4
Fraction by Wt: 100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CORROSIVE, HARMFUL IF INGESTED,
INHALED/ABSORBED. EXTREMELY DESTRUCTIVE TO TISSUE OF THE MUCOUS
MEMBRANES & UPPER RESPIRATORY TRACT, EYES & SKIN. INHALATION: MAY
BE FATAL AS A RESULT OF EDEMA OF THE L ARYNX & BRONCHI, CHEMICAL
PNEUMONITIS, PULMONARY EDEMA & BURNS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SPASM, INFLAMMATION, BURNING SENSATION,
COUGHING, WHEEZING, LARYNGITIS, SHORTNESS OF BREATH, HEADACHE,
NAUSEA, VOMITING.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/LARGE AMOUNTS OF WATER. SKIN: FLUSH W/LARGE
AMOUNTS OF WATER FOR 5 MINS, FOLLOWED BY A THOROUGH SOAP & WATER
WASH. INGESTION: WASH OUT MOUTH THOROUGHLY W/WATER. GIVE ABOUT 1/2
PINT OF WA TER TO DRINK & DILUTE IN STOMACH. DON'TINDUCE VOMITING.
INHALATION: REMOVE TO FRESH AIR. REST & KEEP WARM. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:78F
Extinguishing Media:CO2, ABC, DRY CHEMICAL
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT & RESPIRATORY
PROTECTION.
Unusual Fire/Explosion Hazard:COMBUSTIBLE, EMITS TOXIC FUMES UNDER FIRE
CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WARN OTHERS TO KEEP A SAFE DISTANCE. VENTILATE
AREA & SHUT OFF SOURCES OF IGNITION. WEAR APPROPRIATE PROTECTIVE
EQUIPMENT. CONTAIN W/AN APPROPRIATE ABSORBENT & PLACE IN A SUITABLE
CONTAINER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL AREA, PROTECTED FROM
MOISTURE. IDEALLY IN A FLAMMABLE LIQUID CABINET/STORAGE ROOM,
SEPARATE FROM ACIDS, OXIDIZING MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ORGANIC VAPOR/ACID GAS/SCBA.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): RECOMMENDED
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:150.8F
Spec Gravity:1.12
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:MOISTURE, HEAT, OPEN FLAME.
Hazardous Decomposition Products:CO, CO2, NITROGEN OXIDES, SILICON
OXIDE & HYDROGEN CHLORIDE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
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===================== Product Identification =====================
Product ID:PACKING MATERIAL
Preparer's Name:HMIS TECHNICIAN
CAGE:JO772
CAGE:14153
CAGE:JO772
============= Composition/Information on Ingredients =============
Ingred Name:ASBESTOS, CHRYSOTILE
CAS:12001-29-5
RTECS #:CI6478500
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:2 FIBERS/CC; A1;9293
Ingred Name:COPPER (SARA III)
CAS:7440-50-8
RTECS #:GL5325000
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2MG/M3 FUME; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:BRASS
Other REC Limits:NONE RECOMMENDED
Ingred Name:OIL
Other REC Limits:NONE RECOMMENDED
Ingred Name:GRAPHITE, NATURAL
CAS:7782-42-5
RTECS #:MD9659600
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MPPCF RDUST
ACGIH TLV:2 MG/M3 RDUST; 9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:MINOR EYS/SKIN IRRITATION.
INGESTION- IRRITATION OF GI TRACT. INHALATION-IRRITATION OF
RESPIRATORY TRACT. CHRONIC: ASBESTOSIS, LUNG CANCER, &
MESOTHELIOMA, ALL OF WHICH ARE DISABLING AND FATAL D ISEASES OF THE
LUNG. INHALATION AND INGESTION OF ASBESTOS FIBERS MAY CAUSE CANCER
OF THE BOWEL.
Explanation of Carcinogenicity:CONTAINS ASBESTOS [12001-29-5] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:INHALATION: FATIGUE AND SHORTNESS OF BREATH
THAT GETS WORSE WITH TIME AND EVENTUALLY BECOMES DISABLING. EYES:
IRRITATION. SKIN: IRRITATION. INGESTION: MILD STOMACH DISTRESS.
DIARRHEA, VOMITING, AND NA USEA.
Medical Cond Aggravated by Exposure:ASTHMA, EMPHYSEMA, AND TUBERCULOSIS
ARE ALL GENERALLY AGGRAVATED BY EXPOSURE TO ASBESTOS FIBERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. SEE DOCTOR. EYES: RINSE
THOROUGHLY WITH WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: WASH
THOROUGHLY WITH SOAP AND WATER. IF IRRITATION PERSISTS, SEE DOCTOR.
INGESTION: DIL UTE WITH WATER. DO NOT INDUCE VOMITING.SEE DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point:NOT REQUIRED
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:VACUUM THE MATERIAL WITH A HEPA FILTERED
VACUUM. THE EQUIPMENT SHALL BE USED & EMPTIED SO AS TO MINIMIZE THE
RE-ENTRY OF ASBESTOS INTO THE WORKPLACE. OTHERWISE, WET THE
MATERIAL WITH WATER & SURFACTAN T AND THEN SHOVEL OR MOP UP
CONTAMINATION.
======================Handling and Storage ======================
Handling and Storage Precautions:ITEM IS NONFRIABLE & WILL NOT SHED
FIBERS IN NORMAL USE AND STORAGE. USED ITEMS SHALL BE WETTED
BEFORE, DURING & AFTER DISASSEMBLY.
Other Precautions:IF IT IS NECESSARY TO CUT OR IMPACT THE ITEM WHILE
INSTALLING IT, WEAR A RESPIRATOR AND PROTECTIVE CLOTHING. USED
ITEMS SHALL BE IDENTIFIED AND DISPOSED OF IN ACCORDANCE WITH ALL
LOCAL, STATE AND FEDE RAL REGULATIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A NIOSH/MSHA APPROVED HEPA RESPIRATOR IF
REQUIRED. WEAR SELF-CONTAINED BREATHING APPARATUS IF REQUIRED FOR
HIGH LEVELS OF CONTAMINATES.
Ventilation:LOCAL EXHAUST SUFFICIENT TO ENTRAIN ALL PARTICULATE
EMISSIONS. HEPA FILTER REQUIRED. NO LEAKS ON PRESSURE SIDE OF FAN.
Other Protective Equipment:USE COVERALLS OR DISPOSABLE CLOTHING.
Work Hygienic Practices:WET WORK TO THE DEGREE POSSIBLE. WASH HANDS
AFTER HANDLING ITEM. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
MSDS GENERATED BY HMIS TECHNICIAN. MANUFACTURER IS UNKNOWN OR OUT OF
BUSINESS. WHEN HMIS IS ABLE TO OBTAIN AN MSDS FROM MANUFACTURER,
THIS RECORD WILL BE UPDATED. INGREDIENTS ARE FROM DLSC TIR PART M
OR PARTSMASTER TECHNICAL CHARACTRISTICS.
================== Physical/Chemical Properties ==================
HCC:T6
Solubility in Water:INSOLUBLE
Appearance and Odor:BRAIDED, SQUARE SOLID, 0.875 INCHES X 0.875 INCHES;
LUBRICATED W/GRAPHITE & OIL
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG MINERAL ACIDS, AND STRONG ALKALIS
Stability Condition to Avoid:ACCUMULATIONS OF DUST
Hazardous Decomposition Products:ASBESTOS DUST
==================== Disposal Considerations ====================
Waste Disposal Methods:WET THE MATERIAL WITH WATER AND SURFACTANT.
PLACE IN 6 MIL THICK POLYETHYLENE PLASTIC BAG. PLACE THESE BAGS
INTO ANOTHER POLY BAG OR A SAFE PLACE UNTIL IT CAN BE SHIPPED TO AN
APPROVED DISPOSAL SITE. IDENTIFY WITH ASBESTOS CANCER WARNING
LABEL.
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===================== Product Identification =====================
Product ID:TEMPERATURE INDICATING CRAYONS, CW 1493
Preparer's Name:KEN HEARREAN
CAGE:67292
CAGE:67292
============= Composition/Information on Ingredients =============
Ingred Name:MOLYBDENUM TRIOXIDE
CAS:1313-27-5
RTECS #:QA4725000
Fraction by Wt: 16-38%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MATLS TO AVOID:MAY BE INCOMPAT W/CHLORINE TRIFLUORIDE,
POTASSIUM, SODIUM, MOLTEN MAGNESIUM, ALUMINUM, LITHIUM & SILICON.
RTECS #:9999999ZZ
Ingred Name:HAZ DECOMP PROD: FROM METAL BEING HEATED. TEMP INDICATING
CRAYON FOR 1000F MAY GIVE OFF CHROMIUM OXIDE FUMES. (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3: PRIMARY ROUTE OF ENTRY OF WELDING FUMES & GASES IS
BY INHAL. 1 REC WAS TO DETERM COMPOSITION & QTY OF (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: FUMES & GASES TO WHICH WORKERS ARE EXPOS IS TO TAKE
AIR SAMPLE INSIDE WELDER'S HELMET, IF WORN, OR IN (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: WORKER'S BRTHG ZONE. SEE ANSI/AWS F1.1, AVAIL FROM
AMERICAN WELDING SOCIETY, P.O. BOX 351040, MIAMI, FL 33135.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: CRAYON MAY AFFECT BLOOD, RESPIRATORY
SYSTEM, LIVER, KIDNEYS, EYES, SKIN AND GI TRACT.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC: 351040, MIAMI, FL 33135 & OSHA PUBLICATION 2206
(29 CFR 1910), US GOVT PRINTING OFFICE, WASHINGTON, (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: DC. 20402 FOR MORE DETAIL.
RTECS #:9999999ZZ
Ingred Name:VENT: AREA. TRAIN WELDER TO KEEP HEAD OUT OF THE FUMES.
RTECS #:9999999ZZ
Ingred Name:EYE PROT: . WHEN WELDING, BRAZING/SOLDERING, WEAR
HELMET/USE FACE SHIELD W/FILTER LENS. AS RULE OF THUMB,(ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: START W/SHADE WHICH IS TOO DARK TO SEE WELD ZONE.
THEN GO TO NEXT LIGHTER SHADE WHICH GIVES SUFFICIENT (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: VIEW OF WELD ZONE. PROVIDE PROT SCREENS & FLASH
GOGGS, IF NECESSARY, TO SHIELD OTHER.
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP: & TO PROT CLTHG. WHEN USING PROD IN
CONJUNCTION W/WELDING, WEAR HEAD, HAND & BODY PROT WHICH (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: HELP PVNT INJURY FROM RADIA, SPKS & ELEC SHOCK. SEE
RTECS #:9999999ZZ
Ingred Name:ING 15: FACE SHIELD & MAY INCL ARM PROTECTORS, APRONS,
HATS, SHOULDER PROT, AS WELL AS DARK SUBSTANTIAL CLTHG. (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16: TRAIN WELDER NOT TO TOUCH LIVE ELECTRICAL PARTS &
TO INSULATE HIMSELF FROM WORK AND GROUND.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: MAY CAUSE IRRIT OF RESP
SYS, HDCHS, DIZZ & SLIGHT NAUS. SKIN CONT: PRLNGD CONT MAY CAUSE
MINOR IRRIT. EYE CONT: MAY CAUSE TEMPORARY IRRIT. INGEST: NOT
NORMAL ROUTE OF ENTRY. DO NOT INGES T. FUMES & GASES CAN BE
DANGEROUS TO YOUR HLTH. SHORT-TERM (ACUTE) OVEREXP TO FUMES FROM
TEMPERATURE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INDICATING CRAYONS MAY RSLT IN
DISCOMFORT SUCH AS: DIZZ, NAUS/DRYNESS/IRRIT OF NOSE, THROAT/EYES.
LONG-TERM (CHRONIC) OVEREXP TO 1000F TEMP INDICATING CRAYON MAY
CAUSE KIDNEY/LIVER DMG. CHRO NIC OVEREXP TO OTHERS HAS NOT LEAD TO
SIGNIFICANT HLTH HAZS. TARGET ORGANS: OVEREXP TO 1000F TEMP
INDICATING (ING 7)
Medical Cond Aggravated by Exposure:PREEXISTING RESPIRATORY/ALLERGIC
CONDITIONS.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE FROM AREA OF EXPOS TO LOCATION W/FRESH AIR. IF
BRTHG IS DFCLT, SEEK MED ATTN. SKIN CONT: WASH AREAS W/SOAP &
WATER. IF IRRIT PERSISTS, SEEK MED ATTN. EYE CONT: FLUSH W/WATER
FOR @ LST 15 MINS. IF PAIN/IRRIT PERSISTS, SEEK MEDAID. INGEST: DO
NOT INDUCE VOMIT. SEEK MED ADVICE IMMED & PROVIDE PRODUCT
INGREDIENT INFORMATION.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WELDING ARCS & SPKS & FUEL GAS TORCHES &
SOLDERING IRONS USED FOR WELDING, BRAZING & SOLDERING OPERATIONS
CAN IGNITE COMBUST. REFER TO AMERICAN NATL (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:COLLECT SPILLED MATERIAL FOR RECLAMATION AND
REUSE OR DISPOSAL IN SEALED CONTAINERS. KEEP AIRBORNE DUST AT A
MINIMUM WHEN CLEANING UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN/CLTHG.
USE GOOD HOUSEKEEPING PRACTICES TO PREVENT ACCUMULATIONS OF DUST OR
FUMES.
Other Precautions:READ & UNDERSTAND MFR'S INSTRUCTIONS & PRECAUTIONARY
LBL ON PROD. FOR INFO RELATING TO HEATING, WELDING & BRAZING
OPERATIONS, SEE AMERICAN NATL STD Z49.1 SFTY IN WELDING & CUTTING,
PUBLISHED BY AMERIC AN WELDING SOCIETY, P.O. BOX (ING 8)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPRVD RESPIRABLE FUME/DUST RESPIRATOR
OR AIR SUPPLIED WHEN USING PRODS IN CONFINED SPACE/WHEN WELDING,
BRAZING/SOLDERING IN CONFINED SPACE/WHERE LOC EXHAUST/VENT DOES NOT
KEEP EXPOSURE BELO W TLV.
Ventilation:USE ENOUGH VENT, LOC EXHST @ WORK AREA/BOTH, TO KEEP FUMES
& GASES BELOW TLV'S IN WORKER'S BRTHG ZONE & GENERAL (ING 10)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . USE
CHEM RESIST APRONS TO AVOID PRLNGD/RPTD SKIN CONT W/CHEMS PRODS(ING
14)
Work Hygienic Practices:WASH HANDS AFTER HANDLING. DO NOT SMOKE, EAT OR
DRINK IN WORK AREA.
Supplemental Safety and Health
EXPLO HAZ: STD Z49.1 FOR FIRE PREVENTION DURING WELDING. VIOLENT
DETONATION/EXOTHERMIC RXNS MAY OCCUR ON MIXING TEMP INDICATING
CRAYONS FOR 850, 950, & 1050F WITH INCOMPATIBLE MATERIALS.
TEMPERATURES INDICATING CRAYON FOR 1000F MAY ACT AS MODERATE
OXIDIZER & SUPPORT COMBUSTION WHEN MIXED WITH OTHER MATERIALS.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:1050F/566C
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:CRAYON-LIKE PRODUCT, NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALL TEMP INDICATING CRAYONS MAY BE INCOMPAT W/STRONG ACIDS, ALKALIS &
OXIDIZERS. CRAYONS FOR 850, 950 & 1050F (ING 2)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:IN USE, TEMP INDICATING CRAYONS MAY
GIVE OFF FUMES & VAPS OF PHENOL, CO, CO*2 &, IN ADDN, FUMES MAY BE
GENERATED (ING 3)
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSABLE CONTAINER, OR
LINER IN ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH
FEDERAL, STATE ANDLOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SULFURIC ACID REAG ACS
CAGE:5A188
CAGE:5A188
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: >95%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT
IS LISTED AS A CACINOGEN BY NTP, IARC, OR OSHA.
Effects of Overexposure:EYES: SEVERE DAMAGE/BLINDNESS VERY RAPIDLY.
SKIN: BURNS, POSSIBLE DEEP ULCERATIONS. INHALATION: FUMES CAUSE
DAMAGE TO THE NASAL/RESPIRATORY PASSAGES. INGESTION: SEVERE DAMAGE
TO MUCOUS MEMBRANES/DEEP TISSUE.
======================= First Aid Measures =======================
First Aid:SKIN: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. DISCARD
CONTAMINATED CLOTHING. GET MEDICAL HELP. EYES: IMMEDIATELY FLUSH
WITH WATER FOR 15 MINUTES LIFTING UPPER/LOWER LIDS UNTIL MEDICAL
HELP IS OBT AINED. CALL DOCTOR. DONT USE CHEMICAL ANTIDOTE.
INGESTION: DONT INDUCE VOMITNG. GIVE WATER/MILK OF MAGNESIA. KEEP
PERSON WARM AND QUIET. INHALATION: MOVE TO FRESH AIR. GET IMMEDIATE
MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WITH
FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:SULFURIC ACID REACTS WITH MOST METALS TO
GIVE HYDROGEN GAS WHICH CAN FORM EXPLOSIVE MIXTURES WITH AIR.
================== Accidental Release Measures ==================
Spill Release Procedures:SM.SPILL:COVER W SOD BICARB.,SODA ASH/SLAKED
LIME MIX(50-50).FORM SLURRY.SCOOP UP SLURRY & WASH W SODA ASH
SOLN.LARGE SPILL:ELIMINATE ALL IGNITION SOURCES.EVACUATE AREA.WEAR
PROTEC.EQUIP,DIKE AREA OF SPILL,PUMP LIQD TO SALVAGE TANK.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED. OBSERVE ALL
PRECAUTIONS ON LABEL. NEVER STORE NEAR FLAMMABLE LIQUIDS/STRONG
ALKALIES.
Other Precautions:GIVES HEAT WHEN ADDED TO WATER, RESULTING IN VOILENT
BOILING AND SPATTERING. NEVER ADD WATER TO ACID. ALWAYS ADD ACID
SLOWLY IN SMALL AMOUNTS TO WATER. NEVER USE HOT WATER. OBSERVE ALL
PRECAUTIONS FOR EMPTY DRUMS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR, OR
ACID VAPOR TYPE RESPIRATOR.
Ventilation:MECHANICAL(GENERAL) AND/OR LOCAL EXHAUST
Other Protective Equipment:TO PREVENT SKIN CONTACT, WEAR IMPERVIOUS
CLOTHING AND BOOTS.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:554F,290C
Spec Gravity:1.840
Evaporation Rate & Reference:< 1 (ETHER = 1)
Solubility in Water:COMPLETE
Appearance and Odor:DENSE, OILY LIQUID. COLORLESS TO DARK BROWN COLOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES, OXIDIZERS, FLAMMABLE/COMBUSTIBLE MATERIAL, POWDERED
METALS.
Stability Condition to Avoid:HIGH HEAT
Hazardous Decomposition Products:ACID FUMES, SULFUR OXIDES, HYDROGEN
GAS
==================== Disposal Considerations ====================
Waste Disposal Methods:SMALL:FLUSH DOWN DRAIN W/WATER.LARGE
SPILL:COLLECT & ADD SLOWLY TO LARGE VOL OF AGITD SOLN OF SODA
ASH/SLAKED LIME.ADD NEUTRALIZED SOLN TO EXCESS RUNNING WATER IAW
LOCAL REGULATIONS.REVIEW LOCAL,STATE /FED REGS. TO DETERMINE
DISPOSAL PROCEDURE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:70% ISOPROPYL RUBBING ALCOHOL IN WATER
CAGE:DIVIN
CAGE:DIVIN
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 70%
Other REC Limits:400 PPM
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 30%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 OR HMAN 131G ISOPROH RTECS-CHEMINFO
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SOURCE CHEMINFO(MSDS POOR)INHAL:MILD
IRRITATION @400PPM.SKIN:BRIEF EXPOSURE NOT
IRRITATING.PROLONGED-DRYING,CRACKING.EYE:MILDLY IRRITATING
@400PPM.DIRECT CONTACT MAY CAUSE SEVERE IRRITATION.INGEST:GI
DISTURBANCES.
Explanation of Carcinogenicity:THIS PRODUCT IS NOT LISTED BY IARC, NTP
OR OSHA AS A CARCINOGEN, MUTAGEN, TERATOGEN OR NEUROTOXIN.
Effects of Overexposure:INHAL:HIGH CONCENTRATIONS CAUSE
ATAXIA,DROWSINESS,DEEP NARCOSIS.INGEST:GI
PAIN,NAUSEA,CRAMPS,VOMITING,DIARRHEA ...UNCONSCIOUSNESS,DEATH.
Medical Cond Aggravated by Exposure:NOT REPORTED.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH FOR 15 MINUTES WHILE HOLDING EYELIDS OPEN.
GET MEDICAL ATTENTION. SKIN:WASH WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING. GET MEDICAL ADVICE. INHALATION: REMOVE TO
FRESH AIR. GIVE MOUTH-TO-MOUTH RESUSCITATION OR O2 IF NOT
BREATHING.GET MEDICAL ATTENTION.INGESTION:DO NOT INDUCE
VOMITING.KEEP HEAD BELOW HIPS IF VOMITING OCCURS.IF CONSCIOUS GIVE
1PT OF WARM WATER.CALL DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point: 70.0F,21.1C
Autoignition Temp:Autoignition Temp Text:750F
Lower Limits:2.0
Upper Limits:12.0
Extinguishing Media:DRY CHEMICAL OR ALCOHOL TYPE FOAM. WATER SPRAY MAY
BE INEFFECTIVE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND
FULL FACE-PIECE SELF-CONTAINED BREATHING APPARATUS. COOL FIRE
EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:RELEASES FLAMMABLE VAPOR WHICH MAY BURN
AND EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PROTECTIVE AND RESPIRATORY
EQUIPEMENT.EXTINGUISH IGNITION SOURCES.BLANKET SPILL WITH
FOAM(REDUCE VAPORS).ABSORB ONTO A NON-COMBUSTIBLE ABSORBANT;PLACE
IN APPROPRIATE CONTAINER FOR DISPOSAL. NOTIFY IN CASE OF SPILL TO
WATERWAYS,800-424-9300.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAMES. DO NOT STORE OR SHIP
IN ALUMINUM CONTAINERS.
Other Precautions:THIS MATERIAL WILL ATTACT SOME FORMS OF PLASTIC,
RUBBER OR COATINGS. EMPTY CONTAINERS MAY CONTAIN FLAMMABLE VAPORS
OR RESIDUES AND MUST BE HANDLED WITH CARE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AIR SUPPLIED MASKS IN CONFINED AREAS. NIOSH
APPROVED RESPIRATORS FOR ORGANIC MISTS/VAPORS RECOMMENDED FOR LOW
VAPOR LEVELS.
Ventilation:LOCAL EXHAUST AS NECESSARY OR MECHANICAL (GENERAL)
EXPLOSION- PROOF VENTILATION EQUIPMENT.
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
SINCE THIS MSDS WAS POOR,HMIS INCLUDED INFORMATION FROM RTECS-CHEMINFO
AS NEEDED.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:>180F,>82C
Spec Gravity:0.87
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID;CLEAR,COLORLESS;MEDICINAL ODOR
Corrosion Rate:UNKNOWNN
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS,ALUMINUM.
Stability Condition to Avoid:EXPOSURE TO AIR,HIGH HEAT,SOURCES OF
IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF OR RECOVER IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MERCURY, QUIDKSILVER, HYDRARGYRUM
Preparer's Name:SCHUYLER TILLY
CAGE:23471
CAGE:23471
============= Composition/Information on Ingredients =============
Ingred Name:MERCURY (SARA III)
CAS:7439-97-6
RTECS #:OV4550000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:S, C, 0.1 MG/M3
ACGIH TLV:S, 0.05 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN:IRRITATION. ABSORBED
THROUGH SKIN CAUSING ANURIA. EYE:IRRITATION, CORNEAL INJURY OR
BURNS. INGESTION:IMMEDIATE NECROSIS IN MOUTH, THROAT, ESOPHAGUS &
STOMACH. DEATH MAY OCCURE. INHALATION: DYSPNEA, COUGH, FEVER,
NAUSEA & VOMITING, DIARRHEA, STOMATITIS, SALIVATION & METALLIC
TASTE. CHRONIC: CNS DISTURBANCES.
Explanation of Carcinogenicity:MERCURY IS NOT LISTED BY IARC, NTP, OR
OSHA AS A CARCINOGEN.
Effects of Overexposure:TREMORS, CONVULSIONS & OTHER CNS DISTURBANCES,
PNEUMONITIS, CHEST PAINS, DYSPNEA, COUGHING, STOMATITIS, GINGIVITIS
AND LOOSENING OF TEETH, SALIVATION, LOSS OF MEMORY, METALLIC TASTE,
DIZZINESS, CLUMSI NESS, SLURRED SPEECH, DIARRHEA, PAIN & NUMBNESS
IN EXTREMITIES, NEPHRITIS, ANXIETY, HEADACHE, WEIGHT LOSS, AND
INSOMNIA.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF
ALCOHOLISM, CHRONIC KIDNEY DISEASE OR KNOWN ALLERGY TO MERCURY MAY
BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
CPR/OXYGEN. GET MEDICAL ATTENTION. EYE: IMMEDIATELY FLUSH EYES WITH
PLENTY OF WATER FOR 15 MINUTES HOLDING EYELIDS OPEN. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. WASH SKIN WITH
PLENTY OF SOAP & WATER. INGESTION: GET IMMEDIATE MEDICAL ATTENTION.
A 5% SOLUTION OF SODIUM FORMALDEHYDE SULFOXYLATE MAY BE USED TO
INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL: PICK UP WITH VACUUM EQUIPMENT
SPECIFICALLY DESIGNED FOR MERCURY PICK UP OR USE MERCURY SPILL KIT.
LARGE SPILL: EVACUATE AND VENTILATE AREA. IF POSSIBLE, STOP LEAK.
DIKE TO RETAIN. VACUUM UP FREE LIQUID. DO NOT TOUCH SPILLED
MATERIAL.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN SEALED UNBREAKABLE
POLYETHYLENE CONTAINERS IN A COOL, DRY, WELL VENTILATED AREA AWAY
FROM HEAT. PROTECT CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:THIS CHEMICAL IS SUBJECT TO SARA SECTION 313
REPORTING. PROVIDE PREPLACEMENT AND PERIODIC MEDICAL EXAMS FOR
THOSE REGULARLY EXPOSED TO MERCURY, WITH EMPHASIS ON CNS, SKIN,
LUNGS, LIVER, KIDNEYS AND G. I. TRACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE NIOSH/MSHA APPROVED RESPIRATORS AS
PER CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND
NIOSH-RESPIRATOR DECISION LOGIC-PUBL ICATION NUMBER 87.108.
Ventilation:PROVIDE SUFFICIENT GENERAL/LOCAL EXHAUST VENTILATION IN
PATTERN/VOLUME TO CONTROL INHALATION EXPOSURES BELOW OSHA'S PEL.
Other Protective Equipment:SEPARATE WORK AND STREET CLOTHING. STORE
WORK CLOTHING IN SPECIAL LOCKERS. SHOWER BEFORE CHANGING TO STREET
CLOTHES.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
DO NOT GET ON SKIN, IN EYES OR ON CLOTHING. DO NOT BREATHE VAPORS.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:675F,357C
Melt/Freeze Pt:M.P/F.P Text:-38F,-39C
Vapor Pres:0.0012
Vapor Density:7.0
Spec Gravity:13.6, DENSITY
Solubility in Water:INSOLUBLE
Appearance and Odor:SILVER-WHITE, LIQUID METAL, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS INCLUDE
TOXIC MERCURY VAPORS AND OXYGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT INCINERATE - RETURN TO RECLAMATION
CENTER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DETERGENT PD 223 B(FED SPEC)
CAGE:NCHEM
CAGE:81348
CAGE:NCHEM
============= Composition/Information on Ingredients =============
Ingred Name:DETERGENT'SYNTHETIC)
===================== Hazards Identification =====================
Effects of Overexposure:NONE FROM VAPORS.MILD EYE IRRITATION ON CONTACT
WITH CONCENTRATE.DIARRHEA FROM INGESTION.
======================= First Aid Measures =======================
First Aid:WASH CONCENTRATE FROM EYES WITH WATER UNITL IRRITATION STOPS
IF IRRITATION PERSISTS SEE A DR. IF INGESTED SEE A DR.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:NONE REQUIRED
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP EXCESS W/MOP OR WET VAC.WASH REMAINDER
TO SEWER.BIODEGRADABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BETWEEN 35-130 F
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:NONE REQUIRED
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:212 F 100 C
Vapor Pres:25M
Spec Gravity:1.10
Evaporation Rate & Reference:WATER 1
Solubility in Water:100%
Appearance and Odor:VERY LIGHT AMBER LIQUID-DETERGENT ODOR
Percent Volatiles by Volume:80
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Hazardous Decomposition Products:CO,CO*2 FROM INCINERATION
==================== Disposal Considerations ====================
Waste Disposal Methods:SEWER, LANDFILL OR INCINERATE FOLLOWING LOCAL
ORDINANCES.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:CUSTOM PLASMA STANDARD, PLC9-3X
Preparer's Name:LINDA OLCHVARY
CAGE:07977
CAGE:07977
============= Composition/Information on Ingredients =============
Ingred Name:OXALIC ACID
CAS:144-62-7
RTECS #:RO2450000
Fraction by Wt: 0-1%
OSHA PEL:1 MG/M3/2 STEL
ACGIH TLV:1 MG/M3/2 STEL; 9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: ORAL(RAT) 375 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONCENTRATED OXALIC ACID CAN BE
HARMFUL IF IT IS INHALED, INGESTED, OR ABSORBED THROUGH THE SKIN.
IT IS VERY DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES & UPPER
RESPIRATORY TRACT, SKIN & EYES. IF IN HALED, IT CAN CAUSE DEATH
RESULTING FROM SPASM, INFLAMMATION & EDEMA. IF EXPOSED TO OXALIC
ACID, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: SYMPTOMS MIGHT INCLUDE WHEEZING,
COUGHING, BURNING SENSATION, LARYNGITIS, HEADACHE, NAUSEA,
VOMITING, AND SHORTNESS OF BREATH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR A MINIMUM OF 15 MIN, OCCASIONALLY
LIFTING UPPER/LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING,
THEN FLUSH W/WATER FOR AT LEAST 15 MIN. WASH CLOTHING THOROUGHLY
BEFORE REUSE . INHAL: MOVE TO FRESH AIR. IF IRRITATION CONTINUES,
GET MED ATTN IMMEDIATELY. INGEST: CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:APPROPRIATE FOR SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. DILUTE SPILL W/WATER &
NEUTRALIZE W/SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO A SEALED
CONTR FOR PROPER DISPOSAL. WASH SPILL SITE OFF W/WATER AFTER
MATERIAL PICK-UP IS COMPLETE. WEA R SPECIAL PROTECTION EQUIPMENTS.
Neutralizing Agent:SEE SPILL/RELEASE PROCEDURES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE. KEEP
TIGHTLY SEALED WHEN NOT IN USE. HAVE IMMED AVAILABILITY OF AN EYE
WASH IN CASE OF EMERGENCY.
Other Precautions:WARNING! TOXIC & CORROSIVE. AVOID INHALATION,
INGESTION, & CONTACT WITH EYES & SKIN. WASH CAREFULLY AFTER USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:LOCAL EXHAUST: CHEMICAL FUME HOOD.
Other Protective Equipment:LAB COAT. EMERGENCY EYE WASH & DELUGE SHOWER
.
Work Hygienic Practices:WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:T6
Spec Gravity:APPROX 1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT SOLUTION WITHOUT AN ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPAT W/OXALIC ACID INCLUDES BASES, ACID CHLORIDES, ALKALI METALS, &
OXALIC ACID CORRODES STEEL.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF CO2 & CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE
DISPOSAL AGENCY FOR REGULATIONS. DISPOSAL MUST BE I/A/W FEDERAL,
STATE, AND LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:9339 CONTACT CLEANER
Preparer's Name:VERE HAGEMAN
CAGE:EO641
CAGE:72653
CAGE:EO641
============= Composition/Information on Ingredients =============
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROETHANE) (CHLOROTHENE NU),
AEROTHANE TT, CHLOROTHENE
CAS:71-55-6
RTECS #:KJ2975000
Fraction by Wt: 73%
Other REC Limits:450 PPM STEL
OSHA PEL:350 PPM
ACGIH TLV:1910 MG/CUM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:BENZIN, NAPHTHA, MINERAL SPIRITS, PETROLEUM NAPHTHA
CAS:8030-30-6
RTECS #:DE3030000
Fraction by Wt: 26%
Other REC Limits:STEL 400 PPM
OSHA PEL:500 PPM
ACGIH TLV:300 PPM
Ingred Name:DIMETHYL POLYSILOXANE (MONOMER: DIMETHYL SILOXANE),
SILICONE FLUID, DOW CORNING 200, POLYMETHYLSILOXANE
CAS:63148-62-9
RTECS #:JT6484500
Fraction by Wt: <1%
Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL
CARBINOL
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: <1%
Other REC Limits:400 PPM
OSHA PEL:400 PPM
ACGIH TLV:400 PPM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: CONJUNCTIVITIS. SKIN:
DERMATITIS. INHALATION: IRRITATION OF NOSE & THROAT, COUGH,
DIZZINESS, BRONCHITIS, PNEUMONIA, DROWSINESS, & BLURRED VISION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: COMA, CONVULSIONS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR 15 MINS OR MORE. SKIN: WASH W/SOAP &
WTER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN OR ARTIFICIAL
RESPIRATION. INGESTION: DON'T INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:OC
Flash Point:25C
Lower Limits:2%
Upper Limits:12%
Extinguishing Media:CO2, FOAM
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:TOXIC GASES EMITTED WHEN EXPOSED TO FLAME
OR HIGH HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP W/ABSORBENT MATERIAL. SEAL IN METAL
CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM FLAME OR HIGH HEAT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR SELF-CONTAINED BREATHING APPARATUS.
Ventilation:MECHANICAL: NORMAL VENTILATION SHOULD SUFFICE.
Other Protective Equipment:BUTYL APRON
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:60C
Vapor Density:>1
Spec Gravity: 0.87
Solubility in Water:SLIGHT
Appearance and Odor:RED TRANSPARENT LIQUID, ALCOHOL/SOLVENT ODOR.
Percent Volatiles by Volume:94%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY BE SLIGHTLY CORROSIVE TO ALUMINUM ALLOYS.
Stability Condition to Avoid:FLAME, HIGH HEAT, FIRE
Hazardous Decomposition Products:TOXIC GASES
==================== Disposal Considerations ====================
Waste Disposal Methods:AUTHORIZED INCINERATOR IN ACCORDANCE W/LOCAL,
STATE, & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:EL16 PT B
Kit Part:Y
CAGE:TO189
CAGE:TO189
============= Composition/Information on Ingredients =============
Ingred Name:NON AROMATIC AMINE
> Wt:10.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION OF
RESPIRATORY PASSAGES. INGESTION: MAY CAUSE IRRITATION OF MOUTH AND
DIGESTIVE TRACT. MAY BE TOXIC BY INGESTION. CONTACT WITH SKIN AND
EYES: CAUSES EYE BURNS IN RABBI TS. A SIMILAR DEGREE OF EYE INJURY
WOULD PROBABLY OCCUR IN HUMANS. MILDLY IRRITATING TO RABBIT SKIN
AND LIKELY TO IRRITATE HUMAN SKIN ALSO.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. KEEP WARM AND AT REST. IN
CASE OF RESPIRATORY DISTRESS, GIVE OXYGEN AND OBTAIN MEDICAL
ATTENTION IMMEDIATELY. SKIN: WASH IMMEDIATELY REMOVING CONTAMINATED
CLOTHING WH ILE WASHING PROCEEDS. CONTINUE WASHING FOR AT LEAST 15
MINUTES. CONTAMINATED CLOTHING SHOULD BE DRY CLEANED BEFORE USE.
EYE CONTACT: IMMEDIATELY FLOOD WITH COPIOUS AMOUNTS OF WATER FOR AT
LEAST 15 MIN UTES. OBTAIN MEDICAL ATTENTION IF SORENESS PERSISTS.
INGESTION: OBTAIN MEDICAL ATTENTION URGENTLY. DO NOT INDUCE
VOMITING BECAUSE OF THE RISK OF ASPIRATION.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE DRY CHEMICAL, FOAM OR CARBON DIOXIDE
EXTINGUISHERS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CLASSIFIED AS FLAMMABLE BY UK/EEC
REGULATIONS. THERMAL DEGRADATION MAY PRODUCE AMMONIA, NITROGEN
OXIDES AND/OR CYANIDE.
================== Accidental Release Measures ==================
Spill Release Procedures:EXTINGUISH ALL SOURCES OF IGNITION AND TRY TO
PREVENT SPILLS ENTERING DRAINS OR WATER COURSES. ABSORB SPILLS IN
EARTH, SAND OR OTHER INERT MATERIAL AND REMOVE TO A SAFE PLACE FOR
DISPOSAL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:AVOID CONTACT WITH SKIN AND INHALATION OF VAPORS.
ATMOSPHERIC CONCENTRATIONS SHOULD BE MINIMIZED BY THE PROVISION OF
ADEQUATE VENTILATION.
FACESHIELD .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . ADDITIONAL PROTECTIVE CLOTHING WHERE NECESSARY.
Work Hygienic Practices:MAINTAIN GOOD STANDARDS OF INDUSTRIAL HYGIENE
DURING USE.
Supplemental Safety and Health
PHYSICAL DATA - SOLUBILITY IN ORGANIC SOLVENT: <45% @ 25C; DENSITY:
1300-2000 KG/M3.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:>40.C, 104.F
Vapor Pres:NA
Solubility in Water:<20 WT % @ 20C
Appearance and Odor:WHITE PASTE WITH DISTINCTIVE ODOR.
=================== Toxicological Information===================
Toxicological Information:THE TOXICOLOGICAL PROPERTIES OF THESE
MATERIALS HAVE NOT BEEN FULLY ASSESSED AND CARE SHOULD BE EXERCISED
IN THEIR HANDLING.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .
=================== MSDS Transport Information ===================
Transport Information:TRANSPORT CLASSIFICATION: N/A.
===================== Regulatory Information =====================
State Regulatory Information:
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:104/105/107 COPPER/COPPER ALLOYS
CAGE:40518
CAGE:40518
============= Composition/Information on Ingredients =============
Ingred Name:SILVER
CAS:7440-22-4
RTECS #:VW3500000
Fraction by Wt: <1%
OSHA PEL:0.01 MG/CUM
ACGIH TLV:0.1 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: BALANCE
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:RESPIRATORY TRACT IRRITATION, METAL
FUME FEVER, EYE IRRITATION. LEAD INTOXICATION INCLUDING KIDNEY
DISEASE, ANEMIA, NERVOUS DISORDERS, REPRODUCTIVE EFFECTS, BIRTH
DEFECTS & KIDNEY CANCER. COPPER FUMES CAUSES METAL FUME FEVER,
SKIN/HAIR DISCOLORATION, KERATINIZATION OF HANDS/FEET SOLES, &
CHRONIC BRONCHITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:METAL FUME FEVER SYMPTOMS: SWEET OR METTALLIC
TASTE IN MOUTH, DRYNESS & THROAT IRRITATION, COUGH, SHORTNESS OF
BREATH, CHEST PAIN, NAUSEA, VOMITING, WEAKNESS, FATIGUE,
MUSCLE/JOINT PAIN, CHILLS & SWEA TING. COPPER: SKIN/HAIR
DISCOLORATION. SILVER: PERMANENT PIGMENTATION (GRAY TO PURPLE) OF
SKIN & EYES. SEE SUPP.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER. SKIN: VACUUM OFF EXCESS DUST. WASH
W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR. METAL FUME FEVER
MAY BE TREATED SYMPTOMATICALLY. INGESTION: OBTAIN MEDICAL ATTENTION
IF LARGE Q UANTITIES HAVE BEEN INGESTED. OBTAIN MEDICAL ATTENTION
IN ALL CASES.
===================== Fire Fighting Measures =====================
Fire Fighting Procedures:SOLID MASSIVE FORM ISN'T COMBUSTIBLE. WEAR
SELF-CONTAINED BREATHING APPARATUS & PROTECTIVE CLOTHING. WHEN IN
DUST FORM USE DRY CHEMICAL/SAND.
Unusual Fire/Explosion Hazard:FIRE & EXPLOSION HAZARDS ARE MODERATE
WHEN MATERIAL IS IN THE FORM OF DUST & EXPOSED TO HEAT, FLAMES,
CHEMICAL REACTION OR IN CONTACT W/POWDERFUL OXIDIZERS.
================== Accidental Release Measures ==================
Spill Release Procedures:LARGE QUANTITIES OF DUST: VACUUM/WET SWEEP.
LIQUIDS W/SOLID METAL: EVACUATE AREA. ABSORB W/VERMICULATE/DRY
SAND/SIMILAR MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:GOOD HOUSEKEEPING MUST BE PRACTICED
DURING STORAGE, TRANSFER & USE. AVOID EXCESSIVE DUST ACCUMULATION.
Other Precautions:ALWAYS EVALUATE THE JOBS DONE ON THIS PRODUCT IN
ACCORDANCE W/OSHA, FEDERAL, STATE OR LOCAL STANDARDS. APPLY
RECOMMENDATIONS OF NFPA 49 FOR COPPER ALLOYS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/OSHA APPROVED RESPIRATORY PROTECTION
IF EXPOSURE EXCEEDS THE PEL/TLV LIMITS.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL): REQUIRED IF DUST/FUME
CREATED IN HANDLING OR WORKING ON THIS MATERIAL
Other Protective Equipment:GRINDING OPERATIONS MAY REQUIRED FACE
SHIELDS. MELTING/WELDING REQUIRE FACE SHIELDS W/SPECIALTY TINTED
GLASS.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE. WASH HANDS BEFORE
EATING/DRINKING/SMOKING/LEAVING WORK AFTER CONTACT W/METAL DUST OR
FUME.
Supplemental Safety and Health
UNDER NORMAL CONDITIONS THE SOLID ALLOY PRESENTS NO SIGNIFICANT HEALTH
HAZARDS. PROCESSSING OF THE ALLOY BY DUST/FUME PRODUCING OPERATION
(GRINDING/BUFFING/HEATING/WELDING) MAY RESULT IN POTENTIAL FOR
EXPOSURE TO AIRBORNE METAL PARTICULATES/FUME.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text: 1500-2260F
Spec Gravity:7.4-9
Solubility in Water:INSOLUBLE
Appearance and Odor:SILVER OR YELLOW TO RED SOLID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES & OXIDERS. MAY REACT VIOLENTLY W/WATER. MERCURY,
AMMONIA & ACETYLENE.
Stability Condition to Avoid:HEAT, FLAMES
Hazardous Decomposition Products:METAL FUME
==================== Disposal Considerations ====================
Waste Disposal Methods:MAXIMIZE PRODUCT RECOVERY FOR REUSE OR
RECYCLING. CONDITIONS MAY CAUSE THIS MATERIAL TO BECOME A SOLID
HAZARDOUS WASTE. SOLID WASTE LEACHATE TESTING MAY INDICATE THE NEED
FOR PROPERLY PERMITTED DISPOS AL IN ACCORDANCE W/FEDERAL, STATE, &
LOCAL LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FERROTITANIUM (HIGH TI GRADE), PC3434
CAGE:1N758
CAGE:1N758
============= Composition/Information on Ingredients =============
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 9%
OSHA PEL:15 MG/M3 DUST;5 RESP
ACGIH TLV:10 MG/M3 DUST;5 FUME
Ingred Name:CARBON
CAS:7440-44-0
RTECS #:FF5250100
Fraction by Wt: 0-2%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9293
Ingred Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
OSHA PEL:10 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: 0-14%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:TITANIUM (LIMITS AS TITANIUM DIOXIDE)
CAS:7440-32-6
RTECS #:XR1700000
Fraction by Wt: 38-75%
OSHA PEL:10 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EFFECTS ASSOCIATED WITH OVEREXPOSURE
TO METAL DUSTS MAY INCLUDE RESPIRATORY IRRITATION, CONJUNCTIVITIS,
PNEUMOCONISIS, ETC.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:IF IRRITATION OCCURS,
REMOVE TO FRESH AIR. CONTACT A PHYSICIAN. SKIN:IF IRRITATION
OCCURS, WASH SKIN. CONTACT A PHYSICIAN. EYES:IF IRRITATION OCCURS,
FLUSH EYE S WITH WATER FOR AT LEAST 15 MINUTES. CONTACT A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Extinguishing Media:CLASS D FIRE: DO NOT USE WATER. USE DRY CHEMICAL,
DRY SAND OR CARBON DIOXIDE TO SMOTHER FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. FIRE MAY BE ISOLATED & ALLOWED TO BURN ITSELF OUT. DO NOT DISTURB
BURNING METAL WHILE EXTING FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXPLOSIONS MAY BE INITIATED BY
EXPOSING ANY CONCENTRATED DUST SUSPENSION IN AN ENCLOSED INDUSTRIAL
AREA TO A SPARK OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:NO SPECIAL STEPS NECESSARY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID AND CONTROL OPERATIONS WHICH
CREATE DUSTING.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN DUSTY AREAS, USE A NIOSH/MSHA APPROVED
SCHEDULE 21C RESPIRATOR.
Ventilation:LOCAL EXHAUST IS RECOMMENDED WHERE DUSTING MAY OCCUR. USE
MECHANICAL (GENERAL) VENTILATION FOR GENERAL AREA CONTROL.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:2912F,1600C
Spec Gravity:5
Solubility in Water:INSOLUBLE/NEGLIGIBLE
Appearance and Odor:GRAYISH METALLIC, LUMP OR POWDER, ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, STRONG OXIDIZERS, STRONG BASES AND MOISTURE.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:N-TETRADECANE
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:TETRADECANE
CAS:629-59-4
RTECS #:XB8000000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPP DATA: OR ANY DISCOLORATION OF STORAGE TANK DUE TO
FIRE(1876 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.4,(ING 3)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 2: GUIDE PAGE 27). EXTINGUISH ONLY IF FLOW CAN BE
STOPPED; USE FLOODING AMOUNTS OF WATER AS A FOG, SOLID (ING 4)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 3: STREAMS MAY BE INEFFECTIVE. COOL CONTAINERS WITH
FLOODING AMOUNTS OF WATER, APPLY FROM AS FAR A DISTANCE(ING 5)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 4: AS POSSIBLE. AVOID VAPORS, KEEP UPWIND.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:EFTS OF OVEREXP: EDEMA & HEMORRHAGING. CHRONIC: INHAL:
PLNGD EXPOS TO LGE VAP CONC MAY CAUSE IRRIT & CNS DEPRESS.(ING 7)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 6: RPTD/PRLNGD CONTACT OF LIQUID W/SKIN MAY CAUSE DERM
W/DRYING & CRACKING DUE TO DEFATTING ACTION. THIS MATL(ING 8)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 7: APPLIED TO SKIN OF MICE INTERMITTENTLY FOR 20 WEEKS
PRDCED TUMORS AT SITE APPLICATION. EYE: PRLNGD EXPOS (ING 9)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 8: TO VAPOR MAY CAUSE CONJUNCTIVITIS. ANTIDOTE: NO
SPECIFIC ANTIDOTE. TREAT SYMPTOMATICALLY & SUPPORTIVELY.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:FIRST AID PROC: AMOUNTS OF WATER UNTIL NO EVIDENCE OF
CHEMICAL REMAINS(APPROX 15-20 MINS). GET MED ATTN IMMED.(ING 11)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 10: INGEST: TREAT SYMPTOMATICALLY & SUPPORTIVELY. GET
MED ATTN & ADVICE ON WHETHER TO USE(ING 12)
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 11: GASTRIC LAVAGE. EXTREME CARE MUST BE TAKEN TO PVNT
ASPIRATION. A CUFFED ENDOTRACHEAL TUBE USED BY (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: QUALIFIED MEDICAL PERSONNEL MIGHT BE ADVISABLE.
KEEP HEAD LOWER THAN HIPS TO PREVENT ASPIRATION SHOULD (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13: VOMITING OCCUR.
RTECS #:9999999ZZ
Ingred Name:RESP PROT:THE WORKING LIMITS OF THE RESPIRATOR & BE JOINTLY
APPROVED BY NIOSH/MSHA. CHEMICAL CARTRIDGE RESP W/(ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15: AN ORG VAP CARTRDIGES(S) W/FULL FACEPIECE. GAS MASK
W/ORG VAP CANISTER (CHIN-STYLE/FRONT/BACK-MOUNTED(ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16: CANISTER) W/FULL FACEPIECE. TYPE "C" SUPPLIED AIR
RESP W/FULL FACEPIECE OPERATED IN PRESS-DEMAND/OTHER(ING 18)
RTECS #:9999999ZZ
Other REC Limits:NONE RECOMMENDED
Ingred Name:ING 17:POSITIVE PRESS MODE W/FULL FACEPIECE, HELMET/HOOD
OPERATED IN CONTINUOUS-FLOW MODE. SCBA APPARATUS W/FULL(ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:FACEPIECE OPERATED IN PRESS-DEMAND/OTHER POSITIVE
PRESSURE MODE.
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP: SHOULD PROVIDE EYEWASH FOUNTAIN WHICH
MEETS ANSI DESIGN CRITERIA W/IN IMMED WORK AREA FOR EMERG USE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: IRRIT/NARCOTIC. SKIN: IRRIT.
EYE: IRRIT. INGEST: NARCOTIC. ACUTE: INHAL: EXPOS TO LGE VAP CONC
MAY CAUSE IRRIT OF MUC MEMBS. SYSTEMIC EFTS MAY ALSO OCCUR W/HDCH,
NAUS, DIZZ & OTHER CNS EFTS. SK IN: MAY CAUSE IRRIT & PERCUTANEOUS
ABSORP. ALKANES HAVE BEEN SHOWN TO BE ABSORBED INTO HUMAN TISS.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: IN ANIMAL STUDIES VARIOUS MEMBERS OF
THE ALKANE GROUP HAVE PRDCD SYSTEMIC INTOX W/SYMPS OF CNS DEPRESS.
EYE: MAY CAUSE IRRIT. INGEST: MAY CAUSE NAUS, DIARR & OTHER GI
DISTURBS ALONG W/SYMPS OF CNS DEPRESS. ASPIR OF LIQ INTO LUNGSMAY
OCCUR. IN ANIMALS STUDIES, ASPIR PRDCD ASPHYXIA RSLTG IN PNEUM,
PULM(ING 6)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMED. IF BRTHG
HAS STOPPED, PERFORM ARTF RESP. KEEP PERS WARM & AT REST. TREAT
SYMPTOMATICALLY & SUPPORTIVELY. GET MED ATTN IMMED. SKIN: REMOVE
CONTAMD C LTHG & SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD
DETERGENT & LGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL
REMAINS(APPROX 15-20 MINS). GET MED ATTN IMMED. EYE: WASH EYES
IMMED W/LGE(ING 10)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:212F,100C
Lower Limits:0.5%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER
SPRAY/STANDARD FOAM. FOR LGR FIRES: USE WATER SPRAY, FOG/STANDARD
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
MOVE CNTNR FROM FIRE AREA IF POSS. COOL FIRE-EXPOSED CNTNRS W/WATER
FROM SIDE UNTIL WELL AFTER(SUPDAT)
Unusual Fire/Explosion Hazard:SLIGHT FIRE HAZARD WHEN EXPOSED TO HEAT
OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:OCCUP SPILL: STOP LEAK IF YOU CAN DO IT W/OUT
RISK. FOR SMALLS, TAKE UP W/SAND/OTHER ABSORB MATL & PLACE INTO
CLEAN, DRY CNTNRS FOR LATER DISP. KEEP UNNEC PEOPLE AWAY. ISOLATE
HAZARD AREA & DENY ENTRY .
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOWING RESPS ARE RECOMM BASED ON INFOR FOUND
IN PHYSICAL DATA, TOX & HLTH EFTS SECTIONS. THEY ARE RANKED IN
ORDER FROM MIN TO MAX RESP PROT. SPECIFIC RESP SELECTED MUST BE
BASED ON CONTAMD LEVELS F OUND WORK PLACE, MUST NOT EXCEED(ING 15)
Ventilation:PROVIDE LOCAL EXHAUST VENT &/GENERAL DILUTION VENTILATION
TO MEET PUBLISHED EXPOSURE LIMITS.
Other Protective Equipment:EMER EYEWASH: WHERE THERE IS ANY POSS THAT
AN EMPLOYEE'S EYES MAY BE EXPOSED TO THIS SUBSTANCE, THE
EMPLOYER(ING 20)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA: FOAM(1987 EMERGENCY RESPONSE GUIDEBOOK, DOT P 5800.4).
FIRE FIGHT PROC: FIRE IS OUT. STAY AWAY FROM STOR TANK ENDS FOR
MASSIVE FIRE IN STORAGE AREA, USE UNMANNED HOSE HOLDER/MONITOR NOZZ
S, ELSE WITHDRAW FROM AREA & LET FIRE BURN. WITHDRAW IMMED IN CASE
OF RISING SOUND FROM VENTING SAFETY DEVICE(ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:489F,254C
Melt/Freeze Pt:M.P/F.P Text:43.0F,6.1C
Vapor Pres:1 @ 76.4C
Vapor Density:6.83
Spec Gravity:0.767 @ 25C
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
TETRADECANE: OXIDIZERS: MAY REACT VIOLENTLY OR VIGOROUSLY.
Stability Condition to Avoid:MAY BURN BUT DOES NOT IGNIT READILY. AVOID
CONTACT W/STRONG OXIDIZERS, EXCESSIVE HEAT, SPARKS OR OPEN FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:26-027
CAGE:01094
CAGE:60020
CAGE:01094
============= Composition/Information on Ingredients =============
Ingred Name:PIGMENTS
Fraction by Wt: 50%
Ingred Name:VEHICLE
Fraction by Wt: 16.3%
Ingred Name:SOLVENTS
Fraction by Wt: 32%
ACGIH TLV:200 PPM
Ingred Name:ADDITIVES
Fraction by Wt: 1.7%
Ingred Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: .08%
OSHA PEL:0.05 MG/M3;1910.1025
ACGIH TLV:0.15 MG/M3;DUST 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:EYE IRRITATION, DRYING OF SKIN; HEADACHES,
DIZZINESS
======================= First Aid Measures =======================
First Aid:FLUSH EYES WITH WATER, WASH SKIN WITH MILD SOAP AND WATER;
REMOVE TO FRESH AIR.
===================== Fire Fighting Measures =====================
Flash Point:90F, 32.2C TCC
Lower Limits:.9
Upper Limits:6
Extinguishing Media:H20, C02, FOAM, DRY CHEMICAL
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE SOURCES OF IGNITION ARE OR CONTAINER
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, OPEN
FLAME. USE WITH ADEQUATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELF CONTAINED BREATHING APPARATUS
Ventilation:LOCAL EXHAUST
Other Protective Equipment:NO
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:253F,122.8C
Vapor Pres:12
Vapor Density:>AIR
Spec Gravity:1.290
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK LIQUID
Percent Volatiles by Volume:70
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME
Hazardous Decomposition Products:CO
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE UNDE SAFE CONDITIONS OR DISPOSE OF IN
ACCORANCE WITH REGULATIONS
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:TT-P-102E TYPE I WHITE REV'83 700W13
Preparer's Name:ROBERT COMMISSO
CAGE:58962
CAGE:58962
CAGE:58963
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS
(VAPOR PRESSURE 2 MMHG @ 68F)
Fraction by Wt: 15%
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 15%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:MAGNESIUM SILICATE
CAS:1343-90-4
RTECS #:OM4360000
Fraction by Wt: 10%
ACGIH TLV:2 MG/M3
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 0.16%
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 0.16%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:VOC. ORGANIC CMPD 2.18 LB/GAL LESS WATER & NPRS* 261 G/L
RTECS #:9999999VO
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:YES
Health Hazards Acute and Chronic:MAY BE ABSORBED THROUGH THE SKIN.
ASPIRATION INTO THE LUNGS MAY CAUSE PNEUMONTITIS, PULMONARY EDEMA &
HEMORRAGE. INHAL. OF HI CONCENT. OF VAPORS MAY LEAD TO LUNG
CHANGES, NAUSEA, VOMITING,COUGH,PULMONARY IRRIT. & CENTRAL
NERVOUS SYSTMDEPRESSION.
Effects of Overexposure:EYE: MAY CAUSE IRRITATION; SKIN: MAY CAUSE
IRRITATION, DERMITITIS,DEFATTINGINHAL: MAY CAUSE
DROWSINESS,DIZZINESS,FATIGUE FOLLOWED BY COMA.
INGST: GASTROINTESTINAL DISTURBANCES
Medical Cond Aggravated by Exposure:AILMENTS INVOLVING SKIN, CENTRAL
NERVOUS SYSTEM, LIVER AND KIDNEY.
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH W/LG AMNTS OF WTR FOR 15 MINS., GET
MEDICAL ATTENTION SKIN: WASH THOROUGHLY W/SOAP & WATER, SEEK
MEDICAL ATTENTION INGST: IMMEDIATELY SEEK
MEDICAL AID. DO NOT INDUCE VOMITING. DO NOT ATTEMPT TOGIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:54F/12.2C
Autoignition Temp:Autoignition Temp Text:**
Lower Limits:1.0
Upper Limits:NA
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG
Fire Fighting Procedures:APPROVED GAS MASK REQUIRED FOR FIRE FIGHTING
PERSONNEL. WATER MAY BE INEFFECTIVEWATER MAY BE USED TO COOL
CONTAINERS, IF WTR IS USED FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELEC. EQUIP, SPARKS, AND OPENFLAME. CLOSED CONTAINERS
MAY EXPLODE WHEN EXPOSED TO HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. REMOVE ALL
SOURCES OF IGNITION. STAY UPWIND. ABSROB W/INERT MATERIAL.FLUSH
AREA WITH WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED/UPRIGHT TO
PREVENT LEAKAGE.DO NOT USE IN CONFINED AREAS, TANK OR PIT,
WITHOUTADEQUATE VENTILATION.
Other Precautions:AVOID FLAMES, WELDING, OPEN LIGHTS, ETC. AVOID SKIN
AND EYE CONTACT. AVOIDBREATHING OF VAPORS AND SPRAY MIST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WITHIN OSHA PROTECTION FACTOR, AIR PURIFYING
OV/FILTER UNITS OK FOR USE.
Ventilation:LOCAL AND MECHANICAL EXHAUST
Other Protective Equipment:EYE BATH AND SAFETY SHOWERS.
Work Hygienic Practices:MAINTAIN GOOD PERSONAL HYGIENE
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:147-310F
Vapor Density:> AIR
Spec Gravity:1.5
Viscosity:75-95 KU
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NIL
Appearance and Odor:VISCOUS LIQUID WITH TYPICAL PAINT ODOR
Percent Volatiles by Volume:32.87
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:FLAMES, SPARKS, SMOKING AND HEAT
Hazardous Decomposition Products:CARBON MONOXIDE/DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL FEDERAL, STATE,
ANDLOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:37 FLESH PHOTO OIL COLOR
CAGE:JOHNM
CAGE:JOHNM
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOL (ETHYL ALCOHOL), TECSOL, ALCOHOL
CAS:64-17-5
RTECS #:KQ6300000
Fraction by Wt: >0.5%
Other REC Limits:1900 MG/CUM
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ingred Name:HYDRATED ALUMINA, ALUMINUM HYDROXIDE, ALUMINUM OXIDE
HYDRATEALUMINA TRIHYDRATE, ALUMINUM TRIHYDROXIDE
CAS:21645-51-2
RTECS #:BD0940000
Fraction by Wt: 22.7%
OSHA PEL:15 MG/CUM (DUST)
ACGIH TLV:2 MG/CUM (DUST)
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: CONTACT MAY CAUSE REDNESS,
TEARING. SENSITIVE INDIVIDUALS MAY EXPERIENCE DERMATITIS AFTER LONG
EXPOSURE TO SKIN. INGESTION OF LARGE AMOUNTS MAY CAUSE GI UPSET.
INHALATION: MILD IRRITATION OF NOS E, THROAT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:REDNESS, TEARING, IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/LUKEWARM WATER FOR 15 MINUTES. SKIN:REMOVE
W/WATERLESS CLEANER THEN WASH W/SOAP & WARM WATER. INHALATION:
REMOVE TO FRESH AIR. INGESTION: KEEP WARM/QUIET. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:148F
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:AVOID USE OF WATER, BUT IF ONLY ALTERNATIVE,
IMPLEMENT. USE WATER TO KEEP FIRE EXPOSED CONTAINERS COOL.
Unusual Fire/Explosion Hazard:RAGS & WASTE PAPER CONTAINING THIS
MATERIAL MAY HEAT & BURN SPONTANEOUSLY.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: PICK UP W/ABSORBENT MATERIAL & TRANSFER
INTO CLOSED METAL CONTAINERS & SOAKED W/WATER. LARGE: CAN BE
SCOOPED UP & PUT INTO CONTAINERS & SALVAGED.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID ACCUMULATION OF CONTAMINATED
RAGS/WIPING MATERIALS BY IMMEDIATE IMMERSION IN WATER, STORE IN
METAL CAN W/TIGHT LIDS.
Other Precautions:PREVENT REPEATED/PROLONGED SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Ventilation:INTERMITTENT CLEAN AIR EXCHANGES
Other Protective Equipment:EYE WASHES
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:0.5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHLORIDE, CHLORINATED RUBBER
Hazardous Decomposition Products:CO2, CO
==================== Disposal Considerations ====================
Waste Disposal Methods:CAREFULLY INCINERATE/USE SECURE LANDFILL/SPECIAL
WASTE LANDFILL IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MIL-C-22750F, ACTIVATOR, PART B UO-135
Kit Part:Y
Preparer's Name:DAVID SCHMETTERER
CAGE:DO165
CAGE:DO165
CAGE:5V430
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III) (VP =
71.2 MMHG)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 46.0%
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:NH2CH2CH(CH3)(CH2)3NH2 (VP=130.0 MMHG)
CAS:15520-10-2
RTECS #:SA0248500
Fraction by Wt: 23.0%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT EST.
ACGIH TLV:NOT EST.
Ingred Name:PHENYL CARBINOL (MAY CONTAIN AS IMPURITIES: 100-52-7
BENZALDEHYDE 0.3%, 103-50-4 DIBENZYL ETHER 0.1%, 150-76-5 0.025%
CAS:100-51-6
RTECS #:DN3150000
Fraction by Wt: 20.0%
Other REC Limits:NONE RECOMMENDED
Ingred Name:EPOXY RESIN
CAS:25085-99-8
Fraction by Wt: 8.9%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:REPEATED/PROLONGED OCCUPATIONAL
OVEREXPOSURE TO SOLVENTS ASSOCIATED W/PERMANENT BRAIN/NERVOUS
SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING THE CONTENTS MAY BE HARMFUL O R FATAL. PROLONGED
OVEREXPOSURE (INHAL)MAY CAUSE DELAYED LUNG DISEASE.
Explanation of Carcinogenicity:MAY CONTAIN TRACE AMTS OF SOME CHEM
KNOWN TO THE STATE OF CATO BE CARCINOGENS OR REPRODCTIVE TOXINS.
Effects of Overexposure:OVEREXPOSURE MAY PRODUCE VARIOUS EFFECTS. ACUTE
TOXICITY (HEADACHE, DIZZINESS, NAUSEA, LOSS CONSCIOUSNESS. SEVERE
EYE IRRITATION POSSIBLY RESULTING PERMANENT DAMAGE. IRRITATED
MUCOUS MEMBRANES. VOMITI NG FROM INGESTION. SKIN DEFATTING/DRYING.
SENSITIZATION AFTER REPEATED CONTACT.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/PLENTY CLEAN H20 15 MIN, LIFTING LIDS, GET MED
ATTN. INHAL: GET FRESH AIR, PROVIDE OXYGEN IF BREATH DIFFICULT.
GIVE ARTIF RESP IF NOT BREATHING. GET MED ATTN. KEEP VICTIM
WARM/QUIET. NEVE R GIVE UNCONS PERSON LIQ. INGEST: CALL DR. IMMED.
DON'T INDUCE VOMIT. IF VOMIT SPONTANEOUSLY, KEEP HEAD BELOW HIPS.
SKIN: FLUSH W/H20 WHILE REMOVING CONTAM CLOTHES/SHOES. IF IRRIT
PERSIST, GET MED AID
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:22.0F,-5.6C
Lower Limits:1.8
Extinguishing Media:FOAM, CO2, OR DRY CHEMICAL
Fire Fighting Procedures:WATER MAY BE USED TO KEEP EXPOSED CONTAINERS
COOL & KEEP FLAMMABLE STRUCTURE WETDON'T ENTER FIRE AREA WITHOUT
PROPER PROTECTION, HAZARDOUS DECOMP MAY BE PRESENT
Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE
LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVER HEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:WARNING - FLAMMABLE. ELIMINATE ALL IGNITION
SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING.
SOAK UP WITHABSORBENT & PLACE IN NON-LEAKING CONATINERS. SEAL
TIGHTLY FOR PROPER DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:TREAT AS A HAZARDOUS-FLAMMABLE
MATERIAL. KNOW APPLICABLE D.O.T. REG. BEFORE ATTEMPTING TO
TRANSPORT THIS MATERIAL.
Other Precautions:WARNING: HOT ORGANIC CHEMICAL VAPORS OR MISTS ARE
SUSCEPTIBLE TO SUDDEN SPONTANEOUS COMBUSTION WHEN MIXED W/AIR.
IGNITION MAY OCCUR @ TEMPS BELOW THOSE PUBLISHED AS
AUTOIGNITION/IGNITION TEMPS. IGNITI ON TEMPS DECREASE W/INCREASING
VAPOR*
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IMPORTANT-MUST PROVIDE ADEQUATE VENT TO MAINTAIN
VAPOR CONCENTRATE BELOW ESTAB- LISHED TLV LIMIT AS GIVEN BY OSHA.
IN MORE CONFINED AREAS A NIOSH/MSHA APPROVED RESPIRATOR EQUIPPED
WITH ORGANIC VAPOR C ARTRIDGE SHOULD BE WORN.
Ventilation:MUST PROVIDE ADEQUATE VENTILATION, SEE PARAGRAPH ABOVE.
Other Protective Equipment:HAVE EYE BATH & SAFETY SHOWER AVAILABLE.
Supplemental Safety and Health
KEY1:F3. *VOLUME AND VAPOR/AIR CONTACT TIME AND ARE INFLUENCED BY PRESS
CHANGES. IGNITION MAY OCCUR AT TYPICAL ELEVATED TEMP PROCESS
CONDITIONS, ESPECIALLY IN PROCESS OPERATING UNDER VACUUM IF SUBJEC
TED TO SUDDEN INGRESS OF AIR, OUTSIDE PROCESS EQUIPMENT OPERATING
UNDER ELEVATED PRESS IF SUDDEN ESCAPE OF VAPORS/MIST.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:175 TO 401F
Vapor Density:>AIR
Spec Gravity:0.89
Viscosity:70 KU
Evaporation Rate & Reference:3.31 X N-BUTYL ACETATE
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR LIQUID
Percent Volatiles by Volume:73.3
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS & STRONG ALKALIES. NOT CORROSIVE TO METAL.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, STRONG
ALKALIES, & OXIDIZING AGENTS.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION OR PRODUCTS LIKE
THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER TOXIC
GASES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH CURRENT
LOCAL, STATE & FEDERAL REG. CONTACT AN APPROVED DISPOSAL FACILITY
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:KETAC-SILVER MAXICAP LIQUID
CAGE:JO596
CAGE:JO596
CAGE:D8001
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTACT WITH EYES MAY CAUSE IRRITATION
DUE TO FOREIGN BODY REACTION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:UNKNOWN.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE
OXYGEN/ARTIFICIAL RESPIRATION) . SKIN: FLUSH W/COPIOUS AMOUNTS OF
WATER. CALL MD . EYES: FLUSH PROMPTLY WITH FLOWING WATER FOR AT
LEAST 15 MINUTES. IF IRRITATION DEVELOPS, CONSULT MD. INGEST:
DRINK PLENTY OF WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP AND DISCARD IN A SUITABLE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA AWAY FROM
FOODSTUFF AND BEVERAGES.
Other Precautions:HANDLING OF THE PRODUCT EXCLUSIVELY BY DENTAL
SPECIALISTS ACCORDING TO THE INSTRUCTIONS FOR USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:AVOID EYE CONTACT. DO NOT EAT, DRINK OR SMOKE
WHEN USING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Vapor Pres:16 @ 68F
Vapor Density:<1.0
Spec Gravity:>1 (H*2O=1)
Evaporation Rate & Reference:1.0 (BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID; SLIGHTLY ACIDIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NOT ESTABLISHED.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE CARRIED OUT IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:413 BLUE COLOR AGENT
Preparer's Name:S ABDUL RAZZAK
CAGE:16522
CAGE:16522
============= Composition/Information on Ingredients =============
Ingred Name:NON HAZARDOUS INGREDIENTS.
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION, SENSITIZATION AND
DERMATITIS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR A MINIMUM OF 15 MINUTES. IF
IRRITATION EXISTS, SEEK MED ATTN. SKIN: WASH EXPOSED AREAS W/ SOAP
& WATER. INHAL: REMOVE TO FRESH AIR & RESTORE BREATHING, IF
NECESSARY. INGEST: DO NOT INDUCE VOMITING. CONSULT MD.
===================== Fire Fighting Measures =====================
Flash Point:200F,93C
Extinguishing Media:FOAM, DRY CHEMICAL CO2.
Fire Fighting Procedures:WATER MAY BE USED TO COOL CLOSED CONTRS TO
PVNT PRESS BUILD UP & POSS AUTOIGNIT OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT. USE NIOSH/MSHA APPRVD (SUPP DATA)
Unusual Fire/Explosion Hazard:DECOMPOSITION & COMBUSTION PRODUCTS MAY
BE TOXIC.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP SPILLED MATERIAL AND DISCARD INTO
PROPER WASTE CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM HIGH HEAT & OPEN
FLAME.
Other Precautions:USE PROTECTIVE CREAMS WHERE SKIN CONTACT IS LIKELY.
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NORMALLY NONE NECESSARY. IF EXPOSURE LIMITS ARE
EXCEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: SCBA & FULL PROTECTIVE EQUIPMENT .
================== Physical/Chemical Properties ==================
HCC:V4
Vapor Density:HVR/AIR
Spec Gravity:1.05 +/- 0.25
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:BLUE PASTE, AROMATIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:STORAGE AT ELEVATED TEMPERATURES.
Hazardous Decomposition Products:ON BURNING, EMITS ACRID FUMES, CO2,
AND CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE, AND
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: EASY-FLO 45
Cage: 6A753
=======================================================
Contractor Summary
=======================================================
Cage: 6A753
=======================================================
Ingredients
=======================================================
ORGANS & BRAIN. CADMIUM HAS ALSO CAUSED
-----------------------------
-----------------------------
MUSCULOSKELETAL SYSTEM.
-----------------------------
-----------------------------
CUTTING" (AMERICAN WELDING SOCIETY, MIAMI, FL 33135).
-----------------------------
-----------------------------
(SHADE #3 OR #4) ARE RECOMMENDED.
-----------------------------
-----------------------------
Cas: 7440-43-9
RTECS #: EU9800000
% Wt: 5-24
OSHA PEL: 0.05 MG/M3 DUST&FUME
ACGIH TLV: 0.05 MG/M3 DUST
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 7440-50-8
RTECS #: GL5325000
% Wt: 15-45
OSHA PEL: 0.1MG/M3 FUME;1 DUST
ACGIH TLV: 0.2MG/M3 FUME;1 DUST
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 7440-22-4
RTECS #: VW3500000
% Wt: 20-50
OSHA PEL: 0.01 MG/M3
ACGIH TLV: 0.1 MG/M3
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 7440-66-6
RTECS #: ZG8600000
% Wt: 16-30
OSHA PEL: 10 MG/M3 (ZNO)
ACGIH TLV: 10 MG/M3 (ZNO)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
SYMPS:METALLIC TASTE, DRY THROAT, COUGH,
-----------------------------
FATG. CHRONIC EXPOS TO ZINC METAL HAS NOT
-----------------------------
MATL IN SOLID FORMS IS NOT KNOWN TO BE
-----------------------------
LOCALIZED ARGYRIA (FROM SILVER), &/OR
-----------------------------
IN FINELY-DIVIDED FORM MAY PRDCE LOCALIZED
-----------------------------
THIS MATL IN FINELY-DIVIDED FROM MAY PRDCE
-----------------------------
CHRONIC INGEST MAY PRDCE DMG TO LIVER,
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: INHAL:ING 1:ACUTE EXPOS TO CADMIUM OXIDE FUME MAY PRDCE
PNEUM, TRACHEOBRONCH & PULM EDEMA. CHRONIC EXPOS TO CADMIUM (DUST/FUME)
MAY PRDCE GI SYMPS, ANEMIA, EOSINOPHILIA, RHINITIS, DISCOLORATION OF TEE TH,
MICROFRACTURES, KIDNEY DISEASE & CANCER. ING 2: ACUTE EXPOS MAY CAUSE
RESP TRACT IRRIT, FEVER, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CADMIUM:IARC MONOGRAPHS, SUPP, VOL 7, PG 139,
1987:GRP 2A. NTP 6TH ANNUAL RPT ON CARCINS, 1991:ANTIC TO BE (SUPP DATA)
Signs And Symptions Of Overexposure: HLTH HAZ:MUSCLE ACHE, CHILLS, COUGH, WEAK
& METALLIC TASTE. CHRONIC EXPOS MAY CAUSE DMG TO LIVER, KIDNEY, SPLEEN,
PANCREAS & BRAIN. ING 3:CHRONIC EXPOS MAY PRDCE ARGYRIA, PERM BLUE-GRAY
DISCOLORATION OF SKIN, EYES, MUC MEMBS & RESP TRACT. ING 4:ACUTE EXPOS
OF ZINC OXIDE FUME MAY CAUSE RESP TRACT IRRIT & "METAL
Medical Cond Aggravated By Exposure: PRE-EXISTING PULM DISEASES (E.G., BRONCH,
EMPHYSEMA) MAY BE AGGRAVATED BY INHAL EXPOS TO THIS MATL, PARTICULARLY AS
FUME. ADDNLY, EXPOS TO CADMIUM BY INHAL &/OR INGEST MAY AGGRAVATE PRE-
First Aid: INHAL:REMOVE SUBJECT FROM CONTAM AREA, ADMIN OXYGEN & SEEK MED
ATTN. KEEP SUBJECT WARM & AT REST. PERFORM ARTF RESP IF BRTHG HAS
STOPPED. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED AREA W/LG QTYS OF WATE R FOR
AT LST 5 MINS. SEEK MED ATTN IF NEC. EYES:FLUSH AFFECTED AREAS W/WATER FOR AT
LST 15 MINS. SEEK MED ASSISTANCE IF NEC. INGEST:IF SUBJECT IS CONSCIOUS,
INDUCE VOMIT. IF UNCON/CONVULSIVE,
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: CLEAN UP SPILLED MATERIAL SO AS TO MINIMIZE
DISPERSION OF DUST. WET SWEEPING OR VACUUMING USING HEPA FILTRATION ARE
RECOMMENDED METHODS. RQ:ING 1:1 LB. ING 2:5000 LBS. ING 3:1000 LBS. ING 4:
1000 LBS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS (FP N). RETURN TO MANUFACTURER FOR RECLAIM.
Handling And Storage Precautions: DO NOT STORE AT HIGHLY-ELEVATED TEMPS/IN
PROXIMITY TO INCOMPAT MATLS. DANGER. CONTAINS CADMIUM. CANCER HAZ. AVOID
CREATING DUST.
Other Precautions: CAN CAUSE LUNG & KIDNEY DISEASE. BRAZING ALLOYS MAY BE
USED W/SEPARATELY-APPLIED FLUX WHICH, WHEN HEATED, MAY EMIT IRRIT &/OR
TOX GASES & FUMES. CONSULT MSDS FOR SPECIFIC FLUX IN USE TO DETERM ITS
HAZ S & APPROP PROT MEASURES. FOR
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: USE DRY POWDER. DO NOT USE WATER.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: IN FINELY-DIVIDED FORM, THIS MATL MAY IGNITE
WHEN EXPOS TO FLAME/BY RXN W/INCOMPATL MATLS. FIRES/EXPLOS INVOLVING THIS
MATL MAY RELS POTNTLY TOXIC (SUPP DATA)
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF EXPOSURE LEVELS EXCEED OSHA PEL(S), WEAR NIOSH/ MSHA
APPROVED RESPIRATOR HAVING PROTECTION FACTOR APPROPRIATE TO AIRBORNE
CONCENTRATIONS OF CONTAMINANTS GENERATED.
Ventilation: USE MECH LOC EXHST VENT ADEQ TO MAINTAIN AIRBORNE CONCS OF ALL
COMPONENTS & THEIR DECOMP PRODS TO W/IN THEIR
Other Protective Equipment: WEAR APPROP PROT CLTHG TO PVNT SKIN INJURIES FROM
HAZS OF BRAZING &/OR FOR PRLNG/RPTD CONT W/FINELY-DIVIDED
Work Hygienic Practices: TO AVOID INGESTION OF MATERIAL, WASH HANDS & FACE
BEFORE EATING, DRINKING OR CONSUMPTION OF TOBACCO.
Supplemental Safety and Health: EXPLO HAZ:EMISSIONS OF METAL/METAL OXIDE FUMES
OF INGS. MATLS TO AVOID:PEROXIDES, PEROXYFORMIC ACID, CHLORINE &
FLUORINE, PERMONOSULFURIC ACID, CHLORATES, CRO3, MN & CA CHLORIDES, CS2,
HYDRAZINE MONON ITRATE, NITROBENZENE, FE(CO)5, SELENINYL BROMIDE. EXPLAN OF
CARCIN:CARCIN. HUMAN:LUNG, PROSTATE, RENAL SYSTEM EFTS.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: N1
M.P/F.P Text: >1110F,>599
Spec Gravity: 8.79-9.53
Solubility in Water: INSOLUBLE
Appearance and Odor: LIGHT YELLOW METAL IN FORM OF WIRE, ROD, STRIP, PWDR/
PREFORMED SHAPES(ODORLESS
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZERS, SE, TE, MG, ACETYLENE, NH3, HNO3, AZIDES,
ETHANOL, ETHYLENE IMINE, CF3, INORG & ORGANIC (SUPP DATA)
Hazardous Decomposition Products: HEATING AT BRAZING TEMPERATURES MAY LIBERATE
OXIDES OF METALS IN INGREDIENTS SECTION, AS FUME.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: EASY-FLO 45
Cage: 6A753
Company Name: HANDY & HARMAN
Street: 1770 KINGS HIGHWAY
Zipcode: 06430-5317
Label Required IND: Y
Date Of Label Review: 11/24/1993
Status Code: C
Label Date: 11/24/1993
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: AVOID CREATING DUST. DO NOT STORE AT HIGHLY ELEVATED
TEMPS/IN PROXIMITY TO INCOMPATIBLE MATERIALS. ACUTE:INHALATION:MAY CAUSE
RESPIRATORY TRACT IRRITATION, METAL FUME FEVER, PNEUMONITIS & PULMONARY
ED EMA. SKIN:FINELY DIVIDED PARTICLES MAY PRODUCE LOCALIZED IRRITATION,
ARGYRIA, DISCOLORATION & DERMATITIS. EYE:MAY PRODUCE ARGYRIA, IRRITATION,
CONJUNCTIVITIS & ULCERATION OF CORNEA. INGEST:GASTRIC IRR ITATION,
VOMITING, ABDOMINAL PAIN, HEMORRHAGE, DIARRHEA. CHRONIC:CANCER
HAZARD.CONTAINS CADMIUM WHICH IS LISTED AS A HUMAN LUNG, PROSTATE & RENAL
SYSTEM CARCINOGEN (FP N). CAN CAUSE LUNG & KIDNEY DISE ASE. MAY DAMAGE
LIVER, SPLEEN, PANCREAS & BRAIN.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DIMETHYL GLYOXIME
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:2,3-BUTANEDIONE DIOXIME
CAS:95-45-4
RTECS #:EK2975000
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LDLO=250MG/KG ORAL-RAT
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TOXIC AND MAY BE IRRITATING TO
EYES/SKIN/MUCOUS MEMBRANES. INGEST:LOW DOSES WERE REQUIRED TO KILL
SOME OF RATS TESTED. HOWEVER SYSTEMIC AFFECTS WERE NOT REPORTED.
Explanation of Carcinogenicity:PER MSDS:CARCINOGEN STATUS:NONE.
Effects of Overexposure:IRRITATING TO EYES, SKIN, MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MFG.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPO TO FRESH AIR IMMED.IF STOP BREATH
PERFORM ART RESP.KEEP PERSON WARM/REST.TREAT
SYMPT/SUPORT.SKIN:REMOVE CONTAMIN CLOTH/SHOES IMMED.WASH
W/SOAP/MILD DETERGENT/LG AMTS OF WATER 15 -20MINS.EYE:WASH IMMED
W/LG AMTS OF WATER/NORMAL SALINE OPENING EYELIDS
15-20MINS.INGEST:TREAT SYMPT/SUPPORT.IN ALL CASES GET MED
ATTN.GASTRIC LAVAGE PERFORMED BY QUAL MED PERS IF ADVISED TO
(SUPPLEM)
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER SPRAY OR
STANDARD FOAM. LG FIRES:USE WATER SPRAY, FOG OR STANDARD FOAM.
Fire Fighting Procedures:NO ACUTE HAZARD. MOVE CONTAINER FROM FIRE AREA
IF POSSBILE. AVOID BREATHING VAPROS/DUSTS. KEEP UPWIND.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP AND PLACE IN SUITABLE CLEAN, DRY
CONTAINERS FOR RECLAMATION OR LATER DISPOSAL. DO NOT FLUSH W/WATER.
KEEP UNNECESSARY PEOPLE AWAY.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MFG.
Other Precautions:NONE SPECIFIED BY MFG.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESP RECOMMENDED BASED ON INFO FOUND IN PHYSICAL
DATA/TOXICITY & HEALTH EFFECTS.SELECTED BASED ON CONTAMIN LEVELS IN
WORKPLACE,MUST NOT EXCEED WORKING LIMITS OF RESP,APPPROVED BY
NISOH/MSHA.
Ventilation:PROVIDE LOCAL EXHAUST OR PROCESS ENCLOSURE VENTILATION
SYSTEM.
Other Protective Equipment:IMPERVIOUS CLOTHING/EQMPT TO PREVENT
REPEAT/PROLONG SKIN CONTACT.EMERGENCY EYEWASH IMMED WORK AREA FOR
EMERGENCY USE.
Work Hygienic Practices:WASH HANDS AFTER HANDLING.LAUNDER CONTAMIN
CLOTH PRIOR TO REUSE.
Supplemental Safety and Health
1STAID:DO SO IF THERE'RE NO SIGNS OF PERFORATION.NO SPECIFIC
ANTIDOTE.TREAT SYMPT/SUPPORT.
================== Physical/Chemical Properties ==================
HCC:T6
Boiling Pt:B.P. Text:275F,135C
Melt/Freeze Pt:M.P/F.P Text:453F,234C
Solubility in Water:NEGLIGIBLE (0.06%)
Appearance and Odor:ODORLESS WHITE CRYSTALS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NO DATA AVAILABLE.
Stability Condition to Avoid:NONE REPORTED.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:NONE SPECIFIED BY MFG. HOWEVER DISPOSE OF IN
ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:WINTERIZER FLOATERS
Preparer's Name:JANE R BROWN
CAGE:54760
CAGE:54760
============= Composition/Information on Ingredients =============
Ingred Name:TRICHLORO-S-TRIAZINETRIONE
CAS:87-90-1
RTECS #:XZ1925000
Fraction by Wt: 99%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/INHALATION: IRRITATION
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/LARGE VOLUMES OF WATER FOR AT LEAST 15 MINS.
SKIN: BRUSH OFF EXCESS MATERIAL & FLUSH W/WATER FOR AT LEAST 15
MINS. INGESTION: DRINK LARGE QUANTITIES OF WATER. DON'T INDUCE
VOMITING. INHAL ATION: AVOID BREATHING DUST. REMOVE TO FRESH AIR.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER
Fire Fighting Procedures:ISOLATE CONTAINER IN OPEN AIR, IF POSSIBLE.
DELUGE W/WATER. USE NIOSH/MSHA APPROVED SELF-COTAINED BREATHING
APPARATUS.
Unusual Fire/Explosion Hazard:CONTACT W/MOST ORGANIC MATERIALS MAY
RESULT IN FIRE. MAY BE EXPLOSIVE, W/THE EVOLUTION OF TOXIC GASES.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. PICK UP &
PLACE IN CLEAN DRY PLASTIC OR PLASTIC-LINED CONTAINERS. ISOLATE
CONTAINERS IN OPEN, WELL-VENTILATED AREA. FLUSH SMALL RESIDUES INTO
SEWER W/LARGE QUANTITIES O F WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
AREA AWAY FROM ANY OTHER CHEMICALS. ALWAYS OPEN CONTAINERS IN A
WELL-VENTILATED AREA.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID BREATHING DUST.
KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARARTUS. ENGINEERING OR ADMINISTRATIVE CONTROLS SHOULD BE
IMPLEMENTED TO REDUCE EXPOSURE.
Ventilation:ADEQUATE MECHANICAL (GENERAL/OR LOCAL EXHAUST) TO MAINTAIN
EXPOSURE BELOW TLV'S.
Other Protective Equipment:RUBBER OR VINYL APRON
Work Hygienic Practices:REMOVE & WASH CONTAMINATED CLOTHES BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:MODERATE
Appearance and Odor:WHITE STICKS; CHLORINE ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SOLVENTS, ORGANIC MATTER, INORGANIC REDUCING AGENTS, AMMONIA, NITROGEN
BEARING COMPOUNDS.
Stability Condition to Avoid:HIGH TEMPERATURES, CONTAMINATION,
MOISTURE, HIGH HUMIDITY, POOR VENTILATION
Hazardous Decomposition Products:NITROGEN TRICHLORIDE, CO, PHOSGENE
(400F) & OTHER CHLORINE GASES.
==================== Disposal Considerations ====================
Waste Disposal Methods:LARGE AMOUNTS SHOULD BE TRANSPORTED TO A
PERMITTED HAZARDOUS WASTE FACILITY FOR PROPER DISPOSAL. FOLLOW ALL
FEDERAL, STATE & LOCAL HAZARDOUS WASTE REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CS3204 PART B
Kit Part:Y
CAGE:14439
CAGE:14439
============= Composition/Information on Ingredients =============
Ingred Name:MANGANESE DIOXIDE (DUST) *
CAS:1313-13-9
RTECS #:OP0350000
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:*MANGANESE DIOXIDE-DUST-EXPO. LIMITS IS BASED ON DUST
PRTCLSPRTCLS ARE WETTED OUT-NO AIRBORNE PRTCLS FROM NORMAL USE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IMPAIRMENT OF CENTRAL NERVOUS SYSTEM
Effects of Overexposure:SLUGGISHNESS, SLEEPLESSNESS AND/OR WEAKNESS IN
THE LEGS.
Medical Cond Aggravated by Exposure:NONE KNOWN
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH LARGE AMOUNTS OF WATER, CONTACT A PHYSICIAN.
SKIN: WASH WITH SOAP AND WATER.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL, CO2, FOAM, WATER
Fire Fighting Procedures:IN CONFINED AREAS WEAR SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:EXPLOSION HAZARD IF HEATED WITH
OXIDIZABLE MATERIALS.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP AND TRANSFER TO SAFETY CONTAINER,
WASH SURFACE WITH SOAP AND WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY AREA.
Other Precautions:WASH HANDS BEFORE EATING, DRINKING, OR SMOKING AFTER
HANDLING THIS PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NEEDED
Ventilation:NA
Other Protective Equipment:APPROPRIATE TO PREVENT PROLONGED CONTACT
WITH SKIN.
Work Hygienic Practices:TRAIN PERSONNEL IN SAFE HANDLING OF THIS
PRODUCT
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:2.0
Evaporation Rate & Reference:NIL
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK PASTE, OILY ODOR, LIQUID AT ROOM TEMPERATURE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REDUCING AGENTS AND COMBUSTIBLES, H2S, POTASSIUM AZIDE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CO2, CO, NO, NO2, DUST
==================== Disposal Considerations ====================
Waste Disposal Methods:REACT WITH BASE COMPONENT AND DISPOSE AS SOLID
WASTE ACCORDING TO FEDERAL, STATE, AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:6481 VACUTAINER W/HEPARIN
Preparer's Name:FU-CHUNG LIN
CAGE:06531
CAGE:06531
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM HEPARIN
CAS:9041-08-1
RTECS #:MI0850000
Fraction by Wt: 100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYE/INHALATION: IRRITATION.
INGESTION: GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA,
NOSEBLEEDS, BLOOD IN URINE, OR TARRY STOOLS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN/EYE/INHALATION: IRRITATION. INGESTION:
GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA,
NOSEBLEEDS, BLOOD IN URINE, & TARRY STOOLS.
Medical Cond Aggravated by Exposure:HYPERTENSION, CONDITIONS ASSOCIATED
W/INCREASED BLEEDING TENDENCIES, MENSTRUATION, LIVER DISEASE
W/IMPAIRED HEMOSTASIS.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: WASH W/LARGE AMOUNTS OF WATER. INHALATION: REMOVE
TO FRESH AIR. INGESTION: GIVE 2 GLASSES OF WATER. INDUCE VOMITING.
OBTAIN MEDICAL ATTENTION IN ALL CASES. NOTE TO PHYSICIAN:
SUBCUTANEOUS I NJECTION; NEUTRALIZE HEPARIN EFFECT.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH W/WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE & HANDLE ACCORDINGLY.
Other Precautions:BECAUSE HEPARIN IS A MIXTURE OF ACTIVE PRINCIPLES
HAVING THE PROPERTY OF PROLONGING CLOTTING TIME OF BLOOD, IT IS
NECESSARY TO PREVENT INHALATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED UNDER NORMAL & INTENDED USES.
Ventilation:GENERAL ROOM
Other Protective Equipment:EMERGENCY EYE BATH
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:COMPLETE
Appearance and Odor:WHITE POWDER W/NO CHARACTERISTIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. NORMALLY SMALL VOLUMES CAN BE DISPOSED INTO A
SEWER SYSTEM.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SP-4G SODIUM PERSULFATE ETCHANT
Preparer's Name:CRIS WILLIAMS
CAGE:52519
CAGE:2P655
CAGE:52519
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM PERSULFATE
CAS:7775-27-1
RTECS #:SE0525000
Fraction by Wt: 100%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 895 MG/KG
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY BE HARMFUL IF INGESTED. MAY
IRRITATE SKIN AND EYES ON CONTACT. MAY IRRITATE RESPIRATORY SYSTEM
IF INHALED. CHRONIC: ALLERGIC PERSONS MAY DEVELOP DERMATITIS OR
ASTHMA.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:INHALED: WHEEZING, COUGHING, SNEEZING,
SHORTNESS OF BREATH. EYES: REDNESS, TEARING, BLURRED VISION,
DISCOMFORT OR ITCHING. SKIN: REDNESS, ITCHING, DISCOMFORT.
INGESTED: NAUSEA, VOMITING, DIARRHEA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALED: REMOVE PERSON TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION IF NOT BREATHING; GIVE OXYGEN IF BREATHING DIFFICULT.
SKIN: WASH WITH SOAP AND WATER. EYES: FLUSH WITH LOTS OF WATER. SEE
DOCTOR. INGES TED: IF CONSCIOUS, GIVE 1-2 GLASSES OF WATER AND CALL
DOCTOR. IF ANT SYMPTOMS PERSIST; CALL A DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:WATER OR WATER FOG
Fire Fighting Procedures:CONSIDER AS AN OXIDIZER WITH ACID MIST. WEAR
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:OXYGEN RELEASED BY HEAT OF FIRE MAY
INTENSIFY FIRE IN COMBUSTIBLE SURROUNDINGS.
================== Accidental Release Measures ==================
Spill Release Procedures:MATERIAL SHOULD BE PUT INTO APPROVED DOT
CONTAINER AND DILUTED WITH LARGE QUANTITY OF WATER. WEAR PROPER
PROTECTIVE CLOTHING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A TIGHTLY CLOSED CONTAINER IN
A COOL, DRY PLACE AWAY FROM POINT HEAT SOURCES AND INCOMPATIBLE
MATERIALS.
Other Precautions:FOR STORAGE REQUIREMENTS; REFER TO NFPA BULLETIN 43 A
ON THE STORAGE OF LIQUID AND SOLID OXIDIZING MATERIALS. AVOID
CONTAMINATION OF OPENED PRODUCT, KEEP CLOSED WHEN NOT IN USE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHEN EXPOSURE ABOVE THE ESTABLISHED STANDARD IS
LIKELY, RESPIRATORY PROGRAM IN ACORDANCE WITH OSHA GENERAL INDUSTRY
STANDARD 1910.134 AND RESPIRATORY EQUIPMENT SUCH AS A NIOSH/MSHA
APPROVED RESPIRATOR FOR DUST MUST BE IMPLEMENTED.
Ventilation:USE ONLY IN WELL VENTILATED AREAS. LOCAL OR GENERAL
MECHANICAL TO CONTROL DUST TO OSHA STANDARD.
Other Protective Equipment:FULL COVER CLOTHING
Work Hygienic Practices:WASH HANDS AFTER USE AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
CONTAINER SIZE:8 LB BAG. PART A OF A 2 PART KIT. KEY1=D2. MSDS WRIITEN
BY KEPRO FROM INFORMATION PROVIDED BY FMC CORP, PHILADELPHIA, PA.
================== Physical/Chemical Properties ==================
HCC:D1
Melt/Freeze Pt:M.P/F.P Text:DECOMPOSES
Vapor Pres:NONE
Spec Gravity:2.6
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE CRYSTALS, NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
EASILY OXIDIZABLE MATERIALS, COMBUSTIBLE MATERIAL, ACIDS, STRONG
ALKALIS
Stability Condition to Avoid:DECOMPOSES WITH EXOTHERMIC REACTION.
MOISTURE, HEAT AND CONTACT WITH REDUCING AGENTS.
Hazardous Decomposition Products:OXYGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE IN WATER AND DISPOSE VIA A TREATMENT
SYSTEM IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.
BECAUSE LOCAL AND STATE REQUIREMENTS DIFFER; CONSULT WITH LOCAL AND
STATE OFFICIALS BEFORE DISPOSING.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ZIRCONIUM HYDRIDE
CAGE:FO994
CAGE:FO994
CAGE:67027
============= Composition/Information on Ingredients =============
Ingred Name:ZIRCONIUM HYDRIDE; (ZRH*2)
CAS:7704-99-6
RTECS #:ZH8015000
Fraction by Wt: 100%
OSHA PEL:5 MG ZR/M3
ACGIH TLV:5 MG ZR/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: RESPIRATORY
IRRITANT. REACTION OF ZRH*2 AND WARM MUCOUS MEMBRANES MAY PRODUCE
H*2 AND CAUSTIC ZR(OH)*4. ZIRCONIUM AND COMPOUNDS HAVE BEEN FOUND
TO CAUSE PULMONARY GRANULOMAS. SKIN: IRRITATING TO MOIST SKIN,
POSSIBLY CAUSTIC. ALLERGIC DERMATITIS MAY OCCUR. EYES: IRRITATING,
POSSIBLY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CORROSIVE. INGESTION MAY CAUSE
DISCOMFORT DUE TO REACTION OF ZRH*2 WITH STOMACH ACID TO LIBERATE
HYDROGEN GAS AND HEAT. ZIRCONIUM IS CONSIDERED OF LOW TOXICITY.
CHRONIC: NONE SPECIFIED BY MA NUFACTURER.
Medical Cond Aggravated by Exposure:PREVIOUS RESPIRATORY AND SKIN
DISORDERS.
======================= First Aid Measures =======================
First Aid:INGESTION: ADMINISTER WATER AND DO NOT INDUCE VOMITING. SEEK
MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. SEEK MEDICAL
ATTENTION. SKIN: WASH AFFECTED AREA WITH SOAP AND WATER. SEEK
MEDICAL ATTE NTION IF SYMPTOMS PERSIST. EYES: FLUSH FOR AT LEAST 15
MINUTES WITH LUKEWARM WATER. SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FLAMMABLE WHEN WET. CAN EXPLODE WHEN DRY.
HYDROGEN GAS EVOLVED ON DECOMPOSITION. HOT WATER/STEAM MAY REACT
WITH ZRH*2 TO EVOLVE FLAMMABLE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
ENSURE AREA WHERE SPILL OCCURRED IS PROT FROM EXPOS TO
MOISTURE/WATER & ISOLATED & WELL VENT. VACUUM UP SPILL USING HIGH
EFFICIENCY UNIT & PLACE IN CONTR FOR PROPER DISP. TAKE CARE NOT TO
RAISE DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS
AWAY FROM HEAT, FLAMES, OXIDANTS, ACIDS, AND STEAM.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED DUST-MIST RESPIRATOR.
Ventilation:LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV FOR ZR. HANDLE
IN INERT ATMOSPHERE. MECHANICAL (GENERAL) NOT RECOMMENDED.
Other Protective Equipment:WEAR PROT APPAREL TO PVNT SKIN & CLTHG
CONTAM. EMER EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AND FACE THOROUGHLY AFTER HANDLING
AND BEFORE EATING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:SUP DAT
Spec Gravity:5.6
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY-BLACK METALLIC POWDER, NO ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
OXIDANTS, ACIDS, STEAM, WATER (FIRE HAZARD).
Stability Condition to Avoid:ON CONTACT WITH WATER.
Hazardous Decomposition Products:H*2.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE TO APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CARBOLINE 3358
CAGE:06634
CAGE:06634
============= Composition/Information on Ingredients =============
Ingred Name:PROPANOL, ALLYLOXY-; (PROPYLENE GLYCOL)
CAS:1331-17-5
RTECS #:UA4900000
Fraction by Wt: 5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC COMPOUNDS (MIXED PRODUCT THINNED TO
MAXIMUM LEVEL): 1.3 LBS/GAL, 159 G/L
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:COLOR BLEND; (COLOR PIGMENT: MAY CONTAIN INGS 2-4 AND OTHER
PARTICULATES NOT OTHERWISE REGULATED)
Fraction by Wt: <10%
OSHA PEL:N/K
ACGIH TLV:3.5 MG/M3 (MFR)
Ingred Name:IRON (III) OXIDE; (IRON OXIDES)
CAS:1309-37-1
RTECS #:NO7400000
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3 (FE)
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:10 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:CALCIUM CARBONATE
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: <10%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:PHTHALIC ACID, DIBUTYL ESTER; (DIBUTYL PHTHALATE) (SARA
III)
CAS:84-74-2
RTECS #:TI0875000
Fraction by Wt: <5%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-; (GLYCOL ETHER SOLVENT)
CAS:112-34-5
RTECS #:KJ9100000
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 50%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ACRYLIC RESIN
Fraction by Wt: 25%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PHOSPHORIC ACID, ZINC SALT; (ZINC PHOSPHATE)
CAS:7779-90-0
RTECS #:TD0600900
Fraction by Wt: 15%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION:HARMFUL, MAY AFFECT
BRAIN/ NERVOUS SYSTEM, CAUSING DIZZINESS, HEADACHE/NAUSEA. MAY
CAUSE NOSE & THROAT IRRITATION. EYES:MAY CAUSE IRRITATION. SKIN:MAY
CAUSE IRRITATION. CHRONIC: REPO RTS HAVE ASSOCIATED REPEATED &
PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS W/PERMANENT BRAIN &
NERVOUS SYSTEM DAMAGE
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:THOSE WITH CONDITIONS THAT COULD BE
AGGRAVATED BY EXPOSURE TO DUST OR ORGANIC VAPORS SHOULD SEE A
PHYSICIAN PRIOR TO USE.
======================= First Aid Measures =======================
First Aid:WHEN EXPOSED, ALWAYS GET MEDICAL ATTENTION. EYES: FLUSH WITH
WATER FOR AT LEAST 15 MINUTES. SKIN: WASH WITH SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & CLEAN BEFORE REUSE. INHALATION: REMOVE TO
FRESH AIR. PROVIDE OXYGEN IF BREATHING IS DIFFICULT. USE
ARTIFICIAL RESPIRATION IF NOT BREATHING. GET MEDICAL ATTENTION.
INGESTION: DO NOT INDUCE VOMITING! ALWAYS GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:248F,120C
Lower Limits:1000%
Upper Limits:1%
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . EVACUATE HAZ AREA OF UNPROTECTED PERS. COOL
SURROUNDING CNTRS W/WATER IN CASE OF FIRE EXPOS.
Unusual Fire/Explosion Hazard:WATER BASED PROD HOWEVER IT DOES CNTN SM
AMT OF VOLAT ORG CMPDS. VAP ARE HVR/AIR & WILL ACCUM. VAP WILL FORM
EXPLO CONC W/AIR. VAP TRAVEL LONG DIST & (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:ELIM ALL IGNIT SOURCES. HNDLG EQUIP MUST BE
GROUNDED TO PVNT SPK. EVACUATE AREA OF UNPROT PERS. WEAR APPROP
PROT CLTHG & EQUIP. FOLLOW SAFE HNDLG & USE GUIDELINES. CONTAIN &
SOAK UP RESIDUAL W/ ABSORB(CLAY/SAND). TAKE UP ABSORB MATL & SEAL
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPK, OPEN FLAME &
STRONG OXIDIZING AGENTS. KEEP CNTNRS CLSD. STORE IN COOL, DRY PLACE
W/ADEQ VENT.
Other Precautions:IF POURING OR TRANSFERRING MATERIALS GROUND ALL
CONTAINERS & TOOLS. DO NOT WELD, HEAT, CUT OR DRILL ON FULL OR
EMPTY CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ONLY W/VENT TO KEEP LEVELS < EXPOS
GUIDELINES. USER SHOULD TEST & MONITOR EXPOS LEVELS TO INSURE ALL
PERS BELOW GUIDELINES. IF NOT SURE/IF NOT ABLE TO MONITOR USE
NIOSH/MSHA APPROVED AIR- PURIFYIN G RESPIRATOR.
Ventilation:USE EXPLOSION-PROOF VENT WHEN REQUIRED TO KEEP BELOW HLTH
EXPOSURE GUIDELINES & LEL.
Other Protective Equipment:IMPERVIOUS CLOTHING. IF MATERIAL PENETRATES
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING,
DRINKING/USING TOILET FACILITIES. USE OF HAND CLEANER RECOM.
LAUNDER CONTAMD (SUPDAT)
Supplemental Safety and Health
EXPLO HAZ:WILL FLASHBACK. HAZ DECOMP PROD: WELDING, CUTTING/ABRASIVE
GRINDING CAN CREATE SMOKE & FUMES. DO NOT BREATHE. SPILL
PROC:TIGHTLY FOR PROPER DISP. HYGIENE PRACT:CLTHG BEFORE REUSE.
LEATHER SH OES CAN ABSORB & PASS THROUGH HAZ MATLS. CHECK SHOES
CAREFULLY AFTER SOAKING BEFORE REUSE.
================== Physical/Chemical Properties ==================
HCC:T6
Boiling Pt:B.P. Text:441F,227C
Vapor Density:HVR/AIR
Spec Gravity:1.19
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:63
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAMES.
Hazardous Decomposition Products:CO, NITROGEN OXIDES & UNIDENTIFIED ORG
CMPDS. CONSIDER ALL SMOKE & FUMES FROM BURNING MATL AS VERY HAZ.
(SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SODIUM BISULFITE ANHY TECH 100#
CAGE:5A188
CAGE:5A188
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM BISULFITE (SASA III)
CAS:7631-90-5
RTECS #:VZ2000000
Fraction by Wt: >95%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:EYE,SKIN,NASAL,RESPIRATORY PASSAGE
IRRITNT.INGESTION:GI IRRITNT,NAUSEA,VOMITING,DIARRHEA.
======================= First Aid Measures =======================
First Aid:SKIN:WASH W.SOAP & WATER.EYES:FLUSH W/WATER.INGEST:GIVE 2
GLASSES OF WATER INDUCE VOMITNG.INHAL:MOVE TO FRESH AIR.GIVE
CPR/OXYGEN IF NEEDED.KEEP PERSON WARM/QUIET AND CALL DR.
===================== Fire Fighting Measures =====================
Upper Limits:UNAV
Extinguishing Media:WATER FOG,CO*2
Fire Fighting Procedures:SELF-CNTND BRTHG APP. W.FULL-FACEPIECE OPRATD
POST.PR.MODE.
Unusual Fire/Explosion Hazard:N/A.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILL:COVER W.SODA ASH.MIX AND SCOOP
INTO A BEAKER OF WATER.LARGE SPILL:COLLECT AND ADD SLOWLY TO A
LARGE VOLUME OF WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS HAZARDOUS WHEN EMPTIED
(RETAIN PRODUCT RESIDUES).ALL HAZARD PRECAUTIONS MUST BE OBSERVED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA JOINTLY APPROVED DUST RESPIRATOR.
Ventilation:MECHANICAL(GEN/LOCAL EXHAUST) TO MAINTAIN EXPOSURE BELOW
TLV
Other Protective Equipment:TO PREVENT SKIN CONTACT:IMPERVIOUS
CLOHES/BOOTS ON ARMS,LEGS
Supplemental Safety and Health
SEC VII:WASTE DISPOSAL:DEPOSIT SLUDGE ON LANDFILL.
================== Physical/Chemical Properties ==================
HCC:C3
Spec Gravity:1.48
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE CRYSTALS,SLIGHT SULFUROUS ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID STRONG MINERAL ACIDS & OXIDIZERS
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS:SULFUR
COMPOUNDS,ETC.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOVLE IN LG AMT WATER,ADD SODA ASH>NEUTRALIZE
W.6M-HCL.FLUSH DOWN DRAIN W.EXCESS WATER.LG SPILL:COLLECT,ADD TO LG
CONT.WATER.STIR IN SLIGHT EXCESS SODA ASH.LET STAND 24 HR.DECANT TO
ANOTHER CONT.NE UTRALIZE W.6M-HCL.FLUSH DOWN DRAIN(SEE SUPPL DATA)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RC 5097 (781016) RESIN
CAGE:DO229
CAGE:18873
CAGE:DO229
============= Composition/Information on Ingredients =============
Ingred Name:AROMATIC PETROLEUM DISTILLATE
Fraction by Wt: 18%
ACGIH TLV:100 PPM-MFR
Ingred Name:METHYL PYRROLIDONE
CAS:872-50-4
RTECS #:UY5790000
Fraction by Wt: 71%
ACGIH TLV:25 PPM-MFR
===================== Hazards Identification =====================
Effects of Overexposure:HEADACHE,NAUSEA,IMPAIRMENT OF REACTION TIME &
COORDINATION.
======================= First Aid Measures =======================
First Aid:INHALATION-MOVE TO FRESH AIR.SKIN-WASH WITH SOAP/WATER.REMOVE
CONTAMINATED CLOTHES.EYES-FLUSH WITH WATER FOR AT LEAST 15 MIN.CALL
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:100-140 F CC
Lower Limits:1.1
Upper Limits:7.0
Extinguishing Media:CO*2, FOAM, DRY CHEM.
Fire Fighting Procedures:WATER FOG TO COOL EXP CONT TO PREVENT PRESSURE
BUILD UP
Unusual Fire/Explosion Hazard:MFR SAYS NONE APPLICABLE.RECOMMEND USING
SELF CONTAINED BREATHING GEAR.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID PROLONGED SKIN CONTACT & BREATHING OF
VAPOR.REMOVE IGNITION SOURCES.REMOVE WITH INERT SOLVENT,VENTILATE
AREA.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM HEAT,SPARKS,OPEN FLAME.CLOSE
CONTAINER AFTER EACH USE.DO NOT STORE ABOVE 120F
Other Precautions:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING OR
SMOKING.OBSERVE LABEL PRECAUTIONS.CONTAINERS SHOULD BE GROUNDED
WHEN POURING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MESA RESPIRATOR TC-23C IF AIR CONTAMINANT
CONTROL NOT FEASIBLE
Ventilation:LOCAL TO KEEP BELOW TLV/LEL.REMOVE IGNITION SOURCES.
Other Protective Equipment:AS APPROPRIATE FOR GOOD INDUSTRIAL HYGIENE
PRACTICES.
Supplemental Safety and Health
MSDS DATE-2/25/82.VAP PRESS & VAP DENSITY ARE FOR PRINCIPAL SOLVENT.
BOILING POINT RANGE:150-205C.FLASH POINT RANGE:37-60C.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:302-401 F
Vapor Pres:452
Vapor Density:3.4
Spec Gravity:1.016
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SEMI-VISCOUS LIQUID WITH CHARACTERISTIC ODOR
Percent Volatiles by Volume:91.1
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MFR SAYS NONE RECOMMEND KEEP FROM OXIDIZERS.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE, SMOKE
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:74-6435, LYOPHILIZED CATALASE FOR 125 ML
Kit Part:Y
Resp. Party Other MSDS Num.:ENZYME CATALYSIS REPL SET /PT #74-6435
CAGE:59896
Contract Num:MDA414-00-P-4948
CAGE:59896
Contract Num:MDA414-01-P-2038
CAGE:59896
============= Composition/Information on Ingredients =============
Ingred Name:CATALASE (FROM BOVINE LIVER)
CAS:9001-05-2
RTECS #:FI4378000
= Wt:100.
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: N/P. POTENTIAL HEALTH
EFFECTS: EYES-MAY CAUSE IRRITATION. SKIN-MAY CAUSE IRRITATION.
INGESTION-MAY CAUSE GASTROINTESTINAL DISCOMFORT. INHALATION-MAY
CAUSE IRRITATION TO RESPIRATORY TRA CT.
Explanation of Carcinogenicity:NOT LISTED AS CAUSING CANVER BY IARC,
NTP OR OSHA.
Effects of Overexposure:EYES-MAY CAUSE IRRITATION. SKIN-MAY CAUSE
IRRITATION. INGESTION-MAY CAUSE GASTROINTESTINAL DISCOMFORT.
INHALATION-MAY CAUSE IRRITATION TO RESPIRATORY TRACT.
Medical Cond Aggravated by Exposure:NO DATA AVAILABLE.
======================= First Aid Measures =======================
First Aid:EYES-FLUSH WITH WATER FOR AT LEAST 15 MINS, RAISING &
LOWERING EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION
PERSISTS. SKIN-THOROUGHLY WASH EXPOSED AREA FOR AT LEAST 15 MIN.
REMOVE CONTAM INATED CLOTHES. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. GET MEDICAL AID IF IRRITATION PERSISTS. INGESTION-IF
SWALLOWED, IF CONSCIOUS, GIVE PLENTY OF WATER. IMMEDIATELY CALL A
PHYSICIAN OR POISON C ONTROL CENTER. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. INHALATION-REMOVE TO FRESH AIR. GIVE
OXYGEN IF BREATHING IS DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF
BREATHING HAS STOPPED. KEEP PERSON WARM, QUIET, & GET MEDICAL AID.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE OR APPROPRIATE
FOAM.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE
EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE EXPECTED.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF SPILL. CLEAN-UP PERONNEL
SHOULD WEAR PROPER PROTECTIVE EQUIPMENT. AVOID CREATING DUST. SWEEP
OR SCOOP UP AND CONTAINERIZE FOR DISPOSAL.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE AWAY FROM
HEAT. DO NOT GET IN EYES, ON SKIN OR CLOTHING.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NEEDED UNDER NORMAL CONDITIONS OF USE WITH
ADEQUATE VENTILATION. NIOSH APPROVED EQUIPMENT SHOULD BE WORN IF
PELS ARE EXCEEDED.
Ventilation:LOCAL EXHAUST: ACCEPTABLE. MECHANICAL (GENERAL): REQUIRED.
Other Protective Equipment:LAB COAT, EYE WASH STATION AND SAFETY
SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING, DO NOT TAKE
INTERNALLY.
Supplemental Safety and Health
THIS MSDS IS FOR ONE PART OF A KIT. THE HMIS SERIAL NUMBERS FOR ALL
PARTS OF THIS KIT (INCLUDING THE ONE FOR THIS MSDS) ARE: CLFGH,
CLFFX, CLFFH, & CLFFJ.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:NO DATA AVAILABLE
Vapor Pres:NO DATA AVAILABLE
Evaporation Rate & Reference:NO DATA AVAILABLE
Solubility in Water:NO DATA AVAILABLE
Appearance and Odor:SOLID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NO DATA AVAILABLE.
Stability Condition to Avoid:NO DATA AVAILABLE.
Hazardous Decomposition Products:UNKNOWN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information===================
Toxicological Information:CHRONIC: MUTATION DATA CITED.
===================== Ecological Information =====================
Ecological:EPA WASTE NUMBER: NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL ENVIRONMENTAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE
DISPOSER (TSD) TO ASSURE COMPLIANCE.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED.
===================== Regulatory Information =====================
SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312
REPORTING: ACUTE. LYPOPHILIZED CATALASE: SARA SECTION 313 CHEMICALS
NAME LIST: NO; SARA SECTION 313 CHEMICALS CHEMICAL CATEGORY: NO;
SARA EHS SECTION 302 TPQ: NO.
Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY.
LYPOPHILIZED CATALASE: CERCLA SECTION 103 RQ LBS: NO; RCRA SECTION
261.33: NO.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:EPI-SEAL PASTE SPEC.2020
Kit Part:Y
CAGE:3L885
CAGE:3L885
============= Composition/Information on Ingredients =============
Ingred Name:DURAMITE (CAS NO. 471-34-1)
CAS:471-34-1
RTECS #:FF9335000
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
OSHA PEL:15MG/M3 DUST/5 FUME
ACGIH TLV:10MG/M3 DUST; 9192
Ingred Name:ARALDITE 6004 (CAS NO. 25068-38-6)
CAS:25068-38-6
RTECS #:SL6475000
Ingred Name:SILICA, AMORPHOUS, DUST
CAS:112945-52-5
RTECS #:VV7310000
OSHA PEL:6 MG/M3
ACGIH TLV:10 MG/M3; 8990
===================== Hazards Identification =====================
Effects of Overexposure:POSSIBLE IRRITATION. STRONG SENSITIZER. AVOID
VAP INHALE. PREVENT ALL SKIN & EYE CONTACT.
======================= First Aid Measures =======================
First Aid:SKIN:WASH AFFECTED AREAS W/SOAP & WATER.LAUNDER CONTAM
CLOTHES BEFORE REUSE. EYES:FLUSH W/WATER FOR 15 MIN. INH:REMOVE TO
FRESH AIR IMMED,GIVE O*2 OR ARTIF RESP IF NEC. BE EXAMINED BY A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:>250F COC
Lower Limits:N/D
Upper Limits:N/D
Extinguishing Media:DRY CHEMICAL, FOAM, CO*2
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRV RESPIR;COOL EXPOS CANS
W/WATER SPRAY
Unusual Fire/Explosion Hazard:NO UNUSUAL HAZARDS. THE PRODUCT SHOULD BE
HANDLED AS A COMBUSTIBLE MATERIAL.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. SOAK UP
W/ABSORBENT MATERIAL OR SCRAPE UP. CLEAN UP CONTAMINATED AREA
W/WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:PRACTICE GOOD CAUTION & PERSONAL
HYGIENE TO AVOID SKIN & EYE CONTACT. STORE IN COOL PLACE. AVOID
SPARKS & FLAMES.
Other Precautions:AVOID BREATHING VAPORS OF HEATED PRODUCT. DISCARD
CONTAMINATED SHOES & OTHER LEATHER ARTICLES. MFR RECM NIOSH/MSHA
APPROVED ORGANIC VAPOR RESPIRATOR,HOWEVER,SHOULD CONSULT SAFETY/IH
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROT
REQD,CONSULT SAFETY OFF./I.H.
Ventilation:LOCAL EXHAUST;GENERAL MECHANICAL VENTILATION
Other Protective Equipment:RUBBER APRONS OR COVERALLS
Supplemental Safety and Health
DATE OF PREP: 6/9/86. PART A OF A TWO PART KIT. KEY1:N1.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:N/D
Vapor Pres:N/D
Vapor Density:N/D
Spec Gravity:1.12
Evaporation Rate & Reference:N/D
Solubility in Water:SLIGHT
Appearance and Odor:WHITE PASTE; CHARACTERISTIC ODOR
Percent Volatiles by Volume:N/D
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:CO &/OR CO*2
Conditions to Avoid Polymerization:EXCESS HEATING OVER LONG TIME
W/EXCESS OF CURING AGENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE UNDER APPROVED CONDITIONS THAT MEET
FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BLACK DEVELOPER F048DC
CAGE:S4117
CAGE:S4117
============= Composition/Information on Ingredients =============
Ingred Name:FERRITE (CONSISTING OF INGREDIENTS 2 - 4)
RTECS #:9999999ZZ
Fraction by Wt: >96%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:IRON (III) OXIDE
CAS:1309-37-1
RTECS #:NO7400000
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3 (FE)
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
OSHA PEL:15MG/M3 TDUST;5 FUME
ACGIH TLV:10MG/M3 TDUST
Ingred Name:COPPER OXIDE
CAS:1317-38-0
RTECS #:GL7900000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:STYRENE ACRYLATE COPOLYMER
CAS:27136-15-8
Fraction by Wt: <4%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:MAY CAUSE IRRITATION OR CORNEAL
INJURY DUE TO MECHANICAL ACTION. SKIN:ESSENTIALLY NONIRRITATING.
INHAL:MINIMAL IRRITATION TO RESPIRATORY TRACT MAY OCCUR.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:NONE
Medical Cond Aggravated by Exposure:NO DATA AVAILABLE.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . SKIN:FLUSH W/COPIOUS AMOUNTS OF
WATER. CALL MD . EYE:FLUSH IMMEDIATELY W/PLENTY OF WATER FOR AT
LEAST 15 MINUTES. INHAL:REMOVE TO FRESH AIR. IF EFFECTS OCCUR,
CONSULT MEDICAL PERSONNEL.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER FOG, FOAM, CO*2 OR DRY CHEMICALS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE UNDER NORMAL STORAGE CONDITIONS &
USE. NON-SENSITIVE TO MECHANICAL IMPACT. WHEN SUSPENDED IN AIR,
SENSITIVE TO STATIC CHARGE & COMBUSTIBLE.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP OR CLEAN UP W/VACUUM CLEANER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:INHALATION & CONTACT W/SKIN OR EYE
SHOULD BE AVOIDED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED UNDER NORMAL USE. IN DUSTY
ATMOSPHERES, A NIOSH/MSHA APPROVED RESPIRATOR SHOULD BE USED.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT FOR MOST
CONDITIONS.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Spec Gravity:5.1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK FINE POWDER; ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR DUMP UNDER CONDITIONS WHICH MEET
FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ENE BLACK IMMERSION D 6
CAGE:85962
CAGE:85962
============= Composition/Information on Ingredients =============
Ingred Name:PHOSPHORIC ACID (SARA III)
CAS:7664-38-2
RTECS #:TB6300000
Fraction by Wt: <5%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: <1%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SELENIOUS ACID (SARA III)
CAS:7783-00-8
RTECS #:VS7175000
Fraction by Wt: <5%
OSHA PEL:0.2 MG (SE)/M3
ACGIH TLV:0.2 MG(SE)/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:COPPER (II) SULFATE (1:1);(COPPER SULFATE)(SARA III)
CAS:7758-98-7
RTECS #:GL8800000
Fraction by Wt: <5%
OSHA PEL:1 MG (CU)/M3
ACGIH TLV:1 MG(CU)/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INGESTION, ABSORBTION & INHALATION MAY
AFFORD SERIOUS RISK OF POISONING. MATERIAL IS IRRITATING TO SKIN &
EYES.
Explanation of Carcinogenicity:SULFURIC ACID MIST:IARC MONOGRAPHS, VOL
54, PG 41, 1992: GROUP 1 ANIMAL:PULM IRRIT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE/SKIN: IMMEDIATELY FLUSH AFFECTED AREA W/LGE AMTS OF CLEAN
WATER FOR AT LEAST 15 MINS. FOR EYES, GET MED ATTN. INHAL: REMOVE
FROM AREA TO FRESH AIR. INGEST: GIVE LARGE QTYS OF MILK OR WATER.
DO NOT INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, CO*2, DRY CHEMICAL OR AS IS NECESSARY
FOR PRIMARY CAUSE OF FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT. HEATING OF SOLN MAY LIBERATE TOXIC FUMES.
Unusual Fire/Explosion Hazard:CONTACT OF SOLUTION WITH METALS MAY
LIBERATE HYDROGEN GAS WHICH IS FLAMMABLE & EXPLOSIVE.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP ON SUITABLE ABSROBENT & TRANSFER TO
TREATMENT AREA. SWEEP UP SOLIDS OR FLUSH SOLUTIONS WITH WATER &
TRANSFER TO WASTE TREATMENT AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY AREA AWAY FROM
SUNLIGHT & HEAT. KEEP CNTNR CLSD WHEN NOT IN USE. STORE TO PVNT
PHYSICAL DMG TO CNTNR.
Other Precautions:AVOID CONTACT WITH CONCENTRATED ACIDS & OXIDIZING
MATERIALS. USE IN A WELL VENTILATED AREA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED DUST &/MIST RESPIRATOR.
Ventilation:LOCAL EXHAUST TO MAINTAIN LEVEL BELOW TLV.
Other Protective Equipment:PROTECTIVE CLOTHING TO PREVENT SKIN CONTACT.
ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAV: 1.09-1.11 (H*2O=1). PH: 5% SOLUTION <1.
================== Physical/Chemical Properties ==================
Spec Gravity:SUPP DATA
pH:SUPDAT
Solubility in Water:COMPLETE
Appearance and Odor:BLUE, CLEAR SOLUTION WITH LITTLE OR NO ODOR.
Percent Volatiles by Volume:>85
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH CONCENTRATED ACIDS AND STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID OVERHEATING OF SOLUTION (ABOVE 120
DEGREES F).
Hazardous Decomposition Products:TOXIC HYDROGEN SELENIDE FUMES MAY BE
PRODUCED.
==================== Disposal Considerations ====================
Waste Disposal Methods:REDUCE W/SUITABLE REDUCING MATERIAL; SULFUR
DIOXIDE, BISULFITES OR METALLIC ZINC TO ELEMENTAL SELENIUM. COLLECT
& DISPOSE OF SELENIUM IN ACCORDANCE WITH ALL FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SB 836 9175 (SAE GRADE 85W/140)
CAGE:70878
CAGE:70878
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM HYDROCARBON
===================== Hazards Identification =====================
Effects of Overexposure:IRRITANT TO SKIN & EYES W/PROLONGED CONTACT.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER FOR 15 MINUTES. CALL PHYSICIAN. SKIN:WASH
THOROUGHLY WITH SOAP AND WATER.INGESTION:CALL PHYSICIAN
IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:400F, 204C, COC
Extinguishing Media:DRY CHEMICAL,FOAM, SAND, EARTH, WATERFOG, CO*2
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:DENSE SMOKE
================== Accidental Release Measures ==================
Spill Release Procedures:TRANSFER BULK OF MATERIAL INTO ANOTHER
CONTAINER. ABSORB REMAINING MATERIAL WITH PROPER ABSORBENT SUCH AS
SAND, EARTH, VERMICULITE. SWEEP UP AND DISPOSE AS SOLID WASTE.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:MFR RECOMMENDS NONE.
Ventilation:MFR RECOMMENDS NONE
Supplemental Safety and Health
SPEC:MIL-L-2105C. CONTAINER:1 GAL CAN.
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:149C, 300F
Spec Gravity:0.936
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER LIQUID WITH MINERAL OIL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS:CHROMIC ACID, H*20*2, BROMINE
Hazardous Decomposition Products:CO & CO*2
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE DISPOSAL METHOD MUST BE IAW FEDERAL, STATE
AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HYDRAZINE CHEMETS, ULR CHEMETS, VACUETTES AND VACU-VIALS
Kit Part:Y
CAGE:7K791
CAGE:7K791
Contract Num:SP0440-99-M-M948
CAGE:7Z016
============= Composition/Information on Ingredients =============
Ingred Name:P-DIMETHYLAMINO BENZALDEHYDE
CAS:100-10-7
RTECS #:CU5775000
< Wt:1.
Other REC Limits:NONE RECOMMENDED
Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA 302/313)
(CERCLA)
CAS:7647-01-0
RTECS #:MW4025000
= Wt:6.5
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM; 9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
> Wt:16.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
Ingred Name:METHYL ALCOHOL (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
< Wt:20.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 200 PPM
ACGIH TLV:S,200PPM/250STEL; 95
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
< Wt:56.
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:C 50 PPM,VAPOR; 9495
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Health Hazards Acute and Chronic:ACUTE-IRRITATION. CHRONIC-IRRITATION
AND SENSITIZATION DERMATITIS.
Explanation of Carcinogenicity:NTP CARCINOGENISIS STUDIES; TEST
COMPLETED (POST PEER REVIEW), OCTOBER 1992. NIOSH ANALYTICAL
METHODS: SEE ETHYLENE GLYCOL, 5500.
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING, CHEMICAL BURNS,
SENSITIZATION, DERMATITIS.
Medical Cond Aggravated by Exposure:MAY CAUSE IRRITATION TO EYES, SKIN
AND MUCOUS MEMBRANES.
======================= First Aid Measures =======================
First Aid:EYE AND SKIN CONTACT- IMMEDIATELY FLUSH EYES AND SKIN WITH
WATER FOR 15 MINUTES. INGESTION- SEEK MEDICAL ATTENTION.
INHALATION- REMOVE INDIVIDUAL TO FRESH AIR.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:=51.1C, 124.F
Autoignition Temp:=397.8C, 748.F
Lower Limits:3.2%
Upper Limits:15.3%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM OR
WATER.
Fire Fighting Procedures:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Unusual Fire/Explosion Hazard:NO DATA PROVIDED BY RESPONSIBLE PARTY.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. PLACE IN
SMALL CONTAINER FOR DISPOSAL. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================Handling and Storage ======================
Handling and Storage Precautions:PRODUCT SHOULD BE STORED IN THE DARK
AND AT ROOM TEMPERATURE; HOWEVER, TEMPERATURES UP TO 120F OR EVEN
BELOW FREEZING WILL NOT NORMALLY AFFECT REAGENT PERFORMANCE.
Other Precautions:WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING
AND BEFORE EATING, DRINKING, SMOKING. KEEP OUT OF REACH OF
CHILDREN. DO NOT TAKE INTERNALLY. DO NOT INHALE. DO NOT GET IN EYES
OR ON SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Ventilation:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Other Protective Equipment:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Work Hygienic Practices:AVOID CONTACT WITH EYES. WASH THOROUGHLY AFTER
HANDLING.
Supplemental Safety and Health
FRAGILE: LIQUID IN GLASS. HANDLE WITH CARE.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:=115.C, 239.F
Melt/Freeze Pt:=-8.C, 17.6F
Spec Gravity:0.98
pH:<0.5
Solubility in Water:MISCIBLE
Appearance and Odor:PALE YELLOW LIQUID - ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NO DATA PROVIDED BY RESPONSIBLE PARTY.
Stability Condition to Avoid:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC FUMES.
=================== Toxicological Information===================
Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
===================== Ecological Information =====================
Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
===================== Regulatory Information =====================
SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SILICONE LUBRICANT, PART NO. 82146
CAGE:62377
CAGE:62377
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM DISTILLATE
Fraction by Wt: 17%
ACGIH TLV:500PPM
Ingred Name:DIMETHYL POLYSILOXANE
Fraction by Wt: 5%
Ingred Name:DISPERSAL AGENT
Fraction by Wt: 2-3%
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 10%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9192
===================== Hazards Identification =====================
Effects of Overexposure:DIZZINESS, DROWSINESS. AT VERY HIGH
CONCENTRATIONS, IRRITATION OF EYES AND MUCOUS MEMBRANES.
======================= First Aid Measures =======================
First Aid:INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL ATTENTION.
INHALATION: REMOVE TO FRESH AIR. SKIN: WASH WITH SOAP AND WATER.
EYES: FLUSH WITH PLENTY OF WATER. IF IRRITATION PERSISTS, GET
MEDICAL ATTENTI ON.
===================== Fire Fighting Measures =====================
Flash Point:33F (BASE ONLY)
Extinguishing Media:WATER FOG, FOAM, CO2
Unusual Fire/Explosion Hazard:CANS MAY BURST AT HIGH TEMP; BURNS TO
GIVE STANDARD CO2,CO, AND SMALL AMOUNT OF SILICA
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID SPARKS OR FLAME. VENTILATE. SOAK UP
LIQUID IN ANY INERT ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BELOW 120F. DO NOT USE NEAR
SPARKS OR FLAME. AVOID PROLONGED OR FREQUENT SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Ventilation:MUST BE ADEQUATE TO AVOID EXCEEDING TLV.
Supplemental Safety and Health
P.O. BOX 11915/ 705 N. MOUNTAIN ROAD, NEWINGTON, CONNECTICUT 06111.
================== Physical/Chemical Properties ==================
Vapor Pres: 55
Spec Gravity:0.95
Solubility in Water:PARTIAL
Appearance and Odor:CLEAR SPRAY, SLIGHT, MILD ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT INCINERATE CANS, USE LICENSED DISPOSAL
SERVICE. LANDFILL OR INCINERATE ABSORBED LIQUID SPILLAGE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:LAMINAR X500 LT STBLE HRDNR, 10C81
Preparer's Name:GALBREATH
CAGE:57294
CAGE:98795
CAGE:57294
============= Composition/Information on Ingredients =============
Ingred Name:HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)
(CERCLA) VP: 0.05 @ 20C
CAS:822-06-0
RTECS #:MO1740000
Fraction by Wt: <10%
OSHA PEL:N/K
ACGIH TLV:0.005 PPM; 9495
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS;
((HOMOPOLYMER) HEXAMETHYLENE DIISOCYANATE)
CAS:28182-81-2
RTECS #:NQ9170000
Fraction by Wt: 70-80%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA) VP:
8.0 @ 20C
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 10-20%
OSHA PEL:150 PPM
ACGIH TLV:150 PPM/200STEL;9495
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:XYLENE (SARA 313) (CERCLA) VP: 21.0 @ 20C
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 10-20%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM/150STEL;9495
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:VOLATILE ORGANIC CONTENT: 2.2 POUNDS PER GALLON LESS WATER
RTECS #:9999999VO
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:OVER EXPOSURE BY INHALATION MAY
CAUSE IRRITATION OF THE RESPIRATORY TRACT, HEADACHE, DIZZINESS, OR
DROWSINESS. SKIN AND EYE: IRRITANT TO THE EYES AND SKIN, AND SKIN
SENSITIVITY. CHRONIC: THOSE H AZARDOUS MATERIALS LISTED IN
INGREDIENTSECTION MAY AFFECT THE FOLLOWING ORGANS: RESPIRATORY
TRACT, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: ALLERGIC RESPIRATORY/SKIN REACTION,
CENTRAL NERVOUS SYSTEM, KIDNEYS, LIVER, CARDIAC SENSITIZATION.
Medical Cond Aggravated by Exposure:RESPIRATORY PROBLEMS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. EYE: FLUSH IMMEDIATELY WITH
LARGE AMOUNTS OF RUNNING WATER FOR AT LEAST 15 MINUTES. SKIN:
REMOVE CONTAMINATED CLOTHING AND WASH SKIN WITH SOAP AND WATER.
INGESTION: D RINK WATER. IF NECESSARY, CONSULT A PHYSICIAN FOR ANY
OF THESE CONDITIONS.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:91.0F,32.8C
Lower Limits:1.10%
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, OR CARBON
DIOXIDE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, AVOID
BREATHING VAPORS, VENTILATE AREA, AND REMOVE WITH INERT ABSORBANT &
NON-SPARKING TOOLS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS. BEFOR E ATTEMPTING TO CLEAN UP, SEE INGREDIENT
SECTION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT TAKE INTERNALLY. CONTAINERS
SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUID IN
EXCESS OF A FEW INCHES.
Other Precautions:MAKE SURE THE DRUM IS COMPLETELY EMPTY BEFORE
ATTEMPTING TO WELD OR BRAZE. THE DRUM SHOULD BE INDUSTRIALLY
CLEANED PRIOR TO REUSE. DO NOT FLAME CUT, BRAZE, OR WELD WITHOUT A
NIOSH APPROVED RESPIRATOR OR APPROPRIATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE GEN DILUTION/LOC EXHST FAILS TO ADEQUATELY
DILUTE THE TWA/PEL OF THE MATL, THEN RESP PROT SHOULD BE USED AS
FOLLOWS: DO NOT BRTH VAP/SPRAY MIST. WEAR AN APPROP, PROPERLY
FITTED RESP APPRVD BY NI OSH WHEN EXPOSED. AN AIR (SUPDAT)
Ventilation:PROVIDE GEN DILUTION/LOCAL EXHAUST VENTILATION TO KEEP TWA
& LEL BELOW ACCEPTABLE LIMITS & TO REMOVE DECOMP PRODUCTS.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID:THE DRUMS MAY EXPLODE. RESP PROC:LINE RESPIRATOR (TC19C
NIOSH) IS RECOMMENDED. A VAPOR/PARTICULATE RESPIRATOR (TC23C NIOSH)
MAY BE APPROPRIATE WHEN AIR-BORNE MONITORING SHOWS ISOCYANATE S TO
BE 10 TIMES LESS THAN THE APPLICABLE EXPOSURE LIMITS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>259F,>126C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
WILL REACT W/H*2O/H*2O CONTAINING PRODS TO GIVE OFF HEAT & FUMES. DO
NOT ALLOW H*2O TO ENTER SEALED DRUMS AS (SUPDAT)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FUMES MAY CNTN CARBON MONOXIDE &
OXIDES OF NITROGEN. MAY PRODUCE HAZS FUMES WHEN HEATED TO
DECOMPOSITION AS IN WELDING.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ISOPROPYL ALCOHOL
Kit Part:Y
Preparer's Name:C.A. EISENHARD
CAGE:60777
CAGE:60777
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPANOL OR ISOPROPYL ALCOHOL (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 99%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL;9495
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PROLONGED OR REPEATED EXPOSURE TO HIGH
CONCENTRATIONS CAN PRODUCE SEVERE OR FATAL CNS DEPRESSION.
Explanation of Carcinogenicity:IARC LISTS ISOPROPYL ALCOHOL AS A CLASS
3 (INSUFFICIENT EVIDENCE).
Effects of Overexposure:HEADACHE, DIZZINESS, NAUSEA, VOMITING,
DROWSINESS, INCCORDINATION, UNCONSCIOUSNESS, POSSIBLE DEATH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES-FLUSH WITH WATER FOR 15 MINUTES.GET MEDICAL ATTENTION.
SKIN-FLUSH WITH WATER.IF IRRITATION PERSISTS,GET MEDICAL
ATTENTION.INHALATION-REMOVE VICTIM TO FRESH AIR & PROVIDE
ARTIFICIAL RESPIRATION IF NEEDED.GET MEDICAL
ATTENTION.INGESTION-IF CONSCIOUS,GIVE WATER TO DRINK & INDUCE
VOMITING,KEEPING VICTIM'S HEAD BELOW HIPS.GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:53.0F,11.7C
Lower Limits:2
Upper Limits:12.7
Extinguishing Media:WATER FOG, CARBON DIOXIDE, DRY CHEMICAL, FOAM. DO
NOT USE DIRECT STREAM OF WATER, PRODUCT WILL FLOAT/REIGNITE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR. COOL FIRE EXPOSED CONTAINERS AND STRUCTURES
WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:VAPOR MAY BE MOVED BY AIR CURRENTS TO
DISTANT IGNITION SOURCES FROM HANDLING POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROPER PROTETCIVE CLOTHING. ELIMINATE ALL
SOURCES OF IGNITION. USE NON-SPARKING TOOLS. MOP UP OR ABSORB ONTO
INERT MATERIALS AND PLACE IN A CONTAINER FOR LATER DISPOSAL. REPORT
IF REQUIRED. DISPO SE OF IAW ALL APPLICABLE REGULATIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
PLACE AWAY FROM SOURCES OF IGNITION AND STRONG OXIDIZING AGENTS.
Other Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE. PROPERLY BOND
& GROUND CONTAINERS WHEN TRANSFERRING PRODUCT. DO NOT USE PRESSURE
TO EMPTY CONTAINER. CONTAINERS, EVEN "EMPTY" ONES RETAIN PRODUCT
RESIDUE AND VAP ORS.OBEY WARNINGS/PRECAUTIONS AS IF FULL
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE
WITH 29 CFR 1910.13 4 AND MANUFACTURER'S RECOMMENDATIONS.
Ventilation:USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR
LOCAL EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION & SAFETY SHOWER. LONG
SLEEVED SHIRT, TROUSERS, SAFETY SHOES, RUBBER APRON. EYE WASH
STATION.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
PART 2 OF 2 PART KIT. SEE PNI A THIS NSN/CAGE.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:181F,83C
Melt/Freeze Pt:M.P/F.P Text:-127F,-88C
Vapor Pres:33
Vapor Density:2.07
Spec Gravity:0.79
Evaporation Rate & Reference:3 (N-BUTYL ACETATE=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID; MEDICINAL ALCOHOLIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER. DLA-HMIS: STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. DLA-HMIS:
AVOID HEAT, FLAMES, AND OXIDIZABLE MATERIALS.
Hazardous Decomposition Products:MAY LIBERATE CARBON MONOXIDE AND
CARBON DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL ENVIRONMENTAL REGULATIONS. EPA/RCRA WASTE NUMBER(S) D001
MAY APPLY TO UNUSED/UNCONTAMINATED PRODUCT.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:C33200 FREE CUTTING TUBE BRASS
CAGE:COPPE
CAGE:COPPE
============= Composition/Information on Ingredients =============
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 66.50%
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: 31.90%
OSHA PEL:15MG/M3 TDUST/5 FUME
ACGIH TLV:10MG/M3 TDUST; 9293
Ingred Name:LEAD, INORGANIC LEAD (SUSPECTED HUMAN CARCINOGEN BY IARC,
NTP & ACGIH)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 1.60%
OSHA PEL:0.05 MG/CUM
ACGIH TLV:0.15 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: METAL FUME FEVER W/FLU
SYMPTOM/HAND/FEET KERATINIZATION/UPPER RESPIRATORY
IRRITATION/METALLIC TASTE/NAUSEA/POISON/FATIGUE/HEADACHE/ACHING
BONE/MUSCLE/CONSTIPATION/ABDOMINAL PAIN/APPETITE L
OSS/SEIZURE/COMA/DEATH/ANEMIA/KIDNEY DAMAGE/CONVULSION/DELIRIUM.
SKIN/HAIR: DISCOLORATION, PALE & BLUISH TINT.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:INHALATION: NOSE/MOUTH/THROAT IRRITATION.
NAUSEA/COMITING/CHILLS/FEVER. MUSCLE/JOINT PAIN.
THIRST/BRONCHITIS/PNEUMONIA/APPETITE LOSS/WRIST PARALYSIS. CNS
EFFECTS/DELIRIUM/CONVULSION/COMA/DEATH. DECREA SED FERTILITY &
INCREASED CHANCES OF MISCARRIAGE OR BIRTH DEFECTS. ACCUMULATIVE
POSION.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF WATER. SKIN: VACUUM OFF EXCESS DUST.
WASH WELL W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:SPECIAL MIXTURES OF DRY CHEMICAL OR SAND.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NON COMBUSTIBLE. MODERATE WHEN MATERIAL
IS IN THE FORM OF DUST & EXPOSED TO HEAT, FLAMES, CHEMICAL REACTION
OR IN CONTACT W/POWERFUL OXIDIZERS.
================== Accidental Release Measures ==================
Spill Release Procedures:DUST: VACUUM OR WET SWEEP. VENTILATE AREA.
LIQUIDS (ACIDS/BASES) CONTAINING SOLUBILIZED METAL, EVACUATE
UNPROTECTED PERSONNEL. ABSORB W/VERMICULITE, DRY SAND, OR SIMILAR
MATERIAL. CLEANUP PERSONNEL SH OULD WEAR RESPIRATORS & PROTECTIVE
CLOTHING.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID INCOMPATIBLE MATERIALS & KEEP
DUST FROM SOURCES OF IGNITION.
Other Precautions:MOLTEN METAL MAY REACT VIOLENTLY W/WATER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURE ABOVE THE PEL OR TLV, NIOSH APPROVED
RESPIRATOR FOR FUME OR DUST, DEPENDENT UPON THE SOURCE OF AIRBORNE
CONTAMINANT.
Ventilation:LOCAL EXHAUST/MECHANICAL (GENERAL) REQUIRED IF DUST OR
FUMES ARE CREATED.
Other Protective Equipment:AS REQUIRED FOR THE WORK DONE ON OR WITH THE
METAL. I.E. FACE SHIELDS & SPECIALLY TINTED GLASSES.
Work Hygienic Practices:EVALUATE THE JOBS DONE ON THIS PRODUCT IN
ACCORDANCE W/OSHA, STATE, FEDERAL, LOCAL STANDARDS.
Supplemental Safety and Health
UNDER NORMAL HANDLING CONDITIONS THE SOLID ALLOY PRESENTS NO
SIGNIFICANT HEALTH HAZARDS. PROCESSING OF THE ALLOY BY DUST OR FUME
PRODUCING OPERATIONS (GRINDING, BUFFING, HEATING, WELDING, ETC.)
MAY RE SULT IN THE POTENTIAL FOR EXPOSURE TO AIRBORNE METAL
PARTICULATES OR FUMES.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:1290-2260F
Spec Gravity:7.45-9
Solubility in Water:INSOLUBLE
Appearance and Odor:SOLID, SILVER OR YELLOW TO RED, ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, BASES & OXIDIZERS.
Stability Condition to Avoid:HEAT, FLAME, CHEMICAL REACTION & OTHER
IGNITION SOURCES WHEN MATERIAL IS IN DUST FORM.
Hazardous Decomposition Products:METAL FUME
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. WEAR RESPIRATORS & PROTECTIVE CLOTHING.
VENTILATE AREA.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: C-5A ANTISEIZE, ANTI-SEIZE LUBRICANT, 39761
Cage: 05972
=======================================================
Contractor Summary
=======================================================
Cage: 05972
Cage: 9H439
Box: 81084
Contract Number: N00406-99-M-7424
=======================================================
Ingredients
=======================================================
Cas: 7782-42-5
RTECS #: MD9659600
< Wt: 20.
OSHA PEL: 2.5 MG/M3
ACGIH TLV: 2 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 64742-52-5
RTECS #: PY8035001
NAPHTHENIC; (HYDROTREATED PETROLEUM DISTILLATES)
< Wt: 25.
------------------------------
Cas: 7440-50-8
RTECS #: GL5325000
< Wt: 25.
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 64742-18-3
RTECS #: PY8032001
SOLVENT-REFINING AND/OR HYDROTREATMENT); (PETROLEUM DISTILLATE)
< Wt: 15.
OSHA PEL: 5 MG/M3
ACGIH TLV: 5 MG/M3
ACGIH STEL: 10 MG/M3
------------------------------
Cas: 14808-60-7
RTECS #: VV7330000
< Wt: .2
Other REC Limits: TLV:0.1 MG/M3 (MFR)
OSHA PEL: 0.1 MG/M3
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 64755-01-7
> Wt: 3.
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: HARMFUL IF SWALLOWED. AT ELEVATED TEMPS MAY CAUSE IRRIT OF
EYES & RESP TRACT. EYE CONT:SLIGHTLY IRRIT BUT DOES NOT INJURE TISS. SKIN
CONT:PRLNG/RPTD CONT MAY CAUSE IRRIT. INHAL:INHAL OF DUST AT LEVELS ABOVE
RELS MAY CAUSE METALLIC/SWEET TASTE, IRRIT OF PHARYNX & POSS ULCERATION
W/PERFORATION OF NASAL SEPTUM. INGEST:MOD TOX. IRRIT TO MOUTH, THROAT &
STOM, W/NAUS. CHRONIC:RPTD & PRLNG INHAL OF GRAPH ITE/CARBON DUSTS MAY
CAUSE PULM FIBROSIS, EMPHYSEMA & PNEUMOCONIOSIS. SEVERITY OF THESE EFTS
IS GREATLY INFLUENCED BY PRESENCE OF OTHER HARMFUL MINERAL DUSTS, MOST
NOTABLY CRYSTALLINE SILICA. THIS PRO D CNTNS ENCAPSULATED (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: SILICA, CRYSTALLINE - QUARTZ: IARC MONOGRAPHS,
VOL 68, PG 41, 1997:GROUP 1. NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998:
REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN.
Signs And Symptions Of Overexposure: HLTH HAZ:SILICON DIOXIDE (QUARTZ, SILICA).
NO EXPOS TO FREE RESPIRABLE SILICA IS ANTIC DURING NORM USE OF THIS PROD. IT
SHOULD BE NOTED, HOWEVER, THAT FREE RESPIRABLE SILICA HAS BEEN LISTED AS
CONFIRM ED HUMAN CARCIN BY NTP & IARC. INHAL OF FREE RESPIRABLE SILICA
MAY CAUSE SILICOSIS/OTHER SERIOUS DELAYED LUNG INJURY. SILICA MAY BE RELS BY
GRINDING/MACHINING OF COATED MATLS. THIS PROD CNTNS ENCAPSUL ATED METAL PWDR
WHICH CNTNS COPPER & ZINC. NO EXPOS TO FREE METAL PWDR MAY BE RELS,
HOWEVER, BY GRINDING/MACHINING OF CURED CMPD/COATED SURF. RPTD/PRLNG OVEREXP
TO METAL DUST MAY CAUSE METAL-FUME FEVE R, METALLIC TASTE & (SUPP DATA)
Medical Cond Aggravated By Exposure: PREEXISTING PULMONARY & DERMATOLOGICAL
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO HAZARDOUS COMPONENTS.
First Aid: EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES.
GET MED ATTN, IF IRRIT PERSISTS. SKIN:WASH WITH SOAP & WATER. GET MED
ATTN IF IRRIT DEVELOPS OR PERSISTS. INHAL:NO SPECIFIC TREATME NT IS NECESSARY
SINCE THIS MATL IS NOT LIKELY TO BE HAZARDOUS BY INHAL. IF EXPOSED TO
EXCESSIVE LEVELS OF DUSTS OR FUMES, REMOVE TO FRESH AIR & GET MED ATTN IF
COUGH OR OTHER SYMPTOMS DEVELOP. INGEST: IF SWALLOWED, DO NOT INDUCE
VOMIITING. GIVE VICTIM A GLASS OF WATER OR MILK. CALL MD OR POISON CONTROL
CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
NOTES TO MD:NO INFORMA TION.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: RECLAIM CLEAN MATERIAL. CONTAMINATED MATERIAL SHOULD
BE SWEPT OR SHOVELED INTO APPROPRIATE WASTE CONTAINER & DISPOSED OF I/A/W
APPLICABLE FEDERAL, STATE & LOCAL REGULATIONS.
Waste Disposal Methods: REVIEW ALL CURRENT FEDERAL, STATE & LOCAL
REGULATIONS REGARDING HEALTH & DISPOSAL FOR APPROPRIATE DISPOSAL
PROCEDURES. INCINERATION PREFERRED. COMPONENT RCRA CLASSIFICATIONS: NOT
REGULATED. COMPONENTRCRA CODES: NO INFORMATION. CERCLA RQ VALUE (MINIMUM):
NONE.
Handling And Storage Precautions: AVOID PROLONGED OR REPEATED CONTACT WITH
SKIN. DO NOT TAKE INTERNALLY. FOR INDUSTRIAL USE ONLY. STORE AWAY FROM HEAT.
KEEP OUT OF REACH OF CHILDREN.
Other Precautions: FOLLOW GENERAL INDUSTRIAL SAFETY PRACTICES DURING USE. DO
NOT REUSE EMPTY CONTAINERS WITHOUT COMMERCIAL CLEAN OR RECONDITION. FOLLOW
ALL MSDS/LABEL PRECAUTIONS EVEN AFTER CONTAINER IS EMPTIED.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point: =148.9C, 300.F
Autoignition Temp Text: N/I
Extinguishing Media: CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). USE WATER TO COOL EXPOSED CONTAINERS. WATER STREAM DIRECTED INTO FIRE
MAY CAUSE FROTHING WITH SUBSEQUENT SPREAD OF FLAME.
Unusual Fire/Explosion Hazard: FINELY DIVIDED DUST IN AIR MAY PRESENT EXPLOSION
HAZ. PREVENT DUST BUILDUP. CLSD CNTNRS MAY RUPTURE/EXPLODE (DUE TO PRESS
BUILD-UP) WHEN EXPOSED TO EXTREME HEAT. IRRITATING &/OR TOXIC GASES/FUMES
MAY BE GENERATED BY THERMAL DECOMP/COMBUST.RATING: HEALTH - 1;
FLAMMABILITY - 1; REACTIVITY - 0.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE NORMALLY REQUIRED UNDER GENERAL VENT. IF EXPOSURE
LEVELS ARE UNKNOWN, IF LEVELS EXCEED TLV/PEL, OR IF EFFECTS OCCUR, USE NIOSH
APPROVED DUST/MIST RESPIRATOR I/A/W WITH APPLICABLE HEALTH & SAFETY
REGULATIONS & MFR'S RECOMMENDATIONS. USE NIOSH APPROVED DUST/MIST
RESPIRATOR WHEN GRINDING OR MACHINING COATING OR COATED ITEMS.
Ventilation: GENERAL VENTILATION USUALLY ADEQUATE.
Other Protective Equipment: EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). CLEAN CLOTHING TO COVER SKIN.
Work Hygienic Practices: WASH HANDS BEFORE EATING.
Supplemental Safety and Health: EFTS OF OVEREXP:DISCOLORATION OF SKIN &
HAIR. REFER TO PROTECTIVE EQUIPMENT SECTION FOR APPROPRIATE PROTECTIVE
MEASURES. PHYSICAL DATA: ODOR THRESHOLD: NO DATA. COEFFICIENT OF WATER/OIL
DISTRIBUTION: NOT APPLICABLE.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >287.8C, 550.F
B.P. Text: 550F - 4215F
Vapor Density: HVR/AIR
Spec Gravity: 1.3017
Viscosity: HIGH
Evaporation Rate & Reference: SLOWER THAN BUTYL ACETATE
Solubility in Water: INSOLUBLE
Appearance and Odor: COPPER COLORED PASTE; SLIGHT PETROLEUM ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID PROLONGED EXPOSURE TO HEAT. THIS PRODUCT IS
STABLE UNDER NORMAL STORAGE CONDITIONS.
Materials To Avoid: STRONG LEWIS OR MINERAL ACIDS. STRONG BASES OR OXIDANTS.
NITRATES, NITRITES, CHLORINATED HYDROCARBONS, CHLORIDES, PALLADIUM, SELENIUM,
MANGANESE, MAGNESIUM + POTASSIUM CHLORATE, SODIUM CARBONATE, SULFATES,
DIBORANE.
Hazardous Decomposition Products: OXIDES OF CARBON, VARIOUS HYDROCARBONS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR UNDER NORMAL CONDITIONS.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: NO PRODUCT OR COMPONENT TOXICOLOGICAL INFORMATION IS
AVAILABLE.
=======================================================
Ecological Information
=======================================================
Ecological: ECOLOGICAL TEST DATA: NO INFORMATION.
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: CERCLA - SARA HAZARD CATEGORY: THIS PRODUCT HAS
BEEN REVIEWED & IS CONSIDERED, UNDER APPLICABLE DEFINITIONS, TO MEET
FOLLOWING CATEGORIES: IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD. SARA
SECTION 313: THIS PRODUCT CONTAINS FOLLOWING SUBSTANCES SUBJECT TO REPORTING
REQUIREMENTS OF SECTION 313 & 40 CFR PART 372: COPPER - CAS $7440-50-8 -
WT = <25%.
Federal Regulatory Information: OSHA: HAZARDOUS BY DEFINITION OF HAZARD
COMMUNICATION STANDARD (29 CFR 1910.1200). TOXIC SUBSTANCES CONTROL ACT:
CHEMICAL SUBSTANCES IN THIS PRODUCT ARE ON TSCA SECTION 8 INVENTORY. CANADIAN
W: TH IS MSDS HAS BEEN PREPARED IN COMPLIANCE W/CONTROLLED PRODUCT
REGULATIONS EXCEPT FOR USE OF THE 16 HEADINGS. CANADIAN W CLASS: D2B, D2A.
State Regulatory Information: NEW JERSEY RIGHT-TO-KNOW: FOLLOWING MATERIALS ARE
NON-HAZARDOUS, BUT ARE AMONG TOP FIVE COMPONENTS IN THIS PRODUCT: FATTY
ACIDS, TALLOW, CALCIUM SALTS - CAS #64755-01-7. PENNSYLVANIA RIGHT-TO-KNOW:
FO LLOWING NON-HAZARDOUS INGREDIENTS ARE PRESENT IN PRODUCT AT >3%: FATTY
ACIDS, TALLOW, CALCIUM SALTS - CAS #64755-01-7 & HYDROTREATED HEAVY
PARAFFINIC DISTILLATE - CAS #64742-54-7. CALIFORNIA PROPOSIT ION 65: WARNING:
CHEMICAL(S) NOTED BELOW & CONTAINED IN THIS PRODUCT, ARE KNOWN TO STATE
OF CALIFORN IA TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM:
NONE KNOWN.
=======================================================
Other Information
=======================================================
Other Information: PLEASE CONTACT LOCTITE CORPORATION QUALITY DEPARTMENT FOR
ASSISTANCE & RECOMMENDATIONS ON SPECIFICATIONS FOR THIS PRODUCT - ROCKY
HILL, CT - FAX: 860-571-5473.
=======================================================
HAZCOM Label
=======================================================
Product ID: C-5A ANTISEIZE, ANTI-SEIZE LUBRICANT, 39761
Cage: 05972
Company Name: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
Zipcode: 06067-3910
Label Required IND: Y
Date Of Label Review: 08/13/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE:ELEVATED TEMPS MAY CAUSE IRRIT OF EYES &
RESP TRACT. EYE:SLIGHTLY IRRIT BUT DOES NOT INJURE TISS. SKIN:PRLNG/RPTD CONT
MAY CAUSE IRRIT. INHAL:INHAL OF DUST AT LEVELS ABOVE RELS MAY CAUSE METAL
LIC/SWEET TASTE, IRRIT OF PHARYNX & POSS ULCER W/PERFORATION OF NASAL
SEPTUM. INGEST:MOD TOX. IRRIT TO MOUTH, THROAT & STOM, W/NAUS. CHRONIC:
CANCER HAZ. CONTAINS SILICA, CRYSTALLINE-QUARTS WHICH IS L ISTED AS A HUMAN
LUNG CARCIN (FP N). RPTD & PRLNG INHAL OF GRAPHITE/CARBON DUSTS MAY CAUSE
PULM FIBROSIS, EMPHYSEMA & PNEUM. INHAL OF FREE SILICA MAY CAUSE
SILICOSIS/DELAYED LUNG INJURY. MAY CAUSE MET AL-FUME FEVER. DISCOLORATION OF
SKIN & HAIR.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MIL-S-46163, TYPE 1, GRADE K
CAGE:33150
CAGE:33150
============= Composition/Information on Ingredients =============
Ingred Name:AROMATIC DIMETHYACRYLATE ESTER
Minumum % Wt:40.
Maxumum % Wt:50.
Ingred Name:HYDROXYALKYL METHYLCRYLATE
RTECS #:HY1000488
Minumum % Wt:30.
Maxumum % Wt:40.
Ingred Name:BISPHENOL A FUMERATE RESIN
RTECS #:FR1001927
Minumum % Wt:15.
Maxumum % Wt:20.
Ingred Name:CUMEN HYDROPEROXIDE*
RTECS #:CH1003641
Minumum % Wt:1.
Maxumum % Wt:3.
Ingred Name:1-ACETYL-2-PHENYLHYDRAZINE
CAS:114-83-0
RTECS #:AJ2900000
Minumum % Wt:.1
Maxumum % Wt:1.
Ingred Name:N, N-DIALKYLTOLUIDINES
RTECS #:DT1001910
Minumum % Wt:.1
Maxumum % Wt:1.
Ingred Name:MALEIC ACID
CAS:110-16-7
RTECS #:OM9625000
Minumum % Wt:.1
Maxumum % Wt:1.
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SACCHARIN*
RTECS #:SA1002328
Minumum % Wt:1.
Maxumum % Wt:2.
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:MAY CAUSE DERMATITIS ON PROLONGED
CONTACT IN SENSITIVE INDIVIDUAL. FIRST AID: INGESTION: DO NOT
INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTIAN MEDICAL ATTENTION.
INHALATION: DOES NOT APPLY SKIN CONTACT: WASH THOUROUGHLY WITH
SOAP AND WATER EYE CONTACT: FLUSH AT LEAST 15 MINUTES WITH WATER.
OBTAIN MEDICAL ATTENTION.
Explanation of Carcinogenicity:MAY CAUSE DERMATITIS ON PROLONGED
CONTACT IN SENSITIVE INDIVIDUAL. FIRST AID: INGESTION: DO NOT
INDUCE VOMITING. KEEP INDIVIDUAL CALM. OBTIAN MEDICAL ATTENTION.
INHALATION: DOES NOT APPLY SKIN CONTACT: WASH THOUROUGHLY WITH
SOAP AND WATER EYE CONTACT: FLUSH AT LEAST 15 MINUTES WITH WATER.
OBTAIN MEDICAL ATTENTION.
Medical Cond Aggravated by Exposure:
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>93.3C, 200.F
>200F
Extinguishing Media:CO2, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:DOES NOT APPLY
Unusual Fire/Explosion Hazard:HAZARDOUS PRODUCTS FORMED: CO2, FOAM,
DRY CHEMICAL.
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP IN AN INERT ABSORBENT. STORE IN A
PARTLY FILLED, CLOSED CONTAINER UNTIL DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE: STORE BELOW 110F TO PRESERVE
SHELF LIFE. HANDLING: AVOID PROLONGED SKIN CONTACT. KEEP AWAY
FROM EYES.
============= Exposure Controls/Personal Protection =============
Ventilation:DOES NOT APPLY
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:>148.9C, 300.F
B.P. Text:>300F
Vapor Pres:< 5MMHG@80'F
Volatile Org Content %:38
Spec Gravity:1.11 @ 80' F
Solubility in Water:SLIGHT
Appearance and Odor:RED LIQUID/ MILD ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
=================== Toxicological Information===================
Toxicological Information:EYE IRRITANT. ORAL LD50 MORE THAN 10,000
MG/KG. ESTIMATED DERMAL LD50 GREATER THAN 2000 MG/KG.
===================== Ecological Information =====================
Ecological:THESE EFFECTS WERE NOT SEEN IN RATS EXPOSED FOR 1 YEAR TO
350 PPM OF ANOTHER SIMILAR SOLVENT,RATS EXPOSED TO VAPORS OF A
SIMILAR SOLVENT DURING PREGNANCY SHOWED EMBRY/FETOTOXICITY AT
CONCENTRATIONS PR ODUCING MATERIAL TOXICITY.NOTE TO PHYSICIAN: IF
MORE THAN 2.0 ML/KG HAS BEEN INGESTED AND VOMITING HAS NOT
OCCURRED, APHESIS SHOULD BE INDUCED WITH SUPERVISION. KEEP VICTIMS
HEAD BELOW HIPS TO PREVE NT ASPIRATION. IF SYMPTOMS SUCH AS LOSS
OF GAG REFLEX, CONVULSIONS OR UNCONSIIUOSNESS OCCUR BEFORE EMISIS,
GASTRIC LAVAGE USING A CUFFED ENDOTRACHEAL TUBE SHOULD BE
CONSIDERED.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE FOLLOWING EPA AND LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:UN# 1263 SHIPPING NAME: PAINT. HAZARD CLASS:
FLAMMABLE LIQUID.
===================== Regulatory Information =====================
SARA Title III Information:FEDERAL REGULATION REPORTABLE QUANTITY:
UNDER EPA-RCRA (40 CFR 261,21), THIS PRODUCT IS CLASSIFIED AS AN
OIL UNDER SECTION 311. SPILLS INTO OR LEADING INTO SURFACE WATES
THAT CAUSE A SHEEN MUST BE R EPORTED TO THE NATIONAL RESPONSE
CENTER 1-800-424-8802. EPA-COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIAQBILITY ACT. UNDER EPA-CERCLA (SUPERFUND)
RELEASE TO LAND, OR WATER MAY BE REPORT ABLE TO THE NATIONAL
RESPONSE CENTER 1-800-424-8802. (CIRCUMSTANCES SURROUNDING THE
RELEASE AND CLEAN-UP DETERMINE REPORTABLE QUANTITY.
State Regulatory Information:
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PAINT ETCH
CAGE:HO334
CAGE:HO334
CAGE:9B440
============= Composition/Information on Ingredients =============
Ingred Name:METHANE, DICHLORO-; (DICHLOROMETHANE) (SARA 313) (CERCLA)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 58%
OSHA PEL:500 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHYL ALCOHOL; (METHANOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 8%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM;250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL) (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 1%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM;500 STEL
Ingred Name:ALIPHATIC HYDROCARBONS
Fraction by Wt: 32%
OSHA PEL:N/K
ACGIH TLV:100 PPM (MFR)
Ingred Name:VOLATILE ORGANIC COMPOUNDS: 800 G/L (MAX).
RTECS #:9999999VO
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NAUSEA, DIZZINESS, DRUNKENNESS.
EXCESSIVE EXPOSURE MAY IRRITATE RESPIRATORY TRACT. EYE/SKIN
IRRITANT. SYSTEMIC EFFECTS: POSSIBLE NERVOUS SYSTEM, LIVER OR
KIDNEY DAMAGE W/EXCESSIVE EXPOSURES. MAY CAUSE CARDIAC ARRHYTHMIAS
& CARBOXY HEMOGLOBINEMIA. CHLOROCARBON MATLS HAVE PRODUCED SENSIT
OF MYOCARDIUM TO(EFTS OF OVEREXP)
Explanation of Carcinogenicity:DICHLOROMETHANE:IARC MONOGRAPHS, SUPP,
VOL 7, PG 194, 1987:GRP 2B. NTP 7TH ANNUAL RPT ON CARCINS,
1994:ANTIC TO (SUPDAT)
Effects of Overexposure:HLTH HAZ:EPINEPHRINE IN LAB ANIMALS & COULD
HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY
BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS
ACUTELY OR CHRONICALLY EXPOS ED TO CHLOROCARBONS .
Medical Cond Aggravated by Exposure:SOME SKIN CONDITIONS MAY BE
AGGRAVATED.
======================= First Aid Measures =======================
First Aid:INHAL:MOVE VICTIM TO FRESH AIR. RESTORE BREATHING IF
NECESSARY. CALL MD. INGEST:DO NOT INDUCE VOMITING. SKIN:FLUSH
W/WATER FOR 15 MINUTES. EYES:FLUSH W/WATER FOR AT LEAST 15 MINUTES.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:110F,43C
Lower Limits:13%
Upper Limits:23%
Extinguishing Media:WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESS DEMAND SCBA &
FULL PROT EQUIP . FORMS FLAMM VAP-AIR MIXTS AT TEMPS ABOVE AMBIENT.
LOWER TEMPS DECREASE IGNITABILITY.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE HCL & PHOSGENE .
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL SPILLS:MOP UP, WIPE UP OR SOAK UP
IMMEDIATELY. REMOVE TO OUT-OF-DOORS. LARGE SPILLS:EVACUATE AREA,
CONTAIN LIQUID, TRANSFER TO CLOSED METAL CONTAINERS. KEEP OUT OF
WATER SUPPLY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATHING VAPORS. STORE IN COOL
PLACES. VAPORS ARE HEAVIER THAN AIR & WILL COLLECT IN LOW AREAS.
Other Precautions:REMOVE CONTAINER CAP SLOWLY TO RELEASE PRESSURE. NO
SMOKING IS AREA OF USE. DO NOT USE IN GENERAL VICINITY OF ARC
WELDING, OPEN FLAMES OR HOT SURFACES. HEAT &/OR UV RADIATION MAY
CAUSE THE FORMATION O F HCL &/OR PHOSGENE .
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED AIR-PURIFYING RESPIRATOR
(SELF-CONTAINED BREATHING APPARATUS).
Ventilation:LOCAL EXHAUST: PREFERABLE. MECHANICAL (GENERAL):
ACCEPTABLE.
Other Protective Equipment:EMER EYE WASH AND DELUGE SHOWER WHICH MEETS
ANSI DESIGN CRITERIA .
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE AROUND PRODUCT. WASH
HANDS AFTER USE.
Supplemental Safety and Health
EXPLAN OF CARCIN:BE CARCINOGEN. ANIMAL:LUNGS, THORAX, ENDOCRINE SYSTEM.
EYE PROT:& FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:104F,40C
Vapor Pres:304
Vapor Density:2.93
Spec Gravity:1.03 (H*2O=1)
Evaporation Rate & Reference:5.5 (BUTYL ACETATE=1)
Solubility in Water:14%
Appearance and Odor:CLEAR TO OPAQUE LIQUID; PUNGENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALUMINUM, POSSIBLY SODIUM, POTASSIUM & MAGNESIUM.
Stability Condition to Avoid:HYDROLYSIS PRODUCING SMALL AMOUNTS OF
HYDROCHLORIC ACID POSSIBLE W/GROSS WATER CONTAMINATION.
Hazardous Decomposition Products:HCL, PHOSGENE . HEAT CAUSES THERMAL
DEGRADATION W/EVOLUTION OF HYDROCHLORIC ACID.
==================== Disposal Considerations ====================
Waste Disposal Methods:SEND TO RECLAIMER, PERMITTED INCINERATORS OR
EVAPORATE SMALL QUANTITIES I/A/W LOCAL, STATE & FEDERAL
REGULATIONS. DUMPING IS ILLEGAL.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: ENSTRIP N-122A, 2534 PART A
Kit Part: Y
Cage: GO075
Box: 1900
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: GO075
Box: 1900
Cage: 02258
Box: 1900
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: (ACUTE) INHAL: CAN CAUSE IRRITATION. INGEST: CAN CAUSE
IRRITATION TO MOUTH, THROAT, ESOPHAGUS AND STOMACH. SKIN: CAN CAUSE
IRRITATION. EYES: CAN CAUSE SEVERE IRRITATION. (CHRONIC) NAUSEA, VOMITING, DI
STURBANCES OF THE DIGESTIVE TRACT, CHROME SORES, BONE FLUOROSIS &
POSSIBLY OSTEOSCLEROSIS & LUNG CANCER.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE PERSON FROM CONTAM AREA. IF BRTHG STOPS, RESUSCITATE
& ADMINISTER OXYGEN IF AVAIL. CALL MD IMMED. INGEST:NEVER GIVE ANYTHING
BY MOUTH TO UNCON PERSON, OBTAIN MD IMMED. IF VOMIT OCCURS SPO NTANEOUSLY,
KEEP AIRWAY CLEAR. IF SWALLOWED, GIVE LRG AMTS OF WATER & INDUCE VOMIT.
CALL MD IMMED. SKIN:IMMED WASH CONTAM SKIN W/ PLENTY OF WATER FOR 15 MIN.
REMOVE CONTAM CLTHG & FOOTWEAR. (SUPP DATA
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AVOID CONTACT WITH SKIN, EYES & CLOTHING. WEAR
PROTECTIVE EQUIPMENT. SWEEP OR SHOVEL SPILLED MATERIAL INTO CLEAN PLASTIC
LINED CONTAINER AND COVER. FLUSH SPILL AREA WITH COPIOUS AMOUNTS OF WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY PLACE. KEEP AWAY FROM
ACIDS AND OXIDIZERS. LOOSEN COVER CAUTIOUSLY WHEN OPENING.
Other Precautions: FOR WASTE DISPOSAL OF OPERATING SOLUTIONS CONSULT
ENTHONE-OMI WASTE DISPOSAL PROCEDURES. FOR MAJOR SPILLS CONSULT ENTHONE-OMI
FOR DISPOSAL ASSISTANCE.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: WATER FOG OR SPRAY, FOAM.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: PRODUCT MAY SELF-SUSTAIN COMBUSTION IF IGNITED.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR WHEN AIR
CONCENTRATION IS GREATER THAN THE TLV OR PEL. USE CARTRIDGE FILTER FOR DUSTS.
Ventilation: LOCAL EXHAUST RECOMMENDED.
Other Protective Equipment: CHEMICALLY RESISTANT COVERALLS, HATS, AND SHOES OR
BOOTS. EMERGENCY EYEWASH AND SAFETY SHOWER SHOULD BE AVAILABLE.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: FIRST AID PROC: WASH CLOTHING BEFORE REUSE.
DISCARD FOOTWEAR IF IT CANNOT BE DECONTAMINATED. SEEK MD IMMEDIATELY. EYES:
FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, HOLDING LIDS APART
TO E NSURE FLUSHING OF ENTIRE SURFACE TO PREVENT OR RELIEVE IRRITATION. IF
IRRITATION PERSISTS, SEEK MD. KEY1:N1.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: C2
Solubility in Water: ESSENTIALLY COMPLETE
Appearance and Odor: LIGHT YELLOW POWDER WITH A FAINT ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Materials To Avoid: OXIDIZING AGENTS, ACIDS, ACID SALTS.
Hazardous Decomposition Products: NOX, SOX AND COX.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: ENSTRIP N-122A, 2534 PART A
Cage: GO075
Assigned IND: Y
Company Name: ENTHONE-OMI INC
PO Box: 1900
Zipcode: 06508
Label Required IND: Y
Date Of Label Review: 11/05/1991
Status Code: C
Label Date: 11/05/1991
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHALATION CAN CAUSE IRRITATION. SWALLOWING CAN
CAUSE IRRITATION TO MOUTH, THROAT, ESOPHAGUS, AND STOMACH. CAN CAUSE EYE AND
SKIN IRRITATION. CHRONIC EFFECTS: NAUSEA, VOMITING, DISTURBANCES OF THE
DIGESTIVE TRACT, CHROME SORES, BONEFLUOROSIS AND POSSIBLY OSTEOSCLEROSIS AND
LUNG CANCER.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:111 1756 KODAK K-LAB FIXER AND REPLENISHER, PROCESS K-14M
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:ETHYLENEDIAMINE-TETRAACETIC ACID (EDTA) (CERCLA)
CAS:60-00-4
RTECS #:AH4025000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
Fraction by Wt: 50-60%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 30-40%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMMONIUM SULFITE (CERCLA)
CAS:10196-04-0
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SODIUM BISULFITE (SASA III) (CERCLA)
CAS:7631-90-5
RTECS #:VZ2000000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SODIUM SULFITE
CAS:7757-83-7
RTECS #:WE2150000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: LOW HAZARD FOR RECOMMENDED
HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT
IRRITATION. SKIN: LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION:
EXPECTED TO BE A LOW INGESTION HA ZARD.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION-IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR. EYES-ANY MATERIAL THAT CONTACTS THE
EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL
ATTENTION IF SYM PTOMS OCCUR. SKIN-WASH WITH SOAP & WATER. GET
MEDCIAL ATTENTION IF SYMPTOMS OCCUR. INGESTED-DRINK 1-2 GLASSES OF
WATER. SEEK MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:USE WITH ADEUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. KEEP FROM CONTACT WITH OXIDIZING MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
Work Hygienic Practices:IT IS GOOD INDUSTRIAL HYGIENE PRACTICE TO
MINIMIZE EYE CONTACT. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
LOW HAZARD FOR RECOMMENDED HANDLING. KEEP OUT OF REACH OF CHILDREN.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:18 MMHG
Vapor Density:0.6 AIR=1
Spec Gravity:1.37
pH:6.2
Solubility in Water:COMPLETE.
Appearance and Odor:LIQUID, COLORLESS, ODORLESS.
Percent Volatiles by Volume:30-40
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, SODIUM HYPOCHLORITE, STRONG OXIDIZING AGENTS.
CONTACT WITH BASE LIBERATES FLAMMABLE MATERIAL.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AMMONIA, SULFUR DIOXIDE, CHLORAMINE
NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: 75-5410-9962-0, SCOTCHLITE GLASS BUBBLES, (SUP DAT)
Cage: 1BY21
=======================================================
Contractor Summary
=======================================================
Cage: 76381
Cage: 1BY21
=======================================================
Ingredients
=======================================================
Cas: 65997-17-3
% Wt: 97-100
OSHA PEL: 5 MG/M3 RESP DUST
ACGIH TLV: 10 MG/M3 (<7MICRONS)
------------------------------
Cas: 112945-52-5
RTECS #: VV7310000
% Wt: <3
OSHA PEL: 6 MG/M3
ACGIH TLV: 10 MG/M3
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: EYES: MECH IRRIT INCL IRRIT, REDNESS, SCRATCHING OF
CORNEA & TEARING. SKIN: MECH IRRIT INCL ITCH & REDNESS. INHAL: IRRIT
(UPPER RESP) INCL SORENESS OF NOSE & THROAT, COUGHING & SNEEZING.
WHILE THE FOLLOWING EFTS ARE ASSOC W/ONE OR MORE OF THE INDIVIDUAL INGS IN
THIS PROD & ARE REQUIRED TO BE (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: INCL ON MSDS BY U.S. OSHA HAZ
COMMUNICATION STD, THEY ARE NOT EXPECTED EFTS DURING FORESEEABLE USE OF PROD:
LUNG DMG INCL COUGHING, DFCLTY BRTHG, WHEEZING, TIGHTNESS IN CHEST,
CONGESTION, & COUGHING UP OF BLOOD. INGEST: IRRIT OF GI TISS INCL PAIN,
VOMIT, ABDOM TENDERNESS, NAUS, BLOOD IN VOMITUS & IN FECES.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. GET IMMEDIATE MEDICAL ATTENTION. SKIN: FLUSH WITH LARGE AMOUNTS OF
WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. IN HALATION: IF
SIGNS/SYMPTOMS OCCUR, REMOVE PERSON TO FRESH AIR. IF SIGNS/SYMPTOMS CONTINUE,
CALL MD. INGESTION: DRINK TWO GLASSES OF WATER. CALL MD.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REFER TO OTHER SECTIONS OF THIS MSDS FOR INFO
REGARDING PHYSICAL & HLTH HAZ, RESP PROT, VENT, & PERS PROT EQUIP.
CALL (612) 733-1110 OR (612) 733-6100 FOR 24-HR SPILL ASSIST. VENT AREA.
VACUUM, USE WE T SWEEPING CMPD/WATER TO AVOID DUSTING.(SUP DAT)
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISP OF WASTE PROD IN SANITARY LANDFILL. SINCE REGS
VARY, CONSULT APPLIC REGS/AUTH BEFORE DISP. IN THE EVENT OF AN UNCONTROLLED
RELEASE, THE USER SHOULD DETERMINE IF RELEASE QUALIFIES AS REPORTABLE QT Y.
DISP OF I/A/W LOC, STATE & FED REGS (FP N).
Handling And Storage Precautions: AVOID EYE AND SKIN CONTACT. AVOID INHALATION
OF DUST. DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
Other Precautions: USE IN WELL-VENTILATED AREA. KEEP CONTAINER DRY. KEEP
CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: NON-COMBUSTIBLE. CHOOSE MATERIAL SUITABLE FOR SURROUNDING
FIRE.
Fire Fighting Procedures: WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE
ANTICIPATED.
=======================================================
Control Measures
=======================================================
Respiratory Protection: SELECT ONE OF THE FOLLOWING NIOSH APPRVD RESPS BASED ON
AIRBORNE CONC OF CONTAMINANTS & I/A/W OSHA REGS: HALF-MASK DUST RESP,
HALF-MASK HIGH-EFFICIENCY FILTER RESP, HALF-MASK SUPPLIED AIR RESP, FULL-F
ACE DUST RESP, FULL-FACE HIGH- (SUP DAT)
Ventilation: USE W/APPROP LOC EXHST VENT. PROVIDE APPROP LOC EXHST VENT AT
TRANSFER POINTS. IF EXHST VENT IS NOT ADEQ, USE (SUP DAT)
Other Protective Equipment: EMERGENCY EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). WEAR COVERALLS, APRON.
Work Hygienic Practices: WASH EXPOSED AREAS THOROUGHLY WITH SOAP AND WATER. DO
NOT INGEST.
Supplemental Safety and Health: TRADE NAME/PART #: TYPES B, K, L & S. SPILL
PROC: CAUTION! VACUUM CLEANER COULD BE AN IGNIT SOURCE. PLACE IN APPRVD METAL
CONTR & SEAL. RESP PROT: EFFICIENCY FILTER RESP, FULL-FACE SUPPLIED AIR
RESP. VENT: APPROP NIOSH APPRVD RESP.
=======================================================
Physical/Chemical Properties
=======================================================
PH: BASIC
Solubility in Water: SLIGHT
Appearance and Odor: FINE POWDER (LESS THAN 10UM IN DIAMETER), WHITE, ODORLESS
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG ACIDS, STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: SILICON TETRAFLUORIDE WHEN DISSOLVED IN
HYDROFLUORIC ACID.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: 75-5410-9962-0, SCOTCHLITE GLASS BUBBLES, (SUP DAT)
Cage: 1BY21
Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
Zipcode: 55144-1000
Label Required IND: Y
Date Of Label Review: 11/04/1997
Status Code: C
Label Date: 11/04/1997
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYES: MECHANICAL IRRITATION INCLUDING
IRRITATION, REDNESS, SCRATCHING OF CORNEA AND TEARING. SKIN: MECHANICAL
IRRITATION INCLUDING ITCHING AND REDNESS. INHALATION: IRRITATION (UPPER
RESPIRATORY ) INCLUDING SORENESS OF NOSE AND THROAT, COUGHING AND SNEEZING.
INGESTION: IRRITATION OF GASTROINTESTINAL TISSUE. CHRONIC: NONE SPECIFIED BY
MANUFACTURER.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:AIRBRAKE ANTIFREEZE, HDAAHA
CAGE:0KDB2
CAGE:0KDB2
============= Composition/Information on Ingredients =============
Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 33%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM;250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ACETONE (SARA 313) (CERCLA). %:0.001 MAX.
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 0.001%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM;1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 1-3%
OSHA PEL:N/K
ACGIH TLV:50 PPM, VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SUPDAT:LIFTING LOWER & UPPER LIDS OCCAS. GET MED ATTN AS
SOON AS POSS. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4:AREA W/SOAP & WATER; APPLY SKIN LOTIONS. IF
IRRITATION PERSISTS, GET MEDICAL ATTENTION.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC:COMBUST CHAMBER. SPILLS IN SENSITIVE AREAS MAY
BE DILUTED & FLUSHED TO GROUND W/WATER SPRAY. DO NOT (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:FLUSH TO SEWER/OTHER CONFINED SPACE. SPILLS OF 5,000
LBS/MORE MUST BE REPORTED TO THE NRC (800-424-8802) (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7:PURSUANT TO CERCLA. WARN OCCUPANTS OF DOWNWIND AREAS.
RTECS #:9999999ZZ
Ingred Name:WASTE DISP METH:DISTILLATION PROCS. RCRA
REQUIREMENTS:METHANOL IS ASSIGNED HAZ WASTE NUMBER OF U154 UNDER
3001. (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:IT IS CONSIDERED A TOXIC WASTE.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:& VISUAL FUNCTIONS, LIVER & KIDNEY SYSTEMS.
PROVIDE SUITABLE TRAINING TO THOSE WORKING W/METHANOL. (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:MONITOR THE WORKPLACE. KEEP RECORDS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:METHANOL IS POIS, NARC CHEM THAT CAN
AFFECT BODY THRU INHAL, INGEST & PERHAPS PRLNG/RPTD SKIN CONT.
ABSORPTION BY INHAL/INGEST IS RAPID & EXCRETION IS MUCH SLOWER THAN
FOR ETHYL ALCOHOL, RESULTING IN DELAYED EFT/COMPOUNDING OF EFTS BY
RPTDEXPOS. IT IS IMPORTANT TO BE AWARE THAT AFTER INGEST/INHAL,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INITIAL SYMPS MAY BE ONLY THAT OF MILD
INTOX, BUT MAY BECOME SEV AFTER 12-18 HRS. TOX EFTS ARE EXERTED
UPON CNS, ESP OPTIC NERVE. INGEST CAN PRDCE BLINDNESS; 100-250 ML
CAN BE FATAL. SYMPS OF OVEREXP INCL DIZZ, VISUAL IMPAIRMENT, NAUS,
RESP FAILURE, MUSCULAR INCOORD & NARCOS. PRLNG/RPTD SKIN CONT MAY
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:GET MED ATTN IMMED. INDUCE VOMIT W/1 TBSP OF IPECAC/BY
TOUCHING BACK OF THROAT (ONLY IF CONSCIOUS). ONCE VOMIT HAS
OCCURRED, HAVE PATIENT DRINK MILK, WATER/SOLN OF SODIUM BICARBONATE
IN WATER ( 1 HEAPING TBSP PER QUART). INHAL:REMOVEVICTIM TO FRESH
AIR AT ONCE. RESTORE &/OR SUPPORT BRTHG AS REQD. KEEP VICTIM WARM &
AT REST. GET MED ATTN AS SOON AS POSS. PVNT EXPOS TO METHANOL FOR 7
(SUPDAT)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:60.0F,15.6C
Lower Limits:6.7%
Upper Limits:36.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM & WATER
MIST OR FOG. USE A BLANKETING EFFECT TO SMOTHER FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MODERATE EXPLOSION HAZARD & DANGEROUS
FIRE HAZARD WHEN EXPOSED TO HEAT, SPARKS OR FLAMES & CAN REACT
VIGOROUSLY W/OXIDIZING AGENTS.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL IGNIT SOURCES. PROVIDE ADEQ VENT.
SM QTYS MAY BE ABSORBED ON PAPER TOWELS. EVAPORATE IN SAFE PLACE
(SUCH AS FUME HOOD). BURN PAPER IN APPRVD INCIN/OPEN PIT AWAY FROM
BLDGS & PEOPLE. LG QTYS CAN BE COLLECTED & ATOMIZED IN SUITABLE
(ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:FLAMM LIQ. GROUND & ELECTRICALLY
INTERCONNECT CNTNRS FOR TRANSFER. USE SPARKPROOF TOOLS. NO SMOKING
IN AREA OF USE/STOR. AVOID CONTACT W/EYES.
Other Precautions:AVOID PRLNG/RPTD BRTHG OF VAP/CONT W/SKIN. DO NOT
INGEST! STORE IN WELL-VENTED, FIREPROOF AREA, AWAY FROM SOURCES OF
HEAT, OPEN FLAME & IGNIT. PROVIDE PREPLACEMENT MED EXAMS FOR
INDUSTRIALLY EXPOS WOR KERS, W/EMPHASIS ON NEUROLOGICAL(ING 11)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ANY NIOSH APPROVED AIR-SUPPLIED RESPIRATOR OR
SELF-CONTAINED BREATHING APPARATUS. ONLY NIOSH APPROVED EQUIPMENT
SHOULD BE USED.
Ventilation:LOC EXHST:TO MEET TLV REQUIREMENTS; 100 LFM MIN SHOULD BE
USED WHERE VAP EXPOS IS LIKELY. MECH (GEN):CONTROLS (SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . IMPERVIOUS APRONS & BOOTS WHERE SPLASHING CAN OCCUR.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHILE
HANDLING METHANOL.
Supplemental Safety and Health
% VOLAT:100(WT). EFTS OF OVEREXP:CAUSE DERM, ERYTHEMA, SCALING & POSS
SYSTEMIC EFTS. TOX DATA:INHAL:8600 MG/M3=LACRIM; COUGH; OTHER
CHANGES TO LUNGS, THORAX/RESP. VENT:MUST BE SPARKPROOF &
EXPLO-PROOF . EYE PROT:FULL LGTH FSHLD . FIRST AID PROC:DAYS.
EYES:WASH IMMED W/RUNNING WATER FOR AT LST 15 MINS, (ING 4)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:181F,83C
Melt/Freeze Pt:M.P/F.P Text:144F,62C
Vapor Pres:97 @ 68F
Vapor Density:1.1
Spec Gravity:0.807 (H*2O=1)
Evaporation Rate & Reference:5.9 (BUTYL ACETATE=1)
Solubility in Water:TOTALLY MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/CHARACTERISTIC PUNGENT
ALCOHOL ODOR.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS NITRATES, PERCHLORATES OR SULFURIC
ACID.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, OXIDIZING
CONDITIONS.
Hazardous Decomposition Products:TOXIC GASES & VAPORS (I.E., CARBON
MONOXIDE, FORMALDEHYDE) MAY BE RELEASED IN A METHANOL FIRE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS .
ABSORB IN VERMICULITE, DRY SAND, EARTH/SIMILAR MATL & DISP IN
SECURED SANIT LANDFILL. ATOMIZE IN SUITABLE COMBUST CHAMBER; DISP
OF VIA LICENSED WASTE S OLV DISP COMPANY/RECLAIM VIA FILTRATION&
(ING 9)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CORLAR EPOXY ENAMEL, BLUE HAZE, 823-8232
CAGE:19898
CAGE:18873
CAGE:19898
============= Composition/Information on Ingredients =============
Ingred Name:AROMATIC PETROLEUM DISTILLATE (AROMATIC BY ANALOGY TO
XYLENE)
Fraction by Wt: 5.0%
ACGIH TLV:100PPM(PER MFR)
Ingred Name:ETHER ALCOHOL
Fraction by Wt: 5.0%
ACGIH TLV:200PPM(PER MFR)
Ingred Name:ALIPHATIC ALCOHOL
Fraction by Wt: 4.0%
ACGIH TLV:50 PPM(PER MFR)
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 14.0%
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:BARIUM (SARA III)
CAS:7440-39-3
RTECS #:CQ8370000
Fraction by Wt: 15.0%
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG/M3; 9192
===================== Hazards Identification =====================
Effects of Overexposure:CAUSES HEADACHE,NAUSEA,IMPAIRMENT OF REACTION
TIME AND COORDINATION.
======================= First Aid Measures =======================
First Aid:INHALATION:MOVE TO FRESH AIR TO IMPROVE BREATHING;SKIN:WASH
WITH SOAP & WATER.REMOVE CONTAMINATED CLOTHING;EYES:FLUSH WITH
WATER FOR AT LEAST 15 MIN.CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:73-100F -(C.C.)
Lower Limits:1.0
Upper Limits:18.0
Extinguishing Media:CO*2, FOAM, DRY CHEM.
Fire Fighting Procedures:COOL CLOSED CONTNRS W/H*2O USING FOG NOZZLES
TO AVOID PRESSR
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION
SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM
FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL
ABSORBENT,SHOVEL INTO METAL DRUMS:LG SPILL:DI KE W COMMERCIAL
ABSORBENT,PUMP INTO COVERED DRUMS.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FORM HEAT,SPARKS & OPEN
FLAMES.CLOSE CONTAINERS AFETER EACH USE.DO NOT STORE ABOVE
120F;AVOID PROLONGED SKIN CONTACT.
Other Precautions:WASH THROUGHLY AFTER HANDLING AND BEFORE EATING OR
SMOKING;OBSERVE LABEL PRECAUTIONS;CONTAINERS SHOULD BE GROUNDED
WHEN POURING;USE NON-SPARKING TOOLS TO REMOVE SPILL;AVOID BREATHING
VAPORS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE CARTRIDGE-TYPE RESP IAW MFR DIRCTION IF AIR
CONTMNTS UNCONTRLABL
Ventilation:LOCAL & MECH PROVIDE SUFFICIENT VENT TO KEEP BELOW TLV
LEVEL
Other Protective Equipment:USE APPROPRIATE INDUSTRIAL HYGIENE
PRACTICES.
Supplemental Safety and Health
MSDS FM MFR DATED:11/12/65;VAP PRESSURE/DENSITY NOTED OF PRINCIPAL
SOLVENT;NIOSH 6:OF7525000,LEAD, CAS #7439-92-1, 0.05%,TLV
0.15MG/CUM;NIOSH 7:1001434AU,AQUEOUS SOLUTION *SEE ADDL DATA*
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:212-374F
Vapor Pres:10
Vapor Density:3.7
Spec Gravity:1.506
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:APPRECIABLE
Appearance and Odor:BLUE,SEMI-VISCOUS LIQUID;STRONG SOLVENT ODOR.
Percent Volatiles by Volume:50.8
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, CORROSIVES
Stability Condition to Avoid:HEAT, IGNITION SOURCES
Hazardous Decomposition Products:CO,CO*2,SMOKE AND OXIDES OF LEAD &
BARIUM.
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:38 CLEAR FINISH GLOSS, H 24
CAGE:77359
CAGE:77359
============= Composition/Information on Ingredients =============
Ingred Name:VENT: LIMITS WHICH MAY BE LISTED IN INGREDS SECTION. REFER
TO INDUSTRIAL VENTILATION; A MANUAL FOR RECOMMENDED (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: PRACTICE-AMERICAN CONFERENCE OF GOVERNMENTAL
INDUSTRIAL HYGIENISTS.
RTECS #:9999999ZZ
Ingred Name:ING 9: AND GUIDELINE, AMERICAN INDUSTRIAL HYGIENE ASSOC."
RTECS #:9999999ZZ
Ingred Name:NAPHTHA, MEDIUM ALIPHATIC, VP: 20
CAS:64742-88-7
Fraction by Wt: 65%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
Ingred Name:SUPP DATA: REQUIRED FOR OVEREXPOSURE SHOULD BE DIRECTED AT
CONTROL OF SYMPTOMS AND CLINICAL CONDITIONS.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC: ABSORB. USE ONLY NON-SPARKING TOOLS. PLACE
ABSORB DIKING MATLS IN COVERED METAL CNTNRS FOR DISP. PVNT(ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3: CONTAMINATION OF SEWERS, STREAMS, AND GROUNDWATER
WITH SPILLED MATERIAL OR USED ABSORBENT.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC: IS NOT A PRESSURE VESSEL.
RTECS #:9999999ZZ
Ingred Name:RESP PROT: AREAS A NIOSH/MSHA APPRVD CHEM CARTRIDGE RESP
MAY BE REQD. UNDER CERTAIN CNDTNS, SUCH AS SPRAYING, A (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:NIOSH/MSHA APPRVD MECH PREFILTER MAY ALSO BE REQD. IN
CONFINED AREAS USE A NIOSH/MSHA APPRVD AIR SUPP RESP.(ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: IF TLV'S LISTED IN INGREDS SECTION ARE EXCEEDED, USE
A NIOSH/MSHA APPRVD PROPERLY FITTED RESP W/APPROP (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: PROT FACTOR. REFER TO OSHA 29CFR 1910.134
"RESPIRATORY PROTECTION" AND "RESPIRATORY PROTECTION A MANUAL (ING
10)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST: CAN CAUSE
GASTROINTESTINAL IRRITATION, NAUSEA, AND VOMITING. ASPIRATION OF
MATERIAL INTO LUNG MAY CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE
FATAL. INHALATION: MAY CAUSE NOSE OR THROAT IRR ITATION. HIGH
CONCENTRATIONS MAY CAUSE ACUTE CENTRAL NERVOUS SYS DEPRESSION
CHARACTERIZED BY HEADACHES,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DIZZINESS, NAUSEA AND CONFUSION. EYE;
MAY CAUSE EYE IRRITATION. SKIN: MAY CAUSE DEFATTING AND IRRIT OF
SKIN. CHRONIC: REPORTS HAVE ASSOCIATED PROLONGED AND REPEATED
OCCUPATIONAL OVEREXP TO S OLVENTS WITH PERMANENT BRAIN AND NERVOUS
SYSTEM DMG. INTENTIONAL MISUSE BY DELIB CONC/INHAL CONT MAY BE
HARMFUL/FATAL.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: DO NOT INDUCE VOMIT. CALL POIS CNTRL CENTER, HOSPITAL
EMER ROOM/PHYS IMMED. INHAL: REMOVE TO FRESH AIR IMMED. IF BRTHG
HAS STOPPED, GIVE ARTF RESP. KEEP WARM/QUIET. GET MED ATTN IMMED.
EYE: FL USH W/LRG AMTS OF H*2O FOR AT LEAST 15 MIN, LIFTING
UPPER/LOWER LIDS OCCASIONALLY. GET MED ATTN. SKIN: REMOVE CONTAM
CLTHG. WASH AFFECTED AREAS W/SOAP/H*2O. OBTAIN MED ATTN IF IRRIT
(SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:103F,39C
Extinguishing Media:USE NFPA CLASS B FIRE EXTING (CO*2, ALL PURPOSE DRY
CHEM/ALCOHOL FOAM)DESIGNED TO EXTING FLAM LIQ FIRES. (SUPP DATA)
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT
EQUIP.H*2O MAY BE INEFT, BUT MAY BE USED TO COOL EXPOS CNTNRS TO
PVNT PRESS BUILD-UP & POSS AUTO-IGNIT/ (SUPP DATA)
Unusual Fire/Explosion Hazard:DURING EMER CNDTNS, OVEREXP TO DECOMP
PRODS MAY CAUSE HLTH HAZ. SYMP MAY NOT BE IMMED APPARENT. OBTAIN
MED ATTN. KEEP CNTNRS TIGHTLY CLSD. ISOLATE (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP SPECTATORS AWAY. ELIMINATE ALL IGNIT
SOURCES (FLAMES, HOT SURFS, & SOURCES OF ELEC, STATIC/FRICTIONAL
SPARKS). DIKE/CONT SPILL W/INERT MATL (E.G. SAND, EARTH). TRANSFER
LIQ TO COVERED METAL CNTNR S FOR RECOVERY/DISP, OR REMOVE W/INERT
(ING 3)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 115F (45C). STORE
LARGE QUANTITIES IN COMPLIANCE WITH OSHA 29 CFR 1910.106.
Other Precautions:DO NOT TAKE INTERNALLY. CLOSE CNTNR AFTER EACH USE.
EMPTY CNTNRS MUST NOT BE WASHED &RE-USED FOR ANY PURPOSE. CNTNRS
SHD BE GROUNDED/BONDED TO RECEIVING CNTNR.DO NOT WELD, BRAZE/CUT ON
EMPTY CNTNR. NE VER USE PRESS TO EMPTY. DRUM (ING 5)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:PROPER SELECTION OF RESP PROT DEPENDS UPON MANY
FACTORS INCLG DURATION/LEVEL OF EXPOS/CNDTNS OF USE. IN GEN EXPOS
TO ORG CHEM SUCH AS THOSE CONT IN PROD MAY NOT REQ USE OF RESP PROT
IF USED IN WELL VE NT AREAS. IN RESTRICTED VENT (ING 6)
Ventilation:PROVIDE LOC EXHST VENT IN SUFF VOL/PATTERN SO AS TO
MAINTAIN EXPOS BELOW NUISANCE DUST LIMITS& PERMISSIBLE EXPOS(ING
11)
Other Protective Equipment:NOT LIKELY TO BE NEEDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA: POLYMER FOAM IS PREFERRED FOR LRG FIRES. FIRE FIGHT PROC:
EXPLO WHEN EXPOS TO EXTREME HEAT. IF H*2O IS USED, FOG NOZ
PREFERABLE. EXPLO HAZ: FROM HEAT, ELEC EQUIP, SPARKS/FLAME. CLSD
CNTN RS MAY EXPLO WHEN EXPOS TO EXTREME HEAT. FIRST AID PROC:
PERSISTS. NOTES TO PHYS: ANY TREATMENT THAT MIGHT BE (ING 2)
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:302F,150C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:0.9
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:74
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:EXCESSIVE HEAT (>115F (46C)), SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISP I/A/W FED, STATE & LOCAL LAWS. INCINERATE
ONLY IN EPA PERMITTED FACILITY. DO NOT INCINERATE CLSD CNTNRS.
OBSERVE PREC FOR DISP OF FLAM MATLS. CONTAM ABSORB MAY BE DISP IN
HAZ WASTE LANDFILL. DISP ONLY I/A/W FED, STATE, AND LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HYDRAZINE REAGENT B, 259
CAGE:24774
CAGE:24774
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL; (IPA) (SARA III). FP: 53F,11.7C.
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:400 PPM;500 PPM STEL
ACGIH TLV:400 PPM;500 PPM STEL
Ingred Name:HYDROGEN CHLORIDE; (HYDROCHLORIC ACID) (SARA III)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 11-15%
OSHA PEL:5 PPM, C
ACGIH TLV:5 PPM, C
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SEVERE IRRIT TO SKIN. SEVERE
IRRIT TO EYES, POSS CORR. VAPS, GASES, MISTS AND/OR AEROSOLS CAUSE
IRRIT TO UPPER RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE
DIZZINESS AND HEADACHE. CHRONIC: P ROLONGED OR REPEATED
OVEREXPOSURE MAY CAUSE LIVER AND KIDNEY TOXICITY AND MAY CAUSE
DEFATTING-TYPE DERMATITIS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:EXCESSIVE DERMAL EXPOSURE CAUSES DEFATTING AND
DRYING OF SKIN; EXCESSIVE INHALATION OF VAPOR CAUSES DIZZINESS,
HEADACHE AND NAUSEA.
Medical Cond Aggravated by Exposure:NOT KNOWN.
======================= First Aid Measures =======================
First Aid:SKIN: REMOVE CONTAMD CLTHG. WASH EXPOS AREA W/LRG QTY OF SOAP
SOLN/WATER FOR 15 MINS. EYE: IMMED FLUSH W/WATER FOR AT LST 15
MINS. IMMED CONT PHYS FOR ADDNL TREATMENT. INHAL: REMOVE VICTIM
FROM CONTAM D AREA TO FRESH AIR. APPLY APPROP FIRSTAID TREATMENT AS
NEC. INGEST: GEN: DO NOT FEED ANYTHING BY MOUTH TO AN UNCON/CONVUL
VICTIM. SPECIFIC: DO NOT INDUCE VOMIT. IMMED CONT PHYS. DILUTE
(SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point:ING 1
Extinguishing Media:FLAM LIQ. DRY CHEM, CARBON DIOXIDE,OR FOAM. WATER
SPRAY SHOULD BE USED ONLY TO COOL FIRE-EXPOS CNTNRS & DISPERSE
VAPS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:GEN:VENT AREA,USE SPECIFIED PROT EQUIP.CONTAIN
& ABSORB ON ABSORB MATL.PLACE IN WASTE DISP CNTNR.WASTE CHARACT OF
ABSORB MATL/ANY CONTAMD SOIL,SHOULD BE DETERM I/A/W RCRA REGS.
SPECIFIC: REMOVE IGNITI ON SOURCES. FLUSH AREA W/WATER. SPREAD
SAND/GRIT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNR CLSD WHEN NOT IN USE. KEEP
AWAY FROM FLAMES/SPARKS. BOND CNTNRS DURING FILLING OR DISCHARGE
WHEN PERFORMED AT TEMPS AT/ABOVE PROD FL PT.
Other Precautions:FLAMMABLE. CORROSIVE TO SKIN AND EYES. STORE IN
EXPLOSIVE PROOF AREA WHERE ELECTRICAL EQUIPMENT MEETS NFPA CODE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE PROT EQUIP I/A/W 29 CFR SEC 1910.132-134.
USE NIOSH/MSHA APPRVD RESP W/IN USE LIMITATIONS/ELSE USE NIOSH/MSHA
APPRVD SUPP AIR RESP. IF VENT IS INADEQ/SIGNIFICANT REAGENT EXPOS
IS LIKELY, USE NIOSH /MSHA APPRVD RESP W/ORG VAP CARTRIDGES.
Ventilation:ADEQUATE VENTILATION TO MAINTAIN AIR CONTAMINANTS BELOW
EXPOSURE LIMITS.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER .
NECESSARY.
Supplemental Safety and Health
PH: 0.9 (AS IS). FIRST AID PROCEDURES: CONTENTS OF STOMACH USING 3-4
GLASSES MILK OR WATER.
================== Physical/Chemical Properties ==================
HCC:F6
Spec Gravity:0.840
pH:SUPDAT
Evaporation Rate & Reference:<1 (ETHER=1)
Solubility in Water:100%
Appearance and Odor:COLORLESS LIQUID, ALCOHOL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS. CORROSIVE TO STEEL.
Stability Condition to Avoid:CONTAMINATION.
Hazardous Decomposition Products:THERMAL DECOMPOSITION (DESTRUCTIVE
FIRES) YIELDS ELEMENTAL OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:GEN:WATER CONTAMINATED W/REAGENT MAY BE SENT TO
SANITARY SEWER, I/A/W ANY FED, ST,& LOC AGREEMENT, A TREATMENT
FACILITY OR DISCHARGED UNDER NPDES PERMIT. REAGENT (AS IS): INCIN
OR BURY IN APPROVED LAN DFILL I/A/W FEDERAL, STATE, AND LOCAL REGS
.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:(3:1) CAT, MIL-C-85285B, 36495 PC 03GY340CA
Kit Part:Y
Preparer's Name:NORM GAUL
CAGE:5M511
CAGE:33461
CAGE:5M511
============= Composition/Information on Ingredients =============
Ingred Name:ALIPHATIC ISOCYANATE (HEXAMETHYLENE DIISOCYANATE [HDI] CAS:
822-06-0; FREE MONOMER CONTENT <.5%)
CAS:28182-81-2
RTECS #:HQ9170000
Fraction by Wt: 35%
Other REC Limits:MOBAY:CEILING.02 PPM
ACGIH TLV:TWA: 0.005 PPM
Ingred Name:ALIPHATIC ISOCYANATE(HEXAMETHYLENE DIISOCYANATE [HDI]
CAS:822-06-0;FREE MONOMER<.5% @MFR.AFTER3-6 MOS MAY RISE 1.6% MAX)
CAS:28182-81-2
RTECS #:HQ9170000
Fraction by Wt: 40%
Other REC Limits:MOBAY:CEILING.02 PPM
ACGIH TLV:TWA: 0.005 PPM
Ingred Name:C8&10 AROMATIC HYDROCARBON (VAPOR PRESSURE 3 MM HG @ 68F)
CAS:64742-95-6
Fraction by Wt: <5%
Other REC Limits:PEL: 100 PPM
Ingred Name:N-BUTYL ACETATE (VAPOR PRESSURE 13 MM HG @ 68F)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:150 PPM/STEL 200 PPM
ACGIH TLV:150 PPM/STEL 200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHYL 3-ETHOXYPROPIONATE (VAPOR PRESSURE .7 MM HG @ 68F)
CAS:763-69-9
RTECS #:UF3325000
Fraction by Wt: 20%
Other REC Limits:50 PPM/STEL 100 PPM
Ingred Name:VOC: 282 G/L
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE; IRRITATING TO EYES, NOSE &
THROAT. INHAL: HEADACHES, DIZZINESS, STAGGERING, DIFFICULT
BREATHING, CONFUSION, UNCONSCIOUSNESS, COMA. SKIN: IRRITATING
(SWELLING, REDNESS, RASH). EYES: IRRIT (TEARI NG, REDNESS, SWELLING
W/STINGING). INGEST: IRRITATION, CORROSIVE TO GI TRACT. ASPIRATION
(VOMITING)-CHEMICAL PNEUMONITIS
Effects of Overexposure:CHRONIC; AS A RESULT OF PREVIOUS REPEATED
OVEREXPOSURE OR A SINGLE LARGE DOSE, CERTAIN INDIVIDUALS WILL
DEVELOP ISOCYANATE SENSITIZATION WHICH WILL CAUSE THEM TO REACT TO
A LATER EXPOSURE OF ISOCYANAT E LEVELS WELL BELOW THE TLV VALUE OF
ISOCYANATES.
Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY
DISORDERS. SKIN ALLERGIES, ECZEMA AND DERMATITIS. ISOCYANATE
SENSITIZATION.
======================= First Aid Measures =======================
First Aid:INHAL: MOVE TO FRESH AIR. RESTORE BREATHING. ASTHMATIC TYPE
SYMPTOMS MAY DEVELOP (IMMED/DELAYED). GET MED AID. SKIN: REMOVE
CONTAMINATED CLOTHING. WASH AFFECTED AREAS WITH SOAP & WATER. WASH
CONTAMINA TED CLOTHES BEFORE REUSE. EYES: FLUSH WITH LUKEWARM WATER
(LOW PRESSURE) 15 MIN, LIFTING EYELIDS. GET MED AID. INGEST: DONT
INDUCE VOMITING. DO NOT GIVE ANYTHING TO AN UNCONSCIOUS PERSON. GET
MED AID.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:76.0F,24.4C
Lower Limits:1.00
Upper Limits:7.60
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG
Fire Fighting Procedures:USE FULL PROTECT CLOTH/FIREFIGHT EQUIP W/
SCBA. WATER MAY BE USED TO COOL CLSD CNTNRS (PREVENT PRESS
BLDUP/AUTOIGNIT/ EXPLOS). HDI/IRRIT VAPOR GENERATED BY FIRE
Unusual Fire/Explosion Hazard:KEEP CNTNR CLSD. KEEP FROM HEAT/IGNIT
SOURCE. CLSD CNTNR MAY EXPLODE W/HEAT. APPLIC TO HOT SURFACE REQ
SPECIAL PRECAUTION. OVEREXPOSURE TO DECOMP PROD-HLTH HZD.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES).
VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND
NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN BUILDINGS IN COMPLIANCE WITH
OSHA 1910.106. AVOID STORING NEAR HIGH TEMPS/IGNITION SOURCE. STORE
IN CLOSED CONTAINER IN WELL VENTILATED AREA.
Other Precautions:KEEP CNTNR TIGHT/UPRIGHT (PREVENT LEAK). PREVENT
PROLONG VAPOR BREATHING. PROLONG OVEREXPOSURE MAY CAUSE ALLERGIC
REACTION.AVOID CONTACT W/SKIN & EYES. DONT INGEST.DONT HANDLE TILL
MFR PRECAUTIONS REA D/UNDERSTOOD. SMOKE IN SMOKE AREAS ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE RESPIRATOR RECOMMENDED FOR USE IN ORGANIC
VAPOR ENVIRONMENT (AIR PURIFYING/FRESH AIR SUPPLIED). OBSERVE OSHA
RESPIRATOR REGULATIONS.VAPOR PARTIC RESPIRATOR (TC23C) MAY BE USED
WHEN AIR MONITORING SHOWS VAPOR LEVELS BELOW 10X TLV/PEL.
Ventilation:EXHAUST VENT TO KEEP AIRBORNE CONCENTRATION
(HDI,POLYISOCYANATES, SOLVENT) BELOW TLVS. REMOVE IGNITION SOURCES.
Other Protective Equipment:THE USE OF LONG SLEEVE AND LONG LEG CLOTHING
RECOMMENDED. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
Work Hygienic Practices:WASH HANDS BEFORE EATING, SMOKING OR USING
WASHROOM.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F5
Boiling Pt:B.P. Text:260 TO 338F
Vapor Density:> AIR
Spec Gravity:0.95198
Evaporation Rate & Reference:0.15 X N-BUTYL ACETATE
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR
Percent Volatiles by Volume:26.5
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH
REACT WITH ISOCYANATES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CARBON
MONOXIDE, CARBON DIOXIDE, AND OXIDES OF NITROGEN, TRACES OF HCN AND
HDI.
Conditions to Avoid Polymerization:CONTACT WITH MOISTURE, MATERIALS
WHICH REACT WITH ISOCYANATES AND HIGH TEMPERATURES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST BE
HANDLED WITH CARE, DUE TO PRODUCT RESIDUE & FLAMMABLE VAPOR. DONT
INCINERATE CLOSED CONTAI NER. EPA HZD WASTE #: D001, F003,
F005,IGNITABLE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SUNOCO ULTRA GL5 80W-90
Preparer's Name:MARIA DAYRIT
CAGE:IK762
CAGE:78628
CAGE:IK762
============= Composition/Information on Ingredients =============
Ingred Name:SOLVENT-REFINED RESIDUUM, REFINED PETROLEUM OILS *96-4*
CAS:64742-01-4
Fraction by Wt: 60%
Ingred Name:OLEFIN SULFIDE
CAS:72162-26-6
Fraction by Wt: 5%
Ingred Name:AMINES, POLYETHYLENEPOLY-, REACTION PRODUCTS W/SUCCINIC
ANHYDRIDE POLYISOBUTENYL DERIVS
CAS:84605-20-9
Fraction by Wt: 1-5%
Ingred Name:AMINES, C12-14-TERT-ALKYL, REACTION PRODUCTS WITH
O,O-DI-C1-14-ALKYL HYDROGEN PHOSPHORODITHIOATE
CAS:71888-91-0
Fraction by Wt: 1-5%
Ingred Name:1-PROPENOIC ACID, 2-METYL-, EICOSYL ESTER, POLYMER *96-4*
CAS:68171-46-0
Fraction by Wt: 1%
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED HEAVY
PARAFFINIC, LUBRICATING OIL BASE STOCK
CAS:64741-88-4
RTECS #:PY8040500
Fraction by Wt: 30-50%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(LAB ANIMAL): >15 G/KG
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: MINIMAL IRRITATION.
SULFURIZED OLEFIN: IRRITATION TO EYES, NOSE & THROAT; CNS EFFECTS &
DEATH. SKIN/EYES: IRRITATION. INGESTION: SLIGHTLY TOXIC. ALKYLAMINE
SALT OF DITHIOPHOSPHORIC ACID: CA N CAUSE RESPIRATORY PARALYSIS &
DEATH.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION. SULFURIZED OLEFIN: IRRITATION,
DIZZINESS, LOSS OF BALANCE & COORDINATION, RESPIRATORY FAILURE.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS,
RESPIRATORY, PULMONARY & LUNG DISORDERS, ASTHMA-LIKE CONDITIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH W/SOAP & WATER
UNTIL NO ODOR REMAINS. EYES: FLUSH W/WATER. INGESTION: INDUCTION OF
VOMITING NOT REQUIRED. SMALL AMOUNTS SHOULD BE RINSED OUT UNTIL
TASTE IS GONE. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>350F
Extinguishing Media:WATER SPRAY, REGULAR FOAM, DRY CHEMICAL, CO2.
Fire Fighting Procedures:WEAR SCBA. WEAR STRUCTURAL FIRE FIGHTERS
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:CAN BE MADE TO BURN (FLASHPOINT >200F).
AUTOIGNITION TEMP: 695F.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN. USE PROTECTIVE EQUIPMENT. ABSORB ON
INERT MATERIAL. SHOVEL, SWEEP/VACUUM AREA.
======================Handling and Storage ======================
Handling and Storage Precautions:USE NFPA CLASS IIIB STORAGE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH CERTIFIED HALF MASK AIR PURIFYING
RESPIRATOR W/DUST/MIST FILTERS/HEPA FILTER CARTRIDGES UP TO 10
TIMES EXPOSURE LIMIT/FULL FACE AIR PURIFYING RESPIRATOR W/DUST/MIST
FILTERS/HEPA FILTER CARTRIDGE S UP TO 50 TIMES EXPOSURE LIMIT.
(SUPP)
Ventilation:GENERAL DILUTION IS ACCEPTABLE.
Other Protective Equipment:POLYVINYL ALCOHOL, VITON. CHEMICAL RESISTANT
CLOTHING.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
AIR PURIFYING RESPIRATORS IS LIMITED. USE A POSITIVE PRESSURE DEMAND
FULL FACE SUPPLIED AIR RESPIRATOR/SCBA FOR EXPOSURES >50X THE
EXPOSURE LIMIT/A POSITIVE PRESSURE DEMAND FULL FACE SUPPLIED AIR
RESP IRATOR W/ESCAPE BOTTLE/SCBA.
================== Physical/Chemical Properties ==================
Vapor Pres:<0.0001
Vapor Density:>10
Spec Gravity:0.89
Evaporation Rate & Reference:(ETHYL ETHER = 1): <1000
Solubility in Water:0
Appearance and Odor:AMBER VISCOUS LIQUID W/SLIGHT ODOR
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Hazardous Decomposition Products:COMBUSTION: CO & ASPHYXIANTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T FLUSH TO DRAIN/STORM SEWER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:THINNER & REDUCERS, 441-01
CAGE:EO716
CAGE:18873
CAGE:EO716
============= Composition/Information on Ingredients =============
Ingred Name:SOLVENT NAPHTHA; (AROMATIC HYDROCARBON-2). VP:10 @ 20C.
CAS:64742-94-5
RTECS #:WF3100000
Other REC Limits:100 PPM (MFR)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:2-BUTOXYETHANOL; (ETHYLENE GLYCOL MONOBUTYL ETHER). VP:0.6
@ 20C.
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 2%
OSHA PEL:50 PPM, S
ACGIH TLV:25 PPM, S
Ingred Name:ISOPROPYL ALCOHOL (SARA 313). VP:33 @ 20C.
CAS:67-63-0
RTECS #:NT8050000
OSHA PEL:400 PPM
ACGIH TLV:400 PPM;500 STEL
Ingred Name:SOLVENT NAPHTHA (PETROLEUM) MEDIUM ALIPHATIC; (MEDIUM
MINERAL SPIRITS)
CAS:64742-88-7
Other REC Limits:100 PPM (MFR)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DIBASIC ESTER; (MIXED DIBASIC ESTERS). VP:0.2 @ 20C.
Other REC Limits:10 MG/M3 (MFR)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TOLUENE (SARA 313) (CERCLA). VP:38.7 @ 20C.
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 11%
OSHA PEL:200 PPM
ACGIH TLV:50 PPM, S
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGEST:GI DISTRESS. INHAL:MAY CAUSE
NOSE & THROAT IRRIT. RPTD & PRLNG OVEREXP TO SOLVS MAY LEAD TO PERM
BRAIN & NERV SYS DMG. EYE WATERING, HDCHS, NAUS, DIZZ & LOSS OF
COORD ARE SIGNS THAT SOLV LEVELS ARE TOO HIGH. EYE CONT:MAY CAUSE
IRRIT/BURNING. SKIN:RPTD/PRLNG LIQ CONT MAY CAUSE IRRIT
W/DISCOMFORT & DERM. INGS 1 & 4:LAB STUDIES W/RATS HAVE SHOWN THAT
PETRO DISTILS CAUSE KIDNEY DMG & KIDNEY/LIV ER TUMORS. SEVERAL
STUDIES EVAL PETRO WORKERS HAVE NOT SHOWN SIGNIFICANT INCR OF
KIDNEY DMG/INCR IN KIDNEY/LIVER TUMORS. ING 2:CAN BEABSORBED THRU
SKIN IN HARMFUL AMTS. MAY CAUSE INJURY TO KIDNEYS, LI VER,(EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: BLOOD &/OR BONE MARROW. RPTD OVEREXP
MAY RSLT IN DMG TO BLOOD. EYE CONT MAY CAUSE CORNEAL INJURY. HAS
BEEN TOX TO FETUS IN LAB ANIMALS AT DOSES THAT ARE TOX TO MOTHER.
ING 3:INGEST STUDIES O N LAB ANIMALS SHOWED THAT VERY HIGH ORAL
DOSES CAUSED INCR LIVER & KIDNEY WTS. ING 4: MAY CAUSE TEMPORARY
UPPER RESP &/OR LUNG IRRIT W/COUGH, DFCLT BRTHG/SHORTNESS OF
BREATH. ING 5:HIGH AIRBORNE LEVEL S IN RATS HAVE SHOWN MILD INJURY
TO OLFACTORY REGION OF NOSE. ING 6:RECURRENT OVEREXP MAY RSLT IN
LIVER & KIDNEY INJURY. HIGH AIRBORNE LEVELS HAVE PRDCD IRREG
HEARTBEATS IN ANIMALS & OCCAS PALPITATION S IN HUMANS. RATS EXPOS
TO VERY(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY & HAVE NAMES OF INGREDIENT
AVAILABLE. INHAL:REMOVE TO FRESH AIR. IF BREATHING DIFFICULTY
PERSISTS, OR OCCURS LATER, CONSULT MD. EYES:FLUSH W/PLENTY OF WATER
FOR AT LEAST 15 MINUTES; CALL MD. SKIN:WASH W/SOAP & WATER. IF
IRRITATION OCCURS, CONTACT MD.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>20F,>-7C
Lower Limits:0.8%
Upper Limits:19%
Extinguishing Media:WATER SPRAY, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER FROM FOG NOZZLES MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD-UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASH POINT, EMITS
FLAMM VAPS WHICH, WHEN MIXED W/AIR, CAN BURN/BE EXPLO. FINE
MISTS/SPRAYS MAY BE FLAMM AT TEMPS BELOW FLASH POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT & BREATHING OF VAPOR. WEAR A PROPERLY FITTED
NIOSH/MSHA APPROVED VAPOR/PARTICULATE RESPIRATOR (TC-23C). CONFINE
& REMOVE W/INERT ABSORB ENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:OSHA STORAGE:1B. DO NOT BREATHE VAPORS
OR MISTS. OBSERVE LABEL PRECAUTIONS. KEEP AWAY FROM HEAT, SPARKS &
FLAME. CLOSE CONTAINER AFTER EACH USE.
Other Precautions:GROUND CONTAINERS WHEN POURING. DO NOT STORE ABOVE
120F. DO NOT SAND, FLAME CUT, BRAZE OR WELD DRY COATING W/OUT A
NIOSH/MSHA APPROVED RESPIRATOR OR APPROPRIATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR PROPERLY FITTED NIOSH/MSHA APPRVD
VAP/PARTICULATE RESP FOR USE W/PAINT DURING APPLICATION & UNTIL ALL
VAPS & SPRAY MISTS ARE EXHAUSTED. IN ALL CASES, FOLLOW RESP MFR'S
DIRECTIONS FOR RESP USE. DO NOT PERMIT ANYONE W/OUT PROT IN
PAINTING AREA.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP
CONTAMINANTS BELOW APPLICABLE OSHA REQUIREMENTS.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . COVERALLS ARE RECOMMENDED.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING
OR SMOKING.
Supplemental Safety and Health
EFTS OF OVEREXP: HIGH AIRBORNE LEVELS HAVE EXHIBITED HIGH FREQENCY
HEARING DEFICITS. THE SIGNIFICANCE OF THIS TO MAN IS UNKNOWN.
WARNING:THIS CHEM IS KNOWN TO STATE OF CALIFORNIA TO CAUSE BIRTH
DEFECT S & OTHER REPRO HARM. ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC (OTHER INFO)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>129F,>54C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.79
VOC Grams/Liter:6.5
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MISCIBLE
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:76.1-100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO, CO*2, SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. INCINERATE ABSORBED MATERIAL I/A/W FEDERAL, STATE &
LOCAL REQUIREMENTS. DO NOT INCINERATE IN CLOSED CONTAINERS.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SUPER KOROPON PRIMER MMS-405 R-66, 513-721
CAGE:32758
CAGE:62758
CAGE:32758
============= Composition/Information on Ingredients =============
Ingred Name:LEAD CHROMATE (OSHA PEL FOR LEAD FROM 29CFR
1910.1025),(CRO3 CEILING 0.1 MG/M3)
CAS:7758-97-6
RTECS #:GB2975000
Fraction by Wt: <5.0%
OSHA PEL:0.05 MG/M3 (PB)
ACGIH TLV:0.05MG/M3(CR)A2;8990
Ingred Name:2-ETHOXYETHYL ACETATE (CELLOSOLVE ACETATE) (EGEEA)
CAS:111-15-9
RTECS #:KK8225000
Fraction by Wt: <5.0%
OSHA PEL:S,100 PPM
ACGIH TLV:S, 5 PPM; 9192
Ingred Name:N-BUTYL ACETATE (SARA III)
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 20%
OSHA PEL:150 PPM/200 STEL
ACGIH TLV:150 PPM/200STEL;9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 10%
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: <5.0%
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
===================== Hazards Identification =====================
Effects of Overexposure:INH:ANESTHETIC/RESP TRACT IRRIT/CNS DEPRESS
W/HDCH/DIZZ/UNCONS/COMA. SKIN/EYE:PRIMARY IRRIT.
======================= First Aid Measures =======================
First Aid:INH:MOVE FROM EXPOS/RESTORE BREATH/KEEP WARM/QUIET. SKIN:WASH
W/H*2O/REMOVE CONTAM CLTHNG. EYES:FLUSH W/H*2O 15 MINS. ING/ALL THE
ABOVE:CALL MD. REPRO/BLOOD DISORDERS/BIRTH DEFECTS OBS IN ANIMALS
W/2- ETHOXYETHYL ACETATE:OBS PRECAUTNS/AVOIDOVEREXPOS.
===================== Fire Fighting Measures =====================
Flash Point:22F,-5.6C CC
Lower Limits:1.7
Extinguishing Media:USE NFPA CLASS B EXTINGUISHERS:CO*2,DRY CHEMICAL OR
FOAM.
Fire Fighting Procedures:H*2O SPRAY POSS INEFFECT-USE FOG NOZZLE. COOL
CNTNRS W/H*2O.
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLD IF EXPSD TO EXTREME
HEAT. DO NOT APPLY TO HOT SURFACES. ISOLATE, CLOSE TIGHTLY
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS. VENTILATE AREA. REMOVE W/INERT ABSORBENT &
NON-SPARKING TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 120F,49C. STORE LRG
AMTS IN BLDGS DESIGNED FOR FLAM LIQ STORAGE. GROUND CNTNRS WHEN
POURING. AVOID FREE FALL OF LIQ > A FEW INCHES.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT SAND/FLAME
CUT/BRAZE/WELD THE DRY COATING W/O NIOSH APPRVD RESP OR APPROPRIATE
VENT. WASH CONTAMINATED CLTHNG BEFORE REUSE. OBSERVE PRECAUTIONARY
LABEL WARNINGS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPRVD RESP FOR EXPOSURE OF
CONCERN. SCBA DURING FIRE
Ventilation:GENERAL DILUTION OR LOCAL EXHAUST TO KEEP TLV BELOW LIMITS.
Other Protective Equipment:PROT CLTHNG SUCH AS BUTYL RUBBER APRON. SFTY
SHOWER/EYE BATH
Supplemental Safety and Health
ADDTNL INGRED:CALCIUM CHROMATE PIGMENT <5.0% 0.05MG/CUM AS CR. TALC(NON
ASBESTIFORM) 10% 2MG/CUM RESPIRABLE DUST. EPOXY RESIN 20%. TITANIUM
DIOXIDE 25% 5MG/CUM RESP DUST. VAP PRESS:2.0 TO 70.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:176-313F
Vapor Density:>1.0
Evaporation Rate & Reference:<1.0, ETHER
Percent Volatiles by Volume:57.8
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, ELECTRICAL EQUIP, SPARKS & OPEN
FLAME.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE HAZARDOUS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS. INCINERATE IN APPROVED FACILITY. DO NOT INCINERATE
CLOSED CONTAINERS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:OAKITE ENPROX 702
CAGE:44389
CAGE:44389
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 35-45%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:NON-HAZARDOUS INGREDIENTS.
Fraction by Wt: 55-65%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE EFFECTS OF OVEREXPOSURE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:INHALATION OF MIST MAY CAUSE RESPIRATORY
IRRITATION W/COUGHING, SNEEZING, SALIVATION & DIFFICULT BREATHING.
SEVERE EXPOSURES MAY LEAD TO CHEMICAL PNEUMONITIS. SEVERE SKIN
IRRITATION & BURNS. EYE CONTA CT CAUSES SEVERE OR PERMANENT DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMED FLUSH EYES W/LARGE AMTS OF WATER FOR AT LEAST 15
MIN WHILE HOLDING THE EYELIDS OPEN. GET PROMPT MED ATTN. SKIN:
IMMED REMOVE CONTAM CLTHG; WASH SKIN W/LARGE AMTS OF WATER FOR AT
LEAST 15 M IN. GET PROMPT MED ATTN. INHAL: MOVE VICTIM TO FRESH AIR
& RESTORE BRTHG IF NECESSARY. STAY W/VICTIM UNTIL ARRIVAL OF
EMERGENCY MED PERSONNEL. INGEST: CONTACT LOCAL POISON CONTROL
CENTER OR MD IMMED.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING MATERIALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SELF-CONTAINED
BREATHING APPARATUS, AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:PRODUCT HAS OXIDIZING PROPERTIES.
DANGEROUS FIRE RISK ON CONTACT WITH COMBUSTIBLE MATERIALS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PERSONAL PROT EQUIP (NIOSH/MSHA APPROVED
ACID GAS CARTRIDGE &/HIGH EFFICIENCY PARTICULATE FILTER
RESPIRATOR). REMOVE HEAT AND IGNITION SOURCES. VENT AREA.
NEUTRALIZE W/SODA ASH OR LIME. CLEAN UP W/NONCOMBUSTIBLE ABSORBANT
MATERIAL.
Neutralizing Agent:SODA ASH OR LIME.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED CONTAINER IN
WELL-VENTILATED AREA.
Other Precautions:NOTE: IF DILUTING, ALWAYS ADD THIS PRODUCT SLOWLY TO
WATER WITH CONSTANT STIRRING. DO NOT ADD THIS PRODUCT TO CHLORINE
RELEASING MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED, OR FOR SYMP OF OVEREXP, USE
NIOSH/MSHA-APPRVD ACID GAS CARTRIDGE &/HIGH EFFICIENCY PARTICULATE
FILTER RESPIRATOR.
Ventilation:LOC EXHAUST MAY BE NECESSARY UNDER SOME HNDLG/USE CNDTNS.
SPECIFIC NEED SHOULD BE ADDRESSED BY HEALTH/SAFETY PERSONNEL.
Other Protective Equipment:CHEM RESISTANT APRON OR COVERALLS & OR FOOT
COVERINGS AS NEEDED. EMERGENCY EYE WASH & DELUGE SHOWER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:<18
Vapor Density:<1
Spec Gravity:1.284
pH:1.1
Evaporation Rate & Reference:1 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID; ODORLESS
Percent Volatiles by Volume:0.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALIES, COMBUSTIBLES. CONTACT WITH CERTAIN METALS MAY YIELD EXPLOSIVE
HYDROGEN GAS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:SULFUR DIOXIDE, HYDROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CHROMATOGRAPHY SOLVENT,74-6470/6865/6475
CAGE:59896
CAGE:59896
============= Composition/Information on Ingredients =============
Ingred Name:VM&P NAPHTHA (LIGROINE)/PETROLEUM ETHER
CAS:8032-32-4
RTECS #:OI6180000
Fraction by Wt: 90%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:300 PPM
ACGIH TLV:300 PPM; 9596
Ingred Name:ACETONE (SARA 313) (CERCLA)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL;9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LC50 (INH, RAT) 3400 PPM/4H (PET. ETHER)
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, CNS, KIDNEYS,
RESPIRATORY & GI TRACTS. ACUTE- MAY CAUSE EYE IRRITATION.
PROLONGED/REPEATED SKIN CONTACT MAY CAUSE IRRITATION & DEFTTING.
HIGH VAPOR CONCENTRATIONS MAY CAUSE RE SPIRATORY TRACT IRRITATION &
CNS EFFECTS. IF SWALLOWED, CAN CAUSE GI TRACT IRRITATION &
DISCOMFORT. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, DEFATTING, TEARING, DISCOMFORT
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED KIDNEY OR RESPIRATORY FUNCTION
MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH
WATER FOR 15 MINUTES, HOLDING EYELIDS OPEN. SKIN:WASH WITH SOAP &
PLENTY OF WATER. ORAL:IF CONSCIOUS, DRINK PLENTYOF WATER. GET
MEDICAL ATTENTION IMMEDIATELY. NEVER GIVE ANYTHING BY MOUTH TO AN
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:-40F,-40C
Lower Limits:1.1
Upper Limits:5.9
Extinguishing Media:USE CARBON DIOXIDE (CO2), ALCOHOL FOAM OR DRY
CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:VAPOR IS HEAVIER THAN AIR AND CAN TRAVEL
CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK.
CONTAINERS MAY RUPTURE DUE TO VAPOR PRESSURE BUILDUP.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. ELIMINATE SOURCES
OF IGNITION. VENTILATE AREA. PICK UP SPILL WITH NON-FLAMMABLE
ABSORBENT SUCH AS SAND, EARTH, VERMICULITE. GROUND ALL HANDLING
EQUIPMENTS. PREVENT LIQUID FR OM ENTERING SEWERS OR WATERWAYS.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, VENTILATED AREA, AWAY
FROM HEAT, FLAMES, SPARKS, HOT SURFACES & INCOMPATIBLE MATERIALS.
KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions:DO NOT BREATHE MISTS/VAPOR. DO NOT GET IN EYES, ON
SKIN OR ON CLOTHING. KEEP OUT OF REACH OF CHILDREN. WASH THOROUGHLY
AFTER HANDLING. DO NOT INGEST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. IF TLV IS EXCEEDED OR
FOR SYMPTOMS OF OVER EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR
RESPIRATOR OR AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A
NIOSH-APPROVED POSITIVE-PRES SURE SELF-CONTAINED BREATHING
APPARATUS.
Ventilation:MECHANICAL (GENERAL AND/OR LOCAL EXHAUST, EXPLOSION-PROOF)
VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:SAFETY SHOWER AND EYE WASH FOUNTAIN SHOULD
BE LOCATED NEARBY. WEAR APPROPRIATE PROTECTIVE CLOTHING FOR RISK OF
EXPOSURE.
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F3
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:95F - 140F
Vapor Pres:NOT KNOWN
Vapor Density:2.5
Spec Gravity:0.6
Evaporation Rate & Reference:>1 (N-BUTYL ACETATE=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID; GASOLINE-LIKE ODOR
Percent Volatiles by Volume:90-100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, FLAME OR HOT SURFACES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE DISPOSAL TO BE PERFORMED IN COMPLIANCE
WITH ALL CURRENT LOCAL, STATE AND FEDERAL REGULATIONS. RECYCLING OR
INCINERATION IS RECOMMENDED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:P-TOLUENESULFONYL CHLORIDE 99+% GOLD LABEL,
CAGE:60928
CAGE:60928
============= Composition/Information on Ingredients =============
Ingred Name:P-TOLUENESULFONYL CHLORIDE (99+% GOLD LABEL)
CAS:98-59-9
Fraction by Wt: 99%+
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL IF SWALLOWED, INHALED,
OR ABSORBED THROUGH SKIN. CAUSES BURNS. MATERIAL IS EXTREMELY
DESTRUCTIVE TO TISSUE OF THE MUCOUS MEMBRANES AND UPPER RESP TRACT,
EYES & SKIN. INHAL MAY BE FATAL AS A RESULT OF SPASM, INFLAM &
EDEMA OFLARYNX & BRONCHI, CHEM PNEUM & PULM EDEMA.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:BURNING SENSATION, COUGHING, WHEEZING,
LARYNGITIS, SHORTNESS OF BREATH, HEADACHE, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:IN CASE OF CONTACT, IMMEDIATELY FLUSH EYES OR SKIN WITH
COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING
CONTAMINATED CLOTHING AND SHOES. ASSURE ADEQUATE FLUSHING OF EYES
BY SEPARATING THE EYELIDS WITH FINGERS. IF INHALED, REMOVE TO
FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST: CALL MD
IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DO NOT USE WATER. CO*2, DRY CHEMICAL POWDER,
ALCOHOL OR POLYMER FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
AND FULL PROTECTIVE EQUIPMENT . PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CNDTNS.
WATER HYDROLYZES MATL LIBERATING ACIDIC GAS WHICH IN CONT W/METAL
SURF CAN GENERATE FLAM AND/OR EXPLOSIVE (SEE SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA, RUBBER BOOTS AND
IN A CLOSED CONTAINER AND HOLD FOR WASTE DISPOSAL. AVOID RAISING
DUST. VENT AREA AND W ASH SPILL SITE AFTER MATL PICKUP IS COMPLETE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST. KEEP TIGHTLY
CLOSED. MOISTURE-SENSITIVE. STORE IN A COOL DRY PLACE.
Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLTHG. AVOID PRLNGD
OR RPTD EXPOS. CORR. LACHRYMATOR. NO SMOKING IN AREA OF USE. DO NOT
USE IN GEN VICINITY OF ARC WELDING, OPEN FLAME OR HOT SURF. HEAT
MAY CAUSE FORMA TION OF HCL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER AND EYE
BATH.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLO HAZ: HYDROGEN GAS. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE
HCL.
================== Physical/Chemical Properties ==================
HCC:C1
Melt/Freeze Pt:M.P/F.P Text:153F,67C
Vapor Pres:1.0MM @88C
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
STRONG OXIDIZING AGENTS & STRONG BASES.
Stability Condition to Avoid:MOISTURE.
Hazardous Decomposition Products:CO, CO*2, SO*X & HYDROGEN CHLORIDE
GAS. PHOSGENE .
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE & LOCAL LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BUR-NU
CAGE:15044
CAGE:15044
============= Composition/Information on Ingredients =============
Ingred Name:POLYETHYLENE GLYCOL 400 DILAURATE
CAS:9005-02-1
Fraction by Wt: 5%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: IRRITANT.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN: IRRITANT.
Medical Cond Aggravated by Exposure:NONE INDICATED
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF RESPIRATORY IRRITATION
OCCURS OR BREATHING BECOMES DIFFICULT, SEEK MEDICAL ATTENTION.
EYE/SKIN: FLUSH W/LARGE AMOUNTS OF RUNNING WATER FOR 15 MINUTES.
SEEK MEDICAL ATTENTION IF IRRITATION OCCURS. INGESTION: GIVE
SEVERAL GLASSES OF WATER. INDUCE VOMITING & GIVE FLUIDS UNTIL
VOMITUS IS CLEAR.
===================== Fire Fighting Measures =====================
Flash Point:249C
Extinguishing Media:CO2, FOAM, DRY CHEMICAL, WATER SPRAY
Fire Fighting Procedures:TREAT AS HOT OIL/FAT FIRE
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:MOP UP & FLUSH AREA WITH WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE INDICATED
Ventilation:MECHANICAL
Other Protective Equipment:EYE BATH
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:0.99
Solubility in Water:DISPERSIBLE
Appearance and Odor:YELLOW LIQUID, MILD FATTY ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, ALKALIS, OXIDIZERS.
Hazardous Decomposition Products:CO2, CO
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR LANDFILL, AS PERMITTED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:134-140 STAY OPEN
Preparer's Name:DICK KARBO
CAGE:KMADD
CAGE:KMADD
============= Composition/Information on Ingredients =============
Ingred Name:BARIUM COMPOUNDS
Fraction by Wt: 4%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN
CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA
W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>200F
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE
CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS.
Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED
Ventilation:LOCAL EXHAUST
Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS
USED.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:470-610F
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:INSOLUBLE
Appearance and Odor:OILY
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:624 650T CYLINDER OIL 1000
CAGE:38431
CAGE:38431
CAGE:7B131
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL OIL (EXPOSURE REGULATED AS 'OIL MIST')
CAS:8012-95-1
RTECS #:PY8030000
Fraction by Wt: 91%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3/10 STEL;9192
Ingred Name:METHACRYLATE COPOLYMER
Fraction by Wt: 4%
Ingred Name:TALLOW OIL, ACIDLESS
Fraction by Wt: 5%
Ingred Name:SILICONEANTI-FOAMANT
Fraction by Wt: <1%
Ingred Name:ADDITIVES (COMBINED W/PHOSPHATE & NITROGEN EQUAL 0.1%)
===================== Hazards Identification =====================
Effects of Overexposure:EYES:MINIMAL IRRITATION.INH:MINIMAL IRRITATION.
SKIN:MINIMAL IRRITATION
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/ WATER FOR 15 MINUTES. SKIN:WASH W/SOAP & WATER.
INH* MOVE INDIVIDUAL TO FRESH AIR.
===================== Fire Fighting Measures =====================
Flash Point:540F; 282C, COC
Extinguishing Media:WATER SPRAY, DRY CHEM, FOAM, OR CO*2.
Fire Fighting Procedures:WATER OR FOAM MAY CAUSE FROTHING.,SCBA,PROTECT
CLOTH.
Unusual Fire/Explosion Hazard:HEAT OR COMBUSTION MAY RELEASE ALDEHYDES,
KETONES, AND OXIDES OF NITROGEN AND SULFUR, CO AND CO*2.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL. ABSORB B W/INERT POROUS
MATERIAL
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR IF REQUIRED
Ventilation:NORMAL VENTILATION SUFFICIENT TO KEEP BELOW TLV
Supplemental Safety and Health
VP:NIL. % VOLATILE:NIL. TLV:5 MG/CUM FOR MINERAL OIL MIST AVERAGED OVER
8 HR EXPOSURE (MFR).N/D:NOT DETERMINED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:N/D
Spec Gravity:0.916
Evaporation Rate & Reference:N/D
Solubility in Water:INSOLUBLE
Appearance and Odor:OPAQUE, GREEN LIQUID
================= Stability and Reactivity Data =================
Hazardous Decomposition Products:HEAT RELEASES
ALDEHYDES,KETONE,NITROGEN & SULFUR OXIDIES,CO.
==================== Disposal Considerations ====================
Waste Disposal Methods:MFR RECOMMENDS CONTACTING A WASTE OIL CONTRACTOR
OR DISPOSAL SPECIALIST. ALL MATERIAL MUST BE DISPOSED IAW
FEDERAL,STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:KODAK MICROFILM FIXER AND REPLENISHER, WORKING SOLUTION
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 80-85%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMMONIUM THIOSULFATE
CAS:7783-18-8
RTECS #:XN6465000
Fraction by Wt: 10-15%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM ACETATE
CAS:127-09-3
RTECS #:AJ4300010
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMMONIUM BISULFITE
CAS:10192-30-0
RTECS #:WT3595000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:AMMONIUM ACETATE
CAS:631-61-8
RTECS #:AF3675000
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: LOW HAZARD FOR RECOMMENDED
HANDLING. EYES: NO SPECIFIC HAZARD KNOWN. MAY CAUSE TRANSIENT
IRRITATION. SKIN: LOW HAZARD FOR RECOMMENDED HANDLING. INGESTION:
EXPECTED TO BE A LOW INGESTION HA ZARD.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION-IF SYMPTOMATIC, REMOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES-ANY MATERIAL THAT CONTACTS THE
EYE SHOULD BE WASHED OUT IMMEDIATELY WITH WATER. GET MEDICAL
ATTENTION IF SYMPTOMS OCCUR. SKIN-WASH WITH SOAP & WATER.
INGESTED-DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE APPROPIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING. FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT MATERIAL,
THEN PLACE INA CONTAINER FOR CHEMICAL WASTE. CLEAN SURFACE
THOROUGHLY TO REMOVE RESIDUAL C ONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES.
Other Precautions:USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
Work Hygienic Practices:GOOD INDUSTRIAL HYGIENE PRACTICES SHOULD BE
FOLLOWED WHICH INCLUDES PREVENTING SKIN/EYE CONTACT AND INHALATION.
Supplemental Safety and Health
LOW HAZARD FOR RECOMMENDED HANDLING.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:23 MBAR
Vapor Density:0.6
Spec Gravity:1.10
pH:5.3
Solubility in Water:COMPLETE
Appearance and Odor:LIQUID. COLORLESS-LIGHT YELLOW. SLIGHT ACIDIC ODOR.
Percent Volatiles by Volume:90-95
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES, SODIUM HYPOCHLORITE, STRONG OXIDIZING AGENTS.
CONTACT WITH BASES LIBERATES FLAMMABLE MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:AMMONIA, CHLORAMINE, CARBON MONOXIDE,
CARBON DIOXIDE, NITROGEN OXIDES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE, OR LOCAL LAWS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:156 4632 FIRST DEVELOPER, PROCESS E-6, CONCENTRATE
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 55 - 60%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
Ingred Name:POTASSIUM SULFITE
CAS:10117-38-1
RTECS #:WT3530000
Fraction by Wt: 10 - 15%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POTASSIUM CARBONATE
CAS:584-08-7
RTECS #:TS7750000
Fraction by Wt: 5 - 10%
Other REC Limits:NONE RECOMMENDED
Ingred Name:POTASSIUM HYDROQUINONE MONOSULFONATE
CAS:21799-87-1
Fraction by Wt: 5 - 10%
Other REC Limits:NONE RECOMMENDED
Ingred Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 5 - 10%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM CARBONATE
CAS:497-19-8
RTECS #:VZ4050000
Fraction by Wt: 1 - 5%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: LOW HAZARD FOR INHALATION AND
INGESTION FOR RECOMMENDED HANDLING. CONTACT MAY CAUSE TRANSIENT EYE
IRRITATION; ALLERGIC SKIN REACTION.
Explanation of Carcinogenicity:NO INGREDIENT OF A CONCENTRATION OF 0.1%
OR GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Effects of Overexposure:EYES: REDNESS, TEARING, DISCOMFORT. SKIN:
REDNESS, ITCHING, DISCOMFORT.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALED: IF SYMPTOMATIC REMOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: FLUSH WITH LOTS OF WATER FOR
15 MINUTES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN; REMOVE
CONTAMINATE D CLOTHES. WASH WITH AND WATER. GET MEDICAL ATTENTION
IF SYMPTOMS OCCUR. INGESTED: IF CONSCIOUS, DRINK 1-2 GLASSES OF
WATER. SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM
Fire Fighting Procedures:SOLUTION CONTAINS A STRONG REDUCING AGENT.
DRIED PRODUCT RESIDUE CAND ACT AS A REDUCING AGENT. ELEVATED
TEMPERATURE CAN CAUSE DECOMPOSITION.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED AND AWAY
FROM OXIDIZERS & ACIDS.
Other Precautions:THIS MATERIAL IS A MODERATELY ALKALINE AQUEOUS
SOLUTION, AND THIS PROPERTY MAY CAUSE ADVERSE ENVIRONMENTAL
EFFECTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:GOOD GENERAL VENTILATION (10 AIR EXCHANGES PER HOUR) SHOULD
BE SUFFICIENT.
Other Protective Equipment:WASH STATION, EYE WASH STATION & SAFETY
SHOWER.
Work Hygienic Practices:USE OF A NON-ALKALINE TYPE OF SKIN CLEANSER AND
REACTION.
Supplemental Safety and Health
KEY1;N1.
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NONE
Boiling Pt:B.P. Text:>212F,>100C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Pres:18
Vapor Density:0.6
Spec Gravity:1.316
pH:9.9
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT BROWN LIQUID, NO ODOR
Percent Volatiles by Volume:55-60
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE AND PROBABLY CARBON
MONOXIDE. OXIDES OF SULFUR MAY ALSO BE PRESENT.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HEXAMETHYLENE DIISOCYANATE, 118 8200, 906735
CAGE:GO467
CAGE:ACRSR
CAGE:GO467
============= Composition/Information on Ingredients =============
Ingred Name:HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)
(CERCLA)
CAS:822-06-0
RTECS #:MO1740000
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION:HARMFUL IF INHALED. VAPOR
IRRITATING. MAY CAUSE RESPIRATORY SENSITIZATION W/ASTHMA-LIKE
REACTION. SKIN:CAUSES BURNS. MAY CAUSE ALLERGIC REACTION. HARMFUL
IF ABSORBED THROUGH SKIN. EYE:CAUSE S SEVERE BURNS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. IF SYMPTOMS ARE PRESENT, CALL MD. SKIN:IMMEDIATELY
FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATT
ENTION IF SYMPTOMS ARE PRESENT AFTER WASHING. EYE:IMMEDIATELY FLUSH
W/PLENTY OF WATER FOR AT LEAST 15 MINUTES & CALL MD IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:284F,140C
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
USE WATER W/CAUT & IN FLOODING AMTS. MATL REACTS W/WATER. WATER MAY
BE INEFT IN FIGHTING FIRE. USE (SUPDAT)
Unusual Fire/Explosion Hazard:FIRE/EXCESSIVE HEAT MAY PRDCE HAZ DECOMP
PRODS. REACTS W/WATER. FIRE/EXCESSIVE HEAT MAY RESULT IN VIOLENT
RUPTURE OF CNTNR DUE TO BULK POLYMERIZATION.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB MATERIAL IN VERMICULITE OR OTHER
SUITABLE ABSORBENT & PLACE INTO IMPERVIOUS CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM CONTACT W/OXIDIZING
MATERIALS. KEEP CONTAINER TIGHTLY CLOSED & AWAY FROM ANY CONTACT
W/WATER, ACIDS, STRONG BASES, METALS, AMINES/ALCOHOLS.
Other Precautions:DO NOT ADD WATER TO CLSD CNTNR SINCE RXN MAY RSLT IN
VIOLENT RUPTURE OF CNTNR. STORE IN COOL, DRY PLACE. REFRIGERATION
REQUIRED, BUT KEEP FROM FREEZING. SINCE EMPTY CNTNR RETAINS PROD
RESIDUE, FOLLOW LBL WARNINGS EVEN AFTER CNTNR IS EMPTY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH/MSHA APPROVED ORGANIC VAPOR RESPIRATOR
SHOULD BE WORN IF NEEDED.
Ventilation:GOOD GENERAL ROOM VENTILATION SHOULD BE USED. LOCAL EXHAUST
MAY BE NEEDED.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . PROTECTIVE CLOTHING SHOULD BE WORN.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
% VOLAT:NEGLIGIBLE (WT). FIRE FIGHT PROC:WATER SPRAY TO KEEP
FIRE-EXPOSED CNTNRS COOL. FIGHT FIRE FROM PROTECTED LOCATION. HAZ
DECOMP PROD:DECOMP MAY PRODUCE CYANIDE FUMES. EYE PROT:& FULL
LENGTH FACE SHIELD .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:415F,213C
Vapor Pres:0.03 @ 20C
Spec Gravity:1.05 (H*2O=1)
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:DECOMPOSES
Appearance and Odor:COLORLESS LIQUID.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, WATER, ACIDS, STRONG BASES, METALS, AMINES, ALCOHOLS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:COMBUST WILL PRDCE CARBON DIOXIDE &
PROBABLY CARBON MONOXIDE. OXIDES OF NITROGEN MAY ALSO BE PRESENT.
HEATING TO(SUPDAT)
Conditions to Avoid Polymerization:MAY OCCUR UPON HEATING.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE BY INCINERATION OR CONTRACT W/LICENSED
CHEMICAL WASTE DISPOSAL AGENCY. DISCHARGE, TREATMENT OR DISPOSAL
MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:7224 CLIFF BLUE, 8054839
CAGE:DO804
CAGE:DO804
CAGE:38360
============= Composition/Information on Ingredients =============
Ingred Name:WASTE DISP: RENDER THE RESULTING MATL HAZARDOUS. CONTACT
FEDERAL, STATE AND LOCAL AUTHORITIES FOR DISPOSAL INFO. (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: CONSULT 40 CFR PART 261 IDENTIFICATION AND LISTING
OF HAZARDOUS WASTE.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC: AND FOR CONTROLLING THE FIRE/EXPLOSION HAZARD.
A QUALIFIED INDEPENDENT TESTING COMPANY CAN DETERMINE (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: IF THE EXISTING CONCENTRATIONS ARE WITHIN THE
ESTABLISHED RECOMMENDED/PERMISSIBLE EXPOSURE LEVELS.
RTECS #:9999999ZZ
Ingred Name:PHOSPHORIC ACID, TRIBUTYL ESTER; (TRIBUTYL PHOSPHATE)
CAS:126-73-8
RTECS #:TC7700000
Fraction by Wt: 20-50%
OSHA PEL:5 MG/M3
ACGIH TLV:0.2 PPM; 9293
Ingred Name:HEXAHYDROPHTHALIC ANHYDRIDE
CAS:85-42-7
Fraction by Wt: 0-5%
Ingred Name:SILANE, 3-(2,3-EPOXYPROPOXY) PROPYLTRIMETHOXY-; (SILANE
A-187)
CAS:2530-83-8
RTECS #:VV4025000
Fraction by Wt: 0-3%
Ingred Name:SPILL PROC: STANDARD: 29 CFR PART 1910.120 HAZARDOUS WASTE
OPERATIONS AND EMERGENCY RESPONSE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION, INFLAMMATION. SKIN:
IRRITATION, DERMATITIS. INHAL: DIZZINESS, LOSS OF CONSCIOUSNESS,
IRRITATION, SENSITIZER WITH ASTHMATOID EFFECTS, WHEEZING, COUGHING,
SORE THROAT. INGEST: NAUSEA, VOMITING, ABDOMINAL PAIN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR @ LST 15 MIN. CALL A PHYSICIAN IMMED.
SKIN: WASH W/SOAP & WATER. LAUNDER CONTAM CLOTHING BEFORE REUSE.
GET MED ATTN. INHAL:REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF
BREATHING I S DIFFICULT. BEGIN RESUSCITATION IF BRTHG HAS STOPPED.
KEEP PERSON WARM & QUIET. GET MEDICAL ATTN. INGEST: DO NOT INDUCE
VOMITING. GET MEDICAL ATTN IMMED. NOTE TO MD: TRIBUTYL PHOSPHATE
(SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point:>200F,>93C
Extinguishing Media:DRY CHEMICAL, CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND AND MAY BE IGNITED AT DISTANT LOCATIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. ABSORB
SPILLED MATL WITH VERMICULITE OR FLOOR ABSORBENT. DISPOSE OF CONTAM
4)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:CNTNRS OF THESE MATLS MAY BE HAZARDOUS
WHEN EMPTIED, SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES WHICH CAN
GENERATE VAPS WITHIN THE INFLAMMABLE LIMITS.
Other Precautions:FOR FLAMM OR COMBUSTIBLE PRODS FOLLOW STORAGE &
HANDLING GUIDELINES PRESENTED IN NFPA 30 FLAMMABLE & COMBUSTIBLE
LIQUIDS CODE. THE USE OF A HAZARDOUS CHEMICAL MAY REQUIRE
SUPPLEMENTAL VENTILATION FOR THE PROTECTION OF PERSONNEL (ING 7)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW
APPLICABLE OCCUPATIONAL EXPOSURE STANDARDS. ENGINEERING OR
ADMINISTRATIVE CONTROLS OR NIOSH/MSHA APPRVD RESPS CAN BE USED TO
REDUCE EXPOSURE. ENGINEERING CONTROLS ARE PREFERRED BY OSHA.
Ventilation:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW APPLICABLE
OCCUPATIONAL EXPOSURE STANDARDS.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: POSSESSES ONLY WEAK ANTICHOLINESTERASE ACTIVITY WHICH
SHOULD NOT REQUIRE SPECIFIC TREATMENT. LARGE DOSES HAVE BEEN
REPORTED TO CAUSE DYSPNEA, WEAKNESS, PULMONARY EDEMA, AND TWITCHING
I N RATS. CHRONIC INHALATION OF LARGE DOSES CAN LEAD TO GENERAL
POISONING WITH PARALYSIS.
================== Physical/Chemical Properties ==================
Vapor Pres:VERY LOW
Evaporation Rate & Reference:VERY SLOW
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID OR SEMI-SOLID INK AS COLOR ABOVE, MILD ODOR.
Percent Volatiles by Volume:APPROX
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS AND BASES. WATER.
Stability Condition to Avoid:HEAT AND FLAME.
Hazardous Decomposition Products:CO, CO*2, SILICON OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:UNDER RCRA, IT IS THE RESPONSIBILITY OF THE
GENERATOR OF THE WASTE TO DETERMINE, AT THE TIME OF DISPOSAL,
WHETHER THE WASTE GENERATED MEETS THE FEDERAL OR STATE HAZAROUS
WASTE CRITERIA. USES, TRANSFOR MATIONS, MIXTURES, PROCESSES, ETC.
MAY (ING 5)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CLASSIC SUPER HEAVY DUTY INDUSTRIAL
CAGE:66571
CAGE:66571
============= Composition/Information on Ingredients =============
Ingred Name:CARBON BLACK; (ACETYLENE BLACK)
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 3-7%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:AMMONIUM CHLORIDE (CERCLA)
CAS:12125-02-9
RTECS #:BP4550000
Fraction by Wt: 0-10%
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3 FUME
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:MANGANESE DIOXIDE
CAS:1313-13-9
RTECS #:OP0350000
Fraction by Wt: 15-31%
OSHA PEL:5 MG MN/M3 CEILING
ACGIH TLV:5 MG MN/M3
Ingred Name:ZINC (SARA 313) (CERCLA)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 7-42%
OSHA PEL:15 MG/M3 (MFR)
ACGIH TLV:10 MG/M3 (MFR)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ZINC CHLORIDE (SARA 313) (CERCLA)
CAS:7646-85-7
RTECS #:ZH1400000
Fraction by Wt: 2-10%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/2 STEL(FUME)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:OTHER PREC: BATTERIES IN DEVICES. IF SOLDERING/WELDING TO
BATTERY IS REQUIRED, CONSULT YOUR MFR REPRESENTATIVE (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: FOR PROPER PREC TO PVNT SEAL DMG/SHORT CIRCUIT.
CHARGING: THIS BATTERY IS MANUFACTURED IN CHARGED STATE. (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: IT IS NOT DESIGNED FOR RECHARGING. RECHARGING CAN
CAUSE BATTERY LEAKAGE/IN SOME CASES, HIGH PRESS RUPTURE.(ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: INADVERTENT CHARGING CAN OCCUR IF BATTERY IS
INSTALLED BACKWARDS. LABELING: IF MFR LABEL/PACKAGE WARNINGS(ING
10)
RTECS #:9999999ZZ
Ingred Name:ING 9: ARE NOT VISIBLE, IT IS IMPORTANT TO PROVIDE PACKAGE
&/OR DEVICE LABEL STATING: WARNING: DO NOT DISP OF (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10: IN FIRE, RECHARGE, PUT IN BACKWARDS, MIX W/USED OR
OTHER BATTERY TYPES-MAY EXPLODE/LEAK & CAUSE PERS (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: INJURY. WHERE ACCIDENTAL INGEST OF SML BATTERIES IS
POSS, LABEL SHOULD STATE: WARNING: (1) KEEP AWAY (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12: FROM SML CHILDREN. IF SWALLOWED, PROMPTLY SEE MD.
RTECS #:9999999ZZ
Ingred Name:ING 13: DISP OF IN FIRE, RECHARGE, PUT IN BACKWARDS, MIX
W/USED OR OTHER BATTERY TYPES-MAY EXPLODE/LEAK & (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: CAUSE PERSONAL INJURY.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST: CAN BE HARMFUL.
CONTENTS OF OPEN BATTERY CAN CAUSE SERIOUS CHEM BURNS OF MOUTH,
ESOPHAGUS, & GI TRACT. INHAL: CONTENTS OF OPEN BATTERY CAN CAUSE
RESP IRRIT. SKIN: CONTENTS OF OPEN BATTE RY CAN CAUSE IRRIT &/OR
CHEM BURNS. EYES: CONTENTS OF OPEN BATTERY CAN CAUSE SEV IRRIT &
CHEM BURNS.
Explanation of Carcinogenicity:CARBON BLACK: IARC MONOGRAPHS, VOLUME
65, PAGE 149, 1996: GROUP 2B. ANIMAL: LUNG.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST: DO NOT INDUCE VOMIT/GIVE FOOD/DRINK. SEEK MED ATTN
IMMED. CALL NATL BATTERY INGEST HOTLINE FOR ADVICE & FOLLOW-UP
(202-625-3333) COLLECT, DAY/NIGHT. INHAL: PROVIDE FRESH AIR & SEEK
MED ATTN. S KIN: REMOVE CONTAM CLTHG & WASH SKIN W/SOAP & WATER. IF
CHEM BURNS OCCURS/IRRIT PERSISTS, SEEK MED ATTN. EYES: IMMED FLUSH
THORO W/WATER FOR AT LEAST 15 MIN, LIFTING UPPER & LOWER LIDS, (SUP
DAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:IT IS PERMISSIBLE TO USE ANY CLASS OF EXTINGUISHING
MEDIUM ON THESE BATTERIES OR THEIR PACKAGING MATERIAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . COOL EXTERIOR OF BATTERIES IF EXPOSED TO FIRE TO
PREVENT RUPTURE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:IF POTTING/SCALING BATTERY IN
AIRTIGHT/WATERTIGHT CONTR IS REQUIRED, CONSULT YOUR MFR
REPRESENTATIVE FOR PREC SUGGESTIONS. BATTERIES NORM EVOLVE HYDROGEN
WHICH, WHEN COMBINED W/OXYGEN FROM AIR, CAN PR DCE COMBUST/EXPLO
MIXT UNLESS VENTED. (SUP DAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:ACCIDENTAL SHORT CIRCUIT FOR A FEW
SECONDS WILL NOT SERIOUSLY AFFECT BATTERY.
Other Precautions:PRLNG SHORT CIRCUITS WILL CAUSE BATTERY TO LOSE
ENERGY, & CAN CAUSE SFTY RELEASE VENT TO OPEN. SOURCES OF SHORT
CIRCUITS INCL JUMBLED BATTERIES IN BULK CONTRS, METAL JEWELRY,
METAL COVERED TABLES/META L BELTS USED FOR ASSEMBLY OF (ING 6)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NECCESARY UNDER NORMAL CONDITIONS. USE NIOSH
APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NOT NECESSARY UNDER NORMAL CONDITIONS.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: UNTIL NO EVIDENCE OF CHEM REMAINS. SEEK MED ATTN. SPILL
PROC: IF SUCH MIXT IS PRESENT, SHORT CIRCUITS, HIGH TEMP/STATIC
SPKS CAN CAUSE IGNIT. DO NOT OBSTRUCT SFTY RELEASE VENTS ON BATT
ERIES. ENCAPSULATION (POTTING) OF BATTERIES WILL NOT ALLOW CELL
VENTING & CAN CAUSE HIGH PRESSURE RUPTURE.
================== Physical/Chemical Properties ==================
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL,
STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:31 FLUX, ALUMINUM AND MAGNESIUM WELDING (SUPDAT)
CAGE:69482
CAGE:69482
============= Composition/Information on Ingredients =============
Ingred Name:LITHIUM CHLORIDE
CAS:7447-41-8
RTECS #:OJ5950000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:LITHIUM FLUORIDE
CAS:7789-24-4
RTECS #:OJ6125000
OSHA PEL:2.5 MG/M3
ACGIH TLV:2.5 MG/M3
Ingred Name:POTASSIUM CHLORIDE
CAS:7447-40-7
RTECS #:TS8050000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SODIUM CHLORIDE
CAS:7647-14-5
RTECS #:VZ4725000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ZINC CHLORIDE (SARA 313) (CERCLA)
CAS:7646-85-7
RTECS #:ZH1400000
Fraction by Wt: <15%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 2STEL(FUME)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SUPDAT: PAINT, PLATING OR GALVANIZING) NUMBER OF WELDING
OPERATIONS & VOL OF WORK AREA, QUALITY & AMT OF VENT, (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: POSITION OF WORKER'S HEAD W/RESPECT TO FUME PLUME AS
WELL AS PRESENCE OF CONTAMINANTS IN ATM (SUCH AS (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: CHLORINATED HYDROCARB VAPS FROM CLEANING OR PAINTING
ACTIVITIES). WHEN MATLS ARE CONSUMED, FUME & GAS (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: DECOMP PRODS GENERATED ARE DIFFERENT IN PERCENT &
FORM FROM LISTED INGREDS. DECOMP PRODS OF NORMAL (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: OPERATION INCL THOSE ORIGINATING FROM
VOLATILIZATION, RXN OR OXIDATION OF INGREDS PLUS THOSE FROM MATL
(ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10: BEING WORKED & COATINGS ETC NOTED ABOVE.
RTECS #:9999999ZZ
Ingred Name:VENT: ENVIRONMENTAL REGULATIONS FOR EXHAUSTS.
RTECS #:9999999ZZ
Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT: PUBLISHED BY AWS & OSHA PUBLICATION 2206 (29
CFR 1910) FOR MORE DETAIL ON CONTROL & PROT MEASURES.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST:NAUS, VOMIT. CAN CAUSE
CHEM BURN TO DIGEST SYS & TOX EFTS DUE TO LITHIUM ION. INHAL:RESP
SYS IRRITANT. LITHIUM DUST & FUMES ARE ABSORBED THRU LUNGS. LUNG
DMG. SKIN: DERM; POSS CHEM BURN. NOT KNOWN AS SKIN ABSORB.
EYES:IRRIT &POSS BURN OF EYE SURFS. CHRONIC: COUGH, CNS EFTS,
ERYTH, NAUS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:& KIDNEY EFTS. CHRONIC FLUORIDE
ABSORPTION CAN RSLT IN OSSEOUS FLUOROSIS, INCRD RADIOGRAPHIC
DENSITY OF BONES & MOTTLING OF TEETH. TARGET ORGAN:MAY BE FATAL IF
SWALLOWED/INHALED; CAUSES EYE & SKIN BURNS. TOX. WHEN PRODS ARE
USED AS REC & VENT MAINTAINS EXPOS TO DECOMP PRODS BELOW LIMS REC
OVEREXP IS UNLIKELY.
Medical Cond Aggravated by Exposure:PRE-EXISTING LUNG AND SKIN
DISORDERS WILL BE AGGRAVATED.
======================= First Aid Measures =======================
First Aid:INGEST: CALL MD AT ONCE OR POIS CTL CTR. ADVISE OF INGREDS
IMMED. MAY BE FATAL! CORR TO MUC MEMBS. SKIN: PROMPTLY FLUSH
W/WATER TO REMOVE ALL RESIDUE. IF RASH/BURN DEVELOPS, CONSULT MD.
MATL IS CORR. W/WATER, POSS HF. INHAL: REMOVE TO FRESH AIR. IF
FUMES ARE INHALED, CALL MD. OVERINHAL MAY BE FATAL! EYE: FLUSH
W/WATER FOR AT LST 15 MIN TO REMOVE ALL RESIDUE. GET MED HELP NOW!
BLINDNESS CAN RESULT!
===================== Fire Fighting Measures =====================
Extinguishing Media:NONE; PRODUCT IS AN INHERENT RETARDANT.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . METAL HALIDE AND TOXIC FUMES PRODUCED.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL, ABSORB, SWEEP UP. REMOVE TO
CHEMICAL SEWER. FLUSH AREA WITH WATER TO CHEMICAL SEWER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE FLUX @ AMBIENT CNDTNS. KEEP
UNDER EXTREMELY DRY & CTLD CNDTNS. WASH THOROUGHLY AFTER HNDLG TO
REMOVE ALL RESIDUE. DO NOT WEAR CNTCT LENSES.
Other Precautions:FOR ALL FLUXES, REMOVE & PROFESSIONALLY WASH CONTAMD
CLOTHING BEFORE REUSE. ALSO, DO NOT BREATHE FUMES. MAY BE FATAL!
MATERIAL WILL NATURALLY ABSORB MOISTURE & CAKE SOLID. EXISTING LUNG
DISORDERS WILL HAVE INCREASED TOX SUSCEPTIBILITY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF THE WORK STATION IS NOT PROPERLY VENTILATED
TO EXHAUST ALL FUMES, VAPORS AND DUSTS USE A NIOSH APPROVED MASK.
Ventilation:MAINTAIN AIR FLOW AWAY FROM USER TO REMOVE ALL FUMES, VAPS
& DUSTS SO PEL/TLV ARE NEVER EXCEEDED. ADHERE TO (ING 12)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . FULL
PROT EQUIP NORMALLY USED IN BRAZE/WELD OPERATION SO AS TO PVNT
CNTCT.
Work Hygienic Practices:READ & UNDERSTAND MFR'S INSTRUCTIONS &
PRECAUTIONARY LABEL ON PROD. SEE ANS Z49.1, "SAFETY IN WELDING &
CUTTING"(ING 14)
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: AND BRAZING FLUXES. HAZ DECOMP PRODS:
COMPOSITION & QTY OF BOTH ARE DEPENDENT UPON MATL BEING WORKED,
PROCESS, PROCS & CONSUMABLES USED. OTHER CNDTNS WHICH ALSO
INFLUENCE COM POSITION & QTY OF FUMES & GASES TO WHICH WORKERS MAY
BE EXPOSED INCL: COATINGS ON MATL BEING WORKED (SUCH AS (ING 6)
================== Physical/Chemical Properties ==================
Spec Gravity:2.15 (H*2O=1)
Solubility in Water:SLIGHT
Appearance and Odor:BLUE POWDER; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, CYANIDES AND SULFIDES.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:IN PRESENCE OF WATER & HEAT, HCL & HF
WILL BE GIVEN OFF. WELDING FUMES & GASES CANNOT BE CLASSIFIED
SIMPLY. (SUPDAT)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CUSTOM W/R ENAMEL DARK TAN FED STND 36555,(
CAGE:54626
CAGE:54626
============= Composition/Information on Ingredients =============
Ingred Name:2-BUTOXYETHANOL
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 5%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY) (DIETHYLENE GLYCOL MONOBUTYL
ETHER)
CAS:112-34-5
RTECS #:KJ9100000
Fraction by Wt: <5%
OSHA PEL:25 PPM, S
ACGIH TLV:25 PPM, S
Ingred Name:DIBUTYL PHTHALATE (SARA III)
CAS:84-74-2
RTECS #:TI0875000
Fraction by Wt: <5%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3; 9192
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:TALC (CONTAINING NO ASBESTOS)
CAS:14807-96-6
RTECS #:WW2710000
Fraction by Wt: <5%
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST; 9192
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 20%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & UPPER
RESP SYS. IN CONFINED AREA VAPS IN HIGH CONC MAY CAUSE HDCH,
NAUS/DIZZ. REDNESS & ITCHING/BURNING SENSATION MAY INDICATE
EYE/EXCESSIVE SKIN EXPOS. CHRONIC: PRLNGD OV EREXP TO SOLV INGRED
IN SECTION II MAY CAUSE ADVERSE EFTS TO LIVER, URINARY, & BLOOD
FORMING SYS. (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFFECTS ON CNS, THE HEMATOPOIETIC TISSUES, THE
BLOOD, THE KIDNEYS AND THE LIVER, ASSOCIATED WITH THE
ADMINISTRATION OF ETHYLENE GLYCO L MONOBUTYL ETHER (EGBE) AND
ETHYLENE GLYCOL MONOBUTYL ETHER ACETATE (EGBEA). (EXTRACTED FROM
DHHS (NIOSH) PUB 90-118.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND
QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYE: FLUSH
EYES WI TH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION. INGEST: CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:199F,93C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP
. H2O SPRAY MAY BE INEFFECTIVE. IF H2O IS USED, FOG NOZ ARE
PREFERABLE. H2O MAY BE USED TO (SUPP DATA)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO
BUILD- UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAINERS WITH COMPLETE AND APPROPRIATE
LABELING. DO NOT TAKE INTERNALLY.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPRVD PROPERLY FITTED ORG VAP/
PARTICULATE RESP WHEN SANDING OR ABRADING DRIED FILM, WEAR A
NIOSH/MSHA APPRVD DUST MASK OR PARTICULATE RESPIRATOR.
Ventilation:LOCAL EXHAUST PREFERABLE. GEN EXHST ACCEPTABLE IF EXPOS IS
MAINTAINED BELOW (SEE SUPP DATA)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP AND POS
AUTOIGNIT OR EXPLO WHEN EXPOSED TO EXTREME HEAT. VENT: APPLICABLE
EXPOSURE LIMITS. REFER TO OSHA STANDARDS 1910.94, 1910.107,
1910.108.
================== Physical/Chemical Properties ==================
HCC:V4
Boiling Pt:B.P. Text:212F,100C
Vapor Density:HVR/AIR
pH:8.3
Evaporation Rate & Reference:SLOWER THAN ETHER.
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:59.7
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE (BY
FIRE).
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM PROD IS NOT HAZ AS DEFINED UNDER THE
RCRA 40 CFR 261. INCINERATE IN APPRVD FACILITY. DO NOT INCIN CLSD
CNTNR. DISP OF I/A/W FEDERAL, STATE, AND LOCAL REGULATIONS
REGARDING POLLUTION.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:50-5,000 PPM HEXANE IN AIR
Preparer's Name:L. WILSON
CAGE:FO148
CAGE:FO148
CAGE:51906
============= Composition/Information on Ingredients =============
Ingred Name:HEXANE. PERCENT: 0.005-0.5
CAS:110-54-3
RTECS #:MN9275000
Fraction by Wt: ING
OSHA PEL:500 PPM
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:NITROGEN
CAS:7727-37-9
RTECS #:QW9700000
Fraction by Wt: 78.7%
ACGIH TLV:ASPHYXIANT
Ingred Name:OXYGEN
CAS:7782-44-7
RTECS #:RS2060000
Fraction by Wt: 20.8%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NONE IDENTIFIED.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:NONE IDENTIFIED.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTF RESP.
IF BREATHING DIFFICULT, GIVE O2. SKIN: FLUSH WITH COPIOUS AMOUNTS
OF WATER. CALL MD . EYES: IMMED FLUSH WITH POTABLE WATER FOR A MIN
IMUM OF 15 MIN, SEEK ASSISTANCE FROM MD. INGEST: CALL MD .
===================== Fire Fighting Measures =====================
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:USE WHAT IS APPROP FOR SURROUNDING FIRE. SM FIRES:
DRY CHEM OR CO2, LG FIRES: WATER SPRAY, FOG OR STD FOAM IS RECOM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CYLINDER MAY EXPLODE IN HEAT OF FIRE.
WITHDRAW IMMED IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE.
================== Accidental Release Measures ==================
Spill Release Procedures:NO SPECIAL PRECAUTIONS IF RELEASED IN WORK
SPACES WITH NORMAL VENTILATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY AREA. DO NOT
PUNCTURE CYLINDER.
Other Precautions:EXPOSURE TO TEMPERATURES ABOVE 150F MAY OPERATE
EXCESS- PRESSURE VALVE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NECESSARY. USE NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST/MECHANICAL(GEN): RECOMMENDED.
Other Protective Equipment:NONE.
Work Hygienic Practices:NO SPECIAL PRACTICES REQUIRED.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Vapor Density:1.0
Spec Gravity:1.29
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS GAS, MAY HAVE FAINT GASOLINE-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS, OIL IN HIGH PRESSURE EQUIPMENT.
Stability Condition to Avoid:NONE IDENTIFIED.
Hazardous Decomposition Products:CO, CO2.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE GAS @ SLOW RATE. DO NOT INCINERATE.
EMPTY CYLINDERS MAY BE DISCARDED AS METAL REFUSE, OBSERVING
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:LUBRIPLATE LITHIUM SERIES, DS-ES
Preparer's Name:ROBERT J. SIBILIA
CAGE:9N579
CAGE:73219
CAGE:9N579
============= Composition/Information on Ingredients =============
Ingred Name:NONHAZARDOUS INGREDIENTS
Other REC Limits:5MG/M3 OIL MIST(MFR)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ZINC COMPOUNDS
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: PROLONGED OR REPEATED SKIN
CONTACT MAY CAUSE IRRITATION. PROUCT CONTACTING EYES MAY CAUSE
IRRITATION. HUMAN HEALTH RISKS VARY FROM PERSONS TO PERSON. AS A
PREC, EXPOSURE TO LIQIDS, VAP, MISTS & FUMES SHOULD BE MINIMIZED.
THIS PRODUCT HAS A LOW ORDER OF ACUTE ORAL TOX, BUT MINUTE AMTS
ASPIRATED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: INTO LUNGS DURING INGESTION MAY CAUSE
MILD TO SEVERE PULMONARY INJURY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/CLEAR WATER FOR AT LEAST 15 MINUTES/UNTIL IRRIT
SUBSIDES. IF IRRIT PERSISTS, CONSULT A PHYS. SKIN: REMOVE ANY
CONTAMD CLTHG & WASH W/SOAP & WARM WATER. IF INJECTED BY HIGH PRESS
UNDER SKI N, REGARDLESS OF APPEAR/ITS SIZE, CONT A PHYS IMMED.
DELAY MAY CAUSE LOSS OF AFFECTED PART OF BODY. INHAL: REMOVE FROM
EXPOS AND CALL A PHYS. INGEST: CALL A PHYS IMMED. DO NOT INDUCE
VOMIT.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>425F,>218C
Lower Limits:0.9%
Upper Limits:7%
Extinguishing Media:FOAM, DRY CHEMICAL, CARBON DIOXIDE OR WATER SPRAY
(FOG).
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . COOL EXPOSED CONTRS W/WATER.
Unusual Fire/Explosion Hazard:DO NOT STORE/MIX WITH STRONG OXIDANTS.
EMPTY CONTAINERS RETAIN RESIDUE. DO NOT CUT, DRILL, GRIND/WELD, AS
THEY MAY EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:SCRAPE UP GREASE, WASH REMAINDER W/SUITABLE
PETROLEUM SOLVENT OR ADD ABSORBENT. KEEP PETROLEUM PRODUCTS OUT OF
SEWERS & WATER COURSES. ADVISE AUTHORITIES IF PRODUCT HAS
ENTERED/MAY ENTER SEWERS AND WA TER COURSES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. DO NOT HANDLE/STORE NEAR HEAT, SPARKS, FLAME/STRONG OXIDANTS.
Other Precautions:REMOVE OIL-SOAKED CLOTHING AND LAUNDER BEFORE REUSE.
CLEANSE SKIN THORO AFTER CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NORMALLY NOT NEEDED. USE NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST: USE TO CAPTURE FUMES AND VAPORS.
Other Protective Equipment:USE OIL-RESISTANT APRON, IF NEEDED.
Work Hygienic Practices:REMOVE OIL-SOAKED CLTHG & LAUNDER BEFORE REUSE.
CLEANSE SKIN THORO AFTER CONTACT.
Supplemental Safety and Health
SPEC GRAV: 0.91-0.94(H*2O=1).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>550F,>288C
Melt/Freeze Pt:M.P/F.P Text:SEMI-SOLID
Vapor Pres:<0.01
Vapor Density:>5
Spec Gravity:SUPDAT
Evaporation Rate & Reference:<0.01(BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:YELLOWISH OFF-WHITE GREASE WITH MINERAL OIL ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDANTS LIKE LIQUID CHLORINE, CONENCTRATED
OXYGEN.
Hazardous Decomposition Products:MAY FORM SO*2. IF INCOMPLETE
COMBUSTION, CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:ASSURE CONFORMITY WITH APPLICABLE DISPOSAL
REGULATIONS. DISPOSE OF ABSORBED MATERIAL AT AN APPROVED WASTE
DISPOSAL FACILITY/SITE. DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL
REGULATIONS .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ANSULITE 3% AFFF (AFC-3-A)
CAGE:EO780
CAGE:03670
CAGE:EO780
============= Composition/Information on Ingredients =============
Ingred Name:FLUOROSURFACTANTS
Fraction by Wt: <80%
Ingred Name:WATER _
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: <80%
Ingred Name:DIETHYLENE GLYCOL MONOBUTYL ETHER (BUTYL CARBITOL)
CAS:112-34-5
RTECS #:KJ9100000
Fraction by Wt: 20%
Ingred Name:HYDROCARBON SURFACTANTS
Fraction by Wt: <80%
Ingred Name:INORGANIC SALT
Fraction by Wt: <80%
===================== Hazards Identification =====================
Effects of Overexposure:IRRITATION OF THE EYES, SKIN AND MUCOUS
MEMBRANES.
======================= First Aid Measures =======================
First Aid:EYE CONTACT: FLUSH/WATER; IF IRRITATION PERSISTS, SEEK
MEDICAL ATTENTION. SKIN CONTACT: WASH WITH SOAP/WATER. INHALATION:
REMOVE VICTIM TO FRESH AIR. INGESTION: IF PATIENT IS CONSCIOUS,
GIVE WATER AND INDUCE VOMITING. SEEK MEDICAL HELP.
===================== Fire Fighting Measures =====================
Flash Point:NONE TO BOILING
Fire Fighting Procedures:THIS IS AN EXTINGUISHING AGENT
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:RINSE FLOOR THOROUGHLY WITH WATER AS MATERIAL
IS SLIPPER. PREVENT MATERIAL FROM REACNG SEWERS OR WATERWAYS TO
AVOID NUISANCE FOAMING.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN ORIGINAL CONTAINER.
Other Precautions:DON'T MIX AGENTS. AVOID SKIN AND EYE CONTACT. AVOID
INGESTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY NECESSARY.
Ventilation:MECHANICAL: RECOMMENDED
Other Protective Equipment:EYE WASH/SAFETY SHOWERS ARE GOOD SAFETY
PRACTICE.
Supplemental Safety and Health
MSDS DATED: 01 JUN 1986.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:97F
Vapor Density:1
Spec Gravity:1.02
Evaporation Rate & Reference:(BU AC = 1): 0.46
Solubility in Water:100%
Appearance and Odor:CLEAR STRAW COLORED LIQUID, MILD SWEET ODOR.
Percent Volatiles by Volume:90%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTIVE METALS/MATERIALS REACTIVE WITH WATER _
Stability Condition to Avoid:ELECTRICALLY ENERGIZED EQUIPMENT
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN COMPLIANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ENAMEL+LACQUER CLEANUP SOLVENT 3939-S
Preparer's Name:PRODUCT MANAGER
CAGE:18873
CAGE:18873
============= Composition/Information on Ingredients =============
Ingred Name:MEDIUM MINERAL SPIRITS VAPOR PRESSURE= 20 MM HG @ 20 C
CAS:64742-88-7
Other REC Limits:DU PONT=100 PPM
Ingred Name:TOLUENE (SARA 313) (CERCLA) (VP = 36.7 @ 20C)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 13%
Other REC Limits:DU PONT=50PPM(8&12HR
OSHA PEL:200 PPM
ACGIH TLV:50 PPM SKIN
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:1,2,4-TRIMETHYLBENZENE VAPOR PRESSURE=7 MM HG @ 44 C
CAS:95-63-6
RTECS #:DC3325000
Fraction by Wt: 0-3%
OSHA PEL:25 PPM
OSHA STEL:25 PPM
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:REPORTS HAVE ASSOCIATED
REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS W/ PERMANENT BRAIN &
NERVOUS SYSTEM DAMAGE.
Effects of Overexposure:INHAL: MAY CAUSE NOSE & THROAT IRRITATION. MAY
CAUSE NERVOUS SYSTEM DEPRESSION, CHARACTERIZED BY THE FOLLOWING
PROGRESSIVE STEPS: HEADACHE, DIZZINESS, NAUSEA, STAGGERING GATE,
CONFUSION, UNCONSCIOUSNE SS. SKIN/ EYE CONTACT: MAY CAUSE
IRRITATION/BURNING OF EYES. REPEATED/PROLONGED LIQUID CONTACT MAY
CAUSE SKIN IRRITATION W/ DISCOMFORT & DERMATITIS.
Medical Cond Aggravated by Exposure:INDIVIDUALS W/ PRE-EXISTING
DISEASES OF THE CNS MAY HAVE INCREASED SUSCEPTABILITY TO THE
TOXICITY OF EXCESSIVE EXPOSURES.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION, PREFERRABLY MOUTH TO MOUTH. IF BREATHING
DIFFICULTY PERSISTS, CONSULT A PHYSICIAN. EYES: FLUSH WITH WATER
FOR 15 MINUTES , LIFTING LIDS TO RINSE ENTIRE EYE. CALL DR IMMED.
SKIN: WASH W/ SOAP & WATER. IF IRRITATION OCCURS, CALL DR.
INGESTION: GI DISTRESS. IN UNLIKELY EVENT OF INGESTION, CALL DR
IMMED & HAVE NAMES OF INGR EDIENTS AVAILABLE.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:20F TO BELOW 73F
Lower Limits:0.9
Upper Limits:7.0
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT W/SCBA. WATER FROM
FOG NOZZLES MAY BE USED TO PREVENT PRESSURE BUILD UP.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE FLASH POINT, EMITS
FLAMMABLE VAPORS WHICH WHEN MIXED W/AIR CAN BURN/EXPLODE. FINE
MISTS/SPRAYS MAY BE FLAMMABLE BELOW FLASH POINT.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. REMOVE SOURCES OF IGNITION.
PREVENT SKIN CONTACT & BREATHING OF VAPOR. CONFINE & REMOVE W/
INERT ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:OBSERVE LABEL PRECAUTIONS. KEEP AWAY
FROM IGNITS. CLOSE CONTAINERS AFTER EACH USE. GROUND CONTAINERS
WHEN POURING. WASH THOROUGHLY AFTER HANDLING & BEFORE EATING OR
SMOKING. DONT STORE ABOVE 120F.
Other Precautions:GROUND CONTAINERS WHEN POURING. DO NOT SAND, FLAME
CUT, BRAISE, WELD DRY COATING WITHOUT NIOSH/MSHA APPROVED
RESPIRATOR OR APPROPRIATE VENTILATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DO NOT BREATHE VAPORS OR MISTS. WEAR PROPERLY
FITTED AIR PURIFYING RESPIRATOR W/ ORGANIC VAPOR CARTRIDGES
(NIOSH/MSHA APPROVED (TC-23C) & PARTICULATE FILTER (NISOH TC-84A)
DURING APPLICATION & UNTIL A LL VAPORS/SPRAY MISTS ARE EXHAUSTED.
FOLLOW RESPIRATOR MANUFACTURER'S DIRECTIONS FOR RESPIRATOR USE.
Ventilation:SUFFICIENT VENTILATION IN VOLUME & PATTERN TO KEEP CONTAM
BELOW APPLICABLE OSHA REGULATIONS.
Other Protective Equipment:COVERALLS. DO NOT USE PROTECTIVE CREAMS FOR
PROTECTION. CREAMS MAY BE USED FOR EASE OF CLEAN UP.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE EATING
OR SMOKING.
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:108 TO 205 C APPROX
Vapor Density:>AIR
VOC Grams/Liter:6.5
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLE FORSEEABLE.
Hazardous Decomposition Products:CO, CO2, SMOKE, OXIDES OF HEAVY METALS
(SEE TOXICOLOGICAL).
=================== Toxicological Information===================
Toxicological Information:TOLUENE: RECURRENT OVEREXPOSURE MAY RESULT IN
LIVER & KIDNEY INJURY. HIGH AIRBORNE LEVELS HAVE PRODUCED IRREGULAR
HEARTBEATS IN AMINALS & OCCASIONAL PALPATATIONS IN HUMANS. RATS
EXPOSED TO VERY HIGH A IRBORNE LEVELS EXHIBITED HIGH FREQUENCY
HEARING DEFICITS. SIGNIFICANCE OF THIS RESEARCH TO MAN UNKNOWN.
CHROMOSOMAL CHANGES IN CIRCULATING BLOOD OF EXPOSED WORKERS HAVE
BEEN REPORTED. THE SIGNIFICANCE OF THESE REPORTS IS UNCLEAR B/C OF
EXPOSURE TO OTHER SUBSTANCES. TOLUENE IS KNOWN TO CAUSE BIRTH
DEFECTS/OTHER REPRODUCTIVE HARM. *CONTINUED UNDER ECOLOGICAL
===================== Ecological Information =====================
Ecological:MEDIUM MINERAL SPIRITS: LAB STUDIES W/ RATS SHOW THAT
PETROLEUM DISTALLETTES CAN CAUSE KIDNEY DAMAGE & KIDNEY/LIVER
TUMORS. THESE EFFECTS NOT SEEN IN SIMILAR STUDIES W/ GHINEA PIGS,
DOGS, OR MONKEYS. STUDIES EVALUATING PETROLEUM WORKERS HAVE NOT
SHOWN A SIGNIFICANT INCREASE OF KIDNEY DAMAGE OR INCREASE IN
KIDNEY/LIVER TUMORS. ECOLOGICAL: DO NOT ALLOW MATERIAL TO
CONTAMINATE GROUNDWATER SY STEMS. INCINERATE ABSORBED MATERIAL IN
ACCORDANCE W/ FED/STATE/LOCAL REQUIREMENTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DONT ALLOW MATERIAL TO CONTAMINATE GROUND WATER
SYSTEMS. INCINERATE ABSORBED MATERIAL IN ACCORDANCE W/FEDERAL,
STATE & LOCAL REGULATIONS. DONT INCINERATE CLOSED CONTAINERS.
===================== Regulatory Information =====================
SARA Title III Information:TOLUENE; I,2,4 TRIMETHYLBENZENE.
State Regulatory Information:WARNING: THIS CHEMCIAL IS KNOWN TO THE
STATE OF CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPRODUCTIVE
HARM.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:3-7-90 TYPE S DEVELOPER REPLENISHER PART B
Kit Part:Y
CAGE:PICKE
CAGE:PICKE
CAGE:8A053
============= Composition/Information on Ingredients =============
Ingred Name:ACETIC ACID (CERCLA)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 30-40%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL; 9596
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 30-40%
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 30-40%
Other REC Limits:NONE RECOMMENDED
Ingred Name:1-PHENYL-3-PYRAZOLIDONE
CAS:92-43-3
RTECS #:UQ8750000
Fraction by Wt: 3-7%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT AS A WHOLE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE CONTACT MAY CAUSE BURNS. VAPOR
IRRITATING TO EYES. SKIN CONTACT CAUSES IRRITATION. HARMFUL IF
SWALLOWED. MAY CAUSE BURNS OF THE GASTROINTESTINAL TRACT.
INHALATION OF VAPOR MAY CAUSE IRRITATION OF UPPER RESPIRATORY
TRACT. CONTAINS ACETIC ACID WHICH MAY PUT PERSONS WHO HAVE CHRONIC
DISEASE AT INCREASED RISK.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE BURNS, SKIN IRRITATION, GI TRACT BURNS,
UPPER RESPIRATORY TRACT IRRITATION.
Medical Cond Aggravated by Exposure:CONTAINS ACETIC ACID WHICH MAY PUT
PERSONS WHO HAVE CHRONIC RESPIRATORY, SKIN OR EYE DISEASE AT AN
INCREASED RISK.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION. IN HALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET
MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GIVE LARGE
AMOUNTS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MD.
===================== Fire Fighting Measures =====================
Flash Point:>200F,>93C
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:ATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL
FOAM.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:FIRE MAY PRODUCE HAZARDOUS AND/OR TOXIC
DECOMPOSITION PRODUCTS.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH TO SEWER WITH LARGE AMOUNT OF WATER IF
ALLOWABLE. MAY REQUIRE NEUTRALIZATION IF PH BELOW 3 OR ABOVE 12.
OTHERWISE ABSORB SPILL WITH VERMICULITE OR OTHER SUITABLE ABSORBENT
AND PLACE IN IMPERVIOU S CONTAINER FOR DISPOSAL. REMOVE RESIDUAL.
Neutralizing Agent:SODIUM BICARBONATE (BAKING SODA).
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND
CLOTHING. STORE BETWEEN 10-25 C(50-80F). PROTECT SHIPMENTS FROM
FREEZING (KEEP ABOVE 40F).
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ORGANIC VAPOR, ACID GAS.
IF RESPIRATORS ARE USE D, A PROGRAM SHOULD BE INSTITUTED.
Ventilation:GOOD GENERAL VENTILATION (10 ROOM VOLUMES PER HOUR) SHOULD
BE SUFFICIENT TO CONTROL AIRBORNE LEVELS BELOW EXPOSURE LIMIT
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
KEY1:C4. WASH CONTAMINATED CLOTHING BEFORE REUSE. DISCARD CONTAMINATED
SHOES.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:1.1
pH:2
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:ORANGE/BLACK LIQUID, PUNGENT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, BASES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
OXIDES OF NITROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PLCD2-3X, PLASMA STD, 10,000 PPM CADMIUM IN 5% NITRIC ACID
Resp. Party Other MSDS Num.:PLCD2/CLCD2
Preparer's Name:SUSHA RAMONE
CAGE:07977
CAGE:04XT3
CAGE:07977
============= Composition/Information on Ingredients =============
Ingred Name:NITRIC ACID; (HNO*3)
CAS:7697-37-2
RTECS #:QU5775000
Minumum % Wt:2.
Maxumum % Wt:5.
OSHA PEL:5 MG/M3;2 PPM
ACGIH TLV:5.2 MG/M3;2 PPM
ACGIH STEL:10 MG/M3;4 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:CADMIUM NITRATE TETRAHYDRATE; (CD)LD50: (ORAL, RAT) 225
MG/KG
CAS:10022-68-1
RTECS #:EV1850000
Minumum % Wt:.1
Maxumum % Wt:1.
ACGIH TLV:0.05MG/M3(AS CD TWA)
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Minumum % Wt:94.
Maxumum % Wt:97.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:CORROSIVE. HARMFUL BY INGESTION.
IRRITATING TO THE EYES AND SKIN UPON CONTACT. MAY CAUSE CANCER
(ACCORDING TO OSHA, IARC, NTP).
Explanation of Carcinogenicity:CADMIUM NITRATE: IARC MONOGRAPHS, VOL
58, PG 119, 1993:GROUP 1; NTP 8TH ANNUAL REPORT ON CARCINOGENS:
KNOWN CARCINOGEN; OSHA REGULATED: 29 CFR 1910.1027.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:GENERAL: REMOVE CONTAMINATED CLOTHING, WASH THOROUGHLY BEFORE
REUSE. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER AND LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING
AND FLUSH WITH WATER THOROUGHLY. INHALATION: MOVE TO FRESH AIR.
CONSULT DOCTOR IF SYMPTOMS PERSIST. INGESTION: GET IMMEDIATE
MEDICAL HELP. IF THE PATIENT IS CONSCIOUS, GIVE LARGE QUANTITIES OF
WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:OXIDES OF NITROGEN CAN BE RELEASED IN
CASE OF FIRE. NOT EXPLOSIVE. NOT SELF-IGNITING.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. WEAR PROT EQUIP. DO NOT ALLOW
TO ENTER DRAINAGE SYSTEMS OR WATER WAYS. DILUTE SPILL W/WATER &
NEUTRALIZE WITH SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED
CONTAINER FOR PROPER D ISPOSAL. WASH SPILL SITE W/WATER AFTER
MATERIAL PICK UP IS COMPLETE. WEAR CHEMICAL RESISTANT GLASSES,
Neutralizing Agent:SODA ASH, LIMESTONE, ETC.
======================Handling and Storage ======================
Handling and Storage Precautions:ENSURE GOOD VENTILATION/EXHAUSTION AT
WORK PLACE. HAVE AN IMMEDIATE AVAILABILITY OF AN EYE WASH IN CASE
OF EMERGENCY. STORE AT ROOM TEMPERATURE. KEEP THE CONTAINER TIGHTLY
CLOSED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN CASE OF BRIEF EXPOSURE, USE NIOSH APPROVED
RESPIRATOR.
Ventilation:USE UNDER A FUME HOOD.
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR PROTECTIVE APRON.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: IN 5% NITRIC ACID.
================== Physical/Chemical Properties ==================
Boiling Pt:=100.C, 212.F
Spec Gravity:APPROX 1
pH:1 TO 2
Solubility in Water:MISCIBLE
Appearance and Odor:TRANSPARENT LIQUID WITH AN ACRID ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS WITH STRONG ALKALI, VARIOUS METALS, AND ORGANIC SUBSTANCES.
Stability Condition to Avoid:STABLE UNDER NORMAL STORAGE AND USE.
Hazardous Decomposition Products:TOXIC FUMES UNDER CONDITIONS OF FIRE.
=================== Toxicological Information===================
Toxicological Information:MAY PRDCE CAUSTIC EFFECT ON SKIN, MUC MEMBS &
EYES. SWALLOWING WILL LEAD TO A STRONG CAUSTIC EFFECT ON MOUTH &
THROAT & TO THE DANGER OF PERFORATION OF ESOPHAGUS & STOMACH.
CADMIUM COMPOUNDS (PURE) AR E CONSIDERED TO BE CARCINOGENIC
ACCORDING TO OSHA, NTP, & IARC. INCREASED INCIDENCE OF PROSTATIC
CANCER HAS BEEN REPORTED FOLLOWING EXPOS TO CADMIUM & ITS SALTS.
EXPERIMENTAL TUMORIGEN, & NEOPLASTIGEN . TOXICITY DATA:
CONCENTRATED HNO*3-RTECS #QU57775000; ORL-HMN LDLO:430 MG/KG' LDLO:
110 MG/KG. CD-RTECS #EU9800000; ORL-RAT LD50: 225 MG/KG; UNK-MAN
LDLO: 15 MG/KG.
===================== Ecological Information =====================
Ecological:DO NOT ALLOW PRODUCT TO REACH GROUND WATER, WATER BODIES OR
SEWAGE SYSTEM.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTACT LOCAL HAZARDOUS CHEMICAL WASTE DISPOSAL
AGENCY FOR FEDERAL, STATE AND LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:TRANSPORT INFO - AIR: CLASS 8. UN/ID #3264.
PACKING GROUP: III. PROPER SHIPPING NAME: CORROSIVE LIQUID, ACIDIC,
INORGANIC, N.O.S. (NITRIC ACID SOLUTION). GROUND: CLASS 8. UN/ID
NUMBER: 3264. PACKING G ROUP: III. PROPER SHIPPING NAME: CORROSIVE
LIQUID, ACIDIC, INORGANIC N.O.S. (NITRIC ACID SOLUTION).
===================== Regulatory Information =====================
SARA Title III Information:SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OF SARA TITLE III & OF 40 CFR 372.
Federal Regulatory Information:COMPONENTS OF THIS SOLN ARE REPORTED IN
EPA TSCA INVENTORY LIST. WHMIS CLASSIFICATION (CANADA): CLASS D &
CLASS E. EC GUIDELINES: C: CORR. RISK PHRASES: 22-HARMFUL IF
SWALLOWED. 34-CAUSES BURNS. 36/37 /38-IRRIT TO EYES, RESP SYS &
SKIN. 48/21-HARMFUL; DANGER OF SERIOUS DMG TO HLTH BY PRLNGD EXPOS
IN CNTCT W/SKIN. SFTY PHRASES: 36/37/37:WEAR SUITABLE PROT CLTHG,
W/PLENTY OF WATER & SEEK MED ATTN. 45-IN CASE OF ACCIDENT/IF YOU
FEEL UNW ELL, SEEK MED ADVICE IMMED. 53:AVOID EXPOS-OBTAIN SPEC
INSTRUCTION BEFORE USE. NOTE:RESTRICTED TO PROFESSIONAL USERS.
State Regulatory Information:THIS SOLUTION CONTAINS CHEMICAL(S) KNOWN
TO CAUSE CANCER ACCORDING TO THE STATE OF CALIFORNIA (PROPOSITION
65).
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ACTIVATOR ORANGE 12197 PN U3-002, PART B
Kit Part:Y
Preparer's Name:DAVID SCHMETTERER
CAGE:DO165
CAGE:DO165
CAGE:5V430
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ETHYL KETONE (SARA III) (VAPOR PRESSURE 71.2 MM HG)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 40%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM
ACGIH TLV:200 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:NONYLPHENOL (CONTAINS A TRACE OF PHENOL, CAS # 108-95-2,
WHICH HAS A TLV VALUE OF 5 PPM) (VAPOR PRESSURE 0.9 MM HG)
CAS:25154-52-3
RTECS #:SM5600000
Fraction by Wt: 15%
Other REC Limits:NONE SPECIFIED
Ingred Name:METAL XYLENE DIAMINE
CAS:1477-55-0
RTECS #:PF8970000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
ACGIH TLV:0.1 MG/M3
Ingred Name:AMINE ADDUCT
CAS:68738-77-2
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:CRYSTALLINE SILICA
CAS:14464-46-1
RTECS #:VV7325000
Fraction by Wt: <0.1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.05 MG/M3 RDUST9293
Ingred Name:RED PIGMENT 48 (PRODUCT CONTAINS PROPRIETARY AMOUNT OF
MANGANESE CAS # 7439-96-5)
CAS:5280-66-0
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:SILICON DIOXIDE (MAY BE RELEASED BY SANDING DRIED PAINT
FILM)
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 30%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
Ingred Name:VOC: 464 GPL.
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:YES
Health Hazards Acute and Chronic:OVEREXPOSURE: ACUTE TOXICITY,
RESULTING IN HEADACHE, DIZZINESS, NAUSEA, LOSS OF CONSCIOUSNESS.
SEVERE EYE IRRITATION POSSIBLY RESULTING IN PERMANENT DAMAGE.
IRRITATED MUCOUS MEMBRANES. VOMITING DUE TO INGESTION. DEFATTING
AND DRYING OF THESKIN. SENSITIZATION AFTER REPEATED CONTACT.
Explanation of Carcinogenicity:THERE IS LIMITED EVIDENCE OF
CARCINOGENICITY OF CRYSTALLINE SILICA TO HUMANS.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/CLEAN LUKEWARM LOW PRESSURE WATER 15 MIN,
LIFTING EYELIDS. GET MED AID. INHAL: REMOVE TO FRESH AIR. PROVIDE
OXYGEN IF BREATHING DIFFICULT. GIVE ARTIF RESPIRATION IF NOT
BREATHING. GET MEDAID. KEEP WARM & COMFORTABLE. NEVER GIVE
UNCONSCIOUS PERSON LIQUIDS. INGEST: CALL DR. INDUCE VOMIT ONLY ON
INSTRUCT OF DR. IF VOMIT OCCURS, KEEP HEAD BELOW HIPS (PREVENT
ASPIRATION OF LIQ INTO LUNG)*
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:22.0F,-5.6C
Lower Limits:2
Extinguishing Media:FOAM, CO2, OR DRY CHEMICAL.
Fire Fighting Procedures:USE WATER TO KEEP EXPOSED CONTAINERS COOL, &
TO KEEP FLAMMABLE STRUCTURES WET. DO NOT ENTER FIRE AREA W/O
PROTECTION BECAUSE HAZARD DECOMP PROD MAY BE PRESENT.
Unusual Fire/Explosion Hazard:WATER PRESSURE MAY SPREAD A FLAMMABLE
LIQUID FIRE. SEALED CONTAINERS MAY EXPLODE IF OVERHEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:WARNING - FLAMMABLE. ELIMINATE ALL IGNITION
SOURCES. HANDLING EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING.
SOAK UP W/ABSORBENT & PLACE IN NON-LEAKING CONTAINERS. SEAL TIGHTLY
FOR PROPER DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:HAZARD-FLAMMABLE. KNOW DOT REGS BEFORE
TRANSPORTING. WARNING: HOT ORGANIC CHEMICAL VAPORS/MISTS MAY
SPONTANEOUSLY COMBUST WHEN MIXED W/AIR.
Other Precautions:IGNITION MAY OCCUR AT TEMPS BELOW PUBLISHED
AUTOIGNIT/IGNIT TEMPS. IGNITION TEMPS DECREASE W/INCREASING VAPOR
VOLUME & VAPOR/AIR CONTACT TIME & ARE INFLUENCED BY PRESSURE
CHANGES. IGNIT MAY OCCUR AT T YPICAL ELEVATED TEMP PROCESS
CONDITION**
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IMPORTANT-MUST PROVIDE VENT TO MAINTAIN VAPOR
CONCENTRATIONS BELOW ESTABLISHED TLV LIMIT. IN CONFINED AREAS
NIOSH/MSHA RESPIRATOR EQUIPPED WITH ORGANIC VAPOR CARTRIDGE SHOULD
BE WORN.
Ventilation:MUST PROVIDE VENTILATION.
Other Protective Equipment:HAVE EYE BATH AND SAFETY SHOWER AVAILABLE.
Supplemental Safety and Health
**ESP IN PROCESS OPERATING UNDER VACUUM IF SUBJECTED TO SUDDEN INGRESS
OF AIR/OUTSIDE PROCESS EQUIP OPERATING UNDER ELEVATED PRESSURE IF
SUDDEN ESCAPE OF VAPORS/MISTS TO ATMOSPHERE OCCURS. PROPOSED US E
OF PROD IN ELEVATED TEMP PROCESSES SHOULD BE EVALUATED TO ASSURE
SAFE OPERATING CONDIIONS ESTABLISHED/MAINTAINED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:174 TO 567F
Vapor Density:> AIR.
Spec Gravity:1.14
Viscosity:>200 CENTI
Evaporation Rate & Reference:4.61 X N-BUTYL ACETATE
Solubility in Water:SLIGHT
Appearance and Odor:ORANGE LIQUID, SOLVENT ODOR
Percent Volatiles by Volume:57.7
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY BE INCOMPATIBLE WITH OXIDIZING AGENTS AND STRONG ALKALIES.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES, AND
INCOMPATIBILITIES.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS
LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER
TOXIC GASES.
Conditions to Avoid Polymerization:AVOID HEAT, SPARKS, OPEN FLAMES, AND
INCOMPATIBILITIES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORD W/LOCAL, STATE & FED
REGS. CONTACT APPRV'D DISPOSAL FACILITY.
* SKIN: FLUSH W/WATER WHILE REMOVING CONTAM
CLOTH, SHOES. WA SH W/SOAP & WATER. IF IRRIT PERSISTS, GET MED AID.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SULFITE TITRETS, K-9610
CAGE:7K791
CAGE:7K791
============= Composition/Information on Ingredients =============
Ingred Name:TITRET, CONTAINING INGREDIENTS 1 - 4
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ACETIC ACID, (ETHYLENEDINITRILO)TETRA-, DISODIUM; (DISODIUM
ETHYLENEDIAMINE TETRAACETATE)
CAS:6381-92-6
RTECS #:AH4410000
Fraction by Wt: <1.0%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:THYODENE
CAS:9005-84-9
Fraction by Wt: <3.0%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER; (DEIONIZED WATER)
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: >95.0%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:OTHER COMPONENTS
Fraction by Wt: <1.0%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:PHOSPHORIC ACID (SARA 313) (CERCLA) (IN THE VALVE ASSEMBLY)
CAS:7664-38-2
RTECS #:TB6300000
Fraction by Wt: 100%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3/3 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IN THE TITRET: ACUTE/CHRONIC: NONE
KNOWN. IN THE VALVE ASSEMBLY: ACUTE: IRRITATION AND BURNS. CHRONIC:
IRRITATION AND SENSITIZATION DERMATITIS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:IN TITRET: MAY CAUSE IRRITATION TO
THE SKIN AND EYES. IN VALVE ASSEMBLY: MAY CAUSE IRRITATION TO THE
SKIN, EYES AND MUCOUS MEMBRANES. MAY CAUSE REDNESS, PAIN AND BURNS.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15
MINUTES. INGESTION: SEEK MEDICAL ATTENTION. INHALATION: REMOVE
INDIVIDUAL TO FRESH AIR.
===================== Fire Fighting Measures =====================
Extinguishing Media:IN TITRET: WATER. IN VALVE ASSEMBLY: DRY CHEMICAL,
CARBON DIOXIDE, WATER SPRAY OR FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. PLACE IN
SMALL CONTAINERS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:PROD SHOULD BE STORED IN THE DARK & AT
ROOM TEMP; HOWEVER, TEMPERATURES UP TO 120F/EVEN BELOW FREEZING
WILL NOT NORMALLY AFFECT REAGENT PERFORMANCE.
Other Precautions:IF THIS PRODUCT IS USED AS DIRECTED, THE USER WILL
NOT COME IN CONTACT WITH OR BE EXPOSED TO ANY OF ITS CHEMICAL
COMPONENTS. AVOID CONTACT WITH EYES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
BP: IN TITRET: 212F,100C. IN VALVE ASSEMBLY: 316F,158C. SPEC GRAV
(H*2O=1): IN TITRET: 1.0. IN VALVE ASSEMBLY: 1.68. VP: IN TITRET:
N/A. IN VALVE ASSEMBLY: 2.2 @ 21C. MP: IN TITRET: 32F,0C. IN VALVE
A SSEMBLY: 69.8F,21C. VAP DENS: IN TITRET: N/A. IN VALVE ASSEMBLY:
N/K. PH: IN TITRET: 10. IN VALVE ASSEMBLY: 1.5.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SUP DAT
Melt/Freeze Pt:M.P/F.P Text:SUP DAT
Vapor Pres:SUP DAT
Vapor Density:SUP DAT
Spec Gravity:SUP DAT
pH:SUPDAT
Solubility in Water:COMPLETE
Appearance and Odor:TITRET: COLORLESS LIQ, NO ODOR. VALVE ASSEMBLY:
COLORLESS SYRUPY LIQ, NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:IN TITRET: NONE. IN VALVE ASSEMBLY:
TOXIC FUMES OF OXIDES OF PHOSPHOROUS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:XEROX 1035/2830 DEVELOPER, 82-0042-893 4025
CAGE:FO912
CAGE:FO912
CAGE:47811
============= Composition/Information on Ingredients =============
Ingred Name:TONER CONSISTING OF INGREDIENTS 2-6
RTECS #:9999999ZZ
Fraction by Wt: < 5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:STYRENE, ACRYLATE COPOLYMER
CAS:25213-39-2
Fraction by Wt: 88-96%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CARBON BLACK
CAS:1333-86-4
RTECS #:FF5800000
Fraction by Wt: 5-15%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:PROPENE POLYMERS; (POLYOLEFIN)
CAS:9003-07-4
RTECS #:UD1842000
Fraction by Wt: < 5%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:AMORPHOUS SILICA
CAS:112945-52-5
RTECS #:VV7310000
Fraction by Wt: < 1%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ZINC STEARATE
CAS:557-05-1
RTECS #:ZH5200000
Fraction by Wt: < 1%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:CARRIER CONSISTING OF INGREDIENT 8.
RTECS #:9999999ZZ
Fraction by Wt: < 95%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:IRON NICKEL ZINC OXIDE; (FERRITE POWDER)
CAS:12645-50-0
RTECS #:NO7118000
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MIN RESP TRACT IRRIT MAY OCCUR AS
W/EXPOSURE TO LRG AMTS OF NON-TOX DUST. NON TOXIC. IN XEROX
SPONSERED CHRONIC INHAL STUDY IN RATS USING A SPECIAL TEST TONER,
THERE WERE NO LUNG CHANGES @ ALL IN LOWE ST EXPOS LEVEL (1 MG/M3).
THE MOST RELEVANT LEVEL TO POTENTIAL HUMAN EXPOSURES. A VERY SLIGHT
DEGREE OF(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:FIBROSIS WAS OBSERVED @ THE HIGHEST
EXPOS LEVEL (16 MG/M3) IN ALL ANIMALS. THESE FINDINGS ARE
ATTRIBUTED TO LUNG OVERLOADING, A GENERIC RESPONSE TO EXCESSIVE
AMTS OF ANY DUST RETAINED IN LUNG S FOR A PRLNGD INTERVAL. THE
SPECIAL TEST TONER WAS TEN TIMES MORE RESP THAN COMMERCIALLY AVAIL
TONERS TO (SUPP DATA)
Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY
PRODUCT LITERATURE.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MIN. SKIN: WASH WITH
SOAP AND WATER. INHAL: REMOVE FROM EXPOSURE. INGEST: DILUTE STOMACH
CONTENTS W/SEVERAL GLASSES OF WATER.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:AVOID INHALATION OF SMOKE. WEAR NIOSH/MSHA
APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER, WHEN
DISPERSED IN AIR, IT FORMS EXPLOSIVE MIXTURES.
================== Accidental Release Measures ==================
Spill Release Procedures:IF SPILLED, SWEEP UP OR VACUUM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE.
Other Precautions:AVOID PROLONGED INHALATION OF EXCESSIVE DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHEN USED AS INTENDED IN COPIER OR
PRINTER EQUIPMENT. NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP: COMPLY WITH EPA TESTING PROTOCOL AND WOULD NOT
FUNCTION PROPERLY IN A COPIER OR PRINTING EQUIPMENT.
================== Physical/Chemical Properties ==================
Spec Gravity:1 (H*2O=1)
Appearance and Odor:BLACK GRANULAR/FAINT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE TOXIC.
AVOID BREATHING SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT INCINERATE. NO SPECIAL TECHNIQUES BEYOND
NORMAL PRACTICE. INSURE CONFORMITY WITH FEDERAL, STATE OR LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:WATER REDUCIBLE LOW BAKE TEXTURE ENAMEL (SU
CAGE:54636
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:SUPP DATA:DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED IN
ING SECTION, APPLIC LIMITS FOR NUISANCE DUSTS ARE (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:ACGIH TLV 10 MG/M3 (TOTAL DUST), 5 MG/M3 (RESPIRABLE
FRACTION).
RTECS #:9999999ZZ
Ingred Name:VENT:EXPOSURE LIMITS. REFER TO OSHA STANDARDS 1910.94,
1910.107, 1910.108.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP:ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL
ETHER (EGBE) & ETHYLENE GLYCOL MONOBUTYL ETHER (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:ACETATE (EGBEA). (EXTRACTED FROM DHHS (NIOSH)
PUBLICATION NO. 90-118) .
RTECS #:9999999ZZ
Ingred Name:RESP PROT:APPROVED BY NIOSH/MSHA FOR DUST WHICH MAY BE
GENERATED FROM THIS PRODUCT, UNDERLYING PAINT, OR THE ABRASIVE.
RTECS #:9999999ZZ
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL). VP:0.6
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 5%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
Ingred Name:ETHANOL, 2-(2-BUTOXYETHOXY)-;(2-(2-BUTOXYETHOXY)-ETHANOL).
VP:0.1
CAS:112-34-5
RTECS #:KJ9100000
Fraction by Wt: <5%
Ingred Name:PHTHALIC ACID, DIBUTYL ESTER; (DIBUTYL PHTHALATE) (SARA
III)
CAS:84-74-2
RTECS #:TI0875000
Fraction by Wt: <5%
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS;(TALC)
CAS:14807-96-6
RTECS #:MW2710000
Fraction by Wt: 0-20%
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 0-25%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF EYES, SKIN AND
UPPER RESPIRATORY SYSTEM. IN CONFINED AREA VAPORS IN HIGH
CONCENTRATIONS MAY CAUSE HEADACHE, NAUSEA OR DIZZINESS. REDNESS AND
ITCHING/BURNING SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOSURE.
PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS IN ING SECTION MAY
CAUSE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:ADVERSE EFTS TO LIVER, URINARY, &
BLOOD FORMING SYS. RATS EXPOSED TO TITANIUM DUST AT 250 MG/M3
DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOS LEVELS ARE NOT
ATTAINABLE IN WORKPLACE. ANIMALS STUD IES HAVE CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD,
KIDNEYS, & LIVER (ING 9)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY WITH SOAP
AND WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
EYES:FL USH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. GET MEDICAL ATTENTION. INGEST:CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>199F,>93C
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZ ARE
PREF. WATER MAY BE USED TO COOL (SUPP DATA)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNR CLSD WHEN NOT IN USE.
TRANFER ONLY TO APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT
TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:USE ONLY W/ADEQ VENT.AVOID BRTHG VAP & SPRAY
MIST.AVOID CNTCT W/SKIN & EYES. THIS COATING CONTAINS MATLS
CLASSIFIED AS NUISANCE PARTICULATES, SUCH AS TITANIUM
DIOXIDE/CALCIUM CARBONATE (SEE ACGIH TLV LIST, PREFACE & APPENDIX
D), (SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMITS BY VENT, WEAR PROPERLY FITTED ORGANIC VAP/PARTICULATE
RESP APPRVD BY NIOSH/MSHA FOR PROT AGAINST MATLS IN ING SECTION.
WHEN SANDING/ABRADING DRIED FILM, WEAR DUST/MIST RESP (ING 11)
Ventilation:LOCAL EXHAUST PREF. GENERAL EXHAUST ACCEPTABLE IF EXPOS TO
MATLS IN ING SECTION IS MAINTAINED BELOW APPLIC (ING 8)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO.:NON-LEAD COLORS WHITE, F73 W 562. FIREFIGHTERS
PROC:CLSD CNTNRS TO PRVNT PRESS BUILD-UP & POSS AUTOIGNITION/EXPLO
WHEN EXPOSED TO EXTREME HEAT. OTHER PREC:WHICH MAY BE PRESENT AT
HAZ LEVELS ONLY DURING SANDING/ABRADING OF (ING 6)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:1.08-1.27
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:60-64%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THIS PROD IS NOT HAZ AS DEFINED UNDER
THE RESOURCE CONSERVATION AND RECOVERY ACT (RCRA) 40 CFR 261. INCIN
IN APPROVED FACILITY. DO NOT INCINERATE CLOSED CONTAINER. DISPOSE
OF IN ACCORD W/FE DERAL, STATE, & LOCAL REGS REGARDING POLLUTION.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:FAULT-FINDER DEVELOPER 1033
CAGE:92381
CAGE:92381
============= Composition/Information on Ingredients =============
Ingred Name:SYNTHETIC SILICATE POWDERS
Fraction by Wt: 5%
Ingred Name:SOLVENT ALCOHOL
Fraction by Wt: 10%
ACGIH TLV:400 PPM
Ingred Name:KETONES
Fraction by Wt: 35%
ACGIH TLV:200 PPM
Ingred Name:HALOGENATED HYDROCARBONS PROPELLANT
Fraction by Wt: 50%
ACGIH TLV:1000 PPM
===================== Hazards Identification =====================
Effects of Overexposure:IRRITATION OF
NOSE/THROAT,EYES.HEADACHE,NAUSEA,DIZZINESS.POSSIBLE
NARCOSIS,POSSIBLE CARDIAC ARRHYTHM
======================= First Aid Measures =======================
First Aid:REMOVE TO FRESH AIR,CALL A DOCTOR.GIVE ARTIFICIAL RESPIRATION
IF NECESSARY.DO NOT GIVE EPINEPHRINE OR SMILAR DRUGS.IF SWALLOWED
INDUCE VOMITING,CALL A DOCTOR.SKIN OR EYE CONTACT:FLUSH WELL WITH
WATER.
===================== Fire Fighting Measures =====================
Flash Point:25F-65F TOC
Extinguishing Media:CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRE.TYPE
FOAM.
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:TREAT CONTAINERS AS CYLINDERK OF
COMPRESSED GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH SPILL AWAY WITH WATER
======================Handling and Storage ======================
Handling and Storage Precautions:AEROSOL CONTAINER.DO NOT STORE IN
DIRECT SUNLIGHT, NEAR OPEN FLAME OR RADIATOR.
Other Precautions:DO NOT STORE AT TEMPERATURES OVER 120F.AVOID
EXCESSIVE INHALATION.
============= Exposure Controls/Personal Protection =============
Ventilation:LOCAL-YES, GENERAL-YES
Other Protective Equipment:EYE BATH;SAFETY SHOWER.
Supplemental Safety and Health
THIS PRODUCT 1033 IS ONE OF THREE PRODUCTS WHICH MAKE UP AN INSPECTION
PENETRANT KIT GROUP VII.THE OTHER TWO PRODUCTS ARE 1032 AND
1031WHICH ARE PENETRANT AND CLEANER RESPECTIVELY.
================== Physical/Chemical Properties ==================
HCC:V3
Boiling Pt:B.P. Text:175
Vapor Density:2.5
Spec Gravity:0.806
Evaporation Rate & Reference:5.7-BUTYL ACETATE
Solubility in Water:26.8
Appearance and Odor:CLEAR LIQUID,NONRESIDUAL ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTAMINATION WITH ALKALIS
Stability Condition to Avoid:OPEN FLAMES OR SPARKS.
==================== Disposal Considerations ====================
Waste Disposal Methods:AEROSOL CONTAINER:DO NOT PUNCTURE OR
INCINERATE.WHEN LIQUID IS ALL EXPELLED,CONTINUE TO DEPRESS BUTTON
UNTIL ALL GAS IS EXPELLED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:EASYPOXY K-45 PART A RESIN
Kit Part:Y
Preparer's Name:MARVIN A FRIEDMAN
CAGE:DO146
CAGE:DO146
INC.
CAGE:16245
============= Composition/Information on Ingredients =============
Ingred Name:BISPHENOL A-EPICHLOROHYDRIN COPOLYMER
CAS:25068-38-6
RTECS #:SL6475000
Fraction by Wt: 90-100%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:GLYCERIN (GLYCEROL)
CAS:56-81-5
RTECS #:MA8050000
Fraction by Wt: <1%
OSHA PEL:15 MG/M3 (MIST)
ACGIH TLV:10 MG/M3 (MIST)
Ingred Name:SILICA, FUMED.
CAS:7631-86-9
Fraction by Wt: 0-10%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGRDIENTS
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:ALLERGIC SKIN RXNS/PRIMARY SKIN
IRRIT MAY BE PRDCED BY PRLNGD/RPTD DERM CONT W/EPOXY RESINS.
OVEREXP TO VAP DURING HEAT CURING MAY CAUSE IRRIT/INJURY OF RESP
TRACT & EYE IRRIT. DIRECT CONT W/THI S MATL MAY CAUSE MOD EYE &
SKIN IRRIT. TOX INFO ON OSHA REGULATED COMPONENTS OF PROD IS AS
FOLLOWS: (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:PRLNGD/RPTD DERM EXPOS TO EPOXY RESINS
MAY PRDCE ALLERGIC SKIN RXNS/PRIMARY SKIN IRRIT. GLYCERINE:EYE/SKIN
CONT WILL PRDCE MILD IRRIT. INHAL OF MIST COULD CAUSE RESP IRRIT.
AMORPHOUS SILICA:O VEREXP TO SYNTHETIC AMORPHOUS SILICA DUST BY
INHAL, ABSORP/INGEST IS NOT EXPECTED TO CAUSE ADVERSE EFFECTS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . SKIN:IMMED WASH AFFECTED
AREAS W/SOAP & PLENTY OF WATER. REMOVE CONTAMD CLTHG & SHOES. OBTA
IN MED ATTN. DESTROY/THORO CLEAN SHOES BEFORE REUSE. DO NOT REUSE
CONTAMD CLTHG W/OUT LAUNDERING. EYE:IMMED IRRIGATE W/PLENTY OF
WATER FOR @ LEAST 15 MINS. OBTAIN MED ATTN IF IRRIT PERSISTS.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:>212F,>100C
Extinguishing Media:USE WATER SPRAY, CARBON DIOXIDE OR DRY CHEMICAL TO
EXTINGUISH FIRES.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER TO KEEP CONTAINERS COOL.
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION OR COMBUSTION MAY
PRODUCE PHENOLICS AND OXIDES OF CARBON.
================== Accidental Release Measures ==================
Spill Release Procedures:WHERE EXPOS LEV IS NOT KNOWN, WEAR NIOSH/MSHA
APPRVD, POS PRESS, SELF-CONTAINED RESP. WHERE EXPOS LEV IS KNOWN,
WEAR NIOSH/MSHA APPRVD RESP SUITABLE FOR LEV OF EXPOS. IN ADDN TO
PROT CLTHG/EQUIP IN EX POS CTLS/PERSONAL PROT SECTION, WEAR
(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONT W/EYES. AVOID PRLNGD/RPTD
CONT W/SKIN. WASH THOROUGHLY AFTER HANLDING.
Other Precautions:CUTTING, GRINDING, OR SANDING OF PARTS FABRICATED
AFTER CURING OF THIS MATL MAY CREATE RESPIRABLE DUST PARTICLES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE EXPOS ARE BELOW PEL, NO RESP PROT IS REQD.
WHERE EXPOS EXCEED PEL, USE RESP APPRVD BY NIOSH/MSHA FOR MATL &
LEV OF EXPOS. A NIOSH/MSHA APPRVD FULL FACEPIECE RESP WILL PROVIDE
EYE & FACE PROT.
Ventilation:WHERE MATL IS NOT USED IN CLSD SYS, GOOD ENCLOSURE & LOC
EXHAUST VENT SHOULD BE PROVIDED TO CTRL EXPOS WHEN (SUPDAT)
Other Protective Equipment:APRON, WORKPANTS, LONG SLEEVE WORK
SHIRT/DISP COVERALLS. BARRIER CREAMS. ANSI APPRVD EMER EYE WASH &
DELUGE (SUPDAT)
Work Hygienic Practices:FOOD, BEVERAGES, & TOBACCO PRODS SHOULD NOT
CARRIED, STORE/CONSUMED WHERE MATL IS IN USE. BEFORE EATING,
(SUPDAT)
Supplemental Safety and Health
SPILL RELEASE PROC:IMPERVIOUS BOOTS. COVER SPILLS W/SOME INERT ABSORB
MATL; SWEEP UP & PLACE IN WASTE DISP CNTNR. FLUSH AREA W/WATER.
VENT:SPRAYING/CURING @ ELEVATED TEMPS. HYGIENE PRACT:DRINKING/SMKN
G, WASH FACE & HANDS W/SOAP & WATER. EYE PROT:FULL LENGTH
FACESHIELD . OTHER PROT EQUIP:SHOWER .
================== Physical/Chemical Properties ==================
Spec Gravity:1.2
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:NOT KNOWN
Appearance and Odor:MILKY VISCOUS LIQUID, CHARACTERISTIC ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIS, BASES AND AMINES.
Stability Condition to Avoid:AVOID EXCESSIVE HEATING OVER LONG PERIODS
OF TIME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION
MAY PRODUCE PHENOLICS AND OXIDES OF CARBON.
Conditions to Avoid Polymerization:AVOID ACIDS, BASES OR AMINES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W APPLICALBLE FEDERAL,
STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PR-1764 B-1, PART A
CAGE:DO563
CAGE:83574
CAGE:DO563
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM DICHROMATE
CAS:13423-61-5
Fraction by Wt: 20%
OSHA PEL:0.1 PPM (CRO*3), C
ACGIH TLV:0.05 MG (CR)/M3
Ingred Name:MANGANESE DIOXIDE
CAS:1313-13-9
RTECS #:OP0350000
Fraction by Wt: 35%
OSHA PEL:5 MG (MN)/M3, C
ACGIH TLV:5 MG (MN)/M3
Ingred Name:XYLENE
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 5%
OSHA PEL:100 PPM;150 PPM STEL
ACGIH TLV:100 PPM;150 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:GUANIDINE, 1,3-DIPHENYL-; (DIPHENYL GUANIDINE)
CAS:102-06-7
RTECS #:MF0875000
Fraction by Wt: <5%
Ingred Name:TERPHENYLS, HYDROGENATED
CAS:61788-32-7
RTECS #:WZ6535000
Fraction by Wt: 30%
OSHA PEL:0.5 PPM
ACGIH TLV:0.5 PPM
Ingred Name:SILICON DIOXIDE
CAS:67762-90-7
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: STRONG IRRIT. MAY CAUSE EYE
DAMAGE. SKIN: IRRIT. MAY CAUSE ALLERGIC SKIN RASH IN SENSITIZED
INDIVIDUALS. PROLONGED EXPOSURE TO HEXAVALENT CHROMIUM COMPOUNDS
OVER PEL MAY CAUSE PAINLESS PENETRATI NG ULCERS OF SKIN. INHAL &
INGEST: ALGHOUGH MAIN HAZ OF MANGANESE COMPOUNDS IS BY BREATHING
DUST, (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:MAGNESIUM DICHROMATE:HEXAVALENT CHROMIUM
COMPOUND:IARC GROUP1, NTP GROUP 1.
Effects of Overexposure:HLTH HAZ: INGESTION SHD BE AVOIDED AS PREC
AGAINST MANGANESE POISONING. SYMP OF MANGANESE POISONING ARE
WEAKNESS AND SLEEPINESS. PROLONGED EXPOSURE TO HEXAVALENT CHROMIUM
COMPOUNDS OVER PEL MAY CAUSE PENETRATING ULCERS OF MUC MEMB OF THE
NOSE AND PERFORATION OF THE CARTILAGENOUS NASAL SEPTUM.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH LUKE WARM WATER FOR AT LEAST 15 MINUTES. IF
SYMPTOMS PERSIST, CONSULT PHYSICIAN. SKIN: WASH WITH SOAP AND
WATER. IF SYMPTOMS PERSIST, CONSULT PHYSICIAN. INHALATION: REMOVE
TO FRESH AI R. IF SYMPTOMS ARE PRESENT CONSULT PHYSICIAN.
INGESTION: CONSULT A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:140F,60C
Lower Limits:1.1%
Upper Limits:7.0%
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM, WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE H*2O TO COOL HEAT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:EXCESSIVE HEAT MAY CAUSE DECOMPOSITION OF
MANGANESE DIOXIDE, RESULTING IN OXIDATION AND POSSIBLE IGNITION OF
HYDROCARBON VEHICLE.
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP INTO CONTAINERS, CLEAN-UP RESIDUE WITH
1,1,1-TRICHLOROETHANE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING AND
BEFORE SMOKING OR EATING. AVOID INGESTION.
Other Precautions:THIS PRODUCT CONTAINS A TOXIC CHEMICAL OR CHEMICALS
SUBJECT TO REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF
SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR
PART 372.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:GENERAL VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE SMOKING
OR EATING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Spec Gravity:1.62
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK PASTE.
Percent Volatiles by Volume:12
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
EASILY OXIDIZABLE MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:OXIDES OF CARBON AND NITROGEN,
MANGANESE COMPOUNDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:EPA WASTE NO. D-007. DISPOSE OF SPILLAGE IN
COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: CIRCUIT WORKS CONDUCTIVE PEN, CW2200MTP-T
Cage: 21267
Resp. Party Other MSDS No.: 4001
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 21267
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENTS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: VAPORS OF THIS PRODUCT MAY IRRITATE THE EYES. LIQUID
IS IRRITATING AND MAY CAUSE TEARING, REDNESS, SWELLING OR TEMPORARY CORNEAL
DAMAGE. SKIN: CONTACT MAY CAUSE IRRITATION. PROLONGED CONTACT MAY CAUSE
DERMATITIS. INGESTION: HARMFUL IF SWALLOWED. MAY CAUSE NERVOUS SYSTEM
DEPRESSION. DO NOT INGEST. INHALATION: HARMFUL IF INHALED. MAY CAUSE
HEADACHE, NAUSEA, VOMITING, DIZZINESS, DROWSINESS, IRR ITATION OF THE
RESPIRATORY TRACT/MUCOUS MEMBRANES. EXTREME OVEREXPOSURE MAY CAUSE LOSS OF
CONSCIOUSNESS AND NARCOSIS. CHRONIC: ANIMAL STUDIES HAVE CLEARLY SHOWN
DOSE-RELATED ADVERSE EFFECTS ON THE CNS , HEMATOPOIETIC (EFTS OF OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZS: TISSUE, BLOOD, KIDNEYS AND
LIVER ASSOCIATED WITH THE ADMINISTRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER
ACETATE (EGBEA) (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO 90-118) (FP N).
Medical Cond Aggravated By Exposure: HEART, LUNG, EYE, SKIN.
First Aid: EYES: IMMED FLUSH W/LARGE AMTS OF WATER. AFTER INITIAL FLUSHING,
REMOVE ANY CONTACT LENSES & CONTINUE FLUSHING FOR AT LEAST 15 MINUTES.
HAVE EYES EXAMINED BY MD IF DISCOMFORT PERSISTS. SKIN: REMOVE CO NTAM CLTHG
& WASH SKIN W/SOAP & WATER. GET MED ATTN IF IRRITATION DEVELOPS OR
PERSISTS. WASH CLTHG SEPARATELY BEFORE REUSE. INGEST: IF SWALLOWED, GIVE TWO
OR MORE GLASSES OF WATER IMMED. DO NOT INDUCE VOMITING. GET MED ATTN. INHAL:
IN CASE OF EXPOSURE TO HIGH CONCS OF VAP/MIST, REMOVE TO FRESH AIR. IF
BREATHING IS DFCLT, GIVE OXYGEN & CALL MD. IF BREATHING HAS STOPPED,
APPLY ARTF RESP & CALL MD.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: LARGE SPILLS: REMOVE ALL SOURCES OF IGNIT (SPARKS,
OPEN FLAMES, ETC). WEAR NIOSH APPRVD SCBA & APPROP PERSONAL PROT EQUIP.
VENT AREA & CONTAIN & ABSORB SPILL W/INERT MATL. COLLECT SPILL BY
SCOOPING UP LIQS & ABSORB MATL & PLACE IN CHEM WASTE CNTNR FOR
PROPER DISP. DO NOT FLUSH TO SEWER. PVNT MATL FROM ENTERING STORM SEWERS,
DITCHES THAT LEAD TO WATERWAYS & GROUND. SMALL SPILLS: ABSORB (SUPDAT)
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND
LOCAL REGULATIONS. WATER RUNOFF CAN CAUSE ENVIRONMENTAL DAMAGE.
Handling And Storage Precautions: AVOID PROLONGED OR REPEATED CONTACT WITH
SKIN, EYES OR CLOTHING. WASH HANDS BEFORE EATING. USE WITH ADEQUATE
VENTILATION. AVOID BREATHING PRODUCT VAPOR. DO NOT REUSE THIS CONTAINER.
STORE IN A COOL, D RY PLACE, AWAY FROM HEAT, SPARKS OR FLAMES.
Other Precautions: KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. DO NOT STORE
IN DIRECT SUNLIGHT. KEEP OUT OF REACH OF CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point: =24.4C, 76.F
Lower Limits: 1.5%
Upper Limits: 10.0%
Extinguishing Media: USE ALCOHOL FOAM, WATER FOAM, CARBON DIOXIDE, DRY CHEM OR
WATER SPRAY. WATER MAY NOT BE EFTIVE IN FIGHTING FIRE BUT CAN BE USED TO COOL
OVERHEATED AREAS. CARE MUST BE (SUPDAT)
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). REMOVE ALL IGNITION SOURCES. USE WATER SPRAY TO COOL OVERHEATED
CONTAINERS. TAKE CARE NOT TO SPREAD FIRE WITH WATER.
Unusual Fire/Explosion Hazard: SOLVENT VAPORS ARE AN EXPLOSION HAZARD. KEEP
MATERIAL AWAY FROM ALL SOURCES OF IGNITION, EXTREME HEAT, SPARKS OR OPEN
FLAME. MATERIAL CAN BE EASILY IGNITED AND BURNS WITH INTENSE HEAT. NFPA CODE
- HEA LTH: 2; FLAMMABILITY: 3; REACTIVITY: 1; PERSONAL PROTECTION: - .
=======================================================
Control Measures
=======================================================
Respiratory Protection: THIS MATERIAL DOES NOT HAVE ESTABLISHED EXPOSURE
LIMITS. WEAR A NIOSH APPROVED POSITIVE PRESSURE, AIR-SUPPLIED RESPIRATOR IN
SITUATIONS WHERE THERE MAY BE A POTENTIAL FOR AIRBORNE EXPOSURE.
Ventilation: GOOD GEN VENT SHOULD BE SUFFICIENT TO CONTROL AIRBORNE LEVELS. LOC
EXHST VENT MAY BE NEC TO CONTROL ANY AIR CONTAMINANTS TO W/IN THEIR TLVS
DURING USE OF PROD.
Other Protective Equipment: EYE WASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N).
Supplemental Safety and Health: SPILL PROC: SPILL W/ABSORB MATL, THEN PLACE IN
A CHEMICAL WASTE CNTNR FOR PROPER DISPOSAL. EXTING MEDIA: TAKEN TO NOT SPREAD
THE FIRE.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >126.1C, 259.F
B.P. Text: 259-378F (H*2O=1)
Vapor Pres: 5-6 MM @ 20C (AIR=1)
Vapor Density: HVR/AIR
Spec Gravity: 1.8-2.0
Evaporation Rate & Reference: FASTER (BUTYL ACETATE=1)
Solubility in Water: APPRECIABLE >10%
Appearance and Odor: SILVER COLORED PAINT; AROMATIC HYDROCARBON ODOR.
Percent Volatiles by Volume: <30-40
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID HEAT, SPARKS, OPEN FLAME AND STRONG
OXIDIZING CONDITIONS.
Materials To Avoid: DO NOT MIX STRONG OXIDIZERS, ACIDS, BASES, CAUSTICS, AMINES
AND ALKALI CONTAMINATION.
Hazardous Decomposition Products: DECOMPOSITION MAY RELEASE CARBON MONOXIDE,
CARBON DIOXIDE, OXIDES OF NITROGEN, MONOMERS & SMOKE. DEPENDING ON
CONDITIONS, SOME HIGHLY REACTIVE PEROXIDES MAY BE FORMED.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
Toxicological Information: PROPYLENE GLYCOL METHYL ETHER ACETATE LD50 (DERMAL,
RBT): >5.0; LC50: (INHAL, RAT) >4300 PPM. BUTYL ACETATE: LC50: (INHAL,
RAT) 2000 PPM. NO INGREDIENTS LISTED AS HUMAN CARCINOGENS BY NTP OR IARC.
=======================================================
Ecological Information
=======================================================
Ecological: ENVIRONMENTAL IMPACT INFORMATION: AVOID RUNOFF INTO STORM SEWERS
AND DITCHES WHICH LEAD TO WATERWAYS. WATER RUNOFF CAN CAUSE ENVIRONMENTAL
DAMAGE. US REGS REQUIRE REPORTING SPILLS OF THIS MATERIAL THA T COULD REACH
ANY SURFACE WATERS. THE TOLL FREE NUMBER OF THE US COAST GUARD NATIONAL
RESPONSE CENTER IS 1-800-424-8802.
=======================================================
=======================================================
Transport Information: AIR - PROPER SHIPPING NAME: FLAMMABLE LIQUIDS N.O.S. UN
NUMBER: UN1993. CLASS 3. PKG GROUP: III. HAZARD LABEL: FLAMMABLE LIQUID
(BUTYL ACETATE). PKG INSTR: Y305/305. MAX QUANTITY: 1L/5L. GROUND - PROP ER
SHIPPING NAME: CONSUMER COMMODITY ORM-D. CLASS: ORM-D. HAZARD LABEL: ORM-D.
PKG INSTR: 173.150. MAX QUANTITY: 5L.
=======================================================
Regulatory Information
=======================================================
Federal Regulatory Information: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF THE
EMERGENCY PLANNING AND COMMUNITY RIGHT-TO-KNOW ACT OF 1986 (40 CFR 372).
PRODUCT CONTAIN S NO SECTION 313 LISTED CHEMICALS. THIS INFORMATION SHOULD BE
INCLUDED ON ALL MSDS THAT ARE COPIED AND DISTRUBUTED FOR THIS MATERIAL. ALL
INGREDIENTS IN THE PRODUCT ARE LISTED ON THE TSCA INVENTORY.
=======================================================
Other Information
=======================================================
Other Information: DO NOT PUNCTURE OR INCINERATE CONTAINERS. NORMAL VENTILATION
FOR STANDARD MANUFACTURING PRACTICES IS USUALLY ADEQUATE. LOCAL EXHAUST
SHOULD BE USED WHEN LARGE AMOUNTS ARE RELEASED. W: INGREDIENT D ISCLOSURE
LIST: BUTYL ACETATE (123-86-4) STATUS: FLAMMABLE LIQUID. CODES: HEALTH:
2; FLAMMABILITY: 3; REACTIVITY: 1; PERSONAL PROTECTION:B.
=======================================================
HAZCOM Label
=======================================================
Product ID: CIRCUIT WORKS CONDUCTIVE PEN, CW2200MTP-T
Cage: 21267
Company Name: CHEMTRONICS INC
Street: 8125 COBB CENTER DRIVE
Zipcode: 30152
Label Required IND: Y
Date Of Label Review: 07/13/1999
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: EYES: VAPORS MAY IRRITATE. LIQUID
IRRITATES & MAY CAUSE TEARING, REDNESS, SWELLING/TEMPORARY CORNEAL
DAMAGE. SKIN: CONT MAY CAUSE IRRIT. PRLNGD CONT MAY CAUSE DERM. INGEST:
HARMFUL. MAY CUASE NERVOUS SYSTEM DEPRESSION. DO NOT INGEST. INHAL: HARMFUL.
MAY CAUSE HEADACHE, NAUSEA, VOMITING, DIZZINESS, DROWSINESS, IRRIT OF RESP
TRACT/MUCOUS MEMBRANES. EXTREME OVEREXPOSURE MAY CUASE LO SS OF CONSCIOUSNESS
AND NARCOSIS. CHRONIC: ANIMAL STUDIES HAVE CLEARLY SHOWN DOSE-RELATED ADVERSE
EFFECTS ON THE CNS, BLOOD-FORMING TISSUE, BLOOD, LIVER AND KIDNEYS ASSOCIATED
WITH ADMINISTRATION OF 2 -BUTOXYETHANOL ACETATE (FP N).
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BDI-584-1 MICROSCAN 40% POTASSIUM HYDROXIDE
CAGE:0WG31
CAGE:0WG31
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM HYDROXIDE
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 33%
Other REC Limits:2 MG/CUM (CEILING)
OSHA PEL:2 MG/CUM
ACGIH TLV:2 MG/CUM (CEILING)
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
Fraction by Wt: 68%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CORROSIVE, MAY CAUSE SEVER BURNS,
DERMATITIS.
Explanation of Carcinogenicity:NONE
Medical Cond Aggravated by Exposure:SKIN & EYE CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYES: WASH IMMEDIATELY W/WATER FOR 20 MINUTES. CONTINUE
W/NORMAL SALINE. SKIN: REMOVE CONTAMINATED CLOTHING IMMEDIATELY,
WASH AFFECTED AREA W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
GIVE CPR IF NECESSARY. INGESTION: DILUTE BY GIVINGWATER OR MILK.
ALLOW VOMITING TO OCCUR. KEEP HEAD BELOW HIPS TO AVOID ASPIRATION.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE AGENT SUITABLE FOR SURROUNDING FIRE
Fire Fighting Procedures:AVOID BREATHING VAPORS. KEEP UPWIND.
================== Accidental Release Measures ==================
Spill Release Procedures:NEUTRALIZE.
Neutralizing Agent:CITRIC ACID
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL PLACE AWAY FROM
INCOMPATIBLE CHEMICALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED
Ventilation:MECHANICAL (GENERAL)
Other Protective Equipment:APPROPRIATE IMPERVIOUS CLOTHING
Work Hygienic Practices:GOOD LABORATORY PRACTICES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, ACROLEIN, ACRYLONITRILLE, BROMOFORM, CALCIUM CARBIDE, CHLORINE
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:CORROSIVE VAPORS.
==================== Disposal Considerations ====================
Waste Disposal Methods:NEUTRALIZED MATERIAL MAY BE DISPOSE INTO
SANITARY SEWER. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:VELODUR METAL STANDARD BASE, 1002 VEL
Kit Part:Y
Preparer's Name:SAFETY DEPT
CAGE:6X913
CAGE:6X913
============= Composition/Information on Ingredients =============
Ingred Name:DGBA EPOXY RESINS; (DIGLYCIDYL ETHER OF BISPHENOL A RESIN)
CAS:25068-38-6
RTECS #:SL6475000
Fraction by Wt: 35-55%
Ingred Name:NON HAZARDOUS INGREDIENTS
Fraction by Wt: 45-65%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SLIGHT IRRITATION OF EYES
POSSIBLE, THEREFORE AVOID EYE CONTACT. CHRONIC: SLIGHT SKIN
SENSITIZER.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:ALLERGIES, SKIN CONDITIONS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER CONTINOUSLY FOR AT LEAST 15 MINUTES.
SKIN: WASH THOROUGHLY WITH SOAP AND WARM WATER. INHAL: NO DATA.
REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O2/ARTIFICIAL
RESPIRATION)(FP N ). INGEST: GIVE LARGE AMOUNTS OF WATER OR MILK.
DO NOT INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:481F,249C
Extinguishing Media:DRY CHEMICAL, CO2, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:PREVENT SKIN AND EYE CONTACT. REMOVE
CONTAMINATED CLOTHING. ABSORB MATERIAL AND DISPOSE OF ACCORDING TO
STATE AND LOCAL REGULATIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE - WASH HANDS
AFTER HANDLING MATERIAL. DO NOT TOUCH EYES DURING MATERIAL
HANDLING.
Other Precautions:STORE COOL AND DRY. IF END PRODUCT STANDARD A & B IS
MACHINED, WEAR PROTECTIVE EQUIPMENT TO AVOID OVEREXPOSURE TO
NUISANCE PARTICLES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NECESSARY. USE NIOSH/MSHA APPROVED
RESPIRATOR FOR EXPOSURE OF CONCERN .
Ventilation:MECHANICAL REQUIRED.
Other Protective Equipment:NONE
Work Hygienic Practices:WASH HANDS THOROUGHLY ESPECIALLY BEFORE EATING,
DRINKING, SMOKING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Vapor Pres:@ 26C NIL
Vapor Density:>1
Spec Gravity:2.7
Solubility in Water:NIL
Appearance and Odor:STEEL TO DARK GRAY PASTE. LOW ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:OPEN FLAME
Hazardous Decomposition Products:FROM INCOMPLETE COMBUSTION: COX,
ACIDS, ALDEHYDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:TRANSPORT TO WASTE DISPOSAL FACILITY IN
COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
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