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===================== Product Identification =====================
Product ID:149 4319 CYAN PIGMENTED INK,MX 1740
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 70 - 90%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT RELEVANT
ACGIH TLV:NOT RELEVANT
Ingred Name:GLYCERIN (GLYCEROL)
CAS:56-81-5
RTECS #:MA8050000
Fraction by Wt: 5 - 15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:15 MG/M3 (MIST)
ACGIH TLV:10 MG/M3 (MIST);9596
Ingred Name:DIETHYLENE GLYCOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: <12%
Other REC Limits:NONE RECOMMENDED
Ingred Name:PIGMENT/CYAN PHTHALOCYANINE PIGMENT
CAS:81422-13-1
Fraction by Wt: 1 - 5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM
OLEYLMETHYLTAURIDE/2-(METHYL(1-OXO-9-OCTADECENYL)AMINO)ETHANESULFON
IC ACID,SODIUM SALT
CAS:137-20-2
Fraction by Wt: <3%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) IS NOT KNOWN.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, GI TRACT.
ACUTE- CAUSES EYE & SKIN IRRITATION. EXPECTED TO BE A LOW HAZARD BY
INHALATION. HARMFUL IF INGESTED. CAN CAUSE GASTROINTESTINAL TRACT
IRRITATION. CHRONIC - CAN CAUSE KIDNEY DAMAGE, BLOOD DISORDERS
BASED ON ANIMAL DATA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, VOMITING
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:FLUSH WITH
WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING.
EYE:FLUSH WITH WATER FOR 15 MINUTES. HOLD EYELIDS OPEN.
INHALED:MOVE TO FRESH AIR.ORAL:IF CONSCIOUS, INDUCE VOMITING
IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. CALL A
PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE (CO2), ALCOHOL FOAM
OR DRY CHEMICAL. USE WATER SPRAY TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION
PRODUCTS MAY BE FORMED.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB SPILL WITH INERT MATERIAL SUCH AS
VERMICULITE. PLACE IN A CONTAINER FOR DISPOSAL. CLEAN AREA
THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION. PREVENT RUNOFF FROM
ENTERING SEWERS OR WATERWAYS.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM STRONG OXIDIZING
AGENTS. KEEP CONTAINER CLOSED. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE WITH
ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION (TYPICALLY 10 AIR CHANGES/HR)
SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
ECOLOGICAL INFORMATION: A LOW BIOCHEMICAL OXYGEN DEMAND, A LOW
POTENTIAL TO AFFECT AQUATIC ORGANISMS. AFTER DILUTION WITH WATER,
FOLLOWED BY SECONDARY WASTE TREATMENT, THIS MATERIAL IS NOT
EXPECTED TO CAUSE ADVERSE ENVIRNMENTAL EFFECTS.
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:>212F,>100C
Vapor Pres:18 @ 68F
Vapor Density:0.6
Appearance and Odor:CYAN LIQUID
Percent Volatiles by Volume:75- 95
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL IS SUBJECT TO
FEDERAL, STATE OR LOCAL LAWS. CONTRACT WITH A LICENSED CHEMICAL
DISPOSAL AGENCY.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ISOPROPANOL,ISOPROPYL ALCOHOL
CAGE:LO738
CAGE:66611
CAGE:LO738
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 70%.
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
Ingred Name:WATER (DEIONIZED,SOFT)
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 30%.
===================== Hazards Identification =====================
Effects of Overexposure:ACUTE:VAP.IRR.NOSE&THROATLIQ.WILL DAMAGE
EYE/CHRONIC:PROLONGED/REPEATED SKIN CONTACT,IRR./
======================= First Aid Measures =======================
First Aid:INHALED:REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEED
(CAUTION:CPR MAY EXPOSE RESCUER)EYES/SKIN:FLUSH W.WATER 15 MIN.
REMOVE CONTAMINATED CLOTHES.KEEP WARM/QUIET. GET MEDICAL ATTENTION
===================== Fire Fighting Measures =====================
Flash Point:63F,17C,TCC
Lower Limits:2.0
Upper Limits:12.0
Extinguishing Media:SM FIRE:CO*2,DRY CHEM;LG FIRE:ALC.TYPE FOAM.
Fire Fighting Procedures:DILUTION OF BURNING LIQ.W/22-25 VOLS OF WTR
WILL EXTINGUISH.
Unusual Fire/Explosion Hazard:RESP.PROTEC.REQD.FOR FIREFIGHTING
PERSONNEL.STAY UPWIND IF POSSIBLE.COOL EXPSD.TANKS WITH WTR.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP PUBLIC AWAY.SHUT OFF SOURCE IF POSSIBLE
W/O HAZ.;ELIMINATE SOURCES OF IGN.WARN OCCUPANTS OF DOWNWIND AREAS
OF EXPL.HAZ.;PREVENT LIQ.FROM ENTERING WTRCOURSES,LOW AREAS.CONTAIN
SPILLED LIQ.W/SAND,E ARTH.DILUTE W/WTR.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTRS HAZ WHEN EMPTY. ALL HAZ PRECS
MUST BE OBSERVED. PROT. CONTRS AGAINST PHYS. DAMAGE KEEP CONTRS
CLOSED.AVOID FIRE HAZ. STG IN COOL, DRY PLACE.
Other Precautions:DO NOT HANDLE/STORE NEAR FLAME,HEAT.STRONG
OXIDIZERS.ADEQUATE VENTILATION REQUIRED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPVD AIR SUPPLIED MASK IN ENCLOSED
SPACES.
Ventilation:EXPL.PROOF MECH.VENTIL;LOCAL EXH.>60FPM IN ENCLOSED SPACES.
Other Protective Equipment:NONE
Supplemental Safety and Health
UNDATED MSDS/FREEZING
PT:-58F,-50C/INCOMPATIB:PHOSP.TRICHLOR.,ALDEHYDES,MONOMERS,POLYMERI
ZABLE ESTERS,HYDROGEN W/PALLADIUM & STORING IN ALUMINUM VESSELS/
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:176F,80C
Vapor Pres:29.
Vapor Density:1.6
Spec Gravity:0.878
Evaporation Rate & Reference:1.7 (BU AC=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,COLORLESS LIQ,ALC TYPE ODOR.
Percent Volatiles by Volume:70.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKYLENE OXIDES,AC,ANHYDRINES,INORG.AC.,HALOGENS-SEE SUPPL-
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:RECOVER FREE LIQ.BY PUMPING OR W/SUITABLE
ABSORBANT.CONSULT A DISPOSAL EXPERT AND ENSURE CONFORMITY TO
LOCAL,STATE,FED,REGS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:170 8767,HARDNR & REPL,PROC C-41V,PART C
CAGE:19139
CAGE:19139
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM ACETATE
CAS:126-96-5
RTECS #:AJ4375000
Fraction by Wt: 45-50%
Ingred Name:SODIUM SULFATE
CAS:7757-82-6
RTECS #:WE1650000
Fraction by Wt: 30-35%
Ingred Name:BORIC ACID
CAS:10043-35-3
RTECS #:ED4550000
Fraction by Wt: 10-15%
===================== Hazards Identification =====================
Effects of Overexposure:MFG. STATES MATERIAL HAS LOW HAZARD:FOLLOW
STANDARD CHEMICAL FIRST AID.
======================= First Aid Measures =======================
First Aid:INHALE:REMOVE TO FRESH AIR,GIVE CPR/O*2 IF NEED;EYES:FLUSH W
LG AMTS H*2O FOR 15 MIN;SKIN:FLUSH W LG AMTS H*2O;INGEST:RINSE
MOUTH,CALL DR.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:EXTINGUISH WITH AGENT SUITABLE FOR SURROUNDING FIRE
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE NOTED
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH MATL TO SEWER W/LGE AMTS WATER.
FED,STATE & LOCAL REGS TAKE PRECEDENCE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED,LOW
FIRE RISK AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL
CONTACT.KEEP CONTAINERS THIGHTLY CLOSED.
Other Precautions:AVOID PROLONGED OR REPEATED CONTACT W CHEMICAL.REMOVE
& WASH CONTAMINATED CLOTHING.MAINTAINT STRICT HYGIENE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR EXCESSIVE DISPERSAL,IN AIR,WEAR DUST
RESPIRATOR.
Ventilation:NO SPECIAL REQUIREMENTS.
Other Protective Equipment:NO SPECIAL REQUIREMENTS.
Supplemental Safety and Health
THIS IS PART C OF A 3-PART KIT. MIXTURE NR 3762.KEY1:N1.
================== Physical/Chemical Properties ==================
HCC:F6
Spec Gravity:>1.0
Solubility in Water:APPRECIABLE
Appearance and Odor:SOLID MIXTURE:WHITE POWDER,ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE NOTED
Stability Condition to Avoid:NONE NOTED
Hazardous Decomposition Products:NONE NOTED
==================== Disposal Considerations ====================
Waste Disposal Methods:SEE SPILL/RELEASE PROCEDURES.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CATALYST, U-2964
Preparer's Name:P D MOORE
CAGE:60003
CAGE:60003
============= Composition/Information on Ingredients =============
Ingred Name:ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS; (HOMOPOLYMER
OF HDI)
CAS:28182-81-2
RTECS #:NQ9170000
Fraction by Wt: 75%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:6-UNDECANONE; (DIAMYL KETONE)
CAS:927-49-1
RTECS #:YQ2820000
Fraction by Wt: 10%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ETHYL 2 NONANONE
CAS:5440-39-1
Fraction by Wt: 10%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:2-HEXANONE; (METHYL N-AMYL KETONE)
CAS:591-78-6
RTECS #:MP1400000
Fraction by Wt: <5%
OSHA PEL:100 PPM
ACGIH TLV:S, 5 PPM
Ingred Name:2-HEXANONE, 5-METHYL-; (METHYL ISOAMYL KETONE). VP:4.5 @
68F
CAS:110-12-3
RTECS #:MP3850000
Fraction by Wt: <5%
OSHA PEL:100 PPM
ACGIH TLV:50 PPM
Ingred Name:HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE)
(CERCLA)
CAS:822-06-0
RTECS #:MO1740000
Fraction by Wt: <0.1%
OSHA PEL:N/K
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:COATING & MATERIAL VOLATILE ORGANIC COMPOUND:1.94 LB/GL
(233 G/L)
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:IRRITATION TO
RESPIRATORY TRACT (NOSE, THROAT, LUNGS). SKIN & EYE:SEVERELY
IRRITATING, WILL INJURE EYE TISSUE IF NOT PROPERLY REMOVED. SKIN
ABSORP:SENSITIZER. ALLERGIC SKIN REACTION M AY OCCUR IN SOME
INDIVIDUALS. INGESTION:CONSULT PHYSICIAN. HEXAMETHYLENE DIISOCYANTE
(HDI) MONOMER (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CONTENT <0.1% BASED ON RESIN SOLIDS AT
TIME OF MANUFACTURE. HOWEVER, AFTER 3-6 MONTHS STORAGE, FREE
MONOMER CONTENT MAY RISE TO MAXIMUM OF 0.2%.
Medical Cond Aggravated by Exposure:RESPIRATORY PROBLEMS CAN BE
INCREASED BY INHALATION OF VAPORS.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER FOR AT LEAST 15 MINS. GET IMMED MED ATTN.
SKIN:REMOVE CONTAMD CLTHG. WASH AFFECTED AREA W/SOAP & WATER.
INHAL:MOVE TO FRESH AIR. OBTAIN MED ATTN IF NEEDED. INGEST:DO NOT
INDUCE VOMI T. GET IMMED MED ATTN. IF SENSITIZED TOAN ISOCYANATE,
NO FURTHER EXPOS CAN BE PERMITTED.
===================== Fire Fighting Measures =====================
Flash Point:184F,84C
Lower Limits:1.0%
Upper Limits:8.2%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . USE WATER FOG NOZZLES TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:DO NOT USE WATER. FLAMM LIQ, CAN RELEASE
VAPS THAT FORM FLAMM MIX @ TEMP @ OR ABOVE FLASHPOINT. ELIM &
ISOLATE FROM ALL SOURCES OF IGNIT. COMBUST WILL (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR RESPIRATOR, ABSORB W/VERMICULITE OR OTHER
ABSORBENT MATERIAL. ELIMINATE ALL IGNITION SOURCES. STOP SPILL AT
SOURCE AND PREVENT SPREADING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN DRY AREA. KEEP CNTNRS TIGHTLY
CLSD. PROTECT FROM PHYSICAL DMG. EMPTIED CNTNRS RETAIN PROD
RESIDUES (VAP, LIQ, AND/OR SOLID).
Other Precautions:ALL HAZ PREC GIVEN IN MSDS MUST BE OBSERVED. STORE
<120F. STOR LG QTYS IN BUILDING DESIGNED TO COMPLY W/OSHA 1910.106.
KEEP CLOSURE TIGHT & CNTNR UPRIGHT TO PVNT LEAKAGE. DO NOT STORE
NEAR HEAT, SPKS/ FLAME. DO NOT GET IN EYES. KEEP (SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV OF PROD/ANY COMPONENT IS EXCEEDED,
NIOSH/MSHA JOINTLY APPRVD AIR SUPPLY RESP IS ADVISED IN ABSENCE OF
PROPER ENVIR CTL. OSHA REGS ALSO PERMIT OTHER NIOSH/MSHA RESPS
UNDER SPECIFIED CNDTNS. (SEE SFTY EQUIP SUPPLIER). (SUPDAT)
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENT TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:SOLVENT RESISTANT IMPERVIOUS CLOTHING &
BOOTS. ANSI APPRVD EMERGENCY EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER USE, BEFORE
EATING OR SMOKING.
Supplemental Safety and Health
EXPLO HAZ:PRDCE CO*2, CO, & TOXIC GASES. OTHER PREC:AWAY FROM CHILDREN.
AVOID SKIN CONT. DO NOT TAKE INTERNALLY. FOR INDUST USE. RESP
PROT:ENGINEERING/ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:286F,141C
Vapor Pres:SEE INGS
Vapor Density:HVR/IAR
Spec Gravity:1.1 (H*2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR LIQUID, SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID ALKALI METAL HYDROXIDES, SUCH AS SODIUM HYDROXIDE, AND STRONG
OXIDIZERS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT.
Hazardous Decomposition Products:BY FIRE:CO*2, CO, OXIDES OF NITROGEN,
TRACES OF HCN, HDI.
==================== Disposal Considerations ====================
Waste Disposal Methods:DESTROY BY LIQUID INCINERATION. CONTAMD
ABSORBENT MAY BE DEPOSITED IN A LANDFILL IN ACCORDANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:R65-002-050 EP-S TONER CARTRIDGE BLACK
CAGE:EO274
CAGE:EO274
CAGE:1BA63
============= Composition/Information on Ingredients =============
Ingred Name:STYRENE ACRYLATE COPOLYMER *95-4*
CAS:23153-46-2
Fraction by Wt: 60-70%
Ingred Name:IRON OXIDE, MAGNETITE *95-4*
CAS:1317-61-9
Fraction by Wt: 30-40%
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (KNOWN CARCINOGEN BY NTP;
IARC CARC - GROUP 3) *95-4*
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 0.5%
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CHROMIUM COMPOUNDS (TYPE NOT SPECIFIED)
Fraction by Wt: 2%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HUMAN EXPOSURE TO TONER
HAS BEEN SHOWN TO CAUSE MINIMAL RESPIRATORY TRACT IRRITATION. EYES:
MAY CAUSE TRANSIENT IRRITATION.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: WASH OUT IMMEDIATELY
W/WATER. SKIN: WASH W/SOAP & WATER. INGESTION: DRINK 1-2 GLASSES OF
WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NON-FLAMMABLE SOLID. TONER MATERIAL, LIKE
MOST ORGANIC MATERIAL IN POWDER FORM, IS CAPABLE OF CREATING A DUST
EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID INHALATION OF THE DUST. SWEEP MATERIAL
ONTO PAPER & DISPOSE COLLECTED TONER AS PLASTIC WASTE.
======================Handling and Storage ======================
Handling and Storage Precautions:USE ADEQUATE VENTILATION. STORE IN A
COOL PLACE. MINIMIZE DUST GENERATION & ACCUMULATION.
Other Precautions:AVOID BREATHING DUST. KEEP FROM CONTACT W/OXIDIZING
MATERIALS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD (TYPICALLY 4-6 ROOM VOLUMES PER HOUR) SHOULD BE USED.
Other Protective Equipment:WASHING FACILITIES
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:212-302F
Spec Gravity:1.4-1.6
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK FINE POWDER W/TYPICAL PLASTIC ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:CO2, CO
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE/LANDFILL, CAN BE INCINERATED
IAW/FEDERAL, STATE & LOCAL REGULATIONS. DISCHARGE,
TREATMENT/DISPOSAL MAY BE SUBJECT TO NATIONAL STATE/LOCAL LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MARS BLACK
Preparer's Name:WOODHALL STOPFORD
CAGE:72925
CAGE:72925
============= Composition/Information on Ingredients =============
Ingred Name:NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC,
ACGIH) INTENDED CHANGE (IC)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 1.00%
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
ACGIH TLV:0.05 MG/CUM IC
Ingred Name:HEXACHLOROBENZENE
CAS:118-74-1
RTECS #:DA2975000
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:CADMIUM PIGMENT
Ingred Name:CADMIUM SUSPECTED HUMAN CARCINOGEN (ACGIH,IARC, & NTP)
INTENDED CHANGE (IC)
CAS:7440-43-9
RTECS #:EU9800000
Fraction by Wt: 0.05%
Other REC Limits:A2 CARCINOGEN
OSHA PEL:0.05 MG/CUM (CD)
ACGIH TLV:0.01 MG/CUM
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:COBALT
CAS:7440-48-4
RTECS #:GF8750000
Other REC Limits:0.05 PPM
OSHA PEL:0.1 MG/CUM
ACGIH TLV:0.05 MG/CUM
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGESTION: MAY BE HARMFUL IF
SWALLOWED. CRONIC: EXPOSURE MAY CAUSE DAMAGE TO THE HEART/LUNGS.
EXPOSURE MAY CAUSE DAMAGE TOTHE CHEST. EXPOSURE MAY CAUSE HARM TO
THE DEVELOPING FETUS. LUNG DISEASE. KID NEY DISEASE. PREGNANCY.
HEART DISEASE.
Explanation of Carcinogenicity:NONE
======================= First Aid Measures =======================
First Aid:INGESTION: GET PROMPT MEDICAL ATTENTION. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
================== Accidental Release Measures ==================
Spill Release Procedures:NO SPECIAL SPILL PROCEDURES REQUIRED.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH-CERTIFIED MASK FOR DUSTS
Ventilation:LOCALLY EXHAUSTING HOOD
Work Hygienic Practices:DON'T SPRAY APPLY. WASH HANDS IMMEDIATELY AFTER
USE. WHEN USING DON'T EAT, DRINK/SMOKE. AVOID USING IF PREGNANT.
Supplemental Safety and Health
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FEDERAL, STATAE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:05129 OXAZEPAM-PHENYL-D5--DEA SCHEDULE IV ITEM
Kit Part:Y
CAGE:21076
CAGE:21076
============= Composition/Information on Ingredients =============
Ingred Name:OXAZEPAM-PHENYL-D5
CAS:65854-78-6
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): >8 GM/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY BE HARMFUL BY INHALATION,
INGESTION/SKIN ABSORPTION. TOXIC. MAY CAUSE CANCER.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:MAY BE HARMFUL IF INHALED, INGESTED/ABSORBED.
TOXIC. MAY CAUSE CANCER.
======================= First Aid Measures =======================
First Aid:INGESTION: WASH OUT MOUTH W/WATER PROVIDED PERSON IS
CONSCIOUS. INHALATION: REMOVE TO FRESH AIR. SKIN: FLUSH W/COPIOUS
AMOUNTS OF WATER FOR 15 MINS. EYES: FLUSH W/COPIOUS AMOUNTS OF
WATER FOR 15 MINS.OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO2, DRY CHEMICAL POWDER/APPROPRIATE FOAM.
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
SWEEP UP, PLACE IN A BAG & HOLD FOR WASTE DISPOSAL. AVOID RAISING
DUST. VENTILATE AREA & WASH SITE AFTER MATERIAL PICKUP IS COMPLETE.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED IN A
COOL WELL VENTILATED AREA.
Other Precautions:DON'T BREATHE DUST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:392F
Solubility in Water:COMPLETE
Appearance and Odor:SOLID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:COMBUSTION: CO, CO2, NITROGEN OXIDES,
HYDROGEN CHLORIDE GAS
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:THERMOLITE 12
CAGE:2A781
CAGE:2A781
CAGE:76323
============= Composition/Information on Ingredients =============
Ingred Name:DIBUTYL TIN DILAURATE (AS TIN)
CAS:77-58-7
RTECS #:WH7000000
Fraction by Wt: 95.0%
OSHA PEL:S, 0.1 MG/M3
ACGIH TLV:S, 0.1 MG/M3; 8990
===================== Hazards Identification =====================
Effects of Overexposure:EYES/SKIN: MAY CAUSE BURNS. FUMES OR VAPORS MAY
IRRIT UPPER RESP TRACT.
======================= First Aid Measures =======================
First Aid:EYES;IMMED FLUSH W/PLENTY OF WATER FOR 15 MIN. GET MED ATTN.
SKIN;WASH W/SOAP & WATER. RMV CONTAM CLTHG & SHOES. WASH CLTHG
BEFORE REUSE
===================== Fire Fighting Measures =====================
Flash Point:440F,226
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM, DRY CHEM
Fire Fighting Procedures:AVOID EYE/SKIN CNTCT. DO NOT BREATHE FUMES.
Unusual Fire/Explosion Hazard:MAY GENERATE IRRIT FUMES IF EXPOSED TO
OPEN FLAME
================== Accidental Release Measures ==================
Spill Release Procedures:MAY BE INJURIOUS TO AQUATIC LIFE IF DISCHARGED
TO OPEN WATERS. CONFINE AREA OF SPILL. COVER W/SAND OR OTHER INERT
MATL. TRANSFER TO SUITABLE CNTNRS FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
Other Precautions:AVOID EYE & SKIN CONTACT.DO NOT BREATHE FUMES OR
W/ADEQUATE VENTILATION.WASH THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT NORMALLY REQUIRED.
Ventilation:LOCAL EXHAUST:RECOMMENDED;MECHANICAL(GEN):REQUIRED
Other Protective Equipment:NONE
Supplemental Safety and Health
MSDS UNDATED. FORMULA:(C*4H*9)*2SN (OCOC*10H20CH*3)*2
================== Physical/Chemical Properties ==================
HCC:N1
Vapor Density:21.8
Spec Gravity:1.05
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SOFT CHRYSTALS OR YELLOW LIQUID MP=22-24C
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS
Stability Condition to Avoid:HIGH TEMP OR OPEN FLAME
Hazardous Decomposition Products:BUTYLTINS
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR DISPOSE OF AS SOLID WASTE. FOLLOW
ALL APPLICABLE FED, STATE, LOCAL LAWS FOR CHEM POLLUTION CONTROL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:COPPER, AAS SOLUTION 1000 PPM
CAGE:MORTO
CAGE:78518
CAGE:MORTO
============= Composition/Information on Ingredients =============
Ingred Name:COPPER NITRATE
CAS:3251-23-8
RTECS #:QR7400000
Fraction by Wt: .1%
OSHA PEL:100 UG/CUM
ACGIH TLV:1 MG/CUM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:NITRIC ACID (SARA III)
CAS:7697-37-2
RTECS #:QU5775000
Fraction by Wt: 2.4%
OSHA PEL:2 PPM/4 STEL
ACGIH TLV:2 PPM/4 STEL; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER, H2O
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BAL
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT): 940 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: EYE, SKIN & MUCOUS
MEMBRANE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: SKIN, EYES & MUCOUS MEMBRANE
IRRITATION.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE FROM EXPOSURE. SEEK MED ATTN. EYES: FLUSH
W/LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: REMOVE ANY
CONTAMINATED CLOTHING. FLUSH W/LARGE AMOUNTS AMOUNTS OF WATER FOR
15 MIN UTES. INGESTION: SEEK MED ATTN.
===================== Fire Fighting Measures =====================
Extinguishing Media:NONCOMBUSTIBLE
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA. IF WITHOUT,
REMOVE MATERIAL FROM FIRE AREA. COOL CONTAINERS W/WATER FROM
MAXIMUM DISTANCE.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES WHEN HEATED TO
DECOMPOSITION.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR FULL PROTECTIVE CLOTHING & RESPIRATORY
PROTECTION. ELIMINATE ALL SOURCES OF IGNITION. COVER SPILL W/DRY
SAND, DRY VERMICULITE, MIX WELL & CAREFULLY TRANSFER TO WELL-MARKED
CONTAINER. CLOSE CONTAI NER TIGHTLY. SUBMIT OR RETAIN FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:CORROSIVE LIQUID. KEEP CONTAINER
TIGHTLY CLOSED. STORE IN A COOL, DRY WELL-VENTILATED AREA. WASH
THOROUGHLY AFTER USE. CLOSE CONTAINER TIGHTLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR FOR ACID VAPORS.
FOR EMERGENCY, SELF-CONTAINED BREATHING APPARATUS.
Ventilation:LOCAL EXHAUST: FUME HOOD
Other Protective Equipment:LAB COAT/APRON, FLAME & CHEMICAL RESISTANT
COVERALLS, HATS, BOOTS, EYEWASH & SAFETY SHOWER.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING. USE HYGIENIC WASH
FACILITIES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:>1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REDUCING MATERIALS, STRONG BASES, COMBUSTIBLE ORGANICS, POWDERED
METALS.
Stability Condition to Avoid:HEAT, CONTACT W/INCOMPATIBLE MATERIALS, &
SOURCES OF IGNITION
Hazardous Decomposition Products:NOX, HYDROGEN NITRATE, & TOXIC FUMES
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT STATE, LOCAL, & FEDERAL REGULATIONS FOR
PROPER DISPOSAL OF COPPER IN NITRIC ACID SOLUTION.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SKD-S SPOTCHECK DEVELOPER (NEW FORMULATION)
CAGE:37676
CAGE:37676
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL ACETATE (SARA III)
CAS:141-78-6
RTECS #:AH5425000
Fraction by Wt: 40%
OSHA PEL:400 PPM
ACGIH TLV:400 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ACETONE (SARA III)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 30%
OSHA PEL:1000PPM
ACGIH TLV:750PPM/1000STEL;9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:BUTANE
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 10%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM; 9192
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 10%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT; 9192
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATES EYES.
Effects of Overexposure:INHALATION:CAUSES DIZZINESS,DROWSINESS,NAUSEA;
SKIN:LIQUID IRRITATES BY DISSOLVING SKIN OIL; EYES:VAPORS/LIQUID
CAUSES IRRITATION.
Medical Cond Aggravated by Exposure:NOT KNOWN
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR.IF BREATHING IS DIFFICULT,GIVE
OXYGEN; SKIN:REMOVE CONTAMINATED CLOTHES.WASH OFF WITH FLOWING
WATER.USE SOOTHING LOTION.IF IRRITATION PERSISTS,GET MEDICAL ATTN;
EYES:IMM EDIATELY RINSE/FLUSH WITH COPIOUS AMOUNT OF RUNNING
WATER,AND GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE,FOAM
Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:AEROSOL CANS CAN BURST IF HEATED ABOVE
130F(54.4C).
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE IGNITION SOURCES.SM QTY:WIPE UP OR MOP
UP BUT DO NOT BREATHE VAPORS.PLACE RAGS IN CLOSED DRUMS; LG
QTY:WEAR PERSONAL SAFETY EQUIPMENTS.DIKE AREA FAR AHEAD.ABSORB
LIQUID WITH COMMERCIAL ABSORBEN T.TRANSFER WASTE MATL IN SALVAGE
TANKS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM HEAT SOURCES IN WELL
VENTILATED AREA.AVOID AGAINST PHYSICAL DAMAGE TO CONTAINERS.KEEP
CONTAINERS TIGHTLY CLOSED.
Other Precautions:DO NOT BREATHE VAPORS.DO NOT SMOKE WHILE USING.DO NOT
HEAT ABOVE 130F(54C).AVOID FREQUENT OR PROLONGED SKIN CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A RESPIRATOR WITH ABSORBENT CARTRIDGE IN
POORLY VENTILATED AREAS.IN CONFINED,UNVENTILATED SPACES,WEAR FULL
MASK WITH AIR SUPPLY.
Ventilation:GENERAL VENTILATION TO KEEP BELOW TLV LIMITS.
Work Hygienic Practices:WASH HANDS WITH SOAP/WATER AFTER HANDLING/USE.
Supplemental Safety and Health
ONE PART PROD. QPL 25135-15 ALSO COVERS OTHER
PROD.(SKD-NF/ZP-9B,SKD-HT,SKD-LT,ZP-9E,& ZP/9F DEVELOPERS) OF SAME
COMPANY UNDER FORM "D",TYPE "II" OF MIL-I-25135D;THIS IS SKD-S, A
NEW FORMULATION WHICH REPLACES PNIND:D)
================== Physical/Chemical Properties ==================
HCC:V3
Spec Gravity:0.9 (OF LIQUID)
Evaporation Rate & Reference:0.5 (ETHER=1)
Solubility in Water:MODERATE
Appearance and Odor:WHITE LIQUID BEFORE FILLING IN AEROSOL CANS
Percent Volatiles by Volume:90.0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI METALS,ACIDS
Stability Condition to Avoid:HEAT/HIGH TEMPERATURES.
Hazardous Decomposition Products:WHEN INVOLVE IN COMBUSTION,EMITS
OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF AS EPA HAZARDOUS WASTE D001
(IGNITABLE WASTE),IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL,STATE,LOCAL REGULATIONS.EMPTY AEROS CANS BEFORE
DISCARDING.PRESSURIZED AEROSOL CANS ARE NOT AN ACCEPT ABLE WASTE.DO
NOT INCINERATE CANS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:N,N-DIMETHYLFORMAMIDE, 99%, D119RS50
CAGE:1B464
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:N,N-DIMETHYLFORMAMIDE LD50: (ORAL, RAT) 2800 MG/KG
CAS:68-12-2
RTECS #:LQ2100000
= Wt:100.
OSHA PEL:30 MG/M3;10 PPM
ACGIH TLV:30 MG/M3;10 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENT
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE: CAUSES SEVERE EYE IRRITATION.
VAPORS MAY CAUSE EYE IRRITATION. SKIN: PROLONGED AND/OR REPEATED
CONTACT MAY CAUSE IRRITATION AND/OR DERMATITIS. SUBSTANCE IS
RAPIDLY ABSORBED THROUGH THE SKIN. IF A BSORBED, CAUSES SYMPTOMS
SIMILAR TO INHALATION. STRONG IRRITANT OF THE SKIN. INGESTION: MAY
CAUSE IRRITATION OF THE DIGESTIVE TRACT. MAY CAUSE EFFECTS SIMILAR
TO THOSE FOR INHALATION EXPOSURE. INHALAT ION: MAY CAUSE
RESPIRATORY TRACT IRRITATION. MAY CAUSE KIDNEY DAMAGE. MAY BE
HARMFUL IF INHALED. INHALATION MAY PRODUCE NAUSEA, VOMITING,
ANOREXIA, COLIC, HIGH BLOOD PRESSURE, HEPATOMEGALY, JAUNDICE A ND
(EFFECTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:DIMETHYLFORMAMIDE: IARC MONOGRAPHS ON
EVALUATION OF CARCINOGENIC RISK OF CHEMICALS TO MAN, VOLUME 47,
PAGE 171, 1989:GROUP 2B.
Effects of Overexposure:HEALTH HAZARDS: ALTERED LIVER FUNCTION.
CHRONIC: POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY
ANIMALS. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH EYES W/PLENTY OF WATER FOR AT LEAST
15 MINUTES, OCCASIONALLY LIFTING UPPER & LOWER LIDS. GET MEDICAL
AID IMMEDIATELY. SKIN: GET MEDICAL AID IMMEDIATELY. IMMEDIATELY
FLUSH SKINW/PLENTY OF SOAP & WATER FOR AT LEAST 15 MINUTES WHILE
REMOVING CONTAMINATED CLOTHING & SHOES. INGEST: IF VICTIM IS
CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE
ANYTHING BY MOUTH T O UNCONSCIOUS PERSON. GET MEDICAL AID
IMMEDIATELY. INHAL: GET MEDICAL AID IMMEDIATELY. REMOVE FROM
EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIF FICULT, GIVE OXYGEN.
NOTES TO MD: NONE.
===================== Fire Fighting Measures =====================
Flash Point:=58.C, 136.4F
Autoignition Temp:=445.C, 833.F
Lower Limits:2.2%
Upper Limits:15.2%
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEM, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESIST FOAM. USE WATER SPRAY TO COOL
FIRE-EXPOSED CNTNRS. WATER MAY BE INEFTIVE. FOR LARGE FIRES, USE
(SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . CONTACT PROFESSIONAL FIRE-FIGHTERS IMMEDIATELY. COOL
CONTAINERS W/FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS
OUT. NFPA RATING: HEALTH-1; FLAMMABILITY-2; REACTIVITY-0.
Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO SOURCE OF IGNITION &
FLASH BACK. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
FLAMMABLE LIQUID. VAPORS MAY BE HEAVIER THAN AIR. THEY CAN SPREAD
ALONG GROUND & COLLECT IN LOW OR CONFINED AREAS. VAPORS MAY FORM
AN EXPLOSIVE MIXTURE W/AIR. CONTAINERS MAY EXPLODE WHEN HEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION. ABSORB SPILL
W/INERT MATERIAL (EG, DRY SAND OR EARTH), THEN PLACE INTO CHEMICAL
WASTE CONTAINER. DO NOT FLUSH INTO A SEWER. REMOVE ALL SOURCES OF
IGNIT. A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS. WATER
SPRAY MAY REDUCE VAPOR BUT MAY NOT PREVENT IGNITION IN CLOSED
SPACES.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME.
KEEP AWAY FROM SOURCES OF IGNIT. STORE IN TIGHTLY CLOSED CNTNR.
KEEP FROM CONTACT W/OXIDIZING MATLS. STORE IN A COOL, DRY,
WELL-VENTD AREA AWAY FROM INCOMPATIBLE S UBSTANCES. WASH THOROUGHLY
AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ
VENT.
Other Precautions:GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. AVOID
CNTCT W/EYES, SKIN & CLTHG. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ
&/OR VAP) & CAN BE DANGEROUS. KEEP CNTNR TIGHTLY CLSD. AVOID CNTCT
W/HEAT, SPKS & F LAME. AVOID INGEST & INHAL. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY C NTNRS TO
(SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHES AND WASH BEFORE REUSE.
Supplemental Safety and Health
EXTING MEDIA: WATER SPRAY, FOG OR ALCOHOL-RESISTANT FOAM. DO NOT USE
STRAIGHT STREAMS OF WATER. OTHER PRECS: SPKS/OPEN FLAMES. EXPOS
LIMITS: N,N-DIMETHYLFORMAMIDE - ACGIH: 10 PPM; 30 MG/M3; SKIN-POTNT
L FOR CUTANEOUS ABSORPTION. NIOSH: 10 PPM TWA; 30 MG/M3 TWA 500 PPM
IDLH. OSHA-FINAL PELS: 10 PPM TWA; 30 MG/M3 TWA.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:153760C
Melt/Freeze Pt:=-61.C, -77.8F
Decomp Temp:=350.C, 662.F
Vapor Pres:3.725 MM HG
Vapor Density:2.5(AIR=1)
Spec Gravity:0.9450
pH:6.7
Viscosity:0.8 MPAS 20 DEG
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS TO PALE YELLOW LIQUID - CLEAR;
AMINE-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS (MINERAL, NON-OXIDIZING, EG HYDROCHLORIC ACID, HYDROFLUORIC ACID,
MURIATIC ACID, PHOSOPHORIC ACID), ACIDS (MINERAL, OXIDIZING, EG
CHROMIC ACID, HYPOCHLOROUS ACID, NITRIC ACID, SULFURIC ACID),
METALS (ALKALI & ALKALINE
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES,
STRONG OXIDANTS.
Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN,
CARBON DIOXIDE.
=================== Toxicological Information===================
Toxicological Information:CAS # 68-12-2. LD50/LC50: INHALATION, MOUSE:
LC50 = 9400 MG/M3/2H; ORAL, MOUSE: LD50 = 3700 MG/KG; SKIN, RABBIT:
LD50 = 4720 MG/KG. CARCINOGENICITY: ACGIH: A4 - NOT CLASSIFIABLE AS
HUMAN CARCINOGEN. O SHA: POSSIBLE SELECT CARCINOGEN. IARC:GROUP 2B
CARCINOGEN. EPIDEMIOLOGY: A SIGNIFICANT EXCESS OF PROSTATE CANCER
WAS OBSERVED AMONG WORKERS EXPOSED TO DMF AND ACRYLONITRILE.
TERATOGENICITY: EXPERIMENT AL TERATOGEN EFFECTS HAVE BEEN REPORTED.
REPRODUCTIVE EFFECTS: EXPERIMENTAL REPRODUCTIVE EFFECTS HAVE BEEN
REPORTED. NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: HUMAN
MUTATION DATA REPORTED. OTHER STUDIES: NO DATA AVAILABLE.
===================== Ecological Information =====================
Ecological:EXOTOXICITY: NOT AVAIL. ENVIRONMENTAL FATE: SUBSTANCE
EXPECTED TO BIODEGRADE RAPIDLY IN ENVIRONMENT & SHOULD BE HIGHLY
MOBILE IN SOIL. PHYSICAL/CHEM:NOT AVAIL. OTHER:NOT AVAIL. --FED REG
INFO:POLLUTAN TS UNDER CWA. NONE OF CHEMS IN PROD CONSIDERED HIGHLY
HAZ BY OSHA. EUROPEAN INTERNATIONAL REGS - EUROPEAN LABELING I/A/W
EC DIRECTIVES. HAZ SYMBOLS: T. RISK PHRASES: R 20/21 HARMFUL BY
INHAL & IN CNTC T W/SKIN. R 36 IRRIT TO EYES. R 61 MAY CAUSE HARM
TO UNBORN CHILD. SFTY PHRASES: S 45 IN CASE OF ACCIDENT/IF YOU FEEL
UNWELL, SEEK MED ADVICE IMMED (SHOW LABEL WHERE POSS). S 53 AVOID
EXPOS - OBTAIN S PEC INSTRUCTIONS (TRANSPORT INFO)
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:SHIPPING NAME - US DOT: N,N-DIMETHYLFORMAMIDE,
IATA:NO INFO AVAIL, RID/ADR:NO INFO AVAIL, IMO:NO INFO AVAIL,
CANADA TDG: N,N-DIMETHYLFORMAMIDE. HAZ CLASS - US DOT:3; CANADA
TDG:3. UN NUMBER: US DOT:UN 2265; CANADA TDG:UN2265. PACKING
GROUP-US DOT:III; CANADA TDG:III. ADDNL INFO: CANADA TDG: FL PT
58C. --ECOLOGICAL INFO: BEFORE USE. WGK (WATER DANGER/PROT) - CAS
#68-12-2:1. CANADA - CAS #68-12-2 LIS TED ON CANADA'S DSL/NDSL
LIST. PROD HAS WHMIS CLASSIFICATION OF B3, D2B. NOT LISTED ON
CANADA'S INGRED DISCLOSURE LIST. EXPOS LIMS: CAS #68-12-2:
OEL-AUSTRALIA:TWA 10PPM (30MG/M3); SKIN OEL-BELGIUM: T WA 10PPM
(30MG/M3); (SARA REG INFO)
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ):NONE OF THE CHEMS IN MATL
HAVE RQ. SECTION 302 (TPQ):NONE OF CHEMS IN PROD HAVE TPQ. SARA
CODES CAS #68-12-2; ACUTE, FLAM. SECTION 313: MATL CONTAINS
N,N-DIMETHYLFORMAMIDE (CAS #68-12 -2, 100%), WHICH IS SUBJECT TO
REPORTINGREQS OF SECTION 313 OF SARA TITLE III & 40 CFR PART 373.
--TRANSPORT INFO: SKIN OEL-CZECHOSLOVAKIA:TWA 30MG/M3; STEL 60
MG/M3 OEL-DENMARK:TWA 10PPM (30MG/M3); S KIN OEL-FINLAND:TWA 10PPM
(30MG/M3); STEL 20PPM (60MG/M3); SKIN OEL-FRANCE:TWA 10PPM
(30MG/M3); SKIN OEL-GERMANY:TWA 20PPM (60MG/M3); SKIN
OEL-HUNGARY:TWA 10MG/M3; STEL 20MG/M3; SKIN OEL-JAPAN:TWA 10P PM
(30MG/M3); SKIN OEL- (STATE REG INFO)
Federal Regulatory Information:CAS #68-12-2 - LISTED ON THE TSCA
INVENTORY. HLTH & SAFETY REPORTING LIST: EFTIVE DATE: APRIL
13,1989; SUNSET DATE: 12/19/1995. CHEM TEST RULES:NONE OF CHEMS IN
PROD ARE UNDER CHEM TEST RULE. NONE OF CHEMS ARE LISTED UNDER TSCA
SECTION 12B. NONE OF CHEMS IN MATL HAVE SNUR UNDER TSCA. CLEAN AIR
ACT: #68-12-2 IS LISTED AS HAZ AIR POLLUTANT. THIS MATL DOES NOT
CNTN ANY CLASS 1 OZONE DEPLETORS. MATL D OES NOT CNTN ANY CLASS 2
OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED
AS HAZ S UBSTANCES UNDER CWA. NONE OF CHEMS ARE LISTED AS PRIORITY
POLLUTANTS UNDER CWA. NONE OF CHEMS IN PROD LISTED AS TOXIC
(ECOLOGICAL INFO)
State Regulatory Information:CAS #68-12-2 CAN BE FOUND ON FOLLOWING
STATE RIGHT TO KNOW LISTS: CA, NJ, FL, PA, MN, MA. CA NO
SIGNIFICANT RISK LEVEL:NONE OF CHEMS IN PROD LISTED. --SARA TITLE
III: NETHERLANDS:TWA 10PPM (30MG/M3); SKIN OEL-PHILLIPPINES:TWA
10PPM (30MG/M3); SKIN OEL-POLAND:TWA 10MG/M3 OEL-RUSSIA:TWA 10PPM;
STEL 10MG/M3; SKIN OEL-SWEDEN:TWA 10PPM (30MG/M3); STEL 15PPM
(45MG/M3); SKIN OEL-SWITZERLAND:TWA 10PPM 930 MG/M3); STEL 20PPM;
SKIN OEL-TURKEY:TWA 10PPM (30MG/M3); SKIN OEL-UNITED KINGDOM:TWA
10PPM (30MG/M3) ; STEL 20PPM; SKIN OEL BULGARIA, COLOMBIA, JORDAN,
KOREA CHECK ACGIH TLV. OEL NEW ZEALAND, SINGAPORE, VIETNAM CHECK
ACGIH TLV.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:5006 COLD SOLVENT PAINT STRIPPER
Preparer's Name:DEBORAH A. TREWARTHA
CAGE:7R331
CAGE:7R331
============= Composition/Information on Ingredients =============
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 1-10%
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:METHANOL; (METHYL ALCOHOL)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 1-10%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ETHANOL, 2-BUTOXY-; (ETHYLENE GLYCOL MONOBUTYL ETHER)
(EGBE)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 1-10%
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
Ingred Name:FORMIC ACID (SARA III)
CAS:64-18-6
RTECS #:LQ4900000
Fraction by Wt: 10-30%
OSHA PEL:5 PPM
ACGIH TLV:5 PPM;10 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE (DICHLOROMETHANE))
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 30-60%
OSHA PEL:500 PPM, C;1000 PPM
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SUPDAT:& SYMPTOMS OF EXPOSURE: REDNESS, BURNING SENSATION,
ITCHING, INFLAMMATION, PAIN, TEARING.
RTECS #:9999999ZZ
Ingred Name:HYDROGEN FLUORIDE (SARA III)
CAS:7664-39-3
RTECS #:MW7875000
Fraction by Wt: 1-10%
OSHA PEL:3 PPM;6 PPM STEL (F)
ACGIH TLV:3 PPM (F), C
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCD SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIM EFT IN
HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED
EXCEPT FOR LIFE-SUSTAINING US ES IN HUMANS ACUTELY/CHRONICALLY
EXPOSED TO CHLOROCARBONS . NOTE:TOLUENE (108-88-3) APPEARS ON (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:GROUP 2B (IARC),
ANTICIPATED TO BE A CARCINOGEN (NTP).
Effects of Overexposure:HLTH HAZ:NAVY LIST OF OCCUP REPRO HAZS. SEEK
CONSULTATION FROM APPROP HLTH PROFS CONCERNING LATEST HAZ LIST INFO
& SAFE HNDLG & EXPOS RECS . ANIMAL STUDIES HAVE CLEARLY
DEMONSTRATED DOSE-RELATED EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD,
KIDNEYS & LIVER, ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER
(SUPDAT)
Medical Cond Aggravated by Exposure:NOT AVAILABLE.
======================= First Aid Measures =======================
First Aid:IMPORTANT TO HAVE WATER READILY AVAIL WHERE THIS PROD IS
HNDLD. EYES:IMMED FLUSH W/PLENTY OF WATER FOR @ LST 15 MINS. CONT
MD IMMED. SKIN:FLUSH W/PLENTY OF WATER. INHAL:SEEK FRESH AIR. IF
IRRIT PERSIS TS OBTAIN MED ATTN. INGEST:NEVER GIVE ANYTHING BY
MOUTH TO UNCON PERS. HAVE CONSCIOUS PERS DRINK SEVERAL GLASSES OF
WATER & INDUCE VOMIT. KEEP AIRWAY CLEAR; SEEK MD'S ATTN IMMED.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:WATER, CARBON DIOXIDE, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL HCL &
PHOSGENE . WEAR ALL PROT EQUIP. USE WATER SPRAY TO COOL CNTNRS NEAR
FIRE. PROD CONTAINS METHYLENE CHLORIDE- (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR ALL PROTECTIVE EQUIPMENT WHEN HANDLING
SPILLS OR LEAKS. DIKE & SCOOP INTO SUITABLE CONTAINER. USE
ABSORBENT MATERIAL TO PICK UP REMAINDER. FLUSH FINAL TRACES
W/PLENTY OF WATER. AVOID EXPOSURE TO HEAT, OPEN FLAMES & SPARKS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:WEAR ALL PROT EQUIP WHEN HNDLG PROD.
KEEP CNTNR CLSD WHEN NOT IN USE. DO NOT GET IN EYES/TAKE
INTERNALLY. DO NOT STORE NEAR HEAT/SPKS/OPEN FLAME.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN OF
ARC WELDING, OPEN FLAMES/HOT SURFS. HEAT &/OR UV RADIA MAY CAUSE
FORM OF HCL &/OR PHOSGENE . AVOID BRTHG OF VAPS. USE ONLY AS
DIRECTED. USE ONLY IN WELL-VENTED WORK AREAS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR ORGANIC
VAPORS TC-23C-123, I.E. 3M#8712 OR SUPPLIED AIR RESPIRATOR.
Ventilation:LOCAL EXHAUST &/OR MECHANICAL (GENERAL) VENTILATION AS
NEEDED TO CONTROL VAPORS.
Other Protective Equipment:RUBBER APRON, RUBBER BOOTS, EYE WASH &
SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE. REMOVE & WASH SOILED
CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ:MAY FORM EXPLO MIXT IN ATM OF HIGH OXYGEN CONTENT. EFTS OF
OVEREXP:(EGBE). (EXTRACTED FROM DHHS (NIOSH) PUB NO.90-118). .
ACUTE:DIRECT CONT CAN CAUSE SEV EYE & SKIN INJURY. IRRIT TO EY ES,
SKIN & MUC MEMBS. MAY CAUSE BURNS. CHRONIC:IRRIT TO EYES, SKIN &
RESP TRACT, DERM, CNS DEPRESS; BURNS. SIGNS (ING 7)
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:104F,40C
Spec Gravity:1.13 (H*2O=1)
Solubility in Water:SLIGHT
Appearance and Odor:LIGHT AMBER LIQUID; SOLVENT ODOR.
Percent Volatiles by Volume:75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS & STRONG ALKALIES.
Stability Condition to Avoid:DO NOT BURN OR USE ON HOT METALS. DO NOT
USE NEAR OPEN FLAME.
Hazardous Decomposition Products:AT HIGH TEMPS, THIS PROD DECOMPOSES TO
GIVE OFF HYDROCHLORIC ACID AS GAS PLUS OTHER TOX & IRRIT VAPS SUCH
AS PHOSGENE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF COMPLYING W/LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:S-T DRAIN OPENER
CAGE:0PZ33
CAGE:6J861
CAGE:0PZ33
CAGE:0APY9
============= Composition/Information on Ingredients =============
Ingred Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 86%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL RAT) IS 2140 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION OF VAPORS CAUSES SEVERE
IRRITATION OR BURNS OF THE RESPIRATORY SYSTEM, PULMONARY EDEMA, OR
LUNG INFLAMMATION. EYE CONTACT CAUSES SEVERE DAMAGE AND POSSIBLE
BLINDNESS. SKIN CONTACT CAUSES BU RNS AND POSSIBLE DEEP ULCERATION.
INGESTION CAUSES SEVERE BURNS TO MOUTH, THROAT, AND STOMACH.
Explanation of Carcinogenicity:THIS CHEMICAL IS NOT LISTED BY IARC,
NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:SEVERE IRRITATION OR BURNS TO EYES, NOSE AND
THROAT. PULMONARY EDEMA, BRONICAL EMPHYSEMA, CONJUNCTIVITIS,
STOMATITIS, DENTAL EROSION, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE RESPIRATORY TRACT MAY
BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION:REMOVE TO FRESH AIR. RESUSCITATE IF NOT BREATHING.
GET MEDICAL ATTENTION. EYES:IMMEDIATELY FLUSH WITH PLENTY OF WATER
FOR 15 MINUTES HOLDING EYELIDS OPEN. GET PROMPT MEDICAL ATTENTION.
SKIN :REMOVE CONTAMINATED CLOTHING. WASH WITH PLENTY OF WATER FOR
15 MINUTES. GET MEDICAL ADVICE. INGESTION:DO NOT INDUCE VOMITING.
GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET IMMEDIATE MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. EVACUATE AREA. COOL
FIRE EXPOSED CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:ACID IS ITSELF NONFLAMMABLE. BUT MAY
CAUSE IGNITION OF COMBUSTIBLE MATERIALS. HIGHLY FLAMMABLE HYROGEN
GAS IS GENERATED BY ACTION OF GAS ON METALS.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. WEAR FULL
PROTECTIVE EQUIPMENT. STOP LEAK IF YOU CAN DO SO WITHOUT RISK. DIKE
TO RETAIN RUNOFF. PUMP LIQUID TO SALVAGE TANK. NEUTRALIZE SMALL
AMOUNTS WITH SODA ASH O R LIME. MAKE SLURRY AND SHOVEL INTO
DISPOSAL DRUM.
Neutralizing Agent:SODIUM BICARBONATE OR A SODA ASH/SLAKED LIME MIXTURE
(50-50)
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. KEEP
CONTAINERS AWAY FROM HEAT. ISOLATE FROM INCOMPATIBLE MATERIALS. ADD
ACID TO WATER SLOWLY TO PREVENT SPLATTERING.
Other Precautions:ADDITION TO WATER RELEASES HEAT WHICH CAN RESULT IN
VIOLENT BOILING AND SPATTERING. ALWAYS ANDD SLOWLY AND IN SMALL
AMOUNTS. NEVER USE HOT WATER. NEVER ADD WATER TO ACIDS. ALWAYS ADD
ACIDS TO WATER. E MPTY CONTAINERS MAY BE HAZARDOUS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION EXCEEDS TLV, A NIOSH
APPROVED SELF-CONTAINED BREATHING APPARATUS IS RECOMMENDED.
Ventilation:USE SUFFICIENT MECHANICAL (GENERAL) VENTILATION TO MAINTAIN
EXPOSURE BELOW TLV REQUIREMENTS.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE IMPERVIOUS WORK CLOTHING, BOOTS AND APRON AS
REQUIRED.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:440F,227C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:1.775
Evaporation Rate & Reference:NOT SPECIFIED
Solubility in Water:COMPLETE
Appearance and Odor:DARK AMBER LIQUID WITH VERY SLIGHT ACID ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI OXIDIZING AGENTS
Stability Condition to Avoid:CONTACT WITH CAUSTIC OR WATER
Hazardous Decomposition Products:OXIDES OF SULFUR AND HYDROGEN
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL SHOULD BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DIESEL FUEL NO. 2, LOW/HIGH SULFUR; 3502;3504;3510;4152.
Preparer's Name:MSDS ADMINISTRATOR
CAGE:5R396
CAGE:5R396
============= Composition/Information on Ingredients =============
Ingred Name:DIESEL FUEL, NO. 2 (PETROLEUM MID-DISTILLATE).
CAS:68476-34-6
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL RAT = 9ML/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE IRRIT TO EYES/LUNGS/SKIN AFT
PROLONG/REPEAT EXPOSURE. ASPIRATION INTO LUNGS MAY CAUSE LUNG
DAMAGE & DEATH.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:OVEREXPOSURE MAY CAUSE WEAKNESS,HEADACHE,
NAUSEA,CONFUSION,BLURRED VISION,DROWSINESS,UNSPECIFIED CNS
EFFECTS.LARGE EXPOSURE MAY CAUSE DIZZINESS,SLURRED SPEECH,FLUSHED
FACE,UNCONSCIOUSNESS, CONVULSIONS .STUDIES IN MICE/RATS W/CHRONIC
EXPOUSRE HAVE SHOWN DIESEL EXHAUST MAY PRODUCE LUNG TUMORS AND
LYMPHOMAS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MFG.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN IF BREATH DIFFI OR ARTI
RESP IF NOT BRETH.CALL PHYSICIAN.SKIN:WASH W/SOAP & WATER.IF IRRIT
DEVELOP/PERSIST,CALL PHYSICIAN.EYES:IMMED FLUSH W/PLENTY OF WATER
FOR @ 15MINS.CALL PHYSICIAN.INGEST:DO NOT INDUCE VOMITING.IF
CONSCIOUS GIVE 2 GLASSES OF WATER.PHYSICIAN:GIVE 5ML/KG (OR 350ML)
OF CHARCOAL SOLUTION (50GMS CHARCOAL IN 400ML WATER).
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:130F,54C
Lower Limits:0.4
Upper Limits:6
Extinguishing Media:WATER SPRAY, FOAM, DRY CHEMICAL, CARBON DIOXIDE.
NFPA CLASSIFICATION:CLASS II COMBUSTIBLE LIQUID.
Fire Fighting Procedures:DON'T ENTER ENCLOSE/CONFINE SPACE W/O PROPER
PROT EQPMT INCLUDING RESP PROT.W/WATER SPRAY COOL FIRE EXPOSED
CNTNRS & DISPERSE/FLUSH VAP/PROTECT FROM SPILL/LEAK.
Unusual Fire/Explosion Hazard:PRODUCTS OF COMBUSTION MAY CONTAIN CARBON
MONOXIDE, CARBON DIOXIDE & OTHER TOXIC MATERIALS.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE IGNITION SOURCES.USE EXPLOSION-PROOF
EQPMT & APPROPRIATE PPE.DIKE & PREVENT FROM ENTERING
SEWERS/WATERWAYS.SOAK UP W/ABSORBENT MATL.(SAWDUST,SAND,OIL DRY).IF
SPILLED INTO NAVIGABLE WATERS REPOR T TO NAT RESP CNTR
800-424-8802.READ MSDS.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN WELL-VENTILATED AREA.KEEP
CONTAINER TIGHTLY CLOSED.STORE IAW NAT FIRE PROTECTION ASSOC
RECOMMENDATIONS.STORE AWAY FROM HEAT/SPARKS/FLAME/OXID
Other Precautions:DO NOT BREATH VAPORS/MISTS.GROUND CONTAINERS WHEN
TRANSFERRING LIQUID (FLOWING FUEL GENERATES STATIC ELECTRICITY).
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELECT APPROPRIATE NIOSH-APPROVED RESP
PROTECTION WHEN NEEDED TO AVOID INHAL OF MIST/VAPORS AND TO
MAINTAIN EXPOSURES BELOW ACCEPTABLE LIMITS.
Ventilation:USE ONLY WITH ADEQUATE VENTILATION. MECHANICAL (GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Other Protective Equipment:COVERALLS IF SPLASHING IS PROBABLE.
Work Hygienic Practices:WASH HANDS AFTER HANDLING. LAUNDER CONTAMIN
CLOTHES PRIOR TO REUSE.
Supplemental Safety and Health
NOT SUBJECT TO CA PROP 65. CONTAINS DIESEL FUEL OIL SUBJECT TO PEN
WORKER/COMM RIGHT TO KNOW.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:350F,177C
Vapor Pres:1MM@68F
Vapor Density:>1
Spec Gravity:0.84-0.88 @60C
Viscosity:1.9CAT@40C
Solubility in Water:INSOLUBLE
Appearance and Odor:AROMATIC ODOR;LIQUID;HIGH SULFUR-GREEN;LOW
SULFUR-RED OR UNDYED(CLEAR OR STRAW)
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCMPATIBLE OR CAN REAC WTIH STRONG OXIDIZERS.
Stability Condition to Avoid:AVOID HEAT, SPARKS, FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE, AND
OTHER TOXIC MATERIALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:TREATMENT/STORAGE/TRANSP/DISPOSAL MUST BE IAW
APPLICABLE FED/STATE/PROVINCIAL/LOC REGS.DO NOT FLUSH TO SURFACE
WATER/SANITARY SEWER SYS.BY ITSELF LIQ IS EXPECTED TO BE RCRA
IGNITABLE HAZ WASTE.CONTAIN S PETRO
HYDROCARBONS-RQ(FILM/SHEEN/DISCOLO WATER.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:G185 SPECIALTY STEEL
CAGE:GO164
CAGE:0R811
CAGE:GO164
============= Composition/Information on Ingredients =============
Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC
OXIDE/METAL OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT/IRON
CAS:1309-37-1
RTECS #:NO7400000
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 9293
Ingred Name:MANGANESE, MN COMPOUNDS
CAS:7439-96-5
RTECS #:OO9275000
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
Ingred Name:MOLYBDENUM (SOLUBLE COMPOUND), LEAD MOLYBDATE
CAS:7439-98-7
RTECS #:QA4680000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
Ingred Name:NICKEL (SOLUBLE) (SUSPECTED HUMAN CARCINOGEN BY NTP, IARC,
ACGIH) INTENDED CHANGE (IC)
CAS:7440-02-0
RTECS #:QR5950000
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
ACGIH TLV:0.05 MG/CUM IC
Ingred Name:VANADIUM
CAS:1314-62-1
RTECS #:YW1355000
OSHA PEL:C,0.5 MG/M3
ACGIH TLV:0.05 MG/M3RDUST;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:TANTALUM
CAS:7440-25-7
RTECS #:WW5505000
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:TITANIUM DIOXIDE, TIO2
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER
CAS:7440-50-8
RTECS #:GL5325000
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ALUMINUM (POWDER)
CAS:7429-90-5
RTECS #:BD0330000
OSHA PEL:15 MG/CUM
ACGIH TLV:10 MG/CUM (DUST)
Ingred Name:BORON OXIDE, TRIOXIDE
CAS:1303-86-2
RTECS #:ED7900000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
Ingred Name:COBALT
CAS:7440-48-4
RTECS #:GF8750000
Other REC Limits:0.05 PPM
OSHA PEL:0.1 MG/M3;AS CO
ACGIH TLV:0.05 MG/M3;DUST 9293
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN
CARCINOGEN BY IARC, NTP & ACGIH)
CAS:7440-47-3
RTECS #:GB4200000
OSHA PEL:1 MG/CUM (CEILING)
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: HEATING, CUTTING, BRAZING
OR WELDING MAY CAUSE ADVERSE HEALTH EFFECTS DUE TO SOME OF THE
CONSTITUENTS IN THE FORMULA.
Explanation of Carcinogenicity:SEE INGREDIENTS
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL RESPIRATION
IF BREATHING STOPS, OR OXYGEN IF NECESSARY. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Fire Fighting Procedures:NO FIRE OR EXPLOSION HAZARD.
======================Handling and Storage ======================
Handling and Storage Precautions:DURING WELDING, PRECAUTIONS SHOULD BE
TAKEN FOR AIRBORNE CONTAMINANTS & NOXIOUS GASES THAT MAY ORIGINATE
FROM COMPONENTS OF WELDING ROD.
Other Precautions:WHEN HEATED FOR HOT DEFORMATION, PRECAUTIONS SHOULD
BE TAKEN TO PREVENT BURNS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE DUST MASK WHEN HANDLING IN ITS POWDER FORM.
USE PROPERLY FITTED, NIOSH APPROVED, DUST FUME RESPIRATOR DURING
WELDING OR BURNING WHEN FUMES EXCEED TLV.
Ventilation:EXHAUST SYSTEMS WHEN ABRASIVE CUTTING, GRINDING, WELDING &
BURNING.
Other Protective Equipment:AS REQUIRED FOR THE OPERATION BEING
PERFORMED.
Supplemental Safety and Health
BURRS MAY EXIST ON THE MATERIAL.
================== Physical/Chemical Properties ==================
Appearance and Odor:SOLID W/METALLIC LUSTRE ODORLESS.
SHEETS/STRIP/BARS/RODS/BILLETS/SHAPES/PROFILE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:METAL FUMES & CERTAIN NOXIOUS GASES
SUCH AS CO MAY BE PRODUCED DURING WELDING OR BURNING
==================== Disposal Considerations ====================
Waste Disposal Methods:IF IS RECOMMENDED ALL SCRAP GENERATED BE
RECLAIMED & SUBSEQUENTLY RECYCLED. DISPOSE OF IN ACCORDANCE
W/FEDERAL, STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: SILVER-COPPER-PHOSPHORUS BRAZING ALLOYS,SIL-FOS 5 (71-050)
Cage: 91874
=======================================================
Contractor Summary
=======================================================
Cage: 91874
=======================================================
Ingredients
=======================================================
Cas: 7440-50-8
RTECS #: GL5325000
% low Wt: 27.
% high Wt: 92.6
Other REC Limits: N/K (FP N)
OSHA PEL: 1 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 1 MG/M3
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
------------------------------
Cas: 7723-14-0
RTECS #: TH3495000
% low Wt: .01
% high Wt: 7.25
Other REC Limits: N/K (FP N)
OSHA PEL: 0.1 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.1 MG/M3;0.02 PPM
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 7440-22-4
RTECS #: VW3500000
% low Wt: .9
% high Wt: 73.
Other REC Limits: N/K (FP N)
OSHA PEL: 0.01 MG/M3
OSHA STEL: N/K (FP N)
ACGIH TLV: 0.1 MG/M3
ACGIH STEL: N/K (FP N)
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INHAL: INHAL OF COMPONENTS OF THESE PRODS IS NOT
KNOWN TO PRESENT A SIGNIFICANT RISK TO HLTH WHEN USED ACCORDING TO
INSTRUCTIONS & W/APPROP PROT MEASURES. INHAL OF COMPONENT ELEMENTS HAS
BEEN R EPORTED TO CAUSE ONE/MORE OF THE FOLLOWING SYMPS & EFTS UPON
EXCESS HIGH/PRLNG EXPOS: COPPER: ACUTE EXPOS MAY CAUSE RESP TRACT IRRIT,
FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAK, & METALLIC TASTE. PHOSPHO RUS:
THE RED FORM OF PHOSPHORUS IS STABLE & RELATIVELY NON-TOX AT ROOM TEMP.
WHEN HEATED IN PRESENCE OF AIR, IT IS CONVERTED TO PHOSPHORUS PENTOXIDE,
WHICH IS CORR & IRRITATING TO EYES, NOSE, THROAT, & MUC MEMBS. (EFTS
OF OVEREXP)
Explanation Of Carcinogenicity: NONE OF THE COMPONENTS OF THESE PRODUCTS ARE
CLASSIFIED AS POTENTIAL OR DEMONSTRATED HUMAN CARCINOGENS BY IARC, NTP, OR
OSHA.
Signs And Symptions Of Overexposure: HLTH HAZ: SKIN: CONT W/THESE PRODS IN
FINELY-DIVIDED FORMS MAY CAUSE ARGYRIA, IRRIT, DISCOLORATION, &/OR CONT
DERM. EYES: CONT W/THESE PRODS IN FINELY-DIVIDED FORMS MAY CAUSE IRRIT,
ARGYRIA, CONJ, &/O R ULCERATION OF CORNEA. INGEST: INGEST OF THESE PRODS
IN FINELY-DIVIDED FORMS MAY CAUSE NAUS, VOMIT, & GI IRRIT. CHRONIC:
INHAL: COPPER: EXPOS MAY DMG LIVER, KIDNEY, SPLEEN, PANCREAS, & BRAIN.
SILVER: CHRONIC EXPOS MAY PRDCE ARGYRIA, A PERM BLUE-GRAY DISCOLORATION OF
SKIN, EYES, MUC MEMBS, & RESP TRACT. INGEST: LONG-TERM CHRONIC INGEST MAY
DMG LIVER, KIDNEYS, & GI SYS.
Medical Cond Aggravated By Exposure: PRE-EXISTING PULM DISEASES (BRONCH,
ASTHMA) MAY BE AGGRAVATED BY INHAL EXPOS, PARTICULARLY AS FUME. CHRONIC EXPOS
BY INHAL &/OR INGEST MAY AGGRAVATE PRE-EXISTING DISEASES OF LIVER,
KIDNEYS, & GI SYS.
First Aid: INHALATION: IF SIGNS AND SYMPTOMS OF TOXICITY ARE OBSERVED, REMOVE
SUBJECT FROM AREA, ADMINISTER OXYGEN, AND SEEK MEDICAL ATTENTION. KEEP THE
SUBJECT WARM AND AT REST. PERFORM ARTIFICIAL RESPIRATION I F BREATHING HAS
STOPPED. SKIN: REMOVE CONTAMINATED CLOTHING. WASH AFFECTED AREA WITH LARGE
QUANTITIES OF WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL ASSISTANCE IF
NECESSARY. EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES. SEEK MEDICAL
ASSISTANCE IF NECESSARY. INGESTION: IF SUBJECT IS CONSCIOUS, INDUCE VOMITING.
IF UNCONSCIOUS OR CONVULSIVE, SEEK IMMEDIATE MEDICAL ASSISTANCE.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: IF A FINELY-DIVIDED FORM OF PRODUCT IS SPILLED, CLEAN
UP SPILLAGE SO AS TO MINIMIZE DISPERSION OF DUST. WET SWEEPING OR VACUUMING
USING HEPA FILTRATION ARE RECOMMENDED.
Waste Disposal Methods: CONSULT THE MANUFACTURER FOR DISPOSITION OF UNUSED OR
UNUSABLE PRODUCT. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS (FP N).
Handling And Storage Precautions: DO NOT STORE IN PROXIMITY TO INCOMPATIBLE
MATERIALS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: USE DRY CHEMICAL. DO NOT USE WATER.
Fire Fighting Procedures: WEAR NIOSH APPROVED SELF-CONTAINED BREATHING
APPARATUS AND FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: IN FINELY-DIVIDED FORM, THESE PRODUCTS MAY
IGNITE WHEN EXPOSED TO FLAME OR BY REACTION WITH INCOMPATIBLE MATERIALS. IF
PRESENT IN A FIRE OR EXPLOSION, THEY MAY EMIT FUMES OF THE CONSTITUENT METALS
OR METAL OXIDES AND PHOSPHORUS PENTOXIDE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: IF EXPOSURE LEVEL EXCEEDS AN OSHA PEL/OTHER APPLICABLE
STANDARD, USE NIOSH-APPROVED RESPIRATOR HAVING CONFIGURATION (CLASS, TYPE OF
FACEPIECE, FILTER MEDIA, ASSIGNED PROTECTION FACTOR, ETC) APPROPRIAT E TO
CONCENTRATION OF CONTAMINANT(S) GENERATED. FOR GUIDANCE ON SELECTION &
USE OF RESPIRATORY PROTECTION, CONSULT ANSI Z88.2 (ANSI, NEW YORK, NY 10036
USA).
Ventilation: USE APPROP VENT (E.G., DILUTION, LOC EXHST) ADEQ TO MAINTAIN CONCS
OF ALL COMPONENTS & THEIR DECOMP BYPRODS TO W/IN THEIR RESPECTIVE OSHA
PEL/OTHER APPLIC STDS.
(FP N).
Other Protective Equipment: ANSI APPRVD EMER EYEWASH & DELUGE SHOWER (FP N).
WEAR APPROP PROT CLTHG TO PVNT SKIN INJURIES FROM HAZS OF BRAZING &/OR FOR
PRLNG/RPTD CONT W/FINELY-DIVIDED FORMS OF PROD. AVOID FLAMM FABRICS.
Work Hygienic Practices: TO MINIMIZE THE POSSIBILITY OF INGESTION, WASH HANDS
AND FACE BEFORE EATING, DRINKING, APPLYING COSMETICS, OR USING TOBACCO.
Supplemental Safety and Health: APPEARANCE/ODOR: TAPE, GRAIN, OR PREFORMED
SHAPES. MATERIALS TO AVOID: FERRIC CARBONYL, SELENINYL BROMIDE. CHEMICAL
FORMULA: ALLOYS OF SILVER, COPPER, AND PHOSPHORUS.
=======================================================
Physical/Chemical Properties
=======================================================
Melt/Freeze Pt: =643.3C, ######F
Spec Gravity: 7.86 - 8.44
Solubility in Water: INSOLUBLE
Appearance and Odor: ODORLESS LIGHT-COPPER METALS IN FORM OF WIRE, ROD, STRIP,
POWDER, (SUP DAT)
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES SULFIDE, (SUP DAT)
Stability Condition To Avoid: STABLE AT ROOM TEMPERATURE. SILVER AND COPPER CAN
FORM UNSTABLE ACETYLIDES UPON CONTACT WITH ACETYLENE GAS.
Materials To Avoid: AMMONIA, HNO*3, AZIDES, ETHANOL, ETHYLENE IMINE, MG,
CHLORATES, BROMATES & IODATES, INORG & ORG PEROXIDES, PEROXYFORMIC ACID,
NITROBENZENE, HALOGENS, PERMONOSULFONIC ACID, SEOCL, SEOF, SEF*4, HYDRAZINE
MONONITRATE, CARBON D
Hazardous Decomposition Products: HEATING TO ELEVATED TEMPERATURES MAY LIBERATE
METAL/METAL OXIDE FUME AND PHOSPHORUS PENTOXIDE.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
=======================================================
Transport Information: HAZARD CLASS: SHIPMENT NOT CONTROLLED BY USDOT/ICAO/IMO
REGULATIONS.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: HAZARD CLASSES: ACUTE HEALTH HAZARD, CHRONIC HEALTH
HAZARD. SECTION 313 SUPPLIER NOTIFICATION: THIS PRODUCT CONTAINS THE
FOLLOWING TOXIC CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION
313 OF THE EMERGENCY PLANNING & COMMUNITY RIGHT-TO-KNOW ACT (EPCRA) OF
1986 AND OF 40 CFR 372: COPPER, CAS # 7440-50-8, 27-92.6 PERCENT OF MIXTURE;
PHOSPHORUS, CAS # 7723-14-0, 0.01-7.25 PERCENT OF MIXTUR E; SILVER, CAS #
7440-22-4, 0.9-73 PERCENT OF MIXTURE. THIS INFORMATION MUST BE INCLUDED ON
ALL MSDS THAT ARE COPIED AND DISTRIBUTED FOR THIS MATERIAL.
=======================================================
HAZCOM Label
=======================================================
Product ID: SILVER-COPPER-PHOSPHORUS BRAZING ALLOYS,SIL-FOS 5 (71-050)
Cage: 91874
Company Name: LUCAS-MILHAUPT INC A HANDY & HARMAN CO
Street: 5656 SOUTH PENNSYLVANIA AVENUE
Zipcode: 53110
Label Required IND: Y
Date Of Label Review: 06/20/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHAL: INHAL OF COMPONENT ELEMENTS HAS BEEN
REPORTED TO CAUSE ONE/MORE OF THE FOLLOWING SYMPS & EFTS UPON EXCESS
HIGH/PRLNG EXPOS: RESP TRACT IRRIT, FEVER, MUSCLE ACHE, CHILLS, COUGH, WEAK,
& M ETALLIC TASTE. IRRITATING TO EYES, NOSE,THROAT, & MUC MEMBS.
SKIN: MAY CAUSE ARGYRIA, IRRIT, DISCOLORATION &/OR CONTACT DERM. EYES:
MAY CAUSE IRRIT, ARGYRIA, CONJUCTIVITIS &/OR ULCERATION OF CORNEA. I
NGEST: MAY CAUSE NAUS, VOMIT, & GI IRRIT. CHRONIC: INHAL OVEREXP MAY
DAMAGE LIVER, KIDNEY, SPLEEN, PANCREAS & BRAIN. INGEST OVEREXP MAY DAMAGE
LIVER, KIDNEYS & GI SYSTEM.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TRAFFIC PAINT, RED, WATER BORNE, WCP-706 SERIES
Preparer's Name:DAN DULAVA
CAGE:WC0LL
CAGE:WC0LL
CAGE:WSTPA
============= Composition/Information on Ingredients =============
Ingred Name:SILICA, CRYSTALLINE - QUARTZ; (CRYSTALLINE SILICA) MAY
CONTAIN INGS 2,3 & 4
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 11.05%
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3 RDUST
Ingred Name:FORMALDEHYDE (SARA 302/313) (CERCLA)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: <0.1%
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM, A2
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:ETHYLENE OXIDE (SARA 302/313) (CERCLA)
CAS:75-21-8
RTECS #:KX2450000
Fraction by Wt: <0.1%
OSHA PEL:1 PPM; SEE 1910.1047
ACGIH TLV:1 PPM, A2
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:ACETALDEHYDE (SARA 313) (CERCLA)
CAS:75-07-0
RTECS #:AB1925000
Fraction by Wt: <0.1%
OSHA PEL:200 PPM
ACGIH TLV:C 25PPM, A3
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:CALCIUM CARBONATE
CAS:1317-65-3
RTECS #:EV9580000
Fraction by Wt: 26%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:VOLATILE ORGANIC COMPOUND LB/GAL:UNDER 250 (G/L)
RTECS #:9999999VO
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:TRACE COMPONENT AND RESIDUAL
MONOMER VAPORS MAY BE IRRITATING TO EYES, SKIN, MUCOUS MEMBRANES,
RESPIRATORY TRACT, AND MAY PRODUCE SYMPTOMS OF HEADACHE, NAUSEA IN
POORLY VENTILATED AREAS. PROLONG ED CONTACT MAY CAUSE TRANSIENT
REDDENING OF SKIN. DIRECT EYE CONT MAY CAUSE IRRITATION. THIS
PRODUCT (EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC
MONOGRAPHS, SUPP. VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL RPT
ON CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ:CONTAINS CRYSTALLINE SILICA WHICH IS
CONSIDERED A HAZ BY INHAL. CRYSTALLINE SILICA HAS BEEN CLASSIFIED
AS PROBABLY CARCIN FOR HUMANS BY IARC. CRYSTALLINE SILICA IS ALSO
KNOWN CAUSE OF SILICOS IS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTF RESP) . EYES:IMMEDIATELY FLUSH
W/POTABLE WATER FOR MINIMUM OF 15 MINUTES, SEEK ASSISTANCE FROM MD
( ). SKIN:FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD .
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . NON-FLAMMABLE. AFTER WATER EVAPORATES, REMAINING
MATERIAL WILL BURN.
Unusual Fire/Explosion Hazard:PRODUCT WILL NOT BURN BUT MAY SPATTER IF
TEMPERATURE EXCEEDS BOILING POINT OF WATER. DRIED SOLIDS CAN BURN
GIVING OFF OXIDES OF CARBON.
================== Accidental Release Measures ==================
Spill Release Procedures:STAY UPWIND AND AWAY FROM SPILL. IF SPILL IS
INDOORS, VENTILATE AREA OF SPILL. IF LARGE SPILL, CALL SPILL
RESPONSE TEAM. NOTIFY APPROPRIATE STATE/LOCAL AGENCIES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:ALWAYS PROTECT YOURSELF WHEN USING
THIS PRODUCT. KEEP IN CLOSED CONTAINER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:MAINTAIN PROPER VENTILATION IN THE WORKING AREA TO KEEP AIR
CONTAMINANT CONC BELOW OSHA PERMISSIBLE EXPOSURE LEVEL.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
PROT CLTHG AS REQD TO PREVENT SKIN CONTACT.
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMOKING/USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG BEFORE
REUSE.
Supplemental Safety and Health
EXPLAN OF CARCIN:1994:ANTIC TO BE CARCINOGEN.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>210F,>99C
Vapor Density:HVR/AIR
Spec Gravity:1.74
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:DILUTABLE
Appearance and Odor:OPAQUE LIQUID, MILD PAINT ODOR.
Percent Volatiles by Volume:48.72
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID MINERALS THAT REACT WITH WATER.
Stability Condition to Avoid:AVOID FREEZING.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY
PRODUCE CARBON MONOXIDE AND CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL,
COUNTY, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:2724 DEFENDER RUST REMOVER
Preparer's Name:RICK GLISSON
CAGE:66086
CAGE:66086
============= Composition/Information on Ingredients =============
Ingred Name:NON HAZARDOUS INGREDIENTS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN IRRITATION. DO NOT GET
IN EYES, ON SKIN OR IN CLOTHING. AVOID BREATHING MISTS. INGEST:
INTERNAL IRRITATION & DAMAGE CAN RESULT IF INGESTED. SKIN:
IRRITATING TO SKIN. EYES: CONTACT OF TH E LIQUID WITH/EYES MAY
RESULT IN IRRITATION OR BURNS DEPENDING UPON EXTENT OF EXPOSURE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:DO NOT INDUCE VOMIT.IMMED GIVE LG QTYS OF WATER.IF
VOMIT DOES OCCUR, GIVE FLUIDS AGAIN.DO NOT INDUCE VOMIT/GIVE
ANYTHING BY MOUTH TO UNCON PERS.CALL MD/NEAREST POISON CONTROL
CENTER IMMED.SKIN: IMMED FLUSH ALL AFFECTED AREAS W/LG AMTS OF
WATER FOR @ LST 15 MIN.REMOVE ALL CONTAMD CLTHG.IMPORTANT:BE SURE
TO DISCARD CONTAMD CLTHG & SHOES. EYES: IMMED FLUSH W/LG QTYS OF
RUNNING WATER (SUPP DATA)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE AND WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SM:FLUSH W/WATER. WEAR SUITABLE PROT CLTHG &
EYE PROT TO PVNT SKIN & EYE CONT. LG SPILL:NEUT SPILL AREA W/SODA
ASH & THEN FLUSH AREA W/COPIOUS AMTS OF WATER. EXERCISE CAUTION
DURING NEUT AS HEAT MAY B E GENERATED.LG:FLUSH W/COPIOUS AMTS OF
WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:ALWAYS STORE UNUSED PORTION IN
ORIGINAL CNTNR W/CAP SECURE. NEVER STORE IN UNLABELED/IMPROPERLY
LABELD CNTNR.
Other Precautions:CNTNRS SHLD BE STORED IN COOL, DRY, WELL-VENTED AREA.
EXERCISE DUE CAUTION TO PVNT DAM TO/LEAKAGE FROM CNTNR. ALWAYS USE
PLASTIC CNTNRS. AS W/ALL CHEMS, USE W/DUE CARE ACCORDING TO LABEL
INSTRUCTIONS & PRECS.KEEP OUT OF REACH OF (SUPP DATA)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE ADEQ VENTILATION IS NOT AVAILABLE,
NIOSH//MSHA APPROVED RESPIRATORS SHLD BE USED TO REDUCE EXPOSURE.
SAFETY GLASSES OR FACE SHIELD MAY BE REQUIRED IN CERTAIN USE
CONDITIONS TO PREVENT EYE CONT/I RRIT, SUCH AS SPRAYING
APPLICATION.
Ventilation:ADEQUATE VENTILATION.
Other Protective Equipment:IMPERVIOUS CLOTHING AND FOOTWEAR IF NEEDED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VP: SAME AS WATER. FIRST AID PROC: FOR A MINIMUM OF 15 MIN. HOLD LIDS
APART DURING FLUSHING TO COMPLETELY RINSE ALL SURFACES. OTHER PREC:
CHILDREN. FOR COMMERCIAL/INDUSTRIAL USE ONLY.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:212F,100C
Vapor Pres:SUPP DATA
Vapor Density:HVR/AIR
Spec Gravity:1.1 (WATER=1)
pH:<2
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:MIXES WITH WATER
Appearance and Odor:WHITE, MEDIUM BODIED LIQUID WITH LOW ODOR.
Percent Volatiles by Volume:>50
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SOFT METALS SUCH AS ALUMINUM, MAGNESIUM, ZINC.
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:LARGE SPILL: IF MATERIAL IS NOT TO BE
NEUTRALIZED, THEN DIKE PRODUCT WITH ABSORBENT AND DISPOSE AT
APPROVED LANDFILL. CONTAINER DISPOSAL: THOROUGHLY DOT HAZARD
CLASSIFICATION NOT REGULATED. DISPOSE OF I/A/W FEDERAL, STATE &
LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BLACK DEVELOPER FOR DC111, ETC
CAGE:0AH08
CAGE:79775
CAGE:0AH08
CAGE:65678
============= Composition/Information on Ingredients =============
Ingred Name:IRON OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: 70%
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 9293
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:15MG/M3 TDUST/5 FUME
ACGIH TLV:10MG/M3 TDUST; 9293
Ingred Name:MAGNESIUM OXIDE
CAS:1309-48-4
RTECS #:OM3850000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:15 MG/M3 PARTICULATE
ACGIH TLV:10 MG/M3;TDUST; 9293
Ingred Name:CUPRIC OXIDE
CAS:1317-38-0
RTECS #:GL7900000
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG CU/M3
ACGIH TLV:1 MG CU/M3
Ingred Name:BLACK TONER FOR DC-111
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RAT LD50 IS NOT KNOWN
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS PRACTICALLY NON-TOXIC. IT
PRODUCES PHYSICAL IRRITATION OF BODY TISSUES. RESPIRATORY
IRRITATION MAY OCCUR IF LARGE AMOUNTS OF DUST ARE INHALED.
Explanation of Carcinogenicity:THE PRODUCT CONTAINS NO INGREDIENT THAT
IS LISTED BY IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE:PHYSICAL IRRITATION SKIN:POSSIBLE
IRRITATIONINHALED:RESPIRATORY IRRITATION WITH EXPOSURE TO LARGE
AMOUNTS OF DUST. INGESTED:NOT REPORTED.
Medical Cond Aggravated by Exposure:NONE REPORTED
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH
SOAP & WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE
REUSE. INHALED:REMOVE TO FRESH AIR. RESTORE BREATHING IF
NECESSARY.INGESTED:D O NOT INDUCE VOMITING. GIVE 2 LARGE GLASSES
OF MILK OR WATER AND GET IMMEDIATE MEDICAL CARE. GIVE NOTHING BY
MOUTH IF UNCONSCIOUS. IF IRRITATION PERSISTS OR IS SEVERE,SEE A
DOCTOR.
===================== Fire Fighting Measures =====================
Flash Point:NOT RELAVANT
Extinguishing Media:USE CARBON DIOXIDE,
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY. CONTAIN RUNOFF.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP BEING CAREFUL TO CREATE AS LITTLE
DUST AS POSSIBLE OR VACUUM.
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY, DARK AREA. KEEP
TIGHTLY CLOSED.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATOR WILL NOT NORMALLY BE NECESSARY. USE
NIOSH/MSHA APPROVED RESPIRATOR FOR DUST IF EXPOSURE IS ABOVE THE
TLV/PEL FOR NUISANCE DUST.
Ventilation:NOT NORMALLY REQUIRED.
Other Protective Equipment:NONE REQUIRED
Work Hygienic Practices:USE OF GOOD PERSONAL HYGIENE PRACTICES IS
SUFFICIENT. AVOID INHALATION,INGESTION OR SKIN CONTACT IF POSSIBLE.
Supplemental Safety and Health
BLACK DEVELOPER IS USED FOR MODELS
DC-211,213RE,313Z,313ZD,4055,4085,2105.
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:POWDER
pH:UNKNON
Solubility in Water:NEGLIGIBLE
Appearance and Odor:FINE BLACK POWDER, PRACTICALLY ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE GIVEN BY MANUFACTURER (SUPPLIER).
Hazardous Decomposition Products:NONE GIVEN BY MANUFACTURER (SUPPLIER).
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W ALL FEDERAL, STATE AND LOCAL
REGULATIONS. DGSC-SSH SUGGESTS THAT DISPOSAL MAY BE DONE AS THOUGH
PRODUCT WERE ORDINARY REFUSE.
| 1 | eyes_protection_mandatory |
=======================================================
NIIN: 01-398-2513
Product ID: H7143, NICAD BATTERY, SEALED
Article: Y
Cage: 56469
Box: 1508
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: BATTERY, STORAGE
Unit of Issue: EA
=======================================================
Regulated Components
=======================================================
Regulated Component Name: CADMIUM & CADMIUM HYDROXIDE
Percent Text: 13-15%
Regulated Component Name: POTASSIUM HYDROXIDE
CAS: 1310-58-3
Percent Text: 2-4%
Regulated Component Name: NICKEL & NICKEL HYDROXIDE
Percent Text: 20-30%
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NOT PROVIDED
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Explanation Of Carcinogenicity: CONTAINS CADMIUM.
Signs And Symptions Of Overexposure: UNDER NORMAL USE, H7143 BATTERY DOES NOT
RELEASE TOXIC MATERIAL.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: ELECTROLYTE, POTASSIUM HYDROXIDE IS CAUSTIC. DO NOT
ALLOW SKIN OR EYE CONTACT. FLUSH WITH WATER. THERE IS ONLY A TRACE AMOUNT OF
POTASSIUM HYDROXIDE AVAILABLE IN THE BATTERY.
Neutralizing Agent: NOT PROVIDED
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE &
FEDERAL REGULATIONS.
Handling And Storage Precautions: DO NOT INCINERATE OR MUTILATE; MAY BURST
RELEASING TOXIC MATERIAL.
Other Precautions: DO NOT SHOR CIRCUIT THE BATTERY, IT MAY CAUSE BURNS WHEN IN
CONTACT WITH THE SKIN OR EYES.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NOT AVAILABLE
Lower Limits: NA
Upper Limits: NA
Extinguishing Media: NO INFO AVAILABLE
Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS IF LARGE
QUANTITIES OF BATTERIES ARE ON FIRE. WAREHOUSE OR DEPOT TYPE STORAGE.
Unusual Fire/Explosion Hazard: CADMIUM FUMES MAY BE RELEASED DURING BURNING.
=======================================================
Control Measures
=======================================================
Supplemental Safety and Health: NONE
=======================================================
Physical/Chemical Properties
=======================================================
HCC: Z5
NRC/State LIC No: NOT RELEVANT
B.P. Text: NOT AVAILABLE
M.P/F.P Text: NOT AVAILABLE
Decomp Text: NOT PROVIDED
Vapor Pres: NOT AVAILABLE
Vapor Density: NA
Spec Gravity: NOT AVAILABLE
Solubility in Water: SHORT CIRCUIT
Appearance and Odor: SEALED BATTERY
Corrosion Rate: NOT PROVIDED
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: BURNING (FIRE), RUPTURING.
Materials To Avoid: NO INFORMATION AVAILABLE.
Hazardous Decomposition Products: CADMIUM FUMES MAY BE RELEASED DURING A FIRE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE
=======================================================
Toxicological Information
=======================================================
Toxicological Information: NOT PROVIDED
=======================================================
Ecological Information
=======================================================
Ecological: NOT PROVIDED
=======================================================
=======================================================
Transport Information: NOT PROVIDED
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: NOT PROVIDED
Federal Regulatory Information: NOT PROVIDED
State Regulatory Information: NOT PROVIDED
=======================================================
Other Information
=======================================================
Other Information: ALEXANDER MFG. CO. CONSIDERS THIS BATTERY AN "ARTICLE" AS
DEFINED IN 29 CFR 1910-1200 (C). FURTHER, THIS ARTICLE (BATTERY) DOES NOT
RELEASE OR OTHERWISE RESULT IN EXPOSURE TO A HAZARDOUS CHEMICAL UNDE R THE
CONDITIONS OF YOUR INTENDED USE. EACH CELL OF THE BATTERY IS A SEALED
CONTAINER ENCLOSING A NICKEL ELECTRODE, A CADMIUM ELECTRODE & POTASSIUM
HYDROXIDE ELECTROLYTE.
=======================================================
Transportation Information
=======================================================
Trans ID NO: 155081
Product ID: H7143, NICAD BATTERY, SEALED
Review Date: 10/24/2000
Multiple KIT Number: 0
Unit Of Issue: EA
Additional Data: DRY SEALED NI-CD BATTERY NOT REGULATED FOR TRANSPORTATION, PER
MFR AND PER DOT/IATA. SEE APPENDIX AOF IATA AND 49CFR173.159. MH 10/20/00.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: H7143, NICAD BATTERY, SEALED
Cage: 56469
Company Name: ALEXANDER TECHNOLOGIES INC
Street: 1511 S. GARFIELD PL
PO Box: 1508
Zipcode: 50401
Label Required IND: Y
Date Of Label Review: 10/24/2000
Status Code: A
MFG Label NO: NOT PROVIDED
Year Procured: 2000
Origination Code: F
Skin Protection IND: NO
Signal Word: NONE
Respiratory Protection IND: NO
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: NONE PROVIDED. FIRST AID: INHALATION:
DURING A FIRE INVOLVING LARGE QUANTITIES OF BATTERIES, CADMIUM FUMES MAY BE
RELEASED. SKIN: IF BATTERY RUPTURES, SKIN MAY COME IN CONTACT WITH TRAC E
AMOUNT OF POTASSIUM HYDROXIDE, WILL CAUSE A BURN. IMMEDIATELY WASH WITH
PLENTY OF WATER. EYES: IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT
LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OC CASIONALLY. GET MEDICAL
ATTENTION IMMEDIATELY. ELECTROLYTE, POTASSIUM HYDROXIDEIS CAUSTIC. DO NOT
ALLOW SKIN OR EYE CONTACT. FLUSH WITH WATER. THERE IS ONLY A TRACE AMOUNT OF
POTASSIUM HYDROXIDE AVAIL ABLE IN THE BATTERY.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:3,5-DIMETHYLPHENOL, O-876
CAGE:84898
CAGE:84898
CAGE:8Y898
============= Composition/Information on Ingredients =============
Ingred Name:3,5-XYLENOL; (3,5-DIMETHYLPHENOL)
CAS:108-68-9
RTECS #:ZE6475000
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (RAT) 608 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ALL CHEMS SHOULD BE CONSIDERED HAZ -
AVOID DIRECT PHYSICAL CONTACT! CAN BE HARMFUL IF ABSORBED THRU THE
SKIN! CAN BE HARMFUL IF INHALED! CAN BE FATAL IF ABSORBED THRU
SKIN! CAN BE FATAL IF INHALED! MA Y BE FATAL IF SWALLOWED. VAPS
&/OR DIRECT EYE CONTACT CAN CAUSE SEV EYE BURNS. CAN CAUSE EYE
IRRIT. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CAN CAUSE SKIN IRRIT. CAN BE HARMFUL
IF SWALLOWED. RPTD EXPOS TO VAPS &/OR DUST CAN CAUSE EYE INJURY.
MAY BE RAPIDLY ABSORBED THRU THE SKIN W/POTENTIAL ADVERSE HEALTH
EFTS. CAN BE FATAL OR C AUSE BLINDNESS IF SWALLOWED. CAN BE
IRRITATING TO MUCOUS MEMBRANES. PRLNGD EXPOS MAY CAUSE
NAUS/HDCH/DIZZ &/OR EYE DMG.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:ANTIDOTE IS SUBSTANCE INTENDED TO COUNTERACT EFT OF POISON.
IT SHOULD BE ADMIN ONLY BY MD/TRAINED EMER PERS. MED ADVICE CAN BE
OBTAINED FROM POIS CTL CTR. EYES:FLUSH CONTINUOUSLY W/WATER FOR AT
LEAST 15-20 MIN. SKIN: FLUSH W/WATER FOR 15-20 MIN. IF NO BURNS
HAVE OCCURRED-USE SOAP & WATER TO CLEANSE SKIN. INHAL: REMOVE TO
FRESH AIR. ADMIN OXYGEN IF HAVING DFCLTY BRTHG. IF BRTHG HAS
STOPPED (SUPDAT)
===================== Fire Fighting Measures =====================
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR APPROPRIATE OSHA-REGULATED
EQUIPMENT. VENTILATE AREA. SWEEP UP AND PLACE IN AN APPROPRIATE
CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE
ANY RESIDUES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES AND
CLOTHING. KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY PLACE. STORE
ONLY WITH COMPATIBLE CHEMICALS.
Other Precautions:PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD
NOT HANDLE THIS CHEM OR ITS CNTNR. THIS PROD IS FURNISHED FOR LAB
USE ONLY! PRODS MAY NOT BE USED AS DRUGS, COSMETICS,
AGRICULTURAL/PESTICIDAL PRODS, FOOD ADDITIVES OR AS HOUSEHOLD
CHEMS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . USE
APPROPRIATE OSHA/MSHA APPROVED SAFETY EQUIPMENT.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IN THE
LABORATORY.
Supplemental Safety and Health
FIRST AID PROC: ADMIN ARTF RESP. IF IN CARD ARREST ADMIN CPR. CONTINUE
LIFE SUPPORTING MEASURES UNTIL MED ASSISTANCE HAS ARRIVED. EYE
PROT: AND FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:432F,222C
Melt/Freeze Pt:M.P/F.P Text:151F,66C
Solubility in Water:VERY SLIGHTLY SOL
Appearance and Odor:WHITE CRYSTALLINE SOLID; PHENOL LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
REACTS W/ACID HALIDES & ANHYDRIDES. INCOMPAT W/STRONG BASES & W/STRONG
ACIDS. INCOMPAT W/STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:CORRODES STEEL. CORRODES COPPER AND ITS
ALLOYS.
Hazardous Decomposition Products:DECOMPOSITION LIBERATES TOXIC FUMES.
DECOMPOSITION PRODUCTS ARE CORROSIVE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . BURN IN A CHEMICAL INCINERATOR
EQUIPPED WITH AN AFTERBURNER AND SCRUBBER.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: SATINHIDE LATEX LO-LUSTRE ENAMEL, 88-29
Cage: 47695
Box: 9
Resp. Party Other MSDS No.: 88 LINE (042392M)
=======================================================
Contractor Summary
=======================================================
Cage: 47695
=======================================================
Ingredients
=======================================================
Cas: 1332-58-7
RTECS #: GF1670500
% low Wt: 5.
% high Wt: 10.
OSHA PEL: 15 MG/M3
ACGIH TLV: 2 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
% low Wt: 25.
% high Wt: 30.
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 112-34-5
RTECS #: KJ9100000
% low Wt: 2.
% high Wt: 5.
------------------------------
Cas: 107-21-1
RTECS #: KW2975000
% low Wt: 2.
% high Wt: 5.
ACGIH TLV: NOT ESTABLISHED
ACGIH STEL: C127 MG/M3;C50 PPM
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
------------------------------
Cas: 25265-77-4
RTECS #: UF6000000
% low Wt: 1.
% high Wt: 2.
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
% low Wt: 55.
% high Wt: 60.
------------------------------
% low Wt: 25.
% high Wt: 30.
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE: INGEST: NOT KNOWN. EYE CONT: CAUSES IRRIT. SKIN
CONT: MAY CAUSE SLIGHT IRRIT. MAY BE ABSORED THROUGH SKIN. INHAL: VAP &
SPRAY MIST MAY BE HARMFUL IF INHALED. VAP GENERATED @ ELEVATED TEMPS IRRI
TATES EYES, NOSE & THROAT. SIGNS & SYMPS OF OVEREXP: REDNESS,
ITCHING, BURNING SENSATION & VISUAL DISTURB MAY INDICATE EXCESS EYE CONT.
DRYNESS, ITCHING, CRACKING, BURNING, REDNESS, & SWELL ARE CNDTNSASSOC
W/EXCESS SKIN CONT. CHRONIC: AVOID LONG TERM & RPTD CONT. PROD CNTNS
TITANIUM DIOXIDE. ANIMALS INHALING MASSIVE QTYS OF TITANIUM DIOXIDE DUST IN
LONG-TERM STUDY DEVELOPED LUNG TUMORS. STUDIES W /HUMANS INVOLVED (EFTS OF
OVEREXP)
Signs And Symptions Of Overexposure: EFTS OF OVEREXP: IN MFR OF PIGMENT
INDICATE NO INCR RISK OF CANCER FROM EXPOS. POTNTL FOR INHAL OF TITANIUM
DIOXIDE DUSTS FROM COATINGS IS VERY LIMITED. SINCE OVEREXP ARE NOT EXPECTED,
THERE IS NO SIG NIFICANT HAZ FOR MAN. PROD CNTNS DIETHYLENE GLYCOL MONOBUTYL
ETHER (DEGBE). DEGBE CONSUMED IN DRINKING WATER @ LOW LEVELS BY RATS FOR 30
DAYS CAUSED INJURY TO EITHER LIVER, KIDNEY, SPLEEN/TESTES. PROD CNTNS
ETHYLENE GLYCOL WHICH MAY CAUSE KIDNEY & LIVER DMG & WHICH HAS BEEN
SHOWN TO CAUSE BIRTH DEFECTS IN LAB ANIMALS. NO EVID OF THESE EFTS HAS BEEN
FOUND IN HUMANS.
First Aid: INGEST: IF SWALLOWED, GIVE 1-2 GLASSES OF WATER, BUT DO NOT INDUCE
VOMITING. EYE CONT: FLUSH IMMEDIATELY W/PLENTY OF WATER FOR AT LST 15
MINUTES. SKIN CONT: FLUSH IMMEDIATELY W/PLENTY OF WATER FOLLOWE D BY WASHING
WITH SOAP & WATER. INHAL: REMOVE TO FRESH AIR. APPLY ARTF RESP &
OTHER SUPPORTIVE, MEASURES AS REQD. OTHER IF INGEST, ANY TYPE OF
OVEREXP/SYMPS OF OVEREXP OCCUR DURING/FOLLOWING USE OF TH IS PROD, CONT
POISON CONTROL CENTER, EMERGENCY ROOM/PHYS IMMEDIATELY; HAVE MSDS INFORMATION
AVAILABLE.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: PROVIDE MAX VENT. ONLY PERSONNEL EQUIPPED W/PROPER
RESP & SKIN & EYE PROT SHOULD BE PERMITTED IN AREA. REMOVE ALL
SOURCES OF IGNIT. TAKE UP SPILLED MATERIAL W/SAWDUST, VERMICULITE, OR OTHER
ABSORBENT MATERIAL AND PLACE INTO CONTAINERS FOR DISPOSAL.
Waste Disposal Methods: WASTE MATERIAL MUST BE DISPOSED OF I/A/W FEDERAL,
STATE, PROVINCIAL, & LOCAL ENVIRONMENTAL CONTROL REGS. EMPTY CONTAINERS
SHOULD BE RECYCLED OR DISPOSED OF THROUGH AN APPROVED WASTE MANAGEMENT
FACILIT Y.
Handling And Storage Precautions: DO NOT STORE ABOVE 120F. STORE LARGE
QUANTITIES IN BUILDING DESIGNED & PROTECTED FOR STORAGE OF NFPA CLASS
IIIB COMBUSTIBLE LIQUIDS. PROTECT FROM FREEZING.
Other Precautions: IF THIS MATERIAL IS PART OF A MULTIPLE COMPONENT COATING
SYSTEM, READ THE MSDS(S) FOR THE OTHER COMPONENT OR COMPONENTS BEFORE
BLENDING AS THE RESULTING MIXTURE MAY HAVE THE HAZARDS OF ALL OF ITS PART S.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Extinguishing Media: USE NFPA CLASS B EXTINGUISHERS (CARBON DIOXIDE, DRY
CHEMICAL/UNIVERSAL AQUEOUS FILM FORMING FOAM) DESIGNED TO EXTINGUISH NFPA
CLASS IIIB COMBUSTIBLE LIQUID FIRES.
Fire Fighting Procedures: WATER SRPAY MAY BE INEFTIVE. WATER SPRAY MAY BE USED
TO COOL CLOSED CNTNRS TO PVNT PRESSURE BUILD-UP & POSSIBLE
AUTOIGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. IF WATER IS USED, FOG NOZZLES
ARE PREF. US E NIOSH APPRVD SCBA AND FULL PROTECTIVE EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE OR BURST (DUE TO
THE BUILD-UP OF STEAM PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
=======================================================
Control Measures
=======================================================
Respiratory Protection: OVEREXP TO VAPS MAY BE PREVENTED BY ENSURING VENT
CONTROLS. VAP EXHAUST/FRESH AIR ENTRY. NIOSH APPRVD (TC-23C) AIR
PURIFYING/AIR SUPPLIED (TC-19C) RESPS MAY ALSO REDUCE EXPOSURE. READ RESP
MANUFACTURE R'S INSTRUCTION & LITERATURE CAREFULLY TO DETERM TYPE OF
AIRBORNE CONTAMINANTS AGAINST WHICH RESP IS EFTIVE & HOW IT IS TO BE
PROPERLY FITTED.
Ventilation: PROVIDE GEN DILUTION/LOC EXHST VENT IN VOL & PATTERN TO KEEP
CONC OF INGRES LISTED IN INGRED SECTION BELOW LOWEST SUGGESTED EXPOS (SUPDAT)
Other Protective Equipment: EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). WEAR IMPERMEABLE CLTHG SUFFICIENT TO COVER EXPOSED SKIN
SURFS CONSTRUCTED OF: NITRILE, NEOPRENE, OR LATEX.
Work Hygienic Practices: CLEAN OR DISCARD CONTAMINATED CLOTHING AND SHOES.
Supplemental Safety and Health: VENT: LIMITS. LEL IN FIRE & EXPLOSION
HAZARD DATA SECTION BELOW STATED LIMIT, & TO REMOVE DECOMP PRODS DURING
WELDING/FLAME CUTTING ON SURFS COATED W/THIS PROD. APPEAR/ODOR: ANY SOLVENTS
LISTED IN SEC TION II.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: >100.C, 212.F
B.P. Text: 100-244C
Vapor Pres: <18
Vapor Density: HVR/AIR
Spec Gravity: 1.1-1.3
Appearance and Odor: VISCOUS LIQUID WITH AN ODOR CHARACTERISTIC OF THE CHEMICAL
FAMILY AND (SUPDAT)
Percent Volatiles by Volume: 65-74
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG
MINERAL ACIDS, OR STRONG OXIDIZING AGENTS.
Materials To Avoid: AVOID CONTACT WITH STRONG ALKALIES, STRONG MINERAL ACIDS,
OR STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: MAY PRODUCE HAZARDOUS DECOMPOSITION PRODUCTS
WHEN HEATED. WELDING, BRAZING, OR FLAME-CUTTING ON SURFACES COATED WITH THIS
PRODUCT MAY PRODUCE FUMES INCLUDING: CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
Transport Information: SHIPPING INFORMATION: US-DOT-SHIP.NAME/HAZ CLASS: NOT
REGULATED. UN NUMBER: N/A.
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: IN-PLANT HAZARD RATINGS: HEALTH = 2, FLAMMABILITY = 0,
REACTIVITY = 0. 0=MINMAL. 1=SLIGHT. 2=MODERATE. 3=SERIOUS. 4=SEVERE.
*=COATINGS INGREDIENT(S) WHICH MAY CAUSE (LONG-TERM) HEALTH EFFECTS.PHYSIC
AL DATA: WT//GAL (LBS): 9-11 (U.S.); % SOLID BY WEIGHT: 31-50.
=======================================================
HAZCOM Label
=======================================================
Product ID: SATINHIDE LATEX LO-LUSTRE ENAMEL, 88-29
Cage: 47695
Company Name: PPG INDUSTRIES INC
Street: ONE PPG PLACE
Zipcode: 15272
Label Required IND: Y
Date Of Label Review: 07/07/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INGEST: NOT KNOWN. EYE CONT: CAUSES IRRIT. SKIN
CONT: MAY CAUSE SLIGHT IRRIT. MAY BE ABSORED THROUGH SKIN. INHAL: VAP &
SPRAY MIST MAY BE HARMFUL IF INHALED. VAP GENERATED @ ELEVATED TEMPS IRRI
TATES EYES, NOSE & THROAT. SIGNS & SYMPSOF OVEREXP: REDNESS, ITCHING,
BURNING SENSATION & VISUAL DISTURB MAY INDICATE EXCESS EYE CONT. DRYNESS,
ITCHING, CRACKING, BURNING, REDNESS, & SWELL ARE CNDTNS ASSOC W/EXCESS
SKIN CONT. CHRONIC: PROD CNTNS TITANIUM DIOXIDE. ANIMALS INHALINGMASSIVE QTYS
OF TITANIUM DIOXIDE DUST IN LONG-TERM STUDY DEVELOPED LUNG TUMORS. POSSIBLE
LIVER, KIDNEY, SPLEEN & TESTES INJURY. POSSIBLE BIRTH DEFECTS.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TURBO OIL 274
CAGE:DO850
CAGE:29700
CAGE:DO850
============= Composition/Information on Ingredients =============
Ingred Name:POLYOLESTERS
===================== Hazards Identification =====================
Effects of Overexposure:PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE
MILD SKIN IRRITATION.
======================= First Aid Measures =======================
First Aid:SKIN: WASH THOROUGHLY WITH SOAP & WARM WATER. EYE: FLUSH WITH
CLEAR WATER 15 MIN. OR UNTIL IRRITATION SUBSIDES.
===================== Fire Fighting Measures =====================
Flash Point:455F C.O.C.
Lower Limits:1.0
Upper Limits:12.0
Extinguishing Media:FOAM,DRY CHEM.CO*2,WATER FOG OR SPRAY.
Fire Fighting Procedures:USE CBA FOR ENCLOSED AREA.COOL EXPOSED
CONTAINERS W/H*2O
Unusual Fire/Explosion Hazard:DO NOT MIX OR STORE WITH STRONG OXIDANTS
LIKE CHLORINE OR CONCENTRATED OXYGEN.
================== Accidental Release Measures ==================
Spill Release Procedures:RECOVER FREE LIQUID.ADD ABSORBENT TO SPILL
AREA. KEEP PETROLEUM PRODUCTS OUT OF SEWERS & WATERCOURSES BY
DIKING OR IMPOUNDING.ADVISE AUTHORITIES IF PRODUCT HAS ENTERED OR
MAY ENTER SEWERS,WATERCOURSES OR EXTENSIVE LAND AREAS.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN
USE. DO NOT HANDLE OR STORE NEAR HEAT,SPARKS,FLAME OR STRONG
OXIDANTS.
Other Precautions:AVOID BREATHING OIL MIST.REMOVE OIL-SOAKED CLOTHING &
LAUNDER BEFORE RE-USE DISCARD OIL-SOAKED SHOES.WASH SKIN WELL WITH
SOAP & WATER AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE AIR SUPPLIED RESPIRATORY PROTECTION IN
CONFINED SPACE
Ventilation:>60 FPM HOOD OR FACE VELOCITY FOR CONFINED SPACES
Other Protective Equipment:CHEM.RESISTANT APRON OR OTHER PROTECTIVE
CLOTHING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:410-465C
Vapor Density:>17.
Spec Gravity:0.953
Evaporation Rate & Reference:<0.01 BU ACETATE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:STRAW COLORED LIQUID. BLAND FATTY ODOR.455F C.O.C.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:STRONG OXIDANTS:LIQUID
CHLORINE,CONCENTRATED OXYGEN
Hazardous Decomposition Products:FUMES,SMOKE,CARBON MONOXIDE,SULFUR
OXIDES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF ABSORBED MATERIAL IAW ALL LOCAL,STATE
& FED.LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HERCULES (ALL-PURPOSE CLEANER/DEGREASER) (#CF/66)
CAGE:NO600
CAGE:0LDP3
CAGE:NO600
============= Composition/Information on Ingredients =============
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: TO 100%
Other REC Limits:NONE RECOMMENDED
Ingred Name:LIQUIFIED PETROLEUM GAS
CAS:68476-85-7
RTECS #:SE7545000
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM
Ingred Name:SODIUM NITRITE
CAS:7632-00-0
RTECS #:RA1225000
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:SODIUM LAURYL SULFATE
CAS:151-21-3
RTECS #:WT1050000
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:AMPHOTERIC SURFACTANT
CAS:68298-20-4
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT EST.
ACGIH TLV:NOT EST.
Ingred Name:CITRUS TERPENES
CAS:5989-27-5
RTECS #:GW6360000
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:MONOETHANOLAMINE
CAS:141-43-5
RTECS #:KJ5775000
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:3 PPM/STEL 6 PPM
ACGIH TLV:3 PPM
Ingred Name:COCONUT DIETHANOLAMIDE
CAS:8051-30-7
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:TETRASODIUM EDTA
CAS:64-02-8
RTECS #:AH5075000
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:GLYCOL ETHER (SARA III)
CAS:112-34-5
RTECS #:KJ9100000
Fraction by Wt: 3.255%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: DEFATTING TO SKIN ON REPEATED
CONTACT. EYES: IRRITANT. MAY CAUSE REDNESS/SWELLING OF THE
CONJUNCTIVA. INHALATION: NA. INGESTION: MAY IRRITATE
GASTROINTESTINAL SYSTEM. VOMITING & DIARRHEA EXPECTE D W/ LARGE
DOSES.
======================= First Aid Measures =======================
First Aid:SKIN: FLUSH W/ WATER. SEEK MEDICAL ATTN. IF IRRITATION
OCCURS. EYES: FLUSH W/ LARGE QUANTITIES WATER. SEEK MEDICAL ATTN.
IF IRRITATION PERSISTS. INHALATION: NA. INGESTION: DILUTE W/ 2
GLASSES WATER. S EEK MEDICAL ATTN. IF SYMPTOMS PERSIST.
===================== Fire Fighting Measures =====================
Flash Point:NR
Lower Limits:1.8
Upper Limits:8.4
Extinguishing Media:WATER, FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:NA
Unusual Fire/Explosion Hazard:HEATED CANS MAY BURST.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA IMMEDIATELY. MOP UP OR
OTHERWISE ABSORB & HOLD FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. DO NOT
STORE ABOVE 120F. STORE IN WELL-VENTILATED AREA.
INDUSTRIAL/INSTITUTIONAL USE ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO SPECIAL REQUIREMENTS.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT FOR MOST
CONDITIONS. LOCAL EXHAUST VENT. MAY BE NECESSARY SOME OPERATIONS.
Other Protective Equipment:NA
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NA
Vapor Pres:40PSIG@68F
Vapor Density:>1
Spec Gravity:NA
pH:10-11
Evaporation Rate & Reference:(WATER=1): <1
Solubility in Water:100%
Appearance and Odor:AEROSOL SPRAY WITH PLEASANT ODOR.
Percent Volatiles by Volume:95+
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NK
==================== Disposal Considerations ====================
Waste Disposal Methods:ANY METHOD IN ACCORDANCE W/ APPLICABLE LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SHER-LINER STRIPING PAINT, 160-0022, HANDICAP BLUE
CAGE:54636
CAGE:54636
============= Composition/Information on Ingredients =============
Ingred Name:PROPANE (PROPELLANT). VP:760.
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 10%
OSHA PEL:1000 PPM
ACGIH TLV:ASPHYXIANT
Ingred Name:BUTANE (PROPELLANT). VP:760.
CAS:106-97-8
RTECS #:EJ4200000
Fraction by Wt: 10%
OSHA PEL:800 PPM
ACGIH TLV:800 PPM
Ingred Name:V.M. & P. NAPHTHA. VP:12.
CAS:64742-89-8
Fraction by Wt: 3%
OSHA PEL:300 PPM;400 PPM(MFR)
ACGIH TLV:300 PPM (MFR)
Ingred Name:BENZENE, ETHYL-; (ETHYLBENZENE) (SARA 313). VP:7.1.
CAS:100-41-4
RTECS #:DA0700000
Fraction by Wt: 2%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM;125 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENE (SARA 313) (CERCLA). VP:5.9.
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 13%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM;150 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE (SARA 313) (CERCLA). VP:180.
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 17%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM;1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE).
OSHA PEL:15 MG/M3; 5 MG/M3 RDUST (MFR).
CAS:471-34-1
RTECS #:FF9335000
Fraction by Wt: 5%
OSHA PEL:SEE INGREDIENT
ACGIH TLV:10 MG/M3 (MFR)
Ingred Name:BARIUM SULFATE
CAS:7727-43-7
RTECS #:CR0600000
Fraction by Wt: 7%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 11%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:BARIUM COMPOUND (CONTAINING 4% BARIUM)
Fraction by Wt: 7%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT:WORKPLACE. RPTS HAVE ASSOC RPTD & PRLNG OVEREXP TO
SOLVS W/PERM BRAIN & NERV SYS DMG. INTENTIONAL MISUSE (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:BY DELIB CONC & INHAL CONTENTS CAN BE HARMFUL/FATAL.
WARNING:PROD CONTAINS CHEM(S) KNOWN TO THE STATE OF (ING 14)
RTECS #:9999999ZZ
Ingred Name:ING 13:CALIFORNIA TO CAUSE CANCER (CAL PROP 65).
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:PROCS. HEAT FROM SUNLIGHT, RADIATORS, STOVES,
HOT WATER & OTHER HEAT SOURCES COULD CAUSE CNTNR TO (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15:BURST. DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF
CHILDREN. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & (ING 17)
RTECS #:9999999ZZ
Ingred Name:ING 16:SPRAY MIST. AVOID CONT W/SKIN & EYES. THESE COATINGS
MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES (ING 18)
RTECS #:9999999ZZ
Ingred Name:ING 17:WHICH MAY BE PRESENT AT HAZ LEVELS ONLY DURING
SANDING/ABRADING OF DRIED FILM. IF NO SPECIFIC DUSTS ARE (ING 19)
RTECS #:9999999ZZ
Ingred Name:ING 18:LISTED, APPLIC LIMS FOR NUISANCE DUSTS ARE ACGIH TLV
10 MG/M3 (TDUST), OSHA PEL 15 MG/M3 (TDUST), 5 MG/M3(ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19:(RESPIRABLE FRACTION). ADDITION OF REDUCERS/OTHER
ADDITIVES TO THESE PRODS MAY SUBSTANTIALLY ALTER THE (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20:COMPOSITION & HAZARDS OF THE PRODUCTS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. TO MIN EXPOS, FOLLOW RECS FOR
PROPER USE, VENT & PPE. ACUTE:IRRIT OF EYES, SKIN & RESP SYS. MAY
CAUSE NERV SYS DEPRESS. EXTREME OV EREXP MAY RSLT IN UNCON & POSS
DEATH. HDCH, DIZZ, NAUS & LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:EXPOS TO VAPS/SPRAY MIST. REDNESS &
ITCH/BURNING SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS.
CHRONIC:PRLNG OVEREXP TO SOLV INGS MAY CAUSE ADVERSE EFTS TO LIVER,
URINARY, REPRO & CARDIO-V ASCULAR SYS. RATS EXPOS TO TITANIUM
DIOXIDE DUST AT 250 MG/M3 DEVEL LUNG CANCER, HOWEVER, SUCH EXPOS
LEVELS ARE (SUPDAT)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM &
QUIET. SKIN:WASH AFFECTED AREA THOROUGHLY W/SOAP & WATER. REMOVE
CONTAMINATED CLOTHING & LAUNDER BEFORE RE-USE. EYES:FLUSH W/LARGE
AMOUNTS OFWATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION.
INGEST:SEEK MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:<0F,<-18C
Lower Limits:0.7%
Upper Limits:12.8%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WASTE MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:EXTREMELY FLAMM. CLSD CNTNRS MAY EXPLODE
WHEN EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS REQS SPECIAL
PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP (SUPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DOL STOR CATEGORY-1A. CONTENTS ARE
EXTREMELY FLAMM. KEEP AWAY FROM HEAT, SPKS & OPEN FLAME. VAPS WILL
ACCUM READILY & MAY IGNITE EXPLOSIVELY.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA
VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS;
TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF
IGNIT. CONSULT NFPA CODE . USE APPRVD BONDING & GROUNDING(ING 15)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIC LIMS BY VENT, WEAR A PROPERLY FITTED NIOSH APPRVD ORG
VAP/PARTICULATE RESP FOR PROT AGAINST INGS. WHEN SANDING/ABRADING
DRIED FILM, WEAR NIOSH APPRV D DUST/MIST RESP FOR DUST WHICH
(SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS TO INGS IS
MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS (SUPP DATA)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLO WHEN EXPOS
TO EXTREME HEAT. EXPLO HAZ:PRODS MAY CAUSE HLTH HAZ. SYMPS MAY NOT
BE IMMED APPARENT. OBTAIN MED ATTN. RESP PROT:MAY BE GENERATED
FROM THIS PROD, UNDERLYING PAINT/ABRASIVE. VENT:1910.94, 1910.107,
1910.108. EFTS OF OVEREXP:NOT ATTAINABLE IN (ING 12)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:<325F,<163C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Volatile Org Content %:56
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>75
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGREDIENTS.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE FROM THESE PRODUCTS MAY BE HAZARDOUS AS
DEFINED UNDER THE RCRA (40 CFR 261). WASTE MUST BE TESTED FOR
IGNITABILITY TO DETERM APPLIC EPA HAZ WASTE NUMBER. DO NOT INCIN.
DEPRESSURIZE CNTNR. DISP O F I/A/W FED, STATE & LOC REGS
REGARDINGPOLLUTION.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: PSX-700FD CURE
Cage: 0Y2E4
Box: 1020
Resp. Party Other MSDS No.: NPCA 1-85
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 0Y2E4
Box: 1020
=======================================================
Item Description Information
=======================================================
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NOT SPECIFIED
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Effects of Exposure: TARGET ORGANS:LIVER, HEART, SKIN, EYES, STOMACH. SKIN:
IRRITANT. BURNS. SENSITIZATION OR ALLERGIC REACTION, SUCH AS RASH OR HIVES.
EYES: SEVERE IRRITANT. CORNEAL INJURY. INHALATION: IRRITANT. INGESTI ON: CAN
BE FATAL IF SWALLOWED.
Signs And Symptions Of Overexposure: HEADACHE, NAUSEA, DIZZINESS. SKIN:RASH,
HIVES. INHALATION: IRRITANT. ASPIRATION INTO LUNGS CAN DAMAGE LUNGS AND CAUSE
CHEMICAL PNEUMONIA. EYES: IRREVERSIBLE BURNS AND DAMAGE, METHANOL CAN CAUSE
BLINDN ESS. INGESTION: LIVER DAMAGE.
Medical Cond Aggravated By Exposure: KIDNEYS, LIVER, SKIN, EYES
First Aid: INHALATION:REMOVE TO FRESH AIR. RESTORE TO NORMAL BREATHING. TREAT
SYMPTOMATICALLY. SEE PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING. CONSULT PHYSICIAN. EYES: FLU SH IMMEDIATELY
WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES AND GET MEDICAL ATTENTION.
INGESTION: DRINK 1-2 GLASSES OF WATER TO DILUTE. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. DO NOT IN DUCE VOMITING (UNLESS METHANOL) CONTACT
PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY TREAT SYMPTOMATICALLY. AFTER
FLUSHING EYES FOR 15 MINUTES SEE PHYSICIAN/OPTHALMOLOGIST.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION. AVOID BREATHING
VAPORS. VENTILATE AREA. USE ABSORBENT, INERT, CLEANUP MATERIALS (DO NOT USE
SAWDUST). REMOVE ABSORBENT MATERIAL WITH NON-SPARKING TOOLS. PLACE IN SEPER
ATE CONTAINER. KEEP OUT OF SEWERS AND WATERWAYS. IF ENTRY IS THREATENED OR
OCCURS, NOTIFY LOCAL AUTHORITIES.
Neutralizing Agent: NONE SPECIFIED
Waste Disposal Methods: PLACE IN SEPERATE, CLOSED CONTAINER IN ACCORDANCE WITH
ALL APPLICABLE LOCAL, STATE,AND FEDERAL REGULATIONS. THIS MATERIAL HAS NOT
BEEN TESTED BY TOXICITY CHARACTERISTIC LEACHING PROCEDURES.
Handling And Storage Precautions: KEEP CONTAINER CLOSED, UPRIGHT WHEN NOT IN
USE. STORE IN COOL, DRY, WELL-VENTILATED AREA. AVOID PROLONGED STORAGE AT
TEMPERATURES ABOVE 100F.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: SCC
Flash Point: =82.2C, 180.F
Extinguishing Media: FOAM, CARBON DIOXIDE, DRY CHEMICAL
Fire Fighting Procedures: WEAR FULL PROTECTIVE EQUIPMENT, SELF-CONTAINED
BREATHING APPARATUS. WATER MAY BE USED TO COOL CLOSED CONTAINERS TO PREVENT
PRESSURE BUILD-UP OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT AND PRESSURE BUILDUP. KEEPAWAY FROM HEAT AND OPEN FLAME.
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR NIOSH/MSHA CERTIFIED RESPIRATOR DESIGNED TO REMOVE
DUST/SPRAY MIST/VAPOR PARTICULATES. REFER TO "NIOSH POCKET GUIDE TO CHEMICAL
HAZARDS" FOR SPECIFIC CONDITIONS. IN CONFINED/RESTRICTED AREAS USE AIR-LINE
VENTUILATION RESPIRATORS OR HOODS. REFER TO 29 CFR1919.134 AND 1915; PART
1910.146; ANSI Z88.2
Ventilation: SUFFICIENT VENTILATION IN VOLUME AND PATTERN TO KEEP AIR
CONTAMINANT CONCENTRATIONS BELOW TLV LIMITS.
Other Protective Equipment: RESISTENT COVERALLS AND SHOE COVERINGS.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING,
SMOKING OR USING TOILET. LAUNDER CONTAMINATED CLOTHING BEFORE USE.
Supplemental Safety and Health: PRODUCT IS USED AS PART OF A KIT WITH PSX-700
RESIN (8010-00-D00-7872).
=======================================================
Physical/Chemical Properties
=======================================================
HCC: V4
Vapor Density: >AIR
VOC Grams/Liter: 120
Evaporation Rate & Reference: NOT PROVIDED
Appearance and Odor: LIQUID; ODOR N/A
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT, OPEN FLAMES, ARC OR SPARKS. WATER OR
MOISTURE. HIGH TEMPERATURES.
Materials To Avoid: STRONG OXIDIZERS, ACIDS, ALKALIES. WATER.
Hazardous Decomposition Products: CO, CO2, NOX, SILICON OXIDE FUMES, TOXIC
GASES AND FUMES. FORMELDEHYDE AT TEMPERATURE ABOVE 300 F(150C). TIN COMPOUND
FUMES.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
Toxicological Information: PER MSDS PROPRIETARY INGREDIENT 1 (<10%): PEL/TLV
LIMITS BASED ON TRACE AMOUNTS OF TIN AND 2,4-PENTANEDIONE, PROPRIETARY
INGREDIENT 2 (<70%): TRACE CONTAMINANT TOLUENE @< 10PPM, ETHANOL 0.5%,
PROPRIET ARY INGREDIENT 3 (<30%): LIMITS BASED ON METHANOL @ 2%, TRACE
AMOUNT TOLUENE @ 50 PPM
=======================================================
Ecological Information
=======================================================
Ecological: CONTAINS CHEMICALS REQUIRED TO BE REPORTED UNDER SARA
=======================================================
=======================================================
Transport Information: PER MSDS REGULATED BY DOT AS COMBUSTIBLE
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: PER MSDS CONTAINS CHEMICAL REQUIRED TO BE REPORTED
UNDER SARA
Federal Regulatory Information: ALL INGREDIENTS ARE ON TSCA INVENTORY OR ARE
EXEMPT.
State Regulatory Information: PER MSDS CONTAINS CHEMICAL KNOWN TO STATE OF
CALIFORNIA TO CAUSE BIRTH DEFECTS OR OTHER REPORDUCTIVE HARM (PROP 65).
=======================================================
Other Information
=======================================================
Other Information: NOT PROVIDED
=======================================================
Transportation Information
=======================================================
Trans ID NO: 150461
Product ID: PSX-700FD CURE
Review Date: 12/02/1999
Multiple KIT Number: 0
Additional Data: ITEM CLASSED AS NOT REGULATED BY DOT BASED ON THE ASSUMPTION
THAT THE CONTAINER SIZE IS LESS THAN 11 0 GAL (I.E. IS A NON-BULK CONTAINER)
AND IS THEREFORE NOT SUBJECT TO DOT REGULATIONS.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: PSX-700FD CURE
Cage: 0Y2E4
Company Name: AMERON PROTECTIVE COATINGS
Street: 201 NORTH BERRY STREET
PO Box: 1020
Zipcode: 92622-1020
Label Required IND: Y
Date Of Label Review: 12/02/1999
Status Code: A
Origination Code: F
Signal Word: WARNING
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Moderate
Reactivity Hazard: Slight
Hazard And Precautions: TARGET ORGANS:LIVER, HEART, SKIN, EYES, STOMACH. SKIN:
IRRITANT. BURNS. SENSITIZATION OR ALLERGIC REACTION, SUCH AS RASH OR HIVES.
EYES: SEVERE IRRITANT. CORNEAL INJURY. INHALATION: IRRITANT. INGESTI ON: CAN
BE FATAL IF SWALLOWED.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:COPPER ALLOYS, SHEET
CAGE:0B5P5
CAGE:0B5P5
============= Composition/Information on Ingredients =============
Ingred Name:COPPER (SARA III)
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 100%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO FUMES/DUST MAY
PRODUCE IRRITATION OF EYES & RESPIRATORY SYSTEM. INHALATION OF HIGH
CONCENTRATIONS OF FRESHLY FORMED OXIDE FUMES OF COPPER MAY CAUSE
METAL FUME FEVER CHARACTERIZE D BY A METALLIC TASTE IN MOUTH &
IRRITATION OF THROAT & INFLUENZA-LIKE SYMPTOMS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:CHRONIC DISEASES OR DISORDERS OF
THE RESPIRATORY SYSTEM.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE
OXYGEN/ARTIFICIAL RESPIRATION) . SKIN:FLUSH W/COPIOUS AMOUNTS OF
WATER. CALL MD . EYES:IMMEDIATELY FLUSH W/POTABLE WATER FOR A
MINIMUM OF15 MINS. SEEK ASSISTANCE FROM MD . INGEST:CALL MD
IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:PROD IN SOLID STATE PRESENT NO
FIRE/EXPLOS HAZ. DUST HAZ EXISTS UNDER FAVORING CNDTNS OF SMALL
PRACTICE SIZE. DISPERSION IN AIR & STRONG IGNIT SOURCE (SUP DAT)
================== Accidental Release Measures ==================
Spill Release Procedures:PRODUCT IS A SOLID ALLOY AND SPILL IS UNLIKELY
.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED DUST & FUME RESPIRATOR
SHOULD BE USED TO AVOID EXCESSIVE INHALATION OF PARTICULATES WHEN
EXPOSURE EXCEEDS TLV'S.
Ventilation:ADEQ VENT SHOULD BE UTILIZED WHEN WELDING, BURNING, SAWING,
BRAZING, GRINDING OR MACHINING WHEN EXPOS EXCEEDS TLV'S.
Other Protective Equipment:OTHER PROTECTIVE EQUIPMENT SHOULD BE
UTILIZED AS REQUIRED BY THE WELDING STANDARDS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ:MAY RESULT IN AN EXPLOSION. HAZ DECOMP PROD:CONTACTING
MATERIALS ARE INVOLVED.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:1924F,1051C
Spec Gravity:8.94 (H*2O=1)
Appearance and Odor:REDDISH-BROWN METAL; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPAT W/MERCURY, AMMONIA, ACETYLENE, ACIDS. AVOID EXPOS DURING STOR
TO STRONG ACIDS, BASES OR OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOX GASES, AEROSOLS & VAPS MAY BE
RELSD IN FIRE INVOLVING COPPER ALLOY IF FUMES OF OTHER CMPDS OR
OTHER (SUPP DATA)
==================== Disposal Considerations ====================
Waste Disposal Methods:USED OR UNUSED PRODUCT SHOULD BE TESTED TO
DETERMINE HAZARD STATUS & DISPOSAL REQUIREMENTS UNDER FEDERAL,
STATE OR LOCAL LAWS & REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
NIIN: 00-576-9634
Product ID: BLAST-O-LITE
Cage: 23842
Box: 4366
=======================================================
Contractor Summary
=======================================================
Cage: 23842
Box: 4366
=======================================================
Item Description Information
=======================================================
Item Manager: GSA
Item Name: GRAIN,ABRASIVE
Specification Number: MIL-G-9954
Unit of Issue: CO
Quantitative Expression: 00000000050LB
UI Container Qty: 1
=======================================================
Ingredients
=======================================================
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHAL: IRRITATION OF RESPIRATORY TRACT. EYE: IRRITATION.
First Aid: EYE: FLUSH W/COPIOUS AMOUNTS OF WATER. INHAL: MOVE TO FRESH AIR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AVOID EXCESS DUSTING. SWEEP/VACUUM SPILLED MATERIAL.
Waste Disposal Methods: MAY BE DISPOSED OF IN APPROVED LANDFILL IN ACCORDANCE
W/FEDERAL/STATE/LOCAL REGULATIONS. PRECAUTIONS SHOULD BE TAKEN IN
HANDLING/STORAGE, AVOID EXCESSIVE DUSTING.
Handling And Storage Precautions: PRECAUTIONS: AVOID EXCESSIVE DUSTING.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NA
Lower Limits: NA
Upper Limits: NA
Extinguishing Media: NA
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH/MSHA APPROVED DUST MASK IF LIMITS EXCEEDED.
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: NA
Vapor Pres: NA
Vapor Density: NA
Spec Gravity: 2.5
Evaporation Rate & Reference: NA
Solubility in Water: INSOLUBLE
Appearance and Odor: WHITE POWDER, ODORLESS
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Materials To Avoid: HYDROFLUORIC, FLUOSILICIC, PHOSPHORIC ACIDS & HOT STRONG
ALKALINE SOLUTIONS
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 77255
Product ID: BLAST-O-LITE
Review Date: 04/17/1997
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CO
Container QTY: 1
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: BLAST-O-LITE
Cage: 23842
Company Name: LUKENS GENERAL INDUSTRIES INC FLEX-O-LITE DIVISION
Street: 8301 FLEX-O-LITE DRIVE
PO Box: 4366
Zipcode: 63123-0166
Label Required IND: Y
Date Of Label Review: 10/12/1999
Status Code: A
Origination Code: G
Hazard And Precautions: INHAL: IRRITATION OF RESPIRATORY TRACT. EYE:
IRRITATION.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MULTI PURPOSE DRY-SET MORTAR
CAGE:93715
CAGE:93715
============= Composition/Information on Ingredients =============
Ingred Name:SILICATE, PORTLAND CEMENT; (PORTLAND CEMENT)
CAS:65997-15-1
RTECS #:VV8770000
Fraction by Wt: 40-50%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
CAS:14808-60-7
RTECS #:VV7330000
Fraction by Wt: 50-60%
OSHA PEL:SEE TABLE Z3
ACGIH TLV:0.1 MG/M3 RDUST;9293
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:PROLONGED OR REPEATED OVEREXPOSURE TO
DUST MAY CAUSE SKIN, EYE, NOSE AND THROAT IRRITATION.
Explanation of Carcinogenicity:SILICA CRYSTALLINE (QUARTZ): GROUP 2A
(IARC), ANTICIPATED TO BE CARCINOGEN (NTP).
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:EXISTING SKIN CONDITIONS.
======================= First Aid Measures =======================
First Aid:CALL PHYSICIAN IMMEDIATELY. EYE: FLUSH EYES WITH PLENTY OF
WATER FOR AT LEAST 15 MINUTES. INGESTION: CALL MD IMMEDIATELY .
SKIN: WASH THOROUGHLY WITH SOAP AND WATER OR HAND CLEANER. WASH
CLOTHIN G BEFORE REUSE. INHALATION: REMOVE FROMEXPOSURE. SUPPORT
BREATHING (GIVE ARTIFICIAL RESPIRATION/OXYGEN) .
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE CONDITIONS
.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID RAISING EXCESSIVE DUST. WHEN SWEEPING
UP, USE WATER MIST OR VACUUM.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN DRY PLACE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. USE ONLY AS DIRECTED
ON LABEL. CLOSE CONTAINER AFTER EACH USE. DO NOT RE-USE CONTAINER.
AVOID SKIN AND EYE CONTACT. HANDLE AND MIX POWDER CAREFULLY TO
AVOID CREATING DUS T. STIR CAREFULLY TO AVOID SPLASHES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE WITH POSITIVE FRESH AIR CROSS VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH SKIN WITH SOAP AND WATER OR HAND CLEANER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Vapor Pres:NIL
Spec Gravity:2.85-2.95
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:NONE KNOWN.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS. DO NOT FLUSH MATERIAL DOWN DRAIN.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RHODAMINE B, 97% (UV-VIS), R21-100
Resp. Party Other MSDS Num.:20113
CAGE:1B464
CAGE:22527
CAGE:1B464
============= Composition/Information on Ingredients =============
Ingred Name:C.I. FOOD RED 15
CAS:81-88-9
RTECS #:BP3675000
> Wt:90.
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFO
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: MAY CAUSE EYE IRRITATION AND
POSSIBLE BURNS. SKIN: CAUSES SKIN IRRITATION. INGESTION: MAY CAUSE
GASTROINTESTINAL IRRITATION WITH NAUSEA, VOMITING AND DIARRHEA.
INHALATION: DUST IS IRRITATING TO T HE RESPIRATORY TRACT. CHRONIC:
NO INFORMATION FOUND.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH EYES W/PLENTY OF WATER FOR AT LEAST 15 MIN,
OCCASIONALLY LIFTING UPPER & LOWER LIDS. IF IRRIT DEVELOPS, GET MED
AID. SKIN: GET MED AID IF IRRIT DEVELOPS OR PERSISTS. FLUSH SKIN
W/PLENTY OF SOAP & WATER. INGEST: IF VICTIM IS CONSCIOUS & ALERT,
GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCON PERSON. GET MED AID. INDUCE VOMITING BY GIVING ONE
TEASPOON OF SYRUP OF IPECAC. INHAL: REMOVE FROM EXPOSURE TO FRESH
AIR IMMED. IF NOT BREATHING GIVE ARTIFICIAL RESPIRATION. IF
BREATHING IS DIFFICULT, GIVE OXYGEN. GET MED AID IF COUGH OR OTHER
SYMPTOMS APPEAR. NOTES TO MD: TREAT SYMPTOMATICALLY.
===================== Fire Fighting Measures =====================
Flash Point:NOT AVAILABLE
Lower Limits:NOT AVAIL
Upper Limits:NOT AVAIL
Extinguishing Media:IN CASE OF FIRE, USE WATER, DRY CHEMICAL, CHEMICAL
FOAM, OR ALCOHOL-RESISTANT FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . NFPA RATING: NOT PUBLISHED.
Unusual Fire/Explosion Hazard:DUSTS AT SUFFICIENT CONCENTRATIONS CAN
FORM EXPLOSIVE MIXTURES WITH AIR. DURING A FIRE, IRRITATING AND
HIGHLY TOXIC GASES MAY BE GENERATED BY THERMAL DECOMPOSITION OR
COMBUSTION.
================== Accidental Release Measures ==================
Spill Release Procedures:GENERAL INFORMATION: USE PROPER PERSONAL
PROTECTIVE EQUIPMENT AS INDICATED IN SECTION 8 - EXPOSURE CONTROLS,
PERSONAL PROTECTION. SPILLS/LEAKS: SWEEP UP, THEN PLACE INTO A
SUITABLE CONTAINER FOR DISPO SAL.
======================Handling and Storage ======================
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE REUSE. USE WITH ADEQUATE
VENTILATION. AVOID CONTACT WITH SKIN AND EYES. AVOID INGESTION AND
INHALATION. STORE IN A COOL, DR Y PLACE. STORE IN A TIGHTLY CLOSED
CONTAINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR
EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
FACESHIELD .
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT
SKIN EXPOSURE.
Supplemental Safety and Health
EXPOSURE LIMITS: C.I. FOOD RED 15 - ACGIH, NIOSH, OSHA-FINAL PELS: NONE
LISTED; NO OSHA VACATED PELS ARE LISTED FOR THIS CHEMICAL. PHYSICAL
DATA: MOLECULAR FORMULA: C28H31CLN2O3.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:=215.C, 419.F
Decomp Temp:Decomp Text:NOT AVAILABLE
Vapor Pres:NEGLIGIBLE
Spec Gravity:1.3100
pH:NOT AVAILABLE
Viscosity:NOT AVAILABLE
Solubility in Water:NOT AVAILABLE
Appearance and Odor:APPEARANCE: NOT AVAILABLE; ODOR: NONE REPORTED;
PHYSICAL STATE: SOLID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS.
Stability Condition to Avoid:AVOID INCOMPATIBLE MATERIALS. STABLE UNDER
NORMAL TEMPERATURES AND PRESSURES.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, NITROGEN OXIDES,
CARBON MONOXIDE, CARBON DIOXIDE, NITROGEN.
=================== Toxicological Information===================
Toxicological Information:CAS #80-88-9; RTECS #BP367500 - LD50/LC50:
ORAL, MOUSE: LD50 = 887 MG/KG. CARCINOGENICITY: CALIFORNIA:
CARCIN-INITIAL DATE 7/1/90. IARC: GROUP 3 CARCINOGEN. EPIDEMIOLOGY:
PER IARC, THERE IS NO ADEQUAT E HUMAN DATA FOR CARCINOGENICITY OF
RHODAMINE. THERE IS LIMITED ANIMAL EVIDENCE FOR ITS
CARCINOGENICITY. ACCORDING TO RTECS, RHODAMINE IS AN EQUI VOCAL
TUMORGENIC AGENT CAUSING TUMORS AT SITE OF APPLI CATION IN RATS.
TLDO VALUE IS 3600 MG/KG/68 WKS. TOXIC DOSE OTHER THAN THE LOWEST
IS REPORTED TO BE 3870 MG/KG/68 WEEKS. TERATOGENICITY: NO DATA
AVAILABLE. REPRODUCTIVE EFFECTS: RHODAMINE HAS CAUSED ( OTHER INFO)
===================== Ecological Information =====================
Ecological:ECOTOXICITY: NOT AVAIL. ENVIRONMENTAL FATE: NOT AVAIL.
PHYSICAL/CHEM: NOT AVAIL. OTHER: NOT AVAIL. FEDERAL REG INFO:
POLLUTANTS UNDER CWA. NONE OF CHEMS IN THIS PROD ARE CONSIDERED
HIGHLY HAZ BY OSHA. EUROPEAN/INTERNATIONAL REGS - EUROPEAN LABELIN
I/A/W EC DIRECTIVES: HAZ SYMBOLS: XN. RISK PHRASES: R 20/22 HARMFUL
BY INHAL & IF SWALLOWED. R 40 POSS RISKS OF IRREVERSIBLE EFTS.
SAFETY PHRASES: S 24/ 25 AVOID CONTACT W/SKIN & EYES. WGK (WATER
DANGER/PROT) CAS #81-88-9:2. CANADA: CAS #81-88-9 IS LISTED ON
CANADA'S DSL/NDSL LIST. THIS PROD HAS WHMIS CLASSIFICATION OF D2B.
CAS #81-88-9 IS NOT LISTEDON CANADA'S INGRED DISCLOSURE LIST.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTEN WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIST ED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: NONE LISTED.
=================== MSDS Transport Information ===================
Transport Information:SHIPPING NAME - US DOT: NO INFORMATION AVAILABLE.
IATA: NOT REGULATED AS A HAZARDOUS MATERIAL. RID/ADR: NOT REGULATED
AS A HAZARDOUS MATERIAL. IMO: NOT REGULATED AS A HAZARDOUS
MATERIAL. CANADA TDG: N O INFORMATION AVAILABLE.
===================== Regulatory Information =====================
SARA Title III Information:SECTION 302 (RQ): NONE OF CHEMICALS IN THIS
MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS IN
THIS PRODUCT HAVE A TPQ. SARA CODES: CAS #81-88-9: ACUTE, CHRONIC.
SECTION 313: THIS CHEMIC AL IS NOT AT A HIGH ENOUGH CONCENTRATION
TO BE REPORTABLE UNDER SECTION 313. NO CHEMICALS ARE REPORTABLE
UNDER SECTION 313.
Federal Regulatory Information:CAS #81-88-9 IS LISTED ON TSCA
INVENTORY. NONE OF THE CHEMS ARE ON THE HEALTH & SAFETY REPORTING
LIST. NONE OF CHEMS IN THIS PROD ARE UNDER CHEMICAL TEST RULE. NONE
OF THE CHEMS ARE LISTED UNDER TSCASECTION 12B. NONE OF CHEMS IN
THIS MATL HAVE SNUR UNDER TSCA. CLEAN AIR ACT: THIS MATL DOES NOT
CNTN ANY HAZ AIR POLLUTANTS. THIS MATL DOES NOT CNTN ANY CLASS 1
OZONE DEPLETORS. THIS MATL DOES NOT CNT N ANY CLASS 2 OZONE
DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED AS HAZ
SUBSTANCES U NDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS PRIORITY
POLLUTANTS UNDER CWA. NONE OF CHEMS IN PROD ARE LISTED AS TOXIC
(ECOLOGICAL INFO)
State Regulatory Information:CAS #81-88-9 CAN BE FOUND ON THE FOLLOWING
STATE RIGHT TO KNOW LISTS: CALIFORNIA, NEW JERSEY, PENNSYLVANIA,
MASSACHUSETTS. THE FOLLOWING STATEMENT(S) IS (ARE) MADE IN ORDER TO
COMPLY WITH THE CALIFORN IA SAFE DRINKING WATER ACT: WARNING: THIS
PRODUCT CONTAINS C.I. FOOD RED 15, A CHEMICAL KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER. CALIFORNIA NO SIGNIFICANT RISK LEVEL:
NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:W F LATEX SATIN FINISH ENAMEL, 367
CAGE:09585
CAGE:09585
CAGE:91950
============= Composition/Information on Ingredients =============
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 19.2%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:CLAY (KAOLIN); (HYDROUS ALUM SILICATES)
CAS:1332-58-7
RTECS #:GF1670500
Fraction by Wt: 5.2%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:IRRITATION OF THE
RESPIRATORY TRACT. SKIN & EYE CONTACT:PRIMARY IRRITATION. INGESTION
OF LARGE AMOUNTS COULD CAUSE SERIOUS INJURY. CHRONIC:NONE LISTED BY
MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE EXPECTED WHEN USED IN
ACCORDANCE WITH SAFE HANDLING AND USE INFORMATION.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. GET MED HELP FOR ANY BRTHG DFCLTY.
EYE:FLUSH THORO W/WATER FOR @ LEAST 15 MINS. CALL PHYS. SKIN:WASH
WITH SOAP AND WATER. INGEST:DRINK 1-2 GLASSES OF WATER TO DILUTE.
DO NOT INDUCE VOMITING. CALL PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>250F,>121C
Extinguishing Media:FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . COOL EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY BURST IF EXPOSED TO
EXTREME HEAT OR FIRE. TOXIC GASES MAY FORM WHEN PRODUCT BURNS.
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH WITH WATER. ABSORB WITH SAWDUST OR RAGS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT THROW OR DROP CONTAINERS. AVOID
CONT W/EYES & PRLNGD CONT W/SKIN OR BRTHG OF SPRAY MIST OR SANDING
DUST. CLOSE CONTAINER AFTER EACH USE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DO NOT TAKE
INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR SPECIFIED FOR
PROTECTION AGAINST PAINT SPRAY MIST AND SANDING DUST IN RESTRICTED
OR CONFINED AREAS.
Ventilation:ADEQ TO MAINTAIN WORKING ATM BELOW TLV & LEL. MECH EXHAUST
MAY BE REQD IN CONFINED AREAS.
Other Protective Equipment:CLTHG ADEQ TO PROTECT SKIN. ANSI APPRVD
EMERGENCY EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:REMOVE AND WASH CLOTHING BEFORE REUSE. WASH
HANDS BEFORE EATING, SMOKING OR USING THE WASHROOM.
Supplemental Safety and Health
% VOLAT:66.1-69.2.
================== Physical/Chemical Properties ==================
Vapor Density:HVR/AIR
Spec Gravity:1.10-1.22
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT KNOWN
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:SUPDAT
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORESEEABLE.
Stability Condition to Avoid:ELEVATED TEMPERATURES.
Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON DIOXIDE AND
CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONVENTIONAL PROCEDURES IN COMPLIANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GTD-SP, 9074
CAGE:BIOLO
CAGE:BIOLO
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM MONOHYDROGEN PHOSPHATE; (DISODIUM PHOSPHATE) (SARA
III)
CAS:7558-79-4
RTECS #:WC4500000
Fraction by Wt: 10-15%
ACGIH TLV:10 MG/M3 (MFR)
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SODIUM DIHYDROGEN PHOSPHATE; (MONOSODIUM PHOSPHATE)
CAS:7558-80-7
RTECS #:WA1900000
Fraction by Wt: 3-5%
ACGIH TLV:10 MG/M3 (MFR)
Ingred Name:SODIUM BICARBONATE
CAS:144-55-8
RTECS #:VZ0950000
Fraction by Wt: 15-20%
Ingred Name:TRITON X-120 (CONSISTING OF INGREDIENTS 5 & 6)
Fraction by Wt: 15-20%
Ingred Name:MAGNESIUM CARBONATE
CAS:546-93-0
RTECS #:OM2470000
OSHA PEL:15MG/M3 TDUST;5 RESP
ACGIH TLV:10MG/M3 TDUST
Ingred Name:OCTYL PHENOL CONDENSED WITH 8-10 MOLES ETHYLENE OXIDE;
(TX100)
CAS:9036-19-5
RTECS #:RI0525000
Ingred Name:VIABLE BACTERIAL CULTURES
Fraction by Wt: 50%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGEST:NO EFT IF INGESTED IN SMALL
AMTS.RELATIVE TO OTHER MATL,A SINGLE DOSE OF PROD IS RARELY TOX BY
INGEST.IRRIT OF MOUTH,PHARYNX,ESOPHAGUS & STOM CAN DEVELOP
FOLLOWING INGEST.EYE:MATL MAY CAUSE IRR IT.BIOHAZARD.ORGANISMS USED
ARE NONPATHOGENIC BUT CAN CAUSE INFECTION WHEN IN CONT W/OPEN
WOUNDS. THESE (EFTS OF OVEREXP
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:ORGANISMS ARE SUSCEPTIBLE TO MANY
COMMONLY-USED ANTIBIOTICS. SKIN:SLIGHT REDNESS ON HANDS & FOREARMS,
IF INDIV HAS A HISTORY OF DERMAL ALLERGIC REACTION, DERMATITIS &
SKIN SENSITIZATION CAN D EVELOP AFTER RPTD &/OR PRLNGD CONT W/HUMAN
SKIN. INHAL:PROD MAY PRDCE NUISANCE DUST, WHICH IRRIATE RESP
PASSAGES.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:REMOVE CONTAMINATED CLOTHING & FOOTWEAR. WASH MATERIAL
OFF THE SKIN W/PLENTY OF SOAP & WATER. WASH CLOTHING & FOOTWEAR
BEFORE REUSE. EYES:IMMEDIATELY FLUSH W/PLENTY OF WATER FOR AT LEAST
15 MINS & HAVE EYES EXAMINED & TREATED BY MEDICAL PERSONNEL.
INHAL:REMOVE VICTIM TO FRESH AIR. INGEST:CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR NIOSH/MSHA APPROVED RESPIRATOR FOR
NUISANCE DUST DURING CLEANUP. FOR SMALL SPILLS, FLUSH TO WASTE
TREATMENT SEWER (PRODUCT IS BIODEGRADABLE). FOR LARGE SPILLS,
CONTAIN & COLLECT FOR REUSE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:TO MAINTAIN SHELF LIFE, AVOID PRLNGD
EXPOS TO HIGH TEMPS & HUMIDITY. USE NIOSH/MSHA APPRVD RESP. AVOID
HNDLNG, WHICH WOULD CREATE LGE AMTS OF DUST.
Other Precautions:AVOID CREATING DUST. PREVENT SKIN & EYE CONTACT. NO
TLV ASSIGNED TO THIS MIXTURE. CONTROL OF EXPOSURE TO BELOW THE TLV
FOR THE INGREDS WILL BE SUFFICIENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF NEEDED, USE NIOSH/MSHA APPROVED RESPIRATOR
FOR NUISANCE DUST.
Ventilation:GENERAL MECHANICAL VENTILATION.
Other Protective Equipment:LONG SLEEVE CLOTHING & EYEWASH STATION IN
WORK AREA.
Work Hygienic Practices:MINIMIZE EXPOSURE IN ACCORDANCE W/GOOD HYGIENE
PRACTICE.
Supplemental Safety and Health
PH:7.2-7.4. SOL IN H*2O:MODERATE-CONTAINS VIABLE BACTERIA
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:0.66-0.77
pH:SUPDAT
Solubility in Water:(SUPP DATA)
Appearance and Odor:FREE FLOWING, CHALKY COLORED POWDER; YEAST-LIKE
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALI COMPOUNDS MAY INACTIVATE BIOLOGICAL CULTURES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL OF THIS PRODUCT OR ITS RESIDUES MUST BE
IN ACCORDANCE W/ALL LOCAL, STATE & FEDERAL REQUIREMENTS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BALLAST
Preparer's Name:RAJAN CHAUDRY
CAGE:98775
CAGE:98775
============= Composition/Information on Ingredients =============
Ingred Name:MANUFACTURER LISTS NOTHING UNDER "INGREDIENTS" IMPLYING
THAT THERE ARE NO HAZARDOUS INGREDIENTS PER HAZ COM STANDARD.
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:NONE SPECIFIED BY MANUFACTURER.
===================== Fire Fighting Measures =====================
Extinguishing Media:NONE SPECIFIED BY MANUFACTURER.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SPECIFIED BY MANUFACTURER.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
PER MR. RAJAN CHAUDRY OF ADVANCE TRANSFORMER CO., IN A LETTER DATED 24
JULY 1995, THE ITEM DOES NOT REQUIRE AN MSDS UNDER 1910.1200 BECAUE
IT IS AN ARTICLE.
================== Physical/Chemical Properties ==================
HCC:N1
Appearance and Odor:NSN CANCELLED 95060.REPLACEMENT
NSN=625001341-3465.BALLAST FOR FLUORESCENT LAMP
================= Stability and Reactivity Data =================
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:NONE SPECIFIED BY MANUFACTURER.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:EXT MAGNESIUM SPEC GRADE AZ61A
CAGE:96717
CAGE:96717
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM
CAS:7439-95-4
RTECS #:OM2100000
Fraction by Wt: >92%.
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 6.5%
OSHA PEL:15MG/M3 DUST/5 FUME
ACGIH TLV:10MG/M3 DUST; 9192
Ingred Name:ZINC (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 1.0%
OSHA PEL:10 MG ZNO/M3
ACGIH TLV:10 MG ZNO/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:MANGANESE (SARA III)
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: 0.15%
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
===================== Hazards Identification =====================
Effects of Overexposure:N/A,EYE/SKIN: MECHANICAL INJURY AS FROM ANY
FOREIGN BODY.
======================= First Aid Measures =======================
First Aid:EYES: MECHANICAL INJURY ONLY. SKIN/INHAL/INGEST: NO SPECIAL
FIRST AID NEEDED.
===================== Fire Fighting Measures =====================
Extinguishing Media:MELTING FLUX,DRY SAND,METAL EXTINGUISHG PWDRS(GI,
MET-L-X )
Fire Fighting Procedures:HEATED IN AIR TO TEMP.NEAR MLT.PT,MATERIAL
IGNITIES & PRD.HZ
Unusual Fire/Explosion Hazard:USE OF WATER ON MOLTEN MAGNESIUM WILL
PRODUCE HYDROGEN GAS & MAY CAUSE AN EXPLOSION
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN OFF AND USE.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE W/CARE TO AVOID PRODUCT
DAMAGE/AND OR PERSONAL INJURY. STORE PRODUCT IN DRY LOCATION.;
WET,MOIST OR HIGH HUMIDITY STORAGE WILL LEAD TO PRD.CORR
Other Precautions:STORE AWAY FROM COMBUSTIBLES. SEE NAT. FIRE PROTECT.
ASSOC. (NFPA-48)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NEEDED
HT.TRT. OPERATI
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:940 F(MLT.P
Spec Gravity:1.8
Appearance and Odor:SILVER SOLID, NO ODOR.
Percent Volatiles by Volume:0.
================= Stability and Reactivity Data =================
ACID/WATER: REACTS W/ACID TO FORM HYDROGEN GAS.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:03GY049CAT, CAT MIL-C-83286 16473
Kit Part:Y
CAGE:33458
CAGE:33458
CAGE:33461
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOL, 2-ETHOXY-, ACETATE; (2-ETHOXYETHYL ACETATE). VP:
2.
CAS:111-15-9
RTECS #:KK8225000
Fraction by Wt: 10%
OSHA PEL:100 PPM, S
ACGIH TLV:5 PPM, S
Ingred Name:ISOCYANIC ACID, HEXAMETHYLENE ESTER, POLYMERS; (ALIPHATIC
ISOCYANATE)
CAS:28182-81-2
RTECS #:NQ9170000
Fraction by Wt: 30%
Ingred Name:HEXANE, 1,6-DIISOCYANATO-; (HEXAMETHYLENE DIISOCYANATE).
FREE MONOMER CONTENT <0.7% BASED ON RESIN SOLIDS AT THE (ING 4)
CAS:822-06-0
RTECS #:MO1740000
Fraction by Wt: SEE ING
Other REC Limits:0.02PPM, C (MOBAY)
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ING 3: TIME OF MANUFACTURE. HOWEVER, AFTER 3-6 MONTHS
STORAGE, THE FREE MONOMER CONTENT MAY RISE TO A MAXIMUM OF 1.6%.
RTECS #:9999999ZZ
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (SARA III).
VP: 8.
CAS:123-86-4
RTECS #:AF7350000
Fraction by Wt: 5%
OSHA PEL:150 PPM;200 PPM STEL
ACGIH TLV:150 PPM;200 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:XYLENE. VP: 5.1.
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 5%
OSHA PEL:100 PPM;150 PPM STEL
ACGIH TLV:100 PPM;150 PPM STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:2-BUTANONE; (METHYL ETHYL KETONE) (SARA III). VP: 70.2.
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 50%
OSHA PEL:200 PPM;300 PPM STEL
ACGIH TLV:200 PPM;300 PPM STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:SUPP DATA: INGEST: CAN RSLT IN IRRIT & POSS CORROSIVE
ACTION IN MOUTH/STOM TISS/DIGEST TRACT. VOMIT MAY CAUSE (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8: ASPIR OF SOLVENT, RSLTG IN CHEM PNEUMONITIS.
CHRONIC: 2-ETHOXYETHYL ACETATE MAY BE ABSORBED THRU SKIN & (ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9: HAS BEEN SHOWN TO BE A REPROD HLTH HAZ IN TEST
ANIMALS, ALSO THERE MAY BE LIVER &/OR KIDNEY EFFECTS. (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10: NIOSH RECOMMENDS THAT 2-ETHOXYETHYL ACETATE BE
REGARDED IN WORKPLACE AS HAVING POTNTL TO CAUSE ADVERSE (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11: REPRODUCTIVE EFFECTS IN MALE AND FEMALE WORKERS .
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC: VOMITING. DO NOT GIVE ANYTHING TO AN
UNCONSCIOUS PERSON. OBTAIN MEDICAL ATTENTION.
RTECS #:9999999ZZ
Ingred Name:OTHER PREC: HAVE BEEN READ & UNDERSTOOD. WASH HANDS BEFORE
EATING, SMOKING, OR USING WASHROOM. SMOKE IN SMKG AREA ONLY.
RTECS #:9999999ZZ
Ingred Name:RESP PROT: AIR SUPPLIED RESPIRATOR IF THE TLV VALUE OF HDI
IS OVER THE PERMISSIBLE LIMIT.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: IRRIT OF RESP TRACT &
ACUTE NERVS SYS DEPRESS CHARACT BY THE FOLLOWING PROGRESSIVE STEPS:
HDACH/DIZZ/STAG GAIT/CONFUSION/UNCON/COMA. SKIN CONT: ISOCYANATES
REACT W/SKIN PROTEIN/ MOISTURE & CAN CAUSE IRRIT. SYMP MAY BE
SWELLING/ REDNESS/RASH. PRLNG/RTPD CONT CAN CAUSE MOD
IRRIT/DRYING/DEFAT(EFT OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: OF SKIN WHICH CAN CAUSE SKIN TO
CRACK. AS RSLT OF PREVIOUS RPTD OVEREXP OR SINGLE LG DOSE, CERTAIN
INDIVIDUALS WILL DEVELOP ISOCYANATE SENSIT WHICH WILL CAUSE THEM TO
REACT TO LATER EXPOS OF ISOCYANATE LEVELS WELL BELOW TLV VALUE.
EYES: LIQ/AREOSOLS/VAPS ARE IRRIT & MAY CAUSE TEARING/REDNESS/
(SUPP DATA)
Medical Cond Aggravated by Exposure:ASTHMA AND ANY OTHER RESPIRATORY
DISORDERS. SKIN ALLERGIES, ECZEMA, AND DERMATITIS. ISOCYANATE
SENSITIZATION.
======================= First Aid Measures =======================
First Aid:INHAL: MOVE TO AREA FREE FROM RISK OF FURTHER EXPOS. RESTORE
BRTHG. ASTHMATIC TYPE SYMP MAY DEVELOP & MAY BE IMMED/DELAYED BY
SEVERAL HRS. OBTAIN MED ATTN. SKIN: REMOVE CONTAMD CLTHG. WASH
AFFECTED AR EAS THORO W/SOAP & WATER. WASH CONTAMD CLTHG THORO
BEFORE REUSE. EYES: FLUSH W/CLEAN LUKEWARM WATER (LOW PRESS) FOR AT
LST 15 MIN, OCCAS LIFTING LIDS. OBTAIN MED ATTN. INGEST: DO NOT
INDUCE (ING 13)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:23.0F,-5.0C
Lower Limits:1%
Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER MAY BE USED TO COOL CLOSED CONTRS TO PREVENT PRESSURE
BUILD-UP/AUTO-IGNITION/ EXPLOSION. (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CONTRS TIGHTLY CLOSED. ISOLATE FROM
HEAT/ SPARKS/ELEC EQUIP/OPEN FLAME. CLOSED CONTRS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATION TO (SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL SOURCES OF IGNITION (FLAME, SPARK SOURCES, HOT SURFACES).
VENTILATE AREA. CONTAIN AND REMOVE WITH INERT ABSORBENT AND
NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN BLDGS DESIGNED TO COMPLY
W/OSHA 1910.106. AVOID STORING NEAR HIGH TEMP/FIRE/OPEN FLAMES/
SPARK SOURCES. STORE IN TIGHTLY CLOSED CONTRS.
Other Precautions:STORE IN WELL-VENTD AREAS. KEEP CONTRS TIGHT/ UPRIGHT
TO PVNT LEAKAGE. PVNT PRLNG BRTHG OF VAPS/ SPRAY MISTS. PRLNG
OVEREXP CAUSE ALLERGIC RXN. AVOID CONT W/SKIN & EYES. DO NOT TAKE
INTERNALLY. DO NOTHANDLE UNTIL MFR'S SFTY PREC (ING 14)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPRVD RESPIRATOR FOR USE IN AN
ORGANIC VAP ENVIRON (AIR PURIFYING OR FRESH AIR SUPPLIED) IS NEC.
OBSERVE OSHA REGS FOR RESP USE. VENT SHLD BE PROVIDED TO KEEP EXPOS
LEVELS BELOW OSHA PERMI SSIBLE LIMITS. USE NIOSH/MHSA (ING 15)
Ventilation:EXHST VENT SUFFICIENT TO KEEP AIRBORNE CONC OF SOLV,
HDI/POLYISOCYANATES BELOW THEIR RESPECTIVE TLV'S MUST BE UTILIZED.
Other Protective Equipment:USE LONG SLEEVE AND LONG LEG CLOTHING.
Work Hygienic Practices:REMOVE/WASH CONTAMD CLTHG BEFORE REUSE. WASH
HANDS BEFORE EATING, SMOKING, OR USING WASHROOM. SMOKE IN SMKG
AREAS ONLY.
Supplemental Safety and Health
FIRE FIGHT PROC: DURING FIRE, HDI VAPS/OTHER IRRITATING VAPS MAY BE
GENERATED BY COMBUST/ THERMAL DECOMP. EXPLO HAZ: HOT SURF REQ
SPECIAL PREC. DURING EMER CNDTNS, OVEREXP TO DECOMP PRODS MAY CAUSE
HL TH HAZ. SYMP MAY NOT BE IMMED APPARENT.EFTS OF OVEREXP: SWELLING
ACCOMPANIED BY A STINGING SENSATION. (ING 8)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:175F,79C
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Spec Gravity:0.915
Evaporation Rate & Reference:2.3 X N-BUTYL ACETATE
Appearance and Odor:AMBER LIQUID WITH SOLVENT ODOR.
Percent Volatiles by Volume:74.9
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, METAL COMPOUNDS AND SURFACE
ACTIVE MATERIALS.
Stability Condition to Avoid:CONTACT WITH MOISTURE, MATERIAL WHICH
REACT WITH ISOCYANATES AND HIGH TEMPERATURES.
Hazardous Decomposition Products:BY HIGH HEAT/TEMPERATURE: CO, CO*2,
AND NO*X, TRACES OF HCN AND HDI.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MUST BE DISPOSED OF I/A/W FEDERAL, STATE,
AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS. EMPTY CONTAINERS MUST
BE HANDLED WITH CARE, DUE TO PRODUCT RESIDUE AND FLAMMABLE VAPOR.
DO NOT INCINERATE C LOSED CONTAINERS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SHARPIE FINE POINT PERMANENT MARKER, YELLOW
CAGE:86874
CAGE:86874
============= Composition/Information on Ingredients =============
Ingred Name:DYES
Ingred Name:PROPYL ALCOHOL; (N-PROPANOL)
CAS:71-23-8
RTECS #:UH8225000
OSHA PEL:200 PPM;250 STEL
ACGIH TLV:200 PPM;250 STEL, S
Ingred Name:BUTYL ALCOHOL; (N-BUTANOL)(SARA III)
CAS:71-36-3
RTECS #:EO1400000
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:2-PENTANONE, 4-HYDROXY-4-METHYL-; (DIACETONE ALCOHOL)
CAS:123-42-2
RTECS #:SA9100000
OSHA PEL:50 PPM
ACGIH TLV:50 PPM
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THIS PRODUCT IS NOT CONSIDERED TOXIC
UNDER FEDERAL HAZARDOUS SUBSTANCES ACT REGULATIONS, TITLE 16 PART
1500. THIS PRODUCT IS CONSIDERED SAFE WHEN USED UNDER NORMAL USE
CONDITIONS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL:REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O*2/ARTIFICIAL RESPIRATION) .
EYES:IMMEDIATELY FLUSH WITH POTABLE WATER FOR A MINIMUM OF 15
MINUTES, SEEK AS SISTANCE FROM MD . SKIN:FLUSH WITH COPIOUS AMOUNTS
OF WATER. CALL MD .
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:84F,28.9C
Lower Limits:2.2%
Upper Limits:14%
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:WIPE UP WITH ABSORBENT MATERIAL AND DISCARD AS
SOLID WASTE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT SHAKE MARKER. KEEP CAP ON
MARKER WHEN NOT IN USE.
Other Precautions:THIS PRODUCT IS CONSIDERED SAFE WHEN USED UNDER
NORMAL USE CONDITIONS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE UNDER NORMAL USE CONDITIONS.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPEC GRAVITY:0.8044 @ 20C (H*2O = 1).
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:207F,97C
Vapor Pres:13 @ 20C
Vapor Density:2.07 @ 20C
Spec Gravity:SUPDAT
Evaporation Rate & Reference:1.3 (BUTYL ACETATE = 1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS MOBILE LIQUID WITH MILD ALCOHOL
ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NOT AVAILABLE
Stability Condition to Avoid:NOT AVAILABLE
Hazardous Decomposition Products:NOT AVAILABLE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS . DISCARD AS SOLID WASTE.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: CHROMIC ACID, 10%, LC13100
Cage: EO318
=======================================================
Contractor Summary
=======================================================
Cage: EO318
Cage: 0MX47
=======================================================
Ingredients
=======================================================
Cas: 1333-82-0
RTECS #: GB6650000
80 MG/KG
% Wt: 10
OSHA PEL: 0.5 MG CR/M3
ACGIH TLV: 0.05 MG CR/M3
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
% Wt: BALANCE
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
ALL TRACE OF CHEM IS GONE. FOR BURNS,
-----------------------------
ONCE. INGEST: GIVE CONSCIOUS VICTIM LG
-----------------------------
GASTRIC LAVAGE. GET MED AID AT ONCE.
-----------------------------
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: SEE INGREDIENT 1
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: ACUTE: EYE, NOSE, THROAT, RESPIRATORY IRRITANT; MAY
PRODUCE BURNS & ULCERS. SYMPTOMS INCLUDE HEADACHE, COUGH, FLUID IN LUNGS,
BRONCHITIS, CHEST PAINS, EMPHYSEMA, LIVER & KIDNEY DAMAGE,
CONJUNCTIVITIS, CORNEAL DAMAGE (POSSIBLE BLINDNESS), ABDOMINAL PAIN,
VOMITING & DIARRHEA. CHRONIC: SENSITIZATION (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CHROMIUM (VI) OXIDE (1:3): IARC MONOGRAPHS ON
EVALUATION OF CARCIN RISK OF CHEMS TO MAN, VOL 49, PG 49, 1990: (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: DERMATITIS, ULCERATION &
PERFORATION OF THE RESPIRATORY TRACT, DISCOLORATION OF TEETH & POTENTIAL
CARCINOGENIC EFFECTS. CERTAIN SALTS OF CHROMIUM ARE IMPLICATED IN INCREASED
INCIDENCE OF LUN G CANCER AMONG WORKERS EXPOSED; POSSIBILITY OF OTHER TUMOR
SITES EXISTS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL: MOVE TO FRESH AIR. GIVE ARTF RESP IF NEC. MAINTAIN AIRWAY
(THROAT MAY SWELL) & BLOOD PRESS; ADMIN OXYGEN IF NEEDED. KEEP WARM, AT
REST. GET MED AID AT ONCE. SKIN: REMOVE CONTAMD CLTHG & SHOES I MMED.
WASH W/MILD SOAP; FLUSH W/LG AMTSOF WATER (15-20 MIN) UNTIL CHEM IS GONE.
COVER BURNS W/DRY STERILE DRESSING (SECURE, NOT TIGHT). GET MED AID AT ONCE.
EYES: FLUSH W/LG AMTS OF WATER
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: CONTAIN IF POSS. ABSORB W/CEMENT, FLY ASH,
DIATOMACEOUS EARTH OR SUITABLE INERT MATL. MAY BE NEUTRALIZED W/LIME, CRUSHED
LIMESTONE, SODIUM BICARBONATE TO PH OF 7. SCOOP MATL INTO PLASTIC CNTNR FOR
DIS P. LABEL CNTNR, INDICATE MATL CONTAINS CHROMIUM.
Neutralizing Agent: MAY BE NEUTRALIZED W/LIME, CRUSHED LIMESTONE, SODIUM
BICARBONATE TO A PH OF 7.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. KEEP OUT OF SEWERS AND DRAINS WHERE HARMFUL CHEMICAL REACTIONS
COULD OCCUR OR CHROMIUM MAY PERSIST IN THE ENVIRONMENT.
Handling And Storage Precautions: STORE AS CORROSIVE ACID. PROTECT FROM HEAT
& INCOMPATIBLE MATERIALS. KEEP CONTAINERS CAPPED. STORE IN
GLASS/POLYETHYLENE - NO UNMARKED CONTAINERS.
Other Precautions: DO NOT POUR WASTE INTO DRAINS OR SEWERS. DO NOT WEAR CONTACT
LENSES WHEN WORKING WITH CHEMICALS.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NON-FLAMMABLE
Extinguishing Media: DRY CHEMICAL, CARBON DIOXIDE, WATER SPRAY, FOG OR FOAM FOR
LARGE FIRES.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). KEEP CONTAINERS COOL; MOVE IF POSSIBLE. AVOID BREATHING
TOXIC & CORROSIVE VAPORS - KEEP UPWIND.
Unusual Fire/Explosion Hazard: NEGLIG FIRE HAZ; MOD FIRE & EXPLO HAZ WHEN
IN CNTCT W/METALS (EXPLO HYDROGEN GAS IS FORMED) OR COMBUST ORGANIC OR
READILY OXIDIZABLE MATLS. WHEN TOX (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: AT 5MG/M3 & 50MG/M3 H*2SO*4 - USE NIOSH/MSHA APPRVD
SUPPLIED AIR RESP W/FULL FACEPIECE (SAF) OR NIOSH/MSHA APPRVD SCBA W/FULL
FACEPIECE. AT 20MG/M3 CR & 100MF/M3 H*2SO*4 - USE NIOSH/MSHA APPRVD SAF
IN PRESS DEMAND OR CONTINUOUS
Ventilation: PROVIDE LOCAL EXHAUST OR GENERAL DILUTION VENTILATION TO MEET
PERMISSABLE EXPOSURE LIMITS (PEL).
Other Protective Equipment: DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N).
PROVIDE EYE-WASH FOUNTAIN IN IMMED WORK AREA. WEAR ACID PROOF CLTHG.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLO HAZ: CHROMIUM TRIOXIDE IS FORMED, OXYGEN
IS ALSO RELEASED INCREASING FIRE HAZ. MATLS TO AVOID: ALCOHOLS, FUELS, ACETIC
ANHYDRIDE, PYRIDINE, NITRIC & PERCHLORIC ACIDS. EXPLAN OF CARCIN: GROUP
1. NTP 7TH ANNUAL REPORT ON CARCINS, 1991:KNOWN TO BE CARCIN. HUMAN:LUNG
TUMORS.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: T6
Vapor Pres: 14 @ 20C
Spec Gravity: >1
PH: ACIDIC
Evaporation Rate & Reference: >1 ETHER =1
Solubility in Water: SOLUBLE
Appearance and Odor: CLEAR ORANGE SOLUTION; ODORLESS.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT OR EXPOSURE TO ORGANIC MATERIALS THAT RESULT
IN VIOLENT EXOTHERMIC REACTIONS.
Materials To Avoid: REACTS VIOLENTLY OR EXPLO W/METALS (ESP POWDERED),
CARBIDES, CHLORATES, FULMINATES, PICRATES, PERMANGANATES, (SUPDAT)
Hazardous Decomposition Products: THERMAL DECOMPOSITION RESULTS IN POSSIBLE
TRIVALENT CHROMIUM FORMATION WITH LIBERATED OXYGEN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: CHROMIC ACID, 10%, LC13100
Cage: EO318
Assigned IND: Y
Company Name: LABCHEM INC
Street: 200 WILLIAM PITT WAY
Zipcode: 15238
Label Required IND: Y
Date Of Label Review: 01/11/1995
Status Code: C
Label Date: 01/11/1995
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: FIRE/EXPLOSION HAZARD IN CONTACT WITH METALS, ALCOHOLS,
FUELS & OTHER MATERIALS. ACUTE: EYE, NOSE, THROAT, RESPIRATORY IRRITANT;
MAY PRODUCE BURNS & ULCERS. SYMPTOMS INCLUDE HEADACHE, COUGH, FLUID IN
LUNGS, BRONCHITIS, CHEST PAINS, EMPHYSEMA, LIVER & KIDNEY DAMAGE,
CONJUNCTIVITIS, CORNEAL DAMAGE (POSSIBLE BLINDNESS), ABDOMINAL PAIN, VOMITING
& DIARRHEA. CHRONIC: CANCER HAZARD. CONTAINS CHROMIUM (V I) OXIDE (1:3),
WHICH IS LISTED AS A HUMAN LUNG CARCINOGEN (FP N). SENSITIZATION DERMATITIS,
ULCERATION & PERFORATION OF THE RESPIRATORY TRACT, DISCOLORATION OF
TEETH.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:LEAD-ACID BATTERY
Preparer's Name:NONE
CAGE:25759
CAGE:25759
CAGE:78258
============= Composition/Information on Ingredients =============
Ingred Name:LEAD-LEAD OXIDE (SARA III)
Fraction by Wt: 69%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.05 MG PB/M3
ACGIH TLV:0.15 MG PB/M3;DUST94
Ingred Name:SULFURIC ACID ELECTROLYTE
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 21%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:NON-HAZARDOUS MATERIALS
Fraction by Wt: 10%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS UNKNOWN.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SEVERE BURNS AND EYE DAMAGE
FROM SULFURIC ACID ELECTROLYTE. ILLNESS FROM SULFUR OXIDE FUMES.
CHRONIC: NONE SPECIFIED BY MANUFACTURER. NOT APPLICABLE FOR
FINISHED PRODUCT USED IN NORMAL CONDITIO NS.
Explanation of Carcinogenicity:LEAD AND LEAD COMPOUNDS: IARC GROUP 2B
I: "POSSIBLY CARCINOGENIC TO HUMANS","INADEQUATE EVIDENCE".
Effects of Overexposure:IRRITATION AND ACID BURNS. PUNGENT ODOR AND
RESPIRATORY IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:FOR SULFUR OXIDE FUMES, DISCONNECT BATTERIES, EVACUATE AND
VENTILATE AREA. EXTERNAL EXPOSURE: REMOVE CONTAMINATED CLOTHING.
FLUSH AREAS CONTAMINATED BY SULFURIC ACID ELECTROLYTE WITH WATER.
GET MEDICA L ATTENTION. INTERNAL EXPOSURE: DRINK LARGE AMOUNTS OF
WATER OR MILK, FOLLOWED BY MILK OF MAGNESIA, BEATEN EGGS, OR
VEGETABLE OIL. GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:MULTI-PURPOSE DRY CHEMICAL OR MULTI-PURPOSE CARBON
DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT. COOL BATTERY EXTERIOR TO PREVENT RUPTURE.
ACID MISTS AND VAPORS IN A FIRE ARE TOXIC AND CORROSIVE.
Unusual Fire/Explosion Hazard:HYDROGEN GAS MAY BE PRODUCED AND MAY
EXPLODE IF IGNITED. REMOVE ALL SOURCES OF IGNITION. VENTILATE AREA.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID CONTACT WITH ACID MATERIALS. NEUTRALIZE
WITH BAKING SODA. FLUSH WITH LARGE AMOUNTS OF WATER.
Neutralizing Agent:BAKING SODA IN WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:BATTERIES WITH RELEASED ELECTROLYTE
SHALL BE SEALED IN POLYETHYLENE BAGS.
Other Precautions:DO NOT CRACK BATTERY CASES. DO NOT OVERCHARGE. KEEP
LIGHTED CIGARETTES, SPARKS, AND FLAMES AWAY FROM CHARGING
BATTERIES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NORMALLY REQUIRED. WEAR NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE.
Ventilation:NATURAL CONVECTION IS NORMALLY ADEQUATE.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE.
================== Physical/Chemical Properties ==================
HCC:C1
Appearance and Odor:6 VOLT BATTERY, 2.1 IN. WIDE BY 5.5 IN. LONG BY 4
IN. HIGH.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SOLVENTS MAY DISSOLVE BATTERY CASE MATERIAL.
Stability Condition to Avoid:AVOID SHORTING, OVERCHARGING.
Hazardous Decomposition Products:SEVERE OVERCHARGE AND OVERHEATING MAY
CAUSE SULFUR OXIDE FUMES.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:PLACE IN ACID-RESISTANT CONTAINERS. DISPOSE IN
ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. DO NOT
INCINERATE. DISPOSE WITH AUTOMOTIVE BATTERY SCRAP.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CADMIUM PLATED AIRCRAFT PART
CAGE:55284
CAGE:55284
============= Composition/Information on Ingredients =============
Ingred Name:CADMIUM (SARA 313) (CERCLA)
CAS:7440-43-9
RTECS #:EU9800000
Fraction by Wt: TRACE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 MG/M3 DUST; Z-2
ACGIH TLV:0.01 MG/M3 DUST;9495
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:THIS METAL AIRCRAFT PART IS PLATED
W/CADMIUM. PART IS NOT HAZARDOUS. HAZARDS ARE FROM DUSTS & FUMES
GENERATED IF PART IS MACHINED. AVOID CONTACT W/CADMIUM DUST &
FUMES. ACUTE-ACUTE PNEUMONITIS & PULMO NARY EDEMA. CHRONIC-KIDNEY
DISEASE, LUNG & PROSTATE CANCER, REDUCED PULMONARY FUNCTION & LUNG
DISEASE.
Explanation of Carcinogenicity:PLATED W/CADMIUM [7440-43-9] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES:REDNESS OR PAIN. SKIN:IRRITATION.
INHALATION:RESPIRATORY IRRITATION, SHORTNESS OF BREATH, CHEST PAIN,
FLU-LIKE SYMPTOMS, WEAKNESS, FEVER, HEADACHE, CHILLS, SWEATING,
MUSCULAR PAIN. INGESTION:VOMI TING, ABDOMINAL PAIN, NAUSEA,
DIARRHEA,HEADACHE, & SORE THROAT.
Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION ON MSDS.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ATTENTION IMMEDIATELY FOR ANY EXPOSURE. EYE:FLUSH
W/WATER TO 15 MIN. SKIN:WASH W/SOAP & WATER. REMOVE CONTAMINATED
CLOTHING & LAUNDER BEFORE REUSE. INHALED:REMOVE FROM EXPOSURE. AID
OR RES TORE BREATHING AS NEEDED. INGESTED:TREATMENT MUST BE
ADMINISTERED BY MEDICAL PERSONNEL. ADVICE TO PHYSICIAN:DO NOT
PERFORM CHELATION THERAPY.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY SAND, DRY DOLOMITE, DRY GRAPHITE, OR SODIUM
CHLORIDE
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS
W/FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE MODE.
Unusual Fire/Explosion Hazard:CADMIUM DUST CREATED DURING MACHINING MAY
PRESENT A MODERATE EXPLOSION HAZARD WHEN EXPOSED TO FLAME. DUST &
STRONG OXIDIZERS MAY CASUSE FIRE OR EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:(ALWAYS WEAR RECOMMENDED PERSONAL PROTECTIVE
EQUIPMENT.) ANY NORMAL CLEAN-UP PROCEDURE IS APPLICABLE. AVOID
GENERATION OF DUSTS. SPILLS & RELEASES MAY HAVE TO BE REPORTED TO
FEDERAL &/OR LOCAL AUTHOR ITIES.
Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS.
======================Handling and Storage ======================
Handling and Storage Precautions:SHIPPING & STORAGE CONTAINERS
CONTAINING CADMIUM, CADMIUM COMPOUNDS, CONTAMINATERD CLOTHING &
EQUIPMENT, WASTE, SCRAP, ETC. MUST BEAR WARNING LABELS.
Other Precautions:AVOID CONTACT TO SKIN, EYES & CLOTHING. AVOID
BREATHING DUST. USE ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:RESPIRATORS USED MUST BE APPROVED BY BOTH MSHA &
NIOSH. AIR PURIFYING RESPIRATORS MUST BE EQUIPPED W/HEPA FILTERS.
AIR SUPPLIED RESPIRATORS OPERATED IN POSITIVE PRESSURE MODE ARE
ALSO ACCEPTABLE. SUIT EQUIPMENT TO EXPOSURE LEVEL.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP CADMIUM
DUST & FUME LEVELS BELOW THE TLV.
Other Protective Equipment:RUBBER APRON AND/OR SUIT REQUIRED. CLEAN
CHANGE ROOMS, HAND WASHING FACILITIES, SHOWERS SHOULD BE AVAILABLE.
Work Hygienic Practices:MFR:?.HMIS:USE GOOD CHEMICAL HYGIENE
PRACTICES. AVOID CONTACT IF AT ALL POSSIBLE. WASH THOROUGHLY AFTER
HANDLING.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NONE
Appearance and Odor:MATTED TEXTURE METALLIC TO POLISHED METAL FINISH
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
HYDROCHLORIC &/OR NITRIC ACIDS
Stability Condition to Avoid:MFR GAVE NO INFORMATION ON MSDS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:RCRA HAZARDOUS WASTE = D006. DISPOSE I/A/W
FEDERAL, STATE & LOCAL REGULATIONS. NOTE:THIS MATERIAL MAY HAVE
VALUE ON A RECYCLED BASIS. IF RECLAIMED, THE MATERIAL IS NOT
HAZARDOUS UNDER RCRA. THIS INFOR MATION IS FOR THE PRODUCT SHIPPED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:2584 ALKALINITY CONTROL
Preparer's Name:RICKY A. STACKHOUS
CAGE:FO908
CAGE:FO908
CAGE:89524
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM HYDROXIDE (SARA III). LD50: (ORAL,RAT) 205 MG/KG
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 20-40%
OSHA PEL:2 MG/M3
ACGIH TLV:C 2 MG/M3; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:POTASSIUM HYDROXIDE (SARA III). LD50:(ORAL,RAT) 1,260
MG/KG
CAS:1310-58-3
RTECS #:TT2100000
Fraction by Wt: 10-20%
OSHA PEL:2 MG/M3, C
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Ingred Name:MATLS TO AVOID: HEAT, SPLATTERING OR BOILING AND THE
RELEASE OF TOXIC FUMES. AVOID CONTACT WITH ALUMINUM, TIN, (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: ZINC, AND ZINC ALLOYS.
RTECS #:9999999ZZ
Ingred Name:FIRST AID PROC:SYMPTOMS & CLINICAL CNDTN. CAUTION: IF
UNCON, HAVING TROUBLE BRTHG, OR IN CONVULSIONS, DO NOT (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:INDUCE VOMIT/GIVE WATER. NOTE TO MD: PROBABLE
MUSCOSAL DMG MAY CONTRAINDICATE THE USE OF GASTRIC LAVAGE. (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: MEASURES AGAINST CIRCULATORY SHOCK, RESPIRATORY
DEPRESSION, & CONVULSIONS MAY BE NEEED.
RTECS #:9999999ZZ
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP: SLICKER SUIT IS RECOMMENDED IF GROSS
EXPOSURE IS POSSIBLE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE:CORROSIVE TO EYES W/POSSIBLE
PERMANENT DMG DEPENDING ON THE LENGTH OF EXPOSURE & ON THE FIRST
AID ACTION GIVEN. SKIN: CORROSIVE TO THE SKIN. POSSIBLY RESULTING
IN THIRD DEGREE BURNS DEPENDING ON T HE LENGTH OF EXPOSURE AND ON
THE FIRST AID ACTION GIVEN. INGEST: CAN BE HARMFUL. CAN CAUSE
BURNS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: INHALATION: CAN BE CORROSIVE TO THE
MUCOUS MEMBRANES AND THE LUNGS. A REVIEW OF AVAIALABLE DATA DOES
NOT IDENTIFY ANY SYMPTOMS FROM EXPOSURE NOT PREVIOUSLY MENTIONED.
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF EXISTING CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYES:IMMED FLUSH FOR @ LST 15 MIN WHILE HOLDING EYELIDS OPEN.
CALL MD AT ONCE. SKIN:IMMED FLUSH W/WATER FOR @ LST 15 MIN. FOR A
LRG SPLASH, FLOOD BODY UNDER SHOWER. CALL MD AT ONCE. INGEST:DO NOT
INDU CE VOMITING. GIVE WATER. CALL MD @ ONCE. INHAL:REMOVE TO FRESH
AIR. TREAT SYMPTOMS. CALL MD. NOTE TO MD: BASED ON THE INDIVIDUAL
RXNS OF THE PATIENT, THE MD'S JUDGEMENT SHLD BE USED TO CTRL (ING
6)
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTACT WITH REACTIVE METALS MAY RESULT
IN THE GENERATION OF FLAMMABLE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:SML: CNTN W/ABSORB MATL, SUCH AS CLAY,
SOIL/ANY COMMERCIALLY AVAIL ABSORBENT. SHOVEL RECLAIMED LIQUID &
ABSORB INTO RECOVERY OR SALVAGE DRUMS FOR DISPOSAL. REFER TO CERCLA
IN SECT 14. LRG SPILL: DIKE TO PVNT FURTHER MOVEMENT & RECLAIM
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT GET IN EYE/SKIN/CLTHG. DO NOT
TAKE INTERNALLY. EMPTY CNTNRS MAY CONTAIN RESIDUAL PROD. DO NOT
REUSE CNTNR UNLESS PROPER RECONDITIONED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF IT IS POSS TO GENERATE SIGNIFICANT LEVLES OF
MIST, A NIOSH/MSHA APPRVD OR EQUIVALENT DUST RESP IS RECOMMENDED.
FOR LRG SPILLS, ENTRY INTO LARGE TANKS, VESSELS OR ENCLOSED SML
SPACES W/INADEQ VENT, A NIOSH/MSHA APPRVD PRESS- (SUPP DATA)
Ventilation:GENERAL VENTILATION IS RECOMMENDED.
Other Protective Equipment:THE AVAILABILITY OF AN EYE WASH FOUNTAIN AND
SAFETY SHOWER IS RECOMMENDED. WEAR IMPERMEABLE BOOTS & APRON. (ING
10)
Work Hygienic Practices:IF CLTHG IS CONTAM, REMOVE CLTHG & THORO WASH
THE AFFECTED AREA. LAUNDER CONTAM CLTHG BEFORE REUSE.
Supplemental Safety and Health
SPILL PROC: INTO RECOVERY OR SALVAGE DRUMS OR TANK TRUCK FOR DISPOSAL.
REFER TO CERCLA IN SECTION 14. WASTE DISP METH: INDUSTRIAL WASTE
LANDFILL. A HAZ LIQUID WASTE CAN ALSO BE DEEP-WELL INJECTED IN A
CCORDANCE WITH LOCAL, STATE AND FEDERALREGULATIONS. RESP PROT:
DEMAND, SCBA IS RECOMMENDED.
================== Physical/Chemical Properties ==================
Vapor Density:12.5
Spec Gravity:1.5 @ 70F
pH:14
Solubility in Water:COMPLETELY
Appearance and Odor:COLORLESS LIQUID. NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CNTCT W/STRONG ACIDS (SULFURIC, PHOSPHORIC, NITRIC, HYDROCHLORIC,
CHROMIC, SULFONIC) WHICH CAN GENERATE (ING 4)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:IF THIS PROD BECOMES A WASTE, IT MEETS CRITERIA
OF A HAZ WASTE AS DEFINED UNDER THE RCRA 40 CFR 261. HAZ WASTE
D002. AS A HAZ LIQ WASTE, IT MUST BE SOLIDIFIED W/STABILIZING
AGENTS SO THAT NO FREE LIQREMAINS BEFORE DISP TO LICENSED (SUPP
DATA)
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ARCTIC MOTOR OIL W
Preparer's Name:DGSC-SSH
CAGE:PSOGC
CAGE:PSOGC
============= Composition/Information on Ingredients =============
Ingred Name:PETROLEUM BASED LUBRICATING OIL
Fraction by Wt: >90%
Other REC Limits:NONE SPECIFIED
OSHA PEL:5 MG/M3 (MIST)
ACGIH TLV:5 MG/M3 (MIST)
Ingred Name:ADDITIVES INCLUDING INHIBITORS, ANTIWARE AGENTS, & ZINC
DIALKYLDITHIOPHOSPHATE.
Fraction by Wt: <10%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS >5G/KG ESTIMATED
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ON RARE OCCASIONS, PROLONGED AND
REPEATED EXPOSURE TO OIL MIST POSES A RISK OF PULMONARY DISEASE
SUCH AS CHRONIC LUNG INFLAMMATION. THIS CONDITION IS USUALLY
ASYMPTOMATIC AS A RESULT OF REPEATED SMALLASPIRATIONS. SHORTNESS
OF BREATH AND COUGH ARE THE MOST COMMON SYMPTOMS. ASPIRATION MAY
LEAD TO CHEMICAL PNEUMONITIS.
Explanation of Carcinogenicity:IARC HAS DETERMINED THERE IS SUFFICIENT
EVIDENCE FOR THE CARCINOGENICITY IN EXPERIMENTAL ANIMALS OF USED
MOTOR OIL.
Effects of Overexposure:GENERALLY CONSIDERED MINIMALLY IRRITATING TO
THE EYES AND MILDLY IRRITATIONG TO THE SKIN. PROLONGED AND REPEATED
CONTACT MAY RESULT IN VARIOUS SKIN DISORDERS SUCH AS DERMATITIS,
FOLLICULITIS OR OIL AC NE. INHALATION OF VAPOR OR OIL MIST MAYCAUSE
MILD UPPER RESPIRATORY TRACT IRRITATION. SLIGHTLY TOXIC IF
SWALLOWED.
Medical Cond Aggravated by Exposure:PREEXISTING SKIN AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
======================= First Aid Measures =======================
First Aid:SKIN: REMOVE CONTAMINATED CLOTHING. WASH WITH SOAP AND WATER.
GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. INHALATION: REMOVE TO
FRESH AIR & RESTORE BREATHING IF NECESSARY. GET MEDICAL ATTENTION.
EYE : IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. INGESTION: MAY ACT AS A
LAXATIVE. DO NOT INDUCE VOMITING. RELATIVELY NON-TOXIC UNLESS
ASPIRATED.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>290F,>143C
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:COMBUSTIBLE LIQUID. WILL RELEASE
FLAMMABLE VAPORS WHEN HEATED ABOVE FLASH POINT. VAPORS CAN BE
EXPLOSIVE IF CONFINED.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL IMMEDIATELY. DO NOT ALLOW SPILL
TO ENTER SEWERS OR WATERCOURSES, REMOVE ALL SOURCES OF IGNITION.
ABSORB WITH APPROPRIATE INERT MATERIAL SUCH AS SAND, CLAY, ETC.
LARGE SPILLS MAY BE PICKE D UP USING VACUUM PUMPS, SHOVELS,
BUCKETS, ETC.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT TRANSFER TO UNMARKED
CONTAINERS. STORE IN CLOSED CONTAINERS AWAY FROM HEAT, SPARKS, OPEN
FLAME, OR OXIDIZING MATERIALS. COMBUSTIBLE LIQUID.
Other Precautions:MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. PROPERLY DISPOSE OF
CONTAMINATED LEATHER ARTICL ES THAT CAN NOT BE DECONTAMINATED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED AIR-PURIFYING RESPIRATOR
FOR ORGANIC VAPORS AND PARTICULATES OR AN ATMOSPHERE-SUPPLYING
RESPIRATOR IF REQUIRED. PROTECTION IS NOT REQUIRED UNDER NORMAL USE
CONDITIONS.
Ventilation:NO SPECIAL REQUIREMENTS UNDER ORDINARY CONDITIONS OF USE.
MECHANICAL EXHAUST RECOMMENDED IF USED IN ENCLOSED AREA.
Other Protective Equipment:WEAR PROTECTIVE CLOTHING, APRON AND BOOTS AS
REQUIRED TO MINIMIZE SKIN CONTACT.
Work Hygienic Practices:MINIMIZE SKIN CONTACT. WASH WITH SOAP AND WATER
BEFORE EATING, DIRNKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
THIS PRODUCT IS CLASSIFIED AS AN OIL UNDER SECTION 311 OF THE CLEAN
WATER ACT. SPILLS ENTERING SURFACE WATERS OR ANY WATER COURSES OR
SEWERS ENTERING/LEADING TO SURFACE WATERS THAT CAUSE A SHEEN MUST
BE REPORTED TO THE NATIONAL RESPONSE CENTER. 800-424-8602
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:B.P. Text:>600F,>316C
Melt/Freeze Pt:M.P/F.P Text:-65F,-54C
Decomp Temp:Decomp Text:>500F,>260C
Vapor Pres:NIL
Vapor Density:>1
Spec Gravity:0.86
Viscosity:5.75CS@210F
Solubility in Water:NEGLIGIBLE
Appearance and Odor:AMBER LUBRICATING OIL, PETROLEUM ODOR
Percent Volatiles by Volume:0
Corrosion Rate:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CARBON MONOXIDE AND OTHER UNIDENTIFIED
ORGANIC COMPOUNDS MAY BE FORMED UPON COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE MAY BE BURNED IN AN APPROVED INCINERATOR
OR DISPOSED OF IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND
FEDERAL LAWS AND REGULATIONS. RECYCLE IF POSSIBLE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GLYCOL ETHER DB
CAGE:34897
CAGE:34897
============= Composition/Information on Ingredients =============
Ingred Name:DIETHYLENE GLYCOL MONOBUTYL ETHER
CAS:112-34-5
RTECS #:KJ9100000
Fraction by Wt: >95%
===================== Hazards Identification =====================
Effects of Overexposure:EYE/SKIN:IRRIT. INHALATION: RESP
IRRIT,DIZZY,FATIGUE,UNCONSCIOUSNESS OR ASPHYXIATION. *SEE SUP DATA
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH WATER 15 MIN,SEE MD. SKIN: WASH WITH SOAP &
WATER,REMOVE CONTAMINATED CLOTH. INGESTION: GIVE 2 GLASS
WATER,INDUCE VOMITING,CALL A MD. INHALATION: REMOVE TO FRESH
AIR,GIVE ARTIF RESP IF NEEDED,GET MEDICAL ATTN.
===================== Fire Fighting Measures =====================
Flash Point:240F/115C (CC)
Lower Limits:0.9
Extinguishing Media:ALCOHOL FOAM,WATER FOG,CARBON DIOXIDE,DRY CHEMICAL
Fire Fighting Procedures:SELF-CONT BREATH APP
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR,CAN TRAVEL
ALONG GROUND TO SOURCE OF IGNITION AND CAUSE FLASH BACK
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES,EXCLUD UNPROTECTED
PERSONS. STOP SPILL AT SOURCE AND PREVENT SPREADING. PUMP LIQUID TO
SALVAGE TANK,SPREAD ABSORBENT ON REMAINDER. SHOVEL INTO
CONTAINERS.PREVENT RUN OFF INT O SEWERS,RIVERS OR OTHER BODIES OF
WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS MAY BE HAZARDOUS WHEN EMPTY
AS RESIDUES (VAPOR,LIQUID,SOLIDS) REMAIN
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESP DEVICE IN ACCORD WITH
EXPOSURE OF CONCERN
Ventilation:MECHANICAL GENERAL/LOCAL EXHAUST
Other Protective Equipment:AS NEEDED TO PREVENT SKIN CONTACT
Supplemental Safety and Health
*INGESTION: GI IRRIT,NAUSEA,VOMITING,DIARRHEA. OVEREXPOSURE TO MATERIAL
HAS CAUSED KIDNEY DAMAGE IN LAB ANIMALS.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:447F/230C
Vapor Pres:<1
Vapor Density:5.6
Spec Gravity:0.954
Evaporation Rate & Reference:<1 (BUAC)
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:CO,CO2,VARIOUS HYDROCARBONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DESTROY BY LIQUID INCINERATION.CONTAMINATED
ABSORBENT MAY BE PLACED IN SANITARY LANDFILL IN ACCORDANCE WITH
LOCAL,STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:METHYL CELLOSOLVE
Preparer's Name:DOD/HMIS (DGSC-SSH)
CAGE:86511
CAGE:86511
============= Composition/Information on Ingredients =============
Ingred Name:2-METHOXYETHANOL (EGME) (SARA III)
CAS:109-86-4
RTECS #:KL5775000
Fraction by Wt: >99%.
OSHA PEL:S, 25 PPM
ACGIH TLV:S, 5 PPM; 9192
Ingred Name:SEC. 3.3 OF SPEC INDICATES THE PRESENCE OF AN
ANTIOXIDANT,50- 150 PPM (EITHER;
RTECS #:9999999ZZ
Ingred Name:2,6 DITERTIARY BUTYL,4-METHYLPHENOL;OR 2,4
DIMETHYL,6-TERTIARY BUTYLPHENOL; OR
RTECS #:9999999ZZ
Ingred Name:2,6 DITERTIARY BUTYLPHENOL; OR MIXED TERTIARY BUTYLPHENOL
COMPOSITION)
RTECS #:9999999ZZ
Ingred Name:ANTIOXIDANT,(RANGE 50-150 PPM) SEE ABOVE FOR OPTIONS
PERMITTED BY SPEC.
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:.
Effects of Overexposure:HEAD, DIZZINESS, DROW, FTG, NAU, VOMIT, TREMOR,
CONF, EYE AND SKIN IRRIT, ANEM.
Medical Cond Aggravated by Exposure:.
======================= First Aid Measures =======================
First Aid:INHAL:RMV TO FRESH AIR. IF NOT BRTHNG GIVE CPR; IF BRTHNG
DIFF GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER. SKIN: WASH
W/SOAP&WATER. RMV CONTAM CLTHG&SHOES. INGEST:INDUCE VOMIT. RPT
UNTIL VOMIT IS CLEAR. NOTHG BY MOUTH IF UNCONSC. GET MEDICAL ATTN.
===================== Fire Fighting Measures =====================
Flash Point:103F,39.4C(TCC)
Autoignition Temp:Autoignition Temp Text:545F
Lower Limits:2.5
Upper Limits:19.8
Extinguishing Media:WATER SPRAY,CO2,DRY CHEMICAL,ALCOHOL OR UNIVERSAL
TYPE FOAMS
Fire Fighting Procedures:USE SCBA AND PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR SCBA AND PROTECTIVE CLOTHING. VENT AREA,
ELIM IGNIT SOURCE. DIKE TO RETAIN LIQUID. STOP LEAK WITHOUT RISK.
ABSORB SMALL AMOUNT WITH INERT MATERIAL OR PUMP/VAC LARGE AMOUNT
INTO CLOSED DISPOSAL CO NTAINER. FLUSH RESIDUE WITH LARGE AMOUNT OF
WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID SKIN,EYE,CLOTHES CONTACT.AVOID
VAPOR. KEEP FROM HEAT/FLAME.KEEP CONTAINER CLOSED.USE WITH GOOD
VENTILATION.WASH THOROUGHLY AFTER HANDLING.
Other Precautions:NONE
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH, MSHA APPROVED RESP/AIR SUPPLIED AIR MASK.
Ventilation:MECHANICAL (GEN) RECOMMENDED FOR NORMAL OPERATIONS.
Other Protective Equipment:EYE BATH & SAFETY SHOWER
Work Hygienic Practices:.
Supplemental Safety and Health
MSDS DATED 1 MAR 83. **NOTE THAT THIS MSDS COPIED FROM ANOTHER ONE
RECEIVED FROM PHIPPS ON NSN 6850-00-060-5312.**
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:256F,124.4C
Vapor Pres:6
Vapor Density:2.62
Spec Gravity:0.9663
Evaporation Rate & Reference:0.62 (BU AC = 1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID, MILD ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS & IGNITION SOURCES
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:THERMAL DECOMP: CARBON MONOXIDE &/OR
CARBON DIOXIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE FEDERAL,STATE, &LOCAL REGULATIONS
| 1 | eyes_protection_mandatory |
=======================================================
NIIN: 01-444-9120
Product ID: GS-3/E
Cage: 20772
Box: 483
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 15747
Contract Number: SP0400-01-M-W387
Cage: 20772
Box: 483
Cage: 9T424
Contract Number: SPO450-01-M-D714
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: LEAK TEST COMPOUND
Specification Number: UNKNOWN
Unit of Issue: BX
Quantitative Expression: 00000000006EA
UI Container Qty: 0
Type of Container: CAPSULE FORM
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NO DATA PROVIDED BY MANUFACTURER
Route Of Entry Inds - Inhalation: YES
Skin: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EMERGENCY OVERVIEW: MAY CAUSE EYE, SKIN AND RESPIRATORY
SYSTEM IRRITATION. EYE: CAN CAUSE MILD IRRITATION. SKIN: IRRITATION CAN OCCUR
FOLLOWING PROLONGED OR REPEATED CONTACT. INHALATION (BREATHING): P ROCCESING
VAPORS CAN POSSIBLY CAUSE IRRITATION TO THE UPPER RESPIRATORY TRACT.
INGESTION (SWALLOWING): INGESTION CAN CAUSE GASTROINTESTINAL IRRITATION.
Explanation Of Carcinogenicity: NO DATA PROVIDED BY MANUFACTURER
Signs And Symptions Of Overexposure: EYE: CAN CAUSE MILD IRRITATION. SKIN:
IRRITATION CAN OCCUR FOLLOWING PROLONGED OR REPEATED CONTACT. INHALATION
(BREATHING): PROCCESING VAPORS CAN POSSIBLY CAUSE IRRITATION TO THE UPPER
RESPIRATORY TRA CT. INGESTION (SWALLOWING): INGESTION CAN CAUSE
GASTROINTESTINAL IRRITATION.
Medical Cond Aggravated By Exposure: A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF ANY EXISTING MEDICAL CONDITIONS.
First Aid: EYE: FLUSH EYES WITH PLENTY OF WATER FOR 15 MINUTES. IF IRRITATION
DEVELOPS, CONSULT A PHYSICIAN. SKIN: REMOVE CONTAMINATED CLOTHING, WASH
AFFECTED AREA WITH SOAP AND PLENTY OF WATER. IF IRRITATION DE VELOPS, CONSULT
A PHYSICIAN. WASH CONTAMINATED CLOTHING SEPARATELY BEFORE REUSE. INHALATION
(BREATHING): REMOVE TO FRESH AIR, IF SYMPTOMS DEVELOP, SEEK IMMEDIATE MEDICAL
ATTENTION. IF NOT BREATHING, G IVE ARTIFICIAL RESPIRATION. INGESTION
(SWALLOWING): CALL A PHYSICIAN IMMEDIATELY. INDUCE VOMITING ONLY AS DIRECTED
BY MEDICAL PERSONNEL.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SAFELY STOP DISCHARGE. CONTAIN MATERIAL, AS
NECESSARY, WITH A DIKE OR BARRIER. STOP MATERIAL FROM CONTAMINATING SOIL OR
FROM ENTERING SEWER OR BODIES OF WATER. CONTAIN WITH ABSORBENT MATERIAL, SUCH
AS CLAY, SOIL OR ANY COMMERCIALLY AVAILABLE ABSORBENT. SHOVEL RECLAIMED DYE
& ABSORBENT INTO A RECOVERY OR SALVAGE DRUMS FOR DISPOSAL. APPROPRIATE
SAFETY MEASURES & PROTECTIVE EQUIPMENT SHOULD BE USED.
Neutralizing Agent: NO DATA PROVIDED BY MANUFACTURER
Waste Disposal Methods: DISPOSE OF I/A/W APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS . REPORTING: SPILLS OF THIS MATERIAL IN EXCESS OF A COMPONENT'S
RQ MUST BE REPORTED TO THE NATIONAL RESPONSE CENTER (1-800-424-8802) AN D THE
APPROPRIATE STATE AND LOCAL EMERGENCY RESPONSE ORGANIZATIONS. NOTE: PRODUCT
CONTAINS NO REGULA TED INGREDIENTS.
Handling And Storage Precautions: STORE IN A COOL, DRY, WELL-VENTILATED AREA
AWAY FROM HEAT, IGNITION SOURCES, AND DIRECT SUNLIGHT. ALWAYS KEEP CONTAINERS
TIGHTLY CLOSED. WARNING: HOT ORGANIC CHEMICAL VAPORS OR MISTS CAN SUDDENLY
& WI THOUT WARNING COMBUST WHEN MIXED WITH AIR.
Other Precautions: EVACUATION: ISOLATE HAZARD AREA. KEEP UNNECESSARY &
UNPROTECTED PERSONNEL FROM ENTERING AREA. ELIMINATE ALL SOURCES OF IGNITION.
EMPTY CONTAINERS CAN RETAIN PRODUCT RESIDUES. DO NOT REUSE EMPTY CONTAI NER
FOR FOOD, CLOTHING, OR PRODUCTS FOR HUMAN OR ANIMAL CONSUMPTION OR WHERE SKIN
CONTACT MAY OCCUR.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point: >204.4C, 400.F
Extinguishing Media: SMALL FIRES: USE DRY CHEMICAL, CARBON DIOXIDE, HALON,
WATER SPRAY, OR FOAM. LARGE FIRES: USE WATER SPRAY, FOG, OR ALCOHOL FOAM.
Fire Fighting Procedures: FIREFIGHTERS AND OTHERS WHO MAY BE EXPOSED TO THE
PRODUCTS OF COMBUSTION SHOULD BE EQUIPPED WITH NIOSH-APPROVED,
POSITIVE-PRESSURE, SELF-CONTAINED BREATHING APPARATUS (SCBA) AND FULL
PROTECTIVE CLOTHI NG.
Unusual Fire/Explosion Hazard: MAY LIBERATE IRRITATING OR TOXIC VAPORS DURING
COMBUSTION OR DECOMPOSITION. SMOKE, SOOT, AND TOXIC/IRRITATING FUMES (I.E.,
CARBON DIOXIDE, CARBON MONOXIDE, ETC.), OXIDES OF NITROGEN.
=======================================================
Control Measures
=======================================================
Respiratory Protection: AVOID BREATHING VAPOR &/OR MIST. IF OCCUPATIONAL
EXPOSURE LIMITS ARE EXCEEDED WEAR NIOSH/OSHA APPROVED EQUIPMENT. DETERMINE
THE APPROPRIATE TYPE BY CONSULTING THE RESPIRATOR MANUFACTURER. HIGH AIRBORN
E CONCENTRATIONS MAY NECESSITATE THE USE OF SCBA OR A SUPPLIED AIR
RESPIRATOR. RESPIRATORY PROTECTION PROGRAMS MUST BE IN COMPLIANCE WITH 29CFR
1910.134.
Ventilation: MAINTAIN AIRBORNE CONCENTRATIONS BELOW THE ESTABLISHED EXPOSURE
LIMITS BY PROVIDING ADEQUATE VENTILATION. (SEE SUPPLEMENTAL)
Other Protective Equipment: AN EYE WASH FACILITY. WEAR PROTECTIVE CLOTHING.
MANUFACTURER TO DETERMINE THE PROPER TYPE FOR SPECIFIC OPERATION.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING, ESPECIALLY BEFORE
EATING, DRINKING, SMOKING, OR USING RESTROOM FACILITIES. CONTAMINATED
CLOTHING & SHOES SHOULD BE THOROUGHLY CLEANED & DRIED BEFORE REUSE.
Supplemental Safety and Health: GENERAL (DILUTION) VENTILATION MAY BE
ACCEPTABLE, HOWEVER, LOCAL EXHAUST VENTILATION IS RECOMMENDED WHEN VAPORS,
MISTS, OR DUSTS CAN BE RELEASED. NOTE TO PHYSICIAN: TREATMENT SHOULD BE
DIRECTED AT PRE VENTING ABSORPTION, ADMINISTERING TO THE SYMPTOMS AS THEY
OCCUR, AND PROVIDING SUPPORTIVE THERAPY.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: V6
Boiling Point: >204.4C, 400.F
Vapor Pres: <0.01 MMHG@20C
Vapor Density: >1
Spec Gravity: 0.98
Solubility in Water: NOT SOLUBLE
Appearance and Odor: AMBER LIQUID; MILD ODOR.
Percent Volatiles by Volume: 0
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES.
Materials To Avoid: OXIDIZERS.
Hazardous Decomposition Products: COMBUSTION MAY PRODUCE CARBON DIOXIDE AND
CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: NO DATA ARE AVAILABLE ON THIS PRODUCT.
=======================================================
Ecological Information
=======================================================
Ecological: NO DATA ARE AVAILABLE ON THIS PRODUCT.
=======================================================
=======================================================
Transport Information: DOT SHIPPING NAME: NOT REGULATED.
=======================================================
Regulatory Information
=======================================================
Sara Title III Information: OZONE-DEPLETING CHEMICALS: NO REGULATED
INGREDIENTS.SECTION 302-EXTREMELY HAZARDOUS SUBSTANCES: NO REGULATED
INGREDIENTS.SECTION 311/312-HAZARD CATEGORIES: FIRE HAZRD: YES; SUDDEN
RELEASE OF PRESS URE HAZARD: NO; REACTIVITY HAZARD: NO; IMMEDIATE(ACUTE)
HEALTH HAZARD: YES; DELAYED (CHRONIC) HEALTH HAZARD: NO.
Federal Regulatory Information: TSCA: THE CHEMICAL COMPONENTS OF THIS PRODUCT
ARE CONTAINED ON THE SECTION 8(B) CHEMICAL SUBSTANCE INVENTORY LIST.
CERCLA: NO REGULATED INGREDIENTS.
State Regulatory Information: PENNSYLVANIA-NEW JERSEY R-T-K: FLUORESCENT DYE,
NJ TSRN 80100312-5002P, 40-60%; LUBRICANT OIL, NJ TSRN 80100312-5004P,
40-60%. CALIFORNIA- CALIFORNIA PROPOSITION 65 - NO REGULATED INGREDIENTS.
=======================================================
Other Information
=======================================================
Other Information: NO DATA PROVIDED BY MANUFACTURER
=======================================================
Transportation Information
=======================================================
Trans ID NO: 155956
Product ID: GS-3/E
Review Date: 02/14/2001
Net Unit Weight: UNKNOWN
Multiple KIT Number: 0
Unit Of Issue: BX
Container QTY: 0
Type Of Container: CAPSULE FORM
Additional Data: NOT REGULATED PER MSDS.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: GS-3/E
Cage: 20772
Company Name: SPECTRONICS CORP
Street: 956 BRUSH HOLLOW RD
PO Box: 483
Zipcode: 11590
Label Required IND: Y
Date Of Label Review: 02/14/2001
Status Code: A
Year Procured: 2001
Origination Code: F
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: N/P. EMERGENCY OVERVIEW: MAY CAUSE EYE,
SKIN AND RESPIRATORY SYSTEM IRRITATION. EYE: CAN CAUSE MILD IRRITATION. SKIN:
IRRITATION CAN OCCUR FOLLOWING PROLONGED OR REPEATED CONTACT. INHA LATION
(BREATHING): PROCCESING VAPORS CAN POSSIBLY CAUSE IRRITATION TO THE UPPER
RESPIRATORY TRACT. INGESTION (SWALLOWING): INGESTION CAN CAUSE
GASTROINTESTINAL IRRITATION.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TECHNI-SILVER E-2 BRIGHTENER
Preparer's Name:WILLIAM A. WILSON
CAGE:20816
CAGE:20816
============= Composition/Information on Ingredients =============
Ingred Name:SELENIUM DIOXIDE (SARA III)
CAS:7446-08-4
RTECS #:VS8575000
Fraction by Wt: 0.004%
OSHA PEL:0.2 MG SE/M3
ACGIH TLV:0.2 MG SE/M3
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Ingred Name:HYDRAZINE; (HYDRAZINE HYDRATE) (SARA III)
CAS:302-01-2
RTECS #:MU7175000
Fraction by Wt: 0.17%
OSHA PEL:S, 1 PPM
ACGIH TLV:S, 0.1 PPM, A2; 9293
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ETHANOL, 2,2',2"-NITRILOTRI-; (TRIETHANOLAMINE)
CAS:102-71-6
RTECS #:KL9275000
Fraction by Wt: 0.20%
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: HEALTH EFFECTS ARE MODERATE:
MAY CAUSE BOTH REVERSIBLE AND IRREVERSIBLE CHANGES, NOT SEVERE
ENOUGH TO CAUSE DEATH OR PERMANET INJURY. CHRONIC: MAY CAUSE DAMAGE
TO THE LIVER AND DESTRUCTION OF R ED BLOOD CELLS.
Explanation of Carcinogenicity:HYDRAZINE: GROUP 2B (IARC), GROUP 2
(NTP)
Effects of Overexposure:INHALATION: MAY CAUSE RESPIRATORY TRACT
IRRITATION, COUGH OR EDEMA OF THE LUNG. SKIN/EYES: MAY CAUSE
IRRITATION OR DERMATITIS. CAN BE ABSORBED THROUGH THE SKIN. INGEST:
MAY CAUSE VOMITING, DIARRHEA, C RAMPS, LOSS OF REFLEXES, CEREBRAL
IRRITATION (CONVULSIONS) AND POSSIBLY DEATH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH WITH WATER (UNDER LIDS) FOR AT LEAST 15 MIN.
CONSULT PHYSICIAN. SKIN: WASH THOROUGHLY WITH SOAP AND WATER. WASH
CONTAMINATED CLOTHING AFTER REMOVAL. IF IRRITATION DEVELOPS,
CONSULT PHYSICIA N. INHAL: REMOVE PATIENT TO FRESH AIR. IF
BREATHING IS DIFFICULT, ADMIN O2. IF BREATHING HAS STOPPED, ADMIN
ARTIFICIAL RESP. INGEST: INDUCE VOMITING AND CONSULT PHYSICIAN
IMMED.
===================== Fire Fighting Measures =====================
Flash Point:DOES NOT BURN
Extinguishing Media:DOES NOT BURN. EXTINGUISHING MEDIA SUITABLE FOR
SURROUNDING FIRE .
Fire Fighting Procedures:NONE. WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:ADD DRY ABSORBENT AND SHOVEL OR SWEEP UP AND
PLACE IN AN APPROVED DOT CONTAINER AND SEAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE (55-85 F).
KEEP CONTAINER CLOSED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IN A LARGE SPILL, WEAR NIOSH/MSHA APPROVED
BREATHING APPARATUS; OTHERWISE; IT IS NOT REQUIRED.
Ventilation:GENERAL EXHAUST.
Other Protective Equipment:RUBBER APRON IS OPTIONAL.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR SMOKING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:C2
Boiling Pt:B.P. Text:212F,100C
Solubility in Water:COMPLETE
Appearance and Odor:WATER WHITE TO LIGHT YELLOW SOLUTION; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Stability Condition to Avoid:EXCESS HEAT.
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: M/M FIX ALL, 5020
Cage: 0A649
Box: 152170
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 0A649
Box: 152170
Cage: 0A6H9
Box: 152170
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: LD50:(ORAL,RAT) >5 G/KG.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:EYES:CAUSES IRRIT W/STINGING, REDNESS & TEARING.
SKIN:MAY CAUSE IRRIT W/REDNESS & ITCH. INHAL:LIQ/VAP CAUSES IRRIT.
CHRONIC:EXCESSIVE INHAL OF VAP MAY CAUSE APPEAR OF BLOOD IN URINE. RPTD/PRLNG
INHAL MAY CAUSE LIVER ABNORMS, KIDNEY/LUNG DMG, SPLEEN DMG, BLOOD ABNORMS,
WT LOSS, ANOREXIA/TESTIS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:DMG. TARGET ORGANS:LIVER, KIDNEY,
LUNGS, BLOOD, SPLEEN, TESTES. ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFTS ON CNS, HEMATOPOIETIC TISS, BLOOD, KIDNEYS &
LIVER, ASSOC W/ADMINOF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE). (EXTRACTED
FROM DHHS (NIOSH) PUBLICATION NO.90-118) (FP N).
Medical Cond Aggravated By Exposure: MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
INCLUDE DISEASES & DISORDERS OF THE KIDNEYS, LIVER, LUNGS, SPLEEN, BLOOD
& TESTES.
First Aid: INHAL:REMOVE FROM AREA TO FRESH AIR. SEEK MED ATTN IF RESP IRRIT
DEVELOPS/IF BRTHG BECOMES DFCLT. EYE:IMMED RINSE W/WATER. REMOVE ANY CONT
LENSES & CONTINUE FLUSHING FOR AT LST 15 MINS. HOLD EYELIDS A PART TO
ENSURE RINSING OF ENTIRE SURF OF EYES & LIDS W/WATER. GET IMMED MED ATTN.
SKIN:WASH AFFECTED AREAS W/PLENTY OF SOAP & WATER FOR SEVERAL MINS.
REMOVE & CLEAN CONTAM CLTHG & SHOES. SEEK (SUPDAT)
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: AEROSOL PACKAGING, SO SPILL UNLIKELY. IF LEAK OCCURS,
WIPE UP RESIDUE & FLUSH AREA W/WATER.
Waste Disposal Methods: DISPOSE OF I/A/W ALL FEDERAL, STATE & LOCAL
REGULATIONS.
Handling And Storage Precautions: STORAGE TEMPERATURE: MAX - 120F; MIN - 32F.
STORE INDOORS. DO NOT USE OR STORE NEAR HEAT, HOT SURFACES, SPARKS OR OPEN
FLAME.
Other Precautions: READ THE ENTIRE LABEL BEFORE USING THIS PRODUCT. KEEP OUT OF
REACH OF CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NON-FLAMMABLE
Extinguishing Media: "ALCOHOL" FOAM, CO*2, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: DO NOT PUNCTURE OR INCINERATE AEROSOL CANS.
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE NIOSH/MSHA APPROVED ORGANIC RESPIRATOR IN EMERGENCY
SITUATIONS.
Ventilation: GOOD INDUSTRIAL HYGIENE PRACTICE DICTATES THAT WORK AREAS SHOULD
PROVIDE ADEQ VENT/CONTROLS TO MAINTAIN & MEET
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI
DESIGN CRITERIA (FP N). GENERAL WORK CLOTHES & PROTECTIVE SHOES.
Work Hygienic Practices: WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: NOTE:USERS OF "L" VERSION SHOULD CONSULT "LR"
VERSION FOR ADDNL INFO (FP N). FIRST AID PROC:MED ATTN IF IRRIT DEVELOPS.
INGEST:GIVE 3-4 GLASSES OF WATER, BUT DO NOT INDUCE VOMIT. IF VOMIT OCCURS,
GIVEFLUIDS AGAIN. GET IMMED MED ATTN IF DISCOMFORT OCCURS. NOTES TO
MD:ETHYLENE GLYCOL MONOBUTYL ETHER - ORGANIC
=======================================================
Physical/Chemical Properties
=======================================================
B.P. Text: 210F,99C
Vapor Pres: 20
Vapor Density: 0.6
Spec Gravity: 1.01 (H*2O=1)
PH: 12
Evaporation Rate & Reference: 0.1 (BUTYL ACETATE=1)
Solubility in Water: COMPLETE
Appearance and Odor: NON-VISCOUS, WHITE, OPAQUE; SWEET ODOR.
Percent Volatiles by Volume: 97
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: STRONG OXIDIZING AGENTS & STRONG ALKALIES. PREVENT CONTACT
W/ZINC, MAGNESIUM OR GALVANIZED METALS.
Hazardous Decomposition Products: OXIDES OF CARBON & OTHER UNIDENTIFIED ORGANIC
COMPOUNDS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: M/M FIX ALL, 5020
Cage: 0A649
Company Name: CERTIFIED LABS
Street: UNKNOWN
PO Box: 152170
Zipcode: 75015
Label Required IND: Y
Date Of Label Review: 03/27/1996
Status Code: C
Label Date: 03/27/1996
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:EYES:CAUSES IRRITATION WITH STINGING, REDNESS
& TEARING. SKIN:MAY CAUSE IRRITATION WITH REDNESS & ITCHING.
INHALATION:LIQUID OR VAPOR CAUSES IRRITATION. CHRONIC:ANIMAL STUDIES CLEARLY
DEMONSTRAT ED DOSE-RELATED ADVERSE EFFECTS ON THE CENTRAL NERVOUS SYSTEM,
BLOOD-FORMING TISSUES, BLOOD, KIDNEYS & LIVER, ASSOCIATED WITH
ADMINISTRATION OF ETHYLENE GLYCOL MONOBUTYL ETHER (FP N). EXCESSIVE INHALA
TION OF VAPOR MAY CAUSE APPEAR OF BLOOD IN URINE.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:IMP-EP-TURBINE OIL, MIL-L-17331H & AM-1, 2190 TEP
CAGE:58563
CAGE:58563
CAGE:4P459
============= Composition/Information on Ingredients =============
Ingred Name:LUBE OIL BASE STOCK
CAS:64741-88-4
RTECS #:PY8040501
> Wt:99.
Other REC Limits:NONE RECOMMENDED
Ingred Name:"PROPRIETARY" ADDITIVES(PER MSDS:LZ857, EXXON CHEM COREXIT
"C")
< Wt:1.
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Health Hazards Acute and Chronic:WHILE THIS PRODUCT MAY IRRITATE THE
SKIN FROM PROLONGED SKIN CONTACT, THERE IS NO MEDICAL OR
TOXICOLOGICAL EVIDENCE THAT IT'S AN IRRITANT, A CORROSIVE OR A
CARCINOGEN. IT HAS LOW ORDER OF ORAL/DERMAL TOXICITY. INHALATION
OF PRODUCT MIST MAY CAUSE PULMONARY PROBLEMS WHICH, AS WITH ANY
ILLNESS, IF LEFT UNATTENDED, SHOULD CAUSE PULMONARY INJURY.
Explanation of Carcinogenicity:NO AVAILABLE DATA. N
Effects of Overexposure:FROM HUMAN EXP. & THE AVAILABLE TECHNICAL DATA
CONCERNING THGIS PRODUCT & DUE TO ITS LOW ORDER OF DERMAL, ORAL &
INGESTIVE TOXICITY, THE SIGNS & SYMPTOMS OF OVER EXPOSURE ARE
UNKNOWN.
Medical Cond Aggravated by Exposure:DIRECT CONTACT W/EYES MAY CAUSE EYE
IRRITATION. PROLONGED SKIN CONTACT MAY CAUSE SKIN IRRITATION.
======================= First Aid Measures =======================
First Aid:IF SWALLOWED DO NOT INDUCE VOMIT. CALL PHYSICIAN IMMED. IF
SPLASHED INTO EYES PURGE WITH COPIOUS AMOUNTS OF WATER. IN CASE OF
SKIN CONTACT CLEANSE WITH WATERLESS SOAP FOLLOWED BY THOROUGH
WASHING WI TH SOAP & WATER.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=226.7C, 440.F
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:CARBON DIOXIDE, WATER FOG, FOAM OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR MESA/NIOSH APPROVED SELF-CONTAINED
BREATHING APPARATUS. USE WATER SPRAY TO COOL EXPOSED TANKS, DRUMS &
PERSONNEL.
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILLED MATL W/SAND/EARTH/CLAY/OTHER
SUITABLE DIKING MATERIAL. RECOVER FREE LIQUID BY PUMPING INTO
DRUMS/OTHER SUITABLE CONTAINERS. CLEAN AREA W/RAGS OR OTHER
ABSORBING MATERIALS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:THESE LUBRICANT BECOME VERY VISCOUS
WHEN STORED @LOW TEMPS. IT CONGEALS @-12C -32C. USE PRODUCT
W/CAUTION AROUND OPEN FLAMES/HEAT/SPARKS/PILOT LIGHTS/STATIC
ELECTRICITY.
Other Precautions:EMPTY CNTNR WARNING: EMPTY CNTNRS RETAIN
RESIDUE(LIQ/VAP)-DANGEROUS. DON'T PRESSURIZE/ CUT /WELD /BRAZE/
SOLDER/ DRILL/ EXPOSE CONTNRS TO HEAT/FLAME/SPARKS/OTHER SOURCES OF
IGNITION. DON'T ATTEMPT TOCLEAN-RESIDUE DIFFICUTL TO REMOVE.
EMPTY DRUMS (SEE SUPPLE)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE SUPPLIED-AIR RESPIRATORY PROTECTION IN
CONFINED OR ENCLOSED SPACES IF NEEDED.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:MINIMIZE BREATHING VAP/MIST/FUMES. REMOVE
CONTAMIN CLOTHING; LAUNDER/DRY CLEAN BEFORE REUSE. OIL SOAKED SHOES
SHOULD BE DISCARDED
Supplemental Safety and Health
OTHER PRECAUT:SHOULD BE COMPLETELY DRAINED/PROPERLY BUNGED/PROMPTLY
RETURENED TO DRUM RECONDITIONER. ALL OTHER CNTNRS SHOULD BE
DISPOSED OF IN ENVIRO SAFE MANNER & IAW LOCAL/STATE/FED REGS.
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:=600.C, 1112.F
Melt/Freeze Pt:M.P/F.P Text:0
Decomp Temp:Decomp Text:NP
Vapor Pres:1MM @20C
Vapor Density:1
Spec Gravity:1
pH:NP
Viscosity:NP
Evaporation Rate & Reference:1, (N-BUTYL ACETATE=1)
Solubility in Water:0
Appearance and Odor:AMBER COLOR, NO ODOR.
Percent Volatiles by Volume:NP
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
KEEP AWAY FROM STRONG ACIDS, ALKALIES & OXIDIZERS.
Stability Condition to Avoid:KEEP AWAY FROM EXTREME HEAT & OPEN FLAME.
Hazardous Decomposition Products:WHEN BURNING NITRIC ACID, CARBON
MONOXIDE, & DIOXIDE, DENSE CARBONACEOUS SMOKE.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN APPROVED EQUIPMENT OR LANDFILL
CONTAMIN DIKING MATERIAL ACCORDING TO CURRENT LOCAL, STATE &
FEDERAL REGULATIONS.THIS APPLIES TO UNRECOVERABLE LIQUID AS WELL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:OXALIC ACID
Preparer's Name:C.A. EISENHARD
CAGE:DO735
CAGE:60777
CAGE:DO735
CAGE:0AN91
============= Composition/Information on Ingredients =============
Ingred Name:OXALIC ACID
CAS:144-62-7
RTECS #:RO2450000
Fraction by Wt: >99.0%
OSHA PEL:1 MG/M3/2 STEL
ACGIH TLV:1 MG/M3/2 STEL; 9192
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50 (RAT) IS 375MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:**TOXIC--CORROSIVE**EYES:MAY CAUSE
IRRITATION.SKIN:MAY CAUSE IRRITATION AND BURNS.INGEST:JUST A FEW
GRAMS MAY BE FATAL.MAY CAUSE GI TRACT IRRITATION AND
BURNS.INHAL:MAY CAUSE RESPIRATORY IRRITATION.CH
RONIC:EMACIATION,WEAKNESS,DERMATITIS,DELAYED KIDNEY AND LIVER
DAMAGE.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:ULCERATIONS OF THE MUCOUS MEMBRANES OF THE NOSE
AND THROAT,HEADACHE,NERVIOUSNESS.PAIN IN THE BACK FROM PROLONGED
EXPOSURE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
LIVER,KIDNEY,SKIN AND RESPIRATORY AILMENTS MAY BE AT INCREASED RISK
FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH A SOLUTION OF
EPSOM SALTS.GET DOCTOR.EYES:FLUSH WITH WATER FOR 15
MINUTES.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL
RESPIRATION IF NEEDED.INGEST:D O NOT INDUCE VOMITING.GET PROMPT
QUALIFIED MEDICAL ATTENTION.IF CONSCIOUS,GIVE WATER,MILK OR SOLUBLE
CALCIUM OR MAGNESIUM
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:REMOVE ALL IGNITION SOURCES;VAPORS
DECOMPOSE TO HAZARDOUS PRODUCTS AT HIGH TEMPERATURES.WATER OR FOAM
MAY CAUSE FROTHING ON MOLTEN OXALIC ACID.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA.USE PROPER PROTECTIVE AND
RESPIRATORY EQUIPMENT.SWEEP OR VACUUM;DO NOT CREATE DUST;PLACE IN A
DRY CONTAINER FOR DISPOSAL.CLEAN SPILL AREA WITH WATER.AVOID
DISCHARGE INTO SEWER OR WATERW AYS.
Neutralizing Agent:SODA ASH
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA; KEEP AWAY FROM HEAT,OXIDIZERS AND INCOMPATIBLE MATERIALS.
Other Precautions:AVOID SKIN AND EYE CONTACT.DO NOT INHALE
VAPORS/MISTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR
A NOISH/MSHA APPROVED RESPIRATOR FOR ACID DUST,DEPENDING ON THE
AIRBORN CONCENTRATION.
Ventilation:USE LOCAL EXHAUST(FUME HOOD).
Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A
LOCAL EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:C2
Boiling Pt:=111.1C, 232.F
Melt/Freeze Pt:=100.6C, 213.F
Vapor Pres:NIL
Spec Gravity:1.65
Solubility in Water:MODERATE (9.5%)
Appearance and Odor:TRANSPARENT COLORLESS CRYSTALS(SMALL,PER
0-0-6908),ODORLESS.SUBLIMES AT 302F.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SILVER COMPOUNDS,ALKALIES,STRONG OXIDIZERS,OLEUM.
Stability Condition to Avoid:HEAT ABOVE 212F,SPARKS,AND OPEN
FLAMES,WATER.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE,FORMIC
ACID.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HOLIDAY HOUSEHOLD INSECT FOGGER (REGULAR), 02475
Preparer's Name:GENE F. TAPPAN
CAGE:71112
CAGE:71112
CAGE:90994
============= Composition/Information on Ingredients =============
Ingred Name:BENZENEACETIC ACID, 4-CHLORO-ALPHA-(1-METHYLETHYL)-,
CYANO(3-PHENOXYPHENYL) METHYL ESTER; (FENVALERATE)
CAS:51630-58-1
RTECS #:CY1576350
Fraction by Wt: 80%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TOLUENE, ALPHA-(2-(2-BUTOXYETHOXY)ETHOXY)-4,
5-(METHYLENEDIOXY)-2-PROPYL-; (PIPERONYL BUTOXIDE)
CAS:51-03-6
RTECS #:XS8050000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:5-NORBORNENE-2, 3-DICRABOXIMIDE, N-(2-ETHYLHEXYL)-;
(MGK-264)
CAS:463-04-7
RTECS #:RB8575000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ETHANE, 1,1,1-TRICHLORO-; (METHYL CHLOROFORM)
(1,1,1-TRICHLOROETHANE)
CAS:71-55-6
RTECS #:KJ2975000
OSHA PEL:350 PPM;450 STEL
ACGIH TLV:350 PPM;450 STEL
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ozone Depleting Chemical:1
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:SUPDAT:IN LAB ANIMALS & COULD HAVE SIMILAR EFT IN HUMANS.
ADRENOMIMETICS (E.G.EPINEPHRINE) MAY BE CONTRAINDICATED(ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6:EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR
CHRONICALLY EXPOSED TO CHLOROCARBONS .
RTECS #:9999999ZZ
Ingred Name:OTHER PREC:WASHED BEFORE USE. REMOVE PETS & COVER FISH
AQUARIUMS & DELICATE PLANTS BEFORE SPRAYING. REMOVE ALL (ING 9)
RTECS #:9999999ZZ
Ingred Name:ING 8:MOTOR VEHICLES BEFORE USING IN GARAGES. IN COMMERCIAL
FOOD-HNDLG FACILITIES, COVER/REMOVE ANY FOOD & FOOD-(ING 10)
RTECS #:9999999ZZ
Ingred Name:ING 9:PROCESSING EQUIP DURING APPLICATION. DO NOT APPLY
WHILE FOOD PROCESSING IS UNDERWAY. AFTER SPACE SPRAYING (ING 11)
RTECS #:9999999ZZ
Ingred Name:ING 10:IN BAKERIES/OTHER FOOD-PROCESSING PLANTS, WASH
W/POTABLE WATER ALL EQUIP, BENCHES, SHELVING, WHERE EXPOS (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:FOOD WILL BE HNDLD. NO SMOKING IN AREA OF USE. DO
NOT USE IN GEN VICIN OF ARC WELDING, OPEN FLAMES/HOT (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:SURFACES. HEAT &/OR UV RADIATION MAY CAUSE THE
FORMATION OF HCL &/OR PHOSGENE .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INGEST:NOT ORALLY TOX. SKIN:NOT
PRIMARY IRRIT. EYE:NOT IRRIT. INHAL:NOT TOX. HLTH EFTS ASSOC
W/EXPOS TO INDIVIDUAL INGS IN UNDILUTED FORMS ARE DISCUSSED BELOW.
NOTE:THIS INFO CONCERNS HLTH EFTS ASSOC W/PROD INGS IN THEIR
UNDILUTED STATE, AT HIGHER CONC LEVELS THAN WOULD BE DERIVED FROM
NORMAL USE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:OF FINISHED PROD I/A/W LBL DIRECTIONS.
ING 3:MAY CAUSE SKIN IRRIT. BRTHG EXCESS VAP CONCS MAY ELICIT RESP
IRRIT, NAUS & HDCHS. LONG-TERM SYSTEMIC HLTH EFTS UNKNOWN. ING
4:EXPOS TO EXCESSIVE V APS CAN IRRIT NOSE, THROAT & LUNGS & CAUSE
CNS EFTS INCL DIZZ, WEAK, FATG, NAUS, HDCH & UNCON. CHRONIC OVEREXP
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD/POISON CONTROL CENTER IMMEDIATELY. DO NOT
INDUCE VOMITING. NOTE TO MD:MAY PRESENT ASPIRATION HAZARD.
SKIN:REMOVE CONTAMINATED CLOTHING & WASH AFFECTED AREAS W/SOAP &
WATER. OBTAIN MEDIC AL ATTENTION IF IRRITATION OCCURS. EYE:FLUSH
W/WATER. REMOVE CONTACT LENSES. CONTINUE FLUSHING FOR AT LST 15
MINS. CALL MD IMMEDIATELY. INHAL:REMOVE VICTIM TO FRESH AIR. APPLY
ARTF RESP IF INDICATED.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO*2, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CONTENTS UNDER PRESSURE. FLAME EXTENSION:
0-3 INCHES. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE HCL &
PHOSGENE .
================== Accidental Release Measures ==================
Spill Release Procedures:SOAK UP W/ABSORBENT MATERIAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP OUT OF REACH OF CHILDREN. DO NOT
USE/STORE NEAR HEAT/OPEN FLAME. EXPOS TO TEMPS >130F MAY CAUSE
BURSTING. AVOID BRTHG VAPS/SPRAY MIST.
Other Precautions:DO NOT OPERATE CLOTHES DRYER WHILE FOGGING. HARMFUL
IF SWALLOWED/ABSORBED THRU SKIN. AVOID CONT W/SKIN & EYES. DO NOT
APPLY DIRECTLY TO FOOD IN HOME, ALL FOOD-PROCESSING SURFS &
UTENSILS SHOULD BE COV ERED DURING TREATMENT/THORO (ING 8)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE.
Other Protective Equipment:NONE REQUIRED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VP:PRESS IN CAN:48 PSIG @ 70F. EFTS OF OVEREXP:MAY CAUSE CARDIAC ABNORM
& DMG TO LUNGS, LIVER & KIDNEYS. ING 5:SIMPLE ASPHY WHICH MAY CAUSE
CNS DEPRESS & CARDIAC SENSIT AT HIGH CONCS. CONTINUED EXPOX AT
HIGH LEVELS MAY RSLT IN UNCON, COMA & DEATH. CHLOROCARBON MATLS
HAVE PRDCD SENSIT OF MYOCARDIUM TO EPINEPHRINE(ING 6)
================== Physical/Chemical Properties ==================
Vapor Pres:SUPP DATA
Spec Gravity:1.3 (CONC)
Solubility in Water:INSOLUBLE
Appearance and Odor:AEROSOL SPRAY; CHARACTERISTIC CHLORINATED SOLVENT
ODOR.
Percent Volatiles by Volume:>95
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MAY SOFTEN SOME ASPHALT OR N-WAX FLOORS.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:HCL, PHOSGENE .
==================== Disposal Considerations ====================
Waste Disposal Methods:WRAP CONTAINER & PUT IN TRASH COLLECTION. LARGE
QUANTITY DISPOSAL: DEGAS CANS & COLLECT LIQUID CONTENTS. TRANSPORT
TO SECURE LANDFILL, APPROVED INCINERATOR OR OTHER FACILITY IN
ACCORD W/FEDERAL, STATE & LOCAL LAW.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DA-6270 STYLENE
Preparer's Name:RICK LOWE
CAGE:64557
CAGE:64557
============= Composition/Information on Ingredients =============
Ingred Name:STODDARD SOLVENT; (MINERAL SPIRITS)
CAS:8052-41-3
RTECS #:WJ8925000
Fraction by Wt: 15%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
Ingred Name:ACETONE (SARA III)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 15%
OSHA PEL:750 PPM;1000 STEL
ACGIH TLV:750 PPM;1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:NAPHTHA, LIGHT AROMATIC; (AROMATIC PETROLEUM DISTILLATES)
CAS:64742-95-6
Fraction by Wt: <5%
OSHA PEL:100 PPM
ACGIH TLV:100 PPM
Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 25%
OSHA PEL:500 PPM;1000 PPM, C
ACGIH TLV:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE)
CAS:75-28-5
RTECS #:TZ4300000
Fraction by Wt: 15%
Ingred Name:PROPANE
CAS:74-98-6
RTECS #:TX2275000
Fraction by Wt: 15%
OSHA PEL:1000 PPM
ACGIH TLV:SIMPLE ASPHYXIANT
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCD SENSIT
OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE SIM EFT IN
HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED
EXCEPT FOR LIFE-SUSTAINING US ES IN HUMANS ACUTELY/CHRONICALLY
EXPOSED TO CHLOROCARBONS . ACUTE & CHRONIC:INHAL:ANESTHETIC IN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:GP 2B (IARC
SUP7,P194,'87), ANTIC TO BE CARCIN (NTP 6TH ANN RPT, '91).
Effects of Overexposure:HLTH HAZ:CONFINED AREAS WHERE VAPORS ARE HIGH
CONCENTRATION. IRRITANT TO UPPER RESP SYSTEM. MAY RESULT IN LT
HEAD, STAG GAIT, GIDD & POSSIBLE NAUSEA. SKIN:IRRITANT.
INGEST:HARMFUL/FATAL IF SWALLOWED.
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING SKIN, EYES,
UPPER RESPIRATORY CONDITIONS.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. EYES:FLUSH W/WATER FOR AT LEAST 15
MINUTES. SKIN:WASH W/SOAP & WATER. INGEST:CALL MD IMMEDIATELY. DO
NOT INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:SUPP DATA
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA
& FULL PROTECTIVE EQUIPMENT . WATER MAY BE INEFFECTIVE. WATER MAY
BE USED TO KEEP FIRE EXPOSED CNTNRS COOL.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCL HCL &
PHOSGENE . DO NOT SPRAY NEAR OPEN FLAME - KEEP AT ROOM TEMP AS
EXPOS TO DIRECT SUNLIGHT/OTHER HEAT MAY CAUSE BURSTING.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL SOURCES OF IGNTION. VENTILATE -
AVOID BREATHING VAPORS & REMOVE W/INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE >120F. KEEP AT ROOM TEMP
AS EXPOS TO DIRECT SUNLIGHT/HEAT MAY CAUSE BURSTING. KEEP AWAY FROM
CHILDREN. DO NOT PUNCTURE/INCIN.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF HCL AND/OR PHOSGENE . DO
NOT SPRAY NEAR FIRE OR OPEN FLAME.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . AVOID BREATHING OF VAPOR OR SPRAY MIST.
Ventilation:LOCAL EXHAUST: YES. MECHANICAL (GENERAL): AS NEEDED.
Other Protective Equipment:NONE
Work Hygienic Practices:NORMAL WORK/HYGIENIC PRACTICES APPLY.
Supplemental Safety and Health
BP:-0.0F,-18C (PROPELLANT). FL PT:20F,-6.7C (PROPELLANT).
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:SUPP DATA
Vapor Pres:55+/-PSIG
Vapor Density:>1
Evaporation Rate & Reference:FASTER/ETHER (ETHER=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:GREYISH-BLACK LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:DO NOT STORE >120F.
Hazardous Decomposition Products:BY OPEN FLAME - CARBON MONOXIDE,
CARBON DIOXIDE, HYDROGEN CHLORIDE & PHOSGENE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT INCINERATE. DISPOSE I/A/W FEDERAL, STATE
& LOCAL REGULATIONS REGARDING POLLUTION.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:39-80055-044 PART B
Kit Part:Y
CAGE:0KDPZ
CAGE:0KDPZ
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Health Hazards Acute and Chronic:MAY CAUSE INJURY TO SKIN FOLLOWING
PROLONGED OR REPEATED CONTACT AND MAY CAUSE SKIN SENSITIZATION OR
OTHER ALLERGIC RESPONSES. SPI CLASS 3.
======================= First Aid Measures =======================
First Aid:AVOID INHALATION OF VAPOR. USE GOOD VENTILATION, PARTICULARLY
IF HEATED OR SPRAYED. PREVENT CONTACT WITH SKIN. IF CONTACT OCCURS,
WASH IMMEDIATELY WITH SOAP AND WATER. IF IRRITATION OCCURS, REMOVE
IND IVIDUAL FROM FURTHER CONTACT WITH MATERIAL.
===================== Fire Fighting Measures =====================
Flash Point:180F,82C
Extinguishing Media:CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP UP EXCESS AND REMOVE. RESIDUAL CAN BE
REMOVED WITH NONFLAMMABLE SOLVENT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED ORGANIC VAPOR RESPIRATOR.
Ventilation:LOCAL & MECHANICAL EXHAUST.
Other Protective Equipment:SAFETY SHOWER AND EYE WASH FACILITIES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:1.01
Appearance and Odor:CLEAR LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
EPOXY RESINS UNDER UNCONTROLLED CONDITIONS, STRONG ACIDS.
Stability Condition to Avoid:STORAGE AT ELEVATED TEMPERATURES OVER LONG
PERIODS OF TIME.
Hazardous Decomposition Products:TOXIC FUMES AT DECOMPOSITION
TEMPERATURES.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN ACCORDANCE WITH LOCAL POLLUTION
REGULATIONS AND ORDINANCES.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HYDROCHLORIC ACID
CAGE:DO667
CAGE:97854
CAGE:60777
CAGE:DO667
CAGE:3P400
============= Composition/Information on Ingredients =============
Ingred Name:HYDROGEN CHLORIDE (HYDROCHLORIC ACID) (SARA III)
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 35.21%
OSHA PEL:C 5 PPM
ACGIH TLV:C 5 PPM; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: BALANCE
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 ORAL RABBIT IS 900MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:SEVERE AND PAINFUL BURNS ON
CONTACT, EYE DAMAGE,SKIN BURS,IRRITATION TO MUCOUS
MEMBRANES;RESPIRATORY IRRITATION. CHRONIC:TISSUE DAMAGE.
Explanation of Carcinogenicity:HYDROCHLORIC ACID IS CLASSIFIED
IARC-3(INSUFFICIENT EVIDENCE-HUMAN).
Effects of Overexposure:CAN CAUSE SEVERE BURNS TO SKIN & EYES,
IRRITATING RESPIRATORY TRACT
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN AND
RESPIRATORY AILMENTS MAY BE AT INCREASED RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND
WATER.GET MEDICAL ATTENTION.EYES:FLUSH WITH WATER FOR 15
MINUTES.GET MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN
OR ARTIFICIAL RESPIRAT ION IF NEEDED.GET MEDICAL
ATTENTION.INGEST:DO NOT INDUCE VOMITING.GET PROMPT QUALIFIED
MEDICAL ATTENTION.IF CONSCIOUS,GIVE WATER OR MILK OR MAGNESIA.
===================== Fire Fighting Measures =====================
Flash Point:NON-FLAMMABLE
Extinguishing Media:SODA ASH, FLAKED LIME, CARBON DIOXIDE, WATER,
CARBON DIOXIDE
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA IN AN ENCLOSED
AREA.
Unusual Fire/Explosion Hazard:REACTS WITH MANY METALS & EVOLVES
HYDROGEN WHICH CAN EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:FLOOD WITH WATER & SODA ASH;FORM A SLURRY;SOAK
UP WITH AN INERT NON-COMBUSTIBLE ABSORBANT;PLACE IN A DOT APPROVED
CONTAINER FOR DISPOSAL.
Neutralizing Agent:SODA ASH,SLAKED LIME.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN WELL VENTILATED AREA, AWAY
FROM HIGHLY FLAMMABLE SUBSTANCES DO NOT STORE NEAR HEATING DEVICES
OR DIRECT SUNLIGHT
Other Precautions:FOLLOW LABEL DIRECTIONS.AVOID BREATHING VAPORS.AVOID
SKIN AND EYE CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE EITHER A SELF-CONTAINED BREATHING APPARATUS OR
A NIOSH/MSHA APPROVED RESPIRATOR FOR ACID GAS,DEPENDING ON THE
AIRBORN CONCENTRATION.
Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Other Protective Equipment:ACID RESISTANT BOOTS & APRON
Work Hygienic Practices:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A LOCAL
EYE WASH STATION AND SAFETY SHOWER.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:230F,110C
Melt/Freeze Pt:M.P/F.P Text:-51F,-46C
Vapor Pres:73
Spec Gravity:1.1700
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS TO SLIGHT YELLOW LIQUID WITH A
SHARP, PUNGENT, IRRITATING ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
METALS & METAL OXIDES
Stability Condition to Avoid:HIGH HEAT.
Hazardous Decomposition Products:HYDROGEN GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:2A0-6080 PLASTI-GRIT TYPE II HARD (50 LB BAG)
CAGE:98231
CAGE:98231
============= Composition/Information on Ingredients =============
Ingred Name:UREA, POLYMER W/FORMALDEHYDE
CAS:9011-05-6
RTECS #:YU1610000
Fraction by Wt: 99.5%
Ingred Name:STEARAMIDOPROPYLDIMETHYL-BETA-HYDROXYETHYL AMMONIUM NITRATE
(QUATERNARY AMMONIUM COMPOUND)
CAS:2764-13-8
Fraction by Wt: <0.5%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION. INHALATION:
RESPIRATORY TRACT IRRITATION. INGESTION: HARMFUL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY
TRACT IRRITATION. INGESTION: HARMFUL.
======================= First Aid Measures =======================
First Aid:SKIN: WASH THOROUGHLY W/SOAP & WATER. EYES: FLUSH W/WATER FOR
15 MINS. INHALATION: REMOVE TO FRESH AIR. INGESTION: INDUCE
VOMITING BY GIVING TWO GLASSES OF WATER. OBTAIN MEDICAL ATTENTION
IN ALL CASES .
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:32F
Extinguishing Media:FOAM, DRY CHEMICAL, CO2, WATER, STEAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL
PROTECTIVE CLOTHING. WEAR A FULL FACE PIECE.
Unusual Fire/Explosion Hazard:POWDER FORMS EXPLOSIVE MIXTURE W/AIR.
SEALED (CLOSED) CONTAINERS CAN BUILD UP PRESSURE IF EXPOSED TO HEAT
(FIRE).
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP & PLACE IN APPROPRIATE DISPOSAL
CONTAINER. USE PROPER SAFETY EQUIPMENT.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED, PROPERLY LABELED
CONTAINERS IN COOL VENTILATED AREA. KEEP AWAY FROM HEAT, OPEN
FLAMES, & OXIDIZING AGENTS.
Other Precautions:DON'T TRANSFER TO UNMARKED CONTAINERS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR AN APPROVED NIOSH/MSHA PROPERLY FITTED DUST
RESPIRATOR.
Ventilation:PROVIDE MECHANICAL/LOCAL EXHAUST VENTILATION TO KEEP <TLV.
Other Protective Equipment:FACESHIELD, PROTECTIVE RUBBER APRON, SHOES
OR BOOTS
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, SMOKING, OR
APPLYING COSMETICS. REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
THE UREA FORMALDEHYDE RESIN IS THERMOSET TO FORM A HARD INERT PLASTIC.
THERE IS NO RESIDUAL RESIN.
================== Physical/Chemical Properties ==================
Spec Gravity:1.5
pH:4-8
Solubility in Water:INSOLUBLE
Appearance and Odor:GRANULAR, NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS
Stability Condition to Avoid:IGNITION SOURCES SUCH AS OPEN FLAMES &
EXCESSIVE HEAT
Hazardous Decomposition Products:CO, CO2, SMOKE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN A SANITARY LANDFILL IN ACCORDANCE
W/LOCAL, STATE, & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:RHODORSIL FLUID 47 V 100 THROUGH 2500000,VV-D-1078 B
CAGE:LO044
CAGE:LO044
Contract Num:SP0450-00-M-C011
CAGE:2B613
============= Composition/Information on Ingredients =============
Ingred Name:POLY (DIMETHYLSILOXANE)
CAS:63148-62-9
RTECS #:JJ6484500
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) > 5000 MG/KG
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:NOT PROVIDED. ACUTE-
EYE:MAY CAUSE FOREIGN BODY IRRITATION ONLY. SKIN:NON-IRRITATING.
LOW ACUTE DERMAL TOXICITY. INHALE:NOT LIKELY. ORAL:EXPECTED TO BE A
LOW INGESTION HAZARD. CHRONIC- T HIS PRODUCT DOES NOT CONTAIN ANY
INGREDIENT DESIGNED BY IARC, NTP OR OSHA AS PROBABLE OR SUSPECTED
HUMAN CARCINOGENS.
Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY
INGREDIENT DESIGNED BY IARC, NTP OR OSHA AS PROBABLE OR SUSPECTED
HUMAN CARCINOGENS.
Effects of Overexposure:EYE IRRITATION
======================= First Aid Measures =======================
First Aid:EYE CONTACT: IN CASE OF EYE CONTACT, IMMEDIATELY ABSORB
EXCESS WITH CLEAN ABSORBENT CLOTH OR COTTON. THEN HOLD EYELIDS OPEN
AND FLUSH WITH GENTLE STREAM OF WATER FOR AT LEAST 15 MINUTES.
SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS OR PERSISTS. SKIN
CONTACT: WIPE EXCESS OFF WITH A DRY CLOTH; THEN WASH SKIN WITH SOAP
AND WATER. SEEK MEDICAL ATTENTION IF IRRITATION DEVELOPS, OR
PERSISTS. INHALATIO N: INHALATION IS NOT AN EXPECTED ROUTE OF
EXPOSURE. IF RESPIRATORY IRRITATION OCCURS REMOVE TO FRESH AIR. GET
MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, GIVE 1-2 GLASSES OF
WATER TO DRINK. SEEK MEDIC AL ATTENTION. DO NOT LEAVE VICTIM.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:=300.C, 572.F
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. COOL CONTAINERS EXPOSED TO FIRE
WITH WATER.
Unusual Fire/Explosion Hazard:WILL BURN UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. PICK UP SPILL WITH
INERT ABSORBENT SUCH AS SAND OR VERMICULITE. SCRAP UP AND PLACE IN
APPROPRIATE CLOSED CONTAINER FOR DISPOSAL. FLOOR IS SLIPPERY. WASH
SPILL AREA THOROUGHL Y TO REMOVE RESIDUAL CONTAMINATION.
Neutralizing Agent:NOT RELEVANT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BETWEEN 41F-77F. KEEP CONTAINER
TIGHTLY CLOSED.
Other Precautions:DO NOT GET IN EYES, ON SKIN OR ON CLOTHING. WASH
THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. KEEP OUT
OF REACH OF CHILDREN. DO NOT INGEST. AT HIGH TEMPERATURES, PRODUCT
FORMS FORMALDEHYDEWHICH IS A POTENTIAL CANCER HAZARD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SELECT NIOSH/MSHA APPROVED EQUIPMENT USED ON
ACTUAL OR POTENTIAL AIRBORNE CONCENTRATIONS AND IN ACCORDANCE WITH
THE APPROPRIATE REGULATORY STANDARDS AND/OR INDUSTRIAL
RECOMMENDATIONS.
Ventilation:GENERAL AREA DILUTION/EXHAUST VENTILATION.
Other Protective Equipment:SKIN CONTTACT SHOULD BE MINIMIZED THROUGH
PANTS).CONSIDERATION MUST BE GIVEN BOTH TO DURABILITY AS WELL AS
PERMEATION RESISTANCE.
Work Hygienic Practices:DONOT STORE,USE,AND/OR CONSUME
FOOD,BEVERAGE,TOBACCOPRODUCTS,OR COSMETICS WHERE MATERIAL IS
STORED.WASH HANDS AND FACE CAREFULLY BEFORE EATING,DRINKING,USING
TOBACCO,APPLYING COSMETICS,OR USING TOILET.*
Supplemental Safety and Health
* WASH EXPOSED SKIN PROMPTLY TO REMOVE ACCIDENTAL SPLASHES OF CONTACT
WITH THIS MATERIAL.
================== Physical/Chemical Properties ==================
HCC:V6
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:<-54.C, -65.2F
Vapor Pres:<0.01@392F
Spec Gravity:>0.96
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, VISCOUS LIQUID - ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS, STRONG BASES
Stability Condition to Avoid:HEAT, FLAMES, SPARKS
Hazardous Decomposition Products:DIMETHYLCYCSILOXANES,
METHYLPHENYLCYCLOSILOXANES, FORMALDEHYDE
=================== Toxicological Information===================
Toxicological Information:LD50 (ORAL, RAT) > 5,000 MG/KG
===================== Ecological Information =====================
Ecological:NO DATA FOUND.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO FEDERAL, STATE OR LOCAL LAWS.
===================== Regulatory Information =====================
Federal Regulatory Information:ALL INGREDIENTS ARE ON TSCA INVENTORY.
State Regulatory Information:PROPOSITION 65: NONE
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:GASKET
CAGE:72433
CAGE:72433
CAGE:93591
============= Composition/Information on Ingredients =============
Ingred Name:ASBESTOS, CHRYSOTILE
CAS:12001-29-5
RTECS #:CI6478500
Fraction by Wt: <20%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:2 FIBERS/CC; A1;9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE- NONE UNDER NORMAL CONDITIONS OF
USE. HOWEVER, GRINDING, SANDING OR MACHINING MAY PRODUCE NUISANCE
PARTICULATES THAT CAN CAUSE IRRITATION OF EYES, SKIN AND
RESPIRATORY PASSAGES. CHRONIC- LONG TE RM EXPOSURE TO ASBESTOS CAN
CAUSE IRREVERSIBLE ASBESTOSIS, LUNG DISEASE, LUNG CANCER.
Explanation of Carcinogenicity:ASBESTOS IS REGULATED BY OSHA AS A
CARCINOGEN.
Effects of Overexposure:NONE UNDER NORMAL CONDITIONS OF USE. HOWEVER,
GRINDING, SANDING OR MACHINING MAY PRODUCE NUISANCE PARTICULATES
THAT CAN CAUSE IRRITATION OF EYES, SKIN AND RESPIRATORY PASSAGES.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS SUCH AS DERMATITIS, RESPIRATORY PROBLEMS, LUNG DISEASE OR
ANY CONDITION THAT MAY BE AGGRAVATED BY NUISANCE DUST OR FIBERS.
======================= First Aid Measures =======================
First Aid:SEEK MEDICAL ATTENTION IF SYMPTOMS DEVELOP. IN CASE OF EYE
IRRITATION GENTLY RINSE WITH WATER FOR 15 MINUTES WHILE KEEPING
EYELIDS OPEN. SKIN: WASH FREQUENTLY WITH SOAP AND WATER.
INHALATION: REMOVE T O FRESH AIR. INGESTION: UNLIKELY.
===================== Fire Fighting Measures =====================
Flash Point:NON FLAMMABLE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS, IF NEEDED.
Unusual Fire/Explosion Hazard:ASBESTOS FIBERS MAY BE RELEASED IN A
FIRE.
================== Accidental Release Measures ==================
Spill Release Procedures:TREAT DUST AS FREE ASBESTOS. DO NOT DRY SWEEP
OR USE COMPRESSED AIR. WET METHOD SHOULD BE USED FOR EXTRACTION OF
DUST AND DEBRIS. HIGH EFFICIENCY PARTICULATE APPARATUS (HEPA)
VACUUMS SHOULD BE USED.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE- AVOID CREATING DUST BY
SANDING OR GRINDING THE PRODUCT.
Other Precautions:USE IN WELL VENTILATED AREA. AVOID BREATHING DUST OR
FIBERS. MINIMIZE CONTACT WITH SKIN. AVOID CONTACT WITH EYES. DO NOT
RAISE DUST. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR
DRINKING. KEEP AWAY FROM REACH OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED HIGH EFFICIENCY FIBERS/FUMES
RESPIRATOR WHEN AIRBORNE FIBER CONCENTRATIONS EXCEED THE PEL.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV. CHECK LOCAL REGULATIONS
FOR EMISSION STANDARDS.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER, WORK
CLOTHING AND APRON AS REQUIRED. DO NOT WEAR CONTACT LENSES
Work Hygienic Practices:DON'T TAKE PROTECTIVE GEAR/CLOTHING HOME IF
EXPOSED TO DUST. DON'T SHAKE. DON'T EAT IN AREA WHERE ASBESTOS/DUST
PRESENT.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:T6
Spec Gravity:2.5
Solubility in Water:NEGLIGIBLE
Appearance and Odor:SOLID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:FIRE
Hazardous Decomposition Products:ASBESTOS FIBERS MAY BE RELEASED IN A
FIRE.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTE SHOULD BE CONTAINED IN IMPERMEABLE BAGS,
LABELED AND DISPOSED IN ACCORDANCE WITH ALL LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:809 1464 C DEVELOPER, GREEN
CAGE:19139
CAGE:19139
CAGE:5K871
============= Composition/Information on Ingredients =============
Ingred Name:GREEN PHTHALOCYANINE PIGMENT MFR GIVES CAS AS 14302-13-7
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:STRONTIUM FERRITE
CAS:12023-91-5
Fraction by Wt: 85-90%
Other REC Limits:NONE RECOMMENDED
Ingred Name:STYRENE BUTYLACRYLATE COPOLYMER
CAS:60806-47-5
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT GIVEN
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPECTED TO BE A LOW INHALATION HAZARD
FOR RECOMMENDED HANDLING. MAY CAUSE TRANSIENT EYE IRRITATION. LOW
SKIN CONTACT HAZARD FOR RECOMMENDED HANDLING. EXPECTED TO BE A LOW
INGESTION HAZARD.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMEEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:COMBUSTIBLESOLID
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR
SURROUNDING FIRE.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:DO NOT USE A VACUUM CLEANER TO CLEAN UP
SPILLS OF POWDERED TONERS. THE VERY FINE PARTICLES CAN CAUSE A FIRE
OR EXPLOSION. SWEEP MATERIAL ONTO PAPER AND PLACE IN A FIBER
CARTON.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATHING DUST. USE WITH
ADEQUATE VENTILATION. KEEP CONTAINER CLOSED. KEEP FROM CONTACT WITH
OXIDIZING MATERIALS. MINIMIZE DUST GENERATION.
Other Precautions:MINIMIZE DUST ACCUMULATION. REFER TO NFPA PAMPHLET
NO. 654, "PREVENTION OF FIRE AND DUST EXPLOSIONS IN THECHEMICAL,
DYE, PHARMACEUTICAL, AND PLASTICS INDUSTRIES."
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD GENERAL VENTILATION, TYPICALLY 10 AIR CHANGES PER
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NEGLIGIBLE
Vapor Density:NEGLIGIBLE
Spec Gravity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GREEN POWDER, SLIGHT ODOR
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE WITH COMMON MATERIALS AND CONTAMINANTS WITH WHICH THE MATERIAL MAY
REASONABLY COME INTO CONTACT.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:CAN BE INCINERATED WHEN IN COMPLIANCE WITH LOCAL
REGULATIONS. CONTRACT WITH A LICENSED CHEMICAL DISPOSAL AGENCY.
DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT TO NATIONAL, STATE
OR LOCAL LAWS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:04652/04653 METHOTREXATE PARENTERAL LOW SODIUM 500MG/1G/VIAL
CAGE:04543
CAGE:04543
============= Composition/Information on Ingredients =============
Ingred Name:METHOTREXATE (IARC - GROUP 3)*95-1*
CAS:59-05-2
RTECS #:MA1225000
Fraction by Wt: 100%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL LD50(RAT): 180-320 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:METHOTREXATE- DEPRESSION OF BONE
MARROW FUNCTION,LEUKOPENIA,THROMBOCYTOPENIA,GI BLEEDING,LIVER
DAMAGE,EFFECTS ON FERTILITY,MENSTRUAL DYSFUNCTION,HEMATOLOGIC
CHANGES,SUPPRESSION OF IMMUNE SYSTEM,INDUCE D LUNG
DISEASE,CHROMOSOMAL CHANGES,ABNORMAL FETAL
DEVELOPMENT,ABORTIONS,MALFORMATIONS. (SEE SUPP)
Explanation of Carcinogenicity:NONE
Effects of Overexposure:GI DISTURBANCES, NAUSEA, VOMITING, LOSS OF
APETITIE, DIARRHEA, CONGESTION OF THE LUNGS, COUGH
Medical Cond Aggravated by Exposure:PRE-EXISTING KIDNEY FUNCTION
IMPAIRMENT.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/PLENTY OF COOL WATER FOR 20 MINS. SKIN: WASH
W/SOAP & COOL RUNNING WATER. INHALATION: REMOVE TO FRESH AIR. GIVE
CPR/OXYGEN IF NEEDED. INGESTION: INDUCE VOMITING IMMEDIATELY AS
DIRECTED B Y MEDICAL PERSONNEL. NEVER INDUCE VOMITING/GIVE ANYTHING
BY MOUTH IF UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
NOTE TO PHYSICIAN: CALCIUM LEUCOVORIN IS A POTENT NEUTRALIZER OF
METHOTREXATE.
===================== Fire Fighting Measures =====================
Unusual Fire/Explosion Hazard:METHOTREXATE DUST IS A CLASS 0 DUST
EXPLOSION HAZARD.
================== Accidental Release Measures ==================
APPROVED SELF-CONTAINED RESPIRATOR/A SUPPLIED AIR RESPIRATOR,
CONTAIN & COLLECT MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:MINIMIZES EXCESSIVE HANDLING.
METHOTREXATE IS A POTENT ANTI-CANCER DRUG, & IS EXTREMELY TOXIC &
MUST BE HANDLED W/GREAT CAUTION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR AN APPROVED AIR-PURIFYING RESPIRATOR
W/HIGH-EFFICIENCY CARTRIDGES.
Ventilation:CLOSED-SYSTSEM HANDLING/LOCAL EXHAUST
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. DESTROY CONTAMINATED LETHER ITEMS.
Supplemental Safety and Health
PH:7.8-8.9 EACH SOLUTION HAS A SPECIFIC PH WITHIN THAT RANGE.FIRST
AID:METHOTREXATE BLOOD LEVELS SHOULD BE MONITORED & THE CALCIUM
LEUCOVORIN DOSE ADJUSTED ACCORDINGLY. COMPLETE HOMOGRAMS
LIVER/KIDNEY TESTS ARE RECOMMENDED. HEALTH HAZARDS CONT'D: EYE
IRRITATION REPORTED IN 25% OF PATIENTS.
================== Physical/Chemical Properties ==================
Decomp Temp:Decomp Text:365-399.2F
pH:(SUPP)
Solubility in Water:INSOLUBLE
Appearance and Odor:DARK YELLOW, FREEZE DRIED PRESERVATIVE-FREE, LOW
SODIUM, CAKE/CRYSTALLINE MASS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALINE SOLUTIONS
Stability Condition to Avoid:TEMP >365F.
Hazardous Decomposition Products:CO, CO2, NITROGEN OXIDES, ALDEHYDES,
KETONES, ORGANIC ACIDS, HYDROGEN CYANIDE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSEOF IAW/LOCAL, STATE & FEDERAL
REGULATIONS. INCINERATION IS RECOMMENDED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:NOX, DC-14A
CAGE:06645
CAGE:06645
============= Composition/Information on Ingredients =============
Ingred Name:DISTILLATES, RESIDUE, LOW-BOILING; (AROMATIC PETROLEUM
DISTILLATE)
CAS:68477-31-6
RTECS #:JN9500000
Fraction by Wt: 32%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ETHANOL, 2-BUTOXY-; (2-BUTOXYETHANOL)
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 8%
OSHA PEL:50 PPM, S
ACGIH TLV:25 PPM, S
Ingred Name:KEROSENE; (ALIPHATIC HYDROCARBON)
CAS:8008-20-6
RTECS #:OA5500000
Fraction by Wt: 43%
OSHA PEL:500 PPM (MFR)
ACGIH TLV:400 PPM (MFR)
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL/FATAL IF SWALLOWED. EXCESSIVE
INHALATION OF VAPOR WILL CAUSE DIZZINESS, NASAL AND RESPIRATORY
IRRITATION. ANIMAL STUDIES HAVE CLEARLY DEMONSTRATED DOSE-RELATED
ADVERSE EFTS ON CNS, HEMATOPOIET IC TISSUE, BLOOD, KIDNEYS, & LIVER
ASSOC W/ADMIN OF ETHYLENE GLYCOL MONOBUTYL ETHER (EGBE). (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: (EXTRACTED FROM DHHS (NIOSH) PUB NO.
90-118) .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH IMMED WITH WATER FOR AT LEAST 15 MINUTES. IF
IRRITATION PERSISTS, CALL PHYSICIAN. SKIN:WASH WITH SOAP AND WATER.
INGEST: DO NOT INDUCE VOMITING. GIVE A GLASS OF WATER. DO NOT GIVE
LARGE AM OUNTS OF WATER AS THIS MAY CAUSE VOMITING. CALL PHYSICIAN.
INHAL: MOVE TO FRESH AIR.
===================== Fire Fighting Measures =====================
Flash Point:149F,65C
Lower Limits:1%
Extinguishing Media:FOAM, DRY CHEMICAL/CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS ARE HVR/AIR. CAN TRAVEL ALONG
GROUND AND IGNITE.
================== Accidental Release Measures ==================
Spill Release Procedures:SM SPILL: ABSORB IN DIRT, SAWDUST/OTHER
ABSORBENT. PLACE IN HOOD. LARGE SPILL: DIKE AREA AND PUMP TO INTACT
CONTAINER. ABSORB RESIDUE AND PLACE IN A CONTAINER. EXTINGUISH ALL
IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN TIGHTLY SEALED CONTAINER.
KEEP AWAY FROM HEAT SOURCES.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. PLACE USED RAGS IN
APPROVED SAFETY WASTE RECEPTACLE OR WASH WITH SOAP AND WATER AND
DISCARD TO AVOID POTENTIAL FIRE HAZARD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:365F,185C
Vapor Pres:1@20F
Vapor Density:7.1
Spec Gravity:0.93(H*2O=1)
pH:9.6
Solubility in Water:EMULSIFIABLE
Appearance and Odor:DARK AMBER LIQUID WITH AROMATIC ODOR
Percent Volatiles by Volume:73.8
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:TRIPLE RINSE CONTAINER WITH COLD WATER, THEN
DISPOSE OF I/A/W FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:5747-5807 OFFSET
Preparer's Name:DICK KARBO
CAGE:KMADD
CAGE:KMADD
============= Composition/Information on Ingredients =============
Ingred Name:COPPER COMPOUND
Fraction by Wt: 3%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PROLONGED CONTACT W/SKIN/EYES CAN
CAUSE IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION
======================= First Aid Measures =======================
First Aid:EYES: FLUSH IMMEDIATELY W/WATER. SKIN: WASH AFFECTED AREA
W/SOAP & WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>200F
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL: WIPE UP & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS. LARGE: SCOOP MATERIAL INTO SEALABLE
CONTAINERS. WIPE UP REMAINDER & STORE WIPERS IN UNDERWRITERS
APPROVED CONTAINERS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS.
Other Precautions:AVOID CONTACT W/SKIN, EYES & CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AS REQUIRED
Ventilation:LOCAL EXHAUST
Work Hygienic Practices:WASH AFTER USE. REMOVE/LAUNDER CONTAMINATED
CLOTHING BEFORE REUSE. DON'T CONSUME FOOD/BEVERAGE WHERE PRODUCT IS
USED.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:470-610F
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:INSOLUBLE
Appearance and Odor:OILY
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TT-E-2784 GRAY, #36118
CAGE:JO954
CAGE:JO954
CAGE:39934
============= Composition/Information on Ingredients =============
Ingred Name:PROPYLENE GLYCOL
CAS:57-55-6
RTECS #:TY2000000
Fraction by Wt: 6.25%
Other REC Limits:NONE RECOMMENDED
Ingred Name:2,2,4-TRIMETHYL-1-3-PENTANEDIOL MONOISOBUTYRATE
CAS:25265-77-4
Fraction by Wt: 4.86%
Other REC Limits:NONE RECOMMENDED
Ingred Name:DIMETHYLAMINOETHANOL LOW VOC
CAS:108-01-0
RTECS #:KK6125000
Fraction by Wt: 0.38%
Other REC Limits:NONE RECOMMENDED
Ingred Name:2-N-OCTYL-4-ISOTHIAZOLIN-3-ONE
CAS:123-96-6
RTECS #:RH0795000
Fraction by Wt: 0.18%
Other REC Limits:NONE RECOMMENDED
Ingred Name:NON HAZARDOUS INGREDIENTS
Fraction by Wt: 88.33%
Other REC Limits:NONE RECOMMENDED
Ingred Name:VOC = 1.7 LBS/GL
RTECS #:9999999VO
Other REC Limits:NONE RECOMMENDED
OSHA PEL:NOT EST.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: HEADACHE, NAUSEA, IRRITATION.
EYE: IRRITATION. CHRONIC: SKIN: IRRITATION.
Medical Cond Aggravated by Exposure:LUNG DISEASE
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINUTES. CALL DR.
SKIN: WASH W/SOAP & WATER. INGEST: GIVE 2 GLASSES OF WATER TO
DRINK. CALL DR.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:>212F,>100C
Autoignition Temp:Autoignition Temp Text:216F
Lower Limits:NONE
Upper Limits:NA
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE SCBA (PRESSURE DEMAND NIOSH/MSHA APPROVED)
& FULL PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:MATERIAL MAY SPLATTER ABOVE 212F. POLYMER
FILM MAY BURN.
================== Accidental Release Measures ==================
Spill Release Procedures:EVAC AREA. FLOOR MAY BE SLIPPERY, USE CARE TO
AVOID FALLING. DIKE/ABSORB. TRANSFER TO SEPARATE, SUITABLE
CONTAINER FOR RECOVERY/DISPOSAL. DONT CONTAMINATE SEWERS, OPEN
BODIES OF WATER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP FROM FREEZING.
Other Precautions:KEEP AWAY FROM CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:APPROVED MECHANICAL FILTER RESPIRATOR
Ventilation:NORMAL (FAN)
Other Protective Equipment:EYEWASH STATION
Supplemental Safety and Health
NK
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212 TO 644F
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Decomp Temp:Decomp Text:350F,177C
Vapor Pres:NONE
Vapor Density:>AIR
Spec Gravity:1.01
pH:<9.0
Viscosity:77-95 KU
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:SLIGHT
Appearance and Odor:LIQUID W/SLIGHT ODOR
Percent Volatiles by Volume:60.6
Corrosion Rate:NA
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NK
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:ACRYLIC MONOMERS
==================== Disposal Considerations ====================
Waste Disposal Methods:IN ACCORDANCE W/FEDERAL, STATE & LOCAL
AUTHORITIES.
| 1 | eyes_protection_mandatory |
=======================================================
NIIN: 01-181-7121
Product ID: PROPYLENE GLYCOL INDUSTRIAL
Cage: TO380
Resp. Party Other MSDS No.: P000029.001.OSHA.AE
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: PROPYLENE GLYCOL,TECHNICAL
Specification Number: MIL-P-83800
Unit of Issue: GL
UI Container Qty: 0
Type of Container: CAN
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
Route Of Entry Inds - Inhalation: NO
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: NO SIGNIFICANT SIGNS OR SYMPTOMS INDICATIVE OF ANY ADVERSE
HEALTH HAZARD ARE EXPECTED TO OCCUR AS A RESULT OF INHALATION EXPOSURE. EYE:
MAY CAUSE MINOR IRRITATION. SKIN: MINOR IRRITATION. INGEST: NO S IGNIFICANT
SIGNS OR SYMPTOMS INDICATIVE OF ANY ADVERSE HEALTH HAZARD ARE EXPECTED TO
OCCUR AS A RESULT OF INGESTION.
Explanation Of Carcinogenicity: NONE LISTED.
Signs And Symptions Of Overexposure: MINOR IRRITATION.
Medical Cond Aggravated By Exposure: THIS MATERIAL OR ITS EMISSIONS MAY
AGGRAVATE PRE-EXISTING EYE DISEASE.
First Aid: INHALE: NOT EXPECTED TO REPSENT A SIGNIFICANT INHALATION HAZARD
UNDER ANTICIPATED CONDITIONS OF NORMAL USE. EYE: RINSE WITH CLEAN WATER FOR
20-30 MINUTES. RETRACT EYELIDS OFTEN. OBTAIN EMERGENCY MEDIC AL ATTENTION IF
PAIN, BLINKING, TEARS OR REDNESS PERSIST. SKIN: NOT EXPECTED TO RPESENT A
SIGNIFICANT SKIN HAZARD UNDER ANTICIPATED CONDITIONS OF NORMAL USE. INGEST:
NOT EXPECTED TO PRESENT A SIGNIFIC ANT INGESTION HAZARD UNDER ANTICIPATED
CONDITIONS OF NORMAL USE.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: MAY CONTAMINATE WATER SUPPLIES. PREVENT FLOW TO
SEWER/PUBLIC WATERS. STOP RELEASE. NOTIFY FIRE AND ENVIRONMENTAL AUTHORITIES.
RESTRICT WATER USE FOR CLEANUP. SLIPPERY WALKING. SPREAD GRANULAR COVER.
Waste Disposal Methods: LANDFILL SOLIDS AT PERMITTED SITES. USE REGISTERED
TRANSPORTERS. BURN CONCENTRATED LIQUIDS, DILUTING WITH CLEAN , LOW VISCOSITY
FUEL. AVOID FLAME-OUTS. ASSURE EMISSIONS COMPLY WITH APPLICABLE REGULATI ONS.
DILUTE AQUEOUS WASTE MAY BIODEGRADE.ASSURE EFFLUENT COMPLIES WITH
APPLICABLE REGULATIONS.
Handling And Storage Precautions: KEEP CONTAINERS TIGHTLY CLOSED TO PREVENT
CONTAMINATION. STORE AT 65-90F.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: PMCC
Flash Point: =108.9C, 228.F
Autoignition Temp: =371.1C, 700.F
Lower Limits: 2.4
Upper Limits: 17.4
Extinguishing Media: ALCOHOL TYPE FOAM,CO2,DRY CHEMICAL
Fire Fighting Procedures: DO NOT ENTER FIRE AREA WITHOUT PROPER
PROTECTION.FIGHT FIRE FROM A SAFE DISTANCE/PROTECTED LOCATION.HEAT MAY BUILD
ENOUGH PRESSURE TO RUPTURE CLOSED CONTAINERS/SPREADING FIRE/INCREASING RISK
OF BURNS/ INJURIES.USE WATER SPRAY/FOG FOR COOLING.AVOID FROTHING/S/STEAM
EXPLOSION. WATER SOLUBLE
Unusual Fire/Explosion Hazard: HEAT FROM FIRE CAN GENERATE FLAMMABLE VAPOR.WHEN
MIXED WITH AIR AND EXPOSED TO IGNITION SOURCE,VAPOR CAN BURN IN OPENOR
EXPLODE.VAPORS MAY TRAVEL ALONG THE GROUND BEFORE IGNITING AND FLASH BACK TO
SOU RCE.FINE SPRAYS,MISSTS MAY BE COMBUSTIBLE AT TEMPERATURES BELOW NORMAL
FLASH POINT.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NO SPECIAL RESPIRATORY PROTECTION IS RECOMMENDED UNDER
ANTICIPATED CONDITIONS OF NORMAL USE WITH ADEQUATE VENTILATION.
Ventilation: NO SPECIAL VENTILATION IS RECOMMENDED UNDER ANTICIPATED CONDITIONS
OF NORMAL USE BEYOND THAT NEEDED FOR NORMAL COMFORT CONTROL.
Work Hygienic Practices: USE GOOD PERDONAL HYGIENE PRACTICE.WASH HANDS BEFORE
EATING,DRINKING,SMOKING,OR USING TOILET FACILITIES.PROMPTLY REMOVE SOILED
CLOTHING/WASH THOROUGHLY BEFORE REUSE.SHOWER AFTER WORK **
Supplemental Safety and Health: **USING PLENTY OF SOAP AND WATER.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: N1
Boiling Point: =187.8C, 370.F
Melt/Freeze Pt: =-60.C, -76.F
Vapor Pres: 0 MMHG @ 68F
Spec Gravity: 1.04
Viscosity: 46CPS
Solubility in Water: COMPLETE
Appearance and Odor: CLEAR,COLORLESS;SLIGHTLY VISCOUS LIQUID;LITTLE OR NO ODOR
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES,OXIDIZING CONDITIONS
Materials To Avoid: STRONG OXIDIZING AGENTS
Hazardous Decomposition Products: INCOMPLETE COMBUSTION MAY PRODUCE CARBON
MONOXIDE AND OTHER TOXIC GASES
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
Transport Information: NOT REGULATED.
=======================================================
Regulatory Information
=======================================================
State Regulatory Information: PENNSYLVANIA RIGHT TO KNOW: HAZARDOUS SUBSTANCE
MUST BE IDENTIFIED WHEN PRESENT IN MATERIALS AT LEVELS GREATER THAN THE STATE
SPECIFIED CRITERION. THE CRITERION IS >= 1%. COMPONENTS WITH CAS NUMBERS I
N THIS MATERIAL AT A LEVEL WHICH COULD REQUIRE REPORTING UNDER THE STATUTE
ARE: PROPYLENE GLYCOL (CAS 57-55-6).
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Trans ID NO: 149600
Product ID: PROPYLENE GLYCOL INDUSTRIAL
Review Date: 10/31/1999
Net Unit Weight: 1 GAL
Multiple KIT Number: 0
Unit Of Issue: GL
Container QTY: 0
Type Of Container: CAN
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: PROPYLENE GLYCOL INDUSTRIAL
Cage: TO380
Assigned IND: Y
Company Name: LYONDELL CHEMICAL WORLDWIDE, INC.
Street: 1221 MCKINNEY STREET
Zipcode: 77101
Label Required IND: Y
Date Of Label Review: 10/31/1999
Status Code: A
Origination
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: None
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: HEALTH HAZARD: EYE IRRITANT. PHYSICAL HAZARD:
COMBUSTIBLE. AQUEOUS SOLUTION MAY PRODUCE FLAMMABLE VAPORS. PRECAUTIONARY
MEASURES: DO NOT HANDLE NEAR HEAT, SPARKS, OR OPEN FLAMES. FIRST AID: NHALE:
NOT EXPECTED TO REPSENT A SIGNIFICANT INHALATION HAZARD UNDER ANTICIPATED
CONDITIONS OF NORMAL USE. EYE: RINSE WITH CLEAN WATER FOR 20-30 MINUTES.
RETRACT EYELIDS OFTEN. OBTAIN MEDICAL ATTENTION IF PAIN, BLINKING, TEARS OR
REDNESS PERSIST. SKIN: NOT EXPECTED TO RPESENT A SIGNIFICANT SKIN HAZARD
UNDER ANTICIPATED CONDITIONS OF NORMAL USE. INGEST: NOT EXPECTED TO PRESENT A
SIGNIFICANT INGESTION HAZARDUNDER ANTICIPATED CONDITIONS OF NORMAL USE.
=======================================================
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:FLEXTRON, 2378
Preparer's Name:J BURNWORTH
CAGE:9H480
CAGE:9H480
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: HIGH CONCENTRATIONS
OF VAPORS MAY CAUSE HEADACHE, NAUSEA & IRRITATION OF THE NOSE,
THROAT, & LUNGS. EYE: MAY CAUSE IRRITATION/BURNING. SKIN: REPEATED
LIQUID CONTACT MAY CAUSE IRRITA TION & DERMATITIS. INGESTION:
SWALLOWING CAN CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING
& (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DIARRHEA. VOMITING CAN RESULT IN
ASPIRATION OF MATERIAL INTO THE LUNGS WHICH CAN CAUSE CHEMICAL
PNEUMONITIS. CHRONIC: UNPROTECTED OVEREXPOSURE TO MISTS FROM SPRAY
APPLICATION MAY CAUSE LUNGDISEASE (SILICOSIS).
Medical Cond Aggravated by Exposure:NONE KNOWN AT THIS TIME.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED,
APPLY ARTIFICIAL RESPIRATION. CONSULT MD. EYES: WASH WITH CLEAN
WATER FOR AT LEAST 15 MINUTES. CONSULT MD. SKIN: WASH AFFECTED
AREAS WITH SOA P AND WATER. REMOVE CONTAMINATED CLOTHING. CONSULT
MD. INGESTION: DRINK ONE OR TWO GLASSES OF WATER TO DILUTE. CONSULT
MD OR POISON CONTROL CENTER IMMEDIATELY.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE FOAM, ALCOHOL FOAM, CARBON DIOXIDE, DRY
CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WATER MAY BE USED TO COOL CLOSED
CONTAINERS TO PREVENT PRESSURE BUILD UP AND EXPLOSION WHEN EXPOSED
TO EXTREME HEAT.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. PREVENT SKIN AND EYE CONTACT
AND BREATHING OF VAPOR. CONTAIN AND REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE ABOVE 200F.
Other Precautions:DO NOT TAKE INTERNALLY. KEEP OUT OF THE REACH OF
CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NOT REQUIRED FOR BRUSH AND ROLL APPLICATION. FOR
SPRAY APPLICATION, WEAR A PROPERLY FITTED NIOSH/MSHA (TC-23C)
APPROVED VAPOR/PARTICULATE RESPIRATOR UNTIL ALL VAPORS AND SPRAY
MIST ARE EXHAUSTED.
Ventilation:PROVIDE SUFFICIENT VENT IN VOL & PATTERN TO KEEP AIR CONTAM
CONC BELOW APPLIC OSHA PEL/ACGIH TLV OCCUP EXPOS LIMITS.
Other Protective Equipment:COVERALLS, HOOD ARE REC DURING SPRAY
APPLICATION. PROT CREAMS MAY BE USED FOR EASE OF CLEAN-UP, NOT FOR
PROT.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING THE RESTROOM.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F,100C
Vapor Density:LTR/AIR
Spec Gravity:1.34 (H*2O=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:DILUTABLE
Appearance and Odor:MULTI COLORED LIQUIDS, WITH AMMONIACAL ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN AT THIS TIME.
Stability Condition to Avoid:DO NOT HEAT ABOVE 200F.
Hazardous Decomposition Products:NONE KNOWN AT THIS TIME.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. ABSORB LARGE SPILLS WITH SAND, CLAY, OR DIATOMACEOUS
EARTH. DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL DISPOSAL
REQUIREMENTS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MIL-R-83936B,AM1,REMOVER,PAINT,TANK TYPE
CAGE:MO694
CAGE:MO694
CAGE:3D863
============= Composition/Information on Ingredients =============
Ingred Name:ETHANOLAMINE
CAS:141-43-5
RTECS #:KJ5775000
OSHA PEL:3 PPM/6 STEL
ACGIH TLV:3 PPM/6 STEL; 9192
===================== Hazards Identification =====================
Effects of Overexposure:AVOID SKIN/EYE CNTCT
======================= First Aid Measures =======================
First Aid:SKIN: WASH THOROUGHLY W/MILD SOAP & WATER. EYES: IMMED FLUSH
W/WATER AT LEAST 15 MIN. CALL MD.
===================== Fire Fighting Measures =====================
Flash Point:170F TCC
Extinguishing Media:CO*2, FOAM
================== Accidental Release Measures ==================
Spill Release Procedures:MFR SUGGESTS FLUSH TO DRAIN W/WATER
============= Exposure Controls/Personal Protection =============
Ventilation:LOCAL EXHST DESIRABLE
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:195F
Spec Gravity:0.97
Appearance and Odor:TWO-PHASE, LIGHT AMBER LIQ, SOLVENT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IAW LOCAL, STATE, FED REG
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:PR-1005-L-R RUBBER SOLUTION
Preparer's Name:JCS
CAGE:DO563
CAGE:83574
CAGE:DO563
============= Composition/Information on Ingredients =============
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 50%
Other REC Limits:NONE SPECIFIED
OSHA PEL:200 PPM/300 STEL
ACGIH TLV:200 PPM/300STEL 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 15%
Other REC Limits:NONE SPECIFIED
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9192
Ingred Name:METHYL ISOBUTYL KETONE (SARA III)
CAS:108-10-1
RTECS #:SA9275000
Fraction by Wt: 10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:100 PPM/75 STEL
ACGIH TLV:50 PPM/75 STEL; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:PHENOL POLYMER WITH FORMALDEHYDE (PHENOLIC RESIN)
CAS:9039-25-2
Fraction by Wt: 15%
Other REC Limits:NONE SPECIFIED
Ingred Name:VOC, G/L (LESS EXEMPTIONS): 677
RTECS #:9999999VO
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: LIQUID CONTACT MAY DAMAGE EYE
TISSUE. SKIN: DERMATITIS. INHALATION AND INGESTION: POSSIBLE COMA.
Explanation of Carcinogenicity:NO
Effects of Overexposure:EYES: IRRITATION. LIQUID CONTACT MAY DAMAGE EYE
TISSUE. SKIN: IRRITATION & DERMATITIS. INHALATION: NOSE & THROAT
IRRITATION, HEADACHE, DIZZINESS, NAUSEA, VOMITING, MENTAL
DEPRESSION, NARCOSIS, ANESTHE SIA & COMA. INGESTION: HEADACHE,
DIZZINESS, FLUSHING, NAUSEA, VOMITING, MENTAL DEPRESSION, NARCOSIS,
ANESTHESIA & COMA.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH LUKE WARM WATER FOR 15 MINUTES, IF SYMPTOMS
PERSIST, CONSULT A PHYSICIAN. SKIN: WASH WITH SOAP & WATER. IF
SYMPTOMS PERSIST, CONSULT A PHYSICIAN. INHALATION: REMOVE TO FRESH
AIR. IF S YMPTOMS ARE PRESENT, CONSULT A PHYSICIAN. AND INGESTION:
INDUCE VOMITING. CONSULT A PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:23 F/-5 C
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:USE AIR SUPPLIED RESPIRATOR. USE WATER TO COOL
HEAT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:HIGH TEMPERATURES MAY CAUSE PRESSURE
BUILD-UP IN CLOSED CONTAINERS.
================== Accidental Release Measures ==================
Spill Release Procedures:PROTECT FROM IGNITION. COVER WITH ABSORBENT
MATERIAL. SCOOP INTO CONTAINER. CLEAN UP RESIDUE WITH
1,1,1-TRICHLOROETHANE.
======================Handling and Storage ======================
Other Precautions:THIS PRODUCT CONTAINS A TOXIC CHEMICAL SUBJECT TO THE
REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUND
AMENDMENTS & REAUTHORIZATION ACT OF 1986 & 40 CFR PART 372.
============= Exposure Controls/Personal Protection =============
Ventilation:GENERAL VENTILATION TO MAINTAIN VAPORS BELOW PEL.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:0.86
Solubility in Water:APPRECIABLE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:OXIDES OF CARBON
==================== Disposal Considerations ====================
Waste Disposal Methods:EPA NO. D-001 HAZARDOUS WASTE. DISPOSE IN
COMPLIANCE WITH FEDERAL AND STATE REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ASPHALT EMULSION, LMCRS-2H
CAGE:5W738
CAGE:5W738
============= Composition/Information on Ingredients =============
Ingred Name:ASPHALT; (PETROLEUM ASPHALT)
CAS:8052-42-2
RTECS #:CI9900000
Fraction by Wt: 26-65%
OSHA PEL:N/K
ACGIH TLV:5 MG/M3
Ingred Name:SUPDAT:HYGENE PRACT:LEATHER MATL. OBSERVE GOOD PERSONAL
HYGIENE. WASH THORO AFTER WORKING W/ASPHALT & BEFORE EATING.
RTECS #:9999999ZZ
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES:IRRITATION. SKIN:MILD IRRITATION.
REPEATED CONTACT CAN CAUSE DERMATITIS. INHAL:RESPIRATORY
IRRITATION, NAUSEA, DIZZINESS, HEADACHE. INGEST:STOMACH IRRITATION,
NAUSEA, AND VOMITING. BREATHING ASPH ALT AEROSOL OR ASPHALT SMOKE
FOR PROTRACTED PERIODS OF TIME HAS PRODUCED DAM TO THE LUNGS OF
MICE. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:AMONG THE CHANGES OBSERVED WERE
BRONCHITIS, PNEUMONITIS, AND ABSCESS FORMATION. ASPHALT FUME
CONDENSATES HAVE BEEN SHOWN TO PRODUCE A TUMOROGENIC RESPONSE WHEN
REPEATEDLY APPLIED TO THE SKIN OF EXPERIMENTAL ANIMALS. THE
RELEVANCE OF THIS DATA TO HUMANS IS NOT KNOWN AT THIS TIME.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINS
WHILE HOLDING EYELIDS OPEN. GET MED ATTN IF CONDITION PERSISTS.
SKIN:WASH WITH SOAP AND WATER OR USE WATERLESS HANDCLEANER.
INHAL:REMOVE TO FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN;
IF BREATHING HAS STOPPED, GIVE ARTIF RESP. GET MED ATTN. INGEST:IF
VICTIM IS CONSCIOUS, GIVE LIQUIDS. INDUCE VOMITING. CALL A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:DRY CHEMICAL, WATER FOG, FOAM CO*2.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY FOAM IF HEATED TO 212F OR IF MIXED
WITH MATERIALS IN EXCESS OF 212F.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL IMMED IN SMALLEST AREA POSS.
RECOVER AS MUCH OF THE PROD AS POSS. RESIDUAL FLUID SHOULD BE
SOAKED UP BY USE OF ABSORBANT MATLS. SWEEP UP & DISPOSE OF IN
ACCORDANCE WITH FEDERAL, STATE & LOCAL REGS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE >180F/USE HEATING SURF
>200F AT SEA LEVEL. SKIN CONT SHOULD BE MINIMIZED. HYDROGEN SULFIDE
IS EXTREMELY FLAMM, HIGHLY TOXIC GAS. (SUPDAT)
Other Precautions:WHEN ASPHALT PRODS ARE HEATED, THEY OFTEN GIVE OFF SM
AMTS OF HYDROGEN SULFIDE. MINIMIZE BRTHG VAPS, FUMES, OR MIST; WHEN
POSS, USE VENT/WORK UPWIND OF SOURCE OF VAPS, FUMES OR MIST.
EXPOSING SKIN TO ASPHALT FUMES, MIST OR VAPS, AS (SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQD FOR NORMAL CONDTNS. IF OPERATING
CONDTNS CAUSE HIGH VAP CONCS/TLV IS EXCEEDED, USE NIOSH/MSHA
APPROVED SUPPLIED AIR RESPIRATOR.
Ventilation:NORMAL VENT UNLESS VAPS ARE HIGH, THEN MECH VENT SHOULD BE
USED.
Other Protective Equipment:COMPLETE PROT CLTHG IF MATL IS BEING HANDLED
HOT.
Work Hygienic Practices:CLEAN EXPOSED SKIN W/SOAP & WATER OR WATERLESS
HAND CLEANER. LAUNDER OR DISCARD CONTMD CLTHG. DISCARD CONTAMD (ING
2)
Supplemental Safety and Health
SPEC GRAV:SLIGHTLY >1 (WATER =1). HANDLING/STOR:REFER TO FOLLOW
PUBLICATION ENTITLED "SAFE STORAGE & HNDLG OF HOT ASPHALT"; THE
ASPHALT INSTITUTE, INFORMATION SERIES NO. 180, AUG 1981. OTHER
PREC:MAY OCCUR W/ROAD WORK, CAN INCREASE SENSIT TO SUNBURN. EYE
PROT:SFTY GLASSES W/SFTY SHIELD IF MATL IS COLD.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>212F,>100C
Spec Gravity:SUPDAT
Evaporation Rate & Reference:NO DATA AVAILABLE
Solubility in Water:DILUTES WITH WATER
Appearance and Odor:BROWN TO BLACK LIQUID OR SEMISOLID
Percent Volatiles by Volume:30
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:HEAT, FLAME OR SPARK. DO NOT HEAT TO
BOILING POINT - 212F.
Hazardous Decomposition Products:HAZARDOUS GASES/VAPORS PRODUCED ARE
CARBON DIOXIDE, CARBON MONOXIDE, OR SULFUR DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE AS MUCH OF RECOVERABLE PROD AS POSS.
DISPOSE OF NONRECYCLABLE MATL BY SUCH METHS AS CONTROLLED
INCINERATION/BLENDING W/AGGREGATE & USED FOR PATCHING & OTHER
MAINTENANCE USE. DISPOSE OF IN ACCO RDANCE WITH FEDERAL, STATE AND
LOCAL REGS .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:BROMTHYMOL BLUE,0.04% IN AQU 2-PROPANOL OR ISOPROPYL ALCOHOL
CAGE:3D869
CAGE:3D869
============= Composition/Information on Ingredients =============
Ingred Name:BROMOTHYMOL BLUE
CAS:76-59-5
RTECS #:SJ7450000
Fraction by Wt: 0.04%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ISOPROPYL ALCOHOL (SARA 313)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 44.2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM
ACGIH TLV:400 PPM/500STEL;9596
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 55.4%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL:EXCESSIVE VAP INHAL CAN CAUSE
NASAL/RESP IRRIT,CNS EFFECTS INCLUDE
DIZZ,WEAK,FTG,NAU,HEAD,POSSIBLE UNCONSC.SKIN/EYE:CAUSES
IRRIT,REDNESS,TEARING IN EYES & SLIGHT SKIN IRRIT.ABSORB THRU
SKIN:HARM FUL.INGEST:CAN CAUSE GI IRRIT,NAU,VOMIT,DIARR.
Explanation of Carcinogenicity:PER MSDS:PRODUCTS INGRED ARE NOT FOUND
IN NTP/IARC.
Effects of Overexposure:NASAL/RESP IRRIT,CNS
EFFECTS,DIZZ,WEAK,FTG,NAU,HEADACHE,UNCONSCIOUSNESS. EYE
IRRIT,REDNESS,TEARING. SKIN IRRIT,HARMFUL IF ABSORBED THRU SKIN.GI
IRRIT,NAU,VOMIT,DIARRHEA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYE:HOLD LID OPEN,WASH W/WATER FOR 15MINS.SKIN:WASH
W/SOAP/WATER.LAUNDER CONTAMIN CLOTH BEF RESUE.INHAL:BREATHING
DIFFICULT SUPPLY AIR OR OXY OR REMOVE TO FRESH AIR.CALL
DOCTOR.INGEST:IMMED DRINK 2 GL ASSES OF WATER.INDUCE VOMIT BY
EITHER GIVEING IPECAC SYRUP OR BY PLACING FINGER AT BACK OF
THROAT.NEVER GIVE ANYTING BY MOUTH TO UNCONSC PERSON.GET MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:54.0F,12.2C
Autoignition Temp:Autoignition Temp Text:867F
Lower Limits:2.0
Upper Limits:12.0
Extinguishing Media:ALCOHOL FOAM OR CARBON DIOXIDE OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS W/FULL
FACEPIECE OPERATED IN THE POSITIVE PORESSURE DEMAND MODE WHEN
FIGHTING FIRES.
Unusual Fire/Explosion Hazard:MATL READILY GIVES OFF VAP WHICH MAY
TRAVEL ALONG GROUND/BE MOVED BY VENTI;IGN BY PILOT LGHTS,OTHER
FLAMES,HEATERS,OTHER IGN SOURCES @LOC DISTANT FROM (SUPPLEM)
================== Accidental Release Measures ==================
Spill Release Procedures:TOPS SPILL W/O RISK.PREVENT FROM ENTERING
SEWERS/STORM DRAINS/OTHER UNAUTHORIZED TREATMENT DRAINAGE SYS & NAT
WATERWAYS.REMOVE IGN SOURCES(FLARES,FLAMES,PILOT LIGHT,ELECT
SPARKS).PERSON W/OPPE SHOULD BE EXCLUDED FROM SPILL AREA TIL
CLEAN.PUMP (SUPPL)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE MATL IN SEALED PLASTIC CNTNRS IN
COOL,DRY PLACE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPO LIMIT OF PRODUCT OR ANY
COMPONENETS IS EXCEEDED NIOSH/MSHA APPROVED AIR RESP IS ADVISED IN
ABSENCE OF PROPER ENVIRO CONTROL.
Ventilation:VENTILATION MUST BE CHECKED @MONTHLY INTERVALS.BE SURE THAT
AIR TURN OVER IS ADEQUATE.
Other Protective Equipment:RUBBER APRONS OR DISPOSABLE COVERALLS &
RUBBER APRONS.
Work Hygienic Practices:DO NOT EAT IN WORK AREA.ALWAYS WASH EQPMT &
HANDS AFT WORK SHIFT.SPILL IMMED WASH SPILL AREA.
Supplemental Safety and Health
FIRE/EXPLO HAZ:MATL HNDLG PT.ALL 5 GAL PAILS/LGER METAL CNTNRS INCLUDE
TANK CARS/TANK TRUCKS SHOULD BE GROUNDED &/OR BONDED WHEN MATL
TRANSFERRED. SPILL:LIQ TO SALVAGE TK;REMAINING LIQ TAKE UP SAND/CL
AY/EARTH/FLOOR ABSORBENT/OTHER ABSOR MATL.SHOVEL INTO CNTNR.
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:180F,82C
Melt/Freeze Pt:M.P/F.P Text:-128F,-89C
Decomp Temp:Decomp Text:NP
Vapor Pres:33MM
Vapor Density:2.1
Spec Gravity:0.79
pH:NP
Viscosity:NP
Evaporation Rate & Reference:2.83, BUTYL ACETATE=1.
Solubility in Water:COMPLETE.
Appearance and Odor:YELLOW TO BLUE LIQUID, WITH SLIGHT ODOR OF RUBBING
ALCOHOL.
Percent Volatiles by Volume:NP
Corrosion Rate:NP
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS,STRONG ALKALIS,STRONG MINERAL ACIDS.
Stability Condition to Avoid:HEAT, FLAME, OR TOHER SOURCES OF IGNITION.
Hazardous Decomposition Products:CARBON MONOXIDE & CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF PRODUCT IN LICENSED HAZ WASTE DISPO
FACILITY IAW APPLICABLE FED/STATE/LOC REGS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:5356 ALUMINUM MIG/TIG ALLOY WIRE OR ROD
CAGE:0ACE2
CAGE:0ACE2
============= Composition/Information on Ingredients =============
Ingred Name:ALUMINUM (SARA III)
CAS:7429-90-5
RTECS #:BD0330000
Fraction by Wt: 93-94.3%
Other REC Limits:NONE SPECIFIED
OSHA PEL:15MG/M3 DUST/5 FUME
ACGIH TLV:10MG/M3 DUST; 9192
Ingred Name:CHROMIUM (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: <0.20%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:COPPER (SARA III)
CAS:7440-50-8
RTECS #:GL5325000
Fraction by Wt: 0.10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.1MG/M3 FUME/1 DUST
ACGIH TLV:0.2MG/M3 FUME; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:IRON
CAS:7439-86-6
RTECS #:NO6925000
Fraction by Wt: 0.40%
Other REC Limits:NONE SPECIFIED
Ingred Name:MAGNESIUM
CAS:7439-95-4
RTECS #:OM2100000
Fraction by Wt: 4.5-5.5%
Other REC Limits:NONE SPECIFIED
Ingred Name:MANGANESE (SARA III)
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: <0.20%
Other REC Limits:NONE SPECIFIED
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
Ingred Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: 0.25%
Other REC Limits:NONE SPECIFIED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:TITANIUM, METAL
CAS:7440-32-6
RTECS #:XR1700000
Fraction by Wt: <0.20%
Other REC Limits:NONE SPECIFIED
Ingred Name:ZINC (SARA III)
CAS:7440-66-6
RTECS #:ZG8600000
Fraction by Wt: 0.10%
Other REC Limits:NONE SPECIFIED
OSHA PEL:10 MG ZNO/M3
ACGIH TLV:10 MG ZNO/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:UNCLASSIFIED WELDING FUMES=5MG/M3 PEL
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUMES,
GASES OR DUST MAY RESULT IN DISCOMFORT SUCH AS DIZZINESS, NAUSEA,
FEVER, DRYNESS AND/OR IRRITATION OF NOSE, THROAT AND EYES. SKIN
SENSITIVITY MAY ALSO BE NOTED. A CUTE EXPOSURE FROM SOME TOXIC
GASES MAYCAUSE PULMONARY EDEMA, ASPHYXIATION AND EXCESSIVE EXPOSURE
CAN BE FATAL.
Explanation of Carcinogenicity:NONE OF THE METALS LISTED IN THIS ALLOY
ARE LISTED AS CARCONOGENS. CHROMIUM, A SUSPECT CARCINOGEN MAY EXIST
IN TRACE AMT
Effects of Overexposure:EXPOSURE TO WELDING FUMES MAY RESULT IN
DISCOMFORT SUCH AS DIZZINESS, NAUSEA, FEVER, DRYNESS AND/OR
IRRITATION OF NOSE, THROAT AND EYES. SKIN SENSITIVITY MAY ALSO BE
NOTED. WATERY EYES, HEADACHE, BREA THING DIFFICULTY, FREQUENT
COUGHING AND/OR CHEST PAINS MAY OCCUR FROM ACUTE EXPOSURE. TOXIC
GASES CAN BE FATAL.
Medical Cond Aggravated by Exposure:SOME WORKERS MAY BE AFFECTED BY A
PRE-EXISTING CONDITION OR OTHER OCCUPATIONAL ILLNESS BECAUSE OF THE
WIDE VARIATION IN INDIVIDUAL SUSCEPTIBILITIES.
======================= First Aid Measures =======================
First Aid:IN CASE OF ELECTRICAL SHOCK, TURN OFF POWER PRIOR TO REMOVAL
FROM EXPOSURE AREA AND ADMINISTRATION OF FIRST AID. REMOVE FROM
EXPOSURE AREA AND CALL FOR MEDICAL AID. ADMINISTER OXYGEN IF
BREATHING IS D IFFICULT. IF NOT BREATHING, BEGIN ARTIFICIAL
RESPIRATION. IF NO DETECTABLE PULSE, BEGIN EXTERNAL HEART MASSAGE.
REMOVE VICTIM FROM WELDING AND DUSTY AREAS.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL AS APPROPRIATE FOR SURROUNDINGS.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS SUCH AS METAL FUMES.
================== Accidental Release Measures ==================
Spill Release Procedures:CLEAN UP ANY GRINDING DUST OR WASTE RESIDUES
AND PLACE IN SUITABLE DOT APPROVED CONTAINERS AND DISPOSE OF IN
FULL COMPLIANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. AVOID
INHALATION AND SKIN EXPOSU RE.
======================Handling and Storage ======================
CLOTHING WHEN CUTTING, GRINDING OR WELDING. DO NOT EXPOSE SKIN TO
RADIATION WHEN HOT CUTTING OR WELDING.
Other Precautions:PROVIDE PROTECTIVE SCREENS TO SHIELD OTHERS. WHEN
ELECTRODES AND FLUXES ARE CONSUMED, THE FUME AND GAS DECOMPOSITION
PRODUCTS GENERATED ARE DIFFERENT IN FORM FROM THE INGREDIENTS
LISTED. NEW COMPOUNDS NOT IN THE ELECTRODES MAY FORM.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE WELD FUME RESPIRATOR OR AIR SUPPLIED
RESPIRATOR WHEN CUTTING, GRINDING OR WELDING IN A CONFINED SPACE OR
WHERE LOCAL EXHAUST OR GENERAL VENTILATION DOES NOT KEEP EXPOSURE
BELOW RECOMMENDED LIMITS. USE ONLY NIOSH APPROVED RESPIRATORS.
Ventilation:USE ENOUGH VENTILATION WHEN CUTTING, GRINDING OR WELDING TO
KEEP THE DUST, FUMES & GASES FROM THE WORKERS BREATHING ZONE
Other Protective Equipment:FLAME RETARDANT CLOTHING WHEN CUTTING,
GRINDING OR WELDING. DO NOT EXPOSE SKIN TO RADIATION WHEN HOT
CUTTING OR WELDING.
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING OR SMOKING.
LAUNDER CONTAMINATIED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
WELDING AND HOT CUTTING FUMES & GASES CANNOT BE CLASSIFIED SIMPLY.
THEIR COMPOSITION AND QUANTITY ARE DEPENDENT ON THE METAL BEING
WELDED, THE PROCEDURES, PROCESSES AND THE TYPE OF WIRE OR
ELECTRODESUSED. OTHER INFLUENCING FACTORS ARE THEPRESENCE OF
CONTAMINANTS. CHLORINATED SOLVENTS MAY DECOMPOSE TO TOXIC GASES.
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:2.7 APPROX.
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:WELDING AND CUTTING OPERATION MAY
INCLUDE OXIDES OF THE METALS, CHROMATES, FLUORIDES, COMPLEX
METALLICS, AND OZONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS. PRACTICE GOOD HOUSEKEEPING IN CLEANING UP AROUND METAL
DUST AND PARTICULATE AREAS.
| 1 | eyes_protection_mandatory |
=======================================================
NIIN: 01-187-8862
Product ID: 56707 PST HIGH TEMPERATURE ANTI-GALLING SEALANT
Cage: 05972
=======================================================
Preparer Co. when other than Responsible Party Co.
=======================================================
Cage: 05972
=======================================================
Contractor Summary
=======================================================
Cage: 05972
=======================================================
Item Description Information
=======================================================
Item Manager: N35
Item Name: SEALING COMPOUND
Specification Number: UNKNOWN
Unit of Issue: TU
Quantitative Expression: 00000000006ML
UI Container Qty: 1
Type of Container: TUBE
=======================================================
Ingredients
=======================================================
Cas: 39382-25-7
% Wt: 30-35
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 25852-47-5
% Wt: 20-25
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 9004-81-3
RTECS #: TQ8701000
% Wt: 20-25
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 9002-88-4
RTECS #: TQ3325000
% Wt: 5-10
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 116-14-3
RTECS #: KX4025000
% Wt: 5-10
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 13463-67-7
RTECS #: XR2275000
% Wt: 3-5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 15 MG/M3 TDUST
ACGIH TLV: 10 MG/M3 TDUST; 9596
------------------------------
Cas: 80-15-9
RTECS #: MX2450000
(CERCLA)
% Wt: 1-3
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
------------------------------
Cas: 613-48-9
% Wt: 1-3
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 81-07-2
RTECS #: DE4200000
% Wt: 1-3
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
------------------------------
Cas: 112945-52-5
RTECS #: VV7310000
% Wt: 1-3
Other REC Limits: NONE RECOMMENDED
OSHA PEL: 6 MG/M3
ACGIH TLV: 10 MG/M3
------------------------------
Cas: 25068-38-6
RTECS #: SL6475000
% Wt: 0.1-1
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: ORAL LD50 >10000MNG/KG.
Route Of Entry Inds - Inhalation: NO
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: MODERATE EYE IRRITANT.
Explanation Of Carcinogenicity: PER MSDS:CA PROP 65:PROD CONTAINS CHEM KNOWN TO
STATE OF CA CAUSE CANCER(EPICHLOROHYDRIN).
Signs And Symptions Of Overexposure: MAY CAUSE DERMATITIS ON PROLONGED CONTACT
IN SENSITIVE INDIVIDUALS.
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INGEST:DO NOT INDUCE VOMITING. KEEP INDIVIDUAL CALM. INHAL:DOES NOT
APPLY. SKIN:WASH W/WATER. EYE:FLUSH @LEAST 15MINS W/WATER. OBTAIN MED ATTN.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: SOAK UP IN INERT ABSORBENT. STORE IN PARTLY FILLED,
CLOSED CONTAINER UNTIL DISPOSAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE FOLLOWING EPA & LOCAL REGULATIONS.
CONTAINS CHEM SUBJ TO SEC 313 TITLE III SARA TOXIC CHEMICALS.
Handling And Storage Precautions: STORE BELOW 100F.CALL LOCTITE CUSTOMER SERV
800-243-4874 FOR SHELF LIFE INFO.AVOID PROLONGED SKIN CONTACT.KEEP AWAZY FROM
EYES.
Other Precautions: THIS PRODUCT CONTAINS SACCHARIN. NO PROP 65 HAZARD WARNING
IS NECESSARY IF PRODUCT IS USED AS REASONABLY ANTICIPATED.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Method: TCC
Flash Point Text: >200F,>93C
Lower Limits: NOT AVAILABL
Upper Limits: NOT AVAILABL
Extinguishing Media: CARBON DIOXIDE, FOAM, DRY CHGEMICAL
Fire Fighting Procedures: NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE SPECIFIED BY MANUFACTURER.
Ventilation: DOES NOT APPLY.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: V7
B.P. Text: >300F,>149C
Vapor Pres: <5 @80F
Vapor Density: NA
Spec Gravity: 1.14 @80F
PH: NA
Evaporation Rate & Reference: NOT AVAILABLE.
Solubility in Water: SLIGHT
Appearance and Odor: WHITE PASTE, MILD ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE
Hazardous Decomposition Products: IRRITATING ORGANIC VAPOR.
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
Other Information: VOLITILE ORGANIC CONTENT AS LISTED ON MSDS, VOC (EPA METHOD
24) 8.6%.
=======================================================
Transportation Information
=======================================================
Trans ID NO: 113799
Product ID: 56707 PST HIGH TEMPERATURE ANTI-GALLING SEALANT
Review Date: 07/29/1996
Net Unit Weight: UNKNOWN
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: TU
Container QTY: 1
Type Of Container: TUBE
Additional Data: PER MSDS:DOT/IATA:UNRESTRICTED, UN#:NONE, HAZ CLASS:NONE.
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
=======================================================
HAZCOM Label
=======================================================
Product ID: 56707 PST HIGH TEMPERATURE ANTI-GALLING SEALANT
Cage: 05972
Company Name: LOCTITE CORPORATION
Street: 1001 TROUT BROOK CROSSING
Zipcode: 06067-3910
Label Required IND: Y
Date Of Label Review: 07/29/1996
Status Code: C
Label Date: 07/29/1996
Origination Code: F
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: MODERATE EYE IRRITANT. STORE BELOW 100F.CALL LOCTITE
CUSTOMER SERV 800-243-4874 FOR SHELF LIFE INFO.AVOID PROLONGED SKIN
CONTACT.KEEP AWAZY FROM EYES. FIRST AID: INGEST:DO NOT INDUCE VOMITING. KEEP
IN DIVIDUAL CALM. INHAL:DOES NOT APPLY. SKIN:WASH W/WATER. EYE:FLUSH @LEAST
15MINS W/WATER. OBTAIN MED ATTN. FIRE:CARBON DIOXIDE, FOAM, DRY CHEMICAL.
SPILL:SOAK UP IN INERT ABSORBENT. STORE IN PARTLYH FI LLED CLOSED CNTNR TIL
DISPOSAL. DISPO:INCINERATE FOLLOWING EPA & LOC REGS. TARGET ORGANS:CNS,
EYE.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SC-0840 ADHESIVE
CAGE:0DH19
CAGE:0DH19
============= Composition/Information on Ingredients =============
Ingred Name:CYCLOHEXANONE (SARA III)
CAS:108-94-1
RTECS #:GW1050000
Fraction by Wt: 1-10% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 25 PPM
ACGIH TLV:S, 25 PPM; 9394
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:FORMALDEHYDE (SARA III)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: 0.19% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9394
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
CAS:78-93-3
RTECS #:EL6475000
Fraction by Wt: 10% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM
ACGIH TLV:200 PPM/300STEL;9394
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 10% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM; Z-2
ACGIH TLV:S, 50 PPM; 9394
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ACETONE (SARA III)
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 10% %
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:750PPM/1000STEL;9294
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:NON-HAZARDOUS INGREDIENTS
Fraction by Wt: BALANCE
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:NOT GIVEN FOR PRODUCT AS A WHOLE
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:MAY CAUSE MODERATE EYE IRRITATION.
LIQUID CONTACT WILL DRY AND DEFAT THE SKIN. PROLONGED CONTACT MAY
CAUSE DERMATITIS. VAPORS MAY IRRITATE THE NOSE, THROAT AND
RESPIRATORY TRACT AND CAUSE HEADACHES, N AUSEA OR UNCONSCIOUSNESS.
LONG-TERM OVEREXPOSURE MAY CAUSE LIVER AND KIDNEY DAMAGE.
Explanation of Carcinogenicity:CONTAINS F [50-00-0] WHICH IS
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE IRRITATION, SKIN IRRITATION, DERMATITIS,
UPPER RESPIRATORY TRACT IRRITATION, NAUSEA, VOMITING, DIARRHEA,
LIVER/KIDNEY DAMAGE, UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH WITH WATER FOR 15 MINUTES WHILE HOLDING EYELIDS
OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, GET MEDICAL
ATTENTION. IN HALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET
MEDICAL ATTENTION. INGESTION: GET MEDICAL ATTENTION IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:0F,-18C
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE, FOAM
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:THERE IS THE POSSIBILITY OF PRESSURE
BUILDUP IN CLOSED CONTAINERS WHEN HEATED.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN AND REMOVE WITH INERT ABSORBENT. USE
NON-SPARKING TOOLS. KEEP SPILL OUT OF SEWERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS AND FLAME.
AVOID BREATHING VAPORS. USE ONLY WITH ADEQUATE VENTILATION. AVOID
CONTACT WITH EYES, SKIN AND CLOTHING.
Other Precautions:KEEP CONTAINER CLOSED. EMPTIED CONTAINERS RETAIN
VAPOR AND PRODUCT RESIDUE. OBSERVE ALL LABELED SAFEGUARDS UNTIL
CONTAINER IS CLEANED. DO NOT CUT OR WELD ON OR NEAR THIS CONTAINER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS PER
CURRENT 29 CFR 1910.134, INSTRUCTIONS/WARNINGS AND NIOSH RESPIRATOR
SELECTION.
Ventilation:LOCAL EXHAUST AND MECHANICAL (GENERAL) VENTILATION TO
MAINTAIN EXPOSURE LEVELS.
Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO AVOID
SKIN CONTACT. AN EMERGENCY EYE WASH STATION AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
OVEREXPOSURE TO TOLUENE MAY CAUSE FEMALE AND MALE REPRODUCTIVE
DISORDERS, BASED ON TESTS WITH LABORATORY ANIMALS.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:>133F,>56C
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Spec Gravity:< 1
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NON-MISCIBLE
Appearance and Odor:LIQUID
Percent Volatiles by Volume:70 %
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:HEAT, OPEN FLAME
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
UNIDENTIFIED ORGANIC COMPOUNDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:KAOWOOL CERAWOOL BLANKET
CAGE:0UHC8
CAGE:0UHC8
============= Composition/Information on Ingredients =============
Ingred Name:FIBROUS GLASS; (ALUMINOSILICATE) (REFRACTORY CERAMIC FIBER
(RCF))
CAS:65997-17-3
Fraction by Wt: 100%
OSHA PEL:1 FIBER/CC
ACGIH TLV:1 FIBER/CC
Ingred Name:SUPDAT:& 1910.134, RESPECTIVELY. FOR FURTHER INFORMATION,
REFER TO THERMAL CERAMICS' PUBLICATION, "HEALTH & (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2:SAFETY ASPECTS OF REFRACTORY CERAMIC FIBERS," DATED
05/90.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HANDLING RCF PRODUCTS MAY GENERATE
RESPIRABLE PARTICULATES WHICH MAY CAUSE TEMPORARY IRRITATION OR
DISCOMFORT OF THE SKIN, EYES, NOSE, THROAT OR LUNGS AND MAY
AGGRAVATE BRONCHIAL DISORDERS. CHRONIC:LO NG-TERM EXPOSURE TO RCF
CAUSES NO KNOWNCHRONIC HEALTH PROBLEMS IN HUMANS. LIMITED TESTING
W/LABORATORY (EFTS OF OVEREX)
Explanation of Carcinogenicity:REFRACTORY CERAMIC FIBER:IARC, CATEGORY
2B, VOL 43, P 39, 1988.
Effects of Overexposure:HLTH HAZ:ANIMALS HAS PRODUCED CONFLICTING
RESULTS CONCERNING THE POSSIBLE CARCINOGENICITY OF RCF. (IARC
BELIEVES THERE IS SUFFICIENT EVIDENCE OF CARCINOGENICITY IN ANIMALS
BUT INSUFFICIENT DATA IN HUM ANS.)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. INGESTION: DRINK PLENTY OF
WATER. SKIN: WASH WITH MILD SOAP AND WATER. EYES: FLUSH WITH PLENTY
OF WATER. IF IRRITATION PERSISTS, CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE.
================== Accidental Release Measures ==================
Spill Release Procedures:FOLLOW ROUTINE HOUSEKEEPING PROCEDURES.
VACUUMING WITH HEPA FILTER IS PREFERRED. IF SWEEPING IS NECESSARY,
USE A DUST SUPPRESSANT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:PREC TO BE TAKEN AFTER SERVICE & UPON REMOVAL:AS
MANUFACTURED, RCF PROD ARE ALUMINOSILICATES WHICH MAY TRANSFORM
UPON HEATING TO MULTITE & CRISTOBALITE (FORM OF CRYSTALLINE
SILICA). REMOVAL OF RCF PRO D AFTER SERVICE MAY GENERATE (SUPDAT)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR TO PREVENT
INHALATION OF RCF & CRISTOBALITE WHENEVER THERE IS EXPOSURE OF
CONCERN.
Ventilation:LOCAL/MECHANICAL:FOLLOW OSHA STANDARD 29 CFR 1910.94.
Other Protective Equipment:LONG-SLEEVED SHIRTS, LONG PANTS, CAP.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
OTHER PREC:DUST. PRLNG/RPTD INHAL OF RESPIRABLE FREE CRYSTALLINE SILICA
DUST MAY CAUSE DELAYED LUNG INJURY (SILICOSIS). IARC HAS PLACED
CRYSTALLINE SILICA IN CATEGORY 2A. OSHA RECOM TLV & PEL FOR RESP
CRISTOBALITE IS 0.05 MG/M3. APPROP VENT & RESP PROT SHOULD BE
PROVIDED IN COMPLIANCE W/OSHA STDS 29 CFR 1910.94 (ING 2)
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:2.56 ((H2O=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:WOOL-LIKE FIBROUS MATERIAL. NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:NONE.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:WASTES ARE NOT HAZARDOUS WASTES AS DEFINED BY
RCRA (40 CFR 261). COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. METHOD OF DISPOSAL: LANDFILL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:VITAL I CHLORINATED BEADS, 712091
Preparer's Name:PHIL RIVES
CAGE:IO856
CAGE:11392
CAGE:IO856
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM POLYACRYLATE
CAS:25608-12-2
Fraction by Wt: 0.999%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:HYPOCHLOROUS ACID, CALCIUM SALT; (CALCIUM HYPOCHLORITE)
(SARA III)
CAS:7778-54-3
RTECS #:NH3485000
Fraction by Wt: 0.001%
Other REC Limits:N/K
OSHA PEL:0.5 PPM (CL)
ACGIH TLV:0.5 PPM (CL)
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE IRRITATION OF EXPOSED AREA.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SLIGHT IRRITANT EFFECTS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
======================= First Aid Measures =======================
First Aid:INHAL:MOVE TO FRESH AIR & CALL MD. EYE:FLUSH W/COOL WATER FOR
15 MINUTES & CALL MD. SKIN:WASH W/SOAP & WATER. INGEST:GET MEDICAL
ATTENTION.
===================== Fire Fighting Measures =====================
Extinguishing Media:ANY AVAILABLE MEDIUM, ALTHOUGH NON-FLAMMABLE AS
SUPPLIED.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
FIREFIGHTING PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:MAY EMIT CHLORINE GAS. BECOMES SLIPPERY
WHEN WET.
================== Accidental Release Measures ==================
Spill Release Procedures:VACUUM CLEAN SPILLAGE. WET, SWEEP OR WASH
AWAY. THE PRODUCT WILL BECOME SLIPPERY WHEN WET.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:NORMAL HYGIENIC PRACTICES. STORE IN
COOL, DRY PLACE. AVOID CREATING DUST OR BREATHING POWDER. AVOID
SKIN & EYE CONTACT.
Other Precautions:KEEP AWAY FROM CHILDREN. SLIPPERY WHEN WET. WHEN
CONCENTRATIONS OF DUST EXCEED RECOMMENDED TLV, USE NIOSH/MSHA
APPROVED RESPIRATOR. MAY STAIN CARPET, UPHOLSTERY & OTHER FABRICS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR PROLONGED EXPOSURE, USE NIOSH/MSHA APPROVED
RESPIRATOR.
Ventilation:LOCAL EXHAUST, MECHANICAL (GENERAL) AS APPROPRIATE.
Other Protective Equipment:NONE REQUIRED.
Work Hygienic Practices:USE GOOD HOUSEKEEPING PRACTICES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
Spec Gravity:0.9 (H2O=1)
Solubility in Water:NEGLIGIBLE.
Appearance and Odor:WHITE TO PINK COLOR WITH A CHLORINE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OTHER CHEMICALS, ACIDS OR AMMONIA CONTAINING PRODUCTS. HYDROFLUORIC
ACID & CERTAIN ORGANIC COMPOUNDS. STRONG OXIDIZERS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION: CO, CO2,
HYDROCARBONS, COULD EMIT CHLORINE GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:CONSULT CURRENT LOCAL, STATE, AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:LINDE MOLECULAR SIEVE AND MOLSIV
CAGE:DO713
CAGE:22627
CAGE:00334
CAGE:DO713
CAGE:61637
============= Composition/Information on Ingredients =============
Ingred Name:DESICCANT ACITIVATED (SODIUM ALUMINUM SILICATES)
Fraction by Wt: 100%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: DUST MAY IRRITATE EYES, NOSE
AND THROAT. CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:IRRITATION OF EYES,NOSE & TROAT BY DUST.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:IN CASE OF EYE CONTACT, IMMEDIATELY FLUSH EYES WITH PLENTY OF
WATER FOR AT LEAST 15 MINS. IF IRRITATION PERSISTS, SEE A DOCTOR.
===================== Fire Fighting Measures =====================
Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING WHEN FIGHTING A CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:NONE KNOWN.
================== Accidental Release Measures ==================
Spill Release Procedures:SWEEP UP & PLACE IN A WASTE DISPOSAL
CONTAINER. FLUSH AREA WITH WATER. AVOID RAISING DUST.
======================Handling and Storage ======================
Handling and Storage Precautions:CAUSES EYE IRRITATION. BREATHING DUST
MAY BE HARMFUL. MAY CAUSE SKIN IRRITATION. OPEN CONTAINER SLOWLY TO
AVOID DUST. DO NOT GET IN EYES.
Other Precautions:AVOID BREATHING DUST AND PROLONGED CONTACT WITH SKIN.
USE WITH ADEQUATE VENTILATION. KEEP CONTAINER CLOSED. DO NOT
INGEST.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:FOR EXCESSIVE DUSTINESS, WEAR A RESPIRATOR
SELECTED PER OSHA 29CFR1910.134.
Ventilation:LOCAL EXHAUST AND/OR MECHANICAL VENTILATION, SEE OSHA 29
CFR 1910.134.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE.
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:1.1
pH:8-11
Solubility in Water:NEGLIGIBLE
Appearance and Odor:NO ODOR-DEPENDING ON PRODUCT MAY APPEAR AS A BEAD,
PELLET, MESH OR POWDER.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
SUDDEN CONTACT WITH HIGH CONCENTRATIONS OF CHEMICALS HAVING HIGH HEAT
OF ADSORPTION SUCH AS HCL, OLEFINS, ETC.
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:NONE KNOWN
==================== Disposal Considerations ====================
Waste Disposal Methods:BURY IN A LANDFILL IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:NORPAR 13, 133599-00599
CAGE:29667
CAGE:29667
CAGE:29700
============= Composition/Information on Ingredients =============
Ingred Name:PARAFFINIC OILS; (PARAFFINS (PETROLEUM), NORMAL C5-20)
CAS:64771-72-8
Fraction by Wt: 100%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:EXPLO HAZ: EXPLODE. KEEP PROD AWAY FROM IGNIT SOURCES, SUCH
AS HEAT, SPKS, PILOT LIGHTS, STATIC ELEC & OPEN (ING 3)
RTECS #:9999999ZZ
Ingred Name:ING 2: FLAMES. EMPTY CNTNRS RETAIN RESIDUE (LIQ &/OR VAP) &
CAN BE DANGEROUS. DO NOT PRESSURIZE, CUT, WELD, (ING 4)
RTECS #:9999999ZZ
Ingred Name:ING 3: BRAZE, SOLDER, DRILL, GRIND OR EXPOSE SUCH CNTNRS TO
HEAT, FLAME, SPKS, STATIC ELEC OR OTHER SOURCES OF (ING 5)
RTECS #:9999999ZZ
Ingred Name:ING 4: IGNIT; THEY MAY EXPLODE & CAUSE INJURY/DEATH. DO NOT
ATTEMPT TO CLEAN SINCE RESIDUE IS DIFFICULT TO (ING 6)
RTECS #:9999999ZZ
Ingred Name:ING 5: REMOVE. EMPTY DRUMS SHOULD BE COMPLETELY DRAINED,
PROPERLY BUNGED & PROMPTLY RETURNED TO DRUM (ING 7)
RTECS #:9999999ZZ
Ingred Name:ING 6: RECONDITIONER. ALL OTHER CNTNRS SHOULD BE DISPOSED
OF IN ENVIRON SAFE MANNER & I/A/W GOVT REGS. FOR WORK (ING 8)
RTECS #:9999999ZZ
Ingred Name:ING 7: ON TANKS REFER TO OSHA REGS, ANSI Z49.1 & OTHER GOVT
& INDUS REFERENCES PERTAINING TO CLEANING, REPAIRING, (ING 9
RTECS #:9999999ZZ
Ingred Name:ING 8: WELDING OR OTHER CONTEMPLATED OPERATIONS.
RTECS #:9999999ZZ
Ingred Name:EFTS OF OVEREXP: INTO LUNGS DURING INGESTION OR VOMITING
MAY CAUSE MILD TO SEVERE PULMONARY INJURY & POSSIBLY DEATH.
RTECS #:9999999ZZ
Ingred Name:FIRST AID: INJECTION MAY BE MINIMAL/ABSENT, EARLY SURGICAL
TREATMENT W/IN FIRST FEW HRS MAY SIGNIFICANTLY (ING 12)
RTECS #:9999999ZZ
Ingred Name:ING 11:REDUCE ULTIMATE EXTENT OF INJURY. INHAL:IF OVERECOME
BY VAP, REMOVE FROM EXPOS & CALL MD IMMED. IF BRTHG (ING 13)
RTECS #:9999999ZZ
Ingred Name:ING 12:IS IRREGULAR/HAS STOPPED, START RESUSCITATION, ADMIN
OXYGEN IF AVAIL. INGEST:DO NOT INDUCE VOMIT; CALL MD IMMED.
RTECS #:9999999ZZ
Ingred Name:SPILL PROC:BY DIKING/IMPOUNDING. ADVISE AUTHS IF PROD HAS
ENTERED/MAY ENTER SEWERS, WATERCOURSES OR EXTENSIVE (ING 15)
RTECS #:9999999ZZ
Ingred Name:ING 14: LAND AREAS. ASSURE CONFORMITY W/APPLIC GOVT REGS.
CONTINUE TO OBSERVE PRECS FOR VOLAT, COMBUST VAPS (ING 16)
RTECS #:9999999ZZ
Ingred Name:ING 15: FROM ABSORBED MATERIAL.
RTECS #:9999999ZZ
Ingred Name:VENT: SMOKING OR USE OF FLAME OR OTHER IGNITION SOURCES.
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP: AVOID CONTAMINATING REGULAR CLOTHING
WHICH COULD RESULT IN PROLONGED/REPEATED SKIN CONTACT.
RTECS #:9999999ZZ
Ingred Name:HYGIENE PRACT: CONTAMD SHOES & THORO CLEAN & DRY CLEAN
BEFORE REUSE. CLEANSE SKIN THORO AFTER CONTACT, BEFORE (ING 20)
RTECS #:9999999ZZ
Ingred Name:ING 19: BREAKS & MEALS & AT END OF WORK PERIOD. PROD IS
READILY REMOVED FROM SKIN BY WATERLESS HAND CLEANERS (ING 21)
RTECS #:9999999ZZ
Ingred Name:ING 20: FOLLOWED BY WASHING THOROUGHLY WITH SOAP & WATER.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL, RAT) >5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HLTH STUDIES SHOW MANY PETRO
HYDROCARBS & SYNTHETIC LUBRICANTS POSE POTNTL HUMAN HLTH RISKS
WHICH VARY FROM PERSON TO PERSON. AS PREC, EXPOS SHOULD BE MIN.
HIGH VAP CONCS (> APPROX 700PPM, ATTAINABLE AT ELEVATED TEMPS WELL
ABOVE AMBIENT) ARE IRRIT TO EYES & RESP TRACT & MAY CAUSE HDCH,
DIZZ, ANESTH, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: DROW, UNCON & OTHER CNS EFTS INCL
DEATH. PRLNGD/RPTD SKIN CNTCT TENDS TO REMOVE SKIN OILS, POSS
LEADING TO IRRIT & DERM; HOWEVER, BASED ON HUMAN EXPERIENCE & AVAIL
TOX DATA, PROD JUDGED NEIT HER "CORR" NOR "IRRITANT" BY OSHA. EYE
CNTCT MAY CAUSE IRRIT. PROD HAS LOW ORDER OF TOX BUT MINUTE AMTS
ASPIR (ING 10)
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE AN
EXISTING DERMATITIS.
======================= First Aid Measures =======================
First Aid:EYE:FLUSH W/CLEAR WATER FOR AT LEAST 15 MIN & UNTIL IRRIT
SUBSIDES. IF IRRIT PERSISTS, CALL MD. SKIN:REMOVE ANY CONTAMD CLTHG
& WASH SKIN W/SOAP & WATER. LAUNDER/DRY-CLEAN CLTHG BEFORE REUSE.
IF PROD IS INJECTED INTO/UNDER SKIN/INTO ANY PART OF BODY,
REGARDLESS OF APPEAR OF WOUND/ITS SIZE, PERS SHOULD BE EVALUATED
IMMED BY MD AS SURGICAL EMER. EVEN THOUGH INITIAL SYMPS FROM HIGH
PRESS (ING 11)
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>200F,>93C
Lower Limits:1.4%
Upper Limits:8.9%
Extinguishing Media:FOAM, H*2O SPRAY(FOG), DRY CHEM, CO*2 & VAP LIQ
TYPE EXTING AGENTS MAY ALL BE SUITABLE DEPENDING ON SIZE/POTNTL
(SUPDAT)
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. USE
WATER TO KEEP FIRE-EXPOS CNTNRS COOL. IF LEAK/SPILL HAS NOT
IGNITED, USE WATER SPRAY TO DISPERSE (SUPDAT)
Unusual Fire/Explosion Hazard:THIS LIQ IS VOLAT & GIVES OFF INVISIBLE
VAPS. LIQ/VAP MAY SETTLE IN LOW AREAS/TRAVEL SOME DIST ALONG
GROUND/SURF TO IGNIT SOURCES WHERE THEY MAY IGNITE/ (ING 2)
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF & ELIM ALL IGNIT SOURCES. KEEP PEOPLE
AWAY. RECOVER FREE PROD. ADD SAND, EARTH/OTHER SUITABLE ABSORB TO
SPILL AREA. MIN BRTHG VAPS & SKIN CNTCT. VENT CONFINED SPACES. OPEN
ALL WINDOWS & DOORS . KEEP PROD OUT OF SEWERS & WATERCOURSES (ING
14)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP CNTNRS CLSD WHEN NOT IN USE. DO
NOT STORE NEAR HEAT, SPARKS, FLAME OR STRONG OXIDANTS. IN ORDER TO
PREVENT FIRE/EXPLO HAZS, USE APPROP EQUIP.
Other Precautions:TO PVNT FIRE/EXPLO RISK FROM STATIC ACCUM &
DISCHARGE, EFTIVELY GROUND PROD TRANSFER SYS I/A/W NFPA STD FOR
PETRO PRODS. INFO ON ELEC EQUIP APPROP FOR USE W/PROD MAY BE FOUND
IN LATEST EDITION OF NATL ELEC CODE (NFPA-70) AVAIL FROM NFPA.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED SUPPLIED-AIR RESPIRATORY
PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:USE ONLY W/VENT SUFFICIENT TO PVNT EXCEEDING RECOM EXPOS
LIMIT OR BUILDUP OF EXPLO CONCS OF VAP IN AIR. NO (ING 17)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . USE
CHEM-RESISTANT APRON/OTHER IMPERVIOUS CLTHG, IF NEEDED, TO (ING 18)
Work Hygienic Practices:MIN BRTHG VAP/MIST. AVOID PRLNGD/RTPD CNTCT
W/SKIN. REMOVE CONTAMD CLTHG; LAUNDER/DRY-CLEAN BEFORE REUSE.
REMOVE(ING 19)
Supplemental Safety and Health
EXTING MEDIA: SIZE OF FIRE & RELATED CIRCUMSTANCES. PLAN PROT &
RESPONSE STRATEGY THRU CONSULT W/LOC FIRE PROT AUTHS/APPROP
SPECIALISTS. FIRE FIGHT PROC: VAPS & TO PROVIDE PROT FOR PERS
ATTEMPTING TO STOP LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS
AWAY FROM EXPOS. MINIMIZE BRTHG OF GASES, VAP, FUMES OR DECOMP
PRODS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>437F,>225C
Melt/Freeze Pt:M.P/F.P Text:24.8F,-4.0C
Vapor Pres:<0.2 @ 20C
Vapor Density:6.4
Spec Gravity:0.76 @ 15.6C
pH:NEUT
Evaporation Rate & Reference:<0.01 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE; 0.0001%
Appearance and Odor:CLEAR, WATER-WHITE LIQUID; FAINT, PETROLEUM
HYDROCARBON ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS SUCH AS LIQ CHLORINE, CONC O*2, SODIUM HYPOCHLORITE,
CALCIUM HYPOCHLORITE, ETC; SERIOUS EXPLO HAZ.
Stability Condition to Avoid:THIS PRODUCT IS STABLE AND WILL NOT REACT
VIOLENTLY WITH WATER.
Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE,
ALDEHYDES AND OTHER DECOMPOSITION PRODUCTS IN THE CASE OF
INCOMPLETE COMBUSTION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Preparer's Name:DOD HMIS/DGSC-SSH
CAGE:JO772
CAGE:14153
CAGE:JO772
============= Composition/Information on Ingredients =============
Ingred Name:ASBESTOS, CHRYSOTILE
CAS:12001-29-5
RTECS #:CI6478500
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:2 FIBERS/CC; A1;9192
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & STEEL & NICKEL
COMPOSITION
RTECS #:9999999ZZ
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
RTECS #:9999999ZZ
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
================== Physical/Chemical Properties ==================
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
==================== Disposal Considerations ====================
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:775999 ORTHO PERMEAFIX
CAGE:GO537
CAGE:61829
CAGE:GO537
============= Composition/Information on Ingredients =============
Ingred Name:FORMALDEHYDE, FORMALIN (SUSPECTED HUMAN CARCINOGEN BY IARC;
ACGIH; SUSPECTED CARCINOGEN BY NTP; IARC - GROUP 2A) *96-1*
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: 1.78%
OSHA PEL:2 PPM
ACGIH TLV:0.3 PPM )
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:INHIBITORS
Fraction by Wt: <15%
Ingred Name:STABILIZER
Fraction by Wt: <2%
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE SEVERE
IRRITATION OF THE NOSE, THROAT & WINDPIPE. HIGH CONCENTRATIONS HAVE
CAUSED LUNG INJURY, PULMONARY EDEMA, PNEUMONITIS & DEATH.
SKIN/EYES: IRRITATION. INGESTION: MAY CAUSE I RRITATION & SEVERE
PAIN IN THE MOUTH, THROAT, ESOPHAGUS & INTESTINAL TRACT. MASSIVE
DOSES CAN CAUSE LIVER/KIDNEY DAMAGE.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, TINGLING, DRYNESS, REDNESS,
GARLIC-LIKE BREATH, HEADACHE, SEDATION, DIARRHEA, DISTURBANCES,
PAIN, BLURRED VISION, NAUSEA, VOMITING, CRAMPS, CHILLS, DROWSINESS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NEEDED.
SKIN: WASH AREAS THOROUGHLY W/SOAP & WATER. EYES: IMMEIDATELY FLUSH
W/LOW PRESSURE COOL WATER FOR 15 MINS, OPENING TO ENSURE FLUSHING.
INGES TION: REMOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NEEDED. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, FOAM/CO2
Fire Fighting Procedures:WEAR SCBA & PROTECTIVE CLOTHING.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN BY PLACING A SUITABLE ABSORBENT
MATERIAL AROUND THE EDGES & WORK INWARD. CAREFULLY SCOOP UP INTO AN
APPROPRIATE WASTE CONTAINER FOR DISPOSAL.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T USE BEYOND EXPIRATION DATE.
STORE AT ROOM TEMP UNTIL USE.
Other Precautions:CAUTION! PRODUCT IS INTENDED FOR USE W/HUMAN
BLOOD/BLOOD ELEMENTS. ALL BLOOD COMPONENTS & PRODUCTS CONTAINING
BLOOD COMPONENTS SHOULD BE HANDLED & DISPOSED AS IF CAPABLE OF
TRANSMITTING INFECTIOUS AGE NTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF NECESSARY, USE AN APPROPRIATE NIOSH/MSHA
APPROVED FORMALDEHYDE CARTRIDGE RESPIRATOR.
Ventilation:GENERAL & LOCAL EXHAUST, AS A LABORATORY FUME HOOD/OTHER
DESIGNATED AREA.
Other Protective Equipment:LAB COAT, EYE WASH FOUNTAIN & SAFETY SHOWER.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING. USE GOOD HYGIENE PRACTICES.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:1
pH:7.6
Solubility in Water:COMPLETE
Appearance and Odor:AN ORANGE TO YELLOWISH LIQUID A CHARACTERISTIC ODOR
W/A SLIGHT BITTER TASTE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:EXCESSIVE HEATING
Hazardous Decomposition Products:THERMAL: TOXIC & IRRITATING VAPORS,
GASES/FUMES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:DENSFIL PLASTIC OBTURATORS (SIZES 25-40),669297
Kit Part:Y
CAGE:11107
CAGE:11107
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS
Fraction by Wt: 100%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 (ORAL, RAT) IS UNKNOWN.
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:NONE. ACUTE AND CHRONIC-
NO KNOWN HAZARD.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NONE
Medical Cond Aggravated by Exposure:NONE
======================= First Aid Measures =======================
First Aid:NONE
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:AS WITH ANY FIRE, WEAR PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS TO AVOID
INHALATION OF HAZARDOUS DECOMPOSTION PRODUCTS.
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:NO SPECIAL REQUIREMENTS.
Neutralizing Agent:NOT RELEVENT
======================Handling and Storage ======================
Handling and Storage Precautions:NO SPECIAL PRECAUTION IS NEEDED.
Other Precautions:WASH HANDS AFTER HANDLING. KEEP OUT OF REACH OF SMALL
CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:NONE
Other Protective Equipment:NONE
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
KEY1:N1. KIT CONSISTS OF GUTTA PERCHA (PNI: A), GUTTA PERCHA POINTS
(PNI: B), DENSFIL OBUTURATORS, TITANIUM WIRE CORE (PNI: C), DENSFIL
PLASTIC OBTURATORS, SIZES 25 TO 40 (PNI: D) OR DENSFIL PLASTIC O
BTURATORS, SIZES 45-160.
================== Physical/Chemical Properties ==================
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:B.P. Text:536F,280C
Melt/Freeze Pt:M.P/F.P Text:536F,280C
Spec Gravity:1.37 - 1.42
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NONE
Appearance and Odor:SOLID MATERIAL - ESSENTIALLY ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
Conditions to Avoid Polymerization:MAY OCCUR
==================== Disposal Considerations ====================
Waste Disposal Methods:ANY ORDINARY DISPOSAL METHOD. OBSERVE LOCAL,
STATE AND FEDERAL REGULATIONS.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:METHYL RED INDICATOR 0.01% W/V AQUEOUS
CAGE:0E6V4
CAGE:0E6V4
============= Composition/Information on Ingredients =============
Ingred Name:BENZOIC ACID, 2-((4-DIMETHYLAMINO) PHENYLAZO)-; (METHYL
RED). %:1 (W/V) MAX.
CAS:493-52-7
RTECS #:DG8960000
Fraction by Wt: SEE ING
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: MATRIX
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:SKIN & EYE IRRITANT. TARGET
ORGANS: DATA NOT AVAILABLE FOR DILUTE SOLUTIONS &/OR MIXTURES.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:INGEST:CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O2/ARTF RESP) . SKIN: IMMEDIATELY RINSE
W/COPIOUS AMOUNTS OF WATER. EYES:IMMEDIATELY RINSE W/ COPIOUS AMOUN
TS OF WATER FOR AT LEAST 15 MINUTES.
===================== Fire Fighting Measures =====================
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE
================== Accidental Release Measures ==================
Spill Release Procedures:FLUSH SPILL AREA W/COPIOUS AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:TOXICOLOGICAL PROPERTIES UNKNOWN.
MINIMIZE CONTACT W/SKIN & EYES. CAUTION:CAUSES SKIN & EYE
IRRITATION. DO NOT GET IN EYES. AVOID SKIN CONTACT.
Other Precautions:DO NOT HANDLE UNTIL THE MANUFACTURER'S SAFETY
PRECAUTIONS HAVE BEEN READ & UNDERSTOOD.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Other Protective Equipment:APRONS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:N1
Appearance and Odor:DARK COLORED ODORLESS LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Preparer's Name:DOD HMIS/DGSC-SSH
CAGE:JO772
CAGE:14153
CAGE:JO772
============= Composition/Information on Ingredients =============
Ingred Name:ASBESTOS, CHRYSOTILE
CAS:12001-29-5
RTECS #:CI6478500
OSHA PEL:0.2 FIBERS/CC
ACGIH TLV:2 FIBERS/CC; A1;9192
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER & STEEL & NICKEL
COMPOSITION
RTECS #:9999999ZZ
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
RTECS #:9999999ZZ
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
======================= First Aid Measures =======================
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
================== Accidental Release Measures ==================
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
======================Handling and Storage ======================
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
================== Physical/Chemical Properties ==================
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
==================== Disposal Considerations ====================
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
POLLUTANT I/A/W 40CFR61 SUBPART "M" PERTAINING TO ASBESTOS. USE
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HALON 1301,FREON FE 1301
CAGE:03670
CAGE:03670
CAGE:0FA36
============= Composition/Information on Ingredients =============
Ingred Name:TRIFLUOROBROMOMETHANE (HALON 1301) (SARA III)
CAS:75-63-8
RTECS #:PA5425000
Fraction by Wt: >99%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1000 PPM
ACGIH TLV:1000 PPM; 9293
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:(RAT) 2112 MG/L 4 HRS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYES/SKIN:LIQUID CAN CAUSE
FROSTBITE. INHALATION:VAPOR IS HEAVIER THAN AIR & CAN CAUSE
SUFFOCATION. VERY HIGH CONCENTRATIONS CAN CAUSE GIDDINESS,
SHORTNESS OF BREATH, NARCOSIS, CARDIAC IRREGULAR ITIES,
UNCONSCIOUSNESS OR EVEN DEATH. ORAL:NOT LIKELY. CHRONIC- NONE
KNOWN.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:DIZZINESS, IMPAIRED COORDINATION, REDUCED
MENTAL ACUITY AND CARDIAC EFFECTS CAN OCCUR. UNCONSCIOUSNESS OR
EVEN DEATH IN HIGH CONCENTRATIONS WITH LONGER EXPOSURES.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING CARDIAC
DISEASES MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
======================= First Aid Measures =======================
First Aid:OBTAIN MEDICAL HELP IF SYMPTOMS PERSIST. INHALATION:REMOVE TO
FRESH AIR. EYES/SKIN:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES.
HOLD EYELIDS OPEN. TREAT FOR FROSTBITE IF NECESSARY. INGESTION: NOT
LIKE LY. NOTE TO PHYSICIAN:DO NOT GIVE ADRENALINE OR SIMILAR
SYMPTOMATIC DRUGS. DO NOT ALLOW VICTIM TO EXERCISE UNTIL 24 HOURS
FOLLOWING SPECIFIC EXPOSURES. FREEZE BURNS OF MUCOSAL TISSUE CAN
DEVELOP.
===================== Fire Fighting Measures =====================
Extinguishing Media:THIS IS A FIRE EXTINGUISHING AGENT. USE WATER TO
COOL FIRE-EXPOSED CYLINDERS OR OTHER CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND NIOSH-
APPROVED SELF-CONTAINED BREATHING APPARATUS WHEN ENTERING
UNVENTILATED FIRE AREAS WHERE PRODUCT HAS BEEN USED.
Unusual Fire/Explosion Hazard:CONTAINERS ARE EQUIPPED WITH PRESSURE AND
TEMPERATURE RELIEF DEVICES, BUT RUPTURE MAY OCCUR UNDER FIRE
CONDITIONS & MAY PRODUCE TOXIC FUMES IN FIRES OVER 900F.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. VENTILATE HTE AREA. COOL OR
REMOVE HOT METAL SURFACES AND OPEN FLAMES.
Neutralizing Agent:NOT APPLICABLE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE-STORE AS A LIQUIFIED
COMPRESSED GAS IN DOT APPROVED PRESSURE VESSELS AWAY FROM HIGH
TEMPERATURES. KEEP AWAY FROM INCOMPATIBLE MATERIALS.
Other Precautions:AVOID BREATHING VAPORS OR MISTS. DO NOT GET IN EYES,
ON SKIN OR ON CLOTHING. WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. REMOVE CONTAMINATED CLOTHING PROMPTLY. KEEP OUT
OF REACH OF C HILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NON REQUIRED UNDER NORMAL CONDITIONS. IF HIGH
VAPOR OR MIST CONCENTRATIONS EXPECTED, USE NIOSH-APPROVED
RESPIRATOR FOR ORGANIC VAPORS AND MISTS. WEAR SUPPLIED-AIR
RESPIRATOR PROTECTION IN CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment:EYE WASH STATION, EMERGENCY SHOWER, NORMAL
WORK CLOTHING COVERING ARMS AND LEGS
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING OR DRINKING. DO
NOT BREATHE DUSTS. AVOID CONTACT WITH EYES AND SKIN.
Supplemental Safety and Health
USE IN A WELL VENTILATED AREA ONLY. DO NOT RELEASE TO ENVIRONMENT.
================== Physical/Chemical Properties ==================
HCC:G3
Boiling Pt:B.P. Text:-72F,-58C
Decomp Temp:Decomp Text:>900F,>482C
Vapor Pres:10292 @70F
Vapor Density:5.2
Spec Gravity:1.57
Evaporation Rate & Reference:GAS AT ROOM TEMPERATURE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS GAS - SWEET ODOR
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACTIVE METALS AND FIRES INVOLVING METAL HAYDRIDES.
Stability Condition to Avoid:EXCESSIVE HEAT (ABOVE 900F)
Hazardous Decomposition Products:HYDROGEN FLUORIDE & HYDROGEN
BROMIDE.THEY HAVE A SHARP IRRITATING ODOR & IN EVEN LOW
CONCENTRATIONS CAUSE INJURY/ DEATH.
==================== Disposal Considerations ====================
Waste Disposal Methods:RETURN TO DRMO OR MANUFACTURER FOR RECYCLING OR
REUSE.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:T6NW4
CAGE:14655
CAGE:14655
============= Composition/Information on Ingredients =============
Ingred Name:POLYCHLORINATED BIPHENYLS (PCBS) (SARA III)
CAS:1336-36-3
RTECS #:TQ1350000
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
===================== Hazards Identification =====================
Effects of Overexposure:ABSORBED THRU SKIN,LUNGS,INTESTINE.CAUSES
CANCER,LIVER,KIDNEY,STOMACH,EYE,HEARING DISORDER(SUP DATA)
======================= First Aid Measures =======================
First Aid:EYES:FLUSH W/WATER IMMEDIATELY.SKIN:WASH W/SOAP
IMMEDIATELY.INHAL:REMOVE TO FRESH AIR,GIVE ART.RESPIR. AS
NEEDED.INGEST:GET MEDICAL ATTN.GIVE LARGE QTY OF SALT WATER,INDUCE
VOMITING,BUT DO NOT MAKE UN CONSCIOUS PERSON VOMIT.
================== Accidental Release Measures ==================
Spill Release Procedures:USE ABSORBENT & DIKES TO PREVENT
RUNOFF.ISOLATE & NOTIFY PROPER AUTHORITIES.
======================Handling and Storage ======================
Handling and Storage Precautions:STORAGE MUST FOLLOW RCRA REQUIREMENTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:SUPPLIED AIR W/FULL FACEPIECE,HELMET OR HOOD
Ventilation:LOCAL EXHAUST
Other Protective Equipment:FULL CLOTHING TO PREVENT SKIN CONTACT
Supplemental Safety and Health
OVEREXPOS:CAN CAUSE FORMATION OF CYSTS,CAUSES STILLBIRTHS.IRRITATES
EYES,NOSE THROAT.
================== Physical/Chemical Properties ==================
HCC:V1
Appearance and Odor:LIGHT STRAW-COLORED LIQUID,AROMATIC ODOR
================= Stability and Reactivity Data =================
STRONG OXIDIZERS
==================== Disposal Considerations ====================
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-GENERALLY HIGH
TEMPERATURE INCINERATION.ONLY APPROVED DISPOSAL OPERATOR PERMITTED.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HURRI CLEAN F1-40
CAGE:70180
CAGE:70180
============= Composition/Information on Ingredients =============
Ingred Name:SILICIC ACID (H*2SIO*3), DISODIUM SALT; (SODIUM
METASILICATE)
CAS:6834-92-0
RTECS #:VV9275000
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:2-BUTOXYETHANOL
CAS:111-76-2
RTECS #:KJ8575000
OSHA PEL:25 PPM, S
ACGIH TLV:25 PPM, S
Ingred Name:SODIUM HYDROXIDE (SARA III)
CAS:1310-73-2
RTECS #:WB4900000
OSHA PEL:2 MG/M3, C
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFTS ON THE CNS, HEMATOPOIETIC TISSUES, BLOOD,
KIDNEYS & LIVER, ASSOCIATED W/ADMINISTRATION OF ETHYLENE GLYCOL
MONOBUTYL ETHER (EGBE) & ETHYLEN E GLYCOL MONOBUTYL ETHER ACETATE
(EGBEA). (EXTRACTED FROM DHHS (NIOSH) PUBLICATION NO. 90-118) .
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: EYES:CAUSES BURNS. SKIN:CAUSES BURNS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN:REMOVE CONTAM CLTHG & SHOES IMMEDIATELY. WASH AFFECTED
AREA WITH LARGE AMOUNTS OF WATER FOR 15-20 MINUTES. GET MEDICAL
ATTENTION. EYES:WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WATER,
(OCCASION ALLY LIFTING UPPER AND LOWER LIDS) FOR AT LEAST 15
MINUTES. GET MD ATTENTION. INHAL:REMOVE TO FRESH AIR. SUPPORT BRTHG
(GIVE O*2 ARTIFICIAL RESPIRATION) . INGEST: CALL MD IMMEDIATELY .
===================== Fire Fighting Measures =====================
Flash Point:>200F,>93C
Extinguishing Media:USE EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING
FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP SPILL. FLUSH WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH EYES, SKIN AND
CLOTHING.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EYE PROT:FULL LENGTH FACESHIELD .
================== Physical/Chemical Properties ==================
HCC:B3
Solubility in Water:COMPLETE
Appearance and Odor:FLUORESCENT GREEN LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS .
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:X-PANDOTITE
CAGE:95534
CAGE:95534
============= Composition/Information on Ingredients =============
Ingred Name:MAGNESIUM OXIDE
CAS:1309-48-4
RTECS #:OM3850000
OSHA PEL:15 MG/M3 PARTICULATE
ACGIH TLV:10 MG/M3;TDUST; 9293
Ingred Name:CALCIUM CARBONATE; (MARBLE) (LIMESTONE)
CAS:1317-65-3
RTECS #:EV9580000
OSHA PEL:15MG/M3 TDUST;5RDUST
ACGIH TLV:10 MG/M3 TDUST
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
CAS:13463-67-7
RTECS #:XR2275000
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:MAGNESIUM CHLORIDE
CAS:7786-30-3
RTECS #:OM2800000
Ingred Name:NON-HAZARDOUS INGREDIENTS
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION OF DUST MAY CAUSE RESP
IRRIT. ALTHOUGH UNLIKELY, INHAL OF FUMES FROM HEATED MATL MAY CAUSE
METAL FUME FEVER, AN ILLNESS CHARACTERIZED BY DELAYED SYMPTOMS OF
COUGH, MUSCLE PAINS, CHILLS & NA USEA. SKIN IRRIT;
PROLONGED/REPEATED CONTACT MAY CAUSE BURNS. EYE CONTACT IS
IRRITATING & MAY CAUSE DAMAGE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:EYES: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR
AT LEAST 15 MINUTES WHILE HOLDING EYELIDS OPEN. GET PROMPT MEDICAL
ATTENTION. SKIN: WASH AFFECTED AREA WITH LARGE AMOUNTS OF WATER.
GET MED ICAL HELP IF IRRITATION PERSISTS. INHAL: MOVE VICTIM TO
FRESH AIR AND TREAT SYMPTOMATICALLY. INGEST: CONTACT LOCAL POISON
CONTROL CENTER OR MD IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING MATERIALS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PERSONAL PROTECTIVE EQUIPMENT. CAREFULLY
CLEAN UP SPILLED MATERIAL AND PLACE IN DRY CONTAINERS FOR DISPOSAL.
AVOID DUST GENERATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED CONTAINER IN DRY AREA.
Other Precautions:AVOID DUST GENERATION.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF TLV IS EXCEEDED, OR FOR SYMPTOMS OF
OVEREXPOSURE, WEAR A NIOSH/MSHA APPROVED RESPIRATOR FOR DUSTS AND
FUMES.
Ventilation:LOCAL EXHST MAY BE NECESSARY UNDER SOME HANDLING/USE
CONDITIONS. SPECIFIC NEEDS SHOULD BE ADDRESSED BY (SUPP DATA)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
VENT: SUPERVISORY OR HEALTH/SAFETY PERSONNEL.
================== Physical/Chemical Properties ==================
HCC:N1
Spec Gravity:2.63
Solubility in Water:APPRECIABLE
Appearance and Odor:BLUISH-WHITE POWDER; ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, CHLORINE, MAGNESIUM
OXIDE FUME.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
=======================================================
Product ID: SCOTCH-WELD DP-110 B/A PART A GRAY EPOXY ADHESIVE, A
Kit Part: Y
Cage: 1BY21
Proprietary Ind: Y
=======================================================
Contractor Summary
=======================================================
Cage: 76381
Cage: 1BY21
=======================================================
Ingredients
=======================================================
-----------------------------
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE: EXTREMELY IRRIT TO EYES. MAY CAUSE PERMANENT EYE
DAMAGE. DUST FROM GRINDING, CUTTING OR SANDING OPERATIONS ON THE CURED MATL
MAY CAUSE IRRITATION. SKIN: MAY CAUSE SKIN IRRIT. MAY CAUSE AN ALLERGI C SKIN
REACTION IN CERTAIN INDIVIDUALS.INHAL: VAPORS MAY BE IRRIT TO THE RESP SYS.
DUST FROM GRINDING,(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ: CUTTING AND SANDING OPERATIONS
ON THE CURED MATERIAL MAY CAUSE DIGESTIVE SYSTEM IRRITATION.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE: IMMED FLUSH W/LRG AMTS OF WATER FOR AT LEAST 15 MIN, WHILE
HOLDING EYELIDS OPEN. IMMED CALL MD. FLUSHING EYE W/WATER MAY NOT HAVE THE
CAPABILITY OF PREVENTING INJURY. SKIN: IMMED WASH AFFECTED AR EA THORO W/SOAP
AND WATER. INHAL: PROVIDE FRESH AIR. INGEST: DO NOT INDUCE VOMIT. IMMED CALL
A PHYSICIAN OR POISON CONTROL CENTER.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: VENTILATE THE AREA. OBSERVE THE PRECAUTIONS FROM
OTHER SECTIONS. COLLECT SPILLED MATERIALS. PLACE IN U.S. DEPARTMENT OF
TRANSPORTATION APPROVED METAL CONTAINER AND SEAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: MIX PART A W/PART B. COMPLETELY CURE & DISPOSE OF
FULLY CURED WASTE PROD IN A SANITARY LANDFILL. INCINERATE UNCURED BULK PROD
AFTER MIXING W/FLAMM MATL IN AN INDUSTRIAL OR COMMERCIAL FACILITY. DISP SH LD
BE I/A/W APPLIC FED, STATE OR LOC REGS.
Handling And Storage Precautions: FOR INDUST USE ONLY. THIS MATL CONSISTS OF
TWO COMPONENTS. THE PRECS FOR EACH COMPONENT SHOULD BE OBSERVRD WHEN SEPARATE
OR MIXED.
Other Precautions: AVOID EYE CONTACT. AVOID SKIN CNTCT. AVOID EYE CONTACT WITH
OR BREATHING DUST FROM CUTTING, GRINDING OR SANDING OPERATIONS ON THE CURED
MATERIAL. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP OUT OF THE REACH OF
CHILDREN.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: >200F,>93C
Extinguishing Media: CO*2, FOAM, DRY CHEMICAL, WATER.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N) WHEN FIGHTING FIRES INVOLVING THIS MATERIAL.
Unusual Fire/Explosion Hazard: NONE.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NIOSH/MSHA APPROVED DUST MASK.
Ventilation: USE ONLY WITH SUFFICIENT VENT TO MAINTAIN VAPOR CONC BELOW
RECOMMENDED EXPOSURE LIMITS.
Other Protective Equipment: PROTECTIVE CLOTHING AS NECESSARY TO PREVENT SKIN
CONTACT.
Work Hygienic Practices: WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.1 (WATER=1)
Solubility in Water: NIL
Appearance and Odor: BLACK, PASTE, VERY SLIGHT ODOR.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: HEAT IS GENERATED DURING CURE. DO NOT CURE UP A
MASS LARGER THAN 50 GRAMS TO PREVENT THE POSSIBILITY OF EXOTHERM.
Hazardous Decomposition Products: CO, CO*2, SO*2 AND N DECOMPOSITION PRODUCTS
WHEN SUBJECTED TO EXCESSIVE HEAT OR FLAME.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
Product ID: SCOTCH-WELD DP-110 B/A PART A GRAY EPOXY ADHESIVE, A
Cage: 1BY21
Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
Zipcode: 55144-1000
Label Required IND: Y
Date Of Label Review: 07/27/1993
Status Code: C
Label Date: 07/27/1993
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: FOR INDUSTRIAL AND PROFESSIONAL USE ONLY. AVOID EYE
CONTACT. ACUTE: EYES: EXTREMELY IRRITATING. MAY CAUSE PERMANENT EYE DAMAGE.
SKIN: MAY CAUSE IRRITATION. INHAL: VAPORS MAY BE IRRITATING TO RESPIRATO RY
SYSTEM. INGEST: MAY CAUSE DIGESTIVE SYSTEM IRRITATION. CHRONIC: MAY CAUSE
ALLERGIC SKIN REACTION.
=======================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MOBILGREASE 28
Resp. Party Other MSDS Num.:5530626-00
CAGE:6G112
CAGE:6G112
Contract Num:SP0450-00-M-C161
CAGE:0T5C6
============= Composition/Information on Ingredients =============
Ingred Name:1,3-PROPANEDIOL, 2,2-BIS(HYDROXYMETHYL)- OR PENTAERYTHRITOL
CAS:115-77-5
RTECS #:RZ2490000
= Wt:1.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50 > 2000 MG/KG
Health Hazards Acute and Chronic:NO SIGNIFIGANT EFFECTS EXPECTED.
Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Effects of Overexposure:NO SIGNIFIGANT EFFECTS EXPECTED.
Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE
PARTY.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH THOROUGHLY WITH WATER. IF IRRITATION OCCURS, CALL
A PHYSICIAN. SKIN: WASH CONTACT AREAS WITH SOAP AND WATER. HIGH
PRESSURE ACCIDENTAL INJECTION THROUGH THE SKIN REQUIRES IMMEDIATE
MEDICAL A TTENTON FOR POSSIBLE INCISION, IRRIGATION AND/OR
DEBRIDEMENT. INHALATION: NOT EXPECTED TO BE A PROBLEM. INGESTION:
NOT EXPECTED TO BE A PROBLEM. HOWEVER, IF GREATER THAN 1/2
LITER(PINT) INGESTED, IMME DIATELY GIVE 1 TO 2 GLASSES OF WATER AND
CALL A PHYSICIAN, HOSPITAL EMERGENCY ROOM OR POISON CONTROL CENTER
FOR ASSISTANCE. DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:=232.C, 449.6F
EST. (OIL COC).
Extinguishing Media:CARBON DIOXIDE, FOAM, DRY CHEMICAL AND WATER FOG.
Fire Fighting Procedures:WATER OR FOAM MAY CAUSE FROTHING. USE WATER TO
KEEP FIRE EXPOSED CONTAINERS COOL. WATER SPRAY MAY BE USED TO FLUSH
SPILLS AWAY FROM EXPOSURE. PREVENT RUNOFF FROM FIRE CONTROL OR
DILUTION FROM ENTERING STREAMS, SEWERS, OR DRINKING WATER SUPPLY.
FIRES IN ENCLOSED AREAS, FIREFIGHTERS USE SELF-CONTAINED BREATHING
APPARATUS
Unusual Fire/Explosion Hazard:NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:SHOVEL UP AND DISPOSE OF AT AN APPROPRIATE
WASTE DISPOSAL FACILITY IN ACCORDANCE WITH CURRENT APPLICABLE LAWS
& REGULATIONS, & PRODUCT CHARACTERISTICS AT TIME OF DISPOSAL.
PREVENT SPILLS FROM ENTERING STORM SEWERS OR DRAINS & CONTACT WITH
SOIL. REPORT SPILLS AS REQUIRED TO APPROPRIATE AUTHORITIES. US
COAST GUARD REQUIRES REPORTING OF SPILLS THAT COULD ENTER
WATERWAYS. NOTIFY USCG AT 800-424-8802.
Neutralizing Agent:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================Handling and Storage ======================
Handling and Storage Precautions:HIGH PRESSURE INJECTION UNDER THE SKIN
MAY OCCUR DUE TO THE RUPTURE OF PRESSURIZED LINES. ALWAYS SEEK
MEDICAL ATTENTION. DO NOT STORE IN OPEN OR UNLABELED CONTAINERS.
STORE AWAY FROM STRONG OXIDIZING AGENTS OR COMBUSTIBLE MATERIAL.
Other Precautions:NO DATA PROVIDED BY RESPONSIBLE PARTY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NO SPECIAL REQUIREMENT UNDER ORDINARY CONDITIONS
OF USE AND WITH ADEQUATE VENTILATION.
Ventilation:NO SPECIAL REQUIREMENTS UNDER ORDINARY CONDITONS OF USE AND
WITH ADEQUATE VENTILATION.
Other Protective Equipment:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Work Hygienic Practices:GOOD PERSONAL HYGIENE PRACTICES SHOULD ALWAYS
BE FOLLOWED.
Supplemental Safety and Health
NO DATA PROVIDED BY RESPONSIBLE PARTY.
================== Physical/Chemical Properties ==================
HCC:V6
Boiling Pt:>316.C, 600.8F
Vapor Pres:<0.1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:RED GREASE. MILD ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:EXTREME HEAT.
Hazardous Decomposition Products:NITROGEN OXIDES. PHOSPHORUS OXIDES.
CARBON MONOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information===================
Toxicological Information:ORAL TOXICITY (RATS): PRACTICALLY NON-TOXIC
(LD50 >2000 MG/KG). DERMAL TOXICITY (RABBITS): PRACTICALLY
NON-TOXIC (LD50 >2000 MG/KG). INHALATION TOXICITY (RATS): NOT
APPLICABLE - HARMFUL CONCENTRATIONS OF MISTS AND/OR VAPORS ARE
UNLIKELY TO BE ENCOUNTERED. EYE IRRITATION (RABBITS): PRACTICALLY
NON-IRRITATING (DRAIZE SCORE-0 OR GREATER BUT 6 OR LESS). SKIN
IRRITATION (RABBITS): PRACTICALLY NON-IRRIT ATING (PRIMARY
IRRITATION INDEX-0.5 OR LESS). SUBCHRONIC TOXICOLOGY (SUMMARY):
EXTENSIVE EVALUATIONS SHOWED NO ADVERSE EFFECTS. CHRONIC
TOXICOLOGY: FORMULATIONS HAVE NOT CAUSED SKIN SENSITIZATION IN H
UMANS.
===================== Ecological Information =====================
Ecological:ENVIRONEMNTAL FATE AND EFFECTS: NOT ESTABLISHED.
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT IS SUITABLE FOR BURNING IN AN ENCLOSED
CONTROLLED BURNER FOR FUEL VALUE OR DISPOSAL BY SUPERVISED
INCINERATION. SUCH BURNING MAY BE LIMITED PURSUANT TO THE RCRA. IN
ADDITION, THE PRODUCT IS SU ITABLE FOR PROCESSING BY AN APPROVED
RECYCLING FACILITY OR CAN BE DISPOSED OF AT ANY GOVERNMENT APPR
OVED WASTE DISPOSAL FACILITY.
=================== MSDS Transport Information ===================
Transport Information:US DOT: NOT REGULATED BY US DOT. RID/ADR: NOT
REGULATED BY RID/ADR. IMO: NOT REGULATED BY IMO. IATA: NOT
REGULATED BY IATA.
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III: THIS PRODUCT CONTAINS NO
"EXTREMELY HAZARDOUS SUBSTANCES". SARA 311/31 REPORTABLE HAZARD
QUANTITIES: NONE. THIS PRODUCT CONTAINS NO CHEMICALS REPORTABLE
UNDER SARA 313 TOXIC RELEASE PR OGRAM.
Federal Regulatory Information:1,3-PROPANEDIOL,
2,2-BIS(HYDROXYMETHYL)-, CAS# 15-77-5, IS LISTED ON THE FOLLOWING
LISTS: ACGIH: ALL, OSHA Z. RCRA INFORMATION: UNUSED PRODUCT IS NOT
SPECIFICALLY LISTED BY EPA AS A HAZARDOUS WASTE (4 0 CFR PART 261D)
NOR IS IT FORMULATED TO CONTAIN MATERIALS WHICH ARE LISTED WASTES.
IT DOES NOT EXHIBIT THE HAZARDOUS CHARACTERISTICS OF IGNITABILITY,
CORROSIVITY OR REACTIVITY AND IS NOT FORMULATED W ITH CONTAMINANTS
AS DETERMINED BY THE TOXICITY CHARACTERIC LEACHING PROCEDURE
(TCLP). HOWEVER, USED PRODUCT MAY BE REGULATED.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TT-S-711C RED MAHOGANY
Preparer's Name:DOUGLAS KIER
CAGE:DO047
CAGE:DO047
CAGE:0AL09
============= Composition/Information on Ingredients =============
Ingred Name:MINERAL SPIRITS
(VAPOR PRESSURE 2.0 MM HG @ 68 F)
CAS:64475-85-0
RTECS #:PY8240000
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:MINERAL SPIRITS
CAS:68551-16-6
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:NOTICE: REPORTS HAVE ASSOCIATED
REPEATED & PROLONGED OCCUPATIONAL OVER-EXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN & NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING & INHALING TH E CONTENTS MAY BE HARMFUL
OR FATAL.
Effects of Overexposure:INHALE: NASAL & RESPIRATORY IRRI, DIZZI, WEAK,
FATIGUE, NAUSEA, HEADACHE, POSS- IBLE UNCONSC & EVEN ASPHYXIATION.
SKIN: MOD IRRI, DEFATT, DERMATITIS. EYE: RED, IRRI, TEARING,
BLURRED VISION. SWALLOW: GASTRONINTESTINAL IRRI, NAUSEA,
VOMITINGDIARRHEA. ASPIRATION INTO LUNGS CAN CAUSE CHEM PNEUMONITIS
WHICH CAN BE FATAL.
======================= First Aid Measures =======================
First Aid:INHALE: REMOVE TO FRESH AIR. IF BREATH IS DIFFICULT, ADMIN
OXYGEN. IF BREATH HASSTOPED GIVE CPR. KEEP PERSON WARM, QUIET & GET
MED ATTN. EYE: WASH WITH WATER 15 MIN. CONSULT PHYSICIAN. SKIN:
IF IRRI PERSISTS, WASH THOROUGHLY WITH SOAP &WATER, REMOVE & WASH
CLOTHING BEFORE RE-USE. INGEST: DO NOT INDUCE VOMIT. GET MED
ATTN. ASPIRATION INTO LUNGS CAN CAUSE CHEM PNEUMONITIS WHICH CAN BE
FATAL.
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:103 F/39 C
Lower Limits:1.0
Extinguishing Media:USE FOAM, CO2, DRY CHEMICAL, WATER SPRAY OR FOG
Fire Fighting Procedures:CLOSED CONTAIN MAY EXPLODE FROM EXTREME HEAT.
USE WATER FOR COOLING PURPOSES. AVOID SPREADING OF BURNING
LIQUID. SELF-CONTAINED BREATHING APPARATUS IS NEEDED.
Unusual Fire/Explosion Hazard:DON'T APPLY TO HOT SURFACES. KEEP AWAY
FROM HEAT, SPARKS, ELEC EQUIP & OPEN FLAME. DON'T STORE OR MIX
WITH STRONG OXIDANTS. KEEP CONTAINERS TIGHTLY CLOSED.
================== Accidental Release Measures ==================
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. KEEP PEOPLE AWAY.
RE-COVER FREE LIQ. ADD ABSORBENT (SAND, EARTH, ETC.) TO SPILL AREA.
AVOID BREATHING VAPORS. VENT AREA. KEEP OUT OF SEWERS &
WATERCOURSES BY DIKING OR IM- POUND. ADVISE AUTHORITIES IF PRODUCT
HAS ENTERED.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T HANDLE OR STORE NEAR HEAT,
SPARKS, FLAME OR STRONG OXIDANT. ADEQUATE VENTILATION REQUIRED. NO
SMOKING OR OPEN LIGHTS. DON'T TAKE INTERNALLY.
Other Precautions:REMOVE CONTAMINATED CLOTHING, LAUNDER BEFORE RE-USE.
WASH SKIN THOROUGHLY WITH SOAP & WATER AFTER CONTACT. GROUND
CONTAINERS WHEN POURING & LIMIT FREE FALL TO MINIMIZE STATIC CHARGE
BUILD-UP. EMPTY C ONTAINERS MAY BE HAZARDOUS FROM RESIDUE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ORGANIC VAPOR CANISTER OR SUPPLIED-AIR
RESPIRATORY PROTECTION WHEN TLV IS EXCEEDED.
Ventilation:APPLICATION AREAS-PROVIDED WITH SUFFICIENT MECH VENTILATION
W/EXPLOSION PROOF EQUIP TO MAINTAIN EXPOSURE LEVEL BELOW TLV
Other Protective Equipment:PROTECTIVE CREAM WHERE SKIN CONTACT IS
LIKELY. WEAR IMPER- VIOUS CLOTHING & BOOTS TO PREVENT
REPEATED/PROLONGED CONTACT
Work Hygienic Practices:WASH HANDS BEFORE EATING OR USING THE WASHROOM,
SMOKE INSMOKING AREAS ONLY.
Supplemental Safety and Health
DO NOT TAKE INTERNALLY. AVOID PROLONGED CONTACT WITH SKIN OR BREATHING
OF SPRAY MIST. CLOSE CONTAINER AFTER EACH USE. KEEP AWAY FROM
CHILDREN. THIS PRODUCT CON-TAINS NO LEAD PIGMENT. EMPTY CONTAINERS
MAY BE HAZARDOUS FROM RESIDUES/VAPORS &ALL CAUTIONS ON THIS SHEET
APPLY TO THEM.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:314-383 F
Vapor Density:> AIR
pH:NA
Viscosity:10"-25" 4FC
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NEGLIGIBLE
Appearance and Odor:THIN LIQUID, VARIOUS COLORS, MILD ODOR
Percent Volatiles by Volume:65-69
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURE OR DIRECT HEATING
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEATED TO
DECOMP. FUMES MAY CONTAIN CARBON MONOXIDE/DIOXIDE, VARIOUS
HYDROCARBONS, ETC.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS. BEFORE ATTEMPTING CLEAN-UP, REFER TO HAZARD
CAUTION INFORMATION IN OTHER SECTIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ACECAP 97 SYSTEMIC INSECTIDE IMPLANTS
CAGE:0AHD1
CAGE:0AHD1
CAGE:OO504
============= Composition/Information on Ingredients =============
Ingred Name:ACEPHATE, 0,5-DIMETHYL ACETYLPHOSPHORAMIDOTHIOATE
CAS:30560-19-1
RTECS #:TB4760000
Fraction by Wt: 97%
Ingred Name:INERT INGREDIENTS (TYPE NOT SPECIFIED)
Fraction by Wt: 3%
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RATS LD50: 945 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: SLIGHT MEMBRANE IRRITATION W/O
CORNEAL INJURY. SKIN: SLIGHT ERYTHEMA. INHALATION: BREATHING,
IRRITATION TO THE RESPIRATORY TRACT. INGESTION: TOXICITY, &
HARMFUL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES: SLIGHT MEMBRANE IRRITATION W/O CORNEAL
INJURY. SKIN: SLIGHT ERYTHEMA. INHALATION: PROFUSE SWEATING,
CRAMPS, NAUSEA, VOMITING, UNCONSCIOUS, CONVULSIONS, RESPIRATORY
DEPRESSION/CARDIAC ARREST & FA TAL. INGESTION: TOXICITY & HARMFUL.
======================= First Aid Measures =======================
First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINUTES. SKIN: WASH
THOROUGHLY W/SOAP & WATER. INHALATION: MOVE TO FRESH AIR.
INGESTION: GIVE WATER OR MILK TO DRINK. CONSULT MEDICAL PERSONNEL
BEFORE INDUCING VOMI TING. ATROPINE SULFATE IS ANTIDOTAL. PROTOPAM
MAY BE USED W/ATROPINE. OBTAIN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG
Fire Fighting Procedures:MINIMIZE THE AMOUNT OF WATER USED FOR FIRE
FIGHTING. DON'T ENTER ANY ENCLOSED AREA W/O FULL PROTECTIVE
EQUIPMENT, INCLUDING SELF-CONTAINED BREATHING EQUIPMENT.
Unusual Fire/Explosion Hazard:DECONTAMINATE PERSONAL PROTECTIVE
EQUIPMENT/FIRE FIGHTING EQUIPMENT BEFORE REUSE.
================== Accidental Release Measures ==================
Spill Release Procedures:VACUUM W/MACHINES EQUIPPED W/HIGH EFFICIENCY
FILTERS OR SWEEP UP MATERIAL/PLACE IN A DISPOSABLE CONTAINER. SCRUB
CONTAMINATED AREA W/DETERGENT & WATER USING A STIFF BROOM. PICK UP
LIQUID W/OIL DRY, CA T LITTER, CLAY, RAGS OR OTHER ABSORBENT.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATHING SMOKE/MISTS. AVOID
PERSONNEL/EQUIPMENT CONTACT W/FALLOUT/RUNOFF. CONTAIN/ISOLATE
RUNOFF & DEBRIS FOR PROPER DISPOSAL.
Other Precautions:DON'T STORE OR TRANSPORT NEAR FEED OR FOOD. KEEP
PESTICIDE IN ORIGINAL CONTAINER. PRODUCTS OF COMBUSTION FROM FIRES
INVOLVING THIS MATERIAL. MAY BE TOXIC. AVOID CONTACT W/EYES & SKIN.
KEEP OUT OF REAC H OF CHILDREN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:BREATHING THE DUST CAN BE MINIMIZED BY WEARING
AN APPROVED RESPIRATOR FOR PESTICIDES.
Ventilation:IF OPERATING CONDITIONS CREATE HIGH AIRBORNE CONCENTRATIONS
OF THIS MATERIAL, SPECIAL VENTILATION MAY BE NEEDED
Other Protective Equipment:IMPERVIOUS PROTECTIVE CLOTHING
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
REPEATED EXPOSURE MAY RESULT IN DEPLITION OF CHOLINESTERASE.
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:116-192F
Vapor Pres:1.7
Spec Gravity:1.35
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE POWDER W/STRONG CABBAGE-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALINE MATERIALS, HYPOCHLORITE OXIDANT
Hazardous Decomposition Products:NOXIOUS GASES, CO, WATER, OXIDES OF
SULFUR, NITROGEN, PHOSPHORUS, CO
==================== Disposal Considerations ====================
Waste Disposal Methods:CHECK GOVERNMENTAL REGULATIONS & LOCAL
AUTHORITIES FOR APPROVED DISPOSAL OF THIS MATERIAL.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:MAKE A BOND
CAGE:53798
CAGE:53798
============= Composition/Information on Ingredients =============
Ingred Name:NON-HAZARDOUS INGREDIENTS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NO ADVERSE HEALTH EFFECTS EXPECTED.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NO ADVERSE HEALTH EFFECTS EXPECTED.
======================= First Aid Measures =======================
First Aid:SKIN: WASH THOROUGHLY W/SOAP & WATER. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER FOG, FOAM, CO2/DRY CHEMICAL.
Fire Fighting Procedures:WEAR SCBA TO PROTECT AGAINST IRRITATING/TOXIC
FUMES PRODUCED BY BURNING RUBBER-LIKE MATERIALS.
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP ADHESIVE FOR REUSE.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE, BELOW
100F.
Other Precautions:THIS PRODUCT ISN'T RESISTANT TO PETROLEUM TYPE
SOLVENTS. READ & FOLLOW ALL LABEL DIRECTIONS & PRECAUTIONS BEFORE
USING THIS PRODUCT. THESE PRODUCTS ARE INTENDED FOR INDUSTRIAL &
INSTITUTIONAL USE ONLY . NOT FOR HOUSEHOLD USE/RESALE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED
Ventilation:NORMAL VENTILATION IS ADEQUATE
Supplemental Safety and Health
KEEP OUT OF REACH OF CHILDREN.
================== Physical/Chemical Properties ==================
Appearance and Odor:A BLACK, RUBBERY, FLEXIBLE ADHESIVE AVAILABLE IN
ROLLS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE EXPECTED
Stability Condition to Avoid:HEAT >257F.
Hazardous Decomposition Products:BURNING: CO & IRRITATING SMOKE
PRODUCED BY BURNING RUBBER LIKE MATERIALS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PRODUCT IS COMBUSTIBLE. DISPOSE OF LARGE
QUANTITIES IN A NON-TOXIC LAND FILL/INCINERATE W/A SUITABLE
POLYVINYL CHLORIDE FUME SCRUBBER. DISPOSE OF IAW/FEDERAL, STATE &
LOCAL REGULATIONS.
| 0 | eyes_protection_not_mandatory |
===================== Product Identification =====================
Product ID:CALIBRATION GAS,METHANE 2.5% IN AIR
CAGE:05083
CAGE:05083
============= Composition/Information on Ingredients =============
Ingred Name:METHANE
CAS:74-82-8
RTECS #:PA1490000
Fraction by Wt: 2.5%
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:ASPHYXIANT; 9394
Ingred Name:AIR, REFRIGERATED LIQUID; AIR COMPRESSED (UN1002, DOT); AIR
REFRIGERATED LIQUID (CRYOGENIC LIQUID) (UN1003) (DOT)
RTECS #:AX5271000
Fraction by Wt: 97.5%
Other REC Limits:NONE RECOMMENDED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:NONE. ACUTE-
EYE/SKIN:NONE KNOWN OR EXPECTED. INHALATION:NONE. METHANE IS A
NON-TOXIC SIMPLE ASPHYXIANT. THE CONCENTRATION OF METHANE IN THIS
MIXTURE IS TOO LOW TO DEPRESS OXYGEN CONCENT RATION. INGESTION:NOT
APPLICABLE. THIS IS A GAS. CHRONIC- NONE KNOWN OR EXPECTED. METHANE
IS A NON-TOXIC GAS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NONE
Medical Cond Aggravated by Exposure:NONE KNOWN OR EXPECTED.
======================= First Aid Measures =======================
First Aid:NONE NEEDED.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:-306F,-188C(CH4)
Lower Limits:5% (METHANE)
Upper Limits:15% (METHAN)
Extinguishing Media:THIS GAS IS NOT FLAMMABLE (2.5% METHANE IN AIR;
LEL=5%). COOL FIRE-EXPOSED CONTAINERS WITH WATER.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING & NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS OPERATED IN + PRESSURE MODE. USE
SHIELDING TO PROTECT FROM CYLINDER EXPLOSION.
Unusual Fire/Explosion Hazard:COMPRESSED AIR/METHANE MIXTURES AT HIGH
PRESSURE WILL ACCELERATE BURNING OF OTHER MATERIALS. GAS CYLINDERS
EXPOSED TO FIRE MAY VENT RAPIDLY OR EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:NONE NEEDED. THIS MATERIAL IS NON-TOXIC AND
NON-FALMMABLE.
Neutralizing Agent:NOT RELEVENT
======================Handling and Storage ======================
Handling and Storage Precautions:STORE CYLINDERS SECURE, AWAY FROM HEAT
& FLAME. STORE IN COOL AREA. STORAGE TEMPERATURE SHOULD NOT EXCEED
130F(54C).
Other Precautions:DO NOT DROP CYLINDERS. WASH HANDS AFTER HANDLING
CYLINDERS. PROTECT FROM PHYSICAL DAMAGE. FOR ADDITIONAL HANDLING
RECOMMENDATION ON COMPRESSED CYLINDERS, CONSULT COMPRESSED GAS
ASSOCIATION PAMPHELET P -1.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NEEDED.
Ventilation:NO SPECIAL VENTILATION REQUIRED.
Other Protective Equipment:SAFETY SHOES AND HEARING PROTECTION
Work Hygienic Practices:USE PROPER CARE WHEN HANDLING CYLINDERS. CLOSE
CYLINDER VALVES WHEN NOT IN USE/EMPTY. DO NOT DEFACE CYLINDERS OR
LABELS.
Supplemental Safety and Health
CONTENTS UNDER PRESSURE. DO NOT PUNCTURE. NEVER THROW CONTAINER INTO
FIRE OR INCINERATOR. USE A PRESSURE REGULATOR WHEN CONNECTING TO
LOWER PRESSURE PIPING SYSTEMS. USE A CHECK VALVE TO PREVENT BACKFL
OW.
================== Physical/Chemical Properties ==================
HCC:G3
NRC/State Lic Num:NOT RELEVENT
Boiling Pt:B.P. Text:-260F (CH4)
Vapor Pres:GAS @ 20C
Vapor Density:0.991
Spec Gravity:0.673 KG/M3
Evaporation Rate & Reference:GAS
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS, ODORLESS, TASTELESS COMPRESSED GAS IN
CYLINDER
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, FLAMES
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ACETIC ACID, REAGENT GRADE
CAGE:19898
CAGE:18873
CAGE:19898
============= Composition/Information on Ingredients =============
Ingred Name:ACETIC ACID (SARA III)
CAS:64-19-7
RTECS #:AF1225000
Fraction by Wt: 99.9%
OSHA PEL:10 PPM
ACGIH TLV:10 PPM/15 STEL; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Effects of Overexposure:SKIN/EYES:CAUSES BURNS;INH:IRRIT/BURNS RESP
TRACT;VAPORS/MIS ARE EXTREMELY IRRITG & CAUSE BURNS.
======================= First Aid Measures =======================
First Aid:SKIN:WASH W.SOAP & H*2O EYES:FLUSH W. H*2O. INGESTED:GIVE 2
GLASSES H*2O; INDUCE VOMITING.CALL A PHYSICIAN. INHALE:REMOVE TO
FRESH AIR. GIVE CPR/OXYGEN IF NEED. KEEP WARM & QUIET. REMOVE
CONTAMINATED CLOTHING. IF UNCONS DO NOT TAKE ANYTHINGBY MOUTH.
===================== Fire Fighting Measures =====================
Flash Point:109F,43C CC
Lower Limits:5.4
Upper Limits:16.0
Extinguishing Media:USE LARGE VOLUME OF WATER,DRY CHEMICAL OR CO*2.
Fire Fighting Procedures:WEAR SELF-CNTD BRTHG,APP H*20 SPRAY TO COOL
CONTR.
Unusual Fire/Explosion Hazard:CONTACT W/CERTAIN METALS PRODUCE H*2
GAS.EMITS CO,CO*2,ACETIC ANHYDRIDE WHEN BURNED.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE IGNITION SOURCES. STOP LEAK W/O
RISK. EVACUATE AREA. SM SPILL:ABSORB WITH INERT ABSORBENT,FLUSH
AREA WITH WATER. LG SPILL:NEUTRALIZE WITH SODA ASH. FLUSH
NEUTRALIZED SOLUTION TO SEWER IN ACC ORDANCE WITH INTERNATIONAL
FED,STA, & LOCAL REGS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENTILATED
AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT. KEEP
CONTAINERS TIGHTLY CLOSED
Other Precautions:AVOID BREATHING VAPORS.MISTS/VAP HARMFUL IF INHLD;USE
W/ADEQUATE VENTILATION;REMOVE CAPS OR OTHER CLOSURES CAREFULLY TO
AVOID SPURTING;WASH HANDS & CONTAINERS THOROUGHLY AFTER HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE NEEDED IN NORMAL CONDITIONS;HOWEVER,USE
NIOSH APPRVD IF NEEDED.
Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE
VENTILATION
Other Protective Equipment:CHEM RESISTANT BOOTS,CLOTHING,EYE SHOWER
ALSO REQD.
Supplemental Safety and Health
MSDS FM MFR UNDATED;SPEC REFERENCE:O-C-265B.
================== Physical/Chemical Properties ==================
HCC:F6
Boiling Pt:B.P. Text:245F/118C
Vapor Pres:11
Vapor Density:2.1
Spec Gravity:1.05
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR,COLORLESS LIQUID, STRONG VINEGAR-LIKE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
FLAMMABLES, OXIDIZERS
Stability Condition to Avoid:HEAT, IGNITION SOURCES
Hazardous Decomposition Products:CO,CO*2,ACETIC ANHYDRIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP IN COVERED DRUMS,PENDING DISPOSAL. HANDLE &
DISPOSE IN FULL COMPLIANCE WITH ALL APPLICABLE
INTERNATIONAL,FEDERAL,STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:SODIUM SULFATE(2295)
CAGE:1L168
CAGE:1L168
CAGE:1L164
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM SULFATE;CAS.NO.7757-82-6
CAS:7757-82-6
RTECS #:WE1650000
Fraction by Wt: >99%
===================== Hazards Identification =====================
Effects of Overexposure:INHAL:DUST/MIST IRRITATES NOSE,THROAT &
LUNGS;EYES:IRRITATES;SKIN:IRRITATES PROLNGED EXPOSURE;
======================= First Aid Measures =======================
First Aid:EYES:FLUSH PROMPTLY W/PLENTY OF WATER(15 MIN. MINIM).GET
MEDICAL ATTENTION;INGESTION:DRINK WATER,INDUCE VOMITING & GET MED.
ATTN.;SKIN:WASH W/PLENTY OF WATER;INHALATION:FOR IRRITATION OR
DISCOMFORT,GE T MEDICAL ATTENT.
===================== Fire Fighting Measures =====================
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF-CNTND BRTHG APP
Unusual Fire/Explosion Hazard:WHEN HEATED TO DECOMPOSITION,EMITS TOXIC
FUMES OF SO*X(OXIDES OF SULFUR)
================== Accidental Release Measures ==================
Spill Release Procedures:SCOOP OR SWEEP UP DRY CHEMICAL FOR USE OR
DISPOSAL & PLACE IN A SUITABLE CONTAINER. FLUSH RESIDUE WITH WATER
TO AN AUTHORIZED DRAIN IF ENVIRONMENTAL REGULATIONS PERMIT.
======================Handling and Storage ======================
Handling and Storage Precautions:STOREINA COOL,DRY PLACE.AVOID CONTACT
W/EYES SKIN & CLOTHING.AVOID BREATHING DUST. WASH THOROUGHLY AFTER
HANDLING;DO NOT WEAR CONTACT LENSES.
Other Precautions:NONE NOTED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE REQUIRED,USE A NIOSH APPROVED RESPIRATOR
FOR DUSTS.
Ventilation:LOCAL VENTILATIN IF DISTY CONDITIONS PREVAIL
Other Protective Equipment:AS REQUIRED TO PREVENT PROLONGED CONTACT.
Supplemental Safety and Health
MSDS DATE:6/78 & 9/81.
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:>1472F MELT
Spec Gravity:2.68
Solubility in Water:17% @ 20C
Appearance and Odor:WHIT CRYSTALLINE GRANULES/POWDER;ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MOLTEN ACTIVE METALS,INCLUDING ALUMINUM OF MAGNESIUM.
Stability Condition to Avoid:DECOMPOSITION OF PRODUCT VIA HEAT.
Hazardous Decomposition Products:TOXIC FUMESOF XO*X WHEN HEATED TO
DCEOMPISITION
==================== Disposal Considerations ====================
Waste Disposal Methods:FLUSH SPILL RESIDUE WITH WATER TO AN AUTHORIZED
DRAIN FI ALLOWED BY ENVIROMNENTAL REGULATIONS; DISPOSE OF BY MEANS
AS TO COMPLY W/LOCAL,STATE & FEDERAL REGULATION.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:3669 SPRED HOUSE DURA-FLAT FINISH
CAGE:01PD6
CAGE:72818
CAGE:01PD6
============= Composition/Information on Ingredients =============
Ingred Name:WEIGHT PER GALLON IN POUNDS: 11.2
RTECS #:9999999WG
Ingred Name:FORMALDEHYDE, FORMALIN (2A CARCINOGEN BY NTP, IARC, OSHA)
INTENDED CHANGE
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: <0.1%
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM; A2; 9293
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:GLYCOL ETHERS, DIETHYLENE GLYCOL, 2,2-OXYBISETHANOL
CAS:111-46-6
RTECS #:ID5950000
Fraction by Wt: 5-10%
Ingred Name:TITANIUM DIOXIDE, TIO2
CAS:13463-67-7
RTECS #:XR2275000
Fraction by Wt: 10-20%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Ingred Name:ZINC OXIDE
CAS:1314-13-2
RTECS #:ZH4810000
Fraction by Wt: 5-10%
OSHA PEL:15MG/M3 TDUST/5 FUME
ACGIH TLV:10MG/M3 TDUST; 9293
Ingred Name:ACRYLIC COPOLYMER
Fraction by Wt: 5-10%
Ingred Name:TALL OIL FATTY ACIDS, PENTAERYTHRITOL, ISOPHTHALIC ACID
POLYMER*92-3*
CAS:67746-05-8
Fraction by Wt: 1-5%
Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 40-50%
Ingred Name:CLAY (KAOLIN)
CAS:1332-58-7
RTECS #:GF1670500
Fraction by Wt: 10-20%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:2 MG/M3 TDUST; 9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY TRACT
IRRITATION. SKIN/EYES: IRRITATION. INGESTION: LARGE AMOUNTS COULD
CAUSE SERIOUS INJURY.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:INHALATION: MUCOUS MEMBRANE IRRITATION,
DROWSINESS, DIZZINESS, &/OR LIGHTHEADEDNESS, HEADACHE, NAUSEA,
ALLERGIC SENSITIZATION. SKIN: DERMATITIS, DIZZINESS, &/OR
LIGHTHEADEDNESS, HEADACHE, NAUSEA. MAY BE ABSORBED.
Medical Cond Aggravated by Exposure:EYES, SKIN, RESPIRATORY, LUNG,
KIDNEY, LIVER & NERVOUS SYSTEM DISORDERS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED
BREATHING. HAVE TRAINED PERSON GIVE OXYGEN IF NECESSARY. SKIN: WASH
OFF QUICKLY W/PLENTY OF WATER, THEN SOAP & WATER. EYES: FLUSH
W/PLENTY OF WATER FOR AT LEAST 15 MINS. INGESTION: OBTAIN MEDICAL
ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:>200F
Extinguishing Media:DRY CHEMICAL OR FOAM
Fire Fighting Procedures:CLOSED CONTAINERS MAY BURST IF EXPOSED TO
EXTREME HEAT OR FIRE.
Unusual Fire/Explosion Hazard:WATER MAY BE USED TO COOL & PROTECT
EXPOSED CONTAINERS.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. COLLECT SPILLS W/ABSORBENT
MATERIAL.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE <100F. KEEP FROM FREEZING. USE
ONLY W/ADEQUATE VENTILATION. KEEP CONTAINERS TIGHTLY CLOSED &
UPRIGHT WHEN NOT IN USE. DON'T TAKE INTERNALLY.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT W/SKIN,
EYES & BREATHING OF VAPORS. AVOID CONDITIONS WHICH RESULT IN
FORMATION OF INHALABLE PARTICLES SUCH AS SPRAYING OR ABRADING
(SANDING) PAINTED SURFAC ES.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE ONLY NIOSH/MSHA APPROVED RESPIRATORS
Ventilation:DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP
OF VAPORS.
Other Protective Equipment:EYE WASH, SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING, BEFORE EATING OR
SMOKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text: 212F
Percent Volatiles by Volume:72.1%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, HYDROFLUORIC ACID
Stability Condition to Avoid:ELEVATED TEMPERATURES
Hazardous Decomposition Products:CO, CO2
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/ALL APPLICABLE
REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:CAUSTIC SODA, LYE, SODIUM HYDRATE, 6482
CAGE:DO242
CAGE:63612
CAGE:DO242
============= Composition/Information on Ingredients =============
Ingred Name:SODIUM HYDROXIDE (CERCLA)
CAS:1310-73-2
RTECS #:WB4900000
Fraction by Wt: 100%
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3, C
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:SUPP DATA:SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
RTECS #:9999999ZZ
Ingred Name:OTHER PROT EQUIP:WHEN HANDLING THIS MATERIAL. SAFETY
EQUIPMENT SHOULD BE READILY AVAILABLE.
RTECS #:9999999ZZ
Ingred Name:EYE PROT:& FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXTREMELY TOXIC & CORROSIVE. CAUSES
SEVERE BURNS ON CONTACT W/BODY TISSUE. VAPOR IRRITATING TO EYES &
RESPIRATORY PASSAGES. TESTS ON LABORATORY ANIMALS INDICATE MATERIAL
MAY PRODUCE ADVERSE MUTAGENIC EFFECTS. CITED IN RTECS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:DATA NOT AVAILABLE.
======================= First Aid Measures =======================
First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE.
SKIN:IMMEDIATELY FLUSH THORO W/LARGE AMOUNTS OF WATER. REMOVE
CONTAMINATED CLOTHING & WASH BEFORE REUSE. EYES:IMMEDIATELY FLUSH
THORO W/WATER FOR AT LEAST 15 MINUTES. INHAL:REMOVE TO FRESH AIR;
GIVE ARTF RESP IF BREATHING HAS STOPPED. INGEST:DO NOT INDUCE
VOMITING; IF CONSCIOUS, GIVE WATER FREELY & GET MEDICAL ATTENTION.
===================== Fire Fighting Measures =====================
Flash Point:NONCOMBUSTIBLE
Extinguishing Media:FLOOD W/WATER, USING CARE NOT TO SPLATTER OR SPLASH
MATERIAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CAN REACT W/CERTAIN METALS (AL, SN, MG,
CU, ETC) TO RELEASE EXPLOSIVE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA OF ALL UNNEC PERS. WEAR SUITABLE
PROT EQUIP LISTED UNDER EXPOS/PERSONAL PROT SECTION. ELIM ANY IGNIT
SOURCES UNTIL AREA IS DETERMINED TO BE FREE FROM EXPLO/FIRE HAZS.
CONTAIN RELS & ELIM ITS SOURCE, IF THIS CAN BE DONE W/OUT (SUPP
DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:DO NOT BREATHE DUST/VAP. STORE IN DRY,
WELL-VENTED AREA AWAY FROM ACID, METALS, EXPLOIVES, ORG PEROXIDES &
EASILY IGNITABLE MATLS.
Other Precautions:KEEP CNTNR TIGHTLY CLSD. WHILE MAKING SOLN ADD SLOWLY
TO SURF OF SOLN TO AVOID VIOLENT SPLATTERING. DO NOT GET IN EYES,
ON SKIN/ON CLTHG. RETAINED RESIDUE MAY MAKE EMPTY CNTNRS HAZ; USE
CAUT. DO NOT T AKE INTERNALLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOS LIM(S) OF PROD/ANY COMPONENT
IS EXCEEDED, NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS ADVISED IN
ABSENCE OF PROPER ENVIRON CONTROL. OSHA REGS ALSO PERMIT OTHER
NIOSH/MSHA APPRVD RESPS (N EG PRESS TYPE) UNDER SPECIFIED (SUPDAT)
Ventilation:MATERIAL SHOULD BE HANDLED OR TRANSFERRED IN AN APPROVED
FUME HOOD OR W/ADEQUATE VENTILATION.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . PROT CLTHG (IMPERVIOUS) SHOULD BE WORN (ING
3)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
SPILL PROC:RISK. TAKE UP & CONTAINERIZE FOR PROPER DISP AS DESCRIBED
UNDER DISP SECTION. COMPLY W/FED, STATE & LOC REGS ON REPORTING
RELS. RQ: SODIUM HYDROXIDE - 1000 LBS. REFER TO REGULATORY INFO FOR
OTHER REGULATORY DATA. RESP PROT:CNDTNS (SEE YOUR SAFETY EQUIP
SUPPLIER). ENGINEERING &/OR ADMIN CONTROLS (ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:2534F,1390C
Melt/Freeze Pt:M.P/F.P Text:605F,318C
Spec Gravity:2.13 (H*2O=1)
Solubility in Water:SOLUBLE
Appearance and Odor:WHITE, DELIQUESCENT PELLETS, FLAKES OR GRANULES;
ODORLESS.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, ACIDS, CHLORINATED HYDROCARBONS, METALS, ORGANIC MATERIALS.
Stability Condition to Avoid:CONTACT W/MOISTURE MAY GENERATE SUFFICIENT
HEAT TO IGNITE SURROUNDING COMBUSTIBLE MATERIAL.
Hazardous Decomposition Products:NONE INDICATED.
==================== Disposal Considerations ====================
Waste Disposal Methods:MATL DOES NOT HAVE EPA WASTE NUMBER & IS NOT A
LISTED WASTE, HOWEVER CONSULTATION W/PERMITTED WASTE DISP SITE
(TSD) SHOULD BE ACCOMPLISHED. ALWAYS CONT A PERMITTED WASTE
DISPOSER (TSD) TO ASSURE COMPL IANCE W/ALL CURRENT LOC, STATE & FED
REGS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:HYPOCHLORITE VACUETTES, R-5805
CAGE:7K791
CAGE:7K791
============= Composition/Information on Ingredients =============
Ingred Name:FORMALDEHYDE; (FORMALDEHYDE SOLUTION 37%) (SARA 302/313)
(CERCLA)
CAS:50-00-0
RTECS #:LP8925000
Fraction by Wt: <0.2%
OSHA PEL:SEE 1910.1048
ACGIH TLV:C 0.3 PPM, A2
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
Ingred Name:POTASSIUM PHOSPHATE, MONOBASIC
CAS:7778-77-0
Fraction by Wt: 2.0%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:METHANOL (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 4.0%
OSHA PEL:S, 200 PPM
ACGIH TLV:S,200PPM/250STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:WATER; (DEIONIZED WATER)
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: >93%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:OTHER COMPONENTS
Fraction by Wt: <1.0%
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE:IRRITATION. CHRONIC:IRRITATION
AND SENSITIZATION DERMATITIS.
Explanation of Carcinogenicity:FORMALDEHYDE:IARC MONOGRAPHS, SUPP, VOL
7, PG 211, 1987:GROUP 2A. NTP 7TH ANNUAL RPT ON CARCINS, 1994:ANTIC
(SUPP DATA)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:MAY CAUSE IRRITATION TO EYES, SKIN
AND MUCOUS MEMBRANES.
======================= First Aid Measures =======================
First Aid:EYE CONTACT:IMMEDIATELY FLUSH EYES WITH WATER FOR AT LEAST 15
MINUTES. SKIN CONTACT:IMMEDIATELY FLUSH SKIN WITH WATER FOR AT
LEAST 15 MINUTES. INGESTION:SEEK MEDICAL ATTENTION.
INHALATION:REMOVE TO FR ESH AIR.
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMICAL OR CARBON DIOXIDE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
================== Accidental Release Measures ==================
Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. PLACE IN
SMALL CONTAINERS FOR DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
======================Handling and Storage ======================
Handling and Storage Precautions:PRODUCT SHOULD BE STORED IN DARK AND
AT ROOM TEMP; HOWEVER, TEMPS UP TO 120F OR EVEN BELOW FREEZING WILL
NOT NORMALLY AFFECT REAGENT PERFORMANCE.
Other Precautions:IF THIS PRODUCT IS USED AS DIRECTED, THE USER WILL
NOT COME IN CONTACT WITH OR BE EXPOSED TO ANY OF ITS CHEMICAL
COMPONENTS. AVOID CONTACT WITH EYES. FRAGILE:LIQUID IN GLASS.
HANDLE WITH CARE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EXPLAN OF CARCIN:TO BE CARCINOGEN. OSHA REGULATED:CFR 29 1910.1048.
ANIMAL:NASAL TUMORS.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:203F,95C
Melt/Freeze Pt:M.P/F.P Text:32.0F,0.0C
Spec Gravity:1 (H*2O=1)
pH:4
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID; NO ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NONE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE
& LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:POTASSIUM CHLORIDE, 5596
Resp. Party Other MSDS Num.:P5631
CAGE:70829
CAGE:70829
============= Composition/Information on Ingredients =============
Ingred Name:POTASSIUM CHLORIDE
CAS:7447-40-7
RTECS #:TS8050000
= Wt:100.
Other REC Limits:N/K
OSHA PEL:15 MG/M3
OSHA STEL:N/K
ACGIH TLV:10 MG/M3
ACGIH STEL:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: INHALATION OF HIGH
CONCENTRATIONS OF DUST MAY CAUSE NASAL OR LUNG IRRITATION.
INGESTION: LARGE QUANTITIES CAN PRODUCE GASTROINTESTINAL IRRITATION
AND VOMITING. MAY PRODUCE WEAKNESSAND CIRCULATORY PROBLEMS. MAY
AFFECT HEART. IN SEVERE CASES, INGESTION MAY BE FATAL. SKIN:
CONTACT MAY CAUSE IRRITATION OR RASH, PARTICULARLY WITH MOIST SKIN.
EYES: POTASSIUM CHLORIDE IS A MODERATE EY E IRRITANT. REDNESS,
TEARING, POSSIBLE ABRASION CAN OCCUR. CHRONIC: NO INFORMATION
FOUND.
Medical Cond Aggravated by Exposure:
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL
PERSONNEL. NEVER G IVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
CALL A PHYSICIAN. SKIN: REMOVE ANY CONTAMINATED CLOTHING. WASH SKIN
WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. GET MEDICAL ATTENTION
IF IRRITATION DEV ELOPS OR PERSISTS. EYES: IN CASE OF CONTACT,
IMMEDIATELY FLUSH EYES WITH PLENTY OF WATER FOR AT LEAST 15
MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. CALL A
PHYSICIAN IF IRRITATION PERSISTS.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE HAZARD. NOT
CONSIDERED TO BE AN EXPLOSION HAZARD.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR
APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN CONTROL
MEASURES SECTION. PICK UP AND PLACE IN A SUITABLE CONTAINER FOR
RECLAMATION OR DISPOSAL, USING A METHOD THAT DOES NOT GENERATE
DUST.
======================Handling and Storage ======================
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTAINER,
STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL
DAMAGE. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY
SINCE THEY RETAIN PRODUCT RESIDUES(DUST, SOLIDS); OBSERVE ALL
WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT.
Other Precautions:AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH
ADEQUATE VENTILATION. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD
HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO 10 TIMES EXPOS
LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP
SUPPLIER, WHICHEVER IS LOWEST. A NIOS H APPRVD FULL-FACE PIECE
DUST/MIST RESP MAY BE WORN UP TO 50 TIMES EXPOS LIM/MAX USE CONC
SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (SUP DAT)
Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS
BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF BECAUSE IT
CAN CTL EMISSIONS OF (OTHER INFO)
Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE
SHOWER . WEAR CLEAN BODY-COVERING CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
RESP PROT: WHICHEVER IS LOWEST. FOR EMERS/INSTANCES WHERE EXPOS LEVELS
ARE NOT KNOWN, USE A NIOSH APPRVD FULL-FACEPIECE POS-PRESS,
AIR-SUPPLIED RESP. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT
WORKER S IN OXYGEN-DEFICIENT ATMS. PHYSICAL/CHEM PROPERTIES:
DENSITY: 1.987; PH: CA. 7 SATURATED AQ. SL. @ 15C.
================== Physical/Chemical Properties ==================
Boiling Pt:=1500.C, 2732.F
B.P. Text:SUBLIMES
Melt/Freeze Pt:=772.2C, ######F
pH:SEE SUP DAT
Solubility in Water:28.1 G/100G OF WATER @ 0C
Appearance and Odor:WHITE CRYSTALS OR POWDER; ODORLESS.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BROMINE TRIFLUORIDE; POTASSIUM PERMANGANATE PLUS SULFURIC ACID.
Stability Condition to Avoid:NO INFORMATION FOUND.
Hazardous Decomposition Products:OXIDES OF THE CONTAINED METAL AND
HALOGEN, POSSIBLY ALSO FREE, OR IONIC HALOGEN.
=================== Toxicological Information===================
Toxicological Information:ORAL RAT LD50: 2600 MG/KG; IRRITATION EYE
RABBIT (STANDARD DRAIZE): 500 MG/24 HR MILD; INVESTIGATED AS A
MUTAGEN.
===================== Ecological Information =====================
Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL
TOXICITY: NO INFORMATION FOUND.
==================== Disposal Considerations ====================
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE MANAGED IN APPROPRIATE & APPROVED WASTE DISPOSAL
FACILITY. PROCESSING, USE/CONTAMINATION OF PROD MAY CHANGE WASTE
MANAGEMENT OPTIONS. STATE & LOCAL DISP REGULATIONS MAY DIFFER FROM
FEDERAL DISPOSAL REGULATIONS. DISPOSE OF CONTAINER & UNUSED C
ONTENTS I/A/W FEDERAL, STATE & LOCAL REQUIREMENTS.
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED. OTHER INFORMATION: LAB PROTECTIVE
STORAGE). EMERGENCY OVERVIEW: CAUTION! MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE IRRITAT ION TO SKIN, EYES, AND RESPIRATORY TRACT.
===================== Regulatory Information =====================
SARA Title III Information:SARA 302 RQ/TPQ: NOT LISTED. SARA
LIST/CHEMICAL CATG.: NOT LISTED. SARA 311/312: ACUTE: YES; CHRONIC:
NO; FIRE: NO; PRESSURE: NO; REACGIVITY: NO (PURE/SOLID).
Federal Regulatory Information:POTASSIUM CHLORIDE LISTED IN TSCA, EC,
JAPAN, AUSTRALIA, KOREA, CANADA DSL; NOT LISTED IN CANADA NDSL,
CERCLA, RCRA 261.33, TSCA 8 (D). CHEMICAL WEAPONS CONVENTION: NO.
TSCA 12 (B): NO. CDTA: NO. AUST RALIAN HAZCHEM CODE: NO INFORMATION
FOUND. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS: THIS MSDS HAS
BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED
PRODUCTS REGULATIONS (CPR) AND T HE MSDS CONTAINS ALL OF THE
INFORMATION REQUIRED BY THE CPR.
State Regulatory Information:POTASSIUM CHLORIDE LISTED IN PHILADELPHIA.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:TT-E-506K GLOSS ENAMEL Y60
Preparer's Name:PATRICIA SHAW
CAGE:HO931
CAGE:3Z268
CAGE:HO931
============= Composition/Information on Ingredients =============
Ingred Name:HYDROCARBON MIXTURE (VAPOR PRESSURE 2.0 MM HG @ 68 F)
CAS:64741-41-9
Fraction by Wt: 30%
Other REC Limits:NONE SPECIFIED
OSHA PEL:500 PPM
ACGIH TLV:100 PPM
Ingred Name:BARIUM SULFATE (SARA 313)
CAS:7727-43-7
RTECS #:CR0600000
Fraction by Wt: 13%
Other REC Limits:NONE SPECIFIED
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: NASAL & RESP IRRIT, NARCOSIS
(CNTRL NERV SYS DEPRESS). EYE: SEVERE IRRIT. SKIN: IRRIT, DEFAT,
DERMATITIS. INGEST: DIGEST TRACT IRRIT, CNTRL NERV SYS DEPRESS.
ASPIRATION HZD. MAT'L ENTER LUNGS ( SWALLOW/VOMIT), CAUSE LUNG
INFLAMM. CHRONIC: CNTRL NERV SYS/RESP SYS/LUNG/EYE/SKIN/GI
TRACT/LIVER/SPLEEN/KIDNEY DAMAGE.
Effects of Overexposure:INHALATION: DIZZINESS, WEAKNESS, FATIGUE,
NAUSEA, AND HEADACHE. EYE: TEARING, REDNESS, AND BLURRED VISION.
Medical Cond Aggravated by Exposure:RESPIRATORY TRACT IRRITATION,
DERMATITIS, NAUSEA.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH W/WATER 15 MIN, OCCASIONALLY LIFTING EYELIDS. GET
MED ATTN. SKIN: REMOVE CONTAMINATED CLOTHING, WASH W/SOAP & WATER.
IF IRRITATION PERSISTS, SEE DR. INHAL: REMOVE TO FRESH AIR. APPLY
ARTIF RESPIRATION/ADMINISTER OXYGEN IF NEEDED. CONSULT DR. INGEST:
UNLESS DIRECTED BY MED PERSONNEL. IF ADVICE UNAVAIL, TAKE TO EMERG
ROOM.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:104F,40C
Lower Limits:1.0
Upper Limits:6.1
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE EXTINGUISHER (NFPA FLAMMABLE LIQ FIRE).
WATER MAY BE INEFFECTIVE, USE AS FOG FOR COOLING. WEAR FULL
PROTECTIVE CLOTHING & BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:VAPORS FORM EXPLOSIVE MIX W/AIR (LEL TO
UEL) WHICH CAN BE IGNITED BY MANY SOURCES. CLOSED CNTNRS MAY
EXPLODE W/HEAT. ISOLATE FROM HEAT/IGNITION SOURCES.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL. REMOVE
ALL IGNITION SOURCES. VENTILATE AREA. PROVIDE PROTECTIVE EQUIPMENT.
DIKE AROUND SPILL AREA. COVER SPILL WITH INERT ABSORBENT AND
TRANSFER USING NON-SPARKIN G TOOLS.
======================Handling and Storage ======================
Handling and Storage Precautions:STORE BELOW 80 F IN CLOSED CONTAINER.
STORE IN ORIGINAL CONTAINER. AVOID FLAME AND HIGH TEMPERATURES. DO
NOT STORE NEAR OXIDIZING AGENTS OR ACIDS.
Other Precautions:VAPOR IS HEAVIER THAN AIR, MAY TRAVEL CONSIDERABLE
DISTANCE TO IGNITION SOURCE & FLASHBACK. DON'T INGEST OR INHALE.
GROUND ALL CONNECTIONS, CONTAINERS, ETC WHEN POURING OR TRANSFERING
TO MINIMIZE STAT IC ELECTRICITY. USE NON-SPARK TOOLS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA EQUIPMENT WHEN AIRBORNE EXPOSURE
LIMITS ARE EXCEEDED. CONSULT RESPIRATOR MANUFACTURER TO DETERMINE
EQUIPMENT FOR GIVEN APPLICATION. HIGH AIRBORN CONCENTRATIONS MAY
REQUIRE USE OF SUPPLI ED-AIR RESPIRATOR OR SCBA.
Ventilation:PROVIDE VENTILATION TO CONTROL EXPOSURE LEVELS BELOW
AIRBORNE EXPOSURE LIMITS. VENT EQUIPMENT MUST BE EXPLOSION PROOF.
Other Protective Equipment:WEAR IMPERMEABLE APRONS & PROTECT CLOTHES
WHEN POSSIBLE TO PREVENT REPEAT/EXTEND EXPOSURE OF SKIN. HEAD CAPS
RECOMMENDED
Work Hygienic Practices:AFTER USING, WASH BEFORE EATING, TOILETING OR
SMOKING.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:315F,157C
Vapor Density:> AIR
Spec Gravity:1.3 (WATER=1)
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NOT WATER SOLUBLE
Appearance and Odor:PIGMENTED LIQUID. SOLVENT ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:DO NOT EXPOSE TO HEAT OR IGNITION SOURCES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CARBON
DIOXIDE AND/OR MONOXIDE, LOW MOLECULAR WEIGHT HYDROCARBONS &
ORGANIC ACIDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:KEEP OUT OF DRAINS, SEWERS AND WATERWAYS.
DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:C810D-66;5445901090002960
Preparer's Name:SAME AS MFR
CAGE:00297
CAGE:00297
============= Composition/Information on Ingredients =============
Ingred Name:ISOPROPYL ALCOHOL (SARA III)
CAS:67-63-0
RTECS #:NT8050000
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:400 PPM/500 STEL
ACGIH TLV:400 PPM/500STEL;9293
Ingred Name:N-PROPYL ALCOHOL
CAS:71-23-8
RTECS #:UH8225000
Fraction by Wt: 5-10%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/250 STEL
ACGIH TLV:S,200PPM/250STEL9293
Ingred Name:N-BUTYL ALCOHOL (SARA III)
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Ingred Name:2-BUTOXYETHANOL
CAS:111-76-2
RTECS #:KJ8575000
Fraction by Wt: 10-15%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:S, 50 PPM
ACGIH TLV:S, 25 PPM; 9293
Ingred Name:TOLUENE (SARA III)
CAS:108-88-3
RTECS #:XS5250000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:200 PPM/150 STEL
ACGIH TLV:50 PPM; 9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
CAS:1330-20-7
RTECS #:ZE2100000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:100 PPM/150 STEL
ACGIH TLV:100 PPM/150STEL;9293
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Ingred Name:ISOBUTYL ACETATE (SARA III)
CAS:110-19-0
RTECS #:AI4025000
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:150 PPM
ACGIH TLV:150 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:PEL=200PPM;300PPM(CEILING);500PPM(10MIN)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES:DIRECT CONTACT WITH LIQUID MAY
CAUSE IRRITATION.SKIN:PROLONGED/REPEATED CONTACT MAY CAUSE
DEFATTING,SENSITIZATION.PRODUCT IS ABSORBED THROUGH
SKIN.INHAL:RESPIRATORY TRACT IRRITATION,CNS DEPRESSIO
N.INGEST:CAUSE GI DISTURBANCES.MAY CAUSE LUNG DAMAGE IF VOMITED
AFTER SWALLOWING.
Explanation of Carcinogenicity:ETHYLENE GLYCOL MONOBUTYL ETHER HAS
CUASED LIVER,KIDNEY,LUNG AND BLOD DAMAGE IN LAB ANIAMLS.
Effects of
Overexposure:SKIN:REDNESS.BLISTERING.IRRITATION,DERMATITIS.INHAL:WE
AKNESS,HEADACHE,DIZZINESS,INCOORDINATION ...POSSIBLE
COLLAPSE.INGEST:(IN ADDITION TO THOSE LISTED FOR
INHAL)NAUSEA,VOMITING,DIARRHEA.
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING CONDITION
OF THE RESPIRATORY TRACT,SKIN,LIVER,CNS,EYES MAY BE AT INCREASED
RISK FROM EXPOSURE.
======================= First Aid Measures =======================
First Aid:EYES:FLUSH WITH WATER.CALL DOCTOR.SKIN:REMOVE CONTAMINATED
CLOTHING.WASH WITH SOAP AND WATER.IF REDNESS,ITCHING,BURNING OR
OTHER SYMPTOMS PERSIST CALL DOCTOR.INHAL:REMOVE FROM EXPOSURE.GIVE
O2 OR ARTI FICIAL RESPIRATION IF NEEDED.INGEST:DO NOT INDUCE
VOMITING.IF CONSCIOUS,GIVE 1 GLASS OF MILK OR 1-2OZ OF ACTIVATED
CHARCOAL(AS TOLERATED).GET PROMPT QUALIFIED MEDICAL
HELP.PHYSICIAN-TREAT FOR SYMPTOMS
===================== Fire Fighting Measures =====================
Flash Point:60.0F,15.6C
Extinguishing Media:CARBON DIOXIDE,DRY CHEMICAL OR FOAM.WATER MAY BE
INEFFECTIVE.USE CO2,DRY CHEMICAL,WATER SPRAY,ALCOHOL PER MFR
RECOMMDATN
Fire Fighting Procedures:WEAR COMPLETE FIRE PROTECTIVE
EQUIPMENT,INCLUDING FULL-FACE SELF-CONTAINED BREATHING
APPARATUS.USE WATER TO COOL FIRE EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard:VAPORS FORM EXPLOSIVE MIXTURE WITH
AIR.VAPORS CAN TRAVEL ALONG THE GROUND AND FLASHBACK.OPEN/CLOSED
CONTAINERS MAY CONTAIN VAPOR.CLOSED CONTAINERS MAY EXPLODE.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP LEAK(IF SAFE).AVOID BREATHING
VAPORS.ELIMINATE SOURCES OF IGNITION.VENTILATE AREA.TAKE UP WITH A
NON-FLAMMABLE INERT ADSORBANT(AVOID OXIDIZING AGENTS!)PLACE IN
APPROPRIATE CONTAINER FOR DISPOSAL. RQ=100LBS;800-424-8802
Neutralizing Agent:NONE
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH SKIN AND EYES.AVOID
VAPORS.HANDLE IAW 29CFR1910.106&107(FOR SPRAYING).STORE IN
BUILDINGS IAW OSHA1910.106.
Other Precautions:KEEP IN CLOSED,LABELED CONTAINERS,IN A COOL,DRY,WELL
VENTILATED AREA.AVOID CONTAINER DAMAGE.GROUND AND BOND DRUMS WHEN
TRANSFERRING LIQUIDS.KEEP AWAY FROM OXIDIZING MATERIELS.DO NOT
PRESSURIZE EMPTY D RUMS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH.MSHA RESPIRATOR IAW 29CFR1910.134.IF
WITHIN OSHA PROTECTION FACTOR,AIR PURIFYING OV/FILTER UNITS OKAY.
Ventilation:SUFFICIENT GENERAL/LOCAL EXHUAST VENTILATION.USE LOCAL
EXHAUT IN ENCLOSED SPACES.
Other Protective Equipment:FACE SHIELD,IF SPLASHING IS
ANTICIPATED.INDUSTRIAL CLOTHING,FOOTWEAR,HEAD/NECK
COVER,APRON,JACKET,PANTS,COVERALLS.
Work Hygienic Practices:WASH HANDS.SEPERATE WORK CLOTHES FROM STREET
CLOTHES.LAUNDER WORK CLOTHES BEFORE REUSE.KEEP FOOD OUT OF THE WORK
AREA.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:F2
NRC/State Lic Num:NONE
Vapor Density:>1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID;NO COLOR REPORTED;TYPICAL SOLVENT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT SPARKS,OPEN FLAMES.
Hazardous Decomposition Products:CARBON MONOXIDE,CARBON DIOXIDE.
==================== Disposal Considerations ====================
Waste Disposal Methods:CLASSIFIED EPA IGNITABLE HAZARDOUS WASTE.DISPOSE
OF IN ACCORDANCE WITH FEDERAL,STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ETHYL ACETATE
Kit Part:=== Responsible Party ===
780-471-4036
780-471-4036
CAGE:Company Name:MATHESON TRI-GAS, INC.
780-471-4036
CAGE:
============= Composition/Information on Ingredients =============
Ingred Name:ETHYL ACETATE
CAS:141-78-6
Fraction by Wt: 100.0%
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:No IARC:NoOSHA:No
Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE:
irritation, symptoms of drunkenness LONG TERM EXPOSURE: no
information on significant adverse effects SKIN CONTACT: SHORT TERM
EXPOSURE: irritation LONG TERM EXPOSURE: no information on
significant adverse effects EYE CONTACT: SHORT TERM EXPOSURE:
irritation, tearing LONG TERM EXPOSURE: eye damage INGESTION: SHORT
TERM EXPOSURE: sore throat, diarrhea, stomach pain, headache,
drowsiness, symptoms of drunkenness LONG TERM EXPOSURE: no
information on significant adverse effects
Medical Cond Aggravated by Exposure:
======================= First Aid Measures =======================
First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
Get immediate medical attention. SKIN CONTACT: Wash skin with soap
and water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention, if needed. Thoroughly
clean and dry contaminated clothing and shoes before reuse. EYE
CONTACT: Flush eyes with plenty of water for at least 15 minutes.
Then get immediate medical attention. INGESTION: Contact local
poison control center or physician immediately. Never make an
unconscious person vomit or drink fluids. When vomiting occurs,
keep head lower than hips to help prevent aspiration. If person is
unconscious, turn head to side. Get medical attention immediately.
NOTE TO PHYSICIAN: For ingestion, consider gastric lavage and
activated charcoal slurry. Consider oxygen.
===================== Fire Fighting Measures =====================
Flash Point:25 F (-4 C) (CC)
Autoignition Temp:799 F (426 C)
Lower Limits:2.2%
Upper Limits:11.5%
Extinguishing Media:alcohol resistant foam, carbon dioxide, regular dry
chemical, water, alcohol resistant foam Large fires: Use
alcohol-resistant foam or flood with fine water spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Cool containers with water spray until well
after the fire is out. Stay away from the ends of tanks. For fires
in cargo or storage area: Cool containers with water from unmanned
hose holder or monitor nozzles until well after fire is out. If
this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let
the fire burn. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire.
For tank, rail car or tank truck: Evacuation radius: 800 meters
(1/2 mile). Water may be ineffective.
Unusual Fire/Explosion Hazard:Severe fire hazard. The vapor is heavier
than air. Vapors or gases may ignite at distant ignition sources
and flash back. Vapor/air mixtures are explosive above flash point.
================== Accidental Release Measures ==================
Spill Release Procedures:Avoid heat, flames, sparks and other sources
of ignition. Remove sources of ignition. Stop leak if possible
without personal risk. Reduce vapors with water spray. Small
spills: Absorb with sand or other non-combustible material. Collect
spilled material in appropriate container for disposal. Large
spills: Dike for later disposal. Keep unnecessary people away,
isolate hazard area and deny entry. Stay upwind and keep out of low
areas. Notify Local Emergency Planning Committee and State
Emergency Response Commission for release greater than or equal to
RQ (U.S. SARA Section 304). If release occurs in the U.S. and is
reportable under CERCLA Section 103, notify the National Response
Center at (800)424-8802 (USA) or (202)426-2675 (USA).
Neutralizing Agent:
======================Handling and Storage ======================
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Subject to storage
regulations: U.S. OSHA 29 CFR 1910.106. Grounding and bonding
required. Keep separated from incompatible substances.
Other Precautions:
============= Exposure Controls/Personal Protection =============
Respiratory Protection:The following respirators and maximum use
concentrations are drawn from NIOSH and/or OSHA. 2000 ppm Any
supplied-air respirator. Any powered, air-purifying respirator with
organic vapor cartridge(s). Any chemical cartridge respirator with
a full facepiece and organic vapor cartridge(s). Any air-purifying
respirator with a full facepiece and an organic vapor canister. Any
self-contained breathing apparatus with a full facepiece. Any
supplied-air respirator with a full facepiece. Escape - Any
air-purifying respirator with a full facepiece and an organic vapor
canister. Any appropriate escape-type, self-contained breathing
apparatus. For Unknown Concentrations or Immediately Dangerous to
Life or Health - Any supplied-air respirator with full facepiece
and operated in a pressure-demand or other positive-pressure mode
in combination with a separate escape supply. Any self-contained
breathing apparatus with a full facepiece.
Ventilation:Provide local exhaust or process enclosure ventilation
system. Ventilation equipment should be explosion-resistant if
explosive concentrations of material are present. Ensure compliance
with applicable exposure limits.
emergency eye wash fountain and quick drench shower in the
immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
ETHYL ACETATE: 400 ppm (1400 mg/m3) OSHA TWA 400 ppm ACGIH TWA 400 ppm
(1400 mg/m3) NIOSH recommended TWA 10 hour(s)
================== Physical/Chemical Properties ==================
Boiling Pt:171 F (77 C)
Melt/Freeze Pt:-119 F (-84 C)
Vapor Pres:100 mmHg @ 27 C
Vapor Density:3.04
Spec Gravity:0.902
pH:Not available
Evaporation Rate & Reference:6.0 (butyl acetate=1)
Solubility in Water:8.7%
Appearance and Odor:PHYSICAL STATE:liquid APPEARANCE:translucent
COLOR:colorless PHYSICAL FORM:volatile liquid ODOR:fruity odor
Corrosion Rate:
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:Stable at normal temperatures
and pressure.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Containers may rupture or explode if exposed
to heat.
Hazardous Decomposition Products:Thermal decomposition products: oxides
of carbon Thermal decomposition products: oxides of carbon
Conditions to Avoid Polymerization:Will not polymerize.
=================== Toxicological Information===================
Toxicological Information:ETHYL ACETATE: IRRITATION DATA: 400 ppm
eyes-human TOXICITY DATA: 200 gm/m3 inhalation-rat LC50; >20 ml/kg
skin-rabbit LD50; 5620 mg/kg oral-rat LD50 CARCINOGEN STATUS:
ACGIH: A4 -Not Classifiable as a Human Carcinogen LOCAL EFFECTS:
Irritant: inhalation, skin, eye ACUTE TOXICITY LEVEL: Slightly
Toxic: inhalation, ingestion TARGET ORGANS: central nervous system
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: blood system disorders,
respiratory disorders, skin disorders and allergies MUTAGENIC DATA:
Available.
===================== Ecological Information =====================
Ecological:ECOTOXICITY DATA: FISH TOXICITY: 1500000 ug/L 48 hour(s)
LC50 (Mortality) Medaka, high-eyes (Oryzias latipes) INVERTEBRATE
TOXICITY: 6000 mg/L 24 hour(s) EC100 (Abundance) Water flea
(Daphnia magna) ALGAL TOXICITY: >1000000 ug/L 48 hour(s)
(Population Growth) Green algae (Scenedesmus pannonicus) OTHER
TOXICITY: 150000 ug/L 48 week(s) LC50 (Mortality) Mexican axolotl
(Ambystoma mexicanum)
==================== Disposal Considerations ====================
Waste Disposal Methods:Subject to disposal regulations: U.S. EPA 40 CFR
262. Hazardous Waste Number(s): D001.
=================== MSDS Transport Information ===================
Transport Information:U.S. DOT 49 CFR 172.101: PROPER SHIPPING NAME:
Ethyl acetate ID NUMBER: UN1173 HAZARD CLASS OR DIVISION: 3 PACKING
GROUP: II LABELING REQUIREMENTS: Flammable liquid
===================== Regulatory Information =====================
SARA Title III Information: SARA TITLE III SECTION 302 EXTREMELY
HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated. SARA TITLE
III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not
regulated.SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS
CATEGORIES (40 CFR 370.21): ACUTE: Yes CHRONIC: No FIRE: Yes
REACTIVE: No SUDDEN RELEASE: No SARA TITLE III SECTION 313 (40
CFR 372.65): Not regulated.
Federal Regulatory Information:CERCLA SECTIONS 102a/103 HAZARDOUS
SUBSTANCES (40 CFR 302.4):ETHYL ACETATE: 5000LBSRQ OSHA PROCESS
SAFETY (29CFR1910.119): Not regulated.
State Regulatory Information: California Proposition 65: Not regulated.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:ALIPHATIC POLYISOCYANATE-COMPONENT A -TYPE 1
Preparer's Name:ERNEST CARTER
CAGE:09225
CAGE:09225
============= Composition/Information on Ingredients =============
Ingred Name:IRON OXIDE BLACK
CAS:1317-61-9
Minumum % Wt:5.
Maxumum % Wt:10.
Ingred Name:METHYL AMYL KETONE
CAS:110-43-0
RTECS #:MJ5075000
Minumum % Wt:20.
Maxumum % Wt:30.
OSHA PEL:465 MG/M3;100 PPM
ACGIH TLV:233 MG/M3;50 PPM
Ingred Name:HEXAMETHYLENE DIISOCYANATE HOMOPOLYMER
CAS:28182-81-2
RTECS #:NQ9170000
Minumum % Wt:30.
Maxumum % Wt:40.
Ingred Name:TITANIUM DIOXIDE
CAS:13463-67-7
RTECS #:XR2275000
Minumum % Wt:1.
Maxumum % Wt:5.
OSHA PEL:15 MG/M3
ACGIH TLV:10 MG/M3
Ingred Name:HEXAMETHYLENE DIISOCYANATE
CAS:822-06-0
RTECS #:MO1740000
= Wt:.04
ACGIH TLV:0.034 MG/M3;.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CRYSTALITE A 2
CAS:14808-60-7
RTECS #:VV7330000
Minumum % Wt:15.
Maxumum % Wt:20.
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:EYE CONTACT WITH LIQUID, AEROSOLS AND
VAPORS CAN BE IRRITATING CAUSING TEARING, REDDENING AND SWELLING
ACCOMPANIED BY A STINGING AND/OR A FEELING LIKE THAT OF FINE DUST
IN THE EYES. SKIN CONTACT:ISOCY ANATES REACT WITH SKIN PROTEIN AND
MOISTURE AND CAN CAUSE IRRITATION. SYMPTOMS OF SKIN IRRITATION MAY
BE REDDENING, RASH, SWELLING,SCALING OR BLISTERING.
INHALATION:ANESTHETIC. CAN CAUSE IRRITATION OF THE RESPIRATORY
TRACT OR ACUTE NERVOUS SYSTEM DEPRESSION CHARACTERIZED BY THE
FOLLOWING PROGRESSIVE STEPS IF SEVERE OVEREXPOSURE IS CONTINUED:
HEADACHE, DIZZINESS, STAGGERING GAIT, CONFUSION OR UNCON
SCIOUSNESS. INGESTION: CAN RESULT IN
Effects of Overexposure:IRRITATION AND POSSIBLE CORROSIVE ACTION IN THE
MOUTH, STOMACH TISSUE AND DIGESTIVE TRACT, SYMPTOMS CAN INCLUDE
SORE THROAT, ABDOMINAL PAIN, NAUSEA, VOMITING AND DIARRHEA. CHRONIC
EFFECTS: REPORTS HAV E ASSOCIATED REPEATED AND PROLONGED
OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS SYSTEM DAMAGE, LIVER AND KIDNEY DAMAGE.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
AILMENTS;SKIN ALLERGIES AND ECZEMA; CHEMICAL SENSITIZATION.
======================= First Aid Measures =======================
First Aid:EYE CONTACT: FLUSH IMMEDIATELY WITH LOW PRESSURE LUKE WARM
RUNNING WATER FOR AT LEAST 15 MINUTES WHILE LIFTING EYELIDS. TAKE
TO A PHYSICIAN FOR TREATMENT. SKIN CONTACT: REMOVE CONTAMINATED
CLOTHING IM MEDIATELY. WASH AFFECTED AREAS THOROUGHLY WITH SOAP AND
WATER. GET MEDICAL ATTENTION. INHALATION: MOVE TO AN AREA FREE FROM
RISK OF FUTHER EXPOSURE. OBTAIN MEDICAL ATTENTION. INGESTION: CALL
A PHYSICI AN IMMEDIATELY. DO NOT INDUCE VOMITING.
===================== Fire Fighting Measures =====================
Lower Limits:1.1%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING SELF
CONTAINED BREATHING APPARATUS SHOULD BE WORN.DURING A FIRE,
IRRITATING AND HIGHLY TOXIC GASES AND SMOKE ARE PRESENT FROM THE
DECOMPOSITION/COMBUSTION PRODUCTS.KEEP CONTAINERS TIGHTLY CLOSED.
ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAMES.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL AND
REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, ELECTRICAL,
STATIC AND FRICTIONAL SPARKS).VENTILATE AREA. EQUIP CLEAN UP CREW
WITH APPROPRIATE PROTECTIVE EQUIPMENT.AVOID BREATHING VAPORS.
AVOID SKIN CONTACT. PREVENT ENTRY INTO DRAINS, SEWERS AND
WATERWAYS. NOTIFY APPROPRIATE AUTHORITIES IF NECESSARY.
======================Handling and Storage ======================
Handling and Storage Precautions:PRECAUTIONS MUST BE TAKEN SO THAT
PERSONS HANDLING THIS PRODUCT DO NOT BREATHE THE VAPORS OR HAVE IT
CONTACT THE EYES OR SKIN. IN SPRAY OPERATIONS, PROTECTION MUST BE
AFFORDED AGAINST EXPOSURE TO BOTH VAPOR AND SPRAY MIST. DO NOT
STORE ABOVE 120 F OR LOW 23 F. STORE LARGE QUANTITIES IN BUILDINGS
DES
============= Exposure Controls/Personal Protection =============
Respiratory Protection:THE SURGEON GENERAL REQUIRES AIRLINE RESPIRATORS
TO BE USED UNLESS AIR SAMPLING SHOWS EXPOSURE TO BE BELOW OSHA
LIMITS. THEN, EITHER AIR-PURIFYING CHEMICAL CARTRIDGE RESPIRATORS
ARE REQUIRED.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE
CONCENTRATIONS OF THE ISOCYANATES BELOW THEIR RESPECTIVE EXPOSURE
LIMITS MUST BE UTILIZED.
EXPOSED SKIN AREA AS POSSIBLE
Other Protective Equipment:SAFETY SHOWERS AND EYE WASH STATIONS SHOULD
BE AVAILABLE. EDUCATE AND TRAIN EMPLOYEES IN THE SAFE USE OF THIS
PRODUCT.
Supplemental Safety and Health
MEDICAL SURVEILLANCE OF ALL EMPLOYEES WHO HANDLE OR COME IN CONTACT
WITH THIS PRODUCT IS RECOMMENDED. THIS SHOULD INCLUDE
PRE-EMPLOYMENT AND PERIODIC MEDICAL EXAMINATIONS WITH RESPIRATORY
FUNCTION TES TS. PERSON WITH ASTHMA SHOULD NOT USE ISOCYANATES.
ONCE A PERSON IS SENSITIZED TO ISOCYANATES, NO FURTHER EXPOSURE
PERMI
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:LO-295.0-HI-305.0 F
Vapor Pres:2.14
Vapor Density:3.94
Spec Gravity:1.224
VOC Pounds/Gallon:364
Evaporation Rate & Reference:.400 (BUTYL ACETATE=1)
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPAQUE LIQUID LIQUID SOLVENT ODOR
Percent Volatiles by Volume:44.5659
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CONTAMINATION WITH WATER, EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS,
BASES, METAL COMPLEXES OR OTHER ACTIVE MATERIALS. ONCE THE MATERIAL
HAS BEEN EXPOSED TO ANY OF THE ABOVE OR ATMOSPHERIC MOISTURE, DO
NOT RESEAL CONTAINER A
Stability Condition to Avoid:CONTAMINATION WITH WATER, EPOXY CATALYSTS,
ALCOHOLS, GLYCOL ETHERS, BASES, METAL COMPLEXES OR OTHER ACTIVE
MATERIALS. ONCE THE MATERIAL HAS BEEN EXPOSED TO ANY OF THE ABOVE
OR ATMOSP
Hazardous Decomposition Products:MAY PRODUCE HAZARDOUS FUMES WHEN
HEATED TO DECOMPOSITION AS IN WELDING, FUMES MAY CANTAIN THE
FOLLOWING: CARBON MONOXIDE, CARBON DIOXIDE, HYDROGEN CHLORIDE AND
POSSIBLE CYANIDE, HEXAMETHYLENE DIISOCYANA
Conditions to Avoid Polymerization:WILL NOT OCCUR.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECYCLE, FUEL BLEND OR INCINERATE. DISPOSE OF IN
ACCORDANCE WITH APPLICABLE LAWS AND REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:PSN: PAINT, 3, UN1263, III. LABEL: FLAMMABLE
LIQUID.
===================== Regulatory Information =====================
SARA Title III Information:THIS PRODUCT CONTAINS NAPHTHALENE, CAS #
91-20-3 (2.863% WT), AND IS SUBJECT TO THE REPORTING REQUIREMENT
OF SEC 313 ( 40 CFR 372).
Federal Regulatory Information:THE INGREDIENTS OF THIS PRODUCT ARE ON
THE TSCA INVENTORY.
======================= Other Information =======================
======================================================================
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:2827 NALCO COOLING TREATMENT
CAGE:89524
CAGE:89524
============= Composition/Information on Ingredients =============
Ingred Name:PHOSPHONATES
Ingred Name:SUBSTITUTED CARBOXYLATE
Ingred Name:TRACER
Ingred Name:1,H-BENZOTRIAZOLE (4 OR 5) METHYL SODIUM SALT
SODIUM TOLYLTRIAZOLE
CAS:64665-57-2
Fraction by Wt: 1-5%
Ingred Name:SUBSTITUTED TRIAZOLE
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL RATS LD50: 5,000 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES/INGESTION: IRRITATION.
INHALATION: BREATHING DIFFICULTY OR CONVULSIONS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN/EYES/INGESTION: IRRITATION. INHALATION:
BREATHING DIFFICULTY OR CONVULSIONS.
======================= First Aid Measures =======================
First Aid:EYES/SKIN: FLUSH W/WATER FOR 15 MINS. INGESTION: IF
CONSCIOUS/BREATHING DIFFICULTY/CONVULSIONS, DON'T INDUCE VOMITING
OR GIVE WATER. INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL
ATTENTION IN ALL CA SES. NOTE TO PHYSICIAN: THE
PHYSICIAN'SJUDGEMENT IS BASED ON THE INDIVIDUAL'S REACTIONS TO
CONTROL THE SYMPTOMS/CLINICAL CONDITION. NO SPECIFIC ANTIDOTE IS
KNOWN.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:>200F
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS IN
PRESSURE DEMAND.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN W/ABSORBENT MATERIAL, SUCH AS
CLAY/SOIL/COMMERCIALLY AVAILABLE ABSORBENT. DIKE TO PREVENT FURTHER
MOVEMENT OR SHOVEL RECLAIMED LIQUID/ABSORBENT INTO RECOVERY,
SALVAGE DRUMS OR TANK TRUCK FOR D ISPOSAL. WEAR PROTECTIVE
EQUIPMENT.
======================Handling and Storage ======================
Handling and Storage Precautions:DON'T GET IN EYES, ON SKIN OR ON
CLOTHING. DON'T TAKE INTERNALLY. EMPTY CONTAINERS MAY CONTAIN
RESIDUAL PRODUCT. DON'T BREATHE SMOKE OR FUMES.
Other Precautions:DON'T REUSE CONTAINER UNLESS PROPERLY RECONDITIONED.
AVOID CONTACT W/STRONG ACIDS. WEAR PROTECTIVE EQUIPMENT WHEN
ATTACHING FEEDING EQUIPMENT, DOING MAINTENANCE, OR HANDLING
PRODUCT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF SIGNIFICANT MISTS/AEROSOLS ARE GENERATED,
WEAR NIOSH APPROVED/EQUIVALENT RESPIRATOR. IF ENTERING LARGE
TANKS/VESSELS/ENCLOSED SPACES W/INADEQUATE VENTILATION. WEAR SCBA
IN PRESSURE DEMAND.
Ventilation:GENERAL VENTILATION IS RECOMMENDED
Other Protective Equipment:SHOES & SUITABLE PROTECTIVE EQUIPMENT
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS THOROUGHLY.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:212F
Melt/Freeze Pt:M.P/F.P Text:24F
Spec Gravity:1.14
pH:13
Appearance and Odor:CLEAR BRIGHT YELLOW/ORANGE LIQUID
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS SUCH AS SULFURIC, PHOSPHORIC, NITRIC, HYDROCHLORIC,
CHROMIC & SULFONIC ACIDS
Stability Condition to Avoid:HEAT & SPLATTERING
Hazardous Decomposition Products:TOXIC FUMES, CO, CO2 & NITROGEN OXIDES
==================== Disposal Considerations ====================
Waste Disposal Methods:SOLIDIFY W/STABILIZING AGENTS SUCH AS SAND/FLY
ASH/CEMENT AS A NON-HAZARDOUS LIQUID WASTE SO THAT NO FREE LIQUID
REMAINS BEFORE INDUSTRIAL WASTE LANDFILL OR DEEP-WELL INJECTION IN
ACCORDANCE W/LOCAL/S TATE/FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
===================== Product Identification =====================
Product ID:2-HYDROXYPROPYL-B-CYCLODEXTRIN CELL CULTURE TESTED, C0926
CAGE:21076
CAGE:21076
============= Composition/Information on Ingredients =============
Ingred Name:2-HYDROXYPROPYL-B-CYCLODEXTRIN
CAS:128446-35-5
= Wt:100.
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE EFFECTS: MAY BE HARMFUL BY
INHALATION, INGESTION OR SKIN ABSORPTION. MAY CAUSE EYE IRRITATION.
MAY CAUSE SKIN IRRITATION. THE TOXICOLOGICAL PROPERTIES HAVE NOT
BEEN THOROUGHLY INVESTIGATED.
Effects of Overexposure:SEE HEALTH HAZARDS.
======================= First Aid Measures =======================
First Aid:INGESTION: IF SWALLOWED, WASH OUT MOUTH WITH WATER PROVIDED
PERSON IS CONSCIOUS. CALL A PHYSICIAN. SKIN: IN CASE OF SKIN
CONTACT, FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15
MINUTES. REMOVE CO NTAMINATED CLOTHING AND SHOES. CALL A PHYSICIAN.
INHALATION: IF INHALED, REMOVE TO FRESH AIR. IF BREATHING BECOMES
DIFFICULT, CALL A PHYSICIAN. EYES: IN CASE OF CONTACT WITH EYES,
FLUSH WITH COPIOUS A MOUNTS OF WATER FOR AT LEAST 15 MINUTES.
ASSURE ADEQUATE FLUSHING BY SEPARATING THE EYELIDS WITH FINGERS.
CALL A PHYSICIAN.
===================== Fire Fighting Measures =====================
Extinguishing Media:WATER SPRAY. CARBON DIOXIDE, DRY CHEMICAL POWDER OR
APPROPRIATE FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT TO PREVENT CONTACT WITH SKIN AND EYES.
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
================== Accidental Release Measures ==================
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. SWEEP UP, PLACE IN
A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST. VENTILATE
AREA AND WASH SPILL SITE AFTER MATERIAL PICKUP IS COMPLETE.
======================Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATHING DUST. KEEP TIGHTLY
CLOSED. STORE IN A COOL, DRY PLACE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:EYE WASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Spec Gravity:0.2
Solubility in Water:SOLUBLE
Appearance and Odor:SOLID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:TOXIC FUMES OF: CARBON MONOXIDE,
CARBON DIOXIDE.
=================== Toxicological Information===================
Toxicological Information:SEE HEALTH HAZARDS.
===================== Ecological Information =====================
Ecological:DATA NOT YET AVAILABLE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:CONTACT SIGMA CHEMICAL COMPANY FOR TRANSPORTATION
INFORMATION.
===================== Regulatory Information =====================
Federal Regulatory Information:EUROPEAN INFORMATION: CAUTION: SUBSTANCE
NOT YET FULLY TESTED.
======================= Other Information =======================
| 1 | eyes_protection_mandatory |
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