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* Exposure Controls/Personal Protection *
Respiratory Protection:IF SOLID METAL ALLOYS ARE CONVERTED IN MFG
(INCLUDING GRINDING, HIGH TEMP CUTTING & WELDING) PROCESSES TO
DUSTS/FUMES/ GASES/MISTS, & VENTILATION IS NOT ADEQUATE TO MAINTAIN
EXPOSURES BELOW LIMITS SPE CIFIED IN INGREDIENTS SECTION, (ING 5)
Ventilation:IF SOLID METAL ALLOYS ARE CONVERTED TO DUSTS/FUMES/ MISTS,
MAINTAIN WORKING ENVIRON BELOW EXPOS LIMITS SPECIFIED (ING 6)
Other Protective Equipment:WHEN CUTTING/GRINDING/WELDING, WEAR FLAME
RETARDANT CLOTHING. SELECT WELDING LENSE SHADE FROM AWS PUBLICATION
F2.2.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FLUORIDES & COMPLEX METALLICS. THE GASES MAY INCL CO, OZONE AND
NOX. SPILL PROC: GRINDING OR WELDING OPERATIONS, VACUUM RESIDUE I
NTO SUITABLE CONTRS & DISPOSE. HNDLG/STOR PREC: USE OF THIS MATL
DOES NOT CREATE EXPOS WHICH EXCEED LEVELS SPECIFIED.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ALUMINUM (SARA III)
Fraction by Wt: 1%
Ingred Name:MANGANESE (SARA III)
Fraction by Wt: 2%
OSHA PEL:(C) 5 MG/M3 DUST
Ingred Name:NICKEL (SARA III)
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:SILICON
Fraction by Wt: 2%
Ingred Name:RESP PROT: THE RESPIRATORY PROTECTION SHLD BE USED. USE
Ingred Name:VENT: IN INGREDIENT SECTION AND BY USE OF ADEQUATE EXHAUST
VENTILATION.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:UNDER NORM HNDLG/USE, EXPOS TO SOLID,
MASSIVE FORMS OF ALLOY PRESENTS FEW HLTH HAZ. THEY MAY INCL SKIN
IRRIT/ OTHER ALLERGIC RXNS IN SENSITIVE INDIVIDUALS. ACUTE: EXPOS
TO DUST, WELDING FUME & GASES M AY CAUSE NAUS, TIGHTNESS OF CHEST,
FEVER, IRRIT OF EYES/NOSE/ THROAT/SKIN; LOSS OF CONSCIOUSNESS DUE
TO (EFTS OF OVEREXP
Explanation of Carcinogenicity:NICKEL: GROUP 2B (IARC), ANTICIPATED TO
BE A CARCINOGEN (NTP).
Effects of Overexposure:HLTH HAZ: WELDING GASES OR LACK OF O2. CHRONIC:
ADVERSE EFFECTS MAY INCLUDE SKIN SENSITIZATION, NEUROLOGICAL DAMAGE
& RESPIRATORY DISEASES (BRONCHIAL ASTHMA, LUNG FIBROSIS OR
PNEUMOCONIOSIS). RECENT E PIDEMIOLOGICAL STUDIES OF WORKERS MELTING
& WORKING ALLOYS CONTAINING NICKEL HAVE FOUND NO INCREASED RISK OF
CANCER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: REMOVE FROM EXPOSURE AND OBTAIN PROMPT MEDICAL
ATTENTION. ADMINISTER O2 IF VICTIM IS UNCONSCIOUS. IF NOT
BREATHING, RESUSCITATE IMMEDIATELY. INGEST: CALL MD IMMEDIATELY .
MINUTES, SEEK ASSISTANCE FROM MD . SKIN: FLUSH W/COPIOUS AMOUNTS OF
WATER. CALL MD .
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MATERIAL IS NONFLAMMABLE; HOWEVER,
WELDING ARCS AND SPARKS CAN IGNITE FLAMMABLE LIQUIDS AND VAPORS AND
COMBUSTIBLE SOLIDS.
* Accidental Release Measures *
Spill Release Procedures:UNDER NORMAL HNDLG/USE, MATL IS NOT VOLAT OR
DUSTY & DOES NOT PRESENT SPILLAGE/LEAKAGE PROBLEMS. NO PROT REQD,
EXCEPT AVOID PRLNG/RPTD DIRECT SKIN CONT IF SENSITIVE TO METALS.
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:MATL IN SOLID FORM DOES NOT REQUIRE
SPECIAL PRECAUTIONS IN HNDLG/STORING. HOWEVER, USE INDUSTRIAL
HYGIENE AIR MONITORING TO ENSURE THAT (SUPP DATA)
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
Boiling Pt:B.P. Text:SUPP DATA
Spec Gravity:8.7
Solubility in Water:0
Appearance and Odor:GREY METALLIC (SOLID METALS SHAPED AS WIRE, ROD OR
STRIP). ODORLESS.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID ACIDS. CONTACT WITH MINERAL ACIDS WILL RELEASE HYDROGEN - A
READILY COMBUSTIBLE GAS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FUMES/GASES FROM WELDING & HIGH TEMP
CUTTING CNTN CONSTITUENTS DIFFERENT FROM LISTED INGREDIENTS & MAY
INCL (SUPP DATA)
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH EPA OR FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR BASED ON
CONTAMINATION LEVEL AND WORKING LIMITS OF RESPIRATOR.
Ventilation:LOCAL EXHAUST RECOMMENDED WHEN APPROPRIATE TO CONTROL
EMPLOYEE EXPOSURE. MECHANICAL VENT. NOT RECOMMENDED AS SOLE MEANS
Other Protective Equipment:CHEMICAL PROTECTIVE CLOTHING, INCLUDING
Work Hygienic Practices:WASH THOROUGHLY WITH SOAP AND WATER AFTER
HANDLING.
Supplemental Safety and Health
NONE
* Product Identification *
Product ID:METHYL ETHYL KETONE
Preparer's Name:CHEMICAL GROUP
CAGE:0RIR4
CAGE:0RIR4
* Composition/Information on Ingredients *
Ingred Name:METHYL ETHYL KETONE (2-BUTA) (MEK) (SARA III)
Other REC Limits: RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:NO
Health Hazards Acute and Chronic:INGESTION: MENTAL SLUGGISHNESS.
INHALATION: CAUSES IRRITATION OF NASAL PASSAGES AND THROAT. CAUSES
STUPOR (CNS DEPRESSION). SKIN: MODERATE SKIN INJURY, DRYING,
DERMATITIS. EYE: LIQUID AND VAPORS ARE I RRITATING. CAN CAUSE
SEVERE INJURY- DAMAGE REVERSIBLE
Explanation of Carcinogenicity:MFG. STATES "NO INFORMATION"
Effects of Overexposure:EYES: SEVERE INJURY. SKIN: DRYING OF SKIN,
DERMATITIS. INHALATION: STUPOR (CENTERAL NERVOUS SYSTEM
DEPRESSION). INGESTION: SLUGGISHNESS.
Medical Cond Aggravated by Exposure:SIGNIFICANT EXPOSURE TO THIS
CHEMICAL MAY ADVERSELY AFFECT PEOPLE WITH CHRONIC DISEASE OF
RESPIRATORY SYSTEM, SKIN, PERIPHERAL NERVOUS SYSTEM, CENTRAL
NERVOUS SYSTEM, AND/OR EYES.
* First Aid Measures *
First Aid:INGESTION: DO NOT INDUCE VOMITING, GIVE 2 GLASSES WATER/MILK.
CONTACT A PHYSICIAN. INHALATION: REMOVE PATIENT FROM CONTAMINATED
AREA. IF NOT BREATHING GIVE ARTIFICAL RESPIRATION, THEN OXYGEN IF
NEEDED . CONTACT A PHYSICIAN IMMEDIATELY. SKIN:REMOVE CLOTHES/WASH
CONTAMINATED SKIN WITH WATER. IF IRRITATION PERSISTS, CONTACT A
PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:TOC
Lower Limits:2.0
Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICALS FOR SMALL
FIRES, ALCOHOL-TYPE AQUEOUS FILM-FORMING FOAM OR WATER SPRAY ON
LARGE FIRE
Fire Fighting Procedures:IF POTENTIAL EXPOSURE TO VAPORS/PRODUCTS OF
COMBUSTION EXISTS,WEAR COMPLETE PROTECTIVE EQUIPMENT. WATER SPRAY
CAN BE USED TO REDUCE INTENSITY OF FLAME.
Unusual Fire/Explosion Hazard:VAPOR HEAVIER THAN AIR AND CAN TRAVEL
GREAT DISTANCE TO A SOURCE OF IGNITION AND FLASHBACK. MATERIAL
CREATES SPECIAL HAZARD BECAUSE TO FLOATS ON WATER.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE IGNITION SOURCES. AVOID EYE/SKIN
CONTACT.PLACE LEAKING CONTAINERS IN WELL VENTILATED AREA WITH SPILL
CONTAINMENT. IF FIRE POTENTIAL EXIST, BLANKET SPILL WITH ALCOHOL
TYPE AQUEOUS FILM-FORMI NG FOAM OR USE WATER SPRAY TO DISPERSE
VAPORS.
Neutralizing Agent: SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, WELL-VENTILATED AREA.
KEEP AWAY FROM HEAT, SPARKS & FLAME. KEEP CLOSED WHEN NOT IN USE.
ALWAYS OPEN CONTAINERS SLOWLY TO VENT PRESSURE.
Other Precautions:USE SPARK RESISTANT TOOLS. WHEN TRANSFERING FOLLOW
PROPER GROUNDING PROCEDURES. USE WITH ADEQUATE VENTILATION. AVOID
BREATHING VAPOR, CONTACT WITH EYES, SKIN AND CLOTHING. DISCARD
CONTAMINATED LEATHER CLOTHING.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:2.5
Evaporation Rate & Reference:5.7 (BUTYL ACETATE=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:CLEAR,COLORLESS, MOBILE LIQUID WITH STRONG
CHARACTERISTIC "KETONE" ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CAUSTIC SODA & OTHER STRONG ALKALIS; HYDROCHLORIC, SULFURIC & OTHER
STRONG INORGANIC ACIDS; AMINES, OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, AND FLAME.
Hazardous Decomposition Products:CARBON MONIXIDE
* Disposal Considerations *
Waste Disposal Methods:ALL NOTIFICATION, CLEAN-UP & DISPOSAL SHOULD BE
CARRIED OUT IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL
REGULATIONS. PREFERRED METHODS OF WASTE DISPOSAL ARE INCINERATION
OR BIOLOGICAL TREATMENT IN FED ERAL/STATE APPROVED FACILITY.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR AN APPROVED AIR-PURIFYING RESPIRATOR
W/HIGH-EFFICIENCY CARTRIDGES ADEQUATE TO CONTROL EXPOSURE IF PEL IS
EXCEEDED.
Ventilation:USE CLOSED-SYSTEM HANDLING, LABORATORY BENCH HOOD/LOCAL
EXHAUST TO CONTROL DUST/MIST.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE/LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
INFORMATION IS FOR SODIUM BICARBONATE. PH: 5.5-7.5 (AQUEOUS SOLUTION OF
PIPRACIL).
* Product Identification *
CAGE:0HMG4
CAGE:0HMG4
* Composition/Information on Ingredients *
Ingred Name:SODIUM BICARBONATE
Fraction by Wt: 2-4%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HAS THE CHARACTERISTICALLY LOW
POTENTIAL FOR TOXICITY FOUND W/OPTHER PENICILLIAN-TYPE ANTIBIOTICS.
CLINICALLY-OBSERVED SIDE EFFECTS THAT ARE SEEN INCLUDE ALLERGIC
REACTIONS. REVERSIBLE EFFECTS ON THE BLOOD, LIVER & KIDNEY FROM
PROLONGED/HIGH-DOSE CLINICAL USE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:RASH, HIVES, SEVERE ITCHING, DIARRHEA, NAUSEA,
VOMITING, FEVER, HEADACHE, DIZZINESS, FATIGUE, LOCAL REDNESS,
ERYTHEMA, THROMBOPHLEBITIS.
Medical Cond Aggravated by Exposure:ALLERGIC REACTIONS TO ANY
PENICILLINS &/CEPHALOSPORINS.
* First Aid Measures *
First Aid:EYES: IMMEDIATELY FLUSH W/PLENTY OF COOL, LOW-PRESSURE WATER
INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEEDED.
INGESTION: DON'T INDUCE VOMITING EXCEPT AS DIRECTED BY MEDICAL
PERSONNEL. NEVER GIVE ANYTHING BY MOUTH/INDUCE VOMITING IF
UNCONSCIOUS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Accidental Release Measures *
APPROVED FULL FACE AIR-PURIFYING RESPIRATOR W/HIGH EFFICIENCY
CARTRIDGES/SELF CONTAINED/SUPPLIED AIR RESPIRATOR. CONTAIN &
COLLECT.
*Handling and Storage *
Handling and Storage Precautions:STORE AT CONTROLLED ROOM TEMP OF
USE.
* Physical/Chemical Properties *
pH:(SUPP)
Solubility in Water:COMPLETE (SUPP)
Appearance and Odor:WHITE LYOPHILIZED CAKE.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS/BASES.
Hazardous Decomposition Products:CO/CO2/NITROGEN
OXIDES/ALDEHYDES/KETONES/ORGANIC ACIDS/HYDROGEN CYANIDE/SULFUR
OXIDES/OTHER SULFUR CONTAINING COMPOUNDS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WITH SATIFACTORY VENTILATION, RESPIRATORY
PROTECTION NOT USUALLY REQUIRED.
Ventilation:GENERAL ROOM VENTILATION IS USUALLY SATISFACTORY, USE LOCAL
EXHAUST VENTILATION WHEN NECESSARY.
Other Protective Equipment:WEAR DISPOSABLE GARMENTS IF DIRECT SKIN
CONTACT IS ANTICIPATED.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
* Product Identification *
Product ID:DEXTROSE INJECTION
Preparer's Name:GREGORY KOLAR
* Composition/Information on Ingredients *
Ingred Name:DEXTROSE
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER FOR INJECTION (NOTE: PRESERVATIVE FREE)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE, SKIN AND RESPIRATORY IRRITATION
MAY OCCUR. THIS PRODUCT IS INTENDED FOR THERAPUTIC USE ONLY WHEN
PRESCRIBED BY A PHYSICIAN. POTENTIAL ADVERSE REACTIONS FROM
PRESCRIBED DOSES AND OVERDOSES ARE DES CRIBED IN PACKAGE INSERT.
OCCUPATIONAL EXPOSURE HAS NOT BEEN FULLY INVESTIGATED.
Effects of Overexposure:EYE, SKIN AND RESPIRATORY IRRITATION MAY OCCUR.
THIS PRODUCT IS INTENDED FOR THERAPUTIC USE ONLY WHEN PRESCRIBED BY
A PHYSICIAN. POTENTIAL ADVERSE REACTIONS FROM PRESCRIBED DOSES AND
OVERDOSES ARE DES CRIBED IN PACKAGE INSERT. OCCUPATIONAL EXPOSURE
HAS NOT BEEN FULLY INVESTIGATED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. GET MEDICAL
ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING. FLUSH AREA WITH
LARGE AMOUNTS OF WATER. GET MEDICAL ATTENTION. INHALATION: MOVE TO
FRESH AIR. IF NOT BREATHING GIVE CPR. GET MEDICAL ATTENTION.
INGESTION: FLUSH MOUTH OUT WITH WATER IMMEDIATELY. GET MEDICAL
ATTENTION. GENERAL: FOR ADDITIONAL INFORMATION SEE THE PRODUCT
INSERT.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR FOAM
AS APPROPRIATE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:CLEAN-UP: WEAR RECOMMENDED PERSONAL PROTECTIVE
EQUIPMENT. USE ABSORBENT TOWELS OR BOOMS TO CLEAN-UP SPILL. WIPE
SURFACES CLEAN AND WASH WITH SOAP AND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AS A GENERAL RULE, WHEN HANDLING
PHARMACEUTICAL PRODUCTS AVOID ALL CONTACT AND INHALATION OF DUST,
FUME, MISTS, OR VAPORS ASSOCIATED WITH THE PRODUCT.
Other Precautions:PROTECT FROM FREEZING.
* Physical/Chemical Properties *
HCC:N1
pH:3.5-7
Solubility in Water:FREELY SOLUBLE
Appearance and Odor:CLEAR, COLORLESS SOLUTION. ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:PROTECT FROM FREEZING.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:TLV'S EXCEEDED/SPRAY MIST PRESENT: USE
NIOSH/MSHA APPROVED RESPIRATORY PROTECTION APPROPRIATE FOR
INDICATED COMPONENTS. CONFINED AREAS:NIOSH APPR'D AIR SUPPLIED
RESPIRATOR USE.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENTILATION IN
VOLUME/PATTERN TO KEEP LEVEL OF HAZARD INGREDIENT BELOW TLV/PEL
LIMITS.
Other Protective Equipment:AVOID SKIN CONTACT BY USE OF OTHER
PROTECTIVE CLOTHING. A SAFETY SHOWER, EYE BATH & WASHING
FACILITIES.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE. AVOID
SKIN CONTACT & BREATHING VAPORS OR MIST.
Supplemental Safety and Health
DEPENDING ON AMOUNT & CIRCUMSTANCES, UNAUTHORIZED RELEASE OF MATERIAL
INTO ENVIRONMENT MAY BE REPORTABLE UNDER FEDERAL LAW TO THE
AGE NCIES MAY ALSO HAVE REPORTING REQUIREMENTS OF WHICH YOU SHOULD
BE AWARE.
* Product Identification *
Kit Part:Y
CAGE:DESOT
CAGE:DESOT
* Composition/Information on Ingredients *
Ingred Name:EPOXY RESIN (VAPOR PRESSURE 0 MM HG)
Other REC Limits:NONE SPECIFIED
Ingred Name:TOLUENE (SARA III)
Fraction by Wt: 5%.
Other REC Limits:NONE SPECIFIED
Ingred Name:BISPHENOL A EPOXY RESIN (VAPOR PRESSURE 0 MM HG)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:N-BUTYL ACETATE (VAPOR PRESSURE 8.4 MM HG)
Other REC Limits:NONE SPECIFIED
Ingred Name:TOLUENE DIISOCYANATE (VAPOR PRESSURE 0 MM HG)
Fraction by Wt: < 5%.
Other REC Limits:NONE SPECIFIED
Fraction by Wt: < 5%.
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
Ingred Name:STRONTIUM CHROMATE(SARA III)
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.1 PPM CRO3;CEILING
Ingred Name:AMORPHOUS SILICA (VAPOR PRESSURE 0 MM HG)
Fraction by Wt: < 5%
Other REC Limits:NONE SPECIFIED
OSHA PEL:5 MG/M3
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:HIGH FLASH NAPHTHA (VAPOR PRESSURE 2 MM HG)
Fraction by Wt: < 5%
Other REC Limits:NONE SPECIFIED
Fraction by Wt: < 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:PHTHALO GREEN PIGMENT (VAPOR PRESSURE 0 MM HG)
Fraction by Wt: < 5%
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALE: NASAL/RESPIRATORY
IRRITATION,ACUTE CENTRAL NERVOUS SYSTEM
DEPRESSION-HEADACHE,DIZZINESS,STAGGERING GAIT, CONFUSION OR
UNCONSCIOUSNESS.ASPHYXIATION. SKIN: PROLONG/REPEAT CONTACT CAUSES
IRRITATI ON, DEFATTING OR DERMATITIS. EYE: IRRITATION. INGEST: MAY
CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING & DIARRHEA
Explanation of Carcinogenicity:THE CHROMIUM COMPOUND IS LISTED AS A
CARCINOGEN BY THE IARC & NTP.
Effects of Overexposure:ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE
CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. REPORTS HAVE ASSOCIATED
REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND N ERVOUS SYSTEM DAMAGE. EFFECT INCLUDE
CONCENTRATION DIFFICULTIES, DIMINISHED MANUAL DEXTERITY AND MEMORY
LOSS.
Medical Cond Aggravated by Exposure:SKIN,LUNG,EYE CONDITIONS. LAB
ANIMALS EXPOSED TO TOLUENE HAD DAMAGED LIVER, KIDNEYS, LUNG,
SPLEEN. XYLENE CAUSES LIVER, KIDNEY, LUNG, SPLEEN, HEART, ADRENALS
DAMAGE. PREG LAB MICE,EMBRYO/ FETO EFFECTS
* First Aid Measures *
First Aid:INHALATION: REMOVE PERSON TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION IF REQUIRED. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
KEEP WARM & QUIET. GET MEDICAL ATTN. SKIN: WASH AREAS WITH SOAP &
WATER. DO NOT USE SOLVENTS. REMOVE CONTAMINATED CLOTHING & WASH
MINUTES. GET MEDICAL ATTN. PREFER AN OPTHALMOLOGIST. INGESTION: GET
MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1.
Extinguishing Media:EXTINGUISHERS (CARBON DIOXIDE, DRY CHEMICAL OR
FOAM)
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE,USE TO COOL FIRE
EXPOSED CNTNRS. FOG NOZZLE IS PREFERABLE. WEAR NIOSH/MSHA APPROVED
SELF- CONTAINED BREATHING APPARATUS/PROTECT CLOTHES
Unusual Fire/Explosion Hazard:VAPORS MAY ACCUMULATE IN CONFINED AREAS,
FORM EXPLOSIVE MIX W/AIR. VAPORS MAY TRAVEL DISTANCES & FLASHBACK
OR FLAME TO THE HANDLING SITE. CNTNRS MAY EXPLODE.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITE SOURCES. WEAR PERSONAL
PROTECTIVE EQUIP. AVOID BREATHING VAPORS & SKIN OR EYE CONTACT. USE
NON- SPARK TOOLS. USE EMERGENCY RESPONSE PRO IF MANAGING RELEASE IS
BEYOND CAPABILITY OF IN -HOUSE PERSONS. SM:DIKE & ABSORB W/INERT
MATERIAL.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. ISOLATE
FLAMMABLE LIQ IN ACCORD W/NFPA CODES/GOVERNMENT REG
Other Precautions:FOLLOW GROUND/BOND PROCEDURES WHEN TRANSFERRING.AVOID
FREE FALL OF LIQ.DO NOT SMOKE WHERE MATERIAL IS USED OR STORED.DO
NOT APPLY TO HOT SURFACES.EMPTIES MAY CONTAIN EXPLOSIVE VAPORS.DO
NOT CUT, PUNCT URE, WELD ON DRUM.DO NOT TAKE INTERNALLY
* Physical/Chemical Properties *
HCC:F2
Vapor Density:> THAN AIR
Spec Gravity:< WATER
Evaporation Rate & Reference:SLOWER THA N-BU AC
Appearance and Odor:LIQUID, SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION ARE HAZARDOUS
INCLUDING CARBON MONOXIDE AND CARBON DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:ENSURE MATERIAL IS PACKAGED, STORED, TRANSPORTED
& OTHERWISE MANAGED IN ACCORD W/LOCAL,STATE & FED REGS. NO DISPOSAL
METHOD IS TO BE USED THAT WOULD POSE ENVIR OR HUMAN HEALTH THREAT
INCLUDING ANY WHI CH WOULD CONTAMINATE GROUND/SURFACE WATER.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPRVD RESP W/FILTER CARTRIDGES
APPRVD FOR DUST/FUMES/MISTS SHOULD BE WORN AT ALL TIMES DURING
SPRAY PROCESS TO PROTECT OPERATOR FROM EXPOS TO DUST & FUMES.
NIOSH/MSHA APPRVD RESPS MAY ALSO BE WORN WHEN PROD HNDLG GENERATES
DUST.
Ventilation:PRODUCT SHOULD BE USED WITH THE APPROPRIATE LOCAL EXHAUST
VENTILATION PROVIDED.
Other Protective Equipment:EAR PROT WHEN EXCESS NOISE LEVELS (REFER TO
APPROP GUIDELINES). ALUMINIZED APRON DURING PLASMA SPRAY PROCESS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: FINE METAL DUSTS OF MOLYBDENUM ARE FLAM & MAY EXPLODE IF
EXPOS TO HEAT/FLAME/OXIDIZERS. COBALT MAY IGNITE IF AIRBORNE IN
PRESENCE OF IGNIT SOURCE/SPONT. CHROMIUM MAY IGNITE IF AIRBORNE IN
P RESENCE OF IGNIT SOURCE. HAZ DECOMP PROD: WHEN MOLYBDENUM IS
HEATED TO DECOMP, TOX FUMES OF MOLYBDENUM ARE EMITTED.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SILICON
Fraction by Wt: 2.5%
Ingred Name:MOLYBDENUM
Ingred Name:COBALT (SARA III)
OSHA PEL:0.1 MG/M3 AS CO
Ingred Name:NICKEL (SARA III)
Fraction by Wt: 1%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Ingred Name:CHROMIUM (SARA III)
Fraction by Wt: 8.5%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:EXPLAN OF CARCIN: FIBROSIS (BLOOD EFTS). NICKEL: IARC
MONOGRAPHS ON EVALUATION OF CARCIN RISK OF CHEMS TO MAN, (ING 7)
Ingred Name:EFTS OF OVEREXP: SKIN & EYES. PORTION OF METALLIC
MOLYBDENUM MAY BE CONVERTED DURING THERMAL SPRAY PROCESS TO (ING 9)
Ingred Name:ING 8:MOLYBDENUM OXIDE. TARGET ORGANS:RESP TRACT, KIDNEYS,
Ingred Name:ING 9: BY INHAL & SKIN CNTCT. INHAL MAY CAUSE PROGRESSIVE,
TARGET ORGANS: LUNGS, SKIN.
BE WORN DURING OTHER PHASES OF PROD HNDLG TO AVOID SKIN CNTCT.
Ingred Name:EYE PROT: COMBUST SPRAYING SHADE #5, PLASMA SPRAYING UP TO
PHASES OF PRODUCT HANDLING.
Ingred Name:OTHER PROT EQUIP: OTHER APPROP PROT CLTHG MAY BE WORN AS
WASH FACILITIES ARE RECOMMENDED.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SILICON:NO KNOWN TOX ASSOC W/INHAL.
UNDER NORM USE/CNDTNS SILICON DIOXIDE IS FORMED; INHAL MAY CAUSE
PNEUMOCONIOSIS:SILICOSIS. SILICOSIS IS PULM FIBROSIS CHARACT BY GEN
FIBROTIC CHG ON X-RAY EXAM, SHO RTNESS OF BREATH, COUGH, DECR CHEST
EXPANSION, LESSENED CAPACITY FOR WORK & INCR SUSCEPTIBILITY TO
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:COBALT: IARC MONOGRAPHS ON EVALUATION OF
ANIMAL:PULM (ING 6)
Effects of Overexposure:HLTH HAZ: TB. TARGET ORGAN:LUNGS.
MOLYBDENUM:HAZ BY INHAL, INGEST, SKIN & EYE CNTCT. INHAL MAY CAUSE
RESP TRACT IRRIT & PNEUMOCONIOSIS. INHAL OF METALLIC DUST FROM
ALLOYS & CARBIDES MAY CAUSE HARD MET AL LUNG DISEASE. INGEST MAY
CAUSE ANEMIA, LIVER & KIDNEY FATTY DEGENERATION. SKIN & EYE CNTCT
MAY CAUSE IRRIT TO (ING 8)
Medical Cond Aggravated by Exposure:CONSULT A PHYSICIAN.
* First Aid Measures *
First Aid:EYES: FLUSH EYE WITH SUFFICIENT AMOUNTS OF WATER FOR AT LEAST
SOAP AND WATER. INHALATION: EXPOSE TO FRESH AIR. CONSULT MD IF
IRRITATIONOR RESPIRATORY DISTRESS PERSISTS. INGESTION: CONSULT
MD.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE CLASS D FIRE EXTINGUISHER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . TREAT AS A METALLIC FIRE.
Unusual Fire/Explosion Hazard:FINE METAL DUSTS ARE FLAM & MAY EXPLODE
WHEN EXPOS TO HEAT/FLAME/OXIDIZERS. SILICON MAY IGNITE IF EXPOS TO
FLAME/OXIDIZERS;DO NOT HEAT/EXPOSE TO WATER. (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:VACUUM LOOSE POWDER ONLY WITH VACUUMS EQUIPPED
WITH HEPA FILTRATION. VACUUMS APPROPRIATE FOR USE W/METALLIC DUSTS
SHOULD BE UTILIZED. WIPE THE AREA CLEAN. DO NOT USE WATER FOR CLEAN
UP OPERATIONS. DO NOT SWEEP. AVOID GENERATING AIRBORNE DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM INCOMPATS. STORE
PRODUCT CNTNRS IN A WELL-VENT, CLEAN, COOL & DRY AREA. STORE IN A
MANNER TO MINIMIZE PUNCTURES & BREAKAGE OF CNTNRS.
Other Precautions:AVOID INGESTION, INHALATION AND EXCESSIVE SKIN
CONTACT. AVOID CONTACT OF POWDER WITH WATER AND OXIDIZERS.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:4.5 (H*2O=1)
Solubility in Water:NEGATIVE
Appearance and Odor:POWDER; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS, ACIDS, SULFUR, NI(NO*3)*2, COMBUSTIBLES. MOLYBDENUM MAY
REACT W/WATER TO FORM EXPLOSIVE HYDROGEN GAS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:OZONE & NITRIC OXIDE ARE FORMED BY
PLASMA FLAME(SIMILAR TO WELD FUMES). ACTION IS INDEPENDENT OF METAL
POWDER. (SUPDAT)
* Disposal Considerations *
Waste Disposal Methods:EMPTY PRODUCT CONTAINERS, PRODUCT WASTE AND
CLEANING MEDIA SHOULD BE STORED AND DISPOSED OF ACCORDING TO THE
APPROPRIATE LOCAL, STATE AND FEDERAL REGULATORY GUIDELINES.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE A FUME RESPIRATOR OR AIR SUPPLIED RESPIRATOR
WHEN WELDING IN CONFINED SPACES/WHERE VENTILATION IS INADEQUATE IN
MAINTAINING EXPOSURE <TLV. DETERMINE THE COMPOSITION/QUANTITY OF
FUMES/GASES BY TAKI NG AN AIR SAMPLE FROM INSIDE HELMET.
Ventilation:USE ENOUGH VENTILATION, LOCAL EXHAUST AT THE ARC, OR BOTH
TO KEEP FUMES & GASES FROM THE WORKER'S BREATHING ZONE & <TLV.
Other Protective Equipment:ARM/SHOULDER PROTECTORS, APRONS, HATS,
WELDER'S HELMET. SEE SUPP FOR LENSE SHADE RECOMMENDATIONS.
Work Hygienic Practices:INGESTION OF MATERIAL IS POSSIBLE VIA DIRTY
HAND CONTACT W/FOOD & MOUTH.
Supplemental Safety and Health
START W/LENSE SHADE THAT IS TOO DARK TO SEE THE WELD ZONE. THEN GO TO A
LIGHTER SHADE (LOWER NUMBER SHADE) WHICH GIVE SUFFICIENT VIEW OF
OXIDES/FLUORIDES OF AL, BA, CA, MG, K, NA, SR, & TI. WELDING
PRODUCES CHEMICALS KNOWN TO CAUSE CANCER BY THESTATE OF CA.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CALCIUM OXIDE
OSHA PEL:5 MG/M3
Ingred Name:MAGNESIUM
Ingred Name:MAGNESIUM OXIDE
Ingred Name:POTASSIUM
Ingred Name:POTASSIUM DIOXIDE
Ingred Name:SODIUM (SARA III)
Ingred Name:SODIUM OXIDE
Ingred Name:STRONTIUM
Ingred Name:STRONTIUM OXIDE
Ingred Name:TITANIUM (DRY POWDER) (TI)
Ingred Name:TITANIUM DIOXIDE
Ingred Name:NICKEL (SARA III)
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/M3
Ingred Name:COBALT (SARA III)
Fraction by Wt: 2%
OSHA PEL:0.1 MG/M3;AS CO
Ingred Name:CHROMIUM (SARA III)
OSHA PEL:1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:MOLYBDENUM
Fraction by Wt: 5.5%
Ingred Name:TUNGSTEN
Fraction by Wt: 2.5%
Ingred Name:IRON
OSHA PEL:5 MG/CUM
Ingred Name:SILICON
Fraction by Wt: 1%
Ingred Name:MANGANESE (SARA III)
Fraction by Wt: 1%
OSHA PEL:(C) 5 MG/M3 DUST
Ingred Name:COPPER (SARA III)
Fraction by Wt: 2%
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1MG/M3 FUME/1 DUST
Ingred Name:COLUMBIUM, NIOBIUM
Other REC Limits:5 MG/CUM
Ingred Name:ALUMINUM (SARA III)
Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS
FORMS) (SARA III)
Ingred Name:BARIUM (SARA III)
OSHA PEL:0.5 MG/M3
Ingred Name:CALCIUM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: NUISANCE DUST CAUSES
MUCOUS MEMBRANE/RESPIRATORY/NOSE/THROAT IRRITATION, DIZZINESS,
PULMONARY IRRITANT, TIGHTNESS IN CHEST, METAL FUME FEVER, MUSCLE
ACHE, DRY THROAT, COUGHING, LOW BACK PA IN, FATIGUE/HEADACHE. SKIN:
ALLERGIC REACTION/DERMATITIS. INGESTION: METALLIC
TASTE/NAUSEA/BURNS/VOMITING. EYE: INJURY.
Explanation of Carcinogenicity:CHROMIUM & NICKEL ARE ANIMAL & HUMAN
CARCINOGENS.
Effects of Overexposure:INHALATION: POSSIBLE LUNG FIBROSIS, RESPIRATORY
HYPERSENSITIVITY/AFFECTS CENTRAL NERVOUS SYSTEM/MUSCULAR WEAKNESS,
TREMORS, SYMPTOMS SIMILAR TO PARKINSON'S DISEASE & SIDEROSIS
(BENIGN). ELECTRIC SHOCK CAN KILL. SHIELDING GASES CAN
DISPLACEBREATHING AIR & CAUSE ASPHYXIATION IN CONFINED WORK
SPACES/UNVENTILATED AREAS.
Medical Cond Aggravated by Exposure:RESPIRATORY ALLERGIC CONDITIONS.
SOME STUDIES SHOW A HIGHER LEVEL OF LUNG RELATED PROBLEMS AMONG
OLDER WORKERS WHO SMOKE THAN THOSE WHO DID NOT SMOKE.
* First Aid Measures *
REMOVE VICTIM FROM THE WELDING AREA. IF VICTIM IS UNCONSCIOUS,
ADMINISTER OXYGEN. IF VICTIM IS NOT BREATHING, BEGIN RESUSCITATION.
INGESTION:EMPLOY THE FIRST AID TECHNIQUES RECOMMENDED BY THE
AMERICAN RED CROSS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
Extinguishing Media:EXTINGUISHING MEDIA SUITABLE FOR SURROUNDING FIRE.
"CUTTING & WELDING PROCESSES" BEFORE USING THIS PRODUCT.
Unusual Fire/Explosion Hazard:PRODUCT IS NON-FLAMMABLE & NON-EXPLOSIVE,
AS SHIPPED. WELDING ARCS & SPARKS CAN IGNITE COMBUSTIBLES &
INITIATE FIRES & EXPLOSIONS.
* Accidental Release Measures *
Spill Release Procedures:IF THE FUMES ARE REMOVED BY FILTRATION/SOME
OTHER MEANS & AIR/GAS STREAM IS PUT BACK INTO THE ROOM, GASES MAY
BUILD UP TO TOXIC OR ASPHYXIATION LEVELS. GAS BUILD-UP SHOULD BE
MONITORED & IF EXCESSIVE SHOULD BE REMOVED/REDUCED TO SAFE LEVELS.
*Handling and Storage *
Handling and Storage Precautions:ARCS PRODUCE ULTRAVIOLET/INFRARED
RADIATION. SMAW ELECTRODES ARE METAL CORE RODS COATED W/FLUX. AVOID
PHYSICAL ACCIDENTS. READ LABELS.
Other Precautions:TRAIN WELDER TO AVOID ELECTRIC SHOCK BY MAINTAINING A
DRY WORK AREA, INSULATING FROM THE WORKPIECE & GROUND. DON'T TOUCH
LIVE ELECTRICAL PARTS. PREVENT INJURY FROM RADIATION/SPARKS/&
ELECTRIC SHOCK. K EEP HEAD OUT OF WELDING PLUME.
* Physical/Chemical Properties *
Spec Gravity:7-9
Solubility in Water:INSOLUBLE
Appearance and Odor:BARE WIRE WELDING PRODUCTS ARE PRODUCED AS STRAIGHT
LENGTHS & COILED WIRES.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:CO/CO2/OZONE/OXIDES OF
NITROGEN/CHROMIUM II & III/NICKEL/COBALT/COPPER. WELDING
FUMES/GASES CANNOT BE EASILY CLASSIFIED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF FUME, FLUX & WELD GRINDING RESIDUES
FROM THE WORK AREA, OR FROM FILTERS, IN ACCORDANCE W/LOCAL, STATE,
& FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO MINIMIZE CONTACT WITH SKIN.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHES AND WASH BEFORE REUSE.
Supplemental Safety and Health
EXTING MEDIA: WATER SPRAY, FOG OR ALCOHOL-RESISTANT FOAM. DO NOT USE
STRAIGHT STREAMS OF WATER. OTHER PRECS: SPKS/OPEN FLAMES. EXPOS
* Product Identification *
* Composition/Information on Ingredients *
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYE: CAUSES SEVERE EYE IRRITATION.
VAPORS MAY CAUSE EYE IRRITATION. SKIN: PROLONGED AND/OR REPEATED
CONTACT MAY CAUSE IRRITATION AND/OR DERMATITIS. SUBSTANCE IS
RAPIDLY ABSORBED THROUGH THE SKIN. IF A BSORBED, CAUSES SYMPTOMS
SIMILAR TO INHALATION. STRONG IRRITANT OF THE SKIN. INGESTION: MAY
CAUSE IRRITATION OF THE DIGESTIVE TRACT. MAY CAUSE EFFECTS SIMILAR
TO THOSE FOR INHALATION EXPOSURE. INHALAT ION: MAY CAUSE
RESPIRATORY TRACT IRRITATION. MAY CAUSE KIDNEY DAMAGE. MAY BE
HARMFUL IF INHALED. INHALATION MAY PRODUCE NAUSEA, VOMITING,
ANOREXIA, COLIC, HIGH BLOOD PRESSURE, HEPATOMEGALY, JAUNDICE A ND
(EFFECTS OF OVEREXPOSURE)
Explanation of Carcinogenicity:DIMETHYLFORMAMIDE: IARC MONOGRAPHS ON
Effects of Overexposure:HEALTH HAZARDS: ALTERED LIVER FUNCTION.
CHRONIC: POSSIBLE CANCER HAZARD BASED ON TESTS WITH LABORATORY
ANIMALS. PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS.
* First Aid Measures *
First Aid:EYES: IMMEDIATELY FLUSH EYES W/PLENTY OF WATER FOR AT LEAST
AID IMMEDIATELY. SKIN: GET MEDICAL AID IMMEDIATELY. IMMEDIATELY
REMOVING CONTAMINATED CLOTHING & SHOES. INGEST: IF VICTIM IS
CONSCIOUS & ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. NEVER GIVE
ANYTHING BY MOUTH T O UNCONSCIOUS PERSON. GET MEDICAL AID
IMMEDIATELY. INHAL: GET MEDICAL AID IMMEDIATELY. REMOVE FROM
EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIF FICULT, GIVE OXYGEN.
NOTES TO MD: NONE.
* Fire Fighting Measures *
Lower Limits:2.2%
Extinguishing Media:FOR SMALL FIRES, USE DRY CHEM, CARBON DIOXIDE,
WATER SPRAY OR ALCOHOL-RESIST FOAM. USE WATER SPRAY TO COOL
FIRE-EXPOSED CNTNRS. WATER MAY BE INEFTIVE. FOR LARGE FIRES, USE
(SUPDAT)
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . CONTACT PROFESSIONAL FIRE-FIGHTERS IMMEDIATELY. COOL
CONTAINERS W/FLOODING QUANTITIES OF WATER UNTIL WELL AFTER FIRE IS
OUT. NFPA RATING: HEALTH-1; FLAMMABILITY-2; REACTIVITY-0.
Unusual Fire/Explosion Hazard:VAPORS CAN TRAVEL TO SOURCE OF IGNITION &
FLASH BACK. USE WATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.
FLAMMABLE LIQUID. VAPORS MAY BE HEAVIER THAN AIR. THEY CAN SPREAD
ALONG GROUND & COLLECT IN LOW OR CONFINED AREAS. VAPORS MAY FORM
AN EXPLOSIVE MIXTURE W/AIR. CONTAINERS MAY EXPLODE WHEN HEATED.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED IN EXPOSURE CONTROLS, PERSONAL PROTECTION. ABSORB SPILL
W/INERT MATERIAL (EG, DRY SAND OR EARTH), THEN PLACE INTO CHEMICAL
WASTE CONTAINER. DO NOT FLUSH INTO A SEWER. REMOVE ALL SOURCES OF
IGNIT. A VAPOR SUPPRESSING FOAM MAY BE USED TO REDUCE VAPORS. WATER
SPRAY MAY REDUCE VAPOR BUT MAY NOT PREVENT IGNITION IN CLOSED
SPACES.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME.
KEEP AWAY FROM SOURCES OF IGNIT. STORE IN TIGHTLY CLOSED CNTNR.
KEEP FROM CONTACT W/OXIDIZING MATLS. STORE IN A COOL, DRY,
WELL-VENTD AREA AWAY FROM INCOMPATIBLE S UBSTANCES. WASH THOROUGHLY
AFTER HNDLG. REMOVE CONTAM CLTHG & WASH BEFORE REUSE. USE W/ADEQ
VENT.
Other Precautions:GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. AVOID
CNTCT W/EYES, SKIN & CLTHG. EMPTY CNTNRS RETAIN PROD RESIDUE (LIQ
&/OR VAP) & CAN BE DANGEROUS. KEEP CNTNR TIGHTLY CLSD. AVOID CNTCT
W/HEAT, SPKS & F LAME. AVOID INGEST & INHAL. DO NOT PRESSURIZE,
CUT, WELD, BRAZE, SOLDER, DRILL, GRIND/EXPOSE EMPTY C NTNRS TO
(SUPDAT)
* Physical/Chemical Properties *
Vapor Density:2.5(AIR=1)
pH:6.7
Solubility in Water:SOLUBLE
Appearance and Odor:CLEAR, COLORLESS TO PALE YELLOW LIQUID - CLEAR;
AMINE-LIKE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS (MINERAL, NON-OXIDIZING, EG HYDROCHLORIC ACID, HYDROFLUORIC ACID,
MURIATIC ACID, PHOSOPHORIC ACID), ACIDS (MINERAL, OXIDIZING, EG
CHROMIC ACID, HYPOCHLOROUS ACID, NITRIC ACID, SULFURIC ACID),
METALS (ALKALI & ALKALINE
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES,
STRONG OXIDANTS.
Hazardous Decomposition Products:CARBON MONOXIDE, OXIDES OF NITROGEN,
CARBON DIOXIDE.
* Toxicological Information*
HUMAN CARCINOGEN. O SHA: POSSIBLE SELECT CARCINOGEN. IARC:GROUP 2B
CARCINOGEN. EPIDEMIOLOGY: A SIGNIFICANT EXCESS OF PROSTATE CANCER
WAS OBSERVED AMONG WORKERS EXPOSED TO DMF AND ACRYLONITRILE.
TERATOGENICITY: EXPERIMENT AL TERATOGEN EFFECTS HAVE BEEN REPORTED.
REPRODUCTIVE EFFECTS: EXPERIMENTAL REPRODUCTIVE EFFECTS HAVE BEEN
REPORTED. NEUROTOXICITY: NO DATA AVAILABLE. MUTAGENICITY: HUMAN
MUTATION DATA REPORTED. OTHER STUDIES: NO DATA AVAILABLE.
* Ecological Information *
Ecological:EXOTOXICITY: NOT AVAIL. ENVIRONMENTAL FATE: SUBSTANCE
EXPECTED TO BIODEGRADE RAPIDLY IN ENVIRONMENT & SHOULD BE HIGHLY
MOBILE IN SOIL. PHYSICAL/CHEM:NOT AVAIL. OTHER:NOT AVAIL. --FED REG
INFO:POLLUTAN TS UNDER CWA. NONE OF CHEMS IN PROD CONSIDERED HIGHLY
HAZ BY OSHA. EUROPEAN INTERNATIONAL REGS - EUROPEAN LABELING I/A/W
EXPOS - OBTAIN S PEC INSTRUCTIONS (TRANSPORT INFO)
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF
CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE
LEVELS: NONE LIS TED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES:
NONE LISTED. RCRA U-SERIES: NONE LISTED.
* MSDS Transport Information *
Transport Information:SHIPPING NAME - US DOT: N,N-DIMETHYLFORMAMIDE,
IATA:NO INFO AVAIL, RID/ADR:NO INFO AVAIL, IMO:NO INFO AVAIL,
CANADA TDG: N,N-DIMETHYLFORMAMIDE. HAZ CLASS - US DOT:3; CANADA
GROUP-US DOT:III; CANADA TDG:III. ADDNL INFO: CANADA TDG: FL PT
LIST. PROD HAS WHMIS CLASSIFICATION OF B3, D2B. NOT LISTED ON
* Regulatory Information *
INVENTORY. HLTH & SAFETY REPORTING LIST: EFTIVE DATE: APRIL
PROD ARE UNDER CHEM TEST RULE. NONE OF CHEMS ARE LISTED UNDER TSCA
CNTN ANY CLASS 1 OZONE DEPLETORS. MATL D OES NOT CNTN ANY CLASS 2
OZONE DEPLETORS. CLEAN WATER ACT: NONE OF CHEMS IN PROD ARE LISTED
AS HAZ S UBSTANCES UNDER CWA. NONE OF CHEMS ARE LISTED AS PRIORITY
POLLUTANTS UNDER CWA. NONE OF CHEMS IN PROD LISTED AS TOXIC
(ECOLOGICAL INFO)
STATE RIGHT TO KNOW LISTS: CA, NJ, FL, PA, MN, MA. CA NO
SIGNIFICANT RISK LEVEL:NONE OF CHEMS IN PROD LISTED. --SARA TITLE
KOREA CHECK ACGIH TLV. OEL NEW ZEALAND, SINGAPORE, VIETNAM CHECK
ACGIH TLV.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:GOOD VENTILATION(TYPICALLY 4-6RM VOL/HR)SHOULD BE
USED.VENTILATION RATES SHOULD BE MATCHED TO CONDITIONS.
Other Protective Equipment:WASHING FACILITIES.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
OTHER PRECAUT:HOWEVER ITS NOT EXPECTED TO CAUSE ANY ADVERSE ENVIRO
EFFECTS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:IRON POWDER
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:5 MG/M3 (OXIDE FUME)
Ingred Name:STYRENE BUTYLACRYLATE COPOLYMER
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:VINYLIDENE FLUORIDE HOMOPOYMER
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:RED AZO PIGMENT
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:BENZYLDIMETHYLOCTADECYLAMMONIUM
CHLORIDE;(BENZENEMETHANAMINIUM SALT)
Fraction by Wt: <0.1%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL:EXPECTED TO BE LOW HAZ FOR
RECOMMENDED HNDLG.EYE:NO SPECIFIC HAZ KNOWN.MAY CAUSE TRANSIENT
IRRIT.SKIN:EXPECTED TO BE LOW HAZ FOR RECOMMENDED
HNDLG.INGEST:EXPECTED TO BE LOW INGEST HAZ.
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY
CLASSIFICATION:IARC/ACGIH/NTP/OSHA:NONE.
Effects of Overexposure:TRANSIENT EYE IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:SYMPTOMATIC MOVE TO FRESH AIR.TREAT
SYMPTOMATICALLY.SYMPTOMS PERSIST GET MED ATTN.EYE:ANY MATL THAT
CONTACTS EYE SHOULD BE WASHED OUT IMMED W/WATER.SYMPTOMS OCCUR GET
MED ATTN.SKIN:WASH W/SOAP/W ATER.SYMPTOMS OCCUR GET MED
ATTN.INGEST:DRINK 1-2 GLASSES OF WATER.SEEK MED ATTN.NEVER GIVE
ANYTHING BY MOUTH TO UNCONSC PERSON.
* Fire Fighting Measures *
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:WATER SPRAY,CARBON DIOXIDE (CO2), DRY CHEMICAL.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING.FIRE OR EXCESSIVE HEAT MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS.
Unusual Fire/Explosion Hazard:POWDERED MATERIAL MAY FORM EXPLOSIVE
DUST-AIR MIXTURES.COMBUSTIBLE SOLID.
* Accidental Release Measures *
Spill Release Procedures:DONT USE VACUUM CLEANER TO CLEAN UP SPILLS OF
POWDERED DEVELOPERS & TONERS.THE VERY FINE PARTICLES CAN CAUSE FIRE
OR EXPLOSION.SWEEP MATERIAL ONTO PAPER & PLACE IN FIBER
CARTON.AVOID GENERATION OF DUS T.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID BREATH DUST.USE W/ADEQU
VENTI.POWDERED MATL MAY FORM EXPLO DUST-AIR MIXTURES.MIN DUST
GENERATION/ACCUMULATION.KEEP AWAY FRM IGN SOURCES.
IN CHEM/DYE/PHARMA/PLASTICS INDUSTRIES".KEEP FROM CONTACT
W/OXIDIZING MATLS.KEEP CNTNR CLSD.MATL HASNT BEEN TESTED FOR ENVIRO
IN SPILL SITU ATION MATL MAY BE VISUALLY(SUPPLEMENTAL)
* Physical/Chemical Properties *
HCC:N1
Boiling Pt:B.P. Text:NP
Melt/Freeze Pt:M.P/F.P Text:N/AVAI
Decomp Temp:Decomp Text:NP
Vapor Pres:NEGLIGIBLE
Vapor Density:NEGLIGIBLE
Spec Gravity:N/AVAI
pH:NA
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:NELGIGIBLE
Appearance and Odor:SOLID (POWDER), RED COLOR, SLIGHT ODOR
Percent Volatiles by Volume:NEGLIG
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:HAZ COMBUSTION PRODUCTS:CARBON
DIOXIDE, CARBON MONOXIDE, OXIDES OF IRON.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE/LANDFILL.CAN BE INCINERATED WHEN IN
COMPLIANCE W/LOC REGS.DISCHARGE/TREAT/DISPO SUBJ TO NAT/STATE/LOC
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Item Description Information
*
Item Name: TONER,DIRECT ELECTROSTATIC PROCESS
*
Ingredients
*
(MIXTURE WITH INGREDIENT 2))
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
& 2ETHYLHEX 2PROPEN; (STYRENE ACRYLIC RESIN (MIXTURE WITH INGREDIENT 1))
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 3-7
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 1-5
OSHA PEL: 3.5 MG/M3
ACGIH TLV: 3.5 MG/M3
------------------------------
% Wt: 0.1-1
OSHA PEL: 6 MG/M3
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: YES
OSHA: NO
Effects of Exposure: EYE: MECH EYE IRRIT: SIGNS/SYMPTOMS CAN INCLUDE IRRIT,
REDNESS, SCRATCHING OF CORNEA & TEARING. SKIN: MECH SKIN IRRIT:
SIGNS/SYMPTOMS CAN INCLUDE ITCHING & REDNESS. INHAL: IRRIT (UPPER RESP):
SIGNS/SY MPTOMS CAN INCL SORENESS OF NOSE & THROAT, COUGHING &
SNEEZING. INGEST: IRRIT OF GI TISS: SIGNS/SYMPS (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CARBON BLACK: IARC MONOGRAPHS ON THE EVAL OF
Signs And Symptions Of Overexposure: HLTH HAZ: CAN INCLUDE PAIN, VOMIT, ABDOM
TENDERNESS, NAUS, BLOOD IN VOMITUS & BLOOD IN FECES. WHILE THE FOLLOWING
EFTS ARE ASSOCIATED W/ONE OR MORE OF INDIVIDUAL INGREDS IN PROD & ARE
REQD TO BE INCLU DED ON MSDS BY OSHA STDS, THEY ARE NOT EXPECTED EFTS DURING
FORSEEABLE USE OF PROD. PNEUMOCONIOSIS (GENERAL): SIGNS/SYMPS CAN INCL
PERSISTENT COUGH & SHORTNESS OF BREATH.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD (FP N).EYES:
GET IMMEDIATE MEDICAL ATTENTION. INHALATION: IF SIGNS/SYMPTOMS OCCUR, REMOVE
PERSON TO FRESH AIR. IF SIGNS/SYMPTOMS CONTINUE, CALL MD. INGESTION: DRINK
TWO GLASSES OF WATER. CALL MD.
*
Handling and Disposal
*
Spill Release Procedures: OBSERVE PRECAUTIONS FROM OTHER SECTIONS. VACUUM TO
AVOID DUSTING. CAUTION! A VACUUM CLEANER COULD BE AN IGNITION SOURCE. CLEAN
UP RESIDUE WITH WATER. PLACE IN A CLOSED CONTAINER. CAUTION: POWDER SPILL ON
FLOORS MAY CREATE A SLIP HAZARD.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL IN A SANITARY LANDFILL OR AN INDUSTRIAL
INCINERATOR MAY BE OPTION. SINCE REGULATIONS AND DISPOSAL OPTIONS VARY,
CONSULT APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS OR WASTE DISPOSAL
AUTHO RITIES PRIOR TO DISPOSAL.
Handling And Storage Precautions: STORE AT ROOM TEMPERATURE. KEEP OUT OF THE
REACH OF CHILDREN.
Other Precautions: KEEP AWAY FROM HEAT, SPARKS, OPEN FLAME AND OTHER SOURCES OF
IGNITION. AVOID EYE CONTACT. AVOID PROLONGED/REPEATED SKIN CONTACT. AVOID
PROLONGED BREATHING OF DUST.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: DUST CLOUDS OF THIS MATERIAL IN COMBINATION WITH
AN IGNITION SOURCE MAY BE EXPLOSIVE.
*
*
Respiratory Protection: AVOID PROLONGED BREATHING OF DUST. USE NIOSH APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: USE IN A WELL-VENTILATED AREA.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: AVOID EYE CONTACT. AVOID PROLONGED OR REPEATED SKIN
CONTACT. WASH HANDS AFTER HANDLING AND BEFORE EATING.
*
Physical/Chemical Properties
*
Spec Gravity: 0.3-0.5(H*2O=1)
Solubility in Water: NIL
Appearance and Odor: FINE BLACK POWDER; ESSENTIALLY ODORLESS.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEMPERATURE STORAGE CAN CAUSE CLUMPING
OF TONER POWDER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: COMBUSTION PRODUCTS MAY INCLUDE CARBON
DIOXIDE, CARBON MONOXIDE, HYDROCARBONS, STYRENE MONOMER & CARBON
PARTICULATES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Company Name: MINNESOTA MINING AND MFG CO ENGINEERING DOCUMENT SYSTEMS DIV
Street: 3M CTR
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: EYES: IRRITATION, REDNESS, SCRATCHING OF CORNEA
AND TEARING. SKIN: IRRITATION, ITCHING AND REDNESS. INHALATION: UPPER
RESPIRATORY IRRITATION, SORENESS OF NOSE AND THROAT, COUGHING AND SNEEZING.
INGESTION: IRRITATION OF GASTROINTESTINAL TISSUES, PAIN, VOMITING, ABDOMINAL
TENDERNESS, NAUSEA, BLOOD IN VOMITUS AND IN FECES. POSSIBLE PNEUMOCONIOSIS;
PERSISTANT COUGH AND SHORTNESS OF BREATH. CHRO NIC: CANCER HAZARD. CONTAINS
CARBON BLACK WHICH IS LISTED AS AN ANIMAL LUNG CARCINOGEN (FP N).
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE ONLY W/VENT TO KEEP LEVELS BELOW EXPOSURE
GUIDELINES. USER SHOULD TEST & MONITOR EXPOSURE LEVELS TO INSURE
ALL PERSONNEL ARE BELOW GUIDELINES. IF NOT SURE OR IF NOT ABLE TO
MONITOR, USE NIOSH APPR OVED AIR-PURIFYING RESPIRATOR.
Ventilation:USE EXPLOSION-PROOF VENTILATION WHEN REQUIRED TO KEEP BELOW
HEALTH EXPOS GUIDELINES & LOWER EXPLOSION LIMIT (LEL).
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . RECOM
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
APPLYING COSMETICS OR USING TOILET FACILITIES. USE OF HAND CLEANER
(SUPDAT)
Supplemental Safety and Health
EXPLO HAZ: VAP BELOW LOWER EXPLOSION LEVEL (LEL). SPILL PROC: & SEAL
TIGHTLY FOR PROPER DISP. HNDLG/STOR PRECS: MATLS GROUND ALL CNTNRS
& TOOLS. ALSO WEAR PROT EQUIP. OTHER PROT EQUIP: PENETRATES TO S
CLTHG BEFORE REUSE. LEATHER SHOES CAN ABSORB (ING 7)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM SILICOFLUORIDE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:COLOR PIGMENT MIXTURE MAY CONTAIN INGREDS 3-5 & OTHER
PARTICULATES IN VARYING AMOUNTS DEPENDING ON COLOR OF PRODUCT
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:IRON OXIDES
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM DIOXIDE
Ingred Name:CARBON BLACK
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPDAT: & PASS THRU HAZARDOUS MATLS. CHECK SHOES CAREFULLY
AFTER SOAKING BEFORE REUSE. FOR INDUSTRIAL USE ONLY.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: OVEREXPOSURE WILL BE
IRRITATING TO MUCOUS MEMBRANES. CONTACT: CAN CAUSE EYE IRRITATION.
CAN CAUSE SKIN IRRITATION. WARNING: THIS PRODUCT CONTAINS A
CHEMICAL(S) KNOWN TO THE STATE OF CALIFO RNIA TO CAUSE CANCER AND
BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:IF YOU HAVE A CONDITIONS THAT COULD
BE AGGRAVATED BY EXPOSURE TO DUST OR ORGANIC VAPORS SEE MD PRIOR TO
USE.
* First Aid Measures *
WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING AND CLEAN BEFORE
REUSE. INHAL: REMOVE TO FRESH AIR. PROVIDE OXYGEN IF BREATHING IS
DIFFICUL T. USE ARTIFICIAL RESPIRATION IF NOT BREATHING. GET
MEDICAL ATTENTION. INGEST: DO NOT INDUCE VOMITING! ALWAYS GET
MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT . EVACUATE HAZARD AREA OF UNPROTECTED PERSONNEL. COOL
SURROUNDING CNTNRS W/WATER IN CASE OF FIRE EXPOS.
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & WILL ACCUMULATE. VAPS
WILL FORM EXPLO CONCS W/AIR. VAPS TRAVEL LONG DISTS & WILL
FLASHBACK. USE MECH VENT WHEN NEC TO KEEP PERCENT (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:ELIM ALL IGNIT SOURCES. HNDLG EQUIP MUST BE
GROUNDED TO PVNT SPKG. EVACUATE AREA OF UNPROT PERS. WEAR APPROP
PERSONAL PROT CLTHG & EQUIP. FOLLOW SAFE HNDLG & USE GUIDELINES.
CNTN & SOAK UP RESIDUAL W/ ABSORB (CLAY/SAND). TAKE UP ABSORB
MATL(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN
FLAMES & STRONG BASES. KEEP CNTNRS CLOSED. STORE IN COOL, DRY PLACE
W/ADEQ VENT. IF POURING OR TRANSFERRING (SUPDAT)
Other Precautions:DO NOT WELD, HEAT OR DRILL ON FULL OR EMPTY
CONTAINERS. FOR INDUSTRIAL USE ONLY.
* Physical/Chemical Properties *
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID STRONG BASES. THIS PRODUCT CONTAINS A STRONG ACID AND WILL REACT
WITH STRONG BASES.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES AND STRONG
BASES.
Hazardous Decomposition Products:CARBON MONOXIDE, STRONG ACIDS AND
UNIDENTIFIED ORGANIC COMPOUNDS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:RESTRICTED AREA: NIOSH APPR'D CHEMICAL CARTRIDGE
RESPIRATOR. SPRAYING: MECHANICAL PREFILTER MAY BE REQUIRED.
CONFINED AREAS: NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR.
EXCEEDED TLV AREA:NIOSH/MSHA A PPR'D RESPIRATOR W/RIGHT PROTECT
FACTOR.
Ventilation:GENERAL DILUTION/LOCAL EXHAUST VENTILATION IN SUFFICIENT
VOLUME & PATTERN TO KEEP CONCENTRATIONS BELOW EXPOSURE LIMITS.
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER.
Supplemental Safety and Health
FLAMMABLE. THIS PRODUCT, IF DISCARDED DIRECTLY, WOULD BE CLASSIFIED A
HAZARDOUS WASTE BASED ON ITS IGNITABILITY CHARACTERISTIC.
* Product Identification *
Preparer's Name:W. A. ELLISON
* Composition/Information on Ingredients *
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Other REC Limits:NONE SPECIFIED
Ingred Name:SOLVENT NAPTHA, LIGHT AROMATIC (SOLVENT)
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:N-BUTYL ACETATE (SARA III)
Other REC Limits:NONE SPECIFIED
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
Fraction by Wt: <1%
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE TABLE Z3
UFL 7.0) (SOLVENT)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:ETHYL BENZENE (SARA III)
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:METHYL ISOAMYL KETONE
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
CALCULATED *(NEGLIGIBLY PHOTOCHEMICALLY REACTIVE MATERIALS)
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SWALLOWING: GASTROINTESTINAL
IRRITATION. ASPIRATION OF MATERIAL INTO LUNG MAY CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL. INHALATION: NOSE OR THROAT
IRRITATION. ACUTE CENTRAL NERVOUS SYSTEM DEPRESS ION. EYE/SKIN:
SEVERE IRRITATION. CORNEAL DAMAGE. PNEUMOCONIOSIS. LIVER, KIDNEY,
BLOOD INJURY. PERIPHERAL NEUROPATHY.
Explanation of Carcinogenicity:IARC CONSIDERS CRYSTALLINE SILICA TO
HAVE LIMITED EVIDENCE OF CARCINOGENICITY IN HUMANS. (IARC GROUP
2A).
Effects of Overexposure:SWALLOW: NAUSEA, VOMITING. INHALE: HEADACHES,
DIZZINESS, NAUSEA & CONFUSION. SKIN: LIQUID MATERIAL MAY BE
ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. REPORTS ASSOCIATE
PROLONGED/ REPEATED OVEREXPOSURE T O SOLVENTS W/PERMANENT BRAIN &
NERVOUS SYSTEM DAMAGE. DELIBERATELY CONCENTRATING & INHALING COULD
BE HARMFUL OR FATAL.
Medical Cond Aggravated by Exposure:PREXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA. LAB STUDIES
W/RATS INDICATE SOME EVIDENCE THAT METHYL ETHYL KETONE MAY BE
EMBRYOTOXIC, FETOTOXIC AND TERATOGENIC.
* First Aid Measures *
First Aid:SWALLOWING: DO NOT INDUCE VOMITING. CALL POISON CONTROL,
EMERGENCY ROOM OR PHYSICIAN IMMED. INHALE: REMOVE TO FRESH AIR
IMMED. IF BREATHING HAS STOPPED, GIVE CPR. KEEP WARM & QUIET. GET
UPPER & LOWER LIDS OCCASIONALLY. GET MEDICAL ATTN. SKIN: REMOVE
CONTAM CLOTHING. WASH AFFECTED AREA W/SOAP & WATER. PERSISTANT
IRRIT/MEDICAL AID.
* Fire Fighting Measures *
Lower Limits:1.0
Extinguishing Media:NFPA CLASS B EXT-(CARBON DIOXIDE, ALL PURPOSE DRY
CHEMICAL OR ALCOHOL FOAM.) POLYMER FOAM IS PREFERRED FOR LARGE
FIRES.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, USE TO COOL
CONTAINERS (FOG NOZZLES PREFERABLE) TO PREVENT PRESSURE BUILD-UP &
AUTO- IGNITE OR EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE
TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY
NOT BE IMMEDIATELY APPARENT. GET MEDICAL ATTENTION.
* Accidental Release Measures *
Spill Release Procedures:WEAR APPROPRIATE PROTECTION. KEEP SPECTATORS
AWAY. REMOVE IGNITE SOURCES. DIKE, CONTAIN & REMOVE SPILL W/INERT
MATERIAL. USE COVERED METAL CONTAINERS FOR RECOVERY/DISPOSAL. USE
NON-SPARKING TOOLS. PRE VENT CONTAM OF SEWERS, STREAMS, AND
GROUNDWATER.
*Handling and Storage *
INTERNALLY. CLOSE CONTAINER AFTER EACH USE.
Other Precautions:DO NOT BREATHE SANDING DUST. DO NOT WASH OR RE-USE
EMPTY CONTAINERS FOR ANY PURPOSE. GROUND & BOND CONTAINERS TO THE
RECEIVING CONTAINER. DO NOT WELD, BRAZE OR CUT ON EMPTY CONTAINER.
NEVER EMPTY W/ P RESSURE. DRUM IS NOT A PRESSURE VESSEL.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:> AIR
Spec Gravity:1.0
pH:4-7
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT IN WATER
Appearance and Odor:LIQUID, SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
SOURCES OF IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL LAWS & REGULATIONS. INCINERATE ONLY IN EPA FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS.USE PRECAUTIONS FOR DISPOSAL OF
ABSORBENTS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOSURE CAN'T BE CONTROLLED <
APPLICABLE LIMITS, WEAR A PROPERLY FITTED ORGANIC VAPOR/PARTICULATE
RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING/ABRADING DRIED
FILM, WEAR A DUST/MIST RES PIRATOR APPROVED BY NIOSH/MSHA FOR DUST.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
MAINTAINED < APPLICABLE EXPOSURE LIMITS.
Other Protective Equipment:TO MINIMIZE EXPOSURE, USE VENTILATION &
PERSONAL PROTECTIVE EQUIPMENT.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE EXPLOSION CONT'D: APPLICATION TO HOT SURFACES REQUIRES SPECIAL
PRECAUTIONS. PRECAUTIONS CONT'D: AVOID CONTACT W/SKIN & EYES.
* Product Identification *
* Composition/Information on Ingredients *
MINERAL SPIRITS
Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH
Fraction by Wt: 1%
Ingred Name:1,3,5,-TRIMETHYLBENZENE
Fraction by Wt: 1%
Fraction by Wt: 2%
Ingred Name:TITANIUM DIOXIDE, TIO2 (SUSPECTED ANIMAL CARCINOGEN, IARC
Ingred Name:ETHYLENE GLYCOL, GLYCOL
Fraction by Wt: <5%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & RESPIRATORY
SYSTEM, CNS DEPRESSION & POSSIBLY DEATH. CRYSTALLINE SILICA-MAY
CAUSE LUNG DAMAGE (SILICOSIS) & POSSIBLY CANCER. PROLONGED
OVEREXPOSURE TO SOLVENTS MAY CAUSE ADV ERSE EFFECTS TO THE LIVER &
URINARY SYSTEMS. OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN
& NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE,
DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING
SENSATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. KEEP WARM
& QUIET. SKIN: WASH AREA THOROUGHLY W/SOAP & WATER. EYES: FLUSH
ALL CASE S.
* Fire Fighting Measures *
Lower Limits:1
Upper Limits:7
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT & SCBA. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. USE WATER TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM ANY IGNITION SOURCE. CLOSED CONTAINERS EXPOSED TO EXTREME HEAT
MAY EXPLODE. (SEE SUPP)
* Accidental Release Measures *
Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE & REMOVE
W/INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT & OPEN FLAME. USE
APPROVED BONDING & GROUNDING PROCEDURES. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE. DON'T TAKE INTERNALLY.
Other Precautions:TRANSFER ONLY TO APPROVED CONTAINERS W/COMPLETE &
APPROPRIATE LABELING. KEEP OUT OF REACH OF CHILDREN. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS CAN BE
HARMFUL/FATAL. AV OID BREATHING VAPOR & SPRAY MIST. (SUPP)
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:CAPE COD RED SOLID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, ELECTRICAL EQUIPMENT, SPARKS, OPEN
FLAME & OTHER SOURCES OF IGNITION, HOT SURFACES.
Hazardous Decomposition Products:BY FIRE: CO2, CO
* Disposal Considerations *
Waste Disposal Methods:WASTE MAY BE HAZARDOUS UNDER THE RCRA & MUST BE
TESTED FOR IGNITABILITY TO DETERMINE THE APPLICABLE EPA HAZARDOUS
WASTE NUMBERS. INCINERATE IN APPROVED FACILITY. DON'T INCINERATE
CLOSED CONTAINERS. DI SPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK.
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS
CLOTHING.
Supplemental Safety and Health
BY DGSC-STF.
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION.
LATENT EFFECTS:SOMATIC/GENETIC DAMAGE.
* First Aid Measures *
First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE
COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN
PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT
VICTIM(S) MAY BE CON TAMINATED.
* Fire Fighting Measures *
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD
BRTHG APP.
Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE
IN HEAT OF FIRE.
* Accidental Release Measures *
*Handling and Storage *
Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION.
PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN
AREA FOR RADIOACTIVE MATERIALS.
* Physical/Chemical Properties *
HCC:A2
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL
Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION;
FISSION PRODUCTS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH
DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURE MAY/DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS, USE NIOSH APPROVED RESPIRATOR TO PREVENT
RESPIRATOR/AIR PURIFYING RESPIRAT OR FOR ORGANIC VAPORS &
PARTICULATES.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMKNG, APPLYING COSMETICS/USING TOILET FACILITIES. LAUNDER CONTAM
Supplemental Safety and Health
HAZ DECOMP PROD: & GASES WILL EVOLVE WHEN THIS MATL UNDERGOES
PYROLYSIS/COMBUST. CARBON MONOXIDE & OTHER UNIDENTIFIED ORG CMPDS
MAY BE FORMED UPON COMBUST. FIRST AID PROC: TREATMENT IS NEC UNLESS
LGE QTYS INGESTED. HOWEVER, GET MED ADVICE.NOTE TO MD: IN GEN,
EMESIS INDUCTION IS UNNEC IN HIGH VISCOSITY, LOW (ING 8)
* Product Identification *
CAGE:SHELO
CAGE:SHELO
* Composition/Information on Ingredients *
7
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MINERAL OIL (SEV), PETRO DISTIL, HYDROTREATED HEAVY
PARAFFINIC; (SOL. REF., HYDROTREATED HEAVY PARAFFINIC DISTILLATE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, CATALYTIC DEWAXED
(SEVERE), HEAVY PARAFFINIC
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SOLVENT REFINED HYDROTREATED RESIDUAL OIL; (SOL. REF.,
HYDROTREATED RESIDUAL OIL)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POLYMERIC ADDITIVE IN OIL (MIXTURE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ADDITIVE PACKAGE, CONTAINING INGREDIENT 7
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ZINC DIALKYLDITHIOPHOSPHATE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUP DAT: VOLATILITY PRODUCTS, I.E. MOST OILS AND GREASES.
Ingred Name:SPILL PROC: STOR/SALVAGE VESSELS. SOAK UP RESIDUE W/ABSORB
Ingred Name:ING 9: PROPERLY. FLUSH AREA W/WATER TO REMOVE TRACE
RESIDUE. SML SPILLS: TAKE UP W/ABSORB MATL & DISP OF PROPERLY.
Ingred Name:WASTE DISP METH: DISPOSE OF IN ACCORDANCE WITH LOCAL,
STATE, AND FEDERAL REGULATIONS .
Ingred Name:HYGIENE PRACT: CLOTHING BEFORE REUSE. CONTAMINATED LEATHER
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN: LUBRICATING OILS ARE GEN
CONSIDERED NO MORE THAN MILDLY IRRIT. PRLNG & RPTD CONT MAY RSLT IN
VARIOUS SKIN DISORDERS SUCH AS DERM, FOLLICULITIS/OIL ACNE. INHAL:
VAP (GENERATED AT HIGH TEMP S ONLY)/OIL MIST MAY RSLT IN MILD
IRRITTO NOSE, THROAT & RESP TRACT. INGEST: LUBRICATING OILS ARE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: GEN CONSIDERED NO MORE THAN SLIGHTLY
TOX IF SWALLOWED. EYES: LUBRICATING BASE OILS ARE GEN CONSIDERED NO
MORE THAN SLIGHTLY TOX. SIGNS & SYMPS: IRRIT AS NOTED ABOVE.
CHRONIC: NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:PREEXISTING SKIN AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE TO THIS PRODUCT.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR & PROVIDE OXYGEN IF BRTHG IS
MIN WHILE HOLDING EYELIDS OPEN. GET MED ATTN. SKIN: REMOVE CONTAM
CLTHG/SHOES & WIPE EXCESS FROM SKIN. FLUSH SKIN W/WATER. FOLLOW BY
WASHING W/SOAP & WATER. IF IRRIT OCCURS, GET MED ATTN. DO NOT REUSE
CLTHG UNTIL CLEANED. INGEST: DO NOT INDUCE VOMIT. IN GEN, NO (SUP
DAT)
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:WATER FOG, FOAM, DRY CHEMICAL OR CARBON DIOXIDE. DO
NOT USE DIRECT STREAM OF WATER.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . MATERIAL WILL NOT BURN UNLESS PREHEATED. COOL
FIRE-EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:PRODUCT WILL FLOAT AND CAN BE REIGNITED
ON SURFACE OF WATER.
* Accidental Release Measures *
Spill Release Procedures:MAY BURN ALTHOUGH NOT READILY IGNITABLE. USE
CAUTIOUS JUDGEMENT WHEN CLEANING UP LGE SPILLS. LGE SPILLS: WEAR
NIOSH APPRVD RESP & PROT CLTHG AS APPROP. SHUT OFF SOURCE OF LEAK
IF SAFE TO DO SO. DIKE & CONTAIN. REMOVE W/VACUUM TRUCKS/PUMP TO
(ING 9)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE WITH ADEQUATE
VENTILATION. KEEP AWAY FROM OPEN FLAMES AND HIGH TEMPERATURES.
Other Precautions:AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. AVOID
CONTACT WITH EYES.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN BUTYL ACETATE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK RED LIQUID, STRONG HYDROCARBON ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HEAT, FLAME.
Hazardous Decomposition Products:THERMAL DECOMP PRODS ARE HIGHLY
DEPENDENT ON COMBUST CNDTNS. COMPLEX MIX OF AIRBORNE SOLID, LIQ,
PARTICULATES (SUP DAT)
* Disposal Considerations *
Waste Disposal Methods:PLACE IN APPROP DISP FACILITY IN COMPLIANCE
W/LOC REGS. ENVIRON HAZS: UNDER ERA-CWA, THIS PROD IS CONSIDERED AN
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR DUST MASK.
Ventilation:LOCAL EXHAUST: AS REQUIRED. MECHANICAL (GENERAL): VENT FAN.
Supplemental Safety and Health
SOLUBILITY IN WATER: POWDERS-APPRECIABLE. LIQUIDS-MISCIBLE.
* Product Identification *
Product ID:HYALURONIC ACID
* Composition/Information on Ingredients *
Ingred Name:HYALURONIC ACID
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE SKIN, EYE/RESPIRATORY TRACT
IRRITATION UPON CONTACT. ALLERGIC REACTIONS IN CERTAIN SENSITIVE
INDIVIDUALS MAY DEVELOP.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, ALLERGIC REACTIONS.
Medical Cond Aggravated by Exposure:ALLERGIES, ASTHMA.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES/SKIN: WASH THOROUGHLY
W/WATER. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:AVOID PHYSICAL CONTACT & DUST DURING REMOVAL.
USE NORMAL CLEAN-UP PROCEDURES & WASH THOROUGHLY W/WATER.
*Handling and Storage *
Handling and Storage Precautions:NONE
Other Precautions:NONE
* Physical/Chemical Properties *
Solubility in Water:(SEE SUPP)
Appearance and Odor:POWDERS- WHITE TO TAN. LIQUIDS-WHITE TO BROWN. BOTH
HAVE TYPICAL ENZYME ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:FLUSH IN SEWERAGE SYSTEM W/WATER IAW/FEDERAL,
STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Item Description Information
*
Item Manager: S9G
Item Name: HYDRAULIC FLUID,PETROLEUM BASE
Unit of Issue: QT
UI Container Qty: G
*
Ingredients
*
Other REC Limits: NONE RECOMMENDED
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INGESTION-NOT NORMALLY EXPECTED TO CAUSE ANY ILL EFFECTS.
INHALATION-NO SIGNIFICANT ADVERSE HEALTH EFFECTS ARE EXPECTED TO OCCUR.
EYE-NOT NORMALLY EXPECTED TO CAUSE ANY ILL EFFECTS. SKIN-NOT NORMALLY
EXPECTED TO CAUSE ANY ILL EFFECTS.
Explanation Of Carcinogenicity: NOT CARCINOGENIC.
Signs And Symptions Of Overexposure: SKIN-PROLONGED AND/OR REPEATED CONTACT MAY
PRODUCE MILD SKIN IRRITATION AND INFLAMMATION.
Medical Cond Aggravated By Exposure: PERSONNEL WITH PRE-EXISTING SKIN DISORDER
SHOULD AVOID CONTACT.
First Aid: INGESTION-DO NOT INDUCE VOMITING. CONSULT PHYSICIAN.
INHALATION-REMOVE FROM CONTAMINATED AREA. APPLY ARTIFICIAL RESPIRATION. IF
UNCONSCIOUS CONSULT PHYSICIAN. EYE-FLUSH WITH COPIOUS AMOUNTS OF WATER. IF
IRRITATION DEVELOPS CONSULT PHYSICIAN. SKIN-WASH WITH SOAP AND WATER. CONSULT
PHYSICIAN IF IRRITATION DEVELOPS.
*
Handling and Disposal
*
Spill Release Procedures: STOP FLOW. WIPE OR MOP UP OR ABSORB WITH DIATOMACEOUS
EARTH OR OTHER INERT MATERIAL. STORE IN APPROPIATE CONTAINER FOR DISPOSAL.
Waste Disposal Methods: IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Handling And Storage Precautions: AVOID STORAGE NEAR OPEN FLAME OR OTHER
SOURCES OF IGNITION. EXCESSIVE MISTING MAY CAUSE SLIPPERY FLOORS. PROPER
FOOTWARE REQUIRED.
Other Precautions: WASH OR TAKE SHOWER IF GENERAL CONTACT OCCURS. REMOVE
OIL-SOAKED CLOTHING AND LAUNDER BEFORE REUSE. DISCARD CONTAMINATED LEATHER
*
Fire and Explosion Hazard Information
*
Flash Point Method: COC
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures: DO NOT ENETR ANY ENCLOSED OR CONFINED AREA WITHOUT
PROPER PROTECTIVE EQUIPMENT & SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard: SLIGHTLY COMBUSTIBLE, WHEN HEATED ABOVE FLASH
POINT. WILL RELEASE FLAMMABLE VAPORS WHICH CAN BURN IN OPEN OR BE EXPLOSIVE
IN CONFINED SPACES IF EXPOSED TO HEAT.
*
*
Respiratory Protection: NONE NORMALLY REQUIRED.
Ventilation: SUFFICIENT TO MAINTAIN ATMOSPHERE BELOW TLV LIMIT.
Other Protective Equipment: CHEMICALLY RESISTANT BOOTS AND APRONS RECOMMENDED.
Work Hygienic Practices: WASH HANDS WITH SOAP AND WATER BEFORE EATING, DRINKING
OR SMOKING.
Supplemental Safety and Health: NONE.
*
Physical/Chemical Properties
*
HCC: V6
Vapor Pres: <0.1 MMHG
Vapor Density: >AIR
Evaporation Rate & Reference: LESS THAN ETHER
Solubility in Water: INSOLUBLE
Appearance and Odor: YELLOW, OILY LIQUID. PETROLEM ODOR.
Percent Volatiles by Volume: NIL
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: DO NOT HEAT ABOVE FLASH POINT.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: CARBON MONOXIDE AND ASPHYXIANTS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NONE.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Net Unit Weight: 1.8 LBS
AF MMAC Code: NR
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: QT
Container QTY: G
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Company Name: TECHNOLUBE PRODUCT COMPANY
Status Code: C
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: None
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: AVOID STORAGE NEAR OPEN FLAME OR OTHER SOURCES OF
IGNITION. EXCESSIVE MISTING MAY CAUSE SLIPPERY FLOORS. PROPER FOOTWARE
REQUIRED. IN CASE OF SPILL: STOP FLOW. WIPE OR MOP UP OR ABSORB WITH
DIATOMACEO US EARTH OR OTHER INERT MATERIAL. STOREIN APPROPIATE CONTAINER FOR
DISPOSAL. FIRST AID: INGESTION-DO NOT INDUCE VOMITING. CONSULT PHYSICIAN.
INHALATION-REMOVE FROM CONTAMINATED AREA. APPLY ARTIFICIAL RESPIRATION. IF
UNCONSCIOUS CONSULT PHYSICIAN. EYE-FLUSH WITH COPIOUS AMOUNTS OF WATER. IF
IRRITATION DEVELOPS CONSULT PHYSICIAN. SKIN-WASH WITH SOAP AND WATER. CONSULT
PHYSICIAN IF IRRITATION DEVELOP S.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR A PROPERLY FITTED NIOSH/MSHA APPROVED
VAPOR/PARTICAULATE RESPIRATOR OR AN AIR-SUPPLYING RESPIRATOR UNLESS
VENTILATION IS ADEQUATE TO KEEP AIRBORNE CONTAMINATION BELOW
APPLICABLE OSHA, PEL OR ACGI H TLV OCCUPATIONAL EXPOSURE LIMITS.
Ventilation:PROVIDE SUFFICIENT VENTILATION IN VOLUME AND PATTERN,W/
EXPLOSION PROOF EQUIPMENT TO KEEP AIR CONTAMINANT CONCENTRATION
* Product Identification *
Preparer's Name:J. BURNWORTH
* Composition/Information on Ingredients *
INDICATES CHEMICAL (S) SUBJECT TO THE REPORTING REQUIRMENTS OF
OSHA STEL:KN
ACGIH TLV:KN
OSHA STEL:KN
Ingred Name:*NAPHTHA, HEAVY ALKYLATE (ODORLESS) * INDICATES CHEMICAL
OSHA STEL:KN
ACGIH STEL:KN
Ingred Name:*CARBON BLACK * INDICATES CHEMICAL (S) SUBJECT TO THE
OSHA PEL:KN
OSHA STEL:KN
ACGIH TLV:KN
OSHA PEL:KN
OSHA STEL:KN
ACGIH STEL:KN
Ingred Name:XYLENE
= Wt:1.
* Hazards Identification *
Health Hazards Acute and Chronic:ACUTE: (SHORT TERM) OVER EXPOSURE CAN
CAUSE SKIN AND EYE IRRITATION. INHALATION CAN CAUSE ACUTE NERVOUS
SYSTEM DEPRESSION CHARACTERIZED BY NASAL IRRITATION, HEADACHE,
DIZZINESS, CONFUSION OR UNCONSCI OUSNESS. CHRONIC: (LONG TERM)
OVEREXPOSURE TO VAPORS MAY CAUSE KIDNEY OR LIVER DAMAGE.
Explanation of Carcinogenicity:KN
Effects of Overexposure:EYE CONTACT: SEVERE IRRITATION, REDNESS,
TEARING, AND BLURRED VISION. SKIN CONTACT: FREQUENT OR PROLONGED
EXPOSURE CAN CAUSE MODERATE IRRITATION, DEFATTING AND DERMATITUS.
INHALATION: EXCESSIVE IN HALATION OF VAPORS CAN CAUSE NASAL AND
RESPIRATORY IRRITATION, DIZZINESS, WEAKNESS, FATIGUE, NAUSEA, AND
HEADACHE. HIGH CONCENTRATIONS MAY RESULT IN NARCOSIS. (CENTRAL
NERVOUS SYSTEM DEPRESSION).
Medical Cond Aggravated by Exposure:KN
* First Aid Measures *
MINUTES, OCCASIONALLY LIFT-ING THE EYELIDS. OBTAIN MEDICAL
ATTENTION.SKIN CONTACT: REMOVE CONTAMINATED CLOTHING. WASH
AFFECTED SKIN AR EAS THOROUGHLY WITH SOAP AND WATER. WASH
CONTAMINATED CLOTHING THOROUGHLY BEFORE RE-USE.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1
Upper Limits:7
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT, INLUDING A
SELF-CONTAINED BREATHING APPARATUS, SHOULD BE USED. WATER MAY BE
USED TO COOL CLOSED CONTAINERS TO PREVENT PRESSURE BUILD UP AND
POSSIBLE AUTO-IGNITION OR EXPLOSI ON WHEN EXPOSED TO EXTREME HEAT.
AVOID SPREADING BURNING LIQUID WITH WATER USED FOR COOLING.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DURING
EMERGENCY CONDITIONS, OVER EXPOSUR E TO DECOMPOSITION PRODUCTS MAY
CAUSE A HEALTH HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE THE AREA. REMOVE ALL SOURCES OF
IGNITION (FLAME, HOT SURFACES, ELE-CTRICAL, STATIC OR FRICTIONAL
SPARKS). AVOID SKIN CONTACT AND BREATHING VAPORS.CONTAIN AND
REMOVE WITH INERT ABSORBENT AND NON-SPARKING TOOLS. REMOVE ALL
NON-ESSENTIAL PERSONNEL. DIKE AROUND THE SPILLED MATERIAL.
Neutralizing Agent:SAND , CLAY OR DIATOMACEOUS EARTH.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, WELL VENTILATED AREA
AWAY FROM SOURCES OF IGNITION. STORE LARGE QUANTITES ONLY IN
Other Precautions:DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF
CHILDREN.
BELOW APPLICABLE OSHA PEL OR ACGIH TLV*
SKIN CONTACT.
SKIN CONTACT.
DURING SPRAY APPLICATION. PROTECTIVE CREAMS MAY BE USED FOR EASE
OF CLEAN-UP, NOT FOR PROTECTION. EYE BATH AND SAFETY SHOWER MAY BE
NECESSARY.
Work Hygienic Practices:KN
Supplemental Safety and Health
KN
* Physical/Chemical Properties *
Vapor Density:>THAN AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:APPEARANCE: COLORED LIQUIDODOR: AN ALIPHATIC ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
EXTREME HEAT, SPARKS OR OPEN FLAME.
Stability Condition to Avoid:KN
Hazardous Decomposition Products:STRONG OXIDIZING MATERIALS.
Conditions to Avoid Polymerization:KN
* Toxicological Information*
* Ecological Information *
INFORMATION IS REQUIRED.
* Disposal Considerations *
Waste Disposal Methods:DO NOT ALLOW MATERIAL TO CONTAMINATE GROUND
WATER SYSTEMS. ABSORB LARGE SPILLS WITH SAND, CLAY OR DIATOMACEOUS
EARTH. DISPOSE IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
DISPOSAL REQUIREMENTS.
* MSDS Transport Information *
Transport Information:(DOT) DESCRIPTION FOR DOMESTIC TRANSPORTATION;
ORM-D ( CONSUMER COMODITY ) DESCRIPTION FOR INTERNATIONAL
ALL INCLUSIVE.
* Regulatory Information *
SARA Title III Information:\
Federal Regulatory Information:KN
State Regulatory Information:KN
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR OR
AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED. USE IN ACCORDANCE
BE USED. VENTILATION RATES WILL BE MATCHED TO CONDITIONS.
Other Protective Equipment:PROTECTIVE CLOTHING APPROPRIATE FOR THE RISK
OF EXPOSURE.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
HCC=N1. THIS ITEM IS PART OF A KIT; THIS MSDS REPRESENTS A FORMULA
CHANGE FOR PNI C (MFR PART A). THE ITEM HAS A COMPONENT WHICH
CONTAINS HAZARDOUS MATERIALS.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:SODIUM SULFITE
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM CARBONATE
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 8%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SODIUM HEXAMETAPHOPHATE (METAPHOSPHORIC ACID, HEXASODIUM
SALT) (CERCLA)
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM BICARBONATE
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:1-PHENYL-3-PYRAZOLIDONE
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-AIRBORNE DUST IRRITATING. MAY
CAUSE IRRITATION OF MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT.
CONTACT WITH SKIN & EYES MAY BE IRRITTAING. MAY CAUSE ALLERGIC SKIN
REACTION. HARMFUL IF SWALLOWED. MAY CAUSE G/I TRACT IRRITATION.
CHRONIC-PROLONGED EYE CONTACT MAY CAUSE EYE INJURY.
Explanation of Carcinogenicity:IN ADDITION TO THE ABOVE, PRODUCT IS
NEGATIVE W/REGARD TO:ACGIH CANCER, CALIFORNIA CANCER & REPRODUCTIVE
EFFECTS.
Effects of Overexposure:INHALATION:UPPER RESPIRATORY TRACT IRRITATION.
EYES:IRRITATION. SKIN:PROLONGED OR RAPEATED CONTACT; IRRITATION,
ALLERGIC REACTION. INGESTION:SULFITE ALLERGIC REACTION.
Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION OF MSDS.
* First Aid Measures *
First Aid:IF ANY SYMPTOMS OCCUR, GET IMMEDIATE MEDICAL ATTENTION.
INHALATION:IF SYMPTOMATIC,MOVE TO FRESH AIR. EYE:FLUSH W/PLENTY OF
CLOTHING & L AUNDER BEFORE REUSE. INGESTION:INDUCE VOMITING AS
DIRECTED BY MEDICAL PERSONNEL. NOTHING BY MOUTH IF UNCONSCIOUS.
CALL PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO SEWER W/LARGE AMOUNTS OF WATER.
OTHERWISE, ABSORB SPILL W/VE
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED. KEEP AWAY FROM
ACIDS. AVOID BREATHING DUST. AVOID CONTACT WITH EYES, SKIN AND
CLOTHES. USE WITH ADEQUATE VENTILATION.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. THE ROUTINE USE OF A
NON-ALKALINE (ACID) TYPE OF AHND CLEANER AND REGULAR CLEANING OF
WORKING SURFACES WILL HELP MINIMIZE THE POSSIBILITY OF SKIN
REACTION.
* Physical/Chemical Properties *
HCC:N1
NRC/State Lic Num:NONE
Vapor Pres:NEGLIGIBLE
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE SOLID; ODORLESS
Percent Volatiles by Volume:NIL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS.
Stability Condition to Avoid:MFR GAVE NO INFORMATION OF MSDS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
SULFUR DIOXIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT, OR DISPOSAL MAY BE SUBJECT
TO LOCAL, STATE AND FEDERAL REGULATIONS. FLUSH TO SEWER WITH LARGE
AMOUNTS OF WATER.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED SUPPLIED-AIR RESPIRATORY
PROTECTION IN CONFINED OR ENCLOSED SPACES IF NEEDED.
Ventilation:LOCAL EXHAUST &/OR MECHANICAL (GENERAL) VENTILATION
RECOMMENDED. USE EXPLOSION-PROOF EQUIPMENT.
Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE
SHOWER . USE CHEM-RESIST APRON/OTHER IMPERVIOUS CLTHG, IF NEEDED,
(SUPDAT)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC:WATER SPRAY TO DISPERSE VAPS & TO PROT PERS ATTEMPTING
TO STOP LEAK. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM
EXPOS. EYE PROT:& FULL LENGTH FACESHIELD . OTHER PROT EQUIP :TO
AVOID CONTAMINATING REGULAR CLOTHING WHICH COULD RESULT IN
PROLONGED OR REPEATED SKIN CONTACT.
* Product Identification *
Product ID:VISCOSITY STANDARD N2B
* Composition/Information on Ingredients *
Ingred Name:STODDARD SOLVENT; (NARROW-CUT STODDARD SOLVENT, CONTAINING
INGS 2 - 6)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:C8+ AROMATICS
OSHA PEL:N/K
ACGIH TLV:N/K
Fraction by Wt: 0.8%
Fraction by Wt: 0.4%
Ingred Name:BENZENE, ETHYL-; (ETHYLBENZENE)
Fraction by Wt: 0.2%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
PPM) ARE IRRITATING TO EYES AND RESIRATORY TRACT, MAY CAUSE
HEADACHES AND DIZZINESS, ARE ANESTHETIC. CHRONIC:PROLONGED
INHALATION MAY CAUSE CENTRAL NERVOUS SYSTE M DISORDERS. REPEATED
SKIN CONTACT TENDS TO REMOVE SKIN OILS, POSSIBLY LEADING TO
IRRITATION AND (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:DERMATITIS. NOTE:TOLUENE APPEARS ON
THE NAVY LIST OF OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM
APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE
HANDLING & EXPOS INFO (FP N ).
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
First Aid:INHAL:REMOVE FROM EXPOSURE & CALL MD IMMED. IF BREATHING IS
IRREGULAR/HAS STOPPED, START RESUSCITATION, ADMINISTER OXYGEN, IF
SUBSIDES. IF IRRIT PERSISTS, CALL MD. SKIN:REMOVE ANY CONTAM
CLOTHING & WASH SKIN THORO W/SOAP & WATER. INGEST:DO NOT INDUCE
VOMITING; CALL MD IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:0.9%
Upper Limits:7%
Extinguishing Media:FOAM, WATER SPRAY (FOG), DRY CHEMICAL, CO*2.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER MAY BE INEFT BUT SHOULD BE USED TO KEEP FIRE-EXPOS CNTNRS
COOL. IF LEAK/SPILL HAS IGNITED; USE (SUPP DATA)
Unusual Fire/Explosion Hazard:MINIMIZE BREATHING GASES, VAPOR, FUMES OR
DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:SHUT OFF IGNITION SOURCES. KEEP PEOPLE AWAY.
RECOVER FREE PRODUCT. ADD SAND OR EARTH OR OTHER SUITABLE ABSORBENT
TO SPILL AREA. MINIMIZE SKIN CONTACT. VENTILATE CONFINED SPACES.
OPEN ALL WINDOWS & DOO RS. KEEP PRODUCT OUT OF SEWERS &
WATERCOURSES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP PRODUCT AWAY FROM HEAT, SPARKS,
PILOT LIGHTS, STATIC ELECTRICITY & OPEN FLAME.
* Physical/Chemical Properties *
Vapor Density:4.8
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIGHT-COLORED LIQUID; SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG OXIDANTS SUCH AS LIQ CHLORINE, CONCENTRATED
OXYGEN, SODIUM HYPOCHLORITE OR CALCIUM HYPOCHLORITE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FUMES, SMOKE, CARBON MONOXIDE,
ALDEHYDES & OTHER DECOMPOSITION PRODUCTS IN CASE OF INCOMPLETE
COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . ASSUME CONFORMITY W/APPLICABLE GOVERNMENT
REGULATIONS. CONTINUE TO OBSERVE PRECAUTIONS FOR VOLATILE,
COMBUSTIBLE VAPORS FROM ABSORBED MATERIAL.
| 1 | eyes_protection_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Item Description Information
*
Unit of Issue: EA
UI Container Qty: Z
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: NITROGLYCERIN CAN CAUSE ALLERGIC CONTACT
DERMATITIS.HYPERTENSION,BLINDNESS,LIVER AND KIDNEY INJURY CAN RESULT AFTER
EXTREME NITROGLYCERIN EXPOSURE.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: HAZARDS ARE FOR NITROGLYCERIN. SKIN
IRRITATION, HEADACHE, DECREASED BLOOD PRESSURE & AT HIGH EXPOSURE
EUPHORIA, HEADACHE, L IGHT-HEADEDNESS, ATAXIA, WEAKNESS, RAPID HEARTBEAT,
LABORED BREATHING, NAUSEA, VOMITING, MENTAL CONFUSION.
Medical Cond Aggravated By Exposure: ANEMIA AND GLAUCOMA MAY BE AGGRAVATED BY
EXTREME OVEREXPOSURE TO NITROGLYCERIN.
First Aid: EYES:IMMED FLUSH W/ H*2O.REMOVE CONT LENSES,CONTINUE FLUSHING FOR AT
SOAP & H*2O.REMOVE CONTAM CLTHG/SHOES.GET MED ATTN. IN GEST:DRINK 1-2
GLASSES H*2O.GET MED ATTN.GIVE NOTHING BY MOUTH IF UNCON. INHAL:MOVE TO FRESH
AIR.SYMP DEVELOP:GET MED ATTN.MD NOTE:USE SUPPORTIVE MEASURES-BED REST &
OXYGEN INHALATION.(SEE SUPP DATA)
*
Handling and Disposal
*
Spill Release Procedures: IF BAG OPEN:ELIM ALL IGNIT SOURCES.VENTILATE
AREA.WEAR SKIN PROT DURING CLEANUP.CLEAN UP IMMED USING SOFT BRISTLED BRUSH
& CONDUCTIVE RUBBER OR PLASTIC SHOVEL.USE EXTREME CAUTION-MATERIAL IS
SENSITIVE TO FRICTION,IMPACT & ELECTROSTATIC DISCHARGE.
Neutralizing Agent: NOT KNOWN
Waste Disposal Methods: DISP IAW FED,STATE,& LOCAL REG.COORDINATE W/
SUPPORTING INSTALLATION/MACOM ENVIRON OFFICE BEFORE DISP (FP A).EMPTY CONTR
MAY RETAIN RESIDUE.OBSERVE ALL PRECAUTIONS.USE EMPTY CONTR ONLY FOR ORIGINAL
PR ODUCT.DISP EMPTY CLOTH BAGS/CONTRS IAW ARMY REGS.
Handling And Storage Precautions: EXPLOSIVE,UNSTABLE,FLAMMABLE SOLID.FOLLOW
ARMY REGS FOR HANDLING & STORAGE.OPEN CONTRS IN WELL-VENT AREA,ALLOW
ACCUM VAPORS TO ESCAPE PRIOR TO HNDLG.
Other Precautions: PREVENT SKIN CONTACT WITH BAG CONTENTS.AVOID BREATHING
DUSTS.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: DELUGE WITH WATER.ALL MATERIAL MAY BE CONSUMED BEFORE FIRE
EXTINGUISHED UNLESS LARGE QTIES OF WATER USED VERY QUICKLY.
Fire Fighting Procedures: WEAR SELF-CONTAINED BREATHING APPARATUS (SCBA) AND
FULL TURNOUT GEAR (FP A).EVACUATE THE AREA.
SECONDS).EASILY IGNITED,HIGHLY COMBUSTIBLE EXPLOSIVE.
*
*
Respiratory Protection: MSHA-NIOSH APPROVED POSITIVE PRESSURE AIR-SUPPLIED
RESPIRATOR PROVIDES THE BEST PROTECTION.
Ventilation: USE LOCAL EXHAUST IF NEEDED TO KEEP EXPOSURES TO A MINIMUM.
Other Protective Equipment: IMPERVIOUS COVERALLS & APRON.EYEWASH FACILITIES AS
NEEDED.
Work Hygienic Practices: WASH CONTAM CLTHG & DECONTAMINATE SHOES BEFORE
REUSE.SHOWER THOROUGHLY AT END OF WORK SHIFT.WASH WORK CLOTHES DAILY.
FORM.IF CYANOSIS IS SEVERE,MAY BE HELPFUL TO ADMINISTER 1% METHYLENE BLUE,1-2
M G/KG BODY WT OVER 5-MIN INTERVALS.REPEAT AFTER 1 HOUR IF NEC,DO NOT EXCEED
7 MG/KG TOTAL DOSE.
*
Physical/Chemical Properties
*
M.P/F.P Text: NOT KNOWN
Decomp Text: NOT KNOWN
Vapor Pres: SEE ING 1
Vapor Density: SEE ING 1
Spec Gravity: SEE SUPP
Evaporation Rate & Reference: NOT KNOWN
Solubility in Water: NEGLIGIBLE
Appearance and Odor: SEWN CLOTH BAGS CONTAINING PROPELLENT.
Percent Volatiles by Volume: NEGLIG
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: STABLE UNDER NORMAL CONDITIONS.
Materials To Avoid: ACIDS AND BASES.
Hazardous Decomposition Products: COMBUSTION PRODUCTS:CARBON DIOXIDE,CARBON
MONOXIDE,NITROGEN OXIDES.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: ICI AMERICAS INC FILMS DIV
Street: NEW MURPHY RD AND CONCORD PIKE
Label Required IND: Y
Status Code: C
Origination Code: G
Hazard And Precautions: NITROGLYCERIN CAN CAUSE ALLERGIC CONTACT
DERMATITIS.HYPERTENSION,BLINDNESS,LIVER AND KIDNEY INJURY CAN RESULT AFTER
EXTREME NITROGLYCERIN EXPOSURE.
HAZARDS ARE FOR NITROGLYCERIN. SKIN
IRRITATION, HEADACHE, DECREASED BLOOD PRESSURE & AT HIGH EXPOSURE
EUPHORIA, HEADACHE, LIGHT-HEADEDNESS, ATAXIA, WEAKNESS, RAPID HEARTBEAT,
LABORED BREATHING, NAUSEA, VOMITING, MENTAL CONFUSION.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:GEN EXP MAY NOT REQ THE USE OF RESP PROT. RESTR
VENT AREAS A NIOSH APPVD CHEM CARTRIDGE RESP MAYBE REQD FOR SPEC
MECHANICAL PREFILTER MA YBE REQUIRED.
Ventilation:GENERAL DILUTION AND LOCAL EXHAUST VENTILATION TO MAINTAIN
HAZ SUBSTANCES BELOW LOWEST EXPOSURE LIMITS.
Other Protective Equipment:AS REQUIRED TO PREVENT SKIN CONTACT. SEE
OSHA STD FOR LEAD. EYEWASH FACILITY AND SAFETY SHOWER.
Supplemental Safety and Health
RESPIRATION PROTECTION CONTINUED: CONFINED AREAS USE A NIOSH/MSHA
APPROVED AIR SUPPLIED RESPIRATOR.
* Product Identification *
Preparer's Name:W.A. ELLISON
* Composition/Information on Ingredients *
Ingred Name:VM&P NAPHTHA
Ingred Name:ISOBUTYL ALCOHOL (SARA III)
Ingred Name:TOLUENE (SARA III)
Fraction by Wt: < 5%
Ingred Name:N-HEPTANE
Ingred Name:TALC (CONTAINING NO ASBESTOS)
OSHA PEL:2 MG/M3 RDUST
Ingred Name:TITANIUM DIOXIDE
Ingred Name:LEAD (SARA III)
Fraction by Wt: < 1%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:SWALLOWING:GASTROINTESTINAL
IRRITATION,NAUSEA,VOMITING.ASPIRATION OF MATERIAL INTO LUNG MAY
CAUSE CHEMICAL PNEUMONITIS. INHALATION: NOSE/THROAT IRRITATION. MAY
CAUSE ACUTE CENTRAL NERVOUS SYSTEM DEPRE SSION. EYE: MAY CAUSE EYE
IRRITATION SKIN: PRIMARY SKIN IRRITANT. MAY CAUSE DEFATTING AND
ITRITATION OF THE SKIN.
Explanation of Carcinogenicity:CHROMIUM/CHROMIUM COMPOUNDS AND LEAD
CHROMATE HAS BEEN LISTED AS POTENTIAL CARCINOGENS.
Effects of Overexposure:REPEATED/PROLONGED OVEREXPOSURE TO RELATIVELY
ISOLUBLE CHROMATES MAY CAUSE LUNG CANCER. OVEREXPOSURE TO TOLUENE
MAY CAUSE LIVER DAMAGE. CHRONIC O/EXPOSURE TO LEAD MAY RESULT IN
SEVERE DAMAGE TO BLOOD FORMING, NERVOUS, URINARY, REPRO SYS.LOSS
OF APPETITE,METALLIC TASTE IN MOUTH,INSOMNIA,HEADACHE,MUSCLE &
POINT PAIN.
Medical Cond Aggravated by Exposure:PREXISTING KIDNEY CONDITIONS MAY BE
AGGRAVATED BY EXPOSURES TO LEAD.
* First Aid Measures *
First Aid:SWALLOWING;DO NOT INDUCE VOMITING.SEEK MEDICAL ATTENTION
IMMEDIATELY. INHAL:REMOVE TO FRESH AIR. IF BREATHING STOPPED GIVE
CPR. KEEP WARM & QUIET. SEEK MED ATTN. EYE: FLUSH W/LG AMTS WTR
IMMEDIATELY FLUSH CONTAMINATED AREA WITH LARGE AMOUNTS OF WATER.
REMOVECONTAMINATED CLOTHING AS WATER IS APPLIED. CONSULT A
PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:NFPA CL B FIRE EXT. POLYMER FOAM FOR LARGE FIRES
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. USE
WATER TO COOL EXPOSED CONTAINERS TOPREVENT PRESSURE BUILD-UP AND
POSSIBLE EXPLOSION. FOG NOZZLE PREFERRED W/WATER.
Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMPOSITION PRODUCTS
MAY CAUSE HEALTH HAZARD. OBTAIN MEDICAL ATTN. WARNING FLAMMABLE.
DANGER EXTREMELY FLAMMABLE. VAPORS MAY CAUSE FLASH FIRE.
* Accidental Release Measures *
Spill Release Procedures:WEAR RESPIRATORS,EYE,HAND,BODY PROTECTION
APPROPRIATE FOR SIZE OF SPILL. KEEP SPECTATOR AWAY. ELIMINATE
IGNITION SOURCES. DIKE AND CONTAIN SPILL W/INERT MATERIAL.TRANSFER
LIQ TO COOVERED METAL CONTAIN ERS FOR RECOVERY/DISPOSAL.PREVENT
CONTAMINATION.
*Handling and Storage *
Other Precautions:CLOSE CONTR AFTER EACH USE. DO NOT BREATH SANDING
DUST. EMPTY CONTR NOT TO BE REUSED ANY PURPOSE. CONTRS SHOULD BE
GROUNDED & BONDED TO THE REC CONTR. DO NOT WELD/BRAZE/CUT ON CONTR.
NEVER USE PRESSUR E TO EMPTY. DRUM NOT A PRESSURE VESSEL.
* Physical/Chemical Properties *
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF
IGNITION.
Hazardous Decomposition Products:WILL NOT OCCUR
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT SPARKS AND
FLAME.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE ONLY IN EPA PERMITTED FACILITY. RCRA
C LASSIFICATION DOO1. CONTAMINATED ABSORBANT DISPOSED IN A
HAZARDOUS WASTE LANDFILL. DO NOT INCINERATECLOSED CONTAINERS.
DISPOSE ONLY IAW FEDERAL, STATE LOCAL REG. HAZARDOUS WASTE NUMBER
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:RESPIRATOR FOR AIRBORNE PARTICLES.
Ventilation:LOCAL EXHAUST SHOULD BE SUFFICIENT
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
WORKING PROCEDURES SHOULD MINIMIZE FOGGING AFFECT.
* Product Identification *
Product ID:RUBBERIZER (TM), BOOMS, PILLOWS, PARTICULATE
Preparer's Name:PHILIP W. STAGG
CAGE:0GFG5
CAGE:0GFG5
* Composition/Information on Ingredients *
Ingred Name:NON HAZARDOUS INGREDIENTS
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NONE SPECIFIED BY MANUFACTURER.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:RESPIRATORY CONDITIONS AND EYE IRRITATION ARE
POSSIBLE AND SKIN IRRITATION AS WITH EXPOSURE TO ANY FINE OR GRAINY
MATERIAL.
Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS AND EYE
IRRITATION AND SKIN CONDITIONS MAY BE AGGRAVATED BY EXPOSURE.
* First Aid Measures *
First Aid:FLUSH AFFECTED AREAS THOROUGHLY WITH WATER AND CONSULT A
PHYSICIAN IF IRRITATION PERSISTS.
* Fire Fighting Measures *
Flash Point Method:COC
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:CARBON DIOXIDE, LOW PRESSURE WATER AND DRY CHEMICAL
Fire Fighting Procedures:USE OF LOW PRESSURE WATER IS ADVISED, HIGH
PRESSURE WATER MAY GENERATE AIRBORNE DUST RESULTING IN A N
EXPLOSION HAZARD.
Unusual Fire/Explosion Hazard:DUST AND AIR MIXTURES MAY BE EXPLOSIVE IN
THE PRESENCE OF SPARKS OR ANY IGNITION SOURCE. THIS IS A SIMILAR
HAZARD TO THAT OF ANY ORGANIC DUST.
* Accidental Release Measures *
Spill Release Procedures:IF NOT CONTAMINATED, IT MAY BE SWEPT UP AND
RETURNED TO ITS CONTAINER. IF CONTAMINATED, DISPOSE OF PROPERLY.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:PRODUCT SHOULD BE STORED AWAY FROM
EXCESSIVE HEAT AND/OR IGNITION SOURCES. PREFERRABLE LONG TERM
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:N1
Boiling Pt:B.P. Text:NOT GIVEN
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Pres:NOT GIVEN
Vapor Density:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE, GRAINY MATERIAL, MILD, SWEET ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
DO NOT ALLOW CONTACT WITH STRONG OXIDIZING AGENTS, IE CONCENTRATED
NITRIC AND SULFURIC ACIDS, ETC.
Stability Condition to Avoid:IGNITION SOURCES, EXCESSIVE HEAT.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
OXIDES OF CARBON.
* Disposal Considerations *
Waste Disposal Methods:DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER
OR LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:APPROPRIATE NIOSH RESPIRATOR SHOULD BE AVIALABLE
FOR NON-ROUTINE OR EMERGENCY USE ABOVE THE TLV.
Ventilation:USE GENERAL AND LOCAL EXHAUST VENTILATION (EXPLOSION-PROOF)
TO KEEP VAPORS BELOW THE TLV REQUIREMENTS IN THE WORKPLACE.
Other Protective Equipment:RUBBER BOOTS, CLOTHING TO BE CHANGED DAILY
AND LAUNDERED. EYEWASH FOUNTAINS, SHOWERS AND WASHING FACILITIES.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
PROVIDE SUITABLE TRAINING TO THOSE HANDLING AND WORKING WITH THIS
MATERIAL. AVOID INHALATION OF VAPORS. INDOOR USE OF THIS MATERIAL
REQUIRES EXHAUST VENTILATION TO REMOVE VAPORS.
* Product Identification *
Product ID:REGULAR UNLEADED AUTOMOTIVE GASOLINE
CAGE:0LMC0
* Composition/Information on Ingredients *
Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III)
Other REC Limits:NONE SPECIFIED
Ingred Name:HYDROCARBONS (AROMATIC & PARAFFINIC)
Other REC Limits:NONE SPECIFIED
Ingred Name:BENZENE (SARA III)
Fraction by Wt: < 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:ETHYL BENZENE (SARA III)
Fraction by Wt: 1 - 3%
Other REC Limits:NONE SPECIFIED
Ingred Name:CYCLOHEXANE (SARA III)
Fraction by Wt: < 2%
Other REC Limits:NONE SPECIFIED
Ingred Name:CUMENE (SARA III)
Fraction by Wt: < 2%
Other REC Limits:NONE SPECIFIED
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Other REC Limits:NONE SPECIFIED
Ingred Name:TOLUENE (SARA III)
Other REC Limits:NONE SPECIFIED
Ingred Name:METHYL TERT-BUTYL ETHER (SARA III)
Other REC Limits:NONE SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION CAUSES INTENSE BURNING OF
MUCOUS MEMBRANES, THROAT AND RESPIRATORY TRACT, BRONCHOPNEUMONIA,
PULMONAY EDEMA. REPEATED OR PROLONGED SKIN CONTACT CAUSES
DERMATITIS, BLISTERING OF THE SKIN, DEF ATTING. EYE CONTACT MAY
CAUSE HYPEREMIAOF THE CONJUNCTIVA. INGESTION MAY CAUSE CENTRAL
NERVOUS SYSTEM DISTURBANCES.
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS BENZENE WHICH IS
LISTED AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:BURNING OF MUCOUS MEMBRANES, THROAT,
RESPIRATORY TRACT, BRONCHOPNEUMONIA, PULMONAY EDEMA, DERMATITIS,
SKIN BLISTERING, DEFATTING, INEBRIATION, DROWSINESS, BLURRED
VISION, VERTIGO, CONFUSION, VOMITING, UNCONSCIOUSNESS,
CONVULSIONS, CYANOSIS. ASPIRATION HAZARD.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN CONDITIONS MAY BE
AGGRAVATED BY EXPOSURE.
* First Aid Measures *
UNDER EYELIDS. CALL A PHYSICIAN. SKIN: REMOVE CONTAMINATED
CLOTHING. WASH EFFECTED AREA WITH SOAP AND WATER. IF IRRITATION
DEVELOPS, CALL A P HYSICIAN. INHALTION: REMOVE TO FRESH AIR.
RESSTORE BREATHING AND ADMINISTER OXYGEN IF NEEDED. INGESTION: DO
NOT INDUCE VOMITING! CONTACT A PHYSICIAN. NEVER GIVE ANYTHING BY
MOUTH IF UNCONSCIOUS.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, ALCOHOL FOAM
Fire Fighting Procedures:USE OF WATER MAY BE INEFFECTIVE TO EXTINGUISH
FIRE, BUT USE WATER SPRAY TO COOL FIRE EXPOSED DRUMS AND TANKS.
FIRE-FIGHTERS SHOULD WEAR SCBA AND PROTECTIVE GEAR
Unusual Fire/Explosion Hazard:VAPORS CAN FLOW ALONG SURFACES, REACH
DISTANT IGNITION SOURCES AND FLASH BACK. CAN REACT VIOLENTLY WITH
OXIDIZING AGENTS.
* Accidental Release Measures *
Spill Release Procedures:REPORT SPILLS AS REQUIRED. REMOVE SOURCES OF
HEAT OR IGNITION. PROVIDE ADEQUATE VENTILATION. CLEAN-UP PERSONNEL
REQUIRE PROTECTION AGAINST LIQUID CONTACT AND VAPOR INHALATION.
CONTAIN SPILL. DO NOT AL LOW TO ENTER SEWER OR SURFACE WATER. ADD
ABSORBENT
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS IN A COOL,
DRY, WELL-VENTILATED AREA AWAY FROM SOURCES OF HEAAT, IGNITION AND
STRONG OXIDIZING AGENTS.
Other Precautions:PROTECT CONTAINERS FROM PHYSICAL DAMAGE. AVOID DIRECT
SUNLIGHT. OUTDOOR OR DETACHED STORAGE PREFERRED. NO SMOKING IN
AREAS OF USE. PREVENT STATIC ELECTRIC SPARKS AND USE
EXPLOSION-PROOF ELECTRICAL SER VICES. AVOID SKIN CONTACT.
* Physical/Chemical Properties *
HCC:F2
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Density:3.0 - 4.0
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, MOBILE LIQUID WITH A CHARACTERISTIC GASOLINE
ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:SPARKS, IGNITION SOURCES, OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE,
HYDROCARBONS
* Disposal Considerations *
Waste Disposal Methods:BURN SCRAP MATERIAL IN AN APPROVED INCINERATOR.
BURN CONTAMINATED IQUID BY SPRAYING INTO AN INCINERATOR. DISPOSE IN
ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SCBA
Ventilation:AS MUCH AS POSSIBLE
Other Protective Equipment:NONE
Supplemental Safety and Health
* Product Identification *
Product ID:MERCURY BATTERY
* Composition/Information on Ingredients *
Fraction by Wt: 6%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:POTASSIUM HYDROXIDE
Fraction by Wt: 9%
Other REC Limits:2 MG/CUM (CEILING)
ACGIH TLV:2 MG/CUM (CEILING)
Fraction by Wt: <1%
Other REC Limits:INORGANIC 0.1 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ZINC
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: BURNS. EYES: PERMANENT INJURY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:MERCURY INTOXICATION
* First Aid Measures *
First Aid:SKIN: FLUSH IMMEDIATELY W/WATER. EYES: FLUSH W/COPIOUS
OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Fire Fighting Procedures:USE SCBA WHEN LARGE NUMBER OF CELLS ARE
INVOLVED. CELLS MAY RELEASE TOXIC MERCURY FUMES WHEN INTEGRITY OF
CAN IS BROKEN.
* Accidental Release Measures *
Spill Release Procedures:AVOID SKIN & EYE CONTACT. DON'T INHALE.
*Handling and Storage *
Handling and Storage Precautions:AVOID MECHANICAL/ELECTRICAL ABUSE. USE
AT ROOM TEMP.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, DISASSEMBLING, PUNCTURING/RECHARGING
Hazardous Decomposition Products:MERCURY VAPORS & CAUSTIC POTASSIUM
HYDROXIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE SMALL QUANTITIES W/NORMAL TRASH. CHECK
W/LOCAL ENVIRONMENTAL AGENCIES/DURACELL FOR INFORMATION REGARDING
PROPER DISPOSAL OF LARGE QUANTITIES. DISPOSE OF IAW/FEDERAL, STATE
& LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
------------------------------
< Wt: 1.
OSHA PEL: see Table Z-2
ACGIH TLV: NOT ESTABLISHED
ACGIH STEL: C2.6 MG/M3;C3 PPM
------------------------------
< Wt: 1.
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Effects of Exposure: POLYTETRAFLUOROETHYLENE: INHALATION: MAY CAUSE PERSISTENT
PULMONARY EFFECTS IN SOME INDIVIDUALS. HYDROGEN FLUORIDE: SEVERE EYE/NOSE
& THROAT IRRITATION. PULMONARY EDEMA. OVEREXPOUSRE CAN INJURE THE L IVER
& KIDNEYS. CARBONYL FLUORIDE: IRRITATION, EYE CORROSION
W/CORNEAL/CONJUNCTIVAL ULCERATION. IRRITATION OF THE UPPER RESPIRATORY
PASSAGES/TEMPORARY LUNG IRRITATION EFFECTS.
Signs And Symptions Of Overexposure: POLYTETRAFLUOROETHYLENE: FEVER, FLU-LIKE
ILLNESS, CHILLS, COUGH. HYDROGEN FLUORIDE: CHOKING, COUGHING, IRRITATION,
FEVER, CHILLS, DIFFICULTY IN BREATHING, CYANOSIS, CARBONYL FLUORIDE:
IRRITATION, DISC OMFORT, RASH, COUGH, DIFFICULTY BREATHING, SHORTNESS OF
BREATH.
Medical Cond Aggravated By Exposure: INDIVIDUALS W/PREEXISTING DISEASES OF THE
LUNGS.
First Aid: INHALATION: REMOVE TO FRESH AIR. SKIN: IF MOLTEN POLYMER GETS ON
SKIN, COOL RAPIDLY W/COLD WATER. DON'T ATTEMPT TO PEEL POLYMER FROM SKIN.
*
Handling and Disposal
*
Spill Release Procedures: USE APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT DURING
CLEAN-UP. SPILLED MATERIAL IS A SLIPPING HAZARD. RECOVER UNDAMAGED &
MINIMALLY CONTAMINATED MATERIAL FOR REUSE & RECLAMATION. SHOVEL/SWEEP UP.
Waste Disposal Methods: DISPOSE OF BY RECYCLING/LANDFILL. INCINERATE ONLY IF
INCINERATOR IS CAPABLE OF SCRUBBING OUT HYDROGEN FLUORIDE & OTHER ACIDIC
COMBUSTION PRODUCTS. TREATMENT, STORAGE, TRANSPORTATION & DISPOSAL MUST
BE IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
Handling And Storage Precautions: KEEP CONTAINERS CLOSED TO AVOID
CONTAMINATION. DON'T USE A TORCH TO CLEAN THIS MATERIAL FROM EQUIPMENT W/O
LOCAL EXHAUST VENTILATION & RESPIRATOR.
Other Precautions: AVOID BREATHING DUST. AVOID CONTAMINATION OF
CIGARETTES/TOBACCO W/DUST FROM THE MATERIAL.
*
Fire and Explosion Hazard Information
*
Flash Point Method: CC
Extinguishing Media: WATER, FOAM, DRY CHEMICAL, CO2
Fire Fighting Procedures: WEAR SELF CONTAINED BREATHING APPARATUS. WEAR FULL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard: HYDROGEN FLUORIDE FUMES EMITTED DURING A FIRE
HANDLING REFUSE FROM FIRE.
*
*
PURIFYING RESPIRATOR W/DUST/MIST CARTRIDGE/CANISTER MAY PROVIDE PROTECTION
FROM AIRBORNE PARTICULATES. HIGHER PROCESSING TEMPS & IF VENTILATION IS
INADEQUATE TO MAINTAIN CONCENTRATIONS BELOW EXPOSURE LIMITS, USE A POSITIVE
PRESSURE AIR SUPPLIED RESPIRATOR.
Ventilation: LOCAL EXHAUST
Other Protective Equipment: HEAT RESISTANT CLOTHING & FOOTWEAR.
Work Hygienic Practices: CLEANSING THE SKIN AFTER USE IS ADVISABLE.
Supplemental Safety and Health: REVIEW FIRE FIGHTING MEASURES & HANDLING
(PERSONNEL) SECTIONS BEFORE PROCEEDING W/CLEAN-UP.
*
Physical/Chemical Properties
*
Spec Gravity: 2.1-2.3
Solubility in Water: INSOLUBLE
Appearance and Odor: WHITE GRANULES W/NO ODOR
*
Reactivity Data
*
Stability Indicator: YES
Materials To Avoid: ALUMINUM, MAGNESIUM, POTENT OXIDIZERS LIKE FLUORINE,
CHLORINE TRIFLUORIDE
Hazardous Decomposition Products: EVOLUTION OF PARTICULATE MATTER
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
Ecological: AQUATIC TOXICITY: TOXICITY IS EXPECTED TO BE LOW BASED ON
INSOLUBILITY IN WATER.
*
*
Transport Information: NOT REGULATED.
*
Regulatory Information
*
State Regulatory Information: STATE RIGHT-TO-KNOW: NO LISTED.
*
Other Information
*
Other Information: MEDICAL USE: CAUTION: DON'T USE IN MEDICAL APPLICATIONS
INVOLVING PERMANENT IMPLANTATION IN THE HUMAN BODY. FOR OTHER MEDICAL
ERIAL SAFETY DATA SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNED HEREIN
& DOES NOT RELATE TO USE IN COMBINATION W/ANY OTHER MATERIAL/IN ANY
PROCESS.
*
HAZCOM Label
*
Assigned IND: Y
Company Name: DUPONT FLUOROPRODUCTS
Label Required IND: Y
Status Code: A
Origination Code: G
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:ANY NIOSH APPROVED AIR-SUPPLIED RESPIRATOR OR
SELF-CONTAINED BREATHING APPARATUS. ONLY NIOSH APPROVED EQUIPMENT
SHOULD BE USED.
USED WHERE VAP EXPOS IS LIKELY. MECH (GEN):CONTROLS (SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . IMPERVIOUS APRONS & BOOTS WHERE SPLASHING CAN OCCUR.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHILE
HANDLING METHANOL.
Supplemental Safety and Health
CHANGES TO LUNGS, THORAX/RESP. VENT:MUST BE SPARKPROOF &
EXPLO-PROOF . EYE PROT:FULL LGTH FSHLD . FIRST AID PROC:DAYS.
* Product Identification *
Product ID:AIRBRAKE ANTIFREEZE, HDAAHA
CAGE:0KDB2
CAGE:0KDB2
* Composition/Information on Ingredients *
Fraction by Wt: 1-3%
OSHA PEL:N/K
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SUPDAT:LIFTING LOWER & UPPER LIDS OCCAS. GET MED ATTN AS
SOON AS POSS. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED (ING 5)
Ingred Name:ING 4:AREA W/SOAP & WATER; APPLY SKIN LOTIONS. IF
IRRITATION PERSISTS, GET MEDICAL ATTENTION.
Ingred Name:SPILL PROC:COMBUST CHAMBER. SPILLS IN SENSITIVE AREAS MAY
BE DILUTED & FLUSHED TO GROUND W/WATER SPRAY. DO NOT (ING 7)
Ingred Name:ING 7:PURSUANT TO CERCLA. WARN OCCUPANTS OF DOWNWIND AREAS.
Ingred Name:WASTE DISP METH:DISTILLATION PROCS. RCRA
Ingred Name:ING 9:IT IS CONSIDERED A TOXIC WASTE.
Ingred Name:OTHER PREC:& VISUAL FUNCTIONS, LIVER & KIDNEY SYSTEMS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:METHANOL IS POIS, NARC CHEM THAT CAN
AFFECT BODY THRU INHAL, INGEST & PERHAPS PRLNG/RPTD SKIN CONT.
ABSORPTION BY INHAL/INGEST IS RAPID & EXCRETION IS MUCH SLOWER THAN
FOR ETHYL ALCOHOL, RESULTING IN DELAYED EFT/COMPOUNDING OF EFTS BY
RPTDEXPOS. IT IS IMPORTANT TO BE AWARE THAT AFTER INGEST/INHAL,
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INITIAL SYMPS MAY BE ONLY THAT OF MILD
CAN BE FATAL. SYMPS OF OVEREXP INCL DIZZ, VISUAL IMPAIRMENT, NAUS,
RESP FAILURE, MUSCULAR INCOORD & NARCOS. PRLNG/RPTD SKIN CONT MAY
(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST:GET MED ATTN IMMED. INDUCE VOMIT W/1 TBSP OF IPECAC/BY
TOUCHING BACK OF THROAT (ONLY IF CONSCIOUS). ONCE VOMIT HAS
OCCURRED, HAVE PATIENT DRINK MILK, WATER/SOLN OF SODIUM BICARBONATE
IN WATER ( 1 HEAPING TBSP PER QUART). INHAL:REMOVEVICTIM TO FRESH
AIR AT ONCE. RESTORE &/OR SUPPORT BRTHG AS REQD. KEEP VICTIM WARM &
AT REST. GET MED ATTN AS SOON AS POSS. PVNT EXPOS TO METHANOL FOR 7
(SUPDAT)
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:6.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM & WATER
MIST OR FOG. USE A BLANKETING EFFECT TO SMOTHER FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:MODERATE EXPLOSION HAZARD & DANGEROUS
FIRE HAZARD WHEN EXPOSED TO HEAT, SPARKS OR FLAMES & CAN REACT
VIGOROUSLY W/OXIDIZING AGENTS.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNIT SOURCES. PROVIDE ADEQ VENT.
SM QTYS MAY BE ABSORBED ON PAPER TOWELS. EVAPORATE IN SAFE PLACE
(SUCH AS FUME HOOD). BURN PAPER IN APPRVD INCIN/OPEN PIT AWAY FROM
BLDGS & PEOPLE. LG QTYS CAN BE COLLECTED & ATOMIZED IN SUITABLE
(ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:FLAMM LIQ. GROUND & ELECTRICALLY
INTERCONNECT CNTNRS FOR TRANSFER. USE SPARKPROOF TOOLS. NO SMOKING
IN AREA OF USE/STOR. AVOID CONTACT W/EYES.
Other Precautions:AVOID PRLNG/RPTD BRTHG OF VAP/CONT W/SKIN. DO NOT
INGEST! STORE IN WELL-VENTED, FIREPROOF AREA, AWAY FROM SOURCES OF
HEAT, OPEN FLAME & IGNIT. PROVIDE PREPLACEMENT MED EXAMS FOR
* Physical/Chemical Properties *
Vapor Density:1.1
Evaporation Rate & Reference:5.9 (BUTYL ACETATE=1)
Solubility in Water:TOTALLY MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/CHARACTERISTIC PUNGENT
ALCOHOL ODOR.
Percent Volatiles by Volume:SUPDAT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS NITRATES, PERCHLORATES OR SULFURIC
ACID.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, OXIDIZING
CONDITIONS.
Hazardous Decomposition Products:TOXIC GASES & VAPORS (I.E., CARBON
MONOXIDE, FORMALDEHYDE) MAY BE RELEASED IN A METHANOL FIRE.
* Disposal Considerations *
Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS .
ABSORB IN VERMICULITE, DRY SAND, EARTH/SIMILAR MATL & DISP IN
SECURED SANIT LANDFILL. ATOMIZE IN SUITABLE COMBUST CHAMBER; DISP
OF VIA LICENSED WASTE S OLV DISP COMPANY/RECLAIM VIA FILTRATION&
(ING 9)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:VENT HOOD.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . LAB COAT & APRON. THIS IS A LAB-USE (SUPDAT)
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PH:1 (0.1M SOLN). EXPLO HAZ:IGNITE COMBUST MATLS. TOX GASES
PRDCD:SULFUR DIOXIDE, HYDROGEN. MATLS TO AVOID:COMBUST MATLS,
CARBIDES. SPILL PROC:BAKER NEUTRASORB(R) OR TEAM(R) 'LOW NA+' ACID
NEUTRALIZER S ARE FOR SPILLS OF THIS PROD. EYE PROT:& FULL LENGTH
FACESHIELD . OTHER PROT EQUIP:PROD FOR WHICH NO (ING 3)
* Product Identification *
* Composition/Information on Ingredients *
MG/KG.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3;3 STEL
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPP DATA:INDUSTRIAL PROTECTIVE EQUIPMENT HAS BEEN
DESIGNATED.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHALATION:SEVERE IRRITATION OR
BURNS OF RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION.
SKIN/EYE CONTACT:BURNS. SKIN ABSORPTION:NONE IDENTIFIED.
INGESTION:NAUSEA, VOMITING, SEVERE BURNS TO MOUTH, THROAT &
STOMACH, KIDNEY DISFUNCTION. CHRONIC:LUNG DAMAGE. TARGET
ORGANS:RESPIRATORY SYSTEM,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SULFURIC ACID:IARC MONOGRAPHS ON EVAL OF
IRRIT.
Effects of Overexposure:HLTH HAZ:LUNGS, EYES, SKIN, TEETH, KIDNEYS.
Medical Cond Aggravated by Exposure:RESPIRATORY SYSTEM DISEASE.
* First Aid Measures *
First Aid:INGEST:CALL MD. IF SWALLOWED, DO NOT INDUCE VOMIT. IF
CONSCIOUS, GIVE LG AMTS OF WATER. INHAL:REMOVE TO FRESH AIR. IF NOT
BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. SKIN:IMMED
CLTHG & SHOES. WASH CLTHG BEFORE RE-USE. EYE:IMMED FLUSH W/PLENTY
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:USE DRY CHEMICAL OR CARBON DIOXIDE. DO NOT USE
WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . DO NOT GET WATER INSIDE CONTAINERS.
Unusual Fire/Explosion Hazard:REACTS W/MOST METALS TO PRDCE HYDROGEN
GAS, WHICH CAN FORM EXPLO MIXT W/AIR. VIOLENT EXOTHERMIC RXN OCCURS
W/WATER. SUFFICIENT HEAT MAY BE PRDCD TO (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT CLTHG.
STOP LEAK IF YOU CAN DO SO W/OUT RISK. DO NOT USE WATER. NEUT SPILL
&/OR WASHINGS W/SODA ASH/LIME. WITH CLEAN SHOVEL, PLACE MATL INTO
CLEAN, DRY CNTNR &COVER. MOVE CNTNR(S) FROM SPILL AREA.
J.T.(SUPDAT)
Neutralizing Agent:SODA ASH OR LIME.
*Handling and Storage *
Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE IN
CORROSION-PROOF AREA. KEEP CNTNRS OUT OF SUN & AWAY FROM HEAT.
ISOLATE FROM INCOMPATIBLE MATERIALS. CORROSIVE MATL.
Other Precautions:POISON. DANGER. CAUSES SEV BURNS. REACTS VIOLENTLY
W/WATER. HARMFUL IF SWALLOWED/INHALED. CONT W/OTHER MATLS MAY CAUSE
FIRE. DO NOT GET IN EYES, ON SKIN, ON CLTHG. DO NOT BREATHE VAP.
USE W/ADEQ VENT.
* Physical/Chemical Properties *
pH:SUPDAT
Appearance and Odor:CLEAR, COLORLESS LIQUID; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER, ORGANIC MATLS, MOST COMMON METALS, STRONG BASES, CARBONATES,
SULFIDES, CYANIDES, STRONG REDUCING AGENTS, (SUPDAT)
Stability Condition to Avoid:MOISTURE, HEAT.
Hazardous Decomposition Products:OXIDES OF SULFUR, HYDROGEN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W ALL APPLICABLE FEDERAL, STATE &
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE GEN DILUTION/LOC EXHAUST FAILS TO ADEQ
DILUTE TWA/PEL OF MATL, THEN RESP PROT SHOULD BE USED AS
RESPS/HOODS FOR ENCLOSED & CONFI NED AREAS. NIOSH/MSHA APPRVD
(SUPDAT)
Ventilation:PROVIDE GEN DILUTION/LOC EXHAUST VENT TO KEEP TWA & LEL
BELOW ACCEPTABLE LIMITS & TO REMOVE DECOMP PRODUCTS.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLAN OF CARCIN:ANTIC TO BE CARCINOGEN. RESP PROT:AIR PURIFYING RESPS
MAY BE USED FOR OTHER AREAS.
* Product Identification *
Preparer's Name:MCQUINN
CAGE:0S4B8
CAGE:0S4B8
* Composition/Information on Ingredients *
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:0.1 MG/M3 RDUST
Ingred Name:ACETIC ACID, BUTYL ESTER; (BUTYL ACETATE) (CERCLA). VP:8.0
Ingred Name:ACETIC ACID, 2-METHOXY-1-METHYLETHYL ESTER; (1-METHOXY
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:VOLATILE ORGANIC CONTENT:3.8 POUNDS PER GALLON LESS WATER
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:OVEREXPOSURE BY INHALATION MAY
CAUSE IRRITATION OF RESPIRATORY TRACT, HEADACHE, DIZZINESS, OR
DROWSINESS. SKIN OR EYE CONTACT:IRRITANT TO EYES AND SKIN.
CHRONIC:MAY AFFECT RESPIRATORY TRACT - CE NTRAL NERVOUS SYSTEM -
KIDNEYS.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ:IARC MONO,
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:UNKNOWN AT THIS TIME.
* First Aid Measures *
First Aid:INHAL:REMOVE FROM EXPOSURE. EYE:FLUSH IMMEDIATELY WITH LG
CLOTHING & WASH SKIN WITH SOAP AND WATER. INGEST:DRINK WATER. IF
NECESSARY, CON SULT PHYSICIAN FOR ANY OF THESE CONDITIONS.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:USE WATER FOG, FOAM, DRY CHEMICAL, OR CARBON
DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, AVOID
BREATHING VAPORS, VENTILATE AREA, AND REMOVE W/INERT ABSORB &
NON-SPARKING TOOLS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT TAKE INTERNALLY. CNTNRS SHOULD
BE GROUNDED WHEN POURING. AVOID FREE FALL OF LIQUID IN EXCESS OF
FEW INCHES.
Other Precautions:MAKE SURE DRUM IS COMPLETELY EMPTY BEFORE ATTEMPTING
TO WELD/BRAZE. DRUM SHOULD BE INDUSTRIALLY CLEANED PRIOR TO REUSE.
DO NOT FLAME CUT, BRAZE, OR WELD W/OUT NIOSH/MSHA APPRVD RESP OR
APPROP VENTILAT ION.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:FUMES MAY CONTAIN CARBON MONOXIDE &
OXIDES OF NITROGEN. MAY PRODUCE HAZ FUMES WHEN HEATED TO DECOMP AS
IN WELDING.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGUALTIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED OR FOR SYMPTOMS OF OVER
EXPOSURE, WEAR NIOSH-APPROVED ORGANIC VAPOR RESPIRATOR OR
AIR-PURIFYING RESPIRATOR. IN EMERGENCY, WEAR A NIOSH-APPROVED
POSITIVE-PRESSURE SELF-CONTAINED BREA THING APPARATUS.
Ventilation:LOCAL EXHAUST IS RECOMMENDED FOR CONFINED AREAS. GENERAL
MECHANICAL VENTILATION IS ADEQUATE FOR NORMAL USE.
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN. ACUTE-
EYES/SKIN:MILD IRRITATION. INHALE:LOW HAZARD AT ROOM TEMPERATURE.
ORAL:MAY BE HARMFUL. CHRONIC- CAUSES SEVERE EYE IRRITATION. VAPORS
CAN CAUSE DAMAGE TO KIDNEYS, LIVER , LUNG, BLOOD AND CENTRAL
NERVOUS SYSTEM. INGESTION OF EXCESSIVE AMOUNTS MAY DAMAGE CENTRAL
NERVOUS SYSTEM AND KIDNEYS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, HEADACHE, DIZZINESS
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASES OF THE EYE, SKIN, RESPIRATORY TRACT, LIVER, KIDNEYS,
BLOOD, CNS MAY HAVE INCREASED SUSCEPTIBILITY TO THE TOXICITY OF
EXCESSIVE EXPOSURES.
* First Aid Measures *
First Aid:CALL PHYSICIAN IF SYMPTOMS PERSIST. EYE:IMMEDIATELY FLUSH
WATER. INHALED:REMOVE TO FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED.
ORAL:IF CONSCIOUS, DRINK 2 GLASSES OF WATER & INDUCE VOMITING.
CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. NEVER GIVE
FLUID OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS
CONVULSIONS.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:3.2
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, SAND, FOAM/DRY
CHEMICAL. WATER SPRAY MAY BE USED TO KEEP FIRE EXPOSED CONTAINERS
COOL.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:PREVENT SKIN AND EYE CONTACT. ABSORB SPILLS
WITH INERT MATERIAL SUCH AS SAND OR VERMICULITE. SCRAPE SPILL UP
INTO NONPOROUS CONTAINERS. SPILL AREA IS SLIPPERY. CLEAN SPILL AREA
WITH SOAP AND WATER.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL PLACE. KEEP CONTAINER
TIGHTLY CLOSED.
Other Precautions:WASH THOROUGHLY WITH SOAP AND WATER AFTER HANDLING
AND BEFORE EATING, DRINKING, SMOKING. KEEP OUT OF REACH OF
CHILDREN.
* Physical/Chemical Properties *
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Vapor Density:>1
Evaporation Rate & Reference:<1 (N-BUTYL ACETATE=1)
Solubility in Water:DISPERSIBLE
Appearance and Odor:COLORED LIQUID - MILD ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:OPEN FLAME
Hazardous Decomposition Products:MAY FORM CARBON MONOXIDE, CARBON
DIOXIDE, SMOKE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. INCINERATION IS RECOMMENDED.
| 1 | eyes_protection_mandatory |
Control Measures
*
Product ID: CONTACT CLEANER
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALATION: DIZZINESS. INGESTION: NAUSEA. SKIN: MILD
IRRITATION. MAY CAUSE LOCALIZED DEFATTING OF TISSUE. EYES: IRRITATION,
REDDENING.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE.
First Aid: INHALATION: REMOVE TO FRESH AIR. APPLY ARTIFICIAL RESPIRATION IF
INDICATED. INGESTION: DO NOT INDUCE VOMITING. CONTACT MD IMMEDIATELY. SKIN:
CONTACT MD.
*
Handling and Disposal
*
Spill Release Procedures: WIPE UP WITH RAG OR USE SOME ABSORBENT CLAY MATERIAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF RESIDUE IN ACCORDANCE WITH FEDERAL, STATE
AND LOCAL GUIDELINES.
Handling And Storage Precautions: DO NOT USE OR STORE NEAR HEAT OR OPEN FLAME.
Other Precautions: VAPOR MAY COLLECT IN LOW-LYING AREAS.
*
Fire and Explosion Hazard Information
*
Flash Point Method: TCC
Lower Limits: 1.2%
Upper Limits: 7.5%
Extinguishing Media: CARBON DIOXIDE.
Fire Fighting Procedures: NONE. USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: CONTENTS UNDER PRESSURE. EXPOSURE TO
ATMOSPHERE IN CONFINED AREAS.
*
*
Respiratory Protection: ONLY USE IN WELL-VENTILATED AREAS. USE NIOSH APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N).
Ventilation: LOCAL EXHAUST: SUFFICIENT.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
*
Physical/Chemical Properties
*
Vapor Density: <1
Evaporation Rate & Reference: 7.1
Solubility in Water: 0% (BUTYL ACETATE=1)
Appearance and Odor: CLEAR WATER WHITE SPRAY; SOLVENT ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: NONE KNOWN.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: CONTACT CLEANER
Assigned IND: Y
Company Name: MKG SALES ASSOCIATES
Label Required IND: Y
Status Code: C
Origination
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHALATION: DIZZINESS. INGESTION: NAUSEA. SKIN:
MILD IRRITATION. MAY CAUSE LOCALIZED DEFATTING OF TISSUE. EYES: IRRITATION,
REDDENING. CHRONIC: NONE LISTED BY MANUFACTURER.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SELF CONTAINED BREATHING APPARATUS FOR SPILLS.
Ventilation:LOCAL EXHAUST VENTILATION REQUIRED TO COMPLY W/OSHA
THRESHOLD LIMIT.
Other Protective Equipment:FACE SHILED, BOTTS, RESISTANT CLOTHING,
EYEWASH STATION IN AREA.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
WASH CONTAMINATED CLOTHING BEFORE REUSE.
* Product Identification *
Product ID:AQUA AMMONIA, AMMONIUM HYDROXIDE SOLUTION #2
* Composition/Information on Ingredients *
Ingred Name:AMMONIUM HYDROXIDE (CERCLA)
Other REC Limits:NONE RECOMMENDED
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
Ingred Name:NON-HAZARDOUS CORROSION INHIBITOR
Fraction by Wt: TRACE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION & DESTRUCTION OF TISSUE ON
ANY EXPOSED PART OF THE BODY DUE TO FREEZING OF TISSUE & CAUSTIC
ACTION PRODUCED BY REACTION OF AMMONIA & BODY MOISTURE. SEVERE
COUGHING & BRONCHIAL SPASMS CAN OC CUR. AMMONIA IS NOT ACCUMULATED
IN THE BODY & THERE IS NO EVIDENCE OF CHRONIC EFFECT.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, SERIOUS OCCULAR DAMAGE, VISUAL
DISTURBANCES, SCARRING OF CORNES, EYE ITCHING, CONJUNCTIVITIS,
TISSUE BURNS, SKIN ITCHING, SKIN IRRITATION, THROAT IRRITATION, GI
TRACT IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP AND WATER. IF IRRITATION PERSIST, GET MEDICAL
ATTENTION. INH ALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET
MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:NONFLAMMABLE. USE EXTINGUISHING MEDIA SUITABLE FOR
SURROUNDING FIRE.
Fire Fighting Procedures:NOT CONSIDERED PRIMARY FIRE HAZARD BUT CARE
SHOULD BE TAKEN TO AVOID EXPOSURE TO LIQUID PRODUCT INVOLVED IN
FIRE. USE FULL PROTECTIVE GEAR AND SCBA.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:WEAR RESPIRATORY PROTECTION AND PROTECTIVE
CLOTHING. STOP SOURCE IF POSSIBLE. STAY UPWIND AND USE WATER SPRAY
TO ABSORB EVOLVED GAS. DILUTE WITH ABUNDANCE OF WATER. REPORTABLE
WATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SUNLIGHT OR OPEN
FLAMES. STORE IN WELL-VENTILATED AREA.
* Physical/Chemical Properties *
HCC:B1
Decomp Temp:Decomp Text:NOT GIVEN
Vapor Density:< 1
Evaporation Rate & Reference:SIMILAR TO WATER
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID WITH VERY PUNGENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
SULFURIC ACID, STRONG MINERAL ACIDS, HYPOCHLORITE SOLUTIONS(BLEACH),
HALOGENS, SODIUM HYDROXIDE, METALS
Stability Condition to Avoid:EXCESSIVE HEAT.
Hazardous Decomposition Products:WILL LIBERATE AMMONIA IF HEATED.
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:RESPIRATOR PROTECTION IS NOT NORMALLY NEEDED.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYE WASH WHICH MEETS ANSI DESIGN
CRITERIA .
Work Hygienic Practices:IF CLTHG IS CONTAM, REMOVE CLTHG & THORO WASH
THE AFFECTED AREA. LAUNDER CONTAM CLTHG BEFORE REUSE. DISCARD (ING
6)
Supplemental Safety and Health
COOL CONTAINERS EXPOSED TO FIRE. FIRST AID PROC: CONVULSIONS, DO
NOT INDUCE VOMITING OR GIVE WATER. HYGIENE PRACT: CONTAMINATED SH
OES AND LEATHER ITEMS. SPILL PROC: RECOVERY OR SALVAGE DRUMS FOR
DISPOSAL. REFER TO CERCLA IN (ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ING 2: DRUMS OR TANK TRUCK FOR DISPOSAL. REFER TO CERCLA IN
REGULATORY INFO SECTION.
Ingred Name:WASTE DISP: LIQUID WASTE, IT SHOULD BE SOLIDIFIED BEFORE
DISPOSAL TO A SANITARY LANDFILL. CAN BE DEEP-WELL (ING 5)
Ingred Name:ING 4: INJECTED IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS.
Ingred Name:WORK HYGIENE: DISCARD CONTAMINATED SHOES AND LEATHER ITEMS.
Ingred Name:TRIPHOSPHORIC ACID, PENTASODIUM SALT; (SODIUM
TRIPOLYPHOSPHATE) (SARA III)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SUPP DATA: REGULATROY INFO SECTION. LRG SPILLS: DIKE TO
PVNT FURTHER MOVEMENT & RECLAIM INTO RECOVERY OR SALVAGE (ING 3)
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: CAN CAUSE TRANSIENT IRRITATION.
SKIN: CAN CAUSE TRANSIENT IRRITATION.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:A REVIEW OF AVAILABLE DATA DOES NOT IDENTIFY
ANY SYMPTOMS FROM EXPOSURE.
Medical Cond Aggravated by Exposure:A REVIEW OF AVAILABLE DATA DOES NOT
IDENTIFY ANY WORSENING OF EXISTING CONDITIONS.
* First Aid Measures *
(GIVE O*2/ARTF RESP). INGEST:GET MD IMMED . NOTE TO MD: NO SPEC
IFIC ANTIDOTE IS KNOWN. BASED ON THE INDIVIDUAL RXNS OF THE
PATIENT, THE MD'S JUDGEMENT SHOULD BE USED TO CONTROL SYMPTOMS &
CLINICAL CNDTNS. CAUTION: IF UNCON, HAVING TROUBLE BRTHG OR IN
(SUPP DATA)
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:THIS PROD WOULD NOT BE EXPECTED TO BURN UNLESS ALL
WATER IS BOILED AWAY. THE REMAINING ORGANICS MAY BE (SUPP DATA)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:MAY EVOLVE SO*X UNDER FIRE CONDITIONS.
* Accidental Release Measures *
Spill Release Procedures:IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE
W/ABSORB MATL, SUCH AS SAW DUST, CLAY, SOIL OR ANY COMMERCIALLY
AVAILABLE ABSORBENT. SHOV EL RECLAIMED LIQUID & ABSORBENT INTO
(SUPP DATA)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:DO NOT BREATHE SMOKE OR FUMES. WEAR SUITABLE
PROTECTIVE EQUIPMENT.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:1.1
pH:SUPDAT
Solubility in Water:COMPLETELY
Appearance and Odor:DARK BROWN LIQUID, SWEET ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:IN THE EVENT OF COMBUSTION CO, CO*2,
SO*X MAY BE FORMED.
* Disposal Considerations *
Waste Disposal Methods:IF THIS PROD BECOMES A WASTE, IT DOES NOT MEET
4)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
Ventilation:LOCAL RECOMMENDED
Other Protective Equipment:EYE WASH STATION
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POLYDIMETHYLSILOXANE POLYMERS
Other REC Limits:NONE RECOMMENDED
Ingred Name:TEFLON (TETRAFLUORO ETHYLENE POLYMER)
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM BICARBONATE
Fraction by Wt: 1.0%
Other REC Limits:NONE RECOMMENDED
Ingred Name:HEPES
Fraction by Wt: 1.0%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE AND CHRONIC- PRODUCT IS NOT
EXPECTED TO PRESENT A HEALTH HAZARD WHEN EMPLOYING GOOD LABORATORY
PRACTICES.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NONE IF USED AS INTENDED.
* First Aid Measures *
First Aid:GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. SKIN:REMOVE
CONTAMINATED CLOTHING. WASH SKIN WITH SOAP & WATER. EYE:FLUSH WITH
ORAL:IF CONSCI OUS, DRINK TWO GLASSES OF WATER. INDUCEVOMITING.
CALL A PHYSICIAN.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:CONTAIN THE SPILL WITH ABSORBENT MATERIAL.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE IN CLOSED CONTAINERS.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. USE LOCAL EXHAUST TO
CONTROL EMPLOYEE EXPOSURE.
* Physical/Chemical Properties *
HCC:N1
NRC/State Lic Num:NOT RELEVANT
Appearance and Odor:CLEAR, ODORLESS SOLUTIONS: ACID (YELLOW), NORMAL
(GREEN), ALKALI (RED)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONEDES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
* Product Identification *
Preparer's Name:DOD HMIS/DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS, CHRYSOTILE
OSHA PEL:0.2 FIBERS/CC
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC RUBBER COMPOSITION
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
*Handling and Storage *
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
* Physical/Chemical Properties *
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS. DIRECT
PHYSICAL CONTACT SHOULD BE AVOIDED.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST: CALL MD IMMEDIATELY (FP N). EYES: FLUSH WITH COPIOUS AMOUNTS
INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN IF NECESSARY. CONTACT MD.
*
Handling and Disposal
*
Spill Release Procedures: DUE TO SMALL QUANTITY INVOLVED, SPILLS/LEAKS SHOULD
NOT POSE A SIGNIFICANT PROBLEM. A LEAKING BOTTLE MAY BE PLACED IN PLASTIC BAG
& NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE ABSORBED ON
VERMICULITE OR SAND.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER & SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS
CONCERNING DISPOSAL.
Handling And Storage Precautions: KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY
PLACE.
Other Precautions: THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS TRAINED
IN THE SAFE HANDLING OF HAZARDOUS CHEMICALS.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
*
*
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment: WEAR CHEMICAL RESISTANT CLOTHING SUCH AS LAB COAT
&/OR RUBBER APRON TO PREVENT CONTACT W/EYES, SKIN & CLOTHING.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
FACESHIELD (FP N).
*
Physical/Chemical Properties
*
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: ULTRA SCIENTIFIC
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: AVOID PHYSICAL CONTACT. CHRONIC: NONE LISTED BY
MANUFACTURER.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:OUTDOORS:USE MECHANICAL FILT RESP WHILE
SPRAYING.RESTRICTED VENTI AREA:USE APPROV CHEM/MECH FILT DESIGNED
TO REMOVE COMBINATION OF PARTICULATES & VAPORS.CONFINED AREAS:USE
APPROVED AIR LINE TYP RESP O R HOODS.
Ventilation:PROVIDE VENTI OF SUFFIC VOL/PTRN TO KEEP AIR CONTAM CONCEN
BEL VALS.EXHAUS FILT SYS TO AVOID ENVIRO CONTAM.IAW EMISS REG
Other Protective Equipment:WEAR CHEM RESIST SHOES.REMOVE/WASH CONTAM
CLOTH BEF REUSE.WEAR RUBB/PLAST APRON.CLEAN H2O SOURCE AVAI FOR
EYE/SKIN FLUSH
Work Hygienic Practices:WASH HANDS BEF EAT/WASHRM USE.SMOKE IN
DESIGNATED SMOKING AREAS ONLY.AVOID REP/PROL SKIN CONTACT.LIQ
PENETR LEATHER-BURN
Supplemental Safety and Health
FIREFIGHT:EQPTM +SCBA SHOULD BE USED TO PROT FIGHTER FRM HAZ COMBUST
PROD.AVOID BURN LIQ SPREAD W/H2O. FIRE/EXPLO:EMERG
CONDITIONS/OVEREXPO MAY CAUSE HEALTH HAZ.SYMPT MAY NOT BE IMMED
APPARENT.GET MED ATTN.VAP MAY IGNITE BY STAT ELECT/FRICSPARKS.VAP
HEAVIER THAN AIR-TRAVEL DISTANCES TO IGN PT/FLASHBACK.KEEP CNTNR
CLSD
* Product Identification *
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
Ingred Name:ALIPHATIC HYDROCARBON (MS)
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: <8%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: NA
Other REC Limits:NONE RECOMMENDED
Ingred Name:PROPANE
Other REC Limits:NONE RECOMMENDED
Ingred Name:BUTANE
Other REC Limits:NONE RECOMMENDED
Ingred Name:ISOBUTANE
Other REC Limits:NONE RECOMMENDED
Ingred Name:TITANIUM DIOXIDE
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 0-5%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:ANESTHETIC.IRRIT RESP
TRACT,ACUTE NERV SYS DEPRESS CHARACTERIZED BY FOLLOWING PROGRESSIVE
STEPS:HEAD,DIZZ,STAGGERING
GAIT,CONFUSION,UNCONSC,COMA,ASPHIXIATION.SKIN/EYE CONTACT:PRIMARY
IRRIT .CHRONIC:OVEREXPO TO THIS MATL(OR COMPO)HS BEEN SUGGESTED AS
CAUSE OF REPRODUCTIVE DISORDERS,CARDIAC/LIV ABNORM,EYE DMG.
Explanation of Carcinogenicity:PER
MSDS:CARCINOGENICITY:NTP/IARC/OSHA:NO.
Effects of Overexposure:ANESTHETIC,IRRIT RESP TRACT,NERVOUS SYS
DEPRESSION-HEADACHE,DIZZ,STAGGERING
GAIT,CONFUSION,UNCONSC,COMA,ASPHIXIATION. EYE/SKIN IRRIT.
REPRODUCTIVE DISORDERS,CARDIAC & LIVER ABNORMALITIES, EYE DAMAGE.
Medical Cond Aggravated by Exposure:ASHTMA. RESPIRATORY &/OR SKIN
ALLERGIES IN SUSCEPTABLE PERSONS.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR.RESTORE BREATHING.TREAT
SYMPTOM.CONSULT DR.SPLASH(EYE):FLUSH IMMED W/LG ATMS OF
CONSULT PHYSICIAN.SPLASH(SKIN):WA SH W/SOAP/WATER.REMOVE CONTAMIN
CLOTH.CONSULT DR IF IRRIT PERSISTS.INGEST:CONSULT DR/POISON CNTRL
CNTR IMMED.TREAT SYMPTOMATICALLY.
* Fire Fighting Measures *
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:0.9
Upper Limits:NP
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
OSHA:CLASS IA, DOT FLAMMABLE LIQUID.
Fire Fighting Procedures:H2O MAY BE INEFFECTIVE;IF USE,FOG NOZZ
PREFER.H2O MAY BE USED TO COOL CLSD CNTNR-PREVENT PRESSURE
BUILDUP/AUTO-IGN WHEN EXPO TO EXTREME HEAT.FULL PROTECT(SUPPL)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT/ELECTR EQPMT/SPARKS/OPN
FLAME.APPLICATION TO HOT SURFACES REQUIRE SPEC PRECAUT.CLSD CNTNR
MAY EXPLO WHEN EXPO TO EXTREME HEAT.DURING (SUPPLE)
* Accidental Release Measures *
Spill Release Procedures:LIMIT SPREAD OF SPILL/LEAK.REMOVE ALL SOURCES
OF IGNITION.SOAK UP W/INERT ABSORBANT MATL.USE NON-SPARKING TOOLS
WHEN REMOVING WET ABSORBENT.SEE OTHER MSDS SECTION FOR REQUIRED
PROTECTIVE MEASURES.KEEP MATL OUT OF SEWERS &/OR DRAINS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM EXTREME HEAT/FIRE/OPEN
Other Precautions:DONT HNDLG TIL MFG SAF PRECAUT READ/UNDERSTOOD.STORE
IN WELL VENTI AREA.KEEP DR OUT OF DIRECT SUN/TIGHT
/UPRIGHT.DONT STORE/USE NEAR HEAT/SPARK/OPN FLAME.GROUND/BOND
WHEN POUR.DONT USE PRESS TO EM PTY-NOT PRESS VESS.
* Physical/Chemical Properties *
HCC:V3
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:NP
Vapor Density:>AIR
Spec Gravity:NP
pH:NP
Viscosity:NP
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NP
Appearance and Odor:LIGHT YELLOW
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
PEROXIDES OR STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAME.
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEAT TO
DECOMPO,AS IN WELD OR FIRE.FUMES MAY CONTAIN:CO,CO2,&VARIOUS OTHER
HYDROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:DISPO OF IAW ALL LOC,STATE,FED REGS.APPROVED
LANDFILL,APPROVED HAZ WASTE SITE,INCINERATION.CHEM SUBJ TO REPORT
BENZENE,XYLENE,TOLUENE,N-BUTANOL,ACETONE.CNTNR DISPO IAW APPL
LAWS/REGS.DONT GIVE EMPTY DR TO PEOPLE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:VENTILATION RATE SUFFICIENT TO KEEP VAPORS AND SPRAY MISTS
BELOW THE OSHA PELS.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:MINERAL OIL, WHITE; (WHITE MINERAL OIL)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:KEROSENE
ACGIH TLV:N/K
Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: DIZZINESS, NAUSEA. SKIN:
IRRITATES SKIN BY DISSOLVING SKIN OILS. EYE: IRRITATING TO EYES.
INGEST: GASTRIC UPSET.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. SKIN: WASH OFF PROMPTLY WITH SOAP
AND WATER. USE SOOTHING LOTIONS. EYE: RINSE COPIOUSLY WITH WATER
CONTROL OF PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:1%
Upper Limits:6%
Extinguishing Media:CARBON DIOXIDE, FOAM.
Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY. DO NOT
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:AEROSOL CANS MAY BURST IF HEATED ABOVE
* Accidental Release Measures *
Spill Release Procedures:
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:AVOID REPEATED OR PROLONGED CONTACT
WITH SKIN. DO NOT GET IN EYES. AVOID BREATHING SPRAY MIST.
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Vapor Density:> 1
pH:NEUT
Evaporation Rate & Reference:NIL
Solubility in Water:EMULSIFIABLE
Appearance and Odor:GREEN OILY LIQUID.
Percent Volatiles by Volume:5
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:
Hazardous Decomposition Products:WHEN BURNING, SOOT, SMOKE, OXIDES OF
CARBON AND NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE OR SEND TO WASTE DISPOSER WHO CAN
INCINERATE IT. EMPTY OUT AEROSOL CANS BEFORE DISPOSAL. PRESSURIZED
AEROSOL CANS ARE NOT AN ACCEPTABLE WASTE. DISPOSAL MUST BE IN
ACCORDANCE WITH FEDERAL, S TATE AND LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION IS INADEQUATE OR SIGNIFICANT
PRODUCT EXPOSURE IS LIKELY, USE A NIOSH/MSHA APPROVED RESPIRATOR
WITH DUST/MIST FUME CARTRIDGES.
Ventilation:ADEQUATE VENTILATION.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . FULL COVERALLS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
* Product Identification *
Product ID:CONPRO-ONE SHOT
CAGE:CNPRC
* Composition/Information on Ingredients *
Ingred Name:A GRADED DRY POWDER MIXTURE OF INGREDIENTS 2-5
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CALCIUM OXIDE
OSHA PEL:5 MG/M3
ACGIH TLV:2 MG/M3
Ingred Name:SILICIC ACID, CALCIUM SALT; (CALCIUM SILICATE)
Ingred Name:SILICON DIOXIDE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CALCIUM CARBONATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN:MAY CAUSE SKIN IRRITATION AFTER
CONTACT. HYPERSENSITIVE INDIVIDUALS MAY DEVELOP AN ALLERGIC
DERMATITIS. EYE:SEVERLY DAMAGING TO THE EYES. RESPIRATORY
EFFECTS:MAY CAUSE MINOR IRRITATION TO UPPER R ESPIRATORY TRACT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:SKIN:REMOVE CONTAMINATED CLOTHING. WASH EXPOSED AREA WITH A
PHYSIC IAN IMMEDIATELY FOR ADDITIONAL TREATMENT. INHAL:REMOVE FROM
CONTAM AREA TO FRESH AIR. APPLY APPROP FIRST AID TREATMENT AS NEC.
INGESTION:DO NOT FEED ANYTHING BY MOUTH TO AN UNCON/CONVULSIVE
VICTIM.
* Fire Fighting Measures *
Extinguishing Media:GEN:MATL WILL NOT CONTRIBUTE TO COMBUST. FOAM/WATER
MAY CREATE SLIPPERY CNDTN. CONT W/WATER MAY CAUSE EVENTIAL (SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:GENERAL:USE DRY CLEAN UP METHODS THAT DO NOT
DISPENSE THE DUST INTO THE AIR. SPECIFIC:AVOID BREATHING THE DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN A DRY ENVIRONMENT.
Other Precautions:NORMAL CHEMICAL HANDLING.
PROT:AND FULL LENGTH FACE SHIELD .
* Physical/Chemical Properties *
Spec Gravity:SUPP DATA
pH:SUPDAT
Evaporation Rate & Reference:<1 ETHER=1
Solubility in Water:1% (LEAVES SEDIMENT)
Appearance and Odor:GRAY DRY POWDER WITH A MILD ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL DECOMPOSITION YIELDS OXIDES OF
CA, S, N, NA, K AND HALOGENS IF PRESENT.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . GENERAL:MATERIAL CAN BE RETURNED TO CONTAINER FOR
LATER USE OR DISPOSED OF AS COMMON WASTE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF 8 HR EXPOSURE LIMIT OR VALUE IS EXCEEDED FOR
ANY COMPONENT, USE AN APPROVED NIOSH/MSHA RESPIRATOR. CONSULT YOUR
FOR RESPIRATOR REQ UIREMENTS.
Ventilation:PROVIDE SUFF MECH VENT (LOCAL/GEN EXHST) TO MAINTAIN EXP
BELOW PEL & TLV. VAPS ARE HVR/AIR & WILL COLLECT IN (ING 6)
Other Protective Equipment:PROVIDE EYEWASH & SOLVENT IMPERVIOUS APRON
IF BODY CONTACT WITH PRODUCT MAY OCCUR. BARRIER CREAMS MAY BE USED.
Work Hygienic Practices:WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EXPLO HAZ: THERMAL DECOMP PROD MAY INCLUDE HCL AND PHOSGENE . EFTS OF
OVEREXP: CHLOROCARBON MATLS HAVE PRODUCED SENSIT OF MYOCARDIUM TO
EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR EFT IN H UMANS.
ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT
FOR LIFE-SUSTAINING USES (INGREDIENT 5)
* Product Identification *
Product ID:DAP WELDWOOD ORIGINAL CONTACT CEMENT
* Composition/Information on Ingredients *
Ingred Name:METHYL CHLOROFORM (1,1,1-TRICHLOROEHANE) (SARA III)
Ozone Depleting Chemical:1
Ingred Name:TOLUENE (SARA III)
Ingred Name:OTHER PREC: STORE AWAY FROM CAUSTICS AND OXIDIZERS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY IRRIT EYES/SKIN/NOSE & RESP
TRACT. HARMFUL IF INHALED. HARMFUL/FATAL IF SWALLOWED. IF INGESTED
CAUSES VOMIT, DIARRRHEA, & DEPRESSED RESP. INHAL MAY AFFECT
BRAIN/NERV SYS CAUSING DIZZ HDCH/N AUSEA, OVEREXP/MISUSE OF TOLUENE
CAN CAUSE LIVER, KIDNEY & BRAIN DAMAGE. CHRONIC: REPORTS HAVE ASSOC
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:DIETHYLENE DIOXIDE(1,4 -DIOXANE): IARC
GROUP 2B, NTP GROUP 2
Effects of Overexposure:HLTH HAZ: PRLNG & RPTD OCCUP OVEREXP TO SOLV
W/PERMANENT BRAIN & NERV SYS DAMAGE. PRLNG/RPTD CNTCT OF 1,1,1-
TRICHLOROETHANE & TOLUENE W/SKIN CAN CAUSE DEFATTING OF THE SKIN
LEADING TO DERMATITIS. 1,1 ,1-TRICHLOROETHANE HAS BEEN FOUND TO
CAUSE LIVER ABNORMALITIES, KIDNEY DAMAGE, & LUNG DAMAGE IN LAB
ANIMALS. (SUPP DATA)
Medical Cond Aggravated by Exposure:1,1,1-TRICHLOROETHANE MAY AGGRAVATE
ACUTE AND CHRONIC LIVER DISEASE AND RHYTHM DISORDERS OF THE HEART.
* First Aid Measures *
CONTACT A PHYSICIAN IMMEDIATELY. SKIN: WASH IMMEDIATELY WITH SOAP
AND WATER. INHAL: REMOVE TO FRESH AIR. CONTACT A PHYSICIAN
IMMEDIATELY. IN GEST: DO NOT INDUCE VOMITING. CONTACT APHYSICIAN OR
REGIONAL POISON CONTROL CENTER IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL OR WATER FOG.
Fire Fighting Procedures:NIOSH/MSHA APPROVED PRESSURE DEMAND SCBA AND
FULL PROT EQUIP IS REC TO PROTECT FROM COMBUSTION PRODUCTS. COOL
EXPOSED CONTAINERS WITH WATER.
Unusual Fire/Explosion Hazard:CNTNRS MAY EXPLO IF EXPOS TO EXTREME
HEAT. ELIM SOURCES OF IGNIT: HEAT/ELEC EQUIP/SPARKS & FLAMES. DO
NOT PUT IN CONTACT W/OXIDIZING/CAUSTIC MATLS. (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBENT MATERIAL OR SCRAPE UP DRIED
MATERIAL AND PLACE INTO CONTAINERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CNTNRS AWAY FROM EXCESS HEAT &
FREEZING. KEEP CNTNRS TIGHLY CLOSED WHN NOT IN USE. KEEP OUT OF
Other Precautions:INTENTIONAL MISUSE BY DELIB CONC & INHAL VAPS MAY BE
HARMFUL/FATAL. NO SMOKING IN AREA OF USE. DO NOT USE IN GEN VICIN
OF ARC WELD/OPEN FLAMES/HOT SURF. HEAT &/OR UV RADIA MAY CAUSE
FORMATION OF HCL A ND/OR PHOSGENE . (ING 7)
* Physical/Chemical Properties *
HCC:F5
Vapor Density:> 1.0
Evaporation Rate & Reference:> 1 (N-BUTYL ACETATE)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:TAN PASTE WITH HYDROCARBON ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS AND CAUSTICS.
Stability Condition to Avoid:EXCESSIVE HEAT.
Hazardous Decomposition Products:NORMAL COMBUSTION PRODUCTS, I.E. COX,
NOX. HCL AND PHOSGENE .
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF ACCORDING TO FEDERAL, STATE, AND
LOCAL REGULATIONS. DISCARDED MATERIAL SHOULD BE INCINERATED AT A
PERMITTED FACILITY. DO NOT REUSE EMPTY CONTAINERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SELECT APPROPRIATE NIOSH/MSHA APPROVED
RESPIRATOR (E.G., DUST AND FUME RESP, ETC) BASED ON ACTUAL OR
POTENTIAL AIRBORNE CONTAMINANTS & THEIR CONCENTRATIONS PRESENT.
Ventilation:USE W/ADEQ VENT TO MEET EXPOS LMTS LISTED. WHERE EXPOS LMT
IS/MAY BE EXCEEDED, USE NIOSH/MSHA APPRVD RESP PROT.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
HAZ DECOMP PROD: HEAT GENERATION. W/ACIDS & ALKALIS: GENERATES
HYDROGEN. W/HALOGENATED CMPDS: CAN REACT VIOLENTLY WITH FINELY
DIVIDED ALUMINUM. OTHER PRECS: OF THE INGOT ON FURNACE SILLS, IF
THEY ARE SUITABLE FOR THAT PURPOSE. 4. PERFORM FURNACE CHARGING
SEQUENCE IN SUCH A WAY THAT SUBMERGENCE OF REMELT (ING 6)
* Product Identification *
Product ID:CASTING INGOT, 5XX.X
Preparer's Name:HAZ MATLS CTL COMMITTEE
* Composition/Information on Ingredients *
Ingred Name:IRON. TLV AS IRON OXIDE FUME. PEL AS IRON OXIDE DUST.
ACGIH TLV:5 MG/M3
Ingred Name:MAGNESIUM
Ingred Name:ZINC
Ingred Name:ALUMINUM
Ingred Name:SUPP DATA: INGOT IN MOLTEN ALUMINUM IS AVOIDED.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ALUMINUM DUST/FINES & FUMES ARE A LOW
HEALTH RISK BY INHAL. FOR STD OPS (E.G.,MILLING, CUTTING, GRINDING)
AL SHOULD BE TREATED AS A NUISANCE DUST & IS SO DEFINED BY ACGIH.
PLASMA ARC CUTTING/WELDING A LUMINUM CAN GENERATE OZONE. OVEREXP TO
OZONE CAN RESULT IN MUC MEMB IRRIT, AS WELL AS PULM CHANGES (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: INCLUDING IRRITATION, CONGESTION AND
EDEMA. REFER TO ORIGINAL MSDS FOR SPECIFIC HAZARDS OF INDIVIDUAL
INGREDIENTS .
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: IF IRRIT OR PULMONARY SYMPS DEVELOP, CONSULT MD. SKIN:
IF IRRITATION DEVELOPS CONSULT MD. EYES: IMMED FLUSH WITH POTABLE
LY .
* Fire Fighting Measures *
Extinguishing Media:USE CLASS D EXTINGUISHING AGENTS ON SMALL CHIPS OR
FINES. USE COARSE WATER SPRAY ON CHIPS, TURNINGS, ETC.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DUST CLOUDS MAY BE EXPLOSIVE. PREVENT
FORMATION OF DUST CLOUD. MOLTEN AL MAY EXPLODE ON CONTACT W/WATER.
* Accidental Release Measures *
Spill Release Procedures:COLLECT SCRAP FOR REMELTING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:1. INSPECT ALL REMELT INGOT PRIOR TO
FURNACE CHARGING & REMOVE SURF CONTAM(SUCH AS ICE/SNOW/DEPOSITS OF
GREASE/OIL/OTHER SURF CONTAM RSLTG FROM STOR.
Other Precautions:2. STORE INGOT IN DRY, HEATED AREAS W/ANY
CRACKS/CAVITIES POINTED DOWNWARDS. 3. PREHEAT & DRY INGOT
ADEQUATELY BEFORE CHARGING IT INTO A FURNACE. THIS IS TYPICALLY
DONE BY USE OF OVENS, HOMOGENIZING F URNACES, GAS
FLAME/PLACEMENT(SUPP DATA)
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NONE
Appearance and Odor:SILVERY SOLID W/NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS VIOLENTLY W/WATER, RUST, METAL OXIDES (CU, FE, PB) &
NITRATES/FERTILIZERS CONTAINING AMMONIUM NITRATE.
Stability Condition to Avoid:MOISTURE & CONTAMINATION ON OR IN REMELT
INGOT.
Hazardous Decomposition Products:W/WATER: HYDROGEN & HEAT SLOWLY.
W/HEAT: OXIDIZES AT TEMP-DEPEND RATE. W/STRONG OXIDIZERS: VIOLENT
RXN W/MUCH(SUPP DATA)
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE &
LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOS LIMIT IS EXCEEDED, A NIOSH APPRVD
HALF-FACE HIGH EFFICIENCY DUST/MIST RESP MAY BE WORN FOR UP TO TEN
TIMES EXPOS LIMIT/MAX USE CONC SPECIFIED BY APPROP REGULATORY
AGENCY/RESP SUPPLIER, WHICHE VER IS LOWEST. NIOSH APPRVD FULL-FACE
EXPOS LIMIT/MAX USE CONC SPECIFIED BY APPROP (SUPDAT)
Ventilation:SYS OF LOC &/GEN EXHST IS RECOMD TO KEEP EMPLOYEE EXPOS
BELOW THE AIRBORNE EXPOS LIM. LOC EXHST VENT IS GENRLY PERFERRED
BECAUSE IT CAN CNTRL (OTHER INFO)
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCLUDING BOOTS,
LAB COAT, APRON OR COVERALLS, AS APPROPRIATE, TO PREVENT SKIN
CONTCT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP: HYPERTENSION & GRAY FACIAL COLOR MAY ALSO BE NOTED.
RESP PROT: REGULATORY AGENCY/RESP SUPPLIER, WHICHEVER IS LOWEST.
FOR EMER/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE A FULL-F
ACEPIECE POS-PRESS, AIR SUPPLIED RESP. WARNING: AIR-PURIFYING RESP
DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENT ATMS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ACETIC ACID LEAD SALT (2:1); (LEAD ACETATE)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: LEAD CAN BE ABSORBED
THROUGH RESP SYS. LOCAL IRRIT OF BRONCHIA & LUNGS CAN OCCUR &, IN
CASES OF ACUTE EXPOS, SYMPS SUCH AS METALLIC TASTE, CHEST &
ADOMINAL PAIN, & INCRD LEAD BLOOD LEVEL S MAY FOLLOW. SEE ALSO
INGEST. INGEST: POISON! SYMPS OF LEAD POISONING INCLUDE ABDOM PAIN
& SPASMS, NAUSEA, VOMIT, HDCH, ACUTE POISONING CAN LEAD TO MUSCLE
WEAK, "LEAD LINE" ON GUMS, METALLIC TASTE, D EFINED LOSS OF
APPETITE, INSOMNIA, DIZZ, HIGH LEAD LEVELS IN BLOOD & URINE
W/SHOCK, COMA & DEATH IN EXTREME CASES. SKIN CONTACT: LEAD & LEAD
COMPOUNDS MAY BE ABSORBED THROUGH SKIN ON PRLNGD EXPOS; SYM P OF
LEAD POISONING (EFTS OF OVEREXP)
Explanation of Carcinogenicity:LEAD ACETATE: IARC GROUP 2B, SUPPLEMENT
Effects of Overexposure:HLTH HAZ: DESCRIBED FOR INGEST EXPOSURE MAY
OCCUR. CONTACT OVER SHORT PERIODS MAY CAUSE LOCAL IRRIT, REDNESS &
PAIN. EYE CONTACT: ABSORPTION CAN OCCUR THROUGH EYE TISSUES BUT
MORE COMMON HAZ ARE LOCAL IRRIT/ABRASION. CHRONIC: LEAD APPEARS ON
NAVY LISTING OF OCCUPATIONAL CHEM REPROD HAZ. SEEK CONSULTATION
FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO &
SAFE HANDLING & EXPOS INFO (F P N). LEAD IS A CUMMULATIVE POISON &
EXPOS EVEN TO SMALL AMTS CAN RAISE BODY'S CONTENT TO TOX LEVELS.
SYMPS OF CHRONIC EXPOS ARE LIKE THOSE OF INGEST POISONING;
RESTLESSNESS, IRRITABILITY, VISUAL DIST URBANCES, (SUPDAT)
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING KIDNEY,
NERVE OR CIRCULATORY DISORDERS OR WITH SKIN OR EYE PROBLEMS MAY BE
SUSCEPTIBLE TO THE EFFECTS OF THIS SUBSTANCE.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL
ATTENTION. INGEST: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY
MEDICAL PER SONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS
PERSON. GET MEDICAL ATTENTION. SKIN CONTACT: IMMEDIATELY FLUSH
CLOTHING & SHOES . GET MEDICAL ATTENTION. WASH CLOTHING BEFORE
REUSE. THROUGHLY CLEAN SHOES BEFORE REUSE. EYE CONTACT: IMMEDIATELY
EYELIDS OCCASIONALLY . GET MEDICAL ATTENTION IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE. DO NOT ALLOW WATER RUNOFF TO ENTER SEWERS OR
WATERWAYS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . LEAD ACETATE CAN PRODUCE ACETIC ACID, CARBON MONOXIDE,
AND TOXIC FUMES OF LEAD OXIDE IN FIRE SITUATION. NFPA RATINGS:
HEALTH: 3, FLAMMABILI TY: 1, REACTIVITY: 0.
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD
OR FIRE HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENT AREA OF LEAK/SPILL. WEAR APPROP PERSONAL
PROT EQUIP AS SPECIFIED IN SECTION 8. SPILLS: SWEEP UP &
CONTAINERIZE FOR RECLAMATION/DISPOSAL. VACUUMING/WET SWEEPING MAY
BE USED TO AVOID DUST DISPERSAL . US REGULATIONS (CERCLA) REQUIRE
REPORTING SPILLS AND RELEASES TO SOIL, WATER & AIR IN EXCESS OF
REPORTABLE QUANTITIES. TOLL FREE NUMBER FOR US COAST GUARD NATIONAL
*Handling and Storage *
Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CNTNR, STORED
IN COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DMG.
ISOLATE FROM INCOMPATIBLE SUBSTANCES, AREAS IN WHICH EXPOS TO LEAD
METAL/LEAD COMPONDS MAY OCCUR SHOUL D BE IDENTIFIED BY SIGNS/APPROP
MEANS, & ACCESS TO AREA SHOULD BE LIMITED TO AUTHORIZED PERSONS.
Other Precautions:CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
EMPTY SINCE THEY RETAIN PRODUCT RESIDUE (DUST, SOLIDS); OBSERVE ALL
WARNINGS AND PRECAUTIONS LISTED FOR PRODUCT.
* Physical/Chemical Properties *
B.P. Text:DECOMPOSES
Vapor Pres:(MM HG): NO INFO FOUND
Vapor Density:NO INFO
pH:5.5-6.5
Evaporation Rate & Reference:(BUAC=1) NO INFO FOUND
Appearance and Odor:WHITE CRYSTALLINE GRANULES; SLIGHT ACETIC ACID
ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BROMATES, PHENOL, CHLORAL HYDRATE, SULFIDE, HYDROGEN PEROXIDE,
RESORCINOL, SALICYLIC ACID, SULFITES, VEGETABLE INFUSIONS, ALKALIS,
TANNIN, PHOSPHATES, CITRATES, CHLORIDES, CARBONATES, TARTRATES AND
ACIDS.
Stability Condition to Avoid:HEAT, FLAMES, IGNITION SOURCES AND
INCOMPATIBLES. STABLE UNDER NORMAL CONDITIONS OF USE AND STORAGE.
READILY ABSORBS CO*2 FROM THE AIR.
Hazardous Decomposition Products:TOXIC FUMES OF LEAD OR LEAD OXIDE AND
CARBON MONOXIDE MAY BE RELEASED WHEN HEATED TO DECOMPOSITION.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Toxicological Information*
(TRIHYDRATE FORM).INVESTIGATED AS A TUMORIGEN, MUTAGEN,
REPRODUCTIVE EFFECTOR. REPRODUCTIVE TOX: LEAD AND OTHER SMELTER
EMISSIONS ARE HUMAN REPRODUCTIVE HAZARDS. (CHEMICAL COUNCIL ON
ENVIRONMENTAL QUALITY; CHEMICAL HAZARDS TO HUMAN REPRODUCTION,
* Ecological Information *
Ecological:ENVIRONMENTAL FATE: WHEN RELEASED INTO SOIL, THIS MATERIAL
IS NOT EXPECTED TO LEACH INTO GROUNDWATER. THIS MATERIAL MAY
BIOACCUMULATE TO SOME EXTENT. ENVIRONMENTAL TOXICITY. NO
INFORMATION FOUND.
* Disposal Considerations *
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
SHOULD BE HANDLED AS HAZS WASTE & SENT TO A RCRA APPRVD WASTE
FACILITY. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE
MANAGEMENT OPTIONS. STATE & LOCAL DISPOSAL REGS MAY DIFFER FROM
FEDERAL DISPOSAL REGS. DISPOSE OF CONTAINER & UNUSED CONTENTS I
/A/W/FED, STATE & LOCAL REQUIREMENTS.
* MSDS Transport Information *
Transport Information:DOMESTIC (LAND, DOT): PROPER SHIPPING NAME: RQ,
IMO): PROPER SHI PPING NAME: LEAD ACETATE, HAZARD CLASS: 6.1,
* Regulatory Information *
NO PRESSURE: NO REACTIVITY: NO (MIXTURE/SOLID)
Federal Regulatory Information:WHMIS: THIS MSDS HAS BEEN PREPARED
ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PRODUCTS
REGULATIONS (CPR) AND THE MSDS CONTAINS ALL OF THE INFORMATION
REQUIRED BY THE CPR.
KNOWN TO STATE OF CA TO CAUSE CANCER & BIRTH DEFECTS/OTHER REPOD
HARM:
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS DO NOT MAINTAIN AIRBORNE
CONCENTRATIONS BELOW RECOMMENDED EXPOSURE LIMITS, AN APPROVED
RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ORGANIC VAPOR. IF
RESPIRATORS ARE USED, A PROGR AM SHOULD BE INSTITUTED.
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
KEY1:C4. REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
Ingred Name:ETHANOL, 2,2',2"-NITRILOTRI-; (TRIETHANOLAMINE)
Other REC Limits:NONE RECOMMENDED
ACGIH TLV:5 MG/M3
Ingred Name:DIETHYLHYDROXYLAMINE
Other REC Limits:NONE RECOMMENDED
Ingred Name:STILBENE SULFONIC ACID DERIVATIVE
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM CHLORIDE
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:BASED ON ANIMAL DATA, MAY CAUSE
ADVERSE EFFECTS ON THE KIDNEY/LIVER. MAY BE HARMFUL IF INHALED. EYE
CONTACT CAUSES IRRITATION. SKIN CONTACT CAUSES IRRITATION. HARMFUL
IF ABSORBED THROUGH THE SKIN. HAR MFUL IF SWALLOWED.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:KIDNEY/LIVER EFFECTS, EYE IRRITATION, SKIN
IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMMEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: INDUCE VOMITING AS DIRECTED BY MEDICAL PERSONNEL. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL PHYSICIAN OR
POISON CONTROL ASAP.
* Fire Fighting Measures *
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL TANKS AND
CONTAINERS EXPOSED TO FIRE WITH WATER.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS. ELEVATED TEMPERATURES CAN CAUSE
DECOMPOSITION.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. NEUTRALIZE
PRIOR TO DISPOSAL. FLUSH TO SEWER WITH LARGE AMOUNTS OF WATER IF
ALLOWABLE. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE.
Neutralizing Agent:NEUTRALIZATION AND SEWERING MAY NOT BE ALLOWED IN
SOME STATES AND MUNICIPALITIES
*Handling and Storage *
Handling and Storage Precautions:AVOID PROLONGED OR REPEATED BREATHING
OF MIST OR VAPOR. AVOID CONTACT WITH EYES, SKIN AND CLOTHING. USE
WITH ADEQUATE VENTILATION.
Other Precautions:KEEP FROM CONTACT WITH OXIDIZING MATERIALS. KEEP AWAY
FROM HEAT AND FLAME. KEEP CONTAINER CLOSED. STORE IN A COOL PLACE.
* Physical/Chemical Properties *
HCC:C2
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Density:0.6
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT YELLOW LIQUID, SLIGHT AMINE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF NITROGEN
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. MAY REQUIRE NEUTRALIZATION IF PH
FEDERAL, STATE ANDLOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Preparer Co. when other than Responsible Party Co.
*
*
Contractor Summary
*
*
Ingredients
*
------------------------------
-----------------------------
ACGIH TLV: 5 MG/CUM
------------------------------
------------------------------
------------------------------
ACGIH TLV: SIMPLE ASPHYXIANT
------------------------------
------------------------------
Ozone Depleting Chemical: 1
------------------------------
PETROLEUM DISTILLATES, MINERAL OIL (SEVERE)
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY IRRITATION.
INGESTION: ASPIRATION HAZARD. HIGH CONCENTRATIONS MAY CAUSE LUNG,
LIVER/KIDNEY DAMAGE. 2-BUTOXYETHANOL MAY CAUSE CORNEAL INJURY, BLOOD ABNORM
ALITIES. MAY BE ABSORBED THROUGH THE SKIN W/TOXIC EFFECTS & MAY CAUSE
DAMAGE TO SPLEEN & TESTES.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, DIZZINESS, NARCOSIS, CARDIAC
ABNORMALITIES, NASAL & BRAIN DAMAGE.
Medical Cond Aggravated By Exposure: HEART DISEASE, RESPIRATORY DISORDERS.
TOLUENE: CNS DISEASES & ALCOHOLISM.
First Aid: INGESTION: DON'T INDUCE VOMITING. KEEP CALM. GASTRIC LAVAGE.
INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN IF NEEDED. SKIN: WASH W/SOAP
ALL CASES. NEVER ADMINISTER ADRENALIN FOLLOWING OVEREXPOSURE.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE IGNITION SOURCES. MAINTAIN ADEQUATE
VENTILATION. SOAK UP IN AN INERT ABSORBENT & STORE IN A CLOSED CONTAINER
UNTIL DISPOSAL.
Waste Disposal Methods: DON'T PUNCTURE/INCINERATE CANS. GIVE CANS TO LICENSED
Handling And Storage Precautions: STORE AWAY FROM HEAT & OTHER IGNITION
APPROVED RESPIRATOR.
Other Precautions: AVOID BREATHING VAPORS & CONTACT W/EYES, SKIN/CLOTHING.
DON'T SMOKE WHILE USING.
*
Fire and Explosion Hazard Information
*
Flash Point Method: TCC
Lower Limits: 1.8
Upper Limits: 9.5
Extinguishing Media: CO2, WATER FOG, DRY CHEMICAL.
Unusual Fire/Explosion Hazard: HEATED CANS MAY RUPTURE.
*
*
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation: LOCAL EXHAUST VENTILATION TO MAINTAIN VAPOR CONCENTRATIONS
<TLVS. USE SCBA WHEN CONCENTRATIONS EXCEED TLVS.
Other Protective Equipment: LONG SLEEVES, LONG PANTS.
*
Physical/Chemical Properties
*
Vapor Density: 4
Spec Gravity: 0.8
Evaporation Rate & Reference: FASTER THAN BU AC
Solubility in Water: NEGLIGIBLE
Appearance and Odor: PURPLE LIQUID W/SOLVENT ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: HEAT, SPARKS, OPEN FLAMES & OTHER IGNITION
Materials To Avoid: STRONG OXIDIZERS, ACTIVE METALS, STRONG ALKALIES, REACTIVE
METALS, ZINC, SODIUM, POTASSIUM.
Hazardous Decomposition Products: FIRE/THERMAL: CO2, WATER, HALOGEN ACIDS,
PHOSGENE.
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: LOCTITE CORP
Label Required IND: Y
Status Code: A
Origination Code: G
Hazard And Precautions: SKIN/EYES: IRRITATION. INHALATION: RESPIRATORY
IRRITATION. INGESTION: ASPIRATION HAZARD. HIGH CONCENTRATIONS MAY CAUSE LUNG,
LIVER/KIDNEY DAMAGE. 2-BUTOXYETHANOL MAY CAUSE CORNEAL INJURY, BLOOD ABNORM
ALITIES. MAY BE ABSORBED THROUGH THE SKIN W/TOXIC EFFECTS & MAY CAUSE
DAMAGE TO SPLEEN & TESTES.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHEN RESPIRATORS ARE REQUIRED, SELECT NIOSH/MSHA
APPROVED EQUIPMENT BASED BASED ON ACTUAL OR POTENTIAL AIRBORNE
CONCENTRATIONS AND IN ACCORDANCE WITH LATEST OSHA STANDARD.
Ventilation:GENERAL AREA DILUTION/EXHAUST VENTILATION RECOMMENDED.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
DO NOT STORE, USE OR CONSUME FOODS, BEVERAGES, TOBACCO PRODUCTS OR
COSMETICS IN AREAS WHERE THIS MATERIAL IS STORED. WASAH HANDS AND
FACE CAREFULLY BEFORE EATING, DRINKING, USING TOBACCO, APPLYING CO
SMETICS OR USING THE TOILET.
* Product Identification *
CAGE:0A5D1
CAGE:0A5D1
CAGE:0PGK2
* Composition/Information on Ingredients *
Ingred Name:POLY (DIMETHYLSILOXANE)
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THIS IS A VISCOUS FLUID THAT DOES NOT
EASILY FORM A MIST OR VAPOR AND THEREFORE INHALATION HAZARDS ARE
MINIMAL. PRODUCT NON-IRRITATING TO EYES AND SKIN. LOW ACUTE ORAL
TOXICITY. LOW ACUTE DERMAL TOXIC ITY.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:UNDER CERTAIN CONDITIONS THIS PRODUCT MAY
GENERATE FORMALDEHYDE AS A BYPRODUCT OF OXIDATIVE THERNAL
DECOMPOSITION. FORMALDEHYDE IS LISTED AS A POTENTIAL HUMAN
CARCINOGEN BY IARC, OSHA AND ACGIH.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED CLOTHING.
WASH WITH SOAP AND WATER. IF IRRITATION PERSIST, GET MEDICAL
ATTENTION. INH ALATION: REMOVE TO FRESH AIR. RESTORE BREATHING. GET
MEDICAL ATTENTION. INGESTION: IF CONSCIOUS, GIVE 1-2 GLASSES OF
WATER TO DRINK. DO NOT GIVE ANYTHING BY MOUTH IF UNCONSCIOUS. SEEK
MEDICAL ATTN.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD WEAR SELF CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE GEAR. COOL TANKS AND
CONTAINERS EXPOSED TO FIRE WITH WATER.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:ABSORB WITH AN INERT ABSORBENT. SCRAPE UP AND
PLACE IN APPROPRIATE CLOSED CONTAINER. CLEAN UP RESIDUAL MATERIAL
WITH AN APPROPRIATE SOLVENT LIKE PAINT THINNER OR MINERAL SPIRITS,
PROVIDED THERE IS GOO D VENTILATION AND NO IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
PROLONGED CONTACT WITH SKIN AND EYES. SPILLED MATERIAL MAY MAAKE
FLOOR SLIPPERY.
Other Precautions:DO NOT LEAVE TRACES OF PRODUCT ON FLOORS, LADDERS,
ETC. DO NOT FLUSH TO DRAIN. STORE IN TIGHTLY CLOSED CONTAINERS.
STORE IN AN AREA THAT IS DRY, WELL-VENTILATTED, AWAY FROM IGNITION
SOURCES, AWAY FROMINCOMPATIBLES.
* Physical/Chemical Properties *
HCC:V6
Boiling Pt:B.P. Text:NOT GIVEN
Vapor Density:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, VISCOUS LIQUID, ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG OXIDIZING MATERIALS, STRONG BASES.
Stability Condition to Avoid:AVOID HEAT, SPARK AND OPEN FLAME.
Hazardous Decomposition Products:DIMETHYLCYCLOSILOXANES,
METHYLPHENYLCYCLOSILOXANES, FORMALDEHYDE
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Cage: 0FTT5
*
Preparer Co. when other than Responsible Party Co.
*
Cage: 0FTT5
*
Contractor Summary
*
Cage: 0FTT5
*
Item Description Information
*
Item Manager: GSA
Item Name: ENAMEL
Unit of Issue: PT
UI Container Qty: 0
*
Ingredients
*
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE RECOMMENDED
------------------------------
Other REC Limits: NONE RECOMMENDED
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CONCENTRATING & INHALING CONTENTS HARMFUL OR FATAL.
REPEATED/PROLONGED OVEREXPOSURE ASSOCIATED WITH PERMANENT BRAIN & NERVOUS
SYSTEM DAMAGE. IN CONFINED AREA, HIGH CONCENTRATION ARE ANESTHETIC. SKIN
& RESPIRATORY TRACT IRRITATION. LIGHT HEADED, STAGGERING, GIDDINESS,
NAUSEA. HARMFUL IF SWALLOWED. SEVERE EYE IRRITATION.
Signs And Symptions Of Overexposure: IRRITATION TO EYES, THROAT, AND
RESPIRATORY TRACT. MAY CAUSE HEADACHES, NAUSEA, AND VOMITING.
Medical Cond Aggravated By Exposure: RESPIRATORY AILMENTS.
First Aid: FOR CONTACT WITH SKIN OR CLOTHES, WASH WITH SOAP & WATER; WASH
& CONTACT PHYSICIAN/OPHTHALMOLOGIST IMMEDIATELY. IF SWALLOWE D, DO NOT
INDUCE VOMITING. GET IMMEDIATE MEDICAL AID. IF INHALED, REMOVE TO FRESH AIR.
GIVE ARTIFICIAL RESPIRATION IF NECESSARY & GET MEDICAL AID. NEVER GIVE
ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION AND VENTILATE AREA.
MOP SPILLS WITH INERT ABSORBENT. AVOID BREATHING VAPORS.
Waste Disposal Methods: DISPOSE IN ACCORD WITH FEDERAL, STATE, LOCAL
HEAT OR PROLONGED EXPOSURE TO SUN MAY CAUSE CAN TO BURST. DISCARD EMPTY CAN
IN TR ASH PICK-UP. DO NOT PLACE IN HOME TRASHCOMPACTOR.
Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. CONTENTS UNDER
SPRAY, MIST, OR VAPORS.
Other Precautions: AVOID CONTACT WITH EYES AND SKIN. USE WITH GOOD VENTILATION.
READ ENTIRE LABEL BEFORE USING. FOLLOW ALL LABEL DIRECTIONS. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING AND INHALING OR SWALLOWING CO NTENTS MAY
BE HARMFUL OR FATAL.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NR
Lower Limits: 1.8
Upper Limits: 9.5
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, SAND, WATER SPRAY
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE, USE TO COOL FIRE EXPOSED
CONTAINERS. WEAR SCBA. USE SHIELDING TO PROTECT PERSONNEL FROM BURSTING,
RUPTURING OR VENTING OF CONTAINERS.
Unusual Fire/Explosion Hazard: DO NOT SPRAY NEAR OPEN FLAME. AT ELEVATED
*
*
Respiratory Protection: NONE BELOW TLV. USE NIOSH/MSHA APPROVED MASK ABOVE TLV.
Ventilation: LOCAL EXHAUST: PREFERRED. MECHANICAL (GENERAL): ACCEPTABLE AT
POINT OF MIST OR SPRAY RELEASE.
Other Protective Equipment: IMPERVIOUS CLOTHES TO PROTECT SKIN. EYE WASH
STATION.
Work Hygienic Practices: USE GOOD PERSONAL HYGIENE. DO NOT EAT, DRINK, OR SMOKE
WHILE USING PRODUCT.
*
Physical/Chemical Properties
*
HCC: V3
Vapor Density: >1.5
Solubility in Water: INSOLUBLE
Appearance and Odor: GRAY / PAINT
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT
Hazardous Decomposition Products: CARBON MONOXIDE AND POSSIBLE HYDROGEN
CHLORIDE
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: PT
Container QTY: 0
*
Detail DOT Information
*
DOT PSN Code: DTJ
Symbols: D
DOT Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
Label: NONE
Bulk Pack: NONE
Vessel Stow Req: A
*
Detail IMO Information
*
IMO PSN Code: AKH
IMO Proper Shipping Name: AEROSOLS/AEROSOL PRODUCT ?
UN Hazard Class: 9?
IMO Packaging Group: -
Subsidiary Risk Label: -
*
Detail IATA Information
*
IATA PSN Code: ALS
IATA Proper Shipping Name: AEROSOLS, FLAMMABLE
IATA PSN Modifier: (EACH NOT EXCEEDING 1 L CAPACITY)
IATA UN Class: 2.1
IATA Label: FLAMMABLE GAS
*
Detail AFI Information
*
AFI PSN Code: ALR
AFI Symbols: *
AFI Proper Shipping Name: AEROSOLS, FLAMMABLE, N.O.S.
AFI PSN Modifier: (EACH NOT EXCEEDING 1L CAPACITY)
AFI Hazard Class: 2.1
Special Provisions: P4
Back Pack Reference: A6.3
*
HAZCOM Label
*
Cage: 0FTT5
Company Name: LHB INDUSTRIES
Label Required IND: Y
Status Code: C
Origination Code: G
Hazard And Precautions: CONCENTRATING & INHALING CONTENTS HARMFUL OR FATAL.
REPEATED/PROLONGED OVEREXPOSURE ASSOCIATED WITH PERMANENT BRAIN & NERVOUS
SYSTEM DAMAGE. IN CONFINED AREA, HIGH CONCENTRATION ARE ANESTHETIC. SKIN
& RESPIRATORY TRACT IRRITATION. LIGHT HEADED, STAGGERING, GIDDINESS,
NAUSEA. HARMFUL IF SWALLOWED. SEVERE EYE IRRITATION.IRRITATION TO EYES,
THROAT, AND RESPIRATORY TRACT. MAY CAUSE HEADACHES, NAUSEA, AND VOMITING.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR IF EXPOSURE EXCEEDS
THE PERMISSIBLE EXPOSURE LIMIT (PEL).
Ventilation:SUFFICIENT TO KEEP EXPOSURE BELOW THE PEL, GENERAL ROOM AIR
CIRCULATION SUFFICIENT FOR NORMAL USE OF PRODUCT.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MATLS TO AVOID: CROTONALDEHYDE, OXIDANTS, PHOSGENE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SULFURIC ACID, MONODODECYL ESTER, SODIUM SALT; (DODECYL
SULFATE, SODIUM SALT)
Fraction by Wt: 2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:DIPROPYLENE GLYCOL, MONOMETHYL ETHER
Fraction by Wt: 2%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHALATION: IRRITATION, CENTRAL
NERVOUS SYSTEM DEPRESSION. SKIN CONTACT: DEFATTING, DERMATITIS
POSSIBLE. INGESTION: NAUSEA, VOMITING, HEADACHE, DIZZINESS, COMA
POSSIBLE, ABDOMINAL PAIN, VOMITIN G, DIARRHEA. CHRONIC: NONE LISTED
BY MANUFACTURER.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NOT APPLICABLE.
* First Aid Measures *
First Aid:INHALATION: MOVE TO FRESH AIR, GET MEDICAL HELP. SKIN
CONTACT: WASH WITH SOAP AND WATER. INGESTION: GASTRIC LAVAGE, GIVE
FLUIDS, GET MEDICAL HELP. EYE CONTACT: FLUSH WITH WATER FOR AT
* Fire Fighting Measures *
Flash Point Method:OC
Extinguishing Media:CO*2, FOAM, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:REMOVE SOURCES OF IGNITION, ABSORB WITH
VERMICULITE.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
PLACE.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Spec Gravity:1.0
Evaporation Rate & Reference:<1
Solubility in Water:SOLUBLE
Appearance and Odor:PURPLE LIQUID, ODOR OF RUBBING ALCOHOL.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HYDROGEN & PALLADIUM, NITROFORM, OLEUM, POTASSIUM-TERT-BUTOXIDE,
ALUMINUM, ALUMINUM ISOPROPOXIDE, (SUPDAT)
Stability Condition to Avoid:SOURCES OF IGNITION, HEAT, OPEN FLAME.
Hazardous Decomposition Products:CO, CO*2, SIO*2.
* Disposal Considerations *
Waste Disposal Methods:AS PER LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:MECH RESPIRAT TO REMOV OVERSPRAY IN OUTDOOR OR
OPEN AREA.
Ventilation:PROVID GEN DILUT/LOC EXHAUS VENTIL IN VOL TO KP BELOW TLV.
Other Protective Equipment:USE PROTECTIV EQPMT TO PREVENT SKIN CONTACT
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ISOBUTYL ALCOHOL (SARA III)
Fraction by Wt: <5%
Ingred Name:ISOBUTYL ACETATE
Ingred Name:TOLUENE (SARA III)
Fraction by Wt: 8%
Ingred Name:METHYL ISOBUTYL KETONE (HEXONE) (SARA III)
Fraction by Wt: <0.5%
Other REC Limits:NONE RECOMMENDED
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Fraction by Wt: <0.5%
* Hazards Identification *
Effects of Overexposure:INHAL:ANEST:IRRIT OF NOSE, THROAT,EYES & POSS
DIZZ & NAUSEA.
* First Aid Measures *
First Aid:INHAL:REMOV FR EXPOS & PROVD FRESH AIR.SPLASH EYES,FLUSH
WASH AFFECT AREA W/WATR.INGEST:DO NOT INDUC VOMITING.CONSULT A
PHYSICIAN IMM ED IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:CO*2,DRY CHEM,OR ALCOH FOAM.POLYMER FOAM IS PREF
F/LG FIRES
Fire Fighting Procedures:SELF-CONTAIN BREATHING APPARATUS SHLD BE AVAIL
F/FIREMEN.
Unusual Fire/Explosion Hazard:KP CONTNRS TIGHTLY CLOS & ISOLAT FR
HEAT,ELECTR EQPMT,SPARKS & OPN FLAM.DO NOT APLY TO VERY HOT SURF
* Accidental Release Measures *
Spill Release Procedures:REMOV ALL SOURCES OF IGNIT(FLAMES,HOT
SURFACES,& ELECTR,STATIC OR FRICTIONAL SPARKS.VENTILAT AREA & AVOID
BREATHING VAPORS.REMOV W/INERT ABSORBENT & USE NON-SPARKING
TOOLS.STEPS MUST BE TAKEN TO AVOIDCONTAM OF GROUND WATER OR
STREAMS.
*Handling and Storage *
EA OTHR & GROUNDED PROPLY TRANSF/POUR IN ANOTHER
Other Precautions:DO NOT CUT OR WELD ON EMPTY CONTNRS DO NOT USE UNTIL
ALL SAFETY PRECAUTIONS & MIXING DIRECTIONS HAVE BEEN READ & FULLY
UNDERSTOOD BY THE USER.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:HEAV
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG ACIDS OR ALKALIS.
Stability Condition to Avoid:FIRES,HEAT,SPARKS, & HOT SURFACES
Hazardous Decomposition Products:SMOKE & OXIDES OF NITROGEN
Conditions to Avoid Polymerization:DO NOT AD DRIERS OR REACTIVE CHEM
W/O TECH SUPERVISION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/LOC,STATE, & FEDERAL
REGULATIONS.INCINERATE IN EPA APPRVD FACILITY.DO NOT INCINERATE
CLOSED CONTAINERS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: NO
Effects of Exposure: INHAL:CAUTION! MAY CAUSE IRRITATION TO UPPER RESPIRATORY
TRACT. AVOID PROLONGED OR REPEATED INHALATION. EYE:CAUSES SEVERE IRRITATION
OR BURNS. MAY CAUSE PERMANENT VISUAL IMPAIRMENT. INGEST: DO NOT TAK E
INTERNALLY. MAY CAUSE GASTROINTESTINAL IRRITATION OR ULCERATION. MAY CAUSE
BURNS OF MOUTH & THROAT. (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: CRYSTALLINE SILICA QUARTZ:GROUP 2B (IARC);
ANTICIPATED TO BE A CARCINOGEN (NTP)
Signs And Symptions Of Overexposure: HLTH HAZ:SKIN:CAUSES SEVERE IRRITATION OR
BURNS. NOT CONSIDERED TOXIC BY ABSORPTION BUT PROLONGED EXPOSURE MAY CAUSE
ABSORPTION OF HARMFUL AMTS. CNTNS HAZ FILLERS WHICH ARE NOT HAZ IN WET/
ENCAPSULATE D STATE BUT IF FORMULA CONTAINING HAZ FILLER IS REDUCED TO RESP
FRACTION BY GRINDING/PUTTING INTO AIRBORNE (SUPP DATA)
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
UPPER/LOWER LIDS. GET MD IMMED. INGEST:DO NOT INDUCE VOMIT. GIVE LRG AMTS OF
WATER/MILK IF AVAIL & TAKE TO MD. SKIN:IMMED REMOVE CONTAM CLTHG /SHOES.
SOAP IF AVAIL OR FOLLOW BY WASHING W/SOAP & WATER. DO NOT REUSE CLTHG
UNTIL THORO CLEANED. CONTAM LEATHER (SUPP DATA)
*
Handling and Disposal
*
Spill Release Procedures: AVOID ALL PERSONAL CONTACT. CONTAIN SPILL IF
POSSIBLE. WIPE UP OR ABSORB ON SUITABLE MATERIAL AND SHOVEL UP. CLEAN UP WITH
SUITABLE VENTILATION.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: CONTROLLED INCINERATION OR BURY IN LEGAL LANDFILL.
HANDLE IN COMPLIANCE WITH LOCAL, STATE AND FEDERAL EPA REGULATIONS.
Handling And Storage Precautions: NONE SPECIFIED BY MANUFACTURER.
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
*
Fire and Explosion Hazard Information
*
Flash Point Method: PMCC
Extinguishing Media: WATER SPRAY, DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures: WEAR NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
*
*
Respiratory Protection: IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL OR
VENTILATION, WEAR NIOSH/MSHA APPROVED RESPIRATOR WHENEVER EXPOSED TO FUMES OR
Ventilation: LOCAL EXHAUST RECOMMENDED.
Other Protective Equipment: EMERGENCY EYE WASH AND DELUGE SHOWER (FP N).
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EFTS OF OVEREXP:POWDER, THE POWDER IS
CONSIDERED A HAZARDOUS MATERIAL. FIRST AIR PROC:ARTICLES, INCLUDING SHOES,
CANNOT BE DECONTAMINATED AND SHOULD BE DESTROYED.
*
Physical/Chemical Properties
*
HCC: V7
B.P. Text: NONE
Vapor Density: HVR/AIR
Appearance and Odor: LIQUID
Percent Volatiles by Volume: 0
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: ACIDS, OXIDIZING AGENTS, KETONES, ALDEHYDES, HALIDES.
Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
Additional Data: NOT REGULATED FOR TRANSPORTATION
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Company Name: HARDMAN INC
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Severe
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. AVOID ACIDS, OXIDIZERS, KETONES,
ALDEHYDES, HALIDES. ACUTE:CONTACT CAUSES SEVERE SKIN/EYE IRRITATION, BURNS,
MAY CAUSE PERMANENT VISUAL IMPAIRMENT. MAY BE ABSORBED BY SKIN IN TOXIC
AMOUNT S. INGESTION MAY CAUSE GI IRRITATION, ULCERATION, BURNS TO MOUTH &
THROAT. INHALATION MAY CAUSE UPPER RESPIRATORY TRACT IRRITATION. POWDERED
PRODUCT IS CONSIDERED HAZARDOUS. CHRONIC:CANCER HAZARD. CRY STALLINE SILICA
QUARTZ IS LISTED AS A CARCINOGEN.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE AN APPROPRIATE, PROPERLY FITTED RESPIRATOR
IF EXPOSURES EXCEED PEL/TLV VALUES.
Ventilation:EXPLOSION PROOF MECHANICAL EXHAUST: SUFFICIENT TO MAINTAIN
AIRBORNE CONCENTRATIONS < THEIR PEL/TLV VALUES.
Other Protective Equipment:CHEMICAL RESISTANT APRON & IMPERVIOUS
CLOTHING, EYE WASH FACILITIES & SAFETY SHOWER.
Supplemental Safety and Health
WASH HANDS & FACE THOROUGHLY AFTER HANDLING & BEFORE
EATING/DRINKING/SMOKING. LARGE SPILL CONT'D: SHUT OFF SOURCE OF
RELEASE W/O RISK OF INJURY. DIKE AREA TO CONTAIN & PREVENT RELEASES
TO SEWERS/OTHER WATERWAYS. COLLECT MATERIAL FOR SALVALGE/DISPOSAL.
PREVENT RUNOFF FROM ENTERING SEWER/OTHER WATERWAYS. B.P: HEPTANE.
* Product Identification *
Preparer's Name:DAVID HAAS
* Composition/Information on Ingredients *
Ingred Name:SILVER
ACGIH TLV:0.1 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:COPPER (DUST & MIST), BRONZE POWDER
Other REC Limits:1 MG(CU)/M3 (DUST)
OSHA PEL:0.1 MG(CU)/M3 (FUME)
ACGIH TLV:0.2 MG/M3 (FUME)
Ingred Name:POLYISOBUTYLENE
Ingred Name:HEPTANE
Fraction by Wt: <2%
ACGIH TLV:0.2 MG/CUM
Ingred Name:COLUMBIA CARBON, CARBON BLACK, LAMPBLACK, BLACK PEARLS
Fraction by Wt: <2%
Other REC Limits:3.5 MG/CUM (NIOSH)
OSHA PEL:3.5 MG/CUM
ACGIH TLV:3.5 MG/CUM
Ingred Name:EPICHLOROHYDRIN, CHLOROMETHYLOXIRANE (ANIMAL CARCINOGEN BY
Other REC Limits:2 PPM
OSHA PEL:5 PPM (SKIN) TWA
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRITATON. SKIN:
IRRITATION & DERMATITIS. INHALATION: HIGH VAPOR CONCENTRATIONS MAY
CAUSE RESPIRATORY IRRITATION & MAY CAUSE ANESTHETIC EFFECTS/OTHER
TEMPORARY CENTRAL NERVOUS SYSTEM EFFE CTS. EXCESSIVE/PROLONGED
CONTACT W/SILVER/SILVER COMPOUNDS HAS BEEN KNOWN TO CAUSE ARGYRIA,
A BLUE-GRAY DISCOLORATION.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, DEFATTING, DRYNESS, HEADACHES,
NAUSEA, DIZZINESS.
* First Aid Measures *
FLUSH AREA THOROUGHLY W/PLENTY OF WATER. FOLLOW BY WASHING W/SOAP &
WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NEEDED.
ING ESTION: DON'T INDUCE VOMITING. IF CONSCIOUS & ALERT, DILUTE BY
GIVING WATER TO DRINK; NEVER GIVE ANYTHING BY MOUTH TO A DROWSY,
UNCONSCIOUS/CONVULSING PERSON. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SCBA & FULL PROTECTIVE
EQUIPMENT. COOL EXPOSED CONTAINERS W/WATER TO PREVENT PRESSURE
BUILDUP. EVACUATE AREA & FIGHT FIRE FROM A DISTANCE
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY VIOLENTLY RUPTURE
UNDER FIRE CONDITIONS. VAPORS ARE HEAVIER THAN AIR & MAY TRAVEL TO
DISTANT SOURCE OF IGNITION & FLASH BACK.
* Accidental Release Measures *
Spill Release Procedures:SMALL: WIPE UP/ABSORB W/VERMICULITE/OTHER
MATERIAL. WASH AREA W/SOAPY WATER TO REMOVE RESIDUE. COLLECT
ABSORBED MATERIAL & WATER RINSE IN APPROPRIATE CHEMICAL WASTE
CONTAINERS. LARGE: EVACUATE PERSONN EL & CLEANUP IMMEDIATE AREA.
(SEE SUPP)
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY LOCATION
W/ADEQUATE VENTILATION. KEEP CONTAINER TIGHTLY SEALED WHEN NOT IN
USE. DON'T STORE NEAR HEAT, SPARKS/OPEN FLAME.
Other Precautions:EMPTY CONTAINER MAY CONTAIN FLAMMABLE LIQUID/VAPOR
RESIDUE. DON'T CUT, WELD, SOLDER, DRILL, GRIND/EXPOSE CONTAINER TO
HEAT, FLAME/OTHER SOURCE OF IGNITION. THEY MAY EXLODE & CAUSE
INJURY/DEATH.
* Physical/Chemical Properties *
Vapor Pres:8
Vapor Density:>1
Spec Gravity:>1.5
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY-SILVER LIQUID W/SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, BASES.
Stability Condition to Avoid:OPEN FLAME, HEAT, SPARKS/OTHER SOURCES OF
IGNITION.
Hazardous Decomposition Products:CO, CO2, ALDEHYDES, ACIDS & OTHER
ORGANIC SUBSTANCES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF AS AN IGNITABLE WASTE IAW/FEDERAL,
STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST REQUIRED.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:R.L.
* Composition/Information on Ingredients *
Ingred Name:PYRIDAZINE; (1,2-DIAZINE)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATING TO SKIN, EYES & MUCOUS
MEMBRANES. TOXICOLOGICAL PROPERTIES HAVE NOT BEEN THOROUGHLY
INVESTIGATED. POSSIBLE TOXIC VIA ORAL, SKIN & MUCOUS MEMBRANES.
MODERATE TO SEVERE ERYTHEMA (REDNESS) & M ODERATE EDEMA (RAISED
SKIN).
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:SKIN:REMOVE CONTAM CLTHG, RINSE LIBERALLY W/SOAP & WATER FOR
CONSIDERABLE PERIOD. CALL MD. INGEST:RINSE MOUTH SEVERAL TIMES
W/WATER, DO NOT SWALLOW. CALL MD/TAKE PATIENT TO HOSPITAL.
PATIENT TO HOSPITAL. INHAL:TAKE PATIENT INTO FRESH AIR & ALLOW TO
REST. CALL MD/TAKE PATIENT TO HOSPITAL.
* Fire Fighting Measures *
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:RISK OF EXPLOSIVE MIXTURE IN AIR.
EXPLOSION! VAPORS EXPOSED TO HEAT OR FLAMES.
* Accidental Release Measures *
Spill Release Procedures:ABSORB LIQUID IN DRY SAND, DIATONITE,
VERMICULITE, ETC, SHOVEL MIXTURE INTO PLASTIC BAGS & TRANSPORT TO
CENTRAL DEPOT FOR CHEMICAL WASTE.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORAGE: ROOM TEMPERATURE. FLAMMABLE,
IRRITANT.
Other Precautions:SWEEP INTO SUITABLE CONTAINER FOR DISPOSAL.
* Physical/Chemical Properties *
Solubility in Water:VERY SOLUBLE
Appearance and Odor:COLORLESS/YELLOW LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:
Hazardous Decomposition Products:DECOMPOSTION/HEATED OR BURNED: TOXIC
FUMES OF NO*X.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE OR LANDFILL AS COMPLIES W/FEDERAL,
STATE & LOCAL LAWS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE WET GRINDING/MACHINING PROCESSES TO KEEP
AIRBORNE DUSTS TO MINIMUM. IF TLV IS EXCEEDED, USE NIOSH/MSHA
APPROVED RESPIRATOR.
Ventilation:USE LOCAL VENTILATION TO KEEP TLV BELOW RECOMMENDED LEVELS.
Other Protective Equipment:USE PERSONAL PROTECTION EQUIPMENT WHEN
REQUIRED.
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE PRACTICES. DO NOT
EAT, DRINK OR SMOKE IN AREAS WHERE DUSTS ARE GENERATED.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:MACHINABLE MAGNET ALLOY
Preparer's Name:K.L. LATIMER
* Composition/Information on Ingredients *
Ingred Name:COBALT
OSHA PEL:0.1 MG/M3;AS CO
Ingred Name:CHROMIUM
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:VANADIUM PENTOXIDE (PEL/TEL AS VANADIUM PENTOXIDE, V*2O*5)
Fraction by Wt: 0-5%
OSHA PEL:C,0.5 MG/M3
Ingred Name:IRON(III) OXIDE; (IRON)
Fraction by Wt: BALANCE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION OF AIRBORNE DUSTS OR FUMES.
ANY LONG-TERM EXPOSURE TO DUSTS EXCEEDING RECOMMENDED TLV LEVELS
MAY RESULT IN IRRITATION TO UPPER RESPIRATORY TRACT. PRODUCT AS
SUPPLIED, PRESENTS NO HEALTH HAZ ARD UNLESS IT IS ABRASIVE GROUND,
CUT, MACHINED OR MELTED. THESE PROCEDURES MAY PRODUCE HAZ AMOUNTS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM: GROUP1(NTP), GROUP 1(IARC).
Effects of Overexposure:HLTH HAZ: OF METALLIC DUSTS OR FUMES.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:SKIN: WASH SKIN AND USE GOOD PERSONAL HYGIENE PRACTICES.
INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG. GIVE O2/ARTF RESP .
* Fire Fighting Measures *
Extinguishing Media:NON-COMBUSTIBLE. MEDIA SUITABLE FOR SURROUNDING
FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:FINE METAL POWDERS PRODUCED BY DRY
ABRASIVE GRINDING OR MACHINING MAY CAUSE AN EXPLOSIVE HAZARD.
* Accidental Release Measures *
Spill Release Procedures:DUSTS MAY BE VACUUMED OR WET SWEPT TO KEEP
AIRBORNE CONCENTRATIONS TO A MINIMUM.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:USE GOOD MANUFACTURING PRACTICES AND
GOOD HOUSEKEEPING PRACTICES THAT WILL KEEP GENERATED DUSTS TO A
MINIMUM.
Other Precautions:CONTROL DUST LEVELS BY WET GRINDING OR MACHINING,
LOCAL EXHAUST VENTILATION, AND GOOD HOUSEKEEPING.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NOT SOLUBLE
Appearance and Odor:SILVER-GREY; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS NITRIC ACID.
Stability Condition to Avoid:AVOID GENERATION OF AIRBORNE DUSTS WHICH
COULD CREATE FIRE AND EXPLOSIVE HAZARD.
Hazardous Decomposition Products:
* Disposal Considerations *
Waste Disposal Methods:RECYCLING OF PRODUCT IS RECOMMENDED. DISPOSE IN
ACCORDANCE WITH FEDERAL, STATE, AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE A MSHA/NIOSH APPROVED VAPOR RESPIRATOR.
Ventilation:PROVIDE LOCAL EXHAUST/MECHANICAL VENTILATION TO KEEP <TLV.
IMPERVIOUS CLOTHING & BOOTS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PRODUCT DOES NOT CONTAIN LEAD OR CHROMATE PIGMENTS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CYCLOHEXANONE (SARA III)
Ingred Name:BUTYRIC ACID LACTONE, TETRAHYDRO-2-FURANONE, BLO
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Fraction by Wt: 0.5-2.8%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: IRRITATION & DAMAGE. SKIN:
IRRITATION, RED, & DRY. INHALATION: RESPIRATORY TRACT IRRITATION,
HEADACHE, DIZZINESS, NAUSEA, VOMITING, LOSS OF CONSCIOUSNESS,
KIDNEY, LIVER, & CENTRAL NERVOUS SYSTEM DAMAGE. INGESTION:
IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYE: IRRITATION & DAMAGE. SKIN: IRRITATION,
RED, & DRY. INHALATION: RESPIRATORY TRACT IRRITATION, HEADACHE,
DIZZINESS, NAUSEA, VOMITING, LOSS OF CONSCIOUSNESS, KIDNEY, LIVER,
& CENTRAL NERVOUS SYSTEM DAMAGE. INGESTION: IRRITATION.
* First Aid Measures *
WASH THOROUGHLY W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
GIVE CPR IF NEEDED. INGESTION: INDUCE VOMITING. OBTAIN MEDICAL
ATTENTION IN A LL CASES.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1%
Upper Limits:6.9%
Extinguishing Media:WATER FOG, ALCOHOL FOAM, CO2, & DRY CHEMICAL.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS. USE
WATER FOG TO COOL CONTAINERS.
Unusual Fire/Explosion Hazard:VAPOR IS >AIR, IT MAY TRAVEL & IGNITE OR
FLASHBACK. EMPTY CONTAINERS STILL COULD IGNITE EXPLOSIVELY. KEEP
AREA CLEAR OF SOURCES OF IGNITION.
* Accidental Release Measures *
Spill Release Procedures:ABSORB W/SAND. REMOVE ALL SOURCES OF IGNITION.
DIKE AREA W/SAND TO CONTAIN SPILLED LIQUID. OPEN ALL WINDOWS &
DOORS. PUMP INTO SALVAGE TANK.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS COOL, DRY & AWAY FROM
IGNITION SOURCES. CHECK ALL CONTAINERS FOR LEAKS.
Other Precautions:OVERHEATING MAY CAUSE CONTAINER TO RUPTURE & EMPTY
CONTAINERS CONTAINING RESIDUE MAY CAUSE A HAZARD. AVOID BREATHING
FUMES & CONTACT W/SKIN. DON'T TAKE INTERNALLY. WASH THOROUGHLY
AFTER HANDLING.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN BU AC
Solubility in Water:<0.1%
Appearance and Odor:CLEAR & COLORED PASTE W/PUNGENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, ALKALIES, & ACIDS.
Stability Condition to Avoid:EXTREME HEAT, COLD, & ELEVATED TEMPS.
Hazardous Decomposition Products:ACRID SMOKE, CO, CO2, & VARIOUS
HYDROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS. KEEP MATERIAL OUT OF SEWERS & STREAMS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AIR MASK IF USED IN A CONFINED AREA.
Ventilation:LOCAL EXHAUST: TO REMOVE VAPORS AWAY FROM WORKER. SPECIAL:
DO NOT RECIRCULATE AIR UNLESS SCRUBBED WITH ACID.
Other Protective Equipment:USE OF SKIN CREAM IS RECOMMENDED. EYE WASH
STATIONS SHOULD BE PROVIDED WITHIN IMMEDIATE WORK AREA FOR
EMERGENCY USE.
Supplemental Safety and Health
* Product Identification *
Product ID:TORRSEAL PART B
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:DIETHYLENETRIAMINE
Other REC Limits:NONE SPECIFIED
ACGIH TLV:1 PPM
Ingred Name:MAGNESIUM SILICATE HYDRATE
Other REC Limits:NONE SPECIFIED
ACGIH TLV:2 MG/M3
Ingred Name:SILICA
Other REC Limits:NONE SPECIFIED
ACGIH TLV:0.1 MG/M3
Ingred Name:DIETHYLENETRIAMINE EPICHLOROHYDRIN BIS PHENOL A ADDUCT
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Health Hazards Acute and Chronic:THIS IS A STRONG SENSITIZER. VAPOR MAY
CAUSE IRRITATION OF LUNG, NOSE, THROAT, AND EYES. CONTACT MAY CAUSE
SKIN AND EYE BURNS. NO KNOWN CHRONIC EXPOSURE HAZARDS.
Effects of Overexposure:VAPOR MAY CAUSE IRRITATION TO LUNGS, NOSE,
THROAT, AND EYES. IT MAY CAUSE COUGHING AND SNEEZING. CONTACT MAY
CAUSE SKIN AND EYE BURNS.
Medical Cond Aggravated by Exposure:ANY PREEXISTING RESPIRATORY, EYE OR
SKIN DISORDER MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
First Aid:IN CASE OR SKIN CONTACT WASH IMMEDIATELY WITH SOAP AND WATER.
IN CASE OF EYE CONTACT FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT
* Fire Fighting Measures *
Flash Point Method:OC
Extinguishing Media:USE WATER SPRAY, DRY CHEMICAL, ALCOHOL FOAM, OR
CO2.
Fire Fighting Procedures:USE WATER TO KEEP FIRE-EXPOSED CONTAINERS
COOL. WATER SPRAY MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOSURES
AND TO DILUTE SPILL TO NONFLAMMABLE MIXTURE.
Unusual Fire/Explosion Hazard:CARE MUST BE TAKEN TO PREVENT IGNITION
WHEN PROCESSING OR HANDLING AT TEMPERATURES ABOVE THE FLASH POINT.
* Accidental Release Measures *
Spill Release Procedures:SCRAPE UP EXCESS, TRANSFER TO METAL CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:PROTECT FROM PHYSICAL DAMAGE. STORE IN
COOL, DRY, WELL VENTILATED AREA AWAY FROM ANY AREA WHERE FIRE
HAZARD MAY BE ACUTE.
Other Precautions:AVOID SKIN CONTACT.
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:NIL
Vapor Density:3.5
Solubility in Water:PARTIAL
Appearance and Odor:TAN, HIGH VISCOSITY LIQUID, STRONG AMMONIA-LIKE
ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTAMINATION WITH STRONG ACIDS.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
HYDROGEN CYANIDE, NITROGEN OXIDES, CO AND CO2.
Conditions to Avoid Polymerization:DO NOT MIX LARGE BATCHES OF EPOXY
RESIN & DIETHYLENETRIAMINE WITHOUT RECOGNITION OF DEVELOPMENT OF
EXOTHERMIC HEAT.
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED INCINERATION OR PUT IN METAL
CONTAINER FOR LANDFILL BURIAL. SOLIDIFY BY MIXING WITH PART A
(RESIN) BEFORE LANDFILL. THIS IS NOT A HAZARDOUS MATERIAL UNDER
(RCRA)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:MUST PROVIDE ADEQUATE VENRTILATION TO KEEP VAPOR
CONCENTRATIONS BELOW ESTABLISHED TLV LIMIT. IN MORE CONFINED AREAS
A NIOSH-MSHA APPROVED RESPIRATOR EQUIPPED WITH ORGANIC VAPOR
CARTRIDGE SHOULD BE WOR N.
Ventilation:MUST PROVIDE ADEQUAE VENTILATION.
Other Protective Equipment:HAVE EYE WASH BATH AVAILABLE.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)
Ingred Name:ALCOHOL
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:TOXICITY MAY CAUSE HEADACHE,
DIZZINESS, NAUSEA, AND LOSS OF CONSCIOUSNESS. EYE IRRITATION,
IRRITATED MUCOUS MEMBRANES, VOMITING DUE TO INGESTION, DEFATTING
AND DRYING OF THE SKIN MAY RESULT IN IRRITAT ION AND DERMATITIS.
Effects of Overexposure:OVEREXPOSURE MAY PRODUCE VARIOUS EFFECTS-ACUTE
TOXICITY, EYE IRRITATION, IRRITATED MUCOUS MEMBRANES, VOMITING,
SKIN IRRITATION & DERMATITIS.
Medical Cond Aggravated by Exposure:SEE ABOVE.
* First Aid Measures *
First Aid:DO NOT INDUCE VOMITING, EYE CONTACT-FLUSH EYES WITH WATER FOR
OXYGEN IF NECESSARY. KEEP VICTIM QUIET. SKIN CONTACT-FLUSH WITH
WATER-REMOVE CONTAMINATED CLOTHING, WASH WITH SOAP AND WATER. GET
MEDICAL ATTENTION IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:2.
Extinguishing Media:FOAM, CO2, OR DRY CHEMICAL.
Fire Fighting Procedures:WATER MAY BE USED TO KEEP CONTAINERS COOL AND
TO KEEP FLAMMABLE STRUCTURE WET. DO NOT ENTER FIRE AREA W/O PROPER
PROTECTION.
Unusual Fire/Explosion Hazard:SEALED CONTAINERS MAY EXPLODE IF
OVERHEATED. WATER PRESSURE MAY SPREAD A FLAMMABLE LIQUID FIRE.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. HANDLING
EQUIPMENT MUST BE GROUNDED TO PREVENT SPARKING. SOAK UP WITH AN
ABSORBENT AND PLACE IN NON-LEAKING CONTAINERS. SEAL TIGHTLY FOR
PROPER DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:TREAT AS A HAZARDOUS-FLAMMABLE
MATERIAL. KNOW APPLICABLE DOT REGULATIONS BEFORE ATTEMPTING TO
TRANSPORT THIS MATERIAL.
* Physical/Chemical Properties *
Vapor Density:>AIR
Appearance and Odor:CLEAR LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS AND STRONG ALKALIES.
Stability Condition to Avoid:AVOID HEAT, SPARKS, OPEN FLAMES AND
INCOMPATIBILITIES,STRONG OXIDIZING AGENTS AND ALKALIES.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION FOR PRODUCTS
LIKE THIS MAY GENERATE HIGHLY POISONOUS CARBON MONOXIDE AND OTHER
TOXIC GASES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH CURRENT LOCAL, STATE
AND FEDERAL REGULATION. CONTACT AN APPROVED DISPOSAL FACILITY.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION IS INADEQUATE AND IF MIST
GENERATED, USE NIOSH/MSHA CERTIFIED RESPIRATOR WHICH WILL PROTECT
AGAINST MIST.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:MULTI-PURPOSE ATF
Preparer's Name:DONALD BARKER
* Composition/Information on Ingredients *
Ingred Name:MINERAL OIL, PETROLEUM DISTILLATES, SOLVENT-REFINED
(SEVERE) HEAVY PARAFFINIC; (SOLVENT-REFINED PARAFFINIC (ING 2)
OSHA PEL:5 MG/M3
ACGIH TLV:5 MG/M3
Ingred Name:ING 1: PETROLEUM OIL)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: NO SIGNIFICANT HEALTH HAZARD
IDENTIFIED. SKIN: NONE EXPECTED FOR SINGLE SHORT-TERM EXPOSURE.
PROLONGED OR REPEATED CONTACT MAY PRODUCE SOME IRRITATION. INHAL:
NO SIGNIFICANT HEALTH HAZARD IDENTI FIED. INGEST: NO SIGNIFICANT
HEALTH HAZARD IDENTIFIED.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
SKIN: WASH EXPOSED SKIN WITH SOAP AND WATER. INHAL: IF ADVERSE
EFFECTS OCCUR, REMOVE TO UNCONTAMINATED AREA. GET MEDICAL
ATTENTION. INGEST: IF A LARGE AMOUNT IS SWALLOWED, GET MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:AGENTS APPROVED FOR CLASS B HAZARDS (E.G., DRY
CHEMICAL, CARBON DIOXIDE, HALOGENATED AGENTS, FOAM, STEAM) OR WATER
FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN ON AN ABSORBENT MATERIAL (E.G., SAND,
SAWDUST, DIRT, CLAY). KEEP OUT OF SEWERS AND WATERWAYS.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:
Other Precautions:
* Physical/Chemical Properties *
HCC:V1
Solubility in Water:NEGLIGIBLE, <0.1%
Appearance and Odor:RED, OILY LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE IDENTIFIED.
Stability Condition to Avoid:NONE IDENTIFIED.
Hazardous Decomposition Products:INCOMPLETE BURNING CAN PRODUCE CARBON
MONOXIDE AND/OR CARBON DIOXIDE AND OTHER HARMFUL PRODUCTS.
* Disposal Considerations *
Waste Disposal Methods:ENCLOSED-CONTROLLED INCINERATION IS RECOMMENDED
UNLESS DIRECTED OTHERWISE BY APPLICABLE ORDINANCES. DISPOSE OF IN
ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR MASK WHEN DUST IS PRESENT.
Ventilation:GENERAL OR LOCAL EXHAUST VENTIALTION
Work Hygienic Practices:USE GOOD PERSONAL HYGIENE & SAFETY PRACTICES.
Supplemental Safety and Health
* Product Identification *
Product ID:HYDROCK/RAPIDSTONE
* Composition/Information on Ingredients *
Ingred Name:CALCIUM SULFATE
Other REC Limits:5 MG/CUM (DUST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES & SKIN: IRRITATION. INHALATION:
NASAL IRRITATION. INGESTION: IF INGESTED MAY CAUSE AN OBSTRUCTION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: COUGHING, SNEEZING.
* First Aid Measures *
First Aid:EYES: FLUSH W/WATER. SKIN: WASH W/SOAP & WATER. INHALATION:
REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:NOT COMBUSTIBLE
* Accidental Release Measures *
Spill Release Procedures:SWEEP OR VACUUM INTO CONTAINER. AVOID CREATING
DUST.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE IN CLOSED
CONTAINERS. MOSITURE OR WATER WILL HARDEN PRODUCT IN STORAGE.
Other Precautions:USE ACCRODING TO DIRECTIONS.
* Physical/Chemical Properties *
Solubility in Water:SLIGHT
Appearance and Odor:YELLOW, WHITE, IVORY POWDER, ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS
CALCIUM OXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN LANDFILL I/A/W LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Cage: 0FTT5
*
Preparer Co. when other than Responsible Party Co.
*
Cage: 0FTT5
*
Contractor Summary
*
Cage: 0FTT5
*
Item Description Information
*
Item Manager: GSA
Item Name: LACQUER
Unit of Issue: PT
UI Container Qty: 0
*
Ingredients
*
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
-----------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: CONCENTRATING & INHALING MAY BE HARMFUL/FATAL.
REPEATED & PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS: PERMANENT
BRAIN & NERVOUS SYS DAMAGE. IN CONFINED AREAS VAPOR IN HIGH CONC ARE
ANESTHETIC. IR RIT TO SKIN & RESP TRACT. LIGHT HEADEDNESS, STAGGERING,
GIDDINESS, NAUSEA. HARMFUL IF SWALLOWED. SEVERE EYE IRRITATION.
Signs And Symptions Of Overexposure: IRRITATION TO EYES, THROAT AND RESPIRATORY
TRACT. MAY CAUSE HEADACHES, NAUSEA AND VOMITING.
Medical Cond Aggravated By Exposure: RESPIRATORY AILMENTS.
First Aid: FOR CONTACT WITH SKIN OR CLOTHES WASH WITH SOAP & WATER; WASH
& CONTACT PHYSICIAN/OPHTHAMOLOGIST IMMEDIATELY. IF SWALLOWED, DO NOT
INDUCE VOMITING. GET IMMEDIATE MEDICAL AID. IF INHALED, REMOVE TO FRESH AIR
AND GIVE ARTIFICIAL RESPIRATION IF NECESSARY AND GET MED AID. NEVER GIVE
ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION AND VENTILATE AREA.
MOP SPILLS WITH INERT ABSORBENT. AVOID BREATHING VAPORS.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL
HEAT OR PROLONGED EXPOSURE TO SUN MAY CAUSE BURSTING. DISCARD EMPTY CAN IN T
RASH PICK-UP. DON'T PLACE IN HOME TRASHCOMPACTOR.
Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN!
SPRAY, MIST OR VAPOR.
Other Precautions: AVOID CONTACT WITH EYES AND SKIN. USE WITH GOOD VENTILATION.
READ ENTIRE LABEL BEFORE USING. FOLLOW ALL LABEL DIRECTIONS. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING & INHALING OR SWALLOWING CONT ENTS
MAY BE HARMFUL OR FATAL.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NR
Lower Limits: 1.8
Upper Limits: 9.5
Extinguishing Media: CO2, DRY CHEMICAL, FOAM, SAND, WATER SPRAY. AVOID
SPREADING ANY BURNING LIQUID WITH WATER SPRAY.
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE, USE TO KEEP FIRE EXPOSED
CNTNR COOL. WEAR SCBA. USE SHIELDING TO PROTECT PERSONNEL AGAINST BURSTING,
RUPTURING OR VENTING OF CNTNRS.
Unusual Fire/Explosion Hazard: DON'T SPRAY NEAR OPEN FLAME. AT ELEVATED
*
*
Respiratory Protection: NONE BELOW TLV. USE NIOSH/MSHA APPROVED MASK ABOVE TLV.
Ventilation: LOCAL EXHAUST: PREFERRED. MECHANICAL (GENERAL): ACCEPTABLE AT
POINT OF MIST OR SPRAY RELEASE.
Other Protective Equipment: IMPERVIOUS CLOTHING TO PROTECT SKIN. EYE WASH
STATION.
Work Hygienic Practices: USE GOOD PERSONAL HYGIENE. DO NOT EAT, DRINK OR SMOKE
WHILE USING PRODUCT.
*
Physical/Chemical Properties
*
HCC: V3
Vapor Density: >1.5
Solubility in Water: INSOLUBLE
Appearance and Odor: ORANGE PAINT/SOLVENT ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT.
Hazardous Decomposition Products: CARBON MONOXIDE, AND POSSIBLE HYDROGEN
CHLORIDE.
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: PT
Container QTY: 0
*
Detail DOT Information
*
DOT PSN Code: DTJ
Symbols: D
DOT Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
Label: NONE
Bulk Pack: NONE
Vessel Stow Req: A
*
Detail IMO Information
*
IMO PSN Code: AKH
IMO Proper Shipping Name: AEROSOLS/AEROSOL PRODUCT ?
UN Hazard Class: 9?
IMO Packaging Group: -
Subsidiary Risk Label: -
*
Detail IATA Information
*
IATA PSN Code: ALS
IATA Proper Shipping Name: AEROSOLS, FLAMMABLE
IATA PSN Modifier: (EACH NOT EXCEEDING 1 L CAPACITY)
IATA UN Class: 2.1
IATA Label: FLAMMABLE GAS
*
Detail AFI Information
*
AFI PSN Code: ALS
AFI Proper Shipping Name: AEROSOLS, NONFLAMMABLE, N.O.S.
AFI PSN Modifier: CONTAINING SUBSTANCES IN CLASS 8, PACKING GROUP I OR II
AFI Hazard Class: FORB
Back Pack Reference: FORBIDDEN
*
HAZCOM Label
*
Cage: 0FTT5
Company Name: LHB INDUSTRIES
Label Required IND: Y
Status Code: C
Origination Code: G
Hazard And Precautions: CONCENTRATING & INHALING MAY BE HARMFUL/FATAL.
REPEATED & PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS: PERMANENT
BRAIN & NERVOUS SYS DAMAGE. IN CONFINED AREAS VAPOR IN HIGH CONC ARE
ANESTHETIC. IR RIT TO SKIN & RESP TRACT. LIGHT HEADEDNESS, STAGGERING,
GIDDINESS, NAUSEA. HARMFUL IF SWALLOWED. SEVERE EYE IRRITATION. IRRITATION TO
EYES, THROAT AND RESPIRATORY TRACT. MAY CAUSE HEADACHES, NAUSEA AN D
VOMITING.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED
Ventilation:NOT REQUIRED
Other Protective Equipment:CLEAN BODY PROTECTIVE CLOTHING
Supplemental Safety and Health
* Product Identification *
CAGE:NATCC
CAGE:NATCC
* Composition/Information on Ingredients *
Ingred Name:CHROMIC ACID (SOLID OR SOLUTION), CRO3, CHROMIUM (VI)
OSHA PEL:0.1 MG/CUM (CRO3)
Ingred Name:NON HAZARDOUS INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE MILD IRRITATION OF EYES,
SKIN & GI TRACT.
Explanation of Carcinogenicity:SEE INGREDIENTS. CONFIRMED HUMAN
CARCINOGEN BY ACGIH.
Effects of Overexposure:MAY CAUSE MILD IRRITATION OF SKIN, EYES & GI
TRACT.
Medical Cond Aggravated by Exposure:SKIN DISORDERS
* First Aid Measures *
First Aid:EYES: FLUSH W/LARGE QUANTITIES OF WATER. SKIN: WASH W/SOAP &
WATER/USE WATERLESS CLEANER. INGESTION: DON'T INDUCE VOMITING.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:ON DRIED PRODUCT: WATER, FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:NONE REQUIRED
Unusual Fire/Explosion Hazard:MATERIAL CAN SPLATTER ABOVE THE BOILING
* Accidental Release Measures *
Spill Release Procedures:KEEP AWAY FROM DRAINS, SEWERS & WATERWAYS.
DIKE AREA. SHOVEL INTO CONTAINERS & ALLOW TO DRY. DRIED SPILLS MAY
BE STEAM CLEANED/USE A COMMERCIAL DEGREASING COMPOUND.
*Handling and Storage *
Handling and Storage Precautions:STORE AT TEMPS ABOVE FREEZING. KEEP
TIGHTLY COVERED. MATERIAL MAY DEVELOP BACTERIAL ODOR ON LONG-TERM
STORAGE IF CONTAMINATED.
Other Precautions:AVOID PERSONAL CONTACT.
* Physical/Chemical Properties *
Vapor Pres:1
Vapor Density:1
Evaporation Rate & Reference:(WATER=1): 1
Solubility in Water:DISPERSES
Appearance and Odor:BROWNISH-BLACK THIXOTROPIC LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS/BASES
Hazardous Decomposition Products:OXIDES OF CARBON
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENT, WEAR A PROPERLY FITTED ORGANIC
VAPOR/PARTICULATE RESP APPRVD BY NIOSH FOR PROTECTION AGAINST
MATERIALS IN INGREDIENTS.
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS TO MATLS IN
INGRED SECTION IS MAINTAINED BELOW APPLIC EXPOS LIMITS. REFER TO
OSHA STDS (SUPDAT)
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . USE W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST. AVOID
CONT W/SKIN & EYES.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR TRADE NAME/PART NO: RUST PREVENTATIVES & MAINTENANCE PRODS - 2. WT
PREC: INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS CAN BE
* Product Identification *
Resp. Party Other MSDS Num.:LUBE2/ISD
* Composition/Information on Ingredients *
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EXPOS MAY BE BY INHALATION
AND/OR SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO
MINIMIZE EXPOSURE, FOLLOW RECOMMENDATIONS FOR PROPER USE,
VENTILATION, AND PERSONAL PROTECTIVE EQUIPMEN T. EFFECTS OF
OVEREXPOSURE: IRRITATION OF EYES, SKIN AND RESPIRATORY SYSTEM. MAY
CAUSE NERVOUS SYSTEM DEPRESSION. EXTREME OVEREXPOSURE MAY RESULT IN
UNCONSCIOUSNESS AND POSSIBLY DEATH. SIGNS AND SYMPT OMS OF
OVEREXPOSURE: HEADACHE, DIZZINESS, NAUSEA, AND LOSS OF COORDINATION
ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR SPRAY MISTS.
REDNESS AND ITCHING OR BURNING SENSATION MAY INDICATE EYE OR
EXCESSIVE SKIN EXPOSURE.(EFT OF OVEREXP)
Explanation of Carcinogenicity:TETRACHLOROETHYLENE: GROUP 2B, IARC
Effects of Overexposure:HEALTH HAZARDS (CONT):CHRONIC HEALTH HAZARDS:
PROLONGED OVEREXPOSURE TO SOLVENT INGREDIENTS MAY CAUSE ADVERSE
EFFECTS TO LIVER, URINARY AND CARDIOVASCULAR SYSTEMS. REPORTS HAVE
ASSOCIATED REPEATED AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH
PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. TETRACHLOROETHYLENE,
LISTED BY NTP AND IARC AS AN ANIMAL CARCINOGEN AND BY OSHA AS A
POTENTIAL CARCINOGEN, PRODUCED LIVER TUMORS AND LEUKEMIA IN RATS
AND LUNG TUMORS IN MICE. EPIDEMIOLOGICAL EVIDENCE IS CONFLICTING
AND INCONCLUSIVE.
Medical Cond Aggravated by Exposure:CARDIOVASCULAR PROBLEMS MAY BE
AGGRAVATED BY OVEREXPOSURE TO METHYLENE CHLORIDE.
* First Aid Measures *
First Aid:INHAL: IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING.
KEEP WARM AND QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY W/SOAP &
WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE.
GET MEDICAL ATTENTION. INGEST: GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Lower Limits:1.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOGG
NOZZLES ARE PREFERABLE. WATER MAY BE USED TO COOL CLSD CNTNRS TO
PVNT PRESS BUILD UP & POSS AUTOIGNIT OR EXPLOSION WHEN EXPOSED TO
EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLSD CNTNRS MAY EXPLODE (DUE TO BUILD-UP
OF PRESS) WHEN EXPOSED TO EXTREME HEAT. ISOLATE FROM HEAT, ELEC
EQUIP, SPKS & OPEN FLAME. APPLICATION TO HOT SURFS REQS SPECIAL
PRECAUTIONS. DURING EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE
HLTH HAZ. SYMPS MAY NOT BE IMMED APPARENT. OBTAIN MED ATTN.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:CONTENTS ARE EXTREMELY FLAMM. KEEP
AWAY FROM HEAT, SPKS, & OPEN FLAME. VAPS WILL ACCUM READILY & MAY
IGNITE EXPLO. DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA
VENTILATED-DO NOT SMOKE-EXTING ALL FL AMES, PILOT LIGHT, &
HEATERS-TURN OFF STOVES, ELEC TOOLS & APPLIANCES, & ANY OTHER
SOURCES OF IGNIT.
Other Precautions:CONSULT NFPA CODE. USE APPRVD BONDING & GROUNDING
PROCEDURES. CONTENTS UNDER PRESS. DO NOT PUNCTURE, INCIN/EXPOSE TO
& OTHER HEAT SOU RCES COULD CAUSE CNTNR TO BURST. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN. (SUPDAT)
* Physical/Chemical Properties *
Vapor Pres:SEE INGREDIENTS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:FASTER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS LISTED IN INGREDIENT SECTION II.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM PRODUCTS MAY BE HAZARDOUS AS DEFINED
BE TESTED FOR IGNITABILITY TO DETERM APPLIC RPA HAZ WASTE NUMBERS.
DO NOT INCIN. DEPRE SSURIZE CNTNR. DISPOSE OF I/A/W FEDERAL, STATE,
& LOCAL REGS REGARDING POLLUTION.
* Regulatory Information *
SARA Title III Information:TETRACHLOROETHYLENE IS SUBJECT TO THE
REPORTING REQUIREMENTS OF THE SUPERFUND AMENDMENTS AND
Federal Regulatory Information:ALL CHEMICALS IN THESE PRODUCTS ARE
LISTED, OR ARE EXEMPT FROM LISTING, ON THE TSCA INVENTORY.
State Regulatory Information:WARNING: THIS PRODUCT CONTAINS CHEMICALS
KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
RESP/SCBA WHERE AIRBORNE EXPOS IS LIKELY. IF USED, FULL FACEPIECE
REPLACES NEED FOR CHEM GOGGS &/OR FSHLD. IF EXPOS CANNOT BE KEPT AT
MIN W/ENGINEERING CONTROLS, USE NIOSH APPRVD RESP EQUP AS NOTED.
OBSERVE RESP USE LIMITATIONS SPECIFIED BY NIOSH/MFR. FOR EMER &
OTHER CNDTNS WHERE THERE MAY BE (OTHER INFO)
Ventilation:INVESTIGATE ENGINEERING TECHNIQUES TO REDUCE EXPOS BELOW
AIRBORNE EXPOS LIMS. PROVIDE VENT IF NEC TO CONTROL EXPOS LEVELS
BELOW AIRBORNE EXPOS LIMS.(OTHER INFO)
APPROP TYPE OF MATL.
FACESHIELD .
Other Protective Equipment:EYE WASH & DELUGE SHWR MTG ANSI DESIGN
CRITER . WEAR APPROP CHEM RESIST PROT CLTHG TO PVNT SKIN CONT. --
EPINEPHRINE TO (HYGIENE PRACT)
Work Hygienic Practices:RINSE CONTAM SKIN PROMPTLY. WASH CONTAM CLTHG &
CLEAN PROT EQUIP BEFORE REUSE. WASH SKIN THORO AFTER HNDLG. --
OTHER PROT EQUIP:SIMULATE HUMAN STRESS RXN, RESULTED IN HEART
SENSIT IN (HAZ DECOMP PROD)
Supplemental Safety and Health
ITY - 0. -- CNDTNS(STAB): THERMAL DECOMP. DO NOT MIX W/OXYG OR AIR
ABOVE ATMOSPHERIC PRESS.
* Product Identification *
Preparer's Name:RAY MADARIAGA
* Composition/Information on Ingredients *
8-HR TWA (M).
= Wt:4.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE EFTS:RAPID VOLATILIZATION OF LIQ
MAY CAUSE FROSTBITE IF LIQ IS APPLIED TO EYES. SKIN EFTS:CONT W/LIQ
MAY CAUSE TISS TO FREEZE (FROSTBITE). CAN CAUSE IRRIT. OTHER TOX
EFTS:SKIN CONT & INHAL ARE EXP ECTED TO BE PRIMARY RTES OF OCCUP
EXPOS. AS W/MOST LIQUEFIED GASES, CONT W/RAPIDLY VOLATILIZING
LIQ/COLD VAPS CAN CAUSE FROSTBITE TO ANY TISS DUE TO CRYOGENIC
(EXTREME LOW TEMP) EFT OF THIS MATL. VAPS MAY BE MILDLY IRRIT TO
EYES. ACUTE STUDIES W/LAB ANIMALS INDICATE THAT COMPONENTS OF THIS
HALOCARBON MIXT ARE PRACTICALLY NON-TOX BY INHAL RTE. HOWEVER,
EXPOS TO HALOCARBON GASES AT HIGH CONCS MAY AF FECT NERV SYS &
PRDCE (EFTS OF OVEREXP)
Explanation of Carcinogenicity:N/P -- TOX INFO:HUMAN STRESS RXNS
DOGS. NO TOX EFTS & NO TUMORS WERE OBSERVED IN ORAL DOSE STUDY OF
FOLLOWED BY LIFETIME OBSERVATION. LONG-TERM INHAL (2-YRS) OF HIGH
PROC)
Effects of Overexposure:HLTH HAZ:RAPID ANESTH EFT. DENSE VAP OF THIS
PROD DISPLACES AIR IN CONFINED SPACES, THEREBY REDUCING OXYG AVAIL
FOR BRTHG. UPON EXPOS TO SUCH ATM, PERS MAY EXPER SYMPS OF OXYG
DEFICIENCY, INCL HDCH, D IZZ, DROW, CYANOSIS, LACK OF MUSC CONTROL
FOLLOWED BY COLLAPSE. PRLNG EXPOS TO OXYG-DEFICIENT ATM MAY BE
FATAL. AS W/MANY OTHER HALOGENATED HYDROCARBONS, INHAL OF THIS CMPD
MAY CAUSE INCR IN SENSITIVI TY OF HEART TO ADRENALINE, WHICH COULD
RSLT IN IRREG HEARTBEATS (CARD ARRHYS). RAPID HEARTBEATS
(TACHYCARDIA) & REDUCED HEART FUNC. -- OTHER INFO:SIGNIFICATION NEW
CNDTNS)
Medical Cond Aggravated by Exposure:DUE TO POTNTL FOR THIS EFT, WORKERS
W/HEART DISEASE/COMPROMISED HEART FUNC SHOULD ONLY HAVE LTD EXPOS
* First Aid Measures *
First Aid:INGEST:N/A-PROD IS GAS AT AMBIENT CNDTNS. EYES:IMMED FLUSH
PERSISTS. SKIN:FLUSH EXPOS SKIN W/LUKEWARM WATER (NOT HOT) - OR USE
OTHER MEANS TO WARM SLOWLY. GET MED ATTN IF FROSTBITTEN BY LIQ/IF
IRRIT OCCURS. INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF
RESP. IF BRTHG IS DFCLT GIVE OXYG. GET MED ATTN. DO NOT GIVE
ADRENALINE, EPINEPH RINE/SIMILAR DRUGS FOLLOWING EXPOS TO THIS
PROD. -- EXPLAN OF CARCIN:LIFE-THREATENING TUMORS OF TESTES IN
THIS STUDY. NEG IN MOUSE DOM INANT LETHAL ASSAY. NO (EXTING MEDIA)
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Autoignition Temp:Autoignition Temp Text:N/E
Extinguishing Media:USE WATER SPRAY/FOG, CO*2, DRY CHEM/WATER STREAM.
-- FIRST AID PROC:BIRTH DEFECTS WERE NOTED IN RATS & RABBITS EXPOS
BY INHAL DURING PREGNANCY, EVEN AT LEVELS (FIRE FIGHT PROC)
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . FIRE
FIGHTING EQUIP SHOULD BE THORO DECONTAM AFTER USE. - EXTING
EFTS IN MOTHERS & THEIR OFFSPRING. ING PRDCD NO GENETIC CHANGES IN
STD TEST USING ANIMALS (VIVO TEST) & ANIMAL/BACTERIAL CELLS. (SPILL
PROC)
Unusual Fire/Explosion Hazard:PROD IS NOT FLAMM AT AMBIENT TEMPS & ATM
PRESS. HOWEVER, THIS MATL WILL BECOME COMBUST WHEN MIXED W/AIR
UNDER PRESS & EXPOS TO STRONG IGNIT SOURCES. MAY DECOMPOSE DURING
CONT W/FLAMES, HEATING ELEMENT S/IN COMBUST ENGINES RELS IRRIT, TOX
& CORR GASES. CNTNR MAY EXPLODE IF HEATED DUE TO RESULTING PRESS
RISE. (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:REMOVE/EXTING IGNIT/COMBUST SOURCES. EVACUATE
ENCLSD SPACES UNTIL GAS IS DISPERSED. KEEP UPWIND. STOP LEAK IF
POSS W/OUT RISK. DISPERSE GAS W/FLOOR-LEVEL FORCED-AIR VENT. EXHST
VAPS OUTDOORS. REMOVE A LL FLAMES, HEATING ELEMENTS & GAS ENGINES.
WASH CONTAM CLOTHES BEFORE USE. DESTROY CONTAM SHOES. -- FIRE FIGHT
PROC:METABOLISM STUDIES IN RATS EXPOS BY ORAL & INHAL RTES SHOW
THAT ING IS (NEUT AGENT)
Neutralizing Agent:N/P -- SPILL PROC:NOT METABOLIZED/ACCUMULATED IN
BODY TO ANY SIGNIFICANT EXTENT & IS RAPIDLY ELIM IN(OTHER PREC)
*Handling and Storage *
Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN/CLTHG. DO
NOT BREATHE VAP, MIST/GAS. KEEP CNTNR CLSD. KEEP AWAY FROM HEAT,
SPKS & FLAMES. STORE IN TIGHTLY CLSD CNTNRS. EMPTY CNTNR MAY
CONTAIN HAZ RESIDUE. DO NOT DROP, RE USE/REFILL CTNR. DO NOT SMOKE.
DO NOT CUT, GRIND/WELD ON/NEAR CNTNR DUE TO POSS TOX FUME
GENERATION.
Other Precautions:READ LBL BEFORE USE. PROD SHOULD NOT BE MIXED W/AIR
ABOVE ATMOSPHERIC PRESS FOR LEAK TESTING/ANY OTHER PURPOSE. -- NEUT
W/MANY OTHER HALOGENATED HYDROCARBONS, INHAL OF HI GH(OTHER PROT
EQUIP)
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:N/A / N/E
Vapor Density:SUPP DATA
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUEFIED GAS WITH FAINT ETHEREAL
(ETHER-LIKE) ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONT W/STRONG ALKALI/ALKALINE EARTH METALS, FINELY POWDERED
METALS SUCH AS ALUMINUM, MAGNESIUM/ZINC & STRONG OXIDIZERS. SINCE
THEY MAY REACT WITH/ACCELERATE DECOMP OF THIS MATL.
Stability Condition to Avoid:AVOID FLAMES, SPKS, EXTREMELY HOT SURFS,
HEATING ELEMENTS, PILOT LIGHTS, STATIC ELEC, WELDING ARCS, COMBUST
ENGINES, POTNTL IGNIT SOURCES/OTHER HIGH TEMP SOURCES WHICH
INDUCE(SUPDAT)
Hazardous Decomposition Products:THERMAL DECOMP PRODS INCL HYDROGEN
FLUORIDE, CARBON MONOXIDE & CARBON DIOXIDE. -- HYGIENE PRACT:DOGS.
WKS, SLIGHT (CNDTNS (POLYM))
* Toxicological Information*
Toxicological Information:DATA FROM LAB STUDIES CONDUCTED BY ELF
ATOCHEM NORTH AMERICA, INC & FROM SCIENTIFIC LITERATURE ON INGS ARE
GUINEA PIGS FOLLOWING RPTD EXPOS. INHA L OF VERY HIGH CONCS OF THIS
DOGS, CATS & MONKEYS. AS W/MANY OTHER HALOGENATED HYDROCARBONS,
INHAL FOLLOWED BY IV INJECTION OF EPINE PHRINE TO STIMULATE (EXPLAN
OF CARCIN)
* Ecological Information *
ECOTOXICOLOGICAL INFO:NO DATA AVAIL. CHEM FATE INFO:WHEN RELS INTO
ENVIRON, ING MAY BE EXPECTED TO PARTITION ALMOST EXCLUSIVELY INTO
ATM. BASED ON ITS LOW N-OCTANOL/WATER PARTITION COEFFICIENT (LOG
READY BIODEGRADABILITY CLSD BOTTLE TEST, ING APPEARED TO BE STABLE
(ABOUT 2% DEGRADED). ING DOES NOT DISSOCIATE (OTHER INFO)
* Disposal Considerations *
Waste Disposal Methods:RECYCLE/RECLAIM IF POSS. RECLAIMED MATL MAY BE
INCIN BUT TOX & CORR COMBUST PRODS MUST BE HNDLD APPROPLY. CONSULT
FED, STATE/LOC AUTHS FOR PROPER DISP PROCS. -- CNDTNS(POLYM):NOTED
IN RATS & GUINEA PI GS. RPTD "NOSE ONLY" INHAL OF LOWER
PORTED TO PRDCE TESTICULAR CHANGES(TRANSPORT INFO)
* MSDS Transport Information *
Transport Information:DOMESTIC-OTHER THAN AIR (DOT): PROPER SHIPPING
NAME:LIQUEFIED GAS, N.O.S. TRIFLUOROETHANE, PENTAFLUOROETHANE &
GAS). DOT PLACARD:NON-FLA MM GAS. PROPER SHIPPING
DESCRIPTION:LIQUEFIED GAS, N.O.S.(CONTAINS TRIFLUOROETHANE,
METH:IN RATS. SUBSEQUENT STUDY SHOWED THAT TESTIC ULAR EFTS WERE
PROBABLY DUE TO EXCESS BODY HEAT & STRESS CAUSED BY "NOSE ONLY"
ORAL ADMIN OF ING(SARA TITLE III)
* Regulatory Information *
IN RATS WAS LOWER BODY WTS. NO BIRTH DEFECTS/ANY OTHER EFTS ON
OFFSPRING/MOTHERS WERE NOTED IN RATS & RABBITS EXPOS BY INHAL TO
GENETIC CHANGES IN STD TESTS USING ANIMALS/ANIMAL CELLS. BOTH POS &
NEG RESPONSES HAVE BEEN REPORTED I N ASSAYS USING BACTERIAL CELLS.
ING DID NOT INDUCE PEROXISOME PROLIFERATION IN RAT LEVER CELL
(FED REGULATORY)
Federal Regulatory Information:N/P -- SARA TITLE III:INHAL EXPOS TO
LABORED BRTHG, NOT NO SYMPS WERE NOTED AFTER EXPOS. AS WITH MANY
INTRAVENOUS INJECTION OF EPINEPHRIN TO STIMULATE HUMAN STRESS
ADVERSE EFFECTS WERE OBSERVED IN A SERIES OF INHAL STUDIES WITH
PPM. NO BIRTH DEFECTS OR OTHER EFFECTS ON OFFSPRING WERE NOTED IN
RATS (STATE REGULATORY INFO)
State Regulatory Information:N/P -- FED REGULATORY: AND RABBITS EXPOSED
CHANGES IN MANY STANDARD TEST S WHICH USE ANIMALS AND ANIMAL OR
BACTERIAL CELLS.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:RESPIRATOR WHEN WELDING, BRAZING, OR SOLDERING
IN CONFINED SPACE, IF >TLV.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP THE FUMES & GASES
<TLV.
Supplemental Safety and Health
WELDING WIRE IS A NONHAZARDOUS SOLID AT AMBIENT TEMPERATURE. HAZARDS
MAY RESULT FROM FUME GENERATED DURING WELDING.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:GRAPHITE, SYNTHETIC
Ingred Name:CHROMIUM (SARA III)
OSHA PEL:1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:NICKEL (SARA III)
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/M3
Ingred Name:MOLYBDENUM
Fraction by Wt: 2.0-4.0%
Ingred Name:MANGANESE (SARA III)
Fraction by Wt: 1.0-2%.%
OSHA PEL:(C) 5 MG/M3 DUST
Ingred Name:SILICA, CRYSTALLINE - FUSED
OSHA PEL:SEE TABLE Z3
Ingred Name:COPPER (SARA III)
Other REC Limits:0.2 MG/CUM FUMES
OSHA PEL:0.1MG/M3 FUME/1 DUST
Ingred Name:IRON
Fraction by Wt: BALANCE
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:YES
Health Hazards Acute and Chronic:SHORT TERM EXPOSURE TO WELDING FUME
MAY RESULT IN DISCOMFORT, DIZZINESS, NAUSEA, DRYNESS OR IRRITATION
OF THE THROAT.
Explanation of Carcinogenicity:NICKEL & CHROMIUM SHOULD BE CONSIDERED
POSSIBLE CARCINOGENS.
Effects of Overexposure:LONG TERM EXPOSURE TO WELDING FUME, GASES OR
DUST MAY CONTRIBUTE TO PULMONARY IRRITATION OR PNEUMOCONIOSIS. LONG
TERM EXPOSURE TO IRON FUME MAY PRODUCE SIDEROSIS.
* Fire Fighting Measures *
Unusual Fire/Explosion Hazard:NONFLAMMABLE. WELDING ARC, OPEN FLAME &
SPARKS CAN IGNITE COMBUSTIBLES.
*Handling and Storage *
Handling and Storage Precautions:TRAIN EMPLOYEE TO KEEP HIS HEAD OUT OF
THE FUMES.
Other Precautions:ONE RECOMMENDED WAY TO DETERMINE THE COMPOSITION &
QUANTITY OF FUMES & GASES TO WHICH WORKERS ARE EXPOSED IS TO TAKE
AN AIR SAMPLE FROM INSIDE THE WELDER'S HELMET IF WORN OR IN THE
WORKER'S BREATHINGZONE.
* Physical/Chemical Properties *
Appearance and Odor:SOLID WIRE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:CO, CO2, OZONE, OXIDES OF METAL &
NITROGEN.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:DUST RESPIRATOR IF NEEDED.
Ventilation:LOCAL EXHAUST OR BREATHING PROTECTION
Other Protective Equipment:CLEAN LONG SLEEVED & LEGGED CLOTHING,HAND &
FACE COVERING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CALCIUM CHLORIDE,ANHYDROUS
* Hazards Identification *
Effects of Overexposure:COUGHING,SHORTNESS OF BREATH,IRRITATES
SKIN,EYES,ABDOMINAL SPASM,NAUSEA.
* First Aid Measures *
First Aid:INHALATION:FRESH AIR,REST,& TRANSPORT TO HOSPITAL.SKIN:REMOVE
CONTAMINATED CLOTHES,RINSE SKIN W/PLENTY OF WATER OR
SHOWER.EYES:FIRST RINSE WITH PLENTY OF WATER,THEN TRANSPORT TO A
DR.INGEST:RINSE MOUT H,GIVE PLENTY OF WATER TO DRINK,CALL A DR.
* Accidental Release Measures *
Spill Release Procedures:NO SPECIAL PRECAUTIONS MECESSARY-SWEEP UP
SPILLED SUBSTANCE,WASH AWAY REMAINDER W/LARGE AMOUNT OF WATER.AVOID
CONTACT WITH LIQUID & SOLID.KEEP PEOPLE AWAY(WITHOUT PROTECTIVE
CLOTHING).STOP LEAK IF POS SIBLE.ISOLATE & REMOVE DISCHARGED MATL.
*Handling and Storage *
Handling and Storage Precautions:AVOID EYE & PROLONED SKIN
CONTACT.STORE IN DRY,WELL VENTILATED AREA.ALWAYS USE COOL
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE TO OFF WHITE,ODORLESS SOLID GRANULAR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
METALS WILL SLOWLY CORRODE IN H*2O SOLNS,BASES(AS AN ACID)
Stability Condition to Avoid:EXPOSURE TO ATMOSPHERE,CACL*2 PICKUP WATER
& FORM A SOLUTION
Hazardous Decomposition Products:CHLORIDES
* Disposal Considerations *
Waste Disposal Methods:WASH AWAY WITH EXCESS OF WATER OR BURY IAW
FEDERAL,STATE & LOCAL REGS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS AS SPECIFIED
BY INDUSTRIAL HYGIENIST OR QUALIFIED SAFETY PROFESSIONAL. LUNG
FUNCTION TESTS ARE RECOMMENDED FOR USERS OF NEGATIVE PRESSURE
DEVICES.
Ventilation:LOCAL EXHAUST VENTILATION SHOULD BE USED TO CONTROL
EXPOSURE TO AIRBORNE DUST AND FUME WHENEVER POSSIBLE.
Other Protective Equipment:UNIFORMS, DISPOSABLE COVERALLS, SAFETY
SHOES, ETC. MAY BE REQUIRED DURING METAL HANDLING OPERATIONS AS
APPROPRIATE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXTING MEDIA: CLASS "D" FIRE EXTING POWDER. FIRST AID PROC:AMTS OF
LENSES SHOULD NOT BE WORN WHEN WORKING WITH METAL DUSTS & POWDERS.
SPILL PROC:OR DUST & AVOID CONTAMINATION OF AIR & WATER. PROPERLY
LABEL ALL MATLS COLLECTED IN WASTE CONTAINER.
* Product Identification *
Product ID:BERYLLIUM COPPER CASTING ALLOYS, CU-4BE (MA
Preparer's Name:W.J. HETRICK
CAGE:0VZP9
CAGE:0VZP9
* Composition/Information on Ingredients *
Ingred Name:ING 5:TO FURTHER RISK IF HANDLING AND USE OF MATERIAL
CAUSES EXCESSIVE EXPOSURE.
Ingred Name:EFTS OF OVEREXP:EYE:PARTICULATE METAL (DUST, FUME OR
POWDER) MAY BE DANGEROUS TO EYE & SURROUNDING TISS. AIRBORNE(ING 8)
Ingred Name:ING 7:PARTICULATE (CHIPS, DUST OR POWDER) IS ALWAYS POTNTL
PROBLEM AS WELL AS INSERTING FINGERS INTO EYE SOCKET IF(ING 9
Ingred Name:ING 8:THE HAND/CLTHG IS CONTAM W/METAL PARTICULATE.
ACUTE:METAL DUST & FUMES OF INGREDS CAN CAUSE IRRIT TO SKIN,(ING
Ingred Name:ING 9:EYE AND MUCUS MEMBRANE. CONTACT COPPER MAY CAUSE
DUST/PARTICULATE. EXCESS INHAL OF COPPER & NICKEL CAN CAUSE (ING
NUMEROUS ELEMENTAL CONSTITUENTS IN ALLOY.
SUMMARY) .
Ingred Name:BERYLLIUM (SARA III)
Fraction by Wt: 4%
OSHA PEL:2 UG/M3
Ingred Name:COPPER (SARA III)
Fraction by Wt: BALANCE
OSHA PEL:0.1MG/M3 FUME;1 DUST
ACGIH TLV:0.2MG/M3 FUME;1 DUST
Ingred Name:MED CNDTNS:CNDTNS SUCH AS ASTHMA, EMPHYSEMA, CHRONIC
BRONCH, ETC. MAY INCUR FURTHER DISABILITY IF EXCESS CONC (ING 4)
Ingred Name:ING 3:OF DUST/FUME ARE INHALED. IF PRIOR DMG OR DISEASE TO
NEUROLOGIC (NERV), CIRCULATORY, HEMATOLOGIC (BLOOD) OR(ING 5)
Ingred Name:ING 4:RENAL (KIDNEY) SYS HAS OCCURED, PROPER SCREENING OR
EXAMS SHOULD BE CONDUCTED ON INDIV WHO MAY BE EXPOSED (ING 6)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL:INHAL OF METAL DUST, FUME OR
POWDER MAY RSLT FROM MELTING, DROSS HNDLG, CASTING, WELDING,
GRINDING, CRUSHING OR SIMILAR OPERS WHICH GENERATE AIRBORNE METAL
PARTICULATE DURING USE OF MATL. INGEST :HAND, CLTHG, FOOD & DRINK
CNTCT W/METAL DUST, FUME OR POWDER CAN CAUSE INGEST OF PARTICULATE
DURING (EFTS OF OVEREXP)
Explanation of Carcinogenicity:BERYLLIUM:POSS CARC TO HUM (GROUP
Effects of Overexposure:HEALTH HAZARD: HAND TO MOUTH ACTIVITIES SUCH AS
EATING, DRINKING, SMOKING, NAIL BITING, ETC. SKIN: IN FORM OF METAL
DUST POWDER, SKIN CONTACT OR ABRASION MAY ALSO CAUSE IRRITITATION
OR DERMATITIS. (IN G 7)
Medical Cond Aggravated by Exposure:INDIV WHO MAY HAVE HAD ALLERG RXN
OR SENSIT TO METALS SUCH AS CHROME & COPPER MAY ENCOUNTER SKIN
RASH/DERM IF SKIN CNTCT W/PROD OCCURS. PERS W/IMPAIRED PULM
FUNCTION, AIRWAY DISEASES & (ING 3)
* First Aid Measures *
First Aid:INHAL:BRTHG DFCLTY CAUSED BY DUST/FUME REQS REMOVAL TO FRESH
AIR. IF BRTHG STOPPED, GIVE ARTF RESP & GET MD IMMED. INGEST:HAVE
AFFECTED PERS DRINK LRG QTYS OF WATER & ATTEMPT TO INDUCE VOMIT IF
CONSCI OUS. GET MD IMMED. SKIN:CUTS/ABRASIONS CAN BE TREATED BY
STANDARD FIRST AID. SKIN CONTAM W/DUST/POWDER CAN BE REMOVED BY
WASHING W/SOAP & WATER. IF IRRIT PERSISTS GET MD. EYE:FLUSH
W/COPIOUS (SUPDAT)
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:USE EXTING MEDIA APPROP TO SURROUNDING FIRE. TO
EXTING METAL POWDER FIRE USE DRY SAND, DRY GRAPHITE OR OTHER
(SUPDAT)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROTECTIVE
EQUIPMENT . IF MATERIAL IS REDUCED TO POWDER FORM, CAUTION MUST BE
USED TO PREVENT FIRE OR EXPLOSION.
Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE
ASSOCIATED WITH THIS MATERIAL.
* Accidental Release Measures *
Spill Release Procedures:IN SOLID FORM MATL POSES NO SPECIAL CLEAN-UP
PROBLEMS. IF MATL IS IN POWDER/DUST FORM, CLEAN-UP SHOULD BE
CONDUCTED W/VACUUM SYS UTILIZING HIGH EFFICIENCY PARTICULATE AIR
FILTRATION SYS. CAUTION SHOUL D BE TAKEN TO MIN AIRBORNE GEN OF
POWDER (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE METAL AND METAL POWDER IN DRY
AREA. DO NOT STORE ADJACENT TO MINERAL ACIDS. FINE METAL POWDERS
SHOULD BE KEPT AWAY FROM FLAMES & IGNIT SOURCES.
Other Precautions:PRODUCT MUST BE HANDLED ACCORDINGLY TO THE SIZE,
SHAPE AND QUANTITY OF MATERIAL INVOLVED. SOLID METAL MAY REQ USE OF
HOISTS, CRANES, ETC. POWDERS SHOULD BE MOVED OR TRANSPORTED TO
MINIMIZE SPILL OR RE LEASE POTENTIAL.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NONE
Appearance and Odor:SOLID, BRASS COLOR, NO ODOR
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/MINERAL ACIDS/OXIDIZING AGENTS WHICH MAY GENERATE
HYDROGEN GAS; EVOLUTION OF HYDROGEN MAY BE EXPLO HAZ.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:VARIOUS ELEMENTAL METALS & METAL
OXIDES MAY BE GENERATED FRM MELTING OR DROSS HANDLING OPERATIONS.
* Disposal Considerations *
Waste Disposal Methods:PRIOR TO DISP CONSIDER IF MATL HAS RECOVERY
VALUE. STATE/FED REGS MAY REQ SPECIFIC LABELING, PACKING, STORAGE,
TRANSPORTATION, & DISP PROC. CNTCT ENVIRON ENGINEER/CONSULTANT
FAMILIAR W/WASTE DISP REGS . DISP MUST BE I/A/W LOC, STATE & FED
REGS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:LOCAL EXHAUST
Other Protective Equipment:CLOTHING TO PROTECT SKIN
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PORTLAND CEMENT
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
OSHA PEL:SEE TABLE Z3
* Hazards Identification *
Effects of Overexposure:EYES:INFLAMM.INHAL:NOSE INFLAM.SKIN:ALKALI
BURNS,DRY SKIN(WET CEMENT).INGEST:CONSTIPATION
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR.EYES:FLUSH W/ PLENTYOF WATER & CALL
MD.SKIN:WASH W/ SOAP & WATER.INGEST:CALL MD
* Fire Fighting Measures *
Flash Point:N/R PER MFR
Fire Fighting Procedures:NONE PER MFR
Unusual Fire/Explosion Hazard:NONE PER MFR
* Accidental Release Measures *
Spill Release Procedures:SWEEP OR VACUUM USING GOOD VENTILATION
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY AREA.WASH THOROUGHLY
AFTER HANDLING.
Other Precautions:PRODUCT WILL HARDEN IF IN CONTACT W/ WATER.
* Physical/Chemical Properties *
HCC:N1
Boiling Pt:B.P. Text:N/R(SOLID)
Solubility in Water:SLIGHT
Appearance and Odor:GREY POWDER-NO ODOR
Percent Volatiles by Volume:0.0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:CONTAMINATION W/ WATER
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN SANITARY LANDFILL IN ACCORDANCE W/
FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:CHEMICAL FUME HOOD.
Other Protective Equipment:LAB COAT.
Work Hygienic Practices:WASH CAREFULLY AFTER USE.
Supplemental Safety and Health
MATLS TO AVOID: CAN REACT EXPLOSIVELY WHEN HEATED.
* Product Identification *
Preparer's Name:VANAJA SIVAKUMAR
* Composition/Information on Ingredients *
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ZINC OXIDE MAY BE HARMFUL IF INGESTED,
INHALED OR CONTACTED WITH THE SKIN OR EYES. INHALATION OF ZINC
OXIDE FUMES CAN LEAD TO METAL FUME FEVER. SYMPTOMS OF THE FEVER ARE
METALLIC TASTE, THROAT IRRITAT ION, COUGHING WITH DYSPNEA, FATIGUE,
FEVER & CHILLS. OVEREXPOS TO ZINC OXIDE MAY ALSO CAUSE GI (EFTS OF
OVEREXPOS)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: DISTURBANCE AND LIVER DYSFUNCTION.
SKIN CONTACT MAY RESULT IN DERMATITIS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
LIFTING UPPER AND LOWER LIDS. SKIN: REMOVE CONTAMINATED CLOTHING,
THOROUGHLY BE FORE REUSE. INHAL: MOVE TO FRESH AIR. ALL EXPOSURES:
IF IRRITATION CONTINUES, GET MEDICAL ATTENTION IMMEDIATELY. INGEST:
CALL MD IMMEDIATELY .
* Fire Fighting Measures *
Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AND VENTILATE AREA. SWEEP UP AND
PLACE IN BAG, HOLD FOR PROPER DISPOSAL. WEAR PROTECTIVE CLOTHING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN TIGHTLY SEALED CONTAINER, IN A
COOL, DRY AREA.
Other Precautions:AVOID INHALATION, INGESTION AND CONTACT WITH EYES AND
SKIN.
* Physical/Chemical Properties *
HCC:N1
Appearance and Odor:WHITE-YELLOWISH POWDER WITH A METALLIC ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HAS EXPLODED WHEN MIXED W/CHLORINATED RUB. REACTS VIOLENTLY
W/MAGNESIUM, LINSEED OIL. ZINC OXIDE & MAGNESIUM,(SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES.
* Disposal Considerations *
Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE
DISPOSAL AGENCY FOR REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT APPLICABLE. USE NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL, MECHANICAL & SPECIAL VENTILATION: NOT APPLICABLE.
Other Protective Equipment:EYEWASH AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA .
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:STAT TRAK PLUS CONTAINS NO HAZARDOUS MATERIALS AS DEFINED
BY THE OSHA HAZARD COMMUNICATION RULE.
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NOT APPLICABLE.
Explanation of Carcinogenicity:NO INDICATORS GIVEN.
Effects of Overexposure:NOT APPLICABLE.
Medical Cond Aggravated by Exposure:NOT APPLICABLE.
* First Aid Measures *
First Aid:NOT APPLICABLE. EYES: IMMEDIATELY FLUSH WITH POTABLE WATER
WITH COPIOUS AMOUNTS OF WATER. CALL MD . INHAL: REMOVE TO FRES H
AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . INGEST: CALL MD
IMMEDIATELY .
* Fire Fighting Measures *
Extinguishing Media:NOT APPLICABLE. USE MEDIA SUITABLE FOR SURROUNDING
FIRE .
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE.
* Accidental Release Measures *
Spill Release Procedures:NOT APPLICABLE.
*Handling and Storage *
Handling and Storage Precautions:NOT APPLICABLE.
* Physical/Chemical Properties *
Vapor Pres:NOT APPLICABLE.
Spec Gravity:NOT APPLICABLE.
Solubility in Water:NOT APPLICABLE.
Appearance and Odor:NOT APPLICABLE.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:NOT APPLICABLE.
* Disposal Considerations *
Waste Disposal Methods:NOT APPLICABLE. DISPOSE OF IN ACCORDANCE WITH
LOCAL, STATE, AND FEDERAL REGULATIONS .
* MSDS Transport Information *
Transport Information:THIS PRODUCT IS NON-HAZARDOUS. THE PRODUCT
CONTAINS NO KNOWN CARCINOGENS. NO SPECIAL WARNING LABELS ARE
APPLICABLE FOR THIS PRODUCT; TH EREFORE NO OSHA WARNING WOULD
APPEAR ON THE LABEL. NO EPA HAZARD CLASSIFICATION CODE.
* Regulatory Information *
Federal Regulatory Information:NFPA: HEALTH -1, FIRE-1, REACTIVITY-0:
HMIS HEALTH-1, FIRE-1, REACTIVITY-1: HAZARD RATINGS:
0=INSIGNIFICANT, 1=MODERATE, 2=HIGH.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF WORKING IN CONFINED SPACES &/EXPOSURE MAY OR
DOES EXCEED OCCUP EXPOS LIMITS USE A NIOSH/MSHA APPROVED RESPIRATOR
TO PREVENT OVEREXPOSURE.
Ventilation:SUFF VENT, IN VOL & PATTERN, SHOULD BE PROVIDED TO KEEP AIR
CONTAM BELOW CURRENT APPLIC OSHA PEL/ACGIH'S TLV LIMIT.
Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA. PROTECTIVE CLTHG AS REQD TO PVNT SKIN
CONTACT.
Work Hygienic Practices:WASH W/SOAP & WATER BEFORE EATING, DRINKING,
SMOKING OR USING TOILET FACILITIES. LAUNDER CONTAMD CLTHG BEFORE
REUSE.
Supplemental Safety and Health
TRADENAME/PART#: GRAY SOLVENT BASED. FIRE FIGHT PROC: UNCONFINED TAR
FIRES. DO NOT DIRECT STREAM OF WATER INTO BURNING LIQUID. OTHER
PREC: GENERATED DURING BURNING/DUSTS GENERATED DURING REMOVAL OF DR
Y COATINGS.
* Product Identification *
Preparer's Name:RAK
* Composition/Information on Ingredients *
OSHA PEL:N/K
ACGIH TLV:N/K
Fraction by Wt: 5%
Ingred Name:ALKYD RESIN
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE;(TITANIUM DIOXIDE)
Ingred Name:ALKYD RESIN
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: OVEREXP CAN LEAD TO CNS DEPRESS
PRDCG SUCH EFTS AS HDCH, DIZZ, NAUSEA & LOSS OF CONSCIOUSNESS. EYE:
SHORT-TERM CONTACT MAY RSLT IN SLIGHT EYE IRRIT. PRLNGD & RPTD CONT
MAY BE MORE IRRIT. SKIN: PRLNGD & RPTD LIQUID CONT CAN CAUSE
DEFATTING & DRYING OF SKIN WHICH MAY RESULT IN SKIN IRRIT & DERM.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: INHAL: HIGH CONCS/PRLNGD EXPOS TO
LOWER CONCS MAY BE SLIGHTLY IRRIT TO MUCOUS MEMBRANES.
Medical Cond Aggravated by Exposure:NONE.
* First Aid Measures *
OPEN. GET MED ATTN. SKIN: WASH W/SOAP & WATER. REMOVE CONTAMD CLTHG
& SHOES; DO NOT REUSE UNTIL CLEANED. IF PERSISTENT IRRIT OCCURS,
GET M ED ATTN. INHAL: REMOVE VICTIM TO FRESH AIR & PROVIDE O*2 IF
BRTHG IS DFCLT. GIVE ARTF RESP IF NOT BRTHG. GET MED ATTN. INGEST:
DO NOT INDUCE VOMITING!!
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:2.8%
Upper Limits:7.0%
Extinguishing Media:WATER FOG, DRY CHEMICAL, CO*2, FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
EVAC HAZ AREA OF UNPROT PERS. COOL FIRE-EXPOSED CNTNRS W/WATER.
WATER/FOG IS RECOMM FOR CONTROL OF(SUPDAT)
Unusual Fire/Explosion Hazard:VAPS ARE HVR/AIR & MAY ACCUM IN LOW AREAS
OR AREAS INADEQ VENTD. VAPS MAY ALSO TRAVEL ALONG GROUND TO BE
IGNITED AT LOCATIONS DISTANT FROM HANDLING SITE.
* Accidental Release Measures *
Spill Release Procedures:WARNING! FLAMM. ELIM ALL IGNIT SOURCES. HNDLG
EQUIP MUST BE GROUNDED TO PVNT SPARKING. LGE SPILLS: EVAC HAZARD
AREA OF UNPROT PERS. WEAR APPROPRIATE NIOSH/MSHA APPRVD RESP &
PROTECTIVE CLOTHING. DIKE & CONTAIN.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARK, OPEN
FLAME. KEEP CNTNRS TIGHTLY CLSD. STORE AWAY FROM STRONG OXIDIZING
AGENTS IN COOL, DRY PLACE W/ADEQ EXPLOS-PROOF VENT.
Other Precautions:GROUND EQUIP TO PVNT ACCUM OF STATIC CHARGE. IF
POURING/TRANFERRING MATLS, CNTNRS MUST BE BONDED & GROUNDED. DO NOT
WELD, HEAT/DRILL ON/NEAR CNTNRS; EVEN EMPTIED CNTNRS CAN CNTN
EXPLOS VAPS. PROVIDE R ESP PROT AGAINST SMOKE & FUMES (SUPDAT)
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY LIQUID W/HYDROCARBON ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE.
Stability Condition to Avoid:AVOID HEAT, SPARKS, AND OPEN FLAME.
Hazardous Decomposition Products:NONE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NUISANCE DUST MASK RECOMMENDED WHILE GRINDING
FIRED PORCELAIN.
Ventilation:MECHANICAL EXHAUST
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NICKEL (SOLUBLE)
INTENDED CHANGE (IC)
Fraction by Wt: <5%
Other REC Limits:1 MG/CUM
OSHA PEL:1 MG/CUM
Ingred Name:VANADIUM
Fraction by Wt: <5%
OSHA PEL:C,0.5 MG/M3
Ingred Name:ZINC OXIDE
Fraction by Wt: <5%
Ingred Name:ZIRCONIUM
Fraction by Wt: <5%
OSHA PEL:5 MG/CUM
ACGIH TLV:5 MG/CUM
Ingred Name:ALUMINUM OXIDE, BAUXITE, ALUMINA, DIALUMINUM TRIOXIDE
Fraction by Wt: <5%
Ingred Name:BARIUM (SOLUBLE COMPOUNDS)
Fraction by Wt: <5%
OSHA PEL:0.5 MG/CUM
ACGIH TLV:0.5 MG/CUM
Ingred Name:BORON OXIDE, TRIOXIDE
Fraction by Wt: <5%
Ingred Name:CALCIUM OXIDE; LIME
Fraction by Wt: <5%
OSHA PEL:5 MG/CUM
ACGIH TLV:2 MG/CUM
Ingred Name:MAGNESIUM OXIDE, MAGNESIA
Fraction by Wt: <5%
Ingred Name:SILICA, CRYSTALLINE - FUSED
Fraction by Wt: <5%
OSHA PEL:SEE TABLE Z3
Ingred Name:TIN (AS SN)
Fraction by Wt: <5%
OSHA PEL:2.0 MG/CUM
ACGIH TLV:2.0 MG/CUM
Ingred Name:TITANIUM DIOXIDE, TITANIUM(IV) OXIDE, TIO2
Fraction by Wt: <5%
Ingred Name:CHROMIUM METAL, CHROMIUM, CHROME (SUSPECTED A1 HUMAN
CARCINOGEN BY IARC, NTP & ACGIH)
Fraction by Wt: <5%
OSHA PEL:1 MG/CUM
ACGIH TLV:0.5 MG/CUM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:COBALT
Fraction by Wt: <5%
OSHA PEL:0.1 MG/M3;AS CO
Ingred Name:RED IRON OXIDE/IRON (III) OXIDE/FERRIC OXIDE/YELLOW FERRIC
OXIDE/METAL OXIDE/YELLOW IRON OXIDE/IRON OXIDE PIGMENT/IRON
Fraction by Wt: <5%
Ingred Name:MANGANESE, MN COMPOUNDS
Fraction by Wt: <5%
OSHA PEL:(C) 5 MG/M3 DUST
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Explanation of Carcinogenicity:CHROMIUM IS A SUSPECTED A1 HUMAN
CARCINOGEN BY ACGIH.
* Fire Fighting Measures *
Flash Point:NON-FLAMMABLE
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP SPILLED MATERIAL.
*Handling and Storage *
Other Precautions:AVOID BREATHING CERAMIC DUST. AVOID LICKING CERAMIC
APPLICATION BRUSH.
* Physical/Chemical Properties *
Evaporation Rate & Reference:0
Solubility in Water:INSOLUBLE
Appearance and Odor:WHITE OR LIGHT PASTEL COLORED PORCELAIN POWDER W/NO
ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HYDROFLUORIC ACID
* Disposal Considerations *
Waste Disposal Methods:DISPOSE AS SOLID WASTE IN ACCORDANCE W/LOCAL,
STATE, & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN . AVOID PROLONGED BREATHING OF FUMES.
Ventilation:LOCAL EXHAUST:PROVIDE ADEQUATE VENTILATION.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:USE NORMAL GOOD HYGIENIC PRACTICES. LAUNDER
CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ETHANOL, 2-BUTOXY-; (BUTYL OXITOL)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION:DO NOT INHALE! SIGNS AND
SYMPTOMS:INHALATION:POSSIBLE DIZZINESS AND LIGHT HEADEDNESS;
EYES:RED AND WATERING. CHRONIC:ANIMAL STUDIES CLEARLY DEMONSTRATED
DOSE-RELATED ADVERSE EFFECTS ON THE CNS, THE HEMATOPOIETIC
TISSUES, THE BLOOD, THE KIDNEYS AND LIVER, ASSOCIATED WITH THE
ADMINISTRATION (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:OF ETHYLENE GLYCOL MONOBUTYL ETHER
Medical Cond Aggravated by Exposure:INHALATION:MAY CAUSE HEADACHE,
EYES:MAY CAUSE IRRITATION.
* First Aid Measures *
First Aid:INGESTION:CALL MD IMMEDIATELY . SKIN:FLUSH W/COPIOUS AMOUNTS
OF WATER. CALL MD . INHALATION:REMOVE TO FRESH AIR, SEEK MEDICAL
ATTENTION IF CONDITION PERSISTS. EYES:FLUSH WITH WATER FOR AT
RELIEVED.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
* Accidental Release Measures *
Spill Release Procedures:SCOOP UP MATERIAL AND PLACE IN TRASH
CONTAINER. CONTAIN SPILL WITH SAND, DIRT OR SAWDUST.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM HEAT, KEEP CONTAINER
CLOSED AFTER USE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN AND PETS!
* Physical/Chemical Properties *
Vapor Density:1
Solubility in Water:SLIGHT
Appearance and Odor:WHITE PASTE WITH SLIGHT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
LIQUID OXYGEN; LIQUID SODIUM, GASEOUS FLUORINE.
Stability Condition to Avoid:LIQUID OXYGEN SYSTEMS, SOURCES OF
IGNITION.
Hazardous Decomposition Products:NONE.
Conditions to Avoid Polymerization:STRONG OXIDIZING AGENTS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE MATERIAL ACCORDING TO
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF AIRBORNE DUST LEVELS ARE HIGH A NIOSH APPRVD
DUST MASK IS RECOMMENDED TO AVOID INHALATION.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:LONG-SLEEVED SHIRT & LONG PANTS, WATERPROOF
SHOES PLUS SOCKS. ANSI APPRVD EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:FOLLLOW MFR'S INSTRUCTIONS FOR
CLEANING/MAINTAINING PPE. IF NO SUCH INSTRUCTION FOR WASHABLES, USE
DETERGENT (SUPDAT)
Supplemental Safety and Health
HAZ DECOMP PROD:ALSO POSSIBLE. HYGIENE PRACT:AND HOT WATER. KEEP AND
WASH PPE SEPARATELY FROM OTHER LAUNDRY.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ANILINE, 3,4-DIMETHYL-2,6-DINITRO-N-(1- ETHYLPROPYL)-;
N-(1-ETHYLPROPYL)-3,4-DIMETHYL-2,6- DINITROBENZENAMINE (ING 2)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ING 1:(PENDLMETHANLIN))
Ingred Name:POTASSIUM CHLORIDE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SULFUR
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:UREA
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:AMMONIUM PHOSPHATE MONOBASIC; (AMMONIATED PHOSPHATE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:NUISANCE DUST
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:POSSIBLE NAUSEA, VOMITING, AND
DIARRHEA. MAY IRRITATE EYES, NOSE, THROAT, AND SKIN. POSSIBLE EYE
LISTED BY MANUFACTURER.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SKIN ABRASIONS AND SORE. INHALATION
OF DUST MAY AGGRAVATE ASTHMA.
* First Aid Measures *
OPEN. GET MED ATTN IF IRRIT PERSISTS. SKIN:WASH THOROUGHLY. IF
IRRIT PERSISTS, GET MED ATTN. INHAL:REMOVE TO FRESH AIR. TREAT
SYMPTOMATICA LLY. CALL PHYS. INGEST:RINSE MOUTH & GIVE 2 GLASSES OF
MILK/WATER & SALINE LAXATIVE. DO NOT INDUCE VOMITING. GET MEDICAL
ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, WATER FOG, FOAM, CO*2. CONTAIN RUNOFF
AS ACTIVE INGREDIENT IS TOXIC TO AQUATIC ORGANISMS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:SULFUR DUST CAN FORM EXPLOSIVE MIXTURES
WITH AIR. IF PRODUCT IS CONSUMED IN A FIRE, TOXIC SULFUR DIOXIDE
WILL FORM.
* Accidental Release Measures *
Spill Release Procedures:READ LABEL. SWEEP UP SPILLS. AVOID CONTACT
WITH SKIN, EYES, OR CLOTHING. WASH HANDS AFTER HANDLING. USE GOOD
HOUSEKEEPING PRACTICES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:READ LABEL FOR STORAGE & DISPOSAL
INSTRUCTIONS. AVOID BAG BREAKAGE, KEEP AWAY FROM FEED OR
FOODSTUFFS. AVOID CONTACT WITH SKIN, EYES, OR CLOTHING.
Other Precautions:WASH AFTER HANDLING. KEEP OUT OF REACH OF CHILDREN.
KEEP OUT OF LAKES, STREAMS, OR PONDS. AVOID CONTAMINATION WITH
OXIDIZING AGENTS OR STRONG ALKALI.
* Physical/Chemical Properties *
Appearance and Odor:GRANULAR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTACT WITH STRONG OXIDIZING AGENTS OR FIRE.
Stability Condition to Avoid:CONTACT WITH STRONG OXIDIZING AGENTS OR
FIRE.
Hazardous Decomposition Products:IN FIRE, THERM DECOMP OF UREA &
METHYLENE UREAS WILL GENERATE AMMONIA. OXIDES OF NITROGEN, SULFUR &
CARBON ARE (SUPDAT)
* Disposal Considerations *
Waste Disposal Methods:READ LABEL. DISPOSE OF SMALL WASTE QUANTITIES
ACCORDING TO LABEL DIRECTIONS. FOR LARGE QUANTITIES OF WASTE,
CONSULT FEDERAL, STATE AND LOCAL WASTE OFFICIALS.
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* Exposure Controls/Personal Protection *
PROTECTION FOR LEAD.WELL-VENTILATED AREA,RESPIR PROTECT NOT
REQUIRED.RESTRICTED AREA,NIOSH APPROVED CHEM CART RESPIR MAY BE
REQUIRED.CONFINED AREA,NIOSH/MSH A APPROVED AIR-SUPPLIED RESPIR.
Ventilation:PROVIDE GENERAL DILUTION & LOCAL EXHAUST VENTILATION.
Other Protective Equipment:AS REQUIRED TO PREVENT SKIN CONTACT. SEE
OSHA STANDARD FOR LEAD
Supplemental Safety and Health
CONTACT.
* Product Identification *
Preparer's Name:W. A. ELLISON
* Composition/Information on Ingredients *
Ingred Name:VM&P NAPHTHA (LIGROINE)
Ingred Name:MINERAL SPIRITS
Ingred Name:CARBON BLACK
OSHA PEL:3.5 MG/M3
Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE
OSHA PEL:SEE TABLE Z3
Ingred Name:SILICA, CRYSTALLINE - FUSED
OSHA PEL:SEE TABLE Z3
Ingred Name:TALC (CONTAINING NO ASBESTOS)
OSHA PEL:2 MG/M3 RDUST
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:REPEATED EXPOSURE TO CRYSTALLINE
SILICA MAY CAUSE PNEUMOCONIOSIS,A PROGRESSIVELY DISABLING LUNG
DISEASE;RELATIVELY INSOLUBLE CHROMATES MAY CAUSE LUNG
CANCER;CHRONIC OVEREXPOSURE TO LEAD MAY RESULT IN DAMAGE TO BLOOD
FORMING,NERVOUS,URINARY& REPRO SYSTEM;SOLVENT HAVE BEEN ASSOCIATED
WITH PERM BRAIN & NERVOUS SYS DAMAGE
Explanation of Carcinogenicity:CHROM & CERTAIN CHROM COMP ARE LISTED AS
POTENTIAL CARCIN BY NTP & IARC. LEAD CHROM POTENTIAL ANIMAL CARCIN
BY IARC.
Effects of Overexposure:SWALLOWING-GASTROINTESTINAL IRRITATION, NAUSEA
& VOMITING.ASPIRATION OF MATERIAL INTO LUNG MAY CAUSE CHEMICAL
PNEUMONITIS WHICH CAN BE FATAL.INHALED-MAY CAUSE NOSE & THROAT
IRRITATION. HIGH CONCENTRAT IONS MAY CAUSE ACUTE NERVOUS SYSTEM
DEPRESS.EYE-MAY CAUSE EYE IRRITATION.SKIN-MAY CAUSE DEFATTING AND
IRRITATION OF SKIN
Medical Cond Aggravated by Exposure:PRE-EXISTING KIDNEY CONDITION MAY
BE AGGRAVATED BY EXPOSURES TO LEAD; PRE-EXISTING RESPIRATORY
CONDITION MAY BE AGGRAVATED BY EXPOSURE TO CRYSTALLINE SILICA.
* First Aid Measures *
First Aid:IF SWALLOWED-DO NOT INDUCE VOMITING. CALL POISON CONTROL
CENTER, HOSPITAL EMERG ROOM OR MD IMMED. INHALED-REMOVE TO FRESH
AIR IMMED. IF BREATHING HAS STOPPED, GIVE ARTIFICIAL RESPIRATION.
KEEP WARM & QUIET. MED ATTN IMMED. EYE-FLUSH WITH LARGE AMOUNTS OF
CLOTHING. WASH AFFECTED AREA WITH SOAP & WATER. MED ATTN IF
IRRITATION PERSISTS.
* Fire Fighting Measures *
Extinguishing Media:NFPA CLASS B FIRE EXTINGUISHER DESIGNED TO
EXTINGUISH FLAMMABLE LIQUID FIRES. POLYMER FOAM PREFERRED FOR LARGE
FIRES.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS. WATER
MAY BE INEFFECTIVE, BUT MAY BE USED TO PREVENT PRESSURE BUILD-UP.
IF WATER IS USED, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:OVEREXPOSURE TO DECOMP PROD MAY CAUSE A
HEALTH HAZARD.OBTAIN MED ATTN.KEEP CONTAINER TIGHTLY CLOSED.ISOLATE
FROM HEAT, ELEC EQUIP, SPARKS & FLAME.
* Accidental Release Measures *
Spill Release Procedures:KEEP SPECTATORS AWAY. ELIM ALL IGNITION
SOURCES. DIKE & CONTN SPILL WITH INERT MATL. TR LQDS TO COV MTL
CNTNR FOR RECOV OR DISP OR REM W/INERT ABSORB. USE NON-SPRKG
TOOLS.PLACE ABSORB MAT IN COV METAL CONTNR FOR DISP.PREVENT CONTAM
OF SEW,STRMS,ETC
*Handling and Storage *
Other Precautions:DO NOT TAKE INTERNALLY. CLOSE CONTAINER AFTER EACH
USE. DO NO BREATHE SANDING DUST. DO NOT WASH AND RE-USE CONTAINERS
FOR ANY PURPOSE. DO NOT WELD, BRAZE OR CUT ON EMPTY CONTAINER.
NEVER USE PRESSURETO EMPTY.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:2
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT AND SOURCES OF
IGNITION.
Hazardous Decomposition Products:BURNING, WHEN HEATED BY WELDING OR
CUTTING, WILL PRODUCE SMOKE, CARBON MONOX & CARBON DIOX. MAYBE
OXIDES OF LEAD.
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT SPARKS AND
FLAME.
* Disposal Considerations *
Waste Disposal Methods:IAW FED, STATE & LOCAL LAWS. INCINERATE ONLY IN
EPA PERMITTED FACILITY. DO NOT INCINERATE CLOSED CONTAINERS.
OBSERVE PRECAUTIONS FOR DISPOSAL OF FLAMMABLE MATERIALS.
CONTAMINATED ABSORBANT MAY BE DISP OSED IN A HAZARDOUS WASTE
LANDFILL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERS EXPOS CANNOT BE CONTROLLED BELOW APPLIC
LIMS BY VENT, WEAR A PROPERLY FITTED ORG VAP/PARTICULATE RESP
APPRVD BY NIOSH FOR PROT AGAINST MATLS IN SECTION 2. WHEN
SANDING/ABRADING DRIED FILM, WEA R A DUST/MIST RESP APPRVD BY NIOSH
FOR PROT AGAINST MATLS IN SECTION 2. WHEN SANDING/ABRADING THE
DRIED FILM, WEAR A DUST/MIST RESP APPRVD BY NIOSH FOR (SUPDAT)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF THE EXPOS TO MATLS
IN SECTION 2 IS MAINTAINED BELOW APPLIC EXPOS LIMS. REFER TO OSHA
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART #:CAULKS, SPACKLING COMPOUNDS, FILLER & SEALANTS.
RESPIRATORY PROTECTION: PROTECTION AGAINST NON-VOLATILE MATERIALS
IN SECTION 2.
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: 1%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (CALCIUM CARBONATE)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRITATION OF EYES, SKIN AND
RESPIRATORY SYSTEM. IN A CONFINED AREA VAPORS IN HIGH CONCENTRATION
MAY CAUSE HEADACHE, NAUSEA OR DIZZINESS. SIGNS AND SYMPTOMS OF
OVEREXPOSURE: REDNESS AND ITCHING OR BURNING SENSATION MAY
INDICATE EYE OR EXCESSIVE SKIN EXPOSURE. CHRONIC: ETHYLENE GLYCOL
IS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: CONSIDERED AN ANIMAL TERATOGEN. IT
HAS BEEN SHOWN TO CAUSE BIRTH DEFECTS IN RATS AND MICE AT HIGH
DOSES WHEN GIVEN IN DRINKING WATER OR BY SAVAGE. THERE IS NO
EVIDENCE TO INDICATE IT CAUSES BIRTH DEFECTS IN HUMANS. PROLONGED
OVEREXPOSURE TO ETHYLENE GLYCOL MAY CAUSE ADVERSE EFFECTS TO THE
REPRODUCTIVE SYSTEM.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND
QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH
MEDICAL ATTENTION. INGEST: SEEK MEDICAL ATTENTION IMMEDIATELY.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . WATER SPRAY MAY BE INEFFECTIVE. IF H*2O IS USED, FOG
NOZZLES ARE PREFERED. H*2O MAY BE USED TO COOL CLOSED CONTAINERS TO
PREVENT PRESSURE BU ILD-UP & POSSIBLE AUTOIGNITION OR EXPLOSION
WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO THE
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AND REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAINERS WITH COMPLETE AND APPROPRIATE
LABELING. DO NOT TAKE INTERNALLY.
KNOWN TO THE STATE OF CA TO CAUSE CANCER.
* Physical/Chemical Properties *
Vapor Pres:SEE INGRED
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM THESE PRODUCT IS NOT HAZARDOUS AS
FEDERAL, STATE, AND LOCAL REGULATIONS REGARDING POLLUTION.
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* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SPILL PROC: ENTER WATERWAYS, GROUNDWATER, OR SEWER SYSTEMS. EYE PROT:
FULL LENGTH FACESHIELD.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM HYDROXIDE
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3
Ingred Name:PHOSPHATE ESTER
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: PRODUCT IS STRONGLY ALKALINE;
CONTACT W/SKIN/EYES MAY CAUSE SEVERE BURNS. PERMANENT EYE DAMAGE OR
BLINDNESS MAY OCCUR. HARMFUL IF INGESTED. INHALATION OF DUSTS/MISTS
MAY IRRITATE RESPIRATORY TR ACT. CHRONIC: NONE KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:EXISTING SKIN AND RESPIRATORY
DISORDERS MAY BE AGGRAVATED BY EXPOSURE.
* First Aid Measures *
MINUTES. IF IRRIT OCCURS, SEEK MED ATTN. SKIN: WASH THORO WITH
OBTAIN MEDATTN. REMOVE AND LAUNDER CONTAMD CLTHG BEFORE REUSE.
INGEST: DRINK WATER TO DILUTE. SEEK IMMED MED ATTN. DO NOT INDUCE
VOMIT. INHAL: REMOVE FROM EXPOS. IF DISCOMFORT OCCURS & PERSISTS,
SEEK MED ATTN.
* Fire Fighting Measures *
Flash Point:NON-COMBUSTIBLE
Extinguishing Media:USE MEDIA APPROPRIATE TO PRIMARY CAUSE OF FIRE.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
AVOID CONT W/FIRE FIGHTING PERS AS BURNS MAY RSLT FROM CONT W/SKIN.
USE SPRAY TO COOL NEARBY CONTRS.
Unusual Fire/Explosion Hazard:NONE KNOWN.
* Accidental Release Measures *
Spill Release Procedures:APPROP PROT CLTHG & EQUIP MUST BE WORN BY
CLEAN-UP PERS. CNTN SPILLAGE IN SUITABLE CONTRS/HOLDING AREA. MATL
THAT CANNOT BE CNTND SHOULD BE ABSORBED W/INERT MATL SUCH AS
DIATOMACEOUS EARTH & PLACED IN SUITABLE CONTR. DO NOT ALLOW SPILL
TO (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:C2
Spec Gravity:>1(H*2O=1)
Solubility in Water:COMPLETELY SOLUBLE
Appearance and Odor:CLEAR BLUE LIQUID WITH MILD ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:CONTACT AND STORAGE NEXT TO INCOMPATIBLE
MATERIAL.
Hazardous Decomposition Products:NONE KNOWN.
* Disposal Considerations *
Waste Disposal Methods:IF MATL CANNOT BE SALVAGED, A POSS METH OF DISP
IS NEUT FOLLOWED BY DISCHARGE INTO A TRTMT SYS I/A/W LOC, ST & FED
REGS. SOLUTIONS WHICH ARE NOT NEUTRALIZED MUST BE DISPOSED OF AS
HAZARDOUS WASTE I/A/ W LOCAL, STATE FEDERAL LAW .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED WHERE ADEQUATE VENTILATION
CONDITIONS EXIST. IF AIRBORNE CONCENTRATION IS HIGH, USE AN
APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR OR DUST MASK.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
FUME OR DUST LEVELS AS LOW AS POSSIBLE.
Other Protective Equipment:WEAR UNIFORM.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ZINC NITRATE (6-HYDRATE)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION OF DUST MAY CAUSE
IRRITATION OF UPPER RESPIRATORY TRACT. CONTACT WITH SKIN OR EYES
MAY CAUSE IRRITATION. INGESTION MAY CAUSE NAUSEA AND VOMITING.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.
* First Aid Measures *
First Aid:INGEST: IF SWALLOWED, IF CONSCIOUS, IMMEDIATELY INDUCE
VOMITING. INHAL: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
MINUTES. SKIN: FLUSH WITH WATER. ALL EXPOSURES: CALL MD.
* Fire Fighting Measures *
Extinguishing Media:USE WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE
WATER TO KEEP FIRE-EXPOS CNTNRS COOL.
Unusual Fire/Explosion Hazard:CAN REACT VIOLENTLY WITH SHOCK, FRICTION
OR HEAT. STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE
FIRE.
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH/MSHA SCBA & FULL PROT CLOTHING.
KEEP COMBUSTIBLES (WOOD, PAPER, OIL, ETC.) AWAY FROM SPILLED
MATERIALS. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL INTO CLEAN,
DRY CONTAINERS AND COVER; REM OVE FROM AREA. FLUSH SPILL AREA WITH
WATER.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD. STORE
SEPARATELY & AWAY FROM FLAMM & COMBUST MATLS. ISOLATE FROM INCOMPAT
CONTACT WITH CLOTHING & OTHER COMBUSTIBLE MATERIALS. AVOID CONTACT
WITH EYES, SKIN, CLOTHING. AVOID BREATHING DUST. USE WITH ADEQUATE
VENTILATION.
* Physical/Chemical Properties *
HCC:D1
Vapor Density:8.4
Appearance and Odor:WHITE CRYSTALS; ODORLESS.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG REDUCING AGENTS, COMBUSTIBLE MATERIALS, ORGANIC MATERIALS,
STRONG ACIDS, STRONG BASES.
Stability Condition to Avoid:HEAT, FLAME, SHOCK, FRICTION.
Hazardous Decomposition Products:OXIDES OF NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE AND
LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NORMALLY NOT NEEDED. OVEREXPOSURE WEAR NIOSH
APPROVED RESPIRATOR FOR ORGANIC VAPORS.
Ventilation:MECHANICAL IS ACCEPTABLE, LOCAL IS PREFERRED.
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA .
Supplemental Safety and Health
PHYSICAL DATA:LIQUID DENSITY: HEAVIER THAN WATER.
* Product Identification *
Preparer's Name:DE DE NAGLE
* Composition/Information on Ingredients *
Ingred Name:POLYETHERETHERKETONE (PEEK) (NO HAZARDOUS INGREDIENTS KNOWN
AT THIS TIME TIME)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: ACUTE OR IMMEDIATE EFFECTS,
ROUTES OF ENTRY AND SYMPTOMS: INGESTION: NOT A PROBABLE ROUTE OF
EXPOSURE. SKIN: PELLETS NOT LIKELY TO CAUSE IRRITATION. CONTACT
WITH MOLTEN MATERIAL MAY CAUSE THERM AL BURNS. EYE: SOLID/DUST MAY
CAUSE IRRITATION TO THE EYES, SKIN, AND RESPIRATORY TRACT. CHRONIC:
NONE KNOWN.
Effects of Overexposure:SEE HEALTH HAZARDS.
* First Aid Measures *
First Aid:INGESTION: CALL MD IMMEDIATELY . EYES: FLUSH WITH WATER FOR
WASH WITH SOAP AND WATER. FOR THERMAL BURNS-IMMEDIATELY FLUSH WITH
C OLD WATER. DO NOT ATTEMPT TO REMOVE POLYMER FROM SKIN. OBTAIN
MEDICAL ATTENTION. INHALATION: LEAVE EXPOSED AREA, SEEK MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:FLAMMABILITY CLASS 1. WATER SPRAY & FOAM. WATER
SPRAY IS PREFERRED. DRY CHEMICAL & CO*2 ARE NOT GENERALLY
RECOMMENDED DUE TO THEIR LACK OF COOLING CAPACITY WHICH MAY ALLOW
RE-IGNIT.
Fire Fighting Procedures:PERSONS EXPOSED TO PRODUCTS OF COMBUSTION
SHOULD WEAR NIOSH APPROVED SELF CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:AIRBORNE DUSTS MAY BE EXPLOSIVE IN THE
PRESENCE OF A HIGH TEMPERATURES SOURCE OF IGNITION.
* Accidental Release Measures *
Spill Release Procedures:SPILLS ARE A SLIPPING HAZARD-SWEEP AREA AS
NEEDED.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A DRY SPRINKLER EQUIPPED
WAREHOUSE.
Other Precautions:PROPER PURGING AND SHUT DOWN PROCEDURES SHOULD BE
FOLLOWED TO AVOID OVERHEATING OF MATERIAL.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:NONE
Vapor Density:NON VOLAT
Evaporation Rate & Reference:UNAVAILABLE
Appearance and Odor:CYLINDRICAL PELLETS. NO ODORS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONCENTRATED SULPHURIC ACID.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:CARBON DIOXIDE - DIOXIDE AND OTHER
HARMFUL PRODUCTS.
* Disposal Considerations *
Waste Disposal Methods:THE PELLETS, REGRIND, AND PURGE OF THIS MATERIAL
ARE NON-HAZARDOUS AND MAY BE DISCARDED IN ACCORDANCE WITH STATE,
FEDERAL, AND LOCAL REGULATIONS.
* Regulatory Information *
SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
Federal Regulatory Information:ALL INGREDIENTS IN THIS PRODUCT ARE
LISTED IN THE T.S.C.A. INVENTORY.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE ENVIRONMENTAL CONTROLS ARE LACKING OR IN
ENCLOSED SPACES USE A NIOSH MSHA APPROVED RESPIRATOR FOR ACID GASES
AND ORGANIC VAPORS.
Ventilation:LOCAL VENTILATION AT THE WORKSITE;MECHANICAL(GENERAL)
VENTILATION TO MAINTAIN TLV/PEL.
Other Protective Equipment:LONG PANTS,LONG SLEEVED SHIRTS.PROVIDE LOCAL
EYE WASH AND QUICK DRENCH SHOWER.
Work Hygienic Practices:USE REASONABLE CARE IN HANDLING THIS
PRODUCT.WASH HANDS AFTER USE AND BEFORE EATING.
Supplemental Safety and Health
NONE
* Product Identification *
Preparer's Name:PRODUCT STEWARDSHIP
* Composition/Information on Ingredients *
Ingred Name:STYRENE BUTADIENE (POLYMER WITH INGREDIENTS 2 AND 3)
Other REC Limits: RECOMMENDED
Ingred Name:POLYPHENYLENE OXIDE
Other REC Limits: RECOMMENDED
Ingred Name:TRIPHENYL PHOSPHATE
Other REC Limits: RECOMMENDED
OSHA PEL:3 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES:MAY CAUSE IRRITATION OR
INJURY.SKIN:MOLTEN MATERIAL MAY CAUSE BURNS.INHAL:FUMES MAY DAMAGE
BLOOD FORMING ORGANS.INGEST:UNLIKELY ROUTE OF ENTRY.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:EYES:IRRITATION.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING DISEASES
OF THE BLOOD FORMING ORGANS MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH WATER.SEEK
MEDICAL ATENTION IF RASH OCCURS.FOR BURNS,COOL WITH WATER;DO NOT
MINUTES.INHAL: REMOVE TO FRESH AIR.GIVE OXYGEN OR ARTIFICIAL
RESPIRATION IF NEEDED.INGEST:UNLIKELY ROUTE OF EXPOSURE.
* Fire Fighting Measures *
Flash Point:
Extinguishing Media:WATER SPRAY,FOAM.CARBON DIOXIDE AND DRY CHEMICAL
ARE NOT RECOMMENDED.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.COOL FIRE EXPOSED CONTAINERS WITH WATER
FOG.
Unusual Fire/Explosion Hazard:FIRE CONDITIONS MAY EVOLVE TOXIC FUMES.
* Accidental Release Measures *
Spill Release Procedures:SWEEP INTO AN APPROPRIATE CONTAINER FOR
DISPOSAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL,DRY,WELL-VENTILATED
PLACE.KEEP CONTAINER CLOSED WHEN NOT IN USE.USE WITH ADEQUATE
VENTILATION.
Other Precautions:DUST FROM GRINDINGS MAY CREATE FLAMMABLE MIXTURES
WITH AIR.
* Physical/Chemical Properties *
HCC:N1
Vapor Pres:NEGLIGIBLE
Spec Gravity:>1
Evaporation Rate & Reference:NEGLIGIBLE
Solubility in Water:NEGLIGIBLE
Appearance and Odor:PLASTIC PELLETS;SLIGHT ODOR.COLOR NOT REPORTED.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT REPORTED.
Stability Condition to Avoid:HIGH HEAT,SOURCES OF IGNITION.
Hazardous Decomposition Products:TRIARYLPHOSPHATE
ESTERS,PHENOL,STYRENE,ALIPHATIC
AMINES,ALDEHYDES,ALCOHOLS,TOLUENE,ETHYL BENZENE,4-VINYLCYCLOHEXANE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
BIS(4-CYCLOHEXYLISOCYANATE))
% Wt: <1
------------------------------
% Wt: <2
------------------------------
------------------------------
% Wt: <5
------------------------------
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TOLUENE APPEARS ON NAVY LIST OF OCCUP CHEM REPROD HAZS.
SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING LATEST HAZ LIST
INFO & SAFE HNDLG & EXPOS INFO (FP N). ACUTE:EYE:CAUSES IRRIT. SKIN:
MAY BE ABSORB THRU SKIN IN HARMFUL AMTS. MAY CAUSE SKIN SENSITIZ. MAY CAUSE
DERM. CAUSES IRRIT. INHAL: POSS IRRIT OF RESP SYS CAN OCCUR CAUSING VARIETY
OF SYMPS SUCH AS DRYNESS OF THROAT, TIGHTNESS OF CHEST, & SHORTNESS OF
BREATH. ALLERGIC CNDTNS CAN OCCUR IN CERTAIN INDIVIDUALS W/HIGH SENSITIVITY
TO ISOCYANATES; THIS MAY RSLT IN ASTHMA-LIKE SYMPS. MAY CAUSE CNS DEPRESS
CHARACT BY FOLLOWING PROGRE SSIVE STEPS: HDCH, (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: HLTH HAZ: DIZZ, STAGG GAIT, CONFUSN,
UNCON/COMA. MAY CAUSE RESP SENSITIZ. MAY CAUSE LUNG DMG. INGEST:HARMFUL IF
SWALLOWED. INGEST IS NOT EXPECTED RTE OF ENTRY IN INDUST/COMMERCIAL USES.
CHRONIC:MAY CA USE LIVER/KIDNEY DMG. PRTD/PRLNGD SOLV OVEREXP MAY RSLT IN
PERM CNS DMG. MAY CAUSE LONG-TERM LUNG DMG. MAY AFFECT GI SYS, BLOOD &
BLOOD-FORMING ORGANS. CHRONIC:SKIN CONT MAY CAUSE DERM.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
EYELIDS OPEN WHILE FLUSHING. GET PROMPT MED ATTN. SKIN:FLUSH CONTAMD SKIN
W/LG AMTS OF WATER WHILE REMOVING CONTAMD CLTHG. WASH AFFECTED S KIN AREAS
W/SOAP & WATER. GET MED ATTN IF SYMPS OCCUR. INHAL:MOVE PERSON TO FRESH
AIR. RESTORE & SUPPORT CONTINUED BRTHG. IF BRTHG IS DFCLT, GIVE OXYG. GET
IMMED MED ATTN. INGEST:IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE VICTIM 1-2
GLASSES OF WATER/MILK. CALL PHYS/POIS CTL CTR IMMED FOR FURTHER INSTRUCTION.
NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON.
*
Handling and Disposal
*
Spill Release Procedures: KEEP NON-ESSNTL PERS SAFE DIST AWAY FROM SPILL AREA.
REMOVE ALL SOURCES OF IGNIT (FLAME, HOT SURFS, & ELEC, STATIC/FRICTIONAL
SPRAKS). AVOID BRTHG VAPS. USE NIOSH/MSHA APPRVD SCBA. NOTIFY APPROP AUTH IF
NEC. CNTN & REMOVE W/INERT ABSORB MATL & NON-SPK TOOLS. AVOID CONT.
BEFORE CLEANUP, REFER TO HAZ CAUTION INFO IN OTHER SECTIONS OF MSDS FORM.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSAL SHOULD BE DONE IN ACCORDANCE WITH FEDERAL
DETERM TO BE HAZ, USE LICENSED HAZ WASTE TRANSPORTER & DISPOSAL FACILITY.
Handling And Storage Precautions: KEEP CLOSURE TIGHT & CNTNR UPRIGHT TO
PVNT LEAKAGE. GROUND & BOND CNTNRS WHEN TRANSFERRING MATL. AVOID SKIN
& EYE CONT. WASH THORO AFTER HANDLING.
Other Precautions: AVOID BRTHG VAP/SPRAY MISTS. DO NOT HNDL UNTIL ALL SFTY PREC
ARE READ & UNDERSTOOD. EMPTY CNTNRS SHOULD NOT BE REUSED. USE W/ADEQ
VENT. BECAUSE EMTPY CNTNRS MAY RETAIN PROD RESIDUE & FLAM VAPS, KEEP A
WAY FROM HEAT, SPK & FLAME; DO NO CUT, PUNCTURE/WELD ON/NEAR EMPTY CNTNR.
DO NOT SMOKE WHERE PROD IS USED OR (SUPDAT)
*
Fire and Explosion Hazard Information
*
Flash Point Method: SCC
Lower Limits: 1.0%
Extinguishing Media: CO*2, DRY CHEMICAL, FOAM, WATER FOG.
Fire Fighting Procedures: NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP N).
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZ ARE PREF. DURING
FIRE, IRRITATING &/OR TOX GASES & PARTICULATE MAY BE GENERATED BY
THERM DECOMP /COMBUST.
Unusual Fire/Explosion Hazard: FLAM LIQ & VAP. KEEP CNTNRS TIGHTLY CLSD.
ISOLATE FROM HEAT, ELEC EQUIP, SPARKS, OPEN FLAME, & OTHER SOURCES OF
IGNIT. CLSD CNTNRS MAY RUPTURE WHEN EXPOS TO EXTREME HEAT. USE WATER SPRAY TO
KEEP FIRE EXPOS CNTNRS COOL.
*
*
Respiratory Protection: PROD CNTNS ISOCYANATES WHICH HAVE POOR ODOR WARNING
PROPERTIES. IF OCCUP EXPOS LIMS ARE EXCEEDED, NIOSH/MSHA APPRVD SUPPLIED-AIR
Ventilation: SUFFICIENT VENT IN PATTERN & VOL SHOULD BE PROVIDED IN ORDER
TO MAINTAIN AIR CONTAMINANT LEVS BELOW REC EXPOS LIMS. CAUTION:SOLV VAPS ARE
HVR/AIR & (SUPDAT)
Other Protective Equipment: EYE WASH FOUNTAIN & DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). DISPOSABLE/IMPERVIOUS CLTHG IF WORK CLTHG CONTAM IS
LIKELY. REMOVE & WASH CONTAMD CLTHG BEFORE REUSE. WHEN SPRAY- (OTHER INFO)
Work Hygienic Practices: WASH HANDS BEFORE EATING, SMKNG/USING TOILET FACILITY.
DO NOT SMOKE IN ANY CHEM HNDLG/STOR AREA. FOOD/BEVERAGES SHOULD NOT BE
CONSUMED ANYWHERE PROD IS HNDLD/STORED. WASH THORO AFTER HANDLING.
Supplemental Safety and Health: OTHER PRECS: STORED. DO NOT STORE/USE NEAR
FOR SPECIFIC STOR REQS. STORE ONLY IN WELL-VENT AREAS. DO NOT PUNCTURE,
DRAG/SLIDE C NTNR. KEEP CNTNR CLSD WHEN NOT IN USE. VENT: COLLECT IN LOWER
LEVS OF WORK AREA. SUFFICIENT VENT (USING (OTHER INFO)
*
Physical/Chemical Properties
*
Vapor Density: HVR/AIR
Evaporation Rate & Reference: SLOWER THAN ETHER
Solubility in Water: INSOLUBLE
Appearance and Odor: BLACK LIQUID, SOLVENT ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: HIGH TEMPERATURES. SOURCES OF IGNITION.
Materials To Avoid: AMINES, ACIDS, WATER, HYDROXYL, OR ACTIVE HYDROGEN
COMPOUNDS.
Hazardous Decomposition Products: MONOMERIC ISOCYANATE, TRACES OF HYDROGEN
CYANIDE, NITROGEN DIOXIDE. CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
Other Information: SUPDAT: EXPLO- PROOF EQUIP) SHOULD BE PROVIDED TO PVNT FLAM
VAP/AIR MIXTURES FROM ACCUMULATING. OTHER PROT EQUIP: APPLYING MATL &
EXPOS TO OVERSPRAY MAY OCCUR, IMPERVIOUS PROT CLTHG, INCLDG HEAD COVER ING
*
HAZCOM Label
*
Assigned IND: Y
Company Name: LORD CORP
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAM. AVOID H*2O.ACUTE:EYE:CAUSES IRRIT. SKIN:MAY BE
ABSORB THRU SKIN IN HARMFUL AMTS. MAY CAUSE DERM. INHAL:POSS IRRIT OF RESP
SYS CAN OCCUR CAUSING VARIETY OF SYMPS AS DRYNESS OF THROAT, TIGHTNESS O F
CHEST, & SHORTNESS OF BREATH. ALLERGIC CNDTNS CAN OCCUR IN CERTAIN
INDIVIDUALS W/HIGH SENSITIVITY TO ISOCYANATES; MAY RSLT IN ASTHMA-LIKE SYMPS.
MAY CAUSE CNS DEPRESS CHARACT BY FOLLOWING PROGRESSIV E STEPS:HDCH, DIZZ,
STAGG GAIT, CONFUSN, UNCON/COMA. MAY CAUSE LUNG DMG. CHRONIC:TOLUENE APPEARS
ON NAVY LIST OF OCCUP REPROD HAZ LIST (FP N). MAY CAUSE LIVER/KIDNEY DMG.
PERM CNS DMG, LUNG DMG, DERM. MAY CAUSE SKIN AND RESPIRATORY SENSITIZATION.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR WITH
HYDROCARBON VAPOR CANISTER OR USE NIOSH/MSHA APPROVED SUPPLIED AIR
RESPIRATOR IN CONFINED OR ENCLOSED SPACES.
Ventilation:LOCAL EXHAUST AND EXPLOSION-PROOF MECHANICAL (GENERAL)
VENTILATION. USE ONLY WITH ADEQUATE VENTILATION.
Other Protective Equipment:USE CHEMICAL-RESISTANT APRON OR OTHER
CLOTHING IF NEEDED TO AVOID REPEATED OR PROLONGED SKIN CONTACT.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:HYDROTREATED HEAVY NAPHTHA;(ISOPAR G)
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:VAPOR AND LIQUID SLIGHTLY IRRITATING
TO EYES BUT DOES NOT INJURE EYE TISSUE. FREQUENT OR PROLONGED SKIN
CONTACT MAY CAUSE DERMATITIS. INHALATION OF HIGH CONCENTRATIONS OF
VAPOR OR MIST MAY BE IRRITATI NG TO THE RESPIRATORY TRACT.
ASPIRATIONOF VOMITUS AFTER INGESTION OF SMALL AMOUNT MAY CAUSE
PULMONARY INJURY OR DEATH.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE, SKIN & RESPIRATORY TRACT IRRITATION.
INHALATION MAY CAUSE HEADACHES, DIZZINESS, ANESTHESIA, DROWSINESS,
UNCONSCIOUSNESS, AND OTHER CENTRAL NERVOUS SYSTEM EFFECTS,
INCLUDING DEATH.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE EYES, SKIN, OR
RESPIRATORY TRACT MAY BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
EYELIDS OPEN. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH
SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL
ATTENTION. INHALA TION: REMOVE TO FRESH AIR. GIVE MOUTH-TO-MOUTH
RESUSCITATION IF NOT BREATHING. GET MEDICAL ATTENTION. INGESTION:
DO NOT INDUCE VOMITING. KEEP HEAD BELOW HIPS IF VOMITING OCCURS.
GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:0.8
Upper Limits:7.0
Extinguishing Media:USE WATER FOG, CARBON DIOXIDE, FOAM, OR DRY
CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:DO NOT MIX OR STORE WITH STRONG OXIDANTS
LIKE LIQUID CHLORINE OR CONCENTRATED OXYGEN. COMBUSTIBLE LIQUID.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT.
REMOVE ALL IGNITION SOURCES. RECOVER FREE LIQUID. ADD INERT
ABSORBENT AND RECOVER FOR PROPER DISPOSAL. AVOID BREATHING VAPORS.
VENTILATE CONFINED SPACES. KEEP PRODUCTS OUT OF SEWERS AND WATER
COURSES.
Neutralizing Agent:NOT APPLICABLE.
*Handling and Storage *
Handling and Storage Precautions:DO NOT HANDLE OR STORE NEAR HEAT,
SPARKS, FLAME OR STRONG OXIDANTS. USE ONLY WITH ADEQUATE
VENTILATION.
Other Precautions:AVOID BREATHING VAPORS. AVOID PROLONGED OR REPEATED
CONTACT WITH SKIN. REMOVE CONTAMINATED CLOTHING, LAUNDER BEFORE
REUSE. REMOVE CONTAMINATED SHOES AND THOROUGHLY DRY BEFORE REUSE.
WASH SKIN THOROUGH LY WITH SOAP AND WATER AFTER CONTACT.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:5.0
Evaporation Rate & Reference:0.3,(N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK LIQUID, MILD ISOPARAFFINIC HYDROCARBON ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS LIKE LIQUID CHLORINE, CONCENTRATED OXYGEN,
SODIUM OR CALCIUM HYPOCHLORITES.
Hazardous Decomposition Products:INCOMPLETE COMBUSTION MAY PRODUCE
FUMES, SMOKE, CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE MADE IN ACCORDANCE WITH ALL
APPLICABLE FEDERAL, STATE AND LOCAL LAWS AND REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED UNDER ORDINARY CONDITIONS OF USE.
USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF
CONCERN .
Ventilation:MECHANICAL EXHAUST, FUME HOOD.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
ODOR:ING 4:COLORLESS LIQ, PUNGENT ODOR. FIRST AID
PROC:FORMALDEHYDE. DO NOT USE GASTRIC LAVAGE/EMETICS. CALL MD
IMMED.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:FORMALDEHYDE (SARA III). VD:1.0 (GAS). EVAP RATE:>1
Fraction by Wt: 4%
Ingred Name:ACETIC ACID, SOLIUM SALT; (SODIUM ACETATE)
Fraction by Wt: 1.5%
Fraction by Wt: 2%
Fraction by Wt: N/K4%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:DANGER! POISON, MAY BE HARMFUL OR
FATAL IF SWALLOWED. HARMFUL IF INHALED OR ABSORBED THROUGH SKIN.
SENSITIZER, EXPOSURE MAY CAUSE HYPERSENSITIVITY TO SKIN, EYES AND
RESPIRATORY TRACT. SUSPECT CANCER H AZARD. CONTAINS MATERIAL WHICH
MAY CAUSE CANCER. AVOID BREATHING VAPOR AND EYE/SKIN CONTACT.
Explanation of Carcinogenicity:FORMALDEHYDE:ANTICIPATED TO BE A
CARCINOGEN (NTP), GROUP 2B (IARC), OSHA REGULATED.
Effects of Overexposure:SEE HEALTH HAZARDS
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING EYE, SKIN
OR RESPIRATORY DISORDERS MAY BE MORE SUSCEPTIBLE TO EFFECTS OF THIS
SUBSTANCE.
* First Aid Measures *
First Aid:INHAL:NOT APPLICABLE UNDER NORMAL CONDITIONS OF USE. SEEK MD
ASSIST IF NEC. EYES:FLUSH IMMED W/COPIOUS AMTS OF WATER FOR AT
LRG AMTS OF WATER, ACTIVATED CHARCOAL/MILK IF AVAILABLE & INDUCE
VOMIT BY STICKING FINGER DOWN THROAT. ANY ORGANIC MATL WILL
INACTIVATE (SUPDAT)
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:SEE INGS
Upper Limits:SEE INGS
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL OR ALCOHOL FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . COMBUSTIBLE, KEEP AWAY FROM HEAT AND FLAME.
Unusual Fire/Explosion Hazard:EMITS HIGHLY TOXIC FUMES OF FORMALDEHYDE
GAS.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROT EQUIP AS SPECIFIED. WEAR PROT CLTHG
& NIOSH/MSHA APPROVED SCBA/RESP W/APPRVD CARTRIDGE IF NEC. REMOVE
ALL SOURCES OF IGNIT. CONTAIN SPILL & ABSORB W/INERT MATL. SCOOP UP
& PLACE IN APPRVD HA Z WASTE CONTR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. STORE
AT ROOM TEMPERATURE. KEEP AWAY FROM HEAT AND FLAME.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:F4
Boiling Pt:B.P. Text:SUPDAT
Melt/Freeze Pt:M.P/F.P Text:SUPDAT
Vapor Pres:SUPDAT
Vapor Density:SEE INGS
Spec Gravity:SUPDAT
Evaporation Rate & Reference:SEE INGREDIENTS
Appearance and Odor:SODIUM ACETATE:COLORLESS CRYSTALS. ACETIC
ACID:COLORLESS LIQ. (SUPDAT)
Percent Volatiles by Volume:INGRED
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HYDROCHLORIC ACID, PERCHLORIC ACID, ALKALIES, AMINES AND STRONG
OXIDIZERS.
Stability Condition to Avoid:IMCOMPATIBLE SUBSTANCES.
Hazardous Decomposition Products:HIGHLY TOXIC FUMES OF FORMALDEHYDE
GAS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE BY MEANS WHICH COMPLY WITH ALL LOCAL,
STATE AND FEDERAL REGULATIONS OR CONTACT AN APPROVED AND LISCENSED
DISPOSAL AGENCY.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY
CONDITIONS/ADEQUATE VENT.
Ventilation:MECH(GEN)OR LOCAL EXHAUST THAT PROVIDES ADEQUATE
VENTILATION
Other Protective Equipment:SAFETY SHOWER & EYE BATH
Supplemental Safety and Health
MSDS IS UNDATED
* Product Identification *
Product ID:POTASSIUM NITRATE,ACS
* Composition/Information on Ingredients *
Fraction by Wt: UNKN
* Hazards Identification *
Effects of Overexposure:INHALATION:COUGHING,SHORTNESS OF BREATH.
SKIN:-REDNESS EYES:-REDNESS,PAIN.INGESTION:ABDOMINAL SPASM
* First Aid Measures *
First Aid:INHALATION:KEEP PATIENT IN FRESH AIR.CALL A DOCTOR.SKIN:WASH
WITH PLENTY OF WATER EYES:WASH WITH PLENTY OF WATER.CALL A DOCTOR.
INGESTION:RINSE MOUTH,GIVE PLENTY OF WATER TO DRINK,INDUCE
VOMITING,AND CALL A DOCTOR.
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Fire Fighting Procedures:AN APPROVED SCBA SHOULD BE WORN
Unusual Fire/Explosion Hazard:FIRE AND EXPLOSION HAZARD WHEN SHOCKED OR
HEATED IN CONTACT WITH ORGANIC MATERIALS OR REDUCERS
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP SPILLED SUBSTANCE AND REMOVE TO SAFE
PLACE,WASH AWAY REMAINDER WITH LARGE AMOUNT OF WATER.
*Handling and Storage *
Handling and Storage Precautions:SEPARATE FROM COMBUSTIBLE, ORGANIC OR
OTHER READILY OXIDIZABLE MATERIAL.
Other Precautions:AVOID SKIN AND EYE EXPOSURE.
* Physical/Chemical Properties *
HCC:D1
NRC/State Lic Num:NOT RELEVANT
Vapor Pres:NEG
Vapor Density:3.5
Solubility in Water:APPRECIABLE
Appearance and Odor:TRANSPARENT WHITE CRYSTALS-ODORLESS
Percent Volatiles by Volume:NEGL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG REDUCERS,ORGANIC MATERIALS.
Stability Condition to Avoid:NONE SPECIFIED BY THE MFR.
Hazardous Decomposition Products:THERMAL DECOMPOSITION OR BURNING MAY
PRODUCE NO*X
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL,STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED NORMALLY. NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST.
Other Protective Equipment:RUBBER APRON, LONG-SLEEVED SHIRTS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
EFTS OF OVEREXP:IRRIT. HYPERSENSITIVE INDIVIDUALS MAY DEVELOP ASTHMA
BRONCHITIS. SKIN/EYES:IRRITATION, ALLERGIC SENSITIZATION IN SOME
INDIVIDUALS IN PRESENCE OF HEAT & HUMIDITY. (NICKEL ITCH). INGEST:
NAUSEA, GASTROINTESTINAL PROBLEMS, UNCONSCIOUSNESS.
* Product Identification *
Product ID:ACID NICKEL BRUSH PLATE
Preparer's Name:WILLIAM A WILSON
* Composition/Information on Ingredients *
OSHA PEL:1 MG(NI)/M3
ACGIH TLV:0.1 MG(NI)/M3
OSHA PEL:1 MG(NI)/M3
ACGIH TLV:0.1 MG(NI)/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:LOCAL:IRRITANT, ALLERGEN,
INGESTION, INHALATION - SLIGHT. CAUSES READILY REVERSIBLE CHANGES
WHICH DISAPPEAR AFTER END OF EXPOSURE. SYSTEMIC:INGESTION,
INHALATION - SLIGHT. CAUSES READILY REVERSI BLE CHANGES WHICH
DISAPPEAR AFTER END OF EXPOSURE. CHRONIC:LOCAL:IRRITANT, ALLERGEN -
SLIGHT TO (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:MODERATE. MAY INVOLVE BOTH
IRREVERSIBLE & REVERSIBLE CHANGES; NOT SEVERE ENOUGH TO CAUSE
DEATH/PERMANENT INJURY. SYSTEMIC:INHALATION - MODERATE. MAY INVOLVE
BOTH IRREVERSIBLE AND REVERSIBLE C HANGES; NOT SEVERE ENOUGH TO
CAUSE DEATH OR PERMANENT INJURY. SIGNS & SYMP OF
OVEREXP:INHAL:UPPER RESP TRACT (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
THORO W/SOAP & WATER. CALL PHYS. INHAL:REMOVE TO FRESH AIR. IF
BRTHG DIFFICULTIES DEVELOP, CALL PHYS. INGEST:INDUCE VOMIT IF
CONSCIOUS. MAINTAI N RESPIRATION. CALL PHYS.
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:FLUSH W/WATER AFTER ABSORBING ON CLAY OR
SAWDUST. DISPOSE OF AT PROPER WASTE DISPOSAL OR SITE, OR RECOVER
NICKEL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED. STORE IN COOL,
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Solubility in Water:VERY SOLUBLE
Appearance and Odor:GREEN SOLUTION; ACID ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CYANIDES.
Stability Condition to Avoid:DO NOT MIX WITH CYANIDES.
Hazardous Decomposition Products:NONE.
* Disposal Considerations *
Waste Disposal Methods:SHOULD BE IN ACCORDANCE WITH FEDERAL, STATE, AND
LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED RESPIRATOR
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE
BATH
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:1,2-DICHLOROETHANE, ETHYLENE DICHLORIDE (ANIMAL CARCINOGEN
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF SWALLOWED, INHALED/ABSORBED
THROUGH SKIN. VAPOR/MIST IS IRRITATING TO THE EYES, MUCOUS
MEMBRANES & UPPER RESPIRATORY TRACT. MAY CAUSE CNS DEPRESSION.
SKIN: IRRITATION/DERMATITIS. INGESTION: DAMAGE TO LIVER/KIDNEYS.
MAY ALTER GENETIC MATERIAL. MUTAGEN.
Explanation of Carcinogenicity:SEE INGREDIENTS.
Effects of Overexposure:IRRITATION, NAUSEA, HEADACHE, VOMITING, GI
DISTURBANCES
* First Aid Measures *
First Aid:EYES/SKIN: IMMEDIATELY FLUSH W/COPIOUS AMOUNTS OF WATER FOR
CPR/OXYGEN IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Lower Limits:6.2
Extinguishing Media:CO2, DRY CHEMICAL POWDER, ALCOHOL/POLYMER FOAM
Fire Fighting Procedures:WATER MAY BE EFFECTIVE FOR COOLING, BUT MAY
NOT EFFECT EXTINGUISHMENT. WEAR SELF CONTAINED BREATHING APPARATUS
& PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO
SOURCE OF IGNITION & FLASH BACK. FLAMMABLE LIQUID. AUTO-IGNITION
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL IGNITION SOURCES.
WEAR SELF CONTAINED BREATHING APPARATUS, RUBBER BOOTS & HEAVY
CONTAINERS FOR DISPOSAL. VENTILA TE AREA & WASH SITE AFTER MATERIAL
PICKUP.
*Handling and Storage *
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. KEEP AWAY FROM
HEAT, SPARKS & OPEN FLAME. STORE UNDER NITROGEN. STORE IN A COOL,
DRY PLACE. HARMFUL LIQUID, TOXIC.
Other Precautions:WEAR PROTECTIVE CLOTHING & EQUIPMENT. DON'T BREATHE
VAPOR/GET IN EYES, ON SKIN/ON CLOTHING. AVOID PROLONGED/REPEATED
EXPOSURE.
* Physical/Chemical Properties *
Vapor Density:3.4
Appearance and Odor:COLORLESS LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, ALUMINUM
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME
Hazardous Decomposition Products:CO, CO2, HYDROGEN CHLORIDE GAS,
PHOSGENE GAS
* Disposal Considerations *
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN
AFTERBURNER & SCRUBBER IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF TLV IS EXCEEDED, OR FOR SYMPTOMS OF
OVEREXPOSURE, WEAR A NIOSH-APPROVED DUST/MIST RESPIRATOR.
Ventilation:IF NEEDED, PROVIDE MECHANICAL VENTILATION TO KEEP <TLV
Other Protective Equipment:NONE
Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE.
Supplemental Safety and Health
* Product Identification *
Product ID:SANI-TUFF E-2 RATED CLEANSER
Preparer's Name:EDWARD J. ROSENTAL
* Composition/Information on Ingredients *
Ingred Name:P-CHLORO-M-XYLENOL (4-CHLORO-3,5-XYLENOL)
Fraction by Wt: <5%
SODIUM SALTS
Ingred Name:HEXYLENE GLYCOL
Ingred Name:ETHYL ALCOHOL (ETHANOL)
Fraction by Wt: <5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: RESPIRATORY IRRITATION.
SKIN: IRRITATION. EYE: BURNING & IRRITATION. INGESTION: NAUSEA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: RESPIRATORY IRRITATION. SKIN:
IRRITATION. EYE: BURNING & IRRITATION. INGESTION: NAUSEA.
* First Aid Measures *
First Aid:INHALATION: MOVE VICTIM TO FRESH AIR. SKIN: WASH AFFECTED
OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:CO2, DRY CHEMICAL, OR FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS
* Accidental Release Measures *
Spill Release Procedures:CLEAN UP W/ABSORBENT MATERIAL.
*Handling and Storage *
* Physical/Chemical Properties *
Vapor Density:<1
pH: 5.5
Evaporation Rate & Reference:(ETHER = 1): <1
Solubility in Water:COMPLETE
Appearance and Odor:THICK YELLOW LIQUID W/MEDICINAL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SPRAYING, USE NIOSH APPROVED MECHANICAL
RESPIRATOR. RESTRICTED AREAS USE NIOSH APPROVED CHEMICAL
CARTRIDGE/MECHANICAL FILTER. CONFINED AREA USE NIOSH APPROVED
AIR-SUPPLIED RESPIRATOR.
Ventilation:GENERAL DILUTION & LOCAL EXHAUST VENTILATION.
Other Protective Equipment:NOT LIKELY TO BE NEEDED
Supplemental Safety and Health
NK
* Product Identification *
Preparer's Name:W.A. ELLISON
* Composition/Information on Ingredients *
Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:REPEATED EXPOSURE TO CRYSTALLINE
SILICA MAY CAUSE PNEUMOCONIOSIS,A PROGRESSIVELYDISABLING LUNG
DISEASE. OVREXPOSURE TO XYLENE MAY CAUSE INJURY TO LIVER,KIDNEYS &
BLOOD. PROLONGED/REPEATED OVEREXPOSURE TO SOLVENTS W/PERMANENT
BRAIN & NERVOUSSYSTEM DAMAGE. DELIBERATE MISUSE OF CONTENTS MAY BE
HARMFUL OF FATAL.
Effects of Overexposure:INGST: GASTROINTESTINAL IRRIT,NAUSEA,VOMITING &
DIARRHEA. ASPIRATION OF MATL IN TO LUNGS CAN CAUSE CHEM.
PNEUMONITIS WHICH CAN BE FATAL. INHAL:MAY CAUSE IRRIT. TO
NOSE,THROAT & ACUTE NERVOUS SYSTEM DE PRESSION. EYE:
IRRITATIONSKIN: MAY CAUSE DEFATTING & IRRITATION OF THE SKIN.
Medical Cond Aggravated by Exposure:PREXISTING RESPIRATORY CONDITIONS
MAY BE AGGRAVAT-ED BY EXPOSURE TO CRYSTALLINE SILICA
* First Aid Measures *
First Aid:INGST: CALL A PHYSICIAN IMMEDIATELY. DO NOT INDUCE VOMITING.
INHAL: REMOVE TO FRESH AIR IMMEDIATELY,GIVE
ARTIFICIAL RESPIRATION IF NEEDED.KEEP WARM/QUIET, GET MEDICAL
LIFTING EYELIDS, GET MEDICAL ATTN. SKIN: WASH AFFECTED AREA
W/SOAP & WATER, GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Extinguishing Media:NFPA CLASS B FIRE EXTINGUISHER DESIGNED TO
EXTINGUISH FLAMMABLE LIQUID FIRES. POLYMER FOAM PREFERRED FOR LARGE
FIRES.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS. WATER
MAY BE INNEFECTIVE, BUT MAY BE USED TO PREVENT PRESSURE BUILD-UP.
IF WATER IS USED, FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. DIKE &
CONTAIN SPILL W/INERT MATL. TRANSFER LIQ TO COVER METAL
CONTAINER. USE NON SPARKING TOOLS. PREVENT CONTAMINATION OF
SEWER,STREAMS, & GROUNDWATER W/SPILLED MATL OR USED ABSORBENT.
*Handling and Storage *
CLOSE CONTAINER AFTER EACH USE.
Other Precautions:DO NOT TAKE INTERNALLY. DO NOT BREATH SANDING DUST.
DO NOT WASH & REUSE CONTNRS FOR ANY PURPOSE. DO NOT WELD, BRAZE OR
CUT ON EMPTY CONT. NEVER USE PRESSURE TO EMPTY. CONTAINER SHOULD
BE GROUNDED & BONDED TO THE RECEIVING CONTAINER.
* Physical/Chemical Properties *
Vapor Density:>AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS.
Stability Condition to Avoid:EXCESSIVE HEAT AND SOURCES OF IGNITION
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE AND CARBON
DIOXIDE.
Conditions to Avoid Polymerization:KEEP AWAY FROM HEAT, SPARKS, AND
FLAME
* Disposal Considerations *
Waste Disposal Methods:INCINERATE ONLY IN EPA FACILITY. DO NOT
INCINERATECLOSED CONTAINERS. DISPOSE IN ACCORDANCE WITH
FEDERAL,STATE, & LOCAL REGULATIONS. CONTAMINATED ABSORBENT MAY BE
DISPOSED IN A HAZARDOUS WASTE LANDFILL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:PROTECTIVE MASK.
Ventilation:MECHANICAL EXHAUST REQUIRED
Other Protective Equipment:PROTECTIVE CLOTHING, SAFETY SHOWER & EYE
BATH
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
INCOMPATIBLES CONT'D: CALCIUM HYPOCHLORITE, NITRIC ACID + HYDROFLUORIC
ACID, NITRIC ACID + SULFURIC ACID, SODIUM PEROXIDE, HYDROGEN
PEROXIDE/POTASSIUM PERMANGANTE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:1,2-PROPANEDIOL (PROPYLENE GLYCOL)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HARMFUL IF INHALED/SWALLOWED. MAY
CAUSE EYE & SKIN IRRITATION. MAY CAUSE CNS DEPRESSION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NAUSEA, HEADACHE, VOMITING,
GASTROINTESTINAL DISURBANCES
* First Aid Measures *
First Aid:SKIN: FLUSH W/WATER. EYES: TREAT BY IMMEDIATE & PROLONGED
IRRIGATION W/COPIOUS AMOUNTS OF WATER. INGESTION: WASH OUT MOUTH
W/WATER IF CONSCIOUS. INHALATION: REMOVE TO FRESH AIR. OBTAIN
MEDICAL ATTENTI ON IN ALL CASES.
* Fire Fighting Measures *
Lower Limits:2.6
Extinguishing Media:WATER SPRAY, CO2, DRY CHEMICAL POWDER/APPROPRIATE
FOAM
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS &
PROTECTIVE CLOTHING TO PREVENT CONTACT W/SKIN & EYES.
* Accidental Release Measures *
PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH SITE
AFTER MATERIAL PICKUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. HYGROSCOPIC.
STORE IN A COOL, DRY PLACE.
Other Precautions:DON'T BREATHE VAPORS. AVOID CONTACT W/EYES, SKIN &
CLOTHING.
* Physical/Chemical Properties *
Appearance and Odor:VISCOUS COLORLESS LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACID CHLORIDES, ACID ANHYDRIDES, OXIDIZING AGENTS,CHLOROFORMATES,
REDUCING AGENTS
Stability Condition to Avoid:MOISTURE
Hazardous Decomposition Products:CO, CO2
* Disposal Considerations *
Waste Disposal Methods:DISSOLVE/MIX THE MATERIAL W/A COMBUSTIBLE
SOLVENT & BURN IN A CHEMICAL INCINERATOR EQUIPPED W/AN AFTERBURNER
& SCRUBBER IN ACCORDANCE W/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR DUST/MIST
IF ABOVE PEL/TLV.
Ventilation:LOCAL/GENERAL TO MAINTAIN PEL/TLV.
Other Protective Equipment:PROTECTIVE CLOTHINGS.EYE-WASH FACILITIES.
Work Hygienic Practices:AVOID CONTACT WITH EYES AND SKIN;DO NOT BREATHE
VAPORS/MIST/DUST.WASH THOROUGHLY AFTER EACH USE.
Supplemental Safety and Health
* Product Identification *
Product ID:ALUMINUM SULFATE
* Composition/Information on Ingredients *
Ingred Name:ALUMINUM SULFATE (SARA III)
OSHA PEL:2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRITATION OF
EYES,SKIN,RESPIRATORY OR G,I.TRACT;REDNESS OR BURNS OF EYES ARE
POSSIBLE.MAY CAUSE NASAL DISCHARGE,NOSE BLEED,SORE THROAT,COUGHING
AND DIFFICULTY IN BREATHING.
Explanation of Carcinogenicity:DATA PER MGF MSDS.
Effects of Overexposure:SEE HEALTH HAZARDS DATA.
Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS MAY BE
WORSEN.
* First Aid Measures *
First Aid:EYES AND SKIN:FLUSH WITH LARGE AMOUNT OF WATER FOR ABOUT
TO FRESH AIR;CALL A PHYSICIAN.INGESTION:SEEK MEDICAL ATTENTION
IMMEDIATELY.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:NOT FLAMMABLE;USE CARBON DIOXIDE, FOAM, DRY
CHEMICAL, OR WATER FOG IN CASE OF SURROUNDING FIRE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NONE EXPECTED
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION;SWEEP UP OR
VACUUM AND COLLECT FOR PROPER DISPOSAL IN AN APPROVED CONTAINER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY AND WELL VENTILATED
AREA.KEEP CONTAINER CLOSED WHEN NOT IN USE.
Other Precautions:WASH THOROUGHLY AFTER EACH USE.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:1.3
pH:3.5,1%
Solubility in Water:SOLUBLE
Appearance and Odor:ODORLESS,WHITE CRYSTALS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACTIVE METALS
Stability Condition to Avoid:HIGH TEMPERATURES
Hazardous Decomposition Products:MAY PRODUCE OXIDES OF ALUMINUM AND
SULFUR
* Disposal Considerations *
Waste Disposal Methods:CONSULT LOCAL AUTHORITIES;DISPOSAL MUST BE IN
ACCORDANCE WITH LOCAL,STATE AND FEDERAL REGULATIONS
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
TYPE.
Ventilation:NOT REQUIRED.
Other Protective Equipment:USE PROTECTIVE CLOTHING FOR CLEANLINESS AS
DESIRED.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:MIKE PELLNY
CAGE:WIDGE
CAGE:WIDGE
* Composition/Information on Ingredients *
Ingred Name:VM&P NAPHTHA (LIGROINE)
Other REC Limits:NONE SPECIFIED
Ingred Name:PARAFFIN WAX
Other REC Limits:NONE SPECIFIED
OSHA PEL:2 MG/M3 (FUME)
Ingred Name:GRAPHITE, SYNTHETIC
Fraction by Wt: 2-5%
Other REC Limits:NONE SPECIFIED
Ingred Name:HYDRO-TREATED ALIPHATIC OIL
Fraction by Wt: 2-5%
Other REC Limits:NONE SPECIFIED
Ingred Name:CALCIUM SULFONATE BASED CORROSION INHIBITOR (CALCIUM
SULFONATE PLUS OIL, WAX, AND/OR SOLVENT LISTED ABOVE.)
Other REC Limits:NONE SPECIFIED
Ingred Name:VOC: 3.3 LB/GL
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Health Hazards Acute and Chronic:MAY CAUSE HEADACHES OR NAUSEA, EYE
IRRITATION IF SPLASHED INTO THE EYE, DEFATTING OF SKIN. THRESHOLD
* First Aid Measures *
First Aid:INHALATION: REMOVE PERSON TO FRESH AIR. SKIN: CLEAN AFFECTED
AREA. EYES: CLEAN AFFECTED AREA WITH EYE WASH AND CONSULT
PHYSICIAN. INGESTION: CONSULT PHYSICIAN. NOTE TO PHYSICIAN: TREAT
FOR SOLVENT ING ESTION.
* Fire Fighting Measures *
Flash Point:NR
Lower Limits:0.7
Upper Limits:6.0
Extinguishing Media:USE CO2, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:VAPORS HEAVIER THAN AIR. WATER MAY CAUSE
FROTHING.
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBENT, DIKE LARGE SPILLS, AVOID USE OF
SPARKS OR OPEN FLAMES, VENTILATE WELL. USE NON-SPARKING TOOLS.
*Handling and Storage *
Handling and Storage Precautions:AVOID OPEN SPARKS OR FLAMES. STORE
* Physical/Chemical Properties *
HCC:V3
Vapor Pres:2.6
Vapor Density:+1
Appearance and Odor:BLACK PASTE, MILD SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID OPEN FLAMES
Conditions to Avoid Polymerization:OPEN FLAMES AND/OR SPARKS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:UNDER NORMAL INTENDED USE NO SPECIAL PROTECTION
IS REQUIRED.AVOID INHALATION. USE NIOSH/MSHA APPROVED RESP FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:UNDER NORMAL INTENDED USE, NO SPECIAL
EQUIPMENT/CLOTHING REQUIRED.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POLYESTER RESIN
Ingred Name:STYRENE-ACRYLIC RESIN
Ingred Name:ORGANIC PIGMENT
Ingred Name:POLYPROPLYLENE WAX
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE/SKIN: NON IRRITANT, NOT
SENSITIZED.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:MINIMAL IRRITATION TO RESPIRATORY TRACT MAY
OCCUR AS WITH EXPOSURE TO LARGE AMOUNT OF ANY NON-TOXIC POWDER.
Medical Cond Aggravated by Exposure:ACCUMULATION OF DUST IN THE
RESPIRATORY SYSTEM.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR, CONSULT MD IF SYMPTOMS PERSISTS.
EYES: IN CASE OF CONTACT, IMMED FLUSH EYES WITH COPIOUS QUANTITIES
* Fire Fighting Measures *
Extinguishing Media:WATER SPRAY, FOAM CO*2, DRY POWDER.
Fire Fighting Procedures:THIS MATL WILL BURN IN CASE OF FIRE.DECOMP
PRODS ARE CO, CO*2, & NO*X. AVOID INHAL OF SMOKE. WEAR NIOSH/MSHA
APPRVD SCBA & FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP OR CLEAN WITH A VACUUM CLEANER (USE
GROUNDED VACUUM CLEANER).
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:NO SPECIAL HANDLING REQUIREMENTS
NEEDED FOR SAFETY REASONS. AVOID INHALATION.
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:1.1
Solubility in Water:INSOLUBLE
Appearance and Odor:FINE ODORLESS POWDER (CYAN COLOR)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS AND BASES.
Stability Condition to Avoid:HIGH TEMPS
Hazardous Decomposition Products:PHENOL DERIVATIVES, CARBON MONOXIDE,
* Disposal Considerations *
Waste Disposal Methods:LANDFILL OR INCINERATE IN COMPLIANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE AIR SUPPLIED OR SELF-CONTAINED BREATHING
APPARATUS IN AREAS OF HIGH VAPOR CONCENTRATIONS.
Ventilation:PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENTILATION IN
VOLUME & PATTERN TO KEEP TLV BELOW ACCEPTABLE LEVELS.
Other Protective Equipment:EYE WASH, SAFETY SHOWER, IMPERVIOUS CLOTHING
AND BOOTS.
Work Hygienic Practices:WASH THOROUGHLY AFTER USE AND BEFORE EATING,
SMOKING OR USING REST ROOM FACILITIES.
Supplemental Safety and Health
OTHER PRECAUTIONS: DO NOT GET IN EYES. AVOID SKIN CONTACT. PREVENT
REPEATED OR PROLONGED BREATHING OF VAPORS OR SPRAY MISTS. AVOID
CONTACT WITH OR BREATHING OF FUMES RELEASED DURING CURING PROCESS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NAPHTHA, MEDIUM ALIPHATIC
Other REC Limits:NONE SPECIFIED
Ingred Name:NAPHTHA, LIGHT ALIPHATIC (PETROLEUM) (THIS MATERIAL
Fraction by Wt: 7.6%
Other REC Limits:NONE SPECIFIED
Ingred Name:PROPYLENE GLYCOL MONOMETHYL ETHER ACETATE
Other REC Limits:NONE SPECIFIED
Ingred Name:N-BUTYL ALCOHOL (SARA III)
Fraction by Wt: 6.1%
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION-VAPORS MAY CAUSE IRRITATION
TO RESPIRATORY TRACT. SKIN-REPEATED OR PROLONGED CONTACT CAM CAUSE
IRRITATION, DEFATTING AND DERMATITIS. EYE-VAPORS MAY BE IRRITATING.
DIRECT CONTACT CAN CAUSE S EVERE EYE DAMAGE.
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:INHALATION-HEADACHE, DIZZINESS, DROWSINESS,
NARCOSIS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: REMOVE FROM EXPOSURE TO FUMES, INTO A FRESH AIR
ENVIRONMENT. EYE-FLUSH IMMEDIATELY WITH LARGE QUANTITIES OF COOL
EFFECTED AREAS WITH WATER. REMOVE CONTAMINATED CLOTHING. WASH
THOROUGHLY WITH SOAP AND WATER.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:0.8%
Extinguishing Media:FOAM, "ALCOHOL" FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WATER SPRAY MAY BE INEFFECTIVE. USE WATER TO
COOL FIRE EXPOSED CONTAINERS. USE FOG NOZZLES. WEAR SELF CONTAINED
BREATHING APPARATUS & FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:A STRAIGHT STREAM OF WATER WILL SPREAD
FIRE. A VAPOR ACCUMULATION WILL FLASH &/OR EXPLODE IF IGNITED.
CONTAINER MAY BURST IN FIRE. COOL WITH WATER SPRAY OR FOG.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. PROVIDE ADEQUATE
VENTILATION. AVOID BREATHING VAPORS. SHUT OFF SOURCE OF SPILL IF
CAN BE DONE SAFELY. USE NON-SPARKING TOOLS. ABSORB ON ABSORBENT
MATERIAL.
*Handling and Storage *
CLOSURE TIGHT & CONTAINER UPRIGHT TO PREVENT LEAKAGE. DO NOT STORE
OR USE NEAR HEAT, SPARKS OR FLAME.
Other Precautions:STORAGE-STORE OUT OF SUN. STORE ONLY IN WELL
VENTUILATED AREAS. DRUMS OR PAILS OF THIS MATERIAL SHOULD BE
GROUNDED WHEN POURING. NEVER USE PRESSURE TO EMPTY. DRUM IS NOT A
PRESSURE VESSEL. DO NOT PUNC TURE, DRAG OR SLIDE CONTAINER.
* Physical/Chemical Properties *
HCC:F4
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:OPEN FLAMES, SPARKS OR HIGH TEMPERATURES.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN ACCORDANCE WITH POLLUTION CONTROL
REGULATIONS, OR USE METHODS OF DISPOSAL WHICH ARE IN COMPLIANCE
WITH FEDERAL, STATE OR LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR AN APPROVED ORGANIC VAPOR RESPIRATOR IF
VENTILATION IS INADEQUATE.
Other Protective Equipment:CHEMICAL BOOTS, APRON
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:BENZYL ALCOHOL
Other REC Limits:5 MG/CUM
OSHA PEL:5 PPM (SKIN)
ACGIH TLV:5 PPM (SKIN)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: MAY CAUSE SEVERE IRRITATION &
BURNS. SKIN: MAY CAUSE SEVERE IRRITATION, BURNS & SYSTEMIC
POISONING. INHALATION: MAY CAUSE IRRITATION & CNS DEPRESSION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, BURNS, DRYING, DEFATTING.
* First Aid Measures *
First Aid:INGESTION: DON'T INDUCE VOMITING. SKIN: FLUSH W/SOAP & WATER.
FRESH AIR. GIVE CPR IF NEEDED. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Flash Point Method:COC
Flash Point:NONE TO BOIL
Extinguishing Media:FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:FULL FIREFIGHTER'S EQUIPMENT.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:ABSORB W/SAND/INERT MATERIAL. SWEEP/SCOOP UP &
REMOVE. PREVENT SPREAD. MOP, SQUEEGEE, INDUSTRIAL VACUUM.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A DRY, PROTECTED AREA. KEEP
CONTAINER CLOSED WHEN NOT IN USE. USE W/ADEQUATE VENTILATION.
Other Precautions:AVOID BREATHING VAPORS. AVOID CONTACT W/SKIN, EYES &
CLOTHING.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:PARTIAL
Appearance and Odor:VISCOUS EMULSION W/SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Hazardous Decomposition Products:BY THERMAL DECOMPOSITION: CO, CO2.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE RESPIRABLE FUME RESPIRATOR OR AIR SUPPLIED
RESPIRATOR WHEN WELDING IN CONFINED SPACE OF WHERE LOCAL EXHAUST OR
VENTI DOES NOT KEEP EXPO BELOW RECOMMENDED EXPO LMITS.
Ventilation:USE ENOUGH VENTI,LOC EXHAU @ARC,OR BOTH TO KEEP FUME/GAS
FRM WORKER BREATH ZONE/GEN AREA.MAKE SURE INHAL AIR NOT CONTAM.
Other Protective Equipment:PROV PROT SCREENS/FLASH GOGG IF NECESSARY TO
SHIELD OTHERS.START W/SHADE TOO DARK TO SEE WELD ZONE-GO NEXT
LIGHTER SHADE
Work Hygienic Practices:TRAIN WELD TO KEEP HEAD OUT OF FUMES.WEAR
HAND/HEAD/BODY PROT-PREVENT INJURY RM RADIATION/SPARK/ELECTRIC
SHOCK.
Supplemental Safety and Health
DECOMP PROD:PLAT,GALVA),#OF WELD,VOL OF WORKAREA,QUAL/AMT OF
VENTI,WELDER HEAD POSITION TO FUME PLUME,CONTAM IN ATM(CHLORINATED
HYDROCARBON VAP FRM CLEAN/DEGREASE ACTIV).ALSO FRM NORM OPERATION
FRM VO LITION,RX,OXIDATION OF MATL,BASE METAL,COAT,ETC.FE
OXIDES,COMPLEX OXIES OF MN,SI,NI,CR,MO,V;OZONE,NI OXIDES,SHIELD
GAS,
* Product Identification *
CAGE:ROBIN
CAGE:ROBIN
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1MG/M3 FUME/1 DUST
Ingred Name:IRON
Fraction by Wt: BALANCE
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C, 5 MG/M3 (FUME)
Ingred Name:SILICON DIOXIDE
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Fraction by Wt: 9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
Ingred Name:MANGANESE OXIDE
Fraction by Wt: 1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 5 MG(MN)/M3
Ingred Name:TITANIUM DIOXIDE
Fraction by Wt: 4%
Other REC Limits:NONE RECOMMENDED
Ingred Name:ZIRCONIUM COMPOUNDS
Fraction by Wt: 2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:5 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ELECTRIC ARC-WELDING MAY CREATE ONE OR
MORE OF FOLLOWING HEALTH HAZARDS:FUMES/GASES CAN BE DANGEROUS TO
YOUR HEALTH;ARC RAYS CAN INJURE EYE/BURN SKIN;ELECTRIC SHOCK CAN
KILL.
Explanation of Carcinogenicity:PER MSDS:CHROMIUM CMPDS ARE REQUIRED TO
BE CONSIDERED CARC BY OSHA.
Effects of Overexposure:SHORT-TERM OVEREXPO TO WELDING FUMES MAY RESULT
IN DISCOMFT:DIZZ,NAUI,DRYNESS OR IRRIT OF OSE/THROAT/EYES,TIGHTNESS
IN CHESXT,FEVER,ALLERGIC RXS.LONG-TERM(CHRONIC)OVEREXPO TO WELDING
FUMES MAY LEAD TO SIDEROSIS(IRON DEPOSIT IN LUNGS),BEILEVE BY SOME
INVESTIGATORS TO AFFECT PULM FUNCTION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:REMOVE TO FRESH AIR.OBTAIN MED ATTN.EMPLOY FIRST AID
TECHNIQUES RECOMMENDED BY AMERICAN RED CROSS.
* Fire Fighting Measures *
Flash Point:NP
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:NP
Upper Limits:NP
Extinguishing Media:NONE SPECIFIED BY MANUFACTURER.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:NONFLAMM:WELDING ARC/SPARKS CAN IGNITE
COMBUSTIBLES.
* Accidental Release Measures *
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:READ/UNDERSTAND MFG
APRON,HAT,DARK CLOTH.TRAIN WELDER NOT TOUCH LIVE ELECT/INSULATE.
Other Precautions:ONE RECOMMENDED WAY TO DETERIMINE COMPOSITION/QUANT
OF FUMES/GASES TO WHICH WORKER ARE EXPO TO IS TO TAKE AIR SMPL FRM
INSIDE WELDER HELMET IF WORN OR IN WORKER BREATH ZONE.SEE AWS
* Physical/Chemical Properties *
HCC:M1
Boiling Pt:B.P. Text:NP
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:NP
Vapor Density:NP
Spec Gravity:NP
pH:NP
Viscosity:NP
Evaporation Rate & Reference:NP
Solubility in Water:NP
Appearance and Odor:NP
Percent Volatiles by Volume:NP
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:WELD FUME/GAS COMPO/QUAL DEPENDENT
UPON METAL WELD/PROCESS/PROCEDURE/ELECTRODE.ALSO CAOTING ON METAL
WELD(PAINT,(SUPPL))
* Disposal Considerations *
Waste Disposal Methods:CONTAINS MATL SUBJ TO REPORTING REQMTS OF SEC
SURROUNDING ENVIRO.DISCARD ANY PRODUCT RESIDUE,DISPO CNTNR/LINER IN
ENVIRO ACCEPTABLE MANNER IN FULL COMPLIANCE W/FED/STATE/LOC REGS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED. NIOSH/MSHA APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NONE REQUIRED.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EFTS OF OVEREXP:& WOULD NOT FUNC PROPERLY IN MFR EQUIP. SYMPS OF
OVEREXP:MINIMAL RESP TRACT IRRIT MAY OCCUR AS W/EXPOS TO LG AMTS OF
ANY NON-TOX DUST. SPILL PROC:TO REDUCE STATIC BUILDUP (SEE FIRE & E
XPLO DATA). RESIDUE CAN BE REMOVED W/SOAP & COLD WATER. GARMENTS
MAY BE WASHED/DRY CLEANED, AFTER REMOVAL OF (ING 7)
* Product Identification *
CAGE:0E6G9
CAGE:0E6G9
* Composition/Information on Ingredients *
Ingred Name:ACRYLIC ACID BUTYL ESTER POLYMER WITH STYRENE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CARBON BLACK
Fraction by Wt: 5-0%
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
Ingred Name:PROPENE POLYMERS; (POLYPROPYLENE)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:POLYETHYLENE
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:QUARTERNARY AMMONIUM SALT
Fraction by Wt: 1-3%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Fraction by Wt: 1-3%
Ingred Name:SUPDAT:LOOSE TONER.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IN A MFR SPONSORED CHRONIC INHAL STUDY
IN RATS USING SPEC TEST TONER, THERE WERE NO LUNG CHANGES AT ALL IN
LOWEST EXPOS LEV (1 MG/M3), MOST RELEVANT LEV TO POTNTL HUMAN
@ MIDDLE EXPOS LEV (4 MG/M3) WHILE SLIGHT DEGREE OF FIBROSIS WAS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
MG/M3) IN ALL ANIMALS. THESE FINDING ARE ATTRIBUTED TO "LUNG
OVERLOADING" A GENERIC RESPONSE TO EXCESS AMTS OF ANY DUST RETAINED
RESPIRABLE THAN COMMERCIALLY AVAIL MFR TONER TO COMPLY W/EPA
TESTING PROTOCOL(SUPDAT)
Medical Cond Aggravated by Exposure:NONE WHEN USED AS DESCRIBED BY
PRODUCT LITERATURE.
* First Aid Measures *
SOAP AND WATER. INHAL:REMOVE FROM EXPOSURE. INGEST:DILUTE STOMACH
CONTENTS WITH SEVERAL GLASSES OF WATER.
* Fire Fighting Measures *
Extinguishing Media:WATER, DRY CHEMICAL, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . AVOID INHALATION OF SMOKE.
Unusual Fire/Explosion Hazard:TONER IS A COMBUSTIBLE POWDER. LIKE MOST
ORGANIC MATERIALS IN POWDER FORM, WHEN DISPERSED IN AIR, IT CAN
FORM EXPLOSIVE MIXTURES.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP/VACUUM SPILLED TONER & CAREFULLY
TRANSFER INTO SEALABLE WASTE CNTNR. SWEEP SLOWLY TO MINIMIZE
GENERATION OF DUST DURING CLEAN-UP. IF VACUUM IS USED, MOTOR MUST
BE RATED AS DUST TIGHT. CONDUCT IVE HOSE BONDED TO MACHINE SHOULD
BE USED (SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE WITH WITH ADEQUATE VENTILATION.
AVOID PROLONGED INHALATION OF EXCESSIVE DUST.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Spec Gravity:>1 (H*2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:BLACK POWDER/FAINT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:AVOID PROLONGED INHALATION OF EXCESSIVE
DUST.
Hazardous Decomposition Products:PRODUCTS OF COMBUSTION MAY BE TOXIC.
AVOID BREATHING SMOKE.
* Disposal Considerations *
Waste Disposal Methods:WHEN DISPOSED, THIS MATL IS NOT HAZ WASTE
REQUIREMENTS MAY BE MOVE RESTRICTIVE. THEREFORE, CONSULTATION
W/APPROP FED, STATE & LOCAL WASTE DISP A UTH IS ADVISED. INCIN ONLY
IN CLSD CNTNR.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Supplemental Safety and Health
* Product Identification *
Preparer's Name:CHARLES MARTIN
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NITROGEN OXIDES-IRRITATION & BURNING.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:NITROGEN OXIDES-IRRITATION, HEADACHE,
DIZZINESS, FALL IN BLOOD PRESSURE, CONGESTION IN NOSE & THROAT.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN
ALL CASES.
* Fire Fighting Measures *
Fire Fighting Procedures:DON'T FIGHT FIRE INVOLVING THIS UNIT.
Unusual Fire/Explosion Hazard:THIS UNIT CONTAINS HIGH ENERGY MATERIALS.
*Handling and Storage *
Handling and Storage Precautions:HANDLE W/CARE AVOIDING ELECTROSTATIC
DISCHARGE, HEAT & IMPACT. STORE IN DRY, MOISTURE FREE ENVIRONMENT.
Other Precautions:UNITS WHICH HAVE INCURRERD SUBSTANTIAL IMPACT MAY
SUSTAIN INTERNAL DAMAGE. CONSULT W/TRA ENGINEERING STAFF FOR
EVALUATION.
* Physical/Chemical Properties *
Appearance and Odor:METALLIC W/NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:ELECTROSTATIC DISCHARGE, HEAT & IMPACT.
Hazardous Decomposition Products:METAL FRAGMENTS. BY-PRODUCTS OF
COMBUSTION: CO2 & NITROGEN OXIDES.
* Disposal Considerations *
Waste Disposal Methods:UNITS SHOULD BE DEACTIVATED BY A RCRA PERMITTED
FACILITY IAW/FEDERAL, STATE & LOCAL REGULATIONS. EPA WASTE CODE
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR RESPIRATOR WITH FILTER CARTRIDGE IF
SPRAYING IN UNVENTILATED AREA.
Ventilation:GENERAL VENTILATION OF 1-3 CHANGES PER HOUR,WHEN SPRAYED.
Other Protective Equipment:NOT KNOWN
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING OR USE.LAUNDER
CONTAMINATED CLOTHES BEFORE REUSE.
Supplemental Safety and Health
ZE-3 OR ZE-4B EMULSIFIER;THIS ENTRY DESCRIBES ZL-2C WHICH MAY BE
INCLUDED I N OTHER KIT OF DIFFERENT METHOD & LEVEL;ZL-2C ALSO
AVAILABLE AS SEPARATE ITEM UNDER THE SAME METHOD & LVL;KEY1:N1
* Product Identification *
Product ID:ZL-2C ZYGLO PENETRANT
Kit Part:Y
Preparer's Name:BRUCE C. GRAHAM
* Composition/Information on Ingredients *
Ingred Name:DISTILLATES(PETROLEUM),CATALYTIC REFORMER FRACTIONATER
RESIDUE,LOW BOILING
Ingred Name:KEROSENE
Ingred Name:UNIDENTIFIED COMPONENTS
* Hazards Identification *
Health Hazards Acute and Chronic:IRRITATES EYES.
Effects of Overexposure:INHALATION:CAUSES DIZZINESS,DROWSINESS,NAUSEA;
SKIN:LIQUID IRRITATES BY DISSOLVING SKIN OIL; EYES:VAPORS/LIQUID
CAUSES IRRITATION; INGESTION:NOT LISTED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NOT KNOWN
* First Aid Measures *
First Aid:INHALATION:REMOVE TO FRESH AIR.IF BREATHING IS DIFFICULT,GIVE
OXYGEN; SKIN:REMOVE CONTAMINATED CLOTHES.WASH OFF WITH FLOWING
WATER.USE SOOTHING LOTION.IF IRRITATION PERSISTS,GET MEDICAL ATTN;
EYES:IMM EDIATELY RINSE/FLUSH WITH COPIOUS AMOUNT OF RUNNING
WATER,AND GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:1.0%
Upper Limits:6.0%
Extinguishing Media:CARBON DIOXIDE,FOAM
Fire Fighting Procedures:KEEP CONTAINERS COOL WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:WHEN INVOLVE IN COMBUSTION,MAY EMIT TOXIC
GASES AT OR ABOVE DECOMPOSITION TEMPERATURE.
* Accidental Release Measures *
Spill Release Procedures:REMOVE IGNITION SOURCES.SM QTY:WIPE UP OR MOP
UP BUT DO NOT BREATHE VAPORS.PLACE RAGS IN CLOSED DRUMS; LG
QTY:WEAR PERSONAL SAFETY EQUIPMENTS.DIKE AREA FAR AHEAD.ABSORB
LIQUID WITH COMMERCIAL ABSORBEN T.TRANSFER WASTE MATL IN SALVAGE
TANKS.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM HEAT SOURCES IN WELL
VENTILATED AREA.AVOID AGAINST PHYSICAL DAMAGE TO CONTAINERS.KEEP
CONTAINERS TIGHTLY CLOSED.
Other Precautions:DO NOT BREATHE VAPORS.DO NOT SMOKE WHILE USING.DO NOT
* Physical/Chemical Properties *
HCC:N1
Vapor Density:>1.0
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GREEN LIQUID,PETROLEUM HYDROCARBON ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE NOTED BY MANUFACTURER.
Stability Condition to Avoid:HEAT,HIGH TEMPERATURES
Hazardous Decomposition Products:EMITS OXIDES OF CARBON AND NITROGEN.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE OR DISPOSE OF AS EPA HAZARDOUS WASTE
FEDERAL,STATE,LOCAL REGULATIONS.IF LOCAL AUTHORITIES PROHIBIT
DUMPING RINSINGS DOWN THE SEWER,P URIFY RINSINGS WITH MAGNAFLUX
WASTEWATER SYSTEM.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED UNDER NORMAL PRODUCT USAGE.
Ventilation:NOT REQUIRED UNDER NORMAL PRODUCT USAGE.
Other Protective Equipment:NOT REQUIRED UNDER NORMAL PRODUCT USAGE.
Work Hygienic Practices:GOOD PERSONAL HYGIENE SHOULD BE PRACTICED.
Supplemental Safety and Health
WASTE CONT'D: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE
* First Aid Measures *
First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Extinguishing Media:WATERSPRAY
Fire Fighting Procedures:IF PRODUCT BECOMES INVOLVED IN FIRE SITUATION
EXTINGUISHING MEDIA FOR SURROUNDING MATERIAL SHOULD BE APPROPRIATE.
Unusual Fire/Explosion Hazard:PRODUCT WILL NOT BURN.
* Accidental Release Measures *
Spill Release Procedures:USE PAPER TOWELS TO PICKUP GELLED MATERIAL.
WASH AREA W/SOAP & WATER AFTER CLEANUP IS COMPLETE.
*Handling and Storage *
Handling and Storage Precautions:GOOD PERSONAL HYGIENE SHOULD BE
PRACTICED.
* Physical/Chemical Properties *
Appearance and Odor:GELLED MEDIA OF VARING COLORS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:OBSERVE ASEPTIC TECHNIQUES & ESTABLISHED
PRECAUTIONS AGAINST MICROBIOLOGICAL HAZARDS THROUGHOUT ALL
PROCEDURES. AFTER USE, PREPARED PLATES, SPECIMEN CONTAINERS & OTHER
CONTAMINATED MATERIALS MUST BE S TERILED BY AUTOCLAVING. (SEE SUPP)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURE EXCEEDS OCCUPATIONAL EXPOS LIMITS,
WEAR A NIOSH APPRVD RESPIRATOR. PROPER EQUIPMENT INCLUDES A NIOSH
APPRVD COMBINATION ORGANIC VAPOR/PARTICULATE FILTER CHEMICAL
CARTRIDGE RESPIRATOR FOR L OW CONCENTRATIONS OR NIOSH (ING 7)
Ventilation:GENERAL: HIGHLY RECOMD FOR ALL INDOOR SITUATIONS TO CONTROL
FUGITIVE EMISSIONS. ELECTRICAL & MECHANICAL EQUIP (ING 9)
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . IN
CONFINED SPACES/WHERE RISK OF SKIN EXPOS IS HIGH WEAR IMPERVIOUS
CLTHG.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING PRIOR TO REUSE.
USE GOOD PERSONAL HYGIENE.
Supplemental Safety and Health
SPILL PROC: IF SAFE TO DO SO. DIKE & CONTAIN LAND SPILLS; CONTAIN WATER
SPILLS BY BOOMING. USE WATER FOG TO KNOCK DOWN VAPORS; CONTAIN
RUNOFF. FOR LARGE SPILLS, REMOVE BY MECH MEANS & PLACE IN CNTNRS.
ABSORB RESIDUE OR SMALL SPILLS W/ABSORB MATL & REMOVE TO
NON-LEAKING CNTNRS FOR DISPOSAL. FLUSH AREA W/WATER (ING 3)
* Product Identification *
* Composition/Information on Ingredients *
MG/KG.
Ingred Name:SUPDAT: TO REMOVE TRACE RESIDUE. DISPOSE OF RECOVERED MATL
AS NOTED IN WASTE DISPOSAL SECTION. NOTIFY APPROP (ING 4)
Ingred Name:ING 3: ENVIRONMENTAL AGENCIES. DO NOT ALLOW PRODUCT OR
RUNOFF FROM FIRE CONTROL TO ENTER STORM OR SANITARY (ING 5)
Ingred Name:ING 4: SEWERS, LAKES, RIVERS, STREAMS OR PUBLIC WATERWAYS.
BLOCK OFF DRAINS & DITCHES. PROVINCIAL REGS REQUIRE & (ING 6)
Ingred Name:ING 5: FEDERAL REGS MAY REQUIRE THAT ENVIRONMENTAL &/OR
OTHER AGENCIES BE NOTIFIED OF A SPILL INCIDENT.
Ingred Name:RESP PROT: APPRVD ATMOSPHERE-SUPPLIED, POSITIVE PRESSURE
DEMAND SELF-CONTAINED OR AIRLINE BREATHING APPARATUS (ING 8)
Ingred Name:ING 7: FOR HIGH CONCENTRATIONS.
Ingred Name:VENT: SHOULD BE EXPLOSION PROOF. LOCAL: ALSO RECOMD WHERE
Ingred Name:ING 9: AIRBORNE CONCENTRATIONS BELOW THE RECOMD
OR LOCALLY).
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:MAY BE IRRITATING TO SKIN & EYES.
PRLNGD & RPTD CNTCT W/SKIN CAN CAUSE DEFATTING & DRYING OF SKIN
RSLTG IN SKIN IRRITATION & DERMATITIS. VAPORS ARE MODERATELY
IRRITATING TO EYES & RESPIRATORY PASSAGES . PRLNGD EXPOSURE TO HIGH
VAPOR CONCENTRATION CAN CAUSE HEADACHE, DIZZINESS, NAUSEA & CNS
DEPRESSION. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: LIQUID IS HIGHLY TOXIC WHEN TAKEN
INTO LUNGS CAUSING SEVERE CHEMICAL PNEUMONITIS. CHRONIC: TOLUENE
APPEARS ON THE NAVY LIST OF OCCUPATIONAL CHEMICAL REPRODUCTIVE
HAZARDS. SEEK CONSULTATION F ROM APPROPRIATE HEALTH PROFESSIONALS
CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING & EXPOSURE INFO
.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: REMOVE FROM FURTHER EXPOSURE & RESTORE BREATHING, IF
MIN. SKIN: WASH CONTAMD SKIN W/MILD SOAP & WATER. IF IRRITATION
OCCURS & PERSISTS, OBTAIN MED ATTN. INGEST: DO NOT INDUCE
VOMITING. OBTAIN MED ATTN IMMED. NOTE TO MD: MAIN HAZARD FOLLOWING
ACCIDENTAL INGEST IS ASPIRATION OF LIQUID INTO LUNGS PRODUCING CHEM
PNEUMONITIS.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1.0%
Upper Limits:7.1%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, FOAM, WATER FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . FLAMMABLE. DO NOT USE WATER EXCEPT AS A FOG.
Unusual Fire/Explosion Hazard:VAPORS FORM EXPLOSIVE MIXTURE W/AIR
BETWEEN UPPER & LOWER FLAMMABLE LIMITS. VAPORS MAY TRAVEL ALONG
GROUND AND FLASHBACK ALONG VAPOR TRAIL MAY OCCUR.
* Accidental Release Measures *
Spill Release Procedures:ISSUE WARNING "FLAMMABLE." ELIMINATE ALL IGNIT
SOURCES. ISOLATE HAZARD AREA & RESTRICT ACCESS. TRY TO WORK UP WIND
OF SPILL. AVOID DIRECT CONTACT W/MATL. WEAR APPROP NIOSH APPRVD
BRTHG APPARATUS (IF A PPLICABLE) & PROT CLTHG. STOP LEAK
ONLY(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA, AWAY FROM HEAT & IGNITION SOURCES. AVOID BREATHING VAPORS &
PROLONGED OR REPEATED CONTACT WITH SKIN.
Other Precautions:BOND & GROUND TRANSFER CONTAINERS & EQUIPMENT TO
AVOID STATIC ACCUMULATION. EMPTY CONTAINERS ARE HAZARDOUS, MAY
CONTAIN FLAMMABLE/EXPLOSIVE LIQUID RESIDUE OR VAPORS. KEEP AWAY
FROM SPARKS AND OPEN OPE N FLAMES.
* Physical/Chemical Properties *
Vapor Density:3.1
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQUID; AROMATIC HYDROCARBON ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZING AGENTS, LEWIS OR MINERAL ACIDS.
Stability Condition to Avoid:AVOID EXCESSIVE HEAT,OPEN FLAMES AND ALL
IGNITION SOURCES.
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE ARE
PRODUCED ON COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE & LOCAL REGULATIONS . RECLAIM OR DISPOSE OF AT A LICENSED
WASTE DISPOSAL COMPANY. INCINERATE WITH APPROVAL OF ENVIRONMENT
AUTHORITY. LANDFILL A BSORBED MATERIAL IN A GOVERNMENT APPROVED
SITE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPRVD RESPIRATOR W/FULL FACEPIECE IF
EXP IS EXCESSIVE.
Ventilation:LOCAL EXHAUST VENTILATION PREFERRED.
Supplemental Safety and Health
* Product Identification *
Product ID:TRIBUTOXYETHYL PHOSPHATE
* Composition/Information on Ingredients *
* Hazards Identification *
Effects of Overexposure:MAY CAUSE EYE,SKIN & RESPIRATORY IRRITATION IN
EXPOSED INDIVIDUALS.MAY BE HARMFUL IF SWALLOWED.
* First Aid Measures *
PHYSICIAN.SKIN:WASH W/SOAP,PLENTY OF H*2O.WASH CLOTHING BEFORE
REUSE.INHAL:REMOVE TO FRESH AIR.IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION,PR EFERABLY MOUTH-TO-MOUTH.IF BREATHING(SEE SUPP DATA
* Fire Fighting Measures *
Extinguishing Media:CO*2,DRY CHEMICAL,FOAM/H*2O.
Fire Fighting Procedures:WEAR FULL PROT CLOTHING,SELF-CONTAINED
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:PHOSPHORUS OXIDE FUMES MAY BE PRODUCED
DURING FIRE.
* Accidental Release Measures *
Spill Release Procedures:SPILLS SHOULD BE CONFINED & ABSORBED ON
SUITABLE MEDIUM SUCH AS SAW-DUST,CLAY OR FILTERCEL & DISPOSED OF AS
RECOMMENDED.THIS MATL SHOULD NOT BE SPILLED,DUMPED,RINSED OR WASHED
INTO SEWERS OR PUBLIC WA TERWAYS.
*Handling and Storage *
Handling and Storage Precautions:WASH THOROUGHLY AFTER HANDLING.EMPTY
CNTNR RETAINS VAPOR & PRODUCT RESIDUE.OBSERVE LABEL SAFEGUARDS.DO
NOT REUSE CNTNR.AVOID SKIN & EYE CONTACT.
Other Precautions:USE W/ADEQUATE VENT OR NIOSH/MSHA APPROVED
RESPIRATOR.
* Physical/Chemical Properties *
Appearance and Odor:CLEAR,OILY LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:PHOSPHORUS OXIDE FUMES MAY BE PRODUCED
DURING FIRES.
* Disposal Considerations *
Waste Disposal Methods:WASTE PRODUCT SHOULD BE INCINERATED DISPOSED OF
IN APPROVED HAZARDOUS WASTE LANDFILL IN ACCORDANCE WITH LOCAL,STATE
& FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Product ID: QED, ENVIRONMENTALLY PREFERRED SOLVENT (SEE SUPPLEMENTAL)
Proprietary Ind: Y
*
Contractor Summary
*
*
Item Description Information
*
Item Manager: S9G
Item Name: CLEANING COMPOUND,SOLVENT
Specification Number: UNKNOWN
Unit of Issue: BX
UI Container Qty: 1
Type of Container: CONTAINER
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INGESTION: SWALLOWING LARGE AMOUNTS MAY BE HARMFUL, BY
CAUSING GASTROINTESTINAL IRRITATION.INHALATION: BREATHING LARGE AMOUNTS MAY
BE HARMFUL, BY CAUSING NOSE, THROAT, RESPIRATORY TRACT IRRITATION. EYES:
IRRITANT. LIQUID CONTACT WILL IRRITATE EYES AND MAY CAUSE STINGING, TEARING
AND REDNESS. SKIN CONTACT: MAY CAUSE MILD IRRITATION OF REDNESS AND BURNING.
Signs And Symptions Of Overexposure: INGESTION: SWALLOWING LARGE AMOUNTS MAY BE
HARMFUL, BY CAUSING GASTROINTESTINAL IRRITATION. INHALATION: BREATHING LARGE
AMOUNTS MAY BE HARMFUL, BY CAUSING NOSE, THROAT, RESPIRATORY TRACT
IRRITATION. EYES: IRRITANT. LIQUID CONTACT WILL IRRITATE EYES AND MAY CAUSE
STINGING, TEARING AND REDNESS. SKIN CONTACT: MAY CAUSE MILD IRRITATION OF
REDNESS AND BURNING.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGESTION: SEEK MEDICAL ATT'N IMMEDIATELY. IF INDIVIDUAL IS DROWSY
OR UNCONSCIOUS, DON'T GIVE ANYTHING BY MOUTH; PLACE INDIVIDUAL ON LEFT SIDE
WITH HEAD DOWN. CONTACT MEDICAL FACILITY OR POISON CONTRO L CENTER FOR ADVICE
ABOUT WHETHER TO INDUCE VOMITING. INHALATION: REMOVE TO FRESH AIR, IF
BREATHING IS DIFFICULT GIVE OXYGEN. KEEP PERSON WARM & QUIET. SEEK
MINUTES. GET MEDICAL ATT'N IF IRRITATION PERSISTS. SKIN: WASH WITH SOAP &
WATER. THOROUGHLY CLEAN CONTAMINATED CLOTHING & SHOES BEFORE REUSE. IF
SYMPTOMS PERSIST, SEEK MEDICA L ATT'N.
*
Handling and Disposal
*
Spill Release Procedures: SMALL: ABSORB LIQUID ON VERMICULITE, FLOOR ABSORBENT,
OR OTHER ABSORBENT MATERIAL AND TRANSFER TO HOOD. LARGE: ELIMINATE ALL
IGNITION SOURCES. PERSONS NOT WEARING PROTECTIVE EQUIPMENT SHOULD BE EXCLUD
ED FROM AREA OF SPILL. STOP SPILL AT SOURCE, PREVENT FROM ENTERING DRAINS,
SEWERS, STREAMS, ETC. IF RUNOFF OCCURS, NOTIFY AUTHORITIES. PUMP OR VACUUM
TRANSFER TO CLEAN CONTAINERS.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: QED LIQUID IS TO BE DISPOSED OF ACCORDING TO LOCAL,
STATE, AND FEDERAL REGULATIONS. PLEASE CALL US IF YOU NEED ADDITIONAL
DISPOSAL INFORMATION.
Handling And Storage Precautions: SINCE EMPTY CONTAINERS RETAIN PRODUCT
RESIDUES. ALL METAL PAILS OR DRUMS SHOULD BE GROUNDED AND/OR BONDED WHEN
MATERIAL IS TRANSFERRED. ANY USE OF THIS PRODUCT IN ELEVATED TEMPERATURE
PROCESSES SHOULD BE THOROUGHLY EVALUATED TO ESTABLISH & MAINTAIN SAFE
OPERATING CONDITIONS.
Other Precautions: KEEP THIS AND ALL CHEMICALS OUT OF THE REACH OF CHILDREN.
*
Fire and Explosion Hazard Information
*
Flash Point Method: TCC
Lower Limits: 1.2
Upper Limits: 9.6
Extinguishing Media: REGULAR FOAM, WATER FOG, CO2, DRY CHEMICALS, CLASS B.
Fire Fighting Procedures: KEEP FIRE EXPOSED CONTAINERS COOL WITH WATER. FIRE
FIGHTERS SHOULD WEAR SELF-CONTAINED BREATHING APPARATUS WITH A FULL FAEPIECE
OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WITH APPROPRIATE GEAR AND
CHEMICAL RESISTANT PERSONAL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard: VAPORS ARE HEAVIER THAN AIR AND MAY TRAVEL ALONG
THE GROUND OR BE MOVED BY VENTILATION AND IGNITED BY HEAT, PILOT LIGHTS,
OTHER FLAMES AND IGNITION SOURCES AT LOCATIONS DISTANT FROM MATERIAL
HANDLIN G POINT. NEVER USE WELDING OR CUTTING TORCH ON OR NEAR DRUM (EVEN
EMPTY) BECAUSE PRODUCT CAN IGNITE EXPLOSIVELY.
*
*
Respiratory Protection: NOT REQUIRED UNDER CONDITIONS OF NORMAL USE. IF VAPOR
MIST IS GENERATED USE A NIOSH CERTIFIED ORGANIC VAPOR MASK.
Ventilation: LOCAL EXHAUST/HOOD OR FAN MAY BE USED.
Other Protective Equipment: NONE REQUIRED UNDER NORMAL USE.
Work Hygienic Practices: STORE RAGS USED WITH THIS MATERIAL IN AN AIR TIGHT,
METAL CONTAINER TO PREVENT SPONTANEOUS COMBUSTION. TREAT THIS CHEMICAL WITH
RESPECT AND FOLLOW ALL MSDS INSTRUCTIONS.
*
Physical/Chemical Properties
*
HCC: F4
Solubility in Water: NEGLIGIBLE.
Appearance and Odor: CLEAR, COLORLESS LIQUID; MILD PETROLEUM ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: SOURCES OF IGNITION SUCH AS SPARKS, HOT SPOTS,
WELDING, FLAMES AND CIGARETTES. IGNITION/FLASH MAY RESULT IF CONCENTRATION OF
PRODUCT IS IN THE FLAMMMABLE RANGE.
Materials To Avoid: IF MIXED WITH STRONG OXIDIZERS AND/OR ACIDS THERE IS THE
POSSIBILITY OF A DANGEROUS CHEMICAL REACTION.
Hazardous Decomposition Products: MAY FORM CARBON DIOXIDE AND CARBON MONOXIDE
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
Federal Regulatory Information: RCRA REGULATED. ALL MATERIALS IN PRODUCT ARE
TSCA LISTED.
*
Other Information
*
Other Information: UNDER RCRA, THIS MATERIALS IS CONSIDERED A HAZARDOUS WASTE
*
Transportation Information
*
Product ID: QED, ENVIRONMENTALLY PREFERRED SOLVENT (SEE SUPPLEMENTAL)
Multiple KIT Number: 0
Unit Of Issue: BX
Container QTY: 1
Type Of Container: CONTAINER
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Product ID: QED, ENVIRONMENTALLY PREFERRED SOLVENT (SEE SUPPLEMENTAL)
Company Name: ECOLINK INC
Label Required IND: Y
Status Code: A
Origination Code: F
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: NO
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: N/P. INGESTION: SWALLOWING LARGE
AMOUNTS MAY BE HARMFUL, BY CAUSING GASTROINTESTINAL IRRITATION. INHALATION:
BREATHING LARGE AMOUNTS MAY BE HARMFUL, BY CAUSING NOSE, THROAT, RESPIRATO RY
TRACT IRRITATION. EYES: IRRITANT. LIQUID CONTACT WILL IRRITATE EYES AND MAY
CAUSE STINGING, TEARING AND REDNESS. SKIN CONTACT: MAY CAUSE MILD IRRITATION
OF REDNESS AND BURNING.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR NIOSH/MSHA APPROVED FACE MASK W/ORGANIC
VAPOR CANISTER.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
KEY1;F3.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:PENTANE, 2,2,4-TRIMETHYL-; (PENTANE,
2,2,4-TRIMETHYLISO-OCTANE) (C*8HL*8)
OSHA PEL:N/K
ACGIH TLV:N/K
Fraction by Wt: SEE ING
OSHA PEL:1 MG/M3 (MFR)
ACGIH TLV:1 MG/M3 (MFR)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:CONTAINS LOW CONCENTRATION(S) OF
MATERIAL(S) KNOWN TO STATE OF CALIFORNIA TO CAUSE CANCER. SUCH
CONCENTRATION(S) IS/ARE SUBSTANTIALLY BELOW OSHA-HCS THRESHOLDS
WHICH WOULD REQUIRE LISTING HEREIN AS A COMPONENT OF THIS MIXTURE.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
W/LARGE VOLUMES OF WATER. INHAL:IMMEDIATELY MOVE TO FRESH AIR. GIVE
OXYGEN IF BREATHING IS LABORED. IF BREATHING STOPS, GIVE ARTIFICIAL
RESPIRATI ON. INGEST:NEVER GIVE ANYTHING BY MOUTHTO AN UNCONSCIOUS
PERSON. NEVER TRY TO MAKE AN UNCONSCIOUS PERSON VOMIT. DO NOT
INDUCE VOMITING.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:1.1%
Upper Limits:6%
Extinguishing Media:CO2, FOAM, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CAN REACT VIGOROUSLY W/REDUCING
MATERIALS.
* Accidental Release Measures *
Spill Release Procedures:TAKE UP W/ABSORBENT MATERIAL. VENTILATE AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN SEALED CNTNR IN COOL, DRY
LOCATION. KEEP AWAY FROM HEAT. STORE IN DRY, WELL VENTILATED AREA.
KEEP AWAY FROM IGNIT SOURCES. AVOID BRTHG VAPS.
Other Precautions:AVOID EYE/SKIN CONT. THIS MATL IS INTENDED FOR R&D
USE ONLY & MAY NOT BE USED FOR DRUG, HOUSEHOLD/OTHER PURPOSES. IT
SHOULD BE HANDLED ONLY BY QUALIFIED PERSONS TRAINED IN LAB PROCS &
GOOD SAFETY PRAC TICES.
* Physical/Chemical Properties *
HCC:F3
Vapor Density:3.9
Evaporation Rate & Reference:>1 (ETHER=1)
Appearance and Odor:CLEAR COLORLESS LIQUID.
Percent Volatiles by Volume:1
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REDUCING AGENTS.
* Disposal Considerations *
Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Subsets and Splits