text
stringlengths 789
11.3k
| label
int64 0
1
| label_text
stringclasses 2
values |
|---|---|---|
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR FOR OIL MIST
IF REQUIRED.
Ventilation:LOCAL & MECHANICAL(GENERAL) VENTILATION RECOMMENDED TO
PREVENT BUILD-UP OF OIL MISTS IN THE WORKING AREA.
Other Protective Equipment:EYE WASH STATION AND SAFETY SHOWER.
INDUSTRIAL-TYPE WORK CLOTHING AND APRON AS REQUIRED.
Work Hygienic Practices:CONTAMINATED CLOTHING SHOULD BE CHANGED
IMMEDIATELY AND THOROUGHLY CLEANSED BEFORE RE-USE. THIS APPLIES TO
UNDERGARMENTS
Supplemental Safety and Health
AVOID PROLONGED OR REPEATED EXPOSURE. DO NOT GET ON SKIN OR IN EYES. DO
NOT BREATHE VAPORS OR MISTS. BUILD-UP OF OIL MISTS IN THE WORKING
ATMOSPHERE MUST BE PREVENTED. DO NOT INGEST. IF ASPIRATED INTO THE
LUNGS, SEND PATIENT TO HOSPITAL OROBTAIN MEDICAL ATTENTION
IMMEDIATELY.
* Product Identification *
Kit Part:Y
DIV
* Composition/Information on Ingredients *
Ingred Name:ESTERS
Other REC Limits:NONE SPECIFIED
Ingred Name:SURFACTANT(S) - TYPE NOT SPECIFIED
Other REC Limits:NONE SPECIFIED
Ingred Name:HYDROCARBON SOLVENTS
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE, SKIN, GASTROINTESTINAL
TRACT IRRITATION. CHRONIC: PROLONGED OR REPEATED SKIN CONTACT MAY
RESULT IN AN ALLERGIC SKIN REACTION OR DEFATTING OF THE SKIN.
Explanation of Carcinogenicity:NONE OF THE COMPOUNDS IN THIS PRODUCT IS
LISTED BY IARC, NTP, OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYE, SKIN, GASTROINTESTINAL TRACT IRRITATION
SUCH AS TEARING, RASH, OR NAUSEA.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING THE SKIN MAY BE AT
INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
EYELID. GET MEDICAL ATTENTION IMMEDIATELY. SKIN: WASH WITH SOAP &
WATER. REMOVE CONTAMINATED CLOTHING. GET MEDICAL ADVICE.
ASPIRATION: GET I MMEDIATE MEDICAL ATTENTION. INGESTION: DO NOT
INDUCE VOMITING. GIVE NOTHING BY MOUTH IF UNCONSCIOUS. GET MEDICAL
ATTENTION IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY CAUSE
PRODUCTION OF HAZARDOUS DECOMPOSITION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:PREVENT ENTRY OF PRODUCT INTO STREAMS, SEWERS
AND RIVERS. SMALL: SHOULD BE SOAKED UP WITH ABSORBENT CLAY OR
DIATOMACEOUS EARTH AND DISPOSED OF IN AN APPROVED MANNER. LARGE:
CONTAIN AS SOON AS POSSIBLE AND REMOVE BY BEST AVAILABLE MEANS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA. KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. PROTECT
CONTAINERS FROM PHYSICAL DAMAGE.
Other Precautions:TO AVOID THE POSSIBILITY OF SKIN DISORDERS, REPEATED
OR PROLONGED CONTACT WITH LUBRICANTS AND INDUSTRIAL OILS IS TO BE
AVOIDED. IT IS ESSENTIAL THAT ALL WHO COME INTO CONTACT WITH SUCH
PRODUCTS MAINTA IN HIGH STANDARDS OF PERSONAL HYGIENE.
* Physical/Chemical Properties *
HCC:V4
Appearance and Odor:YELLOW GREEN FLUORESCENT MOBILE LIQUID. ODOR NOT
SPECIFIED.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN FLAMES
Hazardous Decomposition Products:CARBON MONOXIDE AND CARBON DIOXIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL SHOULD BE BY INCINERATION IN ACCORDANCE
WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS. TAKE CARE
TO AVOID FLARE-UP WHEN INCINERATING.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED UNDER INTENDED USE. AVOID
BREATHING SMOKE.
Ventilation:ADEQUATE
Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, PROTECTIVE
CLOTHING
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES.
Supplemental Safety and Health
KEY1:C1. EACH FLEXIBLE TUBE CONTAINS TWO SEALED GLASS AMPULES, ONE WITH
APPROXIMATELY 0.4 GRAM ACETIC ACID SORBED ON SILICA GEL (PNI A) AND
ONE WITH APPROXIMATELY 0.3 GRAM ETHYLENEDIAMIONE SORBED ON P UMICE
(PNI B). WHEN AMPULES ARE CRUSHED,THE REACTION PRODUCT IS
ETHYLENEDIAMINE ACETATE SMOKE.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
Ingred Name:PUMICE
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, LIVER,
KIDNEY, NOSE, THROAT. ACUTE- ETHYLENEDIAMINE IS IN SEALED TUBE. IF
BROKEN, MAY CAUSE IRRITATION OF EYES, SKIN AND RESPIRATORY TRACT.
HARMFUL IF INGESTED. NOTE THAT SMOK E GENERATION IS UNDER MANUAL
CONTROL. OVEREXPOSURE IS NOT POSSIBLE. CHRONIC- UNKNOWN.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, TEARING, PAIN
* First Aid Measures *
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:REMOVE TO FRESH
MINUTES, HOLDING EYELIDS OPEN. CALL PHYSICIAN. SKIN:FLUSH WITH
PLENTY OF W ATER. ORAL:IF TUBE IS SWALLOWED & CONSCIOUS, DRINK TWO
GLASSES OF WATER. GET MEDICAL ATTENTION IMMEDIATELY. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Lower Limits:4.2%
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL
FACEPIECE. LESS THAN 1 GRAM FLAMMABLE MATERIAL PER SEALED TUBE.
Unusual Fire/Explosion Hazard:AMPULES MAY RUPTURE AND EMIT TOXIC OR
CORROSIVE GASES.
* Accidental Release Measures *
Spill Release Procedures:IF SMOKE IS GENERATED, LEAVE AREA UNTIL SMOKE
MATERIAL AND PLACE IN A BUCKET 3/4 FULL OF WATER. EXAMINE THAT BOTH
AMPULES WITHIN THETUBE ARE CRUSHED. IF ONE NOT BROKEN, CRUSH IT.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINER, IN
VENTILATED AREA. DO NOT BREAK AMPULES BEFORE PROPER USE.
Other Precautions:WASH THOROUGHLY WITH WATER AFTER HANDLING AND BEFORE
EATING, DRINKING. KEEP OUT OF REACH OF CHILDREN. THIS PRODUCT IS
FOR USE IN DETERMINATION OF DIRECTION AND VELOCITY OF VENTILATION
AIR CURRENTS. AV OID BREATHING EMMISIONS FROM TUBE.
* Physical/Chemical Properties *
HCC:F6
NRC/State Lic Num:NOT RELEVANT
Spec Gravity:0.9;ETHYLENEDIA
Viscosity:NOT RELEVANT
Solubility in Water:COMPLETE (BASE)
Appearance and Odor:ETHYLENEDIAMINE/PUMICE AMPULE - GRAY TO BLACK
GRANULES, AMMONIA ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:EXCESSIVE HEAT
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. FILTER SOLIDS FROM THE WATER AND DISPOSE
TO TRASH. THE FILTERED WATER CAN BE RELEASED TO THE DRAIN.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE W/POS FRESH AIR CROSS VENT. HANDLE/ MIX POWDER
CAREFULLY TO AVOID CREATING DUST. STIR CAREFULLY TO AVOID SPLASHES.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH SKIN THOROUGHLY WITH SOAP AND WATER OR
HAND CLEANER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:WHITE DRY TILE GROUT
* Composition/Information on Ingredients *
Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
OSHA PEL:SEE TABLE Z3
Ingred Name:PORTLAND CEMENT
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:WET CEMENT CAN DRY SKIN AND CAUSE
ALKALI BURNS. PROLONGED OR REPEATED OVEREXPOSURE TO DUST MAY CAUSE
SKIN, EYE, NOSE AND THROAT IRRITATION. HYPERSENSITIVE INDIVIDUALS
MAY DEVELOP AN ALLERGIC DERMATITI S. PROLONGED EXPOSURE TO
RESPIRABLE CRYSTALLINE SILICA MAY CAUSE DELAYED LUNG INJURY
(SILICOSIS).
Explanation of Carcinogenicity:CRYSTALLINE SILICA:GROUP 2A (IARC).
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:EXISTING SKIN CONDITIONS.
* First Aid Measures *
SKIN: WASH THOROUGHLY WITH SOAP AND WATER OR HAND CLEANER. WASH
CLOTHING BEFORE REUSEING. CALL PHYSICIAN IMMED. INGEST: GET MD
IMMED . IN HAL: REMOVE TO FRESH AIR. SUPPORT BRTHG. (GIVE O*2/ARTF
RESP) .
* Fire Fighting Measures *
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:AVOID RAISING EXCESSIVE DUST. SWEEP UP, USE
WATER MIST OR VACUUM.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY PLACE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. USE ONLY AS DIRECTED
ON LABEL. CLOSE CONTAINER AFTER EACH USE. DO NOT RE-USE CONTAINER.
AVOID SKIN AND EYE CONTACT.
* Physical/Chemical Properties *
HCC:T6
Appearance and Odor:
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:NONE KNOWN.
Conditions to Avoid Polymerization:HEATS AND HARDENS WITH WATER.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL SOLID WASTE
DISPOSAL REGULATIONS. DO NOT FLUSH MATERIAL DOWN DRAIN.
| 1 | eyes_protection_mandatory |
Control Measures
*
Cage: 0FTT5
*
Preparer Co. when other than Responsible Party Co.
*
Cage: 0FTT5
*
Contractor Summary
*
Cage: 0FTT5
*
Item Description Information
*
Item Manager: GSA
Item Name: PRIMER COATING
Unit of Issue: PT
UI Container Qty: 4
Type of Container: METAL
*
Ingredients
*
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE SPECIFIED
------------------------------
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED
------------------------------
Other REC Limits: NONE SPECIFIED
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING THE CONTENTS MAY BE HARMFUL/FATAL. REPORTS HAVE ASSOCIATED
REPEATED/PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN
& N ERVOUS SYSTEM DAMAGE. IN CONFINED AREASVAPORS ARE ANESTHETIC. IRRIT
TO SKIN AND RESPIRATORY TRACT. OVEREXPOSURE MAY
Signs And Symptions Of Overexposure: IRRITATION TO EYES, THROAT AND RESPIRATORY
TRACT. MAY CAUSE HEADACHES, NAUSEA AND VOMITING. RESULT IN LIGHT HEADEDNESS,
STAGGERING GAIT, GIDDINESS AND POSSIBLE NAUSEA. HARMFUL IF SWALLOWED. SEVERE
EYE IRRITATION.
Medical Cond Aggravated By Exposure: RESPIRATORY AILMENTS.
First Aid: FOR CONTACT WITH SKIN OR CLOTHES WASH WITH SOAP AND WATER; WASH
PHYSICIAN/OPHTHALMOLOGIST IMMEDIATELY. INGEST: DO NOT INDUCE VOMI TING! GET
IMMEDIATE MEDICAL AID. INHAL:REMOVE TO FRESH AIR AND GIVE ARTIFICIAL
RESPIRATION IF NECESSARY AND GET MEDICAL AID. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS PERSON.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION AND VENTILATE AREA.
MOP SPILLS WITH INERT ABSORBENT. AVOID BREATHING VAPORS.
Waste Disposal Methods: IN ACCORDANCE W/APPLICABLE FEDERAL/STATE/LOCAL REGS. DO
PROLONGED EXPOSURE TO SUN MAY CAUSE CAN TO BURST. DISCARD EMPTY CAN IN TRA SH
PICK-UP. DO NOT PLACE IN HOME TRASH COMPACTOR.
Handling And Storage Precautions: KEEP FROM CHILDREN! CAUTION: CONTENTS UNDER
OR VAPOR/CONTACT W/EYES-SKIN.
Other Precautions: AVOID CONTACT WITH EYES AND SKIN. USE WITH GOOD VENTILATION.
READ ENTIRE LABEL BEFORE USING. FOLLOW ALL LABEL DIRECTIONS. INTENTIONAL
MISUSE BY DELIBERATELY CONCENTRATING AND INHALING OR SWALLOWING CO NTENTS MAY
BE HARMFUL OR FATAL.
*
Fire and Explosion Hazard Information
*
Flash Point Text: NR
Lower Limits: 1.8
Upper Limits: 9.5
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM, SAND, WATER SPRAY.
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE-MAY BE USED TO KEEP FIRE
EXPOSED CNTNRS COOL. WEAR SCBA. USE SHIELDING TO PROTECT PERSONNEL AGAINST
BURSTING/RUPTURING/VENTING OF CNTNR
Unusual Fire/Explosion Hazard: DO NOT SPRAY NEAR OPEN FLAME. AT ELEVATED TEMP
*
*
Respiratory Protection: NONE BELOW TLV. USE NIOSH/MSHA APPROVED MASK ABOVE TLV.
Ventilation: LOCAL EXHAUST: PREFERRED. MECHANICAL (GENERAL): ACCEPTABLE AT
POINT OF MIST OR SPRAY RELEASE.
Other Protective Equipment: IMPERVIOUS CLOTHES TO PROTECT SKIN. EYE WASH
STATION.
Work Hygienic Practices: USE GOOD PERSONAL HYGIENE. DO NOT EAT, DRINK OR SMOKE
WHILE USING PRODUCT.
*
Physical/Chemical Properties
*
HCC: V3
Vapor Density: >1.5
Evaporation Rate & Reference: (BU AC = 1)
Solubility in Water: INSOLUBLE
Appearance and Odor: GRAY/PAINT
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXTREME HEAT.
Hazardous Decomposition Products: CARBON MONOXIDE AND POSSIBLE HYDROGEN
CHLORIDE
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: PT
Container QTY: 4
Type Of Container: METAL
*
Detail DOT Information
*
DOT PSN Code: DTJ
Symbols: D
DOT Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
Label: NONE
Bulk Pack: NONE
Vessel Stow Req: A
*
Detail IMO Information
*
IMO PSN Code: AKH
IMO Proper Shipping Name: AEROSOLS/AEROSOL PRODUCT ?
UN Hazard Class: 9?
IMO Packaging Group: -
Subsidiary Risk Label: -
*
Detail IATA Information
*
IATA PSN Code: ALS
IATA Proper Shipping Name: AEROSOLS, FLAMMABLE
IATA PSN Modifier: (EACH NOT EXCEEDING 1 L CAPACITY)
IATA UN Class: 2.1
IATA Label: FLAMMABLE GAS
*
Detail AFI Information
*
AFI PSN Code: ALS
AFI Proper Shipping Name: AEROSOLS, NONFLAMMABLE, N.O.S.
AFI PSN Modifier: CONTAINING SUBSTANCES IN CLASS 8, PACKING GROUP I OR II
AFI Hazard Class: FORB
Back Pack Reference: FORBIDDEN
*
HAZCOM Label
*
Cage: 0FTT5
Company Name: LHB INDUSTRIES
Label Required IND: Y
Status Code: C
Origination Code: G
Hazard And Precautions: INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING THE CONTENTS MAY BE HARMFUL/FATAL. REPORTS HAVE ASSOCIATED
REPEATED/PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN
& N ERVOUS SYSTEM DAMAGE. IN CONFINED AREASVAPORS ARE ANESTHETIC. IRRIT
TO SKIN AND RESPIRATORY TRACT. OVEREXPOSURE MAY IRRITATION TO EYES, THROAT
AND RESPIRATORY TRACT. MAY CAUSE HEADACHES, NAUSEA AND VOMITING.
RESULT IN LIGHT HEADEDNESS, STAGGERING GAIT,GIDDINESS AND POSSIBLE
NAUSEA. HARMFUL IF SWALLOWED. SEVERE EYE IRRITATION.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH ORGANIC VAPOR RESPIRATOR FOR CONFINED
AREAS.
Ventilation:LOCAL OR MECHANICAL
Other Protective Equipment:BARRIER SKIN CREAM
Work Hygienic Practices:WASH HANDS AFTER USE & BEFORE EATING OR
SMOKING.
Supplemental Safety and Health
* Product Identification *
Product ID:DYNATROL II PART A ACTIVATOR
* Composition/Information on Ingredients *
Ingred Name:TOLUENE-2,4-DIISOCYANATE (TDI) (SARA III)
Fraction by Wt: <5%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE IRRITATION TO
LUNGS & PULMONARY EDEMA MAY OCCUR AFTER A SERIOUS VAPOR EXPOSURE.
PULMONARY SENSITIZATION CAN OCCUR IN SOME INDIVIDUALS.
Explanation of Carcinogenicity:TDI POTENTIAL CARCINOGEN.
Effects of Overexposure:INHALATION: MAY CAUSE IRRITATION TO LUNGS &
PULMONARY EDEMA MAY OCCUR AFTER A SERIOUS VAPOR EXPOSURE. PULMONARY
SENSITIZATION CAN OCCUR IN SOME INDIVIDUALS.
Medical Cond Aggravated by Exposure:PRECLUDE FROM EXPOSURE THOSE
INDIVIDUALS HAVING A HISTORY OF RESPIRATORY ILLNESS, ASTHMATIC
CONDITIONS, EYE DAMAGE & TDI SENSITIZATIONS.
* First Aid Measures *
First Aid:SKIN: WASH W/SOAP & WATER. INHALATION: REMOVE TO FRESH AIR.
AID BREATHING, IF NECESSARY. GET MED ATT. EYES: FLUSH W/WATER FOR
MATERIAL & CO NSULT PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:DRY CHEMICAL, WATER FOG, FOAM & CO2
Fire Fighting Procedures:SCBA SHOULD BE WORN WHEN FIGHTING FIRES
INVOLVING CHEMICALS.
W/RELEASE OF CO2 WHICH CAN CAUSE PRESSURE BUILDUP IN CLOSED
CONTAINERS. USE COLD WATER TO COOL FIRE-EXPOSED CONTAINERS.
* Accidental Release Measures *
Spill Release Procedures:SCRAPE UP & PLACE IN CONTAINERS. ALLOW TO
HARDEN IN OPEN CONTAINERS. CO2 WILL BE EVOLVED. FINISH CLEARING
AREA W/SOLVENT SUCH AS CELLOSOLVE ACETATE. FOLLOW SOLVENT
MANUFACTURER'S PRECAUTIONS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN UNOPENED CONTAINERS AT OR
Other Precautions:THIS PRODUCT CONTAINS DIISOCYANATES. AVOID PROLONGED
BREATHING OF VAPORS & CONTACT W/EYES & SKIN. KEEP OUT OF REACH OF
CHILDREN.
* Physical/Chemical Properties *
Vapor Density:6.0
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR, LIGHT YELLOW LIQUID - TDI ODOR
Percent Volatiles by Volume:NEG.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
WATER OR MOISTURE & ANY OTHER PRODUCTS THAT MAY REACT W/ISOCYANATES.
Stability Condition to Avoid:HIGH TEMPERATURES
Hazardous Decomposition Products:TDI VAPORS, OXIDES OF NITROGEN, CO &
HCN.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Item Description Information
*
Item Manager: GSA
Item Name: ADHESIVE
Unit of Issue: CN
UI Container Qty: B
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:INHALATION OF VAPOR/MIST MAY CAUSE RESPIRATORY
IRRITATION & TEMPORARY NERVOUS SYSTEM IMPAIRMENT.CONTACT MAY CAUSE SKIN
& EYE IRRITATION.N-HEXANE MAY BE ABSORBED THROUSH SKIN IN HARMFUL
AMOUNTS.I NGESTION IS NOT A LIKELY ROUTE OF EXPOSURE.CHRONIC:PROLONGED
EXPOSURE MAY CAUSE DERMATITIS,NERVOUS SYSTEM DAMAGE.
Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR
GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN.
Signs And Symptions Of Overexposure: INHALED-RESPIRATORY IRRITATION, MILD
LIGHT-HEADEDNESS, WEAKNESS, DIZZINESS, HEADACHE, NAUSEA, FACIAL NUMBNESS.
SKIN-DEFATTING, IRRITATION, DERMATITIS. EYES-IRRITATION. INGESTED-WHILE NOT A
LIKELY ROUT E; IF CONCENTRATED & SWALLOWED-ASPIRATION AND/OR GI TRACT
IRRITATION MAY OCCUR-NAUSEA, VOMITING.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
PHYSICIAN. SKIN-WASH WITH MILD SOAP & WATER. INHALED-REMOVE TO
UNCONTAMINATED AIR. CALL A PHYSICIAN IF NOT BREATHING. INGESTED-DO NOT IN
DUCE VOMITING! CONTACT POISON CONTROL CENTER OR PHYSICIAN IMMEDIATELY.
*
Handling and Disposal
*
Spill Release Procedures: ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA.
WEAR APPROPRIATE PERSONAL PROTECTIVE GEAR. USE NON-SPARKING TOOLS. CONTAIN
SPILL. COVER WITH ABSORBENT MATERIAL AS NEEDED. COLLECT SPILLED MATERIAL.
PLACE IN A US DOT-APPROVED CONTAINER AND SEAL.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: INCINERATE ABSORBED AND PARTIALLY FULL CANS AFTER
MIXING WITH FLAMMABLE MATERIAL IN A LICENSED HAZARDOUS WASTE FACILITY. THE
FACILITY MUST BE CAPABLE OF HANDLING AEROSOL CANS. DO NOT PUNCTURE OR BURN
Handling And Storage Precautions: STORE IN A COOL, DRY PLACE AWAY FROM SOURCES
WORK/STORAGE AREA.
Other Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID SKIN & EYE
CONTACT.VAPORS RELEASED MAY BE EASILY IGNITED AND BURN EXPLOSIVELY. AVOID
PROLONGED BREATHING OF VAPORS AND SPRAY. USE ONLY IN WELL-VENTILATED AREAS.
IN TENTIONAL INHALATION MAY BE FATAL.
*
Fire and Explosion Hazard Information
*
Lower Limits: 1.0
Upper Limits: 7.0
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures: TREAT AS A PRESSURIZED CONTAINER. WEAR SELF-CONTAINED
BREATHING APPARATUS AND FULL FIRE FIGHTER'S PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard: EXTREMELY FLAMMABLE. TREAT AS A PRESSURIZED
CONTAINER. OVERHEATED, CLOSED CONTAINERS ADJACENT TO FIRE COULD EXPLODE DUE
TO PRESSURE BUILD-UP.
*
*
Respiratory Protection: DLA-: IF ENGINEERING CONTROLS FAIL OR NON-ROUTINE USE
OR AN EMERGENCY OCCURS; WEAR AN MSHA/NIOSH APPROVED RESPIRATOR WITH ORGANIC
VAPOR CARTRIDGE OR AN AIR-SUPPLIED RESPIRATOR OR SCBA, AS REQUIRED . USE IAW
Ventilation: USE ADEQUATE EXPLOSION-PROOF MECHANICAL VENTILATION OR LOCAL
EXHAUST TO MAINTAIN EXPOSURE BELOW TLV(S).
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. DLA-: EYE WASH
STATION & SAFETY SHOWER.
Work Hygienic Practices: WASH HANDS AFTER HANDLING AND BEFORE EATING, DRINKING,
OR SMOKING. LAUNDER CONTAMINATED CLOTHES BEFORE REUSE.
*
Physical/Chemical Properties
*
HCC: V3
B.P. Text: GAS
M.P/F.P Text: UNKNOWN
Decomp Text: UNKNOWN
Vapor Pres: GAS
Spec Gravity: <1
Viscosity: UNKNOWN
Solubility in Water: NEGLIGIBLE/NIL
Appearance and Odor: CLEAR LIQUID; HEXANE SOLVENT ODOR.
Corrosion Rate: UNKNOWN
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: DO NOT PUNCTURE OR INCINERATE CONTAINER. DO NOT
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE AND SMOKE
PARTICLES WHEN SUBJECTED TO EXCESSIVE HEAT OR FLAME.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Tech Entry NOS Shipping Nm: CONTAINS PROPANE AND ISOBUTANE
Net Unit Weight: 1.5 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CN
Container QTY: B
Additional Data: PSN ARE BEST GUESS BY DLA- STAFF.
*
Detail DOT Information
*
DOT PSN Code: DTJ
Symbols: D
DOT Proper Shipping Name: CONSUMER COMMODITY
Hazard Class: ORM-D
Label: NONE
Bulk Pack: NONE
Vessel Stow Req: A
*
Detail IMO Information
*
IMO PSN Code: EQB
IMO Proper Shipping Name: COMPRESSED GAS, FLAMMABLE, N.O.S. o
UN Hazard Class: 2(2.1)
IMO Packaging Group: -
Subsidiary Risk Label: -
*
Detail IATA Information
*
IATA PSN Code: HDW
IATA Proper Shipping Name: CONSUMER COMMODITY +
IATA UN Class: 9
IATA Label: MISCELLANEOUS
*
Detail AFI Information
*
AFI PSN Code: HEB
AFI Proper Shipping Name: CONSUMER COMMODITY
AFI Hazard Class: 9
Special Provisions: P5
*
HAZCOM Label
*
Company Name: MINNESOTA MINING AND MFG CO AUTOMOTIVE TRADES DIV
Street: 3M CTR
Label Required IND: Y
Status Code: C
Origination Code: F
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE! CONTENTS UNDER PRESSURE! INHALATION OF
VAPOR/MIST MAY CAUSE RESPIRATORY IRRITATION & TEMPORARY NERVOUS SYSTEM
IMPAIRMENT.CONTACT MAY CAUSE SKIN & EYE IRRITATION.N-HEXANE MAY BE
ABSORBED THR OUSH SKIN IN HARMFUL AMOUNTS.PROLONGED EXPOSURE MAY CAUSE
DERMATITIS,NERVOUS SYSTEM DAMAGE. TARGET ORGANS:NERVOUS
SYSTEM,LUNGS,SKIN,EYES. FIRST AID:EYES-IMMEDIATELY FLUSH WITH WATER FOR AT
WATER.INHALED-REMOVE TO UNCONTAMINATED AIR.CALL A PHYSICIAN IF NOT
BREATHING.INGESTED-DO NOT INDUCE VOMITING!CONTACT POISON CONTROL CENTER OR
PHYSICIAN IMMEDIATELY.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NON REQUIRED UNDER NORMAL CONDITIONS. IF HIGH
VAPORS/MIST IS GENERATED, USE NIOSH-APPROVED RESPIRATOR FOR ORGANIC
VAPORS AND MISTS. WEAR SUPPLIED-AIR RESPIRATOR PROTECTION IN
CONFINED OR ENCLOSED SPAC ES.
Ventilation:GOOD GENERAL VENTILATION.
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:WASH HANDS BEFORE EATING OR DRINKING. KEEP AWAY
FROM FOOD.
Supplemental Safety and Health
THIS IS PART "D" OF A FOUR PART KIT, SAME NSN. THIS PRODUCT IS A KIT OR
A MULTIPART WHICH CONSISTS OF MULTIPLE, INDEPENDENTLY PACKAGED
* Product Identification *
Kit Part:Y
CAGE:0K0U5
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits:NONE SPECIFIED
Ingred Name:PHOSPHORIC ACID (SARA III)
Other REC Limits:NONE SPECIFIED
OSHA PEL:1 MG/M3/3 STEL
Ingred Name:SILICA GEL/AMORPHOUS SILICA
Fraction by Wt: 3-7%
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE-EYE:CHEMICAL BURNS.
SKIN:CHEMICAL BURNS. INHALATION:IRRITATION OF UPPER RESPIRATORY
TRACT. INGESTION:UNLIKELY ROUTE, BUT CAN CAUSE DAMAGE TO GI AND
ORAL TISSUES. CHRONIC-ULCERATION, LUNG DAMAGE, PNEUMOCONIOSIS.
Effects of Overexposure:EYE:REDNESS, CHEMICAL BURNS, ULCER, PAIN,
TEARING, SWELLING, IMPAIRED VISION. SKIN:REDNESS, SWELLING,
DRYNESS, BLISTERING, ITCHING & PAIN. INHALATION:IRRITATION,
COUGHING, WHEEZING, TIGHTNESS IN CHEST , CONGESTION & COUGHING UP
BLOOD. INGESTION:VOMITING, ABDOMINAL PAIN, NAUSEA, ORAL & GI BURNS.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN AND LUNG
DISORDERS MAY BE MORE SUSCEPTIBLE TO THIS MATERIAL.
* First Aid Measures *
First Aid:INHALATION:REMOVE TO FRESH AIR, PROVIDE CPR/OXYGEN IF NEEDED.
CONTACT:WASH WITH SOAP AND WATER. GET MED ATTENTION IF SYMPTOMS
PERSIS T. INGESTION:DO NOT INDUCE VOMITING, DRINK 1-2 GLASSES OF
WATER. GET MEDICAL HELP IMMEDIATELY.
* Fire Fighting Measures *
Fire Fighting Procedures:WEAR NIOSH-APPROVED SELF-CONTAINED BREATHING
APPARATUS IF NEEDED.
Unusual Fire/Explosion Hazard:MAY EMIT TOXIC VAPORS IN THE HEAT OF
FIRE.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENTS. VENTILATE AREA.
COVER SPILL WITH A SLURRY OF SODA ASH AND SLAKED LIME. COLLECT
SPILLED MATERIAL. CLEAN UP RESIDUE. PLACE IN A US DOT-APPROVED
CONTAINER AND SEAL.
Neutralizing Agent:SODA ASH AND SLAKED LIME.
*Handling and Storage *
Handling and Storage Precautions:STORAGE-STORE AT ROOM TEMPERATURE.
KEEP AWAY FROM STRONG ALKALIS.
Other Precautions:AVOID CONTACT WITH EYES AND SKIN. USE IN A WELL
VENTILATED AREA. WASH THOROUGHLY AFTER HANDLING MATERIAL. KEEP AWAY
FROM REACH OF CHILDREN.
* Physical/Chemical Properties *
HCC:C1
pH:1.0
Solubility in Water:INFINITE
Appearance and Odor:BLUE GEL
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS, CORROSIVE TO METALS.
Stability Condition to Avoid:FIRE
Hazardous Decomposition Products:OXIDES OF PHOSPHORUS AND SILICON.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS. FLUSH SPENT SOLUTIONS AND SMALL QUANTITIES
NEUTRALIZED WASTE PRODUCT TO A WASTEWATER TREATMENT SYSTEM.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:OUTDOOR/OPEN AREAS:SANDING,GRINDING.USE
NIOSH/MSHA MECHANICAL FILTER.RESTRICTED VENT:WEAR NIOSH/MSHA
CHEM/MECH FILTERS. CONFINED AREAS:NIOSH/MSHA APPROVED AIR SUPPLY
RESPIRATOR HOODS.USE NIOSH/MSHA AP PROVED RESP.WHEN FLAME CUT SEE
SUP DATA
Ventilation:PROVIDE GENERAL DILUTION OR LOCAL EXHAUST VENT IN VOL &
PATT TO KEEP CONTAM CONC BELOW APPLICABLE SAFETY &HLTH STANDARDS
Other Protective Equipment:NOT REQUIRED
Work Hygienic Practices:REMOVE & WASH SOILED CLOTHING BEFORE REUSE WASH
HANDS BEFORE EATING,SMOKING OR USING THE WASH ROOM.
Supplemental Safety and Health
PRODUCT.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ALUMINUM SILICATE ANHYDROUS
Fraction by Wt: <
OSHA PEL:
ACGIH TLV:
Ingred Name:SILICA, AMORPHOUS, DIATOMACEOUS EARTH, CONTAINING LESS THAN
1% CRYSTALLINE SILICA
Fraction by Wt: < 5%
Ingred Name:2,2,4 TRIMETHYL PENTANE DIOL 1.3 MONOISOBUTYRATE
Fraction by Wt: < 5%
Other REC Limits:
OSHA PEL:
ACGIH TLV:
Ingred Name:AQUA AMMONIA
Fraction by Wt: <0.5%
OSHA PEL:
ACGIH TLV:
Ingred Name:WATER
Other REC Limits:
OSHA PEL:
ACGIH TLV:
Ingred Name:CALCIUM CARBONATE (MARBLE) (LIMESTONE)
Ingred Name:POLYVINYL ACETATE ACRYLIC RESIN
OSHA PEL:N/K FP-N
ACGIH TLV:N/K FP-N
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
Other REC Limits:0.1 MG CUM
OSHA PEL:SEE TABLE Z3
Ingred Name:TITANIUM DIOXIDE
Ingred Name:ETHYLENE GLYCOL (SARA III)
Fraction by Wt: 5%
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:KAOLIN
Fraction by Wt: < 5%
Ingred Name:ALUMINUM SILICATE
Fraction by Wt: < 5%
OSHA PEL:
ACGIH TLV:
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE SIGN & SYMPTOMS OF OVEREXPOSURE.
Explanation of Carcinogenicity:N/A FPN
Effects of Overexposure:ACUTE BREATHING:IRRITATION OF THE RESPIRATORY
TRACT;HEADACHE,DIZZINESS.SKIN OR EYE CONTACT;PRIMARY
IRRITATION.CHRONIC:PROLONGED & REPEATED BREATHING OF SPRAY MIST
&/OR SANDING DUST OVER A PERIOD OF YE ARS MAY CAUSE DUST DISEASE OF
THE LUNGS.
Medical Cond Aggravated by Exposure:NONE WHEN USED IN ACCORDANCE W/SAFE
HANDLING & USE INFORMATION.
* First Aid Measures *
First Aid:INHAL:IF BREATHED.REMOVE TO FRESH AIR.EYES;FLUSH IMMEDIATELY
VOMITING,CONSULT PHYSICIAN IMMEDIATELY.TREAT SYMPTOMATICALLY.
* Fire Fighting Measures *
Flash Point:NONE(MFR)
Extinguishing Media:USE CO*2,DRY CHEMICAL,FOAM OR OTHER NAT FIRE
PROTECT ASSOCIATION APPROVED METHOD FOR TREATING A CLASS B FIRE.
Fire Fighting Procedures:USE FULL PROT EQUIP INCLUDING SCBA H*2O SPRAY
MAY BE INEFFECTIVE.H*2O USED FOG NOZZLES PREF.H*2O SHOULD BE USED
TO COOL CLOSED CONTR & PREVENT PRES BUILD-UP.
Unusual Fire/Explosion Hazard:CLOSED CONTR EXPOSE TO EXTREME HEAT MAY
EXPLODE IN EMERGENCY;OVEREXPOS TO DECOMP PROD CAUSE HEALTH
HAZ.SYMPTOM NOT IMMED APPARENT.OBTAIN MEDICAL ATTENTION.
* Accidental Release Measures *
Spill Release Procedures:WASH W/ H*2O.CONTAIN SPILLED MATRL & REMOVE W/
INERT ABSORBENT.STORE IN CLOSED CONTAINERS UNTIL PROPERLY DISPOSED
OF.
Neutralizing Agent:N/K
*Handling and Storage *
FREEZING.KEEP CONTAINER CLOSED WHEN NOT IN USE.DO NOT REUSE EMPTY
CONTAINERS.KEEP OUT OF REACH OF CHILDREN.
Other Precautions:
* Physical/Chemical Properties *
Melt/Freeze Pt:M.P/F.P Text:
Decomp Temp:Decomp Text:
Vapor Pres:
Vapor Density:LIGHT> AIR
Spec Gravity:
pH:
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:
Appearance and Odor:
Corrosion Rate:
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:
Hazardous Decomposition Products:HAZ FUMES MAY CONTAIN CARBON
MONOXIDE,CARBON DIOXIDE,OXIDES OF NITROGEN & OXIDES OF METALS
LISTED IN INGRED SECTION.
Conditions to Avoid Polymerization:
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/ LOCAL,STATE AND
FEDERAL REGS.INCINERATE ONLY IN APPROVED FACILITY.DO NOT INCINERATE
CLOSED CONTAINERS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:TOXIC DUST RESPIRATOR OR AIRLINE MASK SHOULD BE
USED IF MATERIAL IS RELEASED TO ATMOSPHERE.
Ventilation:AS NECESSARY TO REMOVE DUST. NOT NECESSARY IF MATERIAL IS
CONTAINED IN VIALS. RECOMMEND USE OF HEPA FILTER.
Other Protective Equipment:PROTECTIVE OUTER CLOTHING, PREFERRABLY MADE
OF DISPOSABLE MATERIAL, IS RECOMMENDED.
Work Hygienic Practices:MATERIAL SHOULD BE HANDLED IN A LAB HOOD
WHENEVER POSSIBLE. HOOD SHOULD HAVE AN ABSOLUTE FILTER.
Supplemental Safety and Health
* Product Identification *
Product ID:L-ASPARAGINASE /ELSPAR/
* Composition/Information on Ingredients *
Ingred Name:L-ASPARAGINASE
Fraction by Wt: 6%
Ingred Name:MANNITOL
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:COMPOUND HAS BEEN SHOWN TO CAUSE BIRTH
DEFECTS IN LAB ANIMALS WHEN GIVEN INTRAVENOUSLY AT DOSES IN
THEAPEUTIC RANGE. NOT CONSIDERED A POTENTIAL OCCUPATIONAL HAZARD AS
THE COMPLEX NATURE OF THE COMPOUN D'S STRUCTURE WOULD INHIBIT
ABSORPTION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES AND SKIN: IRRITATION. INGESTION: NOT
CONSIDERED A POTENTIAL ROUTE OF SYSTEMIC EXPOSURE. INHALATION:
IRRITATION TO UPPER RESPIRATORY TRACT. SOME EXPOSED WORKERS HAVE
EXPERIENCED CHILLS, FEVER, SLI GHT RESPIRATORY DISTRESS AND
DIARRHEA.
* First Aid Measures *
MINUTES. GET MEDICAL ATTENTION. SKIN: WASH IMMEDIATELY WITH SOAP
AND WATER. INHALATION: REMOVE FROM EXPOSURE. GET MEDICAL ATTENTION
IF SYMPTOM S APPEAR. INGESTION: DO NOT INDUCE VOMITING. DILUTE WITH
WATER AND GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER SPRAY OR ALL PURPOSE DRY CHEMICAL TO FIGHT
FIRES.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS AND
PROTECT CLOTHING IF COMPOUND IS RELEASED DURING FIRE OR IS BURNING.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:VACUUM OR SWEEP UP SPILLED MATERIAL. AVOID
CREATION OF AIRBORNE DUST. WEAR SUITABLE PROTECTIVE EQUIPMENT.
*Handling and Storage *
Handling and Storage Precautions:MATL IS AN ENZYMATIC PROTEIN. SHOULD
Other Precautions:NONE
* Physical/Chemical Properties *
HCC:T6
Solubility in Water:COMPLETE
Appearance and Odor:WHITE LYOPHYLLIZED PLUG OR POWDER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
Stability Condition to Avoid:OPEN CONTAINERS -AT RISK OF BACTERIAL
CONTAMINATION
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL
REGULATIONS. INCINERATION IS THE PREFERRED METHOD.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE SELF CONTAINED/AIR-SUPPLIED BREATHING
APPARATUS W/FULL FACEPIECE FOR NON-ROUTINE/EMERGENCY USE >THE TLV.
Ventilation:GENERAL/LOCAL EXHAUST (EXPLOSION-PROOF) TO MEET TLV
VELOCITY.
Other Protective Equipment:NEOPRENE APRON, EYEWASH FOUNTAIN, WASHING
FACILITIES, DRENCHING SAFETY SHOWERS
Supplemental Safety and Health
PER ACGIH/OSHA. INCOMPATIBILITIES CONT'D: POTASSIUM TERT-BUTOX
IDE/HYPOCHLOROUS
ACID/ISOCYANATES/NITROFORM/PHOSGENE/NITROFORM/PHOSGENE/OLEUM/PERCHL
ORIC ACID/STRONG OXIDIZING AGENTS.
* Product Identification *
Kit Part:Y
Preparer's Name:ROBERT DAVIS
* Composition/Information on Ingredients *
Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL
CARBINOL
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MILD IRRITANT TO THE
NOSE/THROAT. EYES: LOCAL IRRITANT, BURNING SENSATIONS W/POSSIBLE
DAMAGE. SKIN: BURNING SENSATION W/POSSIBLE IRRITATION. INGESTION:
BURNING SENSATION OF THE DIGESTIVE T RACT/CNS DEPRESSION. POISONOUS
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, NARCOSIS, NAUSEA, HEADACHE, BURNING
SENSATION, STINGING, DEFATTING, VOMITING, BLEEDING
* First Aid Measures *
INHALATION: REMOVE TO FRESH AIR. RESTORE/SUPPORT BREATHING AS
NEEDED, GIVE OXYGEN. INGESTION: GIVE WATER TO DRINK TO DILUTE. IF
CONSCIOUS & ALE RT & AMOUNT INGESTED IS LARGE, INDUCE VOMITING.
OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:USE WATERSPRAY TO COOL FIRE EXPOSED
CONTAINERS/A FINE WATER MIST TO SMOTHER THE FIRE/DISPERSE VAPORS. A
WATER STREAM MAY NOT BE EFFECTIVE. WEAR SCBA.
Unusual Fire/Explosion Hazard:A MODERATE EXPLOSION HAZARD EXISTS WHEN
THIS MATERIAL IS EXPOSED TO HEAT/FLAMES.
* Accidental Release Measures *
Spill Release Procedures:SMALL: ABSORB W/PAPER TOWELS, EVAPORATE IN
EXHAUST HOOD, BURN DRY PAPER. LARGE: CONTAIN; COLLECT LIQUID/ABSORB
W/VERMICULITE. PLACE INTO COVERED CONTAINER, USE NON-SPARKING TOOLS
FOR DISPOSAL. USE WAT ER SPRAY TO DILUTE/FLUSH AREA.
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY AREA AWAY FROM EXCESSIVE
IN ORIGINAL SEALED CONTAINERS.
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR TO COLORLESS LIQUID W/ALCOHOL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACETADEHYDE/CHLORINE/ETHYLENE OXIDE/HYDROGEN-PALLADIUM
COMBINATION/HYDROGEN PEROXIDE-SULFURIC ACID COMBINATION. (SUPP)
Stability Condition to Avoid:MOISTURE, EXCESSIVE HEAT, FLAMES, LIGHT
Hazardous Decomposition Products:CO, ALUMINUM
* Disposal Considerations *
Waste Disposal Methods:BURN WASTE LIQUID IN AN APPROVED
INCINERATOR/DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL
REGULATIONS. ABSORBED LIQUID CAN BE LANDFILLED. FLAMMABLE LIQUID
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
NECESSARY.
Ventilation:LOCAL EXHAUST VENTILATION MAY BE NECESSARY TO CONTROL ANY
AIR CONTAMINANTS TO WITHIN THEIR TLVS DURING USE OF PRODUCT.
Other Protective Equipment:WEAR APPROPIATE PROTECTIVE CLOTHING TO
PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. REMOVE
CONTAMINATED CLOTHING AND WASH BEFORE RESUE.
Supplemental Safety and Health
HAZARD CLASS 6.1.
* Product Identification *
* Composition/Information on Ingredients *
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE-MAY CAUSE IRRITATION. SKIN-MAY
CAUSE IRRITATION. INGESTION-CAUSES GASTROINTESTINAL IRRITATION, MAY
CAUSE CENTRAL NERVOUS SYSTEM. INHALATION-MAY CAUSE CENTRAL NERVOUS
SYSTEM EFFECTS, CAUSES RESPIRA TORY TRACT IRRITATION. CHRONIC:
PROLONGED OR REPEATED SKIN CONTACT MAY CAUSE DERMATITIS.
Explanation of Carcinogenicity:POSSIBLE CANCER HAZARD BASED ON TEST
WITH LABORATORY ANIMALS.
Effects of Overexposure:EYE-POSSIBLE EYE BURNS. SKIN-POSSIBLE BURNS.
INGESTION-NAUSEA, VOMITING, DIARRHEA, EXCITEMENT, HEADACHE,
DIZZINESS, DROWSINESS, COLLAPSE, UNCONSCIOUSNESS, COMA & DEATH DUE
TO RESPIRATORY FAILURE. INHA LATION-MAY CAUSE HEADACHE, DIZZINESS,
UNCONSCIOUS & COMA.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MEDICAL AID IMMEDIATELY. SKIN-GET MEDICAL AID. IMMEDIATELY FLUSH
& ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GETMEDICAL AID
IMMEDIATELY. INHALATION-GET MEDICAL AID IMMEDIATELY. REMOVE FROM
EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, PERFORM CPR OR
GIVE OXYGEN.
* Fire Fighting Measures *
Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL,
CARBON DIOXIDE OR CHEMICAL FOAM. USE WATER SPRAY TO COOL EXPOSED
CONTNRS
Fire Fighting Procedures:AS IN ANY FIRE, WEAR A SELF-CONTAINED
BREATHING APPARATUS IN PRESSURE DEMAND, MSHA/NIOSH & FULL
PROTECTIVE GEAR.
Unusual Fire/Explosion Hazard:VAPORS MIXED WITH AIR IN PROPER PORTION
WILL PROPAGATE A FLMAE.
* Accidental Release Measures *
Spill Release Procedures:ABSORB SPILL WITH INERT MATERIAL, (E.G. DRY
SAND OR EARTH) THEN PLACE INTO A CHEMICAL WASTE CONTAINER. REMOVE
ALL SOURCES OF IGNITION. USE A SPARK-PROOF TOOL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAMES.
STORE IN A TIGHTLY CLOSED CONTAINER. KEEP FROM CONTACT WITH
OXIDIZING MATERIALS.
Other Precautions:STORE IN COOL, DRY WELL-VENTILATED AREA AWAY FROM
INCOMPATIBLE SUBSTANCES. USE WITH ADEQUATE VENTILATION. LOOSEN
CLOSURE CAUTIOUSLY BEFORE OPENING. DO NOT GET ON SKIN AND CLOTHING.
KEEP CONTAINER TIGH TLY CLOSED. DO NOT INGEST OR INHALE.
* Physical/Chemical Properties *
HCC:T4
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:N/AV
Vapor Density:2.9
pH:N/AV
Viscosity:NP
Evaporation Rate & Reference:N/AV
Solubility in Water:MODERATELY
Appearance and Odor:LIQUID, COLORLESS, ETHEREAL ODOR.
Percent Volatiles by Volume:NP
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDANTS, NITROGEN TETROXIDE, LIQUID OXYGEN, POTASSIUM, SODIUM,
LITHIUM, POTASSIUM HYDROXIDE, FINE MAGNESIUM, ET.
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, IGNITION SOURCES,
EXCESSIVE HEAT, STRONG OXIDANTS.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CARBON
MONOXIDE, CARBON DIOXIDE.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. THIS MATERIAL IS BANNED FROM LAND
DISPOSAL ACCORDING TO RCRA.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT REQUIRED
Ventilation:VENTILATION PROVIDES COMFORT TO PERSONNEL.
Other Protective Equipment:RUBBER APRON
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POTASSIUM HYDROXIDE (SARA III)
OSHA PEL:C, 2 MG/M3
* Hazards Identification *
Effects of Overexposure:IRRITATION & POSSIBLE CAUSTIC BURNS OF CONTACT
AREA/SKIN RASHED.
* First Aid Measures *
First Aid:EYES: WASH W/5% BORIC ACID SOLUTION. CALL DOCTOR. SKIN: FLOOD
WITH WATER THEN WASH WITH VINEGAR. INGESTION: GIVE VINEGAR OR JUICE
OF LEMON, GRAPEFRUIT OR ORANGE COPIOUSLY. FOLLOW WITH OLIVE OIL.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CO2 OR DRY CHEMICAL.
Fire Fighting Procedures:NONE
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:RINSE AREA W/MILD ACETIC ACID SOLUTION
(VINEGAR) TO NEUTRALIZE THEN FLUSH THOROUGHLYITH WATER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. AVOID
GENTLY WHEN INSTALLING CELL INSTRUMENT.
Other Precautions:DON'T PUNCTURE CELL MEMBRANE AS POTASSIUM HYDROXIDE
ELECTROLYTE COULD BE RELEASED.
* Physical/Chemical Properties *
Solubility in Water:YES
Appearance and Odor:COLORLESS LIQUID W/CONSISTENCY MORE THAN WATER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS WITH SOME METALS AND ORGANIC MATERIALS.
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:DILUTE W/WATER PRIOR TO INTRODUCTION INTO WASTE
SYSTEM. CONSULT LOCAL AUTHORITIES REGARDING REGULATIONS FOR CAUSTIC
SOLUTIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:The following respirators and maximum use
chemical cartridge respirator with organic vapor cartridge(s). Any
air-purifying respirator with a full facepiece and an organic vapor
canister. Any powered, air-purifying respirator with organic vapor
cartridge(s). Any supplied-air respirator. Any self-contained
breathing apparatus with a full facepiece. Escape - Any
air-purifying respirator with a full facepiece and an organic vapor
canister. Any appropriate escape-type, self-contained breathing
apparatus. For Unknown Concentrations or Immediately Dangerous to
Life or Health - Any supplied-air respirator with full facepiece
and operated in a pressure-demand or other positive-pressure mode
in combination with a separate escape supply. Any self-contained
breathing apparatus with a full facepiece.
Ventilation:Ventilation equipment should be explosion-resistant if
explosive concentrations of material are present. Provide local
exhaust ventilation system. Ensure compliance with applicable
exposure limits.
Provide an emergency eye wash fountain and quick drench shower in
the immediate work area.
Other Protective Equipment:Wear appropriate chemical resistant
clothing.
Supplemental Safety and Health
* Product Identification *
Product ID:ETHYL BENZENE
Kit Part:* Responsible Party *
CAGE:Company Name:MATHESON TRI-GAS, INC.
CAGE:
* Composition/Information on Ingredients *
Ingred Name:ETHYL BENZENE
* Hazards Identification *
Reports of Carcinogenicity:NTP:No IARC:Yes OSHA:No
Health Hazards Acute and Chronic:INHALATION: SHORT TERM EXPOSURE:
irritation, difficulty breathing, headache, symptoms of
drunkenness, coma LONG TERM EXPOSURE: drowsiness, liver damage SKIN
CONTACT: SHORT TERM EXPOSURE: irritation (possibly severe),
absorption may occur, symptoms of drunkenness LONG TERM EXPOSURE:
blisters, rash EYE CONTACT: SHORT TERM EXPOSURE: irritation,
tearing, eye damage LONG TERM EXPOSURE: same as effects reported in
short term exposure INGESTION: SHORT TERM EXPOSURE: nausea,
vomiting, stomach pain LONG TERM EXPOSURE: no information on
significant adverse effects
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid: INHALATION: If adverse effects occur, remove to
uncontaminated area. Give artificial respiration if not breathing.
If breathing is difficult, oxygen should be administered by
qualified personnel. Get immediate medical attention. SKIN CONTACT:
removing contaminated clothing and shoes. Get immediate medical
attention. Thoroughly clean and dry contaminated clothing and shoes
before reuse. Destroy contaminated shoes. EYE CONTACT: Flush eyes
medical attention. INGESTION: Contact local poison control center
or physician immediately. Never make an unconscious person vomit or
drink fluids. When vomiting occurs, keep head lower than hips to
help prevent aspiration. If person is unconscious, turn head to
side. Get medical attention immediately. NOTE TO PHYSICIAN: For
inhalation, consider oxygen. For ingestion, consider gastric
lavage and activated charcoal slurry.
* Fire Fighting Measures *
Lower Limits:0.8%
Upper Limits:6.7%
Extinguishing Media:regular dry chemical, carbon dioxide, water,
regular foam Large fires: Use regular foam or flood with fine water
spray.
Fire Fighting Procedures:Move container from fire area if it can be
done without risk. Cool containers with water spray until well
after the fire is out. Stay away from the ends of tanks. For fires
in cargo or storage area: Cool containers with water from unmanned
hose holder or monitor nozzles until well after fire is out. If
this is impossible then take the following precautions: Keep
unnecessary people away, isolate hazard area and deny entry. Let
the fire burn. Withdraw immediately in case of rising sound from
venting safety device or any discoloration of tanks due to fire.
(1/2 mile). Water may be ineffective.
Unusual Fire/Explosion Hazard:Severe fire hazard. Vapor/air mixtures
are explosive above flash point. The vapor is heavier than air.
Vapors or gases may ignite at distant ignition sources and flash
back. Electrostatic discharges may be generated by flow or
agitation resulting in ignition or explosion.
* Accidental Release Measures *
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:Store and handle in accordance with
all current regulations and standards. Protect from physical
damage. Store outside or in a detached building. Store with
incompatible substances.
Other Precautions:
* Physical/Chemical Properties *
pH:Not available
Evaporation Rate & Reference:<1 (butyl acetate=1)
Appearance and Odor:PHYSICAL STATE:liquid COLOR:colorless ODOR:aromatic
odor
Corrosion Rate:
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:Stable at normal temperatures
and pressure.
Stability Condition to Avoid:Avoid heat, flames, sparks and other
sources of ignition. Containers may rupture or explode if exposed
to heat. Keep out of water supplies and sewers.
Hazardous Decomposition Products:Thermal decomposition products: oxides
of carbon Thermal decomposition products: oxides of carbon
Conditions to Avoid Polymerization:Will not polymerize.
* Toxicological Information*
CARCINOGEN STATUS: IARC: Human Inadequate Evidence, Animal
Sufficient Evidence, Group 2B LOCAL EFFECTS: Irritant: inhalation,
skin, eye ACUTE TOXICITY LEVEL: Moderately Toxic: ingestion
Slightly Toxic: dermal absorption TARGET ORGANS: central nervous
system MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: kidney disorders,
liver disorders, respiratory disorders, skin disorders and
allergies TUMORIGENIC DATA: Available. MUTAGENIC DATA: Available.
REPRODUCTIVE EFFECTS DATA: Available. ADDITIONAL DATA: May cross
the placenta.
* Ecological Information *
water solubility) HENRY'S LAW CONSTANT: 6.6 E -3 atm-m3/mol
m/s wind) ENVIRONMENTAL SUMMARY: Relatively non-persistent in the
environment. Not expected to leach through the soil or the
sediment. Accumulates very little in the bodies of living
organisms. Highly volatile from water.
* Disposal Considerations *
Waste Disposal Methods:Dispose in accordance with all applicable
* MSDS Transport Information *
GROUP: II LABELING REQUIREMENTS: Flammable liquid
* Regulatory Information *
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY NEEDED. FOR OIL TYPE MIST, USE
NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:LOC EXHST:FOLLOW ACGIH INDUSTRIAL VENT RECOM. MECH
(GEN):RECOM. PROVIDE VENT SUITABLE FOR BLDG STRUCTURE & WORK
(SUPDAT)
Other Protective Equipment:CLEAN CLOTHES. WHERE SPLASH CAN OCCUR, USE
APRON OR CHEMICAL SUIT.
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING.
Supplemental Safety and Health
EXPLO HAZ: DRUM (EVEN EMPTY) BECAUSE PROD CAN IGNITE EXPLOSIVELY.
CARCIN. SPILL PROC: RECOMMENDED CONTROL MEASURES. PERSONS NOT
WEARING PROT EQUIP SHOULD BE EXCLUDED FROM AREA OF SPILL DURING
CLEANUP. VENT: AREA. SPECIAL:NOT REQD UNDER NORM CNDTNS OF USE.
* Product Identification *
Product ID:MICROFINISH NO ODS
* Composition/Information on Ingredients *
Ingred Name:PARAFFIN WAXES AND HYDROCARBON WAXES, CHLORINATED;
(CHLORINATED PARAFFIN)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION, REDNESS. NO OTHER
EFFECTS EXPECTED UNDER NORMAL USE. SPECIFIC TOXICOLOGY STUDIES HAVE
NOT BEEN CONDUCTED ON THIS PRODUCT. THIS HAZARD EVALUATION IS BASED
ON INFORMATION FROM SIMILAR PRODUCTS, INGREDIENTS AND PROFESSIONAL
EXPERIENCE.
Explanation of Carcinogenicity:CHLORINATED PARAFFIN: IARC MONOGRAPHS ON
2B. (SUPDAT)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INGEST: CALL MD IMMEDIATELY . INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) . SKIN:
FLUSH W/COPIOUS AMOUNTS OF WATER. CALL MD . EYES: FLUSH WITH LARGE
IRRITATION PERSISTS.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . TREAT AS AN OIL FIRE. WATER MAY BE USED TO KEEP
FIRE-EXPOSED CONTAINERS COOL UNTIL FIRE IS OUT.
Unusual Fire/Explosion Hazard:COMBUST CAN PRDCE ACID GASES (HYDROGEN
CHLORIDE). EXPOSING DRUMS TO INTENSE HEAT COULD CAUSE DRUMS TO
RUPTURE. NEVER USE WELDING/CUTTING TORCH ON/NEAR (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:CLEAN UP SPILLS PROMPTLY. SURFACES CAN BE
SLIPPERY. TREAT AS OIL SPILL. FOR SM SPILLS, ABSORB ON INERT MATL
(CLAY, SAND, DIRT, ETC). FOR LG SPILLS CONTAIN W/ABOSRB MATL &
CONTACT DISP COMPANY. ALWAYS PACKAGE IN DOT APPRVD CNTNR. OBSERVE
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
PREFERRED. DO NOT STORE NEAR FOOD OR FEED. IF STORED ABOVE
RECOMMENDED TEMP, CAREFULLY VENT POSSIBLE VAPS IN OPEN AREA.
Other Precautions:REPAIR & MAINTENANCE OF CONTAMINATED EQUIPMENT: CLEAN
THOROUGHLY AS APPROPRIATE TO THE SPECIFIC EQUIPMENT. OBSERVE
RECOMMENDED CONTROL MEASURES.
* Physical/Chemical Properties *
Evaporation Rate & Reference:SLOWER THAN WATER
Solubility in Water:< 0.2%
Appearance and Odor:STRAW COLOR, MEDIUM VISCOSITY; BLAND ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AND REDUCING AGENTS, STRONG ALKALI.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:COMBUSTION CAN PRODUCE OXIDES OF
CARBON, HYDROGEN CHLORIDE, INCOMPLETELY BURNED HYDROCARBON
PRODUCTS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . TRANSPORT IN DOT APPROVED CONTAINERS
TO AN EPA APPROVED TREATMENT, STORAGE AND DISPOSAL (TSD) FACILITY.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR IF
VENTILATION IS INADEQUATE.
Ventilation:LOCAL AND MECHANICAL EXHAUST ACCEPTABLE.
Other Protective Equipment:COVERALLS OR APRON TO MINIMIZE CONTACT.
Work Hygienic Practices:AVOID SKIN AND EYE CONTACT. USE STANDARD GOOD
HOUSEKEEPING PRACTICES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Kit Part:Y
Preparer's Name:PAT FRASER
* Composition/Information on Ingredients *
Ingred Name:NON HAZARDOUS INGREDIENTS
Fraction by Wt: BALANCE
Ingred Name:EPOXY RESIN; (BISPHENOL-A EPOXY)
Ingred Name:NOVALAC EPOXY RESIN; (NOVOLAC EPOXY RESINS)
Ingred Name:PROPANE, 2,2-BIS(P-(2,3-EPOXYPROPOXY) PHENYL)-; (BISPHENOL
A DIGLYCIDYL ETHER)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:POSSIBLE REDNESS OR MILD TRANSIENT
IRRITATION OF SKIN UPON PROLONGED, REPEATED CONTACT.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:REDNESS OR MILD TRANSIENT IRRITATION IN
SENSITIVE INDIVIDUALS.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
EYELIDS APART-GET MD. SKIN:WASH WITH SOAP & WATER. INHAL:MOVE TO
FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF RESP) . INGEST:CALL MD
IM MEDIATELY .
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:USE WATER FOG, DRY CHEMICAL, FOAM, CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT (FP N0.
Unusual Fire/Explosion Hazard:NONE KNOWN.
* Accidental Release Measures *
Spill Release Procedures:WHEN POSSIBLE MIX COMPONENTS A & B & ALLOW TO
CURE TO AN INERT, HARMLESS SOLID; OTHERWISE ABSORB SPILL WITH INERT
ABOSRBENT MATERIAL; SWEEP OR SCOOP UP. WASH AREA WITH DETERGENT AND
WATER. PREVENT WAS HINGS FROM ENTERING WATERWAYS.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE AT ROOM TEMPERATURE.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
Vapor Density:>1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:DARK GREY PASTE, CHARACTERISTIC EPOXY RESIN ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ACIDS, BASES, AMINES & MERCAPTANS.
Stability Condition to Avoid:EXCESSIVE HEAT.
Hazardous Decomposition Products:PYROLYSIS YIELDS CO, CO*2, AND
INCOMPLETELY BURNED HYDROCARBONS.
Conditions to Avoid Polymerization:PREMATURE REACTION W/ACIDS, AMINES,
MERCAPTANS.
* Disposal Considerations *
Waste Disposal Methods:BURY CURED PRODUCT IN POSTED LANDFILL. FOR
UNCURED PRODUCT, USE CONTROLLED INCINERATION OR BURY IN A POSTED
LANDFILL IN ACCORDANCE TO LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS WHEN LARGE NUMBERS OF CELLS ARE INVOLVED IN A FIRE.
Ventilation:SUBSEQUENT TO A FIRE PROVIDE AS MUCH VENTILATION AS
POSSIBLE.
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
RECOMMENDED WHEN HANDLING LEAKERS.
* Product Identification *
Product ID:ZINC AIR BATTERIES
* Composition/Information on Ingredients *
OSHA PEL:C 2 MG/M3
ACGIH TLV:C 2 MG/M3
Ingred Name:ING 1:APPEARANCE AND ODOR:CLEAR LIQUID.
Fraction by Wt: 1.6-2.5%
OSHA PEL:5 MG MN/M3 CEILING
ACGIH TLV:5 MG MN/M3
5)
Ingred Name:ING 4:APPEARANCE AND ODOR:GREY POWDER.
Fraction by Wt: 0.6-1.3%
OSHA PEL:C, 0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ING 6:SOL IN H*2O;0%. APPEARANCE AND ODOR:AMALGAM WITH ZN.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE/CHRONIC:THESE CHEMICALS ARE
CONTAINED IN A SEALED CAN. RISK OF EXPOSURE OCCURS ONLY IF THE
BATTERY IS MECHANICALLY OR ELECTRICALLY ABUSED. THE MOST LIKELY
RISK IS ACUTE EXPOSURE WHEN A CELL LEAK S. KOH IS CAUSTIC AND SKIN
CONTACT CAN CAUSE BURNS. EYE CONTACT WITH KOH MAY CAUSE PERMANENT
INJURY. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:MERCURY APPEARS ON NAVY LISTING OF
OCCUP CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH
PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS
INFO . SIGNS/SYMPS OF EX POS:SKIN & EYE CONT W/KOH MAY CAUSE CHEM
BURNS. AT ELEVATED TEMP, HG VAP MAY BE GENERATED WHICH SHOULD NOT
BE INHALED.
Medical Cond Aggravated by Exposure:AN ACUTE EXPOSURE WILL NOT
GENERALLY AGGRAVATE ANY MEDICAL CONDITION.
* First Aid Measures *
First Aid:INGESTION:CALL MD IMMEDIATELY . SKIN:FLUSH IMMEDIATELY WITH
MINUTES AND SEE PHYSICIAN AT ONCE. INHALATION:REMOVE TO FRESH AIR.
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:CELLS MAY RELEASE TOXIC MERCURY VAPORS
WHEN THE INTEGRITY OF THE CANS IS BROKEN.
* Accidental Release Measures *
Spill Release Procedures:AVOID SKIN AND EYE CONTACT. DO NOT INHALE
VAPORS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID MECHANICAL OR ELECTRICAL ABUSE.
STORE AT ROOM TEMPERATURE.
Other Precautions:DO NOT ATTEMPT TO RECHARGE. INSTALL CELLS IN ACCORD
W/EQUIP INSTRUCTIONS. DO NOT DISPOSE IN FIRE. REPLACE ALL BATTERIES
IN EQUIP AT SAME TIME. DO NOT MIX BATTERY SYS SUCH AS ALKALINE &
ZINC CARBON IN SOME EQUIP. DO NOT CARRY (SUPP DATA)
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:SEE INGS
Melt/Freeze Pt:M.P/F.P Text:SEE INGS
Vapor Pres:SEE INGS
Spec Gravity:SEE INGS
Solubility in Water:SEE INGREDIENTS
Appearance and Odor:SEE INGREDIENTS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:DO NOT HEAT, DISASSEMBLE, OR RECHARGE.
Hazardous Decomposition Products:WHEN HEATED, CELLS MAY EMIT HAZARDOUS
VAPORS OF HG AND CAUSTIC KOH.
* Disposal Considerations *
Waste Disposal Methods:IN SMALL QUANTITIES, CELLS MAY BE DISPOSED OF
WITH HOUSEHOLD TRASH. OPEN CELLS IN LARGE QUANTITIES SHOULD BE
TREATED AS A HAZARDOUS WASTE. DO NOT INCIN SINCE CELLS MAY EXPLODE
AT EXCESSIVE TEMPS. DISP OSE IN ACCORD WITH APPLIC FED, STATE & LOC
REGS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE AN APPROPRIATE NIOSH APPROVED RESPIRATOR IN
POORLY VENTILATED AREAS.
Ventilation:LOCAL EXHAUST
Other Protective Equipment:APRON OR PROTECTIVE CLOTHING
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS & FACE AFTER USE.
Supplemental Safety and Health
* Product Identification *
CAGE:0VWY3
* Composition/Information on Ingredients *
Ingred Name:PLATINUM
Fraction by Wt: <1%
Ingred Name:INDIUM
OSHA PEL:0.1 MG/CUM
ACGIH TLV:0.1 MG/CUM
Ingred Name:TIN (AS SN)
Fraction by Wt: <1%
OSHA PEL:2.0 MG/CUM
ACGIH TLV:2.0 MG/CUM
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MODERATELY TOXIC.
HEADACHE, VOMITING. SKIN: IRRITATION & BURNS. INGESTION: EXTREMELY
TOXIC.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: PERMANENT DAMAGE TO THE NERVOUS
SYSTEM & DEATH.
* First Aid Measures *
First Aid:EYES/SKIN: FLUSH W/WATER. INGESTION: DON'T INDUCE VOMITING.
INHALATION: REMOVE TO FRESH AIR. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Flash Point Method:SCC
Extinguishing Media:DRY CHEMICAL, SAND OR OTHER APPROVED EXTINGUISHING
MATERIAL FOR METAL FIRES.
Fire Fighting Procedures:PROTECTIVE CLOTHING & POSITIVE PRESSURE, SCBA.
Unusual Fire/Explosion Hazard:METAL POWDERS & METAL DUSTS MAY CAUSE
CATALYTIC OXIDATION OF FLAMMABLE ORGANIC SOLVENT VAPORS.
* Accidental Release Measures *
Spill Release Procedures:SWEEP OR VACUUM UP SPILL. PLACE SPILLED
MATERIAL IN METAL SAFETY CAN.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED & STORE
IN COOL, DRY AREA.
* Physical/Chemical Properties *
Appearance and Odor:NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
HYDROGEN PEROXIDE, METHANOL & FLAMMABLE ORGANIC SOLVENT VAPORS.
Hazardous Decomposition Products:METAL OXIDE FUMES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
FEDERAL REGULATIONS OR SEND TO A REFINERY FOR RECOVERY OF PRECIOUS
METALS.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENT, WEAR A NIOSH/MSHA APPRVD PROPERLY FITTED
ORGANIC VAPOR/PARTICULATE RESP FOR PROT AGAINST MATLS IN INGRED
SECT. WHEN SANDING OR A BRADING THE DRIED FILM, WEAR (ING 8)
Ventilation:LOC EXHST PREFERABLE. GEN EXHST ACCEPTABLE IF EXPOS TO
MATLS IN ING SEC IS MAINTAINED BELOW APPLIC EXPOS LIMITS.(ING 7)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
PH: 8.3-9.8. FIRE FIGHT PROC: CLSD CNTNRS TO PVNT PRESS BUILD-UP
AND POSS AUTOIGNIT OR EXPLO WHEN EXPOSED TO EXTREME HEAT. EFTS OF
OVEREXP: ATTAINABLE IN THE WORKPLACE. OTHER PREC: ABRADING OF THE
DRIED FILM. IF NO SPECIFIC DUSTS ARE LISTED (ING 5)
* Product Identification *
Product ID:LATEX FLAT INTERIOR PROFESSIONAL FINISHES (
* Composition/Information on Ingredients *
Ingred Name:CARBONIC ACID, CALCIUM SALT (1:1); (BASE CALCIUM
Fraction by Wt: 6%
OSHA PEL:SEE INGREDIENT NAME
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Fraction by Wt: 8-9%
Ingred Name:SUPP DATA:IN ING SEC, THE APPLICABLE LIMITS FOR NUISANCE
Ingred Name:ING 5:(TDUST),5 MG/M3(RESP FRACTION).ACUTE SIGNS &
SYMP:REDNESS/ITCHING/BURNING SENS MAY INDICATE EYE/EXCESS SKIN
EXPOS.
Ingred Name:RESP PROT:NIOSH/MSHA APPRVD DUST/MIST RESPIRATOR FOR DUST
WHICH MAY BE GENERATED FROM THIS PRODUCT, UNDERLYING (ING 9)
Ingred Name:ING 8: PAINT, OR THE ABRASIVE.
Ingred Name:CARCINOGENICITY: BE CARCINOGENIC (NTP SIXTH ANNUAL REPORT
Ingred Name:SILICA, CRYSTALLINE - CRISTOBALITE
Fraction by Wt: 3%
OSHA PEL:SEE TABLE Z3
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)
Fraction by Wt: 4%
OSHA PEL:2 MG/M3 RDUST
ACGIH TLV:2 MG/M3 RDUST
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:IRRIT OF EYES, SKIN & UPPER RESP
SYSTEM. IN A CONFINED AREA VAPORS IN HIGH CONC MAY CAUSE HEADACHE,
NAUSEA OR DIZZINESS. CHRONIC: CRYSTALLINE SILICA (QUARTZ,
CRISTOBALITE) IS LISTED BY IARC. LON G TERM EXPOSURE TO HIGH LEVELS
OF SILICA DUST, WHICH CAN OCCUR ONLY WHEN SANDING OR ABRADING THE
DRY (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CRYSTALLINE SILICA (CRISTOBALITE): GROUP
Effects of Overexposure:HLTH HAZ:FILM MAY CAUSE LUNG DMG (SILICOSIS) &
POSSIBLY CANCER. PROLONGED OVEREXP TO SOLVENT INGREDIENTS IN INGRED
SEC MAY CAUSE ADVERSE EFFECTS TO THE LIVER, URINARY, & BLOOD
MG/M3 DEVELOPED LUNG CANCER, HOWEVER, SUCH EXPOSURE LEVELS ARE NOT
(SUPP DATA)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND
QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. EYES: FLUSH
ATTENTION. INGEST: GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFTIVE.IF WATER IS USED, FOG NOZZ ARE
PREFERABLE.WATER MAY BE USED TO COOL (SUPP DATA)
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE (DUE TO
BUILD-UP OF PRESSURE) WHEN EXPOSED TO EXTREME HEAT.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAINERS WITH COMPLETE AND APPROPRIATE
LABELING. DO NOT TAKE INTERNALLY.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. USE ONLY W/ADEQ VENT.
AVOID BRTHG VAP & SPRAY MIST. AVOID CNTCT W/SKIN & EYES. COATING
MAY CNTN MATLS CLASSIFIED AS NUISANCE PARTICULATES WHICH MAY BE
PRESENT AT HAZ LEV ELS ONLY DURING SANDING OR (SUPP DATA)
* Physical/Chemical Properties *
HCC:N1
Vapor Density:HVR/AIR
Spec Gravity:1.1-1.4
pH:SUPDAT
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM THIS PRODUCT IS NOT HAZ AS DEFINED
INCINERATE CLOSED CONTAINER. DISPOSE OF IN ACCORDANCE WITH FEDERAL,
STATE, LOCAL REGULA TIONS REGARDING POLLUTION.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED ORGANIC VAPOR RESPIRATOR AND
LOCAL VENTILATION WHERE EXPOSURE TO VAPORS IS LIKELY. USE NIOSH
APPROVED SUPPLIED-AIR RESPIRATOR IF VAPOR CONCENTRATIONS ARE HIGH
AND ENGINEERING CONTRO LS ARE INADEQUATE.
Ventilation:USE FUME HOOD IN LABORATORY AND GENERAL VENTILATION
ELSEWHERE.
Other Protective Equipment:ANSI APPROVED EYE WASH AND DELUGE SHOWER .
WEAR FLAME-RESISTANT LAB COAT OR COVERALLS, FLAME-RESISTANT CAP AND
Work Hygienic Practices:USE GOOD HOUSEKEEPING PRACTICES TO AVOID
HAZARDOUS CONDITIONS. WASH THOROUGHLY AFTER HANDLING. WEAR
CONDUCTIVE SAFETY SHOES. THERE SHOULD BE NO CONSUMPTION OF FOOD OR
DRINK IN THE WORKPLACE.
Supplemental Safety and Health
SPILL PROC: SPILL W/COMPATIBLE ABSORBENTS & DISPOSE IN ACCORDANCE
W/LOCAL, STATE & FEDERAL REGULATIONS. DECONTAMINATE SPILL AREA WITH
ACETONE WETTED MOPS & SPONGES. SMALL SPILL: SAME AS FOR LARGE SPIL
L.
* Product Identification *
Product ID:N-BUTYLNITRATOETHYLINITRAMINE (WITH MNA STABILIZER)
* Composition/Information on Ingredients *
Ingred Name:N-BUTYLNITRATOETHYLNITRAMINE
Code:F
Ingred Name:N-METHYL-P-NITROANILINE (MNA) (CRYSTALLINE MATERIAL
DISSOLVED IN N-BUTYLNITROETHYLNITRAMINE TO STABILIZE PRODUCT)
Minumum % Wt:0.
Maxumum % Wt:1.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: NO EVIDENCE OF IRRITANT EFFECTS
FROM NORMAL HANDLING AND USE. HOWEVER, CONTACT WITH UNPROTECTED
SKIN AND EYES MAY CAUSE SLIGHT TO MILD IRRITATION. (BASED ON
CONTACT, AND IS IRRITATING TO THE EYES, SKIN AND RESPIRATORY
SYSTEM. HOWEVER, THE SMALL QUANTITY DISSOLV ED IN BUTYL NENA IS NOT
LIKELY TO PRESENT A SIGNIFICANT HEALTH HAZARD.) CHRONIC: BUTYL NENA
HAS TESTED POSITIVE AS A MUTAGEN. SINCE MOST GENOTOXIC COMPOUNDS
ARE CARCINOGENIC, BUTYL NENA SHOULD BE CONS IDERED A POTENTIAL
CARCINOGEN.
Effects of Overexposure:INHALATION: INHALATION OF VAPORS WILL CAUSE
HEADACHE. NAUSEA AND VOMITING ARE POSSIBLE EFFECTS. EYE CONTACT:
SLIGHT TO MILD IRRITATION. SKIN CONTACT: NO EVIDENCE OF IRRITANT
EFFECTS FROM NORMAL HANDLI NG AND USE. HOWEVER, CONTACT WITH
UNPROTECTED SKIN MAY CAUSE SLIGHT TO MILD IRRITATION. HEADACHE,
NAUSEA, VOMITING ARE POSSIBLE EFFECTS THROUGH SKIN ABSORPTION.
INGESTION: MAY CAUSE HEADACHE, NAUSEA, VOMITING. INGESTION HIGHLY
UNLIKELY UNDER NORMAL INDUSTRIAL USE.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR IMMED. IF BREATHING HAS STOPPED,
GIVE ARTIFICIAL RESPIRATION. SEEK IMMED MED ATTN. EYES: IMMED FLUSH
HOLDING EYE LID(S) OPEN. SEEK IMMED MED ATTN. SKIN: REMOVE
CONTAMINATED CLOTHING. WASH AFFECTED AREA(S) THOROUGHLY W/MILD SOAP
AND WATER. SEEK MED ATTN IF IRRITATION PERSISTS. INGEST: IF VICTIM
IS ALERT AND NOT C ONVULSING, GIVE ONE (1) CUP OF WATER TO DILUTE
INGESTED MATERIAL. DO NOT INDUCE VOMITING. SEEK IMMED MED ATTN.
EMERGENCY MED TREATMENT PROCEDURES: NO SPECIAL PROCEDURES. KEEP
VICTIM CALM AND AT REST. TREAT SYMPTOMATICALLY AND SUPPORTIVELY.
* Fire Fighting Measures *
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL. IF ONLY WATER
IS AVAILABLE, USE IN THE FORM OF A FOG.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . WATER SPRAY SHOULD BE USED TO COOL CONTAINERS.
DECOMPOSITION OF MATERIAL PRODUCES TOXIC GASES AND VAPORS (OXIDES
OF NITROGEN AND CARBON).
Unusual Fire/Explosion Hazard:N-BUTYLNITRATOETHYLNITRAMINE IS LOW FIRE
HAZARD WHEN EXPOSED TO HEAT OR FLAME. THERE IS, HOWEVER, A RISK OF
EXPLOSION IF MATERIAL IS HEATED UNDER CONFINEMENT. MATERIAL HAS
BEEN RECLASSIFIED FROM A CLA SS 1 DIVISION 3 LIQUID EXPLOSIVE TO
CLASS 9 (HAZARDOUS) SUBSTANCE. SEE ATTACHMENT TO MSDS.
* Accidental Release Measures *
Spill Release Procedures:LARGE SPILL: CLEAN UP SPILLS IMMED. USE ALL
REQD PERSONAL PROT EQUIP. AVOID USE OF SPARK-PRODUCING TOOLS. BE
CAREFUL TO AVOID SHOCK, FRICTION & CONTACT W/GRIT. USE COMPATIBLE
ABSORB SOCKS TO PREVENT S PREADING OF SPILL. REMOVE ALL SOURCES OF
IGNIT SUCH AS HEAT, SPARKS & FLAME. USE CONDUCTIVE CNTNRS & GROUND
TO AVOID ELECTROSTATIC DISCHARGE WHEN TRANSFERRING MATL BETWEEN
CNTNRS. TAKE UP (SUPDAT)
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL-VENTILATED
AREA. KEEP AWAY FROM HEAT, SPARKS AND FLAME. KEEP CONTAINERS
Other Precautions:AVOID CONTACT W/EYES, SKIN OR CLTHG. AVOID EXPOS TO
LIGHT, HEAT, MOISTURE & ORGANIC SOLIDS, LIQS & VAPS. USE ONLY
W/ADEQ VENT & AVOID BRTHG VAPS. WASH THOROUGHLY W/SOAP & WATER
AFTER HNDLG. WASH CONTA M CLTHG BEFORE REUSE. ALWAYS USE GOOD
INDUSTRIAL HYGIENE & HOUSEKEEPING PRACTICES.
* Physical/Chemical Properties *
Vapor Density:>1(AIR=1)
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR TO YELLOW OILY LIQUID WITH SLIGHT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT W/STRONG ACIDS AND OXIDIZABLE MATERIALS. FOR OTHER
MATERIALS THAT MAY CONTACT THIS MATERIAL, TEST TO ENSURE
COMPATIBILITY. OTHER MATERIALS MAY INCLUDE EXPLOSIVES, SOLVENTS,
METALS, PLASTICS, ABSORBENTS & OTHER
Stability Condition to Avoid:KEEP AWAY FROM HEAT, SPARKS, FLAME AND
Hazardous Decomposition Products:AMMONIA AND OXIDES OF NITROGEN AND
CARBON.
* Toxicological Information*
Toxicological Information:N/P. OTHER INFO: LOW TOXICITY. HOWEVER, AMES
AND CHO TESTS HAVE SHOWN THAT THIS MATERIAL IS A MUTAGEN AND,
THEREFORE, A POTENTIAL CARCINOGEN. THIS MATERIAL WAS PREVIOUSLY
CLASSIFIED AS A CLASS 1, DIVI SION 3 LIQUID EXPLOSIVE. BASED ON
FLASH POINT TEST AND EXPLOSIVE HAZARD CLASSIFICATION TESTS
WARFARE CENTER, INDIAN HEAD DIVISION, THISMATERIAL HAS BEEN
RECLASSIFIED AS A CLASS 9 (HAZARDOUS) SUBSTANCE. SEE ATTACHMENT TO
MSDS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS . DEVELOP WASTE MINIMIZATION PLAN
EMPLOYING EFFICIENCY IMPROVEMENTS AND RECYCLING. DISPOSE AS
* MSDS Transport Information *
Transport Information:SHIPPING NAME: ENVIRONMENTALLY HAZARDOUS
DOT HAZARD CLASS: 9. DOT SHIPPING LABEL: CLASS 9.
* Regulatory Information *
Federal Regulatory Information:TSCA STATUS:
N-BUTYLNITRATOETHYLNITRAMINE IS NOT LISTED IN THE TSCA CHEMICAL
INVENTORY. RCRA: N/A.
State Regulatory Information:N-BUTYLNITRATOETHYLNITRAMINE IS A
CONTROLLED WASTE IN THE STATE OF MARYLAND.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
NECESSARY.
Ventilation:USE ADEQUATE GENERAL OR LOCAL EXHAUST VENTILATION TO KEEP
AIRBORNE CONCENTRATIONS BELOW THE PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
TARGET ORGANS: NONE. FIRST AID PROC: GIVE OXYGEN. GET MED AID. NO
* Product Identification *
* Composition/Information on Ingredients *
MG/KG
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: DUST MAY CAUSE MECH IRRIT. SKIN:
MAY CAUSE SKIN IRRIT. INGEST: MOD TOXIC TO HUMANS BY INGEST. INHAL:
EFTS MAY BE DELAYED. INHAL OF FUMES MAY CAUSE METAL FUME FEVER
WHICH IS CHARACTERIZED BY FLU-L IKE SYMPS W/METALLIC TASTE, FEVER,
CHILLS, COUGH, WEAK, CHEST PAIN, MUSC PAIN & INCREASED WHITE BLOOD
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: CELL COUNT. ZINC OXIDE DUST IS
CONSIDERED TO BE OF LOW TOX & IS CLASSIFIED AS A NUISANCE
PARTICULATE BY ACGIH. HOWEVER, INHAL OF FUMES OR VERY FINE DUST MAY
CAUSE "ZINC FUME FEVER" WHICH IS CHARACTERIZED BY FLU-LIKE SYMPS
W/METALLIC TASTE, COUGH, WEAK, FATIGUE, MUSC PAIN & NAUS FOLLOWED
BY FEVER & (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
OCCASNLY LIFTING UPPER & LOWER LIDS. GET MED AID. SKIN: GET MED
REMOVING CONT AMD CLTHG & SHOES. INGEST: IF CONSCIOUS& ALERT, GIVE
2-4 CUPFULS OF MILK OR WATER. GET MED AID. INHAL: REMOVE FROM EXPOS
TO FRESH AIR IMMED. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT,
(SUPDAT)
* Fire Fighting Measures *
Extinguishing Media:SUBSTANCE IS NONCOMBUSTIBLE; USE AGENT MOST
APPROPRIATE TO EXTINGUISHING SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . MATERIAL WILL NOT BURN.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS
INDICATED. VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A SUITABLE
DISPOSAL CONTAINER. AVOID GENERATING DUSTY CONDITIONS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A DRY AREA.
Other Precautions:USE WITH ADEQUATE VENTILATION. MINIMIZE DUST
GENERATION AND ACCUMULATION. AVOID BREATHING DUST, VAPOR, MIST OR
GAS. AVOID CONTACT WITH EYES, SKIN AND CLOTHING.
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE OR YELLOWISH WHITE POWDER; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS EXPLOSIVELY W/MAGNESIUM WHEN HEATED. MIXTURES OF CHLORINATED
RUBBER & ZINC OXIDE CAN EXPLODE VIOLENTLY (SUPDAT)
Stability Condition to Avoid:INCOMPATIBLE MATERIALS.
Hazardous Decomposition Products:TOXIC FUMES OF ZINC OXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE AND LOCAL REGULATIONS. NOT LISTED AS A MATERIAL BANNED FROM
LAND DISPOSAL ACCORDING TO RCRA.
| 1 | eyes_protection_mandatory |
Control Measures
*
Proprietary Ind: Y
*
Contractor Summary
*
*
Item Description Information
*
Type/Grade/Class: TY1, CL 2, GR 3
Type of Container: UNKNOWN
*
Ingredients
*
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE:MILD IRRITATION FROM LIQUID CONTACT, VAPORS FROM
HEATED MATERIAL OR DUST FROM CUTTING GRINDING, ETC. SKIN:MILD SKIN
IRRITATION. ALSO POSSIBLE ALLERGIC SKIN REACTION. INHALED:RESPIRATORY
IRRITATION DUE TO VAPORS FROM HEATED MATERIAL OR DUST. INGESTED:G/I
IRRITATION.
Explanation Of Carcinogenicity: MFR LISTED ONLY INFORMATION ABOUT
P-CHLOROPHENYLDIMETHYLUREA (IARC GROUP 3). DOES NOT EXPECT IT TO BE
CARCINOGEN.
Signs And Symptions Of Overexposure: EYE:REDNESS, SWELLING, PAIN, TEARING.
SKIN:REDNESS, SWELLING, BLISTERING, ITCHING.INHALED:RESPIRATORY IRRITATION.
INGESTED:G/I IRRITATION, PAIN, VOMITING, ABDOMINAL TENDERNESS, NAUSEA, BLOOD
IN VOMI TUS & FECES.
Medical Cond Aggravated By Exposure: NO INFORMATION GIVEN BY MFR ON MSDS.
First Aid: IF ANY SYMPTOMS PERSIST OR ARE SEVERE, GERT MEDICAL ATTENTION.
W/LARGE AMOUNTS OF WATER. INHALED:NOT IF SYMPTOMS APPERAR, REMO VE TO FRESH
AIR. INGESTED:DO NOT INDUCEVOMITING. DRINK 2 GLASSES OF WATER. CALL A
PHYSICIAN.
*
Handling and Disposal
*
Neutralizing Agent: NO INFORMATION GIVEN BY MFR ON MSDS.
Waste Disposal Methods: INCINERATE UNCURED WASTE IN AN INDUSTRIAL OR COMMERCIAL
INCINERATOR. DOSPOSE OF COMPLETLY CURED (OR POLYMERIZED) MATERIAL IN A
SANITARY LANDFILL.
RETURN TO ROOM TEMPERATURE BEFORE USE. KEEP OUT OF THE REACH OF CHILDREN.
Other Precautions: USE WATER AS A LUBRICANT ON MACHINING TOOLS TO ELIMINATE
DUST AND IMPROVE MACHINABILITY OF CURED PARTS.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: WATER, CO2, FOAM & DRY CHEMICAL.
Fire Fighting Procedures: WEAR FULL PROTECTIVE CLOTHING (HELMET, SCBA OR
PRESSURE DEMAND BREATHING APPARATUS, BUNKER COAT & PANTS, BANDS AROUND
ARMS, SAIST, FACE MASK, HEAD COVERING.
*
*
Respiratory Protection: AVOID INHALATION OF VAPORS CREATED DURING CURE CYCLE
& DUST CREATED BY CUTTING, GRINDING, ETC. WEAR NIOSH/MSHA APPROVED
RESPIRATOR SELECTED BASED ON AIRBORNE CONCENTRATIONS I/A/W OSHA REGULATIONS.
(MF R SUGGESTS HALF MASK DUST RESPIRATOR.)
Ventilation: USE W/APPROPRIATE LOCAL EXHAUST TO PREVENT BREATHING DUST OR
VAPORS. VENT CURING OVENS OUTDOORS.
Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices: DO NOT EAT, DRINK OR SMOKE WHEN USING THIS PRODUCT.
WASH EXPOSED AREAS THOROUGHLY WITH SOAP & WATER.
Supplemental Safety and Health: MSDS ENTERED INTO THE BY DGSC AT REQUEST OF
GSA.
*
Physical/Chemical Properties
*
HCC: N1
NRC/State LIC No: NONE
M.P/F.P Text: UNKNOWN
Decomp Text: UNKNOWN
Solubility in Water: INSOLUBLE
Appearance and Odor: FILM,OFF-WHITE, NO ODOR.
Corrosion Rate: UNKNOWNN
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: HEAT
Materials To Avoid: NO INFORMATION GIVEN BY MFR ON MSDS.
Hazardous Decomposition Products: CARBON DIOXIDE AND CARBON MONOXIDE
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
Transportation Information
*
Net Unit Weight: UNKNOWN
AF MMAC Code: Z
Multiple KIT Number: 0
Review IND: Y
Type Of Container: UNKNOWN
*
Detail DOT Information
*
DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail IMO Information
*
IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
*
Detail IATA Information
*
IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
Detail AFI Information
*
AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
*
HAZCOM Label
*
Company Name: 3M MINNESOTA MINING AND MFG CO ADHESIVES SEALERS DIV
Street: 3M CTR
Label Required IND: Y
Status Code: C
MFG Label NO: NONE
Origination Code: F
Skin Protection IND: YES
Signal Word: CAUTION
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR APPROPRIATE NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:USE ONLY IN A CHEMICAL FUME HOOD.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. OTHER PROTECTIVE
CLOTHING.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CAFFEINE
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:HARMFUL IF INHALED OR SWALLOWED.
MAY CAUSE IRRITATION. POSSIBLE TERATOGEN. CHRONIC:OVEREXPOSURE MAY
CAUSE REPRODUCTIVE DISORDER(S) BASED ON TESTS WITH LABORATORY
ANIMALS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:INGEST:CALL MD IMMEDIATELY . EYES:FLUSH WITH COPIOUS AMOUNTS
AND SHOES. WASH CONTAMINATED CLOTHINGBEFORE REUSE.
INHALATION:REMOVE TO FRESH AIR. IF NOT BREATHING GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. CALL A
PHYSICIAN.
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH/MSHA APPROVED RESPIRATOR, CHEMICAL
PLACE IN A BAG AND HOLD FOR WASTE DISPOSAL. AVOID RAISING DUST.
VENTILATE AREA AND WASH SP ILL SITE AFTER MATERIAL PICKUP IS
COMPLETE.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP TIGHTLY CLOSED. STORE IN A COOL,
DRY PLACE.
Other Precautions:DO NOT BREATHE DUST. AVOID CONTACT WITH EYES, SKIN
AND CLOTHING. AVOID PROLONGED OR REPEATED EXPOSURE. TOXIC.
* Physical/Chemical Properties *
Appearance and Odor:
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE AND NITROGEN OXIDES.
* Disposal Considerations *
Waste Disposal Methods:DISSOLVE OR MIX THE MATERIAL WITH A COMBUSTIBLE
SOLVENT AND BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL
LAWS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:LOCAL EXHAUST AND MECHANICAL/GENERAL VENTILATION.
Other Protective Equipment:AS NEEDED TO PROTECT SKIN.
Work Hygienic Practices:WASH HANDS FREQUENTLY AND THOROUGHLY DURING
CONTACT WITH MATERIAL AND AT END OF WORKDAY .
Supplemental Safety and Health
* Product Identification *
Product ID:DEX-O-TEX TERRAZZO M GROUT, (SEE SUPP DATA)
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:PROPANE, 2,2-BIS (P-(2,3-EPOXYPROXY)PHENYL) (MODIFIED
DIGLYCIDYL ETHER OF BISPHENOL A)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:MAY CAUSE SKIN AND EYE
IRRITATION. CHRONIC:MAY CAUSE DERMATITIS AND SENSITIZATION.
Effects of Overexposure:NONE SPECIFIED BY MANUFACTURER.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR - GIVE OXYGEN IF NECESSARY.
SKIN:WASH WITH SOAP AND WATER - REMOVE CONTAMINATED CLOTHING.
INGEST:INDUCE VOMITING AND CALL A PHYSICIAN.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:FOAM, CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY
BE TOXIC.
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBENT MATERIAL AND SHOVEL INTO
CLOSEABLE CONTAINERS. FLUSH CONTAMINATED AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY AREA. USE EYE AND
SKIN PROTECTION DURING APPLICATION. KEEP AWAY FROM OPEN FLAMES.
Other Precautions:USE GOOD VENTILATION DURING APPLICATION.
* Physical/Chemical Properties *
Spec Gravity:1.1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:STRAW COLORED, SLIGHTLY CLOUDY, THIXOTROPIC LIQUID
- SLIGHT AROMATIC ODOR.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID HIGH TEMPERATURES - STORE IN COOL,
DRY AREA.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS - CARBON
MONOXIDE, ETC. WHEN HEATED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN SANITARY LANDFILL IN ACCORDANCE
WITH LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: 5 MG/M3 (CN)
ACGIH TLV: 5 MG/M3, S (CN)
------------------------------
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3, C
------------------------------
% Wt: BALANCE
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
AREA.
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ING 1:ACUTE:HIGHLY TOXIC BY INHAL & INGEST. MAY CAUSE
IRRIT TO NOSE & MUC MEMBS. SKIN CONTACT MAY CAUSE REDNESS, PAIN, BURNS,
DERM. EYE CONTACT MAY CAUSE IRRIT, CORROSION, REDNESS, BLURRED VISION, COR
NEAL BURNS. INGEST IN LG QTYS MAY CAUSEIMMEDIATE UNCON, CONVLS & DEATH,
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:LEVELS OF INGEST MAY CAUSE
CORROSION TO GI TRACT. CHRONIC:EXPOS TO LOW LEVELS OVER LONG PERIODS OF TIME
MAY CAUSE LOSS OF APPETITE, HDCH, NAUS, DIZZ, UPPER RESP TRACT IRRIT. PRLNG
SKIN CONT M AY CAUSE DERM & "CYANIDE RASH" CHARACT BY ITCH. PRLNG EYE
CONT MAY CAUSE CONJ & CORROSION OF CORNEA.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INHAL:REMOVE FROM EXPOS AREA IMMED. IF BRTHG HAS STOPPED, GIVE ARTF
RESP. MAINTAIN AIRWAY & ADMIN OXYGEN. GET MED AID AT ONCE. SKIN:REMOVE
BANDAGES. GET MED AID AT ONCE. INGEST:IF VICTIM IS CONSCIOUS, GIVE SYRUP OF
IPECAC & PERFORM GASTRIC (SUPDAT)
*
Handling and Disposal
*
Spill Release Procedures: FOR SMALL SPILLS, TAKE UP W/SAND OR OTHER ABSORBENT
MATERIAL & PLACE IN SUITABLE CONTAINERS (PLASTIC) FOR LATER DISPOSAL. FOR
LARGE SPILLS, DIKE FAR AHEAD FOR LATER DISPOSAL. VENTILATE CLOSED AREAS BE
FORE ENTERING.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF ACCORDING TO FEDERAL, STATE & LOCAL
REGULATIONS.
Handling And Storage Precautions: STORE IN COOL, DRY AREA AWAY FROM
INCOMPATIBLE MATERIALS (ACIDS, OXIDIZERS).
Other Precautions: NONE SPECIFIED BY MANUFACTURER.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: DRY CHEMICAL, WATER SPRAY, REGULAR FOAM.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT (FP N). MOVE FROM FIRE AREA IF POSSIBLE. FIGHT FIRE FROM A
DISTANCE.
Unusual Fire/Explosion Hazard: NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR
FLAME.
*
*
Respiratory Protection: NIOSH/MSHA APPROVED AIR-PURIFYING FULL FACEPIECE
RESPIRATOR W/CHIN-STYLE OR FRONT- OR BACK-MOUNTED CANISTER PROVIDING
PROTECTION AGAINST CYANDIDE.
Ventilation: PROVIDE LOCAL EXHAUST & VENTILATION TO MEET EXPOSURE LIMITS.
Other Protective Equipment: DELUGE SHOWER WHICH MEETS ANSI DESIGN CRITERIA (FP
N). WEAR PROT CLTHG TO PREVENT SKIN CONT. ANSI APPRVD EYE WASH
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: PH:ALKALINE. FIRST AID PROC:LAVAGE. FOLLOWING
ANTIDOTE IS REC, HOWEVER QUALIFED MED PERS SHOULD MAKE DECISION:AMYL NITRATE
*
Physical/Chemical Properties
*
Spec Gravity: 1
PH: SUPDAT
Solubility in Water: SOLUBLE
Appearance and Odor: CLEAR, COLORLESS SOLUTION; FAINT ODOR OF BITTER ALMONDS.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Materials To Avoid: CONTACT W/ACIDS, OXIDIZERS, CHLORATES, NITRATES, NITRITES.
Hazardous Decomposition Products: THERMAL DECOMPOSITION PRODUCTS INCLUDE TOXIC
HYDROGEN CYANIDE GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Assigned IND: Y
Company Name: LABCHEM INC
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:HIGHLY TOXIC BY INHAL & INGEST. MAY CAUSE
IRRIT TO NOSE & MUC MEMBS. SKIN CONTACT MAY CAUSE REDNESS, PAIN, BURNS,
DERM. EYE CONTACT MAY CAUSE IRRIT, CORROSION, REDNESS, BLURRED VISION,
CORNEAL B URNS. INGEST IN LG QTYS MAY CAUSE IMMEDIATE UNCON, CONVLS &
TO GI TRACT. CHRONIC:APPETITE LOSS, HEADACHE, NAUSEA, DIZZINESS , UPPER
RESPIRATORY TRACT IRRITATION. SKIN:DERMATITIS, "CYANIDE RASH" CHARACTERIZED
BY ITCH. EYE:CONJ, CORROSION OF CORNEA.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF OPERATIONS ARE SUCH THAT ATMOSPHERIC LEVELS
OF CONTAMINANTS EXCEED PRESCRIBED LIMITS, PROVIDE ADEQ NIOSH/MSHA
Ventilation:IF OPERATIONS ARE SUCH THAT ATM LEVELS OF CONTAMINANTS
EXCEED PRESCRIBED LIMITS, PROVIDE LOCAL EXHAUST VENTILATION.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
APPEAR/ODOR: PIPE OR TUBING.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:IRON (AS IRON OXIDE FUME)
ACGIH TLV:5 (FE) MG/M3
Ingred Name:MANGANESE (SARA III)
Fraction by Wt: <2%
OSHA PEL:(C) 5 MG/M3 DUST
Ingred Name:CARBON
Fraction by Wt: <0.3%
Ingred Name:PHOSPHOROUS (YELLOW) (SARA III)
Fraction by Wt: <0.1%
OSHA PEL:0.1 MG/M3
ACGIH TLV:0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:SULFUR (AS SULFUR DIOXIDE) (SARA III)
Fraction by Wt: <0.1%
OSHA PEL:2 PPM; 5 PPM STEL
ACGIH TLV:2 PPM; 5 PPM STEL
Ingred Name:SILICON
Fraction by Wt: <1%
Ingred Name:CHROMIUM (VI); (AS SOLUBLE CR SALTS) (SARA III)
OSHA PEL:0.5 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:NICKEL (AS METAL NI) (SARA III)
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: DUST/FUME MAY CAUSE IRRIT TO
EYES/ NOSE/ THROAT; LEAVE A METALLIC TASTE IN MOUTH; RSLT IN METAL
FUME FEVER; OR PRDCE FLU-LIKE SYMP. CHRONIC: CHROMIUM: SKIN
ULCERATION, IRRITATIVE DERMAT, ALLERG IC RXN, ULCERATION OF MUC
MEMB, PERFORATION OF NASAL SEPTUM, BRONCH CARCINOMA,
ADENOCARCINOMA, MUTAGEN. (EFT OF OVEREXP)
Explanation of Carcinogenicity:NICKEL: ANTICIPATED TO BE A CARCINOGEN
(NTP) , GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ: IRON: SIDEROSIS. MANGANESE:
BRONCHITIS, PNEUMONITIS, LACK OF COORDINATION. NICKEL: INFLAMM OF
RESP TRACT, PNEUMOCONIOSIS. SKIN SENSITIZER, CERTAIN NICKEL CMPDS
CAN CAUSE CANCER. PHOSPHORUS: NECROSIS OF THE MANDIBLE. SULFUR:
EDEMAOF THE LUNGS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL: IN THE EVENT OF ACUTE EXPOSURE, REMOVE TO FRESH AIR,
ADMINISTER OXYGEN, AND SEEK MD ASSISTANCE. INGEST: CALL MD
IMMEDIATELY . EYES: IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM
AMOUNTS OF WATER. CALL MD .
* Fire Fighting Measures *
Extinguishing Media:USE METHODS APPLICABLE TO SURROUNDING FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Other Precautions:PLASMA ARC CUTTING OR WELDING CAN GENERATE OZONE.
OVEREXPOS CAN RESULT IN MUCUOUS MEMBRANE IRRITATION, AS WELL AS
PULMONARY CHANGES INCLUDING IRRITATION, CONGESTION AND EDEMA.
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:>7 (H2O=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GRAYISH TO SILVERY ODORLESS SHEET, STRIP, PLATE,
BAR, STRUCTURAL SHAPE,(SUPDATA
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT INCOMPATIBLE WITH MATERIALS.
Stability Condition to Avoid:MAY LIBERATE METAL FUMES, METAL OXIDES, OR
OTHER OXIDES IF EXPOSED TO ELEVATED TEMPERATURES.
* Disposal Considerations *
Waste Disposal Methods:MATL MAY BE RECLAIMED FOR REUSE. ACID PICKLING
OF PROD MAY RSLT IN FORMATION OF HEXAVALENT CHROMIUM WHICH IS A HAZ
SUBSTANCES. DISPOSAL MUST BE I/A/W FEDERAL, STATE, & LOCAL REGS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOR SULFURIC ACID MIST, USE HALF MASK NEGATIVE
PRESSURE WITH DUST AND MIST FILTER.
Ventilation:USE MECHANICAL VENTILATION WITH 3 TO 4 AIR CHANGES PER
HOUR.
Other Protective Equipment:RUBBER APRON AND BOOTS.EYES WASH STATION AND
SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
THIS MSDS IS FOR ACID IN BATTERY.ADDITIONAL HAZARDS ASSOCIATED WITH THE
LEAD CONTAINED IN THE BATTERY PLATES MAY BE PRESENT AT TIME OF
DISPOSAL.
* Product Identification *
Product ID:TITAN AC/DC, SEE "SUPP DATA"
* Composition/Information on Ingredients *
Ingred Name:LEAD (SARA III)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ANTIMONY (SARA III)
Fraction by Wt: >2%
OSHA PEL:0.5 MG/M3
Ingred Name:ARSENIC (SARA III)
Fraction by Wt: <0.2%
OSHA PEL:0.5 MG/M3 (AS)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CALCIUM, METAL
Fraction by Wt: <0.2%
Other REC Limits:NONE ESTABLISHED
Ingred Name:SULFURIC ACID (SARA III)
OSHA PEL:1 MG/M3
Ingred Name:POLYPROPYLENE
Fraction by Wt: 5%
Other REC Limits:NONE ESTABLISHED
OSHA PEL:NONE ESTABLISHED
ACGIH TLV:NONE ESTABLISHED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SEE SIGNS AND SYMPTOMS OF
OVEREXPOSURE.
Effects of Overexposure:CONTACT MAY CAUSE PERMANENT DAMAGE TO
EYES,SEVERE BURNS AND ULCERATION OF SKIN. INHALATION CAUSES UPPER
RESPIRATORY IRRITATION AND POSSIBLE PULMONARY EDEMA. INGESTION
CAUSES SEVERE INJURIES.
Medical Cond Aggravated by Exposure:RESPIRATORY CONDITIONS WILL BE
AGGRAVATED BY BREATHING ACID MISTS.
* First Aid Measures *
First Aid:EYES/SKIN:FLUSH WITH PLENTY OF WATER.SEE DOCTOR
IMMEDIATELY.REMOVE CONTAMINATED CLOTHING AND SHOES.
INHALATION:REMOVE TO FRESH AIR.GIVE OXYGEN/CPR IF NEEDED.SEE
DOCTOR.
* Fire Fighting Measures *
Extinguishing Media:USE CARBON DIOXIDE, FOAM, HALOGEN, DRY CHEMICAL.
Fire Fighting Procedures:IF ON CHARGE, SHUT OFF POWER.
Unusual Fire/Explosion Hazard:NONE STATED
* Accidental Release Measures *
Spill Release Procedures:WEAR APPROPIATE PROTECTIVE EQUIPMENT.DILUTE
CAUTIOUSLY WITH WATER.COVER WITH SODA ASH OR QUICKLIME.SCOOP UP AND
PLACE IN APPROPIATE DISPOSAL CONTAINER.
Neutralizing Agent:SODA ASH (SODIUM CARBONATE) OR QUICKLIME (CALCIUM
OXIDE).
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM IGNITION SOURCES AND
COMBUSTIBLE MATERIALS.AVOID CONTACT WITH ORGANIC MATERIALS.
Other Precautions:KEEP TERMINALS COVERED IN PLASTIC CASE.AVOID SHORTING
BATTERIES.
* Physical/Chemical Properties *
HCC:C1
pH:<7
Appearance and Odor:BATTERY
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE STATED
Stability Condition to Avoid:PROLONGED OVERCHARGE.
Hazardous Decomposition Products:MAY GENERATE ARSINE,STIBINE AND/OR
SULFURIC ACID MIST ON OVERCHARGE.
* Disposal Considerations *
Waste Disposal Methods:RETURN SPENT BATTERY TO SECONDARY LEAD SMELTER.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPRVD RESP PROTECTN FOR PARTICULAR
EXPOSURE OF CONCERN.
Ventilation:SPECIAL-LGE VOLUME AIR MOVER FOR LGE
TANK.MECH-EXPLOSN-PROOF
Other Protective Equipment:APRONS, PROTECTIVE CLOTHING
Supplemental Safety and Health
BOILING POINT & VAPOR PRESSURE ARE GIVEN FOR MINERAL SPIRITS. PRODUCT
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ASPHALT (PETROLEUM)
Ingred Name:NAPHTHA (PETROLEUM SPIRITS OR BENZIN)
Ingred Name:NAPHTA (PETROLEUM SPIRITS OR BENZIN)
Fraction by Wt: 5-7%
* Hazards Identification *
Effects of Overexposure:AVOID INHALATION. AVOID SKIN AND EYE CONTACT.
* First Aid Measures *
First Aid:INHALATION:MOVE TO FRESH AIR. ARTIFICIAL RESPIRATION IF
NECESSARY. SKIN:REMOVE CONTAMINATED CLOTHING, WASH AREA W/WARM
WATER. EYE:WASH W/SALINE. CALL MD.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, FOAM, POWDER, CARBON DIOXIDE.
Unusual Fire/Explosion Hazard:NONE OTHER THAN STANDARD PROCEDURES FOR
FIGHTING BURNING LIQUIDS.
* Accidental Release Measures *
ADEQUATE VENTILATION. ABSORB LIQUID IN SAWDUST OR WITH RAGS.
*Handling and Storage *
Handling and Storage Precautions:NO SMOKING IN STORAGE AREA. KEEP FROM
HEAT AND OPEN FLAMES. DOT CATEGORY:COMBUSTIBLE LIQUID.
Other Precautions:INSURE ADEQUATE VENTILATION DURING USE.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:1.9
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:OPEN FLAMES. EXCESSIVE HEAT.
Hazardous Decomposition Products:(THERMAL ONLY) NITROGEN DIOXIDE,
CARBON MONOXIDE
* Disposal Considerations *
Waste Disposal Methods:MFR SUGGESTS BURYING OR CONTROLLED INCINERATION
IN ACCORDANCE W/LOCAL, STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE SUPPLIED-AIR RESPIRATORY PROTECTION IN
CONFINED OR ENCLOSED SPACES, IF NEEDED.
Ventilation:PROVIDE ADEQUATE VENTILATION TO PREVENT EXCEEDING
RECOMMENDED EXPOSURE LIMIT OR BUILD-UP OF EXPLOSIVE CONC. IN AIR.
Other Protective Equipment:USE CHEMICAL-RESISTANT APRON OR OTHER
IMPERVIOUS CLOTHING,AS NEEDED,TO PROTECT REGULAR CLOTHING OR SKIN
CONTACT.
Work Hygienic Practices:WASH HANDS AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
USE EXPLOSION-PROOF EQUIPMENT.
* Product Identification *
* Composition/Information on Ingredients *
ISOPARAFFINIC HYDROCARBONS.
OSHA PEL:5 MG/M3 (OIL MIST)
ACGIH TLV:5 MG/M3 (OIL MIST)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: PROLONGED OR
REPEATED SKIN CONTACT TENDS TO REMOVE SKIN OILS POSSIBLY LEADING TO
IRRITATION AND DERMATITIS. PRODUCT IS NEITHER A "CORROSIVE" NOR AN
"IRRITANT" BY OSHA CRITERIA. PRODUCT HAS A LOW ORDER OF ACUTE ORAL
AND DERMAL TOXICITY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:HIGH VAPOR CONCENTRATIONS (GREATER THAN
TRACT. MAY CAUSE HEADACHES AND DIZZINESS, ARE ANESTHETIC, AND MAY
HAVE OTHER CNS EFFECTS.
Medical Cond Aggravated by Exposure:SKIN CONTACT MAY AGGRAVATE EXISTING
DERMATITIS.
* First Aid Measures *
First Aid:EYES: FLUSH WITH LARGE AMOUNTS OF WATER. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION. SKIN: REMOVE CONTAMINATED
CLOTHING. WASH SKIN WITH SOAP AND WATER. INHALATION: MOVE TO FRESH
AIR. GET MEDICAL AT TENTION. IF BREATHING IS IRREGULAR OR HAS
STOPPED, GIVE CPR, GIVE OXYGEN IF AVAILABLE. INGESTION: DO NOT
INDUCE VOMITING. GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:1%
Upper Limits:7%
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:IF LEAK OR SPILL HAS IGNITED, USE WATER SPRAY
TO DISPERSE VAPORS AND PROTECT MEN ATTEMPTING TO STOP LEAK.
WATERSPRAY MAY BE USED TO FLUSH SPILLS FROM EXPOSURES.
Unusual Fire/Explosion Hazard:USE SUPPLIED-AIR BREATHING APPARATUS FOR
ENCLOSED OR CONFINED SPACES OR AS OTHERWISE NEEDED.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. RECOVER FREE
PRODUCT. ADD SAND, EARTH, OTHER ABSORBENT TO SPILL AREA. MINIMIZE
SKIN CONTACT. VENTILATE CONFINED SPACES. OPEN WINDOWS AND DOORS.
KEEP PRODUCT OUT OF SEWE RS, WATER COURSES, OR EXTENSIVE LAND
AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE NEAR HEAT, SPARKS, FLAME,
STRONG OXIDANTS. GROUND TRANSFER SYSTEM TO PREVENT FIRE OR
EXPLOSIVE RISK FROM STATIC ELECTRICITY.
Other Precautions:KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT SMOKE
IN STORAGE OR WORK AREA.
* Physical/Chemical Properties *
HCC:F4
Vapor Density: 4.7
Evaporation Rate & Reference:1.5 (BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID. FAINT PETROLEUM ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:WILL NOT REACT VIOLENTLY WITH WATER.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF WASTE IN ACCORDANCE WITH LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
AND NIOSH.
Ventilation:USE LOCAL EXHAUST WHERE TLV IS EXCEEDED. VENTILATE SUMPS
AND PITS WHERE VAPOR MAY COLLECT.
Other Protective Equipment:SAFETY SHOWER AND EYEWASH STATION NEAR WORK
ARE.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
THIS ENTRY MADE FROM TWO MSDS'S SUPPLIED BY MANUFACTURER FOR EACH
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NITROGEN
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Ozone Depleting Chemical:1
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION OF MODERATE CONCENTRATIONS
MAY CAUSE HEADACHE, DROWSINESS, DIZZINESS, EXCITATION, EXCESS
SALIVATION, VOMITING, UNCONSCIOUSNESS, NARCOSIS, CARDIAC
ARRHYTHMIAS. LIQUID CONTACT MAY CAUSE FROST BITE.
Explanation of Carcinogenicity:PRODUCT CONTAINS NO INGREDIENTS
CURRENTLY CLASSIFIED AS CARCINOGENIC BY NTP, IARC OR OSHA.
Effects of Overexposure:HEADACHE, DROWSINESS, DIZZINESS, EXCITATION,
EXCESS SALIVATION, VOMITING, UNCONSCIOUSNESS, SKIN BURNS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. CALL A PHYSICIAN. DO NOT
GIVE EPINEPHRINE OR SIMILAR DRUGS. GIVE ARTIFICIAL RESPIRATION IF
NOT BREATHING. GIVE OXYGEN IF BREATHING IS DIFFICULT. EYES: FLUSH
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:NONFLAMMABLE. ITEM IS A FIRE EXTINGUISHER.
Fire Fighting Procedures:USE PROCEDURES APPROPRIATE FOR SURROUNDING
FIRE. EVACUATE PERSONNEL FROM DANGER AREA. DELUGE CONTAINER WITH
WATER SPRAY. USE SCBA TO PROTECT AGAINST FUMES.
Unusual Fire/Explosion Hazard:CONTAINER MAY RUPTURE DUE TO HEAT OF
FIRE. NO PART OF CONTAINER SHOULD BE SUBJECTED TO A TEMPERATURE
* Accidental Release Measures *
Spill Release Procedures:EVACUATE PERSONNEL FROM DANGER AREA. USE
SELF-CONTAINED BREATHING APPARATUS WHERE NEEDED. VENTILATE AREA
WHERE LEAK OCCURED. TEST AREA FOR SUFFICIENT OXYGEN PRIOR TO
PERMITTING RE-ENTRY OF PERSONNEL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE AND USE WITH ADEQUATE
VENTILATION. STORE CONTAINERS IN A CLEAN, DRY AREA. DO NOT HEAT
Other Precautions:AVOID CONTAINER DAMAGE. NEVER WORK ON A PRESSURIZED
SYSTEM. IF THERE IS A LEAK, CLOSE THE CYLINDER VALVE, BLOW DOWN THE
SYSTEM BY VENTING TO A SAFE PLACE, THEN REPAIR THE LEAK.
* Physical/Chemical Properties *
HCC:G3
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Evaporation Rate & Reference:GAS
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS GAS, SLIGHT ETHERAL ODOR DUE TO
BROMOTRIFLUOROMETHANE
Percent Volatiles by Volume:GAS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
LIQUID CONTACT WITH ALKALI AND ALKALINE EARTH METALS -- POWDERED
ALUMINUM, ZINC, BERYLLIUM, LITHIUM, NEODYMIUM, TITANIUM
Stability Condition to Avoid:STABLE UNDER NORMAL CONDITIONS. AVOID
Hazardous Decomposition Products:HYDROGEN FLUORIDES, HYDROGEN BROMIDES,
FREE BROMINE, CARBONYL HALIDE.
* Disposal Considerations *
Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN
NECESSARY.
Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS
LOW.
Other Protective Equipment:ANSI APPRVD EMER EYE WASH & DELUGE SHOWER .
WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MATLS TO AVOID: AMMONIUM HYDROXIDE, AZIRIDINE, CALCIUM CARBIDE,
ETHANOL, ETHANOL & NITRIC ACID., ETHYLENEIMINE, 1-BROMO-2-PROPYNE,
CHARCOAL, CHLORINE TRIFLUORIDE, ETHYLENENE OXIDE, ETHYLENE
HYDROPEROX IDE, HYDROGEN PEROXIDE, MAGNESIUM ARSENIC/CUPROUS
ACETYLIDE. EFTS OF OVEREXP: & MUC MEMB. THE CNDTN DEVELOPS (ING 2)
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SILVER (I) NITRATE (1:1); (NITRIC ACID, SILVER(1+) SALT
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
NO OTHER SYMPS/PHYSICAL IMPAIRMENT ASSOC W/ARGYRIA. (ING 3)
Ingred Name:ING 2:CHRONIC SKIN CONTACT MAY CAUSE LOCAL ARGYRIA, A
PERMANENT DISCOLORATION OF THE SKIN.
Ingred Name:FIRST AID PROC:TO AN UNCONSCIOUS PERSON. GET MED AID IMMED.
INHAL:GET MED AID IMMED. REMOVE FROM EXPOS TO FRESH (ING 5)
Ingred Name:ING 4:AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. (ING 6)
Ingred Name:ING 5:NOTES TO PHYSICIAN: TREAT SYMPTOMATICALLY AND
SUPPORTIVELY.
Ingred Name:EYE PROT: AND FULL LENGTH FACESHIELD .
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE:CNTCT W/EYES MAY CAUSE SEV
IRRIT, & POSS EYE BURNS. SKIN:CAUSES SEV SKIN IRRIT. CAUSES SKIN
BURNS. INGEST:HARMFUL IF SWALLOWED. MAY CAUSE SEV GI TRACT IRRIT
W/NAUS; VOMIT & POSS BURNS. LETH AL DOSE FOR HUMANS IS 2 GRAMS.
INHAL:CAUSE SEV IRRIT OF UPPER RESP TRACT W/COUGHING, BURNS, BRTHG
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:DFCLTY, & POSS COMA. CHRONIC:MAY CAUSE
METHEMOGLOBINEMIA, WHICH IS CHARACT BY CHOCOLATE-BROWN COLORED
BLOOD, HDCH, WEAK, DIZZ, BRTH SHORTNESS, CYANOSIS, RAPID HEART
RATE, UNCONSCIOUSNESS & PO SS DEATH. CHRONIC INHAL/INGEST MAY CAUSE
"ARGYRIA", WHICH IS CHARACTERIZED BY BLUE-GRAY PIGMENTATION OF THE
SKIN(SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
LIFTING THE UPPER & LOWER LIDS. GET MED AID IMMED. DO NOT ALLOW
VICTIM TO RUB/KEEP EYES CLSD. SKIN: GET MED AID IMMED. IMMED FLUSH
CLTHGS & SHOES. INGEST: DO NOT INDUCE VOMIT. IF VOMIT CONSCIOUS &
ALERT, GIVE 2-4 CUPFULS OF MILK/H*2O. NEVER GIVE ANYTHING BY MOUTH
(ING 4)
* Fire Fighting Measures *
Extinguishing Media:SUBSTANCE IS NONCOMBUSTIBLE; USE AGENT MOST
APPROPRIATE TO EXTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . STRONG OXIDIZER. CONTACT WITH COMBUSTIBLE MATERIALS MAY
CAUSE A FIRE.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
* Accidental Release Measures *
Spill Release Procedures:VACUUM OR SWEEP UP MATERIAL AND PLACE INTO A
SUITABLE DISPOSAL CONTAINER. AVOID GENERATING DUSTY CONDITIONS.
REMOVE ALL SOURCES OF IGNITION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM SOURCES OF IGNITION. DO
NOT STORE NEAR COMBUSTIBLE MATERIALS. STORE IN A TIGHTLY CLOSED
CONTAINER.
Other Precautions:STORE IN A COOL, DRY, WELL-VENTILATED AREA AWAY FROM
INCOMPATIBLE SUBSTANCES. USE W/ADEQUATE VENT. DO NOT GET IN EYES,
ON SKIN, OR ON CLOTHING. KEEP CONTAINER TIGHTLY CLOSED. DO NOT
INGEST/INHALE. DO NOT STORE NEAR COMBUSTIBLE MATERIALS.
* Physical/Chemical Properties *
Evaporation Rate & Reference:NOT AVAILABLE
Solubility in Water:SOLUBLE IN WATER
Appearance and Odor:WHITE OR COLORLESS CRYSTALS; ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REACTS DANGEROUSLY (EXPLOSION, IGNITION, PROPELLANT TYPE BURNING,
FORMATION EXPLOSIVE PRODUCTS) W/ACETYLENE, (SUPDAT)
Stability Condition to Avoid:INCOMPATIBLE MATERIALS, COMBUSTIBLE
MATERIALS, REDUCING AGENTS.
Hazardous Decomposition Products:NITROGEN OXIDES, SILVER OXIDES.
Conditions to Avoid Polymerization:HAS NOT BEEN REPORTED.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL,
STATE, AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN .
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:NONE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:JORGE DIAZ
* Composition/Information on Ingredients *
Ingred Name:BENZENESULFONIC ACID, DODECYL-, CMPND WITH
2,2'2"-NITRILOTRIS (ETHANOL);(TRIETHANOLAMINE DODECYLBENZENE
SULFONATE)
Ingred Name:NONYLPHENOXYPOLY (ETHYLENEOXY) ETHANOL;
(NONYLPHENOXYPOLYETHOXYETHANOL)
Ingred Name:COCO IMIDAZOLINE AMPHOTERIC
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN AND EYE IRRITANT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:NONE KNOWN.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
PHYSICIAN IF IRRITATION PERSISTS. INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE O2/ARTF RESP) . INGEST: GET MD IMMEDIATELY
.
* Fire Fighting Measures *
Extinguishing Media:NOT APPLICABLE. EXTINGUISHING MEDIA SUITABLE FOR
SURROUNDING FIRE .
Fire Fighting Procedures:NONE. WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO SEWER WITH COPIOUS AMOUNTS OF WATER.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:KEEP OUT OF RECH OF CHILDREN.
Other Precautions:
* Physical/Chemical Properties *
HCC:N1
Spec Gravity:1.0 (H2O=1)
Solubility in Water:COMPLETE
Appearance and Odor:BLUE COLOR, PERFUMED LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:
Hazardous Decomposition Products:CO, CO2.
* Disposal Considerations *
Waste Disposal Methods:FOLLOW ALL FEDERAL, STATE AND LOCAL WASTE
DISPOSAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Product ID: RED VALVE ACTION PAINT MARKER
*
Preparer Co. when other than Responsible Party Co.
*
*
Contractor Summary
*
*
Ingredients
*
------------------------------
% Wt: 1-5
------------------------------
------------------------------
% Wt: 1-5
------------------------------
% Wt: 1-5
OSHA PEL: 5 MG/CUM DUST
ACGIH TLV: RESPIRABLE DUST
------------------------------
% Wt: 1-5
Other REC Limits: 5 MG/CUM (DUST)
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: MAY CAUSE SLIGHT IRRITATION. SKIN: MAY CAUSE
IRRITATION & DERMATITIS. INGESTION: ASPIRATION OF EVEN SMALL QUANTITIES
OF VOMITUS INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS & PULMONARY
EDEMA/HEMORR HAGE. INHALATION: MAY CAUSE CNS DEPRESSION & IRRITATION OF
THROAT, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION, DEFATTING, DRYING, HEADACHE,
NAUSEA, DIZZINESS, LOSS OF CONSCIOUSNESS.
THOROUGHLY W/SOAP & WATER. INGESTION: DON'T INDUCE VOMITING. ASPIRATION
HAZARD. INHALATION: REMOVE TO FRESH AIR. GIVE CPR/OXYGEN IF NEE DED. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
*
Handling and Disposal
*
Spill Release Procedures: WEAR RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT.
SMALL: TAKE UP W/ABSORBENT MATERIAL & PLACE IN NON-LEAKING CONTAINER.
SEAL CONTAINER FOR PROPER DISPOSAL. LARGE: DIKE & CONTAIN. REMOVE
IGNITION SOURCES . PROVIDE ADEQUATE VENTILATION. (SEE SUPP)
Waste Disposal Methods: DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
Handling And Storage Precautions: STORE AWAY FROM IGNITION SOURCES, IN A COOL,
WELL VENTILATED AREA. HANDLE AS A FLAMMABLE LIQUID. DON'T DROP CONTAINER.
READ ALL LABEL CAUTIONS.
Other Precautions: AVOID PROLONGED/REPEATED BREATHING OF VAPORS, MISTS
&/DUSTS. USERS OF THIS PRODUCT MUST BE PROPERLY TRAINED & QUALIFIED
IN ITS USE. USE IN WELL VENTILATED AREAS. KEEP OUT OF REACH OF SMALL
CHILDREN.
*
Fire and Explosion Hazard Information
*
Flash Point Method: SCC
Lower Limits: 1
Upper Limits: 7
Extinguishing Media: ALCOHOL RESISTANT FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures: WEAR RESPIRATORY PROTECTION & FULL FIRE-FIGHTING
TURN-OUT GEAR. KEEP PERSONNEL REMOVED & UPWIND OF ANY FIRE. WATER SPRAY
MAY BE INEFFECTIVE. (SEE SUPP)
Unusual Fire/Explosion Hazard: A STREAM OF WATER COULD SPREAD FIRE. VAPORS MAY
TRAVEL TO DISTANT IGNITION SOURCE & FLASH BACK. PRODUCT MAY FLOAT &
BE REIGNITED AT WATER'S SURFACE.
*
*
Respiratory Protection: WEAR A NIOSH APPROVED ATMOSPHERE SUPPLYING/AN
AIR-PURIFYING RESPIRATOR W/APPROPRIATE CHEMICAL/MECHANICAL FILTERS.
Ventilation: MECHANICAL (GENERAL)/LOCAL EXHAUST: SUFFICIENT TO MAINTAIN
EXPOSURE <TLVS.
Other Protective Equipment: RUBBER APRON, CHEMICAL SAFETY SHOES
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health: SPECIAL FIRE: WATER MAY BE USED TO COOL
CONTAINERS. IF WATER IS USED, FOG NOZZLES ARE PREFERRED. SPILLS: TAKE UP
W/ABSORBENT MATERIAL & PLACE IN NON-LEAKING CONTAINER. SEAL CONTAIENR FOR
PROPER DISPOS AL.
*
Physical/Chemical Properties
*
Vapor Density: >1
Spec Gravity: 1
VOC Pounds/Gallon: 6.7
Evaporation Rate & Reference: SLOWER THAN ETHYL ETHER
Solubility in Water: INSOLUBLE
Appearance and Odor: RED PAINT/LIQUID W/PAINT-LIKE ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: HEAT, SPARKS, HOT SURFACES, OPEN FLAMES & OTHER
IGNITION SOURCES.
Materials To Avoid: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products: CO & UNIDENTIFIED ORGANIC COMPOUNDS.
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Product ID: RED VALVE ACTION PAINT MARKER
Company Name: LA-CO INDUSTRIES, INC./MARKAL CO.
Label Required IND: Y
Status Code: A
Origination Code: G
Hazard And Precautions: EYES: MAY CAUSE SLIGHT IRRITATION. SKIN: MAY CAUSE
IRRITATION & DERMATITIS. INGESTION: ASPIRATION OF EVEN SMALL QUANTITIES
OF VOMITUS INTO LUNGS MAY CAUSE CHEMICAL PNEUMONITIS & PULMONARY
EDEMA/HEMORR HAGE. INHALATION: MAY CAUSE CNS DEPRESSION & IRRITATION OF
THROAT, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENT DOES NOT MAINTAIN INHAL EXPOS BELOW PEL,
IN OSHA PROT FACTOR, NIOSH/MSHA APPRVD AIR PURIFYING OV/FILTER
UNITS OK. FULL FACE PIECE RESP PROT UNITS REQ.
Ventilation:PROVIDE SUFFICIENT GEN/LOC EXHAUST VENT IN PATTERN/VOLUME
TO CONTROL INHAL EXPOS BELOW CURRENT EXPOS LIM & AREAS(ING 9)
Other Protective Equipment:PROTECTIVE GARMENTS SUCH AS APRONS, JACKETS,
PANTS, COVERALLS, BOOTS ETC.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES & REC
PROCEDURES. WASH EXPOS AREAS PROMPTLY & THORO AFTER SKIN CONT
Supplemental Safety and Health
HAZ:CAN FORM EXPLOS MIX IN AIR AT ELEVATED TEMP. CLSD CONTR MAY
EXPLODE WHEN EXPOSED TO EXTREME HEAT (FIRE). EFTS OF
OVEREXPOS:DEATH. INGEST:MAY CAUSE DIZZ, NAUS, STOMACH UPSET.
CAUSES EYE IRRIT. HARMFUL IF INHAL/INGEST/ABSORB THROUGH SKIN. (ING
4)
* Product Identification *
Kit Part:Y
Preparer's Name:OCCUP HLTH/PROD SFTY DEPT
* Composition/Information on Ingredients *
Ingred Name:ING 7:USE W/ADEQ VENT. DO NOT USE PRODUCT UNTIL MSDS HAS
BEEN READ & UNDERSTOOD. NOT FOR USE/STORAGE IN/AROUND HOME.
Ingred Name:VENT:BELOW FLAMM VAP CONC. LOC EXHAUST IS NEC FOR USE IN
ENCLOSED/CONFINED SPACES.
Ingred Name:HYGIENE PRACT:WORKING W/PROD & BEFORE EATING, DRINKING,
PRODUCT.
Ingred Name:OTHER PREC:AREA. PROTECT FROM PHYSICAL DMG. KEEP CONTRS
CLSD WHEN MATL IS NOT IN USE. MAINTAIN GOOD HOUSEKEEPING.(ING 8)
Ingred Name:STYRENE (SARA III)
Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA III)
Ingred Name:POLYMER, UNSPECIFIED
Ingred Name:SUPDAT:AVOID PROLONGED AND/OR REPEATED CONTACT.
Ingred Name:FIRST AID PROC:OVEREXPOS TO MATL. TREATMENT SHOULD BE
DIRECTED AT CONTROL OF SYMPS & CLINICAL CONDITIONS.
Ingred Name:SPILL PROC:FLUSH AWAY WITH WATER TO SEWER SERVICED BY A
WASTEWATER TREATMENT FACILITY.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRODUCED
SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A
SIMILAR EFT IN HUMANS. ADRENOMETICS (E.G., EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAI NING USES IN HUMANS
ACUTELY/CHRONICALLYEXPOSED TO CHLOROCARBONS . EYE:VAP MAY CAUSE
IRRIT, (EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:GROUP 2 (NTP), GROUP
2B (IARC). STRENE:GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ:TEARING, BLURRED VISION. DIRECT CONT
MAY PRODUCE CORNEAL DMG. SKIN:PRLNGD/RPTD CONT CAN CAUSE IRRIT
(POSS SEV). ABSORPTION OF LIQ THROUGH SKIN MAY PRODUCE DMG TO
INTERNAL ORGANS. INHAL:HIGH C ONC OF VAP CAN CAUSE IRRIT OF RESP
TRACT INCLUDING NOSE & THROAT, HDCH, DIZZ, NAUS, WEAKNESS,
COLLAPSE, COMA/(SUPDAT)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING DISEASE
IN/ HISTORY OF AILMENTS INVOLVING KIDNEY, LIVER, SKIN, RESP TRACT,
BLOOD, CARDIOVASCULAR SYS ARE AT GREATER THAN NORMAL RISK OF DEV
ADVERSE EFTS WHEN EXPOS TO MATL.
* First Aid Measures *
MD AID. SKIN:REMOVE CONTAM CLTHG. WASH THORO W/SOAP & WATER. IF
IRRIT PERSISTS, SEEK MD AID. WASH CONTAM CLTHG BEFORE REUSE.
INHAL:REMOVE FROM EXPOS. IF BRTHG HAS STOPPED/DFCLT,ADMIN ARTIF
RESP/O2 AS INDICATED. SEEK MD AID. INGEST:DO NOT INDUCE VOMIT.
IMMED SEEK MD AID. NOTE TO MD:THERE IS NO SPECIFIC ANTIDOTE FOR
EFTS FROM (ING 5)
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:USE DRY CHEMICAL, CARBON DIOXIDE, FOAM OR WATER
SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA &
FULL PROT EQUIP . USE WATER TO COOL FIRE-EXPOSED
CONTR/STRUCTURE/PROT PERSONNEL. WATER/FOAM MAY CAUSE (SUPDAT)
Unusual Fire/Explosion Hazard:THERM DECOMP PROD MAY INCLUDE HCL &
PHOSGENE . COMBUST LIQ (OSHA CLASS IIIB)-SLIGHT FIRE HAZ WHEN EXPOS
TO HEAT/ FLAME. NO UNUSUAL FIRE HAZ. VAP (SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. STAY UPWIND.
WEAR APPROP EYE, SKIN & NIOSH/MSHA APPRVD RESP PROT. SMALL
SPILL:TAKE UP W/ SAND/OTHER NONCOMBUST ABSORB MATL. DIKE LRG SPILLS
FOR LATER DISP. WASH DOWN SPI LL AREA W/1-5% AQUEUOS AMMONIA
SOLUTION& (ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID SKIN & EYE CONT W/LIQUEFIED
GASES. AVOID PRLNGD/RPTD CONT W/SKIN/EYES. DO NOT WEAR CONTAM
CLTHG. DISCARD CONTAM FOOTWEAR.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES/HOT SURF. HEAT AND/OR UV RADIA
MAY CAUSE FORMATION OF HCL AND/OR PHOSGENE . KEEP IN CLSD, LBL
CONTR WITH IN A COOL (WELL SHADED), DRY VENT (ING 7)
* Physical/Chemical Properties *
HCC:T6
Solubility in Water:INSOLUBLE
Appearance and Odor:CLEAR PALE YELLOW LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
OXIDIZING AGENTS, ACIDS, CAUSTIC, METALLIC HALIDES (SALTS)
Stability Condition to Avoid:AVOID OPEN FLAME, HEAT, OXIDIZING AGENTS,
FREE RADICAL CATALYSTS AND PEROXIDE.
Hazardous Decomposition Products:HCL, PHOSGENE . SMOKE, CO, CO2,
HALOGEN, HALOGEN ACIDS, HYDROGEN CHLORIDE.
Conditions to Avoid Polymerization:HEAT, OXIDIZING AGENTS, FREE RADICAL
CATALYSTS, PEROXIDE.
* Disposal Considerations *
Waste Disposal Methods:DECOMPOSITION OF THIS PRODUCT MAY PRODUCE
HAZARDOUS VAPORS. DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NONE REQUIRED W/NORMAL USE.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH EXPOSED SKIN FOR HYGIENIC PURPOSES.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:WESTLEYS CONCENTRATE CAR WASH, WCW4
CAGE:BLUE2
CAGE:BLUCL
CAGE:BLUE2
* Composition/Information on Ingredients *
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BENZENESULFONIC ACID, DODECYL-, SODIUM SALT; (SODIUM
DODECYLBENZENE SULFONATE) (CERCLA)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:ALCOHOL ETHOXYSULFATE SALT; (SODIUM FATTY ALCOHOL ETHER
SULFATE)
OSHA PEL:N/K
ACGIH TLV:N/K
(COCO DIETHANOL AMIDE)
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NOT RELEVANT
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE O*2/ARTF
RESP) . SKIN:WASH W/SOAP & WATER. EYES:REMOVE CONTACT LENSES &
W/WATER & THEN DRINK 1 GLASS OF WATER. CALL MD.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
* Accidental Release Measures *
Spill Release Procedures:WASH AWAY W/WATER, OR APPLY INERT ABSORBANT.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE AT AMBIENT TEMPERATURES AWAY
FROM FOOD & DRINK.
Other Precautions:KEEP FROM FREEZING. KEEP AWAY FROM CHILDREN. DO NOT
STORE NEAR FOOD OR DRINK.
* Physical/Chemical Properties *
pH:9
Solubility in Water:COMPLETE
Appearance and Odor:TRANSPARENT, BLUE VISCOUS LIQUID WITH
FLORAL/HYACINTH FRAGRANCE.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN TO BLUE CORAL, INC.
Stability Condition to Avoid:NONE KNOWN TO BLUE CORAL, INC.
Hazardous Decomposition Products:NONE KNOWN TO BLUE CORAL, INC.
* Disposal Considerations *
Waste Disposal Methods:APPLY INERT ABSORBANT, SWEEP UP & CARRY TO
LANDFILL OR ACCORDING TO LOCAL, STATE OR FEDERAL POLLUTION CONTROL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:RESP PROT REQUIRED IF AIRBORNE CONCENTRATION
HIGH-EFFICIENCY PARTICULATE RESPIRATOR IS RECOMMENDED. ABOVE THIS
LEVEL, A NIOSH/MSHA APPROVED SCBA IS ADVISED.
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
REQUIREMENTS.
Other Protective Equipment:UNIFORM. EMERGENCY EYE BATH AND DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MATLS TO AVOID: AGENTS, CARBIDES.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:STANNOUS CHLORIDE DIHYDRATE
OSHA PEL:2 MG/M3 (SN)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHAL: IRRIT OF UPPER RESPIRATORY
TRACT, SEVERE IRRITATION OR BURNS OF MUCOUS MEMBRANES. SKIN: SEVERE
IRRITATION OR BURNS, PROLONGED CONTACT MAY CAUSE SKIN SENSIT. EYE:
SEVERE IRRITATION OR BURNS. SKI N ABSORPTION: RAPID ABSORPTION.
INGEST:IRRIT & BURNS TO MOUTH & STOMACH, HDCH, NAUS, VOMIT, DIZZ,
GI IRRIT.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE IDENTIFIED.
* First Aid Measures *
First Aid:INGEST: CALL MD. IF SWALLOWED, DO NOT INDUCE VOMIT. IF
CONSCIOUS, GIVE LRG AMTS OF WATER. INHAL: REMOVE TO FRESH AIR. IF
NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DIFFICULT, GIVE OXYGEN.
REMOVING CONTAM CLTHG & SHOES. WASH CLTHG BEFORE RE-USE. EYE: IMMED
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING
FIRE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. MOVE CONTAINERS FROM FIRE AREA IF IT CAN BE DONE WITHOUT RISK.
USE WATER TO KEEP FIRE-EXPOSED CNTNRS COOL.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO HEAT MAY
EXPLODE. NOTE: DECOMPOSES AT MELTING POINT.
* Accidental Release Measures *
Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE CLOTHING. WITH CLEAN SHOVEL, CAREFULLY PLACE MATERIAL
INTO CLEAN, DRY CONTAINER AND COVER; REMOVE FROM AREA. FLUSH SPILL
AREA WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN, ON
CLOTHING. AVOID BREATHING DUST. KEEP IN TIGHTLY CLOSED CONTAINER IN
A COOL PLACE. WASH THOROUGHLY AFTER HANDLING.
Other Precautions:SUITABLE FOR ANY GENERAL CHEMICAL STORAGE AREA.
* Physical/Chemical Properties *
HCC:C3
Appearance and Odor:SOLID WHITE CRYSTALS, ODORLESS.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BROMINE TRIFLUORIDE & TRICHLORIDE, NITRATES, ALKALIES, ALCOHOLS,
AMMONIA, SODIUM, POTASSIUM, STRONG OXIDIZING(SUPP DATA)
Stability Condition to Avoid:HEAT, FLAME, MOISTURE.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, TIN OXIDE FUME.
* Disposal Considerations *
Waste Disposal Methods:IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE
& LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT APPLICABLE. USE NIOSH APPROVED RESPIRATOR
APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:NOT APPLICABLE.
Other Protective Equipment:EMERGENCY EYEWASH AND DELUGE SHOWER MEETING
ANSI DESIGN CRITERIA .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:ALKALINE BATTERIES
* Composition/Information on Ingredients *
Ingred Name:CARBON
Fraction by Wt: <5%
OSHA PEL:N/K
ACGIH TLV:3.0 MG/M3 (MFR)
Ingred Name:MANGANESE DIOXIDE
Fraction by Wt: <5%
OSHA PEL:5 MG MN/M3 CEILING
ACGIH TLV:5 MG MN/M3
Fraction by Wt: <5%
OSHA PEL:C, 0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:POTASSIUM HYDROXIDE (CERCLA)
Fraction by Wt: 2-8%
OSHA PEL:C 2 MG/M3
ACGIH TLV:C 2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: NONE UNDER NORMAL CONDITIONS.
CHRONIC:
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
First Aid:INGESTION: CONTACT THE NATIONAL CAPITOL POISON CENTER,
COPIOUS AMO UNTS OF WATER. SEE MD . INHALATION: REMOVE TO FRESH
AIR. SUPPORT BREATHING (GIVE OXYGEN OR ARTIFICIAL RESPIRATION) .
* Fire Fighting Measures *
Extinguishing Media:IN BULK STORAGE AREAS, USE CARBON DIOXIDE, FOAM OR
DRY POWDER; WATER MAY CAUSE ELECTRICAL SHORTS.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CELLS MAY RUPTURE WHEN EXPOSED TO
EXCESSIVE HEAT.
* Accidental Release Measures *
Spill Release Procedures:BATTERIES ARE A DRY SOLID AND CAN BE HANDLED
EASILY WITH SHOVELS OR SIMILAR EQUIPMENT. WHEN ACCUMULATING LARGE
QUANTITIES OF UNDISCHARGED BATTERIES FOR DISPOSAL, PACK IN A
NON-CONDUCTIVE INSULATING MA TERIAL.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE UNPACKAGED CELLS TOGETHER
SO CONTACTS CAN TOUCH. THIS SITUATION WILL RESULT IN CELL SHORTING
AND HEAT BUILD-UP.
Other Precautions:DO NOT RECHARGE THIS TYPE OF BATTERY.
* Physical/Chemical Properties *
Appearance and Odor:VARIOUS COLORS, NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Stability Condition to Avoid:EXCESSIVE HEAT, ELECTRICAL SHORT.
Hazardous Decomposition Products:NOT APPLICABLE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE ACCORDING TO APPROPRIATE LOCAL, STATE
AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Other Protective Equipment:PROTECTIVE CLOTHING,AS NEEDED.PROVIDE A
LOCAL EYE WASH STATION AND SAFETY SHOWER.
Work Hygienic Practices:NORMAL PRACTICES AND PROCEDURES.
Supplemental Safety and Health
NONE.
* Product Identification *
Product ID:SEALED NICKEL-CADMIUM ACCUMULATOR
Preparer's Name:DR. J.WOIDT-Q.A. MGR.
* Composition/Information on Ingredients *
Ingred Name:NICKEL HYDROXIDE (SARA III)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG(NI)/M3
Ingred Name:NICKEL (SARA III)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
Ingred Name:CADMIUM (AS CD);(SARA III)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 MG/M3 DUST; Z-2
IS 1.3 KG/L
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C, 2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:NO EXPOSURE EXPECTED UNDER NORMAL
CONDITIONS OF USE. IF BATTERY RUPTURES, CONTACT MAY CAUSE BURNS.
Explanation of Carcinogenicity:NICKEL AND CADMIUM ARE LISTED UNDER IARC
AND NTP. NO EXPOSURE EXPECTED UNDER NORMAL CONDITIONS OF USE.
Effects of Overexposure:NO EXPOSURE EXPECTED UNDER NORMAL CONDITIONS OF
USE. IF CONTACTED WHEN BATTERY RUPTURE, IT MAY CAUSE BURNS TO EYES
AND SKIN.
* First Aid Measures *
First Aid:IF LEAKAGE FROM BATTERY CONTACT EYES: FLUSH IF PLENTY OF
WITH PLENTY OF WATER. WASH WITH SOAP AND WATER. IF IRRITATION
PERSISTS, GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CONTACT WITH STRONG OXIDIZERS MAY CAUSE
FIRE OR EXPLOSION. MAY BURST WHEN SUBJECT TO EXTREME HEAT. CADMIUM
FUMES OR VAPORS ARE TOXIC AND CAN CAUSE DEATH.
* Accidental Release Measures *
AND SAFETY GLASSES. COLLECT ALL RELEASED MATERIAL IN A PLASTIC BAG
FOR WASTE DISPOSAL. WASH AREA WITH PLENTY OF WATER.
Neutralizing Agent:DILUTE BORIC ACID.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE. PROTECT FROM
PHYSICAL DAMAGE, HEAT, FLAMES AND INCOMPATIBLE MATERIALS.
Other Precautions:DO NOT SHORT CIRCUIT BATTERIES. THEY MAY CAUSE BURNS
WHEN IN CONTACT WITH SKIN OR EYES. USE PROPER BATTERY CHARGER.
OBSERVE CORRECT POLARITY.
* Physical/Chemical Properties *
HCC:N1
Appearance and Odor:CAUSTIC ELECTROLYTE IN BATTERY CASE.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, NITRATES, NITRIC ACID. BATTERY MAY SHORT
CIRCUIT IN WATER.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES.
Hazardous Decomposition Products:METAL OXIDE FUMES MAY BE EVOLVED AT
TEMPERATURES ABOVE MELTING POINT.
* Disposal Considerations *
Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS. DO NOT INCINERATE OR DISPOSE OF WITH HOUSEHOLD TRASH.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:GENERAL
Other Protective Equipment:RUBBER OR PLASTIC APRON
Supplemental Safety and Health
* Product Identification *
Product ID:UNIVERSAL PROCESSOR CLEANER
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN/EYES: IRRITATION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:SKIN/EYES: IRRITATION.
* First Aid Measures *
First Aid:SKIN/EYES: FLUSH W/WATER. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE MEDIA APPLICABLE TO THE PRIMARY CAUSE OF FIRE.
Fire Fighting Procedures:EVACUATE TO A SAFE AREA REMOVED & UPWIND OF
THE FIRE.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN SPILL. NEUTRALIZE W/SODIUM
BICARBONATE. FLUSH TO SEWER W/PLENTY OF WATER.
Neutralizing Agent:SODIUM BICARBONATE
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE. DON'T STORE OR CONSUME FOOD, DRINKS, OR TOBACCO IN AREAS
WHERE THEY MIGHT BE CONTAMIANTED BY PRODUCT.
Other Precautions:DON'T WEAR CONTACT LENSES WHILE HANDLING PRODUCT.
* Physical/Chemical Properties *
pH:4.5
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR BLUE LIQUID W/NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
REDUCING AGENTS
Stability Condition to Avoid:FIRE OR EXCESSIVE HEAT
* Disposal Considerations *
Waste Disposal Methods:FLUSH TO SEWER W/PLENTY OF WATER IN ACCORDANCE
W/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY REQUIRED. IF VAPOR CONCENTRATIONS
IS HIGH, USE A NIOSH APPROVED ORGANIC VAPOR RESPIRATOR.
Ventilation:MECHANICAL EXHAUST MAY BE NEEDED IN CONFINED AREAS.
Other Protective Equipment:RUBBER APRONS, EYEWASH STATION, SAFETY
SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.WASH THOROUGHLY W/SOAP & WATER.
Supplemental Safety and Health
* Product Identification *
Product ID:GLIDSAFE (R) PREPSOLV
* Composition/Information on Ingredients *
Ingred Name:CARVENE; CYCLOHEXENE, 1-METHYL-4-(1-METHYLETHENYL), CITRUS
TERPENE, D-LIMONENE, P-MENTHADIENE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION. SKIN: IRRITATION.
MAY CONTAIN TRACE AMOUNTS OF DEGRADED MATERIAL (CREATED BY
OXIDATION) WHICH ARE ALLERGENIC TO SENSITIVE INDIVIDUALS.
INHALATION: CAN CAUSE RESPIRATORY TRACT IRRITAT ION.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, SORE THROAT, COUGHING, SHORTNESS OF
BREATH, NAUSEA, DIZZINESS.
* First Aid Measures *
& WATER. INHALATION: REMOVE TO FRESH AIR. INGESTION: DRINK LOTS OF
WATER TO DILUTE SUBSTANCE. OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:TCC
Extinguishing Media:CO2, DRY CHEMICAL, FOAM. IF WATER IS USED, USE AS A
SPRAY.
Unusual Fire/Explosion Hazard:FLAMMABLE LIQUID. AVOID HEAT, SPARKS &
* Accidental Release Measures *
Spill Release Procedures:SMALL: ABSORBED BY DIRT, SAND/OTHER SUITABLE
ABSORBENT. LARGE: MAY BE DIKED W/EARTH & PUMPED TO CLOSED
CONTAINERS FOR RECOVERY/DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:AVOID PROLONGED EXPOSURE TO AIR, HEAT,
SPARKS & OPEN FLAMES. AVOID WARM STORAGE. KEEP CONTAINERS TIGHTLY
CLOSED WHEN NOT IN USE.
Other Precautions:STORE AWAY FROM STRONG ACIDS & BASES.
* Physical/Chemical Properties *
Vapor Pres:1
Vapor Density:4.7
Evaporation Rate & Reference:(BU AC =1): >1
Solubility in Water:<0.1
Appearance and Odor:CLEAR, NEARLY COLORLESS LIQUID W/CITRUS ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, BASES. MATERIALS THAT REACT W/UNSATURATED HYDROCARBONS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES. OXIDATION OF
HUGE AMOUNTS.
Hazardous Decomposition Products:CO2, CO, ACRID FUMES
* Disposal Considerations *
Waste Disposal Methods:DON'T DISCHARGE INTO LAKES, STREAMS,
PONDS/PUBLIC WATERS. PRODUCT IS CONSIDERED A HAZARDOUS WASTE. UN/NA
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:LOCAL EXHAUST: RECOMMENDED
Other Protective Equipment:EMERGENCY SHOWER & EYE WASH STATION
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:KEROSENE, KEROSINE
Ingred Name:BENZIN, NAPHTHA, MINERAL SPIRITS, PETROLEUM NAPHTHA
Fraction by Wt: <5%
Ingred Name:PROPANE
Fraction by Wt: <5%
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:ISOBUTANE, 2-METHYLPROPANE
Fraction by Wt: <5%
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: SEVERE IRRITATION. INGESTION: GI
IRRITATION. SKIN: IRRITATION. INHALATION: RESPIRATORY TRACT
IRRITATION, NERVOUS SYSTEM DEPRESSION. EUPHORIA.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, REDNESS, BURNING, NAUSEA, DIARRHEA,
DEFATTING, DIZZINESS, WEAKNESS, HEADACHE, NARCOSIS
* First Aid Measures *
GIVE SEVERAL GLASSES OF WATER. DON'T INDUCE VOMITING. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. INHALATION: REMOVE TO
FRESH AIR.GIVE CPR IF NEEDED. SKIN: WASH W/SOAP & WATER. OBTAIN
MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Extinguishing Media:FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:USE FULL PROTECTIVE GEAR & SCBA. COOL FIRE
EXPOSED CONTAINERS W/WATER SPRAY.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA & REMOVE ALL SOURCES OF
IGNITION. SOAK UP ON INERT ABSORBENT & PLACE IN A CLOSED CONTAINER
FOR DISPOSAL.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL DRY PLACE. KEEP
CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE. KEEP AWAY FROM HEAT/OPEN
FLAME & DIRECT SUNLIGHT.
Other Precautions:KEEP OUT OF REACH OF CHILDREN. DON'T
PUNCTURE/INCINERATE CANS. USE W/ADEQUATE VENTILATION.
* Physical/Chemical Properties *
Vapor Density:<1
Evaporation Rate & Reference:(EHTER=1): >1
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, WATER WHITE LIQUID W/SOLVENT ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE
SUNLIGHT
Hazardous Decomposition Products:OXIDES OF CARBON, HYDROCHLORIC ACID &
CHLORINE GASES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF CANS IN NON-INCINERATED TRASH ONLY.
DISPOSE OF IAW/LOCAL, STATE & FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF INCINERATED, USE NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED AIR RESPIRATOR WITH
FULL FACEPIECE, OPERATED IN POSITIVE PRESSURE MODE.
Ventilation:USE ADEQUATE LOCAL EXHAUST VENTILATION WHEN FUMES PRESENT.
Other Protective Equipment:EYE WASH STATION, QUICK DRENCH SHOWER AND
IMPERVIOUS CLOTHING
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A, SAME NSN. DO NOT
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:NICKEL OXIDE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3 AS NI
ACGIH TLV:1 MG/M3 AS NI
POTASSIUM HYDROXIDE)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 2 MG/M3
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.2 MG (CD)/M3 DUST
Fraction by Wt: 9%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.1MG/M3 FUME/1 DUST
Ingred Name:NYLON II
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:TARGET ORGANS:EYES, SKIN, RESPIRATORY,
GI TRACTS. ACUTE- CONTENTS OF AN OPEN BATTERY (KOH) CAN CAUSE
SEVERE IRRITATION/BURNS TO TISSUE CONTACTED. CAN CAUSE BLINDNESS.
NICKEL MAY CAUSE SKIN SENSITIZATI ON. INGESTION CAN BE
HARMFUL/FATAL. CHRONIC- CADMIUM MAY CAUSE LUNG OR KIDNEY DAMAGE.
NICKEL MAY CAUSE LUNG DAMAGE.
LISTED BY NTP AND IARC AND REGULATED BY OSHA AS A CARCINOGEN. ALSO
CONTAINS NICKEL
Effects of Overexposure:NONE UNDER NORMAL CONDITIONS OF USE. IF LEAKING
OR INCINERATED: SEVERE IRRITATION, BURNS, CHEST PAIN, COUGHING,
SWEATING, CHILLS, SHORTNESS OF BREATH, WEAKNESS, BLINDNESS, NICKEL
ITCH
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING SKIN
DISORDERS, EYE PROBLEMS OR IMPAIRED KIDNEY OR RESPIRATORY FUNCTION
MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT.
* First Aid Measures *
First Aid:GET MEDICAL ATTENTION IMMEDIATELY. EYE/SKIN:IF CONTACT WITH
POTASSIUM HYDROXIDE ELECTROLYTE, IMMEDIATELY FLUSH WITH WATER FOR
USED TO NEUTRALIZE KOH ON SKIN. INHALED:REMOVETO FRESH AIR.
PROVIDE OXYGEN/CPR IF NEEDED. ORAL:DO NOT INDUCE VOMITING. IF
CONSCIOUS, DRINK LARGE AMOUNT OF WATER OR MILK.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, FOAM OR DRY CHEMICAL
FOR SURROUNDING FIRE. USE WATER SPRAY TO COOL FIRE EXPOSED
CONTAINERS.
Fire Fighting Procedures:WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. HAZARDOUS DECOMPOSITION
PRODUCTS MAY BE FORMED.
Unusual Fire/Explosion Hazard:CADMIUM AND NICKEL FUMES ARE TOXIC AND
CAN CAUSE DEATH.
* Accidental Release Measures *
Spill Release Procedures:BATTERY AND CELL CASES WILL NORMALLY CONTAIN
MATERIALS OF CONCERN. USE INDUSTRIAL ABSORBENT TO COLLECT LIQUID
ACID.
Neutralizing Agent:CITRIC ACID
*Handling and Storage *
Handling and Storage Precautions:DO NOT SHORT CIRCUIT. AVOID BREAKING,
CRUSHING OR OTHERWISE DESTROYING THE PHYSICAL INTEGRITY OF THE CELL
OR BATTERY.
Other Precautions:DO NOT INCINERATE. DO NOT TOUCH BROKEN OR LEAKING
BATTERIES. WASH THOROUGHLY AFTER HANDLING. AVOID BREATHING FUMES.
KEEP OUT OF REACH OF SMALL CHILDREN. NO SMOKING DURING BATTERY
CHARGING. ALWAYS USE EXTREME CARE. AVOID OPEN FLAME.
* Physical/Chemical Properties *
HCC:B1
NRC/State Lic Num:NOT RELEVANT
Spec Gravity:NOT RELEVANT
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:NOT RELEVANT
Appearance and Odor:BATTERY - NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ORGANIC CHEMICALS, ACIDS, METALS SUCH AS ZINC, ALUMINUM, TIN,
CHLORINATED AND AROMATIC HYDROCARBONS, NITROCARBONS
Stability Condition to Avoid:EXCESSIVE HEAT, FIRE
Hazardous Decomposition Products:TOXIC FUMES OF CADMIUM OXIDE, NICKEL
OXIDE, CADMIUM, POTASSIUM HYDROXIDE
* Disposal Considerations *
Waste Disposal Methods:CELLS AND BATTERIES MAY BE RETURNED TO SAFT FOR
RECYCLING OR AT SENDERS EXPENSE TO A PERMITTED TREATMENT, STORAGE,
DISPOSAL FACILITY (TSDF). DISPOSAL MUST BE MADE IN ACCORDANCE WITH
ALL APPLICABLE FED ERAL, STATE AND LOCAL LAWS AND REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPRVD RESP PROTECTION FOR SOLVENT
VAPORS
Ventilation:LOCAL EXHST & MECHANICAL
Other Protective Equipment:CONFORM W/RECOGNIZED HYGIENIC PRACTICES FOR
STODDARD SOLVNT
Supplemental Safety and Health
* Product Identification *
Product ID:NEW METAL GARD
* Composition/Information on Ingredients *
Ingred Name:STODDARD SOLVENT
* Hazards Identification *
Effects of Overexposure:INH: NASAL & RESP IRRIT, DIZ,WEAKNESS. SKIN:
PRIMARY IRRIT. PRLNG/RPTD CNTCT MAY CAUSE DERMATITIS.
* First Aid Measures *
First Aid:SKIN:WASH THOROUGHLY W/SOAP & WATER. EYES:FLUSH THOROUGHLY
W/CLEAN WATER, GET MEDICAL ATTN. INH: REMOVE TO FRESH AIR. CALL MD.
* Fire Fighting Measures *
Extinguishing Media:CO*2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:DO NOT USE WATER
Unusual Fire/Explosion Hazard:CAUTION! COMBUSTIBLE: AVOID EXCESSIVE
HEAT, SPARKS OR OPEN FLAMES.
* Accidental Release Measures *
Spill Release Procedures:HANDLE AS AN OIL SPILL. AVOID BREATHING VAPORS
OR MISTS - USE ADEQ VENTILATION. ABSORB LIQUID ON VERMICULITE,
FLOOR ABSORBENT. ELIMINATE SOURCES OF IGNITION. PREVENT RUNOFF TO
SEWERS OR STREAMS.
*Handling and Storage *
Handling and Storage Precautions:CAUTION!COMBUSTIBLE!STORE AT TEMP
BELOW FLASH POINT. STORE IN A COOL, DRY AREA IN TIGHTLY CLSD
CONTAINERS. KEEP FROM EXCESS HEAT, SPARKS, OPEN FLAME
Other Precautions:USE ADEQ VENTILATION. AVOID BREATHING VAPORS OR
MISTS.AVOID CONTACT W/THE SKIN, EYES & CLOTHING. WASH THOROUBHLY
W/SOAP & WATER AFTER HANDLING.
* Physical/Chemical Properties *
Vapor Density:4.0
Solubility in Water:NEGLIGIBLE
Appearance and Odor:TAN LIQ W/ MINERAL SPIRITS ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS
Hazardous Decomposition Products:THERM DECOMP OR BURNING-POSS OXIDES OF
C, CA, S, & P
* Disposal Considerations *
Waste Disposal Methods:SM SPILLS:ALLOW TO EVAP IN HOOD OR PROTECTED
AREA. LG SPILL:DEPOSIT LIQ IN ABSORBENT IN APPROVED LAND FILL IAW
FED, STATE & LOCAL CODES OR BY CONTROLLED INCINERATION. (MFR RECM)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF AIRBORNE DUST LEVELS ARE HIGH, A NIOSH
APPROVED DUST MASK IS RECOMMENDED TO AVOID INHALATION.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH AFTER HANDLING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:UREA
OSHA PEL:N/K
ACGIH TLV:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:NUISANCE DUST
ACGIH TLV:5 MG/M3 (MFR)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: POSSIBLE NAUSEA, VOMITING AND
DIARRHEA - POSSIBLE EYE AND SKIN IRRITATION. CHRONIC: NONE KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:SKIN ABRASIONS AND SORES.
INHALATION OF DUST MAY AGGRAVATE ASTHMA.
* First Aid Measures *
EYELIDS OPEN. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN:
WASH THOROUGHLY. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INHAL: REMOVE T O FRESH AIR. TREAT SYMPTOMATICALLY. CALL A
PHYSICIAN. INGESTION: INDUCE VOMITING OR GASTRIC LAVAGE IF LARGE
AMOUNTS INGESTED. TREAT SYMPTOMATIC AND SUPPORTIVE.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, WATER FOG, FOAM, CO*2.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:SULFUR DUST CAN FORM EXPLOSIVE MIXTURE
WITH AIR. IF PRODUCT IS CONSUMED IN A FIRE, TOXIC SULFUR DIOXIDE
WILL FORM.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP SPILLS. USE GOOD HOUSEKEEPING
PRACTICES. AVOID CONTACT WITH SKIN, EYES, OR CLOTHING. WASH AFTER
HANDLING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:AVOID BAG BREAKAGE, KEEP AWAY FORM
FEED OR FOODSTUFFS. AVOID CONTACT WITH SKIN, EYES, OR CLOTHING.
KEEP OUT OF REACH OF CHILDREN.
Other Precautions:KEEP OUT OF LAKES, STREAMS, OR PONDS.
* Physical/Chemical Properties *
Appearance and Odor:GRANULAR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:IN A FIRE, THERMAL DECOMPOSITION OF
UREA & METHYLENE UREAS WILL GENERATE AMMONIA. OXIDES OF NITROGEN,
SULFUR & CARBON ARE ALSO POSSIBLE.
* Disposal Considerations *
Waste Disposal Methods:REMOVE TO APPROVED LANDFILL IN ACCORDANCE WITH
FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED CHEMICAL CARTRIDGE RESPIRATOR IS
RECOMMENDED WHEN USING THES PRODUCT.
Ventilation:LOCAL & GENERAL VENT NEC TO KEEP AIR CONC BELOW TLV (FP N/
ORNL).SUFFICIENT LOCAL EXHAUST & MECHANICAL VENT IN LOW AREAS
Other Protective Equipment:EYEWASH STATIONS. NEOPRENE APRON SUITABLE TO
PROTECT CLOTHING.
Work Hygienic Practices:GOOD HOUSEKEEPING.
Supplemental Safety and Health
ADRENOMIMETICS (I.E., EPINEPHRINE) MAY BE CONTRA-INDICATED EXCEPT
FOR LIFE- SUSTA INING USES IN HUMANS ACUTELY OR CHRONICALLY EXPOSED
TO CHLOROCARBONS OR CHLOROFLUOROCARBONS .
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:1,1,1-TRICHLOROETHANE
Other REC Limits:N/K
Ozone Depleting Chemical:1
Other REC Limits:N/K
Ozone Depleting Chemical:1
Other REC Limits:N/K
Ozone Depleting Chemical:1
Ingred Name:FLOUROPOLYMER
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:HAS BEEN SUGGESTED TO CAUSE CARDIAC
ABNORMALITIES, LIVER, KIDNEY AND LUNG DAMAGE. CARDIAC SENSITIZER BY
INGESTION. SEVERE INHALATION OVEREXPOSURE MAY CAUSE DEATH.
DELIBERATELY CONCENTRATING AND INHALI NG VAPORS MAY BE HARMFUL OR
FATAL.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES/SKIN:SEVERE IRRITATION. INGESTION:N/K .
INHALATION: NARCOTIC AT HIGH CONCENTRATIONS. MAY CAUSE DIZZINESS,
WEAKNESS, UNCONSCIOUSNESS.
Medical Cond Aggravated by Exposure:CARDIAC ABNORMALITIES
* First Aid Measures *
IRRITATION PERSISTS.SKIN:WASH WITH SOAP & WATER. INGESTION:CALL MD
IMMEDIATELY .INHALATION:REMOVE TO FRESH AIR,GIVE OXYGEN IF
BREATHING D IFFICULT.GET MEDICAL ATTENTION.MD NOTE:CHLOROCARBON/
CHLOROFLUOROCARBON (CFC) MATERIALS HAVE PRODUCED SENSITIZATION OF
THE MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR
EFFECT (SUPDA
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:CARBON DIOXIDE AND FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED PRESSURE DEMAND
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE EQUIPMENT .
USE SHIELDING TO PROTECT FROM RUPTURED CANS.
Unusual Fire/Explosion Hazard:THERMAL DECOMP PRODS MAY INCLUDE
FLUORIDES, CHLORIDES & PHOSGENE . EXCESS HEAT CAN CAUSE CNTNR
RUPTURE.HAZ DECOMP PROD:CO,CO2,HCL AND TRACES OF PHOSGENE.
* Accidental Release Measures *
Spill Release Procedures:WASH AWAY WITH WATER.
Neutralizing Agent:N/K
*Handling and Storage *
Handling and Storage Precautions:CONTENTS UNDER PRESSURE. DO NOT
VENTILATED AREA. AVOID CONTACT WITH EYES AND SKIN.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES, OR HOT SURFACES. HEAT MAY
CAUSE THE FORMATION OF CHLORIDES, FLUORIDES OR PHOSGENE . KEEP OUT
OF REACH O F CHILDREN. AVOID BREATHING VAPORS.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:SEE SUPP
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:SEE SUPP
Vapor Density:>1,AIR=1
Spec Gravity:1.0,WATER=1
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Solubility in Water:NIL
Appearance and Odor:OPAQUE WHITE LIQUID WITH SHARP ETHEREAL ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, ALUMINUM METAL.
Stability Condition to Avoid:SOURCES OF EXTREME HEAT.
Hazardous Decomposition Products:FLUORIDES, CHLORIDES AND PHOSGENE .
CARBON DIOXIDE, CARBON MONOXIDE AND HYDROGEN CHLORIDE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .DO NOT INCINERATE AEROSOL.BURY
ACCORDING TO LOCAL,STATE AND FEDERAL REGULATIONS.WASTE CONTENTS MAY
LISTED.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE OVERSPRAY IS PRESENT, NIOSH APPRVD POS
PROPERLY FITTED NIOSH APPRVD ORG VAP/PARTICULATE RESP FOR PROT
AGAINST INGS MAY BE EFTIVE. FOLL OW RESP MFR'S DIRECTIONS FOR (ING
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPT IF EXPOS IS MAINTAINED
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . USE BARRIER CREAM ON EXPOSED SKIN.
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC:PVNT PRESS BUILD-UP & POSS AUTO-IGNIT/EXPLO WHEN EXPOS
TO EXTREME HEAT. MATLS TO AVOID:PRESS IN & POSS BURSTING OF CLSD
CNTNRS. WASTE DISP METH:INCIN CLSD CNTNR. DISP OF I/A/W FED, STA TE
& LOC REGS REGARDING POLLUTION. EXPLO HAZ:HOT SURFS REQS SPECIAL
PRECS. DURING EMER CNDTNS OVEREXP TO DECOMP (ING 8)
* Product Identification *
* Composition/Information on Ingredients *
Fraction by Wt: 7%
Fraction by Wt: 4%
Fraction by Wt: 6%
Ingred Name:CYCLOHEXANONE (CERCLA). VP:2.
Ingred Name:ACETIC ACID, BUTYL ESTER; (N-BUTYL ACETATE) (CERCLA).
Ingred Name:TALC (POWDER), CONTAINING NO ASBESTOS FIBERS; (TALC)
ACGIH TLV:2 MG/M3 RDUST
Ingred Name:SUPP DATA:PRODUCTS MAY CAUSE HEALTH HAZARD. SYMPTOMS MAY
NOT BE IMMEDIATELY APPARENT. OBTAIN MEDICAL ATTENTION.
Ingred Name:EFTS OF OVEREXP:ALLERGIC RXN ON RPTD EXPOS. METHYL ETHYL
Ingred Name:ING 9:ASSOC RPTD & PRLNG OVEREXP TO SOLVS W/PERM BRAIN &
LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO .
Ingred Name:OTHER PREC:APPRVD CNTNRS W/COMPLETE & APPROP LABELING. KEEP
ISOCYANATES. USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY
Ingred Name:RESP PROT:USE. WEAR NIOSH APPRVD RESP FOR WHOLE TIME OF
AGAINST NON-VOLATILE INGREDIENTS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPOS MAY BE BY INHAL &/OR SKIN/EYE
CONT, DEPENDING ON CNDTNS OF USE. ALCOHOLS & ACETATES CAN BE
ABSORBED THRU SKIN. FOLLOW RECS FOR PROPER USE, VENT & PPE TO MIN
EXPOS. ACUTE:IRRIT OF EYES, SKIN & RE SP SYS. MAY CAUSE NERV SYS
DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON & POSS DEATH. HDCH,
DIZZ, NAUS & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:LOSS OF COORD ARE INDICATIONS OF
EXCESSIVE EXPOS TO VAPS/SPRAY MISTS. REDNESS & ITCH/BURNING
SENSATION MAY INDICATE EYE/EXCESSIVE SKIN EXPOS. CHRONIC:PRLNG
OVEREXP TO SOLV INGS MAY CAUSE ADVE RSE EFTS TO LIVER, URINARY,
BLOOD FORMING, CVS & REPRO SYS. PERS SENSITIVE TO ISOCYANATE WILL
EXPER INCR (ING 9)
Medical Cond Aggravated by Exposure:MAY CAUSE ALLERGIC RESPIRATORY &/OR
SKIN REACTION IN SUSCEPTIBLE PERSONS OR SENSITIZATION. THIS EFFECT
MAY BE DELAYED FOR SEVERAL HOURS AFTER EXPOSURE.
* First Aid Measures *
First Aid:INHAL:LEAVE AREA & GET FRESH AIR. IF PROBLEMS REMAIN OR OCCUR
LATER, IMEDIATELY GET MEDICAL ATTENTION. SKIN:WASH AFFECTED AREA
THOROUGHLY W/SOAP & WATER. REMOVE CONTAMINATED CLOTHING & LAUNDER
MINUTES. GET MEDICAL ATTENTION. INGEST:GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Lower Limits:0.7%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP .
WATER SPRAY MAY BE INEFT. IF WATER IS USED, FOG NOZZ ARE PREF.
WATER MAY BE USED TO COOL CLSD CNTNRS TO (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. APPLICATION TO HOT SURFS(SUPDAT)
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. VENT AREA. FOR
COLORS & REDUCERS:REMOVE W/INERT ABSORB. FOR CATALYSTS:ALL PERS IN
AREA SHOULD BE PROT AS IN PROT INFO SECTION. COVER SPILL W/ABSORB
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DOL STOR CATEGORY-1B. KEEP AWAY FROM
HEAT, SPKS & OPEN FLAME. CONSULT NFPA CODE. USE APPRVD BONDING &
GROUNDING PROCS. DO NOT TAKE INTERNALLY.
Other Precautions:DURING USE & UNTIL ALL VAPS ARE GONE:KEEP AREA
VENTED; DO NOT SMOKE; EXTING ALL FLAMES, PILOT LIGHTS & HEATERS;
TURN OFF STOVES, ELEC TOOLS & APPLIANCES & ANY OTHER SOURCES OF
* Physical/Chemical Properties *
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CONTAM OF CATALYST W/WATER, ALCOHOLS, AMINES & OTHER CMPDS WHICH REACT
W/ISOCYANATES, MAY RSLT IN DANGEROUS (SUPP DATA)
Stability Condition to Avoid:NONE KNOWN.
Hazardous Decomposition Products:BY FIRE:CARBON DIOXIDE, CARBON
MONOXIDE, OXIDES OF METALS IN INGS, OXIDES OF NITROGEN, POSSIBILITY
OF HYDROGEN CYANIDE.
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM PRODS MAY BE HAZ AS DEFINED UNDER
APPLIC EPA HAZ WASTE NUMBERS. WASTE FROM PRODS CNTNG ING 3 MUST
ALSO BE TESTED FOR EXTRAC TABILITY. INCIN IN APPRVD FACILITY. DO
NOT(SUPDAT)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WITH ADEQUATE VENTILATION, RESPIRATORY EQUIPMENT
SHOULD NOT BE NEEDED. IF ADEQUATE VENTILATION IS NOT AFFORDED, WEAR
NIOSH/ MSHA APPROVED RESPIRATORY EQUIPMENT APPROVED FOR ORGANIC
VAPORS.
Ventilation:USE NATURAL CROSS-VENT, LOC (MECH) PICK-UP &/OR GEN AREA
(MECH) VENT TO PVNT ACCUM OF VAPS. VENT SHOULD BE (SUPP DATA)
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
KEY1;T6. VENT:SUFFICIENT TO KEEP VAPOR CONCENTRATION BELOW TLV.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:BASE MATERIAL (CONSISTING OF INGREDIENTS 2-4)
Ingred Name:SILICA (AMORPHOUS)
Fraction by Wt: 2-5%
Ingred Name:PROPANE, 1-(P-TERT-BUTYLPHENOXY)-2, 3-EPOXY-; (EPOXY RESIN)
Ingred Name:STYRENE POLYMER; (POLYSTYRENE RESIN)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:UPON MIXING & BEFORE CURING, SKIN &
EYE IRRITANT. REPEATED CONTACT MAY CAUSE SENSITIZATION &/OR
DERMATITIS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:CURRENT ALLERGIES & SKIN
CONDITIONS.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR IF EXPOSED TO EXCESS CONCENTRATIONS
OF VAPOR. CALL MD IMMEDIATELY. EYE:FLUSH WELL W/WATER FOR AT LEAST
WATE R. REFER TO MD IF IRRITATION OR SYMPTOMS PERSIST. INGEST:CALL
POISON CONTROL CENTER OR MD FOR GUIDANCE.
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, HALON, WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS IN A FIRE MAY RUPTURE
DUE TO PRESSURE BUILD-UP; USE WATER TO COOL CONTAINERS TO PREVENT
THIS.
* Accidental Release Measures *
Spill Release Procedures:SCOOP MATERIAL INTO CONTAINER, AVOIDING EYE &
SKIN CONTACT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:THIS ADHESIVE IS PACKAGED IN A UNIT
CONSISTING OF BOTH PART A & PART B. READ LABEL CAUTIOUSLY &
Other Precautions:CLOSE CONTAINER AFTER EACH USE. DO NOT REUSE
CONTAINER. KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
HCC:C2
Vapor Density:HVR/AIR
Appearance and Odor:COLORED LIQUID W/MILD ODOR.
Percent Volatiles by Volume:0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS, STRONG ACIDS.
Stability Condition to Avoid:NONE KNOWN
Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE &
OTHER TOXIC VAPORS & GASES THAT ARE COMMON TO THERMAL DEGRADATION
OF ORGANIC CMPDS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, STATE & LOCAL DISPOSAL
REGULATIONS. DO NOT FLUSH EPOXY MATERIAL DOWN DRAINS.
| 1 | eyes_protection_mandatory |
Control Measures
*
Cage: OFTT5
*
Preparer Co. when other than Responsible Party Co.
*
Cage: OFTT5
Assigned Ind: Y
*
Contractor Summary
*
Cage: OFTT5
*
Item Description Information
*
Item Manager: GSA
Item Name: ENAMEL
Type/Grade/Class: TYPE I
Unit of Issue: PT
UI Container Qty: 0
Type of Container: METAL
*
Ingredients
*
------------------------------
------------------------------
------------------------------
------------------------------
------------------------------
------------------------------
------------------------------
ACGIH TLV: NONE
------------------------------
ACGIH TLV: SIMPLE ASPHYXIANT
------------------------------
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: HARMFUL IF SWALLOWED. REPEATED/PROLNGED OVEREXPOSURE TO
SOLVENT WILL CAUSE PERMODENT BRAIN/NERVOUS SYSTEM DAMAGE. IN CONFINED AREAS;
VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC. IRRITATION TO SKIN/RES PIRATORY
TRACT/THROAT. SEVERE EYE IRRITATION.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: IRRITATION/HEADACHES/NAUSEA/VOMITING/LIGHT
HEADEDNESS/STAGGERING GAIT/GIDDINESS.
Medical Cond Aggravated By Exposure: RESPIRATORY AILMENTS.
INHALATION: REMOVE TO FRESH AIR/GIVE CPR IF NECESSARY. INGESTION: DON'T
INDUCE VOMITING NEVER GIVE UNCONSCIOUS PERSON ANYTHING BY MOUTH. OBTAI N
MEDICAL ATTENTION IN ALL CASES.
*
Handling and Disposal
*
Spill Release Procedures: REMOVE ALL SOURCES OF IGNITION/VENTILATE AREA. MOP
SPILLS W/INERT ABSORBENT. AVOID BREATHING VAPORS.
Waste Disposal Methods: DISCARD EMPTY CAN IN TRASH PICK-UP. DON'T PLACE IN HOME
TRASH COMPACTOR. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL
REGULATIONS.
Handling And Storage Precautions: CAUTION CONTENTS UNDER PRESSURE. DON'T STORE
W/EYES/SKIN. USE W/GOOD VENTILATION.
Other Precautions: READ ENTIRE LABEL BEFORE USING. INTENTIONAL MISUSE BY
DELIBERATELY CONCENTRATING/INHALING/SWALLOWING MAY BE HARMFUL/FATAL. KEEP OUT
HEAT MAY CAUSE CAN TO BURST.
*
Fire and Explosion Hazard Information
*
Lower Limits: 2.2
ANY BURNING LIQUID W/WATER SPRAY.
Fire Fighting Procedures: WATER MAY BE INEFFECTIVE, BUT MAY BE USED TO KEEP
FIRE EXPOSED CONTAINERS COOL. USE SCBA/SHIELDING TO PROTECT AGAINST
BURSTING/RUPTURING/VENTING OF CONTAINERS.
*
*
Respiratory Protection: USE NIOSH/MSHA APPROVED MASK ABOVE TLV.
Ventilation: LOCAL EXHAUST: PREFERRED. MECHANICAL (GENERAL): ACCEPTABLE AT
POINT OF MIST/SPRAY RELEASE.
Other Protective Equipment: IMPERVIOUS CLOTHES, EYE WASH STATION.
Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE REUSE. USE
GOOD PERSONAL HYGIENE. DON'T EAT/DRINK/SMOKE WHILE USING PRODUCT.
*
Physical/Chemical Properties
*
HCC: V3
Solubility in Water: INSOLUBLE
Appearance and Odor: YELLOW/PAINT
*
Reactivity Data
*
Stability Indicator: YES
IGNITION SOURCES.
Hazardous Decomposition Products: CO
Hazardous Polymerization Indicator: NO
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Cage: OFTT5
Assigned IND: Y
Company Name: LHB INDUSTRIES
Label Required IND: Y
Status Code: C
Origination Code: F
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: HARMFUL IF SWALLOWED. REPEATED/PROLNGED OVEREXPOSURE TO
SOLVENT WILL CAUSE PERMODENT BRAIN/NERVOUS SYSTEM DAMAGE. IN CONFINED AREAS;
VAPORS IN HIGH CONCENTRATION ARE ANESTHETIC. IRRITATION TO SKIN/RES PIRATORY
TRACT/THROAT. SEVERE EYE IRRITATION. TARGET ORGANS: EYES, SKIN, RESPIRATORY
& DIGESTION TRACTS, BRAIN & NERVOUS SYSTEM. RGANS: EYES, LUNGS &
CENTRAL NERVOUS SYSTEM.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH APPROVED DUST RESPIRATOR (NUISANCE
DUST) IF CONCENTRATION EXCEEDS TLV.
Ventilation:RECOMMENDED DURING CAST REMOVAL
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:CALCIUM SULFATE
Other REC Limits:5 MG/CUM (DUST)
Ingred Name:COTTON
Fraction by Wt: 6%
Ingred Name:BINDERS, TYPE UNSPECIFIED
Fraction by Wt: 1%
Ingred Name:STARCH
Fraction by Wt: 1%
Other REC Limits:NUISANCE PARTICULATE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: DUST MAY CAUSE IRRITATION. SKIN:
SUFFICIENT HEAT TO CAUSE BURNS IF A LARGE MASS, SUCH AS A CAST OF A
HAND OR AN ARM, IS KEPT IN CONTACT WHILE HARDENING. INHALATION:
DUST PARTICLES MAY CAUSE PHYS ICAL IRRITATION OF NASAL PASSAGE,
THROAT & RESPIRATORY SYSTEM. INGESTION: HARDENING, RESULTING IN
OBSTRUCTION/PYLORUS.
Explanation of Carcinogenicity:NONE
* First Aid Measures *
First Aid:EYES/SKIN: FLUSH W/PLENTY OF WATER. INHALATION: REMOVE TO
FRESH AIR. INGESTION: SEEK PROMPT MEDICAL ATTENTION. TREAT SYMPTOMS
OF PHYSICAL OBSTRUCTION OF PASSAGEWAYS. OBTAIN MEDICAL ATTENTION IN
ALL CA SES.
* Accidental Release Measures *
Spill Release Procedures:PLACE MATERIAL INTO CLEAN, DRY CONTAINER &
COVER. VACUUM UP REMAINING DUST ON FLOOR TO MINIMIZE CREATING
EXCESS AIRBORNE DUST BY SWEEPING. WASH SPILL W/PLENTY OF WATER.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT W/HIGH HUMIDITY
CONDITIONS/WATER IN STORAGE TO AVOID PREMATURE HARDENING OF CASTING
MATERIAL.
Other Precautions:DEW POINT CONDITIONS OR OTHER CONDITIONS CAUSING THE
PRESENCE OF WATER WILL HARDEN PLASTER DURING STORAGE. PRODUCT
HARDENS IN 5-8 MINS AFTER WATER APPLICATION.
* Physical/Chemical Properties *
Appearance and Odor:BANDAGES: COTTON GAUZE ROLLS IMPREGNATED W/CALCIUM
SULFATE/ODORLESS WHITE POWDE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HIGH HUMIDITY
* Disposal Considerations *
Waste Disposal Methods:NOT CONSIDERED A HAZARDOUS WASTE UNDER RCRA/EPA
DEFINITION. PLASTER OF PARIS MAY PLUG DRAINS WHEN SOLIDIFIED.
DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY REQUIRED. USE NIOSH/MSHA APPROVED
RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN .
Ventilation:MECHANICAL (GENERAL): PREFERRED.
Other Protective Equipment:RUBBER APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Preparer's Name:WILLIAM DIGNIN
* Composition/Information on Ingredients *
Ingred Name:GLUTARALDEHYDE; (1,5-PENTANEDIAL). VAP DENS: 3.5
OSHA PEL:0.2 PPM, C
ACGIH TLV:0.2 PPM, C
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: HARMFUL SKIN ABSORPTION.
IRRITATION OF EYES, SKIN, MUCOSA. SEVERE CORNEAL INJURY. HEADACHE.
BRONCHITIS. NAUSEA. CHRONIC: SENSITIZATION. SKIN RASH.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NO DATA.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. CALL MD IF SYMP PERSIST. EYES:
IMMED FLUSH WITH WATER. CALL MD IF IRRITATION PERSISTS. INGEST:
GIVE 2 GLA SSES OF WATER AND INDUCE VOMITING. CALLMD.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:CONTAIN WITH ABSORBENT. DO NOT FLUSH TO DRAIN.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY AREA.
Other Precautions:
* Physical/Chemical Properties *
HCC:T6
Vapor Density:ING 1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR LIQUID WITH SHARP ALDEHYDE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ALKALIES AND ACIDS.
Hazardous Decomposition Products:CO OR CO*2 IF BURNED.
* Disposal Considerations *
Waste Disposal Methods:APPROVED WASTE MANAGEMENT FACILITY. INCINERATION
WHERE PERMITTED. DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:THERE ARE NO INGREDIENTS ABOVE 0.1% WHICH ARE
IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Ventilation:USE LOCAL EXHAUST.
Other Protective Equipment:NO SPECIAL REQUIREMENTS
Work Hygienic Practices:EXECISE GOOD LABORATORY PRACTICES.WASH HANDS
AFTER USE AND BEFORE EATING.
Supplemental Safety and Health
NONE
* Product Identification *
Preparer's Name:JANET MEHTA
CAGE:0BZC5
CAGE:0BZC5
* Composition/Information on Ingredients *
Ingred Name:ASCORBIC ACID
Other REC Limits: RECOMMENDED
OSHA PEL:NOT EXTABLISHED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES:MAY CAUSE IRRITATION.SKIN:MAY
CAUSE IRRITATION.MAY BE DERMALLY ABSORBED.INGEST:MAY CAUSE GI TRACT
IRRITATION.INHAL:MAY CAUSE RESPIRATORY IRRITATION.CHRONIC:POSSIBLE
HYPERSENSITIZATION.
Explanation of Carcinogenicity:THERE ARE NO INGREDIENTS ABOVE 0.1%
WHICH ARE IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.
Effects of Overexposure:SYSTEMIC
EFFECTS:DIARRHEA,FLUSHING,HEADACHE,INCREASE IN
URINATION,NAUSEA,VOMITING,STOMACH CRAMPS.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
HYPERSENSITIVITY TO ASCORBIC ACID MAY BE AT INCREASED RISK FROM
EXPOSURE.
* First Aid Measures *
First Aid:SKIN:REMOVE CONTAMINATED CLOTHING;WASH WITH SOAP AND
MINUTES.GET MEDICAL ATTENTION.INHAL:REMOVE TO FRESH AIR.GIVE OXYGEN
OR ARTIFICIAL RESPIRAT ION IF NEEDED.INGEST:GET PROMPT QUALIFIED
MEDICAL ATTENTION.IF CONSCIOUS,FLUSH MOUTH WITH WATER.
* Fire Fighting Measures *
Flash Point:
Extinguishing Media:WATER SPRAY,DRY CHEMICAL,CARBON DIOXIDE,FOAM.
Fire Fighting Procedures:USE A SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:FIRE CONDITIONS MAY EVOLVE TOXIC FUMES.
* Accidental Release Measures *
Spill Release Procedures:WIPE UP WORKING SURFACE TO DRYNESS;PLACE
COLLECTED MATERIAL IN AN APPROPRIATE CONTAINER FOR DISPOSAL;CLEAN
SPILL AREA WITH SOAP AND WATER TO REMOVE SLIPPERINESS.
Neutralizing Agent:NOT APPLICABLE.
*Handling and Storage *
CLOSED WHEN NOT IN USE.KEEP AWAY FROM HEAT,LIGHT,AIR AND
INCOMPATIBLE MATERIALS.
Other Precautions:FOLLOW LABEL DIRECTIONS.AVOID BREATHING VAPORS.AVOID
SKIN AND EYE CONTACT.
* Physical/Chemical Properties *
HCC:N1
pH:5.5-7
Solubility in Water:SOLUBLE
Appearance and Odor:LIQUID,CLEAR;PALE YELLOW;ODORLESS.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS,FERRIC SALTS OR SALTS OF HEAVY METALS.
Stability Condition to Avoid:HEAT,LIGHT AND OXYGEN MAY CAUSE
DECOMPOSITION.
Hazardous Decomposition Products: SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH FEDERAL,STATE AND
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATORY PROTECTION IS NOT
REQUIRED UNDER NORMAL USE. USE NIOSH APPROVED RESPIRATORS WHERE
DUST, MIST OR SPRAY MAY BE GENERATED.
Ventilation:LOC EXHST VENT WHERE DUST/MIST/SPRAY MAY BE GENERATED.
WHERE CO/OTHER RXN PRODS MAY BE GENERATED SPEC VENT MAY BE REQD.
Other Protective Equipment:ANSI APPRVD EYE WASH & DELUGE SHOWER . WEAR
IMPERVIOUS PROT CLTHG & CHEM RESIST SFTY SHOES TO MINIMIZE CNTCT.
Work Hygienic Practices:WASH CONTAM CLTHG W/SOAP & WATER & DRY BEFORE
Supplemental Safety and Health
WHEN HNDLG THIS PROD, AVOID CNTCT W/ALUMINUM, TIN, ZINC & ALLOYS
CONTAINING THESE METALS. DO NOT MIX W/STRONG ACIDS W/OUT DILUTIO N
& AGITATION TO PVNT VIOLENT OR EXPLO RXN. AVOID CNTCT W/LEATHER,
WOOL, ACIDS, ORG HALOGEN CMPDS & ORGANIC NITRO CMPDS.
* Product Identification *
CAGE:0STM5
* Composition/Information on Ingredients *
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:SODIUM HYDROXIDE (NA(OH)) (CERCLA)
OSHA PEL:2 MG/M3
ACGIH TLV:2 MG/M3, C
Ingred Name:SODIUM CHLORIDE (NACL)
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:CHLORIC ACID, SODIUM SALT
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:EFTS OF OVEREXP: MUC MEMBS OF MOUTH, THROAT, ESOPHAGUS &
STOM. CHRONIC:NO KNOWN EFTS. FOR MORE INFO CNTCT NEHC .
Ingred Name:FIRST AID: IF BRTHG DFCLT HAVE TRAINED PERSON ADMIN O*2. IF
RESPIRATION STOPS, GIVE MOUTH-TO-MOUTH RESUSCITATION.(ING 7)
Ingred Name:ING 6:GET MED ATTN. INGEST:NEVER GIVE ANYTHING BY MOUTH IF
UNCON. IF SWALLOWED, DO NOT INDUCE VOMIT. GIVE LG QTYS(ING 8)
Ingred Name:ING 7: OF WATER. IF AVAIL, GIVE SEVERAL GLASSES OF MILK. IF
VOMIT OCCURS SPONT, KEEP AIRWAY CLEAR. GET MED ATTN IMMED.
Ingred Name:SPILL PROC:APPRVD CNTNRS, LABELED & STORED IN SAFE PLACE
Ingred Name:ING 9: MAY BE HANDLED BY REMOVING AFFECTED SOILS & PLACING
AGENCIES. CAUTION:CAUSTIC SODA MAY REACT VIOLENTLY W/ACIDS & WATER.
Ingred Name:HNDLG/STOR PRECS: EXPOS IS POSS. WHEN HNDLG WEAR PPE. WASH
Ingred Name:OTHER PRECS: SLOWLY TO SURF OF LUKEWARM WATER TO ASSURE
CONCENTRATED AT BOTTOM OF MIXING VESSEL, EXCESS HEAT MAY BE (ING
GRADUALLY, STIRRING CONSTANTLY. ALWAYS EMPTY & CLEAN CNTNRS (ING
DOT REGS. REMOVE RESIDUAL CAUSTIC SODA FROM CNTNRS BEFORE DISP.
Ingred Name:EYE PROT: & FULL LENGTH FACESHIELD .
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:CORR TO ALL BODY TISS BY ALL
ROUTES OF EXPOS. EFT OF LOC DERMAL EXPOS MAY CONSIST OF MULTIPLE
AREAS OF SUPERFICIAL DESTRUCTION OF SKIN/OF PRIMARY IRRITANT DERM.
SIMILARLY, INHAL OF DUST/SPRAY/MI ST MAY RSLT IN VARYING DEGREES OF
IRRIT/DMG TO RESP TRACT TISS & INCRD SUSCEPTIBILITY TO RESP
ILLNESS. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: INHAL:BRTHG DUST/MIST/SPRAY MAY CAUSE
DMG TO UPPER RESP TRACT & LUNG TISS PROPER WHICH COULD PRDCE CHEM
PNEUM, DEPENDING ON SEVERITY OF EXPOS. SKIN:CNTCT PRDCES SEV BURNS
& DESTROYS TISS. IR RIT MAY BE DELAYED. EYE CNTCT:CAUSES SEV BURNS
RSLTG IN DMG TO EYES & POSS BLINDNESS. INGEST:CAUSES SEV BURNS TO
(ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
LIDS APART TO ENSURE FLUSHING OF ENTIRE SURF. WASHING EYES W/IN
SEVERAL SECS IS ESSNTL TO ACHIEVE MAX EFTIVENESS. GET MED ATTN
CONTAM CLTHG & FOOTWEAR. WASH CLTHG BEFORE REUSE & DISCARD FOOTWEAR
IF CANNOT BE DECONTAM. GET MED ATTN IMMED. INHAL:REMOVE TO FRESH
AIR.(ING 6)
* Fire Fighting Measures *
Extinguishing Media:THIS PRODUCT IS NOT COMBUSTIBLE. FOAM, CARBON
DIOXIDE OR DRY CHEMICAL MAY BE USED WHERE THIS PRODUCT IS STORED.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT . AVOID DIRECT CONTACT OF THIS PRODUCT WITH WATER AS THIS
CAN CAUSE A VIOLENT EXOTHERMIC REACTION.
Unusual Fire/Explosion Hazard:DIRECT CONTACT WITH WATER CAN CAUSE A
VIOLENT EXOTHERMIC REACTION. SEE REACTIVITY SECTION.
* Accidental Release Measures *
Spill Release Procedures:STOP LEAKS. CNTN & CLEAN UP SPILLS IMMED;
REMOVE BY USING VACUUM TRUCK. NEUT REMAINING TRACES OF MATL W/ANY
DILUTE INORG ACID. FLUSH SPILL AREA W/WATER FOLLOWED BY LIBERAL
COVERING OF SODIUM BICARBONA TE. REMOVE & PLACE ALL CLEAN-UP MATL
IN(ING 9)
Neutralizing Agent:INORGANIC ACID SUCH AS HYDROCHLORIC, SULFURIC,
NITRIC, PHOSPHORIC & ACETIC ACID.
*Handling and Storage *
Handling and Storage Precautions:DO NOT GET INTO EYES, ON SKIN/CLTHG.
AVOID BRTHG DUST/MISTS/SPRAY. DO NOT TAKE INTERNALLY. USE W/ADEQ
Other Precautions:PROD CAN REACT VIOLENTLY W/WATER. CONSIDERABLE HEAT
GENERATED WHEN PROD MIXED W/WATER; WHEN MAKING SOLNS ALWAYS
CAREFULLY FOLLOW THESE STEPS. ALWAYS WEAR ALL PROT CLTHG. NEVER ADD
* Physical/Chemical Properties *
pH:SUPDAT
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:COMPLETELY SOLUBLE
Appearance and Odor:CLEAR LIQUID WITH NO DISTINCT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
SEE HNDLG & STOR SECTION. AVOID CNTCT W/WATER. PROD MAY BE ADDED SLOWLY
TO WATER/ACIDS W/DILUTION & AGITATION (SUPDAT)
Stability Condition to Avoid:UNDER NORMAL CONDITIONS, THIS PRODUCT IS
STABLE.
Hazardous Decomposition Products:NONE KNOWN.
* Disposal Considerations *
Waste Disposal Methods:MATLS RSLTG FROM CLEANUP MAY BE HAZ WASTES &
THEREFORE, SUBJECT TO SPECIFIC REGS. PACKAGE, STORE, TRANSPORT &
DISP OF ALL CLEAN-UP MATLS & ANY CONTAM EQUIP I/A/W ALL APPLIC FED,
STATE & LOC HLTH & ENV IRONMENTAL REGS. CNTCT NEHC FOR MORE INFO .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED DUST MASK RESPIRATOR.
Ventilation:MECHANICAL EXHAUST.
Other Protective Equipment:USE CARBIDE TIPPED BLADES FOR SAWING.
EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA .
Work Hygienic Practices:WASH HANDS BEFORE EATING OR SMOKING. LAUNDER
CLOTHES SEPARATELY FROM HOUSEHOLD LAUNDRY.
Supplemental Safety and Health
* Product Identification *
Product ID:CCA PRESSURE TREATED WOOD
Preparer's Name:ZYGMUNT TOWARNICKI
CAGE:CSXXX
CAGE:CSXXX
* Composition/Information on Ingredients *
Ingred Name:TRIVALENT CHROMIUM COMPOUND
Fraction by Wt: 0.4-3.8%
OSHA PEL:0.1 MG/M3 (MFR)
ACGIH TLV:0.1 MG/M3 (MFR)
Ingred Name:COPPER OXIDE
Fraction by Wt: 0.2-1.6%
OSHA PEL:1.0 MG/M3 (MFR)
ACGIH TLV:1.0 MG/M3 (MFR)
Fraction by Wt: 0.3-2.7%
OSHA PEL:0.5 MG/M3 (MFR)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:NO OSHA:YES
Health Hazards Acute and Chronic:ACUTE: INHAL: WOOD DUST MAY CAUSE
IRRIT TO UPPER RESP TRACT. SKIN: MAY CAUSE MILD DERM/SKIN
SENSITIVITY. SKIN ABSORPTION: MAY CAUSE MILD DERM/SKIN SENSITIVITY.
EYES: DUST CAN CAUSE IRRIT. INGEST: WOOD FIBERS MAY CAUSE
ABDOMINAL PAIN, NAUSEA, DIARRHEA. CHRONIC: WOOD DUST MAY SKIN CAUSE
IRRIT & BREATHING DIFFICULTY.
Explanation of Carcinogenicity:ARSENIC PENTOXIDE: NTP 7TH ANNUAL REPORT
FEDERAL (SUP DAT)
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MINUTES. SKIN: WASH WITH SOAP AND WATER. CONTACT MD IF IRRITATION
PERSISTS. INHALATION: MOVE TO FRESH AIR. INGESTION: INDUCE VOMITING
IF PERSON IS CONSCIOUS. NOTES TO MD: WOOD DUST CONTAINS CHROMATED
COPPER ARSENATE.
* Fire Fighting Measures *
Extinguishing Media:WATER, FOG, FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . TOXIC VAPORS MAY BE GIVEN OFF FROM BURNING
WOOD. ASHES MAY CONTAIN TOXIC COMPOUNDS.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:MAINTAIN CLEAN WORK AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:ALWAYS FOLLOW GOOD HYGIENE PRACTICE.
AVOID HANDLING OR SAWING FRESHLY TREATED WET WOOD.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
Spec Gravity:0.6 (H*2O=1)
Solubility in Water:HIGHLY INSOLUBLE
Appearance and Odor:LIGHT TO DARK GREEN COLOR, NO ODOR APPARENT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NOT APPLICABLE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:THERMAL: ASH WILL CONTAIN FREE ARSENIC
AND CHROMIUM AND MAY BE TOXIC.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF TREATED WOOD WASTE IN ACCORDANCE WITH
ALL LOCAL, STATE & FEDERAL LAWS IN SANITARY LANDFILL. DO NOT BURN.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED ORGANIC VAPOR RESPIRATOR.
Ventilation:LOCAL & MECHANICAL EXHAUST
Other Protective Equipment:SAFETY SHOWER AND EYE WASH FACILITIES.
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
CAGE:0KDPZ
CAGE:0KDPZ
CAGE:0KDP7
* Composition/Information on Ingredients *
Ingred Name:N-BUTYL GLYCIDYL ETHER (BGE)
Fraction by Wt: 2.5%
Other REC Limits:NONE SPECIFIED
Ingred Name:EPICHLOROHYDRIN (SARA III)
Other REC Limits:NONE SPECIFIED
OSHA PEL:S, 5 PPM
Ingred Name:SILVER (SARA III)
Other REC Limits:NONE SPECIFIED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:PROPRIETARY ORGANIC SOLVENTS
* Hazards Identification *
Health Hazards Acute and Chronic:SILVER DUST IS NONTOXIC, BUT IT CAN
LEAD TO LIFE LONG DISFIGUREMENT BY DEPOSITING SILVER UNDER THE SKIN
(ON THE TISSUES), WHICH DARKENS UPON EXPOSURE TO LIGHT.
PIGMENTATION MAY FORM IN THE LUNGS OF IN DIVIDUALS WHO HAVE INHALED
SILVER DUST.
Effects of Overexposure:CAN CAUSE MILD SKIN IRRITATION. MILDLY
IRRITATING TO EYES.
* First Aid Measures *
First Aid:GET MEDICAL ATTENTION IMMEDIATELY. INHALATION:REMOVE TO FRESH
AIR. GIVE ARTIFICIAL RESPIRATION IF NECESSARY. SKIN:WASH WITH SOAP
& WATER. GET MEDICAL HELP IF IRRITATION PERSISTS. EYES:FLUSH WITH
* Fire Fighting Measures *
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:USE SELF CONTAINED BREATHING APPARATUS.
* Accidental Release Measures *
Spill Release Procedures:SCOOP UP EXCESS AND REMOVE. RESIDUAL CAN BE
REMOVED WITH NONFLAMMABLE SOLVENT. INCINERATE IN ACCORDANCE WITH
LOCAL POLLUTION REGULATIONS AND ORDINANCES.
**MASSES OF MORE THAN 3 POUNDS PLUS AN ALIPHATIC AMINE WILL CAUSE
IRREVERSIBLE POLYMERIZATION WITH CONSIDERABLE HEAT BUILD-UP.
* Physical/Chemical Properties *
Spec Gravity:7.8
Appearance and Odor:SILVER COLORED PASTE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS,ACETYLENE,AMMONIA,ETHANOL,OXALIC ACID,TARTARIC
ACID, & NITRIC ACID, ETHLENEIMINE, BROMOAZIDE & *
Stability Condition to Avoid:STORAGE AT ELEVATED TEMPERATURES OVER LONG
PERIODS OF TIME.
Hazardous Decomposition Products:CO, CO2 *HYDROGEN PERXIDE.
Conditions to Avoid Polymerization:EXCESSIVE EXOTHERMS WHEN CURED.**
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN ACCORDANCE WITH LOCAL POLLUTION
REGULATIONS AND ORDINANCES.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPRVD AIRRESP OR AIR HOSE MASK WHEN
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PIGMENTS
Ingred Name:VEHICLE
Ingred Name:ADDITIVES
Fraction by Wt: 1.4%
Ingred Name:WATER
* Hazards Identification *
Effects of Overexposure:SKIN & EYE:IRRITANT
* First Aid Measures *
MILD SOAP & WATER. SEE MD.
* Fire Fighting Measures *
Flash Point:NONE, PMCC
Extinguishing Media:NON-FLAMMABLE
* Accidental Release Measures *
Spill Release Procedures:WIPE UP IMMEDITELY & SAFELY. DISCARD SATURATED
ABSORBANTS. IN THE EVENT OF LARGE SPILLS, DIKE AREA & PUMP MATERIAL
TO A WASTE TANK. CLEAN UP AREA WITH SOAP & WATER.
*Handling and Storage *
Handling and Storage Precautions:DO NOT STORE AT TEMPERATURES ABOE
Other Precautions:MFR STATES THERE ARE NO HAZARDOUS INGREDIENTS IN
PRODUCT.
O*2 DEFICIENCTY-MFR
Ventilation:LOCAL EXHAUST & MECH VENT RECOMMD TO KEEP BELOW TLV.
Supplemental Safety and Health
* Physical/Chemical Properties *
HCC:N1
Evaporation Rate & Reference:1, (WATER=1)
Solubility in Water:APPRECIABLE
Appearance and Odor:VARIES WITH COLOR,LOW MILD SWEET ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL METHODS MUST BE IAW FEDERAL,STATE &
LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED. USE NIOSH APPROVED
RESPIRATOR IF PRODUCT IS MISTED OR TLV IS EXCEEDED.
Ventilation:NORMAL ROOM VENTILATION IS NORMALLY SUFFICIENT. USE LOCAL
EXHAUST WHEN NECESSARY TO MAINTAIN EXPOSURE BELOW TLV.
Work Hygienic Practices:USE NORMAL CHEMICAL HYGIENE PRACTICE.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:KAREL WRIGHT
DIV
* Composition/Information on Ingredients *
Ingred Name:TRIPHENYL PHOSPHATE
Fraction by Wt: <0.2%
OSHA PEL:3 MG/M3
Ingred Name:POLYALPHAOLEFIN (PER.SPEC.SECT. 3.2)
Ingred Name:CORROSION INHIBITORS - TYPE NOT SPECIFIED (PER SPEC.SECT.
3.2.1.1)
Ingred Name:RUBBER SWELLING AGENTS - TYPE NOT SPECIFIED. (PER
SPEC.SECT. 3.2.1.2)
Ingred Name:ANTI-WEAR AGENTS - TYPE NOT SPECIFIED (PER SPEC.SECT.
3.2.1.4)
Ingred Name:RED DYE
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:PRODUCT IS A MILD IRRITANT. TRIPHENYL
PHOSPHATE HAS BEEN REPORTED TO INHIBIT CHOLINESTERASE IN HUMANS.
TRIPHENYL PHOSPHATE COMPRISES <0.2% OF THE PRODUCT.
Effects of Overexposure:EYE,SKIN IRRITATION
Medical Cond Aggravated by Exposure:NONE REPORTED.
* First Aid Measures *
CLOTHING. WASH WITH SOAP & WATER. INHALED:REMOVE FROM EXPOSURE. -IF
ANY SYMPTOMS ARE SEVERE,GET MEDICAL ATTENTION.- INGESTED:DO NOT
INDUCE VOMITIN G DUE TO ASPIRATION HAZARD. GET IMMEDIATE MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point Method:COC
Extinguishing Media:CO2, FOAM, DRY CHEM & H2O FOG.
Fire Fighting Procedures:WATER OR FOAM MAY CAUSE FROTHING IF PRODUCT IS
Unusual Fire/Explosion Hazard:PRODUCT IS COMBUSTIBLE AT ELEVATED
TEMPERATURES.
* Accidental Release Measures *
Spill Release Procedures:ABSORB ON INERT MATERIAL. STORE IN CLOSED
CONTAINERS PENDING DISPOSAL.
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED
AREA FREE FROM IGNITION SOURCES.
* Physical/Chemical Properties *
HCC:V6
Solubility in Water:SIGHT
Appearance and Odor:CLEAR RED OILY LIQUID - PETROLEUM ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT,IGNITION SOURCES
Hazardous Decomposition Products:NORMAL PRODUCTS OF COMBUSTION PLUS
SULFUR OXIDES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W FEDERAL,STATE,LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WHERE AIR CONTAMINANTS CAN EXCEED ACCEPTABLE
CRITERIA USS NIOSH/MSHA APPROVED RESPIRATORY PROTECTION EQUIPMENT.
SELECT RESPIRATORS BASED ON FORM & CONCENTRATION OF CONTAMINATES &
Ventilation:OPEN DOORS, WINDOWS OR USE OTHER MEANS(I.E. EXHAUST FAN) TO
ENSURE FRESH AIR ENTRY DURING APPLICATION & DRYING.
Other Protective Equipment:MFR GAVE NO INFORMATION ON MSDS.
Work Hygienic Practices:HANDLE I/A/W GOOD INDUSTRIAL HYGIENE & SAFETY
PRACTICES. AVOID UNNEDESSARY EXPOSURE. REMOVE FROM EYES, SKIN,
CLOTHING.
Supplemental Safety and Health
MSDS IS FOR AEROSOL CAN OF ADHESIVE WHILE TIR DESCRIBES 3 FL OZ SELF
SPREADER BOTTLE. ITEM WAS PURCHASED BY DSCV, BUT NO CTDF WAS
INCLUDED IN THE PACKAGE.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:DIMETHYL ETHER
Ingred Name:N-HEPTANE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NOT TOXIC DERMALLY. NOT TOXIC ORALLY.
MAY BE HARMFUL IF INHALED. MAY CAUSE EYE &/OR SKIN IRRITATION.
Explanation of Carcinogenicity:MANUFACTURER GAVE NO INFORMATION ABOUT
CARCINOGENICITY. HMIS FOUND NO LISTING & DOES NOT EXPECT IT TO BE
CARCINOGENIC.
Effects of Overexposure:SKIN:IRRITATION. INHALATION:IRRITATION OF NOSE,
THROAT & LUNGS; CNS DEPRESSION. INGESTION:MFR GAVE NO INFORMATION
ON MSDS. EYES:IRRITATION.
Medical Cond Aggravated by Exposure:MFR GAVE NO INFORMATION ON MSDS.
* First Aid Measures *
First Aid:IF IRRITATION PERSISTS OR IS SEVERE, GET MEDICAL ATTENTION.
FROM EXPOSURE. AID OR RESTORE BREATHING AS NEEDED. INGESTED:DILUTE
BY DRINK ING A LARGE QUANTITY OF WATER. IMMEDIATELY CONTACT POISON
CONTROL CENTER OR HOSPITAL EMERGENCY ROOM FOR ADDITIONAL TREATMENT
DIRECTIONS.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL,FOAM OR CO2. WATER MAY BE INEFFECTIVE.
USE IT TO COOL FIRE EXPOSED CONTAINERS.
Fire Fighting Procedures:AVOID OPEN FLAMES, SPARKS, PILOT LIGHTS. VAPOR
MAY IGNITE EXPLOSIVELY. SPRAY MIST OR VAPOR EVAPORATING FROM
DEPOSITED FILM IS HEAVIER THAN AIR & MAY FLASH BACK.
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE! DO NOT INCINERATE
RADIATOR, IGNITION SOURCES. DO NOT PUNCTURE.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. SOAK UP WITH
ABSORBENT MATERIAL AND REMOVE TO A CHEMICAL DISPOSAL AREA. PREVENT
ENTRY INTO NATURAL BODIES OF WATER.
Neutralizing Agent:MFR GAVE NO INFORMATION ON MSDS.
*Handling and Storage *
Handling and Storage Precautions:STORE COOL, DRY PLACE. KEEP TIGHTLY
Other Precautions:USE W/ADEQUATE VENTILATION. AVOID BREATHING VAPORS OR
MIST. OPEN WINDOWS, DOORS OR USE EXHAUST FAN TO ENSURE FRESH AIR
ENTRY DURING APPLICATION & DRYING. IF SYMPTOMS DEVELOP, WEAR
RESPIRATORY PROTECTI ON OR LEAVE AREA.
* Physical/Chemical Properties *
HCC:V3
NRC/State Lic Num:NONE
Vapor Density:>1
Evaporation Rate & Reference:<1 (ETHER = 1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE TO OFF-WHITE IN COLOR, MILD TO SLIGHT
ETHEREAL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
(4-3.1)
Hazardous Decomposition Products:MFR GAVE NO INFORMATION ON MSDS.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE I/A/W FEDERAL, STATE/PROVINCIAL & LOCAL
REGULATIONS. EMPTY CONTAINER:MAY CONTAIN EXPLOSIVE VAPORS. DO NOT
CUT,PUNCTURE OR WELD ON OR NEARBY. INCINERATION WILL CAUSE
CONTAINER TO BURST VIOLENTL Y.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:OUTDOORS:USE MECHANICAL FILT RESP WHILE
SPRAYING.RESTRICTED VENTI AREA:USE APPROV CHEM/MECH FILT DESIGNED
TO REMOVE COMBINATION OF PARTICULATES & VAPORS.CONFINED AREAS:USE
APPROVED AIR LINE TYP RESP O R HOODS.
Ventilation:PROVIDE VENTI OF SUFFIC VOL/PTRN TO KEEP AIR CONTAM CONCEN
BEL VALS.EXHAUS FILT SYS TO AVOID ENVIRO CONTAM.IAW EMISS REG
Other Protective Equipment:WEAR CHEM RESIST SHOES.REMOVE/WASH CONTAM
CLOTH BEF REUSE.WEAR RUBB/PLAST APRON.CLEAN H2O SOURCE AVAI FOR
EYE/SKIN FLUSH
Work Hygienic Practices:WASH HANDS BEF EAT/WASHRM USE.SMOKE IN
DESIGNATED SMOKING AREAS ONLY.AVOID REP/PROL SKIN CONTACT.LIQ
PENETR LEATHER-BURN
Supplemental Safety and Health
FIREFIGHT:EQPTM +SCBA SHOULD BE USED TO PROT FIGHTER FRM HAZ COMBUST
PROD.AVOID BURN LIQ SPREAD W/H2O. FIRE/EXPLO:EMERG
CONDITIONS/OVEREXPO MAY CAUSE HEALTH HAZ.SYMPT MAY NOT BE IMMED
APPARENT.GET MED ATTN.VAP MAY IGNITE BY STAT ELECT/FRICSPARKS.VAP
HEAVIER THAN AIR-TRAVEL DISTANCES TO IGN PT/FLASHBACK.KEEP CNTNR
CLSD
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:KAOLIN
Other REC Limits:NONE RECOMMENDED
Ingred Name:CALCIUM CARBONATE
Other REC Limits:NONE RECOMMENDED
Ingred Name:TITANIUM DIOXIDE
Other REC Limits:NONE RECOMMENDED
Ingred Name:ALIPHATIC HYDROCARBON (VM & P NAPHTHA) CONTAINS INGREDS
5,6.
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: <8%
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: <2%
Other REC Limits:NONE RECOMMENDED
INGRED #8.
Other REC Limits:NONE RECOMMENDED
Other REC Limits:NONE RECOMMENDED
Fraction by Wt: NA
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:INHAL:ANESTHETIC.IRRIT RESP
TRACT,ACUTE NERV SYS DEPRESS CHARACTERIZED BY FOLLOWING PROGRESSIVE
STEPS:HEAD,DIZZ,STAGGERING
GAIT,CONFUSION,UNCONSC,COMA,ASPHIXIATION.SKIN/EYE CONTACT:PRIMARY
IRRIT .CHRONIC:OVEREXPO TO MATL/COMPO HAS BEEN SUGGESTED AS CAUSE
OF LUNG DMG,CARDIAC ABNORMALITY.SILICOSIS,CARDIO-PULM IMPAIR
Explanation of Carcinogenicity:PER MSDS:CARCINOGENICITY:IARC. (CONTAINS
CRYSTALLINE SILICA).
Effects of Overexposure:ANESTHETIC,IRRIT RESP TRACT,NERVOUS SYS
DEPRESSION-HEADACHE,DIZZ,STAGGERING
GAIT,CONFUSION,UNCONSC,COMA,ASPHIXIATION. EYE/SKIN IRRIT. LUNG
DAMAGE, CARDIAC ABNORMALITY, SILICOSIS, CARDIO-PULMONARY IMPA
IRMENT.REPORTS ASSOC REP/PROL OCCUP OVEREXPO TO SOLVT W/PERM
BRAIN/CNS DMG.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR.RESTORE BREATHING.TREAT
SYMPTOM.CONSULT DR.SPLASH(EYE):FLUSH IMMED W/LG ATMS OF
CONSULT PHYSICIAN.SPLASH(SKIN):WA SH W/SOAP/WATER.REMOVE CONTAMIN
CLOTH.CONSULT DR IF IRRIT PERSISTS.INGEST:CONSULT DR/POISON CNTRL
CNTR IMMED.TREAT SYMPTOMATICALLY.
* Fire Fighting Measures *
Autoignition Temp:Autoignition Temp Text:NP
Lower Limits:0.9
Upper Limits:NP
Extinguishing Media:FOAM, ALCOHOL FOAM, CO2, DRY CHEMICAL, WATER FOG.
OSHA:CLASS IB, DOT FLAMMABLE LIQUID.
Fire Fighting Procedures:H2O MAY BE INEFFECTIVE;IF USE,FOG NOZZ
PREFER.H2O MAY BE USED TO COOL CLSD CNTNR-PREVENT PRESSURE
BUILDUP/AUTO-IGN WHEN EXPO TO EXTREME HEAT.FULL PROTECT(SUPPL)
Unusual Fire/Explosion Hazard:ISOLATE FROM HEAT/ELECTR EQPMT/SPARKS/OPN
FLAME.APPLICATION TO HOT SURFACES REQUIRE SPEC PRECAUT.CLSD CNTNR
MAY EXPLO WHEN EXPO TO EXTREME HEAT.DURING (SUPPLE)
* Accidental Release Measures *
Spill Release Procedures:LIMIT SPREAD OF SPILL/LEAK.REMOVE ALL SOURCES
OF IGNITION.SOAK UP W/INERT ABSORBANT MATL.USE NON-SPARKING TOOLS
WHEN REMOVING WET ABSORBENT.SEE OTHER MSDS SECTION FOR REQUIRED
PROTECTIVE MEASURES.KEEP MATL OUT OF SEWERS &/OR DRAINS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM EXTREME HEAT/FIRE/OPEN
Other Precautions:DONT HNDLG TIL MFG SAF PRECAUT READ/UNDERSTOOD.STORE
IN WELL VENTI AREA.KEEP DR OUT OF DIRECT SUN/TIGHT
/UPRIGHT.DONT STORE/USE NEAR HEAT/SPARK/OPN FLAME.GROUND/BOND
WHEN POUR.DONT USE PRESS TO EM PTY-NOT PRESS VESS.
* Physical/Chemical Properties *
HCC:F3
Melt/Freeze Pt:M.P/F.P Text:NP
Decomp Temp:Decomp Text:NP
Vapor Pres:NP
Vapor Density:>AIR
Spec Gravity:NP
pH:NP
Viscosity:NP
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:NP
Appearance and Odor:WHITE PAINT
Corrosion Rate:NP
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
PEROXIDES OR STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT,SPARKS,OPEN FLAME.
Hazardous Decomposition Products:MAY PRODUCE FUMES WHEN HEAT TO
DECOMPO,AS IN WELD OR FIRE.FUMES MAY CONTAIN:CO,CO2,&VARIOUS OTHER
HYDROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:DISPO OF IAW ALL LOC,STATE,FED REGS.APPROVED
LANDFILL,APPROVED HAZ WASTE SITE,INCINERATION.CHEM SUBJ TO REPORT
CLEANED.FOLLOW ALL PRECA UT W/EMPTY DR AS IF FULL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE A NIOSH APPROVED RESPIRABLE FUME RESPIRATOR
WHEN WELDING IN CONFINED SPACES & WHENEVER FUME CONCS EXCEED
APPLICABLE LIMITS FOR ZIRCONIUM, TUNGSTEN OR OTHER WELDING FUMES.
Ventilation:GEN &/OR LOC EXHST AT WELDING ARC REC. IF SUCH EQUIP IS NOT
AVAIL, USE NIOSH APPRVD RESPS AS SPECIFIED ABOVE. AIR SAMPLING IF
NEC TO DETERMINE CORRECTIVE MEAS.
OR (SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
SHOWER . FOOTWEAR:SUITABLE FOR METAL WORKING. CLOTHING:DARK,
Work Hygienic Practices:OPERATOR TRAINED TO AVOID ELECTRICAL SHOCK & UV
RAY EXPOSURE.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:DENNIS WILSON
* Composition/Information on Ingredients *
Ingred Name:TUNGSTEN
OSHA PEL:N/K
ACGIH TLV:1 MG/M3;3 STEL
Ingred Name:ZIRCONIUM; (ZIRCONIUM (DRY))
Fraction by Wt: 1%
OSHA PEL:5 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION OF FUMES GENERATED DURING
WELDING. MOST STUDIES HAVE FOUND TUNGSTEN TO BE TOXICOLOGICALLY
INERT. SIGNS AND SYMPTOMS OF EXPOSURE: BREATHING DIFFICULTY,
HEADACHE, NAUSEA, DRYNESS OR IRRITATIO N OF NOSE, THROAT, EYES.
BURNING SENSATION OF SKIN OR EYES. UNCONSCIOUSNESS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:RESPIRATORY PROBLEMS, ERYTHMAS.
* First Aid Measures *
First Aid:INGEST:CALL MD IMMEDIATELY . EYES:IMMEDIATELY FLUSH W/POTABLE
INHAL:REMOVE TO FRESH AIR. IF BREATHING IMPAIRED, ASSISTED RESPIR
ATION MAY BE REQUIRED. SKIN:TREAT U.V. EXPOSURE SIMILAR TO SEVERE
SUNBURN, SEEK MEDICAL ATTENTION!
* Fire Fighting Measures *
Extinguishing Media:MEDIA SUITABLE FOR SURROUNDING FIRE . NOT
FLAMMABLE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:WELDING ARC & SPARKS CAN IGNITE
COMBUSTIBLE MATERIALS, ZIRCONIUM IS DANGEROUS IN FORM OF DUST, BY
CHEMICAL REACTION TO AIR, WHEN EXPOSED TO HEAT OF FLAME/CHEMICAL
CUTTING" PUBLISHED BY AMERICAN WELDING SOCIETY.
* Accidental Release Measures *
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Other Precautions:NONE.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:SUPP DATA
Solubility in Water:NOT SOLUBLE
Appearance and Odor:SOLID, GRAY METAL CYLINDER; NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Hazardous Decomposition Products:WELDING FUMES (OXIDES OF METAL BEING
WELDED & GASES, SUCH AS CARBON MONOXIDE, OZONE & OXIDES OF
NITROGEN) DEPENDING ON PROCESS & METAL BEING WELDED. SOME LOSS OF
ELECTRODE WILL OCCUR.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE & FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NOT REQUIRED WHEN SUFFICIENT VENTILATION IS
PROVIDED.
Ventilation:GOOD ENCLOSURE AND LOCAL VENTILATION SHOULD BE PROVIDED.
Other Protective Equipment:EYE WASH & DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA . WEAR LAB COAT OR APRON.
INSIDE. WASH HANDS AFTER USING & BEFORE EATING. DO NOT EAT, SMOKE
OR DRINK IN WORK AREA.
Supplemental Safety and Health
PHYSICAL/CHEMICAL CHARACTS: SOLUBILITY IN WATER: UNPOLYMERIZED MATERIAL
SOLUBLE IN ANY PROPORTIONS.
* Product Identification *
CAGE:1ENU5
CAGE:1ENU5
* Composition/Information on Ingredients *
Fraction by Wt: </= 0.2%
OSHA PEL:0.3 MG/M3
Ingred Name:SODIUM AZIDE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: MAY CAUSE DAMAGE TO THE CENTRAL
NERVOUS SYSTEM. CHRONIC: MAY CAUSE NEUROPATHY SUCH AS INCREASED
SWEATING, TINGLING AND WEAKNESS IN THE HANDS AND FEET. UNSTEADY
GAIT AND DECREASED REFLEXES MAY A LSO BE OBSERVED. EITHER ACUTE OR
CHRONIC EXPOSURE MAY LEAD TO WEAK OR ABSENT REFLEXES. AN EARLY SIGN
OF OVEREXPOSURE IS PEELING OF SKIN OF FINGERTIPS.
REASONABLY ANTICIPATED TO BE HUMAN CARCINOGEN. ANIMAL: CNS TOXIN,
NEOPLASMS.
Effects of Overexposure:INHALATION: AIRBORNE ACRYLAMIDE IS READILY
ABSORBED THROUGH THE LUNG AND OVEREXPOSURE WILL PRODUCE SIGNS OF
NEUROPATHY. CONTACT WITH EYES: SODIUM AZIDE: MAY CAUSE IRRITATION.
ACRYLAMIDE: MAY CAUSE CON JUNCTIVAL IRRITATION. ABSORBED THROUGH
SKIN: ACRYLAMIDE: READILY ABSORBED THROUGH SKIN. MAY CAUSE DAMAGE
TO THE CENTRAL NERVOUS SYSTEM. INGESTION: NEUROTOXICITY FROM A
SINGLE INGESTION CAN RESULT BUT IS MORE LIKELY TO OCCUR AFTER
REPEATED INGESTION OF SMALL AMOUNTS OVER A PERIOD OF SEVERAL DAYS
OR WEEKS.
* First Aid Measures *
First Aid:EYES: IMMEDIATELY FLUSH WITH LARGE AMOUNTS OF WATER FOR AT
IMMEDIATE MED ATTN. SKIN: IMMEDIATELY REMOVE ANY CONTAMINATED
CLOTHING WITHOUT DELAY. DO NOT RE-USE CONTAMINATED CLOTHING
WITHOUT RE-LAUNDERING. WASH SKIN WITH SOAP OR MILD DETERGENT &
PERSISTS. INHAL: REMOVE TO F RESH AIR. IF NOT BREATHING GIVE CPR.
CONSULT MED PERSONNEL. IF BREATHING IS DIFFICULT, GIVE OXYGEN.
INGEST: GIVE TWO GLASSES OF WATER & THEN INDUCE VOMITING. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSC IOUS PERSON. GET MED ATTN
IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:NOT COMBUSTIBLE. USE WHATEVER IS NEEDED TO PUT OUT
SURROUNDING FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT APPLICABLE.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA OF SPILL ABSORB LIQUID SPILLS
WITH A DRY INERT ABSORBENT MATERIAL. DO NOT PERMIT LIQUID SPILLS TO
DRY. CONTAINERIZE ABSORBED MATERIAL FOR DISPOSAL IN AN APPROVED
WASTE FACILITY.
*Handling and Storage *
Handling and Storage Precautions:RECOMMENDED STORAGE CONDITIONS:
KEEP AWAY FROM HEAT SOURCES.
Other Precautions:PROTECTIVE MEASURES DURING MAINTENANCE OF
AND NIOSH APPROVED RESPIRATORY EQUIPMENT MUST BE WORN.
* Physical/Chemical Properties *
Vapor Pres:SAME AS WATER
Spec Gravity:1.0
Solubility in Water:(SUPP DATA)
Appearance and Odor:CLEAR GEL AND PACKAGING BUFFER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING AND REDUCING AGENTS, BRASS, ALUMINUM, COPPER, IRON AND
PEROXIDES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE, CARBON DIOXIDE, AMMONIA AND/OR OXIDES OF NITROGEN.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
* Toxicological Information*
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE DONE I/A/W ALL APPLICABLE
FEDERAL, STATE & LOCAL REGULATIONS ON SPILL REPORTING, WASTE
HANDLING & WASTE DISPOSAL.
* MSDS Transport Information *
Transport Information:PROPER SHIPPING NAME/HAZARD CODE-ALKYLAMINES,
CONTAINS: CYCLOHEXYLAMINE, DIETHYLAMINOETHANOL, MORPHOLINE.
ECOLOGICAL INFO (CONT): ON NO MO RTALITY OR ABNORMAL EFFECTS.
NO MORTALITY OR ABNORMAL EFFECTS. TOXIC ITY RATING: SLIGHTLY TOXIC.
INFO (CONT): EXTREMELY IRRIT (CORR). SKIN SENSITIZATION:
CYCLOHEXYLAMINE CAN CAUSE SENSITIZATION (CONTACT NEHC FOR
ADDITIONAL INFORMATION)
* Regulatory Information *
SARA Title III Information:THIS PRODUCT CONTAINS THE FOLLOWING TOXIC
State Regulatory Information:
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR A POSITIVE PRESSURE SUPPLIED AIR
HISTORY OF LUNG/BREATHING PROBLEMS/REACTION TO ISOCYANATES
SHOULDN'T USE/BE EXPOSED TO PRODUCT.
Ventilation:SUFFICIENT IN VOLUME & PATTERN TO KEEP CONTAMINANTS BELOW
APPLICABLE OSHA LIMITS.
Other Protective Equipment:COVERALLS.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING & BEFORE
EATING/SMOKING.
Supplemental Safety and Health
CONTAINER & DISPOSE OF MATERIAL.
* Product Identification *
Preparer's Name:T R LOUER
* Composition/Information on Ingredients *
Ingred Name:SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH
Ingred Name:ETHYL 3-ETHOXYPROPIONATE, PROPANOIC ACID, 3-ETHOXY-, ETHYL
Ingred Name:ISOPROPANOL (ISOPROPYL ALCOHOL), 2-PROPANOL, DIMETHYL
Ingred Name:LIGHT ALIPHATIC NAPHTHA, VM & P NAPHTHA, LACOLENE
Ingred Name:VOLATILE ORGANIC CONTENT: 6.6 LBS/GAL
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INHALATION: MAY CAUSE NOSE & THROAT
IRRITATION. EXPOSURE TO ISOCYANATES MAY CAUSE RESPIRATORY
SENSITIZATION & MAY CAUSE A DECREASE IN LUNG FUNCTION WHICH MAY BE
PERMANENT. EYES: IRRITATION/BURNING. SK IN: IRRITATION &
DERMATITIS. REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE
PERMANENT BRAIN & CNS DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:GI DISTRESS, IRRITATION, EYE WATERING,
HEADACHES, NAUSEA, DIZZINESS, LOSS OF COORDINATION, BURNING,
DISCOMFORT.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. EYES: FLUSH W/PLENTY OF
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:CC
Lower Limits:0.2
Extinguishing Media:WATER SPRAY, FOAM, CO2, DRY CHEMICAL.
Fire Fighting Procedures:USE FULL PROTECTIVE EQUIPMENT & SCBA. WATER
FROM FOG NOZZLES MAY BE USED TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:WHEN HEATED ABOVE THE FLASHPOINT, EMITS
FLAMMABLE VAPORS, WHEN MIXED W/AIR CAN BURN/BE EXPLOSIVE. FINE
MISTS/SPRAYS MAY BE FLAMMABLE AT TEMPS < THE FLASHPOINT.
* Accidental Release Measures *
Spill Release Procedures:DON'T BREATHE VAPORS. DON'T GET IN EYES/ON
SKIN. WEAR A POSITIVE PRESSURE SUPPLIED AIR VAPOR/PARTICULATE
OF IGNITION. ABSORB W/INERT MATERIAL. VENTILATE AREA. (SEE SUPP)
*Handling and Storage *
Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS & FLAME.
CLOSE CONTAINER AFTER EACH USE. GROUND CONTAINERS WHEN POURING.
Other Precautions:DON'T SAND, FLAME CUT, BRAZE/WELD DRY COATING W/O A
NIOSH/MSHA APPROVED RESPIRATOR/APPROPRIATE VENTILATION. DON'T
BREATHE VAPORS. DON'T PERMIT ANYONE W/O PROTECTION IN THE PAINTING
AREA.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:LESS THAN ETHER
Solubility in Water:MISCIBLE
Percent Volatiles by Volume:(SUPP)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE REASONABLY FORSEEABLE.
Hazardous Decomposition Products:CO, CO2, SMOKE.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE/DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS. DON'T ALLOW MATERIAL TO CONTAMINATE GROUND WATER
SYSTEMS. DON'T INCINERATE IN CLOSED CONTAINERS. FLAMMABLE LIQUID
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:DEVICE APPROVED BY NIOSH/MSHA.
Ventilation:LOCAL EXHAUST PREFERABLE. MECHANICAL EXHAUST ACCEPTABLE.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:AVOID BREATHING VAPOR OR SPRAY MIST. AVOID
CONTACT WITH SKIN OR EYES.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:HOUSE & TRIM. EVAP RATE:SLOWER THAN ETHER
(BUTYL ACETATE=1).
* Product Identification *
CAGE:0D4B9
CAGE:0D4B9
* Composition/Information on Ingredients *
Ingred Name:TITANIUM OXIDE; (TITANIUM DIOXIDE)
Ingred Name:CLAY (KAOLIN); ALUMINUM SILICATE
Ingred Name:IRON (III) OXIDE; (RED IRON OXIDE)
Fraction by Wt: 5.4%
ACGIH TLV:5 MG/M3 (FE)
Ingred Name:NEPHELINE SYENITE
Fraction by Wt: 3.3%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:HYDRATED IRON OXIDE; (YELLOW IRON OXIDE)
Fraction by Wt: 2%
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:AMMONIA (SARA III)
Fraction by Wt: <0.1%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: IN A CONFINED AREA VAPORS IN
HIGH CONCENTRATION ARE ANESTHETIC. IRRITANT TO UPPER RESPIRATORY
SYSTEM. LIGHTHEADEDNESS & STAGGERED GAIT. CHRONIC PROBLEMS WITH
RESPIRATORY SYSTEM MAY BE AGGRAVATE D BY EXPOSURE TO VAPORS.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:CHRONIC PROBLEMS WITH RESPIRATORY
SYSTEM MAY BE AGGRAVATED BY EXPOSURE TO VAPORS.
* First Aid Measures *
First Aid:INGESTION: CALL MD IMMEDIATELY . INHALATION: REMOVE FROM
EXPOSURE. RESTORE BREATHING. KEEP WARM & QUIET. SKIN: WASH FROM
MINUT ES. GET MEDICAL AID. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:NON-COMBUSTIBLE. FOR DRY SOLIDS USE WATER, FOAM,
CARBON DIOXIDE, DRY CHEMICALS.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . WATER MAY BE USED TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS EXPOSED TO EXTREME HEAT
MAY RUPTURE DUE TO PRESSURE BUILD-UP. CONTENTS MAY SPATTER IF
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE &
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:DOL STORAGE CATEGORY 3B.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
HCC:V4
Vapor Density:HVR/AIR
Evaporation Rate & Reference:SUPDAT
Solubility in Water:INSOLUBLE
Appearance and Odor:COLORED PIGMENTED LIQUID WITH SLIGHT AMMONIA ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NO HAZARDOUS REACTIONS ARE EXPECTED UNDER NORMAL USE.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:INCINERATE IN APPROVED FACILITY. DO NOT
INCINERATE CLOSED CONTAINERS. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE & LOCAL REGULATIONS REGARDING POLLUTION.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:AS REQUIRED
Ventilation:AS REQUIRED
Other Protective Equipment:AS REQUIRED
Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:DALE M. OREM
* Composition/Information on Ingredients *
Ingred Name:NON-HAZARDOUS FOR INGREDIENTS
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Explanation of Carcinogenicity:NONE
* Fire Fighting Measures *
Extinguishing Media:WATERSPRAY
Unusual Fire/Explosion Hazard:ANY ORGANIC POWDER CAN BE POTENTIALLY
EXPLOSIVE IF DISBURSED IN AIR IN CERTAIN CONCENTRATIONS. THESE
CONCENTRATIONS HAVE NOT BEEN DETERMINED.
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP.
*Handling and Storage *
Other Precautions:USE OF THIS PRODUCT IN ACCORDANCE W/MANUFACTURER'S
INSTRUCTIONS SHOULD NOT RESULT IN EXPLOSIVE MIXTURES BEING FORMED.
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:LIGHT TAN BROWN POWDER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF W/NORMAL LABORATORY TRASH. FOLLOW ALL
FEDERAL, STATE, & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:FOR CONDITIONS OF USE WHERE EXPOSURE TO DUST IS
APPARENT, NIOSH/MSHA APPROVED DUST/MIST RESPIRATOR MAY BE WORN. FOR
EMERGENCIES, A NIOSH/MSHA APPRVD SCBA MAY BE NECESSARY.
Ventilation:LOC EXHST SYS WHICH CAPTURES CONTAMINANT AT ITS SOURCE IS
RECOM TO PVNT DISPERSION OF CONTAMINANT INTO WORKROOM AIR.
Other Protective Equipment:CLEAN BODY-COVERING CLTHG. EYE WASH FOUNTAIN
& QUICK-DRENCH FACILITIES IN WORK AREA.
Work Hygienic Practices:CONTACT LENSES SHLD NOT BE WORN WHEN WORKING
W/THIS MATL. WASH CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
EFTS OF OVEREXP: SEVERE CONTACT CAN CAUSE DESTRUCT OF TISSUE. CHRONIC
EXPOSURE: NO INFORMATION FOUND. FIRST AID PROC: EYE: WASH W/PLENTY
CCAS. GET MED ATTN IMMED.
* Product Identification *
Product ID:SODIUM SULFIDE
* Composition/Information on Ingredients *
OSHA PEL:SEE INGREDIENT NAME
ACGIH TLV:SEE INGREDIENT NAME
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
IN AIR) HYDROGEN SULFIDE WHICH MAY ACCUM IN CONFINED SPACES DUE TO
DECOMP OF SODIUM SULFIDE OR FROM ITS RXN W/ACIDS. SYMPTOMS INCLUDE
PAINFUL CONJ/HDACH/NAUS/DIZZ /COUGHING &, IN EXTREME CASES, PULM
EDEMA & POSS DEATH. INGEST: CORROSIVE, TOXIC. SODIUM SULFIDE IS A
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: STRONG BASE & CAN CAUSE SEV BURNS ON
MUC MEMB. HYDROLYSIS BY GASTRIC FLUIDS RELS TOX HYDROGEN SULFIDE.
SYMPS/EFTS ARE SIMILAR TO THOSE UNDER INHAL. SKIN: IRRITANT. CONT
CAN PRDCE SERIOUS CAU STIC BURNS W/PAINFUL INFLAMM & POSS DESTRUCT
OF TISS. EYES: IRRITANT. INFLAMM/TEARING/PAIN MAY BE EXPECTED.(SUPP
DATA)
Medical Cond Aggravated by Exposure:PERSONS W/PRE-EXISTING SKIN
DISORDERS OR EYE PROBLEMS, OR IMPAIRED LIVER, KIDNEY OR RESPIRATORY
FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
BRTHG IS DFCLT, GIVE O*2. CALL MD. INGEST:GIVE SEV GLASSES OF
WATER/MILK, IF AVAIL, TO DRINK. VOMIT MAY OCCUR SPONT, BUT DO NOT
INDUCE! NEVE R GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MED ATTN
REMOVING CONTAMD CLTHG/SHOES & WASH BEFORE REUSE. CALL MD IMMED.
(SUPP DATA)
* Fire Fighting Measures *
Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING
SURROUNDING FIRE.
Fire Fighting Procedures:NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A HAZARD.
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. CLEAN-UP PERS
REQUIRE PROT CLTHG & RESP PROT FROM DUST. SPILLS: PICK UP & PLACE
IN A SUITABLE CONTR FOR RECLAMATION OR DISPOSAL IN A METHOD THAT
DOES NOT GENERATE DUST.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED CONTR.
PROTECT CONTR FROM PHYSICAL DAMAGE. STORE IN AN EXPLOSION-PROOF
REFRIGERATOR. ISOLATE FROM ACIDS AND ALKALIES.
Other Precautions:DANGER! MAY BE FATAL IF SWALLOWED/INHALED. CORROSIVE.
CAUSES BURNS. DO NOT GET IN EYES. AVOID BRTHG GAS. AVOID CONTACT
W/EYES, SKIN & CLTHG. KEEP CONTAINER CLOSED. USE ONLY W/ADEQUATE
VENTILATION.
* Physical/Chemical Properties *
HCC:C2
Appearance and Odor:WHITE CRYSTALS WITH SULFIDE ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
ACIDS, OXIDANTS.
Stability Condition to Avoid:DARKENS ON EXPOSURE TO AIR OR LIGHT.
SODIUM HYDROXIDE FORMS IN AQUEOUS SOLUTIONS.
Hazardous Decomposition Products:HYDROGEN SULFIDE AT ROOM TEMPERATURE,
OXIDES OF SULFUR AND SODIUM UNDER FIRE CONDITIONS.
* Disposal Considerations *
Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECLAMATION MAY BE
DISPOSED IN A RCRA APPRVD HAZ WASTE FACILITY. DO NOT CONTACT
W/ACIDS. DO NOT HANDLE W/BARE HANDS. ENSURE COMPLIANCE W/LOCAL,
STATE AND FEDERAL REGULATIO NS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF WELL VENTED, RESPIRATOR MAY NOT BE REQ'D.
RESTRICTED VENT, NIOSH CHEM CARTRIDGE RSPRTR. CONFINED AREA,
NIOSH/MSHA AIR SUPPLIED RSPRTR. TLV'S EXCEEDED, FITTED NIOSH/MSHA
Ventilation:LOCAL EXHAUST (VOL/PATTRN) TO MAINTAIN EXPOSURE BELOW
TLV/PEL.
Other Protective Equipment:EYEWASH FACILITY, SAFETY SHOWER.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:W A ELLISON
* Composition/Information on Ingredients *
(LFL 1.0; UFL 7.0)
Other REC Limits:NONE SPECIFIED
Ingred Name:SOLVENT NAPHTHA, LIGHT AROMATIC (SOLVENT)
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:N-BUTYL ACETATE (SOLVENT) (LFL 1.7; UFL 7.6) (VAPOR
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:ETHYL BENZENE (SOLVENT) (SARA III) (VAPOR PRESSURE 1 MM HG
Fraction by Wt: <5%
Other REC Limits:NONE SPECIFIED
Ingred Name:TITANIUM DIOXIDE (PIGMENT)
Other REC Limits:NONE SPECIFIED
Ingred Name:TRIMETHYL BENZENE
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Ingred Name:1,2,4-TRIMETHYLBENZENE (SARA III)
Fraction by Wt: 5%
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:INGEST: ASPIRATION OF MAT'L INTO LUNG
MAY CAUSE CHEMICAL PNEUMONITIS WHICH CAN BE FATAL. INHAL:
NOSE/THROAT IRRITATION. HIGH CONCENTRATION: CENTRAL NERVOUS SYSTEM
DEPRESS. EYE: SEVERE IRRIT, CORNEAL D AMAGE. SKIN: DEFATTING &
IRRITATION. OVEREXPOSURE: LIVER, KIDNEY & BLOOD DAMAGE. PERM BRAIN
& NERVOUS SYS DAMAGE. *
Explanation of Carcinogenicity:NO
Effects of Overexposure:INGEST: NAUSEA, VOMITING. INHAL: HEADACHE,
DIZZINESS, NAUSEA, CONFUSION.
* INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING &
INHALING CONTENTS MAY BE HA RMFUL OR FATAL. RAT: INCREASED
BENIGN/MALIGNANT LUNG TUMORS AT HIGH EXPOSURE LEVELS.
* First Aid Measures *
First Aid:INGEST: DON'T INDUCE VOMIT. CALL POISON CNTRL CTR, HOSP EMERG
RM/DR IMMED. INHAL: REMOVE TO FRESH AIR IMMED. BREATH STOPPED, GIVE
ARTIF RESPIRATION. KEEP WARM, QUIET. GET MED AID IMMED. EYE: FLUSH
CLOTHES. WASH W/SOAP & WATER. NOTES TO PHYSICIAN: DIRECT TREATMENT
REQ'D FOR OVEREXPOSURE AT CONTROL OF SYMPTOMS & CLINICAL
CONDITIONS.
* Fire Fighting Measures *
Lower Limits:1.0
Upper Limits:7.6
Extinguishing Media:USE NFPA CLASS B EXTINGUISHERS (CO2, ALL PURPOSE
DRY CHEMICAL/ALCOHOL FOAM). POLYMER FOAM IS PREFERRED FOR LARGE
FIRES.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE, MAY USE (PREFER FOG
NOZZLE) TO COOL EXPOSED CNTNRS TO PREVENT PRESSURE BLDUP & AUTO
IGNITION/EXPLOSION WHEN EXPOSED TO EXTREME HEAT.
Unusual Fire/Explosion Hazard:DURING EMERGENCY CONDITIONS, OVEREXPOSURE
TO DECOMPOSITION PRODUCTS MAY CAUSE A HEALTH HAZARD. SYMPTOMS MAY
NOT BE IMMEDIATELY APPARENT. GET MEDICAL ATTENTION.
* Accidental Release Measures *
Spill Release Procedures:WEAR RESPIRATOR, EYE, HAND, BODY PROTECT FOR
SIZE OF SPILL/EXPOSURES ENCOUNTERED. EVACUATE SPECTATORS. ELIM
IGNIT SOURCES. DIKE/CONTAIN SPILL W/INERT MAT'L. TRANSFER LIQ TO
COVERED METAL CONTAINERS/RE MOVE W/ABSORB. USE NON-SPARKING TOOLS.
**
Neutralizing Agent:N/K ** PREVENT CONTAMINATION OF SEWERS, STREAMS,
GROUNDWATER.
*Handling and Storage *
INTERNALLY. CLOSE CONTAINER AFTER EACH USE.
Other Precautions:EMPTY CONTAINERS MUST NOT BE WASHED AND REUSED FOR
ANY PURPOSE. CONTAINERS SHOULD BE GROUNDED AND BONDED TO THE
RECEIVING CONTAINER. DO NOT WELD, BRAZE OR CUT ON EMPTY CONTAINER.
NEVER USE PRESSURE TO EMPTY. DRUM IS NOT A PRESSURE VESSEL.
* Physical/Chemical Properties *
HCC:F2
Vapor Density:> AIR.
Spec Gravity:1.1
pH:4-7
Evaporation Rate & Reference:SLOWER THAN DIETHYL ETHER
Solubility in Water:SLIGHT IN WATER.
Appearance and Odor:LIQUID, SOLVENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS OR ALKALINE MATERIALS. OXIDIZING MATERIALS.
OF IGNITION.
Hazardous Decomposition Products:BURNING, INCLUDING WHEN HEATED BY
WELDING OR CUTTING, WILL PRODUCE SMOKE, CARBON MONOXIDE, AND CARBON
DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN ACCORDANCE W/FED, STATE, LOCAL LAWS.
INCINERATE IN EPA PERMITTED FACILITY. DON'T INCINERATE CLSD CNTNRS.
OBSERVE PRECAUTIONS FOR DISPOSAL IN HAZARDOUS WASTE LANDFILL.
DISPOSE ONLY IN ACCORD ANCE WITH FEDERAL, STATE & LOCAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:ANY CHEMICAL CARTRIDGE RESPIRATOR WITH
CARTRIDGES PROVIDING PROTECTION AGAINST MERCURY. ANY SUPPLIED-AIR
RESPIRATOR; ANY SELF-CONTAINED BREATHING APPARATUS.
Ventilation:PROVIDE SUFFICIENT GENERAL/LOCAL EXHAUST VENTILATION IN
PATTERN/VOLUME TO CONTROL INHALATION EXPOSURES BELOW OSHA'S PEL.
Other Protective Equipment:APPROPRIATE IMPERVIOUS CLOTHING AND
EQUIPMENT TO PREVENT SKIN CONTACT.
Work Hygienic Practices:MAINTAIN EYE WASH AND QUI
Supplemental Safety and Health
THE INFORMATION IN THIS MSDS IS FURNISHED FOR MERCURY. USER OF THIS
MSDS SHOULD TAKE INTO ACCOUNT THIS ITEM HAVE A VERY SMALL AMOUNT OF
MERCURY WHICH IS IN A THERMOMETER. THIS INFORMATION CAN BE USED IN
AREAS WHICH APPLY TO THE USE OF THE THERMOMETER.
* Product Identification *
Product ID:METALLIC MERCURY
CAGE:0SDN9
CAGE:0SDN9
* Composition/Information on Ingredients *
Ingred Name:MERCURY (SARA III)
Other REC Limits:NONE SPECIFIED
OSHA PEL:S, C, 0.1 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: SKIN:IRRITATION. ABSORBED
THROUGH SKIN CAUSING ANURIA. EYE:IRRITATION, CORNEAL INJURY OR
BURNS. INGESTION: METALLIC MERCURY GENERALLY SHOWS NO EFFECT. DEATH
MAY OCCUR. INHALATION: DYSPNEA, COUG H, FEVER, NAUSEA & VOMITING,
DIARRHEA, STOMATITIS, SALIVATION & METALLIC TASTE. CHRONIC: CNS
DISTURBANCES.
Explanation of Carcinogenicity:MERCURY IS NOT LISTED BY IARC, NTP, OR
OSHA AS A CARCINOGEN.
Effects of Overexposure:TREMORS, CONVULSIONS & OTHER CNS DISTURBANCES,
PNEUMONITIS, CHEST PAINS, DYSPNEA, COUGHING, STOMATITIS, GINGIVITIS
AND LOOSENING OF TEETH, SALIVATION, LOSS OF MEMORY, METALLIC TASTE,
DIZZINESS, CLUMSI NESS, SLURRED SPEECH, DIARRHEA, PAIN & NUMBNESS
IN EXTREMITIES, NEPHRITIS, ANXIETY, HEADACHE, WEIGHT LOSS, AND
INSOMNIA.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF
ALCOHOLISM, CHRONIC KIDNEY DISEASE OR KNOWN ALLERGY TO MERCURY MAY
BE AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING GIVE
CPR/OXYGEN. GET MEDICAL ATTENTION. EYE: IMMEDIATELY FLUSH EYES WITH
ATTENTION. S KIN: REMOVE CONTAMINATED CLOTHING. WASHSKIN WITH
PLENTY OF SOAP & WATER. INGESTION: GET IMMEDIATE MEDICAL ATTENTION.
GIVE TWO TO FOUR GLASSES OF WATER, AND INDUCE VOMITING BY TOUCHING
BACK OF THROAT.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:SMALL FIRE: DRY CHEMICAL, CARBON DIOXIDE, HALON,
WATER SPRAY OR FOAM. LARGE FIRE: WATER SPRAY, FOG OR FOAM.
Fire Fighting Procedures:MOVE CONTAINERS FROM AREA IF POSSIBLE. COOL
CONTAINERS EXPOSED TO FLAMES WITH WATER FROM THE SIDE UNTIL FIRE IS
OUT. STAY UPWIND.
Unusual Fire/Explosion Hazard:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO
HEAT OR FLAME.
* Accidental Release Measures *
Spill Release Procedures:SMALL SPILL: TAKE UP WITH SAND OR OTHER
ABSORBENT MATERIAL AND PLACE INTO CONTAINERS FOR LATER RECLAMATION.
FOR LARGE SPILLS, DIKE FAR AHEAD OF SPILL. ISOLATE HAZARD AREA AND
DENY ENTRY.
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLE
MATERIALS. STORE IN PLASTIC, GLASS, OR STEEL CONTAINERS WITH TIGHT
FITTING SEALS. STORE IN COOL, WELL VENTILATED AREA.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
* Physical/Chemical Properties *
HCC:Z2
Vapor Density:7.0
Solubility in Water:NEGLIGIBLE
Appearance and Odor:ODORLESS, SILVERY LIQUID WITH A METALLIC LUSTER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ALUMINUM, AMINES, AMMONIA, BORON, BROMINE, METHYL AZIDE, OXALIC ACID,
NITOMETHANE, COPPER AND ALLOYS.
Stability Condition to Avoid:ELEVATED TEMPERATURES AND OPEN FLAME.
Hazardous Decomposition Products:TOXIC VAPORS
* Disposal Considerations *
Waste Disposal Methods:SCRAP MERCURY CAN BE RECLAIMED. DISPOSAL MUST BE
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE NORMALLY REQUIRED.
Ventilation:NONE NORMALLY REQUIRED.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. INDUSTRIAL TYPE
WORK CLOTHING AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER MIXING WITH ELECTROLYTE
AND BEFORE EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
ALTHOUGH BOTTLED DISTILLED WATER IS NORMALLY NOT HAZARDOUS, THIS
BATTERY WATER IS USED IN LEAD ACID BATTERIES WHICH CONTAIN
HAZARDOUS SULFURIC ACID ELECTROLYTE. CONSULT YOUR MSDS FOR THE
BATTERY OR SU LFURIC ACID ELECTROLYTE FOR ADDITIONAL SAFETY AND
HEALTH INFORMATION.
* Product Identification *
Product ID:DISTILLED WATER
Preparer's Name:DGSC-SSH
CAGE:0A5A0
CAGE:0A5A0
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:NONE
Explanation of Carcinogenicity:WATER IS NOT LISTED BY IARC, NTP OR OSHA
AS A CARCINOGEN, MUTAGEN, TERATOGEN OR NEUROTOXIN.
Effects of Overexposure:WATER MAY CAUSE DEATH BY DROWNING.
Medical Cond Aggravated by Exposure:NONE KNOWN
* First Aid Measures *
First Aid:INHALATION(ASPIRATED LIQUID): GIVE MOUTH-TO- MOUTH
RESUSCITATION IF NOT BREATHING. GIVE OXYGEN IF BREATHING IS
DIFFICULT. GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
* Accidental Release Measures *
Spill Release Procedures:IF UNUSED WATER IS SPILLED, MOP UP OR FLUSH TO
SEWER.
Neutralizing Agent:NONE
*Handling and Storage *
Handling and Storage Precautions:USE CARE WHEN USING IN LEAD-ACID
BATTERIES WHICH CONTAIN HAZARDOUS SULFURIC ACID.
Other Precautions:NONE
* Physical/Chemical Properties *
HCC:N1
Vapor Density:0.6
Spec Gravity:1.0
pH:7
Evaporation Rate & Reference:1 (WATER=1)
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQUID. NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MOISTURE SENSITIVE COMPOUNDS
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:NONE NORMALLY REQUIRED FOR NEW MATERIAL.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Ventilation:MECHANICAL
Other Protective Equipment:RUBBER APRON
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM FORMALDEHYDE BISULFITE
Ingred Name:TRIETHYLENE GLYCOL
Ingred Name:HYDROQUINONE (SARA III)
OSHA PEL:2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
* Hazards Identification *
Effects of Overexposure:NA
* First Aid Measures *
First Aid:IMMEDIATELY FLUSH CONTACTED AREAS WITH WATER. CONSULT
PHYSICIAN IF SOLUTION GETS INTO EYES. MAY CAUSE DERMATITIS TO
SENSITIVE INDIVIDUALS.
* Fire Fighting Measures *
Flash Point:NA
Extinguishing Media:NA
Fire Fighting Procedures:NA
Unusual Fire/Explosion Hazard:NA
* Accidental Release Measures *
Spill Release Procedures:USE ABSORBENT MATERIAL TO PICK UP. STORE IN
D.O.T. APPROVED DRUMS.
*Handling and Storage *
Handling and Storage Precautions:ORDINARY PRECAUTIONS. AVOID SKIN
CONTACT.
Other Precautions:NOT TO BE TAKEN INTERNALLY. KEEP FROM REACH OF
CHILDREN.
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:NA
Vapor Pres:NA
Vapor Density:NA
Spec Gravity:NA
Solubility in Water:NA
Appearance and Odor:LIGHT YELLOW TO CLEAR ODORLESS SOLUTION
Percent Volatiles by Volume:NA
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF ACCORDING TO LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SUPPLIED AIR RESPIR/SCBA; ESCAPE: GAS MASK
Ventilation:LOCAL EXHAUST TO MAINTN BELOW TLV.
Other Protective Equipment:FULL PROTECTIVE CLOTHING,SAFETY SHOWER,EYE
WASH STATION
Supplemental Safety and Health
* Product Identification *
Product ID:BROMOFORM
* Composition/Information on Ingredients *
Ingred Name:BROMOFORM (TRIBROMOMETHANE) (SARA III)
OSHA PEL:S, 0.5 PPM
* Hazards Identification *
Effects of Overexposure:INH:VAP IRRIT RESP TRACT;ING:POISON!CAUSES
DIZZ,LIUR INJURY;SKIN/EYES:IRRIT.SPLASH MAY DAMAGE EYES.
* First Aid Measures *
First Aid:INHAL:RMV TO FRESH AIR.GIVE CPR/OXYGEN IF BREATHING IS
DIFFICULT.GET MD;INGEST:IMMED INDUCE VOMIT BY GIVING 2 GL OF
WATER.NOTHING BY MOUTH IF UNCONSCIOUS.GET MD IMMED;SKIN/EYES:FLUSH
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
CONTR.
Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD
* Accidental Release Measures *
Spill Release Procedures:VENTILATE & EVAC AREA.USE PROTCTV CLOTHG &
RESP PROTCTION FM VAP.CONTAIN & RECOVR LIQ WHEN POSS.SPILLS MAY BE
ABSORBD W/INERT MATL,VERMICULITE,DRY SAND & PLACE IN A CONTNR
PENDING DISPOSAL.DO NOT FLUS H TO SEWER.HAVE DRY POWDR EXTINGUISHR
ON HAND.
*Handling and Storage *
Handling and Storage Precautions:KEEP IN TIGHTLY CLOSED CONTNRS AT
COOL,DRY,VENTILATED PLACE.PROTECT AGAINST PHY DAMAGE.
Other Precautions:AVOID BREATHING MIST.USE W/ADEQUATE VENTILATION.KEEP
CONTAINERS CLOSED.WASH THOROUGHLY AFTER HANDLING.AVOID SKIN,EYES &
CLOTHING CONTACT.
* Physical/Chemical Properties *
HCC:C1
Vapor Pres:5
Vapor Density:8.7
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR,COLORLESS SOLUTION.CHLOROFORM-LIKE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
CHEMICALLY ACTIVE METALS,SUCH AS NA,K,CA,AL(POWDERED),CAUSTC
Hazardous Decomposition Products:TOXIC FUMES OF BROMIDES,HYDROGEN
BROMIDES & BROMINES.
* Disposal Considerations *
Waste Disposal Methods:COLLECTED WASTE MAY BE TRANSFERRED TO A
CLOSED,PREFERABLY METAL,CONTAINER AND SENT TO A RCRA-APPROVED WASTE
DISPOSAL FACILITY.ENSURE COMPLIANCE WITH LOCAL,STATE & FEDERAL
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURES EXCEED ESTABLISHED LIMITS, A
NIOSH/MSHA APPROVED RESPIRATOR FOR ASBESTOS SHOULD BE USED.
CONSULT YOUR SAFETY OFFICE/IH PERSONNEL FOR GUIDANCE FOR THE TASK
AT HAND.
Ventilation:LOCAL EXHAUST IS RECOMMENDED IN SITUATIONS WHERE DUST IS
GENERATED BY ABRASIVE ACTIONS, ABRASION OR OTHER MEANS.
Other Protective Equipment:AS REQUIRED FOR TASK AT HAND, AND THE
GUIDANCE SET FORTH BY YOUR SAFETY OFFICE OR IH PERSONNEL
Work Hygienic Practices:DONOT INHALE DUST CREATED BY ABRADING ACTIONS.
USE FULL PROTECTION AGAINST AIRBORNE FIBERS. AVOID AIRBORNE DUST
CREATION
Supplemental Safety and Health
GENERIC "MSDS" CREATED FOR "NSN" IDENTIFIED BY "DISC" AS CONTAINING
ASBESTOS.WHEN A MANUFACTURER'S SPECIFIC "MSDS" IS PROVIDED FOR
MATERIAL PROCURED UNDER THIS NSN, THIS GENERIC "MSDS" WILL BE
REMOVED.
* Product Identification *
Preparer's Name:DOD HMIS/DGSC-SSH
* Composition/Information on Ingredients *
Ingred Name:ASBESTOS, CHRYSOTILE
OSHA PEL:0.2 FIBERS/CC
Ingred Name:ASBESTOS & NATURAL/SYNTHETIC COMPOSITION
Ingred Name:GENERIC "MSDS". SPECIFIC ASBESTOS TYPE NOT KNOWN. ONE
CITED IS ASSUMED. INFORMATION BASED ON SEGMENT "M" OF "DLSC TIR"
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: NO ACUTE EFFECTS ARE KNOWN;
CHRONIC: DUST FROM ABRASIVE ACTIONS(EG. CUTTING, MACHINING,
FILING, ETC.) MAYCONTAIN ASBESTOS FIBERS. CHRONIC OVEREXPOSURE
TO AIRBORNE FIBERS MAY LEAD TO ASBESTOSIS & MESOTHELIOMA.
SMOKINGCOMBINED W/FIBER INHALATION GREATLY INCREASES LUNG
CANCER RISK!
Explanation of Carcinogenicity:OVEREXPOSURE TO AIRBORNE CONCENTRATIONS
OF ASBESTOS MAY LEAD TO ASBESTOSIS AND MESOTHELIOMA.
Effects of Overexposure:INHAL: INHALATION OF AIRBORNE DUST CONTAINING
ASBESTOS FIBERS ON REPEATED EXPOSURE MAY CAUSE OR CAN LEAD TO
ASBESTOSIS/ MESOTHELIOMA; SKIN: N/K; EYE: POTENTIAL IRRITATION
FROM AIRBORNE DUST; INGEST: N/K.
Medical Cond Aggravated by Exposure:RESPIRATORY DEFICIENCIES DUE TO
REPEATED INHALATION OF AIRBORNE FIBERS.
* First Aid Measures *
First Aid:INHAL: REMOVE TO FRESH AIR. OBTAIN MEDICAL ADVICE; SKIN:
WASH EXPOSED AREA WITH SOAP & WATER; EYE: FLOOD W/ WATER. IF
IRRITATION OCCURS, GET MEDICAL ATTN; INGEST: CONSULT A
PHYSICIAN; OTHER: CHANGE CLOTHING AS REQUIRED TO AVOIDCARRYING
DUST PARTICLES INTO OTHER AREAS
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:MATERIAL IS NOT FLAMMABLE ; USE MEDIA APPROPRIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:COMBUSTION PRODUCTS OF THIS MATERIAL MAY BE
TOXIC. USE A SELF-CONTAINED BREATHING APPARATUS WHEN FIGHTING FIRES
INVOLVING CHEMICAL PRODUCTS.
Unusual Fire/Explosion Hazard:NONE KNOWN
* Accidental Release Measures *
Spill Release Procedures:USE PROPER PERSONAL PROTECTION. VACUUM OR WET
CLEAN IF DUST IS INVOLVED. ANY VACUUM SYSTEM SHOULD BE EQUIPPED W/
AN OUTLET "HEPA" FILTER TO PREVENT REINTRODUCING ASBESTOS FIBERS TO
THE ATMOSPHERE.
*Handling and Storage *
Handling and Storage Precautions:HANDLE IN A MATTER TO MINIMIZE
FORMATION OR RETENTION OF AIRBORNE DUST. USE PROPER PERSONAL
PROTECTION FOR TASK AT HAND. CHECK W/YOUR SAFETY OFFICE!!!
Other Precautions:AS MANUFACTURED, LOCKED-IN ASBESTOS DOES NOT PRESENT
A HAZARD. ONLY WHEN THE ITEM IS SUBJECTED TO ABRASIVE ACTIONS &
DUST IS GENERATED, THEN ASBESTOS FIBERS MAY BE RELEASED & BECOME
AIRBORNE.
* Physical/Chemical Properties *
HCC:T6
Evaporation Rate & Reference:NONE
Solubility in Water:NOT SOLUBLE
Appearance and Odor:MANUFACTURED COMMODITY DESCRIBED BY LOGISTICS:
"ITEM-NAME"
Percent Volatiles by Volume:NONE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE KNOWN
* Disposal Considerations *
Waste Disposal Methods:DUST SHOULD BE HANDLED AS A HAZARDOUS AIR
LANDFILLS APPROVED FOR ASBESTOS DISPOSAL. NOTE IF ITEM UNDER
CONSIDERATION FOR DISPOSAL IS "FRIABLE OR NON-FRIABLE".
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE HALF-MASK RESPIRATOR W/ORGANIC VAPOR
CARTRIDGEAPPROVED BY NIOSH/MSHA WHERE EXCESSIVE EXPOSURE TO VAPORS
MAY OCCUR. USE AN APPROPRIATE, PROPERLY FITTED RESPIRATOR
(NIOSH/MSHA APPROVED) DURING & AFT ER APPLICATION.
Ventilation:REQUIRED TO CONTROL VAPOR/DUST/MIST CONCENTRATION.
Other Protective Equipment:EYEWASH STATIONS & SAFETY SHOWERS
Supplemental Safety and Health
* Product Identification *
Kit Part:Y
Preparer's Name:JIM SCHMIDT
CAGE:0ULT0
CAGE:0ULT0
* Composition/Information on Ingredients *
Ingred Name:TALC (POWDER), (ASBESTOS FREE), TALCUM; HYDROUS MAGNESIUM
SILICATE
OSHA PEL:2 MG/CUM (RESP DUST)
ACGIH TLV:2 MG/CUM (RESP DUST)
Ingred Name:CRYSTALLINE-QUARTZ SILICA, SILICA DUST (SUSPECTED HUMAN
ACGIH TLV:0.1 MG/CUM RESP DUST
Ingred Name:PROPYLENEGLYCOL MONOMETHYL ETHER ACETATE,
1-METHOXY-2-PROPANOL ACETATE
Ingred Name:HEXONE, METHYL ISOBUTYL KETONE (MIBK), 4-METHYL-2-PENTANONE
Ingred Name:2-HEPTANONE, METHYL N-AMYL KETONE
Ingred Name:2-BUTANONE (METHYL ETHYL KETONE) (MEK)
Ingred Name:TITANIUM DIOXIDE, TITANIUM OXIDE (SUSPECTED ANIMAL
Ingred Name:2,4-PENTANEDIONE, ACETYLACETONE
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY CAUSE NOSE, THROAT & UPPER
RESPIRATORY TRACT IRRITATION. SPRAY MISTS/VAPORS MAY CAUSE
IRRITATION TO EYES, MUCOUS MEMBRANE, NOSE, THROAT, RESPIRATORY
TRACT & SKIN. CAN BE ABSORBED THROUGH SKIN CAUS ING ORGAN DAMAGE.
REPEATED/PROLONGED OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT
BRAIN & NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:IRRITATION
* First Aid Measures *
REMOVE TO FRESH AIR. RESTORE BREATHING IF REQUIRED. INGESTION:
RINSE MOUTH IMMMEDIATELTY. GIVE 6-8OZ OF LIQUID. NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DON'T INDUCEVOMITING
UNLESS ADVISED BY A PHYSICIAN. OBTAIN MEDICAL ATTENTION IN ALL
CASES.
* Fire Fighting Measures *
Lower Limits:1
Extinguishing Media:CO2, DRY CHEMICALS/ALCOHOL FOAM
Fire Fighting Procedures:EVACUATE AREA. DON'T ENTER CONFINED SPACE W/O
PROTECTIVE EQUIPMENT & POSITIVE PREESURE NIOSH-APPROVED SCBA. COOL
CONTAINERS W/WATER. FIGHT FROM PROTECTED AREA.
Unusual Fire/Explosion Hazard:VAPORS MAY BE HEAVIER THAN AIR & TRAVEL
ALONG THE GROUND TO DISTANT IGNITION SOURCE & FLASH BACK.
LIQUID/VAPORS ARE DANGEROUS FIRE/EXPLOSION HAZARD WHEN HEATED.
* Accidental Release Measures *
Spill Release Procedures:STAY UPWIND & AWAY UNLESS WEARING APPROPRIATE
PROTECTIVE EQUIPMENT. STOP &/CONTAIN SAFELY. KEEP ALL SOURCES OF
IGNITION AWAY. VENTILATE AREA. USE NON-SPARKING TOOLS. COVER
W/INERT MATERIAL TO REDUCE F UMES.
(SEESUPP)
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINERS COOL, DRY & AWAY FROM
SOURCES OF IGNITION. USE & STORE W/ADEQUATE VENTILATION. DON'T
SMOKE IN STORAGE AREAS.
Other Precautions:KEEP CONTAINERS TIGHTLY CLOSED WHEN NOT IN USE.
ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS & OPEN FLAME. AVOID
CONTACT/BREATHING VAPORS/MIST. DON'T FLAME CUT/WELD EMPTY DRUMS.
KEEP WELDING/CUTTIN G EQUIPMENT AWAY FROM PRODUCT.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:(BU AC=1): >1
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
N-BUTYL ACETATE: STRONG OXIDIZERS, ACIDS, BASES & ALKALIES.
Stability Condition to Avoid:SPARKS, OPEN FLAME, HOT SURFACES & ALL
OTHER SOURCES OF HEAT & IGNITION.
Hazardous Decomposition Products:THERMAL: OXIDES OF CARBON & VARIOUS
HYDROCARBONS
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IAW/FEDERAL, STATE & LOCAL
REGULATIONS.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF THE TLV OF ANY COMPONENT IS EXCEEDED, A
NIOSH/ MSHA APPROVED AIR SUPPLIED RESPIRATOR IS ADVISED IN THE
ABSENCE OF PROPER ENVIRONMENTAL CONTROLS. ENGINEERING OR
ADMINISTRATIVE CONTROLS SHOULD BE IMP LEMENTED TO REDUCE EXPOSURE.
Ventilation:PROVIDE SUFFICIENT GENERAL EXPLOSION-PROOF VENTILATION TO
MAINTAIN EXPOSURE BELOW TLV.
Other Protective Equipment:IMPERVIOUS CLOTHING AND BOOTS TO PREVENT
SKIN CONTACT. DO NOT WEAR CONTACT LENSES.
Work Hygienic Practices:WASH WITH SOAP AND WATER BEFORE EATING,
DRINKING, SMOKING, OR USING TOILET FACILITIES. LAUNDER CONTAMINATED
CLOTHING.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:RICHARD MARCI
* Composition/Information on Ingredients *
Ingred Name:XYLENES (O-,M-,P- ISOMERS)(SARA III)
Other REC Limits:NONE RECOMMENDED
Ingred Name:STYRENATED ALKYD RESIN
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES AND MUCOUS
MEMBRANES, CHEMICAL PNEUMONITTA, PULMONARY EDEMA/HEMORRHAGE AND
DEPRESSION OF CENTRAL NERVOUS SYSTEM.
Explanation of Carcinogenicity:NONE OF THE COMPONENTS OF THIS PRODUCT
HAVE BEEN DETERMINED BY THE NTP, IARC, OR OSHA TO CAUSE CANCER IN
HUMANS.
Effects of Overexposure:SKIN/EYES: IRRITATION, REDNESS. INHALATION/
INGESTION: DIZZINESS, EXCITEMENT, DROWSINESS, INCOHERENCE,
STAGGERING GAIT, NAUSEA AND VOMITING.
Medical Cond Aggravated by Exposure:PRE-EXISTING CONDITIONS SUCH AS DRY
SKIN, DERMITITIS, CHEMICAL PNEUMONITTA, PULMONARY EDEMA/HEMORRHAGE
* First Aid Measures *
First Aid:EYE CONTACT: FLUSH WITH WATER. SKIN CONTACT: WASH WITH SOAP
AND WATER; REMOVE CONTAMINATED CLOTHING. INHALATION: REMOVE VICTIM
TO FRESH AIR AND PROVIDE OXYGEN IF BREATHINGIS DIFFICULT. GIVE
ARTIFICIALRESPIRATION IF NOT BREATHING. INGESTION: DO NOT INDUCE
VOMITING EVEN IF VOMITING OCURS. IF VOMITING OCCURS, KEEP HEAD
LOWER THAN HIPS TO PREVENT ASPIRATION OF LIQUID INTO LUNGS. GET
MEDICAL ATTENTION
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:1.0
Upper Limits:7.0
Extinguishing Media:USE CARBON DIOXIDE, FOAM, OR DRY CHEMICAL.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA &
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:SOLVENT VAPORS ARE HEAVIER THAN AIR AND
MAY TRAVEL ALONG THE GROUND AND BE IGNITED AT LOCATIONS DISTANT
FROM HANDLING POINT. DIRECT WATER STREAM MAY SPREAD FIRE
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. PERSONS NOT
WEARING PROTECTIVE EQUIPMENT SHOULD BE KEPT AWAY FROM AREA OF SPILL
UNTIL CLEANUP HAS BEEN COMPLETED. STOP SPILL AT SOURCE. KEEP FROM
ENTERING SEWERS, STREA M. ABSORB WITH INERT MATERIAL/PLACE IN
CONTAINER
Neutralizing Agent:NONE SPECIFIED.
*Handling and Storage *
Handling and Storage Precautions:STORE MATERIAL IN TIGHTLY CLOSED
CONTAINERS AWAY FROM SOURCES OF HEAT OR IGNITION, CONTAINERS SHOULD
BE GROUNDED WHEN TRANSFERRING.
Other Precautions:DO NOT TRANSFER TO UNMARKED CONTAINERS. NEVER USE
PRESSURE TO EMPTY CONTAINERS; LOOSEN CLOSURES CAREFULLY. DO NOT USE
WELDING OR CUTTING TORCHES ON OR NEAR CONTAINERS (EVEN
EMPTY);PRODUCT (RESIDUE) CA N IGNITE EXPLOSIVELY.
* Physical/Chemical Properties *
HCC:F4
Vapor Pres:5.1 MM HG
Vapor Density:>1(AIR=1)
Evaporation Rate & Reference:9 (ETHER=1)
Solubility in Water:INSOLUBLE
Appearance and Odor:AMBER LIQUID, XYLENE ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HIGH TEMPERATURES, SPARKS, AND OPEN
FLAMES. CONTACT WITH STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:BURNING MAY PRODUCE CARBON DIOXIDE AND
CARBON MONOXIDE
* Disposal Considerations *
Waste Disposal Methods:MATERIAL NOT USEABLE FOR ITS ORIGINAL PURPOSE
AND CONTAMINATED ABSORBENT WILL BE HAZARDOUS WASTE. DISPOSE OF IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. KEEP FROM
ENTERING SEWERS, STREAMS , OTHER BODIES OF WATER.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE REQUIRED
Ventilation:MECHANICAL: RECOMMENDED
Other Protective Equipment:NONE REQUIRED
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SODIUM SILFITE
Ingred Name:ACETIC ACID (SARA III)
Ingred Name:BORIC ACID
Ingred Name:AMMONIUM THIOSULFATE
* Hazards Identification *
Effects of Overexposure:EYE: IRRITATION. SKIN: POSSIBLE IRRITATION ON
PROLONGED CONTACT. INGESTION: PAIN/UPSET STOMACH.
* First Aid Measures *
First Aid:EYES: FLUSH WITH WATER. SKIN: WASH WITH SOAP & WATER.
INGESTION: DRINK WATER AND MILK, INDUCE VOMITING AND CALL A
PHYSICIAN IMMEDIATELY.
* Fire Fighting Measures *
Flash Point:NOT COMBUSTIBLE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NONE REQUIRED
Fire Fighting Procedures:NONE REQUIRED
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:MOP UP SMALL SPILLS ON WASTE TOWELING AND
DISPOSE OF IN A PROPER CONTAINER, LOCAL, STE AND FEDERAL
REGULATIONS TAKING PROCEDENCE. LARGE SPILLS: FLUSH TO SEW WITH
PLENTY OF WATER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY PLACE.
* Physical/Chemical Properties *
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, PALE STRAW; SOUR ODOR OF AMMONIA/VINEGAR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS AND STRONG ALKALIS
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:WITH ACIDS, SULFUR DIOXIDE. WITH
ALKALIS, AMMONIA
* Disposal Considerations *
Waste Disposal Methods:FLUSH TO SEWER WITH PLENTY OF WATER.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE PROPERLY FITTED ORGANIC VAPOR/PARTICULATE
RESPIRATOR APPROVED BY NIOSH/MSHA. WHEN SANDING OR ABRADING THE
DRIED FILM, WEAR A DUST/MIST RESPIRATOR FOR DUST WHICH MAY BE
GENERATED FROM PRODUCT, UNDE RLYING PAINT, OR ABRASIVE. SEE SUPPL.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE WHEN
EXPOSURE LIMITS ARE EXCEEDED
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
THIS COATING MAY CONTAIN MATERIALS CLASSIFIED AS NUISANCE PARTICULATES
WHICH MAY BE PRESENT AT HAZARDOUS LEVELS ONLY DURING SANDING OR
ABRADING OF THE DRIED FILM.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PROPANE
ACGIH TLV:SIMPLE ASPHYXIANT
Ingred Name:ISOBUTANE, 2-METHYLPROPANE
Ingred Name:TOLUENE
Fraction by Wt: 5%
Ingred Name:XYLENE, DIMETHYLBENZENE, XYLOL
Ingred Name:ACETONE; DIMETHYL KETONE
Ingred Name:ETHYL 3-ETHOXYPROPIONATE
Fraction by Wt: 4%
Ingred Name:TITANIUM DIOXIDE, TIO2
Fraction by Wt: 4%
Ingred Name:VOL ORGANIC CMPD: PERCENT BY WEIGHT
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & RESPIRATORY
SYSTEM. NERVOUS SYSTEM DEPRESSION. PERMANENT BRAIN & NERVOUS SYSTEM
DAMAGE. MAY CAUSE ADVERSE EFFECTS TO LIVER, URINARY, BLOOD FORMING,
CARDIO-VASCULAR & REPRODU CTIVE SYSTEMS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: HEADACHE, DIZZINESS, NAUSEA, LOSS
OF COORDINATION, UNCONSCIOUSNESS & DEATH. EYES/SKIN: REDNESS,
ITCHING & BURNING SENSATION.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR & RESTORE BREATHING. KEEP
MINS. INGESTION: OBTAIN MEDICAL ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:PMCC
Flash Point:<0F
Lower Limits:0.7%
Upper Limits:7%
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS. WATER MAY BE USED TO COOL
CLOSED CONTAINERS. FOG NOZZLES ARE PREFERABLE.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE DUE TO
PRESSURE BUILD-UP, POSSIBLE AUTOIGNITION WHEN EXPOSED TO EXTREME
HEAT. CONTENTS ARE EXTREMELY FLAMMABLE.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL IGNITION SOURCES. VENTILATE AREA.
REMOVE W/INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:USE APPROVED BONDING & GROUNDING
PROCEDURES. CONTENTS UNDER PRESSURE. DON'T PUNCTURE, INCINERATE, OR
Other Precautions:USE ONLY W/ADEQUATE VENTILATION. AVOID BREATHING
VAPOR/SPRAY MIST. AVOID SKIN & EYE CONTACT. DON'T TAKE INTERNALLY.
KEEP OUT OF REACH OF CHILDREN. INTENTIONAL MISUSE BY DELIBERATELY
CONCENTRATING & IN HALING CONTENTS CAN BE HARMFUL OR FATAL.
* Physical/Chemical Properties *
Vapor Density:>1
Evaporation Rate & Reference:FASTER THAN ETHER
Appearance and Odor:GRAY PAINT
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, PILOT LIGHTS,
HEATERS, SUNLIGHT, STOVES, ELECTRIC TOOLS, APPLICANCES & OTHER
IGNITION SOURCES
Hazardous Decomposition Products:CO & CO2
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM PRODUCT MAY BE HAZARDOUS AS DEFINED
UNDER RCRA. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERMINE
APPLICABLE EPA HAZARDOUS WASTE NUMBERS. DON'T INCINERATE.
DEPRESSURIZE CONTAINER. DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE
& LOCAL LAWS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURE EXCEEDS PERMISSABLE EXPOSURE LIMITS,
USE APPROPRIATE NIOSH APPROVED RESPIRATORY EQUIPMENT.
Ventilation:LOCAL EXHAUST RECOMMENDED. MECHANICAL VENTILATION
RECOMMENDED.
SHIELD.
Other Protective Equipment:EYE WASH FOUNTAIN, SAFETY SHOWER.
Work Hygienic Practices:WASH HANDS BEFORE EATING.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:HENRY SIMMONS
* Composition/Information on Ingredients *
Ingred Name:ETHYLENE GLYCOL
< Wt:5.
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:ACRYLIC POLYMER PLUS PROPRIETARY ADDITIVES
* Hazards Identification *
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN, NOSE, THROAT, AND RESPIRATORY
IRRITATION MAY RESULT FROM OVEREXPOSURE.
Effects of Overexposure:INHALATION HEALTH RISKS AND SYMPTONS OF
EXPOSURE:ADVERSE HEALTH EFFECTS FROM VAPORS OR SPRAY MISTS IN
POORLY VENTILATED AREAS MAY INCLUDE IRRITATION OF THE NOSE, THROAT
AND RESPIRATORY TRACT IRRITATIO N ALSO OCCUR. HEADACHES AND NAUSEA
MAY ALSO OCCUR.SKIN AND EYE CONTACT HEALTH RISKS AND SYMPTONS OF
EXPOSURE:PROLONGED OR REPEATED CONTACT WITH PRODUCT MAY CAUSE SKIN
IRRITATION.DIRECT CONTACT WITH PR ODUCT MAY RESULT IN EYE
IRRITATION. SKIN ABSOPTION HEALTH RISKS AND SYMPTONS OF EXPOSURE:
NOT LIKELY TO BE ABSORBED THROUGH THE SKIN. INJESTION HEALTH RISKS
AND SYMPTOMS OF EXPOSURE: INGESTION MAY CAU SE IRRITATION.
Medical Cond Aggravated by Exposure:NONE KNOWN.
* First Aid Measures *
First Aid:INHALATION: REMOVE TO FRESH AIR AND ARTIFICIAL RESPIRATION OF
OXYGEN IF NEEDED. CALL A PHYSICIAN. INGESTION: DO NOT INDUCE
VOMITING, CALL A PHYSICIAN. EYE CONTACT: FLUSH EYES WITH WATER FOR
AND WATER. CALL A PHYSICIAN IF IRRITATION PERSISTS.
* Fire Fighting Measures *
Lower Limits:3.2%
Extinguishing Media:NONE KNOW.
Fire Fighting Procedures:NONE.
Unusual Fire/Explosion Hazard:PRODUCT WILL NOT BURN BUT MAY SPATTER IF
TEMPERATURE EXCEEDS BOILING POINT. POLYMER FILMS ARE CAPABLE OF
BURNING GIVING OFF OXIDES OF CARBON/NITROGEN.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. DIKE AND
CONTAIN SPILL WITH INERT OR SPILLLED. KEEP SPILLS AND RUNOFFS OFF
MUNICIPAL SEWERS AND OPEN BODIES OF WATER.
*Handling and Storage *
Handling and Storage Precautions:ELIMINATE ALL SOURCES OF IGNITION.
DIKE AND CONTAIN SPILL WITH INERT OR SPILLLED. KEEP SPILLS AND
RUNOFFS OFF MUNICIPAL SEWERS AND OPEN BODIES OF WATER.
Other Precautions:MAY BE HARMFUL IF SWALLOWED. BREATHING VAPOR OR MIST
MAY BE HARMFUL. USE WITH ADEQUATE VENTILATION. AVOID EYE AND SKIN
CONTACT.
* Physical/Chemical Properties *
Vapor Density:>AIR
Spec Gravity:1.4
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:COMPLETE
Appearance and Odor:VISCOUS LIQUID SLIGHT AMMONIA ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:FREEZING TEMPERATURES.
Hazardous Decomposition Products:NONE KNOWN
* Toxicological Information*
Toxicological Information:PHARMOCOLOGICAL ACTIVITY: PURINETHOL IS A
POTENT CYTOTOXIC AGENT AND IS INDICATED FOR REMISSION INDUCTION AND
MAINTENANCE THERAPY OF ACUTE LYMPHATIC LEUKEMIA. OCCUPATIONAL
ACUTE TOXICITY: THE APPROXIMATE LETAL DOSE OF MERCAPTOPURINE
MG/KG. REPEAT DOSE TOXICITY: SAME ADVERS E EFFECTS AS WHEN USED
MEDICALLY: MYELOSUPPRESSION, HEPATOTOXICITY, GASTROINTESTINAL
TOXICITY.ADVERSE CHANGES TO IMMUNE SYSTEM MAY ALSO ACCOMPANY
EXPOSUERE TO THIS SUBSTANCE.
* Ecological Information *
Ecological:ENVIORONMENTAL FATE: MERCAPTOPURINE MONOHYDRATE
COMPARTMENTALIZES IN THE AQUATIC ENVIRONMENT. ENVIRONMENTAL
EFFECTS: MERCAPTOPURINE MONOHYDRATE IS UNLIKELY TO BIOACCUMULATE
* Disposal Considerations *
Waste Disposal Methods:OBEY RELEVANT LOCAL, STATE, AND FEDERAL LAWS. DO
NOT CONTAMINATE ANY LAKES, PONDS, STREAMS, OR UNDERGROUND WATER
SUPPLIES. TREAT AS HAZARDOUS WASTE. DISPOSE OF IN ACCORDANCE WITH
FEDERAL, STATE, AND LOCAL REGULATIONS. PRECAUTIONS TO BE TAKEN
IN HANDLING AND STORING AVOID FREEZING. AVOID CONTACT WITH
MICROORGANISMS. KEEP CONTAINER CLOSED WHEN
* MSDS Transport Information *
Transport Information:US DOT PROPER SHIPPING NAME: NOT REGULATED FOR
TARNSPORTATION. IATA/ICAO PROPER SHIPPING NAME: NOT REGULATED FOR
TARNSPORTATION. IMDG PROPER SHIPPING NAME: NOT REGULATED FOR
TARNSPORTATION. RQ = NONE.MARINE POLLUTANT: NO.
* Regulatory Information *
SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR SUITABLE FOR
ORGANIC VAPORS IF NECESSARY.
Ventilation:PROVIDE ADEQUATE CROSS AIR CIRCULATION. EXHAUST AT POINT OF
USE.
Other Protective Equipment:EYEWASH STATION, EMERGENCY SHOWER,
IMPERMEABLE APRON OR GARMENT TO MINIMIZE SKIN CONTACT.
Work Hygienic Practices:WASH HANDS WITH SOAP AND WATER AND USE HAND
CREAM.
Supplemental Safety and Health
FIRE FIGHT PROC: USE SAND TO CONTAIN BURNING MATERIAL. RUN OFF FROM
FIRE CONTROL MAY CAUSE POLLUTION. HNDLG/STOR PREC: TITANIUM DIOXIDE
* Product Identification *
Product ID:MAGMA QUARTZ INDUST AGG'T
CAGE:BELZO
CAGE:BELZO
* Composition/Information on Ingredients *
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
OSHA PEL:SEE TABLE Z3
Ingred Name:SILICON DIOXIDE
OSHA PEL:5 MG/M3 RDUST Z-3
Ingred Name:TITANIUM DIOXIDE
Ingred Name:DGBA EPOXY RESINS (BIS-A-DIGLYCIDYL ETHER RESIN)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SENSITIZER. EXTREMELY IRRITATING TO
SKIN AND EYES. GENERALLY CONSIDERED A NUISANCE. PROLONGED CONTACT
MAY CAUSE HEADACHE AND NAUSEA. IRRITATES EYES AND RESPIRATORY
TRACT.
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: GROUP 2A
(IARC).
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:MOVE TO FRESH AIR AND GIVE ARTIFICIAL RESPIRATION IF
WITH SOAP AND WATER. IF SWALLOWED, INDUCE VOMITING. DRINK LARGE
QUANTITIES OF W ATER IMMEDIATELY. IF SWALLOWED, CALL POISON CENTER
OR TAKE TO A HOSPITAL IMMEDIATELY.
* Fire Fighting Measures *
Extinguishing Media:WATER FOG (NOT A DIRECT STREAM OF WATER), FOAM,
CO*2 & DRY CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROT EQUIP
. FULL BUNKER GEAR SHOULD BE WORN IN EXTREME CASES. USE WATER TO
DILUTE SPILLS & COOL CNTNRS. (SUPP DATA)
Unusual Fire/Explosion Hazard:LIQUID IS IRRITATING TO EYES AND SKIN.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNIT. USE SAND TO
ABSORB MATL & DISPOSE OF PROPERLY. KEEP OUT OF WATER SUPPLY.
TRANSFER TO CLSD METAL CNTNR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:MUST BE KEPT IN DRY, COOL AND COVERED
AREA. AVOID BRTHG VAPS. EMPTY CNTNRS RETAIN RESIDUE & MAY BE
DANGEROUS. DISCARD CONTAM SHOES. (SEE SUPP DATA)
Other Precautions:CHECK ALL CONTAINERS FOR LEAKS. AVOID PROLONGED
BREATHING OR CONTACT WITH SKIN.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:<0.1%
Appearance and Odor:DAMP GRAY POWDER WITH EPOXY ODOR.
Percent Volatiles by Volume:0.0
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO*X & ALDEHYDES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL REGULATIONS .
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NOT NORMALLY REQUIRED EXCEPT IF DRIED FILM IS
BURNING. IF CONDITIONS EXIST WHERE PEL OR TLV MAY BE EXCEEDED, WEAR
NIOSH/ MSHA APPROVED RESPIRATOR.
Ventilation:USE SUFFICIENT VENT IN VOL & PATTERN BY OPENING WINDOWS &
DOORS, TO KEEP AIR CONTAMINANT CONCENTRATION BELOW PEL OR TLV.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:USE GOOD HYGIENE PRACTICES (WASH HANDS BEFORE
EATING, USING WASHROOM, OR SMOKING).
Supplemental Safety and Health
OTHER PREC: PROCESS USED/END USE OF DRIED MATL. METHANOL CANNOT BE MADE
NON-POISONOUS. INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS
MAY BE HARMFUL OR FATAL.
* Product Identification *
Preparer's Name:B.L. EUDY
* Composition/Information on Ingredients *
Ingred Name:METHANOL
Fraction by Wt: 2.9%
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: IRRITATE. SKIN: NO
EFFECT. INHAL: MAY CAUSE IRRIT TO THROAT, HEADACHE, NAUSEA,
VOMITING AND DIZZINESS. INGEST: NOT LIKELY TO OCCUR. IF SWALLOWED,
NO SIDE AFFECTS KNOWN. CHRONIC: REPORTS H AVE ASSOCIATED REPEATED
AND PROLONGED OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND
NERVOUS (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: SYSTEM DAMAGE.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
IRRIT OCCURS. SKIN: WASH WITH SOAP AND WATER. INHAL: MOVE PERSON TO
FRESH AIR. IF BREATHING STOPS, ADMINISTER ARTF RESP & CALL PHYS
IMMED. INGE ST: GIVE 2 GLASSES OF WATER. INDUCE VOMIT AND CALL PHYS
IMMED.
* Fire Fighting Measures *
Extinguishing Media:WATER FOG, CO2, DRY CHEMICAL, AND CHEMICAL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE KNOWN.
* Accidental Release Measures *
Spill Release Procedures:DISPENSE SAND, SAWDUST, & VERMICULITE. COLLECT
AND PLACE IN WASTE CONTAINER. WASH AREA THOROUGHLY WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
NEVER USE PRESS TO EMPTY. DRUM IS NOT PRESS VESSEL. DO NOT TAKE
INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:KEEP CLOSURE TIGHT & CONTR UPRIGHT TO PVNT LEAKAGE.
PROD AS SUPPLIED IS LIQ, & THERE ARE NO DUST HAZ FROM POWDERS IN
IT. WHEN PROD IS PROCESSED, POWDERS SHOULD BE ENCAPSULATED. USE
MUST DETERM IF THER E IS DUAL HAZ BECAUSE OF (SUPP DATA)
* Physical/Chemical Properties *
HCC:C1
Vapor Pres:SAME H2O
Vapor Density:SAME H2O
Spec Gravity:1.0(H2O=1)
pH:1.1
Evaporation Rate & Reference:1(WATER=1)
Solubility in Water:DILUTABLE
Appearance and Odor:PALE GREEN VISCOUS LIQUID
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:DRIED MATL MAY PRDCE CO, CO2, H2O,
NOX, & OTHER PROD FROM BURNING OF AROMATIC HYDROCARBONS.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS. DIRECT
PHYSICAL CONTACT SHOULD BE AVOIDED.
Explanation Of Carcinogenicity: NOT RELEVANT.
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST: CALL MD IMMEDIATELY (FP N). EYES: FLUSH WITH COPIOUS AMOUNTS
INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN IF NECESSARY. CONTACT MD.
*
Handling and Disposal
*
Spill Release Procedures: DUE TO THE SMALL QUANTITY INVOLVED, SPILLS OR LEAKS
SHOULD NOT POSE A SIGNIFICANT PROBLEM. A LEAKING BOTTLE MAY BE PLACED IN A
PLASTIC BAG AND NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLE MAY BE
ABSORBED ON VERMICULITE OR SAND.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS
CONCERNING DISPOSAL.
Handling And Storage Precautions: KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY
PLACE.
Other Precautions: THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS TRAINED
IN THE SAFE HANDLING OF HAZARDOUS CHEMICALS.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER OR WATER SPRAY.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: NONE SPECIFIED BY MANUFACTURER.
*
*
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment: USE APPROP NIOSH/MSHA APPRVD SFTY EQUIP. WEAR CHEM
RESISTANT CLTHG SUCH AS LAB COAT &/OR RUB APRON TO PVNT CNTCT.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: NONE SPECIFIED BY MANUFACTURER.
*
Physical/Chemical Properties
*
HCC: N1
Appearance and Odor: NONE SPECIFIED BY MANUFACTURER.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: ULTRA SCIENTIFIC
Label Required IND: Y
Status Code: C
Origination Code: G
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: None
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: COMBUSTIBLE. ACUTE: ALL CHEMICALS SHOULD BE CONSIDERED
HAZARDOUS. DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED. CHRONIC: NONE SPECIFIED
BY MANUFACTURER.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT(S) OF PROD/ ANY
COMPONENT IS EXCEEDED (SEE TLV/PEL), A NIOSH APPRVD AIR SUPPLIED
RESP IS ADVISED IN ABSENCE OF PROPER ENVIRON CONTROL. OSHA REGS
ALSO PERMIT OTHER NIOSH RES PS (NEG PRESS TYPE) UNDER SPECIFIED
CNDTNS (SEE YOUR SFTY EQUIP SUPPLIER). ENGINEERING AND/OR
ADMINISTRATIVE CONTROLS SHOULD BE IMPLEMENTED TO REDUCE EXPOSURE.
Ventilation:MATERIAL SHOULD BE HNDLD/TRANSFERRED IN APPRVD FUME HOOD OR
WITH ADEQUATE VENTILATION.
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY.
Supplemental Safety and Health
SPILL RELEASE PROC: REGS ON RPTG RELEASES. REFER TO REGULATORY INFO FOR
REPORTABLE QTY & OTHER REGULATORY DATA.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ETHANE, 1,1,2-TRICHLORO-1,2,2-TRIFLUORO-;
(1,1,2-TRIFLUOROTRICHLOROETHANE)
Ozone Depleting Chemical:1
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
DROWSINESS, LOSS OF CONCENTRATION, POSSIBLE NARCOSIS. POSSIBLE
CARDIAC ARRHYTHMIA AT HIGHER CONCENTRATIONS. LIQUID AND VAPOR
IRRITATING TO SKIN, EYES, OR MUCOUS MEMBRAN ES. CHLOROFLUOROCARBON
(CFC) MATERIALS HAVE PRODUCED SENSITIZATION OF THE MYOCARDIUM TO
EPINEPHRINE N LABORATORY ANIMALS & COULD HAVE SIMILAR EFFECT IN
HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY B E CONTRAINDICATED
EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS ACUTELY OR CHRONICALLY
EXPOSED TO CFC'S.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:HEART CONDITIONS.
* First Aid Measures *
First Aid:GET MEDICAL ASSISTANCE FOR ALL CASES OF OVEREXPOSURE. SKIN:
WASH THOROUGHLY WITH SOAP AND WATER. EYES: IMMEDIATELY FLUSH
TO FRESH AIR; GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS
STOPPED. INGESTION: DO NOT INDUCE VOMITING; GET IMMEDIATE MEDICAL
ATTENTION.
* Fire Fighting Measures *
Flash Point:NONCOMBUSTIBLE
Extinguishing Media:USE ANY SUITABLE FOR ADJACENT MATERIAL.
Fire Fighting Procedures:USE NIOSH APPROVED PRESSURE DEMAND SCBA AND
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THERMAL DECOMPOSITION PRODUCES TOXIC
FUMES. THERMAL DECOMPOSITION PRODUCTS MAY INCLUDE CHLORIDE,
FLUORIDES AND PHOSGENE .
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA OF ALL UNNECESSARY PERSONNEL.
WEAR SUITABLE PROT EQUIP LISTED UNDER EXPOSURE/PERSONAL PROT. ELIM
ANY IGNIT SOURCES UNTIL AREA IS DETERMINED TO BE FREE FROM
EXPLOSION/FIRE HAZARDS. CONTAI N RELEASE & ELIM ITS SOURCE, IF THIS
CAN BE DONE W/OUT RISK. TAKE UP & CONTAINERIZE FOR PROPER DISP AS
DESCRIBED UNDER DISPOSAL. COMPLY WITH FEDERAL, STATE, AND LOCAL
(SUPDAT)
*Handling and Storage *
Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN A COOL, DRY AREA AWAY FROM IGNITION SOURCES AND OXIDIZERS. DO
NOT BREATHE VAPOR. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING.
Other Precautions:NO SMOKING IN AREA OF USE. DO NOT USE IN THE GENERAL
VICINITY OF ARC WELDING, OPEN FLAMES OR HOT SURFACES. HEAT AND/OR
UV RADIATION MAY CAUSE THE FORMATION OF CHLORIDES, FLUORIDES AND
PHOSGENE .
* Physical/Chemical Properties *
Vapor Density:6.5
Solubility in Water:SLIGHT
Appearance and Odor:COLORLESS LIQUID, SLIGHT ETHER ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZERS. MAY REACT EXPLOSIVELY ON CONTACT WITH ACTIVE MEATALS: NA, K,
BA, AL, BE, MG, AZ, TITANIUM, LITHIUM, SAMARIUM.
Hazardous Decomposition Products:HALOGEN ACIDS, HALOGENS, CARBONYL
HALIDES, PHOSGENE. CHLORIDES, FLUORIDES AND PHOSGENE .
* Toxicological Information*
PPM/6H. TOXICOLOGICAL FINDINGS: NONE. CITED IN REGISTRY OF TOXIC
EFFECTS OF CHEMICAL SUBSTANCES (RTECS).
* Disposal Considerations *
Waste Disposal Methods:MATERIAL DOES NOT HAVE AN EPA WASTE NUMBER AND
IS NOT A LISTED WASTE, HOWEVER CONSULTATION WITH PERMITTED WASTE
DISPOSAL SITE (TSD) SHOULD BE ACCOMPLISHED. ALWAYS CONTACT
PERMITTED WASTE DISPOSER (TSD ) TO ASSURE COMPLIANCE WITH ALL
CURRENT LOCAL, STATE AND FEDERAL REGULATIONS.
* MSDS Transport Information *
Transport Information:DOT PROPER SHIPPING NAME: NON-REGULATED. DOT ID
NUMBER: NONE.
* Regulatory Information *
Federal Regulatory Information:TSCA STATEMENT: THE CAS NUMBER OF THIS
PRODUCT IS LISTED ONT HE TSCA INVENTORY.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:WEAR SUITABLE NIOSH/MSHA APPROVED RESPIRATOR
WHERE EXPOSURE LIMITS ARE EXCEEDED.
Ventilation:LOCAL EXHAUST: STANDARD PLANT VENTILATION; ESPECIALLY AT
POINT WHERE PRODUCT IS DRIED. MECH(GEN): YES.
Other Protective Equipment:AS INDICATED FOR SPECIFIC APPLICATION FOR
PRECAUTION TOWARD FIRE AND VAPOR INHALATION OVEREXPOSURE.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: AUTO-IGNIT/EXPLO WHEN EXPOSED TO EXTREME HEAT. FOG
NOZZ ARE PREF IF WATER IS USED. EXPLO HAZ: GENERATORS. EXTINGUISH
ALL PILOT LIGHTS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ISOPROPYL ALCOHOL; (ISOPROPANOL)
Fraction by Wt: <5%
Ingred Name:METHANOL; (METHYL ALCOHOL)
Fraction by Wt: 7%
Ingred Name:VM&P NAPHTHA
Fraction by Wt: <3%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:INGEST: ACUTE: GI IRRIT; CHRONIC: NOT
KNOWN. INHAL: ACUTE: ANESTHETIC EFTS; OVEREXPOSURE COULD CAUSE
UNCON & DEATH; CHRONIC: NOT KNOWN. SKIN: WILL NOT BE ABSORBED THRU
SKIN. ACUTE: IRRITATION. CHRONIC : NOT KNOWN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:INGEST: GI IRRITATION. INHAL: DIZZINESS,
STAGGERING GAIT, LT HEAD HDCH, CONFUSION, NAUS, UNCON. SKIN:
IRRITATION.
Medical Cond Aggravated by Exposure:HEART, LUNGS AND KIDNEY CONDITIONS
MAY BE AGGRAVATED BY INHALATION.
* First Aid Measures *
First Aid:CONSULT PHYSICIAN IN ALL CASES. INGEST: DO NOT INDUCE
VOMITING. INHAL: REMOVE FROM VAPOR AREA. ADMINISTER OXYGEN IF
BREATHING IS LABORED. APPLY ARTF RESP IF BREATHING HAS STOPPED.
WITH SOAP AND WATER. APPLY MOISTURIZING LOTION.
* Fire Fighting Measures *
Flash Point Method:SCC
Lower Limits:6%
Extinguishing Media:NFPA CLASS B EXTINGUISHERS (CO*2, DRY
CHEMICAL/FOAM).
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFTIVE. WATER MAY BE USED TO COOL CLSD CONTRS
TO PVNT PRESS BUILD-UP & POSS (SUPP DATA)
Unusual Fire/Explosion Hazard:KEEP CONTRS CLSD WHEN NOT IN USE. CLSD
CONTRS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT. DO NOT USE IN
VICIN OF OPEN FLAME, SPARKS/STATIC ELEC (SUPP DATA)
* Accidental Release Measures *
Spill Release Procedures:VENTILATE AREA. SCRAPE INTO CONTAINERS FOR
DISPOSAL.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
QTY BUILDING DESIGNED AND PROTECTED FOR STORAGE OF NFPA CLASS B
FLAMMABLE (OR COMBUSTIBLE) MATERIALS.
Other Precautions:KEEP OUT OF REACH OF CHILDREN.
* Physical/Chemical Properties *
HCC:F4
Vapor Density:>1
Evaporation Rate & Reference:SLOWER THAN 1(ETHER=1)
Solubility in Water:NIL
Appearance and Odor:BROWN, SOLVENT BASE MASTIC, WITH MILD ALCOHOL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME.
Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY PRODUCE
CARBON MONOXIDE AND ORGANIC COMPOUNDS OF UNKNOWN STRUCTURE.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF CONTAINER I/A/W LOCAL, STATE AND
FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF NEEDED:NIOSH/MSHA APPRVD
Ventilation:MFR RECM MECHANICAL VENTILATION
Other Protective Equipment:PROTECTIVE CLOTHING.
Supplemental Safety and Health
UNTIL COOL TO ROOM TEMP BEFORE ATTEMPTING CLEAN UP.
* Product Identification *
Product ID:QUICKSET EXTRA
* Composition/Information on Ingredients *
Ingred Name:METHYL ETHYL KETONE PEROXIDE (MEKP) (SARA III)
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 0.7 PPM
* Hazards Identification *
Effects of Overexposure:EYE IRRIT, BLINDNESS.HARMFUL IF INH. HARMFUL OR
FATAL IF SWALLOWED.SEVERE SKIN IRRIT.
* First Aid Measures *
& H*2O-CALL MD.INH:REMOVE TO FRESH AIR-CALL MD IF DISCOMFORT
PERSISTS.IF SWALLOWED:ADMINISTER LRG QUANT OF H*2O-CNTCT MD IMMED.
* Fire Fighting Measures *
Extinguishing Media:CO*2,WATER SPRAY,FOAM
Fire Fighting Procedures:FIRE:USE H*2O.KEEP CONTNR COOL W/H*2O SPRAY.
(SUPP DATA)
Unusual Fire/Explosion Hazard:POTENTIAL EXPLOSION HAZARDS.ONCE
IGNITED,PROD WILL BURN VIGOROUSLY.
* Accidental Release Measures *
Spill Release Procedures:ABSORB SPILL W/INERT MATERL SUCH AS
PERLITE,VERMICULITE,SAND OR DIRT & THEN WET W/H*2O,SWEEP UP USING
NON-SPARK EQUIP & PLACE IN DOUBLE POLYETHYLENE BAGS.ISOLATE LEAKERS
& CONTAMINATED CONTAINER TO A SAFE PLACE FOR DISPOSAL.
*Handling and Storage *
AWAY FROM PROMOTER & COMBUST MATERL.AVOID HEAT,SPARK,OPEN FLAME &
DIRECT SUNLIGHT.AVOID CONTAMIN-KEEP CLSD
Other Precautions:ISOLATED STORAGE IS DESIRABLE.NEVER MIX ANY PROMOTER
OR ACCELERATOR W/PROD AS VERY RAPID OR EXPLOSIVE DECOMPOSITION
COULD OCCUR.DO NOT STORE TOGETHER W/FOOD & DRINK.
* Physical/Chemical Properties *
HCC:V3
Solubility in Water:MODERATE
Appearance and Odor:CLEAR LIQUID.SLIGHTLY PUNGENT ODOR
Percent Volatiles by Volume:3
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRB ACID,BASE,OXIDIZABLE,ACCELERATOR,PROMOTOR,METAL SALT.
* Disposal Considerations *
Waste Disposal Methods:BURY NEUTRALIZED WASTE IN EPA-APPROVED OR LOCAL
HAZARDOUS WASTE DISPOSAL LANDFILL MUST BE IAW LOCAL,STATE & FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
% Wt: 1-5
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
------------------------------
% Wt: <0.1
OSHA PEL: N/K (FP N)
------------------------------
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
------------------------------
APPEARS ON THE NAVY LIST OF OCCUP CHEM REPRO
-----------------------------
LATEST HAZ LIST INFO & SAFE HNDLG &
-----------------------------
MAY INCL TOXICITY TO LIVER, KIDNEY,
-----------------------------
ASSOC RPTD & PRLNGD OCCUP OVEREXP TO
-----------------------------
BY DELIB CONC & INHALING CONTENTS MAY BE
-----------------------------
EFTS IN HUMANS. DEVELOPMENTAL TOXICITY
-----------------------------
INHAL. ADDNLY, DELIB INHAL OF TOLUENE
-----------------------------
& SUDDEN DEATH.
-----------------------------
IRRIT OR OTHER EFTS PERSIST, OBTAIN MED
-----------------------------
IMMEDIATELY.
-----------------------------
DURING CLEANUP. LARGE SPILLS: SHUT OFF
-----------------------------
OR SALVAGE VESSELS. USE ABSORB TO PICK UP
-----------------------------
SEWERS & WATER COURSES. SMALL SPILLS: USE
-----------------------------
-----------------------------
INHALABLE PARTICLES SUCH AS SPRAYING OR
-----------------------------
AVOIDED, USE APPROP NIOSH APPRVD RESP PROT
-----------------------------
HAZARDOUS RESIDUES. GROUND EQUIPMENT WHEN
-----------------------------
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: INHAL: IRRIT OF RESP TRACT. PRLNGD INHAL MAY LEAD TO FATG,
DROW, DIZZ &/OR LT HEAD, HDCH, UNCOORD, NAUS, COUGH, CNS DEPRESS, RESP
PROBS, INTOXICATION, CONFUSION, ANESTH EFT OR NARCOSIS, DFCLTY BRTHG, CARD
ABNORMS, LOSS OF CONSCIOUSNESS, RESP FAILURE, ASPHYXIATION, DEATH. SKIN
CONTACT: IRRIT OF SKIN. (EFTS OF OVEREXP)
Signs And Symptions Of Overexposure: HLTH HAZ: PRLNGD/RPTD CONTACT CAN CAUSE
DERM, DEFAT. SKIN CONTACT W/LIQ DIMETHYL ETHER MAY CAUSE FREEZING OF SKIN.
EYES: IRRIT. PRLNGD/RPTD CONTACT CAN CAUSE BLURRED VISION, TEARING, REDNESS,
SEVERE I RRIT, CORNEAL INJURY. INGEST: MAY CAUSELUNG INFLAM & DAMAGE DUE
TO ASPIR OF MATL INTO LUNGS, NAUSEA, VOMIT,
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS.
ASTHMA-LIKE CONDITIONS. CARDIAC ABNORMALITIES. KIDNEY DISORDERS. LIVER
DISORDERS. NERVOUS SYSTEM DISORDERS.
First Aid: INHAL: REMOVE TO FRESH AIR. RESTORE & SUPPORT CONTINUED BRTHG.
GET EMER MED ATTN. HAVE TRAINED PERSON GIVE OXYGEN IF NEC. GET MED HELP FOR
ANY BRTHG DFCLTY. GET MED ATTN IF DISCOMFORT OR IRRIT PERSIST S. SKIN: FLUSH
FROM SKIN W/WATER. THEN WASH THOROUGHLY W/SOAP & WATER. REMOVE CONTAM
CLTHG. WASH CONTAM CLTHG BEFORE REUSE. IF IRRIT OCCURS, CONSULT MD. EYES:
FLUSH IMMED W/LARGE AMTS OF
*
Handling and Disposal
*
Spill Release Procedures: COMPLY W/ALL APPLICABLE HEALTH & ENVIRONMENTAL
REGS. ELIMINATE ALL SOURCES OF IGNIT. VENT AREA. VENT AREA W/EXPLOSION-PROOF
EQUIP. SPILLS MAY BE COLLECTED W/ABSORB MATLS. USE NON-SPKG TOOLS. EVACUATE
ALL UNNEC PERS. PLACE COLLECTED MATL IN
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS. AVOID DISCHARGE TO NATURAL WATERS.
SPARKS AND OPEN FLAME.
Other Precautions: USE ONLY W/ADEQ VENT. DO NOT TAKE INTERNALLY. KEEP OUT OF
REACH OF CHILDREN. AVOID CONTACT W/SKIN & EYES & BRTHG OF VAPS. WASH
HANDS THOROUGHLY AFTER HNDLG, ESP BEFORE EATING OR SMOKING. KEEP CNTNRS T
IGHTLY CLOSED & UPRIGHT WHEN
*
Fire and Explosion Hazard Information
*
Lower Limits: 3.4%
Extinguishing Media: DRY CHEMICAL OR FOAM. WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N). WATER MAY BE USED TO COOL AND PROTECT EXPOSED CONTAINERS.
Unusual Fire/Explosion Hazard: CLOSED CNTNRS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT OR FIRE. VAPS MAY IGNITE EXPLOSIVELY AT AMBIENT TEMPS. VAPS ARE
HVR/AIR & MAY TRAVEL LONG DISTS (SUPDAT)
*
*
Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED
Ventilation: PROVIDE DILUTION VENT OR LOCAL EXHAUST TO PREVENT BUILD-UP OF
VAPS. USE EXPLOSION-PROOF EQUIP. USE NON-SPARKING EQUIP.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
IMPERVIOUS CLOTHING, FACE SHIELD.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health: EXPLO HAZ: TO SOURCE OF IGNIT & FLASH BACK.
MAY DECOMPOSE UNDER FIRE CONDITIONS EMITTING IRRITANT &/OR TOXIC GASES.
CNDTNS TO AVOID: W/ORGANIC PEROXIDES, CONTACT W/OXIDIZABLE MATLS, SPARKS,
OPEN FLAME , IGNITION SOURCES. EXPLAN OF CARCIN: CARCIN. OSHA REGULATED: CFR
*
Physical/Chemical Properties
*
Appearance and Odor: LIQUID.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: CAN FORM EXPLOSIVE PEROXIDES ON LONG STANDING IN
AIR. AVOID ELEVATED TEMPS. CONTACT W/OXIDIZING AGENTS, CONTAM (SUPDAT)
Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES, VINYL POLYMERS.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Assigned IND: Y
Company Name: ICI PAINTS
Label Required IND: Y
Status Code: C
Origination
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMMABLE. ACUTE: INHAL: RESP TRACT IRRIT, FATG, DROW,
DIZZ &/OR LT HEAD, HDCH, UNCOORD, NAUS, COUGH, CNS DEPRESS, RESP PROBS,
INTOXICATION, CONFUSION, ANESTH EFT OR NARCOSIS, DFCLTY BRTHG, CARD ABNOR MS,
UNCON, RESP FAILURE, ASPHYX, DEATH.SKIN: IRRIT, DERM, DEFAT. CONTACT W/LIQ
DIMETHYL ETHER MAY CAUSE FREEZING OF SKIN. EYES: IRRIT, BLURRED VISION,
TEARING, REDNESS, CORNEAL INJURY. INGEST: LUNG IN FLAM & DMG DUE TO
ASPIR, NAUS, VOMIT, DIARR, GI DISTURBS, CNS DEPRESS. CHRONIC: CANCER HAZARD.
CONTAINS BENZENE WHICH IS LISTED AS A HUMAN BLOOD CARCIN (FP N). TOLUENE
APPEARS ON THE NAVY OCCUP CHEM R EPRO HAZS LIST (FP N).
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED SCBA, GAS MASKS EQUIPPED
WITH ORGANIC CARTRIDGES, MASKS WITH EXTERNAL AIR SOURCES.
Ventilation:LOCAL EXHAUST/MECHANICAL(GEN): YES. SPECIAL: TDI VAPS ARE
HVR/AIR. DESIGN EXHAUST SYSTEMS ACCORDINGLY.
Other Protective Equipment:COVERALLS, BOOTS, RUBBER APRONS. EMERGENCY
EYEWASH AND DELUGE SHOWER .
Work Hygienic Practices:DO NOT EAT, DRINK/SMOKE IN WORKING AREAS. KEEP
CLOTHING CLEAN AND EQUIPMENT CLEAN @ ALL TIMES.
Supplemental Safety and Health
KEY1;T3. SOL IN H2O: REACTS WITH WATER, GENERATING CARBON DIOXIDE.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:ISOCYANIC ACID, METHYL-M-PHENYLENE ESTER;
(TOLUENE-2,4-DIISOCYANATE (TDI))
Ingred Name:POLYESTER POLYOL
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:BENZOYL CHLORIDE
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:VAPORS INHAL MAY CAUSE SEVERE
IRRITATION OF RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE
PULMONARY EDEMA, CHRONIC LUNG IMPAIRMENT. LIQUID CONTACT CAUSES
SERIOUS SKIN AND EYE BURNS.
Explanation of Carcinogenicity:TOLUENE DIISOCYANATE:IARC MONOGRAPHS
Effects of Overexposure:DIFFICULT, LABORED BREATHING, ASTHMA-LIKE
ATTACKS IN SENSITIVE PERSONS, SEVERE IRRITATION OF SKIN, EYE
DAMAGE, OR TDI SENSITIZATION.
Medical Cond Aggravated by Exposure:RESPIRATORY, BRONCHIAL CONDITIONS.
SKIN SENSITIVITY.
* First Aid Measures *
SKIN: WASH W/PLENTY OF SOAP & WATER. REMOVE CONTAMD CLTHG. INGEST:
GIVE PLENTY OF WATER. DO NOT INDUCE VOMIT. GET MED ATTN. INHAL:
MOVE TO FRESH AIR. GIVE OXYGEN IF NEC. GET MEDATTN.
* Fire Fighting Measures *
Flash Point Method:PMCC
Lower Limits:0.9%
Upper Limits:9.5%
Extinguishing Media:WATER FOG, CARBON DIOXIDE OR FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . OXIDES OF CARBON, NITROGEN, ISOCYANATE VAPS
& HCN WILL BE GENERATED.
Unusual Fire/Explosion Hazard:WATER CONTAM MATL WILL GENERATE CARBON
DIOXIDE WHICH MAY CAUSE EXPLOS RUPTURE OF CLSD CONTRS WHEN EXPOSED
TO FIRE CNDTNS. COOL DOWN CLSD CONTRS W/WATER SPRAY.
* Accidental Release Measures *
Spill Release Procedures:CLEAN UP CREW MUST WEAR FULL PROT EQUIP.
WATER, 8% CONCENTRATED AMMONIA, & 2% DETERGENT. SHOVEL IT INTO OPEN
TOP DRUMS & REMOVE TO WE LL VENTILATED AREA.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN TIGHTLY CLOSED CONTAINERS IN
Other Precautions:PROD REACTS W/WATER & OTHER SUBSTANCES GENERATING
CARBON DIOXIDE GAS WHICH WILL CAUSE SEALED CONTRS TO EXPAND & POSS
RUPTURE. DO NOT RESEAL CONTRS IF CONTAM IS SUSPECTED. EXPOS TO VAPS
OF HOT MATL CAN BE EXTREMELY DANGEROUS.
* Physical/Chemical Properties *
HCC:T3
Vapor Density:6
Spec Gravity:1.2(H2O=1)
Solubility in Water:SUPP DATA
Appearance and Odor:LIGHT YELLOW, MEDIUM VISCOSITY LIQUID. STRONG
PUNGENT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BASIC COMPOUNDS, CAUSTIC SODA, TERTIARY AMINES, WATER.
PERIODS OF TIME.
Hazardous Decomposition Products:ISOCYANATE VAPORS, OXIDES OF CARBON
AND NITROGEN, HCN.
Conditions to Avoid Polymerization:WATER AND OTHER PRODUCTS THAT REACT
W/ ISOCYANATES.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL OF WASTE MUST BE DONE I/A/W FEDERAL,
STATE AND LOCAL ENVIRONMENTAL CONTROL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED. IF ENGINEERING CONTROLS
DO NOT MAINTAIN AIRBORNE CONCENTRATIONS BELOW RECOMMENDED EXPOSURE
LIMITS, AN APPROVED RESPIRATOR MUST BE WORN. RESPIRATOR TYPE: ACID
GAS. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO
HOUR) SHOULD BE USED. VENTILATION RATES SHOULD BE MATCHED TO
CONDITIONS.
SHOULD BE WORN.
Other Protective Equipment:EYE BATH, SAFETY SHOWER, WASHING FACILITIES.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES. IT IS
A GOOD INDUSTRIAL HYGIENE PRACTICE TO MINIMIZE SKIN CONTACT.
Supplemental Safety and Health
VENTILATION: USE PROCESS ENCLOSURES, LOCAL EXHAUST VENTILATION, OR
OTHER ENGINEERING CONTROLS TO MAINTAIN AIRBORNE LEVELS BELOW
RECOMMENDED EXPOSURE LIMITS.
* Product Identification *
Kit Part:Y
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
Ingred Name:SULFURIC ACID
Minumum % Wt:1.
Maxumum % Wt:5.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
Ingred Name:POTASSIUM PERMANGANATE
< Wt:1.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:C 5 MG(MN)/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHALATION: EXPECTED TO BE A LOW
HAZARD FOR RECOMMENDED HANDLING. EYES: NO SPECIFIC HAZARD KNOWN.
MAY CAUSE TRANSIENT IRRITATION. SKIN: LOW HAZARD FOR RECOMMENDED
HANDLING. INGESTION: EXPECTED TO BE A LOW INGESTION HAZARD.
Explanation of Carcinogenicity:INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC): GROUP 1, STRONG INORGANIC MISTS OR VAPORS CONTAINING
SULFURIC ACID - AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL
HYGIENISTS (ACGIH) (SULFURIC ACI D): SUSPECTED HUMAN CARCINOGEN
(A2) - NATIONAL TOXICOLOGY PROGRAM (NTP): NONE - OCCUPATIONAL
SAFETY AND HEALTH ADMINISTRATION (OSHA): NONE
* First Aid Measures *
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. TREAT
SYMPTOMATICALLY. GET MEDICAL ATTENTION IF SYMPTOMS PERSIST. EYES:
ANY MATERIAL THAT CONTACTS THE EYE SHOULD BE WASHED OUT IMMEDIATELY
WITH WATER. G ET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH
WITH SOAP AND WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media: USE APPROPRIATE AGENT FOR ADJACENT FIRE.
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE THOROUGHLY TO REMOVE RESIDUAL CONTAMINATION.
*Handling and Storage *
Handling and Storage Precautions:STORAGE: KEEP CONTAINER CLOSED. KEEP
AWAY FROM INCOMPATIBLE SUBSTANCES (SEE INCOMPATIBILITY SECTION).
Other Precautions:PERSONAL PRECAUTIONARY MEASURES: AVOID BREATHING MIST
AT CONCENTRATIONS GREATER THAN THE EXPOSURE LIMITS. AVOID CONTACT
WITH EYES AND PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH
ADEQUATE VENTILA TION. WASH THOROUGHLY AFTER HANDLING.
* Physical/Chemical Properties *
HCC:C1
Vapor Density:0.6
pH:< 2.0
Viscosity:NOT GIVEN
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:PURPLE LIQUID, NO ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BASES.
Stability Condition to Avoid:STABLE.
Hazardous Decomposition Products:NONE (NONCOMBUSTIBLE).
* Toxicological Information*
Toxicological Information:GENERAL: INTERNATIONAL AGENCY FOR RESEARCH ON
CANCER (IARC) HAS DETERMINED THAT OCCUPATIONAL EXPOSURE TO STRONG
INORGANIC MISTS OR VAPORS CONTAINING SULFURIC ACID IS CARCINOGENIC
TO HUMANS. PRODUCT IS NOT EXPECTED TO GENERATE MISTS OR VAPORS
WHEN PRODUCT INSTRUCTIONS FOR MIXING AND USE ARE FOLLOWED. DO NOT
USE SUBSTANCE IN A WAY THAT WOULD GENERATE VAPOR, MIST, AEROSOL,
DUST OR OTHER POTENTIAL INH ALATION EXPOSURE.
* Ecological Information *
Ecological:THE FOLLOWING PROPERTIES ARE ESTIMATED FROM THE COMPONENTS
OF THE PREPARATIONS. WORKING SOLUTION: POTENTIAL TOXICITY: FISH
BIOACCUMULATION: LOG POW<1. COD (APPROXIMATE G/L): 0. BOD5
(APPROXIMATE G/L): 0. POTENTIAL TOXICITY WASTE TREATMENT
* Disposal Considerations *
Waste Disposal Methods:CONTRACT WITH A LICENSED CHEMICAL DISPOSAL
AGENCY. SINCE EMPTIED CONTAINERS RETAIN PRODUCT RESIDUE, FOLLOW
LABEL WARNINGS EVEN AFTER CONTAINER IS EMPTIED.
* MSDS Transport Information *
Transport Information:FOR TRANSPORTATION INFORMATION REGARDING THIS
PRODUCT CALL THE KODAK WORLDWIDE TRANSPORTATION HAZMAT HOT LINE:
MONDAY THROUGH FRIDAY.
* Regulatory Information *
SARA Title III Information:CHEMICAL(S) SUBJECT TO THE REPORTING
State Regulatory Information:MATERIAL(S) KNOWN TO THE STATE OF
CALIFORNIA TO CAUSE CANCER: NONE. MATERIAL(S) KNOWN TO THE STATE
OF CALIFORNIA TO CAUSE ADVERSE REPRODUCTIVE EFFECTS: NONE.
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS ARE INADEQUATE TO
CONTROL DUST CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A
NIOSH-APPROVED DUST RESPIRATOR SHOULD BE WORN. IF RESPIRATORS ARE
Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV
Other Protective Equipment:LONG SLEEVE WORK CLOTHING, EYE WASH FOUNTAIN
Work Hygienic Practices:OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING,
DRINKING/SMOKING.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:SILICON
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS:EYE, SKIN, RESPIRATORY &
GI TRACTS. ACUTE- EYES/SKIN:MAY CAUSE MECHANICAL IRRITATION.
INHALE:DUSTS MAY CAUSE RESPIRATORY TRACT IRRITATION. ORAL:MAY CAUSE
IRRITATION OF GASTROINTESTINAL T RACT. CHRONIC- MAY CAUSE DELAYED
CHRONIC LUNG INJURY.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, COUGH, TEARING, REDNESS
Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE
EXISTING MEDICAL CONDITIONS SUCH AS RESPIRATORY AILMENTS.
* First Aid Measures *
First Aid:GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH
MINUTES. HOLD EYELIDS OPEN. CONSULT PHYSICIAN. SKIN:WASH WITH SOAP
& PLENTY OF WATER. ORAL:RINSE OUT MOUTH WITH WATER. DRINK 2-4
CUPFULS OF WATER. SEEK MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point:FLAMMABLE SOLID
Lower Limits:NOT RELEVANT
Upper Limits:NOT RELEVANT
Extinguishing Media:USE CARBON DIOXIDE, FOAM OR DRY CHEMICAL. DO NOT
USE WATER DIRECTLY ON FIRE.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING AND
NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS IN PRESSURE
DEMAND. HAZARDOUS DECOMPOSITION PRODUCTS MAY BE FORMED.
Unusual Fire/Explosion Hazard:HIGHLY TOXIC GASES MAY BE GENERATED.
* Accidental Release Measures *
Spill Release Procedures:WEAR PROTECTIVE EQUIPMENT. CAREFULLY SWEEP UP
SPILL. PLACE IN A WASTE DISPOSAL CONTAINER. AVOID DUSTING.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL, DRY PLACE, IN TIGHTLY
CLOSED CONTAINER, AWAY FROM INCOMPATIBLE MATERIALS. KEEP OUT OF
REACH OF CHILDREN.
PROPERLY FITTED NIOSH-APPROVED DUST RESPIRATOR FOR DUSTY
CONDITIONS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. AVOID CONTACT WIT H EYES AND SKIN. AVOID INHALING DUST.
* Physical/Chemical Properties *
HCC:F8
NRC/State Lic Num:NOT RELEVANT
Viscosity:NOT RELEVANT
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:INSOLUBLE
Appearance and Odor:DARK GREY FINE CRYSTALLINE POWDER
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS
Stability Condition to Avoid:MOISTURE
Hazardous Decomposition Products:IRRITATING AND TOXIC GASES
* Disposal Considerations *
Waste Disposal Methods:LANDFILL IN ACCEPTABLE MANNER, IN FULL
COMPLIANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. REUSING OR
RECYCLING IS RECOMMENDED.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW
APPLICABLE OCCUPATIONAL EXPOSURE STANDARDS. ENGINEERING OR
ADMINISTRATIVE CONTROLS OR NIOSH/MSHA APPRVD RESPS CAN BE USED TO
REDUCE EXPOSURE. ENGINEERING CONTROLS ARE PREFERRED BY OSHA.
Ventilation:SUFFICIENT TO MAINTAIN OPERATOR EXPOSURE BELOW APPLICABLE
OCCUPATIONAL EXPOSURE STANDARDS.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRST AID PROC: POSSESSES ONLY WEAK ANTICHOLINESTERASE ACTIVITY WHICH
SHOULD NOT REQUIRE SPECIFIC TREATMENT. LARGE DOSES HAVE BEEN
REPORTED TO CAUSE DYSPNEA, WEAKNESS, PULMONARY EDEMA, AND TWITCHING
I N RATS. CHRONIC INHALATION OF LARGE DOSES CAN LEAD TO GENERAL
POISONING WITH PARALYSIS.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:PHOSPHORIC ACID, TRIBUTYL ESTER; (TRIBUTYL PHOSPHATE)
OSHA PEL:0.2 PPM
ACGIH TLV:0.2 PPM
Ingred Name:HEXAHYDROPHTHALIC ANHYDRIDE
Fraction by Wt: 0-5%
Ingred Name:SILANE, 3-(2,3-EPOXYPROPOXY) PROPYLTRIMETHOXY-; (SILANE
Fraction by Wt: 0-3%
OPERATIONS AND EMERGENCY RESPONSE.
Ingred Name:WASTE DISP: RENDER THE RESULTING MATL HAZARDOUS. CONTACT
FEDERAL, STATE AND LOCAL AUTHORITIES FOR DISPOSAL INFO. (ING 6)
OF HAZARDOUS WASTE.
Ingred Name:OTHER PREC: AND FOR CONTROLLING THE FIRE/EXPLOSION HAZARD.
A QUALIFIED INDEPENDENT TESTING COMPANY CAN DETERMINE (ING 8)
Ingred Name:ING 7: IF THE EXISTING CONCENTRATIONS ARE WITHIN THE
ESTABLISHED RECOMMENDED/PERMISSIBLE EXPOSURE LEVELS.
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES: IRRITATION, INFLAMMATION. SKIN:
IRRITATION, DERMATITIS. INHAL: DIZZINESS, LOSS OF CONSCIOUSNESS,
IRRITATION, SENSITIZER WITH ASTHMATOID EFFECTS, WHEEZING, COUGHING,
SORE THROAT. INGEST: NAUSEA, VOMITING, ABDOMINAL PAIN.
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
SKIN: WASH W/SOAP & WATER. LAUNDER CONTAM CLOTHING BEFORE REUSE.
GET MED ATTN. INHAL:REMOVE TO FRESH AIR. ADMINISTER OXYGEN IF
BREATHING I S DIFFICULT. BEGIN RESUSCITATION IF BRTHG HAS STOPPED.
KEEP PERSON WARM & QUIET. GET MEDICAL ATTN. INGEST: DO NOT INDUCE
VOMITING. GET MEDICAL ATTN IMMED. NOTE TO MD: TRIBUTYL PHOSPHATE
(SUPP DATA)
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL, CO*2.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG THE GROUND AND MAY BE IGNITED AT DISTANT LOCATIONS.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION. ABSORB
SPILLED MATL WITH VERMICULITE OR FLOOR ABSORBENT. DISPOSE OF CONTAM
4)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:CNTNRS OF THESE MATLS MAY BE HAZARDOUS
WHEN EMPTIED, SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES WHICH CAN
GENERATE VAPS WITHIN THE FLAMMABLE LIMITS.
Other Precautions:FOR FLAMM OR COMBUSTIBLE PRODS FOLLOW STORAGE &
LIQUIDS CODE. THE USE OF A HAZARDOUS CHEMICAL MAY REQUIRE
SUPPLEMENTAL VENTILATION FOR THE PROTECTION OF PERSONNEL (ING 7)
* Physical/Chemical Properties *
Vapor Pres:VERY LOW
Evaporation Rate & Reference:VERY SLOW
Solubility in Water:NEGLIGIBLE
Appearance and Odor:LIQUID OR SEMI-SOLID INK AS COLOR ABOVE, MILD ODOR.
Percent Volatiles by Volume:APPROX
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ACIDS AND BASES. WATER.
Stability Condition to Avoid:HEAT AND FLAME.
Hazardous Decomposition Products:CO, CO*2, SILICON OXIDES.
* Disposal Considerations *
Waste Disposal Methods:UNDER RCRA, IT IS THE RESPONSIBILITY OF THE
GENERATOR OF THE WASTE TO DETERMINE, AT THE TIME OF DISPOSAL,
WHETHER THE WASTE GENERATED MEETS THE FEDERAL OR STATE HAZAROUS
WASTE CRITERIA. USES, TRANSFOR MATIONS, MIXTURES, PROCESSES, ETC.
MAY (ING 5)
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL (TLV), USE NIOSH/MSHA APPROVED RESPIRATOR AS
NIOSH-RESPIRATOR SELECTION.
AIR CHANGES PER HOUR IS RECOMMENDED.
Other Protective Equipment:SAFETY SHOWER AND EYE BATH. INDUSTRIAL TYPE
WORK CLOTHING AND APRON AS REQUIRED TO AVOID PROLONGED OR REPEATED
CONTACT.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING OR DRINKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
(PNI A) AND 3 BOTTLES OF O-TOLIDENE DIHYDROCHLORIDE (PNI B) + 3
* Product Identification *
Product ID:CHLORINATION KIT, CALCIUM HYPOCHLORITE
Kit Part:Y
Preparer's Name:VICKI MCCLURRY
* Composition/Information on Ingredients *
CHLORINE
Other REC Limits:NONE SPECIFIED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:THIS MATERIAL HAS THE POTENTIAL TO BE
IMMEDIATELY DANGEROUS TO LIFE AND HEALTH. IRRITATING TO THE NOSE,
MOUTH, THROAT, AND LUNGS. CAN BURN RESPIRATORY TRACT. HIGH
CONCENTRATIONS OR CHRONIC SMALLER EXP OSURES CAN RESULT IN
PERMANENT LUNG DAMAGE. EXPOSURE TO EYE AND SKIN CAUSES SEVERE
IRRITATION AND CAN RESULT IN DAMAGE.
Explanation of Carcinogenicity:CALCIUM HYPOCHLORITE IS NOT LISTED BY
IARC, NTP OR OSHA AS A CARCINOGEN.
Effects of Overexposure:SEVERE IRRITATION AND BURNING TO EXPOSED TISSUE
OF EYES, SKIN, RESPIRATORY TRACT. INGESTION CAN BURN THE ENTIRE
GASTROINTESTINAL TRACT INCLUDING THE STOMACH AND INTESTINES,
RESULTING IN VOMITING, DIAR RHEA, BLEEDING AND/OR TISSUE
ULCERATION. CAUSES SCAR TISSUE FORMATION.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF SKIN,
CARDIOVASCULAR AND RESPIRATORY DISORDERS MAY BE AT INCREASED RISK
FROM EXPOSURE. MATERIAL AGGRAVATES ANY SINUS OR BREATHING PROBLEM.
CORROSIVE TO MUCOUS MEMBRANES.
* First Aid Measures *
MINUTES. GET MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR.
GIVE ARTIFICIAL RESPIRATION IF NEEDED INGESTION: GIVE LARGE
QUANTITIES OF WATE R. DO NOT INDUCE VOMITING. GET
MEDICALATTENTION. RELAUNDER ANY EXPOSED CLOTHING BEFORE REUSE.
* Fire Fighting Measures *
Extinguishing Media:USE WATER FOR, CARBON DIOXIDE, OR DRY CHEMICAL, AS
APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACE SELF-CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY. CONTAIN RUNOFF.
Unusual Fire/Explosion Hazard:COMBUSTION OR HEAT OF FIRE MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND VAPORS.
* Accidental Release Measures *
Spill Release Procedures:PICK UP SPILLED MATERIAL AND PLACE IN CLEAN,
DRY CONTAINER FOR DISPOSAL. IF SPILLED INTO WATER, MONITOR FOR
AVAILABLE CHLORINE AND PH. STAY UPWIND OF SPILLS, IF POSSIBLE.
Neutralizing Agent:CONTACT MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN A COOL, DRY, WELL VENTILATED
AREA AWAY FROM SOURCES OF IGNITION. KEEP CONTAINER CLOSED WHEN NOT
IN USE. PROTECT FROM PHYSICAL DAMAGE.
Other Precautions:MATERIAL IS A STRONG OXIDIZER. TAKE PRECAUTIONS. DO
NOT RESUSE CONTAINER OR PLACE EXCESS MATERIAL WHICH MAY BE ORGANIC
CONTAMINATED BACK INTO CONTAINER ONCE REMOVED. AVOID BREATHING OF
DUST.
* Physical/Chemical Properties *
HCC:D1
Solubility in Water:APPRECIABLE
Appearance and Odor:WHITE GRANULAR SOLID
Percent Volatiles by Volume:0 %
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ORGANIC MATERIALS IN GENERAL, SOLVENTS, ACIDS, ISOCYANURATES, STRONG
OXIDIZERS.
DECOMPOSITION OCCURS.
Hazardous Decomposition Products:CHLORINE GAS AND HYDROGEN CHLORIDE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATIONS. CONTAMINATED SPILL MATERIAL
MAY BE A HAZARDOUS WASTE.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL
EXPOSURE LIMITS, USE A NIOSH APPROVED RESPIRATOR TO PREVENT
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER . WEAR PROT CLTHG AS REQUIRED TO PREVENT SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
NONE SPECIFIED BY MANUFACTURER.
* Product Identification *
Product ID:ANIONIC EMULSION RS-1
Preparer's Name:ALFRED B HECTOR
CAGE:TLFRS
* Composition/Information on Ingredients *
Ingred Name:RESIDUES (PETROLEUM), VACUUM; (PETROLEUM ASPHALT)
OSHA PEL:N/K
ACGIH TLV:5 MG/M3 (MFR)
Ingred Name:WATER
OSHA PEL:N/K
ACGIH TLV:N/K
Ingred Name:MINOR ADDITIVES
Fraction by Wt: 1%
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYES AND SKIN:PRODUCT IS PRESUMED TO
BE MINIMALLY IRRITATING. CONTACT AT ELEVATED TEMPERATURES CAN
RESULT IN THERMAL BURNS. PROLONGED AND REPEATED CONTACT MAY RESULT
IN VARIOUS SKIN DISORDERS. INHALAT ION:INHALATION OF VAPORS
(GENERATED AT HIGH TEMPERATURES) MAY CAUSE IRRITATION TO THE NOSE,
THROAT & (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZS:RESP TRACT. THIS PRODUCT CONTAINS
TRACE AMOUNTS OF A SUBSTANCE DESIGNATED BY THE STATE OF CALIFORNIA
TO BE A CARCINOGEN/REPRODUCTIVE TOXIN. NOTE:THE CONCENTRATION OF
THIS SUBSTANCE IS SIGNIF ICANTLY BELOW TO DE MINIUS REPORTING
THRESHOLD ESTABLISHED BY THE OSHA HAZARD COMMUNICATION STANDARD.
Medical Cond Aggravated by Exposure:
* First Aid Measures *
LIDS OPEN. GET MEDICAL ATTENTION. SKIN:IF HOT ASPHALT STRIKES SKIN,
DRENCH OR IMMERSE THE AREA IN WATER. DO NOT TRY TO REMOVE ASPHALT
FROM B URN AREA. SEEK MEDICAL ATTENTION. INHAL:REMOVE TO FRESH AIR
& PROVIDE OXYG IF BRTHG IS DFCLT. GET MED ATTN. INGEST:DO NOT
INDUCE VOMIT. NO DANGER IN GENERAL UNLESS LG QTYS ARE INGESTED. GET
MED ATTN.
* Fire Fighting Measures *
Extinguishing Media:DRY CHEMICAL OR FOAM.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT . NONE.
Unusual Fire/Explosion Hazard:
* Accidental Release Measures *
Spill Release Procedures:PREVENT PRODUCT FROM ENTERING SEWERS OR
WATERWAYS. MATERIAL MAY BURN ALTHOUGH NOT READILY IGNITABLE. DIKE
AND CONTAIN. REMOVE WITH VACUUM TRUCK OR PUMP INTO STORAGE. SOAK UP
RESIDUE WITH ABSORBENT SUC H AS SAND, DISPOSE OF PROPERLY.
Neutralizing Agent:
*Handling and Storage *
Handling and Storage Precautions:UNDER EPA-CWA, PROD IS CLASSIFIED AS
Other Precautions:
* Physical/Chemical Properties *
Spec Gravity:1
Solubility in Water:APPRECIABLE (BY WT)
Appearance and Odor:BROWN LIQUID, SLIGHT ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:NO
NOT COMPATABLE WITH VARIOUS SUBSTANCES, I.E., ANIONIC EMULSIONS.
Stability Condition to Avoid:DO NOT ALLOW EMULSIONS TO FREEZE.
Hazardous Decomposition Products:CARBON MONOXIDE, HYDROGEN SULFIDE AND
UNIDENTIFIED ORGANIC COMPOUNDS MAY BE FORMED DURING COMBUSTION.
* Disposal Considerations *
Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS . PLACE IN AN APPROPRIATE DISPOSAL FACILITY IN
COMPLIANCE WITH LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SHOULD BE NEEDED.
HOUR, SHOULD BE USED. RATES SHOULD MATCH CONDITIONS.
Other Protective Equipment:CHEMICAL RESISTANT CLOTHING AS NECESSARY TO
PREVENT SKIN CONTACT. AN EMERGENCY EYEWASH AND SHOWER SHOULD BE
AVAILABLE.
Work Hygienic Practices:WASH HANDS THOROUGHLY WITH SOAP AND WATER
BEFORE EATING, DRINKING, SMOKING OR USING TOILET FACILITIES.
Supplemental Safety and Health
REMOVE AND WASH CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR
THOROUGHLY CLEAN CONTAMINATED SHOES.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:WATER
Other REC Limits:NONE RECOMMENDED
Ingred Name:BENZYL ALCOHOL
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM XYLENE SULFONATE
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM DODECYLBENZENESULFONATE (SARA III)
Fraction by Wt: < 1%
Other REC Limits:NONE RECOMMENDED
Ingred Name:SODIUM TOLUENE SULFONATE
Fraction by Wt: 1-5%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EXPECTED TO BE A LOW INHALATION HAZARD
FOR RECOMMENDED HANDLING. CAUSES EYE IRRITATION. PROLONGED OR
REPEATED SKIN CONTACT MAY CAUSE DRYING, CRACKING OR IRRITATION.
EXPECTED TO BE A LOW INGESTION HAZA RD. MAY CAUSE IRRITATION OF THE
GASTROINTESTINAL TRACT.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:EYE IRRITATION, SKIN
DRYING/CRACKING/IRRITATION, GI TRACT IRRITATION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALATION: IF SYMPTOMATIC, MOVE TO FRESH AIR. GET MEDICAL
ATTENTION IF SYMPTOMS PERSIST. EYES: WASH OUT IMEEDIATELY WITH
WATER. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR. SKIN: WASH WITH
SOAP AND WATER . GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.
INGESTION: DRINK 1-2 GLASSES OF WATER. SEEK MEDICAL ATTENTION.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Lower Limits:NOT GIVEN
Upper Limits:NOT GIVEN
Extinguishing Media:WATER SPRAY, CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL
FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS AND
PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:FIRE OR EXCESSIVE HEAT MAY PRODUCE
HAZARDOUS DECOMPOSTION PRODUCTS.
* Accidental Release Measures *
Spill Release Procedures:FLUSH TO SEWER IF ALLOWABLE WITH LARGE AMOUNTS
OF WATER. OTHERWISE, ABSORB SPILL WITH VERMICULITE OR OTHER INERT
MATERIAL, THEN PLACE IN A CONTAINER FOR CHEMICAL WASTE. CLEAN
SURFACE TO REMOVE RESIDUA L CONTAMINATION.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:USE WITH ADEQUATE VENTILATION. WASH
THOROUGHLY AFTER HANDLING. KEEP FROM CONTACT WITH OXIDIZING
MATERIALS. KEEP CONTAINER TIGHTLY CLOSED.
Other Precautions:AVOID CONTACT WITH EYES. AVOID PROLONGED OR REPEATED
CONTACT SKIN.
* Physical/Chemical Properties *
HCC:N1
Melt/Freeze Pt:M.P/F.P Text:NOT GIVEN
Vapor Density:1.0
pH:7.2
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:COMPLETE
Appearance and Odor:COLORLESS LIQUID, ALCOHOL ODOR
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE,
OXIDES OF SULFUR
* Disposal Considerations *
Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT
TO NATIONAL, STATE OR LOCAL LAWS. DISPOSE OF IN ACCORDANCE WITH
ALL APPLICABLE FEDERAL, STATE AND LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:SCBA IF INVOLVED IN FIRE, OTHERWISE GAS MASK.
Ventilation:PROVIDE MECHAN(GEN/LOCAL EXHAUST)VENT TO MAINTN <TLV
Other Protective Equipment:EYE WASH STATION. APRONS. SPECIAL IMPERVIOUS
CLOTHING.
Supplemental Safety and Health
BY DGSC-STF.
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Effects of Overexposure:HAZ DEGREE DEPENDS ON TYPE/QUANT OF RADIATION.
LATENT EFFECTS:SOMATIC/GENETIC DAMAGE.
* First Aid Measures *
First Aid:USE FIRST AID. CALL MEDICAL EMERGENCY CARE. REMOVE/ISOLATE
COMTAMINATED CLOTHING.SHOWER VICTIM(S) W. SOAP & H*2O. DETAIN
PERSONNEL/EQUIPMENT EXPOSED. ADVISE MEDICAL PERSONNEL THAT
VICTIM(S) MAY BE CON TAMINATED.
* Fire Fighting Measures *
Extinguishing Media:EXTINQUISH W. AGENT SUITABLE FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR CHEMICAL PROTECTIVE SUIT WITH SELF CONTD
BRTHG APP.
Unusual Fire/Explosion Hazard:SOME OF MATL MAY BURN. CONT MAY EXPLODE
IN HEAT OF FIRE.
* Accidental Release Measures *
*Handling and Storage *
Handling and Storage Precautions:SHIELD ACCORDING TO EMITTED RADIATION.
PROTECT FROM FILM/FILM PLATES. KEEP CONTAINERS CLOSED. STORE IN
AREA FOR RADIOACTIVE MATERIALS.
* Physical/Chemical Properties *
HCC:A2
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
ISOLATE,SEGREGATE FROM MOST OTHER TYPE MATERIAL
Hazardous Decomposition Products:DEPENDS ON CHEMICAL COMPOSITION;
FISSION PRODUCTS
* Disposal Considerations *
Waste Disposal Methods:CONTROLLED DISPOSAL REQUIRED-IN ACCORDANCE WITH
DOD REGULATIONS AND FEDERAL,STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR.
Ventilation:MECHANICAL EXHAUST REQUIRED.
Other Protective Equipment:ANSI APPRVD EMERGENCY EYE WASH & DELUGE
SHOWER .
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
LENGTH FACESHIELD (8-INCH MIN) .
* Product Identification *
* Composition/Information on Ingredients *
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ACUTE:MAY BE HARMFUL BY INHALATION,
INGESTION, OR SKIN ABSORPTION. CAUSES SEVERE EYE IRRITATION. CAUSES
SKIN IRRITATION. MATERIAL IS IRRITATING TO MUCOUS MEMBRANES AND
UPPER RESPIRATORY TRACT. CAUSES DERMATITIS. TARGET ORGAN(S):LIVER,
KIDNEYS.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
* First Aid Measures *
MINUTES. ASSURE ADEQ FLUSHING OF EYES BY SEPARATING THE EYELIDS
W/FINGERS. FLUSH SKIN WITH WATER. INHAL:REMOVE TO FRESH AIR. IF NOT
BRTHG G IVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYG. INGEST:WASH
OUT MOUTH W/WATER PROVIDED PERSON IS CONSCIOUS. CALL A PHYSICIAN.
REMOVE AND WASH CONTAMINATED CLOTHING PROMPTLY.
* Fire Fighting Measures *
Lower Limits:2%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL POWDER OR APPROPRIATE
FOAM. WATER MAY BE EFTIVE FOR COOLING, BUT NOT EFT EXTINGUISHMENT.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:EXTREMELY FLAMMABLE. VAPOR MAY TRAVEL
CONSIDERABLE DISTANCE TO SOURCE OF IGNITION AND FLASH BACK.
* Accidental Release Measures *
Spill Release Procedures:EVACUATE AREA. SHUT OFF ALL SOURCES OF IGNIT.
W/ACTIVATED CARBON ABSORB, TAKE UP & PLACE IN CLSD CNTNRS.
TRANSPORT OUTDOORS. VENTILAT E AREA & WASH SPILL SITE AFTER MATL
PICKUP(SUPDAT)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:KEEP TIGHLY CLSD. KEEP AWAY FROM HEAT,
SPKS, & OPEN FLAME. STORE IN COOL DRY PLACE. SEV EYE IRRITANT.
AVOID PRLNGD/RPTD EXPOS. DO NOT BREATHE VAPOR.
Other Precautions:DO NOT GET IN EYES, ON SKIN, ON CLTHG. FLAMMABLE.
* Physical/Chemical Properties *
Vapor Pres:SUPDAT
Vapor Density:2
Evaporation Rate & Reference:NOT KNOWN
Solubility in Water:NOT KNOWN
Appearance and Odor:COLORLESS LIQUID.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
BASES, OXIDIZING AGENTS, REDUCING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:TOXIC FUMES OF:CARBON MONOXIDE, CARBON
DIOXIDE.
* Disposal Considerations *
Waste Disposal Methods:BURN IN A CHEMICAL INCINERATOR EQUIPPED WITH AN
AFTERBURNER AND SCRUBBER BUT EXERT EXTRA CARE IN IGNITING AS THIS
MATL IS HIGHLY FLAMMABLE. OBSERVE ALL FEDERAL, STATE AND LOCAL
ENVIRONMENTAL REGULATIO NS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF ENGINEERING CONTROLS ARE INADEQUATE TO
CONTROL DUST CONCENTRATIONS TO AN ACCEPTABLE LEVEL, A
NIOSH-APPROVED DUST RESPIRATOR SHOULD BE WORN IF NEEDED. IF
RESPIRATORS ARE USED, A PROGRAM SHOULD BE IN STITUTED TO COMPLY
WITH OSHA.
Ventilation:LOCAL EXHAUST
Other Protective Equipment:LONG SLEEVE WORK CLOTHING, EYE WASH FOUNTAIN
Work Hygienic Practices:WASH THOROUGHLY BEFORE EATING, DRINKING OR
SMOKING. VACUUM UP ANY DUST. LAUNDER CLOTHING BEFORE REUSE.
Supplemental Safety and Health
FORMULA CHANGED. FOR PREVIOUS FORMULATION, SEE PNI A UNDER THE SAME
NSN.
* Product Identification *
Product ID:MOLECULAR SIEVE TYPE 4 AXH 5
CAGE:0H8X3
* Composition/Information on Ingredients *
Ingred Name:SODIUM OXIDE
Other REC Limits:NONE RECOMMENDED
Ingred Name:ALPHA-ALUMINA (ALUMINUM OXIDE) (EPA LISTS ONLY FIBROUS
FORMS) (SARA III)
Other REC Limits:NONE RECOMMENDED
Ingred Name:SILICA GEL/SILICON OXIDE
Other REC Limits:NONE RECOMMENDED
OSHA PEL:6 MG/M3.
Ingred Name:SILICA, CRYSTALLINE - QUARTZ
Fraction by Wt: <1%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:SEE TABLE Z3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE- EYES:MAY CAUSE IRRITATION &
REDNESS. SKIN:MAY CAUSE IRRITATION, REDNESS AND/OR BURNS.
INHALATION:MAY CAUSE NOSE & THROAT IRRITATION & CHEST DISCOMFORT.
INGESTION:MAY BURN MOUTH & THROAT AS IT G ETS HOT WHEN ADSORB
WATER. CHRONIC- PROLONGED INHALATION MAY CAUSE LUNG DAMAGE.
Explanation of Carcinogenicity:CONTAINS QUARTZ.
Effects of Overexposure:EYE, SKIN, RESPIRATORY TRACT IRRITATION, COUGH,
REDNESS AND/OR BURNS OF EYES AND SKIN
Medical Cond Aggravated by Exposure:BREATHING OF DUST MAY AGGRAVATE
ASTHMA AND INFLAMMATORY OR FIBROTIC PULMONARY DISEASE.
* First Aid Measures *
First Aid:GET MEDICAL CARE IF SYMPTOMS PERSIST. EYES:IMMEDIATELY FLUSH
SOAP & WATER. INHALED:REMOVE TO FRESH AIR. SWALLOWED:IF LARGE
QUANTITIES IN GESTED, DRINK 2 GLASSES OF WATER. CONTACT PHYSICIAN
FOR PERMISSION TO INDUCE VOMITING. NOTE TO PHYSICAN:DESICCANT
GENERATES HEAT AS IT ABSORBS WATER. USED PRODUCT CAN CONTAIN
HAZARDOUS CHEMICALS.
* Fire Fighting Measures *
Flash Point:NONE
Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE.
Fire Fighting Procedures:DEPENDS ON THE USE OF MATERIAL. USED MATERIAL
MAY CONTAIN PRODUCTS OF A HAZARDOUS NATURE. IDENTIFY THE HAZARDS OF
THE RETAINED MATERIAL & INFORM FIRE FIGHTERS.
Unusual Fire/Explosion Hazard:IN THEIR FRESH UNUSED STATE, MOLECULAR
SIEVES ARE NOT FLAMMABLE. WHEN EXPOSED TO WATER, THEY CAN HEAT TO
THE BOILING POINT OF WATER.
* Accidental Release Measures *
Spill Release Procedures:SWEEP THE SPILL AREA. COLLECT AND PLACE THE
SPILLED MATERIAL IN A WASTE DISPOSAL CONTAINER. AVOID RAISING DUST.
Neutralizing Agent:NOT RELEVANT
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY PLACE, IN TIGHTLY CLOSED
CONTAINER, AWAY FROM MOISTURE AND INCOMPATIBLE MATERIALS.
PROPERLY FITTED NIOSH-APPROVED DUST RESPIRATOR FOR DUSTY
CONDITIONS. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER
HANDLING. AVOID CONTACT WIT H EYES. OPEN CONTAINER SLOWLY.
* Physical/Chemical Properties *
HCC:V7
NRC/State Lic Num:NOT RELEVANT
Melt/Freeze Pt:M.P/F.P Text:NOT KNOWN
Spec Gravity:1.1
Evaporation Rate & Reference:NOT RELEVANT
Solubility in Water:INSOLUBLE
Appearance and Odor:TAN BEAD, ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
SUDDEN CONTACT WITH HIGH CONCENTRATIONS OF CHEMICALS HAVING HIGH HEATS
OF ADSORPTION SUCH AS OLEFINS, HCL, ETC..
Stability Condition to Avoid:ADDITION OF MOISTURE (WATER) WITHOUT
FLOODING CAN CAUSE RISE IN TEMPERATURE AND CONTACT WITH SKIN MIGHT
RESULT IN BURNS.
Hazardous Decomposition Products:DECOMPOSITION PRODUCTS OF HYDROCARBONS
WHICH WERE RETAINED ON THE SIEVE, OXIDES OF SODIUM,
* Disposal Considerations *
Waste Disposal Methods:DISCARD ANY PRODUCT (INCLUDING ANY RETAINED
MATERIALS OF USE), DISPOSABLE CONTAINERS OR LINER IN AN
ENVIRONMENTALLY ACCEPTABLE MANNER, IN FULL COMPLIANCE WITH LOCAL,
STATE AND FEDERAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Control Measures
*
*
Contractor Summary
*
*
Ingredients
*
OSHA PEL: 1 MG/M3 CU (MFR)
ACGIH TLV: 1 MG/M3 CU (MFR)
*
Health Hazards Data
*
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: THIS PRODUCT MAY BE IRRITATING TO EYES, SKIN AND
RESPIRATORY TRACT. IRRITATION, VOMITING, DIARRHEA, SHOCK, KIDNEY AND LIVER
DAMAGE, DEATH. CHRONIC EXPOSURE MAY CAUSE DISCOLORATION OF THE SKIN OR HAIR,
MAY DESTROY TISSUES CONTACTED. TARGET ORGANS: LIVER, KIDNEYS.
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS.
Medical Cond Aggravated By Exposure: PRE-EXISTING SKIN DISORDERS OR IMPAIRED
LIVER, KIDNEY OR PULMONARY FUNCTION OR WILSON'S DISEASE MAY INCREASE
SUSCEPTIBILITY TO THE EFFECTS OF THE SUBSTANCE.
CALL MD. SKIN: FLUSH SKIN WITH PLENTY OF WATER. INGEST: INDUCE VOMITING BY
STICKING FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TOAN UNCONSCIOUS
PERSON. CALL MD. INHAL:REMOVE TO FRESH AIR.
*
Handling and Disposal
*
Spill Release Procedures: SWEEP UP POWDER. AVOID BREATHING MATERIAL. DISSOLVE
IN WATER. FLUSH DOWN THE DRAIN WITH EXCESS WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND
LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN TIGHTLY CLOSED CONTAINER IN A COOL,
DRY PLACE.
Other Precautions: AVOID CONTACT WITH EYES, SKIN AND CLOTHING. DO NOT BREATHE
DUST. WASH THOROUGHLY AFTER HANDLING.
*
Fire and Explosion Hazard Information
*
Extinguishing Media: WATER.
Fire Fighting Procedures: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT (FP N).
Unusual Fire/Explosion Hazard: MAY EMIT TOXIC FUMES IN FIRE.
*
*
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN (FP N).
Ventilation: ADEQUATE VENTILATION.
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N). LAB
COAT.
Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER.
*
Physical/Chemical Properties
*
M.P/F.P Text: SUPDAT
PH: SUPDAT
Solubility in Water: VERY SOLUBLE
Appearance and Odor: BLUE-GREEN CRYSTALS; NO ODOR.
*
Reactivity Data
*
Stability Indicator: YES
Stability Condition To Avoid: EXCESSIVE EXPOSURE TO AIR (DEHYDRATES), HEAT.
Materials To Avoid: CONTACT WITH HYDROXYLAMINE OR MAGNESIUM.
Hazardous Decomposition Products: MAY EMIT TOXIC FUMES OF SULFUR OXIDES AND
CUPRIC OXIDE IN FIRE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
*
Toxicological Information
*
*
Ecological Information
*
*
*
*
Regulatory Information
*
*
Other Information
*
*
HAZCOM Label
*
Company Name: HACH COMPANY
Label Required IND: Y
Status Code: C
Origination Code: G
Chronic Hazard IND: Y
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: THIS PRODUCT MAY BE IRRITATING TO EYES, SKIN AND
RESPIRATORY TRACT. IRRITATION, VOMITING, DIARRHEA, SHOCK, KIDNEY AND LIVER
DAMAGE, DEATH. CHRONIC: MAY CAUSE DISCOLORATION OF THE SKIN OR HAIR,MAY
DESTROY TISSUES CONTACTED. TARGET ORGANS: LIVER, KIDNEYS.
*
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE AIR-SUPPLIED MASK IN CONFINED AREA OR IN
EMERGENCY SITUATIONS.
Ventilation:SUFFICIENT MECHANICAL (GENERAL/LOCAL EXHAUST) TO KEEP <TLV.
Other Protective Equipment:IMPERVIOUS CLOTHING, APRON, EYE WASH
STATIONS, SAFETY SHOWER
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:R. W. KLUG
* Composition/Information on Ingredients *
Ingred Name:METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:EYE: INJURY/PAIN/TEARING/BLURRED
VISION. SKIN: DRYNESS/CRACKING/IRRITATION. INHALATION:
STUPOR/HEADACHE/NAUSEA/DIZZINESS/UNCONSCIOUSNESS. INGESTION:
SLUGGISHNESS/NAUSEA/VOMITING/ACIDOSIS/VISUAL ABNORM ALITIES/FATAL
BLINDNESS/CNS & PANCREAS DAMAGE/DEATH/POISONOUS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYE: INJURY/PAIN/TEARING/BLURRED VISION. SKIN:
DRYNESS/CRACKING/IRRITATION. INHALATION:
STUPOR/HEADACHE/NAUSEA/DIZZINESS/UNCONSCIOUSNESS. INGESTION:
SLUGGISHNESS/NAUSEA/VOMITING/ACIDOSIS/VISUAL ABNORM ALITIES/FATAL
BLINDNESS/CNS & PANCREAS DAMAGE/DEATH/POISONOUS.
* First Aid Measures *
INHALATION: REMOVE TO FRESH AIR. RESTORE NORMAL BREATHING.
INGESTION: INDUCE VOMITING IF CONSCIOUS BY GIVING GLASSES OF
WATER/PRESSING FINGER DOWN THROAT. NEVER ADMINISTER LIQUIDS IF
ETHANOL IN 5% AQUEOUS DEXTROSE INTRAVENOUSLY. OBTAIN MEDICAL
ATTENTION IN ALL CASES.
* Fire Fighting Measures *
Flash Point Method:TCC
Lower Limits:6%
Extinguishing Media:ALCOHOL FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS. USE WATER SPRAY TO COOL FIRE-EXPOSED SURFACES
& TO REDUCE THE INTENSITY OF THE FLAMES.
Unusual Fire/Explosion Hazard:VAPORS ARE >AIR/TRAVEL TO IGNITION
SOURCES/FLASHBACK. PRODUCT CAN BURN W/LITTLE OR NO VISIBLE FLAME.
FLAMMABLE LIQUID.
* Accidental Release Measures *
Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES. VENTILATE &
EVACUATE AREA. WEAR PROTECTIVE EQUIPMENT. CONTAIN & COLLECT PRODUCT
W/INERT ABSORBENT. PLACE IN CLOSED CONTAINERS W/NON-SPARKING TOOLS.
PREVENT PRODUCT FROM ENTERING WATER SUPPLY.
*Handling and Storage *
Handling and Storage Precautions:AVOID CONTACT W/SKIN & EYES. AVOID
INGESTION. STORE IN COOL, WELL-VENTILATED AREA. KEEP AWAY FROM
HEAT, SPARKS, OPEN FLAMES.
Other Precautions:KEEP CONTAINERS CLOSED. WHEN TRANSFERRING PRODUCT
FOLLOW PROPER GROUNDING PROCEDURES.
* Physical/Chemical Properties *
Evaporation Rate & Reference:(BU AC = 1): 2
Appearance and Odor:BLUE LIQUID W/SLIGHT ALCOHOL ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
SULFURIC ACID & STRONG OXIDIZING AGENTS
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, & OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:CO
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE, &
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF PERSONAL EXPOSURE CANNOT BE CONTROLLED BELOW
APPLICABLE LIMITS BY VENTILATION.WEAR A PROPERLY FITTED ORGANTIC
VAPOR/PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA FOR PROTECTION
AGAINST MATERIALS. W HEN SANDING OR ABRDING THE DRIED FILM, WEAR A
DUST/MIST RESPIRATOR UNDERLYING PAINT, OR THE ABRASIVE.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF THE
EXPOSURE LIMITS.
FOR PROTECTION.
Supplemental Safety and Health
* Product Identification *
Preparer's Name:ERNEST CARTER
* Composition/Information on Ingredients *
Ingred Name:MINERAL SPIRITS
Code:F
Minumum % Wt:5.
Ingred Name:TOLUENE
Minumum % Wt:.5
Maxumum % Wt:1.
OSHA PEL:SEE TABLE Z-2
Ingred Name:XYLENE
Minumum % Wt:.5
Maxumum % Wt:1.
Ingred Name:LIGHT AROMATIC SOLVENT NAPHTHA (PETROLEUM)
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:1,3,5-TRIMETHYLBENZENE
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:1,2,4-TRIMETHYLBENZENE
Minumum % Wt:3.
Maxumum % Wt:8.
Ingred Name:COBALTOUS 2-ETHYLHEXANOATE
Minumum % Wt:.1
Maxumum % Wt:.2
Minumum % Wt:1.
Maxumum % Wt:5.
Ingred Name:KAOLIN
Minumum % Wt:0.
ACGIH TLV:2 MG/M3
Ingred Name:TALC
Minumum % Wt:0.
Maxumum % Wt:5.
OSHA PEL:SEE TABLE Z-3
ACGIH TLV:2 MG/M3
Ingred Name:CALCIUM CARBONATE
Minumum % Wt:5.
Ingred Name:TITANIUM DIOXIDE
Minumum % Wt:0.
Ingred Name:CARBON BLACK
Minumum % Wt:0.
Maxumum % Wt:5.
OSHA PEL:3.5 MG/M3
ACGIH TLV:3.5 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:EXPOSURE MAY BE BY INHALATION AND/OR
SKIN OR EYE CONTACT, DEPENDING ON CONDITIONS OF USE. TO MINIMIZE,
FOLLOW RECOMMENDATIONS FOR PROPER USE, VENTILATION,AND PERSONAL
PROTECTIVE EQUIPMENT.IRRITATION O F EYES, SKIN AND RESPIRATORY
SYSTEM. MAY CAUSE NERVOUS SYSTEM DEPRESSION.EXTREME OVEREXPOSURE
MAY RESULT IN UNCONSCIOUSNESS AND POSSIBLY DEATH.
Effects of Overexposure:HEADACHE,DIZZINESS,NASEA,AND LOSS OF
COORDINATION ARE INDICATIONS OF EXCESSIVE EXPOSURE TO VAPORS OR
SPRAY MISTS.REDNESS AND ITCHING OR BURING SENSATION MAY INDICATE
EYE OR EXCESSIVE SKIN EXPOSURE.
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.
* First Aid Measures *
First Aid:IF AFFECTED, REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP
WARM AND QUIET. WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE COMTAMINATED CLOTHING AND LAUNDER BEFORE RE-USE. FLUSH EYES
GET MEDICAL ATTENTION.
* Fire Fighting Measures *
Flash Point Method:CALC
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE USED. WATER SPRAY MAY
BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE PREFERABLE. WATER
MAY BE USED TO COOL CLOSED CO NTAINERS TO PREVENT PRESSURE BUILD-UP
AND POSSIBLE AUTOIGNITION OR EXPLOSION WHEN EXPOSED TO EXTREME
HEAT.
Unusual Fire/Explosion Hazard:KEEP CONTAINERS TIGHTLY CLOSED. ISOLATE
FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS, AND OPEN FLAME. CLOSED
CONTAINERS MAY EXPLODE WHEN EXPOSED TO EXTREME HEAT.APPLICATION TO
HOT SURFACES REQUIRES SPECIAL PRECAUTIONS.DURING EMERGENCY
CONDITIONS OVEREXPOSURE TO DECOMPOSITION PRODUCTS MAY CAUSE A
HEALTH HAZARD.L ATTENTION.
* Accidental Release Measures *
Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
*Handling and Storage *
Handling and Storage Precautions:CONTENTS ARE COMBUSTIBLE. KEEP AWAY
FROM HEAT AND OPEN FLAME. CONSULT NFPA CODE. USE APPROVED BONDING
AND GROUNDING. BROCEDURES. KEEP CONTAINER CLOSED WHEN NOT IN USE.
TRANSFER ONLY TO APPROVED CONTAI NERS WITH COMPLETE AND APPROPRIATE
LABELING. DO NOT TEKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN.
Other Precautions:INTENTIONAL MISUSE BY DELIBERATELY CONCENTRATING AND
INHALING THE CONTENTS CAN BE HARMFUL OR FATAL.
* Physical/Chemical Properties *
Vapor Density:HEAVIER
Spec Gravity:1.1-1.4
Evaporation Rate & Reference:SLOWER THAN ETHER
* Stability and Reactivity Data *
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE
Conditions to Avoid Polymerization:WILL NOT OCCUR
* Disposal Considerations *
Waste Disposal Methods:WASTE FROM THIS PRODUCT MAY BE HAZARDOUS AS
APPLICABLE EPA HAZARDOUS WASTE NUMBERS.
* Regulatory Information *
COMPOUND, .2% BY WEIGHT.
NOTIFICATION
* Other Information *
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATR APPROPRIATE FOR
EXPOS OF CONCERN
Ventilation:PREFER LOCAL EXHAUST,ACCEPT GENERAL MECH -KEEP EXP <TLV
Other Protective Equipment:PROT CLOTHES&EQUIP TO PREV RPTD/PRLNG SKIN
CONTACT; EYEWASH.
Supplemental Safety and Health
OVEREXP:TEMP/PERM RESP DISEASE W/POSS DISABILITY/DEATH.SOME LUNG&SKIN
CONDITN WORSEN W/EXP.LUNG&SKIN SENSITIZATN FROM
DUST.FIRE/EXPLO:FIRE OUT.LRG FIRE-USE UNMANND HOSE HOLDR/LET
BURN.USE SCBA
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:TUNGSTEN CARBIDE
Ingred Name:COBALT (SARA III)
OSHA PEL:0.1 MG/M3;AS CO
* Hazards Identification *
Effects of Overexposure:OVEREXP TO METAL POWDR,DUST,MIST FROM
GRIND,SWEEP IS HEALTH HAZ.EYE,SKIN,MUC MEMB IRRIT(SEE SUPP DAT
* First Aid Measures *
First Aid:INHAL:REMOVE TO FRESH AIR IMMED.STOP BREATHING,GIVE ARTIFICL
RESP.KEEP WARM,AT REST.GET MED ATTN IMMED.SKIN:REMOVE CONTAM
PREC)
* Fire Fighting Measures *
Extinguishing Media:LOCALIZED POWDER FIRES:DRY SAND,DRY
DOLOMITE,NACL,SODA ASH.
(SEE SUPP DAT
Unusual Fire/Explosion Hazard:FINELY DIVIDED POWDR/DUST FROM GRIND
EXPECT TO BE FIRE/EXPLO HAZ WHEN EXP TO HIGH TEMP/IGNITN SOURCE
* Accidental Release Measures *
Spill Release Procedures:SWEEP UP W/MINIMUM DUST GENERATION & PLACE
INTO SUITABLE CLEAN,DRY CONTAINERS FOR LATER DISPOSAL OR
RECLAMATION. CLEAN UP RESIDUE USING A HIGH-EFFICIENCY PARTICULATE
FILTER VACUUM OR WET CLEAN UP. USENIOSH/MSHA APPROVED RESPIRATORY
PROTECTION.
*Handling and Storage *
Handling and Storage Precautions:AVOID DUST DISPERSION.FINELY DIVIDED
PARTIC,DUST,FUME POSS FLAM/EXPLO.KEEP FROM IGNITN SOURCE.STORE IN
CLEAN,DRY,COOL AREA.REMOVE DUST BY WASH/VACUUM.
Other Precautions:IMCOMPAT:AMMONIUM NITRATE&METAL/BRF*5,HYDRAZINIUM
NITRATE,NITRYL FLUORIDE,ACETYLENE.FIRST AID:GET MED ATTN
CONSCIOUS).CALL MD IMMED.
* Physical/Chemical Properties *
Solubility in Water:NEGLIGIBLE
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
Hazardous Decomposition Products:THERMAL DECOMP MAY RELEASE ACRID SMOKE
& IRRITATING FUMES.
* Disposal Considerations *
Waste Disposal Methods:SEND TO AN APPROPRIATE RECLAMATION FACILITY IF
AVAILABLE. IF MATERIAL CANNOT BE SENT TO RECLAMATION
FACILITY,DISPOSAL SHOULD BE MADE IN COMPLIANCE W/FEDERAL,STATE &
LOCAL ENVIRONMENTAL REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NONE SPECIFIED BY MANUFACTURER.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:FULL COVERAGE ACID RESIST CLOTH.
Work Hygienic Practices:WASH HANDS AFTER HANDLING.
Supplemental Safety and Health
HEALTH HAZ:RESP IRRIT,AGGRAVATE OTHER RESP CONDITIONS.SEVERE EYE
BURN,FATAL IF INGEST.LEAD ALLOY/CMPDS:DUST INHAL/MATL TRANSF TO
MOUTH:MAY CAUSE LASSITUDE,WT
LOSS,CONSTIPATION,ANEMIA,NAU,VOMIT,PARALYS IS,CNS DEPRESSION.
* Product Identification *
Product ID:AUTOMOTIVE, COMMERCIAL, INDUSTRIAL LEAD ACID BATTERIES.
CAGE:0W3X1
CAGE:0W3X1
* Composition/Information on Ingredients *
IN WATER.
Other REC Limits:NONE RECOMMENDED
OSHA PEL:1 MG/M3
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.5 MG/M3
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TIN, 0.3% TIN IN LEAD ALLOY
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:DURING MAINT &/OR OPERATION EXPO TO
HAZ MAY OCCUR DUT TO EXPO TO BATTERY ACID &/OR
VAP,LEAD,ANTIMONY,ARSENCI,TIN &/OR THIER CMPDS FRM BATTERIES.DURING
OPERATION &/OR CHARGING HYDROGEN GAS IS PRODUCED( FLAMM/EXPLO).
SULFURIC ACID:SEVERE BURNS TO ALL TISSUE.INGEST CAUSES SEVERE
BURN,ULCERATION.INHAL CAUSES SEVERE (SUPPLE)
Effects of Overexposure:ACID BURNS TO ALL TISSUES. ULCERATION
LASSITUDE, WT LOSS, CONSTIPATION, ANEMIA, NAUSEA, VOMITING,
PARALYSIS, CENTRAL NERVOUS SYSTEM DEPRESSION.
Medical Cond Aggravated by Exposure:SULFURIC ACID MAY AGGRAVATED OTHER
RESP CONDITIONS.
* First Aid Measures *
First Aid:SULFURIC ACID:IMMED APPLICATION OF LG QUANT OF RUNNING
WATER.REMOVE CONTAMIN CLOTH UNDER RUNNING WATER.GET MED ATTN
IMMED.EYE:WASH W/LG AMTS OF RUNNING WATER OPENING EYELIDS.REMOVE
CONTACT LENSES.GETMED ATTN IMMED.INGEST:DO NOT INDUCE VOMIT.DRINK
AS MUCH MILK/WATER AS POSSIBLE W/O VOMIT.GET MED ATTN.LEAD
ALLOY/CMPDS:WASH W/SOAP/WATER.EYE:FLUSH WELL W/WATER
* Fire Fighting Measures *
Extinguishing Media:ACID & LEAD ALLOY & CMPDS NOT COMBUSTIBLE.USE
WATER,CARBON DIOXIDE,DRY CHEMICAL ON FIRES IN AREA.
Fire Fighting Procedures:NONE SPECIFIED BY MANUFACTURER.
Unusual Fire/Explosion Hazard:HYDROGEN GAS IS FORMED DURING CHARGING OF
BATTERIES AND BY THE ACTION OF SULFURIC ACID ON MOST METALS.
* Accidental Release Measures *
Spill Release Procedures:PLACE BROKEN/OPENED BATT IN SEALED PLASTIC
CNTNRS THAT WILL NOT LEAK ACID/SOLID MATL.DELIVER TO BATTERY
RECYCLER.
Neutralizing Agent:NEUTRALIZE ACID W/BAKING SODA(SODIUM BICARBONATE) OR
SODA ASH(SODIUM CARBONATE)
*Handling and Storage *
Handling and Storage Precautions:STORE IN WELL VENTI COOL AREA.WEAR
PROT EQPMT WHEN MOVING/CONNECTING/DISCONNECTING/MAINTAINING
BATT/CLEANING UP SPILL/BRUSHING BAT POST/HNDL BAT SOLID
Other Precautions:ACID MAY ESCAPE FRM BATT DURING CHARGE @ HI
TEMP/BROKEN/TURN OVER.AVOID OVERCHARGE/HI TEMP DURING
OPERATIONS/STORAGE.HANDL CAREFULLY TO AVOID DMG/TURNING
OVER.HYDROGEN GAS(FLAMM/EXPLO)FRM CHARGING BAT T/ACTION OF ACID ON
METAL.AVOID IGN SOUR
* Physical/Chemical Properties *
HCC:C3
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIED BY MANUFACTURER.
Stability Condition to Avoid:DAMAGING BATTERIES, OVERCHARGING, & HIGH
TEMPERATURES.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DELIVER TO BATTERY RECYCLER. COMPLY W/ALL
APPLICABLE LOCAL, STATE AND FEDERAL REGULATIONS/LAWS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NIOSH/MSHA ORGANIC VAPOR CARTRIDGE OR SUPPLIED
AIR.
Ventilation:NONE SPECIFIED BY MANUFACTURER.
Other Protective Equipment:SAFETY BOOTS, APRON & LONG SLEEVED SHIRT.
Work Hygienic Practices:PREVENT SPILLS AND EXPOSURES.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:POLYETHER POLYOL
OSHA PEL:N/K
ACGIH TLV:N/K
* Hazards Identification *
Routes of Entry: Inhalation:NOSkin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:SKIN: IRRITATION VIA ABSORBTION
THROUGH DAMAGED SKIN ONLY. INHAL: MIST MAY CAUSE RESP TRACT IRRIT.
INGEST: LARGE AMOUNTS MAY CAUSE CNS EFFECTS AND KIDNEY OR LIVER
DAMAGE.
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:SEE HEALTH HAZARDS.
Medical Cond Aggravated by Exposure:NONE.
* First Aid Measures *
IMMEDIATELY WASH SKIN W/LOTS OF SOAP. INGEST: IF LARGE AMOUNTS
SWALLOWED, INDUCE VOMITING. INHAL: REMOVE TO FRESH AIR. SUPPORT
BREATHING(GIVE O*2/ARTF RESP).
* Fire Fighting Measures *
Flash Point Method:PMCC
Extinguishing Media:WATER FOG, FOAM CO*2, DRY CHEMICAL, ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT. USE WATER TO SPRAY NEARBY CONTAINERS &
STRUCTURES EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:PVNT EXPOSURES W/APPROPRIATE PERS PROT
AIR RESPIRATORS OR A CARTRIDGE TYPE RESPIRATOR FOR ORGANIC VAPORS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL PLACE, DRY & WELL
VENTILATED AWAY FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY
CLOSED WHEN NOT IN USE.
Other Precautions:EMPTY CONTAINERS WILL RETAIN PRODUCT RESIDUE AND
VAPORS.
(H*2O=1).
* Physical/Chemical Properties *
Boiling Pt:B.P. Text:SUPDAT
Vapor Pres:NIL
Vapor Density:>1.0
Spec Gravity:SUPDAT
Solubility in Water:VERY SLIGHTLY
Appearance and Odor:COLORLESS LIQUID W/NO ODOR.
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS AND STRONG ACIDS.
Stability Condition to Avoid:EXTREME TEMPERATURES.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.
* Disposal Considerations *
Waste Disposal Methods:DISPOSE OF SPILLED MATERIALS IN ACCORDANCE WITH
ALL APPLICABLE FEDERAL, STATE & LOCAL REGULATORY AGENCIES.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:IF VENTILATION DOES NOT MAINTAIN INHALATION
EXPOSURES BELOW PEL(TLV), USE RESPIRABLE FUME RESPIRATOR OR AIR
SUPPLIED RESPIRATOR WHILE WELDING IN CONFINED SPACE OR GENERAL WORK
AREA.
Ventilation:LOCAL EXHAUST AT THE ARC.
Other Protective Equipment:WEAR HAND, HEAD AND BODY PROTECTION WHICH
HELP TO PREVENT INJURY FROM RADIATION, SPARKS AND ELECTRICAL SHOCK.
Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. DO NOT WEAR CONTAMINATED CLOTHING OR
FOOTWEAR.
Supplemental Safety and Health
INSULATE FROM WORK AND GROUND. TRAIN THE WELDER NOT TO PERMIT
THEY ARE WET.
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:LEAD (SARA III)
Other REC Limits:NONE RECOMMENDED
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:TIN
Other REC Limits:NONE RECOMMENDED
OSHA PEL:2 MG/M3
Ingred Name:ANTIMONY (SARA III)
Fraction by Wt: 0.2-2.2%
Other REC Limits:NONE RECOMMENDED
OSHA PEL:0.5 MG/M3
Ingred Name:ROSIN ACID
Fraction by Wt: 0.5 - 3%
Other REC Limits:NONE RECOMMENDED
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:NO
Health Hazards Acute and Chronic:ACUTE AND CHRONIC- INHALATION OF DUST
MAY CAUSE IRRITATION. PROLONGED EXPOSURE CAN CAUSE PERMANENT
RESPIRATORY DAMAGE. HEALTH STUDIES HAVE SHOWN THAT POTENTIAL HEALTH
RISKS MAY VARY BY INDIVIDUAL. ALW AYS MINIMIZE EXPOSURE AS A
PRECAUTION.
Explanation of Carcinogenicity:CONTAINS LEAD WHICH MAY CAUSE CANCER.
Effects of Overexposure:INHALATION OF DUST MAY CAUSE IRRITATION.
PROLONGED EXPOSURE CAN CAUSE PERMANENT RESPIRATORY DAMAGE. HEALTH
STUDIES HAVE SHOWN THAT POTENTIAL HEALTH RISKS MAY VARY BY
INDIVIDUAL. ALWAYS MINIMIZE EXPOSU RE AS A PRECAUTION.
Medical Cond Aggravated by Exposure:PERSONS WITH A HISTORY OF AILMENTS
OR WITH A PRE-EXISTING DISEASE INVOLVING RESPIRATORY TRACT MAY BE
AT INCREASED RISK FROM EXPOSURE.
* First Aid Measures *
First Aid:CALL FOR MEDICAL AID. EMPLOY FIRST AID TECHNIQUES RECOMMENDED
BY THE AMERICAN RED CROSS. INHALED:REMOVE TO FRESH AIR. PROVIDE
CPR/OXYGEN IF NEEDED. IN CASE OF ELECTRICAL SHOCK, TURN OFF POWER &
FOLLOW RECOMMENDED TREATMENT. IN CASE OF BURNS, CALL PHYSICIAN. IF
FOR BURN.
* Fire Fighting Measures *
Flash Point:NONFLAMMABLE
Extinguishing Media:DRY CHEMICAL, DO NOT USE WATER.
Fire Fighting Procedures:WEAR SELF CONTAINED BREATHING APPARATUS ABOVE
Unusual Fire/Explosion Hazard:INCOMPLETE THERMAL DEGRADATION OF RESINS
ARE KNOWN TO GIVE OFF SMALL AMOUNTS OF FORMALDEHYDE.
* Accidental Release Measures *
Spill Release Procedures:IF MATERIAL IS RELEASED OR SPILLED, COLLECT
AND USE. IF CONTAMINATED OR IN SMALL PARTICLES, VACUUM OR COLLECT
MATERIAL. NEVER USE METHODS WHICH GENERATE DUST.
Neutralizing Agent:NOT APPLICABLE.
*Handling and Storage *
Handling and Storage Precautions:STORAGE- STORE IN A DRY PLACE.
Other Precautions:READ AND UNDERSTAND THE MANUFACTURER'S INSTRUCTIONS
AND THE PRECAUTIONARY LABEL ON THE PRODUCT. AVOID BREATHING FUMES
OR DUSTS.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:INSOLUBLE
Appearance and Odor:SILVER GREY SOLID, ODORLESS
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG OXIDIZING AGENTS
Stability Condition to Avoid:NONE
* Disposal Considerations *
Waste Disposal Methods:NEVER DISPOSE IN TRASH. HOLD FOR RECYCLING OR
DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL
REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:USE NIOSH/MSHA APPROVED TYPE RESPIRATOR FOR
PROTECTION AGAINST DUST.
Ventilation:LOCAL EXHAUST OR OTHER VENTILATION THAT WILL REDUCE DUST
CONCENTRATIONS TO LESS THAN PERMISSIBLE EXPOSURE LIMITS.
Other Protective Equipment:BARRIER CREAMS MAY HELP PREVENT SKIN
IRRITATION IN HYPERSENSITIVE INDIVIDUALS.
Work Hygienic Practices:PRACTICE GOOD PERSONAL HYGIENE WHEN WORKING IN
AREAS WHERE THIS MATERIAL IS USED.
Supplemental Safety and Health
EFTS OF OVEREXP: HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST
INFO AND SAFE HANDLING & EXPOSURE INFORMATION .
* Product Identification *
CAGE:0GMG6
* Composition/Information on Ingredients *
Ingred Name:ZINC OXIDE
Ingred Name:LEAD (SARA III)
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Ingred Name:CADMIUM (SARA III)
* Hazards Identification *
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NOOSHA:NO
Health Hazards Acute and Chronic:ZINC OXIDE: INHAL OF HIGH LEVELS OF
ZINC OXIDE MAY RESULT IN TIGHTNESS OF CHEST, METALLIC TASTE, COUGH,
DIZZINESS, FEVER, CHILLS, HEADACHE, NAUSEA, AND DRY THROAT.
OVEREXPOSURE MAY PRODUCE SYMPTOMS KN OWN AS METAL FUME FEVER OR
"ZINC SHAKES", AN ACUTE, SELF- LIMITING CONDITION WITHOUT
RECOGNIZED (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: COMPLICATIONS. SYMPTOMS OF METAL FUME
FEVER INCLUDE: CHILLS, FEVER, MUSCULAR PAIN, NAUSEA AND VOMITING.
LIKE ANY FINELY DIVIDED PARTICULATE MATTER, ZINC OXIDE MAY CAUSE
MECHANICAL IRRITATION TO SKIN AND EYES. LEAD APPEARS ON THE NAVY
LIST OF OCCUP CHEM REPROD HAZS. SEEK CONSULTATION FROM APPROP (SUPP
DATA)
Medical Cond Aggravated by Exposure:INHALATION OF DUST MAY BE AN
IRRITANT TO PRE-EXISTING RESPIRATORY CONDITIONS.
* First Aid Measures *
First Aid:INHAL: SYMPTOMS RESULTING FROM INHAL OVEREXP USUALLY
AND POSSIBLY ASPIRIN IS RECOMMENDED TO PROVIDE RELIEF FROM FEVER
AND CHILLS. SKIN: FLUSH AREAS W/LARGE AMTS OF WATER. EYE: FLUSH
EYES W/COPIOUS AMTS OF WATER. IN ALL CASES, CONSULT MD FOR MED
ATTN. INGEST: GET MD IMMEDIATELY .
* Fire Fighting Measures *
Extinguishing Media:ZINC OXIDE DOES NOT BURN. WATER SPRAY, DRY CHEM/
CARBON DIOXIDE EXTINGUISHERS MAY BE USED FOR FIRES IN STORAGE
AREAS.
Fire Fighting Procedures:NON-FLAMMABLE. WEAR NIOSH/MSHA APPROVED SCBA
AND FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:NONE.
* Accidental Release Measures *
Spill Release Procedures:AS WITH ANY NUISANCE DUST, AVOID EXCESSIVE
DUSTING. MATERIAL SHOULD BE CONTAINED FOR RECYCLING.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
*Handling and Storage *
Handling and Storage Precautions:STORE IN DRY WELL-VENTILATED LOCATION.
PROTECT FROM PHYSICAL DAMAGE.
Other Precautions:AVOID PROLONGED CONTACT WITH SKIN. LEAD AND CADMIUM
ARE INHERENT IN THE MANUFACTURE OF ZINC AND ARE NOT PHYSICALLY
ADDED IN THE MANUFACTURER OF ZINC OXIDE.
* Physical/Chemical Properties *
HCC:N1
Solubility in Water:NEGLIGIBLE
Appearance and Odor:WHITE POWDER WITH NO ODOR (P AND G SUFFIX MEANS
PELLETS OR GRANULAR)
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
NONE KNOWN
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:NONE
* Disposal Considerations *
Waste Disposal Methods:DISPOSE IN A CLOSED CONTAINER OR HEAVY BAG.
MATERIAL MAY BE RECYCLED OR DISPOSED OF IN ACCORDANCE WITH FEDERAL,
STATE AND LOCAL ENVIRONMENTAL REGS. THIS MATERIAL MAY BE REGULATED
UNDER CERCLA, TSCA, S ARA, AND/OR RCRA REGULATIONS.
| 1 | eyes_protection_mandatory |
* Exposure Controls/Personal Protection *
Respiratory Protection:NO SPECIAL REQMNTS UNDER ORDINARY
CONDITIONS/ADEQUATE VENT.
Ventilation:MECHNICAL(FUME HOOD)
Other Protective Equipment:USE PROTECTIVE(BARRIER) CREAM ON HANDS.
Supplemental Safety and Health
* Product Identification *
* Composition/Information on Ingredients *
Ingred Name:ANHYDRIDE
Ingred Name:ADDITIVES
Fraction by Wt: 1%
Ingred Name:CATALYST
Fraction by Wt: 2%
Ingred Name:EPOXY RESIN
Ingred Name:SOLVENTS
Fraction by Wt: 3%
* Hazards Identification *
Effects of Overexposure:NONE NOTED BY MANUFACTURER.
* First Aid Measures *
First Aid:INHALED:REMOVE TO FRESH AIR. GIVE CPR OR OXYGEN IF NEED
REMOVE CONTAMINATED CLOTHES.KEEP WARM/QUIET. GET MEDICAL ATTENTION
* Fire Fighting Measures *
Extinguishing Media:CARBON DIOXIDE,WATER.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS OR AIR
MASKS.
Unusual Fire/Explosion Hazard:NONE
* Accidental Release Measures *
Spill Release Procedures:EVACUATE UNPROTECTED PERSONS. ELIM IGNITION
SOURCES. STOP LEAK. H*2O SPRAY COOL CONT/DIVERT SPILL FROM
FIRE/HEAT. PROVIDE VENTILATION. ABSORB W COMMERCIAL
ABSORBENT,SHOVEL INTO METAL DRUMS:LG SPILL:DI KE W COMMERCIAL
ABSORBENT,PUMP INTO COVERED DRUMS.
*Handling and Storage *
Handling and Storage Precautions:STORE IN COOL,DRY,WELL VENT,LOW FIRE
RISK AREA. PROTECT FROM PHYSICAL DAMAGE.AVOID ANY PHYSICAL CONTACT.
Other Precautions:NONE
* Physical/Chemical Properties *
HCC:N1
Vapor Density:>1.0
Spec Gravity:>1.0
Appearance and Odor:HIGHLY VISCOUS,TACKY RESIN,SLIGHTLY FRUITY ODOR
Percent Volatiles by Volume:UNK
* Stability and Reactivity Data *
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITHJ ALKALI.
Stability Condition to Avoid:HIGH TEMPERATURE WILL CURE RESIN.
Hazardous Decomposition Products:CARBON DIOXIDE,CARBON MONOXIDE.
* Disposal Considerations *
Waste Disposal Methods:ELIMINATE IGNITION SOURCES. DESTROY BY LIQUID
INCINERATION. INCINERATION WILL BE EASIER BY MIXING WITH A MORE
FLAMMABLE SOLVENT. HANDLE & DISPOSE IN FULL COMPLIANCE WITH ALL
APPLICABLE INTERNATIONAL,F ED,STATE & LOCAL REGULATIONS.
| 1 | eyes_protection_mandatory |
Subsets and Splits