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1
205-208
14 Sn2+ + 2e– ¾® Sn –0 14 AgI + e– ¾® Ag + I– –0 15 Ni2+ + 2e– ¾® Ni –0 23 V3+ + e– ¾® V2+ –0
1
206-209
14 AgI + e– ¾® Ag + I– –0 15 Ni2+ + 2e– ¾® Ni –0 23 V3+ + e– ¾® V2+ –0 26 Co2+ + 2e– ¾® Co –0
1
207-210
15 Ni2+ + 2e– ¾® Ni –0 23 V3+ + e– ¾® V2+ –0 26 Co2+ + 2e– ¾® Co –0 28 In3+ + 3e– ¾® In –0
1
208-211
23 V3+ + e– ¾® V2+ –0 26 Co2+ + 2e– ¾® Co –0 28 In3+ + 3e– ¾® In –0 34 Tl+ + e– ¾® Tl –0
1
209-212
26 Co2+ + 2e– ¾® Co –0 28 In3+ + 3e– ¾® In –0 34 Tl+ + e– ¾® Tl –0 34 PbSO4 + 2e– ¾® Pb + SO2– 4 –0
1
210-213
28 In3+ + 3e– ¾® In –0 34 Tl+ + e– ¾® Tl –0 34 PbSO4 + 2e– ¾® Pb + SO2– 4 –0 36 Ti3+ + e– ¾® Ti2+ –0
1
211-214
34 Tl+ + e– ¾® Tl –0 34 PbSO4 + 2e– ¾® Pb + SO2– 4 –0 36 Ti3+ + e– ¾® Ti2+ –0 37 Cd2+ + 2e– ¾® Cd –0
1
212-215
34 PbSO4 + 2e– ¾® Pb + SO2– 4 –0 36 Ti3+ + e– ¾® Ti2+ –0 37 Cd2+ + 2e– ¾® Cd –0 40 In2+ + e– ¾® In+ –0
1
213-216
36 Ti3+ + e– ¾® Ti2+ –0 37 Cd2+ + 2e– ¾® Cd –0 40 In2+ + e– ¾® In+ –0 40 Cr3+ + e– ¾® Cr2+ –0
1
214-217
37 Cd2+ + 2e– ¾® Cd –0 40 In2+ + e– ¾® In+ –0 40 Cr3+ + e– ¾® Cr2+ –0 41 Fe2+ + 2e– ¾® Fe –0
1
215-218
40 In2+ + e– ¾® In+ –0 40 Cr3+ + e– ¾® Cr2+ –0 41 Fe2+ + 2e– ¾® Fe –0 44 In3+ + 2e– ¾® In+ –0
1
216-219
40 Cr3+ + e– ¾® Cr2+ –0 41 Fe2+ + 2e– ¾® Fe –0 44 In3+ + 2e– ¾® In+ –0 44 S + 2e– ¾® S2– –0
1
217-220
41 Fe2+ + 2e– ¾® Fe –0 44 In3+ + 2e– ¾® In+ –0 44 S + 2e– ¾® S2– –0 48 In3+ + e– ¾® In2+ –0
1
218-221
44 In3+ + 2e– ¾® In+ –0 44 S + 2e– ¾® S2– –0 48 In3+ + e– ¾® In2+ –0 49 U4+ + e– ¾® U3+ –0
1
219-222
44 S + 2e– ¾® S2– –0 48 In3+ + e– ¾® In2+ –0 49 U4+ + e– ¾® U3+ –0 61 Cr3+ + 3e– ¾® Cr –0
1
220-223
48 In3+ + e– ¾® In2+ –0 49 U4+ + e– ¾® U3+ –0 61 Cr3+ + 3e– ¾® Cr –0 74 Zn2+ + 2e– ¾® Zn –0
1
221-224
49 U4+ + e– ¾® U3+ –0 61 Cr3+ + 3e– ¾® Cr –0 74 Zn2+ + 2e– ¾® Zn –0 76 (continued) Standard potentials at 298 K in electrochemical order APPENDIX III Rationalised 2023-24 144 Chemistry Reduction half-reaction Eo/V Cd(OH)2 + 2e– ¾® Cd + 2OH– –0
1
222-225
61 Cr3+ + 3e– ¾® Cr –0 74 Zn2+ + 2e– ¾® Zn –0 76 (continued) Standard potentials at 298 K in electrochemical order APPENDIX III Rationalised 2023-24 144 Chemistry Reduction half-reaction Eo/V Cd(OH)2 + 2e– ¾® Cd + 2OH– –0 81 2H2O + 2e– ¾® H2 + 2OH– –0
1
223-226
74 Zn2+ + 2e– ¾® Zn –0 76 (continued) Standard potentials at 298 K in electrochemical order APPENDIX III Rationalised 2023-24 144 Chemistry Reduction half-reaction Eo/V Cd(OH)2 + 2e– ¾® Cd + 2OH– –0 81 2H2O + 2e– ¾® H2 + 2OH– –0 83 Cr2+ + 2e– ¾® Cr –0
1
224-227
76 (continued) Standard potentials at 298 K in electrochemical order APPENDIX III Rationalised 2023-24 144 Chemistry Reduction half-reaction Eo/V Cd(OH)2 + 2e– ¾® Cd + 2OH– –0 81 2H2O + 2e– ¾® H2 + 2OH– –0 83 Cr2+ + 2e– ¾® Cr –0 91 Mn2+ + 2e– ¾® Mn –1
1
225-228
81 2H2O + 2e– ¾® H2 + 2OH– –0 83 Cr2+ + 2e– ¾® Cr –0 91 Mn2+ + 2e– ¾® Mn –1 18 V2+ + 2e– ¾® V –1
1
226-229
83 Cr2+ + 2e– ¾® Cr –0 91 Mn2+ + 2e– ¾® Mn –1 18 V2+ + 2e– ¾® V –1 19 Ti2+ + 2e– ¾® Ti –1
1
227-230
91 Mn2+ + 2e– ¾® Mn –1 18 V2+ + 2e– ¾® V –1 19 Ti2+ + 2e– ¾® Ti –1 63 Al3+ + 3e– ¾® Al –1
1
228-231
18 V2+ + 2e– ¾® V –1 19 Ti2+ + 2e– ¾® Ti –1 63 Al3+ + 3e– ¾® Al –1 66 U3+ + 3e– ¾® U –1
1
229-232
19 Ti2+ + 2e– ¾® Ti –1 63 Al3+ + 3e– ¾® Al –1 66 U3+ + 3e– ¾® U –1 79 Sc3+ + 3e– ¾® Sc –2
1
230-233
63 Al3+ + 3e– ¾® Al –1 66 U3+ + 3e– ¾® U –1 79 Sc3+ + 3e– ¾® Sc –2 09 Mg2+ + 2e– ¾® Mg –2
1
231-234
66 U3+ + 3e– ¾® U –1 79 Sc3+ + 3e– ¾® Sc –2 09 Mg2+ + 2e– ¾® Mg –2 36 Ce3+ + 3e– ¾® Ce –2
1
232-235
79 Sc3+ + 3e– ¾® Sc –2 09 Mg2+ + 2e– ¾® Mg –2 36 Ce3+ + 3e– ¾® Ce –2 48 Reduction half-reaction Eo/V La3+ + 3e– ¾® La –2
1
233-236
09 Mg2+ + 2e– ¾® Mg –2 36 Ce3+ + 3e– ¾® Ce –2 48 Reduction half-reaction Eo/V La3+ + 3e– ¾® La –2 52 Na+ + e– ¾® Na –2
1
234-237
36 Ce3+ + 3e– ¾® Ce –2 48 Reduction half-reaction Eo/V La3+ + 3e– ¾® La –2 52 Na+ + e– ¾® Na –2 71 Ca2+ + 2e– ¾® Ca –2
1
235-238
48 Reduction half-reaction Eo/V La3+ + 3e– ¾® La –2 52 Na+ + e– ¾® Na –2 71 Ca2+ + 2e– ¾® Ca –2 87 Sr2+ + 2e– ¾® Sr –2
1
236-239
52 Na+ + e– ¾® Na –2 71 Ca2+ + 2e– ¾® Ca –2 87 Sr2+ + 2e– ¾® Sr –2 89 Ba2+ + 2e– ¾® Ba –2
1
237-240
71 Ca2+ + 2e– ¾® Ca –2 87 Sr2+ + 2e– ¾® Sr –2 89 Ba2+ + 2e– ¾® Ba –2 91 Ra2+ + 2e– ¾® Ra –2
1
238-241
87 Sr2+ + 2e– ¾® Sr –2 89 Ba2+ + 2e– ¾® Ba –2 91 Ra2+ + 2e– ¾® Ra –2 92 Cs+ + e– ¾® Cs –2
1
239-242
89 Ba2+ + 2e– ¾® Ba –2 91 Ra2+ + 2e– ¾® Ra –2 92 Cs+ + e– ¾® Cs –2 92 Rb+ + e– ¾® Rb –2
1
240-243
91 Ra2+ + 2e– ¾® Ra –2 92 Cs+ + e– ¾® Cs –2 92 Rb+ + e– ¾® Rb –2 93 K+ +e– ¾® K –2
1
241-244
92 Cs+ + e– ¾® Cs –2 92 Rb+ + e– ¾® Rb –2 93 K+ +e– ¾® K –2 93 Li+ + e– ¾® Li –3
1
242-245
92 Rb+ + e– ¾® Rb –2 93 K+ +e– ¾® K –2 93 Li+ + e– ¾® Li –3 05 APPENDIX III CONTINUED Rationalised 2023-24 145 Appendix Sometimes, a numerical expression may involve multiplication, division or rational powers of large numbers
1
243-246
93 K+ +e– ¾® K –2 93 Li+ + e– ¾® Li –3 05 APPENDIX III CONTINUED Rationalised 2023-24 145 Appendix Sometimes, a numerical expression may involve multiplication, division or rational powers of large numbers For such calculations, logarithms are very useful
1
244-247
93 Li+ + e– ¾® Li –3 05 APPENDIX III CONTINUED Rationalised 2023-24 145 Appendix Sometimes, a numerical expression may involve multiplication, division or rational powers of large numbers For such calculations, logarithms are very useful They help us in making difficult calculations easy
1
245-248
05 APPENDIX III CONTINUED Rationalised 2023-24 145 Appendix Sometimes, a numerical expression may involve multiplication, division or rational powers of large numbers For such calculations, logarithms are very useful They help us in making difficult calculations easy In Chemistry, logarithm values are required in solving problems of chemical kinetics, thermodynamics, electrochemistry, etc
1
246-249
For such calculations, logarithms are very useful They help us in making difficult calculations easy In Chemistry, logarithm values are required in solving problems of chemical kinetics, thermodynamics, electrochemistry, etc We shall first introduce this concept, and discuss the laws, which will have to be followed in working with logarithms, and then apply this technique to a number of problems to show how it makes difficult calculations simple
1
247-250
They help us in making difficult calculations easy In Chemistry, logarithm values are required in solving problems of chemical kinetics, thermodynamics, electrochemistry, etc We shall first introduce this concept, and discuss the laws, which will have to be followed in working with logarithms, and then apply this technique to a number of problems to show how it makes difficult calculations simple We know that 23 = 8, 32 = 9, 53 = 125, 70 = 1 In general, for a positive real number a, and a rational number m, let am = b, where b is a real number
1
248-251
In Chemistry, logarithm values are required in solving problems of chemical kinetics, thermodynamics, electrochemistry, etc We shall first introduce this concept, and discuss the laws, which will have to be followed in working with logarithms, and then apply this technique to a number of problems to show how it makes difficult calculations simple We know that 23 = 8, 32 = 9, 53 = 125, 70 = 1 In general, for a positive real number a, and a rational number m, let am = b, where b is a real number In other words the mth power of base a is b
1
249-252
We shall first introduce this concept, and discuss the laws, which will have to be followed in working with logarithms, and then apply this technique to a number of problems to show how it makes difficult calculations simple We know that 23 = 8, 32 = 9, 53 = 125, 70 = 1 In general, for a positive real number a, and a rational number m, let am = b, where b is a real number In other words the mth power of base a is b Another way of stating the same fact is logarithm of b to base a is m
1
250-253
We know that 23 = 8, 32 = 9, 53 = 125, 70 = 1 In general, for a positive real number a, and a rational number m, let am = b, where b is a real number In other words the mth power of base a is b Another way of stating the same fact is logarithm of b to base a is m If for a positive real number a, a ¹ 1 am = b, we say that m is the logarithm of b to the base a
1
251-254
In other words the mth power of base a is b Another way of stating the same fact is logarithm of b to base a is m If for a positive real number a, a ¹ 1 am = b, we say that m is the logarithm of b to the base a We write this as logab m ,  “log” being the abbreviation of the word “logarithm”
1
252-255
Another way of stating the same fact is logarithm of b to base a is m If for a positive real number a, a ¹ 1 am = b, we say that m is the logarithm of b to the base a We write this as logab m ,  “log” being the abbreviation of the word “logarithm” Thus, we have = = = = = = = = 3 2 2 3 3 5 0 7 log 8 3, Since2 8 log 9 2, Since3 9 log 125 3, Since5 125 log 1 0, Since7 1 Laws of Logarithms In the following discussion, we shall take logarithms to any base a, (a > 0 and a ¹ 1) First Law: loga (mn) = logam + logan Proof: Suppose that logam = x and logan = y Then ax= m, ay = n Hence mn = ax
1
253-256
If for a positive real number a, a ¹ 1 am = b, we say that m is the logarithm of b to the base a We write this as logab m ,  “log” being the abbreviation of the word “logarithm” Thus, we have = = = = = = = = 3 2 2 3 3 5 0 7 log 8 3, Since2 8 log 9 2, Since3 9 log 125 3, Since5 125 log 1 0, Since7 1 Laws of Logarithms In the following discussion, we shall take logarithms to any base a, (a > 0 and a ¹ 1) First Law: loga (mn) = logam + logan Proof: Suppose that logam = x and logan = y Then ax= m, ay = n Hence mn = ax ay = ax+y It now follows from the definition of logarithms that loga (mn) = x + y = loga m – loga n Second Law: loga m n       = loga m – logan Proof: Let logam = x, logan = y Logarithms APPENDIX IV Rationalised 2023-24 146 Chemistry Then ax = m, ay = n Hence x x y ay m a n a    Therefore a a a m log x y log m log n n           Third Law : loga(mn) = n logam Proof : As before, if logam = x, then ax = m Then   n n x nx m a a   giving loga(mn) = nx = n loga m Thus according to First Law: “the log of the product of two numbers is equal to the sum of their logs
1
254-257
We write this as logab m ,  “log” being the abbreviation of the word “logarithm” Thus, we have = = = = = = = = 3 2 2 3 3 5 0 7 log 8 3, Since2 8 log 9 2, Since3 9 log 125 3, Since5 125 log 1 0, Since7 1 Laws of Logarithms In the following discussion, we shall take logarithms to any base a, (a > 0 and a ¹ 1) First Law: loga (mn) = logam + logan Proof: Suppose that logam = x and logan = y Then ax= m, ay = n Hence mn = ax ay = ax+y It now follows from the definition of logarithms that loga (mn) = x + y = loga m – loga n Second Law: loga m n       = loga m – logan Proof: Let logam = x, logan = y Logarithms APPENDIX IV Rationalised 2023-24 146 Chemistry Then ax = m, ay = n Hence x x y ay m a n a    Therefore a a a m log x y log m log n n           Third Law : loga(mn) = n logam Proof : As before, if logam = x, then ax = m Then   n n x nx m a a   giving loga(mn) = nx = n loga m Thus according to First Law: “the log of the product of two numbers is equal to the sum of their logs Similarly, the Second Law says: the log of the ratio of two numbers is the difference of their logs
1
255-258
Thus, we have = = = = = = = = 3 2 2 3 3 5 0 7 log 8 3, Since2 8 log 9 2, Since3 9 log 125 3, Since5 125 log 1 0, Since7 1 Laws of Logarithms In the following discussion, we shall take logarithms to any base a, (a > 0 and a ¹ 1) First Law: loga (mn) = logam + logan Proof: Suppose that logam = x and logan = y Then ax= m, ay = n Hence mn = ax ay = ax+y It now follows from the definition of logarithms that loga (mn) = x + y = loga m – loga n Second Law: loga m n       = loga m – logan Proof: Let logam = x, logan = y Logarithms APPENDIX IV Rationalised 2023-24 146 Chemistry Then ax = m, ay = n Hence x x y ay m a n a    Therefore a a a m log x y log m log n n           Third Law : loga(mn) = n logam Proof : As before, if logam = x, then ax = m Then   n n x nx m a a   giving loga(mn) = nx = n loga m Thus according to First Law: “the log of the product of two numbers is equal to the sum of their logs Similarly, the Second Law says: the log of the ratio of two numbers is the difference of their logs Thus, the use of these laws converts a problem of multiplication/division into a problem of addition/subtraction, which are far easier to perform than multiplication/division
1
256-259
ay = ax+y It now follows from the definition of logarithms that loga (mn) = x + y = loga m – loga n Second Law: loga m n       = loga m – logan Proof: Let logam = x, logan = y Logarithms APPENDIX IV Rationalised 2023-24 146 Chemistry Then ax = m, ay = n Hence x x y ay m a n a    Therefore a a a m log x y log m log n n           Third Law : loga(mn) = n logam Proof : As before, if logam = x, then ax = m Then   n n x nx m a a   giving loga(mn) = nx = n loga m Thus according to First Law: “the log of the product of two numbers is equal to the sum of their logs Similarly, the Second Law says: the log of the ratio of two numbers is the difference of their logs Thus, the use of these laws converts a problem of multiplication/division into a problem of addition/subtraction, which are far easier to perform than multiplication/division That is why logarithms are so useful in all numerical computations
1
257-260
Similarly, the Second Law says: the log of the ratio of two numbers is the difference of their logs Thus, the use of these laws converts a problem of multiplication/division into a problem of addition/subtraction, which are far easier to perform than multiplication/division That is why logarithms are so useful in all numerical computations Logarithms to Base 10 Because number 10 is the base of writing numbers, it is very convenient to use logarithms to the base 10
1
258-261
Thus, the use of these laws converts a problem of multiplication/division into a problem of addition/subtraction, which are far easier to perform than multiplication/division That is why logarithms are so useful in all numerical computations Logarithms to Base 10 Because number 10 is the base of writing numbers, it is very convenient to use logarithms to the base 10 Some examples are: log10 10 = 1, since 101 = 10 log10 100 = 2, since 102 = 100 log10 10000 = 4, since 104 = 10000 log10 0
1
259-262
That is why logarithms are so useful in all numerical computations Logarithms to Base 10 Because number 10 is the base of writing numbers, it is very convenient to use logarithms to the base 10 Some examples are: log10 10 = 1, since 101 = 10 log10 100 = 2, since 102 = 100 log10 10000 = 4, since 104 = 10000 log10 0 01 = –2, since 10–2 = 0
1
260-263
Logarithms to Base 10 Because number 10 is the base of writing numbers, it is very convenient to use logarithms to the base 10 Some examples are: log10 10 = 1, since 101 = 10 log10 100 = 2, since 102 = 100 log10 10000 = 4, since 104 = 10000 log10 0 01 = –2, since 10–2 = 0 01 log10 0
1
261-264
Some examples are: log10 10 = 1, since 101 = 10 log10 100 = 2, since 102 = 100 log10 10000 = 4, since 104 = 10000 log10 0 01 = –2, since 10–2 = 0 01 log10 0 001 = –3, since 10–3 = 0
1
262-265
01 = –2, since 10–2 = 0 01 log10 0 001 = –3, since 10–3 = 0 001 and log101 = 0 since 100 = 1 The above results indicate that if n is an integral power of 10, i
1
263-266
01 log10 0 001 = –3, since 10–3 = 0 001 and log101 = 0 since 100 = 1 The above results indicate that if n is an integral power of 10, i e
1
264-267
001 = –3, since 10–3 = 0 001 and log101 = 0 since 100 = 1 The above results indicate that if n is an integral power of 10, i e , 1 followed by several zeros or 1 preceded by several zeros immediately to the right of the decimal point, then log n can be easily found
1
265-268
001 and log101 = 0 since 100 = 1 The above results indicate that if n is an integral power of 10, i e , 1 followed by several zeros or 1 preceded by several zeros immediately to the right of the decimal point, then log n can be easily found If n is not an integral power of 10, then it is not easy to calculate log n
1
266-269
e , 1 followed by several zeros or 1 preceded by several zeros immediately to the right of the decimal point, then log n can be easily found If n is not an integral power of 10, then it is not easy to calculate log n But mathematicians have made tables from which we can read off approximate value of the logarithm of any positive number between 1 and 10
1
267-270
, 1 followed by several zeros or 1 preceded by several zeros immediately to the right of the decimal point, then log n can be easily found If n is not an integral power of 10, then it is not easy to calculate log n But mathematicians have made tables from which we can read off approximate value of the logarithm of any positive number between 1 and 10 And these are sufficient for us to calculate the logarithm of any number expressed in decimal form
1
268-271
If n is not an integral power of 10, then it is not easy to calculate log n But mathematicians have made tables from which we can read off approximate value of the logarithm of any positive number between 1 and 10 And these are sufficient for us to calculate the logarithm of any number expressed in decimal form For this purpose, we always express the given decimal as the product of an integral power of 10 and a number between 1 and 10
1
269-272
But mathematicians have made tables from which we can read off approximate value of the logarithm of any positive number between 1 and 10 And these are sufficient for us to calculate the logarithm of any number expressed in decimal form For this purpose, we always express the given decimal as the product of an integral power of 10 and a number between 1 and 10 Standard Form of Decimal We can express any number in decimal form, as the product of (i) an integral power of 10, and (ii) a number between 1 and 10
1
270-273
And these are sufficient for us to calculate the logarithm of any number expressed in decimal form For this purpose, we always express the given decimal as the product of an integral power of 10 and a number between 1 and 10 Standard Form of Decimal We can express any number in decimal form, as the product of (i) an integral power of 10, and (ii) a number between 1 and 10 Here are some examples: (i) 25
1
271-274
For this purpose, we always express the given decimal as the product of an integral power of 10 and a number between 1 and 10 Standard Form of Decimal We can express any number in decimal form, as the product of (i) an integral power of 10, and (ii) a number between 1 and 10 Here are some examples: (i) 25 2 lies between 10 and 100 25
1
272-275
Standard Form of Decimal We can express any number in decimal form, as the product of (i) an integral power of 10, and (ii) a number between 1 and 10 Here are some examples: (i) 25 2 lies between 10 and 100 25 2 = 1 25
1
273-276
Here are some examples: (i) 25 2 lies between 10 and 100 25 2 = 1 25 2 10 2
1
274-277
2 lies between 10 and 100 25 2 = 1 25 2 10 2 52 10 10    (ii) 1038
1
275-278
2 = 1 25 2 10 2 52 10 10    (ii) 1038 4 lies between 1000 and 10000
1
276-279
2 10 2 52 10 10    (ii) 1038 4 lies between 1000 and 10000 3 3 1 0 3 8
1
277-280
52 10 10    (ii) 1038 4 lies between 1000 and 10000 3 3 1 0 3 8 4 1 0 3 8
1
278-281
4 lies between 1000 and 10000 3 3 1 0 3 8 4 1 0 3 8 4 1 0 1
1
279-282
3 3 1 0 3 8 4 1 0 3 8 4 1 0 1 0 3 8 4 1 0 1 0 0 0      (iii) 0
1
280-283
4 1 0 3 8 4 1 0 1 0 3 8 4 1 0 1 0 0 0      (iii) 0 005 lies between 0
1
281-284
4 1 0 1 0 3 8 4 1 0 1 0 0 0      (iii) 0 005 lies between 0 001 and 0
1
282-285
0 3 8 4 1 0 1 0 0 0      (iii) 0 005 lies between 0 001 and 0 01 ∴ 0
1
283-286
005 lies between 0 001 and 0 01 ∴ 0 005 = (0
1
284-287
001 and 0 01 ∴ 0 005 = (0 005 × 1000) × 10 –3 = 5
1
285-288
01 ∴ 0 005 = (0 005 × 1000) × 10 –3 = 5 0 × 10 –3 (iv) 0
1
286-289
005 = (0 005 × 1000) × 10 –3 = 5 0 × 10 –3 (iv) 0 00025 lies between 0
1
287-290
005 × 1000) × 10 –3 = 5 0 × 10 –3 (iv) 0 00025 lies between 0 0001 and 0
1
288-291
0 × 10 –3 (iv) 0 00025 lies between 0 0001 and 0 001 ∴ 0
1
289-292
00025 lies between 0 0001 and 0 001 ∴ 0 00025 = (0
1
290-293
0001 and 0 001 ∴ 0 00025 = (0 00025 × 10000) × 10 –4 = 2
1
291-294
001 ∴ 0 00025 = (0 00025 × 10000) × 10 –4 = 2 5 × 10 –4 Rationalised 2023-24 147 Appendix In each case, we divide or multiply the decimal by a power of 10, to bring one non-zero digit to the left of the decimal point, and do the reverse operation by the same power of 10, indicated separately
1
292-295
00025 = (0 00025 × 10000) × 10 –4 = 2 5 × 10 –4 Rationalised 2023-24 147 Appendix In each case, we divide or multiply the decimal by a power of 10, to bring one non-zero digit to the left of the decimal point, and do the reverse operation by the same power of 10, indicated separately Thus, any positive decimal can be written in the form n = m × 10 p where p is an integer (positive, zero or negative) and 1< m < 10
1
293-296
00025 × 10000) × 10 –4 = 2 5 × 10 –4 Rationalised 2023-24 147 Appendix In each case, we divide or multiply the decimal by a power of 10, to bring one non-zero digit to the left of the decimal point, and do the reverse operation by the same power of 10, indicated separately Thus, any positive decimal can be written in the form n = m × 10 p where p is an integer (positive, zero or negative) and 1< m < 10 This is called the “standard form of n
1
294-297
5 × 10 –4 Rationalised 2023-24 147 Appendix In each case, we divide or multiply the decimal by a power of 10, to bring one non-zero digit to the left of the decimal point, and do the reverse operation by the same power of 10, indicated separately Thus, any positive decimal can be written in the form n = m × 10 p where p is an integer (positive, zero or negative) and 1< m < 10 This is called the “standard form of n ” Working Rule 1
1
295-298
Thus, any positive decimal can be written in the form n = m × 10 p where p is an integer (positive, zero or negative) and 1< m < 10 This is called the “standard form of n ” Working Rule 1 Move the decimal point to the left, or to the right, as may be necessary, to bring one non-zero digit 2
1
296-299
This is called the “standard form of n ” Working Rule 1 Move the decimal point to the left, or to the right, as may be necessary, to bring one non-zero digit 2 to the left of decimal point
1
297-300
” Working Rule 1 Move the decimal point to the left, or to the right, as may be necessary, to bring one non-zero digit 2 to the left of decimal point (i) If you move p places to the left, multiply by 10 (ii) If you move p places to the right, multiply by 10p
1
298-301
Move the decimal point to the left, or to the right, as may be necessary, to bring one non-zero digit 2 to the left of decimal point (i) If you move p places to the left, multiply by 10 (ii) If you move p places to the right, multiply by 10p –p
1
299-302
to the left of decimal point (i) If you move p places to the left, multiply by 10 (ii) If you move p places to the right, multiply by 10p –p (iii) If you do not move the decimal point at all, multiply by 10 0
1
300-303
(i) If you move p places to the left, multiply by 10 (ii) If you move p places to the right, multiply by 10p –p (iii) If you do not move the decimal point at all, multiply by 10 0 (iv) Write the new decimal obtained by the power of 10 (of step 2) to obtain the standard form of the given decimal
1
301-304
–p (iii) If you do not move the decimal point at all, multiply by 10 0 (iv) Write the new decimal obtained by the power of 10 (of step 2) to obtain the standard form of the given decimal Characteristic and Mantissa Consider the standard form of n n = m ×10 p, where 1 < m < 10 Taking logarithms to the base 10 and using the laws of logarithms log n = log m + log 10 p = log m + p log 10 = p + log m Here p is an integer and as 1 < m < 10, so 0 < log m < 1, i
1
302-305
(iii) If you do not move the decimal point at all, multiply by 10 0 (iv) Write the new decimal obtained by the power of 10 (of step 2) to obtain the standard form of the given decimal Characteristic and Mantissa Consider the standard form of n n = m ×10 p, where 1 < m < 10 Taking logarithms to the base 10 and using the laws of logarithms log n = log m + log 10 p = log m + p log 10 = p + log m Here p is an integer and as 1 < m < 10, so 0 < log m < 1, i e
1
303-306
(iv) Write the new decimal obtained by the power of 10 (of step 2) to obtain the standard form of the given decimal Characteristic and Mantissa Consider the standard form of n n = m ×10 p, where 1 < m < 10 Taking logarithms to the base 10 and using the laws of logarithms log n = log m + log 10 p = log m + p log 10 = p + log m Here p is an integer and as 1 < m < 10, so 0 < log m < 1, i e , m lies between 0 and 1
1
304-307
Characteristic and Mantissa Consider the standard form of n n = m ×10 p, where 1 < m < 10 Taking logarithms to the base 10 and using the laws of logarithms log n = log m + log 10 p = log m + p log 10 = p + log m Here p is an integer and as 1 < m < 10, so 0 < log m < 1, i e , m lies between 0 and 1 When log n has been expressed as p + log m, where p is an integer and 0 log m < 1, we say that p is the “characteristic” of log n and that log m is the “mantissa of log n