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Which of the following biological effects is produced by the action of insulin?:
Increase in glycolysis.
Increase in the degradation of glycogen.
Reduction of glucose uptake in the liver.
Chemistry
Reduction in the synthesis of fatty acids.
25
2
6ae47db9-ffaf-49d3-87be-e293f4fb9b92
2024
Which of the following amino acids is synthesized from ribose 5-phosphate?:
Aspartate.
Histidine.
Proline.
Chemistry
Alanine.
26
1
07f11305-aaf1-414f-8383-2af3c3fdeea8
2024
Which of the following lipoproteins contains apolipoprotein A1?:
HDL.
VLDL.
LDL.
Chemistry
IDL.
27
2
81062876-7a75-457f-9f08-da6849e38e53
2024
Sphingomyelin is a sphingolipid formed by:
A ceramide and a fatty acid.
A ceramide and a phosphorylcholine group.
A sphingosine and a sugar.
Chemistry
A sphingosine and a fatty acid.
28
1
8a8bcd6d-99f4-4960-9c65-a370d4025aef
2024
What is the limiting step in the biosynthesis of fatty acids?
The condensation of an activated acyl group and two carbons derived from malonyl-CoA.
The formation of palmitate.
The reduction of the double bond to form the corresponding saturated acyl group.
Chemistry
The synthesis of malonyl-CoA in the reaction catalyzed by acetyl-CoA carboxylase.
29
3
e827e371-485b-4e57-8791-153ed743266f
2024
The common precursor in the synthesis of adrenaline, noradrenaline and dopamine is:
Tryptophan.
Tyrosine.
Methionine.
Chemistry
Arginine.
30
1
61e37c18-9cb7-49dd-8381-d99ec17d9d53
2024
The ATP is an example of:
Ribonucleoside.
Deoxyribonucleotide triphosphate.
Nucleic acid.
Chemistry
Ribonucleotide.
31
3
4f4fcd4c-7432-48c0-ab1e-4e4a6541bd6b
2024
Indicate the option that does not result in megaloblastic anemia:
Iron deficiency.
Cobalamin deficiency.
Lesch-Nyhan Syndrome.
Chemistry
Folic acid deficiency.
32
2
f9ac19b2-8d4d-4175-a15a-a7e28b3d5bd5
2024
In the metabolism of glycogen, indicate the incorrect answer:
Phosphorylase is regulated by allosteric interactions and by reversible phosphorylation.
The synthesis of glycogen requires the intervention of the enzyme phosphorylase.
Glycogen is composed of glucose units linked by α-1,4 glycosidic bonds and branches with α-1,6 glycosidic bonds.
Chemistry
Adrenaline and glucagon indicate the need to degrade glycogen.
33
1
fa228565-9584-4044-8158-2a58b884b676
2024
Which of the following enzymes catalyzes an irreversible reaction of gluconeogenesis?:
Phosphoglycerate kinase.
Glyceraldehyde 3-phosphate dehydrogenase.
Enolase.
Chemistry
Fructose 1,6-bisphosphatase.
34
3
37e503b4-8c66-480f-820d-779643e3d4c8
2024
How does the binding of 2,3-bisphosphoglycerate (BPG) affect the affinity of hemoglobin for oxygen?
The affinity increases by binding to a site remote from the O2 binding site.
It reduces the affinity by binding to a site far from the O2 binding site.
Increases the affinity by binding to the O2 attachment site.
Chemistry
Reduce the affinity by binding to the O2 attachment site.
35
1
631a9adf-4bb2-4d63-b5d4-62988bcc9df4
2024
Which of the following trace elements has no known function in the organism and can be a significant toxic agent?:
Selenium.
Molybdenum.
Chromium.
Chemistry
Aluminum.
36
3
b7868ff2-fc3f-49cd-b45a-082768dfe7f7
2024
The benchmark test to identify the presence of SARS-CoV-2 is the reverse transcriptase polymerase chain reaction (RT-qPCR). What parameter is evaluated to interpret a result as positive or negative?
The threshold value of the cycle number (Ct).
The time it takes to perform the RTqPCR.
The intensity of the fluorescent signal in the tenth amplification cycle.
Chemistry
The denaturation temperature of DNA strands.
37
2
1365f6e3-858a-46ff-ba62-14b77330137b
2024
Indicate which of the following pairs of "glucose transporter (GLUT) - main expression tissue" is correct:
GLUT3 - Muscle.
GLUT2 - Liver.
GLUT4 - Brain.
Chemistry
GLUT1 - Small intestine.
38
1
c9ffa4d5-d8bf-45cb-8122-2e86b1e81173
2024
Osmolarity is the measurement of the concentration of solutes defined as:
Number of osmoles of a solute per kilogram of solution (Osm/kg).
Number of osmoles of a solute per liter of solution (Osm/L).
Number of osmoles of a solute per milligram of solution (Osm/mg).
Chemistry
Number of osmoles of a solute per milliliter of solution (Osm/mL).
39
1
d67cd15f-e835-448a-97ab-46a9c99a8c58
2024
The disease of urine smelling like maple syrup is caused by a deficiency of:
Branched-chain α-keto acid dehydrogenase complex.
Phenylalanine hydroxylase.
Cystathionine β-synthase.
Chemistry
Arginase.
40
2
10b3f577-89fc-4976-b8ed-9aa5a76c88b2
2024
Which statement is correct?:
Metallic elements usually form basic oxides; non-metallic elements usually form acidic oxides.
Metallic elements usually form acidic oxides; non-metallic elements usually form basic oxides.
The elements that form basic oxides tend to form volatile compounds.
Chemistry
The elements that form acidic oxides tend to form solid compounds.
41
2
6f76fb10-b38e-4f77-938c-69d88854e35e
2024
Which of the following statements about the elements of Group 15 of the Periodic Table is false?:
All members of the group, except N, are solids under normal conditions.
They exhibit a wide range of oxidation states.
Pentabromides are known for all members of the group, except for P.
Chemistry
Red phosphorus can be obtained by heating white phosphorus at 300ºC in an inert atmosphere for several days.
42
4
170f6d30-a9dc-4702-957a-e1c494c092b0
2024
Which of the following hydroxides is not considered amphoteric?:
Aluminum hydroxide.
Beryllium hydroxide.
Magnesium hydroxide.
Chemistry
Zinc hydroxide.
43
4
0e480ee5-d270-4d3f-98ee-5b33c376a51c
2024
Cobalt-60, used in radiotherapy, can be produced by bombarding cobalt-59 with:
Beta particles.
Alpha particles.
Neutrons.
Chemistry
X-rays.
44
4
205dc9a2-ccb7-4406-93b5-e0c2c3916076
2024
Which of the following statements about phosphorus trifluoride (PF3) is true?:
It is a weak σ-donor ligand and strong π-acceptor.
It is a strong σ-donor ligand and a strong π-acceptor.
It is a weak σ-donor and weak π-acceptor ligand.
Chemistry
It is a strong σ-donor ligand and weak π-acceptor.
45
2
62fb7b59-73df-401f-a9ba-581a898134ba
2024
Which substance is not considered a secondary pollutant in the urban pollution phenomenon known as "oxidizing" or photochemical smog?
Ozone.
Carbon monoxide.
Peroxyacetyl nitrate.
Chemistry
Nitrogen dioxide.
46
1
8fb2efbb-a70b-4520-bf85-9a50a7b3a08f
2024
Which statement in relation to the elements of Group 1 of the Periodic Table is true?:
Na reacts directly with oxygen to produce peroxide, Na2O2.
Rb reacts directly with oxygen to yield a simple oxide, Rb2O.
The K reacts at room temperature with nitrogen to form a nitride, K3N.
Chemistry
The K reacts directly with carbon to form a carbide, K2C2.
47
2
cd7abc8c-c3e9-4da7-877d-1e05e4f54ca5
2024
Which of the following statements about sulfur oxoanions is correct?:
The sulfite ion is a strong reducer, the sulfate ion is a strong oxidizer, and the persulfate ion is a strong reducer.
The sulfite ion is a strong oxidizer, the sulfate ion is a strong reducer, and the persulfate ion is minimally reactive.
The sulfite ion is a strong reductant, the sulfate ion is minimally reactive, and the persulfate ion is a strong oxidant.
Chemistry
The sulfite ion is slightly reactive, the sulfate ion is a strong oxidizer, and the persulfate ion is a strong oxidizer.
48
4
22317c3b-7503-46f1-a263-afa4c02defdf
2024
Regarding the advantages of using anionic clays as a complement to sunscreens, indicate the incorrect answer:
They promote close contact between the sunscreen and the skin, preventing allergies.
They stabilize the sunscreen.
They absorb UV-A ultraviolet radiation.
Chemistry
They absorb UV-B ultraviolet radiation.
49
2
53039e91-4c82-46a7-be1a-4d31f89b23eb
2024
Which of the following species is not considered a pseudohalide?:
Cyanate ion.
Cyanide ion.
Dicarbide ion.
Chemistry
Sulfocyanide ion.
50
4
45a6d140-95a4-4159-82c9-75ef67dd4527
2024
If the Bohr radius of the first orbit of an atom is 0.5 Å. What is the radius of the second orbit?
0.25 Å.
0.125 Å.
2.0 Å.
Chemistry
1.0 Å.
51
4
318d5ce1-817c-4ab6-8fbc-c8cbe11dc7d3
2024
Which of these molecules are isoelectronic with each other?:
Oxygen and ozone.
Nitrogen and carbon monoxide.
Water and sulfur dioxide.
Chemistry
Water and carbon dioxide.
52
1
c4f37d8f-2790-47e3-961d-d63c20770acf
2024
What is the shape of the SO2 molecule?
Linear, with an O in the center.
Linear, with the S in the center.
Angular, with an O in the center.
Chemistry
Angular, with the S in the center.
53
3
53b5f115-0e12-4534-beb8-01e76a68480e
2024
What is the point group symmetry of the ammonia molecule?
C3v.
C2v.
Td.
Chemistry
D3h.
54
2
cf0c2a4c-90e1-41bd-ab1d-9e8ed8c041bf
2024
Considering the unit cells of the cubic packing systems (EC), body-centered cubic (ECCC) and close-packed cubic (ECC), it can be said that they have, respectively:
4, 5 and 10 atoms in the cell.
8, 9 and 14 atoms in the cell.
2, 3 and 8 atoms in the cell.
Chemistry
1, 2 and 4 atoms in the cell.
55
3
04c5dd79-dc1b-4b9e-9986-e342c7a723fb
2024
The melting points of aluminum fluoride (1290°C) and aluminum iodide (190°C) are clearly different because:
The polarizability of iodide is greater than that of fluoride.
Aluminum has a low polarizability, and fluoride is much more polarizing than iodide.
The fluoride anion is very polarizing.
Chemistry
The aluminum fluoride is a covalent compound and the aluminum iodide is ionic.
56
2
6a32428d-98c3-4a9f-a934-6c58358a62a1
2024
The molecule of Chlorine Trifluoride (ClF3):
It exhibits sp3 hybridization of its central atom.
It has F-Cl-F angles of 90°.
It has in the chlorine atom a single pair of unshared electrons.
Chemistry
It has all the Cl-F distances equal.
57
3
b2b580f1-3db6-4583-b83f-994cf2074578
2024
Unlike other elements, every metallic element is characterized by:
Its density and its high electrical and thermal conductivity.
Its shiny surface and its hardness.
The decrease in its electrical conductivity as the temperature increases.
Chemistry
The increase in its electrical conductivity as the temperature rises.
58
4
dcfff8b0-b2c7-48d6-a161-72eb671c2f0e
2024
To which of the following symmetry groups can a polar molecule belong?:
Oh.
Dꝏh.
Cꝏv.
Chemistry
Sci.
59
4
9d40b40f-95ef-4f2e-ae3e-e97dddab852e
2024
Indicate which of the following statements is true if the reduction potential of the perchlorate ion to chlorate ion is 1.20 V in acidic medium and 0.37 V in basic medium:
The oxidizing capacity of the perchlorate ion decreases as the pH increases.
The perchlorate ion is a better reducing agent in an acidic medium than in a basic medium.
The perchlorate ion is reduced more easily in a basic medium than in an acidic medium.
Chemistry
The oxidizing capacity of the perchlorate ion increases as the pH increases.
60
2
3e32d6d0-eb43-4728-aa87-333d6aaa6c17
2024
The Tc is a widely used isotope in medicine that is obtained by the decay, with the emission of a beta particle (β–), of the isotope:
Mo (Molybdenum)
Tc.
Ru.
Chemistry
Mo.
61
3
c3393128-76a0-4b15-a14f-0449b691d644
2024
Which of the following statements about Frenkel defects is true?:
They are a type of intrinsic defect.
They are a type of extrinsic defect.
Its presence in a compound alters the electrical neutrality of it.
Chemistry
Its presence in a compound alters its stoichiometry.
62
2
e3b96f59-9481-4ec5-8c98-b1ad7926e1a4
2024
Among the compounds most commonly used as contrast agents in magnetic resonance imaging (MRI) are the coordination compounds of:
Gadolinium.
Strontium.
Lead.
Chemistry
Francium.
63
2
5108a4e1-8e58-4f41-bf98-22644367411a
2024
How many Fe-Fe bonds should the compound Fe2(CO)9 have in order to comply with the 18 valence electron rule?
One.
None.
Three.
Chemistry
Two.
64
2
767b2e25-9c85-4f1a-9823-33cc34e04e10
2024
On chromium compounds:
Potassium dichromate in the presence of concentrated hydrochloric acid generates potassium chromate.
Chromium is easily attacked by air, so steel is used to coat it and thus protect it.
Cr(VI) compounds are carcinogenic.
Chemistry
The high stability of potassium dichromate means that it is not an oxidizing agent.
65
4
030b3e72-3b93-44ae-8d2d-e251a06941b3
2024
It is true that:
Hydrofluoric acid is a stronger acid than hydrochloric acid.
Potassium chlorate is a weak oxidizing agent.
Hydrofluoric acid is stored in glass bottles, as it attacks plastic.
Chemistry
Hypochlorous acid is a stronger oxidant than sodium hypochlorite.
66
3
811094d8-7a05-403f-bca2-bf2ec5f55f9a
2024
Indicate the correct answer regarding hydrogen:
It is very reactive at room temperature, due to the weakness of the H-H bond.
It is the most abundant element in the Universe and very abundant in the Earth's atmosphere in the form of H2.
The idea of using it as fuel instead of fossil fuels is known as "Water Economy."
Chemistry
It is used in the saturation of unsaturated fats in the presence of catalysts such as palladium.
67
3
3628e346-d3b6-479a-8171-bf3198e60d46
2024
Hydrogen peroxide:
It easily disproportionates in the presence of traces of alkali.
It is a solid at room temperature.
Reduce the salts of Fe(III) to Fe(II) in an acidic medium.
Chemistry
It is a stronger base than water.
68
2
e8d785d6-4943-4329-863f-a68386e23b67
2024
Two isomers of the compound [M(Cl)2(NH3)2] are known, while only one is known of the compound [M(Br)2(Cl)2]. What is the justification for this fact?
[M(Cl)2(NH3)2] is tetrahedral and [M(Br)2(Cl)2] is square planar.
[M(Cl)2(NH3)2] is square planar and [M(Br)2(Cl)2] is tetrahedral.
Both compounds are square planar, but in [M(Cl)2(NH3)2] the ligands are in trans and in [M(Br)2(Cl)2] the ligands are in cis.
Chemistry
Both compounds are square planar, but in [M(Cl)2(NH3)2] the ligands are in cis and in [M(Br)2(Cl)2] the ligands are in trans.
69
1
2ec4a114-c901-459d-96d5-d28001589050
2024
The most stable allotrope form of elemental sulfur is formed by:
Sulfur atoms forming branched zigzag chains.
Sulfur atoms forming linear zigzag chains.
Eight sulfur atoms joined together forming a zigzag ring.
Chemistry
Six sulfur atoms joined together forming a zigzag ring.
70
4
74a4b2ca-b086-45c0-ad6a-9a488e3e2816
2024
What is the space occupancy efficiency in a face-centered cubic packing?
68%
52%
91%
Chemistry
74%
71
3
1e96e951-d155-4fd9-a7e0-3b0a6fb60aa8
2024
The ammonium cation is often considered a pseudo-alkali metal. Which of the following reasons is false?:
Because, just like with alkali metals, their salts are mostly colorless and soluble in water.
Because it has a +1 charge like all alkali metals.
Because, despite containing two non-metals, its size falls within the range of sizes of the alkali cations.
Chemistry
Because the chemical reactions that its nitrate undergoes are the same as those of the nitrates of alkali metals.
72
3
5a44bdce-5b5f-4f8c-9da8-9bd2975ff09d
2024
How is the trans- [Pt(Cl)2(NH3)2] compound synthesized?
Starting from [Pt(NH3)4]2+ making it react with 2 equivalents of HCl.
Starting from [Pt(Cl)4]2‒ making it react with 2 equivalents of NH3.
Starting from [Pt(NH3)4], making it react with 2 equivalents of HCl.
Chemistry
Starting from [Pt(Cl)4]4+, making it react with 2 equivalents of NH3.
73
2
c07ef360-3662-40b5-8edf-e8c78b60024d
2024
Indicate the false answer regarding the hardness of water:
It is due to the presence of Mg2+ and/or Ca2+ ions in solution.
It can be temporary or permanent.
The presence of polyphosphates in the medium does not affect the hardness of the water.
Chemistry
It causes insoluble foams when reacting with the stearate ions of soaps.
74
4
8ececf60-5536-4d59-9f34-853a0c0a168a
2024
Which statement is correct about carbonyl, sulfo, and triphenylphosphine ligands?:
Carbonyl is a strong field, sulfo is a strong field and triphenylphosphine is a weak field.
Carbonyl is a weak field, sulfur is a strong field, and triphenylphosphine is a weak field.
Carbonyl is a strong field, sulfo is a weak field, and triphenylphosphine is a weak field.
Chemistry
Carbonyl is of strong field, sulfo is of weak field and triphenylphosphine is of strong field.
75
3
0058b1cd-2b6a-4447-9fd8-0aaefeaba482
2024
What is the only existing term for a p1 configuration?
1P.
1S.
1D.
Chemistry
2P.
76
3
7ac1f3ac-e775-4ea6-ac8f-d237d22c6c55
2024
Silicon doped with arsenic is:
An intrinsic semiconductor.
An insulator.
An extrinsic n-type semiconductor.
Chemistry
A p-type extrinsic semiconductor.
77
4
79254b34-e3f1-450f-a297-d590c54214df
2024
The boiling point of hydrogen halides follows the order:
HF >> HCl < HBr < HI.
HF >> HCl > HBr > HI.
HF << HCl < HBr < HI.
Chemistry
HF = HCl > HBr < HI.
78
2
57705951-170c-4e5a-8940-bc3b57863728
2024
With which organic fragment is the organometallic fragment Fe(CO)4 isolobal?
CH2.
CH.
CH4.
Chemistry
CH3.
79
2
28d3665d-73b9-4cd7-a2e7-3f21084e9fb0
2024
Osmium tetroxide reacts with alkenes to produce:
Anti neighboring diols.
Syn neighboring diols.
Racemic mixture of oxacyclopropane derivatives.
Chemistry
Equimolar mixture of vicinal diols in a sin:anti ratio.
80
1
ce0f9ac1-379e-45b6-83d2-aedc129b389b
2024
Which of the following reagents is used in the reductive amination reaction of carbonyl compounds and organic amines?:
Sodium borohydride.
m-Chloroperbenzoic Acid.
Copper (I) and ascorbic acid.
Chemistry
Sodium cyanoborohydride.
81
3
f76c1c1b-4122-4b97-8609-9e434c786bc8
2024
The SN1 substitution of (2R,4R)-2-bromo-4-methylhexane with ethanol in an acidic medium produces:
(2S,4R)-2-Ethoxy-4-methylhexane.
(2rac,4R)-2-Ethoxy-4-methylhexane.
(2R,4R)-2-Ethoxy-4-methylhexane.
Chemistry
(2R,4rac)-2-Ethoxy-4-methylhexane.
82
1
3e32f3bc-748f-4f5c-8745-c66edaca8b9a
2024
The condensation of carbonyl compounds with secondary amines leads to the formation of the corresponding enamines. What is the main advantage of the reaction of these enamines with haloalkanes?
Regioselective formation of aziridinic derivatives.
Insertion of halogens in the alpha position to the carbonyl group.
Minimization of multiple alkylation at the alpha position of the carbonyl derivative.
Chemistry
Formation of alpha-beta hydroxyamines.
83
4
57fa6203-3d51-4bc8-b701-ae81ef1c2cf0
2024
Which of the following is the best leaving group in an SN2 substitution reaction?:
Cl–.
I-.
F-.
Chemistry
Br-.
84
1
a8b72e2c-c5bc-478b-871e-f21351c0d4e4
2024
What product would be predominantly obtained when treating (S)-2-bromobutane with sodium ethoxide in ethanol?
1-butene.
(R)-2-ethoxybutane.
Racemic 2-ethoxybutane.
Chemistry
2-butene.
85
3
c73cc671-7b07-4eb9-911a-e75ce63d6936
2024
What product is formed when ethyl pentanoate reacts with two equivalents of ethylmagnesium bromide?
3-hexanone.
3-heptanone.
3-ethyl-3-heptanol.
Chemistry
3-methyl-3-heptanol.
86
4
19a7361c-4cf5-4792-957d-fa0ae88e81a9
2024
What product will be formed when 2-phenylpropanal reacts with the following compound?
5-phenyl-3-penten-2-one.
4-phenyl-2-pentenal.
5-phenyl-2-hexanone.
Chemistry
5-phenyl-3-hexen-2-one.
87
3
73532abd-692a-496b-8aaf-c85ab8c5ac5a
2024
Which of the following organic liquids is denser than water?:
Toluene.
Tetrahydrofuran.
2-chloro-2-methylpropane.
Chemistry
Dichloromethane.
88
3
ef89291c-3a3b-4191-9067-83e0ad201119
2024
Which of the following cyclic systems is antiaromatic, according to Hückel's rule?
Cyclopentadienyl cation.
Cycloheptatrienyl cation.
Cyclooctatetraenyl dianion.
Chemistry
Cyclopentadienyl anion.
89
2
2f9e5c7c-21ee-44fd-87c6-b399e61fd24b
2024
Which of the following statements about polymers is false?:
The polyglycolic and polylactic acids are biodegradable polyesters.
Neoprene is a synthetic rubber produced from 2-chloro-1,3-butadiene.
The Ziegler-Natta catalyst allows the production of low-density polyethylene, which is very resistant.
Chemistry
Vulcanized rubber has a hardness and elasticity much greater than natural rubber.
90
4
b8d5d8b6-2721-4a80-8f49-8552b95487ea
2024
Which of the following statements about sugars is false?:
The Wohl degradation of D-glucose produces D-arabinose.
The D-idose and the D-gulose are epimers at C-2 and, therefore, form the same osazone.
The reduction of D-galactose with sodium borohydride produces sorbitol, a polyalcohol used as a food additive.
Chemistry
When D-allose is treated with nitric acid, an optically inactive aldonic acid is produced.
91
4
ab2e0178-0cf7-430c-a118-1f67487b4e0d
2024
Which of the following statements is correct?:
Oleic acid is a polyunsaturated fatty acid.
Waxes and glycerides are simple, non-hydrolyzable lipids.
A soap is a sodium or potassium salt of glycerol.
Chemistry
Biodiesel is a mixture of fatty acid methyl esters.
92
3
d200fb37-6987-48ee-bd2e-15f5b5c73f61
2024
What is the majority organic product obtained in the reaction of 2-methylpropanal with sodium hydroxide?
2-Methylpropanoic Acid.
2-Methylpropanol.
2,3,4-Trimethylpentanal.
Chemistry
3-Hydroxy-2,3,4-trimethylpentanal.
93
3
24a38303-73a2-40b3-802b-cd9c04cd38a1
2024
What predominant type of organic compound would you expect in the reaction of cyclohexanone with methylamine in the presence of sodium cyanoborohydride in ethanol?
A hydroxylamine.
A nitrile.
An imine.
Chemistry
An amine.
94
3
91010a14-bebc-4901-ac2d-ca801ae23f14
2024
What reaction conditions could convert an aniline into a phenol?
Treatment with sodium hydroxide, followed by heating in water.
Treatment with sodium nitrite in an acidic medium, followed by heating in water.
Treatment with hydrogen chloride, followed by heating in water.
Chemistry
Treatment with thionyl chloride in an acidic medium, followed by heating in water.
95
1
c04204c1-d271-4bde-bc51-7547813e0b24
2024
What is the main organic product obtained in the reaction of hexanoic acid with lithium aluminium hydride, after an acid work-up?
Hexanal.
Hexanol.
Hexane.
Chemistry
Lithium hexanoate.
96
1
edac2c8a-2f90-4abe-80b4-7f94db107bc1
2024
What is the synthesis of quinolines known as, which involves heating aniline with glycerol, concentrated sulfuric acid, nitrobenzene, and ferrous sulfate?
Combes Synthesis.
Friedländer Synthesis.
Skraup Synthesis.
Chemistry
Doebner Synthesis.
97
4
04772d0a-bfb8-4c0e-a4d6-477cd7dc87ad
2024
Thiophene is an aromatic compound with a sulfur in a ring of:
Four links.
Three links.
Six links.
Chemistry
Five links.
98
3
e03f8226-d6e8-4687-a70c-21b6d108f82d
2024
What compound results from the addition of HBr to 1-butene in the presence of peroxides?
CH3CH2CH2CH2Br.
CH3CH2CHBrCH3.
CH2BrCH2CH=CH2.
Chemistry
CH3CHBrCH=CH2.
99
2
f79140f3-818e-4809-a260-2e6a261f2c91
2024
What chemical reaction is used to transform an alkyne into a ketone?
Hydroboration.
Hydrogenation with Lindlar catalyst.
Hydration under catalysis by acid and mercuric ion.
Chemistry
Reaction with Grignard reagents.
101
4
ebfef547-ec0b-48eb-9624-fc73ac66f955
2024
What is the decreasing order of reactivity of the following compounds towards electrophilic aromatic substitution?:
Phenol > Benzoic Acid > Toluene > Benzene.
Phenol > Toluene > Benzene > Benzoic Acid.
Benzoic Acid > Toluene > Benzene > Phenol.
Chemistry
Toluene > Benzene > Phenol > Benzoic Acid.
104
1
9686fbee-dbd1-4e4c-9b4b-545573ee87ad
2024
What is the best sequence of reactions to prepare heptan-2-one?
a) acetylene, NaNH2; b) 1-bromopentane; c) H2O, HgSO4, H2SO4.
a) propyne, NaNH2; b) 1-bromobutane; c) H2O, HgSO4, H2SO4.
a) acetylene, NaNH2; b) bromomethane; c) NaNH2; d) 1-bromobutane; e) H2O, HgSO4, H2SO4.
Chemistry
a) hex-1-yne, NaNH2; b) bromomethane; c) H2O, HgSO4, H2SO4.
105
2
15aefc81-1dbd-4694-a771-de28a35773bd
2024
The reaction of a phosphorus ylide on a carbonyl group allows us to obtain:
An alcohol.
A condensation aldol dimer.
An aldol.
Chemistry
An alkene.
106
3
a3445c32-c34a-4f01-b9b8-9bfcc7a131a5
2024
Regarding the acidity of the following compounds: benzoic acid, p-methoxybenzoic acid, and p-nitrobenzoic acid, it is established that:
The least acidic is the p-methoxybenzoic acid and the most acidic is the p-nitrobenzoic acid.
The least acidic is benzoic acid and the most acidic is p-methoxybenzoic acid.
The least acidic is benzoic acid and the most acidic is p-nitrobenzoic acid.
Chemistry
The least acidic is the p-methoxybenzoic acid and the most acidic is benzoic acid.
107
2
c33b020a-0053-4a8f-b1c1-16db0f4a545f
2024
Treatment with Na, NH3(liquid) on 2-octyne leads to:
Octane.
(E)-2-octene.
(Z)-2-octene.
Chemistry
1,2-octadiene.
108
1
c016b6f6-8838-469b-85bc-b52d25ec0687
2024
What is the solvent of choice if the reaction of 1-iodo-pentane with sodium azide (NaN3) is intended to proceed with the most favorable kinetics?
Water.
Propanol.
Acetic acid.
Chemistry
Dimethylformamide.
109
3
157e7f48-c422-4eb9-a8c4-e494eda94622
2024
Which of the nuclei indicated cannot be analyzed by a Nuclear Magnetic Resonance spectrometer?
A nucleus with an odd number of protons and an even number of neutrons.
A nucleus with an odd number of protons and an odd number of neutrons.
A nucleus with an even number of protons and an even number of neutrons. 1) BH3/THF 2) H2O2/OHPCC CH2Cl2 1) CH3MgBr 2) H3O+
Chemistry
A nucleus with an even number of protons and an odd number of neutrons.
111
4
5841823a-b028-450e-8d03-479c15d64d17
2024
What is the most appropriate method to prepare n-butylbenzene from benzene?
CH3CH2CH=CH2 / H2SO4.
CH3CH2CH2CH2Cl / AlCl3.
a) CH3CH2CH2COCl / AlCl3; b) H2NNH2 / KOH, heat.
Chemistry
CH3CH2CH2CH2OH / H2SO4.
113
4
acbe3293-1c20-42b5-8818-9ef5128c99ca
2024
The treatment of acetophenone (Ph-CO-CH3) with Br2/CH3COOH leads to:
It does not react under these conditions.
Mixtures of o-BrPh-CO-CH3 + p-BrPh-COCH3.
Ph-CO-CH2Br.
Chemistry
m-BrPh-CO-CH3.
115
4
f7ba2c1e-d665-4f75-bc4c-63824bd6716f
2024
Under what reaction conditions would an alcohol be obtained with anti-Markovnikov regioselectivity from an alkene?
Epoxidation using a peroxycarboxylic acid followed by hydrolysis.
Hydroboration followed by oxidation.
Palladium acetate, CuCl2 in water.
Chemistry
Hydration in strong acid medium.
117
1
a4b8ecd1-e33a-4629-a354-982cfc55e8bd
2024
The Chichibabin reaction involves the condensation of aldehydes and ammonia to obtain:
Pyridines.
Indoles.
Pyrrolidines.
Chemistry
Triazoles.
118
2
cddafaf1-a7d0-4f53-9453-5a500702cd6d
2024
Which of the indicated ketones is suitable as a starting product for the haloform reaction to take place?
2-Pentanone.
3-Heptanone.
Cyclohexanone.
Chemistry
2-Methyl-3-hexanone.
119
2
2a86f917-84ef-4e23-863e-a472d78a92ec
2024
A chromatogram is:
A graph that represents the separation of an analyte from its matrix as a function of mass versus elution volume.
A graph of some function of the solute concentration versus time or elution volume.
A graph that relates the intensity of an analyte signal in the detector to the concentration.
Chemistry
A three-dimensional graph representing a function of the concentration and elution volume against the density.
120
1
48ff8a95-c506-4323-b147-330c4778dce1
2024
What is the ionic strength of a solution formed by KNO3 0.05 M and Na2SO4 0.1 M?
0.25 M.
0.55 M.
0.35 M.
Chemistry
0.15 M.
121
4
165c6aec-1300-4643-93e6-775344c1bfa9
2024
In a chromatogram for a mixture of two components, it is observed that the peaks are not well resolved. Assuming that the length of the column is set at 25 cm and that the packing material is fixed, what measures could be taken to increase the resolution?
Resolution is not a parameter that can be increased or decreased because it does not depend on the chemical nature of the compounds.
Change the eluent, add a buffer to the aqueous phase, or vary the temperature.
Optimize the composition of the mobile phase so that the selectivity factor (α) of the solutes is equal to 1.
Chemistry
Increase the chromatogram time and decrease the inflow rate to the column.
122
1
92cf90a8-0310-4ee9-92fb-fdddb30c87ff
2024
Which of the following is not a type of metallic indicator electrode?:
Of the first kind.
Membrane-based.
Redox.
Chemistry
Of the third kind.
123
1
2efd51cc-452b-49e1-af9f-3fe479de8115
2024
In atomic absorption spectrometry, cold vapor atomization is applied in the quantification of:
Mercury.
Iron.
Lead.
Chemistry
Nickel.
124
2
09b4b414-1457-484e-8469-ce8b05b7ba5d
2024
Indicate the correct answer regarding the following detectors used in gas chromatography:
The flame ionization detector (FID) causes carbonyl, alcohol, halogen, and amine functional groups to generate many ions in the flame.
The thermal conductivity detector (TCD) has a wide range of applications since it is very sensitive.
The electron capture detector (ECD) is widely used in environmental samples as it is sensitive to halogenated organic compounds such as polychlorinated biphenyls.
Chemistry
The thermionic detector is sensitive to organic compounds that contain sulfur and halogens.
125
4
1ac07112-cb77-42ea-af0c-081bdce7609d
2024
Which solvent has a greater elution strength in silica adsorption chromatography?
Pentane.
Hexane.
Acetonitrile.
Chemistry
Methanol.
126
3
bb209ae5-f3a2-4147-9f47-37b8c656d9f0
2024
What is the CORRECT option in relation to chemical ionization in mass spectrometry?:
It produces more fragmentation than electronic ionization.
Does not provide molecular peak.
Increases the ability to separate two peaks of similar masses.
Chemistry
The ionization source is filled with a reactive gas.
127
3
7c17e450-c7d5-4d97-8e22-4f4d34139484
2024
Dialysis is a separation technique that is based on:
The pressure difference that is established on both sides of the dialysis membrane.
The molecular size of the different analytes present in the sample.
The difference between the ionic forces of the sample and the capturing agent or solvent.
Chemistry
The different affinities of the analytes to the solvent or capturing agent.
128
1
8fc348a9-2b84-44a6-845c-68af9d547771
2024
If the amino acids in a blood plasma sample are quantified using cation exchange HPLC, which of the following elutes last?:
Aspartic acid.
Phenylalanine.
Threonine.
Chemistry
Arginine.
129
3
15b8363e-995c-454d-8749-c8ec08329df7
2024
Which of the following is not a method for the determination of total proteins in human serum?:
Kjeldahl.
Biuret.
Winkler.
Chemistry
Lowry.
130
4
008a0b93-8517-4e3f-90bf-73b4bb6aef92
2024
As a consequence of electroosmotic flow, the elution order in a characteristic capillary electrophoresis separation, being: A = anions with greater electrophoretic velocity (v), B = anions with lesser v, C = neutral species, D = cations with greater v, and E = cations with lesser v, is:
D, E, C, B, A.
A, B, C, D, E.
D, E, A, B, C.
Chemistry
A, B, E, D, C.
131
2
ed9678ea-6a53-47f0-8bb9-9c4cd95b1eb5
2024